Unrt»dSt«t«
Environmental Protection
AQWWV
          Office of Air Quality
          Planning and Standards
          Research Triangle Park NC 27711
MAY 1982
Air
                      Draft
                      EIS
VOC Fugitive
Emissions in
On-Shore
Natural Gas
Production  Industry —
Background Information
for Proposed Standards

Preliminary Draft

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                             NOTICE

This document has not been formally released by EPAand should not now be construed to represent Agency policy.
It is being circulated for comment on its technical accuracy and policy implications.
     VOC  Fugitive  Emissions in  On-Shore
      Natural  Gas Production  Industry —
              Background Information
              for Proposed  Standards
                  Emission Standards and Engineering Division
                           MAY 1982

                  U.S. ENVIRONMENTAL PROTECTION AGENCY
                     Office of Air, Noise, and Radiation
                  Office of Air Quality Planning and Standards
                  Research Triangle Park, North Carolina 27711

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This report has been reviewed by the Emission Standards and Engineering Division of the Office of Air
Quality Planning and Standards, EPA, and approved for publication. Mention of trade names or commercial
products is not intended to constitute endorsement or recommendation for use. Copies of this report are
available through the Library Services Office (MD-35), U.S. Environmental Protection Agency. Research
Triangle Park, N.C. 27711, or from the National Technical Information Services, 5285 Port Royal Road,
Springfield, Virginia 22161.

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                            TABLE OF CONTENTS
METRIC CONVERSION TABLE 	   iv
TABLE OF CONTENTS	v
LIST OF TABLES	viii
LIST OF FIGURES	xi
1.0  SUMMARY	1-1
     1.1  Regulatory Alternatives 	   1-1
     1.2  Environmental Impact	1-2
     1.3  Economic Impact	1-2
2.0  INTRODUCTION	2-1
     2.1  Background and Authority for Standards	2-1
     2.2  Selection of Categories of Stationary Sources ....   2-4
     2.3  Procedure for Development of Standards of
          Performance	2-6
     2.4  Consideration of Costs	2-8
     2.5  Consideration of Environmental Impacts	2-9
     2.6  Impact on Existing Sources	2-10
     2.7  Revision of Standards of Performance	2-11
3.0  SOURCES OF VOC EMISSIONS	3-1
     3.1  General	3-1
     3.2  Description of Fugitive Emission Sources	3-1
     3.3  Baseline Fugitive VOC Emissions 	   3-8
     3.4  References	3-12
                                iii

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                      TABLE OF CONTENTS (Continued)
4.0  EMISSION CONTROL TECHNIQUES	4-1
     4.1  Introduction	4-1
     4.2  Leak Detection and Repair Methods	4-1
     4.3  Preventive Programs 	  4-11
     4.4  References	4-18
5.0  MODIFICATION AND RECONSTRUCTION	  5-1
     5.1  General Discussion of Modification and Reconstruction
          Provisions	5-1
     5.2  Applicability of Modification and Reconstruction
          Provisions to Natural Gas/Gasoline Processing
          Plants	5-3
6.0  MODEL PLANTS AND REGULATORY ALTERNATIVES 	  6-1
     6.1  Introduction	6-1
     6.2  Model  Plants	6-1
     6.3  Regulatory Alternatives 	  6-2
     6.4  References	6-10
7.0  ENVIRONMENTAL IMPACTS	7-1
     7.1  Introduction	7-1
     7.2  Emissions Impact	7-1
     7.3  Water  Quality Impact	7-9
     7.4  Solid  Waste Impact	7-9
     7.5  Energy Impacts	7-9
     7.6  Other  Environmental Concerns	7-10
     7.7  References	7-12
8.0  COST ANALYSIS	  8-1
     8.1  Cost Analysis of Regulatory Alternatives	8-1
     8.2  Other  Cost Considerations	8-24
     8.3  References	8-27

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                      TABLE OF CONTENTS (Concluded)
9.0  ECONOMIC ANALYSIS	9-1
     9.1  Industry Profile	9-1
     9.2  Economic Impact Analysis	  9-21
     9.3  Potential Socioeconomic and Inflationary Impacts. .  .  9-30
     9.4  References	9-32
APPENDICES
     A    Evolution of the Background Information Document. .  .  A-l
     A.I  Literature Review 	  A-2
     A.2  Plant Visits	A-4
     A.3  Emission Source Testing 	  A-5
     A.4  Meetings with Industry	A-5
     A.5  Review Process	A-6
     B    Index to Environmental Considerations 	  B-l
     C    Emission Source Test Data	C-l
     C.I  Plant Description and Test Results	C-2
     C.2  References for Appendix C	C-7
     D    Emission Measurement and Continuous Monitoring.  . .  .  D-l
     D.I  Emission Measurement Methods  	  D-2
     D.2  Continuous Monitoring Systems and Devices 	  D-6
     D.3  Performance Test Method	D-7
     D.4  References	D-9
     E    Model for Evaluating the Effects of Leak
          Detection and Repair on Fugitive Emissions from
          Pumps and Valves	E-l
     E.I  Introduction	E-l
     E.2  Description of Model	E-l
     E.3  Model Outputs	E-3
     E.4  References	E-32

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                             LIST OF TABLES
Number                                                           Page

 1-1   Environmental and Economic Impacts of Regulatory
       Alternatives	 1-4

 3-1   Baseline Fugitive Emission Factors for Gas Plants .... 3-9

 3-2   Estimated Baseline Fugitive VOC Emissions From a
       Model Gas Plant	3-11
 4-1   Percentage of Components Predicted to be Leaking In An
       Individual Component Survey 	 4-4

 4-2   Percent of Total VOC Emissions Affected at Various
       Leak Definitions	4-8

 4-3   VOC Emission Correction Factors for Various Inspection
       Intervals, Allowable Repair Times, and Leak
       Definitions 	  ...... 	 4-12

 6-1   Example Types of Equipment Included and Excluded in
       Vessel Inventories for Model Plant Development	6-3

 6-2   Number of Components in Hydrocarbon Service and Number
       of Vessels at Four Gas Plants	6-4

 6-3   Ratios of Numbers of Components to Numbers of Vessels .   . 6-5

 6-4   Fugitive VOC Emission Sources for Three Model Gas
       Processing Plants	6-6

 6-5   Regulatory Alternatives for Fugitive VOC Emission
       Sources at Gas Processing Plants.	6-8

 7-1   Controlled Emission Factors for Various Inspection
       Intervals .	7-2

 7-2   Emissions for Regulatory Alternatives 	 7-4

 7-3   Annual Model Plant Emissions and Percent Emission
       Reduction From Regulatory Alternative I and From
       Previous Regulatory Alternative 	 7-7

 7-4   Projected Fugitive Emissions From Affected Model
       Plants for Regulatory Alternatives for 1983-1987	7-8

 7-5   Energy Impacts of Emission Reductions for
       Regulatory Alternatives for 1983-1987 	 7-11

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                       LIST OF TABLES (Continued)

Number                                                           Page
 8-1   Capital Cost Data	8-2
 8-2   Capital Cost Estimates for Model Plants 	 8-6
 8-3   Leak Detection and Repair Labor-Hour Requirements .... 8-10
 8-4   Leak Detection and Repair Costs	8-11
 8-5   Derivation of Annualized Labor, Administrative,
       Maintenance, and Capital Costs	8-12
 8-6   Labor-Hour Requirements for Initial Leak Repair 	 8-13
 8-7   Initial Leak Repair Costs	8-15
 8-8   Recovery Credits	8-16
 8-9   Annual Cost Estimates	8-17
 8-10  Cost Effectiveness of Regulatory Alternatives 	 8-20
 8-11  Cost Effectiveness by Component Type of Alternative
       Techniques for Control of Fugitive VOC Emissions From
       Natural Gas Plants (Model Plant B)	 8-23
 8-12  Fifth-Year Nationwide Costs of the
       Regulatory Alternatives 	 8-25
 8-13  Statutes That May Be Applicable to the Natural Gas
       Processing Industry 	 8-26
 9-1   Distribution of Gas Plants by Capacity (1980) 	 9-3
 9-2   Distribution of Gas Plants by Process Method (1980) ... 9-5
 9-3   Distribution of Gas Plants by Ownership (1980)	9-6
 9-4   Distribution of Gas Plants by State (1980)	9-7
 9-5   Production of Energy by Type, United States 	 9-8
 9-6   Aggregate Retail Price Elasticities of Demand, U.S.  .  .  . 9-9
 9-7   Natural Gas Gross Withdrawals and Marketed Onshore and
       Offshore Production 	 9-11
 9-8   Composite Financial Data for the Natural Gas Industry
       1976-1981 and 1983-1985 Estimates 	 9-14
 9-9   Projected Lower-48 States Conventional Natural Gas
       Production	9-16
 9-10  Projections of Natural Gas Supply:   Comparison of 1980
       Forecasts	9-18
 9-11  Estimated Number of New Gas Plants, 1983-1987 	 9-20
 9-12  Natural Gas Prices:  History and Projections for
       1965-1995	9-22
                               vii

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                       LIST OF TABLES (Concluded)
Number                                                           Page

 9-13  Onshore Natural Gas Processing, Total and Cumulative
       Before-Tax Net Annualized Cost of VOC NSPS Regulatory
       Alternatives 1983-1987		9-27

 9-14  Onshore Natural Gas Processing Model Plants' Before-Tax
       Net Annualized Cost of VOC NSPS Regulatory Alternatives
       Per Plant 	 ........ 9-28

 9-15  Onshore Natural Gas Processing Model Plants' After-Tax
       Net Annualized Cost of VOC NSPS Regulatory Alternatives
       Per Plant	9-29

 C-l   Gas Plants Tested for Fugitive Emissions  	 C-3

 C-2   Instrument Screening Data for EPA-Tested Gas Plants  . .  . C-5

 C-3   Soap Screening Data for API-Tested and
       EPA-Tested Gas Plants	C-6
 E-l   Results of the Modeled Leak Detection and
       Repair (LDR) Programs ..... 	 E-4

 E-2   Statistical Analysis (SAS) Program to Evaluate the Impact
       of a Maintenance Program on Fugitive Emissions
       From Valves and Pumps	E-5

 E-3   Input Data for Examining the Reduction in Average Leak
       Rate Due  to a Maintenance Program (Valves)	E-18

 E-4   Input Data for Examining the Reduction in Average Leak
       Rate Due  to a Maintenance Program (Pumps)	E-19

 E-5   Estimated Emission Factors and
       Mass Emission Reductions (Valves) 	 E-20

 E-6   Estimated Emission Factors and
       Mass Emission Reductions (Pumps)  ....... 	 E-21

 E-7   Fraction  of Sources Screened and Operated on by Year
       (Valves)	E-22

 E-8   Fraction  of Sources Screened and Operated on by Year
       (Pumps)	 E-23

 E-9   Fraction  of Sources Screened and Operated on by Month
       (Valves)	E-24

 E-10  Fraction  of Sources Screened and Operated on by Month
       (Pumps)	E-25

 E-ll  Estimated Emission Factors and Mass Emission
       Reduction by Quarter (Valves)  	 E-26

 E-12  Estimated Emission Factors and Mass Emission
       Reduction by Quarter (Pumps)   	 E-27

 E-13  Fractional Distribution of Sources by Period (Valves) .  . E-28
 E-14  Fractional Distribution of Sources by Period (Pumps)  .  . E-30
                                VTM

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                             LIST OF FIGURES

Number                                                           Page
 3-1   General schematic of natural gas-gasoline processing. .  .  3-2
 3-2   Diagram of a simple packed seal	3-3
 3-3   Diagram of a basic single mechanical seal	3-4
 3-4   Diagram of a gate valve	3-7
 3-5   Diagram of a spring-loaded relief valve 	  3-7
 4-1   Rupture disk intallation upstream of a relief valve . .  .  4-14
 4-2   Diagram of two closed-loop sampling systems 	  4-17
 9-1   Selected natural gas prices - three categories for the
       period 1955-1979	9-13
 9-2   Projected new discovery onshore natural gas production.  .  9-17
 E-l   Schematic diagram of the modeled leak detection
       and repair program	E-2

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                               1.  SUMMARY

1.1  REGULATORY ALTERNATIVES
     Standards of performance for new stationary sources of volatile
organic compounds (VOC) from fugitive emission sources in the onshore
natural gas production industry are being developed under the authority
of Section 111 of the Clean Air Act.   These standards would reduce
emissions from valves, relief valves, open-ended lines, compressor
seals, pump seals, and sampling connections.
     Four regulatory alternatives were considered.   Regulatory Alternative I
is the baseline alternative and represents the level of control that
would exist in the absence of any standards of performance.   Requirements
of Alternative II are:
     •    Quarterly instrument monitoring for leaks from valves, relief
          valves, and compressor seals;
     •    Quarterly instrument and weekly visual monitoring for leaks
          from pump seals; and
     •    Installation of caps (including plugs, flanges, or second
          valves) on open-ended lines.
     Regulatory Alternative III is more restrictive than Alternative II.
The requirements are as follows:
     •    Monthly monitoring of valves (if a particular valve is found
          not to be leaking for 3 successive months, then 2 months may
          be skipped before the next time it is monitored with an
          instrument);
     •    Monthly monitoring of relief valves and pump seals, and weekly
          visual inspection of pump seals;
     •    Installation of a vent control system to control compressor
          seal emissions;
     •    Installation of closed purge sampling systems on sampling
          connections; and
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     t    Installation of caps (including plugs, flanges, or second
          valves) on open-ended lines.
     Regulatory Alternative IV is the most stringent of the alternatives.
Monthly instrument monitoring would be required for valves, relief
valves would be equipped with a rupture disc, and pumps would be required
to have dual mechanical seals.  Other requirements would be the same as
Alternative III.
1.2  ENVIRONMENTAL IMPACT
     Fugitive emissions of VOC from affected gas production facilities
under Regulatory Alternative I would be approximately 22,000 Mg/yr in
1987, the fifth year of implementation.  This is compared to 6,900,
6,200, and 5,000 Mg/yr under Alternatives II, III, and IV, respectively.
     In addition to reducing emissions to the atmosphere, Alternatives II,
III, and IV would reduce liquid leaks, thereby reducing wastewater
treatment needs.  Some solid waste would be generated by the replacement
of existing equipment (e.g., replaced seal packing, rupture discs).
However, this amount of solid waste would be very small in comparison to
existing levels of solid waste generated by gas plants.
     Energy savings from VOC and non-VOC hydrocarbons would result under
Regulatory Alternatives II-IV.  Under Alternative II, hydrocarbons
recovered during the fifth year of implementation would have an energy
content of approximately 6,400 terajoules.  This is equivalent to the
heating valve of approximately 1,050 barrels of crude oil.  Hydrocarbons
recovered under Alternative III would result in slightly less energy
savings than Alternative II, because emissions are not recovered from
compressor seal leaks.  Alternative IV would result in energy savings of
approximately 6,900 terajoules, which is approximately equivalent to the
heating value of 1,120 barrels of crude oil.
     A more detailed analysis of environmental and energy impacts is
presented in Chapter 7.  A summary of the environmental impacts associated
with the four regulatory alternatives is shown in Table 1-1.
1.3  ECONOMIC IMPACT
     Costs incurred by the onshore natural gas production industry under
Regulatory Alternative II would actually be a credit due to the value of
the recovered hydrocarbons.  In the fifth year of implementation of
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Alternative II, a net annual credit of $160,000 would result.  Net
annual costs incurred during the fifth year under Alternative III would
be approximately $510,000; under Regulatory Alternative IV net annual
costs of over $7 million are incurred.  A more detailed analysis of
costs is included in Chapter 8.  Price impacts of the regulatory
alternatives are expected to be slight regardless of the regulatory
alternative.  No plant closures or curtailments are expected, and effects
on industry profitability, output, growth, and other factors would be
negligible or zero.  A more detailed economic analysis is presented in
Chapter 9.  A summary of environmental, energy, and economic impacts
associated with the alternatives is shown in Table 1-1.
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           Table  1-1.   ENVIRONMENTAL, ENERGY, AND ECONOMIC IMPACTS OF REGULATORY ALTERNATIVES
Administrative
Action
Regulatory
Alternative I
(No action)
Regulatory
Alternative II
Regulatory
Alternative III
Regulatory
Alternative IV
Air
Impact
0
+2**
+2**
+2**
Water
Impact
0
+1**
+1**
+1**
Solid
Waste Energy Noise
Impact Impact Impact
000
0 +1* 0
0 +1* 0
0 +1* 0
Economic
Impact
0
+1*
-i.
-I*
KEY:   + Beneficial impact
      - Adverse impact
0 No impact
1 Negligible impact
2 Small impact
3 Moderate impact
4 Large impact
  * Short-term impact
 ** Long-term impact
*** Irreversible impact

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                             2.  INTRODUCTION

2.1  BACKGROUND AND AUTHORITY FOR STANDARDS
     Before standards of performance are proposed as a Federal regulation,
air pollution control methods available to the affected industry and the
associated costs of installing and maintaining the control equipment are
examined in detail.  Various levels of control based on different technolo-
gies and degrees of efficiency are expressed as regulatory alternatives.
Each of these alternatives is studied by EPA as a prospective basis for a
standard.  The alternatives are investigated in terms of their impacts on
the economics and well-being of the industry, the impacts on the national
economy, and the impacts on the environment.   This document summarizes the
information obtained through these studies so that interested persons will
be privy to the information considered by EPA in the development of the
proposed standard.
     Standards of performance for new stationary sources are established
under Section 111 of the Clean Air Act (42 U.S.C.  7411) as amended, herein-
after referred to as the Act.  Section 111 directs the Administrator to
establish standards of performance for any category of new stationary
source of air pollution which "... causes,  or contributes significantly
to air pollution which may reasonably be anticipated to endanger public
health or welfare."
     The Act requires that standards of performance for stationary sources
reflect, ". .  .  the degree of emission reduction achievable which (taking
into consideration the cost of achieving such emission reduction, and any
nonair quality health and environmental impact and energy requirements) the
Administrator determines has been adequately demonstrated for that category
of sources."  The standards apply only to stationary sources, the construc-
tion or modification of which commences after regulations are proposed by
publication in the Federal Register.

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     The 1977 amendments to the Act altered or added numerous provisions
that apply to the process of establishing standards of performance.
     1.   EPA is required to list the categories of major stationary sources
that have not already been listed and regulated under standards of perfor-
mance.  Regulations must be promulgated for these new categories on the
following schedule:
     a.    25 percent of the listed categories by August 7, 1980.
     b.    75 percent of the listed categories by August 7, 1981.
     c.    100 percent of the listed categories by August 7, 1982.
A governor of a State may apply to the Administrator to add a category not
on the list or may apply to the Administrator to have a standard of perfor-
mance revised.
     2.   EPA is required to review the standards of performance every
4 years and, if appropriate, revise them.
     3.   EPA is authorized to promulgate a standard based on design, equip-
ment, work practice, or operational procedures when a standard based on
emission levels is not feasible.
     4.   The term "standards of performance" is redefined, and a new term
"technological system of continuous emission reduction" is defined. The new
definitions clarify that the control system must be continuous and may
include a low- or non-polluting process or operation.
     5.   The time between the proposal and promulgation of a standard under
section 111 of the Act may be extended to 6 months.
     Standards of performance, by themselves, do not guarantee protection
of health or welfare because they are not designed to achieve any specific
air quality levels.  Rather, they are designed to reflect the degree of
emission limitation achievable through application of the best adequately
demonstrated technological system of continuous emission reduction, taking
into consideration the cost of achieving such emission reduction, any
nonair-quality health and environmental impacts, and energy requirements.
     Congress had several reasons for including these requirements. First,
standards with a degree of uniformity are needed to avoid situations where
some States may attract industries by relaxing standards relative to other
States.   Second, stringent standards enhance the potential for long-term
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growth.  Third, stringent standards may help achieve long-term cost savings
by avoiding the need for more expensive retrofitting when pollution ceilings
may be reduced in the future. Fourth, certain types of standards for coal-
burning sources can adversely affect the coal market by driving up the
price of low-sulfur coal or effectively excluding certain coals from the
reserve base because their untreated pollution potentials are high.  Con-
gress does not intend that new source performance standards contribute to
these problems.  Fifth, the standard-setting process should create incen-
tives for improved technology.
     Promulgation of standards of performance does not prevent State or
local agencies from adopting more stringent emission limitations for the
same sources.  States are free under Section 116 of the Act to establish
even more stringent emission limits than those established under Section 111
or those necessary to attain or maintain the National  Ambient Air Quality
Standards (NAAQS) under Section 110.  Thus, new sources may in some cases
be subject to limitations more stringent than standards of performance
under Section 111, and prospective owners and operators of new sources
should be aware of this possibility in planning for such facilities.
     A similar situation may arise when a major emitting facility is to be
constructed in a geographic area that falls under the  prevention of signi-
ficant deterioration of air quality provisions of Part C of the Act.   These
provisions require, among other things, that major emitting facilities to
be constructed in such areas are to be subject to best available control
technology.   The term Best Available Control Technology (BACT), as defined
in the Act,  means
          ... an emission limitation based on the maximum degree of
          reduction of each pollutant subject to regulation under
          this Act emitted from, or which results from, any major
          emitting facility, which the permitting authority, on a
          case-by-case basis, taking into account energy, environ-
          mental, and economic impacts and other costs, determines is
          achievable for such facility through application of produc-
          tion processes and available methods, systems, and techniques,
          including fuel cleaning or treatment or innovative fuel
          combustion techniques for control of each such pollutant.
          In no event shall application of 'best available control
          technology'  result in emissions of any pollutants which
          will exceed the emissions allowed by any applicable standard
          established pursuant to Sections 111 or 112  of this Act.
          (Section 169(3))

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     Although standards of performance are normally structured in terms of
numerical  emission limits where feasible, alternative approaches are some-
times necessary.   In some cases physical measurement of emissions from a
new source may be impractical  or exorbitantly expensive.  Section lll(h)
provides that the Administrator may promulgate a design or equipment stan-
dard in those cases where it is not feasible to prescribe or enforce a
standard of performance.  For example, emissions of hydrocarbons from
storage vessels for petroleum liquids are greatest during tank filling.
The nature of the emissions, high concentrations for short periods during
filling and low concentrations for longer periods during storage, and the
configuration of storage tanks make direct emission measurement impractical.
Therefore, a more practical approach to standards of performance for storage
vessels has been equipment specification.
     In addition, Section lll(j) authorizes the Administrator to grant
waivers of compliance to permit a source to use innovative continuous
emission control technology.  In order to grant the waiver, the Admini-
strator must find:  (1) a substantial likelihood that the technology will
produce greater emission reductions than the standards require or an equi-
valent reduction at lower economic energy or environmental cost; (2) the
proposed system has not been adequately demonstrated; (3) the technology
will not cause or contribute to an unreasonable risk to the public health,
welfare, or safety; (4) the governor of the State where the source is
located consents; and (5) the waiver will not prevent the attainment or
maintenance of any ambient standard.   A waiver may have conditions attached
to assure the source will not prevent attainment of any NAAQS.   Any such
condition will have the force of a performance standard.  Finally, waivers
have definite end dates and may be terminated earlier if the conditions are
not met or if the system fails to perform as expected.   In such a case, the
source may be given up to 3 years to meet the standards with a mandatory
progress schedule.
2.2  SELECTION OF CATEGORIES OF STATIONARY SOURCES
     Section 111  of the Act directs the Adminstrator to list categories of
stationary sources.  The Administrator "...  shall include a category
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of^^sources in such list if in his judgement it causes, or contributes
significantly to, air pollution which may reasonably be anticipated to
endanger public health or welfare."  Proposal and promulgation of standards
of performance are to follow.
     Since passage of the Clean Air Amendments of 1970, considerable
attention has been given to the development of a system for assigning
priorities to various source categories.  The approach specifies areas of
interest by considering the broad strategy of the Agency for implementing
the Clean Air Act.  Often, these "areas" are actually pollutants emitted by
stationary sources.  Source categories that emit these pollutants are
evaluated and ranked by a process involving such factors as:  (1) the level
of emission control (if any) already required by State regulations,  (2) esti-
mated levels of control that might be required from standards of performance
for the source category, (3) projections of growth and replacement of
existing facilities for the source category, and (4) the estimated incremental
amount of air pollution that could be prevented in a preselected future
year by standards of performance for the source category.   Sources for
which new source performance standards were promulgated or under development
during 1977, or earlier, were selected on these criteria.
     The Act amendments of August 1977 establish specific criteria to be
used in determining priorities for all major source categories not yet
listed by EPA.  These are:  (1) the quantity of air pollutant emissions
that each such category will emit, or will be designed to emit;  (2)  the
extent to which each such pollutant may reasonably be anticipated to endan-
ger public health or welfare; and (3) the mobility and competitive nature
of each such category of sources and the consequent need for nationally
applicable new source standards of performance.
     The Administrator is to promulgate standards for these categories
according to the schedule referred to earlier.
     In some cases it may not be feasible immediately to develop a standard
for a source category with a high priority.   This might happen when a
program of research is needed to develop control techniques or because
techniques for sampling and measuring emissions may require refinement.  In
the developing of standards, differences in the time required to complete
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the necessary investigation for different source categories must also be
considered.   For example, substantially more time may be necessary if
numerous pollutants must be investigated from a single source category.
Further, even late in the development process the schedule for completion
of a standard may change.  For example, inablility to obtain emission data
from well-controlled sources in time to pursue the development process  in a
systematic fashion may force a change in scheduling.  Nevertheless, priority
ranking is, and will continue to be, used to establish the order in which
projects are initiated and resources assigned.
     After the source category has been chosen, the types of facilities
within the source category to which the standard will apply must be deter-
mined.  A source category may have several facilities that cause air pollu-
tion, and emissions from some of these facilities may vary from insignificant
to very expensive to control.  Economic studies of the source category and
of applicable control technology may show that air pollution control is
better served by applying standards to the more severe pollution sources.
For this reason, and because there is no adequately demonstrated system for
controlling emissions from certain facilities, standards often do not apply
to all facilities at a source. For the same reasons, the standards may not
apply to all air pollutants emitted.  Thus, although a source category may
be selected to be covered by a standard of performance, not all pollutants
or facilities within that source category may be covered by the standards.
2.3  PROCEDURE FOR DEVELOPMENT OF STANDARDS OF PERFORMANCE
     Standards of performance must (1) realistically reflect best demon-
strated control practice; (2) adequately consider the cost, the nonair-
quality health and environmental impacts, and the energy requirements of
such control; (3) be applicable to existing sources that are modified or
reconstructed as well as new installations; and (4) meet these conditions
for all variations of operating conditions being considered anywhere in the
country.
     The objective of a program for developing standards is to identify the
best technological system of continuous emission reduction that has been
adequately demonstrated.  The standard-setting process involves three
principal phases of activity:  (1) information gathering, (2) analysis of
the information, and (3) development of the standard of performance.

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     During the information-gathering phase, industries are queried through
a telephone survey, letters of inquiry, and plant visits by EPA representa-
tives.  Information is also gathered from many other sources to provide
reliable data that characterize the pollutant emissions from well-controlled
existing facilities.
     In the second phase of a project, the information about the industry
and the pollutants emitted is used in analytical studies.  Hypothetical
"model plants" are defined to provide a common basis for analysis.   The
model plant definitions, national pollutant emission data, and existing
State regulations governing emissions from the source category are then
used in establishing "regulatory alternatives."  These regulatory alterna-
tives are essentially different levels of emission control.
     EPA conducts studies to determine the impact of each regulatory alterna-
tive on the economics of the industry and on the national economy,  on the
environment, and on energy consumption.  From several possibly applicable
alternatives, EPA selects the single most plausible regulatory alternative
as the basis for a standard of performance for the source category under
study.
     In the third phase of a project, the selected regulatory alternative
is translated into a standard of performance, which, in turn,  is written in
the form of a Federal regulation.  The Federal regulation, when applied to
newly constructed plants, will limit emissions to the levels indicated in
the selected regulatory alternative.
     As early as is practical in each standard-setting project, EPA represen-
tatives discuss the possibilities of a standard and the form it might take
with members of the National Air Pollution Control Techniques Advisory
Committee.  Industry representatives and other interested parties also
participate in these meetings.
     The information acquired in the project is summarized in the Background
Information Document (BID).  The BID, the standard, and a preamble explaining
the standard are widely circulated to the industry being considered for
control, environmental groups, other government agencies, and offices
within EPA.   Through this extensive review process, the points of view of
expert reviewers are taken into consideration as changes are made to the
documentation.
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     A "proposal  package" is assembled and sent through the offices of EPA
Assistant Administrators for concurrence before the proposed standard is
officially endorsed by the EPA Administrator.  After being approved by the
EPA Administrator, the preamble and the proposed regulation are published
in the Federal Register.
     As a part of the Federal Register announcement of the proposed regula-
tion, the public is invited to participate in the standard-setting process.
EPA invites written comments on the proposal and also holds a public hearing
to discuss the proposed standard with interested parties. All public comments
are summarized and incorporated into a second volume of the BID.  All
information reviewed and generated in studies in support of the standard of
performance is available to the public in a "docket" on file in Washington,
D. C.
     Comments from the public are evaluated, and the standard of performance
may be altered in response to the comments.
     The  significant comments and EPA's position on the issues raised are
included  in the "preamble" of a "promulgation package," which also contains
the draft of  the final regulation.  The regulation is then subjected to
another round of review and refinement until it is approved by the EPA
Administrator.  After the Administrator signs the regulation, it is published
as a "final rule" in the Federal Register.
2.4  CONSIDERATION OF COSTS
     Section  317 of the Act requires an economic impact assessment with
respect to any standard of performance established under Section 111 of the
Act.  The assessment is required to contain an analysis of:  (1) the costs
of compliance with the regulation, including the extent to which the cost
of compliance varies depending on the effective date of the regulation and
the development of less expensive or more efficient methods of compliance;
(2) the potential inflationary or recessionary effects of the regulation;
(3) the effects the regulation might have on small business with respect to
competition;  (4) the effects of the regulation on consumer costs; and (5)
the effects of the regulation on energy use. Section 317 also requires that
the economic  impact assessment be as extensive as practicable.
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     The economic impact of a proposed standard upon an industry is usually
addressed both in absolute terms and in terms of the control costs that
would be incurred as a result of compliance with typical, existing State
control regulations.  An incremental approach is necessary because both new
and existing plants would be required to comply with State regulations in
the absence of a Federal standard of performance.   This approach requires a
detailed analysis of the economic impact from the cost differential that
would exist between a proposed standard of performance and the typical
State standard.
     Air pollutant emissions may cause water pollution problems, and cap-
tured potential air pollutants may pose a solid waste disposal problem. The
total environmental impact of an emission source must, therefore, be ana-
lyzed and the costs determined whenever possible.
     A thorough study of the profitability and price-setting mechanisms of
the industry is essential to the analysis so that an accurate estimate of
potential adverse economic impacts can be made for proposed standards.  It
is also essential to know the capital requirements for pollution control
systems already placed on plants so that the additional capital requirements
necessitated by these Federal standards can be placed in proper perspective.
Finally, it is necessary to assess the availability of capital to provide
the additional control equipment needed to meet the standards of performance.
2.5  CONSIDERATION OF ENVIRONMENTAL IMPACTS
     Section 102(2)(C) of the National  Environmental Policy Act (NEPA) of
1969 requires Federal agencies to prepare detailed environmental impact
statements on proposals for legislation and other major Federal actions
significantly affecting the quality of the human environment.  The objective
of NEPA is to build into the decisionmaking process of Federal agencies a
careful consideration of all environmental aspects of proposed actions.
     In a number of legal challenges to standards  of performance for various
industries, the United States Court of Appeals for the District of Columbia
Circuit has held that environmental  impact statements need not be prepared
by the Agency for proposed actions under Section 111 of the Clean Air Act.
Essentially, the Court of Appeals has determined that the best system of
emission reduction requires the Administrator to take into account counter-
                                  2-9

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productive environmental effects of a proposed standard, as well as economic
costs to the industry.   On this basis, therefore, the Court established a
narrow exemption from NEPA for EPA determination under Section 111.
     In addition to these judicial determinations, the Energy Supply and
Environmental Coordination Act (ESECA) of 1974 (PL-93-319) specifically
exempted proposed actions under the Clean Air Act from NEPA requirements.
According to Section 7(c)(l), "No action taken under the Clean Air Act
shall be deemed a major Federal action significantly affecting the quality
of the human environment within the meaning of the National Environmental
Policy Act of 1969" (15 U.S.C. 793(c)(l)).
     Nevertheless, the Agency has concluded that the preparation of environ-
mental impact statements could have beneficial effects on certain regulatory
actions.  Consequently, although not legally required to do so by
Section 102(2)(C) of NEPA, EPA has adopted a policy requiring that environ-
mental impact statements be prepared for various regulatory actions, including
standards of performance developed under Section 111 of the Act.  This
voluntary preparation of environmental impact statements, however, in no
way  legally subjects the Agency to NEPA requirements.
     To implement this policy, a separate section in this document is
devoted solely to an analysis of the potential environmental impacts asso-
ciated with the proposed standards.  Both adverse and beneficial impacts in
such areas as air and water pollution, increased solid waste disposal, and
increased energy consumption are discussed.
2.6  IMPACT ON EXISTING SOURCES
     Section 111 of the Act defines a new source as ".  .  .  any stationary
source, the construction or modification of which is commenced ..." after
the proposed standards are published.   An existing source is redefined as a
new source if "modified" or "reconstructed" as defined in amendments to the
general provisions of Subpart A of 40 CFR Part 60, which were promulgated
in the Federal Register on December 16, 1975 (40 FR 58416).
     Promulgation of a standard of performance requires States to establish
standards of performance for existing sources in the same industry under
Section 111 (d) of the Act if the standard for new sources limits emissions
of a designated pollutant (i.e., a pollutant for which air quality criteria
                                  2-10

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have not been issued under Section 108 or which has not been listed as a
hazardous pollutant under Section 112).  If a State does not act, EPA must
establish such standards.  General provisions outlining procedures for
control of existing sources under Section lll(d) were promulgated on
November 17, 1975, as Subpart B of 40 CFR Part 60 (40 FR 53340).
2.7  REVISION OF STANDARDS OF PERFORMANCE
     Congress was aware that the level of air pollution control  achievable
by any industry may improve with technological advances.   Accordingly,
section 111 of the Act provides that the Administrator ".  .  .  shall, at
least every 4 years, review and, if appropriate, revise ..."  the standards.
Revisions are made to assure that the standards continue to reflect the
best systems that become available in the future.   Such revisions will not
be retroactive, but will apply to stationary sources constructed or modified
after the proposal of the revised standards.
                                  2-11

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                      3.0  SOURCES OF VOC EMISSIONS

3.1  GENERAL
     Natural gas/gasoline processing plants are a part of the oil and
gas industry.  Natural gas is first gathered in the field directly from
gas wells or from oil/gas separation equipment (see Figure 3-1).  The
gas may be compressed at field stations for the purpose of transporting
it to treating or processing facilities.  Treating is necessary in
certain instances for removal of water, sulfur compounds, or carbon
dioxide.  Gas gathering, compression, and treating may or may not occur
at a gas plant.  For the purposes of this document, natural gas/gasoline
processing plants are defined as facilities engaged in the separation of
natural gas liquids from field gas and fractionation of the liquids into
natural gas products, such as ethane, propane, butane, and natural
gasoline.   Types of gas plants are:   absorption, refrigerated absorption,
refrigeration, compression, adsorption, cryogenic - Joule-Thomson, and
cryogenic-expander.
3.2  DESCRIPTION OF FUGITIVE EMISSION SOURCES
     In this document, fugitive emissions from gas plants are considered
to be those volatile organic compound (VOC) emissions that result when
process fluid (either gaseous or liquid) leaks from plant equipment.
VOC emissions are defined as nonmethane-nonethane hydrocarbon emissions.
There are many potential sources of fugitive emissions in a gas plant.
The following sources are considered in this chapter:  pumps, compressors,
valves, relief valves, open-ended lines, sampling connections, flanges
and connections, and gas-operated control valves.  These source types
are described below.
3.2.1  Pumps
     Pumps are used in gas plants for the movement of natural gas liquids.
The centrifugal pump is the most widely used pump.  However, other
                                 3-1

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 Sulfur
Recovery
                     Field Gas Gathering Systems
                          Field Compression
        Gas Treating
Sweetening and Dehydration
(H2S,  C02, and H20 Removal)
                      Separation of Natural Gas
                        Liquids from Field Gas
                          Fractionation of
                         Natural Gas Liquids
                                        Methane
                                       to Sales
                           Sales Products
     (ethane, propane, iso-butane, butane, natural gasoline,  etc.)
   Figure 3-1.   General  Schematic  of Natural  Gas-Gasoline Processing,
                                 3-2

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types, such as the positive-displacement, reciprocating  and  rotary
action, and special canned and diaphragm pumps, may  also be  used.
Natural gas liquids transferred by pumps can  leak at the point  of  contact
between the moving shaft and stationary casing.  Consequently,  all  pumps
except the canned-motor and diaphragm type require a seal at the point
where the shaft penetrates the housing in order to isolate the  pump's
interior from the atmosphere.
     Two generic types of seals, packed and mechanical,  are  currently in
use on pumps.  Packed seals can be used on both reciprocating and  rotary
action types of pumps.  As Figure 3-2 shows,  a packed seal consists of  a
cavity ("stuffing box") in the pump casing filled with special  packing
material that is compressed with a packing gland to  form a seal around
the shaft.  Lubrication is required to prevent the buildup of frictional
heat between the seal and shaft.  The necessary lubrication  is  provided
                                                             2
by a lubricant that flows between the packing and the shaft.
                                            Packing
                                            Gland
                                                 Atmosphere
                                                 End
             Figure  3-2.  Diagram of a simple packed seal.

Mechanical seals are limited in application to pumps with rotating
shafts and can further be categorized as single and dual mechanical
seals.  There are many variations to the basic design of mechanical
                                  3-3

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 seals,  but all  have a lapped seal face between a stationary  element and
 a rotating seal  ring.   In a single mechanical seal application
 (Figure 3-3),  the rotating-seal ring and stationary element  faces  are
 lapped  to  a very high degree of flatness to maintain contact throughout
 their entire mutual  surface area.  As with a packed seal, the seal  faces
 must  be lubricated to remove frictional heat.  However, because of  its
 construction,  much less lubricant is needed.
                 PUMP
                STUFFING
                  BOX
                                                 GLAND
                                                 'RING
              FLUID
               END
                                                     STATIONARY
                                                       ELEMENT

                                                     POSSIBLE
                                                     LEAK AREA
                       SHAFT
                                          »ROTATING
                                          SEAL RING
         Figure  3-3.   Diagram  of  a  basic  single mechanical  seal.2

 3.2.2  Compressors
     Gas compressors  used  in  process  units  are similar to  pumps in that
they can be driven by rotary  or  reciprocating  shafts.   They are also
similar to pumps in their  need for shaft seals to  isolate  the process
gas from the atmosphere.   As  with  pumps,  these seals  can be the source
of fugitive emissions from compressors.
     Rotary shaft seals for compressors  may be chosen  from several
different types:  labyrinth,  restrictive  carbon rings,  mechanical
contact, and liquid film.  All of  these  seal types are  leak restriction
devices; none of them completely eliminate  leakage.  Many  compressors
may be equipped with  ports in the  seal area to evacuate collected  gases.
     Mechanical contact seals are  a common type  of seal for rotary
compressor shafts,  and are similar to the mechanical seals described for
pumps.   In this type of seal the clearance between the  rotating and
stationary elements is reduced to  zero.  Oil or  another suitable
                                 3-4

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lubricant is supplied to the seal faces.  Mechanical seals can achieve
the lowest leak rates of the tyes identified above, but they are not
                                       3
suitable for all processing conditions.
     Packed seals are used for reciprocating compressor shafts.  As with
pumps, the packing in the stuffing box is compressed with a gland to
form a seal.  Packing used on reciprocating compressor shafts is often
of the "chevron" or nested V type.   Because of safety considerations,
compressor seals are normally enclosed and vented outside of the compressor
building.  If hydrogen sulfide is present in the gas, then the vented
vapors are normally flared.
3.2.3  Process Valves
     One of the most common pieces of equipment in gas plants is the
valve.  The types of valves commonly used are globe, gate, plug, ball,
butterfly, relief, and check valves.   All except the relief valve (to be
discussed below) and check valve are activated through a valve stem,
which may have a rotational  or linear motion, depending on the specific
design.  This stem requires a seal to isolate the process fluid inside
the valve from the atmosphere as illustrated by the diagram of a gate
valve in Figure 3-4.   The possibility of a leak through this seal makes
it a potential source of fugitive emissions.   Since a check valve has no
stem or subsequent packing gland, it is not considered to be a potential
source of fugitive emissions.
     Sealing of the stem to prevent leakage can be achieved by packing
inside a packing gland or 0-ring seals.  Valves that require the stem to
move in and out with or without rotation must utilize a packing gland.
Conventional packing glands  are suited for a wide variety of packing
materials.   The most common are various types of braided asbestos that
contain lubricants.   Other packing materials include graphite,  graphite-
impregnated fibers,  and tetrafluoroethylene polymer.  The packing material
used depends on the valve application and configurator    These
conventional packing glands  can be used over a wide range of operating
temperatures.   At high pressures these glands must be quite tight to
attain a good seal.
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3.2.4  Pressure Relief Devices
     Engineering codes require that pressure-relieving  devices  or systems
.be used  in applications where the process  pressure  may  exceed the maximum
allowable working pressure of the vessel.  The  most common  type of
pressure-relieving device used in process  units is  the  pressure relief
valve  (Figure 3-5).  Typically,  relief valves are spring-loaded and
designed to  open when the process pressure exceeds  a set  pressure,
allowing the release of vapors or liquids  until  the system  pressure is
reduced  to its normal operating  level.  When the normal pressure is
                                                          o
reattained,  the valve reseats, and a  seal  is again  formed.   The seal  is
a disk on a  seat, and the possibility of a leak through this seal  makes
the  pressure relief valve a potential source of VOC fugitive emissions.
A seal leak  can result from corrosion or from improper  reseating of the
                                  2
valve  after  a relieving operation.
     Rupture disks may also be used in process  units.  These disks  are
made of  a material that ruptures when a set pressure is exceeded,  thus
allowing the system to depressurize.  The  advantage of a  rupture disk  is
that the disk seals tightly and  does  not allow  any  VOC to escape from
the  system under normal operation.  However, when the disk  does  rupture,
the  system depressurizes until atmospheric conditions are obtained,
unless the disk is used in series with a pressure relief  valve.
3.2.5  Open-Ended Lines
     Some valves are installed in a system so that  they function with
the  downstream line open to the  atmosphere.  Examples are purge  valves,
drain  valves, and vent valves.   A faulty valve  seat or incompletely
closed valve would result in  leakage  through the open-end of the line
and  fugitive VOC emissions to the atmosphere.
3.2.6  Flanges and Connections
     Flanges are bolted, gasket-sealed junctions used wherever pipe or
other  equipment such as vessels, pumps, valves,  and heat  exchangers may
require  isolation or removal.  Connections are  all  other  non-welded
fittings that serve a similar purpose to flanges, that also allow  bends
in pipes (ells), joining two pipes (couplings),  or  joining  three or four
pipes  (tees  or crosses).  The connections  are typically threaded.
                                 3-6

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            PACKING
             GLAND
                                          POSSIBLE
                                          LEAK AREAS
            PACKING
           Figure  3-4.   Diagram of a  gate  valve.'
                 Possible
                 Leak Area
                              Process Side
Figure 3-5.   Diagram of a spring-loaded relief valve.
                          3-7

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     Flanges may become fugitive emission sources when leakage occurs
due to improperly chosen gaskets or poorly assembled flanges.  The
primary cause of flange leakage is due to thermal stress that piping or
flanges in some services undergo; this results in the deformation of the
                              q
seal between the flange faces.   Threaded connections may leak if the
threads become damaged or corroded, or if tightened without sufficient
lubrication or torque.
3.2.7  Gas-Operated Control Valves
     Pneumatic control valves are used widely in process control at gas
plants.  Typically, compressed air is used as the operating medium for
these control valves.   In certain instances, however, field gas or flash
gas is used to supply pressure.    Since gas is either continuously bled
to the atmosphere or is bled each time the valve is activated, this can
potentially be a large source of fugitive emissions.   There are also
some instances where highly pressurized field gas is used as the operating
medium for emergency control valves.   However, these valves are seldom
activated and, therefore, have a much lower emissions potential than
control valves in routine service.
3.2.8  Sampling Connections
     The operation of a gas plant is  checked periodically by routine
analyses of process fluids.  To obtain representative samples for these
analyses, sampling lines must first be purged prior to sampling.   The
purged liquid or vapor is sometimes drained onto the ground or into a
drain, where it can evaporate and release VOC emissions to the atmosphere.
3.3  BASELINE FUGITIVE VOC EMISSIONS
     Baseline fugitive emission data  have been obtained at six natural
gas/gasoline processing plants.   Two  of the plants were tested by Rockwell
International under contract to the American Petroleum Institute,   and
                                                                    -i y
four plants were tested by Radian Corporation under contract to EPA.
Baseline fugitive emission factors for six of the seven component types
                               12
were developed from these data.     The baseline emission factor for one
component type, sampling connections, was developed from refinery data.
The emission factors are presented in Table 3-1.   The factors represent
the average baseline emission rate from each of the components of a
specific type in a gas plant.
                                 3-8

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           Table 3-1.  BASELINE FUGITIVE EMISSION FACTORS FOR
                           GAS PLANTS, kg/day

Component
Valves3
Relief valves9
Open-ended lines3
Compressor seals3
Pump seals3
Sampling connections
Flanges and3
connections
Emission factor
0.18
0.33
0.34
1.0
1.2
0.36
0.011
(0.48)
(4.5)
(0.53)
(4.9)
(1.5)
(0.36)
(0.026)
95% Confidence interval
0.1-0.3
0.007-8
0.1-0.7
0.1-5
0.5-3

0.006-0.02
(0.2-1)
(0.1-100)
(0.2-1)
(0.7-30)
(0.5-4)

(0.01-0.05)
 xx = VOC emission values.
(xx)= Total hydrocarbon emission values.

Reference 12.

 Sufficient data are not available to estimate the amount of methane-
 ethane present.  Therefore, the total hydrocarbon emission value is
 assumed to be equal to the VOC emission value.   Confidence intervals
 are not available.   Reference 13.
                                 3-9

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     The total daily and annual emissions from fugitive sources at a
model gas plant are shown in Table 3-2.  Total daily emissions are
calculated by multiplying the number of pieces of each type of equipment
by the corresponding daily emission factor.   The average percent of
total emissions attributed to each component type is also presented in
Table 3-2.
                                 3-10

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       Table 3-2.   ESTIMATED BASELINE FUGITIVE VOC EMISSIONS FROM
                            A MODEL GAS PLANT

Component Number of
type components
Valves
Relief valves
Open-ended lines
Compressor seals
Pump seals
Sampling connections
Flanges and 3
connections
750
12
150
6
6
21
,000
Total baseline emissions
Baseline
emissions,
kg/day
140
4.0
51
6.0
7.2
7.6
33
249
(360)
( 54)
( 80)
( 29)
( 9.0)
( 7.6)
( 78)
(618)
Percentage of
total emissions
56
2
20
2
3
3
13

(58)
( 9)
(13)
( 5)
( 1)
( 1)
(13)

 xx  =  VOC emission values.
(xx) =  Total hydrocarbon emissions values.

aFrom Table 3-1.
                                 3-11

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3.4  REFERENCES

 1.  Cantrell, A.  Worldwide Gas Processing.  Oil and Gas Journal,
     July 14, 1980.  p. 88.

 2.  Erikson, D.G., and V. Kalcevic.  Emissions Control Options  for  the
     Synthetic Organic Chemicals Manufacturing Industry, Fugitive  Emissions
     Report, Draft Final.  Hydroscience, Inc., 1979.

 3.  Nelson, W.E.  Compressor Seal Fundamentals.  Hydrocarbon  Processing,
     56(12):91-95.  1977.

 4.  Telecon.  R.A. McAllister, TRW, to G.H. Holliday, Shell Oil,  Houston,
     Texas.  March 10, 1981.  Compressors and seals at gas plants.

 5.  Letter from Hennings, T.J., TRW to K.C. Hustvedt, EPA.  May 13,  1981.
     Results of a telephone survey concerning the use of pneumatic
     control valves at gas plants.

 6.  Lyons, J.D., and C.L. Ashland, Jr.   Lyons' Encyclopedia of Valves.
     New York, Van Nostrand Reinhold Co., 1975.  290 p.

 7.  Templeton, H.C.   Valve Installation, Operation and Maintenance.
     Chem. E., 78(23)141-149, 1971.

 8.  Steigerwald, B.J.  Emissions of Hydrocarbons to the Atmosphere  from
     Seals on Pumps and Compressors.  Report No. 6, PB 216 582, Joint
     District, Federal and State Project for the Evaluation of Refinery
     Emissions.  Air Pollution Control District, County of Los Angeles,
     California.   April 1958.  37 p.

 9.  McFarland, I.  Preventing Flange Fires.  Chemical Engineering
     Progress, 65(8):59-61.  1969.

10.  Letter from Hennings, T.J., TRW to K.C. Hustvedt, EPA.  June 30, 1981.
     Results of a telephone survey concerning control of fugitive emissions
     from gas plant compressor seals.

11.  Eaton, W.S., et al.  Fugitive Hydrocarbon Emissions from Petroleum
     Production Operations.  API Publication No. 4322.  March 1980.

12.  DuBose, D.A., J.I. Steinmetz, and G.E.  Harris.   Emission Factors
     and Leak Frequencies for Fittings in Gas Plants, Draft Final Report.
     Radian Corp.  September 8, 1981.

13.  Memo from Hustvedt, K. C. , EPA to J. F. Durham, EPA.  Development
     of a sampling connection purge emission factor.  October 13, 1981.
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                     4.  EMISSION CONTROL TECHNIQUES

4.1  INTRODUCTION
     Sources of fugitive VOC emissions from gas plant equipment were
identified in Chapter 3 of this document.  This chapter discusses the
emission control techniques that can be applied to reduce fugitive VOC
emissions from these sources.  These techniques include leak detection
and repair programs and equipment specifications.   The estimated control
effectiveness of the techniques is also presented.  In some cases, the
techniques for reducing gas plant fugitive emissions are based on transfer
of control technology as applied to related industries.   This approach
is possible because the related industries (e.g.,  refineries) use similar
types of equipment, such as valves, pumps, and compressors.   There may
be differences between gas plants and related industries in average line
temperatures, product composition, or other parameters.   However, these
differences do not influence the applicability of the techniques used in
controlling fugitive emissions.
     This chapter (Section 4.4) also presents other control  strategies
applicable to control of fugitive emissions from gas plants.   However,
the control effectiveness of these alternative strategies has not been
estimated.
4.2  LEAK DETECTION AND REPAIR METHODS
     Leak detection and repair methods can be applied in order to reduce
fugitive emissions from gas plant sources.  Leak detection methods are
used to identify equipment components that are emitting significant
amounts of VOC.   Emissions from leaking sources may be reduced by three
general methods:  repair, modification, or replacement of the source.
                                 4-1

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4.2.1  Leak Detection Techniques
     Various monitoring techniques that can be used in a leak detection
program include individual component surveys, unit area (walk-through)
surveys, and fixed-point monitoring systems.  These emission detection
methods would yield qualitative indications of leaks.
     4.2.1.1  Individual Component Survey.   Each fugitive emission
source (pump, valve, compressor, etc.) is checked for VOC leakage in an
individual component survey.   The source may be checked for leakage by
visual, audible, olfactory, soap solution,  or instrument techniques.
Visual methods are good for locating liquid leaks, especially pump seal
failures.   High pressure leaks may be detected by hearing the escaping
vapors, and leaks of odorous  materials may  be detected by smell.
Predominant industry practices are leak detection by visual, audible,
and olfactory methods.   However, in many instances, even very large VOC
leaks are not detected by these methods.
     Applying a soap solution on equipment  components  is one individual
survey method.  If bubbles are seen in the  soap solution,  a leak from
the component is indicated.  The method requires that  the observer
subjectively determine the rate of leakage  based on formation of soap
bubbles over a specified time period.   The  method is not appropriate for
very hot sources, although ethylene glycol  can be added to the soap
solution to extend the temperature range.   This method is also not
suited for moving shafts on pumps or compressors, since the motion of
the shaft may cause entrainment of air in the soap solution and indicate
a leak when none is present.   In addition,  the method  cannot generally
be applied to open sources such as relief valves or vents without
additional equipment.
     The use of portable hydrocarbon detection instruments is the best
known individual survey method for identifying leaks of VOC from equip-
ment components because it is applicable to all types  of sources.  The
instrument is used to sample  and analyze the air in close proximity to
the potential leak surface by traversing the sampling  probe tip over the
entire area where leaks may occur.   This sampling traverse is called
"monitoring" in subsequent descriptions.  A measure of the hydrocarbon
concentration of the sampled  air is displayed in the instrument meter.
                                 4-2

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The performance criteria for monitoring instruments and a description of
instrument survey methods are included in Appendix D.  Table 4-1 presents
data on the percentage of components that are predicted to have instrument
readings greater than or equal to various concentrations during an
individual component survey.
     4.2.1.2  Unit Area Survey.  A unit area or walk-through survey
entails measuring the ambient VOC concentration within a given distance,
for example, one meter, of all equipment located on ground levels and
other accessible levels within a processing area.  These measurements
are performed with a portable VOC detection instrument utilizing a strip
chart recorder.
     The instrument operator walks a predetermined path to assure total
available coverage of a unit on both the upwind and downwind sides of
the equipment, noting on the chart record the location in a unit where
any elevated VOC concentrations are detected.   If an elevated VOC
concentration is recorded, the components in that area can be screened
individually to locate the specific leaking equipment.
     It is estimated that 50 percent of all significant leaks in a unit
are detected by the walk-through survey, provided that there are only a
few pieces of leaking equipment, thus reducing the VOC background con-
centration sufficiently to allow for reliable detection.
     The major advantages of the unit area survey are that leaks from
accessible leak sources near the ground can be located quickly and that
the leak detection manpower requirements can be lower than those for the
individual component survey.  Some of the shortcomings of this method
are that VOC emissions from adjacent units can cause false leak indica-
tions; high or intermittent winds (local meteorological conditions) can
increase dispersion of VOC, causing leaks to be undetected;  elevated
equipment leaks may not be detected; and additional  effort is necessary
to locate the specific leaking equipment, i.e., individual  checks in
areas where high concentrations are found.
     4.2.1.3  Fixed-Point Monitors.   This method consists of placing
several  automatic hydrocarbon sampling and analysis  instruments at
various  locations in the process unit.   The instruments may sample the
ambient  air intermittently or continuously.   Elevated hydrocarbon
                                 4-3

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                 Table 4-1.  PERCENTAGE OF COMPONENTS PREDICTED TO BE LEAKING
                                IN AN INDIVIDUAL COMPONENT SURVEY

Component
type
Valves3
Relief valves
Compressor seals3
Pump seals3


>100,000 ppmv
9
8
20
10
Predicted

> 50, 000 ppmv
11
11
27
22
percent of sources leaking

> 20, 000 ppmv
14
15
35
26

> 10, 000 ppmv
18
19
43
33

>1,000 ppmv
28
34
60
53
 Reference 1.
'Reference 2.

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concentrations indicate a leaking component.  As in the walk-through
method, an individual component survey is required to identify the
specific leaking component in the area.  Leaks from adjacent units and
meteorological conditions may affect the results obtained.  The efficiency
of this method is not well established, but it has been estimated that
33 percent of the number of leaks identified by a complete individual
                                                          A
component survey could be located by fixed^point monitors.   These leaks
would be detected sooner by fixed-point monitors than by use of portable
monitors, because the fixed-point monitors operate semi-continuously.
Fixed-point monitors are more expensive; multiple units may be required;
and the portable instrument is also required to locate the specific
leaking component.   Calibration and maintenance costs may be higher.
Fixed-point monitors have been used to detect emissions of hazardous  or
toxic substances (such as vinyl chloride) as well as potentially explosive
conditions.  Fixed-point monitors have an advantage in these cases,
since a particular compound can be selected as the sampling criterion.
     4.2.1.4  Visual Inspections.   Visual inspections can be performed
for any of the leak detection techniques discussed above to detect
evidence of liquid leakage from plant equipment.   When such evidence  is
observed, the operator can use a portable VOC detection instrument to
measure the VOC concentration of the source.  In a specific application,
visual inspections can be used to detect the failure of the outer seal
of a pump's dual mechanical seal system.   Observation of liquid leaking
along the shaft indicates an outer seal failure and signals the need  for
   ,     .  5
seal repair.
4.2.2  Repair Methods
     The following descriptions of repair methods include only those
features of each fugitive emission source (pump,  valve, etc.) that
should be considered in assessing the applicability and effectiveness of
each method.
     4.2.2.1  Valves.  Most valves have a packing gland that can be
tightened while in service.  Although this procedure should decrease  the
emissions from the valve, in some cases it may actually increase the
emission rate if the packing is old and brittle or has been overtightened.
Unbalanced tightening of the packing gland may also cause the packing
                                 4-5

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material to be positioned improperly in the valve and allow leakage.
Valves that are not often used can build up a "static" seal of paint or
hardened lubricant that could be broken by tightening the packing gland.
     Plug-type valves can be lubricated with grease to reduce emissions
around the plug.  Some types of valves have no means of in-service
repair and must be isolated from the process and removed for repair or
replacement.   Other valves, such as control valves, may be excluded from
in-service repair by operating procedures or safety procedures.  In many
cases, valves cannot be isolated from the process for removal.   If a
line must be shut down in order to isolate a leaking valve, the emissions
resulting from the shutdown may possibly be greater than the emissions
from the valve if it were allowed to leak until  the next process change
that permits isolation for repair.   Depending on site-specific factors,
it may also be possible to repair leaking process valves by injection of
a sealing fluid into the source of the leak.
     4.2.2.2  Relief valves.   In general, relief valves that leak must
be removed in order to repair the leak.   In some cases of improper
reseating, manual release of the valve may improve the seat seal.   In
order to remove the relief valve without shutting down the process, a
block valve should be attached while the faulty valve is repaired and
tested.  As an alternative to the potential hazard introduced by the
change of a block valve being mistakenly closed when a vessel  is over-
pressured, it may be preferable to install  a second block valve and
relief valve for use when the first relief valve is under repair.   An
even safer alternative is to install a three-way valve with parallel
                                                                    7 8
relief systems so that one of the two relief systems is always  open. '
     Some relief valves may be difficult to monitor.   It may be appropriate
to require less frequent monitoring for relief valves that are  difficult
to access because of location or hazardous operating conditions.
     4.2.2.3   Compressor seals.   Leaks from reciprocating compressor
seals may be reduced by the same repair procedures that were described
for pumps.  If the leak is small, temporary emissions resulting from a
shutdown may be greater than the emissions from the leaking seal.   It is
                                 4-6

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anticipated that for many reciprocating compressor seals it will not be
possible to bring leaks under the designated action level.  In these
instances i't would be more appropriate to vent leaks from compressor
seals to a control device.  This approach is described in Section 4.3.2.
     4.2.2.4  Pumps.  In some cases, it is possible to operate a spare
pump while the leaking pump is being repaired.  Leaks from packed seals
may be reduced by tightening the packing gland.  At some point, the
packing may deteriorate to the point where further tightening would have
no effect or possible even increase fugitive emissions from the seal.
The packing can be replaced with the pump out of service.  When mechanical
seals are utilized, the pump must be dismantled so the leaking seal can
be repaired or replaced.  Dismantling pumps may result in spillage of
some process fluid causing emissions of VOC.  These temporary emissions
have the potential of being greater than the continued leak from the
seal.  Therefore, the pump should be isolated from the process and
flushed of VOC as much as possible prior to repacking or seal  replacement.
     4.2.2.5  Flanges and Connections.   In some cases, leaks from flanges
can be reduced by replacing the flange gaskets.  Leaks from small threaded
connections can be reduced by placing synthetic (e.g., Teflon) tape or
"pipe dope" on the male threads before the connection is made.  Most
flanges and connections cannot be isolated to permit repair of leaks.
Data show that flanges and connections emit relatively small amounts of
VOC (Table 3-1).
4.2.3  Emission Control Effectiveness of Leak Detection and Repair
     The control  efficiency achieved by a leak detection and repair
program is dependent on several factors, including the leak definition,
inspection interval, and the allowable repair time.
     4.2.3.1  Definition of a Leak.   The first step in developing a
monitoring plan for fugitive VOC emissions is to define an instrument
meter reading that is indicative of an equipment leak.   The choice of
the meter reading for defining a leak is influenced by several consi-
derations.   The percent of total mass emissions that can potentially be
controlled by the leak detection and repair program can be affected by
varying the leak definition.   Table 4-2 gives the percent of total  mass
emissions affected at various leak definitions for a number of component
                                 4-7

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oo
                             Table 4-2.  PERCENT OF TOTAL EMISSIONS AFFECTED AT VARIOUS
                                                  LEAK DEFINITIONS

Percent of mass emissions affected at this leak definition
Component type
Valvesb
Relief valvesc
Compressor seals
Pump seals
100,000 ppmv
54
41
63
46
(59)
(42)
(64)
(47)
50,000 ppmv
64
53
75
63
(70)
(56)
(76)
(63)
20,000 ppmv
78
67
87
72
(83)
(69)
(88)
(71)
10,000 ppmv
86
77
92
79
(87)
(77)
(93)
(79)
1,000 ppmv
97
96
99
94
(98)
(96)
(99)
(94)
          xx  = VOC emission values.
         (xx) = Total  hydrocarbon emission valves.
          These figures relate the leak definition to the percentage of total  mass emissions that can
          be expected from sources with concentrations at the source greater than the leak definition.
          If these sources were instantaneously repaired to a zero leak rate and no new leaks occurred,
          then emissions could be expected to be reduced by this maximum theoretical  efficiency.

          Reference 1.

         'Reference 2.

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types.  From the table, it can be seen that, in general, a low leak
definition results in larger potential emission reductions.
     Other considerations are more source specific.  For valves, the
selection of an action level for defining a leak is a tradeoff between
the desire to locate all significant leaks and to ensure that emission
reductions are possible through maintenance.  Although test data show
that some valves with meter readings less than 10,000 ppm have significant
emission rates, most of the major emitters have meter readings greater
than 10,000 ppm.  Maintenance programs on valves have shown that emission
reductions are possible through on-line repair for essentially all
valves with non-zero meter readings.   There are, however, cases where
on-line repair attempts result in an increased emission rate.   The
increased emissions from such a source could be greater than the emission
reduction if maintenance is attempted on low leak valves.  These valves
should, however, be able to achieve essentially 100 percent emission
reduction through off-line repair.  Generally,  the emission rates from
valves with meter readings greater than or equal to 10,000 ppm are
significant enough so that an overall emission reduction is likely for a
leak detection and repair program with a 10,000 ppm leak definition.   In
addition, testing by EPA and industry has shown that meter readings will
generally be either much less than 10,000 ppm or much greater than
10,000 ppm. ' '    Therefore, 10,000 ppm seems  to be the most reasonable
leak definition to direct maintenance effort at the bulk of the valve
emissions while still having confidence that an overall emission reduction
will result.
     For pump and compressor seals, the rationale for selection of an
action level  is different because the cause of leakage is different.   As
opposed to valves, which generally have zero leakage, most seals leak to
a certain extent while operating normally.   These seals would tend to
have low instrument meter readings.  With time, however, as the seal
begins to wear, the concentration and emission rate are likely to increase.
At any time,  catastrophic seal failure can occur with a large increase
in the instrument meter reading and emission rate.   As shown in Table 4-2,
over 90 percent of the emissions from compressor seals and 80 percent of
the emissions from pump seals are from sources  with instrument meter
                                 4-9

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readings greater than or equal to 10,000 ppm.  Since properly designed,
installed, and operated seals should have low instrument meter readings,
and, since the bulk of the pump and compressor seal emissions are from
seals that have worn out or failed such that they have a concentration
equal to or greater than 10,000 ppm, this level was chosen as a reasonable
action level.
     4.2.3.2  Inspection Interval.  The length of time between inspections
should depend on the expected occurrence and recurrence of leaks after a
piece of equipment has been checked and/or repaired.  This interval can
be related to the type of equipment and service conditions, and different
intervals can be specified for different pieces of equipment.  Monitoring
may be scheduled on an annual, quarterly, monthly, or weekly basis.  The
choice of the interval affects the emission reduction achievable, since
more frequent inspection intervals will result in earlier detection and
repair of leaking sources.
     4.2.3.3  Allowable Repair Time.  If a leak is detected, the equipment
should be repaired within a certain time period.   The allowable repair
time should allow the plant operator sufficient time to obtain necessary
repair parts and maintain some degree of flexibility in overall  plant
maintenance scheduling.  The determination of this allowable repair time
will affect emission reductions by influencing the length of time that
leaking sources are allowed to continue to emit VOC.
     4.2.3.4  Estimation of Reduction Efficiency.   Data are presented in
Table 4-2 that show the expected percent of total  emissions from each
type of source contributed by those sources with VOC concentrations
greater than given leak definitions.  If a leak detection and repair
program resulted in repair of all such sources to 0 ppmv; elimination of
all sources over the leak definition between inspections, and instantaneous
repair of those sources found at each inspection,  then emissions could
be expected to be reduced by the amount reported in Table 4-2.  However,
since these conditions are not met in practice, the fraction of emissions
from sources with VOC concentrations over the leak definition represents
the theoretical maximum reduction efficiency.  The approach to estimation
of emission reduction presented here is to reduce this theoretical
maximum control efficiency by accounting quantitatively for those factors
outlined above.

                                 4-10

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     There are two models available for estimation of reduction efficiency

from leak detection and repair.  Both models are used in this BID.  The

first model is described in Appendix E and is applied to valves and

pumps.   It is the preferred model, because it incorporates recently

available data on leak occurrence and recurrence and data on the

effectiveness of simple in-line repair.  These data are not available

for relief valves and compressors.  Therefore, a second model is applied

to these sources.  The model can be expressed mathematically by the

following equation:

                    Reduction efficiency =AxBxCxD
Where:

     A =  Theoretical Maximum Control Efficiency = fraction of total
          mass emissions from sources with VOC concentrations greater
          than the leak definition (from Table 4-2).

     B =  Leak Occurrence and Recurrence Correction Factor = correction
          factor to account for sources which start to leak between
          inspections (occurrence), for sources which are found to be
          leaking, are repaired and start to leak again before the next
          inspection (recurrence), and for known leaks that could not be
          repaired.

     C =  Non-Instantaneous Repair Correction Factor = correction factor
          to account for emissions which occur between detection of a
          leak and subsequent repair, since repair is not instantaneous.

     D =  Imperfect Repair Correction Factor = correction factor to
          account for the fact that some sources which are repaired are
          not reduced to zero.  For computational purposes, all  sources
          which are repaired are assumed to be reduced to an emission
          level equivalent to a concentration of 1,000 ppmv.

As an example of this technique, Table 4-3 gives values for the "B,"

"C," and "D" correction factors for various possible inspection intervals,

allowable repair times, and leak definitions.   These values are given

only for relief valves and compressors seals,  because the reduction

efficiency for valves and pump seals is estimated according to the model

presented in Appendix E.

4.3  PREVENTIVE PROGRAMS

     An alternative approach to controlling fugitive VOC emissions from

gas plant operations is to replace components with leakless equipment.
                                 4-11

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               Table 4-3.  VOC EMISSION CORRECTION FACTORS FOR VARIOUS INSPECTION INTERVALS,
                                ALLOWABLE REPAIR TIMES, AND LEAK DEFINITIONS
 Component type
                        Leak occurence and
                      recurrence correction
                             factor
                         Non-i nstantaneous
                         repair correction
                              factor
                     Imperfect repair correction factor
                       Inspection interval
                         Allowable repair
                            time (days)
                           Leak definition (ppmv)
Quarterly     Monthly
15
100,000
50,000     10,000
1,000
Relief valves

Compressor seals

0.90 0.95 0.98 0.99 0.92
(0.99)
0.90 0.95 0.98 0.99 0.98
(0.97)
0.91
(0.99)
0.98
(0.96)
0.89
(0.99)
0.97
(0.95)
0.85
(0.99)
0.97
(0.94)
 xx  = VOC emission values.
(xx) = Total  hydrocarbon emission values.

aFactor accounts for sources that start to leak between inspections  (occurrence),  for sources that are found
 to be leaking,  are repaired, and start to leak again before the next inspection (recurrence), and for
 leaking sources that cannot be repaired.   Reference 11.

 Factor accounts for emissions that occur between detection of a leak and subsequent repair.   Reference 11.
 Factors accounts for the fact that some sources that are repaired are not reduced to zero.   Repaired
 sources are  assumed to be reduced to a 1,000 ppmv concentration level.   From Tables 3-1,  4-1, 4-2, and
 References 1 and 2.

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-This  approach is  referred  to  as  a  preventive  program.   This  section  will
 discuss  the kinds of equipment that  could  be  applied  in such a  program
 and the  advantages and  disadvantages of  this  equipment.
 4.3.1 Relief Valves
      A rupture disk can be used  upstream of a safety/relief  valve  so
 that  under  normal  conditions  it  seals the  system  tightly but will  break
 when  its  set pressure is exceeded, at which time  the  safety/relief valve
 will  relieve the  pressure.  Figure 4-1 is  a diagram of  a rupture disk
 and safety/relief valve installation.  The installation is arranged  to
 prevent  disk fragments  from lodging  in the valve  and  prevent the valve
 from  being  reseated if  the disk  ruptures.  It is  important that no
 pressure  be allowed to  build  in  the  pocket between the  disk  and the
 safety/relief valve;  otherwise,  the  disk will  not function properly.   A
 pressure  gauge and bleed valve can be used to prevent pressure buildup.
 With  the  use of a pressure gauge,  it can be determined  whether the disk
 is  properly sealing the system against leaks.  It is also necessary  to
 install  a block valve upstream of  the rupture disk so that the disk  can
 be  isolated and repaired on-line without shutting down  the unit.   Alter-
 nately,  to  prevent possible overpressure while using a  block valve,  a
 parallel  system of relief  valves and rupture  disks can  be installed  so
 that  one  rupture  disk/relief  valve is in operation while the other is
 being repaired.
      Use  of a rupture disk upstream  of a safety/relief  valve would
 eliminate leaks due to  improper  seating  of the relief valve.   Also,  the
 disk  can  extend the life of a safety/relief valve by protecting it
 against  system materials that could  be corrosive and thereby cause seal
 degradation.
 4.3.2 Compressor Seals
      Leaks  from compressor seals can be  controlled by enclosing the  seal
 area  or distance  piece  and installing piping  to vent the emissions to a
 suitable  combustion device.   Installation  of  check valves in the piping
 will  prevent back pressure in the  line,  will  serve to maintain a positive
 pressure  to prevent air intake to  the system,  and will  allow release of
 vapors to the combustion device  only when  the pressure  reaches a suffi-
 cient level.   Obtaining a  good seal  at the distance piece door and at
                                 4-13

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                               • —Tension-adjustment
                                      thimble
                                  	Spring
          To
       atmospheric
          vent
                                          BLIND FLANGE
                                                     CONNECTION FOR
                                                     PRESSURE GAUGE
                                                     & BLEED VALVE
                             FROM SYSTEM
Figure  4-1.   Rupture disk installation  upstream  of a relief valve.
                                    4-14

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the point where emissions are vented from the distance piece or seal
area is necessary for maintaining a sufficient pressure (e.g., 15 to
20 psig).  Block valves should also be installed in order to close vent
lines during compressor shutdown periods.  This will prevent hydrocarbon
vapors from entering the work place during compressor maintenance.  It
should not be necessary to install an auxiliary compressor to vent
                                   •I y
emissions to the combustion device.    There may be instances where
retrofitting of such a vent control system to a compressor distance
                                           13
piece may be infeasible for safety reasons.    Therefore, the application
of this preventive program as a retrofit will have to be evaluated on a
case-by-case basis.
4.3.3  Pump Seals
     Pumps can be potential fugitive VOC emission sources because of
leakage through the drive-shaft sealing mechanism.   This kind of leakage
can be reduced to a negligible level through the installation of improved
shaft sealing mechanisms, such as dual mechanical seals.
     Dual mechanical seals consist of two mechnical sealing elements
usually arranged in either a back-to-back or a tandem configuration.   In
both configurations a barrier fluid circulates between the seals.   The
barrier fluid system may be circulating system, or it may rely on convection
to circulate fluid within the system.   While the barrier fluid's main
function is to keep the pumped fluid away from the environment,  it can
serve other functions as well.  A barrier fluid can provide temperature
control in the stuffing box.   It can also protect the pump seals from
the atmosphere, as in the case of pumping easily oxidizable materials
that form abrasive oxides or polymers upon exposure to air.   A wide
variety of fluids can be used as barrier fluids.   Some of the more
common ones that have been used are water (or steam), glycols, methanol,
oil, and heat transfer fluid.   In cases in which product contamination
cannot be tolerated, it may also be possible to use clean product, a
product additive, or a product diluent.
     Emissions of VOC from barrier fluid degassing vents can be controlled
by a closed vent system, which consists of piping and, if necessary,
flow inducing devices to transport the degassing emissions to a control
device, such as a process heater, or vapor recovery system.   Control
                                 4-15

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-effectiveness  of a dual  mechanical  seal  and closed vent system is dependent
 on  the  effectiveness  of  the control  device used and the frequency of
 seal  failure.   Failure of both the  inner and outer seals can result in
 relatively large VOC  emissions at the seal area of the pump.   Pressure
 monitoring of  the barrier fluid may  be used in order to detect failure
             3
 of  the  seals.    In addition,  visual  inspection of the seal  area also can
 be  effective for detecting failure  of the outer seals.   Upon seal failure,
 the leaking pump would have to be shut down for repair.
 4.3.4  Open-Ended Lines
      Fugitive  emissions  from open-ended  lines are caused by leakage
 through the seat of a valve upstream of  the open end of the line.
 Fugitive emissions from  open-ended  lines can be controlled  by installing
 a cap,  plug, flange,  or  second valve to  the open end of the line.  In
 the case of a  second  valve, the upstream valve should always  be closed
 first after the use of the valves.   Each time the cap,  plug,  flange, or
 second  valve is opened,  any VOC that has leaked through the first valve
 seat will  be released.   These emissions  have not been quantified.  The
 control efficiency will  be dependent on  the frequency of removal  of the
 cap or  plug.  Caps, plugs, etc.  for  open-ended lines do not affect
 emissions  that may occur during use  of an upstream valve.   These  emissions
 may be  caused  by line purging for sampling, draining, or venting.
 4.3.5  Closed-Purge Sampling
      VOC emissions from  purging sampling lines can be controlled  by a
 closed-purge sampling system, which  is designed so that the purged VOC
 is  returned to the system or sent to a closed disposal  system so  that
 the handling losses are  minimized.   Figure 4-2 gives two examples of
 closed-purge sampling systems where  the  purged VOC is flushed from a
 point of higher pressure to one of  lower pressure in the system and
 where sample-line dead space is minimized.   Other sampling  systems are
 available  that utilize partially evacuated sampling containers and
                               14
 require no line pressure drop.
      Reduction of emissions for closed-purge sampling is dependent on
 many highly variable  factors, such as frequency of sampling and amount
 of  purge required.   For  emission calculations, it has been  assumed that
 closed-purge sampling systems will provide 100 percent control efficiency
 for the sample purge.

                                  4-16

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                                      Process Line
   Process Line
I
I—"
•^1
                          LJ
Sample
Container
                                 Sample
                                 Container
                          Figure 4-2.  Diagram of Two Closed-Loop Sampling Systems.

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4.3.6  Gas-OperateoSCpntrol Valves
                      "^ ~"
     VOC emissions from pneumatic control valves result when field gas
or flash gas is used as the operating medium.  These emissions can be
eliminated by the use of compressed air.  This will require installation
of an air compression system and connection of the appropriate pressure
supply lines.
                                 4-18

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4.4  REFERENCES

 1.  DuBose, D.A., J.I. Steinmetz, and G.E. Harris.   Emission  Factors
     and Leak Frequencies for Fittings in Gas Plants, Draft  Final  Report.
     Radian Corporation.  September, 1981.

 2.  Hennings, T. J., TRW to VOC/Onshore Production Docket.  April  2,
     1982.   Cumulative distribution of mass emissions and percent  sources
     with respect to screening value for relief valves.

 3.  Erikson, D.G.  and V. Kalcevic.  Emissions Control Options for  the
     Synthetic Organic Chemicals Manufacturing Industry, Fugitive  Emissions
     Report.  Hydroscience, Inc.  Knoxville, TN.  For U.S. Environmental
     Protection Agency.  Research Triangle Park, NC.  Draft  Report  for
     EPA Contract Number 68-02-2577.  February 1979.

 4.  Hustvedt, K.C. and R.C. Weber.  Detection of Volatile Organic
     Compound Emissions from Equipment Leaks.   Paper presented at 71st
     Annual Air Pollution Control Association Meeting.  Houston, TX.
     June 25-30, 1978.

 5.  Hustvedt, K.C. , R.A. Quaney, andW.E. Kelly.   Control of Volatile
     Organic Compound Leaks from Petroleum Refinery Equipment.   U.S.
     Environmental  Protection Agency.   Research Triangle Park,  NC.
     Report Number EPA-450/2-78-036.  June 1978.

 6.  Teller, James H.   Advantages Found in On-Line Leak Sealing.  Oil
     and Gas Journal, 77(29):54-59, 1979.

 7.  Letter from Naughton, D. A., Hartford Steam Boiler Inspection and
     Insurance Company, to M. Cappers, Allied Chemical.  May 28, 1981.
     Proposed EPA regulations requiring isolation valve upstream of
     relief valves and rupture discs.

 8.  Letter from Lambert, J. A., Jr.,  Industrial Risk Insurers, to
     M. A.  Cappers, Allied Chemical.  May 28,  1981.  Proposed EPA
     regulations requiring isolation valve upstream of relief valves and
     rupture discs.

 9.  Letter with attachments from H. H.  McClure, Texas Chemical Council,
     to W.  Barber,  EPA.  June 30, 1980.   Appendix B, page 11.

10.  "A Fugitive Emissions Study in Petrochemical  Manufacturing Unit"
     Kun^Chieh Lee, et. al., Union Carbide Corporation, South Charleston,
     West Virginia, presented to annual  meeting of the Air Pollution
     Control Association, Montreal, Quebec, June 22-27, 1980.  page 2.

11.  Tichenor, B.A., K.C. Hustvedt, and R.C. Weber.  Controlling Petroleum
     Refinery Fugitive Emissions Via Leak Detection and Repair.  Symposium
     on Atmospheric Emissions from Petroleum Refineries.  Austin, TX.
     Report Number EPA-600/9-80-013.  November 6,  1979.
                                 4-19

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12.   Letter and attachment from Hennings> T.J., TRW to K.C. Hustvedt,
     EPA.  June 30, 1981.  Results of a telephone survey concerning
     control of fugitive emissions from gas plant compressor seals.

13.   Letter and attachment from Hennings, T. J., TRW to K. C. Hustvedt,
     EPA.  February 22, 1982.  Results of a telephone survey on safety
     issues concerning compressor vent control  systems.

14.   Letter and attachments from McClure, H.H., Texas Chemical Council,
     to Patrick, D.R., EPA.  May 17, 1979.
                                 4-20

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                   5.  MODIFICATION AND RECONSTRUCTION

     In accordance with the provisions of Title 40 of the Code of Federal
Regulation (CFR), Sections 60.14 and 60.15, an existing facility can
become an affected facility and, consequently, subject to the standards
of performance if it is modified or reconstructed.  An "existing facility,"
defined in 40 CFR 60.2, is a facility of the type for which a standard
of performance is promulgated and the construction or modification of
which was commenced prior to the proposal date of the applicable standards.
The following discussion examines the applicability of modification/
reconstruction provisions to natural gas/gasoline processing plants that
involve fugitive VOC emissions.
5.1  GENERAL DISCUSSION OF MODIFICATION AND RECONSTRUCTION PROVISIONS
5.1.1  Modification
     Modification is defined in Section 60.14 as any physical or operational
change to an existing facility that results in an increase in the emission
rate of the pollutant(s) to which the standard applies.   Paragraph (e)
of Section 60.14 lists exceptions to this definition which are not
considered modifications, irrespective of any changes in the emission
rate.   These changes include:
     1.   Routine maintenance, repair, and replacement;
     2.   An increase in the production rate not requiring a capital
expenditure as defined in Section 60.2(bb);
     3.   An increase in the hours of operation;
     4.   Use of an alternative fuel or raw material if, prior to the
standard, the existing facility was designed to accommodate that alternative
fuel or raw material;
     5.   The addition or use of any system or device whose primary
function is the reduction of air pollutants, except when an emission
                                 5-1

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control system is removed or replaced by a system considered to be  less
environmentally beneficial.
     As stated in paragraph (b), emission factors, material balances,
continuous monitoring systems, and manual emission tests are to be  used
to determine emission rates expressed as kg/day of pollutant.  Paragraph
(c) affirms that the addition of an affected facility to a stationary
source through any mechanism — new construction, modification, or
reconstruction -- does not make any other facility within the stationary
source subject to standards of performance.   Paragraph (f) provides for
superseding any conflicting provisions.  And, (g) stipulates that
compliance be achieved within 180 days of the completion of any
modification.
5.1.2  Reconstruction
     Under the provisions of Section 60.15,  an existing facility becomes
an affected facility upon reconstruction, irrespective of any change in
emission rate.  A source is identified for consideration as a reconstructed
source when:  (1) the fixed capital costs of the new components exceed
50 percent of the fixed capital costs that would be required to construct
a comparable entirely new facility, and (2)  it is technologically and
economically feasible to meet the applicable standards set forth in this
part.  The final judgment on whether a replacement constitutes
reconstruction will be made by the Administrator's determination of
reconstruction will be based on:
     (1)  The fixed capital  cost that would  be required to construct
     a comparable new facility; (2) the estimated life of the
     facility after the replacements compared to the life of a
     comparable entirely new facility; (3) the extent to which the
     components being replaced cause or contribute to the emissions
     from the facility; and (4) any economic or technical limita-
     tions in compliance with applicable standards of performance
     which are inherent in the proposed replacements.
     The purpose of the reconstruction provision is to ensure that an
owner or operator does not perpetuate an existing facility by replacing
all but minor components, support structures, frames,  housing, etc.,
rather than totally replacing it in order to avoid being subject to
applicable performance standards.   In accordance with Section 60.5, EPA
                                 5-2

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will, upon request, determine if an action taken constitutes construction
(including reconstruction).
5.2  APPLICABILITY OF MODIFICATION AND RECONSTRUCTION PROVISIONS TO
     NATURAL GAS/GASOLINE PROCESSING PLANTS
     As a result of cost and energy considerations, as well as changes
in product demand and feedstock supply, there are expected to be a
number of modernization projects at existing gas plants in the near
future.   Some of these projects could result in existing gas plants
becoming subject to the provisions of Sections 60.14 and 60.15.
     For example, a company may decide to add process trains at an
existing facility in order to increase the plant capacity or efficiency.
The additional process equipment would include additional sources of
potential fugitive emissions, such as valves or compressors.   Routine
changes are also made to gas plants, such as those made to increase ease
of maintenance, to increase productivity, to improve plant safety, or
correct minor design flaws.  These types of changes may also result in
an increase of fugitive emissions.   However, measures could be taken to
reduce fugitive emissions from other sources to compensate for the
increase.  The capital expenditure for any of the above additions,
replacements, or changes may exceed the level of capital expenditure as
defined in Section 60.2(bb).   Some changes may involve only the replace-
ment of a potential fugitive emission source such as a valve.   If the
source is replaced with an equivalent source the level of fugitive
emissions would be expected to remain unchanged.
     It may be advantageous for certain plants to convert to an entirely
different processing method.   Most new gas plants use the cryogenic
processing method because it is less costly to operate and because it is
more efficient.  For the same reasons, owners of existing plants may
decide to convert to the cryogenic method.  Depending on the process
method that is presently being used, this may involve a substantial
amount of new equipment.   It is possible that the cost of the conversion
would exceed 50 percent of the cost of a new plant.
                                 5-3

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              6.  MODEL PLANTS AND REGULATORY ALTERNATIVES

6.1  INTRODUCTION
     This chapter presents model plants and regulatory alternatives for
reducing fugitive VOC emissions from natural gas/gasoline processing
plants.  The model plants were selected to represent the range of pro-
cessing complexity in the industry.  They provide a basis for determining
environmental and cost impacts of the regulatory alternatives.  The
regulatory alternatives consist of various combinations of the available
control techniques and provide incremental levels of emission control.
6.2  MODEL PLANTS
     There are a number of different process methods used at gas plants:
absorption, refrigerated absorption, refrigeration, compression, adsorp-
tion, cryogenic - Joule-Thompson, and cryogenic-expander.    Process
conditions are expected to vary widely between plants using these different
methods.  However, available data show that fugitive emissions are
proportional to the number of potential sources, and are not related to
                                                    2
capacity, throughput, age, temperature, or pressure.   Therefore, model
plants defined for this analysis represent different levels of process
complexity (number of fugitive emission sources), rather than different
process methods.
     In order to estimate emissions, control costs, and environmental
impacts on a plant specific basis, three model plants were developed.
With the exception of sampling connections, the number of components for
each model plant is derived from actual component inventories performed
at four gas plants.   Two of the plants were inventoried during EPA
testing,  and two were inventoried during testing by Rockwell International
                                                   4
under contract to the American Petroleum Institute.   The number of
sampling connections is based on the ratio of sampling connections to
open-ended lines as determined at refineries.

                                 6-1

-------
     Complexity of gas plants can be indexed by means of calculating
ratios of component populations to a more easily counted population.
For gas plants, number of vessels appears to be best suited to this
need.   Example types of equipment included and excluded in vessel inven-
tories are listed in Table 6-1.  The vessel inventories for the industry-
tested gas plants are taken from the site diagrams and descriptions
provided in the API/Rockwell report,  and the vessel inventories from
the EPA-tested plants were performed during the testing.  These vessel
inventories and the component inventories are shown in Table 6-2.
Table 6-3 shows the ratios of numbers of components to numbers of vessels
at the four gas plants.  The mean and standard deviation of the four
ratios are also shown in Table 6-3.
     Three model plants have been developed using the average ratios of
components to vessels.  The number of vessels in the model gas plants
are 10, 30, and 100.  This range in number of vessels is based on the
vessel inventories shown in Table 6-2.   The low end of the range, 10
vessels, is approximately equivalent to the number of vessels that are
accounted for in one of the three process trains at the EPA-tested
plant A.  It is assumed that there are existing gas plants with a similar
configuration to the EPA-tested plant A, that have only one process
train.  The high end of the range, 100 vessels, is slightly larger than
the number of vessels at the industry-tested plant C.   Since this was
the largest of the plants tested, it appears reasonable to use this as a
guide in calculating the number of components at the largest model
plant.  The middle-sized model plant has 30 vessels.  This is approximately
the same number of vessels as at three of the four plants tested and may
be representative of a common gas plant size.   The three model plants
and their respective number of components are shown in Table 6-4.
6.3  REGULATORY ALTERNATIVES
     This section presents four regulatory alternatives for controlling
fugitive VOC emissions from natural  gas/gasoline processing plants.   The
alternatives define feasible programs for achieving varying levels of
                                 6-2

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                   Table 6-1.  EXAMPLE TYPES OF EQUIPMENT INCLUDED AND EXCLUDED IN
                            VESSEL INVENTORIES FOR MODEL PLANT DEVELOPMENT
          Included
             Excluded
1.  Absorption/Desorption Units

    a.  Absorbers
    b.  Scrubbers
    c.  Dehydrators
    d.  Stabilizer
    e.  Stripper

2.  Adsorption Units

3.  Distillation/Fractionation Units

    a.  Demethanizer
    b.  Deethanizer
    c.  Depropanizer
    d.  Splitter
    e.  Flash Drum/Tank
    f.  Stills

4.  Heating/Cooling Units

    a.  Heaters
    b.  Chillers
    c.  Heat Exchangers
    d.  Reboilers
    e.  Condensers
    f.  Coolers

5.  Drums/Tanks

    a.  Separator
    b.  Surge
    c.  Gas
    d.  Oil
    e.  Accumulator
    f.  Knockout
1.  Compressors, Pumps

2.  Piping Systems

    a.  Manifold/header systems
    b.  Valves, flanges, connections, etc.
    c.  Meters, gauges, control equipment

3.  Glycol, lube oil, water storage

4.  Any equipment associated with sweetening

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                  Table 6-2.   NUMBER OF COMPONENTS IN HYDROCARBON SERVICE AND NUMBER OF
                                        VESSELS AT FOUR GAS PLANTS

EPA tested plants3

Vessels
Valves
Relief valves
Open-ended lines
Compressor seals
Pump seals
Flanges and connections
A
31
508C
16C
62C
0
1C
1,530C
B
30
541
11
64
8
12
1,440
Industry tested plants
C
90
3,330
20
669
35
32
15,370
D
25
762
7
173
0
3
3,030
 Reference 3.

"'Reference 4.

"Only two  of the  three  adsorption units  at the  plant were  tested  and inventoried.   Estimated total
 number of components  is  therefore based on the sum of the number of components  counted in the
 larger unit plus twice the  number of components counted in the  smaller unit.

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                             Table 6-3.   RATIOS OF NUMBERS OF COMPONENTS TO NUMBERS OF VESSELS0
I
01


Valves
Relief valves
Open-ended lines
Compressor seals
Pump seals
Flanges and
connections
EPA tested
A
16.4
0.5
2.0
0.0
0.0
49.4
plants
B
18.0
0.4
2.1
0.3
0.4
48.0
Industry
C
37.0
0.2
7.4
0.4
0.4
170.8
tested plants
D
30.5
0.3
6.9
0.0
0.1
121.2
Average
ratio
25.5
0.4
4.6
0.2
0.2
97.4
Standard
deviation
of ratio
9.9
0.1
3.0
0.2
0.2
59.7
          Based  on  data  presented in Table  6-2.

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          Table  6-4.   FUGITIVE  VOC  EMISSION  SOURCES  FOR THREE MODEL
                              GAS  PROCESSING  PLANTS

Number of components
Component type
Valves3
Relief valves3
Open-ended lines3
Compressor seals3
Pump seals3
Sampling connections
Flanges and connections3
Model plant
A
(10 vessels)
250
4
50
2
2
7
1,000
Model plant Model plant
B C
(30 vessels) (100 vessels)
750 2
12
150
6
6
21
3,000 10
,500
40
500
20
20
70
,000
 Number of components  based  on  average  ratios presented  in Table 6-3.

'Number of components  based  on  ratio  of sampling connections to open-ended
 lines  at  refineries  (Reference 5).
                                        6-6

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emission reduction.  The first alternative represents a baseline level
of fugitive emissions in which case the impact analysis is based on no
additional controls.  The remaining regulatory alternatives require
increasingly restrictive controls comprised of the techniques discussed
in Chapter 4.   Table 6-5 summarizes the requirements of the regulatory
alternatives.
6.3.1  Regulatory Alternative I
     Regulatory Alternative I reflects normal existing gas plant operations
with no additional regulatory requirements.  This baseline regulatory
alternative provides the basis for incremental comparison of the impacts
of the other regulatory alternatives.
6.3.2  Regulatory Alternative II
     Regulatory Alternative II provides a higher level of emission
control than the baseline alternative through leak detection and repair
methods as well as equipment specifications.
     The regulatory alternative requires quarterly instrument monitoring
of valves, relief valves, compressor seals, and pump seals for leaks.
Leaks that are found to be in excess of a prescribed hydrocarbon concen-
tration (as indicated by a hydrocarbon detection instrument) would be
repaired within a prescribed time period.   Pump seals would additionally
receive weekly visual inspections for leaks.   Leaks found to be tn
excess of the prescribed concentration would be repaired within the
prescribed time period.
     The regulatory alternative also requires that caps (including
plugs, flanges, or second valves) be installed on open-ended lines.
6.3.3  Regulatory Alternative III
     Regulatory Alternative III achieves a greater emission reduction
than Alternative II by requiring monthly instrument monitoring of valves,
relief valves, and pump seals.  If a particular valve is found not to be
leaking for 3 successive months, then 2 months may be skipped before the
next time it is monitored with an instrument.  A compressor vent control
system would be installed to control compressor seal emissions.  Sampling
connections would be equipped with a closed purge sampling system.
Other requirements (caps on open-ended lines, weekly inspection of
pumps) remain the same as Alternative II.
                                 6-7

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              Table  6-5.   REGULATORY ALTERNATIVES FOR FUGITIVE VOC EMISSION  SOURCES  AT GAS PROCESSING  PLANTS
cr>
co

Component type
Valves
Relief valves
Open-ended lines
Sampling connections
Compressor seals
Pump seals

I II
Monitoring Equipment
interval specification
baseline quarterly
control
(no NSPS)
quarterly
cap
none
quarterly
quarterly,
weekly visual
Regulatory

Monitoring
interval
monthly/
quarterly
monthly



monthly,
weekly visual
Alternative
III
Equipment
specification


cap
closed purge
sampling
compressor vent
control


IV
Monitoring Equipment
interval specification
monthly
rupture disc
cap
closed purge
sampling
compressor vent
control
dual seals
       Instrument monitoring of pumps would be supplemented with weekly visual inspections for  liquid leakage.   If liquid is noted to be leaking
       from the pump seal, the seal would be repaired.

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6.3.4  Regulatory Alternative IV
     Regulatory Alternative IV increases emission control by requiring
monthly instrument monitoring of valves.  Relief valves should be equipped
with a rupture disc, and pumps are required to have dual mechanical
seals.   Other requirements are the same as Alternative III.
                                 6-9

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6.4  REFERENCES


 1.  Cantrell, A.  Worldwide Gas Processing.  Oil and Gas Journal, July
     14, 1980. p. 88.

 2.  Assessment of Atmospheric Emissions from Petroleum Refining, Volume
     3, Appendix B.  EPA 600/2-80-075c, April 1980.  Pages 266 and 280.

 3.  Hustvedt, K.C., memo to James F. Durham, Chief, Petroleum Section,
     OAQPS, U.S. EPA.  Preliminary Test Data Summaries of EPA testing at
     Houston Oil and Minerals Smith Point gas plant and Amoco Production
     Hastings gas plant.  March 19, 1981.

 4.  Eaton, W.S., Rockwell International, letter to D.  Markwordt, OAQPS,
     U.S. EPA.  Component Inventory Data from Two API-Tested Gas Plants.
     September 11, 1980.

 5.  VOC Fugitive Emissions in Petroleum Refining Industry - Background
     Information for Proposed Standards.  U.S.  EPA, OAQPS.  April 1981.

 6.  Eaton, W.S., et al.  Fugitive Hydrocarbon Emissions from Petroleum
     Production Operations.   API Publication No.  4322.   March 1980.
                                 6-10

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                        7.  ENVIRONMENTAL IMPACTS

7.1  INTRODUCTION
     This chapter discusses the environmental impacts from implementing
the regulatory alternatives presented in Chapter 6.  The primary emphasis
is a quantitative assessment of the fugitive emissions that would result
from each of the alternatives.  The impacts on water quality, solid
waste, energy and other environmental concerns are also addressed.
7.2  EMISSIONS IMPACT
7.2.1  Emission Source Characterization
     As discussed in Chapter 6, the model plants consist of several
types of components (e.g., valves, pumps) that comprise the major fugitive
emission sources within natural gas/gasoline processing plants.   The
emission factors presented in Table 3-1 are characteristic of existing
gas plant components.   These emissions are referred to as "baseline" and
represent emissions under Regulatory Alternative I.  The control techno-
logy discussed in Chapter 4 is applied in progressive increments in
Alternatives II, III,  and IV in reducing emissions below baseline levels.
7.2.2  Development of Emission Levels
     In order to estimate the impacts of the regulatory alternatives on
fugitive VOC emission levels, emission factors for the model  plants were
determined for each regulatory alternative.   Controlled emission factors
were developed for those component types that would be controlled by the
implementation of a leak detection and repair program.   For relief
valves and compressor seals, these factors were calculated by multiplying
the baseline emission factor for each component type by a control efficiency
factor.   Derivation of these factors is explained in Chapter 4 and
Appendix E.

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                          Table  7-1.   CONTROLLED EMISSION  FACTORS  FOR  VARIOUS  INSPECTION  INTERVALS
--J
 I
ro

Source
type
Valves
Relief
valves
Compressor
seals
Pump
seals
Inspection
interval
quarterly
monthly/quarterly
monthly
quarterly
monthly
quarterly
quarterly
monthly
Baseline
emission factor
(kg/day)
0.
0.
0.
0.
0.
1.
1.
1.
18
18
18
33
33
0
2
2
(0.
(0.
(0.
(4.
(4.
(4.
(1.
(1.
48)
48)
48)
5)
5)
9)
5)
5)
Correction factors
Ab Bc Cd D* e
0.
0.
0.
0.78 0.90 0.98 0.89 (0.99) 0.
0.78 0.95 0.98 0.89 (0.99) 0.
0.92 0.90 0.98 0.97 (0.95) 0.
0.
o.
Control ,
ifficiency
77
78
84
61
65
79
58
65
(0.
(0.
(0.
(0.
(0.
(0.
(0.
(0.
77)
78)
84)
68)
72)
77)
58)
65)
Controlled
emission factor^
(kg/day)
0.041
0.041
0.029
0.13
0.12
0.21
0.50
0.42
(0.11)
(0.11)
(0.079)
(1.4)
(1.3)
(1.1)
(0.63)
(0.53)
  xx = VOC emission  values.
(xx) = Total  hydrocarbon emission values.
aFrom Table 3-1.
 Theoretical  maximum control efficiency at a leak  definition of 10,000 ppmv.   From Table  4-2.
 Lead occurrence  and recurrence correction factor.  Assumed to be 0.90 for quarterly inspection and 0.95 for monthly inspection.
 Non-instantaneous repair correction factor.   For  a 15-day maximum allowable repair time,  assuming a 7.5 day average repair time  yields
 a 0.98 yearly correction factor:  [365 -  (15/2)]/365 = 0.98.
elmperfect repair correction factor.   Calculated as 1 - (f/F), where f = average emission rate for sources at 1000 ppm and F = average
 emission rate for sources greater than 10,000 ppm.  From Table 4-3.
 Control efficiencies for valves and pump  seals are developed on the basis of the model described in Appendix E.  Control efficiencies
 for relief valves and compressor seals are equal  to AxBxCxD.
Controlled emission factor = baseline emission factor x [1 - control efficiency].   Values  for valves and pump seals are provided
 in Appendix  E, Tables E-5 and E-6.

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     The  impacts of the regulatory alternatives on valves and pump  seals
were determined through use of a mathematical model described in Appendix  E.
This model was used in place of the approach "described in Chapter 4
because of the options that are included to evaluate alternative leak
detection and repair programs and because of recently available maintenance
data.  In the case of valves, a "monthly/quarterly" (rather than a
"monthly" or "quarterly")  leak detection and repair program (outlined in
Chapter 6) is included in  Regulatory Alternative III.  Because this
program cannot be satisfactorily evaluated by means of the Chapter  4
approach, the model described in Appendix E was used to evaluate each of
the regulatory alternatives with respect to valves.  Also, the model has
incorporated actual data on leak occurrence, recurrence, and repair
collected at refineries.   It is recognized that the" data collected  at
refineries may not be entirely representative of similar information
that could be collected at gas plants.  However, use of the data in
estimating potential emission reductions is considered more appropriate
than disregarding it in favor of the approach taken in Chapter 4 which
relies heavily on engineering judgement.
     Where the regulatory alternatives require an equipment specification,
it is assumed that there are no subsequent emissions from the controlled
source.  Table 7-2 presents the total fugitive VOC emissions from Model
Plants A, B, and C under each regulatory alternative by component type
and the component percent of the total emissions.   Table 7-3 compares
the relative control effectiveness of Regulatory Alternatives II through
IV over Alternative I (baseline emissions) and also each regulatory
alternative over the previous alternative.
7.2.3  Future Impact on Fugitive VOC Emissions
     Future impacts of the regulatory alternatives were estimated for
the 5-year period, 1983 to 1987 as shown in Table 7-4.   The number of
affected model plants (detailed in Section 9.1.2.2) projected for each
year was multiplied by the estimated total fugitive emissions per model
plant for each of the alternatives (from Table 7-3).
     Over the 5-year period, the total fugitive VOC emissions for new
plants under baseline control  (Regulatory Alternative I) are projected
at 52 gigagrams.   These baseline emissions may reach an additional
                                 7-3

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Table 7-2.  EMISSIONS FOR REGULATORY ALTERNATIVES (MODEL PLANT A)
Component
type
Valves
Relief valves
Open-ended
lines
Compressor
seals
Pump seals
Sampling
connections
Flanges and
connections
Total

I
Baseline
emissions,
kg/day
45
1.
17
2.
2.
2.
11
81
(120)
3 (18)
(27)
0 (9.8)
4 (3.0)
5 (2.5)
(26)
(206)

Percent
total
emissions
56 (58)
2 (9)
21 (13)
2 (5)
3 (1)
3 (1)
14 (13)


II
Controlled
emissions,
kg/day
10
0.52
0.0
0.42
1.0
2.5
11
25
(28)
(5.6)
(0.0)
(2.2)
(1.3)
(2.5)
(26)
(66)
Regulatory Alternative
III
Percent
total
emissions
39 (43)
2 (9)
0 (0)
2 (3)
4 (2)
10 (4)
43 (40)

Controlled
emissions,
kg/day
10
0.48
0.0
0.0
0.84
0.0
11
22
(28)
(5.2)
(0.0)
(0.0)
(1.1)
(0.0)
(26)
(60)
Percent
total
emissions
45 (46)
2 (9)"
0 (0)
0 (0)
4 (2)
0 (0)
49 (43)

IV
Controlled
emissions,
kg/day
7.3 (20)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
11 (26)
18 (46)
Percent
total
emissions
40 (43)
0 (0)
0 (0)
0 (0)
0 (0)
0 (0)
60 (57)


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Table 7-2.  CONTINUED (MODEL PLANT B)
Regulatory Alternative
Component
type
Valves
Relief valves
Open-ended
lines
Compressor
seals
Pump seals
Sampling
connections
Flanges and
connections
Total
I
Baseline
emissions,
kg/day
140 (360)
4.0 (54)
51 (80)
6.0 (29)
7.2 (9.0)
7.6 (7.6)
33 (78)
249 (618)
II
Percent
total
emissions
56 (58)
2 (9)
20 (13)
2 (5)
3 (1)
3 (1)
13 (13)

Controlled
emissions,
kg/day
31 (83)
1.6 (17)
0.0 (0.0)
1.3 (6.6)
3.0 (3.8)
7.6 (7.6)
33 (78)
78 (200)
Percent
total
emissions
40 (42)
2 (9)
0 (0)
2 (3)
4 (2)
10 (4)
43 (40)

III
Controlled
emissions,
kg/day
31 (83)
1.4 (16)
0.0 (0.0)
0.0 (0.0)
2.5 (3.2)
0.0 (0.0)
33 (78)
68 (180)
Percent
total
emissions
46 (46)
2 (9)
0 (0)
0 (0)
4 (2)
0 (0)
49 (43)

IV
Controlled
emissions,
kg/day
22 (59)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
0.0 (0.0)
33 (78)
55 (140)
Percent
total
emissions
40 (43)
0 (0)
0 (0)
0 (0)
0 (0)
0 (0)
60 (57)


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                                                  Table  7-2.   CONCLUDED  (MODEL PLANT C)
I
Ol
Component
type
Valves
Relief valves
Open-ended
lines
Compressor
seals
Pump seals
Sampl i ng
connections
Flanges a,,d
connections
Total

I
Baseline
emissions,
kg/day
450
13
170
20
24
25
110
812
(1,200)
(180)
(265)
(98)
(30)
(25)
(260)
(2,058)

Percent
total
emissions
55 (58)
2 (9)
21 (13)
2 (5)
3 (1)
3 (1)
14 (13)


II
Controlled
emissions,
kg/day
100
5.2
0.0
4.2
10
25
110
250
(280)
(56)
(0.0)
(22)
(13)
(25)
(260)
(660)
Regulatory Alternative
III
Percent
total
emissions
39 (43)
2 (9)
0 (0)
2 (3)
4 (2)
10 (4)
43 (40)

Controlled
emissions,
kg/day
100
4.8
0.0
0.0
8.4
0.0
110
220
(280)
(52)
(0.0)
(0.0)
(ID
(0.0)
(260)
(600)
Percent
total
emissions
45 (46)
2 (9)
0 (0)
0 (0)
4 (2)
0 (0)
49 (43)

IV
Controlled
emissions,
kg/day
73
0.0
0.0
0.0
0.0
0.0
110
180
(200)
(0.0)
(0.0)
(0.0)
(0.0)
(0.0)
(260)
(460)

Percent
total
emissions
40 (43)
0 (0)
0 (0)
0 (0)
0 (0)
0 (0)
60 (57)

       xx  = VOC  emission values.

      (xx) = Total hydrocarbon emission values.

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          Table 7-3.  ANNUAL MODEL PLANT EMISSIONS AND PERCENT EMISSION REDUCTION FROM
                REGULATORY ALTERNATIVE I AND FROM PREVIOUS REGULATORY ALTERNATIVE

Model plant emissions,3 Mg/yr
Regulatory
alternative A
I 30 (75)
II 9.1 (24)
III 8.0 (22)
IV 6.6 (17)

91
28
25
20
B
(230)
(73)
(66)
(51)
C
300 (750)
91 (240)
80 (220)
66 (170)
Percent emission reduction
Total b

70
73
78
•-
(68)
(71)
(77)
Incremental
—
70 (68)
3 (3)
5 (6)
 xx  = VOC emission values.
(xx) = Total hydrocarbon emission values.
 From Table 7-2.  Assume 365 days per year operation.
 Emissions reduction from Regulatory Alternative I.
cEmissions reduction from previous Regulatory Alternative.

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           Table 7-4.   PROJECTED FUGITIVE EMISSIONS  FROM  AFFECTED MODEL  PLANTS FOR
                                REGULATORY ALTERNATIVES  FOR  1983-1987
                          Cumulative number of
                          affected model  plants
Total  fugitive emissions projected  under
     regulatory alternative  (103 Mg/yr)
                    Year
           II
III
IV
1983
1984
New 1985
plants 1986
1987
5-year
5-year
0
0
0
0
0
total
emission
40
80
120
150
180


0
0
0
0
0


3.6
7.3
11
14
16
52
-
(9.2)
(18)
(28)
(35)
(41)
(130)
( - )
1.1
2.2
3.4
4.2
5.0
16
36
(2.9)
(5.8)
(8.8)
(11)
(13)
(42)
(88)
1.0
2.0
3.0
3.8
4.5
14
38
(2.6)
(5.3)
(7.9)
(9.9)
(12)
(38)
(92)
0.80
1.6
2.4
3.0
3.6
11
41
(2.0)
(4.1)
(6.1)
(7.7)
(9.2)
(29)
(100)
                      reduction from baseline

Modified/
reconstructed
plants



1983
1984
1985
1986
1987
5-year
5-year
2
4
6
8
10
total
emission
3
6
9
12
15


3
6
9
12
15


1.2
2.5
3.7
4.9
6.2
19
-
(3.1)
(6.2)
(9.3)
(12)
(15)
(46)
( - )
0.38
0.75
1.1
1.5
1.9
5.6
13
(0.99)
(2.0)
(3.0)
(3.9)
(4.9)
(15)
(31)
0.33 (0.90)
0.67 (1.8)
1.0 (2.7)
1.3 (3.6)
1.7 (4.5)
5.0 (14)
14 (32)
0.27
0.54
0.81
1.1
1.4
4.1
15
(0.70)
(1.4)
(2.1)
(2.8)
(3.5)
(11)
(35)
                      reduction from baseline
 xx  = VOC emission values.
(xx) = Total hydrocarbon emission values.

aThe number of affected model plants projected through 1987 distinguish between new plant  construction and
 modification/reconstruction.  Plants in existence prior to 1983 are  otherwise excluded.   A discussion of
 the growth projections is  in Section 9.1.2.2.

 The total fugitive emissions from Model Plants A, B, and C are derived from the emissions per model plant
 in Table 7-3.  The sum of  emissions in any one year is the sum of the products of the number of affected
 facilities per model  plant times the emissions per model plant.
                                                 7-f

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19 gigagrams from existing plants through modification/reconstruct!'on.
Implementation of Regulatory Alternatives II through IV would reduce the
total new plant emissions to 16, 14, and 11 gigagrams, respectively.
Modification/reconstruction may add up to 5.6, 5.0, and 4.1 gigagrams,
respectively, to the new plant projections.
7.3  WATER QUALITY IMPACT
     Although fugitive emissions from gas plant equipment primarily
impact air quality, they also adversely impact water quality.   In
particular, leaking components handling liquid hydrocarbon streams
increase the waste load entering wastewater treatment systems.   Leaks
from equipment contribute to the waste load by entering drains  via
run-off.  Implementation of Regulatory Alternatives II through  IV would
reduce the waste load on wastewater treatment systems by preventing
leakage from process equipment from entering the wastewater system.
7.4  SOLID WASTE IMPACT
     Solid wastes that are generated by the natural gas/gasoline processing
industry and that are associated with the regulatory alternatives include
replaced mechanical seals, seal packing,  rupture disks, and valves.
Implementation of Regulatory Alternatives II through IV would  increase
solid waste whenever equipment specifications require the replacement of
existing equipment.
     Implementation of Alternatives II through IV,  however, would have
an insignificant impact beyond existing levels (Regulatory Alternative I).
This is because most gas plant solid waste is unrelated to the  regulatory
alternatives.  These sources of solid waste include separator and tank
sludges, filter cakes, and slop oil.  Also,  metal  solid wastes
(e.g., mechanical seals, rupture disks, caps, plugs, and valve  parts)
could be recycled and thus minimize any impact on solid waste.
7.5  ENERGY IMPACTS
     Implementation of Regulatory Alternatives II through IV results in
a net positive energy impact.   The energy savings from the "recovered"
emissions far outweigh the energy requirements of the alternatives.   The
regulatory alternatives would require a minimal increase in energy
consumption due to:  operation of monitoring instruments; installation
                                 7-9

-------
of dual mechanical seals, which require a minimal increase in energy
over single mechanical seals because of seal/shaft friction and operation
of fluid flush system; operation of the compressor vent control system;
closed loop sampling; and operation of combustion devices.
     The energy savings over a 5-year period from new plants alone is
estimated at 4,600 terajoules (Regulatory Alternative II) up to
4,900 terajoules (Regulatory Alternative IV) as shown in Table 7-5.
Modified/reconstructed units may represent an additional 1,600 and
1,800 terajoules, respectively.   Table 7-5 also shows the energy savings
in crude oil equivalents.
7.6  OTHER ENVIRONMENTAL CONCERNS
7.6.1  Irreversible and Irretrievable Commitment of Resources
     Implementation of any of the regulatory alternatives is not expected
to result in any irreversible or irretrievable commitment of resources.
Rather, implementation of Alternatives II through IV would save resources
due to the energy savings associated with the reductions in emissions.
As previously noted, the generation of solid waste used in the control
equipment will not be significant.
7.6.2  Environmental Impact of Delayed Regulatory Action
     As discussed in the above sections, implementation of the regulatory
alternatives will not significantly impact water quality or solid waste.
However, a delay in regulatory action would adversely impact air quality
at the rate shown in Table 7-4.
                                 7-10

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                             Table 7-5.   ENERGY IMPACTS OF EMISSION REDUCTIONS FOR
                                     REGULATORY ALTERNATIVES FOR 1983-1987


New
plants
Modified/
reconstructed
plants
Regulatory
alternative
II
III
IV
II
III
IV
Five-year total Energy value of
recovered emissions recovered emissions
from baseline (103 Mg) (terajoules) '
36 (88)
37 (85)
40 (94)
13 (31)
13 (31)
14 (34)
4,600
4,400
4,900
1,600
1,600
1,800
Crude oil equivalent
of recovered emissions
(103 bbl)d
750
720
800
260
260
290
 xx  = VOC emission values.
(xx) = Total hydrocarbon emission values.

Estimated total fugitive emission reduction from Model  Plants A,  B,  and C,  from Table 7-4.   Numbers are
 corrected to account for emissions not recovered due to venting of compressors  to flares  or incinerators
 in Regulatory Alternatives III and IV.

 Calculated on the basis of 47 terajoules  per gigagram of VOC.   Heating value is assumed to  be equal to
 that of natural gas plant liquid production for 1978-1980 of 3,925,000 Btu/bbl  (4.14 gigajoules/bbl),
 Reference 3.   Specific gravity assumed to be 0.55, Reference 1.

Calculated on the basis of 55 terajoules  per gigagram of methane-ethane.   Composition is  assumed to be
 80 percent methane and 20 percent ethane.  The heats of combustion are assumed  to be 23,000 Btu/lb and
 22,300 Btu/lb for methane and ethane, respectively,  Reference 2.

 Calculated on the basis of 163 bbl crude  per terajoule.   Heating  value is assumed to be equal to that  of
 crude petroleum production for 1978-1980  of 5,800,000 Btu/bbl,  Reference  3.

-------
7.7  REFERENCES

1.   Nelson, W. L.  Petroleum Refinery  Engineering.   McGraw-Hill  Book
     Company, Inc.  New York, 1958.  p. 32.

2.   Perry, R. H., and C. H. Chilton, eds.  Chemical  Engineers'  Handbook,
     Fifth Edition.  McGraw-Hill Book Company, New York.   1973.   p.  9-16.

3.   DOE Monthly  Energy Review.  January 1981.  DOE/EIA-0035  (81/01).
                                 7-12

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                            8.  COST ANALYSIS

8.1  COST ANALYSIS OF REGULATORY ALTERNATIVES
8.1.1  Introduction
     The following sections present estimates of the capital costs,
annual costs, and cost effectiveness for each model plant and regulatory
alternative discussed in Chapter 6.  These estimates will then be used
in Chapter 9 to estimate the economic impact of the regulatory alterna-
tives upon the natural gas/gasoline processing industry.   To ensure a
common cost basis, Chemical Engineering cost indices were used to adjust
control equipment to June 1980 dollars.
8.1.2  New Facilities
     8.1.2.1  Capital Costs.  The bases for the capital costs for monitoring
instruments and control equipment are presented in Table 8-1.  These
data are used to tabulate the capital costs for each model plant under
the regulatory alternatives as given in Table 8-2.
     Regulatory Alternative I requires no additional controls and therefore
incurs no capital costs.  Under Regulatory Alternatives II through IV,
caps for open-ended lines and two monitoring instruments would be purchased.
Although only one instrument is required, it is assumed that plant
operators will purchase a spare in the event that the first becomes
inoperable.  There are no other capital  costs associated with
Alternative II.
     Regulatory Alternative III also includes the cost of a compressor
vent control system and closed-loop sampling connections.  Alternative IV
includes all the costs of Alternative III plus the costs of a rupture
disk system and dual mechanical seals.  The costs of Regulatory Alterna-
tive IV are different for new installation of equipment and for retrofit
installations.

-------
               Table 8-1.   CAPITAL COST DATA (June 1980 dollars)
1.    Monitoring Instruments

     2 instruments (Century Systems OVA-108)
     @ $4,600/instrument
     Total cost is $9,200/plant

2.    Caps for Open-Ended Lines

     Based on cost for 5.1 cm screw-on gate valve, rated at 17.6 kg/cm2    ,
     (250 psi) water, oil, gas (w.o.gfc) pressure.  June 1981 cost is $46.50 ,
     June 1980 cost is 8 percent less  at $43.  Retrofit installation =
     1 hour at $18/hour .   Total cost is $61/1ine.
3.   Compressor Vent Control System

     Model

     Parts6
Model plant A
     e
     10 m 2.5 cm pipe =                 $ 28.20
     120 m 5.1 cm pipe =                 780.00
     four 2.5 cm check valves
       @ $80.40 =                        321.60
     2 elbows @ $6.22 =                   12.44
     3 T's @ $8.16 =                      24.48
     2 gate type block valves
       (21 kg/cm2-w.o.g.) @ $61.77       123.54
          Total Parts                 $1,290.00   x   ^30.6      _  $1>192.oo
     Laborf
     on m/hm/wQ7r   =   4.3 hr for installation by crew
     30 m/hr/crew       2-Q hr for set.up/breakdown
                        2.0 hr for fabrication

                        8.3 hours/crew
     8.3 crew hrs X 2-J§!i = 25 man hrs X $18.00/hrd = Total Labor     $450.00
                    crew                                              	
                                                      Total Dollars $1,642.00
     Model plant B

     Parts6
30 m 2.5 cm pipe =
160 m 5.1 cm pipe =
twelve 2.5 cm check valves
@ $80.40 =
2 elbow @ $6.22 =
11 T's @ $8.16 =
6 gate type block valves
(21 kg/cm2-w.o.g.) @ $61.
Total Parts
$ 84.60
1,040.00
964.80
12.44
89.76
77 370.62 c
$2,562.00 x HS'T = $2,367.00
O^ / . O
(continued)
                                      8-2

-------
                            Table 8-1.  Continued
     Laborf
     30 m/hr/crew   =  6'3 hr for installat1on bV crew
     JU m/hr/crew      3>Q hr for set-up/breakdown
                       6.0 hr fabrication
                      15.3 hours/crew
     15.3 crew hrs X  -    = 45 man hrs X $18.00/hrd = Total Labor    $ 830.00
                                                                           ^
                                                      Total Dollars  $3.197.00

     Model plant C

     Parts6

     50 m 2.5 cm pipe =                $  141.00
     200 m 5.1 cm pipe =                1,300.00
     forty 2.5 cm check valves
       @ $80.42 =                       3,216.80
     6 elbows @ $6.22 =                    74.64
     19 T's @ $8.16 =                     318.24
     20 gate type block valves
       (21 kg/cm2-w.o.g.) @ $61.77      1.235.40          c

          Total Parts                  $6,286.00  x  33P/Q       =   $5.808.00

     Laborf
      nmyhryr      =  8-3 hr for installation
     30 m/hr/crew                 set-Up/breakdown
                      18.0 hr for fabrication

                      32.3 hours/crew

     32.3 crew hrs X |~-^ = 97 man hrs X $18.00/hrd = Total Labor   $1.750.00
                                                                     i^^^^^^^™—™.— «.^^—

                                                      Total Dollars  $7.558.00
4.    Closed-loop Sampling Connections^

     Based on 6 m length of 2.5 cm schedule 40 carbon steel pipe, and three
     2.5 cm ball valves.  Retrofit or new installation = 18 hours at $18/hour.
     Total cost is $530/sampling connection.

5.    Rupture Disk System with Block Valve^

     New Installation

     Rupture Disk Assembly

          7.6 cm rupture disk (stainless) =       $  230
          7.6 cm rupture disk holder
            (carbon steel)                =          384
          0.6 cm pressure gauge           =           18
          0.6 cm bleed gate valve         =           30
          Installation, 16 hrs @ $18/hr   =          288

                                  (continued)~'

                                      8-3

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                       Table 8-1.  Continued
Upstream Block Valve
     7.6 cm gate valve               =          700
     Installation, 10 hrs @ $18/hr   =          180
Offset Mounting
     10.2 cm tee, elbow              =
     Installation, 8 hrs @ $18/hr    =
Retrofit Installation
Relief Valve Replacement
     7.6 cm relief valve (stainless)
     Installation, 10 hrs @ $18/hr
                                             $3,631

Rupture Disk System with 3-Way Valve
New Installation
Costs for rupture disk assembly are the same as for new rupture disk
disk system (above), except replace block valve with
     One 3-way valve (7.6 cm, 2-port) =      $1,320
Additional cost for
     One 7.6 cm pressure relief valve
       stainless                      =      $1,456
     Two 7.6 cm elbows                =          30
     Installation, 36 hrs @ $18/hr    =         648
                                             $4,100
Retrofit Installation
Costs for rupture disk assembly and 3-way valve costs are the same as
for new applications except
     Installation, 72 hrs @ $18/hr    =      $1,296
                                             $4,800

                             (continued)
                                 8-4

-------
                             Table 8-1.  Concluded
7.    Dual Mechanical
     New Installation
          Seal cost                       =       $1,250
          Seal credit                     =         -278
          Installation, 16 hrs @ $18/hr   =          288
                                                  $1,260
     Retrofit Installation
          Seal cost                       =       $1,250
          Installation, 19 hrs @ $18/hr   =          342
                                                  $1,592
 One instrument used as a spare.   Cost is based on Reference 1.
 Reference 2.
 Cost adjustment based on the economic indicators for pipe, valves, and
 fittings in April 1980 (final) vs.  April 1981 (preliminary).   Reference 3.
 Reference 4.
Reference 5.
 Reference 6.
^Reference 7.
hReference 8.
                                      8-5

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Table 8-2.   CAPITAL COST ESTIMATES FOR MODEL PLANTS
         (thousands of June 1980 dollars)

Regulatory
Capital cost item IIa III3
Model Plant A
1. Monitoring instrument 9.2 9.2
2. Caps for open-ended 3.1 3.1
lines
3. Compressor vent control 1.6
system
4. Closed-loop sampling 3.7
connections
5. Rupture disk system
6. Dual mechanical seals
Total 12 18
Alternative
IVb IVC
9.2 9.2
3.1 3.1
1.6 1.6
3.7 3.7
12 17
2.5 3.2
32 38
(continued)
                        8-6

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Table 8-2.   Continued

Regulatory
Capital cost item IIa III8
Model Plant B
1. Monitoring instrument 9.2 9.2
2. Caps for open-ended 9.2 9.2
lines
3. Compressor vent control 3.2
system
4. Closed- loop sampling 11
connections
5. Rupture disk system
6. Dual mechanical seals
Total 18 33
Alternative
IVb
9.2
9.2
3.2
11
37
7.6
77
IVC
9.2
9.2
3.2
11
51
9.6
93
(continued)
         8-7

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                        Table 8-2.  Concluded

Regulatory Alternative
Capital cost item
IIs IIIa IVb
IVC
Model Plant C
1.
2.
3.
4.
5.
6.
Monitoring instrument
Caps for open-ended
lines
Compressor vent control
system
Closed- loop sampling
connections
Rupture disk system
Dual mechanical seals
9.2 9.2 9.2
31 31 31
7.6 7.6
37 37
120
25
9.2
31
7.6
37
170
32
Total                             40       85      230     290
aCosts are the same for new or retrofit installation.
 New installation costs.
cRetrofit installation costs.
 Costs based on 50% rupture disk systems with block valve and
 50% rupture disk systems with 3-way valve.
                                 8-8

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     8.1.2.2  Annual Costs.  Implementation of Regulatory Alternatives II
through IV would require visual and/or instrument monitoring of potential
VOC emissions.  The inspection requirements are given in Chapter 6.
Table 8-3 summarizes the leak detection and repair labor-hour requirements,
and Table 8-4 shows the annual costs for the alternatives by model
plant.   These repair costs cover the expense of repairing those components
in which leaks develop after initial repair.  The cost for leak detection
and repair labor was assumed to be $18.00 per hour.
     Administrative and support costs were estimated at 40 percent of
the sum of leak detection and repair labor costs.   Leak detection labor,
leak repair labor, and administrative/support costs  are recurring annual
costs for each regulatory alternative.
     8.1.2.3  Annual i zed Costs.  The bases for the annual ized control
costs are presented in Table 8-5.   The annualized capital, maintenance,
and miscellaneous costs were calculated by taking the appropriate factor
from Table 8-5 and applying it to the corresponding  capital  cost from
Table 8-2.  The capital recovery factors were calculated using the
equation:
                                   (1 + i)n- 1
          Where i = interest rate, expressed as a decimal,
                n = economic life of the component,  years.
The interest rate used was 10 percent.   The expected life of the monitoring
instrument was 6 years.  Dual mechanical seals and rupture  disks were
assumed to have a 2-year life.   All other control equipment is assumed
to have a 10-year life.
     For the purposes of determining recovery credits,  the  value of VOC
is assumed to be $192/Mg, and the value of methane-ethane is assumed to
be $61/Mg.   The derivation of these values is described in  Table 8-5.
     Implementation of Regulatory Alternatives II, III, and IV involves
initial detection and repair of leaking components.   As shown in Table 8-6,
the repair labor-hour requirements of the initial survey are derived by
multiplying the fraction of sources leaking and repair time per source
by the model plant component counts.   The cost of repairing initial
                                 8-9

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                                       Table  8-3.    LEAK DETECTION  AND REPAIR  LABOR-HOUR REQUIREMENTS
Leak detection
Component type
Valves9

Relief valves

Compressor seals
Pump seals9


Monitoring
interval
quarterly
monthly/
quarterly
monthly
quarterly
monthly
quarterly
quarterly
monthly
weekly
Components per
model plant Type of
ABC monitoring3
250 750 2,500 instrument
instrument
instrument
4 12 40 instrument
instrument
2 6 20 instrument
2 6 20 instrument
instrument
visual
Times
monitored
per year
4.0h
4.3h
11. 9h
4
12
4
4
12
52
Leak repair
Monitoring Percent of Estimated
labor-hours sources number of Repair time
required ' initially leaks per year per source
ABC leaking0 ABC (hours)
33
36
99
4.3
13
1.3
1.3
4.0
0.9
100
108
298
13
38
4.0
4.0
12
2.6
333
358
992
43
130
13
13
40
8.7
18 46 139
47 140
48 143
11 0.2 0.5
0.3 0.8
43 0.3 1.0
33 0.79 2.4
0.82 2.5

464 1.131
467
478
1.8 Oj
2.6
3.4 40k
7.9 II1
8.2




Maintenance-
labor- hours
ABC
52
53
54
0
0
12
8.7
9.0

157
158
162
0
0
40
26
28

524
528
540
0
0
136
87
90

 Assumes that instrument monitoring requires a two-person team, and visual  monitoring,  one person.

 Monitoring time per  person:  pumps-instrument 5 min.,  visual 1/2 rain.;  compressors  5 min.; valves 1 min., and safety/relief valves 8 min.  Reference 7.

 Monitoring labor-hours = number of workers x number of components x time to  monitor x  times monitored per year.

 Based on the number  of sources leaking at >_ 10,000 ppmv.   From Table 4-1.
g
 Annual percent recurrence factors have been applied for monthly and quarterly  instrument inspections for relief valves and compressor seals.
 It is assumed that 5 percent of leaks initially detected are found with monthly monitoring (0.05 x 12 = 0.6) and that 10 percent of leaks
 initially detected are found with quarterly monitoring (0.1 x 4 = 0.4).  Number of  leaks = number of components x fraction of sources initially
 leaking x annual  fraction of recurrence factor.   Reference 7.

 Leak repair labor-hours = number of leaks x repair time.

 The values used in calculating labor-hour requirements for valves and pump seals were  developed on the basis of the model and data presented in Appendix E.

 Fractional numbers accounted for by recognizing that it is not necessary to  monitor valves that have previously been identified as leakers and have
 not yet been repaired.

 Weighted average  based on 75 percent of the leaks repaired on-line,  requiring  0.17  hours per repair, and on 25 percent of the leaks, repaired offline,
 requiring 4 hours per repair.   Reference 9.

'it  is  assumed that these leaks are corrected by routine maintenance  at  no  additional labor requirements.  Reference 10.

'Reference  10.

Based on 50 percent of pumps using mechanical  seals, requiring 16 hours  per  repair, and 50 percent of pumps using packed seals, requiring 6 hours per
repair (including the labor-hour equivalent cost of materials).   References  11 and  12.

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           Table 8-4.   LEAK DETECTION AND REPAIR COSTS3
                        (June 1980 dollars)
 Regulatory.
                   Leak detection cost           Repair cost
                       model plant               model plant
alternative        ABC         A       B
IIC
IIId
IVe
730
970
1,800
2,200
2,900
5,400
7,400
9,700
18,000
1,300
1,100
970
4,000
3,300
2,900
13,000
11,000
9,700
aCosts = labor-hours (Table 8-3) x $18/hour (Table 8-5).

 Regulatory Alternative I (baseline control) has zero costs.

cCalculated on the basis of quarterly instrument monitoring for
 valves, relief valves, compressor seals,  and pump seals,  and
 weekly visual monitoring for pump seals.

 Calculated on the basis of monthly/quarterly instrument
 monitoring for valves, monthly instrument monitoring for
 relief valves and pump seals, and weekly  visual monitoring
 for pump seals.

Calculated on the basis of monthly monitoring of valves.
                               8-11

-------
                  Table 8-5.   DERIVATION OF ANNUALIZED LABOR,
                 ADMINISTRATIVE, MAINTENANCE, AND CAPITAL COSTS
1.   Capital  recovery factor for capital costs
    o  Dual  mechanical seals and rupture disks
    o  Other control equipment
    o  Monitoring instruments

2.   Annual maintenance costs
    o  Control  equipment
    o  Monitoring instruments

3.   Annual miscellaneous costs

4.   Labor costs

5.   Administrative and support costs to
    implement regulatory alternative

6.   Annualized charge for initial leak repairs
7.   Recovery credits
    o  Nonmethane-nonethane hydrocarbons (VOC)
    o  Methane-ethane
0.58 x capital
0.163 x capital
0.23 x capital0
0.05 x capital

$3,000e

0.04 x capitalf

$18/hrg

0.40 x (monitoring, labor +
maintenance labor)

(estimated number of leaking
components per model unit  x
repair time) x $18/hr  x 1.4
x 0.163

$192/Mg!f
$ 61/Mg1
 Applies to cost of seals ($972-incremental cost due to specification of dual
 seals instead of single seals) and disk ($230) only.   Two year life, ten
 percent interest.   Reference 7.

 Ten year life, ten percent interest.   Reference 9.

°Six year life, ten percent interest.   Reference 9.

 From Reference 9.
p
 Includes materials and labor for maintenance and calibration.

 Reference 9.

^Includes wages plus 40 percent for labor-related administrative and overhead
 costs.

 From Reference 9.
 Shown in Table 8-3.

••'initial leak repair amortized for ten years at ten percent interest.
i,
 Based on LPG price of 40
-------
                                Table 8-6.   LABOR-HOUR  REQUIREMENTS FOR INITIAL  LEAK  REPAIR
00
i—»
CO

Number of components
per model plant
Component type
Valves
Relief valves
Compressor seals
Pump seals
A
250
4
2
2
B
750
12
6
6
C
2,500
40
20
20
Percent of
sources
leaking in
Initial survey
18
11
43
33
Estimated
Number of leaks
A
45
0.44
0.86
0.66
B
135
1.3
2.6
2.0
C
450
4.4
8.6
6.6
Repair time
per source
(hours)
1.13
0
40
11



Repair labor-hours
A
51
0
34
7.3
B
153
0
104
22
C
509
0
344
73
             Based on the number of sources leaking at >10,000 ppm from Table 4-1.
            bSee Table 8-3.

-------
leaks was amortized over a 10-year period, since this is a one-time
cost.  Administrative and support costs to implement the regulatory
alternatives were assumed to be 40 percent of the leak detection and
repair labor costs.  The initial leak repair cost in Table 8-7 shows
Alternative II to be the most costly.  Costs decrease for the other
alternatives as equipment specifications replace the labor intensive
equipment repairs.
     8.1.2.4  Recovery Credits.  The annual emissions, total emissions
recovered, and annual recovered product credits for each model plant and
regulatory alternative appear in Table 8-8.  Regulatory Alternative I
represents "baseline emissions" and therefore receives no recovery
credits.   In Alternatives III and IV, there is no recovery credit for
the venting of compressors to flares or incinerators.
     8.1.2.5  Net Annual Costs.  The net annual costs shown in Table 8-9
were determined by subtracting the annual  recovered product credit from
the total cost before credit.  For example, Model Plant A under Regulatory
Alternative II has a net annual cost of $4,000, as a result of $9,500 in
costs and $5,500 in recovery credits.
     8.1.2.6  Cost Effectiveness.   The cost effectiveness of the regulatory
alternatives for each model plant is shown in Table 8-10.  Regulatory
Alternatives II and III for all model plants entail  relatively low costs
per Mg of VOC emission reduction when compared to Alternative IV.   Model
Plant B Regulatory Alternative II  and Model Plant C Regulatory
Alternatives II and III have a net annual  credit.  Table 8-11 presents
the cost effectiveness by component type of the alternative techniques
for control of fugitive VOC emissions at new plants.
8.1.3  Modified/Reconstructed Facilities
     8.1.3.1  Capital Costs.   The bases for determining the capital
costs for modified/reconstructed facilities are presented in Table 8-1.
The capital cost for Alternatives  I, II, and III are the same as for new
plants.  However, the capital -cost for Regulatory Alternative IV is
higher than for new plants.  This  is because of the additional costs
incurred through replacement of relief valves, and retrofit installation
of dual mechanical  seals.
                                 8-14

-------
           Table 8-7.  INITIAL LEAK REPAIR COSTS (JUNE 1980 DOLLARS)
                          Initial repair costs       Annualized initial repair
                           for model plants           costs for model plants
Regulatory
alternative
II
III
IV
A
1,700
1,000
920
B
5,000
3,200
2,800
C
17,000
10,000
9,200
A
390
230
210
B
1,100
730
640
C
3,900
2,300
2,100
aRegulatory Alternative I (baseline control) has zero costs.

bCosts = labor-hours (Table 8-6) x $18/hour (Table 8-5).

cAnnualized cost = Costs x 0.163 (capital  recovery factor,  Table 8-5) x
 1.4 (administrative costs, Table 8-5).
                                8-15

-------
                                              Table 8-8.  RECOVERY CREDITS

Model Plant A
Regulatory
alternative
II
III
IV
Recovered
emissions,3
Mg/yr
20 (48)
21 (50)
22 (55)
Recovered
product
value, b
$/yr
5,500
5,800
6,200
Model Plant B
Recovered
emissions,
Mg/yr
61 (140)
64 (140)
69 (160)
Recovered
product
value, b
$/yr
17,000
17,000
19,000
Model Plant C
Recovered
emissions,
Mg/yr
200 (480)
210 (500)
220 (550)
Recovered
product
value, b
$/yr
55,000
58,000
62,000
        xx  = VOC emission values.
CO
       (xx) = Total hydrocarbon emission values.
        Based on numbers presented in Table 7-3.
        due to venting of compressors to flares or incinerators in Alternatives III and IV.
        Based on recovered VOC
        $61/Mg from Table 8-5.
Based on numbers presented in Table 7-3.   Numbers are corrected to account for emissions not recovered
c

Based on recovered VOC value of $192/Mg,  and recovered non-VOC hydrocarbon (methane-ethane) value of

-------
Table 8-9.  ANNUAL COST ESTIMATES (MODEL PLANT A)
         (thousands of June 1980 dollars)
Cost Item
Annual i zed Capital Costs
A. Control equipment
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Initial leak repair
Operating Costs
A. Maintenance costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed- loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Miscellaneous costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
C. Labor charges
1. Monitoring labor
2. Leak repair labor
3. Administrative and support
Total Before Credit
Recovery Credits
Net Annual Cost
Regulatory
IIa III3


2.1 2.1
0.51 0.51
0.26
0.60


0.39 0.23


3.0 3.0
0.16 0.16
0.08
0.19



0.37 0.37
0.12 0.12
0.06
0.15



0.73 0.97
1.3 1.1
0.81 0.83
9.5 11
(5.5) (5.8)
4.0 5.2
Alternative
IVb


2.1
0.51
0.26
0.60
7.0
1.5
0.21


3.0
0.16
0.08
0.19
0.60
0.13

0.37
0.12
0.06
0.15
0.48
0.10

1.8
0.97
1.1
21
(6.2)
15

IVC


2.1
0.51
0.26
0.60
9.9
1.9
0.21


3.0
0.16
0.08
0.19
0,85
0.16

0.37
0.12
0.06
0.15
0.68
0.13

1.8
0.97
1.1
25
(6.2)
19
                   (continued)
                      8-17

-------
Table 8-9.  CONTINUED (MODEL PLANT B)
Cost Item
Annual ized Capital Costs
A. Control equipment
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Initial leak repair
Operating Costs
A. Maintenance costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Miscellaneous costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
C. Labor charges
1. Monitoring labor
2. Leak repair labor
3. Administrative and support
Total Before Credit
Recovery Credits
Net Annual Cost
Regulatory
IIa III3


2.1 2.1
1.5 1.5
0.52
1.8


1.1 0.73


3.0 3.0
0.46 0.46
0.16
0.56



0.37 0.37
0.37 0.37
0.13
0.44



2.2 2.9
4.0 3.3
2.5 2.5
18 21
(17) (17)
1 4
Alternative
IVb


2.1
1.5
0.52
1.8
21
4.4
0.64


3.0
0.46
0.16
0.56
1.9
0.38

0.37
0.37
0.13
0.44
1.5
0.30

5.4
2.9
3.3
53
(19)
34

IVC


2.1
1.5
0.52
1.8
30
5.6
0.64


3.0
0.46
0.16
0.56
2.6
0.48

0.37
0.37
0.13
0.44
2.0
0.38

5.4
2.9
3.3
65
(19)
46
                 (continued)
                    8-18

-------
                           Table 8-9.   CONCLUDED  (MODEL  PLANT C)
Cost Item
Annuali zed Capital Costs
A. Control equipment
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Initial leak repair
Operating Costs
A. Maintenance costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed- loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
B. Miscellaneous costs
1. Monitoring instruments
2. Caps for open-ended lines
3. Compressor vent control system
4. Closed-loop sampling connections
5. Rupture disk system
6. Dual mechanical seals
C. Labor charges
1. Monitoring labor
2. Leak repair labor
3. Administrative and support
Total Before Credit
Recovery Credits
Net'Annual Cost
Regulatory
IIa III3


2.1 2.1
5.0 5.0
1.2
6.1


3.9 2.3


3.0 3.0
1.5 1.5
0.38
1.9



0.37 0.37
1.2 1.2
0.30
1.5



7.4 9.7
13 11
8.2 8.3
46 56
(55) (58)
(9) (2)
Alternative
IVb


2.1
5.0
1.2
6.1
70
15
2.1


3.0
1.5
0.38
1.9
4.0
1.3

0.37
1.2
0.30
1.5
4.8
1.0

18
9.7
11
160
(62)
98

IVC


2.1
5.0
1.2
6.1
99
19
2.1


3.0
1.5
0.38
1.9
7.5
1.6

0.37
1.2
0.30
1.5
6.8
1.3

18
9.7
11
200
(62)
140
"Costs are the same  for new or modified/reconstructed facilities.
 Costs for new facilities.
cCosts for modified/reconstructed  facilities.
                                              3-19

-------
                                  Table 8-10.   COST EFFECTIVENESS OF REGULATORY ALTERNATIVES

                                                        (Model  Plant A)
oo
ro
o

Regulatory Alternative
Parameter
Capital cost ($)
Annual cost before credit ($)
Annual recovery credit ($)
Net annual cost ($)
Total VOC reduction (Mg/yr)
Cost effectivenessd ($/Mg VOC)
Incremental cost effectiveness6
($/Mg VOC)
I
0
0
0
0
0
0
0
n=
12,000
9,500
5,500
4,000
21
190
190
III3
18,000
11,000
5,800
5,200
22
240
1,200
IVb
32,000
21,000
6,200
15,000
23
650
9,800
IVC
38,000
25,000
6,200
19,000
23
830
13,800
                                                         (continued)

-------
Table 8-10.  Continued (PLANT B)







Regulatory Alternative


00
i
rv>
i— •



Parameter
Capital cost ($)
Annual cost before credit ($)
Annual recovery credit ($)
Net annual cost ($)
Total VOC reduction (Mg/yr)
Cost effectiveness*1 ($/Mg VOC)
Incremental cost effectiveness6
($/Mg VOC)
I
0
0
0
0
0
0
0
IIa
18,000
18,000
17,000
1,000
63
16
16
III3
33,000
21,000
17,000
4,000
66
61
1,000
IVb
77,000
53,000
19,000
34,000
71
480
6,000
IVC
93,000
65,000
19,000
46,000
71
650
8,400
         (continued)

-------
                                     Table 8-10.  Concluded (PLANT C)

Regulatory Alternative
Parameter
Capital cost ($)
Annual cost before credit ($)
Annual recovery credit ($)
Net annual cost ($)
oo
rlo Total VOC reduction (Mg/yr)
ro
Cost effectiveness01 ($/Mg VOC)
Incremental cost effectiveness6
I
0
0
0
0

0

0
0
n'
40,000
46,000
55,000
(9,000)

210

(43)
(43)
in'
85,000
56,000
58,000
(2,000)

220

(9.1)
700
IVb
230,000
160,000
62,000
98,000

230

430
10,000
ivc
290,000
200,000
62,000
140,000

230

610
14,000
 Costs are the same for new or modified/reconstructed facilities.
 Costs for new facilities.

""Costs for modified/reconstructed facilities.
H
 Cost effectiveness = total VOC reduction divided by the net annual cost.

"Incremental  cost effectiveness = difference between the net annual costs of the given and previous
 regulatory alternatives divided by the difference between the total VOC reduction of the given and
 previous  regulatory alternatives.

-------
                       Table 8-11.  COST  EFFECTIVENESS  BY  COMPONENT TYPE OF ALTERNATIVE  TECHNIQUES  FOR
                           CONTROL OF FUGITIVE VOC EMISSIONS FROM NATURAL GAS PLANTS  (MODEL PLANT B)
oo
ro
CO
Component type
Valves


Relief valves



Open-ended lines
Sampling connections
Compressor seals

Pump seals



Number of
Control technique components
Quarterly monitoring 750
Monthly/quarterly monitoring
Monthly monitoring
Quarterly monitoring 12
Monthly monitoring
Rupture disk (new)
Rupture disk (retrofit)
Cap 150
Closed purge 21
Quarterly monitoring 6
Vent control
Quarterly monitoring 6
Monthly monitoring
Dual seals (new)
Dual seals (retrofit)
VOC
emission
reduction,
Mg/yr
40
40
43
0.88
0.95
1.5
1.5
19
2.8
1.7
2.2
1.5
1.7
2.6
2.6
Annual
cost,
$103
7.1
7.3
12
0.33
0.96
24
35
2.3
2.8
15
0.81
0.92
1.2
5.1
6.5
Recovery
credits,
$103
11
11
12
0.94
0.97
1.4
1.4
4.2
0.54
0.72
0.0
0.32
0.35
0.54
0.54
Net
annual
cost
$103
(3.9)
(3.7)
0.0
(0.61)
(0.01)
23
34
(1-9)
2.3
14
0.81
0.60
0.85
4.6
6.0
Cost
effectiveness,
$/Mg
(98)
(93)
0
(690)
(ID
15,000
23,000
(100)
820
8,200
370
400
500
1,800
2,300
Incremental
cost
effectiveness,
$/Mg
(98)
a
1,200
(690)
8,600
42,000
62,000
(100)
820
8,200
(26,000)
400
1,300
4,200
5,700
     (   ) = Net credit.

     aNo change in emissions from previous control alternative.

-------
     8.1.3.2  Annual Costs.   The annual control costs for modified/
reconstructed plants are derived from the same basis as new plants (see
Table 8-5).   The net annual  costs for modified/reconstructed facilities
are higher than for new facilities under Regulatory Alternative IV (I,
II, and III  are the same as  new facilities), as shown in Table 8-10.
The recovery credits remain  the same as for new plants.
     8.1.3.3  Cost Effectiveness.   The cost effectiveness of Regulatory
Alternative IV for modified/reconstructed facilities is also shown in
Table 8-10.   The cost effectiveness of this Alternative is substantially
higher than for new facilities.
8.1.4  Projected Cost Impacts
     The projected costs of  implementing the regulatory alternatives are
presented in Table 8-12.  The cost estimates were obtained by multiplying
the costs per model plant by the model plant growth estimates given in
Table 7-4 for 1983 to 1987.   The cost impacts for new plants and modified/
reconstructed plants are reported separately in order to differentiate
between expected impacts, represented by new plants, and maximum impacts,
represented by new plants with the addition of modified/reconstructed
plant impacts.  A maximum impact would result if all changes to existing
plants constitute modification/reconstruction.   The total  capital  costs
reflect the cumulative costs of implementing the regulatory alternatives
in a given year.  All other  costs shown are for plants subject to  new
source performance standards in the indicated year.
8.2  OTHER COST CONSIDERATIONS
     Environmental, safety,  and health statutes that may cause an  outlay
of funds by the gas processing industry are listed in Table 8-13.
Specific costs to the industry to comply with the provisions, requirements,
and regulations of the statutes are unavailable.
                                 8-24

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                            Table  8-12.   FIFTH  YEAR NATIONWIDE  COSTS  OF  THE  REGULATORY  ALTERNATIVES

                                               (thousands  of  June  1980 dollars)
co
i

Cost item
New plants
Cumulative capital costs by 1987
Total annual costs
Total recovery credit
Net annual costs
Modified/reconstructed facilities
Cumulative capital costs by 1987
Total annual costs
Total recovery credits
Net annual costs
II

3,200
3,200
3,000
200

990
1,100
1,100
0
III

5,900
3,800
3,000
800

2,000
1,300
1,200
100
IV

14,000
9,500
3,400
6,100

6,100
4,200
1,300
900

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                      Table  8-13.   STATUTES  THAT MAY BE APPLICABLE TO THE NATURAL GAS  PROCESSING  INDUSTRY
     Statute
    Applicable provision, regulation or
          requirement of statute
           Statute
 Applicable provision, regulation or
        requirement of statute
    Clean Air Act and Admendments   o  State  implementation plans

                                    o  National emission standards for
                                         hazardous air pollutants

                                    o  New  source performance standards
    Clean Water Act (Federal
      Water Pollution Act)
Co
r\>
CTl
    Resource Conservation and
      Recovery Act
    Toxic  Substances Control
      Act
 o   PSD construction permits
 o   Nonattainment construction permits
 o   Discharge permits

 o   Effluent limitations guidelines

 o   New source performance standards
 o   Control of oil spills and discharges
                                      Pretreatment requirements
                                      Monitoring and reporting
o
o
o  Permitting of industrial  projects
     that impinge on wetlands  or
     public waters
o  Environmental impact statements
o  Permits for treatment,  storage,  and
     disposal of hazardous wastes
o  Establishes system to track
     hazardous wastes
o  Establishes recordkeeping,  reporting,
     labeling, and monitoring  system
     for hazardous wastes
o  Superfund
o  Premanufacture notification
o  Labeling, recordkeeping
o  Reporting requirements
o  Toxicity testing
                                           Occupational  Safety & Health
                                             Act
                                                                              Coastal Zone Management Act
National Environmental  Policy
  Act
Safe Drinking Water Act

Marine Sanctuary Act
                                o  Walking-working  surface  standards

                                o  Means  of  egress  standards
                                o  Occupational  health  and  environ-
                                   mental  control standards
                                o  Hazardous material standards
                                o  Personal  protective  equipment
                                     standards
                                o  General environmental control
                                     standards
                                o  Medical and  first aid standards
                                o  Fire protection  standards
                                o  Compressed gas and compressed air
                                     equipment
                                o  Welding,  brazing, and cutting
                                     standards
                                   States may veto Federal permits for
                                     plants to be sited in coastal zone
o  Requires environmental  impact
     statements
o  Requires underground injection
     control permits
o  Ocean dumping permits
o  Recordkeeping and reporting

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8.3  REFERENCES


 1.  Telephone conversation.  Michael Alexander, TRW, with Ms. M.  Fecci
     of Analabs/Foxboro.  March 23, 1982.  Price of Century Systems
     OVA-108 in July 1980.

 2.  Telephone conversation.  Michael Alexander, TRW, with Mr. Harris  of
     Dillon Supply, Durham, N.C.  June 17, 1981.  Price of gate valves.

 3.  Economic Indicators.  Chemical Engineering.  Vol. 88 #12.  June 15,
     1981.  p.  7.

 4.  Letter with attachments from Texas Chemical Council to Walt Barber,
     U.S. EPA.   June 30, 1980.

 5.  Telephone conversation.  Michael Alexander, TRW, with Danny Keith,
     Dillon Supply Co., Raleigh, N.C.  June 15, 1981.  Costs of valves,
     pipes, and fittings.

 6.  McMahon, Leonard A., 1981 Dodge Guide.  Annual Edition No. 13,
     McGraw-Hill Publishing Co.

 7.  VOC Fugitive Emissions in Petroleum Refining Industry - Background
     Information for Proposed Standards.   U.S. EPA, OAQPS.  April 1981.

 8.  Memorandum from Cole, D.  G., PES, Inc., to K.  C. Hustvedt, U.S.
     Environmental Protection Agency.  Estimated Costs for Rupture Disk
     System with a 3-way valve.  July 29, 1981.

 9.  Erikson, D. G. and V. Kalcevic.  Emission Control Options for the
     Synthetic Organic Chemicals Manufacturing Industry, Fugitive Emissions
     Report, Draft Final.  Hydroscience,  Inc.   1979.

10.  Letter with attachments from J. M.  Johnson, Exxon Company, U.S.A.,
     to Robert T. Walsh, U.S.  EPA.   July 28, 1977.

11.  Environmental Protection Agency.  Control of Volatile Organic
     Compounds Leaks from Petroleum Refinery Equipment.  EPA-450/2-78-036,
     OAQPS No.  1.2-111.  June 1978.

12.  Letter with attachments from R. E.  Van Ingen,  Shell Oil Company,  to
     D. R. Goodwin, OAQPS, U.S. EPA.  January 10, 1977.  Response to 114
     letter on hydrocarbon sources from petroleum refineries.

13.  Telephone conversation.  T. Hennings, TRW, with Editor, Oilgram
     News.  February 25, 1981.   Price of LPG on June 16, 1980.

14.  Nelson, W.  L. , Petroleum Refinery Engineering.  McGraw-Hill Book
     Co. , Inc.   New York.  1958.  p. 32.

15.  DOE Monthly Energy Review.  January 1981.  DOE/EIA-0035(81/01).
     p. 88.
                                 8-27

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             9.  ECONOMIC ANALYSIS OF THE ONSHORE NATURAL GAS
                       PRODUCTION INDUSTRY VOC NSPS

9.1  INDUSTRY PROFILE
     This section describes the general  business and economic conditions of
the onshore natural  gas production industry.  The primary focus of the
discussion is on the natural  gas processing segment of the industry for
which NSPS for VOC emissions  are being considered.
     Projections for the year 1987, five years after a proposal date of
1982 for the NSPS for new, modified or reconstructed sources, were
developed for the industry.  The growth  projections are presented to
illustrate the future trend of the industry.  The profile and the
projections, including significant factors and trends in the industry, are
presented to aid in the determination of economic impacts of the proposed
standards.  The energy and environmental impact analyses also were
conducted based upon these projections.   The economic impacts are described
in subsequent sections.
9.1.1  Onshore Natural Gas Production Industry
The natural gas system in the United States consists of producers,
processors, dealers, interstate and intrastate pipelines, distributors and
consumers.  The production industry includes hundreds of firms engaged in
the exploration, drilling, producing and processing of natural gas.  A
relatively small number of companies dominate the industry.   The American
Association of Petroleum Geologists (AAPG) states that the 16 largest firms
in the industry found 53.7 percent of 2.8 billion barrels of crude oil and
40.3 percent of 41.3 trillion cubic feet of natural gas discovered during
the period from 1969 to 1978.  Also, the AAPG states that the 16 largest
companies accounted for about 60 percent of industry expenditures for
geological and geophysical information and lease acquisition.  However,
                                    9-1

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these large companies spend almost twice as much money as smaller firms on
predrilling exploration and one-half as much as the others on wildcat
drilling.
     Approximately two-thirds of all processed gas is transmitted in
pipelines across state lines to be sold in various metropolitan areas.  The
remainder is sold in intrastate markets.  Approximately 100 pipeline
companies operate the interstate pipeline network.  The pipeline sector of
the industry tends to be dominated by large companies more than the
production sector.  In 1971, the four largest pipeline companies accounted
for 35 percent of the total interstate pipeline volume, while the 20
largest companies transported over 93 percent of the gas.
     Companies involved in the final distribution of the gas constitute the
least concentrated sector of the industry.  Over 1,600 companies buy gas
from pipelines and distribute it to various communities.  Because they
operate  in different service areas, these companies rarely compete with one
another, except in input markets, and are often regulated by state or local
agencies.
     There is some vertical integration in the industry with pipeline
companies often owning producing wells.  However, few companies engage in
production, transmission and distribution of the gas.  In contrast,
horizontal integration is quite extensive.  In the production sector,
almost all companies produce crude oil and natural gas liquids in addition
to natural gas although no one company predominates.  In addition, many
also have investments in coal, oil shale, synfuels and mineral industries.
     9.1.1.1  Natural Gas Processing Facilities.  In 1980, there were 772
gas processing plants in the United States, with a combined total capacity
of approximately 71.2 billion cubic feet per day.  As of January 1, 1980,
these plants were utilizing about 63 percent of their combined capacity.
Table 9-1 presents a distribution of the gas plants based on their
capacity.  As this table indicates, at least 60 percent of the plants have
capacities of 50 million cubic feet per day (MMcfd) or less.  Another 16.8
percent  of the plants have capacities between 50 MMcfd and 100 MMcfd.  The
remainder of the gas plants have capacities greater than 100 MMcfd, ranging
as high  as 2,650 MMcfd.
                                    9-2

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        Table 9-1.  DISTRIBUTION OF GAS PLANTS BY CAPACITY3  (1980)


Plant Capacity                                           Number of Plants
   (MMcfd)


         50                                                      460

 51 -   100                                                      130

100 -   200                                                       70

201 -   300                                                       34

301 -   400                                                        9

401 -   500                                                        3

501 -   600                                                        7

601 -   700                                                        C

701 -   800                                                        2

801 -   900                                                        6

901 - 1,000                                                        6

    > 1,000                                                        6

No Response                                                       39

    TOTAL                                                        772


a Based on data presented in Oil and Gas Journal,  July 14,  1980.
                                    9-3

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     There are a number of different process methods currently being used
at natural gas processing plants: adsorption, refrigerated absorption,
refrigeration, compression, adsorption, cryogenic—Joule-Thomson and
cryogenic-expander.  The distribution of gas plants by these process
methods and combinations of these methods is presented in Table 9-2.
     In 1980, there were 138 different companies operating gas processing
plants in the United States.  Table 9-3, which shows the distribution of
gas plants by ownership, lists the companies that own more than 20 plants.
This table indicates that over 55 percent of the gas plants are owned by
these "larger" companies.  Also, Table 9-3 indicates that almost 85 percent
of the 138 companies own less than ten gas plants.•
     All the gas plants in the United States in 1980 were located in
twenty-two states, including two plants in Alaska.  Table 9-4 shows a
distribution of gas plants based on location and ranked in order of gas
plant capacity.  As the table indicates, over 46 percent of the plants are
located in Texas.  States not listed in Table 9-4 have less than ten gas
plants.
     9.1.1.2  Markets.  Although the natural gas component of total energy
production has decreased from 40 percent in 1973 to 34 percent in 1980 as
indicated in Table 9-5, the natural gas production industry is expected to
continue to supply a significant fraction of total domestic energy
requirements.  Exploration and production activities for natural gas are
anticipated to continue to increase as a result of phased natural gas price
deregulation and expected price increases.
     Imports of natural gas have remained fairly constant since 1973,
ranging from 953 billion cubic feet in 1975 to 1,253 billion cubic feet in
1979.  Imports were 984 billion cubic feet in 1980 representing 4 percent
of domestic consumption.  Exports of natural gas declined from 77 billion
cubic feet in 1973 to 49 billion cubic feet in 1980. Exports are primarily
to Japan and Mexico.  Imports are primarily from Canada, Mexico, and
Algeria.
     Domestic aggregate retail price elasticities of demand for solid
fuels, natural gas, electricity and petroleum are shown in Table 9-6.
These elasticities represent the change in final demand for each fuel with
                                    9-4

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     Table 9-2.  DISTRIBUTION OF GAS PLANTS BY PROCESS METHOD9  (1980)

               Process'Method                             Number of  Plants

Absorption                                                       77
Refrigerated Absorption                                         280
Refrigeration                                                   161
Compression                                                       7
Adsorption                                                       40
Cryogenic-Joule-Thomson                                          19
Cryogenic-Expander                                              147
Absorption & Refrigerated Absorption                              2
Absorption & Compression                                          1
Refrigerated Absorption & Refrigeration                           2
Refrigerated Absorption & Adsorption                              1
Refrigerated Absorption & Cryogenic-Joule-Thomson                "2
Refrigerated Absorption & Cryogenic-Expander                     13
Refrigeration & Compression                                       1
Refrigeration & Cryogenic-Joule-Thomson                           1
Cryogenic-Joule-Thomson & Expander                               10
No Response                                                       8
TOTAL                                                           772

a Based on data presented in Oil and Gas Journal, July 14, 1980.
                                    9-5

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        Table 9-3.  DISTRIBUTION OF GAS PLANTS*BY OWNERSHIP3  (1980)
               Company Owner
Number of Plants
Amoco Production Company
Cities Service Company
Phillips Petroleum Company
Warren Petroleum Company
Exxon Company
Shell Oil Company
Sun Gas Company
Getty Oil Company
Mobil Oil Corporation
Texaco, Inc.
ARCO Oil and Gas Company
Chevron USAS Inc.
Union Oil Company of California
Mitchell Energy & Development Corporation
Number of companies that own between 10 and 20 plants
Number of companies that own less than 10 plants-
Total number of companies that own gas plants
TOTAL
       47
       41
       37
       35
       33
       33
       33
       26
       26
       25
       24
       23
       23
       22
        7
      117
      138
      772
  Based on data presented in Qil and Gas Journal , July 14,  1980.
                                    9-6

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          Table 9-4  DISTRIBUTION OF GAS PLANTS BY STATE3 (1980)
State

Texas
Louisiana
Kansas
Oklahoma
New Mexico
Wyoming
California
Colorado
All other states
TOTAL
Number of plants

356
103
26
86
34
40
37
27
63
772
Plant
capacity
(MMcfd)
24,646.9
24,566.7
5,320.9
4,267.7
3,632.1
1,357.7
1,254.5
799.6
5,346.5
71,192.6
3 Based on data presented in Oil  and Gas Journal,  July 14,  1980.
                                    9-7

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                   Table 9-5.  PRODUCTION OF ENERGY BY TYPE, UNITED STATES (Quadrillion Btu)

1973
1974
1975'
1976
1977
10 1978
i
00
1979
1980
Coal1
14.366
14.468
15.189
15.853
15.829
15.037
17.651
18.877
Crude
oil2
19.493
18.575
17.729
17.262
17.454
18.434
18.104
18.250
NGPL3
2.569
2.471
2.374
2.327
2.327
2.245
2.286
2.263
Natural
gas
(dry)
22.187
21.210
19.640
19.480
19.565
19.485
20.076
19.754
Hydro-
electric
power
2.861
3.177
3.155
2.976
2.333
2.958
2.954
2.913
Nuclear
electric
power
0.910
1.272
1.900
2.111
2.702
2.977
2.748
2.704
Other5
0.046
0.056
0.072
0.081
0.082
0.068
0.089
0.114
Total
energy
produced
62.433
61.229
60.059
60.091
60.293
61.204
63.907
64.876
% NG
of
total
40
39
37
36
36
36
35
34
Totals may not equal sum of components due to independent rounding.

2 Includes bituminous coal, lignite and anthracite.
~ Includes lease condensate.
. Natural gas plant liquids.
r Includes industrial and utility production of hydropower.
  Includes geothermal power and electricity produced from wood and waste.
R = Revised data
Source:   U.S. Department of Energy, Energy Information Administration calculations.
         July 1981.
Monthly Energy Review,

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Table 9-6.  AGGREGATE RETAIL PRICE ELASTICITIES OF DEMAND, U.S.
                      (Estimate for 1985)
Price elasticity of demand
With respect to
Solid fuels
Natural gas
Electricity
Petroleum
Source: The Global
Solid
fuels
-.215
.005
.011
.002
2000 Report
Natural
gas El
.030
-.426
.052
.013
to the President,
ectricity
.131
.228
-.376
.077
(Volume III:
Petroleum
.031
.062
.111
-.263

    Documentation), A report prepared by the Council  on Environmental
    Quality and the Department of State.  April  1981.  p.  301.
                              9-9

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respect to a change in the price of all four aggregate fuel  types.
Therefore, the diagonal corresponding to direct price elasticity  should
have a negative sign.  For example, the domestic  retail price elasticity
for natural gas is -.426, indicating an inelastic aggregate  retail  demand.
Electricity has the highest cross price elasticity with respect to  natural
gas with a value of .228, indicating that a one percent increase  in  the
retail natural gas price causes a .228 percent increase in the aggregate
quantity demanded of electricity.  All of the cross price elasticities are
positive, representing interfuel substitution.
9.1.2  Onshore Natural Gas Production Industry—Growth and Projections
     This section discusses the historical production and price of  natural
gas.  Natural gas production is projected for the years 1985, 1990  and 2000
and distributed in the categories of onshore, offshore, discoveries  from
existing fields and discoveries from new fields.
     9.1.2.1  Historical Data.  Marketed production of natural gas
increased from 5.42 trillion cubic feet in 1949 to a peak of 22.65  trillion
cubic feet in 1973.  Increases in marketed production from 1949 through
1973 averaged 6.0 percent annually.  In 1974 and 1975, marketed production
decreased 4.6 percent and 6.9 percent, respectively.  After 1976, marketed
production declined slightly to 19.67 trillion cubic feet in 1979.
     Total gross withdrawals of natural gas from both gas wells and  oil
wells generally follow the same trend as marketed production.  However, the
volume of natural gas withdrawn from oil wells has remained relatively
constant at about three to five trillion cubic feet per year from 1949 to
the present.  Table 9-7 presents total natural  gas production distributed
between onshore and offshore production for the years 1949 through 1979.
Onshore production declined from 99.1 percent of the total in 1954 to 72.4
percent of the total in 1979.  The difference between gross withdrawals and
marketed production represents quantities from gas wells and oil wells that
were either vented, flared or used for reservoir repressuring.    In 1980,
there were approximately 175,000 producing gas wells in the United States.
Although most natural gas is produced from natural gas wells, about  18
percent is produced from crude oil  wells.
                                   9-10

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            Table 9-7.   NATURAL  GAS GROSS  WITHDRAWALS AND MARKETED ONSHORE AND OFFSHORE PRODUCTION
Production in Trillion Cubic Feet
Year
1949
195C
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970'
1971
1972
1973
1974
1975
1976
1977
1978
1979b
From
Gas Wells
4.99
5.60
6.48
5.84
7.10
7.47
7.84
8.31
8.72
9.15
10.10
10.85
11.20
11.70
12.61
13.11
13.52
13.59
15.35
16.54
17.49
18.59
18.93
19.04
19.37
18.67
17.38
17.19
17.42
17.39
17.17
From
01 T Wells
2.56
2.88
3.21
3.43
3.55
3.52
3.88
4.07
4.19
3.9'9
4.13
4.23
4.27
4.34
4.37
4.43
4.44
5.14
4.91
4.79
5.19
5.19
5.16
4.97
4.70
4.18
3.72
3.75
3.68
3.91
3.75
Gross
Withdrawals
7.55
8.48
9.59
10.27
10.65
10.98
11.72
12.37
12.91
13.15
14.23
15.09
15.46
16.04
16.97
17.54
17.96
19.03
20.25
21.33
22.68
23.79
24.09
24.02
24.07
22.85
21.10
20.94
21.10
21.31
20.92
Marketed3
Production
5.42
6.28
7.46
8.01
8.40
8.74
9.41
10.08
10.68
11.03
12.05
12.77
13.25
13.88
14.75
15.55
16.04
17.21
18.17
19.32
20.70
21.92
22.49
22.53
22.65
21.60
20.11
19.95
20.03
19.97
19.67
Onshore
Production
NA
NA
NA
NA
NA
3.66
9.28
9.94
10.51
10.77
11.70
12.33
12.77
13.24
13.99
14.70
15.10
15.84
16.33
17.00
17.86
18.70
18.74
18.77
18.67
17.37
15.85
15.65
15.49
14.87
14.25
Offshore
Production
NA
NA
NA
NA
NA
0.08
0.13
0.14
0.17
0.26
0.35
0.44
0.48
0.64
0.76
0.85
0.94
1.37
1.84
2.32
2.84
3.22
3.75
3.76
3.98
4.23
4.26
4.30
4.54
5.10
5.42
Percentage
Onshore
NA
NA
NA
NA
NA
99.1
98.6
98.6
98.4
97.6
97.1
96.6
96.4
95.4
94.8
94.5
94.1
92.0
89.9
88.0
36.3
85.3
83.2
83.3
82.4
80.4
78.8
78.4
77.3
74.5
72.4
Offshore
NA
NA
NA
NA
NA
0.9
1.4
1.4
1.6
2.4
2.9
3.4
3.6
4.6
5.2
5.5
5.9
S.O
10.1
12.0
13.7
14.7
16.8
16.7
17.6
19.6
21.2
21.6
22.7
25.5
27.6
NA   Not Available.


  Marketed  production  is  derived.   It  is  gross withdrawals  from producing  reservoirs  less gas  used  for  reservoir
  representing  and quantities  vented and  flared.

  Estimated,  based on  reported data through  November.


  N°te:   Sum  of components may not equal  total due to  independent rounding.  Beginning with  1965 data,  all  volumes
         are  shown on  a pressure base  of  14.73 psia at 60°F.  For prior years,  the pressure  base is  14.65  psia  at
         60°F.

  Sources:


     •   1949 through  1975, U.S. Department  of the Interior, Bureau of Mines, Minerals Yearbook  "Natural  Gas"
         chapter.
     •   1976 through  1978, U.S. Department  of Energy, Energy Information  Administration, Natural Gas Production
         and  Consumption, annual.


  Data from U.S. Department of the Interior. Geological Survey - Conservation Division, Outer  Continental  Shelf
  j tStl S tl CS *
                                                      9-11

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     The nominal  price of natural gas remained reasonably steady during the
period from 1955 through 1973.  Since 1973, the year of the Arab Oil
Embargo, the price has consistently increased in real terms.  Figure 9-1
shows selected natural gas prices for three categories for the period from
1955 through 1979. 4  In 1979, the price of natural gas at the wellhead was
$1.13 per million Btu, $1.85 per million Btu at the city gate and $2.50 per
million Btu delivered to ultimate customer.  This consistent increase in
the price coupled with the deregulation of the price of natural gas in
almost all categories before the end of 1985 will boost the revenues and
profitability margins for the industry.  This will contribute to growth in
capital availability potentially to be used for more drilling, deeper
drilling and increased exploration and production of tight gas formations.
     Since the Oil Embargo in 1973, the financial condition of the onshore
crude oil and natural gas production industry has been improving steadily
in both revenues and net profits.  Composite financial data shown in Table
9-8 indicate increased revenues from $15,292 million in 1976 to $38,000
million in 1980.  During the same period, net profits increased from $1,155
million to $1,925 million.
     Composite net profit margins as a percent of sales however have
declined from 7.6 percent in 1976 to 5.1 percent in 1980.  This fact
indicates that production costs have risen at a faster pace than prices.
Also,  total capital has grown at a slower pace than revenues and profits.
Consequently, return on total assets and return on equity have improved.
According to Value Line Investment Survey; the composite industry will
continue to have a healthy financial future into the 1980's.  It is
projected in 1983-85 that the industry will have a composite net profit
margin  of 4.6 percent on annual revenues of approximately $70 billion in
current dollars.  The long term debt ratio is projected to be 45.5 percent.
Total  capital is projected to increase to $35,500 million in current
dollars or 51 percent of revenues in 1983-85.
     9.1.2.2  Five-Year Projections.  In this subsection, projections for
the number of new and modified and reconstructed gas processing facilities
in the years 1983 through 1987 are developed.  The form of the growth in
terms  of new facilities, modified facilities and reconstructed facilities
                                   9-12

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I
I—•
CO
          2.50
      rs
      4J
      CO
      c.
      o
      -   1.50 -
          1.00
             1955
                                1960
1965
1970
1975    78 79
                                          Year
Figure 9-1.  Selected natural gas prices - three  categories for the period 1955-1979.

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               Table 9-8.  COMPOSITE FINANCIAL DATA FOR THE NATURAL GAS INDUSTRY 1976-1981 and
                                     1983-1985 ESTIMATES (Current dollars)
Item
Revenues ($mill)
Net Profit ($mill)
Income Tax Rate
Net Profit Margin
Long-term Debt Ratio
Common Equity Ratio
Total Capital ($mill)
Net Plant ($mill)
% Earned Total Capital
% Earned Net Worth
% Earned Comm. Equity
% Retained to Comm. Equity
% All Dividends to Net Profit
Average Annual P/E Ratio
Average Annual Dividend Yield
Fixed Charge Coverage
1976
15,292
1,155
44.4%
7.6%
54.3%
41.0%
19,538
18,356
8.0%
12.9%
13.5%
7.5%
48%
7.1
6.3%
278%
1977
19,430
1,356
43.1%
7.0%
50.8%
44.4%
20,207
19,865
8.8%
13.6%
14.2%
8.0%
47%
7.6
5.8%
281%
1978
22,463
1,399
43.9%
6.2%
48 . 5%
46.8%
20,611
21,423
8.9%
13.2%
13.7%
7.2%
50%
7.1
6.6%
284%
1979
30,357
1,702
43.2%
5.6%
48.0%
47 . 1%
22,236
23,453
9.8%
14.7%
15.4%
8.9%
45%
6.8
6.3%
287%
1980
38,000
1,925
44.0%
5.1%
48.5%
48.0%
23,750
26,000
10.5%
15.5%
16.0%
9.0%
45%
NA
NA
290%
1981
46,000
2,200
45.0%
4.8%
47.0%
50.0%
26,000
27,000
10.5%
15.5%
16.0%
9.0%
45%
NA
NA
295%
83-85E
70,000
3,200
47.0%
4.6%
45 . 5%
53.0%
35,500
33,000
11.5%
16.5%
17.0%
9.5%
45%
8.0
6.0%
310%
 E = Estimates
NA = Not available
Source:  A. Bernhard & Company.  "Natural Gas Industry."  Value Line Investment Survey, July 18, 1980.

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is discussed.  The size distribution of new facilities is developed  based
upon industry's historical trend.  Information on the projection of  natural
gas price is presented, and the effect of price deregulation on natural  gas
production is discussed.
     Production of natural gas by conventional techniques has exceeded the
rate of reserve additions in recent years.  Consequently, conventional
reserves are expected to continue declining and production, from
conventional reserves will decline as well.  Annual production of
conventional natural gas is expected to decline roughly 1.5 to 2.0 trillion
cubic feet every five years through 1995.  The production of associated  and
dissolved gas is expected to decline less rapidly than the production of
nonassociated gas, due to higher price incentives for crude oil.
     Table 9-9 presents the American Gas Association's (AGA) projected
Lower-48 states conventional natural  gas production for the period from
1980 through 2000.    In 1985, the production is projected to be 19.7
trillion cubic feet, decreasing to 17.7 trillion cubic feet in 1990.
Natural gas produced through enhanced gas recovery (EGR)  techniques is
expected to increase rapidly and provide a significant portion of the
production by 1995.
     Production from new (past 1977) onshore discoveries  according to AGA
is projected to total 3.6 trillion cubic feet in 1985 and to increase
consistently through 1990 when it will reach the maximum of 4.9 trillion
cubic feet.  An increasing percentage of total onshore production is      •
projected to come from new discoveries.    Table 9-9 includes projected
Lower-48 states onshore conventional  natural gas production from new
discoveries for the period from 1980 through 2000.    Figure 9-2 portrays
the onshore natural gas production from new discoveries through the year
2000.
     Natural gas supply projections are conducted by various oil and gas
companies as well as government and independent study groups.  Table 9-10
presents a comparison of 1990 projection forecasts presented by the
Department of Energy (DOE), the American Gas Association (AGA), Exxon,
Tenneco and other private study groups.    AGA's forecast of 16.3
quadrillion Btu per year is 8.4 percent lower than DOE's forecast of 17.8
                                   9-15

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            Table 9-9.   PROJECTED LOWER-48 STATES CONVENTIONAL
                          NATURAL GAS PRODUCTION
  Gas  Source
                                 Production, Trillion Cubic Feet
1980
1985
1990
1995
2000
Onshore
Old Inter3
Old Intra3
Old Direct Sale
New
Offshore h
Old Inter3'0
New Inter0
Total
Old Inter
Old Intra
Old Direct Sale
New
TOTALd

4.9
3.6
4.0
1.5

5.6
0.1

10.5
3.6
4.0
1.6
19.7

3.6
2.4
2.6
3.6

4.1
3.4

7.7
2.4
2.6
7.0
19.7

2.0
1.3
1.5
4.9

1.4
6.6

3.4
1.3
1.5
11.5
17.7

1.1
0.7
0.8
4.8

0.7
6.5

1.5
0.7
0.8
11.3
14.6

0.7
0.4
0.5
3.8

nil
5.4

0.7
0.4
0.5
9.2
10.8
a
  Including new additions from pre-1977 leases.
c Post-1976 leases only.
  Totals may not add due  to independent rounding.
Source:  American Gas Association, Gas Supply and  Statistics—Total  Energy
         Resource Analysis Model  (TERA) 80-1, Appendix A, Figure A-2,
         p. 21.
                                9-16

-------
                                          1   1   I   I   I   1   1    I   1
   1980
2000
Figure  9-2.   Projected new discovery onshore natural gas production
                                 9-17

-------
        Table 9-10.  PROJECTIONS OF NATURAL GAS SUPPLY:  COMPARISON OF 1990 FORECASTS6 (Quadrillion Btu)
1979 Projections for 1990


Units
Domestic Production
Conventional
North Alaska
Synthetic Gas
Subtotal
Net Imports
Pipeline
Liquefied Natural Gas
Subtotal
Total Supply

1978
Actual

19.5
f
0.2
19.7

0.9
g
0.9
20.6
DOE
DOE/
EIA a/

17.8
0.9
0.3
19.0

0
0.8
0.8
19.8

u
AGAb

15.3-17.3
1.6
1.1
19.9-21.9

2.1
2.0
4.2
24.1-26.1

*•>
DPPC

16.9
0.4
0.6
18.0

2.0
1.0
3.1
21.0

A
Pace0

16.1
1.0
0.8
18.0

1.4
0.8
2.2
20.2

p
Exxon

14.9
f
0.6-1.0
15.5-15.9

1.8
0.8
2.7
18.2-18.6

f
Tenneco

14.8
1.0
1.5
17.3

2.0
3.1
5.1
22.4
  DOE/EIA 1979 Annual Report to Congress, middle range forecast.
  American Gas Association, The Future for Gas Energy in the United States, June 1979.
c Data Resources, Inc., Energy Review, Winter 1980.
  The Pace Company Consultants and Engineers, Inc., The Pace Energy and Petrochemical Outlook to 2000, October
  1979.
e Exxon Company, U.S.A., Energy Outlook 1980-2101, December 1979.
f Tenneco Oil Company, Energy 1979-2000, June 1979.
" Included in conventional  production.
  Less than 0.5 quadrillion Btu.
Note:  Non-EIA projections converted from trillion cubic feet with 1,020 Btu per cubic foot.  Numbers may not
       add to totals because of rounding.

-------
quadrillion Btu per year, and Exxon's forecast of 14.9 quadrillion  Btu  is
16.3 percent lower than DOE's forecast.  AGA's projections were used for
the purposes of this study because their projections included estimates of
new production.  The other forecasters did not.
     The natural gas processing industry is projected to add new plants
needed to process new production.  The number of new gas processing plants
that are projected to begin operating between 1983 and 1987 are presented
in Table 9-11.  This table shows, for each year, the cumulative number of
new plants that are expected to be in operation as a result of "new"
natural gas production.  For this analysis, "new" production is considered
to be gas produced onshore after January 1, 1983 from any well  located
outside of a given radius and depth of a proven reserve and gas produced
offshore from any tract leased after January 1, 1983.  The figures  listed
under the "new production" column include the incremental new production
for that particular year plus the gas produced from the new wells of the
previous years, back to 1983.  Therefore, the cumulative number of new gas
plants expected to be in operation each of the five years was determined by
dividing the projected annual new natural gas production by the average
capacity of existing cryogenic gas plants.  It is assumed that all  new gas
plants will employ the cryogenic process method.
     In addition to new gas processing plants being constructed, it is
estimated that approximately eight existing gas plants will be modified or
reconstructed during each year during the period 1983-1987.  This estimate
approximates the number of expansions reported each year by Oil  and Gas
Journal's semi-annual report on plant expansions and equals one percent of
the total number of gas plants in the United States.
     Natural gas prices are projected by the Department of Energy to
increase because of the Natural Gas Policy Act and phased deregulation of
prices during the period from 1983 through 1987.  By 1985, almost all
categories of natural gas production will be deregulated.  Very little new
gas will  be subject to controls; most old intrastate gas will be
decontrolled and the quantity of old interstate gas that remains controlled
will decline rapidly over time.  Because of this phased deregulation,
natural gas prices are projected to increase during the period from 1983
                                   9-19

-------
        Table 9-11.  ESTIMATED NUMBER OF NEW GAS PLANTS, 1983-1987


                 New natural gas production3             Cumulative number.
Year                (trillion cubic feet)                of new gas plants
1983
1984
1985
1986
1987
1.32
2.62
3.89
4.99
6.07
40
80
120
150
180
a "New" production is considered to be gas which is (1) produced from a new
   well beyond a specified distance from an old well; (2) produced from a
   reservoir from which gas was not produced in commercial quantities prior
   to January 1, 1983, or (3) produced from an offshore tract leased on or
   after January 1, 1983.  These new production figures were developed
   based on American Gas Association's Total Energy Resource Analysis
   (TERA) Model 80-1, November 21, 1980.  The figures reflect an average
   annual decline in production of 6.2 percent, and the source for this
   decline rate is the National Petroleum Council's U.S. Energy Outlook -
   Oil and Gas Availability, 1974.

   It is assumed that all new gas plants will be cryogenic gas plants, with
   an average capacity equivalent to the average capacity of "existing
   cryogenic plants (90 MMcfd).  Therefore, the number of new gas plants
   is developed by dividing the projected annual new production by the
   average capacity of existing cryogenic gas plants.
                                   9-20

-------
through 1987.  In turn, deregulated prices are expected to boost
exploration and production activities.  The history and projections for
natural gas prices are summarized in Table 9-12.
9.2  ECONOMIC IMPACT ANALYSIS
     This section presents the expected economic impacts of alternative
emissions regulations limiting volatile organic compounds (VOC) emissions
from natural  gas/gasoline processing plants.
9.2.1  Economic Impact Assessment Methodology
     The methodology for economic impact assessment of VOC emissions
regulations on the onshore natural  gas processing industry includes the
following steps:
Step 1 - Analyze the absolute magnitude of additional  pollution control
         costs in terms of before-tax annualized cost and after-tax
         annualized costs.
Step 2 - Determine percentage product price increases required for
         regulated plants to maintain constant profitability.
Step 3 - Analyze the regulated plants' ability to pass additional  emissions
         control  costs forward to consumers or backward to suppliers.
Step 4 - Determine the financial  viability of regulated plants.
Step 5 - Analyze expected impacts of emissions regulations on  plant
         closings, curtailment of expansion,  industry output,  industry
         prices,  employment, wages, productivity, plant location,
         international trade, and possible balance of payments effects.
If it is determined in Step 1 and 2 that the  emissions control costs are
small in absolute and relative terms, then expected economic impacts on
output, prices, employment, profitability, etc., will  be small and further
expenditure of resources for detailed impact  analyses justifiably  can  be
foregone.  Such might be the case where annualized pollution control costs
are much less than EPA's trigger criteria for regulatory analysis, i.e.,
$100 million additional (before tax) annualized cost or a price increase of
5 percent required for industry members to maintain pre-control levels of
profitability.
                                   9-21

-------
 Table  9-12.   NATURAL  GAS  PRICES:   HISTORY AND PROJECTIONS FOR 1965-1995

                  (1979 Dollars  per Thousand Cubic Feet)
History3

Price
1965
1973
1978
Projections
1985
1990
1995
Domestic Wellhead Prices






Old Interstate
New Interstate
Old Intrastate
New Intrastate
North Alaska
Average
NA
NA
NA
NA
__
0.36
NA
NA
NA
NA
__
0.35
0




1
.93
NA
NA
NA
__
.02
1.
4.
3.
4.

3.
01
48
29
72
__
26
1
4
3
4
1
3
.18
.04
.32
.28
.85
.42
1.
4.
3.
4.
1-.
4.
39
59
78
82
85
17
Synthetic Gas Prices


High-Btu Coal Gas
Medium-Btu Coal Gas
--
--
__
--


--
--
4.
3.
76
70
4
4
.19
.50
4.
5.
71
44
Imported Gas Prices



Canadian Gas
Mexican Gas
Liquefied Natural Gas
NA
NA
--
NA
NA
--
2

1
.41
NA
.54
6.
6.
5.
21
21
91
6
6
6
.92
.92
.42
8.
8.
7.
51
51
70
Delivered Prices







Al
a


Residential
Commercial
Raw Material
Large boilers
Industrial , Other
Refineries
Electric Utilities
ternative Fuel Cost
Source for historical data i
Congress, 1979, and the foil
Production and Consumption,
2.34
1.60
NA
NA
0.78
NA
0.89
__
s Volume
owing EIA
1978; Uni
2.04
1.46
NA
NA
0.77
NA
0.63
--
2 of the
Energy
2
2


1

1

.77
.38
NA
NA
.61
NA
.72
--
EIA
Data
ted States
Natural Gas, 1978; and, Natural and Synthetic
5.
4.
4.
5.
4.
4.
4.
6.
Annual
41
88
28
24
34
55
74
23
5
5
4
4
4
4
4
6
Report
Reports:
Imports
Gas,
1978.
and

.74
.22
.48
.54
.51
.43
.42
.94
to
Natural
Exports


6.
5.
5.
5.
5.
5.

8.

Gas
of

45
93
21
26
22
13
--
29




c Major fuel-burning installations.

  Notes:   NA = Not available.
          — = Not applicable.

  Source:   DOE/EIA Annual  Report to  Congress,  1980,  Vol.  13,  pg.  90.
                                   9-22

-------
     If it is determined in Steps 1 and 2 that the direct emissions control
costs are significant in either absolute or relative cost to the industry,
then the focus of the analysis turns toward analyzing the ability of
regulated plants to pass additional costs forward to consumers or backward
to suppliers.  The analysis in Step 3 is explained in the context of the
industry's structure, conduct and performance as described in Section 9.1.
Specifically, the level  of competition within the industry and the
elasticity of demand to the regulated plants is important as well as the
elasticity of aggregate product demand.
     If it is determined that the industry is able to pass on all
additional costs, then Step 4 can be omitted since the financial  viability
of regulated plants would not be jeopardized.  Important impacts  may occur
in supplier or consumer sectors and these should be analyzed if expected
price impacts are significant to these sectors.  If, on the other hand,  it
is determined in Step 3 that the industry is unable to pass on all
additional emissions control costs, then Step 4 is needed to determine the
economic viability of regulated and impacted plants.
     If needed, a net present value approach is used in Step 4 to determine
the regulated plants' financial viability.   Specifically, after-tax  net
annualized cost of emissions control is estimated and used to calculate
required percentage price increases needed for regulated plants to  maintain
baseline net present values for each regulatory alternative.   If  the
required price increase for some regulatory alternative exceeds the  amount
which can be successfully passed on or absorbed by the plant then it is
determined that the plant is non-viable for that regulatory alternative.
     Based on the findings in Steps 1 through 4 and the industry  profile in
Section 9.1, additional  analyses of expected economic impacts are
completed.  Expected industry price and output impacts are estimated
simultaneously.  Then related impacts on employment, productivity,
international trade, etc. are brought into focus in Step 5.
     Before-tax annualized costs (BTAC) and after-tax annualized  costs
(ATAC) of emissions controls are computed in Step 1 using the following
equations:
                                   9-23

-------
      BTAC = I  CRF + 0&MQ                                             (1)

      ATAC = IQ CRF TAXF + (1-t) 0&MQ                                  (2)
where,
        I  = initial base year investment
       OM  = annual O&M cost less applicable by-product credits
       CRF =   ^   ;  , the capital recovery factor

         r = the real cost of capital

         n = economic life of the asset, i.e. the capital recovery period
             (variable by asset)

      TAXF = 1-itc - t PVDEP

       itc = investment tax credit rate
         t = corporate income tax rate
     PVDEP = present value of annual depreciation factors per $1
             of investment, i.e.
               Y    DEP
     PVDEP =   £
             y = 1 (l+d)y
         Y = length of the depreciation period, 3, 5, 10 or 15 years

         d = nominal discount rate, and

      DEP  = annual depreciation factors based on the most advantageous
             depreciation methods for the firm, either (1) rapid amortiza-
             tion of pollution control investments or (2) accelerated cost
             recovery as allowed by the 1981 Economy Recovery Act.
                                   9-24

-------
     Required real price increases needed by model gas processing  plants  to
maintain baseline profitability (net present value) are computed according
to Equation 3.

     Inflation and the weighted nominal cost of capital are projected to be
8 and 10 percent, respectively.  This inflation rate is consistent with
recent estimates of large econometric models of the U.S. economy. 2J  Ten
percent nominal weighted natural gas industry cost of capital was estimated
using forecasted 1981-1985 composite natural gas industry stock price
earnings ratios of 7 to 8, a 45 percent debt ratio, 47 percent marginal
corporate income tax rates from Value Line Investment Survey, and 13
percent nominal pre-tax interest rate on new debt for domestic corporations
based on Value Line Investment Survey estimates for 1981-1985.
9.2.2  Economic Impact of VOC NSPS Regulatory Alternatives - Natural
       Gas/Gasoline Processing Plants
     Additional costs for natural gas processing plants to comply with VOC
NSPS regulatory alternatives are expected to be small  in both absolute and
relative terms.  Economic impacts on individual plants and the industry
will be slight.  Total additional before-tax annualized costs of controls
in 1987, the fifth year of controls, are estimated to be as follows:

                                         Total  additional before-tax
      Regulatory alternatives, VOC           annualized cost, 1987
                                            (thousand 1980 dollars)
                    I                                    0
                   II                               -1,003
                  III                                 -424
                   IV                                5,989
II  The assumption ANPV = 0 requires that (1-t) AP Q - ATAC = 0;
    therefore, AP = ATAC/(l-t)Q.  P = the real price increase required to
    amortize at the cost of capital the additional pollution control
    investment and operating costs over constant throughput Q.
2J  Data Resources, Inc. Trend!onq 2005 Forecasts.  September, 1980.
                                   9-25

-------
These estimates are derived at the bottom of Table 9-13 which displays
aggregate or total before-tax annualized costs of regulatory alternatives
II, III, and IV by year.  The projected number of new gas plants during  the
period 1983-1987 is 180 mid-size plants.  The total before-tax annualized
cost for these new plants in 1987, the fifth year of the regulation,  is
-$656,000 for regulatory alternative II, -$160,000 for regulatory
alternative III and $3,886,000 for regulatory alternative IV.
     The projected number of modified and reconstructed plants during the
period 1983-1987 is 10 small, 15 mid-size and 15 large plants.  The total
before-tax annualized cost for these modified and reconstructed plants in
1987 is -$347,000 for regulatory alternative II, -$264,000 for regulatory
alternative III and $2.1 million for regulatory alternative IV-  The
combined total of new and modified and reconstructed plants constructed
during the period 1983-1987 is 10 small plants, 195 mid-size plants, and 15
large plants.  Total before-tax annualized costs for these plants in 1987
is estimated to be -$1.0 million for regulatory alternative II, -$424,000
for regulatory alternative III and nearly $6.0 million for regulatory
alternative IV.
     Before-tax net annualized costs for individual model gas plants and
regulatory alternatives I through IV are shown in Table 9-14.  The new
model plant, producing 90 million cubic feet per day, has before-tax
annualized costs for regulatory alternatives II, III, IV totalling -$3,280,
-$800 and $19,430 respectively.  The smallest modified and reconstructed
model plant has before-tax net annualized costs of $2,240, $2,850 and
$13,690 for alternatives II, III and IV, respectively.  For the modified
and reconstructed model plant B costs are -$3,280, -$800, and $32,760 while
model plant C has costs of -$21,360, -$17,060 and $98,340 for regulatory
alternatives II,  III and IV, respectively.  Negative before-tax net
annualized costs stem from situations where recovery credits outweigh the
annualized investment and operating costs for emissions control.
     After-tax net annualized costs of regulatory alternatives are shown in
Table 9-15.  For the new model plant, the after-tax net annualized cost  for
alternatives II,  III and IV are -$1,590, -$30 and $10,220, respectively.
                                   9-26

-------
               Table  9-13.   ONSHORE  NATURAL  GAS  PROCESSING,  TOTAL  AND  CUMULATIVE  BEFORE-TAX  NET ANNUALIZED
                                  COST  OF VOC NSPS  REGULATORY  ALTERNATIVES  1983-1987
IX)
Category
of Facility Year

New







1983
1984
1985
1986
1987
Projected Cumulative
Number of Gas Plants a/
A


0
0
0
0
0
B


40
80
120
150
180
C


0
0
0
0
0
Regulatory Alternative
II
	 	 Thni


-131.2
-262.4
-393.6
-524.8
-656.0
III
isands of 1980 [

-32.0
-64.0
-96.0
-128.0
-160.0
IV
"\f\~\ 1 AV»C — — — — ..


777.2
1,554.4
2,331.6
3,108.8
3,886.0
Modified/ Reconstructed





Total





1983
1984
1985
1986
1987
2
4
6
8
10
3
6
9
12
15
3
6
9
12
15
-69.4
-138.8
-208.2
-277.6
-347.0
-52.8
-105.6
-158.4
-211.2
-264.0
420.7
841.4
1,262.1
1,682.8
2,103.5
New, Modified & Reconstructed
1983
1984
1985
1986
1987
2
4
6
8
10
43
86
129
162
195
3
6
9
12
15
-200.6
-401.2
-601.8
-802.4
-1,003.0
-84.8
-169.6
-254.4
-339.2
-424.0
1,197.9
2,395.8
3,593.7
4,791.6
5,989.5
    a/  Plants A, B and C  ave.  10,  30  and  100  vessels,  respectively.

-------
                 Table 9-14.  ONSHORE NATURAL GAS  PROCESSING MODEL  PLANTS'  BEFORE-TAX  NET ANNUALIZED
                                 COST OF VOC NSPS  REGULATORY ALTERNATIVES  PER PLANT
I
ro
CO



Model Size
plant No. vessels MMcfd


New 30 90
Modified and
Reconstructed
A 10 30
B 30 90
C 100 250

I
Baseline
control
level


0


0
0
0
Regulatory
II



ThniicAnHc f\~i

-3.28


2.24
-3.28
-21.36
alternative
III



F 1 QQPl HA 1 1 A y*c — — — .

-.80


2.85
-0.80
-17.06

IV





19.43


13.69
32.76
98.34

-------
I
IN}
UD
                  Table 9-15.  ONSHORE NATURAL GAS PROCESSING MODEL  PLANTS'  AFTER-TAX  NET ANNUALIZED
                                  COST OF VOC NSPS REGULATORY ALTERNATIVES  PER  PLANT



Model
plant


New
Modified and
Reconstructed
A
B
C



Size
No. vessels' MMcfd


30 90


10 30
30 90
100 250

I
Baseline
control
level


0


0
0
0
Regulatory
II



~rt~kOiic£knsic t
	 1 nOUSailUb i
-1.59


1.27
-1.59
-10.86
alternative
III



if IQRfl Hnllavc
)T iyou uuiiaib 	
-.30


1.56
-.30
-8.64

IV





10.22


7.57
17.32
51.28

-------
For modified and reconstructed model plant A, these costs are $1,270,
$1,560, and $7,570, respectively; -$1,590, -$30, and $17,320, respectively,
for model plant B; and -$10,860, -$8,640 and $51,280 for model plant C.
     Required price increases for affected gas plants to maintain baseline
profitability (net present value) are very small as estimated below.  For
purposes of this order of magnitude calculation, gas throughput was assumed
to be 30, 90, and 250 MMcfd for plants A, B, and C, respectively.  Gas
throughout for new cryogenic plants was assumed to be 90 MMcfd as explained
in Table 9-11 footnote b.
             Required price increases for VOC NSPS, 1980 $/Mcf
                  New                   Modified and Reconstructed
Regulatory
alternative
II
III
IV
Plant B
(90 MMcfd)
-.00013
-.00002
-.00085
Plant A
(30 MMcfd)
.00032
.00039
.00190
Plant B
(90 MMcfd)
-.00013
-.00002
.00143
Plant C
(250 MMcfd)
-.00033
-.00026
.00155
     Given the inelasticity of retail demand for natural gas and gas
liquids products, it is expected that gas processors will pass a large
portion, if not all, of the incremental emissions control costs forward to
pipelines, gas utilities and eventually to the ultimate consumers of
natural gas and natural gas liquids.  The price impacts will be slight
relative to current product prices, less than 0.5 percent, regardless of
regulatory alternative.  No plant closures or curtailments are expected due
to VOC NSPS.  Effects on industry profitability, output, growth,
employment, productivity, and international  trade will be negligible or
zero due to VOC NSPS on natural gas plants.
     This concludes the analysis of direct economic impacts of VOC NSPS on
the Natural Gas Processing Industry.  Control costs for VOC NSPS and
associated economic impacts are expected to be negligible for individual
plants and particularly for the composite natural gas processing industry.
9.3  POTENTIAL SOCIOECONOMIC AND INFLATIONARY IMPACTS
     This section discusses the potential social disruption and
inflationary  impacts associated with the VOC regulatory alternatives.
     Data presented in Section 9.2 above indicated that additional costs
for control of VOC emissions from natural gas processing plants are

                                   9-30

-------
expected to be small on an absolute and relative basis for all four
regulatory alternatives considered.  No impact is expected on plant
location or structure of the natural gas processing industry.  No job
losses are expected.
     Additional  costs for VOC emissions controls on new, remodeled and
reconstructed gas plants are not expected to have significant inflationary
impacts because  the annualized control  costs per unit of production are
small, i.e., less than 0.5 percent of sales for all model  plants and
regulatory alternatives.  It is expected, however,  that gas processors will
succeed in passing a large share of the added costs forward into product
markets for natural gas liquids.  The direct effect on price will  be
negligible, especially when compared to total industry sales, including
existing (exempt) plants.  No productivity, plant location, or balance of
payments effects are expected due to any of the VOC regulatory
alternatives.
                                   9-31

-------
9.4  REFERENCES FOR CHAPTER 9

 1.  Oil & Gas Journal, January 28, 1980, p. 81
 2.  U.S. Department of Energy, Energy Information Administration.  Annual
     Report to Congress-1979.  Volume Two (of Three):  Data,  and,
     U.S. Department of the Interior, U.S. Geological Survey-Conservation
     Division, Outer Continental Shelf Statistics, June 1980.
 3.  U.S. Department of Energy, Energy Information Administration.  Annual
     Report to Congress-1979.  Volume Two (of Three):  Data.
 4   American Gas Association, Department of Statistics, Gas Facts - 1979
     Data.
 5.  American Gas Association, Gas Supply and Statistics - Total Energy
     Resource Analysis Model (TERA) 80-1, Appendix A, Figure A-2, p. 21.
 6.  U.S. Department of Energy, Energy Information Administration.  Annual
     Report to Congress-1979.  Volume Three (of Three):  Projections.
 7.  U.S. Department of Energy, Energy Information Administration. Annual
     Report to Congress-1979.  Volume Three (of Three):  Projections.
                                   0-32

-------
APPENDIX A - EVOLUTION OF THE BACKGROUND INFORMATION DOCUMENT

-------
A.I  LITERATURE REVIEW

       Date
          Source
April 1958
1958

August 1969


October 11, 1971


1972



1972


1973


1974


1975


1976



June 1977



December 1977

June 1978




June 25-30, 1978
Joint District, Federal
and State Project for
the Evaluation of
Refinery Emissions,
Report Number 6

McGraw-Hill Co. Inc.

Chemical Engineering
Progress

Chemical Engineering/
Deskbook Issue

E.I. duPont de Nemours
and Co.
University of Texas
at Austin

McGraw-Hill Co.
University of Texas
at Austin

Van Nostrand Reinhold
Company

American Petroleum
Institute
EPA-450/3-77-026



Hydrocarbon Processing

KVB, Inc.  KVB 5804-714
EPA (Paper presented
at 71st APCA meeting)
      Data or Information

Emissions of Hydrocarbons to
the Atmosphere from Seals on
Pumps and Compressors
Petroleum Refinery Engineering

Preventing Flange Fires
Valve Installation, Operation
and Maintenance

A Tracer Technique for Determining
Efficiency of an Elevated
Flare

Field Handling of Natural Gas,
Third Edition

Chemical Engineers' Handbook,
Fifth Edition

Plant Processing of Natural Gas
Lyons'  Encyclopedia of Valves
Primer of Oil and Gas Production,
Book 1 of the Vocational
Training Series

Atmospheric Emissions from
Offshore Oil and Gas Development
and Production

Compressor Seal Fundamentals

Control of Hydrocarbon Emissions
from Stationary Sources in the
California South Coast Air
Basin, Volume I

Detection of Volatile Organic
Compounds from Equipment Leaks
                                  A-2

-------
       Date

June 1978



August 1978



February 1979



February 1979




July 16, 1979


October 1979


1979


February 1980



March 1980



March 1980



March 1980


April 1980



June 22-27, 1980



July 14, 1980
          Source

EPA-450/2-78-036



EPA-450/3-78-047



EPA-600/2-79-044



Hydroscience




The Oil and Gas Journal


API Publication 4311
University of Texas
at Austin

K. D. Siege!, Ph.D.
Dissertation, Univ. of
Karlsruhe (German)

American Petroleum
Institute
American Petroleum
Institute
EPA-340/1-80-010
EPA-600/2-80-075
Air Pollution Control
Association Proceedings
Oil and Gas Journal
      Data or Information

Control of Volatile Organic
Compound Leaks from Petroleum
Refinery Equipment

Evaluation of Emissions from
Onshore Drilling, Producing,
and Storing of Oil and Gas

Emission Factors and Frequency
of Leak Occurrence for Fittings
in Refinery Process Units

Emissions Control Options for
the Synthetic Organic Chemicals
Manufacturing Industry, Fugitive
Emissions Report

Advantages Found in On-Line
Leak Sealing

NO  Emissions from Petroleum
Inaustry Operations

A Primer of Oil-Well  Drilling,
Fourth Edition

Degree of Conversion of Flare
Gas in Refinery High Flares
Volume I - Fugitive Hydrocarbon
Emissions from Petroleum
Production Operations

Volume II - Fugitive Hydrocarbon
Emissions from Petroleum
Production Operations

Summary of Available Portable
VOC Detection Instruments

Assessment of Atmospheric
Emissions from Petroleum
Refining

A Fugitive Emission Study in a
Petrochemical Manufacturing
Unit

Worldwide Gas Processing

-------
        Date
          Source
      Data or Information
February 17, 1981   EPA:IERL (Report)
February 1981


April 1981




December 1981
1981
(no date)
EPA Report, Contract
No. 68-02-3542

Preliminary Draft
EPA:ESED
EPA:ESED
EPA Contract No.
68-02-2682
State of New Mexico,
Environmental
Improvement Division
                         Evaluation of Maintenance for
                         Fugitive VOC Emissions Control
Assessment of API/Rockwell
Plant Fugitive Emissions
Gas
VOC Fugitive Emissions in
Petroleum Refining Industry -
Background Information for
Proposed Standards

Control of Volatile Organic
Compound Equipment Leaks from
Natural Gas/Gasoline Processing
Plants

Development of Flare Emission
Measurement Methodology, Draft
Report

Ambient Air Quality Standards
and Air Quality Control
Regulations
A.2  PLANT VISITS

        Date

December 18, 1979
         Company

Exxon Company, U.S.A.
Jay Field, Florida
December 19, 1979   Phillips Petroleum
                    Chatham, Mississippi
January 1980
July 14, 1980
Exxon Company
       Plant/Information

Blackjack Creek facility/gained
familiarity with process
equipment and operating conditions

Chatham facility/gained famil-
iarity with process equipment
and operating conditions

Plant visits to various tank
battery sites in the West
Texas oil and gas field to
gain knowledge of processing
equipment

Tank battery in Kingsville,
Texas/gained familiarity with
gas and oil production processes
and facilities
                                  A-4

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        Date
July 16, 1980
July 18, 1980
July 24, 1980
         Company

Phillips Petroleum Co.




Shell Oil Company




Phillips Petroleum Co.
       Plant/Information

Roosevelt County, New Mexico/
acquired firsthand familiarity
with gas and oil production
processes and facilities

State!ine Production Unit in
Sidney, Montana/acquired
firsthand familiarity with gas
and oil production

Canadian County, Oklahoma/gained
information on gas processing
facilities
A.3  EMISSION SOURCE TESTING

        Date
          Source
October 6-9, 1980   Houston Oil & Minerals
                    Smith Point gas plant,
                    Chambers County, Texas
October 14-16,
1980
February 9-27,
1981
March 2-13, 1981
Amoco Production Co.
Hastings gas plant,
Brazoria County, Texas

Texaco, Inc.,  Paradis
Plant, Paradis,
Louisiana

Gulf Oil Company,
Venice Plant,  Venice,
Louisiana
      Data or Information
                         Fugitive VOC emissions testing
Fugitive VOC emissions testing
Fugitive VOC emissions testing
Fugitive VOC emissions testing
A.4  MEETINGS WITH INDUSTRY

        Date            Attendees

November 30, 1979   API and TRW
December 7, 1979    API and TRW

July 21 & 22,       EPA,  API and TRW
1980
                                      Topic

                         Meeting to discuss onshore
                         production and to solicit the
                         aid of API in gathering field
                         data

                         Introductory Meeting

                         Meeting concerning NSPS develop-
                         ment for the Onshore Production
                         Industry

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        Date
    At-tendees
             Topic
April 29 & 30,
1981

May 1, 1981
NAPCTAC


EPA, API and TRW
January 28, 1982    EPA, API and TRW
Meeting concerning natural
gas/gasoline processing plants

Meeting concerning model
plants

Meeting concerning fugitive
VOC emission factor development
for gas plants
A.5  REVIEW PROCESS

        Date

January 28, 1980


March 19, 1980

March 1981
April 1981
April 1981
June 1981
August 1981
September 1981
     Company

       TRW


       TRW

       TRW
       TRW
       TRW
       TRW
       TRW
       TRW
      Data or Information

Preliminary draft Source
Category Survey Report

Source Category Survey Report

Preliminary draft CTG document,
Control of Volatile Organic
Compound Equipment Leaks from
Natural Gas/Gasoline Processing
Plants

Preliminary Draft, VOC Fugitive
Emissions in Petroleum Refining
Industry Background Information
for Proposed Standards

Model plant package mailed to
industry representatives for
comment

Draft CTG Document, Control of
Volatile Organic Compound
Equipment Leaks from Natural
Gas/Gasoline Processing Plants
(sent to OMB for review)

Draft CTG Document, Control of
Volatile Organic Compound
Equipment Leaks from Natural
Gas/Gasoline Processing Plants

Drafts of Chapters 3 through 6
sent out for industry review
and comments
                                  A-6

-------
        Date

December 1981
Attendees

   TRW
Draft CTG Document, Control of
Volatile Organic Compound
Equipment Leaks from Natural
Gas/Gasoline Processing Plants
                                 A-7

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APPENDIX B - INDEX TO ENVIRONMENTAL IMPACT CONSIDERATIONS

-------
           APPENDIX B.  INDEX TO ENVIRONMENTAL CONSIDERATIONS

     This appendix consists of a reference system which is cross-indexed
with the October 21, 1974, Federal  Register (36 CFR 37419) containing
the Agency guidelines for the preparation of Environmental Impact
Statements.   This index can be used to identify sections of the document
which contain data and information germane to any portion of the Federal
Register guidelines.
                                B-2

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                                                        APPENDIX B

                                         INDEX TO ENVIRONMENTAL IMPACT CONSIDERATIONS
CD

CO
        Agency Guidelines  for  Preparing  Regulatory
          Action  Environmental  Impact  Statements
        	(39 FR  37419)	

        (1)   Background and summary of regulatory
             alternatives

             Statutory basis for  proposing  standards
             Affected industry
             Affected  sources
            Availability  of  control technology
       (2)  Environmental, energy, and economic
            impacts of regulatory alternatives

            Environmental  impacts
Location Within The Background Information Document

The regulatory alternatives are summarized in
Chapter 1, Section 1.1, pages 1-1 through 1-2.

The statutory basis for the proposed standards is
summarized in Chapter 2, Section 2.1, pages 2-1
through 2-4.

A discussion of the industry affected by the
regulatory alternatives is presented in Chapter 3,
Section 3.1,  page 3-1.   Details of the "business/
economic" nature of the industry are presented in
Chapter 9, Section 9.1, pages 9-1 through 9-21.

A description of the sources affected by the
regulatory alternatives is presented in Chapter 3,
Section 3.2,  pages 3-1 through 3-7.

A discussion of available emission control
techniques is presented in Chapter 4, Sections 4.2
and 4.3, pages 4-1 through 4-17.

Various regulatory alternatives are discussed in
Chapter 6, Section 6.3, pages 6-2 through 6-9.

The environmental impacts of the various regulatory
alternatives are presented in Chapter 7, Sections 7.1,
7.2, 7.3, and 7.4, pages 7-1 through 7-9.

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Agency Guidelines for Preparing Regulatory
  Action Environmental  Impact Statements
	(39 FR 37419)	

     Energy impacts
     Cost impacts
     Economic impacts
Location Within The Background Information Document

The energy impacts of the various regulatory
alternatives are discussed in Chapter 7, Section 7.5,
pages 7-9 through 7-11.

Cost impacts of the various regulatory alternatives
are discussed in Chapter 8, Section 8.1, pages 8-1
through 8-28.

The economic impacts of  the various regulatory
alternatives are presented in Chapter 9, Sections 9.2
and 9.3, pages 9-21 through 9-31.

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APPENDIX C.  EMISSION SOURCE TEST DATA

-------
                 APPENDIX C.  EMISSION SOURCE TEST DATA

     Fugitive emission test data have been collected at six natural
gas/gasoline processing plants (see Table C-l) by EPA and industry.  Two
gas plants were tested under contract to the American Petroleum
Institute (API), and four gas plants were tested under contract to EPA.
All six gas plants were screened for fugitive emissions using either
portable hydrocarbon detection instruments, soap solution, or both.
Instrument screening (using EPA's proposed Method 21, described in
Appendix D) was performed at all four of the EPA-tested plants (Plants 3,
4, 5, and 6).   The instruments were calibrated with methane.   Soap
screening (using the method described in Reference 1) was performed at
the two API-tested plants and at three of the EPA-tested plants.   Selected
components were measured for mass emissions at both of the API-tested
plants (Plants 1 and 2) and at two of the EPA-tested plants (Plants 5
and 6).  These mass emission measurements were used in development of
emission factors for gas plant fugitives, which are presented in Table 3-1.
C.I  PLANT DESCRIPTION AND TEST RESULTS
     One API-tested gas plant was of the refrigerated absorption type,
and the other was a cryogenic plant.  Descriptions and schematics of the
plants are provided in Reference 1.   Of the four EPA-tested plants, the
first tested was a solid bed adsorption type (Reference 2).   Natural gas
liquids are removed by adsorption onto silica gel, then stripped from
the bed with hot regeneration gas and condensed out for sales.  There
were three adsorption units, of which only one was operating.   This unit
had a capacity of 60 MMSCFD (million standard cubic feet per day), and
was operating between 33 and 55 MMSCFD during the testing period.  The
second unit was shut down and depressurized, and therefore not tested.
The third unit was also not operating, but it was under natural gas
pressure and was tested.
                                 C-2

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          Table C-l.   GAS PLANTS TESTED FOR FUGITIVE EMISSIONS'
Plant
 No.
   Data
collection
  sponsor
      Plant process
          type
Principal screening
   method(s) used
  1

  2

  3

  4

  5

  6
API

API

EPA

EPA

EPA

EPA
Refrigerated Absorption

Cryogenic

Adsorption

Cryogenic

Refrigerated Absorption

Refrigerated Absorption
Soaping

Soaping

Instrument, Soaping

Instrument, Soaping

Instrument, Soaping

Instrument
Reference 6.

 Less than 50  components were soap screened  at plant  No.  6.
                                  03

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     The second EPA-tested plant was of the cryogenic type (Reference 3).
Feed gas to the plant is compressed and then chilled.  Natural gas
liquids are condensed out and split into two streams:  ethane/propane
and butane-plus.   The cryogenic plant was operating at its rated capacity
of 30 MMSCFD.
     The third EPA-tested plant was of the refrigerated absorption type
(Reference 4).  There were three absorption systems for removal of
natural gas liquids.   The liquids were combined and sent to a single
fractionation train.   The fractionation train separated the liquids into
ethane, propane,  iso-butane, butane, and debutanized natural  gasoline.
Testing was performed on the fractionation train and on the largest
absorption system.   The absorption system that was tested was operating
at 450 MMSCFD, near its capacity of 500 MMSCFD.
     The fourth EPA-tested plant was also of the refrigerated absorption
type (Reference 5).  There were two parallel absorption trains, and one
fractionation train.   Natural gas liquids were fractionated into
ethane/propane, propane, iso-butane, butane, and debutanized  natural
gasoline streams.   The plant was operating at approximately 450 MMSCFD,
about half of its rated capacity of 800 MMSCFD.
     A summary of the instrument screening data collected at  the four
EPA-tested plants is presented in Table C-2.  A summary of the soap
screening data collected at the two API-tested plants and at  all of the
EPA-tested plants is presented in Table C-3.  (Only a very small amount
of soap screening data were collected at Plant 6).   The instrument
screening data are tabulated for each plant, showing the number of each
type of component tested and the percent emitting.   The soap  screening
data are not tabulated for each plant but are instead summarized by soap
score.  A complete tabulation of the soap screening data by plant and by
soap score is provided in Reference 6.
                                 C-4

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                               Table C-2.   INSTRUMENT  SCREENING DATA FOR ERA-TESTED GAS PLANTS6
I
en

Valves
Plant
No.
3
4
5
6
Total
No.
Tested
331
506
1,804
1,038
3,679
Percent
> 10, 000 ppmv
23.6
16.8
12.1
21.5
16.4
Relief valves
No.
Tested
10
7
60
3
80
Percent
> 10, 000 ppmv
90.0
14.3
5.0
33.3
17.5
Open-ended lines
No.
Tested
45
65
472
139
721
Percent
> 10, 000 ppmv
15.6
18.5
11.7
8.6
11.9
Compressor seals
No.
Tested
0
4
30
2
36
Percent
> 10, 000 ppmv
0.0
100
46.7
50.0
52.8
Pump seals
No.
Tested
1
9
51
40
101
Percent
> 10, 000 ppmv
0.0
44.4
33.3
22.5
29.7
Flanges and
connections
No.
Tested
223
281
768
506
1,778
Percent
> 10 ,000 ppmv
5.4
2.1
3.6
2.0
3.1
    Reference 6.

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             Table C-3.   SOAP  SCREENING DATA  FOR API-TESTED AND EPA-TESTED GAS PLANTS'
o
1
en






Valves
Score
0
1
2
3
4
Total
Number
4,483
322
468
426
274
5,973
% of
Total
75.1
5.4
7.8
7.1
4.6

Relief
Number
123
4
2
2
3
134

valves
% of
Total
91.8
3.0
1.5
1.5
2.2


Open-ended lines
Number
945
63
83
59
43
1,193
% of
Total
79.2
5.3
7.0
4.9
3.6


Compressor seals
Number
8
1
2
7
10
28
% of
Total
28.6
3.6
7.1
25.0
35.7

Pump
Number
14
0
1
0
3
18

seals
% of
Total
77.8
0.0
5.6
0.0
16.7


Flanges and
connections
Number
17,982
706
454
190
65
19,397
% of
Total
92.7
3.6
2.3
1.0
0.3
Includes data from two- API-tested plants and four EPA-tested plants.  Reference 6.

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C.2  REFERENCES FOR APPENDIX C


1.    Eaton, W.  S. ,  et al., Fugitive Hydrocarbon Emissions  from  Petroleum
     Production Operations.  API Publication No. 4322.  March 1980.

2.    Harris, G. E.   Fugitive VOC Testing at Houston Oil and Minerals
     Smith Point Plant.   U.S. EPA, ESED/EMB Report No. 80-OSP-l.
     October 1981.

3.    Harris, G. E.   Fugitive VOC Testing at the Amoco Hastings  Gas
     Plant.  U.S.  EPA, ESED/EMB Report No. 80-OSP-2.  July 1981.

4.    Harris, G. E.   Fugitive VOC Testing at the Texaco Paradis  Gas
     Plant, Volume I and II.   U.S. EPA, ESED/EMB Report No. 80-OSP-7.
     July 1981.

5.    Harris, G. E.   Fugitive Test Report at the Gulf Venice Gas Plant,
     Volume I and II.   U.S. EPA, ESED/EMB Report No. 80-OSP-8.
     September 1981.

6.    DuBose, D. A., J. I.  Steinmetz, and G.  E.  Harris.  Emission Factors
     and Leak Frequencies for Fittings in Gas Plant.  Draft Final Report.
     U.S. EPA,  ESED/EMB Report No. 80-FOL-l.   September 1981.
                                 C-7

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APPENDIX D.   EMISSION MEASUREMENT AND CONTINUOUS MONITORING

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                 APPENDIX D:  EMISSION MEASUREMENT AND
                         CONTINUOUS MONITORING
D.I  Emission Measurement Methods
D.I.I  General  Background
     A test method was not available when EPA began the development of
control technique guidelines, new source performance standards, and
hazardous pollutant standards for fugitive volatile organic compounds
from industrial categories such as petroleum refineries, synthetic
organic chemical manufacturing, and other types of processes that
handle organic  materials.
     During the development and selection of a test method, EPA reviewed
the available methods for measurement of fugitive leaks with emphasis
on procedures that would provide data on emission rates from each source.
To measure emission rates, each individual  piece of equipment must be
enclosed in a temporary cover for emission containment.  After containment,
the leak rate can be determined using concentration change  and flow
                                                              (1  2)
measurements.  This procedure has been used in several  studiesv  ' '  and
has been demonstrated to be a feasible method for research  purposes.   It
was not selected for this study because direct measurement  of emission
rates from leaks is a time-consuming and expensive procedure, and is  not
feasible or practical for routine testing.
     Procedures that yield qualitative or semi-quantitative indications
of leak rates were then reviewed.  There are essentially two alternatives:
leak detection by spraying each component leak source with  a soap solution
and observing whether or not bubbles were formed; and, the  use of a
portable analyzer to survey for the presence of increased organic compound
concentration  in the vicinity of a leak source.  Visual, audible, or
                                  D-2

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olefactory inspections are too subjective to be used as indicators of
leakage in these applications.  The use of a portable analyzer was
selected as a basis for the method because it would  have been difficult
to establish a leak definition based on bubble formation rates.   Also,
the temperature of the component,  physical  configuration,  and relative
movement of parts often interfere  with bubble formation.
     Once the basic detection principle was selected, it was  then
necessary to define the procedures for use of the portable analyzer.
Prior to performance of the first  field test, a procedure was reported
                                                                (3)
that conducted surveys at a distance-of 5 cm from the components^ '.  This
                                                                   (A)
information was used to formulate  the test plan for  initial testing^  '.
In addition, measurements were made at distances of  25 cm and 40  cm on
three perpendicular lines around individual sources.   Of the  three
distances, the most repeatable indicator of the presence of a leak was  a
measurement at 5 cm, with a leak definition concentration  of  100  or
1000 ppmv.  The localized meteorological conditions  affected  dispersion
significantly at greater distances.  Also, it was more difficult  to
define a leak at greater distances because of the small  changes from
ambient concentrations observed.  Surveys were conducted at 5 cm  from
the source during the next three facility tests.
     The procedure was distributed for comment in a  draft control
                             fc]
techniques guideline document^ '.   Many commentors felt that  a measure-
ment distance of 5 cm could not be accurately repeated during screening
tests.  Since the concentration profile is rapidly changing between 0 and
about 10 cm from the source, a small variance from 5 cm could significantly
affect the concentration measurement.  In response to these comments, the
procedures were changed so that measurements were made at the surface of
                                 D-3

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the interface, or essentially 0 cm.  This change required that the leak
definition level be increased.  Additional testing at two refineries and
three chemical plants was performed by measuring volatile organic concen-
trations at the interface surface.
     A complication that this change introduces is that a small  mass
emission rate leak ("pin-hole leak") can be totally captured by the
instrument and a high concentration result will be obtained.  This
has occurred occasionally in EPA tests, and a solution to this problem
has not been found.
     The calibration basis for the analyzer was evaluated.   It was
recognized that there are a number of potential vapor stream components
and compositions that can be expected.  Since all  analyzer  types do not
respond equally to different compounds, it was necessary to establish a
reference calibration material.  Based on the expected compounds and the
limited information available on instrument response factors, hexane was
chosen as the reference calibration gas for EPA test programs.  At the
5 cm measurement distance, calibrations were conducted at approximately
100 or 1000 ppmv levels.  After the measurement distance was changed,
calibrations at 10,000 ppmv levels were required.   Commentors pointed
out that hexane standards at this concentration were not readily available
commercially.  Consequently, modifications were incorporated to allow
alternate standard preparation procedures or alternate calibration gases
in the test method recommended in the Control Techniques Guideline Document
for Petroleum Refinery Fugitive Emissions.
     Since that time, studies have been completed that measured the response
factors for several instrument types.  ' ' '  The results of these studies
show that the response factors for methane and hexane are similar
                                 D-4

-------
 enough for the purposes of this method to be used interchangeably.  Therefore,
 in later NSPS, the calibration materials were hexane or. methane.
     The alternative of specifying a different calibration material for
 each type stream and normalization factors for each instrument type was
 not intensively investigated.  There are at least four instrument types
 available that might be used in this procedure, and there are a large
 number of potential stream compositions possible.  The amount of prior
 knowledge necessary to develop and subsequently use such  factors would
make the interpretation of results prohibitively complicated.  Additionally,
 based on EPA test results, the measured frequency of leak occurrence in a
 process unit was not significantly different when the leak definition  was
 based on meter reading using a reference material  and when response factors
were used to correct meter readings to actual  concentrations  for comparison
to the leak definition.  The variation in response factor is  not a  signifi-
cant problem because ambient concentrations  around leaks  are  usually much
higher than the leak definition and much lower  when  no  leak exists.
     An alternative approach to leak detection  was evaluated  by EPA during
field testing/ ''   The approach used was  an  area  survey, or  walkthrough,
using a portable analyzer-  The unit area was  surveyed  by walking through
the unit positioning the instrument probe within  1 meter  of all  valves
and pumps.   The concentration readings were  recorded  on a portable  strip
chart recorder.  After completion  of the walkthrough,  the local  wind
conditions  were used with the chart data  to  locate the  approximate  source
of any increased ambient concentrations.   This  procedure  was  found  to  yield
mixed results.  In some cases, the majority  of  leaks  located  by individual
component testing could be located by walkthrough surveys.  In  other tests,
prevailing  dispersion conditions and local elevated ambient concentrations
                                D-5

-------
complicated or prevented the interpretation of the results.  Additionally,
it was not possible to develop a-general criteria specifying how much of
an ambient increase at a distance of 1 meter is indicative of a 10,000
ppm concentration at the leak source.  Because of the potential variability
in results from site to site, routine walkthrough surveys were not selected
as a reference or alternate test procedure.
D.I.2  Emission Testing Experience
     During the data collection phase of this project, tests were conducted
at four natural gas liquids facilities.   Each unit was surveyed using
Method 21 and, for portions of two plants,  comparative screening using a  soap
scoring technique was performed.   The purpose of  this comparison was  to
determine if leak detection by the two methods could  be incorporated  into
one data set for emission factor  calculation.   The result of this  comparison
was a general  correlation between soap scoring and Method 21.^   '
However, because soap scoring could  not  be  used in all  cases, this alternate
procedure was  not included as a part of  the reference test procedure.
     In addition, source enclosure with  measurement was  performed at  two
plants to develop additional  emission rate  data.   The test procedures  and
results are described in Reference 11.
     The calibration species  used in this study was methane.  Flame
ionization type analyzers were used  for  screening.  The analyzers were
tested and could achieve the  performance requirements of Method 21.
D.2  Continuous Monitoring Systems and Devices
     Since the leak determination procedure is not a  direct emission
measurement technique, there  are  no  continuous monitoring approaches  that
are directly applicable.  Continual  surveillance  is achieved by repeated
                                  D-6

-------
monitoring or screening of all affected potential leak sources.  A continuous
monitoring system or device could serve as an indicator that a leak has
developed between inspection intervals.  The EPA performed a limited evalu-
tion of fixed-point monitoring systems for their effectiveness in leak
          (8 12 13)
detection.  '   '   '  The systems consisted of both remote sensing devices with
a central readout and a central  analyzer system (gas chromatograph)  with
remotely collected samples.  The results of these tests indicated that fixed point
systems were not  capable of sensing all leaks that were found  by individual
component testing.  This is to be expected since these systems are significantly
affected by local dispersion conditions and would require either many  individual —
point locations,  or very low detection sensitivities in order  to achieve
similar results to those obtained using an individual  component survey.
     It is recommended that fixed-point monitoring systems not be required
since general  specifications cannot be formulated to assure equivalent
results, and each installation would have to be evaluated individually.
D.3  Performance  Test Method
     The recommended fugitive emission detection procedure is  Reference
Method 21.  This  method incorporates the use of a portable analyzer  to
detect the presence of volatile organic vapors at the surface  of the inter-
face where direct leakage to atmosphere could occur.  The approach of  this
technique assumes that if an organic leak exists, there will be an increased
vapor concentration in the vicinity of the leak, and that the  measured
concentration is  generally proportional to the mass emission rate of the
organic compound.
     An additional procedure provided in Reference Method 21  is for the
determination of "no detectable emissions."  The portable VOC  analyzer
                                 D-7

-------
is used to determine the local ambient VOC concentration in the vicinity
of the source to be evaluated, and then a measurement is made at the
surface of the potential leak interface.  If a concentration change of
less than 5 percent of the leak definition is observed, then a "no
detectable emissions" condition exists.  The definition of 5 percent of
the leak definition was selected based on the readability of a meter
scale graduated in 2 percent increments from 0 to 100 percent of scale,
and not necessarily on the performance of emission sources.
     Reference Method 21 does not include a specification of the instrument
calibration basis or a definition of a leak in terms of concentration.
Based on the results of EPA field tests and laboratory studies, methane or
hexane is recommended as the reference calibration basis for fugitive emission
sources in the natural gas and crude oil production industries.
     There are at least four types of detection principles currently
available in commercial portable instruments.  These are flame ionization,
catalytic oxidation, infrared absorption (NDIR),  and photoionization.  Two
types  (flame ionization and catalytic oxidation)  are know to be available
in factory mutual certified versions for use in hazardous atmospheres.
     The recommended test procedure includes a set of design and operating
specifications and evaluation procedures by which an analyzer's performance
can be evaluated.  These parameters were selected based on the allowable
tolerances for data collection, and not on EPA evaluations of the performance
of individual instruments.  Based on manufacturers' literature specifications
and reported test results, commercially available analyzers can meet these
requirements.
     The estimated purchase cost for an analyzer ranges from about $1,000
to $5,000 depending on  the type and optional equipment.  The cost of an
annual monitoring program per unit, including semiannual instrument tests
                                  D-8

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and reporting is estimated to be from $3,000 to $4,500.  This estimate is
based on EPA contractor costs experienced during previous test programs.
Performance of monitoring by plant personnel  may result in lower costs.
The above estimates do not include any costs  associated with leak repair
after detection.
D.4  References
     1.  Joint District, Federal, and State Project for the Evaluation of
Refinery Emissions.  Los Angeles County Air Pollution Control  District,
Nine Reports.  1957-1958.
     2.  Wetherold, R. and L. Provost.  Emission Factors and Frequency of
Leak Occurrence for Fittings in Refinery Process Units.   Radian  Corporation,
Austin, TX.  For U.S. Environmental  Protection Agency,  Research  Triangle
Park, NC.  Report Number EPA-600/2-79-044.   February 1979.
     3.  Telecon.  Harrison, P., Meteorology  Research,  Inc., with Hustvedt,
K.C., EPA, CPB.  December 22, 1977.
     4.  Miscellaneous Refinery Equipment VOC Sources at ARCO, Watson
Refinery, and Newhall Refining Company.  U.S. Environmental  Protection
Agency, Emission Standards and Engineering Division, Research  Triangle Park,
NC.  EMB Report Number 77-CAT-6.  December 1979.
     5.  Hustvedt, K.C., R.A. Quaney, and W.E. Kelly.  Control of Volatile
Organic Compound Leaks from Petroleum Refinery Equipment.   U.S.  Environmental
Protection Agency, Research Triangle Park, NC.  OAQPS Guideline  Series.
Report Number EPA-450/2-78-036.  June 1978.
     6.  DuBose, D.A., and 6.E. Harris.  Response Factors of VOC Analyzers
at a Meter Reading of 10,000 ppmv for Selected Organic Compounds.  U.S.
Environmental Protection Agency, Research Triangle Park, NC.  Publication
No. EPA 600/2-81-051.  September 1981.
                                 D-9

-------
     7.  Brown, G.E., et al.   Response Factors of VOC Analyzers Calibrated
with Methane for Selected Organic Compounds.  U.S. Environmental Protection
Agency, Research Triangle Park, NC.  Publication No. EPA 600/2-81-022.
May 1981.
     8.  DuBose, D.A., et al.   Response of Portable VOC Analyzers to
Chemical Mixtures.  U.S. Environmental Protection Agency, Research
Triangle Park, N.C.  Publication No. EPA 600/2-81-110.  September 1981.
     9.  Emission Test Report:  Dow Chemical Company, Plaquemine, La.
EMB Report No. 78-OCM-126, December 1980.
     10.  Weber, R.C., et al.   "Evaluation of the Walkthrough Survey Method
for Detection of Volatile Organic Compound Leaks," EPA Report No.
600/2-81-073, EPA/IERL Cincinnati, Ohio.  April  1981.
     11.  "Data Analysis Report:  Emission Factors and Leak Frequencies for
Fittings in Gas Plants," EMB Report No. 80-FOL-l.  May 1982.
     12  "Emission Test Report:  Sun Petroleum Products Co., Toledo, OH,"
EMB Report No. 78-OCM-12B, October 1980.
     13.  "Emission Test Report:  Union Carbide Corporation, Torrance, CA,"
EMB Report No. 78-OCM-12A, November 1980.
                                   D-10

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APPENDIX E.   MODEL FOR EVALUATING THE EFFECTS OF LEAK DETECTION
    AND REPAIR ON FUGITIVE EMISSIONS FROM PUMPS AND VALVES

-------
     APPENDIX E - MODEL FOR EVALUATING THE EFFECTS OF LEAK DETECTION
         AND REPAIR ON FUGITIVE EMISSIONS FROM PUMPS AND VALVES
E.I  INTRODUCTION
     The purpose of Appendix E is to present a mathematical model for
evaluating the effectiveness of leak detection and repair (LDR) programs
on controlling fugitive emissions from pumps and valves.   In contrast to
the model presented in the BID for analysis of LDR programs on relief
valves and compressor seals, the model in this appendix incorporates
recently available data on leak occurrence and recurrence and data on
the effectiveness of simple in-line repair (Reference 1).   In the BID
model, LDR program impacts are_evaluated through emission correction
factors that are based in part upon engineering judgment.
E.2  DESCRIPTION OF MODEL
     The modeled LDR program is based on the premise that all sources at
any given time are in one of four categories:
1)   Non-leaking sources (sources screening at less than  the action
level);
2)   Leaking sources (sources screening at greater than or equal  to the
action level);
3)   Leaking sources that cannot be repaired on-line and  are awaiting a
     shutdown for repair; and
4)   Repaired sources with early leak occurrence.
     There are four basic components to the model:
1)   Screening of all sources except those in Category 3,  above;
2)   Maintenance of screened sources in Category 2 and 4  above;
3)   Rescreening of repaired sources;
4)   Process turnaround during which maintenance is performed for sources
     in Categories 2, 3, and 4, above.  Figure E-l shows  a schematic
     diagram of this program.
     Since there are only four categories of sources, there are only
four "leak rates" for all sources.   In fact, there are only three distinct
leak rates since the repaired sources experiencing early  leak recurrence

-------
••fly fl«lt«t»»v •«
Figure E-l.   Schematic diagram of the modeled leak  detection and repair  program.

-------
are assumed to have the same leak rate as sources that were unsuccessfully
repaired.   The model does not evaluate gradual changes in leakStates
over time but assumes that all sources in a given category have the same
average leak rate.
     The emissions model enables investigation of several LDR program
scenarios.   General inputs pertaining to the LDR program itself may vary
(for example, frequency of inspection, repairs, and turnarounds).
Further, input characteristics of the emission sources may vary.  Inputs
required in the latter group include:
1)   The fraction of sources initially leaking;
2)   The fraction of sources that become leakers during a period;
3)   The fraction of sources with attempted maintenance for which  repair
     was successful;
4)   The emission reductions from successful and unsuccessful repair.
     Other assumptions associated with the model are:
1)   All repairs occur at the end of the repair period; the effects
     associated with the time interval during which repairs occur  are
     negligible;
2)   Unsuccessfully repaired sources instantaneously fall into the
     unrepaired category;
3)   Leaks other than unsuccessful maintenance and early recurrences
     occur at a linear rate with time during a given monthly period; the
     monthly occurrence rate is assumed linear within an inspection
     period;
4)   A turnaround essentially occurs instantaneously at the end of a
     quarter and before the beginning of the next monitoring period; and
5)   The leak recurrence rate is equal to the leak occurrence rate;
     sources that experience leak occurrence or leak recurrence immediately
     leak at the rate of the "leaking sources" category.
E.3  MODEL OUTPUTS
     The outputs from the modeled LDR programs are shown in Table  E-l
for three LDR scenarios for valves (quarterly, monthly/quarterly,  and
monthly) and two LDR scenarios for pumps (quarterly and monthly).   These
scenarios enabled estimation of emission reductions and costs for  valves
and pumps under Regulatory Alternatives II, III, and IV.   These estimates
are presented in Chapters 7 and 8.
     The Statistical Analysis System (SAS) program is provided in  Table E-2
The data inputs to the modeled LDR programs are provided in Tables E-3
and E-4.  The data outputs appear in Tables E-5 to E-14.
                                 E-3

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               Table E-l.  RESULTS OF THE MODELED LEAK DETECTION AND REPAIR (LDR) PROGRAMS

Emission source
and LDR scenario
Valves
Quarterly
Monthly/Quarterly
Monthly
Pumps
Quarterly
Monthly
Emission factor,
kg/day

0.041 (0.11)
0.041 (0.11)
0.029 (0.079)

0.50 (0.63)
0.42 (0.53)
Percent emission
reduction

77
78
84

58
65
Total fraction of
sources screened in
second turnaround -
annual average

4.0
4.3
11.9

4.0
12.0
Fraction of sources
operated on in
second turnaround -
annual average

0.19
0.19
0.19

0.39
0.41
 XX  = VOC emission values.
(XX) = Total hydrocarbon emission values.

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         Table E-2.   STATISTICAL ANALYSIS  (SAS) PROGRAM TO  EVALUATE
          THE  IMPACT  OF A MAINTENANCE PROGRAM ON FUGITIVE EMISSIONS
                               FROM VALVES AND  PUMPS
       ••^••••••••••••••••^•^••••••••••••••••••••••••••••••••••••••••••••••»«>
S
6
7
e
9
in
11
1?
u
10
1?
lf>
17
18
19
?n
21
?7
3D
11
3?
35
id
37
38
39
HO
ul
«2
MS
uu
•45
• *••!
             >••••••»••»>••••••••••••••••••••••••••••*••••••••••••••!
              THIS STATISTICAL ANALYSIS SYSTEM (SAS) PROGRAM
               ALLOWS THE USER TO EVALUATE THE IMPACT OF A
              nAlNTENANCf PROGRAK ON FUGITIVE EMISSIONS FRO*
                       CFRTAIN IN-LINE SOURCES.
                         RADIAN CORPORATION
                            AUSTIN. TEXAS

                            AUGUST. 1981

                        ••••••••***••••*••*•
 • I
 • t
 • I
 • I
 • I
 • I

 • I
 • I
>•:
OPTION* LS=l32
••*»»••••••••••»>•••••»•»•»•••••••»*••••>*••••••••»•»<
     In ORDFR TO PROPERLY I«PuE"CnT THE PROGRAM THE FOLLOWING
      TIIPUT PARAMETERS ARE
    Ttprs sruf'r.E TYPE IDENTIFICATION
    «rrvicc=scnvicr TTPE IDENTIFICATION
    MflTsP^fCEsS L'NlT IDFUTIFICATION
    TTi srnACTlOU OF SOURCES LEAKluG INITIALLY
    »»n ERROR OF FE1 (MUST P,E ZERO IF OPTION1 = 0)
    rrssFMAcTinu or SUCCTSSFULLY REPAIRED souRcrs THAT EXPERIENCE
        rAPLY FAILURE
                 ERROR OF FE2 «MU$T BE ZERO IF OPTIO()1=0)
                OF sourtcrs OPERATING PROPERLY AT THE BEGINNING
       THAT BECOME LCAxTRS OURluG A PERIOO.
    FTA=i OWPR BOUND OF A THO-TAI(.EO 95* CONFIDENCE INTERVAL ON
        ff (MUST BE ZERO IF OPTION1=0>
    TFnrtiPPER HOUND OF A TWO-TABLED 95X CONFIDENCE INTERVAL ON
        FF (MUST BE ZEF.P IF OpTlONl = 0>
    rlsItalTJAL EHISSlOfi FACTOR  { KG/HR/SOURCE ) FOR ALL SOURCES
    FlAsi OfcFR POUND OF A T»'0-TAlLEO 95t CONFIDENCE INTERVAL ON
        rl (MUST OE ZEI'O IF OpTjONlsQ)
    FlnsiiPPFR noUflO OF A TwO-TAjLEH 95* CONFIDENCE INTERVAL ON
• t
• I
                                                                             • 1
                                                                             •»
                                                                             • J
• I
• I
•I

                                       E-5

-------
                              Table E-2.   CONTINUED
47-            rl (MUST BE 7LU.O  IF OPTiDMlEO)
•n         TURMrFRrouEuCY OF TURNAROUND  UN MONTHS)
•9         FEsTuE VALUE OF FCl tfllEN  A PROCESS  TURNAROUND  OCCURS.
50         PPTIONlcOi IF COMFlflrNCE  INTERVALS  ON  EMISSION AND REDUCTION
51                    ESTlMATfS  ARE  NOT  DESIRED.
*9                si • IF COMFIOFNCE  INTERVALS  ARE DESIRED.
53         PPTION2=0. IF PROGKAv. IS  TO 9C  RUN  FOR ALL  CASES*
54                sl« IF THE PPflGRAM IS  TO RE  RUN ONLT FOR  THOSE
55                    CASES I'-1 WHICH Fr<=IFL.
S6         OPTION3=0. IF MONTHLY FOLLO»-UPS ARE NOT  TO BE PERFORMED
1,7                    BETWEEN THE PERIODIC SCREENING AND  MAINTENANCE
*«                    Of SOURCE*-—  THE  FREOUEMCY OF THESE  CHECKS MuST
59                    <3t SPECIFIED  (SEE  'PERIOD''PARAMETER  BELOW)
60                sl» IF "ONTHLY FOLLO -u^S ARE TO BE  PERFORMED
61                    BETWEEN THE PERIODIC SCREENING AND  MAlNT-
6?                    ENANCE OF  SOURCES.
63         PERlrD=FREOUENCY 
-------
                             Table  E-2.   CONTINUED
•^^     .0    FllE  PRINT LL=L  IIEADCRsH NOTlTLFSt
in*    IF FF>tF(.  THEN k='«M
107    AHRAY A Sfl-SCs  TFA  FFB ElA EIBt
in«    IF OPTTOnlsn THEN TO OvCR At A=.| CNO«
109    JF L<7  THEM PUT  -PAGE-J
110    IF FIPsT.TTPE THEN PUT // TYPE' IF FIRST.UNIT THEN PUT  /.UNIT  "UfllTSM
111    PUT  / Sfr «
11?    s>7 $rRUtr.F  a?9  El a<»7 FF »63 Irl  »76 Fl 8B9 F2  9102 FE1  »H5 Fc2 / S-25 'i1  EIA
113        *.«• *S2 •••  EIP  fr.M a39 '»' P«t3  M« FF* 6.«« S50  «.• FFfl 6.1* 957 •)• P62 •••
im        
-------
                            Table  E-2.  CONTINUED
1*0
J«tl
i«s
1«il
J««S
1«7
1*49
150
151
15?
1«3
]5u
155
157
1 fc 1
169
IfS
16A
167
170
171
172
17U
171
17*
177
17P
179
l^n
101
           »rr? r INACTION or PFPAIKED SOURCES THAT LXPCHICNCL FAHLY  IAJ LUKES*  ;
       |F CHCCKd THEN DOl
       •• LFAK ncciiREncE RATE IFF> FO« «« PCRJOD is GREATER THAN THE  «
       'INITIAL FRACTION OF SOURCES LEAKING UFI. )•• /
       »lo «TliI< WILL KESULT IN * NEGATIVf EMISSIONS REDUCTION. « 81
       »l
       IF OPTTOu?=1 TllFH PUT *?. 'THE OPTION TO NOT RUN THE PROGRAM FOR  THIS  •  /
       *ln 'CASr HAS pEEfj SELECTED. 'r
       RETUPrit
       »'•  PUT    8>56 'I II P U T   D • T At // 826  'FOR EXAMINING  THE  REDUCTION IM •
           'AvfRAFC LFAK PATE DllE TO A MAINTENANCE  PROGRAM'  ////SSI  'El'  8m 
           »f.tt "ITL*  S78 'Fl' S91 'F2« 810M  'FEl'  S117 'FE2«  /  as 'TTPE  OF' 32& lS,'.
           »«tu J3»'-' S62 «•'-• 875 9*1-' 88B 9«»-« 8101  9«'-' 8il«»  9««-:  /
           «6 "tOURCf/U'lIT' 826 'HE AM  (95? ell' 8MH 'MCAN(95X  CD'
           »69 «»'f.EAti CSEI    «  / fl! 120*'-'     I
       RETURN!
       »»
          •••»••••• **«***»*»**»a»««*«*«««*»tt»**»««»*tt*«tt**»tt»*««*«**«ttB9**tt«tt|
                                                                             •!
                                                                             •«
       • Tlir FOiLOklMR MACRO  CPEVELOP* CALCULATES EMISSION RATES  AS  A
       •     FUNCTION OF TIVE  C IN MONTHS)
       ARRAY
       ARRAY
       ARRAY
       ARRAY
       ARRAY
       ARRAY
       ARRAY
       ARllAY
»•«••»••••»•••»»»•••»•••»»'•»•••»•••••»••••«••••••»•••*•»••«•••»•••••»»«

      lOFVELOP                "                    :
      Vlll FEU FE21 Fpl FLU  ARRAY XOfL) TflFEll TOFE21  TflFpl  ToFLU
      X?lS> T2FE12 T2FE29 T2Fp2 T?FL? T?FE11 T2FE21 T2FR1 T2FL1«
      XIiSl T1FE12 T1FC29 TlFp2 T1FL2 TlFEll'TlrE21 TlFpl TlFLJI
       XMS) TSFEl?. T3FC32 T3FP? T3FL2 T3FE11 T3FE21 T3FP1 T3FLU
       XMS) T»»FEl2 TNFf?2 T«4FP.i T"»F|.2 TUFEll T«(FE21 T*»FP1 TuFLlJ
       X«.(S) TSFE1? TSFTP2 TSrP? T**FL2 TlFEll T5FE21 T5FP1 TpFLlJ
       XMS) T^FE12 T6FEP2 T6FP2 T«.FL2 TftFEll T6FE21 T6FP1 TftFLl!
       X7«S) T7FE12 T7FE92 T7FP2 T7FL2 T7FE11 T7FE21 T7FP1 T7FL1I
       X«(Sl TflFEl2 T8Fr?2 T8FP£ TCFL2 TftFEll TBFE21 T8FP1
       X«ISl TeFEl? T9FEP? T9FP? T9FL2 T9FE11 T9FE21 T9FP1
       XlO««) TJOFE12 TlnFf22 TippP2 T10FL2  T10FEH T10FC21  TlOFpl  T10FL1:
       XlllS) T11FC1? TMFE?2 THFP2 T11FL2  TllFEU TllFr2l  TllFpl  T11FL1I
       *12(S) T12PE12 T12FE22 T!?FP2 T12FL2  T12FEH Tl?FF2l  T12FP1  T1?FLU
      Yll  ) TFE12 TFE22 TFP2 TFL2J
      XX(SS) K X1-X12I
      TTIL) FEl?. FE22 FP2 FL2;
      Yin) FEl? FE22 FP2 FL2 FElJ FE21 FPl FL!I
      FS/T) FSi-FSfo:  ARRAY FM(T) FMI.FM&OJ
      I KIT) LEAKl-LFAKfiOs  ARRAY RPIT) REOUCTl-REDUtTfeO:
AHRAY »Fri2lT) FE12_l-rri?.60:   ARRAY AFE22IT)  FE22.1-FF22.60:
ARRAY A!-P?
-------
                           Table  E-2.   CONTINUED
                    ) rin.i-f ril.r.o;    «I»HAT  nrcinTi  f tki.i-rt2l.bn;
in«,    i\R*  FLI.I-FLI.&O;
1»7    CU=ET/nFL«Cl-IFL)«F?M   EE=Fl»ltt    EP=F2«EU
16*    FEjlrOi  FE?1=C»  FLl=lFi  J   FPlsl-Fl.il
1^2    0" OwfP tTI  X=TTt   XO=Vl
I'JS    FEulnsOi  rE2l.O=Ol  FL1.0=lrLj    FPl.Osl-FLl-OI
1^«    FE12* 0=Frll_0+(FE2lln+Fl1_OI«FEli
                               j   FL2_I>=0»
197    pO Tr1 TO 60«
       0=t»On
-------
                         Table E-2.   CONTINUED
>M    t* YPso'-fuEu Lit ;
939    FEl2=«l-rPl|»Fri
       FE?2=<1-FPH«(1-F£|,FE?|
?3S    ELSE Dot
93*.    FEl?sFrlt«tFE2l4FLl)«FEl i
9.37
93S
239
9110    FL9=ni
9«i    ou OVER vi xo=v«
?M3    00 S«s? TO
?m»    Q
?«45    s
       00 Srl.?.5«6«
       SUvErsSUMlSUMCC.XX) t
950    00 SsS.Ti
?5l    SUMEP=SU
?f?    ENOJ
?53        FHHI
?57
9S»«    «Ds  FE21.l-rE91.60j   ARRAY OFPKMI  Fpl.l-FPl.AO «
969    ARRAY  OP) l(M)  FLl-l-FLl_£Ol
970    «=OS
271    00 TrPrfllOD  TO 60  PY PERlOOl
S79       M-M»H  LlsLK! RsROI  HFE12sAFEl?. : BFE??=AFE22|  BFp?.sAFP2l  BFL2=AFL9.I
973       DrrilsAFril;  BFr21=AFr21l   BFPl=ftrPl;  BFL1=AFLU   ENDI
97u    KEPP TYPr  SF.RVTCE  UNIT   L1-U60  R1-R6H Ffl2.0-FEl2.60
9.75        Fr'?".0-FE29_60 rP2.0-FP2.60 FL?._ft-FL2.*0 FE11.0-FEH.60 Fr.21_0-FE?l-f>n
                      .0 Fuj.O-n.1.60   IPS FSI-FS60 IFM FMl-FMfeO EL EE EP IFL
                                       E-10

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                            Table E-2.   CONTINUED
.S77    Tl F?  PfblOn UlKlAL 0»'1TON2t
?76    *
son     ••»•••*••••••••»•••••••••••••»••••••••••••••••«•«••••*»»•••••»•••••••• i
sei     •   THE  roLLOwiiic COPE COMPUTES AMD PRINTS OUT  THE  TOTAL  TRACTION     »i
?B?     •   Or  OliRCrS SCREENED AMD OPERATED 0N OVER EACH TEAR  OF THE FIVE    •!
2*3     •   TrAQ irAlNTEnANCE PROGRAM.                                          •!
2*5     •«
?««,     DATA RAW i  SF.T IljPUT IDROP=SE1-SE5 FF« FFO ElA  EIBll
PB7     IF  OPTTOM2=1 AMD FF>IFL THEN
        DATA .NUIL.JSET RAW( KEEPsTTPE SrRVlCE UNIT  IPS  FSl-FSfeO
          RY TYPr UNIT SCRVICCt
        FlLC PRINTS H=PS lirAOERni NOTlTLrS«
 ???     ARRAY ISIIHFS l.ll SllMFSl-SU«FS5« ARRAT _SUMFn  IJ1
                      IPS FSI-FS12) iSUHp^irSUMtOF  IF" FH
                      FSl3-FS2«4)i SUKF"?zSlJM t OF FM13-FM2UH
 ?9S     SU' I
 SOO     IF Rurisfl THFH 00«
 301     C=A7in=77:C2=fi2!C
 302     IF RtlNsl THEN D0»
 303     PUT "_P»GF_J
        PUT *m aC3 SERVICE  'SERVICE' / S>C1  HI*'-'/
          W r.l 'TOTAL FRACTION OF' *6 'TOTAL FRACTION  OF'  »
        |F R(|Ms1  TMFIJ PyT a  15 'YEAR* Bt
 30«    PUT a ri  'SOUHCES SCOEEHrO'  +6 'SOURCES  OPERATED ON'  I
 309    IF Riifjsl  TMCN PUT 812 2«'-"  81 PUT 8C  5u»'-' ///j
 Sin    DO Jrl TO 5 l
 311    IF RllNsl  THF.N PUT 816 J 9. 3|
 312    PUT aC9 ISUKFS 7.<« *16 _?6 'SUMMARY OF TOTAL FRACTION  OF SOURCES  SCREENED AND •
 316      'OPERATED 'ON FOR'*1 TYPE "BY YFAR' / 859 UNIT 'UNITS' /////I
 S17    RETURfU
 31*    •»
 U9    ••••••••€•••••.»••«•••••••••••••••«•••«••••••••«•••«»•••••••••••••••••»
 J20    •  TuE FPLLOWlnG COOC SIMULATES RCTENING 'NO  EMISSIONS DATA USING   •<
 521    •  SAMPIF VAL'IFS CINPUT) IN  OwDcP TO ESTlMftTF  CONFIDENCE INTERVALS   «|
 A??    •   on r*lSMGns ANO EHICSIONS RCOUCTION.                            «i
                                         E-ll

-------
                            Table  E-2.   CONTINUED
32*
32«    •»
32*    DMA GrwtPATCJ SET
S?A    If OPTTOm2=l AriO FF>IFL THEN DELETE!
327    ARRAy L«n(Z)  SOI  S02j
328    SPl=M«»  FPM3  ElH3;
D?    ARRAY Ml 7.) FFCl EIC1I  ARRAY C2 ( z ) FTC? E1CJ1  ARKAY C3(Z)  FTC3 EIC31
SAS    ARRAY n?(Z) FFps Cin?1  «RRAY 0^(21 FFDS EIOSI
*»•»    ARRAY YO«Z) FFYO ElYOI  ARRAY RVAR(Z) RV.FF nV.EH
335    ARKAY PTlZ) FFPT EIPTI  ARRAT CQIZJ FFCO ClCOl
336    ARRAY IsrrDcIl  SECOl-SETDSl
13*    ARRAY Mill!)  IPL Fl F2 FE1 FE2t  »RRAY RV(I) RV_1FL  Rtf.Fl  Rtf.F2  RV_FEl  RV  F
339    ARRAY CF(X) SEi-SESt
SMn    IF OPTTONl=l THE" 001
3X1    00 Owrfl A:  H1S.02S/A;  ri=U-«A»«?l»Hi)/2-((((R*3«a)»»2)-(B««2) )«H!/6»1
3«2                C2s( (U««2l-(«««2) J/jj  02=U-At
i«3                C3=< (B«.2)-«ll«*2) 1/2j  03=8-UI
X'tn                H3=( (C1.D2)-(.95«C2» )/( CC3.0? »-«C2»03l ><   H2s( ,»5-(03«H3 ) 1/021
5<45                 PTs0.025*H2»(U-A)«                                       END;
306    nO Jsl TO NTRlAL'            ;"
       DO OVF.P MU>  RVsHU+sr«NORWALI.SErD> »                                  END|
       DO OVER vo:  Yr=UMiroRM('sp»                                                •
3U9    IF n<=YO<.0?5 THEN RVARsYO/HXl               ,
350      FL^F IF .025    OUTPllT!EMl);END:ELSr IF OoTIONl=0 THEN OOl
ASA    DO OVER *u:iw="u!ENOJ
357    00 OufP  U;PVAP=U!ENO«
SSfl                  "       OUTPUT JENOJ
559    KEEP TYPr SFRVTCE UNIT Pu.IFL   QV.F1 RV.F2  RV.FE1  RV.FE2 RV_FF Rv.EI  IFL  Fl F?
560        FEl FE? TUPn FE MTRUL OPTION? PERIOD OPTIONS;
3«-l    •»
)6 y    •••*<•*»»••»••••••••••«•••••*••*••••**••••••••••••••*•••••••••*••••«•• |
S6S    •  THE FOLLOWING CODE COMPUTES  AMD PRINTS THE  ESTIMATED EMISSION     •;
564    •  FACTOaS  MJD  FKACTTOtiAI. REDUCTION  IN EMISSIONS  (INCLUDING 90S      •;
365    •  cnrrmEwrr LIMITS) PER TURNAROUND.                                 •;
       QATA CrurpftTEt SET  GENERATE I
                                         E-12

-------
                          Table  E-2.   CONTINUED
       if IBV'IFL «?«irt n OR t?»n  »  OK
170       CSV FP  <0 CR  RV_F2   >(2*F2  )) OR IRV.Fr.KO OR FV_FEl>C?»FEi U  OR
37J       «RV_rr2 <0 pu  «V_FE2  ><2«FE2 II THCN DELETE!
578    ARPAY miltl  IFL   FI  F2 FE1  FE2«  ARRAY Rv(I) RVllFU  «V_F1  Wv_r2  RV.FF.l RV.Fr2|
S7S    APPAT 11(71   FF  Ell    ARRAT Rv^PCZI  RV.FF  RV.EII
37«    00 OuEP MUl  MUsRVI ErtOl    00 OVrd Ul UsRvARl ENOI
375    .OrvruoPi
S7fc    PROC UMlV/ARlATc NOPRTNTl  BT TYPE  UNIT SERVICEI
577        VAR I 1-L60    R1-IR60  t
37B        OUTPUT OUTrSTATS P5=l Ok'Ll-LoWL&O
J7^       LOVR1-LOWR60 P95=HIGIU 1-HlGHt.fO HI6HR) -MI6HR60  I
3i«n    O*TA EFKrAN«s;r«rn6E STATS INPUT IKCEP=TTPE UNIT SERVICE  TURN
3*1                                       OPTION: PERIOD OPTION2  FF
3*9                       RAH  «KEEP=TTH£ (iMjT SERVICE L1-L60 R1-R60)!
S«1S      I'.T Typr UrilT SERVICEi
W«    JF OPTtON2=l  AMD  FT>lFc  THEN nELfTEl
S95    ARRAy lFF(K)
S67    flRRAt "rrU«Kl  FFU1-EFU20I
       A«RAY _R(K)  RDl-ROSOt
       ARRAY 'RI «KI  RLI-"L?O«
       ARRAY _R(I(K)  Rt)l-RU?OI
       ARRAY _«M  IT)  Ll-t6n«
       ARPAY *»«(L(T)  LOwLl-LOWLftOl
3*?3    ARRAY _«IU(T»  MI6IIL1-HIGIIL60I
3»M    ARRAY iHR(T)  Rl-R60l
       ARRAY >«L(T)
       AR«AY IMPU(T)
       0° OvCP
       _»«PL=(1»«R-_MRL
uOl    ARfAY  ISUM  SU*j-SUK6tOO OVER .Su»"t _SUMrO«ENDJ
ul?
••DM    N=60/PrRiOO:
i»C5    00   T=1  TO  HJ
u07
un«
<«P»     IF  I-Ttl  THEM  DO!  K=K4lJ
ulO     .ErseL'wl /TfJi_EFL=.Er-SOPT«SUM2/TN) I .EFUr
••11     lRrSil«»u/TN« _RL=-R-S?RT(SLIM5/TNI j _R
                                          E-13

-------
                            Table  E-2.   CONTINUED
• IS    KfTP TYPF OtilT  SEHVICL  K  EH-EF?o
•if,          rnu-TFUpo  RDI-RD?O KLI-RL?O RUI-RUSO OPTIONI i
•17    DAT* .MlllL.lSET EFMEANSlBY TTPE UNIT SERVICE!
• IB    FILE PPINT1 N=PS  HEADERsH NOTITL.CS!
• 19    ARRAY '.tf lATELT FOLLOWING prRIODIC          »t
•50     •   MMNTrNAHCE) AMD FOR THE END (JUST BEFORE PERIODIC MAINTENANCE     »l
•St     •   I« PERFCnuEOI OF EACH PERIOD.                                      «j
uS?     ••»•»«»•••••»»*»•«••••»*••*••••*••••»••••«•»••••••••••»•»»••«»••••••••!
• 53     •«
•5M     DATA IHULL.J  SET RAW: BY TYPE UHIT SEPVICEI
• 55     Fll E PPTMT3 Ll.=L MEADERsu UOTlTirSj
•5A     AHRAv Ir^l  |JJ FS1-FS12J ARRAY _FM1 (J) FM1-F>«12«
• 57     AHRAY lF«!2  (Jl FS13-FSP«« ARRAY _Fi«2 (J) FM13-FM2HI
• 5«     ARRAY _r«3  (J> PS25-FSS6: ARRAY _rf3 
-------
                               Table E-2.   CONTINUED
«ti    FORMAT Fs:-FS6n F*I_FM«,P  ir«  IFS fc.«n
• «.?    If FIRST. SERVICE OR L<1"«  THEN  P. T .PASE.I
«f.S    PUT / Bl 'INITIAL'  BIS TFS 82* TF" 8"»2  • — •  853  ••-•  867 * — •  87* • — •  89? • --•
»6»    »103 • — • 8117  •--• 812?  • — •  //|
«65    00 Jcl TO 121
• 46    PUT S3 J 2. 815 -FSl  826  .FMl  Sur .FS2 OS1 .FH2
           »** IFSS 876 _FMS 6*n .FS<« eioi _FMH BUS .FSS
           S 12*. .FM5  //I
«7n    RETURNS
»7i    H: PUT /// »3l  'FRACTION  OF  TOTfti  RPURCES  SCREENED AND OP««TED ON F0»» +1
«7?    TtPE  «nY KONTH«  /  851  UNIT  'UNITS  -  '    .
»73    SERVtCr  «SERVlCE'  /////
i»7«    9l« '1ST YEAR1  81**   '2ND  YEAR'  afi9 '3RD  YEAR'  89M  «"«TH TfAR*  »119 '5TH TEAR1  /
u75    91« 19»'.« »39  l9»«.«  a«u 19»«-« 8B9 !»••-'  BllH  19»'.» / 925 'FRACTION* »50
«7A    'FpArTTOM' 975  'FRACTION' 8100  'FRACTION'  8125 'FRACTION' / 81 "»
«77    "FRACTTON    OPERATED'  839  'FRACTION  OPERATED'
«7«    86u TRACTION   OPERATED'  8B«  'FRACTION   OPERATED'   8U«» 'FRACTION   OPERATED'
u79       /»? 'KONTH' Si*  'SrREEnEO' S2«  'ON'  839  'SCREENED'  S55 'ON'
«en    P«M 'sr»»rENED'  a7» 'ow su9  'SCREENED* 8103 «ON'  aim 'SCREENED* sisa 'ON* /
«»«1    91 7.'-« Sti« 8.'-'  S85 «.'-' 839 fl»'-; 8RO «••••  S6K  «•••' 871 *•'•' »69 «•'.«
«t»?    sioo  R«'-' S»HM  e«'-'  PIPS e»'-»i
ueo     •'
 ulf,     •    THF  FOLLOWING CODE PRINTS OUT  THE ESTIMATED- EMISSION FACTORS     »l
 467     •    Ann  FRACTIONAL REDUCTION IN EMISSIONS UNCLUDING 90X CON.        •<
 U«>M     •    nnr.HCC  LlriTS)  FOR FACM PCs j on or THE FIVE YEAR MAINTENANCE     «i
 UB9     •    PROfiRAK.                                                         •;
 U91     •»
 «99     D*TA _r«lLL_«  Hr.RGE STATS INPUTIKrEP=TTPE UNIT SERVICE PERIOD
 »93                                   OPTIOHI OPTIONS FF IFD
 ««tt                        RAW t«EEP=TTPF UNIT SERVICE L1-L20 Rl-R20||
 «95      OY TTPF UNIT SERVICE*
 »96     IF  OPTIOn2=l  AMO FF>lFt THEN
 • 97     FILE PRINT"* W=PS HEAOERaH
 «$A     ARRAY >l  (J) L1-L20:ARRAY .LOW)  (J>  LOWL1-LOWL20I
 U?q     ARFlAv 'HTI5HL  IJ> HlfiHLl-HIGHLaOi  ARRAY _MR «J» Rl-R?0l
 50n     ARRAY linwR Ul  LOwR1-LOwR20J ARPAY .HlRHR (Jl HI6HR1-HI6MR20 «
 501     IF  FIRST. UHTT THEN K=OI  K+U  RUM=MOD
-------
                             Table E-2.   CONTINUED
S07    PUT PC? 'MEAfl rMlSSIPN-KK/IIR  (9fl» til     KEPUCTION  «90«  CI»M
SDK    C>-*C IF OPTTOMjsO THEN PUT 8C2 *3 'MEAN E«ISSION-KG/HR« «l«l
50*                                     'REDUCTION* |
MO    Ir KtiNsl THFN PUT «i« *•'.« 81  PUT BCS «•'•• //   I
511    LsftO/PrRTOOl
SI?    If L>20 TllCN LsSOl
SI 3    DO J=l TO Ll
sm    IF RtiMsi THFN PUT ire J 2. 8«  IF OPTIONISI THEN PUT ec
515        1"|  *.«» *2 «(• _LOwL 5.3
51ft       *t» .HTRHL 5.3  •)••*? ^MR fc.3 *?. M« _LOWR 5.2  •«•
517      .HT6MR *.? ')•  /»
sie    c>-sc IF oPTiOMisO THEN PUT ac *s .VL S.K *zi .MR  6.3 /«
519    cNm
5?0    RCTURHl
Ml    H:  PUT ///// KI37 'ESTIKATED  EMISSION FACTORS (KG/HP)  AND FRACTIONAL  REDUCTION*
5?2        /  8*8  Mf MASS EMISSIONS FOR • TTPf  *BT QUARTER  -•  *1  UMIT   'UNITS'  //// i
       RETURru
525    •»*«•••»••••••••••»«••»••••••«••»•••••*•••••»••«»••••«••«"*••»•••••••••!
526    •   THr FOLLOWING CODE PRINTS  OUT THE FRACTION  OF  TOTAL  SOURCES       »l
527    •   «CRCrNCO AflD OPERAjED ON FOR rACH MONTH  OF  THE FIVE  TEAP          »J
52M    •   MAINTENANCE PROGRAM.                                              •»
5J9    •«»•••••••«• ••»••»*••• •»••«••••••*•••»»••»••••••••••••••••••••••••••• |
ssn    •»
SSI    DATA .NULL- 1 SfT RAW; BY -TTPE  UI4JT  SERVICE!      .  ;
S3?    FllE PRIHT5 LL=L HEADERsu NOTlTLfSl
53S    ARRAY _H 2  (J) FL2.0-FL2*19I ARRAT  -FLl  (J)  FLl.l-FLl.20l
53«t    ARRAY _rrl2 «J) FEl2_0-Frl2.l9 ;              '   '
53S    ARRAY 'Frll «JJ FEll.l-Frll.2n«
53ft    AKnAY _FP22 (J) FE22.0-Fr22.19 «  ARRAY .FE21  (Jl FE21.1-FE21-20J
537    A"RAY 1FP2  u) FP2_n-FP2li9i A"RAY  -FPI  (J)  FPi.i-FPi.2ot
5?6    IP FTRST. SERVICE OR  L<1"» THEN  PUT .PAGE.J
S3fl    PUT /  a«  'INITIAL'  S2l  •---•  833 FL1.0  S.3   850 '-— •  862 Fcil.O 5.3 879 «-.-t
5*0            «91 FE?1_0 fe.H 81 OB  ' — ' »120 FP1.0   5.S /I
SMI    Ls60/PrR10D|
•m?    IF L>?n THEM L=20«
S« 3    00 Jsl TH  Ll
SMI*    PUT 88 J 2. 820  .FL2 5. S 833  .F|.t  5.3 8U9 .FE12 5.3 862 .FEn 5.3
5US      «i7r. *Fr22 &.<« 891  _FE?1 6.«»  8107  .FP2  5.3  8120 .FPI 5.3 /«
5«7     If FIPCT.SEPVlCE  OR  L<1*  THEN P»T  "61 87 '• LEAKERS REFERS TO THOSE SOllKCES '
            'SCRrEMING  GREATER  THAN OR EcuAL TO iO.OOO  PPMV.' I
550    Ht   PUT  ////    »39 'FRATTIOWAL nl^TRIBUTION OF SOURCES FOR' +1
551         'PY  PERTOO'  /  951  UNrT    MjfilTS'  «1  '-' +1 SERVICE    'SERVICE' ////
552         an  'FRACTION  OF  LEAKERS*'  »5^ 'FRACTION OF'  S7P 'FRACTION OF SOURCES'
                                             E-16

-------
                              Table  E-2.   CONCLUDED
SS3        S.Jfl7 'FpACTlOli  OF  SOURCES'   /   P?l  «ru;l TO OCCURPFMCr'
S">«t        ft* «UtmEPAIREf» FOUhrES'  »Ts tEXPERlENCiNG E«RLY FAILURE*
55S        »in7 •OPERATING PROPrRtt1  / 316 S3*'-' P<*7 23»*-* 875 26**-1  BIOS  23»«-«  /
           el*  tBCGjriljIMG'  p3«(  «CNO«  8u7 'PEGlNNlNG* 863 «EMO*
           »9?  "CUD* *l05  'BEGIwnlNG'  Sjjl "EMO* /   8«» «(• PERIOD ««»OMTHS|t
           »1*  »OF PEniOO     OF PERIOD'  S«»7 'OF PERIOD    OF PERIOD*
           »7t  »OF PtniOD     OF PERIOD*  S105 'OF PERIOD    OF PERIOD* /  &«»
Sf.1    RETURN*
                                         E-17

-------
                                            Table  E-3.   INPUT  DATA  FOR  EXAMINING THE REDUCTION  IN
                                           AVERAGE LEAK RATE DUE TO A MAINTENANCE  PROGRAM  (VALVES)
 I
»-*
CD

TYPE OF
SOURCE/UNIT
VALVES
MONTHLY UNITS
THC
VOC

QUART /MONTH UNITS
THC

VOC

QUARTERLY UNITS
THC

VOC

El
MEAN (95Z CD


0.02
0.0075
( t )

0.02
( 9 }
0.0073
( t 1

0.02
( • )
0.0073
( • )
FF
HEAN(95X CD


0.038
1 > )
0.038
( t 1

0.038
1 • 1
0.038
f f )

0.038
4 • )
0.038
( i )
IFL
MEAN (8EI
.

0.18
( 1
0.18
< »
*.*- 1
0.18
( )
0.18
( )

o.ie
( )
0.18 "
( )
Fl
MEAN (BE)


0.374
0.374
1 >

0.374
( 1
0.374
( )

. 0.374
( )
0.374
( )
F2
MEAN (SE)


0.023
( >
0.023
' >

0.023
( )
0.023
( )

0.023
( )
0.023
( )
FE1
MEAN (SE)


O.I
0.1
( 1

0.1
( )
0.1
C • I

0.1 |
( 1 )
' 0.1
( 1
FE2
HE AN (1


•0.14
0.14
'

0.14
(
0.14
(

0.14
|
.0.14
f

»E>



*
)


1

)


1

y
                         TURNAROUND EVERY 12 MONTHS — FRACTION OF SOURCES UNREPAIRED  (FED IS 0 AT THE TURNAROUNDS
                         El  •  EMISSION FACTOR (KG/HR/SOURCE) FOR ALL SOURCES INITIALLY
                         FF  •  FRACTION OF NON-LEAKING SOURCES AT THE BEGINNING THAT  BECONE LEAKERS
                                (SCREENING VALUE GREATER  THAN OR EQUAL TO 10.000 PPHV)  DIIRINft A .1 MONTH PCRIOD  (LEAK OCCURRENCE)
                         IFL • FRACTION OF SOURCES LEAKING  INITIALLY
                         Fl  »  ONE MINUS EMISSIONS REDUCTION FROM AN UNSUCCESSFUL REPAIR. DfFINFD BY EE'FltFL UHERE.
                                EL-AVERAfiE EMISSION FACTOR  FOR SOURCES LKAKIHG AT OR ABOVE THE ACTION LEVEL. AND
                                EE'AVERAGE EMISSION FACTOR  FOR SOURCES UHICH EXPERIENCE EARLY LEAK RECURRENCES
                         F2  •  ONE MINUS EMISSIONS REDUCTION FROM A SUCCESSFUL REPAIR.   DEFINED BY EP"F2*EL UHERE EL IS AS DEFINED ABOVE.  AND
                                EP-AVERAGE EMISSION FACTOR  FOR SOURCES LEAKING BELOU THE ACTION LEVEL
                         FE1 " FRACTION OF SOURCES THAT ARE LEAKING AND FOR UHICH ATTEMPTS AT REPAIR HAVE FAILED
                         FE2 " FRACTION OF REPAIRED SOURCES THAT EXPERIENCE EARLY FAILURES

-------
                                         Table E-4.    INPUT DATA FOR EXAMINING THE REDUCTION IN
                                         AVERAGE  LEAK RATE DUE  TO  A MAINTENANCE PROGRAM (PUMPS)
u>
TYPE OF
SOURCE/UNIT
PUHPS
MONTHLY UNITS
THC

VOC

OUART/HONTH UNITS
THC

VOC

QUARTERLY UNITS
THC

VOC

TURNAROUND
El
HE AH (95Z


0.063
( i
O.OS
( ,

0.063
( i
0.05
( i

0.063
( i
0.05
( f
EVERY 12 MONTHS
FF
CD HCAN(93Z CD


0.102
> ( t I
0.102
> ( i )

0.102
> ( f >
0.102
> ( i )

0.102
> ( i 1
0.102
) ( i >
-- FRACTION OF SOURCES
IFL
HEAN (SE)


0.33
( )
0.33
( )

0.33
( )
0.33
( )

0.33
( )
0.33
( )
UNREPAIRED (FED
Fl
HEAN (SE)


1
( )
1
( )

1
( )
1
( )

1
( )
1
( )
IS 0 Al THE
F2
HEAN (SE)


0.13
( )
0.13
( )

0.13
( )
0.13
( )

0.13
( )
0.13
( )
TURNAROUNDS
FE1
HEAN (SE)

i
0
( )
0
( • )

0
( )
0
( )

0
( )
0
( )

FE2
HEAN 



)

)


)

)


)

)

                   El  *  EMISSION FACTOR (KG/HR/SOURCE) FOR ALL SOURCES INITIALLY
                   FF  =  FRACTION OF NON-LEAKING  SOURCES AT THE BEGINNING  THAT HfCOHE LEAKERS
                          (SCREENING VALUE GREATER THAN OR EQUAL TO lOtOOO  PPHV> DURING A 3 HONTH PERIOD  (LEAK OCCURRENCE)
                   IFL = FRACTION OF SOURCES LEAKING INITIALLY
                   Fl  »  ONE HINUS EMISSIONS REDUCTION FROM AN UNSUCCESSFUL  REPAIR. DFFIHEU BY EE*-F1*EL WHERE.
                          EL'AUERAGE EMISSION FACTOR FOR SOURCES LEAKING  AT OR ABOVE THK ACTION I.EVELt AND
                          EE»AVERA(!E EMISSION FACTOR FOR SOURCES UHICH EXPERIENCE EARLY LEAK RECURRENCES             :
                   F2  "  ONE HINUS EMISSIONS REDUCTION FROH A SUCCESSFUL REPAIRi  DEFINED BY EP"F2*EL WHERE EL IS AS DEFINED AkOVE> AND
                          EP'AVERAGE EMISSION FACTOR FOR SOURCES LEAKING  BELOU THE ACTION LEVEL
                   FE1 - FRACTION OF SOURCES THAT ARE LEAKING AND FOR  UHICH ATTEHPTS AT REPAIR HAVE FAILED
                   FE2 « FRACTION OF REPAIRED SOURCES THAT EXPERIENCE  EARLY FAILURES

-------
                             Table E-5.   ESTIMATED EMISSION  FACTORS  AND  MASS  EMISSION REDUCTIONS  (VALVES)
                                          SUMMARY OF ESTIMATED EMISSION FACTORS  (KG/HR) AND FRACTIONAL REDUCTION
                                               IN HASS EMISSIONS. FOR VALVES BY TURNAROUND - MONTHLY  UNITS
                                                THC SERVICE
                                                                                                    VOC SERVICE
TURNAROUND
1
2
3
4
3
HEAN EMISSION-KG/HR
0.0040
0.0033
0.0033
0.0033
0.0033
REDUCTION
0.798
0.835
0.836
0.836
0.836
MEAN EMISSION-KO/HR
0.001S
0.0012
0.0012
0.0012
0.0012
REDUCTION
0.798
0.83S
0.836
0.836
0.836
                                           SUMMARY OF ESTIMATED EMISSION FACTORS  (KG/HR) AND FRACTIONAL REDUCTION
                                               IN HASS EMISSIONS FOR VALVES BY TURNAROUND - QUART/MONTH UNITS
m

o
                                                THC SEItVICE
                                                                                                    VOC SERVICE
TURNAROUND
1
2
3
4
5
HEAN EH1SSION-KO/HR
0.0051
0.0044
0.0044
0.0044
0.0044
REDUCTION
0.745
0.778
0.779
0.779
0.779
MEAN EMISSION-KG/HR
0.0019
0.0017
0.0017
0.0017
0.0017
REDUCTION
0.745
0.778
0.779
0.779
0.779
                                           SUMMARY OF ESTIMATED EMISSION FACTORS  (KG/HR) AND FRACTIONAL REDUCTION
                                               IN MASS EMISSIONS FOR VA1VES BY TURNAROUND - QUARTERLY UNITS
                                                THC SERVICE
                                                                                                    VOC SERVICE
TURNAROUND
1
2
3
4
5
HEAN EMISSION-KG/HR
0.0054
0.0046
0.0046
0.0046
0.0046
REDUCTION
0.732
0.769
0.771
0.771
0.771
MEAN EHISSION-KG/HR
0.0020
0.0017
0.0017
0.0017
0.0017
REDUCTION
0.732
j 0.769
0.771
! 0.771
j 0.771

-------
                         Table  E-6.   ESTIMATED  EMISSION FACTORS AND MASS EMISSION  REDUCTIONS  (PUMPS)
                                        SUMMARY OF  ESTIMATED EMISSION FACTORS   ftMK FRACTIONAL REDUCTION
                                             IN MASS EMISSIONS FOR PUMPS BY TURNAROUND - MONTHLY UNITS
             TURNAROUND
                                  THC SERVICE

                 MEAN EHISSION-KO/HR
                                                             REDUCTION
             VOC  SERVICE

NEAN EHISS10N-KO/HK
                                                                                                                      REDUCTION
1 0.0219
2 0.0219
3 0.0219
4 0.021?
5 0.021?
0.653
0.653
0.653
0.653
0.653
0.0174
0.0174
0.0174
0.0174
0.0174
0.653
0.653
0.653
0.653
0.653
                                       SUMMARY OF ESTIMATED EMISSION FACTORS (KO/HR>  AND FRACTIONAL REDUCTION
                                            IN MASS EMISSIONS FOR PUMPS BY TURNAROUND - QUART/MONTH UNITS
 I
ro
TURNAROUND
                                 THC  SERVICE

                MEAN EMISSION-KO/HR
                                                                                                  VOC SERVICE
                                                REDUCTION
                                                                         MEAN EHISSIOH-KC/HR
                                                                                                         REDUCTION
                                  0.0256
                                  0.0258
                                  0.0258
                                  0,0258
                                  0.0258
                                                 0.594
                                                 0.590
                                                 0.590
                                                 0.590
                                                 0.590
     0.0203
     0.0205
     0.0205
     0.0205
     0.0205
0.594
0.590
0.590
0.590
0.590
                                       SUMMARY OF  ESTIMATED EMISSION FACTORS (KO/HRi AND FRACTIONAL REDUCTION
                                            IN MASS  EMISSIONS FOR PUMPS BY TURNAROUND  - QUARTERLY UHI1S
            TURNAROUND
                                             THC  SERVICE

                            MEAN EMISSION-KO/HR
                                                            REDUCTION
                                                                                      VOC  SERVICE

                                                                         MEAN EMISSION-KO/HR
                                                                                                                     REDUCTION
1
2
3
4
5
0.0262
0.0262
0.0262
0.0262
0.0262
0.5B4
0.584
0.584
0.584
0.584
0.020B
0.0208
0.0208
0.0208
0.0208
0.584
0.584
0.584
0.584
0.584

-------
Table E-7.   FRACTION OF SOURCES SCREENED AND OPERATED ON  BY YEAR (VALVES)
        SUMMARY OF TOTAL FRACTION OF SOURCES SCREENED AND OPERATED  OH FOR VALVES BY YEAR
                                     MONTHLY UNITS
                      THC SERVICE
                                                              VOC SERVICE
YEAR
1
2
3
4
S
TOTAL FRACTION OF
SOURCES SCREENED
12.6653
11.8787
11.9020
11.9020
11.9020
TOTAL FRACTION OF
SOURCES OPERATED ON
0.4082
0.1943
0.1911
0.1910
0.1910
SUMMARY OF TOTAL FRACTION OF SOURCES SCREENED AND
QUART/MONTH UNITS
YEAR
1
2
3
4
5
THC
TOTAL FRACTION OF
SOURCES SCREENED
5.4014
4.3013
4.2664
4.2659
4.2659
SERVICE
TOTAL FRACTION OF
SOURCES OPERATED ON
0.4007
0.1899
0.1867
0.1867
0.1867
SUMMARY OF TOTAL FRACTION OF SOURCES SCREENED AND
QUARTERLY UNITS
YEAR
1
2
3
4
S
THC
TOTAL FRACTION OF
SOURCES SCREENED
4.8975
3.9729
3.9737
3.9737
3.9737
SERVICE
TOTAL FRACTION Of
SOURCES OPERATED ON
0.3980
0.1884
0.1BS4
0.1853
0.1853
TOTAL FRACTION OF
SOURCES SCREENED
12.6653
11.8987
11.9020
11.9020
11.9020
OPERATED ON FOR VALVES
VOC SERVICE
TOTAL FRACTION OF
SOURCES SCREENED
5.4014
4.3013
4.2664
1.2659
4.2659
OPFRATED ON FOR VALVES
VOC SERVICE
TOTAL FRACTION Of
SOURCES SCREENED
4.8975
3.9729
3.9737
3.9737
3.9737
TOTAL FRACTION OF
SOURCF.S OPERATED ON
0.4082
0.1943
0.1911
0.1910
0.1910
BY YEAR

TOTAL FRACTION OF
SOURCES OPERATED ON
0.4007
0.1899
0.1B67
0.1367
0.1867
BY YEAR
1
TOTAL FRACTION OF
SOURCES OPERATED ON
0.3980
0.1884
0.1854
0.1853
0.1853
                                         E-22

-------
Table E-8.   FRACTION OF  SOURCES  SCREENED AND  OPERATED ON BY
                                                                    (PUMPS)
SUHHARY OF TOTAL FRACTION OF  SOURCES SCREENED AND OPERATED OH FOR PUHPS »Y YEAR
                             HONTHLY UNITS
              THC SERVICE
                                                       WOC SERVICE
TOTAL FRACTION OF
YEAR SOURCES SCREENED
1 13.0000
2 12.0000
3 12.0000
« 12.0000
3 12.0000
TOTAL FRACTION Of
SOURCES OPERATED ON
0.7360
0.4080
0.4080
0.4080
0.4080
SUMMARY 01- TOTAL FRACTION OF SOURCES SCREENED ANli
QUART/MONTH UNITS
THC
TOTftL FRACTION OF
YEAR SOURCES SCREENED
1 6.1867
2 4.7107
3 4.7407
4 4.7407
5 4.7407
SERVICE
TOTAL FRACTION OF
SOURCES OPERATED OH
0.7263
0.3956
0.3936
0.3956
0.3956
SUMMARY OF TOTAL FRACTION OF SOURCES SCREEHKD AND
QUARTERLY UNITS
THC
TOTAL FRACTION Of
YEAR SOURCES SCREENED
1 9.0000
2 4.0000
3 4.0000
4 4.0000
5 4.0000
SERVICE
TOTAL FRACTION Of
SOURCES OPERATED ON
0.7243
0.3943
0.3943
0.3943
0.3943
TOTftL FRACTION OF
SOURCES SCREENED
13.0000
12.0000
12.0000
12.0000
12.0000
OfKRATED OH FOh PUHPS
TOTAL FRACTION OF
SOURCES OPERATED ON
0.7380
0.4080
0.4080
0.40SO
0.4080
BY YEAR
VOC SERVICE
TOTAL FRACTION 0*
SOURCES SCREENED
6.1867
4.7407
4.7407
4.7407
4.7407
OPERATED ON FOR PUMPS
TOTAL FRACTION OF
SOURCES OPERATED ON
0.7263
0.3956
0.3956
0.39'j6
0.3956
BY YEAR
VOC SfcKVICE
TOTAL FRACTION Of
SOURCES SCREENED
5.0000
4.0000
4.0000
4.0000
4.0000
TOTAL FRACTION OF
SOURCES OPERATED ON
0.7243
0.3943
0.3943
0.3943
0.3943
                                E-23

-------
Table E-9.    FRACTION OF  SOURCES  SCREENED  AND  OPERATED  ON  BY  MONTH  (VALVES)
                              FRACTION Of TOTAL SOURCE! SCREENED M* OTfRATEO M FM VALVES it MMTH
                                             MMTM.T Utlltl - TMC SERVICE
NONTM
INITIAL
10
11
12
RONTH
INITIAL
1
11
RONTH
INI IAL
10
11
12
FRACTION
SCREENED
1.0000
0.0020
0.0709
0.0740
0.0794
0.0740
0.0724
0.0712
0.04*0
0.0484
0.0470
0.0494
0.0442
1ST
FRACTION
SCREENED
1 .0000
0.0020
0.0740
0.0734
0.0740
0.0724
0.04*8
0.0470
0.0434
0.0442
FRACTION
OCREENED
1.00.0
0.1420
0.1904
0.0700
0.0324
0.0310
0.0710
0.0322
0.*44D
FRACTION
OPERATED
ON
0.1800
0.0348
0.0147
0.0149
8.0142 .
0.0141
0.0141
0.0141
0.0140
0.0140
0.0140
0.0140
0.0408
FRACTIS
TfAR
FRACTION
OPERATED
ON
0.1800
0.0148
0.0145
0.0142
0.0141
FRACTION
SCREENED
.0000
.0080
.0049
.*031
.*014
.0022
.0*08
.0001
.007*
.M4S
.0091
.0814
IN OF TOTAL
2*18

SCREENED
1.0000
FRACTION OF TOTAL
TEAR 2ND
FRACTION
OPERATED
ON
0.1000
0.0244
0.0091
0.0114
0.004*
0.0190
0.004*
0.04BB
FRACTION
SCREENED
0.0488
0.0470
0.0*87
0.0130
O.**01
0.0128
O.*0«0
FRACTION
OJTCRATCB
ON
0.0109
0.0191
0.0145
0.0144
0.0144
0.0144
0.0141
0.0141
8.0141
0.0141
0.0143
0.0304
OOURCI1 81
MNTNLT
TCAR
FRACTION
ON
0.0103
FRACTION
SCREENED
1.0000
0.0001
0.0*40
O.*054
0.0*3*
0.0025
O.M1I
O.ODV4
0.0882
0.0840
0.0834
0.0810
VNITO - VOC 01
WB

OI:REENED
1.0000
SOURCES SCREENED AND OPE
TEAR
FRACTION
ON
0.0104
0.0021
0.03*1
0.0030
0.034S
0.0050
0.0503
1RD

SCREENED
0.0501
0.04*5
0.0*01
0.0330
0.0370
O.*043
FRACTION
OPERATED
ON
0.0140
0.0147
0.014S
0.0144
0.0144
0.0144
0.0141
0.0141
0.0141
0.0141
0.0141
0.8101
•MICE
TEAR
FRACTION
ON
0.0140
RATEII OR FOR
TEAR
FRACTION
ON
0.0074
0.0014
0.0143
0.0030
0.0030
0.0010
0.0500
FRACTION
SCREENED
1.0000
0.0081
0.0*40
0.0*54
O.**40
0.0023
O.**ll
0.08*4
0.*8S2
0.0048
0.«S34
0.081*
4TH

SCREENED
1.0000
FRACTION
OPERATED
ON
0.0140
0*0147
0.0143
0.0144
0.0144
0.0144
0.014
0.014
0.014
0.014
0.014
0.010
TEAR
FRACTION
ON
0.014*;
VALVES BT NONTH
4TH TEAR

SCREENED
0.0500
O.***l
0.0120
•O.0330
0.0320
0.0323

FRACTION
ON
0.0073
0.0143
0.0050
0.0030
0.0030
0.0010

FRACTION
OCREENED
1.0000
o.ooo*
0.0040
O.*034
0.0040
0.0023
0.0011
0.08*4
0.0082
0 . 0040
0.0034
0.081*
5TN

SCREENED
1.0000
O.**03
0.0*40
.*040
0.003*
STN

SCREENED
0.0900
0.04*7
O.»**l
0.032D
0.0130
0.012B
0.0323

FRACTION
OPERATED
ON
.0140
.0147
.0143
.0144
.0144
.014
0.014
0.014
0.014
0.014
0.014
0.0301
TEAR
FRACTION
ON
0.0140
0.0147
0.0143
0.0143
0.0303
TEAR
FRACTION
ON
0.0075
0.0014
0.0343
0.0030
0.0050
0.0145
0.0050
0.0010

                              FRACTION OF TOTAL ImMCFO SCREENtO AND OFERATEO ON FOR VALUES OT AONTH
                                              OUART/NONTH UNIT! - DOC SERVICE

1ST
FRACTION
MONTH SCREENED
INI
I
1
i:
IAL 1.0000
0.1420
0.0301
•.0324
9.9710
0.0322
•.0317
Q.fAAtt
YEAR 2ND
FRACTION
ON SCREENED
9.1IOO
0.0244
O.M4S
0.004V
0.035S
O.M4f
9,9919
0.0AM
.04H
.0323
.0330
.0323
.0323
.fS40
YCAR
TRACTION
3RD

OH SCREENED
0.0104 •
0.004
0.003
0.001
•.034
0.001
0.050
0
0
0
0
0
.0503
.032S
.0330
. TfO*
.0323
.fD43
TfAR
FRACTION
ON
0.0074
•.0030
•.0030
0.0343
O.OSOO
4TH

SCREENED
0.0300
0.032R
0.0330
0.ftA3
VCAR
TRACT I UK
OH
0.0073
0.0020
0.0050.
O.OOSO
0.0500
STH

SCREENED
0.0300
0.0321
0.0330
0.032D
O.VS43
YEAR
FRACTION
ON
0.0075
0.0030
0.0010
0.0050
0.0010
0.0030
O.OSOO
                              FRACTION OF TOTAL SOURCES SCREENED AND OFCRATF.fl ON FOR VALUES ST MONTH
                                             OUARTCMLV UNIT* - THC SERVICE
NO.
INI
a
i
i
FRACTION
•TH SCREENED
IAL
i
t
.0000
F.OOOO
.0000
of 120
.000*
.0000
.f741
oOOOO
.0000
oTTIS
.0000
.0000
.f47*
FRACTION
QPF.RATED FRACTION
ON SCREENED
O.ltOO
0.0000
0.0000
•.0917
•oOOOO
0.0000
0.0437
O.OOOO
•.0000
0.0411
0.0000
0.0000
«.07»
1.0000
>.oooo
.0000
.0000
,00«
.ffS]
.0000
.0000
,ffO»
.0000
.0000
.fS47
FRACTION
OPERATED
ON
0.0000
0.0000
0.0475
0.0000
0.0000
0.0431
0.0000
•oOOOO
0.0424
0.0000
0.0000
0.03S9
FRACTION
SCRF.F.NFD
0.0000
0.0000
1.0009
0.0000
O.OOOO
o.ftsa
0.0000
0.0000
O.M12
0.0000
0.0000
0.9B70
FRACTION
OPERATED
ON
0.0000
0.0000
0.0430
•.0000
0.0000
0.047H
0.0000
OoOOOO
0.0000
0.0000
0.0332
FRACTION
fCRFtMCP
0.0000
0.0000
1.0000
0.0000
0 . 0000
O.ffSS
0.0000
0.0000
0.0000
o.tooo
O.W70
FRACTION
OPERATED
ON
0.0000
0.0000
0.0430
0.0000
OoOOOO
0.042B
0.0000
0.0000
OoOOOO
0.0000
0.0352
FRACTION
SCREENED
0.0000
0.0000
1.0000
0.0000
0.0000
•.f»35
0.0000
0.0000
O.OOOO
0.0000
0.fS7l
FRACTION
OPERATED
ON
0.0000
0.0000
0.0430
0 . 0000
0.0000
0.042S
0.0000
0.0000
0.0000
•.0000
• o 0532
                              FRACTION OF TOTAL SOURCES SCREENED AND OPERATED W FOR VALVES DT MWTN

iff TEA* MO
FRACTION
FRACTION OPERATED FRACTION
MNTH SCREENED ON SCREENED
INI
i
i
i:
IAL
:
,•0*10
.MM
.MO*
.f020
.0000
.MM
.0000
.•000
.f7H
.0000
.0000
.9474
t. 1IKIQ
.•MO
.MOO
.05S7
.MO*
.•400
.0000
.0000
.041.1
.•000
.0000
.•73S
,.0000
.0000
.0000
.MM
.MOO
.0000
.0000
off Of
.0000
.0000
.fS47
YCAN
FRACTION
OPERATED
ON
•.OOOO
0.0000
0.047S
0.0000
0.0000
OoOOOO
0.0000
•.0424
0.0000
•.OOOO
•.0333
3RD
FRACTION
SCREENED
0.0000
0.0000
1.0000
0.0000
0.0000
O.ffSS
0.0000
0.0000
O.ffl?
0.0000
0.0000
•.tore
TEAR 4TH
TRACTION
OPERATED FRACTION
ON SCREENED
0.0000
0.0000
0.0430
0.0000
•.OOOO
0.042S
0.0000
•.OOOO
•.0474
•.OOOO
0.0000
0.0332
,.0000
.0000
.0000
.0000
.OOOO
.ffSS
.0000
.0000
.V*12
.0000
.0000
.9970
YEAR
FRACTION
Off RATED
ON
• .MOO
•.OOOO
0.0430
0.0000
• .MOO
0.012*
0.0000
0.0000
0.0424
0.0000'
0.0000
••0332'
STH TEAR
FRACTION
FRACTION OPERATED
SCREENED ON
• .MOO
•.OOOO
1.0000
0.0000
•.OOOO
O.VV33
0.0000
•.OOOO
O.f*12
O.OOOO
0.0000
0.9970
.0000
.0000
.0410
.0000
.0000
.042S
.0000
.0000
.0424
.0000
.0000
.0332

-------
Table  E-10.   FRACTION OF  SOURCES  SCREENED  AND OPERATED  ON BY MONTH (PUMPS)
                          I •» I»l«l MIMCLI icitlno Ml ortMtct •* rut rum »T
                                 •MI«.T (Mill - IK U'VICC
M*TN
Ml IAL
1
1
1
111 IAL
1
II
12
INI IAL
11
12
F
FRACTION 01
OCRCCNCB
.MO*
.•999
.9000
.MM
.•MO
.MM
.9009
.9999
.•990
.MM
.MM
1»T TCM
F
OCRKINCB
.MOO
.9999
.9990
.9999
.MOO
.9009
.•000
.•000
.••99
.9009
.9999
.90*4
IBT YfM
•ACTION
ON
.1199
.9149
.9149
.914*
.9149
.9149
.9349
.9140
!oi40
FOACTION
ACTION
ON
.1100
.0140
.9149
.•149
.9140
.•146
.6146
.0140
.9149
.9349
.9149
.9149
FRACTION
1
FR AC 11 OH
BCRCCNCB ON
1 OM0 O.IOM
0 Jl** •.•112
1 •••• O.*771
• *771 O.M24
1 MM •.•*!*
• 6*25 0.9031
• 9*25 9.9011
1 9990 9.9*2*

BCMCNiB
I.MM
I.MOO
1.0000
I.M90
I.MO
I.MO
I.MO
1.999
1.9999
1.0000
OF TOTAL
MB

•CRCCNCB
..
I.MO
I.MO
I.MO
1.000
I.MO
|.0«0
I.MO
1.9000
1.4000
I.MOO
OF TOTAL
MB

BCRCCNCB
0 O*3*
1 4000
• 9*3*
1 M99
9 6*2*
I 0000
FRACTION
ON
•1«140
•••140
•.•140
•.•140
•.•14*
•.•149


I.M96
1.9999
1.9990
1.999
1.900
FRACTION
ON
•.•140
•.•140
0.*140
•.0149
9.9149
•••149 1.990 •••140
•!*i4o I!MM oloato
•OUNCCf BCRCCNCB M» OttkftTCH ON F0«
ftONTNLT IMITB - VOC BCRW1CC
TCM lk» T»M
FRACTION
ON
«
0.0140
*.*140
•.•140
0.6346
•.•140
•.•140
•.•140

•CM.CNCB
«
1.9990
1.9099
1.9009
I.M09
l.«999
1.9990
I.MOO
FRACTION
ON
•.0149
•••149
9.9149
•••140
0.9340
0.0140
•••140
•.0149
•.0140 1.0009 •,0140
• .0140 I.MOO •.•140
0.0140 t.M*0 0.0140
•OURCCt BCNICRCB ANB OfCBATCB ON FO*
OUMt/MONfM VNlfV - INC BCRV1CC
TCM MB TLA*
FRACTION
ON
• Mil
• Mil
• **24
• 0031
9 0*2*

•CBCIHIB
O.O*2*
1.9900
•,••2*
1.9990
0.0*2*
0.0*2*
1.0000
f •ACTION
ON
• .Mil
• .Mil
•.•*3*
O.M11
•.0*2*
0.0011
0.0031
0.0*2*
FRACTION
BCRCLNC*
1.9009
1.9009
1,9000
1.M09
I.0000
I.MOO
1 .0009
1.0999
1.9999
1.9999
I.MM
POTT* OT Ml
4TN

•CRCCNCB
1.4000
1.0900
1.0000
1.0000
1.0000
1.0900
I.MOO
1.0000
1.0000
1.0000
1.0000
PIMM BT MM
4TN

•CRLtNCU
9.4*24
•-•*?*
I.M99
•.9*3*
I.MOO
•••*24
I . 9990
0.9*24
1.0400
FRACTION
OPCRATCB
ON
•.•140
•••140
*.*140
•.9140
4.4140
•.•14«
O.*140
•.4140.
O.OJ49
0.0140
TH
TCM
FRACTION
ON
•-•140
9.0140
•.0140
0.0140
•.•140
•.•140
0.0140
0.9140
0.0140
9.9140
0.0149
TN
TCM
FRACTION
OR
O.M11
• .Mil
•!*011
•.•*24
•.0031
•.**:.•*
0.9031
9.9*24i
FRACTION
FRACTION OPCRATCB
Bty !«*»-_ ON
I.O**9
I.M99
I.MOO
I.MM
I.MM
I.999O
I.MOO
1.9009
1.9999
I.MM
I.MM
STM

BCNCKMB
1.9999
I.MM
I.MOO
I.MM
I.MOO
1.0000
1.0000
1.M69
1.9999
1.9900
I.MOO
I.MM
•TN

•CRCCNXB
0.0*2*
0.**2*
1.90*0
•.0*3*
I.MOO
•.0*24
•.0*2*
1.0*00
9.9*2*
•.9*2*
1.9900
•.•149
•••149
0.9140
•.•140
•.•149
•.•349
•••149
•.•140
•.•14*
•••140
•.•J4*
TIAR
FRACTION
ON
•.•140
*.*140
*.*14»
•.0140
•.9149
•.•140
•.•140
•.•140
•.•140
0.0140
•.0140
•.•340
TCAR
Ft ACT ION
ON
• .Mil
•.•011
4.4*2*
• .Mil
0.0*3*
•.9011
•••Oil
•.9*2*
9.9911
•.9011
0.0*3*
WH
INI
I
1
1
IBT

ITM BCftCCNCB
IAL
1
.9999
.J100
.1100
.M00
.0771
.MOO
.9*14
.9669
.•099
TtAR 2MB
FRACTION
OH tCtCCHCD
9.11*9
9.0113
*.OM2
•.9934
•.•*14
0.0033
0.0*29
•.0*2*
.0*34
.0*24
.0*24
.•000
.0*74
.0060
.9009
TtAK MB
FRACTION
OH BCRCCNCB
9.0031
• .Mil
• .Mil
•.9*24
9.9911
9.9*24
•.0*24
.9*24
.9*24
.4*34
.9*24
.•000
.9*34
.0*34
.4000
.0*7*
.MOO
MA*
FRACTION
ON
• .Mil
•.•031
•.0011
•.9911
0.0*34
0.9011
0.9031
9.6*2*
0.0031
9.0*2*
4TM

•CfttlNl*
--
9.9*34
9.9*24
1.0000
•.0*24
•.0*7*
I. 0000
•.0*2*
1.9900
TCM
FRALT10H
ON
..
;••;»
9.9911
4.4*:*
•.•911
•.0031
•.9*2*
9.9031
•.0*24
JTN

•CRCCNiP
..
0.9*34
1.M99
9.9*24
•.4*1*
1.9000
•••*2*
0.0*2*
1.0000
9.0*2*
9.9*24
1.9990
TFAR
FRACTION
ON
-
9.9031
9.0*24
•.9911
9. Mil
9.0*24
9.9011
9.9031
9.9*24
0.0031
9.0011
9.9*2*
FRACT
IBT TCAR
FRACTION
FRACTION OPCRATCB
MN1M BCAUNCB ON
INITIAL I.MOO •.!!••
O.M90
.9990
.M99
.4900
.MOO
.M49
.M««
| .0000
I .9999
I .0040
UT TCAI
F
FRACTION 04
NOWTN CCRCCNCB
INI IAL 1 MM
• M99
• M99
1 OM9
• M99
• MM
I MM
• MM
• M99
1 MM
1 • M90
I • MOO
12 1 MM
.•090
.9000
.•*•*
.0009
.0*0*
.••99
.**•*
.9000
.•000
.•*•*

ACTION
CRATCB
ON
.11*0
.MOO
.0900
.0*9*
.9009
.9000
.•*•*
.MM
.•094
.0*04
.MOO
.M94
*•*••
2N»
FRACTION
•CRCCNCB
„
••••00
•.0000
1.0000
•.0000
1.0060
0.0999
1.4000
9.9069
•.9600
1.M99
2W
FRACTION

O.MM
•.•066
I.OOOO
9.9999
•.9999
I.M69
• .MM
•.000*
I.MM
0,000*
•.••99
I.90M
OUARUKLT
TCM
FRACTION
ON
..
•.•099
0.6900
•.•*•*
9.9099
6.9*1*
4.4000
•.•V04
4.0OO0
0.0004
•.•*•*
•UftRTCIlT
TCM
OfCRATCB
ON

O.MM
•.•006
•••*•*
4.00*0
0.4000
*.**•*
O.MM
O.MM
•.«*•*
••••06
O.M0*
*.•*•*
UNIT* - THC
FRACTION
•CRCLNiB
..
*.MOO
.0000
.0066
.6000
.0000
.0000
.0000
.OOOO
.0606
.•606
UNITt ' VOC
IRB
BCRCCNCB

.•MO
.0660
.0*60
.0MO
.MOO
.0000
.0990
.0*04
.9999
.9999
.M66
.9909
BCRWICC
TFM
FRACTION
OfCRATCB
ON
..
O.MOO
•.•009
*.0»B4
•.9009
*.**•*
•.•999
*.**«4
•.•999
4.4000
•••«•*
BCRV11C
TI.AR
f CACTI OH
QfCfcAIC*
ON

O.OMO
9.M90
•.•*•*
9. MOO
O.M90
*.•*•*
O.MM
• .MOO
•.•*•*
•.•990
•.•999
*.9*0*
4TM
FRACTION
BCRCLNIft
..
9.9990
9. OOOO
1.0000
•.OOOO
1,4000
9.M09
1.9099
9. MOO
4.0000
1.9990
4TH
FRACTION
•CRCCNCB

9.9999
•••000
1.0000
9.9999
9.9999
1.9000
•.••00
•.4000
I.MOO
•.•009
•.0009
I.MOO
TCAR
FRACTION
OPCRA1CD
ON
._
• .•MO
• . 4000
• . 0*04
•.9900
9.9***
*.MOO
*.***4
9.9090
0.9009
9.9*«*
TCAR '
FRACTION
OPCRATCV
•N

9.M96
•.OOOO
4.0V44
•.•090
•.•000
•••*•*
•.•000
«.M60
•••*•*
•.•060
••••60
•••»•*
3TN
INACTION
•CRCCHt •
„
• . 00*0
•.•066
1.0090
9.9906
1 . 9669
• i*660
0.0000
I.M09
9.9009
•.•666
1.0000
5TN
FRACTION
tCRCINtO

•.0400
9.0906
1 . 9966
9.6996
• .MM
1 .MOO
9.9990
9.9906
1 . OOOO
• .••M
• . 0000
I.MOO
TCM
FRACTION
OPCRATCD
ON
„_
•.9999
•.••00
•.•*94
•.0090
•••*•*
•••000
9. MOO
*.*»•*
•••000
• >4000
•.•••4
TtAR
FRACTION
OPCRATCB
ON

A AAAB
•*AAOA
4.4*4*
9.M90
*. 0000
*.**•*
• .MM
•••000
•>•*•*
• . MOO
9.9966
9.9*0*

-------
Table  E-ll.    ESTIMATED EMISSION  FACTORS  AND  MASS EMISSION  REDUCTION
                                    BY QUARTER  (VALVES)
                         ESTIMATED EHIfllON FACTORS (KI/HIt) AND FRACTIONAL REDUCTION
                          IN MASS EMISSIONS FOR VAI.VEI IT CHARTER - MONTHLY UNITS
PERIOD
11 HONTHS)
1
2
I
4
1
t
1
1
»
to
11
12
11
14
13
It
17
11
IT
20
T*C SERVICE VOC SERVICE
MEAN ENISSION-KS/NR REDUCTION MEAN EM1SSION-KG/HR
0.0041
0.0018
0.0038
0.001*
0.001*
0.001*
0.0040
0.0040
0.0041
0.0041
0.0042
0.0042
0.0012
0.0011
0.0031
0.0032
0.0032
0.0033
0.0011
0.0014
.711
.SOS
.SO*
.007
.105
.803
.800
.7*8
.7*3
.7*3
.7*0
. 7BB
.841
.84*
.844
.842
.83*
.837
.834
.832
.001*
.0014
.0014
.0014
.0015
.0013
.0013
.0015
.0013
.0014
.001*
.001*
.0012
.0012
.0012
.0012
.0012
.0012
.0012
.0013

REDUCTION
0.783
0.808
0.80*
0.807
0.803
0.803
O.SOO
0.7*8
0.795
0.7*3
0.7*0
0,788
0.841
0.846
0.844
0.842
0.83*
0.837
0.814
0.832
                         ESTIMATED EMISSION FACTORS (KG/HR) AHI1 FRACTIONAL REDUCTION
                          IN MASS EMISSIONS FOR VALVES 8T OIlnRTFK - BUART/MONTH UNITS
PERIOD
(3 MONTHS)
1
2
3
4
3
t
7
8
»
10
11
12
13
14
13
1*
17
18
1*
20
THC SERVICE
MEAN ENISSION-KO/HR
0.004*
0.0030
0.0032
0.0023
0.0042
0.0044
0.0043
0.0046
0.0042
0.0044
0.0045
0.004*
0.0042
0.0044
0.004S
0.004*
0.0042
0.0044
0.0043
0.004*

REDUCTION
0.733
0.74*
0.742
0.733
0.786
0.782
0.775
0.7*8
0.78*
0.782
0.773
0.7*8
0.78*
0.782
0.773
0.7*8
0.78*
0.782
0.773
0.7*8
                                                                          VOC SERVICE
                                                               MEAN EHISSION-KG/HR

                                                                    0.001*
                                                                    0.001*
                                                                    0.001*
                                                                    0.0020
                                                                    0.001*
                                                                    0.001*
                                                                    0.0017
                                                                    0.0017
                                                                    0.001*
                                                                    0.001*
                                                                    0.0017
                                                                    0.0017
                                                                    0.001*
                                                                    0.001*
                                                                    0.0017
                                                                    0.0017
                                                                    0.001*
                                                                    0.001*
                                                                    0.0017
                                                                    0.0017
0.753
0.71*
0.742
0.735
0.7BB
0,782
0.775
0.7*8
0.78*
0.782
0.773
0.7*U
0.78*
0.782
0.773
0.7*8
0.78*
0.782
0.775
0.7*8
                         ESTIMATED EMISSION FACTORS (KG/HR) AHIi FRACTIONAL REDUCTION
                          IN MASS EMISSIONS FOR VALVES 8V DUARTER - OUARTERLT UNITS
THC SERVICE
(1 MONTHS) MEAN EHISSION-K6/HR REDUCTION
1 .0053
2
3
4
3
*
7
8
»
10
11
12
13
14
13
1*
17
18
1*
20
.0032
.0033
,0054
.0045
.0045
.0047
.0048
.0044
.0045
.004*
.0048
.0044
.0043
.004*
.0048
.0044
.0045
.004*
.0048
.724
.73*
.735
.72*
.774
.774
.7*7
.7*0
.77*
.77!
.7*8
.7*1
.77*
.775
.7*8
.7*1
.77*
.773
.7*8
.7*1
VOC SERVICE
MEAN EMISSION-KO/HR
0.0021
0.0020
0.0020
0.0020
0.0017
0.0017
0.0017
0.0018
0.0017
0.0017
0.0017
0.0018
0.0017
0.0«17
0.0017
0.0018
0.0017
0.0017
0.0017
0.0018

REDUCTION
0.724
0.73*
0.733
0.72*
0.774
0.774
0.7*7
0.7*0
0.77*
0.775
0.7*8
0.7*1
0.77*
0.773
0.7*8
0.7*1
0.77*
0.775
0.7*8
0.7*1
                                            E-26

-------
Table  E-12.   ESTIMATED  EMISSION  FACTORS  AND  MASS  EMISSION REDUCTION
                               BY QUARTER (PUMPS)
                       CITIMTEI E«IIIION FACTORS C«O/M«> *NI> FRACTIONAL REDUCTION
                        m MII EHiiiiONt ro* ruitrt IT QUARTER - MWTHLT IWITI

(I MONTHS) KM 11
1
3
1
4
9
4
7
(
*
10
tl
12
11
14
IS
14
17
II
1*
20
TNC SERVICE
18810N-KI/HR II
.021*
.021?
.021*
.021* '
.021*
.021*
.021*
.021*
.021*
.021*
.021*
.021*
.021*
.021*
.021*
.0:1*
.021*
.021*
.021*
.021*

DUCTION MEAN Cl
.453
.193
.431
.451
.431
.433
.433
.4=3
.453
.453
,403
.411
.433
.413
.433
.413
.433
.453
.433
.453
VOC URVICE
IISS10N-KI/HR t
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174
.0174

EDUCTION
.433
.433
.433
.453
.433
.433
.433
.453
.433
.433
.453
.433
.453
.453
.433
.423
.433
.453
.433
.433
ESTIMATED EMISSION FACTORS (KB/MR) AN1I FRACTIONAL Id DUCT ION |
IN MASS missions FOR ruHPS iv OUAKTER • OUAKI/HUNIH unlit i
i
THC liRVICC VOC ICRVICt 1
II MONTHS) HEAN EMISSION-KB/HR REDUCTION MEAN EHISSIOH-KG/HR REDUCTION
1
2
3
4
3
4
7
1
»
10
11
12
11
14
15
14
17
11
1*
20
.0241
.023*
.0251
.0251
.0251
.0231
.0231
.0231
.0238
.0231
.0231
.0251
.0230
.0251
.0251
.0258
.025f
.0251
.0258
.0258
.407
.38*
.5*0
.3*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.01*7
.0205
.0205
.0205
.0203
.0205
.0205
.0205
.0203
.0205
.0205
.0205
.0305
.0205
.0305
.0205
.0205
.0205
.0205
.0203
.407
.58*
.3*0
.5*0
.5*0
.3*0
.5*0
.5*0
.3*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.5*0
.3*0
.5*0
.3*0
.3*0
                       EITIHATED ENIIIION FACTORS (KO/HRI AH1I FRACTIONAL KIDUCTION
                        I* HAVE EHISS10NS FUR PUHPS IT QUARTER - OUARTERLT UNITS
PER
(3 KOI
THC (ERVICE VOC SERVICE
ITHS) MEAN EN1S$10H-KO/HR REDUCTION HEAN CHISIION-KO/MR REDUCTION
1
2














10
It
12
11
14
15
14
17
11
1*
20
.0242
.0242
.0242
.0242
.0242
.0343
.0242
.0242
.0242
.0242
.0342
.0343
.0342
.0242
.0243
.0342
.0242
.0342
.0242
.0242
.314
.384
.384
.584
.384
.584
.384
.584
.384
.584
.584
.584
.384
.584
.384
.384
.584
.314
.584
.384
.0208
.0201
.0208
.0208
.0208
.0208
.0308
.0308
.0308
.0208
.0308
.0208
.0208
.0208
.0208
.0308
.0308 '
.0208 :
.0208 '
.0208
.584
.384
.384
.514
.584
.584
.584
.304
.58*
.38'!
.384
.384
.584
.384
.384
.314
.384
.384
.384
.514
                                        E-27

-------
Table E-13.   FRACTIONAL  DISTRIBUTION  OF  SOURCES  BY  PERIOD  (VALVES)
                       F«*CTIOM«L DISTRIBUTION Or SOURCES FOR VAI VES IT PERIOD
                                 NOHTHir UNITS - THC ft.RVICE
FRACTION OF LF.AKERSt FRACTION OF FRACTION (IF SOURCES FRACTION OF SOURCES
DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERIENCING EARI » FAILURE OPCKA1 INO PROPERLY
PERIOD IEOINNINO END IEOIHNINO END BEGINNING END BEGINNING END
(1 HONTNS) OF PERIOD OF PERIOD OF PERIOD OF PIRIOD OF PER I OH OF PERIOD OF PERIOD OF PERIOD
INITIAL
1
2







10
11
12
13
14
IS
1*
17
IB
1»
20
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.ISO
.012
.012
.012
.012
.012
.012
.012
.012
.012
.012
.012
.012
.013
.013
.013
.013
.013
.013
.013
.013
.01S
.021
.023
.021
.02*
.027
.02*
.030
.032
.033
.034
.03*
.000
.002
.003
.005
.006
.001
.00*
.011
.000 	
.019
.021
.023
.025
.021
.027
.02*
.030
.032
.033
.034
.03*
.000
.002
.003
.001
.004
.008
.00*
.011
.0227
.0044
.0021
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0070
.0023
.001*
.0018
.0018
.0018
.0018
.0018
.0000 ' 	 0.820
.0227 0.»S» 0.»47
.0044 «.*74 0.942
.0021 0.»7S 0.»*2
.0018 0.*74 0.941
.0018 0."72 O.»40
.0018 0.971 0.159
.0018 0.*** 0.957
.0018 0.»*8 0.»S4
.0010 0.»*7 0.954
.0018 0.»»5 0.953
. 001H 0.944 0.952
.0018 0.»42 O.»50
.0070 0.**3 0.980
.0025 0.994 0.983
.001* 0.995 0.982
.0018 0.**3 0.981
.0018 0.992 0.979
.0018 0.990 0.978
.0018 0.989 0.974
.0018 0.988 0.975
• LEAKERS REFERS TO TNOSE SOURCES SCREENING GREATER THAN OK EQUAL TO 10 > 000 PPHV.
                       FRACTIONAL DISTRIIUTION OF SOURCES FOR VALVES IT PERIOD
                                 NONTHLT UNITS - VOC SERVICE
FRACTION OF LEAKERSt FRACTION OF FRACTION OF SOURCES
DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERIENCING EARI T FAILURE
PERIOD BEGINNING END BEGINNING END BEGINNING
(1 MONTHS) OF PERIOD OF PERIOD OF PERIOD OF PERIOD OF PERIOD
INITIAL
1
2
3
4
3
4
7
a
*
10
11
12
13
14
IS
14
17
18
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
1* 0.000
20 0.000
.110
.012 0.018
.012 0.021
.012
.012
.012
.012
.012
.012
.012
.012
.012
.012
.013
.013
.01]
.013
.013
.013
.013
.013
.023
.025
.024
.027
.02*
.030
.032
.033
.034
.034
.000
.002
.003
.005
.004
.008
.00*
.011
.000
.018 0.0227
.021 0.0044
.023
.025
.024
.027
.029
.030
.032
.033
.034
.034
.000
.002
.003
.005
.004
.008
.00*
.011
.0021
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0018
.0070
.0073
.001*
.0018
.0018
.0018
.0018
.0018
1 LEAKERS REFERS TO THOSE SOURCES SCREENING GREATER THAN OR EQUAL TO 10.000 PPHV.
END
Of PERIOD
0.0000
0.0727
0.0044
0.0021
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0070
0.0023
0.001*
0.0018
0.0018
0.0018
0.0018
0.0018

FRACTION
OPERATING
BEGINNING
OF PERIOD
	
0.959
».»74
0.»73
0.»74
0.9X2
0.971
0.94*
0.948
0.947
0.9*5
0.944
0.942
0.993
0.994
0.9*3
0.993
0.*»2
0.990
0.989
0.988

OF SOURCES
PROPERLY
END
OF PERIOD
0.120
0.947
0.942
0.942
0.941
0.940
0.959
0.957
0.954
0.954
0.953
0.932
0.930
0.980
0.983
0.982
0.981
0.97*
0.978
0.974
0.»7S

                       FRACTIONAL DISTRIBUTION OF SOURCES FOR VALVES BY PERIOD
                                 OUART/MONTH UNITS -  THC SERVICE
FRACTION OF LEAKERS* FRACTION OF FRACTION OF SOURCES FRACTION OF SOURCES
DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERIENCING EARLY FAILURE OPERATING PROPERLY
PERIOD BEGINNING END BEGINNING END BEGINNING END BEGINNING END
(3 BONIHS) OF PERIOD OF PERIOD OF PERIOD OF PSRIOH OF PERIOD OF PERIOD OF PERIOD OF PERIOD
INITIAL 	
1
2







10
11
12
13
14
IS
14
17
18
1*
20
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.004
.000
.000
.000
.000
.000
.000
.000
.000
.180 — - 0.000 — 0.0000 	 0.820
.033
.034
.034
.033
.034
.037
.034
.034
.034
.037
.03*
.03*
.034
.037
.034
.034
.034
.037
.034
.034
.018
.024
.028
.033
.000
.005
.00*
.013
.000
.005
.00*
.013
.000
.005
.00*
.013
.000
.005
.00*
.013
.021
.025
.02*
.033
.001
.005
.010
.014
.001
.005
.00*
.014
.001
.003
.00*
.014
.001
.005
.00*
.014
.0227 0.0004
.0042 0.0001
.0045 0.0001
.0045 0.0001
.00** 0.0003
.0049 0.0001
.0044 0.0001
.0044 0.0001
.0070 0.0002
.0044 0.0001
.0044 0.0001
.0044 0.0001
.0070 0.0002
.0044 0.0001
.0044 0.0001
.0044 0.0001
.0070 0.0002
.0044 0.0001
.0044 0.0001
.0044 0.0001
.*S» 0.*44
.971 0.939
.»4T 0.»33
.943 0.931
.*TO 0,943
.**! 0.958
.*84 0.954
.982 0.950
.993 0.943
.991 0.958
.987 0.954
.982 0.950
.993 0.943
.991 0.958
.987 0.954
.*82 O.*30
.993 0.943
.991 0.958
.987 0.934
.982 0.950
• LEAKERS REFERS TO THOSE SOURCES SCREENING GREATER THAN OR EQUAL Til 10.000 PPNV.
                                          E-28

-------
        Table  E-13.    CONCLUDED
 FRACTIONAL  IIITRIIUTION OF tOUKCKI FOR VALVEI IT PERIOD

FRACTION OF LEAKERSt FRACTION OF FRACTION Of SOURCES FRACTION OF SOURCES
DUE TO OCCURRENCE UNREPAIRED SOURCE! EXPERItHC INK IARIV FAILURE OPCKATINi; PROPERLY
PERIOD IEOINNING END IEGIHNINO END tECIKHIHG FHD IEGINNIHG END
(3 HONTHS) OF PERIOD OF PERIOD OF PERIOD OF PFRIOD OF PFRIOD OF PERIOD OF PERIOD OF PERIOD
INITIAL
|
3
1
4
9
4
7
«
»
to
11
12
11
14
IS
1*
17
11
If
20
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.180
.03]
.03*
.034
.033
.034
.037
.034
.03*
.034
.037
.034
.034
.034
.037
.034
.034
.034
.037
.034
.034
.018
.024
.026
.033
.000
.005
.00?
.013
.000
.00:
.00*
.013
.000
.003
.OOf
.013
.000
.005
.009
.013
.000 - — 0.0000 	
.021
.025
.02*
.033
.001
.005
.010
.014
.001
.005
.009
.014
.001
.005
,00V
.014
.001
.005
.OOf
.014
.0227 0.0004 O.fSf
.0042 0.0001 «.f71
.0045 0.0001 0.947
.0043 0.0001 4.943
.009* 0.0003 *.ffO
.0045 o.oooi e.ffi
.0044 0.0001 0.986
.0044 0.0001 0.fB2
.0070 0.0002 0.993
.0044 0.0001 O.ffl
.0044 0.0001 0.987
.0046 0.0001 0.982
.0070 0.0002 0.993
.0044 0.0001 O.ffl
.004« 0.0001 0.907
.0044 0.0001 O.f82
.0070 0.0002 0.993
.OO44 0.0001 0.991
.820
.f44
.f3f
.935
.931
.963
.958
.954
.fSO
.963
.958
.954
.fSO
.963
.950
.954
.950
.963
.958
.0044 0.0001 0.987 0.954
.0044 0.0001 0.982 0.750
> LEAKERS REFERS TO THOSE SOURCES SCREENING GREATER THAN OR EOUAL TO 10.000 PPHV.
FRACTIONAL DISTRIIUTION OF SOURCES FOR VALVES IT PERIOD
           QUARTERLY UNITS - THC SERVICE
FRACTION OF LEAKERSI FRACTION OF FRACTION
DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERIENCING
PERIOD
(3 HONTMS)
INITIAL
1
2
3
4
5
4
7
1
9
10
11
12
13
14
IS
16
17
19
If
20
t LEAKERS
IEGIHNINO END IEGINNING
OF PERIOD OF PERIOD OF PERIOD
	
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.110
.034 0.018
.034 0.024
.034
.036
.037
.037
.037
,037
.037
.037
.037
.037
.037
.037
.037
.037
.037
.037
.037
.037
.028
.032
.000
.005
.OOf
.013
.000
.004
.009
.013
.000
.004
.009
.013
.000
.004
.OOf
.013
REFERS TO THOSE SOURCES SCREENING GREATER
END IEGINNING
OF PERIOD OF PFRIOD
0.000 	
0.018
0.024
0.028
0.032
0.000
0.005
O.OOf
0.013
0.000
0.004
0.009
0.013
0.000
0.004
0.009
0.013
0.000
0.004
O.OOf
0.013
.0227
.0074
.0055
.0053
.0103
.0040
.0054
.0053
.0078
.0057
.0054
.0053
.0077
.0057
.0054
.0033
.0077
.0057
.0054
.0053
THAN Ok EQUAL TO 10.000 PPHV
OF SOURCES
EARLY FAILURE
END
OF PERIOD
0.0000
0.0227
0.0074
0.0055
0.0053
0.0103
0.0040
0.0054
0.0053
0.0078
0.0057
0.0054
0,0053
0.0077
0.0057
0.0054
0.0033
0.0077
0.0057
0.0054
0.0053
.
FRACTION
OPERATING
IEGIHNIHG
OF PERIOD
	
O.fSf
0,949
0.966
0.942
0.990
0.989
0.986
0.981
0.992
0.990
0.98*
0.9B?
0.99?
0.990
0.984
0.982
0.992
O.*90
0.986
0.982

OF SOURCES
PROPERLY
END
OF PERIOD
.820
.f23
.932
.930
.926
0.953
0.952
0.949
0.945
0.955
0.953
0.949
0.945
0.955
0.953
0.949
0.943
0.955
0.953
0.949
0.945

FRACTIONAL DISTRIIUTION OF SOURCES FOR VALVES IT PERIOD
           QUARTERLY UNITS - Vf>P StRVICE
FRACTION
DUE TO
PERIOD BEGINNING
(3 KONTHS) OF PERIOD
INITIAL 	
1
2
3






10
11
12
13
14
13
14
17
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
IS 0.000
19 0.000
20 0.000
< LEAKERS REFERS TO
OF LEAKERS* FRACTION OF FRACTION
OCCURRENCE UNREPAIRED SOURCES EXPERIENCING
END IEGINN1HO END lEBIHKING
OF PERIOD OF PERIOD OF PERIOD OF PERIOD
0.180
0.034 0.018
0.034 0.024
0.034
0.034
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
0.037
.028
.032
.000
.005
.009
.013
.000
.004
.009
.013
.000
.004
.009
.013
.000
.004
.009
.013
.000 	
.018 0.0227
.024 0.0074
.028 0.0035
.032
.000
.005
.009
.013
.000
.004
.009
.013
.000
.004
.OOf
.013
.000
.'004
.0053
.0101
.0060
.0054
.0053
.0078
.0057
.0054
.0033
.0077
.0057
.0034
.0053
.0077
.0057
.OOf 0.0054
.013 0.0053
OF SOURCES FRACTION
EARLY FAILURE OPERATING
END IEGINNINO
OF PERIOD OF PERIOD
0.0000 	
0.0227 0.939
0.0074 0.969
0.0053 0.966
0.0053 0.962
0.0103 O.ffO
0.0060
0.0054
0.0053
0.0078
0.0057
0.0054
0.0053
0.0077
0.0057
0.0054
0.0053
0.0077
0.0057
0.0054
0.0053
.989
.986
.981
.992
,990
.986
.982
.992
,990
.984
.982
.992
.990
.986
.982
OF SOURCES
PROPERLY
END
OF PERIOD
0.820
0.923
0.932
0.930
0.924
0.953
0.952
0.949
0.945
0.953
0.953
0.949
0.943
0.955
0.953
0.919
0.945
0.953
0.933
0.949
0.943
THOSE SOURCES SCREENING GREATER THAN OR EOUAL TO 10.000 PPNV.
                     E-29

-------
Table  E-14.    FRACTIONAL  DISTRIBUTION OF  SOURCES  BY PERIOD (PUMPS)
                       FRACTIONAL tlSTRISUTlON 0» SOURCES FOX PUHPS IT PERIOD
                                 HONTHLT UNITS - THC ItRVICE

      FMCT10N OF LEAKEMt            TRACTION Of            FRACTION W SOURCES
        tut TO OCCURRENCE         UNREPAIRED louncti       EIPERIEHIIHG IARLT FAILURE
FRACTION Of SOURCES
OPERATING PkOPCRLT
PERIOD
INITIAL



10
II
13
14
13
17
10
20
1 LEAKERS
BEGINNING
or PERIOD
• •000
• .000
0.000
9.000
• .000
0.000
A, 000
0.000
0.000
• •000
0.000
0.000
0.000
0.000
0.000
• ••00
0.000
0.000
0.000
0.000
REFERS TO
END
•F PERIOD
0.110
0.014
• .014
0.014
• •014
0.014
0.014
0.014
0.014
0.014
0.014
0.014
0.014
0.014
0.014
• .014
0.014
0.014
0.014
0.014
0.014
THOSE SOURCES
BEGINNING END
UF PERIIID OF PERIOD
• .000
0.000
0.000
0.000
• .000
• .000
0.000
0.000
0.000
0.000
0.000
• .000
0.000
0.000
0.000
0.000
o.ooo
• .000
• .000
0.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
SCREENING GREATER THAN Ok EQUAL
BEGINNING END
IIF PERIOD OF PERIOD
0.0000
0.0000
•.0000
•.0000
0.0000
0.0000
0.0000
0.0000
•.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
,0000
.0000
.0000
.0000
.0000
.0000
,0000
.0000
.0000
.0000
.0000
.0000
TO 10.000 PPNV.
or PERIOD or PERIOD
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
.944
.944
.944
.944
if 44
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944

                        r«*CT!ONAL DISTRIBUTION Or SOUKCES FOR PUMPS DV PERIOD
                                  NON1HLT UNITS - VOC SLKV1CE
FRACTION or LEAKERSt FRACTION OF Fpr.CTION OF SOUkCES FRACTION OF SOUKCES

DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERItHCIHG EAKLT FAILURE OPERATING PkOPERLT
PERIOD BEGINNING END BEGINNING END BEGINNING END DEGINNING END
(1 MONTHS! OF PERIOD OF PERIOD IIF PERIUD OF Pt.RIOD OF PEklUD IIF PERIOD OF PERIOD OF PERIOD
INITIAL
1
2
I
4
3
4
1
B
9
10
11
12
11
14
13
14
17
IB
19
20
...
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.110
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.014
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
• 000 — 0.0000 . — . .470
.000 0.0000 0.0000 1.000
.000 0.0000 0.0000 1.000
.000 0.0000 0.0000 |. 000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
•000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
• 000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
•000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.000 0.0000 0.0000 .000
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
.944
• LEAKERS REFERS TO THOSE SOURCES SCREENING GREATER THAN OR EOUAL Til 10,000 PPNV.


FRACTIONAL DISTRIBUTION OF SOURCES FOk PUMPS Dr PERIOD
BUART/NONTH UNtTS - THC SINVICE
FRACTION OF LEAKERSt FRACTION OF FRACTION OF SOURCES FRACTION OF SOURCES

DUE TO OCCURRENCE UNREPAIRED SOURCES EXPERIENCING CARLT FAILURE OPERATING PROPERLY
PERIOD BEGINNING END BEGINNING END BEGINNING END OE01NHING END
(I MONTHS) OF
INITIAL
PERIOD OF PERIOD OF PERIOD OF PERIOD OF PEKIOO OF PERIOD Or PERIOD OP PERIOD
o'.no — o.'ooo
1 0.000 0.077
2 1
1 <
4 1
1.000 0.094
>.000 0.091
1.000 0.093
3 0.000 0.093
4 1
7 <
>.000 0.091
1.000 0.091
t 0.000 0.093
t 1
10 <
11 «
12 <
II t
14 t
IS <
14 <
17 1
10 f
1.000 0.091
i.eoo 0.091
.000 0.091
1.000 0.091
.000 0.091
.••• *.0tl
.•00 0.091
.MO 0.093
.000 0.093
.000 0.091
It 0.000 0.091
20 C
.000 «.091
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.•00 0.000 0.0000
.000 0.000 0.0000
.000 ».000 0.0000
.000 0.000 0.0000
•••0 o.ooo o.oooo
.000 0.000 0,0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.000 0.000 0.0000
.0000 — .470
.0000 t.OOO
.0000 1. 000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
. 0000 1 . 000
.0000 1.000
•0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 1.000
.0000 i.ooo
.923
.904
.907
.907
.907
.907
.907
.907
.907
.907
.907
.90V
.907
.907
.907
.907
.907
.907
.907
.9D7
B LEAKERS REFERS TO THOSE SOURCES SCREENING OkEATER THAN OR EIIUAL TU 10.000 PPHV.
                                        E-30

-------
                       Table  E-14.    CONCLUDED
                  FRACTIONAL IISTRIDUTION Of SOURCE* re* PUWS »T PFR100

                             IUART/RONTN IWITI - VOC MRVICC
FRACTION
  •Ut  TO OCCURRENCE
    FRACTION 0*
••REPAIRED SOUKClt
   FRACTION 0* SOURCES
EXPERIENCING EARLT FAILURE
FRACTION a* SOURCES
OPERATING PHOPERLT
PERIOD KIINN1NI Cm IEIINNINI CM* IEOINN1NO CN» ICSIHNINO END
ii MMTHti or remap or rcmoi or PERIOD or PERIOD or PERIOD or PERIOD 	 OFVPERIOP or PERIOD
INITIAL —


















10
II
12
11
14
13
14
17
10
It
20
.OM
.000
.000
.OOO
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.110
.07? 0.000
.Ot« 0.000
.0*1 0.000
.Ofl 0.000
.Ofl 0.000
.OT1 0.000
.Ofl 0.000
.Ofl O.OOO
.Ofl 0.000
.OtI 0.000
.Ofl 0.000
.Of] 0.000
.Ofl 0.000
.Ofl 0.000
.Ofl 0.000
.Ofl 0.000
.Ofl 0.000
.Ofl 0.000
.Of] 0.000
.Of] 0.000
.000 —
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
,0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000 —
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.170
.»J3
.t04
.to?
.t07
.t07
.fO?
.f07
.f07
.f07
.f07
.f07
.t07
.f07
.f07
.f07
.f07
.f07
.f07
.f07
,f07
• LEAKERS Mri«f TO TMOtE (OUKCEt ICRICNUI MC*TC« TM*M M COIMU. TO 10.0*0 PPHV.
                   FRACTIONAL IISTRIIUTION 01 SOURCES fOR PIMPS IT PERIOD

                              IUARTERLT UNITS - TMC IfRVICE
r RUCTION or LEAKERS*
•UC TO OCCURRENCE
PERIOD SEOINNINO END
11 HONTHS) Or PERIOD Of PERIOD
INITIAL









10
11
12
11
14
IS
It
17
10
If
20
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.130
.Off
.Off
.Oft
.Off
.Oft
.Off
.Off
.Oft
.Oft
.Oft
.Off
.Oft
.Oft
.Off
.Off
.Off
.Off
.Off
.Oft
.Oft
1 LEAKERS RErERi TO THOSE SOURCES
FRACTION Of
UNREPAIRED SOURCES
OEIINNim CNR
Or PERIOD OF PKRIOh
...
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
SCREENIN8 OREATER THAN Ok EQUAL
FRACTIONAL PISTR1RUTION Of SOURCES

FRACTION Or LEAKERS*
SUE TO OCCURRENCE
PERIOD PEOINNINO END
(I MONTHS) Or PERIOD Or PERIOD
INITIAL
1
»
1
4
9
t
7
*
t
10
11
12
11
14
13
1*
17
II
If
10
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.0*0
.0*0
.000
.000
.110
.Off
.Off
.Oft
.Off
.Off
.Oft
.Off
.Oft
.Off
.Off
.Oft
.Off
.Oft
.Oft
.Off
.Off
.0*f
.Off
.Off
.Oft
* LEAKERS REFERS TO THOSE SOURCES
IT

OUARTERLT UNITS - VIIC
FRACTION OP
UNREPAIRED SOURCES
DEOINNINO END
or PERIOD or PERIOD
...
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
SCREENING OREATER THAN (l« KOUAL


rRACTION Or IDURCES
EXPERIENCING EARLY FAILURE
PEOIHMINO END
or PERIOD or PFHIOD
... .0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
Tn toiooo PPHV.
FOR PUNPS IT PERIOD
SFRVICE
FRACTION OF SOURCES
EXPERIENCING EARLT FAILURE
DEOIMNIHG tHt
or ptRion or PERIOD
...
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
o.oooo
o.oooo
0.0000
0.0000
0.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
TO 10.000 PPNV.


FRACTION Of SOURCES
OPERATING PROPERLT
DCGINNING ENH
OF PERIOD OF PtRIOt
... .470
1.000
4.000
(.000
1. 000
1.000
l.ooo
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
l.ooo
1.000
1.000
1.000
1.000
1.000
.tot
.toi
.toi
.tot
.tot
.fOI
.toi
.tot
.toi
.toi
.tO!
.toi
.toi
.toi
.toi
.toi
.toi
.toi
.toi
.tot



PRACTION or SOURCES
OPERATING PROPERLT
DEGINNINB END
or PERIOD or PERIOD
.470
1.000
1.000
1.000
1.000
1.000
1.000
l.ooo
l.ooo
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
.toi
.toi
.toi
.tot
.toi
.toi
.toi
.toi
.toi
.toi
.toi
.tot
• tot
.toi
»toi
.fOI
.tot
.toi
.toi
. mitt

1
1
                                         E-31

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E.4  REFERENCES

1.   Wetherold, R. G., G. J. Langley, et. al.  Evaluation of Maintenance
     for Fugitive VOC Emissions Control.  EPA/IERL EPA-600/52-81-080.
     May 1981.
                                 E-32

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