United States     Office of Air Quality      Emission Standards
            Environmental Protection  Planning and Standards     Division
            Agency        Research Triangle Park, NC 27711
&EPA      National Air Pollution

            Control Techniques

            Advisory Committee

            Minutes of Meeting
            November 19-21,1991
      i

            Volume 2 of 2
                                Printed on Recycled Paper

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     National Air Pollution
     Control Techniques
     Advisory Committee
     Minutes of Meeting
    November 19-21,1991
  U.S. Environmental Protection Agency
      Office Of Air and Radiation

 Office of Air Quality Planning and Standards

      Emission Standards Division

Research Triangle Park, North Carolina 27711

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Two Volume Set:  Volume 1  (Section I - X)
                 Volume 2  (Section I, XI - XVIII, and Appendix)

                        TABLE OF CONTENTS
                                                             PAGE

    I.  INTRODUCTION AND OPENING REMARKS
        Bruce C. Jordan, Committee Chairman 	 1
        Director, Emission Standards Division (ESD)      "
        Office of Air Quality Planning and Standards, EPA

   II.  GENERAL PROVISIONS

        A.  EPA Presentation
            Michele Dubow, ESD  	 5

        B.  Industry Presentation

            Chemical Manufacturers Association  	  19

            Danny Anderson
            Vice President of Environmental Affairs
            First Chemical Corporation

            a.  Supplemental Comments 	  22

        C.  Discussion	28

  III.  HAZARDOUS ORGANIC NATIONAL EMISSION STANDARDS FOR
        HAZARDOUS AIR POLLUTANTS (NESHAP)

        A.  EPA Presentation
            Daphne McMurrer, ESD	33

        B.  Industry Presentation

            Chemical Manufacturers Association  	  43
            Thomas Robinson
            Manager of Regulatory Affairs
            Vulcan Chemicals Corporation

        C.  Discussion	48

   IV-  COKE OVEN NESHAP

        A.  EPA Presentation
            Amanda Agnew,  ESD	53

        B.  Discussion	66

    V.  DRY CLEANING NESHAP

        A.  EPA Presentation
            Linda Herring,  ESD	67

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        B.  Industry Presentation

            1.  International Fabricare Institute  	  *
                William Fisher, Vice President

        C.  Discussion	  .  -   83

   VI.  CHROMIUM ELECTROPLATING NESHAP

        A.  EPA Presentation
            Lalit Banker, BSD	87

        B.  Discussion	99

  VII.  SECTION 112g

        A.  EPA Presentation
            Tim Smith, BSD	105

        B.  Industry Presentations

            1.  Motor Vehicle Manufacturers Association  .  .  119
                Richard Paul
                Manager, Environmental Health

            2,  American Petroleum Institute  	  125
                F. Dan Gealy
                Director, Public Relations
                Atlantic Richfield Company

            3.  Pharmaceutical Manufacturers Association   .  131
                Richard Vetter
                Associate Counsel
                Burroughs Wellcome

            4.  Chemical Manufacturers Association  ....  140
                Joe Woolbert
                Principal Chemical Engineer
                Texas Eastman Chemical Company

        C.  Discussion	145

 VIII.  SOURCE CATEGORY SCHEDULE FOR STANDARDS

        A.  EPA Presentation
            David Svendsgaard and Chuck French,  BSD ....  155


* Did not provide a copy of presentation for inclusion in  the
  minutes.

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                                                          PAGE
   B.  Industry Presentation

         1.  Institute of Chemical Waste Management . . . 181
             Jonathan Kaiser
             Manager, Resource Recovery and Combustion
               Programs
             National Solid Wastes Management Association

     C.  Discussion	190

     D.  Correspondence

         1.  Chemical Manufacturers Association  ....  196

         2.  American Iron and Steel Institute	199
             Bruce A. Steiner
             Vice President, Environment and Energy

IX.  INDUSTRIAL PROCESS COOLING TOWERS

     A.  EPA Presentation
         Phil Mulrine,  BSD	201

     B.  Industry Presentation

         1.  Superior Manufacturing Company  	  227
             Chuck Sanderson, Engineer

     C.  Discussion	236

 X.  MEDICAL WASTE INCINERATORS

     A.  EPA Presentation
         James Eddinger,  BSD	241

     B.  Industry Presentations

         1.  Cremation  Association of North America  .  .  279
             a.   Paul Rahill
             b.   Ed Laux
             c.   Harvey Lapin

         2.  Waste Combustion Equipment Institute  .  .  .  332
             Stephen Shuler
             Chairman

         3.  American Hospital Association 	  340
             Jim McLarney
             Director,  Division of Health Facilities
             Management and Compliance
             and
             Lawrence G.  Doucet
             Doucet and Mainka, P.C.

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                                                            PAGE

          4.  B.C. Wickberg Company	  .  378
              Henry H. Hadley
              President

          5.  Calvert Environmental, Inc   	  386
              Ronald G. Patterson
              President

          6.  Konheim and Ketcham, Inc	397
              Carolyn S. Konheim
              President

      C.  Discussion	435

      D.  Correspondence

          1.  Wisconsin Department of Natural Resources  .  .  457
              Donald F. Theiler
              Director
              Bureau of Air Management

          2.  Joy Energy Systems, Inc	459
              Steve Shuler
              Manager
              Sales and Marketing

 XI.  OVERVIEW OF CONTROL TECHNIQUES GUIDELINES PROGRAM

      A.  EPA Presentations

          1.  General Overview
              Susan R.  Wyatt,  BSD	468

          2.  Transfer Efficiency and Regulatory Guidance for
                Spray Coating Operations
              Dave Salman,  BSD	477

      B.  Discussion	495

XII.  PLASTIC PARTS COATING

      A.  EPA Presentation
          Joanie McLean,  Radian Corporation  	   500

      B.  Industry Presentations

          1.  National  Paint and Coatings Association  . .   521
              Naomi Suss
              PPG Industries,  Inc.
                            "IV

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                                                            PAGE

            2.  Motor Vehicle  Manufacturers Association   .  .   539
               Joe Lennon
               Environmental  Control Engineer
               Ford Motor Company

            3.  Graco, Inc	553
               Steve Kish
               Market Development Manager

            4.  Mobay Corporation 	  562
               John L. Williams
               Director, Technical Marketing

       C.   Discussion	569

       D.   Correspondence

            1.  Navistar International Transportation
                 Corporation	577
               Tim W. McDaniel
               Environmental Manager

            2.  Electrostatic Consultants Company 	 579
               Arvid C. Walberg

            3.  Vantage Products Corporation  	 608
               Dale C. Jones
               Finishing Department Manager

            4.  Motor Vehicle Manufacturers Association .  .  . 623
               Eugene A.  Praschan
               Manager, Emissions and Control

XIII.  OFFSET LITHOGRAPHY

       A.  EPA Presentation
           Donna Jones,  Radian Corporation 	 631


       B.  Industry Presentations

           1.  Rosos  Research Laboratories 	 672
               Agi Rosos
               President

           2.  C.A. Enterprises,  Ltd	676
               Paul L.  Martin
               Vice President, Product  Development

           3.  American Newspaper Publishers  Association  .  . 680
               Wilson  Cunningham
               Vice President, Technical Research

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          4.  National Association of Printing  Ink
                Manufacturers 	  700
              James E. Renson
              Environmental Affairs Coordinator

          5.  Environmental Conservation Board   	  714
              a.  Gerald Bender
                  Vice President
                  Environment, Safety, and Materials
                    Engineering
                  R.R. Donnelley and Sons, Company

              b.  William Schaeffer
                  Consultant, Graphic Arts Technical Foundation

              c.  William Schneidereith, Jr.
                  President
                  Schneidereith and Sons, Inc.

      C.  Discussion	810

      D.  Correspondence

          1.  National Association of Printing Ink
                Manufacturers 	  826
              James H.  Sutphin
              Executive Director

XIV.  OVERVIEW OF CONTROL TECHNIQUES GUIDELINES PROGRAM
      (Repeat of presentations under Section XI.)

 XV.  WOOD FURNITURE COATING

      A.  EPA Presentation and Discussion
          Mary Jo Caldwell,  Midwest Research Institute  .  . 841

      B.  Industry Presentations and Discussions

          1.  Union Carbide	883
              Thayer West
              Marketing Manager,  Unicarb System

          2.  Classic Systems,  Inc	 890
              David Brookman
              Technical  Representative,  Finishing Division

          3.  Graco,  Inc	905
              Steve Kish
              Market Development  Manager
                              VI

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                                                           PAGE

          4.  Mobay Corporation  	 912
              John L. Williams
              Director, Technical Marketing

          5.  American Furniture Manufacturers Association. 921
              Business and Institutional Furniture
                Manufacturers Association
              Kitchen Cabinet Manufacturers Association
              National Paint and Coatings Association

              a.  Robert G. Mclnnes
                  Principal Air Quality Engineer
                  ENSR Consulting and Engineering

              b.  Mark Berkman
                  Senior Consultant
                  National Economic Research Associates

      C .v  Correspondence

          1.  Thomasville Furniture Industries, Inc.   . .  . 963
              Sherry Stookey
              Supervisor
              Environmental Compliance

XVI.  AUTOBODY REFINISHING

      A.   EPA Presentation and Discussion
          Darcy Campbell, Radian Corporation  	 965

      B.   Industry Presentation and Discussions

          1.  National Paint and Coatings Association . .  . 997
              Karl Schultz, Chairman,  Automotive Refinishing
               Coalition

          2.  BASF Corporation	1012
              Bob Inglis
              Director,  Product Planning

          3.  Safety-Kleen	1023
              John P-  Kusz
              Manager, Product Development

          4.  National Auto Dealers Association 	   1028
              Douglas  I.  Greenhaus
              Senior Attorney, Regulatory Affairs

          5.  PPG Industries,  Inc	1037
              R.T. Hilovsky
              Manager, Regulatory Affairs
              Automotive,  Aircraft, and Fleet Finishes
                             VI 1

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                                                              PAGE

             6.   The  Sherwin-Williams  Company  	  1045
                 Gregory  Ocampo
                 Product  Manager

         C.   Correspondence

             1.   Graco, Inc	".  1055
                 Steve Kish
                 Market Development Manager

             2.   Herkules Equipment Corporation   	  1060
                 Richard  A. Robb
                 President

             3.   DuPont-Automotive Products   	  1065
                 Karl R.  Schultz
                 Environmental Consultant

             4.   National Paint  and Coatings Association,   .  1074
                  Automotive Refinish Coalition
                 Jim Sell
                 Senior Counsel

 XVII.   BATCH PROCESSES

         A.   EPA  Presentation
             Randy McDonald, ESD	1115

         B.   Industry Presentations

             1.   On-Demand Environmental Systems, Inc.  . .  .   1148
                 Richard  E. Hamilton
                Vice President

             2.  Chemical Manufacturers Association   ....   1155
                Terri Ranganath
                E.I.  duPont de Nemours and Company

        C.   Discussion	1159

XVIII.  VOLATILE ORGANIC LIQUID STORAGE

        A.  EPA Presentation
            Mark Morris,  ESD	1161

        B.  Industry Presentations

            1.   Conservatek Industries,  Inc	1189
                Rob Ferry
                Vice  President
                              VI

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                                                             PAC
            2.  Chemical Manufacturers Association  ....  1199
                Terri Ranganath
                E.I. duPont de Nemours and Company

        C.  Discussion	1205

        D.  Correspondence

            1.  Petrex, Inc	1206
                W. L. Wagner
                President

            2.  Wisconsin Department of Natural Resources .  1212
                Steven M. Jorgensen
                Engineer, Bureau of Air Management

            3.  American Petroleum Institute  	  1222
                James K. Walters
                Director, Measurement Coordination

APPENDIX: RECORD OF ATTENDANCE  	  1239

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                   I.   INTRODUCTION  AND  COMMENTS
                 Mr. Bruce C. Jordan, Chairperson
            National Air  Pollution  Control  Techniques
                        Advisory Committee
     The National Air Pollution Control Techniques Advisory
Committee  (NAPCTAC) of the U.S. Environmental  Protectional Agency
(EPA) held a meeting on November 19-21, 1991,  at the Sheraton Inn
University Center in Durham, North Carolina.   Mr. Bruce Jordan
called the meeting to order at 9:00 a.m.  Committee members in
attendance were:
     Mr. Donald R. Arkell
     Dr. Patrick R. Atkins
     Mr. William J. Dennison
     Mr. Ralph E. Rise
     Ms. Vivian M. Mclntire
Mr. William O'Sullivan
Dr. John E. Pinkerton
Ms. Deborah A. Sheiman
Mr. Brian L. Taranto
Messrs. Paul H. Arbesraan and Charles A. Collins were unable to
attend the meeting.

     The agenda for the meeting was published in the Federal
Register on October 22, 1991.

     Mr. Jordan opened the meeting by extending a welcome on
behalf of EPA and then introduced his colleagues at the speakers
table; the EPA and EPA contractor staffs on hand to answer
technical, economic, and regulatory questions; and the EPA staff
handling the administrative aspects of the meeting.  He asked
that everyone sign the official register to provide a record of
their participation in the meeting (see Appendix).  Mr. Jordan
noted that minutes of the proceeding would be available as soon
as possible after the date of the meeting.

     Mr. Jordan briefly outlined the agenda and then introduced
the first of several speakers representing EPA and various
industries who addressed issues concerning air pollution to the
Committee.

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                                AGENDA


               U. S. ENVIRONMENTAL PROTECTION AGENCY


   NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
                      Sheraton Inn University Center
                      Brightleaf Ballroom (Third Floor)
                        15-5Q1 at Morreene Road
                         2800 Middleton Avenue
                      Durham, North Carolina  27705
                            (919) 383-8575

                    NOVEMBER 19, 20, AND 21, 1991
 November 19 (Tuesday) - 9:00 a.m.

 NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS
 (NESHAP) PROJECTS STATUS REPORTS
 (Title III of the Clean Air Act Amendments)

              General Provisions

              Hazardous Organic NESHAP (HON)

              Coke Ovens

              Dry Cleaning

              Chromium Electroplating

SECTION  112g
Status Report on the Development of Guidance for New, Modified, and
Reconstructed Sources
(Title III of the Clean Air Act Amendments)

SOURCE CATEGORY SCHEDULE FOR STANDARDS
Status Report on the Development of a Prioritized Agenda for Source Category
Emission Standards Promulgation
(Title III of the Clean Air Act Amendments)

      A LUNCH BREAK WILL BE TAKEN FROM 1:00-2:00 P.M. EACH DAY

11/19/91                            2

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                                  2

November 20 (Wednesday) - 9:00 a.m.

CONTINUATION OF NOVEMBER 19--AS REQUIRED

INDUSTRIAL PROCESS COOLING TOWERS
Status Report on the Development of the Proposed NESHAP
(Title III of the Clean Air Act Amendments)
MEDICAL WASTE INCINERATORS
Status Report on the Development of the Proposed Standards and Emission
Guidelines
(Section 111 and Title III of the Clean Air Act Amendments)
CONTROL TECHNIQUES GUIDELINES (CTG) PROGRAM
(Title I of the Clean Air Act Amendments)

             Overview of Program

             Plastic Parts Coating CTG Document

             Offset Lithography CTG Document


November 21 (Thursday) - 9:00 a.m.

CONTINUATION OF NOVEMBER 20--AS REQUIRED


CONTROL TECHNIQUES GUIDELINES (CTG) PROGRAM
(Title I of the Clean Air Act Amendments)

             Overview of Program

             Wood Furniture Coating CTG Document

             Autobody Refinishing CTG Document

             Batch Processes CTG Document

             Volatile Organic Liquid Storage CTG  Document


      A LUNCH BREAK WILL BE TAKEN FROM 1:00-2:00 P.M. EACH DAY

11/19/91

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                    U.S. ENVIRONMhN I AL PHU I tc I
      NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
 Chairperson and Designated Federal Official
 Mr. Bruce C. Jordan
 Director, Emission Standards Division (MD-13)
 Office of Air Quality Planning and Standards
 U. S. Environmental Protection Agency
 Research Triangle Park, North Carolina 27711
               (919) 541-5572
               FTS:  629-5572
                               COMMITTEE MEMBERS
 Mr. Paul H. Arbesman
 Director, Pollution Control
 Allied-Signal, Inc.
 Columbia Road and Park Avenue
 Morristown, New Jersey 07962
 (201) 455-4286

 Mr. Donald R. Arkell
 Director
 Lane Regional Air Pollution Authority
 225 North 5th Street-Suite 501
 Springfield, Oregon 97477
 (503) 726-2514
 Dr. Patrick R. Atkins
 Director, Environmental Control
 Aluminum Company of America
 1501 Alcoa Building
 Pittsburgh, Pennsylvania 15219
 (412) 553-3805
Mr. Charles A. Collins
Administrator, Air Quality Division
Wyoming Department of Environmental Quality
122 West 25th Street
Cheyenne, Wyoming 82002
(307) 777-7391

Mr. William J. Dennison
Dennison and Associates
4 Cintilar
Irvine, California  92720
(714) 752-4150 or 51
Mr. Ralph E. Hise
President
Advanced Technologies Management, Inc.
2964 Falmouth Road
Cleveland,  Ohio  44122
(216) 751-5135
   Ms. Vivian M. Mclntire
   Environmental Affairs
   Eastman Chemicals Company
   Post Office Box 511
   Kingsport,  Tennessee 37662
   (615) 229-3045

   Mr. William O'Sullivan
   Assistant Director
   Air Quality Engineering and Technology
   N.J. Department of Environmental
   Protection
   401 East State Street, CNO27
   Trenton, New Jersey 08625
   (609) 984-6721

   Dr. John E. Pinkerton
   Program Director, Air Quality
   National Council of the Paper Industry
   for Air and Stream Improvement, Inc.
   260 Madison Avenue
   New York,  New York  10016
   (212) 532-9047

   Ms. Deborah  A. Sheiman
   Resource Specialist
   Natural Resources Defense Council
   1350 New York Avenue, N.W. - Suite 300
   Washington,  D. C.  20005
   (202) 783-7800

   Mr. Brian L. Taranto
   Senior Environmental Conservation
   Associate
   Exxon Chemical Americas
   13501 Katy Freeway
   Houston, Texas 77079
   (713) 870-6117
4
   November 19, 1991

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                        OVERVIEW OF CTG
                             PROGRAM

                     Presented  by Susan Wyatt
                  Chemicals and Petroleum Branch
                   Emission Standards Division
                 Environmental Protection Agency


     Susan  Wyatt,  Chief  of the  Chemicals  and  Petroleum Branch
explained that  all the  remaining agenda items  involved Control
Techniques  Guidelines (CTG's).   Therefore,  the purpose  of  her
presentation was to provide an overview of the CTG program.

     First,  she  explained  that  CTG's apply  to  volatile organic
compound  (VOC)   emissions  in   nonattainment   areas  and  provide
guidance to  States  in writing  VOC rules.   Although CTG's contain
recommended control levels, States can always  adopt more stringent
rules.  They can also adopt less stringent rules  on a case-by-case
basis, provided there  is adequate justification  and the rules are
approved by EPA.  (Slide 2)

     Ms. Wyatt then  described  the Clean Air Act requirements for
CTG's, listed the CTG's EPA is working on, and  described that there
are various opportunities for public comment on CTG's.  EPA is also
developing  rules  and information documents  on other VOC sources.
These were  listed.   (Slides 3-6)

     Ms. Wyatt then  explained  that some of  the source categories
covered by  CTG's  will also be  covered by Title III hazardous air
pollutant standards.   She described why both  are needed for full
coverage, and emphasized that EPA is sensitive to the need to make
the two programs complementary. (Slide  7)  Then she listed the items
to be covered for each CTG project at the NAPCTAC meeting. (Slide 8)

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       OVERVIEW OF VOC
CONTROL TECHNIQUES GUIDELINE (CTG)
           PROGRAM
            NAPCTAC
       NOVEMBER 20-21, 1991
                469

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  WHAT ARE CTG'S? |
• FOR VOC; TITLE I OZONE
  NO N ATTAIN ME NT

• GUIDANCE FOR STATES

• RECOMMENDED RACf

• CASE-BY-CASE RACT

• RACT RULES SUBMITTED TO
  EPA FOR APPROVAL AS PART
  OF STATE IMPLEMENTATION
  PLAN (SIP)
   1 RACT = REASON ABLY AVAILABLE CONTROL TECHNOLOGY

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 WHAT DO THE CAAA
REQUIRE FOR CTG'S?
  13CTG'SBY11/93

  STATES MUST ADOPT
  REGULATIONS FOR CTG
  SOURCE CATEGORIES FOR
  ALL BUT "MARGINAL"
  NONATTAINMENT AREAS
           £71

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             PROJECTS & SCHEDULE
          CTG / SOURCE
                                DRAFT
         FINAL
     SOCMI Distillation
     SOCMI Reactors
                                12/91
         12/92
  8
 10
 Wood Furniture
 Plastic Parts: Business
Machines
 Plastic Parts: Other
 Offset Lithography
 Industrial Wastewater
 Autobody Refinishing
 SOCMI Batch Processing
 VOL Storage Tanks
                                     4/92
          6/93
 11
 12
 13
Cleanup Solvents
Aerospace Coatings
Ship Building & Repair
9/92
11/93
TBD
TBD: Schedule to be determined, projects started in FY 92.
                           £72

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OPPORTUNITIES FOR PUBLIC
       COMMENT?
 NAPCTAC AND PUBLIC
 REVIEW OF PRELIMINARY
 DRAFT (NO
 RECOMMENDATION)

 FR NOTICE - DRAFT FOR
 PUBLIC COMMENTS

 FR NOTICE - FINAL CTG
 PUBLISHED

 PROPOSAL OF STATE
 REGULATIONS
           ^73

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OTHER VOC FEDERAL MEASURES
   MARINE VESSEL LOADING
   RULE

   CONSUMER/COMMERCIAL
   PRODUCTS REPORT AND
   NATIONAL RULES/CTG'S
   INFORMATION DOCUMENTS
   (ACT'S) FOR PESTICIDE
   APPLICATION AND BAKERIES

   STAGE II INFORMATION
   DOCUMENTS
             6

             £74

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   RELATION OF CTG'S TO
      TITLE III RULES
• NEED FOR BOTH

• CONSIDERATION OF BOTH IN
  CTG/RULE DEVELOPMENT
  AND IMPLEMENTATION
           575

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WHAT WILL WE COVER TODAY?

• SIX CTG'S
• EMISSION SOURCES
• CONTROLS
• RACT OPTIONS (NO RACT
  RECOMMENDATIONS)
• EMISSION AND COST
  IMPACTS OF OPTIONS
   - MODEL (EXAMPLE)
     PLANTS
   - NATIONWIDE
• IMPLEMENTATION
  CONSIDERATIONS
• CONSIDERATION OF
  TRANSFER EFFICIENCY IN
  CTG'S INVOLVING COATINGS
             ',;76

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           TRANSFER EFFICIENCY AND REGULATORY GUIDANCE
                   FOR SPRAY COATING OPERATIONS

                         PRESENTATION BY

                           David Salman
                   Chemical Application  Section
                  Chemicals and Petroleum Branch

                        November 20, 1991

     (SLIDE 1) - I will briefly discuss our thoughts on
incorporating transfer efficiency in the regulatory guidance we
will be providing for spray coating operations.

     (SLIDE 2) - To preview our thinking, I have subtitled this
presentation "Why we do not plan to recommend quantitative
consideration of transfer  efficiency in the spray coating CTGs
that will be discussed at  this meeting."

     (SLIDE 3) - To explain the meaning and basis for this plan,
in the rest of my talk I will:

          Identify the spray coating industries and the types of
   spray equipment they use.

          Discuss transfer efficiency, its definition, its
   importance and its complexities.

          Explain how these complexities often make transfer
   efficiency difficult to measure because of its frequent
   variation, and difficult to incorporate quantitatively into
   regulatory guidance or  regulations.

     (SLIDE 4) - Our section has worked with coatings and coating
industries for over fifteen years.  We have worked in the past
with at least 6 coating industries that predominantly spray coat,
preparing control technique guidelines  (CTGs) or new source
performance standards (NSPSs).  We have tried various ways to
deal with transfer efficiency  in these guidelines and
regulations, with limited  success and much difficulty-  We have
drawn upon this experience in  attempting to deal with transfer
efficiency in the three predominantly spray coating industries
which will be discussed at this meeting; plastic parts, wood
furniture and automobile refinishing.

     Each of these industries  coats a wide range of parts with
many different coatings.   Individual facilities in each of these

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industries typically change the size and shape of parts being
coated and/or coatings being sprayed many times each day.

     (SLIDE 5) - There are many types of spray equipment
available.  This slide uses a Chinese restaurant menu approach to
describe various types of spray equipment.  The different types
of spray equipment can be categorized by how they atomize the
paint (air, airless, air-assisted-airless, high-volume low-
pressure and rotary atomizers such as bells and discs), how the
paint is attracted to the part (electrostatic and non-
electrostatic) , and how the equipment is operated (manual hand-
held or automatic equipment ranging from simple reciprocators to
complex robots).

     Most combinations of atomization/attraction/operation are
available.  Most are used to some extent in every spray coating
industry with the exception of automobile refinishing which uses
fewer types of equipment.  Each type of equipment may be used
alone or in combination with other types of equipment in larger
spray booths or in a series of spray booths.

     (SLIDE 6) - In order to understand transfer efficiency, it
is first necessary to understand a little about coatings.  Liquid
coatings can most simply be thought of as containing solvents
(which are often VOCs) and solids (film forming materials).  The
solvents evaporate during application and cure of the coating.
The remaining solids cover the part and dry or cure into the
final film or coating.

     When paint is sprayed, some of the solids sprayed adhere to
the part and some miss or bounce off the part.  The solids that
are wasted because they do not adhere to the part are referred to
as overspray.  Transfer efficiency is a measure of this paint
waste.  Transfer efficiency is the ratio of the amount of solids
deposited on the part(s) to the amount of solids used (sprayed).
For a particular job, where the amount of solids deposited is
constant (coating a given area to a given dry coating thickness),
the amount of solids sprayed varies depending on the transfer
efficiency.  The lower the transfer efficiency, the more solids
need to be sprayed and the greater the amount of waste.  The
better the transfer efficiency, the less solids need to be
sprayed with a corresponding reduction in the amount of waste.

     (SLIDE 7) - Why is transfer efficiency important?  Transfer
efficiency determines the amount of paint used to do a job and
the cost of paint for that job.  Transfer efficiency is directly
related to 1) the quantity of VOC emissions generated and 2) the
amount of solid waste resulting from overspray.  Transfer
efficiency also affects other operating costs such as filters,
maintenance, booth clean-up, ventilation requirements and waste
disposal.

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     (SLIDE 8) - This slide gives a graphical description of how,
for a particular job, the volume of paint used, VOC emissions and
solid waste generated varies with transfer efficiency.

     At 100 percent transfer efficiency, this job could be done
with 3 gallons of coating.  The VOC emissions would equal the
amount of VOC in the 3 gallons of coating and there would be no
solid waste generated from overspray-

     At 60 percent transfer efficiency, 5 gallons of the same
coating would be needed to do the same job.  The VOC emissions
would equal the amount of VOC in the 5 gallons of coating.  The
amount of solid waste generated from overspray would equal the
amount of solids in 2 gallons of coating.

     At 30 percent transfer efficiency, 10 gallons of the same
coating would be needed to do the same job.  The VOC emissions
would equal the amount of VOC in the 10 gallons of coating.  The
amount of solid waste generated from overspray would equal the
amount of solids in 7 gallons of coating.

     At 15 percent transfer efficiency, 20 gallons of the same
coating would be needed to do the same job.  The VOC emissions
would equal the amount of VOC in the 20 gallons of coating.  The
amount of solid waste generated from overspray would equal the
amount of solids in 17 gallons of coating.

     As transfer efficiency goes down, the amount of coating
used, the amount of VOC emitted and the amount of solid waste
generated all increase.

     (SLIDE 9) - What affects transfer efficiency?  The short
answer to this question is virtually everything.  Transfer
efficiency is affected by:

          The skill, technique and fatigue level of the operator.

          The size, shape and complexity of the part.

          The paint being sprayed and its amenability to
     spraying.

          The type, method of operation, maintenance history and
     wear level of the spray equipment.

          Numerous operating parameters such as the spray booth
     ventilation rate, the gun to part distance and the spacing
     of parts on the conveyor.

     All of these potential variables mean that you have to test
to determine transfer efficiency.  You cannot guess or presume
that a particular type of spray gun will achieve a particular


                              £79

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transfer efficiency.  The large number of variables which are
unrelated to the spray gun itself precludes any direct
correlation between transfer efficiency and the type of spray
gun.  A wide range of transfer efficiencies is found for each
type gun, part and paint.


     (SLIDE 10) - When can transfer efficiency vary?  The short
answer to this question is frequently.

     At an individual facility, transfer efficiency can vary:

          From part to part as the size, shape and complexity of
     the part changes.

          From paint to paint as the amenability of the paint to
     spraying changes.

          From person to person as the skill, technique and
     fatigue level of the operator changes, and as the level of
     maintenance and control over automatic equipment changes.

     Transfer efficiency also varies from plant to plant.  Two
plants using the same spray guns and the same paint to coat the
same parts can achieve very different transfer efficiencies.

     This means that testing must be done frequently or
continuously, especially if there are frequent changes in the
size and shape of the parts being coated and the coatings being
used.  As noted earlier, these types of changes occur frequently
in each of the 3 spray coating industries that will be discussed
at this meeting.

     (SLIDE 11) - Another important factor that needs to be
accounted for if transfer efficiency is to be quantitatively
considered in regulatory guidance is establishing a baseline
transfer efficiency for a source category.  A baseline transfer
efficiency is most simply thought of as the transfer efficiency
that can be reasonably expected when reasonably available (RACT)
coatings are used.

     It is difficult to establish meaningful baseline transfer
efficiency values for an industry when many different size and
shape parts are coated.  An appropriate baseline for a hard-to-
coat part may be too low for an easy-to-coat part.  An
appropriate baseline for an easy to coat part may be impossible
to achieve on a hard to coat part.

     Similarly it is difficult to establish meaningful baseline
transfer efficiency values for an industry where many different
types of coatings are used.  Each type of coating may be

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processed (sprayed) differently, so each type of coating could
require a different baseline value.

     As noted previously, each of the 3 predominantly spray
coating industries we are discussing at this meeting coat many
different size and shape parts and use many different coatings.


     (SLIDE 12) - Because of the complexities which yield
frequent variation in transfer efficiency, require frequent
testing to determine transfer efficiency and make setting
baseline transfer efficiency values difficult, we do not plan to
recommend quantitative consideration of transfer efficiency in
the CTGs for these 3 industries.  This means we do not plan to
recommend separate minimum transfer efficiency requirements such
as 50 percent or 65 percent.  This also means that we do not plan
to recommend coating emission limits which directly incorporate
transfer efficiency, for example limits expressed in units of
pounds of VOC per gallon of coating solids deposited.

     (SLIDE 13) - We are giving some consideration to equipment
requirements; for example we could recommend that the use of air
spray be restricted or prohibited.  We believe this would be
directionally correct, but it may be difficult to enforce and
certainly it would be difficult to assess the amount of reduction
that could be credited to a State's or local area's attainment
plan.

    (SLIDE 14) - Even if transfer efficiency is not part of our
guidance, there are many market and economic incentives for
coaters to improve transfer efficiency-  There is the potential
for cost savings resulting from reduced paint usage, reduced
solid waste disposal and easier spray booth clean-up.  There
could also be lower permit fees since with better transfer
efficiency the same work can be done at a lower level of
emissions.  Similarly, improving transfer efficiency can help to
reduce the level of offsets needed for a new facility.  Also with
regard to permits, improving transfer efficiency can allow for
more production under a fixed emission cap since more work can be
done with the same amount of paint while maintaining the same
level of emissions.

     We expect to note in each CTG the various types of spray
equipment that are available, their potential to reduce paint
usage and other possible advantages of their use.

     This concludes my presentation on transfer efficiency.  I
would be happy to answer any questions.
                               £81

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  TRANSFER EFFICIENCY AND
 REGULATORY GUIDANCE FOR
 SPRAY COATING OPERATIONS
      NAPCTAC
NOVEMBER 20-21,  1991

-------
WHY WE DO NOT PLAN TO RECOMMEND
  QUANTITATIVE CONSIDERATION OF
      TRANSFER EFFICIENCY

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IDENTIFY SPRAY COATING
 - INDUSTRIES
 - EQUIPMENT
DISCUSS TRANSFER
EFFICIENCY (TE)
 - DEFINITION
 - IMPORTANCE
 - COMPLEXITIES

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  CURRENT CTG PROJECTS
• PLASTIC PARTS
• WOOD FURNITURE
• AUTO REFINISHING

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TYPES OF SPRAY EQUIPMENT
     AIR
     AIRLESS
     AIR ASSISTED AIRLESS
     HIGH-VOLUME LOW-PRESSURE (HVLP)
     ROTARY ATOMIZERS
ELECTROSTATIC
NON-ELECTROSTATIC
MANUAL
AUTOMATIC

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  TRANSFER EFFICIENCY (TE)
                      SOLVENT (VOC)
COATING =
                      SOLIDS
TE =
  SOLIDS DEPOSITED

SOLIDS USED (SPRAYED)
              '•8'
               6

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 WHY IS TE IMPORTANT?
PAINT USE AND COST
VOC
SOLID WASTE
OTHER OPERATING COSTS

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        100
            3(0)
        60
    ILJ
co CO
 cs
30
                  5(2)
10(7)
         15
                                             20 (17)
                       - GALLONS COATING USED
                       (GALLONS COATING WASTED)-

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WHAT AFFECTS TE?
 OPERATOR
 PART
 PAINT
 SPRAY EQUIPMENT
 NUMEROUS OPERATING
 PARAMETERS
  - SPRAY BOOTH
   VENTILATION
  - GUN TO PART DISTANCE
  - PART SPACING ON
   CONVEYOR

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WHEN CAN TE VARY?
  PART TO PART
  PAINT TO PAINT
  PERSON TO PERSON
  PLANT TO PLANT
          10

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   BASELINE TE
DIFFICULT TO ESTABLISH
MEANINGFUL BASELINE
VALUES WHEN

» MANY DIFFERENT
 SIZE/SHAPE PARTS ARE
 COATED

» MANY DIFFERENT TYPES OF
 COATINGS ARE USED
         '•S2

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DO NOT PLAN TO RECOMMEND I
  SEPARATE MINIMUM TE
  REQUIREMENTS

  COATING EMISSION LIMITS
  WHICH DIRECTLY
  INCORPORATE TE
          :S
           12

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EQUIPMENT REQUIREMENTS ARE
       A POSSIBILITY
EXAMPLE:  PROHIBIT OR
RESTRICT USE OF AIR SPRAY
          13

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    MARKET AND ECONOMIC
   INCENTIVES TO IMPROVE TE
COST SAVINGS  - PAINT
             - SOLID WASTE DISPOSAL

             - SPRAY BOOTH CLEAN-UP

             - PERMIT FEES
 PERMITS
MAXIMIZE PRODUCTION
UNDER EMISSION CAP
MINIMIZE LEVEL OF
OFFSETS NEEDED
              ', CC
              ^ «J ,j
               14

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     After Ms. Wyatt completed her  presentation,  NAPCTAC members
were provided an opportunity to ask questions.

     Mr. Ralph  Hise asked why  EPA is not  developing a  CTG for
POTW's.  Ms.  Wyatt explained that control of emissions from POTW's
are  indirectly  reduced  through  controls  applied  through  the
industrial wastewater CTG.

     Mr.  William  J.  Dennison  asked how  marketplace  incentive
programs interrelate with  the CTG's.  Mr. Bruce Jordan replied that
States have flexibility  as long as equivalency  to RACT is attained.

     Ms. Vivian  Mclntire  expressed concern that  sufficient time
needs to be provided in the State  Implementation  Plan process so
that people  have an opportunity  to apply for case-by-case RACT
determinations.

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          DISCUSSION ON TRANSFER EFFICIENCY PRESENTATION

     QUESTION (Ms. Sheiman) - Could you provide some perspective
on how you have set standards in the past for similar industries?
I recall that some state RACT regulations have the transfer
efficiency concept in them and I presume that the idea for this
came from EPA.

     RESPONSE (Mr. Salman) - There is a long history to this
going back to the CTGs we did in 1977 and 1978.  Some states do
have transfer efficiency considered in their regulations.  For
example, some regulations in California have a minimum transfer
efficiency requirement of 65 percent which is deemed to be met if
you use certain specified types of equipment.  We are concerned
about this because there is no guarantee that 65 percent is
really achieved.  This can lead to two sets of books with
differences between actual and calculated emission rates.

       Some states have become frustrated with dealing with
transfer efficiency.  New York, for example, took transfer
efficiency out of its regulation a few years ago.

     The one area in RACT regulations where there is widespread
use of transfer efficiency is for certain operations at
automobile assembly plants.  We did a lot of work from 1985 to
1988 to establish a specific test procedure and methodology for
determining when to retest.  The paint shop in an automobile
assembly plant is very complex, but they coat the same product
every day for a long time.  The industries we are dealing with at
this meeting change parts and paints much more frequently.

     QUESTION (Ms.  Sheiman) - Without some kind of numerical
standard for transfer efficiency how will we be sure to get some
emission reduction?

     RESPONSE (Mr.  Berry) - We propose to write guidance that
ignores transfer efficiency and to get emission reduction in
other ways.  We feel you cannot measure transfer efficiency.  If
a rule is written based on transfer efficiency, then the
opportunity is created for people to mask real reductions.

     QUESTION (from committee) - By regulating solvent content of
coatings?

     RESPONSE (Mr.  Berry) - That's one way.

     QUESTION (from committee) - There are other alternatives?

-------
     RESPONSE (Mr. Berry) - That is true.

     QUESTION (Mr. O'Sullivan) - The chart shoes that transfer
efficiency is important.  If we ignore it then we may be ignoring
something that is a very useful emission reduction technology.
My question is if EPA does not set specific numerical transfer
efficiency requirements, does EPA expect the states to set them
or would equipment standards be acceptable?

     RESPONSE (Mr. Berry) - We do not expect the states to do
what we have not been able to figure out how to do?

     QUESTION (Mr. O'Sullivan) - The states have to develop SIPs
and they want emission reductions and credit for those emission
reductions.  Is there any mechanism by which states can take
credit for transfer efficiency improvements in their annual
emission reduction projections?

     RESPONSE (Mr. Salman) - That is a good question and it has
already been asked of us by California.  They also wanted to know
if there was some way to take credit for improvements in transfer
efficiency in their plans on an area or industry basis when there
was no specific numerical requirement in the regulation.
     (Mr. Berry) - We are not sure how this will play out.  It is
like trying to measure the soul.  It is hard to get your hands on
this issue, we have tried for a long time .

     QUESTION (audience) - Aren't there methods for measuring
transfer efficiency.  For example, measuring film build and
surface area coated, or the weight gain of coated parts.  These
must give some approximation of transfer efficiency.  Or maybe
measuring the amount of paint waste.  What methods have been
used?

     RESPONSE (Mr. Salman) - The first two methods you mentioned
have been used to determine how much paint was put on the parts,
film build and surface area, and weight gain of coated parts.
Short term transfer efficiency tests have been done using one of
these methods to determine how much paint was put on the part and
measuring paint usage to determine the amount of solids sprayed.
The problem is how much and how often to test when the parts
coated and coatings used are constantly changing.  You could wind
up having to test all the time.  The concept is simple in the
short term.  It may be disruptive or expensive to do a short term
test, but it has been done.  If the parts or coatings change all
the time, then you have to test almost constantly and we have
never seen this done.

     QUESTION  (Mr. Dennison) - You also have to factor in the
constant turnover in who does the spraying.  The person you see
one time may not be there next time.  This would affect transfer
efficiency too.

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     RESPONSE (Mr. Berry) - True, and the presence of a transfer
efficiency testing crew can affect the performance of the
sprayers.  Sprayers may react to having people with clipboards
watching them do their job.

     QUESTION (audience) - From a regulatory standpoint you
should be able to do something with records.  For example,
looking at how much paint was used and what was coated in a month
or a day.

     RESPONSE (Mr. Berry) - We would do that if we thought it
would work.  The labor and the resources are not there to keep
all the necessary records on area coated and film build.  The
records could be awesome.  It could be done, but a lot of
sophistication would be needed and it would be very difficult to
do continuously.

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        U.S. ENVIRONMENTAL PROTECTION AGENCY PRESENTATION
           ON SURFACE COATING OF PLASTIC PARTS CONTROL
                      TECHNIQUES GUIDELINE
     Slide 1.  This presentation covers the development of a CTG
for surface coating of plastic parts.  These are the topics
covered in the presentation.
     First, the industry, coating process, and emissions will be
described, and then the approach to developing and analyzing
control options will be described.  This will include separate
analysis for each of two different sectors of the plastic parts
coating industry—the automotive and the business
machine/miscellaneous sectors.
     Implementation of the control options will be described, and
last, I'll cover particular areas where EPA would like comment.

     Slide 2.  For the purpose of developing the CTG, the
industry was initially divided into three segments, as shown
here, automotive, business machines, and miscellaneous—
(emissions estimates for the industry segments will be presented
in a following slide).
     The business machine and miscellaneous segments were
eventually combined for analysis, because the substrates and
coatings used are similar, and control options could be set for
these parts as a single category.
     The coating facilities covered by the CTG are either in-
house processes at the "end product" manufacturing site,
contractors specializing in molding and coating particular parts,
or job-shops performing coating only.
     Under the automotive sector, the CTG covers interior and
exterior plastic components of automobiles, trucks, tractors,
lawn mowers, and other mobilized equipment.
     The Business Machine segment includes plastic housings for
the products listed here—computers and other business machines,
thinks like TV's and small appliances, and medical equipment.
     Miscellaneous Plastic Parts is a broad category, covering a
diverse array of products.  The ones listed here are examples of
some of the products that fall within this category.  An area
where EPA is particularly interested in comment concerns
miscellaneous plastic parts.  We would welcome information on
particular products that may have unusual coating specifications,
or may otherwise be considered outliers to the miscellaneous
category-  As I have explained, this category was combined with
business machines for developing control options.
                             LGO

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     Slide 3.  These are the general categories of coatings used
to coat plastic parts:  For automotive parts there are different
coatings for interior parts versus exterior parts, and exterior
parts are further divided into flexible and non-flexible parts,
which also require different coatings.
     Examples of specialty coatings are:
          adhesion promoters used on some substrates, or
          glare reducers used on interior parts such as dash
          boards.
     Under Business Machines Coatings these again are general
categories; EMI stands for electro magnetic interference; and RFI
stands for radio frequency interference.
     Shielding coatings act to prevent stray signals from
affecting performance of machines.

     Slide 4.  This is a schematic drawing of a typical coating
line, it shows a series of three spray booths with flash-off
areas between.  Flash-off areas are where initial drying and
evaporation of volatiles occur.
     There may be ovens between booths, or just at the end of the
line; or there may be no oven where air-dry coatings are used in
the case of temperature sensitive plastics.
     Some lines are conveyorized.  On some lines parts are hand
carried from one area to the next.
     VOC Emissions occur in all three areas — booths, flash-off,
and ovens.  Spray booths are clearly where the majority of
emissions occur—about 80 percent.  Ten percent occurs in the
flash-off areas, and the remaining 10 percent in the ovens.  If
no ovens are present, that 10 percent is emitted during flash-
off.

     Slide 5.  Here we show estimated industry-wide emissions for
the two industry segments.  These estimates are based on facility
counts found in supporting documents for State regulations and
the Business Machine NSPS, combined with employment statistics
for non-attainment areas.
     The emission rates were developed using the model facilities
that I'll describe in some following slides.  We don't have
emission estimates for the miscellaneous sector alone, but it
accounts for about 5 percent of the industry, and it's assumed
here that the 5500 tpy is representative of both miscellaneous
and business machine coating emissions.
     These numbers are estimates; there are no inventories
available, but they reflect our best judgement as to the current
industry emissions.

     Slide 6.  Demonstrated VOC controls for the industry are
shown here:  First, under Pollution Prevention technologies, are
lower VOC content coatings.  Lower VOC content can be achieved
using either waterborne coatings, or higher solids content
coatings.
     Waterborne and higher solids coatings are both currently in
use for a variety of applications.  For business machine
applications, waterborne coatings are less common than solvent

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borne coatings; for automotive applications, waterborne coatings
have been used more for interior parts than exterior.  Again
solvent borne coatings are still more commonly used.
     Higher solids coatings are reportedly being used to a
greater extent than waterborne for both automotive and business
machine/miscellaneous applications.
     Under Add-on Control Technologies, thermal incineration and
carbon adsorption are included, controlling exhaust streams from
spray booths and ovens.

     Slide 7.  I'll describe the control options and model plant
analysis separately for two industry segments.  First will be the
automotive.  These are the control options considered for the
Automotive Sector.  On the left side are the coating categories
for which options were developed.  There may be reasons to
develop additional options for red and black coatings due to the
particular needs of some red and black pigments.  EPA is
currently studying this subject.
     Across the top of the table are the baseline and three
control options, in Ibs of VOC per gallon of coating, less water.
Note that while 1 and 2 are coating reformulation options,
control option 3 is use of add-on controls.  We have listed here,
for comparison, the equivalent VOC content that achieves the same
emission reductions as incineration.
     Options 1 and 2 represent the range of VOC contents reported
by coaters and coating manufacturers.  The baseline represents a
level readily achievable by approximately 90 percent of the
coatings reported by coaters and coating manufacturers.
     Control Options 1 and 2 reflect levels that would achieve
substantial emission reductions.  Option 1 is demonstrated by
several coatings per category; Option 2 is also demonstrated, but
by fewer coatings and fewer coating manufacturers.  Generally,
the difference between Option 1 and Option 2 is the number of
suppliers of coatings meeting the VOC level.
     One note on the VOC levels under Option 2:  for exterior
flexible clearcoats, we have received some comments recently
suggesting that the 3.5 Ibs of VOC per gallon of coating is not
readily available.  We expect further input and some further
investigation on these coatings.

     Slide 8.  This table shows the model plants developed for
analysis of control options for the automotive segment.  Four
plant sizes were developed, with various combinations of process
lines.  We used three plants of each size, one each coating
interior parts, exterior flexible parts, and exterior non-
flexible parts, for a total of 12 model plants.  The model plant
parameters are based on responses to questionnaires and several
site visits.

     Slide 9.  The results of the automotive model plant analysis
are shown here.
     For each control option, the range of emission reductions
for all model plants, in TPY and percent, is shown, as are the
ranges of annual control costs and the percent increase in annual

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paint costs.  Additional paint cost figures show the increase in
cost over baseline.
     I would point out that the broad range of percent emission
reductions, in the second column, is due to differences in the
coatings types used in each plant, rather than the plant size
differences.
     And the last column shows the cost effectiveness for each
option.  Again, these are ranges covering all four sizes of model
plant.  The cost effectiveness figures for Options 1 and 2 are
roughly comparable.  Note that, though there is substantial
increase in emission reductions using Option 3, incineration,
there is a disproportionately large increase in costs as well;
this is, of course, reflected in the cost effectiveness figures.
     It should be noted that these incineration costs are for
facilities using conventional spray booths that have not been
engineered to minimize costs of abatement.  If for example, the
waste stream is recirculated to increase the VOC concentration,
the cost effectiveness figures would decrease.

     Slide 10.  Now, for the business machine/miscellaneous
options and analysis:  These are the VOC control options
developed for the business machine/miscellaneous segment.  These
options reflect the same level of demonstration as the automotive
options; and again, the column for Option 3 shows VOC levels that
achieve emission reductions equivalent with incineration.

     Slide 11.  The model plants for the business machine/
miscellaneous segment include three sizes, again developed based
on information collected from questionnaires and site visits.
One model plant was developed for each size category, each model
plant performing similar coating processes.
     These three business machine/miscellaneous model plants,
combined with the 12 automotive model plants gives us a total of
15 model plants.

     Slide 12.  The results of the business machine/miscellaneous
model plant analysis are shown here.  As for the automotive model
plants, we show ranges of emission reductions, annual costs, and
additional annual paint costs for each option.  Again, the ranges
cover the three different model plant size categories.
     Cost effectiveness figures for Options 1 and 2 are roughly
comparable; while the cost effectiveness of incineration is quite
a bit higher.  Again, these costs for incineration reflect use of
conventional spray booths that have not been engineered to
minimize costs of abatement.

     Slide 13.  The national impacts of the three options for
both automotive and business machine/miscellaneous sectors have
been estimated — these impacts are shown here.
     For the automotive sector, reductions range from 12,000 tpy
under Option 1 to 35,000 tpy under Option 3 with associated costs
ranging from $8 million/year for Option 1, to $770 million/year
for Option 3.

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     For business machine/miscellaneous, emission reductions
range from 2500 hundred tpy to 5000 tpy and costs range from
$1 million/year to $106 million/year.

     Slide 14.  Compliance with the VOC control technologies
would be demonstrated as shown here.
     Coaters using lower VOC content coatings would maintain
records of Method 24 tests for VOC content of all coatings used,
and would also keep records of quantities of coatings used.
     Using add-on controls, the coaters would report results of
performance tests, and maintain records of control device
monitoring.

     Slide 15.  These are a few issues that are Currently
undergoing investigation.  EPA has solicited comment in the
NAPCTAC mailout on these issues in particular.
          First of all, EPA is looking into the availability and
          costs of waterborne shielding coatings.
          Some initial comments on the control options for
          business machine color coats and color texture coats
          suggest that they may be too stringent; EPA is looking
          into these coatings further, as well.
          Air dry coatings are given less stringent VOC levels in
          some state regulations.  As you have seen, our control
          options do not recognize air dry coatings as a separate
          category; so we are investigating temperature
          sensitivity of certain substrates.
          And last, the miscellaneous plastic parts category, as
          I have described, is very diverse.  We have collected
          information on products falling into this category, and
          feel that the proposed options are appropriate for
          miscellaneous plastic parts; but we would like comments
          regarding this point.

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 CONTROL TECHNIQUES GUIDELINE
CONTROL OF VOLATILE ORGANIC COMPOUNDS
FROM SURFACE COATING OF PLASTIC PARTS
    NAPCTAC MEETING PRESENTATION
           NOVEMBER 1991

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       OUTLINE OF PRESENTATION
•   INDUSTRY AND PROCESS DESCRIPTION

•   EMISSIONS
•   CONTROL OPTIONS AND ANALYSIS
        AUTOMOTIVE
        BUSINESS MACHINES/MISCELLANEOUS
•   IMPLEMENTATION
•   AREAS FOR COMMENT

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            INDUSTRY DESCRIPTION
1.  AUTOMOTIVE AND OTHER TRANSPORTATION PARTS
    •   AUTOMOBILE PARTS (FASCIA, BUMPERS,
        DASHBOARDS)
    •   TRACTORS, MOWERS
    •   EXCLUDES MARINE COATING

2.  BUSINESS MACHINES AND ELECTRONICS
    •   COMPUTERS
        COPY MACHINES
    •   MISCELLANEOUS OFFICE EQUIPMENT
        ENTERTAINMENT EQUIPMENT  (RADIOS,
        RECORDERS, TELEVISIONS)
                  <
    •   SMALL HOUSEWARE AND PERSONAL APPLIANCES
    •   MEDICAL EQUIPMENT

3.  MISCELLANEOUS PLASTIC PARTS
    •   TOYS
    •   WINDOW FRAMES
    •   SPORTING GOODS

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            COATING TYPES
AUTOMOTIVE

•   PRIMER
    TOPCOAT
        BASECOAT/CLEARCOAT, OR
        STAND-ALONE COLORCOAT
    CLEARCOAT
    SPECIALTY
BUSINESS MACHINE/MISCELLANEOUS
    PRIMER
    COLORCOAT
    COLOR/TEXTURE COAT
    EMI/RFI SHIELDING
               o,,3
               , B

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cc
                                 Oven
              Finished
              Product
Flash-Off Area
             Clearcoat/Texture
                Booth
                                                     Oven
^ * ^

Prime Booth
N
Flash-Off Area







* * >

uoior Booth
                                                                            Flash-Off
                                                                             Area
             Typical Conveyorized Coating Line for Three-Coat Systems

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       INDUSTRY VOC EMISSIONS
       IN NONATTAINMENT AREAS
AUTOMOTIVE - 38,000 TRY
    340 FACILITIES IN NONATTAINMENT AREAS

BUSINESS MACHINES/MISCELLANEOUS - 5500 TRY
    250 FACILITIES IN NONATTAINMENT AREAS
                    10

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      VOC CONTROL TECHNOLOGIES
POLLUTION PREVENTION
    LOWER VOC CONTENT COATINGS
        WATERBORNE
        HIGHER SOLIDS
ADD-ON CONTROL
    THERMAL INCINERATION (98% EFFICIENCY)
    CARBON ADSORPTION (95% EFFICIENCY)

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VOC CONTROL OPTIONS FOR AUTOMOTIVE SECTOR
          (IBS.  VOC/GAL.  COATING)

AUTOMOTIVE INTERIOR
• COLORCOAT
• PRIMER
AUTOMOTIVE EXTERIOR
• FLEXIBLE
COLORCOAT
CLEARCOAT
PRIMER
• NONFLEXIBLE
COLORCOAT
CLEARCOAT
PRIMER
BASELINE

6.3
5.5

4.6
4.3
5.4
4.6
4.3
5.0
OPTION 1
LOWER VOC

5.0
3.5

4.3
3.8
5.0
4.3
3.8
4.5
OPTION 2
LOWER VOC

3.2
3.5

4.1
3.5
4.5
4.1
3.5
3.5
OPTION 3
INCINERATION

0.6
1.2

0.7
0.5
1.0
0.7
0.5
0.8

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                     PARAMETERS FOR AUTOMOTIVE  MODEL PUNTS
MODEL PLANT SIZE
1 . SMALL
2. MEDIUM
3 . LARGE
4. EXTRA LARGE
CAPACITY
(GAL. COATING/YEAR)
12,000
27,000
98,000
300,000
SPRAY BOOTHS
(CONVEYOR)
0
3
6
16
SPRAY BOOTHS
(No CONVEYOR)
3
2
3
4
00
CO

-------
                     AUTOMOTIVE MODEL PLANT ANALYSIS
OPTION
1
2
3
(INCINERATION)
EMISSION
REDUCTION
RANGE
(TONS/YR)
6 TO 642
10 TO 783
22 TO 897
EMISSION
REDUCTION
RANGE (%)
21 TO 70
35 TO 86
78 TO 98
ANNUAL
CONTROL
COST
(1000$/YR)
3.6 TO 430
6 TO 536
503 TO
18,800
%
INCREASE
IN ANNUAL
PAINT
COST*
2.8 TO
4.9
4.5 TO
6.1
68 TO 82
COST
EFFECTIVENESS
($/TON
REDUCTION)
600 TO 669
571 TO 685
7,000 TO
28,000
*FOR OPTION 3,  TOTAL ANNUAL  COSTS FOR ADD-ONS ARE CONSIDERED THE ADDITIONAL
COATING COSTS.

-------
          VOC CONTROL OPTIONS FOR BUSINESS MACHINES/MISCELLANEOUS SECTOR
                              (LBS.  VOC/GAL.  COATING)

• COLORCOAT
• COLORCOAT/
TEXTURE COAT
• PRIMER
• EMI/RFI SHIELDING
BASELINE
4.8
4,8
4.5
4.9
OPTION 1
LOWER VOC
3.5
3.5
2.9
4.0
OPTION 2
LOWER VOC
2.3
2.3
1.2
2.5
OPTION 3
INCINERATION
1.4
1.4
1.2
1.5
 o
I

en

-------
PARAMETERS FOR BUSINESS MACHINES/MISCELLANEOUS MODEL PUNTS
MODEL PLANT SIZE
1 . SMALL
2. MEDIUM
3 . LARGE
CAPACITY
(GAL. COATING/YEAR)
5,000
41,000
103,000
SPRAY BOOTHS
(CONVEYOR)
0
3
6
SPRAY BOOTHS
(No CONVEYOR)
2
2
3

-------
              BUSINESS MACHINES/MISCELLANEOUS MODEL PLANT ANALYSIS
OPTION
1
2
3
EMISSION
REDUCTION
RANGE
(TONS/YR)
6 TO 123
10 TO 191
11 TO 217
EMISSION
REDUCTION
RANGE (%)
50
79
89
ANNUAL
CONTROL
COST
(1000$/YR)
2.9 TO 58
5 TO 98
373 TO 1,487
%
INCREASE
IN ANNUAL
PAINT
COST*
1.4
2.4
27 TO 65
COST
EFFECTIVENESS
($/TON
REDUCTION)
470
492 TO 518
6,800 TO 34,000
rsi
   *FOR OPTION 3, TOTAL ANNUAL COSTS FOR ADD-ONS ARE CONSIDERED THE ADDITIONAL
   COATING COST.

-------
NATIONAL IMPACTS
CONTROL
OPTION
NATIONAL
EMISSION
REDUCTION
(TONS/YR)
NATIONAL
COSTS
(106 $/YR)
COST
EFFECTIVENESS
$/TON
AUTOMOTIVE
1
2
3
12,000
18,500
35,000
8
12
770
660
650
2200
BUSINESS MACHINES/MISCELLANEOUS
1
2
3
2,500
4,000
5,000
1
2
106
400
500
2100
TOTAL
1
2
3
14,500
22,500
40,000
9
14
876
620
620
2200
       13

-------
                  IMPLEMENTATION
             COMPLIANCE/RECORDKEEPING
CONTROL TECHNOLOGY
          COMPLIANCE
  LOWER VOC
  COATINGS
•  RM24 TESTS FOR VOC CONTENT
•  RECORDS OF QUANTITY USED
  ADD-ON CONTROLS
•  PERFORMANCE TESTS
•  CONTROL DEVICE MONITORING
                        14

-------
                  AREAS FOR COMMENT
    COST AND AVAILABILITY OF WATERBORNE SHIELDING
    COATINGS FOR BUSINESS MACHINES
•   BUSINESS MACHINE COLORCOAT AND COLOR/TEXTURE
    COAT CONTROL OPTIONS
    AIR DRY COATINGS FOR TEMPERATURE-SENSITIVE
    AUTOMOTIVE PLASTICS
    MISCELLANEOUS PLASTIC PARTS CATEGORY
                         15
                                r>
                               , • i

-------
           NAOMI  SUSS,  PPG INDUSTRIES,  REPRESENTING THE
             NATIONAL PAINT AND COATINGS ASSOCIATION

Summary of Naomi Suss' Presentation

     The NPCA presentation began with the qualification that it
would only address the Automotive/Transportation portion of the
CTG.  It continued with a discussion of the driving forces that
have led to the increasing use of plastic parts in the automotive
industry.  The primary reasons for their use were noted to have
been reducing vehicle weight to improve fuel economy, the United
States' concern over potential loss of chrome-producing materials
imported from South Africa and the Soviet Union, and the ease
with which frequent design changes could be accommodated by using
plastic rather than metal in fabricating panels and other parts.

     The NPCA then provided a discussion of figures for high bake
and low bake coatings sold in North America in 1990.  The total
reported volume was 6,475,500 gallons.  It was explained that
high bake and low bake coatings are distinguished according to
whether they cure at temperatures above 194°F (high bake) or at
or below the temperature of 194°F (low bake); the distinction of
high bake and low bake coatings is required due to the
temperature sensitivity of certain plastic substrates.  The
coatings represented in the 1990 sales data were further
categorized according to their functions (primer, clear coat,
touch-up, etc.).

     The first two concerns expressed by the NPCA were that the
CTG did not distinguish between high and low bake coatings, and
that specific coating-types that accounted for 41 percent of the
1990 volume were not separately recognized in the study.  The
lack of consideration for additional breakdowns of coating-types
was noted to be  inconsistent with Michigan's State Rule No. 632
which NPCA considers to be a well-developed regulation.

     As the presentation proceeded, the specific needs of red and
black coatings were mentioned.  First, the NPCA said that color-
matching between plastic and metal parts is important.  And
second, the NPCA gave technical reasons for the allowance of
higher VOC contents in red and black coatings.  With the smaller
particle size of red and black pigments (solids) and the need for
thicker film on  some black or red parts, higher molecular weight
resins are required for adequate dispersion and the prevention of
re-agglomeration of pigment.  The viscosity of red and black
coatings is therefore higher, and more solvent is required for
their use.  The NPCA stated that this situation is a critical
impasse for VOC reduction and needs to be recognized.  The NPCA


                             521

-------
also acknowledged that Michigan allows a scaling factor of 1.15
to be used for determining the allowable VOC contents for red and
black coatings, as compared to other colors.  Also noted was the
problem of opacity which occurs when black primer tends to
produce a graying effect on the color of the topcoat.


     The next point of discussion was the use of Method 24
testing.  The NPCA advocated the use of provisions, as in
Michigan's rule, which differentiate between theoretical VOC
content and the VOC content determined by Method 24.  When
Method 24 is used to determine the VOC content of high bake
coatings, the VOC limit is increased by 0.5 Ibs per gallon; for
low bake coatings, the VOC limit is increased by 0.1 Ibs per
gallon.

     The importance of plastic part function and density were
presented.  It was noted that some parts cannot be subjected to
oven temperatures for curing the coatings without losing their
structural integrity.  Higher VOC content coatings must be used
for these parts so that adequate cross-linking of the coating may
be obtained without the use of heat in the curing process.  The
national usage of such coatings (e.g., air dry primer, 6.1
Ibs/gal) was said to be small.

     The NPCA noted that touch-up and repair coatings, used in
small quantities when coated parts are damaged during production,
currently meet or exceed their applicable specifications in the
Michigan regulation.

     In an overview of Table 66, from Michigan's State rule, the
NPCA made the following statements.  The regulation is technology
forcing, and coatings meeting all of the levels are not yet in
existence.  Also, the conditions in the footnotes on the table
still apply to red and black coatings and Method 24 test data.

     The next portion of NPCA's presentation included projected
sales figures for coatings of various VOC contents for 1992 and
1995, with the sales volume held constant at the 1988 level.
Also presented were estimated levels of VOC emissions from
automotive coating applications in 1988, 1992, and 1995.  By
instituting Michigan Rule No. 632 on a national basis, NPCA
predicted a 15 percent emission reduction by 1992 and a
25 percent reduction by 1995 could be achieved.  Because NPCA
felt this study was based on conservative data and assumptions,
even greater reductions could be anticipated.

     Turning the focus of the presentation specifically to the
CTG, the NPCA stated the following concerns.  Not enough
categories of coating-types were present.  Categories should be
made for monocoats as well as for coated parts which have
specifically mandated safety and functional requirements like
headlights, air bag covers, etc.  Allowances for low-use,
specialty coatings, such as for polycarbonates for headlight


                             522

-------
lenses, vacuum-metalizing, stenciling, appliques, and adhesion
promoters, should be made.  The NPCA noted an expected increased
usage of adhesion promoters, the highest volume specialty
coatings, which are used for thermoplastic olefin (TPO)
(polypropylene) bumpers.  Also, data on this trend may be made
available.  The NPCA stated that, due to the low usage of these
specialty coatings, the cost of reformulation would be a major
concern; thus, it was suggested that these coatings be allowed
less stringent VOC content levels.  The origin of the baseline
VOC content values in Table 5.1 was not evident.  Those baseline
values were not reflected in the model plants.  Option 2 VOC
contents are not now available; a more realistic year for their
availability may be 1995.  The evaluation of surface coatings as
systems is complex and was overlooked.  No flexible clearcoats
that meet the level of 3.5 pounds of VOC per gallon of coating
are available.

     The NPCA expressed displeasure with generally all of the
levels; using Table 65 of Michigan's rule for Option 1 and
Michigan's 1992 values for Option 2 was recommended.  However, it
was suggested that red and black coatings be treated separately
rather than providing a scaling factor for them.  Also, monocoats
were suggested to be evaluated separately.

     Finally, the NPCA agreed with the presentation on transfer
efficiency, given earlier by Dave Salman of EPA.  The NPCA said
that although TE is difficult to quantify, coaters will not be
able to afford using less efficient equipment due to the costs
associated with wasting paint.  Because better equipment would
conserve paint, NPCA would expect lower VOC emissions.  After
these  remarks, the NPCA concluded its presentation and took
questions from the NAPCTAC committee.
                              523

-------
            SURFACE COATING OF PLASTIC PARTS

             CONTROL TECHNIQUES GUIDELINE
cn
ro
     National
    Paint &
   Coatings
'Association
            COMMENTS


            NOVEMBER 20,1991

-------
 Automotive Plastic  Parts Coatings

          Total Volume - 6,475,500 Gallons

                                HBBasecoats13%
         HBCIearcoats14% ^^^^^^^

                                       HB Rigid Prime 4%
tn
ro
  HBMonocoats12%
   LB Basecoats 2%
   LB Clearcoats 4%
       LB Prime 1%
                Interior 20%
 Michigan's Rule 632 Categorization

  HB - High Bake
  LB - Low Bake
                                         HB Flex Prime 8%
       LBMonocoats16%
  Touch Up/Repair 2%
Specialty 4%

-------
    Automotive Plastic Parts Coatings
         Total Volume - 6,475,500 Gallons
    Category
    Interior
    Low Bake Prime
    High Bake Flex Prime
    High Bake Rigid Prime
    High Bake Basecoats
    High Bake Clearcoats
    High Bake Monocoats
    Low Bake Basecoats
    Low Bake Clearcoats
    Low Bake Monocoats
    Touch Up & Repair
    Specialty Coatings
Value
1309.3
45.8
544.3
255.7
816.4
918.8
812.6
152.1
261.9
1023.1
105.0
230.5
%_
20
1
8
4
13
14
13
2
4
16
2
4
In 1000 gallon increments.
                        526

-------
 Automotive Plastic  Parts Coatings
            Coatings not Recognized in CTG Draft
                                    HBBasecoats13%
            HBCIearcoats14%
                                            HB Rigid Prime 4%
en
ro
    HB Monocoats 12%
    LB Basecoats 2%
     LB Clearcoats 4%
         LB Prime 1 %
                  Interior 20%
  Michigan's Rule 632 Categorization
   HB - High Bake
   LB - Low Bake
                                              HB Flex Prime 8%
        LBMonocoats16%
  Touch Up/Repair 2%
Specialty 4%

-------
       Categories not Recognized in CTG Draft
Category






High Bake Monocoats



Low Bake Basecoats



Low Bake Prime



Low Bake ClearcoatS



Low Bake Monocoats



Touch Up & Repair



Specialty Coats






         Total Value
Volume
% Total Volume
812.6
152.1
45.8
261.9
1023.1
105.0
230.5
12.6
2.0
0.7
4.0
15.7
2.0
^0
2631.
    41.0
Data From Chart 2 with Data for Above Categories Take Out.
In 1000 gallon increments.
                           528

-------
        Red  &  Black Coatings
            As a Percentage of Total Color Coats
              HB R&B Basecoat 4%
     HB Monocoats 23%
en
10
  HB R&B Monocoat 6%
       LB Basecoats 5%
      LB R&B Basecoat 0%
              LB Monocoats 17%
  Total Color Coat Volume • 2,804,200 Gallons

  Total Red & Black Volume - 856,100 Gallons
HB Basecoats 25%
LB R&B Monocoat 20%

-------
             Red & Black  Coatings
        As a Percentage of Total Color Coats

Category                           Volume           %_

High Bake Basecoats                     696.7            25
High Bake Red & Black Basecoats           119.7             4
High Bake Monocoats                    634.7            23
High Bake Red & Black Monocoats           117.9             6
Low Bake Basecoats                     142.8             5
Low Bake Red & Black Basecoats             9.3             0
Low Bake Monocoats                     473.9            17
Low Bake Red & Black Monocoats           549.2            20
                         530

-------
                                            6-41
                                           Table  65

                  Volatile  organic  compound emission  limitations  for existing
                automobile  and truck plastic parts coating  lines  after  12/31/89
             Operation
                   Pounds of volatile organic  compounds
                   allowed  to  be  emitted per gallon of
                     coating  (minus  water)  as  applied
1.  High bake coating-
   exterior and  interior parts
CD (2;
   (a)  Prime
       (i)    Flexible coating
       (ii)   Nonflexible coating

   (b)  Topcoat
       (i)    Basecoat
       (ii)   Clearcoac
       (iii) Non-basecoat/clearcoat

2. Air-dried coating—exterior parts

   (a)  Prime

   (b)  Topcoat
       (i)    Basecoat
       (ii)   Clearcoat
       (iii) Non-basecoat/clearcoat

3. Air-dried coating—interior parts

4. Touch-up and repair
      (3)
      (3)
                                    5.0
                                    4.0
                                    4.6
                                    4.3
                                    4.7
6.1


5.8
5.4
6.3

6.3

6.3
FOOTNOTES:
(1)  For  red  and black coatings,  the emission limitation shall be  determined  by multiplying
     the  appropriate  limit  in  this  table by 1.15.

(?)  When  method 24 is used to determine  the  volatile  organic  compound content of a coating,
     the  applicable emission  limitation shall be  determined  by adding 0.5 to the appropriate
     limit in this  table.

(3)  When  method 24 is used to determine  the  volatile  organic  compound content of a coating,
     the  applicable emission  limitation shall be  determined  by adding 0.1 to the appropriate
     limit in this  table.
                                              531

-------
   (18) Table 66 reads as follows:
                                                                         6-42
                                                                       Table 66

                                               Volatile Organic Compound Emission Limitations for Existing
                                             Automobile and Truck Plastic Parts Coating Lines After 12/31/92
                 Operation
                                                                                                     Pounds of Volatile Organic Compound
                                                                                                      Allowed to be Emitted per Gallon of
                                                                                                       Coating  (minus water) as Applied
   1.
       High Bake Coating - Exterior and Interior Parts
tn
CO
ro
   2.
       a.      Prime
               (i)      Flexible Coating
               (ii)     Non-Flexible Coating

       b.      Topcoat
               (i)      Basecoat
               (ii)     Clearcoat
               (iii)     Non-Basecoat/Clearcoat

       Air-Dried Coating-Exterior Parts'1"31

       a.      Prime

       b.      Topcoat
               (i)      Basecoat
               (ii)     Clearcoat
               (iii)     Non-Basecoat/Clearcoat

3. Air-Dried Coating-Interior Parts'1"31

4. Touch Up and Repair'31
                                                                                                                         4.5
                                                                                                                         3.5
4.3
4.0
4.3
                                                                                                                        4.8


                                                                                                                        5.0
                                                                                                                        4.5
                                                                                                                        5.0

                                                                                                                        5.0

                                                                                                                        5.2
   111  For red and black coatings, the emission limitation shall be determined by multiplying the appropriate limit in this table by 1.15.
   121  When method 24 is used to determine the volatile organic compound content of a coating, the applicable emission shall be determined by adding 0.5
      the appropriate limit in this table.
   131  When method 24 is used to determine the volatile organic compound content of a coating, the applicable emission limitation shall be determined by adding
      O.l to the appropriate limit in this table.

-------
GJ
        COATINGS FOR AUTOMOTIVE PLASTIC PARTS
                                    Sales
Coatings sold (1000's gallons)
1,000
   0
     -	v

               /
           \    '

                                                \
                                     '"'B-..  \

                            1
                                                   1     1
1
     <3.0      3.26-3.5     3.76-4.0     4.26-4.5     4.76-5.0     5.26-5.5     5.76-6.0
         3.0-3.25    3.51-3.75   4.01-4.25    4.51-4.75    5.01-5.25    5.51-5.75     6.0>
                                 VOC content (#/ga/)
                                1988      1995
VOC content projections based
on constant 1988 sales volume

-------
CJ1
to
                COATINGS FOR AUTOMOTIVE PLASTIC PARTS
                                Emission of VOC in 1988, 92 & 95
        #'s VOC emitted
        8,000
       6,000
       4,000
       2,000

              <3.0     3.26-3.5    3.76-4.0    4.26-4.5    4.76-5.0    5.26-5.5    5.76-6.0
                  3.0-3.25   3.51-3.75   4.01-4.25   4.51-4.75    5.01-5.25   5.51-5.75     6.0>
                                        VOC content (#/gaJ)
                                     1988
1992   hi  1995
       Calculations used high end of
       VOC for each VOC category
                                   GRAPH

-------
wi
CjJ
CJl
            COATINGS FOR AUTOMOTIVE PLASTIC PARTS
                         Total Emissions of VOC In 1988, 92 & 95
     total #'s VOC emitted (1000's)
     35,000
     30,000
     25,000
     20,000
     15,000
     Calculations used high end of
     VOC for each VOC category

1988
                                        Year
                                       1992     1995
                              GRAPH II

-------
                                     TABLE 5-1. CONTROL OPTIONS (LOW VOC COATINGS)8
                                          Baseline*1
                         Control
                         Level 1
                         Control
                         Level 2
                  Number of
                  Database Coatings
                  Meeting Control
                  Level 2-A
 Automotive Interior
                      ColorCoat

                      Primer
6.3

5.5
5.0

3.5
3.2

3.5
15

 1b
 Automotive Exterior
CJT
CU3
        Flexible
                     Colorcoat
                     Clearcoat
                     Primer
4.6
4.3
5.4
4.3
3.8
5.0
4.1
3.5
4.5
68
 7
 3b
        Non-Flexible
                     Colorcoat
                     Clearcoat
                     Primer
4.6
4.3
5.0
4.3
3.8
4.5
4.1
3.5
3.5
79
10
 3"
 *   All units are in Ib VOC/gal. coating, less water, except for values in parentheses; the values in parentheses are percent solids, by volume.

 b   Telephone calls are being made to assess the availability of these coatings.

 M  What is the origin of these numbers?

-------
                                           TABLE 5-1.  CONTROL OPTIONS (LOW VOC COATINGS)'
                                                   Revised Using Rule 632 and Values fron Table 3-4
               Operation                                    Baseline VOC1                       Control Level 12                      Control Level
 1.      High Bake Coating - Exterior and Interior parts


        a.      Prime

                (i)     Flexible                                    6.6                                   5.0                                  4.5s
                (ii)     Non-Flexible                               6.4                                   4.0                                  3.56


        b.      Topcoat
tn
CO             (i)     Basecoat                                  5.85                                  4.6s"                                 4.35/s

-------
                                                  TABLE 5-1.  CONTROL OPTIONS (LOW VOC COATINGS)'
                                                         Revised Using Rule 632 and Values fron Table 3-4
                    Operation                                    Baseline VOC1                        Control Level 12                      Control Level 23



    2. Air-Dried Coating-Exterior Parts'1"31

            a.       Prime                                             6.14                                  6.1                                   4.8

            b.       Topcoat
                    (i)      Basecoat                                  5.84                                  5.8                                   5.0
                    (ii)     Red & Black Basecoat                      6.67                                 6.67                                 5.75
                    (iii)     Clearcoat                                  6.14                                  5.4                                   4.5
                    (iv)     Non-Basecoat/Clearcoat                    6.3                                  6.3                                   5.0
                    (v)     Red & Black Non-Basecoat/Clearcoat       7.25                                 7.25                                 5.75


W 3. Air-Dried Coating-Interior Parts                                6.8                                  6.3                                   5.0
C-0
GD


    4. Touch  Up and Repair'31                                        6.84                                  6.3                                   5.2
    5. Specialty Low Volume Coatings                                7.04/7                                 7.0                                  7.0
    1   VOC levels as given in Table 3-4 partially and what is missing, based on industry survey data to EPA.
    2   Control levels of VOC as given in Ml Rule 632, Table 65 effective after 12/31/89.
    3   Control levels of VOC as given in Ml Rule 632, Table 66 effective after 12/31/92.
    4   Not dealt with in Table 3-4 but based on industry survey data to EPA.
    5   Because of technical consideration, as documented to EPA by industry, red and black colors VOC limits should be set by applying a 1.15 factor to the VOC limits given in1
       Table
    6   VOC limits are for technology forcing products for which no Method 24 data is available and therefore are based on theoretical values. For baked coatings. Method 24 testing^
       gives consistently higher values in the range  of 0.4 to 0.5 Ibs/gal of VOC.
    7   Speciality coatings have unique properties that lower VOC versions can't deliver. However, they are used in low volume and can be restircted to less than 5% of the daily
       or monthly volume used.

-------
          JOE LENNON, FORD MOTOR COMPANY, REPRESENTING
             MOTOR VEHICLE MANUFACTURERS ASSOCIATION

Summary of Joe Lennon/s Presentation

     Mr. Lennon opened by stating that the Motor Vehicle
Manufacturers Association (MVMA) is in agreement with the
comments made by NPCA concerning the plastic parts CTG.
Mr. Lennon's comments address coating automotive plastic parts
only, and, generally speaking, MVMA supports the VOC control
levels in Michigan's Rule 632.

     Specifically, MVMA recommends that VOC control options be
developed for additional coating categories; the additional
categories needed are air dry coatings, and red and black
coatings.  MVMA and NPCA have submitted technical papers to EPA
describing the special needs of these coatings.

     The MVMA also objects to EPA's method of setting control
options based on lowest available VOC contents for each
individual coating category.  Coatings should be considered as
part of a coating system where the specifications of all the
coatings used together are considered.

     New VOC limits will require reformulation of coatings, which
in turn triggers a time consuming product approval process.  For
example, new coatings must be proven resistant to sun, salt, and
weathering.  The Michigan rule allows time for development and
approval of new coatings by phasing in controls over time in two
increments.  The options presented by EPA do not appear to leave
enough time for the approval process.

     Lower VOC coatings can compromise the finish appearance and
quality of coating.  Since U.S. car manufacturers must compete in
a world-wide market, lower VOC content requirements may affect
their ability to compete.  MVMA feels that the color and
appearance of the coating is a primary selling point for
automobiles.

     Coating durability is also affected by VOC levels.  If
reformulated coatings are not given adequate durability tests,
they may be released on the market prematurely.  Resulting
durability failures will cause the need for increased
refinishing, as well as increased warranty complaints.

     Regarding add-on controls, Mr. Lennon stated that
Michigan Rule 632 allows for VOC reduction without the use of



                             539

-------
VOC levels cannot be achieved through reformulation.  Mr. Lennon
continued that the Michigan rule deliberately avoids add-on
technologies because small coaters would be driven out of
business if add-ons become necessary.

     The MVMA also questions the capture and control efficiencies
(100 percent and 98 percent, respectively) used in the CTG model
facilities.  Mr. Lennon pointed out that in the CTG the cost
effectiveness figures for incineration exceed lowest achievable
emission rate (LAER) cost effectiveness figures.

     Mr. Lennon next addressed specialty coatings.  Specialty
coatings are generally high VOC, low usage coatings, and it is
not economical to reformulate them.  The MVMA recommends that EPA
either exempt specialty coatings or set higher VOC limits for
them.

     Finally, Mr. Lennon commented on four particular sections of
the draft CTG.  He disagreed with the transfer efficiency in
Table 3-4.  Based on limited testing on a bumper painting line
that used HVLP and electrostatic spray guns, MVMA feels that
32 percent transfer efficiency is more appropriate for HVLP guns
than the 50 percent figure used in the model plants.  He agreed
with the EPA presentation on transfer efficiency and said he was
pleased that EPA did not plan to recommend explicit quantitative
consideration of transfer efficiency.  In Section 5.1.1, the
emission points addressed are not adequate; MVMA feels that
building vents, water pits, and paint mixing areas also
contribute to emissions, so you cannot assume that all VOC is
emitted from the spray booth, flash-off area and bake oven.
Under Section 7.3.2, MVMA recommends that when plastic and metal
parts are coated together, the less restrictive VOC level should
apply.  In Section 7.8.3, the MVMA feels that quarterly or bi-
annual performance testing is unreasonable and too costly.
Performance tests should be limited to major breakdowns or
equipment replacement.
                             540

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   COMMENTS TO UNITED STATES
   ENVIRONMENTAL PROTECTION
AGENCY'S NATIONAL AIR POLLUTION
       CONTROL TECHNIQUES
       ADVISORY COMMITTEE
     REVIEW OF OCTOBER 1,1991
     DRAFT SURFACE COATING
    OF PLASTIC PARTS CONTROL
      TECHNIQUE GUIDELINE
       DURHAM, NORTH CAROLINA
           NOVEMBER 20,1991
         Motor Vehicle Manufacturers Association
            of the United States, Inc.
                541

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I.  INTRODUCTION
   • REPRESENTING MOTOR VEHICLE
    MANUFACTURERS ASSN. (MVMA)

   • SUPPORT OF COMMENTS BY NATIONAL
    PAINT & COATINGS ASSN. (NPCA)

   • MICHIGAN RULE 632 - MODEL

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II. CTG SUBJECTS OF CONCERN
   • COATING CATEGORIES



   • COMPATIBLE PAINT SYSTEMS



   • APPROVAL PROCESS TIMING



   • QUALITY APPEARANCE



   • DURABILITY OF COATINGS



   • WARRANTY CONSIDERATIONS



   • RACT ADD-ON CONTROL



   • SPECIALTY COATINGS
               543

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III. CATEGORIES OF COATINGS
    • ADDITIONAL CATEGORIES NEEDED

    • RULE 632 STUDIES

    • CTG CATEGORIES NEEDED

      - AIR DRY COATINGS

      - RED & BLACK COLORS

      - MVMA/NPCA TECHNICAL
        SUBMISSIONS
               544

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IV.  COMPATIBLE PAINT SYSTEMS
    • TECHNOLOGY LIMITATIONS/
      LOWEST VOC

    • COMPATIBILITY NEEDS FOR
      APPEARANCE AND PERFORMANCE

    • RACT CONTROL - REASONABLE
      VOC REFORMULATION
               545

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V. APPROVAL PROCESS TIMING
   • EXTENSIVE AND TIME-CONSUMING

   • COATING SUPPLIERS - CURRENT
     RESEARCH AND DEVELOPMENT

   • IMPACT OF TABLE 5-1 LEVEL 1
     CONTROL

   • AVAILABILITY OF APPROVED
     COATINGS
              546

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VL QUALITY APPEARANCE


    • WORLDWIDE COMPETITION

    • IMPORTANCE OF FINISH
      APPEARANCE AND QUALITY

    • CUSTOMER EXPECTATIONS

    • TABLE 5-1 LEVEL 1VOC CONTENT
      MAY IMPACT QUALITY
               547

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VII.  DURABILITY OF COATINGS
     •  AUTOMOBILE COATINGS MUST
       LAST IN THE ELEMENTS FOR AT
       LEAST 7-10 YEARS.

     •  PLASTIC AND METAL COMPONENTS
       MUST MATCH.

     •  PREMATURE DURABILITY FAILURES
       WILL CAUSE REPAINTING - IMPACT
       VOC EMISSIONS.

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VIII.  WARRANTY CONSIDERATIONS
      • CUSTOMER LOYALTY

      • FINANCIAL CONCERNS

      • REFORMULATION MAY ADVERSELY
       IMPACT WARRANTY AND TIMING
                549

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IX.  RACT ADD-ON CONTROLS
    • RULE 632 STRATEGY/NO ADD-ON
      CONTROLS

    • SMALL BUSINESSES INVOLVED

    • DRAFT CTG VALUES IN TABLE 5-1
      LEVEL I MAY FORCE ADD-ON
      CONTROLS

    • EXCESSIVE COST OF ADD-ON
      CONTROLS

    • RULE 632 REQUIRES ADVANCED
      APPLICATION EQUIPMENT

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X.  SPECIALTY COATINGS
    • UNIQUE REQUIREMENTS

    • HIGHER VOC CONTENT/LOWER
     VOLUME

    • REFORMULATION LIMITATIONS

    • EXEMPTION OR HIGHER VOC
     LIMITS

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XI. ADDITIONAL COMMENTS
    • TABLE 3-4 TRANSFER EFFICIENCY

      - HIGH VOLUME LOW PRESSURE (HVLP)

      - ELECTROSTATIC

    • SECTION 5.1.1 EMISSION POINTS

      - MISCELLANEOUS VOC EMISSIONS

      - VOC CAPTURE LIMITATIONS

    • SECTION 7.3.2 METAL/PLASTIC PARTS

      - LEAST RESTRICTIVE VOC LEVEL
        SHOULD APPLY

    • SECTION 7.8.3 PERFORMANCE TESTS

      - QUARTERLY OR BI-ANNUAL
        REQUIREMENT IS UNREASONABLE,
        IMPRACTICAL AND COSTLY

      - SHOULD BE LIMITED TO MAJOR
        BREAKDOWNS OR EQUIPMENT
        REPLACEMENT
                rrrro
                •-J- v> fcJ

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                     STEVE KISH, GRACO, INC.

Summary of Steve Kish/s Presentation

     Mr. Kish represents Graco, Inc., a manufacturer of spray
equipment.  Mr. Kish stated that the CTG assumed a transfer
efficiency of 50 percent for electrostatic spray guns and HVLP
guns, and 25 percent for air spray guns.  He showed Graco test
data which measured the transfer efficiency of electrostatic guns
at 50 percent to 90 percent, HVLP guns at 28 percent to
50 percent, and air guns at 25 percent to 40 percent.  In each
case, the highest transfer efficiency was achieved at the lowest
coating flow rate (3 oz./min), and the lowest transfer efficiency
occurred at the highest coating flow rate (12 oz./min.).  He went
on to say that the pay back period for HVLP was 6 to 13 days, and
for electrostatics it was 6 to 28 days.

     Mr. Kish presented the savings potential for a large plastic
parts coating plant using both HVLP and electrostatics, using air
spray as a baseline.  With HVLP, a 20 percent savings could be
realized on coating.  The assumption of this estimate is that the
number of sprayers is held constant.  It was stated that minimal
training was required for an operator to switch from an air spray
to HVLP.  The limitation of HVLP systems is a throughput of 11 to
12 ounces of coating per minute.  The HVLP gun was assumed to
cost $400, and paint cost was estimated at $40/gallon.

     When using electrostatic guns instead of air spray guns, a
42 percent to 50 percent savings could be achieved based on the
same number of guns in use.  If the number of guns used is
reduced, the savings is reduced to 20 percent to 25 percent.
There are significant cost considerations which are not included
in this scenario.  The first is increased primer coating cost due
to the need to use a conductive primer coat.  The second is the
cost of operator training.  Last, the electrostatic guns require
more maintenance than air spray, about $50 to $70 per gun.  The
capital cost of the electrostatic gun is assumed to be $4000, and
paint cost is $40 per gallon as with HVLP.

     Mr. Kish concluded by stating that both HVLP and
electrostatic application are cost effective and serve to reduce
VOC emissions.
                             553

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        Comments & Observations Of
    Plastic Parts Coating CTG Document
 in the "Automotive/Transportation Facilities"
en
                                 GRACO INC.
GRAC01991                             MINNEAPOLIS, MN

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    What CTG Says About I.E. in Various Operations
tn
en
                      T
                      R
                      A
                      N
                      5
                      F
                      E
                      R

                      E
                      F
                      F
50
35

30
 •
25

20.
15

I0.
 5

 0
                               Electrostatic
50%
25%
3 oz/mln 4.2 oz/mln
HVLP
Airspray
i i .
8.25 oz/mln 11. 4 oz/mln
                           »Alrspray  a HVLP  »Electrostatic
                    Assumes 50% transfer efficiency for electrostatic application
                    Assumes 50% transfer efficiency for HVLP application
                    Assumes 25% transfer efficiency for airspray application
GRACO1991
                    Plastic "automotive/transportation" flowrates based on .70 service factor

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      What Grace's Test Experience Shows About  T.E
                       T
                       R
                       A
                       N
                       S
                       F
                       E
                       R
                                90%
                                 3 oz/min
4.2 oz/min    8.25 oz/min
                              Airspray   HVLP   Electrostatic
                50%
                    Electrostatic
                                                             HVLP
                                                         25%  Airsorav
                                                         11.4 oz/min
                    Shows range of 50-90% transfer efficiency for electrostatic application
                    Shows range of 28-65% transfer efficiency for HVLP application
                    Shows range of 25-50% transfer efficiency for airspray application
                     Plastic "automotive/transportation" flowrates based on .70 service factor
GRACO 1991

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               0
               F
               D
               A
               Y
               S
                      Payback Period in Days at
                     CTG Theoretical Flowrates
26.0_
23.4
20.8_
18.2_
15.6_
I3.0_
10.4
 7.8_
 5.2_
 2.6_
 0.0
                             26 days
                                     J8.6 days
                Electrostatic
HVLP
                                                 4.7 days
                                6.8 days
                                                            5.6 days
                          3 oz/min     42 oz/min
                      « HVLP  a Electrostatic
                         8.25 oz/min
                            I 1.4 oz/min
                   Airspray transfer efficiency is baseline
                   Based on 16-hour production day with $40/gallon paint cost
                   HVLP initial cost est. $410
                   Electrostatic initial cost est. $4000
GRACO 1991

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               s
               A
               V
               I
               N
               G
               S

               P
               E
               R

               D
               A
               Y
                      Payback Period in Dollars
                    at CTG Theoretical Flowrates
440_

396_

352_

308_

264

220
  •

176_

132.

 88

 44
  •

 0
                      $433
         $220
$157.50
            $100
            ft- _
$87
                          3 oz/min     4.2 oz/min
                      o HVLP  n Electrostatic
                        8.25 oz/min
        Electrostatic
         -CJ
         $410
                                 HVLP
         $72
                               .4 oz/min
                   Airspray transfer efficiency is baseline
                   Based on 16-hour production day with $40/gallon paint cost
                   HVLP initial cost estimate $410
                   Electrostatic initial cost estimate $4000
GRACO 1991

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     Under CTG Enactment Using HVLP...


 A Large Plastic "Automotive/Transportation Facility"
              Could Realize the Following:


        • 20 % savings on paint

        • Retention of all spray stations

        • Minimal adjustment costs associated with
          operator training

        • Restricted ability to change coatings to higher
          solids or rheology (gun's ability at threshhold
          at current 11-12 oz/min)
GRACO1991

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 Under CTG Enactment Using Electrostatic..,
 A Large Plastic " Automotive/Transportation Facility"
               Could Realize the Following:
           42-50% savings on paint when retaining all spray stations
           20-25% savings on paint when retaining half of existing
           spray stations
           Significant adjustment costs resulting from:
             Conductive primer or spray supports
             Operator orientation and training
             Increased maintenance costs of $50-80/month/gun
GRACO 1991

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         For Further Documentation
         GRACO INC.
         P.O. BOX 1441
         MINNEAPOLIS, MN 55440-1441
                 Thank You
GRACO 1991

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               JOHN L. WILLIAMS, MOBAY CORPORATION

Summary of Presentation of John L. Williams

     Mobay is the leading supplier of polyurethane raw materials.
This includes aliphatic polyisocyanate resins for polyurethane
coatings.  It is wholly owned by Bayer/AG of Germany.  As of
January 1, 1992, it will be known in the U. S. as Miles, Inc.

     Mr. Williams stated that two-component flexible polyurethane
coatings are the standard for the European automotive industry
and have 25 percent of the U.S. market for exterior plastic
automotive parts.

     Mr. Williams stated that he felt the coatings now meeting
the level of 2.3 Ib VOC/gal for business machines compromise
performance.  VOC levels of 2.8 Ib VOC/gal solvent-based are
currently achievable with two-component polyurethane coatings. He
said that Mobay (Miles) has technology to potentially meet VOC
levels of 1.0 to 1.5 Ib VOC/gal within one to two years with two
component waterborne polyurethane coatings.  He said this
technology has not yet been tested in a large scale application
and may be limited by industry acceptance.

     One concern noted earlier at this meeting was the potential
for health risks from polyurethane coatings.  He stated that
these types of coatings are the standard in Europe (25 percent of
U.S. market), and that they pose no major health hazard with
proper handling.  Mr. Williams offered to supply health and
safety information on polyurethane coatings.

     In the area of automotive/transportation coatings, Mobay is
developing two component polyisocyanate coatings for exterior
clearcoat.  The expected VOC levels for these developmental
coatings are 2.5 to 2.8 Ib VOC/gal.  Mobay is also developing a
2.8 waterborne primer.  Current limitations of these coatings are
that they are not yet Toxic Substance Control Act (TSCA) listed.
They have applied for listing and expect them to be available for
sale by the 3rd or 4th quarter of 1992.  Development of large
scale production capacity for these coatings requires a large
capital outlay that Mobay is prepared to make.  Mobay supports
the development of lower VOC coatings, but these new coatings
must be performance and economically driven products.  Mr.
Williams stressed the need for cooperation between raw material
suppliers, paint manufacturers, coaters and EPA.

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      Mobay's Role in  Coatings for Plastics  Mobay
            •  Mobay is the leading North American Supplier of Aliphatic
              Polyisocyanate resins for use in polyurethane coatings
            •  Mobay sells resins to manufacturers of coatings for plastics
            •  Mobay seeks to act as a technical partner to the plastics
^             coatings industry
               U. S. Environmental Protection Agency, November 19-21,1991

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CD
      Mobcay Supports                                 M°bay
               The need for continued cooperation by the EPA with
               coatings raw materials suppliers, coatings
               manufacturers, and rofintsh coatings users in allowing
               VOC compliant products to be optimized
               Lower VOC coatings to earn market acceptance on
               product merit and economic benefit
               U. S. Environmental Protection Agency, November 19-21,1991

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Current Status of Polyurethane          Mobay
^^^    ^K     ^_        ^^     ^m     ^_ ^^              i'.vV'.V'V.'.V.M.V.V.Sv.v-SV.V.
Coatings for Business Machines
    Currently Available Technology          VOC (Ibs/gal)
    Primers                              2.8
    Colorcoats                            2.8
    Clearcoats                            2.8

    Systems can be improved by resin development
    and formulation changes to lower VOC levels
    and to optimize performance
        U. S. Environmental Protection Agency, November 19-21,1991

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Future  Developments for PU
Coatings for Business Machines

    VOC reductions possible with waterborne 2K
    polyurethane primers, color and clearcoats
                                           Mobay
Potential Benefits
•  Reduced VOC color .and
   clearcoats
   (1.5-1.0 pounds/gallon VOC)
•  Reduced VOC water-borne
   primer
   (1.5-1.0 pounds/gallon VOC)
                    Present Limitations
                    •  No large scale production at this
                       point
                    •  Reasonable currently commercially
                       available technology in 1-2 years
                    •  Technology would require
                    •  Cooperative development with and
                       the approval of coatings
                       manufacturer
                    •  Acceptance of business machine
                       coating users

IL S. Environmental Protection Agency, November 19-21,1991

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Future  Developments for                   Mobay
PU  Coatings for Automotive Plastics    ~

  Further VOC Reductions Possible with Higher Solids
  Two Component Polyurethane Topcoats and
  Waterborne Primers
Potential Benefits

•  Reduced VOC 2K clearcoat
   and pigmented topcoat
   systems
   (2.5-2.8 Ibs/gal VOC)

•  Reduced VOC waterborne
   primer systems
   (2.8 Ibs/gal VOC)
Present Limitations:

•  All resins used in the system are not
   TSCA listed

•  All resins do not have large-scale
   manufacturing capacity established

•  Technology would require:

  • Cooperative development
  • The acceptance of the plastics coatings users
    with/and the approval of manufacturers of
    coatings
        U. S. Environmental Protection Agency, November 19-21,1991

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tn
£73
     Mobay Supports                           Mobav
          The future development of lower VOC
          polyurethane coatings systems for
          plastics in cooperation with coatings
          manufacturers, coatings users, and
          the Environmental Protection Agency
             U. S. Environmental Protection Agency, November 19-21,1991

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               DISCUSSION ON PLASTIC PARTS COATING

QUESTIONS AND COMMENTS FROM THE COMMITTEE ON EPA PRESENTATION

     Question:  Are aerospace plastic parts covered under this
CTG?  The question has come up in California whether the plastic
parts CTG or the aerospace CTG will cover these parts.

     Answer:  We do not know yet.  We discussed this some with
the aerospace industry at a meeting in March or April.  The EPA
will be meeting with representatives from the aerospace industry
next week.  Some aerospace parts, for example seat backs and tray
tables, that are most likely coated outside of the facility may
be best covered by this CTG.  Other parts that are most likely
coated at aerospace facilities, especially those that are coated
as part of a larger assembly or complete aircraft, may be best to
cover in the aerospace CTG.

     Comment:  There is a discrepancy between the cost
effectiveness figures for incineration reported for the model
plant analyses on slides 9 and 12 and for the national impacts
reported on slide 13.

     Answer:  Yes, the national impact cost effectiveness figures
should read $22,000 for automotive, $21,000 for business
machines/miscellaneous, and $22,000 for the total.  We plan to
look at options for reducing air volume and increasing VOC
concentration to bring these costs down.

     Question:  Do you propose that the coater or the coating
manufacturer perform Method 24 tests for VOC content?

     Answer:  We have tried systems where the manufacturer
provides Method 24 test information for each batch of coating so
that the coater does not have to do the testing.  The coater uses
the manufacturer's test results and adds in any dilution solvent
added to the coatings.  We expect to recommend this system in
this CTG.  It is more economical for the coating manufacturer to
run one test on a batch of coating than for many coaters to have
to test coating from the same production batch.

     Question:  Do your emissions estimates include any emissions
prior to spraying?

     Answer:  No, our estimates begin with spraying.  We do not
include emissions from paint mixing.
                             •J *_*

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     Question:  Did your evaluation include alternatives such as
dipping or molded-in color?

     Answer:  We tried to show in the CTG that there are
alternatives such as dipping and molded-in color, but we are
reluctant to tell the industry to dip rather than spray.  The
appearance of dip coated parts is not the same as spray coated
parts.  Some plastic parts do have molded in color.  Coatings,
however, enhance the performance of many plastic parts by
improving color, gloss, chemical resistance, scratch resistance
and ultra-violet resistance.

     Comment:  Considerable VOC emissions occur during gun
cleaning.  Consideration should be give to these emissions.

     Answer:  More will be said about this subject during the
auto refinishing presentation.  We will listen in and see if
there is something we can apply in this CTG.

     Comment:  Consideration should be given to controlling
different types of booths or subsets of booths.

     Answer:  We will consider doing so.  There are examples
today of facilities where automated booths are controlled and
manual booths are not controlled.

     Question:  You have estimated about 40,000 tpy VOC emissions
from plastic parts coating.  Is this large or small relative to
other sources in non-attainment ares?  It sounds large.

     Answer:  In most areas there are many small pieces of the
VOC pie, not a single large piece that accounts for the majority
of emissions.  There are some large plastic parts coating
facilities, but as a percentage of total VOC emissions in a
single non-attainment area they are probably not very large.

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Questions and Comments from the Committee on Naomi Suss'
Presentation

     Question (Committee):  There is a large discrepancy between
the estimated VOC emissions from EPA and NPCA.  Can you explain
the reason?

     Answer (NPCA):  The NPCA surveyed its members and obtained
Method 24 data and quality control data; these values were then
multiplied by the amount of coating actually sold.  We don't know
how to account for the differences; either party could have made
an error.

     Question (Committee):  Is the flexibility afforded by the
Method 24 0.5 pound scaling factor in Michigan's rule still
needed, or can it be eliminated because of knowledge of coatings
currently on the market?

     Answer (NPCA):  These factors were needed when Rule 632 was
developed because the rule was technology forcing.  Coatings that
met the emission limits were not available.  There are some
coatings available now, but the scaling factor should not be
eliminated yet since there are still applications where it is
required.

     Question (Committee):  A half-pound of VOC per gallon of
coating seems like a lot.

     Answer (NPCA):  Let me give you an example of why a half-
pound is appropriate.  The typical coating used for automotive
plastics is a melamine-polyol type cross linking mechanism.
These release by-products, such as methanol and butanol, via a
condensation reaction that can vary from batch-to-batch.  These
VOCs are not part of the original coating formulation.  They
cannot be calculated until you have substantial production
history for the coating to tie the value down.

     Question (EPA):  Then why not just set higher standards for
these combinations?

     Answer (NPCA):  That is an option.

     Question (Committee):  How does choosing to disperse
pigments in resins rather than in solvents affect the VOC
content?

     Answer (NPCA):  Most pigments are dispersed in resins; but
at higher solids contents, solvent may be required to minimize
agglomeration.  A point of diminishing returns is reached.

     Comment (NPCA):  Red coatings can cost two or three times as
much as other coatings and may reach $120 per gallon.  Coaters
require more of these coatings to cover their parts.  Industry
supplies such coatings because they are in dejnan4,
                              .J C

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     Question (EPA):   Were the sales figures just for Michigan?

     Answer (NPCA):   No,  the  figures were for North America,
including those members  in Canada.
                              572

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Questions and Comment from the Committee on Joe Lennon's
Presentation

     Question:  What is the technical reason for using the less
restrictive VOC level when plastic/metal combinations are coated.

     Answer:  There are relatively few situations where this
occurs, and the industry needs flexibility to deal with them.
The Michigan rule may instruct you to categorize parts as metal
or plastic by the predominant type of material.

     Question:  Industry spokespersons have stated that there are
obstacles to either reformulation or using add-on controls;
however, there is a health problem to be addressed.  How should
it be addressed?

     Answer (Naomi Suss, NPCA):  The industry has the same health
and safety concerns.  The automobile industry has worked very
hard to reduce emissions and has had many successes.  The plastic
parts coating industry is pursuing reformulation solutions.
Progress has been made.  For instance, there has been an increase
in weight solids content of 250 percent over the past 10 years;
40 percent of automotive interior coatings VOC level will be down
to 2.5 Ibs VOC per gallon of coating or less by next year.
Powder coatings are being investigated.  One use of powder
coatings is on an SMC grille opening panel for Chrysler vehicles.
Waterborne coatings are being introduced for color coats, one
color at a time to match with vehicle bodies coated with
waterborne basecoat.  Also, two component isocyanate coatings are
being evaluated, but there are health concerns and concerns about
the ease of handling these coatings in production situations.

     Answer (Joe Lennon):  Ford will be using waterborne coatings
for all interior parts at one of its plants, but we still are not
able to meet the Michigan Rule 632 levels at another plant.  We
have a contingency plan to install add-on controls at that
facility-

     Question:  Would alternative curing processes, such as UV
curing, provide a solution?

     Answer (Naomi Suss, NPCA):  UV curing does not show good
performance with high solids coatings; so far for automotive
applications it is better with low solids coatings.

     Question:  What emission reductions do you expect from
Rule 632?

     Answer:  15 percent by 1992, and 25 percent by 1995.

     Comment (Committee):  25 percent is good, but we are looking
for 75 percent reduction.  Perhaps we need to look at add-ons.

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     Question:  What are other countries doing about coating VOC
emissions from plastic parts?

     Answer (Naomi Suss):  Nothing.   They still use low solid
lacquer colorcoats, and about 30 percent solids for their
clearcoats.  Germany is the only other country showing concern;
they are using some waterborne coatings.

     Question:  Would you support an equipment requirement for
transfer efficiency (TE)?

     Answer (Naomi Suss):  There are currently not many plants
that use only conventional spray due to cost incentives of using
higher efficiency guns.  Electrostatic spray and HVLP are
commonly used.  Air-assisted airless is used for some interior
parts, but rarely for exterior parts.  Color matching on the
third coat for metallic colors and,  touch-up of nicks and
scratches occurring during assembly requires the use of air
atomized (conventional) spray.  An equipment requirement would be
acceptable if it allowed for these necessary uses of conventional
spray equipment.

     Comment (Committee):  EPA may need to consider providing
specific guidance on specialty coatings to avoid problems with
implementation at the State level.

     Comment (Committee):  There are so many different types of
parts whose quality may be impacted.  It would help if the
industry could give EPA information on which parts can meet the
control options and which cannot, and a timetable for new
coatings.

     Comment (Naomi Suss):  I have thought of one reason why our
estimate and EPA's estimate of coating usage may differ.  Our
estimate did not include coatings used on plastic parts that are
coated in assembly plants such as SMC hoods, fenders and grille
opening panels.  These coatings are covered by other regulations.
We only included data on coatings used outside of assembly
plants.
                             £74

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Questions and Comments from the Committee on Steve Kish's
Presentation

     Question (Committee):  Can 90 percent transfer efficiency be
achieved with electrostatics?

     Answer:  Yes, theoretically.  That transfer efficiency
(90 percent) was achieved at a paint flow rate of 3 oz./min.
This is not a practical flow rate in a large plant.  A more
typical flow rate is about 15oz./min.  The transfer efficiency at
this flow rate would be about 50 percent for electrostatic spray,
30 percent for HVLP and 25 percent for air spray.

     Question (Committee):  This looks good.  Why aren't
electrostatic guns used?

     Answer:  They are in use in many plants, especially for
automotive plastics.

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Questions and Comments from the Committee on John L. Williams'
Presentation

     Question (Dave Salman):  Do the stated VOC contents for the
waterborne coatings exclude water?

     Answer:  Yes

     Question (Dave Salman):  What kinds of basecoats can be used
with these new two-component automotive clearcoats?

     Answer:  We are not working on developing basecoats, but
these clearcoats are intended for use with both solvent-borne and
waterborne basecoats.  More cooperative development work still
needs to be done to prove compatability with specific basecoats.

     Question (Committee):  Would you recommend a regulation
based on the VOC contents that you have presented?

     Answer:  We would recommend a level of 2.8 Ib VOC/gal for
Business Machine/Miscellaneous.  For automotive coatings, we
can't say that we definitely can reach the levels in
Michigan Rule 632 or the draft CTG, but we are working towards
them.

     Question (Bruce Jordan):  Are the CTG numbers too high?

     Answer:  I decline to say that they are too high, but that
is the inference.

     Question (Bruce Jordan):  What do you think should determine
the VOC content limits?

     Answer:  Performance and economics should drive the
industry.  The U.S. needs to stay competitive in the world
market.  I believe that the technology will soon be available to
meet lower VOC levels and it will be polyurethane technology.

     Question (Bruce Jordan):  What will it take to push industry
toward compliant technology?

     Answer:   EPA is forcing the technology, but a cooperative
effort must be made so that performance is maintained.

     Question (Bruce Jordan):  What is required of EPA to get the
cooperation required?

     Answer:  EPA, manufacturers, coaters, and suppliers must all
work together.  The market is performance and economics driven.
VOC reduction and performance can go together.
                             576

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        Navistar International       6125 Urbana Road                          L.\ J-
        Transportation Corp.        p o Box 600
                           Springfield. OH 45501
                           513 390 2800
U.S. Environmental  Protection ftgencv
Office  of Air Qualit^ Planning and Standards
Research frianale  Park, North Carolina   27711
 INTERNATIONAL

November 14. 1991


Bruce  Jordan. Director Emission Standards Division

SUBJECT: Plastic  Parts Coating Draft  CTG

     Navistar International  Transportation  Corp. is a manufacturer
of  transportation equipment.   Two  facilities  would  appear  to be
potentially affected by  the  proposed  CTG.  The  first manufactures
mold compound (SMC)  components for trucks and  small boats,  applying
primer and conductive coatings to the truck  components only.   The
second  facility  is  a  truck  assembly  plant  which  uses  repair
primers, acrylic  enamels withnut  clearcoat,  acrylic  enamels  with
clearcoat, and  aftermarket  repair coatings.  Navistar appreciates
the  opportunity to  provide  comments  and questions for  the  Draft
CTG.

      In Section 3.1  and other sections  throughout the  CTG,  does
"other mobilized  eguipment"  include  fiberglass  boat hulls'?

     Section 4.4  states that  no  plastic coating  operations  have
paint   spray booth  controls.    The  Navistar  assembly   plant  in
Springfield, Ohio,  utilizes  VOC controls on  two  paint lines which
coat  both  miscellaneous metal  parts  and plastic  parts  using  the
same coatings.

     Section 5.1.1 at the top of p. 5-2   States  that coatings never
leave  the spray booth.   However,  this  does not  account for paint
particles  and   soluble   solvents  entrained  in   the  water  of  a
waterwash booth which has a  remote sludge handling system.   Later
in  the  document  this  is  acknowledged  on  p.   5-9  in  the  first
paragraph.

     Table  5-2    Control   levels  should  permit  in—line  volume
weighted averaging of  allowables when  more than one type of coating
is applied in the  operation  (i.e.  BC/CC).  Thus,  if a source uses
a  clearcoat  with  a  VOC  content   less  than  the  RACT  limit  and  a
basecoat with  a VOC  content  in  excess  of  the  RACT  limit  a daily
volume  weighted  average would  be  used  to  determine  the  RACT
allowable.  A similar provision  is found  in the federal model rule

     NAVtSTAR                    r^rj
                                •J, i, I

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for can coating when sides, ends, etc. are  coated  in  the same line.

     Section   7.3.2   has  an   inconsistent   overlap   with   the
miscellaneous  metal  parts coating CTG and  SIPs.   Proposed  control
levels and  baselines for  plastics  indicate color coatings  with a
higher VOC content than clear coatings, but the miscellaneous metal
parts rules permit a greater  VOC content for clearcoats and a much
lower  VOC  content  for  colored material.    Navistar  finds  the
baseline  VOC  content  for basecoats  closer to the  norm than  the
miscellaneous  metal  parts rules.

     For  operations coatina  both  plastic and metal  in the  same
operation,  EPA should  allow  the least  restrictive  condition  for
clear and  for  color coatings  to apply for both  metal  and  plastic
parts.  EPA should not  reguire separate record  keeping  for guantity
of  paint  applied to metal and  plastic  or the respective  surface
areas  coated.    In  addition,  EPA must  address  the  miscellaneous
metal  parts provisions  which   exempt  the  coating  operations  of
custom vehicles if  production   is less  than 35  vehicles per  day-
Many  of  Navistar s   competitors  use  this  provision to  avoid
regulation  of  their  miscellaneous metal  parts  coating  operations,
including  two  in  the state of Ohio.

     Section 7.6.1  discusses transfer efficiency-   If  a transfer
efficiency  is  included  in the  RACV  determination,  then EPA  must
also  consider  how  this  affects the  miscellaneous  metal  parts
painted in  the  same  operation.

     Section 7.7.2 does not recognize Method 25A  but then in 7.7.3
calls  for  continuous  emissions monitoring   which  yield   "actual
emission" measurements.  Presumably this  would  be  an  FID calibrated
to propane  measuring a blend  of solvents,  like method  25A.

     The   proposed   testing  freguencies  in   Section   7.8.3  are
unreasonable when  reguired more f^eguently  than  annually.


Sincere 1y,
Tim W. McDaniel,  CIH
Environmental  Manager

.cc  E. Ardlen te
     M . Cu1 pepper
                               r >--/

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                                                    /
          ELECTROSTATIC CONSULTANTS CO,
                     ENGINEERING & MANUFACTURING
            P.O. BOX 1587 / LISLE, ILLINOIS 60532 / PHONE (708) 668-5027
                               November 15, 1991

U.S.EPA
Office of Air Quality
Planning and Standards
Research Triangle  Park, NC 27711
Attn:  Bruce C.  Jordan, Dir.
      Emission  Standards Div-

Dear  Mr. Jordan,
      I received  your notice of the next meeting of  NAPCTAC and
the draft of the CTG on surface coating  of plastic parts. Section
3.3.2 on application coating equipment  falls far short of the needs
of the coating industry and I would like to explain the shortcomings
of the listed spray equipment.

CONVENTIONAL AIR SPRAY

      This class  of guns has been the  standard of the industry for
the past 100 years but has been the primary cause of  air pollution
in the spray painting industry.  The transfer efficiency (T.E.) is
very  poor. This  class of guns should be  retired as quickly as pos-
sible.  This, of course, is already being done.

AIRLESS SPRAY

      Airless spray equipment combines  "engineering  extremes" that
can cause too many production problems.  Extreme pressures are com-
bined with extremely small paint orifices.  It wastes paint by
building excessive film thickness.  This does little  to reduce VOCs.

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                                 [2]
It also lowers quality of finish and falls far short of the flexi-
bility of air guns. The gun was developed to improve on the low
efficiency of air atomizing guns but it failed to replace the con-
ventional air atomizing guns.

AIR-ASSISTED AIRLESS SPRAY

       This is a variation of the airless gun and was designed to
improve the atomization of the airless gun.   By improving the atom-
ization, smaller spray particles are produced and this lowers T.E.
compared to the airless gun.  The quality of finish is still sub-
stantially less than that of a conventional  air spray gun and it
cannot be expected to replace conventional air guns when a high
quality of finish is essential. This gun does not offer a solution
to high VOC emissions since the atomization  is still relatively
poor and the larger spray particles tend to  waste paint by building
excessive film thickness.

HIGH VOLUME LOW PRESSURE SPRAY

       The hype generated with the HVLP spray gun seriously over-
states it's value to the spray painting industry. The definition
of an HVLP gun is not adequate to assure an  improvement in T.E.
and a reduction in VOCs.  Variables that must be pinned down to in-
sure an improvement in T.E. are as follows:

       1.   Atomizing air pressure, the only  current requirement of
an HVLP gun.  (10 PSI or less).
       2.   Viscosity of coating material
       3.   Paint flow-rate  (production speed)
       4.   Range of spray particle size at a given air pressure
       5.   Air volume
       6.   Spray velocity
       7.   Film thickness

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                                 [3]
       Most of the variables indicated above will cause an increase
in VOC emissions if they are adjusted in the wrong direction. An
increase in air volume also increases spray velocity but this lowers
I.E. and increases VOC emissions. Obviously, the definition that
calls for high volume (HV) in HVLP is wrong.
       A switch-over to an environmental coating is needed to re-
duce solvent in the coating but this also increases it's viscosity
and makes the material more difficult to atomize. Larger spray par-
ticles are produced and while this may improve I.E., there is a
corresponding increase in film thickness that causes an increase in
paint consumption, an increase in VOCs and a lowering of quality.
Under these conditions, the HVLP gun becomes unacceptable. It fails
to do the job intended.
       A reduction in paint flow-rate is in the right direction if
it is combined with a corresponding increase in I.E. and may be
self-defeating. It also has the effect of reducing production speed
and greatly increasing operating costs.   Once  more, an HVLP gun
may become unacceptable to the end user.  Most HVLP guns on the
market are currently criticized by the end user for lowering quality
and cutting production speed. While many thousands of HVLP guns
have been sold, they have done very little to reduce VOCs.  Placing
the emphasis on atomizing air pressure totally overlooks the many
other important variables.
       Our CFA 740 hand gun is the only  so-called HVLP gun that
controls all variables and actually achieves the end result of
lowering VOCs.  It is the only new invention in air atomization that
has appeared on the scene in the last century. Unfortunately, it
has a lot of unqualified competition that muddies the water and
obscures it's merits. Our CFA 740 hand gun uses an entirely differ-
ent form of air atomization that uses the energy available in com-
pressed air far more efficiently than any other air atomizing spray
gun.  It is entitled to a separate and distinct classification. It
is not a conventional air, airless, air-assisted airless or an HVLP
gun with multiple air jets.  The average HVLP gun is equivalent
                            581

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                                 [4]
to a downgrade of a conventional air gun.
       Our CFA 740 hand gun is the best RACT available for non-
electrostatic hand guns.  It holds the quality and production speed
of a conventional air gun while greatly improving I.E. and reducing
VOC emissions. It will fully atomize the higher viscosity environ-
mental coatings while staying under the 10 PSI atomizing air pres-
sure specified for HVLP guns.  This is the result of a major change
in the mechanics of air atomization. The multiple air jets of a
conventional air atomizer and HVLP atomizers are replaced with a
single, converging annular air orifice and a diverging conical sur-
face that converts the round stream of paint into a thin film prior
to atomization. This concept is known as "Conical Film Atomization"
and achieves equivalent atomization with a fraction of the energy
required with other atomizers.  The CFA 740 hand gun is low in cost
and is interchangeable with all conventional air guns in use in the
country.  Enclosed is a "House Painting Report" that shows the CFA
740 hand gun approaching very close to 100% T.E.  As quality stan-
dards are increased and the product size is reduced, the T.E. will
drop somewhat.  It achieved 65.5% T.E. on 8" x 11" panels in tests
conducted by the SCAQMD.  The 65.5% T.E. still represents a 62%
paint savings and VOC reduction compared to a 25% T.E. conventional
air gun. Since the gun will also spray higher viscosity, higher
solids paint, it can achieve over 90% reduction in VOCs without
requiring the need for very expensive add-on controls.

ELECTROSTATIC SPRAY

       Electrostatic spray has not been used extensively in coating
plastic parts. The first electrostatic system to apply waterborne
coatings on plastic shutters is discussed in the enclosed reprint
from the November 1982 issue of Industrial Finishing Magazine. It
explains our proprietary, patented process for applying waterborne
coatings on non-conductive or semi-conductive substrates. We never
received permission for publishing the actual production photos
because the shutters were a proprietary product manufactured  for
others.
                             502

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                                 [5]
       Photo #1 enclosed shows the first production operation.
Seven different colors are applied on this line. The shutters are
painted 100% automatically and do not require manual touch-up.
       Photo #2 enclosed shows the shutters passing through a
baking oven for four minutes at 170°F.  You will notice the warping
of the shutters. They straighten out once more when cooled to room
temperature.  A higher baking temperature would destroy the shutters
by making the warp permanent.
       Photo #3 enclosed shows the isolated paint pressure tank
that is charged to high voltage because of the electrical feedback
from the charged guns. On new installations designed from scratch,
it is possible to operate with the paint source at ground potential.
       An entire fiber drum of paint fits inside the pressure tank.
It is lifted out and replaced with a drum of paint of another color
when changing colors.
       The system can paint 7'0" high shutters at a conveyor speed
of 15 FPM.  The shutters are placed back-to-back about three minutes
after leaving the baking oven and covered with clear, heat shrink
plastic. They are then placed in cartons for shipment.
       Photo #4 enclosed shows the Auto-Static 400 gun that is used
to paint shutters.  Mounted below the gun is a remote control fluid
pressure regulator that is used to control the paint flow-rate.
This gun also uses the improved "Conical Film Atomization" that was
put on the CFA 740 non-electrostatic hand gun at a later date. This
gun will easily apply  high viscosity waterborne coatings. The
amount of water used in the paint is kept low and the viscosity
high. This permits building the desired film thickness without runs
and sags.  The system when operated with high viscosity waterborne
paint is not sensitive to broad changes in relative humidity and
avoids the high cost of air conditioning a spray booth.
       Also enclosed is a piece of literature on our Aqua-Static
100 electrostatic hand gun for applying waterborne paint. While
this gun easily outperforms all other electrostatic hand guns on

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                                 [6]
waterbornes, we consider it obsolete. We are in the process of re-
placing it with a new model. The Aqua-Static 100 was first placed
on the market in 1971 but our competitors managed to destroy the
market for waterborne paint and pushed for high solids paint. The
Aqua-Static 100 gun used the conductive waterborne paint to bring
the electrostatic charge to the head of the gun. It functioned as
a non-electrostatic gun when used with non-conductive solvent base
paint but would still atomize the high solids coatings much better
than other spray guns. Our competitors controlled the market but
failed to solve environmental problems.
       With our automatic electrostatic guns equipped with "Conical
Film Atomization" and a proper waterborne or high solids environ-
mental coating, the need for installing expensive add-on controls
can be avoided and still meet the most stringent environmental codes.
The enclosed colored environmental comparison for liquid coating
shows a 94% reduction in VOCs.  Attached to this chart is a news
release that explains the switch-over to a waterborne powder slurry
to cut VOC emissions by 100%.  The operating costs of this system
will be half that of a dry powder system.
       Our Auto-Static 400 electrostatic spray system is by far the
best RACT available to the plastic industry. With a waterborne
coating,  it can reduce VOCs by 94% or more.
       Electrostatic spray equipment is substantially more costly
than HVLP guns but can quickly be justified with heavier production
requirements.  In order to obtain the many advantages of electro-
static spray combined with "Conical Film Atomization" to achieve
superior  atomization at still lower air pressure, it is necessary
to install our Auto-Static 400 automatic electrostatic equipment.
It will pay for itself with paint and labor savings in the first
year.   Other electrostatic air gun systems are still using conven-
tional air atomization that is severely limited when attempting to
apply  the higher viscosity environmental coatings. They were de-
signed originally to atomize low viscosity non-compliance paint and
cannot properly apply the new high viscosity waterborne and high
                             504

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                                  [7]
solids environmental coatings.
       Disk and bell electrostatic systems have serious drawbacks.
They do very poorly atomizing conductive waterborne coatings. There
is a serious reduction in quality.  They also provide very poor
"throwing power" into recessed areas and require far too much manual
touch-up. The touch-up is normally done with low efficiency touch-
up guns-that cause a serious drop in overall efficiency.  This
greatly increases overall paint consumption and VOC emissions.
       One of our old customers manufacturing folding chairs gave
a talk at a local seminar recently. We replaced two reciprocating
disks and three touch-up men with our Auto-Static 400 electrostatic
system at his plant. The improvements achieved were as follows:

       1.  Increased production at least 10%
       2.  Eliminated two of the three touch-up men
       3.  Cut overall paint consumption by 30% and reduced VOC
emissions a corresponding amount.
       4.  Reduced annual rejects by $100,000
       5.  Switched the firm over to waterborne coating to achieve
full environmental compliance
       6.  Eliminated a potential fire hazard
       7.  Cut costs by 50% over competitive dry powder systems

       Our continuous efforts to solve air pollution in  the spray
painting industry since 1969 are finally starting to pay off.

                                  Sincerely,
                                  Arvid C. Wallberg CMFgE
ACW/mv                                    /X V
Enclosures                            --^/
                            585

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          ELECTROSTATIC CONSULTANTS  CO
                      P.O. BOX 1587 / LISLE, ILLINOIS 60532
                                  PHONE (708) 668-5027
                                July  3,  1991

                    HOUSE PAINTING  REPORT
      A new sales  field has been added to  the scope of the CFA
740  air-atomizing non-electrostatic hand spray gun. A wooden frame
home with vertical  redwood siding was sprayed in Carmichael, Ca.
and  achieved almost  100% transfer efficiency  (T.E.).  The  gun
coated 300 sq.ft./gal with a paint that was rated as follows:

COVERAGE
      250 - 350 sq.ft./gal on  smooth surfaces
      150 - 250 sq.ft./gal on  porous, rough  or weathered  surfaces

      Since the description of the wooden  surface  fit the latter
description rather  precisely, the actual performance of 300 sq.ft./
gal  was exceptional.  The condition of the  surface  tended  to indi-
cate that two coats  might be required to achieve good coverage. The
single coat proved  to be more than adequate and provided excellent
coverage and uniformity-  The actual coverage indicated on the  paint
can  as shown above  was with a brush or roller.  The CFA 740 air
atomizing spray gun  actually provided even  better  performance.

PAINT
      Sears Weatherbeater, #21455 Navajo Red solid color stain
made for Sears by  Olympic.  Contents:
             Water,  Vinyl Acrylic Resin, Silicon  Dioxide,
             Ethylene Glycol,  Alkyd  Resins & Additives

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                                 -2-
       Reduction:   2 Paint,  1  Water
                   Viscosity 79 Sec.  #2 Zahn Viscosity Cup

       Max.  VOCs:   350 GMS/liter
                  2.92 Lbs/gal

SPRAY GUN
       'CFA 740 hand gun (air atomizing with Conical Film Atomization)
complete with 1 qt. pressure cup.   Fluid orifice 0.120", restrictor
orifice' 0.40" and  0.052".   25' air hose, 3/8" I.D.

AIR COMPRESSOR
       Sears Craftsman 1 HP, 8 Gal. Tank.
                       4.5 S.C.F.M. at 40 PSI
                       3.0 S.C.F.M. at 90 PSI
       Compressor  shut off automatically when 100 PSI was reached
and restarted when tank pressure dropped to 80 PSI.  A small air
pressure regulator on the tank supplied compressed air to the spray
gun.

OPERATING CONDITIONS
       The paint is normally applied with a brush or roller. The
label indicated an airless gun could be used and  the paint applied
uncut.  Conventional air atomizing spray guns are not used for this
type of application because of the excessive spray fog and paint
waste normally generated.  The CFA 740  hand gun was the  first air
atomizing spray gun to be successfully  and  economically  used to
paint a home.  The paint waste was negligible and the quality of
the final coating  was excellent
       The attached air pressure  curve  shows the  operating conditions
for the spray  gun. The gun was  operated as  follows:
            UPSTREAM AIR PRESSURE, PI         20  PSI
            ATOMIZING AIR PRESSURE,?2          5  PSP
            PAINT PRESSURE                   6-9  PSI
                            r '•• 7
                            rj. 0 i

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                                 -3-
       * Meets  California's  SCAQMD environmental requirements
         (10 PSI  is upper  limit).   Conventional air atomizing
         guns are currently  barred from use in the state.

       The 0.040" restrictor orifice was installed in the  paint
inlet connection  of the gun. This  provided a relatively slow speed
and was replaced  with a 0.052" restrictor orifice to increase speed.
The spray gun proved to be much faster than a brush or roller and
applied a higher  quality finish.   It was probably slower than an
airless gun but by precisely controlling the amount of paint applied
to the surface, far less paint is  used.  The gun could also be oper-
ated at much higher speeds if necessary.
       In tests last year, DuPont  preferred the CFA 740 hand gun
for maintenance painting over an airless gun.  Their primary com-
plaint was that it did not use enough paint. I advised them that
they could raise the price of paint used with the gun but  they in-
dicated this could be done over a  long period of time but  not over-
night.  DuPont tried the gun for painting storage tanks in refinery
tank farms, piping, buildings and  even for maintenance painting on
an oil platform in the Gulf of Mexico.  The gun is an excellent pros-
pect for replacing all airless spray equipment used by painting con-
tractors. It provides very high painting efficiency while retaining
all of the  flexibility of a conventional air atomizing gun.  It also
has a major advantage over all other guns used in the wood coating
industry.
       The  primary bottleneck  for house painting  was  the small air
compressor  used.   It had  to be operated almost continuously.  The
compressor  was equipped with  thermal overload  protection that  trip-
ped the  compressor off occasionally  because  of  the  100°F. weather
conditions.  It was necessary  to allow  the  thermal  overload  protec-
tion to  cool for  a while  to permit  an  automatic  reset.  The  compres-
sor was  kept in  the  shade to  minimize  the  overload  shut-off  problem.
An extension cord  with larger  wire  size  would  also  have been helpful
        The  1 HP  compressor  was  selected  since  it  could  be  operated
off of  a  15  amp,  110 volt household circuit.   Most  conventional

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                                 -4-
air atomizing spray guns require  a 4 to 5 HP compressor to
supply  a  single spray  gun.      This is much too large for a
110 volt household circuit and a compressor that large would have
to be operated with a gasoline engine.  Industrial plants with cen-
tral air compressors would easily supply sufficient compressed air
for continuous operation.
       When painting metal gutters and downspouts, it was necessary
to reduce the paint flow-rate by reducing the fluid pressure since
these smooth surfaces required far less paint.  The same thing
could be accomplished by moving the spray gun much faster.

LIMITATIONS
       Operating with a one quart pressure cup required frequent
filling and slowed down production.  The cup would also supply air
instead of paint when aimed on an upward angle.  This prevented
spraying of eaves and the ceiling of porches.  The pressure cup
also added a lot of weight to the gun and made it less manueverable.
The extra weight made the gun more tiring.
       The above problems could be corrected with a pressure cup
supported from the belt of the sprayer.  A larger pressure tank could
be-left on the ground or attached to the air compressor dolly. The
paint would be fed through a fluid hose to the spray gun.  This would
cause a static pressure head reduction of 0.4 to 0.5 PSI  for every
foot of increase in elevation of the spray gun above the  paint pres-
sure tank.  When a sprayer operates on a ladder or scaffolding, he
will have to increase the paint tank pressure by about 0.4 to 0.5
PSI for every foot he is above the paint tank.  This will be needed
to deliver the same amount of paint to the gun and maintain produc-
tion speed.  The pressure will have to be reduced by the  same amount
when the sprayer returns to ground level.  A  small fluid  pressure
regulator mounted on the gun would permit the operator to adjust
the fluid delivery to suit his needs.
       When we ran out  of paint with  the pressure cup, the  spray
gun could spit.  While  this was not a  problem in  the house  painting

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                                 -5-
project,  it would be a problem for automotive  refinishing.   A si-
phon cup  would not cause a similar problem but it  cannot be used
with the  CFA 740 hand gun.  All conventional air guns that  operate
with a paint pressure tank would have the same problem.
       For production maintenance painting,  we would recommend a
minimum of a 2 gallon  paint pressure tank to  avoid running out of
paint frequently-  The paint can be purchased  in one gallon cans
with an empty spare can purchased simultaneously.  By splitting a
gallon of paint into two one gallon cans, there is then  room for
adding water or thinner.  The entire one gallon can can  be  placed
into a 2 gallon pressure tank and avoid getting the pressure tank
dirty.
       A spray gun cannot be used to paint to  the  edges  of  windows
without coating the window as well. This problem was solved by mask-
ing the windows and aluminum frames with newspaper and masking tape.

CONCLUSIONS
       The CFA 740 hand spray gun is an excellent  maintenance paint-
ing tool.  It will compete successfully against brushes  and rollers
by providing greater paint mileage and by operating at higher speeds.
It will also apply a higher quality, more uniform finish. The gun
complies with all of California's environmental code requirements.
       The CFA 740 hand spray gun can handle most of the contract
painting work currently done with airless spray equipment.   Equipment
requirements are greatly  simplified.  The gun is far more flexible
than an airless gun. It permits  infinite adjustment of paint  flow-
rate to provide the production  speed desired.  The  spray pattern
is fully adjustable.  Quality of  atomization and applied film  thick-
ness can be controlled  with precision. Engineering  extremes  such
as extremely small orifices and  extremely high pressures are  avoided.
The CFA  740 hand gun moves spray painting  away from a  black  art  and
into an exact science category.

                                  ARVID  C.  WALBERG  CMfgE
                             FT O I

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f,

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FOR BETTER OR FOR WORSE
                 BETTER  YET, BUY A CFA  740!
                             •TO

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                                                                                 TECH TALK
                           Reprinted from November 1982 issue of INDUSTRIAL FINISHING
                                  « 1982 HITCHCOCK PUBLISHING COMPANY
                                           ALL RIGHTS RESERVED
       How to Spray Plastic and  Wooden
                  Products  Electrostatically
      By Arvid C. Walberg, President
   Arvid C. Walberg & Co., Downers Grove, IL
   Nonconductive  surfaces  can  be
sprayed  electrostatically  without the
pretreatment normally used to make
the surface electrically conductive. The
basic  law  of  electrostatic  painting
requires two electrodes in the system:
one to impart a charge (usually nega-
,tive) to the spray particles and another
(usually grounded) to attract the paint
particles  for  deposition. Both  elec-
trodes must be electrically conductive
to make the system work properly. This
basic law cannot be repealed, but it can
be bent somewhat to accomplish desir-
able results.
   By spraying nonconductive products
electrostatically with waterbome  coat-
ings  the  desired  results  can  be
achieved. The  charging  electrode will
be the spray device, preferably an air-
atomizing electrostatic spray gun. We
suggest air guns because airless guns
lack the flexibility needed in automatic
systems,  and  electrostatic atomizing
devices such as disk and bell systems
do not atomize conductive waterborne
coatings as well as similar nonconduc-
tive solventborne materials. The  paint
particles are  given a negative charge
with the electrostatic gun.
   Because  the waterbome  coatings
are electrically conductive, an electrical
feedback  to the paint source will occur,
and it is necessary to isolate the paint
source from ground. The system would
otherwise short out, eliminate the elec-
trostatic field  and make the  system
spray nonelectrostatically. Isolating the
paint source from ground is very safe,
and, in fact, the overall safety is greatly
improved  because waterborne coatings
are not a potential fire hazard.
  The  charging  electrode is  more  or
less conventional. The collecting  elec-
trode  functions  in a nonconventional
manner, however. Nonconductive prod-
ucts, such as the plastic shutters in the
photo,  start out essentially at ground
potential so there is an initial attraction
for negatively charged spray particles.
The  initial attraction  of waterborne
Automatic electrostatic spray guns apply waterbome coating to polystyrene window shutters
without first applying a conductive pretreatment.
coating material makes the surface of
the  shutter  electrically conductive
through the paint film itself. A painted
path to the grounded metal hanger is
quickly completed and provides a direct
path to ground. This bleeds off the elec-
trical charge, and the electrostatic coat-
ing process continues in approximately
the  same manner as for a grounded
metal product.
  The waterborne coating greatly sim-
plifies the electrostatic spraying of plas-
tic and wooden products by eliminating
costly pretreatment. Painting costs are
reduced by about 50% compared to
conventional   nonelectrostatic  spray
equipment. In a typical installation coat-
ing plastic shutters, the viscosity of the
waterborne coating is very high—30-
to 60-sec range in a Zahn No. 2 cup.
  After electrostatic painting, a 2-min
flash is provided ahead of  the bake
oven. The  parts are in the bake oven
for 4 min with an oven temperature of
71 to 76C (160 to 170F). Higher tem-
peratures  would  cause  permanent
warping of the plastic parts.
  Three minutes after leaving the bake
oven, two shutters are placed back-to-
back and  covered with clear heat-
shrink plastic. The packaged shutters
         < • f • r
are then placed immediately into car-
tons for shipment.               E3
   Arvid C. Walberg is president of two
  manufacturing businesses: Arvid C.
  Walberg & Co. and Environmental
  Finishing Systems Co. Throughout his
  32 years in electrostatic engineering he
  has been responsible for the design of
  more than 1000 automatic electrostatic
  systems installed around the world. He
  holds several dozen patents in the U.S.
  and foreign countries for his many
  innovations. An engineering graduate of
  the Illinois Institute of Technology, he is
  a member of the Society of
  Manufacturing Engineers and a certified
  manufacturing engineer in general
  finishing processes.

-------

-------
'

-------

-------
WALBERG #475  FLUID REGULATOR

-------
Patented, NEW design of this
handgun permits charging
of water-base paints in the gun
itself and eliminates the
awkwardness of heavy
high-voltage cables.
The Aqua-Static 100
        MftlA/     ^'s 9un w't'1 'ts suPer'°r
        nlwlW    "conical film atomization"
         • ••   improves electrostatic efficiency.
         AN            Savings up to 50%

ELECTROSTATIC      ^^
                                          equipment.
a solvent-base gun.
                  HANDGUN
                                     an
            MADE ESPECIALLY
       FOR  WATER-BASE PAINTS
                                                °
                                           'Hi
             Patents - 3746253, 3774844, other patents pending.
NEW from:

AWID C. I^ILBERG & CO.
2741 CURTISS STREET
DOWNERS GROVE, ILLINOIS 60515
(312) 852-5450
                             tfie Aqua-SMic 100
                               the besf there is!

-------
    engineer
      •ing
ELECTROSTATIC CONSULTANTS CO,
            P.O. BOX 1587 / LISLE, ILLINOIS 60532
                        PHONE (708) 668-5027
                  ENVIRONMENTAL COMPARISONS

                            FOR

                      LIQUID COATINGS


Conventional Solvent Base Paint (6 Gallons per hour, one sprayer)

Conventional Air Gun  at 25% Transfer Efficiency

//////


7/7777


///"///


77/7/7


77/777


run/
.
71
t
-•>%
•
25%
                                               75% Solvent, 4 1/2 Gals.
                                               25% Solids,  1 1/2 Gals.

                                                t
Good  Electrostatic Spray System (Cuts Paint Consumption in Half)


//////







//////







/777//

t
75% Solvent, 2 1/4 Gals.
1
25% Solids, 3/4 Gals.
t

50%
Reduction
T n \/ HP c-
in VULS





Switch  to High Solids or  Waterborne  Paint (1 Gallon  with 75% Volume
Solids  Less Water) with Auto-Static  AOO Electrostatic System (HVLP).
Meets all environmental requirements.
        25%  Solvent, 1/4 Gal.
         t
        75%  Solids, 3/4 Gal.
                          94%
                        Reduction
                         In VOCs
Switching to waterborne powder slurries with  Auto-Static 400 system
can reduce emissions by 100%.
                           
-------
           ELECTROSTATIC  CONSULTANTS CO.
                       P.O BOX 1587 / LiSLE. ILLINOIS 60532
                                   PHONE (708) 668-5027
                         NEWS RELEASE

      The Electrostatic Consultants Co. announces an enormous  im-
provement in electrostatic powder coatings equipment. By combining
its  Auto-Static 400  automatic electrostatic spray painting system
with powder slurries,  its gains the best of both worlds!  Here's
how  it works:

TRANSFER EFFICIENCY

      The powder is applied as a liquid in a water  slurry form.
By greatly boosting  the first pass transfer efficiency, the need
for  reclaiming and reusing the overspray is eliminated.  The cost
per  square foot of surface coated is reduced by 50%  or more.  The
Auto-Static 400 guns operate at a higher output voltage and are
the  only HVLP air electrostatic guns on the market.  The atomizing
air  at the air cap is well below 10 PSI air pressure and does not
sacrifice transfer efficiency, quality of finish or  production  speed.

QUALITY OF FINISH

      A powder can  be ground much finer if used in  the form of a
water slur.ry.  The dry powder particles are quite  large and normally
ground into a 25 to  40 micron range  (1.0 to 1.6 mils).  Smaller
particles tend to cake and pack in dry  form and become  very diffi-
cult to handle.  Since quality of finish is inversely  proportional
to particle size, powder slurries permit a much finer  grind and will
provide a much higher quality of finish. Powder can  now achieve an
                            C r
                            « • c1

-------
                                 -2-
automobile type finish.

APPLIED FILM THICKNESS

       The large particle size of dry powder (1.0 to 1.6 mils)
causes the application of excessive film thickness.   It is obviously
impossible to reduce film thickness to 1.0 mils if you apply 1.6
mil particles of 100% solids material.  Keep in mind that the pow-
der is applied more than one layer thick.   Remember  that the cost
of a paint film is directly proportional to its thickness.  A pow-
der slurry can be applied to half the film thickness and cuts costs
by 50% or more.
       Applied film thickness can be held within 0.1 mil (0.0001")
of the desired thickness over an entire work surface with a liquid
coating.  This is greater precision than can be held in the average
machine shop.  Film thickness is built up with multiple thin coats.
It is also constant over the full height of the ware with the full-
stroke reciprocators .  There is no interface problem with adjacent
guns coating different areas on the same work piece.

QUICK COLOR CHANGES

       By eliminating the need for reclaiming and reusing overspray,
the color change time can be reduced  to a few seconds.  This broadens
the market to  include those that must make numerous color changes
every day. Cost savings  are very high over the complicated  color
change techniques required with dry powder systems.

COMPUTER  PROGRAMMERS

       The computer programmer used with  the  Auto-Static  400  elec-
trostatic system uses up to  16 electric eyes  scanning  the ware
ahead of  the electrostatic  system.   It  programs  itself to suit  the
configuration  of products  passing  on  the  conveyor line.   Products
up to 16  different  vertical  dimensions  and  an infinite number  of
                               "O

-------
                                 -3-
horizontal dimensions can be mixed together on the line and sprayed
to suit.
FIRE SAFETY

       Powder slurries eliminate the fire hazard normally associated
with either dry powder or solvent base coating systems.  The water
in the coating prevents ignition with an open flame.  The water ap-
parently prevents the temperature from rising to the ignition point.
The codes that cover "Spray Application Using Flammable and Combus-
tible Materials" no longer apply.  Insurance costs will be greatly
reduced.  The fire safety of a production plant is greatly improved.

FLEXIBILITY

       All of the flexibility of the Auto-Static 400 liquid coating
system is retained.  Waste caused by spraying at large open areas
is avoided.  Four spray guns on each of two full-stroke reciproca-
tors are aimed on eight different compound angles to assure more
complete coverage on every work piece.  This eliminates manual touch-
up on most products. The normal Faraday Cage effect expected with
other electrostatic equipment is overcome. Paint and labor costs
are reduced to a minimum.
       The same electrostatic system will apply all three environ-
mental coatings with equal ease.  This includes waterbornes, high
solids (up to 80% volume solids) and powder.  It is unnecessary for
a user to make a long term commitment to one type of coating or an-
other .

CLEAR-AIRE' SPRAY BOOTHS

       Clear-Aire spray booths are normally furnished  with the Auto-
Static 400 electrostatic coating system as shown in attached Draw-
ing No. 1800.  These booths use a roll-up filter material that
changes itself automatically as needed about 6" at  a time.   This
                             rr o
                             i • u 
-------
                                 -4-
assures uniform ventilation all day long.
       The high collection efficiency of the filter material stops
all particulate emissions from exhaust stacks.   Some of these
booths have operated with high solids coatings  for 5 to 7 years with-
out requiring cleaning of exhaust plenums,  stacks or fans.
       The thorough filtering action permits recycling 80% of the
exhaust air back into the spray booth.  This cuts the heating bill
for exhaust air by $5000 for a 10' high booths  per year in Northern
Illinois. This is with a single shift operation.  They also cut the
size and cost of make-up units needed on new installations.
       As indicated above, the national codes covering "Spray Appli-
cation Using Flammable and Combustible Materials" no longer apply
if waterborne paint or water slurries of powder are applied.

       The 80% recycling spray booth is designed to provide suffi-
cient ventilation to stay below 25% of the LFL  (Lower Flammable
Limit) when conventional solvent base paint is  used at the full
production capacity of 100 square  feet of surface coated per minute.
This is also assuming 25% solids and 75% solvent in the paint. The
LFL is further reduced by 94% when switching to a 75% volume solids
environmental paint.  At the same  production capacity, the vapor
concentration is reduced to 1.5% of the LEL.
       Since there is no solvent vapor produced in dry powder, sys-
tems safety is computed in a different fashion.  Powder concentra-
tion shall not exceed 50% of the MEC  (Minimum Explosive Concentra-
tion).  This is defined as a dry powder concentraion below 0.015
oz per cu.ft. of exhaust air.  By  going to a water slurry, the
powder becomes very safe and it is no longer covered by codes re-
gulating "Spray Application Using  Flammable and Combustible Materi-
als".  This was determined by Factory Mutual Research Corporation,
Scientific Circular 804 dated 1977 covering waterborne coatings.
The Clear-Aire 80% recycing automatic spray booths meet  NFPA  #33
code requirements and are approved by OSHA  for  use with  the Auto-

-------
                                 -5-






Static 400 automatic electrostatic coating system.





                                  ARVIO C. WALBERG CMfgE


ACW/mv
                              TV r.
                               c *J

-------
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-------
             Products  Corporation
        AN INDUCTOTHERM COMPANY
                                      1715 DOGWOOD DR • CONYERS GA 3O2O7 . (4O4i 483-O915
December 3, 1991
Mr  Bruce C.  Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park,  North Carolina  27711

Dear Mr. Jordan:

This  is  in  response  to the  National   Air  Pollution  Control
Techniques  Advisory Committee's (NAPCTAC's) request for  comment
concerning  the proposed Control Techniques Guideline  (CTG)  for
the  control   of volatile organic compounds (vocs)  from  surface
coating of plastic parts.  Specifically addressed is one area  of
the Miscellaneous Plastic Parts Category.

Vantage  Products  molds and paints decorative  window  shutters,
storm  doors, and other  building products  out  of  polypropylene.
The material  used and the conditions that  the parts are subjected
to  do not seem to fall  within the scope  of the CTG discussed  at
the  recent   NAPCTAC  meeting in  Durham,   North  Carolina.    The
enclosed  report was prepared for NAPCTAC  to help make you  aware
of  some of  the unique problems encountered in our  process.   We
hope that you will consider this material  when drafting the final
version of the CTG.  Included in this package is a scale model of
one  of  our  louvered  shutters to  help   you  to  visualize  th
difficulties involved in painting a shape  of this complexity.

Please do not hesitate to contact us if we can provide additional
information   or sources  of information.  Thank you for your   time
and attention.
Sincerely,
Dale C. Jones
Finishing Department Manager
Vantage Products Corporation

(404)  922-6767 (FAX)

cc:  NAPCTAC Committee Members

/encIosures

-------
           COMMENTS ON THE




    CONTROL TECHNIQUES GUIDELINE




               FOR THE




CONTROL OF VOLATILE ORGANIC COMPOUNDS




FROM SURFACE COATING OF PLASTIC PARTS









            SUBCATEGORY:




     MISCELLANEOUS PLASTIC PARTS









            prepared by:




            Dale C. Jones




                 FOR




    VANTAGE PRODUCTS CORPORATION
               Ff 9
               v Hj. «U-

-------
                         TABLE OF CONTENTS










INTRODUCTION                                            PAGE  1




ADHESION PROMOTING  ADDITIVES                            PAGE  3




PRIME COAT / TOP COAT                                   PAGE  3




WATER REDUCIBLE                                         PAGE  3




HIGH SOLIDS                                             PAGE  4




RADIATION CURABLE COATINGS                              PAGE  4




POWDER COATING                                          PAGE  4




UNICARB                                                 PAGE  5




1,1,1-TRICHLOROETHANE                                   PAGE  5




MOLDED-IN COLOR                                         PAGE  5




CHROMATE SOLUTION TREATMENT                             PAGE  7




CORONA DISCHARGE                                        PAGE  7




PLASMA TREATMENT                                        PAGE  7




FLAME TREATMENT                                         PAGE  7




ULTRAVIOLET TREATMENT                                   PAGE  7




MECHANICAL ABRASION                                     PAGE  8




SUPPRESSED SPARK TREATMENT                              PAGE  8




MECHANICAL SYSTEMS                                      PAGE  8




CONCLUSION                                              PAGE  9




INDEX                                                   PAGE  11

-------
Introduction:




It  has  been recommended that the Control  Techniques  Guideline



(CTG) for the coating of miscellaneous plastic parts be   included



as  a  subset of the CTG for Business Machines  and  Electronics.



This  document  is  intended to provide information  that  may  be



helpful  in  formulating  the CTG for those  who  mold  and  coat



polypropylene   (PP) and polyethylene  (PE).  Because of  the  very



low  surface  energy  of  these  materials,  they  are  extremely



difficult  to successfully paint.  However, they  are  relatively



inexpensive,  have  good mechanical properties,  and  are  easily



recyclable.  There  are a number of sources of recycled PP and PE,



and utilizing them  reduces solid waste volumes.






Our  industry (the  manufacture of plastic window shutters,  storm



doors, and other miscellaneous building products) primarily  uses



polypropylene, so that will be the focus of this paper.  When  it



comes  to  coatings,  it is generally true that  what  holds  for



polypropylene  is also applicable to polyethylene.   Since  these



products  are  designed  for exterior  application,  the  painted



finish  must have outstanding adhesion to the substrate and  must



have  the durability to last for years without chalking,  fading,



loss   of   gloss,   or   other   undesirable    characteristics.



Polypropylene parts intended for interior use only (some computer



housings,  office furniture, etc.) are not subjected to the  same



environmental  extremes  and so the integrity of  the  finish  is



somewhat less critical.






In  theory, reducing the emission of Volatile  Organic  Compounds
                             '.II

-------
 (VOCs) can be accomplished by either lowering the VOC content   of




 the coating or by utilizing some mechanical means of removing  the




 VOCs from the exhaust stream.  The principle of source  reduction




 holds  that  it is better not to have the VOCs present  to  start




 with, so the coating alternatives will be discussed first.






 There are two primary methods by which a paint film is held to  a




 substrate; mechanical bonding and electrical bonding.  Mechanical




 bonding  takes  place  when  the  surface  of  the  substrate   is




 dissolved  very  slightly by one of the solvents  in  the  paint.




 When   the  solvent  evaporates  and  the  surface   subsequently




 resolidifies, the interface zone between the part and the coating




 is  blurred.   This is analogous to welding two pieces  of  metal




 together; both pieces melt at the joint, the molten metals mingle




 together, and when they solidify the two pieces have  effectively




 become  one.  Electrical bonding, on the other hand, takes  place




 on the molecular level.  The electrical attraction between  polar




 molecules binds the paint to the substrate.  Generally  speaking,




 this  is  not  as effective as mechanical bonding  but  for  some



 substances  it is the only method that works.  Polypropylene   has




 excellent  resistance  to  chemicals  (automobile  batteries   and




 laboratory  ware are often made of PP) and is unaffected by  most




 solvents.   Mechanical  bonding  of the paint  will  not  happen.




 Unfortunately,   the  surface energy level of PP is very  low   and




 electrical  bonding  does  not  readily  occur  either.   Various




methods have been tried to promote adhesion, with varying degrees




of  success.    Either the paint must contain  some  element  that




 increases adhesion,  or the parts must be pre-treated in some   way

-------
to increase the surface energy level.






Adhesion promoting additives;




A Chlorinated Polyolefin (CPO) additive has been used in coatings



for  PP  quite  successfully as an  adhesion  promoter.   Eastman



Chemical  is  one   manufacturer  of  CPO,  and  supplies  it  in



industrial   quantities   to  formulators   of   coatings.    The



disadvantage  to  CPO is that no one has been able  to  create  a



stable emulsion of it with water, hence a solvent based paint  is



necessary.   These coatings typically contain 4 1/2 Ibs./gal.  of



VOC and up.






Prime coat/top coat



It  is possible to apply a very thin prime coat of solvent  based



material  containing CPO, followed by a topcoat of low VOC  water



reducible paint.  Testing has shown that this system can be  made



to perform adequately under ideal conditions.  Unfortunately, the



combined  VOC content of the prime coat and the  water  reducible



top coat can be equal to that of one coat of solvent based paint.



Also,  if any areas of the part are missed by the prime coat  the



paint will fail to adhere in those areas when exposed to exterior



conditions.   It  would  probably be impossible  to  detect  this



defect until parts started failing in the field.






Water reducible:
As  noted above, a water based paint that combines the  necessary



attributes  of  adhesion  to  PP  and  durability  has  not  been



developed.   The  market  for such a specialty  coating  is  very



small,  and  there  is little incentive for  the  major  coatings

-------
manufacturers  to  spend  a  great deal of lab  time  on  such  a




project.






Hiqh solids:
High  solids paints are subject to roughly the  same  limitations




imposed by CPO as water reducible ones.  The solvent  (hence  VOC)




content  of the coating must be high enough to maintain a  stable




solution.  Thirty five to forty percent volume solids appears  to




be the upper limit.






Rad iat ion curable coatings




Radiation  curable coatings can often be formulated with  no  VOC




content  whatsoever.   They rely on the energy supplied  by  non-




ionizing  electromagnetic radiation (often ultraviolet light)  to




promote  crosslinking of the polymer chains in the resin  system.




This  method  of  "drying"  does  not  rely  on  either   solvent




evaporation  or  auto-oxidative  chemical  reactions.   The   two




problems  associated with radiation curable coatings  that  would




affect  our  industry  are  the inability  of  the  radiation  to




penetrate some opaque colors, and the difficulty/impossibility of




focusing  the  radiation  on  randomly  shaped  three-dimensional



objects.






Powder coating;




Powder coating is another non-VOC finish that is used extensively




in  the  coating of metal parts.  The temperatures  and  time  of




exposure to such temperatures required to cure the parts makes it




unsuited for use with most thermoformed plastics, including PP.

-------
Unicarb:




Still  in its experimental stages is the Unicarb system  invented




by Union Carbide.  It relies on the ability of carbon dioxide  to




become  supercritical at moderate temperatures and pressures.   A




supercritical  substance  exhibits some of the  properties  of  a




liquid  and a gas simultaneously, and it can be used to dilute  a




very viscous coating without the use of additional solvents.  The




process  involves the use of equipment that, for the  most  part,




hasn't been developed yet.  There is at least one pilot plant  in




North Carolina working on coating furniture, but the  indications




are  that  this  technology is still  years  away  from  becoming




viable .






1,1,1-trichloroethane:




There have been some solvents that are not considered VOCs,  most




notably  1,1,1 trichloroethane.   It was not thought  to  initiate




smog-causing  chemical  reactions, and so was exempted  from  VOC




regulations by many states.  Recent evidence suggests that it  is




a  large factor in ozone depletion in the upper  atmosphere,  and




its use is being phased out over the next several years.  No safe




substitute for its use in paint has been developed yet.






Molded-in color:
Finally,  there  may  be products that could  be  molded  in  the



appropriate color instead of painted.  Unfortunately, PP tends to



degrade  when  exposed to the ultraviolet component  of  sunlight



unless  protected by a coat of paint.  There are  additives  that



will stabilize PP against such degradation, but they are far more



expensive than painting.  Using such additives in recycled PP  is

-------
not  recommended by any of the manufacturers, since there   is  no




way  of knowing precisely what is in the plastic and what   effect




these  stabilizers  might  have.   In addition, one  of  the  most




important  benefits of our shutters and storm doors is  that  the




customer  can  paint  over the original  coating  with  any  good




quality exterior house paint.  They would not be able to do  this




if  the part was purchased with the color molded in, as there  is




no paint that we are aware of available on the retail level  that




will adhere to PP -






To  date, technology has not yielded a coating for  polypropylene




that provides the necessary performance qualities and also a  low




VOC content.  The closest approach that we are aware of has 3 1/2




Ibs./gal.  of  VOC  (after subtracting exempt  solvents)  and  is




formulated with 1,1,1-trichloroethane.  Since this appears to  be




an  environmentaly unfriendly solution, it will not be  available




for long.  The alternative to including adhesion promoters  in the




coating  is  to pretreat the surface of the part in some  way  to




raise  energy  levels  to the point where existing  coatings  will




adhere.  The traditional ways of  doing this include:






               1.  Chromate solution treatment




               2.  Corona discharge




               3.  Plasma treatment




               4.  Flame treatment




               5.  UV treatment




               6.  Mechanical abrasion




               7.  Suppressed spark method

-------
Chr ornate solution treatment:

Chromate  solution  treatment   involves dipping the  parts   in  a

solution of 5% potassium dichromate and 95% concentrated sulfuric

acid.   The  mixture must be replaced  from time to time,  and   is

inherently environmentaly unfriendly.


Corona d ischarge:

Corona  discharge   involves exposing the parts to  an  electrical

halo produced by a  high voltage, high  frequency generator.   Ozone

is  produced as a by-product.   Often used to treat webs of   film,

it is not suitable  for three dimensional objects.


Plasma treatment:
Plasma  treatment   is  similar  to  corona  discharge,  but  also

involves a vacuum chamber and the introduction of gasses, such as

argon,  tetrafluoromethane, and nitrogen.  It is a batch  process

and is not compatible with a continuous assembly operation due to

the slow speeds involved.


Flame treatment:
Flame  treatment  is the process of passing the part  through  an

oxidizing  flame  to activate the surface.  The main  problem  is

lack  of  uniformity  in treating  an  awkwardly  shaped  object.

Additives in the plastic can negate the effects of the treatment.


Ultraviolet treatment;

Ultraviolet  treatment  is accomplished by treating  the  plastic

with benzopherone and then exposing the surface to UV  radiation.

Again, the problem is treating three dimensional objects, and the
                           7
                            r;:_7

-------
effects of additives in the plastic.
Mechanical abrasion:
Mechanical abrasion is done with sandpaper or abrasive  blasting.




The  reliability factor is low, and the same problems with  three




dimensional parts and additives are encountered.






Suppressed spark treatment:




Suppressed  spark  treatment involves conveying the parts  to  be




treated  through  a dielectric tunnel containing  a  high  energy




electric field.  The resulting discharge creates a corona effect,




and  is  similar in application to the corona  discharge  method.




Ozone is created as a by-product.  The limitations include  speed




of  treatment and the composition of any additives that might  be




in the plastic.  The parts must also be meticulously cleaned.






The  systems  that  might  be  applicable  to  our  products  and




processes  include  flame  treatment,  mechanical  abrasion,  and




suppressed  spark.   We have performed  extensive  testing  using




these methods in conjunction with a wide variety of low VOC water




reducible  coatings, and have been unable to  produce  acceptable



results.  None of the above reliably or consistently treated  all




of the required surfaces of the parts, and accelerated weathering




tests  showed  consistent  failures.   The  equipment  and  paint




manufacturers  agreed  that  some of the problem is  due  to  the




complex  shape of the parts, and some is probably due to  unknown




(and unpredictable) additives and mold release agents present  in




the recycled and reprocessed polypropylene materials used.






Mechanical systems;

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Since  no viable alternatives presently exist for  VOC   reduction




through coatings technology, abatement equipment was studied.   A




total  of sixty four manufacturers of systems designed to  remove




VOCs  from an exhaust stream were contacted and asked  to  submit




proposals  for  the  installation of  their  systems.    Installed




purchase  price, yearly maintenance costs, and power  consumption




figures   were  requested.   Quotes  were  received  for   carbon




adsorption  units   (both steam and  nitrogen  stripped),  thermal




oxidation  (recuperative and regenerative), catalytic  oxidation,




and  refrigeration  systems  (liquid nitrogen, Rankine  cycle,  and




Brayton  cycle)  to  condense  VOCs  from  the  exhaust   stream.




Refrigeration  was  quickly discounted as an  option.    Based  on




36,000  CFM  of exhaust and a loading of 81 Ibs./hr.  of  toluene




(for  an  equivalent vapor partial pressure of 0.132  mm  Hg),  a




temperature of (-140 degrees F.) would be necessary to reduce the




volume percent of toluene to approximately 7 ppm.  The   operating




costs  alone  would be prohibitive.  The other  systems  averaged




about  $1,000,000 to purchase and install, with  operating  costs




projected to be in  excess of $50,000 per year.  A capital expense




such  as  this is beyond the ability of many small  companies  to




manage and remain competitive.






Conclusion:
In summary, we have determined the following:






     1. The technology does not yet exist to produce a truly  low



VOC  coating  for  polypropylene  that  combines  the   requisite



adhesion  and durability under naturally occurring conditions  of

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environmental stress.


     2.  Pretreatment  of  the  parts  to  maximize  adhesion  of

existing  coatings is not reliable enough or effective enough  to

be a viable option.


     3. Mechanical systems to remove VOCs from the exhaust stream

exist, but are priced beyond the reach of smaller companies.


Manufacturers of polypropylene building materials must  represent

a  very small percentage of all of the coaters of plastic  parts,

but to require the same controls as recommended for manufacturers

of computer housings or toys would not be fair; it could in  fact

have  a crippling effects on our industry.  We would welcome  the

opportunity to review the Control Technology Guideline before its

final  promulgation, and would be happy to supply any  additional

information that might be of use to the NAPCTAC committee.
Sincerely,
Dale C. Jewries
Finishing Department Manager
Vantage Products Corporation

c.c. NAPCTAC Committee Members
                           10

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                               INDEX
 Abatement,  9
 Abrasion,  6,  8
 Acid,  7
 Additives,  3,  5,  7,  8
 Adhesion,  1,  2,  3,  6, 9
 Adsorption,  9
 Argon,  7
 Atmosphere,  5
 Auto-oxidative,  4

 Benzopherone,  7
 Bonding, 2
 Brayton, 9
 By-product,  7, 8

 Carbide, 5
 Carbon,  5,  9
 Catalytic,  9
 Chalking,  1
 Chlorinated,  3
 Chromate,  6,  7
 Coatings,  1,  3,  A,  6, 8, 9, 10
 Compounds,  1
 Corona,  6,  7,  8
 CPO,  3,  4
 Crosslinking,  4
 CTG,  1

 Degradation,  5
 Dichromate,  7
 Dielectric,  8
 Dioxide, 5

 Eastman, 3
 Emission,  1
 Emulsion,  3
 Evaporation, 4

 Fading, 1
 Flame, 6,  77 8
 Furniture,  1,  5

 Hg, 9

 Manufacturers, 4, 6,  8,  9,  10

 NAPCTAC, 10
Nitrogen, 7, 9
Non-ionizing,  4

Oxidation,  9
Oxidizing,  7

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Ozone, 5, 7, 8

Plasma, 6, 7
Polar, 2
Potassium, 7
Powder, 4
Pretreatment, 10

Rad iat ion, 4, 7
Rankine, 9
Recuperative, 9
Recyclable, 1
Recycled, 1, 5, 8
Reduction, 2, 9
Refrigeration, 9
Regenerative, 9

Smog-causing, 5
Solvents, 2, 5, 6
Stabilizers, 6
Sulfuric, 7
Summary, 9
Supercritical, 5

Tetrafluoromethane, 7
Toluene, 9
Trichloroethane, 5, 6

Ultraviolet, 4, 5, 7
Unicarb, 5
UV, 6, 7
                               "*. o

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                                                                              A- /
                    MOTOR VEHICLE MANUFACTURERS ASSOCIATION
                                      of the United States, Inc.

                7430 SECOND AVENUE, SUITE 300 • DETROIT, MICHIGAN 48202 • AREA 313-872-4311
                         TLXNO. 1009770 AUTOMAKERS DET. • FAX NO. 313-872-5400
Thomas H. Hanna                                                          December 11,  1991
President & Chief Executive Officer
     Mr. Bruce C. Jordan
     Director, Emission Standards Division
     U.S. Environmental Protection Agency
     Office of Air Quality Planning and Standards
     Research Triangle Park, North Carolina  27711

     Dear Mr. Jordan

           The Motor Vehicle Manufacturers  Association of the United States,  Inc.  made  a
     presentation to the National Air Pollution Control Techniques Advisory Committee (NAPCTAC)
     meeting on November 20, 1991, commenting on the Environmental Protection Agency (EPA)
     draft Control Technique Guidelines (CTG) on plastic parts painting.  We were pleased to find
     that some of our concerns were already being addressed by EPA and we hope that our comments
     will be seriously considered.

           Enclosed is a copy of the text that is a  companion to the presentation which provides
     much more detail than the outline used in the presentation.

           At the suggestion of Mary Jane  Clark, we are forwarding a copy of this document
     directly  to each of the members of NAPCTAC.

                                                   Sincerely,
                                                   Eugene A.  Praschan
                                                   Manager, Emissions and Control
     cc:     NAPCTAC Members
            James Berry  EPA
            Robert Nelson  NPCA
     MEMBERS:
        CHRYSLER CORPORATION • FORD MOTOR COMPANY • GENERAL MOTORS CORPORATION • HONDA OF AMERICA MFC INC
             NAVISTAR INTERNATIONAL TRANSPORTATION CORP. • PACCAR Inc • VOLVO NORTH AMERICA CORPORATION

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   COMMENTS TO UNITED STATES
   ENVIRONMENTAL PROTECTION
     AGENCY'S NATIONAL AIR
 POLLUTION CONTROL TECHNIQUES
      ADVISORY COMMITTEE
 REVIEW OF OCTOBER 1,1991 DRAFT
SURFACE COATING OF PLASTIC PARTS
 CONTROL TECHNIQUES GUIDELINE
       DURHAM, NORTH CAROLINA
          NOVEMBER 20, 1991
        Motor Vehicle Manufacturers Association
            of the United States, Inc.

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       My name is Joseph F. Lennon, Principal Facility Environmental Control Engineer, Environ-
mental Quality Office, Ford Motor Company.  I am here to speak in behalf of Motor Vehicle Manu-
facturers Association of the United States, Inc. (MVMA) to address our industry's concerns with the
draft Surface Coating of Plastic Parts Control Technique Guideline (CTG).  MVMA is in support of
the comments presented by the National Paint and Coating Association (NPCA).  MVMA member
companies with automobile plastic parts coating facilities located in Michigan worked with NPCA
member companies and Michigan Department of Natural Resources in the four year development of
Rule 632 and believe that rule represents a model for the plastic parts coating CTG for all the rea-
sons stated in the NPCA presentation.

The MVMA comments will address concerns of importance to users of the painted plastic parts and
related to the draft CTG. These concerns include the following:

       • Inadequate number of coating categories
       • Importance of need for compatible coalings in paint systems
       • Sensitivity to time required in coating approval process
       • Quality coatings to provide acceptable appearing paint finishes
       • Coatings that are durable to avoid customer repainting
       • Coatings that will not cause increased warranty costs
       • RACT control requiring add-on controls
       • Recognition of specialty coatings

       Each of these concerns will be briefly addressed below. In addition, several comments
specifically related to the draft CTG document will be included.
 Categories of Coatings.

       NPCA comments have addressed the need for additional categories of coatings for plastic
 parts. Much time was expended during the development of Rule 632 in an effort to determine how
 best to regulate the wide range of plastic/coating combinations that exist in plastic parts components
 for automobiles. After extensive discussion, the categories listed in Rule 632 were determined to be
 the best way to regulate the automobile plastic parts coating industry.

       The draft CTG is significantly different from Rule 632 in that two categories have been
 eliminated or moved into categories that are more restrictive in VOC content. These categories are
 air dry coatings and unique colors (such as reds and blacks) that need allowance for higher VOC
 content due to technical limitations. As appropriately described in Section 3 of the draft CTG, there
 are a number of plastic substrates (such as acrylonitrile-butadiene-styrene, polycarbonate and
 polybutylene terephthalate, polycarbonate, acrylic) that limit the coatings to cure at lower tempera-
 tures (at or below 194 F). These are referred to as air dried coatings. The draft CTG ignores this
 important category of coatings and places them in the same category as high bake coatings.  The
 coating formulations designed for these plastic substrates typically require higher quantities of VOC
 in order to allow the painted parts to retain the required performance characteristics.

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       The draft CTG should allow for a higher VOC content for certain color coatings such as the
reds and blacks. The higher VOC emissions from red and black coatings result from chemical
interactions that occur with the resins that are used in these coating colors.  These issues have been
addressed by the NPCA/MVMA work  group which submitted a lengthy document to EPA on Sep-
tember 17, describing the need for the air dried coating category and for VOC content credit for red
and black coatings. EPA should consider these documents before deciding on final CTG VOC
content emission limits.

       The VOC limits in the CTG appear not to recognize cure volatiles generated under Method
24 analysis. As footnoted in Rule 632, when Method 24 is used to determine VOC content of the
coating, then the applicable VOC limit is to be increased by 0.5 pounds of VOC per gallon.
Paint Systems.	

       The coating of a plastic part typically requires two or more paint layers to make up a total
paint system for specific plastic materials in order to achieve acceptable performance, considering
both initial appearance and functional durability properties. The CTG must recognize that even
though suppliers may have lower VOC primers for a given plastic substrate or lower VOC color
coatings, the combination may not be compatible.

       In other words, one cannot necessarily take the lowest VOC content prep-coat, primer,
basecoat, clearcoat and have a paint system that will meet all the performance/appearance require-
ments that the coated plastic part must meet. The VOC content of the different coating categories
may vary in order to design a coating system that is compatible for the needs of the plastic part being
coated.

       MVMA believes the CTG does not account for the fact that paint coating systems are de-
signed using compatible coating types rather than looking at the lowest VOC content coating in each
coating type and expecting them to perform as a functional coating system. MVMA does support
reduction of VOC content of coatings by reformulation for RACT level control that is reasonable to
achieve.
Approval process.

       The automobile companies require a very extensive and time-consuming approval process
for acceptable coating usage on automobiles.  There are numerous criteria that coatings must meet to
be approved for use on the product. Some of the approval tests are very lengthy in time (such as
exposure to sun tests, salt tests, etc.).

       Rule 632 has already driven coating suppliers to initiate research and development in refor-
mulation of coatings to meet the lower VOC content coating limitations contained in the Rule.
Coatings that have been developed as a result of that research are currently in different phases of the
approval process. The VOC content values listed in Table 5-1, Level 1 control would require the
suppliers to go back and incur additional costs for research and development to reformulate coatings
                                           • r-

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which are already reaching their limits to achieve the lowest VOC content for an approvable coating.
In addition, the approval process would have to begin anew for any new coatings that may result
from the reformulation to a lower VOC content.

       MVMA believes the VOC content values in Table 5-1, Level 1 would require duplication in
time and costs for both the research and development and the approval process efforts that have been
underway to meet Rule 632 VOC content limits. This could jeopardize the availability of having
approved coatings for production.
Quality.	

       The automobile industry competes in the world market place.  Foreign built automobiles
have placed great pressure on the domestic automobile manufacturers to be competitive on initial
appearance and quality of the paint finish. One of the major indications of quality that a customer
sees when he first views a car in a dealer showroom is the appearance and condition of the paint
finish. The paint quality must meet customer expectations! Obviously, it is critical that the appear-
ance of the metal and plastic parts match each other.  Coatings that are reformulated to meet RACT
values in this country must be developed to avoid inferior quality characteristics.  MVMA is con-
cerned that reformulated coatings to achieve the VOC content values included in Table 5-1, Level 1
control may fail to provide adequate perceived quality paint finish on the automobile.
 Durability.	

       The durability of the automobile paint is expected to withstand the washing, waxing, weather
 elements, etc. for a time period of at least 7-10 years.  Paint durability of plastic parts must withstand
 normal owner maintenance practices while retaining color-match between plastic and metal compo-
 nents and acceptable paint appearance. If the draft CTG were to lead to the premature use of paint
 that does not meet durability requirements, then repainting may be necessary. Obviously repainting
 results in more overall VOC emissions than would occur with an initial but durable paint application.
 The need to repaint the automobile could cause the customer to avoid purchase of that vehicle
 nameplate in the future. MVMA believes paint durability could be adversely affected as a result of
 reformulated coatings to a lower VOC content.
Warranty.

       Warranty complaints are a major concern to the automobile companies.  Warranty issues can
be a costly problem in terms of customer loyalty as well as financial considerations. Reformulation
of coatings that are already on the cutting edge of technology in order to meet Rule 632 VOC con-
tent levels may lead to an increase in warranty complaints and subsequent loss of customers.
MVMA believes warranty complaints would increase with reformulated coatings to meet the VOC
content limits proposed in Table 5-1, Level 1 control. Further, even if the technology should be-
come available, warranty complaints could increase because new coatings may have to be rushed
into production prior to completion of all testing required for full approval.

                                       - r-ry

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Add-on Controls.
       The VOC content limits in Rule 632 represent RACT for plastic parts painting processes.
Rule 632 provides for reformulation of coatings and requires the use of advanced application equip-
ment which, in effect, reduces the actual VOC emission rate and could result in an overall environ-
mental impact to be equivalent to those shown in Table 5-1, Level 1.  However, Table 5-1, Level 1
VOC content  emission limits for exterior coatings would require add-on control technology resulting
in a significant economic impact on all automobile plastic parts coatings facilities.

       One of the primary objectives in the development of Rule 632 was to recognize an appropri-
ate RACT VOC content limit for plastic parts coatings that would not require add-on control equip-
ment, but rather a value that would result in forcing technology toward development of reformulated
coatings. The reason for this approach was a recognition of the many small job shops conducting
plastic parts coating operations for the automobile industry. Retrofitting add-on controls on existing
coating facilities is costly and could result in forcing many smaller facilities out of business. The
VOC content  limits contained in Rule 632 substantially met that objective.

       The draft CTG contains VOC values in Table 5-1, Level 1, that do not appear technically
achievable through reformulation of the coatings.  Therefore add-on controls would be the only
method available to achieve these VOC content coating limits. Despite a number of technically
questionable assumptions in determining the cost of add-on controls (i.e., all available VOC emis-
sions assumed to be captured for control; assumption that normal VOC destruction efficiency for
incinerator is  98%), cost per ton for VOC removal are considered to be very high for RACT control.
MVMA is aware of LAER (Lowest Achievable Emission Rate) permit reviews where costs for VOC
removal in the $25,OQO/ton range were considered excessive for the LAER source.  The costs for
add-on control equipment in the draft CTG (even with technically questionable VOC levels) exceed
costs in some LAER permits.

Specialty Coatings.

       The automobile plastic parts coating operations include a large number of specialty coatings
(such as, adhesive prime, electrostatic prep, resist, stencil, texture, vacuum metalizing, gloss reducer,
etc.) that are designed for unique purposes. These coatings usually consist of a high VOC content
but generally  are not used in large volumes and are not conducive to reformulation to lower VOC
content levels. Rule 632 included an exemption for these specialty coatings. MVMA recommends
that the CTG  include either an exemption for these coatings as was done in Rule 632 or provide
specific VOC content values that are reflective of these specialty coatings.
Additional Comments.

       The following additional comments are made regarding specific concerns in the draft CTG:

    • Table 3-4, pages 3-30 thru 3-41. The transfer efficiency (TE) for high volume, low pressure
     (HVLP) applicators is assumed to be 50%.  MVMA test data shows that this value is too high.
     Obviously TE is contingent on many factors including part design but test data for coating

                                           " •'"*' P1
                                             ^O

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    bumpers with HVLP's show about a 32% TE. Page 3-42 of the CTG states that HVLP's and
    electrostatic applicators yield 50% without any basis or explanation for that value. The test
    data from the same bumper coating operation which combines the use of HVLP's and electro-
    static applicators demonstrated an overall TE of about 32%.

   • Section 5.1.1. This section states that there are three points of VOC emissions in the coating
    of plastic parts (spray booth, flash-off areas and curing oven). However, there are other related
    sources of VOC emissions from automobile coating operations - such as, the water pits, paint
    supply tanks and building vents.  Future tests are expected to lead to a greater knowledge of the
    VOC emission points encountered during the coating of plastic parts. It is inappropriate for the
    CTG to use the assumption that 100% of the VOC available in a plastic parts coating operation
    is captured for control purposes.

   • Section 7.3.2. MVMA recommends that in operations where  both plastic and metal parts are
    being coated, the least restrictive coating limitations should apply.

   • Section 7.8.3. The last sentence in this section suggests performance tests may be required
    every "6 months or quarterly". This is unreasonable, impractical and costly. MVMA recom-
    mends that performance tests may be conducted after major breakdowns or where significant
    portions of the control equipment have been replaced.

This concludes the MVMA comments.
                                      {19
                                          fj

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£30

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    1.0  U.S. ENVIRONMENTAL PROTECTION AGENCY'S  PRESENTATION
               ON THE OFFSET LITHOGRAPHIC PRINTING
                  CONTROL TECHNIQUES GUIDELINE
1.1  PRESENTATION
INTRODUCTORY REMARKS
    My name is Donna Lee Jones.  I am with Radian Corporation,
the contractor on the Offset Lithographic Printing Control
Techniques Guideline.  I would also like to introduce Karen
Catlett, the EPA Work Assignment Manager on this project.

INTRODUCTION TO THE CTG
(Slide 1)
    In the next few minutes I will present to you a description
of the offset lithographic printing industry, the sources of VOC
emissions and possible control strategies, and the results of
EPA's regulatory analysis.
(Slide 2)
    It may be possible to characterize the graphic arts industry
into 5 types of printing, of which offset lithographic printing
is one.  The printing types can be characterized in the following
ways:
    (1)  Rotogravure  has  recessed images.
    (2)  Flexography  and  letterpress have  raised letter/images.
    (3)  Offset lithography has chemically differentiated  image
         and non-image areas.
    (4)  All printing types use direct printing except offset
         lithography, which uses indirect  printing.
    In offset lithography, the letters or images are not  raised
or depressed surfaces, but are chemically differentiated  so that
the image area is oil-receptive and accepts the oil-based inks
and the non-image area is water-receptive and does not accept the
inks.
                                1
                             631

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    The CTG and this presentation will only address offset
lithographic printing.
    There is currently a New Source Performance Standards for
publication rotogravure and a CTG for graphic arts (rotogravure
and flexography); a National Emissions Standard for Hazardous Air
Pollutants for all printing types is under development.
    Some example products of offset lithographic printing are
items that we use everyday, such as:  advertisements, business
forms, cereal boxes, greeting cards, telephone directories, and
newspapers.  However, this list is by no means complete and these
products are not limited to the offset lithographic printing
process only-
(Slide 3)
    There are 16,500 offset lithographic printing facilities in
non-attainment areas that contribute 378,000 tons VOC; 1,500 of
these facilities have the potential to emit over 100 tons per
year.
(Slide 4)
    Inks, fountain solution, and cleaning solutions are the
major sources of VOC emissions in Offset Lithographic printing.

THE OFFSET LITHOGRAPHY PRINTING PROCESS
(Slide 5)
    The following is a schematic of an offset lithographic
printing unit, this unit is for illustration only, and is not
intended to exactly replicate a true printing unit.
    A unit is the smallest complete component of a printing
press and can print only one color.  Up to 12 units can be used
in a row, and multiple colors can be printed.  The substrate is
usually paper or cardboard; web or sheet.
    Fountain solution wets the non-image areas of the printing
surfaces so that the ink stays where it is supposed to.  Fountain
solution is a mixture of water, non-volatile printing chemicals,
and an (liquid)  additive that reduces the surface tension of
water so that it spreads across the printing plate surface.
Isopropyl alcohol (a VOC) is the most common additive and is the
source of VOC emissions in the fountain.

                            6322

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    Heatset inks require the addition of heat, via hot-air
dryers, to set.  The VOC's emitted are due to the hydrocarbon
oils contained in the inks.  Non-heatset inks set by oxidation or
adsorption without the use of heat.  Most of the VOC's in non-
heatset inks are retained by the substrate.
    One of the issues we considered with non-heatset inks was
what ultimately happens to the VOC's in the substrate.  Although
no VOC's are expected to be emitted in the normal handling of the
products, the waste handling methods may regenerate the VOC's.
We found that there were three possible outcomes for non-heatset
printed material: landfill, municipal waste combustion, or
recycling.  Most paper goes to a landfill at the moment and only
some is recycled.  It has been estimated that only 7 percent of
paper products go to a municipal waste combustor.  We have
considered the "ultimate fate" of non-heatset products in these
waste handling methods and have concluded that large potential
sources of VOC's from these waste handling methods will be
controlled and therefore we have not addressed this issue in the
CTG.
    Cleaners are used to clean printing surfaces, ink, and
fountain rollers and press exterior surfaces.  Most traditional
cleaning products are 100 percent VOC.

MODEL PLANTS
(Slide 6)
    Based on these printing characteristics we have divided the
industry into four segments (heatset web, non-heatset web (non-
newspaper), non-heatset sheet, newspaper (non-heatset web)),
according to the distinguishing features that I have just
mentioned:
        Whether the press uses dryers (heatset)  or not  (non-
        heatset) ;
        The type of substrate: sheet-fed (sheet  feed) or web
         (web substrate); and
        Newspaper (nonheatset-web) printers were placed in  a
        separate industry segment since the newspaper printing
        process does not use alcohol.

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    Emissions of VOC's are from inks (due to hydrocarbon oils),
fountain solutions (due to alcohol), and cleaning solutions (due
to the solvents).
    At least four facility sizes were used for each industry
segment for a total of 18 model plants in each of the four
industry segments.

EMISSION CONTRIBUTIONS
(Slide 7)
    Using the model plants, the relative VOC emissions of each
industry segment were calculated to demonstrate the potential
emissions of one plant.  This analysis does not take into account
the number of plants in each segment of the industry.
    This table shows the emissions of large uncontrolled model
plants in each industry segment relative to each other.  Non-
heatset sheet ink emissions were set equal to 1, for comparison
purposes only.
    For instance, the VOC emissions from the fountain solution
in the non-heatset sheet model plant are 100 times the ink
emissions.
    For ink emissions, heatset web, as expected, has the highest
potential emissions.
    For the fountain solution, the web processes have the
highest amount of emissions.  The emissions in the web processes
are greater than any other source from the fountain solution and
are greater than the total emissions of the other two industry
segments.
    Cleaners are the second largest source of emissions in all
but one of the segments (heatset web).
    The next slide shows how the distribution facility sizes and
number of facilities effects the emissions profile.
(Slide 8)
    We used the model plants to estimate the baseline VOC
emissions in non-attainment areas.  These estimates were obtained
by multiplying the emissions of a particular size model plant by
the number of facilities of this size estimated to be in non-
attainment areas from industry surveys and population data.

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    In this estimate we have taken into account add-on controls
used in the heatset industry and the use of alcohol replacements
in all industry segments, including the newspaper industry.
    From this we learned that approximately 2/3 of the emissions
are from web and less than 1/3 from sheet-fed, with newspaper
contributing less than 1 percent of the total.
    This slide differs from the previous slide because it takes
into account the size distribution of facilities of each industry
segment within non-attainment areas.

CONTROL OPTIONS - INKS
(Slide 9)
    We looked into the control of VOC emissions from the inks,
fountain solutions, and cleaning solutions.  First I will talk
about the inks.  We investigated the methods of controlling VOC
emissions from a dryer exhaust where heatset inks are used.
    Incinerators (both thermal and catalytic) were one option;
these devices are designed to achieved 98 percent control.
    Another method of control is condenser filters, which are
devices that use room air to cool and condense the hot exhaust
vapors into droplets that are filtered from the exhaust stream.
This type of control can achieve 90 percent control.
    To increase the amount of control from 90 to 95 percent, an
activated carbon bed may be added to condenser filters.  When
activated carbon is used, the residual emissions from the
condenser filter are collected in the carbon bed, which can be
regenerated with steam or hot air.
    Since the ink needs to be water-repellent, water soluble
inks were not an option we considered.  Reformulation to lower
VOC inks does not produce significant VOC reductions, since, as
discussed earlier, the majority of the VOC is retained by the
substrate.
(Slide 10)
    We have estimated the annual costs of these options for the
model plants.  Shown here are the largest and smallest model
plants for the heatset web industry.  Reductions range from 22.2
to 24.2 tons per year for very small facilities; 178 to
                                5
                             635

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193.8 tons per year for large.  The percentage of VOC's reduced
range from 90 to 98 percent.  The costs range from $50,000 to
$73,000 for very small facilities; and from $230 to 336,000 for
large plants.  The cost-effectiveness of the controls ranges from
a low of $1,300 for every ton of VOC removed per year for large
facilities to $3,000 per ton for very small facilities.
(Slide 11)
    The EPA staff recommendations for control are 95 percent.
All staff recommendations have not been through final review by
the EPA.  The rationale for choosing 95 percent, is that this
level gives a high degree of control while allowing for
flexibility in control options (three).
    One of the available options that is particularly desirable
is a condenser filter with carbon, since these devices do not
generate nitrous oxides and the recovered VOC's can be used as a
fuel for the dryer.
    Add-on controls are already being used by over 60 percent of
the heatset facilities (incinerators = 48 percent and condenser
filters = 13 percent).  This information came from a 1990 web
offset survey.

CONTROL OPTIONS - FOUNTAIN SOLUTION
(Slide 12)
    The options for control of VOC's from the fountain solution
address the issue of alcohol use; the more alcohol that is used,
the more VOC's that are emitted into the atmosphere.
    Refrigerating the alcohol does help, since colder
temperatures reduce the evaporation rate of alcohol.
    Alcohol substitutes are available that also reduce the
surface tension of water.  Alcohol substitutes also have a lower
volatility than alcohol and are used in smaller amounts;
therefore, VOC emissions are reduced significantly when they are
used.
    From an uncontrolled baseline estimated to be 17 percent
alcohol in the fountain solution, we considered four types of
emission reduction techniques to reduce VOC emissions from the
fountain solution:  reduce alcohol concentration, refrigerate the

                             636

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fountain solution, a combination of reduction and refrigeration/
and the use of alcohol substitutes.
    Many printers already have switched to alcohol substitutes
to lower the exposure of their employees to the fugitive
emissions of alcohol.
    Although some printers feel that alcohol substitutes are
less forgiving than alcohol in some situations in terms of
achieving the same quality product, we have found that many
facilities have achieved good quality products with training of
employees, management commitment, and good press maintenance.
    From surveys of the industry we found that alcohol
substitutes are used successfully in all types of printing.
(Slide 13)
    The emission reductions with the various options range from
41 to 93 percent for the three categories:  reduce alcohol
concentration, reduce and refrigerate the fountain solution, and
use alcohol substitutes.
    Reduction to 10 percent alcohol is estimated to be give a
low of 41 percent reduction in VOC emissions from the fountain
solution and the use of alcohol substitutes gives 93 percent
reduction in VOC emissions, which is the highest.
    Moving down the list you will notice that at one level of
alcohol, e.g. 3 percent alcohol which is 82 percent control, the
same level of control can be achieved with refrigeration (82
percent) but with a higher level of alcohol (6 percent).
    Alcohol substitutes achieve at least 93 percent reduction,
however, only when the baseline is 17 percent alcohol.
    Care must be taken, however, because some, but not all, of
the alcohol substitutes or non-alcohol additives contain one of
the 190 hazardous air pollutants that are listed in Title I of
the new CAAA.
(Slide 14)
    Here are the EPA staff recommendations for the reduction of
VOC emissions from the fountain solution.  The required level of
control will be based on whether the facility:  is a newspaper
facility, uses web as a substrate, is a large sheet-fed facility
                            637

-------
(defined to have a total of 24 or more units in the entire
facility), or has fewer than 24 sheet-fed units total.
    Since the newspaper industry is already using non-alcohol
additives, this is the level of control they need to maintain.
The 93 percent control doesn't really correspond to the newspaper
industry because non-alcohol additives have been used by this
segment of the industry for a long time.
    The recommendations for the other types of printing were
based on the fact that, theoretically, alcohol substitutes can be
used by all segments of the industry.   But, since alcohol may be
needed for some specific jobs, we have allowed the use of a small
amount of alcohol for web facilities,  equal to 1.6 percent
alcohol, 3 percent alcohol with refrigeration or higher (i.e.
alcohol substitutes).
    Sheet-fed facilities are known to have a unique problem with
reducing alcohol due to the fact that this process has many stops
and starts and resetting of the presses, which leads to a greater
need for alcohol.  Therefore, we have allowed the use of more
alcohol for sheet-fed facilities, equal to 3 percent alcohol.
    Because the smaller sheet-fed facilities are less likely to
be able to cope with the changes necessary to significantly
reduce alcohol and switch to alcohol substitutes, we have allowed
the other sheet-fed facilities (with less than 24 units) an even
greater operational flexibility, to use a slightly higher level
of alcohol than the large sheet-fed facilities, equal to 6
percent alcohol.
    Through surveys of the industry we have found facilities in
all these categories that are using little or no alcohol and
producing quality products.

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(Slide 15)
    The VOC emission reductions ranged from 0.8 to 696 tons per
year, for small to large model plants, respectively.  For each
recommendation there was one option that produced a savings due
to reduction in alcohol costs.

CONTROL OPTIONS - CLEANING SOLUTION
(Slide 16)
    We looked at the options for cleaning solutions and found
that the lower VOC cleaners (less than 100 percent) formed two
groups: 75 percent and 30 percent VOC.  We looked at these two
groups of competitive products that reduce the amount of VOC's in
cleaners.  However, when we compared the ingredients in the
cleaning solution to the 190 Hazardous Air Pollutants in the new
CAAA, we ruled out the 25 percent reduction level (75 percent
VOC) because most of the cleaners appeared to contain one or more
of the Hazardous Air Pollutants.
    Therefore, the EPA staff recommendation for control of VOC's
from cleaning solution is the 70 percent reduction cleaners
(30 percent VOC).
(Slide 17)
    The VOC emission reductions with this control ranged from
0.8 to 39 tons per year, for small to large model plants
respectively.  The costs ranged from $550 to $24,000 over the
cost of traditional cleaners.  The cost-effectiveness was
$629 per ton of VOC removed.

NATIONAL IMPACT OF CONTROL RECOMMENDATIONS
(Slide 18)
    Using the model plants and the estimated distribution of
facilities in ozone non-attainment areas, we again calculated the
potential VOC reductions from all three sources of emissions (by
multiplying model plant emissions by the number of facilities in
non-attainment areas times the percent uncontrolled).
    There were 277 thousand tons of VOC removed by the
recommended control options.  This corresponds to a cost-

-------
effectiveness of control that ranges from $55 to $650 per ton for
an overall average of $250 per ton.
    These costs do not include the potential savings due to
reduction in alcohol costs.

IMPLEMENTATION
(Slide 19)
    Implementation of these recommendations would entail
compliance testing and more frequent monitoring.  For the add-on
controls, the compliance tests required are EPA Method 25 or 25A,
as well as a record of the product used (heatset or non-heatset
ink).   Monitoring requirements are temperature and residence time
measurements.
    The fountain solution compliance requirements are a modified
EPA Method 24 test for VOC content and record of the product used
(alcohol or substitute).  A hydrometer can be used to monitor the
fountain solution with alcohol only-   If the fountain solution is
refrigerated, the xonly compliance test necessary is a temperature
measurement, which can also be used for monitoring.
    The cleaning solution compliance requirements are a modified
EPA Method 24 test for VOC content.  There are no specified
measurement techniques for monitoring the cleaning solution.
                            640
                                10

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   CONTROL TECHNIQUES

          GUIDELINE

Control of Volatile Organic Emissions from
Offset Lithographic Printing
          NAPCTAC Meeting
            Presentation
           November, 1991
              641

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              OFFSET
   LITHOGRAPHIC PRINTING
Outline of Presentation
•  Definitions and Description of Industry
•  Sources of Emissions
•  Options Analysis
  • Available Controls
  • Costs of Control for the Model Plants
  • Staff Recommendations
•  National Emission Reductions and Costs
                 6421

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GRAPHICS ARTS INDUSTRY
     •  Offset Lithography
     •  Flexography
     •  Rotogravure
     •  Letterpress
     •  Screen
            643 2

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CONTRIBUTION OF OFFSET
 LITHOGRAPHIC PRINTING
   Approximately 16,500 facilities in
   non-attainment areas

   Approximately 378,000 tons per year of
   VOC's emitted in non-attainment areas

   More than 1500 facilities have the
   potential to emit over 100 tons per year
   emissions

-------
   SOURCES OF VOC
 EMISSIONS IN OFFSET
LITHOGRAPHIC PRINTING

    • Inks
    • Fountain Solutions
    • Cleaning Solutions
         645 4

-------
            In-feed
Ul
                                          Unit
                             Substrate
                           (usually paper)
                                      Fountain
                                      Solution
ink
           Dryer
        (heatset only)
                                                         Hot Air
                 Finished Product
                                                         Hot Air
                                                        No Dryer in
                                                        Non-heatset
            OFFSET LITHOGRAPHIC PRINTING SCHEMATIC

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     OPTIONS ANALYSIS
Four industry segments
    • HeatsetWeb
    • Non-heatset Web (non-newspaper)
    • Non-heatset Sheet
    • Newspaper (non-heatset web)
Each of the three emission sources was
analyzed separately
18 model plants were used to characterize
the industry
               6476

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 RELATIVE VOC EMISSIONS
          BASED ON
   LARGE MODEL PLANTS

Industry	Inks   Fountain  Cleaners Total
HeatsetWeb     1000    3000     100   4100
Non-heatset Web  50    4000     100   4150
Non-heatset Sheet   1     100     100    200
Newspaper     160    60     300    520
              648^

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   ESTIMATED NATIONAL
     VOC EMISSIONS IN
 NON-ATTAINMENT AREAS
           Number of     Baseline
           Facilities       VOC
Industry in Nonattainment
Segment Areas
Heatset Web
Non-heatset Web
Non-heatset Sheet
Newspaper
Total
400
1,000
15,000
300
16,700
Emission
(TRY)
142,000
136,000
97,000
2,000
377,000
       MnHol Plant   * Facilities in
Emisions = E±,fonS x  Non-attelnment x % uncontrolled
             6498

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       CONTROL OPTIONS
             FOR INKS
*  Add-on controls to the dryer exhaust

Device                   Percent Control
Incinerators (thermal and catalytic)       98
Condenser filters with activated carbon    95
Condenser filters                  90
  Waterborne inks are not an option
  Reformulation was not a significant
  control option
                 G50

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COST OF CONTROL OF VOC
  EMISSIONS FROM INK

Model
Plant
Very
Small


Large




Type of Control
Equipment
Incineration
Condenser/Filter with
Carbon
Condenser/Filter
Incineration
Condenser/Filter with
Carbon
Condenser/Filter

Reductions
Tons/yr
24
23

22
194
188

178
Total
Percent
Reduced
98
95

90
98
95

90
Estimated
Annualized
Costs
$73,000
$69,000

$50,000
$336,000
$290,000

$230,000
Cost
Effectiveness
$/ton
$3,000
$3,000

$2,300
$1 ,700
$1,500

$1,300

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STAFF RECOMMEDATIONS

          FOR INKS

95 percent reduction of VOC in the
dryer exhaust


    • thermal incinerators

    • catalytic incinerators

    • condenser filters with carbon
             652^

-------
       OPTIONS FOR THE
     FOUNTAIN SOLUTION
1.  Reduce alcohol concentration from an
   industry average of 17 percent (by volume)
2.  Refrigerate fountain solution
   containing alcohol to below 60°F
3.  Combinations of 1 and 2
4.  Replace the alcohol with substitutes
               653 1:

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FOUNTAIN SOLUTION

        OPTIONS

        Reduce Alcohol

    Alcohol        Percent VOC
   Concentration      Reduction

     10%            41
      6             67
      3             82
      1.6            90

       Refrigerate Alcohol

    Alcohol        Percent VOC
   Concentration      Reduction

     17%            44
     10             67
      6             82
      3             90

     Use Alcohol Substitutes

    Alcohol        Percent VOC
   Concentration      Reduction

      0%            93
            (554i3

-------
 STAFF RECOMMENDATIONS
  FOR FOUNTAIN SOLUTION
Newspaper
     r_r_.

   Use of non-alcohol additives             control

Web

   The equivalent of 1.6 percent VOC (by volume)
     •  1.6 percent (by volume) alcohol, or          90%
     •  3 percent elcohol with refrigeration        Control

Large Sheet-fed

    The equivalent of 3 percent VOC (by volume)
     •  3 percent alcohol, or                  82%
     •  5 percent alcohol and refrigeration        control

Other Sheet-fed

   The equivalent of 6 percent VOC (by volume)
     •  6 percent alcohol, or                  67%
     •  10 percent alcohol with refrigeration       Control
                  S551(

-------
   EMISSION REDUCTIONS
      AND COSTS FOR
    FOUNTAIN SOLUTION
• 0.8 to 696 TPY for the model plants

Costs

• Savings

-------
       OPTIONS FOR
  CLEANING SOLUTIONS
25 percent VOC reduction
  •  75 Percent VOC (by weight), as used
70 percent VOC reduction
  •  30 Percent VOC (by weight), as used
               16

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   EMISSION REDUCTIONS
      AND COSTS FOR
    CLEANING SOLUTION
  • 0.8 to 39 TRY
Incremental Costs

  • $550 -$24,100 per year
  • $629 per ton of VOC removed
              17

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   NATIONAL IMPACT OF
 RECOMMENDED OPTIONS
Facility Type
Heatset Web
Non-heatset Web
Non-heatse Sheet
Nev paper
Total
Number of
Facilities in
Nonattainment
Areas
400
1,000
15,000
300
16,700
Total VOC
Emissions
Removed (TRY)
125,000
91 ,000
60,000
700
277,000
Cost*
Effectiveness
($/ton)
$288
$55
$350
$650
$250
*Excludinc the large savings in alcohol costs
            .659.
             18

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                    IMPLEMENTATION
Control/Emission
   Reduction
  Technology
             Compliance
 Monitoring
  Add-on Controls
 EPA Method 25 or 25A test
 Records of product used (heatset or nonheatset ink)
 Temperature
 Residence time
 Fountain Solution    - Modification of EPA Method 24 test for VOC content    - Hydrometer
                  - Records of product used (alcohol or substitute)         (alcohol only)
   Refrigeration
- Temperature measurement
- Temperature
    Cleaners
- Modification of EPA Method 24 test for VOC content

-------
   CONTROL TECHNIQUES

          GUIDELINE

Control of Volatile Organic Emissions from
Offset Lithographic Printing
            Appendix

-------
              OFFSET

   LITHOGRAPHIC PRINTING

A process where the image and non-image
areas are on the same plane and are chemically
differentiated so that the image area is oil
receptive and the non-image area is water
receptive
A process that transfers the printing image to an
intermediary surface, which, in turn, transfers
the image to the printing substrate
                   ,-2

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 EXAMPLE INDUSTRY
      PRODUCTS

• Advertisements
• Books
• Business Forms and Brochures
• Catalogues
• C areal Boxes
• G reeting Cards
• L ibels and Wrappers
• haps
• Pharmaceutical Instructions
• Telephone Directories
• Newspapers
             ,-3

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            DEFINITIONS

                   Unit

  The smallest complete component of a printing
     press; each unit can print only one color
                  Press

A printing production assembly that can be made up
       of one or many units to produce a
              finished product
                    ,-4

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TWO TYPES OF SUBSTRATES

                 Web

     A continuous roll of paper used as the
            printing substrate


               Sheet-fed

     Printing paper that is fed to the press in
            individual sheets
                665A_5

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  TWO TYPES OF PRINTING

                Heat-set

   Printing inks that require the addition of heat
                 to set
               Non-heatset

Printing inks that are set by oxidation or adsorption
  without the use of heat. Most of the VOC's in
       non-heatset inks are retained by
               the substrate

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ULTIMATE FATE OF
NON-HEATSET INKS
  Landfill
  Municipal Waste Combustion
  Recycling
        G G 7^.7

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    FOUNTAIN SOLUTION

Fountain solution wets the non-image areas
so that ink stays within the hydrophobic
image areas

A mixture of water, non-volatile printing
chemicals, and an (liquid) additive that
reduces the surface tension of water.

Isopropyl alcohol (a VOC) is the most
common additive

Alcohol substitutes are available that replace
the alcohol and reduce VOC emissions from
the fountain solution.

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   CLEANING SOLUTION
Used to wash printing surfaces, ink and
fountain rollers, and press exterior surfaces
               A-9

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  MODEL PLANTS AND
ESTIMATED ANNUAL VOC
EMISSIONS (tons per year)



Model
Plant
Cod*
A-l
A-ll
A-lll
A-IV
B-l
B-ll
B-lll
B-IV
C-l
C-ll
C-lll
C-IV
0-1
D-ll
D-lll
D-IV
D-V
D-VI





Size
Very Small
Small
Medium
Large
Very Small
Small
Medium
Large
Very Small
Small
Medium



Total
Printing
Units
4-6
6-16
12-32
32-48
4-6
6-16
12-32
32-48
1 -4
2-8
8-24
Large 24-48
Very Small
Small
Medium
Medium Large
Large
Very Large
6
8-10
9-24
18-48
40-96
100-120

Ink



Use
77
170
340
618
77
170
340
618
1
2
6
13
10
48
138
477
1088
2156



VOC
Emissions
25
54
109
198
1
3
5
9
0.01
0.02
0.1
0.2
0.2
1
2
7
16
32

Fountain Solution
Additive



Use
70
153
306
556
97
212
425
773
1.2
2.3
7.5
17
0.7
3.4
10
33
76
151



VOC
Emissions
70
153
306
556
97
212
425
773
1.2
2.3
7.5
17
0.5
2.5
7
25
57
113


Cleaning Solution



Use
2
5
11
20
2
5
11
2
1
2
8
17
2
5
8
16
34
55



VOC
Emissions
2
5
11
2
2
5
11
2
1
2
8
17
2
5
8
16
34
55



Total
Annual
VOC
Emission
97
213
426.
774
100
220
441
802
2
4
16
34
2
9
17
48
107
200

        670
          A-10

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 NATIONAL IMPACT OF
  CONTROLS ON VOC
 EMISSIONS BASED ON
MODEL PLANT ANALYSIS



Modal Plant
Typa

A






Facility Size
1
II
III
IV
Subtotal

B


1
II
III
IV
Subtotal

C


1
II
III
IV
Subtotal

0





1
II
III
IV

V
VI
Subtotal
Total

Number of
Facilities In
Nonattalnnwnt
Areas
41
63
153
152
409
70
240
567
204
1,090
6.634
5,910
1.301
858
14.703
188
42
19
10
4
2

265
16,497
Total VOC Emissions (TRY)



Baseline
2.859
9.616
40.730
83.628
142,435
2.010
15,841
71,726
46,896
136,473
14.515
37.673
17,960
26,718
96.867
427
317
302
438
385
358

2,227
378,001



Removed
2.500
8,408
40.730
73,519
125,157
1,345
10,460
47.741
31.226
90.773
9,840
17,628
12,167
19.756
59.391
197
132
109
115
95
77

725
276,046


After
Control
359
1,208
5.602
10,109
17,278
666
5,381
23,984
15.669
45.700
4.676
20.045
5.793
6.962
37,476
229
184
193
323
291
281

1.501
101,955
        (571
         A-11

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                                                                       TELEPHONE (7O8)-295-1 331
                                                                       FAX (7O8)-295-0732
                          RESEARCH LABORATORIES, INC.
                  990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
                              LAKE BLUFF. ILLINOIS. 6OO44
 October 22,  1991
 Mr.  Bruce  Jordan
 Director
 Emission  Standards  Division
 United  States  Environmental  Protection  Agency
 Office  of Air Quality Planning & Standards
 Research Triangle Park,  NC  27711

 Dear Mr. Jordan:

 As  president of Rosos  Research  Laboratories,  Inc.  and  manufacturer of  the
 original alcohol  replacement, RV  1000, in  1970, I have  the  benefit  of over  21
 years  of experience  in  the  area  of  pressroom  alcohol  elimination.    Rosos1
 motivation  in  the  early  1960's  to  eliminate  isopropyl  alcohol  stemmed from
 pressmen's  complaints  of  headaches  and  nausea caused  by  fugitive  alcohol
 emissions and  variations  in  color stability  and  print  quality  relative  to alcohol
 evaporation   fluctuations.   We  are  proud  to  be  the pioneering  proponents  of
 alcohol elimination  and  in that  spirit,  completely  support  the  premise  of  the
 "Offset Lithographic  Printing  Control  Techniques Guidelines".   Please  permit
 me  to  compliment  you and  the  Radian Corporation  team for  presenting  a well
 researched, definitive CTG.  Since public  comment is solicited  on  page  1   2 of
 the   draft,  I  feel  compelled  to  bring several  issues  to your  attention   which
 unless  clarified  could  create  confusion  in  an  industry which  is  anxious  to
 comply with all  federal and state Control  Techniques Guidelines.

 Since  1950,  Rosos  has specialized  exclusively  in  fountain  solutions  and alcohol
 free  dampening  technology.   Consequently, my  remarks  will  be  limited to  this
 area.   The  first  issue  is  one  of  semantics.   Most printers  are familiar  with  the
 terms,   "alcohol   replacement"   or    "alcohol  substitute"  with  reference  to
 products  containing  75 -  78%  butyl  cellosolve  or  glycol  ether based wetting
 agent.   "Non alcohol additives" is a rather unfamiliar term to  most printers,  but
 one  which  is frequently  utilized  throughout the draft.    This  term may  tend to
 confuse  some   printers  who  might   consider  non-alcohol   additives  to   be
 different  in  chemical make up  than alcohol  substitutes  or replacements.

 On page  2 - 8 and  again  on page 5   7 the erroneous notion is  put forth  that "All
 of the  fountain  solution,  including  the water,  evaporates  after  delivery  to  the
 printing plate because  of  the  heat  and work of the  system on the  solution;  no
•water or alcohol  are disposed  of."  This is true for alcohol  only;  water,  fountain
 solution and wetting agents or  alcohol substitutes  become emulsified  in the  ink
 at whatever  percent or  ratio  the   ink is designed to  pick  up water.   In  addition,
 some   dampening  chemistry  is   transferred  beyond  the  plate   to  the  inking
 train,  or  the  blanket  and  eventually the substrate in all   offset  operations.
 Emulsion of  ink  and water is.  the lithographic  process.
                                      O
72

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                                                                      TELEPHONE (7O8)-295-1 331
                                                                      FAX (7O8)-295-0732
                         RESEARCH LABORATORIES, INC.
                 990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
                             LAKE BLUFF. ILLINOIS, 6OO44
The  next is the  issue  of failure  to  delineate  the distinction between two step
and  one  step  alcohol  elimination.    Alcohol   replacements  or substitutes  are
mixed  at a  0.5  -  3% or 1  -  4 ounces ratio per gallon of water and all require the
addition  of fountain solution at 1    2%  to  desensitize non-image  areas  of the
plate.   This is  commonly  known as  the two  step  method  of alcohol elimination.
On page 3  - 40 a "one step" solution  is  vaguely  mentioned.

As the formulator of the  original  one  step  solution  and the person  who  coined
the phrase,  I would like  to offer the following definition.   A one step solution  is
a  natural   Sudanese  Gum  Arabic based  formulation  which   incorporates  9%
wetting agent  (usually a  member  of  the glycol ether  group)  in the  concentrate
product  as the   requisite  alcohol  replacement.    One  step  solutions  are
recommended  to  be run  at  3% concentrations  or  0.27%, by weight,  VOC's  of
press  ready dampening chemistry  on brush  systems;  or 4    5% concentrations
on continuous   dampening  systems,  (note the figure  illustrated by  page  3-21
or  3  -  29),  or  0.36%    0.45%  by  weight VOC's of  press   ready  dampening
chemistry.    One  steps  eliminate the need for  15    25%  alcohol  on web  and
sheetfed    presses   and   are   monitored   by   conductivity   to   determine
concentration  of  fresh  solution.

One step  solutions offer   the  lowest  achievable level  of  VOC's in  press  ready
dampening  chemistry  with  the exception  of  the  latest  generation  of  totally
non-hazardous,  VOC  free  "one step"  formulations  (R.O.  #50, R.O.  #50 D3)
developed by Rosos from 1988    1991.

On  page  5  -  7  a formula  for calculating alcohol  replacements or   "non-alcohol
additives"  is  postulated.    Since no  formula  for one  step  solutions  is  currently
provided,  I would like to  suggest  the following:

VOC emissions from     =   weight of VOC x 0.09
one  step  solutions         (or % as specified on M.S.D.S.)

On  page 5 -  11  the  erroneous  notion  that  "one  pound  of  alcohol  substitute
replaces  approximately ten pounds  of alcohol"  is  completely misleading.

One may  say  that  1%  alcohol substitute  is  the  functional equivalent of 10%
alcohol in  terms  of  reducing  surface tension,  but  since  the weight  per  pound
of alcohol  substitute and  alcohol are  not identical  and  alcohol  is  fugitive in the
absence  of refrigeration,  the  formula
             weight of  = weight  of alcohol
             substitute            10
is  not accurate.   If only   a  very approximate cost  comparison is required,  please
state  that  fact.

In addition, the  one  step solutions  are not  even  considered  in  a  comparison
despite their  successful  performance  for over  eleven  years!
                                     673

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                                                                      TELEPHONE (7O8)-295-1 331
                                                                      FAX (7O8)-295-O732
                         RESEARCH LABORATORIES, INC.
                  990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
                              LAKE BLUFF. ILLINOIS. 6OO44
I would like  to  quote Gary  Jones  of GATF who  approximated that a web offset
heatset  press  could  easily exceed  100  tpy  VOC's.   Based  on  that, one might
estimate the following VOC  comparison:
20   25% alcohol
              o r
alcohol  free
2 step method
              or
alcohol  free
one step method
              o r
R.O. #50 D3
=  71   91,000 pounds VOC's


=  11,000 pounds VOC's


=  2,000 pounds VOC's

=  VOC free
On page 7-7, under  7.6.1.,  fountain solution VOC content cannot and  should  not
be  calculated  by taking  samples from trays or  tanks.   Only a  freshly  mixed
concentration  of  either  one step  or  two  step  solution  at  it's  recommended
concentration  with printers'  tap  or treated  water  should  be  mixed in  a  control
gallon   to   determine   VQC  content   bv  total  carbon   analysis   or   gas
chromatograph.   Tanks and pans  contain ink,  blanket  wash, roller wash, plate
cleaner  and  other   VOC related  solvent  contaminations  which  could  distort
fountain  solution  VOC  content.   This  is  reiterated  in  the appendix  of the CTG
Model Rule  D5.

On page 7    9, 7.7.3 a statement  is made  that alcohol substitute can be monitored
by  conductivity.     Alcohol  substitutes  are non  conductors  and  cannot be
measured  either  by  pH  or  conductivity; a  refractometer  is   required   to
determine  concentration.    One  step   solutions  however, may be  measured  as
freshly  mixed solution by  both  pH  and  conductivity  before recirculation  tank
contamination, but   only  for concentration,  not  VOC   content.    VOC  content
cannot be  determined  by any  method  except as  percentage  by weight as stated
in the Material Safety Data  Sheet or  total carbon analysis.   Mr.  Gary  McAllister
concurs  with me that Method 24  is  not  an accurate  test  for determining VOC
content  of  aqueous  solutions.

pH meters  are not  less  sensitive than conductivity  meters  as stated.    Fountain
solution  buffering  may  mask  concentrations  slightly,  but  again  this   has  no
relation to VOC  content.

Page  D-6  (sub head D.8)  requires  that a press  operator monitor  VOC content
with  a  temperature  compensated  refractometer  at  least  once  per  eight hour
shift.     A  refractometer  is a  delicate  laboratory  instrument,  which measures
concentrations  by BRIX  %,  not  VQC's.   This  monitoring requirement should  be
reconsidered.   Record  keeping  of  daily  alcohol  usage  or product  consumption
by  weight of VOC's might be  better source for monitoring  VOC  consumption.
Again, conductivity  cannot be used  to  monitor VOC content.
                                    G74

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                                                                      TELEPHONE (7O8J-295-1 33 1
                                                                      FAX (7O8)-295-O732
                         RESEARCH LABORATORIES, INC.
                 99O NORTH SHORE DRIVE •  NORTH SHORE INDUSTRIAL PARK
                             LAKE BLUFF. ILLINOIS, 6OO44
In conclusion, the RACT as presented on page  2 - 14  is certainly achievable and
will   probably  result   in   most  web  offset   printers  completely  eliminating
alcohol  by  one  step  or two  step method  since  no  proportioning system  exists
which  is capable  of  monitoring or consistently  replenishing  between  1.6%  -
3% alcohol.   Less  than  3% alcohol  would  probably  have  a negligible affect  on
reducing surface tension  during high  speed web  offset operation.

Limiting  smaller  sheetfed  operations  to  6%  alcohol  or  10%  alcohol  with
adequate   refrigeration  will   probably  encourage    refrigeration.     Limiting
larger  sheetfed  pressrooms  to   less   than   5%  alcohol  even  with   refrigeration
will  force  them  to  make  the  necessary   mechanical  modifications,  such  as
softer   durometer  dampening   form  and   metering  rollers,   to  facilitate
minimizing   alcohol   consumption   and   compensate   for   some   of  that
"forgiveness"' which 25%    35%  alcohol provided in the  past.  They  too will  be
motivated   to  running  alcohol  free   which  is   readily  achievable   with
management  commitment  and supplier technical   support.   A list  of  sheetfed
and  web printers  who  have operated alcohol free  has  been  provided to  Heather
Brown  of   Radian.    Some  of   these  printers   have  as  much  as twenty   years
experience   in  alcohol   free  operation.

Rosos   commends   E.P.A.'s  efforts   to  establish  CTG's  which  are  realistic,
attainable,   and  the  only responsible means of preserving  our  air  quality for
generations  to come.    To  answer the  criticism of alcohol  elimination affecting
print  quality  or  productivity,  National  Geographic,   a  publication  which sets
standards of  excellence, has  a  12  year  record  of  alcohol  free  quality  and
productivity in  its  Corinth,  Mississippi,  web  offset  pressroom.   Eleven  million
quality  impressions are  produced monthly   to  the  satisfaction  of  both  publisher
and  printer.   It is also encouraging to  note  that Heidelberg/Harris,  one of the
world's   largest  press  manufacturers, is  demonstrating  its  commitment  to run
alcohol  free with a  one step solution  at  4%  at  web offset speeds of 2000 FPM  at
its  own  Customer  Support  and  Training  Center in Nashville, Tennessee.

Rosos   will  continue  its   commitment  to  advancing  not  only alcohol  free
technology,  but  VOC free dampening  chemistry  for  the  future.   R.O.  #50  D3, our
latest  VOC  free  formulation,   is   currently  being   utilized  by  such  leading
printers  as  Holladay  Tyler for  Smithsonian  Magazine, and  divisions  of  R.R.
Donnelley  &  Sons which   indicates  VOC   free chemistry  and  outstanding  print
quality  can coexist successfully.   In closing,  I would  like  to congratulate you
on  your  CTG,  and thank  you  for your  consideration  of my  comments  and
suggestions.
                                    675

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             A REPORT  TO
 THE  NATIONAL AIR POLLUTION CONTROL
    TECHNIQUES ADVISORY  COMMITTEE
U. S. ENVIRONMENTAL  PROTECTION AGENCY
        DURHAM, NORTH CAROLINA
          NOVEMBER  20,  1991
            PAUL L.  MARTIN
       C. A. ENTERPRISES,  LTD.
                ID

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I am Paul Martin, Vice President-Product Development, C. A. Enter-
prises, Ltd. Sioux City, Iowa.
For several years I have been involved with magnetic treatment
of water used for heating and cooling in residential and commercial
uses.  This multi-pole magnetic treatment is a chemical free system
for the control of lime scale and corrosion in all types of water
using equipment.... from small humidifiers to the largest of boilers,
cooling towers and heat exchangers.
While there are many things that are not fully understood, it is
a known fact that a properly designed multi-pole magnetic field
will provide several desirable effects in water-using vessels that
are designed for the transfer of heat.
By altering the configuration of the magnetic fields, by changing
their strength and/or spacing, various results'can be accomplished.
One of these results is to make the water passing through these
fields become more soluble.
At the urging of a large manufacturer of printing presses, this
technology was applied  in developing a non-chemical method that
would lower the surface tension of the water in a fountain solution
and thereby act as a wetting agent....thus reducing the reliance
on isopropyl alcohol  (C3HgO) in the printing process.
The manufacturer of these magnetic units provided six "off the
shelf" units that were  installed on a Harris M-1000 press in Des
Moines, Iowa.  The results were very good.  An immediate reduction
of 60% of alcohol was accomplished.  At the time of this writing,
the magnetic units have been installed for a little over 21 months
and have saved approximately 8,100 gallons of alcohol normally
required to operate that one press.  This has also been accomp-
lished without sacrificing quality, which of course, is vitally
important in the printing industry.
While these results were very gratifying, I thought we  could do
better.  Two new prototypes were built and, with the cooperation
of a large printer of greeting cards  in Kansas City, these were
installed, one on the fountain station of the magenta unit of a
60" MAN sheet fed press and the other on the blue unit  of  a  38"
Toshiba web press.  Both of these  presses were, at  the  time,

                                G77

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                                  (2)

operating in the range of 18% to 20% alcohol in their fountain
solutions.  It was hoped that, with no other changes, the level
of alcohol could be reduced to 5% to 7%.
Two days later, it was reported that both fountain stations were
operating at "0" alcohol and the only alterations made were minute
adjustments to the nip, and a slight increase in the speed of the
water roller.  Ten more units were ordered to complete the treat-
ment of these two presses.  To this day, both presses continue
to operate at levels of alcohol from 0% to 3%, except when metallic
or "day-glo" inks are used.  Under those conditions a slightly
higher level is needed.  For Monday morning start-up, some addi-
tional alcohol is added to improve initial roll-up.
Since that time, all fountain stations for that firm have had units
installed and the plant has reduced its alcohol use from approxi-
mately 270,000# in 1989, to a projection of less than 20,000# in
calendar  1991.  This represents over a quarter million pounds of
VOC's that are being prevented from entering the atmosphere each
year....a reduction of 90%.
Since those first installations, hundreds of units have been installed
on various types of presses, both heat-set and non heat-set, on
sheet fed and web presses throughout the United States and in
Canada, South America, Ireland, the United Kingdom and Japan.
The acceptance level for these units has been very high.
This unit should not be considered to be a "cure-all" for the printing
industry, but it can be a very useful tool in the effort to reduce
VOC's in the work place.  If alcohol is being used to correct a
mechanical problem, such as roller durometer or minor wear, it
will be of no help.  Also, some printers may be very reluctant to
give up their alcohol.  However, in cases where alcohol is being
used merely as a wetting agent, reducing the surface tension of
the fountain solution can reduce that use of alcohol by an absolute
minimum of 50%, and in many cases much much more.  The units are
extremely cost effective, often giving complete "return on invest-
                                                        /
ment" in less than 90 days.
I realize that while this has long been a known technology in many
other applications, it's introduction to the printing industry

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                                   3)
is new,  therefore at the conclusion of this report I will be happy
to answer any questions you might have about our equipment.  Many
of the results we have achieved are referred to in the "Control
Techniques Guidelines" draft report prepared for this meeting,
under sections 2, 4, 5 and 6, under "Reasonably Available Control
Technology" and "Emission control Techniques".
May I say that, we at C. A. Enterprises are very proud to have
taken scale and corrosion control technology and adapted it to
develop emission control technology -
I thank this panel for their time and, as I said earlier, I will
be happy to answer any questions that you or your guests might
have.
                                ! i

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AMERICAN NEWSPAPER PUBLISHERS ASSOCIATION
         COMMENT TO THE DRAFT
    OFFSET LITHOGRAPHIC PRINTING
      CONTROL TECHNOLOGY GUIDELINE
           NAPCTAC MEETING
          NOVEMBER 19-21, 1991
        DURHAM, NORTH CAROLINA

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   The American Newspaper Publishers Association (ANPA) is a trade organization that
represents the publishers of about 1,350 newspapers published in North America. ANPA
maintains a technical staff of chemists, engineers, industrial hygienists and computer
scientists to provide technical expertise on matters  of environmental regulations and
application of new technology.

   ANPA would like to thank the EPA staff and contractor for the opportunity for
information input throughout the entire draft preparation process. Overall, the staff and the
contractor did a very good job of learning an industrial process in spite of the contradictions
and diversity of the lithographic process. However, after distributing portions of the Offset
Lithography Control Technology Guideline (CTG) to our members, the industry requested
that I provide a brief presentation at this meeting to correct several inaccuracies found hi the
CTG.

   The written presentation has two parts. Part one outlines the inaccuracies and the
misconceptions about  the newspaper printing process that overestimates the emissions
from the industry.  The second part, not covered  in today's oral  presentation, are
corrections to the generalized technical information about offset printing and definitions
contained in the document.

Figure 3-1

   The last bar graph should be labeled greater than 250,000 rather than less than.

Newspaper  (Non-Heatset Model Plants)  Table 3-4

   The model newspaper shown in this table is an extrapolation of material usage from an
accurate ink consumption data that ANPA complied from a recognized industrial directory.
The projected usage of fountain solution and cleaners were estimated from ideal usage
ratios instead of empirical data and as a result overestimates or underestimates have
occurred. After seeing the proposed model, ANPA conducted a survey of material usage
by a group of newspapers that act as technical advisors to ANPA operations and projects.
The results from these 63 newspapers were used  to generate a model from  actual
production situations.

   The proposed model (Table 3-4) in the CTG overestimates the fountain solution usage
and the amount of cleaning solution does not accurately reflect industrial practices.  The
similarity between the original ink usage data supplied to the EPA and the survey's ink
consumption demonstrates accuracy of the survey data. ANPA strongly urges that actual
material usage data be incorporated into the newspaper model instead of extrapolated data.

   The column heading "Annual Fountain Solution Alcohol Use Rates" is incongruous
with information provided in the text about fountain solution composition. Newspaper
printing does not use alcohol  in its dampening system. The system uses only alcohol
substitutes. The word alcohol should be removed from the heading and replaced with the
term fountain solution additive.
                                 o
I

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                 TABLE 3-4.   NEWSPAPER  (NON-HEATSET WEB) MODEL PLANTS
                                       ANNUAL PRODUCT  USE


Model Plant
Code
D-I
D-H
D-ffl
D-IV
D-V
D-VI



Size
Very Small
Small
Medium
Medium Large
Large
Extra Large



Total Units1
6
8-10
9-24
18-48
40-%
100-120

Annual Ink
Use Rates
(Tons)
2-19
15-82
67-209
125-829
529-1647
1072-3239
Annual
Fountain
Solution
Alcohol
Use Rates
(Tons)
0.1-1
1-6
5-15
9-58
37-115
75-227
Annual
Cleaning
Solution
(Tons)
3
4-5
4-12
9-24
20-48
50-59
  Double Blanket.
                  ANNUAL USE OF PRODUCTION  MATERIALS BY 63 NEWSPAPERS
                                    VALUES EXPRESSED IN TONS
                                  Ink3
                        Fountain Solution'5
                       Cleaning Solvent0
Very Small (n=10)d

Small (n=9)

Medium  (n=15)

Med. Large (n=15)

Large (n=ll)

Extra Large (n=3)
  17.4 (8.5-26.3) e

  45.9 (34.7-57.1)

  63.5 (42.7-84.3)

240.0 (148.1-331.9)

823(539-1107)

1835 (1250-2330)f
 0.54(0.11-0.97)

 1.44 (0.81-2.07)

 3.01 (2.38-3.64)

13.4 (6.4-20.4)

46.2 (17.8-74.6)

85.8 (30.0-119.2)f
 1.06 (0.29-1.83)

 3.08 (1.80-4.36)

 4.64 (3.61-5.67)

18.23 (8.0-28.5)

53.0 (12.3-93.7)

57.2 (23.8-106.2)f
a   Combines color and black ink used
b   Tons of concentrated fountain solution consumed—calculated using a specific gravity of 8 pounds per gallon
c   Tons of cleaning solvents consumed—calculated using a specific gravity of 7.5 pounds per gallons
d   Number of newspapers surveyed in each circulation class
e   Mean value and numbers within parenthesis represent the statistical 95 percent confidence limit
f   Since n < 7, actual range reported

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Model Plant Production Use and Baseline  (Uncontrolled)  Volatile  Organic
Compound Emissions (average tons per year)   Table 5-1

   I will address only the values reported for model plant code D (newspaper printing).

   Changes made in the Table 3-4 (Newspaper Non-Heatset Model Plants) to reflect actual
product usage should also be made in Table 5-1.  The use of average consumption rates per
hour per unit (Appendix B Section B-l.l) will overestimate the emissions from small
newspaper operations utilizing a small press running at slower speeds and underestimate
the emissions from large newspapers that use large presses running at 2,200 feet per
minute.  ANPA supports the simple emissions calculation  based  on  material usage,
volatility of product and application of an appropriate emission factor which recognizes that
production conditions result in the retention of volatile material within the printed product
(Appendix B Section B-2.1).  However, the volatility of the average products used to
calculate the uncontrolled baseline levels does not reflect the characteristics of the average
materials used in commerce. At best they represent the extremes.

INKS

   The use of a 30 percent VOC ink as an average news ink is unrealistic.  In 1989,
ANPA tested 31 black and 21 color news inks under the severe conditions of Method 24A.
The black inks had a mean value of 22 percent +/-  3.6  (95 percent confidence limit) and
color inks had a mean value of 19 percent +/- 3.0 (95 percent confidence limit). Later that
year a test of other offset inks using Method 24 produced a range of VOC values: black 2-
20 percent, color 2-13 percent.

   In 1990, ANPA requested seven different news ink manufacturers to submit three of
their most commercially successful black ink formulation for a printing evaluation project
being conducted by ANPA. A portion of the test protocol was to test the VOC content of
the ink versus press performance.  Of the 19 inks submitted for evaluation, only two inks
had VOC content greater than 18 percent (24 and 26 percent respectively) and the median
value was nine percent

   These data demonstrate that a 30 percent VOC news ink would represent less than 2.5
percent of the inks used in newspaper printing. The rational for using a 30 percent value is
that it falls between the zero to 45 percent limit based on theoretical estimates of emissions
from mass balance and some limited empirical test data. The theoretical limit represents a
range of how inks can be formulated and not how the "typical" news ink is formulated.

   A VOC content of 12 percent would be a more fair estimate of an average news ink.
Any value exceeding 22.5 percent (the median value of 0 to 45) can not represent the
average theoretical ink. ANPA requests that the values for ink emissions in Table 5-1 be
recalculated to reflect a "typical" ink with a volatility of 12 percent.  This change should
also be made in Appendix B Section B-2.1.

   ANPA requests an inclusion of an emission credit for the VOC content of waste ink that
is incinerated.
                                       3-

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FOUNTAIN SOLUTION

    In section 2.5.2, the text refers to a newspaper's fountain solution usage to vary from 1
to 150 tons.  It is assumed that material as purchased is 100 percent alcohol substitute.
This assumption is erroneous and incongruous with statements made in section 3.5.2.

    The newspaper industry purchases from a variety of vendors a "one-step solution"
concentrated solution as described on page 3-40. Fountain solution is defined in section
3.5.2 as "...the fountain solution is water-based.  The fountain solution contains wetting
agents, acids or buffer salts to maintain the pH of the solution, small quantities of gum
arabic or synthetic resins, and a dampening aid to enhance the spreadability of the fountain
solution across the printing  plate."  Non-alcohol dampening aids that  characterize
newspaper fountain solutions (page  3-40) "...are made up of glycols, such as ethylene
glycol, glycol ethers or 'cellosolve ethers', or proprietary compounds, and are chemically
similar to alcohol." To contain acids and buffer salts to maintain the pH of the solution and
solubilize other inorganic compounds requires that  the "one-step" fountain solution
contains a significant amounts of water.  Inorganic compounds are insoluble in pure
glycols and glycol ethers.

    ANPA contacted three vendors that supply a significant proportion of the fountain
solution concentrate used by the newspaper industry. Each vendor provided a label that
contained mixing  instructions and in some cases an abbreviated listing of contents. I have
attached copies for your review. You will note that mixing instructions are  similar to those
found in the CTG. The materials sold by Rycoline list deionized water as an ingredient and
NENSCO provides the same product in  a ready-to-dilute concentration  and a super
concentrated form. To prepare the ready-to-dilute concentration, five gallons of the super
concentrate  is added to 50 gallons of water. Since there are not instructions to add any
additional alcohol substitutes, one can conclude that the ready-to-dilute form contains about
90 percent water  and the volatility would be less than ten percent by weight since the
MSDS sheets reports the presence of inorganic salts.

    Analytical data support the conclusion that most fountain solution additives purchased
by newspapers contain significant amounts of water. On March 13, 1991, ANPA shared
the Method  24 results of six different fountain solution concentrates with the EPA. The
volatility of these products when water was excluded was less than ten percent

    ANPA requests that values in the Table 5-1 and section 2.5.2 be changed to reflect the
chemical characteristics of the types of fountain additives used in  newspaper printing.
ANPA would suggest that the  values be lowered by a factor of ten. This factor assumes a
ten percent  concentration  of  alcohol substitute in  the purchase product instead of the
unrealistic 100 percent concentration assumed in the original model.

    In Chapter 7 and Appendix D, the CTG advocates the use of conductivity to measure
the concentration  of VOC  in fountain solution.  Conductivity, as used by newspapers to
maintain the dilution rate of the concentrated fountain solution, is dependent on the
inorganic compounds found in  the one-step fountain solution additive and is independent of
the non-ionic and non-dielectric alcohol substitutes.  However, recognition of the proper
concentration of alcohol substitutes in the concentrated fountain solution  additive would
exclude newspapers from the unnecessary expense of monitoring VOC content of fountain
solution by use on a hydrometer or refractive index. Starting concentration of ten percent
alcohol substitutes and dilutions rate as high as four ounces per gallons assures that the
concentration remains below the recommended control level of 2.5 percent An addition of

-------
an exclusion for newspaper printing would be beneficial and remove confusion about the
process.

   Chapter 6 outlines costs of applying a magnetic water treatment to reduce alcohol
substitute usage  by newspapers.  This dubious and unproven water treatment process
should not be applied to facilities that have invested in proven water treatment equipment
such as reverse osmosis or deionization.  Chemical removal water treatment technology
improves print quality in areas where the chemistry of the incoming water source varies
daily. Water treatment has a minimal effect on the annual fountain solution additive usage
but has proven  beneficial by making  daily fountain solution additive consumption
consistent. Application of a magnetic water treatment technology that claims print quality
improvement with less fountain solution additive is only anecdotical and not supported by
empirical data.  It does not justify the minimal expense outline in Table 6-8.

CLEANING  SOLUTIONS

   Press cleaning is a collection of diverse maintenance procedures in the newspaper
industry.  Application of single type  of cleaning solution to every task requires a
dependency on technology that is developing and not proven.  Many of these products
contain water or caustics that may have an unknown long term detrimental effect, like
corrosion, on press equipment.  The acknowledgement of low-VOC cleaners containing
D-limonene in the CTG demonstrates that some of the products being developed contain
compounds that have associated health hazards to the workers. D-limonene has a tainted
lexicological history and has been proven to cause skin sensitivity in workers after repeated
exposure. Since many of the low-VOC products are new, the quantity of a low-VOC
cleaning solution required for cleaning operations is not known and the projected reduction
in emission may not be realized because it takes more product to clean the same amount of
equipment.  In other words, a one-for-one quantity substitution  may  not be a valid
assumption in the economic model, Table 6-9.

   ANPA disagrees with the finding that low-VOC cleaning solutions would not have a
solid waste impact (Section 6.4.3).

   Waste ink that  may account for as much as  two percent  of all ink purchased is
composed of ink too contaminated with foreign material to be a usable product and cleaning
solution-ink mixture that enters a "catch pan" during the press cleaning.  Any cleaning
material that lowers the BTU content or is detrimental to reclaiming a usable ink product
from waste ink creates a significant solid waste dilemma for a newspaper. For smaller
newspapers, the  only economical means to dispose of waste ink is by incineration.  The
price of disposal  is dependent on the BTU content of the material and an increase in water
content caused by water-borne low-VOC cleaners increases the cost and limits the number
of vendors willing to handle the waste.  Waste minimization by ink reclamation requires
that  all non-ink materials such as solvents, water and paper fibers be removed from the
waste ink. The use of low-VOC detergent cleaners that can not removed by distillation
could disrupt the  ink-fountain solution interaction and make the reclaimed ink unusable.

   In a like fashion, cleaning solutions that become too dirty for reuse would either require
a larger energy input to separate them from the water content or higher disposal cost for
low BTU aqueous waste.  The disposal problems related to non-volatile distillation bottoms
are unknown. Disposal options for detergent cleaners would very limited.

   ANPA requests that the EPA consider the inclusion of cleaners with lower vapor
pressure that are less volatile as an alternative to concentration limit on VOC content. This
                                 i" o c
                                 >U dj U.

-------
would allow the printer the option to use the best products that minimize total waste
production and assure that all necessary maintenance operations can be performed.

   ANPA requests that the EPA consider a credit for the solvent that leaves the facility on
cleaning rags.  The laundry service charges an "environmental charge" for the purpose of
disposing the materials contained on the rags.  In effect, the same material is being
regulated twice.

   This concludes my oral presentation.

   ANPA requests the following technical corrections to text contained in the CTG.

       •   Section  2.4.1 second paragraph:  The offset Heat-set lithographic
          printing industry

       •   Section  2.4.3.2:  D-limonene does not have a lower volatility than
          products commonly used.  The  boiling point of D-limonene is
          similar to decane that is a major component of mineral  spirit cleaners

       •   Section 3.2 first paragraph: When the image plate is made, the
          image area is rendered oil receptive and water-repellant

       •   Section 3.3.2 second and third paragraph:  For a web  press the
          across cylinder dimension determines the width of the product and
          the around the  cylinder dimension determines the  length of the
          product. The text has this concept reversed.
                                       6-

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               DISTRIBUTION OF METHOD 24 PERCENT
               VOLATILE CONTENT  FOR 19 COMMERCIALLY
               AVAILABLE BLACK INKS IN 1990
         3-
•o
o
-
o Z
-«= §
I8
~ 1
E
3
2-
         1 -
           12345678 9 1C 1112 1314 15 16 17 1S 192C21 222324252627282930
                          percent volatile

-------
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                                 RYCOLJNE
                                           SEUEN   DEX
                                 FOUNTAIN    SOLUTION
                                                     PRODUCT NO. 23859
                                  DIRECTIONS FOR USE. USE I TO 3 OZ TO ONE GALLON OF MATER FOR DESIRED RESULTS.
                                  CONTAINS: DEIONIZED UATER  CAS I 7732-18-5
                                        OIPROPYLENE GLYCOL CAS I 25265-71-8
                                        OlPOTASSIUn PHOSPHATE CAS I 7758-11-4
                                        SODIUH HEXAHETAFHOSPHATE CAS I 68915-31-1
                                        noNOPOTAssiun PHOSPHATE CAS i 7778-77-8
                                  SPILL     USE AeSOPBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
                                  RESPONSE    CONTAIN LARGE SPILL AND PUHP TO SUITABLE TANK. UASH AREA UITH
                                  PROCEDURE:   SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE KITH UATER.

                                          FOP CHEDICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE
                                          OR ACCIDENT, CALL CHEKTREC 888-424-9388 DAY OR NIGHT.

                                  HASTE     USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
                                  DISPOSAL:   SITE. DISPOSE OF ALL HASTES IN ACCORDANCE UITH FEDERAL,
                                          STATE AND LOCAL REGULATIONS
                                               READ M.S.O.S. BEFORE USING PRODUCT
                                                    RYCOLINE PRODUCTS, INC.
                                               SMO NORTHWEST HIGHWAY. CHICAGO. IL 60830
                                                PHONf- (312) 775-6755 • FAX (312) 775-9414
                                                                                         Qfl i
                                                                                         HHIS
                  HAZARD INDEX
                                                                                                HEALTH
   FIAMMABIUTY
    REACTIVITY
                                                                                              PERSONAL I -'• I
                                                                                             PROTECTION I	I
STORAGE AND HANDLING
KEEP FROM FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EMPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
IIIXINC VESSEL
REHOVE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
              DANGER
            AFTER THIS CONTAINER
             HAS BEEN EMPTIED
              IT MAY CONTAIN
            EXPLOSIVE AND HARMFUL
            VAPOnS AND RESIDUE.
            KEEP AWAY FROM HEAT.
             SPARKS AMD FLAMES*
            DO NOT CUT. PUNCTURE.
            Ofl WELD ON OR NEAR
              THIS CONTAINER
            DO NOT RE-USE CONTAINER
            FOR ANY PURPOSE UNTO.
            COMMERCIALLY CLEANED

-------
CS
     UARNING!
     CAUSES IRRITATION
     AVOID CONTACT UITH SKIN AND EYES.
     AVOID PROLONGED OR REPEATED BREATHING OF HIST.
     PROTECTIVE EQUIPHENT
     FOR NORMAL USE HEAR RECOI1HEKDEO PROTECTIVE
     CLOVES AND SAFETY GLASSES
FIRST AID
EYES: IMMEDIATELY FLUSH UITH HATER FOR AT
    LEAST 1$ MINUTES.  CONTACT LENSES MUST
    BE REMOVED. GET KEOICAL ATTENTION
     SKIN:
         REMOVE ALL CONTAMINATED CLOTHING.
         HASH SKIN UITH SOAP AND HATER.
     BREATHING:
         NO ILL EFFECTS EXPECTED FROM INHALING THIS
         PRODUCT UNLESS UHEN USED IN COMBINATION
         UITH A SOLVENT: ISOPROPYL ALCOHOL.
     SUALLOUINC:
         DILUTE UITH TUO GLASSES OF HATER AND
         INDUCE VOMITING.  GET HEDICAL ATTENTION.
     EXTINGUISHING MEDIA
     IN CASE OF FIRE, USE HATER (FLOOD UITH HATER)
     DRY CHEMICAL, C02 OR ALCOHOL FOAJl
     FOR INDUSTRIAL USE ONLY

     KEEP OUT OF THE REACH OF CHILDREN
                                   RYCOLINE
                                       SEUEN    FOUNTAIN
                                     SOLUTION    TYPE   P
                                                       PRODUCT NO. 23B4I
                                        DIRECTIONS FOR USE: USE 1 TO 3 OZ. TO ONE GALLON OF HATER FOR DESIRED RESULTS.
                                    CONTAINS: DEIONIZED HATER CAS I 7732-18-$
                                          DIPROPYLENE CLYCDL CAS I 252*5-71-8
                                          DIPOTASSIUH PHOSPHATE CAS I 7758-11-4
                                          SODIUM HEXAHETAPHOSPHATE CAS I 68915-31-1
                                          noNOPOTASsiun PHOSPHATE CAS i 7773-77-0
                                    SPILL     USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
                                    RESPONSE    CONTAIN LARGE SPILL AND PUflP TO SUITABLE TANK.  HASH AREA UITH
                                    PROCEDURE:   SUITABLE DETERGENT AND HATER AND THOROUGHLY RINSE HITH HATER.

                                            FOR CHEMICAL EMERGENCY - SPILL. LEAK, FIRE, EXPOSURE
                                            OR ACCIDENT. CALL CHEttTREC 888-424-9388 DAY OR NIGHT.

                                    HASTE     USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
                                    DISPOSAL:   SITE.  DISPOSE OF ALL HASTES IN ACCORDANCE UITH FEDERAL,
                                            STATE AND LOCAL REGULATIONS.
                                                  READ M.S.D.S. BEFORE USING PRODUCT
                                                       RYCOLINE PRODUCTS. INC.
                                                 5540 NORTHWEST HIGHWAY. CHICAGO. IL 60630
                                                   PHONE: (312) 775-6755 • FAX (312) 775-9414
                                                                                                  Oft ft
                                                                                                  HMIS
      HEALTH
   FLAMMABILITY  0


    REACTIVITY [0
                                                                                                       PERSONAL
                                                                                                      PROTECTION
HAZARD INDEX

  0 • Mininul

  1 • Sligm

  2 • Motjeialii

  3 • Sflnous

  4 • Seven;
STORAGE AND HANDLING
KEEP FROM FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EIIPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
niXING VESSEL
REMOVE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
               DANGER
             AFTER THIS CONTAINER
              HAS BEEN EMPTIED
               IT MAY CONTAIN
             EXPLOSIVE AND HARMFUL
             VAPORS AND RESIDUE
             KEEP AWAY FROM HEAT
             SPARKS AND FLAMES'
             DO NOT CUT, PUNCTURE
             OR WELD ON OR NEAR
               THIS CONTAINER
            DO NOT RE USE CONTAINER
             FOR ANY PURPOSE UNTIL
             COMMERCIALLY CLEANED

-------
c
     ilHFNING'
     ChUiES IRRITATION
     H'JOIO tOIITHCT WITH SUN HHD EYES
     AUDIO PROLONGED OR REPEATED BREATHING OF IIIST
     PROTECTIVE EaUIPHENT
     FOfi NOSnnL  USE IIEtf RECOHNENDED PROTECT1UE
     CLOUES AMD  SAFETY GLASSES
FIRST  HID
Ei'ES   MEDIATELY FLUSH UITH UATER FOR AT
      LEH3T 15 I1INUTES  CONTACT LENSES MUST
      BE REMOUEO  GET HEOICAL ATTENTION.

SKIN.  REHOUE ALL CONTAdlNATED CLOTHING
      UASH SUN UITH SOAP (.NO UATER.

BREATHING
      NO ILL EFFECTS EXPECTED FROK INHALING THIS
      PRODUCT UNLESS UHEN USED IN COnBINATION
      UITH A SOLVENT:  1SOPROPYL ALCOHOL.
SUALLOIIING
     DILUTE UITH TUO GLASSES OF UATER AND
      INDUCE UOIUTING.  GET HEDICAL ATTENTION.
     EXTINGUISHING HEDIA
     Hi CASE OF FIRE, USE UATER (FLOOD UITH UATER)
     DRV CHEHICAL,  C02 OR ALCOHOL FOAH
     FOR  INDUSTRIAL USE ONLY

     l-EEF1  OUT  OF THE RcACh  OF CHILDREN
ALKALINE     FOUNTAIN
         LJ Li* LJ  I   >L I-JI  i     -««j     VK^ «-L O* n
                            PRODUCT NO
                                                     DIRECTIONS FOR USE: USE  I TO 3 02.  TO ONE GALLON OF UATER FOR DESIRED RESULTS
                                                     CONTAINS: DEIONIZED MATER  CAS I 7732-18-5
                                                             TETRAPOTASSIUI1 PVROPHOSPHATE CAS I 7328-34-5
                                                             SODIUIt HEIAI1ETAPNOSPHATE  CAS I 68915-31-1
                                                             SODIUH HYDROXIDE  CAS I 1318-73-2
                                                             POLYETHEYLENE GLVCOL  CAS I 25322-68-3
  SPILL       USE ABSORBENT ItATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL
  RESPONSE     CONTAIN LARGE SPILL AND PUHP TO SUITABLE TANK.  HASH AREA UITH
  PROCEDURE    SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE UITH UATER.

             FOR CHEniCAL EflERGENCY - SPILL. LEAK, FIRE, EXPOSURE
             OR ACCIDENT, CALL CHEHTREC 688-424-9388 DAY OR NIGHT.

  UASTE       USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
  DISPOSAL:    SITE  DISPOSE OF ALL UASTES IN ACCORDANCE UITN FEDERAL,
             STATE AND LOCAL REGULATIONS.
                     READ M.S.0.8. BEFORE USING PRODUCT
                           RYCOLINE PRODUCTS, INC.
                    55JO NORTHWEST HIGHWAY. CHICAGO, It. 60630
                      PHONE: (312) 775-6755 • FAX (312) 776-9JH
                                                                                                                            QA  #

                                                                                                                            HHIS    HEALTH JOJ
                                                                                                                                 FLAMMABILITY  0
                                                                                               0
                                                                                                         HA2AHDINDEX

                                                                                                           0 Minimal

                                                                                                           I  Sliyhl

                                                                                                           2 MoOuidto

                                                                                                           3 • SBIIOUS
                                                                                                                                         PERSONAL
                                                                                                                                       PROTECTION
                                                                                STORAGE AND HANDLING
                                                                                KEEP FROn FREEZING
                                                                                KEEP OUT OF SUN AND EXCESSIOE HEAT
                                                                                KEEP CONTAINER CLOSED UHEN NOT IN USE
                                                                                00 NOT PUNCTURE CONTAINER
                                                                                NEUER USE PRESSURE ID EtIPTY CONTAINER
                                                                                00 NOT USE CONTAINER AS A DILUTION OR
                                                                                NIXING UESSEL
                                                                                REflOUE CAP CAREFULLY TO RELIEVE POSSIBLE
                                                                                INTERNAL PRESSURE
                                                                                                                                                 DANGER
                                                                                                                                               AFTER THIS CONTAINER
                                                                                                                                                 HAS BEEN EMPTIED
                                                                                                                                                 IT MAY CONTAIN
                                                                                                                                               EXPLOSIVE AND HARMFUL
                                                                                                                                               VAPORS AND RESIDUE
                                                                                                                                               KEEP AWAY FROM HEAT.
                                                                                                                                                SPARKS AND FLAMESI
                                                                                                                                               DO NOT CUT. PUNCTURE
                                                                                                                                               OH WELD ON OR NEAR
                                                                                                                                                 THIS CONTAINER
                                                                                                                                              DO NOT HE-USE CONTAINER
                                                                                                                                               FOR AMY PURPOSE UNTIL
                                                                                                                                               COMMERCIALLY (XEANEO
                                                                                                                                                                          _..

-------
UARNING!

CAUSES IRRITATION

AVOID CONTACT UITH SKIN AND EVES.

AVOID PROLONGED OR REPEATED BREATHING OF HIST.
PROTECTIVE EQUIPMENT
FOR NORMAL USE UEAR RECOMMENDED PROTECTIVE
CLOUES AND SAFETY GLASSES
FIRST AID

EYES:  imiEDIATELY FLUSH MITH UATER FOR AT
     LEAST 15 niNUTES.  CONTACT LENSES DUST
     BE REMOVED.  GET HEDICAL ATTENTION.
SKIN:
     REHOVE ALL CONTAMINATED CLOTHING.
     HASH SKIN UITH SOAP AND UATER.
BREATHING:

     NO ILL EFFECTS EXPECTED FROI1 INHALING THIS
     PRODUCT UNLESS UHEN USED IN COItBINATION
     UITH A SOLVENT:  ISOPROPYL ALCOHOL.
SUALLOU1NG:
     DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION
EXTINGUISHING MEDIA
IN CASE OF FIRE, USE UATER (FLOOD UITH UATER)
DRY CHEMICAL, C02 OR ALCOHOL FOAI1.
FOR INDUSTRIAL USE ONLY

KEEP OUT OF  THE REACH OF CHILDREN
                                          RYCOUNE
           flLKfiLINE   Y-797   DEX
            FOUNTAIN   SOLUTION
DIRECTIONS FDR USE:
RESULTS.
                                                                    PRODUCT NO. 28936
                USE I TO 3 LIOUID OUNCES PER GALLON OF UATER FOR DESIRED
CONTAINS: DEIOHIZED UATER  CAS I 7732-16-5
       01PROPYLENE GLYCOL CAS < 25265-71-8
       TETRAPOTASSIUH PYROPHOSPHATE  CAS I 732B-34-5
       SODIUI1 HEXANETAPHDSPHATE  CAS I 48915-31-1
SPILL       USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
RESPONSE     CONTAIN LARGE SPILL AND PUMP TO SUITABLE TANK.  HASH AREA UITH
PROCEDURE:    SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE UITH UATER.

           FOR CHEMICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE
           OR ACCIDENT, CALL CHEHTREC 868-424-9386 DAY OR NIGHT.

UASTE       USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
DISPOSAL:     SITE.   DISPOSE OF ALL UASTES IN ACCORDANCE UITH FEDERAL,
           STATE AND LOCAL REGULATIONS.
                 READ M.S.D.S. BEFORE USING PRODUCT
                       HYCOLINE PRODUCTS. INC.
                5540 NORTHWEST HIGHWAY. CHICAGO, IL 60630
                  PHONE: (3I2| 775-6755 • FAX (312) 775-9414
                                                                     UH It

                                                                     HMIS    HEALTH

                                                                         FUMMABIUTY

                                                                           REACTIVITY
             m
             m
                                                                                                                      PERSONAL (X
                                                                                                                     PROTECTION
HAZARD INDEX

  0 • Minimal

  1 - Slight

  2 • MocMi

  3 • Swlwa

  4-Snvw!
STORAGE AND HANDLING
KEEP FROH FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EMPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
niXINC VESSEL
REItOUE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
                  DANGER
                AMER THIS CONTAINER
                 HAS BFEN EMfMIFP
                  IT MAY CON1AIN
               EXPLOSIVF Ann HAIlMriJL
                VAPDMS AMP RESIOUF
                KEEC AWAY f HOM HE AI
                SPARKS AND flAMf SI
               DO NO! CHI PUNCHiflF
                on WELD ON on ME An
                  THIS CONTAINER
               DO NOT RE USE CONTAINER
               FON ANY PURPOSE UNTIL
               COMMERCIALLY CLEANED

-------
            Nensco
                   P.O. Box 544
                Mlllbwy, MA 01S27-OJ48
       liquid   gold
Super Concentrate Fountain Solution
                Contents: 5 Gallons
              MIXING INSTRUCTIONS
  Add 30 Gallons o( water to mixing tank. With mixer running add the entire
  contents of (2) 5 Gallon containers of Super Concentrate. Then add 15 Gallons
  of water to make 55 Gallons. Allow to mix for 5 minutes.
  * NOTE a 27M&IW batch may be mixed by adding (1)5 Gallon contain* of Super
  Concentrate to 22V* gallons ol water.

DIRECTIONS: A starting point of 2 ot/gallon or conductivity 1000 over
          tap water.

CAUTION: Although no health hazard is known, It to advisable to treat
        this matter with respect: Avoid eye contact Avoid prolonged
        or repeated skin contact DO NOT take intemaBy.

FIRST AID: Eye* or 8Un: Rusnw«hvwter.(Eye«oriry-comartphy8Wan)
        If Ingested CONSULT A PHYSICIAN, INDUCE VOMITING.
        KEEPC^OT THE I^EACH OF CHILDREN.          A

               for Protentoral Use Only.
       This product wH bo replaced R detective In manufacturing,
         packaging, or labetog. Except tor such replacement,
         this product to sold without warranty, expressed or
              ImpBed. or labity of any kind.
     Boston • Chleogo  •  los Angelas • Dodos • ftbonta
             Nensco
                   P.aBoz348
                Mlllbury. Mfl OJ 527-0348
      liquid  gold
             News  Dot
           Fountain Solution

          4-1 GAL CONTAINERS

DIRECTIONS,; A starting point of Z ozVgallon or conductivity 1000 over
CAUTION: Although no health hazard Is known, H is advisable to treat
        this matter with respect: Avoid eye contact. Avoid prolonged
       > repealed skin contact DO NOT take internally.

FIRST AID: Eye* or Skin: Rush with water. (Eyes only -contact physician)
        If Ingested CONSULT A PHYSICIAN, INDUCE VOMITING.
        KEEP OUT OF TH£ REACH OF CHILDREN.

               For ProfcMfenal UM Only.
       Trfcprodudvtf be replai^ Idefecth* In nwwfactu^,
         narkanlnn AT Inh^llnn Cw*t*r«* CM ••»*<•% •^•••.•.^—*
                                                                        Boston • Chleogo  •  tosflngeles  •  DoBos • fldonto

-------
 5 GAL
                 Nensco
               Mem fcncjiond Newspaper Supply Co.
                       P.O Boi 348
                       Military. MA 015C7-034B
      ALKA-FOUNT
                      A1
             Fountain Solution
                     ' DIRECTIONS: '
^,;-'' |V-':; -•''-• •""•.'•'"- : 'CAUTION!:'  •.   .   •  .       '-•
, 'v 4-. '« Cdnldlns Tri Potassium Phosphate Solution Avoid eye contact. Avoid prolonged or
• V •' _V repeated skin contact  DO NOT take internally. The use ol protective goggles and
v ;;,1',: chemical resistant gloves Is recommendend.    ....        /    i '
'i&l-V •- ii, ;'[,.<.• •'••. --i . •..).('. ..<;••• ..... ••"•,•        • "< •'•.-' •,'1.V--'.f1": '• '• ; '• •-••'•
••d^:^,.---^                    ,; •..•,':l: / i'-.  : '  , -.
i-; ';-j ! ; >; Skin • Flush' with soap Ant) water. Eye* • Flush copiously with water and/or boric acid
'ti&fo. solution. IF INGESTED, administer large volumes ol water, milk, soda or other acidic
;-'Wi.,' liquids. CONSULT PHYSICIAN. KEEP OUT OF REACH OF CHILDREN.
 • W^fei'^Vi.^

 S^fM!i!bo^^:l^liii^?iWu^
^xstwJi^
5 GAL.
Nensco
                                                                   New England Newspaper Supply Co.
                    p o Box 348
                    Millbury. MR 01527-0348
     ALKA-FOUNT
                   A2
    Super Concentrate Fountain Solution

                   DIRECTIONS:
  Add 30 gallons of water, to mixing vat With mixer running, add the entire contents
  ol (2) 5 Gallon containers of Super Concentrate. Add remaining 15 gallons of water,
  to mako 55 gallons. Allow to mix for 5 minutes.
  • NOTE a 27'..- qnllan bntch may bo mixed by adding 1 1) 5 Gallon container ol Super Concentrate
  to 22".' gallons ol water
              LOADING INSTRUCTIONS:
          On press load 1 to 1 '/;> oz /gallon or as noccessary.

                    CAUTION!:
  Contains Tri Potassium Phosphate Solution. Avoid eye contact. Avoid prolonged or
  repeated skin contact. DO NOT take internally. The use of protective goggles and
  chemical resistant gloves is recommendend.

                    FIRST AID:
  Skin - Flush with soap and water. Eyes - Flush copiously with water and or bone acid
  solution. IF INGESTED, administer large volumes of water, milk, soda or other acidic
  liquids, CONSULT PHYSICIAN. KEEP OUT OF REACH OF CHILDREN.
  Millbury, MR • Chicago  'I. • Uplrnd. CR • Dallas, "DC • flosujell, GR

-------
  "The Original Alkaline Fountain Etch"
  MIRACLE
CONCENTRATE
    For Hard Water (up to 200 ppm)
        NEVER GUM
        ANOTHER PLATE,
       NEVER EXPERIENCE
        STRIPPING AGAIN,
        AND YOU GET
        BETTER PRINTING!
         CORPORATION

  NATIONAL HEADQUARTERS: 25111 GLENDALE AVENUE, DETROIT, MICHIGAN 48239

-------
                                      ^^  •__ ,.•,;•?.•;-... •-".:•; i- -iJ>-';!s'i-,-*v'-"-'-V.T!:-. .=..-..•

                                     Niensco
                                      New €oglond Newspaper Supply Co,

                                               PO SOT 348
                                 Neutro fount
                                      Fountain Solution
CT
CO
cn
       DIRECTIONS
A starting point of 2 ozJgallon is suggested
                                             CAUTION!

                            Although no health hazard is known, It Is advisable to treat this matter with
                            respect: Avoid eye contact. Avoid prolonged or repeated skin contact DO
                            NOT take Internally.

                                             FIRST AID:

                            Eyes or Skin: Flush with water. (Eyes only • contact physician) If Ingested
                            CONSULT A PHYSICIAN, INDUCE VOMITING, KEEP OUT OF THE REACH
                            OF CHILDREN.
                                          For Professional use only.   FORM NO N-NFS s/84 gw

                            This product will be replaced if defective in manufacturing, packaging, or
                            labeling. Except for such replacement, this product is sold without war-
                            ranty, expressed or implied, or liability of any Kind.

                                       OXCQCP.IL - Upland Cfi • Dallas.?X • (tosmell.GR

-------
c -;
                    #2474

          PERFECT  PINK

              ONE-STEP, BUFFERED
         NEUTRAL FOUNTAIN SOLUTION
DIRECTIONS:  PERFECT PINK has been proven effective in producing
clean, crisp newspapers and insert work with the "clean oil" and "low
rub" inks. Use 2 ounces of PERFECT PINK per gallon of water for a
conductivity of approximately 1000 mmhos over the conductivity of the
water used.  It is recommended that you NOT  use over 3 ounces of
PERFECT PINK per gallon of water.
        2535 Ivy Street East
      Gumming, Georgia 30130
              ANCHOR/LITHKEMKO, INC.
                 50 Industrial Loop North
                Orange Park, Florida 32073
                  (904) 264-3500
 280 North Ott :
Corona. California 91720
                                                                           m =
                                                                           o a
                                                                           2 §•
                                                                           >
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                         r~  ~ 3 to
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                                                                                 °
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                            en X o
                            0) F- yi
                            £a^
                            05?^
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                            3 -•?
                            -o^o
                            9 S I
                                                                              w 3
                                                                              (D di
                                                                              Q. O
                                                                              ^ C
In case of eye contact, flush with water for
15 minutes  and seek medical attention.
Wash affected  skin  areas  with soap and
water. If swallowed, induce vomiting and
seek  medical  attention. Contains water,
Monosodium     Phosphate      (CAS
#7558-80-7), TKPP  (CAS #7320-34-5),
EDTA (CAS #64-02-8)  and  Gum  (CAS
#9000-01-5).

V.O.C. - 0 Ibs./gal.

NONPHOTOCHEMICALLY REACTIVE

TARGET ORGAN EFFECTS: None known.
                                                                                            HEALTH
                                                                                            FLAMMABILITY
                                                                                            REACTIVITY
                                          PERSONAL
                                          PROTECTION

-------
                         #2830
                 AQUA  MAGIC

              NEUTRAL FOUNTAIN SOLUTION
     DIRECTIONS:  Mix fountain solution  to yield conductivity of
     1000 mmhos over the conductivity of the incoming water. This
     will normally be obtained by using 2 ounces of fountain solution
     per gallon of water.
  ?535 Ivy Street East
dimming, Georgia 30130
ANCHOR/LITHKEMKO, INC.
    50 Industrial Loop North
   Orange Park, Florida 32073
     (904) 264-3500
 280 North Ott Street
Corona, California 91720
                                                                     r~ o o. [u <
                                                                     rn ffl "> = S
                                                                     UJ D — c/i >*


                                                                     Z CT O - >
                                                                     gns
                                                                     • 5 8
                                                                     a s ^
                                                  |f £
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                             Is
                             O f
                                                                     O

                                                                     5  I
                                                    CAUTION
                                         In case of eye contact, flush with water for
                                         15 minutes and seek medical attention if
                                         irritation persists. Wash affected skin areas
                                         with soap and water. If swallowed, induce
                                         vomiting  and  seek  medical   attention.
                                         Contains  water,  Dipotassium Phosphate
                                         (CAS    #7758-11-4),    Monopotassium
                                         Phosphate (CAS  #7778-77-0), Sodium
                                         Hexameta Phosphate (CAS #10124-56-8)
                                         and EDTA (CAS #64-02-8).

                                         V.O.C.-0.1 lbs./gal.

                                         NONPHOTOCHEMICALLY REACTIVE

                                         TARGET ORGAN EFFECTS: None known.
                                                                   HEALTH
                                                                   FLAMMABILITY
                                                                                      REACTIVITY
                                                                                      PERSONAL
                                                                                      PROTECTION

-------
(=-73
        ANCHOR
                  #2833
        FIRST IMPRESSION
          ALKALINE FOUNTAIN SOLUTION
DIRECTIONS: Use 1.5 to 2.5 ounces per gallon of water for
desired results.  Conductivity  should  read approximately
1200-1500 mmhos above the conductivity of the water used.
                                    TM
             ANCHOR/LITHKEMKO, INC.
        50 Industrial Loop North, Orange Park, FL 32073
      13505 Marquardt Avenue, Santa Fe Springs, CA 90670
                (904) 264-3500
C O Q. CU <
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                CAUTION
         In case of eye contact, (lush with water for
         15 minutes and seek medical attention.
         Wash affected skin areas with soap and
         water. May be harmful if swallowed.  If
         swallowed, induce vomiting  and seek
         medical attention immediately. Contains
         water,  Trisodium Phosphate  (CAS
         #10101-89-0),    Sodium   Hexameta
         Phosphate  (CAS #10124-56-8) and
         Tetrapotassium   Pyrophosphate  (CAS
         #7320-34-5).

         V.O.C. - 0.07 lbs./gal.

         NONPHOTOCHEMICALLY REACTIVE

         TARGET ORGAN EFFECTS: May cause
         eye irritation.
                                                           HEALTH
                                                           FLAMMABILITY
                                                      REACTIVITY
                                                      PERSONAL
                                                      PROTECTION

-------
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            #2606
ALKALINE FOUNTAIN
    CONCENTRATE
      NEWSPAPER AND INSERT
    ALKALINE FOUNTAIN SOLUTION
    DIRECTIONS:  Use 2 ounces of concentrate per gallon of water.
    Conductivity should read approximately 800  mmhos over the
    conductivity of the water used. The pH of the working solution should be
    approximately 10.0.
  2535 Ivy Street East
 Gumming, Georgia 30130
        ANCHOR/LITHKEMKO, INC.
          50 Industrial Loop North
          Orange Park, Florida 32073
           (904) 264-3500
 280 North Ott Street
Corona, California 91720
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                                   CAUTION
                             In case of eye contact, flush with water
                             for 15  minutes  and seek medical
                             attention. Wash affected skin areas with
                             soap and water and seek medical
                             attention if irritation persists. Harmful if
                             swallowed. If swallowed, do NOT induce
                             vomiting and  seek medical attention
                             immediately. Contains water, Solvent EB
                             (CAS   #111-76-2)  and  Sodium
                             Metasilicate (CAS #6834-92-0).

                             V.O.C. = 0.3 Ibs./gal.

                             NONPHOTOCHEMICALLY REACTIVE

                             TARGET ORGAN EFFECTS: Irritating to
                             eyes, skin and respiratory tract. May be
                             absorbed through skin.
                                                      HEALTH
                                                            FLAMMABILITY
                                                            REACTIVITY
                                                            PERSONAL
                                                            PROTECTION

-------
      COMMENTS ON CTG FOR OFFSET LITHOGRAPHY
                  JAMES  E.  RENSON

                    COORDINATOR
               ENVIRONMENTAL AFFAIRS

NATIONAL ASSOCIATION OF PRINTING INK MANUFACTURERS
           PRESENTED AT NAPCTAC MEETING
                NOVEMBER 20, 1991
              DURHAM, NORTH CAROLINA


-------
Comments on CTG for offset lithography.








Ladies and Gentleman:








My name is James E. Renson.  I am Coordinator, Environmental



Affairs for the National Association of Printing Ink



Manufacturers in Harrison, NY.
NAPIM
NAPIM is a national trade association representing small,



medium and large printing ink manufacturers in the U.S.  Its



80 members account for nearly 90% of the total U.S. sales of



printing ink.  The printing ink industry is composed of 224



companies operating a total of 504 manufacturing facilities



according to the U.S. Census of Manufactures for the year



1987.  Total shipments of printing ink in the U.S. were over



$2.7 billion in 1990.  NAPIM has been vitally concerned with



the need to clarify the definition of VOC which currently



varies widely from state to state.  We are also vitally



concerned that the definition of VOC and the application of



this definition to various types of printing inks be



reasonable and fair to the printing and converting



industries in the U.S.
                          1;: r T;
                          s ^ 1

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We would like to compliment Radian Corporation for the



preparation of this draft CTG.  We believe that it is a



comprehensive exposition of considerations to be assessed in



connection with the potential environmental burden from the



offset lithography printing industry in the U.S.  We very



much appreciate this opportunity to comment.







ESTIMATE OF VOC OF NON-HEATSET INKS TOO HIGH







In Section 2.5.1 of the CTG the VOC content for non-heatset



web inks is given as 30% VOC.  We believe this is



unrealistically high.
Table  1 - This table calculates the total weighted average



of VOC for all types of newsink based on the proportion of



total pounds shipped in 1990 for each major type of newsink.



Not only do newsinks account for most non-heatset inks



produced, but they are also typical of other types of non-



heatset web inks as well.  As we show in the table, black



offset ink accounted for about 65% of all the newsink



shipped and conventional or standard newsink, in turn,



represented about 50% of this quantity.  The second column



of the table shows the average percent VOC as measured by



Method 24 based on a detailed analysis of the various types



of these in.  Then using standard offset inks as our


                           "7 po
                           8 
-------
example, we estimate that VOC content is around 5%.  The



weighted average VOC for this type of ink would be 1.3%.



Using the same calculations, we show that the weighted



average percent VOC in all types of newsink shipped in 1990




was around 7.4%.
DEFINITION OF VOC







We note that the CTG is silent on the definition of VOC and



does not delineate the test method to be used.  Based on



previous discussions with EPA staff, it is our understanding



that oven test Method 24 will be specified.  While we are



satisfied that the use of oven test Method 24 is suitable to



measure VOC's for heatset inks, members of the printing ink



industry feel strongly that this test method is much too



severe for measuring VOC content of inks which do not dry



with the application of heat.







Under oven test Method 24 the VOC content is determined by



measuring the weight loss of the sample heated at a



temperature of 110 degrees C for one hour.  Instead,  we



recommend that the test method used in the California Bay



Area known as Method 30 be used.  In Method 30 VOC is



determined by the weight loss when the sample is heated for



one hour at 40 degrees C.  We will show here why we consider



this to be a more appropriate test for no-heat inks.





                           703

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Table 2 - In order to obtain an understanding of the



temperatures which might be expected to be reached on non-



heatset presses, measurements have been made under actual



press conditions.  This slide shows temperatures recorded on



three different types of newspaper presses.   Please note



that 40 degrees C essentially represents the maximum



temperatures that would be reached.
Table 3 - This next slide summarizes sheet fed press



temperatures measured on five different presses.   Note that



in only one case (Komori) did any temperature exceed 40



degrees C and this is a press fitted with an infra red (IR)



unit as are two of the other presses where the temperature



did not exceed 40 degrees C.  Please note that the inks are



not being dried by the application of heat,  but a low



temperature infra red unit is sometimes placed a the end of



a sheetfed press to help set the ink before the sheet enters



the delivery pile.  Please note also that even with the IR



dryer, temperatures are not expected to significantly exceed



40 degrees C.
                            7C4

-------
Table 4 - Method 24 was developed for measuring the VOC's in



paints; not printing inks.  The types of lower boiling



solvents used in paints are not found in non-heatset



printing ink.  Table 4 shows a comparison between mineral



spirits, a solvent commonly used in paints and coatings,



with light distillate oil which are the so-called solvents



used in non-heatset inks.  Solvents with high vapor



pressures and low boiling points used in coatings are



designed to evaporate from the coating while the oils used



in non-heatset inks have low vapor pressures and high



boiling points and are designed to remain with the ink film.
Table 5 - In order to determine the actual emission that



would be expected on a press for various types of news inks,



measurements were taken by ANPA on a full scale press.



Table 5  shows the emissions at critical points on the press



as determined by sampling with an approved EPA sampling



device for airborne vapors (carbon tube).  We consider these



to be very low emission levels.  In order to put them into



perspective it may be helpful to compare them with the



8-hour time weighted average threshold limit value



established by OSHA for airborne mineral spirits which is



2,900mg/M3.
                            7C

-------
Table 6 - Table 6 compares results obtained with Method 30



and Method 24 on the same ink.  It is clear that the



excessively high temperature in Method 24 results in VOC



measurements which do not reflect press conditions








Also shown on this table is a comparison of



thermogravimetric analysis (TGA) results with Method 30.



The TGA apparatus is a very sensitive analytical instrument



designed to give a continuous record of weight loss as a



function of temperature and time.  In order to gain a better



understanding of VOC loss for non-heat set ink, NAPIM



contracted for a series of TGA tests at the U.S. Testing



laboratories.  While only one set of data are shown in this



table, a considerable amount of TGA data were generated have



been provided to Radian.  It demonstrates that Method 30



agrees very well with the more precise TGA analytical



method.

-------
CONCLUSION



The previous slides demonstrate why test Method 24 is not

suitable to realistically measure VOC content of non-heatset

lithographic inks.  Instead oven test Method 30 measures VOC

content at 40 degrees C which is consistent with maximum

temperatures measured on non-heatset lithographic presses.

Therefore NAPIM strongly recommends that the final draft CTG

include oven test Method 30 as the method of choice for

determining VOC content of non-heatset lithographic inks.
so/
comments.jer
                           FV

-------
                               TABLE  1
                       ESTIMATED VOC FOR NEWS INKS
 % OF
 TOTAL
 LBS
               % LBS
AVG.*
% VOC  CALCULATION
                     VOC
                     WEIGHTED
                     AVG. %
 80
BLACKS
      Letterpress
                 35
.35 x .80 x 4
                              1.1
ifset
Standard
Low Rub
No Rub
65
50
35
15

5
10
25
20   COLORS
                                     65 x .80 x .50 x  5
                                                      1.3
                                     65 x .80 x .35 x 10   1.8

                                     65 x .80 x .15 x 25   2.0
                                                           5.1
Oil
Soy
40
60
                               10   .20 x .4 x 10

                                3   .20 x .6 x  3
                                                     0.8

                                                     0.4

                                                     172
TOTAL
                                                     7.4
* Average % VOC measured by Method 24

-------
                       TABLE 2
         NEWSPAPER  PRESS  OPERATING  TEMPERATURES  f°Cl
                               Form Roller   Blanket Cylinder
Circulation    Press Type     Min Max High   Min Max High
37,000         Urbanite       24  34  36     n/a n/a n/a


375,000        Metro          28  34  39     37  36  42


717,000        TKS            28  32  38     29  36  40
Min = Minimum Observed Running Temperature

Max = Maximum Observed Running Temperature

High = Highest Temperature Observed After Press Was Stopped

-------
                                           TABLE  3
                                    SHEETFED   PRESS  TEMPERATURES
>RESS



iPEED,  IPH


-------
                       TABLE 4

                COMPARISON OF MINERAL SPIRITS
                             AND
                LIGHT  DISTILLATE  OIL  (L.D.O.)
                                   VAPOR PRESSURE mm Ha
Temp.
 20

 38

 66

121

177
Rule 66
Min Sp.

   5.6

  12.5

  37.0

 200.0

 740.0
L.D.O.
280 ° C IBP

   0.01

   0.03

   0.18

   3.00

  26.00
Distillation
Range ° C
IBP

50%

FBP
   160

   177

   193
   281

   290

   315
                            711

-------
                     [•ABLE  5
                VOLATILE EMMISSIONS
         DURING CONTROLLED PRODUCTION  RUN
                      (mg/M3)
                           _Ink Type_
Sample         Regular        Low Rub       No  Rub
Location       Black          Black         Black
Right Ink
Form Roller    3.1            5.0           2.6
Left Ink
Form Roller    3.7            5.2          3.2
Pioe Roller    0.6            5.7          1.1

-------
                           TABLE 6
                 COMPARISON OF TGA AND OVEN TEST DATA
                              VOC, % LOSS
INK
Sheetfed
TGA
(40° C)

   0
Method 30
(40° C)
    1.8
Method 24
(110° C)
   14.8
No-Rub News
   0.5
    1.7
   24.3

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        USEPA'S
NATIONAL AIR POLLUTION
  CONTROL TECHNIQUES
  ADVISORY COMMITTEE
        MEETING

   NOVEMBER 20, 1991
   OFFSET LITHOGRAPHY
      CTG DOCUMENT
         I / T
         "/14

-------
     VOC SOURCES
1.  Ink Oil Solvents
2.  Fountain Solution
   Additives
3.  Cleaning Solvents
   a.  Blanket Wash
   b.  Auto Blanket Wash
   c.  Roller Wash
   d.  Other Cleaning
          vis

-------
           Ink Fountain
     Plate Cylinder
    Blanket Cylinder
    Blanket Cylinder
     Plate Cylinder
                                    Inking Rollers
Dampening Roller
     Fountain Solution
                                                  -   Substrate
                                            Dampening Roller
                                                  Fountain Solution
             Ink Fountain
Figure 3-12.  Schematic diagram of blanket-to-blanket printing.
                             3-21
                         716

-------
   CONTROL COSTS
  CONDENSER-FILTER
  CONDENSER-FILTER
w/ACTIVATED CARBON
    INCINERATORS
      THERMAL
     CATALYTIC
        'V' 7
        6 ^ i

-------
       MODEL RULE
        APPLICABILITY



        DEFINITIONS



     EMISSION STANDARDS



    EQUIPMENT STANDARDS



 EMISSION  STANDARDS TESTING



EQUIPMENT STANDARDS TESTING



 MONITORING REQUIREMENTS



 REPORTING/RECORDKEEPING

-------
                 Environmental Conservation Board
                 of the Graphic Communications Industries
An Intra-lndustry Organization for Environmental Affairs
     1899 Preston White Drive
       Reston, VA 22091-4326
703/648-3218 - FAX 703/648-3219
                      ENVIRONMENTAL CONSERVATION BOARD

                                    OF THE

                   GRAPHIC COMMUNICATIONS INDUSTRY, INC.

                        CTG  Committee Draft Comments

                                      on

               United  States Environmental Protection Agency

                        Control Techniques Guideline

                                      For

                        Offset  Lithographic Printing

                           September 6,  1991  Draft

                                  Submitted to  the

                   National Air Pollution Control Technical Advisory Committee

                                on November 20, 1991

    The  following comments on the  September 6,  1991 draft of the
    Offset Lithographic Printing Control Techniques Guideline are
    organized in two  sections.  The first section  (I)  presents  a
    subject-by-subject overview of the draft and the second section
    (II)  provides a sentence-by-sentence critique of the document.
                               printed on recycled paper with vegetable oil ink

-------
                 Environmental Conservation Board
                              Of The
                Graphic Communications Industries
                      CTG  Committee  Comments
                                On
                   Control Techniques  Guideline
                               For
                   Offset  Lithographic Printing
                    (September 6, 1991 Draft)

                       Outline of Comments

 I.  Overview
     A. Introduction
     B. Model Plants
     C. Cleaning Solvents
     D. Fountain Solution
        1. General
        2. Emissions
     E. Inks
     F. Add-on Controls
        1. General
        2. Thermal Afterburners
        3. Catalytic Afterburners
        4. Condenser Filters
     G. Control Device Compliance Testing  (EPA Method 25 and 25A)
     H. Conclusion
II.  Critique of Document Text

-------
I.  Overview

Introduction

The Environmental Conservation Board of the Graphic
Communications Industries (ECB) is an intra-industry organization
for environmental affairs representing the printing industry.
Printing is one of the nations's largest industries, with over
50,000 commercial printing establishments (excluding the
newspaper industry) and more than 800,000 employees.  Although
large in total size, the industry is mainly comprised of many
small entrepreneurial businesses, with 80% of all printers having
20 or -fewer employees.

The ECB would like to thank the United States Environmental
Prptecrion Agency  and In particular the Chemicals and Petroleum
Branch, for the opportunity to comment on the September 6, 1991
draft Control Techniques Guideline for Offset Lithographic
Printing (CTG) at this stage in its development.  The ECB
appreciates the willingness of the Agency to work with industry
experts in the development of this important document.  ECB hopes
that the comments contained herein will prove useful and stands
ready to continue to work with the Agency in the further
development of the CTG.

The preliminary draft version of the CTG presents an attempt by
the Environmental Protection Agency (EPA) through its contractor,
Radian Corporation, to characterize all aspects of the
lithographic printing industry and propose reasonably available
control techniques  (RACT) for controlling VOC emissions from
existing sources, consistent with existing technology and
practices.  Although this draft describes some processes and
emission reduction techniques accurately and in reasonable
detail, it unfortunately contains a number of inaccuracies,
errors, omissions, lacks substantive evidence to support key
points, and appears to rely heavily on undocumented claims.

Outlined below are the areas that the ECB believes must be
revised.  In several areas, quantitative evidence is not
available to document process modification or material
reformulation or substitution.  However, EPA is urged to review
and present the evidence which has been subjected to scrutiny
through publication, testing, and industry experience in
preference to the word of mouth and undocumented claims that make
up such a large portion of this document.  This approach would be
consistent with EPA's stated new approach to environmental
management that includes "-..a more rigorous reliance on sound
science to support EPA's environmental protection mission...".
 (Stephen A. Lingle, Deputy Director, Office of Environmental
Engineering and Technology Demonstration, USEPA, plenary address
to the 1991 Materials Research Society Spring Meeting, printed in
the July 1991 MRS Bulletin).

This draft document addresses the three main VOC emission sources
in lithographic printing which are ink, fountain solution, and

-------
cleaning solvents and recommends methods to reduce these
emissions based on a number of "model" plants.  The ECB comments
discuss these VOC emissions sources, the reductions methods
(technologies) proposed in the draft CTG, EPA's suggested
deemphasis of technologies and emphasis of control levels, and
suggestions for revisions to the draft.  It is imperative that
EPA recognize the differences among the lithographic processes
employed by the industry segments and establish control levels
appropriate to those different material needs.  (The industry
comments below reference the page numbers, in brackets, of the
September 6, 1991 draft CTG.

Model Plants

With three exceptions, the model plants outlined in Tables  3-1
and 3-2 [3-44, 3-45] appear to be reasonable examples of the
various size lithographic printing.

First, the assumption of single blanket units for heatset web
model plants denies the dominant position of blanket-to-blanket
presses in this industry segment.  As a result, the materials
consumption, VOC emissions, and potential reductions are
excessive.

Second, the press width of 38" applied to all facilities other
than newspapers is inconsistent with the data in Figures 3-7 and
3-8 [3-14, 3-15], which would indicate that a 22" or narrower
width is more realistic for the smaller facilities.

Third, all facilities are assumed to operate 3,000 hours per
year.  ECB believes that the following values of 1,500 hours per
year is more realistic for smaller one shift facilities; 3,000
hours per year for two shift (medium sized)  operations; and 4,500
hours per year for the largest facilities.  These more realistic
values should be used to calculate materials consumption, add-on
control device costs, and cost effectiveness of control presented
elsewhere in the CTG.

The materials consumption data in Table 3-3 [3-47] and elsewhere
should also be revised to indicate that large heatset and some
sheetfed lithographic printers in addition to newspapers, have
either lowered or replaced isopropyl alcohol in fountain
solutions with substitutes.  The data presented greatly
overstates VOC consumption for fountain solution by tens or
hundreds of tons for larger printers.

Cleaning Solvents

Low VOC cleaning solutions are proposed as a means of reducing
emissions [2-7].  The draft CTG is recommending water-based
cleaning materials.  The industry assumes that EPA will not
recommend the use of exempt compounds to achieve the 30% VOC
limit.  No evidence is presented to substantiate the claims of
these products actually working and/or lowering VOC emissions.
It is later stated [3-42] these cleaners have been found to be
                            y] n o
                            • > fcj iJ

-------
inferior to solvent cleaners.  It is acknowledged that several
problems are reported with water-based cleaners. If low VOC
materials are to be recommended as cleaning solvents, more
rigorous substantiation other than one performance claim must be
included in the CTG.  As currently proposed, the document only
states that low VOC materials exist, but they may or may not
work.

If use of these materials requires more frequent cleanings,
larger volume use per cleaning, or longer cleaning time, a real
reduction in VOC emissions may not occur.  Also, if highly
volatile organics are used in a low VOC cleaner, emissions from
the cleaner's use may actually result in an increase in total VOC
emissions, due to rapid or even complete VOC evaporation,
relative to a 100% VOC cleaner with a lower vapor pressure.  Low
volatility organic solvents with vapor pressures below 45 mm Hg
at ambient temperature evaporate quite slowly and may leave the
cleaning process primarily as liquid solvent which can be
collected or remains absorbed in the cleaning rag, rather than as
air emissions.

Distinctions must be made between blanket washes and press
cleaning solutions.  The physical requirements between the two
types of cleaning differ which will also affect operations and
productivity.  The document does not distinguish hctween the
cleaning requirements demanded by the various in>. systems
considered.  For example, removing news ink from _r.)c rollers can
usually be accomplished with a lower VOC content material than
removing sheetfed inks.  Difficulty of cleaning is dependent upon
the viscosity of the ink (e.g., as the viscosity of the ink
increases, the effort required for roller, blanket, and press
cleaning also increases).

The information in Table 6-9 [6-17] is based on costs of $0.69
and $0.91 per pound for equal consumption of 100% and 30% VOC
materials, respectively.  Since it is not clear that effective
cleaning can be performed with the untried 30% VOC cleaners, the
additional cost of low VOC cleaner may be higher thereby
resulting in lower emissions reductions.  Additional data is
needed to support the contention that a one-for-one replacement
can be made and that no additional production time will be lost
due to ineffective cleaning.

Although consideration has been given to the benefits of using
untested, low-VOC cleaners [3-40], the replacement of current
organic cleaners with substitutes of lower volatility is not
discussed.  The South Coast Air Quality Manageme-t District
(SCAQMD) has recognized the benefits of a low vapor pressure
cleaning solvent in its recently finalized Rule 1171, Solvent
Cleaning Operations, which supersedes Rule 1130, and limits
solvents used in cleaning lithographic printing equipment to no
more than 900 g/1 VOC and total VOC vapor pressure to less than
25 mm Hg. This limit is considered by SCAQMD as acceptable VOC
emissions reduction technology.  SCAQMD has chosen not to require
water-based cleaners for offset printing due to difficulties
                              ,3

-------
associated with using them.  EPA is urged to consider this
approach in the CTG [4-19].

Furthermore, emissions from cleaning solvents are described as
being equal to the consumption of the VOC components of these
materials [2-9].  This assumption is not correct.  A high
percentage of the cleaning solvent used with automatic cleaning
equipment is transferred to the substrate and in the case of
heatset presses it is transported to the dryer for capture and
control.  With a typical low volatility cleaning solvent, 50% or
more of the solvent may be ultimately controlled.  For manual
cleaning operations, a substantial portion of the solvent is
recovered as liquid waste or remains on the cleaning rag.  For
lower volatility solvents, this may account for as much as 80% of
the solvent consumed.

Another aspect of the issue which has not been fully considered
i& the potential effect on the handling and disposal of liquid
wastes.  The move to water-based cleaning materials creates
expensive treatment options.  The avenues for disposal of liquid
wastes are either treatment or incineration.

Since there is an ever increasing tightening of sewer discharge
limits, the options for disposal are either expensive treatment
equipment or incineration.  Neither waste water treatment nor
incineration are economical.  Unlike 100% VOC cleaners that are
well suited for incorporation into fuel blending operations
because of their high BTU value, water-based cleaners do not
offer an attractive fuel for these operations.  Additional energy
will be required for the incineration of water-based wastes.  It
has been estimated that disposing water-based materials via
incineration costs three times more than the comparable solvent-
based materials.  EPA is urged to consider the financial costs,
additional energy requirements and transfer of media associated
with requiring the use of water-based cleaners.

It is not clear why a method to monitor VOC content in cleaning
solutions [7-10] is necessary.  Accurate measures of potential
VOC emissions can  be simply calculated by using cleaning solvent
consumption records and applying the appropriate factors for
disposal and/or captured emissions.

The use of d-limonene-based cleaning materials should be deleted.
In a January 1990 report issued by the National Toxicology
Program, d-limonene was reported as showing clear evidence of
carcinogenic activity in male rats.

Fountain Solution
1. U.S. Department of Health and Human Servies, National
Toxicology Program, Technical Report Series No. 347, Toxicology
and Carcinogensis Studies of d-Limonene in F344/N Rats and
Mice, January 1990.

-------
General

Taken out of context, the statement at 3-39 that isopropyl
alcohol is a crutch to printers can be misleading.  For certain
printing jobs, the required print quality can only be obtained
when isopropyl alcohol is used in the fountain solution.  As
stated in Chapter 4 [4-19], certain applications such as sheetfed
printing may not be able to reduce or eliminate isopropyl alcohol
as readily as other branches of the industry.

Statements are made about isopropyl alcohol consumption
reductions with refrigerated fountains and through the use of
magnets [2-5, 2-6].  Although refrigeration of fountain solution
will reduce isopropyl alcohol evaporation due to vapor pressure
reduction, the actual emissions reduction will be a function of
fountain temperature and isopropyl alcohol consumption on-press.
The assumption that all isopropyl alcohol is evaporated at the
printing unit, with none of the material carried through the
process is not correct (5-7, ref. 15).  Published studies on both
sheetfed and web presses indicate that more than half of the
fountain solution is transferred to the substrate and in the case
of heatset printing, a significant portion will be carried into
the dryer and exhausted to the pollution control equipment.1

The data in Table 5-3 [5-9] shows cost savings associated with
use of isopropyl alcohol substitutes and VOC reductions (as in
Table 5-1 on page 5-3).  The basis the data used to derive the
17% average isopropyl alcohol level is both in doubt and somewhat
dated.  The 1986-87 survey conducted by NAPL (3-51, ref. 26)
resulted in a 15% average for 1986.  ECB believes that the
average concentration for printers using isopropanol is now lower
as most larger heatset and some sheetfed facilities have already
switched to isopropyl alcohol substitutes.  There are no readily
available cost savings or VOC reductions from fountain solution
for these facilities.  The survey's performed by Radian may
provide some insight.

A device purporting to reduce the surface tension of fountain
solution by "magnetizing" the water is suggested [2-6, 2-10] as a
means of reducing isopropyl alcohol consumption.  Such a claim
should be verified by experimental methods based on a pre-
approved protocol.


1. Karttunen, S. and Lindquist, V., "Water Flow and Surfactant
Effects in Offset Lithography", Advances in Printing Science and
Technology, Vol. 15, Ed.  W.H. Banks, Pentech Press, London, pp.
176-199.


Lindquist, V., Karttunen, S., and Virtanen, J., "New Models for
Offset Lithography", Advances in Printing Science and Technology,
Vol. 16, Ed. W.H. Banks,  Pentech Press, London, pp. 67-96.

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Additionally, certain dampening systems are described
[4-18] as working best with lower concentrations of isopropyl
alcohol due to the surface tension reducing properties of the
brush or spray used to apply the fountain solution.  Again,
unique physical properties are attributed without proper
documentation.  Actually, a brush and a spray generate new
water/air interfaces with the maximum surface tension, i.e. they
act to increase not decrease the instantaneous surface tensions
of water solutions.

Other sections on magnets [4-17, 5-11, 6-15] and the data in
Table 6-8 [6-16] should be deleted unless the claims of magnetic
treatment can be substantiated.  Also, section 5.2.5 [5-9] should
be eliminated since the effect of isopropyl alcohol concentration
on emissions has already been discussed in section 5.2.3.

Although EPA accepts that magnets can change the properties of
water, it remains skeptical that print quality may suffer when
isopropyl alcohol concentrations are reduced in fountain [2-10].
Data derived from laboratory and pressroom studies previously
submitted by GATF indicates that the units do not work .
Additional laboratory and pressroom data resulting from other
studies agrees with GATF's conclusion  .

It is not clear what rationale was used to discount lost
production due to the change from isopropyl alcohol to
substitutes [6-13].  Whether a plant operates 16 or 24 hours per
day should have little effect on the amount of lost production
due to this change.


Emissions

Emissions from fountain solution are described as being equal to
the consumption of the VOC components of these materials [2-8, 5-
7].  Several fundamental concepts regarding these materials are
not considered.  Isopropyl alcohol substitutes and, to a lesser
extent isopropyl alcohol, do not totally evaporate at the
printing unit.  Substantial quantities are transferred to the
substrate where a percentage may be retained or in heatset
operations the majority is driven off and captured in the dryer
exhaust for transport to the pollution control equipment.  Of the
low volatility isopropyl alcohol substitutes such as ethylene
glycol and glycol ethers, in excess of 75% of the fountain


1. Letter to Berry, James, EPA, Research Triangle Park, N.C.,
from Schaeffer, W.D., Graphic Arts Technical Foundation,
Pittsburgh,  Pa., May 15, 1991.

2. Letter to Berry, James, EPA, Research Triangle Park, N.C. from
Schaeffer,  W.D., Graphic Arts Technical Foundation, Pittsburgh,
Pa.,  August 21, 1991

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solution VOC is either retained or captured in a heatset
operation.  It is expected that these materials are also retained
in sheetfed printed products.

Using the basis of 17% isopropanol in the fountain solution and
the value of 1.7% VOC using isopropyl alcohol substitutes,
combined with the much lower (1/4) evaporation of the
substitutes, it would appear that a 40 fold (rather than 16)
reduction in VOC consumption is attainable [4-18].  The lower
evaporation rate of the substitutes also means that fugitive
emissions should be reduced substantially, such that total VOC
emissions from fountain solutions used on presses with oxidizers
should be on the order of 1-5% of similar presses using isopropyl
alcohol.  A blanket application of a factor of ten reduction in
isopropyl alcohol substitute use vs. isopropyl alcohol [5-11] is
not justified for all printing systems.  Although a 90% or
greater reduction in VOC use may be obtained in certain systems,
this is clearly not to be applied across the board as a 90%
reduction in VOC emissions.

The references to 75% VOC in isopropyl alcohol substitutes [4-18,
5-7] are inappropriate.  VOC content of substitutes varies from
one product to another.  The 0.75 factor in equation (5)  [5-7]
should be replaced with a generic term such as "%VOC in
concentrate divided by 100%"-

The claim of 44% isopropyl alcohol reduction with refrigerated
circulators is presented. [4-15].  The use of the 0.44 reduction
factor for the use of all refrigerated fountain solution systems
[5-11] is inappropriate because there are other considerations
beyond the fountain solution temperature that influence alcohol
concentration (e.g., coverage,  water quality, speed of the press,
type of dampening system, and substrate).
In discussing soybean oil inks [3-37], EPA should recognize that
other vegetable oil inks besides soy oil have been and are being
utilized.  Replacement of petroleum with soy, although reducing
the petroleum content, does not necessarily result in any
significant reductions in VOC emissions in nonheatset printing.
Data in Table 5-1 indicate that the vast majority of emissions
from no-heat printing results from fountain solution and cleaning
solvent emissions.  Assuming that the percent of petroleum oils
retained in mixed petroleum/soy inks is the same as for 100%
petroleum inks, replacing 75% of the petroleum oil with soy would
result in emissions reductions of only 6.75 tons of emissions for
plant B-IV (<1% overall reduction), 1.5 tons (4.5%) for C-IV, and
24 tons (12%) for D-VI.

In discussing reactive curing inks [3-38], it should be made
clear that VOC emissions from these materials will be essentially
zero.  VOC content from a Method 24 analysis might indicate a
relatively high VOC content in the uncured material, but as
applied,  the emissions are negligible due to polymerization,
                              ~ i-y

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rather than evaporation in the curing process.  Use of these
materials is restricted to a few special applications.

Add-On Controls

General

The VOC reductions from heatset operations with add-on controls
shown in Table 5-2 [5-6] are misleading due to the omission of
the amount of VOC from fountain solutions and cleaning solvents
being controlled.  By tabulating the reductions only from ink,
the benefit of add-on control is understated.  Add-on controls
may substantially reduce emissions from these other sources,
which will favorably alter the economics and environmental
benefit of these controls.  Tables 5-3 and 6-4 also need to be
revised to reflect this aspect of add-on controls.

The capital costs, annual costs and cost effectiveness in Tables
6-2 [6-6] and 6-3 [6-7] need revision.  They should be based on
more realistic materials consumption data, suggested changes (see
below) in device efficiencies, and in the case heatset include
emissions from sources besides ink, such as cleaning and fountain
solutions, being at least partially controlled.  In addition,
these two tables should contain identical capital and operating
costs.  Also, further cost justification is required to explain
apparent incremental cost discrepancies for the different model
plants.  For example, the relative costs of plant A-II vs. A-I
are >100% for a thermal afterburner, 50% for catalytic, 90% for
condenser filter with carbon and 90% for condenser filter.  It is
not obvious how the equipment was sized for these example
facilities nor how capital and operating costs were calculated.

Additionally, the determination of capital and operating costs
associated with the various model plants is not clearly defined
[6-10].  For example, the largest heatset model plant (A-IV) is
described as a 30,000 scfm facility [6-10].  Yet elsewhere [6-5],
it is stated that  additional incinerators were costed for flows
above 50,000 scfm.  A critical review of costs calculated in the
CTG can only be performed if the capital costs and configuration
of the system(s)  is identified.  For example, significant cost
differences can be expected if pollution control equipment for
plant A-IV consists of three 10,000 scfm devices as opposed to
one 30,000 scfm control.

The basis for the scaling factors in the cost analysis [6-5, 6-9]
is unclear.  These factors should be more fully explained to
allow critical evaluation of the calculated costs.

NOX emissions from afterburners was only briefly mentioned [6-
18].  ECB recommends an analysis of increased NOX emissions
resulting from operation of thermal afterburners at 1600°F (vs.
1350°F) be included.

No consideration is given to other emissions concerns such as the
control of odor by add-on controls [6-18].  Obviously, in

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sensitive areas, odor concerns may come into play.  For odor
control, thermal oxidation is the method of choice.

Thermal Afterburners

The draft CTG does not discuss the use of regenerative thermal
afterburners for controlling emission from printing operations.
Although these devices are relatively new to the printing
industry, a discussion of their operation, destruction efficiency
and costs should be included.

An efficient recuperative thermal afterburner does not require a
residence time of 0.75 seconds at 1400°F for complete oxidation
[4-6].  Operation at 1350°F with a retention time of 0.50 seconds
will provide a high level of control if the system is designed
with enough turbulence and flame contact.  Moreover, operation at
elevated temperature will increase energy consumption, increase
NOX emissions, and reduce equipment life with no detectable
increase in VOC destruction.

The basis for the residence time and combustion chamber
temperature for thermal afterburners [4-6] refers to several
input materials that are totally foreign to offset lithography.
Materials such as C^ to Cc alkanes and olefins, chlorinated
organics and nitrogen containing compounds are not typically
used.  Thermal afterburners for printing are not to be considered
analogous to hazardous waste incinerators.  Recuperative thermal
afterburners operating at 1350°F and residence time of 0.5
seconds have been demonstrated to have outlet concentrations of
less than 20 ppmv in offset printing operations.  In the Illinois
Federal Implementation Plan, EPA has recognized that a 90%
control efficiency for afterburners constitutes RACT for heatset
lithography (55 FR 26877) .

By restricting operation of thermal afterburners to 3,000 hours
per year for the model plants and requiring a 1600°F operating
temperature [6-2], the costs associated with this control are
made considerably higher.

Catalytic Afterburners

The statement is made [2-5] that "Incineration can achieve
approximately 98% control of VOCs".  While thermal afterburners
may provide a very high level of control over an extended
timeframe  catalytic afterburners will show gradual degradation
in performance over time due to deactivation, masking, or
poisoning of the catalyst (as noted on page 4-9).  Therefore,
even if a system with new catalyst may destroy 98% of the VOCs
initially,  a decrease in destruction efficiency should not be
unexpectc-..   if the CTG is to take the position that 98% control
by catalytic afterburners is the minimum acceptable control
efficiency,  the operating costs of the systems must be
substantially increased to reflect the additional costs of
frequent catalyst replacement which will be necessary to maintain
this high level of control.  A more realistic approach would be

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to establish 90% control as the reasonable minimum efficiency for
these systems.  This level of control has been recognized by EPA
as RACT for heatset lithography as part of the Illinois Federal
Implementation Plan (55 FR 26877).

A blanket statement that an unspecified catalyst operating at
840°F with a bed volume of 0.5 to 2 ft3 per 16.8 scf/sec can
achieve 95% destruction efficiency [4-10] is not correct.  In any
given catalytic system, the operating temperature and space
velocity requirements are catalyst specific.  Again, even though
a 95% control may be achieved initially, catalyst degradation
over time will lower this number.  A lower control efficiency
would be consistent with the projected 2-5 year catalyst lifetime
suggested on page 4-10.

Condenser Filters

The discussion of condenser filter systems [2-5, 4-14] states
that up to 97% control can be achieved with these devices and
also suggests the use of carbon canisters coupled with these
devices may increase efficiency.  The stated efficiency of
condenser filter systems of 90% (95% with carbon) [4-14] are
unrealistically high.   Although they provide acceptable VOC
control, the levels stated here, either with or without carbon,
are substantially in excess of normal efficiencies.  Since these
devices are relatively ineffective at controlling captured
fountain solution and cleaning solvent VOCs, the performance of
the condenser filter equipment is overstated.

Although the condenser filters do not offer comparable reduction
efficiencies to afterburners, there are some distinct advantages
when capital and operating costs are considered.  They also do
not directly contribute to the formation of NOX and C02.
The lower removal efficiency has been recognized by EPA in its
most recent determination of RACT for these devices which is set
at 75% control of the non-isopropyl alcohol portion of dryer
exhaust.  The RACT determination was part of the Illinois Federal
Implementation Plan at 55 FR 26877.

Condenser filters are most efficient with high inlet
concentrations and low outside air temperatures.  These
conditions are important because the VOC concentration in the
exhaust of a system (before the carbon) will be at steady state
concentration determined by the properties of the VOCs and the
ambient environmental  temperatures.  If all other factors remain
the same, reducing the inlet concentration to the device will not
necessarily have any effect on the outlet concentration due to
the steady state oil concentration within the unit since this
control technology is subject to influence by seasonal variations
in ambient air temperature.  An increase in the outside
temperature will result in an increase outlet temperature and,
accordingly,  a higher outlet VOC concentration.  If this
technology is to be considered, a more complete analysis of the
process is required, including the function and effectiveness of
control of fountain and cleaning solution VOCs.
                                 10

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Condensed ink oil from a dryer still has a very strong  "burnt
oil" odor from the smaller cracked molecules.  Carbon filters can
help reduce the uncondensible odors, but the carbon must  be
monitored on a daily basis so that it can be regenerated  before
the odor breakthrough is noticeable.

Although cleanup efficiencies are usually better when ambient
temperatures are lower, sometimes very rapid cooling can  cause
submicron aerosol particulate formation.  These submicron
particles tend to pass through the filter and carbon bed.

The contention in Table 6-3 that condenser filter systems require
less maintenance than either catalytic or thermal afterburners is
incorrect.  Just the opposite is true.  Based on industry
experience, the condenser filter systems require the most
maintenance of the three add-on control systems.               \ -  n
ri r t»L  _*. S 	-^     / ^ j- —7"'   * ,  ^.   __ —^' 	 ft t~*  /^  i*si *> i~~ i<*  J&&& &%s1 Cr ( X. ^—-
ff e/*l* t^yr? Sf-^CFJfrj @f££&*£*(/& fj / <$ / (rt&fc£C */' C~G^7 I ^&£- (-*&*'*' *^* C*-T~j  •>—> *•  f / S
Table 6-10 [6-20] does not contain the energy costs or  emissions
associated with installation and operation of the steam
generating capacity required for regenerating the carbon  beds on
condenser filter systems.  The table should be revised  to reflect
these costs.  Footnote d has a steam factor of 3.5 Ibs  of
steam/lb carbon.  This appears to be the annual consumption,
based on data in Table 6-3 and the 5-year carbon life stated  on
page 4-14.  (A 3000 scfm system requires about 4750 Ibs of carbon
and 17,200 Ibs of steam.)  It is unclear how frequently steaming
must occur and the amount of steam that is required per steaming.

There appear to be some unfounded generalizations in the
environmental impact section which can be misleading  [2-15].   For
example, use of oil collected in condenser filter systems to
replace fuel in dryers may be more complicated than simply
burning the material.  State regulations governing disposal of
this liquid may require the printer to tes:- the oil, possibly
obtain a RCRA Part A and B permit (require  of all treatment
storage and disposal facilities), and manifest the material as a
hazardous waste, precluding its use for fuel.  Additionally,  the
cost of modifying a dryer to burn this fuel in combination with
gas has not been included.  Although a value of $0.63/gal for
recovered oil [C-38] has been used to calculate cost for  these
systems based on its use to fuel the dryers, the actual value or
sale or cost for disposal of this material will significantly
lower the economics of this technology.

The potential water pollution problems of high molecular  weight
oil combined with water in condenser filter systems appears to be
understated [2-15. 6-21].  Oil-contaminated water from  these
systems may require extensive treatment before it can be
discharged.

Other Issues

The discussion of EPA Methods 25 and 25A  [7-6] states that Method
25 is not applicable to concentrations below 50 ppm and that


                                 11

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Method 25A is not recommended for incinerators  (where the outlet
concentration should be below 50 ppm).  No recommendation is  made
as to appropriate methods for compliance testing  of afterburner
systems.  The industry does not agree that Method 25 should be
recommended as the best test method for determining emissions
from dryer exhausts. The method is cumbersome,  expensive,  and
provides  inconsistent results and is not suitable for measuring
control device efficiencies, especially those with outlet
concentrations at or below 50 ppmv as C^.

It must be emphasized that steady-state conditions in the heatset
industry  are normally less than one hour for single press
operations.  For multiple press exhausts into a common control
device, steady-state conditions may never exist,  much less for
the three one-hour periods as required for a Method 25 protocol.
Presses'  frequent starts and stops and changes  in operating
speeds greatly affects flow rates and concentrations of exhausts
reaching  the control device.  Thus it would be  very helpful if
there could be more flexibility in the required one hour  steady-
state sampling time.

Method 25A should be the recommended method especially for
control device exhaust emission concentrations  of 50 ppmv or  less
as Cj_.  By utilizing simultaneous inlet and outlet analyzers,
instantaneous efficiencies can be determined, regardless  of
changes in press operating conditions.  It may  also be
recommended as a screening test for determining unknown
concentrations from the outlets of emission control devices.

Reference is made [7-7] to a modification of Method 24 that is
under development for VOC determination of fountain solution  and
cleaning  solutions.   ECB Respectively requests  further detail
concerning the modifications being considered.  In the meantime,
reference to and application of the method should be eliminated.

Summary

The recommendations for control technology, fountain solution and
cleaning  solvent [2-14, 2-15] must all be revised.   Condenser
filter systems with carbon can not routinely control VOC
emissions at 95%.  control device performance on  a routine basis
should be established at the 90% efficiency level.   There  is no
evidence that suggested isopropyl alcohol concentration levels
can be met by printers.  It is entirely unclear what basis was
used to determine what level of isopropyl alcohol  is acceptable
at sheetfed facilities or why a larger printer can necessarily
function at an isopropyl alcohol level only half  of what  is
required for smaller facilities.  No mention is made of the use
of low volatility cleaning solvent or emissions reductions
obtainable through control or revised handling and/or cleaning
procedures.
                                12

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II.  TEXT CRITIQUE of Preliminary Draft of Offset Lithographic
    Printing Control Techniques Guideline

Table of Contents, p. ii, Title for 2.5.6:
     Make "Emission" plural

Table of Contents, p. ii, Title for 2.6.3:
     Make "Emission" plural

Section 2.1, p. 2-1, par. 2, line 5:
     The term "image plate" used extensively in this draft is not
common the industry.  The expression "lithographic plate" is
recommended.

Section 2.1, p. 2-1, par. 2, line 9:
     Transfer of the ink from the lithographic plate is
recommended instead of "Transfer of the image...-1*-

Section 2.2, p.2-2, par. 1, line 1:
     Make the word "arrangements" singular (arrangement)

Section 2.2, p. 2-2, par. 1, line 3:
     Insert the word "fountain" between..."dampening" and
"system."

Section 2.2, p. 2-2, par. 5, last line (11):
     Delete the word "color" and replace with "pigmentation".

     Insert the words "inks for" between "than" and "other"-

Section 2, p. 2-3, Figure 2-1:
     Figure requires an impression cylinder.

Section 2.2, p. 2-4, par. 1, sentence 2:
     Please provide reference.

Section 2.2, p. 2-4, par. 2, line 1:
     Delete "printplate" and replace with "lithographic plate."

Section 2.2, p. 2-4, par. 2, line 5:
     Delete "acids of buffer salts" and replace with "acids and
buffer salts."

Section 2.2, p. 2-4, par. 3, line 1:
     Isopropanol has not traditionally been used as the dampening
aid.  Isopropanol was introduced in the 1950s in conjunction with
Dahlgren or return-flow type dampening systems.  The isopropyl alcohol
enables the fountain solution to spread on the ink form roll and
be carried to the lithographic plate surface.

Section 2.2, p. 2-4, par. 3, last sentence:
     Please cite reference.

Section 2.2, p. 2-4, par. 4, sentence 1:
     Delete "paper pieces" and replace with "paper components."

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Section 2.2, p. 2-4, par 1, sentence 2:
     Delete the word "commercial" and replace with "single".

Section 2.2, p. 2-4, par 1, sentence 3:
     Begin sentence with "Different cleaning solutions...".

Section 2.4.1, p. 2-5, par 2, first sentence:
     Make the first sentence explicit heatset web offset
lithographic printing.

Section 2.4.1., p. 2-5, par. 3, sentence 2:
     Few dryers are equipped with combination burners adaptable
for liquid fuels.  Use as boiler fuel is more common.

     This section states that condenser filter systems can
achieve as high as 97% VOC removal efficiency, while 90% is
typical.  It further states that 95% can be guaranteed if carbon
filters are added to the discharge.  Actual experience does not
confirm these efficiencies.  Industry experience indicates lower
levels of performance during sustained operations.

     In addition, the type of test method used for testing
condenser filters can have a bearing on the cleanup efficiency
values.  In many cases USEPA Method 5 is used and the oil is
measured as if it were 100% particulate or condensed oil aerosol.
In reality, it has been observed that about 15% of the oil can
break down or "crack" in the vicinity of the dryer burner flame
envelope.  The cracking results in the creation of smaller more
volatile molecules that do not condense well at ambient
temperatures.  These smaller molecules are still VOCs but they
are not trapped in the Method 5 and therefore escape detection.
When a Method 25 or 25A is used, the cleanup usually is not as
high as a Method 5 result.

Section 2.4.1, p. 2-5, par. 3, sentence 2:
     Delete "fuel for boilers" and replace with "fuel for
dryers".  Use in dryers has not proved acceptable.

Section 2.4.1., p. 2-5, par. 3, last sentence:
     Carbon has been used in a number of ways to clean up
hydrocarbon in the outlet.  A supplier-specific "carbon canister"
version should not be suggested as the norm.

Section 2.4.2, p. 2-6, par. 1, last sentence:
     Delete the word "trays".

Section 2.4.2, p. 2-6, par. 2:
     Deletion of the magnetic processing of lithographic fountain
solutions is suggested because GATF, other laboratories, and
printing plants have been unable to document any positive
effects.  References to 500 plants in this paragraph and 200
printing units (Section 4.3.2) are not compatible.

Section 2.4.3.1,  p.  2-6,  par. 1, last sentence:

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     Documenting the date of the 17 percent average is important
because of the rapid decrease in isoprc- i alcohol use by the industry.
The 1986-87 survey conducted by NAPL resulted in a 15 percent
average in 1986 (3-51, ref.  27).  The 12 percent difference  (15
vs 17) significantly effects the anticipated RACT VOC reductions.

Section 2.4.3.1, p. 2-6, par. 2, sentence 2:
     The glycol ethers are classified as hazardous air pollutants
and should be noted.

Section 2.4.3.1, p. 2-6, par. 2, sentence 2:
     The term "Cellosolve" is a trade name for a specific glycol
ether and should be replaced by that term.

Section 2.4.3.1, p. 2-7, par. 2, first sentence:
     There are many different factors beyond the type of
dampening system that influence the ability to reduce or totally
replace isopropyl alcohol.  For example, ink type, coverage,
press speed, substrate, roller type and condition, and water
quality all effect the transition to lower levels or substitutes.

Section 2.4.3.2, p. 2-7, par. 1:
     Differentiate between blanket and press cleaners.
     d-limonene is classified as a carcinogen for male rats.

     Avoid the terms "non-toxic" and "nonhazardous" because of
the absence of generally accepted definitions for them.

Section 2.5.1, p. 2-7, Table 5-1, p. 5-3:
     Inclusion of single color heatset and nonheatset presses
will reduce ink use significantly.  The 77 tons annual usage is
believed to be 35 to 50 percent too large for plants A-l and B-l.

Section 2.5.1, p. 2-8, par.  2, sentence 3:
     Provision should be made for waste and spoilage amounts in
the ink use factors.

Section 2.5.2, p. 2-8, par.  1:
     All of the fountain solution does not evaporate "after
delivery to the printing plate."  High speed photographs  and
infrared reflectance studies  demonstrate the existence of
fountain solution on the plate surface and transfer to the
blanket.

     No mention is made of waste and spoilage amounts in the ink
use factors.  Provisions should be made.
1. Ink-Water Balance, Parts I and II, Flint Ink Corporation,
Detroit, Michigan.

2. Pyliotis, D. "Der Wasserhaushalt im Offsetdruck", FOGRA-
Forschungsbericht 3.214, Munchen (1974).

-------
     The concept that no water or isopropyl alcohol is disposed is not
correct.  Printers routinely discard fountain solutions either on
a predetermined frequency (i.e. weekly)  or when it becomes
contaminated.

Section 2.5.3, p. 2-9, par.  1:
     The assumption that all cleaning materials are evaporated at
the plant is not correct.  Up to 80% of solvents used for roller
or press cleaning are retained in the cleaning rags, collected as
liquid waste for disposal, or may be controlled.

Section 2.5.4, p. 2-9, par.l:
     Control equipment efficiencies should be representative
averages not the maximums.  For example, catalytic incineration
should not be expected to achieve 98 percent efficiency on
average.

     Cleanup efficiencies in excess of 98% for catalytic
afterburners is achievable with new systems, but can slowly drop
to lower levels as the catalyst becomes masked or poisoned.  Some
manufacturers use a deep bead-type catalyst beds to help
alleviate this problem.  Nevertheless, a cleanup efficiency of
90% is probably more reasonable for longer catalyst replacement
intervals, thus reducing operational costs.

     The question of long term efficiency and economics of carbon
canisters on condenser filters makes the 95 percent level
suspect.

Section 2.5.5, p. 2-10, par. 1, sentences 1 and 2:
     There is no theoretical or practical basis for the claimed
effects of magnetism.

Section 2.5.6, p. 2-10:
     In heatset web offset and sheetfed lithography, provision
must be made for blanket cleaners which will dissolve blanket
debris, that is, cleaners with VOC content approaching 100
percent.  These cleaners will maintain productivity and minimize
waste with the high viscosity inks1.

Section 2.6.1, p. 2-11, par. 2, last sentence:
     Not "fuel for the dryer" but "fuel for a boiler."  "Fuel for
the dryer" still exists in sections 2.5, 4.2.3.2, 6.1.1, 6.1.4,
6.4.2.

     Section, in general, give no indication of economics in
increased scale of emissions due to heat recovery, multiple


1. MacPhee,  John and Gasparrini, C. Robert, "Test Run to
Determine the Effect of Blanket Washing on the Concentration of
Combustible Vapor in the Dryer of a Heatset Web Offset Press",
TAGA Proceedings 1984, Technical Association of the Graphic Arts,
Rochester, N.Y..
                            j. O

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presses tied to single control units, etc.

Section 2.6.1, p. 2-11, par 3:
     For control at 95% or higher it is likely that catalytic and
thermal units might cost nearly the same since the catalyst would
need to be replaced at least every two years.  On the other hand,
for control at the 90% level, catalytic units could tolerate a
much higher level of poisoning and still achieve 90%.

Section 2.6.2.1, p. 2-12, par. 3, sentence 1:
     The optimism in this sentence does not recognize the
magnitudes of the costs of conversions, including spoilage.  The
projected annual savings, for example, in the sheetfed sector
barely approach the values of single printing jobs.

     The costs associated with higher roller maintenance,
potential water treatment, and experimentation with new types of
rollers need to be taken into consideration.

Section 2.6.2.1, p. 2-12, par. 4:
     Anticipated material "savings" are overstated because they
are based on reductions from an average isopropyl alcohol
concentration of 17%.  As previously described, ECB believes that
the 17% average is not representative.

Section 2.6.2.2, p. 2-12, par. 1:
     Again, VOC "reductions and savings" are overstated, because
average isopropyl alcohol concentrations are based on the 17%
average.  Additionally, some sheetfed and heatset web facilities
are currently using refrigeration as a means to reduce isopropyl
alcohol consumption and for quality control purposes.

Section 2.6.2.3, p. 2-13, par. 1 and 2:
     Delete entire section and references to magnetic processing
of fountain solutions.

Section 2.6.3 p. 2-13, sentences 1 and 2:
     Again, please define the term "non-toxic" as previously
mentioned.  No reference is made to the questionable technical
feasibility of these cleaners in offset printing.

Section 2.7.1, p. 2-14:
     Delete "95 percent" and replace with "90 percent".

Section 2.7.2.1, p. 2-14:
     Delete "1.6 percent" and replace with "8 percent".  Delete
"3 percent" and replace with "12 percent"-

Section 2.7.2.2, p. 2-14, par. 1 and 2:
     No basis for the proposed two levels of isopropyl alcohol
concentrations is presented.  The discussion is arbitrary and not
reasoned.   Dampening requirements for sheetfed printing are
dictated by the types of presses, dampening systems, and work or
jobs being printed.  These factors do not change with the size of
the pressroom and its equipment.

-------
In paragraph 1, delete "6 percent" and "10 percent" and replace
with "10 percent" and "15 percent", respectively.  In paragraph
2, delete " 3 percent" and "5 percent" and replace with "10
percent" and "15 percent", respectively.

Section 2.7.3, p. 2-15:
     Industry needs separate provisions for blanket and press
cleaning solutions at least for heatset and sheetfed lithography.
Blanket cleaners require high VOC concentrations as discussed in
Section 2.5.6 comments.

Section 2.8, p. 2-15, par.l, sentence 1:
     Insert the word "heatset" between "from" and "offset".

Section 2.8, p. 2-15, par. 2, sentence 2:
     Distinction needs to be made between catalytic and thermal
incineration in the generation of NOX.  Emissions of NOX is
typically twice as high with thermal incineration and increases
with increasing temperatures.

Section 2.8, p. 2-15, par 3:
     The problem of waste disposal of recovered "gunk" and oil
contaminated water in condenser filters should not be minimized.
It can be a major factor.  Health related issues of dealing with
recovered waste and equipment cleanup can also be a
consideration.

     In sentence 3, delete "(imperceptibly)".

Section 2.9, p. 2-15, par. 1, sentence 2:
     Does "Exhaust from heatset ink drying...." mean "Controlled
exhaust from...-"?  If so, please be explicit.

Section 2.9, p. 2-16, par. 2, sentence 1:
     The comparison is suspect because the model heatset and non-
heatset web presses are assumed to consist of single units
("single blanket"); whereas, newspaper presses consist of "double
blanket" units.  Ink consumption is assumed to be directly
proportional to the number of units.

Section 3.1, p. 3-2, par. 2, sentence 2:
     Delete the words "March, April, and May of"

Section 3.1, p. 3-2, par. 2, sentence 1:
     Include screen printing.

Section 3.2, p. 3-2, par. 1 and 2:
     Delete "image plate" in the numerous uses and replace with
"lithographic plate"-

Section 3.2, p.3-2, par.  2, sentence 1:
     Delete "ink reservoir" and replace with "ink fountain".

Section 3.2, p. 3-2, par. 2, sentences 2, 3, and 4:

-------
     Delete "image" and "image plate" and replace with "ink" and
"lithographic plate",  respectively.

Section 3.2,  p.  3-2, par.  3, sentence 1:
     Insert the word "generic" between "two" and "types"-

Section 3.2,  p.  3-2, par.  3, sentence 2:
     Revise to read: "...a heated dryer to evaporate ink oils and
cause the printing inks to set and dry.M-

Section 3.2,  p.  3-3, par.  4, sentence 3:
     The scope of sheet-fed lithography is much too narrow.
Sheetfed lithography is the source of all types of commercial
printing, e.g.,  periodicals, advertising, books, business forms,
brochures, folding paper boxes and metal decorating.  Large
volume production jobs 'require the economics of higher speed web
processes.

     Delete the word "specialized"

Section 3.2,  p.  3-3, par.  4, last sentence:
     Delete "individual sheets of"

Section 3.2,  p.  3-4, par.  1:
     Population of weekly newspapers is in excess of 7000 with
some 3100 having presses,  usually single web width newspaper
presses.  They require consideration and inclusion in the CTG.

Section 3.2,  p.  3-4, par.  1 and Figure 3-1:
     The data appears to indicate a total of newspaper facilities
that is larger that the 1,626 noted in the text, the right hand
column should be labeled as ">250,000", and the footnote gives a
31/67% split on morning and evening papers which totals only 98%.

Section 3.3,  p.  3-4, par.  1, lines 6, 7 and 8:
     Delete the word "approximately"

Section 3.3.1.1, p. 3-4, par. 2, sentence 2:
     Revise to read: "-..  one blanket per unit.".

Section 3.3.1.1, p. 3-4, par. 2, sentence 3:
     Revise to read: "...  Two blankets per unit although...".

Section 3.3.1.1, p. 3-4, par. 4, sentence 1:
     For a CIC press and the consistency of terminology recommend
that the five printing systems be referred to as "units" and the
total assembly of five units be a "couple."

     The description of the CIC press implies that this type of
press may operate as a perfecting press.  This is physically
impossible based on the design of the press.

Section 3.3.1.1, p. 3-7, par. 1, sentence 2:
     As suggested previously, interchange the words "units" and
"couples" for consistency and extended calculation.

-------
Section 3.3.1.1, p. 3-7, par. 1, sentence 3:
     Revise to read: "... printing sequentially up to five colors
on one side of the web..."-

Section 3.3.1.1, p. 3-7, par. 3:
     This and the following paragraph together with Figures 3-5
and 3-6 deal with the number of presses operated by given
percentages of companies.  Press models, however, deal with the
number of units in plants.  One additional step could facilitate
the comparison between models and industry profiles.

Figure 3-3, p. 3-8:
     Change this illustration to one of a lithographic CIC press.

Section 3.3.1.2, p. 3-12, par. 1, sentence 2:
     Cylinder gap width comparison between web and sheet presses
has no utility for present purposes.

Section 3.3.1.2, p. 3-12, par. 1, last sentence:
     They may have infrared sources to accelerate ink setting.

Section 3.3.2, p. 3-12, par. 2 and 3:
     Press size is described by the length and circumference of
the press cylinders, not the "maximum length and width of the
paper."

     The discussion of press size interchanges the definition of
length and width, at one point defining width as the
circumference of the cylinder and later using it in the
traditional across the cylinder dimension.  The text should be
clarified to use the term width in the latter context and cut-off
length (or length) in the former.

     Delete all references in this paragraph to the dimensions
and orientation of the job on the press because most of the
current description is incorrect or confused.

Section 3.3.2, p. 3-13, par. 3, line 1:
     Delete the word "determine" and replace with "determines"

Section 3.3.2, p. 3-13, par. 3 and 4:
     Confusion is again created by the attempt to omit perfecting
presses or to equate a printing couple on a heatset web offset
press to a single press unit instead of the two printing units
involved.   The importance involves both materials and consumption
per press unit and the costs of process modification for each
unit, i.e., a five couple heatset press involves ten printing
units.

Section 3.4.1.1, p. 3-13, par. 1, sentence 2:
     Change "web" to "roll."

Section 3.4.2, p. 3-20, par 1, sentence 2:
     Delete "image plate" and replace with "lithographic plate".

-------
     Insert the word "usually" between the words "plate" and
"first" because exceptions exist in Dahlgren type dampening
systems.

Section 3.4.2, p. 3-20, par. 1, last sentence:
     Begin sentence with "The lithographic plate then..."

Section 3.4.3, p. 3-23, par. 2 and 3:
     Move the last sentence in paragraph 2 to the last sentence
in paragraph 3 and revise to read: "The anilox and injector
inking systems are used principally on newspresses."

Section 3.4.4, p. 3-28, par. 1, sentence 2:
     Delete "metering" and replace with "fountain"-

Section 3.4.5, p. 3-28,-par. 1, last sentence:
     Delete "sets" and replace with "dries".

Section 3.4.5, p. 3-28, par. 2, sentence 4:
     Delete "much" and replace with "controlled portions".

Figure 3-17, p. 3-29:
     The "M" roll should be the "F" roll for fountain roll and a
metering roll should be introduced tangential to the chrome roll,

Section 3.4.5, p. 3-32, par 2, sentence 1:
     Delete "270" and replace with "220."

Section 3.4.5, p. 3-32, par. 1, sentence 2:
     Change "burning much" to "oxidizing some of the oil."  The
original statement may have been true for direct flame dryers,
but is not the case in hot air dryers.  This point has caused
confusion in application of the AP.42 retention factors to
heatset printing in the past.

Section 3.5.1, p. 3-36, par. 1 sentence 3:
     Insert "form a continuous film which fixes the "between"
"Binders" and "aid."

Section 3.5.1.1, p. 3-36, par. 1, sentence 2:
     Delete the word "inks" and replace with "ink vehicles."

Section 3.5.1.1, p. 3-36, par. 1, last sentence:
     Insert the word "approximately" between "of" and W90°F"

Section 3.5.1.1, p. 3-36, par 3, sentence 1:
     Delete the word "solvent" and replace with "ink oil."

Section 3.5.1.1, p. 3-36, par. 3, sentence 2:
     Delete the word "solvents" and replace with "oils."

     Same change should be made in the last sentence in the
section.

-------
Section 3.5.1.2, p. 3-36, par. 1, sentences 1:
     Revise to:  Non-heatset ink oils have lower vapor pressures
than heatset ink oils and the inks are not as viscous.

Section 3.5.1.2, p. 3-37, sentence 2:
     Insert "to 8" between "4" and "hours"

Section 3.5.1.2, p. 3-37, par. 1, sentences 2, 4 and 5:
     Delete the word "dry" in all three sentences and replace
with "set."

Section 3.5.1.2, p. 3-37, par. 2, sentence 1:
     Insert the words "in some newspaper inks" between "popular"
and "for.."

Section 3.5.1.2, p. 3-37, par. 3, sentence 1:
     Delete the word "another" and replace with "the major."

Section 3.5.1.2, p. 3-37, par. 3, sentence 3:
     Delete "4" and replace with "8."

Section 3.5.1.4, p^ 3-38, par. 2, sentence 2:
     Infrared inks are not radiation curing inks.

Section 3.5.1.4, p. 3-38, par. 2, sentence 3:
     Delete "cross-linking proprietary chemical components" and
replace with "proprietary cross-linking chemical compounds"

Section 3.5.1.4, p.3-38, par.2, sentence 5 and 6:
     Delete the word "mechanisms" and replace with "components."

Section 3.5.2, p. 3-39, par. 1, sentence 1 and 3:
     Delete the word "printplate" and replace with "lithographic
plate."
     Delete the word "good" and replace with "competitive."

Section 3.5.2, p. 3-39, par. 1, sentence 3:
     Change to "acids and buffer salts."

     Delete the word "printplate"


Section 3.5.3, p. 3-41, par. 1 and 2 and the balance of the par.:
     Once the distinction between blanket and press cleaners is
established, as in the beginning of the second paragraph, then
the distinction should be maintained throughout the section.

     Par.  1, last sentence should start: "Blanket cleaning is
required	"

     Cleaning blankets, for example, once or twice a shift would
be very infrequent in heatset web offset printing.  The frequency
is dependent upon many factors involved with specific printing
jobs.
                                 10

-------
     It is industry's experience that the more viscous the ink,
i.e., sheetfed and heatset web offset, the more difficulty will
be encountered in the cleaning and the greater the need for
cleaner solvency to maintain efficiency.

Section 3.4.5, p. 3-34, Figure 3-21:
     The figure needs further captioning to explain how the chill
stand functions in the printing process.

Section 3.4.6, p. 3-32, par. 2, last sentence:
     Revise as follows: "...of printed paper from the dryer by-
passing the folder, moving through the sheeter and onto the
delivery."

Section 3.5.3, p. 3-41, par. 5, sentence 1:
     Delete the words "boiling", "flammable", and "greater" and
replace with "flash", "ignitable", and "less", respectively.

Section 3.5.3, p. 3-42, par. 2:
     Do not believe that proposed RACT cleaning solutions could
function for UV or thermally catalyzed inks.

Section 3.6, p. 3-42, par. 1, sentence 1:
     Delete the word "processes" and replace with "steps."

Section 3.6, p. 3-43, par. 2:
     Models for heatset and nonheatset web offset omit
consideration of single color  (one to two unit) presses, a very
common production unit.  Total units should range from 1-6 in
both models for very small plants.

     Omission of perfecting presses eliminates probably the most
common press in heatset web offset printing.  Four printing
couples with eight printing units and five couples with ten units
are probably the most popular presses.

     Using 3000 annual hours of operations for all models
exaggerates equipment utilization for all but the largest plants.
A graduated scale of operations ranging from single shift,
approximately 1500 hours, to two shift, 3000 hours (in medium
size plants), and to 45000 hours for the largest plant size
probably constitute better levels of productivity.

     Please see suggested revised Tables 3-1 and 3-2 in Appendix
A.

Section 3.6.1, p. 3-46, par. 2, last sentence:
     Clarify what is expected from plant records.

Section 3.6, p. 3-44, Table 3-1:
     To attribute single blanket status to total units for
Heatset and Non-Heatset Web Model plants seriously biases their
comparison with single units in sheetfed and other presses.
                                 11
                              :3

-------
Section 3.6.2, p. 3-47, Table 3-3:
     A 30-40-fold increase in ink consumption per unit is
postulated when comparing 4 total units for sheetfed with 4 units
for heatset web offset.  This does not make sense.  Please refer
to the discussion of p. 5-1, paragraph 1.  In addition, alcohol
use rates exceeding ink use rates in non-heatset web offset is
very questionable for the industry segment.

Section 3.7, p. 3-49, references:
     Reference number 5 needs updating, the 14th edition (1989)
of the Pocket Pal is available.

     Reference number 7 needs updating, the 5th edition (1988) of
the Printing Ink Handbook is available.

Section 4.1, p. 4-1, par. 1, sentence 2:
     Delete "where the solutions contains isopropyl alcohol" and
insert the phrase "solution, which contains isopropyl alcohol  (or
alcohol substitutes)"

     Insert "partially" between "are" and "driven."

Section 4.2, p. 4-1, par 1, last sentence:
     Suggest deletion of "for reuse" since lithographic printers
rarely reuse the recovered VOC.

Section 4.2.1-4.2.3.3: thru 4-14; p. 4-2 thru 4-14:
     The description of the incinerators did not appear to be
based on typical current design parameters or current
technologies.

Section 4.2.1, p. 4-2, line 6:
      Delete "ignition" and replace with "combustion"

Section 4.2.1.1 , p. 4-2 and 4-3, par. 1:
     This document assumes that all thermal units use a
combustion air source for burner performance.  This can lead to
erroneous data on operating cost both electrical and gas.  Some
incinerators use a raw gas burner.  Fuel consumption can be about
35 percent lower for raw gas burners.

Section 4.2.1.1, p. 4-2 and 4-4:
     The document assumes that over 0.75 seconds residence time
and operating temperatures of 1600°F are necessary to achieve
proper cleanup.  Again, this can be expensive when calculating
operational costs.  For reasonable control with new equipment at
99% and at 95% in continuing service, a temperature of 1350 °F
and a residence time of 0.5 seconds is sufficient.  Recuperative
thermal incinerators have a temperature limitation of about 1450
to 1500°F due to the metal heat exchangers.  Changes to these
levels as recommendations would allow for significant savings  in
operating costs.
                                 12

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Section 4.2.1.1, p. 4-4, par. 1, sentence:
     If secondary heat recovery is used, note that appropriate
equipment prices should be added.

Section 4.2.1.1, p. 4-3, par. 2, last sentence:
     Please provide a reference.

Figures 4-1 and 4-2, p. 4-3 and 4-5:
     Induced draft fans now rarely used.

Section 4.2.1.2, p. 4-6, par. 1:
     Delete sentence referring to hazardous waste incinerators.
This is not relevant to VOC control from lithography.  Very
questionable whether the kinetics of oxidation for C^ to C5
alkanes should be extrapolated to C12 and C18*

     A reference to the increased formation of NOX/ a
photochemical reactant,  as incinerator temperature is increased
from 1400° to 1600°F should be included.

Section 4.2.1.2, p. 4-6, par. 2, sentence 1 and par. 3, p. 4-7:
     States that al. incinerators can obtain 98% destruction
efficiency if operated at 14OO3 F- with a 0.75 second residence
time.  Not necessarily correct as some new units will not attain
this value because of poor mixing or poor design.

Section 4.2.1.3, par. 1, p. 4-7, sentence 2:
     First and only mention of "fluctuations in flows."  Multiple
press emission controls by a single incinerator requires a
variable volume burner in conjunction with extensive valving
which should be referenced.

Section 4.2.2.1, p. 4-7, par. 1, sentence 3:
     No mention is made of mixed oxide catalysts.

Section 4.2.2.1, p.4-7, par. 2, sentence 2:
     Delete "about" and replace with "above"

Section 4.2.2.2, p. 4-9, par. 2, sentence 2:
     Masking is not completely reversible as this paragraph
indicates.

Section 4.2.2.3, p. 4-10, par. 1:
     Catalytic Oxidizer Efficiency.  Suggest use of the term
gaseous hourly space velocity (GHSV) rather then catalyst-to-vent
ratio.  For the example in this section the GHSV would be
calculated as follows:

16.8 sft3    * 60 seconds * 60 minutes = 60,480 sft3 air
     second       minute       hour             hour

60.480 sft3/hr   = 120,960 (hr-1)
0.5 ft3 catalyst
                                 13

-------
Thus this section states a 96% VOC destruction rate at 840°F.
operating temperature with a space velocity of 30,000 to 120,000
hr-1 GHSV.  More typical is a space velocity of 9000 GHSV at
650°F.  This low space velocity means that there is a larger
volume of catalyst for each scfm of exhaust.

     Replacement will be accelerated by frequent process cycling
in heatset web offset printing which translates into frequent
temperature cycling of the catalyst.

Section 4.2.2.2, p. 4-10, par. 2, sentence 2:
     The reference to service life of a catalyst of being 3 to 6
months which is true for monolith units, but not for deep bed
bead substrate design units.  Some deep bed manufacturers provide
a 30 month catalyst warranty even with normal levels of heatset
poisons present and catalysts have been in lithographic service
in excess of five years..

Section 4.2.3.1, p. 4-11, par. 1, last sentence:
     Delete "or"

     Delete "first drop of liquid is formed" and replace with
"condensation can occur"

Section 4.2.3.1, p. 4-11, par. 2, sentence 2:
     Delete the word "valuable"

Section 4.2.3.2, p. 4-14, par. 2 and 3:
     A CTG requires actual experience, not "expected low
solubility of organics" or a five year carbon life.

Section 4.2.3.2, p. 4-14, par. 4, sentence 4:
     What would be done with a 3 shift operation?  Too much
conjecture with an unproved system.  The system as described is
not applicable to a 3 shift operation.

Section 4.2.3.3., p. 4-15, par. 1, sentence 2:
     Delete the word "dryer" and replace with "boiler."

Section 4.3.1, p. 4-15, par. 2, sentence 1:
     "Ink emulsification" can be fountain solution in ink or ink
in fountain solution (tinting).  Which is improved?  Please say
so.

Section 4.3.2, p. 4-17:
     Delete entire section.

Section 4.4.1., p. 4-1, par. 1. sentence 2:
     Delete "printplate" and replace with "lithographic plate."

Section 4.4.1, p. 4-18, par. 1, sentence 1:
     Isopropy1. alcohol use in lithographic dampening is not traditional
It was introduced by Dahlgren with the return flow dampening


                                 14

-------
systems designs in the 50s.

Section 4.4.1, p. 4-18, par. 1, last sentence:
     The reference is to a survey conducted in 1986 by NAPL and
the average then was 15 percent and not 17 percent.  The current
average is believed to have dropped since 1986.

Section 4.4.1.1, p. 4-18, par..1, last sentence:
     Your authority should be the printers, not the suppliers.

Section 4.4.1.1, p. 4-18, par. 2, sentence 2:
     A brush and a spray generate new water/air interfaces with
the maximum surface tension, i.e., they act to increase not
decrease the instantaneous surface tension of water solutions.

Section 4.4.2, p. 4-20, par. 1, last two sentences:
     Delete "lower volatility" and replace with "low volatility."

     d-limonene is a carcinogen for male rats.

Section 4.4.2, p. 4-20, par. 2:
     The feasibility of 30 percent VOC cleaning products has not
been demonstrated and cannot be supported for RACT.  Rule 1171
for the South Coast Air Quality Management District has been
finalized and supersedes Rule 1130.  Rule 1171 no longer requires
the 30 percent or less VOC cleaning products.

Section 4.5. p. 4-21, Reference 3:
     Delete v:.e word "Tech" and replace with "Tec."

Section 5.1.1, p. 5-1, par. 1, sentence 2:
     The 40 fold greater ink use rate for web than for sheetfed
cannot be jur^ified.  Some of this difference, as explained
previously, is due to the inclusion of two printing assemblies in
a web printing unit, (preferably called a perfecting couple), but
even a 20 fold difference in ink use rate is excessive.

Section 5.1.1, p. 5-1, par. 1, sentence 4:
     Operating hours for model plants should be scaled from 1500
hours to 3000 hours in medium size plants and to 4500 hours for
the largest plants reflecting the different equipment utilization
and costs.

Section 5.1.2, p. 5-2, par. 1, sentence 1:
     Insert the words "print and" between "...retained by the..."
and "substrate."

Section 5.1.3, p. 5-4, par. 1, sentence 3 and p. 5-5, par 1.,
sentence 2:
     Rather than quoting initial performance statistics for the
emission control techniques, the CTG requires values
representative of continuing performance levels.

Section 5.2.1, p. 5-5, par. 1, sentence 1:
     Delete the words "blanket and" and change the word "print"


                                 15
                               "7
                              : t

-------
to "1ithographic."

Section 5.2.1, p. 5-5, par. 2, last sentence:
     No use of isopropyl alcohol is included in Table 5-2  since all
tabulated VOC emissions are those from the inks.  Is the
reference to Table 5-3?

Section 5.2.2, p. 5-7, par. 1, sentence 2:
     Delete the word "printplat*e" and replace with "lithographic
plate."

Section 5.2.1, p. 5-6, par. 1, sentence 2:
     Statement incorrect since the plate non-image area
continuously carries a water film (evidenced by numerous studies,
previously referenced) and much of the fountain solution is
emulsified in the ink.  Process studies of web printing
referenced elsewhere have estimated the distribution.

Section 5.2.2, p. 5-7, par. 2, sentence 1:
     The estimated average of 75 percent VOC is questioned.  It
seems unusual to have one absolute value given for all
substitutes.  A range of values should be provided.

     Equation (5) should be revised to read "VOC emissions from
alcohol substitute = Weight of alcohol substitute x %VOC in
concentrate/100%"

Section 5.2.6, p. 5-11 and 5-12:
     Suggest deletion on basis of previous comments.

Section 5.2 General:
     Nowhere is the background developed for the use of brush or
spray dampeners, particularly on web equipment to reduce the need
for isopropanol.

Section 5.3.1, p. 5-12, par. 1, sentence 4:
     To state that "the emissions are equal to the amount of
cleaning solution used neglects the following:
     (1)  Blanket cleaning solution partially remains in the
          cloth and goes to recovery of waste.
     (2)  Blanket cleaning solutions on a heatset blanket
          go into the ink and into the dryer for emission to
          a control device.
     (3)  Press cleaning solution residues, i.e., roller
          washes, are put into tanks for recycling or waste
          disposal.
     Provisions need to be made.

Section 5.3.2, p. 5-13, par. 1:
     Cannot justify cleaning compound recommendation based on 0
to 30 weight percent VOC.   Moreover, distinction needs to be made
between the VOC needs for blanket and press cleaning as
previously described for Section 2.5.6, p. 2-10.

Section 6.1.1, p. 6-2,  par. 2, sentence 3:
                                 16

-------
     This section implies that the emission control device costed
for a given model is based on the match between the rated gas
flows of the press dryers (note that these are not unit
determined, but press dependent) and the control equipment design
range.  This leads to a fictional model of many press dryers with
ducts and valving feeding into single control devices, but no
apparent provision for the costing of these multiple controls.

     Explicit development of the models for heatset web offset
facilities are required if the CTG is to be intelligible to its
audiences.

Table 6-1, p. 6-2:
     Operating temperature of 1000°F for a condenser filter is
not correct.  Thermal incinerator temperatures should be 1400 °
F.  Catalytic incinerator temperatures should be 650 ° F.

     Operating temperatures of 1600°F for thermal and 900°F for
catalytic afterburners must be revised to lower, more realistic
values.

Section 6.1.1, p. 6-3, par.  4, last sentence:
     Delete the word "dryer" and replace with "boiler."

Section 6.1.2, p. 6-4, par.  1, sentence 1:
     The term "model plant dryer exhaust streams" is meaningless.
The relation to the model plant press dryer exhaust streams needs
to be defined.  The relationship between numbers of presses and
dryers is thoroughly confused (Table C-l, P. C-2) and does not
correspond to industry practices generally-

Section 6.1.1, p. 6-3, par.  3, sentence 3:
     The length of the ductwork and the cost are going to be
determined principally by the number of press dryers to be
connected to the emission control device.

     No mention is made of costs associated with valving and
automatic controls for adapting to changing flow rates as presses
come on and off stream.

Section 6.1.2, p. 6-5, par.  2, sentence 3:
     Operating and maintenance labor requirements better
approximated at 1 hr. per week for both incineration methods.

Table 6-3, p. 6-8:
     The table represents a number of misconceptions with respect
to the differentials between technologies.  The biggest areas of
concern are maintenance labor costs being lower on condenser
filter units than incineration units, and the cost of catalyst
replacement.  Four years catalyst life should be more
representative than two years.

Section 6.1.4, p. 6-8, par.  1, sentence 4:
     Adapting a press dryer for use of alternative fuels (other
than gas) is expensive and unless a cost is allowed, no credit
                                 17

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should be given.  Alternatively change "dryer" to "boiler."

     Condensed ink VOCs, moreover, may be considered as hazardous
waste in some areas with attended costs.

Section 6-4. p 6-10:
      Remarkable that catalytic costs so closely approximate
thermal on annual basis.  The large magnitudes of changes for
different size plants is suspect.

Section 6.2.1, p. 6-11, par. 2, last sentence:
     It is questioned why changeover costs are recognized for a
24 hour per day schedule, but not for the 16 hour per day model
plant analysis.  Two crew operations are just as susceptible to
costs -as are three crews.

Section 6.2.3, p. 6-15, par. 1:
     Suggest deletion of entire paragraph.

Section 6.2.1, p. 6-12, Table 6-5:
     The savings estimated for heatset web offset printing are
believed to be much too large principally because this industry
segment has been using brush type dampeners to decrease the need
for isopropyl alcohol.

Section 6.3, p. 6-15, par. 1, sentence 1, and Table 6-9:
     Eliminate term "non-toxic."

     No provision is made for increased time required for blanket
cleaning, increased waste (printed paper and cleaning materials)
and increased volume of cleaning solutions.

Table 6-8, p. 6-16:
     Please delete entire table.

Section 6.4.1.2, p. 6-19, par. 4, sentence 2:
     Delete initial part of sentence through "however."

Section 6.4.1.1, p. 6-18, par. 2, sentence 1:
     Not a product of incomplete combustion.

Section 6.4.2.1, p. 6-21, par. 1, sentence 4:
     Wastewater treatment plants may refuse to accept this
waste in which case the printer may have to process the water or
have it disposed by a waste hauler.  Delete the last sentence
because the risk is not negligible.

Section 6.4.1.3., p 6-21, par. 1, sentence 4:
     The qualification of "equal quantities" has not been tested
and seems doubtful.

Section 6.4.2.1, p. 6-21, par. 2, sentence 5:
     The oils (not solvents) can be burned in the dryer only if
expensive modifications are made.  The oils are often acidic and
require extensive filtration prior to them being burned.  Burning


                                 18
                            •j'

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these oils may also introduce treatment, storage, and disposal
issues with respect to state hazardous waste disposal
regulations.

Section 6.4.3., p. 6-22, par. 1:
     Detergents and emulsified inks will be water pollutants.

Section 6.4.4, p. 6-22, par. 1, sentence 3:
     Natural gas is the principal fuel, not supplemental.

Section 6.4.4, p. 6-23, par. 2, last sentence:
     Capital and operating costs for steam generation must be
included.

Section 6.4.5, p. 6-23, par. 1, sentence 2:
     Insert the word "heatset" between "model" and "plants"

Section 6.4.5, p. 6-23, par. 2, sentence 1:
     Recovered oil by condenser controls cannot be used as fuel
for dryers without modification of the dryer burner.

     Suggest more appropriate summary such as:

     Properly designed incineration equipment has remained the
dominant means of VOC control in the heatset printing industry
because of its low maintenance, its overall reliability, its high
level of destruction efficiency, and its overall cost
effectiveness.

     Condenser filters have been used to a limited extent due to
the perceived potential benefit of solvent recovery, lower NOx
emissions, and lower fuel consumption; however, because of high
maintenance, added cost of disposal of unusable waste oil and
water, and urreliable cleanup efficiency this approach has not
gained wide acceptance in the printing industry in states where
compliance testing is required.

Table 6-10, p. 6-20:
     Values for NOx emissions are very high for both incineration
methods.  Values should be checked with EPA publication AP-42.

Section 6.5.1, p. 6-25, sentence 2:
     A relatively unproven emission control method without long-
term performance records is not suitable for RACT.

Section 6.5.2.1, p. 6-25, par 1, sentences 1, 2, and 3:
     Delete "1.6" and "3" percent and replace with "8" and "12",
respectively.

Section 6.5.2.2, p. 6-25, par 1, sentence 1:
     Delete with no more than 24 single blanket units (or 12
double blanket units)—" Delete "6" and replace with "10"
percent.:
                                 19

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     Delete "10" and replace with "15 percent"

Section 6.5.2.2, p. 6-26, par 1:
     Delete paragraph.  No justification for different treatment
of sheetfed pressrooms.

Section 6.5.3, p. 6-29, par. 1:
     Requires independent treatment of blanket and press
cleaners.  Industry required higher VOC content cleaners to
maintain efficiency and control waste.

Section 6.6, p. 6-28, Reference 21:
     Delete "Concerns" and replace with "Conservation"

Section 7.2, p. 7-2, definition of Cleaning Solution:
     Revise to "liquids used to remove ink and debris from the
operating surfaces	"

Section 7.2, p. 7-2, definition of Dampening System:
     Delete the word "press" and replace with "lithographic
plate."

Section 7.2, p. 7-3, definition of Heat-set:
     Delete the word "set" and replace with "evaporate ink oil
from"

Section 7.2, p. 7-4, definition of term lithography:
     Delete the word "impressed" and replace with "recessed."

Section 7.2, p. 7-3, definition of term press:
     Delete words "finished product" and replace with "printed
sheet or web".

Section 7.2, p. 7-2, definition of term fountain solution:
     Delete the phrase "it spreads better across the printing
surfaces" and replace with "it spreads across ink and the plate
surfaces".

Section 7.3, p. 7-3, par. 1, sentence 1:
     The statement that most printing facilities consist of at
least two types of offset lithographic printing is erroneous.  A
more accurate description of facilities would be that most of
them are dedicated to one process only and that some may contain
more than one type of offset printing process.

Section 7.3, p. 7-3, par. 2, sentence 1:
     The possible definition of affected facilities of "one or
more sub-facilities involved in similar offset lithographic
printing processes" is confusing and contradictory and needs to
be revised.

Section 7.3, p. 7-4, par. 2, sentence 3:
     Delete the word "chapter" and replace with "document"-
                                20
                            r~

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Section 7.3, p. 7-4, par. 2, sentence 1:
     The other suggested definition of affected facility of "an
individual printing press with its own individual dryer exhaust
controls (if heatset) or the combination of two or more presses
and the common dryer exhaust, or fountain solution and cleaning
solution delivery systems that they share" is not accurate and
confusing.

Section 7.3, p. 7-4, par. 3, sentence 2:
     Since only offset lithography is subject to this document,
this entire concept is out of context.

Section 7.4, p. 7-4, par. 1, sentence 4:
     Delete the word "equipment" and replace with "material"-

Section 7.4, p. 7-5, par. 2, sentences 2-5:
     In the discussion of control device efficiency, there is no
consideration of the variable flow rates and concentrations of
organics entering the control device, which will affect
reduction efficiencies.  The test method used to measure the
control device efficiency will also affect the calculated
destruction efficiency values.  Delete "20ppmv" and replace with
"50 ppmv-"

     References to the statements should be provided.

Section 7.4, p. 7-5, par. 2, sentence 5:
     A reference to the statement should be provided.

Section 7.4, p. 7-5, par. 4, sentence 1:
     Delete the word "equipment" and replace with "material"-

Section 7.4, p. 7-6, par. 1, sentence 1:
     Delete the word "densities" and replace with "specific
gravities".

Section 7.5, p. 7-6, par. 1, sentence 1:
     The level of business usually does not require a plant to
"be running at full operating conditions and flow rates."  To
insist on this qualification will increase testing costs many
fold and generate large amounts of solid waste.  Prefer "running
at representative conditions and flow rates."

Appendix A, Section A-2,  p. A-4:
     Fourth reference should be "Carman," not "Carmen."

     Corporate should be "TEC" not "Tec."

Appendix B, Section B-1.0, p. B-l:
     The high ink use for web is believed due to the assumption
that web press units have a single printing assembly as opposed
to the two assemblies characteristic of perfecting heatset
presses (blanket-to-blanket).  The result biases the entire
heatset model analyses.
                                21

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         £>, section t>-o.u, part ±, .Last sentence:
     Assumption of "through stagnant, non-diffusing
air"	invalidates application to new solution surfaces moving on
rotating rollers.

     Application to water evaporation rates calculated by the
same approaches might promote acceptability.

Appendix C., p. C-2, Table C-l, last column:
     The 2:1 ratio of press dryers to presses is not typical of
the heatset web offset industry though it is encountered
infrequently.

Appendix C, p. C-3, Table C-2, column 3:
     Why is total exhaust from plant All five times greater than
that from AI when the ratios of press units are 16/6, ink use
340/154 and dryers 4/2?

Appendix C, Section C-2.0, p. C-4, par. 1:
     Heat Value is typically in the range 6 to 13Btu/scf not "1.2
Btu/scf."

Appendix C, Section C-2.IF, p. C-5:
     Temperature should be "1400° F." not "1600 °F."

Appendix C, Section C-2.2B., p. C-9:
     No provision for valuing in duct work involving multiple
presses on single emission control unit.

Appendix C, Section C-3.0, p. C-15:
     Heat value should be 6 Btu/scf, not 1.2 Btu/scf.

Appendix C, Section 3.IK, p. C-15:
     Temperature should be "650°F-" not "900°F."

Appendix C., Section C-3.2.B.I, p. C-21:
     Why should equipment cost for 0 percent heat recovery exceed
that for 35 percent?

Appendix C, Section C-3.3C, p. C-25:
     Should be "precious metal catalyst" not "metal oxide
catalyst."  Base metal catalysts are very rapidly poisoned by
sulfur.

     Replacement materials for 95% destruction efficiency should
be "4 years" not "2 years."  Vendors currently warranty catalysts
for 2-1/2 years even in the presence of normal amounts of
phosphorous and silica poisoning.

Appendix C, Section C-4.2D, p. 3-36:
     Real plants, particularly A-IV counterparts, operate 3
shifts per day and will not have time today as cool the carbon
beds.  The model is inadequate.

Appendix C.,  Section C-5.4, p. C-42, 43:
                                 22

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     Delete entire section.

Section 7.5, p. 7-6, par. 2, sentence 1:
     It is our understanding that this section will be amended to
indicate that Method 25A will be recommended when outlet values
are below 50 ppmv as C-^.  Method 25A should be the recommended
method for add-on control devices and for screening outlets of
incinerators.  The relatively small negative bias experienced
with Method 25A tests of heatset afterburner outlet exhausts
should outweigh the relatively large inconsistencies,
difficulties, and expense of Method 25.

Section 7.5, p. 7-6, par. 3, sentence 3:
     A reference should be provided.

Section 7.6.1, p. 7-7, par. 1, sentence 2:
     Please provide details and reference to modification of
EPA Method 24.  In recommending and specifying a test method
for the determination of founta:1- solution VOC content, EPA
needs to consider the limited technical and financial
resources of the average printer.

Section 7.6.1, p. 7-7, par. 2, sentence 2:
     The concept embodied by th^s statement is misplaced.  Title
III of the Clean Air Act Amendments of 1990 does not ban the
use of any listed hazardous air pollutant.  Eventually, Title III
will require certain source categories to control the emissions
of hazardous air pollutants through MACT.

Section 7.6.3, p. 7-8, par. 1, sentence 1:
     See comments outlined at 7.6.1, p, 7-7, par. 2, sentence 2.

Section 7.7.1, p. 7-8, par. 2, sentence 3:
     Please provide a reference for this statement.

Section 7.7.1, p.7-8, par. 2, sentence 4:
     Please provide a basis for drawing the conclusion that
temperature monitors with strip charts are "relatively
inexpensive."  Were all of the capital, installation, operation,
maintenance, and personnel costs incorporated into the economic
models used to determine cost/ton reduction ratio?

It is questioned if monitoring temperature rise across a
catalytic bed provides meaningful data, especially since inlet
flows and organic concentration will vary creating variations in
temperature rises across the bed.

Section 7.7.1, p. 7-8, par. 3, sentence 3:
     Efficient operation of the heatset dryer demands that the
pressure within the unit be lower than the pressure in the
pressroom.

     Please define test methods used to qualitatively measure air
flow direction.  Please specify frequency of monitoring.  Were
the capital, operation and maintenance costs including personnel
                                 23

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associated with this testing and monitoring considered in the
economic models for determining cost/ton reduction ratio?

Section 7.7.2, p. 7-9, par. 2, sentence 1 :
     Conductivity at best can only provide an indication of
fountain solution concentration.  Because of daily and even
hourly fluctuations in conductivity of incoming tap water, which
is the most common source of printers water (i.e.
untreated), introduction of contaminants into the fountain
solution, and at times the need to add additional fountain
concentrate during the course of a print run,  using
conductivity as a measure of concentration is limited.

     The use of hydrometers and record-keeping are omitted.
These'are valuable sources of continuing information with minimal
associated costs.

Section 7.7.3, p. 7-9, par. 3:
     See comments outlined above for Section 7.7.2, p. 7-9,

Section 7.7.4, p. 7-9, par. 1, sentence 1:
     The industry questions the relative merits of requiring
continuous temperature monitoring at the fountain tray.  With the
multitude of variables the printer must monitor and control,
the fountain solution temperature measurements should be limited
in number.  A once per shift thermometer measurement of the
recirculator should be sufficient.

     Were the capital, operation, and maintenance costs of the
measuring and monitoring equipment including considerations
of personnel included in the economic models used to
determine the cost/ton reduction ratio?

Section 7.7.5, p. 7-10, par. 1, sentence 3;
     Please describe the term "continuous cleaning operations"
as applied to the offset lithographic industry-

     Only the largest printers will possess a refractometer and
be able to use it efficiency.  Conductivity meters for the
proposed use is questionable and would have to be standardized by
the supplier, not the printer.  The manufacturers' cleaner
specifications of VOC content should be taken at face value for
record keeping purposes.

     Recordkeeping frequency of cleaning solution use should be
very limited in small plant operations, i.e. once a week.  Only
large plants need recordkeeping to be made on a more frequent
basis.

     Differentiating between blanket and press cleaners and their
VOC contents is expected to require separate records.
                                24

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                         COMMENTS
               APPENDIX  C COST CALCULATIONS
                        DRAFT CTG
                  WEB  OFFSET LITHOGRAPHY
GENERAL COMMENTS;

1.   The two shift operating scenario for the model plants does
     not represent this industry's method of operation and
     especially  it should not be assumed so that the third shift
     would be available to such operations as carbon regeneration
     and maintenance.  These functions must be accounted for
     during the operating day-  The proper scenario would be
     three shifts and seven day operation.

2.   For all of the model plants, the hours of operation of the
     control device should exceed the individual press operating
     hours as not all of the presses will run simultaneously,
     i.e., a distribution of zero to eight dryers running.  In
     addition, some control devices will have startup times
     reguired and standby times reguired due to the length of
     time reguired to reach operating conditions.

3.   The carbon bed considered for polishing treatment of the
     cooler-filter system cannot be regenerated by hot air or by
     low pressure steam.  Hot air cannot be used as air pollution
     would only be regenerated.  Additionally, air temperatures
     of 550°F or higher would cause ignition of the carbon bed.
     Low pressure steam, typically 125 psig, could raise the
     carbon bed temperature to only 350 F and would not desorb
     VOC's deposited from a 390°F dryer exhaust.  LA Litho, who
     operated a carbon adsorption system, found that 600°F and
     vacuum conditions in an inert environment were reguired to
     desorb.  A functional regeneration system will add
     considerable capital cost and the regeneration step will
     reguire over a shift of time to conduct.

     Systems such as described above should not be included in
     the RACT documentation since they do not exist nor has it
     been demonstrated they will function over an extended period
     of time.

4.   No provisions have been made in the capital costs of any of
     the add-on controls for the safety purging of the gas-fired
     dryer burners prior to introduction into the control system.
     This would consist as a minimum of a damper system to vent
     the purging air to atmosphere and an actuator to redirect
     the damper(s) at the end of the purging cycle.  Such a
     damper system will cost $15,000 per damper system (at least
     one reguired per press) to insure inherent fail safety.

5.   No provisions have been made in the operating costs of the
     cooler-filter systems for cleaning of the heat exchanger(s)
     and the cleaning, replacement and disposal of the filter
     media involved.

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Page Two

6.   No provisions were made to correct the value of the
     recovered solvent for the additional costs involved to
     modify the dryer burner systems, to store the recovered
     solvent and to operate and maintain these additional
     systems.

SPECIFIC COMMENTS;

Page C-l.  The 0.033 factor should be identified as related to
           the amount of ink solvent applied per unit area
           instead of being dimensionless.  The amount of ink
           applied varies with each customer's requirements and
           is simplified in this equation only by assuming an
           artificial average value for the model.

Page C-2.  The annual ink usage rate appears reasonable for 3000
           operating hours.  However, the web speed is
           inconsistent.  That usage would indicate "type only"
           printing, i.e., paperback books. It is probable that
           reduced speeds should be indicated.

Page C-3.  The Model plant A-I should all have 4,000 scfm Total
           exhaust (Typographical error).

           Page 6-4 indicates the dryer exhaust should contain
           600-800 ppmv of VOC versus the 179-405 ppm listed in
           the table.  Which is correct?  Using the values
           assumed, the VOC for A-III appears to be 135 ppm.

Page C-4.  The molecular weight of the heatset ink solvent is
           too low.  Magiesol 47, a typical solvent, has a
           molecular weight of 195-205.  Any solvent with a lower
           molecular weight will have a higher vapor pressure
           and will not condense to the same degree, rendering
           the cooler-filter systems less effective.

           The oxygen content of the dryer exhaust is usually
           reduced to 18-19% by partial oxidation of the VOC
           material, combustion requirements of the dryer burner
           or due to the production of water vapor and carbon
           dioxide.  The typical analysis is 19% oxygen, 2% water
           vapor, 0.5% carbon dioxide and 78.5% nitrogen.

           In para C-2.1 B. 2., back calculations show that a
           definition of standard conditions of 77°F and 29.92
           in. of Hg was used.  The definition of standard
           conditions in the fan industry is 70°F and 29.92 in.
           of Hg.  Accordingly, the amount of scf in a Ib-mole is
           386.73 scf/lb-mole.

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Page Three

Page C-5.  In para C-2.1 E., the turndown ratio of 20,000 to 50
           is not realistic (400:1).  Flow turndown ratios due to
           varying fan speed are usually 4:1 with an upper limit
           of 6:1.  This can be multiplied with dampers by
           another 4:1 factor.

           In para C-2.1 F., the 1600°F incineration
           temperature is excessive for heatset ink solvents.
           1200-1250°F will destroy the solvents while about
           1400°F is required to destroy the carbon monoxide
           produced.

Page C-6.  In para H., for clarity the division sign used to
           indicate the denominator should be changed to a /.

Page C-8.  In para J.  1., additional air may be required
           during high fire by the dryer burner(s), i.e.,
           startup and speed or temperature changes, if the
           exhaust air oxygen content drops below 16%.  Note:
           the air discharged from the thermal afterburner will
           contain 12.1% oxygen, 8.2% water vapor,  3.7% carbon
           dioxide and 76.0% nitrogen.

           In para C-2.2 A., the equipment cost algorithms do not
           consider the complex arrangement requiring the safety
           purging of the dryers.  The capital cost figures
           appear to be about 25% too low.

Page C-9.  In para C-2.2 C. , the auxiliary collection fan cost
           does not reflect the increased pressure drop
           requirements caused by the heat recovery equipment.
           The pressure drop is a function of the capital cost
           of the heat recovery equipment, thus the algorithm
           must be examined.  Higher percentage heat recovery
           is associated with higher pressure drops and fan
           costs.

Page C-ll. In para C-2.3 A. 1., the amount of operating labor
           required is too high.  A more appropriate level is
           0.1 hour per shift.  The only work to be performed is
           a review of operating temperatures and an overview of
           the condition of the equipment.

           In para C-2.3 B. , the amount of maintenance labor
           required is too high.  A more appropriate level is
           0.1 hour per shift.  There is only one moving part,
           the auxiliary collection fan, and the burner to
           maintain.  The materials should be projected as five
           times the maintenance labor as a number of spares
           should be on hand.

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Page Four

Page C-15.  Similar comments  as on page C-4.   The molecular weight
           of the heatset  ink solvent is too low.  Magiesol 47, a
           typical solvent,  has a molecular weight of 195-205.
           Any solvent  with  a lower molecular weight will have a
           higher vapor pressure and will not condense to the
           same degree,  rendering the cooler-filter systems
           less effective.

           The oxygen content of the dryer exhaust is usually
           reduced to 18-19% by partial oxidation of the VOC
           material, combustion requirements of the dryer burner
           or due to the production of water vapor and carbon
           dioxide.  The typical analysis is 19% oxygen, 2% water
           vapor, 0.5%  carbon dioxide and 78.5% nitrogen.

Page C-22.  Similar comments  as on page C-9.   In para C-3.2 D. ,
           the auxiliary collection fan cost does not reflect the
           increased pressure drop requirements caused by the
           heat recovery equipment.   The pressure drop is a
           function of  the capital cost of the heat recovery
           equipment, thus the algorithm must be examined.
           Higher percentage heat recovery is associated with
           higher pressure drops and fan costs.

Page C-24.  In para C-3.3. A.  1.,  the amount of operating labor
           required is  too high.   A more appropriate level is 0.1
           hour per shift.   The only work to be performed is a
           review of operating temperatures  and surveillance to
           identify any visual malfunctions.

Page C-32.  In para C-4.1 B.,  the cost of the carbon adsorption
           unit is too  low.   This is the only unit that is
           sized based  on the VOC content.  All other units are
           sized considering the air flow through the systems.
           Accordingly,  the  sizing must reflect the maximum VOC
           input, not the average.   If cooling is inadequate or
           filter effectiveness is low,  the  carbon may see up to
           the full concentration of VOC.   For these reasons
           alone, at least two vessels of the size projected
           should be used.   Also,  since low pressure steam will
           not desorb the VOC from the carbon and hot air cannot
           be used, the system must be more  complex.   The only
           system that  has been demonstrated to operate over an
           extended period is the LA Litho method of desorption.
           This system  consisted of electric heaters within the
           carbon bed,  an  inert gas system to prevent ignition
           of the carbon and a vacuum pump and condenser system.
           The increased sophistication of the desorption system
           will increase the capital cost about 50% per vessel.
           The new ECacj will be:

                ECad  = 2   *   1.50  *  68,000

                        =  $204,000

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Page Five

Page C-34. In para C-4.2 A., the amount of operating labor
           required is too low.  In addition to reviewing
           operating temperatures and pressures, cleaning
           operations must be done as well as replace and
           dispose of used filter media.  Since these actions
           must be done with the system offline, a more
           appropriate level is 1.0 hour per shift.  For those
           systems with carbon adsorbers, a level of 10.0 hours
           per regeneration is required.  On the average, one
           regeneration 'of the carbon is required each day.
           Thus the operating labor for regeneration would be
           5.0 hours per shift.

Page C-35. In para C-4.2 B. 1., the amount of maintenance labor
           required is too low.  The system consists of two
           auxiliary collection fans, two to four cooling air
           fans and at least two filter media belts.  A more
           appropriate level is 1.5 hours per shift.

           In para C-4.2 B. 2., the amount of materials should be
           increased appropriately.

           No mention is made of the requirement for cleaning the
           heat exchangers.  For model plant A-III, each cooler-
           filter will require six cleanings per year.  Assume
           cleaning requires sixteen manhours of labor, $1500 of
           cleaning materials and $2000 to dispose of the
           contaminated cleaning solution.  Heat exchanger
           cleaning would cost:

           Labor =  2 * 6 * 16 * 17.21  =  $3,304

           Materials =  2*6* 1500    =  $18,000

           Disposal  =  2 * 6 * 2000    =  $24,000

           Total Annual Heat Exchanger cleaning  = $45,304

           No mention is made of the requirement for either
           replacing the filter media in the traveling bed filter
           or the cleaning and replacement of the candle filters.
           Using a 2 year filter life for the candle filters and
           a candle filter cost of $1000 per candle, the
           replacement cost would be:

           Filters   =  (20,000/500) * 1000  =  $40,000

           Replacement
           Labor          =  32 manhours * 17.21  =  $551

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Page Six

           Annual Filter Replacement Costs

             (Materials & Labor)   =  (40,000 + 551)  *  CRF

                                  =  $40,551  * 0.500

                                  =  $20,276/yr

           In para C-4.2 B.  3.,  the assumed carbon life of five
           years appears too long.   LA Litho found that about
           5% of the carbon bed became unusable each regeneration
           due to contamination by high molecular weight material
           that would not desorb under the temperature and vacuum
           conditions available.   Using $25,647 cost per
           replacement and a yearly average of one regeneration
           per day,  an appropriate annual  carbon replacement cost
           is:

           Annual Carbon Replacement Costs

              (Materials & Labor)   =  25,647 * 5 * 52 * 0.05

                                   =  $333,411

Page C-36. In para C-4.2 D. , the assumption that additional
           electricity costs are negligible is incorrect.  Carbon
           bed pressure drops are expected to be 1.67 in. w.c.
           per foot of thickness.   Using a bulk carbon density  of
           27 Ib/cf and the 11,605 Ib of carbon, 430 cf of carbon
           will be used.  It is likely that a 3 foot carbon bed
           will be used to keep the tank cross-sectional area to
           about 143 sq.ft.  or 13.5 ft. in diameter.  This will
           produce about a 5 in.  w.c.  pressure drop at the
           beginning of the carbon bed life, increasing to up to
           12 in. w.c. as the proportion of fines increase.
           Additionally, the "extra" capacity of the system fans
           is used to extend the times between cleaning or
           replacement of the filter media.  Use of this capacity
           to produce carbon bed flow will greatly increase the
           cleaning or replacement frequency.

           In para C-4.2 E., the carbon bed cannot be regenerated
           by low pressure steam.   Obviously, the daily
           replacement of carbon at $25,647 per replacement is
           unacceptable.  LA Litho has used electrical heating
           under inert atmosphere,  followed by vacuum pumping and
           condensation of vapors.   A vacuum of 1 Torr was
           required.  Electricity will be  required for the heater
           elements and the vacuum pump.  The electricity
           required for each regeneration  is:

           Electricity  =  11.605 * 0.24 *  (600-100) * 1.1
           for heating                 3413

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Page Seven

                        =  449  KWH

           Electricity  =  5 hours at 25 KW
           for pumping

                        =  125  KWH

           Total Electrical use = 449  + 125  =  574  KWH

           Assuming inert gas costs of $100 per regeneration and
           cooling water costs to condense the VOC of $200 per
           regeneration•,  the desorption costs are:

           Regeneration Costs  =  5 * 52 *((0.061)(574)+ 300)

                               =  $87,104

           In addition,  there was no provision for capital costs
           of a condensing and separating system for the
           steaming.   The water condensate will be contaminated
           with the water-soluble VOC from the fountain solution
           and must be treated before reusing as boiler feedwater
           or discharged.

Page C-38. In para C-4.2 M. , the recovery credits are the net of
           value of the solvent recovered minus the costs of
           handling the solvent.  Two dispositions are likely for
           the recovered solvent - sale or burning as alternate
           dryer fuel.  The price available for recovered solvent
           is about $0.25/gal.  The value as an alternate fuel in
           dryers appears to be about $0.63/gal but some
           additional expenditures are required which reduce the
           value of both dispositions.

           A storage tank farm will be required to accumulate the
           recovered solvent.  The recovery rate is approximately
           10 gal/day which will not satisfy the burner fuel
           requirements.   Burner fuel storage capacity should be
           at least 1000 gal and storage for eventual sale would
           probably be about 7000 gal for economy in shipment.
           The tank farm will require minimal operating labor,
           consisting mainly of monitoring tank levels and pumps
           during transfers.

           Use of recovered solvent as an alternate burner fuel
           will require the modification of existing dryers to
           dual-fuel systems.  This involves the addition of a
           liquid fuel feeding system,  a new dual fuel burner and
           modifications to the dryer combustion chamber to
           handle the longer flame length of the liquid fuel.

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Page Eight
           Modification costs are over $20,000 per dryer
           burner.   The sequence of operation of a dual fuel
           burner is to start up on gaseous  fuel,  switch over to
           liquid fuel  and,  on controlled  shutdowns,  switch back
           to gaseous fuel.

           The use of a liquid fuel involves much more
           maintenance  labor and materials on the dual fuel
           burner.   The systems operated to  date have experienced
           some of the  following problems:   sooting due to poor
           atomization  of the liquid fuel  because of  dirty
           nozzles to the extent the white paper web  became gray,
           failure of the fuel pump due to fine solids content in
           recovered solvent that eroded the metal  surfaces,  and
           corrosion due to  the high acidity of the recovered
           solvent from the  presence of partially oxidized
           material.  Since failures in the dryer burner results
           in lost productive time,  the lack of reliability has
           resulted in  an almost total absence of  liquid fueled
           dryers in the industry.

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                   Environmental Conservation Board
                   of the Graphic Communications Industries
n Intra-lndustry Organization for Environmental Affairs
      1899 Preston White Drive
        Reston, VA 22091-4326
703/648-3218 • FAX 703/648-3219
                                Environmental Conservation Board

                                             of the

                                Graphic Communications Industries

                                         Amendments to

                                         APPENDIX D

                                   Offset Lithographic Printing

                                        CTG Model Rule
      The following text of Appendix D, the CTG Model Rule for Offset Lithographic Printing has been
      amended to reflect the suggested changes of the Environmental Conservation Board of the Graphic
      Communications Industries (ECB). Intcrliniatcd language in the text is language that is presently
      included in the Model Rule that ECB recommends be omitted. Language in ALL CAPITALS
      LETTERS AND BOLD FACE is language that ECB recommends be added to the original text.
      A second copy of Appendix  D follows which deletes the interliniated language, with only the
      Model Rule as recommended by ECB remaining.
                                   printed on recycled paper with vegetable oil ink

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                               APPENDIX D







                   OFFSET LITHOGRAPHIC PRINTING



                           CTG MODEL RULE







D.I  INTRODUCTION







   This appendix presents a model rule to limit volatile organic compound (VOC)



emissions from offset lithographic printing operations. This rule is for informational



purposes only and, as such, is not binding on the air quality management authority.



However, EPA expects that State and local air quality rules developed pursuant to



this CTG will  address all the elements covered in the model rule.







   The remainder of this appendix contains the model rule. Separate sections cover



the following  rule elements:    applicability,  definitions,  emissions  standards,



equipment  standards,  emissions  standards  testing,  equipment  standards testing,



monitoring requirements, and reporting/recordkeeping.







D.2  APPLICABILITY







   The  provisions set  forth  in this model  rule apply to the offset lithographic



printing industry only.  There are four types  of offset lithographic printing:  heatset






                                    D-l

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web, non-heatset web (non-newspaper), non-heatset sheet-fed, and newspaper (non-

heatset web).  An affected facility may be defined as follows: one or more printing

operations involved in at least one type of offset lithographic printing process.



   Other types  of printing operations, such as flexography,  rotogravure,  or

letterpress, may be present hi an offset lithographic printing facility; however these

operations are not subject to the requirements set forth hi this model rule.



   Any dryer exhaust stream for which an existing control device is employed to

control VOC emissions should not be required to meet the 95 percent reduction or

20 ppmv emissions limit specified in the model "THE PERCENT REDUCTION

OR EMISSIONS LIMITS SPECIFIED IN SECTION D.4(A) OF THE MODEL"

rule  until  the control device is replaced for other reasons.   In  other words,  no

facility should be required to upgrade or replace a control device that is in place

before the date  of this regulation, provided that the  device is at least 85 percent

efficient in the "MEETS THE APPLICABLE STATE RACT REQUIREMENTS

FOR THE" destruction  "OR  RECOVERY"  of VOC's  and  is operated  and

maintained in accordance with the procedures described hi Sections D.6, D.8, and

D.9.
                                   D-2
                                i-; ^ r?
                                 • Vj i

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D.3 DEFINITIONS







  Alcohol substitutes.  Non-"ISOPROPYL" alcohol additives that contain VOC's



and are used in the fountain solution. Some additives are used to reduce the surface



tension of water; others (especially in the newspaper industry) are added to prevent



piling (ink build-up).







   Cleaning solution.  A liquid "LIQUID SOLVENTS" used to remove ink and



debris from the surfaces of the printing press and its parts.







  Dampening System.   Equipment used to deliver the fountain solution to the



press  "LITHOGRAPHIC PLATE".







   Fountain Solution.  A mixture of "PRIMARILY" water, non-volatile printing



chemicals,  and  an (liquid)  additive  that  "OTHER  CHEMICALS,  AND



ADDITIVES THAT REDUCE THE SURFACE TENSION" reduces the surface



tension of the water so that it spreads easily  across the printing surfaces.   The



fountain solution wets the non-image areas so that the ink is maintained within the



image areas.  Isopropyl alcohol, a VOC, is  the most common additive  "OR



ALCOHOL SUBSTITUTES  ARE COMMONLY used  to reduce the surface



tension of the  fountain solution.
                                  D-3

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  Heat-set.  Any operation "A WEB PRINTING OPERATION" where heat is
required  to  set  "TO  EVAPORATE"  the printing ink "OILS".   Hot air
"HEATSET" dryers are used to deliver the heat.

  HEATSET DRYER "A DEVICE TO HEAT THE PRINTED SUBSTRATE
AND TO PROMOTE EVAPORATION OF INK OILS".

  Lithography.  A planar "PRINTING" process where the image and non-image
areas are chemically  differentiated;  the image area is oil receptive and the non-
image area is water receptive.  This method differs from other printing methods,
where the image is a raised or impressed "IMAGES ARE PRINTED FORM
RAISED OR RECESSED" surface.

  Non-Heatset.  Any operation "A  LITHOGRAPHIC OPERATION" where the
printing inks are set without the use heat. For the purposes of this rule, ultraviolet-
cured "AND ELECTRON BEAM-CURED" inks are considered non-heatset.

  Offset.  A printing process that transfers the printing image "INK FILM FROM
THE LITHOGRAPHIC  PLATE" to an intermediary surface "(BLANKET)",
which, in turn transfers the image "INK FILM" to the printing substrate.
                                D-4

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  Press.  A printing production assembly that can be made up of one or many



"COMPOSED  OF  ONE  OR MORE" units to produce a fmiohcd product



"PRINTED SUBSTRATE".







  RECIRCULATION RESERVOIR.   THE  COLLECTION TANK WHICH



ACCEPTS FOUNTAIN SOLUTION RECIRCULATED FROM PRINTING



UNIT(S).  THE TANK COMMONLY CONTAINS A COARSE FILTER TO



REMOVE CONTAMINANTS FORM THE FOUNTAIN SOLUTION AS WELL



AS THE COOLING COILS FOR REFRIGERATION.







  Sheet-fed.   Any  "A PRINTING"  operation  where paper "INDIVIDUAL



SHEETS  OF SUBSTRATE ARE" is fed to the press in individual sheets



"SEQUENTIALLY".







  Unit. The smallest complete "PRINTING" component of a printing press. Each



unit can print only one color.



  Web. A continuous roll of paper used as the printing substrate.







D.4 EMISSION STANDARDS








  (a)  Any person who owns or operates a heatset offset lithographic printing press



shall reduce VOC emissions from the press dryer exhaust vent by 95 "90" weight-
                              D-5

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 percent of total organics (minus "LESS" methane and ethane) or maintain a



maximum dryer  exhaust "A CONTROL  DEVICE" outlet concentration of 20



ppmv, "LESS THAN 50 PPMV AS C, " whichever is less stringent.







D.5 EQUIPMENT STANDARDS "PROCESS STANDARDS"







   (a)  Any person who owns or operates a web-fed offset lithographic printing



press  that uses  "ISOPROPYL"  alcohol  in the  fountain  solution  shall reduce



 "MAINTAIN" total fountain solution VOC's to 1.6 percent "AT 8 PERCENT" or



 less (by volume). Alternatively, a standard of 3 "12" percent or less (by volume)



 VOC may be used if the fountain  solution containing alcohol is refrigerated to less



 than 60°F.







   (b)  Any person who owns or operates a sheet-fed offset lithographic printing



 facility with a combined total of no more than 24 printing units (single blanket) that



 use alcohol in the fountain solution shall reduce VOC's  to 6 percent or less  (by



 volume) VOC.  "PRESS THAT  USES ISOPROPYL ALCOHOL IN  THE



 FOUNTAIN  SOLUTION   SHALL   MAINTAIN   TOTAL  FOUNTAIN



 SOLUTION VOCS AT 10 PERCENT OR LESS (BY WEIGHT).  Alternatively,



 a standard of 40 "15" percent or less (by volume) VOC may be used if the fountain



 solution containing alcohol is refrigerated to below 60 °F.
                                 D-6

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   (e) — Any person who owns or operates a sheet fed offset lithographic printing



facility with a combined total of 24 printing units (single blanket) or more that use



alcohol  in  the fountain solution  shall reduce VOC's to 3 percent or leas  (by



volume). — Alternatively,  a standard of 5 percent or less containing  alcohol is



refrigerated to below 60--Fr







   {d)"(c)"   Any person  who owns or operates any type of offset lithographic



printing press shall be  considered in compliance with this regulation if the only



VOC's in the fountain  solution are in non-"ISOPROPYL" alcohol additives or



alcohol substitutes, so that the concentration of VOC's in the fountain solution is 2r5



"5" percent or less  (by weight).   (The fountain solution should not contain  any



alcohol.)







   (e}"(d)"  Any person who owns or operates an offset lithographic printing press



shall reduce VOC emissions from cleaning solutions by using cleaning solutions with



a 30 percent or less (as used) VOC content.  "OR A VOC  CONTENT OF  900



GRAMS OR LESS OF VOC PER LITER OF MATERIAL AND A VOC



COMPOSITE PARTIAL PRESSURE OF 25 MM HG  OR LESS AT 2/C  (68
D..6  EMISSIONS STANDARDS TESTING
                                   D-7

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  (a)  For the purpose of demonstrating compliance with the emission control
requirements of this rule, the affected facility "SOURCE" shall be run at fett "THE
MAXIMUM PRACTICAL" operating conditions and flow rates "COMPATIBLE
WITH SCHEDULED PRODUCTION DURING COMPLIANCE TESTING"
during any emission

(b)  Emission tests  shall include an initial test when the control device is installed
that demonstrates compliance with cither the 95 weight-percent reduction or the 20
ppmv emission limit.   "EMISSION  TESTS  FOR SOURCES  INSTALLED
AFTER THE EFFECTIVE DATE OF THIS REGULATION SHALL INCLUDE
AN INITIAL TEST WHEN THE CONTROL DEVICE IS INSTALLED THAT
DEMONSTRATES COMPLIANCE  WITH  EITHER  THE 90  WEIGHT-
PERCENT REDUCTION  OR THE 50 PPMV AS C, EMISSIONS LIMITS
SPECIFIED IN D.4(A)".

   (c)  The following EPA methods (in 40 CFR 60, Appendix A) shall be used to
demonstrate compliance with the emission limit or percent reduction efficiency
requirements listed in D.4  (a) above.   "ALTERNATE METHODS MAY BE
USED WITH THE APPROVAL OF THE ADMINISTRATOR".

   (1)  EPA Method 1 or 1A, as appropriate, shaH "MAY" be used for selection
of the sampling sites.   The control device inlet  sampling site for determining
                               D-8

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efficiency in reducing total organics (less  methane  and  ethane) from the dryer



exhaust shall be placed before the control device inlet and after the dryer.







   (2)  EPA Method 2, 2A, 2C, or 2D, as appropriate, sfeaH "MAY" be used to



determine the volumetric flow rate of the exhaust stream.







   (3) EPA Method 25 or 25A shall be used for determining emissions from hcatsct



dryer exhaust.  "EPA METHOD 18, 25, OR 25A, AS APPROPRIATE, MAY



BE USED TO DETERMINE EMISSIONS FROM HEATSET DRYER AND



CONTROL DEVICE EXHAUSTS". Good judgement is required in determining



the best applicable VOC test method for each situation.







   (i) Since EPA Method 25 has a minimum detectable concentration of 50 ppm



carbon, and given the low concentration of VOC's sometimes present hi dryer



exhaust from offset lithographic presses and the high removal efficiency achievable



with add-on controls, EPA Method 25 A may be more suitable than EPA Method 25



for determining compliance.with a  95 weight percent reduction standard hi some



situations "TO A TEMPERATURE ABOVE THAT OF THE GAS STREAM,



E^J., 350°F".  Note that EPA Method 25 specifies a minimum probe and filter



temperature of 265°F.  To prevent  condensation, the probe and filter should be



heated  to  fee — gas — stream — temperature, — typically — closer — te — 350-F  "A
TEMPERATURE ABOUT THAT OF THE GAS STREAM.JSOV.
                                                     n
                                 D-9

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  (ii) EPA Method 25A utilizes a flame ionization detector (FID), which had the
ability to measure low concentrations. This technique usually is not recommended
for incinerators because incomplete combustion may result in the formation of
aldehydes, kctoncs, and partially oxidized organic species that interfere with the
accuracy of FID measurement.   "INCINERATOR OUTLETS WITH VOC
CONCENTRATIONS IN EXCESS OF 50 PPM AS  C,.  HOWEVER, EPA
METHOD 25A IS PREFERRED FOR INCINERATORS WHERE EXPECTED
OUTLET CONCENTRATIONS  WILL BE BELOW  50  PPM AS  C,  OR
WHERE DRYERS FROM MULTIPLE PRESS LINES DISCHARGE INTO A
CENTRAL CONTROL DEVICE".

D.7  EQUIPMENT STANDARDS TESTING

   (a) Fountain Solution Testing

   (1) A "COMPOSITE" sample of the fountain solution (as used) shall be taken
from the from the fountain tray or  reservoir of fountain  solution (after mixing) of
each until to determine "EACH SUBJECT PRESS TO DETERMINE"  fountain
solution VOC content in accordance with section D.5 (a) through (d) above.

   (2)  A modification of EPA Method 24 (under development) shall be used to
determine the VOC content of the fountain solution samplc(s). "RECORDS OF
                               D-10

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FOUNTAIN SOLUTION COMPOSITION (AS MIXED) MAY BE USED TO



DETERMINE THE VOC CONTENT OF THE FOUNTAIN SOLUTION".








  (b)  Refrigeration Equipment Testing







  (1)  A thermometer or other temperature detection device capable of reading to



0.5°F shall be used to ensure that a refrigerated fountain solution containing alcohol



is below 60°F at all times.







  (c)  Cleaning Solution Testing







  (1)  A sample "SAMPLES" of the cleaning solution "SOLUTIONS" (as used)



shall be taken to demonstrate compliance with  the cleaning solution VOC content



"OR VAPOR PRESSURE imitations listed in  D.5 (e) "(d)" above.







  (2)  A modification of EPA Method 24 (under development) shall be used to



determine the VOC contnct of the cleaning solution (as used).  "RECORDS OF



CLEANING SOLUTION COMPOSITION (AS MIXED) TOGETHER WITH



MATERIAL SAFETY DATA SHEET INFORMATION MAY BE USED TO



DETERMINE  THE  VOC CONTENT OF  THE CLEANING  SOLUTION.



ALTERNATIVELY,  VOC   CONTENT  OR  VAPOR  PRESSURE AS



PROVIDED   BY  THE   MANUFACTURER   MAY  BE  USED  TO
                              D-ll

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DEMONSTRATE COMPLIANCE WITH THE REQUIREMENTS OF D.5
CD)".

D.8 MONITORING REQUIREMENTS

   (a)  Add-on Dryer Exhaust Control Devices

   (1)   The owner or operator of a heatset offset lithographic printing press
"EQUIPPED WITH AN AFTERBURNER" shall install, calibrate, maintain, and
operate a temperature—monitoring—device,  according  to  the  manufacturer's
instructions, "CONTINUOUS TEMPERATURE MONITORING EQUIPMENT
TO MONITOR THE  COMBUSTION  CHAMBER  TEMPERATURE OF
THERMAL AFTERBURNERS OR THE TEMPERATURE RISE ACROSS A
CATALYTIC AFTERBURNER BED. THE COMBUSTION CHAMBER OR
CATALYST INLET TEMPERATURE SHOULD BE SET DURING TESTING
REQUIRED TO DEMONSTRATE COMPLIANCE WITH THE EMISSION
STANDARDS OF D.4 (A)", at the outlet of the control device.  The monitoring
temperature should be set during testing required to  demonstrate compliance with
the emission standard (Section 7.6.3).

   (2)  The temperature monitoring device shall be equipped with a continuous
recorder and shall have an accuracy of Or§!F "5°F".

                              D-12

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   (3)  The dryer pressure shall be maintained lower than the press room air



pressure such that air flows into the dryer at all times.  A 100 percent emissions



capture efficiency for the dryer shall be demonstrated using an air flow direction



measuring device. "THE CAPTURE EFFICIENCY FOR THE DRYER SHALL



BE DEMONSTRATED USING AN AIR FLOW DIRECTION INDICATING



DEVICE".







   (b)  Fountain Solution VOC Concentration







   (1)  The purpose  of monitoring the VOC concentration in the fountain is to



provide data that can be correlated to the mount of material used when the fountain



solution is in compliance with the limits in D.5(a) through (d) above. The following



methods may be used to measure  the concentration of VOC'3 in the fountain



solution of a  frequent basis.    "RECORDS  OF  FOUNTAIN SOLUTION



COMPOSITION (AS MIXED) MAY BE USED TO DETERMINE THE VOC



CONTENT OF THE FOUNTAIN SOLUTION; OR".







   (2) The owner or operator of any offset lithographic printing press shaH "MAY"



monitor fountain solution VOC concentration "AT LEAST ONCE PER BATCH"



with a refractometer that is corrected for temperature, at least once per 8 hour shift.



The refractometer shall have an optical "A VISUAL, ANALOG" or digital readout






                                D-13

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with  an accuracy  of  0.5 percent VOC.  A standard  solution  shall  be used to
calibrate the refractometer for the type of VOC used in the fountain. "SOLUTION;
OR"

   (3) Alternatively, The owner or operator of any offset lithographic printing press
may monitor fountain  solution VOC concentration with a hydrometer equipped with
a temperature correction at least once per 8-hour  shift "AT LEAST ONCE PER
BATCH  WITH  A  HYDROMETER   THAT  IS  CORRECTED  FOR
TEMPERATURE".  The  hydrometer  shall have  an  optical  "A  VISUAL,
ANALOG" or digital readout with  an accuracy of 0.5 percent VOC.

   (4)   The VOC content  of  the fountain  solution may  be monitored  with  Q
conductivity  meter if it is determined that a refractometer or hydrometer cannot be
used for the type of VOC's in the fountain solution.  The conductivity meter reading
for the fountain solution shall  be referenced to the conductivity of the  incoming
n rrk^-/-i*»
WULU1 .

   (c)  Fountain Solution Temperature


   (1)  The owner or operator  of any offset  lithographic printing press using
refrigeration equipment  en "FOR"  the fountain  "SOLUTION" shall  install,
maintain, and continuously operate a  "TO COMPLY WITH SECTION D.5 (a)
                                  D-14

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OR (b) "SHALL MONITOR THE" temperature pfebe in the fountain solution
reservoir below the solution surface.

   (2)  The temperature probe shall be attached to a continuous recording device
such as a strip chart, recorder, or computer.    "THE FOUNTAIN SOLUTION
TEMPERATURE SHALL BE RECORDED AT LEAST ONCE PER 8-HOUR
SHIFT".

   (d)  Cleaning Solution

   (1)  For any offset lithographic printing press with continuous cleaning
equipment, flow "COMPLYING WITH THE CLEANING SOLUTION VOC
CONTENT LIMITS  OF  D.5  (d)  (1)  FOR AUTOMATIC  BLANKET
CLEANING EQUIPMENT, meters are required to monitor water and cleaning
solution flow rates "CONSUMPTION".  The flew meters should be calibrated
"MONITORED" so that the VOC content of the mixed solution complies with the
requirements of D.5(c) above. "D.5 (d) (1) ABOVE".  "IN THE ABSENCE OF
METERS, VOC CONCENTRATION AND CONSUMPTION SHALL  BE
MONITORED AT THE RESERVOIR USING AVAILABLE CALIBRATION,
OR";.
                              D-15

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  (2) "FOR   ANY  OFFSET  LITHOGRAPHIC  PRINTING  PRESS
COMPLYING WITH THE CLEANING SOLUTION VAPOR PRESSURE
LIMITS  OF  D.5  (d) (2)  FOR  AUTOMATIC  BLANKET  CLEANING
EQUIPMENT,  MANUFACTURER'S  DATA ON VOC CONTENT AND
VAPOR PRESSURE MAY BE USED TO DEMONSTRATE COMPLIANCE
WITH THE REQUIREMENTS OF D.5(d) (2) ABOVE".
D.9 REPORTING/RECORDKEEPING

   (a) The owner or operator of any offset lithographic printing press shall record
and report "MAINTAIN" the following key parameters on a regular "DAILY"
basis., but no less than once per 8-hour shift.

   (1) The type of control device operating on the hcatsct offset lithographic
printing press and the operating parameters specified in D.8(a)  above.   "THE
OPERATING PARAMETERS SPECIFIED IN D.8 (a) ABOVE FOR THE
CONTROL DEVICE OPERATING ON THE OFFSET LITHOGRAPHIC
PRINTING PRESS".
                            D-16

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   (2) The equipment standard selected to comply with the requirements in D.5(a)
through (c) above.
      "(2)"  The "MATERIALS AND" the VOC  content of the fountain  and
cleaning solutions, to comply with the requirements in D.5(a) through (e), D.8(b),
and D.8(d) above.

   (4)  "(3)"  The temperature  of the fountain  solution to comply  with  the
requirements in D.8(c) above, if applicable.
      "(4)"  For manual cleaning methods, the amount of cleaning solution and
amount of water added per batch of cleaning solution mixed.
      "(5)"  For automatic cleaning methods, the flow rates of water "BLANKET
CLEANING EQUIPMENT, THE CONSUMPTION OF WATER" and cleaning
solution concentrate, as specific in D.8(d) above "IF APPLICABLE".
       Corrective actions taken when cxcccdanccs of any parameters monitored
according to the requirements of D.6 through D.8, above, occur.
                                  D-17

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                              APPENDIX D

                   OFFSET LITHOGRAPHIC PRINTING
                           CTG MODEL RULE

D.I  INTRODUCTION

   This appendix presents a model rule to limit volatile organic compound (VOC)
emissions from offset lithographic printing operations. This rule is for informational
purposes only and, as such, is not binding on the air quality management authority.
However, EPA expects that State and local air quality rules developed pursuant to
this CTG will address all the elements covered in the model rule.

   The remainder of this appendix contains the model rule.  Separate sections cover
the following  rule  elements:    applicability,  definitions,  emissions standards,
equipment standards,  emissions  standards testing, equipment standards testing,
monitoring requirements, and reporting/recordkeeping.

D.2  APPLICABILITY

   The provisions set forth  in this  model rule apply to the offset lithographic
printing industry only.  There are four types of offset lithographic printing:  heatset
                                   D-l

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web, non-heatset web (non-newspaper), non-heatset sheet-fed, and newspaper (non-



heatset web).  An affected facility may be defined as follows: one or more printing



operations involved in at least one type of offset lithographic printing process.







   Other types of printing  operations,  such as flexography,  rotogravure,  or



letterpress, may be present in an offset lithographic printing facility; however these



operations are not subject to the requirements set forth in this model rule.







   Any dryer exhaust stream for which an existing control device is employed to



control  VOC  emissions  should  not  be required to meet "THE  PERCENT



REDUCTION OR EMISSIONS LIMITS SPECIFIED IN SECTION D.4(A) OF



THE MODEL" rule until the control device is replaced for other reasons. In other



words, no facility should be required to upgrade or replace a control device that is



in place before the date of this regulation,  provided that the device  "MEETS THE



APPLICABLE STATE RACT REQUIREMENTS FOR THE" destruction "OR



RECOVERY" of VOC's and is operated and  maintained in accordance with the



procedures described  in Sections D.6,  D.8, and D.9.
D.3 DEFINITIONS
                                   D-2

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  Alcohol substitutes. Non-"ISOPROPYL" alcohol additives that contain VOC's
and are used in the fountain solution. Some additives are used to reduce the surface
tension of water; others (especially in the newspaper industry) are added to prevent
piling (ink build-up).

   Cleaning solution.   "LIQUID SOLVENTS" used to remove ink and debris from
the surfaces of the printing press and its parts.

   Dampening System.   Equipment used  to deliver the fountain  solution to  the
press "LITHOGRAPHIC PLATE".

   Fountain  Solution.     A  mixture  of  "PRIMARILY"  water,  "OTHER
CHEMICALS,   AND  ADDITIVES  THAT  REDUCE  THE  SURFACE
TENSION" reduces the surface tension of the water so that it spreads easily across
the printing surfaces.  The fountain solution wets the non-image areas so that the
ink is maintained within the image areas. Isopropyl alcohol, "OR ALCOHOL
SUBSTITUTES ARE COMMONLY used to reduce  the surface tension of the
fountain solution.

   Heat-set.  "A WEB PRINTING OPERATION" where heat is required "TO
EVAPORATE"  the printing ink "OILS".  "HEATSET" dryers are used to deliver
the heat.
                                 D-3

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  HEATSET DRYER "A DEVICE TO HEAT THE PRINTED SUBSTRATE



AND TO PROMOTE EVAPORATION OF INK OILS".







  Lithography.  A  "PRINTING" process where the image and non-image areas



are chemically differentiated; the image area is oil receptive and the non-image area



is water receptive.  This method differs from other printing  methods, where the



"IMAGES ARE PRINTED FORM RAISED OR RECESSED" surface.







  Non-Heatset.   "A LITHOGRAPHIC OPERATION" where the printing inks



are set without the use heat. For the purposes of this rule, ultraviolet-cured "AND



ELECTRON BEAM-CURED" inks are considered non-heatset.







  Offset.   A printing process that  transfers the  "INK FILM FROM THE



LITHOGRAPHIC PLATE" to an intermediary surface "(BLANKET)", which, in



turn transfers the  "INK FILM" to the printing substrate.







  Press. A printing production assembly "COMPOSED OF ONE OR MORE"



units to produce a "PRINTED SUBSTRATE".







  RECIRCULATION RESERVOIR.  THE COLLECTION TANK WHICH



ACCEPTS  FOUNTAIN  SOLUTION RECIRCULATED FROM  PRINTING



UNIT(S).  THE TANK COMMONLY CONTAINS A COARSE FILTER TO
                               D-4

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REMOVE CONTAMINANTS FORM THE FOUNTAIN SOLUTION AS WELL
AS THE COOLING COILS FOR REFRIGERATION.

  Sheet-fed.  "A PRINTING" operation  where "INDIVIDUAL SHEETS  OF
SUBSTRATE ARE" is fed to the press "SEQUENTIALLY".

   Unit.   The smallest complete "PRINTING" component of a printing  press.
   Web.  A continuous roll of paper used as the printing substrate.

D.4  EMISSION STANDARDS

   (a) Any person who owns or operates a heatset offset lithographic printing press
shall reduce VOC emissions from the press  dryer exhaust by "90" weight- percent
of total  organics  ("LESS"  methane and  ethane) or maintain "A  CONTROL
DEVICE" outlet concentration of, "LESS THAN 50 PPMV AS C,  " whichever
is less stringent.

D.5 "PROCESS STANDARDS"

   (a) Any person who owns or operates a web-fed offset lithographic printing
press that uses "ISOPROPYL" alcohol in the fountain solution shall "MAINTAIN"
total fountain  solution  VOC's  "AT  8  PERCENT" or less  (by  volume).
                                D-5

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Alternatively, a standard of "12" percent or less (by volume) VOC may be used if
the fountain solution containing alcohol is refrigerated to less than 60°F.

   (b)  Any person who owns or operates a sheet-fed offset lithographic printing
"PRESS  THAT USES  ISOPROPYL  ALCOHOL IN THE  FOUNTAIN
SOLUTION SHALL MAINTAIN TOTAL FOUNTAIN SOLUTION VOCS AT
10 PERCENT OR LESS (BY WEIGHT).  Alternatively, a standard of  "15"
percent or less (by volume) VOC  may be used if the fountain  solution containing
alcohol is refrigerated to below 60 °F.
   "(c)" Any person who owns or operates any type of offset lithographic printing
press shall be considered in compliance with this regulation if the only VOC's in
the fountain  solution  are in non-"ISOPROPYL"  alcohol additives or alcohol
substitutes, so that the concentration of  VOC's in the  fountain  solution is "5"
percent or less (by weight).  (The fountain  solution should not contain any alcohol.)

   "(d)"  Any person who owns  or operates an offset lithographic printing press
shall reduce VOC emissions from cleaning  solutions by using cleaning solutions with
a 30 percent or less VOC content. "OR A  VOC CONTENT OF 900 GRAMS OR
LESS OF VOC PER LITER OF  MATERIAL  AND A VOC COMPOSITE
                                                    0
PARTIAL PRESSURE OF 25 MM HG  OR LESS AT  20/fC (68 T)".
                                 D-6

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D.6 EMISSIONS STANDARDS TESTING

   (a)  For the purpose of demonstrating  compliance with the emission control
requirements of this  rule, the affected  "SOURCE"  shall be run at  "THE
MAXIMUM PRACTICAL" operating conditions and flow rates "COMPATIBLE
WITH SCHEDULED PRODUCTION DURING COMPLIANCE TESTING"

(b)   "EMISSION TESTS  FOR  SOURCES  INSTALLED  AFTER  THE
EFFECTIVE DATE OF THIS REGULATION SHALL INCLUDE AN INITIAL
TEST  WHEN THE  CONTROL   DEVICE  IS  INSTALLED  THAT
DEMONSTRATES COMPLIANCE  WITH EITHER  THE  90 WEIGHT-
PERCENT REDUCTION OR THE 50 PPMV AS C, EMISSIONS LIMITS
SPECIFIED IN D.4(A)M.

   (c)  The following EPA methods (in  40 CFR 60, Appendix A) shall be used to
demonstrate compliance with  the  emission limit or percent reduction efficiency
requirements listed  in D.4 (a) above.   "ALTERNATE METHODS MAY BE
USED WITH THE APPROVAL OF THE ADMINISTRATOR".

   (1)  EPA Method 1 or 1A,  as appropriate, "MAY" be used for selection of the
sampling sites.  The control device inlet sampling site for determining efficiency in
                              D-7
                              irr,

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reducing total organics (less methane and ethane) from the dryer exhaust shall be
placed before the control device inlet and after the dryer.

   (2)  EPA Method 2,  2A,  2C, or 2D, as appropriate, "MAY" be used to
determine the volumetric flow rate of the exhaust stream.

   (3) "EPA METHOD 18, 25, OR 25A, AS APPROPRIATE, MAY BE USED
TO DETERMINE EMISSIONS FROM HEATSET DRYER AND CONTROL
DEVICE EXHAUSTS".   Good judgement is required in determining the best
applicable VOC test method for each situation.

   (i) Since EPA Method 25 has a minimum detectable concentration of 50 ppm
carbon, and given the low  concentration of VOC's sometimes present in dryer
exhaust from offset lithographic presses and  the high removal efficiency achievable
with add-on controls, EPA Method 25 A may be more suitable than EPA Method 25
for determining compliance , "TO A TEMPERATURE ABOVE THAT OF THE
GASrSIKLAM, E.l^r350cFu-.  Note that  EPA Method 25 specifies a minimum
probe and filter temperature of 265°F. To prevent condensation, the probe and filter
should  be  heated to  "A  TEMPERATURE ABOUT THAT OF THE GAS
STREAM^350°F".
   (ii)  EPA Method 25 A utilizes a flame ionization detector (FID), which had the
ability to measure low concentrations. This technique usually is not recommended
                                 D-8

-------
for  "INCINERATOR OUTLETS WITH VOC CONCENTRATIONS IN
EXCESS  OF 50 PPM AS  C,.  HOWEVER, EPA  METHOD  25A IS
PREFERRED  FOR  INCINERATORS  WHERE  EXPECTED OUTLET
CONCENTRATIONS WILL  BE BELOW 50 PPM AS Ct OR WHERE
DRYERS FROM  MULTIPLE PRESS  LINES DISCHARGE INTO  A
CENTRAL CONTROL DEVICE".

D.7 EQUIPMENT STANDARDS TESTING

   (a) Fountain Solution Testing

   (1) A "COMPOSITE" sample of the fountain solution (as used) shall be taken
from the from "EACH SUBJECT PRESS TO DETERMINE" fountain solution
VOC content in accordance with section D.5 (a) through (d) above.

   (2) "RECORDS OF FOUNTAIN SOLUTION COMPOSITION (AS MIXED)
MAY BE USED  TO DETERMINE THE VOC  CONTENT OF  THE
FOUNTAIN SOLUTION".

   (b) Refrigeration Equipment Testing
                           D-9

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  (1)  A thermometer or other temperature detection device capable of reading to



0.5°F shall be used to ensure that a refrigerated fountain solution containing alcohol



is below 60°F.







  (c)  Cleaning Solution Testing







  (1)  "SAMPLES" of the cleaning "SOLUTIONS" (as used) shall be taken to



demonstrate compliance with the cleaning solution VOC content "OR VAPOR



PRESSURE imitations listed in D.5 "(d)" above.







  (2)    "RECORDS OF CLEANING SOLUTION COMPOSITION (AS



MIXED)  TOGETHER  WITH  MATERIAL  SAFETY DATA  SHEET



INFORMATION MAY BE USED TO DETERMINE THE VOC CONTENT OF



THE CLEANING SOLUTION.  ALTERNATIVELY, VOC CONTENT OR



VAPOR PRESSURE AS PROVIDED BY THE MANUFACTURER MAY BE



USED  TO DEMONSTRATE COMPLIANCE WITH THE REQUIREMENTS



OF D.5 (D)".







D.8  MONITORING REQUIREMENTS







  (a)  Add-on Dryer Exhaust Control Devices
                             D-10

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  (1)  The owner or operator of a heatset offset lithographic printing press
"EQUIPPED WITH AN AFTERBURNER" shall install, calibrate, maintain, and
operate  a,  according to the manufacturer's  instructions,  "CONTINUOUS
TEMPERATURE  MONITORING  EQUIPMENT TO  MONITOR  THE
COMBUSTION   CHAMBER   TEMPERATURE   OF  THERMAL
AFTERBURNERS OR THE TEMPERATURE RISE ACROSS A CATALYTIC
AFTERBURNER  BED.  THE COMBUSTION CHAMBER OR CATALYST
INLET TEMPERATURE SHOULD BE SET DURING TESTING REQUIRED
TO DEMONSTRATE COMPLIANCE WITH THE EMISSION STANDARDS
OF D.4 (A)".

  (2)  The temperature monitoring device shall be equipped with a continuous
recorder and shall have an accuracy of "5°F".

  (3)  The dryer pressure shall be maintained  lower than the press room air
pressure such that air flows into the dryer at  all times.  "THE  CAPTURE
EFFICIENCY FOR THE DRYER SHALL BE DEMONSTRATED USING AN
AIR FLOW DIRECTION INDICATING DEVICE".

  (b) Fountain Solution VOC Concentration
                             D-ll

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   (1) "RECORDS OF FOUNTAIN SOLUTION COMPOSITION (AS MIXED)



MAY BE  USED TO  DETERMINE THE VOC  CONTENT  OF  THE



FOUNTAIN SOLUTION; OR".







   (2) The owner or operator of any offset lithographic printing press shaH "MAY"



monitor fountain solution VOC concentration "AT LEAST ONCE PER BATCH"



with a refractometer that is corrected for temperature. The refractometer shall have



"A VISUAL, ANALOG" or digital readout with an accuracy of 0.5 percent VOC.



A standard solution shall be used to calibrate the refractometer for the type of VOC



used  in the fountain. "SOLUTION; OR"







   (3) The owner or operator of any offset lithographic printing press may monitor



fountain solution VOC concentration with a hydrometer equipped with a temperature



correction "AT LEAST ONCE PER BATCH WITH A HYDROMETER THAT



IS CORRECTED FOR  TEMPERATURE". The hydrometer shall have  "A



VISUAL, ANALOG" or digital readout with an accuracy of 0.5 percent VOC.
   (c) Fountain Solution Temperature
   (1) The owner or operator of any offset lithographic printing press using
                                D-12

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refrigeration equipment oa "FOR" the fountain "SOLUTION" "TO COMPLY
WITH SECTION D.5 (a) OR (b) "SHALL MONITOR THE" temperature in the
fountain solution reservoir below the solution surface.

  (2)   "THE FOUNTAIN SOLUTION TEMPERATURE  SHALL  BE
RECORDED AT LEAST ONCE PER 8-HOUR SHIFT".

  (d) Cleaning Solution

  (1)  For any offset lithographic printing press  "COMPLYING WITH THE
CLEANING SOLUTION VOC  CONTENT LIMITS  OF D.5 (d) (1) FOR
AUTOMATIC BLANKET CLEANING EQUIPMENT, meters are required to
monitor water and cleaning solution "CONSUMPTION". The meters should be
"MONITORED" so that the VOC content of the mixed solution complies with the
requirements of "D.5 (d) (1) ABOVE".  "IN THE ABSENCE OF METERS,
VOC CONCENTRATION AND CONSUMPTION SHALL BE MONITORED
AT THE RESERVOIR USING AVAILABLE CALIBRATION, OR";.
   (2) "FOR  ANY  OFFSET  LITHOGRAPHIC  PRINTING  PRESS
COMPLYING WITH THE CLEANING SOLUTION VAPOR PRESSURE
LIMITS  OF  D.5  (d) (2)  FOR AUTOMATIC  BLANKET  CLEANING
                            D-13

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EQUIPMENT, MANUFACTURER'S  DATA  ON  VOC CONTENT  AND
VAPOR PRESSURE MAY BE USED TO DEMONSTRATE COMPLIANCE
WITH THE REQUIREMENTS OF D.5(d) (2) ABOVE".
D.9 REPORTING/RECORDKEEPING

   (a)  The owner or operator of any offset lithographic printing press shall record
and "MAINTAIN" the following key parameters on a "DAILY" basis.

   (1)  THE OPERATING PARAMETERS SPECIFIED IN D.8 (a) ABOVE
FOR  THE  CONTROL  DEVICE  OPERATING  ON THE  OFFSET
LITHOGRAPHIC PRINTING PRESS".
   "(2)" The "MATERIALS AND" the VOC content of the fountain and cleaning
solutions, to comply with the requirements in D.5(a) through (e), D.8(b),  and
D.8(d) above.
   "(3)" The temperature of the fountain solution to comply with the requirements
in D.8(c) above, if applicable.
                             D-14

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   "(4)" For manual cleaning methods, the amount of cleaning solution and amount
of water added per batch of cleaning solution mixed.

   "(5)"   For automatic  cleaning methods, the flow rates of water  "BLANKET
CLEANING EQUIPMENT, THE CONSUMPTION OF WATER" and cleaning
solution concentrate, as specific in D.8(d) above "IF APPLICABLE".
                                D-15

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GRAPHIC ARTS
TECHNICAL FOUNDATION
GRAPHIC ARTS TECHNICAL FOUNDATION « 4615 FORBES AVENUE • PITTSBURGH, PENNSYLVANIA 15213-3796 • 412/621-6941
         „_>:> 'iii
FAX: 412/621-3049 « TELEX: 9103509221
                                            COMMENTS
                                                on
                            DRAFT  CONTROL TECHNIQUES GUIDELINE  -
                                OFFSET  LITHOGRAPHIC PRINTING
                                                by
                                     William  D.  Schaeffer
                             Chairman,  Technical  Committee,  ECB
                     Consultant to  Graphic Arts Technical Foundation
              Research  Director  (ret.)/  Graphic Arts Technical Foundation
                                                                November  20,  1991
  MEMBER-SUPPORTED, NONPROFIT, SCIENTIFIC. TECHNICAL AND EDUCATIONAL ORGANIZATION SERVING THE INTERNATIONAL GRAPHIC COMMUNICATIONS INDUSTRIES SINCE 1924.

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                            COMMENTS
                               on
              DRAFT CONTROL TECHNIQUES GUIDELINE  -
                  OFFSET LITHOGRAPHIC PRINTING
                               by
                      William D. Schaeffer
               Chairman, Technical Committee, ECB
         Consultant to Graphic Arts Technical Foundation
   Research Director (ret.)/  Graphic Arts Technical Foundation
     Our industry greatly appreciates the opportunity to comment

on the Draft CTG document for Offset Lithographic Printing.  We

have provided to you and the USEPA in-depth comments and line-by-

line critiques on the Draft CTG and the model CTG Rule (Appendix

D) .  Time is inadequate to review this material in all of the

detail that it deserves.  Mr. Bender has reviewed the offset

lithographic printing processes and the segments of the printing

industry in which the processes are used.  He has pinpointed and

explained many of the shortcomings of the present document and

the recommendations for RACT.

     My purpose is to review critically three areas in the CTG:

     (1)  The assumptions used in developing the heatset web

          offset model plants and their consequences,

     (2)  RACT recommendations for process materials, i.e.,

          fountain solution and cleaning solutions, and

     (3)  Unrecognized administrative burdens and subsequent

          costs, particularly for the sheetfed printer.


Heatset Web Offset Model Plants


     The assumptions that the printing unit in heatset web offset

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presses contains only a single blanket  (Table 3-1, p. 3-44) is in



direct conflict with the dominant press design in this industry



segment, the blanket-to-blanket printing unit.  As a consequence,



the average number of units per press are estimated as 4 to 6 as



opposed to the correct 8 to 10 for the four or five printing



couples in blanket-to-blanket presses.    Underestimation of the



number of units per press and per plant causes an overestimate of



ink consumption per unit.  Our calculation indicates the number



is 1.6 to 2 times greater than it should be.  Thus the ink



consumption per press unit as estimated from industry surveys



(Sections 3.6.1, p. 3-46 and 5.1.1., p. 5-1) should be 5.7



instead of 10.3 pounds per unit-hour.  Usage of fountain



solution, based on a fixed ratio to ink consumption, therefore,



is also too large.  The overall effect is to exaggerate the VOC



content of heatset ink and fountain solution used annually in the



process  (Table 3-3, p. 3-47) and the potential VOC emission



reductions as a result of the controls proposed as RACT (Table 5-



2, p. 5-6).





RACT Recommendations for Process Materials



     The large majority of the offset lithographic printers



affected by the Control Techniques Guideline are the sheetfed



printers.  The impact on the operations is through the proposed



materials standards, namely, fountain solutions (Sections D.5  (a)



through  (d)) and cleaners (Sections D.5 (e)) and the proposed



monitoring (Sections D.7 (a) through  (c) and D.8  (b) through  (d))



and record keeping requirements.  In brief, the industry



assessments of the draft proposals are:

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     (1)   the proposed reductions in isopropanol use in the



          fountain solution are excessive (D.5 (a) through (d)),



     (2)   the concept that a large sheetfed plant can reduce



          isopropanol use more readily than a small plant is



          without basis (D.5 (c)),



     (3)   the proposed use of a 30 percent VOC content cleaner as



          a universal cleaner to replace the current 100 percent



          VOC blanket and press cleaners is not a demonstrated



          capability (D.5 (e)).  Moreover, excess volumes of



          cleaner would be required to achieve comparable



          results.



     Every one of these three proposals will require additional



non-productive make-ready time between jobs and increase the



amount of print waste produced, while attempting to achieve the



desired print quality.  Ironically, the proposed excessive



reductions in VOC use promises to multiply solid print waste



production, a poor environmental and a poor economic trade-off.



     Additional critical assessments of Draft CTG proposals



include the following:



     (4)   suggestion of a method (modified Method 24) still in



          development for the measurement of VOC content in



          aqueous systems provides absolutely no basis for



          criticism and is certainly inadequate for the CTG



          (Sections D.7 (a)  and D.7 (c)(2)), and



     (5)   the proposed number of sampling sites (Section D.7



          (a)(l)), the frequency of sampling (D.9 (a)), the



          analyses of samples (D.8 (b)  and (c)), and record



          keeping (D.9 (a)(3)  through (6)) comprise demands which

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          none in the sheetfed industry except the largest firms



          are equipped to handle.  These requirements, moreover,



          track only the VOC concentrations in the materials used




          in the processes.



     From the sheetfed printer's perspectives, these last two



sets of requirements, (4) and (5),  virtually insure that the



printer establish a laboratory with trained technicians.  These



facilities do not exist today, and involve an investment totally



ignored in the CTG draft.  The investment, moreover, contributes



nothing to an improved environment.








Industry Suggestions



     Corrective measures are described in detail in the industry



line-by-line comments on Appendix D of the Draft CTG.  Our



recommendation, in brief, are the following:



     (1)  the proposed concentrations in isopropanol fountain



          solution concentrations to be greater than the draft



          proposal, e.g., 10 instead of 6 and 15 instead of 10



          percent VOC,



     (2)  eliminate the proposed differences between fountain



          solution VOC content in small and large sheet-fed



          pressrooms,



     (3)  distinguish between blanket and press cleaners and



          establish an upper vapor pressure limit on 900



          gram/liter VOC cleaners, which provide for efficient



          operations,




     (4)  the printer allowed to use manufacturing suppliers data

-------
          on VOC content of solution components plus mixing



          formulations to calculate VOC content rather than



          experimental determination,  and



     (5)   a reduction in the number of sampling sites, the



          frequency of measurements,  the methods and quality of



          measurements are all suggested modifications.



     The  largest group of offset lithographic printers to be



affected  by the CTG will be the sheetfed printers.   Our industry



committee believes that our suggestions will reduce VOC emissions



with minimal waste increases and limited financial  costs.  We



appreciate your attention to our suggestions and requests.  Their



inclusion in the Control Techniques Guideline will  make the



document  more effective and less frustrating to the regulated



community and beneficial to the environment.

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 Comments  to  Environmental Protection  Agency,  Chemicals  and Petroleum Branch

 made  by C.Um.  Schneidereith representing Schneidereith  & Sons,  Inc.  on

 November  20,  1991.



 Schneidereith  &  Sons  is  a small/medium  sized  commercial printing establishment

 located in Baltimore,  Maryland,  and currently utilizing the printing process

 most  prevalent today  which is  sheet-fed,  offset lithography.

 Employing about  60  people,  this  firm  is  in  the upper 20 percentile  (by size)

 of  printing  firms.  80  percent  of all  commercial firms employ 25  people or

 less,  and only 20 percent  of the firms  employ more  than 25  people.

 Equipment operated  daily on a  two shift  basis are the following:

       (1) Six-color Miller TP104     41  inch width

       (1) Six-color Miehle Roland    41  inch width

       (1) Four-color Miller TP38     38  inch width

       (1) Two-color Miller TP104  -  41  inch width

       (1) Single-color Miehle      -  29  inch width

       (1) Single-color Heidelberg    20  inch width

Total  of  20 printing units  in  operation.

Currently we are using the  following volumes of materials which  contain VOC

concentrations.

       Ink                     @    18,077 pounds per year

      Cleaning Solvents        @     1,980 gallons per year
                                          converts to 12,084  pounds  per year

      Isopropyl Alcohol        @     -0-    none used.

      Alcohol substitutes      @        52 gallons per year

Calculations of the above usage  rates yield VOC emissions as  follows:

      Ink                      @     0.11  tons VOC's per year emitted

      Cleaning solvents        
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                                      -2-




   Impact of Control Techniques Guideline  (CTG) dated  September 6,  1991.	




      This firm has demonstrated  that alcohol  can be completely eliminated




from the lithographic process and still  maintain the highest  of quality




standards in so doing. This firm produces  art  catalogs  for  many of  the leading




museums in Washington and New York along with  the most  difficult advertising




and commercial print projects. Since isopropyl alcohol  repryesints one  of  the




greatest culprits in the quest to reduce VOC's in the printing  industry,




emphasis should be given to the technical  and  educational aspects of  weaning




this industry completely away from its use.




      Operating a complete facility without alcohol is  not  an easily




accomplished task. For example, the rubber rollers used to  apply the  alcohol




substitute & water combination must be maintained in superior condition and




the durometer of the roller (its softness) is critical  to the success of




alcohol substitutes. This is an expensive process to constantly monitor roller




condition and durometer. Rollers must be changed out and replaced far more




frequently without alcohol than with alcohol.




      Roller settings are more critical when not using alcohol.  Alcohol tends




to cover many mechanical sins. These settings are time consuming and require




the attention of the top paid craftsmen  (not more lowly paid  helpers). These




settings must be checked and adjusted more frequently due to  the fact that




without alcohol one has a more limited tolerance range.




      If alcohol can be eliminated from  the process, it is not  logical that




the temperature must be continuously monitored by probes and  recorded for each




fountain unit.  Without alcohol the VOC reduction is of substantial proportions




in itself,  and  the substitutes are used in such small volume  that the total




VOC emission is not a significant  number. Also, the vast majority of dampening




systems in  operation today are refrigerated due to the need to  maintain




constant percentage of alcohol in  the fountain solutions.  Printers who do not

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                                       -3-




 maintain a constant percentage of alcohol will see unacceptable variations in




 the print quality.  Thus,  refrigeration was adapted to dampening fountains in




 attempts to control the evaporation rate of alcohol purely for quality




 reasons.   Should  one unit of refrigeration malfunction and the temperature




 thereby increase,  an operator is  forced to repair it to provide consistency of




 quality.  So the process itself of causing erratic quality ensures the repair



 and maintenance of  such equipment --  thereby making the need to install probes




 and recording  devices redundant and in our opinion not necessary.




       The experience and  learning curve to run high-quality work without




 alcohol is significant. The  experimental phase of testing alcohol substitutes




 in  one fountain on  a multi-color  press lasted  approximately two months.  Once




 alcohol substitutes are introduced  into the  entire press  we noted the real




 impact of the  learning curve:



       a)     Dampening changes  are more difficult  to  effect  using alcohol



             substitutes.




       b)     Roller  problems  are more  critical




       c)     Roller  replacements become major cost  item.




       d)     Build-up of by-products on ink rollers cause  inking irregularities




       e)     Dot gain is increased as  dampening  efficiency decreases due  to



             elimination of alcohol




       f)     Maintenance is more critical  in dampening  units and inking units.




       g)     Spoilage due  to  color being "out of tolerance"  is  more prevalent




             due to  difficulty  in  balancing water and ink. (Cost of reprinting



             entire  jobs can  be  extremely high.)




 (Suggestion) Monitor  fountain  solutions with testing for  VOC concentration and




 temperature  only on  those units using  alcohol. Refrigeration should not  be the




 issue here  -- but rather alcohol.   Testing refrigerated fountain solutions is




not going  to be program effective and will do practically nothing  toward the




goal of reducing VOC emissions. The lithographic printing process  itself will

-------
                                      -4-



"police" the industry in maintaining refrigerated units to correct




temperatures. However, testing those fountain units vhich use alcohol  --




whether refrigerated or not refrigerated -- would be program effective. But




since there is nothing to prohibit non-refrigerated fountains from using




isopropyl alcohol, these units should be addressed in the scheme of imposing




controls.



Sec. D-8, C 1-2 stipulates that on ". . . any press using refrigeration .  . .




shall install, maintain and operate a temperature probe . . .".No mention




made of non-refrigerated units. It should be more important to monitor the




non- refrigerated units,  especially if using isopropyl alcohol.




      The monitoring process itself is burdensome, especially to the small



operators. To install the monitors, educate those responsible, and detail a



person to record and maintain the records will be a very real cost, which in




my estimation will yield negligable results in reducing VOC emissions. In a




small shop -- such as the majority of printing establishments are -- this will




pose a detrimental burden on management which is already over worked and




frustrated by a myriad of regulations and paper work.  I know of not one small




shop which can afford the payroll of someone to monitor fountains every eight



hours.




      If monitoring is deemed necessary it  would be sufficient to monitor and




record the results on every separate batch  of fountain solution when mixed.




Regardless of what is being tested for,  it  will not materially change while in




the process of being used.  Here again the printer and process itself will




"police" the results because if that batch  of fountain solution does change,




it will show up as unacceptable quality and force the operator to shut down.




      Create the incentive  for the owner/operator to explore alternatives and




substitutes instead of imposing yet another layer of non-productive cost in an




industry facing competitive pressures from  over-seas.




      Cleaning solutions  are a unique problem and also a dilemma to printers.


                                   >". ~ "*
                                   1 -' V-

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                                       -5-




 A rag with solvent can easily be rubbed over an inked surface and the ink




 thereby removed.  (The key vork is "rubbed"). A multitude of solvents could




 pass this usage test easily,  regardless of VOC content. Few of the




 applications of cleaning solvents are this simple though.




       Consider the structure  of an inking unit on a printing press.  Current



 sheet-fed press equipment use approximately 20 -  22 rollers in each printing




 unit. The diagrams on pages 2-2 and 3-6 are over  simplifications of roller




 configurations for the average sheet-fed press. Your diagrams show 11 ink




 rollers,  whereas  the sheet-fed presses used today have 20  to 22 ink rollers.




 Thus a six-color  press will have from 120 to 132  rollers which will require




 cleaning  at  least once per day --  possibly several times.  The surfaces of




 some of these rollers are not visible,  being surrounded by the outer rollers.



 The cleaning solutions of products with 30 percent or less VOC concentrations




 will not  dry properly and those inner rollers will not clean-up well.  It  is




 imperative that the cleaning  solutions  used on press rollers will:



       a)  clean properly,




       b)  dry reasonably quickly,




       c)  not leave a residual film.




 It  is impossible  to access  some of the  ink rollers to hand wipe the  residual




 solvent without a major disassembly of  the inking  system which would include a



 day-long  process.




      The percentage of VOC mandated for  cleaning  solvents should  be analyzed




 carefully and  researched  by technical experts thoroughly knowledgeable of




 press equipment and the unique  constraints various ink systems impose upon the




 printer.  To  do  otherwise,  the printer cannot  operate.  I  cannot believe the




 30 percent VOC  limit will yield an acceptable roller solvent.  The  Roller  wash




we currently use, which is giving  satisfactory results,  contains 84  percent




VOC's. It  is incomprehensible to me  that we could  find an  acceptable roller




wash containing only 30 percent VOC's. To  attempt  to use an unsatisfactory

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                                      -6-




product would cripple our operation.




      Ink VOC emissions are not as critical to the small/medium sheet-fed




lithographer as to the larger operators simply because  they use less




volume/poundage. However, such factors as drying, scuff resistance,




appearance, and handling on press are all important.  The recent introduction




of vegetable-based inks such as soy-bean is promising but the results do not




indicate that petroleum-based inks can be phased out any time in the




foreseeable future. There are problems contingent with  the vegetable-based




inks that small operators simply do not have the access to technology and




research to properly make that transition at this point in time.




                                    SUMMARY




      The monitoring requirements as set forth in Section D.8 (b) "Fountain




Solution VOC Concentration" definitely pose an onerous and costly imposition




upon the small/medium operators and should be amended to apply only if




isopropyl alcohol is used in the fountain, and then only applied on a "batch"




basis instead of every 8-hours. Once tested a "batch" will not change




significantly in VOC concentration.




      The Section D.8 (c) "Fountain Solution Temperature" should only be




imposed on those units using isopropyl alcohol.  This section targets




"refrigeration equipment" when it should target  alcohol. There should not be




the need to test any press which uses alcohol substitutes.




      Cleaning solutions should be researched by those intimately familiar




with printing press inking systems prior to  mandating a specific percentage of




VOC concentration.




                                    Respectfully submitted,








                                    C.  Vm.  Schneidereith,  Jr.




                                    President

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1.2  QUESTIONS AND COMMENTS FROM THE COMMITTEE
Question:   Why  is  industry not taking advantage of the large
            cost savings  due  to a  reduction in  alcohol?
Response:   The  industry  has  reduced alcohol for Occupational
            Safety  and  Health Administration (OSHA) regulations
            and  fire  insurance benefits.   However,  it is easier
            for  the operator  to use too much isopropyl alcohol
            (IPA) because it  makes the press easier to operate
            and  keep  within specifications.
Question:   Will ink  pigments poison the  catalyst in a catalytic
            incinerator and can the incinerator actually achieve
            95 percent  control?
Response:   It may  not  be ink pigments that poison the catalyst
            - other ingredients in the inks and in the fountain
            solution  may  poison the catalyst in many cases.
            Most vendors  work with the printers in choosing  the
            best catalyst for their operation.   Industry has
            successfully  used catalysts without poisoning.   As
            for  control,  current use in industry indicates that
            the  catalytic incinerator  can achieve 98 percent
            control.
Question:   Do the  16,700 facilities in non-attainment areas, as
            referred  to in the presentation, take into account
            the  newly revised non-attainment area boundaries?
Response:   Since the boundaries were  only revised about a week
            before  this meeting, there was no time to take into
            account the changes and redo  the numbers for this
            presentation.
Question:   How  are the very  small and large model plants
            differentiated?
Response:   The  size  of the plants are determined by the number
            of printing units.
Question:   Were the  operating costs of incinerators based on
            3000 operating hours per year, and  are the
            incinerators  shut down at  all other times?
Response:   Some incinerators may  shut down, while others may
            "idle"  during the off-hours,  making warm up
                               11

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            unnecessary.  Energy costs were  calculated  based  on
            3000 operating hours per year.
Comment:     The wording in the draft CTG  should be  clarified  to
            ensure that monitoring should take place  only when
            the unit is operational.
Question:    Would reformulation of the inks  to soybean  inks be a
            viable control option for the larger  facilities?
Response:    Soy inks are used in non-heatset processes, which
            have low emissions to begin with.  Requiring heatset
            processes to change to non-heatset was  not
            considered reasonable, and hence were beyond the
            scope of RACT.
Question:    The total percent reduction is plausible  based on
            what the control device sees, but given the amount
            of potential emissions, does  this really  correspond
            to what the control device actually sees?
Response:    We may have not made it very  clear that the
            efficiency values refer to the efficiency of the
            control device and not the percent of all VOC's
            applied to the substrate.  There is approximately 20
            percent retention of VOC's from  ink in  the  paper.
Question:    Do all the volatile organic compounds (VOC) from
            heatset inks go out from the  dryer?
Response:    Essentially, all the VOC's from  the inks  that are
            volatilized exit through the  dryer.
Question:    Do the control options for large sheet-fed  plants
            differ technically from other sheet-fed plants as to
            warrant the different control options?  What is the
            difference between these two  types of plants and  why
            can't control for one unit be the same  for  24 units?
Response:    The lower level of control for larger plants was  due
            to the fact that large plants could cope  with the
            costs better than smaller plants.
Question:    Since the alcohol content of  the fountain solution
            is falling with changes in the industry,  what year
            were the model plants emissions  based on?
                                12

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Response:    The use of fountain solution in the model plant was
             based on a report of a survey performed for a
             meeting held in 1989;  the meeting notes were
             published in 1990.
Question:    Is  there a point in which the performance of the
             fountain solution decreased a great deal due to a
             reduction in alcohol?
Response:    There is no perfect linear relationship between
             alcohol content and performance;  with a management
             commitment to quality, a reduction in alcohol should
             not be a problem.
Question:    What are alcohol substitutes made of?
Response:    They are made up of cellulose derivatives, propylene
             glycol, and glycol ethers.   Material safety data
             sheets (MSDS) do not indicate what makes up the VOC
             content or what the hazardous air pollutant (HAP)
             content is, and, since many vendors feel that the
             fountain solution ingredients are proprietary, it is
             difficult to identify  all the ingredients of
             fountain solution additives.
Comment:     Inks should be considered differently than coatings
             and the structure of the model rule should be
             changed to indicate this difference.
Comment:     There were some reservations that requiring lower
             VOC cleaning solution  (<30 percent VOC) would reduce
             the number of different cleaning products available
             and would thereby impede the cleaning process, since
             one cleaning solution  typically cannot be used for
             every application.   Some printers use 100 percent
             VOC cleaning solution  and maintain that there is no
             viable substitute.
Response:    Users of the lower VOC cleaning solution exist and
             say that they are able to use these cleaners
             successfully.  The EPA is trying to obtain more
             complete data on this  issue and will address it in
             the future.
                                13

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                     2.0  DISCUSSION SECTION

2.1 AGI ROSOS, PRESIDENT, ROSOS RESEARCH LABORATORIES, INC.
2.1.1   Presentation
    Ms. Agi Rosos of Rosos Research Laboratories, Inc. gave a
presentation on alcohol substitutes.   Rosos Research Laboratories
has been a manufacturer of alcohol replacements for over 21
years.   Ms. Rosos read from a prepared speech that is enclosed.
                                14

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2.1.2   Questions and Comments
Question:     Glycol  ethers  were  mentioned as a component of the
             fountain solution.   Since glycol ethers are HAP's,
             are  VOC's being replaced by an equally harmful
             chemistry?
Response:     Ms.  Rosos responded that while the first few
             formulations did indeed contain HAP's, Rosos has
             completely  reformulated the product and are
             currently testing the  new HAP-free formulation.
Question:     Where does  OSHA stand  on alcohol replacements?
Response:     The  response was that  these substitutes are well
             within  the  limits set  by OSHA.   However, the
             17 percent  alcohol  level probably would not be
             allowed by  most states,  but printers that stay below
             10 percent  alcohol  would generally not have any
             problems with  OSHA.
Question:     What are the differences between large sheet-fed and
             other sheet-fed plants,  and is a control distinction
             necessary for  the two  categories?
Response:     Ms.  Rosos answered  that a distinction is not
             necessary but  she does encourage refrigeration on
             all  fountain solutions.
Question:     Why  isn't it possible  to measure the VOC content in
             the  fountain solution  by taking samples from the
             trays and tanks, and why should samples be taken
             from freshly mixed  solution?
Response:     The  response was that  the tanks and trays contain
             recirculated solution  with residual contaminants due
             to contact  with other  parts of the press.  The
             samples should be taken near the tap of the alcohol
             proportioner,  as alcohol is mixed with water.
                                15

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2.2  PAUL MARTIN,  C.A. ENTERPRISES, LTD.
2.2.1  Presentation
    Mr. Paul Martin of C.A. Enterprises, LTD. gave a
presentation regarding the use of magnets in reducing the surface
tension of water in the fountain solution.  C.A. Enterprises has
been primarily a manufacturer of magnets for the treatment of
water used for heating and cooling in residential and commercial
buildings uses for the last 20 years.  The magnets help control
lime, scale and corrosion in equipment that contacts water.
Mr. Martin read from a prepared speech that is enclosed.
                                16

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2.2.2  Questions and Comments
Question:    If  the  magnets  can  do  what you have said they will,
             then why  aren't they used by all  printers?
Response:    Mr. Martin  responded that the use of magnets for
             this industry is a  completely new technology.
             Currently,  there are approximately 1,000 units in
             operation.   The technology was introduced to the
             industry  in April 1990.
Question:    How expensive are these  magnets as compared to the
             cost of a press?
Response:    The response was that  magnets cost about $3000 per
             press,  with a life  approximately  egual  to that of a
             press.  The cost of a  press is approximately $1.6 to
             2 million dollars.
Question:    What types  of modifications to the presses are
             necessary for retrofitting the magnets  to the press?
Response:    Mr. Martin  responded that it took about 10 minutes
             to  add  magnets  to one  press.   After the
             modification, press operators may need  to make
             adjustments to  the  process.  The  most significant
             adjustment  would be the  speed of  the water roller.
Question:    Is  there  anything in the draft CTG that would
             preclude  the use of these magnets?
Response:    There is  nothing in the  draft CTG indicating that
             the magnets are not an option of  control.  In fact,
             the quality of  the  process would  increase as a
             result  of using the magnets.   In  addition, alcohol
             substitutes would become more effective since water
             is  more soluble with the magnets.  Some users run
             the presses with magnets and an alcohol-free
             fountain  solution.
                                17

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2.3  WILSON CUNNINGHAM,  VICE PRESIDENT TECHNICAL RESEARCH,
     AMERICAN NEWSPAPER PUBLISHERS ASSOCIATION
2.3.1  Presentation Summary
    Mr. Wilson Cunningham for the American Newspaper Publishers
Association (ANPA)  gave a presentation to discuss ANPA's comments
on the draft CTG.   The ANPA is a trade association that
represents publishers of approximately 1350 newspapers.
Mr. Cunningham read from a prepared speech that is enclosed.
                               18

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2.3.2  Questions and Comments
Question:   What  is  the  content  of  ink pigments?
Response:   Mr. Cunningham  responded that black ink is mainly
            carbon black, and  all color newspaper pigments are
            complex  organic compounds.
Question:   In  reference to the  chart in the presentation
            showing  the  recommended ranges for fountain solution
            and cleaning solution usage,  as compared to those
            shown in the draft CTG,  the new calculated medians
            seem  to  fall within  the ranges reported in the draft
            CTG,  so  why  would  it be necessary to recalculate  the
            usage rates?
Response:   Mr. Cunningham  responded that while the medians fell
            within the ranges  given in the draft CTG,  the upper
            limits of those ranges  were too high.   In addition
            the ANPA would  prefer to be regulated based on real
            data  as  opposed to projected data.
Question:   Since there  is  such  a wide variation in the volatile
            percent  of inks, could  the volatile content be
            regulated to 10 percent or less?
Response:   The response was that inks are formulated to satisfy
            the consumer as well as regulations.   As rule of
            thumb, as the VOC  content increases,  the amount of
            rub off  decreases, so it is important to find a
            middle ground to allow  the least amount of rub off
            without  significantly increasing VOC content.  In
            general,  VOC content would not go down very much.
Comment:    The rule recommended by the draft CTG is not
            intended to  be  used  for the purpose of emission
            inventories.  Although  credit for waste ink and
            solvent  ink  used to  determine NSPS rules,  it is not
            pertinent to the draft  CTG.
                                19

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2.4  JAMES RENSON, COORDINATOR ENVIRONMENTAL AFFAIRS,  NATIONAL
     ASSOCIATION OF PRINTING INK MANUFACTURERS
2.4.1  Presentation Summary
    Mr. James Renson, of the National Association of Printing
Ink Manufacturers (NAPIM),  gave a presentation on printing inks
as related to the draft CTG.  NAPIM is a national trade
association representing small, medium and large printing ink
manufacturers in the United States.  There are 80 members in this
association accounting for approximately 90 percent of the total
U.S. sales of printing ink.  Mr. Renson read from a prepared
speech that is enclosed.
                                20

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2.4.2  Questions and Comments
Question:    Where  are  no-rub inks  used?
Response:    The  oils in  inks are absorbed leaving carbon black
             on the top of  the substrate.   A no-rub ink has more
             resin,  but also  has higher VOC content.   Some
             examples of  printers using no-rub ink are Time and
             Newsweek magazines.
Question:    Is "Method 30" an EPA  method?
Response:    Mr.  Renson said  that "Method  30" is  a California Bay
             Area Air Quality Management District (BAAQMD)  test
             method.  There is an ATSM  method for EPA Method 24,
             and  there  will soon be an  ATSM Method for BAAQMD
             Method  30.
                               21

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2.5  ENVIRONMENTAL CONSERVATION BOARD (ECB) OF THE GRAPHIC
     COMMUNICATIONS INDUSTRIES
2.5.1  Gerald Bender, Vice President Environmental Affairs,
       R.R. Donnelley & Sons Company; Web Segment
    2.5.1.1  Presentation Summary.  Mr. Bender began his
presentation with a discussion on the sources of VOC's.  The
three sources of VOC are:  ink oil solvents, fountain solution
additives, and cleaning solvents.  Ink oil solvents were not
originally considered VOC's, but when the definition of VOC was
changed, the ink oils fell into the category of VOC's.  These
oils can be compared to No. 2 fuel oil.  The need for fountain
solution as well as the amount depends on the equipment.
Cleaning solutions include blanket wash, auto blanket wash,
roller wash, and other miscellaneous cleaning, such as equipment
cleaners, plate cleaners, etc.
    To explain the concept of blanket-to-blanket printing, a
schematic of the unit was presented (see attachment).  Ink and
fountain solution are applied to a large cylinder called a print
plate.  The image is formed on the print plate and transferred to
the blanket cylinder, and then the final image is printed on the
substrate.  The system shown in the schematic is called a
blanket-to-blanket unit because it prints both sides of the
substrate at the same time.
    There are many types of applicators for fountain solutions,
each one requiring a different need for alcohol or alcohol
substitutes.  The first type of applicator is the continuous
dampening system.  Fountain solution is contained in a shallow
pan and, as shown on the schematic for the continuous dampening
system, there are rollers that pick up the solution and carry it
to the rest of the unit.  In some cases, brushes or spray nozzles
are used in place of rollers to transfer solution to the plate
cylinder.  In this case, alcohol substitutes may be used in
concentrations of about 0.5 to 1 percent, but only to keep the
blanket cylinder free from debris, not for high quality printing.
    This schematic shows a blanket-to-blanket web offset press.
For a four-color press, there would be four sequential units
                                22

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followed by a dryer.  Drying does not occur between colors as
with rotogravure printing.
    A continuous dampening system requires at least 3 to
4 percent alcohol in the fountain solution for good quality.  The
ECB is asking that the level of alcohol allowed be increased to
5 percent to allow a margin for error.  Small printers cannot
afford to not use alcohol.  They need a little more latitude to
add alcohol or alcohol substitutes to make the chemistry work.
    Mr. Bender remarked that since the document deals with
existing operations, printers cannot afford to redesign their
presses to operate with less alcohol.  Alcohol not only cleans
the print plate, but it also changes the rheology properties of
the water (i.e. lowers the surface tension of the water).  Small
variations in the amount of alcohol alter the viscosity of the
water, and therefore change the rate at which the solution is
transferred to the plate.  Older presses cannot speed up their
fountain rollers to accommodate the reduction in alcohol.
    Mr. Bender addressed the control options next.  The three
types of controls are condenser filters, condenser filters with
activated carbon, and incinerators (both catalytic and thermal).
A recommended control level in terms of percent reduction for
condenser filters does not make sense because condenser filters
operate best when the loading is very high.  The ECB suggested
that a concentration limit should be set on the exhaust stream
instead of a percent reduction.
    Condenser filters with carbon work very well in removing the
condensed oils from the dryer exhaust, but the oils are almost
impossible to remove from the carbon.  According to Mr. Bender,
hot air and low pressure steam will not remove the condensed
oils.  Since most facilities do not have high pressure steam at
their convenience, this is not a viable option.  It was suggested
that this type of control was a misapplication of activated
carbon.
    The ECB reviewed the costs for the different control options
and found capital and annual cost to be slightly lower than
expected.   Not included in the cost analysis were costs for
                                23

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safety purges of the incinerator and replacement of the filter
material in the condenser filter.
    The next issue addressed by Mr. Bender was the model  rule in
Appendix D of the draft CTG.  The first topic was the
applicability section (section D.2) of the model rule.  The ECB
would like some guidance to the States as to the definition of a
major source; also, the States need information on how to apply
RACT to the industry.
      The ECB then suggested that the control level  (for  the
emissions standards section (D.4) of the draft CTG) should be 90
percent instead of 95 percent to give the printer some leniency
in operation.
    Mr. Bender suggested changes in the equipment standards
section of the draft CTG (section D.5).  The changes mainly
concerned raising the levels of the alcohol permitted in the
fountain solution.  Also, the States have required the exclusive
use of EPA Test Method 25 to test heatset dryer emissions.  This
test, however, is not repeatable and therefore not a reliable
test method for this industry.
    The rest of the suggested changes for the draft CTG concern
rhetoric and are attached following this summary.
2.5.2  William Schaeffer, Consultant to Graphics Arts Technical
       Foundation (GATF), Chairman of the Technical Committee
    2.5.2.1  Presentation.  Mr. Schaeffer read from a prepared
speech that is enclosed.
2.5.3  C. Wm. Schneidereith, Jr., President, Schneidereith
       & Sons, Inc.; Sheet-fed Industry Segment
    2.5.3.1 Presentation.  Schneidereith & Sons, Inc. is  a
commercial printing facility that operates 20 printing units in
its sheet-fed, offset lithographic facility.  Mr. Schneidereith
read from a prepared speech that is enclosed.
                                24

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2.5.4  Questions and Comments
Question:   An  alternative  concentration requirement may work
            with  incinerators,  but would it work with condenser
            filters?   Couldn't  the air flow from the dryers be
            increased  to  dilute the exhaust and, hence,  lower
            the concentration of VOC's measures, without any
            real  decrease in emissions?
Response:   There is a high concentration of VOC's in the dryer.
            Increasing the  air  flow is not a good idea,  since
            the air leaving should be at the saturation  level or
            dew point.  This option will be researched further.
Question:   Were  there any  numbers to support the claim  that as
            VOC concentration decreases, solid waste increases?
Response:   Waste is generated  during changeover and runs.
            There are  no  numbers at this time concerning the
            trade-off  between VOC's and solid waste.  Data is
            available  on  waste  incurred during various run
            parameters.   Less effective cleaners increase waste
            and decrease  safety.
Question:   During the three presentations, each speaker
            recommended a different limit on the percent alcohol
            allowed in the  fountain solution.  What are  the
            reasons for this discrepancy?
Response:   The different levels refer to different segments of
            the industry.
Question:   Is  taking  samples of batches of solution common for
            small or for  large  facilities?
Response:   Large shops have central fountain solution
            circulators,  smaller shops make 10 gallons at a
            time. Once the batch is made, it won't change.
Question:   Have  cleaning solutions of 30 percent VOC have been
            tried? Have  they been examined for quality?
Response:   These cleaners  have been tried and they do not work.
            The lower  the VOC content, the longer the drying
            time  and the  volume necessary for good cleaning is
            increased.  The press is also shut down during this

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            time, so  it would  shut  down  longer when cleaning
            with these lower VOC  cleaners.
Question:    Six tons  per year  of  cleaning solution emits
            5.13 tons of VOC,  corresponding to approximately
            84 percent VOC.  Is the residual VOC-free?  If so,
            what happens to the remaining 16 percent?   Are all
            the volatile materials  emitted?
Response:    Some of the remaining cleaning solution leaves the
            shop in the cleaning  rags, and the rest goes into
            the waste solution.
Question:    The model plants showed that the fountain solution
            for non-heatset web facilities emits  the largest
            amount of VOC's; another speaker indicated  that this
            was too large.  Is this true?
Response:    The emissions were indeed too high.
Question:    Do inks volatilize?
Response:    The inks  do not volatilize during the normal process
            until, in the case of heatset inks, they reach the
            dryer, where 80 percent is volatilized in the dryer.
Question:    Have you  had any experience  with the  magnet as a
            form of water conditioning?
Response:    GATF submitted surface  tension data comparing water
            with and  without magnets.  No difference was noted
            in the lab studies.
                                26

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nooirn
                   NATIONAL ASSOCIATION OF PRINTING INK MANUFACTURERS, INC.
                   47 Halstead Avenue, Harrison, New York 10528 / Phone: 914-835-5650
                                                  Fax:914-835-5988

                   JAMES H. SUTPHIN, Executive Director

                                   November  11, 1991

Mr. Bruce C. Jordan
Chair, National Air Pollution Control Techniques Advisory
Committee
Director, Emissions Standards Division  (MD-13) Office of Air
Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC  27711


Dear Mr. Jordan,

The purpose of this letter is to present comments on the draft
CTG for offset lithographic printing prepared for EPA by the
Radian Corp.  These comments are presented by the National
Association of Printing Ink Manufacturers, Inc. (NAPIM) on behalf
of the printing ink industry -

NAPIM

NAPIM is a national trade association representing small, medium
and large printing ink manufacturers in the U.S.  Its eighty
members account for nearly ninety percent of the total U.S. sales
of printing ink.  The printing ink industry is composed of 224
companies operating a total of 504 manufacturing facilities
according to the U.S. Census of Manufactures for the year 1987.
Total shipments of printing ink in the U.S. were over $2.7
billion in 1990.

NAPIM has been vitally concerned with the need to clarify the
definition of VOC which currently varies widely from state to
state.  We are also vitally concerned that the definition of VOC,
and the application of this definition to various types of
printing inks, be reasonable and fair to the printing and
converting industries in the U.S.

DEFINITION OF VOC

NAPIM is especially concerned with the proposed definition of VOC
emission from inks which are applied without the addition of heat
(so called no-heat inks).  These inks encompass newsink and other
no-heat web offset inks; forms inks for commercial business
forms, and sheet-fed ink normally used for high quality color
printing.  While NAPIM acknowledges that the use of the Method 24
oven test condition of 110 degrees C for one hour is appropriate
for determining VOC content of heatset inks which are dried
through the application of heat, we submit that the use of Method
24 is not appropriate to define the VOC content of lithographic
ink which is applied without heat as proposed in the draft CTG.

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We have attached a copy of a report prepared by a task force of
the National Printing Ink Research Institute (a subsidiary of
NAPIM) prepared for Radian Corp. to provide background on
measurement of VOC's for no-heat ink.  The data and information
given in this report show clearly that press temperatures for no-
heat inks do not exceed 40 degrees C and that these inks are
normally on the press for less than 20 minutes.  Therefore,
although the draft CTG applies a retention factor of 95 percent
for no-heat inks, the conditions specified for Method 24 are
fundamentally much too severe for inks which are applied without
heat.

In the draft CTG, Radian Corp. has quite properly proposed a
retention factor of 95 percent for no-heat ink.  In other words,
Radian has acknowledged that at least 95 percent of the VOC in
the applied ink remain in the ink on the substrate or are
absorbed into the substrate.  While this may appear to make
allowance for the excessively rigorous Method 24 procedure, NAPIM
believes that the proposed retention factor is readily subject to
change by the states in the preparation of their SIP's whereas
the method to determine VOC will be fixed by the CTG.

ALTERNATIVE METHOD FOR DETERMINING VOC

NAPIM would like to call attention to an oven test method
proposed by the California Air Resources Board for the Bay Area
Air Quality Management District to determine the VOC content of
no-heat ink.  This is known as Method 30 and will shortly_be
confirmed as an approved test method by ASTM.  Method 30 is
conducted at 40 degrees C for one hour and since press
temperatures do not exceed 40 degrees C, and since ink residence
time on press is less than 20 minutes, Method 30 will predict VOC
for no-heat ink with a comfortable margin of safety.  We urge the
NAPCTA Committee to recommend that EPA adopt Method 30 to measure
VOC content of no-heat lithographic inks.

TYPICAL VOC CONTENT

Under section 2.5.1 on page 2-8 an estimated VOC content for non-
heat set web inks is given as 30 percent.  NAPIM submits that this
reflects a "worse case" scenario since in actual practise ink oil
content in these types of ink is much lower.  Based upon
production figures and VOC determinations for the various types
of non-heatset web inks (black and colored newsinks, regular
offset newsinks, no-rub offset newsinks, forms inks, etc.) the
weighted average VOC is estimated at 10 percent.  In order to
reflect the true average VOC content for these inks, it is urged
that the average be changed from 30 percent to 10 percent.

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SUMMARY -

We ask that the foregoing comments be considered in the
Committee's evaluation of the draft CTG and urge that the
suggested change in the method used to determine VOC's in no-heat
ink be adopted.

We appreciate this opportunity to comment on the draft CTG and
would be pleased to answer any question which the Committee may
have.
                                       a H. Sutphin
                                   Executive Director
/dem
Jordan.jhs
cc: NAPCTA Committee
    NPIRI VOC Task Force

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     REPORT TO RADIAN CORPORATION ON VOC'S FOR NON-HEAT INKS

              FROM NAPIM/NPIRI  TASK FORCE ON VOC'S

                          MAY 29,  1991

                          INTRODUCTION
     The graphic arts industry and, in particular, the printing
ink industry (whom we represent)  are concerned about test methods
being used to control VOC emissions for lithographic inks that
are applied at ambient temperatures without heat.  Because of
this concern, NAPIM under its research affiliate NPIRI, formed an
industry Task Force on VOC so that its dialogue with the EPA and
other regulatory bodies would be based upon an industry consensus
and not on a company by company basis.

     Specifically, the Task Force is concerned about the use of
totally unrealistic conditions such as EPA Reference Method 24
(one hour at 110 degrees C) to determine the VOC emission for
inks such as newsinks, forms inks, and sheetfed inks that are not
heated during application.

     Newsinks, forms inks and sheetfed inks contain light
distillate oils that have minimum initial boiling points of 480
to 540 degrees F, and which are essentially non-volatile under
ambient conditions.  Based upon VOC emissions measured at
production newspaper presses and temperature measurements made
for these same news presses and sheetfed presses, the Task Force
submits that an oven test such as Method 30 (one hour at 40
degrees C) more than adequately measures the emissions that may
be expected from these inks.

                        PRESS  TEMPERATURES

     Newspaper Presses - The American Newspaper Publishers
Associations (ANPA) Reston, VA measured temperatures of newspaper
presses at four operating newspapers in the greater Washington
B.C. area (see Table I).  There was virtually no difference in
temperatures taken in the summer and winter time at the same
presses.  Maximum temperatures varied between 30 and 43 degrees C
for continuous operation.  The maximum temperature of 43 degrees
C was achieved for a Mark II Letterpress which is not used for
lithographic ink.  The average maximum for all presses was 36
degrees C.  It seems clear that an oven emissions test of 40
degrees C for one hour more than adequately covers emissions from
newspaper presses since ink residence time on the press roller
train is estimated as less than 20 minutes.

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                              - 2 -
     Sheetfed Presses  - The NAPIM Task Force determined the
temperatures of five production sheetfed presses covering rates
of 4,000 to 9,000 Impressions Per Hour (IPH).  Data are shown in
Table II.  Maximum temperatures of 100 degrees F or 38 degrees C
occurred at the form roller and the delivery location.  In one
instance, a temperature of 110 degrees F (43 degrees C) was
recorded for a press having an Infra-Red heater at the delivery
point.  As is the case for newspaper presses, an oven emissions
test conducted at 40 degrees C for one hour will measure sheetfed
press emissions more than adequately.  Ink residence time in a
sheetfed 'press is also estimated at less than 20 minutes.

                            TGA TESTS

     In an effort to obtain more precise and more meaningful VOC
data, the NPIRI Task Force contracted with the John Brown
Laboratories, Stirling, N.J., to conduct Thermogravimetric
Analyzer (TGA) tests for magenta quick-set sheetfed ink, and a
black no-rub news (black) ink.  These inks were selected because
they contain the highest concentrations of light distillate oils
of all non-heat lithographic inks.

     The tests were conducted with thin films of ink on aluminum
substrates.  Tests using paper as a substrate showed interference
from water vapor which could not be accurately accounted for.
However, an impervious substrate such as aluminum can be expected
to give higher results because of the lack of absorption forces
that can be expected to be present with paper.

     TGA data for the sheetfed ink are shown in Figures 1, 2, and
3 attached.  The three curves represent heating rates of 0.25,
1.0 and 5.0 degrees C per minute respectively-  Note in each case
that there is no weight loss until a temperature of about 50
degrees C is reached, a temperature which exceeds maximum
temperatures measured for a sheetfed press.

     TGA data for the no rub newsink are shown in Figure 4.  VOC
weight loss at 41 degrees C (which exceeds the maximum average
press temperature by 5 degrees C)  is only 0.5%.

TGA/Oven Data A comparison of TGA and oven test data are shown
below:

                                      VOC, % Loss

                         TGA at 40
Ink                      Degrees C     Method 30    Method 24

Sheetfed                     0            1.8          14.8

No-Rub News                0.5            1.7          24.3

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                              - 3 -
     The above results show good agreement between TGA results, a
precise measuring instrument, and Method 30 oven data.  Method 24
data are considerably higher because of its unrealistically
higher temperature (110 degrees C).


                          EMISSION TESTS

     In addition to determining press temperatures, the ANPA also
measured VOC emissions around these same four newspaper presses
during actual production runs.  Data are shown in Table III.  The
maximum concentration determined was 68.3 mg/M .  Inspection of
the GC trace revealed a high concentration of Cg and C-j^
hydrocarbons which undoubtedly came from wash solvent used on the
press.  When inks obtained from the various press runs were
analyzed using an OHSA approved device to collect VOC's, the high
proportion of Cg and C-^ compounds were no longer observed.

     To study emissions under more carefully controlled
conditions, ANPA conducted tests at its press facilities using
inks supplied by NPIRI Task Force members having three different
VOC contents.  Emissions data are shown in Table IV.  Emissions
during the controlled runs were about one-tenth of those measured
during production runs.  During the controlled runs a concerted
effort was made to minimize the effect of wash solvents, which
contributed to the lower emissions observed.  Since emission were
all low, it was difficult to find significant differences among
the various inks.  The low rub and no rub inks, which would be
expected to have higher emissions, did have slightly higher
emissions as a class, than the regular black ink.  However, all
inks were very low in emissions generated.
/dem
radian.jtd

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                                              TABLI5  I
                                                                             Winter

                                                                                     Blanket Cylinde
Circulation     Press Type      Min  Max  High      Min  Max  High     Min Max High        M.JIL

Press Type
i
Urbanite
Metro
TKS
Mark II*
Summer
Form Roller Blanket Cylinder Form Nolle
Min Max High Min Max High Min Max Hl<
24 31 36 n/a n/a n/a 25 30 30
28 34 39 37 36 42 28 34 42
28 32 38 29 36 40 25 36 36
32 43 43 n/a n/a n/a 33 38 44
 37,000         Urbanite        24   31   36        n/a n/a n/a      25  30  30         n/a n/a  n/a

375,000         Metro           28   34   39        37   36  42        28  34  42        ' 29  37   4J

717,000         TKS             28   32   38        29   36  40        25  36  36         28  40   40

717,000         Mark  II*        32   43   43        n/a n/a n/a      33  38  44         n/a n/a  n/a


Min = Minimum Observed  Running  Temperature
Max s Maximum Observed  Running  Temperatuare
High = Highest  Temperature  Observed After  pressn Was Stopped
* Letterpress

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                             TABLE JI                                    -Inly. I Ort!.


                    sTPign PRESS TEMPISHATURKS


RRESS                 MIEIIM:, <1C    MIEIII.E, 4C    MlElll.lt. 4C    HARRIS. 6C   KOMORI 6C
                         16"          31"          .||"          25"          .,n" '


SPEED, IPH

ROOM TEMPERATURE. "F

INK FOUNTAIN, °F

WATER FOUNTAIN, °F

INK TRAIN ROLLERS, °F

FORM ROLLER, "F

PRINTING PLATE, °F

DELIVERY




IRUN1T                    NO         vns         vns          MO          Yns


RAYTGK RAYNGER IK I'lSTOI. TIII-RMOMI-TI-R. M.ulcl «U-380 - ..su.l lo ol.lain ..hovc ,|.,|.,.
>MOO
70 (26°C)
8f) (31°C)
M
90 (32'C)
100 (38°c)
HII
90
7800
90
90
50
90
90
H8
100
5300
88
90
50
90
100
90
90
•II MX)
711
80
55
90
SO
.SI)
75
9IXV)
70
100
_.
98
9H
85
110

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                          TABLE III
            VOLATILE EMISSIONS FOR FOUR NEWSPAPERS
                 DURING PRODUCTION OPERATIONS
Circulation

37,000

37,000

375,000

717,000

717,000

717,000

717,000

*Letterpress
                        Press Type

                       Goss Urbanite



                        Goss Metro
                                           Emission,
                        TKS

                        Goss,  Mark II*

                       Primarily  Cg - C

                           TABLE IV

VOLATILE EMISSIONS DURING CONTROLLED PRODUCTION RUN-^- (mq/M^)
                                           52.6

                                           43.0

                                           68.3

                                           42.8

                                           40.5

                                           19.8

                                           25.8

                                         hydrocarbons
Sample
Location
Right Ink
Form Roller
Left Ink
Form Roller
Pipe Roller
Regular
Black
3.1

3.7
0.6
Ink Type
Low Rub
Black
5.0

5.2
5.7
No Rub
Black
2.6

3.2
1.1
'
  Limited wash solvent

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                             TABLE V
                      VAPOR PRESSURE, mm Eg
                         Rule 66        L.D.O.
Temp.  F ( C)            Min. Sp.       540 IBP

  68 (20)                  5.6           0.01
 100 (38)                 12.5           0.03
 150 (66)                 37.0           0.18
 250 (121)                 200           3.0
 350 (177)                 740           26.0
Distillation
Range  F

    IBP                    320           538
    50%                    350           554
    FBP                    380           599

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                                                  .gure  1
                                     TGA Test Quick Set  Sheet Fed Ink
   2.5-
   2.3-
    2.1-
O>
6
•H
(U
*   1.9-
    1.7H
     1.5-
                        50
100             150
 Jemperature  (°C)
200
250

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                                                  Figure 2


                                     TGA Test Quick  Set Sheet  Fed  Ink
    3.B-
    3.6H
en
en
•i-t
QJ
    3.2H
    2.BH
    2.6H
    2.4
                                                    )
                        r
                       50
                                       100


                                       :, Temperature  (°C)
150
                        **?
                                2UO

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                                            Figure  3


                                TGA Test  Quick  Set  Sheet Fed Ink
    2.On
o»
e
r.
01
rH
cu
    l.BH
    1.2-f-
 r
50
100

^Temperature
                                                          T -

                                                        150
                                                 200
                                                      (°C)
                                                                                         250

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    1.2-
    1.0-
    O.B-
01

E
r\


OJ
    0.6-
     0.4-
     0.2
                  I •
                    .'25
r /
I- /
                                               Figure  4



                                       TGA Test No  Rub News Ink
                            -, I A rrrv < v^
                            -    '
                                                                      j c /o   
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                        WOOD FURNITURE COATING CTG
                      STATUS REPORT TO THE COMMITTEE
                        ON REGULATORY DEVELOPMENT
      Seven presentations were made to the Committee concerning the wood furniture coating
CTG: one by EPA, four by coating and equipment  manufacturers, and  two by  industry
representatives.   The key points  of each presentation and the discussions that followed are
summarized below, accompanied by the handouts prepared by the presenters.

1.    EPA PRESENTATION

      The EPA presentation was made by:

                                Ms. Mary-Jo Caldwell
                              Midwest Research Institute

      Ms. Caldwell summarized the status of the wood furniture coating CTG project. A copy
of the presentation is attached.

      A total of eight SIC codes, covering five industry segments,  were considered in the
analysis.    The  five  industry segments   considered  included  residential wood  furniture
manufacturers, cabinet manufacturers, office furniture manufacturers, institutional furniture
manufacturers, and store fixture manufacturers. These  five industry segments are referred to
as "the wood  furniture industry".

      Based on Census of Manufacturers' data, approximately 11,000 facilities fall into the five
industry segments just mentioned.  The majority of the industry is  made  up  of  residential
furniture and cabinet manufacturers, each of which constitute  about 35 percent of the industry.
More than 90 percent of the 11,000 facilities are considered small, that is, have less than 100
employees.
      It is interesting to note, however, that although large facilities, (i.e., those with more
than 250 employees), constitute  only  three percent of the total number  of facilities, they
contribute  about one-third  of  the total VOC  emissions.   The wood furniture industry VOC
emissions are distributed approximately equally among the three sizes of facilities.  The wood
furniture industry is one of the largest uncontrolled stationary VOC sources.

      Residential furniture manufacturers generally assemble their pieces and then finish them.

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The remainder of the industry also does some prefinishing of unassembled pieces. Coatings are
usually spray applied. The residential furniture manufacturing industry generally uses manual
spraying, whereas the rest of the industry uses both manual and automatic spraying.  Flatline
coating methods such as curtain coating and rollcoating are not presently used extensively by this
industry.

      The finishing process may be a single or multi-step operation.   The coating  may be
manually or automatically spray applied in the spray booth. The piece then leaves the booth,
and may be wiped  before  entering  the flash area, where the faster  solvents are  allowed to
evaporate.  The piece may  then enter an oven, and after cooling, may be sanded, after which
subsequent coatings may be applied.

      The coatings presently  used by this industry  are  primarily solventborne coatings.
Residential furniture manufacturers generally use nitrocellulose lacquers,  which cure by solvent
evaporation. The remainder of the industry uses urea-formaldehyde and melamine-formaldehyde
acid-catalyzed coatings, as well as nitrocellulose lacquers.

      Based on information obtained from  wood furniture manufacturers, EPA estimated that
about 94 percent of the total VOC emissions result from finishing operations, with the remaining
6 percent being attributable to cleanup operations. Volatile organic compound emissions in the
finishing operation occur as a result of solvent evaporation in the spray booths, flash areas, and
ovens.  Cleanup VOC emissions result primarily from  application equipment cleanup, which
usually  occurs  in the spray booth.   Additional  cleanup  VOC emissions result from repair
operations, which also usually occur in the spray booth,  and miscellaneous cleanup operations,
which occur throughout the finishing area.

      In  order to evaluate potential control strategies, EPA had to develop model plants to
represent the wood furniture industry as a whole. The industry was broken down into two main
groups:  residential furniture manufacturers  and other.  Included in the  "other" category are
cabinet  manufacturers, office and  institutional  furniture manufacturers, and  store fixture
manufacturers.  This category is referred to as "office/cabinet", though institutional furniture and
store  fixture manufacturers are also  included in this category.

      The residential furniture manufacturing segment was further broken down into short and
long finishing sequence, and then by size. The majority of the office/cabinet segment  uses the
same finishing sequence, but this segment was broken down by manual and automatic spraying,
(since both application methods are used by this segment  of the industry),  and then by size.  Due
to the capital investment required for an automatic spray  application system, it was assumed that
small facilities would not use automatic spraying.

      For purposes of the analysis,  the size of the model plants was based on total annual VOC
emissions.  Total VOC emissions  of 50 tons per year (ton/yr) corresponds to the small model
plant, 225 ton/yr corresponds to the medium model plant, and 500 ton/yr corresponds to the
large  model plant.

      In  order to evaluate lower-VOC coating alternatives, finishing  sequences had  to be


                                       842

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developed for each of the model plants just discussed. The finishing sequences described during
the presentation are intended to represent typical finishing sequences.  Actual finishing sequences
may, and probably will, differ from those shown.

       The office/cabinet industry uses a finishing sequence that consists basically of application
of stain, sealer,  and topcoat.   Residential furniture manufacturers  using  a short finishing
sequence use essentially the same sequence, except they also apply washcoat  after stain, before
sealer.  Residential  furniture manufacturers using a long  finishing  sequence use the same
coatings as manufacturers using a short sequence, but the coatings are applied more frequently,
and additional coatings, including filler, wiping stain,  and highlight, may also be used.

       The relative VOC emissions from each of the finishing steps was presented.  Topcoat
application contributes from 35 to 40  percent of the total finishing VOC emissions.  Stain and
sealer both constitute about 25 to 30 percent of the total finishing VOC emissions.

       A  variety of factors were considered  in evaluating control methods, including:  the
control techniques available, the types of coatings and finishing sequence used, total VOC
emissions and the concentration of VOC's in the exhaust stream, the number and types of VOC's
present in the exhaust, and the total exhaust flowrate to  be  controlled.

       Based  on the evaluation of the applicability of various control methods,  two primary
control alternatives  were  considered for the finishing process.   The  control alternatives
considered included lower-VOC coatings,  add-on controls,  and a combination of  the  two
methods.  Though these control methods have limited use in this industry, they are not presently
widely  used in the wood furniture coating industry.

       The lower-VOC  coatings evaluated  include waterborne,  polyester,  and polyurethane
coatings.  The add-on controls evaluated include recuperative thermal incineration, regenerative
thermal incineration,  catalytic  incineration, and  combined adsorption/thermal  incineration.
Because the capital and operating costs of add-on controls  are a function of  the  flowrate
controlled,  add-on control vendors  indicated that exhaust  flow  reduction  is  an  essential
consideration when evaluating add-on  controls. Therefore, two exhaust flow reduction methods
were evaluated. These include spray booth recirculation, which involves recirculating a portion
of the spray booth exhaust back into the spray booth, and the air curtain system.  The air curtain
system uses an air curtain to separate  the worker from the VOC emissions.  The worker stands
outside the booth and  reaches through the air curtain to spray apply the coating  to the piece.
Since the worker is not inside the booth,  VOC levels do not have to be maintained below the
permissible exposure limit, and therefore, high exhaust flows are not required and thus, the
spray booth exhaust is significantly less than that of a comparable manual spray booth.

       Three  primary  control alternatives were considered for cleanup operations, including
work practice modifications, reformulation of cleanup materials, and the use of add-on  controls.
Work practice modifications may include the use of enclosed spray  gun cleaners  and  closed
containers for the  storage of  saturated  rags.   Cleanup material reformulation  may include
reformulating with lower-volatility solvents, or may involve the use of aqueous-based  cleaners.
The same add-on controls just described for finishing operations may also be used to control


                                        843

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 VOC emissions resulting from cleanup operations.

       The control alternatives  were evaluated for each model plant, then permutations of
 different controls being applied to different model plants were developed to form RACT options.
 Under a single RACT option, the same controls may not necessarily be applied to all model
 plants.  Therefore, the RACT option descriptors do not necessarily indicate the control strategy
 being applied to all model plants.

       A total of nine RACT options were developed.  Options 1 through 4 involve the use of
 lower-VOC coatings; RACT Options 6 through 9 involve the use of add-on controls; and RACT
 Option 5  involves the use of lower-VOC coatings in conjunction with add-on controls.

       RACT Option 1 is described as full waterborne.  Under this RACT option, office/cabinet
 manufacturers and residential furniture manufacturers using a short finishing sequence use full
 waterborne coating  systems which involve waterborne coatings  for each  of  the coating
 application steps.  The  majority of the  coating  suppliers and wood furniture manufacturers
 contacted indicated that full waterborne coating systems are not presently suitable for residential
 furniture  manufacturers using a long finishing  sequence.  Therefore, under RACT option 1,
 residential furniture manufacturers using a long finishing sequence were assumed to use hybrid
 waterborne coating systems.

       RACT Option 2 is described as hybrid waterborne. Under this RACT option, all plants
 use a hybrid waterborne  coating system consisting of waterborne sealer, topcoat, and highlight
 (as applicable), with conventional solventborne  coatings for the remaining coating steps.

       RACT Option 3 is described as poly ester/poly urethane.  Based on conversations with
 coating suppliers and  wood furniture manufacturers, it was assumed that a dust-free environment
 is required when applying polyester/polyurethane coatings, due to the difficulty in repairing these
 coatings.  Because of the capital investment required for a dust-free environment, it was assumed
 that  small facilities (that   is,  those with less than  100  employees)  would  not apply
 polyester/polyurethane coatings.  Therefore, under RACT option 3, it was assumed that small
 facilities would use hybrid waterborne coating systems, and all medium and large facilities use
 polyester/polyurethane sealer, topcoat, and filler (as applicable) in conjunction with conventional
 solventborne coatings for the remaining coating steps.

       RACT Option 4 is described as polyester/polyurethane with waterborne coatings. RACT
 option 4 is essentially the same as RACT option 3 except that office/cabinet manufacturers and
 residential furniture manufacturers using a short finishing sequence also use waterborne stain and
 washcoat, and residential furniture manufacturers using a long finishing sequence use waterborne
"highlight.

       RACT Option 5 is described  as hybrid waterborne in conjunction with add-on controls
 being used to  control VOC emissions from selected coating steps. Under this RACT option, all
 facilities use hybrid waterborne coating systems.  Due to the capital investment required for add-
 on controls, it was assumed that add-on controls are not used by facilities with less than 50
 employees. Thus, under RACT Option 5, at all facilities with more than  50 employees, it was


                                        844

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assumed that in addition to using hybrid waterborne coating systems, add-on controls are used
to control VOC emissions from stain and washcoat operations.

      RACT  Options  6  through  9 are different  combinations of the four add-on controls
previously discussed being used to control VOC emissions from all coating steps.  Again,
because of the capital investment required,  it was assumed that facilities with less than 50
employees do not use add-on controls.  Because exhaust flow reduction can significantly affect
the capital and operating costs associated with add-on controls, each of the four add-on RACT
options considered the use of add-on controls with and without spray booth recirculation and the
air curtain system.

       The emission reduction and cost associated with applying each of the nine RACT options
previously described to all wood furniture facilities located in ozone nonattainment areas were
evaluated.  The nationwide emission reduction; the nationwide control cost; and the associated
cost effectiveness, that is, the dollars per megagram of VOC emissions reduced, were presented.
For example, RACT Option 1 is described as full waterborne. If this RACT option is applied
to all wood furniture facilities located in ozone nonattainment areas, nationwide VOC emissions
would decrease by almost 95,000 megagrams per year, which represents a 72 percent reduction
over uncontrolled nationwide emissions.  The associated annualized cost to industry would be
about $229,000,000, with a corresponding cost effectiveness of about $2,400 per megagram of
VOC emissions reduced.

       EPA PRESENTATION DISCUSSION

       Following the EPA presentation, Mr. Brian  Taranto of the NAPCTAC asked if the
impact in  the EPA presentation represented just nonattainment areas.  Ms. Mary-Jo Caldwell
responded that this was the case.  Mr.  Taranto then inquired about what percentage of the
emissions  from the wood furniture coating industry are in nonattainment areas.  The project staff
were unable to provide that information and promised to provide it to Mr. Taranto at a later
time. (Mr. Taranto was later told that based on EPA's estimate of nationwide  VOC emissions
for the wood furniture industry, approximately one-third of the total wood furniture coating VOC
emissions  occur in non-attainment areas).

       Ms. Vivian Mclntire noted that  "small"  appeared  to be defined several different ways
throughout the presentation,  as  50 tons/year  of  VOC, 50 employees,  and less than 100
employees.  Ms.  Caldwell explained that the use of less than  100 employees was the Census of
Manufacturers definition.  Because this encompasses most of the industry, the EPA analysis had
to further subcategorize the plants to conduct a meaningful analysis.  The subcategories were
0-35, 36-50, and 51-100 employees.

       Ms. Deborah Sheiman asked for the basis of the decision that some control alternatives
are too expensive for plants employing 50 people or less.  Ms. Karen Catlett of EPA stated that
the cost effectiveness values (dollars per ton of VOC emissions reduced) were much higher for
facilities with less than  50  employees.  For  plants with  at least 50  employees, the cost
effectiveness values range from $500 to 8,000/ton, while for plants with less than 50 employees
the cost effectiveness values ranged from $6,000 to 9,600/ton. Mr. Jordan elaborated that it was


                                       845

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staff judgment that  the costs  are too high.   Ms.  Sheiman  then suggested that  the  line
distinguishing between cost effective and ineffective control may have been drawn in the wrong
place, that some of the plants with less than 50 employees may be able to afford add-on controls.
Ms. Catlett responded that EPA will look into this issue further.

       Mr. John  Pinkerton asked  if this industry is largely uncontrolled, which Ms. Catlett
confirmed. He then inquired about which MACT list the wood furniture coating industry is on
and what the  "best of the best" control is likely to be. Ms. Susan Wyatt replied that it is on the
4-year list. Ms.  Catlett further responded that there are very few controls being used by  this
industry and  that the MACT level of control has not been determined  yet.  Mr. Pinkerton
concluded with the recommendation that the CTG and NESHAP efforts be closely coordinated,
so that the industry is not affected twice by different levels of control.  Ms. Wyatt assured Mr.
Pinkerton that EPA is aware of this possibility, which is the reason the wood furniture coating
industry is on the 4-year list. Ms. Wyatt explained that in this way, the CTG and NESHAP can
be considered together,  and industry will have knowledge of both sets of requirements before
instituting a VOC control strategy.

       Mr. Donald Arkell noted that at this time,  the  MACT floor would appear to be no
control, because most of the industry is uncontrolled.  He asked if the implementation of the
CTG would have the effect of raising the MACT  floor for the NESHAP.  Ms. Wyatt stated  that
the CTG and  the NESHAP are on the same schedule, so the CTG will not be imposed first,  and
thus will not  represent baseline for MACT.  Mr.  Arkell further inquired how MACT would be
determined, if the floor is uncontrolled.  Ms.  Wyatt explained that  EPA  can evaluate control
options more stringent than the MACT floor.  Mr. Jordan  explained that  the MACT floor for
an uncontrolled industry is equal to the minimum control allowed by the  Clean Air Act.  The
EPA is required to set MACT as the maximum  achievable control level.  Mr. Berry of EPA
indicated that since the industry is presently uncontrolled, MACT can be  set at any level after
looking at the impacts of various options.

       Mr. Taranto asked if all of the RACT options are  equally  technically feasible.  Ms.
Catlett said that EPA believes  they are all technically feasible, and that this was one of the
reasons for analyzing the costs for  all of the RACT options.  Mr.  Jordan then  noted  that
technical feasibility means that it can be accomplished; however, it  does not necessarily mean
that performance  won't be affected.

       Ms. Mclntire then inquired if waterborne coatings provide acceptable quality finishes.
Mr. Berry stated  that the wood furniture coating industry has traditionally used nitrocellulose
coatings because the finishes are ideal for the industry because they are easy to repair and have
a high gloss.  According to Mr. Berry, under the current system, consumers do not have a voice
in the marketing decisions.   Mr. Berry said  that it  is  uncertain whether consumers  can
distinguish  between the gloss levels  associated with different finishes, and they would likely
prefer the durability of lower-VOC coatings.   Mr. Berry said that there is a tradeoff between
the workability of the coatings in the plant and the long term performance  of the coatings in the
home.

       Mr. William O'Sullivan noted that many state and local agencies define 25 tons/year as


                                       846

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a "major" source and recommended that EPA conduct an analysis on this basis as well as the
50 tons/year analysis already performed. Mr. O'Sullivan then suggested performing an analysis
of the cost for add-on controls being used to control only the coating steps that emit the majority
of the VOC (topcoat, sealer, stain), rather than for all coatings; this might help to improve the
cost effectiveness values. Ms. Caldwell of MRI noted that, in the EPA analysis, the 50-employee
category was equivalent to about 35 tons/year, close to the value that Mr. O'Sullivan suggested.
Ms. Sheiman interjected that it might be more reasonable  to define cutoffs  on  the basis of
emissions rather than employees.    Ms.  Caldwell went on to explain  that, for nationwide
impacts, it was necessary to use number of employees to classify the plants because that is how
the Census of Manufacturers information is organized.

       Mr. William Dennison emphasized the need for EPA to analyze cleaning emissions (both
spray gun cleaning and housekeeping), which are potentially a large source of VOC emissions.
Mr. Dennison indicated that in his experience in California, spray gun cleaning was a large area
of contention. The EPA staff responded that cleanup emissions will be addressed.

       Mr. Patrick Atkins wondered if EPA had investigated technologies used overseas. Ms.
Caldwell replied that they had looked  at European technologies such as polyester/polyurethane
coatings which  are  used  more  extensively overseas.  However,  furniture is manufactured
significantly differently in Europe,  with the pieces being flatter and more uniform, which lends
the process to some alternative controls.

       Ms.   Sheiman  inquired   about  public  health  issues  related   to  the   use  of
polyester/polyurethane coatings. Mr.  Jordan said that he believed EPA had looked into it and
that there were no risks.  Mr. Jordan stated that he would try to provide details at a later time.

       This concluded the questions from  the NAPCTAC members.  Questions were asked by
a member of the audience.  Mr.  Gerry Currier of Reliance asked if air recirculation and  air
curtains are  commercially available and, if so, where  they  can be obtained.   Ms.  Catlett
responded that air recirculation  is used in  other spray coating industries and to some extent in
furniture coating. Air curtain spray booths are under development and are currently being tested
on a  pilot line.  Ms. Catlett further  explained that  air curtains have been successfully used
commercially on other types of equipment, such as ovens, to contain VOC emissions.

       Mr.  Currier  asked  for  clarification  of Chapter 5 of the CTG document, which he
interpreted as utilizing a permanent a total enclosure incorporating the entire finishing room, not
the individual emission sources.  Ms.  Catlett replied  that he was correct.  The questioner then
asked if any such  enclosures are in use in the wood furniture coating industry.  Ms. Catlett
responded that the industry is largely uncontrolled and, therefore, there is no reason for facilities
to have total enclosures in place since they would merely exhaust to the atmosphere.
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2.    UNICARBR SYSTEM PRESENTATION

      The UNICARBR presentation was made by:

                                     Thayer West
                         Market Manager - UNICARBR System
                                    Union Carbide

      Mr. Thayer presented  a brief description  of how the UNICARBR System works, its
applications, and the VOC emissions reductions achieved (see attached handouts).  The system
substitutes CO2 for conventional solvents in coatings.  This substitution lowers the total VOC
content of the coatings. The CO2 primarily replaces the "fast" solvents and often replaces HAP
solvents. This system offers the additional benefit of often allowing the use of the same resins
currently in use. The coatings used by this system have a high solids content and can be applied
manually or automatically using electrostatic or nonelectrostatic and airless or air-assisted airless
methods.

      The UNICARBR System is currently available for nitrocellulose topcoats and sealers,
pigmented lacquers and enamels, and single component acrylics, polyesters, and urethanes.  A
two-component system is under development and may be available in 1992.

      The VOC reduction achieved by this system varies with the type of coating and final
product and ranges from about 40 to 75 percent.  When looking only at the HAP solvents used
in coatings, reduction of 50 to 85 percent may be achieved.

      The UNICARBR System is  operating commercially at Pennsylvania House, applying
topcoats to chairs. About a 70 percent reduction in VOC emissions from topcoat application has
been achieved, and the plant is achieving more coverage with the same volume of coatings.  A
demonstration system was used at Lehigh,  Marianna that reduced the  number of sealer coats
from four to two by achieving better film builds.  In-plant trials are being conducted at other
furniture manufacturers  and in other industries.  In Japan, the UNICARBR System is being
considered for its performance characteristics,  such as fine particle size and good appearance.

      According to Union Carbide, this system provides numerous advantages, as outlined in
the handouts. It is easy to retrofit because it can be installed at a rate of one line or spray booth
at a time.  Because the faster solvents are replaced with CO2, the majority of the VOC emissions
occur later in the finishing sequence, in the oven.  By moving the solvent emissions from the
booth to the oven, the UNICARBR System makes it easier to control emissions. Finally, Union
Carbide believes that this system has a relatively low investment cost.   It was not included in
EPA's analysis of RACT, and Union Carbide is willing to provide cost information to EPA.

      UNICARBR PRESENTATION DISCUSSION

      Mr. William Dennison asked if there are any size limitations to the technology or any
practical limitations due to cost.  Mr. West stated that it depends on the number of coating steps,
but he believes there  would be economic paybacks even for the plants emitting less than 50


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tons/year.  Mr. West indicated that they are working on making the system more affordable,
such as leasing arrangements.  Mr. Dennison inquired about the training requirements for the
equipment, in light of the high employee turnover typical at furniture plants. Mr. West stated
that the training required is minor.  Mr. Dennison also asked if the gun cleaning requirements
for the UNICARBR System are the same as for other guns; Mr.  West said that they are similar
to the cleaning requirements for airless guns.

      Mr. Ralph  Hise asked a series of  questions regarding how  the  CO2  and  paint are
combined and whether the vessel the coating is stored in is pressurized, and questioned the safety
of the highly pressurized system. Mr. West explained that the paint is not under pressure until
after it enters the spray equipment. The liquid CO2 (at 1,100 psi  and 88°F) is fed from standard
gas  cylinders  into  the  spray equipment.   Simultaneously, the paint is pumped  into the
UNICARBR spray apparatus and mixed with the CO2 at pressure.

      Ms. Mclntire inquired whether the UNICARBR System could be considered reasonably
available at this time, even though it seems there is still quite a bit of trial testing ongoing, and
two-component coatings are not expected to  be available until 1992.  Mr. West stated that it is
currently available for nitrocellulose topcoat and sealer and has been used at Pennsylvania House
for about one year. Mr.  West said that Union Carbide has been working on the UNICARBR
System for 4 to 5 years.

      Mr. Atkins noted that Pennsylvania House  apparently achieves  an increased transfer
efficiency with this equipment and asked if Mr.  West could explain why. Mr. West responded
that it was unclear why there is increased transfer  efficiency, it may be due to more careful
handling by the person  doing the coating or it may be inherent to the technology.

      Mr. Ralph Hise asked if the UNICARBR System paint is more viscous than conventional
paints when it hits  the part.  Mr. West replied that it is  more viscous.

3.    CLASSIC SYSTEMS. INC. PRESENTATION

      The presentation on the Classic Systems, Inc., technology was made by:

                                 Mr. David  Brookman
                                 Classic  Systems, Inc.
                                   Statesville, N.C.

      Mr. Brookman provided a description of the Classic Systems  CamBoothR, which is a
spray booth using low velocity air curtains to isolate the worker from the spray  emissions (see
attached handouts).  Traditional spray booths have an open front, so that  VOC's and overspray
are lost. To ensure worker exposure safety, high volumes of air are exhausted from the booth.
The volume of makeup air  to the booth is usually inadequate, resulting in a negative pressure
within the booth. This pressure differential results in (1) dust entering the booth and degrading
product quality and (2) a cold and drafty work place. There is also a high cost associated with
moving and heating the high volumes of air.
                                      849

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       The goal of the CamBoothR design is to minimize the air volumes being handled, thus
decreasing costs.  Attached to the CamBoothR is an enclosed flash tunnel. There are air curtains
at the entrance of the spray booth, the exit of the flash tunnel, and the entrance and exit of the
oven. These curtains prevent VOC emissions from escaping from these areas during the coating
operation.  These air curtains use recirculated air. The open side of the CamBoothR where the
workers stand, also has an air curtain of fresh filtered air (no recirculation) delivered at a rate
of about 600 feet/minute. The air curtains located in between the worker and the piece are kept
at a relatively low speed to reduce  worker arm fatigue.  It is also possible to add a heating
element to the air curtains near the worker in the winter, if desired.

       The CamboothR design uses a cascading air system, with exhaust from the oven supplying
the  flash tunnel and tunnel exhaust venting to the CamBoothR.   Within the CamBoothR, the air
is added  from the top of the booth at 50 feet/minute and withdrawn from vents at the bottom.
Mr. Brookman  speculated  that  this uniform,  low-velocity downdraft  may  help to  increase
transfer efficiency. The exhaust from the  CamBoothR can then be directed to an add-on control,
such as an incinerator. The exhaust from multiple CamBoothsR can be combined and directed
to a single add-on control device.

       Studies have been performed  by Classic Systems demonstrating that overspray deflecting
off a piece  towards  the worker is  contained by the curtain.   Mr.  Brookman's presentation
included pictures of studies in which smoke was introduced into the CamBoothR and the exhaust
system removed the smoke before it appeared outside the booth.

       Mr.  Brookman presented estimated  operating costs  (electricity, heating,  fuel,  and
incinerator)  for  a typical  spray  booth using 120,000 cubic feet per minute (ftVmin) and a
CamBoothR using 21,000 ft3/min. The total operating costs were about $992,000 for the typical
spray booth and about $145,000 for the CamBoothR.  The largest individual difference was in
the fuel cost for the incinerator.

       CLASSIC SYSTEMS PRESENTATION DISCUSSION

       There were no questions following the Classic Systems presentation.

4.     GRACO. INC. PRESENTATION

       The Graco presentation on transfer efficiency was made by:

                                    Mr. Steve Kish
                             Market Development  Manager
                                       Graco, Inc.

       Mr. Kish presented the results of a study of the transfer efficiencies of different types of
spray guns  (see attached handout). Most of the presentation is included in the handout and will
not be repeated here.

       Mr. Kish agrees with EPA that there are many factors influencing the transfer efficiency


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of a coating system.  The primary factor is operator spray technique (e.g., gun setup, proper
gun position,  proper spray speed, fan pattern adjustment,  cleaning).   However,  operator
technique cannot be controlled.  Therefore, Graco focused their study on the transfer efficiency
of just the application tool (i.e., the spray gun) rather than the entire system.  They tested six
spray  guns under controlled conditions and achieved transfer efficiencies ranging from 30 to 75
percent.  Only the electrostatic  methods achieved transfer efficiencies over 50 percent.  They
feel that the standard target used in this study is typical of what is coated by their customers.

       While admittedly looking at only part of a complex system, Mr. Kish believes that studies
of relative transfer efficiencies of spray guns can provide valuable information. More efficient
application tools will reduce the amount of paint used to finish a part, thus reducing the VOC
emissions.

       GRACO  INC. PRESENTATION DISCUSSION

       Mr. Taranto asked if Mr. Kish agreed with EPA's decision not to numerically define and
include transfer efficiency in the CTG. Mr. Kish stated that if you are looking at the transfer
efficiency of the total system, as EPA  does, then he agrees that it cannot be  quantified.
However, it is possible to look at the transfer efficiency of the application tool (i.e.,  the gun)
alone, as his presentation demonstrated.  Mr.  Dennison noted that if you isolate and evaluate
each  of  the parameters,  you  are not looking at reality, and Mr.  Kish agreed with this
observation.

5.     ENSR PRESENTATION

       The industry-sponsored presentation on the technical aspects of the study being conducted
by the industry group was made by:

                                  Mr. Robert Mclnnes
                            ENSR Consulting and Engineering

       Four trade associations for industries affected by the wood furniture coating CTG formed
a Joint Industries Steering Committee, which sponsored two studies of the cost and economic
impact of possible emission control scenarios.   The goal of the Committee and the  studies are
to assist  in developing  a CTG  that  is  environmentally protective,  technically  feasible,
economically justifiable, and does not restrict the industry.  The study is  not final yet, but will
be completed shortly.  The information in the attached handouts from the presentation will not
be reproduced here.   Instead, this discussion will present clarifying and additional statements
made by Mr. Mclnnes.

       The wood furniture industry is essentially a "fashion" industry,  in  that  it responds to
consumer demands.  In addition, wood is not a uniform substrate, such as metals. Both of these
factors increase the complexity of the manufacturing process and the analysis. A detailed survey
of 160 facilities and site visits  to  24  facilities  were performed, to  develop model plants and
determine the technical feasibility and economic impact of possible control options.
                                      851

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       Technical limitations of many control options that were noted include:

       1.     Wood is sensitive to heat and water.  Therefore,  control technologies cannot
             simply include changes to waterborne coatings and changes in oven temperature.

       2.     Full waterborne coatings are not in use for the "long-sequence" segment of the
             industry and are not available for some types of coatings.  In addition, there are
             quality problems.

       3.     Current coatings and colors have been developed over years of trial and error,
             developed  specifically for each plant and customer by onsite testing.   These
             coatings cannot be changed over night.  Customers  must be provided consistent
             quality. There may also be OSHA and insurance questions regarding the use of
             this technology.

       4.     Air  recirculation is used only in a  very small  number  of plants and is not
             applicable  to all industry segments.   There  may also be  OSHA and insurance
             questions regarding the use of this technology.

       5.     Air curtain systems are not commercially available.

       6.     The UNICARBR System is  not commercially available  for  all coatings, has
             technical problems delivering sufficient coating volumes, and requires longer
             drying times.

       7.     Mobile zone spray  booths and Terr-Aqua  UV/AO  oxidation are developing
             technologies that are not commercially available.

       Twelve model plants were developed to characterize the industry.  Ten parameters were
used to define  each model plant (see  handouts).   The cost  effectiveness of sixteen  control
technologies  were evaluated,  including add-on controls, different application  methods, and
reformulation of coatings (see handouts).  Mr. Mclnnes outlined problems with each of these
categories of control technologies (see handouts).  The cost analysis was performed for different
numbers of ovens and booths, which significantly affects  the cost effectiveness values.   The
model plants contained from five to fifteen booths per facility.  Capital cost, annual cost, and
cost effectiveness were calculated using OAQPS guidelines.

       The capital costs (per plant average  for the industry as a whole) varied widely for each
control category:  from $400 to $210,000 for spray techniques; from $98,000  to $1,030,000 for
reformulations; and from $163,000 to $1,026,000 per booth for add-on controls (see handouts).
The estimated annual operating costs for each control category ranged from:  a cost savings of
$51,000 to expenditures of $470,000  for  spray  techniques; a cost savings of $163,000 to
expenditures  of $1,222,000 for reformulations; and expenditure of from $68,000 to $321,000
per booth for add-on controls  (see handouts).  The cost savings occurred for only one of the
twelve model plants. The average annual operating cost for the remaining eleven model plants
was over $200,000.


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      The VOC emissions reductions achieved for the industry varied widely for each control
alternative, from 2 to 33 percent for improved  spray techniques, 28 to 80 percent for coating
reformulations, and 3 to 86 percent for add-on controls (see handouts). The cost effectiveness
values for each control category ranged from:  a cost savings of $2,100/ton to expenditures of
$9,400/ton for spray techniques; a cost savings of $500/ton to expenditures of $15,800/ton for
reformulations; and expenditures of $1,300 to $87,300/ton for add-on controls (see handouts).

      Mr. Mclnnes concluded his presentation with a discussion of several industry concerns
other than cost.   First, the industry recommends that the units of the standard not be in terms
of pounds of VOC per gallon of coating minus water.  The trend is towards using water in
coatings, and if water is deleted  from the calculation, there will still be high VOC levels. Use
of this format does not show the actual VOC reductions achieved by using waterborne coatings.
Second, because the wood furniture industry is so technically and economically diverse, there
should be different standards for different industry segments.  Finally, Mr. Mclnnes made the
strong recommendation that, if the CTG includes the use of some of the emerging technologies
(e.g., full waterborne coatings), EPA  needs  to  allow sufficient time  for research and
development of these technologies in the CTG.

6.    NERA PRESENTATION

      The industry-sponsored presentation on economic impacts of the CTG was made by:

                                  Dr. Mark Berkman
                        National Economic Research Associates

      The second study sponsored by the Joint Industries Steering Committee was an evaluation
of the economic impact of possible CTG control options on the wood furniture industry. The
Committee decided to conduct a study of the total industry impacts and to assume that the goal
of EPA is to reduce VOC emissions in nonattainment areas at the lowest possible industry cost.
This summary of the presentation will  not include a repetition  of  the  handouts, which are
attached.  Instead, statements made by Dr. Berkman to clarify and expand on the handouts will
be discussed.

       The study looked at total annual operating costs, plant closures, and employment losses.
These economic  factors  were studied as a  function of  increasing  percent VOC emissions
reduction, from  10 to 80 percent.  Over  this range of VOC control, total annual cost ranged
 from $53 to 543 million (see handout for details).

       The projected plant closures for this range of VOC closures ranged from 930 to 2,539
 (see handouts for details).  However, the economic analysis is not complete, and Dr. Berkman
 stated that the plant closure estimates will likely increase in the final report. The closings will
primarily occur among the smaller facilities.

       The number of jobs lost over the range of VOC reductions was  5,283 to 86,534 (see
 handouts for details). The largest number of job losses represents about 30 percent of the total
employment in this industry. The largest facilities in the wood furniture industry will probably


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not close as a result of a CTG but there would be sizeable employment losses.

       Dr. Berkman then presented a discussion of the cost of control to this industry relative
to its VOC emissions.  First, the wood furniture coatings contribute less than 1 percent of the
VOC emissions in the  U.S..  Second, the average cost effectiveness values for the wood
furniture industry is about $3,000/ton.  Dr. Berkman presented the results of a  study by the
Office of Technology Assessment demonstrating that there are numerous other industries with
cost effectiveness values at or below $2,000/ton. This is not to suggest that the wood furniture
industry should not be controlled but rather that it is not a major contributor of VOC emissions
and  should be controlled proportionately to its emissions.
       The study determined that there is a wide range of cost effectiveness values for each
control option for the different model plants. The lowest cost of attaining a 30 percent VOC
reduction ranges from a slight profit to about $15,000/ton for seven of the model plants. For
these reasons, Dr.  Berkman suggested that EPA  consider the cost impacts of the different
segments of the industry separately.

       The  NERA study  also analyzed  the  effect of different  VOC  control  options on
profitability for each of the model plants (see handouts for details).  The cost of VOC control
is difficult to pass along to the customers and, therefore, the CTG would significantly impact
profitability.  The model plants included as part of their initial analysis happened to all be part
of the upper profit quartile.  Therefore, to further analyze the impact of decreased profitability,
they are  adjusting their analysis to include smaller, less profitable model plants.

       The study further analyzed the annual failure rate in  this industry in the absence of any
regulations.   For the period 1986  to  1990, the failure rate of the wood  furniture industry
outstripped the nationwide  failure rate for  all other industries  combined  (see handouts for
details).  In part, this is due to substantial and growing  foreign competition,  which increased
from a value of about $1 billion in  1981 to almost $4 billion in 1990.  The impact  of the CTG
will be to increase the competitive advantage of foreign imports.

       The study also evaluated the impact of the  capital cost of the different levels of VOC
control.  If a plant is able to stay in business following the implementation of the CTG, the cost
of the control will limit the ability to upgrade,  modernize, and  expand the facility.   This
limitation will further decrease the competitiveness of this industry.

       Dr.  Berkman concluded with two  recommendations  to EPA in the development of the
CTG.  First, this industry appears  to be  a  prime candidate for a market-based approach to
regulation.  Second, EPA must review and regulate the industry in the context of its contribution
to total nationwide VOC emissions.

       ENSR/NERA PRESENTATION DISCUSSION

       Mr. Taranto asked if the projections  on plant closures and job losses are for all of the
industry  or only  the facilities in nonattainment areas.   Dr. Berkman replied that the study


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assumed all plants will be affected by the CTG. They are continuing their analysis and plan to
analyze the impacts on only those plants in nonattainment areas.  Dr. Berkman hypothesized that
although the closures and job losses may be decreased when only facilities in nonattainment
areas are considered, the decrease may be offset by (1) increased closures in nonattainment areas
because those facilities would be at an economic disadvantage compared to those in attainment
areas and (2) the increased stringency of some of the financial tests NERA plans to utilize.

      Ms. Mclntire asked whether the NERA study had included an analysis of the impact of
the application of MACT to plants emitting over 10 tons/year in attainment areas, to determine
whether facilities in attainment areas would have a cost advantage. Dr.  Berkman  replied that
this has not been explicitly addressed but that their analysis considers to some extent a combined
RACT/MACT.

      Ms. Mclntire asked why, in the NERA analysis, the use of full waterborne coatings and
ultraviolet (UV)-cured coatings does not eliminate VOC emissions. According to Mr. Mclnnes,
these coatings still contain some amount of VOC.  In addition, there is no UV-cured stain.
Therefore, only about 65 to 70 percent VOC emissions reduction is achieved using these coating
technologies.

       Mr. Dennison asked why UV air oxidation was considered an  emerging technology in
the ENSR study when this technology is an  accepted technology in the aerospace industry.  Mr.
Mclnnes responded that he was unaware of its use in the aerospace industry.  Their classification
of UV air oxidation as an  emerging technology  was based on the fact that  it has not been
demonstrated long term in the wood furniture coating industry; it is currently in use in only one
wood furniture facility.

       Mr. Dennison asked  whether the NERA analysis had considered what would happen
regarding  plant closures in the absence of any regulation,  whether this industry is currently
economically viable. According to Dr. Berkman, the NERA analysis addresses this issue in part
because it includes analysis of current economic conditions  and other factors beside the CTG.
Dr. Berkman agreed that the industry has been undergoing contraction and consolidation and that
a number of existing companies are operating in a negative financial status.  However, the
regulations will exacerbate the problems and confirm the closure of currently marginal facilities.
The final report will have benchmark closure projections as well as demonstrate the additional
effect of the CTG on plant closures.

       Mr. Dennison further noted that, while VOC emissions from wood furniture coating may
be a small percentage of the nationwide VOC emissions, the more important factor to consider
is the industry's percent VOC contribution in only nonattainment areas.  Dr. Berkman concurred
that if you look only at nonattainment areas, the percent VOC contribution of this industry may
increase somewhat.  However, Dr. Berkman said  that the cost to this industry may not be
proportional to the level of VOC emission  reduction achieved relative to other industries.  He
also indicated  that  the stringency of a standard should be proportional to its contribution and
economic impact.

       Mr. Pinkerton asked the EPA staff how economic factors will affect the MACT decisions


                                      855

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for the NESHAP. Ms. Wyatt responded that an economic analysis will be performed for control
options above the MACT floor and the results will be used in selecting options for MACT.

       Ms. Mclntire asked if the NERA analysis was new to EPA.  Ms. Wyatt stated that EPA
knew an analysis was  being  performed but  had not seen any  of the results prior to the
NAPCTAC presentation.

       Mr. O'Sullivan asked what the current dollar value of U.S. sales is for this industry. Dr.
Berkman responded that their study does not directly have this information but that there were
about $4 million in foreign sales in 1990, which is about 15 percent of total U.S.  sales.

       Mr. O'Sullivan further inquired whether the NERA analysis assumed control of all of the
spray booths at a facility.  Mr. O'Sullivan recommended to EPA that they look  at this type of
incremental analysis to develop cutoffs on what types of control technologies should be required
for each type of facility. Dr. Berkman  explained that the NERA study looked at varying levels
of control at a facility, from 10 percent to over 80 percent. If add-on control was the least cost
option for a particular control level, that was the cost used to calculate cost effectiveness. These
different levels of control could be achieved by incrementally controlling different numbers of
spray booths.  Mr. Berkman said that this will be made clear in the final report.

       Mr. O'Sullivan stated that,  from the NERA study, it looked as if there were some clear
decision points for EPA to control at  about the 25, 50, and 75 percent control levels.  He asked
if industry  had any recommendations.   Dr.  Berkman responded  that they  did not  have
recommendations at  this time.  When the report is final, which should be soon,  the industry
plans to work with EPA to analyze the study results.

       Mr.  O'Sullivan  asked  how it can be  feasible to  get promising control technologies
demonstrated in an industry that is essentially uncontrolled. Mr. McGinnis responded that the
industry is currently  trying to use waterborne coatings on several lines.  The industry is always
looking for better and less expensive technologies.  Mr.  O'Sullivan noted  that the state
implementation plans (SIPs) must have a contingency plan in case the state fails to meet  its
emission reduction goals within a specified time.  If the goals are not met, it  triggers the
requirement for add-on controls. It may be possible to use the "hammer" provisions to provide
incentive to this industry to try new  technologies.  He asked how long it takes to  make a new
technology commercially viable.  Mr. Mclnnes estimated that it takes 2 to 4 years to test and
implement new approaches.

       Mr. O'Sullivan asked what NERA would recommend as a cost effectiveness cutoff. Mr.
Mclnnes declined to make  a recommendation.  He noted that the model plants  reflect a wide
range of cost effectiveness values, and that the total amount of VOC emitted from a spray booth
is the primary cost factor.  Booths are  fairly standard in size, and the speed of production is a
key factor, influencing how much VOC is emitted, and  thus, the associated cost effectiveness
of add-on controls.  Mr. O'Sullivan asked if the NERA report included the incremental cost  for
adding add-on controls to a spray booth, to which Mr. Mclnnes replied in the affirmative.

       Mr. O'Sullivan asked if EPA had any policy or thoughts on the issue that had been raised


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several times regarding adjusting the VOC limits to subtract out water.  Mr.  Berry responded
that this was a complex issue and that EPA was aware of it. Mr. Berry said that there is some
problem with very low solids coatings; however, some parties tend to stretch this anomaly over
the full gamut of waterborne coatings, which is not appropriate.  Mr. Berry said that EPA will
be giving this issue further consideration in the development of the CTG.

      Mr. Pinkerton asked if industry has any concerns regarding the two on-going regulatory
tracks (i.e.., development  of RACT and MACT).  Mr.  Mclnnes responded  that industry
definitely would like to see the two developed in parallel, to avoid the problems of multiple and
differing   standards.    Mr. Pinkerton  concurred  that  this  would  be his  very  strong
recommendation.

      Mr. Jordan said  that he was  intrigued by the market-based controls concept briefly
discussed in the industry presentation, and indicated a desire to further discuss this concept in
the future.    Mr. Jordan asked when the NERA study would be completed. Industry responded
that they expect the study to be finished by the end of the year.

7.     MQBAY  CORPORATION PRESENTATION

       The Mobay presentation on polyester and polyurethane  coatings (which is attached) was
made by:

                                  Mr. John Williams
                             Director, Technical Marketing
                                     Mobay Corp.

       Mobay  supplies aliphatic and aromatic polyisocyanate resins  for use in polyurethane
coatings.   These coatings provide  greatly improved  performance (e.g., alcohol and mar
resistance), which will help with foreign competition. The CTG document contains a value of
about 3.4  Ib VOC/gallon for polyurethane coatings and, while this is technically achievable, it
is outside  the typical values. There are two-component solventborne polyurethane coatings for
clear topcoats  that contain 4.6  to 5.5 Ib VOC/gallon.   This represents  about a 23 percent
reduction  from nitrocellulose coatings.  In addition, the high film  build results in a reduced
number of coating applications.  The drawbacks to polyurethane coatings  are the need for (1)
a dust-free coating  environment and (2) worker training  in  the use of the two-component
equipment.

       Non-air inhibited unsaturated polyester coatings are high-gloss, high-build systems.  Clear
topcoats and sealers are commercially available and contain about 1.5 Ib VOC/gallon.  Use of
polyester coatings achieves about 40 to 75 percent VOC reduction for air dry and 88  to 97
percent reduction for ultraviolet (uv)-cure.   Overseas furniture  manufacturers are using these
coatings because of the improved performance. Development is continuing on other coatings.

       Work is ongoing to develop a two-component waterborne polyurethane topcoat and  sealer
containing about 0.9 Ib VOC/gallon.  It should be commercially available in  1 to 2 years.
                                     857

-------
       Customers have expressed some concern about worker health and safety because of the
polyisocyanates in these coatings.  Mobay has conducted extensive monitoring in plants using
polyisocyanates and has found no problems.

       Both the polyurethane and polyester  coatings are to some extent limited to certain
segments of the wood furniture industry.  Mobay supports the use of low-VOC technologies, but
only when combined with improved performance because of the need to increase competitiveness
of U.S. products.

       Mobay supplies  raw materials to coating manufacturers,  but  works closely  with the
coating suppliers and the coating buyers, such as wood furniture manufacturers,  to ensure the
end product satisfies all parties.  Mobay would like to work with EPA, a coating  supplier, and
a wood furniture facility to install and use these new technologies on a demonstration basis.

       Mr. James Berry, ESD/EPA, concluded this session by noting that the wood  furniture
industry has used nitrocellulose coatings for a long time. Polyurethane and polyester coatings
are relatively new to  the  wood furniture industry.   However,  he  suggested  that  industry
representatives look closely at this technology. Mr. Berry said that looking at all paint systems
being used everywhere on every conceivable  end-product, polyester/polyurethane coatings are
generally accepted as the premier coatings for durability, color retention, etc., and may be able
to achieve large VOC emissions reductions at a reasonable cost.  Wood furniture coating is the
largest uncontrolled single-industry VOC source remaining, and EPA  cannot just ignore these
emissions.

       MQBAY PRESENTATION DISCUSSION

  Mr. Atkins inquired about possible health problems associated with  using isocyanates.  Mr.
Williams responded that coatings with isocyanates can be used safely.  He said that all coatings
have some type of hazard, and general safe handling procedures are sufficient to protect workers
from isocyanates.

       Mr. Atkins also  asked if there are special costs associated  with the use and  monitoring
of a polyester or polyurethane coating system.  Mr. Williams acknowledged that  the two-
component coating system requires  two coating pots and a special  spray gun.  He noted,
however, that the equipment  is commonly available and used extensively by the military.

       Ms. Mclntire asked if the toxicity of the two-component coatings is higher than that of
solvents used in conventional coatings.  Ms.  Mclntire said that after  the permit program and
MACT standards are in place, it will be difficult to switch to more toxic coatings.  Mr. Atkins
replied that the solvents used in the two-component coatings are similar to those in conventional
coatings.

       Ms. Mclntire noted that RACT should genuinely be reasonably available.  There are a
number of developing control technologies for the wood furniture coating industry.  While it
may not be within the realm of the CTG process, the Clean Air Act Amendments clearly contain
mechanisms  for encouraging switching to new  technologies that probably are related to the

-------
economic incentive programs.  Incentives that might be offered are extended compliance times,
grants, and issuance of general permits during initial startup phase.

       Mr. Jordan read one question from the audience, which stated that there is at least one
dip tank in use in the industry and asked if EPA would require controls on such an activity.  Mr.
Berry responded that it would depend in part on the VOC content of the coatings and suggested
that the questioner talk to Mr. Berry after the meeting about the specifics of the situation.  Mr.
Jordan also read a comment from the audience, strongly recommending that any size cutoffs be
made in  terms of tons/year  of VOC, not number of employees,  since some companies
subcontract coating of parts and only assemble the finished parts.

       The session concluded with  one question from the audience, stating that the Joint
Industries Steering Committee was unaware of the new waterborne polyester coating discussed
in the Mobay presentation, or Mobay's offer to work with a plant to develop a system and
wondered why EPA had not informed the Committee prior to NAPCTAC. Mr. Berry responded
that  he had  informed Mr. Buck  Deal of Bernhardt (a member of the Joint  Committee)
immediately after hearing the Mobay information. Mr. Deal responded that given the timeframe
of this notice (a few weeks  before NAPCTAC), he did not feel that the Mobay presentation was
appropriate for the NAPCTAC meeting.
                                      859

-------
        CONTROL TECHNIQUES GUIDELINE
        CONTROL OF VOC EMISSIONS FROM
      WOOD FURNITURE COATING OPERATIONS
CO

-------
CD
CT5
                    INTRODUCTION


BACKGROUND

   • OVERVIEW OF WOOD FURNITURE INDUSTRY

   • EMISSION SOURCES


REGULATORY ANALYSIS

   • MODEL PLANTS

   • CONTROL ALTERNATIVES

   • RACT OPTIONS

   • IMPACTS

-------
              INDUSTRIES EVALUATED BY THE ANALYSIS

  SIC CODE    INDUSTRY

  RESIDENTIAL
    2511       WOOD HOUSEHOLD FURNITURE, EXCEPT UPHOLSTERED
    2512
    2519
to
    2517
WOOD HOUSEHOLD FURNITURE, UPHOLSTERED

HOUSEHOLD FURNITURE, NOT ELSEWHERE CLASSIFIED
  CABINETS
    2434       WOOD KITCHEN CABINETS
WOOD TELEVISION, RADIOS, PHONOGRAPH,  AND SEWING  MACHINE
CABINETS
  OFFICE
    2521
WOOD OFFICE FURNITURE
  INSTITUTIONAL
    2531       PUBLIC BUILDING AND RELATED FURNITURE

  FIXTURES
    2541       WOOD  OFFICE AND STORE FIXTURES, PARTITIONS,  SHELVING, AND
              LOCKERS

-------
                    DISTRIBUTION OF FACILITIES
                   BY INDUSTRY SEGMENT
                      APPROXIMATELY 11,000 FACILITIES TOTAL
           FIXTURES (17%)
CO
INSTITUTIONAL (5%)


     OFFICE (6%)
                                            CABINETS (34%)
            RESID. FURN. (37%)

-------
                 DISTRIBUTION OF FACILITIES BY SIZE
CD
                     LARGE (3%)
                MEDIUM (5%)
small 1 -99 employees

medium 100-249 employees

large >249 employees
                                      SMALL (92%)

-------
                                                    SMALL 1-99 EMPLOYEES
                                                    MEDIUM 100-249 EMPLOYEES
                                                    LARGE >249 EMPLOYEES
CD
O3
CJ1
LARGE (32%)
                                           SMALL (39%)
                  MEDIUM (28%)

-------
                               FINISHING SCHEMATIC
CD
 Coating
Application
                                  Oven
 Coating
Application
                    Finishing Operations ~ 94% total VOC emissions
                    Cleanup Operations - 6% total VOC emissions

-------
                REGULATORY ANALYSIS
ONCE THE INDUSTRY AND FINISHING PROCESS WERE CHARACTERIZED,




THE REGULATORY ANALYSIS WAS CONDUCTED, CONSISTING OF:






   • DEVELOPMENT OF MODEL PLANTS




   • EVALUATION OF VOC CONTROL ALTERNATIVES




   • DEVELOPMENT OF RACT OPTIONS




   • IMPACT ANALYSIS

-------
                                     MODEL PLANTS
                Residential Furn.
CD
en
I medium} [ large [  j email |  [medium | | large
                                                                      medium I  I large
                                       Small 50 TRY
                                     Medium 225 TRY
                                       Large 500 TRY

-------
                    FINISHING SEQUENCES
OFFICE/CABINET  RESID. FURN. (SHORT)
STAIN           STAIN
STAIN

SEALER

TOPCOAT
STAIN

WASHCOAT

SEALER

TOPCOAT

TOPCOAT
RESID. FURN. (LONG)
    STAIN

    STAIN

    STAIN

    WASHCOAT

    FILLER

    WIPING STAIN/GLAZE

    SEALER

    TOPCOAT

    HIGHLIGHT

    TOPCOAT

    HIGHLIGHT

    TOPCOAT

-------
             RELATIVE VOC EMISSIONS-FINISHING STEPS
                           (PERCENT)
        TOPCOAT
       HIGHLIGHT
         SEALER
o
  WIPING S./GLAZE
          FILLER
      WASHCOAT
           STAIN

                               NOTE:
                               HIGHLIGHT,
                               WIPING S.,
                               & FILLER
                               USED ONLY
                               IN LONG
                               SEQUENCE.
                 0
10  15   20  25   30   35  40

-------
     PARAMETERS CONSIDERED DURING
       CONTROL METHOD EVALUATION
CONTROL TECHNIQUES AVAILABLE
TYPES OF COATINGS PRESENTLY USED
FINISHING SEQUENCE / INDUSTRY SEGMENT
TOTAL VOC EMISSIONS AND CONCENTRATION
NUMBER AND TYPES OF VOC'S PRESENT IN EXHAUST
EXHAUST FLOWRATE TO BE CONTROLLED

-------
             CONTROL ALTERNATIVES FOR THE
                     FINISHING PROCESS
       LOWER-VOC COATINGS
     • ADD-ON CONTROLS
S3
«vj
10              • RECUPERATIVE THERMAL INCINERATION
               • REGENERATIVE THERMAL INCINERATION
               • CATALYTIC INCINERATION
               • COMBINED ADSORPTION/THERMAL INCINERATION
       COMBINATION OF LOWER-VOC COATINGS AND ADD-ON CONTROLS
       EXHAUST FLOW REDUCTION IS ESSENTIAL FOR ADD-ON CONTROLS

               • RECIRCULATION
               • AIR CURTAIN SYSTEM

-------
       CONTROL ALTERNATIVES FOR
           CLEANUP OPERATIONS
WORK PRACTICE MODIFICATIONS TO MINIMIZE EVAPORATION
REFORMULATION OF CLEANUP MATERIALS
ADD-ON CONTROLS
ANALYSIS NOT COMPLETE

-------
            DEVELOPMENT OF RACT OPTIONS

     • CONTROL ALTERNATIVES EVALUATED FOR EACH MODEL PLANT

     • PERMUTATIONS OF DIFFERENT CONTROLS BEING APPLIED TO THE

     MODEL PLANTS WERE DEVELOPED TO FORM THE RACT OPTIONS
eo
^    • UNDER A SINGLE RACT OPTION, DIFFERENT CONTROLS MAY BE

     APPLIED TO DIFFERENT MODEL PLANTS

     • THUS, RACT OPTION DESCRIPTORS DO NOT NECESSARILY INDICATE

     THE CONTROL STRATEGY APPLIED TO ALL MODEL PLANTS

-------
                         RACT OPTIONS


  1.   FULL WATERBORNE



  2.   HYBRID WATERBORNE



  3.   POLYESTER/POL YURETHANE



5 4.   POLYESTER/POLYURETHANE WITH WATERBORNE
CJl


  5.   HYBRID WATERBORNE AND ADD-ON CONTROLS ON SELECTED STEPS



  6-9  ADD-ON CONTROLS FOR ALL COATING STEPS


                • WITHOUT RECIRCULATION


                • WITH RECIRCULATION


                • WITH AIR CURTAIN SYSTEM

-------
            RACT OPTION 1
          FULL WATERBORNE
O/C & RESIDENTIAL SHORT - FULL WATERBORNE
RESIDENTIAL LONG - HYBRID WATERBORNE

-------
                  RACT OPTION 2
               HYBRID WATERBORNE
S   • WATERBORNE SEALER, TOPCOAT, AND HIGHLIGHT (AS
-J


    APPLICABLE) FOR ALL PLANTS
      CONVENTIONAL SOLVENTBORNE FOR ALL OTHER STEPS

-------
                  RACT OPTION 3
            POLYESTER/POLYURETHANE
    • SMALL PLANTS USE HYBRID WATERBORNE
CD

    • POLYESTER/POLYURETHANE SEALER, TOPCOAT, AND FILLER

    (AS APPLICABLE) FOR ALL MEDIUM AND LARGE PLANTS


    • CONVENTIONAL SOLVENTBORNE FOR ALL OTHER STEPS

-------
CD
                RACT OPTION 4



   POLYESTER/POLYURETHANE WITH WATERBORNE






• SAME AS OPTION 3 EXCEPT:






• O/C & RESIDENTIAL SHORT - WATERBORNE STAIN AND




WASHCOAT (AS APPLICABLE)






• RESIDENTIAL LONG - WATERBORNE HIGHLIGHT, REST




CONVENTIONAL SOLVENTBORNE

-------
                    RACT OPTION 5

 HYBRID WATERBORNE & ADD-ON CONTROLS ON SELECTED STEPS
©3
CD
• HYBRID WATERBORNE COATING SYSTEMS (AS DESCRIBED

PREVIOUSLY) FOR ALL PLANTS


• ADD-ON CONTROLS USED ON STAIN OR STAIN AND WASHCOAT

OPERATIONS AT ALL FACILITIES WITH MORE THAN 50 EMPLOYEES

-------
                 RACT OPTIONS 6-9

    ADD-ON CONTROLS FOR ALL COATING STEPS
    • ALL FACILITIES WITH FEWER THAN 50 EMPLOYEES EXEMPT



S3
2   • FOR EACH RACT OPTION, ADD-ON CONTROLS EVALUATED:
r*=*                       '


      • WITHOUT RECIRCULATION OR AIR CURTAIN SYSTEM


      • WITH RECIRCULATION


      • WITH AIR CURTAIN SYSTEM

-------
      NATIONWIDE IMPACTS
FACILITIES IN OZONE NONATTAINMENT AREAS



€0
CO





RACT OPTION DESCRIPTION
1 FULL WATERBORNE
2 HYBRID WATERBORNE
3 POLYESTER/POLYURETHANE
4 POLYESTER/POLYURETHANE
HYBRID
5 HYBRID WATERBORNE & ADD-ON
6-9 ADD-ON CONTROLS
W/OUT RECIRCULATION
W/RECIRCULATION
W/AIR CURTAIN SYSTEM
NATIONWIDE
VOC EMISSION
REDUCTION
(1000 Mg/YR)
94.8
73.4
69.9
80.9
91.2

64.2
64.2
66.1

72
56
53
61
69

49
49
50
NATIONWIDE
ANNUAL
CONTROL COST
(MM$)
229
147
264
260
347

331-418
244-293
181-211
AVERAGE
COST
EFFECTIVENESS
($/Mg)
2400
2000
3800
3200
3800

5200-6500
3800-4600
2800-3200

-------
11/15/91
1-HTW
          UNICRRB  SYSTEM®

          NttPCTHC  MEETING

         NOUEMBER 21, 1991
                  o .

-------
    LDHflT IS THE UNICRRR® SYSTEM?
      THE UNICflRB® SYSTEM IS fl

  POLLUTION PREUENTION TECHNOLOGY

    FOR THE RPPLICflTION OF SPRRY

    RPPLIED  INDUSTRIRL CORTINGS
11/15/91
2-HTW              084

-------
   HOW DOES THE UNICRRB® SYSTEM
               WORK?
   THE UNICARB® SYSTEM SUBSTITUTES
CARBON DIOXIDE FOR A SIGNIFICANT
AMOUNT OF SOLVENTS IN CONVENTIONAL
SPRAY APPLIED COATINGS, THEREBY
REDUCING VOC'S AND AIR TOXICS.
   UNICARB® COATINGS ARE HIGH IN
SOLIDS, AND CAN BE APPLIED MANUALLY,
AUTOMATICALLY, ELECTROSTATICALLY,
NON-ELECTROSTATICALLY WITH AIRLESS
OR AIR-ASSISTED AIRLESS TYPE SPRAY
GUNS.
11/15/91
3-HTW             J385

-------
    WHERE IS THE UNICRRB® SYSTEM
  flPPLICRBLE IN THE WOOD FURNITURE
             INDUSTRY?
   NITROCELLULOSE TOPCORTS  RND
   SERLERS

   FOR:  RESIDENTIRL  FURNITURE
         CRRINETS
         OFFICE/INSTITUTIONRL

   PIGMENTED  LRCQUERS  RND  ENRMELS

   SINGLE COMPONENT  RCRVLICS,
   POLYESTERS  RND URETHRNES

   2 COMPONENT EQUIPMENT RND
   CORTINGS RRE CURRENTLY IN  THE
   DEUELOPMENTRL STRGE RND SHOULD
   BE RURILRBLE IN 1992 FOR IN-
   PLRNT TESTING
11/15/91
4-HTW

-------
  HOW MUCH CAN THE UNICARB® SYSTEM
            REDUCE VOC'S?
•  FOR NITROCELLULOSE SERLER flND
   TOPCORT RPPLICRTIONS 60%-75%

•  FOR THE MODEL PLRNTS LISTED IN
   TRDLE 4-4 OF THE CTG DRRFT, THE
   TOTRL FINISHING  LINE  UOC
   EMISSIONS WOULD BE REDUCED  BV:

FINISHING LINES   UOC'S RIR TOHICS

LONG FINISHING LINES    37%     50%
SHORT FINISHING LINES    44%     60%
OFFICE/CABINET        44%     50%

   THIS RSSUMES THE UNICRRB® SYSTEM
   IS  USED FOR  BOTH NITROCELLULOSE
   SERLER RND  TOPCORT RPPLICRTIONS
   RT R 65% REDUCTION OF UOC'S
   (4.7LB/GRL),  RND RIR TOHICS
   REDUCTION OF 857.

•  UNICRRB® SYSTEM  NITROCELLULOSE
   CORTINGS HRUE BEEN FORMULRTED
   UJITH.R 90%  REDUCTION IN RIR
   TOHICS
11/15/91
5-HTW
                G81

-------
  IS THE UNICARB® SYSTEM BEING USED
           COMMERCIALLY?
   THE SYSTEM HflS BEEN INSTflLLED
   RND IS OPERRTING COMMERCIRLLV
   RT PENNSVLURNIR  HOUSE
   fi SUCCESSFUL DEMONSTRRTION OF
   THE SYSTEM UJRS CONDUCTED RT
   LEHIGH
   SEUERRL OTHER FURNITURE
   MRNUFRCTURERS RRE CURRENTLY
   CONDUCTING IN-PLRNT TRIRLS IN
   UlRGINIfl,  MISSISSIPPI, CRLIFORNIR
   RND RRIZONR
   TRIRLS  RRE BEING CONDUCTED  IN
   SEUERRL OTHER INDUSTRIES
   INCLUDING:   RUTOMOTIUE OEM,
   RUTOMOTIUE  COMPONENT, PLRSTIC
   CRBINETS RND PLRSTIC RUTOMOTIUE
   COMPONENTS
11/15/91
6-HTW
                O O i

-------
            unlCRRB®  SVSTEM
 ADVANTAGES FOR SEALER AND TOPCOAT
              APPLICATIONS
1)  CONTINUED USE OF NITROCELLULOSE
    CORTINGS

2)  REDUCED UOC'S...65%-75% FOR SERLERS UNO
    TOPCORTS

3)  REDUCED RIR TOHICS...80%-90%

4)  EflSY TO RETROFIT

5)  RELRTIUELV LOW CRPITRL INUESTMENT

6)  HIGHER FILM BUILD

7)  POSSIBLE COST SRUIN6S WHERE MULTIPLE
    SERLERS OR TOPCORTS RRE RPPLIED

8)  COMPLIMENTRRV TO OTHER CORTIN6  SYSTEMS

9)  MOUES SOLUENT EMISSIONS FROM BOOTH TO
    OUEN

10) POLLUTION PREUENTION TECHNOLOGY
11/15/91
7-HTW

-------
                                                       i/M
                                       090
P.O. Box 6130 • Buffalo Shoals Rd. • Statesville, N.C.  28677 • Tel 704-878-9523/Fax 704-878-2914

-------
                                              November 21, 1991


         UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

              "Finishing Systems for Wood Furniture"

                      - Emerging Technology  -


 I.    Int roduct i on

      Classic Systems,  Inc. - Turnkey Contractor -
      primarily furniture  industry

      A.      Involvement  in new technology for
              control 1 ing VOC em i s s i o n s

      B.      CamBooth  - unique use of low velocity,
              push-pull air curtains to  isolate operator
              from unhealthy work environment and greatly
              reduce  exhaust air

II.    Background  for  Development -
      analysis of typical  problems  and complaints:

      A.      Inadequate capture of fumes and over-
              spray  in  typical  open front spray booths

      B.      Inadequate make-up air
              1.       Negative  pressure  in  finishing  room -
                       infiltration  of dust  degrades quality
                       of end product
              2.       Cold and  drafty work  place  in winter
              3.       High operating costs

      C.      Pending VOC  reduction requirements  -  high  initial
              and operating costs with present  large  volume
              exhaust  system

      Conclusion:      Most problems could be  resolved by  greatly
                       reducing  the  amount of  exhausted  air  from
                       the  work  space
                             esi

-------
III.     Review Transparencies

        A.       Typical  System - individual exhaust for oven,
                flash tunnel  and spray booths (open ends)

        B.       CamBooth System - one exhaust for all segments
                (closed  ends)

        C.       Views (front, plan and end)

        D.       Air flow patterns

        E.       Finishing Room - Typical
                1.       Exhaus t fan unit
                2.       Diverter dampers
                3.       VOC system tie-in

        F.       Energy cost comparisons (basic benefits)

 IV.     Slides

        A.       Various  views

        B.       Airflow patterns
                1.       Fron t a i r cur ta i n
                2.       End air curtain
                3.       Internal down draft

        C.       Demonstrate how worker is protected from
                internal environmental

  V-     Questions  and answers
                             G:

-------
                                       OVENOHAUST
                                    Q)
                                                                                                    FUSH TUK1DHAUST
                                                                                                                                               SMATBOOTH DWAUST
                                                                 CONVENTIONAL FINISHING SYSTEM LAYOUT
O
                                                                           OWN EXHAUST ROUTED TO FlAffl TIMCL
OVEN EXT
AIR CURTAH  i.
Lc.-;:;
                                                                                                                      JJU
                                                                                                       BOOTH OOW-ORAn FAN -i
                                                                                                    PU1MC ARFRCH FLASH XMC1 1
                                                                                                 FLAW TUML
                                                                                                  AD OJRTAM
                                                                                             OVENNIT
                                                                                             ABCURTAW
                                                               NEW CAMBOOTH  RNISHING SYSTEM  LAYOUT
                                                                                                                                                 CLASSIC  SYSTEMS. INC.
                                                                                                                                                          P.O. BOX «iao
                                                                                                                                           STATESVILLE. NORTH  CAROUNA 28677
                                                                                                                                                      1CLSPHONE TO4-«7B-eS23

-------
FLASH TUNNEL     \ I  /
 AIR  CURTAIN    C-
                                                   BOOTH EXHAUST FAN
                                BOOTH  DOW-DRAFT FAN
                                 PULLING AIR FROM FLASH TUNNEL
                                                                                                 AIR CURTAIN FAN AND FILTER
0
                                                                                          BOOTH OPERATOR OPENING
                                                                                               W/ AIR CURTAIN
                                                                                    WATERPAN OR DRY MEDIA FILTER SYSTEM
                                           FIASH TUNNa
                                                                                                 SPRAYBOOTH
                                                                                                                                      FTT  BOOTH INLET
                                                                                                                AIR  CURTAIN
                                                              FRONT  ELEVATION
                                                                                                                                               CLASSIC^SYSTEMS. ma
                                                                                                                                          STATESV1LLE, KORn? CAROLINA 88*77

-------
CJ1
       FLASH  TUNNEL
         AIR CURTAIN
                                                                                            BOOTH  EXHAUST FAN
                                                 -BOOTH DOWN-DRAFT FAN
                                                   PULLING AIR FROM FLASH  TUNNEL
                                                                                  PLAN VIEW
                                                                                                              LIGHTS
                                                                                                            AIR PLENUM
                                                                                                       AIR CURTAIN FAN AND FILTER
                                                                                                                                          BOOTH INLET  AIR CURTAIN
                                                                                                                                                      CLASSIC SYSTEMS. INC.
                                                                                                                                                 STATESVOLE, NORTH CAROLINA Start
                                                                                                                                                         nunm m n ttn

-------
                      BOOTH DOWN-DRAFT FAN
                  PULLING AIR FROM FLASH TUNNEL
                        FLASH TUNNEL
                         AIR  CURTAIN
CD
                                   END ELEVATION AT FLASH TUNNEL
AIR PLENUM



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       BOOTH INLET
        AIR CURTAIN
                                                                                                                  • WATERPAN OR DRY MEDIA FILTER SYSTEM
                                                                                             END ELEVATION  AT SPRAYBOOTH
                                                                                                                                           CLASSIC SYSTEMS, INC.
                                                                                                                                       STATESVILLE. NORTI? CAROLINA 28077

-------
CO
                    AIR CURTAIN
                     FAN AND
                      FILTER
AIR PLENUM
 FILTERS FOR  OOWNORAFT AIR
                                       WATERPAN FILTER SYSTEM
AIR CURTAIN
 FAN AND
  FILTER
AIR PLENUM
 FILTERS FOR  DOWNORAFT AIR
                                                                                                                                     CART
                                                             DRY MEDIA FILTER  SYSTEM
                                                                 	  AIR CURTAIN AT 600 FPM

                                                                    •«=-  DOWNDRAFT AIR AT 50 FPM

                                                                 	>  FINISHING SPRAY FROM SPRAY GUN



                                                                INTERIOR VIEW OF FLOW  PATTERN
                                                                                      •FILTER
                                                                                                                                                   CLASSIC SYSTEMS, INC.
                                                                                                                                              STATESVUIZ mem CAROLINA eaerr

-------
                                    OVEN
O
O
                                             O
                                                      O
                                                                                     O
                                                                  UNLOAD
                                                                 LOAD
                    TYPICAL FINISHING SYSTEM
                                                                                             CLASSIC SYSTEMS, INC.
                                                                                         STATESVILLE. NClRTlf CAROLINA

-------
                     BOOTH EXHAUST
                        BOOTH EXHAUST
                                       REMOVABLE
                                        BALANCING
                                         DAMPER
CO
c z
                                                  ACCESS DOORS
        SPRAYBOOTH ROOF
  REMOVABLE
SPCOL SECTION
                                                       SPRAYBOOTH  EXHAUST FAN
                        SPRAYBOOTH ROOF
                                                                                                                                    CLASSIC SYSTEMS, INC,
                                                                                                                                STATB3VILLE, NORTH CAROLINA 20077

-------
EXHAUST TO ATMOSPHERE (CLOSED)
EXHAUST TO ATMOSPHERE (OPEN)
                                                TO INCINERATOR (OPEN)
                                               TO INCINERATOR (CLOSED)
                                                                                                                 ROOF
           FROM
         SPRAYBOOTH
           FROM
         SPRAYBOOTH
                              SPRAYBOOTH EXHAUST DIVERTER VALVE
                                                                                                                         CLASSIC SYSTEMS.  INC.
                                                                                                                    STATESVIUK NORTH CAROLINA 2MT7

-------
STACK
            	I BLOWER
        _rw
INCINERATOR       \-ABQRT DAMPER
              VOC INCINERATION SYSTEM
                                                     -O

                                                                         CLASSIC SYSTEMS, INC.
                                                                              PA KB (00
                                                                      STATGSVniK. NORTH CAROUNA 28877

-------
                                                       •NIRQY  COST  EVALUATION
                                                                                                                                 1900.000
         35
         30
         25
         20
         15
         10 -
   ANNUAL
 OPERATING
   COST IN
 THOUSANDS
OF DOLLARS
                                                               130.000
                                                               ^/Vy/Vy
                                             $22,000
5  -
                   $3,000
                                                         $8,000
                                                                                                                                            1125.000
                    MAKE-UP  AIR
                        HP
                                        SPRAYBOOTH
                                           HP
     FUEL FOR MAKE-UP AIR
GAS
STEAM
              BASIC ASSUMPTION:  A. (6)  EACH  CONVENTIONAL SPRAYBOOTH SYSTEM = 120.000 CFM
                                 (6)  EACH  CAMBOOTH SYSTEM                =  21.000 CFM
                               B. HEATING COST - 1  SHIR, 6 DAYS/WEEK,  18 WEKS/YEAR, AND AVERAGE SOT
                                                TEMPERATURE RISE: GAS 0 $5/MBTU PER HOUR
                                                                STEAM 0 $4/1OOOJ PER HOUR
                               C. HORSEPOWER COST  6 $300 PER HP/YR
                               D. THERMAL  OHDIZER - WITH HEAT RECOVERY. VOC FUEL VALVE INCLUDED.  2600 ANNUAL
                                                   OPERATING HOURS
VOC INCINERATION
  FUEL  -  GAS
                                                                                                                    CONVENTIONAL SPRAYBOOTH  SYSTEM

                                                                                                                    CAMBOOTH SYSTEM
                                                                                                                                CLASSIC SYSTEMS. INC.
                                                                                                                           STATESVIUE. NORTH1 CAROLINA 28*77

-------
Saves Energy & Materials

80% Reduction in CFM
Requirements*

 • reduces energy costs

 • substantially less airflow to
   exhaust control devices

 • increases transfer efficiency
   of spray gun

•Compared to typical conventional
 designs.


Better Quality Production

Reduced Airflow Allows:

 • better operator control of
   coatings applications

 • greatly enhanced dust free
   environment for cleaner finish
      AIR CURTAIN
                              Safer Operation

                              Helps Meet New EPA and
                              OSHA Standards by:

                                • limiting operator exposure to
                                  VOC vapors

                                • lower decibel levels


                              CAMBOOTH Specfications

                              BASIC DESIGN:
                                down-draft with dry filters, air
                                curtains at operator station and
                                all entry and exit points.

                              DIMENSIONS:
                                Based on product size and
                                finishing schedule.

                              EXHAUST RATE:
                                3000 scfm per 20' booth.

                              HORSEPOWER:
                                3 HP per 20'booth.
                       The CAMBOOTH is
                       Adaptable*

                         • can be installed in present
                          booth location

                         • works with overhead or pallet-
                          type conveyor line

                         • can be equipped with the
                          following options:
                            — Flash Tunnel
                            — Drying Oven
                            — Catalytic or Thermal
                               Oxidizer
                            — Carbon Absorption Filter
                               Module

                         • can be supplied as water-
                          wash booth

                       *MODEL AVAILABLE FOR INSPECTION
                        AND PRODUCT TESTING
                                                              EXHAUST FAN
  General Office
Buffalo Shoals Road
   P.O. Box 6130
Statesville, N.C. 28677
 TEL: 800-362-5003
 FAX: 704/878-2914
                                          DRY FILTER MEDIA
                                       OR WATER FILTER SECTION
    SPRAY BOOTH-
                                          AIR CURTAIN
IT-.

-------
                              Introducing The All New
     GVMBOOIH
CLASSIC SYSTEMS, INC.
 Increased Efficiency In The
Manufacturing Environment
  Now in our fifteenth year,
Classic Systems is a company
dedicated to designing and
building products which solve
specific problems relating to
materials handling, and to EPA
and OSHA regulations.
  We currently operate from
2 North Carolina locations with
over 130 employees and annual
sales of more than $10 million.
We serve our customers nation-
wide with innovative solutions
in the following categories:
   • Dust Collection Systems
   • Finishing Systems
   • Fume Control
   • Materials Handling
      CLASSIC
                             from Classic Systems, Inc.
 The CAMBoom utilizes a
 unique Air Curtain design
 and offers the following:
 • Significantly Increased Efficiency
     • Environmental Safety
• Higher Quality Coatings Applications
       FOR USE AS A:
       • Spray Booth
     • Fume Control Device
     SYSTEMS
                            'Patent Pending

-------
GRACO COMMENTS REGARDING PROPOSED
CTG FOR THE WOOD INDUSTRY
Thank you  for the opportunity to present our
comments on the  proposed CTG for the wood
industry.  In  our presentation today, we will
address the issue of transfer efficiency as it
relates to the performance of the  paint
application device.

In reviewing the Draft Chapters 1  through  4
of the Control of  Volatile Organic  Compounds
from Wood Finishing Coating Operations, we
noted several references  to a  lack of a
standard transfer efficiency test.
Specifically, Pages 2--3G and 3--4S.
Basically, transfer  efficiency is
the amount of paint that actually lands on a
part, compared with  the total amount  of paint
being sprayed from the gun.
Our goal is to  maximize transfer
efficiency and minimize the amount of paint
used to paint a part.  Higher transfer
efficiency will result in lower paint usage,
fewer solvent emissions, reduced exposure  by
plant personnel to solvent fumes, less sludge
to  dispose of, and less maintenance and less
paint handling in  general.  This task is
complicated  by  the demands of  real world
production.
The  formula  that expresses  this relationship
is  as follows:
T.E.= Wp/%S x Q x T

-------
Where:

T.E.= Transfer efficiency

Wp= Weight of the paint solids deposited on
parts after baking

%S= Percentage of the sprayed paint that is
made up of solids

Q= Paint  flow rate

T= Time of spray  operation
At Graco, we have long recognized the need
for  a standardized method that would provide
meaningful data to determine  which
application device would provide the most
efficient means of applying  paint to a
customer's product. Our customers range from
companies that paint huge  metal structures
such as aircraft and road graders to
companies that  paint  considerably smaller
objects  like wood spindles  for chairs.
In addition to  part size, shape and substrate
differences, some customers  paint indoors
and some paint outdoors. Some apply paint at
a high delivery rate because they are  painting
product moving down   a conveyor line while
other  paint stationary product  in a paint
booth. The painting environment varies
greatly as well. Some customers have down
draft  paint booths with very  sophisticated air
movement  controls;-others  have  less than
ideal  conditions.
Given this wide array of equipment,  Graco has

-------
developed  a test for determining the transfer
efficiency of the  paint application tool.  We
recognized early on  that there were a number
of factors which will  have an affect on
transfer  efficiency.
Among  them-


• Operator Spray Technique

• Fluid  Delivery Rate

• Atomizing Air Pressure

• Target Size

• Type  of Application  Tool

• Condition  of Application Tool

• Part  Configuration

• Air  Velocity  in the Spray  Booth

• Fluid  Pressure

• Distance of the Spray Gun from the Target
There are also quality standards which  vary
from industry to industry  and even  from plant
to plant  within  the same industry.
Given all of these factors, Graco designed a
transfer  efficiency  test  that  attempted to
eliminate as many variables as  possible. By
doing so, we  felt that the tested  performance
of the  application  tool would  be meaningful
to our needs in product development  and also
our customers' requirements  for the most

-------
efficient  application  tool commensurate  with
their needs  for speed and quality.
At this  time, I  would like  to take this
opportunity  to  describe  that test procedure
for  you.

Graco  uses a test method for determining the
transfer efficiency of each type of
application tool that we feel provides a
reasonably  accurate tranfer efficiency
number for  each application tool. Through this
method, we have removed the  variables of
operator technique,  air  flow past the  booth,
part configuration and so  forth. The test that
we  use calls for painting a group of ten 4 foot
by 6 inch panels hung vertically on  12 inch
centers that are wrapped  with  preweighted
aluminum foil.  The  painting is performed  by a
test gun that has been  preset to approximate
the  demands of a production environment. We
trigger the gun six  inches  before the spray
contacts the first panel and release the
trigger once the last panel has  moved six
inches beyond the gun. By doing so, we can
accurately determine the amount of
paint dispensed through the gun and compare
that to the amount  of paint by  weight that
ended up on the panels. We determine the
weight of  the paint  on the panels by weighing
the  panels before and after spraying and
noting  the difference.
By using this method we are able to provide a
realistic  transfer efficiency  figure that one
could reasonably expect from
each method of spray finishing.  By using the
same test criteria,  here  is how the various
spray technologies performed.
                     o-n
                     Jl O

-------
                                         'o
                                         'o
Air Spray                              30%

HVLP Air Spray                        40%

HVLP Air Assisted Airless Spray        45%

Electrostatic  Ajr  Spray (65kv)          65%

Electrostatic  Air Assisted  Airless
                           Spray      70%

Electrostatic  Air Spray  (85kv)         75%
I  would like to point out that  this method
shows that electrostatic guns  are the only
finishing  tools  that, achieve  transfer
efficiencies of more than  50%.

Due to the recent enactment of air quality
equipment rules  that  prescribe  compliant
types of  finishing equipment, many of you
have  probably heard of another spray
technology, commonly referred to as "HVLP".
The term HVLP stands  for High Volume Low
Pressure  spray. As its name suggests, High
Volume Low Pressure spray uses large
volumes  of air under reduced  pressure
(typically  10 psi  or less)  to atomize  coatings.
Because  the  atomized  paint is propelled from
the HVLP gun at a lower velocity, there is  a
 reduced  chance  of overspray.
Today, there are two forms of HVLP
atomization. These are HVLP air spray and
HVLP air assisted  airless  spray. HVLP air
spray uses large volumes of air at low
pressure to atomize  coatings, while HVLP air
assisted airless spray  uses fluid pressure to
atomize coatings and reduced air  pressure to

-------
sculpt the fan pattern  of the  atomized spray.
Claims  of  extremely  high  transfer
efficiency have been made for HVLP. However,
as I  have tried to make clear, tests can  be
designed to provide a high transfer  efficiency
value.  HVLP can generally provide finishers
with  higher transfer  efficiency  than
conventional air spray systems. And at  its
best,  HVLP will generally exceed the transfer
efficiency  of air spray and approach  the
transfer efficiency  of air assisted  airless
spray while providing  a  high  quality finish.
But it is important  to remember  that HVLP
air  spray  operates  at generally  lower  fluid
flow rates  than  other  spray finishing
methods. The lower atomizing pressures of
HVLP means that you may be forced to  reduce
your fluid  flow  rate  to maintain finish
quality.  At these lower atomizing  air
pressures,  there may simply  not  be enough air
atomizing  pressure  to keep up.

On  the  other hand, HVLP air assisted airless
spray operates  at  fluid flow rates similar  to
conventional  air assisted  airless spray and
therefore  lends  itself to  higher  production
environments.

But please remember, the  test method  I have
described  is  designed to test relative
performance  levels. However, we can say that
this test method has been  shown to be very
useful both to us and to end-users. These
findings have also been corroborated by
anecdotal  evidence.

We know  of  a furniture finishing operation
that was able to achieve  a 40% materials
savings when they "switched  from

-------
conventional air spray to HVLP.

But as we have already noted,  in the real
world, spray finishing conditions are much
more complex.

In addition,  the  industrial finishing  line is
governed by two overriding  concerns—finish
quality and productivity. The finished
appearance of  the product being painted is
essential  to  its success in the  marketplace.

The  need to produce as many finished parts
as possible in  as short a time as possible  is
also essential  to keeping  production costs
down. These two factors  will determine the
selection  of finishing  tools and
the way  they are used on the finishing  line.

We  believe  that transfer efficient  application
tools  will  reduce the amount  of paint used to
finish a  part. This  reduction  will result in
fewer VOC emissions released into  the
environment which  in  turn will benefit
overall air quality. The key issue in
identifying such  transfer  efficient  tools is
the standardized test  method by which we
will  select  them.

-------
Mobay's Role  in the Wood Furniture   Mobay
Coating Industry
         Mobay is the leading North American supplier of
        aliphatic and aromatic polyisocyanate resins for use in
        polyurethane coatings for wood
        Mobay is also the leading North American supplier of
        non-air inhibited unsaturated polyesters for use in
        polyester coatings for wood
        Mobay sells resins to wood coating manufacturers
        Mobay seeks to act as a technical partner to the wood
        furniture coating industry
   Presentation to U. S. Environmental Protection Agency, November 19-21, 1991

-------
Mobay's Role as a                             MobaX.
Raw Material Supplier
         To define the status of our technology with respect to
         VOC compliance
         Enable us to demonstrate technology developments
         and feasibility by working with furniture
         manufacturers and coatings manufacturers
   Presentation to U. S. Environmental Protection Agency, November 19-21,1991

-------
Current Status  of  2-Component           Mobay
Solvent-Borne  Polyurethane Coatings
for Wood  Furniture	_____

      Commercially Available System   VOC (Ibs/gal)
      Clear Top Coats
 Benefits
   Up to a 23% VOC reduction from
   nitrocellulose coatings
   (approximately
   6.0 Ibs/gal to 4.6 Ibs/gal)
   Greatly improved performance
   properties (e.g. alcohol resistance/
   mar resistance)
   High film build resulting in the
   reduced number of coating
   applications
   Currently being used in production
            4.6-5.5

Present Limitations
•  May require adjustments to existing
   production operation and different
   equipment for safe or cost efficient use
   in some wood coating operations
•  May require a degree of wood coatings
   user training/adjustment in operating
   procedure for their proper use
•  Deviation from existing repairability
   procedures
   Presentation to U. S. Environmental Protection Agency, November 19-21, 1991

-------
Current Status of Non-air Inhibited
Unsaturated  Polyesters for use in
Polyester Coatings  for Wood
                                                  Mobay
      Commercially Available System
        Air Dry Clear Top Coats/Sealer
      Developmental Systems
        Air Dry Clear Top Coats/Sealer
        UV-Curable Top Coat
        UV-Curable Sanding Sealer
        UV-Curable Top Coat
        UV-Curable Sealer
                               Contains
                               monomer

                               solvent
                               monomer
                               monomer
                                water/s
-------
cn
    Current Status of  Non-air Inhibited      Mobay
    Unsaturated Polyesters for use in
    Polyester Coatings for Wood  (ContdL)
Benefits
•  40-75% VOC reduction for Air Dry
   unsatu rated polyesters as compared to
   nitrocellulose (i.e. NC @ 6.0 Ibs/gal)
•  88-97% VOC reduction for UV-Cure
   unsaturated polyesters as compared to
   nitrocellulose (i.e. NC @ 6.0 Ibs/gal)
•  Greatly improved performance properties
   (e.g. alcohol resistance/mar resistance)
•  High film build resulting in the reduced
   number of coating applications
•  Two alternative curing methods
Present Limitations
•  May require a degree of
   wood coating user
   training/adjustment in
   operating procedure for
   their proper use.
•  May require additional
   or different equipment
   for safe or cost efficient
   use in wood coatings
   operations.
       Presentation to U. S. Environmental Protection Agency, November 19-21,1991

-------
Mobay Supports                                     Mobav
         ^f      H ^1                                            .•.•.VVV-V.V.V.'.V.SWAVW.-.V.V;
                                                               >MXiX4<«x-:-:->x<»M>
          The reduction of VOC by use of 2-Component Polyurethanes
          and Non-Air Inhibited Unsaturated Polyesters

          The need for continued cooperation by the EPA with
          coatings raw materials suppliers, coatings manufacturers,
          and wood coatings users

           In allowing VOC compliant products to be optimized
           through continued development
           To allow market acceptance of products based on
           economic benefit, property performance, as well
           as VOC reduction.
   Presentation to U. S. Environmental Protection Agency, November 19-21,1991

-------
   Goals of Mobay Development
Mobay
CO
          Environmentally responsible coatings systems
          High performance coatings
      Presentation to U. S. Environmental Protection Agency, November 19-21,1991

-------
t- 3
to
     Future Developments in
     Wood Coatings
                                                     Mobay
        VOC reduction down to 0.9* Ibs/gal via
        2-Component water-borne polyurethane
        topcoats and sealers
Potential Benefits
•  85% reduction in VOC from
   nitrocellulose coatings
•  High performance of a
   2-Component solvent- borne
   polyurethane
•  Clarity of finish
•  Higher film build

* VOC value is less water
Present Limitations
•  No large scale production at this
   point
•  Commercial availability in 1-2
   years
•  Technology would require:
  • cooperative development with and the
    approval of wood coatings manufacturer
  • acceptance of furniture coatings users
        Presentation to U. S. Environmental Protection Agency, November 19-21,1991

-------
Mobay Supports                           Mobay
     The cooperative efforts between the Joint
     Industry Steering Committee (JISC), the paint
     and coatings industry and the EPA by offering
     raw materials and technology that will reduce
     VOC levels and greatly improve the
     performance properties of wood furniture
     coatings and provide off-setting cost benefits
     during the application process
  Presentation to U. S. Environmental Protection Agency, November 19-21, 1991

-------
                                                               101 California Street
                                                               San Francisco, California 94111
National Economic Research Associates, Inc.                                (415) 291-1000
Consulting Economists                                                   Facsimile (415) 291-1020


                        ECONOMIC IMPACTS OF

                       VOC EMISSIONS CONTROL

          ON THE FURNITURE AND CABINET INDUSTRIES
                        PRELIMINARY  FINDINGS
                                   Presented to:

                           National  Air Pollution Control
                          Techniques Advisory Committee


                                   Presented by:

                                 Mark P. Berkman
                                 Senior Consultant
                       National Economic  Research Associates


                                   On Behalf of:

                    American Furniture Manufacturers Association
             Business and Institutional Furniture Manufacturers Association
                     Kitchen Cabinet  Manufacturers  Association
                National Paint  and Coatings Manufacturers  Association
                                November 21, 1991
                              Durham, North Carolina
                                A Marsh & McLennan Company
     White Plains, NY / Washington, DC / Los Angeles / Cambridge, MA / Philadelphia / San Francisco / New York, NY / Ithaca, NY / Seattle / London / Madrid
                                      ~

-------
 PROJECTED TOTAL ANNUAL COST TO THE WOOD FURNITURE
    AND CABINET INDUSTRY OF REDUCING VOC EMISSIONS
    Annual Cost ($ millions)
(9
    600
    500 -
    400 -
    200 -
    100 -
            l        I
          10 %     20 %
30 %    40 %    50 %
Reduction in VOC Emissions
60%
70%

-------
               PROJECTED PLANT CLOSURES
         IN THE WOOD FURNITURE AND CABINET INDUSTRY
   RESULTING FROM THE COSTS OF VOC CONTROL TECHNOLOGY
Number of Plants Closing
3,000
2^00 -
2,000 -
1,500 -
1,000 -
 500 -
  0  I—
                       1,488    U24    1,524   1,524
        10%     20%    30%     40%    50%     60%
                          Reduction in VOC Emissions
70%
80%

-------
SO
                PROJECTED EMPLOYMENT LOSSES
       IN THE WOOD FURNITURE AND CABINET INDUSTRY RESULTING
            FROM THE COSTS OF VOC CONTROL TECHNOLOGY
    Number of jobs lost
    100,000
     80,000 -
     60,000 -
     40,000 -
     20,000 -
17,764   17,764
                          12,513   12,513
             10%     20%     30%    40%    50%    60%
                             Reduction in VOC Emissions
              70%
80%

-------
               Estimated Cost-Effoctlvsnsss of VOC Emission Control Methods In 1994 In Nonsttslnmsnt CWs»


   Oaaolln* volatility
                T80Fa


                 RACT


        Enhanced I/M


              Stag*  II


            New CTOa


       Mathanol fuel*


  Architect, coating*


    Onboard controla


    New mobll* atd'a.


  Stag* II » Onboard
                          Low • $8,700 p*r ton
                          Mean • $30.000  p*r ton
                          High • $61.000 p*r  to ON.
                                                   \
Coal-*lt*ctlv*n*aa In 2004
                        0123468789
                                                    $1.000/ton of VOC r*duo*d
 The cost-effectiveness of enhanced Inspection and maintenance (VM) programs and new mobile standards Include only the cost of VOC
 confrol. Since Onboard controls and new mobile standards do not take affect until after 1994. we present the cost-effectiveness In 2004.
 The thick horizontal bars represent the average cost-effectiveness in nonattainment cities. The thin horizontal lines for gasoline volatility.
 methanol fuels, and l/M programs represent ranges of uncertainty associated with assumptions we used to estimate total annual costs.
 The very large uncertainty associated with the methanol fuels Is due to the uncertainty of methanol prices relative to gasoline prices. We
 were unable to estimate cost-effectiveness uncertainty for other control methods. See figure 7 for a description of control methods.
 SOURCE Otlto* ol1
                  •ft A*«
Catching OurBnath —Next Steps for Reducing Urban Ozone, Congreu of the United States/Office of Technology
Aiaeument, July 1989, Page 17

-------
        WOOD FURNITURE AND FIXTURES MANUFACTURERS
         ACCOUNT FOR LESS THAN ONE PERCENT OF TOTAL
                             VOC EMISSIONS
                Small Stationary
                   42.23%
 -
P
                                                    Large Stationary
                                                       7.83%
      Air, Rail, Marine
         5.58%

       Wood Furniture
        and Fixtures
        Manufacturers
         0.54%
               Highway Vehicles
                  43.82%
   Emission from Wood Furniture and Fixtures
   Manufacturers were subtracted from Large
   Stationary.
Source: Derived from 'Catching Our Breath:
    Steps for Reducing Urban Ozone,"
    U.S. Congress, Office of Technology
    Assessment 1989.

-------
    LOWEST ANNUAL COST OF ATTAINING A 30 PERCENT
       REDUCTION IN VOC EMISSIONS FOR DIFFERENT
       WOOD FURNITURE AND CABINET PLANT TYPES
Cost (dollars/ton)
12,000
 10,000

 8,000

 6,000

 4,000

 2,000

    0

(2,000)
            %£*•
            I
          Casegoods
          10-14 Coats
  Casegoods
  Highspeed
(Up to 10 Coats)
Office Furniture
 (High End
 Casegoods)
Chair
Plant
  Print
  Finish
(Flat Line)
 Kitchen
 Cabinets
(Tow Line)
 Small
Upholstered
 Plant

-------
                       THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
                        MODEL PLANT 3 (HOUSEHOLD FURNITURE: 19 COAT STEPS; $27.0 MILLION)
See
P
           PROFIT/SALES (%)
           6.00%
           4.00% -
           2.00% -
           0.00%
-2.00%  -
          -4.00% -
          -6.00%
                    No Control    HVLP Spray Gam  Hybrid Wtterbome  PuU Wttabame     Union*

                                         VOC CONTROL TECHNOLOGY
    Carbon Adwxptioa
                                                                           Regenerative
                                                                           locutennoB
                    Low Profit Quartile
                                   Model Plant Profit
High Profit Quartile

-------
               THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
     MODEL PLANT FOUR (OFFICE CASEGOODS: 15 COATING STEPS; SALES $11.0 MILLION)
  PROFIT/SALES (%)

 10.00%
  5.00%
  0.00%

 -5.00%
-10.00%
•15.00%
               5.90%
            1.20%!
           -1.00%
                           5.99%
1.29%
                          I
                                                             5.41%
              4.56%
                                                  4.07%
                                   0.71%
                                                                         0.41%
             I
I
I
           No Control   HVLP Spray Guns Hybrid Walerbome Full Waterbome    Unicarb

                                    VOC CONTROL TECHNOLOGY
                                           Carbon Adsorption  Regenerative
                                                        Incineration
              Low Profit Quaitile
              Model Plant Profit
             High Profit Quartile

-------
               THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
     MODEL PLANT EIGHT (KITCHEN CABINETS: 4 COATING STEPS; SALES $13.4 MILLION)
 PROFIT/S ALES (%)
 8.00%
-4.00%
          No Control   HVLP Spray Guns Hybrid Walerbome Full Waierbome    Unicub   Outran Adsorption UV Roll Coating   Regenerative
                                                                                  Incineration
              Low Profit Quartile
VOC CONTROL TECHNOLOGY

  Model Plant Profit      ^  ^ High Profit Quartile

-------

               Annual Failure Rates per 10,000 Concerns
                    (Enterprises listed in Dun & Bradstreet Census
                               of American Business)
Failures per 10,000 companies
200
150 -
100  -
           1986
1987
                            Furniture
1988           1989

All Manufacturing
1990
Source: Business Failure Record, 1986-1990
Dun & Bradstreet Corporation

-------
     Millions of Dollars
     $4,000
                                     U.S. HOUSEHOLD FURNITURE INDUSTRY (SIC 251)
                               DOLLAR VOLUMES OF FOREIGN IMPORTS AND U.S. EXPORTS
                                                         1981-1990
     $3,000
3 to $2,000

^



     $1,000
        $0
                                  I
I
I
I
I
I
_L
            1981      1982       1983      1984      1985      1986       1987

                                        Foreign Imports  U.S. Exports
                                       1988
                                        (est)
                             1989
                             (eat)
                             1990
                             (est)
     Source: U.S. Census Data as reported in The U.S. Household
           Furniture Industry," Economic Industry Reports, Inc., 1990.

-------
9
                    PROJECTED PLANT CLOSINGS
          BY PLANT SIZE AND VOC REDUCTION LEVEL
    Number of Employees in Plants Experiencing Losses
    in excess of 5% of sales
     3,000
     2,500 -
     2,000 -
     1,500 -
     1,000 -
      500 -
        0
1,950
             1-19
                                      25
      20-99   100-249  250-499  500-999
               Size of Plants
              (Number of Employees)
                                                  2,539
  I      I
1000+  All Plants
                80% VOC Reduction

                60% VOC Reduction

                50% VOC Reduction

                40% VOC Reduction

                30% VOC Reduction

             H 20% VOC Reduction

             ^ 10% VOC Reduction

             I  I Already experiencing losses

-------
is
               PROJECTED EMPLOYMENT LOSSES BY
          BY PLANT SIZE AND VOC REDUCTION LEVEL
     Number of Employees in Plants Experiencing Losses
     in excess of 5% of sales
     100,000
      80,000 -
      60,000 -
      40,000 -
      20,000 -
              11,075
..A1,   19334
17,012  HBHHH   15>949   15,927
                                                        86,534
               1-19   20-99   100-249  250-499  500-999
                                Size of Plants
                             (Number of Employees)
                             I       I
                            1000+  All Plants
80% VOC Reduction

60% VOC Reduction

50% VOC Reduction

40% VOC Reduction

30% VOC Reduction

20% VOC Reduction

10% VOC Reduction

Plants already
experiencing losses

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          POLICY IMPLICATIONS
A MARKET-BASED VOC REDUCTION APPROACH SHOULD BE
CONSIDERED AS A SUBSTITUTE FOR OR IN CONJUNCTION
WITH RACT FOR SEVERAL REASONS:

1.   THE  WIDE VARIATION IN CONTROL COSTS AND
    FINANCIAL IMPACTS WITHIN THE INDUSTRY PROVIDES
    AN OPPORTUNITY TO ACHIEVE  SIZEABLE REDUCTIONS
    AND  AVOID  ADVERSE  ECONOMIC  CONSEQUENCES
    THROUGH EMISSIONS TRADING

2.   THE AVAILABILITY OF LOWER COST REDUCTIONS FROM
    OTHER SOURCES PROVIDES AN OPPORTUNITY TO LOWER
    THE OVERALL COSTS OF VOC REDUCTIONS

AT A MINIMUM, THE RACT FOR THE FURNITURE INDUSTRY
SHOULD ACCOUNT   FOR  THE RELATIVE  COSTS AND
CONTRIBUTIONS OF THE INDUSTRY TO THE GOAL OF VOC
REDUCTION
                  n/e/r/a

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Wood Furniture and Kitchen
     Cabinet Industry
Volatile Organic Compound
 Control Technology Study

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Mission Statement

The mission of the Joint Industries Steering Committee is
to participate in the federal Wood Furniture CTG
development process in order to achieve guidelines that:

  • Enhance and improve the environment of the United
   States and the world;
  • Are technically feasible;
  • Are economically justifiable;
  • Do not restrict the future growth and development of
   the United States Wood Furniture and Kitchen
   Cabinet Industries

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Joint Industry Steering Committee
Members
  • American Furniture Manufacturers Association
   (AFMA)
  • National Paint & Coatings Association (NPCA)
  • Kitchen Cabinet Manufacturers Association
   (KCMA)
  • Business and Institutional Furniture
   Manufacturer's Association (BIFMA)

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Industry Characterization

  • Detailed Survey of 160 Industry Facilities
     - Provided Industry-wide Technical and Economic Data
     - Used as Basis for Development of Model Plants
  • Facility Technology Demonstrations and Site
   Visits
     - Visited 24 Facilities
     - Provided On-Site Observations and Analyses of
      Technologies

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  ndustry Characterization (cont)


    • Industry Experts

       - Provided confirmation/refinement to model plant
 ,       characterizations
^      - Collective Knowledge of Actual Conditions at Hundreds
        of Facilities

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Development of Representative Model
Plants

  • Defined 12 Model Plants to Cover Industry
   Characteristics
  • Grouped Survey Responses into the 12 Model
   Plant Categories for Characterization
  • Augmented Survey Data with Site Visits and
   Industry Expertise

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JISC Model Plants
Considerations:
  • Industry Complexity Does Not Lend Itself to
   Simple Characterization
  • Complex Finishing Systems Driven by Consumer
   Demand for Product Quality and Aesthetics
  • Many Coatings with Varying VOC/Solids Contents
  • Multiple Substrates with Differing Properties

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'.J
JISC Model Plants (cont.)

  • Heat and Water Sensitive Substrates
  • Coatings Sensitive to Variations in Temperature
   and Humidity
  • Multiple VOC Emission Points
  • Varying Price Points of Goods Produced

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Model Plants -- Key Parameters

  • Finishing Schedule (No. of Coats and Type)
  • Type of Wood Substrate, Production Line, and
   Product Produced
  • Annual Usage of Each Coating
  • Number/Flow Rate of Spray Booths and Drying
   Ovens

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Model Plants -- Key Parameters (cont.)v

  • Production Rates/Line Speeds
  • Annual VOC Emissions
  • Number of Employees
  • Number and Type of Spray Guns/Roll Coaters
  • Number of Pumps
  • Coating Storage Method

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Control Technologies Evaluated
  • Recuperative Thermal Incineration
  • Regenerative Thermal Incineration
  • Fixed Bed Catalytic Incineration
  • Fluidized Bed Catalytic Incineration
  • Carbon Adsorption
  • Carbon Adsorption/Incineration
  • Full Waterborne Coating System
  • Hybrid Waterborne Coating System

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Control Technologies Evaluated (cont.)
  • UV Curable Coatings
  • UNICARB® System
  • HVLP Spray Guns
  •Terr-Aqua UV/AO
  • Sunkiss Ovens
  • Mobile Zone Spray Booths
  • Recirculating Spray Booths
  • Air Curtain Spray Booths

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Engineering Limitations for Certain Control
Technologies

  • Reduced Flow by Air Recirculation
     - Not Generally Applicable to All Segments of the Industry
     - Limited Actual Use in Industry Facilities
     - OSHA and Insurance Considerations
  • Reduced Flow by Air Curtain
     - Developing Technology, not Commercially Available
     - OSHA and Insurance Considerations

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Engineering Limitations for Certain Control
Technologies (cont.)

 • Full Waterborne Technology for Long Finishing
   Sequences
     - Technical Problems in Meeting Quality Specifications
     - Not Commercially Demonstrated for These Types of
     Finishes
 - UNICARB® for High Speed Lines and Stains
     - Technical Problems in Delivering Sufficient Coating Volumes
     - Slower Evaporating Solvents Require Longer Drying Time
     - Commercially Available for Topcoats and Sealers Only

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Engineering Limitations for Certain Control
Technologies (cont.)
  • Mobile Zone Spray Booths
     - Developing Technology, not Commercially Available
  • Terr-Aqua UV/AO Oxidation
     - Developing Technology, Requires Further Study
  • Sunkiss Ovens
     - Does Not Achieve Sufficient VOC Reduction to be
      Considered a Control Technology

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c:n
Control Technology Evaluation

Determined Capital and Annual Costs for Potentially
Feasible Controls
  • Add-On Emission Controls
     - Catalytic Incineration (fixed bed and fluidized bed)
     - Thermal  Incineration (recuperative and regenerative)
     - Carbon Adsorption
     - Carbon Adsorption/Incineration
  • Application Methods (Transfer Efficiency)
     - HVLP Spray System (slower lines)
     - Roll Coating
     - UNICARB® (slower lines)

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Control Technology Evaluation (cont.)
   Reformulation
     - Hybrid Waterborne Systems
     - Full Waterborne Systems
     - UNICARB® Finishes
     - UV Cured Finishes

-------
 Potential Mass VOC Reductions Available
 (Plant-Wide)
•'.J
Control Technology
Industry as Whole
Spray Techniques:
HVLP
UNICARB®
2-15%
8-33%
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
28-61%
60-75%
42-80%
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
3-86%
3-86%
3-79%

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Problems with Add-On Control Equipment

  • High Capital/Operating Costs
  • High Energy Demand
  • Secondary Environmental Impacts
  • Skilled Labor to Operate Equipment
  • Gas Pretreatment Required
  • OSHA, Safety and Insurance Considerations

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	EIKR
Problems with Waterborne Coatings
  • Production Line Color Control with Waterborne
   Stains
  • Sags and Film Thickness on Vertical Surfaces
  • Repairability
  • Ease of Application/Drying Time
  • Sensitivity to Temperature/Humidity Changes
  • Print Resistance
  • Rubbing Characteristics (Layering)
  • Appearance (Clarity/Color)

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Problems with UNICARB®/UV
   UNICARB®:
   •  Developing Technology
   •  Available Only for Sealer/Topcoat
   •  Restricted to Slower Line Speeds
   UV:
   •  Applicable to Limited Industry Segments
   •  Casegoods Technology Still Under
     Development
   •  Difficult to Repair

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Costs of Alternative Controls


  • Evaluated 11 Control Technologies for the 12
   Model Plants

  • Developed Capital Costs, Annual Costs, Cost
   Effectiveness Following OAQPS Guidelines

-------
Capital Costs of Alternative Controls
Control Technology
Industry as Whole
Spray Techniques:
HVLP
UNICARB®
$400/HVLP Gun
$75,000 -$21 0,000
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
$165,000 -$1,005,000
$286,000 - $1 ,030,000
$98,000 - $1 ,005,000
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$163,000 - $1 ,026,000/booth
$312,000 - $673,000/booth
$419,000 - $885,000/booth

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Annual Operating Costs of Alternative
Controls
Control Technology
Industry as Whole
Spray Techniques (Negative Numbers Indicate Cost Savings):
HVLP
UNICARB®
($51, 000) -$2,000
$25,000 - $470,000
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
($163,000) -$547,000
($166,000) -$300,000
$95,000 - $1 ,222,000
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$103,000 - $321,000/booth
$68,000 -$170,000/booth
$106,000 - $223,000/booth

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 Cost Effectiveness of Alternative Controls
Control Technology
Industry as Whole
Spray Techniques (Negative Numbers Indicate Cost Savings):
HVLP
UNICARB®
($2,100)-$1,800/ton
$2,100-$9,400/ton
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
($500) - $1 1 ,500/ton
($400) - $8,600/ton
$800-$15,800/ton
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$1 ,500 - $87,300/ton
$1,300-$44,100/ton
$1 ,400 - $63,500/ton
••-J
C75

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Additional Issues

  • Units of VOC Limits
  • Multiple Levels for Various Industry Segments
  • Phased Implementation of Developing
   Technologies

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Technical-Economic Analysis  Interface
       ENSR
        Technical Feasbility

        • Evaluate Controls
        • Evaluate Capital and
         Annual Operating Costs
NERA
 Economic Feasibility

 • Identify Least Cost Controls
 • Estimate Financial and
  Employment Impacts at
  Plant and Industry Level

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    November 8,  1991


    Mr. Bruce  C.  Jordan
    Director,  Emission Standards Division  (MD-13)
    Office of  ftir Quality Planning and Standards
    U.S. Environmental Protection Agency
    Research Triangle Park,  N.C.  27711


    Dear Mr. Jordan:

         Subject:   Comments on Draft Chapters  1-4  of the Control
                    Technique Guidelines  (CTG)  for  Control of Volatile
                    Organic Compound Emissions  from Wood Furniture
                    Coating Operations


    We have seven  (7)  plants that will be  affected by the final
    outcome of the control techniques guidelines.   While we are
    optimistic that  source reduction of VOCs will  be one of the
    options in the CTG and one which we can ultimately achieve, we
    are concerned  about the model plant parameters that will be used
    to determine  the  cost of add-on controls.

    Specifically  refer to page 4-3 of the  draft  CTG,  model plant no.s
    2 and 5, and  read the exhaust rates for those  two (2) plants.
    These residential  furniture models are assumed to exhaust the
    same amount of air even though one finishing sequence is twice as
    long as the other.   The short finishing sequence represents six
    (6) finishing  steps which would reasonably correlate to six (6)
    spray booths  while the long finishing  sequence represents twelve
    (12) finishing steps which would reasonably  correlate to twelve
    (12) spray booths.   The exhaust rates  for the  long sequence could
    reasonably be  expected to be twice as  high as  the exhaust rates
    for the short  sequence.

    The use of the above-mentioned exhaust data  will result in
    inaccurate cost figures for those model plants since the cost of
    add-on controls is largely a function  of size  determined by air
    flow rates.   In order to effectively accomplish what you have set
    out to do  you  would need to look at the exhaust rates for the
    long and short  sequences of the model  plants separately.

    We are also concerned about the comments addressing  the
    potential  for  booth enclosure,  especially without the advantage
    of your including  a visit to a residential furniture
    manufacturer.  Due to the number of surfaces that must be coated
    a  worker does  not  merely stand to finish a piece of assembled

Thomasvillc Furniture Industries, Inc.  • P.O. Box 339 • Thomasville, North Carolina 27361  • 919472-4000
                                 P- f* r>
                                 •>' • O J

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Thomasville Furniture Industries, Inc.
Thomasville, North Carolina
    residential furniture  as indicated  in  the  document on  page  3-23.
    The  worker moves on  the  line with the  piece.  Further enclosure
    would  probably be possible but with drastic changes in
    product i on.

    Finally,  it would have  been desirable  to have the draft  of
    Chapter  5 prior to the  NftPTAC meeting.  Mary Jane Clark  in  OAQPS
    has  indicated that the  comment period  following the meeting will
    probably  be two (2)  weeks.   fis it stands we will have  limited
    time for  review and  comment on what may be the most critical part
    of the document.

    Your consideration of  these matters will be greatly appreciated.
    Sincer
    Sherry  Stookey,  Supervisor
    Environmental Compliance
    cc:   Larry Belton
          George Griffin
          Dan  Little
          Jim  Johnson
          Carlyle Nance
          Charley O'Brien
          Dave Masters

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                     AUTOMOBILE REFINISHING
                   CONTROL TECHNIQUES GUIDELINE

                   Presented by: Darcy Campbell
                       Radian Corporation

     The full text from the Environmental Protection Agency's
(EPA's)  presentation of the draft control techniques guideline
(CTG) is provided below.   Following that is a summary of the
questions and discussion that occurred with the National Air
Pollution Control Techniques Advisory Committee (NAPCTAC) after
EPA's presentation.
INTRODUCTION

(Slide 1)
     I would also like to introduce Ellen Ducey, the EPA's Lead
Engineer on this project.
     The facilities covered under this CTG repair and/or refinish
automobiles, vans, motorcycles, and light- and medium-duty
trucks.  Heavy duty trucks are currently covered by another CTG
that EPA developed for Miscellaneous Metal Parts.
     "Shops" are defined as:
        independently-owned shops that repair collision damage
     and do some complete repainting,
        shops at car dealerships that repair transportation
     damage and collision damage that occurs after a car is sold,
     and
        production shops that specialize in complete repainting
     rather than collision repair.
     The definition also includes any facilities that repair new
vehicles damaged in transit.

(Slide 2)
     I will first discuss the refinishing process, along with the
volatile organic compound (VOC) sources.  I will then discuss the
VOC control methods that have been evaluated in terms of their
emission reductions and costs, present the results of our
regulatory analysis, and discuss the implementation of a
regulation for this industry.

(Slide 3)
     Estimates of the number of body shops in the U.S. vary.  We
estimate that there are roughly 63,000.  Extrapolating by
population, there are roughly 30,000 shops in nonattainment
areas.  Taking into consideration the existing State and local
regulations already in place in Texas, New York, New Jersey, and

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California, we estimate that about 100,000 tons of VOC's are
emitted each year from body shops in nonattainment areas.


THE REFINISHING PROCESS

(Slide 4')
     Surface preparation refers to the removal of dirt, wax,
grease and silicone.  Surface preparation products are used
whether a replacement part is painted or the existing finish is
sanded off.
     Several different types of coatings are used in refinishing.
"Primers" are any coatings applied before the topcoat.  Types of
primers include pretreatment wash primers, precoats, primer
surfacers, and primer sealers.  Topcoats determine the final
color of the refinished area.
     Many shops apply coatings in some type of spray booth.  Each
coating is applied to a certain "dry film thickness," which is
expressed in mils, or one-thousandths of an inch.
     An important consideration in the refinishing process is
matching the existing car color.  This is a very complex problem
because there are so many car colors, and more new colors are
introduced every year.  For example, one car manufacturer alone
can introduce 20 new colors each year, and have a total of 70
colors for cars in a given model year.  Refinishing is also made
difficult because topcoats applied by original equipment
manufacturers (OEMs) may be complex two-, three-, or even five-
stage products.
     Additives and specialty coatings are different from the
other coatings.  They are used in small amounts as needed for
easier repair and less customer dissatisfaction.
     After the refinishing process, spray equipment is cleaned
with solvent to remove the paint so the gun can be used again on
another job.


EMISSION CONTRIBUTIONS

(Slide 5)
     Emission contributions shown on this slide have been
estimated using "model" shops, which will be discussed in more
detail later.  As you can see, the majority of emissions are from
application of coatings.  Equipment cleaning contributes
9 percent of the VOC's, additives and specialty coatings
5 percent.  Three percent of emissions are from surface
preparation.  For our purposes, coating emissions begin with
spraying; any emissions that might arise from the mixing process
were not considered.
                            966
                                2

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REGULATORY ANALYSIS

(Slide 6)
     Eight model shops were developed to analyze emission
controls.  They were used to establish a common basis by which to
calculate a baseline and the impacts of any recommended control.
The mode'l shops were developed from information in trade
journals, and from discussions with industry and State agency
representatives.
     Our model shops represent the diversity of the industry.
Shops are delineated by size, equipment, and types of coatings
used.

(Slide 7)
     The model shop size is reflected by the number of employees
and number of jobs.  Anything less than painting an entire car is
considered a "spot" or "panel" repair, and is shown here as a
partial job.
     The information we gathered from trade journals helped us
delineate shops B through H.  Based on discussions with industry
representatives, we added shop A to represent very small shops.
Eighty percent of the model shops are medium-size, with a large
range in the number of jobs they do each year.  Model Shop H
represents the large national chains that have more than 10
employees and a large portion of their work is full jobs.

(Slide 8)
     The model shops have different types of equipment.  Model
Shops A and B represent the smallest shops, which are assumed not
to invest in much equipment.  They do not have gun cleaners or
spray booths.  The other medium-size shops (besides B) are
distinguished by the variety of equipment they have.  Shop C has
a gun cleaner, D has a crossdraft booth, E has both, F has a
downdraft booth, and Shops G and H, the largest shops, have
invested in the most equipment: they use gun cleaners and
downdraft spray booths.
     A distinction is made between crossdraft and downdraft
booths because downdraft booths cost twice as much, and
reportedly produce a much higher quality paint job.
     The combinations of equipment present in the model shops
were developed based on national estimates of the percent of
shops that use this equipment.

(Slide 9)
     The model shops use different types of coatings.  Lacquer is
the easiest to use and the most "forgiving" type of coating.  It
dries quickly and is buffed after drying to remove dirt and dust.
However, it results in the lowest quality finish in terms of
durability.
     Enamels and urethanes dry more slowly because they have
lower VOC levels and higher solids contents, resulting in lower
VOC emission potentials than lacquers.  Because they dry more
slowly,  it is more important that the painting area be as clean

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as possible.  Enamels vary in their finish quality:  there are
low-quality and high-quality enamels.  Urethanes produce the
highest quality finish in terms of gloss, and are the most
durable.

(Slide 10)
     Model Shops A and B use a large percent of lacquer coatings
because they do not have any kind of spray booth.  It is possible
that these shops also use urethane coatings, but in our analysis
we assumed that they only use lacquers and enamels.
     Shops C, D, E, and F use all three types of coatings in
different combinations.  Shops G and H use mostly high-quality
urethane coatings.
VOC CONTROL OPTIONS

(Slide 11)
     To identify VOC control options for this industry, we
surveyed the industry, reviewed published literature and existing
State regulations, and met with several industry representatives
to identify control options.  We then used model shops to
determine emission reductions achievable through the use of these
control options.
     Surface preparation emissions can be reduced by using
products that have lower VOC levels.  Coating application
emissions can be reduced by using coatings with lower VOC levels,
whether they are higher in solids or waterborne rather than
solventborne.  The results of our survey indicated that in most
cases this industry now tends towards higher solids rather than
waterborne coatings.
     Add-on control devices could also be used to control coating
emissions.  Add-on controls are not currently used by any shops,
but they were evaluated because they are used in many other
industries that spray-apply coatings.  An add-on control device
would control emissions from all operations that take place in
the booth.
     Emissions from equipment cleaning can be reduced by using
gun cleaners that minimize evaporation and recirculate the
solvent for several cleanings rather than manually cleaning the
spray equipment.  If a gun is cleaned manually, solvent may be
sprayed through the gun either into the air or into a container
from which it is allowed to evaporate.  With a gun cleaner,
solvent is drawn by suction through the spray guns after they are
attached to hose connections.  The outside of the gun is then
either rinsed manually or automatically, depending on the type of
gun cleaner.  In our evaluation of gun cleaners, we found that in
general they can be divided into two groups: enclosed cleaners
with lids that are shut during the cleaning cycle, and open
cleaners that have no lid.
     Finally, making sure that shops properly dispose of their
waste solvent would further reduce evaporative emissions.


                            968 4

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SURFACE PREPARATION

(Slide 12)
     Emissions from surface preparation products can be reduced
through the use of waterborne rather than solventborne products.
Waterborne products have VOC levels below 1.7 pounds per gallon.
These prbducts are somewhat harder to use than conventional
products because they are more labor intensive and it takes
longer to clean the surface.  They are currently required in
California and Texas.
     Low-VOC products reduce emissions from surface preparation
by 75 percent.  The cost increase is about $5 per gallon, or $1
per full job.
COATINGS

(Slide 13)
     Industry reports that they are actively developing lower VOC
coatings in response to State regulations.  We surveyed the six
major coating manufacturers in the summer of 1990 for information
on their lower VOC coatings.  We asked them to list any
limitations with the use of these products, especially problems
with topcoat color matching.  Color matching is of continuing
concern because a painter may have to repaint a larger area if he
has trouble making the refinish color look the same as the
existing color.  If the color match is not reasonably good,
painters will have to paint a larger area until they reach some
natural break on the car such as a fender or a door.
     Color matching is so important, and there are so many car
colors, we could not just set limits based on the lowest VOC
primers and topcoats identified in our survey-  Taking into
consideration information provided on color match and product
compatibility, we grouped the lower VOC coatings into two
regulatory options.  It should be noted that VOC emission
reductions are not linear.  If you had a coating with a VOC
content of 6.5 Ibs VOC/gal and you wanted to reduce emissions by
40 percent, you could do so by replacing it with a coating with
6 Ibs VOC/gal.  This is due to the fact that the lower VOC
content coating has more solids in a given volume of paint so
less volume is needed to coat the part.  A coating with 5.5 Ibs
VOC/gal reduces emissions by 60 percent from that of the coating
with 6.5 Ibs VOC/gal.  The VOC levels shown on this slide are all
expressed as Ibs VOC/gal coating, less water.
     The VOC contents of the baseline coatings were derived from
the model shops7 use of lacquers, enamels, and urethanes; the
high end reflects greater lacquer use and the low end reflects
more use of urethanes.
     Option 1 coatings are currently available to shops.  We
think that they are widely used because they are not very
different from baseline or existing technology coatings.  We
think there are no color match limitations associated with the
                           969
                                5

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use of Option 1 topcoats.  They do, however, eliminate the use of
essentially all lacquers.
     The Option 2 VOC levels are more stringent.  Coatings with
these levels were reported by at least one company that responded
to the survey.  We have already received some comments that the
Option 2 limits will be difficult to meet, and I think we will
hear more about this in some industry presentations.
     Compared to the baseline, emissions from coatings would be
reduced 35 percent if all shops used Option 1 coatings, and
55 percent if all shops used Option 2 coatings.  The biggest
emission reductions come from the smaller shops that are assumed
to currently use large quantities of lacquers.

(Slide 14)
     With Option 1, the smallest shop can reduce its coating
emissions by 50 percent, or 0.4 tons.  The largest shop reduces
its emissions by 20 percent, or 2.5 tons.
     The cost increases shown here are the incremental paint
costs only and do not include any additional labor or equipment
costs that might be incurred.  There is no cost increase for the
largest shops with the Option 1 coatings because they already use
coatings with low VOC levels.  With Option 2, the smallest shop
can reduce 60 percent of its coating emissions, and the largest
shop can reduce 45 percent of its emissions, or 5 tons per year.
The increased paint costs for Option 2 represent a 9 percent
increase per full car for the smallest shop and a 6 percent
increase for the largest shop.


ADD-ON CONTROLS

(Slide 15)
     For add-on controls, we evaluated catalytic incineration,
carbon adsorption, and biofiltration.  We only evaluated add-on
controls for the largest model shop, where the use of these types
of controls is most feasible because of its high volume of work.
If the spray booth is in relatively constant use> then add-on
controls are more affordable.
     With biofiltration, the spray booth exhaust is passed
through material that contains microorganisms that convert the
VOC's to carbon dioxide and water.  Even though this is only in
the developmental phase in this country, it may be the best add-
on for this industry because it reportedly can function even with
periods of non-use and with low solvent air streams.
     We will continue to investigate the use of add-on controls
for this industry, especially biofiltration.  In particular, we
will investigate whether overseas shops use any type of add-on
control.
                            970
                                6

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ADDITIVES AND SPECIALTY COATINGS

(Slide 16)
     Our analysis indicated that the best way to control
emissions from additives and specialty coatings is to limit their
use rather than require reformulation or discontinuation of their
use.  The use of these products probably prevents some VOC
emissions because a painter can prevent some surface defects from
occurring, and can better blend the new paint into the old
without having to paint a larger area.  These products also
prevent having to repaint areas because of problems such as a
coating flaking off from a refinished bumper.
     Limiting the use of additives and specialty coatings to less
than 5 percent of all coatings also closes the potential loophole
of shops identifying a product as a "specialty coating" and then
using a high volume of it.


GUN CLEANERS

(Slide 17)
     To reduce emissions from gun cleaning, it is recommended
that shops use a gun cleaner rather than manually cleaning their
spray guns.  Based on comments we have received to date, I think
we will be hearing more about the gun cleaning issue in later
presentations.
     Closed gun cleaners are required by some States.  We were
also going to suggest that States require their use until we saw
the results of an independent study that indicates that there is
a large range in the sum of the active and passive VOC losses
from closed gun cleaners.  Some models are not efficient in
controlling evaporation.  The study showed that open gun cleaners
have evaporative losses as low or lower than closed gun cleaners.
Gun cleaner manufacturers are researching ways to further reduce
VOC losses, which may make closed gun cleaners preferable in the
future, especially because from an environmental standpoint a
combination of the two types of gun cleaner designs would
probably be best.
     The primary benefit of a gun cleaner is that roughly 10 guns
can be cleaned with the same amount of solvent that would be used
to clean 1 gun manually.  In terms of emission reductions, this
translates to about an 88 percent reduction in gun cleaning
emissions for a shop that installs a gun cleaner.  This amounts
to an annual emission reduction of 0.2 tons for the smallest shop
and 1 ton for the largest shop that does not already have a gun
cleaner.
     Costs range from $36/year for the smallest model shop to a
cost savings of $800/year for the largest shop because of the
money it saves on solvent purchases.
                            9717

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SUMMARY

(Slide 18)
     The costs and emissions given in this presentation are for
the 30,000 shops in nonattainment areas, and take into
consideration existing State regulations.
     Surface preparation emissions can be reduced by 1600 tons at
a cost of about $2200 dollars per ton.
     An emission reduction of 25,000 tons would result from the
use of Option 1 coatings,' at a cost of $59 million.  The use of
Option 2 coatings would result in an emission reduction of 53,000
tons at a cost of $122 million.  Both options represent a cost of
about $2300 per ton reduced.
     Option 2a is Option 2 coatings used by all shops except H,
which uses carbon adsorption.  Emissions are reduced by 68,000
tons per year at a cost of $292 million.
     The use of gun cleaners results in a national cost savings
because shops will have to purchase less solvent.  The smallest
shops, however, would bear a total national cost of $80,000
because the value of solvent saved would not completely offset
the cost of the gun cleaner.
IMPLEMENTATION

(Slide 19)
     We recommend the following requirements for States
implementing a regulation on the automobile refinishing industry:
        For lower VOC surface preparation products, a State would
     use an operational standard that requires shops to use
     products with VOC levels below 1.7 Ibs per gallon cleaner;
        An operational standard would also be used to require the
     use of lower VOC coatings;
        An equipment standard would require the use of a gun
     cleaner that recirculates solvent, collects spent solvent,
     minimizes evaporation, and meets fire safety and
     occupational safety and health codes.
Most requirements would be enforced by recordkeeping:
        Shops would be asked to maintain records on the number of
     jobs they do, the VOC content and amount of surface
     preparation product they use, and the amount of coating,
     catalyst, and reducer used and their mix ratio; and
        Shops would also be asked to record the VOC content of
     the coating, as applied, less water.
     A shop would know the VOC content if the VOC content was
provided by the manufacturer along with the coating; we will
include a section in the CTG on how shops should get this
information, whether it be given through the "as supplied" and
"as applied" VOC levels on labels, material safety data sheets,
the microfiche provided with mixing machines, or some type of
separate "Application Guide."
     For gun cleaners, compliance would be determined by having
shops maintain records of the amount of replacement solvent they

                           972R
                                o

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use per month and-documentation of the amount of waste solvent
transferred to waste treatment facilities.
OTHER APPROACHES

(Slide 20-)
     Some other "nontraditional" ways to reduce VOC emissions
from body shops that are discussed in the CTG and that may have a
big impact on this industry are some pollution prevention and
market incentive measures.   The EPA's Pollution Prevention office
is looking into these approaches and plans to evaluate their
impacts on the refinishing industry.
     One example of a pollution prevention measure is for the
U.S. Department of Transportation to raise the minimum standard
for the strength of automobile bumpers so that less damage occurs
in a "fender bender" and less of the vehicle has to be repainted.
     Educating consumers about the costs of the more complex
coatings, and showing them that they pay more for these coatings,
may cause car manufacturers to reduce the complexity of topcoats.
     As long as there are an infinite number of colors available
for new cars, there will be a continuing impact on the
refinishing industry.  It is possible that setting a VOC limit on
refinish coatings may make it impossible to color match some OEM
colors.
     We are suggesting that States establish a permitting program
that would help locate shops, and States could use this type of
program to push the industry to be more aware of measures it can
take to reduce VOC emissions.

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    CONTROL
  TECHNIQUES
    GUIDELINE
       Control of
Volatile Organic Compound (VOC)
      Emissions from
Automobile Refinishing Operations
 NAPCTAC Meeting Presentation
       November 1991
         974

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 AUTOMOBILE REFINISHING
OUTLINE OF PRESENT A TION

  • Description of Process

  • Sources of Emissions

  • Regulatory Analysis
   - Control Options
   - Costs

  • National Impacts

  • Implementation
             975

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   CONTRIBUTION TO
    VOC EMISSIONS
-63,000 body shops in the U.S.
-30,000 located in nonattainment areas
Approximately 100,000 tons per year of
VOC's emitted in nonattainment areas
         9763

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       DESCRIPTION OF
   REFINISHING PROCESS
1.  Prepare surface
2.  Apply coatings
   - pretreatment wash primers
   - precoats
   - primer surfacers
   - primer sealers
   - topcoats
   - additives and specialty products

3.  Clean Equipment
             977

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            SOURCES OF VOC EMISSIONS IN
               AUTOMOBILE REFINISHING
 Coating Application
    83%
GD
en
                                                 Equipment
                                                 Cleaning
                                                   9%
                                              Additives and
                                            Specialty Coatings
                                                 5%
                                           Surface Preparation
                                                3%

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REGULATORY ANALYSIS
Eight model shops
Delineated by
-  Size
-  Equipment
-  Types of Coatings
         979

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Shop
Size
Small
Medium
Large
Model
Shop
A
B
C
D
E
F
G
H
Percent
of Shops
10
14
5
10
39
7
5
10
Number of
Employees
<5
5-10
5-10
5-10
5-10
5-10
5-10
>10
Number of
Jobs/Month
Partial
12
29
42
62
83
75
104
62
Full
1
1
2
2
4
8
8
50

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EQUIPMENT
Model
Shop
A,B
c
D
E
F
G,H
Gun
Cleaner

X

X

X
Booths
Crossdraft


X
X


Downdraft




X
X
  981 e

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COATINGS
Type
Lacquer
Enamel
Urethane
VOC Emission
Potential
High
Varies
Low
Finish Quality
Low
Varies
High
  S829

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                     TYPES OF COATINGS
   100
c
0)

o


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    VOC CONTROLS FOR
    EMISSION SOURCES

Surface Preparation
   - Use detergent rather than solvent


Coating Applications
   - Lower VOC coatings
   - Add-on Controls
Equipment Cleaning
   - Automated Gun Cleaners

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 CONTROL OPTION FOR
SURFACE PREPARATION
 Reformulation to Lower VOC products
 - Baseline:    6.4 Ib VOC/gal cleaner
 - Lower VOC:  1.7 Ib VOC/gal cleaner


 Emission Reduction
    25 Ibs/yr   —> 600 Ibs/yr
 (smallest shop)   (largest shop)


 Increase in Materials Cost
    $5/gallon ($1/fuil car)
           985
12

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    CONTROL OPTION FOR
   COATING APPLICATIONS
 REFORMULATION*
Coating
Type
Pretreatment
Wash Primers
Precoats
Primer Surfacers
Primer Sealers
Topcoats
Baseline
Technology
6.5
6.5
4.8 to 5.7
4.6 to 5.6
5.2 to 6.0
Overall Emission Reduction
Option 1
6.0
6.0
3.8
4.6
5.2
35%
Option 2
5.5
5.5
2.1
4.6
4.5
55%
*lb VOC/gal, less water

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   EMISSION REDUCTIONS
          AND COSTS
Option 1
   Emission reduction
      0.4tons/yr   —> 2.5tons/yr
    (smallest shop)   (largest shop)

   Increase in materials cost
      $9/full car  —>  $0/full car
    (smallest shop)   (largest shop)
Option 2
   Emission reduction
      0.5 tons/yr   —>  5 tons/yr
    (smallest shop)   (largest shop)

   Increase in materials cost
      $25/fuilcar   —> $17/fullcar
    (smallest shop)   (largest shop)

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   CONTROL OPTIONS FOR
   COATING APPLICATIONS
ADD-ON CONTROLS

  • Evaluated for Largest Model Shop Only


  • Catalytic Incineration
   -  Emission Reduction:
     from 11tons/yr to 0.6 tons/yr
     (reduces 95% of coating application emissions)
   -  Cost: $155,000/yr

  • Carbon Adsorption
   -  Emission Reduction:
     from 11 tons/yr to 1 ton/yr
     (reduces 90% of coating application emissions)
   -  Cost: $66,000/yr

  • Biofiltration
   -  Emission Reduction:
     from 11 tons/yr to 1 ton/yr
     (reduces 90% of coating application emissions)
                  15

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     ADDITIVES AND
 SPECIALTY COATINGS
Include uniform finish blenders, adhesion
promoters, elastomeric materials, gloss
flatteners, and anti-glare/safety coatings

Necessary for unusual performance
requirements

Used in relatively small amounts to
improve or impart desirable properties

Recommend limiting use (<5 percent of
coating use by volume) and VOC content
(<7lbs VOC/gal, as applied)
             16

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  CONTROL OPTION FOR
  EQUIPMENT CLEANING
• Use gun cleaning equipment designed to
 reduce solvent consumption and
 evaporation

• Emission Reduction
    0.2 tons/yr  —>  1 ton/yr
  (smallest shop)    (largest shop)
 Costs
    $36/year  -
  (smallest shop)
Savings of $800/year
   (largest shop)
              17

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VOC EMISSIONS AND COSTS IN
    NONATTAINMENT AREAS*

Surface
Preparation
Coating
Applications
Option 1
Option 2
Option 2a**
Gun
Cleaning
Baseline
(tpy)
2,400
88,500
9,000
Emission
Reduction
(tpy)
1,500
25,700
53,500
68,500
5,500
Total
National
Costs
(million $/yr)
$33.35
$59.20
$122.00
$292.00
Savings***
Cost
Effectiveness
($/ton VOC
removed)
$2,230
$2,300
$2,280
$4,260
—
'Takes into account existing State and local regulations.

**Add-on control for Model Shop H (Carbon Adsorption).

'"Costs of $81,000 would be borne totally by small shops. Larger shops save
money by using a gun cleaner with national cost savings of approximately
$375,000/yr.
                99118

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IMPLEMENTATION/RECORDKEEPING
    Control
   Technology
      Type of
     Standard
   Recordkeeping
 Lower VOC Surface
Preparation Products
Operational (process and
   material change)
- Amount used
- VOC content of product
- Labeling
Lower VOC Coatings
Operational (process and
   material change)
- Volume of coating,
catalyst, and reducer used
- Mix ratio
- VOC content of coating
- Labeling
  Add-on Controls
     Emission
                                    - Performance records
   Gun Cleaners
     Equipment
- Amount of replacement
solvent used
- Amount of waste solvent
removed
- Documentation of proper
disposal

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 OTHER APPROACHES
Decrease Collision Damage

Educate Consumers
- Cost of "Glamorous" Coatings
- Repair Costs
- Insurance Costs

Permitting Shops
- Identifies Shops
- Require Training
          9S32Q

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COMMITTEE DISCUSSION ON EPA PRESENTATION

     Ms. Mclntire suggested that references to decreasing
collisions and consumer education were beyond the scope of work
of the CTG.  Mr. Berry responded that EPA is supposed to be
giving guidance to the States on how they can achieve emission
reductions.  The EPA is looking at things States can do to
educate consumers, for example, by explaining that since
insurance companies do not inguire as to the color of a car,
those who own cars with glamorous finishes are being subsidized
by those who own cars with less expensive finishes.  The EPA
feels that these recommendations are appropriate.  Mr. Johnson
agreed that these recommendations are within the scope of the
CTG.  Ms. Mclntire agreed on the need for consumer education, but
indicated that it seemed inappropriate to place it in a CTG on
automobile refinishing.  Dr. Pinkerton commented that consumer
education seems like interference.
     Ms. Mclntire suggested that the 5 percent limit for
specialty coatings be for an averaging period longer than a day
because, in some cases, a specialty coating may be the only job a
small shop has for an entire day.
     Dr. Pinkerton inquired on the VOC component from refinishing
activities and whether the VOC's are included in the list of 190
Hazardous Air Pollutants.  Ms. Ducey said some, but not all, are
included.  Ms. Wyatt said that the industry is not on the list of
major sources because the facilities are too small; however, it
is being considered for inclusion as an area source.
     Ms. Mclntire asked how the number of facilities in
nonattainment areas was derived.  Ms. Campbell responded that the
number was population-driven.  Ms. Mclntire suggested that EPA
verify the number.
     Dr. Atkins inquired whether refinishing is driven by the
original equipment manufacturer  (OEM) coating.  Ms. Ducey said  it

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is;  colors must be matched,  but the refinishing process uses
different paints because the cure temperature must be much lower.
     Mr.  O'Sullivan asked why there was no mention of transfer
efficiency (TE) in the CTG,  especially if it is more cost-
effective than other control measures.  The EPA responded that it
is an attractive option that will be encouraged, but a
quantitative requirement based on it will not be part of
recommended RACT in the CTG.
     Mr.  O'Sullivan suggested using Options 1 and 2 as a phased
approach.  He questioned whether the cost-effectiveness figure on
slide 18  (for Option 2a) is  average or incremental.  Ms. Campbell
responded that it is average.  Mr. O'Sullivan suggested showing
incremental cost-effectiveness from Option 2 to Option 2a.  He
also commented that the recordkeeping requirements would be tough
for industry and that permitting should be avoided for small
facilities, although perhaps a standard permit could be
developed.
     Ms.  Mclntire hoped that placing VOC limits on products would
not place industry in a bad  position regarding matching colors.
Mr.  Taranto questioned the statement that limiting VOC levels may
make it impossible to match  OEM colors, and whether it might
require that an entire vehicle be refinished rather than just a
portion.   Mr.  Berry responded that the OEMs could always
introduce colors that refinishers can not match, but while OEMs
are trying to go with "snazzier" coats and colors, EPA is
pressing  the other way.   Eventually, designers of original colors
and repair capabilities must come together to strike a balance
between VOC limits and color match.
     A member of the audience asked how odor varied between
Options 1 and 2.   Ms.  Campbell did not know.  The audience member
recommended odor as well as  air toxics control because odor is
the  major source of complaints for body shops.  Mr. Berry
commented that add-on controls can mitigate odors.

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     The EPA presentation was followed by six industry speakers.
These presentations are provided below in full text.  After each
industry speaker, NAPCTAC members were provided an opportunity to
ask questions.  These questions and the ensuing discussions are
summarized for each presentation.
                             9S6

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Industry  Presentation #1
                                                              «•,
                                                                   \National
                                                              ^  'Coatings
                           POSITION PAPER                      Association

             OF THE NPCA AUTOMOTIVE REFINISH COALITION

                             CONCERNING

     DRAFT AUTOMOBILE  REFINISHING CONTROL TECHNIQUE GUIDELINE

                           **************

                            Introduction

 The NPCA Automotive Refinish Coalition:  The Automotive Refinish
 Coalition was formed in 1988 under the auspices of the NPCA  to
 work for effective and nationally consistent VOC regulations for
 the automotive refinish industry.

 The active participants in the Coalition are the six national
 manufacturers of automotive refinish paints and coatings:  AKZO
 Coatings, Inc.; BASF Corporation; E.I. du Pont de Nemours; Nason
 Automotive Coatings; PPG Industries, Inc.; and the Sherwin
 Williams Company.  Collectively, these companies account for the
 lion's share of the total volume of automotive refinish products
 that are sold in the United States.  These companies also provide
 the majority of the training that is taken by individuals to
 become proficient in the use of automotive refinish products.
 The six individuals who represent these companies on the
 Automotive Refinish Coalition collectively possess over 150  years
 of experience in the industry.  They therefore are in a
 particularly good position to comment on the industry's products
 and the underlying economics and  operational requirements of
 automotive refinish facilities.

 The Coalition also has as adjunct members a number of trade
 associations that represent user segments of the industry.   While
 the adjunct members generally support the positions taken by the
 six manufacturer members of the Coalition, they have not had an
 opportunity to review this position paper.  Consequently, the
 positions taken should be seen as representing only those of the
 six manufacturers.

 Objective of the Coalition;  The objective of the Coalition  is
 the development  of nationally consistent VOC regulations that
 achieve significant, real and effective reductions in VOC
 emissions from automotive refinish facilities while not imposing
 unnecessary additional costs or losses in productivity on the
 automotive refinish facilities.

 Moving to lower VOC containing products will create enormous
 productivity problems for automotive refinish facilities.  Our


                               997
 1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549

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concerns on this score are particularly strong because the
industry has a large population of small businesses.
Approximately 40% of the shops employ less than five individuals
and have sales volume of under $150,000 annually, according to a
1988 EPA study of the industry-

           Effective VOC  Regulations  Must  Recognize and
    Incorporate  Industry's  Practices  and Operational Realities

To achieve the objectives of significant reductions in VOC
emissions from automotive refinish facilities at the least amount
of unnecessary economic disruption to the industry, a regulatory
program must incorporate fundamental technical, operational, and
economic features of the industry.

Achieving Adequate Matching of Repair to OEM Finish:  Achieving
an adequate repair that matches the existing coat so that the
repaired area is imperceptible is the central requirement of the
industry-  Thousands of colors and coatings must be available for
all model years of the various car manufacturers to match the
many different features of thousands of original coatings, such
as their color,  gloss, and durability,  as well as the effects
that time and the elements have had on the OEM color and finish.
All of this must be accomplished at facilities with far less
sophisticated equipment,  under much more difficult and
uncontrolled circumstances than exist at the original equipment
manufacturers' facilities.

Systems Nature of Today's Products;  Today's products are
provided by individual manufacturers in the form of chemically
complex interrelated components to a single system.  The
components of a particular repair system must be used only within
the system of the particular manufacturer and pursuant to the
manufacturer's instructions to ensure that the refinish job will
not fail.

Composite Calculation for Multiple Coat Topcoats is Essential;
The use of multiple coats involving a base coat for color and
clear coats for appearance and protection  as well as in some
cases a midcoat  is the predominate  original equipment
manufacturer (OEM) topcoat system.  The appearance of these OEM
topcoats must be matched by the automotive refinish industry  and
consequently, the industry must use multiple coats in a topcoat
system.

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            Comments Concerning Regulatory Approaches

The RACT VOC Limits of the California Guideline for the Industry
Should be Selected as the RACT Limits for the CTG

The purpose of the CTG is to establish  technology that is the
presumptive norm for "reasonably available control technology"
(RACT) which must be implemented by states in their ozone
nonattainment areas.  EPA has defined (and Congress has accepted)
RACT to mean: "The lowest emission limitation that a particular
source is capable of meeting by the application of control
technology that is reasonably available considering technological
and economic feasibility.  RACT for a particular source is
determined on a case-by-case basis, considering the technological
and economic circumstances of the individual source.  (44 Federal
Register 53761, 53762 (September 17, 1979))

On the basis of this standard — a standard that emphasizes the
economic and technological feasibility of control technologies in
light of technological and economic circumstances of the
sources — the VOC limits that have been established by
California's Air Resources Board's  Automotive Refinish Guideline
for RACT under California's Clean Air Act (which has a much
tougher standard and program for ozone attainment than the
federal law) should be RACT for the national program.  (See
attached chart for the California Guideline RACT limits.)

While the terms "reasonably available" and "feasibility" are not
defined by the EPA, an ordinary dictionary definition of
"feasible" is something that is "capable of being used or dealt
with successfully;"  "available" has been defined in a manner
especially relevant to this discussion as "present in such
chemical or physical form as to be usable;"  and "reasonably"
has among its ordinary meanings "moderate, fair, and
inexpensive."  When the meanings of these terms are coupled with
the requirements of "economic and technological feasibility" and
the additional requirement that the feasibility of the control
technology be ascertained on the basis of the "economic and
technological circumstances of particular sources,"  then
whatever else RACT means, it certainly cannot mean  the
imposition of technology-foreing standards on existing sources.

The California RACT limits have much to recommend them for
adoption in the CTG.

First, by actual implementation in automotive refinish
facilities,  they have been proven to be currently "reasonably
available" and "technologically and economically" feasible.
Second, they have been established by the toughest clean air
program in the country.  In this connection,  we note that the

                                3

                            999

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California Clean Air Act has a much more stringent ozone design
value of .09 ppm  as compared to the federal standard of .12 ppm.

The attached chart represents a comparison of VOC reductions that
could be achieved by implementing the California Guideline's RACT
limits.

According to the Study's Own Findings. Option 1 and Option 2
Limits Are Technology-Forcing Standards; They. Therefore. Are
Completely Inappropriate for the CTG

By the study's own statements, Options 1 and 2 represent
"technology-forcing" VOC limits, requirements that are not
currently "reasonably available" as that term is defined by the
EPA.  Therefore, these options do not qualify as RACT.  Moreover,
if the base coat/clear coat composite calculation method is not
employed, then the limits specified for topcoats under both
Option 1 and Option 2 are not only  "technologically and
economically infeasible" for the "particular sources" of
automotive refinish facilities, they are absolutely impossible to
achieve with today's technology.

The study indicates that lacquer product systems are still widely
used by many of the smaller shops that do not have spray booths.
(See pages  2-7, 2-20 through 2-25 of the study.)  The study also
assumes that such shops constitute  approximately 30% of the
industry.  (See Table 2-1 at page 2-22.)  Moving these shops away
from lacquer products to other more difficult to use and slower
drying products will be difficult and very costly.  The
unmistakable implication of the topcoat limits of Options 1 and 2
is that a large number of the industry's smaller shops will be
put out of business.  The study estimates that the cost of a
spray booth would be approximately $30,000.  We believe that this
estimate is low.  And most of these shops are currently grossing
at most $150,000 per year.  Few if any banks, especially in
today's economic climate, would lend the amounts needed for such
a capital outlay to the smaller shops.  Consequently, topcoat
limits of Options 1 and 2 which would prevent the use of any
lacquer system  do not represent a "currently"  "reasonably
available control technology" as judged on the basis of
"technological and economic feasibility" of these "particular
sources."

The study also states that, "Option 1 VOC limit had the reported
disadvantage of poorly matching OEM colors (especially
metallics), indicating that they are best suited for complete
vehicle refinishing jobs."  (See page 3-4.)  In view of the fact
that the study also finds that the "... the OEMs use metallic and
*pearl' coatings on at least 50 percent of all new vehicles....";
it should be clear that the Option 1 VOC limits do not constitute
"reasonably available control technology" for this industry.
Establishing the Option 1 or 2 limits, according to the study's

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own findings and conclusions, would in effect mandate that a
larger proportion of the repairs be accomplished by complete
refinish jobs.  This would necessarily result in the emissions of
more, not less, VOCs and would fail to achieve the fundamental
objective of RACT — achieving reasonable further progress
towards attainment.  Additionally, there is the question of
whether establishing VOC limits that "poorly match OEM colors"
for 50% of the vehicles the industry repairs constitutes a
"technologically and economically feasible" control technology
for an industry that has as its sole reason for being the ability
to make repairs so that the repair is imperceptible.
The study also contains a number of misleading assumptions
concerning the VOC emissions that should be associated with the
industry's products and operations.  The first of these involves
assuming that the VOC content of products that are supplied to
areas which currently have regulations constitute the baseline
"current technology" of the industry's products that are
generally used in the United States.  (See Table 3-1 at page
3-6.)  In fact, the majority of the products supplied by the
manufacturers are to areas for which no VOC limits for their
products exist, including the vast majority of current ozone
nonattainment areas.  Defining baseline technology as the study
does would lead to  a gross understatement of the contributions
in VOC reductions that properly should be attributed to this
industry introducing lower VOC containing products to areas that
heretofore have not required  lower VOC containing products.  The
Act's new requirement for reducing by 15% overall VOC emissions
in the top four categories of ozone nonattainment areas by 1996
will place extraordinary pressures upon all sources to reduce
their fair share of VOC emissions.  Thus it is essential that the
CTG accurately characterize the existing VOC emissions from this
industry in these areas to ensure that it is not tasked with
regulations that exact an unreasonable contribution in VOC
emissions reductions.

Additional misleading statements and assumptions in the study
concern the following subjects:  the statement concerning current
usage of coatings that implies that all coatings material
supplied to refinishers are in fact applied, when approximately
20% — 25% in practice is wastage and is disposed of by
incineration in which there is no release of VOCs; overstatements
of the required or recommended film thicknesses; and
overstatements of the paint consumption in each of the coatings
categories.  These are more fully discussed in the submission
from BASF.

We anticipate the argument that since the  California Guideline
1992 limits are just around the corner and that since some of
these limits are more stringent than comparable limits in Option
1,  the manufacturers should be able to meet the limits of Option
1 nationwide if they can meet the California 1992 VOC limits in
California.  In answer to such an argument, we point out that the
                          1001

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products that are needed to meet some of these limits, especially
the topcoat limit, are still not yet at a stage of development
that would allow the manufacturers to introduce them into
facilities without substantial expenditures in time and
resources.  These products will require the use of spray booths,
which the study itself notes are not widely used by  the smaller
shops which makes up about 30% of the industry.  Moreover they
will require the use of drying equipment, because the products
will be .mostly waterborne products with substantially longer
drying times.  In order to maintain today's levels of
productivity in terms of the number of vehicles that are
completed substantial expenditures for drying equipment will be
required.

Finally there is a question of scale involved here.  It should be
noted that the California 1992 limits will be confined only to
certain air quality districts in California.  While the
manufacturers may have sufficient resources to weather the
problems and expenditures that will be associated with
introducing these products into  a limited number of areas in
California, imposing similar requirements nationwide results in
an effect on the manufacturers that certainly qualifies as
"economically infeasible."

We realize that the EPA is interested in crafting a GTG that
accurately reflects what can  be accomplished by the industry at
the time the CTG is published and that it is confronted with the
difficulty of a moving target in the technologies.  The six
manufacturers have expended literally tens of millions of dollars
thus far in efforts to develop lower VOC products and the EPA is
right to anticipate that these efforts will continue.  But this
problem  of RACT being overtaken by new developments is addressed
in the newly amended federal Clean Air Act which now requires
that the EPA periodically revisit CTGs to determine if technology
has moved ahead of existing CTG standards.  We'suggest that this
is the only appropriate process recognized by the Act for
introducing technology-foreing factors into developing CTGs.
Requiring technology-forcing limits in the CTG itself is
completely at variance with the essential "reasonably available"
nature of a RACT standard.

We have another suggestion by which this current effort to
determine an automotive refinish CTG could avail itself of new
technologies that might be available at the time this CTG is
finalized.  If this CTG development process takes until 1993 to
be finalized, it is possible that the experience gained in
meeting the California Guideline's 1992 limits in California will
demonstrate by then that the Option 1 .limits  and perhaps some of
the California 1992 limits are in fact "reasonably available" in
terms of their "economic and technological feasibility" for
national implementation.  We note, however, that, with respect to
the California 1992 limits, the industry at the present time
                            1002

-------
does not have a sealer that would meet the limit specified for
this coating.  Because of this and other potential problems of
introducing such advanced systems nationwide, at the present we
believe that a lead time for implementing such limits would be
needed, e.g., implementation in 1994 or 1995.

The Necessity of Base Coat/Clear Coat Averaging For Determining
the Topcoat Limits

The multiple coat system of topcoats is the current predominate
topcoat technology of the automotive manufacturing industry and
the refinish industry must be able to match these topcoats.
Using a composite calculation for the VOC content of the base
coat and clear coat in a topcoat system to determine compliance
with the topcoat VOC limit is dictated by the actual day-to-day
"technological and economic circumstances" and practices of the
industry.

A statement of the study which may account for the failure of the
CTG Model Rule to include  a base coat/clear coat composite
calculation method is an apparent misunderstanding  of the basis
for weighting base coats and clear coats at a ratio of 1 for base
coats to 2 for clear coats.  The ratio is based upon the actual
usage of the industry.  It is the industry experience that the
volume of base coat paint that is used for any given repair is
approximately on half the volume of clear coat that is used.  In
this connection we refer you to the information that has been
provided by the BASF Corporation which is based upon the actual
usages at an automotive refinish type of operation at the Saturn
General Motors plant and by the Sherwin Williams Company.   In
fact that experience indicates that the ratio is higher, e.g.,
for 1 gallon of base coat, 2.3 gallons of clear coat are used.
The study assumes that because clear coats are a higher solids
product than are base coats, then the volume of clear coat
material that is needed to repair the are covered by the base
coat should be twice  the volume of base coat material.  The
major reason  that the industry generally uses twice the amount
of clear coat material as it does base coat material is the need
to achieve adequate color and finish match for spot repairs that
requires that the clear coat in general be extended far beyond
the area covered by the base coat.  About 90% of the automotive
refinish work that is done is spot repair.

The Systems Nature of the Industry's Products

Because the chemistry of the individual components of a repair
system is highly interdependent, the components of a particular
manufacturer's system must be used according to its instructions
and cannot be interchanged with the products of another
manufacturer.  The systems nature of today's repair products has
two very important implications for a regulatory system that
limits the VOC content of the products.  First, regulators can
                           1003

-------
have a great deal of confidence that refinishers will not attempt
to match relatively higher VOC components of one manufacturer's
repair systems with those from another and that therefore the VOC
levels associated with a particular system will be complied with.
Secondly, the regulations cannot simply select the lowest VOC
components of the available repair systems and dictate that these
components be incorporated into every repair system.
and in the right amounts.  As a recent article from an automotive
refinishers professional magazine points out:

     [T]here is no margin for error in applying or mixing today's
     products.  The paint, company chemist was able to create a
     product to suit, but only if you do exactly as he says.  Not
     only must the painter combine the correct solvent, catalyst
     and topcoat in the correct percentages, but it must be
     applied over the correctly mixed undercoats at the correct
     time... There is only one  right way to use today's
     finishes; exactly according to directions and using only one
     brand.

Auto refinishers will not act as their own chemists; they will
follow the manufacturers' instructions or risk a failed job
without the protection of a warranty.

Another feature of the industry that supports the conclusion that
automotive refinishers will comply with the VOC limits specified
for products is the VOC compliance instruction material and the
training that is supplied by the manufacturers to users of their
products.

The Need for Specialty Coatings

It also is essential to recognize the need for relatively higher
VOC containing specialty coatings.  These products constitute a
very small percentage of the products used by the industry but
they are essential to effectively accomplishing certain repairs.
An important example of these are  "uniform finish blender"
specialty coatings to make spot repairs.  This specialty coating
blends the repaired area in with the surrounding original finish
to match all facets of its appearance, including color, metallic
orientation, texture, and appearance.  Greater VOC emissions
would occur if refinishers do not have the ability to perform
spot repairs because they would be required to paint an entire
panel of the vehicle or the entire vehicle itself in order to
achieve acceptable results.

We recognize that the model CTG includes the category of
"specialty coatings."  But its characterizing them as being
"reportedly" needed for unusual job performance requirements,
however, concerns us because that implies that the need of these
products is debatable. The special role of specialty coatings
should be emphasized by the CTG.  It should not be implicitly
                            1004

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questioned by the CTG which might invite states to modify the CTG
by removing the category.

We also recommend that the California Guideline's definition of
specialty coatings should be adopted.  The definition does not
limit the type of coatings that can fall into this category but
restricts the coatings to 5% the total volume of coatings applied
by an automotive refinish facility.  This approach allows for the
development of additional specialty coatings and the 5%
restrictions ensures that the category will not be abused.

The General Use of HVLP gpray Guns Results in Significant
Reductions of VOC Emissions and Should be Encouraged

The efficiency of transferring coatings to the vehicles has been
greatly improved by the use of high volume, low pressure (HVLP)
spray guns.  The resulting VOC reductions that accompany the
reduced amount of coatings material that is required because of
the improved transfer efficiency should be explicitly recognized
by the regulations.  To do otherwise deprives this industry of
having credited to it significant VOC reductions that in fact
result from the use of HVLP spray guns.  The unwillingness of the
EPA to explicitly recognize and to credit VOC reductions
associated with the use of the equipment is a hidebound adherence
to notions concerning "quantification" and "replicability" of VOC
emission reductions.  These principles were established for a
regulatory regime that focused on well-heeled and richly staffed
large stationary sources which lent themselves to such precise
demands for crediting VOC reductions.  The 1990 amendments to the
law, however, require the regulation of much smaller sources and
therefore the EPA's  VOC emissions reduction accreditation
principles must be retailored to measure the effectiveness of
regulatory controls that are appropriate for the much smaller
sources.

As the study notes, appropriate training has a great deal to do
with the efficacy of HVLP use.  In this connection,  it should be
recognized that extensive training is provided in this area by
the manufacturers of automotive refinish coatings and others.
Further,  aside from the regulatory requirement to use such
equipment, autorefinish facilities have a very strong economic
incentive to use the equipment to reduce their consumption of
coatings.

It also should be noted here that the study seems to assume a 35%
transfer efficiency for the conventional spray gun but is
unwilling to assume any transfer efficiency for the HVLP.  This
is anomalous in that any problems that are associated with
achieving effective transfer efficiency with the HVLP spray gun,
such as variability in operator use and the shape of the object
being coated, also apply to conventional spray guns.
                           1005

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The experience of the Coalition is that the use of HVLP spray
guns results in reductions of 20% — 45% in materials usage and
some credit for the resultant VOC reductions should be given.

Add-On Controls

The various engineering add-on control technologies identified by
the study for facilities would be cost prohibitive and or
technologically infeasible for the great majority of automotive
refinish facilities to adopt at this time.  Nonetheless, the
regulations should recognize such controls as voluntary
alternative control techniques that could be used in lieu of
lower VOC containing products.  The technology of add-on controls
could improve in the near future, perhaps rapidly,  and they
could come to represent cost-effective alternative compliance
methods.
                            Conclusion

The objective of the CTG is to establish a guideline for what is
the presumptive norm for "reasonably available control
technology" (RACT) under the federal Clean Air Act.  In
developing such a guideline, the "reasonableness" of the
technology is to be considered as well as both its
"technological" and "economic" feasibility.  On the basis of
these criteria and our knowledge of the industry — the available
coatings technology and the operational and economic requirements
of automotive refinish facilities — we believe that the VOC
limits specified for RACT in the California Guideline should be
the limits established by the CTG.  The adoption of these limits
from a program that is much tougher than the federal program will
ensure that the industry contributes more than its fair share of
VOC emissions reductions in the nation's ozone nonattainment
areas.  We also believe that specialty coatings must be
explicitly recognized as an essential technology for the industry
to achieve VOC emissions reductions.  Further, it is absolutely
critical that the multiple coat composite calculation technique
for determining compliance with VOC topcoat limits be recognized.
This is the way the industry applies the topcoats and it is the
only way that VOC limits for increasingly waterborne topcoats can
be met.  The contributions made by HVLP spray guns should also be
recognized by the CTG.  Finally add-on controls should be
recognized as a voluntary alternative compliance method.

The possibility that the Option 1 or even some of the California
Guideline's 1992 VOC limits may be demonstrated to be "reasonably
available" by the time the CTG is finalized in 1993 is also worth
considering.  The six manufacturers would concur in such an
approach provided that before the limits are adopted as part of
the CTG, the technology has in fact been shown to be reasonably
available and that an appropriate lead time is afforded (e.g.,
until 1994 or 1995) to ensure that the products in fact are
"reasonably available."

                                10

                              1006

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DRAFT CTG
COMPARISON OF VOC EMISSIONS REDUCTIONS

                        GARB'S GUIDELINE
Baseline
Coatina Cateaorv VOC*
Pretreatment Wash
Primers & Precoats 6.5
Primer Surfaces 4.8 - 5.7
Primer Sealers 4.6 - 5.6
Topcoats*** 5.2 - 6.0

Surface Cleaning 6.4
Enclosed Equipment
Cleaning 6.7
Specialty Coatings 7.0
Transfer Efficiency 35%
DRAFT CTG
Reduction Achieved -0-
% of
Total Coatings
Option 1 Ootion 2 CTG CARB Coatina Cateaorv
Pretreatment Wash
6.0 .15% 5.5 .31% 2% . 1% Primers
3.8 4.0% 2.1 7.6% 12% . 12% Primer/Primer
Surfaces
4.6 0.9% 4.6 0.9% 5% . 5% Primer Sealers
5.2 7.7% 4.5 14.5% 58% . 17% Topcoats***
Iridescent***
1.7 5.9% 1.7 5.9% 8% . 8% Surface Cleaning
Enclosed Equipment
85% 0.8% 85% 0.8% 10% . 10% Cleaning
7.0 0.0% 7.0 0.0% 5% . 5% Specialty Coatings
35% 0.0% 35% 0.0% . Transfer Efficiency
CARB GUIDELINE
18.6% 30.0% . Reductions Achieved
Baseline CARE'S
VOC RACT
6.
6.
6.
6.
6.
6.
6.
6.
7.
7
7
7
7
7
8
7
7
0
25%


6.5
6.5
6.0
6.0
6.0
6.0
1.7
88%
7.0
45%'

-0-
0
0
2
2
3
8
6
0
2
.1%
.1%
.3%
.3%
.2%
.7%
.0%
.8%
.8%
0.0%

26

.3%
GARB'S
1992 Limits**
6.5
6.5
2.8
3.5
5.0
5.0
1.7
98%
7.0
45%'


0
0
12
4
22
19
6
0
2
.1%
.1%
.6%
.3%
.8%
.5%
.0%
.8%
.8%
0.0%

69
II
.0% |
  *Baseline VOC set on controlled areas emission survey data.  Should be based on uncontrolled emissions  survey data.

**Technology forcing limits that can be added to CTG in 1994 - 1995 once technology has been demonstrated in California  in 1992 -
  1993.

***VOC limits based on composite multi-stage topcoat calculations.
l.*5*/z5x = *••" factors applied to VOC reduction categories in column expect for enclosed equipment cleaning and surface cleaning.

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COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

     Karl Schultzf National Paint and Coatings Association,
Automotive Refinish Coalition  (See attached Presentation  #1)

     Dr. Pinkerton noted that Mr. Schultz's estimate of 40
percent of shops having less than five employees did not  agree
with the CTG's figure of 10 percent.  Mr. Schultz said his
information was from a magazine survey and he thought it  was
accurate.  He suggested that the model shop analysis might
mislead States in that it misrepresents the industry (i.e.,
lacquer use may be underestimated for a given model shop).  He
noted that shops in this industry can not be pigeonholed; for
example, there are very small shops that specialize in high-
quality work.  Mr. Hise noted that if the magazine survey showed
shops with 5 or less employees, then the model shops could match
40 percent because they show a range of employees.  Ms. Ducey
commented that the number of employees is not used in EPA's
analysis, and does not have to be shown in the CTG.
     Dr. Pinkerton asked whether the Coalition agreed with the
estimate of 100,000 tons per year of VOC being emitted from body
shops in nonattainment areas.  Mr. Schultz said he had not seen
that estimate before, but guessed that it was probably close.
Dr. Pinkerton asked what national emission reductions would their
RACT (and 1992 limits) recommendations achieve.  Mr. Schultz said
they had not been calculated.  Mr. Arkell asked why, on the table
Mr. Schultz provided, the percent reductions in emissions with
CARB's 1990 RACT limits and 1992 limits are higher than EPA's
Option 1 and Option 2 percent reductions.  Mr. Schultz responded
that the differences in solids content per gallon paint were not
taken into consideration in their estimates.  The CARB values
take into consideration a TE of 25 percent for both the baseline
and the 1990 limits,  and a TE of 45 percent for the 1992  limits.
                                1
                            1008

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     Mr.  Arkell questioned whether the major factor in the
difference in percent reductions is the use of different baseline
values.   Mr.  Schultz felt that EPA's baseline is based on
controlled limits, and the Coalition's estimated baseline values
are higher.  He strongly disagreed with EPA's figure.  Mr. Hise
asked if the baseline values used by the Coalition were based on
1990 data.  Mr. Schultz said 1988 data were used.  An audience
member commented that the figure was based on sales, not
consumption.   He said the 1990 VOC coating data are not different
from the 1988 data, but sales have fallen.
     Dr.  Atkins asked if Mr. Schultz had said that compliance
with the 1992 GARB rules would require spray booths.  The answer
was yes;  the Coalition recognizes that shops without spray booths
would have difficulty using some coatings and that this will be a
huge adjustment for small shops.
     Mr.  Arkell questioned whether the California rule requires
65 percent TE.  The answer is yes.  Mr. Arkell than commented
that the discussion seems to keep coming back to TE, even though
EPA has said that it is too difficult to quantify.  He suggested
EPA look at it again.  Perhaps a percent reduction credit could
be given for TE.  He also inquired that if EPA can not quantify
TE, how is California doing it.  The response was that they can't
and are working on that problem now.  California recognizes that
it is a difficult problem, but they also know that success would
result in reductions in VOC's.  Mr. Dennison commented that
California defaulted to high-volume low-pressure (HVLP) spray
equipment, and said that other types of spray equipment would
have to demonstrate that they could achieve 65 percent TE.
Subsequently,  manufacturers of other types of spray equipment
have petitioned, and the State has had to defend the 65 percent
TE requirement which relies on a laboratory test procedure.
     Mr.  Schultz noted that another reason for strongly
suggesting that EPA use the California standards is because this
industry  is a  highly spread out, distribution-based industry and
it must have  uniform standards.  A can of paint can be in the
system for 3  to 5 years.  Multiple standards in the U. S. would
                                2
                            1009

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be unmanageable,-and the Coalition feels the California  standard
is stringent enough to be a national standard.
     Mr. Jordan asked Mr. Schultz to clarify whether he  was
recommending that EPA adopt the 1992 California  limits.  Mr.
Schultz responded that the Coalition is recommending that EPA use
the California RACT limits.  The 1992 limits are not "reasonably
available."  The Coalition would support the 1992 limits after
the products have been demonstrated successfully in California.
From a legal standpoint, the Coalition is concerned that if the
CTG becomes law (with the 1992 limits as RACT), and the  limits
are not achievable for all colors, States would not be able to
relax their State Implementation Plan (SIP) requirements.  He
suggested that if the CTG requirements were different from
California's, the coating manufacturers would be forced to
recommend that States ignore the CTG and use California's limits.
     Mr. Berry commented that the definition of RACT that the
Coalition keeps using is not complete.  The RACT does have a
technology-forcing aspect.
     Citing the fact that specialty coatings need a higher VOC
content, Mr. Dennison asked whether the coating manufacturers had
a time frame for reducing the VOC content of specialty coatings.
Mr. Schultz explained that the manufacturers formulate these
products at 7 Ibs VOC/gal for their unique properties and
applications.  If VOC content must be reduced, solids must be
increased and the paint layers could not be applied thinly
enough.  Mr. Dennison asked whether shops vary in their specialty
coating use.  Mr. Schultz replied that 99 percent of shops would
not exceed the 5 percent cap on their use, but there would be
some small specialty shops, such as van-converters, that might
have trouble with the limit.
     Mr. Dennison inquired about the recordkeeping burden.
Mr. Schultz said that the Coalition feels that it would be real
drain for small shops.   The 2-3 hours per day required for
recordkeeping would be unproductive time.  Mr. Dennison  asked
that if EPA did follow California's lead, would manufacturers be
willing to participate in some type of quantification program.

                            1010

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Mr.  Schultz responded that they do already.  The material safety
data sheets (MSDS) show VOC level.  Mr. Dennison asked whether
the MSDS also show VOC content less water.  The response was yes.
     Ms. Sheiman commented that recordkeeping and public
disclosure of emissions (not already done by this industry) might
go a long way in motivating voluntary compliance by shops and
lead to creative ways of reducing emissions.
     Mr. O'Sullivan asked if manufacturers would consider
developing some type of industry-wide certificate program for
operator training.  Mr. Schultz replied that they are already
looking into this.  The industry does not support distribution of
a product to persons who are not trained in its use.  The
industry is looking at how best to certify operators and the need
for training materials.
     Mr. Berry inguired about how the OEM's ensure that colors
can be matched by refinishers.  Mr. Schultz's answer was that OEM
colors are selected 3-4 years in advance, and properties such as
their handling and consistency are checked.  The colors are also
analyzed for their repair capabilities.  They do sometimes find
that a color can not be matched in refinishing.  Mr. Berry
suggested that the worst thing that could happen (from selection
of any limit) is that it might restrict the designer's future
color choices.  Further, some existing cars would have to be
completely repainted rather than spot repaired because the color
could not be matched.  Mr. Schultz replied that the entire car
may not have to be completely repainted, but at least a larger
area would have to be repainted.
                             1011
                                4

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Industry Presentation #2

BASF Corporation                                    BASF
                                                    Automotive Reflnlshlng
 November 1, 1991
 Mr- Bruce C. Jordan
 Director, Emission Standards Division  (MD-13)
 Office of Air Quality Planning and Standards
 U.S. Environmental Protection Agency
 Research Triangle Park, NC  27711

 Dear Mr. Jordan:

 On behalf of BASF Corporation, I am submitting  the   following  com-
 mentary regarding the September 27, 1991  Draft  of   "Automobile  Re-
 finishing Control Techniques Guideline",  which  you  indicate will be
 the key information source for determination of Reasonable  Avail-
 able  Control Technology (RACT), and subsequent development of con-
 trol  technique guidelines for  regulation of the   volatile organic
 compound (V.O.C.) emissions from the Automobile Refinish  industry.

 In  general, we feel the draft represents an honest attempt to por-
 tray  our industry and does  a good job of  describing  the refinish
 process.  However, there are what we feel to be inaccuracies  that
 tend  to grossly overstate  the industry's contribution  to  V.O.C.
 inventories  that I would like to address, plus present data to you
 that  will substantiate the  use of numerical   averaging  of  V.O.C.
 calculations for multi-stage topcoat systems.

 Major Issues

 I.    The September 27, 1991 Draft does not acknowledge  the  use  of
      numerical  averaging of multi-stage  topcoat systems  for deter-
      mination of V.O.C. content.  Rationale given in the  text  (Page
      3-8)  is that the author felt a "potential" problem  may  exist
      with the equations used to determine the average  V.O.C.  con-
      tent of the combined coatings, in that twice as much clearcoat
      as basecoat may not be needed to cover a given  surface  area.
      Many current state regulations acknowledge the basecoat/clear-
      coat  averaging concept and utilize  the following  equation  for
      calculation of a two-stage topcoat system.



                            1012
19855 West Outer Drive Suite 401 East Dearborn. Michigan 48124 (313) 561-9100

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Page


     V.O.C. r  = V.O.C.    "*" 2 V.O.C.
     Where:    V.O.C. T  =    Total V.O.C.  Content

               V.O.C. BC =    V.O.C. Content  of  Basecoat

               V.O.C. cc ~    V.O.C. Content  of  Clearcoat

The  author of the Draft ; makes the erroneous assumption  that this
equation  was derived from the  ratio of the  dry film thickness of
the  two components  (see  Page 3-7).  In   fact,  the ratios  are not
based  on dry film, but  rather on paint consumption  ratios of two
parts by volume of clearcoat to one part of basecoat.

BASF states in its product literature for  basecoat  clearcoat  sys-
tems to apply the following on each component:

                                APPROXIMATE
                  NUMBER           FILM
                  COATS	   THICKNESS

Basecoat       2-4 Light Coats    0.7 Mils

Clearcoat      2-4 Heavy Coats    2.5 Mils

Material usage ratios under these conditions  actually result  in  a
higher than 2:1 ratio.  This can be substantiated by data collected
by General Motors at their final line repair  area of  their  Saturn
assembly plant in Spring Hill, Tennessee.   The repair  facility  at
Saturn  is basically  a "refinish  shop" and   utilizes our  Diamont
refinish basecoat/clearcoat system.  Material usage at this line is
recorded  on a "material applied"  basis at application.  The  data
below  represents a three  month usage study   conducted earlier  in
1991.

Basecoat/Clearcoat Applied

39.15 Liters Reduced (RFU) Basecoat

89.98 Liters Reduced (RFU) Clearcoat

This  yields a clearcoat/basecoat usage  ratio of 2.30:1, which  is
very favprable compared to the 2:1 ratio for   theoretical  calcula-
tions in B.A.A.Q.M.D. Rule 45, CARS SCM recommendations  and  other
state regulations.

To  further substantiate basecoat/clearcoat usage  ratios, BASF re-
cently did a study on car shells at our Whitehouse,  Ohio  Applica-
tion Facility.  The study was conducted using both conventional air
assisted spray guns and the more efficient HVLP  gun.  Vehicles used
in the study were Caprice Classics, which  are representative  of  a
large size car.  The study also compared usage ratio  for  complete
and  spot repairing.  The study utilized a high  solids (4.4 V.O.C.)
clearcoat with a low solids (6.4 V.O.C.) basecoat so that the worse
case usage ratios would be developed.

                             1013

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Page -3-
Results
     Complete Repainting

     A.   Conventional Air Assisted Gun

          Basecoat                 -



          Guq


          Basecoat Application

          Basecoat Material Usage  -

          Clearcoat                -


          Clearcoat Application

          Clearcoat Usage

          Film Thickness           -
     B.
                              Diamont  Blue  Metallic re-
                              duced  1:0.75 with BR60 re-
                              ducer

                              Sata  Jet Gravity feed  set
                              at 85 PSI

                              Two  medium coats to hiding

                              0.38 gallons

                              Diamont  DC90 2:1 with DH51
                              hardener
                              Two wet coats

                              0.83 gallons

                                  SIDE
HOOD
                              Basecoat
                              Clear
                               1.0 Mils   0.7 Mils

                               2.9        3.5

Volume Ratio Clearcoat :  Basecoat = 0.83:0.38 = 2.18:1

HVLP Spray Gun

Basecoat                 -    Diamont  Blue  Metallic re-
                              duced  1:0.75 with BR60 re-
                              ducer
          Gun

          Basecoat Application

          Basecoat Material  Usage

          Clearcoat


          Clearcoat Application

          Clearcoat Usage

          Film Thickness

                        Basecoat
                        Clear
                              Mattson DC set at 6.0 PSI

                              Two medium coats

                              0.32 gallons

                              Diamont  DC90 2:1 with DH51
                              hardener

                              Two medium coats

                              0.69 gallons

                                SIDE           HOOD
                              0.6 Mils
                              2.1
                              2.7
0.6 Mils
2.9
3.5
                            1014

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page -4-



          Volume Ratio Clearcoat ;  Basecoat = 0.69:0.32 = 2.16:1

2.    Spot Repair

     One  of the most  widely used  technique  for painting a  panel
     with minor damage is to "spot" repair the area.   In  the  case
     of  spot repair, one  of the most  critical qualities the re-
     finish  coating must possess is  the ability to  be  applied  in
     such a fashion that results in the repair area being undetect-
     able from the surrounding original finish in all facets of ap-
     pearance;  including color,  metallic orientation,   texture and
     gloss.   The most popular procedure for spot repairing a base-
     coat/clearcoat finish is to color coat only the  portion of the
     panel  that was damaged and then, in order to  maintain gloss
     and texture, clear coat the entire panel.

     The following technique was used to simulate a  "spot"  repair
     on a vehicle at our Whitehouse,  Ohio facility.

          A.    Spot prime a 2 x 2 foot area on a rear quarter panel
               to simulate the damaged area.

          B.    Color coat with basecoat the "repair"  area,  blending
               out into undamaged portion of the panel.

          C.    Clearcoat the entire panel.

     The  following represents material usage of basecoat and clear
     for the above process.

          Basecoat                 -    Diamont  Blue  Metallic re-
                                        duced 1:0.75  with BR60

          Clearcoat                -    DC90 clear 2:1  with DH51

          Basecoat Usage           -    0.0186 gallon

          Clearcoat                -    0.068 gallons

          Clearcoat:  Basecoat Usage = 0.68:0186 = 3.61:1
                           1015

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Page -5-


     CONCLUSION

     For   BASF,  and  probably  all   other coating suppliers,  the  2:1
     ratio of  clearcoat  to basecoat used on  calculations  for com-
     bined  basecoat/clearcoat V.O.C. actually represents an under-
     statement   of  clearcoat usage.   Since,  to my  knowledge,  no
     commercial  basecoats meet the topcoat  V.O.C.  requirements of
     either Option  I  (5.2  V.O.C.) or option   II (4.5  V.O.C.),  we
     feel  the  topcoat  V.O.C.  requirements  in the  proposal   without
     allowing  basecoat/clearcoat averaging do  not represent reason-
     ably   attainable  control  technology.    The  proposal  should
     therefore either  be modified  to allow averaging, or the V.O.C.
     standards  for  topcoats  should be  raised to  minimum of  6.2
     pounds/gallon.

II.  Option II,  even  with  basecoat/clearcoat  averaging  allowed,
     does   not meet  the  criteria  of Reasonably  Attainable Control
     Technology (RACT) in the area of Pre-Treatment Wash Primer and
     Topcoats,  as the  proposal is  based on  unavailable  technology
     in both areas.

     o     Pre-treatment  requirement of 5.5  pounds/gallon V.O.C.  is
           not   available.   Current  technology is  in   the 6.0-6.5
           range  and chemistry used for  this  type of product does
           not  readily  lend itself  to lower levels.

     o     Topcoat V.O.C. of  4.5 pounds/gallon is not currently at-
           tainable   for  either  metallic  single  stage  colors  or
           multi-stage  topcoat systems even with numerical averaging
           allowed for  the multi-stage systems.

     Recommendation

     Option II does not represent RACT and  therefore should not be
     considered   as  an alternative.   Option I is  acceptable, pro-
     vided multi-stage V.O.C. averaging is allowed.

III. Several questionable assumptions were made in determination of
     Emission  Estimation Techniques in Section 4.0.  These lead to
     a gross overstatement of material usage and subsequently leave
     one to believe  the  industry contributes far more   V.O.C.  than
     it actually  does.

     A.    Section 4.2.1  (Page 4-3) states  "The assumption  is made
           that  all  coating mixed  for the  job  is sprayed and there-
           fore  no emissions  are   attributed to waste   paint."  The
           last  thing  a  painter  wants to  happen  is to run  out of
           paint in the middle of a job.  As  a  consequence,  standard
           practice   is to reduce   at least 25%  more material than
           what  is required and to scrap the overage.   Since by law
           the remaining  material is a hazardous waste,  it is usual-
           ly disposed  of by incineration and consequently,  does not
           contribute to  V.O.C. in  the atmosphere.
                            1016

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Page -6-
     B.   The  film thickness stated  in Section 4.2.1  (Pages 4-5)
          are  overstated compared to what BASF recommends for fin-
          ishes  in  each  category.  The  following represents our
          recommendations compared to what is stated in the draft.

                     FIIH THICKNESS REQUIRED

                                       DRAFT   BASF RECOMMENDATION

          Pre-Treatraent/Pre-Coat     1.0  Mils    0.3-0.5 Mils
          Primer Surfacer            2.25 Mils    2.0     Mils
          Primer Sealer              1.75 Mils    1.0-1.5 Mils
          Topcoat                    3.5  Mils    2.0-3.5 Mils

     C.   Table  4-2 (Pages 4-6) grossly  overstates paint consump-
          tion for each of the coating categories.

          1.    The table suggests 1.6 gallons of pre-coat  or  pre-
               treatment primer is used for a complete  paint  job.
               By  definition  pre-treatment and  pre-coat are only
               used over bare metal areas of the job.    Unless  the
               repaint  is over a completely stripped surface,  only
               3-6  oz. would normally be used.  Even if the job was
               complete  bare  metal, pre-treatment/pre-coat  usage
               would not exceed 0.4 gallons!

          2.    Table  suggests primer surfacer usage  to be 1.2-2.0
               gallons  for complete paint job.   Normal practice is
               to  only apply over poor substrate.   Under this  con-
               dition  only approximately 8 oz.   would be utilized.
               If  complete job were  to be primed   usage would  be
               0.5-1.0  gallons,  depending  on quality  of  primer
               used.

          3.    Table  suggests  sealer  usage of  0.8-1.5  gallons.
               Normal  practice would be to  use approximately  0.25
               gallons of sealer on a complete repaint.

          4.    Table  suggests 2.2-3.8 gallons of  topcoat consumed
               for  a complete paint job.   Actual usage is 1.2-1.75
               gallons.

          5.    Baseline data for topcoat paint consumption given in
               Table 4-2 (Pages 4-6)  is contradictory to that given
               in Table 4-3 (Pages 4-10).   Topcoat  usage per car in
               Table 4-2 is 2.2-3.8 gallons.   Table 4-3 states  1.8-
               3.8 gallons.

     Conclusion

     Data  presented in  Section 4.0  is not  accurate and  grossly
     overstates the baseline V.O.C. contribution for all categories
     of shops in the study.  Therefore,  any of the  analysis utiliz-
     ing  this data as a  baseline is suspect.  This  includes  both
     economic and emission reduction analysis that  are presented in
     the draft.

                           1017

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Page -7-


MINOR ISSUES

I.   Transfer Efficiency

     The draft acknowledges  the  benefits of High Volume   Low  Pres-
     sure spray equipment  in reducing V.O.C.  due to  higher transfer
     efficiency than what  can be achieved by conventional  air as-
     sisted  spray.  However, transfer  efficiency is  not  incorpo-
     rated in the CTG as the author  felt it would be  difficult  to
     control due to variability  of factors such as   coatings  used,
     shape of part and operator  skill.   We acknowledge that the ac-
     tual transfer efficiency will be the result of  a  host of  vari-
     ables  such as operator skill,  size and shape of  part and sur-
     rounding  air velocities.   However,  under any conceivable con-
     dition  there will always be significant advantages  in reduced
     paint usage with HVLP vs. conventional air  atomized  applica-
     tion.   This will range between 20-45%  reduction in material
     usage.

     Recommendation

     We suggest transfer efficiency  be  incorporated  into   the  CTG,
     if not at the upper level the document should   acknowledge  at
     least  a 20% reduction  in paint consumption and with that mag-
     nitude of V.O.C. reduction  require  the use of HVLP or compara-
     ble high transfer efficiency spray  equipment.

II.  Section  2.5.1 (Pages 2-12)  states  Convention Airless  Spray is
     the standard method of  applying coatings in the  refinish  in-
     dustry.  This is a mis-characterization, as to  my   knowledge,
     no  refinish  shops  utilize airless   spray.  The conventional
     means of application  is air  atomized  spray.

III. Section  3.5.3 promotes the  use  of  Biofiltration  as  a  cost ef-
     fective alternative for V.O.C.  control in the   automobile  re-
     finish  industry.   Although the  technology appears to have po-
     tential merit, the fact is  it has never been, to my  knowledge,
     trialed  let alone proven   for  spray  applied  coatings.  Obvi-
     ously,   this  approach  needs considerable  investigation  and
     should  not at this time be considered as representing reason-
     ably attainable control technology.

     Recommendation

     Remove any reference to Biofiltration  from the  CTG unless evi-
     dence  is available the  technology meets the   requirements of
     RACT.

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Page -8-


We  acknowledge  and appreciate  the efforts of  the EPA staff  who
worked on the preparation of the September 27, 1991 Draft for Auto-
motive  Refinishing Control Techniques  Guideline.   The purpose  of
this letter is not to antagonize their efforts, but rather to point
out serious concerns with critical portions of the text.  My desire
and those of my colleagues on the Refinish Coalition is to  aid  in
the  development of a fair and reasonable CTG for our industry.  If
you or any other members of your staff wish to have further discus-
sions  on the issues prior  to the November 21,  1991 NAPCTAC meet-
ing, feel free to contact me.

Sincerely/

BASF CORPORATION
Coatings & Colorants Division
Robert J. Inglis
Director Product Planning

RJI/sep
pc:  D.   Guyomard
     H.J. Robinson
     R.   Sappok
                           1019

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COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

Bob Inglisf BASF Corporation   (See attached Presentation  #2)

     Ms. Mclntire inquired where BASF's estimate that HVLP spray
equipment can improve TE by 20-45 percent came from.  Mr. Inglis
said it was determined through investigations and in practice.
Transfer efficiency does vary by operator and by gun, however, so
you can't just categorize an HVLP gun.  In fact, the same thing
applies to conventional guns.  Ms. Mclntire then asked if TE is
measured by paint consumption.  The answer is yes.  Ms. Mclntire
asked if a standard were to require a certain TE, would shops be
required to maintain records of paint use before and after using
HVLP guns.  Mr. Inglis responded that would be one approach.
There is a definite correlation between paint use and use of HVLP
equipment, and you could establish a ratio.  Operator variability
would be the same in either case.
     Ms. Mclntire asked if manufacturers would be willing to help
small shops in measuring TE.  She also inquired as to how a
baseline would be set.  Mr. Inglis responded that manufacturers
would be willing to work with EPA in setting a baseline.  He
noted that HVLP does improve TE and this should be recognized.
     Mr. Berry requested that Mr. Inglis define "compliant high
TE spray equipment."  He noted that California only says to use
HVLP, which he has heard has difficulty breaking up high-solids
coatings.  California requires the use of HVLP or electrostatic,
and other types of spray equipment are required to prove they can
achieve 65 percent TE.  The question was raised about why HVLP
does not have to prove 65 percent.  California is now in the
process of conducting laboratory tests to allow equipment
manufacturers to prove that their equipment can achieve
65 percent TE, at which point it will be approved for use.  Mr.
Berry stated that HVLP is "directionally" correct, but TE cannot

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be quantified.  Further, someone who already has high TE with
conventional spray equipment would not get credit, while a
careless painter who does not get good TE would get the credit
merely because he uses HVLP.
     Mr. Dennison noted that the definition of HVLP is still an
open issue in California.-  Mr. Berry pointed out that as you
reduce air pressure, the painter has to stand closer to the part
being painted.  This in itself improves TE.  Further, high air
flows in spray booths adversely affect HVLP TE.  Mr. Inglis noted
that the same is true if you use conventional spray equipment.
     In reference to the comment that EPA overestimated paint
use, Ms. Mclntire asked how film thickness is measured.
Mr. Inglis replied that there are measuring devices (gauges) that
are easy to use.  Mr. Jordan asked whether a painter could
achieve the very thin mil thicknesses that the coating
manufacturers recommend.  Mr. Inglis replied that they could.
Mr. Jordan noted that he knew from experience that paint shops do
not use the small amounts cited by BASF.
     Mr. Taranto observed that the coating manufacturers raise
some good questions about the baseline data and estimated
emission reductions.  He requested that EPA work with industry on
this issue, especially because the Coalition's projections are
very different from EPA's.  Mr. Inglis noted that the baseline
data are important, but the coating manufacturers are primarily
interested in developing a meaningful, liveable CTG.
     Mr. O'Sullivan asked whether the statement is correct that
even in small shops the extra 25 percent of paint that is mixed
is incinerated and whether coating manufacturers offer this
service.  Mr. Inglis replied that BASF does not offer this
service but the Resource Conservation and Recovery Act (RCRA)
requirements must be followed by shops.
     Mr. Dennison noted that the discussion of using the topcoat
averaging equation seems to indicate that the basecoat limit is
too strict and the clearcoat limit is lenient.  How could
compliance be determined if the standard was based on averaging?
The answer is by recording coating usage.  Mr. Dennison noted
                             1021
                                2

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that it would be very difficult for a regulating agency to
determine compliance solely based on coating usage.  EPA should
strive to profile the industry as best as possible and minimize
recordkeeping.  Shops should only be required to show that they
use compliant coatings, regardless of how much they use.

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                                     s
                                 November 5,  1991
                                    JPK 91-296
    Mr. Bruce Jordan
    Director of Emissions Standards  Division (MD-13)
    Office- of Air Quality Planning and Standards
    U.S. EPA
    Research Triangle Park, NC   27711

    Dear Mr. Jordan:

    REF:   Draft Document -- Automobile Refinishing Control  Techniques
                            Guidelines Dated September 27,  1991

    On behalf of Safety-Kleen,  I would like  to  thank  the  U.S.  EPA Advisory
    Committee for the opportunity  to comment publicly on  the proposed
    Automobile Refinishing Control Techniques Guidelines.

    Safety-Kleen is a company dedicated to the  recovery and recycling  of
    solvents, thereby reducing  the environmental  impacts  of the  manufacture
    of new materials and the potential environmental  impacts of  disposal.

    We would like to submit the  following comments for consideration in  a
    final  CTG:

    A)     Spray Gun and Equipment  Cleaner Variations

    One of our products, the Model 1107 Paint Gun and Equipment  Cleaner, is
    referred to in the CTG under discussion.  In  Section  2.6 --  Cleaning
    Equipment -- the draft CTG discusses two types of gun cleaners  --an
    enclosed gun cleaner, and an open  gun cleaner.

    In reference to the enclosed gun cleaner, the draft CTG discusses
    "closed" without complete definition of  the meaning of  the word
    "closed".  The enclosed gun  cleaners currently available are "closed"
    only in that they have a lid.  They do not provide a  vapor-tight
    closure, as implied in the discussion.   Additionally, enclosed gun
    cleaners are available in two  significantly different variations:

    1)     In the simplest configuration, an  enclosed  gun  cleaner uses  only
           recirculated solvent and rinses the passages, ports  and exterior
           of the paint gun and paint cup.  This configuration  does  not
          provide  a final rinse of  virgin material to assure  that  residuals
          are purged from the fine passages  and ports of  the paint  gun.
777 BIG TIMBER ROAD         ELGIN. ILLINOIS 60123         PHONE 708/887-8460         FAX 708/697-1295

                                  1023

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U.S. EPA, November 5, 1991, page 2
2)    An alternate version of an enclosed gun cleaner contains a second
      reservoir which allows for a final rinse of clean material.  The
      clean material is then mixed with the recirculated material and
      used until che it is too contaminated for further use.

The Safety-Kleen Model 1107 described in figure 2-4 in the draft CTG,
provides for both recirculated gross cleaning of the spray gun and cup
and for a clean solvent rinse of the gun and cup to minimize the
potential for contamination of subsequently used paint.

It is important to note that test data provided to the U.S. EPA and
gathered by an independent third party with supervision by the South
Coast Air Quality Management .District of California, indicated that the
use of an open gun cleaner, specifically the Safety-Kleen Model 1107,
resulted in emissions that were significantly less than several gun
cleaners that were identified as enclosed systems.

There is a third type of system available which uses line pressure to
purge a spray gun and cup that has been reviewed by the South Coast Air
Quality Management District and is, I believe, also allowed by its
regulations.  This system is manufactured by LighthalL Industries, and
may be of interest to the Agency for inclusion in the CTG.

B)    Paint Cups

In Section 2.6, reference is made to the use of plastic,  rather than
metal paint pots, for spray gun cleaning with the indication that
plastic may be easier to clean than metal surfaces.  This suggestion
may, in fact, be misleading in that several polyethylene plastic paint
pots can become crazed over time and be, in fact, more difficult to
clean.  Further, there are several metal paint pots currently available
with Teflon coating on the interior.   The Teflon-coated paint pot is
extraordinarily easy to clean and allows for very efficient drainage of
solvents after cleaning, maximizing solvent recovery.

C)    Automatic Vs.  Manual Systems

In Section 2.8.2, entitled "Model Shop Equipment*, reference is made to
the presence or absence of "automatic gun cleaning equipment".  We
suggest that the use of the word "automatic gun cleaner" is exclusive of
the two aforementioned manual products.   We suggest that the use of the
words "gun cleaning system" be included, and exclude the potentially
misleading adjective "automatic".  The use of the word "automatic" or
"automated" appears throughout several portions of the draft CTG, and we
request that it be corrected throughout the draft.  Furthermore, single-
stage, automatic closed units may require a final rinse with clean
solvent that is necessarily done external to the unit.
                               1024

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U.S. EPA, November  5,  1991, page  3
D)    Vapor Tight

In Section 6.2, Definitions,  the definition for gun cleaner states:  "A
device made specifically  to clean paint from spray guns which
recirculates solvent to clean a succession of times and is vapor-tight
when  in use.*

No gun cleaner on the market  today is vapor-tight when in use.  Even the
described enclosed gun cleaners are not vapor-tight and emit significant
amounts of volatile organic compounds when they are being used and
subsequent to use.  These losses can be described as "active" losses
during use and "passive"  losses when the product is not being used.
Data  supplied to the Agency has indicated that the use of open systems,
such  as the aforementioned Safety-Kleen Model 1107, are, in fact, more
efficient in reducing emissions in both the active and passive phases.

We suggest that the definition of gun cleaner read:  "A device made
specifically to clean paint from spray guns which recirculates solvent
to clean a succession of  times and minimizes the loss of solvent into
the atmosphere through a  recovery technology".

E)    RACT Considerations

In Section 6.6.2, Gun Cleaners, under Section 6 -- Factors to Consider
When  Implementing Reasonably Available Control Technology - - four
suggestions are made to states:

o     It is suggested that states approve only those gun cleaners that:
      1)    Recirculate the solvent used during the cleaning process,  so
            that the solvent  is used to clean a number of guns before
            being disposed;
      2)    Collect the spent solvent in a manner than insures it is
            available for disposal;
      3)    Are vapor-tight during the cleaning process:
      4)    Meet applicable fire,  safety, and occupational safety and
            health codes, laws, and regulations both in design and in
            the manner in which it can be used.

o     State regulations should specify that the facility is accountable
      for spent solvent from the gun cleaner.   It must not be allowed to
      evaporate.   Documentation must be available to support that it has
      been released to a licensed reclaiming or hazardous waste
      management facility.

Point three requires a system be vapor-tight during the cleaning
process.   This is not consistent with the suggested definition for a gun
cleaner hereinabove,  but, more importantly, it is not consistent with
comments made in Section 3.4,  Emission Reductions From Gun Cleaning, in
which the Agency indicates that equipment is currently available that
                             1025

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U.S. EPA, November 5, 1991, page 4
can reduce solvent consumption, evaporation, and worker exposure.  The
Agency further suggests that gun cleaners can be enclosed or open and
cites a report obtained during the CTG investigation that some open gun
cleaners emitted no more VOC" s than enclosed gun cleaners .

F)    Health Considerations

It is important to note that the use of enclosed gun cleaners, when
compared to open gun cleaners, may pose significant exposure and health
effects that are solved with certain open systems.  In this regard, an
open system, such as the -Safety-Kleen Model 1107, may be both safer to
the user and less damaging to the environment.  (See attached ENSR study
on Evaluation of Worker Exposure to Organic Vapors while Operating Paint
Spray Gun Cleaners . )

Should the Agency require clarification of any of the above comments,  I
would be happy to elaborate.  I plan to attend the meeting on the draft
Auto Body Refinishing CTG Document on November 21, 1991.

Once again, thank you for the opportunity to participate in the
development of this CTG.
JoRn Paul Kusz
Manager, Product Development

JPK/pJ

Encl.

cc :   CAATF
     Mike Callahan
     Jim Sanseverino
     REG/TEST/U.S. EPA

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COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

John Kusz. Safety Kleen (see attached Presentation #3)

     Mr.  O'Sullivan asked if there is any estimate of the
percentage of small shops that deliver their spent solvent to
reclaiming facilities.   Mr.  Kusz said it is hard to give a
definitive answer.  The numbers are expected to be different in
different regions, e.g., the percentage would be greater in
California and in more commercial areas.  Mr. O'Sullivan wanted
to know what percent of the market Safety-Kleen services.
Mr. Kusz preferred not to make that public knowledge, but said
that some information has already been provided to EPA.
                             1027
                                i

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Industry Presentation #4
                   PRESENTATION OF




                        THE




       NATIONAL AUTOMOBILE DEALERS ASSOCIATION




                     BEFORE THE




         U.S.  ENVIRONMENTAL PROTECTION AGENCY




                         BY




                 DOUGLAS I. GREENHAUS




         SENIOR ATTORNEY,  REGULATORY AFFAIRS




                         ON




                  NOVEMBER 21,  1991
                      1928

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     Good morning.  My name is Douglas  I.  Greenhaus and I am the
Senior Attorney for Regulatory Affairs for the National Automobile
Dealers Association (NADA).  It is my pleasure to appear before you
today to present NADA's views  on the U.S. Environmental Protection
Agency's  (EPA)  draft Automobile  Refinishing Control  Techniques
Guideline (CTG).

     NADA is a national trade  association representing over 19,000
franchised car and truck  dealers across the country.  NADA members
are primarily  engaged  in the retail sale  of new  and  used motor
vehicles, both foreign and domestically produced.  NADA members are
also engaged in automotive service repair and parts sales.

     EPA's draft CTG on automotive refinishing is of considerable
importance to  the automobile dealership  body.   NADA's  Industry
Analysis division estimates that  dealership  automobile  and truck
refinishing  operations   account   for  roughly one   third  of  all
autobody sales.   In addition, approximately  sixty  percent of new
vehicle dealerships operate  formal autobody repair and  painting
operations.   In total,  it is estimated that dealership  autobody
departments employ some 103,000 people in 13,500 facilities with an
average of 8 employees per department.

     The average NADA dealership  employees 40 persons  in total.
In addition, over eighty percent of NADA's members are considered
small businesses by the Small  Business Administration.  Given that
                                2
                          1029

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the  refinishing  CTG will  substantially  impact  small  business
refinishing operations,  NADA  is actively working with EPA on the
development of guidelines for the implementation of Section 507 of
the Act.

     NADA  previously provided  EPA  with information  in order to
assist  with the  CTG development process.   In  early 1988,  NADA
submitted the results of a comprehensive membership survey of paint
and coating material use rates.  Earlier this year,  NADA submitted
comments on EPA's Revised Summary of Automotive  Refinishing Model
Shop Emission Costs.  The following comments specifically address
the September 27 draft  CTG.

A.   Surface Preparation
     NADA supports the inclusion of controls on surface preparation
products.     However,   NADA   submits   that  EPA  significantly
underestimates the costs associated with using lower  solvent
content preparation  materials.   It is clear  that the  use of these
materials will take  some amount  of applicator  retraining and will
require  additional time to achieve the same  benefits  as higher
solvent  content  counterparts.    EPA   fails  to   include  these
significant costs  in its analysis.

     With  respect to emissions reduction,  NADA  suggests that the
draft CTG  fails to consider whether lower  solvent  content surface
preparation materials aren't  used in greater quantities. EPA also

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fails to recognize that solvent volatilization  is proportionate to
the amount of time the preparation product remains on the surface
and to  recognize  that not all  of the  VOC's  in  higher solvent
content materials  become airborne prior to being wiped off the
surface being prepared.  In summary, EPA overstates the  emissions
baseline for surface preparation materials.

B.   Coating Applications
     NADA  supports  the  two   option  approach to  paint  system
regulation.  However, NADA is very concerned about the values EPA
has selected.  Obviously, the values selected for each option are
of critical importance to the refinishing industry.  Without proper
paint system quality and  color match capability,  auto refinish
operations will be unable to adequately service their customers.
NADA suggests that EPA consider adopting  the values set out in the
California Air Resources Board Regulation and endorses the National
Paint and Coating Association's comments on that issue.

     Lower solvent content coating systems  are expected to require
considerable applicator retraining.   In  addition,  it is expected
that surface areas will take longer to paint and that drying times
will be longer.  All of these important costs must be factored into
EPA's impact analysis.

     NADA  strongly  supports   EPA's  decision  not to  include  a
transfer efficiency requirement in its CTG. On the otherhand, EPA

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must recognize some VOC emissions reduction benefits attributable
to those shops using improved transfer efficiency.  It is reasnable
to expect that, as reformulated paint systems  become more costly,
facility operators will begin to turn to higher transfer efficiency
equipment in order to reduce costs.

     EPA's  discussion  of higher  transfer  efficiency  fails to
reflect the significant retraining costs involved and the potential
for longer  painting  times,  both  of which are  critical  factors to
the refinishing industry.

C.  Gun Cleaning
     NADA supports the  inclusion of a gun cleaning requirement in
the CTG.  At the same time it is clear that EPA overestimates the
baseline  for this  option and thus  the potential  for  emissions
reduction.   A significant and increasing  source  of  gun cleaning
solvent results from the  in-house distillation of waste paint and
solvent materials.  To count this recycled  solvent in an emissions
baseline would be redundant.  Likewise, the cost  savings shown by
EPA  for gun  washers is  also  erroneous in  light of the use of
recycled gun wash solvent.

     It is also inappropriate for EPA to assume that all the  spent
solvent used to clean guns is fully evaporated  in those shops  which
do not use gun cleaners.  Whether destined for on-site distillation
or  off-site management,  spent  gun wash  is not  left  to totally

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evaporate in the typical automotive refinishing facility.

D.   Add-On Controls
     NAOA strongly objects to the inclusion of add-on controls in
the proposed CTG.  EPA's impact analysis shows that add-on controls
are  not  currently  available  for  the  automotive  refinishing
industry.  In addition,  EPA's data show add-on controls to be from
six  (carbon  adsorption)  to over fourteen  (incinerator)  times as
expensive as surface coating system solvent control alternatives.
On  the  other hand,  add-on controls result  in,  at best,  only a
marginally superior reduction in VOC emissions.

     EPA's  suggestion  that  states require multiple  shops  to
refinish in a single  add-on control equipped facility verges on the
ludicrous.  While this creative concept might conceivably make the
capital and operating costs more "reasonable," theoretical savings
would   be  overshadowed   by   transportation  costs,   scheduling
nightmares, competition concerns, etc.

     Again, all references to add-on controls must be deleted from
the  proposed CTG as they  are clearly not  "reasonably available
control technologies" for  this industry.

E.   Other
     a.   Housekeeping Practices
          NADA  has  long supported  good  refinishing housekeeping

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practices.  Keeping containers closed and minimizing the amount of



materials used is good for business as well as for the environment.







          Throughout  its proposed  document,  EPA refers  to the



proper  management of  waste  paint and  solvent  materials.   NADA



objects to  EPA's repeated  reference  to off-site waste  management



options as somehow being important to the CTG.  Instead,  EPA should



include a  suggested prohibition against  the intentional on-site



disposal-through-evaporation of waste paint and solvent  materials.



Furthermore, there  is  no reason to believe that waste  sludges or



distillation  residues  pose  any  VOC emission  concerns.     The



discussion of waste management,  including recordkeeping, should be



dropped from the CTG as  these materials are already  covered under



applicable  federal   and  state  solid  and/or  hazardous  waste



regulations.







     b.   Reporting and  Recordkeeping



          NADA  strongly objects to EPA's suggested  recordkeeping



and  reporting  requirements  as having  no  relationship  to  VOC



control.  Daily logs  or records would be terribly burdensome for



the  small  business automotive  refinishing  community.   In the



alternative,  EPA should  simply  suggest  that states require



refinishers to keep copies of their preparation, paint system, and



solvent purchase  invoices,  and the  repair  order  documentation



normally kept  in the  ordinary  course of  business.   Analysis of



these normal business records would provide regulatory authorities
                            1034

-------
with more  than adequate information  for  both administrative and
enforcement purposes.

     c.   Miscellaneous
          NADA urges EPA to edit its draft CTG document to remove
a  number  of  irrelevant discussions  including the  reference to
reducing the number and severity of collisions, and the discussion
of electrostatic spray equipment.

          EPA's model  regulation has  a reference to "aftermarket
automobiles."  This  term is  certainly not commonly understood in
the industry and its purpose  is unclear.  While there may be a need
to  distinguish between  OEM painting operations  and  automotive
refinishing,  it makes  no sense to try to  define coverage of the
rule based on where vehicles were purchased.

          EPA's  model  regulation  should  apply to  light  duty
vehicles as  defined in its mobile source  regulations  and should
exclude heavy  duty  vehicles.   The  reference to and definition of
light and medium duty trucks is  inconsistent with other Clean Air
Act definitions.

          On  behalf of NADA  I would  like  to thank you  for the
opportunity  to comment on this matter.    At this  time,  I would
welcome any questions you might  have.
                                8
                             1035

-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

Douglas Greenhaus. National Automobile Dealers Association fNADA]
(see attached Presentation #4)

     Mr. Hise asked how common is distillation of waste/spent
solvent.  Mr. Greenhaus said it is not that common, but it is
increasing.  The use of distillation units avoids off-site
liability disposal and reduces hazardous waste disposal costs.
Distilled solvent can be used in gun cleaners (but it is not pure
enough to mix in paint).  Mr. Hise asked if these units are
readily available to shops.  Mr. Greenhaus said they are; there
are at least 12 distributors, and some facilities share them.
     Dr. Atkins asked if NADA completely supports the California
regulation.  Mr. Greenhouse responded NADA does not support the
regulation for recordkeeping or TE.  In color match issues, they
defer to the coating manufacturers.
     Mr. Dennison recommended that NADA explore the possibility
of multiple shops sharing an add-on control device.
Mr. Greenhaus said they would, but that this practice is not done
at all, and is not "reasonable" for consideration as RACT.  He
was not aware of any NADA members that have add-on control
devices, and NADA would not support the use of add-on controls
for any size shop because the costs are just too high.
     Dr. Atkins asked if Mr. Greenhaus was aware of many odor
complaints.  Mr. Greenhaus replied that they occasionally hear of
shops getting inspected because of odor complaints but most
dealerships are located in non-residential areas.  Mr. Berry
noted that non-dealership facilities could be located in
residential areas.  Mr. Greenhaus agreed that smaller,
independent shops are more likely to be located in residential
areas.

-------
Industry Presentation #5
                              PRESENTATION/COMMENTS OF




                     PPG INDUSTRIES AUTO REFINISH COATINGS GROUP




                      CONCERNING AUTOBODY REFINISHING CTG DRAFT
                                         BY




                                   R.  T.  HILOVSKY




                             MANAGER,  REGULATORY AFFAIRS




                        AUTOMOTIVE,  AIRCRAFT & FLEET FINISHES
                                     1037

-------
- NAPCTAC Meeting - November 21, 1991

- Automotive Refinish CTG Draft


Thank you for the opportunity to address this subject today.

As a supplier of coatings systems, information and training to the
Auto Refinish Industry and an active participant in the NPCA Auto
Refinish Coalition, PPG Industries strongly supports the positions,
objectives, and recommendations of the NPCA Coalition position paper.

    -Objective:  Development of national consistent VOC regulations
    with real, effective, achievable VOC emission reductions.

    -Recognition & incorporation of industry practice and operating
    realities into effective regulations.

    -Selection of the RACT VOC limits of the California Clean Air
    Act Guidance for the Refinish Industry as the RACT limits for
    the CTG.

    -Topcoat limits recognizing multi-stage basecoat/clearcoat or
    tri-coat averaging as necessary to achievable VOC systems
    reductions.

    -The recognition of the systems nature of Refinish products and
    processes.

    -Acknowledgement of the necessity and utility of low-volume usage
    speciality coatings.

    -The effective reductions achievable through the trained use of
    improved transfer efficient application equipment and techniques.


-Systems Nature of Auto Refinish Coatings Operations

    -Product chemistries as they develop require constant testing
    to determine over and under what other coating components and
    substrates these products are compatible

**[Attached overhead transparencies here to demonstrate systems]

    -New material developments and raw material substitutions for
    supply/economic reasons as well as regulation mandates require
    retesting and qualification within the individual manufacturer's
    total system.
         -Knowledge of competitive changes is not available as to
         type or timing.

-------
    -Use of total product systems with their background testing
    history allows consistent use,  application,  and productivity
    recommendations to be made and trained.

    -Total  systems allow thorough technical  service support,
    complaint handling,  and approved application warranties.   This
    better  assures that recommended reductions,  blends and
    application techniques are consistently  followed,  to maintain
    and assure the guarantee and minimize job re-do's  or come backs.


-Training

    Achievement of the desired VOC reductions from any regulation
    is best attained by the consistent,  trained  usage  of compliant
    materials and methods by an applicator confident in the products,
    equipment and achievement of the desired end result in system
    appearance, performance and productivity.

    Auto Refinish systems manufacturer/suppliers are the primary,
    consistent and continuing source of training to the industry.

         -Product Systems Introduction and Training

         -Coating Systems Application Options
              -Printed recommendations and hands-on training

         -Regulatory Requirements
              -OSHA safety and right to know
              -Hazardous waste disposal guidelines
              -VOC emission reduction

         -Product/Process Productivity


CA Guidance RACT is fully accepted,  trainable and in training now.

Thank you for your time and attention,  and I would welcome any
questions you may have.

A final comment before I conclude,  the conclusion that transfer
efficiency  is not easily quantifiable due to product,  part and
process variability,  and thus cannot be assigned a baseline % value,
seriously contrasts with the assigned 35% T.E. value for conventional
air spray used in calculations in the draft  CTG.   35%  T.E. is the
maximum achievable for air spray,  which is certainly subject to all
the same variables.   A reasonable improved T.E.  baseline average can
be established from product usage/purchase records.
                            1039

-------
o
            SUITABILITY OF ONE PRIMER UNDERCOAT OVER ANOTHER
                 2ND COAT
                                                         $

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DL1970

DZL32 34 72

DPE 656
DPE 1202
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      12
                                                                     13

-------
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           SUITABILITY OF ONE PRIMER  UNDERCOAT OVER ANOTHER
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1ST COAT
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DP 70/701
DPX 800
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                                                                    15

-------
             COMPATABILITY OF TOPCOATS    OVER VARIOUS UNDERCOATS

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0X94
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       18
                                                                                             19

-------
              COMPATABILITY OF TOPCOATS    OVER VARIOUS UNDERCOATS

OL 1970
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72
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1987
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      16
                                                                                             17

-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

Ron Hilovsky. PPG Industries (see attached Presentation #5)

     Mr. Hise asked whether the EPA's assumed TE of 35 percent
was accurate for the industry today as an average.   Mr. Hilovsky
responded that conventional spray equipment has a TE of 25-35
percent, while the CTG gives 35 percent as an average for
conventional spray equipment.
                            1G44
                                i

-------
                 Industry Presentation I6
The Sherwin-Williams Company
101 Prospect Avenue, N.W.
Cleveland, Ohio 44115-1075

 •National Air Pollution Control Techniques Advisory Committee Meeting
  November 21, 1991  at Durham, NC
 •Guidance document for Automotive Refinishing CTG


 NAPTAC Committee  Members:


 I appreciate the opportunity to address this committee today.

 We recognize the need to reduce VOC emissions to improve air quality due to not
 only the need to comply to the Clean Air Act but to create a healthy environment for
 all of us.   In doing so you take into consideration environmental and economic
 impacts.   In this  regard  I would like to tell some background information on the
 automotive refinish industry.

 The industry is responsible for the repair and refinish of the average person's second
 largest asset - his  car. (This follows only the home as a person's single largest asset.)

 The industry represents the classic small business profile for the United States.  The
 following facts from  the "Market Profile  1991" Body Shop Business (a widely read and
 highly regarded trade publication) represent the industry:

            • 77.2% of body shops are family owned
             (20.2%  of those are second generation),
            • Currently 2 family members work full time in the body shop,
            • The average body shop has approximately 7 employees,
            • 45.5% of workers refinishing automobiles are paid hourly,
            • 53.4% of body shops generate less than $250,000 in annual sales,
            • Average gross profit margin is 25.0%
             (This translates to less than $62,500 in gross profit per year).

 The reason I bring your attention to these facts is that we take great care in our
  recommendations for PACT. And for how we design new technology for the future.

  I would also like to bring to your attention the heart of the refinish industry - color. The
  ability to restore  a vehicle to its "pre-collision condition" is absolutely  essential. The
  restoring  of a vehicle to OEM specification for quality and performance is necessary
  and expected.  But the  color match  dictates whether a customer  will accept a
  repair. If the repair  is evident to color  mismatch, the vehicle has to be done again
  and at a loss. To give you a feel for the complexity of todays colors I have brought
  the following.

            • '92  Domestic Car Color Chip Book,
            • Alternate color formulas program,
            • Repaired panels
            • Blending - visual demonstration

                                   1045

-------
As you can see, there are literally thousands of colors required to refinish all of todays
vehicles.  And complex color matching is required for today's colors.  We are
sensitive to their needs of providing a quality and warranteed system that they can
use right the first time. Again this impacts our recommendation for PACT.

The draft document for the automotive refinish CTG does not take into account the
use of  a composite VOC for basecoat/clearcoat  colors.   Attached to my
presentation is our company's documentation where the composite calculation of

                     VOC BB/CC = VOC BC + 2 VOC Cc
is derived from. In our test we simulated a medium size repair (replace fender and
blend door) and large repair (replace front fenders  and hood, blend into doors).
We also used a Low Volume Low Pressure gun, a high solids clearcoat, and a high
VOC basecoat color.  This combination represents a worst case scenario (ie - low
amount and VOC of clearcoat, high VOC  basecoat color, and low volume of
material due to high transfer efficient application equipment). The results are still within
the composite VOC calculation. To sum up the results (details are attached):

           • The  ratio  of 2:1 for clearcoat to basecoat  is based in  material by
            volume not dry film thickness. Actual is 2.4:1 for a medium repair and
            2.6:1 for a large repair.

           • The predicted VOC for the composite VOC calculation is understated
            by 2.2% of actual VOC emissions for a medium repair and understated
            by 0.6% of actual VOC emissions for a large repair.

The calculation  is  accurate  and  represents  the  VOC  emissions  of a
basecoat/clearcoat system. With the flexibility to use this composite VOC calculation
we are free to turn loose our Research and Development department to lower VOC
emissions of a basecoat and/or clearcoat. This will encourage innovative solutions
to reduce  VOC emissions at the  lowest cost.   Without this flexibility the VOC limits
proposed (contained within the draft CTG) are not RACT. No system, to the best of
my knowledge, exists that can commercially meet the proposed VOC limits.

RACT is defined as "the lowest emission limitation that a particular source is capable
of meeting by the application of central technology that is  reasonably available
considering technological and economic feasibility".  And it takes into account a
particular  source's "technological and economic circumstances". In your RACT
determination we ask you to recognize our efforts to think and act as an industry:
refinishers  and shop  managers/owners, distributors,  equipment suppliers  and
coatings manufacturers. Our efforts are designed to move our industry to lower their
VOC emissions but  yet preserve the integrity and complexion of the industry by
keeping costs low.


                                 1046

-------
In our considerations we  as  an industry  have been required to weather the
technological advances of the Unibody,on board computer equipment, increased
OEM warranty  periods,  and  basecoat/clearcoat/three stage finishes.   These
advances required new technology and training, as well as capital investment for
new equipment. All at a time of decreased amount of issuance dollars.

The RACT recommendations we make are sensitive to the small  business in the
aftermarket collision repair industry. We have worked together to draft reasonable
rules. We make the recommendation to use California's Technical  Review Group's
recommendation for RACT.  It encompasses the goals of industry and regulators into
a common target. Our focus in not to stop at  RACT.  We have set our ambitious
program to go further.

I would like to make an additional comment.  Hercules approached me about how
their gun  cleaner fit into the CTG.  I believe the attached document should be
reviewed as its results are contrary to some of the information in the draft CTG.

Again I appreciate your time and the hard work of many here to get to where we
are today. The incorporation of our suggestions ensures a workable document for
the United States and tomorrow.
                                    047

-------
                           Basecoat/Clearcoat VOC Calculation

   VOC BC/CC Premise:  The VOC emissions from a repair of an OEM basecoat/clearcoat by an
   aftermarket refmish basecoat/clearcoat can be accurately represented by the following calculation:
                    VOC BC/CC = VOC BC + 2 VOC Cc
   This premise is based on allowing a basecoat with accurate color match capability that will allow
   smaller blends, prevent "re-do's" due to inaccurate color match, and that the volume of the clearcoat to
   basecoat is a minimum of 2:1.

•  Test  Protocol:
   —Test
      Spray two repairs that represent an  "average1" (1-2 panel) and large2 repair (2 or more panels)
      (Small repairs3 - a panel or less represents the lowest VOC emission and consequently will not be
      done). See attached diagram.
   —Equipment:
      Iwata LPS (Low Volume Low Pressure restricted to maximum 10.0 psi at tip).
   —Topcoat System:
      BC)—UltraBase 7® Basecoat Color with BCS-600V (Test Colon '91 General Motors Code 22
            Light Sapphire Blue Metallic UB-35879).
      CC)—Ultra 7000® High Solids Urethane Booth Clearcoat CC-850.

1  Average—Involves up to replacement of 1 panel (such as a fender), applying basecoat to fender and
   blending color into clear to hide any potential color mismatch. This is followed by applying clearcoat
   to fender and door.

2 - Large repair—Involves up to replacement of front end (such as a severe front end collision), applying
   basecoat to both fenders, hood, and blending into doors (to hide any potential color mismatches). This
   is followed by applying clearcoat to two fenders, hood, and both doors.

3 - Small repair—Involves applying basecoat to small spot (usually less than 1 panel) and blending out into
   rest of panel. This is followed by applying clearcoat to entire panel. If color match is good, generally
   the amount of basecoat color used is small compared to clearcoat usage.

•  RESULTS

                               Basecoat                    Clearcoat
   —Mixing Ratio              1:1 UB-35879:BCS-600V     4:2:1 CC-850:CC-R854:CC-H858
   —VOC (Sprayable)          6.07 #/gal                   4.38 #/gal
   —Wt/Gal (Sprayable)        7.66 #/gal                   8.13 #/gal
   —UsageJ Medium repair     3.4 oz.                      8.2 oz.          Ratio: 1:2.4
   —Usage! Large repair       12.1 oz.                    31.6 oz.         Ratio: 1:2.6
   —Actual VOC emissions
       Medium repair            0.16#                      0.28 #           Total: 0.44 #
       Large repair              0.58 #                       1.08 #           Total:!. 66 #
   —Predicted VOC emissions 2
       Medium repair            —                         —               Total: 0.45 #
       Large repair              —                         —               Total: 1.67 #


              1  Usage—      Medium Repair (~ 14 sq. ft.)    Large Repair (~ 44 sq. ft.)
                         BC       92.3g (3.4 oz.)               329.5g (12.1  oz.)
                         CC       234.8g (8.2 oz)              909.3g (31.6 oz.)

-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION

Grea Ocampo.  Sherwin Williams (see attached Presentation #6)
[Note:   There was no committee discussion of attachment to
Presentation  #6]

     In response  to a question by Dr.  Atkins about the 1992
California limits, Mr. Ocampo said they would be hard to meet in
a shop that did not have a heated spray booth because the
clearcoat would dry very slowly-  Some coatings that can meet the
1992 limits are not currently "reasonably available," but may be
in a few years.  Mr. Ocampo stated that he supports the GARB 1990
limits as RACT.
     Mr. Hise asked how the right color is selected.  Mr. Ocampo
replied that  spectrophotometers work for solid lighter colors.
However, even then they are only used for guidance; all color
matches are done  by eye.
     In response  to another speaker's comment that color match
would only be hard with the Option 2 topcoats, Mr. Ocampo said
that all coating  manufacturers agree that without being able to
use the basecoat/clearcoat averaging equation, metallic topcoats
could not meet either option.
                            104!
                                i

-------
           Atxacnment  to
           Industry Presentation  #6
Iterlmlec
                                                                             Phone. 313-363-8882
                                                                             WATS. 1-800-444-4351

                   Hcrkulcs Equipment Corporation                          reiex     '

                   8230 GOLDIE ST.  •  WALLED LAKE, Ml 48390-4108

                                           November 13,  1991
    United States Environment  Protection Agency
    Office of Air Quality  Standards'Division
    Research Triangle  Park, N.C.    27711
    Attention:   Mr.  Bruce C. Jordan
                Director Emission Standards Division

        Subject:   Draft Sept. 27, 1991
                  Automobile Refinishing
                  Control Techniques Guideline
                  (Gun Cleaning)

    Dear Mr.  Jordan,

    Our copy  of  the  draft was delayed in being received  due  to a zip code change
    and was only  reviewed this past weekend,  hence we  are  too late  to obtain time
    for a presentation.  According to Mary Jane Clark, you can distribute copies
    of this letter to the committee.

    Our firm  holds the basic patents on the predominate  type of enclosed gun
    washers found  in body shops both here in  the USA as  well as in  most countries
    abroad identified in your draft in Section 2.6 on  page 2-15 and pictured in
    Figure 2-3 which is commonly referred to  as an Automatic-Enclosed Gun Cleaner.
    To help NAPCTAC  we would like to place before the  committee some additional
    information which is related to paint gun washing  and  "latest applicable
    technology"  for  cleaning of paint guns and related equipment.   To accomplish
    this objective,  a distinct differentiation is made between Automatic-Enclosed
    Gun Cleaners  (Figure 2-3) and the "typical open gun  cleaner" described in
    Section 2.6 page 2-17 and pictured in Figure 2-4 also  known as  a Manual-Open
    Gun Cleaner.   The major differences are compared below:

-------
        Differences             Automatic-Enclosed              Manual-Open

     1.  Closed  during               yes                             no
        cleaning

     2.  Cleans  guns without          yes                             no
        worker  direct
        participation

     3.  Cleans  multiple  guns,        yes                             no
        cups, stirrers,
        strainers  and other
        paint related equipment
        simultaneously

     4.  Cleans  inside and           yes                             no
        outside of guns
        simultaneously

     5.  Workers are exposed          no                              yes
        to solvents during
        cleaning cycle
Much of  the  draft  seems  to paint both Automatic-Closed and Manual-Open Gun
Cleaners with  the  same brush.   This overlooks key issues such as solvent.
consumption, worker  exposure,  cleaning cycle time,  other items which must
constantly be  cleaned  along with the paint gun and  simultaneous multiple gun
cleaning all of  which  impact on the VOC emission and worker exposure.

As a part of the "improved housekeeping practices"  referred to in Section 3.1
page 3-1, Automatic  Enclosed Gun Cleaners can play  an important role.  They
affect radically the amount of time required for cleaning guns, cups,
stirrers, strainers,  etc.   reducing worker direct exposure to solvents while
limiting potential  escape  of V.O.C.  Over the old methods of cleaning, they
significantly  reduce solvent usage and the amount of solvent which must be
maintained at  the  shop.  Virtually all of the tools and related items which
need constant  cleaning including strainers,  stirrers, and mixing vessels can
be cleaned in  the  automatic gun cleaner at the same time the guns are being
cleaned  eliminating  the  need for multiple open containers for various cleaning
functions.

We take  issue  with  the final paragraph in section 3.4 page 3-10 implying that
"Open Gun Cleaners  emit  no more VOC than Enclosed Gun Cleaners." The report
referred to  was  submitted  to SCAQMD in order to obtain a variance allowing
manual-open  gun  washers  to be used in Southern California.  The report was
paid for by  the  waste  hauler owning the rental equipment;  the test  itself
varied from  the  testing  procedure recommended by the SCAQMD, and did not
reflect  knowledgeable  usage of the competitive units, totally ignored multiple
equipment cleaning  which is essential and used antiquated competitive models.

-------
With reference to Section 4.3.1.  page 4-14, it is possible  that minimal
solvent could be emitted from closed gun cleaners, but this  possibility was
virtually eliminated long ago by a redesign of the lid.   (See Attachment No.
1).  All Herkules manufactured or licensed units have or  will have soon
incorporated this feature.

The issue of escaping V.O.C., 4.3.1 page 4-14, during the loading (no hose
connections are required in our standard automotive Automatic-Enclosed Gun
Cleaners) is a valid concern and can be addressed two ways.  The first way is
through education and the second way is through the use of a speed controlled
lid opener and closer.

Proper opening of the lid on-any solvent container requires education.  The
worker does not want to create any more suction during opening and no more
fanning of fumes during closing than necessary.  Hence the industry needs
instruction.  A sample of such instruction for any vessel containing solvent
could read as follows:

                                  CAUTION:
                             READ BEFORE OPENING

    Solvent fumes are normally heavier than air and if not disturbed
    will remain in the container.  To prevent fumes from escaping,
    open and close lid slowly.

        I.  Open lid about one inch to equalize the pressure inside
            and outside.  Then open slowly, this mimimizes the escape
            of fumes through suction.

        2.  Do not slam lid during closing, lower lid slowly to prevent
            fanning which can cause fumes to escape.

In the Definitions Section 6.2 page 6-3 under the heading Gun Cleaner,
reference is made to being "vapor tight";  no gun cleaners in common use are
100% vapor tight.  In fact, if they were vapor tight chances of fume emission
would be increased during loading and the cleaner could become dangerous under
pressure as the content in most cases are extremely volatile.  For this
reason, we believe Sections 6.2 page 6-3, 6.6.2 page 6-10 and Appendix D, page
D-3 Gun Cleaners and Appendix D page D-5 Equipment Standards (d)  (1)  (iii)
need modification to read "reasonably vapor tight" not "vapor tight."

We are continuously trying to improve the design and application of cleaning
equipment to provide both the autobody repair and industrial paint industries
with "state of the art" equipment.  The draft does not take into
consideration the latest models of automatic-enclosed cleaning equipment which
have solved many of the VOC emission problems, for example:
                                  1052

-------
       Features

   1.  Double barrier lid
       design.
       Speed controlled lid
       opener and closer.
       Hose cleaning for
       pressure gun fluid
       lines.
    4.  Paint can and paint
       lid cleaning.
    5.  Combination gun and
       paint can washing.
Herkules Models
Containing Features

All Herkules models
GWR-100-SS
GWR-3-100-SS
CWR-4-100-SS

GWR-3
GWR-3-100-SS
CWR-31
CWR-31-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
CWR-4
CWR-4-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
Result

Reduction of VOC emissions
during both active and
passive states.

Reduction of VOC emissions
during loading and un-
loading.

Reduces solvent needed for
fluid line cleaning, VOC
emission and the need for
open solvent containers
during cleaning.

Allows paint cans to be
reused as mixing or
storage containers,
reducing solid waste
generated in the form
of paint sludge.  Converts
quart, gallon and 5 gallon
cans considered hazardous
to non-hazardous reducing
disposal costs and re-
ducing the amount of
paint which is sent to
hazardous dump sites,
inside cans.

One cleaner cleans
both guns, cups,
stirrers, strainers, etc
and paint cans/lids.
In a  world of constant change, obviously  it is  impossible  to  take  all
available technology into consideration before  approving the  guidelines.
With  minor adjustments to the draft including more specific wording on
Automatic-Enclosed versus Manual-Open Gun Washers and changing  the concept  of
"vapor  tight" to "reasonably vapor tight" the document  should become an
acceptable guideline.
                                       Yours  very  truly,
                                        Richard  A.  Robb
                                        President
RAR/lw
                                *i ° r n>
                                I.» 3 3

-------
ATTACHMENT No.  1
   ORIGINAL
   ALUUIHUM
     LID
ALUMINUM
 FRAMf
    ORIGINAL
     PLASTIC
       TUB
                 HEW
              ALUMINUM
                 LID
VAPQR
SCAL
                                                  GWR  LID/TUB  FIT
                                                   PLASTIC TUB

                                                 HCKKULCS fQUIPMCUr CORP
                                                 Bf LG         PAr.- l-ir-91
                                                               LIO Oe<~l
                                                   STAINLSC? STfCL TUB
                                                   HY LG

-------
         Comments & Observations Of
    Automotive Refinishing CTG Document
en
                                 GRACO INC.
GRAC01"1                             MINNEAPOLIS, MN

-------
     Total Paint Thickness Applied by OEM
    Total

    Paint
  Thickness

   3.5 MILS
          i
                                             Clearcoat
                                             50% of Total Thickness
Basecoat
20% of Total Thickness


Primer
30% of Total Thickness
GRACO 1991

-------
     OEM Prefers Electrostatic Application
M
GR AGO 1991
                 75-80% of all coatings currently
                 applied are electrostatic
                 Including:
                          80% of all primers

                          95% of all clearcoat
                        / 40% of all basecoat

-------
   Graco Test Comparisons of T.E. in Spray
     Forms Show That in Refinish Industry
 C©
        Electrostatic
       Hits the target with
        75% efficiency
   HVLP
Hits the target with
 65% efficiency
  Airspray
Hits the target with
 40% efficiency
            ...Because of very low flowrates
GRACO 1991

-------
              When Using Electrostatic

            Application Throughout the

           Automotive Refinish Process


           •  Basecoat color match is more accurate
             and readily achieved
           •  Application is easier
           •  Greater efficiency results, which
             translates to faster payback of
             electrostatic gun
              EXAMPLE: 10 week payback of $4100 electrostatic unit
                    shop type E-H)

              1.92 Gallons/Day (savings) X $42.50/Gallon X 50 Days = $4080
GRACO1991

-------
fteffkulcc
                                                                               Phone: 313-363-8882
                                                                               WATS: 1-800-444-4351
                                                                               FAX:  313-363-7998
                    Herkulcs Equipment Corporation                            i.v.  231233

                    8230 GOLDIE ST.  •  WALLED LAKE, Ml 48390-4108

                                            November  11,  1991
    United States Environment Protection  Agency
    Office of Air Quality Standards Division
    Research Triangle Park,  N.C.    27711
    Attention:  Mr. Bruce C.  Jordan
                Director Emission Standards Division

        Subject:  Draft Sept.  27, 1991
                  Automobile  Refinishing
                  Control Techniques  Guideline
                   (Gun Cleaning)

    Dear Mr. Jordan,

    Our copy of the draft was  delayed in being received due to a zip code change
    and was only reviewed this past weekend, hence we are too late to obtain time
    for a presentation.  According to Mary Jane Clark, you can distribute copies
    of this letter to the committee.

    Our firm holds the basic  patents  on the predominate type of enclosed gun
    washers found in  body shops both  here in the USA as well as in most countries
    abroad identified in your  draft in Section 2.6 on page 2-15 and pictured in
    Figure 2-3 which  is commonly referred to as an Automatic-Enclosed Gun Cleaner.
    To help NAPCTAC we would  like to  place before the committee some additional
    information which is related to paint gun washing and "latest applicable
    technology" for cleaning  of paint guns and related equipment.  To accomplish
    this objective, a distinct differentiation is made between Automatic-Enclosed
    Gun Cleaners (Figure 2-3)  and the "typical open gun cleaner" described in
    Section 2.6 page  2-17 and  pictured in Figure 2-4 also known as a Manual-Open
    Gun Cleaner.  The major differences are compared below:

-------
        Differences             Automatic-Enclosed              Manual-Open

     1.  Closed  during               yes                             no
        cleaning

     2.  Cleans  guns without         yes                             no
        worker  direct
        participation

     3.  Cleans  multiple guns,        yes                             no
        cups, stirrers,
        strainers  and other
        paint related equipment
        simultaneously

     4.  Cleans  inside and           yes                             no
        outside of guns
        simultaneously

     5.  Workers are exposed         no                              yes
        to solvents during
        cleaning cycle


Much of  the draft  seems to paint both Automatic-Closed and Manual-Open Gun
Cleaners with the  same brush.   This overlooks key issues such as solvent
consumption, worker exposure,  cleaning cycle time, other items which must
constantly be cleaned along with the paint gun and simultaneous mult.iple gun
cleaning all of which impact on the VOC emission and worker exposure.

As a part, of the "improved housekeeping practices" referred to in Section 3.1
page 3-1, Automatic Enclosed Gun Cleaners can play an important role.  They
affect radically the amount of time required for cleaning guns, cups,
stirrers, strainers, etc.   reducing worker direct exposure to solvents while
limiting potential escape of V.O.C.  Over the old methods of cleaning, they
significantly reduce solvent usage and the amount of solvent which must be
maintained at the  shop.  Virtually all of the tools and related items which
need constant cleaning including strainers,  stirrers, and mixing vessels can
be cleaned in the  automatic gun cleaner at the same time the guns are being
cleaned  eliminating the need for multiple open containers for various cleaning
functions.

We take  issue with the final paragraph in section 3.4 page 3-10 implying that
"Open Gun Cleaners emit no more VOC than Enclosed Gun Cleaners." The report
referred to was submitted to SCAQMD in order to obtain a variance allowing
manual-open gun washers to be used in Southern California.  The report was
paid for by the waste hauler owning the rental equipment;  the test itself
varied from the testing procedure recommended by the SCAQMD, and did not
reflect  knowledgeable usage of the competitive units, totally ignored multiple
equipment cleaning which is essential  and used antiquated competitive models.
                                     1061

-------
With reference to Section 4.3.1.  page 4-14, it is possible that minimal
solvent could be emitted from closed gun cleaners, but this possibility was
virtually eliminated long ago by a redesign of the lid.   (See Attachment No.
1).  All Herkules manufactured or licensed units have or  will have soon
incorporated this feature.

The issue of escaping V.O.C., 4.3.1 page 4-14, during the loading (no hose
connections are required in our standard automotive Automatic-Enclosed Gun
Cleaners) is a valid concern and can be addressed two ways.  The first, way is
through education and the second way is through the use of a speed controlled
lid opener and closer.

Proper opening of the lid on any solvent container requires education.  The
worker does not want to create any more suction during opening and no more
fanning of fumes during closing than necessary.  Hence the industry needs
instruction.  A sample of such instruction for any vessel containing solvent
could read as follows:

                                  CAUTION:
                             READ BEFORE OPENING

    Solvent fumes are normally heavier than air and if not disturbed
    will remain in the container.  To prevent fumes from escaping,
    open and close lid slowly.

        1.  Open lid about one inch to equalize the pressure inside
            and outside.  Then open slowly, this mimimizes the escape
            of fumes through suction.

        2.  Do not slam lid during closing, lower lid slowly to prevent
            fanning which can cause fumes to escape.

In the Definitions Section 6.2 page 6-3 under the heading Gun Cleaner,
reference is made to being "vapor tight";  no gun cleaners in common use are
100% vapor tight.  In fact, if they were vapor tight chances of fume emission
would be increased during loading and the cleaner could become dangerous under
pressure as the content in most cases are extremely volatile.  For this
reason, we believe Sections 6.2 page 6-3, 6.6.2 page 6-10 and Appendix D, page
D-3 Gun Cleaners and Appendix D page D-5 Equipment Standards (d)  (1)  (iii)
need modification to read "reasonably vapor tight" not "vapor tight."

We are continuously trying to improve the design and application of cleaning
equipment to provide both the autobody repair and industrial paint industries
with "state of the art" equipment.  The draft does not take into
consideration the latest models of automatic-enclosed cleaning equipment which
have solved many of the VOC emission problems, for example:
                                     1062

-------
       Features

    1.  Double barrier lid
       design.
    2.  Speed controlled lid
       opener and closer.
    3.  Hose cleaning for
       pressure gun fluid
       lines.
    4.  Paint can and paint
       lid cleaning.
    5.  Combination gun and
       paint can washing.
Herkules Models
Containing Features

All Herkules models
GWR-lOO-vSS
GWR-3-100-SS
CWR-4-100-SS

GWR-3
GWR-3-100-SS
CWR-31
CWR-31-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
CWR-4
CWR-4-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
Result

Reduction of VOC emissions
during both active and
passive states.

Reduction of VOC emissions
during loading and un-
loading.

Reduces solvent needed for
fluid line cleaning, VOC
emission and the need for
open solvent containers
during cleaning.

Allows paint cans to be
reused as mixing or
storage containers,
reducing solid waste
generated in the form
of paint sludge.  Converts
quart, gallon and 5 gallon
cans considered hazardous
to non-hazardous reducing
disposal costs and re-
ducing the amount of
paint which is sent to
hazardous dump sites,
inside cans.

One cleaner cleans
both guns, cups,
stirrers, strainers, etc
and paint cans/lids.
In a  world of constant change, obviously it is impossible  to  take  all
available technology into consideration before approving the  guidelines.
With  minor adjustments to the draft including more specific wording  on
Automatic-Enclosed versus Manual-Open Gun Washers and changing  the concept  of
"vapor tight" to "reasonably vapor tight" the document should become an
acceptable guideline.
                                       Youxsvery truly,
                                       Richard A. Robb
                                       President
RAR/lw

-------
ATTACHMENT No.  1
   ORIGINAL
   ALUMIHUM
     LID
ALUMINUM
 FRkME
                HEW
              JILUM/NUM
                LID
VAPOR
SfAL
                                                              PL AST IO
                                                             \   TUB
                                                  GWf? LID /TUB FIT
                                                  PLASTIC TUB     "
                                                                  CORP
                                                BY LG
                                                    DOUKICSEAL LID
                                                   STMHLEZS 5TCCL TUB

-------
AUTOMOTIVE PRODUCTS
Technology and Planning
Wilmington, Delaware 19898
                                 November 14, 1991
   Mr.  Bruce C.  Jordan
   Director, Emission Standards Division  (MD-13)
   Office of Air Quality Planning and Standards
   U.S.  Environmental Protection Agency
   Research Triangle Park, NC  27711

   Dear Mr. Jordan:

                    COMMENTS ON THE AUTOMOBILE
             REFINISHING CONTROL TECHNIQUES GUIDELINE
               DRAFT FOR NAPCTAC REVIEW ON 11/21/91
             It is recognized that the subject draft guidance
   is in its early stages of development and therefore  subject
   to various changes.  Once it is completed and acted  on  by
   the various states, it will forever change how the
   refinishing industry does business and the kind of quality
   product and costs it can deliver to the ultimate customer,
   the consumer.   It is therefore very important that EPA's
   guidance document accurately describes the industry, what
   VOC reductions can be reasonably achieved, and that  it  is
   factual.  These comments are given in the hope that  what is
   presented here will help in that regard.

             In general, the draft guidance document as a  whole
   makes a good descriptive representation of the industry.
   The analysis given is quite complete and substantially
   correct.  Some treatments, however, have to be questioned
   and should be modified, corrected, changed, or described
   more fully.  First some comments of a general nature that
   will be followed by specific comments on the various
   sections in the document.

             EPA is aware of the Suggested Control Measure
   (SCM)  that has been developed by the California Air
   Resources Board (CARB) for the refinish industry for the
   more stringent requirements for ozone attainment under  the
   California CAA.  The SCM establishes RACT and BARCT  guidance
   after a long process of evaluation and interactions  with the
   industry.  Du Pont supports the SCM and has developed
   refinish systems to meet the RACT guidance.  As the  BARCT
   requirements are technology forcing, we are expending all  of
                         Better Things for Better Living

-------
our R&D efforts to satisfy the BARCT guidance for refinish
repair systems.  The refinish industry is a highly
distribution intensive industry with the added
responsibility of the paint suppliers having to train body
shop operations in the use of new, lower VOC repair systems
required for SCM based regulations in California.  It is
only logical and cost effective to have equal requirements
established in other jurisdictions.  It is readily apparent
that 30 or 50 different VOC requirements across the nation
requiring different technologies for each VOC level of
repair systems, and the thousands of color match
developments, would be beyond the capability of any paint
supplier, no matter how large.  It is therefore very
surprising to find the draft CTG document not acknowledging
the work done by CARB or the existence of the SCM.  It is
our belief that RACT established in the SCM is in fact
appropriate to be RACT for the CTG applied nationally.  The
BARCT standards in the SCM are technology forcing and
therefore do not constitute RACT for the proposed CTG.

          It is true that Du Pont, as well as our
competitors, are supporting the SCM standards and R&D work
is currently in place to deliver repair paint systems with
the specified VOC limits.  Whether they can be achieved by
us, or anybody else, only time will tell.  Inventions cannot
be mandated by a certain date.  Should EPA consider using
BARCT standards as an option for a possible RACT standard,
there are two difficulties.  By definition, BARCT is not
RACT.  Secondly, were state agencies or air districts to
adopt such standards into their SIPS, they become law and
cannot be relaxed.  Should industry fail to achieve these
technology forcing standards by a certain date mandated,
what then?  Do body shops cease to operate in that
jurisdiction?  For this scenario, it is necessary that the
CTG provide for some mechanism of alternatives until such
technology can be demonstrated.

          The subject draft guidance assumes that technology
transfers (from high VOC systems to lower VOC systems, to
waterborne systems, etc.) can be readily made without
extensive operator training, process changes, change in
productivity, change in quality, color match capability,
more frequent re-repair, or the cost structure beyond the
change in price for a gallon of paint purchased.  Such
uneven treatment is very unfair and very misleading and
should be corrected.  In fact, a lot of these effects will
force a lov. of the marginal shops to go out of business.
This will cause a realignment of body shop numbers, size and
type.  Competitive pressures will drop for the surviving
shops and costs will skyrocket for the consumer to get his
vehicle repaired.  Insurance rates will rise significantly
as well.  As an example of one effect:  In the proposed
Option 2 level controls in the draft guidance the suggested
limits for certain categories of coatings will dictate the

                          - 0
                          JL 0

-------
use of waterborne technology.  For primer surfacer
waterborne types have been recently introduced into Los
Angeles because of technology forcing regulations.  Topcoats
have not been demonstrated in this industry to date,
contrary to the implied availability in the draft document.
In any event, it can already be shown that waterborne
primers require 2 to 3 times the time to process; that is,
to apply, to dry, to sand, and time to topcoat than solvent
borne coatings.  The quality of the finish also changes.
Only time will tell whether such repairs will hold up to
expected performance standards, or more re-repairs will not
be necessary.  This situation is already causing a
realignment of body shops in the LA area.  Even if
waterborne topcoats were to be available, the same impacts
would also apply.  One would have to add the questions of
color match, aluminum flake gassing tendencies, and
performance properties.  It is obvious that this draft
guidance does not develop these issues and therefore does
not caution agencies as to the inherent difficulties that
technology forcing standards could present for the industry
as well as the agency's ability to achieve claimed VOC
reductions.

          Dividing the industry into eight arbitrary model
body shop segments pigeonholes the industry to a degree that
might not apply in actual fact.  (It is difficult to say
that a particular shop size uses 25% lacquer or 75% lacquer.
A lot of times his customer base dictates what he will use.)
Such categorization could mislead state agencies into making
misguided assumptions about emission inventories, reductions
that can be achieved, or the regulatory levels that should
be set.

          The draft guidance make a good case for the
effectiveness of using high transfer efficiency (TE) to
achieve VOC reduction.  In fact, they could be substantial,
far beyond reductions that can be achieved through coating
reformulations, and in combination could provide drastic
reductions of VOC from this industry.  Use of high T.E.
equipment is also very cost effective as the draft points
out.  However, then the draft backs out because its use is
not readily verifiable.  This position should be
reconsidered by EPA.  It is just as verifiable as running an
incinerator, absorption unit, or biodegradation unit.  They
all have variability that must be accounted for.  Some
procedure must be provided, if only through mass balance
accounting, to allow for T.E. credit.  EPA allows this
procedure for large sources, then why not for these small
sources. (See also comments below for Section 3.3.2.)

          Add-on controls, as Option 3, are dealt with quite
evenly in the draft guidance.  Whether the cost estimates
are low, high or about right is not at issue.  The analysis
plainly shows that they are prohibitive for this industry.

                          JL .' 3 8 7

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Adoption of Option 3 as the control method would drive 3/4
of the body shops out of business.  Option 3 should be kept,
however, as an alternate means of compliance for future
situations.  As the body shop population changes, or add-on
technology gets refined, add-on controls could become a
viable option for body shops.  Other than costs, this draft
implies that add-on controls are easy and viable for this
industry.  What the guidance does not point out is that it
has never been demonstrated in a commercial situation.  The
difficulty with this approach is that for technical reasons
it will not work for intermittent sources of emissions as
body shops invariably are.  It becomes virtually a nightmare
to effectively manipulate and manage the variables involved
for intermittent sources.

          It is critical that the document more clearly
shows that the composite calculations for multi-stage
topcoat  (basecoat-clearcoat and basecoat-midcoat-clearcoat)
are critical to allow setting of VOC limits for both Option
1 and Option 2.  Since any such limits are technology
forcing, this treatment of topcoat VOC will give coating
suppliers a good chance to achieving such reductions.
Failure to do so reduces such chances drastically.  EPA has
documentation in hand from the Bay Area and CARB when those
regulations and guidance were developed that show this to be
a critical component when setting VOC limits for topcoats.
Actual source data also supports this treatment when applied
in practice.

Specific Items Needing Attention

Sec. 2.1       Document states that industry does not deal
(Pg. 2-1)      with heavy trucks but is covered in another
               CTG document.  This is not true as that CTG
               deals with OEM situations not refinishing
               (repairing).  Thus, mobile equipment such as
               farm machinery, construction equipment and
               heavy duty trucks are not covered by the OEM
               CTG or this refinishing CTG.

Sec. 2.3.2     It is true that hardeners promote curing but
(Pg. 2-8)      are also used to increase gloss and/or
               durability.

Sec. 2.3.4     It is true that waterborne primers have been
               introduced in the SCAQMD and Texas Dallas/Ft.
               Worth area to meet the regulatory
               requirements there.  No waterborne basecoats
               are yet anywhere in commerce as this section
               implies.   (A non-coalition member advertises
               that such a product exists in SCAQMD.  It  is
               not found in any shops known to Du Pont.)   It
               is one thing to claim, but another whether
               reasonably available.

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Sec.  2.2.5     "Gun blending" as described does work when
(Pg.  2-4)       using high VOC coatings and conventional
               spray.  It becomes far more difficult to use
               this procedure effectively when dealing with
               low VOC coatings especially when coupled with
               higher T.E. spray equipment.  Even after
               extensive operator training this still
               remains a complicated task and leads to
               likely redo's.  See also Sec. 2.5.2 last two
               paragraphs to reflect the above reality.

Sec.  2.5       Airless spray guns should be air atomizing
(Pg.  2-11)     spray guns.

Sec.  2.5.1     Airless should be changed to air atomizing.
(Pg.  2-12)

Sec.  2.6       The guidance shows that some companies
(Pg.  2-17)     provide solvent recycling only to shops that
               rent their gun cleaning systems.  In our
               view, this is anti-competitive and strictly
               based on profit motive, and not very
               environmentally friendly.  It should not be
               sanctioned in a guidance document.

Sec.  2.7       Document implies that coatings manufacturers
(Pg.  2-20)     do not have the resources or time to devote
               testing product compatibility with
               competitors' coating.  That might be true,
               but the document should also show that such
               cross competitors combination testing becomes
               astronomical in scope, and if even possible,
               could confuse the user and produce many
               failures that would have to be re-done.

Sec.  2.7       Study implies OEM color usage could be
(Pg.  2-19)     restricted, or return to single stage
               coatings, would reduce VOC emissions.  That
               is not quite true.  Use of few colors will
               reduce complexity but use of single stage
               coatings over multi-stage will not reduce
               coatings usage as they are applied, at about
               equal film thicknesses.  Even if it were
               true, then at what costs?  Study should also
               point out that this approach would leave no
               domestic automobile industry in place!

Sec.  3.3.1     The assumption that twice as much clearcoat
(Pg.  3-8)       would not be needed might be true
               theoretically if solids content is the only
               criteria.  In practice, however, this does
               not hold, based on cost as well as how the
               two components get used.  Clearcoat in all
               spot repair and panel repair always gets used

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               over a larger area.  This is 90% of all
               repairs being done.  Basecoat, being the more
               expensive, always gets used as a minimum to
               get the job done.  Actual industry studies
               have validated this ratio consumption.  In
               fact, the ratio understates what it is in
               practice.

Sec. 3.3.1     Document states that Option 2 coatings are
(Pg. 3-5)      currently available, can achieve color match,
               but are not as widely used.  As already
               stated elsewhere, Option 2 coatings are not
               readily available, hence no color match
               predictions can be made.  All VOC levels in
               Option 2 are technology forcing.

Sec. 3.3.2     We agree that transfer efficiency is diffi-
(Pg. 3-9)      cult to verify.  However, the benefits of
               using such approach to control VOC emissions
               must not be ignored.  It can be documented
               that shops changing from conventional spray
               to HVLP, for example, cut their coatings
               purchases roughly in half.  This method of
               control reduces VOC emissions far more
               drastically than product VOC reductions
               alone.  In combination the VOC reductions
               that can be achieved can be over 80%.  EPA
               must find a way to deal with this issue.
               Past experience by EPA is for large source
               control, where testing procedures could be
               required to verify T.E..  Body shops are
               quite different sources, small and
               unsophisticated.  A method should be found,
               if no more than mass balance accounting, to
               arrive at some T.E. credit for VOC controls.
               In fact, the economic gain by shops could
               off-set some of the other costs accrued
               through regulations.

Sec. 3.3.3     This technology, use of supercritical gases
               as the solvent component in spray application
               is in the quite distant future and not as
               implied.  It is one thing to paint a
               recurring, monotonous article than to re-
               paint the ever changing repair of differently
               configured vehicles, especially for the many
               small color changes required.

Sec. 3.5.1     As stated in the general section, add-on
               control devices should be acknowledged that
               they are not feasible for intermittent
               sources.
                          1070

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Sec. 3.5.3.    Biofiltration might be an effective means for
               add-on control for emission streams that are
               constant and predictable.  In a body shop
               configuration the VOC emitted is intermittent
               and also varies from product to product used.
               It is questionable whether a given bacteria
               colony will digest the various VOC's
               uniformly.  This technology needs to be
               demonstrated for the body shop setting first
               before the guidance document should imply
               that it is or might be viable.

Sec. 3.7       Document states that waterborne basecoats are
(Pg. 3-17)     available.  This is disputed as presented in
               the general comments.

Sec. 4.2.1     The film thickness required for each
(Pg. 4-5)      coating shown have to be questioned.  For
               pretreatment wash primer (precoat) 0.1 to 0.5
               mil thickness is more likely than the 1.0 mil
               shown.  For primer surfacer a 1.5 to 2.0 mil
               is more representative than the 2.25 mils
               shown.  For primer sealer a 0.75 to 1.25 mil
               film is more representative than the 1.75
               mils shown.  For topcoats a 2.0 to 2.5 mil
               thickness is more representative than the 3.5
               mils shown.  In the case of topcoats the
               thickness represented can occur when highly
               transparent colors are used and extra film
               thickness is needed to get hiding.  EPA's
               information source should be checked to
               determine if information is average film
               build or maximum.

Sec 4.2.1      Assigns 35% T.E. to conventional spray.  It
(Pg. 4-7)      is more like 25-30% T.E. in practice.

Sec. 5         Table does not account for regeneration and
(Table 5.5)    disposal costs in the carbon adsorption
               column.  They could be significant even if
               such a service were available.

Sec. 5.5.2     In use of waterborne coatings, there is the
(Pg. 5-13)     potential to contaminate water discharges
               that the document does not point out.

Sec. 5.5.3     The disposal costs are not acknowledged for
(Pg. 5-14)     waterborne coatings which can be significant.
               Costs can be 6 times as high as solventborne
               wastes.

Sec. 5.6       It is interesting to note that the costs for
(Pg. 5-17)     the industry are not presented, only by model
               stages.  A quick calculation shows that for

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               Option 2 the industry costs are close to $600
               million as an average.  And this does not
               account for some of the productivity cost
               changes and insurance premium costs changes
               that need to be added as these comments have
               pointed out.

Sec. 6.2       Gun cleaners to be vapor tight needs to be
(Pg. 6-3)      fuller defined.  It should specify that it
               can't exceed x grams/hours of active losses
               and y grams/hour of passive losses or at
               least state "reasonably" vapor tight.

Sec. 6.2       Topcoat definition needs to define these
(Pg. 6-4)      multi-stage coatings to be controlled by a
               composite number arrived on the basis shown
               in Sec. 3.3.1 (Pg. 3-7).

Sec. 6.4.1     As pointed out earlier. Option 2 coatings are
(Pg. 6-6)      not readily available.

Sec. 6.4.2     We disagree with the finding that body shops
(Pg. 6-7)      could be required to use shared painting
               facilities.  This is blatant social
               engineering and goes against free trade
               practices and anti-trust principles.  It is
               one thing to let the free market produce such
               alignments, and quite another when it is
               commanded.  Also, the desire that is laid out
               for biofiltration in this section must be
               tempered with the comments made for Sec.
               3.5.3.
Sec. 6.5.3     It is important to state that the equations
               presented in Sec. 3.3 must be applied, not
               if, in order for industry to have a chance to
               achieve the VOC requirements recommended.

Sec. 6.6.2     Vapor tight needs to be defined as commented
               earlier.  (See Sec. 6.2 comment.)

App. D         Appendix, as currently drafted, is
               incomplete.  This should be redrafted to
               include all the findings of the document and
               the corrective comments provided.  This is
               critical as this is the output of a CTG that
               will be used by agencies to place into
               regulations.

App. D,a       Topcoat definition should contain the
               equations as laid out in Sec. 3.3.1.

App. D,d,l(iii)Vapor tight must be defined as explained
               above.
                              •n,

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App. D,c,3,(i) Topcoat VOC limits must include per
               definition given composite formula as in Sec.
               3.3.1.

Table 3-1      This table apparently represents in concise
(Pg. 3-6)      form the findings of the draft document.
               There are a number of difficulties here and
               might mislead state agencies in a number of
               ways.  First, the baseline VOC ranges given
               represents controlled areas' VOC emissions
               (California) not the uncontrolled emissions
               in the rest of the nation.  Our industry
               survey data to EPA clearly show the
               difference.  This will lead to agencies
               calculating wrong baseline emissions for
               their jurisdiction.  Secondly, the VOC limits
               for Option 1 and Option 2 seem to be set
               quite arbitrarily and are not properly
               documented.  It seems the kind of assumptions
               that were made are, as an example:  Since
               urethane coatings generally are lower in VOC
               content than others, the limits can be set at
               that level.  What it doesn't account for is
               that urethane coatings work well for overall
               repairs, but do not work well at all for spot
               repair work (the majority of repairs).
               Urethane coatings also do not give good
               metallic appearance and are difficult to use
               in spot repair that will duplicate the
               original finish.  As argued in the general
               comment section, this table for Option 1 and
               Option 2 VOC levels should follow the SCM
               determinations for RACT and BART VOC limits.

          We are pleased to have offered this analysis for
the draft CTG for refinish.  I am available to expand on
these items if EPA so desires.  I look forward to working
with EPA to develop a workable and reasonable CTG for the
refinish industry.

                              Very truly yours,
                              Karl R. Schultz
                              Environmental Consultant
KRS/kle

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December 2, 1991
Mr. Bruce Jordan
Director, Emission  Standards  Division (MD-13)
Office of Air Quality  Planning and Standards
U.S. Environmental  Protection Agency
Research Triangle Park, NC  27711
Dear Mr. Jordan:

I am supplying some  additional  information along with  a copy of
the presentation that we  submitted at the November 21 NAPCTAC
meeting.

Most of it is self-explanatory.   The  CARB document was referred
to by us fairly extensively  in  the our presentation.   The article
from an automotive refinish  professional  magazine supports our
arguments concerning the  deep rooted  extent of the product
systems nature of the industry  today.   Also,  the material from Du
Pont compliments similar  instructional material that was referred
to by Ron Hilovsky of PPG.

Also you should be receiving separate comments from many of the
members of the Coalition.

It was good to meet  you at the  meeting.   I have to tell you, in
all honesty I do not believe that I would have been able to hold
up as well as you folks did  in  those  marathon sessions.

If you need additional information, please contact me.
                                                                  ,National
                                                                 , Paint&
                                                                 Coatings
                                                               Association
Sincerely
Senior
       Counsel, State Affairs
Secretary to the NPCA Automotive Refinish Coalition
1500 Rhode Island Avenue, N~W • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549

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                                                                  National
                                                             ^  'Coatings
                          POSITION PAPER                      Association

            OF  THE  NPCA AUTOMOTIVE REFINISH COALITION

                            CONCERNING

     DRAFT AUTOMOBILE REFINISHING CONTROL TECHNIQUE GUIDELINE

                          **************

                           Introduction

 The NPCA Automotive Refinish Coalition;   The Automotive Refinish
 Coalition was formed in 1988 under the auspices of the NPCA to
 work  for effective  and nationally consistent VOC regulations for
 the automotive  refinish industry.

 The active participants in  the Coalition are the six national
 manufacturers of  automotive refinish paints and coatings:  AKZO
 Coatings, Inc.; BASF Corporation;  E.I.  du Pont de Nemours; Nason
 Automotive Coatings;  PPG Industries, Inc. ;  and the Sherwin
 Williams Company.   Collectively,  these companies account for the
 lion's share of the total volume  of automotive refinish products
 that  are sold in  the United States.   These  companies also provide
 the majority of the training that is taken  by individuals to
 become proficient in the use of automotive  refinish products.
 The six individuals who represent these companies on the
 Automotive Refinish Coalition collectively  possess over 150 years
 of experience in  the industry.  They therefore are in a
 particularly good position  to comment on the industry's products
 and the underlying  economics and   operational requirements of
 automotive refinish facilities.

 The Coalition also  has as adjunct members a number of trade
 associations that represent user  segments of the industry.  While
 the adjunct members generally support the positions taken by the
 six manufacturer  members of the Coalition,  they have not had an
 opportunity to  review this  position paper.   Consequently, the
 positions taken should be seen as  representing only those of the
 six manufacturers.

 Objective of the  Coalition;   The  objective  of the Coalition is
 the development   of nationally consistent VOC regulations that
 achieve significant,  real and effective reductions in VOC
 emissions from  automotive refinish facilities while not imposing
 unnecessary additional  costs  or losses  in productivity on the
 automotive refinish facilities.

 Moving to lower VOC containing products  will create enormous
 productivity problems for automotive refinish facilities.  Our
1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549

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concerns on this  score are particularly strong because the
industry has a  large population of small businesses.
Approximately 40% of the shops employ less than five individuals
and have sales  volume of under $150,000 annually, according to a
1988 EPA study  of the industry.

           Effective VOC Regulations  Must Recognize  and
    Incorporate Industry's Practices  and Operational Realities

To achieve the  objectives of significant reductions in VOC
emissions from  automotive refinish facilities at the least amount
of unnecessary  economic disruption to the industry,  a regulatory
program must incorporate fundamental technical, operational, and
economic features of the industry.

Achieving Adequate Matching of Repair to OEM Finish:  Achieving
an adequate repair that matches the existing coat so that the
repaired area is  imperceptible is the central requirement of the
industry.  Thousands of colors and coatings must be available for
all model years of the various car manufacturers to match the
many different  features of thousands of original coatings, such
as their color, gloss, and durability,  as well as the effects
that time and the elements have had on the OEM color and finish.
All of this must  be accomplished at facilities with far less
sophisticated equipment, under much more difficult and
uncontrolled circumstances than exist at the original equipment
manufacturers'  facilities.

Systems Nature  of Today's Products;  Today's products are
provided by individual manufacturers in the form of chemically
complex interrelated components to a single system.   The
components of a particular repair system must be used only within
the system of the particular manufacturer and pursuant to the
manufacturer's  instructions to ensure that the refinish job will
not fail.

Composite Calculation for Multiple Coat Topcoats is Essential;
The use of multiple coats involving a base coat for color and
clear coats for appearance and protection  as well as in some
cases a midcoat  is the predominate  original equipment
manufacturer (OEM) topcoat system.  The appearance of these OEM
topcoats must be  matched by the automotive refinish industry  and
consequently, the industry must use multiple coats in a topcoat
system.

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            Comments Concerning Regulatory Approaches

The RACT VOC Limits of the California Guideline for the Industry
Should be Selected as the RACT Limits for the CTG

The purpose of the CTG is to establish  technology that is the
presumptive norm for "reasonably available control technology"
(RACT) which must be implemented by states in their ozone
nonattainment areas.  EPA has defined (and Congress has accepted)
RACT to mean: "The lowest emission limitation that a particular
source is capable of meeting by the application of control
technology that is reasonably available considering technological
and economic feasibility.  RACT for a particular source is
determined on a case-by-case basis, considering the technological
and economic circumstances of the individual source.  (44 Federal
Register 53761, 53762 (September 17, 1979))

On the basis of this standard — a standard that emphasizes the
economic and technological feasibility of control technologies in
light of technological and economic circumstances of the
sources — the VOC limits that have been established by
California's Air Resources Board's  Automotive Refinish Guideline
for RACT under California's Clean Air Act (which has a much
tougher standard and program for ozone attainment than the
federal law) should be RACT for the national program.  (See
attached chart for the California Guideline RACT limits.)

While the terms "reasonably available" and "feasibility" are not
defined by the EPA, an ordinary dictionary definition of
"feasible" is something that is "capable of being used or dealt
with successfully;"  "available" has been defined in a manner
especially relevant to this discussion as "present in such
chemical or physical form as to be usable;"  and "reasonably"
has among its ordinary meanings "moderate, fair, and
inexpensive."  When the meanings of these terms are coupled with
the requirements of "economic and technological feasibility" and
the additional requirement that the feasibility of the control
technology be ascertained on the basis of the "economic and
technological circumstances of particular sources,"  then
whatever else RACT means, it certainly cannot mean  the
imposition of technology-forcing standards on existing sources.

The California RACT limits have much to recommend them for
adoption in the CTG.

First, by actual implementation in automotive refinish
facilities,  they have been proven to be currently "reasonably
available" and "technologically and economically" feasible.
Second,  they have been established by the toughest clean air
program in the country.   In this connection,  we note that the

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California Clean Air Act has  a much more  stringent  ozone design
value of  .09 ppm  as compared to the  federal  standard of .12 ppm.

The attached chart represents a comparison  of VOC reductions that
could be  achieved by implementing the California Guideline's RACT
limits.

According to the Study's Own  Findings. Option 1 and Option 2
Limits Are Technology-Forcing Standards;  They. Therefore. Are
Completely Inappropriate for  the CTG

By the study's own statements, Options 1  and  2 represent
"technology-forcing" VOC limits, requirements that  are not
currently "reasonably available" as that  term is defined by the
EPA.  Therefore, these options do not qualify as RACT.  Moreover,
if the base coat/clear coat composite calculation method is not
employed, then the limits specified for topcoats under both
Option 1  and Option 2 are not only  "technologically and
economically infeasible" for  the "particular  sources" of
automotive refinish facilities, they  are  absolutely impossible to
achieve with today's technology.

The study indicates that lacquer product  systems are still widely
used by many of the smaller shops that do not have  spray booths.
(See pages  2-7, 2-20 through 2-25 of the study.)   The study also
assumes that such shops constitute  approximately 30% of the
industry.  (See Table 2-1 at  page 2-22.)  Moving these shops away
from lacquer products to other more difficult to use and slower
drying products will be difficult and very  costly.  The
unmistakable implication of the topcoat limits of Options 1 and 2
is that a large number of the industry's  smaller shops will be
put out of business.  The study estimates that the  cost of a
spray booth would be approximately $30,000.   We believe that this
estimate  is low.  And most of these shops are currently grossing
at most $150,000 per year.  Few if any banks, especially in
today's economic climate, would lend  the  amounts needed for such
a capital outlay to the smaller shops.  Consequently, topcoat
limits of Options l and 2 which would prevent the use of any
lacquer system  do not represent a "currently"  "reasonably
available control technology" as judged on  the basis of
"technological and economic feasibility"  of these "particular
sources."

The study also states that, "Option 1 VOC limit had the reported
disadvantage of poorly matching OEM colors  (especially
metallics), indicating that they are  best suited for complete
vehicle refinishing jobs."  (See page 3-4.)   In view of the fact
that the  study also finds that the "..-. the OEMs use metallic and
*pearl' coatings on at least  50 percent of  all new  vehicles	",
it should be clear that the Option 1  VOC  limits do  not constitute
"reasonably available control technology" for this  industry.
Establishing the Option 1 or  2 limits, according to the study's

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own findings and conclusions, would in effect mandate that a
larger proportion of the repairs be accomplished by complete
refinish jobs.   This would necessarily result in the emissions of
more,  not less,  VOCs and would fail to achieve the fundamental
objective of RACT — achieving reasonable further progress
towards attainment.   Additionally, there is the question of
whether establishing VOC limits that "poorly match OEM colors"
for 50% of the vehicles the industry repairs constitutes a
"technologically and economically feasible" control technology
for an industry  that has as its sole reason for being the ability
to make repairs  so that the repair is imperceptible.
The study also contains a number of misleading assumptions
concerning the VOC emissions that should be associated with the
industry's products and operations.  The first of these involves
assuming that the VOC content of products that are supplied to
areas which currently have regulations constitute the baseline
"current technology" of the industry's products that are
generally used in the United States.  (See Table 3-1 at page
3-6.)   In fact,  the majority of the products supplied by the
manufacturers are to areas for which no VOC limits for their
products exist,  including the vast majority of current ozone
nonattainment areas.  Defining baseline technology as the study
does would lead  to  a gross understatement of the contributions
in VOC reductions that properly should be attributed to this
industry introducing lower VOC containing products to areas that
heretofore have  not required  lower VOC containing products.  The
Act's new requirement for reducing by 15% overall VOC emissions
in the top four  categories of ozone nonattainment areas by 1996
will place extraordinary pressures upon all sources to reduce
their fair share of VOC emissions.  Thus it is essential that the
CTG accurately characterize the existing VOC emissions from this
industry in these areas to ensure that it is not tasked with
regulations that exact an unreasonable contribution in VOC
emissions reductions.

Additional misleading statements and assumptions in the study
concern the following subjects:  the statement concerning current
usage of coatings that implies that all coatings material
supplied to refinishers are in fact applied, when approximately
20% — 25% in practice is wastage and is disposed of by
incineration in  which there is no release of VOCs; overstatements
of the required  or recommended film thicknesses; and
overstatements of the paint consumption in each of the coatings
categories.  These are more fully discussed in the submission
from BASF.

We anticipate the argument that since the  California Guideline
1992 limits are  just around the corner and that since some of
these limits are more stringent than comparable limits in Option
1,  the manufacturers should be able to meet the limits of Option
1 nationwide if  they can meet the California 1992 VOC limits in
California.  In  answer to such an argument, we point out that the
                                 701

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products that are needed  to meet  some  of  these limits,  especially
the topcoat limit,  are  still not  yet at a stage of development
that would allow the manufacturers to  introduce them  into
facilities without  substantial expenditures  in time and
resources.  These products will require the  use of spray booths,
which the study itself  notes are  not widely  used by  the smaller
shops which makes up about 30% of the  industry.  Moreover they
will require the use of drying equipment,  because  the products
will be mostly waterborne products with substantially longer
drying times.  In order to maintain today's  levels of
productivity in terms of  the number of vehicles that  are
completed substantial expenditures for drying  equipment will be
required.

Finally there is a  question of scale involved  here.   It should be
noted that the California 1992 limits  will be  confined  only to
certain air quality districts in  California.   While the
manufacturers may have  sufficient resources  to weather  the
problems and expenditures that will be associated  with
introducing these products into   a limited number  of  areas in
California, imposing similar requirements  nationwide  results in
an effect on the manufacturers that certainly  qualifies as
"economically infeasible."

We realize that the EPA is interested  in crafting  a CTG that
accurately reflects what  can  be  accomplished  by the  industry at
the time the CTG is published and that it  is confronted with the
difficulty of a moving  target in  the technologies.  The six
manufacturers have  expended literally  tens of  millions  of dollars
thus far in efforts to  develop lower VOC products  and the EPA is
right to anticipate that  these efforts will  continue.   But this
problem  of RACT being  overtaken  by new developments  is addressed
in the newly amended federal Clean Air Act. which now  requires
that the EPA periodically revisit CTGs to  determine if  technology
has moved ahead of  existing CTG standards.   We suggest  that this
is the only appropriate process recognized by  the  Act for
introducing technology-forcing factors into  developing  CTGs.
Requiring technology-forcing limits in the CTG itself is
completely at variance  with the essential  "reasonably available"
nature of a RACT standard.

We have another suggestion by which this current effort to
determine an automotive refinish  CTG could avail itself of new
technologies that might be available at the  time this CTG is
finalized.  If this CTG development process  takes  until 1993 to
be finalized, it is possible that the  experience gained in
meeting the California  Guideline's 1992 limits in  California will
demonstrate by then that  the Option 1  limits  and  perhaps some of
the California 1992 limits are in fact "reasonably available" in
terms of their "economic  and technological feasibility" for
national implementation.  We note, however,  that,  with  respect to
the California 1992 limits, the industry at  the present time

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does not have a sealer that would meet the limit specified for
this coating.  Because of this and other potential problems of
introducing such advanced systems nationwide, at the present we
believe that a lead time for implementing such limits would be
needed, e.g., implementation in 1994 or 1995.

The Necessity of Base Coat/Clear Coat Averaging For Determining
the Topcoat Limits

The multiple coat system of topcoats is the current predominate
topcoat technology of the automotive manufacturing industry and
the refinish industry must be able to match these topcoats.
Using a composite calculation for the VOC content of the base
coat and clear coat in a topcoat system to determine compliance
with the topcoat VOC limit is dictated by the actual day-to-day
"technological and economic circumstances11 and practices of the
industry.

A statement of the study which may account for the failure of the
CTG Model Rule to include  a base coat/clear coat composite
calculation method is an apparent misunderstanding  of the basis
for weighting base coats and clear coats at a ratio of 1 for base
coats to 2 for clear coats.  The ratio is based upon the actual
usage of the industry.  It is the industry experience that the
volume of base coat paint that is used for any given repair is
approximately on half the volume of clear coat that is used.   In
this connection we refer you to the information that has been
provided by the BASF Corporation which is based upon the actual
usages at an automotive refinish type of operation at the Saturn
General Motors plant and by the Sherwin Williams Company.   In
fact that experience indicates that the ratio is higher, e.g.,
for 1 gallon of base coat, 2.3 gallons of clear coat are used.
The study assumes that because clear coats are a higher solids
product than are base coats, then the volume of clear coat
material that is needed to repair the are covered by the base
coat should be twice  the volume of base coat material.  The
major reason  that the industry generally uses twice the amount
of clear coat material as it does base coat material is the need
to achieve adequate color and finish match for spot repairs that
requires that the clear coat in general be extended far beyond
the area covered by the base coat.   About 90% of the automotive
refinish work that is done is spot repair.

The Systems Nature of the Industry's Products

Because the chemistry of the individual components of a repair
system is highly interdependent,  the components of a particular
manufacturer's system must be used according to its instructions
and cannot be interchanged with the products of another
manufacturer.  The systems nature of today's repair products has
two very important implications for a regulatory system that
limits the VOC content of the products.  First, regulators can
                             If;81

-------
have a great deal  of  confidence that  refinishers will not attempt
to match relatively higher VOC components of one manufacturer's
repair systems with those from another and that therefore the VOC
levels associated  with  a particular system will be complied with.
Secondly, the regulations cannot simply select the lowest VOC
components of the  available repair systems and dictate that these
components be incorporated into every repair system.
and in the right amounts.  As a recent article from an automotive
refinishers professional magazine points out:

     [T]here is no margin for error in applying or mixing today's
     products.  The paint company chemist was able to create a
     product to suit, but only if you do exactly as he says.  Not
     only must the painter combine the correct solvent, catalyst
     and topcoat in the correct percentages, but it must be
     applied over  the correctly mixed undercoats at the correct
     time... There is only one  right way to use today's
     finishes; exactly  according to directions and using only one
     brand.

Auto refinishers will not act as their own chemists; they will
follow the manufacturers' instructions or risk a failed job
without the protection  of a warranty.

Another feature of the  industry that  supports the conclusion that
automotive refinishers  will comply with the VOC limits specified
for products is the VOC compliance instruction material and the
training that is supplied by the manufacturers to users of their
products.

The Need for Specialty  Coatings

It also is essential  to recognize the need for relatively higher
VOC containing specialty coatings.  These products constitute a
very small percentage of the products used by the industry but
they are essential to effectively accomplishing certain repairs.
An important example  of these are  "uniform finish blender"
specialty coatings to make spot repairs.  This specialty coating
blends the repaired area in with the  surrounding original finish
to match all facets of  its appearance, including color, metallic
orientation, texture, and appearance.  Greater VOC emissions
would occur if refinishers do not have the ability to perform
spot repairs because  they would be required to paint an entire
panel of the vehicle  or the entire vehicle itself in order to
achieve acceptable results.

We recognize that  the model CTG includes the category of
"specialty coatings."   But its characterizing them as being
"reportedly" needed for unusual job performance requirements,
however, concerns  us  because that implies that the need of these
products is debatable.  The special role of specialty coatings
should be emphasized  by the CTG.  It  should not be implicitly

                                8

-------
questioned by the CTG which might invite states to modify the CTG
by removing the category.

We also recommend that the California Guideline's definition of
specialty coatings should be adopted.  The definition does not
limit the type of coatings that can fall into this category but
restricts the coatings to 5% the total volume of coatings applied
by an automotive refinish facility.  This approach allows for the
development of additional specialty coatings and the 5%
restrictions ensures that the category will not be abused.

The Gerieral Use of HVLP Spray Guns Results in Significant
Reductions of VOC Emissions and Should be Encouraged

The efficiency of transferring coatings to the vehicles has been
greatly improved by the use of high volume, low pressure (HVLP)
spray guns.  The resulting VOC reductions that accompany the
reduced amount of coatings material that is required because of
the improved transfer efficiency should be explicitly recognized
by the regulations.  To do otherwise deprives this industry of
having credited to it significant VOC reductions that in fact
result from the use of HVLP spray guns.  The unwillingness of the
EPA to explicitly recognize and to credit VOC reductions
associated with the use of the equipment is a hidebound adherence
to notions concerning "quantification" and "replicability" of VOC
emission reductions.  These principles were established for a
regulatory regime that focused on well-heeled and richly staffed
large stationary sources which lent themselves to such precise
demands for crediting VOC reductions.  The 1990 amendments to the
law, however, require the regulation of much smaller sources and
therefore the EPA's  VOC emissions reduction accreditation
principles must be retailored to measure the effectiveness of
regulatory controls that are appropriate for the much smaller
sources.

As the study notes, appropriate training has a great deal to do
with the efficacy of HVLP use.  In this connection,  it should be
recognized that extensive training is provided in this area by
the manufacturers of automotive refinish coatings and others.
Further, aside from the regulatory requirement to use such
equipment, autorefinish facilities have a very strong economic
incentive to use the equipment to reduce their consumption of
coatings.

It also should be noted here that the study seems to assume a 35%
transfer efficiency for the conventional spray gun but is
unwilling to assume any transfer efficiency for the HVLP-  This
is anomalous in that any problems that are associated with
achieving effective transfer efficiency with the HVLP spray gun,
such as variability in operator use and the shape of the object
being coated, also apply to conventional spray guns.
                             1-83

-------
The experience of the Coalition is that the use of HVLP spray
guns results in reductions of 20% — 45% in materials usage and
some credit for the resultant VOC reductions should be given.

Add-On Controls

The various engineering add-on control technologies identified by
the study for facilities would be cost prohibitive and or
technologically infeasible for the great majority of automotive
refinish facilities to adopt at this time.  Nonetheless, the
regulations should recognize such controls as voluntary
alternative control techniques that could be used in lieu of
lower VOC containing products.  The technology of add-on controls
could improve in the near future, perhaps rapidly,  and they
could come to represent cost-effective alternative compliance
methods.
                           Conclusion

The objective of the CTG is to establish a guideline for what is
the presumptive norm for "reasonably available control
technology" (RACT) under the federal Clean Air Act.  In
developing such a guideline,  the "reasonableness" of the
technology is to be considered as well as both its
"technological" and "economic" feasibility-  On the basis of
these criteria and our knowledge of the industry — the available
coatings technology and the operational and economic requirements
of automotive refinish facilities — we believe that the VOC
limits specified for RACT in the California Guideline should be
the limits established by the CTG.  The adoption of these limits
from a program that is much tougher than the federal program will
ensure that the industry contributes more than its fair share of
VOC emissions reductions in the nation's ozone nonattainment
areas.  We also believe that specialty coatings must be
explicitly recognized as an essential technology for the industry
to achieve VOC emissions reductions.  Further,  it is absolutely
critical that the multiple coat composite calculation technique
for determining compliance with VOC topcoat limits be recognized.
This is the way the industry applies the topcoats and it is the
only way that VOC limits for increasingly waterborne topcoats can
be met.  The contributions made by HVLP spray guns should also be
recognized by the CTG.  Finally add-on controls should be
recognized as a voluntary alternative compliance method.

The possibility that the Option 1 or even some of the California
Guideline's 1992 VOC limits may be demonstrated to be "reasonably
available" by the time the CTG is finalized in 1993 is also worth
considering.  The six manufacturers would concur in such an
approach provided that before the limits are adopted as part of
the CTG, the technology has in fact been shown to be reasonably
available and that an appropriate lead time is afforded (e.g.,
until 1994 or 1995)  to ensure that the products in fact are
"reasonably available."

                                10
                                  O F
                                   '

-------
ON OF VOC EMISSIONS REDUCTIONS

                GARB'S GUIDELINE
% Of
Total Coatings
2 CTG GARB Coatina Cateaorv

31%
-
6%
9%
5%
-
9%
8%
0%
0%
•
2% . 1%
. 1%
12% . 12%
*
•
5% . 5%
»
58% . 17%
. 41%
•
8% . 8%
•
•
10% . 10%
•
5% . 5%
•
Pretreatment Wash
Primers
Precoats
Primer/Primer
Surfaces
Primer Sealers
Topcoats***
Metallic/
Iridescent***
Surface Cleaning
Enclosed Equipment
Cleaning
Specialty Coatings
Transfer Efficiency
Baseline GARB
VOC RACT

6.
6.
6.
6.
6.
6.
6.
6.
7.

7
7
7
7
7
8
7
7
0
25%

6
6
6
6
6
6
1

.5
.5
.0
.0
.0
.0
.7
88%
7
.0
45%1
•s

0.
0.
2.
2.
3.
8.
6.
0.
2.
0.
GARB'S
1992 Limits**

1%
1%
3%
3%
2%
7%
0%
8%
8%
0%

6.5
6.5
2.8
3.5
5.0
5.0
1.7
98%
7.0
45%1

0.
0.
12.
4.
22.
19.
6.
0.
2.
0.

1%
1%
6%
3%
8%
5%
0%
8%
8%
0%
0%
GARB GUIDELINE

Reductions Achieved    -0-
26.3%
69.0%
y data.  Should be based on uncontrolled emissions survey data.

n 1994 - 1995 once technology has been demonstrated in California in  1992
Calculations.
ies in column expect for enclosed equipment cleaning and surface cleaning.

-------
                                                                 National
                                                                'Paint&
December  2,  1991
                                                             Association

               NPCA Automotive Refinish Coalition's

                  Additional Comments Concerning

         Technical and Factual Issues Raised by "the Study

The  study is an attempt to  review and  analyze the  current
technologies,  economics, and  operations of the  automotive
refinish  industry to determine the reasonableness  and technical
and  economic feasibility  of  VOC emission reduction  technologies.

The  study,  in  our view, represents an  honest effort  to portray
the  industry accurately  and  demonstrates a sound  grasp of the
basic  features of the automotive refinish process.   Nonetheless,
it contains  a  number of implications,  statements,  and conclusion
that are  inaccurate or misleading.  Since the study  will be the
basis  for standards that will be adopted for this  industry
through a CTG, it is important that it accurately  reflect the
real world of  this industry.

The  following  are a number  of points of disagreements or areas in
which  we  believe a fuller picture is required than what is set
out  by the study-

General Overview of the Industry

We have reservations concerning the characteristics  that the
study  assigns  to various shops as model shops.  This is not to
say  that  we  disagree with all of the study's characterizations or
that we so not appreciate the difficulties associated with
efforts to get a handle on  an industry as diverse  as the
automotive refinish industry.  Nonetheless, we  urge  caution in
extrapolating  from these model shops  to real world  shops.  Some
shops  —  perhaps many — will not fit  neatly into  anyone of the
models.   This  is particularly true with respect to the types of
coatings  that  may be employed by various shops.

The  study also seems to fail  to grasp  the fact  that  coatings
reformulations are not easily accomplished.  Besides the very
difficult task of having to reformulate literally  thousands of
colors to match the diverse automotive population, these new
coatings  must  be transferred  effectively into the  production of
the  shops.   When the coatings become increasingly  waterborne,
they become  much more difficult to reformulate  and they become
even more difficult to train  the end user in how to  use them
effectively.   Lower solvent products are more difficult to use
and  are less forgiving of mistakes.  The transition  to waterborne
products  is  an extremely difficult task and should be recognized
as such.

                              1. -88
1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549

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Coatings Issues

There are several statements in the study which misapprehend the
technologies of current or future coatings or the usage of such
coatings by the industry.

The most important misunderstanding concerns the base coat/clear
coat technology for topcoats.  Actual industry usage of these
coatings demonstrates that the coatings are in fact used at a
ratio of more than 2 clear coat materials for 1 base coat.  The
primary reason for this is that in applying the clear coat in
spot repairs, the material must be extended beyond the repaired
area to match the original finish.

The systems nature of the industry's coatings also is not fully
understood by the study.  The systems nature of today's coatings
is a fundamental fact of the industry and it applies to the
entire range of coatings, including undercoats and not just
topcoats.  The failure of the study to fully understand this
leads to a number of misleading assumptions.  An example of this
is the implication at page 2-8 that non-isocyanate hardeners are
generally available to replace isocyanate hardeners.  In fact
this is not true if the product system involved is based on
isocyanate products.  Also, the study's definition of coating
"system" at page 6-2 limits the systems to primer-topcoats.

The components of automotive refinish product systems are
designed to work together only within a particular manufacturer's
system.  At page 2-20, the study implies that the components
could be made interchangeable if the manufacturers spent
sufficient time and money on the effort.  As an abstract
statement, this comment is true.  But it fails to recognize the
tremendous costs of such an undertaking to the manufacturers and
to the shops and the public in the form of failed jobs.
Additionally, the product differentiation that accompanies the
systems approach is a valuable incentive for the manufacturers to
continually improve their products secure in the knowledge that
technological breakthroughs that for example lower the VOC
content of products will not be easily replicated by their
competitors.

The industry is moving to waterborne products.  That is a fact of
life and the manufacturers have spent tens of millions of dollars
to develop these type of coatings.  Nonetheless, these coatings
are not yet generally available as is implied by the study at
page 3-17.  Also the statement that waterborne higher solids
primer sealers are simply "lagging" is also misleading — they
are much further away from being practical coatings than
"lagging" implies.  Perhaps some of the confusion on this point
arises from the study's understanding of what constitutes a
waterborne coating.  On this score the study at page 2-8 implies
that waterborne systems have only 5%  water as their volatile

-------
fraction.  In fact, the industry considers a product waterborne
when it has 85% of its volatile fraction as water.  Also the
study fails to adequately address the additional  waste  water
disposal costs that will attend the wider use of such products.

On a related subject, at a couple of points the study indicates
that the key ratio for determining the VOC content of a product
is its solvent/solids ratio.  (See page 3-4.)  We agree with this
concept but believe that the  "less water" calculation technique
required by the EPA for determining the VOC content of products
is at variance with this fundamentally sound notion and should be
changed accordingly.

Also with respect to waterborne coatings the study fails to take
adequate account of the additional hazardous wastes that will be
generated by the wider use of such coatings and the attendant
disposal costs.  (See pages 5-13 and 5-14.)  Nor does it
adequately weigh the losses in shop productivity that will
accompany the wider use of the products. (See page 5-17.)  Drying
times will increase greatly and shops without drying booths will
be reduced to completing one half to one third of the vehicles
that they now can complete with solvent borne products.  The
ability to refinish vehicles at a reasonable cost will disappear
and the insurance premiums consumers have to pay for collision
insurance will increase dramatically.

The study also grossly overstates the current volume of products
that are used by the industry- (See the comments from  BASF.)  At
pages 2-3 and 2-4 the study wrongly suggests that a pretreatment
coating is exclusively used with solvent borne systems and a
precoat is exclusively used with  waterborne systems.  Further,
the discussion of adhesion promoters at page 6-2 should be
clarified to make clear that the material is also applied at the
edge of the unsanded area.  In a related point, the study fails
to recognize adequately that specialty coatings constitute  a
very small percentage, less than 5%, of a shop's total coatings
usage and that these products are critical to the shop's ability
to effect certain repairs.  While it is true that these coatings
are higher VOC products, they constitute such a small percentage
of usage that it makes no sense to focus on lowering their VOC
content when the R&D efforts could be better put to reducing VOC
levels in the larger volume products.


Technology Issues

The study contains  number of factual statements concerning
technology issues involving spray booths and HVLP and
conventional spray guns that are misleading.

As to the spray booths, the study at page 2-9 implies that all
coatings are applied in a spray booth.  In fact a number of

-------
coatings,  particularly undercoats, are generally not applied in a
spray booth.  The implication of this is that waterborne products
that are used for undercoats generally would not be accommodated
in a spray booth that could reduce drying times.  Hence, the
widespread introduction of the waterborne products would as
things now stand greatly reduce productivity at many facilities.
In this regard the study greatly understates the costs of
introducing the technology, by focusing exclusively on the costs
of the products and capital equipment.  In fact, significant
productivity losses will accompany the use of waterborne products
and these costs must be taken into account in evaluating any
regulation that would impose them.

As to spray guns, we address the need to recognize the efficacy
of HVLP guns in the body of our comments.  As we state there,
HVLP spray guns do reduce VOC emissions and should be properly
credited for doing so in the CTG.  The study acknowledges at
various points that transfer efficiency in the use of the HVLP
guns can be greatly enhanced through appropriate training and at
page 3-16 stresses the important role played by the manufacturers
of automotive refinish coatings in providing this training.  It
is ironic that much costlier and in our view questionable add-on
controls are considered as potentially effective by the study and
yet the efficacy of a reasonably priced piece of equipment like
HVLP spray guns receives such short shrift.  The study should
recognize the importance of this relationship and see the
manufacturers as more of a partner in assuring lower VOC
emissions from automotive refinish facilities.  In the same
connection, however, the study fails to recognize certain
inherent difficulties that are associated with the use of any
spray gun by implying at  page 2-4 that blending the edge of the
refinish area with the original topcoat could be achieved as
readily through use of the spray gun as it is achieved through
the current practice of employing more dilute blend coats.

The discussion at page 2-15 of the problems of introducing
electrostatic spray guns into automotive refinish shops  merit a
fuller treatment, especially the great risks of fire and of
electrocution that arise if this equipment is not used in
accordance with very strict operating procedures that will be
difficult for many shops to observe.

Add-On Controls

Add-on controls are dealt with fairly evenly by the study at
least in the conclusion that such controls are not presently
generally feasible for the majority of automotive refinish
facilities.  Whether the study's cost estimates for these
controls are accurate (and we believe that they understate the
costs greatly), in the end the study reaches the  appropriate
conclusion that such controls should not be imposed on automotive
refinish facilities as RACT.  We might add that in our opinion,

-------
imposing such controls on the facilities would drive 75% of the
existing shops out of business.  And some of the technological
assumptions concerning such controls are very misplaced.  For
example, it is inconceivable that with today's technology that a
biofiltration system would work at any automotive refinish
facility.  The VOC emissions are simply too varied for any body
of microbes to handle effectively.  Also, incineration is simply
not an effective control technology for automotive refinish
facilities because of the intermittent nature of the emissions.
As to carbon absorption, the study  fails to consider adequately
the costs associated with maintaining such a system, the
decreasing ability of the carbon filters to absorb pollutants
each time they are cleaned, and the hazardous waste that would be
generated by the use of the system.

Despite the admitted problems with add-on controls, we believe
that such technologies should be recognized in the CTG as a
voluntary alternative compliance option.  As the population of
automotive refinish facilities changes, in part due to the VOC
limits, and as the technology of add-on controls improves, this
technology could become more viable and we believe that the
technology should be recognized as a voluntary alternative
compliance method.  The modified version of the SCM which we are
suggesting as the model for the CTG contains such an alternative.

Discussions of Costs

The study's discussion of the additional costs that would be
associated with moving to more waterborne coatings do not address
what will perhaps be the greatest costs associated with their use
— losses in shop productivity.  For shops without drying
equipment the use of these products could well cut their ability
to refinish vehicles to one half or a third of what it is today.
Additionally, the costs of R&D  that are incurred by the
manufacturers of the coatings are not counted nor are the costs
that will be incurred in introducing these more difficult to use
products, including job failures that will inevitably accompany
the widespread use of the products initially.

Appendix D of the Study

Appendix D of the study, whether intended or not, represents the
distillation of a draft CTG that may be picked up by the states
before the CTG process is completed.  Our concerns here are
particularly strong because of the requirement of the federal
Clean Air Act Amendments of 1990 that call for the adoption of
RACT by many ozone nonattainment areas by 1992 — the so-called
"RACT Catch-Up" requirements.  In reconciling  this 1992
requirement with the 1993 due dates for new CTGs, including the
automotive refinish CTG, the EPA has stated that states may use
draft CTGs.  We have had some indication that the regulations set
out in Appendix D  will be substantially modified in the final
                             T w O |
                             JL ii J1

-------
CTG.   We strongly urge  that Appendix D be eliminated from the
study to avoid any confusion on the part of the states during the
interim.

-------
           OSfPDKD
    VOC DATA
EETS
Jr. 1

cs
ro
          RULE 1151
 H.17T.M

-------
The following VOC data is being provided to you to meet the requirements of the South Coast Air Quality
Management District'.1; Rule 1151. It /.v divided into the following pa gen for easy reference,
Page 1        An explanation of each category of the Du Pont COATINGS USAGE CHART used to record daily
             VOC emissions.

Pago 2       An example of a completed COATINGS USAGE CHART.

Page 3-6     VOC data for surface cleaner, precoal coating, primer, single stage, basecoat, and clear. This data is
             reported on maximum VOC and pounds per gallon less water and exempt solvents basis.

Pago 7       Calculation for LI3S of VOC' when divided by the amount actually sprayed.

Pago 
-------


' 1-l|e i'amier Name
or
Initials


7-1 John Doe



\- ''
gs
^
Ooalinps: Puini
Surface Prop, C
Manul. Type
&
Code

Example 1
B 8635A
Example 2
210S
Example 3
B8635K
Example 4
7500S
, Primer
,'lenmip Solvent
VOC VOC less
(g/1 or Waicr &
Ihs/gal) |less exempt

Solvent
i . .
5.2 r 5.2

0.6

5.9


1.9 1

5.9

5.3 5.3

Oil nly si /I liirdoiuT/Addilivc
Miiniil'iii'liiiei i VOC
& 1 (g/l or
Code


793S

-

-

7575S
Ihs/gal I


1.9

-

-

4.2
VOC' less
Water &
less exempt
Solvent

1.9

-

•-

4.2

Tli iniuT/R (Mincer Solvent
Manufacturer
&
Code


V-8096S

-

V-7I60S

-
VOC
(g/l or
Ihs/giil)


6.9

-

6,6


VOC less
witter &
ess exempt
Solvent

6.9

-

6.6

-

Total amount of
comings used



1qt.

1 qt.

2qts.

3qts.
Mix Ratio Gross VOC VOC "a- L.:^
Coaling/ Vehicular ";!•. applied" Applied" k"-< c'f VOC
Solvent Weight water & !e«
exempt solvent
i
8:1:2 : II 5.2 5.2 1.3
I
RTS i II - 1.9 .5
I
1:1 ; II 6.2 6.2 3,1
i
4:1 | II 5.1 5.1 3.8

-------

,m- I'niniL'i Njuno
"or
nilials
A B
Coatings: Paint, Primer
Surface Prep, Cleanup Solvent
Mamil. Typo VOC
& t.g/1 or
Code Ihs/pal)
C D
i
VOC less
Winer &
less exempt
Solvent

Cntnlyst/Hnrdcncr/Addilivc
Maiuifiieiurer
&
Code
F
VOC
(U/l or
llw/giil)
G
v(x: less
W.-iicr &
less cxempi
Solvent
H
Thinner/Reducer Solvent
Miimil'iieiuri:r
&
Code
1
voc:
(g/lor
Ihs/gal)
J
VOC less
wilier &
less exempt
Solvent
K

Total amounl of. Mix Ratio. Gross VOC VOC "a« l.r>v
coalings used ! Coaling/ '• Vehicular "as applied" Applied" lc« tn' VOC
(quarts or gal) | Solvent i Weight water & lc«
j : exempt solvent
L M ! N 0 P Q
i 	 '"! 	
                                                             Coatings Usage Chart Explanation
     ,J\
The date in which the material is sprayed.

I'hc name or initials of the painter actually spraying,

The formula or product number. (Include the total alpha-numeric formula.)

I hr m.minimi Vl)('  nl ihr individual i/oaliiu1, without ivdnirr in  eaialyM. as lislcd in
ihe On Pont VOC Data Sheet. (The ColorNet computer or microfiche lists VOC' of
each color coating.)

The VOC in this column is (lie same as "D"  *

This column is Cor hardeners or catalysts,

The VOC of (lie individual hardener or catalyst, obtained from VOC data sheet.

The VOC in this column is the same as "G" *

List the On Pont solvent number.

The VOC of Ihe thinner/reducer as stated on the VOC data sheet.

The VOC in this column is the same as "J".*

This column lists (lie amount of material actually sprayed.'

\li\ini; raiio of all components.  This information is listed on the  VOC ilaia sheet,
N.  There are two ealegories:

    "1" greater than or equal to 8500 Ibs. G.V.W. (> or = 8500 Ibs.)

    "II" less than 8500 tbs. G.V.W. (< 8500 Ibs.)

().  VOC' "as applied" means the ready to spray VOC of Ihe material applied in relation to
    the mixing ratio and VOC of the individual components. Also called "ready lo spray"
    or"RTS"

P   This column is the same as "0",*

Q.  This column represents the total pounds of VOC emitted, based on the "ready to
    spray", pounds per gallons of the coating and quantity actually sprayed.
    For example: the  ready to spray VOC of 7500S is 5.1.  Three quarts were actually
    sprayed, see example 4 on  page 2.
*  The column is different only when recording the following list of products which
   contain waier or exempt solvent:
   2! OS      225S        227S         616S         3929S        57 ITS
   224S      226S        244S         620S         5662S

-------
VOC DATA SHEET
    RULE 1151
SURFACE CLEANER
MAX. VOC loss
MANUFACTURER TYPE 4 CODE ^ ! ™p|
Ibs/gal) j Solvent
PREP-SOL' II
3929S 1.2 i 4.9
I
!
1
PRETREATMENT COATINGS
t '•
—-3
us
sr>
5717S 1.4 ' 3.7
224S . 0,0 i 0.0
225S .;..1.3.. 3.9.. .
226S i 0.0 " i 0.0
227S : 0.0 ! 0.6
244S ; 5.7 | 6.5
i
PRECOAT COATING
VARIPRIME'
615S j 5.2 , 5.2. ._
615S : 5.2 ! 5.2
; i
I
I
PRIMER
WATERBORNE
210S 0.6 ' 1.9
Cnliilyst/IInrdencr/Addilivc
M;inul';u.'iuivr
K
Code
VOC'
(i:/l or
Ins/gull
VOC less
Winer &
less exempt
Solvent
— | — i .—



. 	 ; 	 i
1 i
	
—
	 _
I
1
i
j
1
- - - - -i — ' -
61 6S
620S

6.5
6.2

— :
,

6,6
6.3

—
Tli in nor/Red ticcr Solvent
Mumil'iieliirer
K 1
Code
-

WATER
WATER
• ~

—

—
voc
tg/l or
Ihs/gnh
VOC loss
wmer &
less exempt
Solvent
— i
•

. ^ .
—








- •

Tdliil iimoiilil i)l Mix Riltio Clross VOC' VOC ";is l.hv
conlhi.us used i C'oiiUMi!/ Vehieuliir ";i* .ipphed" ApphoU" le^1- "!' VOC.'
(i|Uiirl.s or gut) ! Solvent Wei.ehi unier & loss
1 • excmpi solvent
RTS 1.2 4.9
j
1:1 3.7 37
RTS 0.0 0.0
1:2 3.9 3.9
RTS 0.0 0.0
. RTS 0.0 0.0
RTS 6.5 6 5
;
	 	 1:1 . .. 5.8 . 5.9
1M 57 57
1
RTS 06 19

-------
VOC DATA SHEET
    RULE 1151
"»
SURFACE CLEANER
i MAX.
! \jf \p
MANUFACTURER TYPE i CODE i (^f
Ibs/gitl)
PREP-SOL' II
3929S i 1.2
i
I
VOC less
Winer &
less exempt
Solvent
4.9

PRETREATMENT COATINGS
f*
r)
<*£>
.>. V()(' VOf'";is !>>..
ciKiliMji-i used i Gulling/ Vchii'iibr "n- .ipplietl" Applied" le^x pi' VOC
(((linns or gill) I Solvent Weijiht uuier A Ic^v
i . exempt solvent
RTS 1.2 4.9

1:1 3.7 37
RTS 0.0 00
1:2 3.9 3.9
, ,.-RTS °-° ° °
	 :'"RTS. ... 0.0 ^ 0,0
	 : RTS 6.5 "' 6.5
;
. 1:1 5.8 5.9
1 : ' "i 7 IS 7
I
RTS 0.6 1.9

-------
         ATTACHMENT B




Article from BodvShop Business

-------
                                PaintShop
         Common   Complaints,
                Specific  Solutions
                                 by Mark Clark
        n these days of fast-paced
        produce/deliver auto repaint-
        ing, it's haro^tp get a simple
 explanation for tne~cause of common
 painters' problems. In this series of ar-
 ticles, we are going look at some of the
 most common complaints and try to
 explain in simple terms (no degree in
 chemisty required) what went wrong
 and why. These discussions are as ge-
 neric as possible, and no one brand of
 paint is being promoted over another.
  And that leads us to the absolute
 quickest way to reduce all your paint
 problems, no matter what brand you're
 using or what part of the country you're in.
  You can reduce your painting related problems by —
 ready? — 50 percent. Sound like something you'd be
 interested in? Instead of  10 problems a week or 10
 problems a month, you can skip right down to only 5
 problems.
  How? It's easy, it's simple, and it's guaranteed to
 work. Use one brand all the way through, follow a sys-
 tem! When all the undercoats, solvents, topcoats and
 clears are guaranteed compatible, you'll have 50 per-
 cent fewer problems. Problems like adhesion, durabili-
 ty and re-coatability drop to the very minimum.
  The notion that any shop painter can don the chem-
 ical  engineer's hat and start mixing products and
 systems goes back to the days when this business was
 much simpler.
  Back in the days when most undercoats were a lac-
 quer base and most topcoats were either lacquer or a
 simple acrylic enamel, shop painters figured out that
 they could substitute a cheaper solvent from some oth-
 er manufacturer and then color with yet a third brand
 and seldom have problems.
             Like the paint reps say, one of the
            hardest guys to deal with is the paint-
            er who combined-several brands^nd
            didn't have a problem, once or twice or
            even ten times. Then, when his "sys-
            tem" doesn't work, he can't accept the
            fact that he was just lucky each of
            those other times.
             The reason that intermixing is such
            a tremendous risk these days can be
            traced back to the vehicle manufactur-
            er. The consumer keeps demanding a
            better looking, more durable, more
            corrosion-resistant finish. The manu-
            facturers have been able to deliver
OEM finishes hundreds of times better than just a feu-
years ago. Now here comes that super high-tech finish
into the body shop to be repaired "as good as new."
  The aftermarket paint companies have really had to
scramble to create air dry (no heat or electricity like
OEM) finishes durable enough to match original
equipment. This, as you might imagine, was quite a
trick.
  What this means to body shop painters is that there
is no margin for error in applying or mixing today's
products. The  paint company chemist was able to
create a product to suit, but only if you do exactly as
he says. Not only must the painter combine the correct
solvent, catalyst and topcoat in the correct percent-
ages, but it must be applied over the correctly mixed
and applied undercoats at the correct time.
  There is only one right way to use today's finishes:
exactly according to directions and using only one
brand. Besides reducing your paint problems 50 per-
cent, several other benefits also occur. You will have
fewer products  (read that — dollars) in your inventory,
                        (continued on pg. 82)
80 / June 1990 / BodyShop Business

-------
 /continued from pg. SOt
 and since the same system is used all the Lime, every-
 one gets good at it and more work is produced in less
 time. Knowing what one line will do under a variety
 of conditions is better than guessing what a vari-
 ety of products will do under the same  condition.
   Now. having solved one half of your paint problems,
 let's take a look at some of the other ones that are left.
        It's simple to  solve
  half your  paint problems.

   One of the most common and frustrating paint prob-
 lems is die-back. Die-back means that over time the
 paint job loses the gloss it once had. Only one thing
 causes die-back: trapped solvent. It is always at the
 root of an}' die-back. Well that was simple, right?
   The mystery comes up when you try to decide where
 the solvent was trapped. It could be in the primer, the
 primer-surfacer. the sealer, the color coats or the clear-
 coats. Choose one or two or more! All your paint pro-
 ducts have solvent in them, some you add more sol-
 vent to. If you rushed the flash off time on any of the
 products, (who. you?) there is still solvent that wants
 to escape into the air. When it does, it has the same
 effect on the finish as wiping the  car with a solvent-
 soaked rag.
   Maybe the most common die-back occurs when a
 complete paint job is shot late in the day because the
 dust in the shop is at a minimum.
   The painter is the last guy in the shop and after the
 third coat, cleans his equipment, shuts off the fan and
 the light and heads home. When he returns the next
 morning, his great looking, super glossy paint job has
 died back and dulled down.
   What happened was that the bulk of the solvent rose
 up out of the paint film into the air where it should
 have been swept away by the air movement created
 by the fan. With no  fan  running, (to keep the job
 cleaner he thought) the solvent rose to the top of the
 paint  film and just lay there — thus, die-back.
  The solution is to run the fan  for a good 45 - 60
 minutes after the last coat.  At the end of the hour, shut
 off the fan and open the booth doors. You're out of
dust by then, and the air  moving in the open doors
 will help the last of the solvent to evaporate off.
  Air movement plays a big role in die-back. Take this
example: You're painting a  car  in a  two-stall ga-
          rape with little or no air movement. The tempera-
          ture is 70 F  All you  need  is the correct solvent
          for 70 F and the correct .flash time  between coat^
            Now, the same car.  the same 70 F, but you're
          in a crossdraft spray booth with average air move-
          ment.  You need to choose a solvent as if it were
          10° warmer (80 F) because of the air's drying effect.
           Third time, same car. same 70 F, but in a downdraft
        .  booth  with lots of air movement. You now need a
          much  slower drying solvent; in fact, almost 20°
          warmer. You must reduce as if it were 90 F in the
          booth. All that air whistling past causes the surface
          of the paint film to skin over before all the solvent can
          evaporate out. That trapped solvent will eventually
          work its way out, causing extra work for you, and
         -distress for your customer.  Beat this problem by
          choosing the correct solvent for each of your under-
          coats and  topcoats. Equally important, wait the
          recommended flash time (or more) between  coats.
           Another common problem, solvent popping, is caus-
          ed by exactly the same trapped solvent that causes
          die-back. Only in this case, there is so much solvent
          trapped under the prematurely dried "skin" that it
          will Literally burst out of the paint film, leaving little
          craters with a hole on top.
           Solvent poppingis violent die-back. The solution is
          to immediately move to a slower drying solvent.
           When you must re-do something because of die-back
          or solvent popping, sand the finish as soon as you can
          and let it sit around the shop, sanded, for as long as
         possible. When you sand, you open up the paint film.
         giving  the solvent a hole to escape through.
           Another  common problem  is clearcoat  de-lam-
         inating (peeling)  off the color coat. There are two
         likely causes.  How soon the customer comes back
         gives you a good clue as to which one you've got.
           If the customer is back within 8-10 weeks, it is most
         likely a compatibib'ty problem. In other  words, the
         clearcoat never had  an intercoat bond with the
         basecoat and was just "sitting" on the base color.
           There are two kinds of adhesion: mechanical and
         chemical. Mechanical means that you have abraded
         (sanded) the surface to increase the area of contact
         with the next product (i.e., up one side of the sand-
         scratch and down the other means more surface area
         to meet the new coat). Chemical adhesion depends on
         putting a chemically compatible product over anoth-
         er in the correct time frame. You may have the cor-
         rect product, but let your base color dry too long and
         the clear can get  no bite into it.
           If it has been longer than 8 to 10 weeks before the
         customer is back with peeling, chances are the clear-
         coat wasn't applied thick enough.
           The main enemy of your paint  finish is the ultra
         violet rays of the sun. It's hard to put very many UV
                                   (continued  on /Jt
82 / June 1990 /  BodyShop Business
11.00

-------
(continued from p%. 82)
screeners in n clcarcont because then it. isn t clear any-
more. Some of j'our ciearcont's durability depends on
having o thick enough film to withstand the UV.
  What happens many times is that the clearcoat was
applied at an acceptable mil build but was later wet
sanded and buffed to get rid of dirt.
  If, for example, you had two mils of clear in two
coats, you'll take one mil off when you sand and-polish.
The one mil you have left will not stand up very long
to the sun. Now the U V rays come streaming through
the clearcoat and oxidize the base color. The sun's rays
destroy the binder in the color coat, leaving only the
chalky pigment to which the clear won't stick, and off
it comes! The solution is to put on more clear.
  If you know you're going to buff, add an extra coat
for the buffer to remove. This will leave enough clear
film behind to hold out against the sun. Don't worry
abou t getting your film so thick that it will crack, to-
                ri ay s urcthane enamel clears remain flexible up to a
                build of 20 mils or more. There is not, however, much
                to be gained in gloss by going past three to four coats.
                 Next time we'll look into the most common lifting
                problem, discuss a clever solution for blushing and
                examine some clues to where your fisheyes might be
                coming from.  •
                   BodyShop Business is'starting a question and~
                 answer forum for your painting questions. If you
                 have something that you 've always wanted to know
                 and can't seem to find an answer for, send us the
                 question. We can not answer questions about
                 specific brand-name products — address those to
                 your paint rep or jobber. Ask us the "how come"
                 kind of questions. Using a panel of experts, we 'II
                 answer in print the best questions. Thanks for your
                 interest!
                   Classified   Paae
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          818-796-8804
Circle 95 on Reader Service Card
 DISTRIBUTORS WANTED
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      Call (515) 262-4899
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    Classified Ad Space

 BodyShop Business classified
 advertising is available for $195
 per insertions. Six or more ads
 per year are $175 per insertion.

 Classifieds measure 2-1/8 x
 1-1/2.

 Ads can be purchased in double
 units (2-1/8 x 3") for S390 per
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 Advertising deadline is the first
 of every month.

 Contact BodyShop Business Ad-
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 216-535-6117.
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    NEW IDEAS?

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 678-5548
                                                                  6920 S.W llllh Avenue • Beaverton. Oregon 97005
                                        1.101.
                          BodyShopBusiness / June 1990 / 105

-------
                                                      5SD DRAFT 11/7/90
                      DRAFT PROPOSED DETERMINATION OF
                  REASONABLY AVAILABLE CONTROL TECHNOLOGY
                                    AMD
                 BEST AVAILABLE RETROFIT CONTROL TECHNOLOGY
                                    FOR
                   i.  AUTOMOTIVE REFINISHIN6 OPERATIONS
I.    APPLICABILITY

     The provisions of the proposed determination shall  apply to all
     automobile refinishing operations that Include the  finishing or
     refinishing of motor vehicles, mobile equipment and their parts and
     components except as specified in Section IV A   This determination
     shall be considered RACT except where indicated as  BARCT.

II.  DEFINITIONS

     A.  Antiglare/Safety Coat 1 no means a  coating which  does not reflect
         light.

     B-  Basecoat/Clearcoat System means a topcoat system composed of a
         pigmented basecoat portion and a  transparent  clearcoat portion.
         Basecoat/clearcoat systems'  VOC content  shall be calculated
         according to the following formula:
         VOCT..   .      bc  *  2  VI>Ccc
              bc/cc   - - --
                              V

         Where:

         VOC Tbc/cc  1s the  sum of tne WC content as applied in the basecoat
                      (be)  and clearcoat (cc) system.

         VOCbc   is the V(:)C  content as applied of any given basecoat.
         2VOCcc  is two times the YOC content as applied of any given
                clearcoat.

    c-  Camouflage Coating means a coating applied on motor vehicles to
        conceal  such vehicles from detection,

    D.  Catalyst means a substance whose presence initiates the reaction
        between  chemical compounds.

    E.  Color Match means the ability of a repair coating to blend into an
        existing coating so that color difference is not visible.

    f.  Electrostatic Application means the application of charged atomized
        paint droplets which are deposited by electrostatic attraction.
                                   -.1-

-------
                                                          i i LI 11
6.  Executive Officer means th« Emotive  Officer or A1r Pollution
    Control Qfflctr. or his or her  dajftgate-  of  an air Quality
    manaement district O  an air   olltion  control district ,
H. "Extreme Performance Goat-Ing  means  any  coating used on the surface
    of a Group II vehicle,  mobile  equipment  or  their parts or
    components which during intended use  Is  exposed to any of the
    following conditions:

    (1)  Industrial grade detergents,  cleaners  or abrasive scouring
    (2)  Extreme environmental  conditions .as  determined by the APCO
         during the vehicle's  principal  use.

I.  final jtage Manufacture means  where  an  incomplete vehicle chassis
    is delivered to a manufacturer for  installation and paint of a
    truck body and/or components  to form a  completed vehicle.

J.  Grams of VQC Per Liter of  Coating  less  water  and Less Exempt
    Compounds means the weight  of  VOC  per combined volume of VOC and
    coating solids is calculated  by thVfollowing equation:


       Gvoc     •  («s  -   Ww -   W«s   >' 

    where:

    G     = Grams VOC per liter of coating  less water and exempt
            compounds

      W£  = weight of volatile  compounds in grdms
      ww  = weight of water in -grams
      wes - weight of exempt compounds in grams
      Vm  = volume of material  in  liters
      Vy  = volume of water  in  liters

      VfS-=  volume  of exempt compounds  (as  defined  in VOC definition,
            Section II GG)  in liters

-  Graphic  Design Application  meant the application of  logos,  letters,
   numbers  and graphics to a painted surface, with or without  the  use
   of a  template.

-   Ground Support, means vehicles  used  in support  of aircraft
   activities at airports.
                              -2-

-------
                                                 ;>;>u UKAM  11/7/90
 M.   Groug  I_Vflh.1des nuani pauenger cars, Urgt/heavy duty truck cabs
     and chassis,  light  and medium duty trucks and vans, and
     motorcycles.

 N.   Group  II Vehicles and Equipment; means public transit buses and
     mobile equipment.

 0.   Hioh-Volnmft.  low-Prcssurt fHVLPl Sorav means equipment used to
     apply  coatings by means of a gun which operates between 0.1 and 10
     psig air pressure and which operates at a maximum fluid delivery
     pressure of 50 psig.

 P-   large/Heavy Duty Trucks means any truck having a manufacturer's
     gross vehicle weight rating of over 10,000 pounds.

 Q.   LJoht and Medium Duty Trucks and Va/is means  any truck or van having
     a manufacturer's gross vehicle weight rating of 10,000 pounds or
     less.

 R.   Metallic/Iridescent Topcoat means any coating which contains more
     than 5 g/1 (.042 Ib/gal) of metal or iridescent particles, as
     applied, .where such particles are visible in the dried film.

 S.   Mobile Equipment means any equipment which may be drawn or is
     capable of being driven on a roadway, including, but  not limited
     to, truck bodies, truck trailers, utility bodies, camper shells,
    mobile cranes, bulldozers, street cleaners,  golf carts and
     implements of husbandry.

 T.  Precoat means any coating which is  applied to bare metal primarily
     to deactivate the metal surface for corrosion resistance to a
    subsequent water-base primer.

U.  Pretreatment Wash Primer means any coating which contains  a minimum
    of 0.5 percent acid by weight, is necessary  to provide surface
    etching and is applied directly to  bare metal surfaces to  provide
    corrosion resistance and adhesion.

V.  Primer means any coating applied prior to the application  of a
    topcoat for the purpose of corrosion resistance and adhesion of the
    topcoat.

W.  Primer Sealer means any coating applied prior to the application of
     a topcoat for the purpose of corrosion resistance, adhesion of  the
     topcoat, color uniformity, and to promote the ability of an
     undercoat to resist penetration by the topcoat.

 X.   Primer Surfacer means any coating applied prior to the  application
     of a topcoat for the purpose of corrosion resistance,  adhesion  ot
     the topcoat, and which promotes a uniform surface by  filling  in
     surface  imperfections.


                                -3-
                                 1104

-------
                                                      UKAH 11/7/90
 Y.   RtiULti moans tht solvent  usid  to  thin  en Aim 1.

 2.   Refim'shfng means any coating of vehicles, their parts and
     componentSj or mobile tqulpment, Including partial body collision
     repairs,  for the  purpose of protection or beautlHcation and which
  ..  is. subsequent to  UL^ original coating applied at an Original
     Tqulpment  Manufacturing (OEM) plant coating assembly line.

AA-  Specialty  Coatlngl means coatings which are necessary due to
     unusual job performance requirements.  Said coatings Include, but
     are  not limited to, adhesion promoters, uniform finish blenders,
     elastomerk materials, gloss flatteners, bright metal trim repair,
     and  anti-glare/safety coatings.

BB.  Spot/Panel  Repair means the non-assembly line process of  repairing
     and  restoring  a portion of a motor  vehicle  to predamaged  condition.

CC.  Three-Stage  Coating System means a  topcoat  system composed of a
     pigmented  basecoat portion, a semi-transparent midcoat portion, and
     a transparent  clearcoat portion.  Three-stage coating systems'  VOC
     content shall  be  calculated according to the  following formula:

                      VOCbc * YOCmc  + 2 VOCcc
     YOCT3-stage   '   - - - : - : -
    Where:

    VOC T,  f      is the sum of the VOC content  as  applied In the
         J-stage   basecoat, midcoat and clearcoat system.
    VOtL,    is the VOC content as applied of any  given  midcoat.
       me
    Z VOC     is two times the VOC content as applied of any given
          c   clearcoat.

DO. Topcoat means any coating applied over a primer  of  an original OEM
    finish for the purpose of protection or appearance.  For the
    purposes of this rule, base coat/clear coat systems and three-stage
    coating systems shall be considered jointly as a topcoat.

EE. Touch-uo Coatino means a coating applied by brush or hand  held,
    non-refi liable aerosol cans to repair minor surface damage and
    imperfections.

FF. Transfer Efficiency means the ratio of the 'amount of coating solids
    adhering to the object being coated to the total amount of coating
    solids used in the application process, expressed as a percentage.

GG. Volatile Organic Compounds mean any compound  containing at least
    one atom of carbon, except methane, carbon monoxide, carbon
    dioxide, carbonic acid, metallic carbides or  carbonates, ammonium


                               -4-

-------
                                                      ssi) UKAH  n///yu
          carbonate,  1. 1.1-trichloroethane, methylcne chloride,
                                 ( CFr~i n . (HchlorodlfluoroiTtcthana
          chlorodifluoromEthang  (CFC-221. trlf luoromethane (CFC-23),
          trichloroUifluoroethane(CFC-113),d1chlorotetrafluoroethane  (CFC-
          114),  chloropenUfluororethane  (CFC-115), dichlorotrlf luoroethanft
                                                   dlchlorof luorosthane
          (HCFC-141b).and  chlorodlf luorortthanc  (HCFC-H2M.
 III.  STANDARDS

      A.   Limits.   Effective  six months from the date of adoption except
          where dates  are  specified, any person.who appllts coatings to Group
          I  or  II  vehicles, mobile equipment, their parts and components,
          shall comply with Sections III A (1) or A (2) below:

          (1)   Group I Vehicles.  A person shall not refinlsh Group I
               vehicles, their parts and components, or Group II vehicles and
               mobile  equipment where color match is required, using any
               coating with a VOC content in excess of the following limits,
               expressed as grams of VOC per liter (or pounds per gallon) of
               coating applied, excluding water and exempt compounds (as
               defined in  VOC definition. Section II SS), unless emissions to
               the  atmosphere are controlled to an equivalent level by air
               pollution abatement equipment with an abatement device
               efficiency  of  at least 85 percent and which has been approved
               in writing  by  the Executive Officer.
                           RACT
                            VQC
                                             Januar  1.  1992
                                       •BAftCT-
                                                January 1. 1995
                                                     V_QC
Pretreatment Wash   780 g/1 (6.5 Ibs/gal)  780 g/1  (6.5  IbS/gal)  420 g/1 (3,5 Ibs/gal
     Primer
Precoat
Primer/primer
     Surface
Primer Sealer
Topcoat
Metallic/Iridescent
     Topcoat
780 g/1
720 g/1

720 g/1
720 g/1
720 g/1
(6.5 IbS/gal)
(6.0 Ibs/gal)

(6.0 Ibs/gal)
(6.0 IbS/gal)
(6.0 Ibs/gal)
780 g/1 (6.5 IbS/gal)
340 g/1 (2.8 Ibs/gal)

420 g/1 (3.5 Ibs/gal)
600 g/1 (5.0 Ibs/gal)
600 g/1 (5.0 Ibs/gal)
420 g/1 (3.5 Ibs/gal
250 g/1 (2.1 Ibs/gal

340 g/1 (2.8 Ibs/gal
460 g/1 (3.8 Ibs/gal
540 g/1 (4.5 Ibs/gal
         (2)  Group II Vehicles and Mobile Equipment.   A person shall not
              finish or refinish Group II vehicles and equipment or their
              parts and components where color match is not required, using
              any coating with a VOC content 1n excess of the following
              limits, expressed as grams of VOC per liter (or pounds per
              gallon) of coating applied, excluding water and exempt
              compounds (as defined in VOC definition, Section II GG).
                                    -S-

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              unless emljslonj to the at~osph«re are controlled to an
              equivalent level by «1r pollution abatement  equipment with tn
              abatement device efficiency of at least 85 percent and vhlch
              has byen approved 1n writing by the Executive Officer.
                           RACT
                            VOC
                                       -BARCT-
                                             Januar
                                    199?
                                        January 1. 1995
                              VQC
Pretreatment Wash
     Primer
Precoat
Primer
Topcoat
Metallic/Iridescent
     Topcoat
Extreme performance
Camouflage
780 g/1 ($.5 Ibs/gal)  780 g/1 (6.5 Ibs/gal)  420 g/1 (3.5 Ibs/gal
780 g/1
340 g/1
420 g/1
650 g/1

750 g/1
420 g/1
(6.5 Ibs/gal)
(2.8 Ibs/gal)
(3.5 Ibs/gal)
(5.4 Ibs/ga1)

(6.2 Ibs/gal)
(3.6 Ibs/gal)
780 g/1 (6.5 Ibs/gal)
340 g/1 (2.8 Ibs/gal)
420 g/1 (3.5 Ibs/gal)
420 g/1 (3.5 Ibs/gal)

750 g/1 (6.2 Ibs/gal)
420 g/1 (3.5.Ibs/gal)
420 g/1
250 g/1
340 g/1
420 g/1
3.5 Ibs/gal
2.1 Ibs/gal
2.8 Ibs/gal
3.5 Ibs/gal
420 g/1 (3.5 Ibs/gal
420 g/1 (3.5 Ibs/gal
     B.   Lacouer  Spot/Panel  Repair  Limits.   Effective six months from  the
         date  of  adoption,  a person shall not  spot/panel repair Group  I
         vehicles with existing  nitrocellulose or synthetic  lacquer  finishes
         using lacquer coatings  in  excess of the following limits, expressed
         as  grams of  VOC  per liter  (or  pounds  per gallon) of coating
         applied, excluding  water and exempt compounds (as defined in  VOC
         definition,  Section II  GG), unless  emissions to the atmosphere  are
         controlled to an equivalent level by  air pollution abatement
         equipment with an abatement device  efficiency at least 85 percent
         and which has been  approved in writing by the Executive Officer:
          Pretreatment Wash Primer
          Precoat
          Primer/Primer Surfacer
          Primer Sealer
          Topcoat
                                  VOC

                         780  g/1  (6.5
                         780  g/1  (6.5
                             Ibs/gal)
                             Ibs/gal)
                         720  g/1  (6.0  Ibs/gal)
                         780  g/1  (6,5  Ibs/gal)
                         780  g/1  (6.5  Ibs/gal)
    Effective twelve months from the date of adoption, a person shall  not
    spot/panel repair Group I vehicles with existing lacquer finishes  using
    any coating with a VOC content  in excess of the standards set forth  in
    Section III A  (1).

    C.  Transfer Efficiency.  Effective twelve months from  the date  of
        adoption for all  coatings,  a person shall not apply any coating  to
        any Group  I or II vehicles  or mobile equipment or their parts  and
        components unless one of the following methods is used:
                                   -6-

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                                                 SSO DRAFT 11/7/90
    (1)  Electrostatic application equipment, operated 1n accordance
         with the manufacturer's recommendations;

    (2)  High Volume Low Pressure (HVLP) spray equipment, operated 1n
         accordance with the manufacturer's recommendations;

    (3)  Any other coating application which has been demonstrated to
         the satisfaction of the Executive Officer and for which
         written approval of the Executive Officer  has been obtained.

D.  Prohibition of Soedf ication.  Ho person shall solicit or require
    for use or specify the application of a coating on a Group I or II
    vehicle, mobile equipment, or part or component thereof if such use
    or application results in a violation of the provisions of this
    determination.  The prohibition of this Section will apply to all
    written or oral contracts under the terms of which any coating
    which is subject to the provisions of this determination is to be
    applied to any motor vehicle, mobile equipment, or part or
    component at any physical location within the District.

E.  Prohibition of Sale.  A person shall, not offer for sale or sell
    within the District any coating if such product is prohibited by
    any of the provisions of this determination.  The prohibition of
    this section shall apply to the sale of any coating which will be
    applied at any physical location within the jurisdiction of th.<^
    .local air Pollution control agencies. _ This requirement shall not
    apply to the application of coatings where emissions to thg
    .atmosphere are controlled to an equivalent level  of this
    determination bv air pollution abatement equipment that has
    approved in writing bv the Executivg
    Compliance Statement Requirement.   The manufacturer  of  coatings
    subject to this determination  shall  include. a designation of  VOC
    {as defined in Sections  II  G6)  as  supplied, including coating
    components, expressed In grams  per  liter or pounds per  gallon,
    excluding water and exempt  compounds, on data sheets.

    Surface Preparatlon-'and  Clean-up Solvept.  The requirements of this
    section shall  apply to any  person  using solvent for  surface
    preparation and cleanup.

    (1)  A person  shall not  use an  organic compound for  surface
         preparation with a  VOC content  in excess of  200 grams per
         liter (1.67 pounds  per gallon).
    (2)  A person  shall use  closed, nonabsorbent containers for the
         storage or disposal  of cloth  or paper used for  solvent surface
         preparation and cleanup.
    (3)  A person  shall store fresh or  spent solvent  in  closed
         containers.
    (4)  A person  shall not  use organic compounds for the cleanup of
         spray equipment including paint  lines unless an enclosed
         system is used for  cleanup.   The  system must enclose  spray

                               -7-
                                  1

-------
              guns, cups, nozzles, bowli and other parts during vathlng,
              rinsing and draining procedures.  Equipment used shall
              mlnlmiie the evaporation of organic compounds to the
              atmosphere.

     H.  SfflaJ 1 product 1on7Ut 11 Hy Bodies.  The standards set forth In
         Section |II A (1) Shall apply provided production of utility bodies
         where the coating Is required to match that of the vihiclts upon
         which they will be mounted It less than or tqual to 20 vehicles per
         day.  T(\estandards set forth jn Section III A (2) shall apply
         provided production of utility bodies Is greater than 20 vehicles
         par day.

     I.  Specialty Coating* means a person shall not use any specialty
         coating with a VOC content in excess of 840 g/1 (7.0 Ibs/gal),
         excluding vater and exempt compounds.   Use of all specialty
         coatings except antiglare/safety coatings shall not exceed 5.0
         percent of all coatings applied, on a daily basis.  The application
         of topcoats with a specialty coating used as an additive shall be
         subject to the topcoat limits 1n Sections III A (1) or A (2).

     J:'Extreme Performance Coating Requirements means any person seeking
         to use an extreme performance coating in any coatirvg operation
         which is subject to this rule shall comply with the requirements of
         Section VI A.
IV.  EXEMPTIONS

     A.  Original Eoujpment Manufacturer.  The provisions of this Rule shall
         not apply to Original Equipment Manufacturer (OEM) coatings applied
         at manufacturing or assembly plants subject to a Motor Vehicle
         Assembly Plan Rule.
V.   TEST METHODS

     A.  Analysis of Samples.  Samples of volatile organic compounds as
         specified in Sections III A (1) or III A (2) shall be analyzed as
         prescribed by EPA Reference Method 24 or method determined to be
         equivalent and approved by the Executive Officer.

     B.  Determination of Emissions.  Emissions of volatile organic
         compounds as specified in Section III A (1) or III A (2) shall be
         measured as prescribed by EPA Reference-Method 25 or method
         determined to be equivalent or more stringent and approved by the
         Executive Officer.

     C.  nomination of Transfer Efficiency-  Transfer «"jciency as
         required by Section III C (3) shall be determined by a method
         approved by the Executive Officer.


                                    -8-

-------
     D-   Determination of Capture Efficltncy.  Capture efficiency  »s
          r»guir>Qy_Sect ion  III A and R shall bn determined bv the method
          itattd  in suboart  SSS  (Magnetic Tape Coating Facilities!  40  Cfp r
          Part  60. Section 60.713.

     E.   Determination of Iridasceryt particles in Hetanic/Iridtsctnt
      ,  -Topcoat.  IMdtscent particles 1n metallic/Iridescent topcoat as
          defined  In Section II  R shall be determined bv the South  Coast A,1r
          Ouallty  Management District (SCAQMO) Spectrograohic method
          contained in Section 3. Method ?6 of the SCAQHD "Laboratory M»fh,ffd
          of Analysis for Enforcement Samples* manual.

     F.   Determination of Acid  Concentration 1n Prstreatment Wash  Primer.
          Acfd,  concentration in  pratreatment wash primer as defined 1n
          Section  II U shall be  determined bv test method ASTM D-1613-85
          /modified).
VI.  ADMINISTRATIVE REQUIREMENTS

     A.  Extreme Performance Coating Petition.   Any person seeking to use an
         extreme performance coating 1n any coating operation which is
         subject to the provisions of this rule shall  comply with the
         following requirements:

         (1)  A petition shall be submitted to  the  Executive Officer stating
              the performance requirements, volume  of  coating and VOC level
              which is attainable.
         (2)  If the Executive Officer  grants written  approval,  such
              petition will be repeated on an annual basis.
         (3)  If the Executive Officer  grants written  approval,  such
              approval shall contain volume and  YOC  limit  conditions.
         (4)  Records  must be maintained as in  Section VI  (B).

     B-   Coating Records.   Any person subject to Sections  III A  (1) and III
         A (2) shall  comply with the following  requirements:

         (1)  The person shall  maintain and have available during an
              inspection,  a current  list of coatings in use  which provides
              all of  the coating data necessary  to  evaluate  compliance,
              including the following information,  as  applicable:

              (a)  coating, catalyst and reducer used
              (b)  mix ratio of components used
              (c)  VOC content  of coating as applied.

         (2)  The person shall  maintain records  on  a daily basis Including
              the following information:

              (a)  coating and  mix ratio of components in  the coating used
              (b)  quantity of  each  coating applied.


                                    -9-
                                            n
                                           . * V

-------
(3)  The pfcMc.fi jotll maintain records on o monthly b«»U ihoving
     ths typ« «n3 imouht of jotWr.t us«d for cleanup ihd «urf»c«
(4)  Such record* shall be rttained and avallablt for Inspection by
     the ExecutlVt Officer for tht pr»v'1ous 24 month pirlbd.
                           -10-

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                                PaintShop
          Common  Complaints,
                Specific   Solutions
                                  by Mark Clark
        n these days of fast-paced
        produce'deliver auto repaint-
        ing, it's hardj-o get a simple
 explanatioh'for the cause of common
 painters' problems. In this series of ar-
 ticles, we are going look at some of the
 most common complaints and try to
 explain in simple terms (no degree in
 chemisty required) what went wrong
 and why. These discussions are as ge-
 neric as possible, and no one brand of
 paint is being promoted over another.
  And that leads us to the absolute
 quickest way to reduce all your paint
 problems, no matter what brand you're
 using or what part of the country you're in.
  You can reduce your painting related problems by —
 ready?  — 50 percent. Sound like something you'd be
 interested in? Instead of 10 problems a week or 10
 problems a month, you can skip right down to only 5
 problems.
  How? It's easy, it's simple, and it's guaranteed to
 work. Use one brand all the way through, follow a sys-
 tem! When all the undercoats, solvents, topcoats and
 clears are guaranteed compatible, you'll have 50 per-
 cent fewer problems. Problems like adhesion, durabili-
 ty and re-coatability drop to the very minimum.
  The notion that any shop painter can don the chem-
 ical engineer's  hat and start mixing products and
 systems goes back to the days when this business was
 much simpler.
  Back in the days when most undercoats were a lac-
 quer base and most topcoats were either lacquer or a
 simple acrylic enamel, shop painters figured out that
 they could substitute a cheaper solvent from some oth-
 er manufacturer and then color with yet a third brand
 and seldom have problems.
             Like the paint reps say, one of the
            hardest guys to deal with is the paint-
           .er who combined several brands and
            didn't have a problem, once or twice or
            even ten times. Then, when his ''sys-
            tem" doesn't work, he can't accept the
            fact that he was just lucky each of
            those other times.
             The reason that intermixing is such
            a tremendous risk these days can be
            traced back to the vehicle manufactur-
            er. The consumer keeps demanding a
            better looking, more durable, more
            corrosion-resistant finish. The manu-
            facturers have been able to deliver
OEM finishes hundreds of times better than just a few-
years ago. Now here comes that super high-tech finish
into the body shop to be repaired "as good as new."
  The af termarket paint companies have really had to
scramble to create air dry (no heat or electricity like
OEM) finishes durable enough to match original
equipment. This, as you might imagine, was quite a
trick.
  What this means to body shop painters is that there
is no margin for error in applying or mixing today's
products. The  paint company chemist was able to
create a product to suit, but only if you do exactly as
he says. Not only must the painter combine the correct
solvent, catalyst and topcoat in the correct percent-
ages, but it must be applied over the correctly mixed
and appb'ed undercoats at the correct time.
  There is only one right way to use today's finishes;
exactly according to directions and using only one
brand. Besides reducing your paint problems 50 per-
cent, several other benefits also occur.  You will have
fewer products (read that — dollars) in your inventory,
                        (continued on pg. 82)
80 / June 1990 /  BodyShop Business

-------
 (continue*: jnim pg. SOI
 and since ihe same system is used all the time, every-
 one gets {.rood at it and more work is produced in less
 time. Knowing what one line will do under a variety
 of conditions is better than guessing what a vari-
 ety of products will do under the same condition.
   Now. having solved one half of your paint problems.
 let's take a look at some of the other ones that are left.
        It's simple to solve
  half  your  paint  problems.

   One of the most common and frustrating paint prob-
 lems is die-back. Die-back means that over time the
 paint job loses the gloss it once had. Only one thing
 causes die-back: trapped solvent. It is always at the
 root of any die-back. Well that was simple, right?
   The mystery comes up when you try to decide where
 the solvent was trapped. It could be in the primer, the
 primer-surfacer. the sealer, the color coats or the clear-
 coats. Choose one or two or more! All your paint pro-
 ducts have solvent in them, some you  add more sol-
 vent to. If you rushed the flash off time on any of the
 products, (who. you?) there is still solvent that wants
 to escape into the air. When it does, it has the same
 effect on the finish as wiping the car with a solvent-
 soaked rag.
   Maybe the most  common die^back occurs when a
 complete paint job is shot late in the day because the
 dust in the shop is at a minimum.
   The painter is the last guy in the shop and after the
 third coat, cleans his equipment, shuts off the fan and
 the light and heads home. When he returns the next
 morning, his great looking, super glossy paint job has
 died back and dulled down.
   What happened was that the bulk of the solvent rose
 up out of the paint film into the air where it should
 have been swept  away by the air movement created
 by the fan. With no  fan running, -(to  keep the job
 cleaner he thought) the solvent rose to the top of the
 paint film and just lay there — thus, die-back.
  The solution is to run the fan for a good 45 - 60
 minutes after the last coat. At the end of the hour, shut
 off the fan and open the booth doors. You're out of
 dust by then, and the air moving in the open doors
 will help the last  of the  solvent to evaporate off.
  Air movement pla vs a big role in die-back. Take this
 example: You're  painting a car in a  two-stall ga-
 rage with little or no air movement. The tempera-
 ture is 70 F  All  you need is  the correct  solvent
 for  70 F  and the correct .flash time between coats.
   Now. the same car. the same 70  F, but you're
 in a crossdraft spray booth with average air move-
 ment. You need to choose a solvent as if  it were
 10° warmer (80 F) because of the air's drying effect.
   Third time, same car. same 70 F, but in a downdraf t
-booth with lots of air movement. You now need a
 much slower drying solvent; in fact, almost 20°
 warmer. You must reduce as if it were 90 F in the
 booth. All that air whistling past causes the  surface
 of the paint film to skin over before all the solvent can
 evaporate out. That trapped solvent will eventually
 work its way out, causing extra work for you, and
-distress for your customer. Beat this problem by
 choosing the correct solvent for each of your under-
 coats and topcoats.  Equally important,  wait the
 recommended flash time (or more) between coats.
   Another common problem, solvent popping, is caus-
 ed by exactly the same trapped  solvent that causes
 die-back. Only in this case, there is so much solvent
 trapped under the prematurely dried  "skin" that it
 will literally burst out of the paint film, leaving k'ttle
 craters with a hole on top.
   Solvent popping is violent die-back. The solution is
 to immediately move to a slower drying solvent.
   When you must re-do something because of die-back
or solvent popping, sand the finish as soon as you can
and let it sit around the shop, sanded, for as long as
possible. When you sand, you open up the paint  film,
giving the solvent a hole to escape through.
  Another common problem is clearcoat de-lam-
inating (peeling) off the color coat. There are two
likely causes. How soon the customer comes back
gives you a good clue as to which one you've got.
  If the customer is back within 8 -10 weeks, it is most
likely a compatibility problem. In other words, the
clearcoat  never had  an intercoat bond with the
basecoat and was just ''sitting"  on the base  color.
  There are two kinds of adhesion: mechanical and
chemical. Mechanical means that you have abraded
(sanded) the surface to increase the area of contact
with the next product (i.e., up one side of the sand-
scratch and down the other means more surface area
to meet the new coat). Chemical adhesion depends on
putting a chemically compatible product over anoth-
er in the correct time frame. You may have the cor-
rect product, but let your base color dry too long and
the clear can get no bite into it.
  If it has been longer than 8 to 10 weeks before the
customer is back with peeling, chances are the clear-
coat wasn't applied thick enough.
  The main enemy of your paint finish is the ultra
violet rays of the sun. It's hard to put very many UV
                          (continued on ptf. 10-r>)
82 / June 1990  / BodyShop Business

-------
 (continued from pg. 821
 scrocncrs in n clcarcoat because (.hen it. isn t clear any-
 more. Some of your clearcont's durability depends on
 having a thick enough film to withstand the UV.
   What happens many times is that the clearcoat was
 applied at an acceptable mil build but was later wet
 sanded and buffed to get rid of dirt.
   If, for example, you had two mils of clear in two
 coats, you'll take one mi] off when you sand and polish. -
 The one mil you have left will not stand up very long
 to the sun. Now the U V rays come streaming through
 the clearcoat and oxidize the base color. The sun's rays
 destroy the binder in the color coat, leaving only the
 chalky pigment to which the clear won't stick, and off
 it comes! The solution is to put on more clear.
   If you know you're going to buff, add an extra coat
 for the buffer to remove. This will leave enough clear
 film behind to hold out against the sun. Don't worry
 about getting your film so thick that it will crack, to-
                day's urethane enamel clears remain flexible up to a
                build of 20 mils or more. There is not, however, much
                to be gained in gloss by going past three to four coais.
                  Next time we'll look into the most common lifting
                problem, discuss a clever solution for blushing and
                examine some clues to where your fisheyes might be
                coming from. •
                   BodyShop Business is starting a question'and
                 answer forum for your painting questions. If you
                 have something that you 've always wanted to know
                 and can't seem to find an answer for, send us the
                 question. We can not answer questions about
                 specific brand-name products — address those to
                 your paint rep or jobber. Ask us the "how come"
                 kind of questions.  Using a panel of experts, we'll
                 answer in print the best questions. Thanks for your
                 interest.1
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                                                            BodyShop Business / June 1990 / 105

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                      A.  EPA PRESENTATION

     Mr.  Randy McDonald of the Chemicals and Petroleum Branch in
the Emission Standards Division presented the status of the Batch
Processes Control Techniques Guidelines (CTG).  The presentation
was followed by two additional related presentations:  one from
Mr. Rick Hamilton, of On-Demand Environmental Systems, and one
from Ms.  Terri Ranganath,  of E.  I.  du Pont de Nemours & Co.,
Inc., representing the Chemical Manufacturers Association (CMA).
These presentations are summarized below.  Handouts and slides
are attached.  Also included is a summary of the discussion that
took place between the NAPCTAC committee members and the Batch
project team after the three presentations were completed.

1.  Status of Batch Processes CTG

     The objectives of the presentation were to present the
approach taken to develop reasonably available control technology
(RACT) options for controlling volatile organic compounds (VOC)
emissions from batch processes;  to present the options and the
impacts of applying the options to batch processing VOC emissions
on a nationwide basis; and to highlight implementation issues
that still need to be addressed.  The discussion started out with
a characterization of batch processes—namely, that they are
non steady-state processes.   As an example, the emission events
from a batch reactor—such as vessel charging, reactor heatup,
occasional purging of the reactor vapor space, and product
discharge—were described and the characteristics of the
resulting emission stream were said to be continuously changing.
Mr. McDonald pointed out that the scope of the CTG is limited to
five industries, and the CTG contains RACT options for
controlling process vents and equipment leaks.  Wastewater and
storage emissions are addressed in separate CTG's.  Equipment
leak requirements were adopted from the requirements set forth
for emissions from batch processes in the equipment leaks
negotiated regulation.  Mr.  McDonald explained that process vents
were, therefore, the focus for the majority of work done to
develop this CTG.  The focus of the presentation then turned
towards explaining the approach taken to develop the options.  It
is summarized below.

     Four model processes were developed from industry data.
They included typical batch unit operations and associated
equipment such as reactors,  crystallizers, centrifuges, dryers,
and distillation units.   In calculating emissions and estimating
the emission stream characteristics of flowrate, duration, and

-------
VOC concentration, the assumption was made that primary
condensers servicing this equipment were operated at 20"C.  Also,
all pieces of equipment were assumed to be vented.

     Next, Mr. McDonald discussed the time-dependent variation
that can occur in flowrate and VOC concentration, and
subsequently in the resulting emissions.  This concept was
presented using slides that plotted concentration, flowrate, and
emission rate on the y axis and duration of the batch cycle on
the x axis.  Control device selection must account for such
variation and control VOC emissions that are most reasonable to
control.  Two types of control devices were used to examine the
limits of reasonable control for VOC emissions from batch
processes.  They are thermal incineration and refrigeration.
These devices were used exclusively because they can handle a
universe of compounds.  Refrigeration was used for rich VOC
streams (>10,000 parts per million by volume [ppmv]), and thermal
incineration for streams with lower VOC concentrations.  Costing
of the devices was done in accordance with the OAQPS Control Cost
Manual.  An illustration of the dependency of control device cost
effectiveness with the amount of onstream emission duration was
shown by plotting cost effectiveness versus flow rate for a
number of 10,000 ppmv streams having varying onstream
percentages.  This discussion led to the heart of the approach
for developing RACT options, which is outlined below.

     A "mass flux" curve was shown and discussed in detail by
Mr. McDonald.  The mass flux curve is a plot of control device
cost effectiveness (dollars per Megagram [$/Mg]) versus maximum
instantaneous flowrate (standard cubic feet per minute [scfm])
for a set annual emission rate (termed "mass flux") for a range
of concentrations varying from 100 ppmv to 100,000 ppmv-  The
curves form an envelope that describes the range of cost
effectiveness values that are possible using the two control
devices specified above for any flowrate.  The left-hand
endpoints of the mass flux curve represent continuous emission
streams.  They are the lowest maximum instantaneous flowrates
that a vent stream can have for a set concentration to emit the
specified mass flux, which, for the first curve, was
20,000 Ib/yr.  As the curves move from left to right, the
duration of the emission streams becomes shorter and shorter so
that the right hand endpoints of the curve approximate very short
"bursts" containing high flowrates.

     A control device sized to handle emissions streams described
by the right-hand endpoints would be less cost effective (i.e.,
more expensive) than one sized to handle a stream described by
left-hand endpoints because the device would be large enough to
handle the burst but would not operate as long for the same mass
flux value (i.e., the Mg in $/Mg would remain the same, but the $
would be higher).  By drawing a horizontal line at a desired cost
effectiveness, intersecting the envelope formed by the mass flux
curves, and drawing a vertical tie-line down, the limit of


                             1116

-------
maximum instantaneous flowrate for a given cost effectiveness can
be set.  The RACT options were developed based on this analysis
and take the form of a regression line linking mass flux  (or
annual emission rate) and maximum instantaneous flowrate  at
certain cost effectiveness values.  A process vent would
therefore require control to a desired level (the current options
are 90, 95, and 98 percent reduction) if the maximum flowrate
were less than the value obtained from the equation of the
regression line for a specified annual emission rate.  This is
the approach that was taken to evaluate the limits of RACT for
process vents.

     For equipment leaks, Mr. McDonald reiterated that the RACT
option followed the requirements contained in the section
specific to batch processing contained in the equipment leaks
negotiated regulation.

     Mr. McDonald then presented the RACT options and their
associated nationwide impacts.  To estimate these impacts, model
plants were developed from the model processes presented earlier.
The number of facilities represented by these model plants
located in nonattainment areas having batch VOC emissions from
the industries in the scope of the CTG were estimated using data
from the Census of Manufacturers.  Selected RACT options were
shown  on a table with their estimated national emissions
reduction and costs.

     Finally, Mr. McDonald presented a slide of some of the
implementation issues that have arisen since the approach was
developed.  The first of these issues is how to obtain the annual
emission rate for a process vent or group of process vents.
Current thinking is that source testing is not technically and
economically feasible.  The Batch CTG document contains
methodologies for estimating VOC emissions from batch processing
steps.  These methodologies could be used to develop the annual
emissions estimate.  Maximum instantaneous flowrate is presumably
an easier parameter to obtain for various reasons.

     The second implementation issue discussed is how to verify
the annual emission rate.  Because of the format of the RACT
options, facilities will be required to anticipate the annual
emission rate from a process vent or group of process vents to
determine whether the vent must be controlled.  For industries
that have continuously changing production schemes, this task
could become very complicated.  The agency responsible for
enforcing RACT might require an end-of-the-year audit to ensure
that process vents or groups of process vents were controlled as
required.   Finally, testing or monitoring of control device
operating parameters might be required to ensure that the
required control efficiencies (i.e., 90, 95, and 98 percent) were
being achieved.
                              1117

-------
CONTROL TECHNIQUES GUIDELINES
         DOCUMENT
           (CTG)

            for

       VOC EMISSIONS
           from
      BATCH PROCESSES
      NAPCTAC Meeting

      November 21,1991

-------
Batch Processes are discontinuous processes
in which mass, temperature, concentration
and other properties of a system vary with time,
Batch Processes are typically characterized
as "non-steady state"

-------
     INDUSTRIES COVERED
       Polymers and resins
        Pharmaceuticals
     Paints and allied products
Synthetic organic chemicals (SOCMI)
      Agricultural chemicals

-------
         APPLICABILITY OF BATCH CTG
to
- Process vents
- Equipment leaks
- Storage tanks
- Wastewater
                          Covered by this CTG
                           Covered by other
                               CTGs

-------
   PROCESS VENTS
to
to

-------
ro
CO
                  MODEL PROCESSES
OBJECTIVE: To characterize the majority of batch processes
SOLUTION: 4 model processes
1. Solvent reaction with atmospheric dryer
2. Solvent reaction with vacuum dryer
3. Liquid reaction
4. Formulation

-------
                                       SOLVENT
             SOLVENT
             RECOVERY
Mode! batch process for solvent reaction w/ atmospheric dryer
                        1124

-------
                    CRYSTALLIZER
                      SLURRY
                      TANK
          CENTRIFUGE
          Lr
             DIST.
             UNIT
                                       SOLVENT
CENTRIFUGE
           SOLVENT
           RECOVERY
                               VACUUM
                                DRYER
Model batch process for solvent reaction w/ vacuum dryer
                       1125

-------
  WEIGH
  TANK
WEIGH
TANK
            MIX
           TANK
            1     f
         REACTOR
               •SOLVENT
           SURGE
           TANK
            DIST.
            UNIT
          SOLVENT
         RECOVERY
Model batch process for liquid reaction
              1126

-------
WEIGH
TANK
WEIGH
TANK
         MIX
         TANK
       REACTOR
        SURGE
         TANK
                                 SOLVENT
                   FILTER
       Model batch process for formulation
                   1127

-------
   CONCENTRATION, FLOWRATE, and DURATION
               determine
ro
oo
               EMISSIONS

-------
CONCENTRATION PROFILE OF A BATCH PROCESS
   90

   81

   72
O
tr 63
Ld
   54

   45
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18

 9

 0
  Ohr
          N

          Reactor
                                      Distillation
                                       r
                         Vacuum
                           dryer
                                             Solvent
                                            Recovery
                         2.2 hr

                   TIME (24  HOURS)
                                      22.2 hr
24 hr

-------
        FLOWRATE PROFILE OF A BATCH PROCESS
o
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   154 r
   132
E  110
   88
<   66

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    0
             Reactor
      Ohr
                          X
    Vacuum dryer
2.2hr
                                    N
                     TIME (24 HOURS)
                 Distillation
22.2hr
24 hr

-------
       EMISSION PROFILE OF A BATCH PROCESS
  16 r
 CO
< 8
cr
g
00
in

^
LU
   0
             Reactor
         /
     Ohr
                                               Distillation
                                   Vacuum dryer
                           Solvent

                          recovery
2.2hr
                                              22.2hr    24 hr
                      TIME (24 hours)

-------
FLOWRATE PROFILE OF A BATCH PROCESS
154
132
^ 88
1 1 1
1 66
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b-
22
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//
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2.2 hr N| 22.2 hr 24 hr
TIME (24 HOURS)
 CONCENTRATION PROFILE OF A BATCH PROCESS
   90
h-  B1
^  72
^  63
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Q-  54
LU
S  45
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=*  36
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 9
 0
         Reactor
                                   Distillation
                                          Solvent
                                          Recovery
                    2.2 hr     N|
               TIME (24 HOURS)
    EMISSION PROFILE OF A BATCH PROCESS
   16 r

 .c
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 a:
 O
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         Reactor
          n
   nnrT

                                      OiitiUation
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                                             Solvent
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                         2.2 hr       \
                   TIME (24 hours)
                                      22.2 hr    24hr
                       1132

-------
CO
CO
              CONTROL TECHNOLOGY
- Thermal incineration
    (< 10,000 ppmv)

- Condensation/refrigeration
   (>=10,000 ppmv)
     Other devices were examined (i.e. scrubbers and
      carbon adsorption),but these two are UNIVERSAL

-------
CO
        PACT OPTIONS STRUCTURED TO
          CONSIDER VARIATIONS IN:
- Concentration
- Flowrate
- Duration

-------
               Cost to Control by Thermal Incineration
                   For VOC Concentration of 1 0,000 ppmv
CO

  50000
  45000
  40000
  35000
  30000
  25000
P 20000
  15000
  10000
   5000
      0
     O
                 20% 1 0%
                                          7,
            10          100        1000       10000       100000
                 Maximum Instantaneous Flowrate (scfm)

-------
CO
cn
       FORMAT OF OPTIONS

- Linear equations which specify flowrate

 "cutoffs" when annual emission rate is input

- Emission streams must be controlled to a
 certain level (i.e. 98%, 95%, 90%) if the

 maximum flowrate of the emission stream

 is less than the specified cutoff

-------
    APPROACH FOR DEVELOPING RACT OPTIONS
    - Absorb duration into "mass flux" parameter, which
     is the yearly VOC emission rate

£   - Construct "mass flux" curves on axes of cost
S    effectiveness and flowrate for range of concentration

-------
CO
CO
     D)
    CO
    CO
    LLJ

    LU
O
LU
    LL
    LLJ
    8
                          MASS FLUX = 20000 Ibs/yr
                             LOW VOLATILITY Obluene)
                            CONDENSER CONTROL EFFICIENCY - 90%
                                             Short duration events
                   100% duration, 8760 hours
                  Condenser 100,000 ppmv
                                           100
                                   FLOWRATE(scfm)
                                                     1000
10000

-------
       35
C/)
0)
LU
       30-
       25-
LU  "p  20
>  §

P  R
O  .8  15J
       10-
        5-
LL
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8
        0
                          MASS FLUX = 35000 Ibs/yr
                            LOW VOLATILITY fToluene^
                           CONDENSER CONTROL EFFICIENCY - 90%
                         10              100             1000

                                 FLOWRATE(scfm)
                                                                         10000
     	THROX 10OOppmv    	THROX 8750ppmv
                                        	 CONDENSER 10000ppmv	CONDENSERIOOOOOppmv

-------
        35
  CO
  CO
  LJU
        30-
  25-
  UJ -p 20-
 •^  i
OUL
  LJL
  LU    10
   5-
  o
  o
         0-
                           MASS FLUX = 50000 Ibs/yr
                             LOW VOLATILITY fToluene)
                            CONDENSER CONTROL EFFICIENCY - 90%
                                                            (50,000,4000)
                          i  i  i  i i i 111
                    10              100            1000

                            FLOWRATE(scfm)
                                                                         10000
	THROX 10OOppmv    	THROX 8750ppmv
                                            CONDENSER lOOOOppmv 	CXDNDENSERIOOOOOppmv

-------
MASS FLUX = 75000 Ibs/yr
  LOW VOLATILITY (Toluene)
 CONDENSER CONTROL EFFICIENCY » 90%
               100             1000

       FLOWRATE(scfm)
                                                                   10000
	THROX 10OOppmv    	THROX 8750ppmv
                 CONDENSER 10000ppmv 	CONDENSER 100000ppmv

-------
to
                       DATA POINTS
   Mass Flux (Ib/yr)      Flowrate (scfm)    Cost-effectiveness ($/Mg)
20,000
35,000
50,000
75,000
500
2500
4000
7000
10,000
10,000
10,000
10,000
               Flowrate = 0.1167(Mass Flux) -1750

-------
 ,
CO
                     EQUIPMENT LEAKS
      - Adopted equipment leaks negotiated regulation as described
       in the Hazardous Organic NESHAP (HON)

      Portions specific to Batch Processing consider
M     - Exemption from control of sources in service
       less than 300 hr/yr

      • Control via pressure testing or leak detection and repair (LDAR)

-------
              NATIONWIDE IMPACTS

Extrapolated from model processes to model plants to nationwide
totals
Uses census of manufacturers data to estimate facilities located
in non-attainment areas for small, medium, and large groupings

Small plant                  1-19 employees,
                           3 model processes
Medium plant                20-99 employees,
                           10 model processes
Large plant                  >=1 oo employees,
                           30 model processes

-------
BATCH PROCESSES CTG RACT OPTIONS
  OPTION

     1
     DESCRIPTION
      OF OPTION

Controlling equipment leaks
NATIONWIDE
 EMISSION
REDUCTION
   (Mg/yr)

    6,900
NATIONAL
   COST
    ($)

$13,000,000
   AVERAGE
     COST
EFFECTIVENESS
     ($/Mg)

     $1,900
                    90% control of aggregated
                 process vents that are not exempt
               per cutoffs based on the $5K envelope

                     90% control of individual
                 process vents that are not exempt
               per cutoffs based on the $5K envelope

                     98% control of individual
                 process vents that are not exempt
               per cutoffs based on the $5K envelope
                                    53,400
                                    39,400
                                    41,000
 Options 2-4 include controlling equipment leaks to the level found in Option 1
 Options 2-4 do not include controlling the paints and allied products industry
                 $94,500,000
                 $95,000,000
                $363,000,000
                   $1,800
                   $2,400
                   $9,000

-------
CD
        IMPLEMENTATION ISSUES

- Estimating and/or testing to obtain annual VOC
 emission rate (Mass Flux, Ib/yr) and maximum
 instantaneous flowrate (scfm)

- Recordkeeping of process equipment usage,
 coupled with end-of-the-year audit

- Recordkeeping of control device operating
 parameters to ensure compliance with control
 requirements

-------
B.   INDUSTRY PRESENTATIONS
         1147

-------
          Batch Processes Control Techniques Guidelines

                       Richard E. Hamilton
                          Vice President
              On-Demand Environmental Systems, Inc.
                        505 Asbury Street
                        San Jose,  CA 95110

VOC REMOVAL

Thermal processors  offer significant benefits  for VOC abatement
control for a variety of industries. If a centrally located thermal
processing unit  is  used for VOC removal, then  all point sources
that emit VOCs may be ducted together and run to the processor. For
a broad range of applications it's understood that not all of the
facility's   emission  point   sources   will  be   emitting  VOCs
continuously  or  at  the  same  time.  For example,  Figure I shows an
emission cycle of VOCs  coming from a semiconductor manufacturing
process.  Even though the air  flow is  continuous,  VOCs  in the
exhaust stream occur only when  chemicals are being  used  in the
processing steps. For this application,  VOCs are in exhaust stream
an average of 18 percent of the time during the two shift per day
operation and range from 30 to 10 percent. Evaluated over a 24 hour
period, the  emissions average less than  10  percent  of the total
day.

If there are  continuous  VOC  emissions,  central  processors may be
attractive  from the stand  point  of  operating  cost. Figure  2
represents   a  centrally  installed  thermal  processor   for  a
semiconductor manufacturing operation which as we have studied does
not have continuous VOC  emissions.  Using several  smaller thermal
processors within  each  local  manufacturing area may be  a  more
practical approach because each can operate more efficiently under
specific conditions and may be inactive when not needed. Figure 3
shows  the  same point sources benefitting from  locally installed
thermal processors that  can respond to the emission cycle from the
processing equipment.

Effluent from individual pieces of processing equipment, or small
groups of equipment, may be directed to  small VOC  processors. If a
fuel-on-demand type processor is controlled by a VOC sensor and a
microcomputer, it will activate only when needed and consume fuel
only when the attached processing equipment is contributing VOCs to
the air stream.  This will also lower the cost of VOC destruction
since fuel consumption of thermal processors depends on the volume
of air that passes through them.

FUEL-ON-DEMAND THERMAL PROCESSING SYSTEMS

Microprocessor equipped, fuel-on-demand, thermal processing systems
may be activated to correspond to VOC  emission  requirements.  An
activation signal can be generated by an  electric signal indicating
that there are chemicals  in  the  exhaust or  by sensors located in
equipment  exhaust  ducts.  For  example  both  a  heated  surface

                                 1148

-------
semiconductor device  and a gas chromatograph  on a silicon wafer
have been  used  to detect total hydrocarbon levels or individual
solvents in the exhaust. Different combinations  of sensors can be
used to keep the thermal processors active until  VOC levels in the
air stream decay to an acceptable level.

A  fuel-on-demand thermal processor must achieve high destruction
efficiency immediately upon activation.  Some advantages of reduced
fuel consumption  are lost  if appreciable  stabilization time is
required. Small thermal processors can inject fuel  into the stream
containing VOCs. When the mixture reaches its lower flammability
limit, it can be ignited. Proper injection and uniform mixing with
the air  stream  prior to ignition will  prevent channeling of the
VOCs  through the  flame area.  This  is  important  because,  in
instances where such channels actually form,  VOCs may pass through
a  reactor without coming into contact with the  flame. Direct flame
contact is necessary since it enables high destruction efficiencies
with short residence time.  Figure 4 is  a cross  section  of the
reactor  used in  the On-Demand  Environmental  System's thermal
processor which is designed to ensure direct flame contact with the
VOCs in the air stream.

In addition to VOC destruction efficiency, NOx generation is also
an important  consideration.  Consequently,  a  responsive thermal
processor that operates only when  required will reduce the overall
amount of NOx produced,  compared  to systems that maintain a high
temperature on  a  continuous basis.  For  fuel-on-demand thermal
processors, it has been  demonstrated that reactor design affects
the levels of NOx produced during the operation. Levels below lOppm
of NOx  during operation have been  measured  from the  On-Demand
technology shown in Figure 4.

COMPUTER CONTROL

A  personal computer with interface hardware can cost-effectively
operate the thermal processor if the processors are equipped with
variable fuel  flow hardware.  Computer software can  incorporate
selected algorithms to optimize specific applications.  As the VOC
concentrations change, the  computer adjusts the flow of fuel to
maintain specific operating conditions.  In addition  to  the basic
features provided by  computer-controlled systems,  data  and alarm
conditions can be electronically  logged,  thereby providing files
useful for demonstrating regulatory compliance.

INSTALLATION COSTS

Using direct flame contact that provides  efficient energy transfer,
the thermal processors can be made  small and compact.  Therefore,
this technology  provides installation flexibility at the point of
generation of the VOC exhaust. Long and costly ducting runs to
central abatement devices can, therefore, be avoided. The units can
be installed in  a variety  of  configurations and  can be located
outdoors.
                                                       OD335 11/9/91


                                1149

-------
                                    Duty Cycle
                               Two Shift Day (16 Hr.)
                                                                 Figure  1
0.35-d
 0.3-
      On-Demand Environmental Systems

                                                             30.8%
                                             2ao%28.3%
      Avg.=18%
            1   2   3   4   5   12   13  14  15  16  17  18   19   20  21  22
                                     March 1991

-------
                Centrally  Installed Abatement
   Wafer Track
   Positive Photoresist
   Acetate,& HMDS Emission
   200 CFM, 40 ppm, 33% Duty Cycle
in
      Source 1
        Fab A
                  1000
       Equipment Cleaning
       Acetone/ IPA
       1200 CFM, 600 p|
         Sources
am, 85% Duty Cycle
                                 Resist Application
                                 Negative Photoresist
                                 Xylene
                                 500 CFM, 150 ppm, 20% Duty Cycle
                                    Source 2
                                     FabB
                                                           250
                                          Central
                                         Processor
                                          Location
                                      800
1900 CFM
Xylene
Acetone
IPA
Acetate
HMDS
100% Duty Cycle
                                                    Figure  2

                                                     On-Demand
                                                  Environmental Systems

-------
                 Point  Source  Emission  Control
in
to
     Wafer Track
     Positive Photoresist
     Acetate,& HMDS Emission
     200 CFM, 40 ppm, 33% Duty Cycle
                                 Resist Application
                                 Negative Photoresist
                                 Xylene
                                 500 CFM, 150 ppm, 20% Duty Cycle
Sourco 1
Fab A
t



M-


«



_

                25'
M-


-rSsr
Source 2
FabB
+
                               •35'
                   MONITOR
                                  r
                                  I
        Equipment Cleaning
        Acetone/ IPA
        1200 CFM, 600 PI
          Source 3
3m, 85% Duty Cycle
                                        I
                                                                        Figure  3
                                                                         On-Demand
                                                                      Environmental Systems

-------
         VOC  Thermal  Processor
                  Combustion Chamber Exhaust
 Exit Thermocouple
Combustion Zone
 Thermocouple
                                         Figure  4
                                II 11 c o      On-Demand
                      Air + VOC Input 1 J- rM Environmental Systems

-------
Mr. Rick Hamilton, On-Demand Environmental Systems

     This presentation provided an example of actual batch
emissions that currently are being controlled using thermal
incineration.  Several semiconductor facilities in California
have installed the small incinerators that On-Demand designs and
sells.  The on-stream duration of VOC emissions from these
facilities is representative of typical batch processing
industries.  Mr. Hamilton cited an example of VOC emissions7
being in the exhaust stream of a semiconductor process only
18 percent of the time during an 18-hour workday.

     Mr. Hamilton also showed two possible configurations for the
units:  (1) handling manifolded exhaust vents and (2) controlling
individual exhaust vents at the point of generation.  Units
ranging in capacity to handle flowrates of 1,900 (cfm) down to
units handling 65 cfm were shown, and Mr. Hamilton stressed the
compactness of the units, which presumably would ease
installation, especially for controlling process vent streams at
the point of generation.  Finally, there was some discussion of
auxiliary equipment that has been employed with the systems,
primarily in detecting VOC's or specific air toxics in the vent
streams, and of the method of feedback control to augment or
release fuel in the incinerator only during a VOC emission event.
                                1154

-------
CHEMICAL
MANUFACTURERS
ASSOCIATION
                                              STATEMENT OF


                                             TERRI  RANGANTH

                                              ON BEHALF OF


                                 THE CHEMICAL MANUFACTURES ASSOCIATION

                                               BEFORE THE


                                    NATIONAL AIR POLLUTION CONTROL

                                     TECHNIQUES ADVISORY COMMITTEE

                                                 ON THE

                            CONTROL TECHNIQUES GUIDELINES FOR BATCH PROCESS


                                            NOVEMBER 21, 1991
                                               1155
                            2501  M Street, NW      202-887-1100
                            Washington, D.C. 20037  Telex 89617 (CMA WSH)

-------
 TESTIMONY OF THE CHEMICAL MANUFACTURERS ASSOCIATION BEFORE THE
   NATIONAL AIR POLLUTION CONTROL TECHNICAL ADVISORY COMMITTEE
    ON THE CONTROL TECHNIQUES GUIDELINES FOR BATCH PROCESSES
                       NOVEMBER 21, 1991

     Good Afternoon. My name Is Terry Ranganath, Air Quality
Engineer with du Pont.  I am happy to be before you today to
present testimony of the Chemical Manufacturers Association
(CMA) on the draft Control Techniques Guidelines for Control of
Volatile Organic Compound Emissions from Batch Processes.  CMA
is a nonprofit trade association whose members comprise 90% of
the productive capacity for basic chemicals in the United
States.  My presentation this afternoon will feature several of
CMA's observations, concerns, and recommendations regarding
CTG's, particularly the Batch Processing document

     CMA fully appreciates the role of CTG's in setting
Reasonably Available Control Technology (RACT) for
nonattainment areas.  Although styled as guidance documents,
CTG's are in practice more than merely guidance.  Air quality
professionals in government, industry, and environmental groups
recognize that CTG's are regarded as the final word in many
regulatory programs.  It is important that CTG's reflect the
type of well informed and reasoned analysis that such
influential documents demand.

     Control Technique Guidelines hold special significance for
companies that emit substances listed as hazardous air
pollutants (HAPS) under section 112.  Many of the 189 chemicals
listed as HAPs are volatile organics.   Companies that emit
VOC's on the section 112 list face the prospect of complying
with both RACT standards and MACT standards.

     It is important that EPA recognize that RACT and MACT are
two different standards.  The Clean Air Act clearly
contemplates that the "reasonably available" technology of RACT
standards are less stringent than the "maximum degree of
reduction" required under MACT.  CMA is concerned that the CTG
for Batch Processes confuses the two technology requirements.

     CMA supports performance standards based on percent
reduction as presented in the batch processes CTG.  However, we
believe the stringent 98% reduction efficiencies discussed in
the document are not appropriate for setting RACT.  In fact,
the draft CTG reads at times like a MACT standard.  When the
Agency identifies the presumptive norm for RACT for Batch
Processes, the discussion should be limited to control options
more in line with RACT.

     Sources that are required to meet both RACT and MACT for a
particular emission must not be forced to comply with
inconsistent standards.  CMA believes that sources which comply
with the more stringent MACT standard should be deemed to be in
compliance with the less stringent RACT requirements.
                             1156

-------
     The suggested RACT for Batch Processes is not identified
from the list of options in the draft CTG.  When the
presumptive norm for RACT is identified, we recommend that the
Agency revise the acceptable control efficiencies to reflect
the realities of operating the presumptive control equipment.

     Performance of control equipment varies with the type of
chemicals involved and operating conditions.  Therefore,
instead of a single percent reduction efficiency; the CTG
should identify an acceptable performance range which would
reflect real life emission control operations.

     There are two more areas of concern I would like to
address this afternoon.  The first regards the model used for
synthetic resin manufacturing.  The suspension-type
polymerization operation illustrated in the draft CTG is not
representative of typical synthetic resin manufacturing. In
particular, the 100% vapor saturation assumed in the example
does not account for the many operations which undergo full
vessel cleansing with water.  CMA recommends that the CTG
consider more accurate examples of synthetic resin
manufacturing.

     Secondly, we disagree with the suggestion that SOCMI
factors be used to estimate emissions from equipment leaks.
This is inconsistent with Agency's refusal to allow SOCMI
factors to be used in establishing baselines in the credit for
early reduction program.  Disallowing SOCMI factors in the
credits program is a tacit admission that the SOCMI factors
grossly overestimate actual emissions.  We recommend that the
Batch Processing CTG adopt the more accurate POSSEE database,
which is the CMA designed data entry system for fugitive
emissions testing.

     To conclude my comments, I would like to reiterate CMA's
support for the performance based format suggested in the Batch
Processing CTG.  CMA also supports the bubbling approach
discussed in the CTG as a means of complying with overall
process control requirements.  We are interested in working
constructively with EPA in developing technically sound CTG's
and look forward to offering further input.  CMA thanks the
committee for the opportunity to offer our views on the CTG for
Batch Processes.  I'd be happy to answer any questions from the
committee.
                             1157

-------
Ms. Terri Ranganath, Chemical Manufacturers Association

     Ms.  Ranganath, E.  I.  du Pont de Nemours & Co., Inc.,
representing the CMA, made a presentation which is included in
the attached handouts.   CMA agrees with the performance-based
standard of the options but stated that the use of the average
SOCMI factors overstated emissions from leaking process
components.  Additionally, a concern was stated that the
assumption EPA used for vapor space saturation also would
overstate emissions.  The prepared speech also stated that CMA
agreed with the "bubbling approach as a means of compliance."
[Ed. Note:  No bubbling approach is discussed in the CTG; there
is a RACT option that requires that facilities aggregate annual
emissions and maximum flowrates from single unit processes to use
in determining whether control is required.]  Ms. Ranganath also
suggested that the CMA's POSSE data base be used in estimating
equipment leak emissions.
                              1158

-------
                          C.   DISCUSSION

     After all three presentations were made, the floor was
opened up for questions from NAPCTAC members.  This discussion is
summarized below.

     Ms.  Deborah Sheiman of the Natural Resources Defense Council
(NRDC) opened the discussion by asking Mr. McDonald what the
difference was between RACT Options 2 and 3 on the slide.
Mr. McDonald responded that RACT Option 2 represented the
"aggregated" option, while RACT Option 3 represented the
"individual" option for 90 percent control of sources.  Both
options are in accordance with the $5,000/Mg envelope used for
illustrative purposes.  The aggregated options, simply put,
require that the annual emission rates from all process vents
from single process lines be aggregated and then used in the RACT
equation to yield a flowrate cutoff to determine whether the
sources must be controlled.  Mr. McDonald pointed out that the
option does not require that facilities physically manifold their
process vents together, but only requires that the control
requirement be evaluated as if the vents were manifolded
together.  The impact of aggregation in an option is that more
streams will require control for the same cost compare with the
individual option, as the numbers indicated.  Ms. Sheiman also
questioned why the more stringent RACT options were not presented
on the slide.  Mr. McDonald responded that the slide was intended
to show the format and impacts of the options, but for simplicity
showed only four examples.  All RACT options are presented in the
draft CTG document.

     Mr.  Brian Taranto of Exxon Chemical Americas commented on
the assumption made for estimating baseline (i.e., current
control practices).  He also said that the assumption that
industries other than Pharmaceuticals are uncontrolled results in
overestimating the national emissions from batch processes.  He
asked Mr. McDonald what the effect of this overestimation would
be on the estimated nationwide impacts of the CTG.  Mr. McDonald
responded that if the baseline emissions were in fact
overestimated, the net emission reduction resulting from the CTG
would decrease, as would the national cost associated with
implementing it.  Mr. Tarranto suggested that baseline control be
more precisely evaluated.  Ms. Ranganath repeated her concern
that use  of average SOCMI factors also overstate emissions [for
equipment leaks].

     Mr.  John Pinkerton, Program Director of Air Quality for the
National  Council of the Paper Industry for Air and Stream
Improvement, Inc., asked whether batch processing emissions would
be covered under the Hazardous Organic NESHAP (HON).  Ms. Susan
Wyatt, Chief of CPB, stated that the HON specifically exempts VOC
emissions from batch process vents at SOCMI facilities subject to


                                1159

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                                8

the HON.  However, some industries utilizing batch processes,
such as the polymers and resins industry and the Pharmaceuticals
industry, are on the source category list for NESHAP development
efforts.  Two NESHAP's currently are underway for the polymers
and resins industry.  These standards are expected to be
completed within 4 years.  Mr. Pinkerton expressed concern that
the CTG might go into effect before a MACT standard for the same
source, conceivably forcing facilities to undertake costs of
controlling for a less stringent standard, only to have to
retrofit or redesign a control system entirely for a more
stringent standard a short time later.

     Concern was also expressed about the way in which control
device cost effectiveness was calculated.  Mr. McDonald restated
the methodology and stressed that the cost-effectiveness values
obtained for the RACT options are really average values.

     Ms. Vivian Mclntire of Eastman Chemicals Company had several
questions and comments on the CTG.  The first concerned whether
the methodology considered sizing of devices for peak flows that
seemed to be insignificant to the overall emissions profile, as
was described in the slides.  Ms. Brenda Shine of Midwest
Research Institute assured her that the size and, therefore, the
capital cost of the control device was based on the peak or
maximum flow.  Ms. Mclntire suggested that the "mass flux" term
be introduced earlier in the document and pointed out some
typographical problems with the document.  Ms. Mclntyre also
asked about the specifics of the pressure testing provision
contained in the equipment leaks negotiated regulation.  This
question was addressed by Mr. Bob Ajax (seated in the audience),
formerly of the OAQPS Emission Standards Division, who was the
EPA representative in the development of this regulation while an
BSD Branch Chief.  He explained the background of the regulation
and added that the provision allowing pressure testing for batch
equipment was taken directly from industry suggestions.
Ms. Mclntire also expressed her concern that the CTG would
recommend stack testing as a means of verifying emission rate and
added that stack testing of batch emissions could lead to
erroneous results.  [Ed. Note:  EPA has not recommended stack
testing to determine applicability for the batch processes CTG
but rather an estimation procedure as of the date of this NAPCTAC
meeting.

     Mr. Taranto commended the batch team for including energy
and other environmental impacts and asked EPA to address the need
for facilities to obtain emission offsets and to do permitting.

-------
                 VOLATILE ORGANIC LIQUID STORAGE
             CONTROL TECHNIQUES  GUIDELINES DOCUMENT

                       A. EPA PRESENTATION

                         Mr. Mark Morris
                   Emission Standards Division
              U.S.  Environmental Protection Agency
          Research  Triangle Park,  North Carolina  27711

     Mr. Morris presented a summary of the draft CTG. This
presentation is provided in full text below:

     In ozone nonattainment areas there are thousands of tanks
storing petroleum liquids and chemical products at facilities
such as petroleum refineries, chemical plants, manufacturing
facilities,  and terminals and other distribution facilities.
These tanks emit over 200,000 metric tons of volatile organic
compounds (VOC)  annually, making storage tanks one of the largest
stationary sources of VOC emissions.  It is possible to reduce
these emissions by using readily available and cost-effective
controls.

     In this presentation we present the types of storage tanks
and their emission mechanisms and controls.  We also will present
some reasonably available control technology options, or RACT
options, and the benefits and costs of these options.  Finally,
we will discuss the implementation of RACT.

     There are three basic types of tanks.  There are fixed roof
tanks, internal floating tanks, or IFR tanks, and external
floating roof tanks, or EFR tanks.  These tanks are typically
aboveground and field erected.

     Our first diagram is of a fixed roof tank.  These tanks are
typically large, with the average petroleum tank having a
capacity of  1.3  million gallons,  and the average chemical tank
having a capacity of 160,000 gallons to 200,000 gallons.  The
fixed roof tank consists of a welded steel shell with a fixed
roof.  The fixed roof may be sloped or cone-shaped and supported
by one or more columns, or it may be a self-supported dome
without any  supportive columns.  The fixed roof tank is equipped
with hatches that allow access into the tank.  It is also
equipped with a  pressure-vacuum valve.  This valve prevents
damage to the tank by allowing a slight internal pressure or
vacuum to exist  within the tank.   Since this valve allows only a
slight pressure  to exist within the tank, any pressure buildup in
the tank would result in emissions through the valve.


                               llfil

-------
     There are two basic emission mechanisms of the fixed roof
tank:  working losses and breathing losses.  Working losses are
those losses that result due to a change in the liquid level in
the tank.  When liquid is withdrawn from the tank and the liquid
level goes down, ambient air is drawn in through the pressure-
vacuum valve.  This air becomes saturated with VOC's and is
expelled through the pressure-vacuum valve when the liquid level
rises.  Breathing losses result due to daily temperature changes,
which cause the thermal expansion and expulsion of the vapor
inside the tank.  Breathing losses also result from changes in
atmospheric pressure.

     Some of the parameters that affect fixed roof tank emissions
include the tank volume, the number of emptying/filling cycles,
or turnovers, and the vapor pressure and molecular weight of the
stored liquid.  Emissions from typical petroleum and chemical
fixed roof tanks are given on the next slide.

     As shown in the table, working losses make up about 75 to 90
percent of the overall fixed roof tank emissions.  You can also
see from the table that the petroleum tank emits more than the
chemical tank.  Although the chemical tank experiences more
turnovers, the petroleum tank emits more because it is larger.
Emissions in nonattainment areas from fixed roof tanks are given
in the next table.

     Overall, fixed roof tanks emit a substantial amount of
VOC's.  About 23,000 fixed roof tanks emit approximately 87,000
megagrams per year.  As shown in the table, about 11,500
petroleum tanks store liquids with vapor pressures less than or
equal to .5 psia.  These tanks emit about 13,700 megagrams per
year, or about one megagram per tank per year.  About 780
petroleum tanks emit approximately 8300 megagrams per year in the
.5 to 1.0 psia vapor pressure range.  This works out to be about
eleven megagrams per tank per year.  In the vapor pressure range
of 1.0 to 1.5 psia, about 1800 petroleum tanks emit approximately
47,000 megagrams per year, or about 26 megagrams per tank per
year.  You can see from the table that there are no tanks used to
store liquids with vapor pressures greater than or equal to 1.5
psia.  This is due to the fact that the 1977 fixed roof tank CTG
and state implementation plans prohibit the use of fixed roof
tanks for storing liquids above this vapor pressure.  These
emissions can be reduced by using the controls listed on the next
slide.

     Fixed roof tank emissions can be reduced by using vapor
recovery devices such as condensers and carbon adsorbers.  Vapor
control devices can also be used, such as incinerators.  These
devices are capable of reducing emissions by 95 percent or more.
Another, more common option is to install an internal floating
roof.  On average, installing an IFR in a fixed roof tank reduces
emissions by about 95 percent.  Installing an IFR requires that
the fixed roof tank be emptied, cleaned, and degassed.  By
installing an IFR, the fixed roof tank is converted to our second


                              1162

-------
tank type, the internal floating roof tank.

     Again, the internal floating roof tank has two roofs.  It
has a fixed roof and a floating roof which rises and falls with
the liquid level.  The floating roof can rest in complete contact
with the liquid, or it can rest on pontoons above the surface of
the liquid.  IFR's are typically made of aluminum, but can be
made using materials such as steel or stainless steel.  The
floating roof covers most of the liquid surface, and thus
prevents the vaporization of the stored liquid into the space
above the floating roof.  The floating roof does not cover the
entire liquid surface; there is still a space between the
floating roof and the tank wall in which vaporization can occur.
Floating roofs are equipped with seals to close this space.

     Some of the seal types that are used include vapor-mounted
seals, liquid-mounted seals, and mechanical shoe seals.  The
vapor-mounted seal is mounted such that a vapor space exists
between the seal material and the stored liquid.  The liquid-
mounted seal is mounted such that the seal material is submerged
in the liquid and no vapor space exists between the seal and the
liquid.  The mechanical shoe seal consists of a metallic shoe
that is held against the tank wall by springs or weights, and a
seal which extends from the floating roof to the metallic shoe to
close the vapor space.

     Some of the parameters that affect the emissions from the
IFR tank include the tank diameter and the vapor pressure and
molecular weight of the stored liquid.  There are two basic loss
mechanisms of the IFR tank: static losses and working losses.
Static losses consist of losses from seals, deck seams, and deck
fittings.  Working losses, again, result due to changes in the
liquid level.  When the liquid level goes down,  the tank wall  is
exposed.  The liquid that clings to the wall will vaporize and
escape through the roof vents at the top of the tank.   Emissions
from a typical IFR tank are given on the next slide.

     Again, static losses consist of seal losses, fitting losses,
and deck seam losses.  For the purposes of estimating costs and
emissions, a baseline IFR tank was used which was equipped with a
seamed floating roof with a vapor-mounted seal and typical
fittings.  For IFR's equipped with vapor-mounted seals, emissions
can be reduced by taking out the vapor-mounted seal and
installing a liquid-mounted seal.  Emissions could also be
reduced by installing a secondary seal above the vapor-mounted
primary seal.  For IFR's equipped with liquid-mounted seals,
emissions can be reduced by installing a secondary seal above the
liquid-mounted primary seal.  Fitting losses on IFR's can be
reduced by gasketing the fittings.  Gasketing the fittings
results in an emission reduction of about 50 percent.   Some IFR
fittings can be both gasketed and bolted to reduce emissions,  as
in the case of an access hatch.   For seamed IFR's, emissions can
be reduced or eliminated by taking out the seamed roof and
installing a welded roof,  which has no deck seams.  Although


                             11R3

-------
static losses can be reduced by using the controls described
above, there are no controls available  for reducing  the working
losses.  IFR emissions in nonattainment areas are given in the
next slide.

     Overall, about 8000 tanks emit approximately 22,000
megagrams per year.  Most of these emissions are from tanks
storing liquids with vapor pressures greater than or equal to 1.5
psia.  Most of these tanks are fixed roof tank conversions to IFR
tanks due to the 1977 fixed roof tank CTG.

     Our third tank type is the external floating roof tank.  EFR
tanks have no fixed roof but have a roof that rises  and falls
with the liquid level.  EFR's are not typically used in the
chemical industry.  The losses from the EFR tank are similar to
those of the IFR tank in that there are seal losses, fitting
losses, and working losses.  However, EFR losses differ from IFR
losses in several ways.  Since EFR tanks have no fixed roof, the
wind affects the losses more than from  the IFR tank.  EFR tanks
have welded roofs and therefore have no losses from  deck seams as
do IFR tanks.  Emissions from a typical EFR tank are given in the
next slide.

     Again, static losses consist of only seal losses and fitting
losses since EFR's have no deck seams.  There were two baseline
cases for EFR tanks due to past regulations.  The baseline EFR
storing a liquid with a vapor pressure  less than 1.5 psia was one
equipped with a mechanical shoe seal and typical fittings.  The
baseline EFR storing a liquid with any  other vapor pressure was
equipped with a mechanical shoe seal, secondary seal, and typical
fittings.  For EFR's with vapor-mounted seals, emissions can be
reduced by taking out this seal and installing a liquid-mounted
seal or a mechanical shoe seal, or by installing a secondary seal
above the vapor-mounted seal.  For EFR's with liquid-mounted
seals or mechanical shoe seals, emissions can be reduced by
installing secondary seals above these  seals.  Fitting emissions
on EFR's can reduced by gasketing the fittings.  Gasketing the
fittings reduces emissions by about 95  percent.  Again, although
static losses can be reduced, there are no controls  for reducing
working losses.  EFR tank emissions in  nonattainment areas are
given on the next slide.

     About 10,000 EFR tanks emit about  108,000 megagrams per
year.  Most of these emissions are due  to seals on tanks storing
liquids with vapor pressures greater than 1.5 psia.  Since the
1978 external floating roof CTG and state implementation plans
require secondary seals above this vapor pressure, no further
reductions can be achieved above this vapor pressure.  However,
fitting emissions can be reduced at all vapor pressures.

     RACT options for VOL storage consist of control technology
requirements for each tank type and some applicability criteria
such as tank capacity cutoffs and liquid vapor pressure cutoffs.
The control technology requirements for our selected options are,


                             1184

-------
for fixed roof tanks, to install an IFR with a double seal system
or single seal system with a liquid-mounted or mechanical shoe
seal.  The fittings would also have to be controlled.  The
requirements for IFR and EFR tanks would be to install secondary
seals and control fittings.

     This next slide presents our selected RACT options.  These
options differ only in their applicability criteria since the
control technology requirements are all the same.  Option six is
the most stringent option listed.  It has a vapor pressure cutoff
of .5 psia and capacity cutoffs of 20,000 gallons for fixed roof
tanks and 40,000 gallons for IFR and EFR tanks.  Option three in
this table most closely resembles the VOL NSPS level of control.
Option three has a vapor pressure cutoff of .75 psia and a
capacity cutoff of 40,000 gallons for all tank types.  The
impacts of these options are given on the next slide.

     Again, option six is our most stringent option.  It results
in an emission reduction of about 84,000 megagrams per year at a
total annual cost of about 49.3 million dollars, and average cost
effectiveness of about 590 dollars per megagram. Option six
results in an emission reduction of about 80,000 megagrams per
year at a total annual cost of about 37.2 million dollars, and
average cost effectiveness of about 470 dollars per megagram.
Also shown on this table are incremental cost effectiveness
values.  As shown in the table, going from option three to option
four, which is essentially becoming more stringent than the
latest NSPS level of control, results in an incremental cost
effectiveness of about 2200 dollars per megagram.

     Since RACT is a requirement for specific equipment, the
format would be that of an equipment standard.  However, vapor
recovery or control devices are acceptable if they are capable of
achieving 95 percent reduction.  Some sort of compliance
determination would need to be done to ensure proper installation
and operation of the required controls.

     For IFR tanks, this compliance determination would consist
of an initial internal inspection of the tank and seals, followed
by annual visual inspections, and internal inspections once every
ten years.  For EFR tanks, the compliance determination would
consist of initial primary and secondary seal gap measurements,
followed by annual secondary seal gap measurements, and primary
seal gap measurements every five years.  There would also be a
visual inspection whenever the tank was empty.

     The compliance schedule for the different tank types may
differ.  Installing RACT on IFR tanks requires that the tank be
cleaned and degassed.  The emissions that result from the
cleaning process are actually greater than the emission
reductions achieved by installing the controls.  Therefore, it is
recommended that the installation of RACT on IFR tanks be delayed
to the next tank cleaning.  Installing RACT on fixed roof tanks
also requires that the tank be cleaned and degassed.  However,

-------
the emission reductions achieved by installing the controls are
greater.than the cleaning and degassing emissions.  It is
therefore recommended that there be no delay in the installation
of RACT for fixed roof tanks.  Installing RACT on EFR tanks does
not require the tank to be cleaned and degassed.  It is therefore
recommended that there be no delay in the installation of RACT
for EFR tanks

     This concludes our presentation.
                             Ilfifi

-------
  CONTROL TECHNIQUE GUIDELINES
    (CTG) FOR VOLATILE ORGANIC
         LIQUID STORAGE
     NAPCTAC PRESENTATION
       NOVEMBER 21, 1991
                /-> PV
                n 7
b 1906-1. ADD/1

-------
  ORGANIZATION OF PRESENTATION






           •  Types of tanks



           •  RACT options



           •  RACT implementation
b 1906-1. ADD/2

-------
             TYPES OF TANKS
                 Fixed roof tanks



                 Internal floating roof tanks (IFR's)



                 External floating roof tanks (EFR's)
                     lies



b!906-l. ADD/3

-------
Pressure-Vacuum
           Valve
Gauge Hatch
          Manhole
Manhole
                                                                            Tank Support
                                                                            Column
               Nozzle
               (For Submerged
               Fill or Drainage)
                                           I'

-------
   EMISSIONS FROM A TYPICAL FIXED ROOF TANK
Losses
Breathing
Working
Total
Chemical
(160,000 gal,
50 turnovers/yr)
Mg/yr
0.9
5.3
6.2
%
15
85
100
Petroleum
(1 .3 million gal,
1 1 turnovers/yr)
Mg/yr
5.0
15.0
20
%
25
75
100
h 1906-1. ADD'5

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      EMISSIONS FROM FIXED ROOF TANKS IN
            NONATTAINMENT AREAS
Vapor pressure (psia)
< 0.5
0.5 - 1
1 - 1.5
> 1.5
Total
Petroleum liquid
Number
11,500
780
1,800
0
14,100
Emissions
(Mg/yr)
13,700
8,300
47,000
0
69,000
Chemical
Number
8,200
450
450
0
9,100
Emissions
(Mg/yr)
10,500
2,250
4,300
0
17,100
MW6-1 .ADD'6

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     FIXED ROOF TANK CONTROLS
              Vapor recovery/control
              Install IFR
b 1906-1. ADD/7

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                                                Cantor Vent
   Peripheral
   Roof Vent
Primary Seal
     Manhole
        Rkn
                                                                        Tank Support
                                                                        Column with
                                                                        Column Well
                                                                             Rbn Pontoon
              Rim Pontoons
Vapor Space
                                      1174

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    EMISSIONS AND CONTROLS FOR
           A TYPICAL IFR TANK
Baseline
Baseline
Baseline
Seal losses

Vapor-mounted
Liquid-mounted
Vapor-mounted and
 secondary seals
Liquid-mounted and
  secondary seals

Fitting losses

Ungasketed
Gasketed

Deck seam losses

Seams
Welded

Working losses
                           Emissions
                             (Mg/yr)
                                  0.13
                                  0.06
                                  0.05

                                  0.03
                                  0.21
                                  0.11
                                  0.04
                                  0

                                  0.03
b 1906-1. ADD/9

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           EMISSIONS FROM IFR TANKS IN
              NONATTAINMENT AREAS
Vapor
pressure
(psia)
<0.5
0.5 - 1.0
1.0-1.5
>1.5
Petroleum liquid
Number
130
25
60
5,260
Emissions
(Mg/yr)
18
24
84
18,810
Chemical
Number
0
250
250
1,400
Emissions
(Mg/yr)
0
200
300
1,500
M
  h!9O6-l.ADD/10

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   Rolling Ladder •
  Pontoon
  Manhole
•Guide Pole
Main Drain
Automatic
 Bleeder
   Vent
                                      Tank Gauge

                                      Access Hatch

                                      Seal Envelope
                                                                                 Primary
                                                                                 Shoe Seal
                                                                                  • Roof Leg
                                                                                   Support
                                         Rim Vent
                                                        r
                                                        1—Roof Drain
                                          ~ 77
                                           1- -.' a

-------
    EMISSIONS AND CONTROLS FOR
          A TYPICAL EFR TANK
Baseline
«1.5 psia)
Baseline
(>1.5 psia)
Seal losses

Vapor-mounted
Vapor-mounted and
 secondary


Mechanical shoe
                           Emissions
                             (Mg/yr)
          Mechanical shoe and
           secondary

          Liquid-mounted
          Liquid-mounted and
           secondary

          Fitting losses

          Ungasketed
          Gasketed

          Working losses
                                  15.0
                                  4.7
                                   1.25
                        0.12
                        0.70
                        0.10
                        0.24
                        0.02

                        0.22
                   T
                   JL
b!906-l. ADD/12

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        EMISSIONS FROM EFR SEALS AND
       FITTINGS IN NONATTAINMENT AREAS
Vapor
pressure
(psia)
<0.5
0.5 - 1
1 - 1.5
>1.5
Number of
tanks
960
300
470
8,000
Seal
emissions
(Mg/yr)
450
330
1,250
91,500
Fitting
emissions
(Mg/yr)
73
75
190
15,600
Total
523
405
1,440
105,400
M906-I ADD 13

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        RACT OPTION VARIABLES

              •  Control technology
              •  Tank capacity
              •  Liquid vapor pressure
                   II
bl906-l. ADD/14

-------
     RACT  CONTROL TECHNOLOGY

          •  Existing FIXED ROOF TANK -
             INSTALL IFR EQUIPPED with
             -   Vapor mounted primary and
                secondary seals
                      OR
             -   Liquid mounted primary seal
                      OR
             -   Shoe seal
                      AND
             -   Control fittings
          •  Existing IFR
             -   Control fittings
             -   Install secondary seal over
                vapor mounted primary seal
          •  Existing EFR's
             -   Control fittings
             -   Install secondary seal
                   T 1 Q
                   i. i s ?
b!906-l. ADD/15

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                    RACT OPTIONS
Option No.
1
II
III
IV
V
VI
Small
fixed roof
(20K < V <40K
gal)

--
—
—
VP>1.5
VP>0.5
Large
fixed roof
(V >40K gal)
VP>1.0
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
Internal
floating roof
(V >40K gal)
VP>1.5
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
External
floating roof
(V >40K gal)
VP>1.5
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
CO
  M9O6-I.ADD/16

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                 RACT OPTION IMPACTS


Option
No.
1
II
III
IV
V
VI

Emission
reduction
(Mg/yr)
66,200
73,500
79,700
82,800
83,400
84,000
Total
annual
cost
($106/yr)
23.8
32.0
37.2
44.0
46.1
49.3

Cost
effectiveness
($/Mg)
360
430
470
530
550
590
Incremental
cost
effectiveness
($/Mg)
N/A
1,100
900
2,200
3,800
4,800
SO
CO
  M906-1. ADD/17

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        RACT IMPLEMENTATION
            Equipment format
            Compliance determination
                  1184



b!906-l.ADD/18

-------
     COMPLIANCE DETERMINATION
                 FOR IFR's
       Initial internal inspection

       Annual visual inspection

       Internal visual inspection once every
       10 years
b!906-l. ADD/19

-------
     COMPLIANCE DETERMINATION
                FOR EFR's
       Initial gap measurement

       Annual secondary seal gap measurements

       Primary seal gap measurement once every
       5 years

       Visual inspection whenever tank is empty
                  JL


b 1906-1. ADD/20

-------
         COMPLIANCE SCHEDULE
    •  IFR's - existing IFR's required to install
       RACT at next scheduled cleaning or 10
       years after promulgation

    •  Fixed roof tanks

    •  EFR's
                  T i 07
                  .L 1 e.J i


b 1906-1. ADD/21

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B.  INDUSTRY PRESENTATIONS

-------
        Presentation to the USEPA's NAPCTAC
Commenting on the Draft CTG for VOL Storage  Document

           Sheraton  Inn University Center
                Durham, North  Carolina

                Presented  by Rob Ferry
            Conservatek Industries, Inc.
            Chapel Hill, North Carolina
                  November 21,  1991
                          1189

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Summary

The conversion   of   external  floating   roof   tanks  to  internal
floating   roof  tanks by covering  the  tank with a self-supporting
fixed  roof is an established equipment option,  recognized by both
the   American    Petroleum   Institute    (API)  and  the  U.   S.
Environmental   Protection    Agency   (EPA).     The    type    of
self-supporting  roof which is typically  used  for this  purpose is
the aluminum dome.  This fact is also recognized by both  API  and
EPA.   It can be readily demonstrated  from the API Publications
2517  and 2519 that this equipment option has lower emissions than
either internal floating  roof tanks which have column-supported
fixed  roofs,  or typical  external floating  roof  tanks.

The recommendations of  this presentation are that:
           covering an  external floating  roof  tank with a
         self-supporting  roof  be recognized as an equipment
         option,
         -  this equipment option  be described  as typically being
         an aluminum dome,  and
         -  this equipment option  be recognized  as being at the
         most efficient end  of the  hierarchy.
Documentation

Recognition of external floating roofs being converted to
internal floating  roofs by covering with a self-supporting  fixed
roof:
         API - Publication 2519 (excerpt attached)
         EPA  - AP-42 (excerpt attached)

The  typical type of retrofit self-supporting fixed  roof is  an
aluminum dome:
         API - Standard 65O Appendix G (publication  scheduled  for
               December 1991)
         EPA  - CTG for Control of Organic Compound  Emissions from
               Industrial  Wastewater (excerpt from draft attached)

This equipment option has lower emissions than either  Internal
floating roof  tanks with columns,  or external floating  roof
tanks:
         This is a straightforward  conclusion  from  the  API
Publications.  The conversion to an internal floating roof  tank
by covering an external floating roof  tank  would result  in a  floating
deck with no deck  seams,  columns  or stub drains.  API  Publication
2519 has separate figures for typical fitting loss factors  for
column-supported  fixed  roofs  and  self-supporting fixed roofs.
This comparison is summarized in a Table from an article
published in  the  Oil and Gas Journal (copy attached).
         API Publication 2517 expressly states that emissions  from
external floating  roof tanks is wind dependent,  and API
Publication 2519  expressly states  that the  wind  movement  in a
tank which is covered  with a  freely vented  fixed roof  is not
significant.  Covering  the external floating roof tank, then,
eliminates  the effect  of the primary force which Induces vapor
losses (i.e. the wind).
                                11

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The magnitude of this reduction is illustrated on the attached
Figure 1 for both a  typical fitting  scenario and for the case of
a slotted gauge pole.  There  is not  presently a table of loss
factors for the fittings with  this equipment option,  and
alternate methodologies result in different factors.    This is
illustrated  in Figure  1  by  showing  a range  for  the loss  factors,
which is bounded by the two commonly suggested  methodologies.
The API is  currently preparing a contract to have the previous
test data reviewed, and the conflict in the factors  resolved.  It
is readily apparent,  however,  that wherever the most appropriate
value may fall  within  the defined range,  it  would still represent
a significant reduction  in emissions.
Conclusion

If  the  CTG is  silent with respect  to this  equipment option,  then
the States may  not  recognize the emission control efficiency  that
a user achieves by  covering  an external floating  roof tank with a
dome.   Such an omission might serve, in effect,  to discourage the
use of a very effective control technology.   I respectfully
request,  therefore,  that the language  of  the CTG  be
modified to incorporate the recommendations  set forth in  the
Summary above.  This could be  achieved by adopting the specific
language which is  included  in the  API comments concerning this
issue,  and additionally including descriptive  language
identifying aluminum dome roofs, similar to that in the
Industrial Wastewater  CTG (excerpt attached).

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                               EVAPORATION LOSS FROM INTERNAL FLOATING-ROOF TANKS
                                                                                                          19
    SECTION 2—DESCRIPTION OF INTERNAL FLOATING-ROOF TANK COMPONENTS
 2.1   Internal Floating-Roof Tanks

   Internal floating-roof tanks are cylindrical vessels that
 have both a fixed roof over the top^of the  tank, and a
Jloating deck that rests on the liquid stock surface. There
 are two  basic  types  of internal floating-roof tanks:
 (1) tanks in which the fixed roof is supported by vertical
 columns within the tank, which are typical of fixed-roof
 tanks fitted with an internal floating deck; and (2) tanks
 with a self-supporting fixed roof, with no internal sup-
 port columns, which are typical of external floating-roof
 tanks covered  with a fixed roof.  Tanks initially con-
 structed with both a fixed roof and a floating deck may be
 of either  type.
      addition to a  cylindrical shell and fixed roof, the
 basic components of an internal floating-roof tank in-
 clude:  (1) a floating  deck; (2) an  annular rim seal at-
 tached to the perimeter of the floating deck;  and (3) fit-
 tings that penetrate the floating deck and provide support
 for the fixed roof or serve operational functions. General
 types of these components, which are available in a range
 of commercial  designs, are described in this section.
 Included in these descriptions are comments  on evapora-
 tive loss  potential,  as well as  some design and opera-
 tional characteristics.  There are  other factors, such as
 tank maintenance and safety,  which  are important in
 designing and  selecting  tank equipment, but which are
 outside the scope of this publication.
   The use of an internal floating deck will reduce the
 concentration of hydrocarbon vapor in the space between
 the floating deck and the fixed roof from  that which
 would occur in a fixed-roof tank. This could  result in the
 occurrence of flammable vapor-air mixtures within the
 tank. To minimize the occurrence of flammable vapor-air
 mixtures, vents are installed at the top of the tank shell or
 in the fixed roof to provide circulation of air  through the
 space between the fixed roof and the floating deck. API
 Standard 650 [1], Appendix H, specifies the use of such
 vents and outlines design details for the storage of pe-
 troleum liquids. Such  tanks are referred to as freely
 vented internal floating-roof tanks and are those for
 which the loss-estimating  procedures  in Section 1 are
 applicable.
   Closed internal floating-roof tanks refer to those which
 are vented only through a pressure/vacuum  relief vent.
 Such tanks are sometimes used in chemical liquid service
 and in petroleum liquid service  where API Standard 650
 is not used. These  tanks  are  typically designed  with
 auxiliary  safety devices, as specified  by the user. The
 loss-estimating procedures in Section 1 are not applicable
 to closed  internal floating-roof  tanks.
2.2   Floating  Decks

   Floating decks are typically used to control evapora-
tive stock loss. The basic design concept is to reduce the
liquid surface exposed to evaporation to a minimum by
placing a floating deck in contact with the liquid surface
or by confining a layer of saturated vapor under a vapor-
tight  deck floating above the liquid. The loss of vapor
otherwise displaced from fixed-roof tanks by filling and
breathing is virtually eliminated. Evaporation loss does
occur during standing  storage through the  annular rim
space, deck fittings, and, in some cases, deck seams.
   Floating decks are used in volatile stock service, for
stocks with a true vapor pressure at storage conditions
below atmospheric pressure  (that  is, nonboiling). They
are available in virtually all commercial tank sizes, with
diameters ranging from about 400 feet to 20 feet,  and
with slight modification, down to 8  feet. Methods  and
materials have been developed to properly seal the annu-
lar space between the tank shell and the deck rim plate,
as well as sealing  around any number of  fittings  that
penetrate the deck.
   Floating decks  are currently of  two general  types:
(1) decks constructed by bolting (or mechanically join-
ing by any method) sheets or panels of deck material and
(2) decks  of welded construction.  Decks  with  bolted
seams are typically made  of lightweight materials,
whereas welded decks are typically made of steel plates.
Both types of decks are typically designed in accordance
with API Standard 650, Appendix H.
   Floating decks  can  be  further characterized by the
location of the deck relative to the liquid stock surface. A
deck that is supported above the liquid stock surface by
bouyant structures  is referred to as a noncontact deck. A
deck  that floats directly on  the liquid stock surface is
referred to  as a contact deck. Steel decks are typically of
contact design, whereas nonferrous materials are used in
both noncontact and contact designs.
  These general types and designs of floating decks are
currently available in many different materials  and with
various design features. The basic types of floating decks
used in internal floating-roof tanks are described in 2.2.1
through 2.2.4  and  illustrated in Figure 6. More detailed
descriptions are included  in  Bulletin 2513 [7] for the
welded deck types.

2.2.1   NONCONTACT DECKS WITH BOLTED
       SEAMS

  This  deck type is currently available in two basic
designs.  The  most common design  consists  of sheet
aluminum bolted to an aluminum grid framework to form
                                                  •v "


-------
 14
                                                          API PUBLICATION 2519
                 i
                 u.~
                 a
                 Q

                 I
                          4500
                           4000
                           3500
                           3000
                           2500
                           2000
1500
                           1000
                            500
                                                            BOLTED DECK
                                                   F, = (0.0228) D2 + (0.79) D + 105.2
                                                   \
                                                       7
                                                                                    \
                                                                                             7
                                                                                        WELDED DECK (See Note)
                                                                                     F, = (0.0132) D2 + (0.79) 0 + 105.2
                                          50        100        150       200       250
                                                                     TANK DIAMETER, D (It)
                                                                                            300
                                                                                                     350
                                                                                                               400
 BASIS: Fittings include: (1) access hatch, with ungasketed, unbolted cover; (2) adjustable deck legs; (3) gauge
 float well, with ungasketed, unbolted cover; (4) sample well, with slit fabric seal (10 percent open area); (5) 1-
 inch diameter stub drains (only on bolted deck); and (6) vacuum breaker, with gasketed weighted mechanical
 actuation. This basis was derived from a survey of users and manufacturers. Other fittings may be typically useil
 within particular companies or organizations to reflect standards and/or specifications of that group. This figure
 should not supersede information based on actual tank data.

 NOTES: If no specific information is available, assume welded decks are the most common/typical type currently
> in use in tanks with  self-supporting fixed roofs.
                          Figure 2—Total Deck Fitting Loss Factors (F,) for Typical Deck  Fittings
                                            in Tanks with Self-Supporting Fixed Roofs

-------
External Floating Roof  Tanks  -  A  typical  external  floating roof tank is
shown  in Figure  A.3-2.   This  type of  tank consists  of a  cylindrical  steel
shell  equipped with  a roof which  floats on the  surface of the  stored liquid,
rising and  falling with the liquid level.   The  liquid surface  is  completely
covered by  the floating roof, except  at the small annular space between the
roof and the tank wall.  A seal (or seal  system) attached to the  roof
contacts the tank wall  (with  small gaps,  in some cases)  and covers the
annular space.   The  seal slides against the tank wall as  the roof is raised
or  lowered.  The purpose of the floating  roof and the seal  (or  seal  system)
is  to  reduce the evaporation  loss  of  the  stored liquid.

Internal Floating Roof  Tanks  - An  internal  floating  roof  tank has both a
permanent fixed  roof and a deck inside.   The deck rises  and falls with the
liquid level and either floats directly on  the  liquid surface  (contact
deck)  or rests on pontoons several  inches  above the  liquid surface (non-
contact deck).   The  terms "deck"  and  "floating  roof"  can  be used
interrhanflpably  in rpfprpnre  to thf structure floating pn t-ho ] j gi)j d_i n^jHp
    tank.^ihere are two basic types  of internal floating roof  tanks, tanf
in  which the fixed roof is supported  by vertical columns  within the  tank,
and tanks with a self-supporting  fixed roof and no  internal support  columns.
Fixed  roof  tanks that have been retrofitted to  employ a  floating deck are
typically of the first  type,  while external floating  roof tanks typically
have a self-supporting  roof when  converted  to an internal floating roof
tank.  Tanks initially  constructed with both a  fixed  roof and a floating
deck may be of either type.
    _—	•—~^-~	-v___
     The deck serves to restrict evaporation of the organic liquid stock.
Evaporation losses from decks may  come from deck fittings, nonwelded deck
seams, and  the annular  space  between  the  deck and tank wall.  Typical
contact deck and noncontact deck internal  floating roof tanks are shown in
A.3-2
Figure 4.3-2.  External floating roof tank.1

                EMISSION FACTORS
                                 1194
9/85

-------
c/EPA
United States      Office of Air Quality
Environmental Protection Planning and Standards
Agency        Research Triangle Park, NC 27711 April 1989
Air


Guideline Series
       Control of Volatile
       Organic Compound
       Emissions from
       Industrial
       Wastewater

       Volume I • Chapters

       Preliminary Draft

-------
 ratio  of the  tank diameter to the depth of the wastewater contained in the
 tank.	
     .--' ~» •	•——^
^   An  existing open-top tank can be converted to a fixed-roof tank by
 retrofitting  the tank with a dome roof.  Aluminum, geodesic dome roofs are
 available  from several  manufacturers.  These domes have been used
 successfully  to cover petroleum and chemical storage tanks.   The domes are
 clear-span,  self-supported structures (i.e., require no internal columns  be
 placed in  the tank)  that can be installed on open-top tanks ranging in
 diameter from 5 to over_100 m (15 to over 330^ft)_.	
      Although fixed-roof tanks provide large reductions in organic air
 emissions  from open-top tanks, fixed-roof tanks still can emit significant
 quantities of organics.  The major sources of organic air emissions from
 fixed-roof tanks are breathing losses and working losses.  Breathing  losses
 occur from the expulsion of vapor through the roof vents because of the
 expansion  or  contraction of the tank vapor space resulting from daily
 changes in ambient temperature or barometric pressure.   These emissions
 occur in the  absence of any liquid level  change in the tank.  Working  losses
 occur from the displacement of vapors resulting from filling and emptying of
 the tank.
      Breathing and working losses from fixed-roof tanks can be reduced by
 installing an internal  floating roof, connecting the tank roof vents  to an
 add-on control device,  or installing pressure-vacuum relief valves on  the
 tank roof vents.  The use of internal floating roofs in fixed-roof tanks  is
 discussed  in  Section 4.3.2.2.
      For add-on control applications, vapors are contained in the tank until
 the internal  tank pressure attains a preselected level.  Upon reaching this
 level, a pressure switch activates a blower to collect the vapors from the
 tank and transfer the vapors through piping to the add-on control device.
 As a safety precaution, flame arrestors normally are installed between the
 tank and control device.  Other safety devices may be used such as a
 saturator  unit to increase the vapor concentration above the upper explosive
 limit.  Add-on control  devices for organic vapors are discussed in
 Section  4.4.
                               113R
                                     4-24

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    Fitting  losses
                                                                     Fig. 4
                                            Column-supported
                                               ungasketed
              0 :   20  '•  40  ,  66    60,    tOO   120   140   160   186   200
                >•'•-,      ;   .'.M :'! ,   ,         ''.•'{•     •  ,;
                  . '!..         ;; ,    Tank diameter, H         ' ;
 with the same  functionality. Further,
 losses from some deck seams in IFRTs,
 unlike EFRTs, contribute significantly
 to total loss. Fig. 1 shows an example,
 for a specific  case,  of  how  highly
 variable losses are from the two types
 of floating-roof tanks, with  varying
 wind speed and different rim seal and
 floating deck types. Such comparisons
 can be made for specific applications
 to identify cost-effective  loss control
 measures.
   Slock inventory control. The esca-
 lating value of petroleum stocks over
 (he past decade  has caused industry to
 focus attention  on  programs empha-
 sizing accurate stock inventory ac-
 counting  and   control.   Publication
 2519, together with improved opera-
 tional  and  maintenance  practices,
 provides the operator with more accu-
 rate procedures to  estimate evapora-
 tive stock losses, thus allowing for the
 evaluation of alternative controls that
 will enable the operator to select opti-
 mum los's  control methods.
   Environmental  applications.  An
 emission inventory  for existing tanks
 can be  more accurately developed
 using the new publication. Alternative
 design features  can be evaluated in
 the process of providing emission esti-
 mates required in permit applications
 for modified or  new tanks.
  The loss equations yield estimates
 of the total hydrocarbon vapor emit-
 ted to the  atmosphere. For environ-
 mental  considerations, emissions  of
 interest are generally only the reactive
 hydrocarbon vapor, which is typically
defined to  exclude methane and eth-
 ane. Therefore, these components, if
 present, should be subtracted from the
 calculated  losses for  environmental
 applications. The results of this API
 study, as well as the previous study on
 EFRTs, have provided the basis for API
 reviews and comments  on proposed
 environmental  tankage emission con-
 trol  regulations.  These  results  were
 provided in full detail to the Environ-
 mental Protection Agency, most re-
 cently during the public review period
 for the currently proposed regulation
 on benzene storage tanks.

 Calculating IFRT losses
   Formulation  of equations. Because
 essentially  no  data were  generally
 available on evaporative losses from
 IFRTs,  API/CELM developed a com-
 prehensive  test program to identify
 and  independently evaluate all the
 sources of  loss in  an IFRT  and the
 equipment and stock parameters that
 affect losses from each source.
  CELM formed a task group to over-
 see the test program, to analyze the
 results, and to document the resulting
calculation  procedures.  The test  pro-
gram,  conducted principally by Chi-
cago Bridge &  Iron Co.  (CB&I),  and
the data analysis procedures are de-
scribed in detail in the documentation
records for the  publication.
  Losses primarily occur during stand-
 ing storage. These losses occur from:
  1. The  rim  seal area around the
perimeter  of the floating deck
  2. The  area  where fittings  (e.g.,
columns that support the  fixed  roof
that covers the tank) penetrate through


                L197
   the floating deck
     3. Bolted seams in the floating deck
     Losses  can also  occur during and
   following emptying of the tank, due to
   evaporation of the stock which clings
   to the  tank  shell.  These withdrawal
   losses are accounted for in the publi-
   cation, but are often negligible. Thus,
   to avoid unnecessary complexity, the
   following discussion will assume that
   total IFRT losses can be approximated
   by the standing storage  loss.
     The loss equations account  for all
   the important  tank  and  stock para-
   meters that affect loss.  Thus, the most
   accurate loss estimates  are obtained
   when all of the parameters are speci-
   fied  for  a given tank.  However,  in
   many cases,  little specific information
   is practically available about the tank
   or tanks for which an estimate of loss
   is desired.
     Thus, to accommodate the interests
   of both  maximum accuracy,  when
   parameters are known, and maximum
   utility,  when  parameters  are  not
   known, the publication includes infor-
   mation  on the most common/typical
   values  for those  parameters  which
   may not routinely be  known.
    Minimum input. The minimum in-
   put necessary to develop a  loss esti-
   mate  includes:
    • Slock type (i.e.,  refined   petro-
   leum stock, crude oil, or petrochemi-
   cal)
    • True vapor pressure
    • Tank type  (i.e., column-support-
   ed or self-supported fixed roof)
    • Tank diameter
    All  other parameters can be speci-
   fied for existing tanks using the stated
   most common/typical values (e.g., va-
  por-mounted  seal, column-supported
  fixed roof, bolted deck).
    By specifying these four input para-
  meters, estimates of total  loss, as well
  as the  losses  from each  of the three
  sources, can  be calculated.
    Fig. 2 shows how total and source-
  specific losses increase with increas-
  ing tank  diameter  when the  other
  three  basic parameters are  constant
  and specified as noted. Similar plots
  in which  the  other parameters  are
  varied would show:
    • That total loss is roughly propor-
  tional to TVP
    • That total loss from a petrochemi-
  cal is  equal to that from  gasoline (for
  the same TVP), but that crude oil loss
  is approximately 60% lower
    • That the fitting loss is significantly
  reduced if no  columns  are used  to
  support  the fixed roof.
    Additional  parameters. In addition
  to the four required input parameters
  discussed  in  the preceding, several
  other  parameters, if known,  can be
  used to improve the total  loss estimate
  and to evaluate various  loss control

TECHNOLOGY 5
-------
        5000
    4-
                                                                EFRT 10mph SLOTTED GUIDE-POLE +  TYPICAL FITTINGS
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        4-000"
3000 _,_
        2000-
1000-4-
                                                               -EFRT 10mph SLOTTED GUIDE-POLE W/ GASKETED  COVER
                                                                + TYPICAL FITTINGS
•                                                        IFRT, COLUMN-SUPPORTED FIXED ROOF, BOLTED  DECK,
                                                        TYPICAL FITTINGS
                                                                APPROXIMATE REDUCTION IN FITTING LOSS FACTOR BY
                                                                COVERING AN EFRT WITH A SELF-SUPPORTING FIXED  ROOF
                                                       •EFRT - W/ TYPICAL FITTINGS O 10mph
                                                    -*— EFRT - W/  SLOTTED GUIDE POLE + TYPICAL FITTINGS O Zmph1
                                                       -IFRT - SS  FIXED ROOF.  WELDED DECK. SLOTTED GUIDE POLE1
                                                       •IFRT - SS  FIXED ROOF,  WELDED DECK, TYPICAL FITTINGS 2
                                                       -EFRT - W/  TYPICAL FITTINGS O 2mph 2
                                           100'*
                                                   150'*
                                                                 1.2
                                 TANK  DIAMETER  (ft)
                          HIERARCHY  OF EQUIPMENT OPTIONS
                               FITTINGS &  DECK SEAMS

                                     FIGURE  1
ALTERNATE APPROACHES TO EFRT CONVERTED TO  IFRT BY
COVERING WITH  A SELF-SUPPORTING FIXED ROOF.  API IS
CURRENTLY REVIEWING FITTING FACTOR DATA TO CLARIFY
THIS SCENARIO.

NOTE:  FITTING SCENARIOS ARE TAKEN AS THE TYPICALS
DESCRIBED IN API PUBLICATIONS 2517 AND 2519 UNLESS
NOTED OTHERWISE.

-------
CHEMICAL
MANUFACTURERS
ASSOCIATION
                                               STATEMENT OF

                                            TERRI  RANGANATH

                                               ON BEHALF OF

                                 THE CHEMICAL  MANUFACTURERS ASSOCIATION

                                               BEFORE  THE

                       NATIONAL AIR POLLUTION  CONTROL  TECHNIQUES ADVISORY COMMITTEE

                                                 ON  THE

                           CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM

                             VOLATILE ORGANIC  LIQUID STORAGE IN FLOATING AND

                          FIXED ROOF TANKS CONTROL TECHNIQUES GUIDANCE DOCUMENT

                                            NOVEMBER 21,  1991
                                             JL >
                             2501 M Street, NW     202-887-1100
                             Washington, D.C. 20037  Telex 89617 (CMA WSH)

-------
                   CHEMICAL MANUFACTURERS ASSOCIATION
           TESTIMONY BEFORE THE NATIONAL AIR POLLUTION CONTROL
                  TECHNIQUES ADVISORY COMMITTEE ON THE
           CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM
             VOLATILE ORGANIC LIQUID STORAGE IN FLOATING AND
          FIXED ROOF TANKS CONTROL TECHNIQUES GUIDANCE DOCUMENT
     My name is Terri Ranganath.  I am air quality engineer for E.I. du
Pont de Nemours and Company.  I am speaking to you today on behalf of
the Chemical Manufacturers Association (CMA) where I serve as the work
group leader for the New Source Performance Standards/Control
Technology Work Group.  CMA is a nonprofit trade association whose
member companies represent over 90 percent of the production capacity
of basic industrial chemicals in the United States.  We are pleased to
have this opportunity to present our views to the National Air
Pollution Control Techniques Advisory Committee.

     CMA appreciates the statutory requirements for controlling
volatile organic compound (VOC) emissions and the requirement that
ozone nonattainment areas be regulated by reasonably available control
technology (RACT) standards.  Because they form the bases for RACT
standards, CTG's must be documents of high technical quality.

     At a minimum, CTG's should accurately describe the types of
facilities that will be affected by RACT standards.  CMA, however, does
not believe that the "presumptive norm" described in the CTG document
for storage tanks accurately describes the types of volatile organic
liquid (VOL) storage vessels that are commonly in use by the vast
majority of the chemical industry.   The applications in the CTG were
based primarily upon model tanks and model liquids generally employed
by the petroleum industry and can not be readily extended to chemical
facilities without consideration for the unique components of the
industry.   Therefore, CMA believes that the information contained In
the CTG does not have broad based applicability across the chemical
industry.

     Also, while the CTG has broadly defined the types of facilities
which will be subject to the RACT standards, the document does not
clearly establish the goals or the applicability parameters.  CMA
believes that both issues need to be definitively addressed prior to
publication of final guidance document to avoid any confusion on the
part of the regulated community.

     CMA has several recommendations regarding the content of the
storage tank CTG and the approach for defining what is RACT for sources
of VOC's from liquid storage tanks.

-------
 The Applicability  Parameters  and Goals  of  the  CTG  Are Not  Clearly
 Defined

      In explaining what will  be considered an  affected source  for the
 purposes of  this particular CTG, the document  allows for the state
 regulatory agency  to define the specific source or "affected tank"
 which will be  covered by RACT.  The CTG also suggests that the  state
 agency define  vapor pressure  and tank applicability ranges for  each
 type  of tank.  While CMA supports this  basic premise, we believe that
 states require guidance in setting vapor pressure  cut-offs for  RACT
 applicability.  Further, EPA  needs to clearly  define for state  agencies
 the scope of this  CTG and its  relationship to  previously published RACT
 standards.

      The CTG,  as presently written, does not clearly define for state
 agencies the scope of this guidance.  Nor  does it  clearly define its
 relationship to previously published control standards.  Environmental
 managers will  be faced with the question of whether the intended
 purpose of the CTG is to incorporate the two previously published CTG's
 and three NSPS documents, or  to merely  cover facilities not addressed
 in these documents.  The confusion could lead  facilities to duplicate
 their efforts  unnecessarily.   The intention of the CTG needs to be
 stated precisely and directly  in order  to  avoid such an outcome.

     The CTG also  needs to establish parameters for vapor pressure
 cut-offs.  The CTG suggests that state  agencies define vapor pressure
 and applicability  range for each type of storage tank.  While CMA
 supports this  premise, we believe that  RACT standards should issue
 guidelines for setting vapor pressure cut-offs.  The vapor pressure
 baseline discussed does not adequately  consider low volatility  liquids
 such as monomers like styrene, which can polymerize and cause floating
 roof tanks to  fail and not operate as a control device.  Establishing
 cut-offs avoids setting levels of control  which result in diminishing
 returns, both  incrementally and economically.
The CTG Inadequately Addresses Tanks with a Storage Capacity of Less
Than 40.000 Gallons

     Throughout the CTG, the EPA applies what is defined as the
"presumptive norm" for RACT to tanks with volume and vapor pressure
cut-offs of 40,000 gallons and 1.5 psia.  This "norm" and all the
accompanying estimations were based on the petroleum industry.  While
there exists some similarities between the petroleum and chemical
industries, the two do not parallel one another closely enough for the
standards described in the CTG to serve as an accurate reflection of
what may be achievable by the chemical industry.

     EPA also does not consider or adequately address tanks with a
storage capacity of less than 40,000 gallons.  Many of the tanks
utilized in the chemical industry are not 40,000 gallons or larger as
the EPA has assumed in the CTG.  EPA also erroneously assumes that

                             -; 1~1
                             ^ t~>  ' L

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horizontal tanks generally have a capacity of  less than  20,000
gallons.  The CTG states that "... most storage tanks below  20,000
gallons are horizontal rather than vertical tanks and a  large
percentage of these tanks are also underground...".  Across  the
chemical industry vertical tanks are operated  which have capacities of
less 20,000 gallons and there are numerous horizontal tanks  with
capacities above 20,000 gallons.  Further, based on this incorrect
assumption, the CTG document neglects to include any emission profiles
for tanks with capacities smaller than 20,000  gallons.

     In addressing tanks with capacities of 20,000 to 40,000 gallons,
the CTG considers only one vapor pressure and  two turnover rates. CMA
recommends that the EPA expand the emission profiles to the  full range
of vapor pressures discussed in the CTG document, as well as to tanks
with capacities less than 20,000 gallons.  Also, smaller tanks usually
have a higher turnover rate than two.
The CTG Overestimates the Control Efficiency of Internal Floating
Roofs

     Throughout the CTG, the equipment options and the estimated
control efficiencies described are again, based on the petroleum
industry, rather than the chemical industry.  This basis for evaluating
the effectiveness of the control techniques are inappropriate when one
considers expanding the efficiencies to process units which are unique
to the chemical industry.

     In estimating the rate of emissions from internal floating roof
tanks, the CTG acknowledges several factors, including type of roof and
seal selected, number of turnovers, tank volume and liquid type, will
affect the final amount of emission reductions achieved by the model
fixed roof tank.  Based on these factors, all of which were designed
with petroleum liquids as the baseline, the CTG estimates that a
facility can realize a reduction in emissions of 69 to 98 percent.

     CMA believes that the extrapolation of so many factors is
inappropriate and recommends that the CTG be developed which more
accurately reflects the percent reductions achievable by actual
chemical facilities.
The GTG Offers Limited Flexibility in Terms of Technical Alternatives

     The CTG document examines a limited number of control technologies
and, in fact, fails to consider technologies such as tank insulation
and submerged fill that are widely used by chemical facilities to
reduce emissions.  The CTG offers only one equipment standard (internal
floating roofs) and only one stringent control option (98 percent
control) as acceptable control technologies for 20,000 to 40,000 gallon
tanks.  In effect, this limited flexibility discourages the development
of technically innovative control options facilities would consider

-------
when examining  compliance  measures.   Additional  flexibility  is  needed
since neither an  internal  floating  roof,  nor  thermal  combustion are
realistic  controls  for  some  chemical  industry systems.

     The CTG also foregoes any  evaluation of  control  options  for  tanks
with capacities less  than  20,000 gallons  except  for the  installation of
a condenser, with a required control  efficiency  of 90 percent.   The CTG
states that this was  the only control option  examined because most
storage tanks below 20,000 gallons  are horizontal tanks, and  unsuitable
for internal floating roofs.  As stated elsewhere in  our comments, many
tanks with capacities below  20,000  gallons are vertical  systems.  While
we appreciate EPA addressing an alternative technology,  the CTG as
written does not consider  the condenser acceptable RACT.  By  promoting
the use of condensers in these  tanks,  the designated  98  percent control
level will not  be achieved.   In addition, CMA believes the 90 percent
control level is presumptive.   EPA  should acknowledge that condensers
operate at a range  of control levels  dependent on the system.

     Further, many  facilities are currently examining control measures
which will achieve  a  90-95 percent  control rate  of VOC emissions.
However, due to the lack of  flexibility in control options implied by
the CTG document, such  alternative  control efficiencies will  be
by-passed by facilities because they  could, in fact,  be viewed  as
improper controls   by the EPA.

     Internal floating  roof  control levels are also extremely dependent
on the system in which  they  operate.   One control level does  not
adequately address  the  possible range  of  controls available with an
internal floating roof.  Throughout the CTG,  a general equation must
have been used to calculate  the control efficiency of internal  floating
roofs for control of  VOL's.  That equation should be made part of the
CTG.  CMA recommends  that  facilities  be allowed  to utilize the  equation
to analyze the control  efficiency of  an internal floating roof  on their
systems.  The CTG should then allow the facility to meet or exceed that
control efficiency  in a manner  most suitable  for the  facility.
Therefore, a facility may use maximum  flexibility to  reasonably control
emissions in an effective, cost-effective manner.
The CTG Does Not Adequately Address the Interface Between RACT and
MACT Standards

     CMA is concerned that RACT regulations will be required without
consideration for maximum achievable control technology (MACT)
standards which may apply to the same facility.  The two sets of
standards could potentially create duplicative, possibly inconsistent,
regulations under the one regime.  The inconsistency which may result
could create difficulties in administration and enforcement, including
overlapping requirements, unclear jurisdiction and general confusion.
This problem could be further exacerbated because of different
enforcement authorities and different administrative implementation
programs.

-------
     Both standards are clearly defined in the statute, with RACT not
being more stringent than MACT.  We believe that facilities which have
complied with MACT should be deemed in compliance for purposes of RACT,
CMA urges authorities to be careful in their establishment and
designation of RACT standards and remain cognizant of the possibility
which exists for RACT, in effect, from becoming MACT.

     I thank the committee for the opportunity to testify on behalf of
CMA.  We are willing to offer assistance to EPA in its development of
the CTG and look forward to working with the Agency.  At this point I
would be glad to answer any questions.

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                          C: DISCUSSION

Following the presentations by the EPA, Chemical Manufacturers
Association,  and Conservatek, Mr. Bruce Jordan opened the floor
to questions and comments from the NAPCTAC members.  The short
discussion following the presentations and responses to questions
are summarized in the following paragraphs.

Ms. Mclntire asked if tanks with volumes less than 40,000 gallons
would be controlled by RACT.  Ms. Susan Wyatt of CPB/EPA
responded that the Agency was still examining possible volume and
vapor pressure cutoff points to determine the applicability of
RACT.

Ms. Mclntire also asked what emission reduction and cost
effectiveness was being assigned to IFRs.  Mr. Morris responded
that while the emissions reductions vary, typically IFRs are
about 95% effective in reducing emissions from fixed-roof tanks.
Also while the cost effectiveness would vary, about $300 - $400
per megagram was typical for controlling fixed roof tank, with
the installation of an IFR.

Mr. Taranto asked if RACT would be required equipment.
Mr. Morris stated that RACT would be based on requiring specific
equipment, but that RACT would allow for equivalent equipment and
would also allow for vapor control systems that are 95% effective
in reducing emissions.

Mr. Dennision agreed that RACT should be required equipment, but
suggested that EPA consider bifurcating RACT based on industry
type (i.e., chemical industry and petroleum industry)

Ms. Mclntire commented that while her company (Eastman Chemicals)
has numerous tanks, they do not use IFRs.  She had discussed
control of tanks with company personnel, and they agreed that
requiring IFRs was appropriate if an allowance for alternative
control techniques was a specific component of RACT.  Mr. Morris
responded that in all cases RACT would allow for vapor control
devices to be substituted for the installation of the IFR.
                               O

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D.  CORRESPONDENCE
      * O
         •

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PETREX  Inc.
2343 Dorcon Road • P. 0. Box 907 • Warren, Pennsylvania 16365
Telephone 814-723-2050 • Telefax 814-723-2055 • Telex 510 101 3005

November  12,  1991
United States  Environmental  Protection  Agency
Office of Air  Quality Planning  and  Standards
Research Triangle Park,  NC   27711

Attention:   Mr.  Bruce C.  Jordan
            Director
            Emission Standards  Division

Subject:  NAPCTAC Meeting Novembr  19-21,  1991
          CTG  for Volatile  Organic  Liquids

Gentlemen:

This letter transmits our comments  to the draft  CTG  for  volatile organic
liquid.

Our firm has been in the business  of designing,  manufacturing  and  installing
internal floating roofs  for nineteen years.  The contributors  of these
comments have  at least 30 years experience  each  in the tank, floating roof and
seal industry.

We think the CTG is  well  written and covers its  topic well.  There are however
certain  paragraphs and figures  that we  recommend be  changed.   We desire that
the CTG  fairly represent the current state  of  the art, and government regula-
tion and be technically  correct.  We also believe that the document should be
as generic  as  possible.   Some of our comments  are merely editorial.

These comments  have  also been given to  the  API Committee on Evaporation Loss
Measurement.

We expect to attend  the  session on  November 21,  1991, regarding the subject
CTG.

Very truly  yours,

PETREX,  Inc.
W.  L.  Wagner,  P.E,
President

WLW/br

 P.S.  If you have questions please call me or Bill Blumquist.

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PETREX Inc.
2349 Dorcon Road • P. O. Box 907 • Warren, Pennsylvania 16365
Telephone 814-723-2050 • Telefax 814-723-2055 • Telex 510 101 3005

November 7, 1991
Subject:   USEPA
          Control  Technique Guideline
          "Control  of V.O.C.  Emissions  from V.O.L.
           Storage in Floating and Fixed  Roof Tanks"

Our comments on this document are as  follows:

Page 2-3        Aluminum sandwich  panel  contact type  internal  floating roofs do
Para 2.2.3     not share the design feature of having  a mechanical seam
               consisting of overlapping  alumium  sheets bolted  together with
               clamping bars.  Evaporation  loss tests, made and submitted to
               API, on a mechanical seal  consisting  of a  gasket cast in place
               between two mating extrusions show a  much  lower  seam loss.

Pg. 2-4        Is  it common practice  to use P/V vents  and flame arresters
Para. 2.2.3    to  ventilate an IFR tank?

Pg. 2-4        Horizontal tanks,  above  or below ground, should  be  referred to
Para. 2.2.4    and eliminated from discussion.  Delete comments on
               composition, proportions,  etc.   Delete  illustrations Fig. 2-5
               and Fig. 2-6.

Pg. 2-5        Wiper type seals are also  used on  EFR's.   Add  to description
Para. 2.3.1    and Fig. 2-7.

Pg. 2-5        The discussion and illustrations concerning EFR  tank seals
Para. 2.3      should be limited  to mechanical  shoe  seals, liquid mounted
               seals, vapor mounted seals and secondary seals.   The use of a
               vapor mounted seal with  a  weather  shield is not  permitted and
               should not be shown.  No wiper type primary seals are shown.

Pg. 2-6        The height of the  mechanical shoe  seal  is  not  specified in
Para. 2.3.1.1  various EPA standards, such  as in  the Federal  Register, 40 CFR
               Part 60 Subpart Y  Paragraph  61.271 (a)  (1) (iii) and 40 CFR
               Part 60 Subpart Kb, Paragraph 60.1126 (a)  (1)  (ii)  (C).  This
               is  not definitive  since  the  term "mechanical shoe seal" alone
               does not guarantee the performance desired. The basis, we
               believe for the mechanical shoe seal  emissions is a test
               conducted some years ago by  CBI in California  using a 30 inch
               plus shoe.  Shoes  of lesser  length could not provide the same
               emission but could still qualify as a mechanical seal.  API
               2519 equates a mechanical  shoe seal to a liquid  mounted seal
               but with no limits to  shoe length. Later  in this document Pg.
               7-6, Para. 7.5 shoe height is mentioned.

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USEPA
Control  Technique Guideline

Page two


pg.  2-7         It is  highly doubtful  that the "wiping action" of a secondary
Para.  2.3.1.4   seal aids  in reducing  evaporation loss.  Any "wiped" liquid
               would  be above the primary seal.

Pg.  2-7         A shoe mounted seal  extending from the top of the shoe to the
Para.  2.3.1.4   tank shell  is not a  secondary seal.  This and Fig. 2-9 are
               wrong.  See definition Pg. 2-6, Para. 2.3.1.4.

Pg.  2-7         This implies that a  weather shield may be used over a secondary
Para.  2.3.1.4   seal.   A more common practice is  to combine the functions of
               secondary seal and a weather shield.

Pg.  2-8         Reference is made to Fig.  2-10 b.  This would be better
Para.  2.3.2.1   illustrated if the liquid  level were shown.

Pg.  2-9         In the comments on a shingle type seal the language is
Para.  2.3.2.2   misleading.  If a shingle  type construction does not provide a
               continuous  vapor barrier (as used in weather shields) then it
               should not  be considered a wiper seal.

Pg.  2-9         Wiper  seals using a  "blade" construction should not only be
Para.  2.3.2.2   joined but  sealed.  Simple, mechanical joining may not be vapor
               tight.

Pg.  2-9         Current EPA regulations require the use of a single, liquid
Para.  2.3.2.3   mounted seal or a vapor mounted primary seal plus a secondary
               seal.   The  description in  this paragraph and the illustrations
               in Fig. 2-10 and 2-11  do not reflect this requirement.

Pg.  2-9         The statement "Secondary seals are not commonly used on IFR
Para.  2.3.2.3   tanks", is  wrong.

Pg.  2-11       The primary purpose  of an  IFR vent or as described, "Vacuum
Para.  2.4.1.5   Breaker" is to vent  incoming or outgoing air or vapor through
               the IFR when filling or emptying.  The poppet type described
               and illustrated is strictly mechanical.  Other types operating
               on pressure/vacuum or liquid level are also used.

Pg.  2-13       Why is the  trapped vapor space under a mechanical shoe seal
Para.  2.4.1.8   ventilated  and not the vapor space under any other type of
               vapor  mounted seal?

Pg.  2-13       Reference  to Fig 2-3 is wrong.
Para.  2.4.2.1

Pg.  3-1             These  are a recapitulation of AP 42 Para. 4.3 and API           ppj
Para.  3.1  and  3.2  2519  and seem unnecessary.                                      _j

                                                                                    DO
                                                                                    m

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USEPA
Control Technique Guideline

Page three


Pg. 3-29  '     This is an excellent summary of regulations.
Para 3.3

Pg. 3-32       Some reference shold be made to support Subpart Kb, as it is
Para. 3.3.5    often referred to as such.

Pg. 3-33       Reference to the baseline control method as being a low cost,
Para. 3.3.6    non-contact IFR is wrong.  Depending on the diameter a non-
               contact IFR may cost more.  Also the use of a single vapor
               mounted seal is not permitted.

Pg. 3-34       It may be "picky" but when referring to RVP and then "vapor
Para. 3.4      pressure", TVP should be used.

Pg. 4-5        What is the basis for an IFR installation in a fixed roof tank
Para. 4.3      having an emission reduction of only 69%?

Pg. 4-5        What establishes the non-contact, bolted aluminum IFR as the
Para. 4.3      most basic?  Why is the use of a single vapor mounted seal
               mentioned when it is not permitted?

Pg. 4-17                 When retrofitting any IFR with liquid mounted
Para 4.6.2 and 4.6.3     or secondary seals additional buoyancy and storage
                         loss must be considered.  This may be especially
                         important with non-contact IFR's.

Pg. 4-18       Obviously, emissions from liquid stored in a fiberglass fixed
Para. 4.7      roof tank could be controlled by the use of a fiberglass IFR.

Pg. 5-3        This discussion on the relative effect of turnover Para.
5.2.1          rate and emissions from fixed roof tank vs. IFR tanks ignores
               the same relative effect of breathing losses.

Pg. 5-5        This states that the control options for IFR tanks are to
Para. 5.3      install IFR's??

Pg. 5-6        In considering the secondary impact emissions when emptying,
Para. 5.3.2.1  cleaning and degassing an IFR tank a large source of emissions
               has been ignored.  The large volume of hydrocarbon saturated
               trapped vapor under a non-contact IFR makes a large
               contribution.

Pg. 5-7        To suggest that a secondary seal may be added to an existing
Para. 5.4.2.1  EFR tank with the tank in service may be misleading
               economically and safety wise.  Not all such floating roofs have      "U
               a readily available flange to which a secondary seal can be          [fl
               bolted.  Many company safety rules will not permit such work.        -i{
                                                                                    33
                                                                                    m
                                                                                    *

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USEPA
Control  Technique  Guideline

Page four
Pg.  6-3
Para.  6.2

Pg.  7-3
Para.  7.2

Pg.  7-4
Para.  7.5
Pg. 7-6
Para.  7.5
Using 10 years as expected equipment life may be inaccurate.
A vapor mounted seal does not have to be foam filled,
In this paragraph the seal gap criteria appear only following
the paragraph concerning testing for EFR tanks.  Is the intent
to have these criteria apply only to EFR tanks?

N£ holes, tears or other openings in the shoe, seal fabric or
seal envelope is an absolute statement.  Can this be quantified
as in the gap criteria stated above?
General  commment:
General  comment:
     Table 4-1, Pg. 4-2 lists Control Options 1 through 6,
     later reference in Par'a 5.2, Pg. 5-1 is to Control Options
     1 through 5.  Description of these control options in
     Table 4-1, Pg. 4-2 mentions contact or non-contact for the
     first four options (2-5) and no mention of this for Option
     6.  Later on Pg. 5-21, Table 5-1 Control Option V (most
     effective) is described as a contact type IFR.

     Reading the information presented in Table 3-2, Pg.  3-7;
     Table 4-2, Pg. 4-3; Table 4-6, Pg. 4-13 and the general
     discussion on EFR tanks and gap criteria in Para. 7-5,
     Pgs. 7-5, 7-6 and 7-7 leaves the reader confused about the
     use of mechanical shoe seals in riveted tanks.  Is it
     common practice?  Is it acceptable?  What are emissions?
We will  be  pleased  to  discuss  these comments  with  you,
                                                                                    m
                                     1211
                                                                                    m
                                                                                    x

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                    State of Wisconsin \ DEPARTMENT OF NATURAL RESOURCES

                                                                      101 Saudi Wctntcr Street
                                                                            P.O. Box 7921
                                                                 Madison, Wisconsin 53707-7921
Canon D. Besadny                                                          TELEPHONE 608-266-2621
Secretary                                                                  TELEFAX608-267-3579
                                                                          TDD 608-267-6897

 November 14,  1991                                     IN REPLY REFER TO:   4530
 Bruce C.  Jordan,  Director
 Emissions Standards Division (MD-13)
 Office of Air Quality Planning and Standards
 U.S.  Environmental Protection Agency
 Research  Triangle Park,  NC  27711


       SUBJECT:     Comments For Draft  CTG Document   Control of Volatile
                   Organic Compound Emissions from Batch Processes


 Dear  Mr.  Jordan:

 My  name is Steve  Jorgensen,  and I am  an environmental engineer with the
 Wisconsin Dept. of Natural Resources,  Bureau of Air Management.  I've skimmed
 over  the  draft  CTG document entitled  "Control of Volatile Organic Compound
 Emissions from  Batch Processes".   As  a result,  I have several comments
 concerning Chapter 6 and Appendix F,  and will address them in chronological
 order.

       Section 6.3.3.1 Single Stream Versus  Aggregation.

             Sentence 1 of paragraph 2  reads,  ...  and 3/4 of the maximum flow
             rates from each process vent would be used as the maximum
             instantaneous flow rate.

             Question:    Can the reasoning behind using this ratio (3/4) be
                         included in paragraph 2?  What about using the ratio
                         of 1/1?  Such  a ratio would take into account the true
                         maximum (possible)  instantaneous flow rate.

       Section 6.4.1 Industries Covered

             Emissions with durations of under 7,800 hours per year,  for the
             applicable SIC Codes,  are  assumed to be the  result of batch
             processes.   Model  batch processes described  in Tables 6-7 through
             6-10,  however,  set a plant operation limit of 275 days per year
             (24 hour operation per day for  275 days corresponds to 6600 hours
             per year).

             Question:    Can the reasoning for this apparent difference in
                         bases  be included in the section?
                                    •Y f)
                                    JL 
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      Section  6.4.3  Baseline Assumptions/Extrapolations

            Question:   What is the exact definition of baseline  emissions?

            My interpretation from this section is that it represents  the
            remaining uncontrolled emissions from SIC Code 2834
            (pharmaceutical preparations) batch processes after pharmaceutical
            CTG controls have been applied.  Section 6.4.4, paragraph  2,
            sentence 3, however, suggests to me that baseline emissions
            include  (in addition to those described above) the uncontrolled
            emissions from the other 6 applicable SIC Codes.

      Section  6.4.4 Reductions

            The notation used to describe RACT options here appears to be
            incomplete.  In addition to Roman numerals and capital letters,
            numbers have been included elsewhere. For Example, the first RACT
            option listed in Table 6-1 is:  IA.1,5,9.

            Question:   What is the significance of the numbers used in the
                        RACT option descriptions?

My remaining comments for Chapter 6 and Appendix F are addressed on enclosed
copies of Figure 6-1; Tables 6-1,3,11, and 16; and page F-l.
The material covered in Section 6.4.2 through the end of the chapter
(including many of the figures and tables) was very difficult for me to
follow.  I still don't understand the RACT VOC options that are being
proposed, or their associated costs.  For these reasons, I cannot make an
overall comment on the validity of the CTG document.
For your information, I have included the number of known facilities by
applicable SIC Code in Wisconsin.  These facilities, located in non-marginal
nonattainment areas, are listed below.

                        SIC Code     No. of Facilities

                          2821               9
                          2834               11
                          2851               18
                          2861               2
                          2865               5
                          2869               3
                          2879               7

A breakdown of plant size (by employee number as in Table 6-15) would be
available upon request.   [  Note:  The total number of facilities in Wisconsin
within each SIC Code category is slightly larger.   In addition, Wisconsin uses
RACT guidelines to set VOC  limits statewide;  exemptions to these limits are
available for specific circumstances. ]
                                    o

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Sincerely,
Steven M. Jor.gensen, Engineer
Compliance Section
Bureau of Air Management
Wisconsin Dept. of Natural Resources

cc:   Dean Packard   AM/10
      Jon Heinrich - AM/10
      Dale Ziege   AM/10

Enclosures: Figure 6-1; Tables 6-1,3,11,  and 16; and p. F-l
                                    o

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          Cost of Control  by Thermal  Incineration

                     For VOC Concentration of 10000 ppm

                             (T = 1600F. HR = 70%)
30000
28000
26000
24000
27000
70000
j- • - 18000
to
l^» ^16000
*xJ 1 <~t
ct' _ 14000
Mo
** ^12000
0
10000

8000
6000
4000
2000
0






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                 100
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                     Table 6-1. Summary of RACT option exemptions
     PACT OPTION/
  VOLATILITY LEVEL
(CONTROL EFFICIENCY)
         I A. 1,5,9
         (98%)
                                      EXEMPTIONS for
                                    all levels of volatility
         IA.2,6,10
          (98%)
IA.3,7,11
    3/o)
         IA.4,9,12
          (98%)
                                   LOW VOLATILITY SOLVENTS:
                                 if MF < 10.000 bs/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MF0.1508M308 - NO CONTROL
                                MODERATE VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MP0.1062)-961.5 - NO CONTROL
                                   HIGH VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                      if MF >= 10,000 bs/yr AND FR >= (MP0.075)-100 - NO CONTROL

                                   LOW VOLATILITY SOLVENTS:
                                 if MF < 10,000 tos/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MP0.1537)-1527 - NO CONTROL
                                MODERATE VOLATILITY SOLVENTS:
                                 i MF < 10,000 bs/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MP0.0636)-772.7 - NO CONTROL
                                   HIGH VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                      if MF >= 10,000 bs/yr AND FR >= (MP0.055)-450 - NO CONTROL
                                           LOW VOLATILITY SOLVENTS:
                                         if MF < 10,000 bs/yr - NO CONTROL
                              if MF>= 10,000 bs/yr AND FR >= (MP0.0855)-1409 - NO CONTROL
                                         MODERATE VOLATILITY SOLVENTS:
                                         if MF < 10,000 bs/yr - NO CONTROL
                              if MF >= 10,000 bs/yr AND FR >= (MP0.0491)-881.8 - NO CONTROL
                                           HIGH VOLATILITY SOLVENTS:
                                         if MF < 10,000 bs/yr - NO CONTROL
                               if MF >= 10,000 bs/yr AND FR >= (MP0.044)-100 - NO CONTROL
                                   LOW VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MP0.0475)-1563 - NO CONTROL
                                MODERATE VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                     if MF >= 10,000 bs/yr AND FR >= (MP0.0248)-856.3 - NO CONTROL
                                   HIGH VOLATILITY SOLVENTS:
                                 if MF < 10,000 bs/yr - NO CONTROL
                       if MF >= 10,000 bs/yr AND FR >= (MP0.017)-10 - NO CONTROL
                                          -19
                                              * *> 1 P
                                              J_4,< 1.»<

-------
                                       Table 6-2. Percentage of emissions from batch processes
SIC
CODE
2821
2834
2851
2861
2865
2869
2879
SIC DESCRIPTION
Plastics materials and resins
Pharmaceutical preparations
Paints and allied products
Gum and wood chemicals
Cyclic crudes and intermediates
Industrial organic chemicals
Agricultural chemicals
<7800
(hrs/yr)
14,396
8,432
6,006
2,287
223
17,060
92
>0
(hrs/yr) "
124,547
15,459
11,998
20,415
8,365
173,167
3,912
"T 	 " " ' ' "
j
|
% BATCH
; 12%
55%
50%
11%
3%
10%
2%
                  NOTE:  Emissions data was obtained from AIRS facility subset data base search
   CO
Ch

NJ
NJ

-------
               -  /n  Idf&V  /tt£fc frl  •Ty? 6f  /6/  /

Table 6-3. Emission stream characteristics for solvent reaction model process w/ almoiphe^dryer
#of
unit ops per Calculation for 1
model batch unit operation
9.25 Displacement
(2000-gallon vessel)

TOTAL DISPLACEMENT EMISSIONS
(Ibs-batch/year)

Emission
Stream
VOC
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOIJVTIUTY
MODERATE VOLATILITY
HIGH VOLATILITY

Row Rate
(acfm)
18
18
18




Temp.
(DegQ
20
20
20




Duration
(min)
15
15
15




VOC
(vol %)
0.6%
12.6%
57.9%




Emissions
Ib/event
0.29
2.82
30.02



Emissions
Ibs/batch
(Motel)
2.64
26.08
277.66



NO CONTROL
Mass Flux
Ibs/batch
2.64
26.08
277.66
727.02
7172.28
76355.65
CPC (Note 2)
Mass Flux
Ibs/balch
2.64
7.82
30.54
727.02
2151.68
8399.12
             REACTORS
1


M
ro
k=S
CS
1


1





Charging w/purge


1 leal -up w/purge



Reaction w^jurgc


Empty Reactor Purging


TOTAL REACTOR EMISSIONS
(Ibs-batch/year)

LOWVOIATIUTY
MODERATE VOIJkTIUTY
HIGH VOLATILITY
LOW V01.ATILITY
MODERATE VOLATILITY
HIGH VOLATILITY

LOW VOI.ATIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOLATIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOIJiTIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
30
30
30
30
30
30

150
150
150
100
100
100



20
20
20
20 to 30
20 to 30
20 to 30

37
37
37
20
20
20



15
15
15
5
5
5

3
3
3
1
1
1



0.1%
3.1%
14.5%




0.5%
7.5%
27.2%
0.1%
2.7%
12.8%



0.12
1.17
12.51
0.1
0.52
5.13

0.39
2.65
22.19
0.06
0.5
1.5



0.12
1.17
12.51
0.10
0.52
5.13

0.39
2.65
22.19
0.06
0.50
1.50



0.12
1.17
12.51
0.10
0.52
5.13

0.39
2.65
22.19
0.06
0.50
1.50
184.08
1332.65
11365.50
0.12
1.17
5.63
0.10
0,52
1.85

0.39
1.35
5.33
0.06
0.32
1.26
184.08
925.91
3866.79
/•     f   /
                                  /n4
                                  ri
                                                         .

                                                      r
                                                                                       A



                                                                                    F
                                                                                                                                                     n**t ?  ?-

-------
Table 6-11. Solvent reaction model plant w/ atmospheric dryer
           MODEL PLANT EMISSIONS(lbs/yr)
                        SMALL/NC
   LOW VOLATILITY       333.236
MODERATE VOLATILITY    36U50
   HIGH VOLATILITY       749367
                           SMALL/CPC
                              36.236
                              44,621
                              86,603
                        MEDIUM/NC
   LOW VOLATILITY       1,109.676
MODERATE VOLATILITY    1203296
   HIGH VOLATILITY       2,495393
                           MEDIUM/CPC
                              120,666
                              148,590
                              288388
   LOW VOLATILITY
 MODERATE VOLATILITY
   HIGH VOLATILITY
 LARGE/NC
  3332J60
  3,613.502
  7.493,673
 LARGE/CPC
   362360
   446,215
   866.031
            MODEL PLANT EMISSIONS(tons/yr)
   LOW VOLATILITY
 MODERATE VOLATILITY
   HIGH VOLATILITY
 SMALL/NC
   166.62
   180.68
   374.68
 SMALL/CPC
    18.12
    2231
    4330
   LOW VOLATILITY
 MODERATE VOLATILITY
   HIGH VOLATILITY
MEDIUM/NC
   554.84
   601.65
   1247.70
MEDIUM/CPC
   6033
   74.29
   144.19
   LOW VOLATILITY
 MODERATE VOLATILITY
   HIGH VOLATILITY
 LARGE/NC
   1666.18
   1806.75
   3746.84
 LARGE/CPC
   181.18
   223.11
   433.02
NC = No Control
CPC = Current Pharmaceutical Control
   1. For surface condensers on sources emitting:
     -25C for VP>300mmHg
     -ISCfor 150
-------
kttf& ji&f &
OPTION
UNCONTSOLLED BASUJNH
DESCRIPTION EMISSIONS EMISSIONS
OPOKTION (MftV) (Mft^r)
& ^
AGGREGATED PROCESS VENTS WITH PR£SSURE TESTING AND WITHOUT MODE!. IT ANT
1 LJAJ.fl.12 SfifccttstroJo/iiprpted 187 .OH WJ7I
fgaeem verm llui we
DO* cicmpt per flA.4 ,8,12
2 IIU.4.8.12 90* control of •sprtiird 1 87.0*4 69,372
proueu vrni* dul *JT
ixdcietDpt per HB.-4.8.I2
) DC4.8.12 93% control of Hpvp*d 187,0*4 64.371
fTUueu vcnU dm we
DO! ciempt per IIC.4.8,1 2
INDIVIDUAL PROCESS VENTS WTT1I PRESSURE TESTING AND WTTHOUT MODEL Pl^NT 4
4 LA/4,8,12 98% ccrwol of mdividu&l 1B7.0*4 69,57}
pT -:o
^RO> ptOCCU VCQU (hll Ire
"^-^^^ o« curapt per IC.4.8,12
AOX3RECATED PROCESS VENTS WTTII PRESSURE TESTING AND MODEL PI ANT 4
7 IU.4.B.I2 90*eoom>lol.gpT|iicd 221.236 1111.794
pjaueu vcnli lh« ur
DOlcuinplpcrIB.4.8,12
PRESSURE TESTING ALONE WITII MODEL PLANT 4
t PT2 Ojidon of intuiting •
1.419 7.4W
HUl /\
>. _ NA^HONWIDE - NATIOfWfDE - . — — - AVBRACC
EAIISSION EMISSION NATIONAL COST COST PHK% ))62.911.207 S8.B92 8*
I29.4M 19,1)9 6«4 S7* 194.911.746 52.41) U'l
l)l.7a 40,1)0 7(r4 58* IJ41.798.449 J8.525 B-l
:ilj<)6 D.7I9 VM 81* 1IM.JI9.J4) 1I.8IU ml.
6S86 6886 971 92* 112.997.042 11.887 N/A
* Ntiicviwkk tmiuioo reduclion i*iuin bucluv. Cdi«tto P, «u cftlculiled ium| ilic folio* mj f.
  P-^D-t2,3lO)*(E/C)farRow« 1-7        ^
  rtua fcrmul* doea i»4 kllow the reiklud «miMK»u from ptumuoeuliul f<
' lo be iSjrthef rtduced by i|iplying tic RACT option to iheK cmtuioru.
 * Mokl |^4nt 4 re|>r««cni4 painl «mJ vvnuli nunuficiunn
     ys-   (6'/s.^td) * fc/4)

-------
CO ^
CO 45
LU T3
2 C
  cd
IL
II,
O
                 MASS FLUX = 10000 Ibs/yr
                    LOW VOLATILITY (Toluene), CCE = 98%
                                     A-
ou~
Ofi-
oU
20-
15-
1O-
I U
5_

. 	 j 	 . 	 ^ — _ 	 _^ 	 j 	
CIA& rVff$)A4>M &t£^ /?<%££. Ij 1
ct V0(
-------
  American Petroleum Institute
  1220 L Street, Northwest
  Washington, D.C. 20005
  202-682-8145
  James K. Walters
  Director, Measurement Coordination
                                              November 18, 1991
                                              RE: 300
Mr. Bruce C. Jordan
Director, Emission Standards Division
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711

Dear Mr. Jordan:

Attached please find the comments of the American Petroleum Institute (API) on the draft EPA
Control Technique Guideline, "Control of Volatile Organic Compound Emissions from Volatile
Organic Liquid Storage in Floating and Fixed Roof Tanks", as requested in your letter dated
October 4,  1991.

API requests that these comments be included as part of the official record of the EPA National
Air Pollution Control Techniques Advisory Committee meeting being held on November 19-21,
1991.

If you have  any questions on these comments, please contact me.

                                              Very  truly yours,
Attachment

cc:  CELM Members
    D. Wolter, D. Arrick
    Internal Mailing List
                                      T 9 O0>
                                      JL i~> u (^
   An equal opportunity employer

-------
            COMMENTS OF THE AMERICAN PETROLEUM INSTITUTE
                                      ON
        THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                   DRAFT CONTROL TECHNIQUE GUIDELINE

       'CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM
                   VOLATILE ORGANIC LIQUID STORAGE IN
                     FLOATING AND FIXED ROOF TANKS"

                              NOVEMBER 18, 1991
INTRODUCTION

      The American Petroleum Institute (API) is pleased to comment on the EPA's draft
Control Technique Guideline, "Control of Volatile Organic Compound Emissions from Volatile
Organic Liquid Storage in Floating and Fixed Roof Tanks" (herein referred to as the "CTG").
API represents over 250 companies involved in all aspects of the oil and gas industry, including
exploration, production, transportation, refining and marketing.

      The EPA is to be commended on its preparation of the draft CTG. The document is very
comprehensive and many of the issues mentioned herein are complex.  In order to thoroughly
address API's comments, API requests that a meeting with EPA be arranged, as provided for
in EPA's October 4, 1991 letter.

      Also, API requests that the EPA strongly consider delaying the publication of the CTG
until the results of EPA's " 114" letter on tankage distributed to eight companies during the third
quarter of 1991 and  the API fittings loss  tests are available. These results could indicate that
revisions are  needed to the draft CTG.  If EPA must publish the CTG prior to receiving the
results, then EPA should be prepared to discuss (at the meeting mentioned above) ways to
incorporate the results into the CTG.

      The API comments below are divided into General Comments and Specific Comments
(identified by section and page number).

GENERAL COMMENTS

1.    API is pleased that the draft CTG has incorporated many of API's previous comments
      and refers  to and makes use of data, analysis and standards developed by API.  API
      would like to point out that the new API Publication 2518, "Evaporative Loss from
      Fixed-Roof Tanks" is now available and a copy is included for EPA use.  This new
      document should be considered by  EPA during the revisions of both the CTG and AP-42
      for calculations dealing with fixed roof tanks.

                                        1

-------
2.     Most of the November 1983 API comments on the current CTG have been incorporated
       into the 1991 draft CTG except the omission of self-supporting fixed roofs.  The CTG
       should recognize the retrofit of an external floating roof tank with a self-supporting fixed
       roof as an equipment option.  This point is discussed throughout the comments.

3.     API recommends that, in light of the secondary waste generation, emissions,  safety and
       cost impacts, it is important to maintain the flexibility to perform seal upgrades at the
       next scheduled tank maintenance period.

4.     The effective dates for a few of the references to  Subpart K are incorrect. The correct
       effective dates are shown in the appropriate Specific Comments sections.

5.     The draft CTG  does not  mention the  exemption for tanks at drilling or production
       facilities which are  used prior to  custody transfer.  Also,  there is no mention of the
       inspection requirements for the roof seals,  gaskets and membranes in all regulated
       internal and external floating roof  tanks.

6.     The hierarchies suggested in  Section 4.0, Control  Techniques, are overly simplified.
       There is apparently an assumption  that the fittings scenario does not change appreciably
       across the country.  In actual practice, fittings options vary significantly and differences
       in fittings scenarios could change the order  of hierarchy.   Notable examples are the
       presence  or absence of support columns for  an internal floating roof tank and slotted
       gauge poles for an external floating roof tank. API Publications 2517 and 2519 discuss
       typical fittings scenarios.  Further information on this is shown in Section 4.0 of the
       Specific Comments.

7.     In Section 6.0, the CTG should mention the  time frame of the cost estimates and how
       an adjustment for inflation (1991 dollars) is to be  handled. Also, the cost effectiveness
       data  is   shown  as   being   calculated  in  dollars/megagram  but   it   is really
       dollars/megagram/year annualized over ten years.  This is  misleading and  should be
       clarified.

8.     In Section 6.2,  pg  6-2, API suggests  the CTG be corrected to  show  the following
       referenced cost data. The retrofit  cost from CTG Reference 2 lists the price difference
       for internal  floating roof seals, liquid mounted vs. vapor mounted as $20 to $40 per
       linear foot as opposed to $20  as stated in the CTG from Reference 1.

       The data from Reference 2 indicates the retrofit cost of controlling internal floating roof
       fittings is greater than $10,000 per tank, not  the $600 stated in the CTG.

       The installed cost of secondary seals is between $49 per foot and $90 per foot according
       to Reference 2, as  opposed  to the $14 per foot stated.  Some operating  plant data
       indicates  that $90 per foot cost is more representative.

-------
9.
The retrofit cost to control the guide-pole fitting on an external floating roof tank is
$2604 to $3324 according to Reference 2, not $680 as in the CTG.

Considering discrepancies in the input data, some of which are mentioned above,  API
suggests that the cost effectiveness analysis shown in Section 6.0 be evaluated more
closely. API will be addressing this issue in the immediate future and would like to meet
with EPA  to discuss this analysis.  API cannot endorse the draft cost  effectiveness
analysis at  this time.

An API contractor is reviewing  fitting losses with the objective to develop improved
fitting factors.  API invites EPA QA/QC review of the API planned test work.  This
information should be available in  late 1992 and should provide an improved technical
basis for evaluating fitting losses. It is advisable for the EPA to incorporate the resulting
data into the CTG.
SPECIFIC COMMENTS BY SECTION AND PAGE NUMBER
Section 2.2.1, pg 2-1


Section 2.2.3, pg 2-3
Section 2.2.3, pg 2-3
Section 2.2.3, pg 2-4
                    Last  sentence, delete the word  "all" and change  the word
                    "prevent" to "reduce".

                    Add the following wording from AP-42 prior to beginning of first
                    full paragraph.  "There are two basic types of internal floating roof
                    tanks, tanks  in which the fixed  roof is  supported by vertical
                    columns  within the tank, and  tanks with a self-supporting fixed
                    roof and  no internal support columns.  Fixed roof tanks that have
                    been retrofitted to employ a floating deck are typically of the first
                    type, while external  floating  roof tanks typically have  a self-
                    supporting roof when converted to an  internal floating roof tank.
                    Tanks initially constructed with both a fixed roof and a floating
                    deck may be of either type."

                    Third  full paragraph, aluminum  sandwich panel  contact-type
                    internal floating roofs do not share the design feature of having a
                    mechanical seam consisting of overlapping aluminum sheets bolted
                    together with clamping bars. Evaporation loss  tests made by one
                    tank vendor on a mechanical seal  consisting of a gasket cast in
                    place between two mating extrusions  show a much lower seam
                    loss.

                    Last paragraph, it is not common practice to use pressure/vacuum
                    vents and flame arresters to ventilate an internal floating roof tank.
                    In fact, there is the potential to generate explosive atmospheres
                    within the tank and may violate safety standards.

-------
Section 2.3.1, pg 2-5


Section 2.3.1.1, pg 2-6
Section 2.3.1.5, pg 2-7
Section 2.3.2.3, pg 2-9
Section 2.3.2.3, pg 2-9
Section 2.4.1.5, pg 2-11
Section 2.4.1.6, pg 2-12
First paragraph, wiper-type seals are also used on external floating
roof tanks. Add to the description and to Figure 2-7.

The length of the mechanical shoe seal should not be specified
because there are many good quality mechanical shoe seals already
installed in compliance  with regulations that did not previously
specify  shoe length.

The height of the  mechanical shoe is not specified in various EPA
standards, such as  40 CFR Part 60,  Subpart Y,  Para. 61.271
(a)(l)(iii) and 40 CFR Part 60, Subpart  Kb, Para.  60.1126
(a)(l)(ii)(C).  It would  not be reasonable  to require retrofits on
tanks that had working mechanical shoe seals already in place.

The basis for the mechanical shoe seal emissions is probably a test
conducted some years ago by CBI in California using a 30-inch
plus shoe.   Shoes of lesser length could  not provide the same
emission but could still qualify as  a mechanical seal.   API
Publication 2519  equates a  mechanical  shoe seal to a liquid-
mounted seal but with  no  limits to shoe length.   Later  in  the
document, pg 7-6, para. 7.5, shoe height is mentioned.

This implies  that  a weather shield may be used over a secondary
seal.  A more common  practice is to combine the  functions of a
secondary seal and a weather shield.

Current EPA regulations (Subpart Kb) require the use of a single,
liquid-mounted seal or  a  vapor-mounted primary seal plus a
secondary seal. The description in this paragraph and Figures 2-
10 and 2-11 do not reflect this requirement.

The last sentence  states  "Secondary seals are not commonly used
on internal floating roof tanks." This is incorrect  for tanks now
covered by NSPS Kb.

The primary purpose of  an internal floating roof vent or "Vacuum
Breaker" is to vent incoming or outgoing air  or vapor through the
internal floating roof tank when filling or emptying. The poppet-
type described and illustrated is strictly mechanical.  Other types
operating on  pressure/vacuum or liquid level are also used.

Fifth sentence stating: "Open drainage systems can be used only
on  double-deck  floating roofs"  is  incorrect.   Open  drainage
systems are  optional on  open center deck roofs and are  not

-------
Section 2.4.2.1, pg 2-13


Figure 2-7, pg 2-21

Figure 2-11, pg 2-25

Section 2.5, pg 2-32


Section 3.1/3.2, pg 3-1


Section 3.2.1, pg 3-1
Section 3.2.1, pg 3-2


Section 3.2.1, pg 3-2

Table 3-1, pg 3-3
Section 3.2.2, pg 3-4
uncommon. This is also incorrectly presented in API Publication
2517 on pages 41  and 42.  Page 41 states that only double-deck
roofs  have overflow  roof  drains and  page 42  states that some
proprietary designs  are available.   These two statements are
contradictory.

First sentence, the reference to Figure 2-3 is incorrect.  The
correct reference is to Figure 2-1.

The word "Shield" is misspelled in  figures a, c and d.

The word "immersed" is misspelled.

The reference 1 for API Publication 2518 should be changed to
reflect the recent publication date of October 1991.

These are a recapitulation of AP 42, para. 4.3 and API 2519 and
seem unnecessary.

Add a  sentence after the  last complete  sentence  on this page
stating:  "Alternatively, breathing losses from fixed roof tanks may
be calculated using the methods described in API Publication 2518,
revised  October 1991."

Equation  (3-2) should be changed to agree  with the revised
equation in the new API 2518.

In description  of "P", change  "atmospheric" to "absolute".

The paint factor condition for medium  gray on the shell and roof
is listed as 1.40 for  good  paint  and  1.58 for poor paint.  API
Publication 2518,  First Edition, lists 1.46 for good paint.  This
typographical  error should  be  corrected.

API does not have a method for estimating evaporative losses from
horizontal tanks and cannot endorse the EPA method in the CTG.
However, based on the comments below and using  the suggested
changes, the EPA method may constitute a rough or screening
mechanism.

The user is referred to emissions equations for  fixed-roof tanks.
An equivalent diameter, De, is calculated on the length, L, of the
tank and  the  real (vertical)  diameter, D, of the tank.  The
equivalent  diameter is  then used in the  AP-42 fixed-roof tank

-------
                           equations. This calculation method shown is overly simplistic and
                           tends to over-estimate the emissions. This method would be better
                           described as a screening method for estimating emissions.

                           There are two factors that contribute to the over-estimation. The
                           first is that the user is instructed to calculate the average vapor
                           space by multiplying the exposed area of the liquid half-full, using
                           the equivalent diameter, by one-half of the real diameter (for the
                           height  value).  This value will always be greater than the real
                           (default) average vapor space volume, which is one-half of the
                           tank volume.

                           The second is that the exposed area of the stored liquid varies with
                           the liquid height and is at its maximum when the tank is half-full.
                           When the liquid level rises or falls, the exposed area decreases.
                           Therefore, the effective diameter value decreases from this mid-
                           point maximum.  This would have no effect on the vapor space
                           volume calculations but could reduce  the saturation levels of the
                           vapor space,  particularly when lower vapor pressure liquids are
                           stored.  Lower vapor pressure liquids are often stored in horizontal
                           cylindrical tanks.

Section 3.2.3.1.2, pg 3-8   Fourth sentence, change "1 to 15 mi/hr"  to "2 to 15 mi/hr."
Table 3-3, pg 3-9
Table 3-3, pg 3-9
The Kf,  factor for weighted  mechanical actuation, ungasketed
vacuum breaker should be "1.1".

The subscript "c"  states emergency roof drains are not used on
pontoon floating roof tanks.   This is not correct and  should be
deleted.
Table 3-5, pg 3-11
Table 3-5, the number of pontoon legs for the 250 foot diameter
tank should be "35".
Section 3.2.3.1.4, pg 3-14  This section should contain a paragraph explaining the effect of
                           tank color on the vapor pressure.  API Publication 2517, Section
                           2.2.2.3 and Table 10 describe this.
Section 3.2.4, pg 3-15
Section 3.2.4.2, pg 3-21
Add the following sentence to  the  bottom of the  paragraph:
"Vapors  are also  expelled by  the expansion of the air in the
enclosed space due to diurnal temperature changes (breathing)."

The rim  loss factors for tight fitting seals are not provided.  See
API Publication 2519, page 8,  Table 3.
                                           6

                                         122B

-------
Section 3.2.4.2, pg 3-21
Add the reference to "shoe"  seal as stated in the NSPS.
discussion of the NSPS in Section 3.3.5 of this CTG.
See
Section 3.2.4.3, pg 3-24
Section 3.2.4.4, pg 3-29



Section 3.3, pg 3-29

Section 3.3.1, pg  3-29
Section 3.3.4, pg 3-31
Section 3.3.5, pg 3-32
Thus change descriptions to: "Liquid-mounted or shoe primary seal
only" and "Liquid-mounted or shoe primary seal plus secondary
seal".

In description of NF1, add  "In the case of an internal floating roof
tank that has been converted from an external floating roof tank by
retrofitting with a self-supporting roof, Tables 3-3, 3-4 and  3-5
should be used  to estimate the number of fittings."

The deck seam loss factor  (Sd) of 0.20,  which is given as a default
value,  should also be listed as the factor for a deck constructed
with continuous metal sheets with a 5 foot spacing between seams.

This is an excellent summary of  the regulations.

Subpart K became effective June 11, 1973 for tanks greater than
65,000 gallons  that were  constructed, reconstructed or modified
after that  date.   The date of March, 1974 is effective for tanks
between 40,000 and 65,000 gallons.

No mention  is  made of the  exemption for tanks at drilling or
production facilities which are used prior to custody transfer.

Subpart Ka NSPS, the effective date is implied to be April, 1980.
The  subpart  actually   is  effective  for  tanks  constructed,
reconstructed or modified  after May, 1978.

There is no mention of the exemption for production tanks used
prior  to custody transfer, which are less than 420,000 gallons.
Also, there is no mention of the inspection requirements for  the
seals on external floating roof tanks.

Volatile Organic Liquid NSPS,  there is  no mention that this is
actually Subpart Kb.  The effective date is implied to be April
1987.  The subpart actually is  effective for tanks constructed,
reconstructed or modified  after July 1984.

There is no mention of the exemption for production tanks used
prior  to custody transfer, which are less than 420,000 gallons.
Also, there is no mention of the exemption for tanks at gasoline
bulk plants and service  stations,  or tanks used for the storage of

-------
Section 3.3.5, pg 3-32


Section 3.3.5, pg 3-32
Section 3.3.6, pg 3-33
Section 3.4.1.1, pg 3-34


Section 4.0, pg 4-1
Table 4-1, pg 4-2
beverage alcohol. Also, there is no mention of the requirement for
periodic inspection of roof seals,  gaskets, and membranes in all
regulated  internal floating roof tanks and external  floating roof
tanks.

Some  reference  should  be made to support 40 CFR  Part 60,
Subpart Kb as it is often referred to as  such.

Last paragraph,  add as second sentence:  "Shoe seals  are also
typical to internal floating roof tanks which have been converted
from external  floating roof tanks  by retrofitting  with a  self-
supporting fixed roof."

Reference to the baseline control method as being a low cost, non-
contact internal floating roof tank is incorrect.  Depending on the
diameter, a non-contact internal floating roof tank may cost more.
Also, the use of a single vapor-mounted seal is not permitted.

When  referring to RVP and then "vapor pressure", TVP should be
used.

Differences  in  fittings  scenarios  could  change  the order of
hierarchy.  A spreadsheet is attached as Exhibit A which further
illustrates the concern mentioned above.  The CTG  indicates that
the contribution to  the total loss due to fittings is +/- 28%.  The
spreadsheet shows that "typical" fittings on a 50 foot diameter tank
with a mechanical shoe primary seal are, in fact, 28% of the total.
The fittings contribution increases to 72%, however, if the tank
has a slotted guide-pole.  The respective contributions due to each
source category vary too widely to be assigned a representative
percentage.

A hierarchy of equipment cannot be readily achieved  when all
source categories are included in  the same list because different
combinations would result in  different  rankings.    A separate
hierarchy for each source category however,  could be readily
developed.  Such an approach  would also lend itself to including
all  floating  roof tanks,  rather than having  separate  lists for
internal and external floating roof tanks.

This table lists Control  Options 1 through 6.  The reference in
Section 5.2, pg  5-1 is  to Control  Options I through  V.  The
inconsistency in these tables is confusing.

-------
Table4-l,pg4-2


Table 4-1, pg 4-2



Table 4-2, pg 4-3

Table 4-2, pg 4-3
Section 4.3, pg 4-5


Table 4-3, pg 4-7

Table 4-4, pg 4-8

Section 4.3.3, pg 4-9
Section 4.4, pg 4-9
Section 4.4, pg 4-9
Table 4-5, pg 4-11
Under Control Options 5 and 6, add "or shoe" after the words
"liquid-mounted".

Add superscript "b" after superscript "a" in the title after "RATE".
Add another footnote:  "bSelf-supporting fixed roofs would result
in lower emission rates for each control option."

Footnote "a" is missing.

Add superscript "b" after superscript "a" in the title after "RATE".
Add another footnote:  "bConversion to an internal floating roof
tank by retrofitting  with a self-supporting fixed roof would result
in lower emission rates for each control option."  The reason is
primarily because it blocks the wind, but the "shading" effect may
provide  additional  benefit by resulting  in  a  lower  surface
temperature of the stored product.

Third paragraph, are  the  fittings assumed to  be controlled  or
uncontrolled?

In footnote, third sentence, change "split"  to "slit".

Add "or shoe"  after "Liquid-mounted" in two places.

The second paragraph  does not address bolted  construction with
gasketed seams as a potential emission reduction or control.  The
statement that  the deck seam losses are not a factor of the type of
seam is incorrect.

The first paragraph in  this section should  be deleted.   There are
too many options to consider,  i.e. tank size, fittings, seal details,
etc. to make such a generic statement.

First sentence, add  "typical" before the words "internal floating".
Also, add a sentence to the end of the paragraph:  "An internal
floating roof tank with welded deck seams and no support columns
would emit less VOC  per unit of storage  area than do external
floating roof tanks due to the elimination of wind influence."

Deck fitting type 3 (or any equipment description) does not address
slotted gauge pole/sample wells. This should be added.
                                           9

                                       ' o o

-------
Section 4.4.3, pg 4-12
Table 4-6, pg 4-13

Table 4-6, pg 4-13
Table 4-6, pg 4-13


Section 4.5, pg 4-14
Section 4.5, pg 4-14
Section 4.5.1, pg 4-14.
Add a last sentence: "Retrofitting an external floating roof tank
with a self-supporting  fixed roof would convert  the  tank to an
internal floating roof  tank and eliminate the wind influence,
thereby reducing the rim seal losses. "
Title of second column should be
Add as sixth description:  "Metallic shoe primary seal only with
self-supporting  fixed roof retrofitted to tank0."   Add "3.0^" and
"99%" in second and third columns respectively.

Add as last description:  "Liquid-mounted or shoe primary  seal
with rim-mounted secondary seal with self-supporting fixed roof
retrofitted to tank6." Add "1.6d" and "99%" in the second and
third columns respectively.

Add footnotes  as follows: '""Retrofitting with a self-supporting
fixed roof converts the tank to  an internal  floating  roof tank."
"dFrom values listed in Section 3.2.4.1."

Sixth description as  written, change "steel"  to "seal".  Also, in
footnote a, the word "listed" is shown twice.

Delete the first sentence on this  page.  It is uncommon to put a
redundant blower in the vapor collection system.  Blowers/ electric
motors do not fail often enough to justify a full spare.  In case of
a failure, the tank vents through  the pressure/ vacuum vents while
the blower is repaired.   Occasionally, there are more than one
blower for capacity reasons,  not  sparing.

The reference to saturators should be deleted.  Saturators are very
unusual. More common are  systems that are designed to run rich
(above upper explosive limit), enriched  with natural gas to 1.2
times upper explosive limit (21 percent),  or inerted with nitrogen
or inert flue gas. Some systems are designed to run lean  (<25
percent of lower explosive limit).  Flame arresters and/or water
seals are almost always used.

The statement  that  applying the technology  to VOL's is not
difficult should be stricken.  The application of carbon adsorption
to petroleum mixtures is a complex problem. The reference given
is for vapor recovery of a pure hydrocarbon, benzene, which is a
simpler problem.   Some  specific issues to be  concerned about
when applying  carbon adsorption (CA):
                                           10

-------
      o     CA capacities to adsorb C1( C2, C3, and C4 molecules are very low. For practical
             purposes, CA is not a good recovery technology for these molecules.  They pass
             through the bed almost immediately.

      o     Hot vapor streams which contain heavier components  saturate the carbon with
             molecules which cannot be removed except by conditions more severe that the
             CA unit is capable of. The carbon usually must be replaced.

      o     The H2S present in some petroleum product vapors reacts on the carbon to form
             solid  elemental sulfur (Clause Reaction), which fouls the carbon bed.   The
             elemental sulfur cannot be regenerated off the bed so H2S containing streams are
             not good candidates for CA.

      o     Water vapor is  also adsorbed by the carbon,  so vapor streams with high humidity
             must  be dried before  the CA unit.  Also, if water vapor is present, the carbon
             must be protected from sub-freezing temperatures or else the carbon particles will
             be damaged by ice crystal formation.

      o     Part of the complexity of applying carbon  adsorption is in sizing the carbon
             column to handle a peak vapor load in short period of time vs. a truck loading
             rack recovery unit that handles small vapor volumes over a long period of  time.
Section 4.5.1, pg 4-14
Section 4.5.2, pg 4-15
Section 4.5.2, pg 4-15
Section 4.5.2, pg 4-15
Section 4.5.3, pg 4-15
Third paragraph, regarding steam regeneration, it would be unique
for a typical gasoline marketing facility to generate steam and have
an associated wastewater treatment system on site.

First  paragraph,  fourth line, delete "the simplest  to operate".
Oxidation units require a significant supplemental supply of fuel to
operate.  Of concern, they generate NOx and CO which may need
to be removed and also may require regular monitoring.

The reference to saturators should be deleted.  Saturators  are very
uncommon. Vapor gathering systems are deliberately designed to
operate at less than 25  percent of  the lower explosive  limit or
above 1.2 times  the upper explosive limit to avoid the possibility
of propagating explosions.

Delete the word "two"  in  the  second  full paragraph,  second
sentence.  Only a single water seal between the combustion device
and the vapor system is common.  Dual seals are a redundance
used at the owner's option.

Refrigerated  condensation   systems  are  also  used  on  vapor
collection systems in addition to vent condensers.
                                          11

-------
Section 4.6.2, pg 4-17
Sections 4.6.2, pg 4-17
  & 4.6.3
Section 4.6.4, pg 4-17
Section 4.6.5, pg 4-17
Section 4.7, pg 4-18



Section 4.8, pg 4-18


Section 5.2.1, pg 5-3
Section 5.4.1, pg 5-7
Additional rim floatation should be added as another consideration
in the modifications.

When retrofitting any internal floating roof tank with liquid
mounted or secondary seals, additional buoyancy and storage loss
must be considered.  This may be especially important with non-
contact internal floating roof tanks.

Practical experience has shown that hot work and/or tank redesign
is almost always required, therefore, the tank must be taken out of
service, cleaned and degassed.

Add a new section "4.6.5 Self-Supporting Fixed Roofs on External
Floating Roof Tanks.  Several design issues are encountered in the
retrofit of a self-supporting fixed roof to an existing open-top tank.
For example, the reactions from the fixed roof produce localized
loading  on the tank.  The self-supporting fixed roofs are typically
made of aluminum, which results  in the potential for differential
movement between the aluminum fixed roof and the steel tank
shell  due to  the difference  in  their  coefficients of thermal
expansion."

Add the wording, "Emissions from liquid stored in a fiberglass
fixed  roof tank could be controlled  by the  use of a fiberglass
internal floating roof tank."

The date for Reference 1, API Publication 2517, should be June
1989.

Third full paragraph, second sentence. Do  not agree that the only
control option is a condenser.  The proper  control method would
be a vapor balance system; delivery to these tanks is typically by
truck.  This control system is described in an EPA report dated
December  1977  (Report 450/2-77-035,  page  14,   reference
alternative #2   vapor balancing of transport truck and the storage
tanks).

The last sentence should be revised to read: "From Figure 5-8, it
is shown that the greatest  emission reduction for a  baseline
external  floating roof tank with  metallic  shoe  primary seal  is
obtained from  the  addition of a  secondary  seal and controlled
fittings.  From Figure 5-9, it  is shown that the greatest emission
reduction for a baseline external floating roof tank with a vapor-
mounted primary seal is obtained  by  the substitution of a liquid-
                                           12

-------
Section 5.4.2.1, pg 5-7
Figure 5-9, pg 5-20

Section 5.5.1, pg 5-21


Section 5.5.2, pg 5-22


Section 6.2, pg 6-4
Section 6.2, pg 6-3


Section 7.2, pg 7-3
Section 7.2, pg 7-3
mounted  primary  for  the  vapor-mounted  primary  seal  in
conjunction with  the addition of secondary  seals and controlled
fittings."  The sentence,  as written, is incorrect as it refers to two
different baseline tanks and does not differentiate between the two.

First paragraph, it mentions that external floating roof tanks are
equipped with a flange on which a secondary seal can be mounted.
However, due to the ages of most external floating roof tanks, this
flange either requires repair or modification in order to mount the
secondary seal.  In some cases hot work may be needed when
installing a secondary seal on an external floating roof tank.  In
these  cases, tanks would have to be cleaned and degassed.

Also,  adding  a secondary seal to an existing external floating roof
tank  with the tank  in service  may violate  safety  company
guidelines and should be left to each company to decide.

Figure 5-9 does not include a definition for the "1m" abbreviation.

Table 5-1, the word "emissions"  in the title of column  3 is
misspelled.

Table 5-2, the title of column 2 should read "Nationwide Emission
Estimates, Mg/yr (tons/yr)".

The value of petroleum  product recovery  credits  is more
appropriately $50 per ton instead of $320 per  ton, based on
wholesale butane prices at $0.10 per pound. The losses from most
petroleum product (and crude oil) storage is primarily butanes and
pentanes that were contained within  the products.   The CTG
should be revised to show $50 per  ton of recovered product.  See
Exhibit  B.

First full paragraph, using 5  10 years as the expected equipment
life may be  more accurate.

Add the following definition for clarity because of the inspection
requirements  in Section 7.5:   "Internal floating  roof tanks are
storage  vessels that have a floating  roof and a freely vented fixed
roof.  The fixed roof is  not necessarily free of openings but does
span the entire open plan area of the vessel."

Fifth  full  paragraph, a  vapor-mounted seal does not have to be
foam-filled.   Delete "foam-filled."
                                          13

-------
Section 7.5, pg 7-4
Section 7.5, pg 7-6
Section 7.5, pg 7-7
Section 7.6, pg 7-8
Reading the information presented in Table 4-2, Table 4-6 and the
general discussion on external floating roof tanks and gap criteria
in Section 7.5, it may be difficult for operators of riveted tanks
with  mechanical shoe  seals  to  meet  the specified  seal gap
requirements  of Section 7.5.

Item (ii) should be revised to state that no appreciable holes, tears
or other openings  in  the shoe,  seal  fabric  or  seal envelope.
Alternatively, the EPA should quantify this requirement as in the
gap criteria stated above.

The requirement  that the owner prepare an "operating plan" for
control devices is redundant and  unnecessary.  The  devices are
subject to capacity verification and emissions testing when they are
installed. Additional documentation is unnecessary.  In addition,
the  units  are  always  designed  and  tested  (per  state  test
requirements) at maximum, worst case loadings.  The documen-
tation for off peak flow rates, compositions, etc. is generally not
available and would cost individual terminal operators thousands
of dollars  each  to have developed.   This  section could  be
simplified  to  require  that   the  owner/operator   must  have
documentation that the system is capable of handling the peak load
that  is expected from his current maximum  operating  rate.
Previous permit applications,  design/ purchase specifications, or
state approved performance testing would be sufficient.

Item 1., states the highest maximum true vapor pressure for the
range of products stored should be used for emission calculation.
This number  would give the maximum emissions for that product
at that particular time but would not be representative of the true
emissions over the  period of a year.   For example, a products
pipeline will  pump  a varying number of vapor pressure products
depending on the season.  Using the maximum  vapor  pressure
over-estimates  the  true emissions  over  this  period.   A  more
accurate method would be to use the weighted  average true vapor
pressure and  corresponding temperature.
                                           14

-------
            MOV 08  '91  16=33 CONSERVflTEK NO CAR  919 933 4210
                                                                                                                     P.2
         i »T r-¥**\rt**l tW  nt*  f*rt*lVl*.«*-t.lT TtfFJ"**   .—I nATTUO ri/".n/~ TfllU//*
         nirnnm.ni  iir  rmnrnrni urrn   Himiihn niiiir  innnn

                  (assume 10 »ph Mind b(Jttd  for £FRT)
  50'  Diaieter
EOUIPrlEHT  DESCRIPTION
  SEAL
FflCTORS
Open top tank, welded  shell   (EFRis)     38.00
  •echanical  shoe  oriwry  seal

Open top, Melded shell     (£FRi5,ss)     2.00
  shoe priaary + secondary seal

Coluw-supported fined roof  (WFRvii)     6.70
  Bolted dock, priwry ual  only

Coluin-aip'M fixed roof  (blfftvi.ss)     £.50
  Bolted deck, pniary + secondary
Self-supporting  fixed roof
  Uelded deck, sow seal only
    3.00
Self-wip'ting  fixed roof        1.60
                          secuiiddr/
 100' Diaieter
EQUIPHENT DESCRIPTION
  SEA.
FACTORS
Open top,  shoe  seal only   (EFRis)       38.00

Colum-supported, bolted  b)     £.30

Open top,  shoe  + secondary(EFR«s,ss)     2,00

Self-supporting) welded   (vIFRis)        3.00

Self-supporting, wlded   (*IFRis,ss>     1.60
 ISO1  Maieter
F-fiUIPHBO DE5CRIPTIDH
  SEAL
FflCTORS
Open top, shoe seal only   (EFftaO       36.00

Column-supported, bolted  (bIFRvi)        &.70

Colmn-supported, bolted  (bIFRvt,ss)     £.50

Open top, shoe + secondary 
-------
           WHAT IS THE PRODUCT CREDIT FOR REDUCED VOC LOSSES ?
There are two ways of looking at the value of lost material:
  The value is the same as the value of the liquid in the tank, or
  The value is that of the lost material sold as a separate product.

The first method is appropriate for single component liquids, or for
end-user commodities.

The second method is better for unfinished materials in production, and
for wholesalers of broad product slates such as oil refiners.

The material that evaporates from petroleum fuel tankage is primarily
lighter components such as butanes, pentanes, and other light hydrocarbons.
VALUE AS FINISHED PRODUCTS
                                 $/GAL     LB/GAL     $/LB
           CRUDE OIL                0.56       7.1        0.08
           GASOLINE                0.65       5.6       0.12

VALUE AS COMPONENT

           BUTANE (normal)          0.47       4.9       0.10
           NATURAL GASOLINE       0.53       5.6       0.09

                    AVERAGE OF BOTH METHODS =     $0.10
All prices per gal shown above were taken from the Plait's Oilgram Price
Report for Tues., 11/12/91; adjusted to price per gallon units.

All figures rounded off.

-------
APPENDIX:  RECORD OF ATTENDANCE

-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                           NOVEMBER 19,  20,  AND  21, 1991
PLEASE   PRINT
          NAME  AND
        AFFILIATION
                 BUSINESS ADDRESS
                (INCLUDE ZIP CODE)
  TELEPHONE
   NUMBER
DATE(S)
ATTENDED
                                       14Z?

   frmoco Oi
           %OO
            M(L
             II//1&2D
                             /Ol
                     A
-------
                                RECORD OF ATTENDANCE
         NATIONAL  AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19, 20, AND 21,  1991
PLEASE   PRINT
          NAME  AND
        AFFILIATION
 BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
                                   ?
                                   '/*-*•/
                                                         57 V
                          tf-

                                                                     /HL.
                                       .OB
                                            0 C
                                        JC

-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES  ADVISORY COMMITTEE MEETING
                            NOVEMBER  19,  20, AND 21, 1991
PLEASE   PRINT
          NAME AND
        AFFILIATION
 BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
                                                         bo;
                               w
                                                                        I fa ft I
                                                                             i
  AD^yOtf*"*   ~&
                                             <*
-------
                              RECORD OF ATTENDANCE
        NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                          NOVEMBER 19,  20, AND 21,  1991
PLEASE  PRINT
         NAME AND
       AFFILIATION
 BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
  Jodie,
                                                     733-33^0
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-------
                                 RECORD  OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL  TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19, 20, AND 21,  1991
PLEASE    PRINT
          NAME AND
        AFFILIATION
                                BUSINESS ADDRESS
                               (INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
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-------
                                 RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19, 20, AND 21,  1991
PLEASE    PRINT
          NAME AND
        AFFILIATION
 BUSINESS  ADDRESS
(INCLUDE ZIP CODE)
                               TELEPHONE
                                NUMBER
DATE(S)
ATTENDED
                 TT«\  V
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-------
                                 RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION  CONTROL TECHNIQUES ADVISORY COMMITTEE  MEETING
                            NOVEMBER 19,  20,  AND  21,  1991
PLEASE    PRINT
          NAME AND
        AFFILIATION
                             BUSINESS  ADDRESS
                            (INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
   C
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-------
                                 RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION  CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19,  20,  AND 21,  1991
PLEASE   PRINT
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        AFFILIATION
 BUSINESS  ADDRESS
(INCLUDE ZIP CODE)
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 NUMBER
DATE(S)
ATTENDED
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-------
                                 RECORD  OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL  TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19, 20, AND 21,  1991
PLEASE    PRINT
          NAME AND
        AFFILIATION
 BUSINESS ADDRESS
(INCLUDE  ZIP  CODE)
TELEPHONE
 NUMBER
DATE(S)
ATTENDED
                        L,
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-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY  COMMITTEE MEETING
                           NOVEMBER 19,  20,  AND  21, 1991
PLEASE   PRINT
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 BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
 NUMBER
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ATTENDED
                                                          9/7
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                                                                      11-2,1
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-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19,  20, AND 21, 1991
PLEASE   PRINT
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 NUMBER
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ATTENDED
                                    Ckt/irvi KvU
                                            TX
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-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER 19,  20,  AND  21, 1991
PLEASE   PRINT
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 NUMBER
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ATTENDED
                               3) -
                                                         773 -
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            num-
                                   <&£-
                                                                    "/'t-
                                                          7'J
                                                  ..
                                             271 M
                                          11

-------
                               RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE  MEETING
                           NOVEMBER 19, 20,  AND  21, 1991
PLEASE   PRINT
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 NUMBER
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                                                                   ivjil-z.)
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                                            (Mb -17}
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                             373 £
                                          r
                                                      C7/7) -781-

-------
                                RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                            NOVEMBER  19,  20, AND 21,  1991
PLEASE   PRINT
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        AFFILIATION
 BUSINESS ADDRESS
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TELEPHONE
 NUMBER
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                                RECORD OF ATTENDANCE
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         NATIONAL AIR POLLUTION CONTROL TECHNIQUES  ADVISORY COMMITTEE  MEETING
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                                 RECORD OF ATTENDANCE
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                                  RECORD OF ATTENDANCE
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                               RECORD OF ATTENDANCE
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                                 RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY  COMMITTEE  MEETING
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                                RECORD OF ATTENDANCE
         NATIONAL AIR  POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
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                              RECORD OF ATTENDANCE
        NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
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                               RECORD OF ATTENDANCE
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                              RECORD OF ATTENDANCE
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                                 RECORD OF ATTENDANCE
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                             NOVEMBER  19,  20, AND  21, 1991
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-------
                                 RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                             NOVEMBER  19,  20, AND  21, 1991
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-------
                               RECORD OF ATTENDANCE
         NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
                           NOVEMBER 19,  20, AND 21, 1991
PLEASE   PRINT
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  NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE

                        MINUTES OF MEETING

                       NOVEMBER 19-21, 1991
Prepared by:
               Office of the 'Director
               Emission Standards  Division
     I certify that, to the best of my knowledge, the foregoing
minutes and attachments are complete and accurate.
                          Bruce  Cjxtfordan,  Chairperson
                   National Air  Pollution Control Techniques
                               Advisory Committee
                   U.S. Government Printing office
                                        312-014/40042

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