COM
                     EQUATION WORKBOOK



                   SCIENTIFIC PROTOCOL FOR



                 OCEAN DISPOSAL SITE DESIGNATION
              Camp Dresser & McKee

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U.S. Environmental  Protection Agency
   Criteria and Standards Division
       Washington,  D.C.  20460
          EQUATION WORKBOOK

       SCIENTIFIC PROTOCOL FOR

   OCEAN DISPOSAL SITE DESIGNATION
             Prepared by

             T.S. George
              R. Walton
        Camp Dresser & McKee
7630 Little River Turnpike, Suite 500
     Annandale, Virginia  22003
     Telephone:  (703)  642-5500

            February 1984
      Revised:  September 1984
       Contract No. 68-01-6403

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                             TABLE  OF  CONTENTS
List of Figures 	   iii

List of Tables 	   iv

INTRODUCTION 	   1

STAGE 1.  PRELIMINARY SITE EVALUATION  	   1-1

      1.1  Introduction 	   1-1
      1.2  Forms	   1-1
      1.3  Basemaps 	   1-3

STAGE 2.  WASTE PROFILE AND LOADING  CHARACTERIZATION  	   2-1

      2.1  Introduction 	   2-1
      2.2  Forms 	   2-1
      2.3  Calculations for Multiple Sources 	   2-6

STAGE 3.   TRANSPORT MAPPING AND  RESUSPENSION  ESTIMATION  	   3-1

      3.1  Introduction 	   3-1
      3.2  Forms 	   3-4
      3.3  Evaluate and Map Benthic  Impacts Areas for Negatively
           Buoyant Solid Wastes  	   3-4
      3.4  Sediment Resuspension  Potential  for Typical  Conditions ...   3-9
      3.5  Resuspension Probability  Under Episodic (Storm)
           Conditions 	   3-16
      3.6  Estimate Annual Sediment  Transport  Rate 	   3-25
      3.7  Calculate and Map Typical  Long-Term Transport  Contours ...   3-30

STAGE 4.   INITIAL MIXING AND SOURCE STRENGTH  CALCULATIONS  	   4-1

      4.1  Introduction 	   4-1
      4.2  Forms 	   4-1
      4.3  Initial Dilution of Liquid  Phase 	   4-1
      4.4  Source Strengths and  Initial  Conditions 	   4-6
      4.5  Vertical Distribution  of  Constituent Concentrations 	   4-10

STAGE 5.   WATZR QUALITY CRITERIA COMPARISONS	   5-1

      5.1  Introduction 	   5-1
      5.2  Form 	   5-1
      5.3  Near Field Acute Exposure Level  	   5-1
      5.4  Far Field Chronic Exposure  Level Using Discrete  Cloud
           Model  A 	   5-15
      5.5  Far Field Chronic Exposure  Level Using Plume Model  	   5-19

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                             TABLE  OF  CONTENTS
                                (Continued)
STAGE 6.   HYPOXIC EVENT POTENTIAL  ASSESSMENT
      6.1
      6.2
      6.3
      6.4
      6.5
      6.6
      6.7
      6.8
Introduction 	
Forms 	
Ambient BOD Without Disposal  	
Local Water Column BOD With Disposal  	
Initial  Dissolved Oxygen After Disposal  	
Oxygen Depletion Curve For Net Flow,  Urn > 0.0 	
Oxygen Deficit Growth Rate For Net Flow Urn = 0.0 	
Oxygen Deficit Growth Rate Comprehensive Example for Net
Flow Urn = 0.0 	
Page

6-1

6-1
6-3
6-3
6-8
6-9
6-10
6-12

6-19
STAGE 7.   SPECIES SPECIFIC ASSESSMENT 	   7-1
      7.1  Introduction
      7.2  Procedure ...
LIMITATIONS

REFERENCES

APPENDIX A.


APPENDIX B.

APPENDIX C.

APPENDIX D.

APPENDIX E.
  CROSS-REFERENCE TABLE OF EQUATIONS IN PRELIMINARY
     MANUAL AND EQUATION WORKBOOK

  DSP FORMS

  TABLES FROM SITE DESIGNATION MANUAL

  FIGURES FROM SITE DESIGNATION MANUAL

  SUGGESTED SOURCES FOR DATA AND INFORMATION
                                                            7-1
                                                            7-1

                                                            8-1
                                     ii

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                             LIST OF FIGURES

Figure                                                                Page
1-1      Example of Small  Scale Basemap with Landmarks  	  1-5
1-2      Example of Large  Scale Basemap with Bathymetry  	  1-6
3-1      Stage 3,  Transport Mapping  and Resuspension Overview  	  3-2
3-2      Example of Pycnocline Formation  	  3-3
3-3      Definition of Current Variables  	  3-7
3-4      Example of Benthic Deposition Area  	  3-10
3-5      Flowchart for the Estimation of  Resuspension Correction
         in Section 3.5.6  for Each Material  	  3-23
3-6      Volumetric Sediment Transport Rate Versus Mean  Flow for
         Various Wave  Induced Bottom Velocities  	  3-28
3-7      Concentration (g/m ) Contours for Unit  Load at  Point  of
         Disposal, Assuming Continuous Point Source  	  3-35
3-8      Concentration (g/m ) Contours for Unit  Load at  Point  of
         Disposal, Assuming Discrete Point Source  	  3-38
3-9      Concentration (g/m ) Contours of Unit Load at  Point of
         Disposal, Assuming Discrete Distributed Source  	  3-42
4-1      Stage 4,  Initial  Mixing  and source Strength Overview  	  4-2
4-2      Relative Vertical Sediment  Concentration  Profiles  	  4-14
5-1      Stage 5,  Criteria Comparison Overview  	  5-2
5-2      Quadrilateral of  Horizontal Area Over Which Criterion is
         Exceeded 	  5-12
5-3      Horizontal Area Over Which  Criterion for  Lead  is Exceeded
         in Example of Equation 5-6  	  5-16
6-1      Stage 6,  Dissolved Oxygen Assessment Overview  	  6-2
8-1      Area of Impact and Depth of Coverage Using Two  Different
         Estimates 	  8-4
                                    iii

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                               LIST  OF  TABLES
Table                                                                  Page
1-1      Example of Form DSP1  Basic  Site  Characterization
         Information 	   1-2
2-1      Example of Form DSP2  Waste  Source  and Loading
         Characterization 	   2-3
2-2      Example for Single Source of Form  DSP3 Representative
         Waste Profi1e Descri pti on 	   2-4
2-3      Example for Multiple  Sources of  Form DSP3  Representa-
         tive Waste Profile Description  	   2-5
2-4      Example of DSP4 Geochemical  Site Characterization  	   2-7
3-1      Example of Form DSPS  Physical Oceanographic
         Characterization 	   3-5
3-2      Example Wave Frequency Table 	   3-17
3-3      Example Wave Frequency Table for Sand 	   3-19
3-4      Calculation Example of Resuspending Wave Orbital
         Vel oci ty for Sand 	   3-24
4-1      Bioturbation Coefficients,  D, for  Various  Locations 	   4-12
5-1      Example of Form DSP6  Water  Quality Criteria  Comparison
         Summary 	   5-3
6-1      Oxygen Deficit Growth Rate  Worksheet 	   6-21
6-2      Example Oxygen Deficit Growth Rate Worksheet 	   6-22
7-1      Organization of Species Specific Impact Assessment 	   7-2
7-2      Species and Constituent-Specific Summary Table 	   7-4
                                     iv

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                               INTRODUCTION
PURPOSE

The purpose of  this  Equation  Workbook is to  provide  detailed guidance in
the use of  the  equations that have  been  incorporated into the scientific
protocol   for  ocean  disposal  site designation  under  development  by  EPA.
This  was  done  by providing concise descriptions  of the  use  of  each
equation,  hypothetical  examples of the  use of each equation, and tables and
graphs of  necessary coefficients and  constants.

BACKGROUND

The development of a scientific protocol  for  ocean  disposal  site  designa-
tion is a  result of the joint  interest  of  the U.S. Environmental Protection
Agency (EPA) Criteria  and  Standards  Division,  Office  of Water Regulations
and Standards  and the  EPA Environmental Research Laboratory  in  Nar-
ragansett, Rhode Island.

The efforts of  these  two  groups  have  resulted in the  preparation of the
following  two  documents:

    •   A  Preliminary  Ocean Waste Disposal Site  Designation  Manual (ASA,
        1983)

    •   Proceedings of  a Workshop  for the Development of a Scientific Pro-
        tocol  for Ocean Dump Site Designation (Reed and Bierman, 1983)

Preliminary Site Designation Manual

A Preliminary  Ocean Waste Disposal  Site Designation Manual  was prepared by
Applied Science  Associates,  Inc.  (ASA,   1983)  for the  EPA  Criteria  and
Standards  Division (OWRS).  This  Preliminary  Manual  presents  the  disposal

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site  evaluation  protocol in  seven major  stages.  As  reflected  in  the
Equation Workbook, the methodologies presented by ASA in their Preliminary
Manual have not been changed  or modified by  EPA.

The  goal  of the  Preliminary  Manual was to  systematize  the scientific
protocol  for  pre-disposal  marine dumpsite  designation  studies.  This
involved the development of a methodology and a series of mathematical  and
mapping exercises to evaluate  the  capability  of  a given site to receive a
particular type of waste.  The basic strategy of the manual was to attempt
realistic  assessments,  within  the  limitations  of  a  non-computerized
approach, using conservative  assumptions.

The Preliminary Manual  presents numerical calculations which can be carried
out with a hand-held scientific calculator.   In some situations, such as a
highly sensitive  biological  area  where  complex hydrodynamics prevail,  the
approach presented in the manual may  not be  sufficient.   In such cases,  the
manual recommends a hydrodynamic  and biological computer modeling approach
with a coordinated field survey effort.

Proceedings of  a Workshop

The Proceedings of a Workshop for the Development of a Scientific protocol
for Ocean Dump  Site Designation (Reed and Bierman, 1983)  was prepard by Dr.
Mark Reed of Applied Science  Associates, Inc., Wakefield, Rhode Island,  and
Dr. Victor J.  Bierman,  Jr.,  of the EPA  Environmental Research Laboratory,
Narragansett,   Rhode Island.   The  Workshop, which was  attended  by 30
scientific and   technical experts  in  the  fields of physical,  chemical,  and
biological  oceanography, was convened to assist  in  the  development of  the
protocol.   Task  group  reports are  contained in  the  Proceedings  of  the
Workshop which   offer comments  and recommendations on  the  protocol  stages
presented in the Preliminary  Manual.

The   proceedings  contain  recommendations   for   the  development  of   an
operational technical  guidance manual  for  ocean dump  site  designations,
with emphasis on dredged material  disposal in  shallow coastal environments.

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These recommendations have not been  adopted as official EPA  policy  and  no
official  EPA endorsement should be inferred.

EQUATION  WORKBOOK

The Equation Workbook was  developed  directly from the  Preliminary Manual.
No changes were made in  the underlying assumptions,  procedures or equations
presented in the Manual.  The Workbook was  prepared  for use as guidance  in
the scientific  methods  recommended by  the  Preliminary  Manual  for  use  in
ocean disposal  site designation  studies with  particular  emphasis  on the
numerical calculations.

There are  many mathematical  equations  in  the  protocol  which are used  to
describe  physical,  chemical  and biological processes  in the marine environ-
ment.   The Workbook is  designed to aid in the understanding and application
of  these  equations  by  providing   additional   information   and example
calculations for each equation in each of  the  seven  protocol  stages.  The
Workbook  is geared for a level of use by EPA Regional Office personnel and
the District  Office U.S. Army  Corps  of Engineers (CE)  personnel with
general  engineering and  scientific backgrounds,  but who may not necessarily
be familiar with the specialized  equations and principles of the protocol.

In the Equation Workbook,  the equations are  numbered  for each of the  proto-
col stages.  These  numbers  do not necessarily  coincide  with  the numbering
system presented in  the Preliminary  Manual.  This is  due  to  the fact that
the Workbook provides additional   equations,  changes  the  order of equations
or breaks down  large equations into parts to aid  in  the calculation  proce-
dure.   A  cross reference  table  of equations  and  equation  numbers is given
in Appendix A  to provide  a correlation  between the  equations of these  two
documents.

FORMAT OF WORKBOOK

The Workbook   presents  a  section  on  each  of  the  seven  protocol  stages,
Sections  1.0 through 7.0.  The sections  and subsections for each stage  are
presented in  decimal  outline form for  easy  cross-referencing.   For  each

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protocol  stage a general  introduction  is  presented  followed by  a  discussion
of the disposal site protocol (DSP) forms that must  be  filled  out for  that
stage before  any  analysis  can be  carried out  using  the equations.  Major
calculation sequences are then grouped together with  an  explanation of  each
formula or equation.   Special  attention  is  given to the  proper  definition
of each variable in the equation  and  the  units  involved.

For  each  equation  described,  an  example  calculation  is  provided.   The
example calculations for each equation in  each stage use  numerical  values
that  are  on  the  example DSP  forms  or  values  that have been  previously
calculated.   This provides  for a consistently  understandable example
throughout the entire  Workbook.   The  values used in the  examples provided
in the Workbook are not default values and are  not  recommended  for use  when
no other values are available.  They  are  only  used  to provide an  example  of
the calculations performed for each equation.

Section 8.0,  Limitations,  is presented  as  part of  the Workbook  to bring
out, in addition to the  discussion in each  protocol  stage,  several  general
and  specific  points  that the user should  keep in mind  as he applies  the
scientific protocol to particular sites and  wastes  being considered.

Five  appendices  are included  in the  Workbook.    Appendix A  is a  cross-
reference table of equations in the Preliminary Manual  and in  the Equation
Workbook.   Blank disposal site protocol (DSP)  forms are  provided  for use  in
Appendix B.  Appendices C and D  are tables  and  figures  of information  that
are used to carry out  the protocol.   Additional  sources  of information and
recommended reading are given in  Appendix E.

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                   STAGE 1.   PRELIMINARY SITE EVALUATION
1.1  INTRODUCTION

The purpose of this stage is to collect pertinent information in and around
the site or sites chosen in the preliminary efforts of the site designation
procedure.  The information collected is used to determine,  at the earliest
stage,  if  a  site is unacceptable  or if potential  problems  are indicated.
The presence  of  specific conditions within  the site itself  would  make  it
unacceptable  for  disposal; and  if  those  conditions were  present  in  the
general  area  of  the  site, then  they would  indicate potential  problems.
Such conflicting conditions would include:

    •   Marine or estuarine sanctuary,
    •   Military exclusion area,
    t   Interference with navigation, and
    •   Engineering  use  of  seafloor  such  as  seabed  mining  and  undersea
        cables.

Potential problems are  then  addressed  in the other  stages  of the protocol
as the designation procedure continues.

1.2  FORMS

Only one disposal  site protocol form is required as part of Stage 1.  It is
the Basic  Site Characterization  Form,  DSP1.    (See  Appendix B  for blank
form.)  The  form is  used to provide  basic physical information  about  the
disposal site and potential conflicts in the disposal site area such as  the
location of areas used for fisheries and sanctuaries.

Table 1-1 is an example of Form DSP1.  Each variable name is accompanied by
a value and the appropriate units  for  this value.   All  distances are given
                                    1-1

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                           TABLE 1-1.   EXAMPLE OF



             FORM DSP1  BASIC SITE CHARACTERIZATION INFORMATION
Variable
Name
Value
Units
Source/Comments
Site Center Latitude
Longitude
Width
Length
Orientation of Longest Dimension
Site Shape
Distance to Nearest*
(1) Coastline
(2) Fishery Area
(3) Recreational Area
(4) Shipping Lane
(5) Military Exclusion Zone
(6) Ocean Disposal Site
(7) Marine Sanctuary
(8) Engineering Uses of Seafloor
(Specify)
(9) Living Resources
XX°XX'
YY"YY'
5
10
h
N
W
km
km

Rectangular
15
100
15
10
N/a
75
N/A
15
N/A
km
km
km
km
km
km
km
km

Assigned
Assigned
Assigned
Assigned
Assigned
Assigned
State Shoreline
Sport Fishing
Swimming beach at
Beach Town
To Major River
-
Industrial disposal
site
-
Sand mining
-
*From closest site extremity, not from site center
                                     1-2

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in kilometers.  There is also a column on  this  form  for  comments  which may
be used  to further clarify  the  variable  name  in the  first column.  For
example,   in  the comment  column  across  from the  variable   "coastline"  in
Table 1-1 the coastline is identified as  being the state  shoreline.

1.3  BASEMAPS

The first protocol  stage requires the development  of at  least  two basemaps
at different  scales  showing the  location  of the  proposed  waste  disposal
site or  sites.   Coastal  charts  of the  National  Ocean Survey can  provide
good information for  basemap development.    A small  scale map of  the  site
should show the coastline and recognizable  landmarks  (cities, rivers, etc).
This map would generally include  an area  within  a  100 km  radius of the  site
center.  A more detailed, larger  scale map  of the  site  should show the  site
bathymetry.   A  25 km  radius  around  the  site center will  typically  be
included.  All maps should locate  such areas as fisheries,  shipping lanes,
recreational  uses,  etc., which  are listed on Form  DSP1.

Along  most open coastal  areas  the  bathymetry  provided by the  standard
navigational   charts will  not be  sufficient for site  designation  purposes
(transport  calculations,  determination  of  areas  of  deposition,  bottom
roughness  scales  and  the like).   The  boat sheets  developed during  the
survey and used  to prepare  the  charts may, depending on line  spacing  and
sounding frquency,  be more  nearly adequate.  These can  be  obtained, often
now in digital format,  from  the NOS  (National Ocean  Survey,  NOAA).  In the
absence  of such detailed  data a  suplementary  initial  bathymetric  survey
covering the area within a three  to  five mile radius  of  the disposal site,
may be necessary.

Figure 1-1 is an example of a small  scale basemap  with  landmarks.   This map
also shows the location of potential  conflicting  uses  such  as  the shipping
lane, industrial disposal site and sport fishing  areas which are  listed on
the example Form DSP1  given in  Table 1-1.

Figure 1-2 is  an example of a closer  look at the disposal   site  area  on a
larger scale  map which shows the  bathymetry of the area.   This  map  also

                                    1-3

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shows the potential problem areas such as the recreational beach, the sand
mining use and the shipping lane.

The maps developed for Stage 1  provide general locational  information about
the site  and  its relationship to other activities in  the area.   The maps
are, however,  developed as "basemaps"  on which results  are displayed in the
other protocol  stages.    Such  uses  include plotting mean flow direction,
mapping benthic  impact  areas,  drawing concentration  contours and mapping
the distribution of specific organisms.

It is highly recommended that comprehensive  consultation with  local experts
and interest groups be  carried out  at the earliest part of Stage 1.  This
will  serve to  address  all important considerations which will  often
eliminate several problems later  on.
                                    1-4

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                        _STATE_LINE_
                         STATE LINE
                                                         SPORT
                                                        FISHING
                     •r ZZZZSHIPPING LANE
                                                      INDUSTRIAL
                                                      DISPOSAL
                                                  4
                                             0          25
                                             I   I  I  I  I   I
                                              KILOMETERS
Figure  1-1.  Example  of Small Scale Basemap with Landmarks
                              1-5

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Figure 1-2.   Example  of  Large  Scale  Basemap with  Bathymetry
                               1-6

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            STAGE 2.  WASTE PROFILE AND LOADING CHARACTERIZATION
2.1  INTRODUCTION

The  purpose  of  this  stage is  to define  the  representative physical  and
chemical information of a typical  waste expected  to  be released  at  the  site
or  sites  selected  in  the preliminary  site  evaluation  of Stage  1.    The
general procedure is to collect existing data or perform waste  analyses to
provide information to be used in subsequent stages.   Data cm  be  provided
for:

    1.  Specific waste, single source,
    2.  Specific waste, multiple sources,  or
    3.  Non-specific wastes and sources.

2.2  FORMS

Three  forms  must be completed as part of Stage 2  of the  protocol  (Blank
forms are provided in Appendix B).

2.2.1  Form DSP2

The Waste  Source and Loading  Characterization  form provides many  physical
variables which  are used in  calculations  performed in  subsequent  stages.
For each of  several variables on  DSP2 which are  given in the first column,
the value  is placed in  the second column.   For each variable the  units
required are provided  in  the  third  column, and the fourth column  provides
special  comments  and gives  the variable symbol  used  in  the equations
discussed in the text. Default values  for some  of  the  variables  are  also
provided.   For  completion  of DSP2,  fine  particles  are  considered  those
which have a diameter of less  than 0.1  mm.

Table 2-1  is an example of a  completed Form DSP2.   In  this example,  the
waste  type  is  dredge  material  and  the annual  loading  rate  is 5.0 x  10
cubic meters per year.   The  variable symbol  used in  the equations  for

                                    2-1

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annual loading rate is "Qa." The example values  in  Table  2-1  are  also  those
used  throughout  the  other  stages in the example computations provided  for
each equation discussed.

2.2.2  Form DSP3

The Representative Waste Profile  Description  form  is used to describe  the
waste by providing the mean concentrations  of  various constituents measured
in  the  source  materials.   This form can be used for a single or multiple
.source specific  waste,  or  for a non-specific  waste.  For a  single  source,
only  column A  is completed;  and for multiple sources of specific wastes a
"weighted sum" approach is  used as described in  Section 2.3.   For a  generic
waste, Form DSPS is  used to  best  describe  whatever is  known  about the pro-
bable waste  source  or sources.   The  constituents  listed on this form  are
those that are mandatory.

Table 2-2  is an example of a  completed  form for  a single source waste.
Since there  is  only one source,  only  column  A  in  Table 2-2 is filled  in
with percent solids (42) and concentrations for  the other constituents such
as  a  32  mg/kg concentration  for  BOD,  the  biological oxygen demand of  the
waste.  Table  2-3  is an example of a completed  form for a multiple source
waste.   In  the example of Table  2-3, there  are  three  sources  having
fractional  contributions of  the total  material   of 0.2,  0.3 and 0.5.    The
mean concentrations of the  constituents measured in the source material  are
recorded under each  of  the source headings.   For  example, the BOD  concen-
trations for  sources A, B and  C are 30, 20 and  40,  respectively.    The
weighted sum of  the BOD is  calculated  to  be 32 mg/kg.   The weighted  sum
calculation is shown in Section 2.3.

Because a  site  is  designated  only for a  class of  waste  such  as  dredged
material  or sewage sludge, separate forms for DSP2  and DSPS must  be
prepared for  each  distinct class  of  waste.    Separate  site designation
analysis will  also  be required  if  the  evaluation  of different  classes  of
waste is to be undertaken.
                                    2-2

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                TABLE 2-1  EXAMPLE OF



FORM DSP2  WASTE SOURCE AND LOADING CHARACTERIZATION
Variable Name
Value
Units
Comments
(Text Symbol )
Waste Type
Annual Loading Rate
Typical Duration of Dredging
Operation
Typical Number of Disposals
per day
Bulk Specific Gravity
Liquid Phase Specific Gravity
Particle Specific Gravity
Clay-Si It/ Sand-Gravel {Fine/
Coarse) Fractions (Total
Solid Phase)
Volumetric Solid/Liquid
Fractions
Fraction of Fines in Suspended
Cloud (Single Disposal)
Disposal Vessel
Vol ume
Width
Length
Speed
Individual Disposal
Duration
Frequency
Dredge material
S.OxlO6
0.25
14
1.7
1.0
2.65
0.41/
0.59
0.42/
0.58
0.9
4000
20
50
1.0
200
2
nr/yr
fraction
of year

none
none
none
none
none
none
m3
m
m
m/sec
sec
per day

(Qa)
(Tdd)
(Dd)
(sg) bulk
default: 1.0 (sg)
particle
default: 2.65
(sg) particle
(Ff/Fc)
(Fs/Fl)
default: 0.9
(Ffs)
(Vb)
(w)
(1)
(v)
(t)
                         2-3

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            TABLE  2-2.  EXAMPLE, FOR SINGLE SOURCE, OF

       FORM DSP3   REPRESENTATIVE WASTE PROFILE DESCRIPTION
(Mean  Concentration  of Constituents Measured in Source Materials,
                  all concentrations in mg/kg)




Source
A

Source
B

Source
C

Source
D

Source
E
Weighted
Sum
(Cws)
Fractional
Contribution
(Fi)
Constituent
Percent Solids
BOD (5- day)
DO
pH
Total Chlorinated HC
Total Volatile
Organics
Cadmium
Copper
Lead
Mercury

















1.00

42
32
0
6.0
0.005

1
7
15
O.Z5





































































































































1.00




























                              2-4

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          TABLE  2-3.  EXAMPLE, FOR MULTIPLE SOURCES, OF

       FORM  DSP3  REPRESENTATIVE WASTE PROFILE DESCRIPTION
(Mean Concentration of Constituents Measured  in Source Materials,
                  all concentrations in mg/kg)


Source
A
Source
B
Source
C
Source
D
Source
E
Weighted
Sum
(Cws)
Fractional
Contribution
(Fi)
Constituent
Percent Solids
BOD (5-day)
DO
DH
Total Chlorinated HC
Total Volatile
Organics
Cadmium
Copper
Lead
Mercury

















0.2

63
30
0

0.005

1
8
20
0.30

















0.3

28
20
0

0.005

1
6
15
0.15

















0.5

42
40
0

0.005

1
7
13
0.29











































































1.00

42
32
0
6.0
0.005

1
7
15
0.25

















                               2-5

-------
2.2.3  Form DSP4

The Geochemlcal Site  Characterization  form  is  used to record the background
contaminant values in the water column and in the sediments.  These values
are  used for water  quality  analysis in  subsequent  stages.  The  table
provides  for  concentration values  of the constituents and  provides  for
physical characterization of  the  sediment  (percent  gravel,  sand,  silt and
clay)  for  both  summer  and winter  seasons.   Any  additional  constituents
included in this  form are those studied in the source material as given in
Form DSP3.   Table 2-4  is an  example of  a  completed  DSP4 form.   Marine
stations  or  oceanography schools  of  nearby  universities  as  well  as
Environmental  Protection  Agency  and  National  Marine   Fisheries  Services
Laboratories are  potential  sources of  existing data.

Table  2-4  shows   that  at  the proposed site  the  copper  concentration is
0.0006  mg/kg in the water  column and 0.60 mg/kg in the sediment.  Also, the
bottom   of  the  form  shows  that the  percent  of  sand in  the site sediment
during   the  summer season   (60  percent)  is  only slightly  greater  than the
percent sand (58  percent)  during the winter season.

2.3  CALCULATIONS  FOR MULTIPLE SOURCES

The  contaminants  of each individual  waste source are  not considered
separately in the  analyses of subsequent  stages.   Instead, a weighted sum
is calculated and  used  to represent  the concentration  in  the combined or
composite waste.

EQUATION:   Cws =£Ci * Fi                                           (2-1)
                i=l, n

    where   Cws =  concentration of constituent in composite  waste,
             Ci =  concentration of constituent in source i,
             Fi =  fractional contribution of  total materials represented by
                  source i, and
              n =  number of water  sources
                                    2-6

-------
                           TABLE  2-4.   EXAMPLE  OF

                FORM DSP4   GEOCHEMICAL  SITE  CHARACTERIZATION
 Constituent
     or
Characteristic
    Water Column    |     Site Sediments

(Parts per Minion or mg/kg,  Except Solids)
Percent Sol ids
BOD (5-day)
Dissolved Oxygen (DO)
PH
Total Chlorinated HC
Total Volatile Organic s
Cadmium
Copper
Lead
Mercury

Others
as required















0.000015
3.0
6.0
8.0
0.0000005

0.0001
0.0006
0.0004
0.00002


















-
20
2.0
6.0
0.005

0.02
0.60
0.04
0.02


















SEDIMENTS ONLY:
Percent Gravel
Percent Sand
Percent Silt
Percent Clay
Summer
2
60
33
5
Winter
1
58
35
6
                                   2-7

-------
This formula is used for each  of  the  constituents  listed  on Form DSP3.  The
equation is calculated  based  on  the  concentrations  in each of the  sources
and the fractional  contribution of  each  source.

EXAMPLES:

A)  Given      Three  sources A, B and C  as  shown in Table 2-3 and the frac-
              tional  contribution of  0.2 for  Source A,  0.3 for Source B and
              0.5 for  Source  C;  and  the percent solids  of 0.63 for Source
              A,  0.28 for Source  B  and 0.42 for  Source  C,

    then      the weighted percent  solids is

            Cws = (0.2  * 0.63) +  (0.3 *  0.28)  +  (0.5  *  0.42) = 0.42

B)  Given      The same  three  sources and fractional  contributions as pre-
              sented in  example  A  from  Table 2-3, and the BOD concentra-
              tions  of  30 for Source A, 20 for Source B  and 40 for Source
              C,

    then      The weighted concentration of BOD  is

            Cws = (0.2  * 30) + (0.3 * 20) + (0.5 * 40)  =  32 mg/kg or mg/1.
                                    2-8

-------
          STAGE 3.   TRANSPORT  MAPPING AND RESUSPENSION ESTIMATION
3.1  INTRODUCTION

The purpose  of  this stage (see  flow  chart in Figure  3-1)  is to estimate
sediment  deposition and  resuspension  rates  under  typical  and episodic
(storm) conditions,  and to construct characteristic transport  contour maps.

The water column is  divided into  three parts:

    •   the upper water column  (above  pycnocline),
    t   the lower water column  (below  pycnocline), and
    •   the sediments.

These  parts  correspond to  the pelagic, demersal, and benthic  biological
categories of Stages 5, 6, and  7.

A pycnocline is  a location in the  vertical  profile representing a region of
high density gradients  (Figure 3-2).   In the ideal  sense it  separates two
liquids  of different  densities.    Under  actual  conditions  of  interface
diffusion, it represents  a zone  of transition  from  one liquid  density to
the other.   Examples  of  pycnocline  formation can be  found along  a shelf
break  in which  a warm upper  layer  20-40 meters deep forms during the
summer, and  on  the  shelf where a  fresher  upper layer, 5-10  meters thick,
can form following spring runoff.

On  the  appropriate  basemaps (see  Stage 1),  the  benthic  area of sediment
deposition,  and  characteristic concentration contours  for  given disposal
practices are drawn.   The concentration contours are  drawn  for the upper
and lower water  columns, unless there  is no season of the year during which
a pycnocline is  present,  in which case only  one set  of  contours  need be
drawn.    If the  pycnocline varies  throughout  the  year, additional  sets of
contours will be needed to define  concentration  limits.
                                    3-1

-------
            3.3
            3.4
            3.5
            3.6
            3.7
                                         Complete
                                        Form DSPS
                                             portion
NO
V.of waste reach thex*
Evaluate and map
Benthic Impact Areas
t
Calculate
Sediment
Resuspension Potential
for typical conditions
t
Calculate
Resuspension
Probability under
episodic (storm)
conditions
t
Estimate
Annual Sediment
Transport Rate
t
Calculate and map
Typical Long-Term
Transport Contours


Figure 3-1.  Stage 3, Transport  Mapping  and Resuspension Overview
                                 3-2

-------
                     DENSITY  (SIGMA T UNITS)
         24.0
               25.0
26.0
27.0
I   T VI
Q.
HI
Q
     20
     40
     60
     80
    100
    120
    140
    160
    180
   200
                                                  Pycnocline
                                                  Depth
                     I   I   I    I   I   I    I   I    I A I
                Figure 3-2.   Example of Pycnocline Formation
                          3-3

-------
3.2  FORMS

To' perform the  analyses  of Stage 3,  information  from  Forms DSP2 and DSPS
are required.   Form  DSP2 was filled  out in Stage 2,  Form DSPS should be
completed before continuing.

3.2.1  Form DSPS

The  Physical  Oceanographic  Characteristics form  provides  many physical
variables used in this and subsequent stages.  The variable  name is listed
in column 1,  its value is entered  in column  2,  units are given in column 3,
and column 4  gives the  text  symbol.   A completed Form DSPS, which is used
for the example  calculations  in  the text,  is shown in Table  3-1.  Using the
mean net surface drift, Urn, from Form DSPS,  the positie x-axis  is parallel
to Urn, and the  y-axis is perpendicular and to the left on  the  appropriate
basemaps  of  Stage  1.     Suggested   information  sources   are   listed  in
Appendix E.

3.3  EVALUATE AND  MAP BENTHIC  IMPACT AREAS FOR  NEGATIVELY BUOYANT SOLID
     WASTES

3.3.1  Purpose and  Procedure

For negatively  buoyant  solid wastes  (i.e.  those wastes  containing solid
particles whose  specific gravities are greater than the ambient seawater),
calculate the bottom  area upon which the  particles may  accumulate.

This is a three-step  process  for  each group of particles  considered (e.g.
medium sand,  coarse  sand,  etc.).   Firstly,  the  time  for the particles to
reach the bottom is estimated.   Secondly,  the limits of spreading undergone
during  settling is  estimated  from  horizontal  mean  currents and tidal
variability.   Finally, the area  of impact is drawn.

3.3.2  Comments

For positively or neutrally buoyant wastes,  go  to  Section 3.7.

                                   3-4

-------
              TABLE 3-1.   EXAMPLE OF



FORM DSPS  PHYSICAL OCEANOGRAPHIC CHARACTERIZATION
Variable Name
Value
Units
Source/Comments
(Text Symbol )
Maximum Depth
Minimum Depth
Mean Depth
Pycnocllne Depth
Tidal Period
Ellipse Orientation
Major Axis Velocity
Minor Axis Velocity
Mean Net Surface Drift
Magnitude
Direction
Mean Net Bottom Drift
Magnitude
Direction
Mean Wave
Amplitude
Period
Storm Induced Bottom Current
Water Temperature (Annual
Range)
pH (Annual Range)
35
25
30
20
12.42
SW
0.15
0.07
0.05
SW
0.02
SW
0.5
6.5



m
m
m
m
hr
--
m/sec
m/sec
m/sec
m/sec
m
sec
m/sec
degrees
Celsius



(h)
(hp)
(To)

(Utx)
(Uty)
(Urn)
(Ubm)
(H)
(T)
(Usw)
(T)

                       3-5

-------
For  wastes  containing  negatively  buoyant  solid  particles,   perform  the
calculations  below.

During descent, the cloud falls at a rate  determined primarily by its total
mass  and size,  and  entrains  water.   The  cloud would descend to  a
"dissipation"  depth  at which the  initial  momentum  jet is balanced  by
entrainment,   and  the  particles  fall   approximately  with   their  full
velocities  in  the ambient water column.   The complete problem  is  not
simple and remains to be  adequately  parameterized  (ASA,  1983).   Instead,
the conceptually  simple  approach, below,  is  used.

3.3.3  Calculate  Time  for Particles to Reach  Bottom

The time for a  particle  (or group of particles), with  known fall velocity,
to reach the  bottom is given by:
EQUATION:
             t' =
                                                                    (3-1)
    where    t' = time for particles to reach  bottom in sec,
              h = mean depth in m (Form DSPS),  and
             wf = particle fall  velocity  in  m/sec (use  Figure D-15  or
                 typical value for 0.1 mm diameter sand of 0.005 m/sec)
EXAMPLE:

    Gi ven
             h = 30 m (Table 3-1),  and
            wf = 0.005 m/sec
    then
                   30
                               sec
                                   3-6

-------
3.3.4  Calculate  Limits of Area of Impact

The area of impact is an ellipse whose longitudinal  and lateral  dimensions
can  be  estimated by considering  the mean net  surface drift  and tidal
velocities.   Definition of  the  mean  net tidal drift and tidal  velocities
are shown in Figure 3-3.
               NONTIDAL
            NET FLOW (Urn)
TIDAL FLOW (UT)
              Figure 3-3.   Definition  of  Current Variables
EQUATIONS:  dx+  =  (Um + Utx) * t'
           dx-  =  (Um - Utx) * t'
           dy  =  Uty * t1
                  (3-2a)
                  (3-2b)
                  (3-2c)
    where   dx+  = maximum  distance travelled  downstream  parallel  to mean
                 net tidal drift  (longitudinal direction)  in m,
            dx-  = maximum  distance travelled  upstream  parallel to mean  net
                 tidal drift in m,
             dy  = maximum  distance travelled  in lateral direction on each
                 side of  axis of mean net tidal drift in m,
             Um  = mean net tidal drift in m/sec (Form DSPS),
                                   3-7

-------
            Utx = maximum tidal  velocity  parallel  to mean net  tidal  drift
                  direction  in m/sec  (Form DSP5),
            Uty = maximum tidal  velocity  perpendicular to  mean net  tidal
                  drift direction in  m/sec (Form DSPS),  and
             t1 = time for particle to reach bottom in  sec (Eq.  3-1).
EXAMPLE:
    Given
 Urn = 0.05 m/sec (Table 3-1),
Utx = 0.15 m/sec (Table 3-1),
Uty = 0.07 m/sec (Table 3-1),  and
 t1 = 6000 sec (Eq.  3-1 example),
    then    dx+ = (0.05 + 0.15)  * 6,000 = 1,200 m
            dx- = (0.05 - 0.15)   * 6,000 =  -600 m
             dy = 0.07 * 6,000          =   420 m

3.3.5  Calculate Area of Impact

The area of impact is an ellipse, and equals n  multiplied by the product of
the lengths of the major and minor axes.  The  estimate for the area will be
used to calculate the extent of  deposition on  the seafloor.
EQUATION:
A  =
         * Utx * Uty * t
                                    ,2
(3-3)
    where     A = area of impact in m ,
            Utx = maximum tidal  velocity  parallel  to mean net  tidal  drift
                  direction  in m/sec (Form DSP5),
            Uty = maximum tidal  velocity  perpendicular  to  mean  net  tidal
                  drift direction in m/sec (Form DSP5),  and
             t1 = time for particles to  reach bottom in  sec  (Eq. 3-1).
                                    3-8

-------
EXAMPLE:

    Given   Utx = 0.15  m/sec  (Table 3-1),
            Uty = 0.07  m/sec  (Table 3-1), and
             t'  = 6000  sec  (Eq.  3-1 example),

    then       A =  n *  0.15 * 0.07 * 60002 = 1.19 x 106 m2

3.3.6  Draw Area of Impact

The area of  impact  on  the  bottom is  an ellipse,  with point of disposal at
(0,0), contained within the coordinates,
                          t
        ..   _.   , .  _.  •  dx- + dx+   , .  \ / dx- + dx+
        (dx+,0); (dx-,0);
EXAMPLE:

    Given   dx+ =  1200  m,
            dx- =  -600  m,  and
             dy =   420  m,

    then    the area of  impact  is  drawn as an elipse within the four points,
           (1200,0), (-600,0), (300,420),  and  (300,-420),  on the base map,
           centered on the  point of disposal as the origin  (0,0), as shown
           in Figure 3-4.

3.4  SEDIMENT RESUSPENSION POTENTIAL FOR TYPICAL CONDITIONS

3.4.1  Purpose and Procedure

If the  waste  contains negatively buoyant solid particles that  could
accumulate on the  bottom,  calculate the potential for particle resuspension
under typical conditions.
                                   3-9

-------
                                       Point of Disposal (0,0)
(300,-4'20)
       II
  (1 200.
Figure 3-4.  Example  of Benthic Deposition Area
                     3-10

-------
The procedure involves estimating total  bottom velocity,  as the superposi-
tion of  a  wave induced  velocity,  a mean  tidal  velocity,  and a   maximum
tidal  velocity, and comparing it to  an  estimated threshold velocity.   The
wave induced velocity  is  a  function of the wave length.

To  illustrate  the method,  calculations will  be performed for a  sand
material  with  diameter 0.1  mm (150 microns)  only.   In practice,  the
calculations should be performed  for  each material  in the waste.

3.4.2   Comments

For positively or  neutrally buoyant wastes, go to Section 3.5.

For wastes  containing  negatively   buoyant solid  particles,  perform  the
calculation  below  for  each  group  of particles identified.

If  sufficient  historical  information  exists  to   determine  resuspension
estimates,  this section may be omitted.

3.4.3   Calculate Wave  Length

If  the wave length is known, go to Stage 3.4.4,  otherwise  the  iterative
procedure described below can be  used.  A first estimate of the wave length
is given  by,
EQUATION:      L  =
    where     L  =  estimate of wave length in m,
                                                         o
              g  =  acceleration due to gravity = 9.81 tn/sec , and
              T  =  wave  period in  sec (Form DSP5).

This initial  value for  the wave length, L, can then be substituted into the
right hand side  of the  complete equation describing the wave length.
                                   3-11

-------
EQUATION:     L'=
                                      *
                           * tanh   2 x

                      *
                                                                      (3-5)
    where    L'  = wave length  in m,


              h  = mean depth  in m  (Form  DSP5),  and

                                                       x  _   -x

           tanh  = hyperbolic  tangent,  e.g.  tanh (x) = -———.

                                                     ex  +  e"x
An iterative procedure is  used  in which  a  new  estimated wave  length, L'new,


is calculated
EQUATION:  L'new =
                  L1  + L
                                                                      (3-6)
and is substituted into Eq.  3-5  for  L.  The  cycle  described  by  Eqs.  3-5  and


3-6 is repeated until  the  values of  L1  and L'new are  approximately equal.





EXAMPLE:





    Given     g = 9.81 m/sec2,


              T = 6.5  sec  (Table 3-1),  and


              h = 30 m (Table 3-1),
    then
 ,
a)
                     .
                     L  =
                          9.81  *  6.5
                                        cl-  Q,
                                      =  65.97 m
                                                     (Eq.  3-4)
             „,
                                                                  (Eq. 3-5)
                       =  65.53
             c)   L'new  -  65.53 * 65.97 . 65-?5
                                                                  (Eq. 3-6)
             d)      L'  -   9.81*6.5^tanh(,,,JO
                                                                  (Eq. 3-5)
                       =  65.54
                                    3-12

-------
             e)
65.54 + 65.75
      2
                                                                  (Eq. 3-6)
             f)
, •  -  9.81 * 6.5^ *
L.  —  " ' " • "K ^_
              tanh
                                                                  (Eq. 3-5)
                       = 65.54
             g,   L'new=  65'64  t  65'54   =  65.59m
                                        (Eq.  3-6)
At this point L1  =  65.54 m and L'new =  65.59  m are reasonably close, and
the value for the wave length,  L  =  65.6 m is  selected.

3.4.4  Maximum Wave-Induced Bottom  Velocity

The  maximum  wave-induced  bottom  velocity  for a wave  of  height,  H, and
period, T, can  be estimated from  linear wave  theory.   The calculation  is
performed for a mean wave condition.
EQUATION:     Uw =
                  sinh  2n*
                                                                      (3-7)
    where    Uw = maximum wave-induced bottom velocity  in  m/sec,
              H = wave height in  m (Form DSP5),
              T = wave period in  sec  (Form DSP5),
              h = mean depth in m (Form DSP5),
              L = wave length in  m (Eqs. 3-4, 3-5,  and  3-6),  and
                                                  ex -  e"x
           sinh = hyperbolic sine,  e.g.  sinh(x)  =	«	.
                                    3-13

-------
EXAMPLE:
    Given
    then
  H = 0.5 m (Table 3-1),
  T = 6.5 sec (Table 3-1),
  h = 30 m (Table 3-1),  and
  L = 65.6 m (Final  value of Eqs.  3-4,  3-5,  and 3-6 example),
                     0.5 *
             Uw =
                           6.5
                  sinh  Zx *
                              3CJ
                        =0.03 m/sec.
3.4.5  Total  Maximum Bottom Velocity
The  total  maximum bottom  velocity is  estimated as  the  summation of  the
magnitudes of  the  mean net bottom  drift,  the maximum tidal  velocity,  and
the maximum wave-induced bottom velocity.
EQUATION:  Utot = Ubm + Ut + Uw
                                                          (3-8)
    where  Utot =
            Ubm =
             Ut =
            Utx =

            Uty =

             Uw =
      total maximum bottom velocity in m/sec,
      magnitude of mean net bottom drift in m/sec (Form DSP5),
      magnitude of maximum of Utx and Uty,
      maximum  tidal  velocity parallel to mean  net  tidal  drift
      direction in m/sec (Form DSP5),
      maximum  tidal  velocity perpendicular to  mean  net  tidal
      drift direction in m/sec (Form DSPS), and
      magnitude of  maximum  wave-induced  bottom velocity  (Eq.
      3-7).
EXAMPLE:
    Given
Ubm = 0.02 m/sec (Table 3-1),
Utx = 0.15 m/sec (Table 3-1),
Uty = 0.07 m/sec (Table 3-1),
                                    3-14

-------
             Ut  = max  (0.15, 0.07) = 0.15 m/sec, and
             Uw  = 0.03 m/sec (Eq. 3-7 example)

    then   Utot  = 0.02 + 0.15 + 0.03 = 0.20 m/sec.

3.4.6  Potential for Resuspension

Referring to Figure D-6,  or knowing  or assuming typical  grain  diameters,  a
threshold velocity, Vt,  can be  found using Figure D-7,  above which erosion
of  the  portion of the disposed waste  that  reaches  the  bottom can be
expected.   The threshold velocity is compared to the estimated total
maximum bottom velocity to  see if erosion is expected.

EQUATION:  Utot  > Vt,  site  will tend to be dispersive                (3-9a)
    or     Utot  < Vt,  site  will tend to retain waste                 (3-9b)

    where  Utot  = total maximum bottom velocity in m/sec (Eq. 3-8), and
             Vt  = threshold velocity in m/sec (Figure D-7).

EXAMPLE:

    Given  Utot  =0.20 m/sec (Eq. 3-8 example),

    then  a)  from  Figure D-7, using a typical sand diameter of 100 microns
              (0.1  mm),

              Vt ^  22  cm/sec =0.22 m/sec

          b)  from  Eq. 3-9,

              Utot  = 0.20 < Vt = 0.22

    therefore site  will tend to retain waste.
                                   3-15

-------
3.5  RESUSPENSION PROBABILITY UNDER  EPISODIC (STORM) CONDITIONS

3.5.1  Purpose and Procedure

If the  waste contains  negatively buoyant  solid particles  that could
accumulate on the bottom, calculate  the  potential for particle resuspension
under episodic (storm) conditions.

The  procedure is  a  tabular one  in which the  wave  frequencies  near the
proposed  site  are  analyzed,  and  the cumulative probability  of storm
occurrences that will cause resuspension estimated.

To illustrate  the  method, calculations will  be performed  for  a sand
material  with  diameter 0.1 mm  (100  microns)  only.   In  practice, the
calculations should be performed for each  material  in the waste.

3.5.2  Wave Frequency Tables

Obtain a wave frequency  table,  of percent occurrence  of wave height versus
wave  period, for the  site area,  or  as  close  as possible.   These are
available   for most  continental  U.S. coastal  areas  from  the  U.S.  Naval
Weather Service  Command.   Examples are included  in Tables  C-3.    In the
following  examples, frequency values denoted by "*" are < 0.05,  and  will be
ignored.

EXAMPLE:

For  the purpose of calculations  in this  section,  we have arbitrarily
selected an actual frequency table to use  for  our example (see Table 3-2).

3.5.3  Wave Induced Sediment Suspension  Figure

Referring  to Figure D-8 for sand,  D-9 for  silt, or  D-10 for clay (developed
by ASA (1983)  from  the work  of  Madson  and  Grant  (1976),  the line
corresponding to minimum  depth  at  the  site  (Form DSPS)  can be  identified.
The  line  for each  material can be either  drawn directly on  the wave

                                   3-16

-------
                                            TABLE 3-2  EXAMPLE WAVE FREQUENCY TABLE
Period
(sec)
<6
6-7
8-9
10-11
12-13
>13
INDET
TOTAL
PCT
<1
5.3
.1
*
*
.0
.0
4.0
1923
9.5
1-2
23.4
1.4
.4
.1
*
.1
.7
5291
76.0
3-4
23.3
5.6
.9
.3
.1
.1
.5
6241
30.7
5-6
8.3
7.4
1.5
.3
.2
.1
.2
3636
17.9
7
2.0
3.9
1.7
.5
.1
.1
.1
1726
8.5
8-9
.6
1.6
1.3
.3
.1
.1
.1
813
4.0
10-11
.2
.5
.6
.3
.1
*
*
373
1.8
12
*
.2
.3
.2
.1
*
*
165
.8
13-16
*
.1
.2
.2
.1
.1
*
130
.6
17-19
*
*
*
*
*
*
.0
20
.1
20-22
.0
*
*
*
*
*
.0
17
.1
23-25
.0
*
*
.0
.0
.0
*
4
*
26-32
•0
*
*
*
*
.0
.0
7
*
33-40
.0
.0
.0
*
.0
.0
.0
1
*
41-48
.0
.0
.0
.0
.0
.0
.0
0
.0
49-60
.0
.0
.0
.0
.0
.0
.0
0
.0
61-70
.0
.0
.0
.0
.0
.0
.0
0
.0
71-86
.0
.0
.0
.0
.0
.0
.0
0
.0
87+
.0
.0
.0
.0
.0
.0
.0
0
.0
Total
12873
4234
1391
473
149
103
1144
20347
100.0
Mean
Hgt
2
3
6
7
7
7
1
3

CO
I
   NOTE:  Wave heights are in feet.

-------
frequency table for  the  site (discussed in Section 3.5.2)  or else can be
directly overlaid, if the scales  are  similar.   The line drawn on the wave
frequency table represents  wave height and period  combinations  which may
induce resuspension.   All combinations  below  and  to the right of the line
will result in bottom velocities exceeding the threshold velocity.

EXAMPLE:

Given that  the minimum  depth  at the  site  = 25  m (Table  3-1),  the wave
frequency table (Table 3-2),  and Figure  D-8 for  sand, the line  representing
25 m can be drawn  on  the  wave frequency  table  as shown in Table 3-3.

3.5.4  Estimate Probability  of Resuspension

For  each  material   considered,  a  probability   of  resuspension  can  be
calculated by summing all  the percentage occurrences below and  to the  right
of the resuspension  line  (discussed  in  Section 3.5.3, and Figures D-8, D-9,
and  D-10)  on  the wave frequency table (discussed in  Section 3.5.2, and
Table C-3).

It  should be  noted  that values  in the bottom  three  rows of Table C-3
(INDET,  TOTAL, and PCT) should m>t be  included in  the summation.

EQUATION:     S =  lp(i)                                               (3-10)


    where     S =  probability of resuspension  for  material considered, and
           p(i) =  percentage  occurrence  of  a  particular  wave   height
                  combination below and to the right  of the  resuspension
                  line drawn on  the  wave frequency table  (Table C-3).
                                    3-18

-------
TABLE 3-3  EXAMPLE WAVE FREQUENCY TABLE

Period
(sec)
<6
6-7
8-9
10-11
12-13
>13
INDET
TOTAL
PCT

<1
5.3
.1
*
*
.0
.0
4.0
1923
9.5

1-2
23.4
1.4
.4
.1
*
.1
.7
5291
76.0

3-4
23.3
5.6
.9
.3
.1
.1
.5
6241
30.7

5-6
8.3
7.4
1.5
.3
.2
.1
.2
3636
17.9

7
2.0
3.9
1.7
.5
.1
.1
.1
1726
8.5

8-9
.6
1.6
1.3
.3
.1
.1
.1
813
4.0

10-11
.2
.5
.6
.3
.1
*
*
373
1.8

12
*
.2
.3
.2
.1
*
*
165
.8

13-16
*
.1
.2
.2
.1
.1
*
130
.6



17-19









*>
*
*
*
*
*
.0
20
.1
''jniiu

20-22
.0
*
*
*
*
*
.0
17
.1

23-25
.0
*
*
.0
.0
.0
*
4
*

26-32
.0
*
*
*
*
.0
.0
7
*

33-40
.0
.0
.0
*
.0
.0
.0
1
*

41-48
.0
.0
.0
.0
.0
.0
.0
0
.0

49-60
.0
.0
.0
.0
.0
.0
.0
0
.0

61-70
.0
.0
.0
.0
.0
.0
.0
0
.0

71-86
.0
.0
.0
.0
.0
.0
.0
0
.0

87+
.0
.0
.0
.0
.0
.0
.0
0
.0

Total
12873
4234
1391
473
149
103
1144
20347
100.0
Mean
Hgt
2
3
6
7
7
7
1
3


-------
EXAMPLE:
    Given  a wave  frequency  table  (Table 3-2), the  resuspension  line for
           sand (Figure  D-8)  and the overlay of the two  (Table 3-3),

    then  S(sand)  = 2p(i  -  sand line in Table 3-3) = 7.8 percent,
3.5.5  Threshold Velocity  Correction

The above technique (Sections  3.5.2-3.5.4)  does not account for the effects
of mean and tidal  velocities in  estimating  resuspension possibilities.  The
above estimate is improved by  estimating a  new threshold velocity.
EQUATION:   Vtnew = Vt -  Ubm -  Ut
                                                        (3-11)
    where  Vtnew =
              Vt =

             Ubm =
              Ut =
             Utx =

             Uty =
      new threshold velocity  in  m/sec,
      magnitude of  old  threshold  velocity  in m/sec  (Section
      3.4.6),
      magnitude of mean  net bottom drift  in  m/sec  (Form DSP5),
      magnitude of maximum of Utx and Uty,
      maximum  tidal velocity parallel  to mean  net surface
      drift direction  in m/sec (Form DSP5),  and
      maximum tidal  velocity  perpendicular  to  mean net surface
      drift direction  in m/sec (Form DSP5).
EXAMPLE:
    Given
 Vt = 0.22 m/sec (Section  3.4.6  example),
Ubm = 0.02 m/sec (Table 3-1),
Utx = 0.15 m/sec (Table 3-1),
Uty = 0.07 m/sec (Table 3-1),  and
 Ut = max (0.15, 0.07)  = 0.15  m/sec,
    then   Vtnew = 0.22 -  0.02  -  0.15  =  0.05  m/sec.
                                   3-20

-------
3.5.6  Probability  of Resuspenslon Correction

Using the  new  estimate  for the  resuspension  threshold  velocity  from Eq.
3-11,  the probability  of resuspension, estimated in Eq. 3-10,  can be
corrected  to  account  for  other  than wave-induced  ocean  currents alone.
This is  done  by calculating wave-induced bottom  velocities  for  all  wave
height and  period  combinations  not  considered in  the  calculation  of Eq.
3-10 (i.e.  those  combinations  above  and to  the  left  of  the  depth  line
overlaying the wave frequency table), and comparing each value to the new
threshold velocity of  Eq. 3-11.   If the wave-induced bottom  velocity
exceeds  the  new threshold velocity,  its associated percent frequency of
occurrence, p(i),  should be  added to the probability of resuspension, S,
estimated in Eq. 3-10.

This  is  a  three-step process  (see  Figure 3-5),  with each  step being
repeated for each  wave  height and  period combination not  previously
considered.   This  entire procedure  is  repeated  for each  material   (e.g.
clay, sand, silt, etc.).

Step 1 -  Select a  wave height and period combination not previously  used,
         and   calculate   the  wave-induced   bottom current   using   the
         calculations  of  Sections   3.4.3   and  3.4.4   (Note   that   these
         calculations are  performed in metric units and  the  values of  Table
         3-3 are in  English units).

EXAMPLE:

Given that  we  are  calculating  the  probability of resuspension for 0.1 mm
diameter  sand, we  must also consider  those wave height  (H)  and period (T)
combinations which  were  not used for  the example  calculation of Eq.  3-10.
In Table  3-3, these values lie  above and to the  left of the depth line for
                                   3-21

-------
sand, and  are  listed in  the  first two  columns of Table  3-4, with  these
tabulated values representing mid-values  of the range  of  values in  Table
3-3.  Consider  for  example

H = 7 ft (2.1 m) and T  =  6  to 7  sec,  represented by 6.5  sec  (underlined  in
                               Table  3-4),

then performing the calculations of Section 3.4.3  (Column 3 of Table 3-4)
and 3.4.4,  the wave-induced bottom velocity, or orbital  velocity  (Column 4
of Table 3-4),  is

         Uw = 0.11  m/sec.

Step 2 - Compare with  new  threshold  velocity.

EXAMPLE:

    Given    Uw =   0.11 m/sec, and
           Vtnew =   0.05 m/sec  (Eq.  3-11  example),

    then     Uw >  Vtnew

and  the  wave height and  period  combination  (H  =  7  ft, T  =  6  to 7 sec)
should  be  included in  the  probability of resuspension.    (Note:   If Uw <
Vtnew,  then  step 3 is  omitted and  the procedure  repeated  for a new wave
height/period combination.

Step 3 - Compute new probability  of  suspension.

EXAMPLE:

    Given that   (1)  the wave  height and  period combination  (H =  7  ft, and
                     T  =  6  to  7  sec,  columns 1 and 2  in Table 3-4)  should
                     be  included  in  the probability of resuspension,
                                    3-22

-------
                          STEP 1: Select wave
                        height/period combination
                        not used  in Section 3.5.4
                        calculate wave-induced
                          bottom velocity, Uw
                                                NO
                        STEP 3: Add associated
                            % frequency of
                         occurrence P(i) to the
                           previous total, S

                        S(material) = S(material)
                   NO
  Have all
height/period
combinations
  now been
sponsiderecL
Figure  3-5.  Flowchart for the Estimation  of Resuspension
              Correction  in Section  3.5.6.  for each  Material
                             3-23

-------
                                        TABLE 3-4

             CALCULATION  EXAMPLE  OF RESUSPENDING WAVE ORBITAL VELOCITY FOR SAND
1
Height
(ft)
0.5
0.5
0.5
0.5
0.5
0.5
1.5
1.5
1.5
1.5
1.5
1.5
3.5
3.5
3.5
3.5
3.5
3.5
5.5
5.5
5.5
+ 5.5
+ 5.5
+ 5.5
7.0
7.0
+ 7.0
+ 7.0
+ 7.0
+ 7.0
2
Period
(sec)
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3
Length
(m)
14
65
106
106
187
234
14
66
106
147
187
234
14
66
106
147
187
234
14
66
106
147
187
234
14
66
106
147
187
234
4
Speed
(m/sec)
0.00
0.00
0.00
0.01
0.03
0.03
0.00
0.02
0.05
0.08
0.09
0.10
0.00
0.05
0.13
0.19
0.22
0.24
0.00
0.09
0.21
0.30
0.35
0.39
0.00
0.11
0.27
0.38
0.45
0.49
5
Percent
Occurence
5.3
0.1
*
*
0.0
0.0
23.4
1.4
0.4
0.1
*
0.1
23.3
5.6
0.9
0.3
0.1
0.1
8.3
7.4
1.5
0.3
0.2
0.1
2.0
3.9
1.7
0.5
0.1
0.1
1
Height
(ft)
8.5
8.5
+ 8.5
+ 8.5
+ 8.5
+ 8.5
10.5
+ 10.5
+ 10.5
+ 10.5
+ 10.5
+ 10.5
12.0
+ 12.0
+ 12.0
+ 12.0
+ 12.0
+ 12.0
14.5
+ 14.5
+ 14.5
+ 14.5
+ 14.5
+ 14.5






2
Period
(sec)
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0
3.0
6.5
8.5
10.5
12.5
15.0






3
Length
(m)
14
66
106
147
187
234
14
66
106
147
187
234
14
66
106
147
187
234
14
66
106
147
187
234






4
Speed
(m/sec)
0.00
0.14
0.33
0.46
0.54
0.60
0.00
0.17
0.41
0.57
0.67
0.74
0.00
0.19
0.47
0.66
0.77
0.85
0.00
0.24
0.57
0.79
0.93
1.03






5
Percent
Occurrence
0.6
1.6
1.3
0.3
0.1
0.1
0.2
0.5
0.6
0.3
0.1
*
*
0.2
0.3
0.2
0.1
*
*
0.1
0.2
0.2
0.1
0.1






NOTE:   1 and 2 are wave height (H)  and  period  (T)  combinations  (combinations  used in the
       calculation of Eq.  3-10 are  denoted  by  "+"  and  are  not used  in  Section 3.5.6).
       3 is wave length of above  wave height and  period  combination
       4 is wave-induced bottom velocity  or orbital  velocity.
       5 is percent occurrence for  wave height (H)  and period (T) combination (* denotes a
       value < 0.05 and is ignored  for  calculation  purposes).
                                           3-24

-------
                (2)  the associated percentage  frequency of occurrence p(i)
                    (column 5 of Table 3-4), is

                        p(H  =  7 ft,  T = 6 to  7   sec)  = 3.9 percent (This
                        value  is  obtained  from  Table  3-3  by moving along
                        the  row 6-7  sec until arriving at  column  7  feet
                        and is shown  in Table  3-4, column 5) and

                (3)  the  previous probability of resuspension for  sand
                    S(sand) = 7.8 percent

    then  S(sand) = 7.8 + 3.9 = 11.7  percent

NOTE:   If this  example  is completed  for all  wave  height  and  period
       combinations not considered in  Section 3.5.4, then,

       S(sand) = 23.8 percent.

3.6  ESTIMATE ANNUAL SEDIMENT TRANSPORT RATE

3.6.1   Purpose and Procedure

The annual  sediment  transport  rate   for  each material considered (e.g.
medium sand,  coarse  sand,  etc.) is estimated to  determine  whether  or not
the site will tend to accumulate material.

The procedure is to perform a mass balance with the annual loading rate and
the transport rate.

To  illustrate  the method, calculations  will  be performed for  a  sand
material  with  diameter  0.1 mm (100 microns)  only.   In  practice,  the
calculations should be performed for each material in the waste.
                                   3-25

-------
3.6.2  Estimate Resuspending Wave  Orbital  Velocity

For  each percent  occurrence  value, p(i),  of a wave  height  and period
combination that will  probably cause resuspension  under episodic  (storm)
events, a resuspending wave  orbital  velocity  can  be calculated by  summing
all  the  percentage  values  multiplied  by  their  respective wave-induced
bottom  velocities  (calculated  using  Section  3.4.3  and 3.4.4) and  dividing
by the probability  of occurrence,  for each material  considered.
EQUATION:    Uw =
                    p(i)  * Uw(i)
(3-12)
    where    Uw = resuspending  wave  orbital  velocity in m/sec,
           p(i) = percent occurrence of  each wave height  (H), and  period
                  (T)  combination  that can cause resuspension,
          Uw(i) = wave-induced  bottom velocity  for each wave height  (H) and
                  period (T)  combination  that can cause resuspension (using
                  calculations  of  Sections 3.4.3 and 3.4.4), and
              S = probability of occurrence  (Section 3.5.6).
EXAMPLE:
    Given  (1)   the  wave   height   and  period  combinations  that  cause
                resuspension under  episodic  (storm) conditions  from Section
                3.5,

           (2)   the  corresponding  percent  occurrence  values,  p(i),  from
                Table 3-3  or column 5  of Table  3-4,

           (3)   the  corresponding  wave-induced  bottom  velocities,  Uw(i)
                calculated  using  Sections  3.4.3  and  3.4.4  (column  4  of
                Table 3-4),
                                   3-26

-------
           (4)   the  sum  of multiples of  percent  occurrence values, P(i),
                and  corresponding  wave-induced  bottom  velocities,  Uw(i)
                (found by  multiplying  columns  4  and  5 in  Table  3-4)  for
                those   wave   height/period   combinations   that   cause
                resuspension:

                Lp(i)  Uw(8)  =  4.94
                 i

           (5)   S(sand)  = 23.8 percent,
                      4 Q4
    then   Uw(sand)  = -      =  0.21 m/sec,
3.6.3  Annual  Unit Sediment Transport  Rate

Using prepared curves for clay  (Figure D-ll),  silt  (Figure D-12),  very fine
sand (Figure D-13),  and  fine sand  (Figure  D-14), the annual  unit sediment
transport rate per meter  of site width,  Qs,  for each material considered,
can be read from the  appropriate graph.

EXAMPLE:    (note:    values  from  previous  examples  do not  cover  sediment
           transport, thus for  calculations in Sections 3.6.3 - 3.6.6, new
           values that would cause  sediment transport  are used)

    Given  (1)  Fine  sand (Figure 3-6),

           (2)  Mean  net bottom drift,  Ubm = 0.3 m/sec = 30  cm/sec  (a new
                value for this  example only),  and

           (3)  Wave-induced bottom velocity  (Eq.  3-12  example)  Uw  = 0.21
                m/sec = 21.0 cm/sec,

    then    from Figure 3-6,

                                                          3
           annual unit sediment transport rate,  Qs  = 4000 m /m/yr.
                                    3-27

-------
      10'
      10C
      10"
CO
      10'
      101
     10'
          1 Uw=20 cm/sec
       FINE  SAND  (0=0.187 mm)
        I _ I _ 1 _ I
                                                         1      1
               20     30     40     50     60     70     80    90     100
                                   Ubm(cm/sec)
          Figure  3-6.
Volumetric Sediment Transport Rate Versus Mean Flow  for
Various Wave Induced Bottom Velocities  (Source:   Applied
Science Assoc.,  Inc.)
                                   3-28

-------
3.6.4  Annual Sediment Transport Rate

The annual  sediment  transport rate  is  the  annual  unit  sediment  transport
rate multiplied  by  the width of  the benthic receiving  area  calculated  in
Section 3.3.4,
EQUATION:
    where
Qt = B * Qs
                                        (3-13)
                                        o
Qt = annual sediment transport rate in m/yr,
 B = width of the benthic receiving area in m (= 2 * dy),
dy = maximum distance travelled, in m, in lateral direction on
     each  side of  axis  of mean net surface  drift (Eq.  3-2c),
     and
Qs '= annual  unit sediment transport  rate  in m /m/yr (Section
     3.6.3).
EXAMPLE:
    Given    dy = 420 m (Eq.  3-2c example)
              B = 2 * dy = 840 m, and
             Qs = 4000 m3/m/yr (Section 3.6.3 example),
    then
Qt = 840 * 4000 = 3.4xl06 m3/yr.
3.6.5  Potential  for Mounding

If the annual sediment transport rate exceeds  the  annual  disposal  rate,  no
long-term mounding  is  expected.   If  the  annual  disposal  rate  exceeds  the
annual sediment transport rate,  long-term  mounding can be expected, and  the
calculation should proceed to Section 3.6.6.
EQUATION:
Qt > Qa
Qt < Qa
implies no mounding
implies mounding
(3-14a)
(3-14b)
    where    Qt = annual  sediment transport rate (Eq.  3-13), and
             Qa = annual  disposal  rate (Form DSP2).
                                    3-29

-------
EXAMPLE:

    Given    Qt = 3.4xl06 m3/yr (Eq.  3-13  example),  and
             Qa = 5.0xl06 m3/yr (Table  2-1),

    then     Qt < Qa

    and long-term mounding is  expected.

3.6.6  Recalculation for Long-Term Mounding

If long-term mounding  is anticipated,  from Section  3.6.5,  the site  depth
will  decrease with time,  and the  annual sediment transport  rate will
increase, until an equilibrium condition is reached.  The equilibrium site
depth can  be estimated  by  selecting a shallower site  mean depth, h, and
repeating all the calculations in Stage 3  until the  annual  sediment  trans-
port rate (Eq.  3-13) equals the annual  disposal  rate (Form DSP2)  in Section
3.6.5.

3.7  CALCULATE  AND MAP  TYPICAL LONG-TERM  TRANSPORT CONTOURS

3.7.1  Purpose  and Procedure

Long-term  transport contours,  for  the   positively or  neutrally buoyant
portion of the  waste, are calculated  and  mapped to illustrate the  far field
dilution associated with unit  concentration waste loadings under  conditions
of ambient advection and dispersion.

The procedure  is  to  use  closed-form, two-dimensional, horizontal  solutions
of the steady-state mass transport equation,  for both point  and distributed
sources.  A  complete discussion of  these  equations and background  can  be
found in Fischer et al.  (1979).
                                    3-30

-------
3.7.2  Select Appropriate Contour Mapping Methodology

If the mean net surface  drift is  less  than  the mean magnitude of the tidal
current parallel to it (x-direction) over 1/2  tidal  cycle  then overlapping
of various disposal  plumes might be expected and a continuous release plume
model  should  be used.   Otherwise a discrete  point source  or distributed
source model  should be used.

EQUATION:     If Um < Utx  * */4 then follow Sections 3.7.3-3.7.5.    (3-15a)

             If Um > Utx  * */4 then follow Sections 3.7.3,  3.7.4, 3.7.6,
             and 3.7.7                                              (3-15b)

    where    Um = mean net surface drift (Form DSP5), and
            Utx = maximum tidal  velocity parallel  to mean net surface drift
                  direction,  in m/sec (Form DSPS).

EXAMPLE:

    Given    Um = 0.05 m/sec  (Table 3-1), and
            Utx = 0.15 m/sec  (Table 3-1),

    then      0.05 < 0.15  * */4 = 0.12

    and Sections 3.7.3-3.7.5  should be  followed.

3.7.3  Estimate Tidal  Excursions

To estimate dispersion coefficients  in the  x-  and y-directions,  the tidal
excursion in these directions is needed.
EQUATION:    Lx = Utx * I  *  -                                      (3-16a)
             Ly = Uty *    *-                                       (3-16b)
                                    3-31

-------
    where    Lx =  tidal   excursion  parallel  to  mean  net  surface  drift
                  direction  in m,
             Ly =  tidal  excursion perpendicular  to  mean  net surface drift
                  direction  in m,
            Utx =  maximum tidal  velocity,  parallel  to  mean  net  surface
                  drift direction in m/sec  (Form  DSPS),
            Uty =  maximum tidal  velocity perpendicular to mean net surface
                  drift direction in m/sec  (Form  DSPS), and
             To =  period in  sec.
EXAMPLE:
    Given   Utx =  0.15  m/sec  (Table 3-1),
            Uty =  0.07  m/sec  (Table 3-1), and
             To =  12.42 hr  =  44712 sec  (Table 3-1),
    tnen
i v - n
LX - U.
                                          m
                                          m
                         AA.TIO    n
             Ly =  0.07  *  -^4^- * x =  1229 m
3.7.4  Estimate Dispersion  Coefficient

Using the tidal excursion lengths from Section 3.7.3, dispersion coeffici-
ents  can  be  estimated  in  the  x-  and  y-directions  using  a conservative
simplification of the "four-thirds rule"  (Okubo,  1971).
EQUATION:
 Dx = 0.0018 * Lx
 Dy = 0.0018 * Ly
(3-17a)
(3-17b)
    where  Dx,Dy = dispersion  coefficients  parallel  and  perpendicular to
                                                                    o
                   the  mean   net   surface  drift  direction  in  m/sec,
                   respectively,  and
           Lx,Ly = tidal excursions  parallel  and perpedicular to the mean
                   net surface  drift direction  in m,  respectively (Eq.
                   3-16).
                                   3-32

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EXAMPLE:
    Given     Lx =  2634 m  (Eq. 3-16a example), and
              Ly =  1229 m  (Eq. 3-16b example),
then
              Dx =  0.0018  * 2634 = 4.7
              Dy =  0.0018  * 1229 = 2.2 m2/sec
3.7.5  Two-Dimensional  Continuous Point Source Plume Model

If the mean  net surface drift, Urn, is less  than  the  mean tidal  velocity,
Utx *Jt/4, the site is  assumed  to behave as a continuous point source under
successive disposals.   In  this  case, use a two-dimensional continuous point
source plume  model  with  unit  loading (q  =  1) to  develop characteristic
concentration contours.
EQUATION:  C(x,y)   =
q
d *
exp
( 4 n * Dy *
[ & \
[\ )
Urn * x
Urn
4 * Dy
,1/2
* X
                                                                    (3-18)
    where
              C(x,y)  =  concentration  at coordinate x,y  (with  x=0,  y=0
                       as  point of disposal),
                   q  =  mass  input rate/sec  (=1 for unit contours),
                   d  =  calculation depth  in m  (d =  hp if above  the
                       pycnocline, d  =  h -  hp if below the pycnocline,
                       or  d  =  h if  entire water column  depending on
                       application),
                  hp  =  pycnocline depth  (Form DSPS),
                   h  =  mean  depth (Form  DSP5),
                  Dy  =  dispersion coefficient perpendicular to mean net
                       surface  drift direction  in m2/sec  (Eq. 3-17b),
                       and
                  Urn  =  mean  net surface  drift (Form DSPS).
                                   3-33

-------
EXAMPLE:
    Given     calculation above  pycnocline,
              x = 2 km = 2000 m,
              y = 1 km = 1000 m,
              q = 1 g/sec (for unit  contours),
              d = hp = 20 m (Table 3-1),
                       2
             Dy = 2.2 m /sec  (Eq. 3-17b example), and
             Urn = 0.05 m/sec  (Table  3-1),
    then          C(2000,  1000)  =
                                   20  *  (4** 2.2 * 0.05 * 2000)1/2
                  * exp
-1000
                               2U      0.05
                                   4  *  2.2  *  2000

                = 5.55xlO"5  g/m3  or ppm

    The above example calculates  the  concentrations,  for  a  unit  loading, at
    a  single  point  (x = 2000  m,  y =  1000 m).   By  applying Eq. 3-18 for
    several  x, y  locations,  concentration  contours  can  be drawn from the
    center of the site,  which is  the  origin (x = 0, y = 0).

    An  example of concentration  contours  for  a unit  loading is given in
    Figure 3-7.  For  this  particular example,  the contours  were  developed
    by calculating and plotting the concentrations  for several sets  of  x, y
    coordinates on a  rectangular  grid.   Then,  the concentrations contours
    were  formed  by   interplotating   between the  calculated  values  and
    sketching lines  of equal  concentration.

3.7.6  Two-Dimensional Discrete Point Source  Model
If the mean net surface drift,  Urn,  is  greater than  the  mean tidal  velocity,
Utx *  */4, the site  is  assumed  to  behave  as a series  of discrete loadings
which never merge.   In this model,  the source is also assumed  to be  small
                                    3-34

-------
                         STATEJJNE
                         STATE LINE
                                                           SPORT
                                                          FISHING
NEW CITY
                       ~ ~ -~ Z SHIPPING LANE ~ ~ ~
                        DISPOSAL
                        SITE
                          0.001

                          0.00025
                              INDUSTRIAL
                              DISPOSAL
                    0.00012

                    0.0001
                                               0          25
                                               I   I  I  I   I  I
                                                KILOMETERS
Figure 3-7.   Concentration  (g/m3) Contours for Unit Load at Point of
             Disposal,  Assuming  Continuous Point Source
                                3-35

-------
enough to be considered a point source when  viewed from the  far  field.  The
following  two-dimensional  equation discribes  the horizontal  movement and
dispersion of the plume through time.
EQUATION:       C(x,y,t)  =
                             4* * d * (Dx  *  Dy)1/2  *  t
                    exp
•(x  -  Um*t)2       y2
 4 * Dx  *  t   "  4  *  Dy  *  t
(3-19)
    where  C(x,y,t)  = concentration at coordinates  x,y  at time  t  (with  x=0,
                      y=0,  t=0 as the point and time of disposal),
                  Q  = mass  unit (= 1 for unit  contours),
                  d  = calculation depth  in  m  (d =  hp  if  above pycnocline,
                      d =  h  - hp if below pycnocline, and d = h if  entire
                      water column, depending  on application),
                 hp  = pycnocline depth (Form DSPS),
                  h  = mean  depth (Form DSP5),
              Dx,Dy  = dispersion coefficients  parallel  and perpendicular  to
                      mean  net  surface  drift  direction, respectively,  in
                      m2/sec  (Eq. 3-17), and
                 Dm  = mean  net surface drift in m/sec (Form DSP5).
EXAMPLE:

    Given
              calculation above pycnocline,

              x = 920 m,
              y = 300 m,
              t = 1 hr =  3600 sec,
              Q = 1 g (for unit contours),
              d = hp = 20 m (Table  3-1),
             Dx = 4.7 m2/sec (Eq. 3-17a example),
                                    3-36

-------
             Dy =  2.2  m2/sec  (Eq. 3-17b example), and
             Urn =  0.2  m/sec  (chosen here to imply discrete sources from
                  Eq.  3-15b),
    then          0(920,300,3600) =
                                     4* * 20 *  (4.7 * 2.2)    * 3600
                  * exp
                         -(920 - 0.2*3600)2        3002
                              4.7 * 3600      4 * 2.2 * 3600
                         -8    3
                = 1.11x10"   g/m  or  ppm

The  above  example  calculates  the  concentrations  for a  unit load,  at a
single point in space (x = 920 m, y = 300  m)  and time (t = 3600 sec).  By
applying  Eq.  3-19  for  several  x, y  locations  at different t  times,
concentration contours can  be  drawn from the  point  of  disposal,  which is
the origin  (x = 0,  y = 0).

An example  of concentration  contours for  a  unit load  at times of 2, 10, and
20 hours is given in Figure  3-8 with the  positive x -  direction parallel to
the  mean  net  surface drift, Urn,  the y-direction   perpendicular  and the
origin at the point of disposal.   For  this  particular example, the contours
were  developed  by calculating  and plotting on a  rectangular  grid the
concentrations for several  sets of x,  y coordinates  at the three different
times.   Then,  the  concentration  contours were formed  by  interpolating
between the  calculated values and sketching lines  of equal concentration.
For this example, the concentrations,  the x, y  coordinates, and the various
times were chosen  to  produce the  three  separate sets of contours as  shown
in Figure 3-8.

3.7.7  Two-Dimensional Discrete Distributed  Source Model
If the mean net surface drift,  Urn,  is  greater  than the mean tidal velocity,
Utx**/4, the  site  is  assumed  to  behave as a  series  of discrete loadings
which never merge.   In this model,  the source is  assumed  to have finite
                                   3-37

-------
Figure 3-8.   Concentration  (g/m  )  Contours  for  Unit  Load  at  Point
             of Disposal  Assuming  Discrete  Point  Source
                             3-38

-------
dimensions  (distributed) produced  by  a moving barge.   The following  two-
dimensional  equation  describes  the   horizontal  movement  and  dispersion
through time of the liquid  phase  of the waste,  and  is  best applied within  a
short distance and time of  the initial  disposal.
EQUATION:
C(x,y,t) =      *
             4
erf
 Tj- - x + Um*t
(4 * Dx * t)1/2.
                    erf
       f + x - Um*t
      (4 * Ox * t)1/2J
                     erf
                           (4  * Dy  * t)1/2.
                          + erf
                                                       !*
                                 (4 * Dy * t)1/2
                                 (3-20)
    where  C(x,y,t)  = concentration  at coordinates  x,y  at time  t  (with  x=0,
                      y=0,  t=0  as  the  point  and  time  of disposal),
                 Co  = initial  contaminant concentration  (=1  for unit  con-
                      tours),
                erf  = error function (Table  C-2),
                  b  = v * t'  initial plume dimension  along the  x-axis in m,
                       v =  disposal  vessel speed in m/sec (Form DSP2),
                       t'=  individual  disposal duration in sec  (Form DSP2),
                  a  = 2 * w initial  plume dimension along the y-axis in m
                       w =  disposal  vessel width in m (Form DSP2),
                 Urn  = mean  net  surface drift in  m/sec (Form DSP5),  and
              Dx.Dy  = dispersion coefficients parallel  and perpendicular to
                      mean  net  surface drift direction, respectively, in
                      m2/sec  (Eq.  3-17).
EXAMPLE:
    Gi ven
x = 460 m,
y = 100 m,
t = 0.25 hr = 900 sec,
                                    3-39

-------
    then
                 Co  =  1  g/nr*  or  ppm  (for  unit contours),
                  v  =  1.0  m/sec  (Table  2-1),
                  t'=  200  sec (Table 2-1),
                  w  =  20 m (Table  2-1),
                  b  =  v  *  t = 1.0  *  200 = 200 m
                  a  =  2w = 2  * 20  =  40  m
                 Urn  =  0.2  m/sec  (chosen here to imply discrete  source  from
                      Eq.  3-15b),
                 Dx  =  4.7  nf^/sec (Eq. 3-17a example),  and
                 Dy  =  2.2  m2/sec (Eq. 3-17b example),
                  0(280,100,900)  =[ - 1*
                                   4
                 200
                                                   -  280  +  0.2*900
            erf
                    (4 * 4.7 * 900)1/2
                  + erf
                          1200
                          ~r
+ 280 - 0.2*900
                           (4 * 4.7  * 900)1/2
                     erfl
                                40
                                T
     - 100
                        1(4 * 2.2 * 900
               1+ erfl
100
                      (4 * 2.2 * 900) 1/2
                = 0.037 g/m3 or ppm

The above  example calculates  the  concentration for  an  initial unit  con-
taminant concentration at a  single point in space  (x  =  280 m, y =  100  m)
and time (t =  900 sec).   By applying Eq. 3-20  for  several  x,  y locations,
at different t  times,  concentrations contours  can be  drawn  from the point
of disposal,  which is the origin (x = 0,  y = 0).

An example of concentration  contours, for a unit concentration, at times of
0.5 and  1.5  hours is given in  Figure  3-9 with the positive x - direction
parallel to the mean net surface drift, Urn,  the y - direction perpendicular
                                    3-40

-------
and the origin at the point of disposal.   For this particular example,  the
contours were developed by calculating and plotting on  a  rectangular  grid
the  concentrations  for  several sets  of x,  y coordinates at  the  two
different  times.    Then,  the  concentration   contours  were  formed   by
interpolating between the  calculated  values  and sketching lines of  equal
concentration.  For this example, the concentrations, the x, y coordinates,
and  the  various times were  chosen  to produce  the two separate  sets  of
contours as shown in  Figure 3-9.
                                   3-41

-------
               KILOMETERS
              0         1
                    30M
                                   DISPOSAL SITE
                                   BOUNDARY
                                    Point of Disposal


                                t = 0.5  hrs
                            t= 1.5 hrs
Figure 3-9.  Concentration (g/m )  Contours  for Unit Load
            at Point of Disposal  Assuming  Discrete Point Source
                        3-42

-------
         STAGE 4.   INITIAL MIXING  AND  SOURCE  STRENGTH  CALCULATIONS
4.1  INTRODUCTION

The  purpose  of  this stage  (see  flow chart in  figure  4-1)  is to  estimate
initial dilutions of the  liquid  phase in the wake of  the barge,  fractions
of the waste  throughout  the water column, and waste concentrations  in  the
bottom sediments.   The  liquid  phase of  the  waste is  assumed to be well
mixed in the zone of initial mixing  generated by  barge-induced turbulence,
and  subsequently  throughout the water  column  under  conditions of ambient
turbulence.   In order to  make  these assumptions, it  is assumed that  the
disposal  operations occur while  the barge is  moving.  Further,  the estimate
of constituent  concentrations in  this stage are  independent of  background
concentrations and can  be superimposed (in Stage 5).

4.2  FORMS

To perform the  analyses of  Stage 4,  information  from Forms  DSP2,  DSPS,  and
DSPS are used.   Forms  DSP2 and DSPS  were  filled  out  in Stage 2,  and Form
DSPS was filled out in  Stage 3.

4.3  INITIAL DILUTION OF  LIQUID  PHASE

4.3.1  Purpose and Procedure

The initial dilution of the liquid phase of the  disposed waste  is estimated
from barge-induced  turbulent mixing.   It represents an  immediate dilution
rather than  the 4-hour  approximation  used  in  U.S.  EPA/COE  (1977).   The
4-hour dilution  (CFR #40.22721)  is calculated in Stage  5 for  constituents
exceeding EPA Acute Water Quality Criteria.

The  procedure  is  to use an  empirical formula which describes  the  initial
mixing volume generated  by  a  typical barge.   The equivalent depth of this
mixing volume is estimated  from site  characteristics.   The  liquid and sus-
pended  particulate  phases  are  assumed  to be  completely  mixed into  the
mixing volume.
                                    4-1

-------
          SECTION
            4.3
            4.4
            4.5
   Initial dilution
   of liquid phase
                                              I
  Source strengths
and initial conditions
                                              I
Vertical  distribution
   of constituent
   concentrations
Figure 4-1.   Stage 4,  Initial  Mixing and  Source Strength Overview
                            4-2

-------
4.3.2  Equivalent Depth

The equivalent depth,  d,  is  the minimum of the mean  depth,  h  (Form DSPS),
the pycnocline depth, hp (Form DSPS),  or a default value of 20  m.

EXAMPLE:
    Given     h = 30 m (Table 3-1),  and
             hp = 20 m (Table 3-1),

    then      d = minimum (30,  20,  20)  = 20 m

4.3.3  Initial  Liquid Phase Mixing  Zone Volume

The initial mixing  zone  volume  produced by a moving  barge  is the affected
cross-sectional area (assumed to be  twice the barge width multiplied by the
equivalent depth) multiplied  by the length  of  the disposal  track,  and is
empirically defined by
EQUATION:   Vm = d * (2w)  * v * t
                                                        (4-1)
    where    Vm = initial  mixing zone volume in m ,
              d = equivalent depth in m (Section 4.3.2),
              w = disposal vessel  width in m (Form DSP2),
              v = disposal vessel  speed in m/sec (Form DSP2), and
              t = individual disposal duration in sec (Form DSP2).
EXAMPLE:
    Given
d = 20 m (Section 4.3.2 example),
w = 20 m (Table 2-1),
v = 1.0 m/sec (Table 2-1), and
t = 200 sec (Table 2-1),
    then     Vm = 20 * (2*20)  * 1.0 * 200 = 160,000 m3,
                                    4-3

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4.3.4  Calculate Liquid Fraction

If  the  liquid  fraction of the waste  is  unknown (Form DSP2), but  specific
gravities are known, then the liquid fraction of the  total waste is calcu-
lated from a ratio of specific  gravities.
EQUATION-  Fl  =  S?jbu1k)  "  sg(particle)
tquAiiUN.  M    sg(liquid) - sg(particle)
                                                         (4-2)
    where              Fl  = liquid fraction,
                            bulk  specific  gravity  (Form DSP2)
                            particle  phase  specific gravity  (Form DSP2),
                            and
               sg(liquid)  = liquid phase specific  gravity  (Form DSP2).
          Fl
    sg(bulk)
sg(particle)
EXAMPLE:

    Given        sg(bulk)  =  1.7  (Table  2-1),
             sg(particle)  =  2.65 (Table 2-1),
               sg(liquid)  =  1.0  (Table  2-1),

    then     Fl  = i'Z "  HE = 0.58
                  l.U -  
-------
EXAMPLE:

    Given    Fl  =0.58 (Eq. 4-2 example),

    then     Fs = 1  -  0.58 = 0.42

4.3.6  Immediate Dilution of the Liquid Phase

The  initial  dilution of  the liquid phase  of the  total  waste is  the
volumetric ratio of the  volume  of the liquid  phase  to  the initial  mixing
zone volume generated  by the barge-induced turbulence.
EQUATION:
Dl  =
Fl  * Vb
  Vm
                                                                     (4-4)
    where    Dl  = initial  dilution of liquid phase,
             Fl  = liquid fraction of the waste  (Form DSP2 or Eq. 4-2),
             Vb  = volume of  barge in m3 (Form DSP2), and
                                                o
             Vm  = initial  mixing zone volume in m   (Eq. 4-1).
EXAMPLE:
    Given    Fl  =  0.58  (Table  2-1 or Eq. 4-2 example),
             Vb  =  4000  m3  (Table 2-1), and
             Vm  =  160,000  m3  (Eq. 4-1 example),
    then
       °-58  * 40°°
         160,000
                                 = 0 015
                                   U-Ui;s
4.3.7  Immediate Dilution  of  the  Suspended Particulate Phase
The initial  dilution of the suspended particulate phase of the total waste
is the volumetric ratio of  the  suspended particulate phase to the initial
mixing zone volume generated by the barge induced turbulence.  Ff * Ffs is
the product  of the  fraction  of  total  solids  which  is composed  of  fine
particles  of  diameters less than  0.1 mm multiplied  by the estimated
fraction of these  fines which  remain  in  the water column.
                                    4-5

-------
EQUATION:    Ds =
Fs * Vb * Ff * Ffs
        Vm
                                                                      (4-5)
    where    Ds = Initial  dilution  of  the  suspended  particulate phase,
             Fs = solid fraction  of the  waste  (Form  DSP2 or Eq. 4-3),
             Vb = volume of the barge  in m3  (Form  DSP2),
             Ff = fine fraction  (Form  DSP2),
            Ffs = fraction of fines in suspended  particulate  phase  (Form
                  DSP2), and
             Vm = initial  mixing  zone  volume (Eq.  4-1).
EXAMPLE:
    Given    Fs = 0.42 (Table  2-1  or Eq.  4-3  example),
             Vb = 4,000 m3 (Table  2-1),
             Ff = 0.41 (Table  2-1),
            Ffs = 0.90 (Table  2-1),  and
             Vm = 160,000  m3  {Eq.  4-1  example)
    then     nc _ 0.42 * 4,000  * 0.41  *  0.90   n  nn,Q
             us            160,000:u.uujy
4.4  SOURCE STRENGTHS AND INITIAL  CONDITIONS

4.4.1  Purpose and Procedure

The  source  strengths and initial  conditions  are estimated throughout  the
water column  and  bottom, for further  dilution  and water quality  criteria
comparisons.

The  following procedure  assumes  that the  waste  plume  is  approximately
uniformly distributed  through  the entire water  column,  and  that  material
not  suspended  in  the water column goes  to  the  bottom.   As  a first  step,
various solid  fractions  are  calculated using the data of Form DSP2.  Then
the  fraction  of  the waste in the upper water column above the  pycnocline
and  the fraction  of  the  waste in  the  lower  water column  below  the
                                    4-6

-------
pycnocline are calculated.  The whole water column  fraction  Is  also  calcu-
lated followed by the calculation  of the fraction  of the  waste added  to  the
sediment compartment.

If there  is  no  pycnocline,  or it is assumed that the  non-settleable waste
is distributed only through the upper water column,  perform only the  calcu-
lations of Section 4.4.2 (with h = hp)  and go  to Section  4.4.4.

4.4.2  Fraction of Waste in Upper  Water Column

Assuming an approximately uniform vertical distribution  of  the  waste plume
throughout the  entire water  column, the  fraction  of waste  in the upper
water column  is  proportional  to  the  pycnocline depth  divided  by the  site
depth.  If there  is  no pycnocline or it is assumed  that  the non-settleable
waste is  distributed through  the upper  water  column,  assume that hp =  h,
evaluate this section, and go  to Section 4.4.4.
EQUATION:    Fwu = -^ * [Fl  + (Fs * Ff * Ffs)]
                                                                      (4-6)
    where   Fwu = fraction of waste in upper water column,
             hp = pycnocline depth in m (Form DSP5),
              h = mean depth in m (Form DSPS),
             Fl = liquid fraction of total  waste (Form DSP2 or Eq.  4-2),
             Fs = solid fraction of total  waste (Form DSP2  or Eq.  4-3),
             Ff = fraction of fines in solid fraction (Form DSP2),  and
            Ffs = fraction of fines in suspended cloud (Form DSP2).
EXAMPLE:
    Given    hp = 20 m (Table 3-1),
              h = 30 m (Table 3-1),
             Fl = 0.58 (Table 2-1  or Eq.  4-2 example),
             Fs = 0.42 (Table 2-1  or Eq.  4-3 example),
             Ff = 0.41 (Table 2-1),  and
            Ffs = 0.90 (Table 2-1),
                                    4-7

-------
    then
            Fwu = -   * [0.58 + (0.42 * 0.41  * 0.90)]  = 0.49
4.4.3  Fraction of Waste in Lower Water Column

Assuming an approximately uniform vertical  distribution  of the  waste  plume,
the fraction of waste in the lower water column  is  equal  to the fraction  of
non-settleable waste not  retained  in  the upper water column.   If there  is
no pycnocline, omit this section.
EQUATION:    Fwl  =  (1  -
                           * [Fl  + (Fs * Ff * Ffs)]
                                                                      (4-7)
    where   Fwl  = fraction of waste in lower water column,
             hp = pycnocline depth in m (Form DSP5),
              h = mean depth in m (Form DSP5),
             Fl  = liquid fraction of total  waste (Form DSP2 or Eq.  4-2),
             Fs = solid fraction of total  waste (Form DSP2  or Eq.  4-3),
             Ff = fraction of fines in solids fraction (Form DSP2), and
            Ffs = fraction of fines in suspended cloud (Form DSP2).
EXAMPLE:
    Given    hp = 20 m (Table 3-1),
              h = 30 m (Table 3-1),
             Fl = 0.58 (Table 2-1  or Eq.  4-2  example),
             Fs = 0.42 (Table 2-1  or Eq.  4-3  example),
             Ff = 0.41 (Table 2-1),  and
            Ffs = 0.90 (Table 2-1),
    then    Fwl  =(!-§§)* C0.58 + (0.42 * 0.41  * 0.90)]  = 0.24
                                    4-8

-------
4.4.4  Fraction of Waste in  Whole Water Column

The  fraction  of the waste  in  the  whole  water column  is  the  summation of
the  fractions in the upper  and lower water columns.   If there is no pycno-
cline,  or it  is  assumed that the non-settleable waste is distributed
through the upper water column,  set Fwl =  0 for the calculation of Eq. 4-8.
EQUATION:   Fwt = Fwu +  Fwl
(4-8)
    where   Fwt = fraction  of  waste  in whole water column,
            Fwu = fraction  of  waste  in upper water column (Eq. 4-6), and
            Fwl = fraction  of  waste  in lower water column (Eq. 4-7).

EXAMPLE:

    Given   Fwu = 0.49  (Eq. 4-6 example), and
            Fwl = 0.24  (Eq. 4-7 example),

    then    Fwt = 0.49  + 0.24  = 0.73

4.4.5  Fraction of Waste That  Falls  to Sediment

The fraction of the waste  that falls to the sediment is the remaining por-
tion of the waste that  does not remain in the water column.
EQUATION:    Fws =  1  - Fwt

    where    Fws =  fraction of waste that falls to sediment, and
            Fwt =  fraction of waste in whole water column (Eq. 4-8).

EXAMPLE:

    Given    Fwt =  0.73  (Eq. 4-8 example),

    then     Fws =  1  - 0.73 = 0.27
(4-9)
                                   4-9

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4.5  VERTICAL DISTRIBUTION  OF CONSTITUENT CONCENTRATIONS

4.5.1  Purpose and Procedure

That  portion  of  the waste not  in the  water  column is  assumed to settle
directly to  the  sediments  and  be  evenly distributed over  the site area.
For each contaminant constituent in the  waste, the vertical distribution in
the sediment layer is calculated using a one-dimensional  equation which is
analogous  to the  heat flow equation  (Carslaw and Jaeger,  1959).   The
equation assumes  diffusion only (through bioturbation)  into the sediment
layer with no resuspension of fluxes  from  the sediment layer to the water
column.

4.5.2  Contaminant Depositional  Rate

The deposition of  constituent i is estimated assuming that all the solid
portion of the waste goes  to the sea  floor.   It should be noted that this
calculation is identical  to that of Eq.  5-12.

EQUATION:   Q(i)  s Qa *  sg(partM Ci                                 (4-10)


    where   Q(i)  = deposit!onal rate for  constituent  i in  kg/m2/yr,
             Qa  = annual  loading rate  in m3/yr (Form DSP2),
       sg(part)  = particle  specific gravity (Form DSP2),
             Ci  = concentration  of constituent i in  the bulk  waste in mg/kg
                  (Form DSP3), and
              A  = direct  impact  deposition area  in m2 (Eq. 3-3).
                                   4-10

-------
EXAMPLE:

    Given    Qa = S.OxlO6  m3/yr  (Table  2-1),
       sg(part) = 2.65 (Table  2-1),
             Ci = 7 mg/kg  for  copper  (Table 2-2), and
              A = 4.52xl07 m2  (Eq. 3-3  example),

    then    (j) _ S.OxlO6  * 2.65  * 7
                    4.52xl07 * 1000
                = 0.00205  kg/m2/yr.

4.5.3  Vertical Contaminant Concentration  Profile

The vertical contaminant  distribution  is  given by  a one-dimensional equa-
tion  that  assumes  only  diffusion into  the  sediment  layer.   Effects of
suspension  and  bed transport  are neglected.   The  resulting  concentration
profile gives  a  relative  measure based on a  constituent concentration of
unity within the waste.
EQUATION:  C(z,t)  = Q(i)  *
                                .(4  *  D  *  t)172
                                v             /

    where    C(z,t)  = concentration  of contaminent  in  sediment in  kg/m ,
                  z  = depth down  into  sediment in m,
                  t  = time in yrs,
               Q(i)  = contamination  deposition  rate   for   constituent  in
                      kg/n^/yr  (Eq.  4-10),  and
                                                         p
                  D  = bioturbation mixing  coefficient  in  m /yr (default
                                      5  2
                      value in D =  10  m /yr or use  Table  4-1  for typical
                      values).
               erfc  = 1-erf (erf  is  error  function  Table  C-2)
                                    4-11

-------
               TABLE 4-1

BIOTURBATION COEFFICIENT, D, FOR VARIOUS
    LOCATIONS (FROM MATISOFF, 1982)
Bioturbation Coefficient,
o
D, Range (cm /sec)
1 x 10'6
5.4 x 10'8
2.5 x 10'9
3.5-6.3 x 10"8
1.2-3.2 x 10"7
2.9 x 10"7
1.2 x 10'6
0.01-0.99 x 10"6
7.6 x 10'8
4.1 x 10"5
1.5 x 10'4
3 x 10'8
7 x 10"8
8.7-140 x 10'8
1-4.6 x 10'6
1.6-10 x 10"7
1.2-3.4 x 10"7
3.2-41 x 10"9
6.3-16 x 10"9
Depth (cm)
-
-
-
2
2
3
4
5
38
38
30
20
8
8
12-15
5-9
7.5
9
8-15
Location
Chesapeake Bay
San Diego Basin
San Clemente Basin
Buzzards Bay
Long Island Sound
Long Island Sound
Long Island Sound
Long Island Sound
Holy Island Sanch
Caves Haven
Intertidal Sand
Gulf of Mexico
North Atlantic
Laboratory
Central Pacific
Narragansett Bay
New York Bight
New York Bight
Western Atlantic
                  4-12

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EXAMPLE:
    Given         z = 0.01  m (down  into  bottom  sediment),
                  t = 1  yr,   .
               Q(i) = 0.00205  kg/m3/yr  (for  copper, Eq. 4-10  example), and
                  D = 10'5  m2/yr  (default  value),
then  C(0.01,l)  = 0.00205  *
                    0.01
                   2*10
                       -5
                             **  10
                            *  erfc
                                   -5
                   '1/2 * exp/.  -<°'0l2>
                             V
4 * 10"5 * 1
                         0.01
                   (4 * iQ-5 * I)1/2
                = .00205  [178.41*exp(-2.50)  -  500  *  erfc  (1.58)]
                = .0036  kg/nf
    where
erfc (1.58) = 1-.9743 = .0257
PROFILES:    The resulting  concentration  profiles  are drawn in Figure 4-2,
after 1,  10, 100 and 1,000  years  for  various  depths  into the sediment.
                                    4-13

-------
     0.0
         1  yr   10 yr
                         100 yr
c
0)


'•5
0)
CO

o
*-
a
0)
O
0.1
     0.2
1000 yr
                                  468


                                    Concentration (kg/m3)
                                                                  10
      12
          Figure  4-2.   Relative  Vertical  Sediment Concentration Profiles

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                STAGE 5.   WATER  QUALITY  CRITERIA  COMPARISONS
5.1  INTRODUCTION

The purpose of  this  stage  is  to estimate, for the various constituents of
concern, the  concentrations in  the water column  at  the disposal site and
compare those values to water quality  criteria,  such as the EPA Saltwater
Quality  Criteria  or  a   species-specific  value  derived  from  bioassay
experiments.  Equations are provided to  calculate the near field exposure
levels, and the far field  exposure levels for the discrete cloud model and
plume  model  which are discussed in  Stage  3.   Figure  5-1 presents an
overview of the procedures  to  be carried  out for  Stage 5.

5.2  FORM

Only one form is required to be  filled  in for  this stage. The Water Quality
Criteria Comparisons Summary  Form DSP6,  given  in Appendix  B,  is  used to
record  the  calculated  concentration values  and compare  them  to criteria
values. A  summary  of the  EPA saltwater  quality  criteria  is presented in
Table  C-l  of  Appendix  C.   For  each  substance  or constituent  to  be  con-
sidered, a maximum allowable  near  field  (acute)  concentration,  in ppb, is
placed in column three of  Form DSPS and  an average level far field (chron-
ic) concentration in ppb is placed in  column  five of Form DSPS.  An example
of Form  DSPS  for two constituent  is  given  in Table 5-1.  This  example is
discussed below as  part  of  the procedure  for Stage 5.

5.3  NEAR FIELD ACUTE EXPOSURE LEVEL

5.3.1  Purpose and  Procedure

The maximum near field acute water  column exposure level is calculated  as a
function of  the constituent  concentrations  after disposal  and the back-
ground level  concentration  of  the constituents. The estimated concentration
is compared to  the acute or  near field  criterion for that constituent. If
                                    5-1

-------
       SECTION
          5.2
          5.3
          5.4
          5.5
 Select constituents and

obtain Near Field Acute

 and Far Field Chronic

 Criteria for Form DSP6
                                           1
       Compute
   Near Field Acute
 Exposure Levels and
  compare to Criteria
                                           1
       Compute
   Far Field Chronic
 Exposure Levels using
Discrete  Clour!  Model  A
   for Urn > Utx * */4
 and compare to criteria
                                           I
       Compute
   Far Field Chronic
   Exposure Levels
  using Plume Model
  for Urn < Utx * "74
and compare to criteria
Figure 5-1.   Stage 5,  Criteria  Comparison Overview
                            5-2

-------
                TABLE 5-1.  EXAMPLE OF

  FORM DSPS WATER QUALITY CRITERIA COMPARISONS SUMMARY
Substance
Estimated
Concentration
ppb
Near Field
(Acute)
Criterion
ppb
Far Field
(Chronic)
Criterion
ppb
 Copper
Tead
0.65
1000
25.0
67.0
4.0
50.0
                                 WQAi
                            WQCi
                          5-3

-------
it  exceeds  the criterion, then  the  dilution time  to  reach the criterion
concentration is calculated and a map is constructed to show the area over
which the criterion is exceeded.

5.3.2  Concentration of Constituent After Disposal

Prior to the  calculation  of  the  near field level,  the concentration after
disposal of each constituent  being considered  is  calculated.
EQUATION: Mi =
Vb * Fs * Ci  * 1000
        Vm
                                                                     (5-1)
    where
   Mi•= concentration of  constituent  i  in  water column
        after disposal  in  ug/kg  or ppb,
   Vb = volume  of  barge or  disposal  vessel  in m   (Form
        DSP2),
   Fs = volumetric  solid fraction  of waste  (Form DSP2),
   Ci  = concentration of constituent i in the  bulk  waste
        in  mg/kg or ppm (Form DSPS,  use column A for
        single source or weighted  sum  (cws)  for multiple
        sources  of  waste),  and
   Vm = initial  mixing volume in m  (Eq.  4-1).
EXAMPLE:
   Given  constituent i
                     Vb
                     Fs
                     Ci
                     Vm  = 160,000  m*  (Eq.  4-1  example),
        copper,
        4000 m3  (Table 2-1),
        0.42 (Table 2-1),
        7 mg/kg  for copper (Table  2-2),  and
    then
   M.    4000 * 0.42  * 7  * 1000    ,.    ,.
   Mi  = 	160,000	=  74  ug/kg  or  ppb
5.3.3  Suspended Solids Dimension!ess Mass  Ratio
This term  is  also calculated  before  using the  near  field exposure level
equation which is given in the  next  section, 5.3.4.

                                    5-4

-------
EQUATION:  Css = Ds * sg (part)  + Cs                                  (5-2)

    where       Css = suspended  solids mass ratio  subsequent  to  a  disposal,
                      dimension! ess,
                 Ds = dilution of  suspended  particulate phase, dimension-
                      less (Eq.  4-5),
           sg(part) = the particulate  specific  gravity  (Form  DSP2), and
                 Cs = background  water column  percent  suspended solids,
                      dimensionless (Form  DSP4).

EXAMPLE:

    Given        Ds = 0.0039  (Eq. 4-5  example)
           sg(part) = 2.65 (Table 2-1), and
                 Cs = ISxlO'6  (Table 2-4),

    then        Css = 0.0039  * 2.65 +  15xlO"6 = 0.01035.

5.3.4  Maximum Near Field Exposure Level

The near  field acute water  column exposure level  is  calculated from  the
background  constituent   concentration,   and   the  concentration  of   the
constituent  after   disposal.     A petition   coefficient,  f i ,  for   the
constituent is incorporated into the equation  to  allow  for the  tendency of
many  contaminants  to  ahere  to  fine  suspended  particles   instead   of
dissolving.  Metals and some  organic compounds  are examples.

EQUATION:   ELi = f.  f     +  BLi                                       (5"3)
    where            ELi  =  maximum near field  water  column exposure  concen-
                           tration of constituent i  in  ppb,
                      Mi  =  concentration of constituent  i in water  column
                           after disposal  in ppb (Eq. 5-1)
                      fi  =  adsorbed-dissolved   partition  coefficient   for
                           constituent i,  dimensionless (Table C-l),
                                    5-5

-------
                     Css = suspended solids mass  ratio  subsequent to dis-
                           posal,  dimensionsless  (Eq.  5-2), and
                     BLi = background level of constituent i  in water col-
                           umn  at  site  in  ppb  (Form DSP4)
EXAMPLE:
    Given  constituent i  =  copper,
                      Mi  =  74  ppb  (Eq.  5-1 example),
                      fi  =  130,000  for  copper  (Table C-l),
                     Css  =  0.01035  (Eq.  5-2 example),
                     BLi  =  0.6  ppb   (Table   2-4,   0.0006  ppm  in  table
                           converted  to  ppb),

    then             ELi  =  13o)0007*  0.01o35   + 0.6 = 0.65 ppb.

The maximum near field acute water column exposure level  (ELi) of 0.65 ppb
copper is recorded on Form  DSP6  as  shown in the example  given  in Table 5-1.
The EPA maximum allowable  (acute)  concentration  for  copper  of 25 ppb from
Table C-l is also recorded in the  example table  for comparison to the cal-
culated concentration. For this example,  the estimated  concentration  of
0.65 ppb  is just slightly  higher  than  the 0.6  ppb  background concentra-
tions.

The  EPA  saltwater  criterion  for copper  is 25  ppb  and  therefore  the
estimated concentration is  orders of magnitude less than  the  criterion. If
the  estimated  acute  concentration  calculated from  Eq.  5-3  for  a given
constituent is greater than  the acute  criterion,  then  it is necessary to
calculate the  time  to reach  the  criterion  level  as  described in  Section
5.3.5  and the horizontal  area  over which  the  criterion is exceeded  as
described in 5.3.6.

The average level  chronic criteria  for  the constituents  under  consideration
should also be recorded  on  Form DSP6 in the  last column. If  the estimated
concentration of the maximum  near  field water column exposure level (from
                                    5-6

-------
Eq. 5-3  and  recorded  in  column  2)  for any given constituent is  less  than
the  chronic  criteron recorded in  column 5  then there  is no  need to
calculate far field chronic  exposure  levels  for that constituent as  pre-
sented in Sections 5.4 and 5.5.

In the example shown  in Table 5-1,  the  estimated  maximum concentration of
copper is  less  than  the far  field  criterion  and  therefore the  far field
exposure levels  are not evaluated for the example presented  for  Eq. 5-3.

5.3.5  Time to Reach Acute Water Quality Criteria

If the estimated  concentration of a constituent immediately  after disposal,
ELi,  is greater  than the acute water quality criterion, WQAi,  (i.e.,  column
2  is  greater  than  column 3  of Form DSP6) then the time required for  that
waste to be diluted in the  near  field until  its concentration  is equal to
the criterion is calculated.  Times on  the order of a few  hours  should be
sufficient to  achieve  acceptable dilution.

Eq. 3-20  is  used for  this near  field  dilution  calculation.   In Stage 3,
this  equation  is used  to calculate  the concentration  of a  constituent  at  a
given  location  and at a given  time, based  on the  initial contaminant
concentration. For  application  in  this  section,  let the  estimated acute
exposure level (ELi)  equal the  initial  contaminant concentration (Co)  and
let the  acute water  quality criterion (WQAi) equal the concentration
C(x,y,t)  of equation  3-20,  and  solve  for time,  t1. In order to  solve  for
the time at which ELi  = WQAi, an initial assumption for t1  must  be made and
inserted into  the equation  to solve for WQAi.  An iterative  method is used,
that  is, several  choices of  t are  made  until  the  correct value  of WQAi is
computed. Once two different values of time are  found that  closely predict
a  value  higher  and another value lower  than  the WQAi,  the  final  time
estimate can be made by interpolation.

Eq. 3-20 of Stage  3 is transformed  into the  following equation  for  use in
computing the  time it  takes ELi to reach WQAi.
                                   5-7

-------
       WQA1 =
                         «rt
                                                                 (5-4)
where  WQAi

        ELI

        erf
          b
acute  water quality criterion  for  constituent i  in  ppb
(Form DSP6),
maximum near field water column exposure concentra-
tion for constituent i  in ppb (Eq.  5-3),
error function presented in Table C-2,
initial disposal  cloud dimension along  x axis in m
equal to V*t
          a =
where    v = velocity of disposal  vessel  in m/sec
             (Form DSP2), and
         t = duration of disposal  in sec  (Form DSP2)
initial disposal  cloud dimension along y  axis in m
equal to 2*w
              where    w = width of disposal  vessel  in m
         Ex = (4*Dx*t')1/2
              where   Dx = dispersion coefficient in x direction
                           (Eq.  3-17a),  and
                      t1 = time  in sec for ELi  to equal  EQAi
         Ey = (4*Dy*t')1/2
         x  =
          y =
where   Dy = dispersion coefficient in y direction
             (Eq. 3-17b), and
        t1 = time in sec for ELi to equal WQAi
0.0 for this application of calculating time, and
0.0 for this application of calculating time.
                                5-8

-------
In the example calculation  of ELi for copper, ELi was  less than  the  WQAi
for copper and the time calculation was  not  necessary.  For  this  example,
however,  assume that the ELi  for lead is  equal  to  1000 ppb as  shown  in
Table 5-1.

EXAMPLE:

    Given  WQAi = 67 ppb for lead  (Table 5-1),
           ELi = 1000 ppb  for lead  (Table 5-1),
             b = l.O m/sec  * 200  sec = 200  m  (Table 2-1),
           b/2 = 200 m/2 =  100 m,
             a=2*20m=40m  (Table 2-1),
           a/2 = 40 m/2 =  20 m,
            Ox = 4.7 n^/sec (Eq.  3-17a example),
            Dy = 2.2 m2/sec (Eq.  3-17b example),
            x1 = 0.0, and
             y = o.o,

    then  first assume t' =  1 hr = 3600 sec

    Solve for:

          Ex = (4*4.7*3600)1/2 =  260,
          Ey = (4*2.2*3600)1/2 =  178

       a)  Calculate value  for WQAi using Eq. 5-4:
WQAi  =
                   1000
                            erf
                            erf
100+0
~2~6TT
                          <"(^)
          using Table C-2  to  determine the value for erf
          WQAi = (1000/4)  *  [0.41 + 0.41] * [0.13 + 0.13] = 53.3 ppb
                                  5-9

-------
        b)  Compare to given value for WQAi:

            the  calculated WQAi  of  53.3 ppb  is smaller  than  the 67  ppb
            criterion therefore,  try a smaller t', let t'  =  45  min  = 2700
            sec.

        c)  Solve for Ex and Ey as defined in Eq. 5-4:

           Ex = (4*4.7*2700)1/2 =  225, and
           Ey = (4*2.2*2700)1/2 =154

        d)  Calculate value for WQAi:
             WQAi
                    1000  .
                  ~ ^^_^^^^_  «
                  erf
                             erf
           using Table C-2 to determine the value for erf
WQAi =
                        * [0.94] * [0.29] = 68 ppb
Let time  to  reach acute water  quality  criterion  equal  2700  sec  or 45 min
since 68 ppb is approximately equal  to 67 ppb.

5.3.6  Horizontal  Area Over Which Criteria Are  Exceeded

For each of the constituents whose  acute water column exposure level, ELi,
is greater than the  acute  water quality  criterion and  for which a time to
reach the criterion is calculated in  5.3.5,  the horizontal area over which
the criterion  is  exceeded  can  be calculated.  The area  is calculated using
the time to  reach the criterion, t1, and by applying Eq.  3-20 of Stage 3.
Four sets of vertices are computed which approximate the area exceeding the
criterion as a quadrilateral:
                                    5-10

-------
    [0,0], Cx(t'/2), y(t'/2)],  Cx(t'/2),  -y(t'/2)],  [z(t'),  0].
    Figure 5-2 is a schematic showing the vertices of the quadrilateral.

5.3.6.1  Downstream Travel  Distance

The value  x(t')  is  the  downstream travel  distance  required to reach  the
acute criterion and is equal  to

EQUATION:  x1  = Um * t1                                               (5-5)

    where     Um = mean net surface drift in m/sec (Form DSPS),  and
              t1  = time to  reach acute criteria in sec (Section  5.3.5).

EXAMPLE:

    Given     Um = 0.05 m/sec (Table 3-1), and
              t'  = 45 min = 2700 sec (Eq.  5-4 example)

    then   x(t')  = x' = 0.05  *  2700 = 135 m.

The value of  x(t'/2)  is  equal  to half the  x(t')  distance and therefore  in
the example the x(t'/2)  distance is approximately 68  m.
                                    5-11

-------
                           [X(t'/2).Y(t'/2)]
[o.o]
                                               [x(f).o]
     Figure 5-2,
Quadrilateral  for Horizontal  Area Over Which
Criterion is Exceeded
                                5-12

-------
5.3.6.2  Lateral  Distance  of Area

The  value  for y(t'/2)  and therefore  -y(t'/2)  is calculated  by applying
Eq. 3-20 of Stage 3 for a  t =  t'/2 with  C{x,y,t)  = WQAi  and Co = ELi. This
is also  an  iterative  procedure in which  various  values  of y are selected
until the equation is satisfied, i.e., the equation equals the acute water
quality criterion for  the  particular  constituents  under consideration.
           WQAi  =
        erf
                                                                      (5-6)
    where  WQAi

            ELi

            erf
              b
              a =
             Ex =
             Ey =
acute  water quality criterion  for  constituent i  in  ppb
(Form DSP6),
maximum near field water column exposure concentration of
constituent i  in ppb (Eq. 5-3),
error function (Table C-2),
initial disposal cloud dimension along x axis in m
equal to v*t,
initial disposal cloud dimension along y axis in m
equal to 2*w,
(4*0x*t'/2)1/2,
where   Dx = dispersion coefficient (Eq. 3-17a), and
      t'/2 = half the time in sec for ELi to equal WQAi,

(4*Dy*t'/2)1/2
where   Dy = dispersion coefficient (Eq. 3-17b)
      t'/2 = half the time in sec for ELi to equal WQAi,
             x'  = x -  Urn * t'/2  =  0.0
                  where    x  = Urn  *  t'/2,  thus  x'  =  0.0,  and

              y  = distance in m  for  t'/2  = y(t'/2)
                                    5-13

-------
EXAMPLE:
    Given  from  the example for Eq. 5-4

           WQAi  = 67 ppb,
            ELi  = 1000 ppb,
              b  = 200 m,
              a  = 40 m,
                      o
             Dx  = 4.7 m /sec, and
             Dy  = 2.2 m2/sec,

    and for this example

             x1  = 0.0, and
           t'/2  = 2700/2 = 1350 sec,

    then
    a)   Solve  for Ex and Ey:

        Ex   =  (4*4.7*1350)1/2 = 159,
        Ey   =  (4*2.2*1350)1/2 = 109,

    b)   Next let y =  100  m as  first assumption and apply to  equation 5-6
        solving  for WQAi,
          WQAi =
                  1000
ipp-oY   . /ioo+o\
--         --
                    *rf (Z° IW°\ *rf (210910°\
                                   5-14

-------
using Table C-2  to  determine  the value of erf, noting that for this case,
the error function  of  a  negative number is equal to minus the error func-
tion of the number in Table C-2,  i.e.,  erf(-x)  =  -erf(x):
           WQAi  =       -  * [0.625+0.625]  *  [-0.70+0.88]  =  56  ppb
    c)  Compare to criterion:

        The calculated value of 56 ppb  is  too  small.  Try y  =  90 m  and  solve
        for WQAi
           WQAi  =      .  * [1.25]  * [0.21]

                = 66 ppb =* 67  ppb  criterion.  Select 90 m as  value  for y.

From the  example of equation 5-6,  the  four vertices of  the  quadrilateral
for the horizontal area over which the criterion  for lead is exceeded are:
(0,0),   (68,90),  (68, -90),  (135,0).  The area exceeding  the  acute  criterion
of 67 ppb for lead is shown in Figure 5-3.

5.4  FAR FIELD CHRONIC EXPOSURE  LEVEL USING DISCRETE CLOUD MODEL A

5.4.1  Purpose and Procedure

The estimated maximum exposure levels for  each of  the constituents  of  con-
cern as recorded  in column 2  of Form DSP6  are  also compared to the  chronic
level criteria listed in column  5. If the maximum level  is greater than the
chronic level, then a time-dependent dilution calculation is made  to deter-
mine the  time required  to reach the criterion. This  section  describes the
use of Eq. 3-19  of Stage 3 for the far field transport of a  point  source to
estimate  the  time for  the condition where  Urn > Utx * */4,  as discussed in
Section 3.7.6.
                                    5-15

-------
                              (68,90)
 (0.0)
                                                (135,0)
                             (68,-90)
Figure 5-3.
Horizontal  Area  Over  Which  Criterion
in Example  of Equation  5-6.
(Coordinates  in  Meters)
for Lead is  Exceeded
                                5-16

-------
5.4.2  Initial Time

The  initial  time  (to)  for the assumed  point source  to  reach the  actual
initial horizontal area affected by the disposal  of the waste is calculated
using the barge width, length of disposal  and dispersion coefficients.   The
equation  for  the initial  time  is  based on  the  convention that  the  cloud
width  is  given by 4  *  sigma (Csanady, 1973) where  sigma is  the standard
deviation of  a  Gaussian  cloud and  therefore the  perpendicular width  is
twice  the barge width (2*w) and the parallel width  is the length of  the
dump  (v*t).   Then for  sigma2  = [2*(Dx*Dy)1//2  *  to]  the initial time  is
given by:
EQUATION:
EXAMPLE:

    Given
to =
                     w
                  16 * (Dx*Dy)1/2
                                                         (5-7)
    where    to = initial  time in sec,
              w = width of disposal  vessel  in m (Form DSP2),
              v = speed of disposal  vessel  in m/sec (Form DSP2),
              t = individual  disposal  duration in sec (Form DSP2),
                                                            2
             Dx = dispersion  coefficient in x direction in m/sec
                  (Eq.  3-17a), and
                                                            p
             Dy = dispersion  coefficient in y direction in m/sec
                  (Eq.  3-17b).
 w = 20 m (Table 2-1),
 v = 1.0 m/sec (Table 2-1),
 t = 200 sec (Table 2-1),
          P
Dx = 4.7 m/sec (Eq. 3-17a example), and
Dy = 2.2 m2/sec (Eq. 3-17b example),
    then     to = (20*1.0*200)/(16*(4.7*2.2)1/2) = 78 sec
                                    5-17

-------
5.4.3  Total  Time for Constituent  to  Reach Criterion

The disposal  cloud Is now visualized as an Initial point  source. The total
time required for the maximum  concentration  of constituent i in the cloud
to  equal  the chronic  criterion  level,  WQCi,  is  based  on  the following
formula which is derived  from  Eq.  3-19 in Stage 3.  This equation results
from setting  x  and y to  zero  in  Eq.  3-19,  and  neglecting the transport
velocity Urn.
EQUATION:
t =
                                       ELi * Ym
              D
                                   =4«*d*D* WQCi
(5-8)
    where     t =  time  to  reach  chronic  level  in  sec,
              Q =  total  mass  of  constituent  in water column.
                  For this equation  let

                           Q  = ELi*Vm

                  where ELi  = estimated  maximum  water  column   exposure
                              level in  ppb  (Eq.  5-3),  and
                          Vm  = mixing  zone volume in nr*  (Eq.  4-1),

              d =  calculated  depth in  m
              D =  (Dx*Dy)1/2  in  m/sec

                  where   Dx  = dispersion  coefficient  in the  x  direction
                               (Eq.  3-17a),  and
                          Dy  = dispersion  coefficient  in the  y  direction
                               (Eq.  3-17b),  and

              C =  concentration  of constituent in ppb.
                  For this equation  let

                           C  = WQCi  =  chronic  criteria  level  in ppb
                               (Form DSP6).
                                    5-18

-------
EXAMPLE:
    Given   ELi  = 1000 ppb for lead (Table 5-1),
             Vm = 160,000 m3 (Eq.  4-1  example),
              d = 20 m (Section 3.3.2),
             Dx = 4.7 m2/sec (Eq.  3.17a  example),
             Dy = 2.2 m2/sec (Eq.  3.17b  example),
              D = (Dx+Dy)1/2 = (4.7*2.2)1/2 =  3.22  m2/sec,  and
           WQCi  = 50 ppb (Table 5-1),
5.5  FAR FIELD CHRONIC EXPOSURE  LEVEL  USING PLUME  MODEL

5.5.1  Purpose and Procedure

If  the  two dimensional  point source  plume model  is  being  used for  the
condition Urn  <  (Utx * */4) and  unit  contours  have been constructed  for  a
mass loading  rate  of one as  described  in Section 3.7.5, then  the  loading
rate of Eq.  3-18 is calculated as described below.

5.5.2  Loading Rate from Disposal  Operation

Before  the  loading  rate  is calculated,  first calculate the  mass of  the
constituent i  per unit volume  of the waste.

EQUATION: MVi  =   C1 * f*      (Part)                                  (5'9)
                                                                 2
    where       MVi  = mass of constituent per unit volume in kg/m ,
                 Ci  = concentration of  constituent i  in the bulk waste  in
                      mg/kg (Form DSP3),
                 Fs  = solid fraction  of  waste (Form DSP2),  and
           sg(part)  = particle specific  gravity (Form  DSP2).
                                    5-19

-------
EXAMPLE:
    Given        Ci  = 7 mg/kg for copper  (Table  2-2),
                 Fs = 0.42 (Table 2-1),
           sg(part)  = 2.65 (Table 2-1),
                      7 * n &.">  * ? fiR                -j
    then        MY1  = - - U'      *'™  =  0.00779  kg/m
The  source  strength or  loading  rate in  kg/sec  for a  constituent in  the
water column for use in the application  of the  two  dimensional  plume model,
Eq. 3-18, is calculated from
               q =    ^^.***                              (5'10)
               q      3600*24*365  * Tdd  *  (fi*Cs  +  1.0)
    where           q = loading rate in  kg/sec,
                  MVi = mass of constituent  i  per unit volume of waste  in
                        kg/m3  (Eq.  5-9),
                   Qa = annual  loading rate  in  m3/year (Form DSP2),
          3600*24*365 = seconds/year,
                  Tdd = typical  duration  of  dredging operation (Form  DSP2),
                   fi = partition  coefficient,  dimensionless  (Table  C-l),
                        and
                   Cs = background  percent suspended solids, dimensionless
                      (Form DSP4)
EXAMPLE:
    Given   MVi  = 0.00779 kg/m3  (Eq.  5-9),
             Qa  = 5.0xl06 m3/yr  (Table  2-1),
            Tdd  = 0.25 (Table  2-1),
             fi  = 130,000 for  copper  (Table C-l),  and
             Cs  = 15x10, -6 (Table  2-4),
                                    5-20

-------
                              0.00779 * 5.0x10
    then      q
                  3600*24*365  * 0.25  * (130,000*15xlO~6  +  1)
                = 0.00167 kg/sec or 1.67  g/sec

5.5.3  Loading Rate from Bottom Sediment

Eq.  5-10  above  is used to calculate  the  loading  rate of a constituent  to
the  water column from  the  disposal  operation.   Bottom sediment may  also
become a  source of loading to  the  water column  and  a loading  rate  from the
sediment should be calculated.

The  sediment  source  strength  (or  loading  rate)  of  a constituent, is  com-
puted based on a given number  of years of  site usage.  In order to calculate
the  loading  rate, the  maximum  concentration  at the  water-sediment  inter-
face, Ci(o,t),  is calculated  first.  The  Ci(o,t) is a function of  the  con-
centration in the sediment before the disposal,  Co(i), and the depositional
rate, Q(i), for the constituent.

5.5.3.1  Concentration in Sediment Before  Disposal

The concentration in the  sediment  before  the  proposed disposal activity is
calculated as a function of the concentration  in the bulk  waste.
EQUATION: Cod) =
    where     Co(i)  = concentration  of constituent  i  in  sediment  before
                      disposal  activity in kg/m ,
                 Ci  = concentration of  constituent  i  in the bulk waste  in
                      mg/kg (Form DSP3), and
           sg(part)  = particle  specific gravity (Form  DSP2).
EXAMPLE:
    Given        Ci  = 7 mg/kg for copper (Table 2-2),  and
           sg(part)  = 2.65 (Table 2-1).
                                    5-21

-------
Co(1) = 7 *65 = 0.0186 kg/m3
    then
5.5.3.2  Deposition Rate

Next, the rate of deposition of the constituent Is estimated  assuming that
all the mass goes to the sea floor.   This  might be  seen  1n  an  extreme case.
cn.iftTTnu.       nm  - °-a  * s9(Part)  * C1                             /c
EQUATION:       Q(i)  -- A * 1000 -                            (5

    where      Q(1)  = deposition rate for constituent 1  In  kg/m2/yr,
                 Qa  = annual  loading rate In nrVyr (Form DSP2),
           sg(part)  = particle specific  gravity  (Form DSP2),
                 C1  = concentration  of  constituent  1 In the bulk waste  In
                      mg/kg (Form DSP3), and
                  A  = direct Impact  deposition area  In nr (Eq.  3-3).

EXAMPLE:

    Given        Qa  = S.OxlO6 m3/yr  (Table 2-1)
           sg(part)  = 2.65 (Table 2-1)
                 C1  = 7 mg/kg for copper (Table  2-2)
                  A  = 1.19xl06m2 (Eq. 3-3 example)


    then       Qd)-5-0xlfl6 V-65*7
                        1.19x10° * 1000
                    = 0.0779 kg/m2/yr.

5.5.3.3  Maximum Concentration at Interface

Once the  Co(1)  and  the Q(1)  are calculated, the maximum  concentration  at
the interface is calculated by
EQUATION: Ci(o,t) = Cod ) + Q(i) * (— sf-J                          (5-13)
                                    5-22

-------
    where  Ci(o,t)  = maximum concentration  at interface for t years in
                     kg/m3,
             Co(i)  = concentration of constituent  i in sediment before dis-
                     posal activity  in  kg/m3  (Eq.  5-11),
                                                                o
              Q(i)  = deposition  rate  for  constituents  in kg/m /yr (Eq.
                     5-12),
                 t  = time  in years,  and
                 D  = bioturbation mixing  rate  (default 10"5 m2/yr).
EXAMPLE:
    Given    Co(i)  =  0.0186  kg/m3  (Eq. 5-11 example),
              Q(i)  =  0.0779  kg/m2/yr  (Eq. 5-12 example),
                 t  =  10 years (assumed value to be consistent with example
                     of Eq.  5-14), and
                 D  = 10"5  m2/yr  (default  value),
    then  Ci(0,10)  =  0.0186  +  0.0779  *
                                            10
                                         31 *  10
                                               -5
                                                  1/2
                                     =  44  kg/nf.
5.5.3.4  Sediment Source  Strength  (Loading  Rate)

Once the maximum  concentration  at the interface  has  been calculated, the
source strength of  the  dissolved  phase for  a  given constituent, q(i), is
calculated  based  on a given  number  of years  of site  use  and a vertical
diffusion coefficient. The  variables  enclosed within  the brackets  of Eq.
5-14 are those which define  the  maximum concentrations  Ci(o,t)  as presented
in Eq. 5-13.  They are  repeated  here,  however,  so that  different years, n,
of site use can be used.
EQUATION:  q(i)  =
Co(i) + Q(i)  *
                                 n  it
Dz
                                                       fi * Scs
(5-14)
    where  q(i)  =  source  strength of  dissolved  phase  in  kg/sec,
          Co(i)  =  concentration of constituent  i  in sediment before dispos-
                  al  activity  in kg/m3  (Eq.  5-11),
                                   5-23

-------
EXAMPLE:
           Q(i)  =  deposition rate for constituent i in kg/m2/yr (Eq.  5-12),
              n  =  number of years of use (default is 10 years for little or
                  no   resuspension,  one  year  for  a  dispersive  benthic
                  environment,
              D  =  bioturbation mixing rate (default 10"5 m2/yr),
             Dz  =  vertical diffusivity from sediment  to  water  column  (de-
                  fault 0.001 m2/sec),
                   A  1/2
              b  =  —	, the typical horizontal site dimension in m,
                    JT
                                                                2
                  where    A = direct impact deposition area in m
                              (Eq. 3-3),
             fi  =  partition coefficient, dimensionles  (Table C-l), and
            Scs  =  percent  solids  concentration  in  sediment   (default  50
                  percent for  dredged  material,  20 percent  for  sewage
                  sludge).
    Given  Co(i)  = 0.0186 kg/m3 (Eq. 5-11 example),
            Q(i)  = 0.0779 kg/m2/yr  (Eq. 5-12 example),
               n  = 10 years  (default for little or no resuspension),
               D  = 10'5 m2/yr (default value),
              Dz  = 0.001 m2/sec (default value),
               b  = (1.19xl06m2)1/2/* = 347 m (Area A, from Eq. 3-3 example)
              fi  = 130,000 for copper (Table C-l), and
             Scs  = 0.50 (default value for dredged material),
    then    q(i)  =
0.0186 + 0.0779 *
                  * 0.001 *       347
                                          10    \l/2
                                        x * 10'5
                            130,000 * 0.50
                   2.35  x 10"4 kg/sec or = 0.235 g/sec
                                   5-24

-------
                STAGE 6.  HYPOXIC EVENT POTENTIAL ASSESSMENT
6.1 INTRODUCTION

The purpose of this  stage  is to evaluate the potential for a dissolved oxy-
gen depletion  at  the site due to  the disposal  operation  of  neutrally  or
positively buoyant wastes.  Historical  dissolved oxygen  information  in the
region  around the  selected site  should first be used  to determine  if
hypoxia could become a problem and whether  to  continue  with the potential
assessment.  The  analysis  is based on the biochemical oxygen demand (BOD).
The oxygen  depletion curve  (for  net  flow Urn >0.0) and  the oxygen deficit
growth rate  (for  Urn  =  0.0 as  an extreme event) are  computed  based  on the
ambient BOD and the water column BOD  after  disposal.   Figure 6-1 presents
the dissolved oxygen  assessment overview for stage 6.

The analysis  is  performed  under assumed critical conditions of  high
temperature, quiescent weather and strong pycnocline which usually occur in
the summer.  The  following conditions for use in the calculations are spec-
ified as being critical:

    1.  Use the maximum disposal rate average over a 30-day period if data
        available.  Otherwise, use Qa/Tdd from Form DSP2,

    2.  Use low diffusivities.  Let Dx and Dy equal 0.1 m2/sec,

    3.  Use highest water  temperature expected or observed below the pycno-
        cline, and

    4.  Use  the  lowest  net  flow observed,  or  use 0.0 m/sec  as  a default
        value.
                                   6-1

-------
             6.3
             6.4
             6.5
             6.6
             6.7
                                            Specify

                                       critical conditions
                                              I
       Compute
     Ambient BOD
    without disposal
                                              I
       Compute
     Local  Water
     Column BOO
     with disposal
                                              I
       Compute
       Initial DO
    after disposal
                                              I
       Compute
  DO Depletion Curve
   with Net Flow  >0
                                              I
       Compute
DO Deficit Growth Rate
   with Net Flow =0
Figure 6-1.   Stage 6,  Dissolved Oxygen Assessment Overview
                              6-2

-------
6.2  FORMS

All the DSP Forms have been completed up  to  this  stage.   Data  from  several
of the forms are required in the calculations of this  stage.

6.3  AMBIENT BOD WITHOUT  DISPOSAL

6.3.1  Purpose and Scope

The ambient biochemical  oxygen  demand,  BODa, at the site is required as a
base  condition  before  disposal  calculations are  performed.   BODa is
estimated as the  sum  of  the ambient off -site value, BODu, the demand from
the site  sediments,  BODis, which  could include  the  demand  from previous
disposal; and the demand  from resuspended  sediments, BODrs.

6.3.2  Benthic Oxygen  Demand

If the benthic  oxygen demand is not known  and  not recorded on Form DSP4,
it is estimated from the  demand  of  the  accumulated sediment,  decay  factors,
deposition rate and accumulation period.   The decay factor  and deposition
rate are calculated first, and then applied  to  the  formula for the  benthic
oxygen demand.

6.3.2.1  Decay Factor

The decay factor is a  function of the decay  rate and water temperature.
«>UAT10N:    C° •  1 I ££{:! * koi
    where    Co = decay factor,
            exp = exponential  function,
             ko = decay rate at  20°C (default is 0.23/day),  and
              k = ko * (1  + 0.05 * (T-20))

                  where T  = ambient water temperature,  degrees  C.

                                    6-3

-------
EXAMPLE:

    Given    ko = 0.23 per day, and
              t = 25° (Form DSPS),

    then      k = 0.23 (1 + 0.05 *  (25 - 20))  = 0.29 per day,

             rn   1 - exp(-5 * 0.29)  _ . 17
             Co " 1 - exp(-5 * 0.23)  " 1>12

6.3.2.2  Daily Deposition Rate Factor

The deposition rate factor, W, is computed directly from the daily desposi-
tion  rate  of  organic  solids,  dd.    First,  the daily  deposition rate  of
organic solids is approximated by

EQUATION:  dd = dwd * fv * sg (part)  * (1-Ffs) * -yi  * 100°         (6'2)

                                                                     o
    where        dd = daily deposition rate of organic solids in kg/m ,
                dwd = daily waste  dumping rate  (default =  [Qa/Tdd)/365],
                      for Qa and Tdd  on Form DSP2),
                 fv = organic fraction of waste,
           sg(part) = particle specific gravity (Form DSP2),
                Ffs = fraction of fines in suspended cloud,  (Form DSP2),
                  d = equivalent depth in m (Section 4.3.2), and
                 Vm = initial  mixing  zone volume in m (Eq. 4-1),

EXAMPLE:

    Given        Qa = S.OxlO6 m3/yr (Form DSP2),
                Tdd = 0.25 (Form DSP2),
                dwd = (Qa/Tdd)/365  =  (5.0 x 106/0.25)/365 =  5.48 x 104,
                 fv = 0.002,
           sg(part) = 2.65 (Form DSP2),
                Ffs = 0.9 (Form DSP2),
                  d = 20 m (Section 4.3.2 example), and

                                   6-4

-------
                 Vm = 160,000 m3 in m3 (Eq. 4-1 example),

    then         dd = 5.48xl04  *  0.002 *  2.65  * (1-0.9) *  (20/160,000)  *
                      1000 =3.63  kg/m2

Once  the  daily deposition  rate,  dd,  is  calculated , the  deposition  rate
factor, W, is calculated by
EQUAT,ON:  „ .                                                       ,5-3,
                                                   o
    where     W = daily deposition rate factor kg/m ,  and
                                                                 2
             dd = daily deposition rate of organic solids in kg/m
EXAMPLE:
    Given    dd = 3.63 kg/m2 (Eq. 6-3 example),
              * • "*

6.3.2.3  Daily Benthic Oxygen Demand

If  an  observed daily  benthic oxygen  demand is  not available  (from  Form
DSP4),  then the calculated  decay factor and deposition  rate  factor can be
applied to a formula for estimating the benthic  oxygen demand (Fair, et al,
1968).    The  benthic  oxygen  demand,  BODis, is  the  oxygen  demand  of  the
insitu  sediments including those resulting from  previous dumps.

EQUATION:  BODis = 0.0314 * BODw * Co * W * (ta)1/2                  (6-4)

                                               ?
    where  BODis = benthic oxygen demand in g/m  /day,
            BODw = biochemical oxygen demand of  the accumulated sediment in
                                                              /
                   g/kg (the BOD value of the original waste can be usd for
                   default, Form  DSP3,  convert  mg/kg on Form  DSP3 to  g/kg
                   for this equation),
              Co = decay factor (Eq. 6-1),

                                    6-5

-------
               W = deposition rate  factor (Eq.  6-3),  and
              ta = time in days,  up to 365,  during  which  accumulation  takes
                   place,  or the  time  between  resuspension  episodes, or the
                   annual  duration  of  dredging  operation.
EXAMPLE:
    Given   BODw = (32 mg/kg)/(1000 mg/g) = 0.032 g/kg (Table 2-2 and con-
                   version to g/kg),
              Co = 1.12 (Eq.  6-1  example),
               W = 3.66 kg/m2 (Eq.  6-3  example),  and
              ta = 91  days or 0.25  yr  (Tdd  in  Table 2-1),

    then   BODis = 0.0314 * 0.032 * 1.12  *  3.66  * (91)1/2
                 = 0.0393 g/m2/day.

6.3.3  Resuspended Sediment Oxygen  Demand

The oxygen demand of the  organic resuspended  load is  calculated  as  a  func-
tion of the BOD of the accumulated  sediment.

EQUATION:  BODrs = BODw * (1  - exp(-5  * k))                           (6-5)

    where  BODrs = oxygen demand  of resuspended  load  in mg/kg,
            BODw = biochemical oxygen  demand  of accumulated  sediment  in
                   mg/kg (note in Eq.  6-4 units  are g/kg),
             exp = exponential function,  and
               k = ko  *  (1 + 0.05 *  (T-20)), temperature corrected  decay
                   rate

                   where  ko = decay  rate at 20°C, and
                           t = water  temperature °C.

EXAMPLE:

    Given  BODw = 32 mg/kg (original  waste  value in Table  2-2),  and
              k = 0.29 (Eq. 6-1 example),
                                    6-6

-------
    then  BODrs = 32  * (1  -  exp(-5  *  0.29))  = 24.5 mg/kg.

6.3.4  Ambient BOD Without Disposal

The total  ambient BOD at the site without present disposal occurring is the
sum of the off-site BOD,  the resuspended BOD and the benthic oxygen demand
acting on  the waters  up to the  pycnocline.
EQUATION:   BODa =  BODu  +  BODrs +   pp                                (6-6)

    where    BODa = ambient on-site  biochemical  oxygen demand  in  mg/kg or
                   ppm,
            BODu = ambient off-site  BOD  in mg/kg or ppm,
           BODrs = oxygen demand  of resuspended  load  in  mg/kg  or ppm
                   (Eq. 6-5),
                                           p
           BODis = benthic oxygen demand g/m   (Eq. 6-4), and
              di = height of pycnocline  above bottom  (if  no pycnocline and
                   well -mixed, use average depth of site).

EXAMPLE:

    Given    BODu = 3  mg/kg (or mg/1 ) ,
           BODrs = 24.5 mg/kg  (Eq. 6-5 example),
           BODis = 0.0393 g/m2 (Eq.  6-3  example), and
              di = 10 m (Table 3-1,  mean depth of 30 minus pycnocline  depth
                   of 20),
    then    BODa =  3  +  24.5 +      -  =  27.5 mg/kg.
                 Note:         =  (g/m2)/(m) = g/m3 = mg/kg
                                    6-7

-------
6.4  LOCAL WATER COLUMN BOD WITH DISPOSAL

6.4.1  Purpose and Procedure

The  local  water column BOD with  disposal  operations is a  function  of am-
bient BOD  and the waste  load  BOD  of the disposal  material.  This BOD, con-
verted to ultimate BOD, is used in the oxygen depletion curve, Eq. 6-11, in
Section 6.5.

6.4.2  Five-Day Biochemical  Oxygen Demand

The 5-day BOD is computed first and then converted to the ultimate BOD.

EQUATION:  BODd = BODa + (^  * BODw *  ^lj                          (6-7)

    where  BODd = biochemical  oxygen demand in local  water column with dis-
                  posal in mg/kg,
           BODa = ambient biochemical  oxygen demand in mg/kg (Eq. 6-6),
                                                o
             Vb = volume of disposal vessel  in m  (Form DSP2),
             Vm = initial  mixing zone  volume m  (Eq.  4-1),
           BODw = biochemical  oxygen demand of waste  in mg/kg (Form DSP2),
             di  = height of pycnocline above bottom,  in m,  and
              d = equivalent depth.

EXAMPLE:

    Given  BODa  =27.5 mg/kg (Eq.  6-6  example),
             Vb  = 4000 m3 (Table 2-1),
             Vm = 160,000 m3 (Eq.  4-1  example),
           BODw = 32  mg/kg (Table  2-2),
             di  = 10  m (Table 3-1, mean depth of  30  minus  pycnocline depth
                  of  20),  and
              d  = 20  m (Section 4.3.2  example),
    then    BODd  =  27.5  ^5  *  32  *      )=  27.9 mg/kg,

                                    6-8

-------
 6.4.3  Ultimate Biochemical Oxygen Demand

 The computed local water column BOD with dumping calculated in Equation 6-7
 is  the 5-day BOD value.   It is  converted  to ultimate BOD by  a factor of
 1.46 which is based on an assumed decay rate of 0.23 per day,  base e.
EQUATION:  BODult = 1.46 * BODd
                                                          (6-8)
    where  BODult = ultimate biochemical  oxygen  demand of local  water col-
                    umn with disposal in mg/kg, and
             BODd = biochemical  oxygen  demand of  local  water column  with
                    disposal in mg/kg (Eq. 6-7).
EXAMPLE:
    Given    BODd = 27.9 mg/kg (Eq. 6-7 example),

    then   BODult = 1.46 * 27.9 = 40.7 mg/kg.

6.5  INITIAL DISSOLVED OXYGEN AFTER DISPOSAL

The initial dissolved  oxygen  in  the water column  is  required so that sub-
sequent dissolved  oxygen  calculations can be  made as a  function  of time.
The initial  dissolved oxygen  is  calculated as  a  function of  the ambient
dissolved oxygen and the dissolved oxygen of the waste.
EQUATION:
nn. _  (DOa * Vm) + (DOw * Vb)
 U1 "          Vm + Vb
                                                   (6-9)
    where
 DOi
 DOa

  Vm
 DOw
initial dissolved oxygen after disposal in mg/1,
ambient dissolved oxygen in mg/1  (Form DSP4 or Table C-4
for default values based on temperature and salinity),
initial mixing zone volume in m  (Eq. 4-1),
dissolved oxygen of waste  in  mg/1  (Form  DSP3  or use 0.0
as default), and
                                    6-9

-------
             Vb = volume of disposal  vessel  in m  (Form DSP2).
EXAMPLE:
    Given   DOa = 6.0 mg/1  (Table 2-4),
             Vm = 160,000 m3 (Eq. 4-1  example),
            DOw = 0.0 mg/1  (Table 2-2),  and
             Vb = 4,000 m3 (Table 2-1),
    thon    nfH  - (6-0 * 160,000)  + (0.0 * 4,000)
    tnen    UU1            160,000  + 4,000
                = 5.85 mg/1

6.6  OXYGEN DEPLETION CURVE  FOR NET FLOW,  Urn,  > 0.0

6.6.1  Purpose and Procedure

The dissolved oxygen  (DO) concentration is calculated  as  a  function of the
down-current travel  time, and a DO  versus  distance graph  can  be plotted.
At a given time, the  dissolved  oxygen  is  computed based on  the ambient DO,
the  initial  DO,  the  ultimate BOD  and a  dilution factor.   The downstream
dilution factor  is  estimated first, then  applied to  the oxygen  depletion
curve formula.

6.6.2  Downstream Dilution Factor
The downstream dilution factor is approximated using the error function and
the lateral  diffusion coefficient (Brooks, 1960).
EQUATION:  DS =
    where
     erf
                      16 * D * t
                                   1/2
                                                  (6-10)
 DS
erf
  b
downstream dilution factor,
error function (Table C-2),
characteristic source length (distance traveled by vessel
during disposal  process or default of 200 m),
                  6-10

-------
              D = constant lateral diffusion coefficient,
                                 o
                = 0.0018 * b in m /sec, and
              t = time in seconds.
EXAMPLE:
    Given
erf = error function in Table C-2,
  b = disposal vessel  speed  * disposal duration =  1.0  m/sec *
      200 sec = 200 m (Table 2-1),
  D = 0.0018 * b = 0.0018 * 200 = 0.36 m2/sec, and
  t = 86,400 sec (1 day); 432,000 sec (5 days); and 864,000 sec
      (10 days),
   then for  1 day  DS =
   then for  5 days DS =
   then for 10 days DS =
             erf
             erf
             erf
                                     200'
                 ,16
                                          8674(11)
                                     200'
                              16 * LT.36 * 432,000;
       200'	}
16 * 0.36 * 864,000i
1/2  = 0.300,
1/2  = 0.127,
     = 0.089,
6.6.3  Dissolved Oxygen Depletion Curve

The dissolved oxygen concentration  in the water column  at any given down-
stream travel  time is  expressed as a  function  of DO,  BOD  and downstream
dilution after the initial  mixing of the waste.
EQUATION: D0(t) = DOa -[DOa - DOi + BODult * (1 - exp (-k * t))] * DS
                                                                    (6-11)
    where  D0(t)
             DOa
       dissolved oxygen concentration at time t (days) in mg/1,
       ambient dissolved oxygen in mg/1  (Form DSP4 or Table C-4
       for default values),
 DOi  =  initial  dissolved oxygen after disposal in mg/1
       (Eq.  6-9),
                                    6-11

-------
          BODult = ultimate biochemical oxygen demand of local water column
                   with disposal in mg/kg (Eq. 6-8),
             exp = exponential  function,
               k = temperature adjusted BOD decay rate per day
                 = ko * (1 + 0.05 * (T-20))
                    where  ko = BOD decay rate at 20°C per day
                            t = ambient water temperature °C,
                t = time in days, (not seconds), and
               DS = downstream dilution factor (Eq.  6-10).
EXAMPLE:
    Given     DOa = 6.0 mg/1  (Table 2-4),
              DOi = 5.85 mg/1 (Eq. 6-9 example),
           BODult = 40.7 mg/kg (Eq. 6-8 example),
              exp = exponential  function,
                k = 0.29 per day (Eq. 6-1 example),
                t = 1, 5, 10 days, and
               DS = 0.300 for 1  day,
                  = 0.127 for 5  days, and
                  = 0.089 for 10 days,
                    (Eq. 6-10 example),

    then  D0(l day) = 6.0 -[6.0  - 5.85 + 40.7 * (1 - exp(-0.29 * 1))]
                      * 0.30 = 2.88 mg/1,
          D0(5 day) = 6.0 -[6.0  - 5.85 + 40.7 * (1 - exp(-0.29 * 5))]
                      * 0.127 =  2.02 mg/1,
         D0(10 day) = 6.0 -[6.0  - 5.85 + 40.7 (1 - exp(-0.29 * 10))]
                      * 0.089 =  2.56 mg/1

6.7  OXYGEN DEFICIT GROWTH RATE  FOR NET FLOW, Um, = 0.0

6.7.1  Purpose and Procedure

A extreme  case scenario  is  represented here by  setting the net  flow,  Um
equal to zero.  Under  this condition each day's disposal of BOD is treated

                                    6-12

-------
as an independent dispersing cloud.  The  following  procedure  estimates  the
oxygen reduction with respect to time.   It is calculated for the area below
the pycnocline at the  center of the disposal site.  The  method is  carried
out by superimposing on  one  another the effects of the BOD cloud for each
day.

A series of  equations  and  a  specific procedure is  required to  analyze  the
effects of the BOD decay, the oxygen reduction  for  each day,  and the total
oxygen deficit  for  a given period  of time.   Each equation, with a  simple
example is discussed in this Section.   An  overall  example procedure  on  the
application of these equations  is also given  in  Section 6.8 to show  how  the
equations are used in combination.

6.7.2  BOD Mass Loading Rate

The mass  loading rate in  grams  per day for the area below the  pycnocline is
calculated for  application  to  the  equations for  the  water column  BOD  in
Sections  6.7.3 and 6.7.4.
EQUATION:   Qb = (BODw * Vb * Dd * Ff * Ffs)  + (BODis * A)
                                                  (6-12)
    where    Qb
           BODw

             Vb
             Dd
             Ff
            Ffs

          BODis
              A
mass loading rate of BOD in g/day,
                                            o
biochemical  oxygen demand  of  waste in  g/m  (Form DSP3,
units same as mg/1 or mg/kg),
volume of disposal vessel in m  (Form DSP2),
number of barge loads dumped per day (Form DSP2) or
Qa/(Vb * Tdd * 365)
where from Form DSP2
        Qa = annual loading rate in m /yr,
        Vb = volume of disposal vessel in m , and
       Tdd = typical  duration  of  dredging operation  in
             fraction of a year,
fraction of fine particles in waste (Form DSP2),
fraction of fines in suspended cloud of a single disposal
(Form DSP2),
                            2
benthic oxygen demand in g/m /day, and
                           2
disposal settling area in m  (Eq. 3-3),
                  6-13

-------
EXAMPLE:

    Given  BODw = 32 g/m3  (Table  2-2),
             Vb = 4000 m3  (Table  2-1),
             Dd = 5.0xl06/(4000  * 0.25  *  365) = 13.7  or say 14  disposals
                  per day  (Table  2-1),
             Ff = 0.41 (Table  2-1),
            Ffs = 0.9 (Table 2-1),
          BODis = 0.0393 g/m2/day (Eq.  6-4 example),  and
              A = 1.19xl06 m2  (Eq.  3-3  example),

    then     Qb = (32 * 4000 * 14 * 0.41 * 0.9)  + (0.0393 *  1.19xl06)
                = 7.08 x 105 g/day.

6.7.3  Basic Equation for  Each Day's BOD Cloud

The following equation demonstrates the calculation  of  each  day's BOD  con-
centration.   However this  equation  is  actually incorported  into Equation
6-14 which  should  be used  instead  of  Equation  6-13 for  solving  problems.
An example is given here to illustrate  the equation variables.
EQUATION:   X(t)  =            ~                                      (6-13)

    where     X(t)  = BOD concentration after t days in mg/1 ,
                Qb  = BOD mass loading rate in g/day (Eq.  6-12),
                 k  = BOD decay rate per day (in Eq. 6-1),
                 t  = time in days,
                di  = distance from  bottom to pycnocline in m,  and
                 D  = dispersion coefficient = 0.1  m2/sec  = 8640  m2/day (for
                                                  •j
                     this equation  units must be m /day).
                                    6-14

-------
EXAMPLE:
    Given       Qb = 7.08xl05  g/day  (Eq.  6-12  example),
                 k = 0.29 per  day (Eq.  6-1  example),
                 t = one day,
                di = 10 m (Eq.  6-7 example), and
                 D = default 8640 m2/day,
    thon  YM  H™I  - 7.08xl05  * exp(-0.29  *  1)
    then  X(l  day)  -- 4a *  10 * 8640  *  1 -
                   = 0.49 mg/1  BOD.

6.7.4  BOD Concentration Near the Center of the Site

The central  BOD concentration is calculated based on the idea that the dis-
persion clouds  are  superimposed on one  another as the BOD  is  loaded into
the site on  successive days.   The equation can also be considored to show a
BOD cloud as it is followed through time.  The central BOD concentration is
a function of the number of  days  that  have passed since the release of the
waste.
EQUATION- X(n) -.     Q*       *    £    exp(-k * j  * dt)
tgimiiuN. xinj  U* * ^ * D j      .=-        j  * dt
    where  X(n) = central  BOD concentration in mg/1  after n days,
             Qb = BOD mass loading rate in g/day (Eq.  6-12),
             di = distance from bottom to pycnocline in m,
                                                          2
              D = dispersion coefficient, default =  8640 m /day,
             £ = sum all  values of following expression
          j=l,n   for 1 to n number of days,
              k = BOD decay rate per day (in  Eq. 6-1),
              j = number of days from 1 to n, and
             dt = computational  time step equal to 1 day.
                                    6-15

-------
EXAMPLES:

The  following  examples  demonstrate  the specific  use  of  the  variables in
Equation 6-14  for  a three-day  period;  however,  an overall  procedure for
analyzing the oxygen deficit  growth  rate is given in Section 6.8 which uses
Equations 6-14, 6-15,  and 6-16.

A)  Superposition of dispersion  clouds using summation

    Given    Qb = 7.08x10  g/day (Eq. 6-12 example),
             di = 10 m (Eq. 6-7  example),
              D = 8640 m2/day (default),
              k = 0.29 per day  (Eq.  6-1 example),
              j = 1, 2,  and 3 days,  and
             dt = one day,
    then    BOD concentration  at  the  center of the site after 3 days is:

                                       exp(-0.29 *  1 * 1)
  7.08xl05
4* * 10 * 8640
                                                1*1

                                      , exp(-0.29 * 2 *  1)
                                                r~*~i

                                      , exp(-0.29 * 3 *  1)
                                                3*1

                = (0.65)  *  (0.748  +  0.280  +  0.140) = 0.76 mg/1

This  value represents the  BOD  concentrations after  superimposing the
dispersion clouds released  on three  successive  days.

B)  Single cloud followed through  time without  summation.

    Given   all  values  as in  example A above,
                                    6-16

-------
    then   X(l) = 0.65 * 0.748  =  0.49  mg/1
           X(2) = 0.65 * 0.280  =  0.18  mg/1
           X(3) = 0.65 * 0.140  =  0.09  mg/1
These values represent the  central  BOD  concentration of a single cloud at
1, 2 and 3 days.

6.7.5  Dissolved  Oxygen  Deficit for Each  Day's  Release

The DO deficit is equal  to that portion of  the  BOD  that  has been reduced as
a function of decay.  The  deficit resulting from a  single release is
calculated for a  given period of time in  days.
EQUATION:   DODn =
                       [x(i)  -  x(i+l)]
               1=1,n-1
                                            exp(-k  *  t)
                                         i +  exp{-k  *  t)
                                              (6-15)
    where
                   1=1,n-1
           x(i)  and x(i+l)

                         k
                         t
DODn = dissolved oxygen deficit after n days,
 V  = sum of all  values of following expression
       for 1 to (n minus 1) days,
                             BOD concentration in mg/1 for the i   day  and
                             the (1th  plus  one)  day  (Eq.  6-14),
                             BOD decay rate per  day  (in Eq. 6-1),  and
                             i*dt for each i  day and dt is a one day time
                             step.
EXAMPLE:

This example uses a  single  day's  release and the same three day period as
example B for Equation 6-14.  However, a general  procedure  for  calculating
the DO deficit  is presented in  Section 6.8 using Equations 6-14, 6-15 and
6-16.

    Given  X(l)  = 0.49 mg/1,
           X(2)  = 0.18 mg/1,
                                    6-17

-------
           X(3) = 0.09 mg/1 (all  from Eq. 6-14 example B),
              k = 0.29 per day (Eq.  6-1 example),
              n = 3 days,
              i = 1 to n-1 = 1,  2
             dt = one day, and
              t = i*dt =1,2,
    then   DOD3 = [0.49 - 0.18] *
 exp(-0.29  * 1)
f- +  exp(-0.29 *  1)
                    [0.18 - 0.09} *
                                          exp(-0.29 * 2)
                                             exp(-0.29 * 2)
               .   = (0.31 * 0.428)  + (0.09 * 0.528) = 0.18 mg/1

Therefore,  the  total  DO  deficit  from a  single release  over two  days  is
0.18 mg/1.

6.7.6  Total Dissolved Oxygen Deficit for Successive Releases

The total oxygen deficit for a series of BOD releases on successive days is
computed by summing the deficit due to each of the daily BOD releases.
EQUATION:    TOD =
                       DODj
                                (6-16)
    where   TOD = total dissolved oxygen deficit mg/1, and
           DODj = dissolved oxygen deficit for each j day.
EXAMPLE:
    Given  for a single release,

           DOD for day 1 = 0.31*0.428 = 0.13 mg/1,
           DOD for day 2 = 0.09*0.528 = 0.05 mg/1, (Eq.  6-15 example)
                                    6-18

-------
    then   for successive releases  after  2  days

           TOD = (0.13)  + (0.13  + 0.05) = 0.31 mg/1,

    where  0.13 represents the  effect of  the  first day's  release  on the
           first day;  and for the  second day,  (0.13  +  0.05)  represents the
           effect of the second  day's  release on  the  second  day  (0.13) plus
           the effect of the  first  day's  release  on  the second day (0.05).

6.8  OXYGEN DEFICIT GROWTH RATE  COMPREHENSIVE EXAMPLE FOR  NET FLOW Um  = 0.0

This example  demonstrates  a  procedure which uses  a  table of variables to
calculate the oxygen deficit.  This tabulation permits  a  record keeping of
important variables as  calculations are  carried  out.   Table 6-1 is an ex-
ample of  a  blank  calculation sheet used in this example.   For each time
step in days, values are calculated for columns A through  E  which represent
functions as  defined  in the  table.   Table 6-2  is  filled-in for the
following example  which  is  based  on the  same   assumptions and variable
values  presented  in  the  individual  examples  for  Section  6.7.4   through
6.7.6.

Column A
    Calculate the  value  of exp("J*k)  USing j = 1,  2, 3 and  k =0.29 per day.

    For example, on the  first day exP  (-0.29*1)   = 0>748

Column B
    Calculate the  value  of [x(i)-x(i+l)]/m  by using  the differences  in Column
    A
    For example 0.748 -  0.280 =  Column B  for first day
            and 0.280 -  0.140 =  Column B  for second  day.
                                    6-19

-------
Column C
    Calculate ratio using j  = 1,  2 and k  =  0.29 per day
                                      exp(-0.29 * 2)
    For example, on the second day
      0.528
                                      + exp  (-0.29  *  2)
Column D
    Calculate by multiplying columns  B times  C
Column E
             Qb
    M =  -j—^ .*  ^ p   from Equation  6-14.   In  this  example,
M =
           7
         *   1    8640
                        = °'65 Wh1ch  is  mult1'P11ed t1mes Column  D.
    For example,  on the first day M times  column  D = 0.65 * 0.2 = 0.13

Note:     Adding  Column E gives a DO reduction of 0.18 mg/1  for each  day's
         release  which is the same as calculated in the  example for  Equa-
         tion 6-15.
                                    6-20

-------
              TABLE 6-1
OXYGEN DEFICIT GROWTH RATE WORKSHEET
Time
Step
j
(days)
1
2
3
4
5
6
7
8
9
10

(A)
exp(-jk)
J










BOD
Reduction
Rate
(B)
x(i)-x(i+l)
m










Daily
Differential
(C)
exp(-jk)
l/j+exp(-jk)










Ratio of
Decay of
Dispersion
Plus Decay
(D)
(B)*(C)










Daily
Differential
Due to
Decay
(E)
M*(D)










Daily
Contribution
to Oxygen
Deficit
                6-21

-------
                  TABLE 6-2
EXAMPLE OXYGEN DEFICIT GROWTH RATE WORKSHEET
Time
Step
j
(days)
1
2
3
4
5
6
7
8
9
10

(A)
exp(-jk)
J
0.748
0.280
0.140







BOD
Reduction
Rate
(B)
x(1)-x(i+l)
m
0.464
0.140
-







Dally
Differential
(C)
exp(-jk)
l/j+exp(-jk)
0.428
0.528
-







Ratio of
Decay of
Dispersion
Plus Decay
(D)
(B)*(C)
0.200
0.074
-







Daily
Differential
Due to
Decay
(E)
M*(D)
0.13
0.05
-







Daily
Contribution
to Oxygen
Deficit
                    6-22

-------
                   STAGE 7.  SPECIES SPECIFIC ASSESSMENT
7.1  INTRODUCTION

There are no new equations to be solved or specific DSP forms to be filled
out for Stage 7.  This stage is a more detailed assessment of the disposal
activities on specific species  in relation to breeding, spawning, nursery,
feeding or passage areas of  living  resources  in  adult  or juvenile phases.
In order  to.carry out this  phase,  a  knowledge of the  biological  species
present at the  site and in the surrounding affected areas is required.   One
must also be familiar with toxic affects  and bioaccumulation which are two
major aspects to be considered.

Stages 1 through 6 will provide  basic information at the site from which to
proceed with the species specific assessments.   As  part of Stage  1  a
preliminary evaluation of  the  biological  community  should  be undertaken.
Stages 2 through 4 develop the  waste  profile  and loading characteristics,
the transport mapping  and resuspension estimates,  and  the  initial  mixing
and source strength  calculations.   Stage  5 presents a procedure for making
comparisons of  the  predicted water quality  at a site  with  water quality
criteria,  and  Stage 6 demonstrates  a methodology for  determining  the
hypoxic potential  of  the disposal site.

7.2  PROCEDURE

For a  given site,  species  specific  toxicity data could be used where
available.   However,  if specific  biological  and toxicological information
is not available,  a more  general approach  could  be  undertaken.   One
approach is  to  define functional  groups  or  types of  biota in  terms  of
toxicological  and bioaccumulation  responses.   An example  of this generic
representation  of biological types  is presented in  Table 7-1.   For  each
major   domain   (pelagic,   demersal,   and   infaunal)   generic  types   are
recommended in  the  table.    Table  7-1  also includes columns  for the  site
specific species which may be of major consideration,  the pollutant to be
analyzed, the acute  and chronic criterion  for that pollutant, and the FDA

                                   7-1

-------
                    TABLE 7-1



ORGANIZATION OF SPECIES SPECIFIC IMPACT ASSESSMENT
Domain

PELAGIC

DEMERSAL


INFAUNAL
Generic
Type
Phyto-
Plankton
Zoo-
Plankton
Finfish
(Herring)
Crustacean
or
Mollusk
Finfish
(e.g. Cod)
Mollusk
Poly-
chaete
Site
Specific
Species







Pollutant







Acute
Criterion







Chronic
Criterion







FDA
Ti ssue
Limit







                       7-2

-------
tissue limit (or action level) of that contaminant for the  generic type or
the site specific species.

The selection of the  pollutants  or  contaminants  of importance for Stage 7
assessment will  be  identified in Stage 2  where  the  mean concentration of
constituents  measured  in   the   source  materials  are   determined.    The
selection procedure of  generic  or specific species  to  be analyzed at the
site   should    first    consider   harvestable   living    resources   and
protected/endangered species.   Individual  documents on  acute and chronic
values for  a  specific  toxic  pollutant  on a  variety of different species
have  been  published by EPA for  65  toxic  pollutants.  Most of these were
published in  1980,  however  there have been  some recent  updates.   These
documents are entitled  Ambient  Water Quality  Criteria  for  "name of toxic
pollutant".   The  Food and Drug  Administration  (FDA) has developed action
levels for  poisonous  or deleterious  substances  in  human  food and animal
feed  (FDA, 1982).  The  action levels  and tolerances  represent  limits at or
above which  FDA will  take  legal action  to  remove  the  products from the
market.    Action  levels for several   substances are  given for a  variety of
commodities.  Fish,  shellfish,  crustaceans,  and  other aquatic animals are
listed as a commodity for some of the substances  in the  publication.

The general  assessment procedure requires  the  use of  the  basemaps developed
in Stage  3  which  show the  waste load transport  contours  for  various types
of loading conditions.  On these  same maps (or on  overlay maps)  range maps
should be developed for the  selected species  to show their  distribution.
This  should be  done seasonally  and  for both juvenile and adult  life cycle
stages.   A species specific  summary  table  can  be  constructed for  each stage
of  development  to  record  the  criterion   for  a   specific  constituent for
various  indicators such as  mortality,  reproduction, growth  rate, and
behavior.  An example of such a  table is given in Table  7-2.

The potential  impacts  to be  assessed in   the  upper  water  column  (pelagic
domain)  include increased turbidity,  nutrient  enrichment, oxygen  depletion,
toxicological   and  bioaccumulation   effects.     The   plume   model  methods
described in Stage 3 and Stage  5  should be used  to approximate the spatial
and temporal distribution of  the  contaminants  being  investigated.  For the

                                    7-3

-------
                                 TABLE 7-2



              SPECIES AND CONSTITUENT - SPECIFIC SUMMARY TABLE
SPECIES:
CONSTITUENT:
Indicator
Mortality
Reproduction
Growth Rate
Behavior
Criterion




References




                                    7-4

-------
demersal organisms  (those  on or near  the  bottom) an assessment  should be
made of the effect of  hypoxia,  turbidity, toxicity, and  bioaccumulation.
For each of  the  species investigated in these two  domains  the procedures,
including computations and mapping, discussed in  Stages  3 through 6 provide
the methods for estimating these impacts.   For burrowing and filter-feeding
infauna  the exposure  assessment  should   include  not  only the  dissolved
concentrations   but  also  the  sediment absorbed  concentrations  of  the
contaminants.   Equation 5-13  can  be  used to obtain  an  estimate of  the
contaminant concentration in the sediment  after a given number of years of
deposition.
                                    7-5

-------
                                LIMITATIONS

GENERAL DISCUSSION

The  Equation  Workbook  was designed  to  provide detailed  guidance,  with
examples, in the  use  of the equations incorporated into each of the seven
protocol stages for  ocean  disposal  site designation.   The procedures and
equations were  developed  within  the  limitations  of  a  non-computerized
approach so  that  the  numerical  calculations  could  be  carried out  on  a
hand-held  scientific  calculator.    The  overall  strategy  was  to  use
conservative  assumptions,  recognizing  that  in some instances the simplicity
of the  proposed approach might  not  be adequate for the  analysis of highly
complex hydrodynamic  and biological  situations.

The disposal  site  designation  study  is considered to be  a general exercise,
requiring a  relatively low  level  of  effort,  in  which a specific  site(s) has
been proposed for the disposal of a single class  of waste,  such as dredged
material,  sewage sludge  or  industrial by-products.   This  process is
considered  to be  a first-level  evaluation.  If  the  site were found to be
acceptable  at this level,  a more detailed waste-specific  study would follow
as part of  the permit application process.

A major  limitation inherent to  the  equations  and methods  presented in the
protocol  is  the  simplification of  complex processes.  At times these
simplifications  may exclude processes  that,  under certain situations, would
be very  important.   Furthermore, the  assumptions may not be particularly
applicable  to certain disposal operations and waste characteristics.  Some
of  these  cases  are  discussed  below.     Simplified  procedures  may  be
appropriate  for general disposal site  designation studies,  disposal site
comparisons  based on  major  physical  processes,  and estimation of the risk
to  biological   resources.     These   procedures,   however,   may  omit  some
considerations of the physical  behavior  of the disposed waste which  could
be important in the estimation of areal  distribution, settling  and  initial
mixing.
                                    8-1

-------
The physical  behavior of the  disposal materials  such as dredged material or
sewage sludge may be  characterized  generically.   In  addition,  the general
behavior  of  the disposed  waste  will   depend  on whether  it  is neutrally,
negatively or positively buoyant.   Although  the site designation protocol
is  applicable  for  generic  types of waste,  many of  the procedures  and
equations are best  suited  for dredged materials.  The treatment of other
wastes such  as  acid waste,  may  necessitate  modifications to  the general
assumptions in the  protocol.

The  general   limitations  discussed  above  are a result of  the  use of
simplified and conservative  assumptions.   In the next section,  these
limitations are discussed  in more detail  for  several  specific  sections of
the protocol.

It  is  important to  bring out the limitations  of the protocol presented in
the Preliminary Ocean  Waste  Disposal   Site  Designation Manual  and  in  the
Equation  Workbook.   However,  it is not the intent of the  Equation Workbook
to  offer  alternative procedures  and  numerical   calculations  for specific
cases which may  require  modifications to  the original assumptions  so that a
more detailed analysis can  be undertaken.  The  Equation Workbook  offers to
the Corps Districts and EPA  Regions a  detailed  look at equations that are
available for their  use  in  ocean  waste  disposal  site designations.

SPECIFIC  LIMITATIONS

Several specific limitations  are presented in detail  in this section.  The
titles and numbers  given below  correspond to the titles and numbers  for the
appropriate stages.

Evaluate  and  Map Benthic Impact Areas for Negatively Buoyant  Solid
Wastes (3.T)

During descent,  the disposal  cloud falls at a rate determined  primarily by
its total  mass and size, and entrains water.  The cloud would  descend  to a
"dissipation" depth  at which its  initial  momentum  is  balanced  by  en-
trainment. After that,  the particles descend  approximately with  their  fall
                                   8-2

-------
velocities 1n the  ambient water  column.  The  complete  problem is  not
simple, and remains to be adequately parameterized  (ASA,  1983).   Instead,
the conceptually  simpler approach of Section 3.3 is used.

If the  depth  required  for  dissipation  is greater than  the total  depth  of
the site,  the  vertical momentum  will  be transferred horizontally and  the
cloud  will  spread out on  impact with  the  bed.   Several  "rule-of-thumb"
observations  are  proposed by  ASA (1983):   (a) one  can assume a fall
velocity of 3  m/sec for the main body of the solid waste; (b) for sites as
deep as  100 m,  the horizontal  displacement from the release  point can  be
regulated;  and  (c)  for sites of less  than 50  m,  all  the waste will  be
deposited within a  200 m  radius.   It should.be noted  that these observa-
tions  are  for  dredged  material  waste,  and  will  not necessarily  apply  to
other waste types,  such as municipal waste.

It should be further noted that simple disposal models,  such as that  of Koh
and Chang  (1973)  can  be  used to  better describe  the  initial disposal
dynamics for a  variety of waste types and ambient water conditions.

A second simplification in  this  section deals with the estimated area of
impact.  Using the  maximum  tidal components,  Utx  and Uty,  an area is  cal-
culated within which all  the material is  deposited.  However, it may  give
an average  depth of  coverage  which  does  not well  represent  the  actual
(near-Gaussian)  distribution (Figure 8-1).   A  better method may be to  cal-
culate the area of  impact using  the  average tidal components, 2*Utx/*  and
2*Uty/Jt  ,  which  will  give  a greater mean  depth,  and  a  closer  fit  to  the
actual  distribution  in  terms of  standard deviation  (i.e., width,  see
Figure 8-1).

Sediment Resuspension Potential for Typical Conditions  (3.4)

The techniques  used in this section  are based on  a   mean wave condition
using  Naval Weather Service Command  frequency  tables, and  neglects  the
direct effect of  wind-induced  currents  (except through generation of
waves).   In  addition,  the  use  of  Figure  D-7  does  not consider cohesive
                                   8-3

-------
                                   Depth
   Depth of Coverage Using
   Mean Tidal Components
                                                    Actual (near-Gaussian)
                                                    Distribution
                                                                 Depth of Coverage
                                                                 Using Maximum
                                                                 Tidal Components
Distance
Distance
Area of Impact Using
Mean Tidal Components
Area of Impact Using
Maximum Tidal Components
Figure  8-1.  Area of Impact  and Depth of Coverage Using Two Different Estimates.
                                     8-4

-------
material which  would  require  higher threshold  velocities,  Vt,  to  cause
resuspension, and thus will  tend to overestimate the potential to resuspend
in some cases.

There are several alternative approaches one might consider.  The U.S.  Army
Corps of Engineers uses a  significant wave  (defined  as  the average  of the
1/3  highest waves)  which  is  tabulated  in  the Shore  Protection Manual
(1977).   For  sites  where little  information  is  available,  the Corps
recommends  a  simple  wave  generation model  to   provide estimates of  wave
parameters.    Further,  if  a site  has known  cohesive  material,  a  figure
similar to Figure  D-7 would have  to be developed to estimate Vt, or  else
calculated  directly through a knowledge of critical shear stresses.

Resuspension  Probability Under  Episodic (Storm) Conditions  (3.5)

The same comments as  for Section 3.4  apply.

Calculate and Map Typical Long-Term Transport Contours (3.7)

The  calculations  in  this  section assume  that  the entire  liquid  and  fine
fraction phases of the waste mix uniformly throughout the water column (as
do the  calculations  in Stage  4).   This  assumes  no  settling of  the  fine
fraction phase to the bed.   Furthermore,  it assumes  no  resuspension of the
settled solids,  and  no contaminant release,  through   desorption,  to the
overlying water column from the sediment layer.

If these rates are known, from  whatever source, they can be easily added to
the estimation of the  actual water  column  loading rates Q or q, which are
used  in the  calculations  of  Stages  5 and 6.  An alternative  to the
assumption  of  vertical homogeneity,  and  to  perhaps include these other
contaminant  sources  to the water  column,  is to use  computer  disposal
models, some of  which have been developed at  the U.S.  Army COE Waterways
Experiment  Station.

Another limitation  of  this  section is  the distinction  between  choosing
continuous  and discrete source  models.   Although a continuous model  may be

                                   8-5

-------
suggested  by  the calculations  in  Section 3.7.2,  it is  possible  that  the
actual disposals may be so  infrequent  that  the previous disposal  cloud  has
been  transported  beyond the  region  of interest  before the  next  disposal
takes  place.   In  that event, it may be advisable  to use a discrete source
model.

Initial Dilution of Liquid Phase (4.3)

The mixing formula used in Equation (4-1)  is a reasonable approximation  for
barge-induced mixing.  In this case,  the barge is assumed to be moving with
velocity,  V,  and to  dispose the waste in  time,  t.  Alternative  formulae
could  be  used  such  as those presented by Csanady  (1981),  IMCO (1975),  and
the Corps  of  Engineers (1977).   None  of  these formulae can  be used  for a
stationary barge, however, as the  dilution will  tend to 0, which  will tend
to ignore initial  disposal  dynamics.

Source Strengths and Initial  Conditions (4.4)

The assumption in this section is that  the liquid and fine fractions of the
waste are uniformly mixed throughout the entire water column.  This may not
be the case.  For dredged wastes,  the  initial  cloud dynamics may  penetrate
a  shallow  pycnocline (<40 m, for  example)  and mix  the waste only  in  the
lower water column.   For municipal, chemical, and acid wastes, the waste is
much  closer  to the  density of  sea water  and the  seasonal, or  shallow,
pycnocline will often impede or  prevent the  waste  penetrating to  the lower
water column.

As a  first approximation, one could perhaps assume  complete mixing in  the
lower water column for dredged wastes, and  in  the  upper water column above
the seasonal  pycnocline for  these other wastes.  If more detailed knowledge
of the waste  characteristics and dynamics is  available,  it should be used
to modify procedures in this Workbook.
                                    8-6

-------
Vertical Distribution of Constituent Concentrations (4.5)

The techniques In this section consider mixing  processes Into  the sediment
layers  underlying the  deposited  solid fraction  of the waste.   Sources  to
the   overlying   water  column,   through   resuspension,  desorption,   and
diffusion, are neglected.

Near Field Acute Exposure  Level  (5.3)

The  concentration  of  a  constituent  in  the  water  column  after  disposal
(Equation 5-1) is a  function of the barge  volume, volumetric solid fraction
of waste, the concentration of the constituent in the waste  and the initial
mixing  volumes.   Equation 5-1  does not  adequately  consider the  mixing
characteristics  of the waste  itself and  this may  not  be applicable  in  all
cases.   For  example,  viscous  materials  such  as rum  distillery or  some
pharmaceutical wastes disperse slowly in water.   Other types of waste,  such
as iron  acid  waste,  flocculate in  seawater  and do not  settle or disperse
readily.  A more reliable  prediction of the  concentration of a constituent
in the water column  will  be obtained by modifying Equation 5-1 to take  this
type of situation into account.
                                    8-7

-------
                                 REFERENCES
ASA, 1983.  A Preliminary Ocean Waste Disposal  Site  Designation Manual by
Applied Science Associates,  Inc.  for U.S.  Environmental  Protection Agency,
Criteria and Standards Division.   Washington,  D.C.

Brooks, N.H., 1960.   Diffusion of Sewage Effluent in an  Ocean  Current.
Proc. First Int'l. Conf.  Waste Disposal  in the Marine Environment,
Berkeley, Calif.  July 1959,  pp.  246-267.

Carslaw, M.S. and J.C. Jaegar, 1959.  Conduction  of  Heat in  Solids,  Second
Edition, Oxford University Press, London,  U.K.

Csanady, G.T., 1973.   Turbulent Diffusion in  the  Environment.  D. Reidel
Publishing Company,  Dordrecht, Holland.

Csanady, G.T., 1981.   An  Analysis of Dumpsite Diffusion  Experiments.   In:
Ocean Dumping of Industrial  Wastes (Ketchum,  Kester  and  Park,  eds.), Marine
Science 12, Plenum Press, New York, N.Y., pp.  109-129.

Fair, et al., 1968.   Water and Wastewater Engineering, Volume  2.  John
Wiley 1 Sons, Inc.,  New York.

FDA, 1982.  Action Levels for Poisonous  or Deleterious Substances in Human
Food and Animal Feed.  Food  and Drug Administration, Bureau  of Foods,
Washington, D.C.

Fischer, H.B., E.J.  List, R.C.Y.  Koh, J. Imberger, and N.H.  Brooks,  1979.
Mixing in Inland and Coastal  Waters, Academic Press, 483 pp.

IMCO, 1975.  Procedures and  Arrangements for  the  Discharge of  Various
Liquid Substances; Method for Calculation of  Dilution Capacity in the
Ship's Wake.  International  Maritime Consultative Organization document,
MEPC III/7.

Koh, C.Y. and Y.C. Chang, 1973.  Mathematical  Model  for  Barged Ocean
Disposal of Wastes.   Prepared for U.S. EPA by Tetra  Tech Inc., Pasadena,
Calif., 178 p.

Madson, O.S. and W.D. Grant,  1976.  Sediment  Transport in the  Coastal
Environment.  Ralph M. Parson Laboratory Report No.  209, M.I.T.,  Cambridge,
Mass., 105 p.

Malisoff, 1982.  Mathematical  Models of Bioturbation. Ch. 7 in Animal-
Sediment Relations,  The Biogenic Alteration of Sediments (P.L. McCall  and
M.J.S. Tevesz, eds.), Plenum Press,  New York,  N.Y.

Okubo, A., 1971.  Oceanic Diffusion  Diagram.   Deep Sea Research,  18.

-------
Reed, M. and V.J.  Blerman,  1983.   Proceedings  of a  Workshop for  the
Development of a Scientific Protocol  for  Ocean Dump Site  Designation.
Edited by Mark Reed,  Applied Science  Associates,  Inc.  and Victor J.
Blerman, Jr., U.S. Environmental  Protection  Agency,  for U.S.  Environmental
Protection Agency, Criteria and  Standards Division,  Washington,  D.C.

U.S. Army Corps of Engineers,  1977.   Shore Protection  Manual.  Coastal
Engineering Research  Center,  3rd edition, 3  volumes.

U.S. Environmental Protection  Agency/U.S. Army Corps of Engineers, July
1977.  Technical  Committee  on  Criteria  for Dredged  and Fill  Material.
Environmental  Effects Laboratory,  U.S.  Army  COE Waterways Experiment
Station, Vicksburg, Miss.

-------
                 APPENDIX  A

     CROSS-REFERENCE  TABLE OF  EQUATIONS
IN PRELIMINARY  MANUAL AND  EQUATION WORKBOOK

-------
                    CROSS-REFERENCE TABLE OF EQUATIONS

                IN  PRELIMINARY MANUAL AND EQUATION WORKBOOK1
Equation Number in                                      Equation Number in

Preliminary Manual              EQUATION                 Equation Workbook


    (2-1)            Cws  = 2 Ci * Fi                            (2-1)

                          1=1, n


    (3-1)           Uw  =  (H /T)/sinh(2  h/L)                  (not included)



    (3-2)              L  -541                                (3-4)
    (3-3)               L1  =
    (3-4)            L'new  =  L<  *  L                               (3-6)
    (3-5)            Utot  =  Ubm +  Ut  +  Uw                        (3-8)


    (3-6)           Vtnew  =  Vt - Ubm  -  Ut                        (3-11)



    (3-7)              Lx  =  Utx * ^4  *-jr                        (3-16a)
                       Ly  = Uty  * I  *  -                        (3-16b)
    (3-8)              Dx = 0.0018 * Lx                         (3-17a)

                       Dy = 0.0018 * Ly                         (3-17b)


  This table only lists those equations that are numbered in the
  Preliminary Manual.  Some equation variables have been changed in the
  Wookbook for clarification. Some equations are deleted from Workbook
  because they were only references to theory which is applied by other
  equations that are included.


                                    A-l

-------
Equation Number in
Preliminary  Manual
            EQUATION
                                                  Equation Number in

                                                   Equation Workbook
    (3-9)
(4-1)



(4-2)



(4-3)
C(x,y)
                             d * (4* * Dy * Urn *  x)
                                                   172
                                                          (3-18)
                             exp
                                                Urn
                                             "*    *
                                                Dy  *  x
    (3-10)    C(x,y,t) »
                         41* d * (Dx * Dy)1/2 * t
                                            (3-19)
                             exp
(3-11)        C(x,y,t) =  —
                                 -(x - Um*t)'
                                                 4 * Dy
                                   2

                                  Dy * t
                                            - x + Um*t
                                   erf
                                         (4 * Dx * t)
                                                     T72,
                                            (3-20)
                   erf/ 7
        + x - Um*t
                          *    *
                            Dx
                    erf
                                f-y
                           erf
                          k(4 * Dy * t)1/2/       \(4 * Dy * t)
                      Vm = d *  (2w) * v * t
                      Dl =
         FT * Vb
           7m
                      Ds  =
                              * Vb * Ff * Ffs
                                   Ym
172




 (4-1)



 (4-4)



 (4-5)
                                   A-2

-------
Equation Number  in

Preliminary Manual
            EQUATION
                           Equation Number in

                            Equation Workbook
    (4-4)



    (4-5)



    (4-6)



    (4-7)
   * [FI  + (Fs  *  Ff  *  Ffs)]
                                             (4-6)
    Fwl  =(!-!!£)* [F1 +  (Fs * Ff * Ffs)]   (4-7)
    Fwt  = Fwu + Fwl
                  C(z,t) =
•(;
    (5-1)
    (5-2)
    (5-3)
    (5-4)
    (5-5)
    (5-6)
    (5-7)      q(i)
    ELi  = f.
            2*D
                              Mi
                   t    Y"  * cr/        \
                   * D /       exp\4 * D * tl
                                   X    n
                                    (4-8)



                                   l(4-ll)
                                  X      V
                                   * erfc ( - ?
                                         \(4 * D *
                            fi * Css
           BLi
     to =
      t =
                              w * v * t
                            16 *  (Dx*Dy)1/2
(5-3)
                                    (5-7)
                                                 ELi * Vm
                              ^ * d * D * C  = 4;r * d * D * WQCi
                                   ..(5-8)
          	MVi  *  Qa	
   q "    3600*24*365  * Tdd  *  (fi*Cs  +  1.0)
ci(o,t) = cod)  + Qd)
                                                  1/2
                                    (5-10)
                                    (5-13)
                                           C1
                           A  * 100
     Co(i) + Qd)  *
                                           •   (5-12)
                                                   /2

                                                              fi * Scs
                                          (5-14)
                                   A-3

-------
Equation Number in
Prelimi nary Manual
              EQUATION
                                                   Equation Number in
                                                    Equation Workbook
    (6-1)  BODis  =  0.0314 * BODw * Co * W *  (ta)1/2
                                               (6-4)
    (6-1)   dd = dwd *  fv *  sg  (part) *  (1-Ffs) *  ^  * 1000     (6-2)
    (6-3)   BODrs  =  BODw  *  (I  -  exp(-5 * k))
                                               (6-5)
    (6-4)   BODa  =  BODu  + BODrs
                                               (6-6)
(6-6)   BODd  =  BODa +
                               BODw
                                               (6-7)
    (6-7)   BODult  =  1.46  *  BODd
                                               (6-8)
    ,, ft\   nn<  -
    (6-8)   DOi  -
    (6-10)  OS  =
                       *  Vm)  +  (DOw  *  Vb)
                          Vm  +  Vb
erf

                                  1/2
                                               (6-9)
                                                            (6-10)
    (6-9)  D0(t)  =  DOa  -[DOa  -  DOi  + BODult *  (1  -  exp  (-k  *  t))]  * DS
                       *  exp(-k  *  t)
                       *  di  *  D  *  t
                      >n
    (6-14)  DODn =      [x(i)  -  x(i-H)]  *
               1=1,n-1
                                        exp(-k  *  t)
                                        +  exp(-k   *  t)
                                                                    (6-11)
                                               (6-13)
                                          expj1  dtj  *  dt))    <«-
                                                  14)
                                               (6-15)
                                    A-4

-------
Equation Number in                                      Equation Number in
Preliminary Manual             EQUATION                  Equation Workbook
    (6-16)  TOD = X   DOOj                                      (6-16)
                                     A-5

-------
APPENDIX B






DSP FORMS

-------
             FORM DSP1  BASIC SITE CHARACTERIZATION INFORMATION
	 . 	 • 	 1
Variable Name

Site Center Latitude
Longitude
Width
Length
Orientation of Longest Dimension
.Site Shape
Distance to Nearest*
(1) Coastline
(2) Fishery Area
(3) Recreational Area
(4) Shipping Lane
(5) Military Exclusion Zone
(6) Ocean Disposal Site
(7) Marine Sanctuary
(8) Engineering Uses of Seafloor
(Specify)
(9) Living Resources
Value
















Units

N
W
km
km


km
km
km
km
km
km
km
km

Source/Comments

Assigned
Assigned
Assigned
Assigned
Assigned
Assigned









*From closest site extremity,  not from site center
                                   B-l

-------
FORM DSP2  WASTE  SOURCE  AND  LOADING  CHARACTERIZATION
                       1I|  Comments
                        I  Value   |  Units   I  (Text  Symbol)
Variable Name
Waste Type
Annual Loading Rate
Typical Duration of Dredging
Operation
Typical Number of Disposals
per day
Bulk Specific Gravity
Liquid Phase Specific Gravity
Particle Specific Gravity
Clay-Silt/Sand-Gravel (Fine/
Coarse) Fractions (Total
Solid Phase)
Volumetric Solid/Liquid
Fractions
Fraction of Fines in Suspended
Cloud (Single Disposal)
Disposal Vessel
Vol ume
Width
Length
Speed
Individual Disposal
Duration
Frequency
Dredge r














later ial
m3/yr
fraction
of year

none
none
none
none
none
none
m3
m
m
m/sec
sec
per day

(Qa)
(Tdd)
(Dd)
(sg) bulk
default: 1.0 (sg)
particle
default: 2.65
( sg) particle
(Ff/Fc)
(Fs/Fl)
default: 0.9
(Ffs)
(Vb)
(w)
(1)
(V)
(t)
                       B-2

-------
       FORM  DSP3   REPRESENTATIVE WASTE  PROFILE  DESCRIPTION
(Mean Concentration  of  Constituents  Measured  in Source  Materials,
                  all  concentrations in mg/kg)


Fractional
Contribution
(Fi)
Constituent
Percent Sol ids
BOD
DO
pH
Total Chlorinated HC
Total Volatile
Orgam'cs
Cadmium
Copper
Lead
Mercury

















Source
A






























Source
B






























Source
C






























Source
D






























Source
E 1






























Weighted
Sum
(Cws)

1.00




























                            B-3

-------
FORM DSP4  GEOCHEMICAL SITE CHARACTERIZATION
Constituent
or
Characteristic

Percent Sol ids
Biochemical Oxygen Demand (BOD)
Dissolved Oxygen (DO)
pH
Total Chlorinated HC
Total Volatile Organics
Cadmium
Copper
Lead
Mercury















.



SEDIMENTS ONLY:
Percent Gravel
Percent Sand
Percent Silt
Percent Clay
Water Column
(Parts per Mill ion or






























Summer




Site Sediments
• mg/kg, Except Solids)






























Winter




                 B-4

-------
FORM DSPS  PHYSICAL OCEANOGRAPHIC CHARACTERIZATION
	
Variable Name

Maximum Depth
Minimum Depth
Mean Depth
Pycnocl ine Depth
Tidal Period
Ellipse Orientation
Major Axis Velocity
Minor Axis Velocity
Mean Net Surface Drift
Magnitude
Direction
Mean Net Bottom Drift
Magnitude
Direction
Mean Wave
Amp! itude
Period
Storm Induced Bottom Current
Water Temperature (Annual
Range
pH (Annual Range)
Value
















Units

m
m
m
m
hr
—
m/sec
m/sec
m/sec
m/sec

m
sec
m/sec
degrees
Celsius

Source/Comments 1
(Text Symbol) |



(h)
(hp)
(To)

(Utx)
(Uty)
(Urn)
(Ubm)

(H)
(T)
(Usw)
(T)

                    B-5

-------
FORM DSP6 WATER QUALITY CRITERIA COMPARISONS SUMMARY
Substance

Copper
Lead

























Concentration
Estimated
ppb




























Near Field
(Acute)
Criterion
ppb



























WQAi
Far Field
(Chronic)
Criterion
ppb






.




















WQCi
                       B-6

-------
        APPENDIX  C



          TABLES



(From Reference ASA,  1983)

-------
  ASA
         1/12/93
                              TAaLE C-l

               EPA SALTWATER QUALITY CRITERIA SUMMARY
                      (ppb or micrograms/Iiter)
SUBSTANCE
Arsenic ( ~3 )
Cadmium
C fi *• c m i u m ( - 6 )
Coo 3 ?r
LeaS
.»* a — r IJT \j
N i : < e i
Zinc



Arenas ntr.ene
A 1 -3 r i ri
Antimony*
C n lorinated
Benzenes
Ch 1 or- a form*
DDT
-DE
DDE
D e i 1 d r i n
Dithlorosrooane
Ere a s u 1 ran
Enc r i n
cl'joranthene
H»D tac h 1 o^
Heracn lorotiutad iene
°C3 (Auroclor)
Psnta Chlorcohenoi
Phtrtalats Es^ars
Tetrachloroethu Iene
To 1 uene
Toxeohene
V i n u i Chloride


24 HOUR
AVERAGE
LEVEL
(CHRONIC )
—
A. 5
IS
4. 0
50
0. 025
7. 1
5S



97
—
610
129
1240
0. 0010
—
— —
0. 0019
790
0. OO87 .
0. OO23
16
0. 0036
— —
0. 030
34
3. 4
45O
300O
0. 071
—


MAXIMUM
ALLOWABLE
(ACUTE)
08
59
1260
25
67
3. a
137
170



SCO
1. 3
9, OOO
160
2S, 900
0 13
3. 6
14
0. 71
10, 300
0 034
0 037
40
0 053
32
>10. 0
53
2944
12- 200
6300

— —


KL'MAN
HEALTH »*
( INGE5TICN
OF
ORGANISMS
ONLY)
1. 75 no /I
10
50
—
25
146 .
100
5000



20
—
45. 000
20
1. 57
0. C024 nq/1
—
—
—
14, 100
15 =
1. 0
54
0 C29 -ia/1
5

30
1. S
o aa
424, 000

52. 5


ACSCRSED-
DISSOLVED
PARTITION
CCEFr.

220, 000

130, COO
420, OOO


350, COO


















1 1-50, OOC








* fresnuat»r data only
<* These criteria aoply to water containing organisms
     ic n may be
   consumed by humans,  and take into consideration
   bioaccumulation potential of the substance.
the

-------
                                 TABLE C-2
                          ERROR FUNCTION (erf) AND
                    COMPLEMENTARY ERROR FUNCTION  (erfc)
                                            3.0.)

-------
     PUCENI FREQUENCY OF WAVE HEICMI cm vs WAVE PCRIUU (SECONDS)
(SEC)
6-7
1-9
10-11
12-1)
lOTil

<1 1-2 »-<• 5-6 1 «-9 lO-»« I* 13-16 1
V.6 2>.S i».8 2-6 1.0 .» 	 .1 1 1 •!
• .9 1J.6 I.B 1.9 ,« I ,6 J . ,*J
I '.i | — rH !i rV.i !e .1 i .1
.0 • • I .T .1 ».l -2 1 .1
.0 • .1 -0 .0 .1 .5 <• •<•
9.0 .S .7 .1 .1 « -0 0 «
1*21 2079 1^66 906 >7i 2«9 ISJ 92 97
silt . 3 and
7-1., 1
.0
.1
.1
.0
.0
, 16

a-u 11-1
.0 .(
.1
.0
.0
.0 .(
7
.1
• i •
* 26-Ji .
> .0
.0
.0
.0
.0
1 .0
) 1
A
w
.0
.0
.0
.0
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.0
.0
0
• 0

u-ta 4
.0
- .0
.0
.0
.0
.0
• o
0
. 0

9- 60 1
.0
.0
.0
.0
.0
.0
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0
• 0

1-70 1
.0
.0
.0
.0
.0
.0
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0
• 0

1-66
.0
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67, TOUl
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.0 )<•*
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0 7(,10
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HO I
2
6
7
10
0

Table C~to.  l-:.xani|>le U.S.  Naval  Wc:aLluM  S<;rvict; SSMO UaLa  Table
                              (lU)sLon a lea)

Lines lor  ieiuis|)ens ion  thresholds tor  sand  and sill  are superimposed
for  a site depth of 2^  melers,  usiiuj Ficjures  C-H and C-'J.

-------
                                 fMClNl  M(OU(NCV Jf UtVf HilCHi  IMI  VI  MtVf  MIIUO
MIC!
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k 1 0 1 0
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-------
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li! Wave l''rjr<|iu;nry T;il>li: fi>r S.in l-'r anc i :, flUCINI MfOUINC* Of MAVf HllfiHf IPfl Vt M«Vt Mil 100 lilCONOS) • • ft • nn A w\ P |CIU % MIC) «4 1 4-7 • -* 10-11 lt-l» >11 INOIT 1 101*1 4 re? >. Im • • 7. t. • • • • 7 It 4 10. Im_ A «_4, 7 •.! ^— ^ » » » • 1 l>. >. 4. 1. S. 1. 4. 1. >. 1. 4. 2. 1. 1. I- • • • * • • • • t 4»» 141 147 1*1 1 2>.4 K.4 17.* 10. J >|ft_ | • U* I l.( 1. f • 1. • ! • > 1* 1 ?.< i • I • 1. • r 7( k 4. til II 1 •" 1 1 t. t • • i 7 1.1 kl T 1 i | I- I . . • . .i .( .( 1 .< (in )t 11-14 14*1 10* «< 1 1 - « * «••> .0 .0 .0 1 .1 .1 1 .0 ) .1 ) .0 4 4 k .2 .1 I»» 4* 99~^' • • )A ft Aft 4*-Ai * 1 — *• '»• wl .0 .0 . . • . • • • • • • tll.1l 11* •' .1 .< .1 .< .< .< .( < .1 111-1 1 1-i > > I ) ) I > » t »Af 4 9 " • IIIIAI mm **• IUIAC ••••• Ml ••I l»t 141 110 10 I* It mi 100.0 Tub It; C-'Jf. l'x le from I lie National 'rocliiilc.il In formal ion Sri v Ire (NI'IS) in Washington D.C.


-------
                Dissolved Oxygen Saturation, mq/1
Tenser jtur a
'° C'
-
i
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26
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'able  C-4.     Dissolved oxygen  saturation values
              in relation to  salinity
              (Source:  Tetra Tech, Inc.,  1982
and temperature

-------
                                   corrt-
                            • xptl   laced
        chemical           !o« ^*B   lo« K*
 hepcachlor                    •        •

                           <°:"   -5:55
                           <°-3 =   -0-3 =

                            Too -°'32
.3SB                       <0.32   -0.32
 FWA-2-A                  <0.32    0.48
 FV/A-3-A                  <0.32    0.16
 FWA-4-A                  <0.32   -0.12
 nitrobenzene                1.13    1.51
 p-nttrophenoi                2.10    1.59
 naphthalene                 2.53    2.27
 chiorobenzene               2.55    2.47
 2.4.5-'.nchlorophenol         3. 23    2.40
 endrin                      3.17    3.24
 1.1.2.2-tetrachloroethylen«    1.59    1.56
 hexacnlorobenzene           3.39    3.91
 p-diphenylyl phenyl ither     2.74    4.23
 dipnenyl «ther               2.29    2.39
 carbon :etrichlorsde      •    1.24    1.32          _       .         ,      ,
                            2.33    2.2i          zxperinental  ar.d  r.oce.-
                            2.64    lie          correlated  biocor.cer.t r a:
 cnioropyrifo*                2.S7    3.50          c ,-..,.--  v    r^^  ,  . . . . ^ ^ . .
 2.5.5-'..-:chloropyndinol       0.49    0.03          '  "" ' "    . '  3  'I'     ' 7 '--'-•'
 r.urene                    3.      3.0           cr.emicals.    ,he   value   -..:
                            3.ii     3.06
dibenzofuran                3.13     2.80          U5 e   ~QT  0 i C magn i f i C at i O ;
2-chioropnen«nthrene         3.63     3.84           _,--,. -I..;,-,.   ;-  ....a«
pnen.nthrene                3.42     3.14          w d . - ai d >. * w ..a   .3  s - - - . -  -.
2-me'.ny iphenanthrene        3.48     3.54
heptacmor epoxide           4.15     4.08
?.? -DDE                    4.71     4.37
pentachiorophenol           2.39     3.59                        ,         ^ ^ , .
h«xaoromobiph«nyl          4.25     5.07           \frCi7l  MaC.\ay,  1 r 3 . .1
mechoxychior                3.92     3.76
.T.irex                       4.26     4.34
hexabromocycJododecane     4.2S     4.49
hexachiorocyc!open(adiene    1.47     4.19
hepcachloronorOornene       4.05     3.96
hexachioronorbornaaiene     3*. 31     3.96
A/ocior lOl^S                4.53     4.56
Aroclor 1243                4.35  .   4.79
Arocior 1254                5.00     5.15
Aroclor 1260                5.29     5.59
chlordane                   4.53     4.58
octacnloro«tyr«nt            4.52     4.97
p,p -DDT                    4.47     4.43
a.p'-DDT                    4.57     4.43
1,2,4-triehlorobenzene        3.32     2.91
5-bromotndole               1.15     1.55
2.4.5-cribromoanisole         2.94     3.16
jV-phenyl-2-naphthylamine     2.17     3.06
tri*(2.3-dibromopropyi)       0.44     3.66
  phosphate
:ricresyi phoiphatt           2.22     2.10
chlor-.nated ecoiane           1.53     5. 73
diphenylamine               1.43     2.10
toluenediamine               1.96     1.34
chloroform                  0.78     0.63
aeenaphthene                2.59     2.60
benz(a)anthracene           4.00     4.29
1.2.3.5-trichlorobenzene      3.26     3.14
tnfluralin                    3.76     4.02
pyrene                      3.43     3.56
9-methy!inthracene           3. 66     3.75
benzene                     1.10     0.79
anthracene                   2.98     3.02
4 chlorodiphenyl oxide       2.37     2.75
4-chlorobiphenyl             2.77     2.94
pencachlorobenzene          3.70     3.37
dieldrin                     4.11     4.16

-------
       APPENDIX  D



         FIGURES



(From Reference ASA,  1983)

-------
                      Figure
                               0-1
o*t   10   it    12    is

12
10
 «
 4
 4
 2
 0
• z
ta
ii
1<
12
10
 a
 «
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 2
 0
•2
12
30
;s
is
a
22
20
i«
l«
14
12
10
 8
 t
 4
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 0
•2
    \/
  221: mil. N.
                             is    i«    17    is   19    :o
                          1     T7
                          * FRANCISCO
            I  W  .  \/i  V :
                              A' >l  A A A
                             / \J\J W V4
                             f .** V V  v  ,\
                                           \/ \ /
                                    !     1
                          SCATTUE
                         XETCHIKAN
           WOT
ftfH
               /  v\ 7
             -V-
   $m
                                                  fc
                                                     i
                               t    '
                                                 I |
                                                     '
                       DUTCH HARBOR
                                  A
                     i
                          »: Uil
              234.
                      ( from Notional Octon Sgr»rj, NOAA , Tidi
           Typical  Tide  Curves Along Pacific  Coasts of the
           United States (Source:   U.S.  Army Coascai Engir.e
           Research Cancer ,  1973)
                                                             ering

-------
                      Figure  D-2
OAT   10    II    U
11
10
                         U    19    I*    17     II   if   20
                         HAMPTON *OAO$
                                                    ni
    A7\ A .l \ A /\-A~A A /\ /VA / \i/\ / \i A /' /\ I
v
ft
      yry v: v v  v  ^ v  v y \y y V \7 TV y
                                 MC
                       SAVANNAH *IVC* tNTB
                                                      A
     ^^
      :tS
  -^
                           ptHSAcem    !

                          gAtvcrroM
       II          1     i                1
                                              W^?
                 i

    Ml. 1.
              Z3i.
                        ( from Notional Oeton S»r»t j, NOAA, Tiai TOOIII)

                 Typical  Tide Curves Along Atlantic  and
                 Gulf Coasts (Source:   U.S.  Arr.y Coasral
                Research Cancer, 1973)

-------
                           Figure D-3
                         Oregon-Washington
Jen   Feb  Mar   Apr   May    Jun    Jul   Aug   Sep   Oct   Nov   Dec
          Mean Monthly Nearshore Wave Periods (Including Calms) for Five
          Coastal Segments (Source:   'J.5. ArT.y Coastal Engir.eerir.g
          Ceacar, 1973)

-------
                           Figure   D-4
                            Oregon-Washington
       Atlantic (south)-*-
        1      I
                                             Atlantic (north)
Jan
Feb   Mar    Apr   May   Jun   Jul    Aug   Sep   Oct   Nov   Dec
           Mean Monthly Nearshore Wave Heights for rive Coastal Segnents
           (Source:  U.S. Arny Ccascal Engineering Research Cenzer,  1972)

-------
                      Figure   D-5
Mem Wa«« Height it Co.cia
Location
Mean Anno.i
Vive Height (ft.)
Lortlilir* of Conierminoua United Suica
, . Mein Annual
Luutinn _, ,, , !
|Wtv« Hei^nt (ft.) !
Atlantic COMI
Mini*
MOOJC Peak
>tw Himpaiure
Hampton Bcadi
MaaMcJiuMlta
•INjuart
Cipe Cod
Rhode laiand
Point judilh
MiM|u«mieut
New York
Southampton
*'c«tliam|iton
Jonet Beach
Sliort [Veaeli
New Jer»ey
Monmoutli
Deal
•Tom« River
Brigantine
•Atlantic City

1.3

1.4

1.3
2.5

1.3
1.4

1.9
2.6
2.6
1.7

i.r
2J
2.0
1 «»
2.8
TAllanlicCity (BEP1 1.3
tAllanlic City 'CO 1 1.9
>«• Jency (com.)
l.ndlani Itland
Maryland
Ocean Cljr
Vlrpni*
AiMlcaijue
•Virginia Ocich
Virfinia Beach
Nort]> Carolina)
•Mag* Mead
Ntf* Head
WrigiidviHe
Oak laland
lloldrn Ueacii
Georgia
St. Simon laland
Florida
'Diytona Beach
Ponce deLeon
•Lake Worlli
•Pilm Be*cli
Ituca Raton
Hilltboro

1.9

1-3

2.6
1.3
2.0

3.0
3.9
2.3
1.2
1.7

0.4

1.9
•* ^
2.3
2.3
1.9
1.3
CuJf Coajt
Florida
•."
   t CIRC &«*CA £»iiu«oo«
(fuwbrtiktt) obnrrttiooi.
(Source:  U..S. Army Coascai  Engineering Research  Center,  1973)

-------
         Figure  D-6
Wenfworth Scale
(Size Description)
Boulder
Cobble
Pebble
Granule
Sand
Very Coarse
Coarse
Medium
Fine
Very Fine
Silt
Clay
Colloid
Grain
Diameter
d (mm)
256
76.2
64.0
19.0
4.76
4.0
2.0
1.0
0.5
0.42
0.25
0.125
0.074
0.0625
0.00391
0.00024
U-S. Standard
Sieve Size
3 in.
s/4 in.
No. 4
No. 10
No. 40
No. 200
Unified Soil
Classification
(USC)
1
Cobble
Coarse
Fine
. Coarse
Medium
Fine
Gravel
Sand
Silt or Clay
Grain Size Scales  (Soil  Classification)
(Source:  U.S.  Army Coascal Zr.gir.eerir.g
Research Center,  1973)

-------
                   Figure  D-7
1000
                10            I02
                 SIZE OUMETES IN MICRONS
10'
   Current velocities required to transport particulates
   (Source:   Poscaa. 1967)

-------
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                   sediment  s i ze  -O.'I^U  mm  (mini i inn saiul)
                (Suture:  A|i|)lii'tl Sc iuuro Assnf i
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Fifj.  D-10.     W.ivo Induced Si,-d iiniMil  SuspiMiiJ ion
                    sfdim.'nl  size -  0.001  mm  (clriy)
                (Source:   A|)|)lloil Sr icii« c- Assix i .il >••; ,  I

-------
                   CLAY  CD  «  0.001  nun)
20    30
              40
                                 90
100
                      U  (cm/sec)
                       m
Figure  D-ll.
Volumetric  sediment transport rate versus

mean  flow  for various wave - induced bcttcr.

velocities.

(Source:  Applied Science Associacas,  Ir.c.)

-------
in



10S



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r
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c
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                          SILT  (D = 0.033  mm;
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                30
                                   70
                               U  (cm/sec)
                                m
Figure  D-12.  Volumetric sediment transport  rate ve:

              mean flow for  various wave-induced bo1

              velocities.

              (Source:  Applied 5cier.ce Associacas, lac.)
                                                             3 us

-------
                VERY FINE  SAND  (D = 0.074.
.=.CCcn/sacX
2
   :0cr./sec
    20
              50
50
60
70
30
                          U   (c m / 5 e c)
 .-igure  D-13.
                    Volumetric  sediment  transport  rate  ve
                    mean flew  for various  wave - induced  bo
                    velocities.
                    (Source:  Applied Science  Associates, Inc.)

-------
    10
   10'
     s  _
   10
1 •*      w
                             FINE SAND  (D  =  0. Id7 mm)
         :J -LCOcn/sec.'
    10°  Ir
    10
    10°
-'J
40
oO
/ 0
           Figure  D-14.
                     U   (cm/s e c)
                      m

             Volumetric  sedimsr.t  transport  rate versus
             mean flow for  various wave-induced bottcm
             velocities.
             (Source:  Applied Science  Associates, Inc.)

-------
:crj   io
             O»meier cm
D-15.    Settling velocities  of  discrete spherical
        particles in cuiescent  water at IOC.  /Fro
        Fain et al .  , 1963) Settling velocitv  -...-ill
                  "      1 '  ^ a -
                    'U.  i. -  y " - -1
        temperature.

        (Source:  Fair, ec al, 1963)
     increase about 1.> per  degree    ncrease

-------
                APPENDIX E






SUGGESTED SOURCES FOR DATA AND INFORMATION

-------
The reports and publications  denoted by "*"  are  recommended reading  for  all

designation efforts.   Others  are  suggested as additional  sources  of  data or

information.  This section is Appendix  D in  ASA  (1983).


Butson, K.D. and W.L.  Hatch,  1979.   Selective Guide  to Climatic Data
   Sources.  U.S. Department  of Commerce,  National Oceanic  and Atmospheric
   Administration, 142 pp.

Center for Natural Areas,  1977.   A  Summary and Analysis of  Environmental
   Information on the  Continental Shelf from the Bay of Fundy to  Cape
   Hatteras, 3 Volumes,  U.S.  Department of the Interior.  Bureau of Land
   Management.

Csanady, G.T., 1973.   Turbulent Diffusion  in the Environment. D.  Reidel
   Publishing Company, Dordrecht, Holland, 248 pp.

EPA/COE, 1977.  Technical  Committee on  Criteria  for  Dredged and Fill
   Material.  Environmental Effects Laboratory,  U.S. Army Engineer
   Waterways Experiment Station,  Vicksburg,  Miss.

*GESAMP, 1982.  Scientific Criteria for the  Selection of  Waste Disposal
   Sites at Sea.  IMCO/FAO/UNESCO/WMO/IAEA/UN/UNEP Joint  Group of Experts
   on the Scientific Aspects  of Marine  Pollution.  Reports  and Studies No.
   18.  Intergovernmental  Maritime  Consultative  Organization.

*Goldberg, E.D. (ed.), 1980.   Assimilative Capacity  of U.S. Coastal  Waters
   for Pollutants. Crystal Mount, Washington, July 29-August 4,  1979.  UTS'.
   Dept. of commerce,  National  Oceanic  and Atmospheric Administration,
   Env'l. Res. Lab., Boulder, Colorado.  Proceedings of Workshop, 284  pp.

Harris, D.L., 1981.  Tides and Tidal Datums  in the United States.  U.S.
   Army Corps of Engineers, Coastal Engineering  Research  Center,  Fort
   Belvoir, Va., 382  pp.

Komar, P.O., 1976. Beach  Processes and Sedimentation.  Prentice-Hall,
   Inc., Englewood Cliffs, New Jersey,  429 pp.

*MTS (Marine Technology Society),  1982.  Marine  Pollution Papers.
   Reprinted from the  Marine  Pollution  Sessions  of OCEANS '82 Conference
   Proceedings by the  NOAA Office of Marine  Pollution Assessment,
   Rockvllle, Md. 20852.  (M.A. Champ or R.L. Swanson)  pp.  995-1189.

*Pequegnat, W.E., D.D. Smith, R.M.  Darnell,  B.J. Presley, and R.O. Reid,
   1978.  Art Assessment of the Potential Impact of Dredged  Matrlal Disposal
   in the Open Ocean"U.S. Army  Corps  of Engineers, Vicksburg,  Miss., 635
   pp.

Stanley, D.J. and D.J.P. Swift,  1976.  Marine Sediment Transport and
   Environmental Management.   John  Wiley & Sons, N.Y., 602  pp.
                                    E-l

-------
U.S. Army Coastal Engineering Research Center, 1973.   Shore Protection
   Manual.  4 Volumes, U.S.  Government Printing Office, Washington—D~~C
   20402.

U.S. Dept. of Commerce, National  Oceanic and Atmospheric Administration,
   1973.  Environmental Conditions Within Specified Geographical  Reqions
   NOAA/EDIS, Washington, D.C.,  732 pp.       	—	—a	'

U.S. Dept. of Interior, Fish and Wildlife Service,  1980.  Handbook of
   Accute Toxicity of Chemicals  to Fish  and Aquatic Invertebrate^	
   Resource PUD 11 cation 13/.  Washington, U.C.,  97  pp.	'

U.S. Naval  Weather Service Command.  Summary of Synoptic Meteorological
   Observations (SSMO) Tables (for wave  period and  height frequency data)
   Available through NTIS, Washington, D.C.
                                   E-2

-------