United States Office of Air Quality Emission Standards
Environmental Protection Planning and Standards Division
Agency Research Triangle Park, NC 27711
&EPA National Air Pollution
Control Techniques
Advisory Committee
Minutes of Meeting
November 19-21,1991
i
Volume 2 of 2
Printed on Recycled Paper
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National Air Pollution
Control Techniques
Advisory Committee
Minutes of Meeting
November 19-21,1991
U.S. Environmental Protection Agency
Office Of Air and Radiation
Office of Air Quality Planning and Standards
Emission Standards Division
Research Triangle Park, North Carolina 27711
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Two Volume Set: Volume 1 (Section I - X)
Volume 2 (Section I, XI - XVIII, and Appendix)
TABLE OF CONTENTS
PAGE
I. INTRODUCTION AND OPENING REMARKS
Bruce C. Jordan, Committee Chairman 1
Director, Emission Standards Division (ESD) "
Office of Air Quality Planning and Standards, EPA
II. GENERAL PROVISIONS
A. EPA Presentation
Michele Dubow, ESD 5
B. Industry Presentation
Chemical Manufacturers Association 19
Danny Anderson
Vice President of Environmental Affairs
First Chemical Corporation
a. Supplemental Comments 22
C. Discussion 28
III. HAZARDOUS ORGANIC NATIONAL EMISSION STANDARDS FOR
HAZARDOUS AIR POLLUTANTS (NESHAP)
A. EPA Presentation
Daphne McMurrer, ESD 33
B. Industry Presentation
Chemical Manufacturers Association 43
Thomas Robinson
Manager of Regulatory Affairs
Vulcan Chemicals Corporation
C. Discussion 48
IV- COKE OVEN NESHAP
A. EPA Presentation
Amanda Agnew, ESD 53
B. Discussion 66
V. DRY CLEANING NESHAP
A. EPA Presentation
Linda Herring, ESD 67
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B. Industry Presentation
1. International Fabricare Institute *
William Fisher, Vice President
C. Discussion . - 83
VI. CHROMIUM ELECTROPLATING NESHAP
A. EPA Presentation
Lalit Banker, BSD 87
B. Discussion 99
VII. SECTION 112g
A. EPA Presentation
Tim Smith, BSD 105
B. Industry Presentations
1. Motor Vehicle Manufacturers Association . . 119
Richard Paul
Manager, Environmental Health
2, American Petroleum Institute 125
F. Dan Gealy
Director, Public Relations
Atlantic Richfield Company
3. Pharmaceutical Manufacturers Association . 131
Richard Vetter
Associate Counsel
Burroughs Wellcome
4. Chemical Manufacturers Association .... 140
Joe Woolbert
Principal Chemical Engineer
Texas Eastman Chemical Company
C. Discussion 145
VIII. SOURCE CATEGORY SCHEDULE FOR STANDARDS
A. EPA Presentation
David Svendsgaard and Chuck French, BSD .... 155
* Did not provide a copy of presentation for inclusion in the
minutes.
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PAGE
B. Industry Presentation
1. Institute of Chemical Waste Management . . . 181
Jonathan Kaiser
Manager, Resource Recovery and Combustion
Programs
National Solid Wastes Management Association
C. Discussion 190
D. Correspondence
1. Chemical Manufacturers Association .... 196
2. American Iron and Steel Institute 199
Bruce A. Steiner
Vice President, Environment and Energy
IX. INDUSTRIAL PROCESS COOLING TOWERS
A. EPA Presentation
Phil Mulrine, BSD 201
B. Industry Presentation
1. Superior Manufacturing Company 227
Chuck Sanderson, Engineer
C. Discussion 236
X. MEDICAL WASTE INCINERATORS
A. EPA Presentation
James Eddinger, BSD 241
B. Industry Presentations
1. Cremation Association of North America . . 279
a. Paul Rahill
b. Ed Laux
c. Harvey Lapin
2. Waste Combustion Equipment Institute . . . 332
Stephen Shuler
Chairman
3. American Hospital Association 340
Jim McLarney
Director, Division of Health Facilities
Management and Compliance
and
Lawrence G. Doucet
Doucet and Mainka, P.C.
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PAGE
4. B.C. Wickberg Company . 378
Henry H. Hadley
President
5. Calvert Environmental, Inc 386
Ronald G. Patterson
President
6. Konheim and Ketcham, Inc 397
Carolyn S. Konheim
President
C. Discussion 435
D. Correspondence
1. Wisconsin Department of Natural Resources . . 457
Donald F. Theiler
Director
Bureau of Air Management
2. Joy Energy Systems, Inc 459
Steve Shuler
Manager
Sales and Marketing
XI. OVERVIEW OF CONTROL TECHNIQUES GUIDELINES PROGRAM
A. EPA Presentations
1. General Overview
Susan R. Wyatt, BSD 468
2. Transfer Efficiency and Regulatory Guidance for
Spray Coating Operations
Dave Salman, BSD 477
B. Discussion 495
XII. PLASTIC PARTS COATING
A. EPA Presentation
Joanie McLean, Radian Corporation 500
B. Industry Presentations
1. National Paint and Coatings Association . . 521
Naomi Suss
PPG Industries, Inc.
"IV
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PAGE
2. Motor Vehicle Manufacturers Association . . 539
Joe Lennon
Environmental Control Engineer
Ford Motor Company
3. Graco, Inc 553
Steve Kish
Market Development Manager
4. Mobay Corporation 562
John L. Williams
Director, Technical Marketing
C. Discussion 569
D. Correspondence
1. Navistar International Transportation
Corporation 577
Tim W. McDaniel
Environmental Manager
2. Electrostatic Consultants Company 579
Arvid C. Walberg
3. Vantage Products Corporation 608
Dale C. Jones
Finishing Department Manager
4. Motor Vehicle Manufacturers Association . . . 623
Eugene A. Praschan
Manager, Emissions and Control
XIII. OFFSET LITHOGRAPHY
A. EPA Presentation
Donna Jones, Radian Corporation 631
B. Industry Presentations
1. Rosos Research Laboratories 672
Agi Rosos
President
2. C.A. Enterprises, Ltd 676
Paul L. Martin
Vice President, Product Development
3. American Newspaper Publishers Association . . 680
Wilson Cunningham
Vice President, Technical Research
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4. National Association of Printing Ink
Manufacturers 700
James E. Renson
Environmental Affairs Coordinator
5. Environmental Conservation Board 714
a. Gerald Bender
Vice President
Environment, Safety, and Materials
Engineering
R.R. Donnelley and Sons, Company
b. William Schaeffer
Consultant, Graphic Arts Technical Foundation
c. William Schneidereith, Jr.
President
Schneidereith and Sons, Inc.
C. Discussion 810
D. Correspondence
1. National Association of Printing Ink
Manufacturers 826
James H. Sutphin
Executive Director
XIV. OVERVIEW OF CONTROL TECHNIQUES GUIDELINES PROGRAM
(Repeat of presentations under Section XI.)
XV. WOOD FURNITURE COATING
A. EPA Presentation and Discussion
Mary Jo Caldwell, Midwest Research Institute . . 841
B. Industry Presentations and Discussions
1. Union Carbide 883
Thayer West
Marketing Manager, Unicarb System
2. Classic Systems, Inc 890
David Brookman
Technical Representative, Finishing Division
3. Graco, Inc 905
Steve Kish
Market Development Manager
VI
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PAGE
4. Mobay Corporation 912
John L. Williams
Director, Technical Marketing
5. American Furniture Manufacturers Association. 921
Business and Institutional Furniture
Manufacturers Association
Kitchen Cabinet Manufacturers Association
National Paint and Coatings Association
a. Robert G. Mclnnes
Principal Air Quality Engineer
ENSR Consulting and Engineering
b. Mark Berkman
Senior Consultant
National Economic Research Associates
C .v Correspondence
1. Thomasville Furniture Industries, Inc. . . . 963
Sherry Stookey
Supervisor
Environmental Compliance
XVI. AUTOBODY REFINISHING
A. EPA Presentation and Discussion
Darcy Campbell, Radian Corporation 965
B. Industry Presentation and Discussions
1. National Paint and Coatings Association . . . 997
Karl Schultz, Chairman, Automotive Refinishing
Coalition
2. BASF Corporation 1012
Bob Inglis
Director, Product Planning
3. Safety-Kleen 1023
John P- Kusz
Manager, Product Development
4. National Auto Dealers Association 1028
Douglas I. Greenhaus
Senior Attorney, Regulatory Affairs
5. PPG Industries, Inc 1037
R.T. Hilovsky
Manager, Regulatory Affairs
Automotive, Aircraft, and Fleet Finishes
VI 1
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PAGE
6. The Sherwin-Williams Company 1045
Gregory Ocampo
Product Manager
C. Correspondence
1. Graco, Inc ". 1055
Steve Kish
Market Development Manager
2. Herkules Equipment Corporation 1060
Richard A. Robb
President
3. DuPont-Automotive Products 1065
Karl R. Schultz
Environmental Consultant
4. National Paint and Coatings Association, . 1074
Automotive Refinish Coalition
Jim Sell
Senior Counsel
XVII. BATCH PROCESSES
A. EPA Presentation
Randy McDonald, ESD 1115
B. Industry Presentations
1. On-Demand Environmental Systems, Inc. . . . 1148
Richard E. Hamilton
Vice President
2. Chemical Manufacturers Association .... 1155
Terri Ranganath
E.I. duPont de Nemours and Company
C. Discussion 1159
XVIII. VOLATILE ORGANIC LIQUID STORAGE
A. EPA Presentation
Mark Morris, ESD 1161
B. Industry Presentations
1. Conservatek Industries, Inc 1189
Rob Ferry
Vice President
VI
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PAC
2. Chemical Manufacturers Association .... 1199
Terri Ranganath
E.I. duPont de Nemours and Company
C. Discussion 1205
D. Correspondence
1. Petrex, Inc 1206
W. L. Wagner
President
2. Wisconsin Department of Natural Resources . 1212
Steven M. Jorgensen
Engineer, Bureau of Air Management
3. American Petroleum Institute 1222
James K. Walters
Director, Measurement Coordination
APPENDIX: RECORD OF ATTENDANCE 1239
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I. INTRODUCTION AND COMMENTS
Mr. Bruce C. Jordan, Chairperson
National Air Pollution Control Techniques
Advisory Committee
The National Air Pollution Control Techniques Advisory
Committee (NAPCTAC) of the U.S. Environmental Protectional Agency
(EPA) held a meeting on November 19-21, 1991, at the Sheraton Inn
University Center in Durham, North Carolina. Mr. Bruce Jordan
called the meeting to order at 9:00 a.m. Committee members in
attendance were:
Mr. Donald R. Arkell
Dr. Patrick R. Atkins
Mr. William J. Dennison
Mr. Ralph E. Rise
Ms. Vivian M. Mclntire
Mr. William O'Sullivan
Dr. John E. Pinkerton
Ms. Deborah A. Sheiman
Mr. Brian L. Taranto
Messrs. Paul H. Arbesraan and Charles A. Collins were unable to
attend the meeting.
The agenda for the meeting was published in the Federal
Register on October 22, 1991.
Mr. Jordan opened the meeting by extending a welcome on
behalf of EPA and then introduced his colleagues at the speakers
table; the EPA and EPA contractor staffs on hand to answer
technical, economic, and regulatory questions; and the EPA staff
handling the administrative aspects of the meeting. He asked
that everyone sign the official register to provide a record of
their participation in the meeting (see Appendix). Mr. Jordan
noted that minutes of the proceeding would be available as soon
as possible after the date of the meeting.
Mr. Jordan briefly outlined the agenda and then introduced
the first of several speakers representing EPA and various
industries who addressed issues concerning air pollution to the
Committee.
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AGENDA
U. S. ENVIRONMENTAL PROTECTION AGENCY
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
Sheraton Inn University Center
Brightleaf Ballroom (Third Floor)
15-5Q1 at Morreene Road
2800 Middleton Avenue
Durham, North Carolina 27705
(919) 383-8575
NOVEMBER 19, 20, AND 21, 1991
November 19 (Tuesday) - 9:00 a.m.
NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS
(NESHAP) PROJECTS STATUS REPORTS
(Title III of the Clean Air Act Amendments)
General Provisions
Hazardous Organic NESHAP (HON)
Coke Ovens
Dry Cleaning
Chromium Electroplating
SECTION 112g
Status Report on the Development of Guidance for New, Modified, and
Reconstructed Sources
(Title III of the Clean Air Act Amendments)
SOURCE CATEGORY SCHEDULE FOR STANDARDS
Status Report on the Development of a Prioritized Agenda for Source Category
Emission Standards Promulgation
(Title III of the Clean Air Act Amendments)
A LUNCH BREAK WILL BE TAKEN FROM 1:00-2:00 P.M. EACH DAY
11/19/91 2
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2
November 20 (Wednesday) - 9:00 a.m.
CONTINUATION OF NOVEMBER 19--AS REQUIRED
INDUSTRIAL PROCESS COOLING TOWERS
Status Report on the Development of the Proposed NESHAP
(Title III of the Clean Air Act Amendments)
MEDICAL WASTE INCINERATORS
Status Report on the Development of the Proposed Standards and Emission
Guidelines
(Section 111 and Title III of the Clean Air Act Amendments)
CONTROL TECHNIQUES GUIDELINES (CTG) PROGRAM
(Title I of the Clean Air Act Amendments)
Overview of Program
Plastic Parts Coating CTG Document
Offset Lithography CTG Document
November 21 (Thursday) - 9:00 a.m.
CONTINUATION OF NOVEMBER 20--AS REQUIRED
CONTROL TECHNIQUES GUIDELINES (CTG) PROGRAM
(Title I of the Clean Air Act Amendments)
Overview of Program
Wood Furniture Coating CTG Document
Autobody Refinishing CTG Document
Batch Processes CTG Document
Volatile Organic Liquid Storage CTG Document
A LUNCH BREAK WILL BE TAKEN FROM 1:00-2:00 P.M. EACH DAY
11/19/91
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U.S. ENVIRONMhN I AL PHU I tc I
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
Chairperson and Designated Federal Official
Mr. Bruce C. Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
(919) 541-5572
FTS: 629-5572
COMMITTEE MEMBERS
Mr. Paul H. Arbesman
Director, Pollution Control
Allied-Signal, Inc.
Columbia Road and Park Avenue
Morristown, New Jersey 07962
(201) 455-4286
Mr. Donald R. Arkell
Director
Lane Regional Air Pollution Authority
225 North 5th Street-Suite 501
Springfield, Oregon 97477
(503) 726-2514
Dr. Patrick R. Atkins
Director, Environmental Control
Aluminum Company of America
1501 Alcoa Building
Pittsburgh, Pennsylvania 15219
(412) 553-3805
Mr. Charles A. Collins
Administrator, Air Quality Division
Wyoming Department of Environmental Quality
122 West 25th Street
Cheyenne, Wyoming 82002
(307) 777-7391
Mr. William J. Dennison
Dennison and Associates
4 Cintilar
Irvine, California 92720
(714) 752-4150 or 51
Mr. Ralph E. Hise
President
Advanced Technologies Management, Inc.
2964 Falmouth Road
Cleveland, Ohio 44122
(216) 751-5135
Ms. Vivian M. Mclntire
Environmental Affairs
Eastman Chemicals Company
Post Office Box 511
Kingsport, Tennessee 37662
(615) 229-3045
Mr. William O'Sullivan
Assistant Director
Air Quality Engineering and Technology
N.J. Department of Environmental
Protection
401 East State Street, CNO27
Trenton, New Jersey 08625
(609) 984-6721
Dr. John E. Pinkerton
Program Director, Air Quality
National Council of the Paper Industry
for Air and Stream Improvement, Inc.
260 Madison Avenue
New York, New York 10016
(212) 532-9047
Ms. Deborah A. Sheiman
Resource Specialist
Natural Resources Defense Council
1350 New York Avenue, N.W. - Suite 300
Washington, D. C. 20005
(202) 783-7800
Mr. Brian L. Taranto
Senior Environmental Conservation
Associate
Exxon Chemical Americas
13501 Katy Freeway
Houston, Texas 77079
(713) 870-6117
4
November 19, 1991
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OVERVIEW OF CTG
PROGRAM
Presented by Susan Wyatt
Chemicals and Petroleum Branch
Emission Standards Division
Environmental Protection Agency
Susan Wyatt, Chief of the Chemicals and Petroleum Branch
explained that all the remaining agenda items involved Control
Techniques Guidelines (CTG's). Therefore, the purpose of her
presentation was to provide an overview of the CTG program.
First, she explained that CTG's apply to volatile organic
compound (VOC) emissions in nonattainment areas and provide
guidance to States in writing VOC rules. Although CTG's contain
recommended control levels, States can always adopt more stringent
rules. They can also adopt less stringent rules on a case-by-case
basis, provided there is adequate justification and the rules are
approved by EPA. (Slide 2)
Ms. Wyatt then described the Clean Air Act requirements for
CTG's, listed the CTG's EPA is working on, and described that there
are various opportunities for public comment on CTG's. EPA is also
developing rules and information documents on other VOC sources.
These were listed. (Slides 3-6)
Ms. Wyatt then explained that some of the source categories
covered by CTG's will also be covered by Title III hazardous air
pollutant standards. She described why both are needed for full
coverage, and emphasized that EPA is sensitive to the need to make
the two programs complementary. (Slide 7) Then she listed the items
to be covered for each CTG project at the NAPCTAC meeting. (Slide 8)
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OVERVIEW OF VOC
CONTROL TECHNIQUES GUIDELINE (CTG)
PROGRAM
NAPCTAC
NOVEMBER 20-21, 1991
469
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WHAT ARE CTG'S? |
• FOR VOC; TITLE I OZONE
NO N ATTAIN ME NT
• GUIDANCE FOR STATES
• RECOMMENDED RACf
• CASE-BY-CASE RACT
• RACT RULES SUBMITTED TO
EPA FOR APPROVAL AS PART
OF STATE IMPLEMENTATION
PLAN (SIP)
1 RACT = REASON ABLY AVAILABLE CONTROL TECHNOLOGY
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WHAT DO THE CAAA
REQUIRE FOR CTG'S?
13CTG'SBY11/93
STATES MUST ADOPT
REGULATIONS FOR CTG
SOURCE CATEGORIES FOR
ALL BUT "MARGINAL"
NONATTAINMENT AREAS
£71
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PROJECTS & SCHEDULE
CTG / SOURCE
DRAFT
FINAL
SOCMI Distillation
SOCMI Reactors
12/91
12/92
8
10
Wood Furniture
Plastic Parts: Business
Machines
Plastic Parts: Other
Offset Lithography
Industrial Wastewater
Autobody Refinishing
SOCMI Batch Processing
VOL Storage Tanks
4/92
6/93
11
12
13
Cleanup Solvents
Aerospace Coatings
Ship Building & Repair
9/92
11/93
TBD
TBD: Schedule to be determined, projects started in FY 92.
£72
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OPPORTUNITIES FOR PUBLIC
COMMENT?
NAPCTAC AND PUBLIC
REVIEW OF PRELIMINARY
DRAFT (NO
RECOMMENDATION)
FR NOTICE - DRAFT FOR
PUBLIC COMMENTS
FR NOTICE - FINAL CTG
PUBLISHED
PROPOSAL OF STATE
REGULATIONS
^73
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OTHER VOC FEDERAL MEASURES
MARINE VESSEL LOADING
RULE
CONSUMER/COMMERCIAL
PRODUCTS REPORT AND
NATIONAL RULES/CTG'S
INFORMATION DOCUMENTS
(ACT'S) FOR PESTICIDE
APPLICATION AND BAKERIES
STAGE II INFORMATION
DOCUMENTS
6
£74
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RELATION OF CTG'S TO
TITLE III RULES
• NEED FOR BOTH
• CONSIDERATION OF BOTH IN
CTG/RULE DEVELOPMENT
AND IMPLEMENTATION
575
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WHAT WILL WE COVER TODAY?
• SIX CTG'S
• EMISSION SOURCES
• CONTROLS
• RACT OPTIONS (NO RACT
RECOMMENDATIONS)
• EMISSION AND COST
IMPACTS OF OPTIONS
- MODEL (EXAMPLE)
PLANTS
- NATIONWIDE
• IMPLEMENTATION
CONSIDERATIONS
• CONSIDERATION OF
TRANSFER EFFICIENCY IN
CTG'S INVOLVING COATINGS
',;76
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TRANSFER EFFICIENCY AND REGULATORY GUIDANCE
FOR SPRAY COATING OPERATIONS
PRESENTATION BY
David Salman
Chemical Application Section
Chemicals and Petroleum Branch
November 20, 1991
(SLIDE 1) - I will briefly discuss our thoughts on
incorporating transfer efficiency in the regulatory guidance we
will be providing for spray coating operations.
(SLIDE 2) - To preview our thinking, I have subtitled this
presentation "Why we do not plan to recommend quantitative
consideration of transfer efficiency in the spray coating CTGs
that will be discussed at this meeting."
(SLIDE 3) - To explain the meaning and basis for this plan,
in the rest of my talk I will:
Identify the spray coating industries and the types of
spray equipment they use.
Discuss transfer efficiency, its definition, its
importance and its complexities.
Explain how these complexities often make transfer
efficiency difficult to measure because of its frequent
variation, and difficult to incorporate quantitatively into
regulatory guidance or regulations.
(SLIDE 4) - Our section has worked with coatings and coating
industries for over fifteen years. We have worked in the past
with at least 6 coating industries that predominantly spray coat,
preparing control technique guidelines (CTGs) or new source
performance standards (NSPSs). We have tried various ways to
deal with transfer efficiency in these guidelines and
regulations, with limited success and much difficulty- We have
drawn upon this experience in attempting to deal with transfer
efficiency in the three predominantly spray coating industries
which will be discussed at this meeting; plastic parts, wood
furniture and automobile refinishing.
Each of these industries coats a wide range of parts with
many different coatings. Individual facilities in each of these
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industries typically change the size and shape of parts being
coated and/or coatings being sprayed many times each day.
(SLIDE 5) - There are many types of spray equipment
available. This slide uses a Chinese restaurant menu approach to
describe various types of spray equipment. The different types
of spray equipment can be categorized by how they atomize the
paint (air, airless, air-assisted-airless, high-volume low-
pressure and rotary atomizers such as bells and discs), how the
paint is attracted to the part (electrostatic and non-
electrostatic) , and how the equipment is operated (manual hand-
held or automatic equipment ranging from simple reciprocators to
complex robots).
Most combinations of atomization/attraction/operation are
available. Most are used to some extent in every spray coating
industry with the exception of automobile refinishing which uses
fewer types of equipment. Each type of equipment may be used
alone or in combination with other types of equipment in larger
spray booths or in a series of spray booths.
(SLIDE 6) - In order to understand transfer efficiency, it
is first necessary to understand a little about coatings. Liquid
coatings can most simply be thought of as containing solvents
(which are often VOCs) and solids (film forming materials). The
solvents evaporate during application and cure of the coating.
The remaining solids cover the part and dry or cure into the
final film or coating.
When paint is sprayed, some of the solids sprayed adhere to
the part and some miss or bounce off the part. The solids that
are wasted because they do not adhere to the part are referred to
as overspray. Transfer efficiency is a measure of this paint
waste. Transfer efficiency is the ratio of the amount of solids
deposited on the part(s) to the amount of solids used (sprayed).
For a particular job, where the amount of solids deposited is
constant (coating a given area to a given dry coating thickness),
the amount of solids sprayed varies depending on the transfer
efficiency. The lower the transfer efficiency, the more solids
need to be sprayed and the greater the amount of waste. The
better the transfer efficiency, the less solids need to be
sprayed with a corresponding reduction in the amount of waste.
(SLIDE 7) - Why is transfer efficiency important? Transfer
efficiency determines the amount of paint used to do a job and
the cost of paint for that job. Transfer efficiency is directly
related to 1) the quantity of VOC emissions generated and 2) the
amount of solid waste resulting from overspray. Transfer
efficiency also affects other operating costs such as filters,
maintenance, booth clean-up, ventilation requirements and waste
disposal.
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(SLIDE 8) - This slide gives a graphical description of how,
for a particular job, the volume of paint used, VOC emissions and
solid waste generated varies with transfer efficiency.
At 100 percent transfer efficiency, this job could be done
with 3 gallons of coating. The VOC emissions would equal the
amount of VOC in the 3 gallons of coating and there would be no
solid waste generated from overspray-
At 60 percent transfer efficiency, 5 gallons of the same
coating would be needed to do the same job. The VOC emissions
would equal the amount of VOC in the 5 gallons of coating. The
amount of solid waste generated from overspray would equal the
amount of solids in 2 gallons of coating.
At 30 percent transfer efficiency, 10 gallons of the same
coating would be needed to do the same job. The VOC emissions
would equal the amount of VOC in the 10 gallons of coating. The
amount of solid waste generated from overspray would equal the
amount of solids in 7 gallons of coating.
At 15 percent transfer efficiency, 20 gallons of the same
coating would be needed to do the same job. The VOC emissions
would equal the amount of VOC in the 20 gallons of coating. The
amount of solid waste generated from overspray would equal the
amount of solids in 17 gallons of coating.
As transfer efficiency goes down, the amount of coating
used, the amount of VOC emitted and the amount of solid waste
generated all increase.
(SLIDE 9) - What affects transfer efficiency? The short
answer to this question is virtually everything. Transfer
efficiency is affected by:
The skill, technique and fatigue level of the operator.
The size, shape and complexity of the part.
The paint being sprayed and its amenability to
spraying.
The type, method of operation, maintenance history and
wear level of the spray equipment.
Numerous operating parameters such as the spray booth
ventilation rate, the gun to part distance and the spacing
of parts on the conveyor.
All of these potential variables mean that you have to test
to determine transfer efficiency. You cannot guess or presume
that a particular type of spray gun will achieve a particular
£79
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transfer efficiency. The large number of variables which are
unrelated to the spray gun itself precludes any direct
correlation between transfer efficiency and the type of spray
gun. A wide range of transfer efficiencies is found for each
type gun, part and paint.
(SLIDE 10) - When can transfer efficiency vary? The short
answer to this question is frequently.
At an individual facility, transfer efficiency can vary:
From part to part as the size, shape and complexity of
the part changes.
From paint to paint as the amenability of the paint to
spraying changes.
From person to person as the skill, technique and
fatigue level of the operator changes, and as the level of
maintenance and control over automatic equipment changes.
Transfer efficiency also varies from plant to plant. Two
plants using the same spray guns and the same paint to coat the
same parts can achieve very different transfer efficiencies.
This means that testing must be done frequently or
continuously, especially if there are frequent changes in the
size and shape of the parts being coated and the coatings being
used. As noted earlier, these types of changes occur frequently
in each of the 3 spray coating industries that will be discussed
at this meeting.
(SLIDE 11) - Another important factor that needs to be
accounted for if transfer efficiency is to be quantitatively
considered in regulatory guidance is establishing a baseline
transfer efficiency for a source category. A baseline transfer
efficiency is most simply thought of as the transfer efficiency
that can be reasonably expected when reasonably available (RACT)
coatings are used.
It is difficult to establish meaningful baseline transfer
efficiency values for an industry when many different size and
shape parts are coated. An appropriate baseline for a hard-to-
coat part may be too low for an easy-to-coat part. An
appropriate baseline for an easy to coat part may be impossible
to achieve on a hard to coat part.
Similarly it is difficult to establish meaningful baseline
transfer efficiency values for an industry where many different
types of coatings are used. Each type of coating may be
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processed (sprayed) differently, so each type of coating could
require a different baseline value.
As noted previously, each of the 3 predominantly spray
coating industries we are discussing at this meeting coat many
different size and shape parts and use many different coatings.
(SLIDE 12) - Because of the complexities which yield
frequent variation in transfer efficiency, require frequent
testing to determine transfer efficiency and make setting
baseline transfer efficiency values difficult, we do not plan to
recommend quantitative consideration of transfer efficiency in
the CTGs for these 3 industries. This means we do not plan to
recommend separate minimum transfer efficiency requirements such
as 50 percent or 65 percent. This also means that we do not plan
to recommend coating emission limits which directly incorporate
transfer efficiency, for example limits expressed in units of
pounds of VOC per gallon of coating solids deposited.
(SLIDE 13) - We are giving some consideration to equipment
requirements; for example we could recommend that the use of air
spray be restricted or prohibited. We believe this would be
directionally correct, but it may be difficult to enforce and
certainly it would be difficult to assess the amount of reduction
that could be credited to a State's or local area's attainment
plan.
(SLIDE 14) - Even if transfer efficiency is not part of our
guidance, there are many market and economic incentives for
coaters to improve transfer efficiency- There is the potential
for cost savings resulting from reduced paint usage, reduced
solid waste disposal and easier spray booth clean-up. There
could also be lower permit fees since with better transfer
efficiency the same work can be done at a lower level of
emissions. Similarly, improving transfer efficiency can help to
reduce the level of offsets needed for a new facility. Also with
regard to permits, improving transfer efficiency can allow for
more production under a fixed emission cap since more work can be
done with the same amount of paint while maintaining the same
level of emissions.
We expect to note in each CTG the various types of spray
equipment that are available, their potential to reduce paint
usage and other possible advantages of their use.
This concludes my presentation on transfer efficiency. I
would be happy to answer any questions.
£81
-------
TRANSFER EFFICIENCY AND
REGULATORY GUIDANCE FOR
SPRAY COATING OPERATIONS
NAPCTAC
NOVEMBER 20-21, 1991
-------
WHY WE DO NOT PLAN TO RECOMMEND
QUANTITATIVE CONSIDERATION OF
TRANSFER EFFICIENCY
-------
IDENTIFY SPRAY COATING
- INDUSTRIES
- EQUIPMENT
DISCUSS TRANSFER
EFFICIENCY (TE)
- DEFINITION
- IMPORTANCE
- COMPLEXITIES
-------
CURRENT CTG PROJECTS
• PLASTIC PARTS
• WOOD FURNITURE
• AUTO REFINISHING
-------
TYPES OF SPRAY EQUIPMENT
AIR
AIRLESS
AIR ASSISTED AIRLESS
HIGH-VOLUME LOW-PRESSURE (HVLP)
ROTARY ATOMIZERS
ELECTROSTATIC
NON-ELECTROSTATIC
MANUAL
AUTOMATIC
-------
TRANSFER EFFICIENCY (TE)
SOLVENT (VOC)
COATING =
SOLIDS
TE =
SOLIDS DEPOSITED
SOLIDS USED (SPRAYED)
'•8'
6
-------
WHY IS TE IMPORTANT?
PAINT USE AND COST
VOC
SOLID WASTE
OTHER OPERATING COSTS
-------
100
3(0)
60
ILJ
co CO
cs
30
5(2)
10(7)
15
20 (17)
- GALLONS COATING USED
(GALLONS COATING WASTED)-
-------
WHAT AFFECTS TE?
OPERATOR
PART
PAINT
SPRAY EQUIPMENT
NUMEROUS OPERATING
PARAMETERS
- SPRAY BOOTH
VENTILATION
- GUN TO PART DISTANCE
- PART SPACING ON
CONVEYOR
-------
WHEN CAN TE VARY?
PART TO PART
PAINT TO PAINT
PERSON TO PERSON
PLANT TO PLANT
10
-------
BASELINE TE
DIFFICULT TO ESTABLISH
MEANINGFUL BASELINE
VALUES WHEN
» MANY DIFFERENT
SIZE/SHAPE PARTS ARE
COATED
» MANY DIFFERENT TYPES OF
COATINGS ARE USED
'•S2
-------
DO NOT PLAN TO RECOMMEND I
SEPARATE MINIMUM TE
REQUIREMENTS
COATING EMISSION LIMITS
WHICH DIRECTLY
INCORPORATE TE
:S
12
-------
EQUIPMENT REQUIREMENTS ARE
A POSSIBILITY
EXAMPLE: PROHIBIT OR
RESTRICT USE OF AIR SPRAY
13
-------
MARKET AND ECONOMIC
INCENTIVES TO IMPROVE TE
COST SAVINGS - PAINT
- SOLID WASTE DISPOSAL
- SPRAY BOOTH CLEAN-UP
- PERMIT FEES
PERMITS
MAXIMIZE PRODUCTION
UNDER EMISSION CAP
MINIMIZE LEVEL OF
OFFSETS NEEDED
', CC
^ «J ,j
14
-------
After Ms. Wyatt completed her presentation, NAPCTAC members
were provided an opportunity to ask questions.
Mr. Ralph Hise asked why EPA is not developing a CTG for
POTW's. Ms. Wyatt explained that control of emissions from POTW's
are indirectly reduced through controls applied through the
industrial wastewater CTG.
Mr. William J. Dennison asked how marketplace incentive
programs interrelate with the CTG's. Mr. Bruce Jordan replied that
States have flexibility as long as equivalency to RACT is attained.
Ms. Vivian Mclntire expressed concern that sufficient time
needs to be provided in the State Implementation Plan process so
that people have an opportunity to apply for case-by-case RACT
determinations.
-------
DISCUSSION ON TRANSFER EFFICIENCY PRESENTATION
QUESTION (Ms. Sheiman) - Could you provide some perspective
on how you have set standards in the past for similar industries?
I recall that some state RACT regulations have the transfer
efficiency concept in them and I presume that the idea for this
came from EPA.
RESPONSE (Mr. Salman) - There is a long history to this
going back to the CTGs we did in 1977 and 1978. Some states do
have transfer efficiency considered in their regulations. For
example, some regulations in California have a minimum transfer
efficiency requirement of 65 percent which is deemed to be met if
you use certain specified types of equipment. We are concerned
about this because there is no guarantee that 65 percent is
really achieved. This can lead to two sets of books with
differences between actual and calculated emission rates.
Some states have become frustrated with dealing with
transfer efficiency. New York, for example, took transfer
efficiency out of its regulation a few years ago.
The one area in RACT regulations where there is widespread
use of transfer efficiency is for certain operations at
automobile assembly plants. We did a lot of work from 1985 to
1988 to establish a specific test procedure and methodology for
determining when to retest. The paint shop in an automobile
assembly plant is very complex, but they coat the same product
every day for a long time. The industries we are dealing with at
this meeting change parts and paints much more frequently.
QUESTION (Ms. Sheiman) - Without some kind of numerical
standard for transfer efficiency how will we be sure to get some
emission reduction?
RESPONSE (Mr. Berry) - We propose to write guidance that
ignores transfer efficiency and to get emission reduction in
other ways. We feel you cannot measure transfer efficiency. If
a rule is written based on transfer efficiency, then the
opportunity is created for people to mask real reductions.
QUESTION (from committee) - By regulating solvent content of
coatings?
RESPONSE (Mr. Berry) - That's one way.
QUESTION (from committee) - There are other alternatives?
-------
RESPONSE (Mr. Berry) - That is true.
QUESTION (Mr. O'Sullivan) - The chart shoes that transfer
efficiency is important. If we ignore it then we may be ignoring
something that is a very useful emission reduction technology.
My question is if EPA does not set specific numerical transfer
efficiency requirements, does EPA expect the states to set them
or would equipment standards be acceptable?
RESPONSE (Mr. Berry) - We do not expect the states to do
what we have not been able to figure out how to do?
QUESTION (Mr. O'Sullivan) - The states have to develop SIPs
and they want emission reductions and credit for those emission
reductions. Is there any mechanism by which states can take
credit for transfer efficiency improvements in their annual
emission reduction projections?
RESPONSE (Mr. Salman) - That is a good question and it has
already been asked of us by California. They also wanted to know
if there was some way to take credit for improvements in transfer
efficiency in their plans on an area or industry basis when there
was no specific numerical requirement in the regulation.
(Mr. Berry) - We are not sure how this will play out. It is
like trying to measure the soul. It is hard to get your hands on
this issue, we have tried for a long time .
QUESTION (audience) - Aren't there methods for measuring
transfer efficiency. For example, measuring film build and
surface area coated, or the weight gain of coated parts. These
must give some approximation of transfer efficiency. Or maybe
measuring the amount of paint waste. What methods have been
used?
RESPONSE (Mr. Salman) - The first two methods you mentioned
have been used to determine how much paint was put on the parts,
film build and surface area, and weight gain of coated parts.
Short term transfer efficiency tests have been done using one of
these methods to determine how much paint was put on the part and
measuring paint usage to determine the amount of solids sprayed.
The problem is how much and how often to test when the parts
coated and coatings used are constantly changing. You could wind
up having to test all the time. The concept is simple in the
short term. It may be disruptive or expensive to do a short term
test, but it has been done. If the parts or coatings change all
the time, then you have to test almost constantly and we have
never seen this done.
QUESTION (Mr. Dennison) - You also have to factor in the
constant turnover in who does the spraying. The person you see
one time may not be there next time. This would affect transfer
efficiency too.
-------
RESPONSE (Mr. Berry) - True, and the presence of a transfer
efficiency testing crew can affect the performance of the
sprayers. Sprayers may react to having people with clipboards
watching them do their job.
QUESTION (audience) - From a regulatory standpoint you
should be able to do something with records. For example,
looking at how much paint was used and what was coated in a month
or a day.
RESPONSE (Mr. Berry) - We would do that if we thought it
would work. The labor and the resources are not there to keep
all the necessary records on area coated and film build. The
records could be awesome. It could be done, but a lot of
sophistication would be needed and it would be very difficult to
do continuously.
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY PRESENTATION
ON SURFACE COATING OF PLASTIC PARTS CONTROL
TECHNIQUES GUIDELINE
Slide 1. This presentation covers the development of a CTG
for surface coating of plastic parts. These are the topics
covered in the presentation.
First, the industry, coating process, and emissions will be
described, and then the approach to developing and analyzing
control options will be described. This will include separate
analysis for each of two different sectors of the plastic parts
coating industry—the automotive and the business
machine/miscellaneous sectors.
Implementation of the control options will be described, and
last, I'll cover particular areas where EPA would like comment.
Slide 2. For the purpose of developing the CTG, the
industry was initially divided into three segments, as shown
here, automotive, business machines, and miscellaneous—
(emissions estimates for the industry segments will be presented
in a following slide).
The business machine and miscellaneous segments were
eventually combined for analysis, because the substrates and
coatings used are similar, and control options could be set for
these parts as a single category.
The coating facilities covered by the CTG are either in-
house processes at the "end product" manufacturing site,
contractors specializing in molding and coating particular parts,
or job-shops performing coating only.
Under the automotive sector, the CTG covers interior and
exterior plastic components of automobiles, trucks, tractors,
lawn mowers, and other mobilized equipment.
The Business Machine segment includes plastic housings for
the products listed here—computers and other business machines,
thinks like TV's and small appliances, and medical equipment.
Miscellaneous Plastic Parts is a broad category, covering a
diverse array of products. The ones listed here are examples of
some of the products that fall within this category. An area
where EPA is particularly interested in comment concerns
miscellaneous plastic parts. We would welcome information on
particular products that may have unusual coating specifications,
or may otherwise be considered outliers to the miscellaneous
category- As I have explained, this category was combined with
business machines for developing control options.
LGO
-------
Slide 3. These are the general categories of coatings used
to coat plastic parts: For automotive parts there are different
coatings for interior parts versus exterior parts, and exterior
parts are further divided into flexible and non-flexible parts,
which also require different coatings.
Examples of specialty coatings are:
adhesion promoters used on some substrates, or
glare reducers used on interior parts such as dash
boards.
Under Business Machines Coatings these again are general
categories; EMI stands for electro magnetic interference; and RFI
stands for radio frequency interference.
Shielding coatings act to prevent stray signals from
affecting performance of machines.
Slide 4. This is a schematic drawing of a typical coating
line, it shows a series of three spray booths with flash-off
areas between. Flash-off areas are where initial drying and
evaporation of volatiles occur.
There may be ovens between booths, or just at the end of the
line; or there may be no oven where air-dry coatings are used in
the case of temperature sensitive plastics.
Some lines are conveyorized. On some lines parts are hand
carried from one area to the next.
VOC Emissions occur in all three areas — booths, flash-off,
and ovens. Spray booths are clearly where the majority of
emissions occur—about 80 percent. Ten percent occurs in the
flash-off areas, and the remaining 10 percent in the ovens. If
no ovens are present, that 10 percent is emitted during flash-
off.
Slide 5. Here we show estimated industry-wide emissions for
the two industry segments. These estimates are based on facility
counts found in supporting documents for State regulations and
the Business Machine NSPS, combined with employment statistics
for non-attainment areas.
The emission rates were developed using the model facilities
that I'll describe in some following slides. We don't have
emission estimates for the miscellaneous sector alone, but it
accounts for about 5 percent of the industry, and it's assumed
here that the 5500 tpy is representative of both miscellaneous
and business machine coating emissions.
These numbers are estimates; there are no inventories
available, but they reflect our best judgement as to the current
industry emissions.
Slide 6. Demonstrated VOC controls for the industry are
shown here: First, under Pollution Prevention technologies, are
lower VOC content coatings. Lower VOC content can be achieved
using either waterborne coatings, or higher solids content
coatings.
Waterborne and higher solids coatings are both currently in
use for a variety of applications. For business machine
applications, waterborne coatings are less common than solvent
-------
borne coatings; for automotive applications, waterborne coatings
have been used more for interior parts than exterior. Again
solvent borne coatings are still more commonly used.
Higher solids coatings are reportedly being used to a
greater extent than waterborne for both automotive and business
machine/miscellaneous applications.
Under Add-on Control Technologies, thermal incineration and
carbon adsorption are included, controlling exhaust streams from
spray booths and ovens.
Slide 7. I'll describe the control options and model plant
analysis separately for two industry segments. First will be the
automotive. These are the control options considered for the
Automotive Sector. On the left side are the coating categories
for which options were developed. There may be reasons to
develop additional options for red and black coatings due to the
particular needs of some red and black pigments. EPA is
currently studying this subject.
Across the top of the table are the baseline and three
control options, in Ibs of VOC per gallon of coating, less water.
Note that while 1 and 2 are coating reformulation options,
control option 3 is use of add-on controls. We have listed here,
for comparison, the equivalent VOC content that achieves the same
emission reductions as incineration.
Options 1 and 2 represent the range of VOC contents reported
by coaters and coating manufacturers. The baseline represents a
level readily achievable by approximately 90 percent of the
coatings reported by coaters and coating manufacturers.
Control Options 1 and 2 reflect levels that would achieve
substantial emission reductions. Option 1 is demonstrated by
several coatings per category; Option 2 is also demonstrated, but
by fewer coatings and fewer coating manufacturers. Generally,
the difference between Option 1 and Option 2 is the number of
suppliers of coatings meeting the VOC level.
One note on the VOC levels under Option 2: for exterior
flexible clearcoats, we have received some comments recently
suggesting that the 3.5 Ibs of VOC per gallon of coating is not
readily available. We expect further input and some further
investigation on these coatings.
Slide 8. This table shows the model plants developed for
analysis of control options for the automotive segment. Four
plant sizes were developed, with various combinations of process
lines. We used three plants of each size, one each coating
interior parts, exterior flexible parts, and exterior non-
flexible parts, for a total of 12 model plants. The model plant
parameters are based on responses to questionnaires and several
site visits.
Slide 9. The results of the automotive model plant analysis
are shown here.
For each control option, the range of emission reductions
for all model plants, in TPY and percent, is shown, as are the
ranges of annual control costs and the percent increase in annual
-------
paint costs. Additional paint cost figures show the increase in
cost over baseline.
I would point out that the broad range of percent emission
reductions, in the second column, is due to differences in the
coatings types used in each plant, rather than the plant size
differences.
And the last column shows the cost effectiveness for each
option. Again, these are ranges covering all four sizes of model
plant. The cost effectiveness figures for Options 1 and 2 are
roughly comparable. Note that, though there is substantial
increase in emission reductions using Option 3, incineration,
there is a disproportionately large increase in costs as well;
this is, of course, reflected in the cost effectiveness figures.
It should be noted that these incineration costs are for
facilities using conventional spray booths that have not been
engineered to minimize costs of abatement. If for example, the
waste stream is recirculated to increase the VOC concentration,
the cost effectiveness figures would decrease.
Slide 10. Now, for the business machine/miscellaneous
options and analysis: These are the VOC control options
developed for the business machine/miscellaneous segment. These
options reflect the same level of demonstration as the automotive
options; and again, the column for Option 3 shows VOC levels that
achieve emission reductions equivalent with incineration.
Slide 11. The model plants for the business machine/
miscellaneous segment include three sizes, again developed based
on information collected from questionnaires and site visits.
One model plant was developed for each size category, each model
plant performing similar coating processes.
These three business machine/miscellaneous model plants,
combined with the 12 automotive model plants gives us a total of
15 model plants.
Slide 12. The results of the business machine/miscellaneous
model plant analysis are shown here. As for the automotive model
plants, we show ranges of emission reductions, annual costs, and
additional annual paint costs for each option. Again, the ranges
cover the three different model plant size categories.
Cost effectiveness figures for Options 1 and 2 are roughly
comparable; while the cost effectiveness of incineration is quite
a bit higher. Again, these costs for incineration reflect use of
conventional spray booths that have not been engineered to
minimize costs of abatement.
Slide 13. The national impacts of the three options for
both automotive and business machine/miscellaneous sectors have
been estimated — these impacts are shown here.
For the automotive sector, reductions range from 12,000 tpy
under Option 1 to 35,000 tpy under Option 3 with associated costs
ranging from $8 million/year for Option 1, to $770 million/year
for Option 3.
-------
For business machine/miscellaneous, emission reductions
range from 2500 hundred tpy to 5000 tpy and costs range from
$1 million/year to $106 million/year.
Slide 14. Compliance with the VOC control technologies
would be demonstrated as shown here.
Coaters using lower VOC content coatings would maintain
records of Method 24 tests for VOC content of all coatings used,
and would also keep records of quantities of coatings used.
Using add-on controls, the coaters would report results of
performance tests, and maintain records of control device
monitoring.
Slide 15. These are a few issues that are Currently
undergoing investigation. EPA has solicited comment in the
NAPCTAC mailout on these issues in particular.
First of all, EPA is looking into the availability and
costs of waterborne shielding coatings.
Some initial comments on the control options for
business machine color coats and color texture coats
suggest that they may be too stringent; EPA is looking
into these coatings further, as well.
Air dry coatings are given less stringent VOC levels in
some state regulations. As you have seen, our control
options do not recognize air dry coatings as a separate
category; so we are investigating temperature
sensitivity of certain substrates.
And last, the miscellaneous plastic parts category, as
I have described, is very diverse. We have collected
information on products falling into this category, and
feel that the proposed options are appropriate for
miscellaneous plastic parts; but we would like comments
regarding this point.
-------
CONTROL TECHNIQUES GUIDELINE
CONTROL OF VOLATILE ORGANIC COMPOUNDS
FROM SURFACE COATING OF PLASTIC PARTS
NAPCTAC MEETING PRESENTATION
NOVEMBER 1991
-------
OUTLINE OF PRESENTATION
• INDUSTRY AND PROCESS DESCRIPTION
• EMISSIONS
• CONTROL OPTIONS AND ANALYSIS
AUTOMOTIVE
BUSINESS MACHINES/MISCELLANEOUS
• IMPLEMENTATION
• AREAS FOR COMMENT
-------
INDUSTRY DESCRIPTION
1. AUTOMOTIVE AND OTHER TRANSPORTATION PARTS
• AUTOMOBILE PARTS (FASCIA, BUMPERS,
DASHBOARDS)
• TRACTORS, MOWERS
• EXCLUDES MARINE COATING
2. BUSINESS MACHINES AND ELECTRONICS
• COMPUTERS
COPY MACHINES
• MISCELLANEOUS OFFICE EQUIPMENT
ENTERTAINMENT EQUIPMENT (RADIOS,
RECORDERS, TELEVISIONS)
<
• SMALL HOUSEWARE AND PERSONAL APPLIANCES
• MEDICAL EQUIPMENT
3. MISCELLANEOUS PLASTIC PARTS
• TOYS
• WINDOW FRAMES
• SPORTING GOODS
-------
COATING TYPES
AUTOMOTIVE
• PRIMER
TOPCOAT
BASECOAT/CLEARCOAT, OR
STAND-ALONE COLORCOAT
CLEARCOAT
SPECIALTY
BUSINESS MACHINE/MISCELLANEOUS
PRIMER
COLORCOAT
COLOR/TEXTURE COAT
EMI/RFI SHIELDING
o,,3
, B
-------
cc
Oven
Finished
Product
Flash-Off Area
Clearcoat/Texture
Booth
Oven
^ * ^
Prime Booth
N
Flash-Off Area
* * >
uoior Booth
Flash-Off
Area
Typical Conveyorized Coating Line for Three-Coat Systems
-------
INDUSTRY VOC EMISSIONS
IN NONATTAINMENT AREAS
AUTOMOTIVE - 38,000 TRY
340 FACILITIES IN NONATTAINMENT AREAS
BUSINESS MACHINES/MISCELLANEOUS - 5500 TRY
250 FACILITIES IN NONATTAINMENT AREAS
10
-------
VOC CONTROL TECHNOLOGIES
POLLUTION PREVENTION
LOWER VOC CONTENT COATINGS
WATERBORNE
HIGHER SOLIDS
ADD-ON CONTROL
THERMAL INCINERATION (98% EFFICIENCY)
CARBON ADSORPTION (95% EFFICIENCY)
-------
VOC CONTROL OPTIONS FOR AUTOMOTIVE SECTOR
(IBS. VOC/GAL. COATING)
AUTOMOTIVE INTERIOR
• COLORCOAT
• PRIMER
AUTOMOTIVE EXTERIOR
• FLEXIBLE
COLORCOAT
CLEARCOAT
PRIMER
• NONFLEXIBLE
COLORCOAT
CLEARCOAT
PRIMER
BASELINE
6.3
5.5
4.6
4.3
5.4
4.6
4.3
5.0
OPTION 1
LOWER VOC
5.0
3.5
4.3
3.8
5.0
4.3
3.8
4.5
OPTION 2
LOWER VOC
3.2
3.5
4.1
3.5
4.5
4.1
3.5
3.5
OPTION 3
INCINERATION
0.6
1.2
0.7
0.5
1.0
0.7
0.5
0.8
-------
PARAMETERS FOR AUTOMOTIVE MODEL PUNTS
MODEL PLANT SIZE
1 . SMALL
2. MEDIUM
3 . LARGE
4. EXTRA LARGE
CAPACITY
(GAL. COATING/YEAR)
12,000
27,000
98,000
300,000
SPRAY BOOTHS
(CONVEYOR)
0
3
6
16
SPRAY BOOTHS
(No CONVEYOR)
3
2
3
4
00
CO
-------
AUTOMOTIVE MODEL PLANT ANALYSIS
OPTION
1
2
3
(INCINERATION)
EMISSION
REDUCTION
RANGE
(TONS/YR)
6 TO 642
10 TO 783
22 TO 897
EMISSION
REDUCTION
RANGE (%)
21 TO 70
35 TO 86
78 TO 98
ANNUAL
CONTROL
COST
(1000$/YR)
3.6 TO 430
6 TO 536
503 TO
18,800
%
INCREASE
IN ANNUAL
PAINT
COST*
2.8 TO
4.9
4.5 TO
6.1
68 TO 82
COST
EFFECTIVENESS
($/TON
REDUCTION)
600 TO 669
571 TO 685
7,000 TO
28,000
*FOR OPTION 3, TOTAL ANNUAL COSTS FOR ADD-ONS ARE CONSIDERED THE ADDITIONAL
COATING COSTS.
-------
VOC CONTROL OPTIONS FOR BUSINESS MACHINES/MISCELLANEOUS SECTOR
(LBS. VOC/GAL. COATING)
• COLORCOAT
• COLORCOAT/
TEXTURE COAT
• PRIMER
• EMI/RFI SHIELDING
BASELINE
4.8
4,8
4.5
4.9
OPTION 1
LOWER VOC
3.5
3.5
2.9
4.0
OPTION 2
LOWER VOC
2.3
2.3
1.2
2.5
OPTION 3
INCINERATION
1.4
1.4
1.2
1.5
o
I
en
-------
PARAMETERS FOR BUSINESS MACHINES/MISCELLANEOUS MODEL PUNTS
MODEL PLANT SIZE
1 . SMALL
2. MEDIUM
3 . LARGE
CAPACITY
(GAL. COATING/YEAR)
5,000
41,000
103,000
SPRAY BOOTHS
(CONVEYOR)
0
3
6
SPRAY BOOTHS
(No CONVEYOR)
2
2
3
-------
BUSINESS MACHINES/MISCELLANEOUS MODEL PLANT ANALYSIS
OPTION
1
2
3
EMISSION
REDUCTION
RANGE
(TONS/YR)
6 TO 123
10 TO 191
11 TO 217
EMISSION
REDUCTION
RANGE (%)
50
79
89
ANNUAL
CONTROL
COST
(1000$/YR)
2.9 TO 58
5 TO 98
373 TO 1,487
%
INCREASE
IN ANNUAL
PAINT
COST*
1.4
2.4
27 TO 65
COST
EFFECTIVENESS
($/TON
REDUCTION)
470
492 TO 518
6,800 TO 34,000
rsi
*FOR OPTION 3, TOTAL ANNUAL COSTS FOR ADD-ONS ARE CONSIDERED THE ADDITIONAL
COATING COST.
-------
NATIONAL IMPACTS
CONTROL
OPTION
NATIONAL
EMISSION
REDUCTION
(TONS/YR)
NATIONAL
COSTS
(106 $/YR)
COST
EFFECTIVENESS
$/TON
AUTOMOTIVE
1
2
3
12,000
18,500
35,000
8
12
770
660
650
2200
BUSINESS MACHINES/MISCELLANEOUS
1
2
3
2,500
4,000
5,000
1
2
106
400
500
2100
TOTAL
1
2
3
14,500
22,500
40,000
9
14
876
620
620
2200
13
-------
IMPLEMENTATION
COMPLIANCE/RECORDKEEPING
CONTROL TECHNOLOGY
COMPLIANCE
LOWER VOC
COATINGS
• RM24 TESTS FOR VOC CONTENT
• RECORDS OF QUANTITY USED
ADD-ON CONTROLS
• PERFORMANCE TESTS
• CONTROL DEVICE MONITORING
14
-------
AREAS FOR COMMENT
COST AND AVAILABILITY OF WATERBORNE SHIELDING
COATINGS FOR BUSINESS MACHINES
• BUSINESS MACHINE COLORCOAT AND COLOR/TEXTURE
COAT CONTROL OPTIONS
AIR DRY COATINGS FOR TEMPERATURE-SENSITIVE
AUTOMOTIVE PLASTICS
MISCELLANEOUS PLASTIC PARTS CATEGORY
15
r>
, • i
-------
NAOMI SUSS, PPG INDUSTRIES, REPRESENTING THE
NATIONAL PAINT AND COATINGS ASSOCIATION
Summary of Naomi Suss' Presentation
The NPCA presentation began with the qualification that it
would only address the Automotive/Transportation portion of the
CTG. It continued with a discussion of the driving forces that
have led to the increasing use of plastic parts in the automotive
industry. The primary reasons for their use were noted to have
been reducing vehicle weight to improve fuel economy, the United
States' concern over potential loss of chrome-producing materials
imported from South Africa and the Soviet Union, and the ease
with which frequent design changes could be accommodated by using
plastic rather than metal in fabricating panels and other parts.
The NPCA then provided a discussion of figures for high bake
and low bake coatings sold in North America in 1990. The total
reported volume was 6,475,500 gallons. It was explained that
high bake and low bake coatings are distinguished according to
whether they cure at temperatures above 194°F (high bake) or at
or below the temperature of 194°F (low bake); the distinction of
high bake and low bake coatings is required due to the
temperature sensitivity of certain plastic substrates. The
coatings represented in the 1990 sales data were further
categorized according to their functions (primer, clear coat,
touch-up, etc.).
The first two concerns expressed by the NPCA were that the
CTG did not distinguish between high and low bake coatings, and
that specific coating-types that accounted for 41 percent of the
1990 volume were not separately recognized in the study. The
lack of consideration for additional breakdowns of coating-types
was noted to be inconsistent with Michigan's State Rule No. 632
which NPCA considers to be a well-developed regulation.
As the presentation proceeded, the specific needs of red and
black coatings were mentioned. First, the NPCA said that color-
matching between plastic and metal parts is important. And
second, the NPCA gave technical reasons for the allowance of
higher VOC contents in red and black coatings. With the smaller
particle size of red and black pigments (solids) and the need for
thicker film on some black or red parts, higher molecular weight
resins are required for adequate dispersion and the prevention of
re-agglomeration of pigment. The viscosity of red and black
coatings is therefore higher, and more solvent is required for
their use. The NPCA stated that this situation is a critical
impasse for VOC reduction and needs to be recognized. The NPCA
521
-------
also acknowledged that Michigan allows a scaling factor of 1.15
to be used for determining the allowable VOC contents for red and
black coatings, as compared to other colors. Also noted was the
problem of opacity which occurs when black primer tends to
produce a graying effect on the color of the topcoat.
The next point of discussion was the use of Method 24
testing. The NPCA advocated the use of provisions, as in
Michigan's rule, which differentiate between theoretical VOC
content and the VOC content determined by Method 24. When
Method 24 is used to determine the VOC content of high bake
coatings, the VOC limit is increased by 0.5 Ibs per gallon; for
low bake coatings, the VOC limit is increased by 0.1 Ibs per
gallon.
The importance of plastic part function and density were
presented. It was noted that some parts cannot be subjected to
oven temperatures for curing the coatings without losing their
structural integrity. Higher VOC content coatings must be used
for these parts so that adequate cross-linking of the coating may
be obtained without the use of heat in the curing process. The
national usage of such coatings (e.g., air dry primer, 6.1
Ibs/gal) was said to be small.
The NPCA noted that touch-up and repair coatings, used in
small quantities when coated parts are damaged during production,
currently meet or exceed their applicable specifications in the
Michigan regulation.
In an overview of Table 66, from Michigan's State rule, the
NPCA made the following statements. The regulation is technology
forcing, and coatings meeting all of the levels are not yet in
existence. Also, the conditions in the footnotes on the table
still apply to red and black coatings and Method 24 test data.
The next portion of NPCA's presentation included projected
sales figures for coatings of various VOC contents for 1992 and
1995, with the sales volume held constant at the 1988 level.
Also presented were estimated levels of VOC emissions from
automotive coating applications in 1988, 1992, and 1995. By
instituting Michigan Rule No. 632 on a national basis, NPCA
predicted a 15 percent emission reduction by 1992 and a
25 percent reduction by 1995 could be achieved. Because NPCA
felt this study was based on conservative data and assumptions,
even greater reductions could be anticipated.
Turning the focus of the presentation specifically to the
CTG, the NPCA stated the following concerns. Not enough
categories of coating-types were present. Categories should be
made for monocoats as well as for coated parts which have
specifically mandated safety and functional requirements like
headlights, air bag covers, etc. Allowances for low-use,
specialty coatings, such as for polycarbonates for headlight
522
-------
lenses, vacuum-metalizing, stenciling, appliques, and adhesion
promoters, should be made. The NPCA noted an expected increased
usage of adhesion promoters, the highest volume specialty
coatings, which are used for thermoplastic olefin (TPO)
(polypropylene) bumpers. Also, data on this trend may be made
available. The NPCA stated that, due to the low usage of these
specialty coatings, the cost of reformulation would be a major
concern; thus, it was suggested that these coatings be allowed
less stringent VOC content levels. The origin of the baseline
VOC content values in Table 5.1 was not evident. Those baseline
values were not reflected in the model plants. Option 2 VOC
contents are not now available; a more realistic year for their
availability may be 1995. The evaluation of surface coatings as
systems is complex and was overlooked. No flexible clearcoats
that meet the level of 3.5 pounds of VOC per gallon of coating
are available.
The NPCA expressed displeasure with generally all of the
levels; using Table 65 of Michigan's rule for Option 1 and
Michigan's 1992 values for Option 2 was recommended. However, it
was suggested that red and black coatings be treated separately
rather than providing a scaling factor for them. Also, monocoats
were suggested to be evaluated separately.
Finally, the NPCA agreed with the presentation on transfer
efficiency, given earlier by Dave Salman of EPA. The NPCA said
that although TE is difficult to quantify, coaters will not be
able to afford using less efficient equipment due to the costs
associated with wasting paint. Because better equipment would
conserve paint, NPCA would expect lower VOC emissions. After
these remarks, the NPCA concluded its presentation and took
questions from the NAPCTAC committee.
523
-------
SURFACE COATING OF PLASTIC PARTS
CONTROL TECHNIQUES GUIDELINE
cn
ro
National
Paint &
Coatings
'Association
COMMENTS
NOVEMBER 20,1991
-------
Automotive Plastic Parts Coatings
Total Volume - 6,475,500 Gallons
HBBasecoats13%
HBCIearcoats14% ^^^^^^^
HB Rigid Prime 4%
tn
ro
HBMonocoats12%
LB Basecoats 2%
LB Clearcoats 4%
LB Prime 1%
Interior 20%
Michigan's Rule 632 Categorization
HB - High Bake
LB - Low Bake
HB Flex Prime 8%
LBMonocoats16%
Touch Up/Repair 2%
Specialty 4%
-------
Automotive Plastic Parts Coatings
Total Volume - 6,475,500 Gallons
Category
Interior
Low Bake Prime
High Bake Flex Prime
High Bake Rigid Prime
High Bake Basecoats
High Bake Clearcoats
High Bake Monocoats
Low Bake Basecoats
Low Bake Clearcoats
Low Bake Monocoats
Touch Up & Repair
Specialty Coatings
Value
1309.3
45.8
544.3
255.7
816.4
918.8
812.6
152.1
261.9
1023.1
105.0
230.5
%_
20
1
8
4
13
14
13
2
4
16
2
4
In 1000 gallon increments.
526
-------
Automotive Plastic Parts Coatings
Coatings not Recognized in CTG Draft
HBBasecoats13%
HBCIearcoats14%
HB Rigid Prime 4%
en
ro
HB Monocoats 12%
LB Basecoats 2%
LB Clearcoats 4%
LB Prime 1 %
Interior 20%
Michigan's Rule 632 Categorization
HB - High Bake
LB - Low Bake
HB Flex Prime 8%
LBMonocoats16%
Touch Up/Repair 2%
Specialty 4%
-------
Categories not Recognized in CTG Draft
Category
High Bake Monocoats
Low Bake Basecoats
Low Bake Prime
Low Bake ClearcoatS
Low Bake Monocoats
Touch Up & Repair
Specialty Coats
Total Value
Volume
% Total Volume
812.6
152.1
45.8
261.9
1023.1
105.0
230.5
12.6
2.0
0.7
4.0
15.7
2.0
^0
2631.
41.0
Data From Chart 2 with Data for Above Categories Take Out.
In 1000 gallon increments.
528
-------
Red & Black Coatings
As a Percentage of Total Color Coats
HB R&B Basecoat 4%
HB Monocoats 23%
en
10
HB R&B Monocoat 6%
LB Basecoats 5%
LB R&B Basecoat 0%
LB Monocoats 17%
Total Color Coat Volume • 2,804,200 Gallons
Total Red & Black Volume - 856,100 Gallons
HB Basecoats 25%
LB R&B Monocoat 20%
-------
Red & Black Coatings
As a Percentage of Total Color Coats
Category Volume %_
High Bake Basecoats 696.7 25
High Bake Red & Black Basecoats 119.7 4
High Bake Monocoats 634.7 23
High Bake Red & Black Monocoats 117.9 6
Low Bake Basecoats 142.8 5
Low Bake Red & Black Basecoats 9.3 0
Low Bake Monocoats 473.9 17
Low Bake Red & Black Monocoats 549.2 20
530
-------
6-41
Table 65
Volatile organic compound emission limitations for existing
automobile and truck plastic parts coating lines after 12/31/89
Operation
Pounds of volatile organic compounds
allowed to be emitted per gallon of
coating (minus water) as applied
1. High bake coating-
exterior and interior parts
CD (2;
(a) Prime
(i) Flexible coating
(ii) Nonflexible coating
(b) Topcoat
(i) Basecoat
(ii) Clearcoac
(iii) Non-basecoat/clearcoat
2. Air-dried coating—exterior parts
(a) Prime
(b) Topcoat
(i) Basecoat
(ii) Clearcoat
(iii) Non-basecoat/clearcoat
3. Air-dried coating—interior parts
4. Touch-up and repair
(3)
(3)
5.0
4.0
4.6
4.3
4.7
6.1
5.8
5.4
6.3
6.3
6.3
FOOTNOTES:
(1) For red and black coatings, the emission limitation shall be determined by multiplying
the appropriate limit in this table by 1.15.
(?) When method 24 is used to determine the volatile organic compound content of a coating,
the applicable emission limitation shall be determined by adding 0.5 to the appropriate
limit in this table.
(3) When method 24 is used to determine the volatile organic compound content of a coating,
the applicable emission limitation shall be determined by adding 0.1 to the appropriate
limit in this table.
531
-------
(18) Table 66 reads as follows:
6-42
Table 66
Volatile Organic Compound Emission Limitations for Existing
Automobile and Truck Plastic Parts Coating Lines After 12/31/92
Operation
Pounds of Volatile Organic Compound
Allowed to be Emitted per Gallon of
Coating (minus water) as Applied
1.
High Bake Coating - Exterior and Interior Parts
tn
CO
ro
2.
a. Prime
(i) Flexible Coating
(ii) Non-Flexible Coating
b. Topcoat
(i) Basecoat
(ii) Clearcoat
(iii) Non-Basecoat/Clearcoat
Air-Dried Coating-Exterior Parts'1"31
a. Prime
b. Topcoat
(i) Basecoat
(ii) Clearcoat
(iii) Non-Basecoat/Clearcoat
3. Air-Dried Coating-Interior Parts'1"31
4. Touch Up and Repair'31
4.5
3.5
4.3
4.0
4.3
4.8
5.0
4.5
5.0
5.0
5.2
111 For red and black coatings, the emission limitation shall be determined by multiplying the appropriate limit in this table by 1.15.
121 When method 24 is used to determine the volatile organic compound content of a coating, the applicable emission shall be determined by adding 0.5
the appropriate limit in this table.
131 When method 24 is used to determine the volatile organic compound content of a coating, the applicable emission limitation shall be determined by adding
O.l to the appropriate limit in this table.
-------
GJ
COATINGS FOR AUTOMOTIVE PLASTIC PARTS
Sales
Coatings sold (1000's gallons)
1,000
0
- v
/
\ '
\
'"'B-.. \
1
1 1
1
<3.0 3.26-3.5 3.76-4.0 4.26-4.5 4.76-5.0 5.26-5.5 5.76-6.0
3.0-3.25 3.51-3.75 4.01-4.25 4.51-4.75 5.01-5.25 5.51-5.75 6.0>
VOC content (#/ga/)
1988 1995
VOC content projections based
on constant 1988 sales volume
-------
CJ1
to
COATINGS FOR AUTOMOTIVE PLASTIC PARTS
Emission of VOC in 1988, 92 & 95
#'s VOC emitted
8,000
6,000
4,000
2,000
<3.0 3.26-3.5 3.76-4.0 4.26-4.5 4.76-5.0 5.26-5.5 5.76-6.0
3.0-3.25 3.51-3.75 4.01-4.25 4.51-4.75 5.01-5.25 5.51-5.75 6.0>
VOC content (#/gaJ)
1988
1992 hi 1995
Calculations used high end of
VOC for each VOC category
GRAPH
-------
wi
CjJ
CJl
COATINGS FOR AUTOMOTIVE PLASTIC PARTS
Total Emissions of VOC In 1988, 92 & 95
total #'s VOC emitted (1000's)
35,000
30,000
25,000
20,000
15,000
Calculations used high end of
VOC for each VOC category
1988
Year
1992 1995
GRAPH II
-------
TABLE 5-1. CONTROL OPTIONS (LOW VOC COATINGS)8
Baseline*1
Control
Level 1
Control
Level 2
Number of
Database Coatings
Meeting Control
Level 2-A
Automotive Interior
ColorCoat
Primer
6.3
5.5
5.0
3.5
3.2
3.5
15
1b
Automotive Exterior
CJT
CU3
Flexible
Colorcoat
Clearcoat
Primer
4.6
4.3
5.4
4.3
3.8
5.0
4.1
3.5
4.5
68
7
3b
Non-Flexible
Colorcoat
Clearcoat
Primer
4.6
4.3
5.0
4.3
3.8
4.5
4.1
3.5
3.5
79
10
3"
* All units are in Ib VOC/gal. coating, less water, except for values in parentheses; the values in parentheses are percent solids, by volume.
b Telephone calls are being made to assess the availability of these coatings.
M What is the origin of these numbers?
-------
TABLE 5-1. CONTROL OPTIONS (LOW VOC COATINGS)'
Revised Using Rule 632 and Values fron Table 3-4
Operation Baseline VOC1 Control Level 12 Control Level
1. High Bake Coating - Exterior and Interior parts
a. Prime
(i) Flexible 6.6 5.0 4.5s
(ii) Non-Flexible 6.4 4.0 3.56
b. Topcoat
tn
CO (i) Basecoat 5.85 4.6s" 4.35/s
-------
TABLE 5-1. CONTROL OPTIONS (LOW VOC COATINGS)'
Revised Using Rule 632 and Values fron Table 3-4
Operation Baseline VOC1 Control Level 12 Control Level 23
2. Air-Dried Coating-Exterior Parts'1"31
a. Prime 6.14 6.1 4.8
b. Topcoat
(i) Basecoat 5.84 5.8 5.0
(ii) Red & Black Basecoat 6.67 6.67 5.75
(iii) Clearcoat 6.14 5.4 4.5
(iv) Non-Basecoat/Clearcoat 6.3 6.3 5.0
(v) Red & Black Non-Basecoat/Clearcoat 7.25 7.25 5.75
W 3. Air-Dried Coating-Interior Parts 6.8 6.3 5.0
C-0
GD
4. Touch Up and Repair'31 6.84 6.3 5.2
5. Specialty Low Volume Coatings 7.04/7 7.0 7.0
1 VOC levels as given in Table 3-4 partially and what is missing, based on industry survey data to EPA.
2 Control levels of VOC as given in Ml Rule 632, Table 65 effective after 12/31/89.
3 Control levels of VOC as given in Ml Rule 632, Table 66 effective after 12/31/92.
4 Not dealt with in Table 3-4 but based on industry survey data to EPA.
5 Because of technical consideration, as documented to EPA by industry, red and black colors VOC limits should be set by applying a 1.15 factor to the VOC limits given in1
Table
6 VOC limits are for technology forcing products for which no Method 24 data is available and therefore are based on theoretical values. For baked coatings. Method 24 testing^
gives consistently higher values in the range of 0.4 to 0.5 Ibs/gal of VOC.
7 Speciality coatings have unique properties that lower VOC versions can't deliver. However, they are used in low volume and can be restircted to less than 5% of the daily
or monthly volume used.
-------
JOE LENNON, FORD MOTOR COMPANY, REPRESENTING
MOTOR VEHICLE MANUFACTURERS ASSOCIATION
Summary of Joe Lennon/s Presentation
Mr. Lennon opened by stating that the Motor Vehicle
Manufacturers Association (MVMA) is in agreement with the
comments made by NPCA concerning the plastic parts CTG.
Mr. Lennon's comments address coating automotive plastic parts
only, and, generally speaking, MVMA supports the VOC control
levels in Michigan's Rule 632.
Specifically, MVMA recommends that VOC control options be
developed for additional coating categories; the additional
categories needed are air dry coatings, and red and black
coatings. MVMA and NPCA have submitted technical papers to EPA
describing the special needs of these coatings.
The MVMA also objects to EPA's method of setting control
options based on lowest available VOC contents for each
individual coating category. Coatings should be considered as
part of a coating system where the specifications of all the
coatings used together are considered.
New VOC limits will require reformulation of coatings, which
in turn triggers a time consuming product approval process. For
example, new coatings must be proven resistant to sun, salt, and
weathering. The Michigan rule allows time for development and
approval of new coatings by phasing in controls over time in two
increments. The options presented by EPA do not appear to leave
enough time for the approval process.
Lower VOC coatings can compromise the finish appearance and
quality of coating. Since U.S. car manufacturers must compete in
a world-wide market, lower VOC content requirements may affect
their ability to compete. MVMA feels that the color and
appearance of the coating is a primary selling point for
automobiles.
Coating durability is also affected by VOC levels. If
reformulated coatings are not given adequate durability tests,
they may be released on the market prematurely. Resulting
durability failures will cause the need for increased
refinishing, as well as increased warranty complaints.
Regarding add-on controls, Mr. Lennon stated that
Michigan Rule 632 allows for VOC reduction without the use of
539
-------
VOC levels cannot be achieved through reformulation. Mr. Lennon
continued that the Michigan rule deliberately avoids add-on
technologies because small coaters would be driven out of
business if add-ons become necessary.
The MVMA also questions the capture and control efficiencies
(100 percent and 98 percent, respectively) used in the CTG model
facilities. Mr. Lennon pointed out that in the CTG the cost
effectiveness figures for incineration exceed lowest achievable
emission rate (LAER) cost effectiveness figures.
Mr. Lennon next addressed specialty coatings. Specialty
coatings are generally high VOC, low usage coatings, and it is
not economical to reformulate them. The MVMA recommends that EPA
either exempt specialty coatings or set higher VOC limits for
them.
Finally, Mr. Lennon commented on four particular sections of
the draft CTG. He disagreed with the transfer efficiency in
Table 3-4. Based on limited testing on a bumper painting line
that used HVLP and electrostatic spray guns, MVMA feels that
32 percent transfer efficiency is more appropriate for HVLP guns
than the 50 percent figure used in the model plants. He agreed
with the EPA presentation on transfer efficiency and said he was
pleased that EPA did not plan to recommend explicit quantitative
consideration of transfer efficiency. In Section 5.1.1, the
emission points addressed are not adequate; MVMA feels that
building vents, water pits, and paint mixing areas also
contribute to emissions, so you cannot assume that all VOC is
emitted from the spray booth, flash-off area and bake oven.
Under Section 7.3.2, MVMA recommends that when plastic and metal
parts are coated together, the less restrictive VOC level should
apply. In Section 7.8.3, the MVMA feels that quarterly or bi-
annual performance testing is unreasonable and too costly.
Performance tests should be limited to major breakdowns or
equipment replacement.
540
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COMMENTS TO UNITED STATES
ENVIRONMENTAL PROTECTION
AGENCY'S NATIONAL AIR POLLUTION
CONTROL TECHNIQUES
ADVISORY COMMITTEE
REVIEW OF OCTOBER 1,1991
DRAFT SURFACE COATING
OF PLASTIC PARTS CONTROL
TECHNIQUE GUIDELINE
DURHAM, NORTH CAROLINA
NOVEMBER 20,1991
Motor Vehicle Manufacturers Association
of the United States, Inc.
541
-------
I. INTRODUCTION
• REPRESENTING MOTOR VEHICLE
MANUFACTURERS ASSN. (MVMA)
• SUPPORT OF COMMENTS BY NATIONAL
PAINT & COATINGS ASSN. (NPCA)
• MICHIGAN RULE 632 - MODEL
-------
II. CTG SUBJECTS OF CONCERN
• COATING CATEGORIES
• COMPATIBLE PAINT SYSTEMS
• APPROVAL PROCESS TIMING
• QUALITY APPEARANCE
• DURABILITY OF COATINGS
• WARRANTY CONSIDERATIONS
• RACT ADD-ON CONTROL
• SPECIALTY COATINGS
543
-------
III. CATEGORIES OF COATINGS
• ADDITIONAL CATEGORIES NEEDED
• RULE 632 STUDIES
• CTG CATEGORIES NEEDED
- AIR DRY COATINGS
- RED & BLACK COLORS
- MVMA/NPCA TECHNICAL
SUBMISSIONS
544
-------
IV. COMPATIBLE PAINT SYSTEMS
• TECHNOLOGY LIMITATIONS/
LOWEST VOC
• COMPATIBILITY NEEDS FOR
APPEARANCE AND PERFORMANCE
• RACT CONTROL - REASONABLE
VOC REFORMULATION
545
-------
V. APPROVAL PROCESS TIMING
• EXTENSIVE AND TIME-CONSUMING
• COATING SUPPLIERS - CURRENT
RESEARCH AND DEVELOPMENT
• IMPACT OF TABLE 5-1 LEVEL 1
CONTROL
• AVAILABILITY OF APPROVED
COATINGS
546
-------
VL QUALITY APPEARANCE
• WORLDWIDE COMPETITION
• IMPORTANCE OF FINISH
APPEARANCE AND QUALITY
• CUSTOMER EXPECTATIONS
• TABLE 5-1 LEVEL 1VOC CONTENT
MAY IMPACT QUALITY
547
-------
VII. DURABILITY OF COATINGS
• AUTOMOBILE COATINGS MUST
LAST IN THE ELEMENTS FOR AT
LEAST 7-10 YEARS.
• PLASTIC AND METAL COMPONENTS
MUST MATCH.
• PREMATURE DURABILITY FAILURES
WILL CAUSE REPAINTING - IMPACT
VOC EMISSIONS.
-------
VIII. WARRANTY CONSIDERATIONS
• CUSTOMER LOYALTY
• FINANCIAL CONCERNS
• REFORMULATION MAY ADVERSELY
IMPACT WARRANTY AND TIMING
549
-------
IX. RACT ADD-ON CONTROLS
• RULE 632 STRATEGY/NO ADD-ON
CONTROLS
• SMALL BUSINESSES INVOLVED
• DRAFT CTG VALUES IN TABLE 5-1
LEVEL I MAY FORCE ADD-ON
CONTROLS
• EXCESSIVE COST OF ADD-ON
CONTROLS
• RULE 632 REQUIRES ADVANCED
APPLICATION EQUIPMENT
-------
X. SPECIALTY COATINGS
• UNIQUE REQUIREMENTS
• HIGHER VOC CONTENT/LOWER
VOLUME
• REFORMULATION LIMITATIONS
• EXEMPTION OR HIGHER VOC
LIMITS
-------
XI. ADDITIONAL COMMENTS
• TABLE 3-4 TRANSFER EFFICIENCY
- HIGH VOLUME LOW PRESSURE (HVLP)
- ELECTROSTATIC
• SECTION 5.1.1 EMISSION POINTS
- MISCELLANEOUS VOC EMISSIONS
- VOC CAPTURE LIMITATIONS
• SECTION 7.3.2 METAL/PLASTIC PARTS
- LEAST RESTRICTIVE VOC LEVEL
SHOULD APPLY
• SECTION 7.8.3 PERFORMANCE TESTS
- QUARTERLY OR BI-ANNUAL
REQUIREMENT IS UNREASONABLE,
IMPRACTICAL AND COSTLY
- SHOULD BE LIMITED TO MAJOR
BREAKDOWNS OR EQUIPMENT
REPLACEMENT
rrrro
•-J- v> fcJ
-------
STEVE KISH, GRACO, INC.
Summary of Steve Kish/s Presentation
Mr. Kish represents Graco, Inc., a manufacturer of spray
equipment. Mr. Kish stated that the CTG assumed a transfer
efficiency of 50 percent for electrostatic spray guns and HVLP
guns, and 25 percent for air spray guns. He showed Graco test
data which measured the transfer efficiency of electrostatic guns
at 50 percent to 90 percent, HVLP guns at 28 percent to
50 percent, and air guns at 25 percent to 40 percent. In each
case, the highest transfer efficiency was achieved at the lowest
coating flow rate (3 oz./min), and the lowest transfer efficiency
occurred at the highest coating flow rate (12 oz./min.). He went
on to say that the pay back period for HVLP was 6 to 13 days, and
for electrostatics it was 6 to 28 days.
Mr. Kish presented the savings potential for a large plastic
parts coating plant using both HVLP and electrostatics, using air
spray as a baseline. With HVLP, a 20 percent savings could be
realized on coating. The assumption of this estimate is that the
number of sprayers is held constant. It was stated that minimal
training was required for an operator to switch from an air spray
to HVLP. The limitation of HVLP systems is a throughput of 11 to
12 ounces of coating per minute. The HVLP gun was assumed to
cost $400, and paint cost was estimated at $40/gallon.
When using electrostatic guns instead of air spray guns, a
42 percent to 50 percent savings could be achieved based on the
same number of guns in use. If the number of guns used is
reduced, the savings is reduced to 20 percent to 25 percent.
There are significant cost considerations which are not included
in this scenario. The first is increased primer coating cost due
to the need to use a conductive primer coat. The second is the
cost of operator training. Last, the electrostatic guns require
more maintenance than air spray, about $50 to $70 per gun. The
capital cost of the electrostatic gun is assumed to be $4000, and
paint cost is $40 per gallon as with HVLP.
Mr. Kish concluded by stating that both HVLP and
electrostatic application are cost effective and serve to reduce
VOC emissions.
553
-------
Comments & Observations Of
Plastic Parts Coating CTG Document
in the "Automotive/Transportation Facilities"
en
GRACO INC.
GRAC01991 MINNEAPOLIS, MN
-------
What CTG Says About I.E. in Various Operations
tn
en
T
R
A
N
5
F
E
R
E
F
F
50
35
30
•
25
20.
15
I0.
5
0
Electrostatic
50%
25%
3 oz/mln 4.2 oz/mln
HVLP
Airspray
i i .
8.25 oz/mln 11. 4 oz/mln
»Alrspray a HVLP »Electrostatic
Assumes 50% transfer efficiency for electrostatic application
Assumes 50% transfer efficiency for HVLP application
Assumes 25% transfer efficiency for airspray application
GRACO1991
Plastic "automotive/transportation" flowrates based on .70 service factor
-------
What Grace's Test Experience Shows About T.E
T
R
A
N
S
F
E
R
90%
3 oz/min
4.2 oz/min 8.25 oz/min
Airspray HVLP Electrostatic
50%
Electrostatic
HVLP
25% Airsorav
11.4 oz/min
Shows range of 50-90% transfer efficiency for electrostatic application
Shows range of 28-65% transfer efficiency for HVLP application
Shows range of 25-50% transfer efficiency for airspray application
Plastic "automotive/transportation" flowrates based on .70 service factor
GRACO 1991
-------
0
F
D
A
Y
S
Payback Period in Days at
CTG Theoretical Flowrates
26.0_
23.4
20.8_
18.2_
15.6_
I3.0_
10.4
7.8_
5.2_
2.6_
0.0
26 days
J8.6 days
Electrostatic
HVLP
4.7 days
6.8 days
5.6 days
3 oz/min 42 oz/min
« HVLP a Electrostatic
8.25 oz/min
I 1.4 oz/min
Airspray transfer efficiency is baseline
Based on 16-hour production day with $40/gallon paint cost
HVLP initial cost est. $410
Electrostatic initial cost est. $4000
GRACO 1991
-------
s
A
V
I
N
G
S
P
E
R
D
A
Y
Payback Period in Dollars
at CTG Theoretical Flowrates
440_
396_
352_
308_
264
220
•
176_
132.
88
44
•
0
$433
$220
$157.50
$100
ft- _
$87
3 oz/min 4.2 oz/min
o HVLP n Electrostatic
8.25 oz/min
Electrostatic
-CJ
$410
HVLP
$72
.4 oz/min
Airspray transfer efficiency is baseline
Based on 16-hour production day with $40/gallon paint cost
HVLP initial cost estimate $410
Electrostatic initial cost estimate $4000
GRACO 1991
-------
Under CTG Enactment Using HVLP...
A Large Plastic "Automotive/Transportation Facility"
Could Realize the Following:
• 20 % savings on paint
• Retention of all spray stations
• Minimal adjustment costs associated with
operator training
• Restricted ability to change coatings to higher
solids or rheology (gun's ability at threshhold
at current 11-12 oz/min)
GRACO1991
-------
Under CTG Enactment Using Electrostatic..,
A Large Plastic " Automotive/Transportation Facility"
Could Realize the Following:
42-50% savings on paint when retaining all spray stations
20-25% savings on paint when retaining half of existing
spray stations
Significant adjustment costs resulting from:
Conductive primer or spray supports
Operator orientation and training
Increased maintenance costs of $50-80/month/gun
GRACO 1991
-------
For Further Documentation
GRACO INC.
P.O. BOX 1441
MINNEAPOLIS, MN 55440-1441
Thank You
GRACO 1991
-------
JOHN L. WILLIAMS, MOBAY CORPORATION
Summary of Presentation of John L. Williams
Mobay is the leading supplier of polyurethane raw materials.
This includes aliphatic polyisocyanate resins for polyurethane
coatings. It is wholly owned by Bayer/AG of Germany. As of
January 1, 1992, it will be known in the U. S. as Miles, Inc.
Mr. Williams stated that two-component flexible polyurethane
coatings are the standard for the European automotive industry
and have 25 percent of the U.S. market for exterior plastic
automotive parts.
Mr. Williams stated that he felt the coatings now meeting
the level of 2.3 Ib VOC/gal for business machines compromise
performance. VOC levels of 2.8 Ib VOC/gal solvent-based are
currently achievable with two-component polyurethane coatings. He
said that Mobay (Miles) has technology to potentially meet VOC
levels of 1.0 to 1.5 Ib VOC/gal within one to two years with two
component waterborne polyurethane coatings. He said this
technology has not yet been tested in a large scale application
and may be limited by industry acceptance.
One concern noted earlier at this meeting was the potential
for health risks from polyurethane coatings. He stated that
these types of coatings are the standard in Europe (25 percent of
U.S. market), and that they pose no major health hazard with
proper handling. Mr. Williams offered to supply health and
safety information on polyurethane coatings.
In the area of automotive/transportation coatings, Mobay is
developing two component polyisocyanate coatings for exterior
clearcoat. The expected VOC levels for these developmental
coatings are 2.5 to 2.8 Ib VOC/gal. Mobay is also developing a
2.8 waterborne primer. Current limitations of these coatings are
that they are not yet Toxic Substance Control Act (TSCA) listed.
They have applied for listing and expect them to be available for
sale by the 3rd or 4th quarter of 1992. Development of large
scale production capacity for these coatings requires a large
capital outlay that Mobay is prepared to make. Mobay supports
the development of lower VOC coatings, but these new coatings
must be performance and economically driven products. Mr.
Williams stressed the need for cooperation between raw material
suppliers, paint manufacturers, coaters and EPA.
-------
Mobay's Role in Coatings for Plastics Mobay
• Mobay is the leading North American Supplier of Aliphatic
Polyisocyanate resins for use in polyurethane coatings
• Mobay sells resins to manufacturers of coatings for plastics
• Mobay seeks to act as a technical partner to the plastics
^ coatings industry
U. S. Environmental Protection Agency, November 19-21,1991
-------
CD
Mobcay Supports M°bay
The need for continued cooperation by the EPA with
coatings raw materials suppliers, coatings
manufacturers, and rofintsh coatings users in allowing
VOC compliant products to be optimized
Lower VOC coatings to earn market acceptance on
product merit and economic benefit
U. S. Environmental Protection Agency, November 19-21,1991
-------
Current Status of Polyurethane Mobay
^^^ ^K ^_ ^^ ^m ^_ ^^ i'.vV'.V'V.'.V.M.V.V.Sv.v-SV.V.
Coatings for Business Machines
Currently Available Technology VOC (Ibs/gal)
Primers 2.8
Colorcoats 2.8
Clearcoats 2.8
Systems can be improved by resin development
and formulation changes to lower VOC levels
and to optimize performance
U. S. Environmental Protection Agency, November 19-21,1991
-------
Future Developments for PU
Coatings for Business Machines
VOC reductions possible with waterborne 2K
polyurethane primers, color and clearcoats
Mobay
Potential Benefits
• Reduced VOC color .and
clearcoats
(1.5-1.0 pounds/gallon VOC)
• Reduced VOC water-borne
primer
(1.5-1.0 pounds/gallon VOC)
Present Limitations
• No large scale production at this
point
• Reasonable currently commercially
available technology in 1-2 years
• Technology would require
• Cooperative development with and
the approval of coatings
manufacturer
• Acceptance of business machine
coating users
IL S. Environmental Protection Agency, November 19-21,1991
-------
Future Developments for Mobay
PU Coatings for Automotive Plastics ~
Further VOC Reductions Possible with Higher Solids
Two Component Polyurethane Topcoats and
Waterborne Primers
Potential Benefits
• Reduced VOC 2K clearcoat
and pigmented topcoat
systems
(2.5-2.8 Ibs/gal VOC)
• Reduced VOC waterborne
primer systems
(2.8 Ibs/gal VOC)
Present Limitations:
• All resins used in the system are not
TSCA listed
• All resins do not have large-scale
manufacturing capacity established
• Technology would require:
• Cooperative development
• The acceptance of the plastics coatings users
with/and the approval of manufacturers of
coatings
U. S. Environmental Protection Agency, November 19-21,1991
-------
tn
£73
Mobay Supports Mobav
The future development of lower VOC
polyurethane coatings systems for
plastics in cooperation with coatings
manufacturers, coatings users, and
the Environmental Protection Agency
U. S. Environmental Protection Agency, November 19-21,1991
-------
DISCUSSION ON PLASTIC PARTS COATING
QUESTIONS AND COMMENTS FROM THE COMMITTEE ON EPA PRESENTATION
Question: Are aerospace plastic parts covered under this
CTG? The question has come up in California whether the plastic
parts CTG or the aerospace CTG will cover these parts.
Answer: We do not know yet. We discussed this some with
the aerospace industry at a meeting in March or April. The EPA
will be meeting with representatives from the aerospace industry
next week. Some aerospace parts, for example seat backs and tray
tables, that are most likely coated outside of the facility may
be best covered by this CTG. Other parts that are most likely
coated at aerospace facilities, especially those that are coated
as part of a larger assembly or complete aircraft, may be best to
cover in the aerospace CTG.
Comment: There is a discrepancy between the cost
effectiveness figures for incineration reported for the model
plant analyses on slides 9 and 12 and for the national impacts
reported on slide 13.
Answer: Yes, the national impact cost effectiveness figures
should read $22,000 for automotive, $21,000 for business
machines/miscellaneous, and $22,000 for the total. We plan to
look at options for reducing air volume and increasing VOC
concentration to bring these costs down.
Question: Do you propose that the coater or the coating
manufacturer perform Method 24 tests for VOC content?
Answer: We have tried systems where the manufacturer
provides Method 24 test information for each batch of coating so
that the coater does not have to do the testing. The coater uses
the manufacturer's test results and adds in any dilution solvent
added to the coatings. We expect to recommend this system in
this CTG. It is more economical for the coating manufacturer to
run one test on a batch of coating than for many coaters to have
to test coating from the same production batch.
Question: Do your emissions estimates include any emissions
prior to spraying?
Answer: No, our estimates begin with spraying. We do not
include emissions from paint mixing.
•J *_*
-------
Question: Did your evaluation include alternatives such as
dipping or molded-in color?
Answer: We tried to show in the CTG that there are
alternatives such as dipping and molded-in color, but we are
reluctant to tell the industry to dip rather than spray. The
appearance of dip coated parts is not the same as spray coated
parts. Some plastic parts do have molded in color. Coatings,
however, enhance the performance of many plastic parts by
improving color, gloss, chemical resistance, scratch resistance
and ultra-violet resistance.
Comment: Considerable VOC emissions occur during gun
cleaning. Consideration should be give to these emissions.
Answer: More will be said about this subject during the
auto refinishing presentation. We will listen in and see if
there is something we can apply in this CTG.
Comment: Consideration should be given to controlling
different types of booths or subsets of booths.
Answer: We will consider doing so. There are examples
today of facilities where automated booths are controlled and
manual booths are not controlled.
Question: You have estimated about 40,000 tpy VOC emissions
from plastic parts coating. Is this large or small relative to
other sources in non-attainment ares? It sounds large.
Answer: In most areas there are many small pieces of the
VOC pie, not a single large piece that accounts for the majority
of emissions. There are some large plastic parts coating
facilities, but as a percentage of total VOC emissions in a
single non-attainment area they are probably not very large.
-------
Questions and Comments from the Committee on Naomi Suss'
Presentation
Question (Committee): There is a large discrepancy between
the estimated VOC emissions from EPA and NPCA. Can you explain
the reason?
Answer (NPCA): The NPCA surveyed its members and obtained
Method 24 data and quality control data; these values were then
multiplied by the amount of coating actually sold. We don't know
how to account for the differences; either party could have made
an error.
Question (Committee): Is the flexibility afforded by the
Method 24 0.5 pound scaling factor in Michigan's rule still
needed, or can it be eliminated because of knowledge of coatings
currently on the market?
Answer (NPCA): These factors were needed when Rule 632 was
developed because the rule was technology forcing. Coatings that
met the emission limits were not available. There are some
coatings available now, but the scaling factor should not be
eliminated yet since there are still applications where it is
required.
Question (Committee): A half-pound of VOC per gallon of
coating seems like a lot.
Answer (NPCA): Let me give you an example of why a half-
pound is appropriate. The typical coating used for automotive
plastics is a melamine-polyol type cross linking mechanism.
These release by-products, such as methanol and butanol, via a
condensation reaction that can vary from batch-to-batch. These
VOCs are not part of the original coating formulation. They
cannot be calculated until you have substantial production
history for the coating to tie the value down.
Question (EPA): Then why not just set higher standards for
these combinations?
Answer (NPCA): That is an option.
Question (Committee): How does choosing to disperse
pigments in resins rather than in solvents affect the VOC
content?
Answer (NPCA): Most pigments are dispersed in resins; but
at higher solids contents, solvent may be required to minimize
agglomeration. A point of diminishing returns is reached.
Comment (NPCA): Red coatings can cost two or three times as
much as other coatings and may reach $120 per gallon. Coaters
require more of these coatings to cover their parts. Industry
supplies such coatings because they are in dejnan4,
.J C
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Question (EPA): Were the sales figures just for Michigan?
Answer (NPCA): No, the figures were for North America,
including those members in Canada.
572
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Questions and Comment from the Committee on Joe Lennon's
Presentation
Question: What is the technical reason for using the less
restrictive VOC level when plastic/metal combinations are coated.
Answer: There are relatively few situations where this
occurs, and the industry needs flexibility to deal with them.
The Michigan rule may instruct you to categorize parts as metal
or plastic by the predominant type of material.
Question: Industry spokespersons have stated that there are
obstacles to either reformulation or using add-on controls;
however, there is a health problem to be addressed. How should
it be addressed?
Answer (Naomi Suss, NPCA): The industry has the same health
and safety concerns. The automobile industry has worked very
hard to reduce emissions and has had many successes. The plastic
parts coating industry is pursuing reformulation solutions.
Progress has been made. For instance, there has been an increase
in weight solids content of 250 percent over the past 10 years;
40 percent of automotive interior coatings VOC level will be down
to 2.5 Ibs VOC per gallon of coating or less by next year.
Powder coatings are being investigated. One use of powder
coatings is on an SMC grille opening panel for Chrysler vehicles.
Waterborne coatings are being introduced for color coats, one
color at a time to match with vehicle bodies coated with
waterborne basecoat. Also, two component isocyanate coatings are
being evaluated, but there are health concerns and concerns about
the ease of handling these coatings in production situations.
Answer (Joe Lennon): Ford will be using waterborne coatings
for all interior parts at one of its plants, but we still are not
able to meet the Michigan Rule 632 levels at another plant. We
have a contingency plan to install add-on controls at that
facility-
Question: Would alternative curing processes, such as UV
curing, provide a solution?
Answer (Naomi Suss, NPCA): UV curing does not show good
performance with high solids coatings; so far for automotive
applications it is better with low solids coatings.
Question: What emission reductions do you expect from
Rule 632?
Answer: 15 percent by 1992, and 25 percent by 1995.
Comment (Committee): 25 percent is good, but we are looking
for 75 percent reduction. Perhaps we need to look at add-ons.
-------
Question: What are other countries doing about coating VOC
emissions from plastic parts?
Answer (Naomi Suss): Nothing. They still use low solid
lacquer colorcoats, and about 30 percent solids for their
clearcoats. Germany is the only other country showing concern;
they are using some waterborne coatings.
Question: Would you support an equipment requirement for
transfer efficiency (TE)?
Answer (Naomi Suss): There are currently not many plants
that use only conventional spray due to cost incentives of using
higher efficiency guns. Electrostatic spray and HVLP are
commonly used. Air-assisted airless is used for some interior
parts, but rarely for exterior parts. Color matching on the
third coat for metallic colors and, touch-up of nicks and
scratches occurring during assembly requires the use of air
atomized (conventional) spray. An equipment requirement would be
acceptable if it allowed for these necessary uses of conventional
spray equipment.
Comment (Committee): EPA may need to consider providing
specific guidance on specialty coatings to avoid problems with
implementation at the State level.
Comment (Committee): There are so many different types of
parts whose quality may be impacted. It would help if the
industry could give EPA information on which parts can meet the
control options and which cannot, and a timetable for new
coatings.
Comment (Naomi Suss): I have thought of one reason why our
estimate and EPA's estimate of coating usage may differ. Our
estimate did not include coatings used on plastic parts that are
coated in assembly plants such as SMC hoods, fenders and grille
opening panels. These coatings are covered by other regulations.
We only included data on coatings used outside of assembly
plants.
£74
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Questions and Comments from the Committee on Steve Kish's
Presentation
Question (Committee): Can 90 percent transfer efficiency be
achieved with electrostatics?
Answer: Yes, theoretically. That transfer efficiency
(90 percent) was achieved at a paint flow rate of 3 oz./min.
This is not a practical flow rate in a large plant. A more
typical flow rate is about 15oz./min. The transfer efficiency at
this flow rate would be about 50 percent for electrostatic spray,
30 percent for HVLP and 25 percent for air spray.
Question (Committee): This looks good. Why aren't
electrostatic guns used?
Answer: They are in use in many plants, especially for
automotive plastics.
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Questions and Comments from the Committee on John L. Williams'
Presentation
Question (Dave Salman): Do the stated VOC contents for the
waterborne coatings exclude water?
Answer: Yes
Question (Dave Salman): What kinds of basecoats can be used
with these new two-component automotive clearcoats?
Answer: We are not working on developing basecoats, but
these clearcoats are intended for use with both solvent-borne and
waterborne basecoats. More cooperative development work still
needs to be done to prove compatability with specific basecoats.
Question (Committee): Would you recommend a regulation
based on the VOC contents that you have presented?
Answer: We would recommend a level of 2.8 Ib VOC/gal for
Business Machine/Miscellaneous. For automotive coatings, we
can't say that we definitely can reach the levels in
Michigan Rule 632 or the draft CTG, but we are working towards
them.
Question (Bruce Jordan): Are the CTG numbers too high?
Answer: I decline to say that they are too high, but that
is the inference.
Question (Bruce Jordan): What do you think should determine
the VOC content limits?
Answer: Performance and economics should drive the
industry. The U.S. needs to stay competitive in the world
market. I believe that the technology will soon be available to
meet lower VOC levels and it will be polyurethane technology.
Question (Bruce Jordan): What will it take to push industry
toward compliant technology?
Answer: EPA is forcing the technology, but a cooperative
effort must be made so that performance is maintained.
Question (Bruce Jordan): What is required of EPA to get the
cooperation required?
Answer: EPA, manufacturers, coaters, and suppliers must all
work together. The market is performance and economics driven.
VOC reduction and performance can go together.
576
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Navistar International 6125 Urbana Road L.\ J-
Transportation Corp. p o Box 600
Springfield. OH 45501
513 390 2800
U.S. Environmental Protection ftgencv
Office of Air Qualit^ Planning and Standards
Research frianale Park, North Carolina 27711
INTERNATIONAL
November 14. 1991
Bruce Jordan. Director Emission Standards Division
SUBJECT: Plastic Parts Coating Draft CTG
Navistar International Transportation Corp. is a manufacturer
of transportation equipment. Two facilities would appear to be
potentially affected by the proposed CTG. The first manufactures
mold compound (SMC) components for trucks and small boats, applying
primer and conductive coatings to the truck components only. The
second facility is a truck assembly plant which uses repair
primers, acrylic enamels withnut clearcoat, acrylic enamels with
clearcoat, and aftermarket repair coatings. Navistar appreciates
the opportunity to provide comments and questions for the Draft
CTG.
In Section 3.1 and other sections throughout the CTG, does
"other mobilized eguipment" include fiberglass boat hulls'?
Section 4.4 states that no plastic coating operations have
paint spray booth controls. The Navistar assembly plant in
Springfield, Ohio, utilizes VOC controls on two paint lines which
coat both miscellaneous metal parts and plastic parts using the
same coatings.
Section 5.1.1 at the top of p. 5-2 States that coatings never
leave the spray booth. However, this does not account for paint
particles and soluble solvents entrained in the water of a
waterwash booth which has a remote sludge handling system. Later
in the document this is acknowledged on p. 5-9 in the first
paragraph.
Table 5-2 Control levels should permit in—line volume
weighted averaging of allowables when more than one type of coating
is applied in the operation (i.e. BC/CC). Thus, if a source uses
a clearcoat with a VOC content less than the RACT limit and a
basecoat with a VOC content in excess of the RACT limit a daily
volume weighted average would be used to determine the RACT
allowable. A similar provision is found in the federal model rule
NAVtSTAR r^rj
•J, i, I
-------
for can coating when sides, ends, etc. are coated in the same line.
Section 7.3.2 has an inconsistent overlap with the
miscellaneous metal parts coating CTG and SIPs. Proposed control
levels and baselines for plastics indicate color coatings with a
higher VOC content than clear coatings, but the miscellaneous metal
parts rules permit a greater VOC content for clearcoats and a much
lower VOC content for colored material. Navistar finds the
baseline VOC content for basecoats closer to the norm than the
miscellaneous metal parts rules.
For operations coatina both plastic and metal in the same
operation, EPA should allow the least restrictive condition for
clear and for color coatings to apply for both metal and plastic
parts. EPA should not reguire separate record keeping for guantity
of paint applied to metal and plastic or the respective surface
areas coated. In addition, EPA must address the miscellaneous
metal parts provisions which exempt the coating operations of
custom vehicles if production is less than 35 vehicles per day-
Many of Navistar s competitors use this provision to avoid
regulation of their miscellaneous metal parts coating operations,
including two in the state of Ohio.
Section 7.6.1 discusses transfer efficiency- If a transfer
efficiency is included in the RACV determination, then EPA must
also consider how this affects the miscellaneous metal parts
painted in the same operation.
Section 7.7.2 does not recognize Method 25A but then in 7.7.3
calls for continuous emissions monitoring which yield "actual
emission" measurements. Presumably this would be an FID calibrated
to propane measuring a blend of solvents, like method 25A.
The proposed testing freguencies in Section 7.8.3 are
unreasonable when reguired more f^eguently than annually.
Sincere 1y,
Tim W. McDaniel, CIH
Environmental Manager
.cc E. Ardlen te
M . Cu1 pepper
r >--/
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/
ELECTROSTATIC CONSULTANTS CO,
ENGINEERING & MANUFACTURING
P.O. BOX 1587 / LISLE, ILLINOIS 60532 / PHONE (708) 668-5027
November 15, 1991
U.S.EPA
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
Attn: Bruce C. Jordan, Dir.
Emission Standards Div-
Dear Mr. Jordan,
I received your notice of the next meeting of NAPCTAC and
the draft of the CTG on surface coating of plastic parts. Section
3.3.2 on application coating equipment falls far short of the needs
of the coating industry and I would like to explain the shortcomings
of the listed spray equipment.
CONVENTIONAL AIR SPRAY
This class of guns has been the standard of the industry for
the past 100 years but has been the primary cause of air pollution
in the spray painting industry. The transfer efficiency (T.E.) is
very poor. This class of guns should be retired as quickly as pos-
sible. This, of course, is already being done.
AIRLESS SPRAY
Airless spray equipment combines "engineering extremes" that
can cause too many production problems. Extreme pressures are com-
bined with extremely small paint orifices. It wastes paint by
building excessive film thickness. This does little to reduce VOCs.
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[2]
It also lowers quality of finish and falls far short of the flexi-
bility of air guns. The gun was developed to improve on the low
efficiency of air atomizing guns but it failed to replace the con-
ventional air atomizing guns.
AIR-ASSISTED AIRLESS SPRAY
This is a variation of the airless gun and was designed to
improve the atomization of the airless gun. By improving the atom-
ization, smaller spray particles are produced and this lowers T.E.
compared to the airless gun. The quality of finish is still sub-
stantially less than that of a conventional air spray gun and it
cannot be expected to replace conventional air guns when a high
quality of finish is essential. This gun does not offer a solution
to high VOC emissions since the atomization is still relatively
poor and the larger spray particles tend to waste paint by building
excessive film thickness.
HIGH VOLUME LOW PRESSURE SPRAY
The hype generated with the HVLP spray gun seriously over-
states it's value to the spray painting industry. The definition
of an HVLP gun is not adequate to assure an improvement in T.E.
and a reduction in VOCs. Variables that must be pinned down to in-
sure an improvement in T.E. are as follows:
1. Atomizing air pressure, the only current requirement of
an HVLP gun. (10 PSI or less).
2. Viscosity of coating material
3. Paint flow-rate (production speed)
4. Range of spray particle size at a given air pressure
5. Air volume
6. Spray velocity
7. Film thickness
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[3]
Most of the variables indicated above will cause an increase
in VOC emissions if they are adjusted in the wrong direction. An
increase in air volume also increases spray velocity but this lowers
I.E. and increases VOC emissions. Obviously, the definition that
calls for high volume (HV) in HVLP is wrong.
A switch-over to an environmental coating is needed to re-
duce solvent in the coating but this also increases it's viscosity
and makes the material more difficult to atomize. Larger spray par-
ticles are produced and while this may improve I.E., there is a
corresponding increase in film thickness that causes an increase in
paint consumption, an increase in VOCs and a lowering of quality.
Under these conditions, the HVLP gun becomes unacceptable. It fails
to do the job intended.
A reduction in paint flow-rate is in the right direction if
it is combined with a corresponding increase in I.E. and may be
self-defeating. It also has the effect of reducing production speed
and greatly increasing operating costs. Once more, an HVLP gun
may become unacceptable to the end user. Most HVLP guns on the
market are currently criticized by the end user for lowering quality
and cutting production speed. While many thousands of HVLP guns
have been sold, they have done very little to reduce VOCs. Placing
the emphasis on atomizing air pressure totally overlooks the many
other important variables.
Our CFA 740 hand gun is the only so-called HVLP gun that
controls all variables and actually achieves the end result of
lowering VOCs. It is the only new invention in air atomization that
has appeared on the scene in the last century. Unfortunately, it
has a lot of unqualified competition that muddies the water and
obscures it's merits. Our CFA 740 hand gun uses an entirely differ-
ent form of air atomization that uses the energy available in com-
pressed air far more efficiently than any other air atomizing spray
gun. It is entitled to a separate and distinct classification. It
is not a conventional air, airless, air-assisted airless or an HVLP
gun with multiple air jets. The average HVLP gun is equivalent
581
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[4]
to a downgrade of a conventional air gun.
Our CFA 740 hand gun is the best RACT available for non-
electrostatic hand guns. It holds the quality and production speed
of a conventional air gun while greatly improving I.E. and reducing
VOC emissions. It will fully atomize the higher viscosity environ-
mental coatings while staying under the 10 PSI atomizing air pres-
sure specified for HVLP guns. This is the result of a major change
in the mechanics of air atomization. The multiple air jets of a
conventional air atomizer and HVLP atomizers are replaced with a
single, converging annular air orifice and a diverging conical sur-
face that converts the round stream of paint into a thin film prior
to atomization. This concept is known as "Conical Film Atomization"
and achieves equivalent atomization with a fraction of the energy
required with other atomizers. The CFA 740 hand gun is low in cost
and is interchangeable with all conventional air guns in use in the
country. Enclosed is a "House Painting Report" that shows the CFA
740 hand gun approaching very close to 100% T.E. As quality stan-
dards are increased and the product size is reduced, the T.E. will
drop somewhat. It achieved 65.5% T.E. on 8" x 11" panels in tests
conducted by the SCAQMD. The 65.5% T.E. still represents a 62%
paint savings and VOC reduction compared to a 25% T.E. conventional
air gun. Since the gun will also spray higher viscosity, higher
solids paint, it can achieve over 90% reduction in VOCs without
requiring the need for very expensive add-on controls.
ELECTROSTATIC SPRAY
Electrostatic spray has not been used extensively in coating
plastic parts. The first electrostatic system to apply waterborne
coatings on plastic shutters is discussed in the enclosed reprint
from the November 1982 issue of Industrial Finishing Magazine. It
explains our proprietary, patented process for applying waterborne
coatings on non-conductive or semi-conductive substrates. We never
received permission for publishing the actual production photos
because the shutters were a proprietary product manufactured for
others.
502
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[5]
Photo #1 enclosed shows the first production operation.
Seven different colors are applied on this line. The shutters are
painted 100% automatically and do not require manual touch-up.
Photo #2 enclosed shows the shutters passing through a
baking oven for four minutes at 170°F. You will notice the warping
of the shutters. They straighten out once more when cooled to room
temperature. A higher baking temperature would destroy the shutters
by making the warp permanent.
Photo #3 enclosed shows the isolated paint pressure tank
that is charged to high voltage because of the electrical feedback
from the charged guns. On new installations designed from scratch,
it is possible to operate with the paint source at ground potential.
An entire fiber drum of paint fits inside the pressure tank.
It is lifted out and replaced with a drum of paint of another color
when changing colors.
The system can paint 7'0" high shutters at a conveyor speed
of 15 FPM. The shutters are placed back-to-back about three minutes
after leaving the baking oven and covered with clear, heat shrink
plastic. They are then placed in cartons for shipment.
Photo #4 enclosed shows the Auto-Static 400 gun that is used
to paint shutters. Mounted below the gun is a remote control fluid
pressure regulator that is used to control the paint flow-rate.
This gun also uses the improved "Conical Film Atomization" that was
put on the CFA 740 non-electrostatic hand gun at a later date. This
gun will easily apply high viscosity waterborne coatings. The
amount of water used in the paint is kept low and the viscosity
high. This permits building the desired film thickness without runs
and sags. The system when operated with high viscosity waterborne
paint is not sensitive to broad changes in relative humidity and
avoids the high cost of air conditioning a spray booth.
Also enclosed is a piece of literature on our Aqua-Static
100 electrostatic hand gun for applying waterborne paint. While
this gun easily outperforms all other electrostatic hand guns on
-------
[6]
waterbornes, we consider it obsolete. We are in the process of re-
placing it with a new model. The Aqua-Static 100 was first placed
on the market in 1971 but our competitors managed to destroy the
market for waterborne paint and pushed for high solids paint. The
Aqua-Static 100 gun used the conductive waterborne paint to bring
the electrostatic charge to the head of the gun. It functioned as
a non-electrostatic gun when used with non-conductive solvent base
paint but would still atomize the high solids coatings much better
than other spray guns. Our competitors controlled the market but
failed to solve environmental problems.
With our automatic electrostatic guns equipped with "Conical
Film Atomization" and a proper waterborne or high solids environ-
mental coating, the need for installing expensive add-on controls
can be avoided and still meet the most stringent environmental codes.
The enclosed colored environmental comparison for liquid coating
shows a 94% reduction in VOCs. Attached to this chart is a news
release that explains the switch-over to a waterborne powder slurry
to cut VOC emissions by 100%. The operating costs of this system
will be half that of a dry powder system.
Our Auto-Static 400 electrostatic spray system is by far the
best RACT available to the plastic industry. With a waterborne
coating, it can reduce VOCs by 94% or more.
Electrostatic spray equipment is substantially more costly
than HVLP guns but can quickly be justified with heavier production
requirements. In order to obtain the many advantages of electro-
static spray combined with "Conical Film Atomization" to achieve
superior atomization at still lower air pressure, it is necessary
to install our Auto-Static 400 automatic electrostatic equipment.
It will pay for itself with paint and labor savings in the first
year. Other electrostatic air gun systems are still using conven-
tional air atomization that is severely limited when attempting to
apply the higher viscosity environmental coatings. They were de-
signed originally to atomize low viscosity non-compliance paint and
cannot properly apply the new high viscosity waterborne and high
504
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[7]
solids environmental coatings.
Disk and bell electrostatic systems have serious drawbacks.
They do very poorly atomizing conductive waterborne coatings. There
is a serious reduction in quality. They also provide very poor
"throwing power" into recessed areas and require far too much manual
touch-up. The touch-up is normally done with low efficiency touch-
up guns-that cause a serious drop in overall efficiency. This
greatly increases overall paint consumption and VOC emissions.
One of our old customers manufacturing folding chairs gave
a talk at a local seminar recently. We replaced two reciprocating
disks and three touch-up men with our Auto-Static 400 electrostatic
system at his plant. The improvements achieved were as follows:
1. Increased production at least 10%
2. Eliminated two of the three touch-up men
3. Cut overall paint consumption by 30% and reduced VOC
emissions a corresponding amount.
4. Reduced annual rejects by $100,000
5. Switched the firm over to waterborne coating to achieve
full environmental compliance
6. Eliminated a potential fire hazard
7. Cut costs by 50% over competitive dry powder systems
Our continuous efforts to solve air pollution in the spray
painting industry since 1969 are finally starting to pay off.
Sincerely,
Arvid C. Wallberg CMFgE
ACW/mv /X V
Enclosures --^/
585
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ELECTROSTATIC CONSULTANTS CO
P.O. BOX 1587 / LISLE, ILLINOIS 60532
PHONE (708) 668-5027
July 3, 1991
HOUSE PAINTING REPORT
A new sales field has been added to the scope of the CFA
740 air-atomizing non-electrostatic hand spray gun. A wooden frame
home with vertical redwood siding was sprayed in Carmichael, Ca.
and achieved almost 100% transfer efficiency (T.E.). The gun
coated 300 sq.ft./gal with a paint that was rated as follows:
COVERAGE
250 - 350 sq.ft./gal on smooth surfaces
150 - 250 sq.ft./gal on porous, rough or weathered surfaces
Since the description of the wooden surface fit the latter
description rather precisely, the actual performance of 300 sq.ft./
gal was exceptional. The condition of the surface tended to indi-
cate that two coats might be required to achieve good coverage. The
single coat proved to be more than adequate and provided excellent
coverage and uniformity- The actual coverage indicated on the paint
can as shown above was with a brush or roller. The CFA 740 air
atomizing spray gun actually provided even better performance.
PAINT
Sears Weatherbeater, #21455 Navajo Red solid color stain
made for Sears by Olympic. Contents:
Water, Vinyl Acrylic Resin, Silicon Dioxide,
Ethylene Glycol, Alkyd Resins & Additives
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-2-
Reduction: 2 Paint, 1 Water
Viscosity 79 Sec. #2 Zahn Viscosity Cup
Max. VOCs: 350 GMS/liter
2.92 Lbs/gal
SPRAY GUN
'CFA 740 hand gun (air atomizing with Conical Film Atomization)
complete with 1 qt. pressure cup. Fluid orifice 0.120", restrictor
orifice' 0.40" and 0.052". 25' air hose, 3/8" I.D.
AIR COMPRESSOR
Sears Craftsman 1 HP, 8 Gal. Tank.
4.5 S.C.F.M. at 40 PSI
3.0 S.C.F.M. at 90 PSI
Compressor shut off automatically when 100 PSI was reached
and restarted when tank pressure dropped to 80 PSI. A small air
pressure regulator on the tank supplied compressed air to the spray
gun.
OPERATING CONDITIONS
The paint is normally applied with a brush or roller. The
label indicated an airless gun could be used and the paint applied
uncut. Conventional air atomizing spray guns are not used for this
type of application because of the excessive spray fog and paint
waste normally generated. The CFA 740 hand gun was the first air
atomizing spray gun to be successfully and economically used to
paint a home. The paint waste was negligible and the quality of
the final coating was excellent
The attached air pressure curve shows the operating conditions
for the spray gun. The gun was operated as follows:
UPSTREAM AIR PRESSURE, PI 20 PSI
ATOMIZING AIR PRESSURE,?2 5 PSP
PAINT PRESSURE 6-9 PSI
r '•• 7
rj. 0 i
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-3-
* Meets California's SCAQMD environmental requirements
(10 PSI is upper limit). Conventional air atomizing
guns are currently barred from use in the state.
The 0.040" restrictor orifice was installed in the paint
inlet connection of the gun. This provided a relatively slow speed
and was replaced with a 0.052" restrictor orifice to increase speed.
The spray gun proved to be much faster than a brush or roller and
applied a higher quality finish. It was probably slower than an
airless gun but by precisely controlling the amount of paint applied
to the surface, far less paint is used. The gun could also be oper-
ated at much higher speeds if necessary.
In tests last year, DuPont preferred the CFA 740 hand gun
for maintenance painting over an airless gun. Their primary com-
plaint was that it did not use enough paint. I advised them that
they could raise the price of paint used with the gun but they in-
dicated this could be done over a long period of time but not over-
night. DuPont tried the gun for painting storage tanks in refinery
tank farms, piping, buildings and even for maintenance painting on
an oil platform in the Gulf of Mexico. The gun is an excellent pros-
pect for replacing all airless spray equipment used by painting con-
tractors. It provides very high painting efficiency while retaining
all of the flexibility of a conventional air atomizing gun. It also
has a major advantage over all other guns used in the wood coating
industry.
The primary bottleneck for house painting was the small air
compressor used. It had to be operated almost continuously. The
compressor was equipped with thermal overload protection that trip-
ped the compressor off occasionally because of the 100°F. weather
conditions. It was necessary to allow the thermal overload protec-
tion to cool for a while to permit an automatic reset. The compres-
sor was kept in the shade to minimize the overload shut-off problem.
An extension cord with larger wire size would also have been helpful
The 1 HP compressor was selected since it could be operated
off of a 15 amp, 110 volt household circuit. Most conventional
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-4-
air atomizing spray guns require a 4 to 5 HP compressor to
supply a single spray gun. This is much too large for a
110 volt household circuit and a compressor that large would have
to be operated with a gasoline engine. Industrial plants with cen-
tral air compressors would easily supply sufficient compressed air
for continuous operation.
When painting metal gutters and downspouts, it was necessary
to reduce the paint flow-rate by reducing the fluid pressure since
these smooth surfaces required far less paint. The same thing
could be accomplished by moving the spray gun much faster.
LIMITATIONS
Operating with a one quart pressure cup required frequent
filling and slowed down production. The cup would also supply air
instead of paint when aimed on an upward angle. This prevented
spraying of eaves and the ceiling of porches. The pressure cup
also added a lot of weight to the gun and made it less manueverable.
The extra weight made the gun more tiring.
The above problems could be corrected with a pressure cup
supported from the belt of the sprayer. A larger pressure tank could
be-left on the ground or attached to the air compressor dolly. The
paint would be fed through a fluid hose to the spray gun. This would
cause a static pressure head reduction of 0.4 to 0.5 PSI for every
foot of increase in elevation of the spray gun above the paint pres-
sure tank. When a sprayer operates on a ladder or scaffolding, he
will have to increase the paint tank pressure by about 0.4 to 0.5
PSI for every foot he is above the paint tank. This will be needed
to deliver the same amount of paint to the gun and maintain produc-
tion speed. The pressure will have to be reduced by the same amount
when the sprayer returns to ground level. A small fluid pressure
regulator mounted on the gun would permit the operator to adjust
the fluid delivery to suit his needs.
When we ran out of paint with the pressure cup, the spray
gun could spit. While this was not a problem in the house painting
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-5-
project, it would be a problem for automotive refinishing. A si-
phon cup would not cause a similar problem but it cannot be used
with the CFA 740 hand gun. All conventional air guns that operate
with a paint pressure tank would have the same problem.
For production maintenance painting, we would recommend a
minimum of a 2 gallon paint pressure tank to avoid running out of
paint frequently- The paint can be purchased in one gallon cans
with an empty spare can purchased simultaneously. By splitting a
gallon of paint into two one gallon cans, there is then room for
adding water or thinner. The entire one gallon can can be placed
into a 2 gallon pressure tank and avoid getting the pressure tank
dirty.
A spray gun cannot be used to paint to the edges of windows
without coating the window as well. This problem was solved by mask-
ing the windows and aluminum frames with newspaper and masking tape.
CONCLUSIONS
The CFA 740 hand spray gun is an excellent maintenance paint-
ing tool. It will compete successfully against brushes and rollers
by providing greater paint mileage and by operating at higher speeds.
It will also apply a higher quality, more uniform finish. The gun
complies with all of California's environmental code requirements.
The CFA 740 hand spray gun can handle most of the contract
painting work currently done with airless spray equipment. Equipment
requirements are greatly simplified. The gun is far more flexible
than an airless gun. It permits infinite adjustment of paint flow-
rate to provide the production speed desired. The spray pattern
is fully adjustable. Quality of atomization and applied film thick-
ness can be controlled with precision. Engineering extremes such
as extremely small orifices and extremely high pressures are avoided.
The CFA 740 hand gun moves spray painting away from a black art and
into an exact science category.
ARVID C. WALBERG CMfgE
FT O I
-------
f,
-------
FOR BETTER OR FOR WORSE
BETTER YET, BUY A CFA 740!
•TO
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TECH TALK
Reprinted from November 1982 issue of INDUSTRIAL FINISHING
« 1982 HITCHCOCK PUBLISHING COMPANY
ALL RIGHTS RESERVED
How to Spray Plastic and Wooden
Products Electrostatically
By Arvid C. Walberg, President
Arvid C. Walberg & Co., Downers Grove, IL
Nonconductive surfaces can be
sprayed electrostatically without the
pretreatment normally used to make
the surface electrically conductive. The
basic law of electrostatic painting
requires two electrodes in the system:
one to impart a charge (usually nega-
,tive) to the spray particles and another
(usually grounded) to attract the paint
particles for deposition. Both elec-
trodes must be electrically conductive
to make the system work properly. This
basic law cannot be repealed, but it can
be bent somewhat to accomplish desir-
able results.
By spraying nonconductive products
electrostatically with waterbome coat-
ings the desired results can be
achieved. The charging electrode will
be the spray device, preferably an air-
atomizing electrostatic spray gun. We
suggest air guns because airless guns
lack the flexibility needed in automatic
systems, and electrostatic atomizing
devices such as disk and bell systems
do not atomize conductive waterborne
coatings as well as similar nonconduc-
tive solventborne materials. The paint
particles are given a negative charge
with the electrostatic gun.
Because the waterbome coatings
are electrically conductive, an electrical
feedback to the paint source will occur,
and it is necessary to isolate the paint
source from ground. The system would
otherwise short out, eliminate the elec-
trostatic field and make the system
spray nonelectrostatically. Isolating the
paint source from ground is very safe,
and, in fact, the overall safety is greatly
improved because waterborne coatings
are not a potential fire hazard.
The charging electrode is more or
less conventional. The collecting elec-
trode functions in a nonconventional
manner, however. Nonconductive prod-
ucts, such as the plastic shutters in the
photo, start out essentially at ground
potential so there is an initial attraction
for negatively charged spray particles.
The initial attraction of waterborne
Automatic electrostatic spray guns apply waterbome coating to polystyrene window shutters
without first applying a conductive pretreatment.
coating material makes the surface of
the shutter electrically conductive
through the paint film itself. A painted
path to the grounded metal hanger is
quickly completed and provides a direct
path to ground. This bleeds off the elec-
trical charge, and the electrostatic coat-
ing process continues in approximately
the same manner as for a grounded
metal product.
The waterborne coating greatly sim-
plifies the electrostatic spraying of plas-
tic and wooden products by eliminating
costly pretreatment. Painting costs are
reduced by about 50% compared to
conventional nonelectrostatic spray
equipment. In a typical installation coat-
ing plastic shutters, the viscosity of the
waterborne coating is very high—30-
to 60-sec range in a Zahn No. 2 cup.
After electrostatic painting, a 2-min
flash is provided ahead of the bake
oven. The parts are in the bake oven
for 4 min with an oven temperature of
71 to 76C (160 to 170F). Higher tem-
peratures would cause permanent
warping of the plastic parts.
Three minutes after leaving the bake
oven, two shutters are placed back-to-
back and covered with clear heat-
shrink plastic. The packaged shutters
< • f • r
are then placed immediately into car-
tons for shipment. E3
Arvid C. Walberg is president of two
manufacturing businesses: Arvid C.
Walberg & Co. and Environmental
Finishing Systems Co. Throughout his
32 years in electrostatic engineering he
has been responsible for the design of
more than 1000 automatic electrostatic
systems installed around the world. He
holds several dozen patents in the U.S.
and foreign countries for his many
innovations. An engineering graduate of
the Illinois Institute of Technology, he is
a member of the Society of
Manufacturing Engineers and a certified
manufacturing engineer in general
finishing processes.
-------
-------
'
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WALBERG #475 FLUID REGULATOR
-------
Patented, NEW design of this
handgun permits charging
of water-base paints in the gun
itself and eliminates the
awkwardness of heavy
high-voltage cables.
The Aqua-Static 100
MftlA/ ^'s 9un w't'1 'ts suPer'°r
nlwlW "conical film atomization"
• •• improves electrostatic efficiency.
AN Savings up to 50%
ELECTROSTATIC ^^
equipment.
a solvent-base gun.
HANDGUN
an
MADE ESPECIALLY
FOR WATER-BASE PAINTS
°
'Hi
Patents - 3746253, 3774844, other patents pending.
NEW from:
AWID C. I^ILBERG & CO.
2741 CURTISS STREET
DOWNERS GROVE, ILLINOIS 60515
(312) 852-5450
tfie Aqua-SMic 100
the besf there is!
-------
engineer
•ing
ELECTROSTATIC CONSULTANTS CO,
P.O. BOX 1587 / LISLE, ILLINOIS 60532
PHONE (708) 668-5027
ENVIRONMENTAL COMPARISONS
FOR
LIQUID COATINGS
Conventional Solvent Base Paint (6 Gallons per hour, one sprayer)
Conventional Air Gun at 25% Transfer Efficiency
//////
7/7777
///"///
77/7/7
77/777
run/
.
71
t
-•>%
•
25%
75% Solvent, 4 1/2 Gals.
25% Solids, 1 1/2 Gals.
t
Good Electrostatic Spray System (Cuts Paint Consumption in Half)
//////
//////
/777//
t
75% Solvent, 2 1/4 Gals.
1
25% Solids, 3/4 Gals.
t
50%
Reduction
T n \/ HP c-
in VULS
Switch to High Solids or Waterborne Paint (1 Gallon with 75% Volume
Solids Less Water) with Auto-Static AOO Electrostatic System (HVLP).
Meets all environmental requirements.
25% Solvent, 1/4 Gal.
t
75% Solids, 3/4 Gal.
94%
Reduction
In VOCs
Switching to waterborne powder slurries with Auto-Static 400 system
can reduce emissions by 100%.
r i
-------
ELECTROSTATIC CONSULTANTS CO.
P.O BOX 1587 / LiSLE. ILLINOIS 60532
PHONE (708) 668-5027
NEWS RELEASE
The Electrostatic Consultants Co. announces an enormous im-
provement in electrostatic powder coatings equipment. By combining
its Auto-Static 400 automatic electrostatic spray painting system
with powder slurries, its gains the best of both worlds! Here's
how it works:
TRANSFER EFFICIENCY
The powder is applied as a liquid in a water slurry form.
By greatly boosting the first pass transfer efficiency, the need
for reclaiming and reusing the overspray is eliminated. The cost
per square foot of surface coated is reduced by 50% or more. The
Auto-Static 400 guns operate at a higher output voltage and are
the only HVLP air electrostatic guns on the market. The atomizing
air at the air cap is well below 10 PSI air pressure and does not
sacrifice transfer efficiency, quality of finish or production speed.
QUALITY OF FINISH
A powder can be ground much finer if used in the form of a
water slur.ry. The dry powder particles are quite large and normally
ground into a 25 to 40 micron range (1.0 to 1.6 mils). Smaller
particles tend to cake and pack in dry form and become very diffi-
cult to handle. Since quality of finish is inversely proportional
to particle size, powder slurries permit a much finer grind and will
provide a much higher quality of finish. Powder can now achieve an
C r
« • c1
-------
-2-
automobile type finish.
APPLIED FILM THICKNESS
The large particle size of dry powder (1.0 to 1.6 mils)
causes the application of excessive film thickness. It is obviously
impossible to reduce film thickness to 1.0 mils if you apply 1.6
mil particles of 100% solids material. Keep in mind that the pow-
der is applied more than one layer thick. Remember that the cost
of a paint film is directly proportional to its thickness. A pow-
der slurry can be applied to half the film thickness and cuts costs
by 50% or more.
Applied film thickness can be held within 0.1 mil (0.0001")
of the desired thickness over an entire work surface with a liquid
coating. This is greater precision than can be held in the average
machine shop. Film thickness is built up with multiple thin coats.
It is also constant over the full height of the ware with the full-
stroke reciprocators . There is no interface problem with adjacent
guns coating different areas on the same work piece.
QUICK COLOR CHANGES
By eliminating the need for reclaiming and reusing overspray,
the color change time can be reduced to a few seconds. This broadens
the market to include those that must make numerous color changes
every day. Cost savings are very high over the complicated color
change techniques required with dry powder systems.
COMPUTER PROGRAMMERS
The computer programmer used with the Auto-Static 400 elec-
trostatic system uses up to 16 electric eyes scanning the ware
ahead of the electrostatic system. It programs itself to suit the
configuration of products passing on the conveyor line. Products
up to 16 different vertical dimensions and an infinite number of
"O
-------
-3-
horizontal dimensions can be mixed together on the line and sprayed
to suit.
FIRE SAFETY
Powder slurries eliminate the fire hazard normally associated
with either dry powder or solvent base coating systems. The water
in the coating prevents ignition with an open flame. The water ap-
parently prevents the temperature from rising to the ignition point.
The codes that cover "Spray Application Using Flammable and Combus-
tible Materials" no longer apply. Insurance costs will be greatly
reduced. The fire safety of a production plant is greatly improved.
FLEXIBILITY
All of the flexibility of the Auto-Static 400 liquid coating
system is retained. Waste caused by spraying at large open areas
is avoided. Four spray guns on each of two full-stroke reciproca-
tors are aimed on eight different compound angles to assure more
complete coverage on every work piece. This eliminates manual touch-
up on most products. The normal Faraday Cage effect expected with
other electrostatic equipment is overcome. Paint and labor costs
are reduced to a minimum.
The same electrostatic system will apply all three environ-
mental coatings with equal ease. This includes waterbornes, high
solids (up to 80% volume solids) and powder. It is unnecessary for
a user to make a long term commitment to one type of coating or an-
other .
CLEAR-AIRE' SPRAY BOOTHS
Clear-Aire spray booths are normally furnished with the Auto-
Static 400 electrostatic coating system as shown in attached Draw-
ing No. 1800. These booths use a roll-up filter material that
changes itself automatically as needed about 6" at a time. This
rr o
i • u
-------
-4-
assures uniform ventilation all day long.
The high collection efficiency of the filter material stops
all particulate emissions from exhaust stacks. Some of these
booths have operated with high solids coatings for 5 to 7 years with-
out requiring cleaning of exhaust plenums, stacks or fans.
The thorough filtering action permits recycling 80% of the
exhaust air back into the spray booth. This cuts the heating bill
for exhaust air by $5000 for a 10' high booths per year in Northern
Illinois. This is with a single shift operation. They also cut the
size and cost of make-up units needed on new installations.
As indicated above, the national codes covering "Spray Appli-
cation Using Flammable and Combustible Materials" no longer apply
if waterborne paint or water slurries of powder are applied.
The 80% recycling spray booth is designed to provide suffi-
cient ventilation to stay below 25% of the LFL (Lower Flammable
Limit) when conventional solvent base paint is used at the full
production capacity of 100 square feet of surface coated per minute.
This is also assuming 25% solids and 75% solvent in the paint. The
LFL is further reduced by 94% when switching to a 75% volume solids
environmental paint. At the same production capacity, the vapor
concentration is reduced to 1.5% of the LEL.
Since there is no solvent vapor produced in dry powder, sys-
tems safety is computed in a different fashion. Powder concentra-
tion shall not exceed 50% of the MEC (Minimum Explosive Concentra-
tion). This is defined as a dry powder concentraion below 0.015
oz per cu.ft. of exhaust air. By going to a water slurry, the
powder becomes very safe and it is no longer covered by codes re-
gulating "Spray Application Using Flammable and Combustible Materi-
als". This was determined by Factory Mutual Research Corporation,
Scientific Circular 804 dated 1977 covering waterborne coatings.
The Clear-Aire 80% recycing automatic spray booths meet NFPA #33
code requirements and are approved by OSHA for use with the Auto-
-------
-5-
Static 400 automatic electrostatic coating system.
ARVIO C. WALBERG CMfgE
ACW/mv
TV r.
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-------
Products Corporation
AN INDUCTOTHERM COMPANY
1715 DOGWOOD DR • CONYERS GA 3O2O7 . (4O4i 483-O915
December 3, 1991
Mr Bruce C. Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Dear Mr. Jordan:
This is in response to the National Air Pollution Control
Techniques Advisory Committee's (NAPCTAC's) request for comment
concerning the proposed Control Techniques Guideline (CTG) for
the control of volatile organic compounds (vocs) from surface
coating of plastic parts. Specifically addressed is one area of
the Miscellaneous Plastic Parts Category.
Vantage Products molds and paints decorative window shutters,
storm doors, and other building products out of polypropylene.
The material used and the conditions that the parts are subjected
to do not seem to fall within the scope of the CTG discussed at
the recent NAPCTAC meeting in Durham, North Carolina. The
enclosed report was prepared for NAPCTAC to help make you aware
of some of the unique problems encountered in our process. We
hope that you will consider this material when drafting the final
version of the CTG. Included in this package is a scale model of
one of our louvered shutters to help you to visualize th
difficulties involved in painting a shape of this complexity.
Please do not hesitate to contact us if we can provide additional
information or sources of information. Thank you for your time
and attention.
Sincerely,
Dale C. Jones
Finishing Department Manager
Vantage Products Corporation
(404) 922-6767 (FAX)
cc: NAPCTAC Committee Members
/encIosures
-------
COMMENTS ON THE
CONTROL TECHNIQUES GUIDELINE
FOR THE
CONTROL OF VOLATILE ORGANIC COMPOUNDS
FROM SURFACE COATING OF PLASTIC PARTS
SUBCATEGORY:
MISCELLANEOUS PLASTIC PARTS
prepared by:
Dale C. Jones
FOR
VANTAGE PRODUCTS CORPORATION
Ff 9
v Hj. «U-
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TABLE OF CONTENTS
INTRODUCTION PAGE 1
ADHESION PROMOTING ADDITIVES PAGE 3
PRIME COAT / TOP COAT PAGE 3
WATER REDUCIBLE PAGE 3
HIGH SOLIDS PAGE 4
RADIATION CURABLE COATINGS PAGE 4
POWDER COATING PAGE 4
UNICARB PAGE 5
1,1,1-TRICHLOROETHANE PAGE 5
MOLDED-IN COLOR PAGE 5
CHROMATE SOLUTION TREATMENT PAGE 7
CORONA DISCHARGE PAGE 7
PLASMA TREATMENT PAGE 7
FLAME TREATMENT PAGE 7
ULTRAVIOLET TREATMENT PAGE 7
MECHANICAL ABRASION PAGE 8
SUPPRESSED SPARK TREATMENT PAGE 8
MECHANICAL SYSTEMS PAGE 8
CONCLUSION PAGE 9
INDEX PAGE 11
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Introduction:
It has been recommended that the Control Techniques Guideline
(CTG) for the coating of miscellaneous plastic parts be included
as a subset of the CTG for Business Machines and Electronics.
This document is intended to provide information that may be
helpful in formulating the CTG for those who mold and coat
polypropylene (PP) and polyethylene (PE). Because of the very
low surface energy of these materials, they are extremely
difficult to successfully paint. However, they are relatively
inexpensive, have good mechanical properties, and are easily
recyclable. There are a number of sources of recycled PP and PE,
and utilizing them reduces solid waste volumes.
Our industry (the manufacture of plastic window shutters, storm
doors, and other miscellaneous building products) primarily uses
polypropylene, so that will be the focus of this paper. When it
comes to coatings, it is generally true that what holds for
polypropylene is also applicable to polyethylene. Since these
products are designed for exterior application, the painted
finish must have outstanding adhesion to the substrate and must
have the durability to last for years without chalking, fading,
loss of gloss, or other undesirable characteristics.
Polypropylene parts intended for interior use only (some computer
housings, office furniture, etc.) are not subjected to the same
environmental extremes and so the integrity of the finish is
somewhat less critical.
In theory, reducing the emission of Volatile Organic Compounds
'.II
-------
(VOCs) can be accomplished by either lowering the VOC content of
the coating or by utilizing some mechanical means of removing the
VOCs from the exhaust stream. The principle of source reduction
holds that it is better not to have the VOCs present to start
with, so the coating alternatives will be discussed first.
There are two primary methods by which a paint film is held to a
substrate; mechanical bonding and electrical bonding. Mechanical
bonding takes place when the surface of the substrate is
dissolved very slightly by one of the solvents in the paint.
When the solvent evaporates and the surface subsequently
resolidifies, the interface zone between the part and the coating
is blurred. This is analogous to welding two pieces of metal
together; both pieces melt at the joint, the molten metals mingle
together, and when they solidify the two pieces have effectively
become one. Electrical bonding, on the other hand, takes place
on the molecular level. The electrical attraction between polar
molecules binds the paint to the substrate. Generally speaking,
this is not as effective as mechanical bonding but for some
substances it is the only method that works. Polypropylene has
excellent resistance to chemicals (automobile batteries and
laboratory ware are often made of PP) and is unaffected by most
solvents. Mechanical bonding of the paint will not happen.
Unfortunately, the surface energy level of PP is very low and
electrical bonding does not readily occur either. Various
methods have been tried to promote adhesion, with varying degrees
of success. Either the paint must contain some element that
increases adhesion, or the parts must be pre-treated in some way
-------
to increase the surface energy level.
Adhesion promoting additives;
A Chlorinated Polyolefin (CPO) additive has been used in coatings
for PP quite successfully as an adhesion promoter. Eastman
Chemical is one manufacturer of CPO, and supplies it in
industrial quantities to formulators of coatings. The
disadvantage to CPO is that no one has been able to create a
stable emulsion of it with water, hence a solvent based paint is
necessary. These coatings typically contain 4 1/2 Ibs./gal. of
VOC and up.
Prime coat/top coat
It is possible to apply a very thin prime coat of solvent based
material containing CPO, followed by a topcoat of low VOC water
reducible paint. Testing has shown that this system can be made
to perform adequately under ideal conditions. Unfortunately, the
combined VOC content of the prime coat and the water reducible
top coat can be equal to that of one coat of solvent based paint.
Also, if any areas of the part are missed by the prime coat the
paint will fail to adhere in those areas when exposed to exterior
conditions. It would probably be impossible to detect this
defect until parts started failing in the field.
Water reducible:
As noted above, a water based paint that combines the necessary
attributes of adhesion to PP and durability has not been
developed. The market for such a specialty coating is very
small, and there is little incentive for the major coatings
-------
manufacturers to spend a great deal of lab time on such a
project.
Hiqh solids:
High solids paints are subject to roughly the same limitations
imposed by CPO as water reducible ones. The solvent (hence VOC)
content of the coating must be high enough to maintain a stable
solution. Thirty five to forty percent volume solids appears to
be the upper limit.
Rad iat ion curable coatings
Radiation curable coatings can often be formulated with no VOC
content whatsoever. They rely on the energy supplied by non-
ionizing electromagnetic radiation (often ultraviolet light) to
promote crosslinking of the polymer chains in the resin system.
This method of "drying" does not rely on either solvent
evaporation or auto-oxidative chemical reactions. The two
problems associated with radiation curable coatings that would
affect our industry are the inability of the radiation to
penetrate some opaque colors, and the difficulty/impossibility of
focusing the radiation on randomly shaped three-dimensional
objects.
Powder coating;
Powder coating is another non-VOC finish that is used extensively
in the coating of metal parts. The temperatures and time of
exposure to such temperatures required to cure the parts makes it
unsuited for use with most thermoformed plastics, including PP.
-------
Unicarb:
Still in its experimental stages is the Unicarb system invented
by Union Carbide. It relies on the ability of carbon dioxide to
become supercritical at moderate temperatures and pressures. A
supercritical substance exhibits some of the properties of a
liquid and a gas simultaneously, and it can be used to dilute a
very viscous coating without the use of additional solvents. The
process involves the use of equipment that, for the most part,
hasn't been developed yet. There is at least one pilot plant in
North Carolina working on coating furniture, but the indications
are that this technology is still years away from becoming
viable .
1,1,1-trichloroethane:
There have been some solvents that are not considered VOCs, most
notably 1,1,1 trichloroethane. It was not thought to initiate
smog-causing chemical reactions, and so was exempted from VOC
regulations by many states. Recent evidence suggests that it is
a large factor in ozone depletion in the upper atmosphere, and
its use is being phased out over the next several years. No safe
substitute for its use in paint has been developed yet.
Molded-in color:
Finally, there may be products that could be molded in the
appropriate color instead of painted. Unfortunately, PP tends to
degrade when exposed to the ultraviolet component of sunlight
unless protected by a coat of paint. There are additives that
will stabilize PP against such degradation, but they are far more
expensive than painting. Using such additives in recycled PP is
-------
not recommended by any of the manufacturers, since there is no
way of knowing precisely what is in the plastic and what effect
these stabilizers might have. In addition, one of the most
important benefits of our shutters and storm doors is that the
customer can paint over the original coating with any good
quality exterior house paint. They would not be able to do this
if the part was purchased with the color molded in, as there is
no paint that we are aware of available on the retail level that
will adhere to PP -
To date, technology has not yielded a coating for polypropylene
that provides the necessary performance qualities and also a low
VOC content. The closest approach that we are aware of has 3 1/2
Ibs./gal. of VOC (after subtracting exempt solvents) and is
formulated with 1,1,1-trichloroethane. Since this appears to be
an environmentaly unfriendly solution, it will not be available
for long. The alternative to including adhesion promoters in the
coating is to pretreat the surface of the part in some way to
raise energy levels to the point where existing coatings will
adhere. The traditional ways of doing this include:
1. Chromate solution treatment
2. Corona discharge
3. Plasma treatment
4. Flame treatment
5. UV treatment
6. Mechanical abrasion
7. Suppressed spark method
-------
Chr ornate solution treatment:
Chromate solution treatment involves dipping the parts in a
solution of 5% potassium dichromate and 95% concentrated sulfuric
acid. The mixture must be replaced from time to time, and is
inherently environmentaly unfriendly.
Corona d ischarge:
Corona discharge involves exposing the parts to an electrical
halo produced by a high voltage, high frequency generator. Ozone
is produced as a by-product. Often used to treat webs of film,
it is not suitable for three dimensional objects.
Plasma treatment:
Plasma treatment is similar to corona discharge, but also
involves a vacuum chamber and the introduction of gasses, such as
argon, tetrafluoromethane, and nitrogen. It is a batch process
and is not compatible with a continuous assembly operation due to
the slow speeds involved.
Flame treatment:
Flame treatment is the process of passing the part through an
oxidizing flame to activate the surface. The main problem is
lack of uniformity in treating an awkwardly shaped object.
Additives in the plastic can negate the effects of the treatment.
Ultraviolet treatment;
Ultraviolet treatment is accomplished by treating the plastic
with benzopherone and then exposing the surface to UV radiation.
Again, the problem is treating three dimensional objects, and the
7
r;:_7
-------
effects of additives in the plastic.
Mechanical abrasion:
Mechanical abrasion is done with sandpaper or abrasive blasting.
The reliability factor is low, and the same problems with three
dimensional parts and additives are encountered.
Suppressed spark treatment:
Suppressed spark treatment involves conveying the parts to be
treated through a dielectric tunnel containing a high energy
electric field. The resulting discharge creates a corona effect,
and is similar in application to the corona discharge method.
Ozone is created as a by-product. The limitations include speed
of treatment and the composition of any additives that might be
in the plastic. The parts must also be meticulously cleaned.
The systems that might be applicable to our products and
processes include flame treatment, mechanical abrasion, and
suppressed spark. We have performed extensive testing using
these methods in conjunction with a wide variety of low VOC water
reducible coatings, and have been unable to produce acceptable
results. None of the above reliably or consistently treated all
of the required surfaces of the parts, and accelerated weathering
tests showed consistent failures. The equipment and paint
manufacturers agreed that some of the problem is due to the
complex shape of the parts, and some is probably due to unknown
(and unpredictable) additives and mold release agents present in
the recycled and reprocessed polypropylene materials used.
Mechanical systems;
-------
Since no viable alternatives presently exist for VOC reduction
through coatings technology, abatement equipment was studied. A
total of sixty four manufacturers of systems designed to remove
VOCs from an exhaust stream were contacted and asked to submit
proposals for the installation of their systems. Installed
purchase price, yearly maintenance costs, and power consumption
figures were requested. Quotes were received for carbon
adsorption units (both steam and nitrogen stripped), thermal
oxidation (recuperative and regenerative), catalytic oxidation,
and refrigeration systems (liquid nitrogen, Rankine cycle, and
Brayton cycle) to condense VOCs from the exhaust stream.
Refrigeration was quickly discounted as an option. Based on
36,000 CFM of exhaust and a loading of 81 Ibs./hr. of toluene
(for an equivalent vapor partial pressure of 0.132 mm Hg), a
temperature of (-140 degrees F.) would be necessary to reduce the
volume percent of toluene to approximately 7 ppm. The operating
costs alone would be prohibitive. The other systems averaged
about $1,000,000 to purchase and install, with operating costs
projected to be in excess of $50,000 per year. A capital expense
such as this is beyond the ability of many small companies to
manage and remain competitive.
Conclusion:
In summary, we have determined the following:
1. The technology does not yet exist to produce a truly low
VOC coating for polypropylene that combines the requisite
adhesion and durability under naturally occurring conditions of
-------
environmental stress.
2. Pretreatment of the parts to maximize adhesion of
existing coatings is not reliable enough or effective enough to
be a viable option.
3. Mechanical systems to remove VOCs from the exhaust stream
exist, but are priced beyond the reach of smaller companies.
Manufacturers of polypropylene building materials must represent
a very small percentage of all of the coaters of plastic parts,
but to require the same controls as recommended for manufacturers
of computer housings or toys would not be fair; it could in fact
have a crippling effects on our industry. We would welcome the
opportunity to review the Control Technology Guideline before its
final promulgation, and would be happy to supply any additional
information that might be of use to the NAPCTAC committee.
Sincerely,
Dale C. Jewries
Finishing Department Manager
Vantage Products Corporation
c.c. NAPCTAC Committee Members
10
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INDEX
Abatement, 9
Abrasion, 6, 8
Acid, 7
Additives, 3, 5, 7, 8
Adhesion, 1, 2, 3, 6, 9
Adsorption, 9
Argon, 7
Atmosphere, 5
Auto-oxidative, 4
Benzopherone, 7
Bonding, 2
Brayton, 9
By-product, 7, 8
Carbide, 5
Carbon, 5, 9
Catalytic, 9
Chalking, 1
Chlorinated, 3
Chromate, 6, 7
Coatings, 1, 3, A, 6, 8, 9, 10
Compounds, 1
Corona, 6, 7, 8
CPO, 3, 4
Crosslinking, 4
CTG, 1
Degradation, 5
Dichromate, 7
Dielectric, 8
Dioxide, 5
Eastman, 3
Emission, 1
Emulsion, 3
Evaporation, 4
Fading, 1
Flame, 6, 77 8
Furniture, 1, 5
Hg, 9
Manufacturers, 4, 6, 8, 9, 10
NAPCTAC, 10
Nitrogen, 7, 9
Non-ionizing, 4
Oxidation, 9
Oxidizing, 7
-------
Ozone, 5, 7, 8
Plasma, 6, 7
Polar, 2
Potassium, 7
Powder, 4
Pretreatment, 10
Rad iat ion, 4, 7
Rankine, 9
Recuperative, 9
Recyclable, 1
Recycled, 1, 5, 8
Reduction, 2, 9
Refrigeration, 9
Regenerative, 9
Smog-causing, 5
Solvents, 2, 5, 6
Stabilizers, 6
Sulfuric, 7
Summary, 9
Supercritical, 5
Tetrafluoromethane, 7
Toluene, 9
Trichloroethane, 5, 6
Ultraviolet, 4, 5, 7
Unicarb, 5
UV, 6, 7
"*. o
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A- /
MOTOR VEHICLE MANUFACTURERS ASSOCIATION
of the United States, Inc.
7430 SECOND AVENUE, SUITE 300 • DETROIT, MICHIGAN 48202 • AREA 313-872-4311
TLXNO. 1009770 AUTOMAKERS DET. • FAX NO. 313-872-5400
Thomas H. Hanna December 11, 1991
President & Chief Executive Officer
Mr. Bruce C. Jordan
Director, Emission Standards Division
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
Dear Mr. Jordan
The Motor Vehicle Manufacturers Association of the United States, Inc. made a
presentation to the National Air Pollution Control Techniques Advisory Committee (NAPCTAC)
meeting on November 20, 1991, commenting on the Environmental Protection Agency (EPA)
draft Control Technique Guidelines (CTG) on plastic parts painting. We were pleased to find
that some of our concerns were already being addressed by EPA and we hope that our comments
will be seriously considered.
Enclosed is a copy of the text that is a companion to the presentation which provides
much more detail than the outline used in the presentation.
At the suggestion of Mary Jane Clark, we are forwarding a copy of this document
directly to each of the members of NAPCTAC.
Sincerely,
Eugene A. Praschan
Manager, Emissions and Control
cc: NAPCTAC Members
James Berry EPA
Robert Nelson NPCA
MEMBERS:
CHRYSLER CORPORATION • FORD MOTOR COMPANY • GENERAL MOTORS CORPORATION • HONDA OF AMERICA MFC INC
NAVISTAR INTERNATIONAL TRANSPORTATION CORP. • PACCAR Inc • VOLVO NORTH AMERICA CORPORATION
-------
COMMENTS TO UNITED STATES
ENVIRONMENTAL PROTECTION
AGENCY'S NATIONAL AIR
POLLUTION CONTROL TECHNIQUES
ADVISORY COMMITTEE
REVIEW OF OCTOBER 1,1991 DRAFT
SURFACE COATING OF PLASTIC PARTS
CONTROL TECHNIQUES GUIDELINE
DURHAM, NORTH CAROLINA
NOVEMBER 20, 1991
Motor Vehicle Manufacturers Association
of the United States, Inc.
-------
My name is Joseph F. Lennon, Principal Facility Environmental Control Engineer, Environ-
mental Quality Office, Ford Motor Company. I am here to speak in behalf of Motor Vehicle Manu-
facturers Association of the United States, Inc. (MVMA) to address our industry's concerns with the
draft Surface Coating of Plastic Parts Control Technique Guideline (CTG). MVMA is in support of
the comments presented by the National Paint and Coating Association (NPCA). MVMA member
companies with automobile plastic parts coating facilities located in Michigan worked with NPCA
member companies and Michigan Department of Natural Resources in the four year development of
Rule 632 and believe that rule represents a model for the plastic parts coating CTG for all the rea-
sons stated in the NPCA presentation.
The MVMA comments will address concerns of importance to users of the painted plastic parts and
related to the draft CTG. These concerns include the following:
• Inadequate number of coating categories
• Importance of need for compatible coalings in paint systems
• Sensitivity to time required in coating approval process
• Quality coatings to provide acceptable appearing paint finishes
• Coatings that are durable to avoid customer repainting
• Coatings that will not cause increased warranty costs
• RACT control requiring add-on controls
• Recognition of specialty coatings
Each of these concerns will be briefly addressed below. In addition, several comments
specifically related to the draft CTG document will be included.
Categories of Coatings.
NPCA comments have addressed the need for additional categories of coatings for plastic
parts. Much time was expended during the development of Rule 632 in an effort to determine how
best to regulate the wide range of plastic/coating combinations that exist in plastic parts components
for automobiles. After extensive discussion, the categories listed in Rule 632 were determined to be
the best way to regulate the automobile plastic parts coating industry.
The draft CTG is significantly different from Rule 632 in that two categories have been
eliminated or moved into categories that are more restrictive in VOC content. These categories are
air dry coatings and unique colors (such as reds and blacks) that need allowance for higher VOC
content due to technical limitations. As appropriately described in Section 3 of the draft CTG, there
are a number of plastic substrates (such as acrylonitrile-butadiene-styrene, polycarbonate and
polybutylene terephthalate, polycarbonate, acrylic) that limit the coatings to cure at lower tempera-
tures (at or below 194 F). These are referred to as air dried coatings. The draft CTG ignores this
important category of coatings and places them in the same category as high bake coatings. The
coating formulations designed for these plastic substrates typically require higher quantities of VOC
in order to allow the painted parts to retain the required performance characteristics.
-------
The draft CTG should allow for a higher VOC content for certain color coatings such as the
reds and blacks. The higher VOC emissions from red and black coatings result from chemical
interactions that occur with the resins that are used in these coating colors. These issues have been
addressed by the NPCA/MVMA work group which submitted a lengthy document to EPA on Sep-
tember 17, describing the need for the air dried coating category and for VOC content credit for red
and black coatings. EPA should consider these documents before deciding on final CTG VOC
content emission limits.
The VOC limits in the CTG appear not to recognize cure volatiles generated under Method
24 analysis. As footnoted in Rule 632, when Method 24 is used to determine VOC content of the
coating, then the applicable VOC limit is to be increased by 0.5 pounds of VOC per gallon.
Paint Systems.
The coating of a plastic part typically requires two or more paint layers to make up a total
paint system for specific plastic materials in order to achieve acceptable performance, considering
both initial appearance and functional durability properties. The CTG must recognize that even
though suppliers may have lower VOC primers for a given plastic substrate or lower VOC color
coatings, the combination may not be compatible.
In other words, one cannot necessarily take the lowest VOC content prep-coat, primer,
basecoat, clearcoat and have a paint system that will meet all the performance/appearance require-
ments that the coated plastic part must meet. The VOC content of the different coating categories
may vary in order to design a coating system that is compatible for the needs of the plastic part being
coated.
MVMA believes the CTG does not account for the fact that paint coating systems are de-
signed using compatible coating types rather than looking at the lowest VOC content coating in each
coating type and expecting them to perform as a functional coating system. MVMA does support
reduction of VOC content of coatings by reformulation for RACT level control that is reasonable to
achieve.
Approval process.
The automobile companies require a very extensive and time-consuming approval process
for acceptable coating usage on automobiles. There are numerous criteria that coatings must meet to
be approved for use on the product. Some of the approval tests are very lengthy in time (such as
exposure to sun tests, salt tests, etc.).
Rule 632 has already driven coating suppliers to initiate research and development in refor-
mulation of coatings to meet the lower VOC content coating limitations contained in the Rule.
Coatings that have been developed as a result of that research are currently in different phases of the
approval process. The VOC content values listed in Table 5-1, Level 1 control would require the
suppliers to go back and incur additional costs for research and development to reformulate coatings
• r-
-------
which are already reaching their limits to achieve the lowest VOC content for an approvable coating.
In addition, the approval process would have to begin anew for any new coatings that may result
from the reformulation to a lower VOC content.
MVMA believes the VOC content values in Table 5-1, Level 1 would require duplication in
time and costs for both the research and development and the approval process efforts that have been
underway to meet Rule 632 VOC content limits. This could jeopardize the availability of having
approved coatings for production.
Quality.
The automobile industry competes in the world market place. Foreign built automobiles
have placed great pressure on the domestic automobile manufacturers to be competitive on initial
appearance and quality of the paint finish. One of the major indications of quality that a customer
sees when he first views a car in a dealer showroom is the appearance and condition of the paint
finish. The paint quality must meet customer expectations! Obviously, it is critical that the appear-
ance of the metal and plastic parts match each other. Coatings that are reformulated to meet RACT
values in this country must be developed to avoid inferior quality characteristics. MVMA is con-
cerned that reformulated coatings to achieve the VOC content values included in Table 5-1, Level 1
control may fail to provide adequate perceived quality paint finish on the automobile.
Durability.
The durability of the automobile paint is expected to withstand the washing, waxing, weather
elements, etc. for a time period of at least 7-10 years. Paint durability of plastic parts must withstand
normal owner maintenance practices while retaining color-match between plastic and metal compo-
nents and acceptable paint appearance. If the draft CTG were to lead to the premature use of paint
that does not meet durability requirements, then repainting may be necessary. Obviously repainting
results in more overall VOC emissions than would occur with an initial but durable paint application.
The need to repaint the automobile could cause the customer to avoid purchase of that vehicle
nameplate in the future. MVMA believes paint durability could be adversely affected as a result of
reformulated coatings to a lower VOC content.
Warranty.
Warranty complaints are a major concern to the automobile companies. Warranty issues can
be a costly problem in terms of customer loyalty as well as financial considerations. Reformulation
of coatings that are already on the cutting edge of technology in order to meet Rule 632 VOC con-
tent levels may lead to an increase in warranty complaints and subsequent loss of customers.
MVMA believes warranty complaints would increase with reformulated coatings to meet the VOC
content limits proposed in Table 5-1, Level 1 control. Further, even if the technology should be-
come available, warranty complaints could increase because new coatings may have to be rushed
into production prior to completion of all testing required for full approval.
- r-ry
-------
Add-on Controls.
The VOC content limits in Rule 632 represent RACT for plastic parts painting processes.
Rule 632 provides for reformulation of coatings and requires the use of advanced application equip-
ment which, in effect, reduces the actual VOC emission rate and could result in an overall environ-
mental impact to be equivalent to those shown in Table 5-1, Level 1. However, Table 5-1, Level 1
VOC content emission limits for exterior coatings would require add-on control technology resulting
in a significant economic impact on all automobile plastic parts coatings facilities.
One of the primary objectives in the development of Rule 632 was to recognize an appropri-
ate RACT VOC content limit for plastic parts coatings that would not require add-on control equip-
ment, but rather a value that would result in forcing technology toward development of reformulated
coatings. The reason for this approach was a recognition of the many small job shops conducting
plastic parts coating operations for the automobile industry. Retrofitting add-on controls on existing
coating facilities is costly and could result in forcing many smaller facilities out of business. The
VOC content limits contained in Rule 632 substantially met that objective.
The draft CTG contains VOC values in Table 5-1, Level 1, that do not appear technically
achievable through reformulation of the coatings. Therefore add-on controls would be the only
method available to achieve these VOC content coating limits. Despite a number of technically
questionable assumptions in determining the cost of add-on controls (i.e., all available VOC emis-
sions assumed to be captured for control; assumption that normal VOC destruction efficiency for
incinerator is 98%), cost per ton for VOC removal are considered to be very high for RACT control.
MVMA is aware of LAER (Lowest Achievable Emission Rate) permit reviews where costs for VOC
removal in the $25,OQO/ton range were considered excessive for the LAER source. The costs for
add-on control equipment in the draft CTG (even with technically questionable VOC levels) exceed
costs in some LAER permits.
Specialty Coatings.
The automobile plastic parts coating operations include a large number of specialty coatings
(such as, adhesive prime, electrostatic prep, resist, stencil, texture, vacuum metalizing, gloss reducer,
etc.) that are designed for unique purposes. These coatings usually consist of a high VOC content
but generally are not used in large volumes and are not conducive to reformulation to lower VOC
content levels. Rule 632 included an exemption for these specialty coatings. MVMA recommends
that the CTG include either an exemption for these coatings as was done in Rule 632 or provide
specific VOC content values that are reflective of these specialty coatings.
Additional Comments.
The following additional comments are made regarding specific concerns in the draft CTG:
• Table 3-4, pages 3-30 thru 3-41. The transfer efficiency (TE) for high volume, low pressure
(HVLP) applicators is assumed to be 50%. MVMA test data shows that this value is too high.
Obviously TE is contingent on many factors including part design but test data for coating
" •'"*' P1
^O
-------
bumpers with HVLP's show about a 32% TE. Page 3-42 of the CTG states that HVLP's and
electrostatic applicators yield 50% without any basis or explanation for that value. The test
data from the same bumper coating operation which combines the use of HVLP's and electro-
static applicators demonstrated an overall TE of about 32%.
• Section 5.1.1. This section states that there are three points of VOC emissions in the coating
of plastic parts (spray booth, flash-off areas and curing oven). However, there are other related
sources of VOC emissions from automobile coating operations - such as, the water pits, paint
supply tanks and building vents. Future tests are expected to lead to a greater knowledge of the
VOC emission points encountered during the coating of plastic parts. It is inappropriate for the
CTG to use the assumption that 100% of the VOC available in a plastic parts coating operation
is captured for control purposes.
• Section 7.3.2. MVMA recommends that in operations where both plastic and metal parts are
being coated, the least restrictive coating limitations should apply.
• Section 7.8.3. The last sentence in this section suggests performance tests may be required
every "6 months or quarterly". This is unreasonable, impractical and costly. MVMA recom-
mends that performance tests may be conducted after major breakdowns or where significant
portions of the control equipment have been replaced.
This concludes the MVMA comments.
{19
fj
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£30
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1.0 U.S. ENVIRONMENTAL PROTECTION AGENCY'S PRESENTATION
ON THE OFFSET LITHOGRAPHIC PRINTING
CONTROL TECHNIQUES GUIDELINE
1.1 PRESENTATION
INTRODUCTORY REMARKS
My name is Donna Lee Jones. I am with Radian Corporation,
the contractor on the Offset Lithographic Printing Control
Techniques Guideline. I would also like to introduce Karen
Catlett, the EPA Work Assignment Manager on this project.
INTRODUCTION TO THE CTG
(Slide 1)
In the next few minutes I will present to you a description
of the offset lithographic printing industry, the sources of VOC
emissions and possible control strategies, and the results of
EPA's regulatory analysis.
(Slide 2)
It may be possible to characterize the graphic arts industry
into 5 types of printing, of which offset lithographic printing
is one. The printing types can be characterized in the following
ways:
(1) Rotogravure has recessed images.
(2) Flexography and letterpress have raised letter/images.
(3) Offset lithography has chemically differentiated image
and non-image areas.
(4) All printing types use direct printing except offset
lithography, which uses indirect printing.
In offset lithography, the letters or images are not raised
or depressed surfaces, but are chemically differentiated so that
the image area is oil-receptive and accepts the oil-based inks
and the non-image area is water-receptive and does not accept the
inks.
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The CTG and this presentation will only address offset
lithographic printing.
There is currently a New Source Performance Standards for
publication rotogravure and a CTG for graphic arts (rotogravure
and flexography); a National Emissions Standard for Hazardous Air
Pollutants for all printing types is under development.
Some example products of offset lithographic printing are
items that we use everyday, such as: advertisements, business
forms, cereal boxes, greeting cards, telephone directories, and
newspapers. However, this list is by no means complete and these
products are not limited to the offset lithographic printing
process only-
(Slide 3)
There are 16,500 offset lithographic printing facilities in
non-attainment areas that contribute 378,000 tons VOC; 1,500 of
these facilities have the potential to emit over 100 tons per
year.
(Slide 4)
Inks, fountain solution, and cleaning solutions are the
major sources of VOC emissions in Offset Lithographic printing.
THE OFFSET LITHOGRAPHY PRINTING PROCESS
(Slide 5)
The following is a schematic of an offset lithographic
printing unit, this unit is for illustration only, and is not
intended to exactly replicate a true printing unit.
A unit is the smallest complete component of a printing
press and can print only one color. Up to 12 units can be used
in a row, and multiple colors can be printed. The substrate is
usually paper or cardboard; web or sheet.
Fountain solution wets the non-image areas of the printing
surfaces so that the ink stays where it is supposed to. Fountain
solution is a mixture of water, non-volatile printing chemicals,
and an (liquid) additive that reduces the surface tension of
water so that it spreads across the printing plate surface.
Isopropyl alcohol (a VOC) is the most common additive and is the
source of VOC emissions in the fountain.
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Heatset inks require the addition of heat, via hot-air
dryers, to set. The VOC's emitted are due to the hydrocarbon
oils contained in the inks. Non-heatset inks set by oxidation or
adsorption without the use of heat. Most of the VOC's in non-
heatset inks are retained by the substrate.
One of the issues we considered with non-heatset inks was
what ultimately happens to the VOC's in the substrate. Although
no VOC's are expected to be emitted in the normal handling of the
products, the waste handling methods may regenerate the VOC's.
We found that there were three possible outcomes for non-heatset
printed material: landfill, municipal waste combustion, or
recycling. Most paper goes to a landfill at the moment and only
some is recycled. It has been estimated that only 7 percent of
paper products go to a municipal waste combustor. We have
considered the "ultimate fate" of non-heatset products in these
waste handling methods and have concluded that large potential
sources of VOC's from these waste handling methods will be
controlled and therefore we have not addressed this issue in the
CTG.
Cleaners are used to clean printing surfaces, ink, and
fountain rollers and press exterior surfaces. Most traditional
cleaning products are 100 percent VOC.
MODEL PLANTS
(Slide 6)
Based on these printing characteristics we have divided the
industry into four segments (heatset web, non-heatset web (non-
newspaper), non-heatset sheet, newspaper (non-heatset web)),
according to the distinguishing features that I have just
mentioned:
Whether the press uses dryers (heatset) or not (non-
heatset) ;
The type of substrate: sheet-fed (sheet feed) or web
(web substrate); and
Newspaper (nonheatset-web) printers were placed in a
separate industry segment since the newspaper printing
process does not use alcohol.
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Emissions of VOC's are from inks (due to hydrocarbon oils),
fountain solutions (due to alcohol), and cleaning solutions (due
to the solvents).
At least four facility sizes were used for each industry
segment for a total of 18 model plants in each of the four
industry segments.
EMISSION CONTRIBUTIONS
(Slide 7)
Using the model plants, the relative VOC emissions of each
industry segment were calculated to demonstrate the potential
emissions of one plant. This analysis does not take into account
the number of plants in each segment of the industry.
This table shows the emissions of large uncontrolled model
plants in each industry segment relative to each other. Non-
heatset sheet ink emissions were set equal to 1, for comparison
purposes only.
For instance, the VOC emissions from the fountain solution
in the non-heatset sheet model plant are 100 times the ink
emissions.
For ink emissions, heatset web, as expected, has the highest
potential emissions.
For the fountain solution, the web processes have the
highest amount of emissions. The emissions in the web processes
are greater than any other source from the fountain solution and
are greater than the total emissions of the other two industry
segments.
Cleaners are the second largest source of emissions in all
but one of the segments (heatset web).
The next slide shows how the distribution facility sizes and
number of facilities effects the emissions profile.
(Slide 8)
We used the model plants to estimate the baseline VOC
emissions in non-attainment areas. These estimates were obtained
by multiplying the emissions of a particular size model plant by
the number of facilities of this size estimated to be in non-
attainment areas from industry surveys and population data.
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In this estimate we have taken into account add-on controls
used in the heatset industry and the use of alcohol replacements
in all industry segments, including the newspaper industry.
From this we learned that approximately 2/3 of the emissions
are from web and less than 1/3 from sheet-fed, with newspaper
contributing less than 1 percent of the total.
This slide differs from the previous slide because it takes
into account the size distribution of facilities of each industry
segment within non-attainment areas.
CONTROL OPTIONS - INKS
(Slide 9)
We looked into the control of VOC emissions from the inks,
fountain solutions, and cleaning solutions. First I will talk
about the inks. We investigated the methods of controlling VOC
emissions from a dryer exhaust where heatset inks are used.
Incinerators (both thermal and catalytic) were one option;
these devices are designed to achieved 98 percent control.
Another method of control is condenser filters, which are
devices that use room air to cool and condense the hot exhaust
vapors into droplets that are filtered from the exhaust stream.
This type of control can achieve 90 percent control.
To increase the amount of control from 90 to 95 percent, an
activated carbon bed may be added to condenser filters. When
activated carbon is used, the residual emissions from the
condenser filter are collected in the carbon bed, which can be
regenerated with steam or hot air.
Since the ink needs to be water-repellent, water soluble
inks were not an option we considered. Reformulation to lower
VOC inks does not produce significant VOC reductions, since, as
discussed earlier, the majority of the VOC is retained by the
substrate.
(Slide 10)
We have estimated the annual costs of these options for the
model plants. Shown here are the largest and smallest model
plants for the heatset web industry. Reductions range from 22.2
to 24.2 tons per year for very small facilities; 178 to
5
635
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193.8 tons per year for large. The percentage of VOC's reduced
range from 90 to 98 percent. The costs range from $50,000 to
$73,000 for very small facilities; and from $230 to 336,000 for
large plants. The cost-effectiveness of the controls ranges from
a low of $1,300 for every ton of VOC removed per year for large
facilities to $3,000 per ton for very small facilities.
(Slide 11)
The EPA staff recommendations for control are 95 percent.
All staff recommendations have not been through final review by
the EPA. The rationale for choosing 95 percent, is that this
level gives a high degree of control while allowing for
flexibility in control options (three).
One of the available options that is particularly desirable
is a condenser filter with carbon, since these devices do not
generate nitrous oxides and the recovered VOC's can be used as a
fuel for the dryer.
Add-on controls are already being used by over 60 percent of
the heatset facilities (incinerators = 48 percent and condenser
filters = 13 percent). This information came from a 1990 web
offset survey.
CONTROL OPTIONS - FOUNTAIN SOLUTION
(Slide 12)
The options for control of VOC's from the fountain solution
address the issue of alcohol use; the more alcohol that is used,
the more VOC's that are emitted into the atmosphere.
Refrigerating the alcohol does help, since colder
temperatures reduce the evaporation rate of alcohol.
Alcohol substitutes are available that also reduce the
surface tension of water. Alcohol substitutes also have a lower
volatility than alcohol and are used in smaller amounts;
therefore, VOC emissions are reduced significantly when they are
used.
From an uncontrolled baseline estimated to be 17 percent
alcohol in the fountain solution, we considered four types of
emission reduction techniques to reduce VOC emissions from the
fountain solution: reduce alcohol concentration, refrigerate the
636
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fountain solution, a combination of reduction and refrigeration/
and the use of alcohol substitutes.
Many printers already have switched to alcohol substitutes
to lower the exposure of their employees to the fugitive
emissions of alcohol.
Although some printers feel that alcohol substitutes are
less forgiving than alcohol in some situations in terms of
achieving the same quality product, we have found that many
facilities have achieved good quality products with training of
employees, management commitment, and good press maintenance.
From surveys of the industry we found that alcohol
substitutes are used successfully in all types of printing.
(Slide 13)
The emission reductions with the various options range from
41 to 93 percent for the three categories: reduce alcohol
concentration, reduce and refrigerate the fountain solution, and
use alcohol substitutes.
Reduction to 10 percent alcohol is estimated to be give a
low of 41 percent reduction in VOC emissions from the fountain
solution and the use of alcohol substitutes gives 93 percent
reduction in VOC emissions, which is the highest.
Moving down the list you will notice that at one level of
alcohol, e.g. 3 percent alcohol which is 82 percent control, the
same level of control can be achieved with refrigeration (82
percent) but with a higher level of alcohol (6 percent).
Alcohol substitutes achieve at least 93 percent reduction,
however, only when the baseline is 17 percent alcohol.
Care must be taken, however, because some, but not all, of
the alcohol substitutes or non-alcohol additives contain one of
the 190 hazardous air pollutants that are listed in Title I of
the new CAAA.
(Slide 14)
Here are the EPA staff recommendations for the reduction of
VOC emissions from the fountain solution. The required level of
control will be based on whether the facility: is a newspaper
facility, uses web as a substrate, is a large sheet-fed facility
637
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(defined to have a total of 24 or more units in the entire
facility), or has fewer than 24 sheet-fed units total.
Since the newspaper industry is already using non-alcohol
additives, this is the level of control they need to maintain.
The 93 percent control doesn't really correspond to the newspaper
industry because non-alcohol additives have been used by this
segment of the industry for a long time.
The recommendations for the other types of printing were
based on the fact that, theoretically, alcohol substitutes can be
used by all segments of the industry. But, since alcohol may be
needed for some specific jobs, we have allowed the use of a small
amount of alcohol for web facilities, equal to 1.6 percent
alcohol, 3 percent alcohol with refrigeration or higher (i.e.
alcohol substitutes).
Sheet-fed facilities are known to have a unique problem with
reducing alcohol due to the fact that this process has many stops
and starts and resetting of the presses, which leads to a greater
need for alcohol. Therefore, we have allowed the use of more
alcohol for sheet-fed facilities, equal to 3 percent alcohol.
Because the smaller sheet-fed facilities are less likely to
be able to cope with the changes necessary to significantly
reduce alcohol and switch to alcohol substitutes, we have allowed
the other sheet-fed facilities (with less than 24 units) an even
greater operational flexibility, to use a slightly higher level
of alcohol than the large sheet-fed facilities, equal to 6
percent alcohol.
Through surveys of the industry we have found facilities in
all these categories that are using little or no alcohol and
producing quality products.
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(Slide 15)
The VOC emission reductions ranged from 0.8 to 696 tons per
year, for small to large model plants, respectively. For each
recommendation there was one option that produced a savings due
to reduction in alcohol costs.
CONTROL OPTIONS - CLEANING SOLUTION
(Slide 16)
We looked at the options for cleaning solutions and found
that the lower VOC cleaners (less than 100 percent) formed two
groups: 75 percent and 30 percent VOC. We looked at these two
groups of competitive products that reduce the amount of VOC's in
cleaners. However, when we compared the ingredients in the
cleaning solution to the 190 Hazardous Air Pollutants in the new
CAAA, we ruled out the 25 percent reduction level (75 percent
VOC) because most of the cleaners appeared to contain one or more
of the Hazardous Air Pollutants.
Therefore, the EPA staff recommendation for control of VOC's
from cleaning solution is the 70 percent reduction cleaners
(30 percent VOC).
(Slide 17)
The VOC emission reductions with this control ranged from
0.8 to 39 tons per year, for small to large model plants
respectively. The costs ranged from $550 to $24,000 over the
cost of traditional cleaners. The cost-effectiveness was
$629 per ton of VOC removed.
NATIONAL IMPACT OF CONTROL RECOMMENDATIONS
(Slide 18)
Using the model plants and the estimated distribution of
facilities in ozone non-attainment areas, we again calculated the
potential VOC reductions from all three sources of emissions (by
multiplying model plant emissions by the number of facilities in
non-attainment areas times the percent uncontrolled).
There were 277 thousand tons of VOC removed by the
recommended control options. This corresponds to a cost-
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effectiveness of control that ranges from $55 to $650 per ton for
an overall average of $250 per ton.
These costs do not include the potential savings due to
reduction in alcohol costs.
IMPLEMENTATION
(Slide 19)
Implementation of these recommendations would entail
compliance testing and more frequent monitoring. For the add-on
controls, the compliance tests required are EPA Method 25 or 25A,
as well as a record of the product used (heatset or non-heatset
ink). Monitoring requirements are temperature and residence time
measurements.
The fountain solution compliance requirements are a modified
EPA Method 24 test for VOC content and record of the product used
(alcohol or substitute). A hydrometer can be used to monitor the
fountain solution with alcohol only- If the fountain solution is
refrigerated, the xonly compliance test necessary is a temperature
measurement, which can also be used for monitoring.
The cleaning solution compliance requirements are a modified
EPA Method 24 test for VOC content. There are no specified
measurement techniques for monitoring the cleaning solution.
640
10
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CONTROL TECHNIQUES
GUIDELINE
Control of Volatile Organic Emissions from
Offset Lithographic Printing
NAPCTAC Meeting
Presentation
November, 1991
641
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OFFSET
LITHOGRAPHIC PRINTING
Outline of Presentation
• Definitions and Description of Industry
• Sources of Emissions
• Options Analysis
• Available Controls
• Costs of Control for the Model Plants
• Staff Recommendations
• National Emission Reductions and Costs
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GRAPHICS ARTS INDUSTRY
• Offset Lithography
• Flexography
• Rotogravure
• Letterpress
• Screen
643 2
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CONTRIBUTION OF OFFSET
LITHOGRAPHIC PRINTING
Approximately 16,500 facilities in
non-attainment areas
Approximately 378,000 tons per year of
VOC's emitted in non-attainment areas
More than 1500 facilities have the
potential to emit over 100 tons per year
emissions
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SOURCES OF VOC
EMISSIONS IN OFFSET
LITHOGRAPHIC PRINTING
• Inks
• Fountain Solutions
• Cleaning Solutions
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In-feed
Ul
Unit
Substrate
(usually paper)
Fountain
Solution
ink
Dryer
(heatset only)
Hot Air
Finished Product
Hot Air
No Dryer in
Non-heatset
OFFSET LITHOGRAPHIC PRINTING SCHEMATIC
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OPTIONS ANALYSIS
Four industry segments
• HeatsetWeb
• Non-heatset Web (non-newspaper)
• Non-heatset Sheet
• Newspaper (non-heatset web)
Each of the three emission sources was
analyzed separately
18 model plants were used to characterize
the industry
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RELATIVE VOC EMISSIONS
BASED ON
LARGE MODEL PLANTS
Industry Inks Fountain Cleaners Total
HeatsetWeb 1000 3000 100 4100
Non-heatset Web 50 4000 100 4150
Non-heatset Sheet 1 100 100 200
Newspaper 160 60 300 520
648^
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ESTIMATED NATIONAL
VOC EMISSIONS IN
NON-ATTAINMENT AREAS
Number of Baseline
Facilities VOC
Industry in Nonattainment
Segment Areas
Heatset Web
Non-heatset Web
Non-heatset Sheet
Newspaper
Total
400
1,000
15,000
300
16,700
Emission
(TRY)
142,000
136,000
97,000
2,000
377,000
MnHol Plant * Facilities in
Emisions = E±,fonS x Non-attelnment x % uncontrolled
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CONTROL OPTIONS
FOR INKS
* Add-on controls to the dryer exhaust
Device Percent Control
Incinerators (thermal and catalytic) 98
Condenser filters with activated carbon 95
Condenser filters 90
Waterborne inks are not an option
Reformulation was not a significant
control option
G50
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COST OF CONTROL OF VOC
EMISSIONS FROM INK
Model
Plant
Very
Small
Large
Type of Control
Equipment
Incineration
Condenser/Filter with
Carbon
Condenser/Filter
Incineration
Condenser/Filter with
Carbon
Condenser/Filter
Reductions
Tons/yr
24
23
22
194
188
178
Total
Percent
Reduced
98
95
90
98
95
90
Estimated
Annualized
Costs
$73,000
$69,000
$50,000
$336,000
$290,000
$230,000
Cost
Effectiveness
$/ton
$3,000
$3,000
$2,300
$1 ,700
$1,500
$1,300
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STAFF RECOMMEDATIONS
FOR INKS
95 percent reduction of VOC in the
dryer exhaust
• thermal incinerators
• catalytic incinerators
• condenser filters with carbon
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OPTIONS FOR THE
FOUNTAIN SOLUTION
1. Reduce alcohol concentration from an
industry average of 17 percent (by volume)
2. Refrigerate fountain solution
containing alcohol to below 60°F
3. Combinations of 1 and 2
4. Replace the alcohol with substitutes
653 1:
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FOUNTAIN SOLUTION
OPTIONS
Reduce Alcohol
Alcohol Percent VOC
Concentration Reduction
10% 41
6 67
3 82
1.6 90
Refrigerate Alcohol
Alcohol Percent VOC
Concentration Reduction
17% 44
10 67
6 82
3 90
Use Alcohol Substitutes
Alcohol Percent VOC
Concentration Reduction
0% 93
(554i3
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STAFF RECOMMENDATIONS
FOR FOUNTAIN SOLUTION
Newspaper
r_r_.
Use of non-alcohol additives control
Web
The equivalent of 1.6 percent VOC (by volume)
• 1.6 percent (by volume) alcohol, or 90%
• 3 percent elcohol with refrigeration Control
Large Sheet-fed
The equivalent of 3 percent VOC (by volume)
• 3 percent alcohol, or 82%
• 5 percent alcohol and refrigeration control
Other Sheet-fed
The equivalent of 6 percent VOC (by volume)
• 6 percent alcohol, or 67%
• 10 percent alcohol with refrigeration Control
S551(
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EMISSION REDUCTIONS
AND COSTS FOR
FOUNTAIN SOLUTION
• 0.8 to 696 TPY for the model plants
Costs
• Savings
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OPTIONS FOR
CLEANING SOLUTIONS
25 percent VOC reduction
• 75 Percent VOC (by weight), as used
70 percent VOC reduction
• 30 Percent VOC (by weight), as used
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EMISSION REDUCTIONS
AND COSTS FOR
CLEANING SOLUTION
• 0.8 to 39 TRY
Incremental Costs
• $550 -$24,100 per year
• $629 per ton of VOC removed
17
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NATIONAL IMPACT OF
RECOMMENDED OPTIONS
Facility Type
Heatset Web
Non-heatset Web
Non-heatse Sheet
Nev paper
Total
Number of
Facilities in
Nonattainment
Areas
400
1,000
15,000
300
16,700
Total VOC
Emissions
Removed (TRY)
125,000
91 ,000
60,000
700
277,000
Cost*
Effectiveness
($/ton)
$288
$55
$350
$650
$250
*Excludinc the large savings in alcohol costs
.659.
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IMPLEMENTATION
Control/Emission
Reduction
Technology
Compliance
Monitoring
Add-on Controls
EPA Method 25 or 25A test
Records of product used (heatset or nonheatset ink)
Temperature
Residence time
Fountain Solution - Modification of EPA Method 24 test for VOC content - Hydrometer
- Records of product used (alcohol or substitute) (alcohol only)
Refrigeration
- Temperature measurement
- Temperature
Cleaners
- Modification of EPA Method 24 test for VOC content
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CONTROL TECHNIQUES
GUIDELINE
Control of Volatile Organic Emissions from
Offset Lithographic Printing
Appendix
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OFFSET
LITHOGRAPHIC PRINTING
A process where the image and non-image
areas are on the same plane and are chemically
differentiated so that the image area is oil
receptive and the non-image area is water
receptive
A process that transfers the printing image to an
intermediary surface, which, in turn, transfers
the image to the printing substrate
,-2
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EXAMPLE INDUSTRY
PRODUCTS
• Advertisements
• Books
• Business Forms and Brochures
• Catalogues
• C areal Boxes
• G reeting Cards
• L ibels and Wrappers
• haps
• Pharmaceutical Instructions
• Telephone Directories
• Newspapers
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DEFINITIONS
Unit
The smallest complete component of a printing
press; each unit can print only one color
Press
A printing production assembly that can be made up
of one or many units to produce a
finished product
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TWO TYPES OF SUBSTRATES
Web
A continuous roll of paper used as the
printing substrate
Sheet-fed
Printing paper that is fed to the press in
individual sheets
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TWO TYPES OF PRINTING
Heat-set
Printing inks that require the addition of heat
to set
Non-heatset
Printing inks that are set by oxidation or adsorption
without the use of heat. Most of the VOC's in
non-heatset inks are retained by
the substrate
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ULTIMATE FATE OF
NON-HEATSET INKS
Landfill
Municipal Waste Combustion
Recycling
G G 7^.7
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FOUNTAIN SOLUTION
Fountain solution wets the non-image areas
so that ink stays within the hydrophobic
image areas
A mixture of water, non-volatile printing
chemicals, and an (liquid) additive that
reduces the surface tension of water.
Isopropyl alcohol (a VOC) is the most
common additive
Alcohol substitutes are available that replace
the alcohol and reduce VOC emissions from
the fountain solution.
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CLEANING SOLUTION
Used to wash printing surfaces, ink and
fountain rollers, and press exterior surfaces
A-9
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MODEL PLANTS AND
ESTIMATED ANNUAL VOC
EMISSIONS (tons per year)
Model
Plant
Cod*
A-l
A-ll
A-lll
A-IV
B-l
B-ll
B-lll
B-IV
C-l
C-ll
C-lll
C-IV
0-1
D-ll
D-lll
D-IV
D-V
D-VI
Size
Very Small
Small
Medium
Large
Very Small
Small
Medium
Large
Very Small
Small
Medium
Total
Printing
Units
4-6
6-16
12-32
32-48
4-6
6-16
12-32
32-48
1 -4
2-8
8-24
Large 24-48
Very Small
Small
Medium
Medium Large
Large
Very Large
6
8-10
9-24
18-48
40-96
100-120
Ink
Use
77
170
340
618
77
170
340
618
1
2
6
13
10
48
138
477
1088
2156
VOC
Emissions
25
54
109
198
1
3
5
9
0.01
0.02
0.1
0.2
0.2
1
2
7
16
32
Fountain Solution
Additive
Use
70
153
306
556
97
212
425
773
1.2
2.3
7.5
17
0.7
3.4
10
33
76
151
VOC
Emissions
70
153
306
556
97
212
425
773
1.2
2.3
7.5
17
0.5
2.5
7
25
57
113
Cleaning Solution
Use
2
5
11
20
2
5
11
2
1
2
8
17
2
5
8
16
34
55
VOC
Emissions
2
5
11
2
2
5
11
2
1
2
8
17
2
5
8
16
34
55
Total
Annual
VOC
Emission
97
213
426.
774
100
220
441
802
2
4
16
34
2
9
17
48
107
200
670
A-10
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NATIONAL IMPACT OF
CONTROLS ON VOC
EMISSIONS BASED ON
MODEL PLANT ANALYSIS
Modal Plant
Typa
A
Facility Size
1
II
III
IV
Subtotal
B
1
II
III
IV
Subtotal
C
1
II
III
IV
Subtotal
0
1
II
III
IV
V
VI
Subtotal
Total
Number of
Facilities In
Nonattalnnwnt
Areas
41
63
153
152
409
70
240
567
204
1,090
6.634
5,910
1.301
858
14.703
188
42
19
10
4
2
265
16,497
Total VOC Emissions (TRY)
Baseline
2.859
9.616
40.730
83.628
142,435
2.010
15,841
71,726
46,896
136,473
14.515
37.673
17,960
26,718
96.867
427
317
302
438
385
358
2,227
378,001
Removed
2.500
8,408
40.730
73,519
125,157
1,345
10,460
47.741
31.226
90.773
9,840
17,628
12,167
19.756
59.391
197
132
109
115
95
77
725
276,046
After
Control
359
1,208
5.602
10,109
17,278
666
5,381
23,984
15.669
45.700
4.676
20.045
5.793
6.962
37,476
229
184
193
323
291
281
1.501
101,955
(571
A-11
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TELEPHONE (7O8)-295-1 331
FAX (7O8)-295-0732
RESEARCH LABORATORIES, INC.
990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
LAKE BLUFF. ILLINOIS. 6OO44
October 22, 1991
Mr. Bruce Jordan
Director
Emission Standards Division
United States Environmental Protection Agency
Office of Air Quality Planning & Standards
Research Triangle Park, NC 27711
Dear Mr. Jordan:
As president of Rosos Research Laboratories, Inc. and manufacturer of the
original alcohol replacement, RV 1000, in 1970, I have the benefit of over 21
years of experience in the area of pressroom alcohol elimination. Rosos1
motivation in the early 1960's to eliminate isopropyl alcohol stemmed from
pressmen's complaints of headaches and nausea caused by fugitive alcohol
emissions and variations in color stability and print quality relative to alcohol
evaporation fluctuations. We are proud to be the pioneering proponents of
alcohol elimination and in that spirit, completely support the premise of the
"Offset Lithographic Printing Control Techniques Guidelines". Please permit
me to compliment you and the Radian Corporation team for presenting a well
researched, definitive CTG. Since public comment is solicited on page 1 2 of
the draft, I feel compelled to bring several issues to your attention which
unless clarified could create confusion in an industry which is anxious to
comply with all federal and state Control Techniques Guidelines.
Since 1950, Rosos has specialized exclusively in fountain solutions and alcohol
free dampening technology. Consequently, my remarks will be limited to this
area. The first issue is one of semantics. Most printers are familiar with the
terms, "alcohol replacement" or "alcohol substitute" with reference to
products containing 75 - 78% butyl cellosolve or glycol ether based wetting
agent. "Non alcohol additives" is a rather unfamiliar term to most printers, but
one which is frequently utilized throughout the draft. This term may tend to
confuse some printers who might consider non-alcohol additives to be
different in chemical make up than alcohol substitutes or replacements.
On page 2 - 8 and again on page 5 7 the erroneous notion is put forth that "All
of the fountain solution, including the water, evaporates after delivery to the
printing plate because of the heat and work of the system on the solution; no
•water or alcohol are disposed of." This is true for alcohol only; water, fountain
solution and wetting agents or alcohol substitutes become emulsified in the ink
at whatever percent or ratio the ink is designed to pick up water. In addition,
some dampening chemistry is transferred beyond the plate to the inking
train, or the blanket and eventually the substrate in all offset operations.
Emulsion of ink and water is. the lithographic process.
O
72
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TELEPHONE (7O8)-295-1 331
FAX (7O8)-295-0732
RESEARCH LABORATORIES, INC.
990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
LAKE BLUFF. ILLINOIS, 6OO44
The next is the issue of failure to delineate the distinction between two step
and one step alcohol elimination. Alcohol replacements or substitutes are
mixed at a 0.5 - 3% or 1 - 4 ounces ratio per gallon of water and all require the
addition of fountain solution at 1 2% to desensitize non-image areas of the
plate. This is commonly known as the two step method of alcohol elimination.
On page 3 - 40 a "one step" solution is vaguely mentioned.
As the formulator of the original one step solution and the person who coined
the phrase, I would like to offer the following definition. A one step solution is
a natural Sudanese Gum Arabic based formulation which incorporates 9%
wetting agent (usually a member of the glycol ether group) in the concentrate
product as the requisite alcohol replacement. One step solutions are
recommended to be run at 3% concentrations or 0.27%, by weight, VOC's of
press ready dampening chemistry on brush systems; or 4 5% concentrations
on continuous dampening systems, (note the figure illustrated by page 3-21
or 3 - 29), or 0.36% 0.45% by weight VOC's of press ready dampening
chemistry. One steps eliminate the need for 15 25% alcohol on web and
sheetfed presses and are monitored by conductivity to determine
concentration of fresh solution.
One step solutions offer the lowest achievable level of VOC's in press ready
dampening chemistry with the exception of the latest generation of totally
non-hazardous, VOC free "one step" formulations (R.O. #50, R.O. #50 D3)
developed by Rosos from 1988 1991.
On page 5 - 7 a formula for calculating alcohol replacements or "non-alcohol
additives" is postulated. Since no formula for one step solutions is currently
provided, I would like to suggest the following:
VOC emissions from = weight of VOC x 0.09
one step solutions (or % as specified on M.S.D.S.)
On page 5 - 11 the erroneous notion that "one pound of alcohol substitute
replaces approximately ten pounds of alcohol" is completely misleading.
One may say that 1% alcohol substitute is the functional equivalent of 10%
alcohol in terms of reducing surface tension, but since the weight per pound
of alcohol substitute and alcohol are not identical and alcohol is fugitive in the
absence of refrigeration, the formula
weight of = weight of alcohol
substitute 10
is not accurate. If only a very approximate cost comparison is required, please
state that fact.
In addition, the one step solutions are not even considered in a comparison
despite their successful performance for over eleven years!
673
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TELEPHONE (7O8)-295-1 331
FAX (7O8)-295-O732
RESEARCH LABORATORIES, INC.
990 NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
LAKE BLUFF. ILLINOIS. 6OO44
I would like to quote Gary Jones of GATF who approximated that a web offset
heatset press could easily exceed 100 tpy VOC's. Based on that, one might
estimate the following VOC comparison:
20 25% alcohol
o r
alcohol free
2 step method
or
alcohol free
one step method
o r
R.O. #50 D3
= 71 91,000 pounds VOC's
= 11,000 pounds VOC's
= 2,000 pounds VOC's
= VOC free
On page 7-7, under 7.6.1., fountain solution VOC content cannot and should not
be calculated by taking samples from trays or tanks. Only a freshly mixed
concentration of either one step or two step solution at it's recommended
concentration with printers' tap or treated water should be mixed in a control
gallon to determine VQC content bv total carbon analysis or gas
chromatograph. Tanks and pans contain ink, blanket wash, roller wash, plate
cleaner and other VOC related solvent contaminations which could distort
fountain solution VOC content. This is reiterated in the appendix of the CTG
Model Rule D5.
On page 7 9, 7.7.3 a statement is made that alcohol substitute can be monitored
by conductivity. Alcohol substitutes are non conductors and cannot be
measured either by pH or conductivity; a refractometer is required to
determine concentration. One step solutions however, may be measured as
freshly mixed solution by both pH and conductivity before recirculation tank
contamination, but only for concentration, not VOC content. VOC content
cannot be determined by any method except as percentage by weight as stated
in the Material Safety Data Sheet or total carbon analysis. Mr. Gary McAllister
concurs with me that Method 24 is not an accurate test for determining VOC
content of aqueous solutions.
pH meters are not less sensitive than conductivity meters as stated. Fountain
solution buffering may mask concentrations slightly, but again this has no
relation to VOC content.
Page D-6 (sub head D.8) requires that a press operator monitor VOC content
with a temperature compensated refractometer at least once per eight hour
shift. A refractometer is a delicate laboratory instrument, which measures
concentrations by BRIX %, not VQC's. This monitoring requirement should be
reconsidered. Record keeping of daily alcohol usage or product consumption
by weight of VOC's might be better source for monitoring VOC consumption.
Again, conductivity cannot be used to monitor VOC content.
G74
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TELEPHONE (7O8J-295-1 33 1
FAX (7O8)-295-O732
RESEARCH LABORATORIES, INC.
99O NORTH SHORE DRIVE • NORTH SHORE INDUSTRIAL PARK
LAKE BLUFF. ILLINOIS, 6OO44
In conclusion, the RACT as presented on page 2 - 14 is certainly achievable and
will probably result in most web offset printers completely eliminating
alcohol by one step or two step method since no proportioning system exists
which is capable of monitoring or consistently replenishing between 1.6% -
3% alcohol. Less than 3% alcohol would probably have a negligible affect on
reducing surface tension during high speed web offset operation.
Limiting smaller sheetfed operations to 6% alcohol or 10% alcohol with
adequate refrigeration will probably encourage refrigeration. Limiting
larger sheetfed pressrooms to less than 5% alcohol even with refrigeration
will force them to make the necessary mechanical modifications, such as
softer durometer dampening form and metering rollers, to facilitate
minimizing alcohol consumption and compensate for some of that
"forgiveness"' which 25% 35% alcohol provided in the past. They too will be
motivated to running alcohol free which is readily achievable with
management commitment and supplier technical support. A list of sheetfed
and web printers who have operated alcohol free has been provided to Heather
Brown of Radian. Some of these printers have as much as twenty years
experience in alcohol free operation.
Rosos commends E.P.A.'s efforts to establish CTG's which are realistic,
attainable, and the only responsible means of preserving our air quality for
generations to come. To answer the criticism of alcohol elimination affecting
print quality or productivity, National Geographic, a publication which sets
standards of excellence, has a 12 year record of alcohol free quality and
productivity in its Corinth, Mississippi, web offset pressroom. Eleven million
quality impressions are produced monthly to the satisfaction of both publisher
and printer. It is also encouraging to note that Heidelberg/Harris, one of the
world's largest press manufacturers, is demonstrating its commitment to run
alcohol free with a one step solution at 4% at web offset speeds of 2000 FPM at
its own Customer Support and Training Center in Nashville, Tennessee.
Rosos will continue its commitment to advancing not only alcohol free
technology, but VOC free dampening chemistry for the future. R.O. #50 D3, our
latest VOC free formulation, is currently being utilized by such leading
printers as Holladay Tyler for Smithsonian Magazine, and divisions of R.R.
Donnelley & Sons which indicates VOC free chemistry and outstanding print
quality can coexist successfully. In closing, I would like to congratulate you
on your CTG, and thank you for your consideration of my comments and
suggestions.
675
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A REPORT TO
THE NATIONAL AIR POLLUTION CONTROL
TECHNIQUES ADVISORY COMMITTEE
U. S. ENVIRONMENTAL PROTECTION AGENCY
DURHAM, NORTH CAROLINA
NOVEMBER 20, 1991
PAUL L. MARTIN
C. A. ENTERPRISES, LTD.
ID
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I am Paul Martin, Vice President-Product Development, C. A. Enter-
prises, Ltd. Sioux City, Iowa.
For several years I have been involved with magnetic treatment
of water used for heating and cooling in residential and commercial
uses. This multi-pole magnetic treatment is a chemical free system
for the control of lime scale and corrosion in all types of water
using equipment.... from small humidifiers to the largest of boilers,
cooling towers and heat exchangers.
While there are many things that are not fully understood, it is
a known fact that a properly designed multi-pole magnetic field
will provide several desirable effects in water-using vessels that
are designed for the transfer of heat.
By altering the configuration of the magnetic fields, by changing
their strength and/or spacing, various results'can be accomplished.
One of these results is to make the water passing through these
fields become more soluble.
At the urging of a large manufacturer of printing presses, this
technology was applied in developing a non-chemical method that
would lower the surface tension of the water in a fountain solution
and thereby act as a wetting agent....thus reducing the reliance
on isopropyl alcohol (C3HgO) in the printing process.
The manufacturer of these magnetic units provided six "off the
shelf" units that were installed on a Harris M-1000 press in Des
Moines, Iowa. The results were very good. An immediate reduction
of 60% of alcohol was accomplished. At the time of this writing,
the magnetic units have been installed for a little over 21 months
and have saved approximately 8,100 gallons of alcohol normally
required to operate that one press. This has also been accomp-
lished without sacrificing quality, which of course, is vitally
important in the printing industry.
While these results were very gratifying, I thought we could do
better. Two new prototypes were built and, with the cooperation
of a large printer of greeting cards in Kansas City, these were
installed, one on the fountain station of the magenta unit of a
60" MAN sheet fed press and the other on the blue unit of a 38"
Toshiba web press. Both of these presses were, at the time,
G77
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(2)
operating in the range of 18% to 20% alcohol in their fountain
solutions. It was hoped that, with no other changes, the level
of alcohol could be reduced to 5% to 7%.
Two days later, it was reported that both fountain stations were
operating at "0" alcohol and the only alterations made were minute
adjustments to the nip, and a slight increase in the speed of the
water roller. Ten more units were ordered to complete the treat-
ment of these two presses. To this day, both presses continue
to operate at levels of alcohol from 0% to 3%, except when metallic
or "day-glo" inks are used. Under those conditions a slightly
higher level is needed. For Monday morning start-up, some addi-
tional alcohol is added to improve initial roll-up.
Since that time, all fountain stations for that firm have had units
installed and the plant has reduced its alcohol use from approxi-
mately 270,000# in 1989, to a projection of less than 20,000# in
calendar 1991. This represents over a quarter million pounds of
VOC's that are being prevented from entering the atmosphere each
year....a reduction of 90%.
Since those first installations, hundreds of units have been installed
on various types of presses, both heat-set and non heat-set, on
sheet fed and web presses throughout the United States and in
Canada, South America, Ireland, the United Kingdom and Japan.
The acceptance level for these units has been very high.
This unit should not be considered to be a "cure-all" for the printing
industry, but it can be a very useful tool in the effort to reduce
VOC's in the work place. If alcohol is being used to correct a
mechanical problem, such as roller durometer or minor wear, it
will be of no help. Also, some printers may be very reluctant to
give up their alcohol. However, in cases where alcohol is being
used merely as a wetting agent, reducing the surface tension of
the fountain solution can reduce that use of alcohol by an absolute
minimum of 50%, and in many cases much much more. The units are
extremely cost effective, often giving complete "return on invest-
/
ment" in less than 90 days.
I realize that while this has long been a known technology in many
other applications, it's introduction to the printing industry
-------
3)
is new, therefore at the conclusion of this report I will be happy
to answer any questions you might have about our equipment. Many
of the results we have achieved are referred to in the "Control
Techniques Guidelines" draft report prepared for this meeting,
under sections 2, 4, 5 and 6, under "Reasonably Available Control
Technology" and "Emission control Techniques".
May I say that, we at C. A. Enterprises are very proud to have
taken scale and corrosion control technology and adapted it to
develop emission control technology -
I thank this panel for their time and, as I said earlier, I will
be happy to answer any questions that you or your guests might
have.
! i
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AMERICAN NEWSPAPER PUBLISHERS ASSOCIATION
COMMENT TO THE DRAFT
OFFSET LITHOGRAPHIC PRINTING
CONTROL TECHNOLOGY GUIDELINE
NAPCTAC MEETING
NOVEMBER 19-21, 1991
DURHAM, NORTH CAROLINA
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The American Newspaper Publishers Association (ANPA) is a trade organization that
represents the publishers of about 1,350 newspapers published in North America. ANPA
maintains a technical staff of chemists, engineers, industrial hygienists and computer
scientists to provide technical expertise on matters of environmental regulations and
application of new technology.
ANPA would like to thank the EPA staff and contractor for the opportunity for
information input throughout the entire draft preparation process. Overall, the staff and the
contractor did a very good job of learning an industrial process in spite of the contradictions
and diversity of the lithographic process. However, after distributing portions of the Offset
Lithography Control Technology Guideline (CTG) to our members, the industry requested
that I provide a brief presentation at this meeting to correct several inaccuracies found hi the
CTG.
The written presentation has two parts. Part one outlines the inaccuracies and the
misconceptions about the newspaper printing process that overestimates the emissions
from the industry. The second part, not covered in today's oral presentation, are
corrections to the generalized technical information about offset printing and definitions
contained in the document.
Figure 3-1
The last bar graph should be labeled greater than 250,000 rather than less than.
Newspaper (Non-Heatset Model Plants) Table 3-4
The model newspaper shown in this table is an extrapolation of material usage from an
accurate ink consumption data that ANPA complied from a recognized industrial directory.
The projected usage of fountain solution and cleaners were estimated from ideal usage
ratios instead of empirical data and as a result overestimates or underestimates have
occurred. After seeing the proposed model, ANPA conducted a survey of material usage
by a group of newspapers that act as technical advisors to ANPA operations and projects.
The results from these 63 newspapers were used to generate a model from actual
production situations.
The proposed model (Table 3-4) in the CTG overestimates the fountain solution usage
and the amount of cleaning solution does not accurately reflect industrial practices. The
similarity between the original ink usage data supplied to the EPA and the survey's ink
consumption demonstrates accuracy of the survey data. ANPA strongly urges that actual
material usage data be incorporated into the newspaper model instead of extrapolated data.
The column heading "Annual Fountain Solution Alcohol Use Rates" is incongruous
with information provided in the text about fountain solution composition. Newspaper
printing does not use alcohol in its dampening system. The system uses only alcohol
substitutes. The word alcohol should be removed from the heading and replaced with the
term fountain solution additive.
o
I
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TABLE 3-4. NEWSPAPER (NON-HEATSET WEB) MODEL PLANTS
ANNUAL PRODUCT USE
Model Plant
Code
D-I
D-H
D-ffl
D-IV
D-V
D-VI
Size
Very Small
Small
Medium
Medium Large
Large
Extra Large
Total Units1
6
8-10
9-24
18-48
40-%
100-120
Annual Ink
Use Rates
(Tons)
2-19
15-82
67-209
125-829
529-1647
1072-3239
Annual
Fountain
Solution
Alcohol
Use Rates
(Tons)
0.1-1
1-6
5-15
9-58
37-115
75-227
Annual
Cleaning
Solution
(Tons)
3
4-5
4-12
9-24
20-48
50-59
Double Blanket.
ANNUAL USE OF PRODUCTION MATERIALS BY 63 NEWSPAPERS
VALUES EXPRESSED IN TONS
Ink3
Fountain Solution'5
Cleaning Solvent0
Very Small (n=10)d
Small (n=9)
Medium (n=15)
Med. Large (n=15)
Large (n=ll)
Extra Large (n=3)
17.4 (8.5-26.3) e
45.9 (34.7-57.1)
63.5 (42.7-84.3)
240.0 (148.1-331.9)
823(539-1107)
1835 (1250-2330)f
0.54(0.11-0.97)
1.44 (0.81-2.07)
3.01 (2.38-3.64)
13.4 (6.4-20.4)
46.2 (17.8-74.6)
85.8 (30.0-119.2)f
1.06 (0.29-1.83)
3.08 (1.80-4.36)
4.64 (3.61-5.67)
18.23 (8.0-28.5)
53.0 (12.3-93.7)
57.2 (23.8-106.2)f
a Combines color and black ink used
b Tons of concentrated fountain solution consumed—calculated using a specific gravity of 8 pounds per gallon
c Tons of cleaning solvents consumed—calculated using a specific gravity of 7.5 pounds per gallons
d Number of newspapers surveyed in each circulation class
e Mean value and numbers within parenthesis represent the statistical 95 percent confidence limit
f Since n < 7, actual range reported
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Model Plant Production Use and Baseline (Uncontrolled) Volatile Organic
Compound Emissions (average tons per year) Table 5-1
I will address only the values reported for model plant code D (newspaper printing).
Changes made in the Table 3-4 (Newspaper Non-Heatset Model Plants) to reflect actual
product usage should also be made in Table 5-1. The use of average consumption rates per
hour per unit (Appendix B Section B-l.l) will overestimate the emissions from small
newspaper operations utilizing a small press running at slower speeds and underestimate
the emissions from large newspapers that use large presses running at 2,200 feet per
minute. ANPA supports the simple emissions calculation based on material usage,
volatility of product and application of an appropriate emission factor which recognizes that
production conditions result in the retention of volatile material within the printed product
(Appendix B Section B-2.1). However, the volatility of the average products used to
calculate the uncontrolled baseline levels does not reflect the characteristics of the average
materials used in commerce. At best they represent the extremes.
INKS
The use of a 30 percent VOC ink as an average news ink is unrealistic. In 1989,
ANPA tested 31 black and 21 color news inks under the severe conditions of Method 24A.
The black inks had a mean value of 22 percent +/- 3.6 (95 percent confidence limit) and
color inks had a mean value of 19 percent +/- 3.0 (95 percent confidence limit). Later that
year a test of other offset inks using Method 24 produced a range of VOC values: black 2-
20 percent, color 2-13 percent.
In 1990, ANPA requested seven different news ink manufacturers to submit three of
their most commercially successful black ink formulation for a printing evaluation project
being conducted by ANPA. A portion of the test protocol was to test the VOC content of
the ink versus press performance. Of the 19 inks submitted for evaluation, only two inks
had VOC content greater than 18 percent (24 and 26 percent respectively) and the median
value was nine percent
These data demonstrate that a 30 percent VOC news ink would represent less than 2.5
percent of the inks used in newspaper printing. The rational for using a 30 percent value is
that it falls between the zero to 45 percent limit based on theoretical estimates of emissions
from mass balance and some limited empirical test data. The theoretical limit represents a
range of how inks can be formulated and not how the "typical" news ink is formulated.
A VOC content of 12 percent would be a more fair estimate of an average news ink.
Any value exceeding 22.5 percent (the median value of 0 to 45) can not represent the
average theoretical ink. ANPA requests that the values for ink emissions in Table 5-1 be
recalculated to reflect a "typical" ink with a volatility of 12 percent. This change should
also be made in Appendix B Section B-2.1.
ANPA requests an inclusion of an emission credit for the VOC content of waste ink that
is incinerated.
3-
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FOUNTAIN SOLUTION
In section 2.5.2, the text refers to a newspaper's fountain solution usage to vary from 1
to 150 tons. It is assumed that material as purchased is 100 percent alcohol substitute.
This assumption is erroneous and incongruous with statements made in section 3.5.2.
The newspaper industry purchases from a variety of vendors a "one-step solution"
concentrated solution as described on page 3-40. Fountain solution is defined in section
3.5.2 as "...the fountain solution is water-based. The fountain solution contains wetting
agents, acids or buffer salts to maintain the pH of the solution, small quantities of gum
arabic or synthetic resins, and a dampening aid to enhance the spreadability of the fountain
solution across the printing plate." Non-alcohol dampening aids that characterize
newspaper fountain solutions (page 3-40) "...are made up of glycols, such as ethylene
glycol, glycol ethers or 'cellosolve ethers', or proprietary compounds, and are chemically
similar to alcohol." To contain acids and buffer salts to maintain the pH of the solution and
solubilize other inorganic compounds requires that the "one-step" fountain solution
contains a significant amounts of water. Inorganic compounds are insoluble in pure
glycols and glycol ethers.
ANPA contacted three vendors that supply a significant proportion of the fountain
solution concentrate used by the newspaper industry. Each vendor provided a label that
contained mixing instructions and in some cases an abbreviated listing of contents. I have
attached copies for your review. You will note that mixing instructions are similar to those
found in the CTG. The materials sold by Rycoline list deionized water as an ingredient and
NENSCO provides the same product in a ready-to-dilute concentration and a super
concentrated form. To prepare the ready-to-dilute concentration, five gallons of the super
concentrate is added to 50 gallons of water. Since there are not instructions to add any
additional alcohol substitutes, one can conclude that the ready-to-dilute form contains about
90 percent water and the volatility would be less than ten percent by weight since the
MSDS sheets reports the presence of inorganic salts.
Analytical data support the conclusion that most fountain solution additives purchased
by newspapers contain significant amounts of water. On March 13, 1991, ANPA shared
the Method 24 results of six different fountain solution concentrates with the EPA. The
volatility of these products when water was excluded was less than ten percent
ANPA requests that values in the Table 5-1 and section 2.5.2 be changed to reflect the
chemical characteristics of the types of fountain additives used in newspaper printing.
ANPA would suggest that the values be lowered by a factor of ten. This factor assumes a
ten percent concentration of alcohol substitute in the purchase product instead of the
unrealistic 100 percent concentration assumed in the original model.
In Chapter 7 and Appendix D, the CTG advocates the use of conductivity to measure
the concentration of VOC in fountain solution. Conductivity, as used by newspapers to
maintain the dilution rate of the concentrated fountain solution, is dependent on the
inorganic compounds found in the one-step fountain solution additive and is independent of
the non-ionic and non-dielectric alcohol substitutes. However, recognition of the proper
concentration of alcohol substitutes in the concentrated fountain solution additive would
exclude newspapers from the unnecessary expense of monitoring VOC content of fountain
solution by use on a hydrometer or refractive index. Starting concentration of ten percent
alcohol substitutes and dilutions rate as high as four ounces per gallons assures that the
concentration remains below the recommended control level of 2.5 percent An addition of
-------
an exclusion for newspaper printing would be beneficial and remove confusion about the
process.
Chapter 6 outlines costs of applying a magnetic water treatment to reduce alcohol
substitute usage by newspapers. This dubious and unproven water treatment process
should not be applied to facilities that have invested in proven water treatment equipment
such as reverse osmosis or deionization. Chemical removal water treatment technology
improves print quality in areas where the chemistry of the incoming water source varies
daily. Water treatment has a minimal effect on the annual fountain solution additive usage
but has proven beneficial by making daily fountain solution additive consumption
consistent. Application of a magnetic water treatment technology that claims print quality
improvement with less fountain solution additive is only anecdotical and not supported by
empirical data. It does not justify the minimal expense outline in Table 6-8.
CLEANING SOLUTIONS
Press cleaning is a collection of diverse maintenance procedures in the newspaper
industry. Application of single type of cleaning solution to every task requires a
dependency on technology that is developing and not proven. Many of these products
contain water or caustics that may have an unknown long term detrimental effect, like
corrosion, on press equipment. The acknowledgement of low-VOC cleaners containing
D-limonene in the CTG demonstrates that some of the products being developed contain
compounds that have associated health hazards to the workers. D-limonene has a tainted
lexicological history and has been proven to cause skin sensitivity in workers after repeated
exposure. Since many of the low-VOC products are new, the quantity of a low-VOC
cleaning solution required for cleaning operations is not known and the projected reduction
in emission may not be realized because it takes more product to clean the same amount of
equipment. In other words, a one-for-one quantity substitution may not be a valid
assumption in the economic model, Table 6-9.
ANPA disagrees with the finding that low-VOC cleaning solutions would not have a
solid waste impact (Section 6.4.3).
Waste ink that may account for as much as two percent of all ink purchased is
composed of ink too contaminated with foreign material to be a usable product and cleaning
solution-ink mixture that enters a "catch pan" during the press cleaning. Any cleaning
material that lowers the BTU content or is detrimental to reclaiming a usable ink product
from waste ink creates a significant solid waste dilemma for a newspaper. For smaller
newspapers, the only economical means to dispose of waste ink is by incineration. The
price of disposal is dependent on the BTU content of the material and an increase in water
content caused by water-borne low-VOC cleaners increases the cost and limits the number
of vendors willing to handle the waste. Waste minimization by ink reclamation requires
that all non-ink materials such as solvents, water and paper fibers be removed from the
waste ink. The use of low-VOC detergent cleaners that can not removed by distillation
could disrupt the ink-fountain solution interaction and make the reclaimed ink unusable.
In a like fashion, cleaning solutions that become too dirty for reuse would either require
a larger energy input to separate them from the water content or higher disposal cost for
low BTU aqueous waste. The disposal problems related to non-volatile distillation bottoms
are unknown. Disposal options for detergent cleaners would very limited.
ANPA requests that the EPA consider the inclusion of cleaners with lower vapor
pressure that are less volatile as an alternative to concentration limit on VOC content. This
i" o c
>U dj U.
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would allow the printer the option to use the best products that minimize total waste
production and assure that all necessary maintenance operations can be performed.
ANPA requests that the EPA consider a credit for the solvent that leaves the facility on
cleaning rags. The laundry service charges an "environmental charge" for the purpose of
disposing the materials contained on the rags. In effect, the same material is being
regulated twice.
This concludes my oral presentation.
ANPA requests the following technical corrections to text contained in the CTG.
• Section 2.4.1 second paragraph: The offset Heat-set lithographic
printing industry
• Section 2.4.3.2: D-limonene does not have a lower volatility than
products commonly used. The boiling point of D-limonene is
similar to decane that is a major component of mineral spirit cleaners
• Section 3.2 first paragraph: When the image plate is made, the
image area is rendered oil receptive and water-repellant
• Section 3.3.2 second and third paragraph: For a web press the
across cylinder dimension determines the width of the product and
the around the cylinder dimension determines the length of the
product. The text has this concept reversed.
6-
-------
DISTRIBUTION OF METHOD 24 PERCENT
VOLATILE CONTENT FOR 19 COMMERCIALLY
AVAILABLE BLACK INKS IN 1990
3-
•o
o
-
o Z
-«= §
I8
~ 1
E
3
2-
1 -
12345678 9 1C 1112 1314 15 16 17 1S 192C21 222324252627282930
percent volatile
-------
IIAFHING'
CAUSES IRRITATION
A'.'OID COinACT UITH SI'III MID EVE?
A"OIO FPC'IOHC.EO OP PEFEATED FPEATHING Of HIST
PROTECTIVE EQUIPMENT
FOP NOPtlAL U:E IIEA9 PECOnnE
GLOVES MO SAFETY GLASSES
EO PROTECTIVE
FIRST AID
EVES imiEDIATELY FLUSH UITH 1IATEP FOP. flT
LESST 15 Pllll.iTE:. CONTACT LEN;ES HUST
FE PENO'.'ED C-ET MEDICnL STTEIITION
St'IN CEI'DI!E HLL CO'ITHM]'»7ED CLOTHIIIC.
IIA-H SUN UITH SOdP P!!D 1MTE"
BPEATHING
no ILL EFFECT; EJECTED FPOH UWLIHG THIS
FCOPUCT U'lLES: UHEN USED IN COflBIHATlON
UITH A SOL'.'EHT ISflfPOFVL ALCOHOL
SHOLLOUIHC-
DILUTE UITH TUO r.L^SJE? OF MATER AND
IHt'.'CE "OKIMUG GET HEOICnL OTTEHTION
E-TIMC-IJISHIIIC- MEDIA
;il c«?c nr FIFE, U:E IliTE" • CLC"?D UI'P IIATEP)
OP. CHEMK.ML. co2 CF HLCCHOL F?H."
FOR IIICU5TPIAL UrE O'i'-i
KEEP OUT OP THE PEACH OP
RYCOLJNE
SEUEN DEX
FOUNTAIN SOLUTION
PRODUCT NO. 23859
DIRECTIONS FOR USE. USE I TO 3 OZ TO ONE GALLON OF MATER FOR DESIRED RESULTS.
CONTAINS: DEIONIZED UATER CAS I 7732-18-5
OIPROPYLENE GLYCOL CAS I 25265-71-8
OlPOTASSIUn PHOSPHATE CAS I 7758-11-4
SODIUH HEXAHETAFHOSPHATE CAS I 68915-31-1
noNOPOTAssiun PHOSPHATE CAS i 7778-77-8
SPILL USE AeSOPBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
RESPONSE CONTAIN LARGE SPILL AND PUHP TO SUITABLE TANK. UASH AREA UITH
PROCEDURE: SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE KITH UATER.
FOP CHEDICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE
OR ACCIDENT, CALL CHEKTREC 888-424-9388 DAY OR NIGHT.
HASTE USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
DISPOSAL: SITE. DISPOSE OF ALL HASTES IN ACCORDANCE UITH FEDERAL,
STATE AND LOCAL REGULATIONS
READ M.S.O.S. BEFORE USING PRODUCT
RYCOLINE PRODUCTS, INC.
SMO NORTHWEST HIGHWAY. CHICAGO. IL 60830
PHONf- (312) 775-6755 • FAX (312) 775-9414
Qfl i
HHIS
HAZARD INDEX
HEALTH
FIAMMABIUTY
REACTIVITY
PERSONAL I -'• I
PROTECTION I I
STORAGE AND HANDLING
KEEP FROM FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EMPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
IIIXINC VESSEL
REHOVE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
DANGER
AFTER THIS CONTAINER
HAS BEEN EMPTIED
IT MAY CONTAIN
EXPLOSIVE AND HARMFUL
VAPOnS AND RESIDUE.
KEEP AWAY FROM HEAT.
SPARKS AMD FLAMES*
DO NOT CUT. PUNCTURE.
Ofl WELD ON OR NEAR
THIS CONTAINER
DO NOT RE-USE CONTAINER
FOR ANY PURPOSE UNTO.
COMMERCIALLY CLEANED
-------
CS
UARNING!
CAUSES IRRITATION
AVOID CONTACT UITH SKIN AND EYES.
AVOID PROLONGED OR REPEATED BREATHING OF HIST.
PROTECTIVE EQUIPHENT
FOR NORMAL USE HEAR RECOI1HEKDEO PROTECTIVE
CLOVES AND SAFETY GLASSES
FIRST AID
EYES: IMMEDIATELY FLUSH UITH HATER FOR AT
LEAST 1$ MINUTES. CONTACT LENSES MUST
BE REMOVED. GET KEOICAL ATTENTION
SKIN:
REMOVE ALL CONTAMINATED CLOTHING.
HASH SKIN UITH SOAP AND HATER.
BREATHING:
NO ILL EFFECTS EXPECTED FROM INHALING THIS
PRODUCT UNLESS UHEN USED IN COMBINATION
UITH A SOLVENT: ISOPROPYL ALCOHOL.
SUALLOUINC:
DILUTE UITH TUO GLASSES OF HATER AND
INDUCE VOMITING. GET HEDICAL ATTENTION.
EXTINGUISHING MEDIA
IN CASE OF FIRE, USE HATER (FLOOD UITH HATER)
DRY CHEMICAL, C02 OR ALCOHOL FOAJl
FOR INDUSTRIAL USE ONLY
KEEP OUT OF THE REACH OF CHILDREN
RYCOLINE
SEUEN FOUNTAIN
SOLUTION TYPE P
PRODUCT NO. 23B4I
DIRECTIONS FOR USE: USE 1 TO 3 OZ. TO ONE GALLON OF HATER FOR DESIRED RESULTS.
CONTAINS: DEIONIZED HATER CAS I 7732-18-$
DIPROPYLENE CLYCDL CAS I 252*5-71-8
DIPOTASSIUH PHOSPHATE CAS I 7758-11-4
SODIUM HEXAHETAPHOSPHATE CAS I 68915-31-1
noNOPOTASsiun PHOSPHATE CAS i 7773-77-0
SPILL USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
RESPONSE CONTAIN LARGE SPILL AND PUflP TO SUITABLE TANK. HASH AREA UITH
PROCEDURE: SUITABLE DETERGENT AND HATER AND THOROUGHLY RINSE HITH HATER.
FOR CHEMICAL EMERGENCY - SPILL. LEAK, FIRE, EXPOSURE
OR ACCIDENT. CALL CHEttTREC 888-424-9388 DAY OR NIGHT.
HASTE USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
DISPOSAL: SITE. DISPOSE OF ALL HASTES IN ACCORDANCE UITH FEDERAL,
STATE AND LOCAL REGULATIONS.
READ M.S.D.S. BEFORE USING PRODUCT
RYCOLINE PRODUCTS. INC.
5540 NORTHWEST HIGHWAY. CHICAGO. IL 60630
PHONE: (312) 775-6755 • FAX (312) 775-9414
Oft ft
HMIS
HEALTH
FLAMMABILITY 0
REACTIVITY [0
PERSONAL
PROTECTION
HAZARD INDEX
0 • Mininul
1 • Sligm
2 • Motjeialii
3 • Sflnous
4 • Seven;
STORAGE AND HANDLING
KEEP FROM FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EIIPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
niXING VESSEL
REMOVE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
DANGER
AFTER THIS CONTAINER
HAS BEEN EMPTIED
IT MAY CONTAIN
EXPLOSIVE AND HARMFUL
VAPORS AND RESIDUE
KEEP AWAY FROM HEAT
SPARKS AND FLAMES'
DO NOT CUT, PUNCTURE
OR WELD ON OR NEAR
THIS CONTAINER
DO NOT RE USE CONTAINER
FOR ANY PURPOSE UNTIL
COMMERCIALLY CLEANED
-------
c
ilHFNING'
ChUiES IRRITATION
H'JOIO tOIITHCT WITH SUN HHD EYES
AUDIO PROLONGED OR REPEATED BREATHING OF IIIST
PROTECTIVE EaUIPHENT
FOfi NOSnnL USE IIEtf RECOHNENDED PROTECT1UE
CLOUES AMD SAFETY GLASSES
FIRST HID
Ei'ES MEDIATELY FLUSH UITH UATER FOR AT
LEH3T 15 I1INUTES CONTACT LENSES MUST
BE REMOUEO GET HEOICAL ATTENTION.
SKIN. REHOUE ALL CONTAdlNATED CLOTHING
UASH SUN UITH SOAP (.NO UATER.
BREATHING
NO ILL EFFECTS EXPECTED FROK INHALING THIS
PRODUCT UNLESS UHEN USED IN COnBINATION
UITH A SOLVENT: 1SOPROPYL ALCOHOL.
SUALLOIIING
DILUTE UITH TUO GLASSES OF UATER AND
INDUCE UOIUTING. GET HEDICAL ATTENTION.
EXTINGUISHING HEDIA
Hi CASE OF FIRE, USE UATER (FLOOD UITH UATER)
DRV CHEHICAL, C02 OR ALCOHOL FOAH
FOR INDUSTRIAL USE ONLY
l-EEF1 OUT OF THE RcACh OF CHILDREN
ALKALINE FOUNTAIN
LJ Li* LJ I >L I-JI i -««j VK^ «-L O* n
PRODUCT NO
DIRECTIONS FOR USE: USE I TO 3 02. TO ONE GALLON OF UATER FOR DESIRED RESULTS
CONTAINS: DEIONIZED MATER CAS I 7732-18-5
TETRAPOTASSIUI1 PVROPHOSPHATE CAS I 7328-34-5
SODIUIt HEIAI1ETAPNOSPHATE CAS I 68915-31-1
SODIUH HYDROXIDE CAS I 1318-73-2
POLYETHEYLENE GLVCOL CAS I 25322-68-3
SPILL USE ABSORBENT ItATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL
RESPONSE CONTAIN LARGE SPILL AND PUHP TO SUITABLE TANK. HASH AREA UITH
PROCEDURE SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE UITH UATER.
FOR CHEniCAL EflERGENCY - SPILL. LEAK, FIRE, EXPOSURE
OR ACCIDENT, CALL CHEHTREC 688-424-9388 DAY OR NIGHT.
UASTE USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
DISPOSAL: SITE DISPOSE OF ALL UASTES IN ACCORDANCE UITN FEDERAL,
STATE AND LOCAL REGULATIONS.
READ M.S.0.8. BEFORE USING PRODUCT
RYCOLINE PRODUCTS, INC.
55JO NORTHWEST HIGHWAY. CHICAGO, It. 60630
PHONE: (312) 775-6755 • FAX (312) 776-9JH
QA #
HHIS HEALTH JOJ
FLAMMABILITY 0
0
HA2AHDINDEX
0 Minimal
I Sliyhl
2 MoOuidto
3 • SBIIOUS
PERSONAL
PROTECTION
STORAGE AND HANDLING
KEEP FROn FREEZING
KEEP OUT OF SUN AND EXCESSIOE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
00 NOT PUNCTURE CONTAINER
NEUER USE PRESSURE ID EtIPTY CONTAINER
00 NOT USE CONTAINER AS A DILUTION OR
NIXING UESSEL
REflOUE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
DANGER
AFTER THIS CONTAINER
HAS BEEN EMPTIED
IT MAY CONTAIN
EXPLOSIVE AND HARMFUL
VAPORS AND RESIDUE
KEEP AWAY FROM HEAT.
SPARKS AND FLAMESI
DO NOT CUT. PUNCTURE
OH WELD ON OR NEAR
THIS CONTAINER
DO NOT HE-USE CONTAINER
FOR AMY PURPOSE UNTIL
COMMERCIALLY (XEANEO
_..
-------
UARNING!
CAUSES IRRITATION
AVOID CONTACT UITH SKIN AND EVES.
AVOID PROLONGED OR REPEATED BREATHING OF HIST.
PROTECTIVE EQUIPMENT
FOR NORMAL USE UEAR RECOMMENDED PROTECTIVE
CLOUES AND SAFETY GLASSES
FIRST AID
EYES: imiEDIATELY FLUSH MITH UATER FOR AT
LEAST 15 niNUTES. CONTACT LENSES DUST
BE REMOVED. GET HEDICAL ATTENTION.
SKIN:
REHOVE ALL CONTAMINATED CLOTHING.
HASH SKIN UITH SOAP AND UATER.
BREATHING:
NO ILL EFFECTS EXPECTED FROI1 INHALING THIS
PRODUCT UNLESS UHEN USED IN COItBINATION
UITH A SOLVENT: ISOPROPYL ALCOHOL.
SUALLOU1NG:
DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION
EXTINGUISHING MEDIA
IN CASE OF FIRE, USE UATER (FLOOD UITH UATER)
DRY CHEMICAL, C02 OR ALCOHOL FOAI1.
FOR INDUSTRIAL USE ONLY
KEEP OUT OF THE REACH OF CHILDREN
RYCOUNE
flLKfiLINE Y-797 DEX
FOUNTAIN SOLUTION
DIRECTIONS FDR USE:
RESULTS.
PRODUCT NO. 28936
USE I TO 3 LIOUID OUNCES PER GALLON OF UATER FOR DESIRED
CONTAINS: DEIOHIZED UATER CAS I 7732-16-5
01PROPYLENE GLYCOL CAS < 25265-71-8
TETRAPOTASSIUH PYROPHOSPHATE CAS I 732B-34-5
SODIUI1 HEXANETAPHDSPHATE CAS I 48915-31-1
SPILL USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR DISPOSAL.
RESPONSE CONTAIN LARGE SPILL AND PUMP TO SUITABLE TANK. HASH AREA UITH
PROCEDURE: SUITABLE DETERGENT AND UATER AND THOROUGHLY RINSE UITH UATER.
FOR CHEMICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE
OR ACCIDENT, CALL CHEHTREC 868-424-9386 DAY OR NIGHT.
UASTE USE PLASTIC CONTAINERS AND DISPOSE OF IN AN APPROVED LICENSED
DISPOSAL: SITE. DISPOSE OF ALL UASTES IN ACCORDANCE UITH FEDERAL,
STATE AND LOCAL REGULATIONS.
READ M.S.D.S. BEFORE USING PRODUCT
HYCOLINE PRODUCTS. INC.
5540 NORTHWEST HIGHWAY. CHICAGO, IL 60630
PHONE: (3I2| 775-6755 • FAX (312) 775-9414
UH It
HMIS HEALTH
FUMMABIUTY
REACTIVITY
m
m
PERSONAL (X
PROTECTION
HAZARD INDEX
0 • Minimal
1 - Slight
2 • MocMi
3 • Swlwa
4-Snvw!
STORAGE AND HANDLING
KEEP FROH FREEZING
KEEP OUT OF SUN AND EXCESSIVE HEAT
KEEP CONTAINER CLOSED UHEN NOT IN USE
DO NOT PUNCTURE CONTAINER
NEVER USE PRESSURE TO EMPTY CONTAINER
DO NOT USE CONTAINER AS A DILUTION OR
niXINC VESSEL
REItOUE CAP CAREFULLY TO RELIEVE POSSIBLE
INTERNAL PRESSURE
DANGER
AMER THIS CONTAINER
HAS BFEN EMfMIFP
IT MAY CON1AIN
EXPLOSIVF Ann HAIlMriJL
VAPDMS AMP RESIOUF
KEEC AWAY f HOM HE AI
SPARKS AND flAMf SI
DO NO! CHI PUNCHiflF
on WELD ON on ME An
THIS CONTAINER
DO NOT RE USE CONTAINER
FON ANY PURPOSE UNTIL
COMMERCIALLY CLEANED
-------
Nensco
P.O. Box 544
Mlllbwy, MA 01S27-OJ48
liquid gold
Super Concentrate Fountain Solution
Contents: 5 Gallons
MIXING INSTRUCTIONS
Add 30 Gallons o( water to mixing tank. With mixer running add the entire
contents of (2) 5 Gallon containers of Super Concentrate. Then add 15 Gallons
of water to make 55 Gallons. Allow to mix for 5 minutes.
* NOTE a 27M&IW batch may be mixed by adding (1)5 Gallon contain* of Super
Concentrate to 22V* gallons ol water.
DIRECTIONS: A starting point of 2 ot/gallon or conductivity 1000 over
tap water.
CAUTION: Although no health hazard is known, It to advisable to treat
this matter with respect: Avoid eye contact Avoid prolonged
or repeated skin contact DO NOT take intemaBy.
FIRST AID: Eye* or 8Un: Rusnw«hvwter.(Eye«oriry-comartphy8Wan)
If Ingested CONSULT A PHYSICIAN, INDUCE VOMITING.
KEEPC^OT THE I^EACH OF CHILDREN. A
for Protentoral Use Only.
This product wH bo replaced R detective In manufacturing,
packaging, or labetog. Except tor such replacement,
this product to sold without warranty, expressed or
ImpBed. or labity of any kind.
Boston • Chleogo • los Angelas • Dodos • ftbonta
Nensco
P.aBoz348
Mlllbury. Mfl OJ 527-0348
liquid gold
News Dot
Fountain Solution
4-1 GAL CONTAINERS
DIRECTIONS,; A starting point of Z ozVgallon or conductivity 1000 over
CAUTION: Although no health hazard Is known, H is advisable to treat
this matter with respect: Avoid eye contact. Avoid prolonged
> repealed skin contact DO NOT take internally.
FIRST AID: Eye* or Skin: Rush with water. (Eyes only -contact physician)
If Ingested CONSULT A PHYSICIAN, INDUCE VOMITING.
KEEP OUT OF TH£ REACH OF CHILDREN.
For ProfcMfenal UM Only.
Trfcprodudvtf be replai^ Idefecth* In nwwfactu^,
narkanlnn AT Inh^llnn Cw*t*r«* CM ••»*<•% •^•••.•.^—*
Boston • Chleogo • tosflngeles • DoBos • fldonto
-------
5 GAL
Nensco
Mem fcncjiond Newspaper Supply Co.
P.O Boi 348
Military. MA 015C7-034B
ALKA-FOUNT
A1
Fountain Solution
' DIRECTIONS: '
^,;-'' |V-':; -•''-• •""•.'•'"- : 'CAUTION!:' •. . • . '-•
, 'v 4-. '« Cdnldlns Tri Potassium Phosphate Solution Avoid eye contact. Avoid prolonged or
• V •' _V repeated skin contact DO NOT take internally. The use ol protective goggles and
v ;;,1',: chemical resistant gloves Is recommendend. .... / i '
'i&l-V •- ii, ;'[,.<.• •'••. --i . •..).('. ..<;••• ..... ••"•,• • "< •'•.-' •,'1.V--'.f1": '• '• ; '• •-••'•
••d^:^,.---^ ,; •..•,':l: / i'-. : ' , -.
i-; ';-j ! ; >; Skin • Flush' with soap Ant) water. Eye* • Flush copiously with water and/or boric acid
'ti&fo. solution. IF INGESTED, administer large volumes ol water, milk, soda or other acidic
;-'Wi.,' liquids. CONSULT PHYSICIAN. KEEP OUT OF REACH OF CHILDREN.
• W^fei'^Vi.^
S^fM!i!bo^^:l^liii^?iWu^
^xstwJi^
5 GAL.
Nensco
New England Newspaper Supply Co.
p o Box 348
Millbury. MR 01527-0348
ALKA-FOUNT
A2
Super Concentrate Fountain Solution
DIRECTIONS:
Add 30 gallons of water, to mixing vat With mixer running, add the entire contents
ol (2) 5 Gallon containers of Super Concentrate. Add remaining 15 gallons of water,
to mako 55 gallons. Allow to mix for 5 minutes.
• NOTE a 27'..- qnllan bntch may bo mixed by adding 1 1) 5 Gallon container ol Super Concentrate
to 22".' gallons ol water
LOADING INSTRUCTIONS:
On press load 1 to 1 '/;> oz /gallon or as noccessary.
CAUTION!:
Contains Tri Potassium Phosphate Solution. Avoid eye contact. Avoid prolonged or
repeated skin contact. DO NOT take internally. The use of protective goggles and
chemical resistant gloves is recommendend.
FIRST AID:
Skin - Flush with soap and water. Eyes - Flush copiously with water and or bone acid
solution. IF INGESTED, administer large volumes of water, milk, soda or other acidic
liquids, CONSULT PHYSICIAN. KEEP OUT OF REACH OF CHILDREN.
Millbury, MR • Chicago 'I. • Uplrnd. CR • Dallas, "DC • flosujell, GR
-------
"The Original Alkaline Fountain Etch"
MIRACLE
CONCENTRATE
For Hard Water (up to 200 ppm)
NEVER GUM
ANOTHER PLATE,
NEVER EXPERIENCE
STRIPPING AGAIN,
AND YOU GET
BETTER PRINTING!
CORPORATION
NATIONAL HEADQUARTERS: 25111 GLENDALE AVENUE, DETROIT, MICHIGAN 48239
-------
^^ •__ ,.•,;•?.•;-... •-".:•; i- -iJ>-';!s'i-,-*v'-"-'-V.T!:-. .=..-..•
Niensco
New €oglond Newspaper Supply Co,
PO SOT 348
Neutro fount
Fountain Solution
CT
CO
cn
DIRECTIONS
A starting point of 2 ozJgallon is suggested
CAUTION!
Although no health hazard is known, It Is advisable to treat this matter with
respect: Avoid eye contact. Avoid prolonged or repeated skin contact DO
NOT take Internally.
FIRST AID:
Eyes or Skin: Flush with water. (Eyes only • contact physician) If Ingested
CONSULT A PHYSICIAN, INDUCE VOMITING, KEEP OUT OF THE REACH
OF CHILDREN.
For Professional use only. FORM NO N-NFS s/84 gw
This product will be replaced if defective in manufacturing, packaging, or
labeling. Except for such replacement, this product is sold without war-
ranty, expressed or implied, or liability of any Kind.
OXCQCP.IL - Upland Cfi • Dallas.?X • (tosmell.GR
-------
c -;
#2474
PERFECT PINK
ONE-STEP, BUFFERED
NEUTRAL FOUNTAIN SOLUTION
DIRECTIONS: PERFECT PINK has been proven effective in producing
clean, crisp newspapers and insert work with the "clean oil" and "low
rub" inks. Use 2 ounces of PERFECT PINK per gallon of water for a
conductivity of approximately 1000 mmhos over the conductivity of the
water used. It is recommended that you NOT use over 3 ounces of
PERFECT PINK per gallon of water.
2535 Ivy Street East
Gumming, Georgia 30130
ANCHOR/LITHKEMKO, INC.
50 Industrial Loop North
Orange Park, Florida 32073
(904) 264-3500
280 North Ott :
Corona. California 91720
m =
o a
2 §•
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r~ ~ 3 to
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In case of eye contact, flush with water for
15 minutes and seek medical attention.
Wash affected skin areas with soap and
water. If swallowed, induce vomiting and
seek medical attention. Contains water,
Monosodium Phosphate (CAS
#7558-80-7), TKPP (CAS #7320-34-5),
EDTA (CAS #64-02-8) and Gum (CAS
#9000-01-5).
V.O.C. - 0 Ibs./gal.
NONPHOTOCHEMICALLY REACTIVE
TARGET ORGAN EFFECTS: None known.
HEALTH
FLAMMABILITY
REACTIVITY
PERSONAL
PROTECTION
-------
#2830
AQUA MAGIC
NEUTRAL FOUNTAIN SOLUTION
DIRECTIONS: Mix fountain solution to yield conductivity of
1000 mmhos over the conductivity of the incoming water. This
will normally be obtained by using 2 ounces of fountain solution
per gallon of water.
?535 Ivy Street East
dimming, Georgia 30130
ANCHOR/LITHKEMKO, INC.
50 Industrial Loop North
Orange Park, Florida 32073
(904) 264-3500
280 North Ott Street
Corona, California 91720
r~ o o. [u <
rn ffl "> = S
UJ D — c/i >*
Z CT O - >
gns
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CAUTION
In case of eye contact, flush with water for
15 minutes and seek medical attention if
irritation persists. Wash affected skin areas
with soap and water. If swallowed, induce
vomiting and seek medical attention.
Contains water, Dipotassium Phosphate
(CAS #7758-11-4), Monopotassium
Phosphate (CAS #7778-77-0), Sodium
Hexameta Phosphate (CAS #10124-56-8)
and EDTA (CAS #64-02-8).
V.O.C.-0.1 lbs./gal.
NONPHOTOCHEMICALLY REACTIVE
TARGET ORGAN EFFECTS: None known.
HEALTH
FLAMMABILITY
REACTIVITY
PERSONAL
PROTECTION
-------
(=-73
ANCHOR
#2833
FIRST IMPRESSION
ALKALINE FOUNTAIN SOLUTION
DIRECTIONS: Use 1.5 to 2.5 ounces per gallon of water for
desired results. Conductivity should read approximately
1200-1500 mmhos above the conductivity of the water used.
TM
ANCHOR/LITHKEMKO, INC.
50 Industrial Loop North, Orange Park, FL 32073
13505 Marquardt Avenue, Santa Fe Springs, CA 90670
(904) 264-3500
C O Q. CU <
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Z CT O - >
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2 cp_ c
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Mt
IT !=i. D)
0> 3 tO
III
CAUTION
In case of eye contact, (lush with water for
15 minutes and seek medical attention.
Wash affected skin areas with soap and
water. May be harmful if swallowed. If
swallowed, induce vomiting and seek
medical attention immediately. Contains
water, Trisodium Phosphate (CAS
#10101-89-0), Sodium Hexameta
Phosphate (CAS #10124-56-8) and
Tetrapotassium Pyrophosphate (CAS
#7320-34-5).
V.O.C. - 0.07 lbs./gal.
NONPHOTOCHEMICALLY REACTIVE
TARGET ORGAN EFFECTS: May cause
eye irritation.
HEALTH
FLAMMABILITY
REACTIVITY
PERSONAL
PROTECTION
-------
c; n D. o) <
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ALKALINE FOUNTAIN
CONCENTRATE
NEWSPAPER AND INSERT
ALKALINE FOUNTAIN SOLUTION
DIRECTIONS: Use 2 ounces of concentrate per gallon of water.
Conductivity should read approximately 800 mmhos over the
conductivity of the water used. The pH of the working solution should be
approximately 10.0.
2535 Ivy Street East
Gumming, Georgia 30130
ANCHOR/LITHKEMKO, INC.
50 Industrial Loop North
Orange Park, Florida 32073
(904) 264-3500
280 North Ott Street
Corona, California 91720
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CAUTION
In case of eye contact, flush with water
for 15 minutes and seek medical
attention. Wash affected skin areas with
soap and water and seek medical
attention if irritation persists. Harmful if
swallowed. If swallowed, do NOT induce
vomiting and seek medical attention
immediately. Contains water, Solvent EB
(CAS #111-76-2) and Sodium
Metasilicate (CAS #6834-92-0).
V.O.C. = 0.3 Ibs./gal.
NONPHOTOCHEMICALLY REACTIVE
TARGET ORGAN EFFECTS: Irritating to
eyes, skin and respiratory tract. May be
absorbed through skin.
HEALTH
FLAMMABILITY
REACTIVITY
PERSONAL
PROTECTION
-------
COMMENTS ON CTG FOR OFFSET LITHOGRAPHY
JAMES E. RENSON
COORDINATOR
ENVIRONMENTAL AFFAIRS
NATIONAL ASSOCIATION OF PRINTING INK MANUFACTURERS
PRESENTED AT NAPCTAC MEETING
NOVEMBER 20, 1991
DURHAM, NORTH CAROLINA
-------
Comments on CTG for offset lithography.
Ladies and Gentleman:
My name is James E. Renson. I am Coordinator, Environmental
Affairs for the National Association of Printing Ink
Manufacturers in Harrison, NY.
NAPIM
NAPIM is a national trade association representing small,
medium and large printing ink manufacturers in the U.S. Its
80 members account for nearly 90% of the total U.S. sales of
printing ink. The printing ink industry is composed of 224
companies operating a total of 504 manufacturing facilities
according to the U.S. Census of Manufactures for the year
1987. Total shipments of printing ink in the U.S. were over
$2.7 billion in 1990. NAPIM has been vitally concerned with
the need to clarify the definition of VOC which currently
varies widely from state to state. We are also vitally
concerned that the definition of VOC and the application of
this definition to various types of printing inks be
reasonable and fair to the printing and converting
industries in the U.S.
1;: r T;
s ^ 1
-------
We would like to compliment Radian Corporation for the
preparation of this draft CTG. We believe that it is a
comprehensive exposition of considerations to be assessed in
connection with the potential environmental burden from the
offset lithography printing industry in the U.S. We very
much appreciate this opportunity to comment.
ESTIMATE OF VOC OF NON-HEATSET INKS TOO HIGH
In Section 2.5.1 of the CTG the VOC content for non-heatset
web inks is given as 30% VOC. We believe this is
unrealistically high.
Table 1 - This table calculates the total weighted average
of VOC for all types of newsink based on the proportion of
total pounds shipped in 1990 for each major type of newsink.
Not only do newsinks account for most non-heatset inks
produced, but they are also typical of other types of non-
heatset web inks as well. As we show in the table, black
offset ink accounted for about 65% of all the newsink
shipped and conventional or standard newsink, in turn,
represented about 50% of this quantity. The second column
of the table shows the average percent VOC as measured by
Method 24 based on a detailed analysis of the various types
of these in. Then using standard offset inks as our
"7 po
8
-------
example, we estimate that VOC content is around 5%. The
weighted average VOC for this type of ink would be 1.3%.
Using the same calculations, we show that the weighted
average percent VOC in all types of newsink shipped in 1990
was around 7.4%.
DEFINITION OF VOC
We note that the CTG is silent on the definition of VOC and
does not delineate the test method to be used. Based on
previous discussions with EPA staff, it is our understanding
that oven test Method 24 will be specified. While we are
satisfied that the use of oven test Method 24 is suitable to
measure VOC's for heatset inks, members of the printing ink
industry feel strongly that this test method is much too
severe for measuring VOC content of inks which do not dry
with the application of heat.
Under oven test Method 24 the VOC content is determined by
measuring the weight loss of the sample heated at a
temperature of 110 degrees C for one hour. Instead, we
recommend that the test method used in the California Bay
Area known as Method 30 be used. In Method 30 VOC is
determined by the weight loss when the sample is heated for
one hour at 40 degrees C. We will show here why we consider
this to be a more appropriate test for no-heat inks.
703
-------
Table 2 - In order to obtain an understanding of the
temperatures which might be expected to be reached on non-
heatset presses, measurements have been made under actual
press conditions. This slide shows temperatures recorded on
three different types of newspaper presses. Please note
that 40 degrees C essentially represents the maximum
temperatures that would be reached.
Table 3 - This next slide summarizes sheet fed press
temperatures measured on five different presses. Note that
in only one case (Komori) did any temperature exceed 40
degrees C and this is a press fitted with an infra red (IR)
unit as are two of the other presses where the temperature
did not exceed 40 degrees C. Please note that the inks are
not being dried by the application of heat, but a low
temperature infra red unit is sometimes placed a the end of
a sheetfed press to help set the ink before the sheet enters
the delivery pile. Please note also that even with the IR
dryer, temperatures are not expected to significantly exceed
40 degrees C.
7C4
-------
Table 4 - Method 24 was developed for measuring the VOC's in
paints; not printing inks. The types of lower boiling
solvents used in paints are not found in non-heatset
printing ink. Table 4 shows a comparison between mineral
spirits, a solvent commonly used in paints and coatings,
with light distillate oil which are the so-called solvents
used in non-heatset inks. Solvents with high vapor
pressures and low boiling points used in coatings are
designed to evaporate from the coating while the oils used
in non-heatset inks have low vapor pressures and high
boiling points and are designed to remain with the ink film.
Table 5 - In order to determine the actual emission that
would be expected on a press for various types of news inks,
measurements were taken by ANPA on a full scale press.
Table 5 shows the emissions at critical points on the press
as determined by sampling with an approved EPA sampling
device for airborne vapors (carbon tube). We consider these
to be very low emission levels. In order to put them into
perspective it may be helpful to compare them with the
8-hour time weighted average threshold limit value
established by OSHA for airborne mineral spirits which is
2,900mg/M3.
7C
-------
Table 6 - Table 6 compares results obtained with Method 30
and Method 24 on the same ink. It is clear that the
excessively high temperature in Method 24 results in VOC
measurements which do not reflect press conditions
Also shown on this table is a comparison of
thermogravimetric analysis (TGA) results with Method 30.
The TGA apparatus is a very sensitive analytical instrument
designed to give a continuous record of weight loss as a
function of temperature and time. In order to gain a better
understanding of VOC loss for non-heat set ink, NAPIM
contracted for a series of TGA tests at the U.S. Testing
laboratories. While only one set of data are shown in this
table, a considerable amount of TGA data were generated have
been provided to Radian. It demonstrates that Method 30
agrees very well with the more precise TGA analytical
method.
-------
CONCLUSION
The previous slides demonstrate why test Method 24 is not
suitable to realistically measure VOC content of non-heatset
lithographic inks. Instead oven test Method 30 measures VOC
content at 40 degrees C which is consistent with maximum
temperatures measured on non-heatset lithographic presses.
Therefore NAPIM strongly recommends that the final draft CTG
include oven test Method 30 as the method of choice for
determining VOC content of non-heatset lithographic inks.
so/
comments.jer
FV
-------
TABLE 1
ESTIMATED VOC FOR NEWS INKS
% OF
TOTAL
LBS
% LBS
AVG.*
% VOC CALCULATION
VOC
WEIGHTED
AVG. %
80
BLACKS
Letterpress
35
.35 x .80 x 4
1.1
ifset
Standard
Low Rub
No Rub
65
50
35
15
5
10
25
20 COLORS
65 x .80 x .50 x 5
1.3
65 x .80 x .35 x 10 1.8
65 x .80 x .15 x 25 2.0
5.1
Oil
Soy
40
60
10 .20 x .4 x 10
3 .20 x .6 x 3
0.8
0.4
172
TOTAL
7.4
* Average % VOC measured by Method 24
-------
TABLE 2
NEWSPAPER PRESS OPERATING TEMPERATURES f°Cl
Form Roller Blanket Cylinder
Circulation Press Type Min Max High Min Max High
37,000 Urbanite 24 34 36 n/a n/a n/a
375,000 Metro 28 34 39 37 36 42
717,000 TKS 28 32 38 29 36 40
Min = Minimum Observed Running Temperature
Max = Maximum Observed Running Temperature
High = Highest Temperature Observed After Press Was Stopped
-------
TABLE 3
SHEETFED PRESS TEMPERATURES
>RESS
iPEED, IPH
-------
TABLE 4
COMPARISON OF MINERAL SPIRITS
AND
LIGHT DISTILLATE OIL (L.D.O.)
VAPOR PRESSURE mm Ha
Temp.
20
38
66
121
177
Rule 66
Min Sp.
5.6
12.5
37.0
200.0
740.0
L.D.O.
280 ° C IBP
0.01
0.03
0.18
3.00
26.00
Distillation
Range ° C
IBP
50%
FBP
160
177
193
281
290
315
711
-------
[•ABLE 5
VOLATILE EMMISSIONS
DURING CONTROLLED PRODUCTION RUN
(mg/M3)
_Ink Type_
Sample Regular Low Rub No Rub
Location Black Black Black
Right Ink
Form Roller 3.1 5.0 2.6
Left Ink
Form Roller 3.7 5.2 3.2
Pioe Roller 0.6 5.7 1.1
-------
TABLE 6
COMPARISON OF TGA AND OVEN TEST DATA
VOC, % LOSS
INK
Sheetfed
TGA
(40° C)
0
Method 30
(40° C)
1.8
Method 24
(110° C)
14.8
No-Rub News
0.5
1.7
24.3
-------
USEPA'S
NATIONAL AIR POLLUTION
CONTROL TECHNIQUES
ADVISORY COMMITTEE
MEETING
NOVEMBER 20, 1991
OFFSET LITHOGRAPHY
CTG DOCUMENT
I / T
"/14
-------
VOC SOURCES
1. Ink Oil Solvents
2. Fountain Solution
Additives
3. Cleaning Solvents
a. Blanket Wash
b. Auto Blanket Wash
c. Roller Wash
d. Other Cleaning
vis
-------
Ink Fountain
Plate Cylinder
Blanket Cylinder
Blanket Cylinder
Plate Cylinder
Inking Rollers
Dampening Roller
Fountain Solution
- Substrate
Dampening Roller
Fountain Solution
Ink Fountain
Figure 3-12. Schematic diagram of blanket-to-blanket printing.
3-21
716
-------
CONTROL COSTS
CONDENSER-FILTER
CONDENSER-FILTER
w/ACTIVATED CARBON
INCINERATORS
THERMAL
CATALYTIC
'V' 7
6 ^ i
-------
MODEL RULE
APPLICABILITY
DEFINITIONS
EMISSION STANDARDS
EQUIPMENT STANDARDS
EMISSION STANDARDS TESTING
EQUIPMENT STANDARDS TESTING
MONITORING REQUIREMENTS
REPORTING/RECORDKEEPING
-------
Environmental Conservation Board
of the Graphic Communications Industries
An Intra-lndustry Organization for Environmental Affairs
1899 Preston White Drive
Reston, VA 22091-4326
703/648-3218 - FAX 703/648-3219
ENVIRONMENTAL CONSERVATION BOARD
OF THE
GRAPHIC COMMUNICATIONS INDUSTRY, INC.
CTG Committee Draft Comments
on
United States Environmental Protection Agency
Control Techniques Guideline
For
Offset Lithographic Printing
September 6, 1991 Draft
Submitted to the
National Air Pollution Control Technical Advisory Committee
on November 20, 1991
The following comments on the September 6, 1991 draft of the
Offset Lithographic Printing Control Techniques Guideline are
organized in two sections. The first section (I) presents a
subject-by-subject overview of the draft and the second section
(II) provides a sentence-by-sentence critique of the document.
printed on recycled paper with vegetable oil ink
-------
Environmental Conservation Board
Of The
Graphic Communications Industries
CTG Committee Comments
On
Control Techniques Guideline
For
Offset Lithographic Printing
(September 6, 1991 Draft)
Outline of Comments
I. Overview
A. Introduction
B. Model Plants
C. Cleaning Solvents
D. Fountain Solution
1. General
2. Emissions
E. Inks
F. Add-on Controls
1. General
2. Thermal Afterburners
3. Catalytic Afterburners
4. Condenser Filters
G. Control Device Compliance Testing (EPA Method 25 and 25A)
H. Conclusion
II. Critique of Document Text
-------
I. Overview
Introduction
The Environmental Conservation Board of the Graphic
Communications Industries (ECB) is an intra-industry organization
for environmental affairs representing the printing industry.
Printing is one of the nations's largest industries, with over
50,000 commercial printing establishments (excluding the
newspaper industry) and more than 800,000 employees. Although
large in total size, the industry is mainly comprised of many
small entrepreneurial businesses, with 80% of all printers having
20 or -fewer employees.
The ECB would like to thank the United States Environmental
Prptecrion Agency and In particular the Chemicals and Petroleum
Branch, for the opportunity to comment on the September 6, 1991
draft Control Techniques Guideline for Offset Lithographic
Printing (CTG) at this stage in its development. The ECB
appreciates the willingness of the Agency to work with industry
experts in the development of this important document. ECB hopes
that the comments contained herein will prove useful and stands
ready to continue to work with the Agency in the further
development of the CTG.
The preliminary draft version of the CTG presents an attempt by
the Environmental Protection Agency (EPA) through its contractor,
Radian Corporation, to characterize all aspects of the
lithographic printing industry and propose reasonably available
control techniques (RACT) for controlling VOC emissions from
existing sources, consistent with existing technology and
practices. Although this draft describes some processes and
emission reduction techniques accurately and in reasonable
detail, it unfortunately contains a number of inaccuracies,
errors, omissions, lacks substantive evidence to support key
points, and appears to rely heavily on undocumented claims.
Outlined below are the areas that the ECB believes must be
revised. In several areas, quantitative evidence is not
available to document process modification or material
reformulation or substitution. However, EPA is urged to review
and present the evidence which has been subjected to scrutiny
through publication, testing, and industry experience in
preference to the word of mouth and undocumented claims that make
up such a large portion of this document. This approach would be
consistent with EPA's stated new approach to environmental
management that includes "-..a more rigorous reliance on sound
science to support EPA's environmental protection mission...".
(Stephen A. Lingle, Deputy Director, Office of Environmental
Engineering and Technology Demonstration, USEPA, plenary address
to the 1991 Materials Research Society Spring Meeting, printed in
the July 1991 MRS Bulletin).
This draft document addresses the three main VOC emission sources
in lithographic printing which are ink, fountain solution, and
-------
cleaning solvents and recommends methods to reduce these
emissions based on a number of "model" plants. The ECB comments
discuss these VOC emissions sources, the reductions methods
(technologies) proposed in the draft CTG, EPA's suggested
deemphasis of technologies and emphasis of control levels, and
suggestions for revisions to the draft. It is imperative that
EPA recognize the differences among the lithographic processes
employed by the industry segments and establish control levels
appropriate to those different material needs. (The industry
comments below reference the page numbers, in brackets, of the
September 6, 1991 draft CTG.
Model Plants
With three exceptions, the model plants outlined in Tables 3-1
and 3-2 [3-44, 3-45] appear to be reasonable examples of the
various size lithographic printing.
First, the assumption of single blanket units for heatset web
model plants denies the dominant position of blanket-to-blanket
presses in this industry segment. As a result, the materials
consumption, VOC emissions, and potential reductions are
excessive.
Second, the press width of 38" applied to all facilities other
than newspapers is inconsistent with the data in Figures 3-7 and
3-8 [3-14, 3-15], which would indicate that a 22" or narrower
width is more realistic for the smaller facilities.
Third, all facilities are assumed to operate 3,000 hours per
year. ECB believes that the following values of 1,500 hours per
year is more realistic for smaller one shift facilities; 3,000
hours per year for two shift (medium sized) operations; and 4,500
hours per year for the largest facilities. These more realistic
values should be used to calculate materials consumption, add-on
control device costs, and cost effectiveness of control presented
elsewhere in the CTG.
The materials consumption data in Table 3-3 [3-47] and elsewhere
should also be revised to indicate that large heatset and some
sheetfed lithographic printers in addition to newspapers, have
either lowered or replaced isopropyl alcohol in fountain
solutions with substitutes. The data presented greatly
overstates VOC consumption for fountain solution by tens or
hundreds of tons for larger printers.
Cleaning Solvents
Low VOC cleaning solutions are proposed as a means of reducing
emissions [2-7]. The draft CTG is recommending water-based
cleaning materials. The industry assumes that EPA will not
recommend the use of exempt compounds to achieve the 30% VOC
limit. No evidence is presented to substantiate the claims of
these products actually working and/or lowering VOC emissions.
It is later stated [3-42] these cleaners have been found to be
y] n o
• > fcj iJ
-------
inferior to solvent cleaners. It is acknowledged that several
problems are reported with water-based cleaners. If low VOC
materials are to be recommended as cleaning solvents, more
rigorous substantiation other than one performance claim must be
included in the CTG. As currently proposed, the document only
states that low VOC materials exist, but they may or may not
work.
If use of these materials requires more frequent cleanings,
larger volume use per cleaning, or longer cleaning time, a real
reduction in VOC emissions may not occur. Also, if highly
volatile organics are used in a low VOC cleaner, emissions from
the cleaner's use may actually result in an increase in total VOC
emissions, due to rapid or even complete VOC evaporation,
relative to a 100% VOC cleaner with a lower vapor pressure. Low
volatility organic solvents with vapor pressures below 45 mm Hg
at ambient temperature evaporate quite slowly and may leave the
cleaning process primarily as liquid solvent which can be
collected or remains absorbed in the cleaning rag, rather than as
air emissions.
Distinctions must be made between blanket washes and press
cleaning solutions. The physical requirements between the two
types of cleaning differ which will also affect operations and
productivity. The document does not distinguish hctween the
cleaning requirements demanded by the various in>. systems
considered. For example, removing news ink from _r.)c rollers can
usually be accomplished with a lower VOC content material than
removing sheetfed inks. Difficulty of cleaning is dependent upon
the viscosity of the ink (e.g., as the viscosity of the ink
increases, the effort required for roller, blanket, and press
cleaning also increases).
The information in Table 6-9 [6-17] is based on costs of $0.69
and $0.91 per pound for equal consumption of 100% and 30% VOC
materials, respectively. Since it is not clear that effective
cleaning can be performed with the untried 30% VOC cleaners, the
additional cost of low VOC cleaner may be higher thereby
resulting in lower emissions reductions. Additional data is
needed to support the contention that a one-for-one replacement
can be made and that no additional production time will be lost
due to ineffective cleaning.
Although consideration has been given to the benefits of using
untested, low-VOC cleaners [3-40], the replacement of current
organic cleaners with substitutes of lower volatility is not
discussed. The South Coast Air Quality Manageme-t District
(SCAQMD) has recognized the benefits of a low vapor pressure
cleaning solvent in its recently finalized Rule 1171, Solvent
Cleaning Operations, which supersedes Rule 1130, and limits
solvents used in cleaning lithographic printing equipment to no
more than 900 g/1 VOC and total VOC vapor pressure to less than
25 mm Hg. This limit is considered by SCAQMD as acceptable VOC
emissions reduction technology. SCAQMD has chosen not to require
water-based cleaners for offset printing due to difficulties
,3
-------
associated with using them. EPA is urged to consider this
approach in the CTG [4-19].
Furthermore, emissions from cleaning solvents are described as
being equal to the consumption of the VOC components of these
materials [2-9]. This assumption is not correct. A high
percentage of the cleaning solvent used with automatic cleaning
equipment is transferred to the substrate and in the case of
heatset presses it is transported to the dryer for capture and
control. With a typical low volatility cleaning solvent, 50% or
more of the solvent may be ultimately controlled. For manual
cleaning operations, a substantial portion of the solvent is
recovered as liquid waste or remains on the cleaning rag. For
lower volatility solvents, this may account for as much as 80% of
the solvent consumed.
Another aspect of the issue which has not been fully considered
i& the potential effect on the handling and disposal of liquid
wastes. The move to water-based cleaning materials creates
expensive treatment options. The avenues for disposal of liquid
wastes are either treatment or incineration.
Since there is an ever increasing tightening of sewer discharge
limits, the options for disposal are either expensive treatment
equipment or incineration. Neither waste water treatment nor
incineration are economical. Unlike 100% VOC cleaners that are
well suited for incorporation into fuel blending operations
because of their high BTU value, water-based cleaners do not
offer an attractive fuel for these operations. Additional energy
will be required for the incineration of water-based wastes. It
has been estimated that disposing water-based materials via
incineration costs three times more than the comparable solvent-
based materials. EPA is urged to consider the financial costs,
additional energy requirements and transfer of media associated
with requiring the use of water-based cleaners.
It is not clear why a method to monitor VOC content in cleaning
solutions [7-10] is necessary. Accurate measures of potential
VOC emissions can be simply calculated by using cleaning solvent
consumption records and applying the appropriate factors for
disposal and/or captured emissions.
The use of d-limonene-based cleaning materials should be deleted.
In a January 1990 report issued by the National Toxicology
Program, d-limonene was reported as showing clear evidence of
carcinogenic activity in male rats.
Fountain Solution
1. U.S. Department of Health and Human Servies, National
Toxicology Program, Technical Report Series No. 347, Toxicology
and Carcinogensis Studies of d-Limonene in F344/N Rats and
Mice, January 1990.
-------
General
Taken out of context, the statement at 3-39 that isopropyl
alcohol is a crutch to printers can be misleading. For certain
printing jobs, the required print quality can only be obtained
when isopropyl alcohol is used in the fountain solution. As
stated in Chapter 4 [4-19], certain applications such as sheetfed
printing may not be able to reduce or eliminate isopropyl alcohol
as readily as other branches of the industry.
Statements are made about isopropyl alcohol consumption
reductions with refrigerated fountains and through the use of
magnets [2-5, 2-6]. Although refrigeration of fountain solution
will reduce isopropyl alcohol evaporation due to vapor pressure
reduction, the actual emissions reduction will be a function of
fountain temperature and isopropyl alcohol consumption on-press.
The assumption that all isopropyl alcohol is evaporated at the
printing unit, with none of the material carried through the
process is not correct (5-7, ref. 15). Published studies on both
sheetfed and web presses indicate that more than half of the
fountain solution is transferred to the substrate and in the case
of heatset printing, a significant portion will be carried into
the dryer and exhausted to the pollution control equipment.1
The data in Table 5-3 [5-9] shows cost savings associated with
use of isopropyl alcohol substitutes and VOC reductions (as in
Table 5-1 on page 5-3). The basis the data used to derive the
17% average isopropyl alcohol level is both in doubt and somewhat
dated. The 1986-87 survey conducted by NAPL (3-51, ref. 26)
resulted in a 15% average for 1986. ECB believes that the
average concentration for printers using isopropanol is now lower
as most larger heatset and some sheetfed facilities have already
switched to isopropyl alcohol substitutes. There are no readily
available cost savings or VOC reductions from fountain solution
for these facilities. The survey's performed by Radian may
provide some insight.
A device purporting to reduce the surface tension of fountain
solution by "magnetizing" the water is suggested [2-6, 2-10] as a
means of reducing isopropyl alcohol consumption. Such a claim
should be verified by experimental methods based on a pre-
approved protocol.
1. Karttunen, S. and Lindquist, V., "Water Flow and Surfactant
Effects in Offset Lithography", Advances in Printing Science and
Technology, Vol. 15, Ed. W.H. Banks, Pentech Press, London, pp.
176-199.
Lindquist, V., Karttunen, S., and Virtanen, J., "New Models for
Offset Lithography", Advances in Printing Science and Technology,
Vol. 16, Ed. W.H. Banks, Pentech Press, London, pp. 67-96.
-------
Additionally, certain dampening systems are described
[4-18] as working best with lower concentrations of isopropyl
alcohol due to the surface tension reducing properties of the
brush or spray used to apply the fountain solution. Again,
unique physical properties are attributed without proper
documentation. Actually, a brush and a spray generate new
water/air interfaces with the maximum surface tension, i.e. they
act to increase not decrease the instantaneous surface tensions
of water solutions.
Other sections on magnets [4-17, 5-11, 6-15] and the data in
Table 6-8 [6-16] should be deleted unless the claims of magnetic
treatment can be substantiated. Also, section 5.2.5 [5-9] should
be eliminated since the effect of isopropyl alcohol concentration
on emissions has already been discussed in section 5.2.3.
Although EPA accepts that magnets can change the properties of
water, it remains skeptical that print quality may suffer when
isopropyl alcohol concentrations are reduced in fountain [2-10].
Data derived from laboratory and pressroom studies previously
submitted by GATF indicates that the units do not work .
Additional laboratory and pressroom data resulting from other
studies agrees with GATF's conclusion .
It is not clear what rationale was used to discount lost
production due to the change from isopropyl alcohol to
substitutes [6-13]. Whether a plant operates 16 or 24 hours per
day should have little effect on the amount of lost production
due to this change.
Emissions
Emissions from fountain solution are described as being equal to
the consumption of the VOC components of these materials [2-8, 5-
7]. Several fundamental concepts regarding these materials are
not considered. Isopropyl alcohol substitutes and, to a lesser
extent isopropyl alcohol, do not totally evaporate at the
printing unit. Substantial quantities are transferred to the
substrate where a percentage may be retained or in heatset
operations the majority is driven off and captured in the dryer
exhaust for transport to the pollution control equipment. Of the
low volatility isopropyl alcohol substitutes such as ethylene
glycol and glycol ethers, in excess of 75% of the fountain
1. Letter to Berry, James, EPA, Research Triangle Park, N.C.,
from Schaeffer, W.D., Graphic Arts Technical Foundation,
Pittsburgh, Pa., May 15, 1991.
2. Letter to Berry, James, EPA, Research Triangle Park, N.C. from
Schaeffer, W.D., Graphic Arts Technical Foundation, Pittsburgh,
Pa., August 21, 1991
-------
solution VOC is either retained or captured in a heatset
operation. It is expected that these materials are also retained
in sheetfed printed products.
Using the basis of 17% isopropanol in the fountain solution and
the value of 1.7% VOC using isopropyl alcohol substitutes,
combined with the much lower (1/4) evaporation of the
substitutes, it would appear that a 40 fold (rather than 16)
reduction in VOC consumption is attainable [4-18]. The lower
evaporation rate of the substitutes also means that fugitive
emissions should be reduced substantially, such that total VOC
emissions from fountain solutions used on presses with oxidizers
should be on the order of 1-5% of similar presses using isopropyl
alcohol. A blanket application of a factor of ten reduction in
isopropyl alcohol substitute use vs. isopropyl alcohol [5-11] is
not justified for all printing systems. Although a 90% or
greater reduction in VOC use may be obtained in certain systems,
this is clearly not to be applied across the board as a 90%
reduction in VOC emissions.
The references to 75% VOC in isopropyl alcohol substitutes [4-18,
5-7] are inappropriate. VOC content of substitutes varies from
one product to another. The 0.75 factor in equation (5) [5-7]
should be replaced with a generic term such as "%VOC in
concentrate divided by 100%"-
The claim of 44% isopropyl alcohol reduction with refrigerated
circulators is presented. [4-15]. The use of the 0.44 reduction
factor for the use of all refrigerated fountain solution systems
[5-11] is inappropriate because there are other considerations
beyond the fountain solution temperature that influence alcohol
concentration (e.g., coverage, water quality, speed of the press,
type of dampening system, and substrate).
In discussing soybean oil inks [3-37], EPA should recognize that
other vegetable oil inks besides soy oil have been and are being
utilized. Replacement of petroleum with soy, although reducing
the petroleum content, does not necessarily result in any
significant reductions in VOC emissions in nonheatset printing.
Data in Table 5-1 indicate that the vast majority of emissions
from no-heat printing results from fountain solution and cleaning
solvent emissions. Assuming that the percent of petroleum oils
retained in mixed petroleum/soy inks is the same as for 100%
petroleum inks, replacing 75% of the petroleum oil with soy would
result in emissions reductions of only 6.75 tons of emissions for
plant B-IV (<1% overall reduction), 1.5 tons (4.5%) for C-IV, and
24 tons (12%) for D-VI.
In discussing reactive curing inks [3-38], it should be made
clear that VOC emissions from these materials will be essentially
zero. VOC content from a Method 24 analysis might indicate a
relatively high VOC content in the uncured material, but as
applied, the emissions are negligible due to polymerization,
~ i-y
-------
rather than evaporation in the curing process. Use of these
materials is restricted to a few special applications.
Add-On Controls
General
The VOC reductions from heatset operations with add-on controls
shown in Table 5-2 [5-6] are misleading due to the omission of
the amount of VOC from fountain solutions and cleaning solvents
being controlled. By tabulating the reductions only from ink,
the benefit of add-on control is understated. Add-on controls
may substantially reduce emissions from these other sources,
which will favorably alter the economics and environmental
benefit of these controls. Tables 5-3 and 6-4 also need to be
revised to reflect this aspect of add-on controls.
The capital costs, annual costs and cost effectiveness in Tables
6-2 [6-6] and 6-3 [6-7] need revision. They should be based on
more realistic materials consumption data, suggested changes (see
below) in device efficiencies, and in the case heatset include
emissions from sources besides ink, such as cleaning and fountain
solutions, being at least partially controlled. In addition,
these two tables should contain identical capital and operating
costs. Also, further cost justification is required to explain
apparent incremental cost discrepancies for the different model
plants. For example, the relative costs of plant A-II vs. A-I
are >100% for a thermal afterburner, 50% for catalytic, 90% for
condenser filter with carbon and 90% for condenser filter. It is
not obvious how the equipment was sized for these example
facilities nor how capital and operating costs were calculated.
Additionally, the determination of capital and operating costs
associated with the various model plants is not clearly defined
[6-10]. For example, the largest heatset model plant (A-IV) is
described as a 30,000 scfm facility [6-10]. Yet elsewhere [6-5],
it is stated that additional incinerators were costed for flows
above 50,000 scfm. A critical review of costs calculated in the
CTG can only be performed if the capital costs and configuration
of the system(s) is identified. For example, significant cost
differences can be expected if pollution control equipment for
plant A-IV consists of three 10,000 scfm devices as opposed to
one 30,000 scfm control.
The basis for the scaling factors in the cost analysis [6-5, 6-9]
is unclear. These factors should be more fully explained to
allow critical evaluation of the calculated costs.
NOX emissions from afterburners was only briefly mentioned [6-
18]. ECB recommends an analysis of increased NOX emissions
resulting from operation of thermal afterburners at 1600°F (vs.
1350°F) be included.
No consideration is given to other emissions concerns such as the
control of odor by add-on controls [6-18]. Obviously, in
-------
sensitive areas, odor concerns may come into play. For odor
control, thermal oxidation is the method of choice.
Thermal Afterburners
The draft CTG does not discuss the use of regenerative thermal
afterburners for controlling emission from printing operations.
Although these devices are relatively new to the printing
industry, a discussion of their operation, destruction efficiency
and costs should be included.
An efficient recuperative thermal afterburner does not require a
residence time of 0.75 seconds at 1400°F for complete oxidation
[4-6]. Operation at 1350°F with a retention time of 0.50 seconds
will provide a high level of control if the system is designed
with enough turbulence and flame contact. Moreover, operation at
elevated temperature will increase energy consumption, increase
NOX emissions, and reduce equipment life with no detectable
increase in VOC destruction.
The basis for the residence time and combustion chamber
temperature for thermal afterburners [4-6] refers to several
input materials that are totally foreign to offset lithography.
Materials such as C^ to Cc alkanes and olefins, chlorinated
organics and nitrogen containing compounds are not typically
used. Thermal afterburners for printing are not to be considered
analogous to hazardous waste incinerators. Recuperative thermal
afterburners operating at 1350°F and residence time of 0.5
seconds have been demonstrated to have outlet concentrations of
less than 20 ppmv in offset printing operations. In the Illinois
Federal Implementation Plan, EPA has recognized that a 90%
control efficiency for afterburners constitutes RACT for heatset
lithography (55 FR 26877) .
By restricting operation of thermal afterburners to 3,000 hours
per year for the model plants and requiring a 1600°F operating
temperature [6-2], the costs associated with this control are
made considerably higher.
Catalytic Afterburners
The statement is made [2-5] that "Incineration can achieve
approximately 98% control of VOCs". While thermal afterburners
may provide a very high level of control over an extended
timeframe catalytic afterburners will show gradual degradation
in performance over time due to deactivation, masking, or
poisoning of the catalyst (as noted on page 4-9). Therefore,
even if a system with new catalyst may destroy 98% of the VOCs
initially, a decrease in destruction efficiency should not be
unexpectc-.. if the CTG is to take the position that 98% control
by catalytic afterburners is the minimum acceptable control
efficiency, the operating costs of the systems must be
substantially increased to reflect the additional costs of
frequent catalyst replacement which will be necessary to maintain
this high level of control. A more realistic approach would be
-------
to establish 90% control as the reasonable minimum efficiency for
these systems. This level of control has been recognized by EPA
as RACT for heatset lithography as part of the Illinois Federal
Implementation Plan (55 FR 26877).
A blanket statement that an unspecified catalyst operating at
840°F with a bed volume of 0.5 to 2 ft3 per 16.8 scf/sec can
achieve 95% destruction efficiency [4-10] is not correct. In any
given catalytic system, the operating temperature and space
velocity requirements are catalyst specific. Again, even though
a 95% control may be achieved initially, catalyst degradation
over time will lower this number. A lower control efficiency
would be consistent with the projected 2-5 year catalyst lifetime
suggested on page 4-10.
Condenser Filters
The discussion of condenser filter systems [2-5, 4-14] states
that up to 97% control can be achieved with these devices and
also suggests the use of carbon canisters coupled with these
devices may increase efficiency. The stated efficiency of
condenser filter systems of 90% (95% with carbon) [4-14] are
unrealistically high. Although they provide acceptable VOC
control, the levels stated here, either with or without carbon,
are substantially in excess of normal efficiencies. Since these
devices are relatively ineffective at controlling captured
fountain solution and cleaning solvent VOCs, the performance of
the condenser filter equipment is overstated.
Although the condenser filters do not offer comparable reduction
efficiencies to afterburners, there are some distinct advantages
when capital and operating costs are considered. They also do
not directly contribute to the formation of NOX and C02.
The lower removal efficiency has been recognized by EPA in its
most recent determination of RACT for these devices which is set
at 75% control of the non-isopropyl alcohol portion of dryer
exhaust. The RACT determination was part of the Illinois Federal
Implementation Plan at 55 FR 26877.
Condenser filters are most efficient with high inlet
concentrations and low outside air temperatures. These
conditions are important because the VOC concentration in the
exhaust of a system (before the carbon) will be at steady state
concentration determined by the properties of the VOCs and the
ambient environmental temperatures. If all other factors remain
the same, reducing the inlet concentration to the device will not
necessarily have any effect on the outlet concentration due to
the steady state oil concentration within the unit since this
control technology is subject to influence by seasonal variations
in ambient air temperature. An increase in the outside
temperature will result in an increase outlet temperature and,
accordingly, a higher outlet VOC concentration. If this
technology is to be considered, a more complete analysis of the
process is required, including the function and effectiveness of
control of fountain and cleaning solution VOCs.
10
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Condensed ink oil from a dryer still has a very strong "burnt
oil" odor from the smaller cracked molecules. Carbon filters can
help reduce the uncondensible odors, but the carbon must be
monitored on a daily basis so that it can be regenerated before
the odor breakthrough is noticeable.
Although cleanup efficiencies are usually better when ambient
temperatures are lower, sometimes very rapid cooling can cause
submicron aerosol particulate formation. These submicron
particles tend to pass through the filter and carbon bed.
The contention in Table 6-3 that condenser filter systems require
less maintenance than either catalytic or thermal afterburners is
incorrect. Just the opposite is true. Based on industry
experience, the condenser filter systems require the most
maintenance of the three add-on control systems. \ - n
ri r t»L _*. S -^ / ^ j- —7"' * , ^. __ —^' ft t~* /^ i*si *> i~~ i<* J&&& &%s1 Cr ( X. ^—-
ff e/*l* t^yr? Sf-^CFJfrj @f££&*£*(/& fj / <$ / (rt&fc£C */' C~G^7 I ^&£- (-*&*'*' *^* C*-T~j •>—> *• f / S
Table 6-10 [6-20] does not contain the energy costs or emissions
associated with installation and operation of the steam
generating capacity required for regenerating the carbon beds on
condenser filter systems. The table should be revised to reflect
these costs. Footnote d has a steam factor of 3.5 Ibs of
steam/lb carbon. This appears to be the annual consumption,
based on data in Table 6-3 and the 5-year carbon life stated on
page 4-14. (A 3000 scfm system requires about 4750 Ibs of carbon
and 17,200 Ibs of steam.) It is unclear how frequently steaming
must occur and the amount of steam that is required per steaming.
There appear to be some unfounded generalizations in the
environmental impact section which can be misleading [2-15]. For
example, use of oil collected in condenser filter systems to
replace fuel in dryers may be more complicated than simply
burning the material. State regulations governing disposal of
this liquid may require the printer to tes:- the oil, possibly
obtain a RCRA Part A and B permit (require of all treatment
storage and disposal facilities), and manifest the material as a
hazardous waste, precluding its use for fuel. Additionally, the
cost of modifying a dryer to burn this fuel in combination with
gas has not been included. Although a value of $0.63/gal for
recovered oil [C-38] has been used to calculate cost for these
systems based on its use to fuel the dryers, the actual value or
sale or cost for disposal of this material will significantly
lower the economics of this technology.
The potential water pollution problems of high molecular weight
oil combined with water in condenser filter systems appears to be
understated [2-15. 6-21]. Oil-contaminated water from these
systems may require extensive treatment before it can be
discharged.
Other Issues
The discussion of EPA Methods 25 and 25A [7-6] states that Method
25 is not applicable to concentrations below 50 ppm and that
11
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Method 25A is not recommended for incinerators (where the outlet
concentration should be below 50 ppm). No recommendation is made
as to appropriate methods for compliance testing of afterburner
systems. The industry does not agree that Method 25 should be
recommended as the best test method for determining emissions
from dryer exhausts. The method is cumbersome, expensive, and
provides inconsistent results and is not suitable for measuring
control device efficiencies, especially those with outlet
concentrations at or below 50 ppmv as C^.
It must be emphasized that steady-state conditions in the heatset
industry are normally less than one hour for single press
operations. For multiple press exhausts into a common control
device, steady-state conditions may never exist, much less for
the three one-hour periods as required for a Method 25 protocol.
Presses' frequent starts and stops and changes in operating
speeds greatly affects flow rates and concentrations of exhausts
reaching the control device. Thus it would be very helpful if
there could be more flexibility in the required one hour steady-
state sampling time.
Method 25A should be the recommended method especially for
control device exhaust emission concentrations of 50 ppmv or less
as Cj_. By utilizing simultaneous inlet and outlet analyzers,
instantaneous efficiencies can be determined, regardless of
changes in press operating conditions. It may also be
recommended as a screening test for determining unknown
concentrations from the outlets of emission control devices.
Reference is made [7-7] to a modification of Method 24 that is
under development for VOC determination of fountain solution and
cleaning solutions. ECB Respectively requests further detail
concerning the modifications being considered. In the meantime,
reference to and application of the method should be eliminated.
Summary
The recommendations for control technology, fountain solution and
cleaning solvent [2-14, 2-15] must all be revised. Condenser
filter systems with carbon can not routinely control VOC
emissions at 95%. control device performance on a routine basis
should be established at the 90% efficiency level. There is no
evidence that suggested isopropyl alcohol concentration levels
can be met by printers. It is entirely unclear what basis was
used to determine what level of isopropyl alcohol is acceptable
at sheetfed facilities or why a larger printer can necessarily
function at an isopropyl alcohol level only half of what is
required for smaller facilities. No mention is made of the use
of low volatility cleaning solvent or emissions reductions
obtainable through control or revised handling and/or cleaning
procedures.
12
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II. TEXT CRITIQUE of Preliminary Draft of Offset Lithographic
Printing Control Techniques Guideline
Table of Contents, p. ii, Title for 2.5.6:
Make "Emission" plural
Table of Contents, p. ii, Title for 2.6.3:
Make "Emission" plural
Section 2.1, p. 2-1, par. 2, line 5:
The term "image plate" used extensively in this draft is not
common the industry. The expression "lithographic plate" is
recommended.
Section 2.1, p. 2-1, par. 2, line 9:
Transfer of the ink from the lithographic plate is
recommended instead of "Transfer of the image...-1*-
Section 2.2, p.2-2, par. 1, line 1:
Make the word "arrangements" singular (arrangement)
Section 2.2, p. 2-2, par. 1, line 3:
Insert the word "fountain" between..."dampening" and
"system."
Section 2.2, p. 2-2, par. 5, last line (11):
Delete the word "color" and replace with "pigmentation".
Insert the words "inks for" between "than" and "other"-
Section 2, p. 2-3, Figure 2-1:
Figure requires an impression cylinder.
Section 2.2, p. 2-4, par. 1, sentence 2:
Please provide reference.
Section 2.2, p. 2-4, par. 2, line 1:
Delete "printplate" and replace with "lithographic plate."
Section 2.2, p. 2-4, par. 2, line 5:
Delete "acids of buffer salts" and replace with "acids and
buffer salts."
Section 2.2, p. 2-4, par. 3, line 1:
Isopropanol has not traditionally been used as the dampening
aid. Isopropanol was introduced in the 1950s in conjunction with
Dahlgren or return-flow type dampening systems. The isopropyl alcohol
enables the fountain solution to spread on the ink form roll and
be carried to the lithographic plate surface.
Section 2.2, p. 2-4, par. 3, last sentence:
Please cite reference.
Section 2.2, p. 2-4, par. 4, sentence 1:
Delete "paper pieces" and replace with "paper components."
-------
Section 2.2, p. 2-4, par 1, sentence 2:
Delete the word "commercial" and replace with "single".
Section 2.2, p. 2-4, par 1, sentence 3:
Begin sentence with "Different cleaning solutions...".
Section 2.4.1, p. 2-5, par 2, first sentence:
Make the first sentence explicit heatset web offset
lithographic printing.
Section 2.4.1., p. 2-5, par. 3, sentence 2:
Few dryers are equipped with combination burners adaptable
for liquid fuels. Use as boiler fuel is more common.
This section states that condenser filter systems can
achieve as high as 97% VOC removal efficiency, while 90% is
typical. It further states that 95% can be guaranteed if carbon
filters are added to the discharge. Actual experience does not
confirm these efficiencies. Industry experience indicates lower
levels of performance during sustained operations.
In addition, the type of test method used for testing
condenser filters can have a bearing on the cleanup efficiency
values. In many cases USEPA Method 5 is used and the oil is
measured as if it were 100% particulate or condensed oil aerosol.
In reality, it has been observed that about 15% of the oil can
break down or "crack" in the vicinity of the dryer burner flame
envelope. The cracking results in the creation of smaller more
volatile molecules that do not condense well at ambient
temperatures. These smaller molecules are still VOCs but they
are not trapped in the Method 5 and therefore escape detection.
When a Method 25 or 25A is used, the cleanup usually is not as
high as a Method 5 result.
Section 2.4.1, p. 2-5, par. 3, sentence 2:
Delete "fuel for boilers" and replace with "fuel for
dryers". Use in dryers has not proved acceptable.
Section 2.4.1., p. 2-5, par. 3, last sentence:
Carbon has been used in a number of ways to clean up
hydrocarbon in the outlet. A supplier-specific "carbon canister"
version should not be suggested as the norm.
Section 2.4.2, p. 2-6, par. 1, last sentence:
Delete the word "trays".
Section 2.4.2, p. 2-6, par. 2:
Deletion of the magnetic processing of lithographic fountain
solutions is suggested because GATF, other laboratories, and
printing plants have been unable to document any positive
effects. References to 500 plants in this paragraph and 200
printing units (Section 4.3.2) are not compatible.
Section 2.4.3.1, p. 2-6, par. 1, last sentence:
-------
Documenting the date of the 17 percent average is important
because of the rapid decrease in isoprc- i alcohol use by the industry.
The 1986-87 survey conducted by NAPL resulted in a 15 percent
average in 1986 (3-51, ref. 27). The 12 percent difference (15
vs 17) significantly effects the anticipated RACT VOC reductions.
Section 2.4.3.1, p. 2-6, par. 2, sentence 2:
The glycol ethers are classified as hazardous air pollutants
and should be noted.
Section 2.4.3.1, p. 2-6, par. 2, sentence 2:
The term "Cellosolve" is a trade name for a specific glycol
ether and should be replaced by that term.
Section 2.4.3.1, p. 2-7, par. 2, first sentence:
There are many different factors beyond the type of
dampening system that influence the ability to reduce or totally
replace isopropyl alcohol. For example, ink type, coverage,
press speed, substrate, roller type and condition, and water
quality all effect the transition to lower levels or substitutes.
Section 2.4.3.2, p. 2-7, par. 1:
Differentiate between blanket and press cleaners.
d-limonene is classified as a carcinogen for male rats.
Avoid the terms "non-toxic" and "nonhazardous" because of
the absence of generally accepted definitions for them.
Section 2.5.1, p. 2-7, Table 5-1, p. 5-3:
Inclusion of single color heatset and nonheatset presses
will reduce ink use significantly. The 77 tons annual usage is
believed to be 35 to 50 percent too large for plants A-l and B-l.
Section 2.5.1, p. 2-8, par. 2, sentence 3:
Provision should be made for waste and spoilage amounts in
the ink use factors.
Section 2.5.2, p. 2-8, par. 1:
All of the fountain solution does not evaporate "after
delivery to the printing plate." High speed photographs and
infrared reflectance studies demonstrate the existence of
fountain solution on the plate surface and transfer to the
blanket.
No mention is made of waste and spoilage amounts in the ink
use factors. Provisions should be made.
1. Ink-Water Balance, Parts I and II, Flint Ink Corporation,
Detroit, Michigan.
2. Pyliotis, D. "Der Wasserhaushalt im Offsetdruck", FOGRA-
Forschungsbericht 3.214, Munchen (1974).
-------
The concept that no water or isopropyl alcohol is disposed is not
correct. Printers routinely discard fountain solutions either on
a predetermined frequency (i.e. weekly) or when it becomes
contaminated.
Section 2.5.3, p. 2-9, par. 1:
The assumption that all cleaning materials are evaporated at
the plant is not correct. Up to 80% of solvents used for roller
or press cleaning are retained in the cleaning rags, collected as
liquid waste for disposal, or may be controlled.
Section 2.5.4, p. 2-9, par.l:
Control equipment efficiencies should be representative
averages not the maximums. For example, catalytic incineration
should not be expected to achieve 98 percent efficiency on
average.
Cleanup efficiencies in excess of 98% for catalytic
afterburners is achievable with new systems, but can slowly drop
to lower levels as the catalyst becomes masked or poisoned. Some
manufacturers use a deep bead-type catalyst beds to help
alleviate this problem. Nevertheless, a cleanup efficiency of
90% is probably more reasonable for longer catalyst replacement
intervals, thus reducing operational costs.
The question of long term efficiency and economics of carbon
canisters on condenser filters makes the 95 percent level
suspect.
Section 2.5.5, p. 2-10, par. 1, sentences 1 and 2:
There is no theoretical or practical basis for the claimed
effects of magnetism.
Section 2.5.6, p. 2-10:
In heatset web offset and sheetfed lithography, provision
must be made for blanket cleaners which will dissolve blanket
debris, that is, cleaners with VOC content approaching 100
percent. These cleaners will maintain productivity and minimize
waste with the high viscosity inks1.
Section 2.6.1, p. 2-11, par. 2, last sentence:
Not "fuel for the dryer" but "fuel for a boiler." "Fuel for
the dryer" still exists in sections 2.5, 4.2.3.2, 6.1.1, 6.1.4,
6.4.2.
Section, in general, give no indication of economics in
increased scale of emissions due to heat recovery, multiple
1. MacPhee, John and Gasparrini, C. Robert, "Test Run to
Determine the Effect of Blanket Washing on the Concentration of
Combustible Vapor in the Dryer of a Heatset Web Offset Press",
TAGA Proceedings 1984, Technical Association of the Graphic Arts,
Rochester, N.Y..
j. O
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presses tied to single control units, etc.
Section 2.6.1, p. 2-11, par 3:
For control at 95% or higher it is likely that catalytic and
thermal units might cost nearly the same since the catalyst would
need to be replaced at least every two years. On the other hand,
for control at the 90% level, catalytic units could tolerate a
much higher level of poisoning and still achieve 90%.
Section 2.6.2.1, p. 2-12, par. 3, sentence 1:
The optimism in this sentence does not recognize the
magnitudes of the costs of conversions, including spoilage. The
projected annual savings, for example, in the sheetfed sector
barely approach the values of single printing jobs.
The costs associated with higher roller maintenance,
potential water treatment, and experimentation with new types of
rollers need to be taken into consideration.
Section 2.6.2.1, p. 2-12, par. 4:
Anticipated material "savings" are overstated because they
are based on reductions from an average isopropyl alcohol
concentration of 17%. As previously described, ECB believes that
the 17% average is not representative.
Section 2.6.2.2, p. 2-12, par. 1:
Again, VOC "reductions and savings" are overstated, because
average isopropyl alcohol concentrations are based on the 17%
average. Additionally, some sheetfed and heatset web facilities
are currently using refrigeration as a means to reduce isopropyl
alcohol consumption and for quality control purposes.
Section 2.6.2.3, p. 2-13, par. 1 and 2:
Delete entire section and references to magnetic processing
of fountain solutions.
Section 2.6.3 p. 2-13, sentences 1 and 2:
Again, please define the term "non-toxic" as previously
mentioned. No reference is made to the questionable technical
feasibility of these cleaners in offset printing.
Section 2.7.1, p. 2-14:
Delete "95 percent" and replace with "90 percent".
Section 2.7.2.1, p. 2-14:
Delete "1.6 percent" and replace with "8 percent". Delete
"3 percent" and replace with "12 percent"-
Section 2.7.2.2, p. 2-14, par. 1 and 2:
No basis for the proposed two levels of isopropyl alcohol
concentrations is presented. The discussion is arbitrary and not
reasoned. Dampening requirements for sheetfed printing are
dictated by the types of presses, dampening systems, and work or
jobs being printed. These factors do not change with the size of
the pressroom and its equipment.
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In paragraph 1, delete "6 percent" and "10 percent" and replace
with "10 percent" and "15 percent", respectively. In paragraph
2, delete " 3 percent" and "5 percent" and replace with "10
percent" and "15 percent", respectively.
Section 2.7.3, p. 2-15:
Industry needs separate provisions for blanket and press
cleaning solutions at least for heatset and sheetfed lithography.
Blanket cleaners require high VOC concentrations as discussed in
Section 2.5.6 comments.
Section 2.8, p. 2-15, par.l, sentence 1:
Insert the word "heatset" between "from" and "offset".
Section 2.8, p. 2-15, par. 2, sentence 2:
Distinction needs to be made between catalytic and thermal
incineration in the generation of NOX. Emissions of NOX is
typically twice as high with thermal incineration and increases
with increasing temperatures.
Section 2.8, p. 2-15, par 3:
The problem of waste disposal of recovered "gunk" and oil
contaminated water in condenser filters should not be minimized.
It can be a major factor. Health related issues of dealing with
recovered waste and equipment cleanup can also be a
consideration.
In sentence 3, delete "(imperceptibly)".
Section 2.9, p. 2-15, par. 1, sentence 2:
Does "Exhaust from heatset ink drying...." mean "Controlled
exhaust from...-"? If so, please be explicit.
Section 2.9, p. 2-16, par. 2, sentence 1:
The comparison is suspect because the model heatset and non-
heatset web presses are assumed to consist of single units
("single blanket"); whereas, newspaper presses consist of "double
blanket" units. Ink consumption is assumed to be directly
proportional to the number of units.
Section 3.1, p. 3-2, par. 2, sentence 2:
Delete the words "March, April, and May of"
Section 3.1, p. 3-2, par. 2, sentence 1:
Include screen printing.
Section 3.2, p. 3-2, par. 1 and 2:
Delete "image plate" in the numerous uses and replace with
"lithographic plate"-
Section 3.2, p.3-2, par. 2, sentence 1:
Delete "ink reservoir" and replace with "ink fountain".
Section 3.2, p. 3-2, par. 2, sentences 2, 3, and 4:
-------
Delete "image" and "image plate" and replace with "ink" and
"lithographic plate", respectively.
Section 3.2, p. 3-2, par. 3, sentence 1:
Insert the word "generic" between "two" and "types"-
Section 3.2, p. 3-2, par. 3, sentence 2:
Revise to read: "...a heated dryer to evaporate ink oils and
cause the printing inks to set and dry.M-
Section 3.2, p. 3-3, par. 4, sentence 3:
The scope of sheet-fed lithography is much too narrow.
Sheetfed lithography is the source of all types of commercial
printing, e.g., periodicals, advertising, books, business forms,
brochures, folding paper boxes and metal decorating. Large
volume production jobs 'require the economics of higher speed web
processes.
Delete the word "specialized"
Section 3.2, p. 3-3, par. 4, last sentence:
Delete "individual sheets of"
Section 3.2, p. 3-4, par. 1:
Population of weekly newspapers is in excess of 7000 with
some 3100 having presses, usually single web width newspaper
presses. They require consideration and inclusion in the CTG.
Section 3.2, p. 3-4, par. 1 and Figure 3-1:
The data appears to indicate a total of newspaper facilities
that is larger that the 1,626 noted in the text, the right hand
column should be labeled as ">250,000", and the footnote gives a
31/67% split on morning and evening papers which totals only 98%.
Section 3.3, p. 3-4, par. 1, lines 6, 7 and 8:
Delete the word "approximately"
Section 3.3.1.1, p. 3-4, par. 2, sentence 2:
Revise to read: "-.. one blanket per unit.".
Section 3.3.1.1, p. 3-4, par. 2, sentence 3:
Revise to read: "... Two blankets per unit although...".
Section 3.3.1.1, p. 3-4, par. 4, sentence 1:
For a CIC press and the consistency of terminology recommend
that the five printing systems be referred to as "units" and the
total assembly of five units be a "couple."
The description of the CIC press implies that this type of
press may operate as a perfecting press. This is physically
impossible based on the design of the press.
Section 3.3.1.1, p. 3-7, par. 1, sentence 2:
As suggested previously, interchange the words "units" and
"couples" for consistency and extended calculation.
-------
Section 3.3.1.1, p. 3-7, par. 1, sentence 3:
Revise to read: "... printing sequentially up to five colors
on one side of the web..."-
Section 3.3.1.1, p. 3-7, par. 3:
This and the following paragraph together with Figures 3-5
and 3-6 deal with the number of presses operated by given
percentages of companies. Press models, however, deal with the
number of units in plants. One additional step could facilitate
the comparison between models and industry profiles.
Figure 3-3, p. 3-8:
Change this illustration to one of a lithographic CIC press.
Section 3.3.1.2, p. 3-12, par. 1, sentence 2:
Cylinder gap width comparison between web and sheet presses
has no utility for present purposes.
Section 3.3.1.2, p. 3-12, par. 1, last sentence:
They may have infrared sources to accelerate ink setting.
Section 3.3.2, p. 3-12, par. 2 and 3:
Press size is described by the length and circumference of
the press cylinders, not the "maximum length and width of the
paper."
The discussion of press size interchanges the definition of
length and width, at one point defining width as the
circumference of the cylinder and later using it in the
traditional across the cylinder dimension. The text should be
clarified to use the term width in the latter context and cut-off
length (or length) in the former.
Delete all references in this paragraph to the dimensions
and orientation of the job on the press because most of the
current description is incorrect or confused.
Section 3.3.2, p. 3-13, par. 3, line 1:
Delete the word "determine" and replace with "determines"
Section 3.3.2, p. 3-13, par. 3 and 4:
Confusion is again created by the attempt to omit perfecting
presses or to equate a printing couple on a heatset web offset
press to a single press unit instead of the two printing units
involved. The importance involves both materials and consumption
per press unit and the costs of process modification for each
unit, i.e., a five couple heatset press involves ten printing
units.
Section 3.4.1.1, p. 3-13, par. 1, sentence 2:
Change "web" to "roll."
Section 3.4.2, p. 3-20, par 1, sentence 2:
Delete "image plate" and replace with "lithographic plate".
-------
Insert the word "usually" between the words "plate" and
"first" because exceptions exist in Dahlgren type dampening
systems.
Section 3.4.2, p. 3-20, par. 1, last sentence:
Begin sentence with "The lithographic plate then..."
Section 3.4.3, p. 3-23, par. 2 and 3:
Move the last sentence in paragraph 2 to the last sentence
in paragraph 3 and revise to read: "The anilox and injector
inking systems are used principally on newspresses."
Section 3.4.4, p. 3-28, par. 1, sentence 2:
Delete "metering" and replace with "fountain"-
Section 3.4.5, p. 3-28,-par. 1, last sentence:
Delete "sets" and replace with "dries".
Section 3.4.5, p. 3-28, par. 2, sentence 4:
Delete "much" and replace with "controlled portions".
Figure 3-17, p. 3-29:
The "M" roll should be the "F" roll for fountain roll and a
metering roll should be introduced tangential to the chrome roll,
Section 3.4.5, p. 3-32, par 2, sentence 1:
Delete "270" and replace with "220."
Section 3.4.5, p. 3-32, par. 1, sentence 2:
Change "burning much" to "oxidizing some of the oil." The
original statement may have been true for direct flame dryers,
but is not the case in hot air dryers. This point has caused
confusion in application of the AP.42 retention factors to
heatset printing in the past.
Section 3.5.1, p. 3-36, par. 1 sentence 3:
Insert "form a continuous film which fixes the "between"
"Binders" and "aid."
Section 3.5.1.1, p. 3-36, par. 1, sentence 2:
Delete the word "inks" and replace with "ink vehicles."
Section 3.5.1.1, p. 3-36, par. 1, last sentence:
Insert the word "approximately" between "of" and W90°F"
Section 3.5.1.1, p. 3-36, par 3, sentence 1:
Delete the word "solvent" and replace with "ink oil."
Section 3.5.1.1, p. 3-36, par. 3, sentence 2:
Delete the word "solvents" and replace with "oils."
Same change should be made in the last sentence in the
section.
-------
Section 3.5.1.2, p. 3-36, par. 1, sentences 1:
Revise to: Non-heatset ink oils have lower vapor pressures
than heatset ink oils and the inks are not as viscous.
Section 3.5.1.2, p. 3-37, sentence 2:
Insert "to 8" between "4" and "hours"
Section 3.5.1.2, p. 3-37, par. 1, sentences 2, 4 and 5:
Delete the word "dry" in all three sentences and replace
with "set."
Section 3.5.1.2, p. 3-37, par. 2, sentence 1:
Insert the words "in some newspaper inks" between "popular"
and "for.."
Section 3.5.1.2, p. 3-37, par. 3, sentence 1:
Delete the word "another" and replace with "the major."
Section 3.5.1.2, p. 3-37, par. 3, sentence 3:
Delete "4" and replace with "8."
Section 3.5.1.4, p^ 3-38, par. 2, sentence 2:
Infrared inks are not radiation curing inks.
Section 3.5.1.4, p. 3-38, par. 2, sentence 3:
Delete "cross-linking proprietary chemical components" and
replace with "proprietary cross-linking chemical compounds"
Section 3.5.1.4, p.3-38, par.2, sentence 5 and 6:
Delete the word "mechanisms" and replace with "components."
Section 3.5.2, p. 3-39, par. 1, sentence 1 and 3:
Delete the word "printplate" and replace with "lithographic
plate."
Delete the word "good" and replace with "competitive."
Section 3.5.2, p. 3-39, par. 1, sentence 3:
Change to "acids and buffer salts."
Delete the word "printplate"
Section 3.5.3, p. 3-41, par. 1 and 2 and the balance of the par.:
Once the distinction between blanket and press cleaners is
established, as in the beginning of the second paragraph, then
the distinction should be maintained throughout the section.
Par. 1, last sentence should start: "Blanket cleaning is
required "
Cleaning blankets, for example, once or twice a shift would
be very infrequent in heatset web offset printing. The frequency
is dependent upon many factors involved with specific printing
jobs.
10
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It is industry's experience that the more viscous the ink,
i.e., sheetfed and heatset web offset, the more difficulty will
be encountered in the cleaning and the greater the need for
cleaner solvency to maintain efficiency.
Section 3.4.5, p. 3-34, Figure 3-21:
The figure needs further captioning to explain how the chill
stand functions in the printing process.
Section 3.4.6, p. 3-32, par. 2, last sentence:
Revise as follows: "...of printed paper from the dryer by-
passing the folder, moving through the sheeter and onto the
delivery."
Section 3.5.3, p. 3-41, par. 5, sentence 1:
Delete the words "boiling", "flammable", and "greater" and
replace with "flash", "ignitable", and "less", respectively.
Section 3.5.3, p. 3-42, par. 2:
Do not believe that proposed RACT cleaning solutions could
function for UV or thermally catalyzed inks.
Section 3.6, p. 3-42, par. 1, sentence 1:
Delete the word "processes" and replace with "steps."
Section 3.6, p. 3-43, par. 2:
Models for heatset and nonheatset web offset omit
consideration of single color (one to two unit) presses, a very
common production unit. Total units should range from 1-6 in
both models for very small plants.
Omission of perfecting presses eliminates probably the most
common press in heatset web offset printing. Four printing
couples with eight printing units and five couples with ten units
are probably the most popular presses.
Using 3000 annual hours of operations for all models
exaggerates equipment utilization for all but the largest plants.
A graduated scale of operations ranging from single shift,
approximately 1500 hours, to two shift, 3000 hours (in medium
size plants), and to 45000 hours for the largest plant size
probably constitute better levels of productivity.
Please see suggested revised Tables 3-1 and 3-2 in Appendix
A.
Section 3.6.1, p. 3-46, par. 2, last sentence:
Clarify what is expected from plant records.
Section 3.6, p. 3-44, Table 3-1:
To attribute single blanket status to total units for
Heatset and Non-Heatset Web Model plants seriously biases their
comparison with single units in sheetfed and other presses.
11
:3
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Section 3.6.2, p. 3-47, Table 3-3:
A 30-40-fold increase in ink consumption per unit is
postulated when comparing 4 total units for sheetfed with 4 units
for heatset web offset. This does not make sense. Please refer
to the discussion of p. 5-1, paragraph 1. In addition, alcohol
use rates exceeding ink use rates in non-heatset web offset is
very questionable for the industry segment.
Section 3.7, p. 3-49, references:
Reference number 5 needs updating, the 14th edition (1989)
of the Pocket Pal is available.
Reference number 7 needs updating, the 5th edition (1988) of
the Printing Ink Handbook is available.
Section 4.1, p. 4-1, par. 1, sentence 2:
Delete "where the solutions contains isopropyl alcohol" and
insert the phrase "solution, which contains isopropyl alcohol (or
alcohol substitutes)"
Insert "partially" between "are" and "driven."
Section 4.2, p. 4-1, par 1, last sentence:
Suggest deletion of "for reuse" since lithographic printers
rarely reuse the recovered VOC.
Section 4.2.1-4.2.3.3: thru 4-14; p. 4-2 thru 4-14:
The description of the incinerators did not appear to be
based on typical current design parameters or current
technologies.
Section 4.2.1, p. 4-2, line 6:
Delete "ignition" and replace with "combustion"
Section 4.2.1.1 , p. 4-2 and 4-3, par. 1:
This document assumes that all thermal units use a
combustion air source for burner performance. This can lead to
erroneous data on operating cost both electrical and gas. Some
incinerators use a raw gas burner. Fuel consumption can be about
35 percent lower for raw gas burners.
Section 4.2.1.1, p. 4-2 and 4-4:
The document assumes that over 0.75 seconds residence time
and operating temperatures of 1600°F are necessary to achieve
proper cleanup. Again, this can be expensive when calculating
operational costs. For reasonable control with new equipment at
99% and at 95% in continuing service, a temperature of 1350 °F
and a residence time of 0.5 seconds is sufficient. Recuperative
thermal incinerators have a temperature limitation of about 1450
to 1500°F due to the metal heat exchangers. Changes to these
levels as recommendations would allow for significant savings in
operating costs.
12
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Section 4.2.1.1, p. 4-4, par. 1, sentence:
If secondary heat recovery is used, note that appropriate
equipment prices should be added.
Section 4.2.1.1, p. 4-3, par. 2, last sentence:
Please provide a reference.
Figures 4-1 and 4-2, p. 4-3 and 4-5:
Induced draft fans now rarely used.
Section 4.2.1.2, p. 4-6, par. 1:
Delete sentence referring to hazardous waste incinerators.
This is not relevant to VOC control from lithography. Very
questionable whether the kinetics of oxidation for C^ to C5
alkanes should be extrapolated to C12 and C18*
A reference to the increased formation of NOX/ a
photochemical reactant, as incinerator temperature is increased
from 1400° to 1600°F should be included.
Section 4.2.1.2, p. 4-6, par. 2, sentence 1 and par. 3, p. 4-7:
States that al. incinerators can obtain 98% destruction
efficiency if operated at 14OO3 F- with a 0.75 second residence
time. Not necessarily correct as some new units will not attain
this value because of poor mixing or poor design.
Section 4.2.1.3, par. 1, p. 4-7, sentence 2:
First and only mention of "fluctuations in flows." Multiple
press emission controls by a single incinerator requires a
variable volume burner in conjunction with extensive valving
which should be referenced.
Section 4.2.2.1, p. 4-7, par. 1, sentence 3:
No mention is made of mixed oxide catalysts.
Section 4.2.2.1, p.4-7, par. 2, sentence 2:
Delete "about" and replace with "above"
Section 4.2.2.2, p. 4-9, par. 2, sentence 2:
Masking is not completely reversible as this paragraph
indicates.
Section 4.2.2.3, p. 4-10, par. 1:
Catalytic Oxidizer Efficiency. Suggest use of the term
gaseous hourly space velocity (GHSV) rather then catalyst-to-vent
ratio. For the example in this section the GHSV would be
calculated as follows:
16.8 sft3 * 60 seconds * 60 minutes = 60,480 sft3 air
second minute hour hour
60.480 sft3/hr = 120,960 (hr-1)
0.5 ft3 catalyst
13
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Thus this section states a 96% VOC destruction rate at 840°F.
operating temperature with a space velocity of 30,000 to 120,000
hr-1 GHSV. More typical is a space velocity of 9000 GHSV at
650°F. This low space velocity means that there is a larger
volume of catalyst for each scfm of exhaust.
Replacement will be accelerated by frequent process cycling
in heatset web offset printing which translates into frequent
temperature cycling of the catalyst.
Section 4.2.2.2, p. 4-10, par. 2, sentence 2:
The reference to service life of a catalyst of being 3 to 6
months which is true for monolith units, but not for deep bed
bead substrate design units. Some deep bed manufacturers provide
a 30 month catalyst warranty even with normal levels of heatset
poisons present and catalysts have been in lithographic service
in excess of five years..
Section 4.2.3.1, p. 4-11, par. 1, last sentence:
Delete "or"
Delete "first drop of liquid is formed" and replace with
"condensation can occur"
Section 4.2.3.1, p. 4-11, par. 2, sentence 2:
Delete the word "valuable"
Section 4.2.3.2, p. 4-14, par. 2 and 3:
A CTG requires actual experience, not "expected low
solubility of organics" or a five year carbon life.
Section 4.2.3.2, p. 4-14, par. 4, sentence 4:
What would be done with a 3 shift operation? Too much
conjecture with an unproved system. The system as described is
not applicable to a 3 shift operation.
Section 4.2.3.3., p. 4-15, par. 1, sentence 2:
Delete the word "dryer" and replace with "boiler."
Section 4.3.1, p. 4-15, par. 2, sentence 1:
"Ink emulsification" can be fountain solution in ink or ink
in fountain solution (tinting). Which is improved? Please say
so.
Section 4.3.2, p. 4-17:
Delete entire section.
Section 4.4.1., p. 4-1, par. 1. sentence 2:
Delete "printplate" and replace with "lithographic plate."
Section 4.4.1, p. 4-18, par. 1, sentence 1:
Isopropy1. alcohol use in lithographic dampening is not traditional
It was introduced by Dahlgren with the return flow dampening
14
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systems designs in the 50s.
Section 4.4.1, p. 4-18, par. 1, last sentence:
The reference is to a survey conducted in 1986 by NAPL and
the average then was 15 percent and not 17 percent. The current
average is believed to have dropped since 1986.
Section 4.4.1.1, p. 4-18, par..1, last sentence:
Your authority should be the printers, not the suppliers.
Section 4.4.1.1, p. 4-18, par. 2, sentence 2:
A brush and a spray generate new water/air interfaces with
the maximum surface tension, i.e., they act to increase not
decrease the instantaneous surface tension of water solutions.
Section 4.4.2, p. 4-20, par. 1, last two sentences:
Delete "lower volatility" and replace with "low volatility."
d-limonene is a carcinogen for male rats.
Section 4.4.2, p. 4-20, par. 2:
The feasibility of 30 percent VOC cleaning products has not
been demonstrated and cannot be supported for RACT. Rule 1171
for the South Coast Air Quality Management District has been
finalized and supersedes Rule 1130. Rule 1171 no longer requires
the 30 percent or less VOC cleaning products.
Section 4.5. p. 4-21, Reference 3:
Delete v:.e word "Tech" and replace with "Tec."
Section 5.1.1, p. 5-1, par. 1, sentence 2:
The 40 fold greater ink use rate for web than for sheetfed
cannot be jur^ified. Some of this difference, as explained
previously, is due to the inclusion of two printing assemblies in
a web printing unit, (preferably called a perfecting couple), but
even a 20 fold difference in ink use rate is excessive.
Section 5.1.1, p. 5-1, par. 1, sentence 4:
Operating hours for model plants should be scaled from 1500
hours to 3000 hours in medium size plants and to 4500 hours for
the largest plants reflecting the different equipment utilization
and costs.
Section 5.1.2, p. 5-2, par. 1, sentence 1:
Insert the words "print and" between "...retained by the..."
and "substrate."
Section 5.1.3, p. 5-4, par. 1, sentence 3 and p. 5-5, par 1.,
sentence 2:
Rather than quoting initial performance statistics for the
emission control techniques, the CTG requires values
representative of continuing performance levels.
Section 5.2.1, p. 5-5, par. 1, sentence 1:
Delete the words "blanket and" and change the word "print"
15
"7
: t
-------
to "1ithographic."
Section 5.2.1, p. 5-5, par. 2, last sentence:
No use of isopropyl alcohol is included in Table 5-2 since all
tabulated VOC emissions are those from the inks. Is the
reference to Table 5-3?
Section 5.2.2, p. 5-7, par. 1, sentence 2:
Delete the word "printplat*e" and replace with "lithographic
plate."
Section 5.2.1, p. 5-6, par. 1, sentence 2:
Statement incorrect since the plate non-image area
continuously carries a water film (evidenced by numerous studies,
previously referenced) and much of the fountain solution is
emulsified in the ink. Process studies of web printing
referenced elsewhere have estimated the distribution.
Section 5.2.2, p. 5-7, par. 2, sentence 1:
The estimated average of 75 percent VOC is questioned. It
seems unusual to have one absolute value given for all
substitutes. A range of values should be provided.
Equation (5) should be revised to read "VOC emissions from
alcohol substitute = Weight of alcohol substitute x %VOC in
concentrate/100%"
Section 5.2.6, p. 5-11 and 5-12:
Suggest deletion on basis of previous comments.
Section 5.2 General:
Nowhere is the background developed for the use of brush or
spray dampeners, particularly on web equipment to reduce the need
for isopropanol.
Section 5.3.1, p. 5-12, par. 1, sentence 4:
To state that "the emissions are equal to the amount of
cleaning solution used neglects the following:
(1) Blanket cleaning solution partially remains in the
cloth and goes to recovery of waste.
(2) Blanket cleaning solutions on a heatset blanket
go into the ink and into the dryer for emission to
a control device.
(3) Press cleaning solution residues, i.e., roller
washes, are put into tanks for recycling or waste
disposal.
Provisions need to be made.
Section 5.3.2, p. 5-13, par. 1:
Cannot justify cleaning compound recommendation based on 0
to 30 weight percent VOC. Moreover, distinction needs to be made
between the VOC needs for blanket and press cleaning as
previously described for Section 2.5.6, p. 2-10.
Section 6.1.1, p. 6-2, par. 2, sentence 3:
16
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This section implies that the emission control device costed
for a given model is based on the match between the rated gas
flows of the press dryers (note that these are not unit
determined, but press dependent) and the control equipment design
range. This leads to a fictional model of many press dryers with
ducts and valving feeding into single control devices, but no
apparent provision for the costing of these multiple controls.
Explicit development of the models for heatset web offset
facilities are required if the CTG is to be intelligible to its
audiences.
Table 6-1, p. 6-2:
Operating temperature of 1000°F for a condenser filter is
not correct. Thermal incinerator temperatures should be 1400 °
F. Catalytic incinerator temperatures should be 650 ° F.
Operating temperatures of 1600°F for thermal and 900°F for
catalytic afterburners must be revised to lower, more realistic
values.
Section 6.1.1, p. 6-3, par. 4, last sentence:
Delete the word "dryer" and replace with "boiler."
Section 6.1.2, p. 6-4, par. 1, sentence 1:
The term "model plant dryer exhaust streams" is meaningless.
The relation to the model plant press dryer exhaust streams needs
to be defined. The relationship between numbers of presses and
dryers is thoroughly confused (Table C-l, P. C-2) and does not
correspond to industry practices generally-
Section 6.1.1, p. 6-3, par. 3, sentence 3:
The length of the ductwork and the cost are going to be
determined principally by the number of press dryers to be
connected to the emission control device.
No mention is made of costs associated with valving and
automatic controls for adapting to changing flow rates as presses
come on and off stream.
Section 6.1.2, p. 6-5, par. 2, sentence 3:
Operating and maintenance labor requirements better
approximated at 1 hr. per week for both incineration methods.
Table 6-3, p. 6-8:
The table represents a number of misconceptions with respect
to the differentials between technologies. The biggest areas of
concern are maintenance labor costs being lower on condenser
filter units than incineration units, and the cost of catalyst
replacement. Four years catalyst life should be more
representative than two years.
Section 6.1.4, p. 6-8, par. 1, sentence 4:
Adapting a press dryer for use of alternative fuels (other
than gas) is expensive and unless a cost is allowed, no credit
17
-------
should be given. Alternatively change "dryer" to "boiler."
Condensed ink VOCs, moreover, may be considered as hazardous
waste in some areas with attended costs.
Section 6-4. p 6-10:
Remarkable that catalytic costs so closely approximate
thermal on annual basis. The large magnitudes of changes for
different size plants is suspect.
Section 6.2.1, p. 6-11, par. 2, last sentence:
It is questioned why changeover costs are recognized for a
24 hour per day schedule, but not for the 16 hour per day model
plant analysis. Two crew operations are just as susceptible to
costs -as are three crews.
Section 6.2.3, p. 6-15, par. 1:
Suggest deletion of entire paragraph.
Section 6.2.1, p. 6-12, Table 6-5:
The savings estimated for heatset web offset printing are
believed to be much too large principally because this industry
segment has been using brush type dampeners to decrease the need
for isopropyl alcohol.
Section 6.3, p. 6-15, par. 1, sentence 1, and Table 6-9:
Eliminate term "non-toxic."
No provision is made for increased time required for blanket
cleaning, increased waste (printed paper and cleaning materials)
and increased volume of cleaning solutions.
Table 6-8, p. 6-16:
Please delete entire table.
Section 6.4.1.2, p. 6-19, par. 4, sentence 2:
Delete initial part of sentence through "however."
Section 6.4.1.1, p. 6-18, par. 2, sentence 1:
Not a product of incomplete combustion.
Section 6.4.2.1, p. 6-21, par. 1, sentence 4:
Wastewater treatment plants may refuse to accept this
waste in which case the printer may have to process the water or
have it disposed by a waste hauler. Delete the last sentence
because the risk is not negligible.
Section 6.4.1.3., p 6-21, par. 1, sentence 4:
The qualification of "equal quantities" has not been tested
and seems doubtful.
Section 6.4.2.1, p. 6-21, par. 2, sentence 5:
The oils (not solvents) can be burned in the dryer only if
expensive modifications are made. The oils are often acidic and
require extensive filtration prior to them being burned. Burning
18
•j'
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these oils may also introduce treatment, storage, and disposal
issues with respect to state hazardous waste disposal
regulations.
Section 6.4.3., p. 6-22, par. 1:
Detergents and emulsified inks will be water pollutants.
Section 6.4.4, p. 6-22, par. 1, sentence 3:
Natural gas is the principal fuel, not supplemental.
Section 6.4.4, p. 6-23, par. 2, last sentence:
Capital and operating costs for steam generation must be
included.
Section 6.4.5, p. 6-23, par. 1, sentence 2:
Insert the word "heatset" between "model" and "plants"
Section 6.4.5, p. 6-23, par. 2, sentence 1:
Recovered oil by condenser controls cannot be used as fuel
for dryers without modification of the dryer burner.
Suggest more appropriate summary such as:
Properly designed incineration equipment has remained the
dominant means of VOC control in the heatset printing industry
because of its low maintenance, its overall reliability, its high
level of destruction efficiency, and its overall cost
effectiveness.
Condenser filters have been used to a limited extent due to
the perceived potential benefit of solvent recovery, lower NOx
emissions, and lower fuel consumption; however, because of high
maintenance, added cost of disposal of unusable waste oil and
water, and urreliable cleanup efficiency this approach has not
gained wide acceptance in the printing industry in states where
compliance testing is required.
Table 6-10, p. 6-20:
Values for NOx emissions are very high for both incineration
methods. Values should be checked with EPA publication AP-42.
Section 6.5.1, p. 6-25, sentence 2:
A relatively unproven emission control method without long-
term performance records is not suitable for RACT.
Section 6.5.2.1, p. 6-25, par 1, sentences 1, 2, and 3:
Delete "1.6" and "3" percent and replace with "8" and "12",
respectively.
Section 6.5.2.2, p. 6-25, par 1, sentence 1:
Delete with no more than 24 single blanket units (or 12
double blanket units)—" Delete "6" and replace with "10"
percent.:
19
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Delete "10" and replace with "15 percent"
Section 6.5.2.2, p. 6-26, par 1:
Delete paragraph. No justification for different treatment
of sheetfed pressrooms.
Section 6.5.3, p. 6-29, par. 1:
Requires independent treatment of blanket and press
cleaners. Industry required higher VOC content cleaners to
maintain efficiency and control waste.
Section 6.6, p. 6-28, Reference 21:
Delete "Concerns" and replace with "Conservation"
Section 7.2, p. 7-2, definition of Cleaning Solution:
Revise to "liquids used to remove ink and debris from the
operating surfaces "
Section 7.2, p. 7-2, definition of Dampening System:
Delete the word "press" and replace with "lithographic
plate."
Section 7.2, p. 7-3, definition of Heat-set:
Delete the word "set" and replace with "evaporate ink oil
from"
Section 7.2, p. 7-4, definition of term lithography:
Delete the word "impressed" and replace with "recessed."
Section 7.2, p. 7-3, definition of term press:
Delete words "finished product" and replace with "printed
sheet or web".
Section 7.2, p. 7-2, definition of term fountain solution:
Delete the phrase "it spreads better across the printing
surfaces" and replace with "it spreads across ink and the plate
surfaces".
Section 7.3, p. 7-3, par. 1, sentence 1:
The statement that most printing facilities consist of at
least two types of offset lithographic printing is erroneous. A
more accurate description of facilities would be that most of
them are dedicated to one process only and that some may contain
more than one type of offset printing process.
Section 7.3, p. 7-3, par. 2, sentence 1:
The possible definition of affected facilities of "one or
more sub-facilities involved in similar offset lithographic
printing processes" is confusing and contradictory and needs to
be revised.
Section 7.3, p. 7-4, par. 2, sentence 3:
Delete the word "chapter" and replace with "document"-
20
r~
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Section 7.3, p. 7-4, par. 2, sentence 1:
The other suggested definition of affected facility of "an
individual printing press with its own individual dryer exhaust
controls (if heatset) or the combination of two or more presses
and the common dryer exhaust, or fountain solution and cleaning
solution delivery systems that they share" is not accurate and
confusing.
Section 7.3, p. 7-4, par. 3, sentence 2:
Since only offset lithography is subject to this document,
this entire concept is out of context.
Section 7.4, p. 7-4, par. 1, sentence 4:
Delete the word "equipment" and replace with "material"-
Section 7.4, p. 7-5, par. 2, sentences 2-5:
In the discussion of control device efficiency, there is no
consideration of the variable flow rates and concentrations of
organics entering the control device, which will affect
reduction efficiencies. The test method used to measure the
control device efficiency will also affect the calculated
destruction efficiency values. Delete "20ppmv" and replace with
"50 ppmv-"
References to the statements should be provided.
Section 7.4, p. 7-5, par. 2, sentence 5:
A reference to the statement should be provided.
Section 7.4, p. 7-5, par. 4, sentence 1:
Delete the word "equipment" and replace with "material"-
Section 7.4, p. 7-6, par. 1, sentence 1:
Delete the word "densities" and replace with "specific
gravities".
Section 7.5, p. 7-6, par. 1, sentence 1:
The level of business usually does not require a plant to
"be running at full operating conditions and flow rates." To
insist on this qualification will increase testing costs many
fold and generate large amounts of solid waste. Prefer "running
at representative conditions and flow rates."
Appendix A, Section A-2, p. A-4:
Fourth reference should be "Carman," not "Carmen."
Corporate should be "TEC" not "Tec."
Appendix B, Section B-1.0, p. B-l:
The high ink use for web is believed due to the assumption
that web press units have a single printing assembly as opposed
to the two assemblies characteristic of perfecting heatset
presses (blanket-to-blanket). The result biases the entire
heatset model analyses.
21
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£>, section t>-o.u, part ±, .Last sentence:
Assumption of "through stagnant, non-diffusing
air" invalidates application to new solution surfaces moving on
rotating rollers.
Application to water evaporation rates calculated by the
same approaches might promote acceptability.
Appendix C., p. C-2, Table C-l, last column:
The 2:1 ratio of press dryers to presses is not typical of
the heatset web offset industry though it is encountered
infrequently.
Appendix C, p. C-3, Table C-2, column 3:
Why is total exhaust from plant All five times greater than
that from AI when the ratios of press units are 16/6, ink use
340/154 and dryers 4/2?
Appendix C, Section C-2.0, p. C-4, par. 1:
Heat Value is typically in the range 6 to 13Btu/scf not "1.2
Btu/scf."
Appendix C, Section C-2.IF, p. C-5:
Temperature should be "1400° F." not "1600 °F."
Appendix C, Section C-2.2B., p. C-9:
No provision for valuing in duct work involving multiple
presses on single emission control unit.
Appendix C, Section C-3.0, p. C-15:
Heat value should be 6 Btu/scf, not 1.2 Btu/scf.
Appendix C, Section 3.IK, p. C-15:
Temperature should be "650°F-" not "900°F."
Appendix C., Section C-3.2.B.I, p. C-21:
Why should equipment cost for 0 percent heat recovery exceed
that for 35 percent?
Appendix C, Section C-3.3C, p. C-25:
Should be "precious metal catalyst" not "metal oxide
catalyst." Base metal catalysts are very rapidly poisoned by
sulfur.
Replacement materials for 95% destruction efficiency should
be "4 years" not "2 years." Vendors currently warranty catalysts
for 2-1/2 years even in the presence of normal amounts of
phosphorous and silica poisoning.
Appendix C, Section C-4.2D, p. 3-36:
Real plants, particularly A-IV counterparts, operate 3
shifts per day and will not have time today as cool the carbon
beds. The model is inadequate.
Appendix C., Section C-5.4, p. C-42, 43:
22
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Delete entire section.
Section 7.5, p. 7-6, par. 2, sentence 1:
It is our understanding that this section will be amended to
indicate that Method 25A will be recommended when outlet values
are below 50 ppmv as C-^. Method 25A should be the recommended
method for add-on control devices and for screening outlets of
incinerators. The relatively small negative bias experienced
with Method 25A tests of heatset afterburner outlet exhausts
should outweigh the relatively large inconsistencies,
difficulties, and expense of Method 25.
Section 7.5, p. 7-6, par. 3, sentence 3:
A reference should be provided.
Section 7.6.1, p. 7-7, par. 1, sentence 2:
Please provide details and reference to modification of
EPA Method 24. In recommending and specifying a test method
for the determination of founta:1- solution VOC content, EPA
needs to consider the limited technical and financial
resources of the average printer.
Section 7.6.1, p. 7-7, par. 2, sentence 2:
The concept embodied by th^s statement is misplaced. Title
III of the Clean Air Act Amendments of 1990 does not ban the
use of any listed hazardous air pollutant. Eventually, Title III
will require certain source categories to control the emissions
of hazardous air pollutants through MACT.
Section 7.6.3, p. 7-8, par. 1, sentence 1:
See comments outlined at 7.6.1, p, 7-7, par. 2, sentence 2.
Section 7.7.1, p. 7-8, par. 2, sentence 3:
Please provide a reference for this statement.
Section 7.7.1, p.7-8, par. 2, sentence 4:
Please provide a basis for drawing the conclusion that
temperature monitors with strip charts are "relatively
inexpensive." Were all of the capital, installation, operation,
maintenance, and personnel costs incorporated into the economic
models used to determine cost/ton reduction ratio?
It is questioned if monitoring temperature rise across a
catalytic bed provides meaningful data, especially since inlet
flows and organic concentration will vary creating variations in
temperature rises across the bed.
Section 7.7.1, p. 7-8, par. 3, sentence 3:
Efficient operation of the heatset dryer demands that the
pressure within the unit be lower than the pressure in the
pressroom.
Please define test methods used to qualitatively measure air
flow direction. Please specify frequency of monitoring. Were
the capital, operation and maintenance costs including personnel
23
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associated with this testing and monitoring considered in the
economic models for determining cost/ton reduction ratio?
Section 7.7.2, p. 7-9, par. 2, sentence 1 :
Conductivity at best can only provide an indication of
fountain solution concentration. Because of daily and even
hourly fluctuations in conductivity of incoming tap water, which
is the most common source of printers water (i.e.
untreated), introduction of contaminants into the fountain
solution, and at times the need to add additional fountain
concentrate during the course of a print run, using
conductivity as a measure of concentration is limited.
The use of hydrometers and record-keeping are omitted.
These'are valuable sources of continuing information with minimal
associated costs.
Section 7.7.3, p. 7-9, par. 3:
See comments outlined above for Section 7.7.2, p. 7-9,
Section 7.7.4, p. 7-9, par. 1, sentence 1:
The industry questions the relative merits of requiring
continuous temperature monitoring at the fountain tray. With the
multitude of variables the printer must monitor and control,
the fountain solution temperature measurements should be limited
in number. A once per shift thermometer measurement of the
recirculator should be sufficient.
Were the capital, operation, and maintenance costs of the
measuring and monitoring equipment including considerations
of personnel included in the economic models used to
determine the cost/ton reduction ratio?
Section 7.7.5, p. 7-10, par. 1, sentence 3;
Please describe the term "continuous cleaning operations"
as applied to the offset lithographic industry-
Only the largest printers will possess a refractometer and
be able to use it efficiency. Conductivity meters for the
proposed use is questionable and would have to be standardized by
the supplier, not the printer. The manufacturers' cleaner
specifications of VOC content should be taken at face value for
record keeping purposes.
Recordkeeping frequency of cleaning solution use should be
very limited in small plant operations, i.e. once a week. Only
large plants need recordkeeping to be made on a more frequent
basis.
Differentiating between blanket and press cleaners and their
VOC contents is expected to require separate records.
24
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COMMENTS
APPENDIX C COST CALCULATIONS
DRAFT CTG
WEB OFFSET LITHOGRAPHY
GENERAL COMMENTS;
1. The two shift operating scenario for the model plants does
not represent this industry's method of operation and
especially it should not be assumed so that the third shift
would be available to such operations as carbon regeneration
and maintenance. These functions must be accounted for
during the operating day- The proper scenario would be
three shifts and seven day operation.
2. For all of the model plants, the hours of operation of the
control device should exceed the individual press operating
hours as not all of the presses will run simultaneously,
i.e., a distribution of zero to eight dryers running. In
addition, some control devices will have startup times
reguired and standby times reguired due to the length of
time reguired to reach operating conditions.
3. The carbon bed considered for polishing treatment of the
cooler-filter system cannot be regenerated by hot air or by
low pressure steam. Hot air cannot be used as air pollution
would only be regenerated. Additionally, air temperatures
of 550°F or higher would cause ignition of the carbon bed.
Low pressure steam, typically 125 psig, could raise the
carbon bed temperature to only 350 F and would not desorb
VOC's deposited from a 390°F dryer exhaust. LA Litho, who
operated a carbon adsorption system, found that 600°F and
vacuum conditions in an inert environment were reguired to
desorb. A functional regeneration system will add
considerable capital cost and the regeneration step will
reguire over a shift of time to conduct.
Systems such as described above should not be included in
the RACT documentation since they do not exist nor has it
been demonstrated they will function over an extended period
of time.
4. No provisions have been made in the capital costs of any of
the add-on controls for the safety purging of the gas-fired
dryer burners prior to introduction into the control system.
This would consist as a minimum of a damper system to vent
the purging air to atmosphere and an actuator to redirect
the damper(s) at the end of the purging cycle. Such a
damper system will cost $15,000 per damper system (at least
one reguired per press) to insure inherent fail safety.
5. No provisions have been made in the operating costs of the
cooler-filter systems for cleaning of the heat exchanger(s)
and the cleaning, replacement and disposal of the filter
media involved.
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Page Two
6. No provisions were made to correct the value of the
recovered solvent for the additional costs involved to
modify the dryer burner systems, to store the recovered
solvent and to operate and maintain these additional
systems.
SPECIFIC COMMENTS;
Page C-l. The 0.033 factor should be identified as related to
the amount of ink solvent applied per unit area
instead of being dimensionless. The amount of ink
applied varies with each customer's requirements and
is simplified in this equation only by assuming an
artificial average value for the model.
Page C-2. The annual ink usage rate appears reasonable for 3000
operating hours. However, the web speed is
inconsistent. That usage would indicate "type only"
printing, i.e., paperback books. It is probable that
reduced speeds should be indicated.
Page C-3. The Model plant A-I should all have 4,000 scfm Total
exhaust (Typographical error).
Page 6-4 indicates the dryer exhaust should contain
600-800 ppmv of VOC versus the 179-405 ppm listed in
the table. Which is correct? Using the values
assumed, the VOC for A-III appears to be 135 ppm.
Page C-4. The molecular weight of the heatset ink solvent is
too low. Magiesol 47, a typical solvent, has a
molecular weight of 195-205. Any solvent with a lower
molecular weight will have a higher vapor pressure
and will not condense to the same degree, rendering
the cooler-filter systems less effective.
The oxygen content of the dryer exhaust is usually
reduced to 18-19% by partial oxidation of the VOC
material, combustion requirements of the dryer burner
or due to the production of water vapor and carbon
dioxide. The typical analysis is 19% oxygen, 2% water
vapor, 0.5% carbon dioxide and 78.5% nitrogen.
In para C-2.1 B. 2., back calculations show that a
definition of standard conditions of 77°F and 29.92
in. of Hg was used. The definition of standard
conditions in the fan industry is 70°F and 29.92 in.
of Hg. Accordingly, the amount of scf in a Ib-mole is
386.73 scf/lb-mole.
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Page Three
Page C-5. In para C-2.1 E., the turndown ratio of 20,000 to 50
is not realistic (400:1). Flow turndown ratios due to
varying fan speed are usually 4:1 with an upper limit
of 6:1. This can be multiplied with dampers by
another 4:1 factor.
In para C-2.1 F., the 1600°F incineration
temperature is excessive for heatset ink solvents.
1200-1250°F will destroy the solvents while about
1400°F is required to destroy the carbon monoxide
produced.
Page C-6. In para H., for clarity the division sign used to
indicate the denominator should be changed to a /.
Page C-8. In para J. 1., additional air may be required
during high fire by the dryer burner(s), i.e.,
startup and speed or temperature changes, if the
exhaust air oxygen content drops below 16%. Note:
the air discharged from the thermal afterburner will
contain 12.1% oxygen, 8.2% water vapor, 3.7% carbon
dioxide and 76.0% nitrogen.
In para C-2.2 A., the equipment cost algorithms do not
consider the complex arrangement requiring the safety
purging of the dryers. The capital cost figures
appear to be about 25% too low.
Page C-9. In para C-2.2 C. , the auxiliary collection fan cost
does not reflect the increased pressure drop
requirements caused by the heat recovery equipment.
The pressure drop is a function of the capital cost
of the heat recovery equipment, thus the algorithm
must be examined. Higher percentage heat recovery
is associated with higher pressure drops and fan
costs.
Page C-ll. In para C-2.3 A. 1., the amount of operating labor
required is too high. A more appropriate level is
0.1 hour per shift. The only work to be performed is
a review of operating temperatures and an overview of
the condition of the equipment.
In para C-2.3 B. , the amount of maintenance labor
required is too high. A more appropriate level is
0.1 hour per shift. There is only one moving part,
the auxiliary collection fan, and the burner to
maintain. The materials should be projected as five
times the maintenance labor as a number of spares
should be on hand.
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Page Four
Page C-15. Similar comments as on page C-4. The molecular weight
of the heatset ink solvent is too low. Magiesol 47, a
typical solvent, has a molecular weight of 195-205.
Any solvent with a lower molecular weight will have a
higher vapor pressure and will not condense to the
same degree, rendering the cooler-filter systems
less effective.
The oxygen content of the dryer exhaust is usually
reduced to 18-19% by partial oxidation of the VOC
material, combustion requirements of the dryer burner
or due to the production of water vapor and carbon
dioxide. The typical analysis is 19% oxygen, 2% water
vapor, 0.5% carbon dioxide and 78.5% nitrogen.
Page C-22. Similar comments as on page C-9. In para C-3.2 D. ,
the auxiliary collection fan cost does not reflect the
increased pressure drop requirements caused by the
heat recovery equipment. The pressure drop is a
function of the capital cost of the heat recovery
equipment, thus the algorithm must be examined.
Higher percentage heat recovery is associated with
higher pressure drops and fan costs.
Page C-24. In para C-3.3. A. 1., the amount of operating labor
required is too high. A more appropriate level is 0.1
hour per shift. The only work to be performed is a
review of operating temperatures and surveillance to
identify any visual malfunctions.
Page C-32. In para C-4.1 B., the cost of the carbon adsorption
unit is too low. This is the only unit that is
sized based on the VOC content. All other units are
sized considering the air flow through the systems.
Accordingly, the sizing must reflect the maximum VOC
input, not the average. If cooling is inadequate or
filter effectiveness is low, the carbon may see up to
the full concentration of VOC. For these reasons
alone, at least two vessels of the size projected
should be used. Also, since low pressure steam will
not desorb the VOC from the carbon and hot air cannot
be used, the system must be more complex. The only
system that has been demonstrated to operate over an
extended period is the LA Litho method of desorption.
This system consisted of electric heaters within the
carbon bed, an inert gas system to prevent ignition
of the carbon and a vacuum pump and condenser system.
The increased sophistication of the desorption system
will increase the capital cost about 50% per vessel.
The new ECacj will be:
ECad = 2 * 1.50 * 68,000
= $204,000
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Page Five
Page C-34. In para C-4.2 A., the amount of operating labor
required is too low. In addition to reviewing
operating temperatures and pressures, cleaning
operations must be done as well as replace and
dispose of used filter media. Since these actions
must be done with the system offline, a more
appropriate level is 1.0 hour per shift. For those
systems with carbon adsorbers, a level of 10.0 hours
per regeneration is required. On the average, one
regeneration 'of the carbon is required each day.
Thus the operating labor for regeneration would be
5.0 hours per shift.
Page C-35. In para C-4.2 B. 1., the amount of maintenance labor
required is too low. The system consists of two
auxiliary collection fans, two to four cooling air
fans and at least two filter media belts. A more
appropriate level is 1.5 hours per shift.
In para C-4.2 B. 2., the amount of materials should be
increased appropriately.
No mention is made of the requirement for cleaning the
heat exchangers. For model plant A-III, each cooler-
filter will require six cleanings per year. Assume
cleaning requires sixteen manhours of labor, $1500 of
cleaning materials and $2000 to dispose of the
contaminated cleaning solution. Heat exchanger
cleaning would cost:
Labor = 2 * 6 * 16 * 17.21 = $3,304
Materials = 2*6* 1500 = $18,000
Disposal = 2 * 6 * 2000 = $24,000
Total Annual Heat Exchanger cleaning = $45,304
No mention is made of the requirement for either
replacing the filter media in the traveling bed filter
or the cleaning and replacement of the candle filters.
Using a 2 year filter life for the candle filters and
a candle filter cost of $1000 per candle, the
replacement cost would be:
Filters = (20,000/500) * 1000 = $40,000
Replacement
Labor = 32 manhours * 17.21 = $551
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Page Six
Annual Filter Replacement Costs
(Materials & Labor) = (40,000 + 551) * CRF
= $40,551 * 0.500
= $20,276/yr
In para C-4.2 B. 3., the assumed carbon life of five
years appears too long. LA Litho found that about
5% of the carbon bed became unusable each regeneration
due to contamination by high molecular weight material
that would not desorb under the temperature and vacuum
conditions available. Using $25,647 cost per
replacement and a yearly average of one regeneration
per day, an appropriate annual carbon replacement cost
is:
Annual Carbon Replacement Costs
(Materials & Labor) = 25,647 * 5 * 52 * 0.05
= $333,411
Page C-36. In para C-4.2 D. , the assumption that additional
electricity costs are negligible is incorrect. Carbon
bed pressure drops are expected to be 1.67 in. w.c.
per foot of thickness. Using a bulk carbon density of
27 Ib/cf and the 11,605 Ib of carbon, 430 cf of carbon
will be used. It is likely that a 3 foot carbon bed
will be used to keep the tank cross-sectional area to
about 143 sq.ft. or 13.5 ft. in diameter. This will
produce about a 5 in. w.c. pressure drop at the
beginning of the carbon bed life, increasing to up to
12 in. w.c. as the proportion of fines increase.
Additionally, the "extra" capacity of the system fans
is used to extend the times between cleaning or
replacement of the filter media. Use of this capacity
to produce carbon bed flow will greatly increase the
cleaning or replacement frequency.
In para C-4.2 E., the carbon bed cannot be regenerated
by low pressure steam. Obviously, the daily
replacement of carbon at $25,647 per replacement is
unacceptable. LA Litho has used electrical heating
under inert atmosphere, followed by vacuum pumping and
condensation of vapors. A vacuum of 1 Torr was
required. Electricity will be required for the heater
elements and the vacuum pump. The electricity
required for each regeneration is:
Electricity = 11.605 * 0.24 * (600-100) * 1.1
for heating 3413
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Page Seven
= 449 KWH
Electricity = 5 hours at 25 KW
for pumping
= 125 KWH
Total Electrical use = 449 + 125 = 574 KWH
Assuming inert gas costs of $100 per regeneration and
cooling water costs to condense the VOC of $200 per
regeneration•, the desorption costs are:
Regeneration Costs = 5 * 52 *((0.061)(574)+ 300)
= $87,104
In addition, there was no provision for capital costs
of a condensing and separating system for the
steaming. The water condensate will be contaminated
with the water-soluble VOC from the fountain solution
and must be treated before reusing as boiler feedwater
or discharged.
Page C-38. In para C-4.2 M. , the recovery credits are the net of
value of the solvent recovered minus the costs of
handling the solvent. Two dispositions are likely for
the recovered solvent - sale or burning as alternate
dryer fuel. The price available for recovered solvent
is about $0.25/gal. The value as an alternate fuel in
dryers appears to be about $0.63/gal but some
additional expenditures are required which reduce the
value of both dispositions.
A storage tank farm will be required to accumulate the
recovered solvent. The recovery rate is approximately
10 gal/day which will not satisfy the burner fuel
requirements. Burner fuel storage capacity should be
at least 1000 gal and storage for eventual sale would
probably be about 7000 gal for economy in shipment.
The tank farm will require minimal operating labor,
consisting mainly of monitoring tank levels and pumps
during transfers.
Use of recovered solvent as an alternate burner fuel
will require the modification of existing dryers to
dual-fuel systems. This involves the addition of a
liquid fuel feeding system, a new dual fuel burner and
modifications to the dryer combustion chamber to
handle the longer flame length of the liquid fuel.
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Page Eight
Modification costs are over $20,000 per dryer
burner. The sequence of operation of a dual fuel
burner is to start up on gaseous fuel, switch over to
liquid fuel and, on controlled shutdowns, switch back
to gaseous fuel.
The use of a liquid fuel involves much more
maintenance labor and materials on the dual fuel
burner. The systems operated to date have experienced
some of the following problems: sooting due to poor
atomization of the liquid fuel because of dirty
nozzles to the extent the white paper web became gray,
failure of the fuel pump due to fine solids content in
recovered solvent that eroded the metal surfaces, and
corrosion due to the high acidity of the recovered
solvent from the presence of partially oxidized
material. Since failures in the dryer burner results
in lost productive time, the lack of reliability has
resulted in an almost total absence of liquid fueled
dryers in the industry.
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Environmental Conservation Board
of the Graphic Communications Industries
n Intra-lndustry Organization for Environmental Affairs
1899 Preston White Drive
Reston, VA 22091-4326
703/648-3218 • FAX 703/648-3219
Environmental Conservation Board
of the
Graphic Communications Industries
Amendments to
APPENDIX D
Offset Lithographic Printing
CTG Model Rule
The following text of Appendix D, the CTG Model Rule for Offset Lithographic Printing has been
amended to reflect the suggested changes of the Environmental Conservation Board of the Graphic
Communications Industries (ECB). Intcrliniatcd language in the text is language that is presently
included in the Model Rule that ECB recommends be omitted. Language in ALL CAPITALS
LETTERS AND BOLD FACE is language that ECB recommends be added to the original text.
A second copy of Appendix D follows which deletes the interliniated language, with only the
Model Rule as recommended by ECB remaining.
printed on recycled paper with vegetable oil ink
-------
APPENDIX D
OFFSET LITHOGRAPHIC PRINTING
CTG MODEL RULE
D.I INTRODUCTION
This appendix presents a model rule to limit volatile organic compound (VOC)
emissions from offset lithographic printing operations. This rule is for informational
purposes only and, as such, is not binding on the air quality management authority.
However, EPA expects that State and local air quality rules developed pursuant to
this CTG will address all the elements covered in the model rule.
The remainder of this appendix contains the model rule. Separate sections cover
the following rule elements: applicability, definitions, emissions standards,
equipment standards, emissions standards testing, equipment standards testing,
monitoring requirements, and reporting/recordkeeping.
D.2 APPLICABILITY
The provisions set forth in this model rule apply to the offset lithographic
printing industry only. There are four types of offset lithographic printing: heatset
D-l
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web, non-heatset web (non-newspaper), non-heatset sheet-fed, and newspaper (non-
heatset web). An affected facility may be defined as follows: one or more printing
operations involved in at least one type of offset lithographic printing process.
Other types of printing operations, such as flexography, rotogravure, or
letterpress, may be present hi an offset lithographic printing facility; however these
operations are not subject to the requirements set forth hi this model rule.
Any dryer exhaust stream for which an existing control device is employed to
control VOC emissions should not be required to meet the 95 percent reduction or
20 ppmv emissions limit specified in the model "THE PERCENT REDUCTION
OR EMISSIONS LIMITS SPECIFIED IN SECTION D.4(A) OF THE MODEL"
rule until the control device is replaced for other reasons. In other words, no
facility should be required to upgrade or replace a control device that is in place
before the date of this regulation, provided that the device is at least 85 percent
efficient in the "MEETS THE APPLICABLE STATE RACT REQUIREMENTS
FOR THE" destruction "OR RECOVERY" of VOC's and is operated and
maintained in accordance with the procedures described hi Sections D.6, D.8, and
D.9.
D-2
i-; ^ r?
• Vj i
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D.3 DEFINITIONS
Alcohol substitutes. Non-"ISOPROPYL" alcohol additives that contain VOC's
and are used in the fountain solution. Some additives are used to reduce the surface
tension of water; others (especially in the newspaper industry) are added to prevent
piling (ink build-up).
Cleaning solution. A liquid "LIQUID SOLVENTS" used to remove ink and
debris from the surfaces of the printing press and its parts.
Dampening System. Equipment used to deliver the fountain solution to the
press "LITHOGRAPHIC PLATE".
Fountain Solution. A mixture of "PRIMARILY" water, non-volatile printing
chemicals, and an (liquid) additive that "OTHER CHEMICALS, AND
ADDITIVES THAT REDUCE THE SURFACE TENSION" reduces the surface
tension of the water so that it spreads easily across the printing surfaces. The
fountain solution wets the non-image areas so that the ink is maintained within the
image areas. Isopropyl alcohol, a VOC, is the most common additive "OR
ALCOHOL SUBSTITUTES ARE COMMONLY used to reduce the surface
tension of the fountain solution.
D-3
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Heat-set. Any operation "A WEB PRINTING OPERATION" where heat is
required to set "TO EVAPORATE" the printing ink "OILS". Hot air
"HEATSET" dryers are used to deliver the heat.
HEATSET DRYER "A DEVICE TO HEAT THE PRINTED SUBSTRATE
AND TO PROMOTE EVAPORATION OF INK OILS".
Lithography. A planar "PRINTING" process where the image and non-image
areas are chemically differentiated; the image area is oil receptive and the non-
image area is water receptive. This method differs from other printing methods,
where the image is a raised or impressed "IMAGES ARE PRINTED FORM
RAISED OR RECESSED" surface.
Non-Heatset. Any operation "A LITHOGRAPHIC OPERATION" where the
printing inks are set without the use heat. For the purposes of this rule, ultraviolet-
cured "AND ELECTRON BEAM-CURED" inks are considered non-heatset.
Offset. A printing process that transfers the printing image "INK FILM FROM
THE LITHOGRAPHIC PLATE" to an intermediary surface "(BLANKET)",
which, in turn transfers the image "INK FILM" to the printing substrate.
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Press. A printing production assembly that can be made up of one or many
"COMPOSED OF ONE OR MORE" units to produce a fmiohcd product
"PRINTED SUBSTRATE".
RECIRCULATION RESERVOIR. THE COLLECTION TANK WHICH
ACCEPTS FOUNTAIN SOLUTION RECIRCULATED FROM PRINTING
UNIT(S). THE TANK COMMONLY CONTAINS A COARSE FILTER TO
REMOVE CONTAMINANTS FORM THE FOUNTAIN SOLUTION AS WELL
AS THE COOLING COILS FOR REFRIGERATION.
Sheet-fed. Any "A PRINTING" operation where paper "INDIVIDUAL
SHEETS OF SUBSTRATE ARE" is fed to the press in individual sheets
"SEQUENTIALLY".
Unit. The smallest complete "PRINTING" component of a printing press. Each
unit can print only one color.
Web. A continuous roll of paper used as the printing substrate.
D.4 EMISSION STANDARDS
(a) Any person who owns or operates a heatset offset lithographic printing press
shall reduce VOC emissions from the press dryer exhaust vent by 95 "90" weight-
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percent of total organics (minus "LESS" methane and ethane) or maintain a
maximum dryer exhaust "A CONTROL DEVICE" outlet concentration of 20
ppmv, "LESS THAN 50 PPMV AS C, " whichever is less stringent.
D.5 EQUIPMENT STANDARDS "PROCESS STANDARDS"
(a) Any person who owns or operates a web-fed offset lithographic printing
press that uses "ISOPROPYL" alcohol in the fountain solution shall reduce
"MAINTAIN" total fountain solution VOC's to 1.6 percent "AT 8 PERCENT" or
less (by volume). Alternatively, a standard of 3 "12" percent or less (by volume)
VOC may be used if the fountain solution containing alcohol is refrigerated to less
than 60°F.
(b) Any person who owns or operates a sheet-fed offset lithographic printing
facility with a combined total of no more than 24 printing units (single blanket) that
use alcohol in the fountain solution shall reduce VOC's to 6 percent or less (by
volume) VOC. "PRESS THAT USES ISOPROPYL ALCOHOL IN THE
FOUNTAIN SOLUTION SHALL MAINTAIN TOTAL FOUNTAIN
SOLUTION VOCS AT 10 PERCENT OR LESS (BY WEIGHT). Alternatively,
a standard of 40 "15" percent or less (by volume) VOC may be used if the fountain
solution containing alcohol is refrigerated to below 60 °F.
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(e) — Any person who owns or operates a sheet fed offset lithographic printing
facility with a combined total of 24 printing units (single blanket) or more that use
alcohol in the fountain solution shall reduce VOC's to 3 percent or leas (by
volume). — Alternatively, a standard of 5 percent or less containing alcohol is
refrigerated to below 60--Fr
{d)"(c)" Any person who owns or operates any type of offset lithographic
printing press shall be considered in compliance with this regulation if the only
VOC's in the fountain solution are in non-"ISOPROPYL" alcohol additives or
alcohol substitutes, so that the concentration of VOC's in the fountain solution is 2r5
"5" percent or less (by weight). (The fountain solution should not contain any
alcohol.)
(e}"(d)" Any person who owns or operates an offset lithographic printing press
shall reduce VOC emissions from cleaning solutions by using cleaning solutions with
a 30 percent or less (as used) VOC content. "OR A VOC CONTENT OF 900
GRAMS OR LESS OF VOC PER LITER OF MATERIAL AND A VOC
COMPOSITE PARTIAL PRESSURE OF 25 MM HG OR LESS AT 2/C (68
D..6 EMISSIONS STANDARDS TESTING
D-7
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(a) For the purpose of demonstrating compliance with the emission control
requirements of this rule, the affected facility "SOURCE" shall be run at fett "THE
MAXIMUM PRACTICAL" operating conditions and flow rates "COMPATIBLE
WITH SCHEDULED PRODUCTION DURING COMPLIANCE TESTING"
during any emission
(b) Emission tests shall include an initial test when the control device is installed
that demonstrates compliance with cither the 95 weight-percent reduction or the 20
ppmv emission limit. "EMISSION TESTS FOR SOURCES INSTALLED
AFTER THE EFFECTIVE DATE OF THIS REGULATION SHALL INCLUDE
AN INITIAL TEST WHEN THE CONTROL DEVICE IS INSTALLED THAT
DEMONSTRATES COMPLIANCE WITH EITHER THE 90 WEIGHT-
PERCENT REDUCTION OR THE 50 PPMV AS C, EMISSIONS LIMITS
SPECIFIED IN D.4(A)".
(c) The following EPA methods (in 40 CFR 60, Appendix A) shall be used to
demonstrate compliance with the emission limit or percent reduction efficiency
requirements listed in D.4 (a) above. "ALTERNATE METHODS MAY BE
USED WITH THE APPROVAL OF THE ADMINISTRATOR".
(1) EPA Method 1 or 1A, as appropriate, shaH "MAY" be used for selection
of the sampling sites. The control device inlet sampling site for determining
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efficiency in reducing total organics (less methane and ethane) from the dryer
exhaust shall be placed before the control device inlet and after the dryer.
(2) EPA Method 2, 2A, 2C, or 2D, as appropriate, sfeaH "MAY" be used to
determine the volumetric flow rate of the exhaust stream.
(3) EPA Method 25 or 25A shall be used for determining emissions from hcatsct
dryer exhaust. "EPA METHOD 18, 25, OR 25A, AS APPROPRIATE, MAY
BE USED TO DETERMINE EMISSIONS FROM HEATSET DRYER AND
CONTROL DEVICE EXHAUSTS". Good judgement is required in determining
the best applicable VOC test method for each situation.
(i) Since EPA Method 25 has a minimum detectable concentration of 50 ppm
carbon, and given the low concentration of VOC's sometimes present hi dryer
exhaust from offset lithographic presses and the high removal efficiency achievable
with add-on controls, EPA Method 25 A may be more suitable than EPA Method 25
for determining compliance.with a 95 weight percent reduction standard hi some
situations "TO A TEMPERATURE ABOVE THAT OF THE GAS STREAM,
E^J., 350°F". Note that EPA Method 25 specifies a minimum probe and filter
temperature of 265°F. To prevent condensation, the probe and filter should be
heated to fee — gas — stream — temperature, — typically — closer — te — 350-F "A
TEMPERATURE ABOUT THAT OF THE GAS STREAM.JSOV.
n
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(ii) EPA Method 25A utilizes a flame ionization detector (FID), which had the
ability to measure low concentrations. This technique usually is not recommended
for incinerators because incomplete combustion may result in the formation of
aldehydes, kctoncs, and partially oxidized organic species that interfere with the
accuracy of FID measurement. "INCINERATOR OUTLETS WITH VOC
CONCENTRATIONS IN EXCESS OF 50 PPM AS C,. HOWEVER, EPA
METHOD 25A IS PREFERRED FOR INCINERATORS WHERE EXPECTED
OUTLET CONCENTRATIONS WILL BE BELOW 50 PPM AS C, OR
WHERE DRYERS FROM MULTIPLE PRESS LINES DISCHARGE INTO A
CENTRAL CONTROL DEVICE".
D.7 EQUIPMENT STANDARDS TESTING
(a) Fountain Solution Testing
(1) A "COMPOSITE" sample of the fountain solution (as used) shall be taken
from the from the fountain tray or reservoir of fountain solution (after mixing) of
each until to determine "EACH SUBJECT PRESS TO DETERMINE" fountain
solution VOC content in accordance with section D.5 (a) through (d) above.
(2) A modification of EPA Method 24 (under development) shall be used to
determine the VOC content of the fountain solution samplc(s). "RECORDS OF
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FOUNTAIN SOLUTION COMPOSITION (AS MIXED) MAY BE USED TO
DETERMINE THE VOC CONTENT OF THE FOUNTAIN SOLUTION".
(b) Refrigeration Equipment Testing
(1) A thermometer or other temperature detection device capable of reading to
0.5°F shall be used to ensure that a refrigerated fountain solution containing alcohol
is below 60°F at all times.
(c) Cleaning Solution Testing
(1) A sample "SAMPLES" of the cleaning solution "SOLUTIONS" (as used)
shall be taken to demonstrate compliance with the cleaning solution VOC content
"OR VAPOR PRESSURE imitations listed in D.5 (e) "(d)" above.
(2) A modification of EPA Method 24 (under development) shall be used to
determine the VOC contnct of the cleaning solution (as used). "RECORDS OF
CLEANING SOLUTION COMPOSITION (AS MIXED) TOGETHER WITH
MATERIAL SAFETY DATA SHEET INFORMATION MAY BE USED TO
DETERMINE THE VOC CONTENT OF THE CLEANING SOLUTION.
ALTERNATIVELY, VOC CONTENT OR VAPOR PRESSURE AS
PROVIDED BY THE MANUFACTURER MAY BE USED TO
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DEMONSTRATE COMPLIANCE WITH THE REQUIREMENTS OF D.5
CD)".
D.8 MONITORING REQUIREMENTS
(a) Add-on Dryer Exhaust Control Devices
(1) The owner or operator of a heatset offset lithographic printing press
"EQUIPPED WITH AN AFTERBURNER" shall install, calibrate, maintain, and
operate a temperature—monitoring—device, according to the manufacturer's
instructions, "CONTINUOUS TEMPERATURE MONITORING EQUIPMENT
TO MONITOR THE COMBUSTION CHAMBER TEMPERATURE OF
THERMAL AFTERBURNERS OR THE TEMPERATURE RISE ACROSS A
CATALYTIC AFTERBURNER BED. THE COMBUSTION CHAMBER OR
CATALYST INLET TEMPERATURE SHOULD BE SET DURING TESTING
REQUIRED TO DEMONSTRATE COMPLIANCE WITH THE EMISSION
STANDARDS OF D.4 (A)", at the outlet of the control device. The monitoring
temperature should be set during testing required to demonstrate compliance with
the emission standard (Section 7.6.3).
(2) The temperature monitoring device shall be equipped with a continuous
recorder and shall have an accuracy of Or§!F "5°F".
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(3) The dryer pressure shall be maintained lower than the press room air
pressure such that air flows into the dryer at all times. A 100 percent emissions
capture efficiency for the dryer shall be demonstrated using an air flow direction
measuring device. "THE CAPTURE EFFICIENCY FOR THE DRYER SHALL
BE DEMONSTRATED USING AN AIR FLOW DIRECTION INDICATING
DEVICE".
(b) Fountain Solution VOC Concentration
(1) The purpose of monitoring the VOC concentration in the fountain is to
provide data that can be correlated to the mount of material used when the fountain
solution is in compliance with the limits in D.5(a) through (d) above. The following
methods may be used to measure the concentration of VOC'3 in the fountain
solution of a frequent basis. "RECORDS OF FOUNTAIN SOLUTION
COMPOSITION (AS MIXED) MAY BE USED TO DETERMINE THE VOC
CONTENT OF THE FOUNTAIN SOLUTION; OR".
(2) The owner or operator of any offset lithographic printing press shaH "MAY"
monitor fountain solution VOC concentration "AT LEAST ONCE PER BATCH"
with a refractometer that is corrected for temperature, at least once per 8 hour shift.
The refractometer shall have an optical "A VISUAL, ANALOG" or digital readout
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with an accuracy of 0.5 percent VOC. A standard solution shall be used to
calibrate the refractometer for the type of VOC used in the fountain. "SOLUTION;
OR"
(3) Alternatively, The owner or operator of any offset lithographic printing press
may monitor fountain solution VOC concentration with a hydrometer equipped with
a temperature correction at least once per 8-hour shift "AT LEAST ONCE PER
BATCH WITH A HYDROMETER THAT IS CORRECTED FOR
TEMPERATURE". The hydrometer shall have an optical "A VISUAL,
ANALOG" or digital readout with an accuracy of 0.5 percent VOC.
(4) The VOC content of the fountain solution may be monitored with Q
conductivity meter if it is determined that a refractometer or hydrometer cannot be
used for the type of VOC's in the fountain solution. The conductivity meter reading
for the fountain solution shall be referenced to the conductivity of the incoming
n rrk^-/-i*»
WULU1 .
(c) Fountain Solution Temperature
(1) The owner or operator of any offset lithographic printing press using
refrigeration equipment en "FOR" the fountain "SOLUTION" shall install,
maintain, and continuously operate a "TO COMPLY WITH SECTION D.5 (a)
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OR (b) "SHALL MONITOR THE" temperature pfebe in the fountain solution
reservoir below the solution surface.
(2) The temperature probe shall be attached to a continuous recording device
such as a strip chart, recorder, or computer. "THE FOUNTAIN SOLUTION
TEMPERATURE SHALL BE RECORDED AT LEAST ONCE PER 8-HOUR
SHIFT".
(d) Cleaning Solution
(1) For any offset lithographic printing press with continuous cleaning
equipment, flow "COMPLYING WITH THE CLEANING SOLUTION VOC
CONTENT LIMITS OF D.5 (d) (1) FOR AUTOMATIC BLANKET
CLEANING EQUIPMENT, meters are required to monitor water and cleaning
solution flow rates "CONSUMPTION". The flew meters should be calibrated
"MONITORED" so that the VOC content of the mixed solution complies with the
requirements of D.5(c) above. "D.5 (d) (1) ABOVE". "IN THE ABSENCE OF
METERS, VOC CONCENTRATION AND CONSUMPTION SHALL BE
MONITORED AT THE RESERVOIR USING AVAILABLE CALIBRATION,
OR";.
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(2) "FOR ANY OFFSET LITHOGRAPHIC PRINTING PRESS
COMPLYING WITH THE CLEANING SOLUTION VAPOR PRESSURE
LIMITS OF D.5 (d) (2) FOR AUTOMATIC BLANKET CLEANING
EQUIPMENT, MANUFACTURER'S DATA ON VOC CONTENT AND
VAPOR PRESSURE MAY BE USED TO DEMONSTRATE COMPLIANCE
WITH THE REQUIREMENTS OF D.5(d) (2) ABOVE".
D.9 REPORTING/RECORDKEEPING
(a) The owner or operator of any offset lithographic printing press shall record
and report "MAINTAIN" the following key parameters on a regular "DAILY"
basis., but no less than once per 8-hour shift.
(1) The type of control device operating on the hcatsct offset lithographic
printing press and the operating parameters specified in D.8(a) above. "THE
OPERATING PARAMETERS SPECIFIED IN D.8 (a) ABOVE FOR THE
CONTROL DEVICE OPERATING ON THE OFFSET LITHOGRAPHIC
PRINTING PRESS".
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(2) The equipment standard selected to comply with the requirements in D.5(a)
through (c) above.
"(2)" The "MATERIALS AND" the VOC content of the fountain and
cleaning solutions, to comply with the requirements in D.5(a) through (e), D.8(b),
and D.8(d) above.
(4) "(3)" The temperature of the fountain solution to comply with the
requirements in D.8(c) above, if applicable.
"(4)" For manual cleaning methods, the amount of cleaning solution and
amount of water added per batch of cleaning solution mixed.
"(5)" For automatic cleaning methods, the flow rates of water "BLANKET
CLEANING EQUIPMENT, THE CONSUMPTION OF WATER" and cleaning
solution concentrate, as specific in D.8(d) above "IF APPLICABLE".
Corrective actions taken when cxcccdanccs of any parameters monitored
according to the requirements of D.6 through D.8, above, occur.
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APPENDIX D
OFFSET LITHOGRAPHIC PRINTING
CTG MODEL RULE
D.I INTRODUCTION
This appendix presents a model rule to limit volatile organic compound (VOC)
emissions from offset lithographic printing operations. This rule is for informational
purposes only and, as such, is not binding on the air quality management authority.
However, EPA expects that State and local air quality rules developed pursuant to
this CTG will address all the elements covered in the model rule.
The remainder of this appendix contains the model rule. Separate sections cover
the following rule elements: applicability, definitions, emissions standards,
equipment standards, emissions standards testing, equipment standards testing,
monitoring requirements, and reporting/recordkeeping.
D.2 APPLICABILITY
The provisions set forth in this model rule apply to the offset lithographic
printing industry only. There are four types of offset lithographic printing: heatset
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web, non-heatset web (non-newspaper), non-heatset sheet-fed, and newspaper (non-
heatset web). An affected facility may be defined as follows: one or more printing
operations involved in at least one type of offset lithographic printing process.
Other types of printing operations, such as flexography, rotogravure, or
letterpress, may be present in an offset lithographic printing facility; however these
operations are not subject to the requirements set forth in this model rule.
Any dryer exhaust stream for which an existing control device is employed to
control VOC emissions should not be required to meet "THE PERCENT
REDUCTION OR EMISSIONS LIMITS SPECIFIED IN SECTION D.4(A) OF
THE MODEL" rule until the control device is replaced for other reasons. In other
words, no facility should be required to upgrade or replace a control device that is
in place before the date of this regulation, provided that the device "MEETS THE
APPLICABLE STATE RACT REQUIREMENTS FOR THE" destruction "OR
RECOVERY" of VOC's and is operated and maintained in accordance with the
procedures described in Sections D.6, D.8, and D.9.
D.3 DEFINITIONS
D-2
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Alcohol substitutes. Non-"ISOPROPYL" alcohol additives that contain VOC's
and are used in the fountain solution. Some additives are used to reduce the surface
tension of water; others (especially in the newspaper industry) are added to prevent
piling (ink build-up).
Cleaning solution. "LIQUID SOLVENTS" used to remove ink and debris from
the surfaces of the printing press and its parts.
Dampening System. Equipment used to deliver the fountain solution to the
press "LITHOGRAPHIC PLATE".
Fountain Solution. A mixture of "PRIMARILY" water, "OTHER
CHEMICALS, AND ADDITIVES THAT REDUCE THE SURFACE
TENSION" reduces the surface tension of the water so that it spreads easily across
the printing surfaces. The fountain solution wets the non-image areas so that the
ink is maintained within the image areas. Isopropyl alcohol, "OR ALCOHOL
SUBSTITUTES ARE COMMONLY used to reduce the surface tension of the
fountain solution.
Heat-set. "A WEB PRINTING OPERATION" where heat is required "TO
EVAPORATE" the printing ink "OILS". "HEATSET" dryers are used to deliver
the heat.
D-3
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HEATSET DRYER "A DEVICE TO HEAT THE PRINTED SUBSTRATE
AND TO PROMOTE EVAPORATION OF INK OILS".
Lithography. A "PRINTING" process where the image and non-image areas
are chemically differentiated; the image area is oil receptive and the non-image area
is water receptive. This method differs from other printing methods, where the
"IMAGES ARE PRINTED FORM RAISED OR RECESSED" surface.
Non-Heatset. "A LITHOGRAPHIC OPERATION" where the printing inks
are set without the use heat. For the purposes of this rule, ultraviolet-cured "AND
ELECTRON BEAM-CURED" inks are considered non-heatset.
Offset. A printing process that transfers the "INK FILM FROM THE
LITHOGRAPHIC PLATE" to an intermediary surface "(BLANKET)", which, in
turn transfers the "INK FILM" to the printing substrate.
Press. A printing production assembly "COMPOSED OF ONE OR MORE"
units to produce a "PRINTED SUBSTRATE".
RECIRCULATION RESERVOIR. THE COLLECTION TANK WHICH
ACCEPTS FOUNTAIN SOLUTION RECIRCULATED FROM PRINTING
UNIT(S). THE TANK COMMONLY CONTAINS A COARSE FILTER TO
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REMOVE CONTAMINANTS FORM THE FOUNTAIN SOLUTION AS WELL
AS THE COOLING COILS FOR REFRIGERATION.
Sheet-fed. "A PRINTING" operation where "INDIVIDUAL SHEETS OF
SUBSTRATE ARE" is fed to the press "SEQUENTIALLY".
Unit. The smallest complete "PRINTING" component of a printing press.
Web. A continuous roll of paper used as the printing substrate.
D.4 EMISSION STANDARDS
(a) Any person who owns or operates a heatset offset lithographic printing press
shall reduce VOC emissions from the press dryer exhaust by "90" weight- percent
of total organics ("LESS" methane and ethane) or maintain "A CONTROL
DEVICE" outlet concentration of, "LESS THAN 50 PPMV AS C, " whichever
is less stringent.
D.5 "PROCESS STANDARDS"
(a) Any person who owns or operates a web-fed offset lithographic printing
press that uses "ISOPROPYL" alcohol in the fountain solution shall "MAINTAIN"
total fountain solution VOC's "AT 8 PERCENT" or less (by volume).
D-5
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Alternatively, a standard of "12" percent or less (by volume) VOC may be used if
the fountain solution containing alcohol is refrigerated to less than 60°F.
(b) Any person who owns or operates a sheet-fed offset lithographic printing
"PRESS THAT USES ISOPROPYL ALCOHOL IN THE FOUNTAIN
SOLUTION SHALL MAINTAIN TOTAL FOUNTAIN SOLUTION VOCS AT
10 PERCENT OR LESS (BY WEIGHT). Alternatively, a standard of "15"
percent or less (by volume) VOC may be used if the fountain solution containing
alcohol is refrigerated to below 60 °F.
"(c)" Any person who owns or operates any type of offset lithographic printing
press shall be considered in compliance with this regulation if the only VOC's in
the fountain solution are in non-"ISOPROPYL" alcohol additives or alcohol
substitutes, so that the concentration of VOC's in the fountain solution is "5"
percent or less (by weight). (The fountain solution should not contain any alcohol.)
"(d)" Any person who owns or operates an offset lithographic printing press
shall reduce VOC emissions from cleaning solutions by using cleaning solutions with
a 30 percent or less VOC content. "OR A VOC CONTENT OF 900 GRAMS OR
LESS OF VOC PER LITER OF MATERIAL AND A VOC COMPOSITE
0
PARTIAL PRESSURE OF 25 MM HG OR LESS AT 20/fC (68 T)".
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D.6 EMISSIONS STANDARDS TESTING
(a) For the purpose of demonstrating compliance with the emission control
requirements of this rule, the affected "SOURCE" shall be run at "THE
MAXIMUM PRACTICAL" operating conditions and flow rates "COMPATIBLE
WITH SCHEDULED PRODUCTION DURING COMPLIANCE TESTING"
(b) "EMISSION TESTS FOR SOURCES INSTALLED AFTER THE
EFFECTIVE DATE OF THIS REGULATION SHALL INCLUDE AN INITIAL
TEST WHEN THE CONTROL DEVICE IS INSTALLED THAT
DEMONSTRATES COMPLIANCE WITH EITHER THE 90 WEIGHT-
PERCENT REDUCTION OR THE 50 PPMV AS C, EMISSIONS LIMITS
SPECIFIED IN D.4(A)M.
(c) The following EPA methods (in 40 CFR 60, Appendix A) shall be used to
demonstrate compliance with the emission limit or percent reduction efficiency
requirements listed in D.4 (a) above. "ALTERNATE METHODS MAY BE
USED WITH THE APPROVAL OF THE ADMINISTRATOR".
(1) EPA Method 1 or 1A, as appropriate, "MAY" be used for selection of the
sampling sites. The control device inlet sampling site for determining efficiency in
D-7
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reducing total organics (less methane and ethane) from the dryer exhaust shall be
placed before the control device inlet and after the dryer.
(2) EPA Method 2, 2A, 2C, or 2D, as appropriate, "MAY" be used to
determine the volumetric flow rate of the exhaust stream.
(3) "EPA METHOD 18, 25, OR 25A, AS APPROPRIATE, MAY BE USED
TO DETERMINE EMISSIONS FROM HEATSET DRYER AND CONTROL
DEVICE EXHAUSTS". Good judgement is required in determining the best
applicable VOC test method for each situation.
(i) Since EPA Method 25 has a minimum detectable concentration of 50 ppm
carbon, and given the low concentration of VOC's sometimes present in dryer
exhaust from offset lithographic presses and the high removal efficiency achievable
with add-on controls, EPA Method 25 A may be more suitable than EPA Method 25
for determining compliance , "TO A TEMPERATURE ABOVE THAT OF THE
GASrSIKLAM, E.l^r350cFu-. Note that EPA Method 25 specifies a minimum
probe and filter temperature of 265°F. To prevent condensation, the probe and filter
should be heated to "A TEMPERATURE ABOUT THAT OF THE GAS
STREAM^350°F".
(ii) EPA Method 25 A utilizes a flame ionization detector (FID), which had the
ability to measure low concentrations. This technique usually is not recommended
D-8
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for "INCINERATOR OUTLETS WITH VOC CONCENTRATIONS IN
EXCESS OF 50 PPM AS C,. HOWEVER, EPA METHOD 25A IS
PREFERRED FOR INCINERATORS WHERE EXPECTED OUTLET
CONCENTRATIONS WILL BE BELOW 50 PPM AS Ct OR WHERE
DRYERS FROM MULTIPLE PRESS LINES DISCHARGE INTO A
CENTRAL CONTROL DEVICE".
D.7 EQUIPMENT STANDARDS TESTING
(a) Fountain Solution Testing
(1) A "COMPOSITE" sample of the fountain solution (as used) shall be taken
from the from "EACH SUBJECT PRESS TO DETERMINE" fountain solution
VOC content in accordance with section D.5 (a) through (d) above.
(2) "RECORDS OF FOUNTAIN SOLUTION COMPOSITION (AS MIXED)
MAY BE USED TO DETERMINE THE VOC CONTENT OF THE
FOUNTAIN SOLUTION".
(b) Refrigeration Equipment Testing
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(1) A thermometer or other temperature detection device capable of reading to
0.5°F shall be used to ensure that a refrigerated fountain solution containing alcohol
is below 60°F.
(c) Cleaning Solution Testing
(1) "SAMPLES" of the cleaning "SOLUTIONS" (as used) shall be taken to
demonstrate compliance with the cleaning solution VOC content "OR VAPOR
PRESSURE imitations listed in D.5 "(d)" above.
(2) "RECORDS OF CLEANING SOLUTION COMPOSITION (AS
MIXED) TOGETHER WITH MATERIAL SAFETY DATA SHEET
INFORMATION MAY BE USED TO DETERMINE THE VOC CONTENT OF
THE CLEANING SOLUTION. ALTERNATIVELY, VOC CONTENT OR
VAPOR PRESSURE AS PROVIDED BY THE MANUFACTURER MAY BE
USED TO DEMONSTRATE COMPLIANCE WITH THE REQUIREMENTS
OF D.5 (D)".
D.8 MONITORING REQUIREMENTS
(a) Add-on Dryer Exhaust Control Devices
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(1) The owner or operator of a heatset offset lithographic printing press
"EQUIPPED WITH AN AFTERBURNER" shall install, calibrate, maintain, and
operate a, according to the manufacturer's instructions, "CONTINUOUS
TEMPERATURE MONITORING EQUIPMENT TO MONITOR THE
COMBUSTION CHAMBER TEMPERATURE OF THERMAL
AFTERBURNERS OR THE TEMPERATURE RISE ACROSS A CATALYTIC
AFTERBURNER BED. THE COMBUSTION CHAMBER OR CATALYST
INLET TEMPERATURE SHOULD BE SET DURING TESTING REQUIRED
TO DEMONSTRATE COMPLIANCE WITH THE EMISSION STANDARDS
OF D.4 (A)".
(2) The temperature monitoring device shall be equipped with a continuous
recorder and shall have an accuracy of "5°F".
(3) The dryer pressure shall be maintained lower than the press room air
pressure such that air flows into the dryer at all times. "THE CAPTURE
EFFICIENCY FOR THE DRYER SHALL BE DEMONSTRATED USING AN
AIR FLOW DIRECTION INDICATING DEVICE".
(b) Fountain Solution VOC Concentration
D-ll
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(1) "RECORDS OF FOUNTAIN SOLUTION COMPOSITION (AS MIXED)
MAY BE USED TO DETERMINE THE VOC CONTENT OF THE
FOUNTAIN SOLUTION; OR".
(2) The owner or operator of any offset lithographic printing press shaH "MAY"
monitor fountain solution VOC concentration "AT LEAST ONCE PER BATCH"
with a refractometer that is corrected for temperature. The refractometer shall have
"A VISUAL, ANALOG" or digital readout with an accuracy of 0.5 percent VOC.
A standard solution shall be used to calibrate the refractometer for the type of VOC
used in the fountain. "SOLUTION; OR"
(3) The owner or operator of any offset lithographic printing press may monitor
fountain solution VOC concentration with a hydrometer equipped with a temperature
correction "AT LEAST ONCE PER BATCH WITH A HYDROMETER THAT
IS CORRECTED FOR TEMPERATURE". The hydrometer shall have "A
VISUAL, ANALOG" or digital readout with an accuracy of 0.5 percent VOC.
(c) Fountain Solution Temperature
(1) The owner or operator of any offset lithographic printing press using
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refrigeration equipment oa "FOR" the fountain "SOLUTION" "TO COMPLY
WITH SECTION D.5 (a) OR (b) "SHALL MONITOR THE" temperature in the
fountain solution reservoir below the solution surface.
(2) "THE FOUNTAIN SOLUTION TEMPERATURE SHALL BE
RECORDED AT LEAST ONCE PER 8-HOUR SHIFT".
(d) Cleaning Solution
(1) For any offset lithographic printing press "COMPLYING WITH THE
CLEANING SOLUTION VOC CONTENT LIMITS OF D.5 (d) (1) FOR
AUTOMATIC BLANKET CLEANING EQUIPMENT, meters are required to
monitor water and cleaning solution "CONSUMPTION". The meters should be
"MONITORED" so that the VOC content of the mixed solution complies with the
requirements of "D.5 (d) (1) ABOVE". "IN THE ABSENCE OF METERS,
VOC CONCENTRATION AND CONSUMPTION SHALL BE MONITORED
AT THE RESERVOIR USING AVAILABLE CALIBRATION, OR";.
(2) "FOR ANY OFFSET LITHOGRAPHIC PRINTING PRESS
COMPLYING WITH THE CLEANING SOLUTION VAPOR PRESSURE
LIMITS OF D.5 (d) (2) FOR AUTOMATIC BLANKET CLEANING
D-13
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EQUIPMENT, MANUFACTURER'S DATA ON VOC CONTENT AND
VAPOR PRESSURE MAY BE USED TO DEMONSTRATE COMPLIANCE
WITH THE REQUIREMENTS OF D.5(d) (2) ABOVE".
D.9 REPORTING/RECORDKEEPING
(a) The owner or operator of any offset lithographic printing press shall record
and "MAINTAIN" the following key parameters on a "DAILY" basis.
(1) THE OPERATING PARAMETERS SPECIFIED IN D.8 (a) ABOVE
FOR THE CONTROL DEVICE OPERATING ON THE OFFSET
LITHOGRAPHIC PRINTING PRESS".
"(2)" The "MATERIALS AND" the VOC content of the fountain and cleaning
solutions, to comply with the requirements in D.5(a) through (e), D.8(b), and
D.8(d) above.
"(3)" The temperature of the fountain solution to comply with the requirements
in D.8(c) above, if applicable.
D-14
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"(4)" For manual cleaning methods, the amount of cleaning solution and amount
of water added per batch of cleaning solution mixed.
"(5)" For automatic cleaning methods, the flow rates of water "BLANKET
CLEANING EQUIPMENT, THE CONSUMPTION OF WATER" and cleaning
solution concentrate, as specific in D.8(d) above "IF APPLICABLE".
D-15
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GRAPHIC ARTS
TECHNICAL FOUNDATION
GRAPHIC ARTS TECHNICAL FOUNDATION « 4615 FORBES AVENUE • PITTSBURGH, PENNSYLVANIA 15213-3796 • 412/621-6941
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FAX: 412/621-3049 « TELEX: 9103509221
COMMENTS
on
DRAFT CONTROL TECHNIQUES GUIDELINE -
OFFSET LITHOGRAPHIC PRINTING
by
William D. Schaeffer
Chairman, Technical Committee, ECB
Consultant to Graphic Arts Technical Foundation
Research Director (ret.)/ Graphic Arts Technical Foundation
November 20, 1991
MEMBER-SUPPORTED, NONPROFIT, SCIENTIFIC. TECHNICAL AND EDUCATIONAL ORGANIZATION SERVING THE INTERNATIONAL GRAPHIC COMMUNICATIONS INDUSTRIES SINCE 1924.
-------
COMMENTS
on
DRAFT CONTROL TECHNIQUES GUIDELINE -
OFFSET LITHOGRAPHIC PRINTING
by
William D. Schaeffer
Chairman, Technical Committee, ECB
Consultant to Graphic Arts Technical Foundation
Research Director (ret.)/ Graphic Arts Technical Foundation
Our industry greatly appreciates the opportunity to comment
on the Draft CTG document for Offset Lithographic Printing. We
have provided to you and the USEPA in-depth comments and line-by-
line critiques on the Draft CTG and the model CTG Rule (Appendix
D) . Time is inadequate to review this material in all of the
detail that it deserves. Mr. Bender has reviewed the offset
lithographic printing processes and the segments of the printing
industry in which the processes are used. He has pinpointed and
explained many of the shortcomings of the present document and
the recommendations for RACT.
My purpose is to review critically three areas in the CTG:
(1) The assumptions used in developing the heatset web
offset model plants and their consequences,
(2) RACT recommendations for process materials, i.e.,
fountain solution and cleaning solutions, and
(3) Unrecognized administrative burdens and subsequent
costs, particularly for the sheetfed printer.
Heatset Web Offset Model Plants
The assumptions that the printing unit in heatset web offset
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presses contains only a single blanket (Table 3-1, p. 3-44) is in
direct conflict with the dominant press design in this industry
segment, the blanket-to-blanket printing unit. As a consequence,
the average number of units per press are estimated as 4 to 6 as
opposed to the correct 8 to 10 for the four or five printing
couples in blanket-to-blanket presses. Underestimation of the
number of units per press and per plant causes an overestimate of
ink consumption per unit. Our calculation indicates the number
is 1.6 to 2 times greater than it should be. Thus the ink
consumption per press unit as estimated from industry surveys
(Sections 3.6.1, p. 3-46 and 5.1.1., p. 5-1) should be 5.7
instead of 10.3 pounds per unit-hour. Usage of fountain
solution, based on a fixed ratio to ink consumption, therefore,
is also too large. The overall effect is to exaggerate the VOC
content of heatset ink and fountain solution used annually in the
process (Table 3-3, p. 3-47) and the potential VOC emission
reductions as a result of the controls proposed as RACT (Table 5-
2, p. 5-6).
RACT Recommendations for Process Materials
The large majority of the offset lithographic printers
affected by the Control Techniques Guideline are the sheetfed
printers. The impact on the operations is through the proposed
materials standards, namely, fountain solutions (Sections D.5 (a)
through (d)) and cleaners (Sections D.5 (e)) and the proposed
monitoring (Sections D.7 (a) through (c) and D.8 (b) through (d))
and record keeping requirements. In brief, the industry
assessments of the draft proposals are:
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(1) the proposed reductions in isopropanol use in the
fountain solution are excessive (D.5 (a) through (d)),
(2) the concept that a large sheetfed plant can reduce
isopropanol use more readily than a small plant is
without basis (D.5 (c)),
(3) the proposed use of a 30 percent VOC content cleaner as
a universal cleaner to replace the current 100 percent
VOC blanket and press cleaners is not a demonstrated
capability (D.5 (e)). Moreover, excess volumes of
cleaner would be required to achieve comparable
results.
Every one of these three proposals will require additional
non-productive make-ready time between jobs and increase the
amount of print waste produced, while attempting to achieve the
desired print quality. Ironically, the proposed excessive
reductions in VOC use promises to multiply solid print waste
production, a poor environmental and a poor economic trade-off.
Additional critical assessments of Draft CTG proposals
include the following:
(4) suggestion of a method (modified Method 24) still in
development for the measurement of VOC content in
aqueous systems provides absolutely no basis for
criticism and is certainly inadequate for the CTG
(Sections D.7 (a) and D.7 (c)(2)), and
(5) the proposed number of sampling sites (Section D.7
(a)(l)), the frequency of sampling (D.9 (a)), the
analyses of samples (D.8 (b) and (c)), and record
keeping (D.9 (a)(3) through (6)) comprise demands which
-------
none in the sheetfed industry except the largest firms
are equipped to handle. These requirements, moreover,
track only the VOC concentrations in the materials used
in the processes.
From the sheetfed printer's perspectives, these last two
sets of requirements, (4) and (5), virtually insure that the
printer establish a laboratory with trained technicians. These
facilities do not exist today, and involve an investment totally
ignored in the CTG draft. The investment, moreover, contributes
nothing to an improved environment.
Industry Suggestions
Corrective measures are described in detail in the industry
line-by-line comments on Appendix D of the Draft CTG. Our
recommendation, in brief, are the following:
(1) the proposed concentrations in isopropanol fountain
solution concentrations to be greater than the draft
proposal, e.g., 10 instead of 6 and 15 instead of 10
percent VOC,
(2) eliminate the proposed differences between fountain
solution VOC content in small and large sheet-fed
pressrooms,
(3) distinguish between blanket and press cleaners and
establish an upper vapor pressure limit on 900
gram/liter VOC cleaners, which provide for efficient
operations,
(4) the printer allowed to use manufacturing suppliers data
-------
on VOC content of solution components plus mixing
formulations to calculate VOC content rather than
experimental determination, and
(5) a reduction in the number of sampling sites, the
frequency of measurements, the methods and quality of
measurements are all suggested modifications.
The largest group of offset lithographic printers to be
affected by the CTG will be the sheetfed printers. Our industry
committee believes that our suggestions will reduce VOC emissions
with minimal waste increases and limited financial costs. We
appreciate your attention to our suggestions and requests. Their
inclusion in the Control Techniques Guideline will make the
document more effective and less frustrating to the regulated
community and beneficial to the environment.
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Comments to Environmental Protection Agency, Chemicals and Petroleum Branch
made by C.Um. Schneidereith representing Schneidereith & Sons, Inc. on
November 20, 1991.
Schneidereith & Sons is a small/medium sized commercial printing establishment
located in Baltimore, Maryland, and currently utilizing the printing process
most prevalent today which is sheet-fed, offset lithography.
Employing about 60 people, this firm is in the upper 20 percentile (by size)
of printing firms. 80 percent of all commercial firms employ 25 people or
less, and only 20 percent of the firms employ more than 25 people.
Equipment operated daily on a two shift basis are the following:
(1) Six-color Miller TP104 41 inch width
(1) Six-color Miehle Roland 41 inch width
(1) Four-color Miller TP38 38 inch width
(1) Two-color Miller TP104 - 41 inch width
(1) Single-color Miehle - 29 inch width
(1) Single-color Heidelberg 20 inch width
Total of 20 printing units in operation.
Currently we are using the following volumes of materials which contain VOC
concentrations.
Ink @ 18,077 pounds per year
Cleaning Solvents @ 1,980 gallons per year
converts to 12,084 pounds per year
Isopropyl Alcohol @ -0- none used.
Alcohol substitutes @ 52 gallons per year
Calculations of the above usage rates yield VOC emissions as follows:
Ink @ 0.11 tons VOC's per year emitted
Cleaning solvents
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-2-
Impact of Control Techniques Guideline (CTG) dated September 6, 1991.
This firm has demonstrated that alcohol can be completely eliminated
from the lithographic process and still maintain the highest of quality
standards in so doing. This firm produces art catalogs for many of the leading
museums in Washington and New York along with the most difficult advertising
and commercial print projects. Since isopropyl alcohol repryesints one of the
greatest culprits in the quest to reduce VOC's in the printing industry,
emphasis should be given to the technical and educational aspects of weaning
this industry completely away from its use.
Operating a complete facility without alcohol is not an easily
accomplished task. For example, the rubber rollers used to apply the alcohol
substitute & water combination must be maintained in superior condition and
the durometer of the roller (its softness) is critical to the success of
alcohol substitutes. This is an expensive process to constantly monitor roller
condition and durometer. Rollers must be changed out and replaced far more
frequently without alcohol than with alcohol.
Roller settings are more critical when not using alcohol. Alcohol tends
to cover many mechanical sins. These settings are time consuming and require
the attention of the top paid craftsmen (not more lowly paid helpers). These
settings must be checked and adjusted more frequently due to the fact that
without alcohol one has a more limited tolerance range.
If alcohol can be eliminated from the process, it is not logical that
the temperature must be continuously monitored by probes and recorded for each
fountain unit. Without alcohol the VOC reduction is of substantial proportions
in itself, and the substitutes are used in such small volume that the total
VOC emission is not a significant number. Also, the vast majority of dampening
systems in operation today are refrigerated due to the need to maintain
constant percentage of alcohol in the fountain solutions. Printers who do not
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-3-
maintain a constant percentage of alcohol will see unacceptable variations in
the print quality. Thus, refrigeration was adapted to dampening fountains in
attempts to control the evaporation rate of alcohol purely for quality
reasons. Should one unit of refrigeration malfunction and the temperature
thereby increase, an operator is forced to repair it to provide consistency of
quality. So the process itself of causing erratic quality ensures the repair
and maintenance of such equipment -- thereby making the need to install probes
and recording devices redundant and in our opinion not necessary.
The experience and learning curve to run high-quality work without
alcohol is significant. The experimental phase of testing alcohol substitutes
in one fountain on a multi-color press lasted approximately two months. Once
alcohol substitutes are introduced into the entire press we noted the real
impact of the learning curve:
a) Dampening changes are more difficult to effect using alcohol
substitutes.
b) Roller problems are more critical
c) Roller replacements become major cost item.
d) Build-up of by-products on ink rollers cause inking irregularities
e) Dot gain is increased as dampening efficiency decreases due to
elimination of alcohol
f) Maintenance is more critical in dampening units and inking units.
g) Spoilage due to color being "out of tolerance" is more prevalent
due to difficulty in balancing water and ink. (Cost of reprinting
entire jobs can be extremely high.)
(Suggestion) Monitor fountain solutions with testing for VOC concentration and
temperature only on those units using alcohol. Refrigeration should not be the
issue here -- but rather alcohol. Testing refrigerated fountain solutions is
not going to be program effective and will do practically nothing toward the
goal of reducing VOC emissions. The lithographic printing process itself will
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-4-
"police" the industry in maintaining refrigerated units to correct
temperatures. However, testing those fountain units vhich use alcohol --
whether refrigerated or not refrigerated -- would be program effective. But
since there is nothing to prohibit non-refrigerated fountains from using
isopropyl alcohol, these units should be addressed in the scheme of imposing
controls.
Sec. D-8, C 1-2 stipulates that on ". . . any press using refrigeration . . .
shall install, maintain and operate a temperature probe . . .".No mention
made of non-refrigerated units. It should be more important to monitor the
non- refrigerated units, especially if using isopropyl alcohol.
The monitoring process itself is burdensome, especially to the small
operators. To install the monitors, educate those responsible, and detail a
person to record and maintain the records will be a very real cost, which in
my estimation will yield negligable results in reducing VOC emissions. In a
small shop -- such as the majority of printing establishments are -- this will
pose a detrimental burden on management which is already over worked and
frustrated by a myriad of regulations and paper work. I know of not one small
shop which can afford the payroll of someone to monitor fountains every eight
hours.
If monitoring is deemed necessary it would be sufficient to monitor and
record the results on every separate batch of fountain solution when mixed.
Regardless of what is being tested for, it will not materially change while in
the process of being used. Here again the printer and process itself will
"police" the results because if that batch of fountain solution does change,
it will show up as unacceptable quality and force the operator to shut down.
Create the incentive for the owner/operator to explore alternatives and
substitutes instead of imposing yet another layer of non-productive cost in an
industry facing competitive pressures from over-seas.
Cleaning solutions are a unique problem and also a dilemma to printers.
>". ~ "*
1 -' V-
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-5-
A rag with solvent can easily be rubbed over an inked surface and the ink
thereby removed. (The key vork is "rubbed"). A multitude of solvents could
pass this usage test easily, regardless of VOC content. Few of the
applications of cleaning solvents are this simple though.
Consider the structure of an inking unit on a printing press. Current
sheet-fed press equipment use approximately 20 - 22 rollers in each printing
unit. The diagrams on pages 2-2 and 3-6 are over simplifications of roller
configurations for the average sheet-fed press. Your diagrams show 11 ink
rollers, whereas the sheet-fed presses used today have 20 to 22 ink rollers.
Thus a six-color press will have from 120 to 132 rollers which will require
cleaning at least once per day -- possibly several times. The surfaces of
some of these rollers are not visible, being surrounded by the outer rollers.
The cleaning solutions of products with 30 percent or less VOC concentrations
will not dry properly and those inner rollers will not clean-up well. It is
imperative that the cleaning solutions used on press rollers will:
a) clean properly,
b) dry reasonably quickly,
c) not leave a residual film.
It is impossible to access some of the ink rollers to hand wipe the residual
solvent without a major disassembly of the inking system which would include a
day-long process.
The percentage of VOC mandated for cleaning solvents should be analyzed
carefully and researched by technical experts thoroughly knowledgeable of
press equipment and the unique constraints various ink systems impose upon the
printer. To do otherwise, the printer cannot operate. I cannot believe the
30 percent VOC limit will yield an acceptable roller solvent. The Roller wash
we currently use, which is giving satisfactory results, contains 84 percent
VOC's. It is incomprehensible to me that we could find an acceptable roller
wash containing only 30 percent VOC's. To attempt to use an unsatisfactory
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-6-
product would cripple our operation.
Ink VOC emissions are not as critical to the small/medium sheet-fed
lithographer as to the larger operators simply because they use less
volume/poundage. However, such factors as drying, scuff resistance,
appearance, and handling on press are all important. The recent introduction
of vegetable-based inks such as soy-bean is promising but the results do not
indicate that petroleum-based inks can be phased out any time in the
foreseeable future. There are problems contingent with the vegetable-based
inks that small operators simply do not have the access to technology and
research to properly make that transition at this point in time.
SUMMARY
The monitoring requirements as set forth in Section D.8 (b) "Fountain
Solution VOC Concentration" definitely pose an onerous and costly imposition
upon the small/medium operators and should be amended to apply only if
isopropyl alcohol is used in the fountain, and then only applied on a "batch"
basis instead of every 8-hours. Once tested a "batch" will not change
significantly in VOC concentration.
The Section D.8 (c) "Fountain Solution Temperature" should only be
imposed on those units using isopropyl alcohol. This section targets
"refrigeration equipment" when it should target alcohol. There should not be
the need to test any press which uses alcohol substitutes.
Cleaning solutions should be researched by those intimately familiar
with printing press inking systems prior to mandating a specific percentage of
VOC concentration.
Respectfully submitted,
C. Vm. Schneidereith, Jr.
President
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1.2 QUESTIONS AND COMMENTS FROM THE COMMITTEE
Question: Why is industry not taking advantage of the large
cost savings due to a reduction in alcohol?
Response: The industry has reduced alcohol for Occupational
Safety and Health Administration (OSHA) regulations
and fire insurance benefits. However, it is easier
for the operator to use too much isopropyl alcohol
(IPA) because it makes the press easier to operate
and keep within specifications.
Question: Will ink pigments poison the catalyst in a catalytic
incinerator and can the incinerator actually achieve
95 percent control?
Response: It may not be ink pigments that poison the catalyst
- other ingredients in the inks and in the fountain
solution may poison the catalyst in many cases.
Most vendors work with the printers in choosing the
best catalyst for their operation. Industry has
successfully used catalysts without poisoning. As
for control, current use in industry indicates that
the catalytic incinerator can achieve 98 percent
control.
Question: Do the 16,700 facilities in non-attainment areas, as
referred to in the presentation, take into account
the newly revised non-attainment area boundaries?
Response: Since the boundaries were only revised about a week
before this meeting, there was no time to take into
account the changes and redo the numbers for this
presentation.
Question: How are the very small and large model plants
differentiated?
Response: The size of the plants are determined by the number
of printing units.
Question: Were the operating costs of incinerators based on
3000 operating hours per year, and are the
incinerators shut down at all other times?
Response: Some incinerators may shut down, while others may
"idle" during the off-hours, making warm up
11
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unnecessary. Energy costs were calculated based on
3000 operating hours per year.
Comment: The wording in the draft CTG should be clarified to
ensure that monitoring should take place only when
the unit is operational.
Question: Would reformulation of the inks to soybean inks be a
viable control option for the larger facilities?
Response: Soy inks are used in non-heatset processes, which
have low emissions to begin with. Requiring heatset
processes to change to non-heatset was not
considered reasonable, and hence were beyond the
scope of RACT.
Question: The total percent reduction is plausible based on
what the control device sees, but given the amount
of potential emissions, does this really correspond
to what the control device actually sees?
Response: We may have not made it very clear that the
efficiency values refer to the efficiency of the
control device and not the percent of all VOC's
applied to the substrate. There is approximately 20
percent retention of VOC's from ink in the paper.
Question: Do all the volatile organic compounds (VOC) from
heatset inks go out from the dryer?
Response: Essentially, all the VOC's from the inks that are
volatilized exit through the dryer.
Question: Do the control options for large sheet-fed plants
differ technically from other sheet-fed plants as to
warrant the different control options? What is the
difference between these two types of plants and why
can't control for one unit be the same for 24 units?
Response: The lower level of control for larger plants was due
to the fact that large plants could cope with the
costs better than smaller plants.
Question: Since the alcohol content of the fountain solution
is falling with changes in the industry, what year
were the model plants emissions based on?
12
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Response: The use of fountain solution in the model plant was
based on a report of a survey performed for a
meeting held in 1989; the meeting notes were
published in 1990.
Question: Is there a point in which the performance of the
fountain solution decreased a great deal due to a
reduction in alcohol?
Response: There is no perfect linear relationship between
alcohol content and performance; with a management
commitment to quality, a reduction in alcohol should
not be a problem.
Question: What are alcohol substitutes made of?
Response: They are made up of cellulose derivatives, propylene
glycol, and glycol ethers. Material safety data
sheets (MSDS) do not indicate what makes up the VOC
content or what the hazardous air pollutant (HAP)
content is, and, since many vendors feel that the
fountain solution ingredients are proprietary, it is
difficult to identify all the ingredients of
fountain solution additives.
Comment: Inks should be considered differently than coatings
and the structure of the model rule should be
changed to indicate this difference.
Comment: There were some reservations that requiring lower
VOC cleaning solution (<30 percent VOC) would reduce
the number of different cleaning products available
and would thereby impede the cleaning process, since
one cleaning solution typically cannot be used for
every application. Some printers use 100 percent
VOC cleaning solution and maintain that there is no
viable substitute.
Response: Users of the lower VOC cleaning solution exist and
say that they are able to use these cleaners
successfully. The EPA is trying to obtain more
complete data on this issue and will address it in
the future.
13
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2.0 DISCUSSION SECTION
2.1 AGI ROSOS, PRESIDENT, ROSOS RESEARCH LABORATORIES, INC.
2.1.1 Presentation
Ms. Agi Rosos of Rosos Research Laboratories, Inc. gave a
presentation on alcohol substitutes. Rosos Research Laboratories
has been a manufacturer of alcohol replacements for over 21
years. Ms. Rosos read from a prepared speech that is enclosed.
14
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2.1.2 Questions and Comments
Question: Glycol ethers were mentioned as a component of the
fountain solution. Since glycol ethers are HAP's,
are VOC's being replaced by an equally harmful
chemistry?
Response: Ms. Rosos responded that while the first few
formulations did indeed contain HAP's, Rosos has
completely reformulated the product and are
currently testing the new HAP-free formulation.
Question: Where does OSHA stand on alcohol replacements?
Response: The response was that these substitutes are well
within the limits set by OSHA. However, the
17 percent alcohol level probably would not be
allowed by most states, but printers that stay below
10 percent alcohol would generally not have any
problems with OSHA.
Question: What are the differences between large sheet-fed and
other sheet-fed plants, and is a control distinction
necessary for the two categories?
Response: Ms. Rosos answered that a distinction is not
necessary but she does encourage refrigeration on
all fountain solutions.
Question: Why isn't it possible to measure the VOC content in
the fountain solution by taking samples from the
trays and tanks, and why should samples be taken
from freshly mixed solution?
Response: The response was that the tanks and trays contain
recirculated solution with residual contaminants due
to contact with other parts of the press. The
samples should be taken near the tap of the alcohol
proportioner, as alcohol is mixed with water.
15
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2.2 PAUL MARTIN, C.A. ENTERPRISES, LTD.
2.2.1 Presentation
Mr. Paul Martin of C.A. Enterprises, LTD. gave a
presentation regarding the use of magnets in reducing the surface
tension of water in the fountain solution. C.A. Enterprises has
been primarily a manufacturer of magnets for the treatment of
water used for heating and cooling in residential and commercial
buildings uses for the last 20 years. The magnets help control
lime, scale and corrosion in equipment that contacts water.
Mr. Martin read from a prepared speech that is enclosed.
16
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2.2.2 Questions and Comments
Question: If the magnets can do what you have said they will,
then why aren't they used by all printers?
Response: Mr. Martin responded that the use of magnets for
this industry is a completely new technology.
Currently, there are approximately 1,000 units in
operation. The technology was introduced to the
industry in April 1990.
Question: How expensive are these magnets as compared to the
cost of a press?
Response: The response was that magnets cost about $3000 per
press, with a life approximately egual to that of a
press. The cost of a press is approximately $1.6 to
2 million dollars.
Question: What types of modifications to the presses are
necessary for retrofitting the magnets to the press?
Response: Mr. Martin responded that it took about 10 minutes
to add magnets to one press. After the
modification, press operators may need to make
adjustments to the process. The most significant
adjustment would be the speed of the water roller.
Question: Is there anything in the draft CTG that would
preclude the use of these magnets?
Response: There is nothing in the draft CTG indicating that
the magnets are not an option of control. In fact,
the quality of the process would increase as a
result of using the magnets. In addition, alcohol
substitutes would become more effective since water
is more soluble with the magnets. Some users run
the presses with magnets and an alcohol-free
fountain solution.
17
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2.3 WILSON CUNNINGHAM, VICE PRESIDENT TECHNICAL RESEARCH,
AMERICAN NEWSPAPER PUBLISHERS ASSOCIATION
2.3.1 Presentation Summary
Mr. Wilson Cunningham for the American Newspaper Publishers
Association (ANPA) gave a presentation to discuss ANPA's comments
on the draft CTG. The ANPA is a trade association that
represents publishers of approximately 1350 newspapers.
Mr. Cunningham read from a prepared speech that is enclosed.
18
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2.3.2 Questions and Comments
Question: What is the content of ink pigments?
Response: Mr. Cunningham responded that black ink is mainly
carbon black, and all color newspaper pigments are
complex organic compounds.
Question: In reference to the chart in the presentation
showing the recommended ranges for fountain solution
and cleaning solution usage, as compared to those
shown in the draft CTG, the new calculated medians
seem to fall within the ranges reported in the draft
CTG, so why would it be necessary to recalculate the
usage rates?
Response: Mr. Cunningham responded that while the medians fell
within the ranges given in the draft CTG, the upper
limits of those ranges were too high. In addition
the ANPA would prefer to be regulated based on real
data as opposed to projected data.
Question: Since there is such a wide variation in the volatile
percent of inks, could the volatile content be
regulated to 10 percent or less?
Response: The response was that inks are formulated to satisfy
the consumer as well as regulations. As rule of
thumb, as the VOC content increases, the amount of
rub off decreases, so it is important to find a
middle ground to allow the least amount of rub off
without significantly increasing VOC content. In
general, VOC content would not go down very much.
Comment: The rule recommended by the draft CTG is not
intended to be used for the purpose of emission
inventories. Although credit for waste ink and
solvent ink used to determine NSPS rules, it is not
pertinent to the draft CTG.
19
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2.4 JAMES RENSON, COORDINATOR ENVIRONMENTAL AFFAIRS, NATIONAL
ASSOCIATION OF PRINTING INK MANUFACTURERS
2.4.1 Presentation Summary
Mr. James Renson, of the National Association of Printing
Ink Manufacturers (NAPIM), gave a presentation on printing inks
as related to the draft CTG. NAPIM is a national trade
association representing small, medium and large printing ink
manufacturers in the United States. There are 80 members in this
association accounting for approximately 90 percent of the total
U.S. sales of printing ink. Mr. Renson read from a prepared
speech that is enclosed.
20
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2.4.2 Questions and Comments
Question: Where are no-rub inks used?
Response: The oils in inks are absorbed leaving carbon black
on the top of the substrate. A no-rub ink has more
resin, but also has higher VOC content. Some
examples of printers using no-rub ink are Time and
Newsweek magazines.
Question: Is "Method 30" an EPA method?
Response: Mr. Renson said that "Method 30" is a California Bay
Area Air Quality Management District (BAAQMD) test
method. There is an ATSM method for EPA Method 24,
and there will soon be an ATSM Method for BAAQMD
Method 30.
21
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2.5 ENVIRONMENTAL CONSERVATION BOARD (ECB) OF THE GRAPHIC
COMMUNICATIONS INDUSTRIES
2.5.1 Gerald Bender, Vice President Environmental Affairs,
R.R. Donnelley & Sons Company; Web Segment
2.5.1.1 Presentation Summary. Mr. Bender began his
presentation with a discussion on the sources of VOC's. The
three sources of VOC are: ink oil solvents, fountain solution
additives, and cleaning solvents. Ink oil solvents were not
originally considered VOC's, but when the definition of VOC was
changed, the ink oils fell into the category of VOC's. These
oils can be compared to No. 2 fuel oil. The need for fountain
solution as well as the amount depends on the equipment.
Cleaning solutions include blanket wash, auto blanket wash,
roller wash, and other miscellaneous cleaning, such as equipment
cleaners, plate cleaners, etc.
To explain the concept of blanket-to-blanket printing, a
schematic of the unit was presented (see attachment). Ink and
fountain solution are applied to a large cylinder called a print
plate. The image is formed on the print plate and transferred to
the blanket cylinder, and then the final image is printed on the
substrate. The system shown in the schematic is called a
blanket-to-blanket unit because it prints both sides of the
substrate at the same time.
There are many types of applicators for fountain solutions,
each one requiring a different need for alcohol or alcohol
substitutes. The first type of applicator is the continuous
dampening system. Fountain solution is contained in a shallow
pan and, as shown on the schematic for the continuous dampening
system, there are rollers that pick up the solution and carry it
to the rest of the unit. In some cases, brushes or spray nozzles
are used in place of rollers to transfer solution to the plate
cylinder. In this case, alcohol substitutes may be used in
concentrations of about 0.5 to 1 percent, but only to keep the
blanket cylinder free from debris, not for high quality printing.
This schematic shows a blanket-to-blanket web offset press.
For a four-color press, there would be four sequential units
22
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followed by a dryer. Drying does not occur between colors as
with rotogravure printing.
A continuous dampening system requires at least 3 to
4 percent alcohol in the fountain solution for good quality. The
ECB is asking that the level of alcohol allowed be increased to
5 percent to allow a margin for error. Small printers cannot
afford to not use alcohol. They need a little more latitude to
add alcohol or alcohol substitutes to make the chemistry work.
Mr. Bender remarked that since the document deals with
existing operations, printers cannot afford to redesign their
presses to operate with less alcohol. Alcohol not only cleans
the print plate, but it also changes the rheology properties of
the water (i.e. lowers the surface tension of the water). Small
variations in the amount of alcohol alter the viscosity of the
water, and therefore change the rate at which the solution is
transferred to the plate. Older presses cannot speed up their
fountain rollers to accommodate the reduction in alcohol.
Mr. Bender addressed the control options next. The three
types of controls are condenser filters, condenser filters with
activated carbon, and incinerators (both catalytic and thermal).
A recommended control level in terms of percent reduction for
condenser filters does not make sense because condenser filters
operate best when the loading is very high. The ECB suggested
that a concentration limit should be set on the exhaust stream
instead of a percent reduction.
Condenser filters with carbon work very well in removing the
condensed oils from the dryer exhaust, but the oils are almost
impossible to remove from the carbon. According to Mr. Bender,
hot air and low pressure steam will not remove the condensed
oils. Since most facilities do not have high pressure steam at
their convenience, this is not a viable option. It was suggested
that this type of control was a misapplication of activated
carbon.
The ECB reviewed the costs for the different control options
and found capital and annual cost to be slightly lower than
expected. Not included in the cost analysis were costs for
23
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safety purges of the incinerator and replacement of the filter
material in the condenser filter.
The next issue addressed by Mr. Bender was the model rule in
Appendix D of the draft CTG. The first topic was the
applicability section (section D.2) of the model rule. The ECB
would like some guidance to the States as to the definition of a
major source; also, the States need information on how to apply
RACT to the industry.
The ECB then suggested that the control level (for the
emissions standards section (D.4) of the draft CTG) should be 90
percent instead of 95 percent to give the printer some leniency
in operation.
Mr. Bender suggested changes in the equipment standards
section of the draft CTG (section D.5). The changes mainly
concerned raising the levels of the alcohol permitted in the
fountain solution. Also, the States have required the exclusive
use of EPA Test Method 25 to test heatset dryer emissions. This
test, however, is not repeatable and therefore not a reliable
test method for this industry.
The rest of the suggested changes for the draft CTG concern
rhetoric and are attached following this summary.
2.5.2 William Schaeffer, Consultant to Graphics Arts Technical
Foundation (GATF), Chairman of the Technical Committee
2.5.2.1 Presentation. Mr. Schaeffer read from a prepared
speech that is enclosed.
2.5.3 C. Wm. Schneidereith, Jr., President, Schneidereith
& Sons, Inc.; Sheet-fed Industry Segment
2.5.3.1 Presentation. Schneidereith & Sons, Inc. is a
commercial printing facility that operates 20 printing units in
its sheet-fed, offset lithographic facility. Mr. Schneidereith
read from a prepared speech that is enclosed.
24
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2.5.4 Questions and Comments
Question: An alternative concentration requirement may work
with incinerators, but would it work with condenser
filters? Couldn't the air flow from the dryers be
increased to dilute the exhaust and, hence, lower
the concentration of VOC's measures, without any
real decrease in emissions?
Response: There is a high concentration of VOC's in the dryer.
Increasing the air flow is not a good idea, since
the air leaving should be at the saturation level or
dew point. This option will be researched further.
Question: Were there any numbers to support the claim that as
VOC concentration decreases, solid waste increases?
Response: Waste is generated during changeover and runs.
There are no numbers at this time concerning the
trade-off between VOC's and solid waste. Data is
available on waste incurred during various run
parameters. Less effective cleaners increase waste
and decrease safety.
Question: During the three presentations, each speaker
recommended a different limit on the percent alcohol
allowed in the fountain solution. What are the
reasons for this discrepancy?
Response: The different levels refer to different segments of
the industry.
Question: Is taking samples of batches of solution common for
small or for large facilities?
Response: Large shops have central fountain solution
circulators, smaller shops make 10 gallons at a
time. Once the batch is made, it won't change.
Question: Have cleaning solutions of 30 percent VOC have been
tried? Have they been examined for quality?
Response: These cleaners have been tried and they do not work.
The lower the VOC content, the longer the drying
time and the volume necessary for good cleaning is
increased. The press is also shut down during this
-------
time, so it would shut down longer when cleaning
with these lower VOC cleaners.
Question: Six tons per year of cleaning solution emits
5.13 tons of VOC, corresponding to approximately
84 percent VOC. Is the residual VOC-free? If so,
what happens to the remaining 16 percent? Are all
the volatile materials emitted?
Response: Some of the remaining cleaning solution leaves the
shop in the cleaning rags, and the rest goes into
the waste solution.
Question: The model plants showed that the fountain solution
for non-heatset web facilities emits the largest
amount of VOC's; another speaker indicated that this
was too large. Is this true?
Response: The emissions were indeed too high.
Question: Do inks volatilize?
Response: The inks do not volatilize during the normal process
until, in the case of heatset inks, they reach the
dryer, where 80 percent is volatilized in the dryer.
Question: Have you had any experience with the magnet as a
form of water conditioning?
Response: GATF submitted surface tension data comparing water
with and without magnets. No difference was noted
in the lab studies.
26
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nooirn
NATIONAL ASSOCIATION OF PRINTING INK MANUFACTURERS, INC.
47 Halstead Avenue, Harrison, New York 10528 / Phone: 914-835-5650
Fax:914-835-5988
JAMES H. SUTPHIN, Executive Director
November 11, 1991
Mr. Bruce C. Jordan
Chair, National Air Pollution Control Techniques Advisory
Committee
Director, Emissions Standards Division (MD-13) Office of Air
Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Dear Mr. Jordan,
The purpose of this letter is to present comments on the draft
CTG for offset lithographic printing prepared for EPA by the
Radian Corp. These comments are presented by the National
Association of Printing Ink Manufacturers, Inc. (NAPIM) on behalf
of the printing ink industry -
NAPIM
NAPIM is a national trade association representing small, medium
and large printing ink manufacturers in the U.S. Its eighty
members account for nearly ninety percent of the total U.S. sales
of printing ink. The printing ink industry is composed of 224
companies operating a total of 504 manufacturing facilities
according to the U.S. Census of Manufactures for the year 1987.
Total shipments of printing ink in the U.S. were over $2.7
billion in 1990.
NAPIM has been vitally concerned with the need to clarify the
definition of VOC which currently varies widely from state to
state. We are also vitally concerned that the definition of VOC,
and the application of this definition to various types of
printing inks, be reasonable and fair to the printing and
converting industries in the U.S.
DEFINITION OF VOC
NAPIM is especially concerned with the proposed definition of VOC
emission from inks which are applied without the addition of heat
(so called no-heat inks). These inks encompass newsink and other
no-heat web offset inks; forms inks for commercial business
forms, and sheet-fed ink normally used for high quality color
printing. While NAPIM acknowledges that the use of the Method 24
oven test condition of 110 degrees C for one hour is appropriate
for determining VOC content of heatset inks which are dried
through the application of heat, we submit that the use of Method
24 is not appropriate to define the VOC content of lithographic
ink which is applied without heat as proposed in the draft CTG.
-------
We have attached a copy of a report prepared by a task force of
the National Printing Ink Research Institute (a subsidiary of
NAPIM) prepared for Radian Corp. to provide background on
measurement of VOC's for no-heat ink. The data and information
given in this report show clearly that press temperatures for no-
heat inks do not exceed 40 degrees C and that these inks are
normally on the press for less than 20 minutes. Therefore,
although the draft CTG applies a retention factor of 95 percent
for no-heat inks, the conditions specified for Method 24 are
fundamentally much too severe for inks which are applied without
heat.
In the draft CTG, Radian Corp. has quite properly proposed a
retention factor of 95 percent for no-heat ink. In other words,
Radian has acknowledged that at least 95 percent of the VOC in
the applied ink remain in the ink on the substrate or are
absorbed into the substrate. While this may appear to make
allowance for the excessively rigorous Method 24 procedure, NAPIM
believes that the proposed retention factor is readily subject to
change by the states in the preparation of their SIP's whereas
the method to determine VOC will be fixed by the CTG.
ALTERNATIVE METHOD FOR DETERMINING VOC
NAPIM would like to call attention to an oven test method
proposed by the California Air Resources Board for the Bay Area
Air Quality Management District to determine the VOC content of
no-heat ink. This is known as Method 30 and will shortly_be
confirmed as an approved test method by ASTM. Method 30 is
conducted at 40 degrees C for one hour and since press
temperatures do not exceed 40 degrees C, and since ink residence
time on press is less than 20 minutes, Method 30 will predict VOC
for no-heat ink with a comfortable margin of safety. We urge the
NAPCTA Committee to recommend that EPA adopt Method 30 to measure
VOC content of no-heat lithographic inks.
TYPICAL VOC CONTENT
Under section 2.5.1 on page 2-8 an estimated VOC content for non-
heat set web inks is given as 30 percent. NAPIM submits that this
reflects a "worse case" scenario since in actual practise ink oil
content in these types of ink is much lower. Based upon
production figures and VOC determinations for the various types
of non-heatset web inks (black and colored newsinks, regular
offset newsinks, no-rub offset newsinks, forms inks, etc.) the
weighted average VOC is estimated at 10 percent. In order to
reflect the true average VOC content for these inks, it is urged
that the average be changed from 30 percent to 10 percent.
-------
SUMMARY -
We ask that the foregoing comments be considered in the
Committee's evaluation of the draft CTG and urge that the
suggested change in the method used to determine VOC's in no-heat
ink be adopted.
We appreciate this opportunity to comment on the draft CTG and
would be pleased to answer any question which the Committee may
have.
a H. Sutphin
Executive Director
/dem
Jordan.jhs
cc: NAPCTA Committee
NPIRI VOC Task Force
-------
REPORT TO RADIAN CORPORATION ON VOC'S FOR NON-HEAT INKS
FROM NAPIM/NPIRI TASK FORCE ON VOC'S
MAY 29, 1991
INTRODUCTION
The graphic arts industry and, in particular, the printing
ink industry (whom we represent) are concerned about test methods
being used to control VOC emissions for lithographic inks that
are applied at ambient temperatures without heat. Because of
this concern, NAPIM under its research affiliate NPIRI, formed an
industry Task Force on VOC so that its dialogue with the EPA and
other regulatory bodies would be based upon an industry consensus
and not on a company by company basis.
Specifically, the Task Force is concerned about the use of
totally unrealistic conditions such as EPA Reference Method 24
(one hour at 110 degrees C) to determine the VOC emission for
inks such as newsinks, forms inks, and sheetfed inks that are not
heated during application.
Newsinks, forms inks and sheetfed inks contain light
distillate oils that have minimum initial boiling points of 480
to 540 degrees F, and which are essentially non-volatile under
ambient conditions. Based upon VOC emissions measured at
production newspaper presses and temperature measurements made
for these same news presses and sheetfed presses, the Task Force
submits that an oven test such as Method 30 (one hour at 40
degrees C) more than adequately measures the emissions that may
be expected from these inks.
PRESS TEMPERATURES
Newspaper Presses - The American Newspaper Publishers
Associations (ANPA) Reston, VA measured temperatures of newspaper
presses at four operating newspapers in the greater Washington
B.C. area (see Table I). There was virtually no difference in
temperatures taken in the summer and winter time at the same
presses. Maximum temperatures varied between 30 and 43 degrees C
for continuous operation. The maximum temperature of 43 degrees
C was achieved for a Mark II Letterpress which is not used for
lithographic ink. The average maximum for all presses was 36
degrees C. It seems clear that an oven emissions test of 40
degrees C for one hour more than adequately covers emissions from
newspaper presses since ink residence time on the press roller
train is estimated as less than 20 minutes.
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- 2 -
Sheetfed Presses - The NAPIM Task Force determined the
temperatures of five production sheetfed presses covering rates
of 4,000 to 9,000 Impressions Per Hour (IPH). Data are shown in
Table II. Maximum temperatures of 100 degrees F or 38 degrees C
occurred at the form roller and the delivery location. In one
instance, a temperature of 110 degrees F (43 degrees C) was
recorded for a press having an Infra-Red heater at the delivery
point. As is the case for newspaper presses, an oven emissions
test conducted at 40 degrees C for one hour will measure sheetfed
press emissions more than adequately. Ink residence time in a
sheetfed 'press is also estimated at less than 20 minutes.
TGA TESTS
In an effort to obtain more precise and more meaningful VOC
data, the NPIRI Task Force contracted with the John Brown
Laboratories, Stirling, N.J., to conduct Thermogravimetric
Analyzer (TGA) tests for magenta quick-set sheetfed ink, and a
black no-rub news (black) ink. These inks were selected because
they contain the highest concentrations of light distillate oils
of all non-heat lithographic inks.
The tests were conducted with thin films of ink on aluminum
substrates. Tests using paper as a substrate showed interference
from water vapor which could not be accurately accounted for.
However, an impervious substrate such as aluminum can be expected
to give higher results because of the lack of absorption forces
that can be expected to be present with paper.
TGA data for the sheetfed ink are shown in Figures 1, 2, and
3 attached. The three curves represent heating rates of 0.25,
1.0 and 5.0 degrees C per minute respectively- Note in each case
that there is no weight loss until a temperature of about 50
degrees C is reached, a temperature which exceeds maximum
temperatures measured for a sheetfed press.
TGA data for the no rub newsink are shown in Figure 4. VOC
weight loss at 41 degrees C (which exceeds the maximum average
press temperature by 5 degrees C) is only 0.5%.
TGA/Oven Data A comparison of TGA and oven test data are shown
below:
VOC, % Loss
TGA at 40
Ink Degrees C Method 30 Method 24
Sheetfed 0 1.8 14.8
No-Rub News 0.5 1.7 24.3
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- 3 -
The above results show good agreement between TGA results, a
precise measuring instrument, and Method 30 oven data. Method 24
data are considerably higher because of its unrealistically
higher temperature (110 degrees C).
EMISSION TESTS
In addition to determining press temperatures, the ANPA also
measured VOC emissions around these same four newspaper presses
during actual production runs. Data are shown in Table III. The
maximum concentration determined was 68.3 mg/M . Inspection of
the GC trace revealed a high concentration of Cg and C-j^
hydrocarbons which undoubtedly came from wash solvent used on the
press. When inks obtained from the various press runs were
analyzed using an OHSA approved device to collect VOC's, the high
proportion of Cg and C-^ compounds were no longer observed.
To study emissions under more carefully controlled
conditions, ANPA conducted tests at its press facilities using
inks supplied by NPIRI Task Force members having three different
VOC contents. Emissions data are shown in Table IV. Emissions
during the controlled runs were about one-tenth of those measured
during production runs. During the controlled runs a concerted
effort was made to minimize the effect of wash solvents, which
contributed to the lower emissions observed. Since emission were
all low, it was difficult to find significant differences among
the various inks. The low rub and no rub inks, which would be
expected to have higher emissions, did have slightly higher
emissions as a class, than the regular black ink. However, all
inks were very low in emissions generated.
/dem
radian.jtd
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TABLI5 I
Winter
Blanket Cylinde
Circulation Press Type Min Max High Min Max High Min Max High M.JIL
Press Type
i
Urbanite
Metro
TKS
Mark II*
Summer
Form Roller Blanket Cylinder Form Nolle
Min Max High Min Max High Min Max Hl<
24 31 36 n/a n/a n/a 25 30 30
28 34 39 37 36 42 28 34 42
28 32 38 29 36 40 25 36 36
32 43 43 n/a n/a n/a 33 38 44
37,000 Urbanite 24 31 36 n/a n/a n/a 25 30 30 n/a n/a n/a
375,000 Metro 28 34 39 37 36 42 28 34 42 ' 29 37 4J
717,000 TKS 28 32 38 29 36 40 25 36 36 28 40 40
717,000 Mark II* 32 43 43 n/a n/a n/a 33 38 44 n/a n/a n/a
Min = Minimum Observed Running Temperature
Max s Maximum Observed Running Temperatuare
High = Highest Temperature Observed After pressn Was Stopped
* Letterpress
-------
TABLE JI -Inly. I Ort!.
sTPign PRESS TEMPISHATURKS
RRESS MIEIIM:, <1C MIEIII.E, 4C MlElll.lt. 4C HARRIS. 6C KOMORI 6C
16" 31" .||" 25" .,n" '
SPEED, IPH
ROOM TEMPERATURE. "F
INK FOUNTAIN, °F
WATER FOUNTAIN, °F
INK TRAIN ROLLERS, °F
FORM ROLLER, "F
PRINTING PLATE, °F
DELIVERY
IRUN1T NO vns vns MO Yns
RAYTGK RAYNGER IK I'lSTOI. TIII-RMOMI-TI-R. M.ulcl «U-380 - ..su.l lo ol.lain ..hovc ,|.,|.,.
>MOO
70 (26°C)
8f) (31°C)
M
90 (32'C)
100 (38°c)
HII
90
7800
90
90
50
90
90
H8
100
5300
88
90
50
90
100
90
90
•II MX)
711
80
55
90
SO
.SI)
75
9IXV)
70
100
_.
98
9H
85
110
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TABLE III
VOLATILE EMISSIONS FOR FOUR NEWSPAPERS
DURING PRODUCTION OPERATIONS
Circulation
37,000
37,000
375,000
717,000
717,000
717,000
717,000
*Letterpress
Press Type
Goss Urbanite
Goss Metro
Emission,
TKS
Goss, Mark II*
Primarily Cg - C
TABLE IV
VOLATILE EMISSIONS DURING CONTROLLED PRODUCTION RUN-^- (mq/M^)
52.6
43.0
68.3
42.8
40.5
19.8
25.8
hydrocarbons
Sample
Location
Right Ink
Form Roller
Left Ink
Form Roller
Pipe Roller
Regular
Black
3.1
3.7
0.6
Ink Type
Low Rub
Black
5.0
5.2
5.7
No Rub
Black
2.6
3.2
1.1
'
Limited wash solvent
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TABLE V
VAPOR PRESSURE, mm Eg
Rule 66 L.D.O.
Temp. F ( C) Min. Sp. 540 IBP
68 (20) 5.6 0.01
100 (38) 12.5 0.03
150 (66) 37.0 0.18
250 (121) 200 3.0
350 (177) 740 26.0
Distillation
Range F
IBP 320 538
50% 350 554
FBP 380 599
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.gure 1
TGA Test Quick Set Sheet Fed Ink
2.5-
2.3-
2.1-
O>
6
•H
(U
* 1.9-
1.7H
1.5-
50
100 150
Jemperature (°C)
200
250
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Figure 2
TGA Test Quick Set Sheet Fed Ink
3.B-
3.6H
en
en
•i-t
QJ
3.2H
2.BH
2.6H
2.4
)
r
50
100
:, Temperature (°C)
150
**?
2UO
-------
Figure 3
TGA Test Quick Set Sheet Fed Ink
2.On
o»
e
r.
01
rH
cu
l.BH
1.2-f-
r
50
100
^Temperature
T -
150
200
(°C)
250
-------
1.2-
1.0-
O.B-
01
E
r\
OJ
0.6-
0.4-
0.2
I •
.'25
r /
I- /
Figure 4
TGA Test No Rub News Ink
-, I A rrrv < v^
- '
j c /o
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WOOD FURNITURE COATING CTG
STATUS REPORT TO THE COMMITTEE
ON REGULATORY DEVELOPMENT
Seven presentations were made to the Committee concerning the wood furniture coating
CTG: one by EPA, four by coating and equipment manufacturers, and two by industry
representatives. The key points of each presentation and the discussions that followed are
summarized below, accompanied by the handouts prepared by the presenters.
1. EPA PRESENTATION
The EPA presentation was made by:
Ms. Mary-Jo Caldwell
Midwest Research Institute
Ms. Caldwell summarized the status of the wood furniture coating CTG project. A copy
of the presentation is attached.
A total of eight SIC codes, covering five industry segments, were considered in the
analysis. The five industry segments considered included residential wood furniture
manufacturers, cabinet manufacturers, office furniture manufacturers, institutional furniture
manufacturers, and store fixture manufacturers. These five industry segments are referred to
as "the wood furniture industry".
Based on Census of Manufacturers' data, approximately 11,000 facilities fall into the five
industry segments just mentioned. The majority of the industry is made up of residential
furniture and cabinet manufacturers, each of which constitute about 35 percent of the industry.
More than 90 percent of the 11,000 facilities are considered small, that is, have less than 100
employees.
It is interesting to note, however, that although large facilities, (i.e., those with more
than 250 employees), constitute only three percent of the total number of facilities, they
contribute about one-third of the total VOC emissions. The wood furniture industry VOC
emissions are distributed approximately equally among the three sizes of facilities. The wood
furniture industry is one of the largest uncontrolled stationary VOC sources.
Residential furniture manufacturers generally assemble their pieces and then finish them.
-------
The remainder of the industry also does some prefinishing of unassembled pieces. Coatings are
usually spray applied. The residential furniture manufacturing industry generally uses manual
spraying, whereas the rest of the industry uses both manual and automatic spraying. Flatline
coating methods such as curtain coating and rollcoating are not presently used extensively by this
industry.
The finishing process may be a single or multi-step operation. The coating may be
manually or automatically spray applied in the spray booth. The piece then leaves the booth,
and may be wiped before entering the flash area, where the faster solvents are allowed to
evaporate. The piece may then enter an oven, and after cooling, may be sanded, after which
subsequent coatings may be applied.
The coatings presently used by this industry are primarily solventborne coatings.
Residential furniture manufacturers generally use nitrocellulose lacquers, which cure by solvent
evaporation. The remainder of the industry uses urea-formaldehyde and melamine-formaldehyde
acid-catalyzed coatings, as well as nitrocellulose lacquers.
Based on information obtained from wood furniture manufacturers, EPA estimated that
about 94 percent of the total VOC emissions result from finishing operations, with the remaining
6 percent being attributable to cleanup operations. Volatile organic compound emissions in the
finishing operation occur as a result of solvent evaporation in the spray booths, flash areas, and
ovens. Cleanup VOC emissions result primarily from application equipment cleanup, which
usually occurs in the spray booth. Additional cleanup VOC emissions result from repair
operations, which also usually occur in the spray booth, and miscellaneous cleanup operations,
which occur throughout the finishing area.
In order to evaluate potential control strategies, EPA had to develop model plants to
represent the wood furniture industry as a whole. The industry was broken down into two main
groups: residential furniture manufacturers and other. Included in the "other" category are
cabinet manufacturers, office and institutional furniture manufacturers, and store fixture
manufacturers. This category is referred to as "office/cabinet", though institutional furniture and
store fixture manufacturers are also included in this category.
The residential furniture manufacturing segment was further broken down into short and
long finishing sequence, and then by size. The majority of the office/cabinet segment uses the
same finishing sequence, but this segment was broken down by manual and automatic spraying,
(since both application methods are used by this segment of the industry), and then by size. Due
to the capital investment required for an automatic spray application system, it was assumed that
small facilities would not use automatic spraying.
For purposes of the analysis, the size of the model plants was based on total annual VOC
emissions. Total VOC emissions of 50 tons per year (ton/yr) corresponds to the small model
plant, 225 ton/yr corresponds to the medium model plant, and 500 ton/yr corresponds to the
large model plant.
In order to evaluate lower-VOC coating alternatives, finishing sequences had to be
842
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developed for each of the model plants just discussed. The finishing sequences described during
the presentation are intended to represent typical finishing sequences. Actual finishing sequences
may, and probably will, differ from those shown.
The office/cabinet industry uses a finishing sequence that consists basically of application
of stain, sealer, and topcoat. Residential furniture manufacturers using a short finishing
sequence use essentially the same sequence, except they also apply washcoat after stain, before
sealer. Residential furniture manufacturers using a long finishing sequence use the same
coatings as manufacturers using a short sequence, but the coatings are applied more frequently,
and additional coatings, including filler, wiping stain, and highlight, may also be used.
The relative VOC emissions from each of the finishing steps was presented. Topcoat
application contributes from 35 to 40 percent of the total finishing VOC emissions. Stain and
sealer both constitute about 25 to 30 percent of the total finishing VOC emissions.
A variety of factors were considered in evaluating control methods, including: the
control techniques available, the types of coatings and finishing sequence used, total VOC
emissions and the concentration of VOC's in the exhaust stream, the number and types of VOC's
present in the exhaust, and the total exhaust flowrate to be controlled.
Based on the evaluation of the applicability of various control methods, two primary
control alternatives were considered for the finishing process. The control alternatives
considered included lower-VOC coatings, add-on controls, and a combination of the two
methods. Though these control methods have limited use in this industry, they are not presently
widely used in the wood furniture coating industry.
The lower-VOC coatings evaluated include waterborne, polyester, and polyurethane
coatings. The add-on controls evaluated include recuperative thermal incineration, regenerative
thermal incineration, catalytic incineration, and combined adsorption/thermal incineration.
Because the capital and operating costs of add-on controls are a function of the flowrate
controlled, add-on control vendors indicated that exhaust flow reduction is an essential
consideration when evaluating add-on controls. Therefore, two exhaust flow reduction methods
were evaluated. These include spray booth recirculation, which involves recirculating a portion
of the spray booth exhaust back into the spray booth, and the air curtain system. The air curtain
system uses an air curtain to separate the worker from the VOC emissions. The worker stands
outside the booth and reaches through the air curtain to spray apply the coating to the piece.
Since the worker is not inside the booth, VOC levels do not have to be maintained below the
permissible exposure limit, and therefore, high exhaust flows are not required and thus, the
spray booth exhaust is significantly less than that of a comparable manual spray booth.
Three primary control alternatives were considered for cleanup operations, including
work practice modifications, reformulation of cleanup materials, and the use of add-on controls.
Work practice modifications may include the use of enclosed spray gun cleaners and closed
containers for the storage of saturated rags. Cleanup material reformulation may include
reformulating with lower-volatility solvents, or may involve the use of aqueous-based cleaners.
The same add-on controls just described for finishing operations may also be used to control
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VOC emissions resulting from cleanup operations.
The control alternatives were evaluated for each model plant, then permutations of
different controls being applied to different model plants were developed to form RACT options.
Under a single RACT option, the same controls may not necessarily be applied to all model
plants. Therefore, the RACT option descriptors do not necessarily indicate the control strategy
being applied to all model plants.
A total of nine RACT options were developed. Options 1 through 4 involve the use of
lower-VOC coatings; RACT Options 6 through 9 involve the use of add-on controls; and RACT
Option 5 involves the use of lower-VOC coatings in conjunction with add-on controls.
RACT Option 1 is described as full waterborne. Under this RACT option, office/cabinet
manufacturers and residential furniture manufacturers using a short finishing sequence use full
waterborne coating systems which involve waterborne coatings for each of the coating
application steps. The majority of the coating suppliers and wood furniture manufacturers
contacted indicated that full waterborne coating systems are not presently suitable for residential
furniture manufacturers using a long finishing sequence. Therefore, under RACT option 1,
residential furniture manufacturers using a long finishing sequence were assumed to use hybrid
waterborne coating systems.
RACT Option 2 is described as hybrid waterborne. Under this RACT option, all plants
use a hybrid waterborne coating system consisting of waterborne sealer, topcoat, and highlight
(as applicable), with conventional solventborne coatings for the remaining coating steps.
RACT Option 3 is described as poly ester/poly urethane. Based on conversations with
coating suppliers and wood furniture manufacturers, it was assumed that a dust-free environment
is required when applying polyester/polyurethane coatings, due to the difficulty in repairing these
coatings. Because of the capital investment required for a dust-free environment, it was assumed
that small facilities (that is, those with less than 100 employees) would not apply
polyester/polyurethane coatings. Therefore, under RACT option 3, it was assumed that small
facilities would use hybrid waterborne coating systems, and all medium and large facilities use
polyester/polyurethane sealer, topcoat, and filler (as applicable) in conjunction with conventional
solventborne coatings for the remaining coating steps.
RACT Option 4 is described as polyester/polyurethane with waterborne coatings. RACT
option 4 is essentially the same as RACT option 3 except that office/cabinet manufacturers and
residential furniture manufacturers using a short finishing sequence also use waterborne stain and
washcoat, and residential furniture manufacturers using a long finishing sequence use waterborne
"highlight.
RACT Option 5 is described as hybrid waterborne in conjunction with add-on controls
being used to control VOC emissions from selected coating steps. Under this RACT option, all
facilities use hybrid waterborne coating systems. Due to the capital investment required for add-
on controls, it was assumed that add-on controls are not used by facilities with less than 50
employees. Thus, under RACT Option 5, at all facilities with more than 50 employees, it was
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assumed that in addition to using hybrid waterborne coating systems, add-on controls are used
to control VOC emissions from stain and washcoat operations.
RACT Options 6 through 9 are different combinations of the four add-on controls
previously discussed being used to control VOC emissions from all coating steps. Again,
because of the capital investment required, it was assumed that facilities with less than 50
employees do not use add-on controls. Because exhaust flow reduction can significantly affect
the capital and operating costs associated with add-on controls, each of the four add-on RACT
options considered the use of add-on controls with and without spray booth recirculation and the
air curtain system.
The emission reduction and cost associated with applying each of the nine RACT options
previously described to all wood furniture facilities located in ozone nonattainment areas were
evaluated. The nationwide emission reduction; the nationwide control cost; and the associated
cost effectiveness, that is, the dollars per megagram of VOC emissions reduced, were presented.
For example, RACT Option 1 is described as full waterborne. If this RACT option is applied
to all wood furniture facilities located in ozone nonattainment areas, nationwide VOC emissions
would decrease by almost 95,000 megagrams per year, which represents a 72 percent reduction
over uncontrolled nationwide emissions. The associated annualized cost to industry would be
about $229,000,000, with a corresponding cost effectiveness of about $2,400 per megagram of
VOC emissions reduced.
EPA PRESENTATION DISCUSSION
Following the EPA presentation, Mr. Brian Taranto of the NAPCTAC asked if the
impact in the EPA presentation represented just nonattainment areas. Ms. Mary-Jo Caldwell
responded that this was the case. Mr. Taranto then inquired about what percentage of the
emissions from the wood furniture coating industry are in nonattainment areas. The project staff
were unable to provide that information and promised to provide it to Mr. Taranto at a later
time. (Mr. Taranto was later told that based on EPA's estimate of nationwide VOC emissions
for the wood furniture industry, approximately one-third of the total wood furniture coating VOC
emissions occur in non-attainment areas).
Ms. Vivian Mclntire noted that "small" appeared to be defined several different ways
throughout the presentation, as 50 tons/year of VOC, 50 employees, and less than 100
employees. Ms. Caldwell explained that the use of less than 100 employees was the Census of
Manufacturers definition. Because this encompasses most of the industry, the EPA analysis had
to further subcategorize the plants to conduct a meaningful analysis. The subcategories were
0-35, 36-50, and 51-100 employees.
Ms. Deborah Sheiman asked for the basis of the decision that some control alternatives
are too expensive for plants employing 50 people or less. Ms. Karen Catlett of EPA stated that
the cost effectiveness values (dollars per ton of VOC emissions reduced) were much higher for
facilities with less than 50 employees. For plants with at least 50 employees, the cost
effectiveness values range from $500 to 8,000/ton, while for plants with less than 50 employees
the cost effectiveness values ranged from $6,000 to 9,600/ton. Mr. Jordan elaborated that it was
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staff judgment that the costs are too high. Ms. Sheiman then suggested that the line
distinguishing between cost effective and ineffective control may have been drawn in the wrong
place, that some of the plants with less than 50 employees may be able to afford add-on controls.
Ms. Catlett responded that EPA will look into this issue further.
Mr. John Pinkerton asked if this industry is largely uncontrolled, which Ms. Catlett
confirmed. He then inquired about which MACT list the wood furniture coating industry is on
and what the "best of the best" control is likely to be. Ms. Susan Wyatt replied that it is on the
4-year list. Ms. Catlett further responded that there are very few controls being used by this
industry and that the MACT level of control has not been determined yet. Mr. Pinkerton
concluded with the recommendation that the CTG and NESHAP efforts be closely coordinated,
so that the industry is not affected twice by different levels of control. Ms. Wyatt assured Mr.
Pinkerton that EPA is aware of this possibility, which is the reason the wood furniture coating
industry is on the 4-year list. Ms. Wyatt explained that in this way, the CTG and NESHAP can
be considered together, and industry will have knowledge of both sets of requirements before
instituting a VOC control strategy.
Mr. Donald Arkell noted that at this time, the MACT floor would appear to be no
control, because most of the industry is uncontrolled. He asked if the implementation of the
CTG would have the effect of raising the MACT floor for the NESHAP. Ms. Wyatt stated that
the CTG and the NESHAP are on the same schedule, so the CTG will not be imposed first, and
thus will not represent baseline for MACT. Mr. Arkell further inquired how MACT would be
determined, if the floor is uncontrolled. Ms. Wyatt explained that EPA can evaluate control
options more stringent than the MACT floor. Mr. Jordan explained that the MACT floor for
an uncontrolled industry is equal to the minimum control allowed by the Clean Air Act. The
EPA is required to set MACT as the maximum achievable control level. Mr. Berry of EPA
indicated that since the industry is presently uncontrolled, MACT can be set at any level after
looking at the impacts of various options.
Mr. Taranto asked if all of the RACT options are equally technically feasible. Ms.
Catlett said that EPA believes they are all technically feasible, and that this was one of the
reasons for analyzing the costs for all of the RACT options. Mr. Jordan then noted that
technical feasibility means that it can be accomplished; however, it does not necessarily mean
that performance won't be affected.
Ms. Mclntire then inquired if waterborne coatings provide acceptable quality finishes.
Mr. Berry stated that the wood furniture coating industry has traditionally used nitrocellulose
coatings because the finishes are ideal for the industry because they are easy to repair and have
a high gloss. According to Mr. Berry, under the current system, consumers do not have a voice
in the marketing decisions. Mr. Berry said that it is uncertain whether consumers can
distinguish between the gloss levels associated with different finishes, and they would likely
prefer the durability of lower-VOC coatings. Mr. Berry said that there is a tradeoff between
the workability of the coatings in the plant and the long term performance of the coatings in the
home.
Mr. William O'Sullivan noted that many state and local agencies define 25 tons/year as
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a "major" source and recommended that EPA conduct an analysis on this basis as well as the
50 tons/year analysis already performed. Mr. O'Sullivan then suggested performing an analysis
of the cost for add-on controls being used to control only the coating steps that emit the majority
of the VOC (topcoat, sealer, stain), rather than for all coatings; this might help to improve the
cost effectiveness values. Ms. Caldwell of MRI noted that, in the EPA analysis, the 50-employee
category was equivalent to about 35 tons/year, close to the value that Mr. O'Sullivan suggested.
Ms. Sheiman interjected that it might be more reasonable to define cutoffs on the basis of
emissions rather than employees. Ms. Caldwell went on to explain that, for nationwide
impacts, it was necessary to use number of employees to classify the plants because that is how
the Census of Manufacturers information is organized.
Mr. William Dennison emphasized the need for EPA to analyze cleaning emissions (both
spray gun cleaning and housekeeping), which are potentially a large source of VOC emissions.
Mr. Dennison indicated that in his experience in California, spray gun cleaning was a large area
of contention. The EPA staff responded that cleanup emissions will be addressed.
Mr. Patrick Atkins wondered if EPA had investigated technologies used overseas. Ms.
Caldwell replied that they had looked at European technologies such as polyester/polyurethane
coatings which are used more extensively overseas. However, furniture is manufactured
significantly differently in Europe, with the pieces being flatter and more uniform, which lends
the process to some alternative controls.
Ms. Sheiman inquired about public health issues related to the use of
polyester/polyurethane coatings. Mr. Jordan said that he believed EPA had looked into it and
that there were no risks. Mr. Jordan stated that he would try to provide details at a later time.
This concluded the questions from the NAPCTAC members. Questions were asked by
a member of the audience. Mr. Gerry Currier of Reliance asked if air recirculation and air
curtains are commercially available and, if so, where they can be obtained. Ms. Catlett
responded that air recirculation is used in other spray coating industries and to some extent in
furniture coating. Air curtain spray booths are under development and are currently being tested
on a pilot line. Ms. Catlett further explained that air curtains have been successfully used
commercially on other types of equipment, such as ovens, to contain VOC emissions.
Mr. Currier asked for clarification of Chapter 5 of the CTG document, which he
interpreted as utilizing a permanent a total enclosure incorporating the entire finishing room, not
the individual emission sources. Ms. Catlett replied that he was correct. The questioner then
asked if any such enclosures are in use in the wood furniture coating industry. Ms. Catlett
responded that the industry is largely uncontrolled and, therefore, there is no reason for facilities
to have total enclosures in place since they would merely exhaust to the atmosphere.
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2. UNICARBR SYSTEM PRESENTATION
The UNICARBR presentation was made by:
Thayer West
Market Manager - UNICARBR System
Union Carbide
Mr. Thayer presented a brief description of how the UNICARBR System works, its
applications, and the VOC emissions reductions achieved (see attached handouts). The system
substitutes CO2 for conventional solvents in coatings. This substitution lowers the total VOC
content of the coatings. The CO2 primarily replaces the "fast" solvents and often replaces HAP
solvents. This system offers the additional benefit of often allowing the use of the same resins
currently in use. The coatings used by this system have a high solids content and can be applied
manually or automatically using electrostatic or nonelectrostatic and airless or air-assisted airless
methods.
The UNICARBR System is currently available for nitrocellulose topcoats and sealers,
pigmented lacquers and enamels, and single component acrylics, polyesters, and urethanes. A
two-component system is under development and may be available in 1992.
The VOC reduction achieved by this system varies with the type of coating and final
product and ranges from about 40 to 75 percent. When looking only at the HAP solvents used
in coatings, reduction of 50 to 85 percent may be achieved.
The UNICARBR System is operating commercially at Pennsylvania House, applying
topcoats to chairs. About a 70 percent reduction in VOC emissions from topcoat application has
been achieved, and the plant is achieving more coverage with the same volume of coatings. A
demonstration system was used at Lehigh, Marianna that reduced the number of sealer coats
from four to two by achieving better film builds. In-plant trials are being conducted at other
furniture manufacturers and in other industries. In Japan, the UNICARBR System is being
considered for its performance characteristics, such as fine particle size and good appearance.
According to Union Carbide, this system provides numerous advantages, as outlined in
the handouts. It is easy to retrofit because it can be installed at a rate of one line or spray booth
at a time. Because the faster solvents are replaced with CO2, the majority of the VOC emissions
occur later in the finishing sequence, in the oven. By moving the solvent emissions from the
booth to the oven, the UNICARBR System makes it easier to control emissions. Finally, Union
Carbide believes that this system has a relatively low investment cost. It was not included in
EPA's analysis of RACT, and Union Carbide is willing to provide cost information to EPA.
UNICARBR PRESENTATION DISCUSSION
Mr. William Dennison asked if there are any size limitations to the technology or any
practical limitations due to cost. Mr. West stated that it depends on the number of coating steps,
but he believes there would be economic paybacks even for the plants emitting less than 50
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tons/year. Mr. West indicated that they are working on making the system more affordable,
such as leasing arrangements. Mr. Dennison inquired about the training requirements for the
equipment, in light of the high employee turnover typical at furniture plants. Mr. West stated
that the training required is minor. Mr. Dennison also asked if the gun cleaning requirements
for the UNICARBR System are the same as for other guns; Mr. West said that they are similar
to the cleaning requirements for airless guns.
Mr. Ralph Hise asked a series of questions regarding how the CO2 and paint are
combined and whether the vessel the coating is stored in is pressurized, and questioned the safety
of the highly pressurized system. Mr. West explained that the paint is not under pressure until
after it enters the spray equipment. The liquid CO2 (at 1,100 psi and 88°F) is fed from standard
gas cylinders into the spray equipment. Simultaneously, the paint is pumped into the
UNICARBR spray apparatus and mixed with the CO2 at pressure.
Ms. Mclntire inquired whether the UNICARBR System could be considered reasonably
available at this time, even though it seems there is still quite a bit of trial testing ongoing, and
two-component coatings are not expected to be available until 1992. Mr. West stated that it is
currently available for nitrocellulose topcoat and sealer and has been used at Pennsylvania House
for about one year. Mr. West said that Union Carbide has been working on the UNICARBR
System for 4 to 5 years.
Mr. Atkins noted that Pennsylvania House apparently achieves an increased transfer
efficiency with this equipment and asked if Mr. West could explain why. Mr. West responded
that it was unclear why there is increased transfer efficiency, it may be due to more careful
handling by the person doing the coating or it may be inherent to the technology.
Mr. Ralph Hise asked if the UNICARBR System paint is more viscous than conventional
paints when it hits the part. Mr. West replied that it is more viscous.
3. CLASSIC SYSTEMS. INC. PRESENTATION
The presentation on the Classic Systems, Inc., technology was made by:
Mr. David Brookman
Classic Systems, Inc.
Statesville, N.C.
Mr. Brookman provided a description of the Classic Systems CamBoothR, which is a
spray booth using low velocity air curtains to isolate the worker from the spray emissions (see
attached handouts). Traditional spray booths have an open front, so that VOC's and overspray
are lost. To ensure worker exposure safety, high volumes of air are exhausted from the booth.
The volume of makeup air to the booth is usually inadequate, resulting in a negative pressure
within the booth. This pressure differential results in (1) dust entering the booth and degrading
product quality and (2) a cold and drafty work place. There is also a high cost associated with
moving and heating the high volumes of air.
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The goal of the CamBoothR design is to minimize the air volumes being handled, thus
decreasing costs. Attached to the CamBoothR is an enclosed flash tunnel. There are air curtains
at the entrance of the spray booth, the exit of the flash tunnel, and the entrance and exit of the
oven. These curtains prevent VOC emissions from escaping from these areas during the coating
operation. These air curtains use recirculated air. The open side of the CamBoothR where the
workers stand, also has an air curtain of fresh filtered air (no recirculation) delivered at a rate
of about 600 feet/minute. The air curtains located in between the worker and the piece are kept
at a relatively low speed to reduce worker arm fatigue. It is also possible to add a heating
element to the air curtains near the worker in the winter, if desired.
The CamboothR design uses a cascading air system, with exhaust from the oven supplying
the flash tunnel and tunnel exhaust venting to the CamBoothR. Within the CamBoothR, the air
is added from the top of the booth at 50 feet/minute and withdrawn from vents at the bottom.
Mr. Brookman speculated that this uniform, low-velocity downdraft may help to increase
transfer efficiency. The exhaust from the CamBoothR can then be directed to an add-on control,
such as an incinerator. The exhaust from multiple CamBoothsR can be combined and directed
to a single add-on control device.
Studies have been performed by Classic Systems demonstrating that overspray deflecting
off a piece towards the worker is contained by the curtain. Mr. Brookman's presentation
included pictures of studies in which smoke was introduced into the CamBoothR and the exhaust
system removed the smoke before it appeared outside the booth.
Mr. Brookman presented estimated operating costs (electricity, heating, fuel, and
incinerator) for a typical spray booth using 120,000 cubic feet per minute (ftVmin) and a
CamBoothR using 21,000 ft3/min. The total operating costs were about $992,000 for the typical
spray booth and about $145,000 for the CamBoothR. The largest individual difference was in
the fuel cost for the incinerator.
CLASSIC SYSTEMS PRESENTATION DISCUSSION
There were no questions following the Classic Systems presentation.
4. GRACO. INC. PRESENTATION
The Graco presentation on transfer efficiency was made by:
Mr. Steve Kish
Market Development Manager
Graco, Inc.
Mr. Kish presented the results of a study of the transfer efficiencies of different types of
spray guns (see attached handout). Most of the presentation is included in the handout and will
not be repeated here.
Mr. Kish agrees with EPA that there are many factors influencing the transfer efficiency
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of a coating system. The primary factor is operator spray technique (e.g., gun setup, proper
gun position, proper spray speed, fan pattern adjustment, cleaning). However, operator
technique cannot be controlled. Therefore, Graco focused their study on the transfer efficiency
of just the application tool (i.e., the spray gun) rather than the entire system. They tested six
spray guns under controlled conditions and achieved transfer efficiencies ranging from 30 to 75
percent. Only the electrostatic methods achieved transfer efficiencies over 50 percent. They
feel that the standard target used in this study is typical of what is coated by their customers.
While admittedly looking at only part of a complex system, Mr. Kish believes that studies
of relative transfer efficiencies of spray guns can provide valuable information. More efficient
application tools will reduce the amount of paint used to finish a part, thus reducing the VOC
emissions.
GRACO INC. PRESENTATION DISCUSSION
Mr. Taranto asked if Mr. Kish agreed with EPA's decision not to numerically define and
include transfer efficiency in the CTG. Mr. Kish stated that if you are looking at the transfer
efficiency of the total system, as EPA does, then he agrees that it cannot be quantified.
However, it is possible to look at the transfer efficiency of the application tool (i.e., the gun)
alone, as his presentation demonstrated. Mr. Dennison noted that if you isolate and evaluate
each of the parameters, you are not looking at reality, and Mr. Kish agreed with this
observation.
5. ENSR PRESENTATION
The industry-sponsored presentation on the technical aspects of the study being conducted
by the industry group was made by:
Mr. Robert Mclnnes
ENSR Consulting and Engineering
Four trade associations for industries affected by the wood furniture coating CTG formed
a Joint Industries Steering Committee, which sponsored two studies of the cost and economic
impact of possible emission control scenarios. The goal of the Committee and the studies are
to assist in developing a CTG that is environmentally protective, technically feasible,
economically justifiable, and does not restrict the industry. The study is not final yet, but will
be completed shortly. The information in the attached handouts from the presentation will not
be reproduced here. Instead, this discussion will present clarifying and additional statements
made by Mr. Mclnnes.
The wood furniture industry is essentially a "fashion" industry, in that it responds to
consumer demands. In addition, wood is not a uniform substrate, such as metals. Both of these
factors increase the complexity of the manufacturing process and the analysis. A detailed survey
of 160 facilities and site visits to 24 facilities were performed, to develop model plants and
determine the technical feasibility and economic impact of possible control options.
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Technical limitations of many control options that were noted include:
1. Wood is sensitive to heat and water. Therefore, control technologies cannot
simply include changes to waterborne coatings and changes in oven temperature.
2. Full waterborne coatings are not in use for the "long-sequence" segment of the
industry and are not available for some types of coatings. In addition, there are
quality problems.
3. Current coatings and colors have been developed over years of trial and error,
developed specifically for each plant and customer by onsite testing. These
coatings cannot be changed over night. Customers must be provided consistent
quality. There may also be OSHA and insurance questions regarding the use of
this technology.
4. Air recirculation is used only in a very small number of plants and is not
applicable to all industry segments. There may also be OSHA and insurance
questions regarding the use of this technology.
5. Air curtain systems are not commercially available.
6. The UNICARBR System is not commercially available for all coatings, has
technical problems delivering sufficient coating volumes, and requires longer
drying times.
7. Mobile zone spray booths and Terr-Aqua UV/AO oxidation are developing
technologies that are not commercially available.
Twelve model plants were developed to characterize the industry. Ten parameters were
used to define each model plant (see handouts). The cost effectiveness of sixteen control
technologies were evaluated, including add-on controls, different application methods, and
reformulation of coatings (see handouts). Mr. Mclnnes outlined problems with each of these
categories of control technologies (see handouts). The cost analysis was performed for different
numbers of ovens and booths, which significantly affects the cost effectiveness values. The
model plants contained from five to fifteen booths per facility. Capital cost, annual cost, and
cost effectiveness were calculated using OAQPS guidelines.
The capital costs (per plant average for the industry as a whole) varied widely for each
control category: from $400 to $210,000 for spray techniques; from $98,000 to $1,030,000 for
reformulations; and from $163,000 to $1,026,000 per booth for add-on controls (see handouts).
The estimated annual operating costs for each control category ranged from: a cost savings of
$51,000 to expenditures of $470,000 for spray techniques; a cost savings of $163,000 to
expenditures of $1,222,000 for reformulations; and expenditure of from $68,000 to $321,000
per booth for add-on controls (see handouts). The cost savings occurred for only one of the
twelve model plants. The average annual operating cost for the remaining eleven model plants
was over $200,000.
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The VOC emissions reductions achieved for the industry varied widely for each control
alternative, from 2 to 33 percent for improved spray techniques, 28 to 80 percent for coating
reformulations, and 3 to 86 percent for add-on controls (see handouts). The cost effectiveness
values for each control category ranged from: a cost savings of $2,100/ton to expenditures of
$9,400/ton for spray techniques; a cost savings of $500/ton to expenditures of $15,800/ton for
reformulations; and expenditures of $1,300 to $87,300/ton for add-on controls (see handouts).
Mr. Mclnnes concluded his presentation with a discussion of several industry concerns
other than cost. First, the industry recommends that the units of the standard not be in terms
of pounds of VOC per gallon of coating minus water. The trend is towards using water in
coatings, and if water is deleted from the calculation, there will still be high VOC levels. Use
of this format does not show the actual VOC reductions achieved by using waterborne coatings.
Second, because the wood furniture industry is so technically and economically diverse, there
should be different standards for different industry segments. Finally, Mr. Mclnnes made the
strong recommendation that, if the CTG includes the use of some of the emerging technologies
(e.g., full waterborne coatings), EPA needs to allow sufficient time for research and
development of these technologies in the CTG.
6. NERA PRESENTATION
The industry-sponsored presentation on economic impacts of the CTG was made by:
Dr. Mark Berkman
National Economic Research Associates
The second study sponsored by the Joint Industries Steering Committee was an evaluation
of the economic impact of possible CTG control options on the wood furniture industry. The
Committee decided to conduct a study of the total industry impacts and to assume that the goal
of EPA is to reduce VOC emissions in nonattainment areas at the lowest possible industry cost.
This summary of the presentation will not include a repetition of the handouts, which are
attached. Instead, statements made by Dr. Berkman to clarify and expand on the handouts will
be discussed.
The study looked at total annual operating costs, plant closures, and employment losses.
These economic factors were studied as a function of increasing percent VOC emissions
reduction, from 10 to 80 percent. Over this range of VOC control, total annual cost ranged
from $53 to 543 million (see handout for details).
The projected plant closures for this range of VOC closures ranged from 930 to 2,539
(see handouts for details). However, the economic analysis is not complete, and Dr. Berkman
stated that the plant closure estimates will likely increase in the final report. The closings will
primarily occur among the smaller facilities.
The number of jobs lost over the range of VOC reductions was 5,283 to 86,534 (see
handouts for details). The largest number of job losses represents about 30 percent of the total
employment in this industry. The largest facilities in the wood furniture industry will probably
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not close as a result of a CTG but there would be sizeable employment losses.
Dr. Berkman then presented a discussion of the cost of control to this industry relative
to its VOC emissions. First, the wood furniture coatings contribute less than 1 percent of the
VOC emissions in the U.S.. Second, the average cost effectiveness values for the wood
furniture industry is about $3,000/ton. Dr. Berkman presented the results of a study by the
Office of Technology Assessment demonstrating that there are numerous other industries with
cost effectiveness values at or below $2,000/ton. This is not to suggest that the wood furniture
industry should not be controlled but rather that it is not a major contributor of VOC emissions
and should be controlled proportionately to its emissions.
The study determined that there is a wide range of cost effectiveness values for each
control option for the different model plants. The lowest cost of attaining a 30 percent VOC
reduction ranges from a slight profit to about $15,000/ton for seven of the model plants. For
these reasons, Dr. Berkman suggested that EPA consider the cost impacts of the different
segments of the industry separately.
The NERA study also analyzed the effect of different VOC control options on
profitability for each of the model plants (see handouts for details). The cost of VOC control
is difficult to pass along to the customers and, therefore, the CTG would significantly impact
profitability. The model plants included as part of their initial analysis happened to all be part
of the upper profit quartile. Therefore, to further analyze the impact of decreased profitability,
they are adjusting their analysis to include smaller, less profitable model plants.
The study further analyzed the annual failure rate in this industry in the absence of any
regulations. For the period 1986 to 1990, the failure rate of the wood furniture industry
outstripped the nationwide failure rate for all other industries combined (see handouts for
details). In part, this is due to substantial and growing foreign competition, which increased
from a value of about $1 billion in 1981 to almost $4 billion in 1990. The impact of the CTG
will be to increase the competitive advantage of foreign imports.
The study also evaluated the impact of the capital cost of the different levels of VOC
control. If a plant is able to stay in business following the implementation of the CTG, the cost
of the control will limit the ability to upgrade, modernize, and expand the facility. This
limitation will further decrease the competitiveness of this industry.
Dr. Berkman concluded with two recommendations to EPA in the development of the
CTG. First, this industry appears to be a prime candidate for a market-based approach to
regulation. Second, EPA must review and regulate the industry in the context of its contribution
to total nationwide VOC emissions.
ENSR/NERA PRESENTATION DISCUSSION
Mr. Taranto asked if the projections on plant closures and job losses are for all of the
industry or only the facilities in nonattainment areas. Dr. Berkman replied that the study
854
-------
assumed all plants will be affected by the CTG. They are continuing their analysis and plan to
analyze the impacts on only those plants in nonattainment areas. Dr. Berkman hypothesized that
although the closures and job losses may be decreased when only facilities in nonattainment
areas are considered, the decrease may be offset by (1) increased closures in nonattainment areas
because those facilities would be at an economic disadvantage compared to those in attainment
areas and (2) the increased stringency of some of the financial tests NERA plans to utilize.
Ms. Mclntire asked whether the NERA study had included an analysis of the impact of
the application of MACT to plants emitting over 10 tons/year in attainment areas, to determine
whether facilities in attainment areas would have a cost advantage. Dr. Berkman replied that
this has not been explicitly addressed but that their analysis considers to some extent a combined
RACT/MACT.
Ms. Mclntire asked why, in the NERA analysis, the use of full waterborne coatings and
ultraviolet (UV)-cured coatings does not eliminate VOC emissions. According to Mr. Mclnnes,
these coatings still contain some amount of VOC. In addition, there is no UV-cured stain.
Therefore, only about 65 to 70 percent VOC emissions reduction is achieved using these coating
technologies.
Mr. Dennison asked why UV air oxidation was considered an emerging technology in
the ENSR study when this technology is an accepted technology in the aerospace industry. Mr.
Mclnnes responded that he was unaware of its use in the aerospace industry. Their classification
of UV air oxidation as an emerging technology was based on the fact that it has not been
demonstrated long term in the wood furniture coating industry; it is currently in use in only one
wood furniture facility.
Mr. Dennison asked whether the NERA analysis had considered what would happen
regarding plant closures in the absence of any regulation, whether this industry is currently
economically viable. According to Dr. Berkman, the NERA analysis addresses this issue in part
because it includes analysis of current economic conditions and other factors beside the CTG.
Dr. Berkman agreed that the industry has been undergoing contraction and consolidation and that
a number of existing companies are operating in a negative financial status. However, the
regulations will exacerbate the problems and confirm the closure of currently marginal facilities.
The final report will have benchmark closure projections as well as demonstrate the additional
effect of the CTG on plant closures.
Mr. Dennison further noted that, while VOC emissions from wood furniture coating may
be a small percentage of the nationwide VOC emissions, the more important factor to consider
is the industry's percent VOC contribution in only nonattainment areas. Dr. Berkman concurred
that if you look only at nonattainment areas, the percent VOC contribution of this industry may
increase somewhat. However, Dr. Berkman said that the cost to this industry may not be
proportional to the level of VOC emission reduction achieved relative to other industries. He
also indicated that the stringency of a standard should be proportional to its contribution and
economic impact.
Mr. Pinkerton asked the EPA staff how economic factors will affect the MACT decisions
855
-------
for the NESHAP. Ms. Wyatt responded that an economic analysis will be performed for control
options above the MACT floor and the results will be used in selecting options for MACT.
Ms. Mclntire asked if the NERA analysis was new to EPA. Ms. Wyatt stated that EPA
knew an analysis was being performed but had not seen any of the results prior to the
NAPCTAC presentation.
Mr. O'Sullivan asked what the current dollar value of U.S. sales is for this industry. Dr.
Berkman responded that their study does not directly have this information but that there were
about $4 million in foreign sales in 1990, which is about 15 percent of total U.S. sales.
Mr. O'Sullivan further inquired whether the NERA analysis assumed control of all of the
spray booths at a facility. Mr. O'Sullivan recommended to EPA that they look at this type of
incremental analysis to develop cutoffs on what types of control technologies should be required
for each type of facility. Dr. Berkman explained that the NERA study looked at varying levels
of control at a facility, from 10 percent to over 80 percent. If add-on control was the least cost
option for a particular control level, that was the cost used to calculate cost effectiveness. These
different levels of control could be achieved by incrementally controlling different numbers of
spray booths. Mr. Berkman said that this will be made clear in the final report.
Mr. O'Sullivan stated that, from the NERA study, it looked as if there were some clear
decision points for EPA to control at about the 25, 50, and 75 percent control levels. He asked
if industry had any recommendations. Dr. Berkman responded that they did not have
recommendations at this time. When the report is final, which should be soon, the industry
plans to work with EPA to analyze the study results.
Mr. O'Sullivan asked how it can be feasible to get promising control technologies
demonstrated in an industry that is essentially uncontrolled. Mr. McGinnis responded that the
industry is currently trying to use waterborne coatings on several lines. The industry is always
looking for better and less expensive technologies. Mr. O'Sullivan noted that the state
implementation plans (SIPs) must have a contingency plan in case the state fails to meet its
emission reduction goals within a specified time. If the goals are not met, it triggers the
requirement for add-on controls. It may be possible to use the "hammer" provisions to provide
incentive to this industry to try new technologies. He asked how long it takes to make a new
technology commercially viable. Mr. Mclnnes estimated that it takes 2 to 4 years to test and
implement new approaches.
Mr. O'Sullivan asked what NERA would recommend as a cost effectiveness cutoff. Mr.
Mclnnes declined to make a recommendation. He noted that the model plants reflect a wide
range of cost effectiveness values, and that the total amount of VOC emitted from a spray booth
is the primary cost factor. Booths are fairly standard in size, and the speed of production is a
key factor, influencing how much VOC is emitted, and thus, the associated cost effectiveness
of add-on controls. Mr. O'Sullivan asked if the NERA report included the incremental cost for
adding add-on controls to a spray booth, to which Mr. Mclnnes replied in the affirmative.
Mr. O'Sullivan asked if EPA had any policy or thoughts on the issue that had been raised
856
-------
several times regarding adjusting the VOC limits to subtract out water. Mr. Berry responded
that this was a complex issue and that EPA was aware of it. Mr. Berry said that there is some
problem with very low solids coatings; however, some parties tend to stretch this anomaly over
the full gamut of waterborne coatings, which is not appropriate. Mr. Berry said that EPA will
be giving this issue further consideration in the development of the CTG.
Mr. Pinkerton asked if industry has any concerns regarding the two on-going regulatory
tracks (i.e.., development of RACT and MACT). Mr. Mclnnes responded that industry
definitely would like to see the two developed in parallel, to avoid the problems of multiple and
differing standards. Mr. Pinkerton concurred that this would be his very strong
recommendation.
Mr. Jordan said that he was intrigued by the market-based controls concept briefly
discussed in the industry presentation, and indicated a desire to further discuss this concept in
the future. Mr. Jordan asked when the NERA study would be completed. Industry responded
that they expect the study to be finished by the end of the year.
7. MQBAY CORPORATION PRESENTATION
The Mobay presentation on polyester and polyurethane coatings (which is attached) was
made by:
Mr. John Williams
Director, Technical Marketing
Mobay Corp.
Mobay supplies aliphatic and aromatic polyisocyanate resins for use in polyurethane
coatings. These coatings provide greatly improved performance (e.g., alcohol and mar
resistance), which will help with foreign competition. The CTG document contains a value of
about 3.4 Ib VOC/gallon for polyurethane coatings and, while this is technically achievable, it
is outside the typical values. There are two-component solventborne polyurethane coatings for
clear topcoats that contain 4.6 to 5.5 Ib VOC/gallon. This represents about a 23 percent
reduction from nitrocellulose coatings. In addition, the high film build results in a reduced
number of coating applications. The drawbacks to polyurethane coatings are the need for (1)
a dust-free coating environment and (2) worker training in the use of the two-component
equipment.
Non-air inhibited unsaturated polyester coatings are high-gloss, high-build systems. Clear
topcoats and sealers are commercially available and contain about 1.5 Ib VOC/gallon. Use of
polyester coatings achieves about 40 to 75 percent VOC reduction for air dry and 88 to 97
percent reduction for ultraviolet (uv)-cure. Overseas furniture manufacturers are using these
coatings because of the improved performance. Development is continuing on other coatings.
Work is ongoing to develop a two-component waterborne polyurethane topcoat and sealer
containing about 0.9 Ib VOC/gallon. It should be commercially available in 1 to 2 years.
857
-------
Customers have expressed some concern about worker health and safety because of the
polyisocyanates in these coatings. Mobay has conducted extensive monitoring in plants using
polyisocyanates and has found no problems.
Both the polyurethane and polyester coatings are to some extent limited to certain
segments of the wood furniture industry. Mobay supports the use of low-VOC technologies, but
only when combined with improved performance because of the need to increase competitiveness
of U.S. products.
Mobay supplies raw materials to coating manufacturers, but works closely with the
coating suppliers and the coating buyers, such as wood furniture manufacturers, to ensure the
end product satisfies all parties. Mobay would like to work with EPA, a coating supplier, and
a wood furniture facility to install and use these new technologies on a demonstration basis.
Mr. James Berry, ESD/EPA, concluded this session by noting that the wood furniture
industry has used nitrocellulose coatings for a long time. Polyurethane and polyester coatings
are relatively new to the wood furniture industry. However, he suggested that industry
representatives look closely at this technology. Mr. Berry said that looking at all paint systems
being used everywhere on every conceivable end-product, polyester/polyurethane coatings are
generally accepted as the premier coatings for durability, color retention, etc., and may be able
to achieve large VOC emissions reductions at a reasonable cost. Wood furniture coating is the
largest uncontrolled single-industry VOC source remaining, and EPA cannot just ignore these
emissions.
MQBAY PRESENTATION DISCUSSION
Mr. Atkins inquired about possible health problems associated with using isocyanates. Mr.
Williams responded that coatings with isocyanates can be used safely. He said that all coatings
have some type of hazard, and general safe handling procedures are sufficient to protect workers
from isocyanates.
Mr. Atkins also asked if there are special costs associated with the use and monitoring
of a polyester or polyurethane coating system. Mr. Williams acknowledged that the two-
component coating system requires two coating pots and a special spray gun. He noted,
however, that the equipment is commonly available and used extensively by the military.
Ms. Mclntire asked if the toxicity of the two-component coatings is higher than that of
solvents used in conventional coatings. Ms. Mclntire said that after the permit program and
MACT standards are in place, it will be difficult to switch to more toxic coatings. Mr. Atkins
replied that the solvents used in the two-component coatings are similar to those in conventional
coatings.
Ms. Mclntire noted that RACT should genuinely be reasonably available. There are a
number of developing control technologies for the wood furniture coating industry. While it
may not be within the realm of the CTG process, the Clean Air Act Amendments clearly contain
mechanisms for encouraging switching to new technologies that probably are related to the
-------
economic incentive programs. Incentives that might be offered are extended compliance times,
grants, and issuance of general permits during initial startup phase.
Mr. Jordan read one question from the audience, which stated that there is at least one
dip tank in use in the industry and asked if EPA would require controls on such an activity. Mr.
Berry responded that it would depend in part on the VOC content of the coatings and suggested
that the questioner talk to Mr. Berry after the meeting about the specifics of the situation. Mr.
Jordan also read a comment from the audience, strongly recommending that any size cutoffs be
made in terms of tons/year of VOC, not number of employees, since some companies
subcontract coating of parts and only assemble the finished parts.
The session concluded with one question from the audience, stating that the Joint
Industries Steering Committee was unaware of the new waterborne polyester coating discussed
in the Mobay presentation, or Mobay's offer to work with a plant to develop a system and
wondered why EPA had not informed the Committee prior to NAPCTAC. Mr. Berry responded
that he had informed Mr. Buck Deal of Bernhardt (a member of the Joint Committee)
immediately after hearing the Mobay information. Mr. Deal responded that given the timeframe
of this notice (a few weeks before NAPCTAC), he did not feel that the Mobay presentation was
appropriate for the NAPCTAC meeting.
859
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CONTROL TECHNIQUES GUIDELINE
CONTROL OF VOC EMISSIONS FROM
WOOD FURNITURE COATING OPERATIONS
CO
-------
CD
CT5
INTRODUCTION
BACKGROUND
• OVERVIEW OF WOOD FURNITURE INDUSTRY
• EMISSION SOURCES
REGULATORY ANALYSIS
• MODEL PLANTS
• CONTROL ALTERNATIVES
• RACT OPTIONS
• IMPACTS
-------
INDUSTRIES EVALUATED BY THE ANALYSIS
SIC CODE INDUSTRY
RESIDENTIAL
2511 WOOD HOUSEHOLD FURNITURE, EXCEPT UPHOLSTERED
2512
2519
to
2517
WOOD HOUSEHOLD FURNITURE, UPHOLSTERED
HOUSEHOLD FURNITURE, NOT ELSEWHERE CLASSIFIED
CABINETS
2434 WOOD KITCHEN CABINETS
WOOD TELEVISION, RADIOS, PHONOGRAPH, AND SEWING MACHINE
CABINETS
OFFICE
2521
WOOD OFFICE FURNITURE
INSTITUTIONAL
2531 PUBLIC BUILDING AND RELATED FURNITURE
FIXTURES
2541 WOOD OFFICE AND STORE FIXTURES, PARTITIONS, SHELVING, AND
LOCKERS
-------
DISTRIBUTION OF FACILITIES
BY INDUSTRY SEGMENT
APPROXIMATELY 11,000 FACILITIES TOTAL
FIXTURES (17%)
CO
INSTITUTIONAL (5%)
OFFICE (6%)
CABINETS (34%)
RESID. FURN. (37%)
-------
DISTRIBUTION OF FACILITIES BY SIZE
CD
LARGE (3%)
MEDIUM (5%)
small 1 -99 employees
medium 100-249 employees
large >249 employees
SMALL (92%)
-------
SMALL 1-99 EMPLOYEES
MEDIUM 100-249 EMPLOYEES
LARGE >249 EMPLOYEES
CD
O3
CJ1
LARGE (32%)
SMALL (39%)
MEDIUM (28%)
-------
FINISHING SCHEMATIC
CD
Coating
Application
Oven
Coating
Application
Finishing Operations ~ 94% total VOC emissions
Cleanup Operations - 6% total VOC emissions
-------
REGULATORY ANALYSIS
ONCE THE INDUSTRY AND FINISHING PROCESS WERE CHARACTERIZED,
THE REGULATORY ANALYSIS WAS CONDUCTED, CONSISTING OF:
• DEVELOPMENT OF MODEL PLANTS
• EVALUATION OF VOC CONTROL ALTERNATIVES
• DEVELOPMENT OF RACT OPTIONS
• IMPACT ANALYSIS
-------
MODEL PLANTS
Residential Furn.
CD
en
I medium} [ large [ j email | [medium | | large
medium I I large
Small 50 TRY
Medium 225 TRY
Large 500 TRY
-------
FINISHING SEQUENCES
OFFICE/CABINET RESID. FURN. (SHORT)
STAIN STAIN
STAIN
SEALER
TOPCOAT
STAIN
WASHCOAT
SEALER
TOPCOAT
TOPCOAT
RESID. FURN. (LONG)
STAIN
STAIN
STAIN
WASHCOAT
FILLER
WIPING STAIN/GLAZE
SEALER
TOPCOAT
HIGHLIGHT
TOPCOAT
HIGHLIGHT
TOPCOAT
-------
RELATIVE VOC EMISSIONS-FINISHING STEPS
(PERCENT)
TOPCOAT
HIGHLIGHT
SEALER
o
WIPING S./GLAZE
FILLER
WASHCOAT
STAIN
NOTE:
HIGHLIGHT,
WIPING S.,
& FILLER
USED ONLY
IN LONG
SEQUENCE.
0
10 15 20 25 30 35 40
-------
PARAMETERS CONSIDERED DURING
CONTROL METHOD EVALUATION
CONTROL TECHNIQUES AVAILABLE
TYPES OF COATINGS PRESENTLY USED
FINISHING SEQUENCE / INDUSTRY SEGMENT
TOTAL VOC EMISSIONS AND CONCENTRATION
NUMBER AND TYPES OF VOC'S PRESENT IN EXHAUST
EXHAUST FLOWRATE TO BE CONTROLLED
-------
CONTROL ALTERNATIVES FOR THE
FINISHING PROCESS
LOWER-VOC COATINGS
• ADD-ON CONTROLS
S3
«vj
10 • RECUPERATIVE THERMAL INCINERATION
• REGENERATIVE THERMAL INCINERATION
• CATALYTIC INCINERATION
• COMBINED ADSORPTION/THERMAL INCINERATION
COMBINATION OF LOWER-VOC COATINGS AND ADD-ON CONTROLS
EXHAUST FLOW REDUCTION IS ESSENTIAL FOR ADD-ON CONTROLS
• RECIRCULATION
• AIR CURTAIN SYSTEM
-------
CONTROL ALTERNATIVES FOR
CLEANUP OPERATIONS
WORK PRACTICE MODIFICATIONS TO MINIMIZE EVAPORATION
REFORMULATION OF CLEANUP MATERIALS
ADD-ON CONTROLS
ANALYSIS NOT COMPLETE
-------
DEVELOPMENT OF RACT OPTIONS
• CONTROL ALTERNATIVES EVALUATED FOR EACH MODEL PLANT
• PERMUTATIONS OF DIFFERENT CONTROLS BEING APPLIED TO THE
MODEL PLANTS WERE DEVELOPED TO FORM THE RACT OPTIONS
eo
^ • UNDER A SINGLE RACT OPTION, DIFFERENT CONTROLS MAY BE
APPLIED TO DIFFERENT MODEL PLANTS
• THUS, RACT OPTION DESCRIPTORS DO NOT NECESSARILY INDICATE
THE CONTROL STRATEGY APPLIED TO ALL MODEL PLANTS
-------
RACT OPTIONS
1. FULL WATERBORNE
2. HYBRID WATERBORNE
3. POLYESTER/POL YURETHANE
5 4. POLYESTER/POLYURETHANE WITH WATERBORNE
CJl
5. HYBRID WATERBORNE AND ADD-ON CONTROLS ON SELECTED STEPS
6-9 ADD-ON CONTROLS FOR ALL COATING STEPS
• WITHOUT RECIRCULATION
• WITH RECIRCULATION
• WITH AIR CURTAIN SYSTEM
-------
RACT OPTION 1
FULL WATERBORNE
O/C & RESIDENTIAL SHORT - FULL WATERBORNE
RESIDENTIAL LONG - HYBRID WATERBORNE
-------
RACT OPTION 2
HYBRID WATERBORNE
S • WATERBORNE SEALER, TOPCOAT, AND HIGHLIGHT (AS
-J
APPLICABLE) FOR ALL PLANTS
CONVENTIONAL SOLVENTBORNE FOR ALL OTHER STEPS
-------
RACT OPTION 3
POLYESTER/POLYURETHANE
• SMALL PLANTS USE HYBRID WATERBORNE
CD
• POLYESTER/POLYURETHANE SEALER, TOPCOAT, AND FILLER
(AS APPLICABLE) FOR ALL MEDIUM AND LARGE PLANTS
• CONVENTIONAL SOLVENTBORNE FOR ALL OTHER STEPS
-------
CD
RACT OPTION 4
POLYESTER/POLYURETHANE WITH WATERBORNE
• SAME AS OPTION 3 EXCEPT:
• O/C & RESIDENTIAL SHORT - WATERBORNE STAIN AND
WASHCOAT (AS APPLICABLE)
• RESIDENTIAL LONG - WATERBORNE HIGHLIGHT, REST
CONVENTIONAL SOLVENTBORNE
-------
RACT OPTION 5
HYBRID WATERBORNE & ADD-ON CONTROLS ON SELECTED STEPS
©3
CD
• HYBRID WATERBORNE COATING SYSTEMS (AS DESCRIBED
PREVIOUSLY) FOR ALL PLANTS
• ADD-ON CONTROLS USED ON STAIN OR STAIN AND WASHCOAT
OPERATIONS AT ALL FACILITIES WITH MORE THAN 50 EMPLOYEES
-------
RACT OPTIONS 6-9
ADD-ON CONTROLS FOR ALL COATING STEPS
• ALL FACILITIES WITH FEWER THAN 50 EMPLOYEES EXEMPT
S3
2 • FOR EACH RACT OPTION, ADD-ON CONTROLS EVALUATED:
r*=* '
• WITHOUT RECIRCULATION OR AIR CURTAIN SYSTEM
• WITH RECIRCULATION
• WITH AIR CURTAIN SYSTEM
-------
NATIONWIDE IMPACTS
FACILITIES IN OZONE NONATTAINMENT AREAS
€0
CO
RACT OPTION DESCRIPTION
1 FULL WATERBORNE
2 HYBRID WATERBORNE
3 POLYESTER/POLYURETHANE
4 POLYESTER/POLYURETHANE
HYBRID
5 HYBRID WATERBORNE & ADD-ON
6-9 ADD-ON CONTROLS
W/OUT RECIRCULATION
W/RECIRCULATION
W/AIR CURTAIN SYSTEM
NATIONWIDE
VOC EMISSION
REDUCTION
(1000 Mg/YR)
94.8
73.4
69.9
80.9
91.2
64.2
64.2
66.1
72
56
53
61
69
49
49
50
NATIONWIDE
ANNUAL
CONTROL COST
(MM$)
229
147
264
260
347
331-418
244-293
181-211
AVERAGE
COST
EFFECTIVENESS
($/Mg)
2400
2000
3800
3200
3800
5200-6500
3800-4600
2800-3200
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11/15/91
1-HTW
UNICRRB SYSTEM®
NttPCTHC MEETING
NOUEMBER 21, 1991
o .
-------
LDHflT IS THE UNICRRR® SYSTEM?
THE UNICflRB® SYSTEM IS fl
POLLUTION PREUENTION TECHNOLOGY
FOR THE RPPLICflTION OF SPRRY
RPPLIED INDUSTRIRL CORTINGS
11/15/91
2-HTW 084
-------
HOW DOES THE UNICRRB® SYSTEM
WORK?
THE UNICARB® SYSTEM SUBSTITUTES
CARBON DIOXIDE FOR A SIGNIFICANT
AMOUNT OF SOLVENTS IN CONVENTIONAL
SPRAY APPLIED COATINGS, THEREBY
REDUCING VOC'S AND AIR TOXICS.
UNICARB® COATINGS ARE HIGH IN
SOLIDS, AND CAN BE APPLIED MANUALLY,
AUTOMATICALLY, ELECTROSTATICALLY,
NON-ELECTROSTATICALLY WITH AIRLESS
OR AIR-ASSISTED AIRLESS TYPE SPRAY
GUNS.
11/15/91
3-HTW J385
-------
WHERE IS THE UNICRRB® SYSTEM
flPPLICRBLE IN THE WOOD FURNITURE
INDUSTRY?
NITROCELLULOSE TOPCORTS RND
SERLERS
FOR: RESIDENTIRL FURNITURE
CRRINETS
OFFICE/INSTITUTIONRL
PIGMENTED LRCQUERS RND ENRMELS
SINGLE COMPONENT RCRVLICS,
POLYESTERS RND URETHRNES
2 COMPONENT EQUIPMENT RND
CORTINGS RRE CURRENTLY IN THE
DEUELOPMENTRL STRGE RND SHOULD
BE RURILRBLE IN 1992 FOR IN-
PLRNT TESTING
11/15/91
4-HTW
-------
HOW MUCH CAN THE UNICARB® SYSTEM
REDUCE VOC'S?
• FOR NITROCELLULOSE SERLER flND
TOPCORT RPPLICRTIONS 60%-75%
• FOR THE MODEL PLRNTS LISTED IN
TRDLE 4-4 OF THE CTG DRRFT, THE
TOTRL FINISHING LINE UOC
EMISSIONS WOULD BE REDUCED BV:
FINISHING LINES UOC'S RIR TOHICS
LONG FINISHING LINES 37% 50%
SHORT FINISHING LINES 44% 60%
OFFICE/CABINET 44% 50%
THIS RSSUMES THE UNICRRB® SYSTEM
IS USED FOR BOTH NITROCELLULOSE
SERLER RND TOPCORT RPPLICRTIONS
RT R 65% REDUCTION OF UOC'S
(4.7LB/GRL), RND RIR TOHICS
REDUCTION OF 857.
• UNICRRB® SYSTEM NITROCELLULOSE
CORTINGS HRUE BEEN FORMULRTED
UJITH.R 90% REDUCTION IN RIR
TOHICS
11/15/91
5-HTW
G81
-------
IS THE UNICARB® SYSTEM BEING USED
COMMERCIALLY?
THE SYSTEM HflS BEEN INSTflLLED
RND IS OPERRTING COMMERCIRLLV
RT PENNSVLURNIR HOUSE
fi SUCCESSFUL DEMONSTRRTION OF
THE SYSTEM UJRS CONDUCTED RT
LEHIGH
SEUERRL OTHER FURNITURE
MRNUFRCTURERS RRE CURRENTLY
CONDUCTING IN-PLRNT TRIRLS IN
UlRGINIfl, MISSISSIPPI, CRLIFORNIR
RND RRIZONR
TRIRLS RRE BEING CONDUCTED IN
SEUERRL OTHER INDUSTRIES
INCLUDING: RUTOMOTIUE OEM,
RUTOMOTIUE COMPONENT, PLRSTIC
CRBINETS RND PLRSTIC RUTOMOTIUE
COMPONENTS
11/15/91
6-HTW
O O i
-------
unlCRRB® SVSTEM
ADVANTAGES FOR SEALER AND TOPCOAT
APPLICATIONS
1) CONTINUED USE OF NITROCELLULOSE
CORTINGS
2) REDUCED UOC'S...65%-75% FOR SERLERS UNO
TOPCORTS
3) REDUCED RIR TOHICS...80%-90%
4) EflSY TO RETROFIT
5) RELRTIUELV LOW CRPITRL INUESTMENT
6) HIGHER FILM BUILD
7) POSSIBLE COST SRUIN6S WHERE MULTIPLE
SERLERS OR TOPCORTS RRE RPPLIED
8) COMPLIMENTRRV TO OTHER CORTIN6 SYSTEMS
9) MOUES SOLUENT EMISSIONS FROM BOOTH TO
OUEN
10) POLLUTION PREUENTION TECHNOLOGY
11/15/91
7-HTW
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i/M
090
P.O. Box 6130 • Buffalo Shoals Rd. • Statesville, N.C. 28677 • Tel 704-878-9523/Fax 704-878-2914
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November 21, 1991
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
"Finishing Systems for Wood Furniture"
- Emerging Technology -
I. Int roduct i on
Classic Systems, Inc. - Turnkey Contractor -
primarily furniture industry
A. Involvement in new technology for
control 1 ing VOC em i s s i o n s
B. CamBooth - unique use of low velocity,
push-pull air curtains to isolate operator
from unhealthy work environment and greatly
reduce exhaust air
II. Background for Development -
analysis of typical problems and complaints:
A. Inadequate capture of fumes and over-
spray in typical open front spray booths
B. Inadequate make-up air
1. Negative pressure in finishing room -
infiltration of dust degrades quality
of end product
2. Cold and drafty work place in winter
3. High operating costs
C. Pending VOC reduction requirements - high initial
and operating costs with present large volume
exhaust system
Conclusion: Most problems could be resolved by greatly
reducing the amount of exhausted air from
the work space
esi
-------
III. Review Transparencies
A. Typical System - individual exhaust for oven,
flash tunnel and spray booths (open ends)
B. CamBooth System - one exhaust for all segments
(closed ends)
C. Views (front, plan and end)
D. Air flow patterns
E. Finishing Room - Typical
1. Exhaus t fan unit
2. Diverter dampers
3. VOC system tie-in
F. Energy cost comparisons (basic benefits)
IV. Slides
A. Various views
B. Airflow patterns
1. Fron t a i r cur ta i n
2. End air curtain
3. Internal down draft
C. Demonstrate how worker is protected from
internal environmental
V- Questions and answers
G:
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OVENOHAUST
Q)
FUSH TUK1DHAUST
SMATBOOTH DWAUST
CONVENTIONAL FINISHING SYSTEM LAYOUT
O
OWN EXHAUST ROUTED TO FlAffl TIMCL
OVEN EXT
AIR CURTAH i.
Lc.-;:;
JJU
BOOTH OOW-ORAn FAN -i
PU1MC ARFRCH FLASH XMC1 1
FLAW TUML
AD OJRTAM
OVENNIT
ABCURTAW
NEW CAMBOOTH RNISHING SYSTEM LAYOUT
CLASSIC SYSTEMS. INC.
P.O. BOX «iao
STATESVILLE. NORTH CAROUNA 28677
1CLSPHONE TO4-«7B-eS23
-------
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CLASSIC^SYSTEMS. ma
STATESV1LLE, KORn? CAROLINA 88*77
-------
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BOOTH INLET AIR CURTAIN
CLASSIC SYSTEMS. INC.
STATESVOLE, NORTH CAROLINA Start
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-------
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BOOTH INLET
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• WATERPAN OR DRY MEDIA FILTER SYSTEM
END ELEVATION AT SPRAYBOOTH
CLASSIC SYSTEMS, INC.
STATESVILLE. NORTI? CAROLINA 28077
-------
CO
AIR CURTAIN
FAN AND
FILTER
AIR PLENUM
FILTERS FOR OOWNORAFT AIR
WATERPAN FILTER SYSTEM
AIR CURTAIN
FAN AND
FILTER
AIR PLENUM
FILTERS FOR DOWNORAFT AIR
CART
DRY MEDIA FILTER SYSTEM
AIR CURTAIN AT 600 FPM
•«=- DOWNDRAFT AIR AT 50 FPM
> FINISHING SPRAY FROM SPRAY GUN
INTERIOR VIEW OF FLOW PATTERN
•FILTER
CLASSIC SYSTEMS, INC.
STATESVUIZ mem CAROLINA eaerr
-------
OVEN
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UNLOAD
LOAD
TYPICAL FINISHING SYSTEM
CLASSIC SYSTEMS, INC.
STATESVILLE. NClRTlf CAROLINA
-------
BOOTH EXHAUST
BOOTH EXHAUST
REMOVABLE
BALANCING
DAMPER
CO
c z
ACCESS DOORS
SPRAYBOOTH ROOF
REMOVABLE
SPCOL SECTION
SPRAYBOOTH EXHAUST FAN
SPRAYBOOTH ROOF
CLASSIC SYSTEMS, INC,
STATB3VILLE, NORTH CAROLINA 20077
-------
EXHAUST TO ATMOSPHERE (CLOSED)
EXHAUST TO ATMOSPHERE (OPEN)
TO INCINERATOR (OPEN)
TO INCINERATOR (CLOSED)
ROOF
FROM
SPRAYBOOTH
FROM
SPRAYBOOTH
SPRAYBOOTH EXHAUST DIVERTER VALVE
CLASSIC SYSTEMS. INC.
STATESVIUK NORTH CAROLINA 2MT7
-------
STACK
I BLOWER
_rw
INCINERATOR \-ABQRT DAMPER
VOC INCINERATION SYSTEM
-O
CLASSIC SYSTEMS, INC.
PA KB (00
STATGSVniK. NORTH CAROUNA 28877
-------
•NIRQY COST EVALUATION
1900.000
35
30
25
20
15
10 -
ANNUAL
OPERATING
COST IN
THOUSANDS
OF DOLLARS
130.000
^/Vy/Vy
$22,000
5 -
$3,000
$8,000
1125.000
MAKE-UP AIR
HP
SPRAYBOOTH
HP
FUEL FOR MAKE-UP AIR
GAS
STEAM
BASIC ASSUMPTION: A. (6) EACH CONVENTIONAL SPRAYBOOTH SYSTEM = 120.000 CFM
(6) EACH CAMBOOTH SYSTEM = 21.000 CFM
B. HEATING COST - 1 SHIR, 6 DAYS/WEEK, 18 WEKS/YEAR, AND AVERAGE SOT
TEMPERATURE RISE: GAS 0 $5/MBTU PER HOUR
STEAM 0 $4/1OOOJ PER HOUR
C. HORSEPOWER COST 6 $300 PER HP/YR
D. THERMAL OHDIZER - WITH HEAT RECOVERY. VOC FUEL VALVE INCLUDED. 2600 ANNUAL
OPERATING HOURS
VOC INCINERATION
FUEL - GAS
CONVENTIONAL SPRAYBOOTH SYSTEM
CAMBOOTH SYSTEM
CLASSIC SYSTEMS. INC.
STATESVIUE. NORTH1 CAROLINA 28*77
-------
Saves Energy & Materials
80% Reduction in CFM
Requirements*
• reduces energy costs
• substantially less airflow to
exhaust control devices
• increases transfer efficiency
of spray gun
•Compared to typical conventional
designs.
Better Quality Production
Reduced Airflow Allows:
• better operator control of
coatings applications
• greatly enhanced dust free
environment for cleaner finish
AIR CURTAIN
Safer Operation
Helps Meet New EPA and
OSHA Standards by:
• limiting operator exposure to
VOC vapors
• lower decibel levels
CAMBOOTH Specfications
BASIC DESIGN:
down-draft with dry filters, air
curtains at operator station and
all entry and exit points.
DIMENSIONS:
Based on product size and
finishing schedule.
EXHAUST RATE:
3000 scfm per 20' booth.
HORSEPOWER:
3 HP per 20'booth.
The CAMBOOTH is
Adaptable*
• can be installed in present
booth location
• works with overhead or pallet-
type conveyor line
• can be equipped with the
following options:
— Flash Tunnel
— Drying Oven
— Catalytic or Thermal
Oxidizer
— Carbon Absorption Filter
Module
• can be supplied as water-
wash booth
*MODEL AVAILABLE FOR INSPECTION
AND PRODUCT TESTING
EXHAUST FAN
General Office
Buffalo Shoals Road
P.O. Box 6130
Statesville, N.C. 28677
TEL: 800-362-5003
FAX: 704/878-2914
DRY FILTER MEDIA
OR WATER FILTER SECTION
SPRAY BOOTH-
AIR CURTAIN
IT-.
-------
Introducing The All New
GVMBOOIH
CLASSIC SYSTEMS, INC.
Increased Efficiency In The
Manufacturing Environment
Now in our fifteenth year,
Classic Systems is a company
dedicated to designing and
building products which solve
specific problems relating to
materials handling, and to EPA
and OSHA regulations.
We currently operate from
2 North Carolina locations with
over 130 employees and annual
sales of more than $10 million.
We serve our customers nation-
wide with innovative solutions
in the following categories:
• Dust Collection Systems
• Finishing Systems
• Fume Control
• Materials Handling
CLASSIC
from Classic Systems, Inc.
The CAMBoom utilizes a
unique Air Curtain design
and offers the following:
• Significantly Increased Efficiency
• Environmental Safety
• Higher Quality Coatings Applications
FOR USE AS A:
• Spray Booth
• Fume Control Device
SYSTEMS
'Patent Pending
-------
GRACO COMMENTS REGARDING PROPOSED
CTG FOR THE WOOD INDUSTRY
Thank you for the opportunity to present our
comments on the proposed CTG for the wood
industry. In our presentation today, we will
address the issue of transfer efficiency as it
relates to the performance of the paint
application device.
In reviewing the Draft Chapters 1 through 4
of the Control of Volatile Organic Compounds
from Wood Finishing Coating Operations, we
noted several references to a lack of a
standard transfer efficiency test.
Specifically, Pages 2--3G and 3--4S.
Basically, transfer efficiency is
the amount of paint that actually lands on a
part, compared with the total amount of paint
being sprayed from the gun.
Our goal is to maximize transfer
efficiency and minimize the amount of paint
used to paint a part. Higher transfer
efficiency will result in lower paint usage,
fewer solvent emissions, reduced exposure by
plant personnel to solvent fumes, less sludge
to dispose of, and less maintenance and less
paint handling in general. This task is
complicated by the demands of real world
production.
The formula that expresses this relationship
is as follows:
T.E.= Wp/%S x Q x T
-------
Where:
T.E.= Transfer efficiency
Wp= Weight of the paint solids deposited on
parts after baking
%S= Percentage of the sprayed paint that is
made up of solids
Q= Paint flow rate
T= Time of spray operation
At Graco, we have long recognized the need
for a standardized method that would provide
meaningful data to determine which
application device would provide the most
efficient means of applying paint to a
customer's product. Our customers range from
companies that paint huge metal structures
such as aircraft and road graders to
companies that paint considerably smaller
objects like wood spindles for chairs.
In addition to part size, shape and substrate
differences, some customers paint indoors
and some paint outdoors. Some apply paint at
a high delivery rate because they are painting
product moving down a conveyor line while
other paint stationary product in a paint
booth. The painting environment varies
greatly as well. Some customers have down
draft paint booths with very sophisticated air
movement controls;-others have less than
ideal conditions.
Given this wide array of equipment, Graco has
-------
developed a test for determining the transfer
efficiency of the paint application tool. We
recognized early on that there were a number
of factors which will have an affect on
transfer efficiency.
Among them-
• Operator Spray Technique
• Fluid Delivery Rate
• Atomizing Air Pressure
• Target Size
• Type of Application Tool
• Condition of Application Tool
• Part Configuration
• Air Velocity in the Spray Booth
• Fluid Pressure
• Distance of the Spray Gun from the Target
There are also quality standards which vary
from industry to industry and even from plant
to plant within the same industry.
Given all of these factors, Graco designed a
transfer efficiency test that attempted to
eliminate as many variables as possible. By
doing so, we felt that the tested performance
of the application tool would be meaningful
to our needs in product development and also
our customers' requirements for the most
-------
efficient application tool commensurate with
their needs for speed and quality.
At this time, I would like to take this
opportunity to describe that test procedure
for you.
Graco uses a test method for determining the
transfer efficiency of each type of
application tool that we feel provides a
reasonably accurate tranfer efficiency
number for each application tool. Through this
method, we have removed the variables of
operator technique, air flow past the booth,
part configuration and so forth. The test that
we use calls for painting a group of ten 4 foot
by 6 inch panels hung vertically on 12 inch
centers that are wrapped with preweighted
aluminum foil. The painting is performed by a
test gun that has been preset to approximate
the demands of a production environment. We
trigger the gun six inches before the spray
contacts the first panel and release the
trigger once the last panel has moved six
inches beyond the gun. By doing so, we can
accurately determine the amount of
paint dispensed through the gun and compare
that to the amount of paint by weight that
ended up on the panels. We determine the
weight of the paint on the panels by weighing
the panels before and after spraying and
noting the difference.
By using this method we are able to provide a
realistic transfer efficiency figure that one
could reasonably expect from
each method of spray finishing. By using the
same test criteria, here is how the various
spray technologies performed.
o-n
Jl O
-------
'o
'o
Air Spray 30%
HVLP Air Spray 40%
HVLP Air Assisted Airless Spray 45%
Electrostatic Ajr Spray (65kv) 65%
Electrostatic Air Assisted Airless
Spray 70%
Electrostatic Air Spray (85kv) 75%
I would like to point out that this method
shows that electrostatic guns are the only
finishing tools that, achieve transfer
efficiencies of more than 50%.
Due to the recent enactment of air quality
equipment rules that prescribe compliant
types of finishing equipment, many of you
have probably heard of another spray
technology, commonly referred to as "HVLP".
The term HVLP stands for High Volume Low
Pressure spray. As its name suggests, High
Volume Low Pressure spray uses large
volumes of air under reduced pressure
(typically 10 psi or less) to atomize coatings.
Because the atomized paint is propelled from
the HVLP gun at a lower velocity, there is a
reduced chance of overspray.
Today, there are two forms of HVLP
atomization. These are HVLP air spray and
HVLP air assisted airless spray. HVLP air
spray uses large volumes of air at low
pressure to atomize coatings, while HVLP air
assisted airless spray uses fluid pressure to
atomize coatings and reduced air pressure to
-------
sculpt the fan pattern of the atomized spray.
Claims of extremely high transfer
efficiency have been made for HVLP. However,
as I have tried to make clear, tests can be
designed to provide a high transfer efficiency
value. HVLP can generally provide finishers
with higher transfer efficiency than
conventional air spray systems. And at its
best, HVLP will generally exceed the transfer
efficiency of air spray and approach the
transfer efficiency of air assisted airless
spray while providing a high quality finish.
But it is important to remember that HVLP
air spray operates at generally lower fluid
flow rates than other spray finishing
methods. The lower atomizing pressures of
HVLP means that you may be forced to reduce
your fluid flow rate to maintain finish
quality. At these lower atomizing air
pressures, there may simply not be enough air
atomizing pressure to keep up.
On the other hand, HVLP air assisted airless
spray operates at fluid flow rates similar to
conventional air assisted airless spray and
therefore lends itself to higher production
environments.
But please remember, the test method I have
described is designed to test relative
performance levels. However, we can say that
this test method has been shown to be very
useful both to us and to end-users. These
findings have also been corroborated by
anecdotal evidence.
We know of a furniture finishing operation
that was able to achieve a 40% materials
savings when they "switched from
-------
conventional air spray to HVLP.
But as we have already noted, in the real
world, spray finishing conditions are much
more complex.
In addition, the industrial finishing line is
governed by two overriding concerns—finish
quality and productivity. The finished
appearance of the product being painted is
essential to its success in the marketplace.
The need to produce as many finished parts
as possible in as short a time as possible is
also essential to keeping production costs
down. These two factors will determine the
selection of finishing tools and
the way they are used on the finishing line.
We believe that transfer efficient application
tools will reduce the amount of paint used to
finish a part. This reduction will result in
fewer VOC emissions released into the
environment which in turn will benefit
overall air quality. The key issue in
identifying such transfer efficient tools is
the standardized test method by which we
will select them.
-------
Mobay's Role in the Wood Furniture Mobay
Coating Industry
Mobay is the leading North American supplier of
aliphatic and aromatic polyisocyanate resins for use in
polyurethane coatings for wood
Mobay is also the leading North American supplier of
non-air inhibited unsaturated polyesters for use in
polyester coatings for wood
Mobay sells resins to wood coating manufacturers
Mobay seeks to act as a technical partner to the wood
furniture coating industry
Presentation to U. S. Environmental Protection Agency, November 19-21, 1991
-------
Mobay's Role as a MobaX.
Raw Material Supplier
To define the status of our technology with respect to
VOC compliance
Enable us to demonstrate technology developments
and feasibility by working with furniture
manufacturers and coatings manufacturers
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
Current Status of 2-Component Mobay
Solvent-Borne Polyurethane Coatings
for Wood Furniture _____
Commercially Available System VOC (Ibs/gal)
Clear Top Coats
Benefits
Up to a 23% VOC reduction from
nitrocellulose coatings
(approximately
6.0 Ibs/gal to 4.6 Ibs/gal)
Greatly improved performance
properties (e.g. alcohol resistance/
mar resistance)
High film build resulting in the
reduced number of coating
applications
Currently being used in production
4.6-5.5
Present Limitations
• May require adjustments to existing
production operation and different
equipment for safe or cost efficient use
in some wood coating operations
• May require a degree of wood coatings
user training/adjustment in operating
procedure for their proper use
• Deviation from existing repairability
procedures
Presentation to U. S. Environmental Protection Agency, November 19-21, 1991
-------
Current Status of Non-air Inhibited
Unsaturated Polyesters for use in
Polyester Coatings for Wood
Mobay
Commercially Available System
Air Dry Clear Top Coats/Sealer
Developmental Systems
Air Dry Clear Top Coats/Sealer
UV-Curable Top Coat
UV-Curable Sanding Sealer
UV-Curable Top Coat
UV-Curable Sealer
Contains
monomer
solvent
monomer
monomer
water/s^£-)t'
water/
VOC (Ibs/gal.)
1.5
3.6**
0.7**
0.7**
0.2**;*
0.2**;*
*VOC value is less water
VOC Values are for developmental coatings formulations and
might be adjusted higher to suite production needs
**
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
cn
Current Status of Non-air Inhibited Mobay
Unsaturated Polyesters for use in
Polyester Coatings for Wood (ContdL)
Benefits
• 40-75% VOC reduction for Air Dry
unsatu rated polyesters as compared to
nitrocellulose (i.e. NC @ 6.0 Ibs/gal)
• 88-97% VOC reduction for UV-Cure
unsaturated polyesters as compared to
nitrocellulose (i.e. NC @ 6.0 Ibs/gal)
• Greatly improved performance properties
(e.g. alcohol resistance/mar resistance)
• High film build resulting in the reduced
number of coating applications
• Two alternative curing methods
Present Limitations
• May require a degree of
wood coating user
training/adjustment in
operating procedure for
their proper use.
• May require additional
or different equipment
for safe or cost efficient
use in wood coatings
operations.
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
Mobay Supports Mobav
^f H ^1 .•.•.VVV-V.V.V.'.V.SWAVW.-.V.V;
>MXiX4<«x-:-:->x<»M>
The reduction of VOC by use of 2-Component Polyurethanes
and Non-Air Inhibited Unsaturated Polyesters
The need for continued cooperation by the EPA with
coatings raw materials suppliers, coatings manufacturers,
and wood coatings users
In allowing VOC compliant products to be optimized
through continued development
To allow market acceptance of products based on
economic benefit, property performance, as well
as VOC reduction.
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
Goals of Mobay Development
Mobay
CO
Environmentally responsible coatings systems
High performance coatings
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
t- 3
to
Future Developments in
Wood Coatings
Mobay
VOC reduction down to 0.9* Ibs/gal via
2-Component water-borne polyurethane
topcoats and sealers
Potential Benefits
• 85% reduction in VOC from
nitrocellulose coatings
• High performance of a
2-Component solvent- borne
polyurethane
• Clarity of finish
• Higher film build
* VOC value is less water
Present Limitations
• No large scale production at this
point
• Commercial availability in 1-2
years
• Technology would require:
• cooperative development with and the
approval of wood coatings manufacturer
• acceptance of furniture coatings users
Presentation to U. S. Environmental Protection Agency, November 19-21,1991
-------
Mobay Supports Mobay
The cooperative efforts between the Joint
Industry Steering Committee (JISC), the paint
and coatings industry and the EPA by offering
raw materials and technology that will reduce
VOC levels and greatly improve the
performance properties of wood furniture
coatings and provide off-setting cost benefits
during the application process
Presentation to U. S. Environmental Protection Agency, November 19-21, 1991
-------
101 California Street
San Francisco, California 94111
National Economic Research Associates, Inc. (415) 291-1000
Consulting Economists Facsimile (415) 291-1020
ECONOMIC IMPACTS OF
VOC EMISSIONS CONTROL
ON THE FURNITURE AND CABINET INDUSTRIES
PRELIMINARY FINDINGS
Presented to:
National Air Pollution Control
Techniques Advisory Committee
Presented by:
Mark P. Berkman
Senior Consultant
National Economic Research Associates
On Behalf of:
American Furniture Manufacturers Association
Business and Institutional Furniture Manufacturers Association
Kitchen Cabinet Manufacturers Association
National Paint and Coatings Manufacturers Association
November 21, 1991
Durham, North Carolina
A Marsh & McLennan Company
White Plains, NY / Washington, DC / Los Angeles / Cambridge, MA / Philadelphia / San Francisco / New York, NY / Ithaca, NY / Seattle / London / Madrid
~
-------
PROJECTED TOTAL ANNUAL COST TO THE WOOD FURNITURE
AND CABINET INDUSTRY OF REDUCING VOC EMISSIONS
Annual Cost ($ millions)
(9
600
500 -
400 -
200 -
100 -
l I
10 % 20 %
30 % 40 % 50 %
Reduction in VOC Emissions
60%
70%
-------
PROJECTED PLANT CLOSURES
IN THE WOOD FURNITURE AND CABINET INDUSTRY
RESULTING FROM THE COSTS OF VOC CONTROL TECHNOLOGY
Number of Plants Closing
3,000
2^00 -
2,000 -
1,500 -
1,000 -
500 -
0 I—
1,488 U24 1,524 1,524
10% 20% 30% 40% 50% 60%
Reduction in VOC Emissions
70%
80%
-------
SO
PROJECTED EMPLOYMENT LOSSES
IN THE WOOD FURNITURE AND CABINET INDUSTRY RESULTING
FROM THE COSTS OF VOC CONTROL TECHNOLOGY
Number of jobs lost
100,000
80,000 -
60,000 -
40,000 -
20,000 -
17,764 17,764
12,513 12,513
10% 20% 30% 40% 50% 60%
Reduction in VOC Emissions
70%
80%
-------
Estimated Cost-Effoctlvsnsss of VOC Emission Control Methods In 1994 In Nonsttslnmsnt CWs»
Oaaolln* volatility
T80Fa
RACT
Enhanced I/M
Stag* II
New CTOa
Mathanol fuel*
Architect, coating*
Onboard controla
New mobll* atd'a.
Stag* II » Onboard
Low • $8,700 p*r ton
Mean • $30.000 p*r ton
High • $61.000 p*r to ON.
\
Coal-*lt*ctlv*n*aa In 2004
0123468789
$1.000/ton of VOC r*duo*d
The cost-effectiveness of enhanced Inspection and maintenance (VM) programs and new mobile standards Include only the cost of VOC
confrol. Since Onboard controls and new mobile standards do not take affect until after 1994. we present the cost-effectiveness In 2004.
The thick horizontal bars represent the average cost-effectiveness in nonattainment cities. The thin horizontal lines for gasoline volatility.
methanol fuels, and l/M programs represent ranges of uncertainty associated with assumptions we used to estimate total annual costs.
The very large uncertainty associated with the methanol fuels Is due to the uncertainty of methanol prices relative to gasoline prices. We
were unable to estimate cost-effectiveness uncertainty for other control methods. See figure 7 for a description of control methods.
SOURCE Otlto* ol1
•ft A*«
Catching OurBnath —Next Steps for Reducing Urban Ozone, Congreu of the United States/Office of Technology
Aiaeument, July 1989, Page 17
-------
WOOD FURNITURE AND FIXTURES MANUFACTURERS
ACCOUNT FOR LESS THAN ONE PERCENT OF TOTAL
VOC EMISSIONS
Small Stationary
42.23%
-
P
Large Stationary
7.83%
Air, Rail, Marine
5.58%
Wood Furniture
and Fixtures
Manufacturers
0.54%
Highway Vehicles
43.82%
Emission from Wood Furniture and Fixtures
Manufacturers were subtracted from Large
Stationary.
Source: Derived from 'Catching Our Breath:
Steps for Reducing Urban Ozone,"
U.S. Congress, Office of Technology
Assessment 1989.
-------
LOWEST ANNUAL COST OF ATTAINING A 30 PERCENT
REDUCTION IN VOC EMISSIONS FOR DIFFERENT
WOOD FURNITURE AND CABINET PLANT TYPES
Cost (dollars/ton)
12,000
10,000
8,000
6,000
4,000
2,000
0
(2,000)
%£*•
I
Casegoods
10-14 Coats
Casegoods
Highspeed
(Up to 10 Coats)
Office Furniture
(High End
Casegoods)
Chair
Plant
Print
Finish
(Flat Line)
Kitchen
Cabinets
(Tow Line)
Small
Upholstered
Plant
-------
THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
MODEL PLANT 3 (HOUSEHOLD FURNITURE: 19 COAT STEPS; $27.0 MILLION)
See
P
PROFIT/SALES (%)
6.00%
4.00% -
2.00% -
0.00%
-2.00% -
-4.00% -
-6.00%
No Control HVLP Spray Gam Hybrid Wtterbome PuU Wttabame Union*
VOC CONTROL TECHNOLOGY
Carbon Adwxptioa
Regenerative
locutennoB
Low Profit Quartile
Model Plant Profit
High Profit Quartile
-------
THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
MODEL PLANT FOUR (OFFICE CASEGOODS: 15 COATING STEPS; SALES $11.0 MILLION)
PROFIT/SALES (%)
10.00%
5.00%
0.00%
-5.00%
-10.00%
•15.00%
5.90%
1.20%!
-1.00%
5.99%
1.29%
I
5.41%
4.56%
4.07%
0.71%
0.41%
I
I
I
No Control HVLP Spray Guns Hybrid Walerbome Full Waterbome Unicarb
VOC CONTROL TECHNOLOGY
Carbon Adsorption Regenerative
Incineration
Low Profit Quaitile
Model Plant Profit
High Profit Quartile
-------
THE EFFECT OF VOC CONTROL TECHNOLOGY ON PROFITS
MODEL PLANT EIGHT (KITCHEN CABINETS: 4 COATING STEPS; SALES $13.4 MILLION)
PROFIT/S ALES (%)
8.00%
-4.00%
No Control HVLP Spray Guns Hybrid Walerbome Full Waierbome Unicub Outran Adsorption UV Roll Coating Regenerative
Incineration
Low Profit Quartile
VOC CONTROL TECHNOLOGY
Model Plant Profit ^ ^ High Profit Quartile
-------
Annual Failure Rates per 10,000 Concerns
(Enterprises listed in Dun & Bradstreet Census
of American Business)
Failures per 10,000 companies
200
150 -
100 -
1986
1987
Furniture
1988 1989
All Manufacturing
1990
Source: Business Failure Record, 1986-1990
Dun & Bradstreet Corporation
-------
Millions of Dollars
$4,000
U.S. HOUSEHOLD FURNITURE INDUSTRY (SIC 251)
DOLLAR VOLUMES OF FOREIGN IMPORTS AND U.S. EXPORTS
1981-1990
$3,000
3 to $2,000
^
$1,000
$0
I
I
I
I
I
I
_L
1981 1982 1983 1984 1985 1986 1987
Foreign Imports U.S. Exports
1988
(est)
1989
(eat)
1990
(est)
Source: U.S. Census Data as reported in The U.S. Household
Furniture Industry," Economic Industry Reports, Inc., 1990.
-------
9
PROJECTED PLANT CLOSINGS
BY PLANT SIZE AND VOC REDUCTION LEVEL
Number of Employees in Plants Experiencing Losses
in excess of 5% of sales
3,000
2,500 -
2,000 -
1,500 -
1,000 -
500 -
0
1,950
1-19
25
20-99 100-249 250-499 500-999
Size of Plants
(Number of Employees)
2,539
I I
1000+ All Plants
80% VOC Reduction
60% VOC Reduction
50% VOC Reduction
40% VOC Reduction
30% VOC Reduction
H 20% VOC Reduction
^ 10% VOC Reduction
I I Already experiencing losses
-------
is
PROJECTED EMPLOYMENT LOSSES BY
BY PLANT SIZE AND VOC REDUCTION LEVEL
Number of Employees in Plants Experiencing Losses
in excess of 5% of sales
100,000
80,000 -
60,000 -
40,000 -
20,000 -
11,075
..A1, 19334
17,012 HBHHH 15>949 15,927
86,534
1-19 20-99 100-249 250-499 500-999
Size of Plants
(Number of Employees)
I I
1000+ All Plants
80% VOC Reduction
60% VOC Reduction
50% VOC Reduction
40% VOC Reduction
30% VOC Reduction
20% VOC Reduction
10% VOC Reduction
Plants already
experiencing losses
-------
POLICY IMPLICATIONS
A MARKET-BASED VOC REDUCTION APPROACH SHOULD BE
CONSIDERED AS A SUBSTITUTE FOR OR IN CONJUNCTION
WITH RACT FOR SEVERAL REASONS:
1. THE WIDE VARIATION IN CONTROL COSTS AND
FINANCIAL IMPACTS WITHIN THE INDUSTRY PROVIDES
AN OPPORTUNITY TO ACHIEVE SIZEABLE REDUCTIONS
AND AVOID ADVERSE ECONOMIC CONSEQUENCES
THROUGH EMISSIONS TRADING
2. THE AVAILABILITY OF LOWER COST REDUCTIONS FROM
OTHER SOURCES PROVIDES AN OPPORTUNITY TO LOWER
THE OVERALL COSTS OF VOC REDUCTIONS
AT A MINIMUM, THE RACT FOR THE FURNITURE INDUSTRY
SHOULD ACCOUNT FOR THE RELATIVE COSTS AND
CONTRIBUTIONS OF THE INDUSTRY TO THE GOAL OF VOC
REDUCTION
n/e/r/a
-------
Wood Furniture and Kitchen
Cabinet Industry
Volatile Organic Compound
Control Technology Study
-------
Mission Statement
The mission of the Joint Industries Steering Committee is
to participate in the federal Wood Furniture CTG
development process in order to achieve guidelines that:
• Enhance and improve the environment of the United
States and the world;
• Are technically feasible;
• Are economically justifiable;
• Do not restrict the future growth and development of
the United States Wood Furniture and Kitchen
Cabinet Industries
-------
Joint Industry Steering Committee
Members
• American Furniture Manufacturers Association
(AFMA)
• National Paint & Coatings Association (NPCA)
• Kitchen Cabinet Manufacturers Association
(KCMA)
• Business and Institutional Furniture
Manufacturer's Association (BIFMA)
-------
Industry Characterization
• Detailed Survey of 160 Industry Facilities
- Provided Industry-wide Technical and Economic Data
- Used as Basis for Development of Model Plants
• Facility Technology Demonstrations and Site
Visits
- Visited 24 Facilities
- Provided On-Site Observations and Analyses of
Technologies
-------
ndustry Characterization (cont)
• Industry Experts
- Provided confirmation/refinement to model plant
, characterizations
^ - Collective Knowledge of Actual Conditions at Hundreds
of Facilities
-------
Development of Representative Model
Plants
• Defined 12 Model Plants to Cover Industry
Characteristics
• Grouped Survey Responses into the 12 Model
Plant Categories for Characterization
• Augmented Survey Data with Site Visits and
Industry Expertise
-------
JISC Model Plants
Considerations:
• Industry Complexity Does Not Lend Itself to
Simple Characterization
• Complex Finishing Systems Driven by Consumer
Demand for Product Quality and Aesthetics
• Many Coatings with Varying VOC/Solids Contents
• Multiple Substrates with Differing Properties
-------
'.J
JISC Model Plants (cont.)
• Heat and Water Sensitive Substrates
• Coatings Sensitive to Variations in Temperature
and Humidity
• Multiple VOC Emission Points
• Varying Price Points of Goods Produced
-------
Model Plants -- Key Parameters
• Finishing Schedule (No. of Coats and Type)
• Type of Wood Substrate, Production Line, and
Product Produced
• Annual Usage of Each Coating
• Number/Flow Rate of Spray Booths and Drying
Ovens
-------
Model Plants -- Key Parameters (cont.)v
• Production Rates/Line Speeds
• Annual VOC Emissions
• Number of Employees
• Number and Type of Spray Guns/Roll Coaters
• Number of Pumps
• Coating Storage Method
-------
Control Technologies Evaluated
• Recuperative Thermal Incineration
• Regenerative Thermal Incineration
• Fixed Bed Catalytic Incineration
• Fluidized Bed Catalytic Incineration
• Carbon Adsorption
• Carbon Adsorption/Incineration
• Full Waterborne Coating System
• Hybrid Waterborne Coating System
-------
Control Technologies Evaluated (cont.)
• UV Curable Coatings
• UNICARB® System
• HVLP Spray Guns
•Terr-Aqua UV/AO
• Sunkiss Ovens
• Mobile Zone Spray Booths
• Recirculating Spray Booths
• Air Curtain Spray Booths
-------
Engineering Limitations for Certain Control
Technologies
• Reduced Flow by Air Recirculation
- Not Generally Applicable to All Segments of the Industry
- Limited Actual Use in Industry Facilities
- OSHA and Insurance Considerations
• Reduced Flow by Air Curtain
- Developing Technology, not Commercially Available
- OSHA and Insurance Considerations
-------
Engineering Limitations for Certain Control
Technologies (cont.)
• Full Waterborne Technology for Long Finishing
Sequences
- Technical Problems in Meeting Quality Specifications
- Not Commercially Demonstrated for These Types of
Finishes
- UNICARB® for High Speed Lines and Stains
- Technical Problems in Delivering Sufficient Coating Volumes
- Slower Evaporating Solvents Require Longer Drying Time
- Commercially Available for Topcoats and Sealers Only
-------
Engineering Limitations for Certain Control
Technologies (cont.)
• Mobile Zone Spray Booths
- Developing Technology, not Commercially Available
• Terr-Aqua UV/AO Oxidation
- Developing Technology, Requires Further Study
• Sunkiss Ovens
- Does Not Achieve Sufficient VOC Reduction to be
Considered a Control Technology
-------
c:n
Control Technology Evaluation
Determined Capital and Annual Costs for Potentially
Feasible Controls
• Add-On Emission Controls
- Catalytic Incineration (fixed bed and fluidized bed)
- Thermal Incineration (recuperative and regenerative)
- Carbon Adsorption
- Carbon Adsorption/Incineration
• Application Methods (Transfer Efficiency)
- HVLP Spray System (slower lines)
- Roll Coating
- UNICARB® (slower lines)
-------
Control Technology Evaluation (cont.)
Reformulation
- Hybrid Waterborne Systems
- Full Waterborne Systems
- UNICARB® Finishes
- UV Cured Finishes
-------
Potential Mass VOC Reductions Available
(Plant-Wide)
•'.J
Control Technology
Industry as Whole
Spray Techniques:
HVLP
UNICARB®
2-15%
8-33%
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
28-61%
60-75%
42-80%
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
3-86%
3-86%
3-79%
-------
Problems with Add-On Control Equipment
• High Capital/Operating Costs
• High Energy Demand
• Secondary Environmental Impacts
• Skilled Labor to Operate Equipment
• Gas Pretreatment Required
• OSHA, Safety and Insurance Considerations
-------
EIKR
Problems with Waterborne Coatings
• Production Line Color Control with Waterborne
Stains
• Sags and Film Thickness on Vertical Surfaces
• Repairability
• Ease of Application/Drying Time
• Sensitivity to Temperature/Humidity Changes
• Print Resistance
• Rubbing Characteristics (Layering)
• Appearance (Clarity/Color)
-------
Problems with UNICARB®/UV
UNICARB®:
• Developing Technology
• Available Only for Sealer/Topcoat
• Restricted to Slower Line Speeds
UV:
• Applicable to Limited Industry Segments
• Casegoods Technology Still Under
Development
• Difficult to Repair
-------
Costs of Alternative Controls
• Evaluated 11 Control Technologies for the 12
Model Plants
• Developed Capital Costs, Annual Costs, Cost
Effectiveness Following OAQPS Guidelines
-------
Capital Costs of Alternative Controls
Control Technology
Industry as Whole
Spray Techniques:
HVLP
UNICARB®
$400/HVLP Gun
$75,000 -$21 0,000
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
$165,000 -$1,005,000
$286,000 - $1 ,030,000
$98,000 - $1 ,005,000
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$163,000 - $1 ,026,000/booth
$312,000 - $673,000/booth
$419,000 - $885,000/booth
-------
Annual Operating Costs of Alternative
Controls
Control Technology
Industry as Whole
Spray Techniques (Negative Numbers Indicate Cost Savings):
HVLP
UNICARB®
($51, 000) -$2,000
$25,000 - $470,000
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
($163,000) -$547,000
($166,000) -$300,000
$95,000 - $1 ,222,000
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$103,000 - $321,000/booth
$68,000 -$170,000/booth
$106,000 - $223,000/booth
-------
Cost Effectiveness of Alternative Controls
Control Technology
Industry as Whole
Spray Techniques (Negative Numbers Indicate Cost Savings):
HVLP
UNICARB®
($2,100)-$1,800/ton
$2,100-$9,400/ton
Reformulation:
Hybrid Waterborne
Full Waterborne
UV Cured
($500) - $1 1 ,500/ton
($400) - $8,600/ton
$800-$15,800/ton
Add-On Controls:
Incineration
Carbon Adsorption
Carbon Adsorption/Incineration
$1 ,500 - $87,300/ton
$1,300-$44,100/ton
$1 ,400 - $63,500/ton
••-J
C75
-------
Additional Issues
• Units of VOC Limits
• Multiple Levels for Various Industry Segments
• Phased Implementation of Developing
Technologies
-------
Technical-Economic Analysis Interface
ENSR
Technical Feasbility
• Evaluate Controls
• Evaluate Capital and
Annual Operating Costs
NERA
Economic Feasibility
• Identify Least Cost Controls
• Estimate Financial and
Employment Impacts at
Plant and Industry Level
-------
November 8, 1991
Mr. Bruce C. Jordan
Director, Emission Standards Division (MD-13)
Office of ftir Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, N.C. 27711
Dear Mr. Jordan:
Subject: Comments on Draft Chapters 1-4 of the Control
Technique Guidelines (CTG) for Control of Volatile
Organic Compound Emissions from Wood Furniture
Coating Operations
We have seven (7) plants that will be affected by the final
outcome of the control techniques guidelines. While we are
optimistic that source reduction of VOCs will be one of the
options in the CTG and one which we can ultimately achieve, we
are concerned about the model plant parameters that will be used
to determine the cost of add-on controls.
Specifically refer to page 4-3 of the draft CTG, model plant no.s
2 and 5, and read the exhaust rates for those two (2) plants.
These residential furniture models are assumed to exhaust the
same amount of air even though one finishing sequence is twice as
long as the other. The short finishing sequence represents six
(6) finishing steps which would reasonably correlate to six (6)
spray booths while the long finishing sequence represents twelve
(12) finishing steps which would reasonably correlate to twelve
(12) spray booths. The exhaust rates for the long sequence could
reasonably be expected to be twice as high as the exhaust rates
for the short sequence.
The use of the above-mentioned exhaust data will result in
inaccurate cost figures for those model plants since the cost of
add-on controls is largely a function of size determined by air
flow rates. In order to effectively accomplish what you have set
out to do you would need to look at the exhaust rates for the
long and short sequences of the model plants separately.
We are also concerned about the comments addressing the
potential for booth enclosure, especially without the advantage
of your including a visit to a residential furniture
manufacturer. Due to the number of surfaces that must be coated
a worker does not merely stand to finish a piece of assembled
Thomasvillc Furniture Industries, Inc. • P.O. Box 339 • Thomasville, North Carolina 27361 • 919472-4000
P- f* r>
•>' • O J
-------
Thomasville Furniture Industries, Inc.
Thomasville, North Carolina
residential furniture as indicated in the document on page 3-23.
The worker moves on the line with the piece. Further enclosure
would probably be possible but with drastic changes in
product i on.
Finally, it would have been desirable to have the draft of
Chapter 5 prior to the NftPTAC meeting. Mary Jane Clark in OAQPS
has indicated that the comment period following the meeting will
probably be two (2) weeks. fis it stands we will have limited
time for review and comment on what may be the most critical part
of the document.
Your consideration of these matters will be greatly appreciated.
Sincer
Sherry Stookey, Supervisor
Environmental Compliance
cc: Larry Belton
George Griffin
Dan Little
Jim Johnson
Carlyle Nance
Charley O'Brien
Dave Masters
-------
AUTOMOBILE REFINISHING
CONTROL TECHNIQUES GUIDELINE
Presented by: Darcy Campbell
Radian Corporation
The full text from the Environmental Protection Agency's
(EPA's) presentation of the draft control techniques guideline
(CTG) is provided below. Following that is a summary of the
questions and discussion that occurred with the National Air
Pollution Control Techniques Advisory Committee (NAPCTAC) after
EPA's presentation.
INTRODUCTION
(Slide 1)
I would also like to introduce Ellen Ducey, the EPA's Lead
Engineer on this project.
The facilities covered under this CTG repair and/or refinish
automobiles, vans, motorcycles, and light- and medium-duty
trucks. Heavy duty trucks are currently covered by another CTG
that EPA developed for Miscellaneous Metal Parts.
"Shops" are defined as:
independently-owned shops that repair collision damage
and do some complete repainting,
shops at car dealerships that repair transportation
damage and collision damage that occurs after a car is sold,
and
production shops that specialize in complete repainting
rather than collision repair.
The definition also includes any facilities that repair new
vehicles damaged in transit.
(Slide 2)
I will first discuss the refinishing process, along with the
volatile organic compound (VOC) sources. I will then discuss the
VOC control methods that have been evaluated in terms of their
emission reductions and costs, present the results of our
regulatory analysis, and discuss the implementation of a
regulation for this industry.
(Slide 3)
Estimates of the number of body shops in the U.S. vary. We
estimate that there are roughly 63,000. Extrapolating by
population, there are roughly 30,000 shops in nonattainment
areas. Taking into consideration the existing State and local
regulations already in place in Texas, New York, New Jersey, and
-------
California, we estimate that about 100,000 tons of VOC's are
emitted each year from body shops in nonattainment areas.
THE REFINISHING PROCESS
(Slide 4')
Surface preparation refers to the removal of dirt, wax,
grease and silicone. Surface preparation products are used
whether a replacement part is painted or the existing finish is
sanded off.
Several different types of coatings are used in refinishing.
"Primers" are any coatings applied before the topcoat. Types of
primers include pretreatment wash primers, precoats, primer
surfacers, and primer sealers. Topcoats determine the final
color of the refinished area.
Many shops apply coatings in some type of spray booth. Each
coating is applied to a certain "dry film thickness," which is
expressed in mils, or one-thousandths of an inch.
An important consideration in the refinishing process is
matching the existing car color. This is a very complex problem
because there are so many car colors, and more new colors are
introduced every year. For example, one car manufacturer alone
can introduce 20 new colors each year, and have a total of 70
colors for cars in a given model year. Refinishing is also made
difficult because topcoats applied by original equipment
manufacturers (OEMs) may be complex two-, three-, or even five-
stage products.
Additives and specialty coatings are different from the
other coatings. They are used in small amounts as needed for
easier repair and less customer dissatisfaction.
After the refinishing process, spray equipment is cleaned
with solvent to remove the paint so the gun can be used again on
another job.
EMISSION CONTRIBUTIONS
(Slide 5)
Emission contributions shown on this slide have been
estimated using "model" shops, which will be discussed in more
detail later. As you can see, the majority of emissions are from
application of coatings. Equipment cleaning contributes
9 percent of the VOC's, additives and specialty coatings
5 percent. Three percent of emissions are from surface
preparation. For our purposes, coating emissions begin with
spraying; any emissions that might arise from the mixing process
were not considered.
966
2
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REGULATORY ANALYSIS
(Slide 6)
Eight model shops were developed to analyze emission
controls. They were used to establish a common basis by which to
calculate a baseline and the impacts of any recommended control.
The mode'l shops were developed from information in trade
journals, and from discussions with industry and State agency
representatives.
Our model shops represent the diversity of the industry.
Shops are delineated by size, equipment, and types of coatings
used.
(Slide 7)
The model shop size is reflected by the number of employees
and number of jobs. Anything less than painting an entire car is
considered a "spot" or "panel" repair, and is shown here as a
partial job.
The information we gathered from trade journals helped us
delineate shops B through H. Based on discussions with industry
representatives, we added shop A to represent very small shops.
Eighty percent of the model shops are medium-size, with a large
range in the number of jobs they do each year. Model Shop H
represents the large national chains that have more than 10
employees and a large portion of their work is full jobs.
(Slide 8)
The model shops have different types of equipment. Model
Shops A and B represent the smallest shops, which are assumed not
to invest in much equipment. They do not have gun cleaners or
spray booths. The other medium-size shops (besides B) are
distinguished by the variety of equipment they have. Shop C has
a gun cleaner, D has a crossdraft booth, E has both, F has a
downdraft booth, and Shops G and H, the largest shops, have
invested in the most equipment: they use gun cleaners and
downdraft spray booths.
A distinction is made between crossdraft and downdraft
booths because downdraft booths cost twice as much, and
reportedly produce a much higher quality paint job.
The combinations of equipment present in the model shops
were developed based on national estimates of the percent of
shops that use this equipment.
(Slide 9)
The model shops use different types of coatings. Lacquer is
the easiest to use and the most "forgiving" type of coating. It
dries quickly and is buffed after drying to remove dirt and dust.
However, it results in the lowest quality finish in terms of
durability.
Enamels and urethanes dry more slowly because they have
lower VOC levels and higher solids contents, resulting in lower
VOC emission potentials than lacquers. Because they dry more
slowly, it is more important that the painting area be as clean
-------
as possible. Enamels vary in their finish quality: there are
low-quality and high-quality enamels. Urethanes produce the
highest quality finish in terms of gloss, and are the most
durable.
(Slide 10)
Model Shops A and B use a large percent of lacquer coatings
because they do not have any kind of spray booth. It is possible
that these shops also use urethane coatings, but in our analysis
we assumed that they only use lacquers and enamels.
Shops C, D, E, and F use all three types of coatings in
different combinations. Shops G and H use mostly high-quality
urethane coatings.
VOC CONTROL OPTIONS
(Slide 11)
To identify VOC control options for this industry, we
surveyed the industry, reviewed published literature and existing
State regulations, and met with several industry representatives
to identify control options. We then used model shops to
determine emission reductions achievable through the use of these
control options.
Surface preparation emissions can be reduced by using
products that have lower VOC levels. Coating application
emissions can be reduced by using coatings with lower VOC levels,
whether they are higher in solids or waterborne rather than
solventborne. The results of our survey indicated that in most
cases this industry now tends towards higher solids rather than
waterborne coatings.
Add-on control devices could also be used to control coating
emissions. Add-on controls are not currently used by any shops,
but they were evaluated because they are used in many other
industries that spray-apply coatings. An add-on control device
would control emissions from all operations that take place in
the booth.
Emissions from equipment cleaning can be reduced by using
gun cleaners that minimize evaporation and recirculate the
solvent for several cleanings rather than manually cleaning the
spray equipment. If a gun is cleaned manually, solvent may be
sprayed through the gun either into the air or into a container
from which it is allowed to evaporate. With a gun cleaner,
solvent is drawn by suction through the spray guns after they are
attached to hose connections. The outside of the gun is then
either rinsed manually or automatically, depending on the type of
gun cleaner. In our evaluation of gun cleaners, we found that in
general they can be divided into two groups: enclosed cleaners
with lids that are shut during the cleaning cycle, and open
cleaners that have no lid.
Finally, making sure that shops properly dispose of their
waste solvent would further reduce evaporative emissions.
968 4
-------
SURFACE PREPARATION
(Slide 12)
Emissions from surface preparation products can be reduced
through the use of waterborne rather than solventborne products.
Waterborne products have VOC levels below 1.7 pounds per gallon.
These prbducts are somewhat harder to use than conventional
products because they are more labor intensive and it takes
longer to clean the surface. They are currently required in
California and Texas.
Low-VOC products reduce emissions from surface preparation
by 75 percent. The cost increase is about $5 per gallon, or $1
per full job.
COATINGS
(Slide 13)
Industry reports that they are actively developing lower VOC
coatings in response to State regulations. We surveyed the six
major coating manufacturers in the summer of 1990 for information
on their lower VOC coatings. We asked them to list any
limitations with the use of these products, especially problems
with topcoat color matching. Color matching is of continuing
concern because a painter may have to repaint a larger area if he
has trouble making the refinish color look the same as the
existing color. If the color match is not reasonably good,
painters will have to paint a larger area until they reach some
natural break on the car such as a fender or a door.
Color matching is so important, and there are so many car
colors, we could not just set limits based on the lowest VOC
primers and topcoats identified in our survey- Taking into
consideration information provided on color match and product
compatibility, we grouped the lower VOC coatings into two
regulatory options. It should be noted that VOC emission
reductions are not linear. If you had a coating with a VOC
content of 6.5 Ibs VOC/gal and you wanted to reduce emissions by
40 percent, you could do so by replacing it with a coating with
6 Ibs VOC/gal. This is due to the fact that the lower VOC
content coating has more solids in a given volume of paint so
less volume is needed to coat the part. A coating with 5.5 Ibs
VOC/gal reduces emissions by 60 percent from that of the coating
with 6.5 Ibs VOC/gal. The VOC levels shown on this slide are all
expressed as Ibs VOC/gal coating, less water.
The VOC contents of the baseline coatings were derived from
the model shops7 use of lacquers, enamels, and urethanes; the
high end reflects greater lacquer use and the low end reflects
more use of urethanes.
Option 1 coatings are currently available to shops. We
think that they are widely used because they are not very
different from baseline or existing technology coatings. We
think there are no color match limitations associated with the
969
5
-------
use of Option 1 topcoats. They do, however, eliminate the use of
essentially all lacquers.
The Option 2 VOC levels are more stringent. Coatings with
these levels were reported by at least one company that responded
to the survey. We have already received some comments that the
Option 2 limits will be difficult to meet, and I think we will
hear more about this in some industry presentations.
Compared to the baseline, emissions from coatings would be
reduced 35 percent if all shops used Option 1 coatings, and
55 percent if all shops used Option 2 coatings. The biggest
emission reductions come from the smaller shops that are assumed
to currently use large quantities of lacquers.
(Slide 14)
With Option 1, the smallest shop can reduce its coating
emissions by 50 percent, or 0.4 tons. The largest shop reduces
its emissions by 20 percent, or 2.5 tons.
The cost increases shown here are the incremental paint
costs only and do not include any additional labor or equipment
costs that might be incurred. There is no cost increase for the
largest shops with the Option 1 coatings because they already use
coatings with low VOC levels. With Option 2, the smallest shop
can reduce 60 percent of its coating emissions, and the largest
shop can reduce 45 percent of its emissions, or 5 tons per year.
The increased paint costs for Option 2 represent a 9 percent
increase per full car for the smallest shop and a 6 percent
increase for the largest shop.
ADD-ON CONTROLS
(Slide 15)
For add-on controls, we evaluated catalytic incineration,
carbon adsorption, and biofiltration. We only evaluated add-on
controls for the largest model shop, where the use of these types
of controls is most feasible because of its high volume of work.
If the spray booth is in relatively constant use> then add-on
controls are more affordable.
With biofiltration, the spray booth exhaust is passed
through material that contains microorganisms that convert the
VOC's to carbon dioxide and water. Even though this is only in
the developmental phase in this country, it may be the best add-
on for this industry because it reportedly can function even with
periods of non-use and with low solvent air streams.
We will continue to investigate the use of add-on controls
for this industry, especially biofiltration. In particular, we
will investigate whether overseas shops use any type of add-on
control.
970
6
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ADDITIVES AND SPECIALTY COATINGS
(Slide 16)
Our analysis indicated that the best way to control
emissions from additives and specialty coatings is to limit their
use rather than require reformulation or discontinuation of their
use. The use of these products probably prevents some VOC
emissions because a painter can prevent some surface defects from
occurring, and can better blend the new paint into the old
without having to paint a larger area. These products also
prevent having to repaint areas because of problems such as a
coating flaking off from a refinished bumper.
Limiting the use of additives and specialty coatings to less
than 5 percent of all coatings also closes the potential loophole
of shops identifying a product as a "specialty coating" and then
using a high volume of it.
GUN CLEANERS
(Slide 17)
To reduce emissions from gun cleaning, it is recommended
that shops use a gun cleaner rather than manually cleaning their
spray guns. Based on comments we have received to date, I think
we will be hearing more about the gun cleaning issue in later
presentations.
Closed gun cleaners are required by some States. We were
also going to suggest that States require their use until we saw
the results of an independent study that indicates that there is
a large range in the sum of the active and passive VOC losses
from closed gun cleaners. Some models are not efficient in
controlling evaporation. The study showed that open gun cleaners
have evaporative losses as low or lower than closed gun cleaners.
Gun cleaner manufacturers are researching ways to further reduce
VOC losses, which may make closed gun cleaners preferable in the
future, especially because from an environmental standpoint a
combination of the two types of gun cleaner designs would
probably be best.
The primary benefit of a gun cleaner is that roughly 10 guns
can be cleaned with the same amount of solvent that would be used
to clean 1 gun manually. In terms of emission reductions, this
translates to about an 88 percent reduction in gun cleaning
emissions for a shop that installs a gun cleaner. This amounts
to an annual emission reduction of 0.2 tons for the smallest shop
and 1 ton for the largest shop that does not already have a gun
cleaner.
Costs range from $36/year for the smallest model shop to a
cost savings of $800/year for the largest shop because of the
money it saves on solvent purchases.
9717
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SUMMARY
(Slide 18)
The costs and emissions given in this presentation are for
the 30,000 shops in nonattainment areas, and take into
consideration existing State regulations.
Surface preparation emissions can be reduced by 1600 tons at
a cost of about $2200 dollars per ton.
An emission reduction of 25,000 tons would result from the
use of Option 1 coatings,' at a cost of $59 million. The use of
Option 2 coatings would result in an emission reduction of 53,000
tons at a cost of $122 million. Both options represent a cost of
about $2300 per ton reduced.
Option 2a is Option 2 coatings used by all shops except H,
which uses carbon adsorption. Emissions are reduced by 68,000
tons per year at a cost of $292 million.
The use of gun cleaners results in a national cost savings
because shops will have to purchase less solvent. The smallest
shops, however, would bear a total national cost of $80,000
because the value of solvent saved would not completely offset
the cost of the gun cleaner.
IMPLEMENTATION
(Slide 19)
We recommend the following requirements for States
implementing a regulation on the automobile refinishing industry:
For lower VOC surface preparation products, a State would
use an operational standard that requires shops to use
products with VOC levels below 1.7 Ibs per gallon cleaner;
An operational standard would also be used to require the
use of lower VOC coatings;
An equipment standard would require the use of a gun
cleaner that recirculates solvent, collects spent solvent,
minimizes evaporation, and meets fire safety and
occupational safety and health codes.
Most requirements would be enforced by recordkeeping:
Shops would be asked to maintain records on the number of
jobs they do, the VOC content and amount of surface
preparation product they use, and the amount of coating,
catalyst, and reducer used and their mix ratio; and
Shops would also be asked to record the VOC content of
the coating, as applied, less water.
A shop would know the VOC content if the VOC content was
provided by the manufacturer along with the coating; we will
include a section in the CTG on how shops should get this
information, whether it be given through the "as supplied" and
"as applied" VOC levels on labels, material safety data sheets,
the microfiche provided with mixing machines, or some type of
separate "Application Guide."
For gun cleaners, compliance would be determined by having
shops maintain records of the amount of replacement solvent they
972R
o
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use per month and-documentation of the amount of waste solvent
transferred to waste treatment facilities.
OTHER APPROACHES
(Slide 20-)
Some other "nontraditional" ways to reduce VOC emissions
from body shops that are discussed in the CTG and that may have a
big impact on this industry are some pollution prevention and
market incentive measures. The EPA's Pollution Prevention office
is looking into these approaches and plans to evaluate their
impacts on the refinishing industry.
One example of a pollution prevention measure is for the
U.S. Department of Transportation to raise the minimum standard
for the strength of automobile bumpers so that less damage occurs
in a "fender bender" and less of the vehicle has to be repainted.
Educating consumers about the costs of the more complex
coatings, and showing them that they pay more for these coatings,
may cause car manufacturers to reduce the complexity of topcoats.
As long as there are an infinite number of colors available
for new cars, there will be a continuing impact on the
refinishing industry. It is possible that setting a VOC limit on
refinish coatings may make it impossible to color match some OEM
colors.
We are suggesting that States establish a permitting program
that would help locate shops, and States could use this type of
program to push the industry to be more aware of measures it can
take to reduce VOC emissions.
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CONTROL
TECHNIQUES
GUIDELINE
Control of
Volatile Organic Compound (VOC)
Emissions from
Automobile Refinishing Operations
NAPCTAC Meeting Presentation
November 1991
974
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AUTOMOBILE REFINISHING
OUTLINE OF PRESENT A TION
• Description of Process
• Sources of Emissions
• Regulatory Analysis
- Control Options
- Costs
• National Impacts
• Implementation
975
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CONTRIBUTION TO
VOC EMISSIONS
-63,000 body shops in the U.S.
-30,000 located in nonattainment areas
Approximately 100,000 tons per year of
VOC's emitted in nonattainment areas
9763
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DESCRIPTION OF
REFINISHING PROCESS
1. Prepare surface
2. Apply coatings
- pretreatment wash primers
- precoats
- primer surfacers
- primer sealers
- topcoats
- additives and specialty products
3. Clean Equipment
977
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SOURCES OF VOC EMISSIONS IN
AUTOMOBILE REFINISHING
Coating Application
83%
GD
en
Equipment
Cleaning
9%
Additives and
Specialty Coatings
5%
Surface Preparation
3%
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REGULATORY ANALYSIS
Eight model shops
Delineated by
- Size
- Equipment
- Types of Coatings
979
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Shop
Size
Small
Medium
Large
Model
Shop
A
B
C
D
E
F
G
H
Percent
of Shops
10
14
5
10
39
7
5
10
Number of
Employees
<5
5-10
5-10
5-10
5-10
5-10
5-10
>10
Number of
Jobs/Month
Partial
12
29
42
62
83
75
104
62
Full
1
1
2
2
4
8
8
50
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EQUIPMENT
Model
Shop
A,B
c
D
E
F
G,H
Gun
Cleaner
X
X
X
Booths
Crossdraft
X
X
Downdraft
X
X
981 e
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COATINGS
Type
Lacquer
Enamel
Urethane
VOC Emission
Potential
High
Varies
Low
Finish Quality
Low
Varies
High
S829
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TYPES OF COATINGS
100
c
0)
o
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VOC CONTROLS FOR
EMISSION SOURCES
Surface Preparation
- Use detergent rather than solvent
Coating Applications
- Lower VOC coatings
- Add-on Controls
Equipment Cleaning
- Automated Gun Cleaners
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CONTROL OPTION FOR
SURFACE PREPARATION
Reformulation to Lower VOC products
- Baseline: 6.4 Ib VOC/gal cleaner
- Lower VOC: 1.7 Ib VOC/gal cleaner
Emission Reduction
25 Ibs/yr —> 600 Ibs/yr
(smallest shop) (largest shop)
Increase in Materials Cost
$5/gallon ($1/fuil car)
985
12
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CONTROL OPTION FOR
COATING APPLICATIONS
REFORMULATION*
Coating
Type
Pretreatment
Wash Primers
Precoats
Primer Surfacers
Primer Sealers
Topcoats
Baseline
Technology
6.5
6.5
4.8 to 5.7
4.6 to 5.6
5.2 to 6.0
Overall Emission Reduction
Option 1
6.0
6.0
3.8
4.6
5.2
35%
Option 2
5.5
5.5
2.1
4.6
4.5
55%
*lb VOC/gal, less water
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EMISSION REDUCTIONS
AND COSTS
Option 1
Emission reduction
0.4tons/yr —> 2.5tons/yr
(smallest shop) (largest shop)
Increase in materials cost
$9/full car —> $0/full car
(smallest shop) (largest shop)
Option 2
Emission reduction
0.5 tons/yr —> 5 tons/yr
(smallest shop) (largest shop)
Increase in materials cost
$25/fuilcar —> $17/fullcar
(smallest shop) (largest shop)
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CONTROL OPTIONS FOR
COATING APPLICATIONS
ADD-ON CONTROLS
• Evaluated for Largest Model Shop Only
• Catalytic Incineration
- Emission Reduction:
from 11tons/yr to 0.6 tons/yr
(reduces 95% of coating application emissions)
- Cost: $155,000/yr
• Carbon Adsorption
- Emission Reduction:
from 11 tons/yr to 1 ton/yr
(reduces 90% of coating application emissions)
- Cost: $66,000/yr
• Biofiltration
- Emission Reduction:
from 11 tons/yr to 1 ton/yr
(reduces 90% of coating application emissions)
15
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ADDITIVES AND
SPECIALTY COATINGS
Include uniform finish blenders, adhesion
promoters, elastomeric materials, gloss
flatteners, and anti-glare/safety coatings
Necessary for unusual performance
requirements
Used in relatively small amounts to
improve or impart desirable properties
Recommend limiting use (<5 percent of
coating use by volume) and VOC content
(<7lbs VOC/gal, as applied)
16
-------
CONTROL OPTION FOR
EQUIPMENT CLEANING
• Use gun cleaning equipment designed to
reduce solvent consumption and
evaporation
• Emission Reduction
0.2 tons/yr —> 1 ton/yr
(smallest shop) (largest shop)
Costs
$36/year -
(smallest shop)
Savings of $800/year
(largest shop)
17
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VOC EMISSIONS AND COSTS IN
NONATTAINMENT AREAS*
Surface
Preparation
Coating
Applications
Option 1
Option 2
Option 2a**
Gun
Cleaning
Baseline
(tpy)
2,400
88,500
9,000
Emission
Reduction
(tpy)
1,500
25,700
53,500
68,500
5,500
Total
National
Costs
(million $/yr)
$33.35
$59.20
$122.00
$292.00
Savings***
Cost
Effectiveness
($/ton VOC
removed)
$2,230
$2,300
$2,280
$4,260
—
'Takes into account existing State and local regulations.
**Add-on control for Model Shop H (Carbon Adsorption).
'"Costs of $81,000 would be borne totally by small shops. Larger shops save
money by using a gun cleaner with national cost savings of approximately
$375,000/yr.
99118
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IMPLEMENTATION/RECORDKEEPING
Control
Technology
Type of
Standard
Recordkeeping
Lower VOC Surface
Preparation Products
Operational (process and
material change)
- Amount used
- VOC content of product
- Labeling
Lower VOC Coatings
Operational (process and
material change)
- Volume of coating,
catalyst, and reducer used
- Mix ratio
- VOC content of coating
- Labeling
Add-on Controls
Emission
- Performance records
Gun Cleaners
Equipment
- Amount of replacement
solvent used
- Amount of waste solvent
removed
- Documentation of proper
disposal
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OTHER APPROACHES
Decrease Collision Damage
Educate Consumers
- Cost of "Glamorous" Coatings
- Repair Costs
- Insurance Costs
Permitting Shops
- Identifies Shops
- Require Training
9S32Q
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COMMITTEE DISCUSSION ON EPA PRESENTATION
Ms. Mclntire suggested that references to decreasing
collisions and consumer education were beyond the scope of work
of the CTG. Mr. Berry responded that EPA is supposed to be
giving guidance to the States on how they can achieve emission
reductions. The EPA is looking at things States can do to
educate consumers, for example, by explaining that since
insurance companies do not inguire as to the color of a car,
those who own cars with glamorous finishes are being subsidized
by those who own cars with less expensive finishes. The EPA
feels that these recommendations are appropriate. Mr. Johnson
agreed that these recommendations are within the scope of the
CTG. Ms. Mclntire agreed on the need for consumer education, but
indicated that it seemed inappropriate to place it in a CTG on
automobile refinishing. Dr. Pinkerton commented that consumer
education seems like interference.
Ms. Mclntire suggested that the 5 percent limit for
specialty coatings be for an averaging period longer than a day
because, in some cases, a specialty coating may be the only job a
small shop has for an entire day.
Dr. Pinkerton inquired on the VOC component from refinishing
activities and whether the VOC's are included in the list of 190
Hazardous Air Pollutants. Ms. Ducey said some, but not all, are
included. Ms. Wyatt said that the industry is not on the list of
major sources because the facilities are too small; however, it
is being considered for inclusion as an area source.
Ms. Mclntire asked how the number of facilities in
nonattainment areas was derived. Ms. Campbell responded that the
number was population-driven. Ms. Mclntire suggested that EPA
verify the number.
Dr. Atkins inquired whether refinishing is driven by the
original equipment manufacturer (OEM) coating. Ms. Ducey said it
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is; colors must be matched, but the refinishing process uses
different paints because the cure temperature must be much lower.
Mr. O'Sullivan asked why there was no mention of transfer
efficiency (TE) in the CTG, especially if it is more cost-
effective than other control measures. The EPA responded that it
is an attractive option that will be encouraged, but a
quantitative requirement based on it will not be part of
recommended RACT in the CTG.
Mr. O'Sullivan suggested using Options 1 and 2 as a phased
approach. He questioned whether the cost-effectiveness figure on
slide 18 (for Option 2a) is average or incremental. Ms. Campbell
responded that it is average. Mr. O'Sullivan suggested showing
incremental cost-effectiveness from Option 2 to Option 2a. He
also commented that the recordkeeping requirements would be tough
for industry and that permitting should be avoided for small
facilities, although perhaps a standard permit could be
developed.
Ms. Mclntire hoped that placing VOC limits on products would
not place industry in a bad position regarding matching colors.
Mr. Taranto questioned the statement that limiting VOC levels may
make it impossible to match OEM colors, and whether it might
require that an entire vehicle be refinished rather than just a
portion. Mr. Berry responded that the OEMs could always
introduce colors that refinishers can not match, but while OEMs
are trying to go with "snazzier" coats and colors, EPA is
pressing the other way. Eventually, designers of original colors
and repair capabilities must come together to strike a balance
between VOC limits and color match.
A member of the audience asked how odor varied between
Options 1 and 2. Ms. Campbell did not know. The audience member
recommended odor as well as air toxics control because odor is
the major source of complaints for body shops. Mr. Berry
commented that add-on controls can mitigate odors.
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The EPA presentation was followed by six industry speakers.
These presentations are provided below in full text. After each
industry speaker, NAPCTAC members were provided an opportunity to
ask questions. These questions and the ensuing discussions are
summarized for each presentation.
9S6
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Industry Presentation #1
«•,
\National
^ 'Coatings
POSITION PAPER Association
OF THE NPCA AUTOMOTIVE REFINISH COALITION
CONCERNING
DRAFT AUTOMOBILE REFINISHING CONTROL TECHNIQUE GUIDELINE
**************
Introduction
The NPCA Automotive Refinish Coalition: The Automotive Refinish
Coalition was formed in 1988 under the auspices of the NPCA to
work for effective and nationally consistent VOC regulations for
the automotive refinish industry.
The active participants in the Coalition are the six national
manufacturers of automotive refinish paints and coatings: AKZO
Coatings, Inc.; BASF Corporation; E.I. du Pont de Nemours; Nason
Automotive Coatings; PPG Industries, Inc.; and the Sherwin
Williams Company. Collectively, these companies account for the
lion's share of the total volume of automotive refinish products
that are sold in the United States. These companies also provide
the majority of the training that is taken by individuals to
become proficient in the use of automotive refinish products.
The six individuals who represent these companies on the
Automotive Refinish Coalition collectively possess over 150 years
of experience in the industry. They therefore are in a
particularly good position to comment on the industry's products
and the underlying economics and operational requirements of
automotive refinish facilities.
The Coalition also has as adjunct members a number of trade
associations that represent user segments of the industry. While
the adjunct members generally support the positions taken by the
six manufacturer members of the Coalition, they have not had an
opportunity to review this position paper. Consequently, the
positions taken should be seen as representing only those of the
six manufacturers.
Objective of the Coalition; The objective of the Coalition is
the development of nationally consistent VOC regulations that
achieve significant, real and effective reductions in VOC
emissions from automotive refinish facilities while not imposing
unnecessary additional costs or losses in productivity on the
automotive refinish facilities.
Moving to lower VOC containing products will create enormous
productivity problems for automotive refinish facilities. Our
997
1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549
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concerns on this score are particularly strong because the
industry has a large population of small businesses.
Approximately 40% of the shops employ less than five individuals
and have sales volume of under $150,000 annually, according to a
1988 EPA study of the industry-
Effective VOC Regulations Must Recognize and
Incorporate Industry's Practices and Operational Realities
To achieve the objectives of significant reductions in VOC
emissions from automotive refinish facilities at the least amount
of unnecessary economic disruption to the industry, a regulatory
program must incorporate fundamental technical, operational, and
economic features of the industry.
Achieving Adequate Matching of Repair to OEM Finish: Achieving
an adequate repair that matches the existing coat so that the
repaired area is imperceptible is the central requirement of the
industry- Thousands of colors and coatings must be available for
all model years of the various car manufacturers to match the
many different features of thousands of original coatings, such
as their color, gloss, and durability, as well as the effects
that time and the elements have had on the OEM color and finish.
All of this must be accomplished at facilities with far less
sophisticated equipment, under much more difficult and
uncontrolled circumstances than exist at the original equipment
manufacturers' facilities.
Systems Nature of Today's Products; Today's products are
provided by individual manufacturers in the form of chemically
complex interrelated components to a single system. The
components of a particular repair system must be used only within
the system of the particular manufacturer and pursuant to the
manufacturer's instructions to ensure that the refinish job will
not fail.
Composite Calculation for Multiple Coat Topcoats is Essential;
The use of multiple coats involving a base coat for color and
clear coats for appearance and protection as well as in some
cases a midcoat is the predominate original equipment
manufacturer (OEM) topcoat system. The appearance of these OEM
topcoats must be matched by the automotive refinish industry and
consequently, the industry must use multiple coats in a topcoat
system.
-------
Comments Concerning Regulatory Approaches
The RACT VOC Limits of the California Guideline for the Industry
Should be Selected as the RACT Limits for the CTG
The purpose of the CTG is to establish technology that is the
presumptive norm for "reasonably available control technology"
(RACT) which must be implemented by states in their ozone
nonattainment areas. EPA has defined (and Congress has accepted)
RACT to mean: "The lowest emission limitation that a particular
source is capable of meeting by the application of control
technology that is reasonably available considering technological
and economic feasibility. RACT for a particular source is
determined on a case-by-case basis, considering the technological
and economic circumstances of the individual source. (44 Federal
Register 53761, 53762 (September 17, 1979))
On the basis of this standard — a standard that emphasizes the
economic and technological feasibility of control technologies in
light of technological and economic circumstances of the
sources — the VOC limits that have been established by
California's Air Resources Board's Automotive Refinish Guideline
for RACT under California's Clean Air Act (which has a much
tougher standard and program for ozone attainment than the
federal law) should be RACT for the national program. (See
attached chart for the California Guideline RACT limits.)
While the terms "reasonably available" and "feasibility" are not
defined by the EPA, an ordinary dictionary definition of
"feasible" is something that is "capable of being used or dealt
with successfully;" "available" has been defined in a manner
especially relevant to this discussion as "present in such
chemical or physical form as to be usable;" and "reasonably"
has among its ordinary meanings "moderate, fair, and
inexpensive." When the meanings of these terms are coupled with
the requirements of "economic and technological feasibility" and
the additional requirement that the feasibility of the control
technology be ascertained on the basis of the "economic and
technological circumstances of particular sources," then
whatever else RACT means, it certainly cannot mean the
imposition of technology-foreing standards on existing sources.
The California RACT limits have much to recommend them for
adoption in the CTG.
First, by actual implementation in automotive refinish
facilities, they have been proven to be currently "reasonably
available" and "technologically and economically" feasible.
Second, they have been established by the toughest clean air
program in the country. In this connection, we note that the
3
999
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California Clean Air Act has a much more stringent ozone design
value of .09 ppm as compared to the federal standard of .12 ppm.
The attached chart represents a comparison of VOC reductions that
could be achieved by implementing the California Guideline's RACT
limits.
According to the Study's Own Findings. Option 1 and Option 2
Limits Are Technology-Forcing Standards; They. Therefore. Are
Completely Inappropriate for the CTG
By the study's own statements, Options 1 and 2 represent
"technology-forcing" VOC limits, requirements that are not
currently "reasonably available" as that term is defined by the
EPA. Therefore, these options do not qualify as RACT. Moreover,
if the base coat/clear coat composite calculation method is not
employed, then the limits specified for topcoats under both
Option 1 and Option 2 are not only "technologically and
economically infeasible" for the "particular sources" of
automotive refinish facilities, they are absolutely impossible to
achieve with today's technology.
The study indicates that lacquer product systems are still widely
used by many of the smaller shops that do not have spray booths.
(See pages 2-7, 2-20 through 2-25 of the study.) The study also
assumes that such shops constitute approximately 30% of the
industry. (See Table 2-1 at page 2-22.) Moving these shops away
from lacquer products to other more difficult to use and slower
drying products will be difficult and very costly. The
unmistakable implication of the topcoat limits of Options 1 and 2
is that a large number of the industry's smaller shops will be
put out of business. The study estimates that the cost of a
spray booth would be approximately $30,000. We believe that this
estimate is low. And most of these shops are currently grossing
at most $150,000 per year. Few if any banks, especially in
today's economic climate, would lend the amounts needed for such
a capital outlay to the smaller shops. Consequently, topcoat
limits of Options 1 and 2 which would prevent the use of any
lacquer system do not represent a "currently" "reasonably
available control technology" as judged on the basis of
"technological and economic feasibility" of these "particular
sources."
The study also states that, "Option 1 VOC limit had the reported
disadvantage of poorly matching OEM colors (especially
metallics), indicating that they are best suited for complete
vehicle refinishing jobs." (See page 3-4.) In view of the fact
that the study also finds that the "... the OEMs use metallic and
*pearl' coatings on at least 50 percent of all new vehicles....";
it should be clear that the Option 1 VOC limits do not constitute
"reasonably available control technology" for this industry.
Establishing the Option 1 or 2 limits, according to the study's
-------
own findings and conclusions, would in effect mandate that a
larger proportion of the repairs be accomplished by complete
refinish jobs. This would necessarily result in the emissions of
more, not less, VOCs and would fail to achieve the fundamental
objective of RACT — achieving reasonable further progress
towards attainment. Additionally, there is the question of
whether establishing VOC limits that "poorly match OEM colors"
for 50% of the vehicles the industry repairs constitutes a
"technologically and economically feasible" control technology
for an industry that has as its sole reason for being the ability
to make repairs so that the repair is imperceptible.
The study also contains a number of misleading assumptions
concerning the VOC emissions that should be associated with the
industry's products and operations. The first of these involves
assuming that the VOC content of products that are supplied to
areas which currently have regulations constitute the baseline
"current technology" of the industry's products that are
generally used in the United States. (See Table 3-1 at page
3-6.) In fact, the majority of the products supplied by the
manufacturers are to areas for which no VOC limits for their
products exist, including the vast majority of current ozone
nonattainment areas. Defining baseline technology as the study
does would lead to a gross understatement of the contributions
in VOC reductions that properly should be attributed to this
industry introducing lower VOC containing products to areas that
heretofore have not required lower VOC containing products. The
Act's new requirement for reducing by 15% overall VOC emissions
in the top four categories of ozone nonattainment areas by 1996
will place extraordinary pressures upon all sources to reduce
their fair share of VOC emissions. Thus it is essential that the
CTG accurately characterize the existing VOC emissions from this
industry in these areas to ensure that it is not tasked with
regulations that exact an unreasonable contribution in VOC
emissions reductions.
Additional misleading statements and assumptions in the study
concern the following subjects: the statement concerning current
usage of coatings that implies that all coatings material
supplied to refinishers are in fact applied, when approximately
20% — 25% in practice is wastage and is disposed of by
incineration in which there is no release of VOCs; overstatements
of the required or recommended film thicknesses; and
overstatements of the paint consumption in each of the coatings
categories. These are more fully discussed in the submission
from BASF.
We anticipate the argument that since the California Guideline
1992 limits are just around the corner and that since some of
these limits are more stringent than comparable limits in Option
1, the manufacturers should be able to meet the limits of Option
1 nationwide if they can meet the California 1992 VOC limits in
California. In answer to such an argument, we point out that the
1001
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products that are needed to meet some of these limits, especially
the topcoat limit, are still not yet at a stage of development
that would allow the manufacturers to introduce them into
facilities without substantial expenditures in time and
resources. These products will require the use of spray booths,
which the study itself notes are not widely used by the smaller
shops which makes up about 30% of the industry. Moreover they
will require the use of drying equipment, because the products
will be .mostly waterborne products with substantially longer
drying times. In order to maintain today's levels of
productivity in terms of the number of vehicles that are
completed substantial expenditures for drying equipment will be
required.
Finally there is a question of scale involved here. It should be
noted that the California 1992 limits will be confined only to
certain air quality districts in California. While the
manufacturers may have sufficient resources to weather the
problems and expenditures that will be associated with
introducing these products into a limited number of areas in
California, imposing similar requirements nationwide results in
an effect on the manufacturers that certainly qualifies as
"economically infeasible."
We realize that the EPA is interested in crafting a GTG that
accurately reflects what can be accomplished by the industry at
the time the CTG is published and that it is confronted with the
difficulty of a moving target in the technologies. The six
manufacturers have expended literally tens of millions of dollars
thus far in efforts to develop lower VOC products and the EPA is
right to anticipate that these efforts will continue. But this
problem of RACT being overtaken by new developments is addressed
in the newly amended federal Clean Air Act which now requires
that the EPA periodically revisit CTGs to determine if technology
has moved ahead of existing CTG standards. We'suggest that this
is the only appropriate process recognized by the Act for
introducing technology-foreing factors into developing CTGs.
Requiring technology-forcing limits in the CTG itself is
completely at variance with the essential "reasonably available"
nature of a RACT standard.
We have another suggestion by which this current effort to
determine an automotive refinish CTG could avail itself of new
technologies that might be available at the time this CTG is
finalized. If this CTG development process takes until 1993 to
be finalized, it is possible that the experience gained in
meeting the California Guideline's 1992 limits in California will
demonstrate by then that the Option 1 .limits and perhaps some of
the California 1992 limits are in fact "reasonably available" in
terms of their "economic and technological feasibility" for
national implementation. We note, however, that, with respect to
the California 1992 limits, the industry at the present time
1002
-------
does not have a sealer that would meet the limit specified for
this coating. Because of this and other potential problems of
introducing such advanced systems nationwide, at the present we
believe that a lead time for implementing such limits would be
needed, e.g., implementation in 1994 or 1995.
The Necessity of Base Coat/Clear Coat Averaging For Determining
the Topcoat Limits
The multiple coat system of topcoats is the current predominate
topcoat technology of the automotive manufacturing industry and
the refinish industry must be able to match these topcoats.
Using a composite calculation for the VOC content of the base
coat and clear coat in a topcoat system to determine compliance
with the topcoat VOC limit is dictated by the actual day-to-day
"technological and economic circumstances" and practices of the
industry.
A statement of the study which may account for the failure of the
CTG Model Rule to include a base coat/clear coat composite
calculation method is an apparent misunderstanding of the basis
for weighting base coats and clear coats at a ratio of 1 for base
coats to 2 for clear coats. The ratio is based upon the actual
usage of the industry. It is the industry experience that the
volume of base coat paint that is used for any given repair is
approximately on half the volume of clear coat that is used. In
this connection we refer you to the information that has been
provided by the BASF Corporation which is based upon the actual
usages at an automotive refinish type of operation at the Saturn
General Motors plant and by the Sherwin Williams Company. In
fact that experience indicates that the ratio is higher, e.g.,
for 1 gallon of base coat, 2.3 gallons of clear coat are used.
The study assumes that because clear coats are a higher solids
product than are base coats, then the volume of clear coat
material that is needed to repair the are covered by the base
coat should be twice the volume of base coat material. The
major reason that the industry generally uses twice the amount
of clear coat material as it does base coat material is the need
to achieve adequate color and finish match for spot repairs that
requires that the clear coat in general be extended far beyond
the area covered by the base coat. About 90% of the automotive
refinish work that is done is spot repair.
The Systems Nature of the Industry's Products
Because the chemistry of the individual components of a repair
system is highly interdependent, the components of a particular
manufacturer's system must be used according to its instructions
and cannot be interchanged with the products of another
manufacturer. The systems nature of today's repair products has
two very important implications for a regulatory system that
limits the VOC content of the products. First, regulators can
1003
-------
have a great deal of confidence that refinishers will not attempt
to match relatively higher VOC components of one manufacturer's
repair systems with those from another and that therefore the VOC
levels associated with a particular system will be complied with.
Secondly, the regulations cannot simply select the lowest VOC
components of the available repair systems and dictate that these
components be incorporated into every repair system.
and in the right amounts. As a recent article from an automotive
refinishers professional magazine points out:
[T]here is no margin for error in applying or mixing today's
products. The paint, company chemist was able to create a
product to suit, but only if you do exactly as he says. Not
only must the painter combine the correct solvent, catalyst
and topcoat in the correct percentages, but it must be
applied over the correctly mixed undercoats at the correct
time... There is only one right way to use today's
finishes; exactly according to directions and using only one
brand.
Auto refinishers will not act as their own chemists; they will
follow the manufacturers' instructions or risk a failed job
without the protection of a warranty.
Another feature of the industry that supports the conclusion that
automotive refinishers will comply with the VOC limits specified
for products is the VOC compliance instruction material and the
training that is supplied by the manufacturers to users of their
products.
The Need for Specialty Coatings
It also is essential to recognize the need for relatively higher
VOC containing specialty coatings. These products constitute a
very small percentage of the products used by the industry but
they are essential to effectively accomplishing certain repairs.
An important example of these are "uniform finish blender"
specialty coatings to make spot repairs. This specialty coating
blends the repaired area in with the surrounding original finish
to match all facets of its appearance, including color, metallic
orientation, texture, and appearance. Greater VOC emissions
would occur if refinishers do not have the ability to perform
spot repairs because they would be required to paint an entire
panel of the vehicle or the entire vehicle itself in order to
achieve acceptable results.
We recognize that the model CTG includes the category of
"specialty coatings." But its characterizing them as being
"reportedly" needed for unusual job performance requirements,
however, concerns us because that implies that the need of these
products is debatable. The special role of specialty coatings
should be emphasized by the CTG. It should not be implicitly
1004
-------
questioned by the CTG which might invite states to modify the CTG
by removing the category.
We also recommend that the California Guideline's definition of
specialty coatings should be adopted. The definition does not
limit the type of coatings that can fall into this category but
restricts the coatings to 5% the total volume of coatings applied
by an automotive refinish facility. This approach allows for the
development of additional specialty coatings and the 5%
restrictions ensures that the category will not be abused.
The General Use of HVLP gpray Guns Results in Significant
Reductions of VOC Emissions and Should be Encouraged
The efficiency of transferring coatings to the vehicles has been
greatly improved by the use of high volume, low pressure (HVLP)
spray guns. The resulting VOC reductions that accompany the
reduced amount of coatings material that is required because of
the improved transfer efficiency should be explicitly recognized
by the regulations. To do otherwise deprives this industry of
having credited to it significant VOC reductions that in fact
result from the use of HVLP spray guns. The unwillingness of the
EPA to explicitly recognize and to credit VOC reductions
associated with the use of the equipment is a hidebound adherence
to notions concerning "quantification" and "replicability" of VOC
emission reductions. These principles were established for a
regulatory regime that focused on well-heeled and richly staffed
large stationary sources which lent themselves to such precise
demands for crediting VOC reductions. The 1990 amendments to the
law, however, require the regulation of much smaller sources and
therefore the EPA's VOC emissions reduction accreditation
principles must be retailored to measure the effectiveness of
regulatory controls that are appropriate for the much smaller
sources.
As the study notes, appropriate training has a great deal to do
with the efficacy of HVLP use. In this connection, it should be
recognized that extensive training is provided in this area by
the manufacturers of automotive refinish coatings and others.
Further, aside from the regulatory requirement to use such
equipment, autorefinish facilities have a very strong economic
incentive to use the equipment to reduce their consumption of
coatings.
It also should be noted here that the study seems to assume a 35%
transfer efficiency for the conventional spray gun but is
unwilling to assume any transfer efficiency for the HVLP. This
is anomalous in that any problems that are associated with
achieving effective transfer efficiency with the HVLP spray gun,
such as variability in operator use and the shape of the object
being coated, also apply to conventional spray guns.
1005
-------
The experience of the Coalition is that the use of HVLP spray
guns results in reductions of 20% — 45% in materials usage and
some credit for the resultant VOC reductions should be given.
Add-On Controls
The various engineering add-on control technologies identified by
the study for facilities would be cost prohibitive and or
technologically infeasible for the great majority of automotive
refinish facilities to adopt at this time. Nonetheless, the
regulations should recognize such controls as voluntary
alternative control techniques that could be used in lieu of
lower VOC containing products. The technology of add-on controls
could improve in the near future, perhaps rapidly, and they
could come to represent cost-effective alternative compliance
methods.
Conclusion
The objective of the CTG is to establish a guideline for what is
the presumptive norm for "reasonably available control
technology" (RACT) under the federal Clean Air Act. In
developing such a guideline, the "reasonableness" of the
technology is to be considered as well as both its
"technological" and "economic" feasibility. On the basis of
these criteria and our knowledge of the industry — the available
coatings technology and the operational and economic requirements
of automotive refinish facilities — we believe that the VOC
limits specified for RACT in the California Guideline should be
the limits established by the CTG. The adoption of these limits
from a program that is much tougher than the federal program will
ensure that the industry contributes more than its fair share of
VOC emissions reductions in the nation's ozone nonattainment
areas. We also believe that specialty coatings must be
explicitly recognized as an essential technology for the industry
to achieve VOC emissions reductions. Further, it is absolutely
critical that the multiple coat composite calculation technique
for determining compliance with VOC topcoat limits be recognized.
This is the way the industry applies the topcoats and it is the
only way that VOC limits for increasingly waterborne topcoats can
be met. The contributions made by HVLP spray guns should also be
recognized by the CTG. Finally add-on controls should be
recognized as a voluntary alternative compliance method.
The possibility that the Option 1 or even some of the California
Guideline's 1992 VOC limits may be demonstrated to be "reasonably
available" by the time the CTG is finalized in 1993 is also worth
considering. The six manufacturers would concur in such an
approach provided that before the limits are adopted as part of
the CTG, the technology has in fact been shown to be reasonably
available and that an appropriate lead time is afforded (e.g.,
until 1994 or 1995) to ensure that the products in fact are
"reasonably available."
10
1006
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DRAFT CTG
COMPARISON OF VOC EMISSIONS REDUCTIONS
GARB'S GUIDELINE
Baseline
Coatina Cateaorv VOC*
Pretreatment Wash
Primers & Precoats 6.5
Primer Surfaces 4.8 - 5.7
Primer Sealers 4.6 - 5.6
Topcoats*** 5.2 - 6.0
Surface Cleaning 6.4
Enclosed Equipment
Cleaning 6.7
Specialty Coatings 7.0
Transfer Efficiency 35%
DRAFT CTG
Reduction Achieved -0-
% of
Total Coatings
Option 1 Ootion 2 CTG CARB Coatina Cateaorv
Pretreatment Wash
6.0 .15% 5.5 .31% 2% . 1% Primers
3.8 4.0% 2.1 7.6% 12% . 12% Primer/Primer
Surfaces
4.6 0.9% 4.6 0.9% 5% . 5% Primer Sealers
5.2 7.7% 4.5 14.5% 58% . 17% Topcoats***
Iridescent***
1.7 5.9% 1.7 5.9% 8% . 8% Surface Cleaning
Enclosed Equipment
85% 0.8% 85% 0.8% 10% . 10% Cleaning
7.0 0.0% 7.0 0.0% 5% . 5% Specialty Coatings
35% 0.0% 35% 0.0% . Transfer Efficiency
CARB GUIDELINE
18.6% 30.0% . Reductions Achieved
Baseline CARE'S
VOC RACT
6.
6.
6.
6.
6.
6.
6.
6.
7.
7
7
7
7
7
8
7
7
0
25%
6.5
6.5
6.0
6.0
6.0
6.0
1.7
88%
7.0
45%'
-0-
0
0
2
2
3
8
6
0
2
.1%
.1%
.3%
.3%
.2%
.7%
.0%
.8%
.8%
0.0%
26
.3%
GARB'S
1992 Limits**
6.5
6.5
2.8
3.5
5.0
5.0
1.7
98%
7.0
45%'
0
0
12
4
22
19
6
0
2
.1%
.1%
.6%
.3%
.8%
.5%
.0%
.8%
.8%
0.0%
69
II
.0% |
*Baseline VOC set on controlled areas emission survey data. Should be based on uncontrolled emissions survey data.
**Technology forcing limits that can be added to CTG in 1994 - 1995 once technology has been demonstrated in California in 1992 -
1993.
***VOC limits based on composite multi-stage topcoat calculations.
l.*5*/z5x = *••" factors applied to VOC reduction categories in column expect for enclosed equipment cleaning and surface cleaning.
-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
Karl Schultzf National Paint and Coatings Association,
Automotive Refinish Coalition (See attached Presentation #1)
Dr. Pinkerton noted that Mr. Schultz's estimate of 40
percent of shops having less than five employees did not agree
with the CTG's figure of 10 percent. Mr. Schultz said his
information was from a magazine survey and he thought it was
accurate. He suggested that the model shop analysis might
mislead States in that it misrepresents the industry (i.e.,
lacquer use may be underestimated for a given model shop). He
noted that shops in this industry can not be pigeonholed; for
example, there are very small shops that specialize in high-
quality work. Mr. Hise noted that if the magazine survey showed
shops with 5 or less employees, then the model shops could match
40 percent because they show a range of employees. Ms. Ducey
commented that the number of employees is not used in EPA's
analysis, and does not have to be shown in the CTG.
Dr. Pinkerton asked whether the Coalition agreed with the
estimate of 100,000 tons per year of VOC being emitted from body
shops in nonattainment areas. Mr. Schultz said he had not seen
that estimate before, but guessed that it was probably close.
Dr. Pinkerton asked what national emission reductions would their
RACT (and 1992 limits) recommendations achieve. Mr. Schultz said
they had not been calculated. Mr. Arkell asked why, on the table
Mr. Schultz provided, the percent reductions in emissions with
CARB's 1990 RACT limits and 1992 limits are higher than EPA's
Option 1 and Option 2 percent reductions. Mr. Schultz responded
that the differences in solids content per gallon paint were not
taken into consideration in their estimates. The CARB values
take into consideration a TE of 25 percent for both the baseline
and the 1990 limits, and a TE of 45 percent for the 1992 limits.
1
1008
-------
Mr. Arkell questioned whether the major factor in the
difference in percent reductions is the use of different baseline
values. Mr. Schultz felt that EPA's baseline is based on
controlled limits, and the Coalition's estimated baseline values
are higher. He strongly disagreed with EPA's figure. Mr. Hise
asked if the baseline values used by the Coalition were based on
1990 data. Mr. Schultz said 1988 data were used. An audience
member commented that the figure was based on sales, not
consumption. He said the 1990 VOC coating data are not different
from the 1988 data, but sales have fallen.
Dr. Atkins asked if Mr. Schultz had said that compliance
with the 1992 GARB rules would require spray booths. The answer
was yes; the Coalition recognizes that shops without spray booths
would have difficulty using some coatings and that this will be a
huge adjustment for small shops.
Mr. Arkell questioned whether the California rule requires
65 percent TE. The answer is yes. Mr. Arkell than commented
that the discussion seems to keep coming back to TE, even though
EPA has said that it is too difficult to quantify. He suggested
EPA look at it again. Perhaps a percent reduction credit could
be given for TE. He also inquired that if EPA can not quantify
TE, how is California doing it. The response was that they can't
and are working on that problem now. California recognizes that
it is a difficult problem, but they also know that success would
result in reductions in VOC's. Mr. Dennison commented that
California defaulted to high-volume low-pressure (HVLP) spray
equipment, and said that other types of spray equipment would
have to demonstrate that they could achieve 65 percent TE.
Subsequently, manufacturers of other types of spray equipment
have petitioned, and the State has had to defend the 65 percent
TE requirement which relies on a laboratory test procedure.
Mr. Schultz noted that another reason for strongly
suggesting that EPA use the California standards is because this
industry is a highly spread out, distribution-based industry and
it must have uniform standards. A can of paint can be in the
system for 3 to 5 years. Multiple standards in the U. S. would
2
1009
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be unmanageable,-and the Coalition feels the California standard
is stringent enough to be a national standard.
Mr. Jordan asked Mr. Schultz to clarify whether he was
recommending that EPA adopt the 1992 California limits. Mr.
Schultz responded that the Coalition is recommending that EPA use
the California RACT limits. The 1992 limits are not "reasonably
available." The Coalition would support the 1992 limits after
the products have been demonstrated successfully in California.
From a legal standpoint, the Coalition is concerned that if the
CTG becomes law (with the 1992 limits as RACT), and the limits
are not achievable for all colors, States would not be able to
relax their State Implementation Plan (SIP) requirements. He
suggested that if the CTG requirements were different from
California's, the coating manufacturers would be forced to
recommend that States ignore the CTG and use California's limits.
Mr. Berry commented that the definition of RACT that the
Coalition keeps using is not complete. The RACT does have a
technology-forcing aspect.
Citing the fact that specialty coatings need a higher VOC
content, Mr. Dennison asked whether the coating manufacturers had
a time frame for reducing the VOC content of specialty coatings.
Mr. Schultz explained that the manufacturers formulate these
products at 7 Ibs VOC/gal for their unique properties and
applications. If VOC content must be reduced, solids must be
increased and the paint layers could not be applied thinly
enough. Mr. Dennison asked whether shops vary in their specialty
coating use. Mr. Schultz replied that 99 percent of shops would
not exceed the 5 percent cap on their use, but there would be
some small specialty shops, such as van-converters, that might
have trouble with the limit.
Mr. Dennison inquired about the recordkeeping burden.
Mr. Schultz said that the Coalition feels that it would be real
drain for small shops. The 2-3 hours per day required for
recordkeeping would be unproductive time. Mr. Dennison asked
that if EPA did follow California's lead, would manufacturers be
willing to participate in some type of quantification program.
1010
-------
Mr. Schultz responded that they do already. The material safety
data sheets (MSDS) show VOC level. Mr. Dennison asked whether
the MSDS also show VOC content less water. The response was yes.
Ms. Sheiman commented that recordkeeping and public
disclosure of emissions (not already done by this industry) might
go a long way in motivating voluntary compliance by shops and
lead to creative ways of reducing emissions.
Mr. O'Sullivan asked if manufacturers would consider
developing some type of industry-wide certificate program for
operator training. Mr. Schultz replied that they are already
looking into this. The industry does not support distribution of
a product to persons who are not trained in its use. The
industry is looking at how best to certify operators and the need
for training materials.
Mr. Berry inguired about how the OEM's ensure that colors
can be matched by refinishers. Mr. Schultz's answer was that OEM
colors are selected 3-4 years in advance, and properties such as
their handling and consistency are checked. The colors are also
analyzed for their repair capabilities. They do sometimes find
that a color can not be matched in refinishing. Mr. Berry
suggested that the worst thing that could happen (from selection
of any limit) is that it might restrict the designer's future
color choices. Further, some existing cars would have to be
completely repainted rather than spot repaired because the color
could not be matched. Mr. Schultz replied that the entire car
may not have to be completely repainted, but at least a larger
area would have to be repainted.
1011
4
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Industry Presentation #2
BASF Corporation BASF
Automotive Reflnlshlng
November 1, 1991
Mr- Bruce C. Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Dear Mr. Jordan:
On behalf of BASF Corporation, I am submitting the following com-
mentary regarding the September 27, 1991 Draft of "Automobile Re-
finishing Control Techniques Guideline", which you indicate will be
the key information source for determination of Reasonable Avail-
able Control Technology (RACT), and subsequent development of con-
trol technique guidelines for regulation of the volatile organic
compound (V.O.C.) emissions from the Automobile Refinish industry.
In general, we feel the draft represents an honest attempt to por-
tray our industry and does a good job of describing the refinish
process. However, there are what we feel to be inaccuracies that
tend to grossly overstate the industry's contribution to V.O.C.
inventories that I would like to address, plus present data to you
that will substantiate the use of numerical averaging of V.O.C.
calculations for multi-stage topcoat systems.
Major Issues
I. The September 27, 1991 Draft does not acknowledge the use of
numerical averaging of multi-stage topcoat systems for deter-
mination of V.O.C. content. Rationale given in the text (Page
3-8) is that the author felt a "potential" problem may exist
with the equations used to determine the average V.O.C. con-
tent of the combined coatings, in that twice as much clearcoat
as basecoat may not be needed to cover a given surface area.
Many current state regulations acknowledge the basecoat/clear-
coat averaging concept and utilize the following equation for
calculation of a two-stage topcoat system.
1012
19855 West Outer Drive Suite 401 East Dearborn. Michigan 48124 (313) 561-9100
-------
Page
V.O.C. r = V.O.C. "*" 2 V.O.C.
Where: V.O.C. T = Total V.O.C. Content
V.O.C. BC = V.O.C. Content of Basecoat
V.O.C. cc ~ V.O.C. Content of Clearcoat
The author of the Draft ; makes the erroneous assumption that this
equation was derived from the ratio of the dry film thickness of
the two components (see Page 3-7). In fact, the ratios are not
based on dry film, but rather on paint consumption ratios of two
parts by volume of clearcoat to one part of basecoat.
BASF states in its product literature for basecoat clearcoat sys-
tems to apply the following on each component:
APPROXIMATE
NUMBER FILM
COATS THICKNESS
Basecoat 2-4 Light Coats 0.7 Mils
Clearcoat 2-4 Heavy Coats 2.5 Mils
Material usage ratios under these conditions actually result in a
higher than 2:1 ratio. This can be substantiated by data collected
by General Motors at their final line repair area of their Saturn
assembly plant in Spring Hill, Tennessee. The repair facility at
Saturn is basically a "refinish shop" and utilizes our Diamont
refinish basecoat/clearcoat system. Material usage at this line is
recorded on a "material applied" basis at application. The data
below represents a three month usage study conducted earlier in
1991.
Basecoat/Clearcoat Applied
39.15 Liters Reduced (RFU) Basecoat
89.98 Liters Reduced (RFU) Clearcoat
This yields a clearcoat/basecoat usage ratio of 2.30:1, which is
very favprable compared to the 2:1 ratio for theoretical calcula-
tions in B.A.A.Q.M.D. Rule 45, CARS SCM recommendations and other
state regulations.
To further substantiate basecoat/clearcoat usage ratios, BASF re-
cently did a study on car shells at our Whitehouse, Ohio Applica-
tion Facility. The study was conducted using both conventional air
assisted spray guns and the more efficient HVLP gun. Vehicles used
in the study were Caprice Classics, which are representative of a
large size car. The study also compared usage ratio for complete
and spot repairing. The study utilized a high solids (4.4 V.O.C.)
clearcoat with a low solids (6.4 V.O.C.) basecoat so that the worse
case usage ratios would be developed.
1013
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Page -3-
Results
Complete Repainting
A. Conventional Air Assisted Gun
Basecoat -
Guq
Basecoat Application
Basecoat Material Usage -
Clearcoat -
Clearcoat Application
Clearcoat Usage
Film Thickness -
B.
Diamont Blue Metallic re-
duced 1:0.75 with BR60 re-
ducer
Sata Jet Gravity feed set
at 85 PSI
Two medium coats to hiding
0.38 gallons
Diamont DC90 2:1 with DH51
hardener
Two wet coats
0.83 gallons
SIDE
HOOD
Basecoat
Clear
1.0 Mils 0.7 Mils
2.9 3.5
Volume Ratio Clearcoat : Basecoat = 0.83:0.38 = 2.18:1
HVLP Spray Gun
Basecoat - Diamont Blue Metallic re-
duced 1:0.75 with BR60 re-
ducer
Gun
Basecoat Application
Basecoat Material Usage
Clearcoat
Clearcoat Application
Clearcoat Usage
Film Thickness
Basecoat
Clear
Mattson DC set at 6.0 PSI
Two medium coats
0.32 gallons
Diamont DC90 2:1 with DH51
hardener
Two medium coats
0.69 gallons
SIDE HOOD
0.6 Mils
2.1
2.7
0.6 Mils
2.9
3.5
1014
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page -4-
Volume Ratio Clearcoat ; Basecoat = 0.69:0.32 = 2.16:1
2. Spot Repair
One of the most widely used technique for painting a panel
with minor damage is to "spot" repair the area. In the case
of spot repair, one of the most critical qualities the re-
finish coating must possess is the ability to be applied in
such a fashion that results in the repair area being undetect-
able from the surrounding original finish in all facets of ap-
pearance; including color, metallic orientation, texture and
gloss. The most popular procedure for spot repairing a base-
coat/clearcoat finish is to color coat only the portion of the
panel that was damaged and then, in order to maintain gloss
and texture, clear coat the entire panel.
The following technique was used to simulate a "spot" repair
on a vehicle at our Whitehouse, Ohio facility.
A. Spot prime a 2 x 2 foot area on a rear quarter panel
to simulate the damaged area.
B. Color coat with basecoat the "repair" area, blending
out into undamaged portion of the panel.
C. Clearcoat the entire panel.
The following represents material usage of basecoat and clear
for the above process.
Basecoat - Diamont Blue Metallic re-
duced 1:0.75 with BR60
Clearcoat - DC90 clear 2:1 with DH51
Basecoat Usage - 0.0186 gallon
Clearcoat - 0.068 gallons
Clearcoat: Basecoat Usage = 0.68:0186 = 3.61:1
1015
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Page -5-
CONCLUSION
For BASF, and probably all other coating suppliers, the 2:1
ratio of clearcoat to basecoat used on calculations for com-
bined basecoat/clearcoat V.O.C. actually represents an under-
statement of clearcoat usage. Since, to my knowledge, no
commercial basecoats meet the topcoat V.O.C. requirements of
either Option I (5.2 V.O.C.) or option II (4.5 V.O.C.), we
feel the topcoat V.O.C. requirements in the proposal without
allowing basecoat/clearcoat averaging do not represent reason-
ably attainable control technology. The proposal should
therefore either be modified to allow averaging, or the V.O.C.
standards for topcoats should be raised to minimum of 6.2
pounds/gallon.
II. Option II, even with basecoat/clearcoat averaging allowed,
does not meet the criteria of Reasonably Attainable Control
Technology (RACT) in the area of Pre-Treatment Wash Primer and
Topcoats, as the proposal is based on unavailable technology
in both areas.
o Pre-treatment requirement of 5.5 pounds/gallon V.O.C. is
not available. Current technology is in the 6.0-6.5
range and chemistry used for this type of product does
not readily lend itself to lower levels.
o Topcoat V.O.C. of 4.5 pounds/gallon is not currently at-
tainable for either metallic single stage colors or
multi-stage topcoat systems even with numerical averaging
allowed for the multi-stage systems.
Recommendation
Option II does not represent RACT and therefore should not be
considered as an alternative. Option I is acceptable, pro-
vided multi-stage V.O.C. averaging is allowed.
III. Several questionable assumptions were made in determination of
Emission Estimation Techniques in Section 4.0. These lead to
a gross overstatement of material usage and subsequently leave
one to believe the industry contributes far more V.O.C. than
it actually does.
A. Section 4.2.1 (Page 4-3) states "The assumption is made
that all coating mixed for the job is sprayed and there-
fore no emissions are attributed to waste paint." The
last thing a painter wants to happen is to run out of
paint in the middle of a job. As a consequence, standard
practice is to reduce at least 25% more material than
what is required and to scrap the overage. Since by law
the remaining material is a hazardous waste, it is usual-
ly disposed of by incineration and consequently, does not
contribute to V.O.C. in the atmosphere.
1016
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Page -6-
B. The film thickness stated in Section 4.2.1 (Pages 4-5)
are overstated compared to what BASF recommends for fin-
ishes in each category. The following represents our
recommendations compared to what is stated in the draft.
FIIH THICKNESS REQUIRED
DRAFT BASF RECOMMENDATION
Pre-Treatraent/Pre-Coat 1.0 Mils 0.3-0.5 Mils
Primer Surfacer 2.25 Mils 2.0 Mils
Primer Sealer 1.75 Mils 1.0-1.5 Mils
Topcoat 3.5 Mils 2.0-3.5 Mils
C. Table 4-2 (Pages 4-6) grossly overstates paint consump-
tion for each of the coating categories.
1. The table suggests 1.6 gallons of pre-coat or pre-
treatment primer is used for a complete paint job.
By definition pre-treatment and pre-coat are only
used over bare metal areas of the job. Unless the
repaint is over a completely stripped surface, only
3-6 oz. would normally be used. Even if the job was
complete bare metal, pre-treatment/pre-coat usage
would not exceed 0.4 gallons!
2. Table suggests primer surfacer usage to be 1.2-2.0
gallons for complete paint job. Normal practice is
to only apply over poor substrate. Under this con-
dition only approximately 8 oz. would be utilized.
If complete job were to be primed usage would be
0.5-1.0 gallons, depending on quality of primer
used.
3. Table suggests sealer usage of 0.8-1.5 gallons.
Normal practice would be to use approximately 0.25
gallons of sealer on a complete repaint.
4. Table suggests 2.2-3.8 gallons of topcoat consumed
for a complete paint job. Actual usage is 1.2-1.75
gallons.
5. Baseline data for topcoat paint consumption given in
Table 4-2 (Pages 4-6) is contradictory to that given
in Table 4-3 (Pages 4-10). Topcoat usage per car in
Table 4-2 is 2.2-3.8 gallons. Table 4-3 states 1.8-
3.8 gallons.
Conclusion
Data presented in Section 4.0 is not accurate and grossly
overstates the baseline V.O.C. contribution for all categories
of shops in the study. Therefore, any of the analysis utiliz-
ing this data as a baseline is suspect. This includes both
economic and emission reduction analysis that are presented in
the draft.
1017
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Page -7-
MINOR ISSUES
I. Transfer Efficiency
The draft acknowledges the benefits of High Volume Low Pres-
sure spray equipment in reducing V.O.C. due to higher transfer
efficiency than what can be achieved by conventional air as-
sisted spray. However, transfer efficiency is not incorpo-
rated in the CTG as the author felt it would be difficult to
control due to variability of factors such as coatings used,
shape of part and operator skill. We acknowledge that the ac-
tual transfer efficiency will be the result of a host of vari-
ables such as operator skill, size and shape of part and sur-
rounding air velocities. However, under any conceivable con-
dition there will always be significant advantages in reduced
paint usage with HVLP vs. conventional air atomized applica-
tion. This will range between 20-45% reduction in material
usage.
Recommendation
We suggest transfer efficiency be incorporated into the CTG,
if not at the upper level the document should acknowledge at
least a 20% reduction in paint consumption and with that mag-
nitude of V.O.C. reduction require the use of HVLP or compara-
ble high transfer efficiency spray equipment.
II. Section 2.5.1 (Pages 2-12) states Convention Airless Spray is
the standard method of applying coatings in the refinish in-
dustry. This is a mis-characterization, as to my knowledge,
no refinish shops utilize airless spray. The conventional
means of application is air atomized spray.
III. Section 3.5.3 promotes the use of Biofiltration as a cost ef-
fective alternative for V.O.C. control in the automobile re-
finish industry. Although the technology appears to have po-
tential merit, the fact is it has never been, to my knowledge,
trialed let alone proven for spray applied coatings. Obvi-
ously, this approach needs considerable investigation and
should not at this time be considered as representing reason-
ably attainable control technology.
Recommendation
Remove any reference to Biofiltration from the CTG unless evi-
dence is available the technology meets the requirements of
RACT.
-------
Page -8-
We acknowledge and appreciate the efforts of the EPA staff who
worked on the preparation of the September 27, 1991 Draft for Auto-
motive Refinishing Control Techniques Guideline. The purpose of
this letter is not to antagonize their efforts, but rather to point
out serious concerns with critical portions of the text. My desire
and those of my colleagues on the Refinish Coalition is to aid in
the development of a fair and reasonable CTG for our industry. If
you or any other members of your staff wish to have further discus-
sions on the issues prior to the November 21, 1991 NAPCTAC meet-
ing, feel free to contact me.
Sincerely/
BASF CORPORATION
Coatings & Colorants Division
Robert J. Inglis
Director Product Planning
RJI/sep
pc: D. Guyomard
H.J. Robinson
R. Sappok
1019
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COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
Bob Inglisf BASF Corporation (See attached Presentation #2)
Ms. Mclntire inquired where BASF's estimate that HVLP spray
equipment can improve TE by 20-45 percent came from. Mr. Inglis
said it was determined through investigations and in practice.
Transfer efficiency does vary by operator and by gun, however, so
you can't just categorize an HVLP gun. In fact, the same thing
applies to conventional guns. Ms. Mclntire then asked if TE is
measured by paint consumption. The answer is yes. Ms. Mclntire
asked if a standard were to require a certain TE, would shops be
required to maintain records of paint use before and after using
HVLP guns. Mr. Inglis responded that would be one approach.
There is a definite correlation between paint use and use of HVLP
equipment, and you could establish a ratio. Operator variability
would be the same in either case.
Ms. Mclntire asked if manufacturers would be willing to help
small shops in measuring TE. She also inquired as to how a
baseline would be set. Mr. Inglis responded that manufacturers
would be willing to work with EPA in setting a baseline. He
noted that HVLP does improve TE and this should be recognized.
Mr. Berry requested that Mr. Inglis define "compliant high
TE spray equipment." He noted that California only says to use
HVLP, which he has heard has difficulty breaking up high-solids
coatings. California requires the use of HVLP or electrostatic,
and other types of spray equipment are required to prove they can
achieve 65 percent TE. The question was raised about why HVLP
does not have to prove 65 percent. California is now in the
process of conducting laboratory tests to allow equipment
manufacturers to prove that their equipment can achieve
65 percent TE, at which point it will be approved for use. Mr.
Berry stated that HVLP is "directionally" correct, but TE cannot
-------
be quantified. Further, someone who already has high TE with
conventional spray equipment would not get credit, while a
careless painter who does not get good TE would get the credit
merely because he uses HVLP.
Mr. Dennison noted that the definition of HVLP is still an
open issue in California.- Mr. Berry pointed out that as you
reduce air pressure, the painter has to stand closer to the part
being painted. This in itself improves TE. Further, high air
flows in spray booths adversely affect HVLP TE. Mr. Inglis noted
that the same is true if you use conventional spray equipment.
In reference to the comment that EPA overestimated paint
use, Ms. Mclntire asked how film thickness is measured.
Mr. Inglis replied that there are measuring devices (gauges) that
are easy to use. Mr. Jordan asked whether a painter could
achieve the very thin mil thicknesses that the coating
manufacturers recommend. Mr. Inglis replied that they could.
Mr. Jordan noted that he knew from experience that paint shops do
not use the small amounts cited by BASF.
Mr. Taranto observed that the coating manufacturers raise
some good questions about the baseline data and estimated
emission reductions. He requested that EPA work with industry on
this issue, especially because the Coalition's projections are
very different from EPA's. Mr. Inglis noted that the baseline
data are important, but the coating manufacturers are primarily
interested in developing a meaningful, liveable CTG.
Mr. O'Sullivan asked whether the statement is correct that
even in small shops the extra 25 percent of paint that is mixed
is incinerated and whether coating manufacturers offer this
service. Mr. Inglis replied that BASF does not offer this
service but the Resource Conservation and Recovery Act (RCRA)
requirements must be followed by shops.
Mr. Dennison noted that the discussion of using the topcoat
averaging equation seems to indicate that the basecoat limit is
too strict and the clearcoat limit is lenient. How could
compliance be determined if the standard was based on averaging?
The answer is by recording coating usage. Mr. Dennison noted
1021
2
-------
that it would be very difficult for a regulating agency to
determine compliance solely based on coating usage. EPA should
strive to profile the industry as best as possible and minimize
recordkeeping. Shops should only be required to show that they
use compliant coatings, regardless of how much they use.
-------
s
November 5, 1991
JPK 91-296
Mr. Bruce Jordan
Director of Emissions Standards Division (MD-13)
Office- of Air Quality Planning and Standards
U.S. EPA
Research Triangle Park, NC 27711
Dear Mr. Jordan:
REF: Draft Document -- Automobile Refinishing Control Techniques
Guidelines Dated September 27, 1991
On behalf of Safety-Kleen, I would like to thank the U.S. EPA Advisory
Committee for the opportunity to comment publicly on the proposed
Automobile Refinishing Control Techniques Guidelines.
Safety-Kleen is a company dedicated to the recovery and recycling of
solvents, thereby reducing the environmental impacts of the manufacture
of new materials and the potential environmental impacts of disposal.
We would like to submit the following comments for consideration in a
final CTG:
A) Spray Gun and Equipment Cleaner Variations
One of our products, the Model 1107 Paint Gun and Equipment Cleaner, is
referred to in the CTG under discussion. In Section 2.6 -- Cleaning
Equipment -- the draft CTG discusses two types of gun cleaners --an
enclosed gun cleaner, and an open gun cleaner.
In reference to the enclosed gun cleaner, the draft CTG discusses
"closed" without complete definition of the meaning of the word
"closed". The enclosed gun cleaners currently available are "closed"
only in that they have a lid. They do not provide a vapor-tight
closure, as implied in the discussion. Additionally, enclosed gun
cleaners are available in two significantly different variations:
1) In the simplest configuration, an enclosed gun cleaner uses only
recirculated solvent and rinses the passages, ports and exterior
of the paint gun and paint cup. This configuration does not
provide a final rinse of virgin material to assure that residuals
are purged from the fine passages and ports of the paint gun.
777 BIG TIMBER ROAD ELGIN. ILLINOIS 60123 PHONE 708/887-8460 FAX 708/697-1295
1023
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U.S. EPA, November 5, 1991, page 2
2) An alternate version of an enclosed gun cleaner contains a second
reservoir which allows for a final rinse of clean material. The
clean material is then mixed with the recirculated material and
used until che it is too contaminated for further use.
The Safety-Kleen Model 1107 described in figure 2-4 in the draft CTG,
provides for both recirculated gross cleaning of the spray gun and cup
and for a clean solvent rinse of the gun and cup to minimize the
potential for contamination of subsequently used paint.
It is important to note that test data provided to the U.S. EPA and
gathered by an independent third party with supervision by the South
Coast Air Quality Management .District of California, indicated that the
use of an open gun cleaner, specifically the Safety-Kleen Model 1107,
resulted in emissions that were significantly less than several gun
cleaners that were identified as enclosed systems.
There is a third type of system available which uses line pressure to
purge a spray gun and cup that has been reviewed by the South Coast Air
Quality Management District and is, I believe, also allowed by its
regulations. This system is manufactured by LighthalL Industries, and
may be of interest to the Agency for inclusion in the CTG.
B) Paint Cups
In Section 2.6, reference is made to the use of plastic, rather than
metal paint pots, for spray gun cleaning with the indication that
plastic may be easier to clean than metal surfaces. This suggestion
may, in fact, be misleading in that several polyethylene plastic paint
pots can become crazed over time and be, in fact, more difficult to
clean. Further, there are several metal paint pots currently available
with Teflon coating on the interior. The Teflon-coated paint pot is
extraordinarily easy to clean and allows for very efficient drainage of
solvents after cleaning, maximizing solvent recovery.
C) Automatic Vs. Manual Systems
In Section 2.8.2, entitled "Model Shop Equipment*, reference is made to
the presence or absence of "automatic gun cleaning equipment". We
suggest that the use of the word "automatic gun cleaner" is exclusive of
the two aforementioned manual products. We suggest that the use of the
words "gun cleaning system" be included, and exclude the potentially
misleading adjective "automatic". The use of the word "automatic" or
"automated" appears throughout several portions of the draft CTG, and we
request that it be corrected throughout the draft. Furthermore, single-
stage, automatic closed units may require a final rinse with clean
solvent that is necessarily done external to the unit.
1024
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U.S. EPA, November 5, 1991, page 3
D) Vapor Tight
In Section 6.2, Definitions, the definition for gun cleaner states: "A
device made specifically to clean paint from spray guns which
recirculates solvent to clean a succession of times and is vapor-tight
when in use.*
No gun cleaner on the market today is vapor-tight when in use. Even the
described enclosed gun cleaners are not vapor-tight and emit significant
amounts of volatile organic compounds when they are being used and
subsequent to use. These losses can be described as "active" losses
during use and "passive" losses when the product is not being used.
Data supplied to the Agency has indicated that the use of open systems,
such as the aforementioned Safety-Kleen Model 1107, are, in fact, more
efficient in reducing emissions in both the active and passive phases.
We suggest that the definition of gun cleaner read: "A device made
specifically to clean paint from spray guns which recirculates solvent
to clean a succession of times and minimizes the loss of solvent into
the atmosphere through a recovery technology".
E) RACT Considerations
In Section 6.6.2, Gun Cleaners, under Section 6 -- Factors to Consider
When Implementing Reasonably Available Control Technology - - four
suggestions are made to states:
o It is suggested that states approve only those gun cleaners that:
1) Recirculate the solvent used during the cleaning process, so
that the solvent is used to clean a number of guns before
being disposed;
2) Collect the spent solvent in a manner than insures it is
available for disposal;
3) Are vapor-tight during the cleaning process:
4) Meet applicable fire, safety, and occupational safety and
health codes, laws, and regulations both in design and in
the manner in which it can be used.
o State regulations should specify that the facility is accountable
for spent solvent from the gun cleaner. It must not be allowed to
evaporate. Documentation must be available to support that it has
been released to a licensed reclaiming or hazardous waste
management facility.
Point three requires a system be vapor-tight during the cleaning
process. This is not consistent with the suggested definition for a gun
cleaner hereinabove, but, more importantly, it is not consistent with
comments made in Section 3.4, Emission Reductions From Gun Cleaning, in
which the Agency indicates that equipment is currently available that
1025
-------
U.S. EPA, November 5, 1991, page 4
can reduce solvent consumption, evaporation, and worker exposure. The
Agency further suggests that gun cleaners can be enclosed or open and
cites a report obtained during the CTG investigation that some open gun
cleaners emitted no more VOC" s than enclosed gun cleaners .
F) Health Considerations
It is important to note that the use of enclosed gun cleaners, when
compared to open gun cleaners, may pose significant exposure and health
effects that are solved with certain open systems. In this regard, an
open system, such as the -Safety-Kleen Model 1107, may be both safer to
the user and less damaging to the environment. (See attached ENSR study
on Evaluation of Worker Exposure to Organic Vapors while Operating Paint
Spray Gun Cleaners . )
Should the Agency require clarification of any of the above comments, I
would be happy to elaborate. I plan to attend the meeting on the draft
Auto Body Refinishing CTG Document on November 21, 1991.
Once again, thank you for the opportunity to participate in the
development of this CTG.
JoRn Paul Kusz
Manager, Product Development
JPK/pJ
Encl.
cc : CAATF
Mike Callahan
Jim Sanseverino
REG/TEST/U.S. EPA
-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
John Kusz. Safety Kleen (see attached Presentation #3)
Mr. O'Sullivan asked if there is any estimate of the
percentage of small shops that deliver their spent solvent to
reclaiming facilities. Mr. Kusz said it is hard to give a
definitive answer. The numbers are expected to be different in
different regions, e.g., the percentage would be greater in
California and in more commercial areas. Mr. O'Sullivan wanted
to know what percent of the market Safety-Kleen services.
Mr. Kusz preferred not to make that public knowledge, but said
that some information has already been provided to EPA.
1027
i
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Industry Presentation #4
PRESENTATION OF
THE
NATIONAL AUTOMOBILE DEALERS ASSOCIATION
BEFORE THE
U.S. ENVIRONMENTAL PROTECTION AGENCY
BY
DOUGLAS I. GREENHAUS
SENIOR ATTORNEY, REGULATORY AFFAIRS
ON
NOVEMBER 21, 1991
1928
-------
Good morning. My name is Douglas I. Greenhaus and I am the
Senior Attorney for Regulatory Affairs for the National Automobile
Dealers Association (NADA). It is my pleasure to appear before you
today to present NADA's views on the U.S. Environmental Protection
Agency's (EPA) draft Automobile Refinishing Control Techniques
Guideline (CTG).
NADA is a national trade association representing over 19,000
franchised car and truck dealers across the country. NADA members
are primarily engaged in the retail sale of new and used motor
vehicles, both foreign and domestically produced. NADA members are
also engaged in automotive service repair and parts sales.
EPA's draft CTG on automotive refinishing is of considerable
importance to the automobile dealership body. NADA's Industry
Analysis division estimates that dealership automobile and truck
refinishing operations account for roughly one third of all
autobody sales. In addition, approximately sixty percent of new
vehicle dealerships operate formal autobody repair and painting
operations. In total, it is estimated that dealership autobody
departments employ some 103,000 people in 13,500 facilities with an
average of 8 employees per department.
The average NADA dealership employees 40 persons in total.
In addition, over eighty percent of NADA's members are considered
small businesses by the Small Business Administration. Given that
2
1029
-------
the refinishing CTG will substantially impact small business
refinishing operations, NADA is actively working with EPA on the
development of guidelines for the implementation of Section 507 of
the Act.
NADA previously provided EPA with information in order to
assist with the CTG development process. In early 1988, NADA
submitted the results of a comprehensive membership survey of paint
and coating material use rates. Earlier this year, NADA submitted
comments on EPA's Revised Summary of Automotive Refinishing Model
Shop Emission Costs. The following comments specifically address
the September 27 draft CTG.
A. Surface Preparation
NADA supports the inclusion of controls on surface preparation
products. However, NADA submits that EPA significantly
underestimates the costs associated with using lower solvent
content preparation materials. It is clear that the use of these
materials will take some amount of applicator retraining and will
require additional time to achieve the same benefits as higher
solvent content counterparts. EPA fails to include these
significant costs in its analysis.
With respect to emissions reduction, NADA suggests that the
draft CTG fails to consider whether lower solvent content surface
preparation materials aren't used in greater quantities. EPA also
-------
fails to recognize that solvent volatilization is proportionate to
the amount of time the preparation product remains on the surface
and to recognize that not all of the VOC's in higher solvent
content materials become airborne prior to being wiped off the
surface being prepared. In summary, EPA overstates the emissions
baseline for surface preparation materials.
B. Coating Applications
NADA supports the two option approach to paint system
regulation. However, NADA is very concerned about the values EPA
has selected. Obviously, the values selected for each option are
of critical importance to the refinishing industry. Without proper
paint system quality and color match capability, auto refinish
operations will be unable to adequately service their customers.
NADA suggests that EPA consider adopting the values set out in the
California Air Resources Board Regulation and endorses the National
Paint and Coating Association's comments on that issue.
Lower solvent content coating systems are expected to require
considerable applicator retraining. In addition, it is expected
that surface areas will take longer to paint and that drying times
will be longer. All of these important costs must be factored into
EPA's impact analysis.
NADA strongly supports EPA's decision not to include a
transfer efficiency requirement in its CTG. On the otherhand, EPA
-------
must recognize some VOC emissions reduction benefits attributable
to those shops using improved transfer efficiency. It is reasnable
to expect that, as reformulated paint systems become more costly,
facility operators will begin to turn to higher transfer efficiency
equipment in order to reduce costs.
EPA's discussion of higher transfer efficiency fails to
reflect the significant retraining costs involved and the potential
for longer painting times, both of which are critical factors to
the refinishing industry.
C. Gun Cleaning
NADA supports the inclusion of a gun cleaning requirement in
the CTG. At the same time it is clear that EPA overestimates the
baseline for this option and thus the potential for emissions
reduction. A significant and increasing source of gun cleaning
solvent results from the in-house distillation of waste paint and
solvent materials. To count this recycled solvent in an emissions
baseline would be redundant. Likewise, the cost savings shown by
EPA for gun washers is also erroneous in light of the use of
recycled gun wash solvent.
It is also inappropriate for EPA to assume that all the spent
solvent used to clean guns is fully evaporated in those shops which
do not use gun cleaners. Whether destined for on-site distillation
or off-site management, spent gun wash is not left to totally
-------
evaporate in the typical automotive refinishing facility.
D. Add-On Controls
NAOA strongly objects to the inclusion of add-on controls in
the proposed CTG. EPA's impact analysis shows that add-on controls
are not currently available for the automotive refinishing
industry. In addition, EPA's data show add-on controls to be from
six (carbon adsorption) to over fourteen (incinerator) times as
expensive as surface coating system solvent control alternatives.
On the other hand, add-on controls result in, at best, only a
marginally superior reduction in VOC emissions.
EPA's suggestion that states require multiple shops to
refinish in a single add-on control equipped facility verges on the
ludicrous. While this creative concept might conceivably make the
capital and operating costs more "reasonable," theoretical savings
would be overshadowed by transportation costs, scheduling
nightmares, competition concerns, etc.
Again, all references to add-on controls must be deleted from
the proposed CTG as they are clearly not "reasonably available
control technologies" for this industry.
E. Other
a. Housekeeping Practices
NADA has long supported good refinishing housekeeping
-------
practices. Keeping containers closed and minimizing the amount of
materials used is good for business as well as for the environment.
Throughout its proposed document, EPA refers to the
proper management of waste paint and solvent materials. NADA
objects to EPA's repeated reference to off-site waste management
options as somehow being important to the CTG. Instead, EPA should
include a suggested prohibition against the intentional on-site
disposal-through-evaporation of waste paint and solvent materials.
Furthermore, there is no reason to believe that waste sludges or
distillation residues pose any VOC emission concerns. The
discussion of waste management, including recordkeeping, should be
dropped from the CTG as these materials are already covered under
applicable federal and state solid and/or hazardous waste
regulations.
b. Reporting and Recordkeeping
NADA strongly objects to EPA's suggested recordkeeping
and reporting requirements as having no relationship to VOC
control. Daily logs or records would be terribly burdensome for
the small business automotive refinishing community. In the
alternative, EPA should simply suggest that states require
refinishers to keep copies of their preparation, paint system, and
solvent purchase invoices, and the repair order documentation
normally kept in the ordinary course of business. Analysis of
these normal business records would provide regulatory authorities
1034
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with more than adequate information for both administrative and
enforcement purposes.
c. Miscellaneous
NADA urges EPA to edit its draft CTG document to remove
a number of irrelevant discussions including the reference to
reducing the number and severity of collisions, and the discussion
of electrostatic spray equipment.
EPA's model regulation has a reference to "aftermarket
automobiles." This term is certainly not commonly understood in
the industry and its purpose is unclear. While there may be a need
to distinguish between OEM painting operations and automotive
refinishing, it makes no sense to try to define coverage of the
rule based on where vehicles were purchased.
EPA's model regulation should apply to light duty
vehicles as defined in its mobile source regulations and should
exclude heavy duty vehicles. The reference to and definition of
light and medium duty trucks is inconsistent with other Clean Air
Act definitions.
On behalf of NADA I would like to thank you for the
opportunity to comment on this matter. At this time, I would
welcome any questions you might have.
8
1035
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COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
Douglas Greenhaus. National Automobile Dealers Association fNADA]
(see attached Presentation #4)
Mr. Hise asked how common is distillation of waste/spent
solvent. Mr. Greenhaus said it is not that common, but it is
increasing. The use of distillation units avoids off-site
liability disposal and reduces hazardous waste disposal costs.
Distilled solvent can be used in gun cleaners (but it is not pure
enough to mix in paint). Mr. Hise asked if these units are
readily available to shops. Mr. Greenhaus said they are; there
are at least 12 distributors, and some facilities share them.
Dr. Atkins asked if NADA completely supports the California
regulation. Mr. Greenhouse responded NADA does not support the
regulation for recordkeeping or TE. In color match issues, they
defer to the coating manufacturers.
Mr. Dennison recommended that NADA explore the possibility
of multiple shops sharing an add-on control device.
Mr. Greenhaus said they would, but that this practice is not done
at all, and is not "reasonable" for consideration as RACT. He
was not aware of any NADA members that have add-on control
devices, and NADA would not support the use of add-on controls
for any size shop because the costs are just too high.
Dr. Atkins asked if Mr. Greenhaus was aware of many odor
complaints. Mr. Greenhaus replied that they occasionally hear of
shops getting inspected because of odor complaints but most
dealerships are located in non-residential areas. Mr. Berry
noted that non-dealership facilities could be located in
residential areas. Mr. Greenhaus agreed that smaller,
independent shops are more likely to be located in residential
areas.
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Industry Presentation #5
PRESENTATION/COMMENTS OF
PPG INDUSTRIES AUTO REFINISH COATINGS GROUP
CONCERNING AUTOBODY REFINISHING CTG DRAFT
BY
R. T. HILOVSKY
MANAGER, REGULATORY AFFAIRS
AUTOMOTIVE, AIRCRAFT & FLEET FINISHES
1037
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- NAPCTAC Meeting - November 21, 1991
- Automotive Refinish CTG Draft
Thank you for the opportunity to address this subject today.
As a supplier of coatings systems, information and training to the
Auto Refinish Industry and an active participant in the NPCA Auto
Refinish Coalition, PPG Industries strongly supports the positions,
objectives, and recommendations of the NPCA Coalition position paper.
-Objective: Development of national consistent VOC regulations
with real, effective, achievable VOC emission reductions.
-Recognition & incorporation of industry practice and operating
realities into effective regulations.
-Selection of the RACT VOC limits of the California Clean Air
Act Guidance for the Refinish Industry as the RACT limits for
the CTG.
-Topcoat limits recognizing multi-stage basecoat/clearcoat or
tri-coat averaging as necessary to achievable VOC systems
reductions.
-The recognition of the systems nature of Refinish products and
processes.
-Acknowledgement of the necessity and utility of low-volume usage
speciality coatings.
-The effective reductions achievable through the trained use of
improved transfer efficient application equipment and techniques.
-Systems Nature of Auto Refinish Coatings Operations
-Product chemistries as they develop require constant testing
to determine over and under what other coating components and
substrates these products are compatible
**[Attached overhead transparencies here to demonstrate systems]
-New material developments and raw material substitutions for
supply/economic reasons as well as regulation mandates require
retesting and qualification within the individual manufacturer's
total system.
-Knowledge of competitive changes is not available as to
type or timing.
-------
-Use of total product systems with their background testing
history allows consistent use, application, and productivity
recommendations to be made and trained.
-Total systems allow thorough technical service support,
complaint handling, and approved application warranties. This
better assures that recommended reductions, blends and
application techniques are consistently followed, to maintain
and assure the guarantee and minimize job re-do's or come backs.
-Training
Achievement of the desired VOC reductions from any regulation
is best attained by the consistent, trained usage of compliant
materials and methods by an applicator confident in the products,
equipment and achievement of the desired end result in system
appearance, performance and productivity.
Auto Refinish systems manufacturer/suppliers are the primary,
consistent and continuing source of training to the industry.
-Product Systems Introduction and Training
-Coating Systems Application Options
-Printed recommendations and hands-on training
-Regulatory Requirements
-OSHA safety and right to know
-Hazardous waste disposal guidelines
-VOC emission reduction
-Product/Process Productivity
CA Guidance RACT is fully accepted, trainable and in training now.
Thank you for your time and attention, and I would welcome any
questions you may have.
A final comment before I conclude, the conclusion that transfer
efficiency is not easily quantifiable due to product, part and
process variability, and thus cannot be assigned a baseline % value,
seriously contrasts with the assigned 35% T.E. value for conventional
air spray used in calculations in the draft CTG. 35% T.E. is the
maximum achievable for air spray, which is certainly subject to all
the same variables. A reasonable improved T.E. baseline average can
be established from product usage/purchase records.
1039
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o
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12
13
-------
O
SUITABILITY OF ONE PRIMER UNDERCOAT OVER ANOTHER
2ND COAT
1ST COAT
NCR 250/255
DP 70/701
DPX 800
now I4J
UrA IH1
RPU/ mil itw
Urn 101 1, (•>!<
npuf 1191
urn lOti
npu/ 1MJ
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•FULL PANEL ONLY!
15
-------
COMPATABILITY OF TOPCOATS OVER VARIOUS UNDERCOATS
K200/201
K38/201
NCP 290/
259
KT3 30/201
0X94
OPX 844f
OPX 800
OSX 1900
DPW 1832,
1811
DPW 1821
DPW 18441
KTS47
Ouracryl
DDL
Bastcoal
•
-
t
ft
(
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Ouncryl
DDL
-
E
E
£
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Delslar
OAR
VG
•
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Oelilar/
Dellhina
OAR/
DXRBO
VG
VG
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VQ
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Slirlhufle
STAR
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2000
Basecoal
DBC
G1
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E
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2K
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Color
E
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to
f Topcoat mini be flexed wllh appropriate product.
•Product must be seiled wllh KTS 30, DP/401 reduced as a sealer, or DAS
1980,1987.
" Musi be sealed with KTS 30 or DP/401 reduced as a sealer.
18
19
-------
COMPATABILITY OF TOPCOATS OVER VARIOUS UNDERCOATS
OL 1970
02132,34,.
72
OPE 656
DPE 1202
OPE 1338
OPE 1538
023,7
DAS 1980,
1987
DP/401
DX1791/
1792
DPU 35/301
Preet 33
Duracryl
DDL
tailcoat
C
E
•
•
•
•
E
VG
E
•
•
E
Outicryl
DDL
E
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-
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DII2CO
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Oitzco
DOE/
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-
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Delslai
DAR
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Delslar/
Dellhane
DAR/
DXR80
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VG
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t
Slarbasi
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Diltron
DAU
•
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•
-
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VQ
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VG
E
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Oeltron
2000
Basecoal
DBC
-
•
-
G'
G
VG
-
G
Dellton
Basecoal
DBU
-
"
-
E
VG
E
VG
Concept
2K
DCC
-
"
-
-
•
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G'
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-
Durelhane
DU
-
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G
G
G
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-
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Delia
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-
-
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ucv
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-
-
•
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CD
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CO
f Topcoat must be lleied with appropriate product.
•Product mutt be sealed with KTS 30, OP/401 reduced as • seller, or OAI
1980,1987!
0 Mutt be sealed with KTS 30 or DP/401 reduced as a sealer.
16
17
-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
Ron Hilovsky. PPG Industries (see attached Presentation #5)
Mr. Hise asked whether the EPA's assumed TE of 35 percent
was accurate for the industry today as an average. Mr. Hilovsky
responded that conventional spray equipment has a TE of 25-35
percent, while the CTG gives 35 percent as an average for
conventional spray equipment.
1G44
i
-------
Industry Presentation I6
The Sherwin-Williams Company
101 Prospect Avenue, N.W.
Cleveland, Ohio 44115-1075
•National Air Pollution Control Techniques Advisory Committee Meeting
November 21, 1991 at Durham, NC
•Guidance document for Automotive Refinishing CTG
NAPTAC Committee Members:
I appreciate the opportunity to address this committee today.
We recognize the need to reduce VOC emissions to improve air quality due to not
only the need to comply to the Clean Air Act but to create a healthy environment for
all of us. In doing so you take into consideration environmental and economic
impacts. In this regard I would like to tell some background information on the
automotive refinish industry.
The industry is responsible for the repair and refinish of the average person's second
largest asset - his car. (This follows only the home as a person's single largest asset.)
The industry represents the classic small business profile for the United States. The
following facts from the "Market Profile 1991" Body Shop Business (a widely read and
highly regarded trade publication) represent the industry:
• 77.2% of body shops are family owned
(20.2% of those are second generation),
• Currently 2 family members work full time in the body shop,
• The average body shop has approximately 7 employees,
• 45.5% of workers refinishing automobiles are paid hourly,
• 53.4% of body shops generate less than $250,000 in annual sales,
• Average gross profit margin is 25.0%
(This translates to less than $62,500 in gross profit per year).
The reason I bring your attention to these facts is that we take great care in our
recommendations for PACT. And for how we design new technology for the future.
I would also like to bring to your attention the heart of the refinish industry - color. The
ability to restore a vehicle to its "pre-collision condition" is absolutely essential. The
restoring of a vehicle to OEM specification for quality and performance is necessary
and expected. But the color match dictates whether a customer will accept a
repair. If the repair is evident to color mismatch, the vehicle has to be done again
and at a loss. To give you a feel for the complexity of todays colors I have brought
the following.
• '92 Domestic Car Color Chip Book,
• Alternate color formulas program,
• Repaired panels
• Blending - visual demonstration
1045
-------
As you can see, there are literally thousands of colors required to refinish all of todays
vehicles. And complex color matching is required for today's colors. We are
sensitive to their needs of providing a quality and warranteed system that they can
use right the first time. Again this impacts our recommendation for PACT.
The draft document for the automotive refinish CTG does not take into account the
use of a composite VOC for basecoat/clearcoat colors. Attached to my
presentation is our company's documentation where the composite calculation of
VOC BB/CC = VOC BC + 2 VOC Cc
is derived from. In our test we simulated a medium size repair (replace fender and
blend door) and large repair (replace front fenders and hood, blend into doors).
We also used a Low Volume Low Pressure gun, a high solids clearcoat, and a high
VOC basecoat color. This combination represents a worst case scenario (ie - low
amount and VOC of clearcoat, high VOC basecoat color, and low volume of
material due to high transfer efficient application equipment). The results are still within
the composite VOC calculation. To sum up the results (details are attached):
• The ratio of 2:1 for clearcoat to basecoat is based in material by
volume not dry film thickness. Actual is 2.4:1 for a medium repair and
2.6:1 for a large repair.
• The predicted VOC for the composite VOC calculation is understated
by 2.2% of actual VOC emissions for a medium repair and understated
by 0.6% of actual VOC emissions for a large repair.
The calculation is accurate and represents the VOC emissions of a
basecoat/clearcoat system. With the flexibility to use this composite VOC calculation
we are free to turn loose our Research and Development department to lower VOC
emissions of a basecoat and/or clearcoat. This will encourage innovative solutions
to reduce VOC emissions at the lowest cost. Without this flexibility the VOC limits
proposed (contained within the draft CTG) are not RACT. No system, to the best of
my knowledge, exists that can commercially meet the proposed VOC limits.
RACT is defined as "the lowest emission limitation that a particular source is capable
of meeting by the application of central technology that is reasonably available
considering technological and economic feasibility". And it takes into account a
particular source's "technological and economic circumstances". In your RACT
determination we ask you to recognize our efforts to think and act as an industry:
refinishers and shop managers/owners, distributors, equipment suppliers and
coatings manufacturers. Our efforts are designed to move our industry to lower their
VOC emissions but yet preserve the integrity and complexion of the industry by
keeping costs low.
1046
-------
In our considerations we as an industry have been required to weather the
technological advances of the Unibody,on board computer equipment, increased
OEM warranty periods, and basecoat/clearcoat/three stage finishes. These
advances required new technology and training, as well as capital investment for
new equipment. All at a time of decreased amount of issuance dollars.
The RACT recommendations we make are sensitive to the small business in the
aftermarket collision repair industry. We have worked together to draft reasonable
rules. We make the recommendation to use California's Technical Review Group's
recommendation for RACT. It encompasses the goals of industry and regulators into
a common target. Our focus in not to stop at RACT. We have set our ambitious
program to go further.
I would like to make an additional comment. Hercules approached me about how
their gun cleaner fit into the CTG. I believe the attached document should be
reviewed as its results are contrary to some of the information in the draft CTG.
Again I appreciate your time and the hard work of many here to get to where we
are today. The incorporation of our suggestions ensures a workable document for
the United States and tomorrow.
047
-------
Basecoat/Clearcoat VOC Calculation
VOC BC/CC Premise: The VOC emissions from a repair of an OEM basecoat/clearcoat by an
aftermarket refmish basecoat/clearcoat can be accurately represented by the following calculation:
VOC BC/CC = VOC BC + 2 VOC Cc
This premise is based on allowing a basecoat with accurate color match capability that will allow
smaller blends, prevent "re-do's" due to inaccurate color match, and that the volume of the clearcoat to
basecoat is a minimum of 2:1.
• Test Protocol:
—Test
Spray two repairs that represent an "average1" (1-2 panel) and large2 repair (2 or more panels)
(Small repairs3 - a panel or less represents the lowest VOC emission and consequently will not be
done). See attached diagram.
—Equipment:
Iwata LPS (Low Volume Low Pressure restricted to maximum 10.0 psi at tip).
—Topcoat System:
BC)—UltraBase 7® Basecoat Color with BCS-600V (Test Colon '91 General Motors Code 22
Light Sapphire Blue Metallic UB-35879).
CC)—Ultra 7000® High Solids Urethane Booth Clearcoat CC-850.
1 Average—Involves up to replacement of 1 panel (such as a fender), applying basecoat to fender and
blending color into clear to hide any potential color mismatch. This is followed by applying clearcoat
to fender and door.
2 - Large repair—Involves up to replacement of front end (such as a severe front end collision), applying
basecoat to both fenders, hood, and blending into doors (to hide any potential color mismatches). This
is followed by applying clearcoat to two fenders, hood, and both doors.
3 - Small repair—Involves applying basecoat to small spot (usually less than 1 panel) and blending out into
rest of panel. This is followed by applying clearcoat to entire panel. If color match is good, generally
the amount of basecoat color used is small compared to clearcoat usage.
• RESULTS
Basecoat Clearcoat
—Mixing Ratio 1:1 UB-35879:BCS-600V 4:2:1 CC-850:CC-R854:CC-H858
—VOC (Sprayable) 6.07 #/gal 4.38 #/gal
—Wt/Gal (Sprayable) 7.66 #/gal 8.13 #/gal
—UsageJ Medium repair 3.4 oz. 8.2 oz. Ratio: 1:2.4
—Usage! Large repair 12.1 oz. 31.6 oz. Ratio: 1:2.6
—Actual VOC emissions
Medium repair 0.16# 0.28 # Total: 0.44 #
Large repair 0.58 # 1.08 # Total:!. 66 #
—Predicted VOC emissions 2
Medium repair — — Total: 0.45 #
Large repair — — Total: 1.67 #
1 Usage— Medium Repair (~ 14 sq. ft.) Large Repair (~ 44 sq. ft.)
BC 92.3g (3.4 oz.) 329.5g (12.1 oz.)
CC 234.8g (8.2 oz) 909.3g (31.6 oz.)
-------
COMMITTEE DISCUSSION ON INDUSTRY PRESENTATION
Grea Ocampo. Sherwin Williams (see attached Presentation #6)
[Note: There was no committee discussion of attachment to
Presentation #6]
In response to a question by Dr. Atkins about the 1992
California limits, Mr. Ocampo said they would be hard to meet in
a shop that did not have a heated spray booth because the
clearcoat would dry very slowly- Some coatings that can meet the
1992 limits are not currently "reasonably available," but may be
in a few years. Mr. Ocampo stated that he supports the GARB 1990
limits as RACT.
Mr. Hise asked how the right color is selected. Mr. Ocampo
replied that spectrophotometers work for solid lighter colors.
However, even then they are only used for guidance; all color
matches are done by eye.
In response to another speaker's comment that color match
would only be hard with the Option 2 topcoats, Mr. Ocampo said
that all coating manufacturers agree that without being able to
use the basecoat/clearcoat averaging equation, metallic topcoats
could not meet either option.
104!
i
-------
Atxacnment to
Industry Presentation #6
Iterlmlec
Phone. 313-363-8882
WATS. 1-800-444-4351
Hcrkulcs Equipment Corporation reiex '
8230 GOLDIE ST. • WALLED LAKE, Ml 48390-4108
November 13, 1991
United States Environment Protection Agency
Office of Air Quality Standards'Division
Research Triangle Park, N.C. 27711
Attention: Mr. Bruce C. Jordan
Director Emission Standards Division
Subject: Draft Sept. 27, 1991
Automobile Refinishing
Control Techniques Guideline
(Gun Cleaning)
Dear Mr. Jordan,
Our copy of the draft was delayed in being received due to a zip code change
and was only reviewed this past weekend, hence we are too late to obtain time
for a presentation. According to Mary Jane Clark, you can distribute copies
of this letter to the committee.
Our firm holds the basic patents on the predominate type of enclosed gun
washers found in body shops both here in the USA as well as in most countries
abroad identified in your draft in Section 2.6 on page 2-15 and pictured in
Figure 2-3 which is commonly referred to as an Automatic-Enclosed Gun Cleaner.
To help NAPCTAC we would like to place before the committee some additional
information which is related to paint gun washing and "latest applicable
technology" for cleaning of paint guns and related equipment. To accomplish
this objective, a distinct differentiation is made between Automatic-Enclosed
Gun Cleaners (Figure 2-3) and the "typical open gun cleaner" described in
Section 2.6 page 2-17 and pictured in Figure 2-4 also known as a Manual-Open
Gun Cleaner. The major differences are compared below:
-------
Differences Automatic-Enclosed Manual-Open
1. Closed during yes no
cleaning
2. Cleans guns without yes no
worker direct
participation
3. Cleans multiple guns, yes no
cups, stirrers,
strainers and other
paint related equipment
simultaneously
4. Cleans inside and yes no
outside of guns
simultaneously
5. Workers are exposed no yes
to solvents during
cleaning cycle
Much of the draft seems to paint both Automatic-Closed and Manual-Open Gun
Cleaners with the same brush. This overlooks key issues such as solvent.
consumption, worker exposure, cleaning cycle time, other items which must
constantly be cleaned along with the paint gun and simultaneous multiple gun
cleaning all of which impact on the VOC emission and worker exposure.
As a part of the "improved housekeeping practices" referred to in Section 3.1
page 3-1, Automatic Enclosed Gun Cleaners can play an important role. They
affect radically the amount of time required for cleaning guns, cups,
stirrers, strainers, etc. reducing worker direct exposure to solvents while
limiting potential escape of V.O.C. Over the old methods of cleaning, they
significantly reduce solvent usage and the amount of solvent which must be
maintained at the shop. Virtually all of the tools and related items which
need constant cleaning including strainers, stirrers, and mixing vessels can
be cleaned in the automatic gun cleaner at the same time the guns are being
cleaned eliminating the need for multiple open containers for various cleaning
functions.
We take issue with the final paragraph in section 3.4 page 3-10 implying that
"Open Gun Cleaners emit no more VOC than Enclosed Gun Cleaners." The report
referred to was submitted to SCAQMD in order to obtain a variance allowing
manual-open gun washers to be used in Southern California. The report was
paid for by the waste hauler owning the rental equipment; the test itself
varied from the testing procedure recommended by the SCAQMD, and did not
reflect knowledgeable usage of the competitive units, totally ignored multiple
equipment cleaning which is essential and used antiquated competitive models.
-------
With reference to Section 4.3.1. page 4-14, it is possible that minimal
solvent could be emitted from closed gun cleaners, but this possibility was
virtually eliminated long ago by a redesign of the lid. (See Attachment No.
1). All Herkules manufactured or licensed units have or will have soon
incorporated this feature.
The issue of escaping V.O.C., 4.3.1 page 4-14, during the loading (no hose
connections are required in our standard automotive Automatic-Enclosed Gun
Cleaners) is a valid concern and can be addressed two ways. The first way is
through education and the second way is through the use of a speed controlled
lid opener and closer.
Proper opening of the lid on-any solvent container requires education. The
worker does not want to create any more suction during opening and no more
fanning of fumes during closing than necessary. Hence the industry needs
instruction. A sample of such instruction for any vessel containing solvent
could read as follows:
CAUTION:
READ BEFORE OPENING
Solvent fumes are normally heavier than air and if not disturbed
will remain in the container. To prevent fumes from escaping,
open and close lid slowly.
I. Open lid about one inch to equalize the pressure inside
and outside. Then open slowly, this mimimizes the escape
of fumes through suction.
2. Do not slam lid during closing, lower lid slowly to prevent
fanning which can cause fumes to escape.
In the Definitions Section 6.2 page 6-3 under the heading Gun Cleaner,
reference is made to being "vapor tight"; no gun cleaners in common use are
100% vapor tight. In fact, if they were vapor tight chances of fume emission
would be increased during loading and the cleaner could become dangerous under
pressure as the content in most cases are extremely volatile. For this
reason, we believe Sections 6.2 page 6-3, 6.6.2 page 6-10 and Appendix D, page
D-3 Gun Cleaners and Appendix D page D-5 Equipment Standards (d) (1) (iii)
need modification to read "reasonably vapor tight" not "vapor tight."
We are continuously trying to improve the design and application of cleaning
equipment to provide both the autobody repair and industrial paint industries
with "state of the art" equipment. The draft does not take into
consideration the latest models of automatic-enclosed cleaning equipment which
have solved many of the VOC emission problems, for example:
1052
-------
Features
1. Double barrier lid
design.
Speed controlled lid
opener and closer.
Hose cleaning for
pressure gun fluid
lines.
4. Paint can and paint
lid cleaning.
5. Combination gun and
paint can washing.
Herkules Models
Containing Features
All Herkules models
GWR-100-SS
GWR-3-100-SS
CWR-4-100-SS
GWR-3
GWR-3-100-SS
CWR-31
CWR-31-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
CWR-4
CWR-4-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
Result
Reduction of VOC emissions
during both active and
passive states.
Reduction of VOC emissions
during loading and un-
loading.
Reduces solvent needed for
fluid line cleaning, VOC
emission and the need for
open solvent containers
during cleaning.
Allows paint cans to be
reused as mixing or
storage containers,
reducing solid waste
generated in the form
of paint sludge. Converts
quart, gallon and 5 gallon
cans considered hazardous
to non-hazardous reducing
disposal costs and re-
ducing the amount of
paint which is sent to
hazardous dump sites,
inside cans.
One cleaner cleans
both guns, cups,
stirrers, strainers, etc
and paint cans/lids.
In a world of constant change, obviously it is impossible to take all
available technology into consideration before approving the guidelines.
With minor adjustments to the draft including more specific wording on
Automatic-Enclosed versus Manual-Open Gun Washers and changing the concept of
"vapor tight" to "reasonably vapor tight" the document should become an
acceptable guideline.
Yours very truly,
Richard A. Robb
President
RAR/lw
*i ° r n>
I.» 3 3
-------
ATTACHMENT No. 1
ORIGINAL
ALUUIHUM
LID
ALUMINUM
FRAMf
ORIGINAL
PLASTIC
TUB
HEW
ALUMINUM
LID
VAPQR
SCAL
GWR LID/TUB FIT
PLASTIC TUB
HCKKULCS fQUIPMCUr CORP
Bf LG PAr.- l-ir-91
LIO Oe<~l
STAINLSC? STfCL TUB
HY LG
-------
Comments & Observations Of
Automotive Refinishing CTG Document
en
GRACO INC.
GRAC01"1 MINNEAPOLIS, MN
-------
Total Paint Thickness Applied by OEM
Total
Paint
Thickness
3.5 MILS
i
Clearcoat
50% of Total Thickness
Basecoat
20% of Total Thickness
Primer
30% of Total Thickness
GRACO 1991
-------
OEM Prefers Electrostatic Application
M
GR AGO 1991
75-80% of all coatings currently
applied are electrostatic
Including:
80% of all primers
95% of all clearcoat
/ 40% of all basecoat
-------
Graco Test Comparisons of T.E. in Spray
Forms Show That in Refinish Industry
C©
Electrostatic
Hits the target with
75% efficiency
HVLP
Hits the target with
65% efficiency
Airspray
Hits the target with
40% efficiency
...Because of very low flowrates
GRACO 1991
-------
When Using Electrostatic
Application Throughout the
Automotive Refinish Process
• Basecoat color match is more accurate
and readily achieved
• Application is easier
• Greater efficiency results, which
translates to faster payback of
electrostatic gun
EXAMPLE: 10 week payback of $4100 electrostatic unit
shop type E-H)
1.92 Gallons/Day (savings) X $42.50/Gallon X 50 Days = $4080
GRACO1991
-------
fteffkulcc
Phone: 313-363-8882
WATS: 1-800-444-4351
FAX: 313-363-7998
Herkulcs Equipment Corporation i.v. 231233
8230 GOLDIE ST. • WALLED LAKE, Ml 48390-4108
November 11, 1991
United States Environment Protection Agency
Office of Air Quality Standards Division
Research Triangle Park, N.C. 27711
Attention: Mr. Bruce C. Jordan
Director Emission Standards Division
Subject: Draft Sept. 27, 1991
Automobile Refinishing
Control Techniques Guideline
(Gun Cleaning)
Dear Mr. Jordan,
Our copy of the draft was delayed in being received due to a zip code change
and was only reviewed this past weekend, hence we are too late to obtain time
for a presentation. According to Mary Jane Clark, you can distribute copies
of this letter to the committee.
Our firm holds the basic patents on the predominate type of enclosed gun
washers found in body shops both here in the USA as well as in most countries
abroad identified in your draft in Section 2.6 on page 2-15 and pictured in
Figure 2-3 which is commonly referred to as an Automatic-Enclosed Gun Cleaner.
To help NAPCTAC we would like to place before the committee some additional
information which is related to paint gun washing and "latest applicable
technology" for cleaning of paint guns and related equipment. To accomplish
this objective, a distinct differentiation is made between Automatic-Enclosed
Gun Cleaners (Figure 2-3) and the "typical open gun cleaner" described in
Section 2.6 page 2-17 and pictured in Figure 2-4 also known as a Manual-Open
Gun Cleaner. The major differences are compared below:
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Differences Automatic-Enclosed Manual-Open
1. Closed during yes no
cleaning
2. Cleans guns without yes no
worker direct
participation
3. Cleans multiple guns, yes no
cups, stirrers,
strainers and other
paint related equipment
simultaneously
4. Cleans inside and yes no
outside of guns
simultaneously
5. Workers are exposed no yes
to solvents during
cleaning cycle
Much of the draft seems to paint both Automatic-Closed and Manual-Open Gun
Cleaners with the same brush. This overlooks key issues such as solvent
consumption, worker exposure, cleaning cycle time, other items which must
constantly be cleaned along with the paint gun and simultaneous mult.iple gun
cleaning all of which impact on the VOC emission and worker exposure.
As a part, of the "improved housekeeping practices" referred to in Section 3.1
page 3-1, Automatic Enclosed Gun Cleaners can play an important role. They
affect radically the amount of time required for cleaning guns, cups,
stirrers, strainers, etc. reducing worker direct exposure to solvents while
limiting potential escape of V.O.C. Over the old methods of cleaning, they
significantly reduce solvent usage and the amount of solvent which must be
maintained at the shop. Virtually all of the tools and related items which
need constant cleaning including strainers, stirrers, and mixing vessels can
be cleaned in the automatic gun cleaner at the same time the guns are being
cleaned eliminating the need for multiple open containers for various cleaning
functions.
We take issue with the final paragraph in section 3.4 page 3-10 implying that
"Open Gun Cleaners emit no more VOC than Enclosed Gun Cleaners." The report
referred to was submitted to SCAQMD in order to obtain a variance allowing
manual-open gun washers to be used in Southern California. The report was
paid for by the waste hauler owning the rental equipment; the test itself
varied from the testing procedure recommended by the SCAQMD, and did not
reflect knowledgeable usage of the competitive units, totally ignored multiple
equipment cleaning which is essential and used antiquated competitive models.
1061
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With reference to Section 4.3.1. page 4-14, it is possible that minimal
solvent could be emitted from closed gun cleaners, but this possibility was
virtually eliminated long ago by a redesign of the lid. (See Attachment No.
1). All Herkules manufactured or licensed units have or will have soon
incorporated this feature.
The issue of escaping V.O.C., 4.3.1 page 4-14, during the loading (no hose
connections are required in our standard automotive Automatic-Enclosed Gun
Cleaners) is a valid concern and can be addressed two ways. The first, way is
through education and the second way is through the use of a speed controlled
lid opener and closer.
Proper opening of the lid on any solvent container requires education. The
worker does not want to create any more suction during opening and no more
fanning of fumes during closing than necessary. Hence the industry needs
instruction. A sample of such instruction for any vessel containing solvent
could read as follows:
CAUTION:
READ BEFORE OPENING
Solvent fumes are normally heavier than air and if not disturbed
will remain in the container. To prevent fumes from escaping,
open and close lid slowly.
1. Open lid about one inch to equalize the pressure inside
and outside. Then open slowly, this mimimizes the escape
of fumes through suction.
2. Do not slam lid during closing, lower lid slowly to prevent
fanning which can cause fumes to escape.
In the Definitions Section 6.2 page 6-3 under the heading Gun Cleaner,
reference is made to being "vapor tight"; no gun cleaners in common use are
100% vapor tight. In fact, if they were vapor tight chances of fume emission
would be increased during loading and the cleaner could become dangerous under
pressure as the content in most cases are extremely volatile. For this
reason, we believe Sections 6.2 page 6-3, 6.6.2 page 6-10 and Appendix D, page
D-3 Gun Cleaners and Appendix D page D-5 Equipment Standards (d) (1) (iii)
need modification to read "reasonably vapor tight" not "vapor tight."
We are continuously trying to improve the design and application of cleaning
equipment to provide both the autobody repair and industrial paint industries
with "state of the art" equipment. The draft does not take into
consideration the latest models of automatic-enclosed cleaning equipment which
have solved many of the VOC emission problems, for example:
1062
-------
Features
1. Double barrier lid
design.
2. Speed controlled lid
opener and closer.
3. Hose cleaning for
pressure gun fluid
lines.
4. Paint can and paint
lid cleaning.
5. Combination gun and
paint can washing.
Herkules Models
Containing Features
All Herkules models
GWR-lOO-vSS
GWR-3-100-SS
CWR-4-100-SS
GWR-3
GWR-3-100-SS
CWR-31
CWR-31-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
CWR-4
CWR-4-100-SS
CWR
CWR-1
CWR-31
CWR-31-100-SS
Result
Reduction of VOC emissions
during both active and
passive states.
Reduction of VOC emissions
during loading and un-
loading.
Reduces solvent needed for
fluid line cleaning, VOC
emission and the need for
open solvent containers
during cleaning.
Allows paint cans to be
reused as mixing or
storage containers,
reducing solid waste
generated in the form
of paint sludge. Converts
quart, gallon and 5 gallon
cans considered hazardous
to non-hazardous reducing
disposal costs and re-
ducing the amount of
paint which is sent to
hazardous dump sites,
inside cans.
One cleaner cleans
both guns, cups,
stirrers, strainers, etc
and paint cans/lids.
In a world of constant change, obviously it is impossible to take all
available technology into consideration before approving the guidelines.
With minor adjustments to the draft including more specific wording on
Automatic-Enclosed versus Manual-Open Gun Washers and changing the concept of
"vapor tight" to "reasonably vapor tight" the document should become an
acceptable guideline.
Youxsvery truly,
Richard A. Robb
President
RAR/lw
-------
ATTACHMENT No. 1
ORIGINAL
ALUMIHUM
LID
ALUMINUM
FRkME
HEW
JILUM/NUM
LID
VAPOR
SfAL
PL AST IO
\ TUB
GWf? LID /TUB FIT
PLASTIC TUB "
CORP
BY LG
DOUKICSEAL LID
STMHLEZS 5TCCL TUB
-------
AUTOMOTIVE PRODUCTS
Technology and Planning
Wilmington, Delaware 19898
November 14, 1991
Mr. Bruce C. Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Dear Mr. Jordan:
COMMENTS ON THE AUTOMOBILE
REFINISHING CONTROL TECHNIQUES GUIDELINE
DRAFT FOR NAPCTAC REVIEW ON 11/21/91
It is recognized that the subject draft guidance
is in its early stages of development and therefore subject
to various changes. Once it is completed and acted on by
the various states, it will forever change how the
refinishing industry does business and the kind of quality
product and costs it can deliver to the ultimate customer,
the consumer. It is therefore very important that EPA's
guidance document accurately describes the industry, what
VOC reductions can be reasonably achieved, and that it is
factual. These comments are given in the hope that what is
presented here will help in that regard.
In general, the draft guidance document as a whole
makes a good descriptive representation of the industry.
The analysis given is quite complete and substantially
correct. Some treatments, however, have to be questioned
and should be modified, corrected, changed, or described
more fully. First some comments of a general nature that
will be followed by specific comments on the various
sections in the document.
EPA is aware of the Suggested Control Measure
(SCM) that has been developed by the California Air
Resources Board (CARB) for the refinish industry for the
more stringent requirements for ozone attainment under the
California CAA. The SCM establishes RACT and BARCT guidance
after a long process of evaluation and interactions with the
industry. Du Pont supports the SCM and has developed
refinish systems to meet the RACT guidance. As the BARCT
requirements are technology forcing, we are expending all of
Better Things for Better Living
-------
our R&D efforts to satisfy the BARCT guidance for refinish
repair systems. The refinish industry is a highly
distribution intensive industry with the added
responsibility of the paint suppliers having to train body
shop operations in the use of new, lower VOC repair systems
required for SCM based regulations in California. It is
only logical and cost effective to have equal requirements
established in other jurisdictions. It is readily apparent
that 30 or 50 different VOC requirements across the nation
requiring different technologies for each VOC level of
repair systems, and the thousands of color match
developments, would be beyond the capability of any paint
supplier, no matter how large. It is therefore very
surprising to find the draft CTG document not acknowledging
the work done by CARB or the existence of the SCM. It is
our belief that RACT established in the SCM is in fact
appropriate to be RACT for the CTG applied nationally. The
BARCT standards in the SCM are technology forcing and
therefore do not constitute RACT for the proposed CTG.
It is true that Du Pont, as well as our
competitors, are supporting the SCM standards and R&D work
is currently in place to deliver repair paint systems with
the specified VOC limits. Whether they can be achieved by
us, or anybody else, only time will tell. Inventions cannot
be mandated by a certain date. Should EPA consider using
BARCT standards as an option for a possible RACT standard,
there are two difficulties. By definition, BARCT is not
RACT. Secondly, were state agencies or air districts to
adopt such standards into their SIPS, they become law and
cannot be relaxed. Should industry fail to achieve these
technology forcing standards by a certain date mandated,
what then? Do body shops cease to operate in that
jurisdiction? For this scenario, it is necessary that the
CTG provide for some mechanism of alternatives until such
technology can be demonstrated.
The subject draft guidance assumes that technology
transfers (from high VOC systems to lower VOC systems, to
waterborne systems, etc.) can be readily made without
extensive operator training, process changes, change in
productivity, change in quality, color match capability,
more frequent re-repair, or the cost structure beyond the
change in price for a gallon of paint purchased. Such
uneven treatment is very unfair and very misleading and
should be corrected. In fact, a lot of these effects will
force a lov. of the marginal shops to go out of business.
This will cause a realignment of body shop numbers, size and
type. Competitive pressures will drop for the surviving
shops and costs will skyrocket for the consumer to get his
vehicle repaired. Insurance rates will rise significantly
as well. As an example of one effect: In the proposed
Option 2 level controls in the draft guidance the suggested
limits for certain categories of coatings will dictate the
- 0
JL 0
-------
use of waterborne technology. For primer surfacer
waterborne types have been recently introduced into Los
Angeles because of technology forcing regulations. Topcoats
have not been demonstrated in this industry to date,
contrary to the implied availability in the draft document.
In any event, it can already be shown that waterborne
primers require 2 to 3 times the time to process; that is,
to apply, to dry, to sand, and time to topcoat than solvent
borne coatings. The quality of the finish also changes.
Only time will tell whether such repairs will hold up to
expected performance standards, or more re-repairs will not
be necessary. This situation is already causing a
realignment of body shops in the LA area. Even if
waterborne topcoats were to be available, the same impacts
would also apply. One would have to add the questions of
color match, aluminum flake gassing tendencies, and
performance properties. It is obvious that this draft
guidance does not develop these issues and therefore does
not caution agencies as to the inherent difficulties that
technology forcing standards could present for the industry
as well as the agency's ability to achieve claimed VOC
reductions.
Dividing the industry into eight arbitrary model
body shop segments pigeonholes the industry to a degree that
might not apply in actual fact. (It is difficult to say
that a particular shop size uses 25% lacquer or 75% lacquer.
A lot of times his customer base dictates what he will use.)
Such categorization could mislead state agencies into making
misguided assumptions about emission inventories, reductions
that can be achieved, or the regulatory levels that should
be set.
The draft guidance make a good case for the
effectiveness of using high transfer efficiency (TE) to
achieve VOC reduction. In fact, they could be substantial,
far beyond reductions that can be achieved through coating
reformulations, and in combination could provide drastic
reductions of VOC from this industry. Use of high T.E.
equipment is also very cost effective as the draft points
out. However, then the draft backs out because its use is
not readily verifiable. This position should be
reconsidered by EPA. It is just as verifiable as running an
incinerator, absorption unit, or biodegradation unit. They
all have variability that must be accounted for. Some
procedure must be provided, if only through mass balance
accounting, to allow for T.E. credit. EPA allows this
procedure for large sources, then why not for these small
sources. (See also comments below for Section 3.3.2.)
Add-on controls, as Option 3, are dealt with quite
evenly in the draft guidance. Whether the cost estimates
are low, high or about right is not at issue. The analysis
plainly shows that they are prohibitive for this industry.
JL .' 3 8 7
-------
Adoption of Option 3 as the control method would drive 3/4
of the body shops out of business. Option 3 should be kept,
however, as an alternate means of compliance for future
situations. As the body shop population changes, or add-on
technology gets refined, add-on controls could become a
viable option for body shops. Other than costs, this draft
implies that add-on controls are easy and viable for this
industry. What the guidance does not point out is that it
has never been demonstrated in a commercial situation. The
difficulty with this approach is that for technical reasons
it will not work for intermittent sources of emissions as
body shops invariably are. It becomes virtually a nightmare
to effectively manipulate and manage the variables involved
for intermittent sources.
It is critical that the document more clearly
shows that the composite calculations for multi-stage
topcoat (basecoat-clearcoat and basecoat-midcoat-clearcoat)
are critical to allow setting of VOC limits for both Option
1 and Option 2. Since any such limits are technology
forcing, this treatment of topcoat VOC will give coating
suppliers a good chance to achieving such reductions.
Failure to do so reduces such chances drastically. EPA has
documentation in hand from the Bay Area and CARB when those
regulations and guidance were developed that show this to be
a critical component when setting VOC limits for topcoats.
Actual source data also supports this treatment when applied
in practice.
Specific Items Needing Attention
Sec. 2.1 Document states that industry does not deal
(Pg. 2-1) with heavy trucks but is covered in another
CTG document. This is not true as that CTG
deals with OEM situations not refinishing
(repairing). Thus, mobile equipment such as
farm machinery, construction equipment and
heavy duty trucks are not covered by the OEM
CTG or this refinishing CTG.
Sec. 2.3.2 It is true that hardeners promote curing but
(Pg. 2-8) are also used to increase gloss and/or
durability.
Sec. 2.3.4 It is true that waterborne primers have been
introduced in the SCAQMD and Texas Dallas/Ft.
Worth area to meet the regulatory
requirements there. No waterborne basecoats
are yet anywhere in commerce as this section
implies. (A non-coalition member advertises
that such a product exists in SCAQMD. It is
not found in any shops known to Du Pont.) It
is one thing to claim, but another whether
reasonably available.
-------
Sec. 2.2.5 "Gun blending" as described does work when
(Pg. 2-4) using high VOC coatings and conventional
spray. It becomes far more difficult to use
this procedure effectively when dealing with
low VOC coatings especially when coupled with
higher T.E. spray equipment. Even after
extensive operator training this still
remains a complicated task and leads to
likely redo's. See also Sec. 2.5.2 last two
paragraphs to reflect the above reality.
Sec. 2.5 Airless spray guns should be air atomizing
(Pg. 2-11) spray guns.
Sec. 2.5.1 Airless should be changed to air atomizing.
(Pg. 2-12)
Sec. 2.6 The guidance shows that some companies
(Pg. 2-17) provide solvent recycling only to shops that
rent their gun cleaning systems. In our
view, this is anti-competitive and strictly
based on profit motive, and not very
environmentally friendly. It should not be
sanctioned in a guidance document.
Sec. 2.7 Document implies that coatings manufacturers
(Pg. 2-20) do not have the resources or time to devote
testing product compatibility with
competitors' coating. That might be true,
but the document should also show that such
cross competitors combination testing becomes
astronomical in scope, and if even possible,
could confuse the user and produce many
failures that would have to be re-done.
Sec. 2.7 Study implies OEM color usage could be
(Pg. 2-19) restricted, or return to single stage
coatings, would reduce VOC emissions. That
is not quite true. Use of few colors will
reduce complexity but use of single stage
coatings over multi-stage will not reduce
coatings usage as they are applied, at about
equal film thicknesses. Even if it were
true, then at what costs? Study should also
point out that this approach would leave no
domestic automobile industry in place!
Sec. 3.3.1 The assumption that twice as much clearcoat
(Pg. 3-8) would not be needed might be true
theoretically if solids content is the only
criteria. In practice, however, this does
not hold, based on cost as well as how the
two components get used. Clearcoat in all
spot repair and panel repair always gets used
-------
over a larger area. This is 90% of all
repairs being done. Basecoat, being the more
expensive, always gets used as a minimum to
get the job done. Actual industry studies
have validated this ratio consumption. In
fact, the ratio understates what it is in
practice.
Sec. 3.3.1 Document states that Option 2 coatings are
(Pg. 3-5) currently available, can achieve color match,
but are not as widely used. As already
stated elsewhere, Option 2 coatings are not
readily available, hence no color match
predictions can be made. All VOC levels in
Option 2 are technology forcing.
Sec. 3.3.2 We agree that transfer efficiency is diffi-
(Pg. 3-9) cult to verify. However, the benefits of
using such approach to control VOC emissions
must not be ignored. It can be documented
that shops changing from conventional spray
to HVLP, for example, cut their coatings
purchases roughly in half. This method of
control reduces VOC emissions far more
drastically than product VOC reductions
alone. In combination the VOC reductions
that can be achieved can be over 80%. EPA
must find a way to deal with this issue.
Past experience by EPA is for large source
control, where testing procedures could be
required to verify T.E.. Body shops are
quite different sources, small and
unsophisticated. A method should be found,
if no more than mass balance accounting, to
arrive at some T.E. credit for VOC controls.
In fact, the economic gain by shops could
off-set some of the other costs accrued
through regulations.
Sec. 3.3.3 This technology, use of supercritical gases
as the solvent component in spray application
is in the quite distant future and not as
implied. It is one thing to paint a
recurring, monotonous article than to re-
paint the ever changing repair of differently
configured vehicles, especially for the many
small color changes required.
Sec. 3.5.1 As stated in the general section, add-on
control devices should be acknowledged that
they are not feasible for intermittent
sources.
1070
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Sec. 3.5.3. Biofiltration might be an effective means for
add-on control for emission streams that are
constant and predictable. In a body shop
configuration the VOC emitted is intermittent
and also varies from product to product used.
It is questionable whether a given bacteria
colony will digest the various VOC's
uniformly. This technology needs to be
demonstrated for the body shop setting first
before the guidance document should imply
that it is or might be viable.
Sec. 3.7 Document states that waterborne basecoats are
(Pg. 3-17) available. This is disputed as presented in
the general comments.
Sec. 4.2.1 The film thickness required for each
(Pg. 4-5) coating shown have to be questioned. For
pretreatment wash primer (precoat) 0.1 to 0.5
mil thickness is more likely than the 1.0 mil
shown. For primer surfacer a 1.5 to 2.0 mil
is more representative than the 2.25 mils
shown. For primer sealer a 0.75 to 1.25 mil
film is more representative than the 1.75
mils shown. For topcoats a 2.0 to 2.5 mil
thickness is more representative than the 3.5
mils shown. In the case of topcoats the
thickness represented can occur when highly
transparent colors are used and extra film
thickness is needed to get hiding. EPA's
information source should be checked to
determine if information is average film
build or maximum.
Sec 4.2.1 Assigns 35% T.E. to conventional spray. It
(Pg. 4-7) is more like 25-30% T.E. in practice.
Sec. 5 Table does not account for regeneration and
(Table 5.5) disposal costs in the carbon adsorption
column. They could be significant even if
such a service were available.
Sec. 5.5.2 In use of waterborne coatings, there is the
(Pg. 5-13) potential to contaminate water discharges
that the document does not point out.
Sec. 5.5.3 The disposal costs are not acknowledged for
(Pg. 5-14) waterborne coatings which can be significant.
Costs can be 6 times as high as solventborne
wastes.
Sec. 5.6 It is interesting to note that the costs for
(Pg. 5-17) the industry are not presented, only by model
stages. A quick calculation shows that for
-------
Option 2 the industry costs are close to $600
million as an average. And this does not
account for some of the productivity cost
changes and insurance premium costs changes
that need to be added as these comments have
pointed out.
Sec. 6.2 Gun cleaners to be vapor tight needs to be
(Pg. 6-3) fuller defined. It should specify that it
can't exceed x grams/hours of active losses
and y grams/hour of passive losses or at
least state "reasonably" vapor tight.
Sec. 6.2 Topcoat definition needs to define these
(Pg. 6-4) multi-stage coatings to be controlled by a
composite number arrived on the basis shown
in Sec. 3.3.1 (Pg. 3-7).
Sec. 6.4.1 As pointed out earlier. Option 2 coatings are
(Pg. 6-6) not readily available.
Sec. 6.4.2 We disagree with the finding that body shops
(Pg. 6-7) could be required to use shared painting
facilities. This is blatant social
engineering and goes against free trade
practices and anti-trust principles. It is
one thing to let the free market produce such
alignments, and quite another when it is
commanded. Also, the desire that is laid out
for biofiltration in this section must be
tempered with the comments made for Sec.
3.5.3.
Sec. 6.5.3 It is important to state that the equations
presented in Sec. 3.3 must be applied, not
if, in order for industry to have a chance to
achieve the VOC requirements recommended.
Sec. 6.6.2 Vapor tight needs to be defined as commented
earlier. (See Sec. 6.2 comment.)
App. D Appendix, as currently drafted, is
incomplete. This should be redrafted to
include all the findings of the document and
the corrective comments provided. This is
critical as this is the output of a CTG that
will be used by agencies to place into
regulations.
App. D,a Topcoat definition should contain the
equations as laid out in Sec. 3.3.1.
App. D,d,l(iii)Vapor tight must be defined as explained
above.
•n,
-------
App. D,c,3,(i) Topcoat VOC limits must include per
definition given composite formula as in Sec.
3.3.1.
Table 3-1 This table apparently represents in concise
(Pg. 3-6) form the findings of the draft document.
There are a number of difficulties here and
might mislead state agencies in a number of
ways. First, the baseline VOC ranges given
represents controlled areas' VOC emissions
(California) not the uncontrolled emissions
in the rest of the nation. Our industry
survey data to EPA clearly show the
difference. This will lead to agencies
calculating wrong baseline emissions for
their jurisdiction. Secondly, the VOC limits
for Option 1 and Option 2 seem to be set
quite arbitrarily and are not properly
documented. It seems the kind of assumptions
that were made are, as an example: Since
urethane coatings generally are lower in VOC
content than others, the limits can be set at
that level. What it doesn't account for is
that urethane coatings work well for overall
repairs, but do not work well at all for spot
repair work (the majority of repairs).
Urethane coatings also do not give good
metallic appearance and are difficult to use
in spot repair that will duplicate the
original finish. As argued in the general
comment section, this table for Option 1 and
Option 2 VOC levels should follow the SCM
determinations for RACT and BART VOC limits.
We are pleased to have offered this analysis for
the draft CTG for refinish. I am available to expand on
these items if EPA so desires. I look forward to working
with EPA to develop a workable and reasonable CTG for the
refinish industry.
Very truly yours,
Karl R. Schultz
Environmental Consultant
KRS/kle
-------
December 2, 1991
Mr. Bruce Jordan
Director, Emission Standards Division (MD-13)
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Dear Mr. Jordan:
I am supplying some additional information along with a copy of
the presentation that we submitted at the November 21 NAPCTAC
meeting.
Most of it is self-explanatory. The CARB document was referred
to by us fairly extensively in the our presentation. The article
from an automotive refinish professional magazine supports our
arguments concerning the deep rooted extent of the product
systems nature of the industry today. Also, the material from Du
Pont compliments similar instructional material that was referred
to by Ron Hilovsky of PPG.
Also you should be receiving separate comments from many of the
members of the Coalition.
It was good to meet you at the meeting. I have to tell you, in
all honesty I do not believe that I would have been able to hold
up as well as you folks did in those marathon sessions.
If you need additional information, please contact me.
,National
, Paint&
Coatings
Association
Sincerely
Senior
Counsel, State Affairs
Secretary to the NPCA Automotive Refinish Coalition
1500 Rhode Island Avenue, N~W • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549
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National
^ 'Coatings
POSITION PAPER Association
OF THE NPCA AUTOMOTIVE REFINISH COALITION
CONCERNING
DRAFT AUTOMOBILE REFINISHING CONTROL TECHNIQUE GUIDELINE
**************
Introduction
The NPCA Automotive Refinish Coalition; The Automotive Refinish
Coalition was formed in 1988 under the auspices of the NPCA to
work for effective and nationally consistent VOC regulations for
the automotive refinish industry.
The active participants in the Coalition are the six national
manufacturers of automotive refinish paints and coatings: AKZO
Coatings, Inc.; BASF Corporation; E.I. du Pont de Nemours; Nason
Automotive Coatings; PPG Industries, Inc. ; and the Sherwin
Williams Company. Collectively, these companies account for the
lion's share of the total volume of automotive refinish products
that are sold in the United States. These companies also provide
the majority of the training that is taken by individuals to
become proficient in the use of automotive refinish products.
The six individuals who represent these companies on the
Automotive Refinish Coalition collectively possess over 150 years
of experience in the industry. They therefore are in a
particularly good position to comment on the industry's products
and the underlying economics and operational requirements of
automotive refinish facilities.
The Coalition also has as adjunct members a number of trade
associations that represent user segments of the industry. While
the adjunct members generally support the positions taken by the
six manufacturer members of the Coalition, they have not had an
opportunity to review this position paper. Consequently, the
positions taken should be seen as representing only those of the
six manufacturers.
Objective of the Coalition; The objective of the Coalition is
the development of nationally consistent VOC regulations that
achieve significant, real and effective reductions in VOC
emissions from automotive refinish facilities while not imposing
unnecessary additional costs or losses in productivity on the
automotive refinish facilities.
Moving to lower VOC containing products will create enormous
productivity problems for automotive refinish facilities. Our
1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549
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concerns on this score are particularly strong because the
industry has a large population of small businesses.
Approximately 40% of the shops employ less than five individuals
and have sales volume of under $150,000 annually, according to a
1988 EPA study of the industry.
Effective VOC Regulations Must Recognize and
Incorporate Industry's Practices and Operational Realities
To achieve the objectives of significant reductions in VOC
emissions from automotive refinish facilities at the least amount
of unnecessary economic disruption to the industry, a regulatory
program must incorporate fundamental technical, operational, and
economic features of the industry.
Achieving Adequate Matching of Repair to OEM Finish: Achieving
an adequate repair that matches the existing coat so that the
repaired area is imperceptible is the central requirement of the
industry. Thousands of colors and coatings must be available for
all model years of the various car manufacturers to match the
many different features of thousands of original coatings, such
as their color, gloss, and durability, as well as the effects
that time and the elements have had on the OEM color and finish.
All of this must be accomplished at facilities with far less
sophisticated equipment, under much more difficult and
uncontrolled circumstances than exist at the original equipment
manufacturers' facilities.
Systems Nature of Today's Products; Today's products are
provided by individual manufacturers in the form of chemically
complex interrelated components to a single system. The
components of a particular repair system must be used only within
the system of the particular manufacturer and pursuant to the
manufacturer's instructions to ensure that the refinish job will
not fail.
Composite Calculation for Multiple Coat Topcoats is Essential;
The use of multiple coats involving a base coat for color and
clear coats for appearance and protection as well as in some
cases a midcoat is the predominate original equipment
manufacturer (OEM) topcoat system. The appearance of these OEM
topcoats must be matched by the automotive refinish industry and
consequently, the industry must use multiple coats in a topcoat
system.
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Comments Concerning Regulatory Approaches
The RACT VOC Limits of the California Guideline for the Industry
Should be Selected as the RACT Limits for the CTG
The purpose of the CTG is to establish technology that is the
presumptive norm for "reasonably available control technology"
(RACT) which must be implemented by states in their ozone
nonattainment areas. EPA has defined (and Congress has accepted)
RACT to mean: "The lowest emission limitation that a particular
source is capable of meeting by the application of control
technology that is reasonably available considering technological
and economic feasibility. RACT for a particular source is
determined on a case-by-case basis, considering the technological
and economic circumstances of the individual source. (44 Federal
Register 53761, 53762 (September 17, 1979))
On the basis of this standard — a standard that emphasizes the
economic and technological feasibility of control technologies in
light of technological and economic circumstances of the
sources — the VOC limits that have been established by
California's Air Resources Board's Automotive Refinish Guideline
for RACT under California's Clean Air Act (which has a much
tougher standard and program for ozone attainment than the
federal law) should be RACT for the national program. (See
attached chart for the California Guideline RACT limits.)
While the terms "reasonably available" and "feasibility" are not
defined by the EPA, an ordinary dictionary definition of
"feasible" is something that is "capable of being used or dealt
with successfully;" "available" has been defined in a manner
especially relevant to this discussion as "present in such
chemical or physical form as to be usable;" and "reasonably"
has among its ordinary meanings "moderate, fair, and
inexpensive." When the meanings of these terms are coupled with
the requirements of "economic and technological feasibility" and
the additional requirement that the feasibility of the control
technology be ascertained on the basis of the "economic and
technological circumstances of particular sources," then
whatever else RACT means, it certainly cannot mean the
imposition of technology-forcing standards on existing sources.
The California RACT limits have much to recommend them for
adoption in the CTG.
First, by actual implementation in automotive refinish
facilities, they have been proven to be currently "reasonably
available" and "technologically and economically" feasible.
Second, they have been established by the toughest clean air
program in the country. In this connection, we note that the
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California Clean Air Act has a much more stringent ozone design
value of .09 ppm as compared to the federal standard of .12 ppm.
The attached chart represents a comparison of VOC reductions that
could be achieved by implementing the California Guideline's RACT
limits.
According to the Study's Own Findings. Option 1 and Option 2
Limits Are Technology-Forcing Standards; They. Therefore. Are
Completely Inappropriate for the CTG
By the study's own statements, Options 1 and 2 represent
"technology-forcing" VOC limits, requirements that are not
currently "reasonably available" as that term is defined by the
EPA. Therefore, these options do not qualify as RACT. Moreover,
if the base coat/clear coat composite calculation method is not
employed, then the limits specified for topcoats under both
Option 1 and Option 2 are not only "technologically and
economically infeasible" for the "particular sources" of
automotive refinish facilities, they are absolutely impossible to
achieve with today's technology.
The study indicates that lacquer product systems are still widely
used by many of the smaller shops that do not have spray booths.
(See pages 2-7, 2-20 through 2-25 of the study.) The study also
assumes that such shops constitute approximately 30% of the
industry. (See Table 2-1 at page 2-22.) Moving these shops away
from lacquer products to other more difficult to use and slower
drying products will be difficult and very costly. The
unmistakable implication of the topcoat limits of Options 1 and 2
is that a large number of the industry's smaller shops will be
put out of business. The study estimates that the cost of a
spray booth would be approximately $30,000. We believe that this
estimate is low. And most of these shops are currently grossing
at most $150,000 per year. Few if any banks, especially in
today's economic climate, would lend the amounts needed for such
a capital outlay to the smaller shops. Consequently, topcoat
limits of Options l and 2 which would prevent the use of any
lacquer system do not represent a "currently" "reasonably
available control technology" as judged on the basis of
"technological and economic feasibility" of these "particular
sources."
The study also states that, "Option 1 VOC limit had the reported
disadvantage of poorly matching OEM colors (especially
metallics), indicating that they are best suited for complete
vehicle refinishing jobs." (See page 3-4.) In view of the fact
that the study also finds that the "..-. the OEMs use metallic and
*pearl' coatings on at least 50 percent of all new vehicles ",
it should be clear that the Option 1 VOC limits do not constitute
"reasonably available control technology" for this industry.
Establishing the Option 1 or 2 limits, according to the study's
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own findings and conclusions, would in effect mandate that a
larger proportion of the repairs be accomplished by complete
refinish jobs. This would necessarily result in the emissions of
more, not less, VOCs and would fail to achieve the fundamental
objective of RACT — achieving reasonable further progress
towards attainment. Additionally, there is the question of
whether establishing VOC limits that "poorly match OEM colors"
for 50% of the vehicles the industry repairs constitutes a
"technologically and economically feasible" control technology
for an industry that has as its sole reason for being the ability
to make repairs so that the repair is imperceptible.
The study also contains a number of misleading assumptions
concerning the VOC emissions that should be associated with the
industry's products and operations. The first of these involves
assuming that the VOC content of products that are supplied to
areas which currently have regulations constitute the baseline
"current technology" of the industry's products that are
generally used in the United States. (See Table 3-1 at page
3-6.) In fact, the majority of the products supplied by the
manufacturers are to areas for which no VOC limits for their
products exist, including the vast majority of current ozone
nonattainment areas. Defining baseline technology as the study
does would lead to a gross understatement of the contributions
in VOC reductions that properly should be attributed to this
industry introducing lower VOC containing products to areas that
heretofore have not required lower VOC containing products. The
Act's new requirement for reducing by 15% overall VOC emissions
in the top four categories of ozone nonattainment areas by 1996
will place extraordinary pressures upon all sources to reduce
their fair share of VOC emissions. Thus it is essential that the
CTG accurately characterize the existing VOC emissions from this
industry in these areas to ensure that it is not tasked with
regulations that exact an unreasonable contribution in VOC
emissions reductions.
Additional misleading statements and assumptions in the study
concern the following subjects: the statement concerning current
usage of coatings that implies that all coatings material
supplied to refinishers are in fact applied, when approximately
20% — 25% in practice is wastage and is disposed of by
incineration in which there is no release of VOCs; overstatements
of the required or recommended film thicknesses; and
overstatements of the paint consumption in each of the coatings
categories. These are more fully discussed in the submission
from BASF.
We anticipate the argument that since the California Guideline
1992 limits are just around the corner and that since some of
these limits are more stringent than comparable limits in Option
1, the manufacturers should be able to meet the limits of Option
1 nationwide if they can meet the California 1992 VOC limits in
California. In answer to such an argument, we point out that the
701
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products that are needed to meet some of these limits, especially
the topcoat limit, are still not yet at a stage of development
that would allow the manufacturers to introduce them into
facilities without substantial expenditures in time and
resources. These products will require the use of spray booths,
which the study itself notes are not widely used by the smaller
shops which makes up about 30% of the industry. Moreover they
will require the use of drying equipment, because the products
will be mostly waterborne products with substantially longer
drying times. In order to maintain today's levels of
productivity in terms of the number of vehicles that are
completed substantial expenditures for drying equipment will be
required.
Finally there is a question of scale involved here. It should be
noted that the California 1992 limits will be confined only to
certain air quality districts in California. While the
manufacturers may have sufficient resources to weather the
problems and expenditures that will be associated with
introducing these products into a limited number of areas in
California, imposing similar requirements nationwide results in
an effect on the manufacturers that certainly qualifies as
"economically infeasible."
We realize that the EPA is interested in crafting a CTG that
accurately reflects what can be accomplished by the industry at
the time the CTG is published and that it is confronted with the
difficulty of a moving target in the technologies. The six
manufacturers have expended literally tens of millions of dollars
thus far in efforts to develop lower VOC products and the EPA is
right to anticipate that these efforts will continue. But this
problem of RACT being overtaken by new developments is addressed
in the newly amended federal Clean Air Act. which now requires
that the EPA periodically revisit CTGs to determine if technology
has moved ahead of existing CTG standards. We suggest that this
is the only appropriate process recognized by the Act for
introducing technology-forcing factors into developing CTGs.
Requiring technology-forcing limits in the CTG itself is
completely at variance with the essential "reasonably available"
nature of a RACT standard.
We have another suggestion by which this current effort to
determine an automotive refinish CTG could avail itself of new
technologies that might be available at the time this CTG is
finalized. If this CTG development process takes until 1993 to
be finalized, it is possible that the experience gained in
meeting the California Guideline's 1992 limits in California will
demonstrate by then that the Option 1 limits and perhaps some of
the California 1992 limits are in fact "reasonably available" in
terms of their "economic and technological feasibility" for
national implementation. We note, however, that, with respect to
the California 1992 limits, the industry at the present time
-------
does not have a sealer that would meet the limit specified for
this coating. Because of this and other potential problems of
introducing such advanced systems nationwide, at the present we
believe that a lead time for implementing such limits would be
needed, e.g., implementation in 1994 or 1995.
The Necessity of Base Coat/Clear Coat Averaging For Determining
the Topcoat Limits
The multiple coat system of topcoats is the current predominate
topcoat technology of the automotive manufacturing industry and
the refinish industry must be able to match these topcoats.
Using a composite calculation for the VOC content of the base
coat and clear coat in a topcoat system to determine compliance
with the topcoat VOC limit is dictated by the actual day-to-day
"technological and economic circumstances11 and practices of the
industry.
A statement of the study which may account for the failure of the
CTG Model Rule to include a base coat/clear coat composite
calculation method is an apparent misunderstanding of the basis
for weighting base coats and clear coats at a ratio of 1 for base
coats to 2 for clear coats. The ratio is based upon the actual
usage of the industry. It is the industry experience that the
volume of base coat paint that is used for any given repair is
approximately on half the volume of clear coat that is used. In
this connection we refer you to the information that has been
provided by the BASF Corporation which is based upon the actual
usages at an automotive refinish type of operation at the Saturn
General Motors plant and by the Sherwin Williams Company. In
fact that experience indicates that the ratio is higher, e.g.,
for 1 gallon of base coat, 2.3 gallons of clear coat are used.
The study assumes that because clear coats are a higher solids
product than are base coats, then the volume of clear coat
material that is needed to repair the are covered by the base
coat should be twice the volume of base coat material. The
major reason that the industry generally uses twice the amount
of clear coat material as it does base coat material is the need
to achieve adequate color and finish match for spot repairs that
requires that the clear coat in general be extended far beyond
the area covered by the base coat. About 90% of the automotive
refinish work that is done is spot repair.
The Systems Nature of the Industry's Products
Because the chemistry of the individual components of a repair
system is highly interdependent, the components of a particular
manufacturer's system must be used according to its instructions
and cannot be interchanged with the products of another
manufacturer. The systems nature of today's repair products has
two very important implications for a regulatory system that
limits the VOC content of the products. First, regulators can
If;81
-------
have a great deal of confidence that refinishers will not attempt
to match relatively higher VOC components of one manufacturer's
repair systems with those from another and that therefore the VOC
levels associated with a particular system will be complied with.
Secondly, the regulations cannot simply select the lowest VOC
components of the available repair systems and dictate that these
components be incorporated into every repair system.
and in the right amounts. As a recent article from an automotive
refinishers professional magazine points out:
[T]here is no margin for error in applying or mixing today's
products. The paint company chemist was able to create a
product to suit, but only if you do exactly as he says. Not
only must the painter combine the correct solvent, catalyst
and topcoat in the correct percentages, but it must be
applied over the correctly mixed undercoats at the correct
time... There is only one right way to use today's
finishes; exactly according to directions and using only one
brand.
Auto refinishers will not act as their own chemists; they will
follow the manufacturers' instructions or risk a failed job
without the protection of a warranty.
Another feature of the industry that supports the conclusion that
automotive refinishers will comply with the VOC limits specified
for products is the VOC compliance instruction material and the
training that is supplied by the manufacturers to users of their
products.
The Need for Specialty Coatings
It also is essential to recognize the need for relatively higher
VOC containing specialty coatings. These products constitute a
very small percentage of the products used by the industry but
they are essential to effectively accomplishing certain repairs.
An important example of these are "uniform finish blender"
specialty coatings to make spot repairs. This specialty coating
blends the repaired area in with the surrounding original finish
to match all facets of its appearance, including color, metallic
orientation, texture, and appearance. Greater VOC emissions
would occur if refinishers do not have the ability to perform
spot repairs because they would be required to paint an entire
panel of the vehicle or the entire vehicle itself in order to
achieve acceptable results.
We recognize that the model CTG includes the category of
"specialty coatings." But its characterizing them as being
"reportedly" needed for unusual job performance requirements,
however, concerns us because that implies that the need of these
products is debatable. The special role of specialty coatings
should be emphasized by the CTG. It should not be implicitly
8
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questioned by the CTG which might invite states to modify the CTG
by removing the category.
We also recommend that the California Guideline's definition of
specialty coatings should be adopted. The definition does not
limit the type of coatings that can fall into this category but
restricts the coatings to 5% the total volume of coatings applied
by an automotive refinish facility. This approach allows for the
development of additional specialty coatings and the 5%
restrictions ensures that the category will not be abused.
The Gerieral Use of HVLP Spray Guns Results in Significant
Reductions of VOC Emissions and Should be Encouraged
The efficiency of transferring coatings to the vehicles has been
greatly improved by the use of high volume, low pressure (HVLP)
spray guns. The resulting VOC reductions that accompany the
reduced amount of coatings material that is required because of
the improved transfer efficiency should be explicitly recognized
by the regulations. To do otherwise deprives this industry of
having credited to it significant VOC reductions that in fact
result from the use of HVLP spray guns. The unwillingness of the
EPA to explicitly recognize and to credit VOC reductions
associated with the use of the equipment is a hidebound adherence
to notions concerning "quantification" and "replicability" of VOC
emission reductions. These principles were established for a
regulatory regime that focused on well-heeled and richly staffed
large stationary sources which lent themselves to such precise
demands for crediting VOC reductions. The 1990 amendments to the
law, however, require the regulation of much smaller sources and
therefore the EPA's VOC emissions reduction accreditation
principles must be retailored to measure the effectiveness of
regulatory controls that are appropriate for the much smaller
sources.
As the study notes, appropriate training has a great deal to do
with the efficacy of HVLP use. In this connection, it should be
recognized that extensive training is provided in this area by
the manufacturers of automotive refinish coatings and others.
Further, aside from the regulatory requirement to use such
equipment, autorefinish facilities have a very strong economic
incentive to use the equipment to reduce their consumption of
coatings.
It also should be noted here that the study seems to assume a 35%
transfer efficiency for the conventional spray gun but is
unwilling to assume any transfer efficiency for the HVLP- This
is anomalous in that any problems that are associated with
achieving effective transfer efficiency with the HVLP spray gun,
such as variability in operator use and the shape of the object
being coated, also apply to conventional spray guns.
1-83
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The experience of the Coalition is that the use of HVLP spray
guns results in reductions of 20% — 45% in materials usage and
some credit for the resultant VOC reductions should be given.
Add-On Controls
The various engineering add-on control technologies identified by
the study for facilities would be cost prohibitive and or
technologically infeasible for the great majority of automotive
refinish facilities to adopt at this time. Nonetheless, the
regulations should recognize such controls as voluntary
alternative control techniques that could be used in lieu of
lower VOC containing products. The technology of add-on controls
could improve in the near future, perhaps rapidly, and they
could come to represent cost-effective alternative compliance
methods.
Conclusion
The objective of the CTG is to establish a guideline for what is
the presumptive norm for "reasonably available control
technology" (RACT) under the federal Clean Air Act. In
developing such a guideline, the "reasonableness" of the
technology is to be considered as well as both its
"technological" and "economic" feasibility- On the basis of
these criteria and our knowledge of the industry — the available
coatings technology and the operational and economic requirements
of automotive refinish facilities — we believe that the VOC
limits specified for RACT in the California Guideline should be
the limits established by the CTG. The adoption of these limits
from a program that is much tougher than the federal program will
ensure that the industry contributes more than its fair share of
VOC emissions reductions in the nation's ozone nonattainment
areas. We also believe that specialty coatings must be
explicitly recognized as an essential technology for the industry
to achieve VOC emissions reductions. Further, it is absolutely
critical that the multiple coat composite calculation technique
for determining compliance with VOC topcoat limits be recognized.
This is the way the industry applies the topcoats and it is the
only way that VOC limits for increasingly waterborne topcoats can
be met. The contributions made by HVLP spray guns should also be
recognized by the CTG. Finally add-on controls should be
recognized as a voluntary alternative compliance method.
The possibility that the Option 1 or even some of the California
Guideline's 1992 VOC limits may be demonstrated to be "reasonably
available" by the time the CTG is finalized in 1993 is also worth
considering. The six manufacturers would concur in such an
approach provided that before the limits are adopted as part of
the CTG, the technology has in fact been shown to be reasonably
available and that an appropriate lead time is afforded (e.g.,
until 1994 or 1995) to ensure that the products in fact are
"reasonably available."
10
O F
'
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ON OF VOC EMISSIONS REDUCTIONS
GARB'S GUIDELINE
% Of
Total Coatings
2 CTG GARB Coatina Cateaorv
31%
-
6%
9%
5%
-
9%
8%
0%
0%
•
2% . 1%
. 1%
12% . 12%
*
•
5% . 5%
»
58% . 17%
. 41%
•
8% . 8%
•
•
10% . 10%
•
5% . 5%
•
Pretreatment Wash
Primers
Precoats
Primer/Primer
Surfaces
Primer Sealers
Topcoats***
Metallic/
Iridescent***
Surface Cleaning
Enclosed Equipment
Cleaning
Specialty Coatings
Transfer Efficiency
Baseline GARB
VOC RACT
6.
6.
6.
6.
6.
6.
6.
6.
7.
7
7
7
7
7
8
7
7
0
25%
6
6
6
6
6
6
1
.5
.5
.0
.0
.0
.0
.7
88%
7
.0
45%1
•s
0.
0.
2.
2.
3.
8.
6.
0.
2.
0.
GARB'S
1992 Limits**
1%
1%
3%
3%
2%
7%
0%
8%
8%
0%
6.5
6.5
2.8
3.5
5.0
5.0
1.7
98%
7.0
45%1
0.
0.
12.
4.
22.
19.
6.
0.
2.
0.
1%
1%
6%
3%
8%
5%
0%
8%
8%
0%
0%
GARB GUIDELINE
Reductions Achieved -0-
26.3%
69.0%
y data. Should be based on uncontrolled emissions survey data.
n 1994 - 1995 once technology has been demonstrated in California in 1992
Calculations.
ies in column expect for enclosed equipment cleaning and surface cleaning.
-------
National
'Paint&
December 2, 1991
Association
NPCA Automotive Refinish Coalition's
Additional Comments Concerning
Technical and Factual Issues Raised by "the Study
The study is an attempt to review and analyze the current
technologies, economics, and operations of the automotive
refinish industry to determine the reasonableness and technical
and economic feasibility of VOC emission reduction technologies.
The study, in our view, represents an honest effort to portray
the industry accurately and demonstrates a sound grasp of the
basic features of the automotive refinish process. Nonetheless,
it contains a number of implications, statements, and conclusion
that are inaccurate or misleading. Since the study will be the
basis for standards that will be adopted for this industry
through a CTG, it is important that it accurately reflect the
real world of this industry.
The following are a number of points of disagreements or areas in
which we believe a fuller picture is required than what is set
out by the study-
General Overview of the Industry
We have reservations concerning the characteristics that the
study assigns to various shops as model shops. This is not to
say that we disagree with all of the study's characterizations or
that we so not appreciate the difficulties associated with
efforts to get a handle on an industry as diverse as the
automotive refinish industry. Nonetheless, we urge caution in
extrapolating from these model shops to real world shops. Some
shops — perhaps many — will not fit neatly into anyone of the
models. This is particularly true with respect to the types of
coatings that may be employed by various shops.
The study also seems to fail to grasp the fact that coatings
reformulations are not easily accomplished. Besides the very
difficult task of having to reformulate literally thousands of
colors to match the diverse automotive population, these new
coatings must be transferred effectively into the production of
the shops. When the coatings become increasingly waterborne,
they become much more difficult to reformulate and they become
even more difficult to train the end user in how to use them
effectively. Lower solvent products are more difficult to use
and are less forgiving of mistakes. The transition to waterborne
products is an extremely difficult task and should be recognized
as such.
1. -88
1500 Rhode Island Avenue, NW • Washington, DC 20005-5597 • 202/462-6272 • FAX 202/462-8549
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Coatings Issues
There are several statements in the study which misapprehend the
technologies of current or future coatings or the usage of such
coatings by the industry.
The most important misunderstanding concerns the base coat/clear
coat technology for topcoats. Actual industry usage of these
coatings demonstrates that the coatings are in fact used at a
ratio of more than 2 clear coat materials for 1 base coat. The
primary reason for this is that in applying the clear coat in
spot repairs, the material must be extended beyond the repaired
area to match the original finish.
The systems nature of the industry's coatings also is not fully
understood by the study. The systems nature of today's coatings
is a fundamental fact of the industry and it applies to the
entire range of coatings, including undercoats and not just
topcoats. The failure of the study to fully understand this
leads to a number of misleading assumptions. An example of this
is the implication at page 2-8 that non-isocyanate hardeners are
generally available to replace isocyanate hardeners. In fact
this is not true if the product system involved is based on
isocyanate products. Also, the study's definition of coating
"system" at page 6-2 limits the systems to primer-topcoats.
The components of automotive refinish product systems are
designed to work together only within a particular manufacturer's
system. At page 2-20, the study implies that the components
could be made interchangeable if the manufacturers spent
sufficient time and money on the effort. As an abstract
statement, this comment is true. But it fails to recognize the
tremendous costs of such an undertaking to the manufacturers and
to the shops and the public in the form of failed jobs.
Additionally, the product differentiation that accompanies the
systems approach is a valuable incentive for the manufacturers to
continually improve their products secure in the knowledge that
technological breakthroughs that for example lower the VOC
content of products will not be easily replicated by their
competitors.
The industry is moving to waterborne products. That is a fact of
life and the manufacturers have spent tens of millions of dollars
to develop these type of coatings. Nonetheless, these coatings
are not yet generally available as is implied by the study at
page 3-17. Also the statement that waterborne higher solids
primer sealers are simply "lagging" is also misleading — they
are much further away from being practical coatings than
"lagging" implies. Perhaps some of the confusion on this point
arises from the study's understanding of what constitutes a
waterborne coating. On this score the study at page 2-8 implies
that waterborne systems have only 5% water as their volatile
-------
fraction. In fact, the industry considers a product waterborne
when it has 85% of its volatile fraction as water. Also the
study fails to adequately address the additional waste water
disposal costs that will attend the wider use of such products.
On a related subject, at a couple of points the study indicates
that the key ratio for determining the VOC content of a product
is its solvent/solids ratio. (See page 3-4.) We agree with this
concept but believe that the "less water" calculation technique
required by the EPA for determining the VOC content of products
is at variance with this fundamentally sound notion and should be
changed accordingly.
Also with respect to waterborne coatings the study fails to take
adequate account of the additional hazardous wastes that will be
generated by the wider use of such coatings and the attendant
disposal costs. (See pages 5-13 and 5-14.) Nor does it
adequately weigh the losses in shop productivity that will
accompany the wider use of the products. (See page 5-17.) Drying
times will increase greatly and shops without drying booths will
be reduced to completing one half to one third of the vehicles
that they now can complete with solvent borne products. The
ability to refinish vehicles at a reasonable cost will disappear
and the insurance premiums consumers have to pay for collision
insurance will increase dramatically.
The study also grossly overstates the current volume of products
that are used by the industry- (See the comments from BASF.) At
pages 2-3 and 2-4 the study wrongly suggests that a pretreatment
coating is exclusively used with solvent borne systems and a
precoat is exclusively used with waterborne systems. Further,
the discussion of adhesion promoters at page 6-2 should be
clarified to make clear that the material is also applied at the
edge of the unsanded area. In a related point, the study fails
to recognize adequately that specialty coatings constitute a
very small percentage, less than 5%, of a shop's total coatings
usage and that these products are critical to the shop's ability
to effect certain repairs. While it is true that these coatings
are higher VOC products, they constitute such a small percentage
of usage that it makes no sense to focus on lowering their VOC
content when the R&D efforts could be better put to reducing VOC
levels in the larger volume products.
Technology Issues
The study contains number of factual statements concerning
technology issues involving spray booths and HVLP and
conventional spray guns that are misleading.
As to the spray booths, the study at page 2-9 implies that all
coatings are applied in a spray booth. In fact a number of
-------
coatings, particularly undercoats, are generally not applied in a
spray booth. The implication of this is that waterborne products
that are used for undercoats generally would not be accommodated
in a spray booth that could reduce drying times. Hence, the
widespread introduction of the waterborne products would as
things now stand greatly reduce productivity at many facilities.
In this regard the study greatly understates the costs of
introducing the technology, by focusing exclusively on the costs
of the products and capital equipment. In fact, significant
productivity losses will accompany the use of waterborne products
and these costs must be taken into account in evaluating any
regulation that would impose them.
As to spray guns, we address the need to recognize the efficacy
of HVLP guns in the body of our comments. As we state there,
HVLP spray guns do reduce VOC emissions and should be properly
credited for doing so in the CTG. The study acknowledges at
various points that transfer efficiency in the use of the HVLP
guns can be greatly enhanced through appropriate training and at
page 3-16 stresses the important role played by the manufacturers
of automotive refinish coatings in providing this training. It
is ironic that much costlier and in our view questionable add-on
controls are considered as potentially effective by the study and
yet the efficacy of a reasonably priced piece of equipment like
HVLP spray guns receives such short shrift. The study should
recognize the importance of this relationship and see the
manufacturers as more of a partner in assuring lower VOC
emissions from automotive refinish facilities. In the same
connection, however, the study fails to recognize certain
inherent difficulties that are associated with the use of any
spray gun by implying at page 2-4 that blending the edge of the
refinish area with the original topcoat could be achieved as
readily through use of the spray gun as it is achieved through
the current practice of employing more dilute blend coats.
The discussion at page 2-15 of the problems of introducing
electrostatic spray guns into automotive refinish shops merit a
fuller treatment, especially the great risks of fire and of
electrocution that arise if this equipment is not used in
accordance with very strict operating procedures that will be
difficult for many shops to observe.
Add-On Controls
Add-on controls are dealt with fairly evenly by the study at
least in the conclusion that such controls are not presently
generally feasible for the majority of automotive refinish
facilities. Whether the study's cost estimates for these
controls are accurate (and we believe that they understate the
costs greatly), in the end the study reaches the appropriate
conclusion that such controls should not be imposed on automotive
refinish facilities as RACT. We might add that in our opinion,
-------
imposing such controls on the facilities would drive 75% of the
existing shops out of business. And some of the technological
assumptions concerning such controls are very misplaced. For
example, it is inconceivable that with today's technology that a
biofiltration system would work at any automotive refinish
facility. The VOC emissions are simply too varied for any body
of microbes to handle effectively. Also, incineration is simply
not an effective control technology for automotive refinish
facilities because of the intermittent nature of the emissions.
As to carbon absorption, the study fails to consider adequately
the costs associated with maintaining such a system, the
decreasing ability of the carbon filters to absorb pollutants
each time they are cleaned, and the hazardous waste that would be
generated by the use of the system.
Despite the admitted problems with add-on controls, we believe
that such technologies should be recognized in the CTG as a
voluntary alternative compliance option. As the population of
automotive refinish facilities changes, in part due to the VOC
limits, and as the technology of add-on controls improves, this
technology could become more viable and we believe that the
technology should be recognized as a voluntary alternative
compliance method. The modified version of the SCM which we are
suggesting as the model for the CTG contains such an alternative.
Discussions of Costs
The study's discussion of the additional costs that would be
associated with moving to more waterborne coatings do not address
what will perhaps be the greatest costs associated with their use
— losses in shop productivity. For shops without drying
equipment the use of these products could well cut their ability
to refinish vehicles to one half or a third of what it is today.
Additionally, the costs of R&D that are incurred by the
manufacturers of the coatings are not counted nor are the costs
that will be incurred in introducing these more difficult to use
products, including job failures that will inevitably accompany
the widespread use of the products initially.
Appendix D of the Study
Appendix D of the study, whether intended or not, represents the
distillation of a draft CTG that may be picked up by the states
before the CTG process is completed. Our concerns here are
particularly strong because of the requirement of the federal
Clean Air Act Amendments of 1990 that call for the adoption of
RACT by many ozone nonattainment areas by 1992 — the so-called
"RACT Catch-Up" requirements. In reconciling this 1992
requirement with the 1993 due dates for new CTGs, including the
automotive refinish CTG, the EPA has stated that states may use
draft CTGs. We have had some indication that the regulations set
out in Appendix D will be substantially modified in the final
T w O |
JL ii J1
-------
CTG. We strongly urge that Appendix D be eliminated from the
study to avoid any confusion on the part of the states during the
interim.
-------
OSfPDKD
VOC DATA
EETS
Jr. 1
cs
ro
RULE 1151
H.17T.M
-------
The following VOC data is being provided to you to meet the requirements of the South Coast Air Quality
Management District'.1; Rule 1151. It /.v divided into the following pa gen for easy reference,
Page 1 An explanation of each category of the Du Pont COATINGS USAGE CHART used to record daily
VOC emissions.
Pago 2 An example of a completed COATINGS USAGE CHART.
Page 3-6 VOC data for surface cleaner, precoal coating, primer, single stage, basecoat, and clear. This data is
reported on maximum VOC and pounds per gallon less water and exempt solvents basis.
Pago 7 Calculation for LI3S of VOC' when divided by the amount actually sprayed.
Pago
-------
' 1-l|e i'amier Name
or
Initials
7-1 John Doe
\- ''
gs
^
Ooalinps: Puini
Surface Prop, C
Manul. Type
&
Code
Example 1
B 8635A
Example 2
210S
Example 3
B8635K
Example 4
7500S
, Primer
,'lenmip Solvent
VOC VOC less
(g/1 or Waicr &
Ihs/gal) |less exempt
Solvent
i . .
5.2 r 5.2
0.6
5.9
1.9 1
5.9
5.3 5.3
Oil nly si /I liirdoiuT/Addilivc
Miiniil'iii'liiiei i VOC
& 1 (g/l or
Code
793S
-
-
7575S
Ihs/gal I
1.9
-
-
4.2
VOC' less
Water &
less exempt
Solvent
1.9
-
•-
4.2
Tli iniuT/R (Mincer Solvent
Manufacturer
&
Code
V-8096S
-
V-7I60S
-
VOC
(g/l or
Ihs/giil)
6.9
-
6,6
VOC less
witter &
ess exempt
Solvent
6.9
-
6.6
-
Total amount of
comings used
1qt.
1 qt.
2qts.
3qts.
Mix Ratio Gross VOC VOC "a- L.:^
Coaling/ Vehicular ";!•. applied" Applied" k"-< c'f VOC
Solvent Weight water & !e«
exempt solvent
i
8:1:2 : II 5.2 5.2 1.3
I
RTS i II - 1.9 .5
I
1:1 ; II 6.2 6.2 3,1
i
4:1 | II 5.1 5.1 3.8
-------
,m- I'niniL'i Njuno
"or
nilials
A B
Coatings: Paint, Primer
Surface Prep, Cleanup Solvent
Mamil. Typo VOC
& t.g/1 or
Code Ihs/pal)
C D
i
VOC less
Winer &
less exempt
Solvent
Cntnlyst/Hnrdcncr/Addilivc
Maiuifiieiurer
&
Code
F
VOC
(U/l or
llw/giil)
G
v(x: less
W.-iicr &
less cxempi
Solvent
H
Thinner/Reducer Solvent
Miimil'iieiuri:r
&
Code
1
voc:
(g/lor
Ihs/gal)
J
VOC less
wilier &
less exempt
Solvent
K
Total amounl of. Mix Ratio. Gross VOC VOC "a« l.r>v
coalings used ! Coaling/ '• Vehicular "as applied" Applied" lc« tn' VOC
(quarts or gal) | Solvent i Weight water & lc«
j : exempt solvent
L M ! N 0 P Q
i '"!
Coatings Usage Chart Explanation
,J\
The date in which the material is sprayed.
I'hc name or initials of the painter actually spraying,
The formula or product number. (Include the total alpha-numeric formula.)
I hr m.minimi Vl)(' nl ihr individual i/oaliiu1, without ivdnirr in eaialyM. as lislcd in
ihe On Pont VOC Data Sheet. (The ColorNet computer or microfiche lists VOC' of
each color coating.)
The VOC in this column is (lie same as "D" *
This column is Cor hardeners or catalysts,
The VOC of (lie individual hardener or catalyst, obtained from VOC data sheet.
The VOC in this column is the same as "G" *
List the On Pont solvent number.
The VOC of Ihe thinner/reducer as stated on the VOC data sheet.
The VOC in this column is the same as "J".*
This column lists (lie amount of material actually sprayed.'
\li\ini; raiio of all components. This information is listed on the VOC ilaia sheet,
N. There are two ealegories:
"1" greater than or equal to 8500 Ibs. G.V.W. (> or = 8500 Ibs.)
"II" less than 8500 tbs. G.V.W. (< 8500 Ibs.)
(). VOC' "as applied" means the ready to spray VOC of Ihe material applied in relation to
the mixing ratio and VOC of the individual components. Also called "ready lo spray"
or"RTS"
P This column is the same as "0",*
Q. This column represents the total pounds of VOC emitted, based on the "ready to
spray", pounds per gallons of the coating and quantity actually sprayed.
For example: the ready to spray VOC of 7500S is 5.1. Three quarts were actually
sprayed, see example 4 on page 2.
* The column is different only when recording the following list of products which
contain waier or exempt solvent:
2! OS 225S 227S 616S 3929S 57 ITS
224S 226S 244S 620S 5662S
-------
VOC DATA SHEET
RULE 1151
SURFACE CLEANER
MAX. VOC loss
MANUFACTURER TYPE 4 CODE ^ ! ™p|
Ibs/gal) j Solvent
PREP-SOL' II
3929S 1.2 i 4.9
I
!
1
PRETREATMENT COATINGS
t '•
—-3
us
sr>
5717S 1.4 ' 3.7
224S . 0,0 i 0.0
225S .;..1.3.. 3.9.. .
226S i 0.0 " i 0.0
227S : 0.0 ! 0.6
244S ; 5.7 | 6.5
i
PRECOAT COATING
VARIPRIME'
615S j 5.2 , 5.2. ._
615S : 5.2 ! 5.2
; i
I
I
PRIMER
WATERBORNE
210S 0.6 ' 1.9
Cnliilyst/IInrdencr/Addilivc
M;inul';u.'iuivr
K
Code
VOC'
(i:/l or
Ins/gull
VOC less
Winer &
less exempt
Solvent
— | — i .—
. ; i
1 i
—
_
I
1
i
j
1
- - - - -i — ' -
61 6S
620S
6.5
6.2
— :
,
6,6
6.3
—
Tli in nor/Red ticcr Solvent
Mumil'iieliirer
K 1
Code
-
WATER
WATER
• ~
—
—
voc
tg/l or
Ihs/gnh
VOC loss
wmer &
less exempt
Solvent
— i
•
. ^ .
—
- •
Tdliil iimoiilil i)l Mix Riltio Clross VOC' VOC ";is l.hv
conlhi.us used i C'oiiUMi!/ Vehieuliir ";i* .ipphed" ApphoU" le^1- "!' VOC.'
(i|Uiirl.s or gut) ! Solvent Wei.ehi unier & loss
1 • excmpi solvent
RTS 1.2 4.9
j
1:1 3.7 37
RTS 0.0 0.0
1:2 3.9 3.9
RTS 0.0 0.0
. RTS 0.0 0.0
RTS 6.5 6 5
;
1:1 . .. 5.8 . 5.9
1M 57 57
1
RTS 06 19
-------
VOC DATA SHEET
RULE 1151
"»
SURFACE CLEANER
i MAX.
! \jf \p
MANUFACTURER TYPE i CODE i (^f
Ibs/gitl)
PREP-SOL' II
3929S i 1.2
i
I
VOC less
Winer &
less exempt
Solvent
4.9
PRETREATMENT COATINGS
f*
r)
<*£>
.>. V()(' VOf'";is !>>..
ciKiliMji-i used i Gulling/ Vchii'iibr "n- .ipplietl" Applied" le^x pi' VOC
(((linns or gill) I Solvent Weijiht uuier A Ic^v
i . exempt solvent
RTS 1.2 4.9
1:1 3.7 37
RTS 0.0 00
1:2 3.9 3.9
, ,.-RTS °-° ° °
:'"RTS. ... 0.0 ^ 0,0
: RTS 6.5 "' 6.5
;
. 1:1 5.8 5.9
1 : ' "i 7 IS 7
I
RTS 0.6 1.9
-------
ATTACHMENT B
Article from BodvShop Business
-------
PaintShop
Common Complaints,
Specific Solutions
by Mark Clark
n these days of fast-paced
produce/deliver auto repaint-
ing, it's haro^tp get a simple
explanation for tne~cause of common
painters' problems. In this series of ar-
ticles, we are going look at some of the
most common complaints and try to
explain in simple terms (no degree in
chemisty required) what went wrong
and why. These discussions are as ge-
neric as possible, and no one brand of
paint is being promoted over another.
And that leads us to the absolute
quickest way to reduce all your paint
problems, no matter what brand you're
using or what part of the country you're in.
You can reduce your painting related problems by —
ready? — 50 percent. Sound like something you'd be
interested in? Instead of 10 problems a week or 10
problems a month, you can skip right down to only 5
problems.
How? It's easy, it's simple, and it's guaranteed to
work. Use one brand all the way through, follow a sys-
tem! When all the undercoats, solvents, topcoats and
clears are guaranteed compatible, you'll have 50 per-
cent fewer problems. Problems like adhesion, durabili-
ty and re-coatability drop to the very minimum.
The notion that any shop painter can don the chem-
ical engineer's hat and start mixing products and
systems goes back to the days when this business was
much simpler.
Back in the days when most undercoats were a lac-
quer base and most topcoats were either lacquer or a
simple acrylic enamel, shop painters figured out that
they could substitute a cheaper solvent from some oth-
er manufacturer and then color with yet a third brand
and seldom have problems.
Like the paint reps say, one of the
hardest guys to deal with is the paint-
er who combined-several brands^nd
didn't have a problem, once or twice or
even ten times. Then, when his "sys-
tem" doesn't work, he can't accept the
fact that he was just lucky each of
those other times.
The reason that intermixing is such
a tremendous risk these days can be
traced back to the vehicle manufactur-
er. The consumer keeps demanding a
better looking, more durable, more
corrosion-resistant finish. The manu-
facturers have been able to deliver
OEM finishes hundreds of times better than just a feu-
years ago. Now here comes that super high-tech finish
into the body shop to be repaired "as good as new."
The aftermarket paint companies have really had to
scramble to create air dry (no heat or electricity like
OEM) finishes durable enough to match original
equipment. This, as you might imagine, was quite a
trick.
What this means to body shop painters is that there
is no margin for error in applying or mixing today's
products. The paint company chemist was able to
create a product to suit, but only if you do exactly as
he says. Not only must the painter combine the correct
solvent, catalyst and topcoat in the correct percent-
ages, but it must be applied over the correctly mixed
and applied undercoats at the correct time.
There is only one right way to use today's finishes:
exactly according to directions and using only one
brand. Besides reducing your paint problems 50 per-
cent, several other benefits also occur. You will have
fewer products (read that — dollars) in your inventory,
(continued on pg. 82)
80 / June 1990 / BodyShop Business
-------
/continued from pg. SOt
and since the same system is used all the Lime, every-
one gets good at it and more work is produced in less
time. Knowing what one line will do under a variety
of conditions is better than guessing what a vari-
ety of products will do under the same condition.
Now. having solved one half of your paint problems,
let's take a look at some of the other ones that are left.
It's simple to solve
half your paint problems.
One of the most common and frustrating paint prob-
lems is die-back. Die-back means that over time the
paint job loses the gloss it once had. Only one thing
causes die-back: trapped solvent. It is always at the
root of an}' die-back. Well that was simple, right?
The mystery comes up when you try to decide where
the solvent was trapped. It could be in the primer, the
primer-surfacer. the sealer, the color coats or the clear-
coats. Choose one or two or more! All your paint pro-
ducts have solvent in them, some you add more sol-
vent to. If you rushed the flash off time on any of the
products, (who. you?) there is still solvent that wants
to escape into the air. When it does, it has the same
effect on the finish as wiping the car with a solvent-
soaked rag.
Maybe the most common die-back occurs when a
complete paint job is shot late in the day because the
dust in the shop is at a minimum.
The painter is the last guy in the shop and after the
third coat, cleans his equipment, shuts off the fan and
the light and heads home. When he returns the next
morning, his great looking, super glossy paint job has
died back and dulled down.
What happened was that the bulk of the solvent rose
up out of the paint film into the air where it should
have been swept away by the air movement created
by the fan. With no fan running, (to keep the job
cleaner he thought) the solvent rose to the top of the
paint film and just lay there — thus, die-back.
The solution is to run the fan for a good 45 - 60
minutes after the last coat. At the end of the hour, shut
off the fan and open the booth doors. You're out of
dust by then, and the air moving in the open doors
will help the last of the solvent to evaporate off.
Air movement plays a big role in die-back. Take this
example: You're painting a car in a two-stall ga-
rape with little or no air movement. The tempera-
ture is 70 F All you need is the correct solvent
for 70 F and the correct .flash time between coat^
Now, the same car. the same 70 F, but you're
in a crossdraft spray booth with average air move-
ment. You need to choose a solvent as if it were
10° warmer (80 F) because of the air's drying effect.
Third time, same car. same 70 F, but in a downdraft
. booth with lots of air movement. You now need a
much slower drying solvent; in fact, almost 20°
warmer. You must reduce as if it were 90 F in the
booth. All that air whistling past causes the surface
of the paint film to skin over before all the solvent can
evaporate out. That trapped solvent will eventually
work its way out, causing extra work for you, and
-distress for your customer. Beat this problem by
choosing the correct solvent for each of your under-
coats and topcoats. Equally important, wait the
recommended flash time (or more) between coats.
Another common problem, solvent popping, is caus-
ed by exactly the same trapped solvent that causes
die-back. Only in this case, there is so much solvent
trapped under the prematurely dried "skin" that it
will Literally burst out of the paint film, leaving little
craters with a hole on top.
Solvent poppingis violent die-back. The solution is
to immediately move to a slower drying solvent.
When you must re-do something because of die-back
or solvent popping, sand the finish as soon as you can
and let it sit around the shop, sanded, for as long as
possible. When you sand, you open up the paint film.
giving the solvent a hole to escape through.
Another common problem is clearcoat de-lam-
inating (peeling) off the color coat. There are two
likely causes. How soon the customer comes back
gives you a good clue as to which one you've got.
If the customer is back within 8-10 weeks, it is most
likely a compatibib'ty problem. In other words, the
clearcoat never had an intercoat bond with the
basecoat and was just "sitting" on the base color.
There are two kinds of adhesion: mechanical and
chemical. Mechanical means that you have abraded
(sanded) the surface to increase the area of contact
with the next product (i.e., up one side of the sand-
scratch and down the other means more surface area
to meet the new coat). Chemical adhesion depends on
putting a chemically compatible product over anoth-
er in the correct time frame. You may have the cor-
rect product, but let your base color dry too long and
the clear can get no bite into it.
If it has been longer than 8 to 10 weeks before the
customer is back with peeling, chances are the clear-
coat wasn't applied thick enough.
The main enemy of your paint finish is the ultra
violet rays of the sun. It's hard to put very many UV
(continued on /Jt
82 / June 1990 / BodyShop Business
11.00
-------
(continued from p%. 82)
screeners in n clcarcont because then it. isn t clear any-
more. Some of j'our ciearcont's durability depends on
having o thick enough film to withstand the UV.
What happens many times is that the clearcoat was
applied at an acceptable mil build but was later wet
sanded and buffed to get rid of dirt.
If, for example, you had two mils of clear in two
coats, you'll take one mil off when you sand and-polish.
The one mil you have left will not stand up very long
to the sun. Now the U V rays come streaming through
the clearcoat and oxidize the base color. The sun's rays
destroy the binder in the color coat, leaving only the
chalky pigment to which the clear won't stick, and off
it comes! The solution is to put on more clear.
If you know you're going to buff, add an extra coat
for the buffer to remove. This will leave enough clear
film behind to hold out against the sun. Don't worry
abou t getting your film so thick that it will crack, to-
ri ay s urcthane enamel clears remain flexible up to a
build of 20 mils or more. There is not, however, much
to be gained in gloss by going past three to four coats.
Next time we'll look into the most common lifting
problem, discuss a clever solution for blushing and
examine some clues to where your fisheyes might be
coming from. •
BodyShop Business is'starting a question and~
answer forum for your painting questions. If you
have something that you 've always wanted to know
and can't seem to find an answer for, send us the
question. We can not answer questions about
specific brand-name products — address those to
your paint rep or jobber. Ask us the "how come"
kind of questions. Using a panel of experts, we 'II
answer in print the best questions. Thanks for your
interest!
Classified Paae
SELL YOUR USED EQUIPMENT
Spraytxwihs
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Frame & Unibody Repair Systems
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WE HAVE BUYERS!
We do equipment appraisals.
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30 N. Raymond Ave.. Suite 605,
Pasadena, CA 91103
818-796-8804
Circle 95 on Reader Service Card
DISTRIBUTORS WANTED
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Call (515) 262-4899
Circle 96 on Reader Service Card
Classified Ad Space
BodyShop Business classified
advertising is available for $195
per insertions. Six or more ads
per year are $175 per insertion.
Classifieds measure 2-1/8 x
1-1/2.
Ads can be purchased in double
units (2-1/8 x 3") for S390 per
insertion.
Advertising deadline is the first
of every month.
Contact BodyShop Business Ad-
vertising Department at
216-535-6117.
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capital.
PRODUCTION CAR CARE PRODUCTS
USA (800)331-7364 CA (209) S43-7337
NEW IDEAS?
Pull-It Corporation, manufacturers of
the internationally known Mo-Clamp
line of autobody clamps and access-
ories, would like to help you bring your
ideas to the marketplace. Several ol the
products we currently offer were devel-
oped from ideas brought to us by people
such as yourself. With our expertise in
design, manufacture, and distribution,
we can help turn your ideas into money.
We welcome the opportunity to work
with you. Call All Tessman, R&D<
Manager at (503) 644-9167, or (800)'
678-5548
6920 S.W llllh Avenue • Beaverton. Oregon 97005
1.101.
BodyShopBusiness / June 1990 / 105
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5SD DRAFT 11/7/90
DRAFT PROPOSED DETERMINATION OF
REASONABLY AVAILABLE CONTROL TECHNOLOGY
AMD
BEST AVAILABLE RETROFIT CONTROL TECHNOLOGY
FOR
i. AUTOMOTIVE REFINISHIN6 OPERATIONS
I. APPLICABILITY
The provisions of the proposed determination shall apply to all
automobile refinishing operations that Include the finishing or
refinishing of motor vehicles, mobile equipment and their parts and
components except as specified in Section IV A This determination
shall be considered RACT except where indicated as BARCT.
II. DEFINITIONS
A. Antiglare/Safety Coat 1 no means a coating which does not reflect
light.
B- Basecoat/Clearcoat System means a topcoat system composed of a
pigmented basecoat portion and a transparent clearcoat portion.
Basecoat/clearcoat systems' VOC content shall be calculated
according to the following formula:
VOCT.. . bc * 2 VI>Ccc
bc/cc - - --
V
Where:
VOC Tbc/cc 1s the sum of tne WC content as applied in the basecoat
(be) and clearcoat (cc) system.
VOCbc is the V(:)C content as applied of any given basecoat.
2VOCcc is two times the YOC content as applied of any given
clearcoat.
c- Camouflage Coating means a coating applied on motor vehicles to
conceal such vehicles from detection,
D. Catalyst means a substance whose presence initiates the reaction
between chemical compounds.
E. Color Match means the ability of a repair coating to blend into an
existing coating so that color difference is not visible.
f. Electrostatic Application means the application of charged atomized
paint droplets which are deposited by electrostatic attraction.
-.1-
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i i LI 11
6. Executive Officer means th« Emotive Officer or A1r Pollution
Control Qfflctr. or his or her dajftgate- of an air Quality
manaement district O an air olltion control district ,
H. "Extreme Performance Goat-Ing means any coating used on the surface
of a Group II vehicle, mobile equipment or their parts or
components which during intended use Is exposed to any of the
following conditions:
(1) Industrial grade detergents, cleaners or abrasive scouring
(2) Extreme environmental conditions .as determined by the APCO
during the vehicle's principal use.
I. final jtage Manufacture means where an incomplete vehicle chassis
is delivered to a manufacturer for installation and paint of a
truck body and/or components to form a completed vehicle.
J. Grams of VQC Per Liter of Coating less water and Less Exempt
Compounds means the weight of VOC per combined volume of VOC and
coating solids is calculated by thVfollowing equation:
Gvoc • («s - Ww - W«s >'
where:
G = Grams VOC per liter of coating less water and exempt
compounds
W£ = weight of volatile compounds in grdms
ww = weight of water in -grams
wes - weight of exempt compounds in grams
Vm = volume of material in liters
Vy = volume of water in liters
VfS-= volume of exempt compounds (as defined in VOC definition,
Section II GG) in liters
- Graphic Design Application meant the application of logos, letters,
numbers and graphics to a painted surface, with or without the use
of a template.
- Ground Support, means vehicles used in support of aircraft
activities at airports.
-2-
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;>;>u UKAM 11/7/90
M. Groug I_Vflh.1des nuani pauenger cars, Urgt/heavy duty truck cabs
and chassis, light and medium duty trucks and vans, and
motorcycles.
N. Group II Vehicles and Equipment; means public transit buses and
mobile equipment.
0. Hioh-Volnmft. low-Prcssurt fHVLPl Sorav means equipment used to
apply coatings by means of a gun which operates between 0.1 and 10
psig air pressure and which operates at a maximum fluid delivery
pressure of 50 psig.
P- large/Heavy Duty Trucks means any truck having a manufacturer's
gross vehicle weight rating of over 10,000 pounds.
Q. LJoht and Medium Duty Trucks and Va/is means any truck or van having
a manufacturer's gross vehicle weight rating of 10,000 pounds or
less.
R. Metallic/Iridescent Topcoat means any coating which contains more
than 5 g/1 (.042 Ib/gal) of metal or iridescent particles, as
applied, .where such particles are visible in the dried film.
S. Mobile Equipment means any equipment which may be drawn or is
capable of being driven on a roadway, including, but not limited
to, truck bodies, truck trailers, utility bodies, camper shells,
mobile cranes, bulldozers, street cleaners, golf carts and
implements of husbandry.
T. Precoat means any coating which is applied to bare metal primarily
to deactivate the metal surface for corrosion resistance to a
subsequent water-base primer.
U. Pretreatment Wash Primer means any coating which contains a minimum
of 0.5 percent acid by weight, is necessary to provide surface
etching and is applied directly to bare metal surfaces to provide
corrosion resistance and adhesion.
V. Primer means any coating applied prior to the application of a
topcoat for the purpose of corrosion resistance and adhesion of the
topcoat.
W. Primer Sealer means any coating applied prior to the application of
a topcoat for the purpose of corrosion resistance, adhesion of the
topcoat, color uniformity, and to promote the ability of an
undercoat to resist penetration by the topcoat.
X. Primer Surfacer means any coating applied prior to the application
of a topcoat for the purpose of corrosion resistance, adhesion ot
the topcoat, and which promotes a uniform surface by filling in
surface imperfections.
-3-
1104
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UKAH 11/7/90
Y. RtiULti moans tht solvent usid to thin en Aim 1.
2. Refim'shfng means any coating of vehicles, their parts and
componentSj or mobile tqulpment, Including partial body collision
repairs, for the purpose of protection or beautlHcation and which
.. is. subsequent to UL^ original coating applied at an Original
Tqulpment Manufacturing (OEM) plant coating assembly line.
AA- Specialty Coatlngl means coatings which are necessary due to
unusual job performance requirements. Said coatings Include, but
are not limited to, adhesion promoters, uniform finish blenders,
elastomerk materials, gloss flatteners, bright metal trim repair,
and anti-glare/safety coatings.
BB. Spot/Panel Repair means the non-assembly line process of repairing
and restoring a portion of a motor vehicle to predamaged condition.
CC. Three-Stage Coating System means a topcoat system composed of a
pigmented basecoat portion, a semi-transparent midcoat portion, and
a transparent clearcoat portion. Three-stage coating systems' VOC
content shall be calculated according to the following formula:
VOCbc * YOCmc + 2 VOCcc
YOCT3-stage ' - - - : - : -
Where:
VOC T, f is the sum of the VOC content as applied In the
J-stage basecoat, midcoat and clearcoat system.
VOtL, is the VOC content as applied of any given midcoat.
me
Z VOC is two times the VOC content as applied of any given
c clearcoat.
DO. Topcoat means any coating applied over a primer of an original OEM
finish for the purpose of protection or appearance. For the
purposes of this rule, base coat/clear coat systems and three-stage
coating systems shall be considered jointly as a topcoat.
EE. Touch-uo Coatino means a coating applied by brush or hand held,
non-refi liable aerosol cans to repair minor surface damage and
imperfections.
FF. Transfer Efficiency means the ratio of the 'amount of coating solids
adhering to the object being coated to the total amount of coating
solids used in the application process, expressed as a percentage.
GG. Volatile Organic Compounds mean any compound containing at least
one atom of carbon, except methane, carbon monoxide, carbon
dioxide, carbonic acid, metallic carbides or carbonates, ammonium
-4-
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ssi) UKAH n///yu
carbonate, 1. 1.1-trichloroethane, methylcne chloride,
( CFr~i n . (HchlorodlfluoroiTtcthana
chlorodifluoromEthang (CFC-221. trlf luoromethane (CFC-23),
trichloroUifluoroethane(CFC-113),d1chlorotetrafluoroethane (CFC-
114), chloropenUfluororethane (CFC-115), dichlorotrlf luoroethanft
dlchlorof luorosthane
(HCFC-141b).and chlorodlf luorortthanc (HCFC-H2M.
III. STANDARDS
A. Limits. Effective six months from the date of adoption except
where dates are specified, any person.who appllts coatings to Group
I or II vehicles, mobile equipment, their parts and components,
shall comply with Sections III A (1) or A (2) below:
(1) Group I Vehicles. A person shall not refinlsh Group I
vehicles, their parts and components, or Group II vehicles and
mobile equipment where color match is required, using any
coating with a VOC content in excess of the following limits,
expressed as grams of VOC per liter (or pounds per gallon) of
coating applied, excluding water and exempt compounds (as
defined in VOC definition. Section II SS), unless emissions to
the atmosphere are controlled to an equivalent level by air
pollution abatement equipment with an abatement device
efficiency of at least 85 percent and which has been approved
in writing by the Executive Officer.
RACT
VQC
Januar 1. 1992
•BAftCT-
January 1. 1995
V_QC
Pretreatment Wash 780 g/1 (6.5 Ibs/gal) 780 g/1 (6.5 IbS/gal) 420 g/1 (3,5 Ibs/gal
Primer
Precoat
Primer/primer
Surface
Primer Sealer
Topcoat
Metallic/Iridescent
Topcoat
780 g/1
720 g/1
720 g/1
720 g/1
720 g/1
(6.5 IbS/gal)
(6.0 Ibs/gal)
(6.0 Ibs/gal)
(6.0 IbS/gal)
(6.0 Ibs/gal)
780 g/1 (6.5 IbS/gal)
340 g/1 (2.8 Ibs/gal)
420 g/1 (3.5 Ibs/gal)
600 g/1 (5.0 Ibs/gal)
600 g/1 (5.0 Ibs/gal)
420 g/1 (3.5 Ibs/gal
250 g/1 (2.1 Ibs/gal
340 g/1 (2.8 Ibs/gal
460 g/1 (3.8 Ibs/gal
540 g/1 (4.5 Ibs/gal
(2) Group II Vehicles and Mobile Equipment. A person shall not
finish or refinish Group II vehicles and equipment or their
parts and components where color match is not required, using
any coating with a VOC content 1n excess of the following
limits, expressed as grams of VOC per liter (or pounds per
gallon) of coating applied, excluding water and exempt
compounds (as defined in VOC definition, Section II GG).
-S-
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unless emljslonj to the at~osph«re are controlled to an
equivalent level by «1r pollution abatement equipment with tn
abatement device efficiency of at least 85 percent and vhlch
has byen approved 1n writing by the Executive Officer.
RACT
VOC
-BARCT-
Januar
199?
January 1. 1995
VQC
Pretreatment Wash
Primer
Precoat
Primer
Topcoat
Metallic/Iridescent
Topcoat
Extreme performance
Camouflage
780 g/1 ($.5 Ibs/gal) 780 g/1 (6.5 Ibs/gal) 420 g/1 (3.5 Ibs/gal
780 g/1
340 g/1
420 g/1
650 g/1
750 g/1
420 g/1
(6.5 Ibs/gal)
(2.8 Ibs/gal)
(3.5 Ibs/gal)
(5.4 Ibs/ga1)
(6.2 Ibs/gal)
(3.6 Ibs/gal)
780 g/1 (6.5 Ibs/gal)
340 g/1 (2.8 Ibs/gal)
420 g/1 (3.5 Ibs/gal)
420 g/1 (3.5 Ibs/gal)
750 g/1 (6.2 Ibs/gal)
420 g/1 (3.5.Ibs/gal)
420 g/1
250 g/1
340 g/1
420 g/1
3.5 Ibs/gal
2.1 Ibs/gal
2.8 Ibs/gal
3.5 Ibs/gal
420 g/1 (3.5 Ibs/gal
420 g/1 (3.5 Ibs/gal
B. Lacouer Spot/Panel Repair Limits. Effective six months from the
date of adoption, a person shall not spot/panel repair Group I
vehicles with existing nitrocellulose or synthetic lacquer finishes
using lacquer coatings in excess of the following limits, expressed
as grams of VOC per liter (or pounds per gallon) of coating
applied, excluding water and exempt compounds (as defined in VOC
definition, Section II GG), unless emissions to the atmosphere are
controlled to an equivalent level by air pollution abatement
equipment with an abatement device efficiency at least 85 percent
and which has been approved in writing by the Executive Officer:
Pretreatment Wash Primer
Precoat
Primer/Primer Surfacer
Primer Sealer
Topcoat
VOC
780 g/1 (6.5
780 g/1 (6.5
Ibs/gal)
Ibs/gal)
720 g/1 (6.0 Ibs/gal)
780 g/1 (6,5 Ibs/gal)
780 g/1 (6.5 Ibs/gal)
Effective twelve months from the date of adoption, a person shall not
spot/panel repair Group I vehicles with existing lacquer finishes using
any coating with a VOC content in excess of the standards set forth in
Section III A (1).
C. Transfer Efficiency. Effective twelve months from the date of
adoption for all coatings, a person shall not apply any coating to
any Group I or II vehicles or mobile equipment or their parts and
components unless one of the following methods is used:
-6-
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SSO DRAFT 11/7/90
(1) Electrostatic application equipment, operated 1n accordance
with the manufacturer's recommendations;
(2) High Volume Low Pressure (HVLP) spray equipment, operated 1n
accordance with the manufacturer's recommendations;
(3) Any other coating application which has been demonstrated to
the satisfaction of the Executive Officer and for which
written approval of the Executive Officer has been obtained.
D. Prohibition of Soedf ication. Ho person shall solicit or require
for use or specify the application of a coating on a Group I or II
vehicle, mobile equipment, or part or component thereof if such use
or application results in a violation of the provisions of this
determination. The prohibition of this Section will apply to all
written or oral contracts under the terms of which any coating
which is subject to the provisions of this determination is to be
applied to any motor vehicle, mobile equipment, or part or
component at any physical location within the District.
E. Prohibition of Sale. A person shall, not offer for sale or sell
within the District any coating if such product is prohibited by
any of the provisions of this determination. The prohibition of
this section shall apply to the sale of any coating which will be
applied at any physical location within the jurisdiction of th.<^
.local air Pollution control agencies. _ This requirement shall not
apply to the application of coatings where emissions to thg
.atmosphere are controlled to an equivalent level of this
determination bv air pollution abatement equipment that has
approved in writing bv the Executivg
Compliance Statement Requirement. The manufacturer of coatings
subject to this determination shall include. a designation of VOC
{as defined in Sections II G6) as supplied, including coating
components, expressed In grams per liter or pounds per gallon,
excluding water and exempt compounds, on data sheets.
Surface Preparatlon-'and Clean-up Solvept. The requirements of this
section shall apply to any person using solvent for surface
preparation and cleanup.
(1) A person shall not use an organic compound for surface
preparation with a VOC content in excess of 200 grams per
liter (1.67 pounds per gallon).
(2) A person shall use closed, nonabsorbent containers for the
storage or disposal of cloth or paper used for solvent surface
preparation and cleanup.
(3) A person shall store fresh or spent solvent in closed
containers.
(4) A person shall not use organic compounds for the cleanup of
spray equipment including paint lines unless an enclosed
system is used for cleanup. The system must enclose spray
-7-
1
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guns, cups, nozzles, bowli and other parts during vathlng,
rinsing and draining procedures. Equipment used shall
mlnlmiie the evaporation of organic compounds to the
atmosphere.
H. SfflaJ 1 product 1on7Ut 11 Hy Bodies. The standards set forth In
Section |II A (1) Shall apply provided production of utility bodies
where the coating Is required to match that of the vihiclts upon
which they will be mounted It less than or tqual to 20 vehicles per
day. T(\estandards set forth jn Section III A (2) shall apply
provided production of utility bodies Is greater than 20 vehicles
par day.
I. Specialty Coating* means a person shall not use any specialty
coating with a VOC content in excess of 840 g/1 (7.0 Ibs/gal),
excluding vater and exempt compounds. Use of all specialty
coatings except antiglare/safety coatings shall not exceed 5.0
percent of all coatings applied, on a daily basis. The application
of topcoats with a specialty coating used as an additive shall be
subject to the topcoat limits 1n Sections III A (1) or A (2).
J:'Extreme Performance Coating Requirements means any person seeking
to use an extreme performance coating in any coatirvg operation
which is subject to this rule shall comply with the requirements of
Section VI A.
IV. EXEMPTIONS
A. Original Eoujpment Manufacturer. The provisions of this Rule shall
not apply to Original Equipment Manufacturer (OEM) coatings applied
at manufacturing or assembly plants subject to a Motor Vehicle
Assembly Plan Rule.
V. TEST METHODS
A. Analysis of Samples. Samples of volatile organic compounds as
specified in Sections III A (1) or III A (2) shall be analyzed as
prescribed by EPA Reference Method 24 or method determined to be
equivalent and approved by the Executive Officer.
B. Determination of Emissions. Emissions of volatile organic
compounds as specified in Section III A (1) or III A (2) shall be
measured as prescribed by EPA Reference-Method 25 or method
determined to be equivalent or more stringent and approved by the
Executive Officer.
C. nomination of Transfer Efficiency- Transfer «"jciency as
required by Section III C (3) shall be determined by a method
approved by the Executive Officer.
-8-
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D- Determination of Capture Efficltncy. Capture efficiency »s
r»guir>Qy_Sect ion III A and R shall bn determined bv the method
itattd in suboart SSS (Magnetic Tape Coating Facilities! 40 Cfp r
Part 60. Section 60.713.
E. Determination of Iridasceryt particles in Hetanic/Iridtsctnt
, -Topcoat. IMdtscent particles 1n metallic/Iridescent topcoat as
defined In Section II R shall be determined bv the South Coast A,1r
Ouallty Management District (SCAQMO) Spectrograohic method
contained in Section 3. Method ?6 of the SCAQHD "Laboratory M»fh,ffd
of Analysis for Enforcement Samples* manual.
F. Determination of Acid Concentration 1n Prstreatment Wash Primer.
Acfd, concentration in pratreatment wash primer as defined 1n
Section II U shall be determined bv test method ASTM D-1613-85
/modified).
VI. ADMINISTRATIVE REQUIREMENTS
A. Extreme Performance Coating Petition. Any person seeking to use an
extreme performance coating 1n any coating operation which is
subject to the provisions of this rule shall comply with the
following requirements:
(1) A petition shall be submitted to the Executive Officer stating
the performance requirements, volume of coating and VOC level
which is attainable.
(2) If the Executive Officer grants written approval, such
petition will be repeated on an annual basis.
(3) If the Executive Officer grants written approval, such
approval shall contain volume and YOC limit conditions.
(4) Records must be maintained as in Section VI (B).
B- Coating Records. Any person subject to Sections III A (1) and III
A (2) shall comply with the following requirements:
(1) The person shall maintain and have available during an
inspection, a current list of coatings in use which provides
all of the coating data necessary to evaluate compliance,
including the following information, as applicable:
(a) coating, catalyst and reducer used
(b) mix ratio of components used
(c) VOC content of coating as applied.
(2) The person shall maintain records on a daily basis Including
the following information:
(a) coating and mix ratio of components in the coating used
(b) quantity of each coating applied.
-9-
n
. * V
-------
(3) The pfcMc.fi jotll maintain records on o monthly b«»U ihoving
ths typ« «n3 imouht of jotWr.t us«d for cleanup ihd «urf»c«
(4) Such record* shall be rttained and avallablt for Inspection by
the ExecutlVt Officer for tht pr»v'1ous 24 month pirlbd.
-10-
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PaintShop
Common Complaints,
Specific Solutions
by Mark Clark
n these days of fast-paced
produce'deliver auto repaint-
ing, it's hardj-o get a simple
explanatioh'for the cause of common
painters' problems. In this series of ar-
ticles, we are going look at some of the
most common complaints and try to
explain in simple terms (no degree in
chemisty required) what went wrong
and why. These discussions are as ge-
neric as possible, and no one brand of
paint is being promoted over another.
And that leads us to the absolute
quickest way to reduce all your paint
problems, no matter what brand you're
using or what part of the country you're in.
You can reduce your painting related problems by —
ready? — 50 percent. Sound like something you'd be
interested in? Instead of 10 problems a week or 10
problems a month, you can skip right down to only 5
problems.
How? It's easy, it's simple, and it's guaranteed to
work. Use one brand all the way through, follow a sys-
tem! When all the undercoats, solvents, topcoats and
clears are guaranteed compatible, you'll have 50 per-
cent fewer problems. Problems like adhesion, durabili-
ty and re-coatability drop to the very minimum.
The notion that any shop painter can don the chem-
ical engineer's hat and start mixing products and
systems goes back to the days when this business was
much simpler.
Back in the days when most undercoats were a lac-
quer base and most topcoats were either lacquer or a
simple acrylic enamel, shop painters figured out that
they could substitute a cheaper solvent from some oth-
er manufacturer and then color with yet a third brand
and seldom have problems.
Like the paint reps say, one of the
hardest guys to deal with is the paint-
.er who combined several brands and
didn't have a problem, once or twice or
even ten times. Then, when his ''sys-
tem" doesn't work, he can't accept the
fact that he was just lucky each of
those other times.
The reason that intermixing is such
a tremendous risk these days can be
traced back to the vehicle manufactur-
er. The consumer keeps demanding a
better looking, more durable, more
corrosion-resistant finish. The manu-
facturers have been able to deliver
OEM finishes hundreds of times better than just a few-
years ago. Now here comes that super high-tech finish
into the body shop to be repaired "as good as new."
The af termarket paint companies have really had to
scramble to create air dry (no heat or electricity like
OEM) finishes durable enough to match original
equipment. This, as you might imagine, was quite a
trick.
What this means to body shop painters is that there
is no margin for error in applying or mixing today's
products. The paint company chemist was able to
create a product to suit, but only if you do exactly as
he says. Not only must the painter combine the correct
solvent, catalyst and topcoat in the correct percent-
ages, but it must be applied over the correctly mixed
and appb'ed undercoats at the correct time.
There is only one right way to use today's finishes;
exactly according to directions and using only one
brand. Besides reducing your paint problems 50 per-
cent, several other benefits also occur. You will have
fewer products (read that — dollars) in your inventory,
(continued on pg. 82)
80 / June 1990 / BodyShop Business
-------
(continue*: jnim pg. SOI
and since ihe same system is used all the time, every-
one gets {.rood at it and more work is produced in less
time. Knowing what one line will do under a variety
of conditions is better than guessing what a vari-
ety of products will do under the same condition.
Now. having solved one half of your paint problems.
let's take a look at some of the other ones that are left.
It's simple to solve
half your paint problems.
One of the most common and frustrating paint prob-
lems is die-back. Die-back means that over time the
paint job loses the gloss it once had. Only one thing
causes die-back: trapped solvent. It is always at the
root of any die-back. Well that was simple, right?
The mystery comes up when you try to decide where
the solvent was trapped. It could be in the primer, the
primer-surfacer. the sealer, the color coats or the clear-
coats. Choose one or two or more! All your paint pro-
ducts have solvent in them, some you add more sol-
vent to. If you rushed the flash off time on any of the
products, (who. you?) there is still solvent that wants
to escape into the air. When it does, it has the same
effect on the finish as wiping the car with a solvent-
soaked rag.
Maybe the most common die^back occurs when a
complete paint job is shot late in the day because the
dust in the shop is at a minimum.
The painter is the last guy in the shop and after the
third coat, cleans his equipment, shuts off the fan and
the light and heads home. When he returns the next
morning, his great looking, super glossy paint job has
died back and dulled down.
What happened was that the bulk of the solvent rose
up out of the paint film into the air where it should
have been swept away by the air movement created
by the fan. With no fan running, -(to keep the job
cleaner he thought) the solvent rose to the top of the
paint film and just lay there — thus, die-back.
The solution is to run the fan for a good 45 - 60
minutes after the last coat. At the end of the hour, shut
off the fan and open the booth doors. You're out of
dust by then, and the air moving in the open doors
will help the last of the solvent to evaporate off.
Air movement pla vs a big role in die-back. Take this
example: You're painting a car in a two-stall ga-
rage with little or no air movement. The tempera-
ture is 70 F All you need is the correct solvent
for 70 F and the correct .flash time between coats.
Now. the same car. the same 70 F, but you're
in a crossdraft spray booth with average air move-
ment. You need to choose a solvent as if it were
10° warmer (80 F) because of the air's drying effect.
Third time, same car. same 70 F, but in a downdraf t
-booth with lots of air movement. You now need a
much slower drying solvent; in fact, almost 20°
warmer. You must reduce as if it were 90 F in the
booth. All that air whistling past causes the surface
of the paint film to skin over before all the solvent can
evaporate out. That trapped solvent will eventually
work its way out, causing extra work for you, and
-distress for your customer. Beat this problem by
choosing the correct solvent for each of your under-
coats and topcoats. Equally important, wait the
recommended flash time (or more) between coats.
Another common problem, solvent popping, is caus-
ed by exactly the same trapped solvent that causes
die-back. Only in this case, there is so much solvent
trapped under the prematurely dried "skin" that it
will literally burst out of the paint film, leaving k'ttle
craters with a hole on top.
Solvent popping is violent die-back. The solution is
to immediately move to a slower drying solvent.
When you must re-do something because of die-back
or solvent popping, sand the finish as soon as you can
and let it sit around the shop, sanded, for as long as
possible. When you sand, you open up the paint film,
giving the solvent a hole to escape through.
Another common problem is clearcoat de-lam-
inating (peeling) off the color coat. There are two
likely causes. How soon the customer comes back
gives you a good clue as to which one you've got.
If the customer is back within 8 -10 weeks, it is most
likely a compatibility problem. In other words, the
clearcoat never had an intercoat bond with the
basecoat and was just ''sitting" on the base color.
There are two kinds of adhesion: mechanical and
chemical. Mechanical means that you have abraded
(sanded) the surface to increase the area of contact
with the next product (i.e., up one side of the sand-
scratch and down the other means more surface area
to meet the new coat). Chemical adhesion depends on
putting a chemically compatible product over anoth-
er in the correct time frame. You may have the cor-
rect product, but let your base color dry too long and
the clear can get no bite into it.
If it has been longer than 8 to 10 weeks before the
customer is back with peeling, chances are the clear-
coat wasn't applied thick enough.
The main enemy of your paint finish is the ultra
violet rays of the sun. It's hard to put very many UV
(continued on ptf. 10-r>)
82 / June 1990 / BodyShop Business
-------
(continued from pg. 821
scrocncrs in n clcarcoat because (.hen it. isn t clear any-
more. Some of your clearcont's durability depends on
having a thick enough film to withstand the UV.
What happens many times is that the clearcoat was
applied at an acceptable mil build but was later wet
sanded and buffed to get rid of dirt.
If, for example, you had two mils of clear in two
coats, you'll take one mi] off when you sand and polish. -
The one mil you have left will not stand up very long
to the sun. Now the U V rays come streaming through
the clearcoat and oxidize the base color. The sun's rays
destroy the binder in the color coat, leaving only the
chalky pigment to which the clear won't stick, and off
it comes! The solution is to put on more clear.
If you know you're going to buff, add an extra coat
for the buffer to remove. This will leave enough clear
film behind to hold out against the sun. Don't worry
about getting your film so thick that it will crack, to-
day's urethane enamel clears remain flexible up to a
build of 20 mils or more. There is not, however, much
to be gained in gloss by going past three to four coais.
Next time we'll look into the most common lifting
problem, discuss a clever solution for blushing and
examine some clues to where your fisheyes might be
coming from. •
BodyShop Business is starting a question'and
answer forum for your painting questions. If you
have something that you 've always wanted to know
and can't seem to find an answer for, send us the
question. We can not answer questions about
specific brand-name products — address those to
your paint rep or jobber. Ask us the "how come"
kind of questions. Using a panel of experts, we'll
answer in print the best questions. Thanks for your
interest.1
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BodyShop Business / June 1990 / 105
-------
A. EPA PRESENTATION
Mr. Randy McDonald of the Chemicals and Petroleum Branch in
the Emission Standards Division presented the status of the Batch
Processes Control Techniques Guidelines (CTG). The presentation
was followed by two additional related presentations: one from
Mr. Rick Hamilton, of On-Demand Environmental Systems, and one
from Ms. Terri Ranganath, of E. I. du Pont de Nemours & Co.,
Inc., representing the Chemical Manufacturers Association (CMA).
These presentations are summarized below. Handouts and slides
are attached. Also included is a summary of the discussion that
took place between the NAPCTAC committee members and the Batch
project team after the three presentations were completed.
1. Status of Batch Processes CTG
The objectives of the presentation were to present the
approach taken to develop reasonably available control technology
(RACT) options for controlling volatile organic compounds (VOC)
emissions from batch processes; to present the options and the
impacts of applying the options to batch processing VOC emissions
on a nationwide basis; and to highlight implementation issues
that still need to be addressed. The discussion started out with
a characterization of batch processes—namely, that they are
non steady-state processes. As an example, the emission events
from a batch reactor—such as vessel charging, reactor heatup,
occasional purging of the reactor vapor space, and product
discharge—were described and the characteristics of the
resulting emission stream were said to be continuously changing.
Mr. McDonald pointed out that the scope of the CTG is limited to
five industries, and the CTG contains RACT options for
controlling process vents and equipment leaks. Wastewater and
storage emissions are addressed in separate CTG's. Equipment
leak requirements were adopted from the requirements set forth
for emissions from batch processes in the equipment leaks
negotiated regulation. Mr. McDonald explained that process vents
were, therefore, the focus for the majority of work done to
develop this CTG. The focus of the presentation then turned
towards explaining the approach taken to develop the options. It
is summarized below.
Four model processes were developed from industry data.
They included typical batch unit operations and associated
equipment such as reactors, crystallizers, centrifuges, dryers,
and distillation units. In calculating emissions and estimating
the emission stream characteristics of flowrate, duration, and
-------
VOC concentration, the assumption was made that primary
condensers servicing this equipment were operated at 20"C. Also,
all pieces of equipment were assumed to be vented.
Next, Mr. McDonald discussed the time-dependent variation
that can occur in flowrate and VOC concentration, and
subsequently in the resulting emissions. This concept was
presented using slides that plotted concentration, flowrate, and
emission rate on the y axis and duration of the batch cycle on
the x axis. Control device selection must account for such
variation and control VOC emissions that are most reasonable to
control. Two types of control devices were used to examine the
limits of reasonable control for VOC emissions from batch
processes. They are thermal incineration and refrigeration.
These devices were used exclusively because they can handle a
universe of compounds. Refrigeration was used for rich VOC
streams (>10,000 parts per million by volume [ppmv]), and thermal
incineration for streams with lower VOC concentrations. Costing
of the devices was done in accordance with the OAQPS Control Cost
Manual. An illustration of the dependency of control device cost
effectiveness with the amount of onstream emission duration was
shown by plotting cost effectiveness versus flow rate for a
number of 10,000 ppmv streams having varying onstream
percentages. This discussion led to the heart of the approach
for developing RACT options, which is outlined below.
A "mass flux" curve was shown and discussed in detail by
Mr. McDonald. The mass flux curve is a plot of control device
cost effectiveness (dollars per Megagram [$/Mg]) versus maximum
instantaneous flowrate (standard cubic feet per minute [scfm])
for a set annual emission rate (termed "mass flux") for a range
of concentrations varying from 100 ppmv to 100,000 ppmv- The
curves form an envelope that describes the range of cost
effectiveness values that are possible using the two control
devices specified above for any flowrate. The left-hand
endpoints of the mass flux curve represent continuous emission
streams. They are the lowest maximum instantaneous flowrates
that a vent stream can have for a set concentration to emit the
specified mass flux, which, for the first curve, was
20,000 Ib/yr. As the curves move from left to right, the
duration of the emission streams becomes shorter and shorter so
that the right hand endpoints of the curve approximate very short
"bursts" containing high flowrates.
A control device sized to handle emissions streams described
by the right-hand endpoints would be less cost effective (i.e.,
more expensive) than one sized to handle a stream described by
left-hand endpoints because the device would be large enough to
handle the burst but would not operate as long for the same mass
flux value (i.e., the Mg in $/Mg would remain the same, but the $
would be higher). By drawing a horizontal line at a desired cost
effectiveness, intersecting the envelope formed by the mass flux
curves, and drawing a vertical tie-line down, the limit of
1116
-------
maximum instantaneous flowrate for a given cost effectiveness can
be set. The RACT options were developed based on this analysis
and take the form of a regression line linking mass flux (or
annual emission rate) and maximum instantaneous flowrate at
certain cost effectiveness values. A process vent would
therefore require control to a desired level (the current options
are 90, 95, and 98 percent reduction) if the maximum flowrate
were less than the value obtained from the equation of the
regression line for a specified annual emission rate. This is
the approach that was taken to evaluate the limits of RACT for
process vents.
For equipment leaks, Mr. McDonald reiterated that the RACT
option followed the requirements contained in the section
specific to batch processing contained in the equipment leaks
negotiated regulation.
Mr. McDonald then presented the RACT options and their
associated nationwide impacts. To estimate these impacts, model
plants were developed from the model processes presented earlier.
The number of facilities represented by these model plants
located in nonattainment areas having batch VOC emissions from
the industries in the scope of the CTG were estimated using data
from the Census of Manufacturers. Selected RACT options were
shown on a table with their estimated national emissions
reduction and costs.
Finally, Mr. McDonald presented a slide of some of the
implementation issues that have arisen since the approach was
developed. The first of these issues is how to obtain the annual
emission rate for a process vent or group of process vents.
Current thinking is that source testing is not technically and
economically feasible. The Batch CTG document contains
methodologies for estimating VOC emissions from batch processing
steps. These methodologies could be used to develop the annual
emissions estimate. Maximum instantaneous flowrate is presumably
an easier parameter to obtain for various reasons.
The second implementation issue discussed is how to verify
the annual emission rate. Because of the format of the RACT
options, facilities will be required to anticipate the annual
emission rate from a process vent or group of process vents to
determine whether the vent must be controlled. For industries
that have continuously changing production schemes, this task
could become very complicated. The agency responsible for
enforcing RACT might require an end-of-the-year audit to ensure
that process vents or groups of process vents were controlled as
required. Finally, testing or monitoring of control device
operating parameters might be required to ensure that the
required control efficiencies (i.e., 90, 95, and 98 percent) were
being achieved.
1117
-------
CONTROL TECHNIQUES GUIDELINES
DOCUMENT
(CTG)
for
VOC EMISSIONS
from
BATCH PROCESSES
NAPCTAC Meeting
November 21,1991
-------
Batch Processes are discontinuous processes
in which mass, temperature, concentration
and other properties of a system vary with time,
Batch Processes are typically characterized
as "non-steady state"
-------
INDUSTRIES COVERED
Polymers and resins
Pharmaceuticals
Paints and allied products
Synthetic organic chemicals (SOCMI)
Agricultural chemicals
-------
APPLICABILITY OF BATCH CTG
to
- Process vents
- Equipment leaks
- Storage tanks
- Wastewater
Covered by this CTG
Covered by other
CTGs
-------
PROCESS VENTS
to
to
-------
ro
CO
MODEL PROCESSES
OBJECTIVE: To characterize the majority of batch processes
SOLUTION: 4 model processes
1. Solvent reaction with atmospheric dryer
2. Solvent reaction with vacuum dryer
3. Liquid reaction
4. Formulation
-------
SOLVENT
SOLVENT
RECOVERY
Mode! batch process for solvent reaction w/ atmospheric dryer
1124
-------
CRYSTALLIZER
SLURRY
TANK
CENTRIFUGE
Lr
DIST.
UNIT
SOLVENT
CENTRIFUGE
SOLVENT
RECOVERY
VACUUM
DRYER
Model batch process for solvent reaction w/ vacuum dryer
1125
-------
WEIGH
TANK
WEIGH
TANK
MIX
TANK
1 f
REACTOR
•SOLVENT
SURGE
TANK
DIST.
UNIT
SOLVENT
RECOVERY
Model batch process for liquid reaction
1126
-------
WEIGH
TANK
WEIGH
TANK
MIX
TANK
REACTOR
SURGE
TANK
SOLVENT
FILTER
Model batch process for formulation
1127
-------
CONCENTRATION, FLOWRATE, and DURATION
determine
ro
oo
EMISSIONS
-------
CONCENTRATION PROFILE OF A BATCH PROCESS
90
81
72
O
tr 63
Ld
54
45
O
>
O
O
>
27
18
9
0
Ohr
N
Reactor
Distillation
r
Vacuum
dryer
Solvent
Recovery
2.2 hr
TIME (24 HOURS)
22.2 hr
24 hr
-------
FLOWRATE PROFILE OF A BATCH PROCESS
o
CO
154 r
132
E 110
88
< 66
5
Q 44
22
0
Reactor
Ohr
X
Vacuum dryer
2.2hr
N
TIME (24 HOURS)
Distillation
22.2hr
24 hr
-------
EMISSION PROFILE OF A BATCH PROCESS
16 r
CO
< 8
cr
g
00
in
^
LU
0
Reactor
/
Ohr
Distillation
Vacuum dryer
Solvent
recovery
2.2hr
22.2hr 24 hr
TIME (24 hours)
-------
FLOWRATE PROFILE OF A BATCH PROCESS
154
132
^ 88
1 1 1
1 66
g 44
b-
22
0
Reoctor
//
:nnn
Ortr
«? X
e<. >,. ^ Distillation £
/>v r /
O 'j ^ Vacuum dryer *v
mOr- 1 — 1
K ii n.
2.2 hr N| 22.2 hr 24 hr
TIME (24 HOURS)
CONCENTRATION PROFILE OF A BATCH PROCESS
90
h- B1
^ 72
^ 63
UJ
Q- 54
LU
S 45
15
=* 36
O
27
18
9
0
Reactor
Distillation
Solvent
Recovery
2.2 hr N|
TIME (24 HOURS)
EMISSION PROFILE OF A BATCH PROCESS
16 r
.c
\
-Q
UJ
5 8
a:
O
CO
Reactor
n
nnrT
OiitiUation
t*
Vacuum dryer
K
•
Solvent
recovery
2.2 hr \
TIME (24 hours)
22.2 hr 24hr
1132
-------
CO
CO
CONTROL TECHNOLOGY
- Thermal incineration
(< 10,000 ppmv)
- Condensation/refrigeration
(>=10,000 ppmv)
Other devices were examined (i.e. scrubbers and
carbon adsorption),but these two are UNIVERSAL
-------
CO
PACT OPTIONS STRUCTURED TO
CONSIDER VARIATIONS IN:
- Concentration
- Flowrate
- Duration
-------
Cost to Control by Thermal Incineration
For VOC Concentration of 1 0,000 ppmv
CO
50000
45000
40000
35000
30000
25000
P 20000
15000
10000
5000
0
O
20% 1 0%
7,
10 100 1000 10000 100000
Maximum Instantaneous Flowrate (scfm)
-------
CO
cn
FORMAT OF OPTIONS
- Linear equations which specify flowrate
"cutoffs" when annual emission rate is input
- Emission streams must be controlled to a
certain level (i.e. 98%, 95%, 90%) if the
maximum flowrate of the emission stream
is less than the specified cutoff
-------
APPROACH FOR DEVELOPING RACT OPTIONS
- Absorb duration into "mass flux" parameter, which
is the yearly VOC emission rate
£ - Construct "mass flux" curves on axes of cost
S effectiveness and flowrate for range of concentration
-------
CO
CO
D)
CO
CO
LLJ
LU
O
LU
LL
LLJ
8
MASS FLUX = 20000 Ibs/yr
LOW VOLATILITY Obluene)
CONDENSER CONTROL EFFICIENCY - 90%
Short duration events
100% duration, 8760 hours
Condenser 100,000 ppmv
100
FLOWRATE(scfm)
1000
10000
-------
35
C/)
0)
LU
30-
25-
LU "p 20
> §
P R
O .8 15J
10-
5-
LL
LLJ
So
8
0
MASS FLUX = 35000 Ibs/yr
LOW VOLATILITY fToluene^
CONDENSER CONTROL EFFICIENCY - 90%
10 100 1000
FLOWRATE(scfm)
10000
THROX 10OOppmv THROX 8750ppmv
CONDENSER 10000ppmv CONDENSERIOOOOOppmv
-------
35
CO
CO
LJU
30-
25-
UJ -p 20-
•^ i
OUL
LJL
LU 10
5-
o
o
0-
MASS FLUX = 50000 Ibs/yr
LOW VOLATILITY fToluene)
CONDENSER CONTROL EFFICIENCY - 90%
(50,000,4000)
i i i i i i 111
10 100 1000
FLOWRATE(scfm)
10000
THROX 10OOppmv THROX 8750ppmv
CONDENSER lOOOOppmv CXDNDENSERIOOOOOppmv
-------
MASS FLUX = 75000 Ibs/yr
LOW VOLATILITY (Toluene)
CONDENSER CONTROL EFFICIENCY » 90%
100 1000
FLOWRATE(scfm)
10000
THROX 10OOppmv THROX 8750ppmv
CONDENSER 10000ppmv CONDENSER 100000ppmv
-------
to
DATA POINTS
Mass Flux (Ib/yr) Flowrate (scfm) Cost-effectiveness ($/Mg)
20,000
35,000
50,000
75,000
500
2500
4000
7000
10,000
10,000
10,000
10,000
Flowrate = 0.1167(Mass Flux) -1750
-------
,
CO
EQUIPMENT LEAKS
- Adopted equipment leaks negotiated regulation as described
in the Hazardous Organic NESHAP (HON)
Portions specific to Batch Processing consider
M - Exemption from control of sources in service
less than 300 hr/yr
• Control via pressure testing or leak detection and repair (LDAR)
-------
NATIONWIDE IMPACTS
Extrapolated from model processes to model plants to nationwide
totals
Uses census of manufacturers data to estimate facilities located
in non-attainment areas for small, medium, and large groupings
Small plant 1-19 employees,
3 model processes
Medium plant 20-99 employees,
10 model processes
Large plant >=1 oo employees,
30 model processes
-------
BATCH PROCESSES CTG RACT OPTIONS
OPTION
1
DESCRIPTION
OF OPTION
Controlling equipment leaks
NATIONWIDE
EMISSION
REDUCTION
(Mg/yr)
6,900
NATIONAL
COST
($)
$13,000,000
AVERAGE
COST
EFFECTIVENESS
($/Mg)
$1,900
90% control of aggregated
process vents that are not exempt
per cutoffs based on the $5K envelope
90% control of individual
process vents that are not exempt
per cutoffs based on the $5K envelope
98% control of individual
process vents that are not exempt
per cutoffs based on the $5K envelope
53,400
39,400
41,000
Options 2-4 include controlling equipment leaks to the level found in Option 1
Options 2-4 do not include controlling the paints and allied products industry
$94,500,000
$95,000,000
$363,000,000
$1,800
$2,400
$9,000
-------
CD
IMPLEMENTATION ISSUES
- Estimating and/or testing to obtain annual VOC
emission rate (Mass Flux, Ib/yr) and maximum
instantaneous flowrate (scfm)
- Recordkeeping of process equipment usage,
coupled with end-of-the-year audit
- Recordkeeping of control device operating
parameters to ensure compliance with control
requirements
-------
B. INDUSTRY PRESENTATIONS
1147
-------
Batch Processes Control Techniques Guidelines
Richard E. Hamilton
Vice President
On-Demand Environmental Systems, Inc.
505 Asbury Street
San Jose, CA 95110
VOC REMOVAL
Thermal processors offer significant benefits for VOC abatement
control for a variety of industries. If a centrally located thermal
processing unit is used for VOC removal, then all point sources
that emit VOCs may be ducted together and run to the processor. For
a broad range of applications it's understood that not all of the
facility's emission point sources will be emitting VOCs
continuously or at the same time. For example, Figure I shows an
emission cycle of VOCs coming from a semiconductor manufacturing
process. Even though the air flow is continuous, VOCs in the
exhaust stream occur only when chemicals are being used in the
processing steps. For this application, VOCs are in exhaust stream
an average of 18 percent of the time during the two shift per day
operation and range from 30 to 10 percent. Evaluated over a 24 hour
period, the emissions average less than 10 percent of the total
day.
If there are continuous VOC emissions, central processors may be
attractive from the stand point of operating cost. Figure 2
represents a centrally installed thermal processor for a
semiconductor manufacturing operation which as we have studied does
not have continuous VOC emissions. Using several smaller thermal
processors within each local manufacturing area may be a more
practical approach because each can operate more efficiently under
specific conditions and may be inactive when not needed. Figure 3
shows the same point sources benefitting from locally installed
thermal processors that can respond to the emission cycle from the
processing equipment.
Effluent from individual pieces of processing equipment, or small
groups of equipment, may be directed to small VOC processors. If a
fuel-on-demand type processor is controlled by a VOC sensor and a
microcomputer, it will activate only when needed and consume fuel
only when the attached processing equipment is contributing VOCs to
the air stream. This will also lower the cost of VOC destruction
since fuel consumption of thermal processors depends on the volume
of air that passes through them.
FUEL-ON-DEMAND THERMAL PROCESSING SYSTEMS
Microprocessor equipped, fuel-on-demand, thermal processing systems
may be activated to correspond to VOC emission requirements. An
activation signal can be generated by an electric signal indicating
that there are chemicals in the exhaust or by sensors located in
equipment exhaust ducts. For example both a heated surface
1148
-------
semiconductor device and a gas chromatograph on a silicon wafer
have been used to detect total hydrocarbon levels or individual
solvents in the exhaust. Different combinations of sensors can be
used to keep the thermal processors active until VOC levels in the
air stream decay to an acceptable level.
A fuel-on-demand thermal processor must achieve high destruction
efficiency immediately upon activation. Some advantages of reduced
fuel consumption are lost if appreciable stabilization time is
required. Small thermal processors can inject fuel into the stream
containing VOCs. When the mixture reaches its lower flammability
limit, it can be ignited. Proper injection and uniform mixing with
the air stream prior to ignition will prevent channeling of the
VOCs through the flame area. This is important because, in
instances where such channels actually form, VOCs may pass through
a reactor without coming into contact with the flame. Direct flame
contact is necessary since it enables high destruction efficiencies
with short residence time. Figure 4 is a cross section of the
reactor used in the On-Demand Environmental System's thermal
processor which is designed to ensure direct flame contact with the
VOCs in the air stream.
In addition to VOC destruction efficiency, NOx generation is also
an important consideration. Consequently, a responsive thermal
processor that operates only when required will reduce the overall
amount of NOx produced, compared to systems that maintain a high
temperature on a continuous basis. For fuel-on-demand thermal
processors, it has been demonstrated that reactor design affects
the levels of NOx produced during the operation. Levels below lOppm
of NOx during operation have been measured from the On-Demand
technology shown in Figure 4.
COMPUTER CONTROL
A personal computer with interface hardware can cost-effectively
operate the thermal processor if the processors are equipped with
variable fuel flow hardware. Computer software can incorporate
selected algorithms to optimize specific applications. As the VOC
concentrations change, the computer adjusts the flow of fuel to
maintain specific operating conditions. In addition to the basic
features provided by computer-controlled systems, data and alarm
conditions can be electronically logged, thereby providing files
useful for demonstrating regulatory compliance.
INSTALLATION COSTS
Using direct flame contact that provides efficient energy transfer,
the thermal processors can be made small and compact. Therefore,
this technology provides installation flexibility at the point of
generation of the VOC exhaust. Long and costly ducting runs to
central abatement devices can, therefore, be avoided. The units can
be installed in a variety of configurations and can be located
outdoors.
OD335 11/9/91
1149
-------
Duty Cycle
Two Shift Day (16 Hr.)
Figure 1
0.35-d
0.3-
On-Demand Environmental Systems
30.8%
2ao%28.3%
Avg.=18%
1 2 3 4 5 12 13 14 15 16 17 18 19 20 21 22
March 1991
-------
Centrally Installed Abatement
Wafer Track
Positive Photoresist
Acetate,& HMDS Emission
200 CFM, 40 ppm, 33% Duty Cycle
in
Source 1
Fab A
1000
Equipment Cleaning
Acetone/ IPA
1200 CFM, 600 p|
Sources
am, 85% Duty Cycle
Resist Application
Negative Photoresist
Xylene
500 CFM, 150 ppm, 20% Duty Cycle
Source 2
FabB
250
Central
Processor
Location
800
1900 CFM
Xylene
Acetone
IPA
Acetate
HMDS
100% Duty Cycle
Figure 2
On-Demand
Environmental Systems
-------
Point Source Emission Control
in
to
Wafer Track
Positive Photoresist
Acetate,& HMDS Emission
200 CFM, 40 ppm, 33% Duty Cycle
Resist Application
Negative Photoresist
Xylene
500 CFM, 150 ppm, 20% Duty Cycle
Sourco 1
Fab A
t
M-
«
_
25'
M-
-rSsr
Source 2
FabB
+
•35'
MONITOR
r
I
Equipment Cleaning
Acetone/ IPA
1200 CFM, 600 PI
Source 3
3m, 85% Duty Cycle
I
Figure 3
On-Demand
Environmental Systems
-------
VOC Thermal Processor
Combustion Chamber Exhaust
Exit Thermocouple
Combustion Zone
Thermocouple
Figure 4
II 11 c o On-Demand
Air + VOC Input 1 J- rM Environmental Systems
-------
Mr. Rick Hamilton, On-Demand Environmental Systems
This presentation provided an example of actual batch
emissions that currently are being controlled using thermal
incineration. Several semiconductor facilities in California
have installed the small incinerators that On-Demand designs and
sells. The on-stream duration of VOC emissions from these
facilities is representative of typical batch processing
industries. Mr. Hamilton cited an example of VOC emissions7
being in the exhaust stream of a semiconductor process only
18 percent of the time during an 18-hour workday.
Mr. Hamilton also showed two possible configurations for the
units: (1) handling manifolded exhaust vents and (2) controlling
individual exhaust vents at the point of generation. Units
ranging in capacity to handle flowrates of 1,900 (cfm) down to
units handling 65 cfm were shown, and Mr. Hamilton stressed the
compactness of the units, which presumably would ease
installation, especially for controlling process vent streams at
the point of generation. Finally, there was some discussion of
auxiliary equipment that has been employed with the systems,
primarily in detecting VOC's or specific air toxics in the vent
streams, and of the method of feedback control to augment or
release fuel in the incinerator only during a VOC emission event.
1154
-------
CHEMICAL
MANUFACTURERS
ASSOCIATION
STATEMENT OF
TERRI RANGANTH
ON BEHALF OF
THE CHEMICAL MANUFACTURES ASSOCIATION
BEFORE THE
NATIONAL AIR POLLUTION CONTROL
TECHNIQUES ADVISORY COMMITTEE
ON THE
CONTROL TECHNIQUES GUIDELINES FOR BATCH PROCESS
NOVEMBER 21, 1991
1155
2501 M Street, NW 202-887-1100
Washington, D.C. 20037 Telex 89617 (CMA WSH)
-------
TESTIMONY OF THE CHEMICAL MANUFACTURERS ASSOCIATION BEFORE THE
NATIONAL AIR POLLUTION CONTROL TECHNICAL ADVISORY COMMITTEE
ON THE CONTROL TECHNIQUES GUIDELINES FOR BATCH PROCESSES
NOVEMBER 21, 1991
Good Afternoon. My name Is Terry Ranganath, Air Quality
Engineer with du Pont. I am happy to be before you today to
present testimony of the Chemical Manufacturers Association
(CMA) on the draft Control Techniques Guidelines for Control of
Volatile Organic Compound Emissions from Batch Processes. CMA
is a nonprofit trade association whose members comprise 90% of
the productive capacity for basic chemicals in the United
States. My presentation this afternoon will feature several of
CMA's observations, concerns, and recommendations regarding
CTG's, particularly the Batch Processing document
CMA fully appreciates the role of CTG's in setting
Reasonably Available Control Technology (RACT) for
nonattainment areas. Although styled as guidance documents,
CTG's are in practice more than merely guidance. Air quality
professionals in government, industry, and environmental groups
recognize that CTG's are regarded as the final word in many
regulatory programs. It is important that CTG's reflect the
type of well informed and reasoned analysis that such
influential documents demand.
Control Technique Guidelines hold special significance for
companies that emit substances listed as hazardous air
pollutants (HAPS) under section 112. Many of the 189 chemicals
listed as HAPs are volatile organics. Companies that emit
VOC's on the section 112 list face the prospect of complying
with both RACT standards and MACT standards.
It is important that EPA recognize that RACT and MACT are
two different standards. The Clean Air Act clearly
contemplates that the "reasonably available" technology of RACT
standards are less stringent than the "maximum degree of
reduction" required under MACT. CMA is concerned that the CTG
for Batch Processes confuses the two technology requirements.
CMA supports performance standards based on percent
reduction as presented in the batch processes CTG. However, we
believe the stringent 98% reduction efficiencies discussed in
the document are not appropriate for setting RACT. In fact,
the draft CTG reads at times like a MACT standard. When the
Agency identifies the presumptive norm for RACT for Batch
Processes, the discussion should be limited to control options
more in line with RACT.
Sources that are required to meet both RACT and MACT for a
particular emission must not be forced to comply with
inconsistent standards. CMA believes that sources which comply
with the more stringent MACT standard should be deemed to be in
compliance with the less stringent RACT requirements.
1156
-------
The suggested RACT for Batch Processes is not identified
from the list of options in the draft CTG. When the
presumptive norm for RACT is identified, we recommend that the
Agency revise the acceptable control efficiencies to reflect
the realities of operating the presumptive control equipment.
Performance of control equipment varies with the type of
chemicals involved and operating conditions. Therefore,
instead of a single percent reduction efficiency; the CTG
should identify an acceptable performance range which would
reflect real life emission control operations.
There are two more areas of concern I would like to
address this afternoon. The first regards the model used for
synthetic resin manufacturing. The suspension-type
polymerization operation illustrated in the draft CTG is not
representative of typical synthetic resin manufacturing. In
particular, the 100% vapor saturation assumed in the example
does not account for the many operations which undergo full
vessel cleansing with water. CMA recommends that the CTG
consider more accurate examples of synthetic resin
manufacturing.
Secondly, we disagree with the suggestion that SOCMI
factors be used to estimate emissions from equipment leaks.
This is inconsistent with Agency's refusal to allow SOCMI
factors to be used in establishing baselines in the credit for
early reduction program. Disallowing SOCMI factors in the
credits program is a tacit admission that the SOCMI factors
grossly overestimate actual emissions. We recommend that the
Batch Processing CTG adopt the more accurate POSSEE database,
which is the CMA designed data entry system for fugitive
emissions testing.
To conclude my comments, I would like to reiterate CMA's
support for the performance based format suggested in the Batch
Processing CTG. CMA also supports the bubbling approach
discussed in the CTG as a means of complying with overall
process control requirements. We are interested in working
constructively with EPA in developing technically sound CTG's
and look forward to offering further input. CMA thanks the
committee for the opportunity to offer our views on the CTG for
Batch Processes. I'd be happy to answer any questions from the
committee.
1157
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Ms. Terri Ranganath, Chemical Manufacturers Association
Ms. Ranganath, E. I. du Pont de Nemours & Co., Inc.,
representing the CMA, made a presentation which is included in
the attached handouts. CMA agrees with the performance-based
standard of the options but stated that the use of the average
SOCMI factors overstated emissions from leaking process
components. Additionally, a concern was stated that the
assumption EPA used for vapor space saturation also would
overstate emissions. The prepared speech also stated that CMA
agreed with the "bubbling approach as a means of compliance."
[Ed. Note: No bubbling approach is discussed in the CTG; there
is a RACT option that requires that facilities aggregate annual
emissions and maximum flowrates from single unit processes to use
in determining whether control is required.] Ms. Ranganath also
suggested that the CMA's POSSE data base be used in estimating
equipment leak emissions.
1158
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C. DISCUSSION
After all three presentations were made, the floor was
opened up for questions from NAPCTAC members. This discussion is
summarized below.
Ms. Deborah Sheiman of the Natural Resources Defense Council
(NRDC) opened the discussion by asking Mr. McDonald what the
difference was between RACT Options 2 and 3 on the slide.
Mr. McDonald responded that RACT Option 2 represented the
"aggregated" option, while RACT Option 3 represented the
"individual" option for 90 percent control of sources. Both
options are in accordance with the $5,000/Mg envelope used for
illustrative purposes. The aggregated options, simply put,
require that the annual emission rates from all process vents
from single process lines be aggregated and then used in the RACT
equation to yield a flowrate cutoff to determine whether the
sources must be controlled. Mr. McDonald pointed out that the
option does not require that facilities physically manifold their
process vents together, but only requires that the control
requirement be evaluated as if the vents were manifolded
together. The impact of aggregation in an option is that more
streams will require control for the same cost compare with the
individual option, as the numbers indicated. Ms. Sheiman also
questioned why the more stringent RACT options were not presented
on the slide. Mr. McDonald responded that the slide was intended
to show the format and impacts of the options, but for simplicity
showed only four examples. All RACT options are presented in the
draft CTG document.
Mr. Brian Taranto of Exxon Chemical Americas commented on
the assumption made for estimating baseline (i.e., current
control practices). He also said that the assumption that
industries other than Pharmaceuticals are uncontrolled results in
overestimating the national emissions from batch processes. He
asked Mr. McDonald what the effect of this overestimation would
be on the estimated nationwide impacts of the CTG. Mr. McDonald
responded that if the baseline emissions were in fact
overestimated, the net emission reduction resulting from the CTG
would decrease, as would the national cost associated with
implementing it. Mr. Tarranto suggested that baseline control be
more precisely evaluated. Ms. Ranganath repeated her concern
that use of average SOCMI factors also overstate emissions [for
equipment leaks].
Mr. John Pinkerton, Program Director of Air Quality for the
National Council of the Paper Industry for Air and Stream
Improvement, Inc., asked whether batch processing emissions would
be covered under the Hazardous Organic NESHAP (HON). Ms. Susan
Wyatt, Chief of CPB, stated that the HON specifically exempts VOC
emissions from batch process vents at SOCMI facilities subject to
1159
-------
8
the HON. However, some industries utilizing batch processes,
such as the polymers and resins industry and the Pharmaceuticals
industry, are on the source category list for NESHAP development
efforts. Two NESHAP's currently are underway for the polymers
and resins industry. These standards are expected to be
completed within 4 years. Mr. Pinkerton expressed concern that
the CTG might go into effect before a MACT standard for the same
source, conceivably forcing facilities to undertake costs of
controlling for a less stringent standard, only to have to
retrofit or redesign a control system entirely for a more
stringent standard a short time later.
Concern was also expressed about the way in which control
device cost effectiveness was calculated. Mr. McDonald restated
the methodology and stressed that the cost-effectiveness values
obtained for the RACT options are really average values.
Ms. Vivian Mclntire of Eastman Chemicals Company had several
questions and comments on the CTG. The first concerned whether
the methodology considered sizing of devices for peak flows that
seemed to be insignificant to the overall emissions profile, as
was described in the slides. Ms. Brenda Shine of Midwest
Research Institute assured her that the size and, therefore, the
capital cost of the control device was based on the peak or
maximum flow. Ms. Mclntire suggested that the "mass flux" term
be introduced earlier in the document and pointed out some
typographical problems with the document. Ms. Mclntyre also
asked about the specifics of the pressure testing provision
contained in the equipment leaks negotiated regulation. This
question was addressed by Mr. Bob Ajax (seated in the audience),
formerly of the OAQPS Emission Standards Division, who was the
EPA representative in the development of this regulation while an
BSD Branch Chief. He explained the background of the regulation
and added that the provision allowing pressure testing for batch
equipment was taken directly from industry suggestions.
Ms. Mclntire also expressed her concern that the CTG would
recommend stack testing as a means of verifying emission rate and
added that stack testing of batch emissions could lead to
erroneous results. [Ed. Note: EPA has not recommended stack
testing to determine applicability for the batch processes CTG
but rather an estimation procedure as of the date of this NAPCTAC
meeting.
Mr. Taranto commended the batch team for including energy
and other environmental impacts and asked EPA to address the need
for facilities to obtain emission offsets and to do permitting.
-------
VOLATILE ORGANIC LIQUID STORAGE
CONTROL TECHNIQUES GUIDELINES DOCUMENT
A. EPA PRESENTATION
Mr. Mark Morris
Emission Standards Division
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Mr. Morris presented a summary of the draft CTG. This
presentation is provided in full text below:
In ozone nonattainment areas there are thousands of tanks
storing petroleum liquids and chemical products at facilities
such as petroleum refineries, chemical plants, manufacturing
facilities, and terminals and other distribution facilities.
These tanks emit over 200,000 metric tons of volatile organic
compounds (VOC) annually, making storage tanks one of the largest
stationary sources of VOC emissions. It is possible to reduce
these emissions by using readily available and cost-effective
controls.
In this presentation we present the types of storage tanks
and their emission mechanisms and controls. We also will present
some reasonably available control technology options, or RACT
options, and the benefits and costs of these options. Finally,
we will discuss the implementation of RACT.
There are three basic types of tanks. There are fixed roof
tanks, internal floating tanks, or IFR tanks, and external
floating roof tanks, or EFR tanks. These tanks are typically
aboveground and field erected.
Our first diagram is of a fixed roof tank. These tanks are
typically large, with the average petroleum tank having a
capacity of 1.3 million gallons, and the average chemical tank
having a capacity of 160,000 gallons to 200,000 gallons. The
fixed roof tank consists of a welded steel shell with a fixed
roof. The fixed roof may be sloped or cone-shaped and supported
by one or more columns, or it may be a self-supported dome
without any supportive columns. The fixed roof tank is equipped
with hatches that allow access into the tank. It is also
equipped with a pressure-vacuum valve. This valve prevents
damage to the tank by allowing a slight internal pressure or
vacuum to exist within the tank. Since this valve allows only a
slight pressure to exist within the tank, any pressure buildup in
the tank would result in emissions through the valve.
llfil
-------
There are two basic emission mechanisms of the fixed roof
tank: working losses and breathing losses. Working losses are
those losses that result due to a change in the liquid level in
the tank. When liquid is withdrawn from the tank and the liquid
level goes down, ambient air is drawn in through the pressure-
vacuum valve. This air becomes saturated with VOC's and is
expelled through the pressure-vacuum valve when the liquid level
rises. Breathing losses result due to daily temperature changes,
which cause the thermal expansion and expulsion of the vapor
inside the tank. Breathing losses also result from changes in
atmospheric pressure.
Some of the parameters that affect fixed roof tank emissions
include the tank volume, the number of emptying/filling cycles,
or turnovers, and the vapor pressure and molecular weight of the
stored liquid. Emissions from typical petroleum and chemical
fixed roof tanks are given on the next slide.
As shown in the table, working losses make up about 75 to 90
percent of the overall fixed roof tank emissions. You can also
see from the table that the petroleum tank emits more than the
chemical tank. Although the chemical tank experiences more
turnovers, the petroleum tank emits more because it is larger.
Emissions in nonattainment areas from fixed roof tanks are given
in the next table.
Overall, fixed roof tanks emit a substantial amount of
VOC's. About 23,000 fixed roof tanks emit approximately 87,000
megagrams per year. As shown in the table, about 11,500
petroleum tanks store liquids with vapor pressures less than or
equal to .5 psia. These tanks emit about 13,700 megagrams per
year, or about one megagram per tank per year. About 780
petroleum tanks emit approximately 8300 megagrams per year in the
.5 to 1.0 psia vapor pressure range. This works out to be about
eleven megagrams per tank per year. In the vapor pressure range
of 1.0 to 1.5 psia, about 1800 petroleum tanks emit approximately
47,000 megagrams per year, or about 26 megagrams per tank per
year. You can see from the table that there are no tanks used to
store liquids with vapor pressures greater than or equal to 1.5
psia. This is due to the fact that the 1977 fixed roof tank CTG
and state implementation plans prohibit the use of fixed roof
tanks for storing liquids above this vapor pressure. These
emissions can be reduced by using the controls listed on the next
slide.
Fixed roof tank emissions can be reduced by using vapor
recovery devices such as condensers and carbon adsorbers. Vapor
control devices can also be used, such as incinerators. These
devices are capable of reducing emissions by 95 percent or more.
Another, more common option is to install an internal floating
roof. On average, installing an IFR in a fixed roof tank reduces
emissions by about 95 percent. Installing an IFR requires that
the fixed roof tank be emptied, cleaned, and degassed. By
installing an IFR, the fixed roof tank is converted to our second
1162
-------
tank type, the internal floating roof tank.
Again, the internal floating roof tank has two roofs. It
has a fixed roof and a floating roof which rises and falls with
the liquid level. The floating roof can rest in complete contact
with the liquid, or it can rest on pontoons above the surface of
the liquid. IFR's are typically made of aluminum, but can be
made using materials such as steel or stainless steel. The
floating roof covers most of the liquid surface, and thus
prevents the vaporization of the stored liquid into the space
above the floating roof. The floating roof does not cover the
entire liquid surface; there is still a space between the
floating roof and the tank wall in which vaporization can occur.
Floating roofs are equipped with seals to close this space.
Some of the seal types that are used include vapor-mounted
seals, liquid-mounted seals, and mechanical shoe seals. The
vapor-mounted seal is mounted such that a vapor space exists
between the seal material and the stored liquid. The liquid-
mounted seal is mounted such that the seal material is submerged
in the liquid and no vapor space exists between the seal and the
liquid. The mechanical shoe seal consists of a metallic shoe
that is held against the tank wall by springs or weights, and a
seal which extends from the floating roof to the metallic shoe to
close the vapor space.
Some of the parameters that affect the emissions from the
IFR tank include the tank diameter and the vapor pressure and
molecular weight of the stored liquid. There are two basic loss
mechanisms of the IFR tank: static losses and working losses.
Static losses consist of losses from seals, deck seams, and deck
fittings. Working losses, again, result due to changes in the
liquid level. When the liquid level goes down, the tank wall is
exposed. The liquid that clings to the wall will vaporize and
escape through the roof vents at the top of the tank. Emissions
from a typical IFR tank are given on the next slide.
Again, static losses consist of seal losses, fitting losses,
and deck seam losses. For the purposes of estimating costs and
emissions, a baseline IFR tank was used which was equipped with a
seamed floating roof with a vapor-mounted seal and typical
fittings. For IFR's equipped with vapor-mounted seals, emissions
can be reduced by taking out the vapor-mounted seal and
installing a liquid-mounted seal. Emissions could also be
reduced by installing a secondary seal above the vapor-mounted
primary seal. For IFR's equipped with liquid-mounted seals,
emissions can be reduced by installing a secondary seal above the
liquid-mounted primary seal. Fitting losses on IFR's can be
reduced by gasketing the fittings. Gasketing the fittings
results in an emission reduction of about 50 percent. Some IFR
fittings can be both gasketed and bolted to reduce emissions, as
in the case of an access hatch. For seamed IFR's, emissions can
be reduced or eliminated by taking out the seamed roof and
installing a welded roof, which has no deck seams. Although
11R3
-------
static losses can be reduced by using the controls described
above, there are no controls available for reducing the working
losses. IFR emissions in nonattainment areas are given in the
next slide.
Overall, about 8000 tanks emit approximately 22,000
megagrams per year. Most of these emissions are from tanks
storing liquids with vapor pressures greater than or equal to 1.5
psia. Most of these tanks are fixed roof tank conversions to IFR
tanks due to the 1977 fixed roof tank CTG.
Our third tank type is the external floating roof tank. EFR
tanks have no fixed roof but have a roof that rises and falls
with the liquid level. EFR's are not typically used in the
chemical industry. The losses from the EFR tank are similar to
those of the IFR tank in that there are seal losses, fitting
losses, and working losses. However, EFR losses differ from IFR
losses in several ways. Since EFR tanks have no fixed roof, the
wind affects the losses more than from the IFR tank. EFR tanks
have welded roofs and therefore have no losses from deck seams as
do IFR tanks. Emissions from a typical EFR tank are given in the
next slide.
Again, static losses consist of only seal losses and fitting
losses since EFR's have no deck seams. There were two baseline
cases for EFR tanks due to past regulations. The baseline EFR
storing a liquid with a vapor pressure less than 1.5 psia was one
equipped with a mechanical shoe seal and typical fittings. The
baseline EFR storing a liquid with any other vapor pressure was
equipped with a mechanical shoe seal, secondary seal, and typical
fittings. For EFR's with vapor-mounted seals, emissions can be
reduced by taking out this seal and installing a liquid-mounted
seal or a mechanical shoe seal, or by installing a secondary seal
above the vapor-mounted seal. For EFR's with liquid-mounted
seals or mechanical shoe seals, emissions can be reduced by
installing secondary seals above these seals. Fitting emissions
on EFR's can reduced by gasketing the fittings. Gasketing the
fittings reduces emissions by about 95 percent. Again, although
static losses can be reduced, there are no controls for reducing
working losses. EFR tank emissions in nonattainment areas are
given on the next slide.
About 10,000 EFR tanks emit about 108,000 megagrams per
year. Most of these emissions are due to seals on tanks storing
liquids with vapor pressures greater than 1.5 psia. Since the
1978 external floating roof CTG and state implementation plans
require secondary seals above this vapor pressure, no further
reductions can be achieved above this vapor pressure. However,
fitting emissions can be reduced at all vapor pressures.
RACT options for VOL storage consist of control technology
requirements for each tank type and some applicability criteria
such as tank capacity cutoffs and liquid vapor pressure cutoffs.
The control technology requirements for our selected options are,
1184
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for fixed roof tanks, to install an IFR with a double seal system
or single seal system with a liquid-mounted or mechanical shoe
seal. The fittings would also have to be controlled. The
requirements for IFR and EFR tanks would be to install secondary
seals and control fittings.
This next slide presents our selected RACT options. These
options differ only in their applicability criteria since the
control technology requirements are all the same. Option six is
the most stringent option listed. It has a vapor pressure cutoff
of .5 psia and capacity cutoffs of 20,000 gallons for fixed roof
tanks and 40,000 gallons for IFR and EFR tanks. Option three in
this table most closely resembles the VOL NSPS level of control.
Option three has a vapor pressure cutoff of .75 psia and a
capacity cutoff of 40,000 gallons for all tank types. The
impacts of these options are given on the next slide.
Again, option six is our most stringent option. It results
in an emission reduction of about 84,000 megagrams per year at a
total annual cost of about 49.3 million dollars, and average cost
effectiveness of about 590 dollars per megagram. Option six
results in an emission reduction of about 80,000 megagrams per
year at a total annual cost of about 37.2 million dollars, and
average cost effectiveness of about 470 dollars per megagram.
Also shown on this table are incremental cost effectiveness
values. As shown in the table, going from option three to option
four, which is essentially becoming more stringent than the
latest NSPS level of control, results in an incremental cost
effectiveness of about 2200 dollars per megagram.
Since RACT is a requirement for specific equipment, the
format would be that of an equipment standard. However, vapor
recovery or control devices are acceptable if they are capable of
achieving 95 percent reduction. Some sort of compliance
determination would need to be done to ensure proper installation
and operation of the required controls.
For IFR tanks, this compliance determination would consist
of an initial internal inspection of the tank and seals, followed
by annual visual inspections, and internal inspections once every
ten years. For EFR tanks, the compliance determination would
consist of initial primary and secondary seal gap measurements,
followed by annual secondary seal gap measurements, and primary
seal gap measurements every five years. There would also be a
visual inspection whenever the tank was empty.
The compliance schedule for the different tank types may
differ. Installing RACT on IFR tanks requires that the tank be
cleaned and degassed. The emissions that result from the
cleaning process are actually greater than the emission
reductions achieved by installing the controls. Therefore, it is
recommended that the installation of RACT on IFR tanks be delayed
to the next tank cleaning. Installing RACT on fixed roof tanks
also requires that the tank be cleaned and degassed. However,
-------
the emission reductions achieved by installing the controls are
greater.than the cleaning and degassing emissions. It is
therefore recommended that there be no delay in the installation
of RACT for fixed roof tanks. Installing RACT on EFR tanks does
not require the tank to be cleaned and degassed. It is therefore
recommended that there be no delay in the installation of RACT
for EFR tanks
This concludes our presentation.
Ilfifi
-------
CONTROL TECHNIQUE GUIDELINES
(CTG) FOR VOLATILE ORGANIC
LIQUID STORAGE
NAPCTAC PRESENTATION
NOVEMBER 21, 1991
/-> PV
n 7
b 1906-1. ADD/1
-------
ORGANIZATION OF PRESENTATION
• Types of tanks
• RACT options
• RACT implementation
b 1906-1. ADD/2
-------
TYPES OF TANKS
Fixed roof tanks
Internal floating roof tanks (IFR's)
External floating roof tanks (EFR's)
lies
b!906-l. ADD/3
-------
Pressure-Vacuum
Valve
Gauge Hatch
Manhole
Manhole
Tank Support
Column
Nozzle
(For Submerged
Fill or Drainage)
I'
-------
EMISSIONS FROM A TYPICAL FIXED ROOF TANK
Losses
Breathing
Working
Total
Chemical
(160,000 gal,
50 turnovers/yr)
Mg/yr
0.9
5.3
6.2
%
15
85
100
Petroleum
(1 .3 million gal,
1 1 turnovers/yr)
Mg/yr
5.0
15.0
20
%
25
75
100
h 1906-1. ADD'5
-------
EMISSIONS FROM FIXED ROOF TANKS IN
NONATTAINMENT AREAS
Vapor pressure (psia)
< 0.5
0.5 - 1
1 - 1.5
> 1.5
Total
Petroleum liquid
Number
11,500
780
1,800
0
14,100
Emissions
(Mg/yr)
13,700
8,300
47,000
0
69,000
Chemical
Number
8,200
450
450
0
9,100
Emissions
(Mg/yr)
10,500
2,250
4,300
0
17,100
MW6-1 .ADD'6
-------
FIXED ROOF TANK CONTROLS
Vapor recovery/control
Install IFR
b 1906-1. ADD/7
-------
Cantor Vent
Peripheral
Roof Vent
Primary Seal
Manhole
Rkn
Tank Support
Column with
Column Well
Rbn Pontoon
Rim Pontoons
Vapor Space
1174
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EMISSIONS AND CONTROLS FOR
A TYPICAL IFR TANK
Baseline
Baseline
Baseline
Seal losses
Vapor-mounted
Liquid-mounted
Vapor-mounted and
secondary seals
Liquid-mounted and
secondary seals
Fitting losses
Ungasketed
Gasketed
Deck seam losses
Seams
Welded
Working losses
Emissions
(Mg/yr)
0.13
0.06
0.05
0.03
0.21
0.11
0.04
0
0.03
b 1906-1. ADD/9
-------
EMISSIONS FROM IFR TANKS IN
NONATTAINMENT AREAS
Vapor
pressure
(psia)
<0.5
0.5 - 1.0
1.0-1.5
>1.5
Petroleum liquid
Number
130
25
60
5,260
Emissions
(Mg/yr)
18
24
84
18,810
Chemical
Number
0
250
250
1,400
Emissions
(Mg/yr)
0
200
300
1,500
M
h!9O6-l.ADD/10
-------
Rolling Ladder •
Pontoon
Manhole
•Guide Pole
Main Drain
Automatic
Bleeder
Vent
Tank Gauge
Access Hatch
Seal Envelope
Primary
Shoe Seal
• Roof Leg
Support
Rim Vent
r
1—Roof Drain
~ 77
1- -.' a
-------
EMISSIONS AND CONTROLS FOR
A TYPICAL EFR TANK
Baseline
«1.5 psia)
Baseline
(>1.5 psia)
Seal losses
Vapor-mounted
Vapor-mounted and
secondary
Mechanical shoe
Emissions
(Mg/yr)
Mechanical shoe and
secondary
Liquid-mounted
Liquid-mounted and
secondary
Fitting losses
Ungasketed
Gasketed
Working losses
15.0
4.7
1.25
0.12
0.70
0.10
0.24
0.02
0.22
T
JL
b!906-l. ADD/12
-------
EMISSIONS FROM EFR SEALS AND
FITTINGS IN NONATTAINMENT AREAS
Vapor
pressure
(psia)
<0.5
0.5 - 1
1 - 1.5
>1.5
Number of
tanks
960
300
470
8,000
Seal
emissions
(Mg/yr)
450
330
1,250
91,500
Fitting
emissions
(Mg/yr)
73
75
190
15,600
Total
523
405
1,440
105,400
M906-I ADD 13
-------
RACT OPTION VARIABLES
• Control technology
• Tank capacity
• Liquid vapor pressure
II
bl906-l. ADD/14
-------
RACT CONTROL TECHNOLOGY
• Existing FIXED ROOF TANK -
INSTALL IFR EQUIPPED with
- Vapor mounted primary and
secondary seals
OR
- Liquid mounted primary seal
OR
- Shoe seal
AND
- Control fittings
• Existing IFR
- Control fittings
- Install secondary seal over
vapor mounted primary seal
• Existing EFR's
- Control fittings
- Install secondary seal
T 1 Q
i. i s ?
b!906-l. ADD/15
-------
RACT OPTIONS
Option No.
1
II
III
IV
V
VI
Small
fixed roof
(20K < V <40K
gal)
--
—
—
VP>1.5
VP>0.5
Large
fixed roof
(V >40K gal)
VP>1.0
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
Internal
floating roof
(V >40K gal)
VP>1.5
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
External
floating roof
(V >40K gal)
VP>1.5
VP>1.0
VP>0.75
VP>0.5
VP>0.5
VP>0.5
CO
M9O6-I.ADD/16
-------
RACT OPTION IMPACTS
Option
No.
1
II
III
IV
V
VI
Emission
reduction
(Mg/yr)
66,200
73,500
79,700
82,800
83,400
84,000
Total
annual
cost
($106/yr)
23.8
32.0
37.2
44.0
46.1
49.3
Cost
effectiveness
($/Mg)
360
430
470
530
550
590
Incremental
cost
effectiveness
($/Mg)
N/A
1,100
900
2,200
3,800
4,800
SO
CO
M906-1. ADD/17
-------
RACT IMPLEMENTATION
Equipment format
Compliance determination
1184
b!906-l.ADD/18
-------
COMPLIANCE DETERMINATION
FOR IFR's
Initial internal inspection
Annual visual inspection
Internal visual inspection once every
10 years
b!906-l. ADD/19
-------
COMPLIANCE DETERMINATION
FOR EFR's
Initial gap measurement
Annual secondary seal gap measurements
Primary seal gap measurement once every
5 years
Visual inspection whenever tank is empty
JL
b 1906-1. ADD/20
-------
COMPLIANCE SCHEDULE
• IFR's - existing IFR's required to install
RACT at next scheduled cleaning or 10
years after promulgation
• Fixed roof tanks
• EFR's
T i 07
.L 1 e.J i
b 1906-1. ADD/21
-------
B. INDUSTRY PRESENTATIONS
-------
Presentation to the USEPA's NAPCTAC
Commenting on the Draft CTG for VOL Storage Document
Sheraton Inn University Center
Durham, North Carolina
Presented by Rob Ferry
Conservatek Industries, Inc.
Chapel Hill, North Carolina
November 21, 1991
1189
-------
Summary
The conversion of external floating roof tanks to internal
floating roof tanks by covering the tank with a self-supporting
fixed roof is an established equipment option, recognized by both
the American Petroleum Institute (API) and the U. S.
Environmental Protection Agency (EPA). The type of
self-supporting roof which is typically used for this purpose is
the aluminum dome. This fact is also recognized by both API and
EPA. It can be readily demonstrated from the API Publications
2517 and 2519 that this equipment option has lower emissions than
either internal floating roof tanks which have column-supported
fixed roofs, or typical external floating roof tanks.
The recommendations of this presentation are that:
covering an external floating roof tank with a
self-supporting roof be recognized as an equipment
option,
- this equipment option be described as typically being
an aluminum dome, and
- this equipment option be recognized as being at the
most efficient end of the hierarchy.
Documentation
Recognition of external floating roofs being converted to
internal floating roofs by covering with a self-supporting fixed
roof:
API - Publication 2519 (excerpt attached)
EPA - AP-42 (excerpt attached)
The typical type of retrofit self-supporting fixed roof is an
aluminum dome:
API - Standard 65O Appendix G (publication scheduled for
December 1991)
EPA - CTG for Control of Organic Compound Emissions from
Industrial Wastewater (excerpt from draft attached)
This equipment option has lower emissions than either Internal
floating roof tanks with columns, or external floating roof
tanks:
This is a straightforward conclusion from the API
Publications. The conversion to an internal floating roof tank
by covering an external floating roof tank would result in a floating
deck with no deck seams, columns or stub drains. API Publication
2519 has separate figures for typical fitting loss factors for
column-supported fixed roofs and self-supporting fixed roofs.
This comparison is summarized in a Table from an article
published in the Oil and Gas Journal (copy attached).
API Publication 2517 expressly states that emissions from
external floating roof tanks is wind dependent, and API
Publication 2519 expressly states that the wind movement in a
tank which is covered with a freely vented fixed roof is not
significant. Covering the external floating roof tank, then,
eliminates the effect of the primary force which Induces vapor
losses (i.e. the wind).
11
-------
The magnitude of this reduction is illustrated on the attached
Figure 1 for both a typical fitting scenario and for the case of
a slotted gauge pole. There is not presently a table of loss
factors for the fittings with this equipment option, and
alternate methodologies result in different factors. This is
illustrated in Figure 1 by showing a range for the loss factors,
which is bounded by the two commonly suggested methodologies.
The API is currently preparing a contract to have the previous
test data reviewed, and the conflict in the factors resolved. It
is readily apparent, however, that wherever the most appropriate
value may fall within the defined range, it would still represent
a significant reduction in emissions.
Conclusion
If the CTG is silent with respect to this equipment option, then
the States may not recognize the emission control efficiency that
a user achieves by covering an external floating roof tank with a
dome. Such an omission might serve, in effect, to discourage the
use of a very effective control technology. I respectfully
request, therefore, that the language of the CTG be
modified to incorporate the recommendations set forth in the
Summary above. This could be achieved by adopting the specific
language which is included in the API comments concerning this
issue, and additionally including descriptive language
identifying aluminum dome roofs, similar to that in the
Industrial Wastewater CTG (excerpt attached).
-------
EVAPORATION LOSS FROM INTERNAL FLOATING-ROOF TANKS
19
SECTION 2—DESCRIPTION OF INTERNAL FLOATING-ROOF TANK COMPONENTS
2.1 Internal Floating-Roof Tanks
Internal floating-roof tanks are cylindrical vessels that
have both a fixed roof over the top^of the tank, and a
Jloating deck that rests on the liquid stock surface. There
are two basic types of internal floating-roof tanks:
(1) tanks in which the fixed roof is supported by vertical
columns within the tank, which are typical of fixed-roof
tanks fitted with an internal floating deck; and (2) tanks
with a self-supporting fixed roof, with no internal sup-
port columns, which are typical of external floating-roof
tanks covered with a fixed roof. Tanks initially con-
structed with both a fixed roof and a floating deck may be
of either type.
addition to a cylindrical shell and fixed roof, the
basic components of an internal floating-roof tank in-
clude: (1) a floating deck; (2) an annular rim seal at-
tached to the perimeter of the floating deck; and (3) fit-
tings that penetrate the floating deck and provide support
for the fixed roof or serve operational functions. General
types of these components, which are available in a range
of commercial designs, are described in this section.
Included in these descriptions are comments on evapora-
tive loss potential, as well as some design and opera-
tional characteristics. There are other factors, such as
tank maintenance and safety, which are important in
designing and selecting tank equipment, but which are
outside the scope of this publication.
The use of an internal floating deck will reduce the
concentration of hydrocarbon vapor in the space between
the floating deck and the fixed roof from that which
would occur in a fixed-roof tank. This could result in the
occurrence of flammable vapor-air mixtures within the
tank. To minimize the occurrence of flammable vapor-air
mixtures, vents are installed at the top of the tank shell or
in the fixed roof to provide circulation of air through the
space between the fixed roof and the floating deck. API
Standard 650 [1], Appendix H, specifies the use of such
vents and outlines design details for the storage of pe-
troleum liquids. Such tanks are referred to as freely
vented internal floating-roof tanks and are those for
which the loss-estimating procedures in Section 1 are
applicable.
Closed internal floating-roof tanks refer to those which
are vented only through a pressure/vacuum relief vent.
Such tanks are sometimes used in chemical liquid service
and in petroleum liquid service where API Standard 650
is not used. These tanks are typically designed with
auxiliary safety devices, as specified by the user. The
loss-estimating procedures in Section 1 are not applicable
to closed internal floating-roof tanks.
2.2 Floating Decks
Floating decks are typically used to control evapora-
tive stock loss. The basic design concept is to reduce the
liquid surface exposed to evaporation to a minimum by
placing a floating deck in contact with the liquid surface
or by confining a layer of saturated vapor under a vapor-
tight deck floating above the liquid. The loss of vapor
otherwise displaced from fixed-roof tanks by filling and
breathing is virtually eliminated. Evaporation loss does
occur during standing storage through the annular rim
space, deck fittings, and, in some cases, deck seams.
Floating decks are used in volatile stock service, for
stocks with a true vapor pressure at storage conditions
below atmospheric pressure (that is, nonboiling). They
are available in virtually all commercial tank sizes, with
diameters ranging from about 400 feet to 20 feet, and
with slight modification, down to 8 feet. Methods and
materials have been developed to properly seal the annu-
lar space between the tank shell and the deck rim plate,
as well as sealing around any number of fittings that
penetrate the deck.
Floating decks are currently of two general types:
(1) decks constructed by bolting (or mechanically join-
ing by any method) sheets or panels of deck material and
(2) decks of welded construction. Decks with bolted
seams are typically made of lightweight materials,
whereas welded decks are typically made of steel plates.
Both types of decks are typically designed in accordance
with API Standard 650, Appendix H.
Floating decks can be further characterized by the
location of the deck relative to the liquid stock surface. A
deck that is supported above the liquid stock surface by
bouyant structures is referred to as a noncontact deck. A
deck that floats directly on the liquid stock surface is
referred to as a contact deck. Steel decks are typically of
contact design, whereas nonferrous materials are used in
both noncontact and contact designs.
These general types and designs of floating decks are
currently available in many different materials and with
various design features. The basic types of floating decks
used in internal floating-roof tanks are described in 2.2.1
through 2.2.4 and illustrated in Figure 6. More detailed
descriptions are included in Bulletin 2513 [7] for the
welded deck types.
2.2.1 NONCONTACT DECKS WITH BOLTED
SEAMS
This deck type is currently available in two basic
designs. The most common design consists of sheet
aluminum bolted to an aluminum grid framework to form
•v "
-------
14
API PUBLICATION 2519
i
u.~
a
Q
I
4500
4000
3500
3000
2500
2000
1500
1000
500
BOLTED DECK
F, = (0.0228) D2 + (0.79) D + 105.2
\
7
\
7
WELDED DECK (See Note)
F, = (0.0132) D2 + (0.79) 0 + 105.2
50 100 150 200 250
TANK DIAMETER, D (It)
300
350
400
BASIS: Fittings include: (1) access hatch, with ungasketed, unbolted cover; (2) adjustable deck legs; (3) gauge
float well, with ungasketed, unbolted cover; (4) sample well, with slit fabric seal (10 percent open area); (5) 1-
inch diameter stub drains (only on bolted deck); and (6) vacuum breaker, with gasketed weighted mechanical
actuation. This basis was derived from a survey of users and manufacturers. Other fittings may be typically useil
within particular companies or organizations to reflect standards and/or specifications of that group. This figure
should not supersede information based on actual tank data.
NOTES: If no specific information is available, assume welded decks are the most common/typical type currently
> in use in tanks with self-supporting fixed roofs.
Figure 2—Total Deck Fitting Loss Factors (F,) for Typical Deck Fittings
in Tanks with Self-Supporting Fixed Roofs
-------
External Floating Roof Tanks - A typical external floating roof tank is
shown in Figure A.3-2. This type of tank consists of a cylindrical steel
shell equipped with a roof which floats on the surface of the stored liquid,
rising and falling with the liquid level. The liquid surface is completely
covered by the floating roof, except at the small annular space between the
roof and the tank wall. A seal (or seal system) attached to the roof
contacts the tank wall (with small gaps, in some cases) and covers the
annular space. The seal slides against the tank wall as the roof is raised
or lowered. The purpose of the floating roof and the seal (or seal system)
is to reduce the evaporation loss of the stored liquid.
Internal Floating Roof Tanks - An internal floating roof tank has both a
permanent fixed roof and a deck inside. The deck rises and falls with the
liquid level and either floats directly on the liquid surface (contact
deck) or rests on pontoons several inches above the liquid surface (non-
contact deck). The terms "deck" and "floating roof" can be used
interrhanflpably in rpfprpnre to thf structure floating pn t-ho ] j gi)j d_i n^jHp
tank.^ihere are two basic types of internal floating roof tanks, tanf
in which the fixed roof is supported by vertical columns within the tank,
and tanks with a self-supporting fixed roof and no internal support columns.
Fixed roof tanks that have been retrofitted to employ a floating deck are
typically of the first type, while external floating roof tanks typically
have a self-supporting roof when converted to an internal floating roof
tank. Tanks initially constructed with both a fixed roof and a floating
deck may be of either type.
_— •—~^-~ -v___
The deck serves to restrict evaporation of the organic liquid stock.
Evaporation losses from decks may come from deck fittings, nonwelded deck
seams, and the annular space between the deck and tank wall. Typical
contact deck and noncontact deck internal floating roof tanks are shown in
A.3-2
Figure 4.3-2. External floating roof tank.1
EMISSION FACTORS
1194
9/85
-------
c/EPA
United States Office of Air Quality
Environmental Protection Planning and Standards
Agency Research Triangle Park, NC 27711 April 1989
Air
Guideline Series
Control of Volatile
Organic Compound
Emissions from
Industrial
Wastewater
Volume I • Chapters
Preliminary Draft
-------
ratio of the tank diameter to the depth of the wastewater contained in the
tank.
.--' ~» • •——^
^ An existing open-top tank can be converted to a fixed-roof tank by
retrofitting the tank with a dome roof. Aluminum, geodesic dome roofs are
available from several manufacturers. These domes have been used
successfully to cover petroleum and chemical storage tanks. The domes are
clear-span, self-supported structures (i.e., require no internal columns be
placed in the tank) that can be installed on open-top tanks ranging in
diameter from 5 to over_100 m (15 to over 330^ft)_.
Although fixed-roof tanks provide large reductions in organic air
emissions from open-top tanks, fixed-roof tanks still can emit significant
quantities of organics. The major sources of organic air emissions from
fixed-roof tanks are breathing losses and working losses. Breathing losses
occur from the expulsion of vapor through the roof vents because of the
expansion or contraction of the tank vapor space resulting from daily
changes in ambient temperature or barometric pressure. These emissions
occur in the absence of any liquid level change in the tank. Working losses
occur from the displacement of vapors resulting from filling and emptying of
the tank.
Breathing and working losses from fixed-roof tanks can be reduced by
installing an internal floating roof, connecting the tank roof vents to an
add-on control device, or installing pressure-vacuum relief valves on the
tank roof vents. The use of internal floating roofs in fixed-roof tanks is
discussed in Section 4.3.2.2.
For add-on control applications, vapors are contained in the tank until
the internal tank pressure attains a preselected level. Upon reaching this
level, a pressure switch activates a blower to collect the vapors from the
tank and transfer the vapors through piping to the add-on control device.
As a safety precaution, flame arrestors normally are installed between the
tank and control device. Other safety devices may be used such as a
saturator unit to increase the vapor concentration above the upper explosive
limit. Add-on control devices for organic vapors are discussed in
Section 4.4.
113R
4-24
-------
Fitting losses
Fig. 4
Column-supported
ungasketed
0 : 20 '• 40 , 66 60, tOO 120 140 160 186 200
>•'•-, ; .'.M :'! , , ''.•'{• • ,;
. '!.. ;; , Tank diameter, H ' ;
with the same functionality. Further,
losses from some deck seams in IFRTs,
unlike EFRTs, contribute significantly
to total loss. Fig. 1 shows an example,
for a specific case, of how highly
variable losses are from the two types
of floating-roof tanks, with varying
wind speed and different rim seal and
floating deck types. Such comparisons
can be made for specific applications
to identify cost-effective loss control
measures.
Slock inventory control. The esca-
lating value of petroleum stocks over
(he past decade has caused industry to
focus attention on programs empha-
sizing accurate stock inventory ac-
counting and control. Publication
2519, together with improved opera-
tional and maintenance practices,
provides the operator with more accu-
rate procedures to estimate evapora-
tive stock losses, thus allowing for the
evaluation of alternative controls that
will enable the operator to select opti-
mum los's control methods.
Environmental applications. An
emission inventory for existing tanks
can be more accurately developed
using the new publication. Alternative
design features can be evaluated in
the process of providing emission esti-
mates required in permit applications
for modified or new tanks.
The loss equations yield estimates
of the total hydrocarbon vapor emit-
ted to the atmosphere. For environ-
mental considerations, emissions of
interest are generally only the reactive
hydrocarbon vapor, which is typically
defined to exclude methane and eth-
ane. Therefore, these components, if
present, should be subtracted from the
calculated losses for environmental
applications. The results of this API
study, as well as the previous study on
EFRTs, have provided the basis for API
reviews and comments on proposed
environmental tankage emission con-
trol regulations. These results were
provided in full detail to the Environ-
mental Protection Agency, most re-
cently during the public review period
for the currently proposed regulation
on benzene storage tanks.
Calculating IFRT losses
Formulation of equations. Because
essentially no data were generally
available on evaporative losses from
IFRTs, API/CELM developed a com-
prehensive test program to identify
and independently evaluate all the
sources of loss in an IFRT and the
equipment and stock parameters that
affect losses from each source.
CELM formed a task group to over-
see the test program, to analyze the
results, and to document the resulting
calculation procedures. The test pro-
gram, conducted principally by Chi-
cago Bridge & Iron Co. (CB&I), and
the data analysis procedures are de-
scribed in detail in the documentation
records for the publication.
Losses primarily occur during stand-
ing storage. These losses occur from:
1. The rim seal area around the
perimeter of the floating deck
2. The area where fittings (e.g.,
columns that support the fixed roof
that covers the tank) penetrate through
L197
the floating deck
3. Bolted seams in the floating deck
Losses can also occur during and
following emptying of the tank, due to
evaporation of the stock which clings
to the tank shell. These withdrawal
losses are accounted for in the publi-
cation, but are often negligible. Thus,
to avoid unnecessary complexity, the
following discussion will assume that
total IFRT losses can be approximated
by the standing storage loss.
The loss equations account for all
the important tank and stock para-
meters that affect loss. Thus, the most
accurate loss estimates are obtained
when all of the parameters are speci-
fied for a given tank. However, in
many cases, little specific information
is practically available about the tank
or tanks for which an estimate of loss
is desired.
Thus, to accommodate the interests
of both maximum accuracy, when
parameters are known, and maximum
utility, when parameters are not
known, the publication includes infor-
mation on the most common/typical
values for those parameters which
may not routinely be known.
Minimum input. The minimum in-
put necessary to develop a loss esti-
mate includes:
• Slock type (i.e., refined petro-
leum stock, crude oil, or petrochemi-
cal)
• True vapor pressure
• Tank type (i.e., column-support-
ed or self-supported fixed roof)
• Tank diameter
All other parameters can be speci-
fied for existing tanks using the stated
most common/typical values (e.g., va-
por-mounted seal, column-supported
fixed roof, bolted deck).
By specifying these four input para-
meters, estimates of total loss, as well
as the losses from each of the three
sources, can be calculated.
Fig. 2 shows how total and source-
specific losses increase with increas-
ing tank diameter when the other
three basic parameters are constant
and specified as noted. Similar plots
in which the other parameters are
varied would show:
• That total loss is roughly propor-
tional to TVP
• That total loss from a petrochemi-
cal is equal to that from gasoline (for
the same TVP), but that crude oil loss
is approximately 60% lower
• That the fitting loss is significantly
reduced if no columns are used to
support the fixed roof.
Additional parameters. In addition
to the four required input parameters
discussed in the preceding, several
other parameters, if known, can be
used to improve the total loss estimate
and to evaluate various loss control
TECHNOLOGY 5
-------
5000
4-
EFRT 10mph SLOTTED GUIDE-POLE + TYPICAL FITTINGS
,£>
o
E
a:
a
»—
o
en
t/)
o
_i
o
z
F
UJ
:*:
o
UJ
Q
<
O
4-000"
3000 _,_
2000-
1000-4-
-EFRT 10mph SLOTTED GUIDE-POLE W/ GASKETED COVER
+ TYPICAL FITTINGS
• IFRT, COLUMN-SUPPORTED FIXED ROOF, BOLTED DECK,
TYPICAL FITTINGS
APPROXIMATE REDUCTION IN FITTING LOSS FACTOR BY
COVERING AN EFRT WITH A SELF-SUPPORTING FIXED ROOF
•EFRT - W/ TYPICAL FITTINGS O 10mph
-*— EFRT - W/ SLOTTED GUIDE POLE + TYPICAL FITTINGS O Zmph1
-IFRT - SS FIXED ROOF. WELDED DECK. SLOTTED GUIDE POLE1
•IFRT - SS FIXED ROOF, WELDED DECK, TYPICAL FITTINGS 2
-EFRT - W/ TYPICAL FITTINGS O 2mph 2
100'*
150'*
1.2
TANK DIAMETER (ft)
HIERARCHY OF EQUIPMENT OPTIONS
FITTINGS & DECK SEAMS
FIGURE 1
ALTERNATE APPROACHES TO EFRT CONVERTED TO IFRT BY
COVERING WITH A SELF-SUPPORTING FIXED ROOF. API IS
CURRENTLY REVIEWING FITTING FACTOR DATA TO CLARIFY
THIS SCENARIO.
NOTE: FITTING SCENARIOS ARE TAKEN AS THE TYPICALS
DESCRIBED IN API PUBLICATIONS 2517 AND 2519 UNLESS
NOTED OTHERWISE.
-------
CHEMICAL
MANUFACTURERS
ASSOCIATION
STATEMENT OF
TERRI RANGANATH
ON BEHALF OF
THE CHEMICAL MANUFACTURERS ASSOCIATION
BEFORE THE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
ON THE
CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM
VOLATILE ORGANIC LIQUID STORAGE IN FLOATING AND
FIXED ROOF TANKS CONTROL TECHNIQUES GUIDANCE DOCUMENT
NOVEMBER 21, 1991
JL >
2501 M Street, NW 202-887-1100
Washington, D.C. 20037 Telex 89617 (CMA WSH)
-------
CHEMICAL MANUFACTURERS ASSOCIATION
TESTIMONY BEFORE THE NATIONAL AIR POLLUTION CONTROL
TECHNIQUES ADVISORY COMMITTEE ON THE
CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM
VOLATILE ORGANIC LIQUID STORAGE IN FLOATING AND
FIXED ROOF TANKS CONTROL TECHNIQUES GUIDANCE DOCUMENT
My name is Terri Ranganath. I am air quality engineer for E.I. du
Pont de Nemours and Company. I am speaking to you today on behalf of
the Chemical Manufacturers Association (CMA) where I serve as the work
group leader for the New Source Performance Standards/Control
Technology Work Group. CMA is a nonprofit trade association whose
member companies represent over 90 percent of the production capacity
of basic industrial chemicals in the United States. We are pleased to
have this opportunity to present our views to the National Air
Pollution Control Techniques Advisory Committee.
CMA appreciates the statutory requirements for controlling
volatile organic compound (VOC) emissions and the requirement that
ozone nonattainment areas be regulated by reasonably available control
technology (RACT) standards. Because they form the bases for RACT
standards, CTG's must be documents of high technical quality.
At a minimum, CTG's should accurately describe the types of
facilities that will be affected by RACT standards. CMA, however, does
not believe that the "presumptive norm" described in the CTG document
for storage tanks accurately describes the types of volatile organic
liquid (VOL) storage vessels that are commonly in use by the vast
majority of the chemical industry. The applications in the CTG were
based primarily upon model tanks and model liquids generally employed
by the petroleum industry and can not be readily extended to chemical
facilities without consideration for the unique components of the
industry. Therefore, CMA believes that the information contained In
the CTG does not have broad based applicability across the chemical
industry.
Also, while the CTG has broadly defined the types of facilities
which will be subject to the RACT standards, the document does not
clearly establish the goals or the applicability parameters. CMA
believes that both issues need to be definitively addressed prior to
publication of final guidance document to avoid any confusion on the
part of the regulated community.
CMA has several recommendations regarding the content of the
storage tank CTG and the approach for defining what is RACT for sources
of VOC's from liquid storage tanks.
-------
The Applicability Parameters and Goals of the CTG Are Not Clearly
Defined
In explaining what will be considered an affected source for the
purposes of this particular CTG, the document allows for the state
regulatory agency to define the specific source or "affected tank"
which will be covered by RACT. The CTG also suggests that the state
agency define vapor pressure and tank applicability ranges for each
type of tank. While CMA supports this basic premise, we believe that
states require guidance in setting vapor pressure cut-offs for RACT
applicability. Further, EPA needs to clearly define for state agencies
the scope of this CTG and its relationship to previously published RACT
standards.
The CTG, as presently written, does not clearly define for state
agencies the scope of this guidance. Nor does it clearly define its
relationship to previously published control standards. Environmental
managers will be faced with the question of whether the intended
purpose of the CTG is to incorporate the two previously published CTG's
and three NSPS documents, or to merely cover facilities not addressed
in these documents. The confusion could lead facilities to duplicate
their efforts unnecessarily. The intention of the CTG needs to be
stated precisely and directly in order to avoid such an outcome.
The CTG also needs to establish parameters for vapor pressure
cut-offs. The CTG suggests that state agencies define vapor pressure
and applicability range for each type of storage tank. While CMA
supports this premise, we believe that RACT standards should issue
guidelines for setting vapor pressure cut-offs. The vapor pressure
baseline discussed does not adequately consider low volatility liquids
such as monomers like styrene, which can polymerize and cause floating
roof tanks to fail and not operate as a control device. Establishing
cut-offs avoids setting levels of control which result in diminishing
returns, both incrementally and economically.
The CTG Inadequately Addresses Tanks with a Storage Capacity of Less
Than 40.000 Gallons
Throughout the CTG, the EPA applies what is defined as the
"presumptive norm" for RACT to tanks with volume and vapor pressure
cut-offs of 40,000 gallons and 1.5 psia. This "norm" and all the
accompanying estimations were based on the petroleum industry. While
there exists some similarities between the petroleum and chemical
industries, the two do not parallel one another closely enough for the
standards described in the CTG to serve as an accurate reflection of
what may be achievable by the chemical industry.
EPA also does not consider or adequately address tanks with a
storage capacity of less than 40,000 gallons. Many of the tanks
utilized in the chemical industry are not 40,000 gallons or larger as
the EPA has assumed in the CTG. EPA also erroneously assumes that
-; 1~1
^ t~> ' L
-------
horizontal tanks generally have a capacity of less than 20,000
gallons. The CTG states that "... most storage tanks below 20,000
gallons are horizontal rather than vertical tanks and a large
percentage of these tanks are also underground...". Across the
chemical industry vertical tanks are operated which have capacities of
less 20,000 gallons and there are numerous horizontal tanks with
capacities above 20,000 gallons. Further, based on this incorrect
assumption, the CTG document neglects to include any emission profiles
for tanks with capacities smaller than 20,000 gallons.
In addressing tanks with capacities of 20,000 to 40,000 gallons,
the CTG considers only one vapor pressure and two turnover rates. CMA
recommends that the EPA expand the emission profiles to the full range
of vapor pressures discussed in the CTG document, as well as to tanks
with capacities less than 20,000 gallons. Also, smaller tanks usually
have a higher turnover rate than two.
The CTG Overestimates the Control Efficiency of Internal Floating
Roofs
Throughout the CTG, the equipment options and the estimated
control efficiencies described are again, based on the petroleum
industry, rather than the chemical industry. This basis for evaluating
the effectiveness of the control techniques are inappropriate when one
considers expanding the efficiencies to process units which are unique
to the chemical industry.
In estimating the rate of emissions from internal floating roof
tanks, the CTG acknowledges several factors, including type of roof and
seal selected, number of turnovers, tank volume and liquid type, will
affect the final amount of emission reductions achieved by the model
fixed roof tank. Based on these factors, all of which were designed
with petroleum liquids as the baseline, the CTG estimates that a
facility can realize a reduction in emissions of 69 to 98 percent.
CMA believes that the extrapolation of so many factors is
inappropriate and recommends that the CTG be developed which more
accurately reflects the percent reductions achievable by actual
chemical facilities.
The GTG Offers Limited Flexibility in Terms of Technical Alternatives
The CTG document examines a limited number of control technologies
and, in fact, fails to consider technologies such as tank insulation
and submerged fill that are widely used by chemical facilities to
reduce emissions. The CTG offers only one equipment standard (internal
floating roofs) and only one stringent control option (98 percent
control) as acceptable control technologies for 20,000 to 40,000 gallon
tanks. In effect, this limited flexibility discourages the development
of technically innovative control options facilities would consider
-------
when examining compliance measures. Additional flexibility is needed
since neither an internal floating roof, nor thermal combustion are
realistic controls for some chemical industry systems.
The CTG also foregoes any evaluation of control options for tanks
with capacities less than 20,000 gallons except for the installation of
a condenser, with a required control efficiency of 90 percent. The CTG
states that this was the only control option examined because most
storage tanks below 20,000 gallons are horizontal tanks, and unsuitable
for internal floating roofs. As stated elsewhere in our comments, many
tanks with capacities below 20,000 gallons are vertical systems. While
we appreciate EPA addressing an alternative technology, the CTG as
written does not consider the condenser acceptable RACT. By promoting
the use of condensers in these tanks, the designated 98 percent control
level will not be achieved. In addition, CMA believes the 90 percent
control level is presumptive. EPA should acknowledge that condensers
operate at a range of control levels dependent on the system.
Further, many facilities are currently examining control measures
which will achieve a 90-95 percent control rate of VOC emissions.
However, due to the lack of flexibility in control options implied by
the CTG document, such alternative control efficiencies will be
by-passed by facilities because they could, in fact, be viewed as
improper controls by the EPA.
Internal floating roof control levels are also extremely dependent
on the system in which they operate. One control level does not
adequately address the possible range of controls available with an
internal floating roof. Throughout the CTG, a general equation must
have been used to calculate the control efficiency of internal floating
roofs for control of VOL's. That equation should be made part of the
CTG. CMA recommends that facilities be allowed to utilize the equation
to analyze the control efficiency of an internal floating roof on their
systems. The CTG should then allow the facility to meet or exceed that
control efficiency in a manner most suitable for the facility.
Therefore, a facility may use maximum flexibility to reasonably control
emissions in an effective, cost-effective manner.
The CTG Does Not Adequately Address the Interface Between RACT and
MACT Standards
CMA is concerned that RACT regulations will be required without
consideration for maximum achievable control technology (MACT)
standards which may apply to the same facility. The two sets of
standards could potentially create duplicative, possibly inconsistent,
regulations under the one regime. The inconsistency which may result
could create difficulties in administration and enforcement, including
overlapping requirements, unclear jurisdiction and general confusion.
This problem could be further exacerbated because of different
enforcement authorities and different administrative implementation
programs.
-------
Both standards are clearly defined in the statute, with RACT not
being more stringent than MACT. We believe that facilities which have
complied with MACT should be deemed in compliance for purposes of RACT,
CMA urges authorities to be careful in their establishment and
designation of RACT standards and remain cognizant of the possibility
which exists for RACT, in effect, from becoming MACT.
I thank the committee for the opportunity to testify on behalf of
CMA. We are willing to offer assistance to EPA in its development of
the CTG and look forward to working with the Agency. At this point I
would be glad to answer any questions.
-------
C: DISCUSSION
Following the presentations by the EPA, Chemical Manufacturers
Association, and Conservatek, Mr. Bruce Jordan opened the floor
to questions and comments from the NAPCTAC members. The short
discussion following the presentations and responses to questions
are summarized in the following paragraphs.
Ms. Mclntire asked if tanks with volumes less than 40,000 gallons
would be controlled by RACT. Ms. Susan Wyatt of CPB/EPA
responded that the Agency was still examining possible volume and
vapor pressure cutoff points to determine the applicability of
RACT.
Ms. Mclntire also asked what emission reduction and cost
effectiveness was being assigned to IFRs. Mr. Morris responded
that while the emissions reductions vary, typically IFRs are
about 95% effective in reducing emissions from fixed-roof tanks.
Also while the cost effectiveness would vary, about $300 - $400
per megagram was typical for controlling fixed roof tank, with
the installation of an IFR.
Mr. Taranto asked if RACT would be required equipment.
Mr. Morris stated that RACT would be based on requiring specific
equipment, but that RACT would allow for equivalent equipment and
would also allow for vapor control systems that are 95% effective
in reducing emissions.
Mr. Dennision agreed that RACT should be required equipment, but
suggested that EPA consider bifurcating RACT based on industry
type (i.e., chemical industry and petroleum industry)
Ms. Mclntire commented that while her company (Eastman Chemicals)
has numerous tanks, they do not use IFRs. She had discussed
control of tanks with company personnel, and they agreed that
requiring IFRs was appropriate if an allowance for alternative
control techniques was a specific component of RACT. Mr. Morris
responded that in all cases RACT would allow for vapor control
devices to be substituted for the installation of the IFR.
O
-------
D. CORRESPONDENCE
* O
•
-------
PETREX Inc.
2343 Dorcon Road • P. 0. Box 907 • Warren, Pennsylvania 16365
Telephone 814-723-2050 • Telefax 814-723-2055 • Telex 510 101 3005
November 12, 1991
United States Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 27711
Attention: Mr. Bruce C. Jordan
Director
Emission Standards Division
Subject: NAPCTAC Meeting Novembr 19-21, 1991
CTG for Volatile Organic Liquids
Gentlemen:
This letter transmits our comments to the draft CTG for volatile organic
liquid.
Our firm has been in the business of designing, manufacturing and installing
internal floating roofs for nineteen years. The contributors of these
comments have at least 30 years experience each in the tank, floating roof and
seal industry.
We think the CTG is well written and covers its topic well. There are however
certain paragraphs and figures that we recommend be changed. We desire that
the CTG fairly represent the current state of the art, and government regula-
tion and be technically correct. We also believe that the document should be
as generic as possible. Some of our comments are merely editorial.
These comments have also been given to the API Committee on Evaporation Loss
Measurement.
We expect to attend the session on November 21, 1991, regarding the subject
CTG.
Very truly yours,
PETREX, Inc.
W. L. Wagner, P.E,
President
WLW/br
P.S. If you have questions please call me or Bill Blumquist.
-------
PETREX Inc.
2349 Dorcon Road • P. O. Box 907 • Warren, Pennsylvania 16365
Telephone 814-723-2050 • Telefax 814-723-2055 • Telex 510 101 3005
November 7, 1991
Subject: USEPA
Control Technique Guideline
"Control of V.O.C. Emissions from V.O.L.
Storage in Floating and Fixed Roof Tanks"
Our comments on this document are as follows:
Page 2-3 Aluminum sandwich panel contact type internal floating roofs do
Para 2.2.3 not share the design feature of having a mechanical seam
consisting of overlapping alumium sheets bolted together with
clamping bars. Evaporation loss tests, made and submitted to
API, on a mechanical seal consisting of a gasket cast in place
between two mating extrusions show a much lower seam loss.
Pg. 2-4 Is it common practice to use P/V vents and flame arresters
Para. 2.2.3 to ventilate an IFR tank?
Pg. 2-4 Horizontal tanks, above or below ground, should be referred to
Para. 2.2.4 and eliminated from discussion. Delete comments on
composition, proportions, etc. Delete illustrations Fig. 2-5
and Fig. 2-6.
Pg. 2-5 Wiper type seals are also used on EFR's. Add to description
Para. 2.3.1 and Fig. 2-7.
Pg. 2-5 The discussion and illustrations concerning EFR tank seals
Para. 2.3 should be limited to mechanical shoe seals, liquid mounted
seals, vapor mounted seals and secondary seals. The use of a
vapor mounted seal with a weather shield is not permitted and
should not be shown. No wiper type primary seals are shown.
Pg. 2-6 The height of the mechanical shoe seal is not specified in
Para. 2.3.1.1 various EPA standards, such as in the Federal Register, 40 CFR
Part 60 Subpart Y Paragraph 61.271 (a) (1) (iii) and 40 CFR
Part 60 Subpart Kb, Paragraph 60.1126 (a) (1) (ii) (C). This
is not definitive since the term "mechanical shoe seal" alone
does not guarantee the performance desired. The basis, we
believe for the mechanical shoe seal emissions is a test
conducted some years ago by CBI in California using a 30 inch
plus shoe. Shoes of lesser length could not provide the same
emission but could still qualify as a mechanical seal. API
2519 equates a mechanical shoe seal to a liquid mounted seal
but with no limits to shoe length. Later in this document Pg.
7-6, Para. 7.5 shoe height is mentioned.
-------
USEPA
Control Technique Guideline
Page two
pg. 2-7 It is highly doubtful that the "wiping action" of a secondary
Para. 2.3.1.4 seal aids in reducing evaporation loss. Any "wiped" liquid
would be above the primary seal.
Pg. 2-7 A shoe mounted seal extending from the top of the shoe to the
Para. 2.3.1.4 tank shell is not a secondary seal. This and Fig. 2-9 are
wrong. See definition Pg. 2-6, Para. 2.3.1.4.
Pg. 2-7 This implies that a weather shield may be used over a secondary
Para. 2.3.1.4 seal. A more common practice is to combine the functions of
secondary seal and a weather shield.
Pg. 2-8 Reference is made to Fig. 2-10 b. This would be better
Para. 2.3.2.1 illustrated if the liquid level were shown.
Pg. 2-9 In the comments on a shingle type seal the language is
Para. 2.3.2.2 misleading. If a shingle type construction does not provide a
continuous vapor barrier (as used in weather shields) then it
should not be considered a wiper seal.
Pg. 2-9 Wiper seals using a "blade" construction should not only be
Para. 2.3.2.2 joined but sealed. Simple, mechanical joining may not be vapor
tight.
Pg. 2-9 Current EPA regulations require the use of a single, liquid
Para. 2.3.2.3 mounted seal or a vapor mounted primary seal plus a secondary
seal. The description in this paragraph and the illustrations
in Fig. 2-10 and 2-11 do not reflect this requirement.
Pg. 2-9 The statement "Secondary seals are not commonly used on IFR
Para. 2.3.2.3 tanks", is wrong.
Pg. 2-11 The primary purpose of an IFR vent or as described, "Vacuum
Para. 2.4.1.5 Breaker" is to vent incoming or outgoing air or vapor through
the IFR when filling or emptying. The poppet type described
and illustrated is strictly mechanical. Other types operating
on pressure/vacuum or liquid level are also used.
Pg. 2-13 Why is the trapped vapor space under a mechanical shoe seal
Para. 2.4.1.8 ventilated and not the vapor space under any other type of
vapor mounted seal?
Pg. 2-13 Reference to Fig 2-3 is wrong.
Para. 2.4.2.1
Pg. 3-1 These are a recapitulation of AP 42 Para. 4.3 and API ppj
Para. 3.1 and 3.2 2519 and seem unnecessary. _j
DO
m
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USEPA
Control Technique Guideline
Page three
Pg. 3-29 ' This is an excellent summary of regulations.
Para 3.3
Pg. 3-32 Some reference shold be made to support Subpart Kb, as it is
Para. 3.3.5 often referred to as such.
Pg. 3-33 Reference to the baseline control method as being a low cost,
Para. 3.3.6 non-contact IFR is wrong. Depending on the diameter a non-
contact IFR may cost more. Also the use of a single vapor
mounted seal is not permitted.
Pg. 3-34 It may be "picky" but when referring to RVP and then "vapor
Para. 3.4 pressure", TVP should be used.
Pg. 4-5 What is the basis for an IFR installation in a fixed roof tank
Para. 4.3 having an emission reduction of only 69%?
Pg. 4-5 What establishes the non-contact, bolted aluminum IFR as the
Para. 4.3 most basic? Why is the use of a single vapor mounted seal
mentioned when it is not permitted?
Pg. 4-17 When retrofitting any IFR with liquid mounted
Para 4.6.2 and 4.6.3 or secondary seals additional buoyancy and storage
loss must be considered. This may be especially
important with non-contact IFR's.
Pg. 4-18 Obviously, emissions from liquid stored in a fiberglass fixed
Para. 4.7 roof tank could be controlled by the use of a fiberglass IFR.
Pg. 5-3 This discussion on the relative effect of turnover Para.
5.2.1 rate and emissions from fixed roof tank vs. IFR tanks ignores
the same relative effect of breathing losses.
Pg. 5-5 This states that the control options for IFR tanks are to
Para. 5.3 install IFR's??
Pg. 5-6 In considering the secondary impact emissions when emptying,
Para. 5.3.2.1 cleaning and degassing an IFR tank a large source of emissions
has been ignored. The large volume of hydrocarbon saturated
trapped vapor under a non-contact IFR makes a large
contribution.
Pg. 5-7 To suggest that a secondary seal may be added to an existing
Para. 5.4.2.1 EFR tank with the tank in service may be misleading
economically and safety wise. Not all such floating roofs have "U
a readily available flange to which a secondary seal can be [fl
bolted. Many company safety rules will not permit such work. -i{
33
m
*
-------
USEPA
Control Technique Guideline
Page four
Pg. 6-3
Para. 6.2
Pg. 7-3
Para. 7.2
Pg. 7-4
Para. 7.5
Pg. 7-6
Para. 7.5
Using 10 years as expected equipment life may be inaccurate.
A vapor mounted seal does not have to be foam filled,
In this paragraph the seal gap criteria appear only following
the paragraph concerning testing for EFR tanks. Is the intent
to have these criteria apply only to EFR tanks?
N£ holes, tears or other openings in the shoe, seal fabric or
seal envelope is an absolute statement. Can this be quantified
as in the gap criteria stated above?
General commment:
General comment:
Table 4-1, Pg. 4-2 lists Control Options 1 through 6,
later reference in Par'a 5.2, Pg. 5-1 is to Control Options
1 through 5. Description of these control options in
Table 4-1, Pg. 4-2 mentions contact or non-contact for the
first four options (2-5) and no mention of this for Option
6. Later on Pg. 5-21, Table 5-1 Control Option V (most
effective) is described as a contact type IFR.
Reading the information presented in Table 3-2, Pg. 3-7;
Table 4-2, Pg. 4-3; Table 4-6, Pg. 4-13 and the general
discussion on EFR tanks and gap criteria in Para. 7-5,
Pgs. 7-5, 7-6 and 7-7 leaves the reader confused about the
use of mechanical shoe seals in riveted tanks. Is it
common practice? Is it acceptable? What are emissions?
We will be pleased to discuss these comments with you,
m
1211
m
x
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State of Wisconsin \ DEPARTMENT OF NATURAL RESOURCES
101 Saudi Wctntcr Street
P.O. Box 7921
Madison, Wisconsin 53707-7921
Canon D. Besadny TELEPHONE 608-266-2621
Secretary TELEFAX608-267-3579
TDD 608-267-6897
November 14, 1991 IN REPLY REFER TO: 4530
Bruce C. Jordan, Director
Emissions Standards Division (MD-13)
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
SUBJECT: Comments For Draft CTG Document Control of Volatile
Organic Compound Emissions from Batch Processes
Dear Mr. Jordan:
My name is Steve Jorgensen, and I am an environmental engineer with the
Wisconsin Dept. of Natural Resources, Bureau of Air Management. I've skimmed
over the draft CTG document entitled "Control of Volatile Organic Compound
Emissions from Batch Processes". As a result, I have several comments
concerning Chapter 6 and Appendix F, and will address them in chronological
order.
Section 6.3.3.1 Single Stream Versus Aggregation.
Sentence 1 of paragraph 2 reads, ... and 3/4 of the maximum flow
rates from each process vent would be used as the maximum
instantaneous flow rate.
Question: Can the reasoning behind using this ratio (3/4) be
included in paragraph 2? What about using the ratio
of 1/1? Such a ratio would take into account the true
maximum (possible) instantaneous flow rate.
Section 6.4.1 Industries Covered
Emissions with durations of under 7,800 hours per year, for the
applicable SIC Codes, are assumed to be the result of batch
processes. Model batch processes described in Tables 6-7 through
6-10, however, set a plant operation limit of 275 days per year
(24 hour operation per day for 275 days corresponds to 6600 hours
per year).
Question: Can the reasoning for this apparent difference in
bases be included in the section?
•Y f)
JL
-------
Section 6.4.3 Baseline Assumptions/Extrapolations
Question: What is the exact definition of baseline emissions?
My interpretation from this section is that it represents the
remaining uncontrolled emissions from SIC Code 2834
(pharmaceutical preparations) batch processes after pharmaceutical
CTG controls have been applied. Section 6.4.4, paragraph 2,
sentence 3, however, suggests to me that baseline emissions
include (in addition to those described above) the uncontrolled
emissions from the other 6 applicable SIC Codes.
Section 6.4.4 Reductions
The notation used to describe RACT options here appears to be
incomplete. In addition to Roman numerals and capital letters,
numbers have been included elsewhere. For Example, the first RACT
option listed in Table 6-1 is: IA.1,5,9.
Question: What is the significance of the numbers used in the
RACT option descriptions?
My remaining comments for Chapter 6 and Appendix F are addressed on enclosed
copies of Figure 6-1; Tables 6-1,3,11, and 16; and page F-l.
The material covered in Section 6.4.2 through the end of the chapter
(including many of the figures and tables) was very difficult for me to
follow. I still don't understand the RACT VOC options that are being
proposed, or their associated costs. For these reasons, I cannot make an
overall comment on the validity of the CTG document.
For your information, I have included the number of known facilities by
applicable SIC Code in Wisconsin. These facilities, located in non-marginal
nonattainment areas, are listed below.
SIC Code No. of Facilities
2821 9
2834 11
2851 18
2861 2
2865 5
2869 3
2879 7
A breakdown of plant size (by employee number as in Table 6-15) would be
available upon request. [ Note: The total number of facilities in Wisconsin
within each SIC Code category is slightly larger. In addition, Wisconsin uses
RACT guidelines to set VOC limits statewide; exemptions to these limits are
available for specific circumstances. ]
o
-------
Sincerely,
Steven M. Jor.gensen, Engineer
Compliance Section
Bureau of Air Management
Wisconsin Dept. of Natural Resources
cc: Dean Packard AM/10
Jon Heinrich - AM/10
Dale Ziege AM/10
Enclosures: Figure 6-1; Tables 6-1,3,11, and 16; and p. F-l
o
-------
Cost of Control by Thermal Incineration
For VOC Concentration of 10000 ppm
(T = 1600F. HR = 70%)
30000
28000
26000
24000
27000
70000
j- • - 18000
to
l^» ^16000
*xJ 1 <~t
ct' _ 14000
Mo
** ^12000
0
10000
8000
6000
4000
2000
0
\
\
\
\
\ 1 ^
\ I /o
\ fjr~
\Ci,
\
.
^
^J^X^i
InL^M K*>
* ^^ ^k ^ ^
$ ^-l^w'^
& $ > Ic
* I.*''
10
On Slita* Ptictnloi)t
100
uw
1000
UQIIIUB V t t\\ I I o • Halt •, i I n
5 10
r-r ,
10000
I . I
I 0 0 0 IIII
S A * 2,
20 50 1pO
li
5t 4tsi
-------
Table 6-1. Summary of RACT option exemptions
PACT OPTION/
VOLATILITY LEVEL
(CONTROL EFFICIENCY)
I A. 1,5,9
(98%)
EXEMPTIONS for
all levels of volatility
IA.2,6,10
(98%)
IA.3,7,11
3/o)
IA.4,9,12
(98%)
LOW VOLATILITY SOLVENTS:
if MF < 10.000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MF0.1508M308 - NO CONTROL
MODERATE VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.1062)-961.5 - NO CONTROL
HIGH VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.075)-100 - NO CONTROL
LOW VOLATILITY SOLVENTS:
if MF < 10,000 tos/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.1537)-1527 - NO CONTROL
MODERATE VOLATILITY SOLVENTS:
i MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.0636)-772.7 - NO CONTROL
HIGH VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.055)-450 - NO CONTROL
LOW VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF>= 10,000 bs/yr AND FR >= (MP0.0855)-1409 - NO CONTROL
MODERATE VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.0491)-881.8 - NO CONTROL
HIGH VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.044)-100 - NO CONTROL
LOW VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.0475)-1563 - NO CONTROL
MODERATE VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.0248)-856.3 - NO CONTROL
HIGH VOLATILITY SOLVENTS:
if MF < 10,000 bs/yr - NO CONTROL
if MF >= 10,000 bs/yr AND FR >= (MP0.017)-10 - NO CONTROL
-19
* *> 1 P
J_4,< 1.»<
-------
Table 6-2. Percentage of emissions from batch processes
SIC
CODE
2821
2834
2851
2861
2865
2869
2879
SIC DESCRIPTION
Plastics materials and resins
Pharmaceutical preparations
Paints and allied products
Gum and wood chemicals
Cyclic crudes and intermediates
Industrial organic chemicals
Agricultural chemicals
<7800
(hrs/yr)
14,396
8,432
6,006
2,287
223
17,060
92
>0
(hrs/yr) "
124,547
15,459
11,998
20,415
8,365
173,167
3,912
"T " " ' ' "
j
|
% BATCH
; 12%
55%
50%
11%
3%
10%
2%
NOTE: Emissions data was obtained from AIRS facility subset data base search
CO
Ch
NJ
NJ
-------
- /n Idf&V /tt£fc frl •Ty? 6f /6/ /
Table 6-3. Emission stream characteristics for solvent reaction model process w/ almoiphe^dryer
#of
unit ops per Calculation for 1
model batch unit operation
9.25 Displacement
(2000-gallon vessel)
TOTAL DISPLACEMENT EMISSIONS
(Ibs-batch/year)
Emission
Stream
VOC
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOIJVTIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
Row Rate
(acfm)
18
18
18
Temp.
(DegQ
20
20
20
Duration
(min)
15
15
15
VOC
(vol %)
0.6%
12.6%
57.9%
Emissions
Ib/event
0.29
2.82
30.02
Emissions
Ibs/batch
(Motel)
2.64
26.08
277.66
NO CONTROL
Mass Flux
Ibs/batch
2.64
26.08
277.66
727.02
7172.28
76355.65
CPC (Note 2)
Mass Flux
Ibs/balch
2.64
7.82
30.54
727.02
2151.68
8399.12
REACTORS
1
M
ro
k=S
CS
1
1
Charging w/purge
1 leal -up w/purge
Reaction w^jurgc
Empty Reactor Purging
TOTAL REACTOR EMISSIONS
(Ibs-batch/year)
LOWVOIATIUTY
MODERATE VOIJkTIUTY
HIGH VOLATILITY
LOW V01.ATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOI.ATIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOLATIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
LOW VOIJiTIUTY
MODERATE VOLATILITY
HIGH VOLATILITY
30
30
30
30
30
30
150
150
150
100
100
100
20
20
20
20 to 30
20 to 30
20 to 30
37
37
37
20
20
20
15
15
15
5
5
5
3
3
3
1
1
1
0.1%
3.1%
14.5%
0.5%
7.5%
27.2%
0.1%
2.7%
12.8%
0.12
1.17
12.51
0.1
0.52
5.13
0.39
2.65
22.19
0.06
0.5
1.5
0.12
1.17
12.51
0.10
0.52
5.13
0.39
2.65
22.19
0.06
0.50
1.50
0.12
1.17
12.51
0.10
0.52
5.13
0.39
2.65
22.19
0.06
0.50
1.50
184.08
1332.65
11365.50
0.12
1.17
5.63
0.10
0,52
1.85
0.39
1.35
5.33
0.06
0.32
1.26
184.08
925.91
3866.79
/• f /
/n4
ri
.
r
A
F
n**t ? ?-
-------
Table 6-11. Solvent reaction model plant w/ atmospheric dryer
MODEL PLANT EMISSIONS(lbs/yr)
SMALL/NC
LOW VOLATILITY 333.236
MODERATE VOLATILITY 36U50
HIGH VOLATILITY 749367
SMALL/CPC
36.236
44,621
86,603
MEDIUM/NC
LOW VOLATILITY 1,109.676
MODERATE VOLATILITY 1203296
HIGH VOLATILITY 2,495393
MEDIUM/CPC
120,666
148,590
288388
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
LARGE/NC
3332J60
3,613.502
7.493,673
LARGE/CPC
362360
446,215
866.031
MODEL PLANT EMISSIONS(tons/yr)
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
SMALL/NC
166.62
180.68
374.68
SMALL/CPC
18.12
2231
4330
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
MEDIUM/NC
554.84
601.65
1247.70
MEDIUM/CPC
6033
74.29
144.19
LOW VOLATILITY
MODERATE VOLATILITY
HIGH VOLATILITY
LARGE/NC
1666.18
1806.75
3746.84
LARGE/CPC
181.18
223.11
433.02
NC = No Control
CPC = Current Pharmaceutical Control
1. For surface condensers on sources emitting:
-25C for VP>300mmHg
-ISCfor 150
-------
kttf& ji&f &
OPTION
UNCONTSOLLED BASUJNH
DESCRIPTION EMISSIONS EMISSIONS
OPOKTION (MftV) (Mft^r)
& ^
AGGREGATED PROCESS VENTS WITH PR£SSURE TESTING AND WITHOUT MODE!. IT ANT
1 LJAJ.fl.12 SfifccttstroJo/iiprpted 187 .OH WJ7I
fgaeem verm llui we
DO* cicmpt per flA.4 ,8,12
2 IIU.4.8.12 90* control of •sprtiird 1 87.0*4 69,372
proueu vrni* dul *JT
ixdcietDpt per HB.-4.8.I2
) DC4.8.12 93% control of Hpvp*d 187,0*4 64.371
fTUueu vcnU dm we
DO! ciempt per IIC.4.8,1 2
INDIVIDUAL PROCESS VENTS WTT1I PRESSURE TESTING AND WTTHOUT MODEL Pl^NT 4
4 LA/4,8,12 98% ccrwol of mdividu&l 1B7.0*4 69,57}
pT -:o
^RO> ptOCCU VCQU (hll Ire
"^-^^^ o« curapt per IC.4.8,12
AOX3RECATED PROCESS VENTS WTTII PRESSURE TESTING AND MODEL PI ANT 4
7 IU.4.B.I2 90*eoom>lol.gpT|iicd 221.236 1111.794
pjaueu vcnli lh« ur
DOlcuinplpcrIB.4.8,12
PRESSURE TESTING ALONE WITII MODEL PLANT 4
t PT2 Ojidon of intuiting •
1.419 7.4W
HUl /\
>. _ NA^HONWIDE - NATIOfWfDE - . — — - AVBRACC
EAIISSION EMISSION NATIONAL COST COST PHK% ))62.911.207 S8.B92 8*
I29.4M 19,1)9 6«4 S7* 194.911.746 52.41) U'l
l)l.7a 40,1)0 7(r4 58* IJ41.798.449 J8.525 B-l
:ilj<)6 D.7I9 VM 81* 1IM.JI9.J4) 1I.8IU ml.
6S86 6886 971 92* 112.997.042 11.887 N/A
* Ntiicviwkk tmiuioo reduclion i*iuin bucluv. Cdi«tto P, «u cftlculiled ium| ilic folio* mj f.
P-^D-t2,3lO)*(E/C)farRow« 1-7 ^
rtua fcrmul* doea i»4 kllow the reiklud «miMK»u from ptumuoeuliul f<
' lo be iSjrthef rtduced by i|iplying tic RACT option to iheK cmtuioru.
* Mokl |^4nt 4 re|>r««cni4 painl «mJ vvnuli nunuficiunn
ys- (6'/s.^td) * fc/4)
-------
CO ^
CO 45
LU T3
2 C
cd
IL
II,
O
MASS FLUX = 10000 Ibs/yr
LOW VOLATILITY (Toluene), CCE = 98%
A-
ou~
Ofi-
oU
20-
15-
1O-
I U
5_
. j . ^ — _ _^ j
CIA& rVff$)A4>M &t£^ /?<%££. Ij 1
ct V0(
-------
American Petroleum Institute
1220 L Street, Northwest
Washington, D.C. 20005
202-682-8145
James K. Walters
Director, Measurement Coordination
November 18, 1991
RE: 300
Mr. Bruce C. Jordan
Director, Emission Standards Division
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
Dear Mr. Jordan:
Attached please find the comments of the American Petroleum Institute (API) on the draft EPA
Control Technique Guideline, "Control of Volatile Organic Compound Emissions from Volatile
Organic Liquid Storage in Floating and Fixed Roof Tanks", as requested in your letter dated
October 4, 1991.
API requests that these comments be included as part of the official record of the EPA National
Air Pollution Control Techniques Advisory Committee meeting being held on November 19-21,
1991.
If you have any questions on these comments, please contact me.
Very truly yours,
Attachment
cc: CELM Members
D. Wolter, D. Arrick
Internal Mailing List
T 9 O0>
JL i~> u (^
An equal opportunity employer
-------
COMMENTS OF THE AMERICAN PETROLEUM INSTITUTE
ON
THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
DRAFT CONTROL TECHNIQUE GUIDELINE
'CONTROL OF VOLATILE ORGANIC COMPOUND EMISSIONS FROM
VOLATILE ORGANIC LIQUID STORAGE IN
FLOATING AND FIXED ROOF TANKS"
NOVEMBER 18, 1991
INTRODUCTION
The American Petroleum Institute (API) is pleased to comment on the EPA's draft
Control Technique Guideline, "Control of Volatile Organic Compound Emissions from Volatile
Organic Liquid Storage in Floating and Fixed Roof Tanks" (herein referred to as the "CTG").
API represents over 250 companies involved in all aspects of the oil and gas industry, including
exploration, production, transportation, refining and marketing.
The EPA is to be commended on its preparation of the draft CTG. The document is very
comprehensive and many of the issues mentioned herein are complex. In order to thoroughly
address API's comments, API requests that a meeting with EPA be arranged, as provided for
in EPA's October 4, 1991 letter.
Also, API requests that the EPA strongly consider delaying the publication of the CTG
until the results of EPA's " 114" letter on tankage distributed to eight companies during the third
quarter of 1991 and the API fittings loss tests are available. These results could indicate that
revisions are needed to the draft CTG. If EPA must publish the CTG prior to receiving the
results, then EPA should be prepared to discuss (at the meeting mentioned above) ways to
incorporate the results into the CTG.
The API comments below are divided into General Comments and Specific Comments
(identified by section and page number).
GENERAL COMMENTS
1. API is pleased that the draft CTG has incorporated many of API's previous comments
and refers to and makes use of data, analysis and standards developed by API. API
would like to point out that the new API Publication 2518, "Evaporative Loss from
Fixed-Roof Tanks" is now available and a copy is included for EPA use. This new
document should be considered by EPA during the revisions of both the CTG and AP-42
for calculations dealing with fixed roof tanks.
1
-------
2. Most of the November 1983 API comments on the current CTG have been incorporated
into the 1991 draft CTG except the omission of self-supporting fixed roofs. The CTG
should recognize the retrofit of an external floating roof tank with a self-supporting fixed
roof as an equipment option. This point is discussed throughout the comments.
3. API recommends that, in light of the secondary waste generation, emissions, safety and
cost impacts, it is important to maintain the flexibility to perform seal upgrades at the
next scheduled tank maintenance period.
4. The effective dates for a few of the references to Subpart K are incorrect. The correct
effective dates are shown in the appropriate Specific Comments sections.
5. The draft CTG does not mention the exemption for tanks at drilling or production
facilities which are used prior to custody transfer. Also, there is no mention of the
inspection requirements for the roof seals, gaskets and membranes in all regulated
internal and external floating roof tanks.
6. The hierarchies suggested in Section 4.0, Control Techniques, are overly simplified.
There is apparently an assumption that the fittings scenario does not change appreciably
across the country. In actual practice, fittings options vary significantly and differences
in fittings scenarios could change the order of hierarchy. Notable examples are the
presence or absence of support columns for an internal floating roof tank and slotted
gauge poles for an external floating roof tank. API Publications 2517 and 2519 discuss
typical fittings scenarios. Further information on this is shown in Section 4.0 of the
Specific Comments.
7. In Section 6.0, the CTG should mention the time frame of the cost estimates and how
an adjustment for inflation (1991 dollars) is to be handled. Also, the cost effectiveness
data is shown as being calculated in dollars/megagram but it is really
dollars/megagram/year annualized over ten years. This is misleading and should be
clarified.
8. In Section 6.2, pg 6-2, API suggests the CTG be corrected to show the following
referenced cost data. The retrofit cost from CTG Reference 2 lists the price difference
for internal floating roof seals, liquid mounted vs. vapor mounted as $20 to $40 per
linear foot as opposed to $20 as stated in the CTG from Reference 1.
The data from Reference 2 indicates the retrofit cost of controlling internal floating roof
fittings is greater than $10,000 per tank, not the $600 stated in the CTG.
The installed cost of secondary seals is between $49 per foot and $90 per foot according
to Reference 2, as opposed to the $14 per foot stated. Some operating plant data
indicates that $90 per foot cost is more representative.
-------
9.
The retrofit cost to control the guide-pole fitting on an external floating roof tank is
$2604 to $3324 according to Reference 2, not $680 as in the CTG.
Considering discrepancies in the input data, some of which are mentioned above, API
suggests that the cost effectiveness analysis shown in Section 6.0 be evaluated more
closely. API will be addressing this issue in the immediate future and would like to meet
with EPA to discuss this analysis. API cannot endorse the draft cost effectiveness
analysis at this time.
An API contractor is reviewing fitting losses with the objective to develop improved
fitting factors. API invites EPA QA/QC review of the API planned test work. This
information should be available in late 1992 and should provide an improved technical
basis for evaluating fitting losses. It is advisable for the EPA to incorporate the resulting
data into the CTG.
SPECIFIC COMMENTS BY SECTION AND PAGE NUMBER
Section 2.2.1, pg 2-1
Section 2.2.3, pg 2-3
Section 2.2.3, pg 2-3
Section 2.2.3, pg 2-4
Last sentence, delete the word "all" and change the word
"prevent" to "reduce".
Add the following wording from AP-42 prior to beginning of first
full paragraph. "There are two basic types of internal floating roof
tanks, tanks in which the fixed roof is supported by vertical
columns within the tank, and tanks with a self-supporting fixed
roof and no internal support columns. Fixed roof tanks that have
been retrofitted to employ a floating deck are typically of the first
type, while external floating roof tanks typically have a self-
supporting roof when converted to an internal floating roof tank.
Tanks initially constructed with both a fixed roof and a floating
deck may be of either type."
Third full paragraph, aluminum sandwich panel contact-type
internal floating roofs do not share the design feature of having a
mechanical seam consisting of overlapping aluminum sheets bolted
together with clamping bars. Evaporation loss tests made by one
tank vendor on a mechanical seal consisting of a gasket cast in
place between two mating extrusions show a much lower seam
loss.
Last paragraph, it is not common practice to use pressure/vacuum
vents and flame arresters to ventilate an internal floating roof tank.
In fact, there is the potential to generate explosive atmospheres
within the tank and may violate safety standards.
-------
Section 2.3.1, pg 2-5
Section 2.3.1.1, pg 2-6
Section 2.3.1.5, pg 2-7
Section 2.3.2.3, pg 2-9
Section 2.3.2.3, pg 2-9
Section 2.4.1.5, pg 2-11
Section 2.4.1.6, pg 2-12
First paragraph, wiper-type seals are also used on external floating
roof tanks. Add to the description and to Figure 2-7.
The length of the mechanical shoe seal should not be specified
because there are many good quality mechanical shoe seals already
installed in compliance with regulations that did not previously
specify shoe length.
The height of the mechanical shoe is not specified in various EPA
standards, such as 40 CFR Part 60, Subpart Y, Para. 61.271
(a)(l)(iii) and 40 CFR Part 60, Subpart Kb, Para. 60.1126
(a)(l)(ii)(C). It would not be reasonable to require retrofits on
tanks that had working mechanical shoe seals already in place.
The basis for the mechanical shoe seal emissions is probably a test
conducted some years ago by CBI in California using a 30-inch
plus shoe. Shoes of lesser length could not provide the same
emission but could still qualify as a mechanical seal. API
Publication 2519 equates a mechanical shoe seal to a liquid-
mounted seal but with no limits to shoe length. Later in the
document, pg 7-6, para. 7.5, shoe height is mentioned.
This implies that a weather shield may be used over a secondary
seal. A more common practice is to combine the functions of a
secondary seal and a weather shield.
Current EPA regulations (Subpart Kb) require the use of a single,
liquid-mounted seal or a vapor-mounted primary seal plus a
secondary seal. The description in this paragraph and Figures 2-
10 and 2-11 do not reflect this requirement.
The last sentence states "Secondary seals are not commonly used
on internal floating roof tanks." This is incorrect for tanks now
covered by NSPS Kb.
The primary purpose of an internal floating roof vent or "Vacuum
Breaker" is to vent incoming or outgoing air or vapor through the
internal floating roof tank when filling or emptying. The poppet-
type described and illustrated is strictly mechanical. Other types
operating on pressure/vacuum or liquid level are also used.
Fifth sentence stating: "Open drainage systems can be used only
on double-deck floating roofs" is incorrect. Open drainage
systems are optional on open center deck roofs and are not
-------
Section 2.4.2.1, pg 2-13
Figure 2-7, pg 2-21
Figure 2-11, pg 2-25
Section 2.5, pg 2-32
Section 3.1/3.2, pg 3-1
Section 3.2.1, pg 3-1
Section 3.2.1, pg 3-2
Section 3.2.1, pg 3-2
Table 3-1, pg 3-3
Section 3.2.2, pg 3-4
uncommon. This is also incorrectly presented in API Publication
2517 on pages 41 and 42. Page 41 states that only double-deck
roofs have overflow roof drains and page 42 states that some
proprietary designs are available. These two statements are
contradictory.
First sentence, the reference to Figure 2-3 is incorrect. The
correct reference is to Figure 2-1.
The word "Shield" is misspelled in figures a, c and d.
The word "immersed" is misspelled.
The reference 1 for API Publication 2518 should be changed to
reflect the recent publication date of October 1991.
These are a recapitulation of AP 42, para. 4.3 and API 2519 and
seem unnecessary.
Add a sentence after the last complete sentence on this page
stating: "Alternatively, breathing losses from fixed roof tanks may
be calculated using the methods described in API Publication 2518,
revised October 1991."
Equation (3-2) should be changed to agree with the revised
equation in the new API 2518.
In description of "P", change "atmospheric" to "absolute".
The paint factor condition for medium gray on the shell and roof
is listed as 1.40 for good paint and 1.58 for poor paint. API
Publication 2518, First Edition, lists 1.46 for good paint. This
typographical error should be corrected.
API does not have a method for estimating evaporative losses from
horizontal tanks and cannot endorse the EPA method in the CTG.
However, based on the comments below and using the suggested
changes, the EPA method may constitute a rough or screening
mechanism.
The user is referred to emissions equations for fixed-roof tanks.
An equivalent diameter, De, is calculated on the length, L, of the
tank and the real (vertical) diameter, D, of the tank. The
equivalent diameter is then used in the AP-42 fixed-roof tank
-------
equations. This calculation method shown is overly simplistic and
tends to over-estimate the emissions. This method would be better
described as a screening method for estimating emissions.
There are two factors that contribute to the over-estimation. The
first is that the user is instructed to calculate the average vapor
space by multiplying the exposed area of the liquid half-full, using
the equivalent diameter, by one-half of the real diameter (for the
height value). This value will always be greater than the real
(default) average vapor space volume, which is one-half of the
tank volume.
The second is that the exposed area of the stored liquid varies with
the liquid height and is at its maximum when the tank is half-full.
When the liquid level rises or falls, the exposed area decreases.
Therefore, the effective diameter value decreases from this mid-
point maximum. This would have no effect on the vapor space
volume calculations but could reduce the saturation levels of the
vapor space, particularly when lower vapor pressure liquids are
stored. Lower vapor pressure liquids are often stored in horizontal
cylindrical tanks.
Section 3.2.3.1.2, pg 3-8 Fourth sentence, change "1 to 15 mi/hr" to "2 to 15 mi/hr."
Table 3-3, pg 3-9
Table 3-3, pg 3-9
The Kf, factor for weighted mechanical actuation, ungasketed
vacuum breaker should be "1.1".
The subscript "c" states emergency roof drains are not used on
pontoon floating roof tanks. This is not correct and should be
deleted.
Table 3-5, pg 3-11
Table 3-5, the number of pontoon legs for the 250 foot diameter
tank should be "35".
Section 3.2.3.1.4, pg 3-14 This section should contain a paragraph explaining the effect of
tank color on the vapor pressure. API Publication 2517, Section
2.2.2.3 and Table 10 describe this.
Section 3.2.4, pg 3-15
Section 3.2.4.2, pg 3-21
Add the following sentence to the bottom of the paragraph:
"Vapors are also expelled by the expansion of the air in the
enclosed space due to diurnal temperature changes (breathing)."
The rim loss factors for tight fitting seals are not provided. See
API Publication 2519, page 8, Table 3.
6
122B
-------
Section 3.2.4.2, pg 3-21
Add the reference to "shoe" seal as stated in the NSPS.
discussion of the NSPS in Section 3.3.5 of this CTG.
See
Section 3.2.4.3, pg 3-24
Section 3.2.4.4, pg 3-29
Section 3.3, pg 3-29
Section 3.3.1, pg 3-29
Section 3.3.4, pg 3-31
Section 3.3.5, pg 3-32
Thus change descriptions to: "Liquid-mounted or shoe primary seal
only" and "Liquid-mounted or shoe primary seal plus secondary
seal".
In description of NF1, add "In the case of an internal floating roof
tank that has been converted from an external floating roof tank by
retrofitting with a self-supporting roof, Tables 3-3, 3-4 and 3-5
should be used to estimate the number of fittings."
The deck seam loss factor (Sd) of 0.20, which is given as a default
value, should also be listed as the factor for a deck constructed
with continuous metal sheets with a 5 foot spacing between seams.
This is an excellent summary of the regulations.
Subpart K became effective June 11, 1973 for tanks greater than
65,000 gallons that were constructed, reconstructed or modified
after that date. The date of March, 1974 is effective for tanks
between 40,000 and 65,000 gallons.
No mention is made of the exemption for tanks at drilling or
production facilities which are used prior to custody transfer.
Subpart Ka NSPS, the effective date is implied to be April, 1980.
The subpart actually is effective for tanks constructed,
reconstructed or modified after May, 1978.
There is no mention of the exemption for production tanks used
prior to custody transfer, which are less than 420,000 gallons.
Also, there is no mention of the inspection requirements for the
seals on external floating roof tanks.
Volatile Organic Liquid NSPS, there is no mention that this is
actually Subpart Kb. The effective date is implied to be April
1987. The subpart actually is effective for tanks constructed,
reconstructed or modified after July 1984.
There is no mention of the exemption for production tanks used
prior to custody transfer, which are less than 420,000 gallons.
Also, there is no mention of the exemption for tanks at gasoline
bulk plants and service stations, or tanks used for the storage of
-------
Section 3.3.5, pg 3-32
Section 3.3.5, pg 3-32
Section 3.3.6, pg 3-33
Section 3.4.1.1, pg 3-34
Section 4.0, pg 4-1
Table 4-1, pg 4-2
beverage alcohol. Also, there is no mention of the requirement for
periodic inspection of roof seals, gaskets, and membranes in all
regulated internal floating roof tanks and external floating roof
tanks.
Some reference should be made to support 40 CFR Part 60,
Subpart Kb as it is often referred to as such.
Last paragraph, add as second sentence: "Shoe seals are also
typical to internal floating roof tanks which have been converted
from external floating roof tanks by retrofitting with a self-
supporting fixed roof."
Reference to the baseline control method as being a low cost, non-
contact internal floating roof tank is incorrect. Depending on the
diameter, a non-contact internal floating roof tank may cost more.
Also, the use of a single vapor-mounted seal is not permitted.
When referring to RVP and then "vapor pressure", TVP should be
used.
Differences in fittings scenarios could change the order of
hierarchy. A spreadsheet is attached as Exhibit A which further
illustrates the concern mentioned above. The CTG indicates that
the contribution to the total loss due to fittings is +/- 28%. The
spreadsheet shows that "typical" fittings on a 50 foot diameter tank
with a mechanical shoe primary seal are, in fact, 28% of the total.
The fittings contribution increases to 72%, however, if the tank
has a slotted guide-pole. The respective contributions due to each
source category vary too widely to be assigned a representative
percentage.
A hierarchy of equipment cannot be readily achieved when all
source categories are included in the same list because different
combinations would result in different rankings. A separate
hierarchy for each source category however, could be readily
developed. Such an approach would also lend itself to including
all floating roof tanks, rather than having separate lists for
internal and external floating roof tanks.
This table lists Control Options 1 through 6. The reference in
Section 5.2, pg 5-1 is to Control Options I through V. The
inconsistency in these tables is confusing.
-------
Table4-l,pg4-2
Table 4-1, pg 4-2
Table 4-2, pg 4-3
Table 4-2, pg 4-3
Section 4.3, pg 4-5
Table 4-3, pg 4-7
Table 4-4, pg 4-8
Section 4.3.3, pg 4-9
Section 4.4, pg 4-9
Section 4.4, pg 4-9
Table 4-5, pg 4-11
Under Control Options 5 and 6, add "or shoe" after the words
"liquid-mounted".
Add superscript "b" after superscript "a" in the title after "RATE".
Add another footnote: "bSelf-supporting fixed roofs would result
in lower emission rates for each control option."
Footnote "a" is missing.
Add superscript "b" after superscript "a" in the title after "RATE".
Add another footnote: "bConversion to an internal floating roof
tank by retrofitting with a self-supporting fixed roof would result
in lower emission rates for each control option." The reason is
primarily because it blocks the wind, but the "shading" effect may
provide additional benefit by resulting in a lower surface
temperature of the stored product.
Third paragraph, are the fittings assumed to be controlled or
uncontrolled?
In footnote, third sentence, change "split" to "slit".
Add "or shoe" after "Liquid-mounted" in two places.
The second paragraph does not address bolted construction with
gasketed seams as a potential emission reduction or control. The
statement that the deck seam losses are not a factor of the type of
seam is incorrect.
The first paragraph in this section should be deleted. There are
too many options to consider, i.e. tank size, fittings, seal details,
etc. to make such a generic statement.
First sentence, add "typical" before the words "internal floating".
Also, add a sentence to the end of the paragraph: "An internal
floating roof tank with welded deck seams and no support columns
would emit less VOC per unit of storage area than do external
floating roof tanks due to the elimination of wind influence."
Deck fitting type 3 (or any equipment description) does not address
slotted gauge pole/sample wells. This should be added.
9
' o o
-------
Section 4.4.3, pg 4-12
Table 4-6, pg 4-13
Table 4-6, pg 4-13
Table 4-6, pg 4-13
Section 4.5, pg 4-14
Section 4.5, pg 4-14
Section 4.5.1, pg 4-14.
Add a last sentence: "Retrofitting an external floating roof tank
with a self-supporting fixed roof would convert the tank to an
internal floating roof tank and eliminate the wind influence,
thereby reducing the rim seal losses. "
Title of second column should be
Add as sixth description: "Metallic shoe primary seal only with
self-supporting fixed roof retrofitted to tank0." Add "3.0^" and
"99%" in second and third columns respectively.
Add as last description: "Liquid-mounted or shoe primary seal
with rim-mounted secondary seal with self-supporting fixed roof
retrofitted to tank6." Add "1.6d" and "99%" in the second and
third columns respectively.
Add footnotes as follows: '""Retrofitting with a self-supporting
fixed roof converts the tank to an internal floating roof tank."
"dFrom values listed in Section 3.2.4.1."
Sixth description as written, change "steel" to "seal". Also, in
footnote a, the word "listed" is shown twice.
Delete the first sentence on this page. It is uncommon to put a
redundant blower in the vapor collection system. Blowers/ electric
motors do not fail often enough to justify a full spare. In case of
a failure, the tank vents through the pressure/ vacuum vents while
the blower is repaired. Occasionally, there are more than one
blower for capacity reasons, not sparing.
The reference to saturators should be deleted. Saturators are very
unusual. More common are systems that are designed to run rich
(above upper explosive limit), enriched with natural gas to 1.2
times upper explosive limit (21 percent), or inerted with nitrogen
or inert flue gas. Some systems are designed to run lean (<25
percent of lower explosive limit). Flame arresters and/or water
seals are almost always used.
The statement that applying the technology to VOL's is not
difficult should be stricken. The application of carbon adsorption
to petroleum mixtures is a complex problem. The reference given
is for vapor recovery of a pure hydrocarbon, benzene, which is a
simpler problem. Some specific issues to be concerned about
when applying carbon adsorption (CA):
10
-------
o CA capacities to adsorb C1( C2, C3, and C4 molecules are very low. For practical
purposes, CA is not a good recovery technology for these molecules. They pass
through the bed almost immediately.
o Hot vapor streams which contain heavier components saturate the carbon with
molecules which cannot be removed except by conditions more severe that the
CA unit is capable of. The carbon usually must be replaced.
o The H2S present in some petroleum product vapors reacts on the carbon to form
solid elemental sulfur (Clause Reaction), which fouls the carbon bed. The
elemental sulfur cannot be regenerated off the bed so H2S containing streams are
not good candidates for CA.
o Water vapor is also adsorbed by the carbon, so vapor streams with high humidity
must be dried before the CA unit. Also, if water vapor is present, the carbon
must be protected from sub-freezing temperatures or else the carbon particles will
be damaged by ice crystal formation.
o Part of the complexity of applying carbon adsorption is in sizing the carbon
column to handle a peak vapor load in short period of time vs. a truck loading
rack recovery unit that handles small vapor volumes over a long period of time.
Section 4.5.1, pg 4-14
Section 4.5.2, pg 4-15
Section 4.5.2, pg 4-15
Section 4.5.2, pg 4-15
Section 4.5.3, pg 4-15
Third paragraph, regarding steam regeneration, it would be unique
for a typical gasoline marketing facility to generate steam and have
an associated wastewater treatment system on site.
First paragraph, fourth line, delete "the simplest to operate".
Oxidation units require a significant supplemental supply of fuel to
operate. Of concern, they generate NOx and CO which may need
to be removed and also may require regular monitoring.
The reference to saturators should be deleted. Saturators are very
uncommon. Vapor gathering systems are deliberately designed to
operate at less than 25 percent of the lower explosive limit or
above 1.2 times the upper explosive limit to avoid the possibility
of propagating explosions.
Delete the word "two" in the second full paragraph, second
sentence. Only a single water seal between the combustion device
and the vapor system is common. Dual seals are a redundance
used at the owner's option.
Refrigerated condensation systems are also used on vapor
collection systems in addition to vent condensers.
11
-------
Section 4.6.2, pg 4-17
Sections 4.6.2, pg 4-17
& 4.6.3
Section 4.6.4, pg 4-17
Section 4.6.5, pg 4-17
Section 4.7, pg 4-18
Section 4.8, pg 4-18
Section 5.2.1, pg 5-3
Section 5.4.1, pg 5-7
Additional rim floatation should be added as another consideration
in the modifications.
When retrofitting any internal floating roof tank with liquid
mounted or secondary seals, additional buoyancy and storage loss
must be considered. This may be especially important with non-
contact internal floating roof tanks.
Practical experience has shown that hot work and/or tank redesign
is almost always required, therefore, the tank must be taken out of
service, cleaned and degassed.
Add a new section "4.6.5 Self-Supporting Fixed Roofs on External
Floating Roof Tanks. Several design issues are encountered in the
retrofit of a self-supporting fixed roof to an existing open-top tank.
For example, the reactions from the fixed roof produce localized
loading on the tank. The self-supporting fixed roofs are typically
made of aluminum, which results in the potential for differential
movement between the aluminum fixed roof and the steel tank
shell due to the difference in their coefficients of thermal
expansion."
Add the wording, "Emissions from liquid stored in a fiberglass
fixed roof tank could be controlled by the use of a fiberglass
internal floating roof tank."
The date for Reference 1, API Publication 2517, should be June
1989.
Third full paragraph, second sentence. Do not agree that the only
control option is a condenser. The proper control method would
be a vapor balance system; delivery to these tanks is typically by
truck. This control system is described in an EPA report dated
December 1977 (Report 450/2-77-035, page 14, reference
alternative #2 vapor balancing of transport truck and the storage
tanks).
The last sentence should be revised to read: "From Figure 5-8, it
is shown that the greatest emission reduction for a baseline
external floating roof tank with metallic shoe primary seal is
obtained from the addition of a secondary seal and controlled
fittings. From Figure 5-9, it is shown that the greatest emission
reduction for a baseline external floating roof tank with a vapor-
mounted primary seal is obtained by the substitution of a liquid-
12
-------
Section 5.4.2.1, pg 5-7
Figure 5-9, pg 5-20
Section 5.5.1, pg 5-21
Section 5.5.2, pg 5-22
Section 6.2, pg 6-4
Section 6.2, pg 6-3
Section 7.2, pg 7-3
Section 7.2, pg 7-3
mounted primary for the vapor-mounted primary seal in
conjunction with the addition of secondary seals and controlled
fittings." The sentence, as written, is incorrect as it refers to two
different baseline tanks and does not differentiate between the two.
First paragraph, it mentions that external floating roof tanks are
equipped with a flange on which a secondary seal can be mounted.
However, due to the ages of most external floating roof tanks, this
flange either requires repair or modification in order to mount the
secondary seal. In some cases hot work may be needed when
installing a secondary seal on an external floating roof tank. In
these cases, tanks would have to be cleaned and degassed.
Also, adding a secondary seal to an existing external floating roof
tank with the tank in service may violate safety company
guidelines and should be left to each company to decide.
Figure 5-9 does not include a definition for the "1m" abbreviation.
Table 5-1, the word "emissions" in the title of column 3 is
misspelled.
Table 5-2, the title of column 2 should read "Nationwide Emission
Estimates, Mg/yr (tons/yr)".
The value of petroleum product recovery credits is more
appropriately $50 per ton instead of $320 per ton, based on
wholesale butane prices at $0.10 per pound. The losses from most
petroleum product (and crude oil) storage is primarily butanes and
pentanes that were contained within the products. The CTG
should be revised to show $50 per ton of recovered product. See
Exhibit B.
First full paragraph, using 5 10 years as the expected equipment
life may be more accurate.
Add the following definition for clarity because of the inspection
requirements in Section 7.5: "Internal floating roof tanks are
storage vessels that have a floating roof and a freely vented fixed
roof. The fixed roof is not necessarily free of openings but does
span the entire open plan area of the vessel."
Fifth full paragraph, a vapor-mounted seal does not have to be
foam-filled. Delete "foam-filled."
13
-------
Section 7.5, pg 7-4
Section 7.5, pg 7-6
Section 7.5, pg 7-7
Section 7.6, pg 7-8
Reading the information presented in Table 4-2, Table 4-6 and the
general discussion on external floating roof tanks and gap criteria
in Section 7.5, it may be difficult for operators of riveted tanks
with mechanical shoe seals to meet the specified seal gap
requirements of Section 7.5.
Item (ii) should be revised to state that no appreciable holes, tears
or other openings in the shoe, seal fabric or seal envelope.
Alternatively, the EPA should quantify this requirement as in the
gap criteria stated above.
The requirement that the owner prepare an "operating plan" for
control devices is redundant and unnecessary. The devices are
subject to capacity verification and emissions testing when they are
installed. Additional documentation is unnecessary. In addition,
the units are always designed and tested (per state test
requirements) at maximum, worst case loadings. The documen-
tation for off peak flow rates, compositions, etc. is generally not
available and would cost individual terminal operators thousands
of dollars each to have developed. This section could be
simplified to require that the owner/operator must have
documentation that the system is capable of handling the peak load
that is expected from his current maximum operating rate.
Previous permit applications, design/ purchase specifications, or
state approved performance testing would be sufficient.
Item 1., states the highest maximum true vapor pressure for the
range of products stored should be used for emission calculation.
This number would give the maximum emissions for that product
at that particular time but would not be representative of the true
emissions over the period of a year. For example, a products
pipeline will pump a varying number of vapor pressure products
depending on the season. Using the maximum vapor pressure
over-estimates the true emissions over this period. A more
accurate method would be to use the weighted average true vapor
pressure and corresponding temperature.
14
-------
MOV 08 '91 16=33 CONSERVflTEK NO CAR 919 933 4210
P.2
i »T r-¥**\rt**l tW nt* f*rt*lVl*.«*-t.lT TtfFJ"** .—I nATTUO ri/".n/~ TfllU//*
nirnnm.ni iir rmnrnrni urrn Himiihn niiiir innnn
(assume 10 »ph Mind b(Jttd for £FRT)
50' Diaieter
EOUIPrlEHT DESCRIPTION
SEAL
FflCTORS
Open top tank, welded shell (EFRis) 38.00
•echanical shoe oriwry seal
Open top, Melded shell (£FRi5,ss) 2.00
shoe priaary + secondary seal
Coluw-supported fined roof (WFRvii) 6.70
Bolted dock, priwry ual only
Coluin-aip'M fixed roof (blfftvi.ss) £.50
Bolted deck, pniary + secondary
Self-supporting fixed roof
Uelded deck, sow seal only
3.00
Self-wip'ting fixed roof 1.60
secuiiddr/
100' Diaieter
EQUIPHENT DESCRIPTION
SEA.
FACTORS
Open top, shoe seal only (EFRis) 38.00
Colum-supported, bolted b) £.30
Open top, shoe + secondary(EFR«s,ss) 2,00
Self-supporting) welded (vIFRis) 3.00
Self-supporting, wlded (*IFRis,ss> 1.60
ISO1 Maieter
F-fiUIPHBO DE5CRIPTIDH
SEAL
FflCTORS
Open top, shoe seal only (EFftaO 36.00
Column-supported, bolted (bIFRvi) &.70
Colmn-supported, bolted (bIFRvt,ss) £.50
Open top, shoe + secondary
-------
WHAT IS THE PRODUCT CREDIT FOR REDUCED VOC LOSSES ?
There are two ways of looking at the value of lost material:
The value is the same as the value of the liquid in the tank, or
The value is that of the lost material sold as a separate product.
The first method is appropriate for single component liquids, or for
end-user commodities.
The second method is better for unfinished materials in production, and
for wholesalers of broad product slates such as oil refiners.
The material that evaporates from petroleum fuel tankage is primarily
lighter components such as butanes, pentanes, and other light hydrocarbons.
VALUE AS FINISHED PRODUCTS
$/GAL LB/GAL $/LB
CRUDE OIL 0.56 7.1 0.08
GASOLINE 0.65 5.6 0.12
VALUE AS COMPONENT
BUTANE (normal) 0.47 4.9 0.10
NATURAL GASOLINE 0.53 5.6 0.09
AVERAGE OF BOTH METHODS = $0.10
All prices per gal shown above were taken from the Plait's Oilgram Price
Report for Tues., 11/12/91; adjusted to price per gallon units.
All figures rounded off.
-------
APPENDIX: RECORD OF ATTENDANCE
-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
14Z?
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE^ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
AC.
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
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-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
\
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./a-//?/
-------
RECORD OF ATTENDANCE
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE MEETING
NOVEMBER 19, 20, AND 21, 1991
PLEASE PRINT
NAME AND
AFFILIATION
BUSINESS ADDRESS
(INCLUDE ZIP CODE)
TELEPHONE
NUMBER
DATE(S)
ATTENDED
(Tlaresa uJilliamsoo
677-0249
///a'
9/7
H-
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U.5. EPA CmD-13)
-------
NATIONAL AIR POLLUTION CONTROL TECHNIQUES ADVISORY COMMITTEE
MINUTES OF MEETING
NOVEMBER 19-21, 1991
Prepared by:
Office of the 'Director
Emission Standards Division
I certify that, to the best of my knowledge, the foregoing
minutes and attachments are complete and accurate.
Bruce Cjxtfordan, Chairperson
National Air Pollution Control Techniques
Advisory Committee
U.S. Government Printing office
312-014/40042
------- |