EVALUATION OF AN AIR CURTAIN
HOODING  SYSTEM FOR A PRIMARY
      COPPER CONVERTER
        ASARCO, Inc.
     Tacoma, Washington
   Appendices A through I
        PEDCo ENVIRONMENTAL

-------
                                             A-80-40
                                             II-A-40
          EVALUATION OF AN AIR CURTAIN
          HOODING SYSTEM FOR A PRIMARY
                COPPER CONVERTER
                  ASARCO, Inc.
               Tacoma, Washington

             Appendices A through I
                     by

          PEDCo Environmental, Inc.
           Cincinnati, Ohio  45246

           Contract No. 68-03-2924
              Work Directive 9
                  PN 3490-9

                     and

           Contract No. 68-02-3546
           Task Assignment No. 12
                 PN 3530-12

              Project Officers
               John 0. Burckle
Industrial Environmental Research Laboratory
    U.S. Environmental Protection Agency
           Cincinnati, Ohio  45220

                     and

       Alfred Vervaert and Frank Clay
 Emission Standards and Engineering Division
    U.S. Environmental Protection Agency
Research Triangle Park, North Carolina  27711
                December 1983

-------
                APPENDIX A




COMPUTER PRINTOUTS AND EXAMPLE CALCULATIONS
                   A-l

-------
        TRANSMISSOMETER RAW DATA AND OPACITY CALCULATIONS





     Tables A-l through A-4 presents a tabulation of events



during each test and the corresponding optical density and cal-



culated opacity from the strip charts.



     Figure A-l shows the relationship between recorder scale



units, output current in milliamps (mA) and optical density (OD).



The relationship between output current in milliamps and optical



density is linear.  Using this relationship, any peak on the



strip chart can be converted to optical density by converting the



recorder scale units to milliamps and then to optical density.



Figure A-2 shows that the relationship between optical density



and opacity is logrithmetic.



     The following example calculations illustrate the method



used to convert recorder scale units to single pass opacity for



transmissometer data presented in this report:



1.   Recorder scale units to output current  (mA)



          mA = Recorder scale units * 5



          mA = 25 * 5



             = 5
                             A-2

-------
TABLE A-l.   TRANSMISSOMETER OPACITY DATA
         FOR JANUARY 18, 1983
Time
8:30
9:08
9:13
9:16
10:47-11:11
11:11
11:16
11:23
11:28
11:33
11:39
11:44
11:47
12:00
12:05
12:12
15:10
15:13-15:45
15:45
15:53
15:58
16:16
16:18
16:22
Operation
Calibration
Slag skim
Slag skim
Slag skim
Blow
Slag skim
Pour
Pour
Pour
Pour
Pour
Pour
Pour
Pour
Pour
Slag skim
Cold addition
Blow
Slag skim
Slag skim
Slag skim
Matte charge
Matte charge
Matte charge
Optical
density
0.64
0.12
0.16
0.16
0
0.04
0.08
0.12
0.04
0.05
0.16
0.04
0.08
0.08
0.04
0.04
0.04
0
0.08
0.12
0.24
0.36
0.08
0.04
Single
pass opacity
52
13
17
17
0
5
9
13
5
6
17
5
9
9
5
5
5
0
9
13
24
34
9
5
              A-3

-------
TABLE A-2.   TRANSMISSOMETER OPACITY DATA
         FOR JANUARY  19,  1983
Time
7:00
7:26
7:30-8:10
8:10
8:19
8:25
8:34
8:37
8:39
8:42
8:45-9:16
9:16
9:25
9:35
9:38
9:42
9:45-10:10
10:10
10:30
11:27
11:32
11:43-12:30
12:30
12:32
12:35-13:17
13:17
13:20
13:22-2:00
Operation
Calibration
Cold addition (shell slag)
Blow
Slag skim
Slag skim
Slag skim
Matte charge
Matte charge
Cold addition (shell slag)
Cold addition (shell slag)
Blow
Slag skim
Slag skim
Matte charge
Cold addition (shell slag)
Matte charge
Blow
Slag skim
Slag skim
Charge scrap
Charge scrap
Blow
Charge scrap
Charge scrap
Blow
Charge scrap
Charge scrap
Blow
Optical
density
0.64
0.12
0
0.12
0.12
0.12
0.12
0.12
0.28
0.12
0
0.08
0.4
0.08
0.08
0.12
0
0.12
0.12
0.24
0.08
0
0.12
0.16
0
Chart
Single
pass opacity
52
13
0
13
13
13
13
13
28
13
0
9
37
9
9
13
0
13
13
24
9
0
13
17
0
illegible
Chart illegible
0
0
              A-4

-------
TABLE A-3.  TRANSMISSOMETER OPACITY DATA
         FOR JANUARY 20, 1983
Time
7:20
8:25
8:40
8:55
9:10
9:27
9:45
9:48
9:52
10:02
10:04-10:47
10:20-10:46
10:47
10:50
10:55
11:00
11:11
11:12
11:15
11:17
11:18
11:20
Operation
Calibration
Matte charge
Matte charge
Matte charge
Matte charge
Matte charge
Matte charge
Cold addition (shell slag)
Cold addition (shell slag)
Matte charge
Blow
Blow
Slag skim
Slag skim
Slag skim
Slag skim
Matte charge
Matte charge
Matte charge
Cold addition (shell slag)
Cold addition (shell slag)
Blow
Optical
density
0.64
0.28
0.32
0.12
0.12
0.08
0.12
0.56
0.68
0.08
0
Single
pass opaci
52
28
31
13
13
9
13
48
54
9
0
ty











Upset condition considerable
leakage reported. Peaks on
chart not interpreted.
0.04
0.08
0.02
0.08
0.04
0.04
0.04
0.08
0.04
5
9
2
9
5
5
5
9
5
Upset condition, massive
leakage.
i









smoke
             A-5

-------
TABLE A-3  (continued)
Time
13:50-14:25
14:25
14:34
14:40
14:48
14:52
14:55
14:58
15:00-15:37
15:37
15:45
15:54
16:08
16:15-16:55
16:55
17:04
17:33-17:56
17:56
18:10
18:12
18:14
18:15
18:15-18:36
19:23-20:01
Operation
Blow
Slag skim
Slag skim
Slag skim
Matte charge
Matte charge
Cold addition (shell slag)
Cold addition (shell slag)
Blow
Slag skim
Slag skim
Matte charge
Matte charge
Blow
Slag skim
Slag skim
Blow
Slag skim
Blister copper charge
Blister copper charge
Blister copper charge
Blister copper charge
Blow
Blow
Optical
density
0
0.4
0.28
0.08
0.12
0.04
0.12
0.12
0
0.24
0.24
0.04
0.04
0
0.12
0.12
0
0.08
0.08
0.08
0.08
0.08
0
0
Single
pass opacity
0
37
28
9
13
5
13
13
0
24
24
5
5
0
13
13
0
9
9
9
9
9
0
0
                                 A-6

-------
TABLE /T-4 .  TRANSMISSOMETER OPACITY DATA
         FOR JANUARY 22, 1983
Time
10:20
10:44
10:46
10:50
10:54
10:56-11:32
11:37

11:46
11:53
12:05
12:08
16:02-16:22
16:22
16:27
17:01-17:16
17:18
17:26
' 17:28
17:30
17:32
17:34
17:35-18:25
18:27
18:31
18:34
19:01-19:31
20:02-20:33
20:33
20:35-9:05
Operation
Calibration
Matte charge
Matte charge
Cold addition (shell slag)
Cold addition (shell slag)
Blow
Roll out
Slag skim
Slag skim
Slag skim
Matte charge
Matte charge
Blow
Slag skim
Slag skim
Blow
Slag skim
Blister copper charge
Blister copper charge
Blister copper charge
Blister copper charge
Blister copper charge
Blow
Scrap charge
Blister copper charge
Blister copper charge
Blow
Blow
Cold addition
Blow
Optical
density
0.64
0.30
0.30
0.23
0.12
0
0.20
0.60
0.52
0.24
0.12
0.12
0
0.32
Single
pass opacity
52
29
29
23
13
0
21
50
45
24
13
13
0
31
Crane cables blocked beam
0
0
Crane cables blocked beam
Crane cables blocked beam
Crane cables blocked beam
Crane cables blocked beam
Crane cables blocked beam
Crane cables blocked beam
0
0.28
0
28
Crane cables blocked beam
Crane cables blocked beam
0
0
0.48
0
0
0
43
0
               A-7

-------
1UU
ft f\
90
Of\
V) 80
H
5 TO
I 7°
Wan
OU
<
O en
W 50

£ 40
O
CC 
-------
    (0
    z
    tu
    Q
    o
    H
    Q.
    O
            0   10  20  30  40  50  60  70  80  90  100


                          OPACITY. %
Figure A-2.  Relationship  between optical  density and opacity:
                          A-9

-------
2.   Output current to optical density (OP)
          OD = 0utPut current - 2 mA x
                       J. O
          OD = 5 mA- 2 mA
             = 0.3

     Note:  2 mA is subtracted because we have a 10 percent zero
            offset.  Therefore 2 mA is zero optical density.
            Also, this is a double pass optical density, because
            the light beam passes through the emission channel
            and is reflected back to the transceiver.

3.    Optical density to opacity (double pass)


          Opacity = 1 - 10~OD

                  = 1 - 10'0-3

                  = 0.4988

4.    Optical density double pass to opacity single pass
          Opacity (single pass)  = 1 -  \J 1 - opacity (double)
                                         1 - 0.4988
                                = 0.292


          % opacity = 0.292 x 100

                    = 29

     Note:   Single pass opacity may also be calculated by divid-
            ing double pass optical density by 2 and using only
            Equation 3 above.
                              A-10

-------
EXAMPLE TRANSMISSOMETER STRIP  CHART
              A-ll

-------
A-12

-------
A-13

-------
* ! I 40 i  •  ' , ' 60 ! i i
         A-14

-------
              S02 CONTINUOUS EMISSION  MONITOR  EXAMPLE CALCULATIONS
Strip Chart Reduction

     Maximum S02 concentration =  A x  Rf
                                 A y  Pf  y  R
     Average S02 concentration =  " *  *T  *  D
              for merged peaks =      .xAiiBii )Rf
     S02 emitted, Ib/h =
        A x Rf x B x 0 59 x 1Q-9  Ib/mol         g. 0? Jb _   Q  .  f
            C      x ^-by x 1U    dscf x  ppm  x  M>u/ Ib mol.  x g ascT  x
                                              _q
         emitted, Ibs = A x Rf x B x  2.59  x  10   x  64.07  x Q  x 4 min/div.
Nonemclature:

     A = maximum peak height,  1  division  equivalent  to  0.02  inch

     B = peak  width at 1/2 height,  divisions

     C = peak  base, divisions

     Q = average flow rate; 126,924 dscfm for high flow mode
                             76,359 dscfm for low flow  mode

    Rf = calibrated chart response  factor, ppm/division
                                    A-15

-------
                STACK VELOCITY DA1A
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBEH
ASARCO
01/18/83
NO 4 SECONDARY EXHAUST
   V-6
CLOCK TIME
OPERATOR
AMBIENT TEMP
1508
3CHEFFEL
. (DEG.F) 55.



BAR. PRESS. (IN HG) 39.93
STATIC PRESS
.(IN H20) -3.00

MOLECULAR HEIGHT 20.73
STACK INSIDE
OIM(IN) 60.000

PITOT TUBE COEFF. .64
MOISTURE CONTENT(X) 1.00
TRAVERSE
POINT
NO.
-01
-02
•03
-0«
•05
•06
0-01
D-02
0-03
0-0«
0-05
0-06
POSITION VELOCITY
INCHES HEAD
(IN H20)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.200
.400
.400
.200
.200
.100
.100
.400
.500
.400
.500
.300
STACK
TEMP
(DeG.F)
56.
56.
56.
56.
57.
57.
57.
57.
57.
57.
57.
57.
AVERAGE
        1.30A
57.

-------
         PLANT                  ASARCO
         DATE                   01/18/63
         SAMPLING LOCATION      NO  4  SkCONDARV  EXHAUST
         RUN NUHBEH                V-b

  STACK AREA, SO. FT.                   19.655
  STACK ABS. PRES.,  IN H6.              29.71
  STACK GAS TEMPERATURE* OE6.F           57.
  SORTtVEL MD X STACK TEMP  ABS)         26.0

  STACK CAS VELOCITY, ACT.  FPS          63.8
  STACK GAS VOLUME  (MET), ACT.  CFM.  75181.5
  STACK GAS VOLUME  (DRY), ACT.  CFM.  74429.7
  STACK GAS VOLUME  9 29.92  IN.  HG  AND  66 DG. F :
                (DRY)                 75527.0
                (HE!)                 76289.9
 !
M
~J

-------
                                                         SAMPLE  CALCULATIONS
          SYMBOLS:
                    ARE*      CROSS-SECTIONAL  STACK  AREA,  SO  Ft
                    BPRES     BAROMEIHIC PHF.SSURt.  IN  HG
                    DELP      DELTA H
                    OIA       DIAMETER OF CIRCULAR  STACK.  IN
                    DIMI      LENGTH OF RECTANGULAR  STACK,  IN
                    OIM2      WIDTH OF RECTANGULAR  STACK,  IN
                    MOIST     MUISTUHE CONTENT
                    MH        MOLECULAR HEIGHT
                    NP        NUMHER OF TRAVERSE  POINTS
                    BH        MOLE FRACTION  HATER VAPOR
                                                                       PTC        PHOT TUBE COEFFlCtNT

                                                                       SPHtS     STA1IC PHF.SSURE, IN H20
                                                                       STtMP     STACK TEMPEPATUPt, DEG F
                                                                       STHHES    STACK PRESSURE, IN HG

                                                                       STVFL     STACK VELOCITY, AFPM

                                                                       IKMP      IEMPERATURE, DEG F
                                                                       VH        VFLOCITY MtAD, IN H20

                                                                       SVOLFLH   STANDARD VOLUMETRIC FLOH  (HET),  ACFM
                                                                       VOLFLH    VOLUMETRIC FLOH IHfcT), ACFM
                                                                       SVOLFLD   STANDARD VOLUMETRIC FLOH  (D«Y),  OSCFM
 I
M
00
FORMULAS AND SAMPLE CALCULATIONS:


                    SUM(SORT (VH * TEMPI I           311.b
          OELP  a  —	——-—-------  a	   z     26.0
                          NP                        \^


          STPRES  =  BPRES + (SPRES/t3.6)  =  £9.93  + ( -3.UU/13.6)   =     89.7  IN HG


                     SOM(STEMPI           660.
          8TENP  «	  =  —	  =    57.  OEG  F
                       NP                 \i


                                   3.1416 •  (OIA/2)**2         3.1416  *  (  60.000/2)**2
          AREA(CIRCULAR STACK)  s  	 		-.	   x  -—	  s   19.635 SO FT

                                           144                        144


                     85.49 • PTC • OELP       85.49  *  .84 •    36.0
          STVEL  «  .—-.. ——	  s  .......................  s   63.8  AFPM

                     SORTIMH * STPKES)        SORT!  28.73 *   29.7 I


          VOLFLN  *  60. • STVEL * ARE*  s  60. *  63.8 *  19.635  =    75181.5  ACFM


          SVOLFLH  *  VOLFLH • STPRES • ( 460. * 68. )       75181.5  •  29.7  *  (  460. * b8. )
                      	.	.	  =  	.	.	.	  s     76289.9 ACFM

                          29.92 • ( 3TEMP » 460. )               29.92  •  (   56.7 * 460. J


          SVOLFLD - SVOLFLH • (1 - BH) *   76289.9 • (1 -    .01) s     75527.0  DSCFM

-------
                      STACK VELOCITY DA1A
«£>
          PLANT
          DATE
          SAMPLING LOCATION
          RUN NUMBEk
ASARCO
01/12/83
NO a SECONDARY EXHAUST
   V-/
CLOCK TIME 151?
OPERATOR SCHEFFEL
AMBIENT TEMP. (DE6.F) 55.
BAR. PRESS. (IN MG) 29.93
STATIC PRESS. (IN H20) -3.0U
MOLECULAR NEI6HT 28.73
STACK INSIDE DIM(IN) 60.000
PITOT TUBE COEFF. .64
MOISTURE CONTENT(I) 1.00
TRAVERSE POSITION V
POINT INCHES
NO.
0-01 .0
0*02 .0
0=03 .0
0-0« .0
0-05 .0
0-06 .0
-01 .0
-02 .0
-03 .0
-04 .0
-05 .0
-06 .0









VELOCITY
HEAD
IN H«?0)
.100
.400
.500
.500
.400
.100
.100
.300
.300
.200
.800
.100









STACK
TEMP
(OEG.F )
57.
5T.
57.
57.
57.
57.
57.
57.
57.
57.
57.
57.
      AVERAGE
        1.258
57.

-------
         PLANT                 ASARCO
         DATE                  01/12/83
         SAMPLING LOCATION     NO 4 SECONDARY EXHAUST
         RUN NUMBER               V-7

  STACK AREA, SO. FT.                   19.635
  STACK ABS. PRES., IN H6.             39.71
  STACK GAS TEMPERATURE,  DEG.F          57.
  38RT(VEL  HD X  STACK  TEMP APS)         25.5

  STACK GAS VELOCITY,  ACT. FPS         t>8.6
  STACK GAS VOLUME (NET),  ACT. CFM. 73740.4
  STACK GAS VOLUME (ORT),  ACT. CFM. 73010.9
  STACK GAS VOLUME 9 89.92 IN. HG AND 66 06. F :
               (DRV)                74039.5
               (WET)                74787.4
I
to
o

-------
                                              SAMPLt CALCULA1 1UNS
SYMBOLS:
          ARE*      CROSS-SECTIONAL STACK ARtA, S(J FT
          BPRES     BAROMETRIC PHFSSURE, IN HG
          UELP      OELTA P
          OIA       DIAMETER OF CIRCULAR STACK, IN
          OIMI      LENGTH OF RECTANGULAR STACK, IN
          DIM2      N10TH OF RECTANGULAR S1ACK, IN
          MOIST     MOISTURE CONTENT
          MM        MOLECULAH HEIGHT
          NP        NUMBER UF THAVLHSE POINTS
          BM        MOLE FRACTION HATER VAPOH
PTC       PHUT tUHE CUEFF1CENT
SPHtS     STATIC PKESSUHt. IN H20
STtMP     STACK TtMPtWATUWE, OEK F
STPHES    STACK PHESSUNE, IN Hb
STVEL     STACK VELIICITT, AFPM
TEMP      TEMPtRATURE, DEG F
VH        VELOCITY HtAU.  IN H?V
SVULfLH   STANUAHO VULUMtTHIC FLUM  (NET),  ACFM
VOLFLrt    WOLUMETHIC FLOW (HtT), ACFM
bVULf-LU   S1ANUAHU VOLUMETKIC FLON  (DRY),  USCFM
FORMULAS AND SAMPLE CALCULATIONS!


                    SUMISORTIVH * TEMPI!          305.6
          OELP  a  —.	  x  	  z     25.5

                          NP                       18


          STPRES  =  BPRES » (3PRES/I3.6)  =  29.93 *  ( -3.00/13.b)   =     29.7  IN HG


                     SUM13TEMPJ           fcftQ.
          STEMP  *  ———-----  s  — — - — ---  :     57. DEG F

                       NP                 12


                                   3.1416 * (DIA/2)**2        3.1416  •  (  60.000/2)**2
          AREA(CIRCULAR STACK)   =  	  =  	   =   19.635 SO FT
                                           144                        144


                     65.49 * PTC * OELP       85.49 •  .94 *    25.5
          STVEL  «  - — --- — — ---	  a  ................	  s    b2.b  AFPM

                     SORT(MM *  SIPKESJ         SORT (  26.73 *  29.7 I


          VOLFLM  *  bO. * STVEL • AREA  =  60. •  62.6 *  19.635  =    73748.4  ACFM


          SVOLFLM  *  VOLFLH •  S1PRE3 • ( 460. » 68. )       73746.4  •  29.7  •  (  460.  +  68.  )
                      .	.	—  s  -.	—   =     74767.4 ACFM

                          29.9? • ( STEMP » 4bO. )               29.9?  •  (    S7.0 * 4Mt.  )


          SVOLFLO » SVOLFLW *  (1 - BH)  =   747B7.4 * (1 -    .01) =     74039.5  OSCFM

-------
            STACK VELOCITY UAlA
PLANT
DATE
SAMPLING LOCATION
RUN NUMBER
ASARCU
01/12/83
NO 4 StCONOARY EXHAUS1
CLOCK TIME 1523
OPERATOR SCHEFFEL
AMBIENT TEMP. (DEG.F) 55.
BAR. PRESS. (IN HG) 29.93
STATIC PRESS. (IN H20) -2.70
MOLECULAR HEIGHT 28.73
STACK INSIDE OIM(IN) 60.000
PITOT TUBE COEFF. .84
MOISTURE CONTCNT(X) 1.00
TRAVERSE POSITION V
POINT INCHES
NO.
C-OI .0
C-0* .0
> C-03 .0
' C-0« .0
to C-05 .0
C-Ofc .0
0-01 .0
0-02 .0
D-03 .0
0-04 .0
D-05 .0
0-06 .0
AVERAGE 1









VELOCITY
HEAD
[IN H20)
.100
.400
.300
.300
.200
.200
.100
.500
.400
.500
.500
.300
.317









S1ACK
TfcMP
(OEG.F)
57.
57.
57.
57.
57.
57.
57.
57.
5T.
57.
58.
58.
5T.

-------
 I
M
U)
           PLANT                  ASARCO
           DATE                   01/12/83
           SAMPLING  LOCATION      NO  4  StCONUARY  EXHAUST
           RUN NUMBER                V-H

    STACK  AREA, 30.  FT.                   19.635
    STACK  ASS. PRE3.,  IN  H6.              29.73
    STACK  CAS TEMPERATURE.  DEG.F           57.
    SORT(VEL HO X  STACK TEMP  ABS)         26.1

    STACK  CAS VELOCITY, ACT.  FPS          fca.O
    STACK  CAS VOLUME (NET),  ACT.  CFM.  75427.4
    STACK  CAS VOLUME (DRY),  ACT.  CFM.  70673.1
    STACK  CAS VOLUME 9 29.9Z  IN.  HG  AND 66 DG. F :
                 (DRT)                75757.0
                 (WET)                7h522.2

-------
                                                          SAMPLE CAI.CIILA! IONS
           SYMBOLS:
                     AREA       CROSS-SECTIONAL STACK ARtA, SQ Fl
                     BPRES      BAROMETRIC  PRESSURE, IN HG
                     UELP       DELTA  P
                     OIA        DIAMETER  OF CIRCULAR STACK, IN
                     DIM]       LENGTH OF  RECTANGULAR STACK, IN
                     DIM2       WIDTH  OF  RECTANGULAR STACK, IN
                     MOIST      MOISTURE  CONTENT
                     MM         MOLECULAR  HEIGHT
                     NP         NUMBER OF  TRAVERSE POINTS
                     BN         MOLE FRACTION MATER VAPOK
                                                                       PTC        PHOT  TIIHE COF.FFlCtNT
                                                                       SPUES      STATIC PHESSURt, IN H20
                                                                       STtMP      STACK  (EMPtHATURt, OEG F
                                                                       STPHE3     STACK  PRESSURE, IN H(i
                                                                       SW.L      STACK  VtLOCITY, AFPM
                                                                       IEMP       Tt.MPbRATURE, PEG F
                                                                       VH         VELOCIIT MtAO, IN H20
                                                                       SVULFLn    STANDARD VULIIMtTwIC FLOW  (MET),  ACFM
                                                                       VULFLW     VOL'JMEtMIC FLOW IWtT), ACFM
                                                                       SVOLFLO    STANQARU VOLUMfcTRIC FLOW  (URT),  OSCFM
ro
•u
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM(SORT(VH  •  TEMPI I           31?.7
          OELP  *  •	  =  	  =    26.1
                          NP                        12

          STPRES  =  BPRES  *  (SPRES/1J.6)  =  a«».<»3 + ( -?.70/13.6)  =     £9.7  IN HG

                     SUMISTEMP]            696.
          3TEMP  *  ——	  e   	  =    57. OEG F
                       NP                  12

                                    3.1416 • (OIA/2)**?        3.1«l6 *  (  60.UOU/2)**2
          AREA(CIRCULAR STACK)   =   	  =  	  =   19.635 SU  Fl
                                            Ida                       144

                     65.49  *  PTC • HELP        85.49 •  ,«4 *   26.1
          STVEL  =  ——— ——— — —   «  ---—— ——- ———  s    fcq.O  AFPM
                     SORT(MM  * STPRES)         SORT I  26.73 *  29.7 )

          VOLFLW  «  60. •  STVtL • AREA   s  60. *  64.0 •  19.635  =    75427.0  ACFM

          SVOLFLM  =  VOLFLN  • STPRES *  ( 460. + 68. )       75427.4 •  29.7  •  (  460. • 68. )
                      	  s  	  =      76522.2  *CFM
                          29.92  *  (  STEMP * 060. )               29.92  •  (    57.2 * 460. )

          SVOLFLO « SVOLFLM • (1 - HW)  =    76522.2 • (1 -    .01) =     75757.0  OSCFM

-------
                STACK VELOCITT UATA
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO
01/12/83
NO 4 SECONDARY EXHAUST
CLOCK TIME 1529
OPERATOR SCHEFFEL
AMBIENT TEMP. (OE6.F) 55.
BAR. PRESS. (IN HG) 29.93
STATIC PRESS. (IN H20) -2. 70
MOLECULAR HEIGHT 28.73
STACK INSIDE OIM(IN) bO.OOO
PITOT TUBE COEFF. .Bfl
MOISTURE CONTENT(J) 1. 00




>'
1
to
(J1








TRAVERSE
POINT
NO.
0-01
0-02
D-03
0-0«
0-05
0-06
C-01
C-OZ
C-03
C-0«
C-05
C-06
POSITION VELUCITT
INCHES HEAD
(IN H80)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.100
.500
.600
.700
.600
.500
.100
.300
.100
.300
.200
.200
STACK
TEMP
(DEG.F)
57.
57.
57.
58.
58.
58.
57.
58.
58.
58.
58.
5«.
AVERAGE
        1.392
58.

-------
           PLANT                 ASARCO
           DATE                  01/I2/B3
           SAMPLING LOCATION     NO Q SECONDARY EXHAUS1
           RUN NUMBER               V-9

    STACK AREA, SO. FT.                  19.635
    STACK ABS. PRES.» IN HG.             29.73
    STACK CAS TEMPERATURE, OEG.F          56.
    90RT(VEL HO X STACK TEMP ABS)        26.0

    STACK GAS VELOCITY, ACT. FPS         65.7
    STACK GAS VOLUME (MET), ACT. CFM. 77453.3
    STACK GAS VOLUME (DRY), ACT. CFM. 76677.6
    STACK GAS VOLUME 9 29.92 IN. HG AND 68 OG. F  :
                 

-------
                                                            SAMPLE CALCULATIONS
             SYMBOLSI
                       AREA      CROSS-SECTIONAL STACK AREA, SU FT
                       BPRES     BAROMETRIC PRESSURE,  IN MG
                       DELP      DELTA P
                       OIA       DIAMETER OF CIRCULAR  STACK, IN
                       DIM1      LENGTH OF RECTANGULAR STACK,  IN
                       DIM2      NIDTH OF RECTANGULAR  STACK, IN
                       MOIST     MOISTURE CONTENT
                       MM        MOLECULAR HEIGHT
                       NP        NUMBER OF TRAVERSE POINTS
                       BM        MOLE FRACTION (WATER VAPOR
                                                                       HTC        PITOT  TUBE  CUEFMCENT
                                                                       SPUES      STATIC  PRESSURE. IN H20
                                                                       SltMP      STACK  TEMPERATURE, DEC F
                                                                       STPRES     STACK  PRESSURE, IN HG
                                                                       STVEL      STACK  VELOCITY, AFPM
                                                                       TEMP       TEMPERATURE,  PEG F
                                                                       VH         VILOCITY HEAD, IN M20
                                                                       SVOLFLN   STANDARD VOLUMETRIC FLOW (*ET), ACFM
                                                                       VOLFL*     VOLUMETRIC  FLOW IKET). ACFM
                                                                       SVULFLO   STANDARD VOLUMETRIC FLOte (ORY), DSCFM
NJ
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM[SORT IVH • TEMP))
          DCLP  »  ——	  =  	•   «     26.8
                          NP                        18

          STPRES  f  BPRES » (SPRES/13.6)  a  29.93 +  ( -?.70/IJ.b)   =     29.7  TN HG

                     SUMISTEMP)           692.
          8TEHP  «	  «  —	  =     58.  OEG F
                       NP                 12

                                   3.1416 • (DIA/2)**2        3.1416  •  (  60.000/2)**2
          AREA(CIRCULAR STACK)  =  	   =	  =   19.635 SO Ft
                                           144                        144

                     85.49 • PTC * DELP       85.49 •  .84 •    26.8
          STVEL  *  ————————  s  ..........-........-._.  s    65.7  AFPM
                     SORTIMN • STPRES)        SORT I  28.73 •  29.7  I

          VOLFLM  e  60. * STVEL • AREA  =  60.  •   65.7 •  19.635   =    77452.3  ACFM

          SVOLFLW  «  VOLFLH • STPRES •  ( 460. * 68. )       77452.3  •  29.7  •  {  460. » 68. )
                      .	.	  =  	.	..	.	  s     785V0.6 ACFM
                          29.92 • I 3TEMP » 460. )               29.92  •  (   57.7 * 460. )

          SVOLFLO s SVOLFLH •  (1 - B") s   78500.6  • (1 •    .01) *     77715.6  DSCFM

-------
                      STACK VELOCITY DATA
I
do
          PLANT
          DATE
          SAMPLING LOCATION
          RUN NUMBER
ASARCO
Ol/ie/83
NO a SECONDARY EXHAUST
  V-10
CLOCK TIME 1534
OPERATOR SCHEFFEL
AMBIENT TEMP. (DE6.F) 55.
BAR. PRESS. (IN HG) Z9.93
STATIC PRESS. (IN H?0) -a. 70
MOLECULAR HEIGHT ZA.7J
STACK INSIDE DIM(IN) feO.OOO
PITOT TUBE COEFF. .84
MOISTURE CONTENT(X) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
001 .0
C-02 .0
C-03 .0
C-04 .0
C-05 .0
C-06 .0
0-01 .0
0-OZ .0
0-03 .0
0-04 .0
0-05 .0
0-06 .0









VELOCITY
Ht»U
(IN H20)
.100
.400
.500
.500
.400
.aoo
.100
.300
.400
.300
.500
.400









STACK
TEMP
(UbG.F)
57.
57.
58.
58.
5t».
58.
58.
58.
58.
58.
58.
58.
      AVERAGE
                                  58.

-------
        PLANT                 ASARCO
        DATE                  01/12/83
        SAMPLING LOCATION     NO a 3E.CCNDAHY  EXHAUST
        RUN NUMBER              V-tl)

 STACK AREA, 30. FT.                   19.635
 STACK ABS. PRE3., IN H6.              29.73
 STACK CAS TEMPERATURE. OEG.F          SB.
 SORTtVEL HO X STACK TEMP ABS)         26.3

 STACK GAS VELOCITY, ACT. FPS          64.7
 STACK GAS VOLUME (NET), ACT. CFM. 76194.1
 STACK GAS VOLUME (DRY). ACT. CFM. 75432.2
 STACK GAS VOLUME 9 29.92 IN. HG AND 66  DG. F  :
              (ORT)                76428.5
              (WET)                77200.5
>

vo

-------
                                                        SAMPLt CALCULATIONS
          SYMBOLSt
                    AREA      CROSS-SEC I KJNAl STACK AREA, SI) FT
                    BPRES     BAROMETRIC PRESSURE, IN Hf,
                    DELP      DELTA P
                    OIA       DIAMETER OF CIRCULAR STACK, IN
                    DIM!      LENGTH OF RECTANGULAR STACK, IN
                    D1M2      NIOTH OF RECTANGULAR STACK, IN
                    MOIST     MOISTURE CONTENT
                    MN        MOLECULAR HEIGHT
                    NP        NUMBER OF TRAVERSE POINTS
                    BH        MOLE FRACTION HATER VAPOR
PTC       PHUT  TUBE CUEFFlCtNT
SPRES     STATIC PRESSURE,  IN  H20
sTtMp     STACK  TEMPERATURE, OEG F
STPRES    STACK  PRESSURE,  IN HG
STVtL     STACK  VELOCITY,  AFPM
TEMP      ffMPERATURE,  OEG  F
WH        VELOCITY HEAD,  IN H2o
SVULFLW   STANDARD VOLUMETRIC  FLO*
VdLFLH    VOLUMF.TRIC FLOW  (HET),
SVOLFLU   STANDARD VOLUMETRIC  FLOW
                                                                                                           (NET), ACFM
                                                                                                           (ORY), OSCFM
W
Q
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM(SORT IVH  *  TEMP)I           315.9
          OELP  «	   =   	   =    26.3
                          NP                        12

          STPRES  *  BPRES » (3PRES/1J.6)   =   29.93  *  I  -2.70/13.6)  =    29.7 IN MG

                     SUM(STEMP)            694.
          STEMP  «	—   a	   =    58.  OEG F
                       NP                  12

                                   3.141fe  • (T)IA/2)**2        i.iaib « ( bO.OOO/2)**2
          AREA(CIRCULAR STACK)   =  	   =  	   =    19.635 SO Fl
                                            144                        144

                     85.49 • PTC * DELP        85.49  *   .84 *   2b.3
          STVEL  s  .———.—- — ---   3  .............	.......  =   64.7 AFPM
                     SORTIMM * STPRES)         SORT I  28.73 •  29.7 )

          VOLFLH  =  60. * STVEL * AREA  = 60.  *  b4.7  •   19.635  =   76194.1 ACFM

          SVOLFLU  s  VOLFLH • STPRES *  (  460.  * 68. )       76194.1 •  29.7 • ( 460. » 68.  )
                      	  =   —	.	.	   r      77200.5 ACFH
                          29.92  •  (  STEMP  * 4bO. )    '           29.92 • (   57.8 * 4bO.  )

          SVOLFLO s SVOLFLH  • (1 • BH)  r    77200.5 • (I  -     .01) s    76428.5 OSCFM

-------
                STACK VELOCITY DATA
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASAHCO
01/13/83
NO a SECONDARY EXHAUST
  V-l I
CLOCK TIME 1010
OPERATOR 3CHEFFEL
AMBIENT TEMP. (DEG.F) 50.
BAR. PRESS. (IN HG) 30.43
STATIC PRESS. (IN H?0) -3.00
MOLECULAR NE16HI ^«.7J
STACK INSIDE OIM(IN) 60.000
PITOT TUBE COEFF. .84
MOISTURE CONTENT(X) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
0-01 .0
0-02 .0
0-03 .0
0-04 . .0
D-OS .0
0-06 .0
C-OI .0
e-02 .0
C-03 .0
C-0« .0
C-OS .0
C-06 .0









VELOCITY
HEAD
IN H£0)
.oao
.200
.400
.550
.650
.550
.150
.500
.450
.300
.300
.200









STACK
TtMP
(DEG.F)
59.
59.
59.
60.
60.
60.
56.
57.
58.
58.
S9.
59.
AVCRA6E
        1.356

-------
         PLANT                  ASARCO
         DATE                   01/13/63
         SAMPLING  LOCATION      NO  4  SECONDARY  EXHAUST
         RUN NUMBER              V-ll

  STACK  AREA, SO.  FT.                   19.635
  STACK  ABS. PRES.,  IN  H6.              30.21
  STACK  GAS TEMPERATURE*  OEG.F           59.
  SQRUVEL HD X  STACK TEMP  ABS)         26.5

  STACK  CAS VELOCITY, ACT.  FPS          64.5
  STACK  CAS VOLUME (MET), ACT.  CFM.  75976.6
  STACK  CAS VOLUME (DRV), ACT.  CFM.  75217.0
  STACK  CAS VOLUME 9 29.92  IN.  MG  AND  66 06.  F :
               (DRV)                 77311.2
               (NET)                 76092.1
U)
fO

-------
                                                        SAMPLE  CALCULATIONS
          STMBOLSt
                    AREA      CROSS-SECTIONAL STACK AREA,  S(J  FT
                    BPRES     BAROMETRIC PRESSURE, IN HG
                    OELP      DELTA P
                    DIA       DIAMETER OF CIRCULAR STACK,  IN
                    DIM!      LENGTH OF RECTANGULAR STACK,  IN
                    DIM2      WIDTH UF RECTANGULAR STACK,  IN
                    MOIST     MOISTURE CUN1F.NT
                    MM        MOLECULAR WEIGHT
                    NP        NUMBER UF TRAVERSE POINTS
                    BW        MOLE FRACTION WATER VAPOR
PTC       PITOT TUBE COEFFICENT
SPHF.S     STAUC PRESSURE,  IN  H2U
STtMH     STACK IEMPERATUf
.	....  s    ae.s


30.43 » ( -3.00/13.f>)


        59. DEG F


                3.1416
FORMULAS AND SAMPLE CALCULATIONS:

                    SUMtSORMVH  *  TEMPI)
          OELP  «  -	
                          NP

          STPRES  =  BPRES  »  (SPRES/13.6)

                     8UMCSTEMP)            704.

                       NP                  12

                                    3.1416 '

                                            144                        144

                     85.49  *  PTC  •  DELP       85.49 *  .84 •   26.5

                     SQRMMN  • STPRES)         SQHTl  20.73 •  30.2 I

          VOLFLM  s  60. •  STVEL  •  AREA  s  60. •  64.5 *  19.635  =    75976.8  ACFM

          3VOLFLW  s  VOLFLH  * STPRES * ( 460. «• 68. )       75976.8  •  30.2  •  (  460.  » 68. )

                          29.92  •  (  STEMP » 460. )                29.92  •  (    58.7  •»  460. )

          SVOLFLD = SVOLFLW • (1  -  8W)  =    78092.1  • (1 •    .01) =     77311.2  DSCFM
                    STEMP  *
                    AREA1CIRCULAR STACK)
                    STVEL  *
                                                                                           IN MG
   60.000/?)**2
                                                                                          AFPM
                                                                                                         19.635 SO FT
                                                                                                                 78092.1 ACFM

-------
                     STACK VELOCITY DATA
U)
         PLANT
         DATE
         SAMPLING LOCATION
         RUN NUMBEH
ASARCU-TACOMA, WASHINGTON
01/13/83
04 SECONDARY EXHAUST
  V-17
CLOCK TIME
OPERATOR
1 140
OF


AMBIENT TEMP. (DEG.F) 50.
BAR. PRESS.
(IN HG) 30.43

STATIC PRESS. (IN H30) -2. BO
MOLECULAR
HEIGHT ea.73

STACK INSIDE OIM(IN) 60.000
PITOT TUBE
COEFF. .84

MOISTURE CONTENT!*) 1.00
TRAVERSE
POINT
NO.
C-01
C*02
C-03
C-0«
C-OS
C-06
0-01
0-02
0-03
D-04
D-05
D-06
POSITION VELOCITY
INCHES HEAD
(IN H80)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.zoo
.300
.400
.300
.300
.000
.300
.400
.400
.500
.700
.300
STACK
TEMP
IDEG.F)
56.
56.
56.
56.
57.
56.
56.
56.
56.
56.
56.
56.
     AVERAGE
        1.348
56.

-------
        PLANT                 ASARCO-TACOMA, WASHINGTON
        DATE                  OI/I3/H3
        SAMPLING LOCATION     «Q SECONDARY EXHAUST
        RUN NUMBER              V-17

 STACK AREA, SO. FT.                  19.635
 STACK AiS. PRES., IN H6.             30.22
 STACK CAS TEMPERATURE* OE6.F          56.
 SORTtVEL HO X STACK TEMP ABS)        26.3

 STACK CAS VELOCITY, ACT. FPS         64.0
 STACK CAS VOLUME (MET), ACT. CFM. 75109.9
 STACK CAS VOLUME (DRY), ACT. CFM. 70655.6
 STACK CAS VOLUME 8 29.9? IN. HG AND 6$ 06. F  :
              (DRY)                77156.0
              (KET)                77935.1
u>
U1

-------
                                                       SAMPLt CALCULATIONS
         SYMBOLS:
                   ARE*      CROSS-SECTIONAL STACK AREA, SI) KT
                   BPRES     BAROMETRIC PRESSURE, IN HI,
                   OELP      DELTA P
                   01*       DIAMETER OF CIRCULAR STACK, IN
                   DIM!      LENGTH OF RECTANGULAR STACK, IN
                   DIM2      WIDTH OF RECTANGULAR STACK, IN
                   MOIST     MOISIUHE CONTENT
                   M*        MOLECULAR HEIGHT
                   NP        NUMBER OF TRAVERSE POINTS
                   BN        MOLE FRACTION WATER VAPOR
                                                                       PTC        PITDT  TUBE COEFFICENT
                                                                       SPUES      SIATIC  PHFSSURE, IN H20
                                                                       SfhMp      STACK  TEMPERATURE, UEG F
                                                                       STPRES     STACK  PRESSURE, IN MG
                                                                       STVEL      STACK  VELOCITY, AFPM
                                                                       IEMP       1EMPERATURE, OEG F
                                                                       VH         VELOCITY HEAD, IN H20
                                                                       SVULFLW    STANDARD VOLUMETRIC FLOW (NET), ACFM
                                                                       VOLFLW     VOLUMETRIC FLOW (WET), ACFM
                                                                       SVOLFLO    STANDARD VOLUMEThIC FLUW (DRY), 03CFM
>
to
                   STEMP  •
                                                                        26.3
FORMULAS AND SAMPLE CALCULATIONS:


                    SUM(SORT(VH • TEMPI)          315.2
          OELP  »  —	  =  	
                          NP                       12


          STPRES  *  BPRES + (SPUES/13.b)  =  30.«J *  ( -2.00/13.6)   a


                     SUM(STEMP)           673.
                      ...........  9  ..........  s

                       NP                 12
                                            56. DEG F
                                                                                    30.2  IN  HG
                                                                       3.1416 *  ( f>O.OOU/2)**2
                                   3.1416 *  (DIA/2)**2
                                   ...._.-...._..-.-_...  s   ...._.-..._.

                                            144                        144


                                              85.49 •   .84 *    26.3
                    ...........__..__...  s  .........____........_.   =

                     SORT(MW * STPRES)        SORT I  20.73 •   30.2 I


          VOLFLM  *  60. • STVEL * AREA  s   60. •  61.0 •  19.635  =    75409.9 ACFM
AREACCIRCULAR STACK)  s  	



           85.49 • PTC • OELP
STVEL  s  .............	..
                                                                                   64.0  AFPM
                   SVOLFLM  «  VOLFLW • STPRES • ( 460. * 68. )
                               ................................  s

                                   29.92 • ( STEMP » 460. )


                   SWOLFLO * SVOLFLW • (1 - BW) =   77935.4 • (1 -
                                                                                                       19.635 SO FT
                                                              75409.9  *   30.2  • (  460. * 68. )


                                                                  29.92  • (    56.1 * 460. )


                                                              .01)  =     77156.0 DSCFM
                                                                                            77935.4 ACFM

-------
                      STACK VELOCITY DAT*
 I
u>
          PLANT
          DATE
          SAMPLING LOCATION
          RUN NUMBER
ASARCO-TACOMA, WASHINGTON
01/13/83
•4 SECONDARY EXHAUST
  V-18
CLOCK TIME 1144
OPERATOR OF
AMBIENT TEMP. (OE6.F) 50.
BAR. PRESS. (IN HG) 30.43
STATIC PRESS. (IN M20) -2.90
MOLECULAR NE1GHT 28.73
STACK INSIDE DIM(IN) bO.OOO
PITOT TUBE COEFF. .84
MOISTURE CONTENT(I) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
0-01 .0
0-02 .0
D«95 .0
0-04 .0
0-05 .0
0-06 .0
C-OI .0
C-OZ .0
e-os .0
C-04 .0
C-05 .0
C-06 .0









/ELOC1TY
HEAD
(IN H20)
.200
.500
.500
.300
.300
.200
.100
.450
.400
.300
.300
.100









STACK
TEMP
(OEti.F)
55.
5b.
5b.
5b.
5b.
5b.
57.
57.
5b.
5b.
57.
57.
      AVERAGE
        1.304
5b.

-------
          PLANT                 A3AHCO-1ACOMA, WASHINGTON
          DATE                  01/13/83
          SAMPLING LOCATION     «4 SECONDARY EXHAUST
          RUN NUMBEH              V-18

   STACK AREA, SO. FT.                  19.635
   STACK ABS. PRES.. IN MC.             30.28
   STACK GAS TEMPERATURE.  DEG.F          56.
   SORT(VEL HD K STACK TEMP ABS)        25.9

   STACK GAS VELOCITY, ACT. FPS         63.2
   STACK GAS VOLUME (NET), ACT. CFM. 74406.Z
   STACK GAS VOLUME (DRY), ACT. CFM. 73662.2
   STACK GAS VOLUME » 29.92 IN. HG AND 68 06. F t
                (ORT)                760S6.0
                (XET)                76654.5
 I
Ul
00

-------
                                                         SAMPLE  CALCULATIONS
          SYMBOLS!
                    ARE*      CROSS-SECTIONAL STACK  AHEA.  SO  Ft
                    BPMES     BAROMETRIC PRESSURE,  IN  HG
                    OELP      DELTA P
                    OIA       DIAMETER OF CIRCULAR  STACK,  IN
                    OIM1      LENGTH OF RECTANGULAR  STACK,  IN
                    OIM8      WIDTH OF RECTANGULAR  STACK,  1M
                    MOIST     MOISTURE CONTENT
                    MN        MOLECULAR HEIGHT
                    NP        NUMBER OF TRAVERSE  POINTS
                    BN        MOLE FRACTION NATER VAPOR
                                                                       PTC       PHOT TUBE COEFF1CENT

                                                                       SPRF.S     STATIC PRESSURE, IN H20

                                                                       SltMP     STACK TF.MPEMATURE, OE6 F
                                                                       STPHES    STACK PRESSURE, IN Hti
                                                                       STVEL     STACK VELOCITY, AFPM

                                                                       TEMP      TEMPERATURE, OEG F
                                                                       VH        VELUCIIY HEAD,  IN H20

                                                                       SVOLFLM   STANDARD VULUMtTHIC FLU*  (MET),  ACFM

                                                                       VULFLW    VOLUMETRIC FLOW l*ET), ACFM

                                                                       SVULFLO   STANDARD VOLUMETRIC FLOW  (DRT),  DSCFM
U)
vo
FORMULAS AND SAMPLE CALCULATIONS:


                    SUMISORTIVH • TEMPI)           311.0

          OELP  «	  =   	   =     25.9
                          NP                        12


          STPRES  =  BPRES * (SPRES/13.6)  a   30.43  +  (  -2.90/13.6)  =    30.2 IN HG


                     SUMISTEMPI           675.
          STEMP  «	  »  	   =     56.  DEG  F

                       NP                 12


                                   3.1416 • (DIA/2)**2        3.1416 • (  60.000/2)**2
          AREA(CIRCULAR STACK)  =  	   =  	  =   19.635 SO FT
                                           144                        144


                     85.49 * PTC • OELP        85.49  •  .84 •    25.9
          STVEL  «	•	——.	  s  	—	—  =   63.2 AFPM
                     SORT(MM * STPHES)         30MTI  28.73 •   30.2 )


          VOLFLH  •  60. • STVEL • AREA  =  60.  •   63.2  •  19.635  =   74406.2 ACFM


          SVOLFLM  B  VOLFLM • STPRES •  ( 460. »  68. )      74406.2 •  30.2 • ( 460. + 68. )
                      	.	.	.	.	  =  	.	.	  s     76854.5 ACFM

                          29.92 • ( STEMP «• 460.  )                29.92 •  (   56.3 » 460. )


          SVOLFLD e SVOLFLH * (1 - BW) =   76854.5  * (1  -    .01) s    76086.0 DSCFM

-------
                STACK VELOCITY DAT*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO-TACOMA, WASHINGTON
01/13/83
•4 SECONDARY FXHAUST
  V-19
CLOCK TIME 1147
OPERATOR OF
AMBIENT TEMP. (DEG.F) 50.
BAR. PRESS. (IN HG) 30.43
STATIC PRESS. (IN H£0) -3.00
MOLECULAR HEIGHT ?H.73
STACK INSIDE DIM(IN) 60.000
PITOT TUBE COEFF. .84
MOISTURE CONTENT(S) 1.00





>
1
•u
o






TRAVERSE
POINT
NO.
C-01
C-02
C-OJ
C-04
C-05
C-06
0-01
0-OZ
0-03
0-04
0-05
0-06
POSITION VELUCI1T
INCHES HtAU
(IN H?0)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.200
.400
.400
.300
.400
.100
.200
.400
.400
.300
.400
,3Ud
STACK
TEMP
(I)EG.F)
56.
56.
57.
57.
56.
56.
55.
55.
56.
56.
56.
56.
AVERAGE
        1.3J7
56.

-------
       PLANT                 ASAHCO-TACOMA, WASHINGTON
       DATE                  01/13/83
       SAMPLING LOCATION     *« SECONDARY EXHAUST
       RUN NUM8EK              V-19

STACK AREA, 30. FT.                  19.635
STACK ABS. PRES., IN H6.             30.21
STACK GAS TEMPERATURE, OE6.F          56.
SORT(VEL HD X STACK TEMP ABS)        2b.O

STACK GAS VELOCITY, ACT. FPS         63.5
STACK GAS VOLUME (NET), ACT. CFM. 74797.2
STACK GAS VOLUME (DRV), ACT. CFM. 74049.2
STACK GAS VOLUME » 29.92 IN. HG AND 66 DG. F  :
             (DRY)                76504.2
             (WET)                77277.0

-------
                                                         SAMPLt CALCULATIONS
           SYMBOLS!
                     AREA      CROSS-SECTIONAL STACK ARkA,  SO Fl
                     BPRES     BAROMETRIC PHESSUkE,  IN HG
                     UELP      DELTA P
                     DIA       DIAMETER OF CIRCULAR  STACK,  IN
                     01MI      LENGTH OF RECTANGULAR STACK,  IN
                     DIM2      WIDTH OF RECTANGULAR  STACK,  IN
                     MOIST     MOISTURE CONTENT
                     MM        MOLECULAR WEIGHT
                     NP        NUMBER OF TRAVERSE POINTS
                     BM        MOLE FRACTION WATER VAPUH
                                                             Htt        PITUT 1UBE C.UEFFICENT

                                                             SPKFS     StAllL PHESSURt, IN H20
                                                             STtMH     STACK IKMPtHA 1UWt, UtG F
                                                             STPRtS    STACK PRESSURE, IN Hli

                                                             STVEL     STACK VELOCITY, AFPM

                                                             IEMP      TkMPtRATURE, DtG F

                                                             VH         VELDCHV HEAU,  IN H20

                                                             SVULFLW   SUNUAHI) VULUMtTHIC FLOW  (WET),  ACFM

                                                             VOLFLW    VOLUMETRIC FLOW (MET), ACFM

                                                             SVULFLU   STANUAMI) VULUMtTklC FLOW  (DRY),  DSCFM
                                                                           26.0
                                                                                      30.? IN HG
>

N>
FORMULAS AND SAMPLE CALCULATIONS:


                    SUMfSORTtVH •  TEMP))           312.6

          DELP  *  	—	  =   	   =
                          NP                        12


          STPRES  =  BPRES » (SPRES/13.6)  =   30.43  *  ( -3.00/13.6)   =


                     SUM (STEMP)           672.
                       ..........   s  ..»..-----   :    5b.  DILG  F

                       NP                 12


                                   3.1416 *  (OIA/2)**2        3.14|(> *


                                           144                        1


                     SS.49 • PTC • DELP        65.49  •   .64 •    26.0
                    ....................  s   .......................

                     SORTIMW * STPRES)         SURTI  20.73 •   30.2 )


          VOLFLN  »  60. • STVEL • AREA  =  60.  • 63.5 •   19.635  =   74797.2 ACFM


          SVOLFLW  s  VOLFLW • STPRES •  ( 460. *  66. )        74797.2 *  30.2 • ( 460. » 68.  )


                          29.92 •  ( STEMP » 460.  )                29.92 • (   56.0 » 460. )


          SVOLFLD = SVOLFLW •  (1 - BW) =   77277.0 * (I -     .01) =     76504.2 OSCFM
                     STEMP  a
                     AREACCIRCULAR STACK)  =
STVEL  a
                                                                                    19.635  SU FT
                                                                                      63. 5 AFPM
                                                                                                                  77277.0 ACFM

-------
                STACK VELOCITY 0*1*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBEH
ASARCO-TACOMA, WASHINGTON
01/13/63
*q SECONDARY EXHAUST
  v-ao
CLOCK TIME 1151
OPERATOR OF
AMBIENT TEMP. (DEG.F) 50.
BAR. PRESS. (IN HG) 30.43
STATIC PRESS. (IN H20) -2.90
MOLECULAR WEIGHT 26.73
STACK INSIDE DIM(IN) 60.000
PITOT TUBE COEFF. .64
MOISTURE CONTENT(t) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
D-01 .0
D-02 .0
0-05 .0
0-04 .0
D-05 .0
D-06 .0
C-OI .0
C-02 .0
C-03 .0
C-04 .0
C-03 .0
C-Ofc .0









VELOCITY
HEAD
(IN H20)
.100
.400
.500
.500
.400
.300
.100
.400
.250
.200
.250
.100









STACK
TEMP
(DEG.F)
50.
55.
5t>.
57.
57.
57.
57.
57.
57.
57.
57.
57.
AVERAGE
        1.292
57.

-------
       PLANT                 ASARCO-TACOMA, MASHINbTON
       DATE                  01/13/83
       SAMPLING LOCATION     »4 SECONDARY EXHAUST
       RUN NUMBER              V-30

STACK AREA, SO. FT.                  19.635
STACK ASS. PRES.t IN H6.             30.22
STACK GAS TEMPERATURE* OE6.F          57.
SORT(VEL HD X STACK TEMP A93)        25.8

STACK CAS VELOCITY, ACT. FPS         65.9
STACK GAS VOLUME (MET), ACT. CFM. 74050.7
STACK GAS VOLUME (DRV), ACT. CFM. 73310.2
STACK GAS VOLUME 3 29.92 IN. HG AND 66 DG. F t
             (DRY)                75665.8
             (*ET)                76450.3

-------
                                                      SAMPLE CALCULATIONS
        SYMBOLS!
                  AREA      CROSS-SECTIONAL STACK AREA, SQ FT
                  BPRES     BAROMETRIC PRESSURE, IN HG
                  DELP      DELTA P
                  DIA       DIAMETER OF CIRCULAR STACK, IN
                  OIM1      LENGTH OF RECTANGULAR STACK,  IN
                  I) I Ma      MIOTH OF RECTANGULAR STACK, IN
                  MOIST     MOISTURE CONTENT
                  MM        MOLECULAR HEIGHT
                  NP        NUMBER OF TRAVERSE POINTS
                  BM        MOLE FRACTION HATER VAPOR
                                                                       PTC       PHUT TUBE CUEFF1CENT

                                                                       SPUES     STATIC PRESSURE, IN H20

                                                                       SUMP     STACK TEMPERATURE, DEG F

                                                                       STPRES    STACK PRESSURE, IN HG

                                                                       STVEL     STACK VELOCITY, AFPM

                                                                       TEMP      TEMPERATURE, OEG F
                                                                       VH        VELOCITY HEAU, IN M2U

                                                                       SVULFLM   STANDARD VULUMETMIC FLUN  (MET),  ACFM

                                                                       VtlLFLM    VOLUMETRIC FLUM (MET), ALFM

                                                                       SVOLFLO   STANUARO VOLUMETRIC FLOM  (DRY),  OSCFM
**
Ul
                                                                        25.8
FORMULAS AND SAMPLE CALCULATIONS:


                    SUM(SORT IVH • TEMPI)           309.5

          OELP  «  —	-	  =  	
                          NP                        12


          STPRES  =  BPRES * (SPRES/13.6)  =  30.03  »  (  -2.90/13.6)


                     SUM(STEMP)           676.
                     ............  s  -....-.-.-  z

                       NP                 12
                  STEMP  *
57. OEG f
                                           3.1416 •  (DIA/2)**2
        3.iai6
                                                                                   30.2 IN MG
                                                                          60.000/2)«*2
                  AREA(CIRCULAR STACK)  s
                                                                                              19.635 SO FT
                                                   144                        144


                                                      65.49  •   .64  •    25.6
                     65.49 * PTC • OELP
          STVEL  «  ...........	.  *  ..............	...

                     SORT(MM * STPRES)        SORT I   26.73 •   30.2 )
                                                                                   62.9 AFPM
                  VOLFLM  «  60. • STVEL • AREA  =  60. •   62.9  •   19.635  =    74050.7 ACFM
                  SVOLFLN  «  VOLFLM * STPRES •  ( 460. * 66.  )
                              ...._......-..........._....-...   s

                                  29.92 * ( STEMP » 460. )


                  SVOLFLO e SVOLFLM • (1 - BM) s   76450.3  *  (1  -
                                                              74050.7  •  30.2 * ( 460. * 68. )
                                                             • ••••^••••••••••••••••^•••••••••••v

                                                                  29.92 * (   56.S » 4bO. )


                                                              .01)  s    75665.B OSCFM
                                                76450.3 ACFM

-------
                STACK  VELOCITY  DAI*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO-TACOMA, (WASHINGTON
01/13/83
«0 SECONDARY tXHAUST
  V-21
CLOCK TIME
OPERATOR
AMBIENT TEMP
1155
OF
. (DE6.F) 50.



BAR. PRESS. (IN H6) 30.43
STATIC PRESS
MOLECULAR ME
STACK INSIDE
.(IN H20) -2.80
I6HT 26.73
DIM(IN) 60.0UO



PITOT TUBE COEFF. .64
MOISTURE CONTENT(X) 1.00
TRAVERSE
POINT
NO.
C-OI
C-OZ
003
C-04
C-05
C-Ob
0-01
0-02
D-03
0-04
0-05
0-06
POSITION VELOCITY
INCHES HEAD
(IN H20)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.200
.400
.450
.400
.500
.250
.250
.450
.500
.400
.450
.300
STACK
TEMP
IOEG.F)
55.
56.
57.
57.
57.
57.
56.
56.
57.
57.
57.
5B.
AVERAGE
        1.379
57.

-------
            PLANT                 A3ARCU-TACOMA, HASH ING TUN
            DATE                  01/13/83
            SAMPLING LOCATION     «4 SECONDARY EXHAUST
            RUN NUMBER              V-21

     STACK AREA, SO. FT.                  19.635
     STACK AB8. PRES., IN H6.             30.23
     STACK GAS TEMPERATURE, OEG.F          57.
     SQRT(VEL HO X STACK TEMP ABS)        26.7

     STACK GAS VELOCITY, ACT. FPS         65.0
     STACK GAS VOLUME (WET), ACT. CFM. 76588.5
     STACK GAS VOLUME (ORV), ACT. CFM. 75822.6
     STACK GAS VOLUME » 29.92 IN. MG AND 68 06. F  :
                  (ORT)                78273.5
                  (NET)                79064.1
.P.

-------
                                                         SAMPLE CALCULATIONS
           3YMBOLSI
                     AREA       CROSS-SECTIONAL STACK AREA, SlJ FT
                     BPRES      BAROMETRIC PRESSURE, IN HP,
                     DELP       OELTA  P
                     OIA        DIAMETER OF CIRCULAR STACK, IN
                     DIM1       LENGTH OF REC1ANUULAR STACK, IN
                     DIM2       WIDTH  OF RECTANGULAR SIACK. IN
                     MOIST      MUISTUNE CUNUNT
                     MM         MOLECULAR HEIGHT
                     NP         NUMBER OF TRAVERSE POINTS
                     BN         MOLE FRACTION MATER VAPOR
                                                                       PTC       P1TOT TUBE COEFF1CENI
                                                                       SPUES     STATJC PktSSUHE,  IN  H2U
                                                                       STEMP     STACK TEMPERATURE, OEB F
                                                                       STPRES    STACK PRESSURE,  IN HG
                                                                       STVfL     STACK VELOCITY,  AFPM
                                                                       TEMP      TEMPERATURE, OEG  f
                                                                       VH        VELOCITY HEAD,  IN M20
                                                                       SVULFL"   STANUAhU VOLUMETRIC  FLU*  (*F_T),  ACFM
                                                                       VULFLM    VOLUMfTHir FLOn  INET), ACFM
                                                                       bVULFLU   STANDAHU VOLUMETRIC  FLOW  (DRY),  DSCFM
 I
>U
00
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM [SORT I VH * TEMP)I           320.1
          DELP  »  —	   s   	   =     26.7
                          NP                        \i

          STPRES  «  BPRES » (SPHES/l3.b)   =   30.03  »  I -a.80/13.b)   =    30.2 IN HP,

                     SUM(STEMP)           6flO.
          StlEMP  =  —	  e  ——	-   =     57.  DEG  F
                       NP                 ia

                                   3.1416 *  lDIA/a)«*2        3.1416 • ( (>0.000/2)**a
          AREACCIRCULAR STACK)  =  	   r  	  r    11.635  SH  FT
                                            144                        tan

                     85.49 • PTC • DELP        85.49  •   .84 •    26.7
          9TVEL  »  .....——.—. ——-  =  ..............—.......  =   fc^.o AFPM
                     SORT (MM • STPRES1         SORT I  26.73 *   30.2  1

          VOLFLH  a  bO.  • STVEL • AREA  s  60.  *  65.0 •  19.635   =   76588.5 ACFM

          SVOLFLN  •  VOLFLN • STPRES  •  ( 460. * 68. )       76508.5 *  30.2 • ( «bO. » 68.  )
                      ................................ =  ...	.....—.......	.....—....   s      79064.1  ACFM
                          29.92 • « STEMP * 060. )                29.92 • (   56.7 * «bO. )

          SVOLFLD = SVOLFLH •  (1 - BH)  =    79064.1 • (1 -    .01)  =     7H273.5 OSCFM

-------
                STACK VELOCITY DAT*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO
01/14/83
NO 4 SECONDARY EXHAUST
  V-22
CLOCK TIME 1525
OPERATOR SCHEFFEL
AMBIENT TEMP. (OE6.F) 49.
BAR. PRESS. (IN H6) 30.36
STATIC PRESS. (IN H20) -3.00
MOLECULAR HEIGHT 28.73
STACK INSIDE DIH(IN) 60.000
PITOT TUBE COEFF. .64
MOISTURE CONTENT(I) 1.00




>

.tit
vo







TRAVERSE
POINT
NO.
0-01
0-02
Q-03
0-04
0-OS
0-06
c-ot
C-02
C-03
C-04
C-OS
C-06
POSITION VELOCITY
INCHES HEAD
(IN H20)
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.200
.500
,700
.600
.900
.300
.200
.500
.500
.400
.300
.100
STACK
TEMP
(DEG.F)
49.
50.
51.
52.
S3.
53.
51.
52.
52.
52.
53.
53.
AVERAGE
        1.433
52.

-------
         PLANT                  ASARCO
         DATE                   01/14/83
         SAMPLING  LOCATION     NO fl SECONDARY E.XHAUST
         RUN NUMBER               V-2<»

   STACK  AREA, SO.  FT.                   19.635
   STACK  ABS. PRES.f  IN  H6.             30.Oa
   STACK  CAS TEMPERATURE.  OEG.F           52.
   30RKVEL MO X STACK TEMP ABS)         27.0

   STACK  GAS VELOCITY, ACT. FPS          66.0
   STACK  GAS VOLUME  (MET),  ACT.  CFM. 77767.6
   STACK  GAS VOLUME  (DRV),  ACT.  CFM. 76989.9
   STACK  GAS VOLUME 9 29.92 IN.  HG AND 68 06. F :
                (DRY)                 79751.7
                (MET)                 80557.2
en
o

-------
                                                         SAMPLE CALCULATIONS
           SYMBOLS:
                     AREA       CROSS-SECTIONAL  STACK AREA, SO FT
                     BPRES      BAROMETRIC  PRESSURE,  IN HG
                     OELP       DELTA  P
                     OIA        DIAMETER OF  CIRCULAR  STACK, IN
                     DIM1       LENGTH OF RECTANGULAR STACK, IN
                     DIM?       HIDTN  UF RECTANGULAR  STACK, IN
                     MOIST      MOISTURE CONTENT
                     MM        MOLECULAR HEIGHT
                     NP        NUMBER OF TRAVERSE POINTS
                     BM        MOLE FRACTION MATER VAPOR
                                                                       Pit        PITUT  TUBE CUEFF1CENT

                                                                       3PKES      STATIC  PWESSURt, IN H2U
                                                                       STtMP      STACK  TEMPERATURE, DEG F

                                                                       STPRES     STACK  PRESSURE, IN HG

                                                                       STVEL      STACK  VELOCITY, AFPM

                                                                       TEMP      TEMPERATURE, f>EG F
                                                                       VH         VELOCITY HEAD, IN H20

                                                                       SVULFLW   STANDARD VOLUMETRIC FLOM  (MET),  ACFM

                                                                       VULFLM     VULUMF.TRIC FLOW (WET), ACFM

                                                                       SVOLFLD   STANDARD VOLUMETRIC FLUN  (DRY),  USCFM
>
FORMULAS AND SAMPLE CALCULATIONS:


                    SUMI30RTIVM • TEMP)|           324.1
          OELP  «  —•	  e   	   e     27.0

                          NP                        12


          STPRES  »  BPRES * (SPRES/13.6)  =   30.26  »  ( -3.00/13.6)   =     30.0 IN HG


                     SUMCSTEMP)           621.
          3TEMP  «	—	  e  —	  =     52.  OEG  F
                       NP                 12


                                   3.1416 • (DlA/2)**2        3.1416  *  (  60.000/2)**2
          AREA(CIRCULAR STACK)  s  ----—	- —-   t	— —	—  =   19.635 SO FT

                                           144                        Ma


                     85.49 • PTC • OELP        85.49  •  .84 «    27.0
          STVEL  *  ....................  s  .......................   z   66.0 AFPM

                     SORT(MM * STPRES)         SORT!  28.73 *   30.0  I


          VOLFLN  «  60. * STVEL * AREA  z  60.  •   66.0 •  19.635   =    77767.6 ACFM


          SVOLFLM  s  VOLFLM • STPRES  •  ( 460. » 68. )      77767.6  •  30.0 * (  460. » 68. )
                      	.	 r  	  =     80557.2 ACFM

                          29.92 • ( STEMP «• 460. )               29.S2  •  (   51.8 » 460. )


          SVOLFLD « SVOLFLW •  (1 - BM) =   80557.2  • (1 -    .01) =     79751.7 DSCFM

-------
                     STACK  VELOCITY  DATA
         PLANT
         DATE
         SAMPLING LOCATION
         RUN NUMBER
ASARCO
01/18/83
N04 SECONDARY EXHAUST
  v-as
>

ro









TRAVER
POINT
NO.
01
02
03
0«
05
06
01
02
OS
04
05
Ob
CLOCK TIMt 0
OPERATOR SCHEFFEL
AMBIENT TEMP. (OE6.F) 55.
BAR. PRESS. (IN H6) 29.53
STATIC PRESS. (IN H20) -2.50
MOLECULAR NEI6HT ?8.73
STACK INSIDE OIM(IN) 60. QUO
PITOT TUBE COEFF. .84
MOISTURE CONTENT(I) 1.00
SE POSITION \
INCHES

.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0









/ELUCITY STACK
HEAD TEMP
(IN H80) IOEG.F )
.900 5<».
.200 50.
.300 50.
.300 50.
.400 5-».
.400 0.
.100 57.
.300 58.
.300 58.
.400 5«.
.400 SH.
1.400 5H.
    AVERA6E
        1.283
53.

-------
         PLANT                  ASARCO
         DATE                   01/18/83
         SAMPLING  LOCATION      NOO  SECUNDAHY EXHAUST
         RUN NUMBER               V-23

  STACK  AREA, 38.  FT.                   19.635
  STACK  A8S. PRES.,  IN  H6.              29.35
  STACK  GAS TEMPERATURE*  DE6.F           53.
  SORT(VEL HO X  STACK  TEMP  ABS)         25.6

  STACK  CAS VELOCITY,  ACT.  FPS          63.3
  STACK  GAS VOLUME (NET),  ACT.  CFM. 74616.0
  STACK  GAS VOLUME (DRY),  ACT.  CFM. 73069.8
  STACK  GAS VOLUME a 29.92  IN.  HG AND 66 DG. F :
               (DRY)                 74S3S.3
               (*»ET)                 75288.2
>
Ul

-------
                                              SAMPLE CALLULAT1UNS
SYMBOLS!
          ARE*      CROSS-SECTIONAL S1ACK AHfcA,  SO F1
          BPRE3     BAROMETRIC PHtSSUHt, IN HG
          UELP      OELTA P
          DIA       DIAMETER OF CIRCULAR STACK,  IN
          OIM1      LENGTH OF RECTANGULAR STACK,  IN
          DIMS      NIOTH OF RECTANGULAR STACK,  IN
          MOIST     MOISTURE CONTENT
          M*        MOLECULAR WEIGHT
          NP        NUMBER OF TRAVERSE POINTS
          BM        MOLE FRACTION MATER VAPOH
                                                                                HIC       PII01 IUHE CUFFFICtNT
                                                                                SPHES     S1A1IC PkESSUHt,  IN M20
                                                                                b!tMP     STALK TEMPt»ATUHt, OEG F
                                                                                STPHE3    STACK HHtSSURE,  IN HG
                                                                                STVF.L     S1ACK VELOCITY,  AFPM
                                                                                ThMH      1F.MPEWATURE , OEG  F
                                                                                VM        VtLDLIIY Ht«U,  IN H20
                                                                                SVULFLw   SfANUAHO VULUMETHIC FLUW  (w£T),  ACFM
                                                                                VOLFLW    VIILUMEtHIC FLOW  CWET), ACFM
                                                                                SVUI.FLO   STANOARO VOLUMETRIC FLUM  (URT),  OSCFM
>
Ul
FORMULAS AND SAMPLE CALCULATIONS:

                    SUMI30RTIVH * TEMP)]           307.3
          DELP  «  —	  *   	   =     ?5.b
                          NP                        12

          STPRES  s  BPRES » (SPRES/13.6)  =   89.53 *  ( -2.50/13.h)   =     29.3 IN HG

                     SUMCSTEMP]           639.
          SfEMP  s  	  *  	   =     53.  OEG  F
                       NP                 12

                                   3.1016 *  (DIA/2)**2        3.1416 •  (  60.000/2)«*2
          AREA(CIRCULAR STACK)  s  	   =   	  =   19.635 SO FT
                                           laa                        Ma

                     85.«9 • PTC • DELP        85.09 *  .Bfl •    25.6
          STVEL  *  ——-•	  e  	.	—	 =    63.3 AFPM
                     SORT (MM • STPRES)         SORT!  28.73 *   29.3  )

          VOLFLN  *  60. * STVEL • AREA  s  60. *   63.3 *  19.635  =   74616.0 ACFM

          SVOLFLM  -  VOLFLM • STPRES •  ( 46U. »  68. )        74616.0 *  29.3 • ( 46V. * 68. )
                      .	......	.	 =  -.	.	.	  =     75286.2  ACFM
                          29.92 « I STEMP * 460.  )                29.92  •  (   53.3 « 460. )

          SVOLFLD s SVOLFLH •  (1 - B»O =   75288.2  * (1 -     .01) s     74535.3 OSCFM

-------
                STACK VELOCITY DAT*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO
01/19/B3
NO 4 SECONDARY EXHAUST
  v-24
CLOCK TIME 1404
OPERATOR DO
AMBIENT TEMP. (OEG.F) 46.
BAR. PRESS. (IN HG) 29.55
STATIC PRESS. (IN M20) -3.00
MOLECULAR HEIGHT 88.75
STACK INSIDE OIM(IN) 60.000
PITOT TUBE COEFF. .64
MOISTURE CONTENT(X) 1.00
TRAVERSE



>
1
Ui
Ul







POINT
NO.
01
02
OS
04
OS
06
01
02
OS
04
OS
06
POSITION VELOCITY
INCHES HEAD
(IN H20)
.0 .980
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.250
.300
.350
.400
.500
.860
.200
.300
.350
.500
.550
STACK
TEMP
(OtG.F)
55.
58.
60.
61.
62.
62.
60.
62.
62.
63.
63.
HO.
AVERAGE
        1.295
61,

-------
        PLANT                 A3ARCU
        DATE                  01/19/83
        SAMPLING LOCATION     NO 4 SECONDARY EXHAUS1
        RUN NUMBEK              V-2«

 STACK AREA, 90. FT.                  19.635
 STACK ABS. PRES., IN HG.             39.33
 STACK GAS TEMPERATURE.  DEG.F           bl.
 SORT(VEL  HO X  STACK TEMP ABS)         Z5.9

 STACK GAS VELOCITY, ACT. FPS          64.U
 STACK GAS VOLUME (NET), ACT.  CFM. 7*446.a
 STACK GAS VOLUME (DRV), ACT.  CFM. 74691.7
 STACK GAS VOLUME 9 29.92 IN.  HG AND 66 DG. F :
              (DRV)                74248.6
              (WET)                74998.6
 I
Ul
(TV

-------
                                                       SAMPLE CALCIJLA1 IONS
        SYMBOLS:
                   ARE*       CROSS-SECTIONAL STACK ARE*, SO FT
                   BPRES      BAROMETRIC  PRESSURE, IN Hf.
                   OELP       DELTA  P
                   OIA        DIAMETER  OF  CIRCULAR STACK, IN
                   DIM1       LENGTH OF RECTANbULAR STACK, IN
                   OIM2       WIDTH  OF  RECTANGULAR STACK, IN
                   MOIST      MOISTURE  CONTENT
                   MM         MOLECULAR HEIGHT
                   NP         NUMBER OF TRAVERSE POINTS
                   BM         MOLE FRACTION hATEH VAPOH
                                                                       PTC        PITOT  TUBE  COEFF1CENT
                                                                       SPKKS      STATIC  PKESSURE, IN H20
                                                                       SIEMP      STACK  TEMPERATURE, otc F
                                                                       STPHES     STACK  PRESSURE, IN HG
                                                                       3TVEL      STACK  VELOCITY, AFPM
                                                                       TEMP       TF.MPERATURE,  PEG F
                                                                       VH         VF.LUCITY  HEAD,  IN H20
                                                                       SVOLFLW    STANDARD  VOLUMETRIC FLOH  (NET),  ACFM
                                                                       VULFL*     VOLUMETRIC  FLOH (WET), ACFM
                                                                       SVULFLU    STANUAMD  VULUMfcTHlC FLUW  (URt),  OSCFM
 I
Ul
FORMULAS AND SAMPLE CALCULATIONS:

                    SUMISORTIVH  *  TEMPI)           310.6
          OCLP  »  ——	  =  	  =    25.9
                          NP                        12

          STPRES  =  BPRES  »  (SPRES/13.6)  =  29.55 » ( -3.00/J3.6)   =     29.3  IN HG

                     SUM(STEMP)            728.
          STEMP  a  —	  s   ——	    61. DEG F
                       NP                  12

                                    3.1416 • (DIA/2)**2        3.1016  •  (  60.000/2) ••<>
          AREA(CIRCULAR STACK)   s   —	—	—-  =	  =   19.635 SO FT
                                            14Q                        144

                     85.49  •  PTC •  OELP       05.49 •  .84 •   25.9
          STVEL  »  —	   =  	  =    64.0  AFPM
                     SORTlMh  * STPRES)         SIJHTl  *8.M •  29.3 I

          VOLFLH  r  60. *  STVEL •  AREA  =  60. •  64.0 *  19.63S  s    75446.2  ACFM

          SVOLFLM  =  VOLFLW  * STPRES • ( 460. * 68. )       75446.2  •  29.3  •  (  460. «• 68. )
                      	...	  =  	.	  s     74998.6 ACFM
                          29.92  *  (  STEMP » 460. )               29.9?  •  (    60.7 »  460. )

          SVOLFLD = SVOLFLW • (1 -  BW)  =    74998.6 • (1 -    .01) =     74248.6  DSCFM

-------
                      STACK  VELOCITY  0»!»
>

00
         PLANT
         DATE
         SAMPLING  LOCATION
         RUN NUHBEH
ASARCU-TACUMA, WASH 1 NUTUN
01/13/63
•4 SECONDARY EXHAUST
CLOCK TIME
OPERATOR
AMBIENT TEMP. (DEG.F)
BAR. PRESS. (IN HG)
STATIC PRESS. (IN H20)
MOLECULAR HEIGHT
STACK INSIDE DIM(IN)
PITOT TUBE COEFF.
MOISTURE CONTENT(t)
TRAVERSE POSITION
POINT INCHES
NO.
C-01 .0
C-OZ .0
C-03 .0
C-04 .0
C-05 .0
C-06 .0
0-01 .0
D-OZ .0
0-03 .0
0-04 .0
0-05 .0
0-06 .0
I04Z
0 FIT2GERALD
45.
30.43
•6.40
26.73
60.000
.84
1.00
VELOCITY
HEAD
(IN H20)
2.900
4.000
3.600
3.500
3.600
3.600
3.100
3.900
4.400
3.700
4.000
3.600









S1ACK
TEMP
(OEG.F)
51.
53.
55.
55.
55.
5b.
52.
54.
54.
55.
55.
55.
     AVERAGE
        3.675
54.

-------
          PLANT                 ASARCO-TACOMA, WASHINGTON
          DATE                  01/13/63
          SAMPLING LOCATION     »4 SECONDARY EXHAUST
          RUN NUMBER              V-12

   STACK AREA, 90. FT.                  19.63%
   STACK ABS. PRES.r IN HG.             29.01
   STACK GAS TEMPERATURE, DEG.F          54.
   S0RT(VEL HD X STACK TEMP ABS)        43.4

   STACK GAS VELOCITY, ACT. FPS        106.5
   STACK GAS VOLUME (NET), ACT. CFM.I2547S.3
   STACK GAS VOLUME (DRV), ACT. CFM.124220.6
   STACK GAS VOLUME tf 39.92 IN. HG AND 66 DG. F  :
                (ORT)               127124.3
                (MET)               126408.4
Ui
vo

-------
                                                           SAMPLE CALCULATIONS
            SYMBOLS!
                      AREA      CROSS-SECTIONAL STACK  AREA,  SO F1
                      BPRES     BAROMETRIC PRESSURE,  IN MR
                      OELP      DELTA P
                      01A       DIAMETER OF CIRCULAR  STACK,  IN
                      OIM1      LENGTH OF RECTANGULAR  STACK,  IN
                      OIM2      MIDTH OF RECTANGULAR  S1ACK,  IN
                      MOIST     MOISTURE CONTENT
                      MM        MOLECULAR MIIGHT
                      NP        NUMBER OF TRAVERSE POINTS
                      BN        MOLE FRACTION HATER VAPOR
SHWES
STVKL
TEMP
VH
SVULFLW
VOLFLW
SVULT-LI)
                                                                                 HITUT  TUBE CUEFFICfcNT
                                                                                 STATIC PRESSURE. IN H2U
                                                                                 STACK  TEMPERATURt, OEG F
                                                                                 STACK  PRESSURE. IN HG
                                                                                 STACK  VELUCITY, AFPM
                                                                                 TEMPERATURE, OfcG F
                                                                                 VELOCITY HEAU, IN M20
                                                                                 STANUAHU VOLUMETRIC FLUM      5«. OEG F
                       NP                 12

                                   3.1016 * (DIA/2)**2        3.1416  *  (  hO.OOO/£)**£
          AREA(CIRCULAR STACK)  *  - — -- — — --	  z	...-. — -.  =   19.635 SO FT
                                           104                        140

                     65.49 * PTC • DELP       85.49 •  .94 *    43.4
          STVEL  »  ———————  s  .._......._ — ._........  s  106.5 AFPM
                     SORTIMM * STPHES)        SORT I  20.73 *  29.8 )

          VOLFLM  s  60. * STVEL * AREA  s  60.  * 106.5 *  19.635  s   125475.3 ACFM

          SVOLFLN  a  VOLFLM * STPRES • ( obo. •» 68. )       125475.3  •  29.11 * (  460. * 6«. )
                      	....	.	....	.	  s  	  s    120408.4 ACFM
                          29.92 • ( STEMP * 060. )               29.92  •  (   54.1 » 060. )

          SVOLFLD s SVOLFLN  •  (1 - BM) =  128408.4  * (1 -    .01) =    127124.3 DSCFM

-------
                  STACK VELOCITY OAT*
      PLANT
      DATE
      SAMPLING LOCATION
      RUN NUMBER

      CLOCK TIME
      OPERATOR
      AMBIENT TEMP. (DEG.F)
      BAR.PRESS.(IN HG)
      STATIC PRESS.(IN H£Q)
      MOLECULAR HEIGHT
      STACK INSIDE DIM(IN)
      PITOT TUBE COEFF.
      MOISTURE CONTENT(S)
TRAVERSE
 POINT
  NO.
POSITION
 INCHES
A9ARCO-TACOMA, HASHINGTUN
01/13/83
04 SECONOAHY EXHAUST
  V-13

1048
OF
 45.
 30.43
 •8.30
 88.73
 60.000
  .04
  1.00

        VELOCITY
          HEAD
        (IN H20)
 STACK
 TEMP
tOtG.F)
  0-01
  0-02
  0-03
  0-04
  D-05
  D-06
  C-01
  C-02
  C-03
  C-04
  C-05
  C-06
    .0
    .0
    S0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
        3.300
        3.900
        4.300
        4.500
        4.600
        3.800
        3.100
        4.100
        3.800
        3.500
        3.400
        3.000
   57.
   55.
   55.
   55.
   55.
   55.
   53.
   53.
   54.
   55.
   55.
   55.
  AVERAGE
                  3.7T5
                                  55,

-------
         PLANT                 A3AHCO-IACUM»,  WASHINGTON
         DATE                  01/13/83
         SAMPLING LOCATION     *t SECONDARY tXMAUS!
         RUN NUMBER              V-1J

  STACK AREA, SO. FT.                   19.635
  STACK ABS. PRE3., IN HG.              29.8?
  STACK GAS TEMPERATURE, DE6.F           55.
  SORTCVEL HD X STACK TEMP »BS)         44.U

  STACK GAS VELOCITY, ACT. FPS         107.9
  STACK GAS VOLUME (MET), ACT. CFM.127122.5
  STACK GAS VOLUME (DRV), ACT. CFM.125851.3
  STACK GAS VOLUME » 29.92 IN. HG AND  68  DC. F  :
               (DRV)               128658.1
               (WET)               129957.6
m
to

-------
                                                         SAMPLK  CALCULATIONS
           SYMBOLS!
                     AREA      CROSS-SECTIONAL  STACK  AREA,  SO  FT
                     BPRES     BAROMETRIC  PRESSURE,  IN  HG
                     DELP      DELIA P
                     OIA       DIAMETER  OF  CIRCULAR  STACK.  IN
                     DIM!      LENGTH OF RECTANGULAR  STACK,  IN
                     DIM2      NIDTH OF  RECTANGULAR  STACK,  IN
                     MOIST     MOISTURE  CONTENT
                     MM        MOLECULAR WEIGHT
                     NP        NUMBER OF TRAVERSE  POINTS
                     BM        MOLE FRACTION  MATER VAPOR
                                                                      HTC       PHUT  TUBF  COEFF1CENT

                                                                      SPUES     STATIC PRESSURE,  IN  M2U
                                                                      STEMP     STACK  TEMPERATURE, Otb F
                                                                      STPRES    STACK  PRESSURE,  IN HG
                                                                      STVEL     STACK  VELOCITY,  AFPM

                                                                      IEMP      TEMPERATURE,  DEC  F
                                                                      VH        VELOCITY  HfcAO,  IN M2U
                                                                      SVULFLW   STANDARD  VOLUMETRIC  FLO* (MET), ACFM
                                                                      VOLFLM    VULUME1H1C  FLOW  (MET),  ACFM

                                                                      SVULFLO   STANDARD  VOLUMETRIC  FLUM (DRY), DSCFM
FORMULAS ANO SAMPLE CALCULATIONS:


                    SUMCSgRTCVH * TEMP)]

          OELP  «  — — --------- ........ -  =
                          NP

AREA(CIRCULAR STACK)  3
           85.49 • PTC • OELP
STVEL  a  	.....	.-  z  	—	..	
           SORT (MM • STPRESI        SORT!  28.73 •  29.8  )
                                                                                    107. •> AFPM
                                                                                    19.635 SU FT
                     VOLFLM   s   60.  «  STVEL  •  AREA   *   60.  * 107.9 •  19.635  =  127122.5 ACFM


                     3VOLFLH  «   VOLFLN  •  3TPRES  •  ( 460.  » 68.  )       127122.5 •  29.8 • ( 460. » 68. )
                                 ...._..._.._._....__............   s  ._._._....-.......................  s

                                    29.92 •  (  S1EMP *  460. )                29.92 * (   54.6 » 460. )


                     SVOLFLO  e SVOLFLM •  (1  -  BM) *  129957.6  •  (1 -    .01) =   128658.1 03CFM
                                                                                                     129957.6 ACFM

-------
                 STACK  VELOCITY UAIA
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBEW
ASARCO-TACUMA, WASHINGTON
01/15/83
»0 SECONDARY EXHAUST
CLOCK TIME
OPERATOR
AMBIENT TEMP. (DEG.F)
BAR. PRESS. (IN HG)
STATIC PRESS. (IN H20)
MOLECULAR HEIGHT
STACK INSIDE OIM(IN)
PITOT TUBE COEFF.
MOISTURE CONTENT(X)
TRAVERSE POSITION
POINT INCHES
NO.
C-OI .0
C-08 .0
C-03 .0
. C-04 .0
•? C-05 .0
cr. C-06 .0
*• 0-0» .0
0-02 .0
0-05 .0
0-0« .0
0-05 .0
0-06 .0
1052
OF
05.
30. a3
-B.au
2B.73
60.000
.64
1.00
VtLUCITY
HEAU
(IN H£0)
3.100
a. ooo
3.800
3.600
3.900
3.300
3.000
3.800
4.100
3.900
0.200
3.200









STACK
TEMP
(ntG.F)
53.
54.
55.
55.
55.
55.
52.
53.
54.
54.
54.
55.
AVERAGE
        3.658
54,

-------
          PLANT                  ASARCU-TACOMA,  WASHINGTON
          DATE                   01/13/83
          SAMPLING  LOCATION      «4  SECONDARY EXHAUST
          RUN NUMBER               V-IU

   STACK  AREA, SO.  FT.                   19.635
   STACK  ABS. PRES.,  IN  H6.              29.83
   STACK  CAS TEMPERATURE,  DEG.F           54.
   SORTCVEL NO X  STACK TEMP  ABS)         43.3

   STACK  GAS VELOCITY, ACT.  FPS         IOb.2
   STACK  GAS VOLUME (NET), ACT.  CFM.125140.2
   STACK  GAS VOLUME (ORV), ACT.  CFM.123896.7
   STACK  GAS VOLUME 9 29.92  IN.  HG  AND  66 DG. F :
                (DRY)                UbflSS.4
                (NET)                128136.6
a\
Ul

-------
                                              SAMPLE CALCULAt IONS
SYMBOLS:
          AREA      CROSS-SECTIONAL STACK AREA, SO FT
          BPRES     BAROMETRIC PHESSURE, IN HP,
          OELP      DELTA P
          OIA       DIAMETER OF CIRCULAR STACK, IN
          DIM1      LENGTH OF RECTANGULAR STACK,  IN
          DIM2      MIDTH OF RECTANGULAR STACK, IN
          MOIST     MOISTURE CUNlENt
          MX        MOLECULAR WEIGHT
          NP        NUMBER OF TRAVERSE POINTS
          BM        MOLE FRACTION MATER VAPOR
SPRES
STtMP
STPRES
STVEL
TEMP
VH
SVULFLW
SVULFLD
P1TUT TUBE CUEKFICENT
STATIC PRESSURE,  IN H20
STACK rtMPERATURt, DEC F
STACK PRESSURE,  IN HG
STACK VELOCITY,  AFPM
TEMPERATURE, OEG  F
VELOCITY HEAD,  IN M20
STANDARD VULUMfcTRIC FLOW  (MET),  ACFM
VOLUMETRIC FLO*  (MET), ACFM
STANDARD VOLUMETRIC FLOW  (URY),  D3CFM
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM(SORT IVH • TEMPI)          519.6
          DELP  »  ——	  =	   «     43.3
                          NP                        12

          STPRES  =  BPRES <• (SPUES/13.6)  =  30.43 »  ( -8.20/13.6)  =    29.8 IN MG

                     SUM(STEMP)           649.
          8TEMP  *  ——.	  s  	.	.  s     54.  OEG  F
                       NP                 12

                                   3.1416 •  (DIA/2)**2        3.1416 • (  60.000/2)«*2
          AREAtCIRCULAR STACK)  a  	   a  	  =    19.635  SO  FT
                                           144                        144

                     85.49 • PTC • OELP       85.49 •   .84 *    43.3
          STVEL  *	  =	—	  =  106.2 AFPM
                     SORT(MM • STPRESI        SORT I  26.73 *   29.6  I

          VOLFLM  a  60. • STVEL * AREA  =   60.  *  106.2 •  19.635  =  125148.2 ACFM

          SVOLFLM  c  VOLFLM • STPRES *  ( 460. » 60. )       125148.2 •  29.8 • ( 460. » 68. )
                      .	 a  ..	.	  r     128136.6  ACFM
                          29.92 • ( STEMP *  «60. )                29.92 •  (   54.1 » 460. )

          SVOLFLO s SVOLFLM •  (1 - BW) =  128136.6  • (1 -    .01) c   126855.4 DSCFM

-------
                STACK VELOCITY OAU
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO-TACOMA, WASHINGTON
01/13/83
•a SECONDARY EXHAUST
  V-15
CLOCK TIME 1056
OPERATOR OF
AMBIENT TEMP. (OE6.F) 45.
BAR. PRESS. (IN H6) 30.43
STATIC PRESS. (IN H?0) -8.40
MOLECULAR HEIGHT 28.73
STACK INSIDE DIM(IN) 60.000
PITOT TUBE COEFF. .84
MOISTURE CONTENT(S) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
0*01 .0
D-OZ .0
0-03 .0
> 0-04 .0
d, 0-05 .0
•J 0-06 .0
C-01 .0
C-02 .0
C-03 .0
C-04 .0
C-OS .0
C-06 .0 !









/ELOCITY
HEAD
UN Heo)
.100
.000
.500
.700
.800
.800
.000
.800
.600
.500
.500
5.300









STACK
TEMP
(DtG.F)
52.
53.
54.
54.
55.
55.
52.
53.
53.
54.
55.
54.
AVERASC
        3.883
54.

-------
        PLANT                  ASARCO-TACUMA,  WASHINGTON
        DATE                   01/13/03
        SAHPLINC LOCATION      04  SF.CONDAHY  kXHAUSf
        RUN NUMBEH              V-IS

 STACK AREA, 90. FT.                   19.635
 STACK AB3. PRES.,  IN HG.              29.61
 STACK CAS TEMPERATURE, DE6.F           54.
 SQRTCVEL HO X STACK TEMP  AB9)         40.5

 STACK GAS VELOCITY, ACT.  FPS         10V.2
 STACK CAS VOLUME  (NET), ACT.  CFM.128b8b.?
 STACK CAS VOLUME  (DRY), ACT.  CFM.127398.4
 STACK GAS VOLUME 9 29.92  IN.  HG  AND  68 UG. F :
               (DRY)                130462.2
               (NET)                131800.2
m

-------
                                                       SAMPLE C*LCUL*IIONS
         SYMBOLS:
                   AREA      CROSS-SECTIONAL STACK AREA,  SU  FT
                   BPHES     BAROMETRIC HkESSURE, IN HG
                   UELP      DELTA P
                   OIA       DIAMETER OF CIRCULAR STACK,  IN
                   DIMI      LENGTH OF RECTANGULAR STACK,  IN
                   DIM2      MIDTH OF RECTANGULAR STACK,  IN
                   MOIST     MOISTURE CONTENT
                   MM        MOLECULAR WEIGHT
                   NP        NUMBER OF TRAVERSE POINTS
                   Bh        MOLE FRACTION MATER VAPOR
                                                             PTC        PHOT  TUBF. COEFFICENT
                                                             SPHtS      STATIC  PHESSURt, IN M20
                                                             SUMP      STACK  TEMPERATURE,  UtG F
                                                             STPRES     STACK  PRESSURE, IN HG
                                                             STVEL      STACK  VELOCITY, AFPM
                                                             ItMP       TEMPERATURE,  OEG F
                                                             VH         VELOCITY HEAD,  IN M20
                                                             SVULFLM    STANDARD VOLUMETRIC FLOM (MET), ACFM
                                                             VOLfLM     VOLUMETRIC FLOW IMET), ACF*
                                                             SVOI.FLD    STANDARD VOLUMETRIC FLOM CORY), DSCFM
o\
vo
                                                                         oo.5
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM (SORT (VH * TEMPI I          530.2
          DELP  «  -	
                          NP                        12

          STPRES  »  BPRES » (SPRES/13.6)  a  30.03 »  ( -ft.00/13.6)

                     SUMISTEMP)           600.

                       NP                 12
                   STEHP  t
                                            50. DEG F
                                                                                    29.fl IN HG
          AREA(CIRCULAR STACK)  =
                                            3.1016  •  (DIA/2)**2
                                                     100
                                                     3.1016  *  (  60.000/2)***
                                                                               100
                                                                                    19.63S SO FT
           85.49 * PTC • DELP       85.09 •  .80 •    00.5
STVEL  «  —	———	  *  	—	—	—   «   109.2  AFPM
           SORT(MN * STPRES)        SURT I  26.73 •  29.8 I

VOLFLN  •  60. • STVEL • AREA  =  60. * 109.2 •  19.635  *   128685.2  ACFM

SVOLFLN  *  VOLFLN * STPRES • ( 060. «• 68. )      128665.2  •   29.8  •  (  060.  » 68. )

                29.92 • ( STEMP •» 060. )               29.92  • (    53.7 » 060. )

SVOLFLD * SVOLFL* * (1 - HM) =  131800.2 • (1 -     .01) «    130082.2  DSCFM
                                                                                                              131800.2 ACFM

-------
                  STACK VELOCITY DATA
      PLANT
      DATE
      SAMPLING LOCATION
      RUN NUMBEH

      CLOCK TIME
      OPERATOR
      AMBIENT TEMP. (DE6.F)
      BAR.PRESS.(IN MS)
      STATIC PRESS.(IN H20)
      MOLECULAR HEIGHT
      STACK INSIDE DIM(IN)
      PITOT TUBE COEFF.
      MOISTURE CONTENT(t)
TRAVERSE
 POINT
  NO.
POSITION
 INCHES
ASARCO-TACOMA, WASHINGTON
01/13/83
•4 SECONDARY tXHAUST
  V-lb

1059
OF
 45.
 30.43
 -8.20
 28.73
 60.000
  .84
  1.00

        VELOCITY
          HEAD
        (IN H20)
 STACK
 TEMP
(OEG.F)
  C-Ol
  C-02
  C-03
  C-04
  C-05
  C-06
  0-01
  0-02
  0-OS
  0-04
  0*05
  0-Ofc
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
         .500
         .900
         .800
         .800
         .500
         .400
         .000
         .000
         .000
         .800
         .900
         .400
   53.
   54,
   54.
   54.
   54.
   55.
   51.
   53,
   53.
   54.
   54,
   55.
  AVERAGE
                  3.667
                                  54.

-------
       PLANT                 ASARCO-TACOMA, WASHINGTON
       DATE                  01/13/03
       SAMPLING LOCATION     «« SECONDARY EXHAUST
       RUN NUMBER              V-16

STACK AREA, SO. FT.                  19.635
STACK ASS. PRES., IN H6.             29.83
STACK GAS TEMPERATURE, DE6.F          54.
3QRMVEL HD X STACK TEMP ABS)        03.4

STACK GAS VELOCITY, ACT. FPS        106.4
STACK GAS VOLUME (MET), ACT. CFM.125321.5
STACK GAS VOLUME (DRV), ACT. CFM.120068.3
STACK GAS VOLUME d 29.92 IN. HG AND 66 DG. F :
             (DRY)               127134.1
             (MET)               1284IB.3

-------
                                              SAMPLE  CALCULATIONS
SYMBOLS!
          AREA      CROSS-SECTIONAL STACK AREA, SO F1
          8PRES     BAROMETRIC PkESSURt,  IN HG
          OELP      DELTA P
          OIA       DIAMETER OF CIRCULAR  STACK, IN
          DIM!      LENGTH OF RECTANGULAR STACK, IN
          DIM2      WIDTH OF RECTANGULAR  STACK, IN
          MOIST     MOISTURE CUNIENT
          MM        MOLECULAR HEIGHT
          NP        NUMBER OF TRAVERSE POINTS
          BM        MOLE FRACTION HATER VAPOR
                                                                      PTC       PITOT TUBE CUEFFICENT
                                                                      SPUES     STATIC PRESSURE,  IN  M2U
                                                                      STtMH     STACK TEMPERATURE, DEG F
                                                                      STPRES    STACK PRESSURE,  IN HG
                                                                      STVEL     STACK VELOCITY,  AFPM
                                                                      TEMP      TEMPERATURE, OEG  F
                                                                      VH        VELOCITY HEAD,  IN M2U
                                                                      SVOLf-LH   STANDARD VOLUMETRIC  FLOM  (MET),  ACFM
                                                                      VOLFLN    VOLUMETRIC FLON  (MET), ACFM
                                                                      SVOLFLD   STANOAHO VOLUMETRIC  FLUM  (DRY),  OSCFM
                                                               43.4
FORMULAS AND SAMPLE CALCULATIONS:

                    SUMCSORMVH • TEMP))          520.4
          DCLP  •  •.••.--•-•--..----.---  s  ..........  s
                          NP                       12

          STPRES  e  BPRES » (SPkES/13.6)  =  30.43 * ( -8.20/13.6)  =    29.fl IN HG

                     SUM(STEMP)           644.
                    .	..	  3  -——	.  =    54. DEG F
                       NP                 12

                                   3.1416 * (DlA/2)**2        3.1416 • ( 60.000/2)**2
                                     ....................  s  ---..-..........-.--..-...  s
                                           144                       144

                     83.49 • PTC • DELP       85.49 •  .84 •   43.4
                    ....................  s  .......................  s  106.4 AFPM
                     SURTCMH • STPRES)        SORT I  28.73 *  29.8 )

          VOLFLM  »  60. * STVEL * AREA  >  60. * 106.4 •  19.635  *  125321.5 ACFM

          SVOLFLN  z  VOLFLM • STPRES * ( 460. * 68. )      125321.5 •  29.8 • ( 460. * 68.  )
                      _..._....__................._...  s  ..................................
                          29.92 • ( STtMP «• 460. )               29.92 • (   53.7 » 460. )

          SVOLFLD = SVOLFLH •  (1 - BM =  12841B.3 * (1 -    .01) s   127134.1 PSCFM
          STEMP  «
AREA(CIRCULAR STACK)  *
          STVEL
                                                                                              19.635  SO  FT
                                                                                                     138418.3  ACFM

-------
                STACK VELOCITY OAT*
    PLANT
    DATE
    SAMPLING LOCATION
    RUN NUMBER
ASARCO
01/19/83
NO a SECONDARY EXHAUST
  V-17
CLOCK TIME 1606
OPERATOR 9CHEFFEL
AMBIENT TEMP. (OEG.F) 48.
BAR. PRESS. (IN H6) 29.55
STATIC PRESS. (IN H20) -8.60
MOLECULAR HEIGHT 28.73
STACK INSIDE DIM(IN) 60.000
PITOT TUBE COEFF. .«4
MOISTURE CONTENT(S) 1.00
TRAVERSE POSITION \
POINT INCHES
NO.
01 .0 ]
9c .0
> 03 .0
1 04 .0
-J 05 .0
w 06 .0
01 .0
02 .0
03 .0
04 .0
OS .0
06 .0









VELOCITY
HEAD
IN H80)
1.100
.400
.600
.800
.900
.400
.800
.400
.500
.500
.000
.700









STACK
TEMP
(OEG.F)
63.
63.
63.
63.
63.
63.
63.
63.
63.
63.
63.
6J.
AVERAGE
        3.508
63.

-------
       PLANT                 ASARCO
       DATE                  01/19/65
       SAMPLING LOCATION     NO 4 SECONDARY EXHAUST
       RUN NUMBER              V-17

STACK AREA, SO. FT.                  19.635
STACK ABS. PRES., IN H6.             28.90
STACK CAS TEMPERATURE, DE6.F          63.
SORT(VEL HD X STACK TEMP ABS)        42.8

STACK GAS VELOCITY, ACT. FPS        106.6
STACK GAS VOLUME (MET), ACT. CFM.125623.6
STACK GAS VOLUME (DRV), ACT. CFM.124367.4
STACK GAS VOLUME » 29.92 IN. MS AND 68 DG. F :
             (DRY)               121286.4
             (MET)               122513.5

-------
                                                           SAMPLE  CALCULAIIUNS
            SYMBOLS!
                      AREA      CROSS-SECTIONAL STACK  AREA,  SO  FT
                      BPRES     BAROMETRIC PRESSURE,  IN  HG
                      OELP      DELTA P
                      D1A       DIAMETER OF CIRCULAR  STACK,  IN
                      DIM!      LENGTH Of RECTANGULAR  STACK,  IN
                      DIM2      WIDTH OF RECTANGULAR  S1ACK,  IN
                      MOIST     MOISTURE CONTENT
                      MM        MOLECULAR NEIGHT
                      NP        NUMBER OF TRAVERSE  POINTS
                      BW        MOLE FRACTION  HATER VAPOR
                                                                      PTC        PITOT  TUBE  COEFFICENT
                                                                      5PRES      STATIC  PRESSURE,  IN H20
                                                                      SlfcMP      STACK  TEMPERATURE,  OE6 F
                                                                      STPRES     STACK  PRESSURE,  IN  Mb
                                                                      STVEL      STACK  VELOCITY,  AFPM
                                                                      TEMP       TEMPERATURE,  DEB F
                                                                      VM         VELOCITY  HEAD,  IN H2o
                                                                      SVULFLW    STANDARD  VOLUMETRIC FLOW (NET), ACFM
                                                                      VULFLW     VOLUMETRIC  FLOW  IWET), ACFM
                                                                      SVULFLU    STANDARD  VOLUMETRIC FLOW (DRY), OSCFM
                                                                            42.8
-«J
Ul
FORMULAS AND SAMPLE CALCULATIONS:

                    SUM(SORT (VM • TEMPIJ          513.5
          DEL?  »  .......	..	.  s  	.-  c
                          NP                        12

          STPRES  *  BPRES » (SPRES/13.6)  s  24.55 * ( -8.80/13.6)   =     28.9  IN  HG

                     SUMOTEMPI           756.
                    ....	....  s  ....	...  e    fcj. DEC F
                       NP                 12

                                   3.1416 • (DIA/2)**2        3.1416  •  (  60.000/2)**2
                                     ....................  c  ..._........_.._.__.__..
                                           144                        144
                      STEKP  *
AREA(CIRCULAR STACK)  >
19.635 SO FT
                     65.49 • PTC • OELP       65.49 *   .64 •   42.8
          STVEL  •  ................—.-  3  .......................   s   106.6  AFPM
                     SQRUMW • STPRES)        SOHTJ  2».T3 •  28.9 )

          VOLFLW  >  60. * STVEL • AREA  s  60. •  106.6  •  19.635  s   125623.6  ACFM

          9VOLFLW  «  VOLFLW • STPRES •  ( 460. » 66. )       125623.6  •  28.9  •  (  460.  *  68.  )

                          29.92 * ( STtMP * 460. )               29.92 * (    63.0 *  460.  )

          SVOLFLD * SVOLFLW • (1 - BM) s  122513.5 • (1  -     .01) s    121288.4  OSCFM
                                                                                                                 122513.5 ACFM

-------
                                                           I tLH   I'A I A
ML AM
SAMPLING  LUCAlKm

SAKPLK  !»»>£
UHEHATOK
AMBIEH1  TEMP.tOEb.M
HAK. PRESS. UN. HGJ
STATIC  PNESS. ( IN.H2U)
MLTtfc  NUMUEK(S)
STACK INSIDE  UIM.(IN)
PlTUl fUUE COtFF.
IHtMM.  NO.
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 bb.
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NIIZZLK        :  l.U.
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POINT
NO.
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A-OI
A-02
A-03
A-04
A-05
A-06
b-01
B-02
0-03
B-04
B-05
B-Ob
B-05
B-04
B-03
B-Od
b-ot
TOTALS
AVERAGE
SAMPLE
11 ME
0
4U.O
BO.O
120.0
IbO.O
200.0
236.0
200.0
32O.O
3bu.u
40U.O
4411.0
500.0
530.0
bbO.O
59u.o
620.0
650. 0
bbO.O

CLUCK
T I ME
CLUCK)
806
H46
1048
1 1 30
1211
1313
1350
IbOa
745
»c?5
905
945
1133
1203
1233
1 303
1333
1403


GAS ME) EH
READING
ICU.K 1 . )
466. b5b
4H7.300
blO.OOO
b3«4.9UU
bb' .400
b97 .000
bl 7.7bb
640.000
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b9u.OOO
/ 1 ' .000
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7«b.OOO
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8b/./2H
391.073

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HEAD Olf-FtH
llU.He'U) UN.H


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.MOO .00
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,bOU .37
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.bOO .37
.000 cf.Urt
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.bou .37
.000 .99
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.4bO .«!
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.000 l.bb
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1 .20
PHESSUHt STACK
ENTIAL IH.MP
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.97 bB.
.If b9.
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2.43 70.
.57 HU.
,S1 «0.
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2. OB bO.
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1.20 bO.
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55.
78.
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80.
84.
84.
86.
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70.
70.
5b.
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b7 .
'2.
70.
74.
74.
7b.
77.
70.

71.
PUMP
VACUUM
(1N.HG)

2.0
2.0
47.0
4.0
2.0
2.0
2.0
5.0
4.0
6.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0

5.3
SAMPLE
BOX TEMP
(Otb.t- )

260.
2/0.
2/u.
2/0.
270.
270.
250.
260.
260.
260.
270.
2/0.
270.
2/0.
2/0.
2/0.
?70.

266.
IMPlNbEK
TEMP
(UEb.h )

47.
60.
60.
60.
60.
60.
60.
60.
60.
60.
50.
50.
60.
60.
60.
60.
60.

58.

-------
                 PAKMLOLAH  FIELD

     PLANT- NAME AND AOOHEbS

     ASAHCU IACUMA, HASH
                                             S  lAHuLAIllilv

                                        TtSI  IKAM LkAOFh
TEST PATC-I
                      NO4  StCONDAHY txHAUbt
>
TEST OAIE

TB
TF

IT

NP

Y

ON
PM


VM


TM

VMStO


VLC


VMC


BHO

FMD

PC 02

P02

PCO
                TIME-START
                HMk-F 1NISH

                NET I1ME. OF  1EST, MIN.

                NET SAMPLING  POINTS

                METER CALIHHATION FACTUH

                SAMPLING NOl/LE  DIAKEIEH

                PITOI TOBE COEFFICIENI
MO

MNS
           AVENAGt (JrUI-iCE
           DROP
                VOLUME OF OHY  GAS SAMPLED
                Al ME1EH CU^UITIONS

                AVERAGE GAS  METER TEMP

                VOLOMt UF OKY  GAS SAMPLLU
                Al SIANUAHD  CONDITIONS*

                10IAL H20 COLLECTED IN
                IMP1NGEHS AHI)  SILICA GEL,ML,

                VOLOMt UF «V«TEH  VAPOH
                Al blANOAHO  CONDI I IONS*

                PERCENT MOISTORE  HY VOLOMt

                MOLE FRACTION  DRY GAS

                PtKttNT COa  BY VOL., OHY

                PERCENT 02 MY  VOL., OHY

                PEHCtuT CO UY  V«)L., OHY

                PERCENT Ni hY  VOL., 0«r

                MOLECULAR wl-DRY  STALK bAb

                MIILkLULAH K.1-STACN.  GAS
                                            ENGLISH UNITS

                                               III / I M/(l }

                                             HUt>
                                              I/

                                               1.037

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                                                .an
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                                                .lM SLF
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-------
   PB         BAKUMtlKlC


   P3I        SIAIIL HWtS UK  STACK UAb


   PS         S1AC* PKES, AHS.


   TS         AVEHAbt SlALH  TtMP


   VS         AVG blACK GAS  VELOCITY


   AS         STACK AHEA


   OSSTO      STACK t-LUi* NAIE.  UMY*


   09         ACTUAL STACK FLOW HATt


   ISO        PEHCENT I9UK1NETIC


   MN         FlLltWAULt PAHT
                Mb. tHA 5


   CS         F1LTEKAHLE PAHT


   PMR        FILTEKABLk PAHT
                EMISSION HATE
 I
^J
00
UEG F,
                            IN.HG.
                                       .^ii   1 IK-HI;
                                    bM.     t
IU3.0
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                                                          lSc?.UU


                                                          M
-------
       EXAMHLt HANtlCULAII- C ALC'JL A 1 1OWS TKSI  NO.MA1U-I

            NU4 StCUrtDAHY EXHAUM




VOLUME  OF  l»NY GAS SAMPLED A1 STANOAKII Ll)i»l) II IONS

VMSTU  S U/.bO/ * VM  *  Y • (HH  +  PM / 13. M)  /  M>" » <4bll.)


           I7.fc«7 •    3-M.OM •  1.037  • I ."f.'jJ  » l.lVf,  /  13. b)
VMSTU =
                                                                         IVh.lM l)SC^
VOLUMt  OF  MAIEH

VKC *  .0  »  (20.9»3«.B
-------
STACK  bAS  VtLDLllr Af S1ACK  UINII 1 I llHMb

OELP =  SUM.  UF  THt SUHMVH  *  (IS »  «»>('. ))

VS = Sb.«9 *  C^ * I'LLP /

VS = Bb.1V •   .01 •  569. 5
                                                                   I/
      STACK  GAS VOLUMETRIC FLOW  AT  SULK CUNDIIIUNS

      US  = VS  * AS * 3bUU/|ao

      as  =    83. in •  ^t^^l .  36«o/iaa =    bH/
-------
                                                                ^ ItLU  HA I A
             PLANT
             SAMPLING LOCAIION

             SAMPLE TTPE
             AMblbM TEMP. (DEC. F)
             bAK.PhtSS. (IN.HG)
             STATIC PWESS.(1N.H2I»
                           ASAkCU
                           '«)4  SbCUNUflH*  IXHAUST

                           HANI /AhbbML
                                                UA1E
STACK  INSIUt  »l*.(IN)
PITOT  IOBE  CUEFF.
THERM. NO.
LEAKAGE
METEK  CALIB.  FACTOR
KEAU K KttUHO UATA EVEKT
 50.
30.00
-6.00
000250H
  bO.OO
  .04
                                                   .00
                                         .OBO  CFM rf  b.O  1N.MU
                                        1 .037
                                          .0 MlNUIbS
    NIJMHtK

PUUHt Lf.MGIH A rrPt
Nd/ZLH  2-111:  1.0.
A.SbllMKI)  MDiSTllKb
s»AMPLK  HUX  NUMHEK
MtltK «0«  NUMHbH
Mt TfcK HEAD  OlFh .

PHUHt MEATtK StTllNG
MtATEM  HUX  SEMlNb
01/20/83
H«lL-2

6 ^\ bLASb
 .150
 1.0

FH4
1.87

250.
250.

    .6
00
TRAVERSE SAMPLE
POINf I1ME
NO. IMIN.)
CLOCK
TIME
(24-HR
1 I tit* ¥ \
GAS MEItH VbLOClTl OK1FICE PKE5SUHE SlACK
HEADING HbAU UlFFbKbNUAL IbMP
(CU.KI.) (IN.HcMI) IIIV.H2U) IOEG.F)
UbSIWbll
INIT 0
ft-'Jl !0.0
20.0
30.0
40.0
50.0
60.0
A-02 70.0
80.0
9o.O
100.0
110. 0
120.0
A-03 130.0
140.0
150.0
160.0
170.0
180.0
A-04 190.0
200.0
210.0
220.0
230.0
240.0
A-05 250.0
260.0
270.0
280.0
290.0
300.0
820
R30
850
900
910
940
950
1000
1010
1020
1030
1040
1050
1100
1110
1 120
1356
1406
1416
1426
1436
1446
14S6
1506
1516
1526
1536
1546
1556
1606
059.021
066.000 3.500
073.100 3.500
080.000 3.500
084.550
088.990
095.900
900.500
906.000
91 1.000
915.700
920.900
925.600
931.650
930.700
943.630
949.400
954.330
959.300
964.350
969.600
.200
.200
(.500
.200
.300
.300
.300
.300
.400
.400
(.700
.400
.400
.40U
.400
.500
.500
976.000 4.000
983.050 4.000
99e!.000 4.300
99/.000 1.400
2.545 1.400
7.500 1.400
12.450 1.4OO
20.100 4.iOO
20.700 4.600
34.UOO 1.500
1.04
1.05
1 .Ob
.65
.65
1.90
.66
.71
. /4
.73
.73
.73
.00
2.10
.79
.00
.00
.78
.04
.04
2.20
2.20
2.4H
.11
.79
.79
.7-1
c:.5H
2.54
.Ob
ACTUAL
1 .84
1 .85
1 .8b
.65
.65
I .90
.66
.71
.'4
.73
.73
.73
.80
2.10
.79
.80
.80
. 7«»
.84
.84
2.20
2.20
2.40
.77
.79
.74
.79
2.50
2.54
.C6
OKT GAS Mb TEW POMP SAMPLE
IbMP VACUUM BUX TbMP
(Ubb.K) (IN.HU) (UFG.r)
IMPINGEK
TEMP
(UEG.F)
INLtl UlirLtT
80.
02.
02.
75.
/4.
70.
75.
To.
60.
63.
62.
61.
59.
66.
66.
59.
60.
64.
61.
62.
70.
75.
74.
75.
60.
64.
65.
00.
Ml .
b5.
56.
63.
66.
71.
72.
76.
74.
74.
77.
7d.
80.
80.
80.
82.
62.
82.
62.
72.
72.
74.
70.
80.
62.
84.
83.
63.
84.
84.
86.
66.
55.
50.
60.
62.
64.
65.
60.
60.
70.
70.
70.
70.
71.
72.
72.
M.
74.
66.
60.
68.
70.
7o.
70.
72.
74.
M.
76.
76.
76.
11.
4.5
5.0
5.0
5.0
5.0
5.0
5.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
250.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
260.
250.
250.
250.
250.
25".
60.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
60.
58.
60.
60.
60.
60.

-------
PLANI
SAMPLING LOCATION

KtAU ft MtCUKU DATA  EVtKY
   ASANCU
   NU4 btCUMUAKY  bXHAUbt


     .0 MlNUlbb
         UAIt
         KUN NliMHtH
                                                                                                                01/dO/»J3
                                                                                                                PAlL-d
00
NJ
TRAVbKSt
PUINI
NO.
A-Ob





B-01



b-02



B-03


SAMPLE
lilt
310.0
320.0
330.0
340.0
350.0
3bO.O
370. V
380.0
390.0
000.0
010.0
420.0
030.0
000.0
050.0
060.0
470.0
CLOCK
T IMk
(20-MH
CLOCK)
Iblb
Ib2b
Ib3b
lb«b
Ib56
1 70b
1736
170b
1/56
IQOb
1816
1826
1836
1933
1903
1953
2003
GAS Ml IbH VtLUCllT
KIAUINU HtAU
MklMCt PKESSUWb olACK
oiFf-bwewi i AL IKMP
UN.Ht'U) lUtG.KJ
DtSlHtU
00. 700
O5.950
51 .250
5b.ooo
62.000
7U.670
75.000
79.400
M3.80U
91 .000
97.000
IO2.4UO
10/ . 100
1 1 1.800
116.200
121.350
125.45o
3.500
1 .bOO
1 .bOO
1 .600
4.HUO
4.000
1 . 100
1 .100
1.100
3.300
3.300
1.300
I .300
1.300
1 .300
1 .300
1 .300
1.90
.9^
.92
.9tf
ef./d
«!./0
.62
.02
.62
1 .00
10.18
.M
. 70
./3
.73
. /3
. / 3
ALIOAL
1.98
.92
.92
.92
2.70
2. 70
.62
.62
.62
l.rtO
1 .HO
./3
./4
.73
./3
./3
.73
rtM>
lotr,,
Mfclb» PUMP 5AMPLt
' VACUUM HUX TLMP
.f- ) (1'J.Hl,) (Utti.t)
IMPlNbEW
ItMP
(Utb.M
INLtT UUTLLT
67.
64.
63.
62.
HO.
80.
74.
65.
60.
00.
/2.
73.
60.
60.
60.
62.
63.
8b.
87.
87.
86.
87.
87.
86.
82.
82.
84 .
83.
8b.
8b.
70.
70.
7tt.
80.
77.
70.
70.
70.
70.
70.
80.
70.
7 / .
70.
70.
70.
70.
74.
70.
70.
74.
2.0
2.0
2.0
2.0
2.0
2.0
1.0
1.0
1.0
0.0
1.0
3.0
2.0
2.0
2.0
2.0
2.0
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
25(«.
bO.
bO.
bO.
bO.
bO.
60.
bO.
60.
bO.
bO.
60.
bO.
bO.
bO.
bO.
bV.
60.
     TOTALS
     AVERAGE
    070.0
220.829
                                              1.38
                                1.20
b9.
80.
72.
2.0   255.
55.

-------
            PAMUCOLAIh KIH.I)  DAIA K KtSULlS  (AliOLAIlOlM
PLANT- NAME  ANU ADDRESS                ItSI  IKAM LEADER
A3AHCU                                  SSLMKMtL
TtST PATC-3
TEST UAIE
SECHMIANY  tXHAUbl
                      ENGLISH UNITS
                          ui,
                                                                     Ul
TB
TF
TT
MP
Y
ON
CP
PM
1
00
U) VM
TM
VMSTO
VLC
VhC
BMO
FMO
PC02
P02
PCO
PN8
MD
MNS
TIME-START tttJU
T1ME-HNISM <;uu3
NET TIMt OF TEST, MIN. <• 1 0 . U
NEI SAMPLING POINTS U/
METER CALIBRATION FACTOR 1.1M7
SAMPLING NOHLE OIAMEIER ,lbt> IN
P1TOT TOBE COEFFICIENT .»q
AVERAGE ORIFICE PRESSURE 1»«>0 IN-H2U
DROP
VOLUMt OF DRY GAS SAMPLED 2«?tt.»e!V CU-t-T
AT MEIER CONDITIONS
AVERAGE GAS METER TEMP 7S.9 F
VOLOME OF DRY GAS SAMPLED tM5.1U3 SCF
AT STANDARD CONDITIONS*
TOTAL Hi\> COLLECTED IN 38. 8
IMP1NGERS AND SILICA GEL, ML.
VOLUMt OF WATER VAPOR 1 .Belb SCF
AT STANDARD CONDITIONS*
PERCENT MOISTURE HY VOLUME .77
MOLE FRACTION DRY GAS .99?
PERCENT CU^ BY VOL., DRY .UU
PERCENT 0«J HY VOL., DRY iJO.Iu
PERCENT CO UY VOL., DKY .UU
PERCENT HZ bY VOL., DHY 7V. IU
MOLECULAR i*i-r>n» SIACK GAS C'H.HU
MULECULAH WT-STACK GAS c^tt./i
^S"
<< 7U.U
a ?
1 . U 3 7
3.tt MM
.««
30.0 MM-HcJO
b.18U CU-M

-------
   PB         HARUM:CK1C  PfcKSSMhK

   PSI        SIAIIC PRES  OF  STACK GAS

   P3         STAC* PWES,  AifS.

   TS         AVEKAbE S1ALK  UMP

   VS         AVG STACK GAS  VELUtlTr

   AS         STACK AHEA

   (1SSTU      STACK FLUM  KA(F.,  UWT«

   US         ACTUAL STACK FLOH HATt

   ISO        PERCENT 1SOKINETIC

   MN         FILTEMAHLE  PAHT
                M(i. EPA 5

   CS         FILTEHABLE  PAMT

   PMH        FlLUKAbLE PAHT
                EMIbSlUN HATE

      «  66  OEG F,  <;9.92 IN.HG.
00
                              MM-Mb
-b.Ou   |h





HU.b    FPS

      S'J-IN

        SLT- M

        ALFM
                             MM-HI,

                             C
                              SCMH

                  lb!3US.     ACMM
                              M(,/UbCM
lb.0b«> LH/hH

-------
            EXAMPLt  HAH t iLMLATh C ALLUI. A t 1 UN:}  ItSl  i
 I               100. •    I. 83
°?     BMU = — — - --- --— — ------- - --- =    .77
                    3. 103  »    1.83
      MOLE FRACTION OF  OHT  STACK GAS


      FMU = 1100. - BMOJ  /  100.


                100.  -     .8
      FMl) s — .... . — — -- ---- - --- -
                      100.
      AVERAGE MOLECULAN  HEIGHT OF \)H1 STACK  GAb


      MO = (PC02 •  ,aa)  *  (P02 * .3?) »  (PN2 » PCO)  * .28


      MO = (  .00«ia/100)  » (20.9*32/100) +  l(7S.l»  .0) * 2H/100  =    <>8.8  (Bftfl/100)) + 18.  * (HWIJ/lOO)


      MHS =  28.81*  (1.  -(  .77/100)) »  IB.  •  I   ./7/IOO) =    «J«.7b

-------
      STACK  bAS  VtLULllT Al STACK tUMUl T10US

      OELP = SUM.  Uf  IHE S'JWUVH *  (IS  »  IbU.M

      VS = 85. 19 •  CP • UtLP / (SU«T(Mv»S  •  Pb)  • HUTS)

      VS = H5.a9 »   .«« * 1537.0/1  /
                                                                                FH.S
      STACK KAS  VOLUHE1H1C FUO»» AT SIACK  CiUNUITIUNS

      US s VS  *  AS  *  5hOO/lau

      OS =   80.59  *   €?«d7. 3bUU/|ua =
STACK GAS VOLUMETRIC  FLUM AT SIANUAMu  CONDITIONS

OSSTU s 17.647  «  OS  • PS • (I. -  Ittwu/ 1 On) )  / (TS »

          I7.b«7  •     569b538. *  i>9.5b  •  II. - I
           - --- — — — . — .. — .-. ----- .......
                    (   b9. * <4bO.)
      USSIU =
                                                                                 . SCFH
00
PERCENT ISOKlNttlC

ISO s (3«5.5««(TS»«bO.)


130 =
                                           a70.  *
    . 03 M

«»9.Sb •
                                                                           )/(TT«VS«Pb*DN«UNI

                                                                                1 ,2l)5/ 1 3.b) ) / t   7b.»abO.)J)
                                                                              - ---------------------------
                                                                         *  .150
                                                                                                                   s  8b.i; PtHCENT
      PAHTICULATE  LUAU1NG — EPA MtTHUU  b  (Al  STANuAHu CUNUHIUNS)

      CS = 0.001 *  Ml*  * 15.03 / VMSTU

      CS = 0.001 •     307.5 • 15. W/DSC>-
PAHTICULATE LHS/MR  -- EPA MEIHUI) 5

PMH = CS * OSSTU  /  (15.43 * a53.b)

PMH =       .0202 •    5572920. /  (15. 03  *  053
                                                                Ib.0b9

-------
                                                            FIELD  DATA
 I
00
            PLANT
            SAMPLING LOCATION

            SAMPLE TYPE
            OPERATOR
            AMBIENT TEMP.(DEG.F)
            BAR.PRESS.(IN.HG)
            STATIC PRESS.(IN.M20)
            FILTER NUMBER(S)
            STACK INSIDE DIM.(IN)
            PITOT TUBE COEFF.
            THERM. NO.
            LEAKAGE
            METER CALIB. FACTOR
ASARCO
NU 4 SECONDARY EXXHAU3T

PART/ARSENIC
3CHEFFEL
 SO.
29.70
-6.00
3530461
  60.00    .00
  .84

 .002 CFM 3 12.0 IN.HG
1.037
DATE
RUN NUMBER

PROBE LENGTH ft TYPE
NOZZLE      I 1.0.
ASSUMED MOISTURE
SAMPLE BOX NUMBER
METER BOX NUMBER
METEH HEAO DIFF.

PROBE HEATER SETTING
MEATER BOX SETTING
01/22/83
PATt-3

6 FT GLASS
 .150
 1.0

F84
1.87

250.
250.
            READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.
MIT
•01
•02
•03
-04
•05
•06
•0*
-05
-04
•03
-02
-01
-01
-02
-03
-04
-05
B-06
8-06
B-OS
B-04
B-03
B-02
B-01
01
02
03
04
05
06
SAMPLE
TIME
(MIN.)
0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
130.0
140.0
150.0
160.0
170.0
180.0
190.0
200.0
210.0
220.0
230.0
240.0
250.0
260.0
270.0
280.0
290.0
300.0
CLOCK
TIME
(24-HR
CLOCK)
910
920
930
940
950
1000
1010
1054
1104
1114
1124
1134
1149
1159
1209
1613
1623
1633
1712
1722
1732
1742
1752
1802
1812
1822
1910
1920
1934
1944
2025
GAS METER
READING
(CU.FT.)
126.251
133.200
137.800
142.300
147.500
154.400
160.400
169.000
176.300
181.600
186.600
191.300
196.650
202.900
208.200
213.700
218.650
225.600
230.850
236.700
244.000
249.500
254.550
259.300
264.000
268.500
273.500
279.340
286.400
291.300
296.100
VELOCITY
HEAD
(IN.H20)

3.599
1.300
1.300
1.600
3.100
2.260
4.800
3.520
1.700
1.400
1.300
1.740
2.400
1.740
1.740
1.500
2.960
1.700
2.170
3.500
1.900
1.500
1.300
1.200
1.200
1.740
2.180
3.000
1.300
1.500
ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED

1.8?
.70
.71
.88
1.72
1.25
2.64
1.94
.95
.79
.73
.98
1.34
.98
.98
.87
1.65
.90
1.21
1.90
1.05
.83
.73
.68
.68
.98
1.23
1.70
.73
.84
ACTUAL

1.87
.70
.71
.88
1.72
1.25
2.64
1.94
.95
.79
.73
.98
1.34
.98
.98
.87
1.65
.90
1.21
1.90
1.05
.85
.73
.68
.68
.98
1.23
1.70
.73
.84
STACK
TEMP
(DEG.F)

67-
64.
62.
61.
61.
65.
70.
65.
61.
60.
59.
60.
66.
68.
64.
62.
62.
80.
64.
80.
70.
68.
64.
62.
62.
63.
62.
60.
64.
60.
DRV GAS METER PUMP
TEMP VACUUM
(DEG.F) (IN.HG)
INLET

92.
56.
58.
64.
68.
72.
74.
68.
70.
74.
76.
77.
76.
78.
68.
68.
70.
74.
70.
72.
76.
77.
78.
79.
79.
80.
73.
74.
72.
72.
OUTLET

50. 3.0
52. .0
54. .0
56. .0
58. .0
60. .0
63. .0
64. .0
65. .0
66. .0
66. .0
68. .0
69. .0
70. .0
64. .0
64. .0
65. .0
66. .0
66. .0
66. .0
67. .0
68. .0
70. .0
70. .0
70. .0
72. .0
70. .0
70. .0
70. .0
68. .0
SAMPLE
BOX TEMP
(DEG.F)
,
250.
270.
270.
270.
270.
270.
270.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
2SO.
250.
250.
250.
250.
250.
250.
250.
IMPINGE*
TEMP
(OEG.F)

60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.

-------
PLANT
SAMPLING LOCATION
ASARCO
NO 0 SECONDARY EXXHAUST
DATE
RUN NUMBER
01/32/83
PATC-3
READ t RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.
06
05
04
03
02
01
01
02
03
04
05
06
06
05
04
1 "
00
oo TOTALS
AVERAGE
SAMPLE
TIME
(MIN.)
310.0
320.0
330.0
340.0
350.0
360.0
370.0
380.0
390.0
400.0
410.0
420.0
430.0
440.0
450.0
453.0

453.0

CLOCK
TIME
(24-HR
CLOCK)
2035
2045
2055
2105
2115
2125
2135
2145
2155
2205
2215
2225
2320
2330
2340
2343



GAS METER VELOCITY
READING HEAD
(CU.FT.) (IN.M20)
301.400 .500
306.250 .500
311.150 .400
316.000 .300
320.600 .300
325.400 .200
329.720 .200
334.500 .300
339.300 .200
344.000 .300
349.000 .400
357.000 4.000
364.700 4.000
372.700 4.000
380.700 4.000
383.000 3.600

256.749

ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED
.84
.84
.79
.73
.73
.68
.68
.73
.68
.74
.79
2.20
2.30
2.28
2.28
2.07


1.17
ACTUAL
.84
.84
.79
.73
.73
.68
.68
.73
.68
.74
.79
2.20
2.30
2.28
2.28
2.07


1.17
STACK
TEMP
(OEG.F)
DRY GAS
TEMP
(OEG.
METER PUMP
VACUUM
F) (IN.HG)
SAMPLE
BOX TEMP
(OEG.F)
IMPINGER
TEMP
(OEG.F)
INLET OUTLET
60.
60.
65.
63.
6*.
61.
61.
64.
63.
61.
61.
80.
55.
55.
55.
53.


63.
72.
76.
77.
78.
78.
79.
79.
80.
80.
80.
80.
80.
72.
75.
75.
76.


74.
68.
70.
70.
70.
70.
70.
70.
72.
72.
72.
72.
7*.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
70. 4.0
70. 4.0
70. 4.0
70. 4.0


67. 1.6
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
250.
255.


253.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.
60.


60.

-------
           PARTICULATE FIELD DATA & RESULTS TABULATION

PLANT* NAME AND ADDRESS               TEST TEAM LEADER

A8ARCO                                SCHEFFEL
TEST PATC-J
NO « SECONDARY EXXHAUST
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
> PM
1
00
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
01/22/83
910
2343
453
46
1


!
.0

.037
.150 IN
.84
.!? IN-H20
METRIC UNITS
01
910
2343
453.
46
1.
3.
•
29,
/22/83
0

037
a
84
7



MM

MM-I
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTO     VOLUME Of DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL HZO COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

POZ       PERCENT OZ BY VOL., DRY

PCO       PERCENT CO BY VOL., DRV

PNZ       PERCENT NZ BY VOL., DRY

MD        MOLECULAR NT-DRY STACK GAS

MHS       MOLECULAR NT-STACK GAS
                          256.749 CU-FT


                           70.2   F

                          263.952 SCF


                           47.3


                            2.226 SCF
 7.270 CU-M


21.2   C

 7.474 SCM


47.3


  .063 SCM
.6*
.992
.00
20.90
.00
79.10
28.84
28.75
.84
.992
.00
20.90
.00
79.10
28.84
28.75

-------
    PB        BAROMETRIC PRESSURE

    PSI       STATIC PRCS OF STACK GAS

    PS        STACK PRE3, ABS.

    TS        AVERAGE STACK TEMP

    VS        AV6 STACK GAS VELOCITY

    AS        STACK AREA

    USSTD     STACK FLOW RATE. DRV*

    OS        ACTUAL STACK FLON RATE

    ISO       PERCENT ISOKINETIC

    MN        FILTERABLE PART
                MS. EPA 5

    CS        FILTERABLE PART

    PMR       FILTERABLE PART
                EMISSION RATE
                                        79.9

                                      2827.

                                   5524104.

                                   5646645.

                                       101.J

                                       153.6
29.70  IN-HG

-6.00  IN-M20

29.26  IN-HG

63.    F

       FPS

      30-1N

       SCFH

       ACFH
                                          .0090 GR/DSCF*

                                         7.087 LB/HR
   750.38  MM-HG

  -152.40  MM-H20

   743.17  MM-HG

    17.    C

    21.3   MPS

     1.824 SO-M

156426.    SCMH

159896.    ACMH

   101.3

   153.6


    20.552 MG/D3CM

     3.21 KG/HR
*  68 DEC F,
                           IN.HG.
VO
O

-------
      EXAMPLE PARTICIPATE CALCULATIONS  TEST NO.PATC-3

           NO 4 SECONDARY EXXHAUST



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTO * (17.647 * VM • Y * (PB * PM / 13.6)) /  (TM » 460.)

          17.647 •   256.749 • 1.037 •  ( 29.70  +  1.170  /  13.6)
VMSTO * —	—	  =     263.952 D3CF
                         (  70. » 060.)



VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

VMC » .04707 * VLC

VMC « .04707 *   47. *   2.23 SCF



PERCENT MOISTURE IN STACK GAS

•MO * (100. * VMC) / (VMSTO * VMC)

          100. *   2.23
BMO » ——	——	«	—- =   .84 PERCENT
           263.992 «•   2.23



MOLE FRACTION OF DRY STACK GAS

FMD a (100. - B*0) / 100.

          100. •    .8
FMD « ——————— *   .992
               100.



AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

MD * (PC02 • .44) » (P02 * .32) * (PN2  » PCO) * .28

MD * (  .00*44/100) » (20.9*32/100) « ((79.1* .0) • 2R/100 =   28.84



MOLECULAR WEIGHT OF STACK GAS

MMS • MD * (1. - (BWO/100)) * 18. • (BfcO/100)

MMS »  26.84* (1. •(  .84/100)) »!«.*(  .84/100) =   28.75

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP * SUM. OF THE SORT(VH * (TS » 460.))

      VS • 85.49 • CP • OELP / (SORT(MMS * PS) * PNTS)

      VS 8 85.49 *  .84 * 1484.000 / (SOHT( 28.75 • 29.2b)  *  Qfc. =   79.88 FP3



      STACK 6A8 VOLUMETRIC FLO* AT STACK CONDITIONS

      OS = VS * A3 • 3600/144

      OS »   79.68 •  3827. 3600/144 =    5646645. ACFH



      STACK 6AS VOLUMETRIC FLON AT STANDARD CONDITIONS

      OSSTO * 17.647 • OS • PS * (1. • (BMO/100)) / (TS » 460.)

                17.647 •    5646645. *  29.26 •(!.-(  .84/100))
      OSSTO *	•	=    5524104. SCFH
                         (  63. * 460.)



•f     PERCENT ISOKINETIC
vo
to     ISO s (305.58«(TS»460.))«((0.002669«VLC)*(VM«Y«(PB»(PM/13.6))/(TM*460.)))/(TToVS*PS<>DN«DN)

             (305.58«(  63.+460.))«((0.002669*   47.)*(  256.749*1.037*( 29.70«(   1.170/13.6))/(   70.«460.)))
      ISO « ———.——.	.	...	...	..	. s  101.26  PERCENT
                                         453. •     79.88 •   89.26 •  .150 •  .150



      PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS • 0.001 • MN • 15.43 / VMSTD

      CS ' 0.001 •    153.6 • 15.43 /   263.952 >       .0090 GB/OSCF



      PARTICULATE LBS/HR — EPA METHOD 5

      PMR * CS * OSSTD / (15.43 • 453.6)

      PMR «       .0090 •    5524104. / (15.43 • 453.6) *     7.087

-------
END  OF  PROGRAM
:EOJ
CPU  SEC.  *  10.  ELAPSED M]N. r |.  FBI, FEB  18,  1983,   1:55 PM
vi)

-------
                                                        FIELD  DATA
PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
AMBIENT TEMP. (DEC. F)
BAR. PRESS. (IN.HG)
STATIC PRESS. (IN. H20)
FILTER NUMBER m
STACK INSIDE DIM. (IN)
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
METER CALIB. FACTOR
ASARCO
N04 SECONDARY EXHAUST
PART/ARSENIC
SCHEFFEL
55.
29.55
-9.00
0002440
60.00 .00
.84

.002 CFM a 7.0 IN.HG
.986













DATE 01/18/63
RUN NUMBER PASM-I
PROBE LENGTH ft TYPE 6 FOOT GLASS
NOZZLE 2-22M I.D. .120
ASSUMED MOISTURE 1.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB5
METEH HEAD D1FF. 1.95
C FACTOR 1.05
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .00

READ 8 RECORD DATA EVERY .0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME TIME
NO. (MIN.) (24-HR

INIT 0 909
> IS. 6 925
' 77.5 1215
£ 95.0 1254
99.0 1300
105.0 1307
108.0 1310
109.0 1316
110.0 1330
111.0 1343
114.0 1349
140.0 1610
153.6 1625
173.5 830
174.8 833
177.2 840
181.7 845
209.4 945
212.0 1015
220.0 1036
221.0 1138
222.4 1134
230.0 1235
233.5 1322
READING HEAD DIFFERENTIAL
(CU.FT.) (IN.H20) (IN.H20)
DESIRED ACTUAL
668.131
676.729
712.353
722.000
724.900
727.000
728.530
729.143
729.693
730.353
731.954
743.500
750.330
761.560
762.200
764.700
766.035
781.930
783.510
788.230
788.763
789.460
793.537
794.290
.100
.300
.500
.000
.800
.500
.500
.500
.500
.500
.600
.500
.500
.500
.500
.500
.500
.500
.500
.500
.500
.00
.05
.06
.45
.44
.06
.08
.08
.06
.06
.65
.64
.06
.06
.08
.08
.06
.06
.06
.06
.06
.00
.05
.08
.45
.44
.06
.08
.08
.08
.08
.65
.64
.06
.08
.08
.06
.06
.06
.06
.08
.06
.000 .95 .95
.000 .95 .95
STACK
TEMP
(DE6.F)


65.
81.
82.
78.
76.
104.
85.
62.
89.
63.
62.
80.
74.
75.
75.
76.
73.
80.
65.
78.
78.
79.
80.
DRV GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM BOX TEMP TEMP
(OEG.F) (IN.HG) (DEG.F) (OE6.F)
INLET OUTLET

64. 60. 4.0 275. SO.
66. 66. 5.0 275. 60.
76. 74. 5.0 275. 62.
80. 74. 4.0 275. 62.
60. 74. 3.0 275. 62.
80. 74. 2.0 275. 62.
60. 74. 2.0 27S. 62.
80. 74. 2.0 275. 62.
80. 74. 2.0 275. 62.
76. 74. 2.0 275. 62.
72. 70. 4.0 275. 62.
82. 72. 5.0 275. 62.
56. 56. 5.0 270. 60.
65. 60. 5.0 2SO. 60.
66. 60. 5.0 250. 60.
68. 60. 5.0 250. 60.
68. 64. 5.0 260. 60.
74. 70. 5.0 260. 60.
74. 70. 5.0 260. 60.
72. 70. 5.0 260. 60.
72. 69. 5.0 270. 60.
72. 70. 5.0 270. 60.
74. 70. 5.0 270. 60.
TOTALS
AVERAGE
233.5
126.159
                                        1.02
                               1.02
60.
73.
69.
4.1   268.
60.

-------
           PARTICIPATE FIELD DATA S RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

ASARCO                                SCHEFFEL
TEST PASM-t
                N04 SECONDARY EXHAUST

TEST
TB
TF
TT
NP
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/16/83
909
1322
233.5
23
.988
.120 IN
.64
1.02 IN-H20
METRIC UNITS
01/16/63
909
1322
233.5
23
.986
3.0 MM
.84
26.0 MM-I
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H2t COLLECTED IN
          IMPIN6ERS AND SILICA GEL,ML.

VNC       VOLUME OF NATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRV GAS

PC02      PERCENT C02 BY VOL., DRV

P02       PERCENT 02 BY VOL., DRV

PCO       PERCENT CO BY VOL.. DRV

PN2       PERCENT N2 BY VOL.* DRV

MD        MOLECULAR NT-DRY STACK GAS

MNS       MOLECULAR NT-STACK GAS
                                          126.159 CU-FT
3.572 CU-M
71.0 F
122.709 SCF
18.6
.876 SCF
.71
.993
.00
20.90
.00
79.10
28.84
26.76
21.7
3.475
18.6
.025
.71
.993
.00
20.90
.00
79.10
28.84
26.76
C
SCM

SCM









-------
    PB         BAROMETRIC  PRESSURE

    P3I        STATIC  PRE3 Of  STACK  GAS

    PS         STACK PRE3,  ABS.

    TS         AVERAGE STACK TEMP

    VS         AV6 STACK CAS VELOCITY

    AS         STACK AREA

    OSSTO      STACK FLON  RATE, DRY*

    0S         ACTUAL  STACK FLON RATE

    ISO        PERCENT ISOKINETIC

    MN         FILTERABLE  PART
               MG. EPA 5

    CS         FILTERABLE  PART

    PMR        FILTERABLE  PART
               EMISSION  RATE
                                       119.0

                                      2827.

                                   7680645.

                                   8408552.

                                       100.0

                                       227.8
29.55  IN-MG

-9.00  IN-M20

28.89  IN-MG

80.    f

       FPS

      SO-IN

       SCFH

       ACFH
                                          .0286 GR/OSCF*

                                        32.253 LB/HR
   750.57  MM-H6

  -228.60  MM-H20

   733.76  MM-HG

    27.    C

    36.3   MPS

     1.824 SO-M

223156.    SCMH

238105.    ACMH

   100.0

   227.8


    65.565 MG/DSCM

    14.63 KG/HP
•  60 DEC f,
                           IN.H6.
VO

-------
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.PASM-1

           N04 SECONDARY EXHAUST



VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS

VMSTD » (17.647 • VM * Y • (P8 «• PM / 13.6))  /  (TM  *  060.)

          17.647 •   126.159 •  .989 * ( 29.55  »  1.053  /  13.6)
VMSTD « —-———	=     122.709 DSCF
                         (  71. » 460.)



VOLUME OP WATER VAPOR AT STANDARD CONDITIONS

VMC » .04707 • VLC

VMC • .04707 •   19. *    .88 SCF



PERCENT MOISTURE IN STACK GAS

BMO • (100. * VNC) / (VMSTD * VMC)

          190. •    .88
BWO « —————————— z   .71 PERCENT
           122.709 *    .88



MOLC FRACTION OF DRY STACK GAS

FMD * (100. - BNO) / 100.

          100. -    .7
FMD » ——————— s   .993
               100.



AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MD * (PC02 • .44) * (P02 • .32) * (PN2 «• PCO) • .28

MD a (  .00*44/100) » (20.9*32/100) * ((79.1* .0) * 28/100  r   28.84



MOLECULAR HEIGHT OF STACK GAS

MN8 • MD • (1. • (BNO/100)) » 18. • (BHO/100)

MNS •  28.84* (1. -(  .71/100)) » 18. • (  .71/100) 8   28.76

-------
       STACK  6*8 VELOCITY  AT  STACK  CONDITIONS

       DELP • SUM.  OF  THE  SQRT(VH * (TS  *  460.))

       VS « SS.49 • CP • OELP /  (SORT(MMS  •  PS)  •  PNTS)

       VS e 6S.49 •  .04 • 1098.175 /  (SORT( 28.76 •  28.89)   »   23.  =   118.96 FPS



       STACK  CAS VOLUMETRIC FLOM AT STACK  CONDITIONS

       US « VS • AS •  3600/144

       OS •  llB.9fc *   2827.  3600/144  a    8408552. ACFH



       STACK  GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

       OSSTO  • 17.647  • OS •  PS • (1.  •  (BNO/100))  /  (TS  + 460.)

                 17.647 •     8408552.  •  28.89  •(!.-(   .71/100))
       OSSTO  8 —	—.—.	.	s    7880645.  SCFM
                          (  80. »  460.)


>
vi,      PERCENT ISOKINETIC
oo
       ISO »  (305.S8»(TS*460.))M(0.002669«VLC)»(VM«YMPB*(PM/13.6))/(TM»460.)))/(TToV3oPS«DN«ON)

              (305.58M 80.*460.))«((0.002669*    19.)*(   126.159* ,988*(  29.55»(   1.023/13.6))/(  71.*460.)))
       ISO «  ————	———	....	.........—..........	..	......	.—..	.	....... e 100.03 PERCENT
                                          234.  *    118.96 •    28.89 *   .120  •  .120



       PARTICULATE  LOAOIN6 — EPA METHOD 5 (AT  STANDARD CONDITIONS)

       CS » 0.001  • MN * 15.43 / VMSTD

       CS « 0.001  •    227.8  * 15.43 /  122.709 =        .0286  6R/DSCF



       PARTICULATE  LBS/HR  —  EPA METHOD  5

       PMR «  CS  • OSSTD /  (15.43 •  453.6)

       PMR •        .0286 •    7880645. / (15.43  •  453.6)  *    32.253

-------
                                                                 I- 1LLU  OAIA
 I
vo
vo
PLANT ASAKtU
SAMPLING LOCATION Ml) 14 SECDNUAhY
SAMPLE IYPE PAHI /A*i,tNl X
UPbHATUH SCntH-tl
AMBlbNI TEMP.(OFG.F) -JO.
BAK.PHbSS.llN.Ht.) 30.00
STATIC PHESS. UN.H20) -9.uu
F1LTEH NOMBEM(S) 0002505
STACK INSlOb DIM. (IN) 60.00 .00
PHOT TUBE COEFF. ,b4
THbHM. NO.
LEAKAGE .000 OM „• 6.
MEIbH CALltt. FACTOR .968
HEAD A HbCORO DATA
TRAVbHSE
POINT
NO.

INIT






















SAMPLE
TIMb
(M1N.)

0
26.2
29.0
31.0
32.0
33.3
35.6
37.6
05.5
47. S
53.5
55.2
57.7
59.0
85.5
103.3
105.8
106.4
111.0
115.4
122.0
130.7
131.6
CLOCK
TIME
(24-MH
ft 1 If* W t
LL UL K I
820
848
655
945
950
953
1000
1004
1052
KJ57
1 105
1114
1121
1426
1500
1557
1610
1616
1 700
1 70H
1804
1815
1832
EVEHY .0
GAS ME TLK
REALMS,
UU.K 1 .)

795.600
810.110
610.515
81 1.450
81 1.940
612.500
813.757
614.740
616. 5H5
81 9. 7b3
822.600
023.440
024.655
825.375
839.332
840. 0h4
05o. 1 /5
050.440
652.063
855.200
650.900
06«f.672
663.075
MiiUlES
VtLOCll »
HbAO
( 1N.H20)


3.700
3.700
3.700
3. 700
3.700
3.700
3.700
3. 700
3.700
3.700
3.700
3.700
3.700
4.000
4.000
4.00V
4.000
4.000
4.000
3.300
3.300
3.300
tXMAIJSI
5 IN. Mb

iiKincE
IHH-E
I IN.
DESlMtU

.87
.07
.or
.07
.07
.07
.07
.07
.07
.07
.07
.07
.07
.95
.95
.95
.95
.95
.95
.78
.'In
. /rt
OAlh 01/20/83
PHUBb LENGM * TYHt 6 Fl GLASS
NIIZ/LE : 1.0. .120
ASoUMtU M01STOHE 1.0
SAMPLE HOX NU^BEH
WtlEH HOX NUMrftH FB5
ME1EK HEAD 1)1 Ft- . 1 .95
L FAUTOH 1.05
PHOHb MbATER SETTING 250.
HbATtH BOX SbT I ING 250.
KEfE'HENCb PHbSS. 01FF. .00

PHESSuWE
HENT1AL
M2U)
ACIUAL

.87
.87
.fl 1
.87
.87
.87
.87
.87
.87
.87
.87
.87
.87
.95
.95
.95
.9i
.95
.95
.70
.70
.70

SI ACK

UKY GAS

MtTE»
IE.M(J TbMP
tObU.F)


60.
70.
77.
60.
03.
65.
75.
63.
60.
60.
67.
72.
75.
00.
00.
7o.
70.
76.
73.
HO.
70.
70.
(ObG
I Nit!

5«.
7*.
70.
70.
70.
70.
70.
70.
70.
70.
72.
72.
70.
70.
76.
77.
77.
76.
76.
75.
75.
76.
.F)
OOlLbl

56.
64.
66.
66.
66.
66.
66.
66.
66.
66.
66.
67.
66.
67.
70.
72.
It.
72.
72.
72.
72.
72.

PUMP
VACUUM
(1N.HU)


6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0

SAMPLE
BOX TtMP
(UF.G.M


250,
250.
250.
250.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.
270.

IMPlNbEH
TtMP
(OEb.F)


50,
50.
50.
50.
50.
50.
50.
5V.
50.
5V.
5V.
50.
50.
5V.
5V.
5V.
50.
5V.
50.
5V.
50.
50.
     TOTALS

     AVEHAGE
131.6
                                            .00
                                                     .60
                                                             74.
                                                                     72.
                                                                              60.
6.0
                                                                                             266.
                  50.

-------
            HARUCULAIt  MILD DATA K WtSULIS I flUUL A 1 1 HIV




PLANT- NAME AND ADDRESS                 ItSI  ItAM




ASAHCU                                   SCHtFt-tL
TES1 PASM-2
TEST DATE
NU 4 StCUNDARY tXHAUSf
                           hNULISM UNITS




                              01,
MtTRIC  OMTb



   oi /<»o/a 5
Tb
TF
TT
MP
Y
ON
CP
> PM
1
0 VM
TM
VMSTO
VLC
VHC
BMO
FMO
PC 02
PU2
PCO
PN2
MD
MHS
IIME-SIART 82(1 «20
TIME-FINISH ld.Se Ie3<;
NET TIME OF TEST, MIN. 131. b 131. b
NET SAMPLING POINTS tt 22
MtTER CALIBRATION FACTOR .968 .980
SAMPLING NOZZLE DIAMETEK ,\d(j IN J.O MM
P1TUT TUBE COEFFICIENT ,8CM
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME .37 .37
MOLE FRACTION DRY GAS .9<*b .9
-------
 PB         HAHOMtrhIC PKK85UWE


 PSI        STAIIC HUES OK  STACK  GAS


 PS         SlACK HUES, ArtS.


 TS         AVEKAbE SlACK  TEMP


 VS         AVG STACK GAS  VELOCITY


 A3         SlACK AHEA


 USSTO      SlACK FLUn MAfK,  DkT*


 OS         ACIUAL STACK FLUH WATE


 ISO        PERCENT ISOKINETIC


 MN         FlLTENAbLE KAMI
             M(i. EHA b


 CS         F1LTEHAHLE PART


 PMH        FILFEHABLE PART
             EMISSION WAtE
    *   b6 DEb F,  29.93  IN.HU.
 !
M
O
     jii.du   IIV-HI;


     -4.00   IN-M«?U




     71.     F


    110.1    FPS


           SO-IN


             SUFM


778SIB3.     ACFM


    100. B
 UH/OSCI-*

LU/HW
              /bi.OO  MM-Mi,
              /Ob.
              too. a
                          103. ao9  Mb/USCM


                           ^«J.OJ Kb/UK

-------
             bXAMHLt PAHTltiM.ATE  C ALC UL A 1 1 IJI«S  ttSl l\Jll.»'A.SM-ef

                  NU 4 SELONOAHY  EXHAUSI



      VOLUME  OF  UHY bAS SAMPLE!)  AT SUNOANU LUNDIIIMI.S

      VMSri)  = (17.647 • VM  *  Y  • (PB * KM  /  13.6)) /  I I r-  *  «bO.)

                 17.647 •    67.275 •  .9HH  *  (  30.00  »   .800  / 13. h)
      VMSIO  = -------------------- — ..---- ---------------- ....... =      bh.^bb USC^
                                 C  ft). »  any.)
      VOLUME  OF  WAItN VAPUW  AT  STANOARU

      VMC 3  .047U7 * VLC

      VWC =  ,0a707 *    5. =     .3* SCF


      PEKCENI  M01S1UHE IN STACK  GAS

      BHO =  1100.  • VttC) / (VM3TO * VWt)
>
 I                100. •    ,2fl
             -------------------------- =    .it
to                 6b.5b5 *     .?a
      MOLE  FRACTION UF OUT  STACK GAS

      FMU = (100. - BHO) /  100.

                 100. -     .0
      FMU  =  - --- -
                      100.
      AVERAGE  MOLECULAH ME1GHT  OF URT STACK

      MO =  (PCOe • .
-------
      STACK bAS VtLlllIlY  At  STACK t()NI) 1


      UELP = SUM. UF  I ML  SUWT(VH * (IS * 460.))


      V3 = B5.49 * CP  « UELP / (SUKTIMrtS •  Pb)  •  Pulb)


      VS = 85.49 •   .84 •   9H0.732 /  (SliHll  ^rt.BU • e^.Ju)   *   2e!.  =   110. 1<4 M'S





      STACK bAS VOLUMETRIC  FLO* AT STALK CONUIMUNb


      US = VS « AS •  3bOU/lU.J ) ) / I T I • VS«PS*ON*I)N)
                                                                            30.00»(     .8«0/ 13.6 ) ) / (   70. +460.)))
      iso s ------------------------------------------------------------------------------------------------- = ioo.ee  PERCENT
                                           13?.  *     110.14 •    29.34  •




      PAHTICULATk LOADING -- EPA METHUU b  (A I  STAUUAKU CUNUIUUMS)


      CS = 0.001  *  MM  •  15.43 / VHSTU


      CS = 0.001  *     194.9 • lb.43 /    66.b6b  =       .04bd  U«/USC»-




      PAHT1COLATE LHS/MR  -- EPA METHOD 5


      PMK = CS • USSTO /  (15.43 • 453.6)


      PMH =       .U452  •    7525401. / (lb.«3

-------
                                                              FIELD  0»T»
PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
AMBIENT TEMP. (DEC. F)
BAR. PRESS. (IN.HG)
STATIC PRESS. (IN. H20)
FILTER NUMRER(S)
STACK INSIDE DIM. (IN)
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
METER CALIB. FACTOR
READ ft RECORD DATA EVERY
TRAVERSE SAMPLE CLOCK GAS
ASARCO
N0
-------
             PARTICIPATE FIELD DATA « RESULTS TABULATION
  PLANT- NAME AND ADDRESS               TEST TEAM LEADER
  ASARCO                                SCHEFFEL
  TEST PASM-3
                NO* SECONDARY EXHAUST
ENGLISH UNITS , METRIC UNITS
TEST
Ttf
TF
TT
NP
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, HIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
01/22/83 01
955 955
1930 1930
00.0 00.
6 6
.968
.120 IN 3.
.8a
.56 IN-H20 ia.
/22/«3
a

986
0 MM
ea
7 MM-
U1
          DROP

          VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VM3TD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY CAS

PC02      PERCENT COZ BY VOL.. DRY

P02       PERCENT 02 BY VOL.. DRV

PCO       PERCENT CO BY VOL.. DRV

PN2       PERCENT N2 BV VOL.. DRV

MD        MOLECULAR MT-ORY STACK GAS

MMS       MOLECULAR NT-STACK GAS
                                             22.750 CU-FT
.baa CII-M
63.5 F
22.536 SCF
5.6
.260 SCF
l.lb
.986
.00
20.90
.00
79.10
26.80
28.71
17.5
.636
5.6
.007
l.lb
.988
.00
20.90
.00
79.10
26.80
28.71
C
SCM

SCM









-------
     PB        BAROMETRIC PRESSURE


     PSI       STATIC PRES Of STACK GAS


     PS        STACK PRES, ABS.


     TS        AVERAGE STACK TEMP


     VS        AVG STACK GAS VELOCITY


     AS        STACK AREA


     QSSTD     STACK FLO* RATE, DRV*


     OS        ACTUAL STACK FLOM RATE


     ISO       PERCENT ISOKINETIC


     MN        FILTERABLE PART
                 MG. EPA 5


     CS        FILTERABLE PART


     PMR       FILTERABLE PART
                 EMISSION RATE


        *  68 DEG F,  29.9Z IN.HG.
    121.7


   2827.


B19037B.


6600480.


    102.2


     62.4
29.70  IN-HR


-9.00  IN-H20


29.04  IN-HG


72.    F


       FPS


      3D-IN


       SCFM


       »CFH
       .0427 GH/DSCF*


     49.997 LB/HR
   754.3S  MM-MG


  -228.60  MM-H20


   737.57  MM-HG


    22.    C


    37.1   MRS


     1.824 SU-M


231927.    SCMH


243540.    ACMH


   102.2


    62.4




    97.793 MG/OSCM


    22.68 KG/HP
 I
M
O

-------
            EXAMPLE PARTICIPATE CALCULATIONS  TfcST  NO.PASM-3

                 NO3 SECONDARY EXHAUST




      VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

      VMSTD • (17.647 • VM • V •  (PB » PM  / 13.6))  /  (TM  » 460.)

                17.647 •    22.750 *  .988 *  (  ?9.70  »   .SAO  /  13.6)
      VMStO s ....................... —..........	.	=     22.53h DSCF
                               (  64. »  460.)




      VOLUME OF WATER VAPOR AT STANDARD  CONDITIONS

      VNC * .04707 • VLC

      VWC s .04707 •    6. »    .26 SCF




      PERCENT MOISTURE IN STACK GAS

      BWO a (100. « VHC) / (VMSTO » VWC)

>               100. •    .26
jL     BWO s	..........	......	=   |. 16  PERCENT
O                 22.536 *    .26
-J



      MOLE FRACTION OF DRY STACK GAS

      FMO s (100. • BNO) / 100.

                100. •   1.2
      FMD * - — - ———-—— — — s    .988
                     100.




      AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

      MD a (PC02 • .44) » (P02 •  .32) *  (PN2  +  PCU)  • .28

      MO s (  .00*44/100) » (20.9*32/100)  * ((79.1*  .0)  * 28/100  =   28.84




      MOLECULAR WEIGHT OF STACK GAS

      MWS s MD • (1. • (8WO/100)) » 18.  *  (BMO/IOO)

      MWS s  28.84* (1. •( 1.16/100)) »  tfl. *  ( 1.16/100) s    28.71

-------
         STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

         DELP = SUM.  OF  THE  SORT(VH • (TS  *  flfeO.))

         VS  = 85.49 •  CP  • DELP  /  (SORT(MWS  •  PS)  •  PNTS)

         VS  = »5.49 •  .84 •  391.375 /  (SORT( 28.71  *  29.01)   *    8.  =   121.67  FPS



         STACK  GAS VOLUMETRIC FLON AT STACK  CONDITIONS

         OS  = VS  * AS  • 3600/144

         OS  =   121.67  •   2827.  3600/144  =    8600080. ACFH



         STACK  GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

         nSSTD  *  17.647 • OS •  PS • (1.  -  (BMO/100))  /  (TS  *  460.)

                  17.647 •     0600480.  *  29.04  •(!.-(  1.16/100))
         OSSTO  =  -.— ——..—-. — .-.. — -	. —... —-.---— ..	s    819037P.  SCKH
                            (   72. »  460.)



>        PERCENT  ISOKINETIC
 I
Q        ISO s  (305.50*(TS*460.))«((0.002669*VLC)«(VM*Y*(PB*(PM/13.6))/(TM»460.)))/(TT*VS*PS*DN*DN)
00
                (305.5BM  72.«460.))«((0.002669*     6.)*(    22.750* ,988*(  29.70M     .580/13.6))/(  64.4460.)))
         ISO «	—	——	....	.	s 102.16 PERCENT
                                            40.  •    121.67  •    29.04 *   .120  •   .12U



         PARTICULATE  LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

         CS  s 0.001 *  MN  • 15.43 / VMSTD

         CS  s 0.001 *     62.4  * 15.43 /     22.536 =        .0427  GR/DSCF



         PARTICULATE  LBS/HR  -•  EPA METHOD  5

         PMR =  CS • 03STD /  (15.43 •  453.6)

         PMR =        .0427 •    0190378. / (15.43  *  453.6)  a    49.997

-------
                                                                                         Kit LI)   HAT A
VO













PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
AMBIENT TEMP.(OEK.F)
BAR. PRESS. (IN. HG)
STATIC PRESS. (IN. H20)
FILTER NUMBER(S)
STACK INSIDE OIM.(TN)
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
METER CALIB. FACTOR
ASAPCO TACdMA
NU 4
PART
DO
55.
29.53
00000
MAHK
60.
.84
SFC EXHAUSI
SIZE-SK IM


OA1F
HUM N
PKUHt

UMHKtf




Li. Mr, TM R trp^
HM/7LF.



Ill
00 .00







ASSIIM
S«KPL
MHTF.H
MF UM

PWUHt
Fli Mil]
I- mix
mix N
HFAO

: I.D.
sum?
i'JUuHEU
IICMI- H
DIFF .







HtATFW SF TTING
HFATEH HIIX
.000
.980
READ » RECURD DATA EVERY 5.0
TRAVERSE SAMPLE CLOCK GAS METER
POINT
NO.

INIT






























TIME TIME
(MIN.) (24-HR
r i nr tt \
LL UCK }
0 907
S.O 0
10.0 0
15.0 0
15.6 923
20.0 0
25.0 0
30.0 0
35.0 0
40.0 0
45.0 0
50.0 0
55.0 0
59.0 1154
65.0 1206
65.0 1544
70.0 0
75.0 0
60.0 0
65.0 0
67.4 1606
67.4 812
95.0 0
100.0 0
106.2 811
106.2 917
111.2 0
116.2 0
121.2 0
123.4 934
123.4 1013
READING
(CU.FT.)

288.717
292,200
295.590
299.030
299.413
302.440
305.890
309.350
312.780
316.240
319.690
323.180
326.660
329.425
333.534
341.070
344.530
347.980
351.430
354.870
356.472
367.663
372.840
376.240
360.410
393.781
397.180
400.590
404.000
405.438
418.760
CFM ii .0 IM.HC;

MINUTES
VELOCITY UHIFICE PRESSUPF.
HEAD DIFFERENTIAL
(IN.H20) (IN.HPO)
DESIRIH ACTUAL

4,500
4.500
4.450
4.500
4.650
4.700
4.650
4.700
4.700
4.700
4.700
4.650
4.500
4.500
4.450
4.100
4.100
4.150
4.100
4.100
4.450
4.400
4.400
4.400
4.600
4.650
4.700
4.700
4.400
4.600
.63
.63
.63
.63
.b3
.63
.63
.63
.63
.63
.6.3
.63
.63
.63
.63
.63
.63
.63
.63
.63
.6 <
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63



STACK
TEMP
(OEG.F)



DkY GAS
TFMP
(DEC,.



METE*

F)
SETTING



PUMP
VACUUM
(M.HG)




01/18/83
PSSS-1
6* STtFL
.132
1.0

FH9
r'.OH

0.
0.



IHPACTUR ifPlfcGER
if *
(DEG.F
P TM'P
) (DFIi.M
1NLF.T OUTLET

70.
72.
72.
73.
79.
79.
77.
80.
83.
82.
7V.
75.
80.
79.
77.
"5.
75.
84.
"9.
79.
77.
73.
70.
68.
78.
79.
72.
Bb.
73.
78.

52.
53.
S7.
60.
53.
53.
56.
59.
62.
h4.~
66.
67.
*9.
66.
5V.
SM.
60.
*>2.
h5.
67.
S9.
Stl.
S3.
S6.
»>•?.
60.
hi .
63.
6S.
*2.

57.
57.
58.
58.
60.
60.
60.
60.
60.
M.
*2.
63.
63.
65.
60.
63.
63.
h3.
63.
64.
hO.
S3.
54.
54.
*2.
hO.
61).
hU.
M .
S3.

2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.3
2.3
2.3
2.2
2.3
i>.<4
2.4
2."
?.t

70.
72.
72.
73.
70.
79.
77.
60.
83.
P2.
79.
75.
80.
7V.
77.
HS.
75.
«4.
89.
79.
77.
73.
70.
6fl.
78.
79.
7?.
85.
73.
7«.

S7.
47.
47.
47 .
49.
4B.
46.
47.
4H.
«?.
5f>.
53.
53.
53.
53.
53.
53.
53.

-------
PLANT
SAMPLING LOCATION
READ * RECORD OATA
TRAVERSE SAMPLE CLOCK
POINT TIME TIME
NO. (M1N.) (2fl-M«

TOTALS
AVERAGE
125.2 1015
125.2 10)1
130.? 0
132. fc 1039
152. fe
ASAMco TACHMA n«it OI/II/H;
NO M;.F) ( 1 1 . H(, ) (|)Fi;.F) (Dkn.F)
llFSIkfl) ACTUAL INl.tT IMIH.tt
020. 00« «.t>00 1.65 l.hj H7. SI. S3. 2.2 07. 54.
• 27.IOB O.bOO l.M I.h3 79. h,?. f, ) . i.f TO. 5«.
• 30.550 O.hSO I.M I.h3 ««. »-S. >.S. 2.2 Bfl. S«.
•32.220 O.hSO l.fcj 1.6? 70. h7. ^S. ^.^ 70. • 5«.
98.519
1.6! I.h3 76. »>0. ho. 2.2 7H. 51.
PERCENT ISOKtNETIC
III.7

-------
>
I
       TACOMA
NO 0 SEC EXHAUST
01/18/83
 PSSS-1
no
                                             25.OC
    PLANT * CITY
    SAMPLING LOCATION
    DATE
    HUN NUMBER
    OPERATOR
    STACK TEMP.
    BAR.PRESS.(IN. HG)
    STACK PRESS.(IN. MG)
    NOZZLE:i.D.(IN.)
    METER HEAD RIFF.
 CALC. MASS LOADING s  1.6073F-02 GR/ACF
IMPACTOR STAGE                             SI
STAGE INDEX NUMBER                         1
050 (MICROMETERS)                        P.26
MASS (MILLIGRAMS)                       16.30
MG/D3CM/3TAGE                            5.916*00
CUM. PERCENT OF MASS SMALLER  THAN  D50   85.33
                                         AT
                                                                                    FI.OMHATK ( ACt-'M)
                                                                                   inw  cnwi) i i IIINS
                                                                                    n »f .
                                                                                                            77.7F
                                                                          UA3 C"MPIIK1
  77. If
 29.53
 28.7?
 .132
1.630
                                                                          SAMPLING
                                                          1 .76S1F-0? r.k/DSCF
                        2          3
                      7.29       0.70
                      8.70       8.30
                      3.15E»00   3.01E«-0<>
                     77.50      70.03
 3.00
 0.20
 1.52E»00  I.96F»0()   2.39*.
66.25     61.39      55.05
Ty (UK/CO
lAM.MICRMS
N t PK RCENT ) : t(i2
CO
N2
02
H20
I"N(M1N.)
*.7fi9fcE»Ol MR/ACM
S5 36 37
S 6 7
62 .77 .50
00 6.60 16.50
1.00
100. 'i
.00
.00
99. (HI
.00
1.00
132.60
0.03<
SB
8
.28
18.00








*6E«oi MG/DSCM
FILTER
9

26.70
                                                                         00.59
                                                                                                                      6.67E»00
                                                                                                                     20. 03
     CUM. (MG/ACM) SMALLER THAN 050
     CUM. (M6/OSCM) SMALLER THAN 050
     CUM. (GR/ACF) SMALLER THAN 050
     CUM. (6R/DSCF) SMALLER THAN P50
     GEO. MEAN OIA. (MICROMETERS)
     DM/OLOGO (MG/DSCM)
     DN/OLOGO (NO. PAHTICLES/OSCM)
                                         3.22E»01
                                         3.«5t»01
                                         1.01E-02
                                         1.5IE-02
                                         2.87E»OI
                                         5.05E+00
                                         0.39E»05
                      2.92E«OI   2.60E»OI   2.50E*01  2.3IE«01  2.09t»01   1.53E»01   9.06t*00
                      3.13E»01   2.83E»01   2.68E+01  2.0flf«oi  2.20E»01   1.60E»Ol   9.71E«00
                      1.2HE-02   1.15E-02   1.09E-02  1.01E-02  9.I3E-U3   6.69E-V3   3.96E-03
                      1.37E-02   1.20E-02   I.I7E-02  1.08E-02  9.79E-03   7.17E-03   O.^OE-03
                      7.76E*00   5.8SE*00   3.76E»00  2.21E»00  1.12E»00   6.05E-OI   3.91E-01  2.0!E-01
                      5.79F.*01   1.5«E»01   7.80E»00  7.33E*00  7.02E*00   3.«2E»01   2.39£»OI  3.21E«01
                      2.37E»Ofl   I.51E»08   2.81E+OH  1.30h*09  1.01E+10   2.72E»11   7.60E*11  7.61E»12
   STANDARD CONDITIONS ARE 20 OEGC AND  760MM  HG.
   AERODYNAMIC DIAMETERS ARE CALCULATED HEHE  ACCORDING td TH^  TASK t;R(IIIM UN LUNG

-------
ro
       IACOMA
NO 4 SEC EXHAUST
01/18/83
 PSSS-1
on
    PLANT * CITY
    SAMPLING LOCATION
    DATE
    HUN NUMBER
    OPERATOR
    STACK TEMP.                77.7F     25.4C
    BAR.PRESS.(IN. HG)        29.53
    STACK PRESS.(IN. HG)      28.72
    NOZZLEU.o.(IN.)          .132
    METER HEAD DIFF.         1.630
 CALC. MASS LOADING = l.f.473F-02  GR/ACF
IMPACTOR STAGE                             SI
STAGE INDEX NUMBER                         1
D50 (MICROMETERS)                        6.34
MASS (MILLIGRAMS)                       16.30
MG/OSCM/STAGE                            5.91E+00
CUM. PERCENT OF MASS SMALLER  THAN 050   85.33
                                                                                            | AtFM)
                                                                          Al IMPAC10W CONDITIONS
                                                                          IMP A CHIP  Tt^P.

                                                                          PAHUCLF  MKNSITY(r;M/CC)

                                                                          MAX.PAHTirLt  IHAM.MICWI'S

                                                                          GAS COMPUSI T ION fHFRCK'JT ) i



CIV
CO
N?
u?
H20
77. 7F ?5.0C
1.00
1 00. (I
.00
.00
99.00
.00
1 .00
                         1 .76536
                         S^
                         a
                       7.37
                       H.70
                       3. |SE«0(I
                      77.50
         SAMPLING I)IIWATIUN(M|N.)

-0? r,H/ltSCF

   S3        S4

   3         03

 5.94F»00  3.84E»(>0   2.29b»00   I.2IF.»00  7.26E-01   4.75E-01  2.57E-01

 1.60E+OI  7.97F»00   7.60E*00   7.95E»00  «

 1.46E»Ofl  2.69E»OM   1.21E+09   8.67t»09  <
   STANDARD  CONDITIONS ARE 20 DEGC AND 760MM  HG.
   AERODYNAMIC  DIAMETERS APE CALCULATED HEKF  ACCtlHlHMU  TO

-------
            1MPACTUH  FIELD  DAT*  TABULATION

PLANT-NAME  AND ADDRESS                TFS1 TEAM

ASARCU TACOMA                          nil
TEST PSSS-I
      NO « SEC EXHAUST

TEST
TB
TF
TT
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
P1TOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/IB/B3
907
103<»
13?. b
.980
.13? IN
.BO
1.63 IN-H2U
METHIC UNITS
01 /I H/IM
907
10*9
t 1?.b
.980
.1. a MM
.HO
ai .0 MM-I
          DROP

VH        VOLUME OF DRY GAS  SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER  TEMP

VMSTO     VOLUME OF DRY GAS  SAMPLED
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BHO       PERCENT MOISTURE BY  VOLUME

FMO       MOLE FRACTION DRY  G»S

MD        MOLECULAR tiT-DRY STACK GAS

MMS       MOLECULAR WT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ARS.

TS        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
                                  98.519 CU-M


                                  60.1    f

                                  97.127 SCF


                                    .981 SCF


                                   1.00

                                    .990

                                  38.73

                                  2B.62

                                  ?9.53   IN-HH

                                 -11.00   IN-H2U

                                  28.1£   IN-Hi;

                                  7fl.     F

                                 lOO.OH   ACF
                         S. 790  CI«-M


                        1b.6    C

                               SCM
                          .028


                         1.00

                          .990

                         n. 7 3
                       750.06   MM-HG

                      -279.
-------
    ISO       PERCENT ISOKINETIC               111.7                 111.7


    NT         TOTAL MASS OF  PARTICLES            1.715  RR            111.100 MC


    PO         PARTICLE DENSITY                     .06   flM/CJ           1.00


       •  68 DE6 F,  29.92  IN.HG.
 I
M
M
*>.

-------
IMPACTOR RESULTS  AND  EXAMPLE CALCULATIONS

                                      LEADhH
  PLANT-NAME  AND CITY
  ASARCU  TACOMA
  TEST DATE   01/1A/H3
                                  TEST
                                  (IU
    PUN Ml)
    PbSS-1
                                                                        SAV'PLl LOCAI ION
                                                                        I1" t SHL  t XHAUST
CALC. MASS LOADING
                          10TAL  MASS (IF PAH1ICLKS  DIVIDED MY A VULUMt.  UNITS CIVtN AWE GHAINi
                          ACTUAL*  CUHIC HUlT (GX/ACF ) .GNAINS Pf H OWY  STAND AhM* • CUM 1C FOOT ((-.W /ObCF ) ,
                          MILLIGHAMS HEW ACIUAL CUHIC  ME 1 h H (Mr;/ »C")  AMI) MLLU'MACS PtM 1>MV  bT»NI»A«U
                          CUBIC  MF itw («r./nscM.)
     EXAMPLE  CALCULATIONS

          CML(GR'ACF)  s MT(GR)  /  IF(ACF)

                   CML  =             1.715  /    lOa.OHl  =

         CML(GR/OSCF)  s MT(GR)  /  VHSTD(I)SCF)

                   CML  =             t .715  /     97. \?_1  -

          CML(MGXACM)  s MT(MG)  /  IF(ACM)

                   CML  =           til.100  /      £.407  =

         CML(MG/OSCM)  x MT{MG)  /  VMSTDCOSCM)

                   CML  =           111.100  /      ?.750  =
                                                                   Gt =
5.91
                          THE PERCENTAGE tlF TMF  TOTAL  MASS SAMPLED  SMALLtH
                          IN OIAMETEW THAM THt COMHE SPONDI N(; DbO  IMDICATtK
                          FOR THAT  STAbb
     CUM  X  (b)  =
                                 MASS(B)  * MASS(9)

                                 MT  (KG)

                           Ih.SO +      10.00 +

                                     111.10  (MR)
                                                   100   =
                                                      •  100  =

-------
     CUM.(MASS/VOLUME)
THE CUMULATIVE  MASS  LOADING OF PAM1CLIS SMALLER  IN
1HAN TMF CURHF SPUNOINi:  050. MASS/VOLUMfc UNITS  APF_  ^r.
MG/r>SCM,GH/ACF ,r,H/l)SCF .
          EXAMPLE CALCULATIONS

               CUM.(MGXACM)  (5)  = MASS(fc) •» MASS(7)  »  MASS(6)  » MASStV)

                                               IF(ACM)

               CUM.(MG/ACM)  dt  =      6.60 »      16.SO  »      IH.Ud 4

                                                    ?."S  (ACM)


     CEO.MEAN OIA. (MICROMETERS)     THE GF.OMETHIC  MEAN  DIAMETER IN
                                    FOK A PAKTICULAW  SlAlif.

          EXAMPLE CALCULATION

               6EO.MEAN OIA.(J)  = SURT( 050(J)  *  I)SO(J-I))

               GEO.MEAN DIA.(b)  = SDHT(       .B5  *      1.70)   =
     DM/OL06D(MG/D3CM)
DM IS MG/OSCM/STAGE(J)  AND DLOGO IS LOG I 0 (I)SO (J-l )  /
OSO(J)) hHERt  J  IS  TMK  CORHESPONUING STAGE  NUMBER.
FOR STAGE  I  THE  MAXIMUM PAHTICLt OIAMEIFH  IS USED.
FON STAGE  9  (BACKUP  FILTER)  THE HSO IS  ASSUMED  AS
.5 * D50 OF  STAGt 8.
          EXAMPLE CALCULATION

               OM/OL060(J)  =   MG/OSCM/STAGE(J)
                               LUG( OSO(J-l) / 050(J))

               OM/OLOGO  (3)  =              3.01

                               LOG(      7.37 /       a. 78  )
                              16.03
     UN/OLOGO                       THE NUMBER OF  PARTICLES  PER UNIT VOLUME FOW  A  STAGE.

          EXAMPLE  CALCULATION

               UN/OLOGOU)  =            OM/OLOGDU)

                                5.83599F-10 « PD(r,M/CC)  •  GEO.MEAN I) I A . ( J )

               DN/OLOGD  (3)  =                16.03

                                5.235999E-10  *       I.Oil  •        5.9
-------
                                                         FIELD  DATA
PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
AMBIENT TEMP.(OEG.
BAR. PRESS. (IN. HG)
ASAHCO TACOMA
NO 0
PAHT
no
F) 55.
30.00
src FX
SI/E-SK1M

IIATF



HIIN NUMHEH


PWDME
NiU/LE
Lf Nf, IH
:
ASSIIMF.il MIMS1


STATIC PRESS. (IN. H20) -9.00
FILTER NUMPEM(S)
STACK INSIDE 01M.(
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
MACK
IN) bO.
.80

.000
III
00 .00


CFM a) .0 If:. Hi;





SAMPLE
MF It- W
ME HH

PHOHE
Hfc A TfcR

HIJX Ml
HI'* MIN
Mt AH 01

HF.ATE"
mix st

* TYP(-
1 ,\l .
IIHE
MHf- R
Hb^f
(-'(• .

SE TTING
TT ING











01 /20/K3
PSSS-2
b ' STt t-L
.13?
1 .0

FH9
2.0t>

0.
0.

METER CALI8. FACTOR .980
READ » RECORD DATA
TRAVERSE SAMPLE CLOCK
POINT TIME TIME
NO. (MIN.) (20-HR

INIT 0 1005
5.0 G
7.4 1052
9.7 1056
15.2 1106
15.2 1025
16.5 1027
21.5 0
25.7 1000
20.2 1538
30.7 0
01.9 1555
01.9 1655
06.5 1700
50.0 1708
EVERY 5.0
GAS METEH
READING
(CO. FT.)

506.973
510.230
511.738
513.187
516.781
530.989
531.806
535.100
537.800
539.102
502.010
509.658
559.317
562.187
560.921
MIMITf S
VELOCITY DHIFlCf PHESSUHE
HEAP IllFFEHFNTIAL
(IN.H20) (IN.M2U)
HESIHFP ACTUAL

.950 l.«3
.950 .03
.700 .03
.700 .03
.850 .03
.900 .03
3.900 .03
3.900 .03
3.850 .03
0.050 .03
4.050 .03
3.850 .03
3.700 .03
3.700 .03
.53
.03
.03
.03
.03
.03
.03
.03
.03
.03
.03
.03
.03
.03

STACK
TEMP
(DKC.F)

PKY GAS M
TFMP
(DEIJ.F


ETKR PUMP


IMPACTOH IKPINOEH
VACUUM IF
) (I
M.HG) (I)F.G.
HP TEMP
M (UEI..F)
INLET OUTLET

hO.
*0 .
70.
70.
70.
«e.
77.
70.
70.
75.
71.
75.
75.
91.

50.
55.
5b.
55.
56.
Sb.
55.
57.
S6.
50.
56.
56.
6U.
60.

57.
57.
S7.
S8.
59.
57.
^8.
59.
59.
hO.
60.
59.
*o.
60.

2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.1
2.1
2.1

bO
6"
70
70
70
HH
77
70
70
75
71
75
75
91

06.
06.
07.
07.
07.
07.
09.
09.
50.
50.
50.
51.
51.
52.
TOTALS
AVERAGE
50.0
30.081
                                         .03
                               1.03
                                                         70.
                                                                 5b.
                                                       59.
2.0
                                                                                         70.
                                                                                 09.
          PERCENT ISOKINETIC
                              110.5

-------
        PLANT  & CITY


        SAMPLING LOCATION


        DATE


        RUN NUMBER


        OPERATOR


        STACK  TEMP.


        BAR.PRESS.(IN.  H6)


        STACK  PRESS.(IN.  HG)


        NOZZLEtl.D.UN.)


        METER  MEAD DIFF.


    CALC. MASS LOADING a 3.2079E-02 GR/ACF


    IMPACTOR STA6E


    STAGE  INDEX NUMBER


    050  (MICROMETERS)                        6
>

^   MASS (MILLIGRAMS)                        9

M
00   MG/03CM/STAGE                            9


    CUM. PERCENT OF  MASS  SMALLER THAN 050  87
ASARCO TACUMA


NO 4 SEC F.X


01/20/83


 PSSS-2


no


  74.4F


 10.00


 29.34


 .132


1.430
                              l"p*tTUH  FLi'hHATE < ACFM)
                              AT  IKPACTtIN CONDITIONS
                                       H.MP.
23.6C
                                                                  . 4F
                              PARTICLE  DfcNSI TY(t;M/CC)


                              MAX.PAkTICLK OIAM.MICHOS


                              I,AS  Ct>MPOSIT10N(PFWCE'>UMATIUN(MIN.)
 SI


 1





.30


.55E+00


,48
   CUM.  (MG/ACM)  SMALLER THAN 050


   CUM.  (MG/DSCM)  SMALLER THAN DSD


   CUM.  (GR/ACF)  SMALLER THAN 050


   CUM.  (GR/OSCF)  SMALLER THAN 050


   GEO.  MEAN OIA.  (MICROMETERS)


   OM/DLOGD  (MG/DSCM)


   DN/OLOGO  (NO.  PART ICLE V03CM)
b,


b.70E*01


2.81E-02


2.93E-02





8.99E»00


6.
            s^
 5.bO


 5.75t*00


79.95


 5.B7M01


 b.l2K*Ol


 2.5bE-02


 2.b7E-02


 8.15E»00
                        GH/USCF
                       S3
                                  sa
 4.94


 8.20





b8.91
                                J.lfi
                              b5.95
                                                        7. .i4oeE»oi  MR/ACM


                                                       35         Sb        S7


                                                       5          b          7


                                                     1.71        .82       .57


                                                     b.OO       7.80     Ib.OO
   .709





  1 .00


100.11


   .00


   .00


 99.00


   .00


  I .00


  50.40


     7.b542E»oi MG/DSCM


     SB     FILTER


     8         9


    .31


  12.30
                                                               l.bflfc'Ol   1


                                                             25.84       9.29
                                                                                  b.90


                                                                                  7.08E*00
           3.72E+OH
                                                    S7.87     47.38


                                 5.0bE»01   U.H«E»01  4.2SE+01   3.4BE+01   1.90E»01  b.H2E+00


                                 5.27E»Ol   5.0«>E»01  4.
-------
VD
23. 6C
    PLANT * CITY
    SAMPLING LOCATION
    DATE
    RUN NUMBER
    OPERATOR
    STACK TEMP.
    HAR. PRESS. (IN. HG)
    STACK PRESS. (IN. MR)
    NOZZLEII.O.dN.)
    METER HEAD DIFF.
 CALC. MASS LOADING = 3.aOT9E-02 GR/ACF
IMPACTOR STAGE                             SI
STAGE INDEX NUMBER                         1
050 (MICROMETERS)                        8.76
MASS (MILLIGRAMS)                        9.30
MG/OSCM/STAGE                            9.55E*00
CUM. PERCENT OF MASS SMALLER  THAN 050   H7.0B
                                  ASARCO TACOMA
                                  NO  «  SEC  EX
                                  01/20/8?
                                   PSSS-2
                                  on
                                   70. OF
                                   30.00
                                   ?9.3«
                                   .132
                                  i.«so
                                       H.'lhR A f
                              AT  tMPArlllH CnNIM 1 II'MS
                              JMPACTUH U^P.
                              PAKTJCLE OEMS M Y ((.M/CC )
                              »IA x .PAM1 ICI.F 01 AM.KICMUS
                              I.AS  cuMpiisi T KIN (PI- HCM^T ) :
                                                                                          r.?«OHe»()| MG/ACM
                                                                                         55        Sb        S7
                                                                                         S         t>         7
                                                                                       1.7«»       .90       .65
                                                                                       6.00      7.80     16.00
     CUM. (MG/ACM) SMALLER  THAN  050
     CUM. (MG/DSCM) SMALLER THAN  050
     CUM. (GR/ACF) SMALLER  THAN  050
     CUM. (GR/DSCF) SMALLER THAN  050
     GEO. MEAN OIA. (MICROMETERS)
     DM/DL06D (MG/DSCM)
     DN/DLOGD (NO. PARTICLE9/DSCM)
                                           6.02E+01
                                           b.70E»01
                                           2.81E-02
                                           2.93E-02
                                           2.96E»01
                                           9.03E«00
                                           6.65E*05
                              SAMPLING DUHATIUMMK*.)
             3.30a9t-02  GM/OSCF
             S2        S3         S4
             2         3         4
           7.70      5.02       3.21
           5.60      8.20       2.20
           5.75E«(Hl  8.02E*00  2.2bE»oil  6.1bt»00  B.01E»00
          79.95     68.91      65. 9S     57.87     07.3fl     ?5.80
           5.87E+01  5.06E«01  U.eaE+OI  a.2SF+01  3.08E»01   1.90E+UI   6.82E+00
           h.l?E+01  5.27E«Ul  5.05E«t'l  a.0^t»01  3.63E«01   l.«»8t»01   7.11E*00
           2.56E-02  2.21E-02  2.12E-U2  1.86t-02  1.52E-02   8.29E-U3   2.9Hf03
           2.67E-02  2.30E-02  2.21E-02  1.90E-02  1.5«E-02   «.60t-03   3.I1E-03
           8.23F.»on  6.23t*on  a.0.
-------
              IMPACTOR FIELD DATA  1ABULAUON
   PLANT-NAME AND ADDRESS                TEST  TEAM  LtADFK
   ASARCO TACOMA                         DO
   TEST PS8S-2
   TEST DATE
                   NO a SEC EX
                                          ENGLISH UMTS
                                             01/20/83
                                                                  METWIC UNITS
NJ
O
          DROP
VM        VOLUME OF DRY GAS  SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER  TEMP
VMSTD     VOLUME OF DRY GAS  SAMPLED
          AT STANDARD CONDITIONS*
VHC       VOLUME OF NATER VAPOR
          AT STANDARD CONDITIONS*
BMO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY  GAS
MO        MOLECULAR HT-ORY STACK GAS
MHS       MOLECULAR NT-STACK GAS
PB        BAROMETRIC PRESSURE
PSI       STATIC PRES OF STACK GAS
PS        STACK PRES, ARS.
TS        AVERAGE STACK TEMP
IF        GAS SAMPLED AT
          STACK CONDITIONS
  34.081 CU-FT

  ST.6   F
  34.281 SCF

    ,3«6 SCF

   1.00
    .990
  28.73
  28.62
  30.00  IN-Hi:

  -9.00  IN-H2U
  29.30  IN-HG
  74.    F
  35.74  ftCF
TB
TF
TT
Y
ON
CP
PM
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
1045
1708
5P.4
.980
.132 IN
.84
1.43 IN-H2U
10<»5
1708
50

3

?b
    .980

   3.4   MM

    .84

  !b.J   MM-H20

       ) Ctl-M

  14.2   C

    .971 SCM


    .010 SCM


   1 .UO

    .990

  28.73


 782.00  MM-HG

•228.bO  MM-M.20

 745.19  MM-Hli

  24.     C

   1.01  ACM
   AS
          STACK AREA
2827.
                                                     SO-IN
   1.824

-------
ISO       PEHCENT ISOKINETIC




MT        TOTAL  MASS OF PARTICLES




PD        PARTICLE DENSITY




   •  60 OEG  f,   29.92 IN.HG.
HO.5




  J.I 17 PH




   .Ob  (JH/CI
110.-1




 7<4. 50(1 MI;




  l.on  i;«

-------
                 IMPACTOR  RESULTS AND EXAMPLE CALCDLAHDNS
         PLANT-NAME AND  CITY
         ASARCD TACOMA
         TEST DATE  01/20/83
                                 TEST  TEAM  LEADER
                                 DO
 WIIN NU

 PSSS-2
SA^Ml.t L'lt A I HIM
M) tt SKC f X
       CALC. MASS LOADING
ro
to
                          TOTAL MASS OF PARTICLES DIVIDED BY A VULONt.  UNITS GIVf.N ARF  GRAlNb PER
                          ACTUAL* CUBIC FDllT (GH/ACF ) ,f,RA IMS PF.R f)W»  S1ANDARO«« CIIWIL FUfl t ( GR/OSCF ) ,
                          MILLIGRAMS PE»  ACTUAL  CUBIC MF TFW(MG/ACM)  AMD MILL tr.*A».-s PF.X  ORY  STANOAMU
                          CUBIC MFTF.H(Mr,/IISCM.)
EXAMPLE CALCULATIONS


     CML(GR/ACF)  r  MT(GH)  / IF(ACF)


             CML  s             1.107  /


    CML(G»/OSCF)  s  MT(GR)  / VHSTDtDSCF)


             CML  s             1.107  /


     CML(MG/ACM)  *  MT(MG)  / IF (ACM)


             CML  =            70.300  /


    CML(MG/DSCM)  =  MT(MG)  / VMSTD(OStM)


             CML  =            70.300  /
                                                        30.281  =
                                                         1.012 =
                                                          .971  s
                                                                               UR/ACF
.0350  r,k/l)SCF
       Mb/USCM
       050 (MICROMETERS)
                          THE SIZE OF THE  PAHUCLES ON E«CM STAGE  ASSIIMINP, A SO PKRCENT
                          COLLECTION EFFICIENCY  DEFINITION
       MASS (MILLIGRAMS)
                          THE *ASS ON EACH  STAGE  COLLECTED
       M6/OSCM/STAGE
                          THE MASS LOADING  FUR  EACH STAGE. UNITS  GIVEN ARE MILLIGRAMS
                          PER DRY STANDARD  CUHIC  METER F"U« EACH ST AKfc (MR/I1SCM/S T AiJt )
            EXAMPLE CALCULATIONS


                 MG/OSCM/STAGFU)  =   MASS(l) / VMSTD(OSCM)


                 MG/DSCM/STAGEU)  =      9.30 /
       CUM. PERCENT OF
                                           .971  =
                          THE PERCENTAGE  OF  THE  TOTAL MASS SAMPLED  SMALLER
                          IN DIAMETER  THAN  THF  COKHESPIINDINb D^P  INDICATED
                          FOR 1HAT STAGF.
            EXAMPLE CALCULATIONS


                 CUM X  (6)  =  MASS(7) * MASS(B)  »  MASS(9)


                                        MT  (MG)


                 CUM Z  (6)  e      Ift.OU *      12.30  *       h.90


                                            70.30   (MR)
                                                •  100  =
                                                     • 100  =  57.87

-------
 I
M
U)
     CUM.(MASS/VOLUME)
                                         THE  ciiMtiLAtivE M»SS LOADING  (IF  fAhiici.ES  SMALLER  IN
                                         TH*N !HE CHRRESMIK'lilNr.  l>50.  MA SS / vilLHMt UN I t b  AW|-  M.
                                         M<,/I>SCM,GH/ACF
          EXAMPLE  CALCULATIONS

               CUM.(MR/ACM)  (5) = MASS(fc)  *  MASSC7)  » M»SS(8)  »  MASSCO

                                               IF l»CM)

               CUM.(MR/ACM)  (5) =      7.80  »      Ib.UO »      13.30  *
                                   ^^•^••^••^"^^••"•"^^•••^•^^••••^ — • — »^«
                                                    1.01  (ACM)
     GEO.MEAN OIA.(MICROMETERS)
                                         THE  GEUMETHIC MEAN OIAMETEW  IN «ICKIIME IF.KS
                                         FOW  A  PAHtlCULAH S1AC.F..
     EXAMPLE  CALCULATION

          GEO.ME*N DIA.(J) = SORT( 050(J)  *

          GEO.MEAN oiA.(t>) =

DM/DLOGD(MG/OSCM)
                                                          1.79)   =
                                                                             t .
                                    ()M IS MG/OSCM/STA(;t(J) AND OLOGO  IS LOG t U (OSO (J-I )  /
                                    U50(J))  hHfcBt  J  IS tHE CURRESPUNDINr, STAGE NUMBE* .
                                    KOH STAGE  I  THE  M4XIMIIM PARTICLF.  DIAMETf'N IS  USED.
                                    FOR STAGE  <»  (BACKUP FILTER)  THE USO IS ASSUMED  »S
                                    .5 • 050 OF  STAGE 8.
          EXAMPLE CALCULATION

               OM/OLOGIMJ)  =   MG/OSCM/STAGE(J)
                               LUG(
                                                    P50U))
                    OM/OLOGO (1) =
                                   LOG(
                                             8.

                                         7.7a
                                                                       ao.87
                                                 S.<^
                                    THE NUMBER  OF  PAhtlCLFS PER  UNIT  VOLUME F (IH A STAGE.
         ON/DLOGD

               EXAMPLE CALCULATION

                    UN/DLOGD(J) =             DM/DLUGU(J)

                                    5.23599F-10 • PIKGM/CC) • GEO.MEAN I) I » . ( J )

                    ON/DLOGO (3) =                qa.87

                                               10 *      1.00  •        b.i>3
•   CALCULATED AT  STACK  CONDITIONS
•*  CALCULATED AT  STANDARD CONDITIONS
b6 OEG.F AND 89.92 INCHES OF HG (760 MMHG)
                                                                                                    <^^.«48

-------
                                                               F itui)  DATA
 I
M
NJ
PLANT ASAHCU IACOMA
SAMPLING LOCATION NU 4 SEC EX
SAMPLE TYPE PAHT SIZE-SKIM
OPERATOR DO
AMBIENT TEMP. (DEC. F) 50.
BAR. PRESS. (IN. HG) 29.70
STATIC PRESS. (IN. H20) -9.00
FILTER NUMBER(S) MARK III
STACK INSIDE DIM. (IN) 60.00 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM » .0 IM.Hb
METER CALIB. FACTOR .980
READ ft RECORD OATA EVERY 5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY (1HIFICE PRESSURE
POINT TIME TIME READING HEAD DIFFERENTIAL
NO. (MIN.) (24-HR (CU.FI.) (IN.H2U) (IN.H2U)
DESIRED ACTUAL
INIT 0 955 602.112
5.1 1000 605.409 4.500 .61 .61
7.2 1007 606.826 4.450 .61 .61
10.8 1014 609.200 4.500 .61 .61
11.6 1142 609.705 3.850 .61 .61
13.4 1146 610.900 3.850 .61 .61
16.5 1153 612.973 3.900 .61 .61
20.8 1201 615.890 3.800 .61 .61
20.6 1626 623.048 3.900 .61 .61
25.6 0 626.550 3.500 .61 .61
29.1 1635 620.738 3.500 .61 .61
29.1 1720 633.577 3.850 .61 .61
36.0 0 638.370 3.350 .61 .61
39.0 1730 640.409 3.400 .61 .61









DATE
HUN NIIHHEH
HHUBE LK.Nf, tH K. TYPE
Nt'/7LE : 1.0.
• SSHMF.li MfUSTIIHK
SAMPLE HU* MUMHKh
Mf TEH HUX NIIKHEH
ME TEH HE AD D JFK .










PHUBE HEATEH StMING




STACK
TEMP
(DEG.F)


68.
75.
72.
83.
7h.
76.
74.
75.
73.
7h.
75.
/h.
77.
HE ATE« IMIX SE IT ING



UKY GAS METEH PUMP
TEMP VACUUM
(DEG.F) (1N.HG)
I ME I OUTLET

43. 49. 2.0
44. 49. 2.2
'15. 50. 2.2
50. S3. 2.2
17. 53. 2.2
«7. 53. 2.2
40. S5. 2.2
50. 54. 2.2
S3. 55. 2.2
Sh. S6. 2.2
50. S4. 2.2
S5. SH. 2.2
59. S9. 2.2




»M /22/MJ
PSSS-3
6* STEEL
. 132
1.0

FB9
2.H0

0.
0.



IMPACTUH IMPINGES
IE*
(DEG.F


60.
75.
72.
03.
76.
76.
74.
75.
73.
7h.
75.
76.
77.
P TEHH
) (OEb.F)


47.
47.
48.
4fl.
48.
50.
51.
52.
52.
52.
54.
54.
55.
      TOTALS

      AVERAGE
39.0
26.300
                                        I .61
                               1 .61
                                                         75.
50.
54.
                                                                       75.
                                                                                                    51
                PERCENT ISOKINETIC
                              111.0

-------
N)
cn
    PLANT « CITY
    SAMPLING LOCATION
    DATE
    RUN NUMBER
    OPERATOR
    STACK TEMP.
    BAR.PRESS.(IN. HG)
    STACK PRESS.(IN. HG)
    NOZZLE>I.D.(IN.)
    METER HEAD DIFF.
 CALC. MASS LOADING = 2.6551E-02  GR/ACF
IMPACTOR STAGE
STAGE INDEX NUMBER
050 (MICROMETERS)
                                   ASARCU TACUMA
                                   NO a SEC FX
                                   01/22/83
                                    PSSS-3
                                   no
                                     75. \f    23.9C
                                    29.70
                                    29.oa
                                    .133
                                   1.610
  SI
  I
8.63
                                             f. (At.FM)
                             A I  IKPAC TlIK tONPI 1 IONS
                                                                                                                 .717
                                                               7b.lF
                             PAHMTLF OtNS! TY(GM/CC)

                             MAX.PAWT n;il:. DIAM.KICUIIS

                             GAS C11MMHS1T l()N(Pf KCtNT ) :


CfV
Cn
N2
02
H20
1 .00
100.11
.00
.00
9Q.no
.CO
1 .00
                                                           S2
                                                         7.6?
MASS (MILLIGRAMS)                        7.90
MG/DSCM/STAGE                            1.05fc»Ul
CUM. PERCENT OF MASS SMALLER  THAN  05U   83.58



1
1
h.tl7
35
5
.70
.80
jHc^Ol Mliy
S6
b
.HI
5.00
'ACM
S7
7
.57
13.00
6.40t
s«
8
.30
10.40
J3E*01 MG/DSCM
FILTER
9

5.70
            72E»()P
            75
      CUM.  (MG/ACM)  SMALLER  THAN 050
      CUM.  (MG/DSCM)  SMALLER  THAN 050
      CUM.  (GR/ACF)  SMALLER  THAN DSO

      CUM.  (GR/DSCF)  SMALLER  THAN DSO
      GEO.  MEAN DIA.  (MICROMETERS)
      DM/DLOGD  (MG/DSCM)

      DN/OLOGD  (NO.  PARTICLES/DSC*)
                                         5.08E*01

                                         5.J
                                         2.i

                                         2.^
                                         2.94E»01
                                         9.86E»00
                                         7.<
                                                         3
                                                        77
          2.06t-0?
           . 111*00
           .83F*01
         SAMPLING DIIPAT KIN (M tN. )
 U2 GR/OSCF

   S3        SO
   3         4


  .00      1.50
 O.OOE*00  1.99E»00   2.3"
77.75     70.64      70.B9

 4.72E»01  4.53E»01   4.31t*01   3.68E*01  2.03E»01

 0.98E»01  4.78E*Ol   4.5«E»OI   3.BHt»Ot  2.14E*OI   7.59E*00
 2.06E-0?  1.98h-02   1.B8E-02   l.blt-0?  8.69E-03   3.15E-03
 2.1*E-U2  2.09E-0^   1.99E-02   1.69E-02  9.37E-03   3.32E-03
 6.12E»00  3.93K»00   2.3IE*00   1.1HE*00  b.tfOt-Ul   4.I5E-01
 O.OOE*00  1.02E*01   8.9ME*00   c?.07F.*Ol  I.11E*02   5.05F. + 01   2.51E*01
 O.OOE + 00  3.2?t»0«   I.S9t*09   «».«3E*10  b.77E*ll
                                                                                            6.b4E*00   1.73E»01  1.38E«Ol  7.57E»00
                                                                                           60.50      33.47     11.85
    STANDARD CONDITIONS  ARE  20  DEGC  AND 760MM HG.
    AERODYNAMIC DIAMETERS  AKE CALCULATED HEI*E ACCORDING Tit  THE  TASK  GWOI'P UN LUNG liYNAMtCS.

-------
M
to
    PLANT ft CITY
    SAMPLING LOCATION
    DATE
    RUN NUMBER
    OPERATOR
    STACK TEMP.
    BAR.PRESS.(IN. HG)
    STACK PRESS.(IN. HG)
    NOZZLEII.D.UN.)
    METER HEAD DIFF.
 CALC. MASS LOADING a 2.6551E-02 GR/ACF
IMPACTOR STAGE
STAGE INDEX NUMBER
DSO (MICROMETERS)                        0
MASS (MILLIGRAMS)                        7
MG/DSCM/3TAGE                            1
CUM. PERCENT OF MASS SMALLER THAN DSO  03
                                   ASARCO TACUHA
                                   NO n SEC EX
                                   01S22/03
                                    PSSS-3
                                   00
                                     75.IF    23.9C
                                    39.70
                                    29.04
                                    .132
                                   1.610
      CUM.  (MG/ACM)  SMALLER  THAN  DSO
      CUM.  (MG/DSCM)  SMALLER THAN OSO
      CUM.  (GR/ACF)  SMALLER  THAN  OSO
      CUM.  (GR/OSCF)  SMALLER THAN 050
      GEU.  MEAN OIA.  (MICROMETERS)
      OM/DLOGO  (MG/DSCM)
      ON/RLOGD  (NO.  PARTICLES/DSCM)
 SI
 1
,7?
,90
,05E»01
.SB
,08E»01
                                          ,3«fc-02
                                          ,95E»OI
                                          ,90E*00
                                          ,356*05
   S2


 7.70
 2.80
 3.7?E»00
77.75
 4.72E»01
 4.98F»01
 2.06E-02
 2.IBE-02
 ».19E»no
 b.90E«01
 2.40E»0»
   S3
   3
 5.On
  .00
A 1 1 MPAT 1
MAKTKLK
MAX .HAH1 1
FLUMHATb (ACFM)
IIIH CONDITIONS
TKMH. 7S.1F
ntNSlTMGM/tC)
ICLE IlIAM.MICHn.S
MS U'MPMSl TIllNCHfcKCbNM : C08




SAMPLINI;
CF
34
a
3.22
1.50
CO
Hi
U2
H20
l)IJHATinN(MIM. )
»>.0758E»01 MG/ACM
S5 Sfc S7
5 h 7
1.78 .89 .b5
l.HO 5.00 13. 00
.71 /
23. 91.
1.00
100.0
.00
.00
99.00
.00
1.00
39.00
d.406
S8
8
.38
10.40









i3t»oi MG/DSCM
FILTER
9

5.70
                                                                                                            I.73E*Ol   I.3BE*OI   7.57E»00
                                                                                                           33.17      11.85
 O.OOE»()0  l.99t + (IO  2.39t*0»
77.75     74.61     70.09      80.50
 4.72E+U1  1.53E+01  4.31E«01   3.68E+01   2.03E«Ol  7.20t»00
 4.9BF.»01  a.7Bt*Ol  4.b4F.»01   3.8«t»01   2.10E»01  7.59K»00
 2.06E-02  1.9BE-U2  1,8«t-02   I.61E-02   8.89E-03  3.15E-U3
 2.18E-02  2.09t-02  1.99t-02   I.b9t-02   9.37E-03  3.32t-03
 6.20E*00  t.Olf.+Ol)  2.39fc»oO   l.c!6E.+0<>   7.5«>E-0|  4.97E-OI
 O.OOE*00  l.OflF + Ol  9.29E»00   2.21E*01   1.20t*ll2  b.03t*(M
 0.onE*00  3.09t»(»»  I.29E*09   2.I1E«10   5.41t*M  9.39E*1I   2.«4t»I2
    STANDARD CONDITIONS  ARE  20  DEGC  AND 760MM HG.
    AERODYNAMIC DIAMETERS  ARE CALCULATED HERE ACCORDING TO

-------
            IMPACTOH FIELD  OATA  lAHULAltUN

PLANT-NAME  AND ADDRESS                TEST TEAM LEADEN

ASARCO TACOMA                          on
TEST PSS3-3
TEST DATE
      NU a SEC EX
                               ENGLISH  UNITS

                                   01/22/M
          AT STANDARD CONDITIONS*

VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

MD        MOLECULAR HT-ORY STACK GAS

MNS       MOLECULAR ftT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, A«S.

T3        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
                                    .268  SCF


                                   1.00

                                    .990

                                 28.73

                                 2B.62

                                 29.70   IN-HG

                                 -9.00   IN-H20

                                 29.«a   IN-HG

                                 75.     f

                                 27.96   ACF
                                                               METRIC UNITS
TB
TF
TT
Y
DN
CP
PM
VM
TM
VM8TO
TIME-START
TIME -FINISH
NET TIME OF TEST. MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
955
1730
39



1
26
51
26

.0
.980
.132 IN
.80
.61 IN-H2U
.300 CU-FT
.7 F
.507 SCF
9S5
1730
39.0
.9HO
3.0
.80
00.9
.705
10.9
.751



MM

MM-H20
CU-M
t
SCM
    .OOfl SCH


   1.00

    .990

  28.73

  28.62

 75«.3B  MM.MI,

•228.60  MM-H2»>

 737.57  MM-HI;

  2a.    C

    .79  ACM
AS
STACK AREA
2827.   SfJ-IN
   1.82« SU-M

-------
   ISO        PERCENT ISOKINETIC               ltl.0                  111.0




   MT         TOTAL MASS OF PARTICLES              .74?  f.H             qH.IHO Ml




   PO         PARTICLE DENSITY                     .06   i;H/CI           1.00




      •  68 OEG  F,   ^
-------
                     IMPACTPR  RESULTS AND EXAMPLE CAI.CIILAI IUNS
            PLANT-NAME  AND  CITY
            ASARCO TACOMA
            TEST DATE   0!/2?/83
                                 TtST TEAM LEADf.R
                                 no
     RUN
                      SAMHLt  LOCATIUM
                      fjn  «  src  EX
          CALC. MASS LOADING
 \
M
ro
                          TOTAL MASS OF PARTICLES DIVIDED  HY  A  VULDMt. UNITS CIVEN AKE  GRAINS PER
                          ACTUAL* CUHIC EOOT(GR/ACF).GRAINS  PER DRY S T ANUAHI.i** CU'UC F 0(> \ (I,H /USCE ) ,
                          MILLIGRAMS Ptw ACTUAL CUBIC ME IEM(MI;/ACW) AND MILLIl;KA^s PEW  OKY  SIANUAMD
                          CUHIC ME TEH(M(;/DSPM. )
EXAMPLE CALCDLATIONS

     CMLCGR/ACF) = MT(GH)  /  IF(ACF)

             CML =              .702 /     27.957 =

    CML(GR/T)SCF) = MT(GR)  /  VMSTn(DSCE)

             CML =    ,          .702 /     2b.507 =

     CML(MG/ACM) = MT(MG)  /  IF(ACM)

             CML =            08.1UO /        .792 =

    CML(MG/OSCM) = MT(MG)  /  VMSTfMDSCM)

             CML T            Ofl.100 /        .7M =
                                                                                 r,H/ACF
                                                                          ,02«0  t;H/DSCF
                                                                                 MU/DSCM
          D50 (MICROMETERS)
                          THE  SIZE OF TMt PAVTICLES UN  EACH  STAGE ASSUMING A MI PERCENT
                          COLLECTION EFFICIENCY DEFINITION
          MASS (MILLIGRAMS)
                          THE  MASS ON EACH STARE COLLF.CTEO
          MG/DSCM/STAGE
                          THE  MASS LOADING FUR EACH STAGE.  UNITS GIVEN ARE MILLIGRAMS
                          PER  DRY sTANOARn cubic METER  FUR  F.ACM STAGE
               EXAMPLE CALCULATIONS

                    MG/OSCM/STAGE(1)  =   MASS(l) / VMS TO(DSC*)

                    MG/OSCM/STAGEM )  =      7.90 /
                                          .751 =
10.09
          CUM. PERCENT OF  M«SS
                          THE  PERCENTAGE OF THE  TOTAL  MASS  SAMPLED SMALLER
                          IN DIAMETER IHAN THE CORRESPOND I Ut,  l>50
                          FOR  THAT STAGE
               EXAMPLE CALCULATIONS

                    CUM X  (ft)  a  M»ss(7)  + MASS(A) » MAbSO)

                                           MT (MG)

                    CUM I  (6)  =      15.00 *     10.00 »       5.70

                                               08.10   (MG)
                                               *  tOO   =
                                                     •  100   =  70.

-------
          CUM. (MASS/VOLUME)              tHt CUMULAim V*SS  LEADING UF PAPMCLES SMALLER  IN
                                         ?MAN THE COWKt SPI)Nl)|lS(«O

                                                    IF (ACM)

                    CUM.(MG/ACMI  (5)  =      5.00 »      13. on  *      lu.oo «       -3.71;
                                        	    =      '43.07
                                                          .79   (ACM)


          GEO.MEAN DIA.(MICROMETERS)     THE GEOMETRIC MEAN DIAMETEH IN MICKHMFIFKS
                                         FUR A PARTICULAR  SIAUI-.

               EXAMPLE  CALCULATION

                    GEO.MEAN  DTA.U)  = SORT( oso(j)  * osuu-m

                    GEO.MEAN  r>IA.(6)  = SQRT<       .69 *       1.7H)   =      i.?b

 i
£         DM/OL060(MG/OSCM)              DM IS MG/DSCM/STAGE(J)  AND  OLOGD IS LOUIo U)SO(J-I)  /
O                                        U50U)) WHERE J  IS  THf  CORRESPONDING STAGE  NUMBER.
                                         FUR STAGE  1  THE  MAXIMUM  PARMtLE DIAMF. TF.R  IS  IISEU.
                                         FOR STAGE  9  (BACKUP  FILTER) I"E OSu IS ASSIiMEn  AS
                                         .5 • 050 OF  STAGE H.

               EXAMPLE  CALCULATION

                    DM/DLOGOU)  =    MG/OSCM/STAGE(J)

                                    LOG( D50(J-1) / MbO(J))

                    UM/OLOGD  (3)  =               .00

                                    LUG(      7.70  /       5.00  )


          ON/OL060                       THE NUMBER OF PARTICLFS  PER UNIT VOLUME K>K A STAGE.

               EXAMPLE  CALCULATION

                    DN/DLOGDU)  =             OM/DLOKIXJ)

                                     5.23599F-IO •  PDIGM/CC)  *  GF.O.MFAN DIA.(J)

                    DN/DLOGD  (3)  =                 .00

                                     5.^3S999E-10 «       1.0"   •        h.tfu

     *   CALCULATED AT  STACK  CONDTlldNS
     ••  CALCULATED AT  STANDARD  CONOITIONS
     66 DEG.F AND £9.92  INCHES OF  HG  (760 MMHG)

-------
END OF PROGKAM
IFILE FTNIO a CIDROtDA.OLD
IFILE fTNI l=CIOHO£D*fOLD
:RUN CIORZPG:STACK=£OOOO
END OF PROGRAM
tFILE FTN08*CIOR03DA,OLO
tFILE FTN093CIOROOO»,OLD
tRUN CIOR4PG

-------
      ASARCO AVERAGE PARTICLE SIZE DISTRIBUTION
RHOs t.OO GM/CC
                       MEAN CUMULATIVE    UPPER  CUNFTIHNCE
INTERVAL   DIAMETER   MASS CONCFNTHA1 ION      LIMIT
           (MICRONS)       (MG/ACM)           (MG/AL")
                                              2.«7E*00
                                              3.«2F«00
                                              S.bfeE+OU


















>
1
(-<
to
to






























1 ,
2 i
3 <
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27 i
28 i
29 i
30 i
31 J
32 I
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
?.50E-01
J.71E-01
S.95E-01
.20E-OI
.47E-01
.77E-01
.09E-01
.45E-01
.83E-01
.24E-OI
.69E-01
.18E-01
.71E-01
.28E-01
.91E-01
.58E-OI
.32E-01
.01E«00
.10E+00
.19E»00
.29E400
.41E+00
.53E«00
.6fcE*00
,80E»00
.95E400
>. 12E>00
».30E*00
>,50E+00
».71E*00
».95E*00
!.20E-»00
,47E»00
,77E»00
.09E»00
.45E»00
,83E»00
.24E>00
.69E+00
,18E»00
.71E*00
.28E»00
.91E»00
,58E»00
.32E»00
.01E»01
.10E»01
.19E»01
.29E+01
.41E«01
l.53E*01
L.bbE»01
3.00F»00
                           4.34E»00
                           S.1t>F»00
7.19E»00
9.85E*00
1.15E*01
1.34E+01
1.57E*01

2.12E«01
2.47E»01
2.83E»01
3.14E»01
3.40E»01
3.5»E»01
3.70E»01
3.7«E»01
3.80E»01
3.«8E»01
3.91E*01
3.94E*01
  99E»01
 ,04E*oi
 .07E*01
 .09E»OI
 .14E»01
 ,17E*01
 .32E«01
 .39E»01
 .48E»01
 ,58E*01
 .66E*01
 ,79E»01
 ,90E»01
5.02E*01
5.12E*01
5.22E»01
5.29E»01
5.3bE»01
5.43E*01
5.49E*01
5.54F.XI1
5.59E»01
                                              6.24E*00
                                              7.38F»OU
                                              8.69F«00
                                               . 19F»U1
                                               ,40E*Ot
                                               .64E»01
                                              2.24E»OI
                                              2.58E*OI
                                              2.95E»OI
                                              3.2fcE»01
                                              3.52E»01
                                              3.70E*01
                                              3.fl2E*01
                                              3.91E«U1
                                              3.971*01
                                              4.01E*U1
                                              4.07E«01
                                              4.09E+01
                                              4.12E*01
                                              a,15E*01
                                              4.18E+01
                                             4.23E+01
                                             4.25E»ot
                                             4.27E*OI
                                             a.3lE*oi
                                             0.3<»E*01
                                             0.3<>E»OJ
                                             a.53E*oi
                                             4.72E+01
                                             a.83E*UI
                                             o.9aE«ol
                                             5.0t>E + OI
                                             S.1HE»01
                                             5.d9E»01
                                             5.39fc»01
                                             5.66E»01
                                             S.71F*OI
                                             5.75E»OI
                                        CONFIf'tNCE
                                        IMI T
                                                                 S.O/t *UU
                                      9,'iOE + OO
                                      1 . IOE»01
                                      I .««»E»01
                                      1.73E*OI
                                      3.57E*01
                                      3.66E+01
                                      3.75E»01
                                      3.«IE*01
                                      3.83t +01
                                      3.86E+OI
                                      3.89E*OI
                                                                 3.9iE*01
                                      3.98t»01
                                      4.01E»0»
                                     «.U7E*01
                                     4. I2E*UI
                                     4.I8E*OI
                                     0.31E»OJ
                                     U.OUF.+01
                                     5.37F.»OI

-------
    53 '      I.80E*01         5.63F+01           5.79E*<>1            5.««bE + U1
    5a       I.95E*01         5.hfiE»UI           5.«.«.»<'!            b.«^f»ui
    55       2.12E+01         5.69E»5       «.83E*OI         5.B5E«OJ           b.03E«01            S.bHE*01
    66       5.24E»Ol         5.87E*01           b.OME»01            ^.b4E»U1
    67       5.69E + OI         5.8BF.*01           b.05F»(»l            5.70E*Ot
    6S       b.!6E*01         5.89E«OI           b.0bf»01            5./!E»Ot
    69       6.7IE+01         5.89E»01           6.07E«OI            5.7i£»OI
    70       7.28E + 01         5.90E»OI           f..07F*01            5.7JE«U1
    71       7.91E»01         5.9IE*OI           b.O«E»01            5.ME»OI
    72       8.5BE«01         5.91E»01           b.O^E»01            5.7«E»«1
    73       9.32E*01         5.9?F. + 01           b.O'iE + Ol            5.7SE*01
OJ

-------
      ASAHCO AVERAGE PARTICLE  SIZE  DISTRIBUTION
WHO* 1.00 GM/CC
INTERVAL   DIAMETER    RECORDS EXCLUDED FROM MEAN
                      CUMILAT1VF  MASS LONCt N !H A T ION
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                           2
                           2
                           2
                           2
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                           6
                           6
                           6
                           6
                          NONE
                          NONE
                          NONE
                           4
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                           4
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
                          NONE
1 <
2 <
3 i
4 2
5
h
r
8
9
10
11
12
13
14
15
16
17
ie
19
20
21
22
23
24
25
26
27 i
28 i
29 i
30 <
31 i
32 2
33 2
34 2
35 <
36 t
37 <
38 «
39 •
40 «
41 <
42 1
43 1
44 1
45 «
46
47
08
49
50
51
52
53
•.50E-01
J.T1E-01
5.95E-01
I.20E-01
.47E-OI
.77E-01
.09E-01
.45E-01
.83E-01
.24E-01
.69E-01
.18E-01
.71E-01
.28E-OJ
.91E-01
.58E-01
.32E-01
,01E»00
,10E»00
,I9E*00
,29E»00
,41E»00
.53E»00
«66E^OO
.80E»00
,95E»00
>.12E»00
».30E»00
».50E»00
>.71E»00
>.95E»00
J.20E*00
J.47E*00
I.77E»00
I.09E«00
I.45E*00
I.83E»00
>.24E»00
>.69E»00
>.18E+00
».71E»00
r.28E*00
p .91E+00
I.58E«00
>.32E»00
.01E»OI
,IOE*01
,19E»Ot
.29E»01
.41E»01
.53E»01
.66E»01
,80F.*01

-------
54
55
56
57
58
59
60
61
62
63
60
65
66
67
68
69
70
71
72
73
1.95E«01
2.12t»01
2.30E«01
2.50E»01
2.71E+01
2.95E*U1
3.20E+01
3.47E«01
3.77E*01
«.09E»01
fl.«5E»01
fl.83E»01
5.20E»01
5.69E»01
6.J6E»01
6.7JE+01
7.28E»01
7.91E»01
8.58E»01
9.32E»01
NONE
NONE
6
NONE
NONE

-------
   RHOi
 ASARCO AVERAGE
1.00 6H/CC
M
OJ
rERVAL DIAMETER MASS CONCENTR
(MICRONS)
1 2.50E-OI
2 2.7IE-01
3 2.95E-01
4
5
6
7
0
9
10
11
12
13
14
15
16
17
16
19
20
21
22
23
24
25
26
.20E-01
.47E-01
.77E-01
.09E-01
.45E-01
.83E-01
.24E-01
.69E-01
.18E-OI
.71E-01
.28E-01
.91E-01
.58E-01
.32E-01
,01E*00
,10E*00
.19E»00
,29E*00
.41E»00
.53E»00
.6bE»00
,80E»00
,95E*00
27 2.12E+00
28 2.30E+00
29 2.50E»00
30 2.71E+00
31 2.95E*00
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
.20E»00
.«7E»00
.77E*00
,09E»00
.45E+00
.83E»00
,24E»00
.69E*00
.IBEtOO
.71E+00
.28E«00
,91E»00
,58E*OU
,32E*00
.01E*OI
47 1.IOE*01
48 1.I9E+01
49 1.29E«01
50 l.aiE^OI
SI I.53E+OI
52 l.bfcE+OI
S3 I.80E»U1
(PERCENT )
4.2«E»00
5.24E»00
b . 3 3F *0 0
7 . 5WE * U 0
9.01E+00
1 ,07E»01
1 .25E + 01
1.47E*01
1.72E*01
2.01E*OI
2.34E+01
2.73E*01
3.19E*01
3.70E«01
4.30E«01
4.94E*(M
5.4BE»01
5.94E*01
6.25E»01
6.45E»01
6.60E+01
b.7IE+01
b.7flE*01
b.83E»01
6.87E*01
6.92E+OI
b.96E»01
7.01E»01
7.06E»01
7.10E*U1
7. 14E+OI
7.18E»01
7.23E»01
7.28E«01
7.35E»01
7.43E*01
7.54E*01
7.67E»01
7.82E»01
7.99E»01
8.16E»01
8.37E*01
8.56E*01
8.7bE*OI
8.94E*OI
. 1?F»0 1
,24E»0 1
,3SE»01
,47E»01
.SHE »oi
9,h7E»01
9.75E+01
Q.B?F +0 1
PARTICLE SIZE  D1STHIHUTION

  MEAN CUMULATIVE    UPPER CONFIDENCE
                  UN       LIMI I
                        (PEWCENT)
                                                  b.3'*E»00
                                                  7.b8E*00
                                                  9.1
                                         1.52E«01
                                         1.78E«dl
                                         2.08E+OI
                                                  3.35E«»1
                                                  3.90E*01
                                         5.14E»01
                                         5,b9E»01
                                         b. I4E«01
                                         6.1bE*01
                                         6.67F»01
                                         b.83E»01
                                         6.93E»01
                                         7.01E*OI
                                         7.0bE»01
                                         7.10E»01
                                                  7.20E*U1
                                                  7.25E»01
                                                  7.29E»U1
                                                  7.33f*01
                                                  7.36E*01
                                         B.83E»OI
                                         9.03F»01
                                         9.23F«01
                                         9.41E*01
                                                   .46E«OI
                                                   .52E»01
                                                   ,5«F»0|
                                                   ,bbt»OI
                                                   ,77E»01
                                                  7.91E»0|
                                                  8.07F»01
                                                  o.blEfdl
                                                  9.77F»OI
                                                  9.87E»OI
                                                  9.97F.*OJ
                                                                        CDNFlOtNCE
                                                                       LIMIT
                                                                      5.21E««IO
                                                             7 . U 71» U 0
                                                                   Milt
                                                                       .bbE»01
                                                                      ?.bOE»0!
                                             4.10t»OJ
                                             4.7?E»OJ
                                             5.2HE+OI

                                             b.03E»Ot
                                             b.25E+01
                                             b.3HE»01
                                             b.a«t»01
                                                             6.«>aE»01
                                                             b.b9t+01
                                                             6.73E«OI
                                                             b.7HE»01
                                                             b.83E»Ot
                                                             6.H7E+U1
                                                             6.95E»01
                                                             b.99E*UI
                                                             7.05E»UI
                                                             7.tIE«01
                                                             7.I9E»0»
                                                             7.30E*OI
                                                             7.«3E»OI
                                                             7.58F«OI
                                                             7.?
-------
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
I.95E+01
2.30E»01
2.50E+01
                3.«?
                                                     .06E+0?
                                                     .06E*0^
                                                     ,ObE«Oc;
                                                        9.b/fc*
-------
U>
..00
           ASARCO AVERAGE
     RHO= 1.00 6M/CC
PARTICLE SIZE DISTRIBUTION

INTERVAL 1

1 i
2 i
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28 <
29 i
30 I
31 3
32 «
33 <
34 •
35 (
36 1
37 «!

>IAMET6R IH

J. 506-01
J. 956-01
.476-01
.096-01
.836-01
.696-01
.716-01
.916-01
.326-01
.106+00
.296+00
.53E+00
.806+00
.126+00
.506+00
.956+00
.476+00
.096+00
.836+00
.696+00
.716+00
.916+00
.326+00
.106+01
.296+01
.536+01
.806+01
». 126+01
'.506+01
!. 956+01
1.476+01
1.096+01
I.83E+01
i. 696 + 01
I.71E+01
.916+01
'.326+01
MEAN CHANGE
1 MASS CONCENTRATE
(MG/DNM3)
1.556+01
1.976+01
2.59E+OI
3.10E+01
1.18E+01
fc.lOE+01
8.216+01
1.146+02
8.426+01
3.986+01
2.126+01
9.506+00
7.626+00
8.126+00
6.34E+00
7.726+00
9.15E+00
1.196+01
2.05E+01
2.75E+01
3.166+01
3.296+01
3.05E+01
1.66E+01
1.92E+01
1.44E+01
1 .08E + 01
7.656+00
5.726+00
6.I9E+00
5.196+00
4.23E+00
3.53E+00
2.88E+00
2.40E+00
1.9HE+00
1.20E+00
STANDARD 1
IN DEVIAtlllN
(MG/DNM3)
i . isE-oa
1 .7 IE +00
«.?t.F*00
8.16E+00
1 . 3 7 fc + P 1
2.22F+01
3.5IE+01
3.23E+00
6.7BE-P1
2.25F+OI
1 .?2f +01
6.80F+PO
5.976*00
5.66F+00
6.68E+00
5.43E+00
3.75F+OU
2.0VE+00
9.02E+00
1.S8E+01
2.03E+P1
2.23E+P1
2.05E+01
7.60F.-01
8.00E+00
4.59E+PO
3.95E+00
5.02E+00
5.46E+00
6.09E+00
5.46E+00
4.7bE+00
4.0IE+00
3.26E+00
2.59F+00
1 .99F +00
1 . 32E+UO
JPPEW CUNF IDENCE
Ll^ir
(wr, /UNM3)
1 .55F»01
^.05E + t)l
^.79E +01
3.79E+01
S.I 3E+01
7.1bE+OI
o.e<»E + (M
1 . 1 76 + "2
8.476+01
5.05E+01
2. 7 OF. + 01
.276+01
.I8E+01
.21E+01
".53E+00
.03E+H1
.096+01
.29E+OI
2.08E+01
3.SOE+OI
a. 136 + 01
1.366+01
0.03F. + 01
1.716+01
2.306+U1
1 ,b5E«01
1 .27E + 01
l.OOE+01
fl. J3E + 00
1 .ObF + OI
9.026+00
7.58E+PO
h.34E+00
S. 176 + 00
0.226+00
3.38E+00
1 .836 + OU
                                                                                       <  CONFintNCb
                                                                                       L IMIT
                                                                                       3.01E+OI
                                                                                       S.0«t+01
                                                                                       6.b3t+oi
                                                                                       a. lat + uo
                                                                                       3.156 + 00
                                                                                       5.13t+00
                                                                                       1 .096 + 01
                                                                                       1.626+01
                                                            2.196+01
                                                            2.236+01
                                                            
-------
      ASARCO AVERAGE PARTICLE SUE DISTRIBUTION
RHO= t.OO GM/CC
INTERVAL   DIAMETER    RECORDS fiXCLUOtO FROM MEAN
                      CH»NGF IN MASS
1
2
3
4
5
6
7
e
9
10
II
12
13
14
15
16
17
IS
19
to 20
1 21
I-- 22
to 23
vo jq
25
26
27
28
29
30
31
32
33
34
35
36
37
2.50E-OI
2.9SE-01
3.47E-01
4.09E-0!
4.83E-01
5.69E-01
6.7IE-01
7.91E-01
9.32E-01
I.10E»00
1.29£«00
I.53E»00
1.80E+00
2.12E«00
2.50E»00
2.95E*00
3.47E«00
4.09E*00
4.83E»OU
5.69E»00
6.7IE+00
7.91E*00
9.32E»00
1.10E*01
1.29E*01
1.53E»01
1.80E»01
2.12E»01
2.50E«01
2.95E»01
3.47E«01
«.09E»01
«.83E*01
5.69E»OJ
6.7IE«01
7.91E*01
9.32E*01
4
NONE
NONF.
NONE
NONE
NONE
NONE
2
2
NONE
NONE
NONE
f)
6
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
4
NONE
NONE
NONE
NONE
NONE







NONE

-------
      ASARCO AVERAGE
RHO* 1.00 GM/CC

INTERVAL   DIAMETER
PARTICLE SIZE OISTR1HUTION

       MEAN CHANGE
 IN NUMPEH CDNCENTHAIION
        (NII/DNM3)




















•P
1
H
•U
0













1
2
3
•
5
b
7
8
9
10
11
li
13
14
IS
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
2.50E-01
2.95E-01
3.47E-01
4.09E-01
4.83E-01
5.69E-01
6.7IE-01
7.91E-01
9.32E-01
1.10E»00
1.29E»00
1.53E*00
I.80E+00
2.12E+00
2.SOE+00
2.95£*00
3.47E»00
4.09E+00
4.83E»00
5.69E*00
6.71E+00
T.91E»00
9.32E»00
I.10E+OI
1.21E*01
1.53E»01
1.80E»01
2.12E«01
2.50E»01
2.95E»01
3.47E*01
4.09E+01
4.83E»01
5.69E*01
6.71E»Ol
7.91E*OI
9.32E»01
J.18E+1?
9.U7E»U
7.60E*1I
5.20E»11
                              5.73E*10
                              1 .86E + 10
                              5.10E»09
                              2.50E»09
                              1 ,63E»09
                              7.75E*08
                              5.76E*08
3.3tE»08
                              ?.OOE»08
                              1.27E*08
                              7.20E»07
                              2.39E*U7
                              1 .69E*07
                              7.71E*Ob
                              3.54E«U6
7.UOE»05
4.62E»OS
1.18E»05
5.99E»Ofl
STANDANU
UEVIATI UN
(NO/ONM3)
                             I .bOE«09

                             I .07F*10
                             J.b^E»09
                             I .9bE*09
                    8.17E«08
                    O.Obt+08
                    1.71E*08
                    1.53E«08
                    1.29E*08
                    8.61E»07
                    4.fl3E»07
                    1 ,(»9E*06
                    1.01F*06
                                                  1.32F»05
                                                  b.8oE»04
2.H3E»03
                                                  7.6HF»U3
                                                  3.1IE»03
UPPER CDNFIDFNCE
     LIMIT
   (NO/UNM3)
                                                                I.27E«12
                                                                1 .ObE*
                                                                H . 7 1 F »
                                  a.5IF.»
                                  ?.OOE«
                                  7.28F.»
                                  ?.37E«
                                  3.87E»09
                                           l.lbE»09
                                           7.70E»08
                                           a.98E»06
                                           3.58E+OH
                                  3.63E»08
                                           I.68E+OW
                                           9.50E»07
                                           2.47F. *07
                                           2.02E«07
                                           8.88E»Ob
                                  4.1 1E*05
                                           2.b7E»0«
                                           1 ,31F»Oa
                                           a.38F+Oj
                                                 LHWFH  CHfjF JiltNCK
                                                      LIMIT
                                                               1 ,41E»lr»
                                                               I.WMK* ?
                                                                                    a.iat*
                                                                                    «.33^+
                                                                                    1.9BE*
                                   3.3»>t:
                                   1.1 2t
                                   B.29b*0«
                                                                                    3.03t»OH
                                                                                    2.75E*l)H
                                   8.62E*07
                                   4.6Vt»07
                                                      1.35E»07
                                                                                    l.05E*Ob
                                                                                    3.81E»OS
                                                     b,15E»U3
                                                     3.bHt«OJ

-------
      A3ARCO  AVERAGE  PARTICLE SUE D 1 ST H IHUT ION
RHO= 1.00 GM/CC
INTERVAL   DIAMETER     RECORDS EXCLUDED  FROM  MEAN
                      CHANGE IN NIIMHEH  CONC fcNT H A T I (IN
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
ia
19
20
21
22
23
24
25
26
27
26
29
30
31
32
33
34
35
36
37
2.50E-01
2.95E-01
3.47E-01
4.09E-01
«.83E-01
5.69E-01
6.7IE-01
7.9IE-01
9.32E-01
I.IOE'OO
1.29E+00
1.53E»00
1.80E»OU
2.12E»00
2.50E»00
2.9SE+00
3.47E»00
4.09E»00
«.83E»00
S.69E»00
&.7tE«00
7.91E»00
9.32E»00
1.IOE+OI
1.29E»01
1.53E»01
1.80E»01
2. 12E»01
2.50E«OI
2.95E»01
3.47E»Ol
«.09E»01
4.83E*01
5.69E»01
fc.71E»01
7.9IE*01
9.32E»01
4
NONE
NONE
NONE
NONE
NONE
NONE
?
2
NONE
NONE
NONE
6
6
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
4
NONE
NONE
NONE
NONE
NONE






a
NONE

-------
   END OF PROGRAM
   JEOJ
   CPU sec. s  6?.   ELAPSED WIN. = «».  FHI, M*K it,  I«»JM.
NJ

-------
IjOB RPT,P3«909.PET,STACK
PRIORITY * E3| INPRI = 8: TIME = UNLIMITED SECONDS
JOB NUMBER s «JZ«
TUf, FE8 ii, 1983. 10:39 AM
MP3000 / MPE IV C.OO.B4
•FILE FTN10*CIDR01DA,OLO
IRUN STKTSTPG.STACK
  OJ

-------
                                                        FIELD  DATA
PLANT
SAMPLING LOCATION
SAMPLE TVPF
OPERATOR
AMBIENT TEMP. (PEG. F)
BAP. PRESS. (IN. MG)
STATIC PRESS. (IN. H?0)
FILTER NUMPER(S)
STACK INSIDE DIM. (TNI
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
METER CALIB. FACTOR













READ a RECORD O*TA EVERY
ASARCO TACOMA
NO 4 ser FX
PART 3I7E-CHG
on
55.
29.55
«**•«
MARK MI
60.00 .00
.80

.000 CFM a .0 IN.HG
1.001
5.0 MINUTtS
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME TTMF
NO. (MIN.) (24-HR
n nrif )
C l*'l* ** f
> INIT 0 1256
' 5.0 0
£ 8.8 1245
*». 10.0 12^0
15.0 0
15.6 1259
16.1 1302
19.4 1309
20. • 1315
21.1 13*9
22.0 13«2
24.9 1347
24.9 1617
30.0 0
31.7 1*23
32.5 815
36.9 8«1
39.0 845
READING HEAD DIFFERENTIAL
(CU.

145
140
150
151
154
155
155
15T
158
154
159
161
161
164
165
165
168
169
FT.) (IN.H20) (IN.M?0)
OFSIHFO ACTUAL
.035
.350
.760
.589
.800
.158
.367
.512
.101
.537
.153
.035
.875
.420
.477,
.918
.722
.974
.150
.200
.100
.200
.150
.100
.100
.too
.000
.000
.000
.850
.800
.100
.150
.800
.150
.10
.30
.10
.30
.10
.30
.30
.10
.10
.10
.10
.10
.10
.10
.10
.10
.10
.30
.30
.10
.10
.30
.30
.30
.30
.10
.30
.30
.30
.30
.10
.10
.30
.10


DATE
RUN NUMBER




PROBE LFNGTH ft TYPE

NOZZLE
: I.D.

ASSUMED MOISTURE




SAMPLE BOX
METER BOX
METER HEAU

NIJMHEP
NUMBER
OIFF.





PROBE HEATFR SETTING




STACK
TEMP
(DEG.F)


86.
82.
85.
90.
86.
84.
92.
99.
85.
88.
103.
7".
79.
84.
86.
68.
73.
HEATFR nox



DRY GAS METER
TFMP
(DFG.F)
INLFT OUTLFT

65. 63.
66. 63.
66. 63.
67. 63.
6«. 64.
66. 63.
69. 65.
69. 65.
66. 63.
69. 66.
69. 66.
68. 66.
68. 66.
67. 65.
65. 61.
57. 55.
59. 56.
SETTING



PUMP
VACUUM
(IN.HG)


2.2
2.3
2.3
2.1
2.3
2.3
2.6
2.5
2.6
2.6
2.6
2.7
2.7
2.7
2.7
2.8
2.8




01/18/83
PSMC-I
6* STEEL
.111
1.0

FB7
1.71

0.
0.

















IMPACTOR IMPINGER
TEMP TEMP
(DEC.


86
82
85
90
86
84
92
99
85
88
103
79
79
84
86
68
73
F) (DEC.


53
53
53
53
54
54
54
54
54
54
55
55
56
56
56
56
57
F)


*
•
•
•
•
•
•
•
•
•
•
•
•
*
•
•
•
TOTALS
AVERAGE
39.0
24.939
                                       1.30
                              1.10
85,
66.
63.
2.5
                       85.
55.
          PERCENT ISOKTNFTTC
                             104.1

-------
       PL«NT * CITY
       SAMPLING LOCATION
       DATE
       RUN NUMBER
       OPERATOR
       STACK TEMP.
       PAR.PRF3S.dM. H6)
       STACK PRESS.(IN. HC)
       NOZZLEH.D.UN.)
       METER HEAD DIFF.
    CALC. MASS LOADING a 6.6169F.-02 GR/ACF
   IMPACTOR STA6E
   STAGE INDEX NUMBER
   050 (MICROMETERS)
   MASS (MILLIGRAMS)
   M6/OSCM/3TAGE
•SARCO TACOMA
NO a SEC EX
01/18/83
 PSMC-1
no
  85.2F    29.fee
 29.53
 28. 7Z
 .131
1.300
              SI
              1
            8.84
           28.80
in  CUM. PERCENT OF MASS SMALLER THAN 050  75.15
          7
          8
          1
         67
 7.1903E-02  GR/03CF
 32         S3
 2          ^
,80       5.03
,80       6.50
,25F»01   «
.56      61.95
TMPACTOR FLOWRATE(ACFM)
AT IMPACTQB CONDITIONS
TMPACTDR TEMP. 85. 2F
PARTICLE OFNJ»ITY(GM/CC)
MAX. PARTICLE DIAM.MICHOS
PAS COMPnsITION(PERCFNT) : C02
CO
N2
02
H20
SAMPLING Ol'H»TTON(MJN.)
CF 1.5I02E*02 MG/ACM
34 35 36 37
0567
3.21 1.74 .83 .58
3.50 5.30 13.00 19.40
.693
29. 6C
1.00
100.0
.00
.00
99.00
.00
1.00
39.00
1.
38
8
.31
17.60








6454E»02 M6/OSCM
FILTER
9

12.60
   CUM. (MS/ACM) SMALLER THAN D50
   CUM. (N6/OSCM) SMALLER TM«N 050
   CUM. (GR/ACF) SMALLER THAN 050
   CUM. (GR/OSCF) SMALLER THAN 050
   8EO. MEAN DIA. (MICROMFT*R3)
   DM/OLOGD (MG/DSCM)
   ON/DLOGO (NO. PARTICLE1/n3CM)
1.14E*02  1
                                                              1.«OF»01  2.7aF»01  2.49E»01
                                                             a?. 80     26.06      10.87
                                                              6.«8F»01  3.95E*01  1.65E*01
                                                              7.0flF»01  4.?9E»01  1.79E*01
I.78E*OI
            4.97E-02  4
            5.40E-02  4
            ?.97F»01  8
            3.87E*01  ?
            ?.81?+06  7
                  0.95F»00  1
                 58.93     50.36
02E«02  9.38E»01  8.92F*01  *
11F*02  1.02E+02  9.70F»01  f
07F-02  0.10E-02  3.90E-02  3.60E-02  2.83F-02  I.72E-02  7.19E-OS
86E-02  4.05E-02  0.20E-02  3.91E-02  3.08E-02  1.87E-02  7.82E-03
30F*00  6,?6F»00  0.02F.»00  ?.3fcF*00  1.20f»00  6.95F-01  fl.?5F-01  Z.I9E-OI
29E»02  fl.«aF+01  2.5aF»01  2.82E»01  5.91F»01  t.77E»02  «».12F»01  5.92E»OI
                  7.47F»08  4.07F+09  6.09F»10  1.01E*12  2.28^*12
 STANDARD CONDITIONS ARE ?0 D^GC AND 760MM HG.
 AERODYNAMIC OIAMETFRS ARF CAICOLATF.D HFMF ACCOROINR TO THE TASK RROUP ON L»NP, DYNAMICS.

-------
                                      T»COM»

                               NO  a  9F.c  EX
    PLANT « CITY

    SAMPLING LOCATION

    DATE

    RUN NUMBFR

    OPERATOR

    STACK TEMP.



    STACK PRESS.(IN. Hfi)

    N07ZLEII.D.(TN.)

    METER HEAD OtFF.

 CALC. MAS9 LOADINR • 6.M69F-02 GR/ACF

TMPACTOR STAGE

STAGE INDEX NUMBER

D50 (MICROMETERS)

MASS (MILLIGRAMS)

MG/OSCM/STAGE
 PSMC-1

no

  «5.2F

 29.53

 28.72

 .131

1.300
                             TMPACTnH Fl OWRMF (*CFM)
                             AT 1MP«CTOB CUNDIlTflNb
                             TMPACTOR TFMP.

                             PARTTCI.f DFNSITV (G*/tC)

                             MAX.P»RTTCLE DtAM.MICROS

                             r.AS
                                                                                                          . ?F
                                          29. 6C
                                                         CO?

                                                         CO

                                                         N?

                                                         02

                                                         H20
                                                                       SAMPLING DURATTON(MIN.)
   91

   1

 8.92

28.80
                                                       7.1903C-02 GP./f>SCF

                                                       92        S3        SO

                                                       ?         1         4

                                                      ,88      5.12      3.30

                                                      ,80      6.50      3.50
  1.00

100.0

   .00

   .00

 99.00

   .00

  1.00

  39.00

     I .*454E*02 MG/PSCM

     98     FILTER

     8         9

    .39

  17.60     12.60
cn
   CUM. PERCENT OF M«9S  SMALLER  TM»N  050   75.15

   CUM. (MG/ACM) SMALLER THAN  050

   CUM. (M6/OSCM) SMALLER THAN 050

   CUM. (GR/ACF) SMALLER THAN  050

   CUM. (GR/OSCF) SMALLER THAN 050

   6EO. MEAN  DIA.  (MICROMETFR*)

   DM/OL060  (MG/OSCM)

   ON/OLOGD  (NO. PARTICLE9/DSCM)
                                                        l.5io?E«o2  MG/ACM

                                                      S5         S6        97

                                                      567

                      7.88      5.12      3.30       1.82        .91        .66

                      8.80      6.50      3.50       5.30      13.40     19.40

            4.07E»01  1.25E»01  9.20E*00  4.95E*00   7.50E*00   1.90E*01   2.74E»01   2.49E+01

                     67.56     61.95     58.93     54.36      42.80     26.06      10.87

            1.14E+02  1.02E+02  9.38E*01  8.92F»01   8.23E^01   6.48E«01   3.95E«01   I.65E+01

            1.24E«>02  1.I1F»02  1.02E«02  9.70E*01   8.94E+01   7.01E»01   4.29E»OI   1.79E*01

            4.97E-02  4.47E-02  4.10E-02  3.90E-02   3.60E-02   2.B3E-02   1.72E-02   7.19E-03

            5.40E-02  4.86E-02  4.45E-02  4.24E-02   3.91E-02   3.08E-02   1.87E-02   7.D2E-03

            2.99E*01  8.39E*00  6.35F.»00  4.11E*00   2.45E»00   1.29E»00   7.77E-01   5.09E-01  2.77E-01

            3.88E«01  2.31E+02  4.90E»01  2.59F+01   2.91E»01   6.31E»01   1.97E«02   I.09E»02  5.92E*01

            2.78E»06  7.q8E+Oe  3.66E + 08  7.15F.+08   3.78E»09   5.62E«10   8.02E»11   1.58EM2  5.34E»12
 STANDARD  CONDITIONS  ARE  20  DEGC  AND  760MM  HG.

 AERODYNAMIC  DIAMETERS  ARE CALCULATED HERE  ACCORDING TO MERCER.

-------
               IMPACTOR FIELD DAT*  TABULATION
    PLANT-NAME  AND ADDRESS                TEST  TEAM LEADER
    A9ARCO  TACOMA                         DO
    TEST PSMC-I
                NO « SEC EX
 I
**
ENGLISH UNITS
TEST
TB
TF
TT
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
P1TOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
01/18/83
1236
845
39
1


1
.0
.001
.131 IN
.84
.30 IN-H20
METRIC UNITS
01
1236
845
39.
1.
3.
•
33.
/IB/83
0
001
3
84
0


MM

MM-l
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*
VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*
BMO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY GAS
MD        MOLECULAR MT-ORY STACK GAS
NWS       MOLECULAR NT-STACK GAS
PB        BAROMETRIC PRESSURE
PSI       STATIC PRES OF STACK GAS
PS        STACK PRES, ABS.
TS        AVERAGE STACK TEMP
IP        GAS SAMPLED AT
          STACK CONDITIONS
AS        STACK AREA
  24.939 CU-FT

  64.6   F
  24.876 SCF

    .251 SCF

   1.00
    .990
  28.73

  28.62
  29.53  IN-HG
 -11.00  IN-H20

  28.72  IN-HG

  85.    F
  27.03  ACF

2827.   SO-IN
    .706 CU-M

  18.1    C
    .704 SCM

    .007 SCM

   1.00
    .990
  28.73

  28.62
 750.06  MM-HG
•279.40  MM-HIO

 729.52  MM-HG
  30.     C
    .77  ACM

   1.824 SQ-M

-------
ISO       PERCENT ISOKINETIC

MT        TOTAL MASS OF PARTICLES

PD        PARTICLE DENSITY

   •  68 OEG F,  29.9Z IN.HG.
M
.(*
00
104.1


  1.789 Gk


   .06  GR/CI
100.t


I 15.900 MG


  1.00  GM/CC

-------
                 IMPACTOR  RESULTS  AND  EXAMPLE  CALCULATIONS
         PLANT-NAME  AND  CITY
         A3ARCO  TACOMA
         TEST  DATE   01/18/83
       TEST TEAM LEADER
       DO
     NUN NO

     PSMC-I
SAMPLE LOCATION
NU « SEC IX
       CALC.  MASS LOADING
M
*k
VO
TOTAL MASS OF PARTICLES UIVIDED BY A VOLUME. UNITS GIVEN  ANE GRAINS  PEK
ACTUAL* CUBIC FOOT(GH/ACF),GRAINS PEN U»Y STANDARD** CUBIC FOOT(GH/ObCF ) ,
MILLIGRAMS PER ACTUAL CUBIC MEUMMG/AC") AND MILLIGRAMS  PEW OKY  SUNOAHD
CUBIC MFTER(MG/OSCM.)
           EXAMPLE CALCULATIONS


                CML(6R/ACM  * MT(6H)  /  IF(ACF)


                        CML  =             1.789  /      27.031  =


               CML(GR/03CF)  s MT(SR)  /  VMSTD(DSCF)


                        CML  *             1.789  /      20.876  =


                CML(M6/ACM)  s MT(MG)  /  IF(ACM)


                        CML  *           115.900  /        .765  =


               CML(M6/D3CM)  • MT(MG)  /  VMSTD(DSCM)


                        CML  =           115.900  /        .700  =
                                       RR/ACF
                                .0719  GH/DSCF
                             151.41A3  MG/ACM
                             164.S386  Mb/DSCM
      050  (MICROMETERS)
THE SIZE OF THE PARTICLES ON EACH STAGE ASSUMING A 50 PERCENT
COLLECTION EFFICIENCY DEFINITION
      MASS  (MILLIGRAMS)
THE MASS ON EACH STAGE COLLECTED
      M6/DSCM/STA6E



           EXAMPLE CALCULATIONS


                M6/D3CM/STAGEU)  *


                MG/OSCM/STAGE(1)  *


      CUM. PERCENT OF MASS
THE MASS LOADING FOR EACH STAGE. UNITS GIVEN ARE MILLIGRAMS
PER DRY STANDARD CUBIC METER FOR EACH STAGE(MG/DSCM/STAOt)
 MASS(I) / VMSTD(DSCM)


   28.80 /      .700 e
00.75
THE PERCENTAGE OF THE TOTAL MASS SAMPLED SMALLER

IN DIAMETER THAN THE CORRESPONDING DbO  INDICATED

FOR THAT STAGE
           EXAMPLE CALCULATIONS


                CUM S  (6) = MASS(7)  * MASS<8)  » MASS(9)


                                      MT  (MG)


                CUM X  (6) •      19.00 *      17.60  *


                                          115.90   (MG)
                     * 100  =



                    12.60
                          • 100  e  54.36

-------
         CUM.(MASS/VOLUME)
THE CUMULATIVE MASS LOADING OF PARTICLES  SMALLER  IN UIAMtTER
THAN THE CORRESPONDING ObO. MASS/VOLUMt UNITS  »HE  MR/AC",
MG/DSCM,GR/ACF,GK/I)SCF.
              EXAMPLE CALCULATIONS

                   CUM.(MGSACM) (5) « MASS(6) » MASS(7) + MASS(H)  * MAS3(9)

                                                  IFtACM)

                   CUM.(M6/ACM) f5) =     13.40 *      19.«0  »      17.60  «      Ji.bO

                                                        .77   (ACM)
                                                          82.31
I-1
Ui
O
         GEO.MEAN OIA.(MICROMETERS)
THE GEOMETRIC MEAN DIAMETER  IN MICROMETERS
FOR A PARTICULAR STAGE.
              EXAMPLE CALCULATION

                   CEO.MEAN DIA.(J) c 30RT( DSO(J) « D50(J-1))

                   GEO.MEAN OIA.(6) = SURT(      .91 *       i.
         OM/OL06D(M6/DSCM)
DM 1$ MG/09CM/STAGE(J) AND OLOGO  IS  LOG 10(050(J-l)  /
050(J)) WHERE J IS THE CORRESPONDING STAGE  NUMBER.
FOR STAGE 1 THE MAXIMUM PARTICLE  UIAMF.TEM  IS USED.
FOR STAGE 9 (BACKUP FILTER) THE 050  IS  ASSUMED  AS
.S • 050 OF STAGE 6.
              EXAMPLE CALCULATION

                   OM/OL060U) =   MG/DSCM/STAGEU)

                                  LOGC OSO(J-l) / D50(J))

                   OM/DL06D (3) =              9.80

                                  LOG(      7.66 /      5
                             49.01
         ON/OLOGD                      THE NUMBER OF PARTICLES PER  UNIT  VOLUME  FOR A STAGE.

              EXAMPLE CALCULATION

                   ON/DLOGO(J) >            OM/OLOGO(J)

                                   5.23599E-10 * PDlGM/CC)  * GEO.MEAN  DIA.(J)

                   ON/OLOGO (3) =               49.01

                                   5.235999E-10 •       1.00  •
                              .   s
                              6.55
                                         3b5M8240.00
    •   CALCULATED AT STACK CONDITIONS
    ••  CALCULATED AT STANDARD CONDITIONS
    66 OEG.F AND 29.92 INCHES OF HG (760 MMHG)

-------
FIELD  DATA
PLANT ASANCU TACOMA
SAMPLING LOCATION NO a SEC EX
SAMPLE TYPE PART SIZE-CHG
OPERATOR DU
AMBIENT TEMP.(OEG.F) 50.
BAR. PRESS. (IN. HG) 29.80
STATIC PRESS. (IN. H20) »»•••
FILTER NUMRER(S) MARK HI
STACK INSIDE DIM. (IN) 60.00 .00
P1TOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .000 CFM 9
METER CALIB. FACTOR 1.001
READ A RECORD DATA EVERY 5.0 MINUTES
TRAVERSE SAMPLE
POINT
NO.
TIME
(MIN.)
CLOCK GAS METER
TIME
(24-HR
f 1 f\f M %
READING
(CU.FT.)
VELOCITY
HEAD
(1N.H20)
0 IN.HG
DATE 01/19/63
WIIH NUMBER P3MC-2
PRUflE LENGTH ft TYPE b' STEEL
NI1Z7LE : t.U. .131
ASSUMED MOISTURE I .0
SAMPLE BOX NUMBER
MF.TEH BOX NUMBtH FH7
ME IF.H HEAD OIFF . | . M
PWUBE HEATER SETTING 0.
HEATER BOX SETTING 0.
ORIFICE PRESSURE
DIFFERENT
UN.H20)
IAL

STACK
TEMP
(OEG.F)
DESIHED ACTUAL
INIT

>
1
1— '
Ul
I— i



TOTALS
AVERAGE

0
5.0
8.7
9.5
10.6
16.0
18.3
19.0
22.3
22.3

PERCENT
936
0
944
1129
1135
0
1236
1317
1322


ISOKINETIC
170.131
173.400
175.814
176.263
176.915
180.420
181.873
162.256
184.365
14.234



.500
.500
.300
.900
.400
.300
.300
.200


101.8

.30
.30
.30
.30
.30
.30
.30
.30

1.30


.30
.30
.30
.30
.30
.30
.30
.30

1.30


76.
77.
77.
76.
77.
75.
77.
no.

77.

PHY GAS
TEMP
(»ER.
METER

F)
PUMP
VACUUM
(IN.HG)
IMPACTOR IMPINGEH
TEMP
(DEG.F)
TfcMP
(DEG.F)
INLET UUTLET

60.
62.
63.
63.
63.
65.
63.
hb.

63.


58.
59.
61.
61.
61.
61.
61.
63.

61.


2.3
2.3
«?.?
2.2
2.2
2.2
2.2
2.2

2.2


76.
77.
77.
76.
77.
75.
77.
60.

77.


42.
42.
42.
43.
43.
43.
44.
44.

43.


-------
      PLANT ft CITY
      SAMPLING LOCATION
      DATE
      RUN NUMBER
      OPERATOR
      STACK TEMP.
      BAR.PRESS.(IN. HG)
      STACK PRESS.(IN. H6)
      NOZZLESl.D.dN.)
      METER HEAD OIFF.
   CALC. MASS LOADING « 3.8713E-02 6R/ACF
  IMPACTOR STAGE
  STAGE INDEX NUMBER
  090 (MICROMETERS)    '                    0
ASARCO TACOMA
NO 4 SEC EX
01/19/83
 PSMC-2
DO
  76.9F    24.9C
 29.80
 28.99
 .131
1.300
                  IMPACTOH FLUWPATE(ACFM)
                  AI IMPACTOH CONDITIONS
                  IMPALIUR ItMP.
                  PAHT1CLE DENSITY(GM/CC)
                  MAX.PAkTICLE f)IAM. MICROS
                  GAS coMpusirioN(PEWtENt):
                  SAMPLING f)UHATIQN(MIN.)
 I MASS (MILLIGRAMS)
M
J^MG/OSCM/STAGE
  CUM. PERCENT OF MASS SMALLER THAN 050  74
  CUM. (MG/ACM)  SMALLER THAN 050
  CUM. (MG/PSCM) SMALLER THAN 050
  CUM. (GR/ACF)  SMALLER THAN 050
  CUM. (GR/OSCF) SMALLER THAN 050
  GEO. MEAN DIA. (MICROMETERS)
  OM/OLOGO (MG/OSCM)
  DN/OLOGO (NO.  PARTICLES/DSCM)
              SI
              I
             ,85
             ,60
             ,35E*01
             ,93
             ,64E*01
             ,04E*01
             .90E-02
             .08E-02
             ,97E*01
             ,23E»OI
              62E+06
  4.1036E-02 GK/OSCF
  S2        S3        Sa
  i         3         H
7.80      5.00      3.22
3.20      1.60      1.30
              .885
     76.9F    2a.9C
             1 .00
           1UO.O
CU2           .00
CO            .00
N2          99.00
02            .00
H20          1.00
             22.30
                9.3905E«01 MG/DSCM
                ss     FILTER
                8         9
               .31
              7.20      7.30
                                  8.fl589E«01 MG/ACM
                                 35        S6         37
                                 567
                               1.74        .83        .58
                               1.30      2.50      4.30
 7.82E«00  3.91E»00  3.lHt»00  3.1«E*00  b.ltt+00  1.05E»01   1.76E«01   1.78E»01
66.58     62.40     59.01     55.61     89.09      37.86      19.06
 5.90E*01  5.53E*01  5.23E*Ol  4.93E«01  4.35E*01  3.35E»Ol   1.69E»01
 6.25E«01  S.fl6E»01  5.54E«01  5.22E«01  4.61E«01  3.56E+01   1.79£*01
 2.58E-02  2.42E»02  2.28E-0?  2.15E-0?  1.90E-02  1.47t-02   7.38E-03
 2.73E-02  2.56E-02  2.42E-02  2.28E-02  2.01E-02  1.55E-02   7.82E-03
 8.31E*00  6.27E»00  4.03t»00  2.37E»00  1.21E+00  b.VBE-01   4.27E-01   2.21E-01
 l.fl«E*02  2.06E+OI  1.63t*01  1.I9E+OI  1.91E«01  6./9E*01   6.48E«OI   5.93E*01
 4.78E+08  1.59E»08  4.77E«08  1.72E*09  2.08t»10  3.82E+11   1.59E*12   1.05E«13
STANDARD CONOITIONS ARE 20 OEGC AND 760MM HG.
AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO THE TASK GROUP ON LUNG DYNAMICS.

-------
       PLANT ft CITY


       SAMPLING LOCATION


       DATE


       RUN NUMBER


       OPERATOR


       STACK TEMP.


       BAR.PRESS.(IN.  MS)


       STACK PRESS.(IN.  HG)


       NOZZLESI.D.UN.)


       METER HEAD DIFF.
       TACOHA


NO 4 SEC EX


01/19/83


 PSMC-2


00


  76.9F    24.9C


 29.80


 28.99


 .131


1.300
                            IMPACTUW FLUKRATE(ACFM)
                            AI IMPACTUK CONDITIONS
                            IMPACTUW TEMP.

                            PARMCLf DENSITY(GM/CC)

                            MAX.PAkTICLE D1AM.MICROS

                            GAS COMPOSITION(PERCtNT):
    CALC.  MASS  LOADING  •  3.87I3E-02 GR/ACF


   IMPACTOR  STAGE                            31

   STAGE  INDEX  NUMBER                        1

   090  (MICROMETERS)                       8.93
>
 I  MASS (MILLIGRAMS)                       9.60

"J  MG/DSCM/STAGE                           2.35E«Ol

   CUM. PERCENT OF  MASS SMALLER THAN D50  74.93
                            SAMPLING OURATIONCMIN.)

            4.1036E-02 GR/OSCF

            32        S3        SO

            234

          7.89      5.12      3.30

          3.20      l.bO      1.30
              .685


     76.9F    24.9C


             1.00


           100.0


Cl)2           .00


CO            .00


N?          99.00


02            .00


H20          1.00


             22.30


                9.3905E»01 MG/OSCM


                38     FILTER


                8         9


               .39


              7.20      7.30
   CUM.  (M6/ACM)  SMALLER  THAN 050


   CUM.  (MG/DSCM)  SMALLER  THAN 050


   CUM.  (GR/ACF)  SMALLER  THAN 050


   CUM.  (6R/DSCF)  SMALLER  THAN 050


   OEO.  MEAN  DIA.  (MICROMETERS)


   DM/DL060  (MG/DSCM)


   DN/DLOGO  (NO.  PARTICLES/OSCM)
6.64E«01

7.04E*01

2.90E-02


3.08E-02

2.99E*01

2.20E»01

1.60E»06
                                                       8.05R9E«01 MG/ACM


                                                      S5        36     .   37


                                                      5         6         7


                                                    1.82       .91        .66


                                                    1.30      2.50      4.30


                      7.«2E+00  3.9IE+00  3.1«E»UO  3.18E»00  fc.Ilt»00  1.05E*01   1.7bE*01   t.78E«01


                     66.58     62.40     59.01     55.61     49.09     37.86      19.06


                      5.90E»01  5.53E»01  5.23E»01  4.93E»01  4.35E»OI  3.35E*01   1.69E»01


                      6.25E + 01  5.86E»01  5.54E + OI  b.22E»01  4.6U«01  3.56E*01   1.79E*01


                      2.5HE-02  2.42E-02  2.28E-02  2.15E-02  I.90E-02  1.47E-02   7.38E-03


                      2.73E-02  2.56E-02  2.42b-02  2.28E-02  2.01E-02  1.5SE-02   7.82E-03


                      8.39E»00  6.35E*00  fl.llt»00  2.45E«00  1.29t»00  7.781-01   5.10E-01   2.77E-01


                      1.45E«02  2.08E»Oi  l.bht»01  1.23E»0«  2.03E«01  7.b5E»Ol   7.70E*01   5.93E»OI


                      4.69E»08  1.55E»08  4.5BE«08  1.60E»09  1.61E»10  3.06E+1!   1.11E»12   5.33E«12
 STANDARD  CONDITIONS  ARE 20 OEGC AND  760MM HG.

 AERODYNAMIC  DIAMETERS  ARE CALCULATED  HERE ACCORDING  TP  MERCER.

-------
           IMPACTOR FIELD DATA TABULATION

PLANT-NAME AND ADDRESS               TEST TEAM LEADER

A8ARCO TACOHA                         DU
TEST PSMC-2
NO « SEC EX


TEST DATE
TB
TF
TT
Y
ON
CP
PM

|VM
M
Oi
*\M
VMSTD
TIME-START
TIME -FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS

AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGL
ISH UNITS
01/19/83
936
1322
22
1


1

14


61
14


.3
.001
.131 IN
.84
.30 IN-H2U

.234 CU-FT


.9 F
.404 SCF
METRIC UNITS
01/19/83
936
1322
22
1
3

33




16



.3
.001
.3
.84
.0

.403


.6
.408




MM

MM-He!0

CU-M


C
SCM
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

MO        MOLECULAR NT-DRY STACK GAS

MMS       MOLECULAR NT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS

AS        STACK AREA
                             .145 SCF


                            1.00

                             .990

                           28.73

                           28.62

                           29.8(1  IN-HG

                          -11.00  IN-H20

                           28.99  IN-HG

                           77.    F

                           15.27  ACF


                         2827.   SO-IN
    .004 SCM


   1.00

    .990

  28.73

  28.62

 756.92  MM-HU

•279.40  MM-H^O

 736.38  MM-HG

  25.     C

    .43  ACM


   1.824 SO-M

-------
ISO       PERCENT ISOKINETIC


MT        TOTAL MASS OF PARTICLES


PO        PARTICLE DENSITY


   *  68 DEC f,  39.98 IN.HG.
 I
M
cn
lUt.8


   .591 GR


   .06  GR/CI
101 .R


 38.300 MG


  1.00  GM/CC

-------
                 IMPACTOR RESULTS AND EXAMPLE CALCULATIONS
         PLANT-NAME AND CITY
         ASARCO TACOMA
         TEST  DATE   01/19/83
                                TEST TEAM LEADER
                                DO
                             RUN NO
                             PSMC-«!
SAMPLE LUCATION
NO 4 SEC EX
       CALC.  MASS  LOADING
I
M
Ul
                         TOTAL MASS OF PARTICLES DIVIDED BY  A  VOLHMK.  UNITS GIVEN ARE GRAINS PER
                         ACTUAL* CUBIC FOOT(GR/ACF).GRAINS PF R  UHY  STANDARD** CUBIC FOOT(GR/DSCf),
                         MILLIGRAMS PtR ACTUAL CUBIC METER(MG/ACM)  AND MILLIGRAMS PER DRY SIANOARU
                         CUBIC METER(MG/DSCM.)
EXAMPLE CALCULATIONS

     CML(GRXACF) • MT(GR) / IF(ACF)

             CML »             .591 /      15.268 =

    CML(6R/DSCF) • MT(GR) / VMSTD(DSCF)

             CML *             .591 /      14.404 e

     CML(MG/ACM) • MT(MG) / IF(ACM)

             CML *           38.300 /       .43Z =

    CML(MG/OSCM) 3 MT(MG) / VMSTD(DSCM)

             CML 2           38.300 /       .408 =
                                                                     .0387  GR/ACF
                                                                     .0410  GH/DSCF
                                                                   88.5890  MG/ACM
                          93.9U4B  Mti/DSCM
       050  (MICROMETERS)
                         THE SIZE OF THE PARTICLES ON EACH STAGE  ASSUMING  A  50 PERCENT
                         COLLECTION EFFICIENCY DEFINITION
       MASS  (MILLIGRAMS)
                         THE MASS ON EACH STAGE COLLECTED
       Mt/DSCM/STACE
                         THE MASS LOADING FOR EACH STAGE. UNITS GIVEN  ARE  MILLIGRAMS
                         PER DRY STANDARD CUBIC METER FUR EACH STAGE(MG/OSCM/STAGE)
            EXAMPLE  CALCULATIONS

                 MG/DSCM/STAGE(1)  s    MASS(l)  / VMSTD(DSCM)
                 MG/08CM/STAGE(I)

       CUM.  PERCENT  OF  MASS
9.60 /
                                         .408
                         THE PERCENTAGE OF THE TOTAL MASS SAMPLED  SMALLER
                         IN DIAMETER THAN THE CORRESPONDING 050  INDICATED
                         FOR THAT STAGE
EXAMPLE CALCULATIONS

     CUM I (6) = MASS(7) » MASS(B) » MASS(9)

                           MT  (MG)

     CUM X (6) «      4.30 *      T.ao »      7.30

                               38.30   (MG)
                                                          • 100  =
                                                               * 100  s  55.61

-------
       CUM.(MASS/VOLUME)
THE CUMULATIVE MASS LOADING OF PARTICLES  SMALLER  IN  DIAMETER
THAN THE CORRESPONDING 050. MOSS/VOLUME UNITS  ARE  MG/ACM,
MG/DSCM,GR/ACF,GK/USCF.
            EXAMPLE CALCULATIONS

                 CUM.(M6/ACM)  (5) s MASS(6) « MASS(7)  »  MASS(8)  *  MAS3(9)

                                                IF(ACM)

                 CUM.(MS/ACM)  (5) a      2.50 »      a.30  »       7.20  «
                                    • ••••»•••**•••••••••••••«••••••••*••••••<
                                                     .43  (ACM)
                                         7.30
                                                          09.27
       CEO.MEAN OIA.(MICROMETERS)
THE GEOMETRIC MEAN DIAMETER  IN MICROMETE*S
FOR A PARTICULAR STAGE.
            EXAMPLE CALCULATION

                 GEO.MEAN OIA.(J) 9 SQRT( D50(J) * DSO(J-l))

                 6EO.MEAN OIA.(6) z SORT(       .91 *       1.82)
                                    1.29
I
H
Ul
       DM/DL06D(M6/D3CM)
DM IS M6/03CM/STAGE(J) AND OLUGD  13 L0610(050(J-l)
050(J» WHERE J IS THE CURRESPONOING  STAGE  NUMUEH.
FOR STAGE 1 THE MAXIMUM PARTICLE  PIAMF.1RR  IS  USED.
FOR STAGE 9 (BACKUP FILTER) THE 050 IS  ASSUMED  AS
.5 • 050 OF STAGE 8.
            EXAMPLE CALCULATION

                 OM/OLOGD(J) =   M6/03CM/STAGEU)

                                LOG( D50U-1) / 050(J))

                 OM/OLOGD (3) *              3.91

                                LOG(      7.89 /
                 --   r
                 5.12 )
                             20.80
       ON/OL06D                      THE NUMBER OF PARTICLES  PER  UNIT  VOLUME  FOR A STAGE.

            EXAMPLE CALCULATION

                 ON/OLOGO(J) •            DM/OLOGOU)

                                 5.23599E-10 • PD(GMXCC)  *  GEO.MEAN  OIA.(J)

                 ON/OL06D (3) •               20.64

                                 5.235999E-10 •       1.00  •
                              •    s
                              b.35
                                         155073312.00
  •   CALCULATED AT STACK CONDITIONS
  ••  CALCULATED AT STANDARD CONDITIONS
  68 DE6.F AND 29.92 INCHES OF HG  (760 MMHG)

-------
FIELD  DATA













PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
AMBIENT TEMP.(OES.F)
BAR. PRESS. (IN. H6)
STATIC PRESS. (IN. H20)
FILTER NUMBER(S)
STACK INSIDE DIM. (IN)
PITOT TUBE COEFF.
THERM. NO.
LEAKAGE
METER CALIB. FACTOR













READ ft RECORD DATA EVERY
ASARCO TACOMA
NO 4 SEC EX
PART SIZE-CHG
DO
55.
30.00
•9.00
MARK III
60.00 .00
.64

.000 CFM a .0 IN.HG
1.001
5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INIT
>
1
l_i
01
00












TOTALS
AVERAGE

TIME TIME
(MIN.) (84-HR
Pi fif" H 1
LLUI»n |
0 620
5.0 0
10.0 0
15.0 0
20.0 0
25.0 0
27. 9 846
26.5 656
29.1 912
29.7 920
30.3 946
31.3 950
S2.« 950
34.9 1000
36.6 1004
36.5 1114
40.6 1121
40.8

PERCENT I30KINETIC
READING HEAD DIFFERENTIAL
(CU.

164
187
190
193
196
199
201
201
201
202
202
203
203
205
206
207
208
24


FT.) (IN.H20) (1N.H20)
DESIRED ACTUAL
.435
.490
.480
.490
.500
.520
.229
.552
.852
.221
.506
.085
.722
.196
.363
.346
.707
.050
.000
.050
.900
.000
.050
.000
.000
.950
.950
.650
.900
.000
.900
.000
.850
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.14
.272
1.14 1.14
99.7


OATF.
KIIN NUMBER




HKOBE LENGTH A TYPE

NIJ/ZLE
: I. H.

ASSUMED MOISTURE




SAMPLE BUX
METEH BOX
ME TEH HE At)

NUMBER
NUMHEH
DIFF .





PROBE HEATER SETTING




STACK
TEMP
(DEG.F)


80.
96.
64.
84.
84.
85.
82.
83.
85.
83.
85.
94.
76.
73.
73.
73.

83.

HEATER BOX



DKY GAS METEH
TEMP
(UEG.F)
INLET OUTLET

57. 55.
5B. 55.
60. 55.
63. 56.
65. 56.
68. 57.
62. 58.
62. 56.
62. 58.
f>3. 6V.
63. 60.
63. 60.
63. 60.
63. 60.
62. 60.
62. f-0.

62. 58.

SETTING



PUMP
VACUUM
(IN.HG)


2.0
2.0
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2

2.2





01/20/83
PSMC-3
6* STEEL
.131
1.0

FB7
1.71

0.
0.



IMPACTOR IMP1NGER
TEMP TEMP
(DEG.


80
96
«4
84
84
85
62
83
65
83
65
94
76
73
73
73

63

F) (OEG.F)


42.
42.
42.
42.
43.
43.
44.
45.
45.
42.
42.
42.
42.
42.
42.
42.

43.


-------
(Ji
VO
                                               1C
    PLANT ft CITY
    SAMPLING LOCATION
    DATE
    RUN NUMBER
    OPERATOR
    STACK TEMP.
    BAR.PRESS.(IN. HG)
    STACK PRESS.(IN. HG)
    NOZZLEII.O.UN.)
    METER HEAD OIFF.
 CALC. MASS LOADING « 4.0451E-02 GR/ACF
IMPACTOR STAGE
STAGE INDEX NUMBER
DSQ (MICROMETERS)                        9.16
MASS (MILLIGRAMS)                       13.00
M6/DSCM/STA6E                           1.84E+01
CUM. PERCENT OF MASS SMALLER THAN 050  81.10
A9ARCO TACOMA
NO 4 SEC EX
01/20/83
 PSMC-3
00
  82.5F    28,
 30.00
 29.34
 .131
1.140
                                                                         IMPACTUH  FLOKUATt(ACFM)
                                                                         AT  IMPAClOfc  CONDITIONS
                                                                         IMPAttOH  TEMP.

                                                                         PARTICLE  DtNSITY
-------
      PLANT ft CITY

      SAMPLING LOCATION

      DATE

      RUN NUMBER

      OPERATOR

      STACK TEMP.

      BAR.PRESS.(IN. HG)

      STACK PRESS.(IN. HG)

      NOZZLEtl.O.dN.)

      METER HEAD DIFF.

   CALC. MASS LOADING » 4.0451E-02 GR/ACF

  IMPACTOR STA6E

  STAGE INDEX NUMBER

  050 (MICROMETERS)                        9,

  MASS (MILLIGRAMS)                       13,

O MG/DSCM/STA6E                           1,

  CUM. PERCENT OF MASS SMALLER THAN 050  81,
ASARCO TACUMA

NO 4 SEC EX

oi/20/83

 PSMC-3

00

  82. 5F    ?8

 30.00

 29.34

 .131

1.140
                                                                      IMPACTUH FLMWPAlt
                                                                      AT IMPACION CONDITIONS
                                                                      IMPACTOH TtMM.

                                                                      PARTICLE nEMSlTY(GM/CC)

                                                                      MAX.PAMriCLE 01AM.MICROS

                                                                      GAS COMPOSITIONfPEKCENl ) :
                                            1C
                                                                      SAMPLING DUHAT1UN(MIN.)
en
  CUM. (MB/ACM) SMALLER THAN 050

  CUM. (M6/DSCM) SMALLER THAN 050

  CUM. (GR/ACF) SMALLER THAN 050

  CUM. (GR/DSCF) SMALLER THAN 050

  CEO. MEAN OIA. (MICROMETERS)

  OM/DL06D (M6/DSCM)

  DN/DL060 (NO. PARTICLES/OSCM)
7

7

3

3

3.

1.

1.
              SI

              1

              24

              00

              84E»01

              10

              51E«01

              95E»01

              28E-02

              47E-02

              046*01

              78E*01
   4.2815E-02 GK/DSCF

   32        S3        84

   234

 8.17      5.30      3.42

 5.30      3.20      2.00

 7.52E*00  4.54E*00  <

73.40     68.75     65.84
                                                                                     9.?5b5F*01  MG/ACM
                                          55

                                          5

                                        1.89

                                        2.10

                                        2.9BE*00

                                       62.79     48.69
                                                                                              86

                                                                                              6

                                                                                              .95

                                                                                            9.70
              .643

     »2.5F    28.1C

             1.00

           100.0

C02           .00

CO            .00

N?          99.00

02            .00

H20          1.00

             40.80

                9.7976E*01 M6/DSCM

      87        88     FILTER

      789

     .69       .41

   10.80     10.50     12.20

    1.53E»01  1.49E+OI  1.73E+01

   32.99     17.73
                                                    6.79E»01  6.36E«01  6.09E+U1  5.81E«01  4.5IE«01   3.05E*01   1.64E+01

                                                    7.19E*01  6.74E+01  6.fl5E»01  6.15E*01  a.77E»OI   3.23E«01   1.74E*Ot

                                                    2.97E-02  2.78E-02  2.66E-02  2.54E-02  1.97E-02   1.33E-02   7.17E-03

                                                    3.14E-02  2.94E-02  2.82E-02  2.69E-U2  2.08E-02   1.41E-02   7.59E-03

                                                    8.69E*00  6.58E»00  4.25E+00  2.5QE*00  1.30t*00   fl.Ofct-01   5.28E-01   2.87E-01

                                                    1.40E+0?  2.42E*01  1.49t«OI  l.lbE+OI  4.58E>01   1.10E»02   6.54E»01   5.75E*01

                                                    4.06E408  1.62E*OA  3.69E*08  1.35E*09  3.67E*10   4.02E»11   8.47EMI   <
STANDARD CONDITIONS ARE 20 OE6C AND 760MM HG.

AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO MEP.CEH.

-------
           IMPACTOR FIELD DATA  TABULATION

PLANT-NAME AND ADDRESS               TEST TEAM LEADER

ASARCO TACOMA                         OU
TEST PSMC-3
      MO « SEC EX
ENGLISH UNITS
TEST
TB
TF
TT
V
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
01/20/83
820
1121
40
1


1
.8
.001
.131 IN
.84
.14 IN-H20
METRIC UNITS
01/20/83
820
1121
40
1
3

29
.8
.001
.3
.84
.0


MM

MM-I
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTO     VOLUME OP DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

MD        MOLECULAR NT-DRY STACK GAS

MNS       MOLECULAR NT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES* ABS.

T8        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
                                 24.272 CU-FT


                                 60.1   f

                                 24.799 SCF


                                   .250 SCF


                                  1.00

                                   .990

                                 28.73

                                 28.62

                                 30.00  IN-hG

                                 -9.00  IN-H2U

                                 29.34  IN-HG

                                 63.    F

                                 26.25  ACF
                         .687 CU-M


                       15.6   C

                         .702 SCM


                         .007 SCM


                        1.00

                         .990

                       28.73

                       28.62

                      762.00  MM-HU

                      •228.60  MM-H20

                      745.19  MM-HG

                       28.    C

                         .74  ACM
AS
STACK AREA
2827.   SO-IN
                                                                 1.824 SO-M

-------
  ISO       PERCENT ISOKINETIC

  NT        TOTAL MASS OF PARTICLES

  PO        PARTICLE DENSITY
*  68 OE6 F,
                         IN.HG.
I-1
01
                                         99.T


                                          1.062 GH


                                           .06  GH/C1
hH.800 MG


 1.00  liM/CC

-------
                 IMPACTOR RESULTS AND EXAMPLE  CALCULATIONS
M

CO
         PLANT-NAME  AND  CITY
         ASARCO TACOMA
         TEST  DATE   01/20/83
       CALC.  MASS  LOADING
       TEST TEAM LEADER
       DU
     HUN NO
     PSMC-3
SAMPLE LOCATION
NO H SEC EX
TOTAL MASS OF PART1CLES DIVIDED BY A VOLUME.  UNITS  GIVEN  AHE  GRAINS PEN
ACTUAL* CUBIC FOOT (GW/ACF),GHAINS PEN DRY  STANDARD*•  CUHIC  FOOT(GR/DSCF),
MILLIGRAMS PER ACTUAL CUBIC METER(MG/ACM)  AND  MILLIKHAMS  PER  DRY  STANDARD
CUBIC METER(MG/nSCM.)
            EXAMPLE  CALCULATIONS

                 CML(GR/ACF)  •  MT(6H)  /  IF(ACF)

                         CML  »             1.068  /      26.248 =

                CML(GR/D3CF)  *  MT(6R)  /  VMSTD(DSCF)

                         CML  *             1.063  /      24.799 3

                 CML(M6/ACM)  «  MT(MG)  /  IF(ACM)

                         CML  «            66.800  /        .743 =

                CML(M6/03CM)  c  MT(MG)  /  VMSTD(OSCM)

                         CML  9            68.600  /        .702 *
                                 .0409  GR/ACF
                                        GH/DSCF
                              92.56SU  MG/ACM
                              97.9757  MG/USCM
       050  (MICROMETERS)
THE SIZE OF THE PARTICLES ON EACH STAGE  ASSUMING  A  SO  PERCENT
COLLECTION EFFICIENCY DEFINITION
       MASS  (MILLIGRAMS)


       MC/OSCN/3TA6E


            EXAMPLE CALCULATIONS

                 MG/DSCM/3TAGEU)  =

                 M6/DSCM/STAGEU)  *

       CUM.  PERCENT OF  MASS
THE MASS ON EACH STAGE COLLECTED
THE MASS LOADING FOR EACH STAGE. UNITS GIVEN  ARE  MILLIGRAMS
PER DRY STANDARD CURIC METER FOR EACH STAGE(MG/OSCM/STAGE)
 MASS(l) / VMSTOIDSCM)

   13.00 /      .702 e
IB
THE PERCENTAGE OF THE TOTAL MASS SAMPLED  SMALLER
IN DIAMETER THAN THE CORRESPONDING 1)50  INDICATED
FOR THAT STAGE
            EXAMPLE  CALCULATIONS

                 CUM X  (6)  *  MASS(7)  »  MAS3(8)  *  MASS(9)

                                       MT  (MG)

                 CUM X  (6)  s      10.80  *      10.SO  »      12.20

                                           68.80   (MG)
                     • 1UO  =
                            100
        62.79

-------
     CUM.(MASS/VOLUME)             THE CUMULATIVE MASS LOADING UF PARTICLES SMALLER  IN  DIAMETER
                                   THAN THE CORRESPONDING 0*50. MASS/VULUME UNITS  ARE  MR/AC"*,
                                   MG/D3CM,GR/ACF,GH/DSCF.

          EXAMPLE CALCULATIONS

               CUM.(MG/ACM) (5) = MASS(6) «• MASS(7) » MASS(B) » MASS(9)

                                             IFIACM)

               CUM.(MGXACM) (5) c      9.70 »     JO.80 »     10.50 »      12.20
                                  .	    -       5b.i2
                                                   ,7
-------
                                              FttLU  DATA
PLANT ASARCU TACOMA
SAMPLING LOCATION NO 4 SEC EX
SAMPLE TYPE PART SIZE-CHG
OPERATOR 00
AMBIENT TEMP. (OEG.F) 55.
BAR. PRESS. (IN. HG) 30.00
STATIC PRESS. (IN. H20) -9.00
FILTER NUMBER(S) MARK III
STACK INSIDE DIM. (IN) 60.00 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a
METER CALIB. FACTOR 1.001
READ ft RECORD DATA EVERY 5.0 MINUTES
TRAVERSE
POINT
NO.

> INIT
I
f-1
Ul




SAMPLE
TIME
(MIN.)

0
11.2
12.9
15.3
15.8
20.0
23.0
23.7
CLOCK
TIME
(24-HR

1450
1501
1556
1611
1616
0
1816
1838
GAS METER
READING
(CU.FT.)

208.77!
215.588
216.572
216.010
216.271
220.900
222.692
223.036
VELOCITY
HEAD
(IN.H20)


3.800
3.800
3.900
3.600
3.700
3.700
3.600
0 IN.HG
ORIFICE PRESSURE
DIFFERENTIAL
(IN.H?U)
DESIRED ACTUAL

.14 .14
.14 .14
.14 .10
.14 .14
.14 .14
.14 .14
.14 .14
DATE 01/20/63
RUN NUMBER PSMt-4
PROBE LENGTH * TYPE 6* STEEL
NUZZLE : I.U. .131
ASSUMED MOISTURE i.u
SAMPLE RUX NUMBER
METER BOX NUMBER FB7
MFTER HF.AD DIFF . 1.71
PROBE HEATER SETTING 0.
HEATER BUX SETTING 0.
STACK
TEMP
(OEG.F)
DKY GAS METER
TEMP
(OEG.F


PUMP
VACUUM
(IN.HIi)
IMPACTUR IMPINGER
TEMP
(DEb.F)
TEMP
(OEG.F)
INLET OUTLET

83.
81.
73.
60.
64.
82.
61.

62.
65.
65.
65.
6b.
66.
65.

60.
63.
63.
63.
64.
64.
63.

2.1
2.1
2.0
2.1
2.2
2.2
2.1

83.
81.
73.
80.
84.
82.
81.

• 8.
48.
50.
51.
51.
53.
54.
TOTALS
AVERAGE
   23.7
14.267
                                          1.14
                              1.14
61
bb.
63.
2.1
                                                                                          at
                                                                               51.
PERCENT ISOKINETIC
           102.3

-------
a\
    PLANT ft CITY

    SAMPLING LOCATION

    DATE

    RUN NUMBER

    OPERATOR

    STACK TEMP.

    BAR.PRESS.(IN. HG)

    STACK PRESS.(IN. HG)

    NOZZLESI.D.UN.)

    METER HEAD DIFF.

 CALC. MASS LOADING « 5.4798E-02 GR/ACF

IMPACTOR STAGE

STAGE INDEX NUMBER

DSO (MICROMETERS)                        9

MASS (MILLIGRAMS)                       12

MG/DSCM/STAGE                           3

CUM. PERCENT OF MASS SMALLER THAN 050  76
                                ASARCO  TACUMA

                                NO 4 SEC EX

                                01/20/83

                                PSMC-4

                                DO

                                 80.6F    27.OC

                                30.00

                                29.34

                                .131

                                1.140
                           IMPACfUH FLUWHATE(ACFM)
                           Al  IMPAC1UH CONDITIONS
                           IMHACTUR TtMP.

                           PAKTICLE OEN3Iir(GM/CC)

                           MAX.PHHTICLE D1AM.MICROS

                           GAS CHMPUS1tION(PEHCENT)!
                           SAMPLING OURATION(MIN.)
   CUM. (MG/ACM) SMALLER THAN DSO

   CUM. (MG/OSCM) SMALLER THAN DSO

   CUM. (GR/ACF) SMALLER THAN DSO

   CUM. (GR/DSCF) SMALLER THAN DSO

   GEO. MEAN OIA. (MICROMETERS)

   DM/OLOCD (M6/DSCM)

   DN/OL060 (NO. PARTICLES/OSCM)
 SI

 1

,15

,70

,09E*01

,57

,60E»01

,01E*02

.20E-02
                                                       5.7794E-Oa GR/DSCF

                                                       32        S3         84

                                                       234

                                                     8.07      5.21      3.33

                                                     b.OO      11.40      4.40
              .bag

     BO.bF    27.OC

             1.00

           100.0

C02           .00

CO            .00

N2          «*9.00

U2            .00

H20          1.00

             23.70

                1.3225E»02  MG/OSCM

                SS     FILTER

                8         9

               .33

              4.50      4.40
,97E*01

,05E»06
                                   1.2540E+02  MG/ACM

                                 S5         S6         87

                                 b          6          7

                               1.80        .87        .61

                               3.80      3.00      4.00

 l.flfcE+01  2.77E+01  1.07E+01  9.24E+00  7.30t»00  9.73E»00  1.09E»01  1.07E«01

65.50     44.46     36.35     <>9.34     23.80      16.42       8.12

 8.21E+01  5.58E*U1  1.56E+OI  3.b8E*01  2.98E«01  2.06E»OI  l.U2E«01

 6.66t+01  5.8BE+01  4.»lt*01  3.8PE+01  3.156*01  2.17E*01  1.07E»01

 3.59E-02  2.44E-02  1.99E-02  1.61E-02  1.30E-0?  9.00E-03  4.45E-03

 3.791-02  2.57E-02  2.10E-02  1.7UE-02  1.38E-02  9.49E-03  «.69E-03

 A.59E+UU  6.aflE»00  4.1bt*00  2.45E>00  1.25E*00  7.25E-01  4.46E-01  2.31E-01

 2.68E«02  1.46E>02  5.50E*Ol  3.48E»Ol  2.28E*Ol  6.32E*Ol  «.07E*01  3.SSE«01

 6.08E»Od  1.02E+09  1.45E«U9  4.51E«09  2.24E+10  3.17E»11  8.80E«11  5.49E*12
 STANDARD CONDITIONS ARE 20 OE6C AND 760MM HG.

 AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO THE TASK GROUP UN LUNG DYNAMICS.

-------
                                         27.OC
    PLANT a CITY

    SAMPLING LOCATION

    DATE

    RUN NUMBER

    OPERATOR

    STACK TEMP.

    BAR.PRESS.(IN. HG)

    STACK PRESS.(IN. HG)

    NOZZLEU.D.dN.)

    METER HEAD DIFF.

 CALC. MASS LOADING * 5.4798E-02 GR/ACF

IMPACTOR STASE

STAGE INDEX NUMBER

039 (MICROMETERS)                        9,23

MASS (MILLIGRAMS)                       12.70

MC/DSCM/STA6E                           3.09E«OI

CUM. PERCENT OF MASS SMALLER THAN 050  76.57
ASARCO TACOMA

NO 4 SEC EX

01/20/63

 PSMC-4

00

  80. 6F

 30.00

 29.34

 .131

1.140
                                                                       IMPACTdH FLOfcHATt(ACFM)
                                                                       AT  JMPAC10H CONDITIONS
                                                                       1MPACTUH TtMP.

                                                                       PARTICLE DtNSITY(GM/CC)

                                                                       MAX.PAkTKLE (HAM.MICROS

                                                                       GAS COMPUSITION(PEHCENT):
                                            SI

                                            1
                            SAMPLING DUWATIUN(MIN.)

            5.7794E-02 6R/DSCF

            32        S3        SO

            2         3         4

          8,15      5.29      3.        S7

                                                       567

                                                     1.69        .94       .69

                                                     3.80       3.00      4.00

                      1.46E+OI  2.77E+01   1.07t+OI   9.24E«00   7.30E+00   9.73E»00  J.09E»Ol  1.07E«01

                     65.50     44.46     36.35      29.34      23.60     16.42      8.12

                      8.21E*01  5.56t*01   4.56E»Ol   3.68E*01   2.98t*OI   2.066*01  1.02E»01

                      8.66E+01  5.66Et01   4.81E+01   3.88E«01   J.15E»Ol   UO   1.33E»00   8.04E-01  5.27E-01  2.87E-01

                      2.71E+02  1.48E*02   5.60t»01   3.59E+01   2.43E»01   6.99E»01  4.60E»Ol  3.55E>01

                      7.92E*08  9.96E*08   1.40f.*09   4.21E»09   1.95E»|0   2.57E»ll  6.26E«1I  2.86E»12
STANDARD CONDITIONS ARE 20 OEGC AND 760MM HG.

AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO MLRCER.

-------
              IMPACTOR FIELD DATA TABULATION

   PLANT-NAME AND ADDRESS               TEST TEAM LEADER

   ASARCO TACOMA                         DO
   TEST PSMC-4
                NO 4 SEC EX


TEST DATE
TB
TF
TT
Y
ON
CP
PM
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/20/83
1450
1838
23.7
1.001
.131 IN
.84
1.14 1N-H2U
MtTRIC UNITS
01/20/83
1450
1838
?3.7
1.001
3.3
.84
29.0


MM

MM-
00
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VM8TD     VOLUME OP DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

MD        MOLECULAR NT-DRY STACK GAS

MN8       MOLECULAR NT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
14.267 CU-FT


63.9   F

14.473 SCF


  .146 SCF


 1.00

  .990

28.73

28.62

30.00  IN-HG

-9.00  IN-H2U

29.34  IN-HG

81.    F

15.26  ACF
    .404 CU-M


  17.7   C

    .410 SCM


    .004 SCM


   1.00

    .990

  28.73

  28.62

 762.00  MM-Hli

•228.60  MM-H20

 745.19  MM-HG

  27.     C

    .43  ACM
   A8
          STACK AREA
                                            2827.    SO-1N
                      1.024 SU-M

-------
ISO       PERCENT ISOKINETIC               102.3



MT        TOTAL MASS OF PARTICLES             .B36 GK             54.200  HG



PO        PARTICLE DENSITY                    .Oh  GH/CI           1.00   (iM/CC




   •  66 DE6 F,  29.92 TN.HG.
  vo

-------
          IMPACTOR RESULTS AND EXAMPLE CALCULAIIUNS
  PLANT-NAME AND CITY
  ASARCO TACOMA
  TE3T DATE  01/20/83
CALC. MASS LOADING
       TEST TEAM LtAOER
       DO
     RUN NO
     P3MC-1
                                                                                SAMPLE LOCATION
                                                                                NO            54.200  /        .432  =

         CML(MGXOSCM) c MT(MG) / VMSTD(OSCM)

                  CML =           54.200  /        .410  =
                                 .0546   GR/ACF
                                 ,0578   GH/OSCF
                              125.3957   MG/ACM
                              132.2530   MG/DSCM
050 (MICROMETERS)
THE SIZE OF THE PARTICLES UN EACH  STAGt  ASSUMING A 50 PERCENT
COLLECTION EFFICIENCY DEMNIHON
MASS (MILLIGRAMS)
THE MASS ON EACH STAGE COLLECTED
M6/OSCM/3TA6E


     EXAMPLE CALCULATIONS

          MG/OSCM/STAGE(1) s

          MG/03CM/3TA6EU) s

CUM. PERCENT OF MASS
                              THE MASS LOADING FOR EACH  STAGE.  UNITS GIVEN ARE MILLIGRAMS
                              PER DRY STANDARD CUHIC  MITER  FOR  EACH STAGL(MG/OSCM/STAGE)
                               MASS(I) / VMSTD(DSCM)
                                 12.70 /
                .410 a
30.88
                              THE PERCENTAGE OF  THE  TOTAL  MASS  SAMPLbO SMALLER
                              IN DIAMETER  THAN  THE CURHF.SPONU ING  D5U INDICATED
                              FOR THAT 3TAGE
     EXAMPLE CALCULATIONS

          CUM I (6) s MASSC7) * MASSC8) * MAS3(9)

                                MT  (MG)

          CUM X (6) •      4.00 »      4.50 *       4.40

                                    SO.20   (MG)
                     •  100  s
                          •  100  s   £9.34

-------
     CUM.(MASS/VOLUME)
                                    THE CUMULATIVE MASS LOADING OF PARTICLES SMALLER IN UIAMETtR
                                    THAN THE CORRESPONDING 050. MASS/VOLUME UNITS A»t *G/ACM,
                                    MG/DSCM,GR/ACF , (.H/DSCF .
           EXAMPLE CALCULATIONS

                CUM.(M6/ACM) (5) a MASS(6) * MASS(7) » MASS(8) » MASS(9)

                                              IF(ACM)

                CUM.(M6/ACM) (5) s      3.00 »      4.00 »      4.50 *      4.40

                                                    .43  (ACM)
                                                                                            36.79
     6EO.MEAN DIA.(MICROMETERS)
                                    THE GEOMETRIC MEAN DIAMETER IN MICROMETERS
                                    FOR A PARTICULAR STAGE.
          EXAMPLE CALCULATION
               GEO.MEAN DIA.(J)  « SORH O5o(j) • osou-n)
               GEO.MEAN oiA.(b)  r SORU      .94 *      i.H9)
                                                                       1.33
7     DM/OL060(MG/DSCM)
M
~J
                                   DM IS MG/DSCM/STAGEU)  AND DLOGU IS LOG 10 (050 (J-l ) /
                                   D50(J))  WHERE J IS THE  CORRESPONDING STAGE NUMBER.
                                   FOR STAGE 1 THE MAXIMUM PARTICLE OlAMMF.R IS USED.
                                   FOR STAGE 9 (BACKUP FILTER) THE 050 IS ASSUMED AS
                                   .5 • 050 OF STAGE 8.
          EXAMPLE CALCULATION

               OM/DLOGO(J)  =   MG/DSCM/STAGEU)
                              LOG( D50U-1)  / OSO(J))

               OM/DL060 (3)  a             27.73

                              LOG(      8.15 /
                                                     • -   s
                                                     5.29 )
                                                                lflT.7«
     DN/OL06D                      THE NUMBER OF PARTICLES PER UNIT VOLUME FOR A STAGE.

          EXAMPLE CALCULATION

               ON/OL06D(J)  a            DM/DLOGDU)

                               5.23599E-10 * PD(GM/CC)  * GEO.MEAN OIA.(J)

               DN/OL060 (3)  »              11T.74

                               5.235999E-10 •      I.00  •
                                                                 •   «
                                                                  b.57
                                                                            996138624.00
*   CALCULATED AT STACK  CONDITIONS
••  CALCULATED AT STANDARD CONDITIONS
66 OEG.F AND 29.92 INCHES OF  HG (760 MMHG)

-------
                                                            HtLU   DATA
H-

ISJ
PLANT ASARCO TACOMA
SAMPLING LOCATION NO 4 SEC EX
SAMPLE TYPE PART SIZE-CHG
OPERATOR 00
AMBIENT TEMP.(OEG.F) 50.
BAR. PRESS. (IN. MS) 29.70
STATIC PRESS. (IN. H20) -9.00
FILTER NUMBER o) MARK m
STACK INSIDE DIM. (IN) 60.00 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a .0 IN.HG
METER CALI8. FACTOR 1.001
READ » RECORD DATA EVERY 5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME TIME READING HEAD DIFFERENTIAL
NO. (MIN.) (24-HR 
-------
5?
    PLANT » CITY
    SAMPLING LOCATION
    DATE
    RUN NUMBER
    OPERATOR
    STACK TEMP.
    BAR.PRESS.(IN.  HG)
    STACK PRESS.(IN. HG)
    NOZZLEH.0.(IN.)
    METER HEAD DIFF.
 CALC. MASS LOADING > 6.56I4E-02 GR/ACF
IMPACTOR STAGE                            31
STAGE INDEX NUMBER                         I
050 (MICROMETERS)                        9.30
MASS (MILLIGRAMS)                       20.40
M6/DSCM/STAGE                           5.18E*01
CUM. PERCENT OF MASS SMALLER THAN 050  66.78
                              ASARCO TACOMA

                              NO 4 SEC EX

                              01/82/85

                               PSMC-5

                              DP

                                66. 9F    20.5C

                               29.70

                               29.04

                               .131

                              I.140
                            IMPACTUR FLUWHATE(ACFM)
                            AT IMfACrOK LUNOIU'INS
                            IMPACTIJP
                            PAHTICLE DbNSt TT(GM/CC)

                            MAX.PAHTKLE niAM. MICROS

                            GAS cnMPUSITION(PEHCENT) !
                            SAMPLING OUHAT10N(MIN.)

            6.8410E-02 GH/USCF              1
   32
   2

 8.20

 5.40
                      S3
                      3

                    5.30

                    4.20
                                                                          S4

                                                                          4

                                                                        3,3"
                                                                        2.40
  35
  5
1.14

3.80
                    .615

           66.9F    20.5C

                   1.00

                 1UO.O

      C02           .00

      CO            .00

      N2          99.00

      02            .00

      H20          1.00

                   23.50

    MG/ACM             1.5655E«02 MG/OSCM

  56        37         S8     FILTER

  6789

 .88       .62       .34

8.90      7.20      4.60      4.50
  CUM. (MG/ACM) SMALLER THAN 050
  CUM. (MG/OSCM) SMALLER THAN 050
  CUM. (GR/ACF) SMALLER THAN 050
  CUM. (6R/OSCF) SMALLER THAN 050
  GEO. MEAN OIA. (MICROMETERS)
  DM/OLOGD (M6/DSCM)
  DN/OL06D (NO. PARTICLES/DSCM)
I.OOE*02
1.05E+02
4.38E-02

4.57E-02
3.05E+01

5.02E»01

3.39E»06
 I.37E+01  1.07E*OI  6.10E+00  9.66E+00  2.26t»OI   1.83E*01   1.17E»Ol   1.14E+01
57.98     51.14     47.23     41.04     26.55      14.82       7.33
 8.71E*01  7.68E*01  7.09E»01  6.|6E*01  3.99E*01   2.23E»01   I.10E+01
 9.08E»01  8.01E»01  7.39E*U1  6.42E«01  4.16t«01   2.32E»Ot   1.15E»01
 3.80E-02  3.36E-02  3.10E-02  2.69E-02  1.74E-02   9.72E-03   4.8IE>03

 3.97E-02  3.50E-02  3.23E-02  2.8IE-02  I.82E-02   I.OIE-02   5.0IE-03
 8.73E*00  6.59E»00  4.23E«UO  2.a9fc+00  1.27E+00   7.39E-01   4.5fcE-01   2.37E-01
           5.62E+01  3.13E»OI  3.64E«01  7.10t*01   1.19E»02   4.38E»01   I
 7.24E*08  3.T5E+08  7.89E»08  4.48E«09  6.S8t*10   5.65E»11   ».85E»11   5.45E*12
STANDARD CONDITIONS ARE 20 DEGC AND 760MM HG.
AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO THE TASK GROUP ON LUNG DYNAMICS.

-------
    PLANT t CITY



    SAMPLING LOCATION



    DATE



    RUN NUMBER



    OPERATOR



    STACK TEMP.



    BAR.PRESS.(IN. HG)



    STACK PRESS.(IN. HG)



    NOZZLEII.D.dN.)



    METER HEAD OIFF.



 CALC. MASS LOADING « 6.5614E-02 GR/ACF



IMPACTOR STAGE



STAGE INDEX NUMBER



050' (MICROMETERS)



     (MILLIGRAMS)
                              ASARCO TACUMA



                              NO 4 SEC EX



                              01/22/83



                               PSMC-5



                              DO



                                68.9F    20.5C



                               29.70



                               29.0«




                               .131



                              1.140
                                                                     IMHACTUH FLOMRATb(ACFM)


                                                                     AT IMPACtOk CONDITIONS

                                                                     IMPAC1UH TtMM.




                                                                     PARTICLE UtNSITY(GM/CC)




                                                                     MAX.PAKtICLE OIAM.MICROS




                                                                     GAS COMPdSlTIONlPEHCENT):
                                                                     SAMPLING DUHATION(MIN.)
                                           SI




                                           1




                                         9.38




                                        20.40
k



 MG/03CM/3TA6E                            5.I8E+01




 CUM.  PERCENT Of  MASS  SMALLER  THAN  D50   66.78
                                                      6.8410E-02 GR/DSCF



                                                      S2        S3        SO



                                                      2         3         a




                                                    8.20      5.38      3.0b



                                                    5.40      4.20      2.40
              .615



     6B.9F    20.5C




             1.00




           1UO.O




C02           .00




CO            .00




N2          99.00




02            .00




H20          1.00




             23.50




                1.5655E«02 MG/DSCM




                88     FILTER




                »         9




               .41




              4.60      4.50
  CUM. (M6/ACM)  SMALLER THAN 050



  CUM. (MG/DSCM) SMALLER THAN D50




  CUM. (GR/ACF)  SMALLER THAN D50



  CUM. (6R/OSCF) SMALLER THAN D50




  6EO. MEAN OIA. (MICROMETERS)



  OM/DL06D (MG/DSCM)



  DN/DLOBO (NO.  PARTICLES/OSCM)
                                         1.00E»02



                                         1.05E«02



                                         4.38E-02



                                         4.57E-02



                                         3.06E«01



                                         5.04E*01



                                         3.35C»06
                                  1.S015E+02 MG/ACM



                                 35        36         37



                                 5         6          7



                               1.92        .96        .70



                               3.80      8.90      7.20



 1.37E+U1  J.07E+OI  6.IOE«00  9.66E«00  2.26E>01  l.83E»01   1.17t«01   I.14E«01



57.98     51.14     47.23     41.04     26.55      14.62       7.33



 8.71E«01  7.68E + 01  7.0<)E*01  6.16E»01  3.99E+01  2.23E + 01   1.10E*Ot



 9.0BE + 01  8.01E*01  7.3<»t»U1  b.42E»OI  4.16E«01  2.32E»01   I.I5E»01



 3.80E-02  3.36E-02  3.10E-02  2.69E-02  1.74t-02  9.72E-03   4.8U-V3



 3.97E-02  3.50E-02  3.23E>02  2.81E-02  1.82E-02  1.01E-02   5.01E-03



 e.eit+00  b.67E»00  4.32E«00  2.58OUO  1.36t»00  B.18t-0t   5.36E-01   2.92E-01



 2.55E*02  5.69E>01  3.J9E*01  3.75E»01  7.53E»U1  I.32E+02   5.14E»01   3.80E»01



 7.10E*08  3.66E»08  7.59t»08  4.19t»09  5.77E»10  «.60t»ll   6.37E*11   2.92EM2
STANDARD CONDITIONS ARE 20 OE6C  AND 760MM HG.



AERODYNAMIC DIAMETERS ARE CALCULATED HEHE ACCORDING TO MERCER.

-------
           IMPACTOR FIELD DATA TABULATION

PLANT-NAME AND ADDRESS               TEST TEAM  LEADER

A8ARCO TACOMA                         DO
TEST PSMC-5
      NO a SEC EX
ENGLISH UNITS
TEST DATE






1
I-1
VI

TB
TF
TT
Y
ON
CP
PM
VM
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
01/88/83
1047
8180
83
1


1
13
60
13
.5
.001
.131 IN
.84
.14 IN-H8U
.669 CU-FT
.0 F
.851 SCF
METHIC UNITS
01/88/03
1047
8180
83
1
3

89
15

.5
.001
.3
.84
.0
.388
.5
.398


MM

MM-H80
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

MD        MOLECULAR NT-DRY STACK GAS

MNS       MOLECULAR NT-STACK GAS

PB        BAROMETRIC PRESSURE

P3I       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
                                   .140 SCF


                                  1.00

                                   .990

                                 86.73

                                 88.68

                                 89.70  IN-HG

                                 -9.00  IN-H8U

                                 89.04  IN-HR

                                 69.    F

                                 14.44  ACF
                         .004 SCM


                        1.00

                         .990

                       88.73

                       88.68

                      754.38  MM-Hb

                      •888.60  MM-H80

                      737.57  MM-Hti

                       81.    C

                         .41  ACM
AS
STACK AREA
8887.
Sfl-IN
1.884 SO-M

-------
 ISO       PERCENT ISOKINETIC


 MT        TOTAL MASS OF PARTICLtS


 PO        PARTICLE DENSITY
*  66 DE6 f,  89.
                        IN.HG.
 I
\->
-J
                                                GR


                                           .06  GR/CI
61.100 MG


 1.00  GM/CC

-------
                IMPACTOR  RESULTS AND  EXAMPLE  CALCIILA1 IUNS
        PLANT-NAME  AND  CITY
        ASARCO  TACOMA
        TEST  DATE   01/22/83
                                 TEST  TEAM LEAKER
                                 OU
                                                           RUN NU
                                                           PSMC-5
SAMPLE LOCATION
NO 4 SFC tX
     CALC. MASS LOADING
I
H
>J
-J
                         TOTAL MASS OF PARTICLES  DIVIDED  BY A VOLUME. UNITS GIVEN AWE CHAINS PER
                         ACTUAL* CUBIC I-OUUGR/ACF ),CHAINS PEK DHY STANDARD** CUBIC FOOTUJR/OSCF),
                         MILLIGRAMS PER  ACTUAL  CUBIC  METEH(MG/ACM> AND MILLIGRAMS PER OHT STANOAHU
                         CUBIC METER(MG/DSCM.)
EXAMPLE CALCULATIONS

     CML(GR/ACF) « MT(6R) / IF(ACF)

             CML *              .946  /      14.441  =

    CML(GR/DSCF) • MT(GR) / VMSTU(DSCF)

             CML *              .948  /      13.051  =

     CML(MG/ACM) a MT(MG) / IF (ACM)

             CML s           61.400  /        .409  =

    CML(M6/09CM) « WTCHG; / VMSTC(03Cf*}

             CML *           61.400  /        .392  =
                                                                    .0656  GR/ACF
                                                                    .0684  GR/DSCF
                                                                 150.1469  Mb/ACM
                                                       156.5454   MG/OSCM
     DSO  (MICROMETERS)
                         THE SIZE OF  THE PAMTICLES  ON  EACH STAGE ASSUMING A 50 PERCENT
                         COLLECTION EFFICIENCY  DEFINITION
     MASS  (MILLIGRAMS)
     M6/OSCM/STAGE
                         THE MASS ON EACH  STAGE  COLLECTED
                         THE MASS LOADING FUR EACH  STAGE.  UNITS GIVEN ARE MILLIGRAMS
                         PER DRY STANDARD CUBIC  METER  FOR  EACH STAGE(MU/OSCM/STARE)
EXAMPLE CALCULATIONS

     MG/DSCM/3TAGEU) s   MASS(l) / VMSTD(t)SCM)

     M6/DSCM/STAGE(1) =     20.40 /
                                                     392 =
                                                      51.83
     CUM. PERCENT OF MASS
                         THE PERCENTAGE OF THE  TOTAL  MASS  SAMPLED SMALLER
                         IN DIAMETEH THAN THF. CURHF. SPOND ING  050  INDICATED
                         FOR THAT STAGE
                                                         * 100
EXAMPLE CALCULATIONS

     CUM X (6) * MASS(7) » MASS(8) * MASS(9)

                           MT (MG)

     CUM X (6) »      T.20 »      4.60 *       4.50

                               61.40   (MG)
                                                              • 100  =  41.04

-------
        CUM.(MASS/VOLUME)
THE CUMULATIVE MASS LOADING OF PARTICLES  SMALLER  IN DIAMtTEH
THAN THE CORRESPONDING USD. MASS/VOLUME UNITS  AHh  MG/ACM,
MG/DSCM,GR/ACF,GH/USCF.
             EXAMPLE CALCULATIONS

                  CUM.(MG/ACM)  (5) s MASS(b)  *  MAS3(7)  «  MASS(8)  »  MASS(9)

                                                 IF(ACM)

                  CUM.(MG/ACM)  (5) =       6.90  »       7.
~4
CO
THE GEOMETRIC MEAN DIAMETER  IN MICROMFTEHS
FOR A PARTICULAR STAGE.
             EXAMPLE CALCULATION

                  6EO.MEAN OIA.(J) •  SQRT(  050(J)  *  D50U-1))

                  6EO.MEAN DIA.(b) «  SORT (       .96  •       1.
                                    1.36
        OM/OL080(MG/DSCM)
DM IS MG/OSCM/STAGE(J) AND OLOGD  IS  LOG 10(050(J-I)  /
D50U)) WHERE J IS THE CORRESPONDING STAGE  NUMBER.
FOR STAGE 1 THE MAXIMUM PARTICLE  DIAMETER  IS  USED.
FUR STAGE 9 (HACKUH FILTtH)  THE USD  IS  ASSUMED  AS
.S • 050 OF STAGE 8.
             EXAMPLE CALCULATION

                  DM/DLOGOU) =   MG/DSCM/STAGE (J)

                                 LOGl DSO(J-I)  /  D50(J))

                  DM/DLOGD  (3) s              10.67

                                 LOGl       8.26 /
                 -•   3
                 5.38 )
                             56.8T
        DN/DLOSD                       THE NUMBER  OF  PARTICLES PER  UNIT VOLUME FOR A STAGE.

             EXAMPLE CALCULATION

                  DN/DLOGDU) *            DM/DLUGDU)

                                  5.23599E-10  • POIGM/CC)  •  GEU.MEAN DIA.(J)

                  DN/DL060 (3) s               S6.87

                                  5.835999E-10 •       1.00  *       b.67

   •   CALCULATED AT STACK CONDITIONS
   •*  CALCULATED AT STANDARD CONDITIONS
   66 OEG.F AND Z9.9Z INCHES OF HG  (760 MMHG)
                                         365581376.00

-------
 END  OF  PROGRAM
 IFILE FTN10  «  CIDROtDArOLD
 IFILE FTNll«CIOR020A,OLD
 IRUN CIDR2PGfSTACKs20000
 END  OF  PROGRAM
 triLE FTNOe=CIDR03DA,OLO
 IFILE FTN09=CIOROOOA,OLD
 tRUN CIDR4PG
 I
I-1
•J
VD

-------
           ASARCO AVERAGE PARTICLE SIZE DISTRIBUTIONS
RHO» 1.00~6M/CC
                       MEAN CUMULATIVE   UPPEH CONFIDENCE
INTERVAL   DIAMETER   MASS CUNCtNTKATI UN      LIMIT
           (MICRONS)       (MG/ACM)          (MG/ACM)

















>
1
K-1
00
0































1
2
3
•
5
6
7
8
9
10
11
12
13
14
IS
16
17
16
19
20
21
22
23
24
29
26
27
28
29
30
31
32
33
34
35
36
3T
36
39
40
41
42
43
44
45
46
47
46
49
SO
51
52
2.50E-01
2.7IE-01
2.95E-01
3.20E-OI
3.47E-01
3.77E-01
4.09E-01
4.45E-01
4.83E-01
5.24E-01
5.69E-01
6.16E-01
6.71E-01
7.26E-01
7.91E-01
8.S8E-01
9.32E-01
1.01E»00
1.IOE+00
1.19E+00
1.29E»00
1.41E+00
I.S3E+00
1.66E+00
1.80E+00
1.95E*00
2.12E+00
2.30E»00
2.50E+00
2.71E»00
2.95E»00
3.20E*00
3.47E«00
3.77E*00
4.09E»00
4.45E»00
4.83E+00
5.24E*00
5.69E»00
b.I6E*00
b.71E»00
7.28E»00
7.91E»00
8.58E*00
9.32E»00
I.OIE»01
1.10E«01
1 _ J OF ^01
1 * 29E ^ 0 1
1.41E«01
1.53E+01
l.b6E»01
                           6.48E*00
                           7.38E»00
                           8.flOE»00
                           9.5bE»00
1.39E»01
J.58E»01
1.78E»01
2.00E«01
                           2.
                           2.
                           3.
 .50E+01
 .7bE»01
 ,05E*01
3.39E»01
3.7bE»OI
4.09E»01
4.39E*01
0.b6E»01
4.89E»01
5.08E»01
                           5.39E»01
                           5.51E»01
                           5.bOE»01
                           5.b6E»OI
                           5.75E»01
                           5.95E»OI
                            .01E»01
                            ,07E»Ol
                            .13E»OJ
                            .20E»OJ
                            ,29E»0»
                            ,39E*01
                            .53E»01
                            .72E*01
                            ,93E*01
                            .|9E»OI
                            .08E»01
                            .40E+01
                            ,73E»Ol
                            ,OSE»OI
                            ,3bE»01
                            .63E»01
                            .89E+01
                            ,OIE»02
                           1.03E»02
                           I.OSE*02
                  b.b>E»00
                  7.57E»00
                   .I2E«OI
 .bJE«Ol
 .81E»01
2.0/E»01
2.32E«01
3.I3E»01

3.87E*01
4.2IE*OI
0.52E+01
4.79E*OI
5.03E+OI
                  5.aOK»01
                  5.54E*01
                  5.75E*OI
                  5.83E*01
                  S.97E*01
                  fc.OflE+01
                  b,10E»OI
                   .29E»01
                   .3bE*01
                   .44E«OI
                   .70E*01
                   .88E»01
                    10E»01
                    3bE»01
                  7.b5E»01
                  7.96E*01
                  B.b2E«01
                  8.9bE»01
                  9.29E»01
                  1 .01E«Oi>
                  1.04E«02
                  1.0bE+Oa
                                 LOWEH CONFIDENCE
                                      LIM| f
                                      (Mli/ACM)
                   7.1»E»0«
                   8.1
                                                                 ,U5E»Ot
                                                                 ,19E»01
                                                                 .72E*01
                                                                 .93E»01
2.b9E»01

3!29E»«1

3.97E»01
                                                                a.52E*01
                                                                4.75E*01
                                                                4.94E»01
                   5.53E*OI
                   5.bOE»01
                   5.73t»01
                   5.79E»01
                   5.85E«01
                   5.91E+OI
                   5.98E*01
                    ,13E*OI
                    .23E+01
                    .37E*01
                   7.U1E»01
                   7.28E«UI
                   7.87E»01
                   8.19E+U1
                   8.82E»01
                   9.87E+UI
                   l.01E»02

-------
S3
5«
55
56
57
56
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
i.eoE+oi
1.95E+01
2.12E»01
2.30E«01
2.50E»01
2.71E*01
2.95E«01
.47E«01
.77E«01
.09E«01
 ,69E*01
 .71E»01
 ,2$E«OJ
 .91E»01
 .56E+01
                            ,07E»0?
                            ,06E»02
                            .20E«02
                                               ,18E*0?
                                               .21E»02
                                               .23F.«02
                                               ,23E»02
                                              .2«E*02
                                                     .ObK»02
                                                     ,07E»02
                                                     ,08t+02
                                                                  .I0t*08
                                                                  .1IL+U2
                                                                   laE*02
                                                      ,17Et02
                                                      ,17E»02
                                                      .18E«02
>
 I
00

-------
           ASARCO AVERAGE PARTICLE  SIZE DISTRIBUTIONS
MHO* 1.00 6M/CC
INTERVAL   DIAMETER     RECORDS  EXCLUDED FHUM MtAN
                       CU*UlATIVt MASS CON(tNTW«TinN
1 i
2 i
3 i
4
5
6
7
6
9
10
11
12
13
14
IS
16
17
18
19
> 20
1 21
I-1 22
00 ?«
to "
24
25
26
27 i
28 i
29 i
30 i
31 i
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
». 506-01
>. 716-01
». 956-01
.206-01
.476-01
.776-01
.096-01
.456-01
.836-01
.246-01
.696-01
.186-01
.716-01
.286-01
.916-01
.586-01
.326-01
.016+00
.106+00
. 1 96+00
.296+00
.416+00
.53E+00
.66E+00
.806+00
.956+00
!. 126+00
». 306+00
'.50E+00
».71E»00
>. 956+00
1.206+00
S. 476+00
.776+00
.096+00
.456+00
.836+00
.246+00
.696+00
.186+00
.71E+00
.28E+00
.916+00
.586+00
.326+00
.016+01
.IOE+01
.19E+01
.296+01
.416+01
.536+01
.66E+01
.eoE+ui
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
?
2
2
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE

-------
54
SS
96
57
56
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
I.95E+01 NONE
2.12E+OI NONE
2.30E»01 NONE
2.SOE+01 NONE
2.71E«OI a
2.95E*OI K
3.aOE»01
3.47E«01
3.77E*01
4.09E*01
«.45E»01
0.83E*OI
5.24E«01
5.69E»01
6.I8E+OI
6.7IE«01
7.28C*01











7.9IE«OI 8
6.58E«OI 8
9.32E«01 NONE
00
U>

-------
ASARCO AVERAGE PARTICLE SIZE  DISTRIBUTIONS
MHO* 1.00 6M/CC

INTERVAL DIAMETER
(MICRUNS)
1 2.50E-01
2 2.71E-01
3 2.95E-01
m
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
2t)
1 2I
M 22
oo 23
*• 24
25
26
.20E-01
.47E-01
.77E-01
.09E-01
.4SE-OI
.83E-01
.24E-01
.69E-01
.I8E-01
.71E-01
.28E-01
.91E-01
.58E-01
.32E-01
.01E»00
.10E+00
.19E«00
,29E»00
,41E*00
.53E»00
.66E+00
.80E+00
,95E»00
27 2.1«»00
28 2.30E+00
29 2.50E+00
30 2.71E»00
31 2.95E»00
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
.20E+00
.47E»00
.77E»00
,09E»00
,45E»00
.83E*00
.24E*00
.69E»00
.18E»00
,7IE»00
,28E»00
,91E*00
.58E*00
.32E*00
.OlE^Ol
,10E-»01
.19E*01
.29E»01
.41E»01
.53E«01
.bbE*01
.80E+OJ

MEAN CUMULATIVE
MASS CONCENTKAT 1UN
(PERCENT)
5.33E*00
b.07E»00
*>.91E*00
7.8bE«OU
(I.93F + 00
,01F»01
.15E»01
,30E*OI
,flbE»01
.b4E»01
.85E»OJ
2.06E«01
2.27E»01
2.51E«01
2.79E*01
3.09E*01
3.36E»01
3.blE*01
3.83Et01
.02E+01
.18E»01
.32E401
,43E*0 1
.53E»01
,blE»01
,b7E*OI
.73E«01
.78E»01
.84E+01
.89E»01
.94E*01
,99E»01
.OflE»01
5.10E*01
5.17E»01
5.abE»01
5.37E*01
5.52E+01
5.70E*01
5.91E*01
b,14E*01
b.38E»01
b.b4E*01
b.91E*OI
7.I8E+01
7.44E«01
7.b9E»01
7.9?E»01
6.13E»01
8.32E»01
8.09E*01
8.bflE*01
B.78E+01

UPPER CONF IDENCE
LIMI 1
(PERCENT)
b.43E«UU
h.23E*00
7.12E»00
8.11E»00
9.23E»00
.ObE»01
. 19E«01
. 34E+OI
.5IE»01
.70E»01
.9JE»01
2.12E*OI
2.34E*01
2.57E»01
?.8/E*01
3.18E«01
3.4bE»01
3.72E«01
3.94E»01
4. 13E*0 I
«.30E»01
4.44E+01
4 ,55E»0 1
4.65E*01
4.73E*01
4.80E*OJ
4.8bE*01
4.91E«01
4.9bE+01
5.02E+01
5.07E*01
5.12E«01
5.17E»01
5.23E»01
5.3«E»01
5.39E»01
5.51E*01
5.bbE+01
5.84E*01
b.05E«0|
b.29E*Ol
h .54E + 01
b.8 1E*0 1
7.08E*Ol
7.37E»01
7.64E*01
7.89E*OJ
8.I2E+U1
8.33E»01
8.5iiE»01
A.7UE«01
8.85E»01
8.99E*01
                                                  LOWER CONFlOENCh
                                                       LIMI f
                                                      (PERCENT)
                                                      b.70F»UO
                                                      7.blE»00
                                                      8.b3t*00
                                                      I.25E«01
                                                      1 .41E + 01
                                                      1 .79t*OJ
                                                      2.UUE«OI
                                                      2.71E*01
                                                      3.00E«01
                                                      3.2bE*OI
                                                      3.'jOE»01
                                                      3.90E»01
                                                      u.2UL*01

                                                      4.40E«U1
                                                      4.bUE»UI
                                                      a.bbE+01
                                                      4.71E»01
                                                      4.7hE»01
                                                      4.8bE»01
                                                      a.91E»01
                                                      4.97E+01
                                                      5.I2E»01
                                                      5.24E»«1
                                                      5.39E»01
                                                      5.5bE*OI
                                                      5.7bE»01
                                                      b.73E»01
                                                      7.00E»Ol
                                                      7.2'iE*01
                                                      7.93t»01
                                                      8.29E»01
                                                      8.44E«01

-------
S«
55
56
57
56
59
60
61
62
63
64
6%
66
67
68
69
70
71
72
73
1.95E+01
2.12E*01
2.30E+01
2.SOE+01
2.71E+01
2.9SE«01
3.20E*01
3.47E*OI
3.77E*Ol
4.09E«01
4.45E»01
4.83E+01
S.24E«01
5.69E*01
6.ieE»OI
6.71E«01
r.2«E»OI
7.91E«01
e.58E»01
9.32E«01
                          B.90E+01
                            ,01E*OI
                            .IIE*OI
                            ,3hE»01
                            ,5BE»OI
                            .70E»01
                            .75E»OI
                            .79E»01
                            .87E«01
                            .91E»01
                            .<»7F»01
                            .99E«01
                           1.00E«02
9.a9E*01
9.bbE»OI
9.7iE»01
9.80E»Ol
9.91E*01
 ,01E«02
                   fl.70E»OI
                   8.80E»Ol
                   8.90E«Ol
                                                                9.07E»01
                   9.30E»OI
                   9.37E*Ot
                   9.flJE»01
                   9.b9E»01
                   9.72t»01
                   9.75E*OI
                   9.78E»01
00
tn

-------
MHO* 1.00

INTERVAL

    1
    2
    3

    3
    6
    7
    6

   10
   11
   12
   13
   14
   IS
   16
   17
   18
   19
 >20
  '21
 oo 2 2
   24
   23
   26
   27
   28
   29
   30
   31
   32
   33
   34
   33
   36
   37
 ASARCO AVERAGE PARTICLE SIZE DISTH1BUT
6M/CC
                 MEAN CHANGE
DIAMETER

2.50E-01
2.93E-01
3.47E-01
4.09E-01
4.83E-01
5.69E-OI
6.71E-01
7.9IE-01
9.32E-OI
1.10E+00
1.29E»00
I.eOE'OO
2.12E*00
2.30E*00
2.95E+00
 ,47E»00
 .09E+00
 .83E+00
 .69E«00
 .71E*00
 ,91E*00
 .32E+00
 .10E»OI
  .53E»OJ
 3.47E*01
 4.09E*01
 5.69E»OI
 6.7IE+01
 7.91E*01
 9.32E*01
            IN MASS CONCENTRATION
                  (MG/DNM3)
«.|OE*OJ
5.11E+01
                   8.06E+01
                   3.73E*01
                   2.57E*01
                   I.98E»01
I.79E»01
1.93E*OI
a.70E»01
4.81E+01
6.97E*01
8.57E»01
9.52E»Ol
9.77E+01
8.bOE*01
7.iaE»01
5.8bE»OI
fl.bbE»01
3.b7E»01
                  2.97E*01
                  2.51E»01
                   I.73E+01
                  1.19E»01
                  9.B1E»00
                  6.bOE*00
                  IONS

                  STANDARD
                  UEVIAT KIN
                  (MG/UNM3)
                   1.17t«01
1 ,7bE*01
2.IOE+01
                                      a.9bE*01
                                      1.3bE+Ol
                                      3.b3E»01
 ,?5E»01
 ,lbE»01
 .18E»01
                                     3.52E«01
                                     5.5IE»01
                                     b.OVE«01
                                     1.73E»01
                                     2.32E401
                                     I.99E*01
                                     2.04E*01
                                     l.S3E*01
                   1.IOE»OI
                   9.28E*00
                   7.64E>UO
                   b.aOE«OU
          UHPEH CONFIOfcNCt
               LIM1I
             (MG/UNM3)
3.7«fE»01
4E»01
                                 4.35E*01
                                 3.bOE*01
                                 3.5bE«OI
                                     5.20E*00
              2.09E»01
              1.71E+01
              1.43E«UI
              1.18E»01
              8.34E»00
               LOHEH CONFIDENCE
                    LIMIT
                   (MG/ONM3)
                                                                       3.5IE*(M
                                                                       b.
                                  9.b5E»01
                                  7.97t»01
                                  b.U7E*Ul
                                  a.uot»oi
                   
-------
           ASARCO AVERAGE PARTICLE  SIZE  DISTRIBUTIONS
MMO* 1.00 6M/CC
INTERVAL   DIAMETER    RECORDS EXCLUDED FROM MEAN
                      CHANGE  IN  MASS  CUNTHAflUN
1
2
3
4
5
6
7
e
9
10
11
12
13
14
15
16
17
IB
19
> 20
1 2!
m "
™ 23
24
25
26
27
20
29
30
31
32
33
34
35
36
37
2.50E-OI
2.95E-01
3.47E-01
4.09E-01
4.03E-01
S.69E-01
6.71E-OI
7.91E-01
9.32E-01
I.10E+00
1.29E»00
1.53E*00
1.00E+00
2.I2E«00
2.50E«00
2.95E«00
3.47E*00
4.09E«00
«.03E»00
5.69E»00
6S71E*00
7.91E«00
"».32E»00
1.10E«OI
t.29E«01
|(53E«0|
1.00E*01
2.12E^01
2.50E«01
2.95E»0|
3.47E*OI
4.09E«OI
*.83E»0|
5.69E*01
6.7IE«01
7.91E»01
9.32E«01
NONE
NONE
NONE
NONE
NONE
NONE
i
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE







NONE

-------
ASARCO AVERAGE
«HO» 1.00 6M/CC
INTERVAL DIAMETER
1 2.SOE-01
2 2.9SE-01
V
4
5
b
7
a
9
10
11
12
13
14
15
16
17
ia
19
* 20
21
3 "
I 23
24
25
26
27
.47E-01
.09E-01
.83E-01
.69E-01
.71E-01
.91C-01
.32E-01
.10E+00
.29E»00
.53E»00
.BOE+00
.12E»00
,50E»00
.95E»00
,47E*00
.09E»00
.83E+00
,69E»00
.71E»00
.91E^OO
.32E«00
,10E»OJ
»29E*Ol
.53E»01
.80E»01
28 2.12Et01
29 2.50E+01
30 2.95E*01
31 3.47E«01
32 4.09E*01
33 4.83E»01
34 S.69E*01
35 6.71E+01
36 7.91E+01
37 9.32E+01
 PARTICLE SIZE DISTRIBUTIONS
      MEAN CHANGE
IN NUMBER CONCENTRATION
       (NO/DNM3)
        3.07E+12
        ?.41E«12
        1.B7EM?
I.07E«12
8.10E«11
S.ltEttl
4.37E»U
2.22E+I1
 .73E«10
 .OOE»10
 .42E*09
 ,97E*09
 .31E»09
 .33E*09
 .81E»08
 .50E*08
 .22E«06
         ,«3E*08
         .b8E+08
         ,31E*08
         .15E*07
         ,53E»07
2.22E«06
l.l«E*Ob
5.73E»05
2.9flE*OS
1.47E»OS
7.52E»Oa
3.79E*04
l.S6E«04
                  STANDARD
                  DEVIATION
                   8.0flE»l1
                   5.83E*11
                           3.I»F»H
                           8.U9E«1U
                           1.03E»11
                           1.20E+10
                           5.33E»09
                           1.02E*09
                           8.P3E*OB
                           5.87F»OB
                           a.38E«08
                           4.IOE+08
                           3.bbE»08
                   8.13E+08

                   b.8JE»07
                   1.25E»07

                   4!o9E+Ob
                           1.14E«Ub
                           3.05E*Ob
                           I.S8E+OS
                           7.92E*04
                           4.05E»Oa
                           2.oaE+oa
UPPEK CONFIDENCE
     LIHI1
   INO/DNM3)
    1 ,68E + ia

    9.17E+1I
                                         4.81E«09
    l.b3E»09
    1 ,OHt»09
    8.05E»08

    0.39E»08

    1 .07E»08
    3.5bE»07
    l.7a£»07
    8.71F+06
    tt.40E*Ob
    1 ,7«E«05
    4.08E+OM
LOwEH CONFIDtNCE
     LIMIT
   (NO/DNM3)
           I
    7.0at»lI
    a.79t»l1
    3.73E»II
    1 .8flE»l1
    B.75E+10
    3.87t*10
    1 .bOt + 10
                       3.13E»09
                       1.80E+U9
    b.O«E-»0«
    b.85E»0«
    b.01t«08
    1 .83E»Ofl
    1.0JE»0«
    5.33E*07
    2.73E»07
    l.3tt»07
    5.98t*06
    4.55E»05
    2.33E»05
    1.17t*05
                                         1 .97E+01
                       3.01t»«a
                       1.15E»0«

-------
           ASARCO AVERAGE PARTICLE  SIZE  DISTRIBUTIONS
MHO* 1.00 GM/CC
INTERVAL   DIAMETER    RECORDS EXCLUDED  FROM MEAN
                     CHANGE  IN NUMBEH CONCENTRATION
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                          2
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
                         NONE
1
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
-20
721
M22
0023
^24
25
26
27
28
29
30
31
32
33
34
35
36
37
2.50E-OI
2.95E-01
3.47E-01
4.09E-01
4.83E-01
5.69E-01
6.71E-01
7.91E-OJ
9.32E-OI
1.10E+00
1.29E+00
I.53E+00
1.80E+00
2.12E*00
2.50E»00
2.95E»00
3.«7E*00
fl.09E»00
4.83E*00
5,696*00
6.71E»00
7.91E»00
9.32E*00
1.10E»Ol
1 ,29E*01
1.53E*01
i.aoE*oi
2.12E*01
2.50E*OI
2.95E*OI
3.47E*01
4.09EtOt
«.93E*01
5.69E*01
6.71E»01
7.91E»01
9.32E*01
                         NONE

-------
 END OF PROGRAM

 tCOJ

 CPU SEC. * 95.  ELAPSED MIN. * 4.   TUE» FEB ^^. 1963, 10:42 AM
vo
o

-------
FIELD  DATA
PLANT ASARCO TACOMA
SAMPLING LOCATION NU 4 SEC EX
SAMPLE TYPE PART SIZE-BLOW
OPERATOR DO
AMBIENT TEMP. (DEC. F) 55.
BAR. PRESS. (IN.HG) 29.53
STATIC PRESS. (IN. M20) -2.50
FILTER NUMBER (3) MAKK III
STACK INSIDE DIM. (IN) 60.00 .00
P1TOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3
METER CALIB. FACTOR .980
READ S RECORD DATA EVERY 5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT TIME
NO. (MIN.)

INIT 0
1.7
5.0
10.0
15.0
15.0
20.0
25.0
30.0
30.0
35.0
40.0
46.0
53.0
53.0
60.0
65.0
75.0
80.0
60.0
86.0
90.0
95.0
105.0
106.4
106.9
111.6
116.6
120.5
120.5
130.5
TIME
(24-MH

613
815
0
0
829
1515
0
0
1530
732
0
0
0
755
846
0
0
0
0
944
0
0
0
0
1011
1016
0
0
1030
1144
0
READING HEAD
(CU.FT.) (IN.H20)

281.310
262.135
263.750
286.230
268.717
333.534
336.070
338.580
341.070
356.472
358.920
361.390
364.290
367,663
380.410
383.900
386.360
391.310
393.781
405.438
408.600
410.590
413.090
418.100
418.760
420.008
422.650
425.160
427.108
432.220
437. 220
.500
.500
.450
.500
.500
.400
.400
.400
.500
.650
.650
.650
.650
.500
.650
.750
.700
.750
.500
.650
.700
.650
.700
.700
.650
.650
.600
.550
.500
.500
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DES1HEO

.66
.68
.88
.68
.88
.88
.86
.88
.88
.88
.86
.66
.88
.66
.88
.88
.88
.86
.86
.88
.88
.68
.68
.68
.86
.88
.88
.86
.86
.86
H«?U)
ACTUAL

.86
.66
.80
.88
.88
.88
.68
.88
.68
.80
.68
.68
.86
.86
.88
.86
.68
.68
.80
.88
.88
.68
.88
.86
.86
.88
.80
.88
.88
.68
STACK
TEMP
(DEG.F)


64.
64.
63.
62.
64.
69.
66.
68.
64.
55.
54.
54.
55.
64.
66.
63.
62.
62.
64.
66.
64.
62.
62.
61.
66.
66.
67.
66.
64.
67.
DATE 01/18/03
RUN NUMHEH PSB-1
HRUBE LENGTH ft TYPE 6* STEEL
NOZZLE : l.U. .148
ASSUMED MOISTURE 1.0
SAMPLE BOX NUMBER
MEIEH BOX NUMBEH FB9
METEH HEAD OIFF. ?.o0
PROBE HEATER SETTING 0.
HFATEH HUX SETTING 0.
PRY GAS METEH PUMP IMPACTOR IMPINGER
TEMP
(DEC
INLtT

48.
49.
4V.
51.
60.
55.
55.
57.
60.
43.
44.
47.
49.
60.
54.
55.
57.
60.
60.
61.
61.
62.
63.
65.
64.
64.
64.
65.
60.
55.
.F)
00 I LET

54.
54.
54.
55.
61.
61.
61.
M.
61.
50.
50.
50.
50.
61.
57.
57.
57.
58.
61.
63.
63.
63.
63.
63.
64.
64.
64.
64.
61.
62.
VACUUM
( IN.HG)


.5
.S
. *>
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
TEMP
(OF.G.M


64.
64.
63.
62.
64.
69.
68.
68.
64.
5S.
54.
54.
55.
64.
66.
63.
62.
62.
64.
66.
64.
62.
62.
61.
66.
66.
67.
66.
64.
67.
TtMP
tUEd.F)


50.
50.
50.
49.
49.
50.
51.
51.
51.
51.
52.
52.
50.
50.
49.
49.
49.
49.
47.
47.
45.
45.
45.
45.
48.
48.
48.
48.
49.
49.

-------
PLANT
SAMPLING LOCATION
A3AMCU TACOMA
NO a SEC EX
                                                                             OAlt
                                                                             HUN NUMHEM
                             U1/1B/H3
                              P3H-1
READ ft RECORD DATA EVERY  5.0 MINUTES
TRAVERSE  SAMPLE  CLOCK
 POINT     TIME    TIME
  NO.     (MIN.) (24-HR
                    GAS MElEW   VELOCITY
                     READING      HEAD
                     (CD. FT.)   (IN.H20)
                ORIFICE PHESSUHE   STACK
                  DIFFERENTIAL      ItMP
                    UN.H?U)       (OEG.F)
OUT GAS MtltP  PDK.P     IMPACTUH IMPINGEH
    TEMP      VACUUM      TEMP     TLMP
   (DEr,.F)    (1N.HG)  (DEG.F)   (UEti.F)
DESIRED













If
1
vr>
NJ

140.5
150^5
162.5
165.0
175.0
165.0
195.0
200.0
204.6
206.4
210.0
220.0
_. 230.0
240.0
245.0

TOTALS 245.0
AVERAGE
0
0
0
1226
0
0
_ 0
0
1316
1318
0
0
0
0
1401



442.200
447.160
453.150
454.347
459.260
464.300
469.330
471.600
474.300
475.087
476.950
461.970
487.010
492.060
494.590
.500
.500
.450
.500
.450
.400
.400
.400
.400
.400
.350
.400
.350
.400
.350

106.975

.66
.88
.68
.66
.88
.68
.66
.68
.88
.68
.68
.86
.88
.86
.68


.68
ACTUAL
.88
.88
.88
.88
.88
.68
.86
.68
.68
.86
.68
.66
.66
.68
.88


.68
INLET OUTLET
67.
66.
66.
65.
6V.
66.
67.
6V.
64.
68.
68.
68.
66.
65.
65.


64.
57.
61.
64.
67.
64.
65.
67.
67.
70.
70.
66.
68.
6V.
71.
71.


60.
61.
61.
62.
64.
65.
65.
66.
66.
67.
68.
68.
66.
69.
70.
70.


61.
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5


.5
67.
66.
66.
65.
69.
66.
67.
66.
64.
68.
68.
68.
66.
65.
65.


64.
49.
50.
50.
51.
51.
51.
51.
51.
51.
51.
51.
51.
51.
51.
52.


50.
  PERCENT ISOKINETIC
          89.1

-------
      PLANT & CITY
      SAMPLING LOCATION
      DATE
      RUN NUMBER
      OPERATOR
      STACK TEMP.
      BAR.PRESS.(IN. HG)
      STACK PRESS.(IN. HG)
      NOZZLEtl.D.dN.)
      METER HEAD DIFF.
   CALC. MASS LOADING « l.C
  IMPACTOR STAGE
  STAGE INDEX NUMBER
  050 (MICROMETERS)
  MASS (MILLIGRAMS)
  MG/OSCM/STAGE                           2.20E+01
  CUM. PERCENT OF MASS SMALLER THAN 050  13.21
ASAHCO TACOMA
NO 4 StC EX
01/18/83
PSH-1
00
64. 4F 18. OC
29.53
29.35
.148
.880
E-02 GR/ACF
SI
1
!o,es
67.00
1MPACTOH FLOHHATt (ACFM)
AT IMPACTOR CONDITIONS
IMPACTUH TEMP. b«.3F
PARTICLE
MAX .PACT
DENSI rY (GM/CC)
1CLE DIAM.MICHdS
GAS CDMPOSITIOMPF.HCENT ) J C02




SAMPLING
1.1120E-02 GR/OSCF
32 S3 SO
2 3 a
9,60 6,20 3.97
.30 .30 .70
CO
N2
02
H20
DURATION(MIN.)
?.4880E*oi MG/ACM
35 36 37
5 6 7
«?=!6 U«5 ,10
.60 1.20 2.20
1H.OC
1 .00
100.0
.00
.00
99 « OU
.00
1 .00
245.00
2.
38
8
.41
2.60








5446E+01 MG/OSCM
FILTER
9

2.30
  CUM. (MG/ACM) SMALLER THAN 050
  CUM. (M6/OSCM) SMALLER THAN 050
  CUM. (6R/ACF) SMALLER THAN D50
  CUM. (6R/DSCF) SMALLER THAN 050
  GEO. MEAN OIA. (MICROMETERS)
  DM/DL06D (MG/OSCM)
  ON/OL060 (NO. PARTICLES/DSCM)
3.29E»00
3.36E+00
I.44E-03
1.47E-03
3.30E*OJ
2.28E+01
 9.85E-02  9.B5E-02  2.30t-0l  1.97E-01  3.94E-01   7.23L-01   8.54E-01   7.56E-01
12.82     12.44     11.53     10.75      9.20       6.35       2.98
 3.I9E+00  3.09E»00  2.«7E»00  a.67E»00  2.29E*00   1.58t»00   7.41E-01
 3.26E*00  3.I6E»00  2.93E*00  2.74E*00  2.34E*00   l.b?t»00   7.58E-01
 1.39E-03  1.35E-03  1.25E-U3  1.17E-0?  l.OOE-03   6.90E-04   3.20t-04
 1.43E-03  1.38E-03  1.28(:-03  1.20E-03  1.02E-03   7.U6E-04   3.31E-04
 1.02t»01  7.72E»00  4.9frE»00  2.93E*0(»  1.50E»00   8.80t-0l   5.51E-OI   2.90E-OI
 1.81E«00  5.20E-01  1.19E+00  7.46E-01  1,25E*00   4.80E«00   3.33E»00   2.51E»00
 3.25E*06  2.1»>E*06  1.85E*07  5.67E»07  7.03E«08   1.35E*10   3.8IE»10   1.97EM1
STANDARD CONDITIONS ARE 20 DEGC AND 760MM HG.
AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO THt TASK GROUP UN LUNG DYNAMICS.

-------
       PLANT  ft  CITY

       SAMPLING LOCATION

       DATE

       RUN NUMBER

       OPERATOR

       STACK  TEMP.

       BAR.PRESS.(IN. HG)

       STACK  PRESS.(IN. HG)

       NOZZLEII.D.dN.)

       METER  HEAD OIFF.

   CALC. MASS  LOADING •  I.0872E-02  GR/ACF

   IMPACTOR STAGE

   STAGE  INDEX  NUMBER

   059  (MICROMETERS)
ASAUCO TACOMA

NO 4 SEC EX

01/18/63

  P38-1

00

  64.OF    18.UC

 29.53

 29.35

 .146

 .880
              SI

              I

           10.96
                  IMPACTUH FLOWHATf(AC*M)
                  AT 1MPACIOK CONDITIONS
                  1MPACTUW TEMP.

                  PAHTICLK ntNSITYlGM/CC)

                  MAX.PAKT1CLF. DIAM.MICHOS

                  GAS COMPI)SITION(PtHCbNT) !
                                              C02

                                              CO

                                              N2

                                              02

                                              H20
                  SAMPLING OURAT10N(M1N.)
   MASS  (MILLIGRAMS)                       67.00

   MG/DSCM/STAGE                            3.206+01

   CUM.  PERCENT OF MASS SMALLER  THAN  050   13.21
  1.1120E--02 GH/DSCF

  32        S3        34

  234

9.68      6.28      4.05

 .30       .30       .TO
   ,a«7

   18. OC

  1 .00

100.0

   .00

   .00

 99.00

   .00

  1.00

 245.00

     2.504bt»01 MG/DSCM

     38     FILTER

     8          9

    .49

   2.60      Z. JO
  CUM.  (MG/ACM)  SMALLER  THAN 050

  CUM.  (MG/DSCM)  SMALLER  THAN D50

  CUM.  (OR/AC?)  SMALLER  THAN 050

  CUM.  (GR/03CF)  SMALLER  THAN 050

  GEO.  MEAN OIA.  (MICROMETERS)

  DM/DLOGO (MG/DSCM)

  DN/OLOGD (NO.  PARTICLES/DSCM)
            3.29E*00

            3.36£*00

            1.44E-03

            1.47E-03

            3.31E+OI

            2.«9E*01

            1.21O06
                                  2.48»OE*Ol MG/ACM

                                 35        36         S7

                                 567

                               2.24      1.12  .      .82

                                .60      1.20      2.20

 9.85E-02  9.85E-02  2.30k-01  1.97E-01  3.94E-01  7.23E-01   6.54E-01   7.56E-01

12.82     12.44     11.53     10.75      9.20      6.35       2.98

 3.19E+00  3.09E»00  2.87E+00  2.67E+00  2.29b«00  1.5«E»00   7.41E-OI

 3.26E + 00  J.16E»l>0  2.93k«UO  2.74b»uo  2.34t«00  t.62E*00   7.58L»Ul

 1.39E-03  1.351-03  1.25E-03  I.17E-03  l.OOE-03  6.90E-04   3.24E-04

 1.43E-03  I.38E-03  1.2HE-03  1.20t-03  1.02E-03  7.06E-04   3.31E-04

 1.036*01  7.80E»00  5.04E+00  3.0lE»UO  l.59t*00  9.57E-01   6.29F.-OI   3.43E»OI

 1.83E»00  5.25E-01  1.20t»00  7.66E-01  1.32E*00  5.21E+00   3.7«E»00   2.51E«00

 3.20E»Ob  2.1lE+Oh  1.7<>E+07  5.36E+07  b.31E»08  1.14t»10   2.91t»10   I.19E*|1
•STANDARD CONDITIONS ARE 30 DEGC  AND  760MM  HG.

 AERODYNAMIC DIAMETERS ARE CALCULATED  HEfE  ACCORDING  TU  MERCEh.

-------
            IMPACTOR FIELD OAT*  (ADULATION

PLANT-NAME  AND ADDRESS                TEST TEAM LlAOtH

ASARCO TACOMA                         DO
TEST  PS8-I
      NO « SEC EX
ENGLISH UNITS





!
vo
ui


TEST DATE
TB
TF
TT
Y
ON
CP
PM
VN
TM
VM9TO
TIME-START
TIME-FINISH
NET TIME OF TEST,
METER CALIBRATION

MIN.
FACTOR
01
613
1401
245.
•
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER
VOLUME OF DRV GAS
TEMP
SAMPLED
108.
60.
107.
/lfl/H3
0
980
148 IN
84
88 IN-H20
975 CU-FT
6 F
136 SCF
MtTRIt UNITS
01
613
1401
24b.
•
3.
•
22.
3.
15.
3.
/ 1 H / e 3
0
980
«
84
a
Oftfa
9
034


MM

HM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BT VOLUME

FMD       MULE FRACTION DRY GAS

MD        MOLECULAR HT-ORY STACK GAS

MNS       MOLECULAR NT-STACK GAS

PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

T3        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
                                  1.082 SCF


                                  1.00

                                   .990

                                 28.73

                                 26.62

                                 29.53  IN-HG

                                 -2.50  IN-H20

                                 29.35  IN-MG

                                 64.    F

                                109.58  ACF
                         .031 SCM


                        1.00

                         .990

                       26.73

                       28.62

                      750.06  MM-HG

                      •63.bO  MM-H20

                      745.39  MM-HG

                       16.    C

                        3.10  ACM
AS
STACK AREA
2827.   SQ-IN
1.624 SO-M

-------
    ISO       PERCENT  ISOKINETIC


    MT        TOTAL MASS OF  PARTICLES


    PO        PARTICLE DENSITY


       •  60 DEG F,  39.92  IN.HG.
89.1


 1.191 GH



  .Ob  GK/CI
89.1


77.«iOU MG



 1.00  GM/CC
vo
en

-------
                     IMPACTOR RESULTS AND EXAMPLE CALCULATIONS
             PLANT-NAME AND CITY
             ASARCO TACOMA
             TEST DATE  01/16/83
                                 TEST  TEAM  LEADER
                                 DO
HUN NU
 PSH-I
SAMPLE LOCATION
NU « SEC tX
           CALC. MASS LOADING
vo
-J
                         TOTAL MASS  OF  PARTICLES DIVIDED HY A VULUME. UnITS GIVEN ARE GRAINS  PEH
                         ACTUAL* CUBIC  FOOT (Gfc/ACF ),CHAINS PEN DRY STANDARD" CUH1C FUOT (GR/DSCF ) ,
                         MILLIGRAMS  PER ACTUAL  CUBIC  ME IER(MG/ACM) AND MILLIGRAMS PER DRY  ST4NDARO
                         CUBIt METER(MG/DSCM.)
                EXAMPLE CALCULATIONS

                     CML(6R/ACF) « MT(GR) / IF(ACF)

                             CML »             1.191  /     109.?>T9  =

                    CML(GRXDSCF) * MT(GR) / VMSTD(DSCF)

                             CML *             1.191  /     107.136  *

                     CML(M6/ACM) * MT(M6) / IF(ACM)

                             CML s           77.300  /       3.103  =

                    CML1MS/OSCM) a MT(MG) / VMSTDCDSCM)

                             CML *           77.ZOO  /       3.034  =
                                                          .0109  GR/ACF
                                                          .0111  GM/OSCF
                                                                 MU/ACM
                                                                 MG/DSCM
           DSO (MICROMETERS)
                         THE SIZE OF  THE  PARTICLES ON EACH STAGE ASSUMING A SO PERCENT
                         COLLECTION EFFICIENCY  DEFINITION
           MASS (MILLIGRAMS)
                         THE MASS ON  EACH  STAGE  COLLECTED
           M6/D3CM/STA6E


                EXAMPLE CALCULATIONS

                     MG/DSCM/STAGE(1) s

                     MG/DSCM/STAGEU) c

           CUM. PERCENT OF MASS
EXAMPLE CALCULATIONS

     CUM X (6) = MA3S(7)
                         THE MASS LOADING  FOR  EACH STAGE. UNITS GIVEN ARE MILLIGRAMS
                         PEK DRY STANDARD  CUBIC  METER FOR EACH STAGE(MR/DSCM/STAGE)
                          MASS(l)  /  VMSID(DSCM)

                            67.00  /      3.034  =       22.01

                          THE PERCENTAGE  OF  THE TOTAL MASS SAMPLED SMALLER
                          IN DIAMETER THAN  THE  CORRESPONDING DbO INDICATED
                          FUR THAT  STAGE
     CUM X (6) •
                                           MASS(6)  » MASS(9)

                                           MT  (MG)

                                      2.ZO 4      2.60  »
                                      ^^^^^^«ft^^^^^^^^^^«»^**«»^<
                                               77.20   (MG)
                                               *  100  =
                                               2.30
                                                      100
   10.75

-------
           CUM. (MASS/VOLUME)
THE CUMULATIVE MASS LOADING Of PARTICLES  SMALLER  IN UlAMtTER
THAN THE CORRESPONDING OSO. MASS/VULUMt UNI IS  AWE  M
MG/DSCM,GR/ACF,GK/USCF.
                EXAMPLE CALCULATIONS

                     CUM.(M6/ACM)  (5)  e  MASS(6)  * MASS(7)  » MASS(8) * MASS(9)

                                                    IF(ACM)

                     CUM.(MG/ACM)  (5)  *       1.20 »      2.20 «      2.60 »

                                                         3.10  (ACM)
                                                           ,..(,7
           GEO.MEAN OIA. (MICROMETERS)
THE GEOMETRIC MEAN DIAMETER  IN MICHOHFTFHH
FOR A PARTICULAR StAliE.
                EXAMPLE CALCULATION

                     GEO.MEAN OIA.(J)  a  SORT(  D50(J)  * OSO(J-l))

                     GEO.MEAN DlA.(b)  =  SORT(      1.12 •      2.
                                    1.59
           OM/OLOGO(M6/OSCM)
VO
°°
DM IS M6/DSCM/STA6E (J) AND DLOGD  IS LOG10 (D5U ( J-l )  /
050(J)) WHERE J IS  THE CORRESPONDING  STAGE  NUMBER.
FOR STAGE 1 THfc MAXIMUM PARTICLE  DIAMETfcH  IS USED.
FOR STAGE 9 (BACKUP FILTER) THE 050 IS  ASSUMED  AS
.5 * 050 OF STAGE 8.
                EXAMPLE CALCULATION

                     DM/DLOGOU)  *    MG/OSCM/STA6E(J)

                                     LOG(  D50(J-1)  /  D50(J))

                     DM/OLOGD  (3) >                .10
                                   .........................   s
                                     LOG(       9.68 /      6.28 )
                                .53
           DN/OL06D                       THE  NUMBER  OF  PARTICLES PER UNIT VOLUME FOR A STAGE.

                EXAMPLE CALCULATION

                     DN/DLOGDU) •             OM/DLUGOU)

                                      5.23599E-10  * PD(GM/CC)  • GEO.MEAN OIA.(J)

                     DN/DL060  (3) *                  .53
                                     ..................... --- ..... — . ---   :
                                      5.235999E-10 *       l.UO  •       7. BO

      •   CALCULATED AT STACK  CONDITIONS
      ••  CALCULATED AT STANDARD CONDITIONS
      68 OEG.F AND 29.92  INCHES OF HG (760 MMHG)
                                           21la971.50

-------
                                                        FIELD  n*tA
PLANT ASAHCU TACOMA
SAMPLING LOCATION NO 4 SEC EX
SAMPLE TYPE PART SIZE BLOW
OPERATOR DU
AMBIENT TEMP. (DEC. F) 55.
BAR. PRESS. (IN.HG) 30.00
STATIC PRESS. (IN. H20) -3. 00
FILTER NUMBER(S) MARK III
STACK INSIDE DIM. (IN) 60.00 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3 .0 IN.HG
METER CALIB. FACTOR .960
READ S RECORD DATA EVERT 5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METEM VELOCITY ORIFICE PHESSUHE STACK
POINT TIME TIME READING HEAD DIFFERENTIAL TEMP
NO. (MIN.) (24-HR (CU.FT.) (IN.H20) (1N.H2U) (DEG.F)

> INIT 0
M 5.0
«> 10. 0
« 15.0
20.0
25.0
25.0
29.7
35.0
40.0
45.0
50.0
55.0
Wl_l/t,» 1
1004
0
0
0
0
1029
1121
1126
0
0
0
0
1416
DESIRED
495.032
497.500
499.660
502.240
504.600
506.973
516.781
519.016
521.540
523.900
526.260
528.630
530.989
.350
.450
.400
.300
.500
.500
.400
.600
.500
.500
.500
.500

.82
.82
.8?
.82
.82
.8?
.82
.82
.82
.82
.82
.82
ACTUAL

.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
DATE 01/20/83
HUN NUMBER P3H-2
PHUBE LENGTH ft TYPE 6' STEEL
NU12LE : 1.0. .148
ASSUMED M013TUKE 1.0
SAMPLF HO* NUMBEH
MEUH BOX NUMBEH FB9
MFJ1FH HF All OIFF. 2.06
PRUHE HEATkH SETTING 0.
HEATER HOX SETTING 0.
itHY GAS METER PUMP IMPACTUR IMPINGE*
TEMP VACUUM TEMP TEMP
IDEG.F) (IN.HG) (UEG.F) (DEG.F)
INLET UUTLET

63.
65.
63.
63.
61.
63.
66.
*><«.
63.
M.
62.
t>2.

47.
48.
50.
52.
55.
51.
55.
49.
4V.
51.
53.
56.

53.
53.
54.
54.
55.
55.
56.
55.
55.
55.
55.
56.

.5
.5
.5
.0
.0
.0
.0
.0
.0
.0
.0
.0

63.
65.
63.
63.
61.
63.
66.
64.
63.
63.
62.
62.

46.
• 6.
46.
47.
47.
46.
• 9.
49.
49.
50.
50.
50.
TOTALS
AVERAGE
55.0
26.149
                                        .82
                                .82
63.
51,
55.
63.
                                                                                                  48.
          PERCENT ISOKINETIC
                              99.5

-------
      PLANT ft CITY

      SAMPLING LOCATION

      DATE

      RUN NUMBER

      OPERATOR

      STACK TEMP.

      BAR.PRESS.(IN. H6)

      STACK PRESS.(IN. HG)

      NOZZLEM.D.UN.)

      METER HEAD OIFF.

   CALC. MASS LOADING s 4.6339E-02 GR/ACF

  IMPACTOR STAGE

 >STAOE INDEX NUMBER

 0050 (MICROMETERS)                      10
 o
  MASS (MILLIGRAMS)                      45

  MG/D3CM/3TA6E                           b

  CUM. PERCENT OF MASS SMALLER THAN 050  42
ASARCU TACUMA

NO 4 SEC EX

01/20/63


  PSB-2

00


  63.2F    17.3C

 30.00


 29.76

 .MB


 .820
                1MPACTUP FLOWMATt(»CFM)
                AT IMPArrUh CONDITIONS
                IMPACTU" TEMP.


                PAHT1CLE DtNSlTYtGM/tC)

                MAX.HAHTICLE OIAM.MICKOS

                GAS COMP()SITION(PEHCENT ) :
                SAMPLING DURAT1I)N(MIN.)


4.6597E-02 GR/OSCF              1
  CUM. (MG/ACM) SMALLER THAN 050

  CUM. (M6/OSCM) SMALLER THAN 050


  CUM. (6R/ACF) SMALLER THAN 050


  CUM. (6R/OSCF) SMALLER THAN 050


  6EO. MEAN OIA. (MICROMETERS)

  OM/DL06D (M6/DSCM)


  DN/OLOGO (NO. PARTICLES/DSC*)
 SI


 1

,44


,70

,07E*OI


,86


,55E*01


,57E*01


.99E-02


,OOE-02

,23E»01


,19E»01


,50E»06
                        S2
.60
          S3


          3


        5.96


         .60
                                             SO


                                             4


                                           3.BI


                                           1.30
  S5


  5


2.07


2.60
  S6


  6


1.00


8.80
                .461


       63.
-------
>
o
17. 3C
    PLANT ft CITY

    SAMPLING LOCATION

    DATE

    RUN NUMBER

    OPERATOR

    STACK TEMP.

    BAR.PRESS.(IN. HG)

    STACK PRESS.(IN. HG)

    NOZZLE! I.D.dN.)

    METER HEAD OIFF.

 CALC. MASS LOADING « 4.6339E-02 GR/ACF

IMPACTOR STAGE                            SI

STAGE INDEX NUMBER                        I

050 (MICROMETERS)                       10,52

MASS (MILLIGRAMS)                       45.70

MG/OSCM/8TAGE                           b.07E+01

CUM. PERCENT OF MASS SMALLER THAN D50  42.88
                                ASARCU TACOMA

                                NO 0 StC EX

                                01/20/83

                                  PSB-2

                                DO

                                  63. 2F

                                 30.00

                                 29.78

                                 .140

                                 .820
                             IMPACTOR FLOWHA1E
                             AT 1MPACTOH CONDITIONS
                             1MPACTOH TEMP.

                             PARTICLE r>ENSHV(GM/CC)

                             MAX.HAKTICLE OIAM.MICROS

                             li»S COMPOSITION(PEHCENT)!
                             SAMPLING nU»AT10N(MlN.)

             4.b597t-02 KR/OSCF

             32        S3        SO

             234

           9,29      bsQ3      3,89

            .bO       .80      1.30
              ,atj4

     fc3.i»F    17.3C

             I .00

           IUO.O

C02           .00

CO            .00

N2          99.00

02            .00

H20          1.00

             55.00

                1.0bb3E*02 MG/DSCM

                88     FILTER

                8         9
    CUM. (MG/ACM) SMALLER THAN 050

    CUM. (MG/OSCM) SMALLER THAN 050

    CUM. (GR/ACF) SMALLER THAN 050

    CUM. (GR/DSCF) SMALLER THAN 050

    GEO. MEAN DIA. (MICROMETERS)

    DM/OL06D (MG/DSCM)

    ON/OL060 (NO. PARTICLES/OSCM)
 4.55E»01

 4.57t»Ul

 1.99E-02

 2.00E-02

 3.24E*01

 b.21E«01

 3.47F.*Ob
                                   1.0bOlE«02 MG/ACM

                                 S5        Sb         37

                                 5         b          7

                               2.15       1,08        .78        ,«7

                               2.60       8.80      9.70       7.50       3.00

 7.97E-01  l.ObE*00  l.73E»00  3.45E+00   1.17E*Ol  l.d9E*01   9.9bE«00  3.99E*00

42.13     41.13     39.50     3b.25     25.25      13.13       3.75

 4.47E*OI  4.3bE*OI  4.19E+01  3.84E+OI   2.b8E*01  1.39E.+01   3.981*00

 4.49E+U1  a.39t»01  a.21E»Ul  3.87E»«1   2.b9E«01  1.40E«01   O.OOE»00

 1.95E-02  1.91E-02  1.B3E-02  l.bBE-02   1.17E-02  b.OBE-03   1.74E-03

 l.9bt-02  1.92E-02  1.84E-02  1.69E-02   1.18E-02  6.12E-03   1.75E-03

 9.89E»00  7.a
-------
              IMPACTOR FIELD DATA TABULATION

   PLANT-NAME AND ADDRESS               TEST TEAM LEADtH

   ASARCO TACOMA                         DO
   TEST  PSB-3
      NO 4 SEC EX

TEST
TB
TF
TT
Y
DN
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/30/83
1004
1016
55.0
.960
.146 IN
.84
.83 IN-M3U
METHIC UNITS
ui/30/63
1004
1410
5b.O
.980
3.6
.84
20.8


MM

MM-i
O
ro  TM
             DROP

>  VM        VOLUME OF DRY GAS SAMPLED
J.            AT METER CONDITIONS

            .AVERAGE GAS METER TEMP

   VMSTO     VOLUME OF DRY GAS SAMPLED
             AT STANDARD CONDITIONS*

   VNC       VOLUME OF WATER VAPOR
             AT STANDARD CONDITIONS*

   BNO       PERCENT MOISTURE BY VOLUME

   FMD       MOLE FRACTION DRY GAS

   MO        MOLECULAR NT-DRY STACK GAS

   MMS       MOLECULAR NT-STACK GAS

   PB        BAROMETRIC PRESSURE

   PSI       STATIC PRES OF STACK GAS

   PS        STACK PRES, ABS.

   TS        AVERAGE STACK TEMP

   IF        GAS SAMPLED AT
             STACK CONDITIONS
                                 36.149 CU-FT


                                 53.1   F

                                 36.495 SCF


                                   .368 SCF


                                  1.00

                                   .990

                                 38.73

                                 38.63

                                 30.00  IN-HG

                                 -3.00  IN-H3U

                                 39.76  IN-HG

                                 63.    F

                                 36.64  ACF
                         .740 CU-M


                       11.7   C

                         .750 SCM


                         .008 SCM


                        1.00

                         .990

                       36.73

                       36.63

                      763.00  MM-HG

                      -76.30  MM-H20

                      756.40  MM-HG

                       17.    C

                         .75  ACM
   AS
STACK AREA
3637.
                                                    SO-IN
                                                                    1.834 SO-M

-------
   190       PERCENT ISOKINETIC


   MT        TOTAL MASS Of PARTICLES


   PD        PARTICLE DENSITY


      •  68 DE6 F,  89.92 IN.HG.
10
O
U)
V9.5


 l.?35 GN


  .Ob  GK/tl
9V.b


80.000 HG


 I.00  GH/CC

-------
                    1MPACTOR  RESULTS AND EXAMPLE: CALCULATIONS
           PLANT-NAME  AND  CITT
           ASARCO  TACOMA
           TEST DATE   01/20/83
       TEST TEAM LEADER
       no
     HUN NU
                      SAMPLE  LOCATION
                      NU  4  SEC  tX
         CALC. MASS LOADING
N>
O
TOTAL MASS OF PAKTICLES DIVIDED  BY  A  VULUMfc.  UNITS GIVEN ARE GRAINS PEN
ACTUAL* CUBIC FOUT(GR/ACF)rGRA INS PEW DWY  STANUAHD** CUH1C FOOT (bH/OSCF ) .
MILLIGRAMS PER ACTUAL CUBIC METER(MG/ACM)  ANU MILUIGHAMS Ptn HHY STANDARD
CUBIC MtTEH(MG/DSCM.)
              EXAMPLE CALCULATIONS

                   CML(6R/ACF)  «  MT(6R)  / IF(ACF)

                            CML  •             1
                  CML(6R/DSCF)  s  MT(GR)  / VMSTD(DSCF)

                            CML  «             1.235 /

                   CML(MGXACM)  *  MT(MG)  / IF (ACM)

                            CML  =            80.000 /

                  CML(MG/OSCM)  s  MT (MG)  / VMSTD(DSCM)

                            CML  *            80.000 /
                 2b.b42 =        .Oab3   GR/ACF
                                        RR/DSCF
                    ,751 =     106.0496   MG/ACM
                    .750 =     106.6301   MG/DSCM
         050  (MICROMETERS)
THE SIZE OF THE PARTICLES ON EACH  STAGE  ASSUMING A 50 PERCENT
COLLECTION EFFICIENCY DEFINITION
         MASS  (MILLIGRAMS)
THE MASS ON EACH STAGE COLLECTED
         MG/DSCM/STAGE


              EXAMPLE CALCULATIONS

                   MG/03CM/STA6EU)  «

                   MG/DSCM/STAGEM)  =

         CUM. PERCENT OF M«SS
THE MASS LOADING FOR EACH STAGE. UNITS  GIVEN  AWE MILLIGRAMS
PER DRY STANDARD CUBIC METER FUR EACH STAGE(MG/OSCM/STAGE)
 MASS(l) / VMSTD(DSCM)

   05.70 /      .750 =
60.71
THE PERCENTAGE OF THE TOTAL MASS  SAMPLED  SMALLER
IN DIAMETER THAN THE. CORHE SPUNU ING  DbO  INDICATED
FOR THAT STAGE
              EXAMPLE CALCULATIONS

                   CUM X  (b)  2 MASS17)  »  MASS(8)  » MASSO)

                                          MT  (MG)

                   CUM X  (b)  «       9.70  *       7.50 »

                                              HO.00  (MG)
                     • 100  =
                     3.00
                          *  100   =   3b.25

-------
          CUM.(MASS/VOLUME)
THE CUMULATIVE MASS LOADING  OF  PAKlICLtS SMALLtK IN DIAMETER
THAN THE CURHESPUMOING  DbO.  MASS/VOl IIME UNlTij »HE MIJ/ACM,
MG/OSCM,GR/AtF,GH/USCF.
               EXAMPLE  CALCULATIONS

                    CUM.(MG/ACM)  (5)  = MASS(fc) + MASS(7) * MASS(B) •» MA33 CO

                                                  IF(ACM)

                    CUM.(MG/ACM)  (5)  =      8.60 *      V.7U »       7.50  *

                                                        .75  (ACM)
                                         3.00
                                                          S8.10
         GEO.MEAN  OIA.(MICROMETERS)
THE GEOMETRIC MEAN D1AME1EK  IN  MICNOMF. TENS
FOH A PARTICULAR STAGE.
               EXAMPLE  CALCULATION

                    GEO.MEAN OIA.(J)  3 SORTt ObO(J) • D^O(J-l))

                    GEO.MEAN OIA.(6)  = SURK     i.oe *      ?.i5)  =
KJ
O
cn
         OM/OL060(MG/OSCM)
DM IS Mt/DSCM/STAGE(J) ANO OLUGO  IS  LOG 10(050(J-J)  /
D50(J)) HHERE J IS  THE CORRESPONDING STAGE  NUMBER.
FOR STAGE I THE MAXIMUM PARTICLE  UIAMfUK IS USED.
FOR STARE 9 (BACKUP FILTER)  THE 050  IS  ASSUMED  AS
.5 • 050 OF STAGE 8.
               EXAMPLE  CALCULATION

                    OM/OLOGOU)  =    MG/DSCM/STAGE(J)
                                   LUG(  D50(J-1)  / D50(J))

                   OM/OLOGO  (S)  s               1.06

                                   LOG(       9.^9 /
                 --   f
                 t-.OJ )
                               5.66
         DN/DLOGO                       THE NUMBER OF PAhTlCLFS PER UNIT VOLUME FOR  A  STAGE.

               EXAMPLE  CALCULATION

                    DNXDLOGO(J)  •             OM/OLUGD(J)

                                    5.a3599E-10 * PD(GMXCC) • GEO.MEAN D1A.(J)

                    ON/DLOGD  (3)  =                5.66

                                    5.235999E-10 •      1.00  *       7,«9

     *   CALCULATED  AT  STACK  CONDITIONS
     *•  CALCULATED  AT  STANDARD  CONDITIONS
     60 DEG.F  AND 29.92 INCHES OF  HG (760 MMHG)
                                          2576908H.OO

-------
FIELD  DATA
PLANT ASARCO TACOMA
SAMPLING LOCATION NU 4 SEC EX
SAMPLE TYPE PART SIZE-BLOW
OPERATOR DO
AMBIENT TEMP.(DEG.F) 55.
BAR. PRESS. (IN. HG) 30.00
STATIC PRESS. (IN. H20) -3.00
FILTER NUMBER(S) MARK III
STACK INSIDE DIM. (IN) 60.00 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3
METER CALIB. FACTOR .980
READ « RECORD DATA EVERY 5.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT
NO.

INIT
1
to
o
en












TOTALS
AVERAGE

TIME
(MIN.)

0
5.0
10.0
15.0
20.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
60.1
70.1
BO.l
90.1
96.8
96.8

PERCENT
TIME
(24-HR

1616
0
0
0
1636
1734
0
0
0
1754
0
0
1836
0
0
0
2000


ISOKINETIC
READING HEAD
(CD. FT.) (IN.H20)

549.658
552.100
554.530
556.920
559.317
564.921
567.340
569.750
572.160
574.585
577.000
579.430
584.342
589.230
594.030
598.850
602.064
.400
.550
.400
.350
.300
.350
.300
.300
.300
.300
.300
.250
.250
.250
.250
.250
46.802

104.9
0 1N.HG
UHIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.82
.82
.02
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82

.82

H?0)
ACTUAL

.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82
.82

.82

STACK
TEMP
(DEG.F)


64.
63.
62.
62.
65.
66.
66.
65.
65.
72.
70.
69.
64.
64.
62.
63.

65.

DATE 01/20/83
RUN NUMBER PSB-3
PROBE LENGTH * TYPt 6* STEEL
NOZZLE : l.U. .148
ASSUMED MUISTUHE 1.0
SAMPLE BOX NUMHEH
METEH BOX NUMBEH F89
MF. TF.H HEAD OIFF. 2.08
PRUHE HEATEH SETTING 0.
HEATEH BOX SETTING 0.
OUT GAS METER PUMP IMPACTOR IMPINGEK
TEMP
((•EG
INLET

57.
58.
60.
61.
60.
58.
59.
60.
62.
60.
60.
61.
57.
58.
62.
65.

60.

.F)
OUTLET

61.
62.
62.
62.
*»3.
64.
64.
63.
64.
*>5.
65.
65.
63.
63.
63.
64.

63.

VACUUM
(1N.HG)


.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0

.0

TEMP
(DEb.F)


64.
63.
62.
62.
65.
66.
66.
65.
6S.
72.
70.
69.
64.
64.
62.
63.

65.

TEMP
(UEG.F)


50.
50.
51.
53.
53.
54.
54.
54.
55.
50.
48.
48.
48.
48.
49.
50.

51.


-------
to
o
    PLANT » CITY


    SAMPLING LOCATION


    DATE


    RUN NUMBER


    OPERATOR


    STACK TEMP.


    BAR.PRESS.(IN. HG)


    STACK PRESS.(IN. HG)


    NOZZLE * I.D.(IN.)


    METER MEAD OIFF.


 CALC. MASS LOADING * I.9633E-02 GR/ACF


IMPACTOR STAGE


STAGE INDEX NUMBER


050 (MICROMETERS)                       10


MASS (MILLIGRAMS)                       58


M6/D3CM/STAGE                           4


CUM. PERCENT OF MASS SMALLER THAN 050   2
                                 ASAKCU  TACOMA


                                 NO  q  SEC  EX


                                 01/80/03


                                  PSB-3


                                 00


                                  65.IF     16.QC


                                 30.00


                                 29.78


                                 .148


                                 .820
    CUM. (MG/ACM) SMALLER THAN 050


    CUM. (MG/DSCM) SMALLER THAN 050


    CUM. (GR/ACF) SMALLER THAN 050


    CUM. (GR/DSCF) SMALLER THAN 050


    6EO. MEAN DIA. (MICROMETERS)


    DM/DLOGD (MG/OSCM)


    DN/OLOGD (NO. PARTICLES/OSCM)
 SI


 I


,44



.20


,39E»01


.84



,28E»00


,29E«00


.57E-04


.62E-04



,23E*01


,47E*01


,53E«06
  1.9817E


  32


  2


9.21


 .20


1.51E-01


2.50


1.13E»00


I.10E»00


4.92E-04


4.96E-04



9.80E»00
                           IMPACTUK FLOHWATEI

                           AT IMPACTOH ClINPlTiriNS
                           IMPACtllW TEMP.


                           PAkUCLE DENS11Y1GM/CC)


                           MAX.PAKT1CLE D1AM.M1CKOS


                           GAS COHPOSITION(PEKCENI):   C02


                                                       to


                                                       N2


                                                       U2


                                                       H20


                           SAMPLING DURATION(MIN.)


                  •02 GK/OSCF             a.a9?8E«OI MG/ACM
  S3


  3


5.95


 .00
  SO


  4


3.81


 .00
                                                                                       S5
2.07


 .20
bb.lF    18.4C


        I .00


      1UO.O



         .00


         .00



       99.00


         .00



        1.00



        9b.80


           4.5348E»01 M6/D8CM



           S8     FILTER


           8         9


          .39



          .20        .60
 37


 7



.71



.20
                                                                 O.OOE*00  O.OOE+UO  l


                                                                 2.50      2.50      2.17
                                                  5.63E»06
                                 56


                                 fc



                               1.00



                                .30



                               2.?feE-bI   1.51t-0t   1.51E-01  4.53E-01


                               I.b7       1.34       1.00



I.I3E+00  1.13E>00  9.75C-01   7.50E-01   b.OOt-01   4.50E-01


1.1«E»00  1.14E«00  9.64E-01   7.57E-U1   b.Obt-01   4.54t»01


4.92E-04  4.92E-04  4.26E-04   3.28E-U4   2.b2E-04   1.97E-04



4.96E-04  4.96E-04  4.30E-04   3.311.-04   2.b5t»04   1. 986-04



7.10E*00  a.76E»00  2.81E»00   |.aat»oO   ».«lt-01   5.25£<>01  2.76E-01



0.00t»00  O.OOE»00  5.711-01   7. 171-01   I.o0t»00   5.85E-01  l.50E»00



O.OOE+00  O.OOF«00  4.93E«07   4.59E>08   3.21E^09   7.70E»09  1.37E«11
  STANDARD CONDITIONS ARE 20 DEGC AND 760MM HG.


  AERODYNAMIC DIAMETERS ARE CALCULATED HEHE ACCORDING  TO  THE  TASK  GROUP  ON LUNG DYNAMICS.

-------
                              ASARCO TACOMA

                              NO 4 SEC EX

                              01/20/63

                                P3B-3

                              DO

                                65. If

                               30.00

                               it.IB

                               .148

                               .820
18.4C
    PLANT » CITY

    SAMPLING LOCATION

    DATE

    RUN NUMBER

    OPERATOR

    STACK TEMP.

    BAR.PRESS.(IN. HG)

    STACK PRESS.(IN. HG)

    NOZZLEII.D.UN.)

    METER HEAD OIFF.

 CALC. MASS LOADING * 1.9633E-02 GR/ACF             1.98I7E.

IMPACTOR STAGE                            31        32

STAGE INDEX NUMBER                        I         2

090 (MICROMETERS)                       10.51      9.29

MASS (MILLIGRAMS)                       58.20       .20

Mt/DSCM/STAGE                           4.39E+01  1.51E-01

CUM. PERCENT OF MASS SMALLER THAN 050   2.84      2.50

CUM. (M6/ACM) SMALLER THAN 050          1.28E+00  1.1SE+00

CUM. (MG/DSCM) SMALLER THAN 050         1.29E+00  1.14E»00

CUM. (GR/ACF) SMALLER THAN 050          5.57E-04  4.92E-04

CUM. (GR/OSCF) SMALLER THAN 050         5.62E-04  4.96E-04

GEO. MEAN DIA. (MICROMETERS)            3.2at»01  9.88E«00

OM/DLOGO (MG/OSCM)                      4.49E»01  2.80E»00

DN/DLOGD (NO. PARTICLES/OSCM)           2.51E+06  5.54E«06
                             IMPACTUR  FLOWRATE(ACFM)
                             At  IMPACTlW  CUN01TIONS
                             IMPACIOM  TtMp.

                             PARTICLE  OENSIIY(GM/CC)

                             HAX.HAHTICLE 01AM.MICROS

                             GAS COMPUSITIOMPEKCENT):
C02

CO

N?

02

H20
                             SAMPLING DURATION(MIN.)
                                                             >02 GR/D3CF

                                                                S3        34

                                                                3         4

                                                              6.03      3.88

                                                               .00       .00
   .4Mb

   18. aC

  I .00

100.0

   .00

   .00

 99.00

   .00

  1.00

  96.80

     4.53«8E»01 MG/OSCM

     38     FILTER

     8          9

    .46

    .10       .60
                                            4,«928E»01 MG/ACM

                                           S5        36        S7

                                           567

                                         2.15      1.08       .78

                                          .20       .30       .20

                     O.OOE*00   U.OOL4UO   1.51E-01   2.26b-01   1.51E-01  1.51E-01  4.53E-OI

                     2.50       2.50       2.17      1.67      1.34      1.00

                     1.13E»00   I.15E»00   9.75E-01   7.50E-01   6.00E-01  4.50E-01

                     1.14E+00   1.14t»00   9.84E-01   7.571-01   6.06E-01  4.54E-01

                     4.92E-04   4.92E-04   4.26E-04   3.28E-04   2.62E-04  I.97E-04

                     4.96E-04   4.96E-04   4.30E-04   3.3U-04   2.65E-04  1.98E-04

                     7.48E>00   4.84t400   2.89E*00   1.52E*00   9.|8f»01  6.03E-01  3.29E-01

                     O.OOE»00   0.00t»00   5.86E-OI   7.55E-01   1.09E»00  6.67E-01  l.SOE^OO

                     O.OOE+00   O.OOE+00   4.65E+07   4.10E+OB   2.69E*0<»  5.82E»09  S.09E*IO
STANDARD CONDITIONS ARE 20 DEGC  AND 760MM HG.

AERODYNAMIC DIAMETERS ARE CALCULATED HERE ACCORDING TO MERCER.

-------
               IMPACTUR  FIELD  DATA  TABULAUUN
    PLANT-NAME  AND ADDRESS                TF.ST  TEAM  LEADER
    ASARCO TACOMA                          00
    TEST   PS8-3
                NO 4 SEC EX
O
vo

TEST
TB
TF
TT
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/20/83
1616
2000
96.8
.960
.146 IN
.64
.62 IN-H2U
METRIC UNITS
01/20/63
1616
2000
96.6
.960
3.8
.64
20.8


MM

MM-I
          DROP

VM        VOLUME OF DRV GAS SAMPLED
          AT METEH CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

MD        MOLECULAR NT-DRY STACK GAS

MN8       MOLECULAR MT-STACK GAS

PB        BAROMETRIC PRESSURE

P8I       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

T8        AVERAGE STACK TEMP

IF        GAS SAMPLED AT
          STACK CONDITIONS
  46.802 CU-FT


  61.6   F

  46.647 SCF


    .471 SCF


   1.00

    .990

  28.73

  28.62

  30.00  IN-HG

  -3.00  IN-H20

  29.78  IN-HG

  65.    F

  47.06  ACF
  1.325 CU-M


 16.4   C

  1.321 SCM


   .013 SCM


  1.00

   .990

 26.73

 26.6?

762.00  MM-Hb

-76.20  MM-H20

756.00  MM-HG

 IN.    C

  1.33  ACM
   AS
          STACK AREA
2827.   SO-IN
  1.824 SO-M

-------
  ISO       PERCENT ISOKINETIC


  MT         TOTAL MASS OF PARTICLES


  PD         PARTICLE DENSITY


     *   68 OE6 f,  29.92 IN.H6.
to
(-•
o
104.9



   .9i>4 G»



   .Ob  GH/CI
ioa.9


 59.900 MG


  1.00  GM/CC

-------
                   IMPACTOR RESULTS  AND EXAMPLE  CALCULATIONS
          PLANT-NAME AND CITY
          ASARCO TACUMA
          TEST DATE  01/20/83
       TEST TEAM LEADER
       DO
                                                           RUN  N(J
                                                            PSH-3
                   SAMPLE LOCATION
                   NO » SEC bX
        CALC. MASS LOADING
ro
TOTAL MASS OF PARTICLES DIVIDED BY  A  VOLUME.  UNITS GIVEN ARE GRAINS PER
ACTUAL* CUBIC FOOT(GR/ACF),GRAINS PER DRV  STANDARD** CUBIC  FOOT(GR/DSCF),
MILLIGRAMS PER ACTUAL CUBIC METEK(MG/ACM)  AND MILLIGRAMS PER DRV STANDARD
CUBIC METER(MG/DSCM.)
             EXAMPLE CALCULATIONS

                  CML(GRXACF) • MT(GR)  /  IF(ACF)

                          CML •              .924  /

                 CML(6R/DSCF) • MT(GR)  /  VMSTD(DSCF)

                          CML »            .  .424  /

                  CML(MGXACM) • MT(MG)  /  IF(ACM)

                          CML »           59.900  /

                 CMLCMS/OSCM) • MT(MG)  /  VMSTD(DSCM)
                          CML
        050 (MICROMETERS)
    59.900 /
                 47.063
                 46.647 =
                  1.333 =
                                            1.321 =
                                                          .0196   GR/ACF
                                                          .0198   GR/DSCF
                                                        44.9281   MG/ACM
45.3476  MG/DSCM
THE SIZE OF THE PARTICLES UN EACH  STAGE  ASSUMING  A  SO  PERCENT
COLLECTION EFFICIENCY DEFINITION
        MASS (MILLIGRAMS)
THE MASS ON EACH STAGE COLLECTED
        MG/DSCM/STAGE
THE MASS LOADING FOR EACH STAGE. UNITS  GIVEN  ARE  MILLIGRAMS
PER DRY STANDARD CUBIC METER FOR EACH STAGE(MG/DSCM/STAGE)
EXAMPLE CALCULATIONS

     MG/DSCM/STAGE(1) =   MASS(l) / VMSTD(DSCM)

     MG/DSCM/STAGEd) >     56.20 /
                                                      1.321  =
                            43.91
        CUM. PERCENT OF MASS
THE PERCENTAGE OF THE TOTAL MASS SAMPLED  SMALLER
IN DIAMETER THAN THE CORRESPOND ING 050  INDICATED
FOR THAT STAGE
             EXAMPLE CALCULATIONS

                  CUM I (6) e MASS(7) » MASS(8)  » MASS(9)

                                        MT  (MG)

                  CUM X (6) »        .20 »        .20  *

                                            59.90   (MG)
                     • 100  =
                      .60
                          •  100  =    2.17

-------
         CUM.(MASS/VOLUME)
THE CUMULATIVE MASS LOADING OF PARTICLES  SMALLER  IN DIAMETER
THAN THE CORRESPONDING 050. MA33/VULUME UNITS  ARE  MG/AC",
MG/USCM,GR/ACF,GK/USCF.
              EXAMPLE CALCULATIONS

                   CUM.(MGSACM)  (5) s MASS(6)  »  MASS(7)  »  MASS(8)  «•  MASS(9)

                                                  IF(ACM)

                   CUM.(MK/ACM)  (5) =        .30  *        .20  »        .rfO »

                                                       1.33  (ACM)
                                          .60
                                                            .98
 I
M
         CEO.MEAN DIA.(MICROMETERS)
THE 6EUMETRIC MEAN DIAMETER  IN MICROMETERS
FOR A PARTICULAR STAGE.
              EXAMPLE CALCULATION

                   CEO.MEAN DIA.(J) c SURTt  050(J)  •  U51MJ-1M

                   GEO.MEAN DIA.(6) = SUHTC      i.oa  •       2.
                                    1.52
         OM/OL060CM6/09CM)
DM IS MG/DSCM/STAGE(J) AND OLUGO  IS LOG10(DSO(J-l)  /
050(J)) WHERE J IS THE CORRESPONDING  STAGE  NUMBER.
FOR STAGE 1 THE MAXIMUM PARTICLE  DIAMFTEH  IS USED.
FOR STAGE 9 (BACKUP FILTER) THE DSO IS  ASSUMED  AS
.S • DSO OF STAGE 0.
              EXAMPLE CALCULATION

                   DM/OL06DCJ) =   MG/DSCM/STAGEU)

                                  LOG( D50(J-1)  /  DSO(J))

                   DM/OL06D (3) c                .00

                                  LOG(      9.29 /
                 --   x
                 6.03 )
                                .00
         DN/DLOGD                      THE NUMBER OF PARTICLES  PER  UNIT  VOLUME  FOR A STAGE.

              EXAMPLE CALCULATION

                   DN/DL060U) s            OM/DLUGDU)

                                   S.23599E-10  * PD(GMXCC)  * GEO.MEAN  DIA.(J)

                   DN/DL06D (3) *                 .00

                                   b.235999E-10 •       1.00  •        >.a8

    •   CALCULATED AT STACK CONDITIONS
    **  CALCULATED AT STANDARD CONDITIONS
    68 OE6.F AND 29.92 INCHES OF HG  (760 MMHG)
                                                  .00

-------
                                                            FIELD  DATA
ro
M
U)
PLANT A3ARCU TACOMA
SAMPLING LOCATION NO 4 SEC EX
SAMPLE TYPE PAHT SIZE-BLOW
OPERATOR DU
AMBIENT TEMP. (OEG.F) 55.
BAR. PRESS. (IN. HG) 29.70
STATIC PRESS. (IN. H20) -3.00
FILTER NUMBER(S) MARK 111
STACK INSIDE DIM. (IN) bO.OO .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a
METER CALIB. FACTOR .980
READ I RECORD DATA
TRAVERSE
POINT
NO.

INIT


























SAMPLE
TIME
(MIN.)

0
5.0
10.0
15.0
15.0
20.0
25.0
25.0
30.0
40.0
50.0
60.0
70.0
70.9
7B.5
90.0
100.0
10B.9
120.0
130.0
140.0
146.5
160.0
170.0
160.0
190.0
199.9
CLOCK
TIME
(24-HR
ft f!f*K %
l*L vl*™ J
1607
0
0
1622
1706
. 0
1716
1739
0
0
0
0
0
1626
1903
0
0
2036
0
0
0
2116
0
0
0
0
2211
EVERY 5.0
GAS METER
READING
(CU.FT.)

615.937
618.320
620.710
623.046
628.738
631.170
633.577
640.409
642.620
647.650
652.990
657.850
662.710
663.137
667.191
672.720
677.550
681.640
687.240
692.100
696.970
701.097
706.630
711.510
716.400
721.280
725.648
MINUTES
VELOCITY
HEAD
(IN.H20)


.450
.30V
.400
.500
.300
.350
.500
.500
.500
.500
.500
.550
.500
.550
.550
.550
.550
.550
.550
.500
.550
.550
.550
.550
.450
.550
0 IN.HG

ORIFICE
OATE 01/22/83
HUN NUMBER PSB-4
PHUBE LENGTH H TYPE 6* STtEL
NOZ7LE : l.U. .148
ASSUMED MOISTURE 1.0
SAMPLE BOX NUMBER
METER BOX NUMHEP FB9
METER HEAD OIFF. 2.08
PROBE HEATER SETTING 0.
HEATER BUX SETTING 0.

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.82
.82
.82
.82
.62
.62
.02
.82
.82
.82
.82
.82
.62
.82
.82
.82
.82
.82
.82
.82
.82
.62
.82
.62
H2U)
ACTUAL

.62
.82
.62
."2
.82
.82
.82
.82
.82
.82
.82
.62
.82
.82
.62
.82
.82
.82
.82
.62
.82
.82
.82
.62
.82
.«2

STACK
TFMP
(OEG.F)


64.
62.
63.
63.
63.
63.
63.
66.
64.
62.
62.
63.
62.
56.
62.
62.
60.
69.
64.
62.
61.
69.
63.
62.
61.
61.

OUT GAS

METER
TEMP
(DEC
INLET

46.
«9.
50.
60.
53.
53.
60.
58.
61.
64.
65.
65.
67.
56.
54.
56.
59.
61.
62.
64.
65.
64.
65.
66.
66.
67.
.F)
OUTLET

54.
54.
54.
61.
58.
58.
61.
60.
61.
62.
63.
64.
65.
64.
60.
60.
60.
61.
62.
63.
63.
64.
65.
65.
65.
66.

PUMP
VACUUM
(IN.HG)


.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0

IMPACTUR
TEMP
(OEG.F)


64.
62.
63.
63.
63.
63.
63.
66.
64.
62.
62.
63.
62.
56.
62.
62.
60.
69.
64.
62.
61.
69.
63.
62.
61.
61.

IMPINGER
TEMP
(DEG.F)


49.
49.
49.
49.
50.
50.
51.
47.
47.
47.
47.
48.
46.
48.
45.
45.
45.
45.
45.
46.
46.
47."
47.
47.
45.
45.
   TOTALS
   AVERAGE
199.9
97.189
                                          .62
                                .62
63.
6V.
                                                                          61.
                                                                .0
                                63.
                                  47.
             PERCENT ISOKINETIC
                               96.6

-------
                              ASARCO TACUMA


                              NO 4 sec ex


                              01/22/83


                                PSB-0


                              DO


                                62.9F    17.2C


                               21.70


                               29.48


                               .148


                               .820
       PLANT & CITY


       SAMPLING LOCATION


       OAT6


       RUN NUMBER


       OPERATOR


       STACK TEMP.


       BAR.PRESS.(IN. M6)


       STACK PRESS.(IN. HG)


       NOZZLElI.D.dN.)


       METER NEAO DIFF.


    CALC. MASS LOADING » 5.4737E-03 GR/ACF             5.55766-


   IMPACTOR STAGE                            81        S2


   STAGE INDEX NUMBER                        1         2


>  090 (MICROMETERS)                      10.40      9.18

 I
to  MASS (MILLIGRAMS)                      31.40       .00
\->

**  MG/D3CM/8TAG6                           1.156*01  0.006*00


   CUM. PERCENT OF MASS SMALLER THAN 050   9.25      9.29


   CUM. (MG/ACM) SMALLER THAN OSO          1.166*00  1.166*00


   CUM. (M6/08CM) SMALLER THAN 050         1.18E»00  1.186*00


   CUM. (GR/ACF) SMALLER THAN 050          5.066-04  5.066-04


   CUM. (GR/08CF) SMALLER THAN 050         5.10E-04  5.14E-04


   CEO. MEAN DIA. (MICROMETERS)            3.236*01  9.776*00


   OM/OLOGD (MG/DSCM)                      1.17E+01  O.OOE*00


   ON/DLOGO (NO. PARTICLE8/D3CM)           6.666*05  0.006*00
        IMPACTUH FLOWRATE(ACFM)
        •T IHPACTOK CONDITIONS
        IMPAC1UR TEMP.

        PARTICLE OEN3ITY(GH/CC)

        MAX.PAHTICLE DIAM.MICROS

        GAS COMPUSITION(PERCENT):
        SAMPLING OURATION(MIN.)
                                                             •03 GR/DSCF


                                                                S3        SO


                                                                3         4


                                                              5.93      3.79


                                                               .50       .30
              .488


     62.9F    17.2C


             1.00


           100.0


C02           .00


CO            .00


N2          99.00


02            .00


H20          1.00


            199.90


                1.2718C+01 MG/DSCM


                38     FILTER


                8         9


               .39


               .80       .BO
                        1.252be»01 MG/ACM


                      35        36         87


                      567


                    2.06      1.00        .70


                     .20        .30        .30


1.83E-OI  1.10E-V1  7.33E-02  1.10E-01  I.10E-OI   2.936-01   2.936-01


7.80      6.94      6.36      5.49      4.62       2.31


9.77C-01  8.69e-OI  7.96C-01  6.88E-01  5.79E-OI   2.90E-01


9.92E-01  8.82E-U1  8.096-01  6.98E-01  5.886-01   2.94E-01


4.27E-04  3.80E-04  3.486-04  3.01E-04  2.536-04   1.276-04


4.346-04  3.85E-04  3.536-04  3.056-04  2.576-04   I.286-04


7.386*00  4.74E«00  2.806*00  I.43E«00  8.386-V1   5.236-01   2.756-01


9.666-01  5.666-01  2.776-01  3.486-01  7.286-01   1.13fc»00   9.73E-01


4.596*06  1.01t»07  2.426*07  2.256*08  2.366*09   1.516*10   B.«TE»|0
STANDARD CONDITIONS ARE 20 DEGC  AND 760MM HG.


AERODYNAMIC DIAMETERS ARE  CALCULATED HER6 ACCORDING 10 THE TASK  GROUP ON LUNG DYNAMICS.

-------
                               ASAKCD IACUMA
                               NU  a  stc  KX
  PSH-<4

DO


 29.70


 .148

 .820
    PLANT K CITY

    SAMPLING LOCATION

    DATE
    RUN NUMBER
    OPERATOR

    STACK TEMP.
    BAN.PRESS.(IN. MG)

    STACK PRESS.(IN. HG)

    NOZZLEM.o.(IN.)

    METER HEAD DIFF.
 CALC. MASS LOADING = 5.4737E-03  GN/ACF

IMPACTOR STAGE

STAGE INDEX NUMBtR

050 (MICROMETERS)

MASS (MILLIGRAMS)

MG/D3CM/STAGE
CUM. PERCENT OF MASS SMALLER  THAN 050

CUM. (MG/ACM) SMALLER THAN  050

CUM. (MG/DSCM) SMALLER  THAN 050

CUM. (GR/ACF) SMALLER THAN  05U

CUM. (GR/OSCF) SMALLER  THAN 050

6EO. MEAN OIA. (MICROMETERS)

DM/DL060 (MG/DSCM)

DN/DLOGO (NO. PARTICLES/OSCM)
                                         IMHALIIIU FLMH4ATL ( ATFM)
                                         A! INiMACIMH CONDI T IIINS
                                             SI

                                             1

                                          10.48

                                          31.40

                                           1.15E*01

                                           <».85
                                           1 .tt.E»00
                                           1 .lflt«00

                                           5.06fc-0«
                                           5.14E-04
                                                                        HAK11CI>  DKNbl I Y (f'M/CC)

                                                                        MAX.HAKUCLE 01 AM. MICROS

                                                                        GAS CDMMUSI T IIIN(PhKCENl ) !
hb      b.OI       3.87

 .00       .50        .30

o.oot+oo  i.HSE-oi   i.int-ui

9.25      7.HO       b.9«

l.lbb+00  9.77E-01   t

1.1HK»00  V.42F.-01   ^

5.0bt-00  4.27t-04   3.80E-04   3.48E-04  3.01L-04   2.b3t-04  1,27t-0«

          4.34t-04   3.8Sf04   3.53E-04  3.0bt-«4   2.57f04  1.2«E-00

          /.4hk»00   4.8?L»00   2.8HE*00  l.tj?E»00   9.1SK-01  b.Ott-Ot  3.28E-OI

          «».7bE-01   5.7bk-01   2.85L-01  3.bhE-Ol   7.92E-01  1.30t»00  9.73E-OI

          <*.4«»E»Ob   9.7t)K»Ob   2.21t»07  2.01K»ufl   1.98t*09  1.I4E»10
                       O.UOL+UO

                       0.00t+0d
STANDARD CONDITIONS ARE ?0 DEGC  ANU  7hOMM HG.

AERODYNAMIC DIAMETERS ARE CALCULATED HE"K. ACCOMDING 10 Mt»«lEM.

-------
            1MPACTUR  FIELD  DA1A TAHIILATJUN

PLANT-NAME  AND  AOORtSS                TFST TEAM

A9ARCO TACOMA                          0(1
TEST  PSB-0
                 NU  a  StC  EX

TEST
TB
TF
TT
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TFST, MIN.
METER CALIBRATION FACTON
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
01/22/H3
1607
199.9
.9dO
.!t'/h3
ibur
199.9
.9«0
3.« MM
.««
20.8 MM-
TM

VMSTO


VMC


BNO

FMD

MO

MNS

PB

PSI

PS

TS

IF
DROP

VOLUME OF ORT  GAS  SAMPLED
AT METER CONDITIONS

AVERAGE GAS METER  TEMP

VOLUME OF DRY  GAS  SAMPLED
AT STANDARD CONDITIONS*

VOLUME OF WATER  VAPOW
AT STANDARD CONDIUONS*

PERCENT MOISTURE BY  VOLUME

MOLE FRACTION  DRY  GAS

MOLECULAR MT-DRY STACK GAS

MOLECULAR NT-STACK GAS

BAROMETRIC PRESSURE

STATIC PKES OF STACK GAS

STACK PRES. ABS.

AVERAGE STACK  TEMP

GAS SAMPLED AT
STACK CONDITIONS
97.IB9 CU-f-T


60.6   F

96.077 SCF


  .970 SCF


 I .00

  .990

2H.73



29.7u  IN-HG

-3.00  IN-H20

29.08  IN-HP,

63.    (•
                                                                         CU-M


                                                                  15.9   C

                                                                   2.721 SCM


                                                                    .027 SCM


                                                                   I .00

                                                                    .990
                                                                     3W  MM-Hb

                                                                 -76. iV  MM-Hc'O

                                                                 70B.78  MM-HO

                                                                  17.     t

                                                                   i.lb  ACM
          STACK AREA
                                          t!«i»7.   SU-IN
                                                                         S'1-M

-------
 ISO        PbRCENT ISOKINMIC



 MT         TOTAL MASS UF  PAHTICUS



 PD         PARTlCLt DENSITY



    •  60 UEG f,  29.9,?  IN.HG.
 I
to
(-•
•~J
.Ob  I;K/LI
)U.b(IU Ml




 I .11(1

-------
                     IMPACTUR  Rtf SUITS AND EXAMPLI  C Al CIIL A T | U
             PLANT-NAME AMP CITY
             ASARCO TACUMA
             TEST DATfc  01/22/83
                                       TtS I  IEAM  Lt AOfck
                                       1.1)
SAMPLE LUC A I ION
Nil 0 SEC  t X
00
           CALt.  MASS LOADING
                EXAMPLE CALCULATIONS

                     CMUGR/ACF)  =  MT(G») / IF(ACF)

                             CML  =               ,5J«  /      97.b'jO =

                    CML(G»/DSCF)  a  MT(GH) / VMSTrMUSff-)

                             CML  =               .530  /      9b.u7f =

                     CMLCMG/ACM)  =  MT(MG) / IF(ACM)

                             CML  =            3<*.bOO  /       2.7h«? =

                    CML(Mi;/DSCM)  =  MT(MG) / VMSTD(DSCM)

                             CML  =            3«.bOO  /       2.721 =
                                TOIAL MASS OF PARTICLES UIVIOEU HY  A  VOLUME. OHMS  GIVEN Akt GRAINS PER
                                ACIUAL* CUHIC FUUT (Gk/ACF ) DRAINS PhH IIKT STANI)AHM««  ClltUC MjD T (liH /1>SCF ) ,
                                MILLI'iHAMS PEW  Af.rUAl. CUHIC METFM (Mli/ACM) AfJI) MTLl.ir,k»MS Pfctf DKY
                                CUHIC Mt f E
                                                                         P.k/ACF
                                                                  .0056   Gk/USCF
                                                               I?.7176   MG/UStM
          050  (MICROMETERS)
                                THE  Slit OF THt PARTICLES ON EACH  STAGE  ASSUMING  A  bO
                                COLLECTION EFFICIENCY  DEFlNIilUN
          MASS  (MILLIGRAMS)
                                THE  MASS ON EACH  STALE  'OLLFCTED
          M6/USCH/STAGE
                                THE  MASS LOADING FOR  EACH STAGE. UNITS  GIVEN ARE MILLIGRAMS
                                PEN  UMY STANDAkl) CUBIC  METEH FUR EACH  S T AGE (MG/DSCM/S T AGE )
     EXAMPLE  CALCULATIONS

          MG/DSCM/STAGEU) =    MASS(l) / VMSTIHUSCM)

          MG/DSCM/STAGE(1) =      31.40 /

CUM. PERCENT  OF  MASS
                                                                        1 1 .50
                                          THE PERCENTAGE  OF  THE TOTAL MASS  SAMPLEO SMALLER
                                          IN DIAMETER  THAN THE CO»RF SPUNDI Ni: 1)50 INPITATEI)
                                          M)K THAT  STAGE
                EXAMPLE CALCULATIONS

                     CUM X (b) = MASS(7)  + MASS(R)  »  MASS19)

                                            MT (Hli)

                     CUM X (h) =        .30 »        .80  »        .80

                                                40.hU   (MH)
                                                      •  100  =
                                                           • 100  =

-------
            CUM.(MASS/VOLUME)              THE  CUMULATIVE MASS LOADING  OF  PAH1ICI.KS SMALLt"  IN  UlAMtlb«
                                            THAN I Hfc  COHRFSPUNUINi; ObO.  MASS/VOI.U^t UMTS
                                            MG/OSCM.l.W/ACF ,
                  EXAMPLE  CALCOLATIONS

                       CUM.(MGXACM) (S) = MASS(b)  *  MASS(7) » MASS(B)  »  MASS(9)

                                                      1F(ALMJ

                       CUM.(MGXACM) (5) =        .30  *        .30 »        .80  »        .BO
                                          	   =         >eo
                                                           ?./b  (ACM)


            GEO.MEAN  D1A.(MICROMETERS)     IHE  GEOMETRIC MFAN 01AMEILM  IU  M1CKDMF. I EMS
                                            FUH  A  PAMTK.ULAU STAUb.

                 EXAMPLE  CALCULATION

                       GEO.MEAN UIA.U) = SURTC o^ouj  * usu(j-it)

                       GEO.MEAN ou.rb) = SUHTC      i.o; •      z.iaj   =       i.Se;

 i
J^          DM/DLOGDCMG/DSCM)               OM IS  MG/DSCM/STAGE(J) AND OLOGO  IS LOb1U(05U(J-I) /
VO                                          DSO(J))  HHtHE J IS THE COtfHFSPONUlNIi SfAGF NUMHFH.
                                            FOK  STAGE  1  THE MAXIMUM PAHTICLE  DIAMfctEK IS USED.
                                            FOH  STAGE  t  (HACKHP FILTER)  THE 050 IS ASSUMED »S
                                            .i • D-jO OF  STAGt B.

                 EXAMPLE  CALCULATION

                       OM/OLOGDU) =   MG/DSCM/STAGF.CJ)

                                      LUG(  ObO(J-l) / DbO(JJ)

                       OM/OLOGO (3) =                .18

                                      LUG(      9.5 UEG.F AND  <>9.92 INCHES OF HG ChO MMHb)

-------
    END OF PHUliHAM
    :FlLt FTNtO = CIUH01DA,OU»
    :FILE
    :RUN
    END OF PROGRAM
    :FILE
    :FILE FTNn9=CIOROai)A,OLO
    :RUN
 I
ro
to
o

-------
 ,a9F.»OU
 .51E»00
 .50E»00
 .55E*00
 .57E»00
 .5HF.»00.
 .66E*OU
 .73E*00
 .7hE»00
 ,78E»OU
 .81E»00
I .8«E»00
1 ,9SK«00
2.0HE»00
2.56E»00
                   3.0bF-01
                        -01
                   0.93E-01
                   5.45E-01
                   h.01F-01
          AS ARCO AVERAGE  PARTICLE  SI/E IHS rw IHOt IONS
RMOs 1.00 GM/CC
                        MEAN CUMIILAtlVt   UHftH CUNFIUENCt
INTERVAL   D1AMETEH   MASS  CONCENTNAIIUN      LiHll
           (MICKIINS)        (Mf./ACM)            (MC./AtM)

                            2.73E-01
                            2.95E-01
                            3.20E-01
                            3.49E-01
                            3.8?E-OJ
                            0.20E-01
                            4.62E-01
                            5.09E-01
                            5.61E-01
                            6.17E-01
                            b.78E-01
                            7.43E-OI
                            8.I2E-01
                            8.8bE-01
                            9.37E-01
                            9.72E-01
                            l.03E*00
                            1.10E+00
                            1 ,I7E*00
                            1.23E»00
                            1.29E»00
                            1.33F + 00            , 19
1 20
K) ji
M 22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
07
08
09
50
51
52
2.50E-01
2.7IE-01
2.95E-01
3.20E-01
3.47E-01
3.77E-01
4.09E-01
4.45E-01
4.83E-01
5.24E-01
5.69E-01
6.18E-OI
6.71E-01
7.28E-01
7.91E-01
8.58E-01
9.32E-01
I.OIE'OO
1.10E»00
1.19E+00
1.29E»00
1.41E+00
1.53E*00
1.66E+00
I.80E+00
1.95E»00
2.I2E+OU
2.30E+00
2.50F.»00
2.71E«00
2.95E»00
3.20E+00
3.47E»00
3.77E«00
4.09E*00
a.45E+00
0.83E»00
5.24E«00
5.b9£»00
6.18E»00
6.ME»00
7.28E«00
7.91E»00
8.58E»00
9.32E«00
.01E»OI
,|OE»01
.19E«01
.29E»01
.01E»01
.53E*01
l.»»bE*01
                   7. 50E-01
                   H.OJE-"!
                   B.78E-01
                   9.59E-01
                    .01E+OU
                    .1 1E»00
,haF.»OU
.b7E»OU
,h9F.«00
.ME»«0
.75E»00
,7fE»00
.7-*F.«00
,8<«E»OU
.8I>K«UU
,b9F.»OU
                                       W CONFIOtNtE
                                        LIMIT
                                       I'M,/ACM)
                                       3.31E-01
                   l.itt-Ot
                   a.736-01
                   5. / IC-OI

                   b.»«E-01
                   «.b«E-OI
                                         0 I E * 0 1)
                                        .13E+UO
                                        ,1HE»00
                                         c!bE»00
                    ,3at»oo
                    ,3bE»UO
                    .376*00
                    .39E»00
                                                                   .08E+00
                                                                   ,«3E»00
                                        .«JOE*00
                                        ,b2E»00
                                        .•j«E»00
                                                                   .bOE»00
                                                                   ,b3E»UO
                                                                   ,b5E»00
                    ,70E»00
                    ./5E*00
                    .77F. + UO
                                        .i ;F.«OO

-------
     53       1
     54       1.9bE»01         3.9bF.»UU           9F»00           H.hVF«00            7.^'»E*(Mi
     59       2.95E»01         9.h5F»00           1.0bF«01            H.rtltt»00
     60       3.2UE*01         1.13t»01           1.231*01            l.oat*01
     61       3.47E*01         1.3IF+U1           l.«lf+01
     62       3.77E*01         J.fl«»F.»01
     63       0.09E+01         l.bflE«Ol
     64       4.45E»01         l.flbE»01
     65       4.83E»OI         2.05F+U1
     66       5.24E«OI
     67       5.69E»01
     68       6.18E + 01         ?.SbE + OI           r'./lF + 'M
     69       b.71E + 0!         2.72E*01           ?.B/E*OI            c!.bbE»01
     70       7.28E*01         2.8bE*Ul           ^.OdF+IU            c*.7nt»ti1
     71       7.91E*OI         3.00E*01           ».lbf*«'l
     72       8.58E»01         3.12E*01           3.2BE*01
     73       «».32E»01         3.2JE«01           3.«Ut»01            3.<)7E»01
10
to
to

-------
           ASARCO AVERAGE PARTICLE SI78  OlStHlHul I (INS
RHO« 1.00 6M/CC
INTERVAL   OIAMETEH     HtCOROS EXCLUDED fHUM MtAN
                       CUMULATIVE MASS) CONCI-N I h A M(1N
1
2







10
11
12
13
14
15
16
17
18
19
20
te 21
1 22
ro 23
K 2a
25
26
27
28
29
30
31
32
33
34
35
36
37
36
39
40
41
42
43
44
45
46
47
46
49
50
51
52
53
2.50E-01
2.71E-01
2.95E-OI
3.20E-01
3.47E-01
3.77E-01
4.09E-OI
4.45E-OI
4.83E-01
5.24E-01
5.69E-01
6.18E-01
6.71E-01
7.28E-01
7.91E-01
8.58E-01
9.32E-01
.01E»00
,IOE*00
,19E»00
,29E«00
,41E*00
,53E*00
.bbE»00
,fll;E»00
.95E»00
2.12E«00
2.30E*00
2.50E«00
2.71E»00
2.95E«00
3.20E«00
3.47E»00
3.77E*00
4.09E»00
4.45E«00
0.83E+OU
5.24E«OU
5.69E«00
6. I8E»00
6.71E*00
7.28E«00
7.91E*00
8.5BF«00
9.32E»00
.OIE«01
.10E«01
.19E»Ot
.29E*01
.4IE401
.53E*01
.b6E«Ul
. 8Ut »01
4
4








4
4
4
4
2
2
4
4
4








4
4
4
4
4
?
4
4
4
4
4







4
4
4
4
4
4
4
4














4
4

















-------
50
55
56
57
56
59
60
61
62
63
60
65
66
67
68
69
70
71
72
73
1.95E»01
2.12E+01
2.30E+OI
2.50E*01
2.71E»01
2.95E*01
3.20E+01
3.«7E»OI
3.776*01
0.09E*01
fl.*5E*01
fl.83E»01
5.24E^OI
5.69E»01
6.1SE+01
6.7IE»01
7.28E»01
7.91E*Ol
e.5«E»OI
9.32E*Ot
                            a
                            a
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
                           NONE
N>
ro

-------
ASARCO AVERAGE PARTICLt SIZE DISTRIBUTIONS

                               UHPhR  CUNFIUENCE
                            ON      LIMIT
                                   IPEkLtNT)
                                    5.9bF-Ol
RHO« 1.00

INTERVAL

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
> 20
1 21
M a
1° 23
in f3
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
GM/CC

DIAMETER
(MICRONS)
2.50E-U!
2.7IE-01
2.95E-01
3.20E-01
3.47E-01
3.77E-01
4.09E-01
4.45E-01
4.83E-01
5.24E-01
5.69E-01
6.18E-01
6.71E-01
7.28E-01
7.91E-01
8.5BE-01
9.5«>E-01
1.01E*00
1.IOE+00
1 ,19E*00
1.29E*00
1.41E*00
1.53E«00
1 ,66E*00
1.80E«00
1.95E*00
2.12E*00
2.30E*00
2.50E*00
2.71E*00
2.95E*00
3.20E+00
3.a7E*00
3.77E*00
4.09E»00
4.45E*00
4.83E*UU
5.24E*00
5.69E*00
b,18E*00
1>.71E*OU
7 .20E*00
7.91E*00
8.58E»00
9.32E*00
1.01E*OI
1.IOE*01
I.I9E*01
1.29E*01
1.4IE*01
1.53E*U1
1.66E*01
1 ,80E*01

MEAN CUMULAT
MASS CONCENTK
(PERCtNT J
5.80E-OI
6.26E-01
6.80E-01
T.02F.-01
fl.l?E-OI
8.92E-OI
9.B1E-01
.08F»OU
.I9E*00
.31E*00
,44E*OU
,58E*00
,72E»00
,BBF.»00
,99E»00
2.06E*00
?.1BF*00
2.3SE*00
2.49E*00
?o6?E*OU
2.73F*0«
P.82E*00
i?.90E*00
2.97E*00
3.02E*00
3.07E*00
3.11E*00
3.14E»00
3.1 7E*00
3.20E*OU
3.23E *00
3.2f»E*00
3.29E*00
3.33E»00
3.36E»0«
3.40E*00
3.44E*00
3.«9E*00
3.53E»00
3.5BE*00
3.b3E*00
3.6BE*00
3.73E*00
3.79E*00
3.85E«OU
3.91E*00
3.99E*00
4.14F.*00
4.02E*00
4 .B5E*00
5.uat*no
6.^SE*OU
7 .?hE*00
                                    7.11E-01
                                    7.B1E-01
                                    fl.bOF-01
                                     ,ObE*00
                                     , lbE*OU
                                     ,«IE»UO
                                      70E«00
                                      BbF*()U
                                   e.04E*00
                                   c».70E*00
                                   ^.B3E*00
                                   3.19E»00
                                   3.29E*00
                                   3.33E*00
                                   3.36E*00
                                   3.39E»00
                                   3.43E*00
                                   3.49E«00
                                   3.5bE»00
                                   1.591*00
                                   3.b3E*00
                                   3.67E»00
                                   3.7U+OU
                                   5.81E»00
                                   3.9bE«00
                                   u.Oi*E*00
                                   1.0BE*00
                                        «00
                                        »l»0
                                       •«00
                                   S.70E*00
                                   b.51E*00
   CUNFIUINCE
  LIMIT
PtKCENT)
b.b3E-01
b.«BE-01
/.08F-OI
».3bk-OJ
M.16E-OI
  .01E*OU
  .10E*00
  .2IE*00
  ,33E»00
      *00
                                                        .7 3E*00
                                                        .«»IE*OU
                                                       t!.00t»00
                                                       «?. ISt»OU
                                                       ^.51E»Olt
«!.75E*00
r'.HOE + OO
i».85t»00
i.B8E*00
•».92E»00
2.95E*00
i?.9HE»00
5.01E*00
3.04E*UO
3.07E*00
3.1«E*00
3.18E*OV
3.dbt*UO
3.31E*00
3.«0t*00
3.ast*oo
3.bOE*00
3.bbE*00
                                                       3.bBE*00
a. |9t»00
«.blt+00
b.l»E*00
•>.V«»E«00

-------
     50       l.95E»OI         8.0l)fc»OU           H.7ttt»OU           H.Olt+Od
     55       2.I2E+01         9.7bE»UU           1.0<>E»U1
     •»b       ?.30E»01         1.1^f. + Ut           I.l9f+01
     57       a.50t»0t         I.37F*01           I
     56       2.71E»01         1.7Ct»Ol           l
     59       a.95E»ui         a.oof«oi           r
     60       3.£OE*OI         ^.«1f*01           c
     fcl       3.«7E»OJ         a.79E*01           3.00t»OI
     62       3.T7E»01         3.17E«01           3.«1E»OI
     63       4.09E+01         3.5bE«OI           3.81F+01           i.31t*OI
     6fl       «.«5E»01         3.9fcE»01           *.2£l*fil
     65       «.»3E»01         q.30K*01           u.bt*0l
     69       6.71E + 01         5.77E»01           6.0<>.70F.»Ol
     72       8.58E»Ol         b.63E + OI           b.97E*01
     73       9.32E»01         b.87E*01           7.22E*01
 I
to
NJ

-------
ro
N)

RHO« 1.00
INTERVAL
1
2
3
4
5
6
7
6
9
10
It
12
13
14
15
16
17
16
19
20
21
22
23
24
25
26
27
26
29
30
31
32
33
34
35
36
37
ASARCO AVERAGE
GM/CC
D1AMETEH
2.50E-OI
2.95E-01
3.47E-01
4.09E-01
4.83E-01
5.69E-01
6.71E-01
7.91E-01
9.32E-01
1.IOE+00
1.29E«00
1.53E+OU
1.80E+00
2.12E»00
2.50E«00
2.95E*00
3.47E+OV
4.09E«00
«.83E»OU
5,696*00
b.71E»00
7.91E»00
9.32E*00
1.10E«OI
1.29E»Ol
1.53E»OI
1.80E«01
i? • 1 2E *0 1
2»50F. *OI
2.95E»01
3.«7E«01
4.09E«01
4.83E»OI
5.69E*01
6.71E*01
7.91E»01
9.32E»01
                          PAHTICLE  SI/E  D1S1HIHU1 IONS
     MEAN CHANUt
IN MASS CUNCkNl>y*1 IUN
      (MG/DNM3)
7.70E-01
1.0IE*00
I.53E»00
1.7VE»00
2.0«4E»OU
1 .OOE«00
9.30E-01
1.84E«00
1.35E»OU
9.57E-01
b.blE-01
O.B1E-OJ
4.09E-01
4.1SE-01
3.50E-01
5.81E-01
5.b«E-01
b,!3E-01
b.b^E-01
7.3JE-01
1.33E«0«J
fl.7bE»00
8.B7E*00
I.3«E»01
l.9bE»01
                                4.72E»01
5.I1E+01
4.73E»OI
tt«UI
                                                       »01

-------
               ASARCO AVERAGE PARTICLE SUE  UISlHldul IONS
    RMO« 1.00 GM/CC
    INTERVAL   01AMETEW    RECORDS EXCLUDED  FROM
                           CHANGE IN MASS  CUNTHAMUN
ro
oo
1
2
3
4
5
6
7
6
9
10
11
12
13
14
15
16
17
ta
19
2«
21
22
23
24
25
26
27
26
29
30
31
32
33
34
35
36
37
2.SOE-01
2.95E-01
3.47E-01
4.09E-01
4.63E-01
5.69E-01
b. 716-01
7.91E-01
9.32t-01
1.10E»00
1.29E*00
1.53E»00
1.80E+UO
2.12E»00
2.50E»00
2.95E+00
3.47E*00
4.09E»00
fl.83E»00
5.fc9E*00
6.71E»00
7.91E*00
9.32F.*00
1.10E»OJ
1.29E*01
1.5JE»01
1.80E*OI
2.I2E+01
2.50E«01
2.95E»01
3.47E»01
fl.09E»01
«.83E»01
5.(>9E*01
6.7IE»OI
7.91E»01
9.32E*01
4
4
4
4
a
a
4
2 4
2 4
4
a
a
4
a
4
4
? 4
4
4
4
4
4






NONE
NONE
NONE
NONE
NONE
NONE
NONF
NONE
NONE

-------
to
to
RMCte 1.00

INTERVAL

    t
    2
    3
    4
    5

    7
    a
    9
   10
   II
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24
   25
   26
   27
   26
   29
   30
   31
   32
   33
   34
   35
   36
   37
             ASARCO AVERAGE  PAW'JCLt  Sl/fc
            GM/Ct
                                               IUIMS
OIAMEUH

2.SOE-01
2.95E-01
3.47E-01
4.09E-01
4.83E-01
5.69E-01
6.71E-01
7.91E-01
9.32E-01
1.10E+00
I.29E»00
l.53E*00
l.BUE+00
2.12E*00
2.SOE«00
2.95E»00
3.47£»OU
4.09E»00
4,83E»OU
5.69E*00
6.71E»00
7.91£»00
9.32E*00
1.10E»01
1.29E»01
1.53E»01
1.80E»01
2.12E«01
2.50E»01
3.47E«01
a.09E»01
4.83E»01
5.bV£»01
b.71E»01
7.91E*01
9.32E»OI
                         IN
MEAN CHANGE
    CU»ttNlMAlIUH
 (NU/ONM3)
                                 V.77E»10
                                  .8bt.»10
                                 2.I9E»09
  1 ,19£*09
  S.14E40R
  2.|7E«08
  9.bOt»07
  5.00k»07
  3.09E*07
  1 ,b!E*07
  t .45£»07
  4.|9E»Ob

  t,9at»0b
                                4.19E»Ob
                                a.7bt»0b
                                1.45E»06
                                8.b9£«05
  2.71E»05

  7.IbE»U«
STANOAHO
01V 1*1 I UN
(NU/UNM3)

 0.30E»IO
 3.41E*IU
 1,0/E»09
 3.74E«0«
 l.lbC»00
 4.83E*07
 2,bUE»07
 9.93£«0b
                                                    I ,09F*t)/
                                                    9.0«t*0b
                                                    4.b3E»Ob
                                                    l.83E»Ob
                     9.4«*E»Ob
                     t.a«e»0b
                     \.'.
                                                    ^.37E»Ob
 3.00E»Ob


 5.0lt»0«
   CONF IDI-NCE
  I IM1 I
1NII/UNM3)
 9.S7E*10
                                                                   4.78k*IO
                                                                   3.57E*IO
                                                                   I .'
                                                                   4.03E»0<*
                                                                   S.93E»0«*
                                                                    .19E»OB
                I.97E»07
                I.39E»07
               S.ObE»Ob
               3.14E»Ob
                                                                  
-------
           USARCO AVERAGE PARTICLE SIZE  D IS1RJ HUl 1UNS
RHO* 1.00  GM/CC
INTERVAL   DI»METEH     RECORDS EXCLUDED FROM MUN
                      CHANGE IN NUMriErt CONLtMf»I I UN
1
2
3
4
5
6
7
6
9
10
11
12
13
14
15
16
17
16
19
20
1 21
to 22
W 23
0 24
25
26
27
26
29
30
31
32
33
3«
35
36
37
2.50E-01
2.95E-01
3.47E-01
4.09E-01
4.83E-01
5.b9E-01
6.7U-01
7.91E-01
9.32E-01
1.10E*OU
1.29E*00
1 .bit«00
l.«OE»00
2.12E»00
2.50E*00
2.95E»00
3.a/E»00
«.09E+00
4.63E+00
5.6<»E»00
6.71E*OU
7.9IE*00
9.32E*OU
I.10E+01
1 ,29E»01
1.53E»OJ
1.80E»01
2.I2E*01
2.50E»01
2.95E*01
3.47E*01
4.09E»01
«.63E«01
5.69E»01
6.71E»01
7.91E»OI
9.3dE»01
4
U
It
4
U
(1
(1
i. 4
f 4
4
It
It
a
4
4
4
2 4









4
4
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE

-------
I-  1 K U •        11A  1  A
PLANf
SAMPLING LUCA1 tOM
SAMPLE lYPt
UPtMATUH
AMblENI TEMP. (OEG. F)
HAM. PRESS. ( IN. Hb)

MEU.N CAL1U. FACTuft
Ht AD 8 NbCUHl) DATA K
SAMPLE
HMt
(M1N.) (

0
5.0
I0.li
15.0
20.0
25.0
•M 30.0
1 35.0
to
W TOTALS 35.0
M AVERAGE
AbAKCU
NO M bttllivllANY trXHAUSI
Mb 1 HUO b
SCHbH t- tL
U4.
30.^6

.<*e»
VtKY b.O MJNUlkS
CLUCK bAS MEUK UWY GAS M£tEI<
TIME hbAUlNb ffcMP
a«-MH (CU.I-1.) IMbb.F)
I Nit 1
1605 53B.07*
1 bl 0 b«3.00ti 51 .
Ibl5 54B.OOO 57.
IbdO 550. bOO bli.
lb«?5 5b5.000 be?.
Ib30 55B.OOO b«.
!63S 5b2.00u Hi.
\bSB 5t>
-------
SHLFUk
                              MKLI> IIA1A H KEbULKS  IAHIILAUUM
                                 E VA 'It I HIM) b
   PLANT- NAMt  AND AOOfcESS                TEbl  IEAM

   ASAHCO                                  bLHEF^EL

   TEST HS02-I      Nil 4 SECONDARY  EXHAUSI
TEST DA IE

Tb
TF

TT

y

VM


TM

VMSTD


PB
U)
ro VT
VTB


VSULN


VA


oa

OS

N


csoa


SU?PPH


S02HR
              TIMt-STARI
              UME-FIMSH
                                LNbLISM UUlTb

                                   ui/

                                IbUb
NET  I1ME  OF  TEST,

METER CALIBRATION FACTOR

VOLUME  OF  DRY GAS SAMPLED
AT METEH  CONDI1IONS

AVEKAGfc GAS  METEk TEMP

VOLUME  UF  ONY GAS SAMPLED
AT STANDARD  CONDITIONS*

HAHUMETHIC PHESSOHE

VOLUME  OF  BARIUM PERCHLURATE
TITHANT USEO FOR SAMPLE

VOLUME  OF  BARIUM PERCHLUHATE
11 IMAM FUH  THE BLANK

TOTAL VOLUME UF SOLUTION        1000. ML
FUH  THE SULFUR DIOXIDE

VOLUME  UF  SAMPLE ALIUUIIf          i>
-------
OJ
            tXAMHtt SIJLFIIK IlKlXlhF  CALUlLA I JUUS  Ibbl  M

                  NO 4 8F.CUNIIAKY hXMAUSI



      VULHMb (^  UHY GAS SAMPLHI AT  blANDAKU  C I)NI> 1 I J IIUS

      VMSTO =  I/. 607 • VM • Y • (Ph  )  I  (1M + UbO.J

                 17.6<47 •  ?5.5^3  •   ,9«H •  311. ^t,
      VMSTO =  — --------- ---------------------------  =
      CONCtNIKAT ION UF  302 AT STANDARD CIMUMIONS

      CSUa = 7.06  • I0««(-b) • N  *  (WT - VIB)  •  VSUL(^ / VA )/VMSTI)

                7.06 •  10«*(-5) *.0097  • (   1.16  -     .tb) »1000.U  /  e!0.0  )
      CS08 = - --- --- ---------------------------------------------------------   =    .1/41 •  lU**(-5)  Lb/USCF
      CONCENTRATION  UF  S03 BY VULUMt

      SO«?PPM =   030.0  • (VT - VTB)  «  M • VSOLN

                                 •  VA
                  030.0 • (   1.5  -     .15 ) *  .009/  «1000.0
      S02PHM =  -- - ---- - - ---------- — ------- — ..-.-....-..  =     10.60 PHM
                               £"3.16  •   ^0.0
      CONCtNIHATlUN UF SU2 IN LBS/HK

      SOiHK s  CS08 •  10««(-5) *  OS

      S02HK =      .!/  • 10*«(-^)  *         .0  =           .UIM) LHS/MW

-------
MtLU      DA tA
PLAN! ASAKCU
SAMPLlNI. LUCAIIUIM Nil «4 bECUMlAWl bXHAUSI
SAMPLE TYPE SUc-
UPEHOUW SLHtFFEL
AMblEM lEMP.tUEG.M 4V.
HAW.PWESS. (1N.HG) 5S.
«?7.0 17«f(l 5B5.'4iO bb.
TOTALS 9
j> AVERAGE bb.O
to
U)
UAIt Ul/14/Hif
hl/N NIJMHEH HSUtf-c:
KKUHE LENGIM R IYPE 5 Fl GLASS

SAMPLE HUX NllMBb'K
1-iETtK H0« NUMHtW Fbb
HWUHb 'HbAlbK SblTING ebO.


IMP1NGEH Pt«tENT
IEMH OF
(Ohb.t- ) CUNSIANI
U A ( 1-
K A 1 t

59. IIT.5B
59. 71.40
b9. lll.U^

59.



-------
            \SULFUK UlU«J»b MELD DATA  h  htSULlb IAHULAI1UN
                               tPA MLIHIIO  b
PLANT- NAME AHO  AUOHESS

ASARCU

TtSf PSO.?-£      NO  «  SECONDARY EXHAUSI
                                          TESI  ItAM LtAulH
ro PB
01
TEST DAIE

TB         TIME-START
TF         IIMt-FINISH

TT         Nt T IIME  UF TEST, MIN.

Y          MEIER  CALIBRATION FACTOR

VM         VOLUME UF DRY GAS SAMPLED
           AT METER  CUNUIUONS

TM         AVERAbb GAS METER TEMP

VMSTD      VULUMt UF DRY GAS SAMPLED
           AT STANDARD CONDITIONS*

           bAROMLTKlC  PRESSURE

VT         VOLUME UF BARIUM PERCHLUHAIt
           TI IRANI  USEO FOR SAMPLE

VTB        VOLUME UF BARIUM PERCHLURATE
           TIIHANI  FOR THE HLANK

VSOLN      TOTAL  VOLUME OF SOLUTION
           FUR THE SULFUR DIOXIDE

VA         VOLUME UF SAMPLE ALIOUUT
           11TKAIEU

02         UXYbEn ,  PERCENT

OS         FLOW NATE

N          MlKMALllY OF BARIUM
                       TITRANT
  CS02      ClINCtNTKATION OF SULFUR UlUXlUE
            OHY  HAS1S,  S1NO. CONDITIONS

  SU2PPM    CUNCENINAI ION UF SULFUR
            010XIOF.  HY
  9U2HR     LBS OF  SULFUR
                HUUh
                                             tcMGLISM

                                                Ul
                                                      IN-Ml,
                                                3.8 ML
                                                     ML
                                             IUUU. ML


                                               HI. ML
                                                                MEr«it  UNI is

                                                                    u 111

                                                                 b
                                                                t
                                                                     ^r .
l\ .0«J9 CU-F t
bb.O F
«M.5.JS SCF
,b»7 LU-l
IB. j C
.blO SCM
                                                                  7t»0.bO  HM-Hb
                                               .0  t

                                               .0  SCFH

                                               .009/  MILLtUUl VALtNTS/ML


                                               ,b»»  * 10««(-b)  LM/UbCF
                                               .000  I Mij/HK
             •   bH  Dtb Ff   i»«».92 Iln.HU.  fHHY  HAbIS

-------
           tXAMPLt  SULFUK DIOXIDE C AL t HL A I I UiJh Itbl iuj.»'Sll«!-d

                 NU  4 SECONDARY EXHAUSI
     VOLUME 1th  UWY  U«b SAMPLtli Al  SIANDAKU U(iNi) I 1 1

     VMbtU =  17.b«7  •  VM • t • (PB  )  /  (TM + «MJ.)

                \
     VMSfO =
                         (  hS.O » UbO.J
                                                             c-l.blb IKS
CONCtNIWA I ION  OF  SU8 Al STANDARD  CUNUIIIUNS

CSU8 =  7. Ob  •  IO**(-5) * N •  (VT  - VlH) • VSULN  /  VA  )/VMSM)

          7. Oh  •  IO««(-5) *.OU97  • (    3.«3 -     .Ib)  *1UOO.O /
        --------- - ----------- -
                                ^1 .b?
                                                                                      .5flb •  10«*(-b) Lb/OStF
     CONCENTHAT10N  UK  30d BY VOLUME
I    302PPM =  430.0  *  (VT - VTB) * N  •  VSOLN
to             _._._.....___. __ ..... __ ....
SOiPHM =
                          • VA

            430.0 • (   3. S -     .lb )  * .0097  «1000.0
               - --- --— ---- - ---- --
                         21.53  *   20.0
                                                                     3b.b«
CONCtNlHAl ION  OF  SU2 IN LBS/HH

S02HR =  CSD2  •  10**(-5) * US

SU2HH s      ,5V  « I0*«(-b) •
                                                           .000 LHS/MH

-------
                                                         I- ItLU   UA Irt
PLANl
LOCA1 ION
                             MUM StCUNUAHT  HXIlAllSl
SAMPLE  TTPE
OPtKATUH
AMHltNl  ItMP.(UtG.F)
b«H.PRESS.(IH.HU)

MtfKN CAL1B.  FACIDK
NtAl)  K WtCUKU  IIAIA EVEKY
                             SO.
                               b.U MlMJltS
                                                                                   KI/N NIIMHk»

                                                                                   HMUHt  LEM,IH
                                                                                          tYPt
                                                                                                                   t I  GLASS
                                                                                   SAMPLt  HUX  NUMHEK
                                                                                   MtTEK  HIlX NIIMHbK
                                                                                   HKUbt  *HtA ItK StI TING









>
to
U)TOTALS
"-UVtRAGE
SAMPLE.
1 iMt
(MIN.)

0
b.O
10.li
lb.0
au.o
30.0
30.0

CLUCK
TIMt
PI I IP K 1
1 L ul« " /
1800
180b
1610
101*}
1H
-------
              !>UL»-UK  UIDXIUE  FIELD UA1A A KFSULt.S IAUULAIIUU
                                EPA MtlHlIU h
   PLANT- NAME AND AUUKESS


   ASAHCU
   TEST PSO«J-3
      NOQ SECONDARY tXHAUST
                             FES1  ItAM


                             SCHtFI-KL/ANIhSMtWbLK
                                             ENGLISH UNITS
ro
   TEST DATE

   TB
   TF

   TT

   Y

   VM


   TM

   VMS TO


   PB
00  VT


   VTB


   VSOLN


   VA


   OZ

   OS

   N


   C802
TIME-START
TIME-FINISH

NEI TIME OF  TEST,  MIN.

MEIER CALIBRATION  FACTOR

VOLUME OF DRY GAS  SAMPLED
AT METEK CONDITIONS

AVERAGE GAS  METER  TEMP

VOLUME OF DRY GAS  SAMPLED
Al STANDARD  CONDITIONS*

BAROMETK1C PRESSURE

VULUME UF BARIUM PERCHLURATE
TITkANT USEU FOR SAMPLE

VOLUME OF BARIUM PERCHLURATE
TIlkANl FOR  THE BLANK

IUIAL VOLUME OF SOLUTION
FOR THE SULFUR DIOXIDE

VULUME UF SAMPLE ALIOUOI
UTkAlED

OXYGEN , PERCENT

FLOW NATE

NURMALIIV OF BARIUM
PtHCHLORATE  TITkANT

CONCENTRATION OF SULFUR DIOXIDE
URY BASIS, STNO. CONDITIONS

CUNCEMHAUON OF SOLFOR
OIOXIUE BY VOLOME

LHS (JF SULFOk niOXIDE
PEn HOOK
                                10UU
                                1B39
                                  JO.U
                                         CU-F T
                     HE Ik 1C  UNI Ib

                         01/1


                     1HOO
                       13"

                        30.0
  n. a   F

  «!9.3bU SLF





   •j.8 ML



    .Ib ML



1000. ML



  t!0. ML



    .0 X

    .0 SCKH

    .009/ MILLEUUIVALLMTS/ML



    .66  * 10**(-5J  LH/OSCF



  «0.13 PPM



    .OUO LHS/Hk
                                                         ,«3/ LO-M
                                                         .031 5CM
                                                                            MM-Hb
*  6H UEG F,
                                  IN.HI,.  ,UKY

-------
         tXAMHLt SDLFUH  UlUXlOt C ALUILA I lIHJb ItbT 'JtJ.HSUc?-J

              NUM SECUNOAKr  EXHAUbT
   VULUMt  Itf  UWT (,A3 SAMHLIU  AT SlANDAKU tUNl> 1 I IMnS

   VMSTO  = ll.bH? * VM  *  Y  *  (PH ) /  (TM *  UfrO.J
                                           3U.r-h
  VMSIO  =  —»- — ———- — ... --------------- =      c?S.4bU USLK
                       (  71.2  + UhO.)
  CONCtNlkAHUH UF- SU2  AT  STANDARD CUNMIIIUNS

  C302  =  7. Oh • 11MM-5)  •  N * (VT - VlbJ  •  VSOLiv / VA  )/VMSIH

            7.0«> • 10«*(-5)  «.0097 •  (    b.8« -    ,lb)  •10UO.O
  CONCtNTHATUJN OF 3U2  BY  VOLUME

.p 302PPM =  030. U •  IVT  -  VtB) • N • VSOLN
 ,           ----- ........ — . ----- . -----------
N)                      VMSTI) • VA
U)
*°             Q3U.O •  (   S.« -    .15  )  •  .0097 *1000.0
  S02PPM = ------ — - — --.——-- --- -._...._-..-.-.--.--_ r    
-------
                                                                  MtLO   DA I A
HI. AN I
            LOCATION
ASAKCIJ
ND'I  StCUNUAKY  ^ XMAUJj t
SAMPLt  lYPt
UPbHAF UH
AMHltNl  IEMP. (l)tb.F)
HAk.HMtSb. UN. Hi;)
II A It
k|IN MJMHtW

HKUBk LtNlilH
                                                                                                                     TYPE
                                                                                                       GLASS
bO.
SAMPLt  BOX  NUMbEH
Ml IEK 8DX
HklJHt
Mtlt'W
HtAU  K  NtCUHU  IIAIA  EVEHY
       M[l4Uthb










> TOTALS
k AVERAGE
O
SAMPLE
1 IMt
IMN.)

0
b.O
10.0
lb.0
50.0
5b.O
55.0


CLOCK
TIME
^ 1 1 IP K 1
I.LUL R j
1645
iabo
Iflbb
1900
1900
1910



I;AS METEH
WEAD1NU
(CU.F 1 .)

bib. 190
bie.79b
b
-------
                        IJIUXJDK FIELD  UAIA A  HF.bliLtS  lAbliLAIIUU
                                   EPA  Mt I HIIO  b
    PLANT- NAME  AMU ADDRESS

    ASARCU
                         TtSI  TEAM  LEADEH

                         SLHtFFEL/ANIKSMEHUEk
    TEST
NU4 SECONDARY EXHAUST
K>
    TEST  DATE
                            ENUl1SH  UNllb

                               (ll/11/He!
METKIC  UNiib

   U 1 / 1 <4/ttr>
TB
TF
TT
T
VM
TM
VMSTO
PB
VT
VTB
VSOLN
VA
08
QS
N
C$02
S02PPM
S02HR
TIME-START 184b IBdb
IIMfFlNlSH 1V|(J 1410
Ntl I1ME UF TEST, MIN. *b.O 
-------
                    bULFUH MlJXlOE  C ALUJL A I lt)l\iS ItSI MJ.PSU,?-«

                 NU<4 StCUNOAKY  EXHAUSI




     VOLUMt S) *  US

                  ,gb * IO**(-5)  *        .0   =            . (MIU  LHS/MW

-------
                                                             IK LI'  DA I A
HLAM
bAMPLlrtG LOCATION
ASAKLU
HU» bLCONUANY EXHADbT
                                                                                  UAIE
                                                                                      NUMHEH
SAMPLE TYPE SOi;
UPEWAIUH AilItSBEKbtK
AMH1EN1 lEMP.(UEG.F) SU.
HAK.PHESb. UN.Hb) JU.«?b

METEh CALIB. FACItlH .^tt«
WEAO H HEtUKU OA1A EVEMY b.O MlNUlES
SAMPLE CLUCK bAS MtTtK DHY GAS METEN
I1ME TIME HEAOlKb IEMP
(MIN.) (24-HH (CU.hl.) tDEb.F)
IHLt 1
0 1985 633.U3c>
10.0 19ib 6ai.o;o 7a.
eO.O 19«b bMH.Mb »0.
TOTALS ^0.0 lb.t?B3
. AVERAGE >J.V
\
NJ
PWOBE LENI.1H /I TYPE

SAMPLE BOX NUMHEH
Mf- IE*< BOX NUMHtW
HHOHE 'MEAIEH SETTING


1MPINGEH
TEMP
(OEb.F)


60.
60.

bO.


•3 F I


Fb<*
«?bo.


PERCENT
OF
CONSTANT
O A Y C
HA 1 1

99.95
IVO.Cb




                                                                                                                 bLASS
U>

-------
            SULHJH  rmiXIDh MtLU OAfA  K  NlSIILTS IAHOLAI10U
                             tPA Ht IllOU  *

PLANT- MAMt  AND  AUURESS                TkSI  TtAM LtAUtK

ASARCU                                  AnltSblKGtk

TEST PSUd-5      IWH  SECONDARY EXHAUST
TEST UAIt

tit
TF

TT
 VM


 TM

 VMSTD
, VT


 VTB


 VSOLN


 VA


 oa

 US

 N
S02PP*


S02HR
          TIME-START
          TIMt-MNlSH

          Ntt  llMt  OF 1EST, MIN.

          MtTEK CALIBRATION FAC1UH

          VULUMt  UF  DRY  GAS SAMPLEU
          A) MtltH  CONUITIUNS

          AVEHAGt GAS METFR TEMH

          VOLUMt  OF  DRY  GAS SAMPLED
          AT STANDARD CONDITIONS*

          BAHUMtTKIC  PRESSURE

          VULUMt  OF  BARIIIH PEHCHLORATE
          T1TKAMT USED FOR SAMPLE

          VOLUME  UF  BARIUM PCRCHLURATE
          TIIKANT FUR THE  BLANK

          T01AL VULUME OF  SOLUTION
          FUR  THE SULFUR DIOXIDE

          VULUME  OF  SAMPLE ALIOUOl
          TIIKATEU

          UXYbEN  ,  PERCENT

          FLOW RATE

          NORMALITY  OF BARIUM
          HfcWCHLONATE TI1RANT

          CONttNTKAT ION  UF SULFUR DIOXIDE
          UKY  HAS1S,  STNO. CONDITIONS
                                            LNbLlSM UNITS

                                               01/1

                                            IS2S
                                                                MtTRK  UNITS

                                                                    Ul / I t/Ot!
                                                                   •?o.o
                             SULFUH
          LUNLENTKAT1UN
          l'10»lUt  BY
          LBS OF  SULFUR  OlOXlOt
              HliUH
         CU-F T


  77.0   F

  IS.015 SLF


  30.£b  IN-HG

   S.O ML


    .15 ML


IUOQ. ML


  20. ML


    .0 Z

    .0 SCFH

    .OU«»/ MILLEfJUlVALtNTS/ML


   1.11  *  IO*M-5)   LH/USCF


  67. it> fPM


    .000 LHS/HK
                                                                          LU-M


                                                                          t

                                                                          SCM


                                                                          MM-Hb
              6b Otb  F,
                               IN. Mb. ,OKY  HAS1S

-------
            tXAMHLt  bULFUK lllDXIUt C ALLI.'L A 1 I (INS IKS) Ivu .HS

                  N(ta StCUNDAWY EXHAUST
VOLUMt OK  UNIT  (.AS SAMPLhU AT  SlAUUAKU COMilllONS

VMSTU =  lJ.bO.J

           |7.b<*7 •  15.2B3 *   .90H •  30.^6
                                                  =
                    ( 71.0 »
      VMS10 =
                                                                     USt^
                    OF  SU£ AT 3TANDAHU

      CSU^ = 7. Ob • 10*«(-S)  * N *  (VT  >  VlB)  * VSOLN  /  VA  J/VMSIU

               7.06 •  10*o(-S) «.0097 •  (    b.OO -     .15)  "1000.0 /
CSU2 =
                                                                                   =  l.lob  •  10«M-b) LB/USCF
N)
CONCEN1HAT1UN  OF  508 HY VOLUMt

S02PHM s   M30.0 • (VI - VTB)  •  N  » V30LN
          ••••••«••••._.•«---—-.•-••—--.-•-
                    VMSTD • VA

            030.0  • (   5.0 -     .15 ) • .0097  MOOO.O
                 — — - --- —
                         15. oe  «  ao.o
S02PPM =
                                                                      f>7.36
CUNCtUlKAT ION  OF SU8 IN LBS/HR

SUeHH =  C30
-------
MtLU     I)A  FA
PLANI ASAXLU INC
SAMPLING LOCATION NU <« tXHAUSI
SAMPLE TYPE SU2
UPtWAIOK AMtSHEhULK
AMHlENT TEMP. (OEG.F) bU.
HAK.PHtSS.UN.HG) 3U.cfb

METEH CAL1B. FACTIlW .90(1
HtAf> A HECUHU OftlA EVEHY b . 0 MlNUU.b
SAMPLE CLOCK GAS MfcltH
TIME TIME HEADING
PI fir M t
ULUL* J
o eoab bae.»j5
b.U 2031 bb^.bUO
1U.U ?U3h bbb.l
bH. b4. 1UU.2U
bH. 54. 100.12

bM.U 54.

-------
           SOLFUH  UlUXIDt MELD UAfA 14 RESULIb  I AhllL A I 1 UN
                             EF-A wit I HiMj h'
PLANT- NAME ANU  AUURESS

A3ARCO I III,

TEST PSUii-b      NO    IK-HG

   b.3 ML


   i».is ML


IOUO. ML


  •fO. ML


    .0 X

    .0 SCFH

    ,oo«»/ MILLEUUIVALENTS/ML
                                                                  eo.o    c

                                                                     .biJM  SCM


                                                                 /btt.bU   MM-HG
          CONCENTRATION  OF  SULFUR DIOXIDE
          OHY bASIS,  STND.  CONDITIONS

          CONCENIRATION  OF  SULFUR
          U1UXIUE AY  VOLUMt

          LBS OF SULFUR  DIOXIDE '
          PER HOOK
                                    .77   •  10««(-b)  LH/USCF


                                  1b.7<* PPM


                                    .OUU  LbS/HH


»  bH l)tb F,  ^9.9^  1N.HG. fDRY BASIS

-------
             tXAMPLt  SULf-Ulv IllDXIOt CALLULAIlUNb Itbl  No.HSllc'-b

                  MJ  «  tXHAIISt


       VOLUME OH am  GAS  SAMPLCO AI sfAuOAKo  UJNUI i IIM.S

       VMS1U = 17.b17 • VM  * Y  • (MB ) /  UM  »  UbO.J

                 I7.b47 •   iH.Sia *  .908  •   iu.
-------
                                                                 ^ ItLU   DA FA
PLAM
SAMPLING LOCATION
SAMPLE lYPt
OPEWA1UH
AMUIENI ItMP. (l)Eli.F
HAW.PHESS. 1 IN.Hi;)

METtH CALlb. FACIUH
HbAU A HtCOP.1) DATA
SAMPLE
11ME
IM1N.)


V
5.0
10.0
lb.0
20.0
ASAKCU/-I AtOMA, HASH
NU a tXMAObl
502
AN! tbbEKbth
) hO.
10.00

.4bO
EVEHY b.O M1NOIES
CLOCK bAS Mtltt* OKY GAS 'MtltW
TIME KEAUlUb ItUP
(Zfl-HH ICU.FT.) lOtti.F)


IbOb 820. 1VU
Ibll 820. IbO brf.
151b 82n.lbC be!.
1521 »3f?.lbO bu.
Ibiife Hib.lbO b(<.
1)4 It 01/20
WUN NOMBtH PbH«?-
PHOHt LfcNbIM ft TYPt b FT

SAMPLE HOX NOMHEH
MtlKK BOH NIIMHtH Fbb
P'^O'it 'HI-AIFK StITlNb i-bO.


IMPlNbKW PERCENT
TEMP OF
(UEb.F) CUNbTANI
It A 1 t
K ^ 1 C

bO. 99.19
bO. 100. IV
bt. 100.19
53. 100.14
U*      TOTALS
J.      AVERAGE
                     ao.o
                                                                          ia.o
bl.
VD

-------
              SULFUR OIUXlDfc  FH.LO  DAI*  ft WtSULIb I A MllL A I I UN
                                EM A  MhlHUI) t>
   PLANT- NAME ANO AUURESS

   ASARCU/-TACUMA, NASH

   TEST Psoa-7     NO a EXHAUST
                                        Itbl  UAM

                                        ANItShtHGtk
 TEST UATE

 tB
 TF

 TT

 T

 VN


 TM

"VMS TD
   _
U1 PB
O
   VT


   VTB


   V80LN


   VA


   OZ

   08

   N


   CT02


   8U2PPM


   802HR
             IIME-START
NET TIME OF TEST, M1N.

MtTER CALIBRATION FACTOR

VOLUME UF DRY GAS SAMPLED
A1 METER CONDITIONS

AVERAGE GAS METER TEMP

VOLUME UF DRY GAS SAMPLED
AT STANDARD CONDITIONS*

BAROMETRIC PRESSURE

VOLUME OF BARIUM PERCHLUHATE
TITRANT USED FOR SAMPLE

VOLUME UF BARIUM PERCHLURATE
T1THANT FOR THE BLANK

TOTAL VULUME OF SOLUTION
FUR THE SULFUR UIOXIOE

VOLUME OF SAMPLE ALIQUOT
I 1 (HATED

UXYGtN , PERCENT

FLOW RATE

NORMALITY UF BARIUM
PEHCHLUrtATE TITRANT

CONCENTRATION OF SULFUR UIOXIOE
DRY HAS13, STNO. CONDI THINS

CONCENTRATION UF SULFUR
        BY VULUMK
ENGLISH UNITS

   01/<»0/»e;

1506


  .0

    .960

  15.970 CU-FT


  bfl.O   F

  15.791 SLF


  30.00  1N-HI,

    .3 ML


    .20 ML


1000. ML


  2v. ML
                                               ME1KIC

                                                  01

                                               1*06
                                                                      .VhO
                                                        CO-M


                                                 M.i   C

                                                   .447 SCM


                                                76
-------
      tXAMPLt SULFUK  DIOXIDE  L ALCUL A I U'Nb IEM MU.KSUe'-/


           NU 4 EXHAUST
VOLUME (It- OKY GAS SAMPLED  AT  SIAUUAhU tUNUIHONS

VMSIU * 17.6*7 • VM  •  Y  •  (PB )  /  (IM + 460.)

          17.647 *   15.970 •   .9bU *  30.00
         .—— — - — ------ .. ---------------- .- =
                    ( 5«.0  » *b\>.)
VM3TO
                                                              UStF
CONCEN1HA! ION OF 308  AT  STANOAHO  CUNU1TIUNS

CS02 = 7.06 * IO*»(-5) *  N  •  (VT  - VIH) • VSULN / VA  I/VMSIO

         7.C6 •  IO««(-5)  «,0097  • I    ,3«! -    .?0)  *1000.0
                                                                  
-------
   END  OF  PKOtiHAH
   tCOJ
   CPU  SEC.  = 11.  tLAPSEU WIN. r  1.   FMI,  KEB 11, l<»«3,  3: Jb
>
NJ
ro

-------
APPENDIX B




FIELD DATA
    B-l

-------
                     TRAVERSE POINT LOCATION FOR CIRCULARJIUCTS
Plant
Date
            lilt*
Sampling location
Inside of far wall
 of nipple 	
Inside of near wall to outsijd
 nipple (nipple length)
Stack I.D.
                              of
Nearest upstream disturbance
Nearest downstream disturbance
Calculated  by
                                      dd
                                      dd
                                                          SCHEMATIC OF SAMPLING LOCATION
TRAVERSE
POINT
DUMBER
/
Si
A
3-
V
S~
{*>


















FRACTION
OF STACK I.D.
,w
,/rt'
,2%,
•?^y
ihfy
.$&


















STACK I.D.
Co










I


















PRODUCT OF
COLWNS 2 AND 3
(TO NEAREST 1/1 INCH)
























NIPPLE
LENGTH
;z£





\























TRAVERSE POINT LOCATION
FROM OUTSIDE OF RIPPLE
(SMOFCOUMNSUS)
5#
//#
UK
W*
&9
<&¥f


















                                        B-2

-------
                                           CAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
       SAMPLING LOCATION
                            CLOCK
                            TIME
                                                       *«     17
     RUN
    NUMBER
OPERATOR
AMB. TEMP.
  (»F)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. HO)
2.
                                    II
                                               II
                                                           33
MOLECULAR
WT.
.*-.&. 1.3
STACK INSIDE DIMENSION (in.)
51 AM OR SIDE 1
, t.^tL^
SIDE 2
• . • . •
PITOT
TUBE Cp
.'.V
MOISTURE
%
JJ*.
                                                      73
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
L- 1
2.
,3
v
^47"
f.

h i
b
3
• f
'
£





























POSITION
(in.)
11 .12 .13«U










































VELOCITY
HEAD
(Ap ) , in.H.,0
s ^
25.26*2? , 21 .29

/• */
/• *
I. X
/ 2L
A /

/'/
/ T
/ 4^
''t
j.3~
/. ?





























STACK
TEMP, »F
31.39.40.41
i >
L/»
<^t
cv
.^ /
<~7
1
ft
5*
&•
jf^
^r
fT-



























~>

                                    B-3

-------
                                         CAS VELOCITY AND VOLUME DATA
               PLANT AND CITY
                                              RUN DATE
        A
                                                          37
       CAMPLING LOCATION
                           CLOCK
                           TIME
                                      /r/7
                                            »»
     RUN
    NUMBER
OPERATOR
AKB. TEMP.
  CF)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in.  R20)
2.
                                             II
                                                        Ji
                                                                II
MOLECULAR
¥T.
. X«J3
STACK INSIDE DIMENSION (in.)
HAM OR SIDE 1
. 4. z>. » . .
SIDE 2
• . • . i
PITOT
TUBE Cp
.^y
MOISTURE
t
,/.»,
   40
             44 31
                        «l
                                                   73
                                                           76
                    FIELD DATA
TRAVERSE
POINT
NUMBER
7,1.9 .10
J3 1
4
^9
«/
>
&

<- /
J
1
~&
Y
(





























POSITION
(in.)
11 .1 7 ,)3»U










































VELOCITY
HEAD
(ips) , in.H20
J 5. ?6 • 77 . 78 ,29
/ /
f'fs
/'Z
/••fr
'-Y
/, /

I.I
l'\

































STACK
TEMP, «F
31 ,3 9 .40 .41
^7
r-f
£r

-------
                                           CAS VELOCITY MID VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                                       94    »7
       SAMPLING LOCATION
                            CLOCK
                            TIME
    2
     RON
    NUMBER
OPERATOR
AMB. TEMP.
  (»F)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. H20)
MOLECULAR
WT.
.^M.3
STACK INSIDE DIMENSION (in.)
5IAM OK SIDE 1
. 4 '.* . .
SIDE 2

PITOT
TUBE Cp
.et
MOISTURE
%
M
   40
             44 51        41       44     47
                                                      73      76
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
<*^ /
X
J

r^
*T7
<7
*r?

*-j
'*%
-f?
r^
Cl
J7



























-

                                    B-5
                                                           0
                                                      T,  --

-------
                                    GAS VELOCITY AND VOLUME DATA
         PLANT AND CITY
                                       RUN DATE
                                                14     97
SAMPLING LOCATION
st
                    CLOCK
                    TIME
                               »6      •»
RUN
NUMBER
f - ?
OPERATOR
X/c^/
AMB. TEMP.
CF)
. ,M
      44
                  • I
                                *7
                                              73
                                                      76
              FIELD DATA
TRAVERSE
POINT
NUMBER
7,1.9 .10
> 1
*
3
Y
f
I


-------
                                           CAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
       SAMPLING LOCATION
    fi/:f
                                                       34     37
                            CLOCK
                            TIME
                                              »»
     RON
    NUMBER
OPERATOR
         AMB. TEMP.
           (»F)
BAR. PRESS
 (in. Kg)
                   STATIC PRESS
                    (in. H20)
2.
    I/- |
                                    II
                                               31
                                                                   3*
MOLECULAR
WT.
. A'.IJ
STACK INSIDE DIMENSION (in.)
5IAM OR SIDE 1
.6.O.D. .
SIDE 2
t . • . t
PITOT
TUBE Cp
.«y
MOISTURE
%
./J).
             44
                                                      73
                                                             76
                     FIELD DATA
    TRAVERSE
      POINT
      NUMBER
     7.1.9 .10
     M-
           ±
           ±
  POSITION
     (in.)

VELOCITY
  HEAD
                        7 5.26 «37 , 2« .79
  STACK
TEMP, «F
                                       31.19 .40 .41
                                          .-r?
                                    B-7

-------
                                           CAS VELOCITY AMD VOLUME DATA
1.
2.
                PLANT AND CITY
                                                RUN DATE
                                                       >4
       SAMPLING LOCATION
   41
     RON
    NUMBER
         ±
                            CLOCK
                            TINE
                                       4>4>       49
OPERATOR
         AMB. TEMP.
           (»F)
BAR. PRESS
 (in. Hg)
                   STATIC PRESS
                    (in. HO)
                                    II
                                                                   31
MOLECULAR
WT.
.^.
STACK INSIDE DIMENSION (in.)
)IAM OH SIDE 1
. 4 o.o.
SIDE 2
. . • . i
PITOT
TUBE Cp
^^V
MOISTURE
.LO.
                         *'
                                              70
                                                      73
                      FIELD DATA
     TRAVERSE
      POINT
      NUMBER
     I...* 1 .9 .10
  POSITION
     (in.)
VELOCITY
  HEAD
                         23.26.27.28 .29
  STACK
TEMP, »P
                                        II. 39.40 .41
                                         6,6
                                   B-8
                                           r  -  rt

-------
                                           CAS VELOCITY AMD VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                                             17
       SAMPLING LOCATION
                            CLOCK
                            TIME
     RON
    NUMBER
OPERATO
AMB. TEMP.
  CD
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. HO)
    I/-/?"
                                    II
MOLECULAR
HT.
STfjc?
STACK INSIDE DIMENSION (in.)
MAM OR SIDE 1
/ /—>
. £7.C?« ; . —
SIDE 1
-^
. , • A _^x
PITOT
TUBE Cp
• .
MOISTURE
%
,/K
   40
                         • I
                                              70
                                                             if,
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
/!-/
Z
*>
f-
•$
. ta
t>- (
z
^

4
If






























POSITION
(in.)
1 .1 2 ,U«I4










































VELOCITY
HEAD
(Ap ) , in.HjO
7 5.76 • 7 7 , 71 . 7«
//^^
y.-^f
/.&*>
't^
/.2&
j. GO
A &P
/.**?
/t*lo
/"&0
/, "+0
X, 3^>






























STACK
TEMP, »F
31 •) 9 .40 ,41
<£4o
*lt>

-------
                                           GAS VELOCITY AMD VOLUME DATA
                PLANT AND CITY
                                                RUN  DATE
1.
                                                      14     97
       CAMPLING LOCATION
                            CLOCK
                            TIME
   42
                                      46
     RUN
    NUMBER
OPERATO
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. H20)
    (A/*
                                   II
                                               II
                                                                  II
MOLECULAR
HT.
.-&#&.
STACK INSIDE DIMENSION (in.)
51 AM OH SIDE 1


SIDE 2
__
--•—•— » .' ,*^<
PITOT
TUBE Cp


MOISTURE
%
.AC?
   40
                                                     73
                                                             76
                     FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
k~y
•?
^
4
*,
if
CL~ i
Z
^
Jt
]**
c.






























POSITION
(in.)
1 1 .1 3 .1 J«I4










































VELOCITY
HEAD
(Ap ) , in.HjO
? i. ?6 • 77 . )l ,29
/tt-&
/.^O
J,<0
S,?~0
f>.*c>
/'Z-o
/. /&
/i +4
/.t*>
'/,*
-------
                                          GAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                    RUN DATE
i.
                                                 i/l/l 44
SAMPLING LOCATION
                                       CLOCK
                                       TIME
                                      •6
                                             49
     RON
    NUMBER
     OPERATOR
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Kg)
STATIC PRESS
 (in. HjO)
2.
                                   11
                                              31
                                                         15
MOLECULAR
KT.
.a^r^.o
SIDE 2
-: . . .-*>
PITOT
TUBE Cp
. .
MOISTURE
.A*
                                                                 Jl
                                64
                                                    73
                     FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
SL-I
7
5
*
<
I,
^ - i
7
%
4
4.
if






























POSITION
(in.)











































VELOCITY
HEAD
(Apg) , in.HjO
? 5. J6 «?7 , 28 ,29
//zc?
y.-fe?
/f*o
/*2>-o
A ^0
/. xo
// Z^
/.4-t>
/,f°
/, a^fy
/.**&
X ?rO






























STACK
TEMP, »F
31 .19.40 .41
<££
^^
^7
^?
<2,

&<*
^~6>

•£ U




























-

                                                    (s  -.
                                   B-ll

-------
                                           CAS VELOCITY AMD VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                                       14
       SAMPLING LOCATION
                            CLOCK
                            TIME
                                       46
     RON
    NUMBER
OPERATOR
AHB. TEMP.
  CF)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. R20)
2.
                                    II
                                               11
                                                           is
                                                                   it
MOLECULAR
MT.
.?^
STACK INSIDE DIMENSION (in.)
MAM OR SIDE 1
.&£>* ~. .
SIDE 2
— T->
PITOT
TUBE Cp
• .
MOISTURE
%
./P.
   40
              ** it
                         «1
                                              70
                                                      73
                                                              76
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
*'L
t
3
4
f
&
-/I-/
£
4
V-
4
t*






























POSITION
(in.)
M .1 3 ,I3«U










































VELOCITY
HEAD
(Ap ) , in.HjO
? 5> 26 • 7 7 , 21 i 29
A 10
/,*/*>
/,-&£>
S*&-0
/14*°
/,1*y
/tiff
J.40
/.l^
/i &0
/. f£
// t
<7
^ >
5-^




























-

                                    B-12

-------
                                           GAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN  DATE
1.
                                                       a*     »7
       CAMPLING LOCATION
                            CLOCK
                            TIME
                                      *6
     RUN
    NUMBER
OPERSfb
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Kg)
STATIC PRESS
 (in. HO)
2.
                                                          33       31
MOLECULAR
¥T.
^4rc?
STACK INSIDE DIMENSION (in.)
51 AM OR SIDE 1
./£?.£&£? .—
SIDE 2
•^^j^™ ™ • * • J
PITOT
TUBE Cp
• .
MOISTURE
%
.#?.
   40
                                              70      73
                                                             76
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
/>-!
1
?
+
*.
U
fc>*/
z
5
*
>
If






























POSITION
(in.)











































VELOCITY
HEAD
Ups) , in.H20
2S_i24 «?7 j J»_J»
/,**>
s*to
J.4^
/,4o
/.
/. Z«L
S.2.<
'S.4-*,
/f ^o
/.40
/.4-*
/.*>£>






























STACK
TEMP, "F
1» .19 .40 .41
&^
*;/-
f*f
>
o
5"^-
5"i
<<^>
-r?
-5^
•^>
•£•*




























-

                                    B-13

-------
                                      CM VELOCITY AMD VOLUHE DATA
            PLANT AND CITY
                                                       RUN DATE
  7?
                                                  >4    97
    SAMPLING LOCATION
&
                                   CLOCK
                                   TIME
                                  66
  RUN
 NUMBER
        OPERATOR
AMB. TEMP.
  (*F)
BAR. PRESS
 (in. Kg)
STATIC PRESS
 (in. H20)
                                                          '3.o
                                                              31
                               M
                                          31
                                                     35
MOLECULAR
KT.
..?:*. 7.3
STACK INSIDE DIMENSION (in.)
31 AM OH SIDE 1
. £ P. 0. .
SIDE 2
• . • • i
PITOT
TUBE Cp
-./&*
MOISTURE
%
,^,
40
                                         70
                                                 73
                                                        76
                  FIELD DATA
TRAVERSE
POINT
NUMBER
7,1.9 .10
-} /
Ati
*

-------
                                         GAS VELOCITY AMD VOLUME DATA
               PLANT AND CITY
                                             RUN DATE
1.
                                                      ,/U/fl
                                                    14    17     40
       SAMPLING LOCATION
                          CLOCK
                          TINE
     RON
    NUMBER
OPERATOR
AMB. TEMP.
  (»F)
BAR.  PRESS
 (in. Kg)
STATIC PRESS
 (in.  H20)
                                             Jl
MOLECULAR
WT.
.^??.7.3
STACK INSIDE DIMENSION (in.)
JIAM OR SIDE 1
. £o. D. .
SIDE 2
i . • , •
PITOT
TUBE Cp
Jl
MOISTURE
%
./.4
   40
             ** it
                                                   73
                                                          76
                     FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
/
2.
3
r.
3
I

/
J,
~3
y.
5
L,





























POSITION
(in.)
11 i!7 .13*14










































I
VELOCITY
HEAD
(Apg) , in.HjO
J 5.26 • 77 . 21 .2*
a. 9
/. 1
/ 3
7,3
/- ^
V. V

/./
jj'*:
^
AT
Ay
f'T




























B.I
STACK
TEMP, »F
31 .1 9 .40 .41

-------
                                           CAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
       SAMPLING LOCATION
        .  *
                            CLOCK
                            TIME
                                                      34     37
     RON
    NUMBER
OPERATOR
                            AMB. TBMP.
                               CF)
BAR. PRESS
 (in. Hg)
             STATIC PRESS
               (in. HO)
2.
?
.ECU
                                   >l
                                               31
                                                          35      31
     MOLECULAR
    STACK INSIDE DIMENSION (in.)
                HAM OR SIDE 1
                       SIDE 2
 PITOT
TUBE Cp
                                                      MOISTURE
                                                        ./J).
   40
                                 44     47
                                                     73      76
                     FIELD DATA
                                       B-16
                                                         -  9s;//*

-------
                                          CAS VELOCITY AMD VOLUHE 8*TA
                PLANT AND CITY
                                              RUN DATE
1.
     /*S4#€C? -
       SAMPLING LOCATION
                           CLOCK
                           TIME
                                                     >4
    7
     RON
    NUMBER
OPERATOR
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Kg)
STATIC PRESS
 (in. H20)
2.
     '  *-
                                               -•9.4-
                                  II
MOLECULAR
WT.
. 7fo?
STACK INSIDE DIMENSION (in.)
)IAM OH SIDE 1
. <£.0. -r-r"
SIDE 2
• — -J
-. . . . 7
PITOT
TUBE Cp
•
MOISTURE
%
JP.
               »»
                                                    73      76
                     FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
/r /
?
j
71
'?
^
r>-^
**
•?
*

^






























POSITION
(in.)
11.12 ,13*U










































VELOCITY
HEAD
(Apg) . in.HjO
75. 26.77, ?D ,29
"2 ffo
^
* )o
«'ft«
"^/*/<»
-1' ^°
4i
"3, (e>o






























STACK
TEMP, »F
»,39 .40 .41
$/
•$3
^•^
^<
•55"
££
<^_
^?«>
^*-
j^5
^<
«




























-

                                                  &
                                   B-17

-------
                                         CAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                              RUN DATE
1.
                                                     Stf
       SAMPLING LOCATION
                           CLOCK
                           TIME
     RON
    NUMBER
OPERATOR
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Kg)
STATIC PRESS
 (in.  HO)
                                                         J3
MOLECULAR
W.
.Z.<7.£?
STACK INSIDE DIMENSION (in.)
51 AM OR SIDE 1
.^.o.— — -
SIDE 2
. i • i i
PITOT
TUBE Cp
. m
MOISTURE
t
./*.
                        «1
                                                    73      76
                     FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
k- /
2
**
t+
•5
t>
f- /
7
-*>
4
5
L,






























POSITION
(in.)
11 .U.13.U










































VELOCITY
HEAD
(Ap ) , in.H20
75.26.77. J» .29
•2 -**0
^.^0
4-,*uO
4<*O
4<0
*.,"K.O
3, /o
^/y/o
?,«0
Z.<&0
^Xfo
3, oo






























STACK
TEMP, »F
31.19.40 .41
-?7
ss
f*
s
ss
•<£.

-------
                                           GAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                    /A/Are.*/
                                                             37    49
       SAMPLING LOCATION
   ir
                             CLOCK
                             TIME
     RON
    NUMBER
 OPERATOR
PERA
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Hy)
STATIC PRESS
 (in. R20)
2.
7   TT
                                               31
                                                                   31
MOLECULAR
WT.
7 4 &
.^- . '• i
STACK INSIDE DIMENSION (in.)
5IAM OR SIDE 1
/ _.
. ^r^. . .
SIDE 2
>^
. . . . <**
PITOT
TUBE Cp
• .
MOISTURE
%
/0
. AK i
   40
                         • I
                                                      73
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10
X-'/
7
1
q
«c
'L,
h^l
1
*
•f-
f
*






























POSITION
(in.)
n .13 •11*14











1






























VELOCITY
HEAD
(Aps) , in.HjO
J 5. 56 • ?7 , ?i j J»
^/^e>
^,oto
*,
^xO-O
«f5<7
4-Jo
*>rfo
^••Z-cs
•*.-*. o






























STACK
TEMP, »F
31 .1 * .40 .41
«»

-------
                                           OAS VELOCITY AMD VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                                                   40
       SAMPLING LOCATION
                            CLOCK
                            TIME
                                               49
     RUN
    NUMBER
OP
PERATO
AMB. TEMP.
  CF)
BAR. PRESS
 (in. Hg)
STATIC PRESS
 (in. B20)
2.
                                    11
                                               31
                                                           IS
MOLECULAR
HT.
?4&.
STACK INSIDE DIMENSION (in.)
HAM OR SIDE 1
. £?<=>. ' . .
SIDE 2
-r-^^>
PITOT
TUBE Cp
• .
MOISTURE
%
. L*>.
   40
                                              70
                                                      73
                                                              76
                      FIELD DATA
TRAVERSE
POINT
NUMBER
7.1.9 .10

7
^
4-
£-,
co
"3X_3O






























STACK
TEMP, -F
31.39.40 .41
^2-
^^
^(^^2^^
.^ ^i
^5,
<-^
•S "2-
^. ^
•S-i-
^4-
^.^
s^-




























»


-------
                                         CAS VELOCITY AMD VOLUME DATA
                PLANT AND CITY
                                              RUN DATE
1.
       SAMPLING LOCATION
                           CLOCK
                           TIME
                                                     34     37
   43
                                     •6       »9
     RON
    NUMBER
   -r-
OPERATOR
AMB. TEMP.
  CF)
RAR. PRESS
 (in. Hg)
STATIC PRESS
 (in.  H20)
                                  SI
                                             II
MOLECULAR
in.
2-4.0
STACK INSIDE DIMENSION (in.)
>IAM OR SIDE 1

. b& . . .
SIDE 2
- — ^
. . • . S^
PITOT
TUBE Cp
• .
MOISTURE
%
v.e
   40
                        41
                                      47     70      73      76
                     FIELD DATA
                             X, 10
                                                     f, *  Mtt
                                  B-21

-------
                                           CAS VELOCITY AND VOLUME DATA
                PLANT AND CITY
                                                RUN DATE
1.
                                                       >4     »'
       SAMPLING LOCATION
                            CLOCK
                            TIME
    2
                                      •*      *»
     RON
    NUMBER
OPERATOR
         AMB. TEMP.
           (»F)
BAR. PRESS
 (in. Hg)
                   STATIC PRESS
                    (in.  H20)
                                                              -1*0
                                                          15
MOLECULAR
WT.
./17>
STACK INSIDE DIMENSION (in.)
>IAN OR SIDE 1
.£?. . .
SIDE 2
i . • i •
PITOT
TUBE Cp
./;
-------
PARTICUALTE/ARS ENIC
        B-23

-------
                                         EMISSION TESTING FIELD  DATA
                          AMI I Cltl
                                 lEzmEDaj    nDQED   BOO; 00300033(33)
            il I I I M I  I I I
                           OrtMIM
                                             	
                                                                     HUM
                                       SIAU IHIM
                                       OINU. (HEMS)
                                                                                                        riioi
                                                                                                         IUU
                                                        ThIM
                                                              r«tc

•WOT
                                          vsuxriTV
(Mince PMCSSUM
  oirrtUMTiAi.
  UNI.ln.HjOI
                                              •TACC
                                           flNTCMTUM
                          M* CAS NCTM
                           TtNPCHATURC
                                                                                NET
                                                              OUTLET
                                                             IT   »•«»
                                                               out
                                                                                                 VACUUM.
                                                                                                         MMTL* Ml
INTI
  •r
                                                       .1*1
             **
                                                        74
                                                                       "7 o
                                               V.o
                                                                                    10
                                          «J
 I.V7

                                                                        10
                           #r

                                                                                 &
                                                                                                                       *£>
                            i.i-»
                                                              \ .37
                                             jLmC
                 121T
                                                                 ±
717-0
                                                       «

                                                                                 "f-O
                           7525-

^
                  7+
                                                                                   7 o
                                                                      ^
                                                       A7J
                                                                                            Jl^.

                                                                                                   +-JP
       7;
                                                                                          l
                                              <*•/]
                                                                                        TC
                                              &JD

-------
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND INTEGRITY SHEET
Plant  ASfTRCjQ
                                             Sample date   I-JS-&3
Sample location N» 4 Set^A

Run No.   Pf(TC - ]
                                             Recovery date  /-
                                             Recovered by
Particulate filter No. OOO25QT   ^articulate filter sample  I.D.
                                   MO.STUKE
1st
impinger
Final wt t>6 g
Initial wt A5b g
Net wt "^0 g

2nd
impinger
X/7 g
A5o g
31 g
Total
3rd
impinger
£&P g
Zoo g
2ft g
moisture
4th 5th
impinger impinger Silica gel
31 trf
2oO
7
&7.L
g /V
g iloo
g "^
_ g
_ 9 „
g j
g .
W
fffog
3nn g
/T.i g
% spent
                              RECOVERED SAMPLE
Acetone probe rinse
container I.D.
                             r>
0.1 N NaOH probe rinse
container I.D.         066 / H
H«0 impinger
container I.D.
HpO^ impinger
container I.D.
Liquid level
marked

Liquid level
marked

Liquid level
marked

Liquid level
marked
Blank containers I.D.
     Acetone
                             -
                             ft
     0.1 N NaOH     J5£9"7ft
     H2°2
Samples stored and  locked

Remarks
Liquid level
marked
Liquid level
marked
Liquid level
marked
Liquid level
marked
                              LABORATORY CUSTODY
Received by
Remarks
                                                Date
                                   B-25

-------
                                      EMISSION TESTING FLELD DATA

                      •FfMItt
                                          lit*
                                          rn
MUM.
 iUIIC
 MIU.

(I* «,OI
                      flltll MMIM(S)
                                              lt«tl IHIH
                                             OIN».
                                                             NtOTllMMl
                                                             •*.&» I  _  I
                                                                                                                       tus.
VkSm i/l

                                   MQUll.
yum Utu   MIII I *m CM
!wi M.IMU MiJ  * H 0 I »*»«• *
                                                                              CMCK
                                                                                         K

                                                                                       F«CTO«
                                            c
                                          m
                                                            I  wi
                                                          «t MAT *o
                                                                                                                        •icaw


-------
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND INTEGRITY  SHEET
Plant A
WRCLO


Sample location Ho T sSetanJarv CxMaoTT'
Run No. PA
Particulate
Final wt
Initial wt
Net wt
Wl-/
filter No.<
1st
impinger
//«5 9
/So 9
-^5 9

/

Sample di
Recovery
Recovere<
DooiWo / Particulate filter
2nd
Impinger
y?3 g
/5V3 9

-------
                                                 EMISSION  TESTING FIELD  DATA
                                    • tut
       '$m
               1
                                                                  0»H

                                                                                       WMHIW IOCAIIM
                                                                                                                       SMKI tm
           ""   -- -,-   ^                                        -           -  --                    -1 -
                      I t I I 1 I I I  I I
                                             1  1
-i
. t -^
                                                    in*
            •M.    SIM 1C

           fttss.   w»».

           (I*. Nf»l (li. N.Q)|
                                                                               fllHi
       •IS)
 irnci IWIH

OINU. IIKMS)
fllOl  IMtM

IIM I HA.
                                                                                                                                 fMf
            0QQuu D u u HB IE Ij DID CD [DID I
i..- .-!•«:. .••.  ;
,"--'••*.:'•*.;•••.•:••i. ••';•;"::, t
L{ • ' i ** '*. i  II

  •'       -
MIIU.   I  y. ^.Liii I  MIIJ I «««•«*-
I    «.  i  m [MI M.INI wJ  • N 0 | Mew
M.I  IU«CKC«  1   I     f

f fiiTntlcw     '««"•
w»iCfijffl
P-'^m--.*^'   "/>
^;::^ L^.-.C^

                                                             oniricc rwssuM
                                                               DirrCUMTIAk
                                                                                                                                           ^  •'•-.

-------
                    ISI
ESI
t CITI
                                   O..I
                                                            MIVIIW IOU1ION
                                                        I
                                                                                                 wmi tm

                          IM.  I  SUIIC
                                 nut.
                    CM  (IN. HI)  (I*. ",0)
                                                 il«£I IMIH
                                                OINU. (IKNfS)
                                DirrCUHTIAL

-------
Plant
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND INTEGRITY SHEET

                    _ Sample date
Sample location M»
          ^^

Run No.   PftTL-
                                             Recovery date

                                             Recovered by
Parti cul ate filter No.Ooo25o% ^Particulate filter sampl e lo   '(/ft L ?-
Final wt

Initial  wt

Net wt
   1st
impinger

 SQO   9

       9
       g
             /5o
                          2nd
                        impinger
9
9
g
     MOISTURE

       3rd
    impinger
/56
                                  llo
g
g
g
                            Total moisture
           '     
-------
                                                                                    .   . . A •  .
                   fni.      NJD. ywrti IWTU   win
                      •T  I  ill  !«M MO.IMI wo\  • N t

             W3i
         tfA/A I I i
IfHOIll i 17133H
5>l53 I 14

-------
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND INTEGRITY SHEET

Plant   flSftTo	Sample date
Sample location /^6 V  ^w^g^^-Jary fxAwsTRecovery date
Run No.  /VfcsA- ~L^	Recovered by
Particulate filter No. QQ&2S"b*  S Parti cul ate filter sample
                                   MOISTURE

                1st        2nd        3rd        4th        5th
             impinger   implnger   Impinger   Impinger   1mp1nger   Silica gel
Final wt     /£7  g   /&/  g    ff£ g    X77 g   ftf  g
Initial  wt    /5o  g   /5o   g   ZQO  g   2oZ>   g   Zx>o   g
Net wt       -/g^  g     Y   g   - r fo)g     -3 fp)g   -^ (o) g
                            Total  moisture     yV  g         3D % spent


                              RECOVERED  SAMPLE

                                           L1c
container I.D.         f673--£  ^       marked
Acetone probe  rinse     ^M ._   ^           Liquid level          s
0.1 N NaOH probe rinse                      Liquid level
container I.D.         *>&?% ' rr  "          marked
H20 impinger                               Liquid level
container I.D.         j^7T"^r  ^        marked             ^
HpOp impinger                               Liquid level
container I.D.        <*£>7r~Sr  ^         marked
Blank containers  I.D.                       Liquid level
     Acetone           4-Zoon             marked
                            ~~         Liquid level
     0.1  N  NaOH       c569"7/y  ^          marked
                                           Liquid level
                                           marked
                                           Liquid level
     H20£             Qky£ n   S         marked

Samples stored and locked 	
Remarks
                              LABORATORY  CUSTODY


Received by  ^—££^2t,-c^  ^^'^i^t^    Date

Remarks
                                                          (/
                                   B-32

-------

                                                             SMI 1C
                                                                                                                          Mti

»• XVfS-W—
$&&?.-••''
omricc rncssuM
  OirrCMHTlAl.
                                                                                      Mf CAS NCTKB
                                                                                       TtMPMATUU

-------
                              EMISSION TESTING FIELD DATA
                    t cn»
                                           Mil
1
                                                            UNHIK lOUtlM


I I I I I I I I I I I I I
                       i i i i i
                                    I I
                                                            I I  I I I I I I I
                             1
                                                                                 I I I  I I I I I  I I I I

-------
                                                 	!	.„...,.-„. ....
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND INTEGRITY SHEET

Plant    fefVRCO	Sample date   /- Z ? -

                                             Recovery da

                                             Recovered
Sample location

Run No.
Particulate filter No. 353o44J  ^Particulate filter sample" j^fr
                                    MOISTURE


Final wt

Initial wt
Net wt

1st
impinger
//z. g
™

/5e> g
-3t g

2nd
impinger
/^g
r
/So g
/# g
Total
3rd
impinger
^^ g

2oo g
?- g
moisture
4th
impinger
/^f 9

•zoo g
-1 a
^7 T '3> 9
5th
Impinger
//? g

Zr>o g
- 3 g -
?^

Silica gel
^^•3 g

3oo g

r % spent
                               RECOVERED  SAMPLE
Acetone probe rinse    n\a-i  A
container I.D.         T'"7  rf
0.1 N NaOH probe rinse
container I.D.
H20 impinger
container I.D.

HpO^ impinger
container I.D.
                        4/99 fi
Blank containers I.D.
     Acetone
     0.1 N NaOH
     H2°2
Samples stored and locked

Remarks
Liquid level
marked

Liquid level
marked

Liquid level
marked

Liquid level
marked
                                             Liquid  level
                                             marked
                                             Liquid  level
                                             marked
                                             Liquid  level
                                             marked
                                             Liquid  level
                                             marked
                               LABORATORY  CUSTODY
Received by

Remarks
                                                 Date
                                   B-35

-------
                EMISSION TESTING  FIELD  DATA
ftttt t CITf
                                 Mil
                                                      UNMIM I0t*tION
                                                                                          im
                                                         ....   .   -
          1111 11 i  11  i 11
lit.

       H-D.
  «fl.   it)  I
                                   I MH1  I «IU1M
                             m.oi to  «n»   r«ctai >
                                       CMC!
                                                         cni
 R       C
FACTOR  I MCtM
                       Ul
                                HUM


                 VSUKITff
                                    ffttSSUM

-------
          PARTICULATE/ARSENIC TRAIN SAMPLE RECOVERY AND  INTEGRITY SHEET

               o	Sample  date	/-
Plant

Sample location Mo  4 C

Run No.
                                              Recovery date
                                              Recovered b
Particulate filter No.353(Wlfc> ^articulate filter  sample^D.
                                    MOISTURE


Final wt
Initial wt
Net wt
1st
impinger
/V?-g
/5b g
-J g
2nd
impinger
/£z_g
/so g
2-g
3rd
impingi
;>06.L*
3oo g
<5.l> g
^ % spent
                               RECOVERED SAMPLE
Acetone probe rinse
container I.D.
0.1 N NaOH probe rinse
container I.D.
    impinger
container I.D.

HpOp impinger
container I.D.
Blank containers I.D.
     Acetone
     0.1 N NaOH

     H20
Samples stored and locked

Remarks
                               A-
Liquid level
marked

Liquid level
marked

Liquid level
marked

Liquid level
marked
                                             Liquid level
                                             marked
                                             Liquid level
                                             marked
                                             Liquid level
                                             marked
                                             Liquid level
                                             marked
                                                                   7
Received by
Remarks
                               LABORATORY CUSTODY
                                                 Date
                                    B-37

-------
P.S.D. BLOWING
       B-38

-------


-------
                IMPACTOR  EMISSION TESTING  FIELD  DATA
VtMtOI
                   M.   MM.
                   TO
                              1IMIC
(I*.
                      IMTACTOR TTfC
 $!«• IMIH
•MM. |UMt|
                                               ^
                                                                  I A I I 1 I
             MIKI.   I tUt. IWWUlMflt
          i.r i    «••   li» !m wltoi••]  • N •
                           oniricc rwssu
                             oirrtWHTiM,
                                  Mf CAS MCTta

                                   TtMKIIATUU

-------
               ANDERSEN IHPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location
Run number
                                             Sample date 	
                                             Recovery date   ///?/g5
                                             Recovered by  A(cP
                              RECOVERED SAMPLE
Nozzle rinse
container number _
Acetone blank
container number _
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                                         Liquid level
                                         marked
                                         Liquid level
                                         marked
                         Filter number  <•'•
                                      S
                            510
                              53
Container sealed
jine
                                                       '/
                             LABORATORY  CUSTODY
Received by
Remarks
                                              Date
         /
                                     B-41

-------
              IMPACTOR EMISSION TESTING  FIELD DATA
VtMtOi
                |*rt
                     Mill.
                          MM If
1HPHCTW TTK
                                                                mm
                                    ««« I MM
                                             nEiifflffl
                                                           *


-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location /fa .
Run number
                       *5eto«<)*r
                                              Sample date
                                              Recovery date
                                              Recovered by
                              RECOVERED SAMPLE
                   4-iSlfr
Nozzle rinse
container number
Acetone blank
container number
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                                         Liquid level
                                         marked
                                         Liquid level
                                         marked     t
                         Filter number
                                                  Container sealed
                                        s377g-
                                        377
-------
                                                IMPACTOR EMISSION TESTING FIELD  DATA
                               flMt • CITI
                                                                                   urn nit IOUIIM
                                                                                                                     tm
                                       "                            "   "     -  :*-              >
                                                                                 yf-trftft-i i i i i i i i i i  i
                                                             SIM It
                                                                                   ffl

                                                                                                  , 1   .
                                                                                                           . .
                                                                                                                       ifi/o.
                                             •OlliU
.1 M. iMlMiUtll I  Mill I -MM«* |_J
m.  i it> !JQI M>IHI wJ  • m I Mcwi "ET
                                                                                 «««««
                                                                                                         MM ui »t in
i  •
S
                                                           OMiricc russuM
                                                              irrcMMTiAt
                                                             UMI.In.N.OI
                                      Mf CAS MCTKB
                                       TCNrtMTUMC

-------
               ANDERSEN IMPACTOR  RECOVERY AND INTEGRITY SHEET
Plant  //JCp    /QJ^ _ Sample date
Sample location ^. T ^cowc/afi/ <£>/?.au}T   Recovery date
Run number   p£x£> ~O	Recovered by _

                              RECOVERED SAMPLE
Nozzle rinse            //tfzA-         Liquid level  /
container number       T/o^n -'      marked       '
Acetone blank           .                Liquid level
container number	^rloo $  t	marked        /
Filters
     Stage               Filter  number      "  ':   Container sealed
       0
       1
       2
       3
       4
       5
       6
       7
     Backup               i/?-35$ :    ,  " •'/'.'"      /
Samples stored and locked
Remarks
                             LABORATORY CUSTODY
             V  /'       .  /\x;/  .-  '
Received by   \-ts- ,L< *.-••  ••-^-/ Va-fi.,.     Date
           •; >yr  ^ fC-/'/
            T7
Remarks  / •; >yr  ^ fC-/'/
                                   B-45

-------
                                    IMPACTOR EMISSION TESTING  FIELD  DATA
                  1MI I Cltt
                                 33
                                             &E
                                                    Mil
»|n|u|.JM|M|oJ..
                                                                          VMfllW lOUttION
                                                                                                              tm

            1 17?h|iH»|n
                                                                                                            MlKllt
BHBri
               i  i i  i i  i i  i i i i i i  i i
                                                                      I 1 » 1  I I  1 I  I
•".0. |VM»||IWIII
III !lOI MINIM
                                                        Will
                                                        t N t
                                                                 Mtll CM
                                                                 »«CIOt T
                                                                       IOU CMC*
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                                             c
                                            MCVM
                                                                                                 •At Ml
                                                                                                       MAI U1
       H.V
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                                    I  I I
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                                                             L.
                                                                              '  »
                                                                                    MIA
                                            A I I
                                                                                                  '  ' *
        I I
                                                oniricc russuu
                                                  DirrCUHTIAL
                                                                                                                         CONDEN8ER
                                                                                                                        TCMPEKATURK
                                                                                                                            •r

-------
                              HMI t en?
                                                                    Mil
                                                                                           VMMIK IOUMM
                                                                                                                                   tm
                                                                                       ~  •       "  ----------_^4|
                                                                                                       111
         J3P
                                VIMtOI
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                                                                                   IMPWTOM TYPE
                                                                                                               M«CI IHIH
                                                                                                              DIMM.
                                                                                               IMM
                                                                                                C»
                                                                                                                                 TMW
                                                                                                       7^^l *«|«>|M|tt
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                        i i
                                                                                         LJ_LJ_i_l_L_U_l
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                    IIMTM MB tiff
                                              •int.
                                                          .O. |MI»II'WTU * win
                                                          t) !HI HO.IMI n.  » H •
                                                        •Mi.
                                                             JLL
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                                                 r«cioi t
                                                • llMUt Ul «l
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                                                                                      JM. M(
                                                                                        J-L
                                                                        I I  I I
 MM    W     H.V  I1
MAI UflHUI Mil   •»   I
                                                                                                                         UJ U D 010 (C Q CD Q UJCD CD C
                                                                                                                       I  I A I  I I A I A I  I
ym»Tio
»V<70|?» I 13173134
        5>iS3l»4
                                                                                                                                                   17
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                                                                                                OUff CAS NCTEB
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             •P
 CONDENSER
TCHPERATUKe
    •r
                                                                  ±L
                                                         ±
                                                                                                                                  f

              f


-------
               ANDERSEN IMPACTOR RECOVERY AND  INTEGRITY SHEET
Plant 	
Sample location /K> T v5eco*/c/a.ri/
Run number   ^~^"
                     Sample date   /
                     Recovery date _
                     Recovered by
                              RECOVERED SAMPLE
Nozzle rinse
container number 	
Acetone blank
container number 	
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7 .
     Backup
Samples stored and locked
Remarks
Filter nu
                                  mbe
                                         Liquid  level
                                         marked
                                         Liquid  level
                                         marked
Container sealed
                                         -  .1 '/ / '•
ner
                              X
Received by
Remarks
    LABORATORY CUSTODY
    •   '^--^ L / c T.'  Date
       <; ^  /?f
                                    B-48

-------
P.S.D. SKIMMING
     B-49

-------
 IMPACTOR  EMISSION TESTING FIELD DATA
VCLOCITt
  •CAD
(A* ).!•.•,€>
 CONDENSER
TCKPEKATUKE
   •r

-------
                                        IMPACTOR EMISSION TESTING FIELD  DATA
                       WtMtOI
                                           1*0
 •M.    IUIIC
 MISS.   ram
(II N9|l IMIM
              Mill
              • N •
Mill CM.
ratioa ?
                                                                             IUU CNtCK
                                                                           IM.
                                                                                  era
                                                                                          MCTOI
                                                c
                                               MCI
                                                                                                        •«! tit
                                                                                                              MAI Ml
                                                                                                                         .
•i
 MU
 HIM
i i i i i i i i i i i i i i i i  i i
                              AIM
                                        I I 1
I  I I  I
             A 1  1
                                                                   A 1  1  1
         11
                                  A I  M I  M I I A
                                                                                                         1 1 A
                                                                '  'A 1 A I  I
                                                                                                                                           I

-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant  H5ftKCO      /OCQ^Q^	Sample date
Sample location Ho. 4 5fiona)c.ry  E'yhauJt'     Recovery date
Run number  /^-SJ^f-yC ~ /	Recovered by
                              RECOVERED SAMPLE
Nozzle rinse                             Liquid level   /
rnntainpr numhpr   V/7'T/?'  --           imrkpri        /
Acetone blank       ^     ^             Liquid level
container number    "7^>o H  »          marked
Filters
     Stage               Filter number   "  '  '    Container sealed
       0
       1
       2
       3
       4
       5
       6                .*.
       7
     Backup
Samples stored and locked
Remarks
                             LABORATORY CUSTODY
Received by    V A.
-------
                    IMPACTOR  EMISSION
MMT • cut
                                     Mil
                                                                   IOUIIOM
                                                                                                    Tiff
                                                                                      MllllM
 •HMIM
                            Ml SI.
                           II". N|1
 iMTIC
 Mill
(I". «,(
                                                     IMPACTOM TTPt
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                                                                                              mot
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                                otiricc VKCSSUM
                                   DirrCUMTIAL
                                                                                                                     CONDENSER
                                                                                                                    TEMPERATURE
                                                                                                                        •r

-------
               ANDERSEN IMPACTOR RECOVERY AND  INTEGRITY SHEET
Plant
Sample location //c
                                              Sample date  _/
                                                            7W83
Run number  /?J> 55 "
                                  £xh*us1'   Recovery date
                                              Recovered by
Nozzle rinse
container number
Acetone blank
container number
                              RECOVERED  SAMPLE
                                         Liquid  level
                                         marked
                     y-Zo
                                         Liquid level
                                         marked
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                         Filter number
                                                  Container sealed
                                                     X
                                                      X
Received by __-.
Remarks
                             LABORATORY  CUSTODY
                                               Date
                                                          y
                                      B-54

-------
                                           IMPACTOR EMISSION TESTING FIELD DATA
                           AMI • tilt
                                                          Mil
                                                                                   IOUIIOM
                                                                                                           vmt im
                                  . i. i	
                            MtMIOI
                                              m
                                         MIM.
                                        II". HQ
 SHI 1C
 MtSt
(•• |^0)
                                                                       IMPACTOR TYPE
                       HKI IHIH
                       • MM.
                        mot
                        IUW
                         c»
                                                                                                             TWW
                                             301
                                        Hill II M
                                                                 fidk
                                                                              . . .     .
                                                                                                    All
                                                                                                7ST777M17
                      MB im
                                        Mtttt.
                                                                       CM.
                                                                           lUKCMICI
                                                                                cm
                                                                          iptp
                                                                              •
                                                                             racm
                         c
                        raciw
                                                                                                   •Ul Ml
                                                                                                         MAI HI
                               Mr.
                               •r
                                                                                                                     •u
                                      Mill III
                                                         •lU*l«t btlil
                             t»[tr[n|n
                                                                                               >t|ii|rt|n
           1  I I I I I I I I
                                   i/i&t
                                                                 JJL
                                                                       ' ' '
                I I  I I A
9M9H9
                imolll i »|i3|74
           47f43M4|45|4IS>IS4
VUVKMW
                CMC* TIM
            UMCX.  (>« fcr
                                 VELOCITY
                                            oviricc russuM
                                              OirrtUHTIAL
   STACK
tIH»CIWTWMI
OUT CAS MCTKM
 TrNPCHATUU
                                                                                         OUTLET
                                                                                          ewt
                                                    IPO> ACTOR
                                                   TCHPCKATUIIB
                                                      •T
 CONDENSER
TEMPERATURE
   •P
        mz
                                                                                                                       V7
                                           w

 1
              »•
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                  ^?
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             60
          Zr.F
                                                                                           xJi
             4
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                                                                           5

                            m
                                                      m
            23.
                    2



-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location
Run number
Nozzle rinse
container number
Acetone blank
container.number
Filters
                    V

Sample date _
Recovery date
Recovered by _
                                                                /Z-V&3
                              RECOVERED SAMPLE
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                         Filter number
                                         Liquid level
                                         marked
                                         Liquid level
                                         marked
                                                  Container sealed
                                            .-; /
                             LABORATORY CUSTODY
Received by
Remarks   •'-;.
               x
               ( J
                                               Date
                                    B-56

-------
                 tlttl I tltf
         i i i i i i i i i i i  i t i i i i i i i i i  i i i
                                             Mil
                                                               VMVllW IOUI ION
mnn
                  •ffMIOI
           i  i i i i  i i i i  i i i i i
                                  u •»
                                        IllH It
                                      MIM.
                                     (IN. H,(
                                            aWTi-B
       SIM 1C
       MIH
       (!• it 0)
                                                        IWACTOK TYPE
                                                              I  I I I  I I I
                                                                                       IMIM
                                                                                   •!«•. (IKMt)
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-------
ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location //n
Run number
                               Sample date   IH1
                               Recovery date  |-/fl-
                               Recovered by /H\(jP
               RECOVERED SAMPLE
Nozzle
container number
Acetone blank
container number
Filters Pr<
     Stage
       0
       1
       2
       3
       4
       5
       6
  67.r
                          Liquid level      X
                          marked         /
                          Liquid level
                          marked
          Filter number  ._.
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   /
                                     /
                                      /
                                       X
                                      X
     Backup
      ^•filter
Samples stored and locked
Remarks
          OOOOOO5 •
Received by
Remarks  -c.v.  '/; -/C /^
              LABORATORY CUSTODY
                                Date
                       B-58

-------
PARTICLE SIZE DISTRIBUTION
        CHARGING
         B-59

-------
                           IMPACTOR  EMISSION TESTING  FIELD DATA
         HAM • Cltl
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-------
               ANDERSEN IMPACTOR RECOVERY AND  INTEGRITY SHEET
Plant
      /J5fl%CjQ
                                             Sample date  f-
Sample location fjn V ^)e.cz»jJa r /  £xh<\usf'   Recovery date  > - ^ "
Run number  /l$ A\C.Jf-'jL "/ __
                                             Recovered by
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Nozzle rinse
container number 	
Acetone blank
container number 	
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
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Samples stored  and  locked
Remarks
                        Filter number
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                                        C  '"/'•t'i t'

                                         .': .-'-I''- '
                                                     x,
                                                     X
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Remarks

                            LABORATORY CUSTODY
                                              Date   >-'>*•  '/.'•:. u
                                    B-61

-------
                                             IMPACTOR EMISSION TESTING FIELD DATA
                           HMf • tltt
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-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location^
Run number
                                              Sample date
                                  £xrfou$F    Recovery date ///*?
                                              Recovered by
                              RECOVERED SAMPLE
Nozzle rinse
container number _
Acetone blank
container number 	
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                         Filter number
                               -o 3
                                         Liquid level
                                         marked
                                         Liquid level
                                         marked
                                                  Container sealed
Received by 	
Remarks    .V.-,-'
                             LABORATORY CUSTODY
                            N.''/:,.;. T<-._      Date
                                                          ~> '.'
                                     B-63

-------
IMPACTOR EMISSION TESTING FIELD  DATA
             sum
       MISS. I MISS
      III. Mil' ("•
                                       OH* CAS MCTKB
                                       TTHPCRATUM:
                                     TiCcV
 CONDENSER
TEMPERATURE
   •r

-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
                     /o c
Sample location //0
                                  £fy/fcJ?T
Run number    /?S/f\C^
                                              Sample date _
                                              Recovery date
                                              Recovered by _
                              RECOVERED SAMPLE
Nozzle rinse
container number 	
Acetone blank
container number   YZop
Filters
     Stage
                            /)  .
                         Filter number
       1
       2
       3
       4
       5
       6
       7
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Samples stored and locked
Remarks
                                         Liquid level
                                         marked
                                         Liquid level
                                         marked
                                                  Container sealed
                                        •*•'/-'
Received by
Remarks    <
                            .LABORATORY CUSTODY
                                   x'
                                     B-65

-------
                                                   IMPACTOR  EMISSION TESTING  FIELD  DATA
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-------
 ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant
Sample location //Q
Run number
                                Sample date    //
Nozzle rinse
container number
Acetone blank
container number
                    xfjj-Aat.7/"   Recovery date
                                Recovered by
                RECOVERED SAMPLE
                           Liquid level
                           marked
                  L
          2oo ft
                                         Liquid  level
                                         marked
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
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Samples stored and locked
Remarks
           Filter number
                           '     r
                                                   Containersealed
                 " 00  >
Received by
Remarks
  . x1
--• -*•-
                             LABORATORY  CUSTODY
                                 --^"'  •
                                ^-•'/-/..i *..  Date
                                                          /''  -^'c-'-  /?':/' 3
/
                       B-67

-------
                                   IMPACTOR  EMISSION  TESTING  FIELD  DATA
                 • CITf
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-------
               ANDERSEN IMPACTOR RECOVERY AND INTEGRITY SHEET
Plant        o   /b,vof^ _       Sample  date
Sample location M> -/ 5e<*uJa.ry C*h*.vsl      Recovery  date
Run number  P^£&<3    fe^C^S _ Recovered by
                              RECOVERED SAMPLE
Nozzle rinse
container number 	
Acetone blank
container number 	
Filters
     Stage
       0
       1
       2
       3
       4
       5
       6
       7
     Backup
Samples stored and locked
Remarks
                                         Liquid level
                                         marked
                             ft
Liquid level
marked
                         Filter number  ^1  '--/I   Container sealed
              ine
              /
                          v/jF-26
                             LABORATORY CUSTODY
Received by
Remarks
           <- <.
             /
                                    B-69

-------
TRACER INJECTION DATA
         B-70

-------
                         SF6 TRACER GAS INJECTION  DATA
                               RUN NO.
Date
            f
                                Plant
Injection location
Barometric j>ressure

Operatoi
                                      in
                                        .Hg/
Ambient temperature, °F
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             n
                                                                               psi
Time
(24-h)



/^/^
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Bubble meter rate, cc/min
Time
/2,(r/
//.56
//,/ 5
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/
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time, min



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Note:  The tracer gas injection rate is set immediately before  the  actual  source
       injection and checked at the end of the source injection.  The  source
       injection rate is the average of initial  and final.
                                   B-71

-------
                           SF6 TRACER GAS INJECTION DATA

                                 RUN NO.
   Date
                       ///
Injection location   /7//Z

Barometric/pressure

Operator
                                        in.Hg     Ambient  temperature, °F
   Regulator  pressure
                                                                              psi
    Time
   (24-h)
         Time
                           Calibration data
                    Bubble meter rate, cc/min
Initial
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
           Jiff
fl
                             /l./t,
                                                         ,0
           /3,/tr
                                         '
       70
          ft -1d'
                            12
  Note:  The tracer gas injection rate is set immediately before  the  actual  source
         injection and checked at the end of the source injection.  The  source
         injection rate is the average of initial  and final.
                                    B-72

-------
Date
                         SFg TRACER GAS  INJECTION DATA

                               RUN NO. 	


                                Plant
Injection location

Barometric

Operator
                                      in.Hg     Ambient  temperature, °F
Regulator pressure
                                                                               psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                       X
          *.
Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The source
       injection rate is the average of initial  and final.
                                  B-73

-------
Date
                             TRACER GAS INJECTION DATA

                               RUN NO.
                       Plant
Injection location
            ^
BarometriCxUressure

Operator
                             in.Hg      Ambient temperature, °F
Regulator presure
                                                                      _psi
 Time
(24-h)
                         Calibration  data
Time
           Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                                     X
                                                             W.It*
                        s

                                     X
                                                             ft,**
                                        X
        /3
        /JV-7
                                         X
Note:  The tracer gas injection rate is  set immediately  before  the  actual  source
       injection and checked at the  end  of the  source  injection.  The  source
       injection rate is the average of  initial  and  final.
                                  B-74

-------
                         SFg  TRACER GAS  INJECTION DATA

                               RUN NO.
Date
                                Plant
Injection location
                     /
                                                   Le. —
Barometric/pressure

Operate
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                               psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble  meter  rate, cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                                                            4 '*?•
        /3,/Z-
                                       ft Mb
        It.W
        II.
                                     40
Note:   The tracer gas  injection  rate  is  set  immediately before the actual source
       injection and checked  at  the end  of the source injection.  The source
       injection rate  is  the  average  of  initial and final.
                                  B-75

-------
Date
 A/V-ts
      SFg TRACER GAS INJECTION DATA

            RUN NO. 	


             Plant
Injection location
             X"
Barometric mressure

Operator L^jJ,
                            in.Hg     Ambient temperature, °F
Regulator pressure
                                                                    psi
 Time
(24-h)
                        Calibration data
Time
           Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
        />>
        1 1,16
                   //-£•/
        tt.tf
                           //.It,
        /A £3
 /fa*
Note:   The  tracer gas injection rate  is set immediately before  the actual source
       injection and checked at the end of the source injection.  The source
       injection rate is the average  of initial and final.
                                   B-76

-------
Date
          I' I *1 -%>
Injection location
                         SFg TRACER GAS INJECTION DATA

                              RUN NO. _


                               Plant
Barometric pr^isure

Operator
Regulator pressure
                                     in.Hg     Ambient temperature,  °F
                                                                              psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble meter rate, cc/min
                  Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                            //.f f
                                     •50.
                           v//
                                    7
                                                                       3.0
        //,
                                       ^-  z-
                       )
                             //*?

Note:   The tracer gas  injection  rate  is set immediately before the actual  source
       injection and checked  at  the end of the source injection.  The source
       injection rate  is  the  average  of initial and final.
                                  B-77

-------
Date
                        SFg TRACER GAS INJECTION  DATA

                              RUN NO.
                      Plant
Injection  location
           yT/^f
                                             *f- P-*-IA s2*
Barometric ope'ssure

Operator
                            in.Hg     Ambient temperature, °F
Regulator pressure
                                                               £?   psi
 Time
(24-h)
                        Calibration data
Time
        ft./b
           Bubble meter rate, cc/min
                 Initial
Time
                              lilt
                            12,
Final
Average
                                                 1331
Injection
  rate,
 cc/min
                                                    43 >o 2-
Injection
time, min
Note:   The  tracer  gas injection rate is set immediately before  the actual source
       injection and checked at the end of the source injection.  The source
       injection rate is the average of initial  and final.
                                  B-78

-------
                         SFg TRACER GAS INJECTION  DATA

                               RUN NO.
Date
         /-   *l ~
Injection location

Barometric  ressure

Operator
Regulator pressure
                                      in.Hg     Ambient  temperature,  °F
                                                                               _psi
 Time
(24-h)
                         Calibration data
         Time
         17
                    Bubble meter rate,  cc/min
Initial
Time

                             J2.W
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.  The source
       injection rate is the average of initial and final.
                                   B--79

-------
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO.
Date /" /T " "S3
Plant
Injection location ./$£ X^y /^T/^
Barometri c^feT
>^ ^
Operator //-<
f —
!/
/T&&ZCO- /AccwiA /wfetf.
f £f#4c^vL/^^/**f'^rf*.6>b
















' Average



•/-#•£#
















Injection
rate,
cc/min



^^5
















Injection
time, min



T?>O
















Note:   The tracer gas  injection  rate  is  set  immediately  before the actual source
       injection and checked  at  the end  of the  source  injection.  The source
       injection rate  is the  average  of  initial  and  final.
                                  B-80

-------
Date
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO.'
                                Plant
Injection location
                                     £?Wi*£»T
Barometric pressure

Operator
                                      in.Hg     Ambient temperature, °F
ff /
Regulator pressure /^ psi

Time
(24-h)



/oil
t




/CZ$











Calibration data
Bubble meter rate, cc/min
Time
/'7^?
/2,4(
/2-ZZ
fzAl


/3&1
n,i%
rt
fatjt^


J2.40
/z.$f
/Z-Z3-
/?'5>T










Final
X
/
/
tfiMz-


/
/
/
i$ .<:*£>










Average



t>










Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The source
       injection rate is the average of initial  and final.
                                  B-81

-------

           Date
                                   SFg TRACER GAS INJECTION  DATA

                                         RUN NO.
                               Plant
                     A
Injection location

Barometric

Operator
           Regulator pres«/re
                                                in.Hg     Ambient  temperature, °F
                                                                              psi
fa.l-f
fa,
            Time
           (24-h)
                                   Calibration data
         Time
                     . 6 4
                    Bubble meter rate, cc/min
Initial
Time
Final
                                                  X
Average
Injection
  rate,
 cc/min
Injection
time, min
           Note:  The tracer gas injection rate is set immediately before  the  actual  source
                 injection and checked at the end of the source injection.  The  source
                 injection rate is the average of initial and final.
                                           B-82

-------
                         SF6  TRACER GAS INJECTION DATA

                              RUN NO.
Date

Injection location

Barometricj>ressurj

Operate
                                     in.Hg     Ambient temperature,
Regulator press
               ore
                                                            _psi


 Time
(24-h)
                         Calibration data
         Time
        tf'tf
                    Bubble meter rate, cc/min
Initial
                       X
                       X
                        X
                X
Time
Final
                                    X
Average
Injection
  rate,
 cc/min
Injection
time, min
                                                                        /o.o
Note:  The tracer gas  injection  rate  is set immediately before the actual  source
       injection and checked  at  the end of the source injection.  The source
       injection rate  is  the  average  of initial and final.
                    ti
                                 B-83

-------
Date
                         SF6 TRACER GAS INJECTION DATA

                               RUN NO.
Plant
                                       n
Injection location
Barometric ppeisujf-e ±

Operator
Regulator pressu
                                      in.Hg     Ambient temperature,  °F

Time
(24-h)



b^y
















Calibration data
Bubble meter rate, cc/min
Time
fr.W
/?-37
fr&is
/2,2,a
















Initial
^
/
/
*/-$.£&
















Time
IJ%£
U, GO
iJ.Pb
/p ,o (
















Final
/
/
/
' f?ff&
















Average



"7^£>
















Injection
rate,
cc/min



^.t-3
















Injection
time, min



$$.o
















Note:  The tracer gas injection rate is set immediately before the actual source
       injection and checked at the end of the source injection.  The source
       injection rate is the average of initial and final.
                                   B-84

-------
                        SFg TRACER GAS INJECTION DATA

                             RUN NO.
Date
           H-S-S
Injection  location
                   A
  Plant   rfe/fag-gg-
                       Uks^.
Barometric pre^ure

         (  ^f~
Operator
                                    in.Hg     Ambient temperature, °F
Regulator pressu
                                                                           psi
 Time
(24-h)
                        Calibration data
        Time
                   Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time,  min
                              . 55'
                 /*>$
           - 1
 A- Z*
Note:   The tracer gas injection rate is set immediately before the actual source
       injection and checked at the end of the  source injection.  The source
       injection rate is the average of initial and final.
                                   B-85

-------
                         SFg TRACER GAS INJECTION  DATA

                               RUN NO.
Date
       /-
       "|
                                Plant
Injection  location
                    /?/
Barometric p/essure

Operator
Regulator pressure
                                     in.Hg     Ambient temperature, °F
                                                                               psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble meter rate, cc/min
                  Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                                                                            , 0
                                                 - 7
                                5 /
Note:  The tracer gas injection rate is set immediately before  the actual  source
       injection and checked at the end of the source injection.   The  source
       injection rate is the average of initial  and final.
                                    B-86

-------

Date
Injection location  /vi (L
                         SF6 TRACER GAS INJECTION DATA

                               RUN NO.
                                Plant
                                              5» 7
Barometric pjjetsure,

Operator
                                      in.Hg     Ambient temperature, °F
Regulator pressure
               I
psi
Time
(24-h)



#02^









/? tf






Calibration data
Bubble meter rate, cc/min
Time
#•*?
/i $6.
/;,*&
tifi*>

BJ-I
&2-1
//-/
fT^

/?.-&>
/;Yf
/J<3&
/?&i'

C/e't
f/f'L
o/-/
M-t

Initial
X
/
/
^^\
1^





/
/
/
wyj
^r*





Time
/73V
£,4f
b^t
/J.31






fc.Ze
/S-fg
tf'5*-
ti.te






Final
X
/
/
^s.y.3







/
/
fart






Average



41.**










-------
Date
                         SFg  TRACER GAS INJECTION DATA

                               RUN NO. 4
                               Plant
Injection location
Barometric pressure

Opera torC—~7frf>
                                     in.Hg     Ambient temperature,  °F
Regulator prestwre
                                                                              psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble meter rate, cc/min
Initial
Time
Final
                                              /
Average
Injection
  rate,
 cc/min
Injection
time, min
        tf.'H*
                            Jl.kl-
        A??
        Ml
             4
Note:  The tracer gas  injection  rate  is set immediately before the actual source
       injection and checked at  the end of the source injection.  The source
       injection rate  is  the average  of initial and final.
                                     B-88

-------
                        SFg TRACER GAS  INJECTION DATA
Date
          -
Injection location
                              RUN NO.
                               Plant
                                          - 14
Barometric  Assure

         [  j~-J>T
                                     in.Hg     Ambient temperature, °F
Operator
Regulator pressu
                                                                            _psi
 Time
(24-h)
                        Calibration  data
         Time
                   Bubble meter rate, cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/mi n
Injection
time,  min
               X.
               LWv.
                                    2 ^. Z 1 . 2
        n.+l
                                     
-------
TRACER SAMPLE COLLECTION DATA
             B-90

-------
Date     /
                    SFg TRACER GAS BAG SAMPLING FIELD  DATA

                               RUN NO.  -P£tf//K'V«^


                               Plant
Sampling location 	At
                     '«
Barometric pressure    HI-  *> 3.

                                                                              in.Hg
Ambient temperature, °F

Operator    S<-^{.
Sample bag leak checked
                                               Stack  temperature,  °F
         Sample train leak checked
                                                                          t/
  Time
 (24-h)
                 Traverse
                  point
AP
Rate meter
flow^rate,
                                       Dev.
                                    I
                                    I/
     o 3
                                 /,
                       -> &
                        i a
                                 /,
  /C e>
            Q - Q
                    -) 100
               avg.
                                                       Average
                                  B-91

-------
                         SFe TRACER GAS BAG SAMPLING FIELD DATA
                                   RUN NO.
      Date
                /
Plant
C/O
      Sampling location
                           /y0,  T
       Barometric pressure
       Ambient temperature, °F
       Operator
                                               Stack temperature, °F
       Sample bag leak checked

                                               Sample train  leak checked
 ll

f»
m
   I/
  \\
  n
dp   '
         Time
        (24-h)
         1711
          l IB
                    Traverse
                        B3-4
                 ffTJi-V
                6)
                           - 3
               'M
               (I£L
                 Y/r)   c 4 -
      AP
                                             a
                                         7
                                     ft/x
                                    tf Yff
      Rate meter
      flow rate,
       cm3/min
                  Q - Q
          Dev. = (	^Si)  100
                    avg.
                                                      Average
                                                      (Must be <10%)
                                                                          1n.Hg
                                                                          Dev.
                                       B-92

-------
                          SFg  TRACER GAS BAG SAMPLING FIELD DATA

                                    RUN NO.
Date    /'  /* Dev. = (  Q"W)  100

                    ^avg.
                                          f A/-
                                        /
                                                     Average

                                                           be
                                        B-93

-------
                       TRACER GAS BAG SAMPLING  FIELD DATA

                              RUN NO.
Date
         /
Sampling  location
Barometric  pressure
Ambient temperature, °F   ^\5

Operator 	
                                              Stack temperature, °F
Sample bag  leak  checked
  Time
 (24-h)
                Traverse
                   Cl-l
                   AH
                    66 -I
            Q  - Q
                   -) 100
                                              Sample train leak checked
  AP
in.H20
                                         (*
                                    /
Rate meter
flow rate,
 cm3/min
                                                      Average

                                                           be
                                                                           Dev.
                                  B-94

-------
                             SFg TRACER GAS BAG SAMPLING FIELD DATA

                                        RUN NO.
         Date
                                     Plant
                                   i
                                 //&,
       Sampling  location _

       Barometric pressure

       Ambient temperature, °F      r&

       Operator 	
     v»y
                                                        Stack temperature, °F
       Sample  bag  leak checked
           Time
           (24-h)
                       Traverse
                                                        Sample  train leak checked
 AP
Rate meter
flow rate,
 cm3/min
                                                                                      in.Hg
                                                                                  Dev.
1
V,
                            c t>
                     Q - Q
                             -) 100
                                                   A
M'/
                                                                Average
                                          B-95

-------
                  SFg TRACER GAS BAG SAMPUflG FIELD DATA

                            RUN NO.
Date     A/7-/3
                            Plant
Sampling location     tfff. r
Barometric pressure
Ambient temperature, °F

Operator
Sample bag leak checked
                                          Stack temperature, °F
                                          Sample train leak checked
                                                                       in.Hg
  Time
 (24-h)
  7/5/7
               VT^averse
                  tl-l
          CL)     CL-1
          fi)     Dl- /
          ffi
ft
          (//
                   cl-3
                        AP
                                /.¥  /T7
                                /,37t
Rate meter
flow rate,
 cm3/min
                                                                      Dev.
          fO)
                    LL-3
          M
                                         - T.3
 t/
                    01 -
           Q - Q
                  -) 100
             "avg.
                                  }
                                                  Average
     /£/ v 7

                                                 1,3    -£  55

-------
                    SFg TRACER GAS  BAG  SAMPLING FIELD DATA

                               RUN  NO.
Date
      M
13
                               Plant
Sampling location
Barometric pressure
                                                                             in.Hg
Ambient temperature, °F
             *-7
Operator      i£
                                              Stack temperature, °F
Sample bag leak checked
                                 iX
                                               Sample train leak checked
                                  B-97 .

-------
                    SFg TRACER GAS  BAG  SAMPLING FIELD DATA
                               RUN  NO.
Date
Plant
Sampling location
Barometric pressure
Ambient temperature,  °F
Operator
                Stack temperature,  °F
Sample bag leak checked
                Sample train  leak  checked
                                               in.Hg
                                  B-98

-------
          SF,  TRACER GAS BAG SAMPLING FIELD DATA
            6
                    RUN NO.
Date ///?> 4> 7 Plant i.v59
f&: ay
i L : c>n
(4: 1 1
ikM^j


/^- 13
(4; 2>S







Traverse
Oi)i5 point
ftp- fe^-i
to) BZ-t
fe?N Gl-
(7^ Cl-"2-
te& Cb ~)
fiJ5S C^-'Z,
ri)O &\~i
fz^ &\ ~~L


(to) S?
(7s ^P
(?J ^^
(^M >S^




AP
j?^S/ 9^
%>u ^ &
3V ?o
\^l <%(
33-71
33 H~)
3^/"7")
^/ "?s^


^,q/ -|CS
jT?/ "TV
/
/





Rate meter
flow rate,
cm3/min

s'c^L-'fe*' - tr.z.
















Average
rt rt

X Dev.a



















(	^^)  100
                       B-99

-------
           Date
                       TRACER GAS BAG SAMPLING FIELD DATA

                             RUN NO.


                             Plant
                                                                 T  */-
          Sampling location
           Barometric pressure
Ambient temperature, °F

Operator _ C.  A /JTg
                                                       Stack temperature,  °F
          Sample bag leak checked
 p\ctec
—.	
  s^^
            Time
            (24-h)
&L
           o 
-------
      SF6  TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
                              - XX y
Date \in/oJ> Plant /JJ/ltCO
Sampling location ^ y ^# Mf<->£7~
Barometric pressure <^A ?O in.Hg
Ambient temperature, °F vS~£> Stack temperature, °F "7^
Operator
Sample bag
Time
(24-h)
/Z'OG
//.: 
A?'. /^
/I '. 2^
'^Z-'- ZZx
/•z : z^L\
^7 "Z?










P Arres*sec*l^


leak checked ^^ Sample train leak checked ^.^x^

Traverse
point
3t=— &2-~J
3c~~ &Z-'Z—
**- c/-/
31?- C/—Z_
^«T- c£ -/
?»7 - C^> - Z_
^ {
13 / C-SL-
\.iS/ (^3











Rate meter
flow rate,
cm3/min

"
b v**^
-1-^














Average
r> r«

% Dev.a



















'« Dev.  =
   av9
)  100
be <10%)
'avg.
                    B-101

-------
 £fo&^
FlOl£»H
 &ot*-j
          Date
       TRACER GAS BAG SAMPLING FIELD DATA

              RUN NO.


              Plant
          Sampling location
          Barometric pressure
                                                         in.Hg
          Ambient temperature, °F

          Operator
                            Stack temperature,  °F
          Sample bag leak checked
                            Sample train leak checked
            Time
           (24-h)
           (3-Z3
 Traverse
  point
- C(-V
                         - C6-V
     AP
                                       3o/
/.£/
                                       /./ /
Rate  meter
flow  rate,
 cm3/min
                             7
                     Q - Q
                                                            Average
                                         Dev.
                            -)  100
                       avg.
                                         B-102

-------
                    SFg TRACER GAS BAG SAMPLING FIELD DATA
                                                     *
                               RUN NO.
Date
                     Plant
Sampling location
Barometric pressure
Ambient temperature, °F
Operator _
                                    Stack temperature, °F
                      ?
Sample bag leak checked
                                    Sample train leak checked
*X
( Q"Qav9')  100
Average
(Must be
                                                                   in.Hg
                                  B-103

-------
                   SF6 TRACER GAS BAG SAMPLING FIELD DATA
Date
•T.>/S?V>
c Ol f .•>
                              RUN NO.
                              Plant
Sampling  location
Barometric pressure
Ambient  temperature, °F

Operator
                  -C
                                             Stack  temperature, °F
                              A-J"\
Sample  bag leak checked
                                  Sample train leak checked
                                                                in.Hg
  Time
 (24-h)
     Traverse
      point
                                    AP
                                  in.H.O/
Rate meter
flow rate,
 cm3/min
Dev.
 fc  '
                          , -73"
 /c -.
 // :
                                       7
ft  cV
                                .
JLJL
 u In
*« Dev.
           Q - Q
           100
                                                     Average

                                                     (Must be <10%)
                                B-104

-------
                   SF, TRACER GAS BAG SAMPLING FIELD DATA
                                      _~   -    ^   •
                              RUN NO.
Date
                              Plant
Sampling  location
Barometric  pressure
                                                                           in.Hg
Ambient temperature, °F

Operator 	
                                             Stack temperature, °F    6
Sample bag  leak checked
                                             Sample train leak checked
:7
                               B-105

-------
                  SFg TRACER GAS BAG SAMPLING FIELD DATA

                            RUN NO.
Date
             Plant
         /
Sampling location	

Barometric pressure 	

Ambient temperature, °F

Operator

Sample bag leak checked
                                          Stack temperature, °F
                                          Sample train leak checked
  Time
 (24-h)
Traverse
 point
                              ,6 / 69
               3?
                            •7.776-7
                                               Rate meter
                                               flow rate,
                                                cm3/min
                                                                      in.Hg
                                                    :z
Dev.
                            3.37
                                    -Si
           Q - Q
                  -)  100
                                                 Average
                               B-106

-------
TRACER ANALYTICAL DATA SUMMARY
         B-107

-------
mpnt  U^l^Of)

PN  3 Wo-7

'Analyst _
                               LABORATORY DATA

                                           Analysis
                                           Calibration  Number
                           AIR  SAMPLE ANALYSES
                                SF6  TRACER
   Sample  I.D.
                     Atten.
                                        Peak
                                       Height
Response
Concen-
tration
  v/v
                                           30/Y.Y
                                                   1.11*10*
                                 Wat-Yes
                                        2992.
              /O
                       (,¥
'/A
             (, CM S/7t
                                 r
                                           /o
hi*
         rik(?.  bf ^
                                        SO
                                  B-108

-------
Cl lent  //«
PN
              f A
LABORATORY DATA

            Analysis
             Date
Analyst
            Calibration Number
                       AIR  SAMPLE ANALYSES
                            SF6  TRACER
Sample I.D.
                    Atten.
    Peak
   Height
Response
Concen-
tration
  v/v
     r
                                                20X10
                                                    '%
   c • £•
                                               0. M. A
                              ~+ M» ••.*.
           3
                                       $320
                     ff.w.fi.
           3
                             A// 7
                                       UK
    c-/
           v
    />/
                      3?
   C-
           3
  11-7/K7
           H
                                           /
                                               i.Uxic
                                                     '%
                                               /. 27*10
                                                     '*
   r -
                                               330*10'%
   C-t
                      331
   c-/
            v
            V
                                               2. /g'X /<)"*
                                               2.01 VO~
   C-f
                      3X
                             B-109

-------
      Client   Ks UFA/ /
      PN  3?fg •?  Date
                                 LABORATORY DATA
                                             Analysis
      Analyst
                                             Calibration  Number
                              AIR SAMPLE ANALYSES
                                  SF6 TRACER
      Sample I.D.
                           Atten.
                                     Peak
                                    Height
Response
:oncen-
tration
  v/v
31

E

3s-
          C -G
                            3P
                   a
          /)-/
          C-A
                                            27U4
          r.-/
                                              s-/rr-
                                    71)" 7/7 s. 7
V/
                                   ?;.&/;/- r
Y?_

y*"
          C-/
                                        i 3
                                         . 0
                                   79-^777.
il
                                    77.1/77-0
                                             35
                                     B-110

-------
Client   ft
PN 1110-1    Date  H7-13
                               LABORATORY DATA

                                           Analysis
Analyst
                                           Calibration Number
                       AIR SAMPLE ANALYSES
                           SFg TRACER
Sample I.D
                         Atten
  Peak
 Height
Response
Concen-
tration
  v/v
'fc^/tf
                 - 1
                              n
 ,RL\_.
                  rt: PR-1
frQ.a/9/.i
                                      2s- 7J. a:
    c/ -
                      3?
                     33
                            71
                            7 OS/ 76$
     C/-3
     a-3
                      32
                                           131
     D/-3
    D/-¥
          PR - c
                               B-lll

-------
      Client  USfc'^ /

      PN
                                 LABORATORY DATA

                                             Analysis
                   Date
      Analyst
                           Calibration Number  t-IT-?3
                             AIR  SAMPLE ANALYSES
                                  SF6 TRACER
      Sample I.D
                          Atten.
                   Peak
                  Height
Response
Concen-
tration
  v/v
             --3
                           33-
           / - y
                                                    1-ITxiO^
          S/3- V
                                            !(.(.**
                                    //r
                           32.
                                   57
/y
          Cl • 1
                           / 5-63-2
         1.
                                   734/710
                                                    2.
                                  SS
                                                    /.Yfif/0*
17
                                            / 630.1
           Ci-i
           C/-3L
J2/
                                                    /.jox/o
                                         '%
              iK
4rL
t
           S/3-7
                                     ry
                                   B-112

-------
Client _£/!_£
PN 1V70 '7    Date
Analyst 	
                               LABORATORY DATA

                                            Analysis
                                            Calibration  Number
                            AIR SAMPLE  ANALYSES
                                SFg TRACER
   Sample I.D
                     Atten.
         Peak
        Height
Response
Concen-
tration
  v/v
                                           /on.*
        S/'vo
                                 70 Cj 70.1
                          /6
                                         13
                           if,
                              (,0 7
                          /(*
        S/8-/?
                                                    1.10*10'*
                          3?-
                                                    Si. 17* to"*
3 IT
                              £/•
-------
Client  Us L.P/9 I
PN  IWo-t   Date  7-a.*-a
                           LABORATORY DATA

                                       Analysis
Analyst
                      <>
                                       Calibration Number
                       AIR  SAMPLE ANALYSES
                            SFg  TRACER
                                               CUT  Oft   I'? &C'
                    Atten.
                               Peak
                              Height
        Response
Concen-
tration
  v/v
f     '
7 h  -
  r  '
                                                              1.
(.(9*6*7
                                                                 .
                                                93* '0*1
                                       I27Z
                      /6
                             s Y.I
                      1C
                                       Mil-la
        -
                      /(*
                                               +Kn*
                                                     '
                      lio
                                      IISS.JL
      5^- W
                      Ik
7/0
                      H,
                      fb
                                       777-4
                               7/.J
                               70
                      /(*
                                       7/fc.fr
                      /(a
                                               1.I7XIQ'*
                               i* ^
                                       Jtft.H
                               y/v
                                B-114

-------
rn»nt  UlL'P/]  //?

PN  3V7*-?  Date   1-9'-*}
Analyst   G^t'G ML' /*/;-:*. 5
                          LABORATORY DATA
                                      Analysis.
                                      Calibration Number
                       AIR SAMPLE ANALYSES
                               TRACER
Sample I.D.
                    Atten .
 Peak
Height
Response
 oncen-
tration
  v/v
                                      /*/£
        y?
        n
                                              f,
                                              7.
                              37
         5-3
                      35
                                      /zoo
        5-7
                                       1/6*1
                                      /*/£>
                                       /J/0,1
                              31*
                                      /273-t,
        6?
                      331
        (,7
                                      x-2 r/-
                                          . (,
                                              /. 61* l
        71
                             X7//7
                               B-115

-------
EXAMPLE SFg STRIP CHART PRINTOUTS  - JANUARY  1983
                 CALIBRATION
                 BACKGROUND
                 INJECTION SAMPLES
                     B-116

-------


                                                     _!_i  . •  : | : ;  . i  :    j_l	L	I
 j     i'~~" ".r~~ ~±r:~."±~ rrr-iT ziij±r!i;Ttjr!ii~it.^ii~:'riri"'il"l nJ-L'..!

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-------
100
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                              B-118

-------

B-119

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B-120

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                            B-121

-------
B-122

-------
B-123

-------


B-124

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B-125

-------
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      B-126

-------

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B-128

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B-129

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B-130

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100-t-r
                         B-131

-------
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-------
B-133

-------
                            LABORATORY DATA
rn»nt  US tPfi/A
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                                       I


                       SF6 CALIBRATION JANUARY 19, 1983
                            m =  .86787899
                            b =  10.054926
                            r =  .99996
                  1000
                   100
                   10

                    10
                                                                                    TYPICAL WORKING RANGE
-12
                10
,-H
                10
-10
,-9
                  10

         SF6 CONCENTRATION, v/v
                                                                      10
                                                                        -8
                                  10
                                                       -7
                                                                                        10
                                                     -6
                                            Example SFg  calibration  curve - working range

-------
DECEMBER 1982 PRELIMINARY TEST DATA
          SF6 INJECTION
              SAMPLE COLLECTION
          SFg ANALYTICAL SUMMARY
             B-136

-------
                                       GAS VELOCITY AND VOLUME DATA
1.
               PLANT AND CITY
                                                      RUN DATE
                                                 14     17
      SAMPLING LOCATION
CLOCK
TIME
                                  •6
2.
RUN
NUMBER
ww
OPERATOR
td-VF
AMB. TEMP.
CF)
Jf .
BAR. PRESS
(in. Hg)
SPmf-ff
STATIC PRESS
(in. H20)
•
                                21
                                          Jl
                                                     JJ
MOLECULAR
WT.
.<*?.">*
STACK INSIDE DIMENSION (in.)
)IAM OH SIDE 1
. **. . .
SIDE 2
i A • . .
PI TOT
TUBE Cp
,jr
MOISTURE
%
*f.°.
   40
                      • I
                   FIELD DATA
TRAVERSE
POINT
NUMBER
7.8 .9 .10
A-/
A
3
f
*r
6
TM^n^
A "
f
 = ^^ c.  ?iS-^y/T,

-------
                                           CAS VELOCITY AND VOLUME DATA
1.
                PLANT AND CITY
                                                     RUN DATE
                                                               fi
                                                       J4     t't
SAMPLING LOCATION
                                        CLOCK
                                        TIME
   47
                                      *6
     RUN
    NUMBER
     OPERATOR
AMB. TEMP.
  CF)
                                    y.v  .
                      BAR. PRESS
                        (in. Hg)
                   STATIC
                    (in. H20)
                                    21
                                               31
                                                           33
                                                                   16
MOLECULAR
WT.
.2.9.
STACK INSIDE DIMENSION (in.)
3IAM OH SIDE 1
fojfi • , _.
SIDE 2
• . • , i
PITOT
TUBE Cp
_.?^
MOISTURE
t
£*.«>
   40
             «< it
                         * '
                      FIELD  DATA
                                              70
                                                      73
                                                             76 .
     TRAVERSE
      POINT
      NUMBER
     7 . B . 9 .10
      -/
       POSITION
          (in.)
              11 .1 7 ,13«U
  VELOCITY
    HEAD
(ip  ) ,  in.HjO
                         7 J.J6 «57 , J8 ,79

                            .ft,
  STACK
TEMP, "F
                                       36,39 ,40 ,41
                                  3-138

-------
                         SF6 TRACER GAS INJECTION DATA
                               RUN NO.
Date

Injection location

Ba rome t r ic--tfre s s u re
                                      in.Hg     Ambient temperature,  °F
Regulator pressure
           ress
psi
Time
(24-h)



/Z12-
















Calibration data
Bubble meter rate, cc/min
Time
Z//.S3
?W 'O.Ik

2l\,v
















Initial
^"
^^

ZX4
















Time
Z£>?./^
?^?^

2<&M
















Final
/
/

Z,
-------
                         SF6 TRACER GAS INJECTION DATA

                               RUN NO.
Date   /I

Injection location  L2>o<.-c,
                                Plant
                                        J/T^/^^€> -
Barometrip^pressure

Opera to r
                                      in.Hg     Ambient temperature, °F
        r  res
Regulator pressure
                                                                               psi
Time
(24-h)



tfi/
















Calibration data
Bubble meter rate, cc/min
Time
/W&
/?&* ,

/&Z3
















Initial
^
^

3 30
















Time
/34.&0
/?z,3o

/?3£*
















Final
/
/

2.4
-------
Date
                         SFg TRACER GAS  INJECTION DATA
                               RUN  NO.
                                Plant
Injection location
                                                   OF
Barometric^pfessure

Operator
                                      in.Hg     Ambient temperature, °F
        r pres
Regulator pressure
psi
Time
(24-h)




A33















Calibration data
Bubble meter rate, cc/min
Time
^£5
5^'.VS
^3^

^5^.















Initial
y
/
/

#>.n















Time
W.rf
•59. f?
^?.^v-

607-0















Final
/
X
/

^^7















Average




/0-of-















Injection
rate,
cc/min




/&.&?-















Injection
time, min




J2.C? O















Note:  The tracer gas injection rate  is  set  immediately before the actual source
       injection and checked at the end  of the  source  injection.  The source
       injection rate is the average  of  initial and final.
                                   B-141

-------
                         SF6 TRACER GAS  INJECTION DATA
                               RUN NO.
Date
Injection location
Barometric pressure
Operator
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                               PSi
Time
(24-h)




/tf*















Calibration data
Bubble meter rate, oc/min
Time
59,2£-
^.^
i5£ f S.

^32-















Initial
/
^
/

/£>,//















Time
'^S.e«
5f.o5"
5
-------
Date
                         SF6 TRACER GAS  INJECTION DATA
                               RUN NO.
                                Plant
Injection location,
Barometric yr€$3ure
Operator
                                               of
                       3c>.
                                      in.Hg     Ambient temperature, °F
                                                                  '
Regulator pressure
            ess
                                                                               psi
Time
(24-h)




^V/















Calibration data
Bubble meter rate, cc/min
Time
ll
-------
Date
           ' /C -
                         SF6 TRACER GAS  INJECTION DATA

                               RUN  NO.


                                Plant
Injection
location L^bocM<,T^i
Barometric^pfessure ;3°>/O
Operator
^/
?fr*^ tt>£7 <=* £
	 f* 	
in.Hg Ambient temperature, °F ^O


Regulator pressure
                                                                               psi
Time
(24-h)




/?tt















Calibration data
Bubble meter rate, cc/min
Time
M
/M
rtn-

/1,1e















Initial
^
/
/

3c«b















Time
^ /#/?
/^3^
/^^

/^f3















Final
/
/
/

^C^Z















Average




*>& ^















Injection
rate,
cc/mi n




2*f> 
-------
Date
 -/O -
                         SFg  TRACER GAS INJECTION DATA
                               RUN NO.
                                Plant
Injection location

Barometric

Operator
                            rt?
                                          £T
pr
Regulator pressure
                 / O
                                      in.Hg     Ambient temperature, °F
                                                                    psi

Time
(24-h)




/3W-















Calibration data
Bubble meter rate, cc/min
Time
tfrft]
fi,2>&
/4,rft>

$4-3















Initial y
/
/
y

JfS'S















Time
/#£#
/tf 4/
ftfi2>l-

/3,33















Final
x
/
/

3o,^4-















Average
^



SC1.^? I















Injection
rate,
cc/min




2>£>.^f|















Injection
time, min




/£$>.O















Note:  The tracer gas  injection  rate  is set immediately before the actual source
       injection and checked  at  the end of the source injection.  The source
       injection rate  is  the  average  of initial and final.
                                   B-145

-------
                         SFg TRACER  GAS  INJECTION DATA
                               RUN NO.
Date
-//'
    Plant
Injection location j
 /J'
Ba romet r i c^re s s u re

rt    *  i
Operator
- Z&
in.Hg     Ambient  temperature,  °F
Regulator pressure
                                         _psi
Time
(24-h)




rtcq-















Calibration data
Bubble meter rate, cc/min
Time
rt/z
/3,c$
/4, ft

/f; //















Initial
^
/
/

3l«c->















Time
^.^f
?£,tf
10,(,T^

Z^frt















Final
/
/
/

2
-------
Date
                         SFg TRACER GAS INJECTION DATA

                               RUN NO.
                                Plant
A
Injection location

Barometric pjseflure

Operate
                   \
                                      in.Hg     Ambient  temperature,  °f
Regulator p/essure
                                                                               _psi
Time
(24-h)




/C'W-















Calibration data
Bubble meter rate, cc/min
Time
2P.{rf
?Mf
2c>,bi

W-k-l'















Initial
/
/
/

.3tfo*















vTime
?o. %
7V. tf
ZO.^^T

?.t?*e>c















Final
X
X
/

?^,<8S















Average




^^.^^















Injection
rate,
cc/min




/. "o <74















Injection
time, min




W,o















Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The source
       injection rate is the average of initial and final.
                                    B-147

-------
                         SFg  TRACER GAS  INJECTION DATA

                               RUN N
Date
                               Plant
                                                   ///fr3D"v4,
Injection  location
                                   32-/A; &T
Barometric Dfessure

Operator
Regulator prssure
                                     in.Hg     Ambient temperature, °F
Time
(24-h)




/^3
(














Calibration data
Bubble meter rate, cc/min
Time
•10^.
tc.tf
10 bo

?OY\















Initial
/
X
/

^.T?















Time
A^?'
/^?^
/f3*

/^,^>















Final
/
/
/

3v.?t















Average




3^. fe















Injection
rate,
cc/min




W*















Injection
time, min




£6.0















Note:   The tracer gas  injection  rate  is  set  immediately before the actual source
       injection and checked  at  the end  of the source injection.  The source
       injection rate  is  the  average  of  initial and final.
                                   B-148

-------
Date
                         SFg TRACER GAS  INJECTION DATA

                               RUN NO.
                       Plant
Injection location
Barometric pressure

Operator 	
                             in.Hg      Ambient temperature, °F
Regulator pressure
 Time
(24-h)
                         Calibration  data
Time
           Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
time, min
                                                                      300
       233-21
                                 n
                                         ' 1
Note:  The tracer gas injection rate is  set  immediately  before the actual source
       Injection and checked at the end  of the  source  injection.  The source
       injection rate is the average of  initial  and  final.
                                   B-149

-------
Date
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO.
                                Plant
Injection location /•/£
Barometric pressure

Operator
                                      in.Hg     Ambient temperature, °F
              I1
Regulator pressure
                                                                               psi
Time
(24-h)




'r - *
* w


&t
i V- ?
.'/- ?
, v • f









Calibration data
Bubble meter rate, cc/min
Time
'<#> ^
.'-,- ">j.
<: • i
/r vS

?C.7*'-.


*tl
4/1
M
ty
t








Initial
X
/
/

2<;*$

(^)
6-r
sJ
&l
&t-









Time
/6.? XV
/5,5r
/
-------
                         SF6 TRACER GAS  INJECTION DATA

                               RUN  NO.
Date
/J  /-.I-   '$£-
Plant
                                          4e 
^z-^










Calibration data
Bubble meter rate, cc/min
Time
/C. 7^-
l^.^l
/ -; 3V-

/1. ^^~

/.-'
*T'
y •* '„« .
u- "> .'
-4 ^
r»"
/









Initial
x
/
/

u.^
(•^
61
6:1
11
/of










Time
A 3>z
/5.>-(
,/l^-

A//-^















Final
/
/
/

$2 .^ I















Average




32,^1















Injection
rate,
cc/min




3>?.*n















Injection
time, min




ZCr.C















Note:  The tracer gas injection rate is  set  immediately before the actual source
       Injection and checked at the end  of the  source  injection.  The source
       injection rate is the average of  initial  and  final.
                                   B-151

-------
Date
                   V
                         SF6 TRACER GAS INJECTION DATA

                               RUN NO
Plant
Injection location  ,<'.
Barometric^pressure
Ope r a to r
      in.Hg     Ambient temperature,  °F   -^
Regulator pressure
                                               psi
Time
(24-h)




//:^5

d3 • /
Cl 2
13 5
& -4










Calibration data
Bubble meter rate, cc/min
Time
ft 32-
frM
ri-*

/1.'lf-

•~9 J *f~
'T'
4#-
/ j+
-7^-
/









Initial
/
/
/

3* -(r\
i-r^
^
/'<*>
'/?>
/K










Time
}gT^
nrt
ft r+

nii-















Final
/
/
/

32 ,c5















Average




57 3>















Injection
rate,
cc/min




-3^-35















Injection
time, min




74 'G















Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The source
       injection rate is the average of initial  and final.
                                    B-152

-------
Date
        /z-/z-
SF6 TRACER GAS  INJECTION DATA



      RUN NO.





       Plant
Injection location ,
                             Y/.///U
Barometric/pressure



Operator
                                     in.Hg     Ambient temperature, °F
           7
Regulator pressure
Time
(24-h)




/tr^

bi-i
b/-^-
f->|-3
Di-^










Calibration data
Bubble meter rate, cc/min
Time
/f;.Y^
!\>.('i
K.Vs

A-?z

^H
^
*-/•/-
V/f
6









Initial
//
/
/

32 .05
^)
£-£-
/S-&*
/7*
1'6-










Time
/y^i
A/^
/^?^

A'?>>















Final




3/.f5















Average




32 tc-















Injection
rate,
cc/min




3>7:C-G















Injection
time, min




















Note:   The tracer  gas  injection rate is set immediately  before the actual source

       injection and checked at the end of the source injection.  The source

       injection rate  is the average of initial  and final.
                                   B-153

-------
                         SF6 TRACER GAS INJECTION  DATA
                               RUN
Date
Injection location
Barometric,pfessure

Operate
in.Hg     Ambient temperature,  °F
Regulator pressure
                                          psi
Time
(24-h)




/2U-

)>l '
te-z
b? 3
^'/ • ^










Calibration data
Bubble meter rate, cc/min
Time
/f."/r
/&^~
/5"«,

An

?//
^//'
4'7
f//
I









Initial
/
/
/

3/, f 5
^0
^-c
?r
/^
/£Z-










Time
/l?f
/j?.^^
/f (t:^

/^/^















Final
/
/
/

5/,'S















Average




5/.fy










t




Injection
rate,
cc/min




3/.f/















Injection
time, min




/*r, ^















Note:  The tracer gas injection rate is set immediately before  the  actual  source
       injection and checked at the end of the source injection.  The  source
       injection rate is the average of initial  and final.
                                  B-154

-------
Date  /> ~ /?
                         SF6 TRACER GAS  INJECTION DATA



                               RUN NO
                                Plant
Injection location



Barometric aressure
         /      /

Operator  "Z^C
                            ?-?.i-z
£/-3
#/• V










Calibration data
Bubble meter rate, cc/min
Time
/£?*,
/1,K
K&t

/z.li

v/
///
^/r
V
/









Initial
/S
/
/

3V. v'^
^J
i'-a
&••
-s?
^f










Time
/f./S
/•J ^^f-
/^^5

/-b'^-/















Final
/
/
X

3^'//















/Average




$j,m















Injection
rate,
cc/min




3-Z-/?















Injection
time, min




5f,e?















Note:  The tracer gas injection  rate  is  set  immediately before the actual source

       injection and checked  at  the end  of the source injection.  The source

       injection rate is  the  average  of  initial and final.
                                  B-155

-------
Date
                         SF6 TRACER GAS  INJECTION DATA
                               RUN  N0
                               Plant
Injection  location
                                'fil <5&rlu.<>-r -
BarometriCxpfissure
Operator   ' ^
                                     in.Hg     Ambient temperature, °F
Regulator pressure
                                                                              _psi
Time
(24-h)




/32I:Z>-I















Average




5/,f6















Injection
rate,
cc/mi n




31.^(0















Injection
time, min




/3,P















Note:  The tracer gas injection  rate  is  set  immediately  before  the actual  source
       injection and checked at  the end  of the  source  injection.  The  source
       injection rate is the average  of  initial  and  final.
                                B-156

-------
Date
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO.
                                Plant
Injection location
                                            T - P i
£>* ^
83 4'










Calibration data
Bubble meter rate, cc/min
Time
A 7f
/£y>Y
/S?.7?

/tf,e^/

-2-ft
tfy
wi
1st
L









Initial
x
/
/

3l.z*i
fr>N)
M"^
/•$%
//J
/3k










Time
'£ ^
/ ' /
/^ O ^
/^*/5-

/^ /^















Final
/
/
/

31.3^















^Average




2?//l^















Injection
rate,
cc/min




3MJ£















Injection
time, min




/J>O















Note:  The tracer gas injection rate is set immediately before  the  actual  source
       injection and checked at the end of the source injection.  The  source
       injection rate is the average of initial  and final.
                                 B-157

-------
Date  A3 -
                         SFg TRACER GAS  INJECTION DATA

                               RUN  NO.
                                Plant
Injection location

Barometric^pressure

Operate
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                               psi
 Time
(24-h)
                         Calibration  data
         Time
                    Bubble  meter  rate, cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                 3 /. •
 SA-i
Note:  The tracer gas injection  rate  is  set  immediately before the actual source
       injection and checked at  the end  of the  source  injection.  The source
       injection rate is  the average  of  initial and final.
                                   B-15B

-------
                         SFg TRACER GAS  INJECTION DATA

                               RUN  NO.
Date /y£ -/«X -fr> Z- Plant ffZrt&O- l/te£M4;fa/Jfe#/tJ6TeA'
Injection location /^^^//^7/f/A' d^X/fc>7 1 <-ST - reV~3
Barometri cpressure
Operator^ -j^7
£
in.Hg Ambient temperature, °F
^ o

/' ,
Regulator pressure £-? psi

Time
(24-h)




J6:j

bv (
K2) z
b^-3
m ^











Calibration data
Bubble meter rate, cc/min
Time
//* j/.-/
/#£!
ftfa,

tfffa

•2-H
4>fr
tit
qf-jff
I









Initial
/
/
/

3& %r
ffc)
//j,
tfz.
'-tt
'12-










Jime
' ft,?!
/f,$f
H^

/$ & 1'















Final
/
/
\/

32.14-















Average




^i^'-H















Injection
rate,
cc/min




J5A V?-















Injection
time, min




/^/ ^















Note:  The tracer gas injection rate  is  set  immediately before the actual source
       injection and checked at the end  of the  source  injection.  The source
       injection rate is the average  of  initial  and  final.
                                  B-159

-------
Date
                         SFg TRACER GAS INJECTION DATA

                              RUN N
                               Plant
Injection location
                   //e 'tftf-TSt
Barometric j>pessure
              / /
                                     in.Hg     Ambient temperature,  °F
Regulator pressure
                                                                              psi

Time
(24-h)




/6^.

M •!
^ z
c«~5
c*t- 1










Calibration data
Bubble meter rate, cc/min
Time
/Sfr7
tf.tfi
/?& '•

rf.tf

^//-
^.v
£jf-
rV/'
I









Initial
/
/
X

,U-/4-
fy^}
w '
c)'i
tfs-
/#Z-










Time
/ti^c
/fJ-7-
/tfjt-/
-/^ 	
/^3^















Final




2>r$£















Average




^/^















Injection
rate,
cc/min




2,A^£















Injection
time, min




/£


-------
Date
- /^ - s ?-
                         SFg TRACER GAS  INJECTION DATA

                               RUN NO.
Plant
Injection location /W/l//r,///t/
Barometric gpes'sure

Operator
                           in.Hg     Ambient temperature, °F
Regulator pressure
                                                                    J>si
Time
(24-h)




/^'|

^-/
fr ?
Ct>-*>
te-q-










Calibration data
Bubble meter rate, cc/min
Time
*?.*,'•
W<
/M*

M>$

///
&
t/r
•i/f
i









Initial
/X
/
X

3i'.VY
/^;
X/3
/5^ i.
VST*
I4c










Time
/«v&
/€^
/^^

/^^















Final
/
/
/

3". 4 /















Average




3A 6^















Injection
rate,
cc/min




3c.6tf















Injection
time, min




M^















Note:  The tracer gas injection rate is  set  immediately  before the actual  source
       injection and checked at the end  of the  source  injection.  The  source
       injection rate is the average of  initial  and  final.



                                   9-161

-------
Date
                        SF6 TRACER GAS INJECTION DATA

                              RUN NC
                               Plant
Injection  location

Barometric pressure

Operator

                                     in.Hg     Ambient temperature, °F
Regulator pressure
                                                                           ^  psi
 Time
(24-h)
                        Calibration data
         Time
                   Bubble meter rate, cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
        ff.fr
                  3"
                                    3/-OZ-
                   ft
   -**
Note:   The  tracer gas injection rate is set immediately  before the actual source
       injection and checked at the end of the source injection.  The source
       injection rate is the average of initial  and final.
                                 B-162

-------
Date
                         SFg TRACER GAS  INJECTION DATA

                               RUN NO
                                Plant
Injection location
                                       7
Barometric presure
                                      in.Hg      Ambient temperature, °F
Regulator prssure
           ress
psi
Time
(24-h)


t

,H2

(.1-$
A" (r












Calibration data
Bubble meter rate, cc/min
Time
11.2*1
rv.s-f
tfto-

?i l\

L'ti
?f!
i











Initial
/
/
X

f^.fec
f7J
174
/?/












Time
/?^2-
•^.t"f
-/^'. >>

/?A4















Final
/
/
/

w-\i















Average




MM















Injection
rate,
cc/min




•2431















Injection
time, min




/SO















Note:  The tracer gas injection rate is set immediately  before  the  actual  source
       injection and checked at the end of the source  injection.  The  source
       injection rate is the average of initial  and final.
                                  B-163

-------
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO.
Date    /?.-•"' 3~ % /-        Plant ;
                      A    i]         ,
Injection location  /£{.(£ rn/ETA) *J
Barometric pfe

Operator
in.Hg     Ambient  temperature,  °F
Regulator pressure
Time
(24-h)




/ff^

^-6
C ^t












Calibration data
Bubble meter rate, cc/min
Time
ti^
2^-d'
1C >2>

/^;^"

6"/^
*ff
I











Initial
/
/
/
/

3c,/«
/-f^
•?3
^












Time
/^-^/
/^/^
A'.^^

tf.kz-















Final
X
/
/

2*",^















^ Average




V1-^















Injection
rate,
cc/min




— — .^ ,^?
3i>















Injection
time, min




f^. &















Note:  The tracer gas injection rate  is  set  immediately  before the actual source
       injection and checked at the end  of the  source  injection.  The  source
       injection rate is  the average  of  initial  and  final.
                                  B-164

-------
Date
/7 ' IV
                         SFg TRACER GAS INJECTION DATA

                              RUN NO.
                               Plant
                                      n5A££&-
Injection location

Barometric

Operator

                                     in.Hg     Ambient temperature,  °F
Regulator pressure
              L,
                                                                       psi
Time
(Z4-h)




//C X

^-'y
^>^-












Calibration data
Bubble meter rate, cc/min
Time
#&l
/f, &
V.&-.

frfr

faft
m
i











Initial
/^
/
/

?t>.&i>
/'.,)
fe
/v.












Time
/^^
MM
/?.&

tf.M















Final
/
/
/

Zr,?^















Average




ST. 4- 5















Injection
rate,
cc/min




3r-<^















Injection
time, min




-rr ^
o < c. -















Note:   The tracer gas  injection  rate is set immediately before the actual  source
       injection and checked at  the end of the source injection.  The source
       injection rate  is  the average of initial and final.
                                  B-165

-------
                         SF6 TRACER GAS INJECTION  DATA

                               RUN N
Date
Injection location
            x^
Ba romet ri c/pre ^ s u re

OperatorL ^
                                      in.Hg     Ambient  temperature,  °F
Regulator pressure
                                                                               _psi
 Time
(24-h)
                         Calibration data
         Time
                    Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The source
       injection rate is the average of initial  and final.
                                  B-156

-------
Date   /P--/3"  #'.*>
fa t~












Calibration data
Bubble meter rate, cc/min
Time
ff,fg
tf,£?
/rfSjj^

/tf>4&'

L*fl
2>/~f
t











Initial
/
/
/

2S-6- ?
fo)
&Z
x^-












Time
/*/ tW~
2^,1*
/tit-4

/%!?>















Final
/
/
/

3C-*H















Average




*£'•&{-















Injection
rate,
cc/min




^e'-S4-















Injection
time, min




^t C>















Note:  The tracer gas  injection  rate  is  set  immediately before the actual source
       injection and checked  at  the end  of the source injection.  The source
       injection rate  is  the  average  of  initial and final.
                                  B-167

-------
Date
                         SFg TRACER GAS INJECTION  DATA

                               RUN NO
                                Plant
Injection location   /y?/ L-*i/er,
                                           T ~ Tc
Barometric QpeTs)u re
                                      in.Hg     Ambient temperature, °F
                                                                         T°
Regulator pressure
                                                                               psi

Time
(24-h)




:'I3'&

£i- 5
fo- £,












Calibration data
Bubble meter rate, cc/min
Time
tf,^
?<-',/'
/$,{•¥-

ft, ? J>

Ui
-j&r
u











Initial
/
/
/

3*. '^hl
ft*)
£,'j
/.*£












Time
Ififi ^
/<^^^
/£^3

/^/fe»















Final
/
X
/

3r /H















^.Average




3^41















Injection
rate,
cc/min




-3)T> 2J-/















Injection
time, min




<$,c?















Note:  The tracer gas injection rate is set immediately before the actual  source
       injection and checked at the end of the source injection.   The  source
       injection rate is the average of initial  and final.
                                  3-168

-------
                         SFg TRACER GAS  INJECTION DATA

                               RUN N
Date /^ ' /c>" 0 £- Plant rfe4?f d-oXT/i//.' Oc'-T~ r&f'1 *-* ' '
BarometrtjE^ffessure
Operator— t^^-

in.Hg Ambient temperature, °F
?«>

Regulator pressure ^psi

Time
(24-h)




/ i^j/^.

bl -^
b/-<2?













Calibration data
Bubble meter rate, cc/min
Time
/^
//?f?-
1^3

//W3

^/•/
3^V'
L











Initial
/
/
/

Zr-fJi
(-T^)
<*ft
?/












Time
/4' ^^~
//?£r
££**+-

}£*&<3















Final
/
/
/

3r, /^















Average




.3r,-3n















Injection
rate,
cc/mi n




^,^.33^















Injection
time, min




-6 i^7















Note:  The tracer gas injection rate  is  set  immediately before the actual source
       injection and checked at the end  of the  source  injection.  The source
       injection rate is the average  of  initial  and final.
                                    B-169

-------
                         SF6 TRACER GAS  INJECTION DATA

                               RUN N
Date
Injection location
Barometric opesSure

Operator
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                              _psi
 Time
(24-h)
                         Calibration  data
         Time
                    Bubble  meter  rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                   V/
Note:  The tracer gas injection  rate  is  set  immediately before the actual source
       injection and checked at  the end  of the  source  injection.  The source
       injection rate is the average  of  initial  and  final.
                                  B-170

-------
                         SF6 TRACER GAS INJECTION  DATA

                               RUN NO
Date
                       Plant
Injection location
                                      in.Hg      Ambient temperature, °F   "(
Regulator pressure
 Time
(24-h)
                         Calibration data
Time
           Bubble meter rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
Note:  The tracer gas injection rate is set immediately before  the  actual  source
       injection and checked at the end of the source injection.  The  source
       injection rate is the average of initial  and final.
                                  B-171

-------
                         SF6 TRACER GAS  INJECTION DATA
                               RUN
Date
Injection location

Barometric pjsessure

Operate
                                  S=TY -
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                           ~  PSI
 Time
(24-h)
                         Calibration  data
         Time
                    Bubble  meter  rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/mi n
Injection
time, min
                             A//3?-
Note:   The tracer gas  injection  rate  is  set  immediately  before the actual source
       injection and checked at  the end  of the  source  injection.  The  source
       injection rate  is the average  of  initial  and  final.
                                 B-172

-------
                         SF6 TRACER GAS  INJECTION DATA

                               RUN NO .
Date
Injection location

Barometric
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                               psi
 Time
(24-h)
                         Calibration  data
         Time
                    Bubble  meter  rate,  cc/min
Initial
Time
Final
Average
Injection
  rate,
 cc/min
Injection
time, min
                                        X
                                'f
Note:  The tracer gas injection rate is  set  immediately  before the actual source
       injection and checked at the end  of the  source  injection.  The  source
       injection rate is the average of  initial  and  final.
                                B-173

-------
                         SFg  TRACER  GAS  INJECTION DATA

                               RUN NO
/
Date /V- ~/v:> '*£"*- Plant fT3^^^°w \^£*>"* k 1 Jt)for->t\ tn^t"
A /I ~r- K K i§
Injection location /"?/* Cxt^T.A^O —S.(r"T ~ to/^-T \^>'~'*&—
Barometric oi^sl
Operator L— -r^T*
Jure
(^
in.Hg Ambient temperature, °F
-7-0

/ '
Regulator pressure ^> psi

Time
(24-h)




//^?

h^<
^8-(.-













Calibration data
Bubble meter rate, cc/min
Time
/f,£r
/^-^
?<-.<*!

tf.'fr

i-f
'&

/'}£$















Final
X
x
X

'2>C<14-















Average




;3^-^b















Injection
rate,
cc/min




30.^4^















Injection
time, min




s^n















Note:   The tracer gas  injection  rate  is  set  immediately before the actual source
       injection and checked  at  the end  of the  source  injection.  The source
       injection rate  is  the  average  of  initial  and final.
                                  B-174

-------
                         SF6  TRACER GAS  INJECTION DATA
Date
          ?- /3-  fe.
                               RUN m.
                                Plant
Injection location
Barometric
Operator
                                      in.Hg     Ambient temperature, °F
Regulator pressure
                                                                              _psi
Time
(24-h)




/?&>
i














Calibration data
Bubble meter rate, cc/min
Time
#>'
/9>f
/1,/f-

frz/















Initial
x^
/
X

3>
-------
                   SF6 TRACER GAS BAG SAMPLING FIELD  DATA
Date
                              RUN NO.
                              Plant
   -7S
&&fr*4—
Sampling location
                         */£/*.*.«
Barometric pressure
Ambient temperature, °F
Operator
                                              Stack  temperature, °F
Sample bag  leak  checked
                             v
Sample train  leak  checked
                                                                            in.Hg
Time
(24-h)

X.2.24
/**/
/23t>
/Mt




iize.
/23I
/Z3i,
t*&37





Traverse
point

n t *~~
H
il
it





AP
in.H20 x

^,^<5 (&)
3.tt (S3)
j,tf (f?)
S'tf (ss)




*4o (si)
z.6>* (s'e)
3.<>o (S&)
340 (fg]





Rate meter
flow rate,
cm3/min

^&0
«






rip*
H
It
It





Average
Q - Qavo
a* nnw - r. »\SM mn ^Mu«:t HP 
-------
                    SFg TRACER GAS BAG SAMPLING FIELD  DATA
Date       A2 A'A
                              RUN NO.
                              Plant
-  r^,
             /  /
Sampling location
Barometric pressure
                                                                            In.Hg
Ambient temperature,  °F


Operator 	
                                              Stack  temperature, °F
Sample bag leak checked
                                              Sample  train leak checked  »"
Time
(24-h)

f4*f
/U3t>
/4*CC-









~ f~






Average
a Q - Qavo
a* nnu - I - a.v_9M inn rMur.t HP 
-------
                   SF6 TRACER GAS BAG SAMPLING  FIELD DATA
Date

ir
ie1
•n1
tc
e
RUN NO. /A- 5
/**/fc>- Pl.nt A~~- 7^~~
ig location ^«^»U^MM^. 3-t4*4H**T
ff
trie pressure 3c>-l$>
t temperature, °F •— V^ Stack temperature, Of(fru~4*
>r &L*uH+<+
VI ff
bag leak checked ^ Sample train leak checked ^


in.Hg
^H>)

X
Time
(24-h)

l&
-------
                    SFg TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
Date
Plant
Sampling location &l4+i&+*fat4
Sample bag leak checked
Sample train leak checked ^
Time
(24-h)

tiff
J(f6*>
Jt6f
/1ft







/£*/£'
I If ft
/tff
ntD


Traverse
point

7&-J- s/o.r
a
n








Trtt 4- fi/o.+
"
„



AP
in.H20

3.0 ($3)
3$ (&)
3.o to)








J.9& (*fg)
3.6 (it]
3.c ftr)



Rate meter
flow rate,
cm3/min

&t>










gffV





Average
a Q - Qava
a* now - I- aX3.:.^ inn (Mu«;t HP 
% Dev.a


















•

               avg.
                             ^
                                    B-179

-------
SFg TRACER GAS BAG SAMPLING FIELD DATA
           RUN NO.
Date ^-/fi^Z- Plant /w**l£> — /o^****^
Sampling lo
Barometric
Ambient tern
Operator
Sample bag
Time
(24-h)

4 ¥6




9ty

qgftptf




toe?




cation &<+++*»+A. >Ct-^i~«^"~
// \
pressure 3&./O (^y^&e^ "t.^ ' rf*0 } 1n.Hg
perature, °F ^ J
M**4fa~
»
>tack temperature, °F


leak checked |X Sample train leak checked */

Traverse
point

ti ~ *
2-
3
y
^
(.

& " 1
A
^
*/
f
L




in.H20 '

/,^? ^
X * V? ^^?"^ /^/? /
/,7^ ^rl
^,f^ ^^7
^^ ^V7/)

/•74^ <^V^
/.5^ ^^7)
/,;^ fy7y;
^.^ ^>7 )
/./^ f#7)
&
-------
                   SFg TRACER GAS BAG  SAMPLING FIELD DATA
                              RUN NO.
Date JA~/0- V2'~ Plant >&**<££> — i+*~*~ +-
Sampling location ±&4*~*L+»M, 4*<6*»/+J
Operator
Sample bag
Time
(24-h)
r& ( f




/$ ^. 5






//3^





C^ff^L


leak checked *"" Sample train leak checked V

Traverse
point
4- /
j.
3
V
5^
I

&- 1
1
j
//
f
{,





,„!£,„ rn)
/S5b (^fy1
X.'foW?)
At>0 (f?)
X,70 fft)
£> ?e f?&)
£.eo (#t)

/.&> (47)
Z.Zs) (#7)
2.7# (ftf
?.£0 f ft)
ff ^^~ rU&i
r\ , & y ( ^r&/

-------
                    SF,  TRACER  GAS BAG SAMPLING FIELD DATA
                      0
                               RUN NO.
                                           - r
Date
                               Plant
Sampling location
Barometric pressure
3o,/6
                                                                             in.Hg
Ambient temperature,  °F



Operator 	



Sample bag leak checked
                                              Stack temperature, °F   JU,
                                              Sample train leak checked
Time
(24-h)
/t>3$




SlM

/€*/




M02^





Traverse
point
A-/
JL
3
y
r


& - 1
i
/
v
^
^





AP
in.H20 ^rj
/ ^ ^)
#,y# (ft)
f.tb [yt)
ff.fcfyt)
3. cro (if)
$.*>£> (&)

2.*>ffe*}
f>7o fsZ)
fi.fo fcl)
t-.fo (&)
t.jo (&)
$.#) (6c)





Rate meter
flow rate,
cm3/min
^5*"

















n — . Average
Q - Q fiP tn*.- /,65V
a« n™ - (. aYSM inn .. fMuct KP ;
                                   3-102
                                                        .e>  x

                                                          J,

-------
SFg TRACER GAS BAG SAMPLING FIELD DATA
           RUN NO.
Date /2-/*-1i>- Plant fk+~to - T*******
Sampling location i fc?)
2 3 6 (&)
S.tfo £&}

/•9e (f&\
f.k^ (ft)
% 1^ (tf)
*.r* (49)
*.YO (&)
/t.4S (S9)






Rate meter
flow rate,
cm3/min
~sfirG






~*t»










	 ^ Average

% Dev.a



















-) 100

-------
Date
                   SFg TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
Plant
SFZ
                . tJA
Sampling location
Barometric pressure
Ambient temperature,  °F
Operator'
Sample bag  leak  checked
Stack temperature,  °F
Sample train  leak  checked
                              in.Hg
Time
(24-h)
/4-W-
/L/&4-
/4&<&
/4&'Z
/4<#?
/+/z-
/4/t
M/<*
rt'S
/4 zv
Mzi-
/42V
/4z+>
/VzS




Traverse
point
A-/
z
3>
Y
5'
<-
L4lA.«-^£ T&U-S*
Z- 1
z
3
4-
^
6
/d&Tez-r




AP
1"-H'}^)
Z,Z- ^ti.)
7 , 3S /^ /)
7,^0 /CJ>
3,oc^^^)
^.^^ /^O
3 ^ /L-c?)

^^o-/^?-)
P'1*(6>°\
J, ^Lt. - J.C./C,
% Dev.a



















   Dev.  =  (	) 100
        (Must be <10X)
                                   3-184

-------
     SFg TRACER GAS BAG SAMPLING FIELD DATA
                RUN NO.
Date /^"(t -<&"£- Plant r&MLdO -~ /JCxx*As L
/£/*/ Q-
/vy^7
/ys/
7^/5,3
/i/x^'^'
/^^ y
/ fj^. *7




a% Dev. = (-
p>rature, °F -^C" 5
/
~£"4j£-
>tack temperature, °F
^^o

reak checked Sample train leak checked
^Tfc-/<'^
Traverse
point
"B>- 1
li "Z-
3
4
5
6
/Vi^c- «/ y^ni
/?-?
?
J>
4
£
(&
£> j -f L^,




Q - Qavn ^
yM 100
^avg.
* /
"fyto
/ 70 /&*•)
$, ^0 ( foOy
2-(rC> (lr\\
2,^c (<* i\
7,^.5 ^j^)
3.IO /fca)

^//0 /5/)
^(6?o ((fl\

-------
Date
       TRACER GAS BAG SAMPLING FIELD DATA

              RUN NO.


              Plant
Sampling location
Barometric pressure    3£>-
                                                            in.Hg
Ambient tepperature,  °F

Operator—f?<	
Sample bag Teak checked
                             Stack temperature, °F	^
                             Sample train leak checked
  Time
 (24-h)
Traverse
 point
                                     AP
Rate meter
flow rate,
 cm3/min
                                                                            Dev.
 /600
                   5
                  3
                                 A
                                     \/
a           Q - QavQ
•- Dev.  = (	fiSfc-)
 %
                                     Average

                                     (Must be

                           9*
                                    ^/<5^
                                                           ^c
                                 B-186

-------
                 SF6  TRACER GAS BAG SAMPLING FIELD DATA
                           RUN NO.
Date /V-/0-'oZ_ Plant /TW^ " (A^^A, lA^s-fr'Aic* ;d'i&<:>'~~ ^*#4<*£T
Barometric
f
pressure 3^- / ^ 1n.Hg
Ambient temperature, °F :5c> J
Operator —
Sample bag
Time
(24-h)
/5?1
/53/
fe3±
/33f>
/^3?
7:537
/^y/
/^3
/£*&
J^M 3
/£tL>3
/£&/
/553
/5^





>tack temperature, °F
"-^

l«k checked Sample train leak checked
^ykc/i
Traverse
point
B-i
z_
3
^/~
^
6
^/W/O^A«75
^- /
z
5

^A^ST




AP
/^5^^
2*» ^c5 ( fri?)
"2 • (?>& ( t> i j
2 /^f t ^ / )
yrfc-tn}
3, /o ^^

/ f^7 62)
„?, /5 ^S^
^-50 ^o)
J .%$• ^60")
^, ^O^c)
2.^0^6»l)





i 3 j .
'<__ r/lJi'^^jS^ — — G:.^
Rate meter
flow rate,
cm3/min
^r^oo




V

^6?oO



V
V





rj Average
' "A. o
% Dev.a



















Dev. = (	iii-)  100
           ^avg.
(Must be <10%)
                              B-137

-------
                            SFg TRACER GAS BAG SAMPLING FIELD DATA
                                       RUN NO.
        Date
                              Plant
        Sampling location
        Barometric pressure
        Ambient temperature, °F

        Operator 	
        Sample bag leak checked
Cf/D-l
     ^
     3

     V
     S'
    3
    V
    r
          Time
         (24-h)
ll /t
                Traverse
                 point
               -  I
        l% Dev. = (-
                   -) 100
                       avg.
                                                                            in.Hg
                                              Stack  temperature,  °F
                                              Sample train  leak checked
AP
                                  Z.
                                  V,-,
Rate meter
flow rate,
 cm3/min
                 Average

                 (Must be <10X)
                                      Dev.
                                          B-188

-------
                    SFg TRACER  GAS  BAG SAMPLING FIELD DATA
                               RUN  NO.
Date
              Plant
Sampling location
Barometric pressure
                                                            1n.Hg
Ambient temperature,  °F
Operator 	
Sample bag leak checked
  Time
 (24-h)
Traverse
 point
            &-*
            Q   Q
                              Stack temperature, °F   x^^
                              Sample train leak checked
  AP
in.H20
Rate meter
flow rate,
                        Dev.
                                B-189

-------
     SF, TRACER GAS  BAG SAMPLING FIELD DATA
       o

                RUN  NO.
Date / *-'//"*>- Plant A>**-rC£<> — 77f^--A*Ht^'
Barometric
/
pressure 3^->-S in.Hg
Ambient temperature, °F •*- ^' Stack temperature, °F
Operator
Sample bag
Time
(24-h)

<}&











fas?-?,)

/oZl


&-•

ouc, LttbJ

leak checked *^" Sample train leak checked ^"

Traverse
point

*~/
^
5
V
j^
^,



^"/
•^
3
i
>r
&


AP
in.H20

/.y<£> ^Vj)
/7« ("^
^-.«> (^v)
?./&(&)
2^ (&)
t3o (s&)



l.fd (&)
2. /&(<&)
$.fO (&)
*-/4'C&)
Z.eo (s$)
?. *c (s$)



Rate meter
flow rate,
cm3/min

^ <>*>C
-------
                          TRACER GAS BAG SAMPLING FIELD DATA
                                 RUN NO.
10
Date |Z^-|I'£2- Plant /7-5/^ £ G -^/A<^^A> /4/fetf/At6
Sampling location ^^^^ £»A^ y CJ/H-A^ST
Barometric
f
pressure "^>^ "^ "2 in.Hg
Ambient temperature, °F >/£*^53 Stack temperature, °F ^^£
Operator *
Sample bag
Time
(24-h)













P^n
/? lt~
/-?/?


X /
-trs^
r
leaK checked !
^^V
Traverse
point
3-/
Z
^

4
5
6

3. ^
rn* _ £J_
*y - il—


AP
^.^T- ^5,^
/F<^ ^J^)
/?5? /^?)
/>2>o fe
% Dev.a



















                                                         (Must be <10%)
                                        B-191

-------
       Date
                          SF, TRACER GAS BAG SAMPLING FIELD DATA
                            0

                                     RUN NO.
                              Plant
       Sampling  location
       Barometric  pressure
Ambient temp£f*5"ture,  °F

Operator^-.- /Jvf>-	
       Sample bag  Ie6k  checked
                                                                             in.Hg
                                                     Stack temperature,  °F    =•
                                              Sample train leak checked
7*?
         Time
        (24-h)
 /ISO
                 Traverse
                  point
                     A-l
                    g-l
                      3
                     &•*/-
          Dev.  =  (	   av9')  100

         ,-i1        Qav9-
AP
                                         5"- Oo
Rate meter
flow rate,
 cm3/min
                                                             Average
                                           B-192
                                      Dev.

-------
Date
                    SFg TRACER  GAS  BAG SAMPLING FIELD DATA
              RUN NO.


              Plant
                                                  C
Sampling location
Barometric pressure
Ambient temperature,  °F

Operator
Sample bag leak checked
                             Stack temperature, °F
                             Sample train leak checked
                                                            in.Hg
  Time
 (24-h)
Traverse
 point
  AP
in.H20
Rate meter
flow rate,
 cm3/min
Dev.
            Q - Q
              VV*"-'A
                                                      Average
                                       B-193

-------
     SFg TRACER GAS  BAG SAMPLING FIELD DATA
                RUN NO.
Date />£-/J?-F3- Plant #4++>u> ~i*6f-~*L.
Sampling lo
Barometric
Ambient tern
Operator
Sample bag
Time
(24-h)
Jo^

















cation £***^/ 4JL*J~ 2W- (^^S£^)
pressure 2J*1t> in.Hg
perature, °F *^ Stack temperature, °F
4W^


leak checked ^ Sample train leak checked ^"

Traverse
point
fi'l
±.
3
1
f
f.


& " I
Z
3
*/
£~
^




AP
in.H20 ^N
X.0 ( Hi)
2.6 fffi
AS (£-*-!
3./t> fcz-
Z.zs' fa*}
9.rp (&})


2&Be> (f*'}
<*>ftrt> (T*^
3,c& (&>*)
3> 10 (££
$JJQ CS?)
mo (f~i)




^{*£L> (-?.€'
Rate meter
flow rate,
cm3/min















•


r^ 1 & Average
Wv>Q~St-'*&
% Dev.a



















Dev.  =  (	^SL) 100
                                       (Must be <1Q%)

-------
Date
          /* -tf -
                    SFg  TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
              Plant
      rrtMAe —
Sampling location
Barometric pressure
Ambient temperature,  °F

Operator 	
                              Stack temperature,
Sample bag leak checked
           ^^
           Sample  train  leak checked
                                                            in.Hq
  Time
 (24-h)
Traverse
 point
in.H20
                                                    Rate meter
                                                    flow rate,
                                                     cm3/min
Dev.
                       ft/-/)
H: //-//./*
It \i?-H\i I-
                              X -
                              *.c '/*>/)
*% Dev. = (-
            Q - Q
   -) 100
                   Average

                   (Must be  <10%)
               avg.
                                     B-195

-------
                           SF6 TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
                                                             tl r'j
        Date
                              Plant
Sampling location

Barometric  pressure
                                          ff
        Ambient temperature, °F

        Operator
                                             Stack temperature, °F
                   Tr V
Sample bag  leak checked
                                                     Sample train leak checked
''T'9
          Time
         (24-h)
        11:11-
                Traverse
                 point
                    I 'V    (Ot-i )

                      "
                    M-S)
                     "
                          fei-s)
  AP
in.H20
           Q • Q
   Dev.  =  (	^-) 100
              avg.
Rate meter
flow rate,
 cm3/min
                                                             Average
                                                                                    in.Hg
Dev.
                                                             (Must be <10%)
                                           B-196

-------
Date
                   SF6 TRACER GAS BAG SAMPLING FIELD DATA
                              RUN NO.
                              Plant
                                        >&**»-
Sampling  location
Barometric pressure
                                                                            1n.Hg
Ambient temperature,  °F
Operator 	
                             V?
                                              Stack  temperature, °F
Sample bag  leak  checked
                                              Sample train leak checked
              "avg
                                     B-197

-------
                   SFg TRACER  GAS BAG SAMPLING FIELD DATA

                              RUN NO.
Date
                    -A?-re-
         location
Barometric pressure
Ambient  temperature, °F

Operator 	

Sample bag  leak checked
Plant
                                                     Stack temperature, °F
                                                     Sample train leak checked
                                                                                  in.Hg
  Time
 (24-h)
                        Traverse
                         point
       AP
     in.H20
Rate meter
flow rate,
 cmVmin
Dev.
                     te-i)
             6-tf
            &-
-------
Date
                   SF,  TRACER GAS BAG SAMPLING FIELD DATA
                     D

                             RUN NO.
                             Plant
Sampling  location
Barometric pressure
Ambient temperature, °F

Operator 	
                              T
Sample  bag leak checked
                        (J
                                            Stack temperature, °F
                                        in.Hg
                                            Sample train  leak checked   \^

  Time
 (24-h)
 /:*>- //:»v
//:?« '/J
//*•&-//•&
                Traverse
                 point
            *-
-------
                  SF6 TRACER GAS BAG SAMPLING FIELD DATA

                            RUN NO.
Date
                            Plant
Sampling location
Barometric pressure
                               
                            *>*? fw)
                                  M)
Rate meter
flow rate,
 cm3/min
   Dev. =
           Q -  Q
               av9
                  -) 100
             *avg.
                 Average

                 (Must be   y
                                                                 e+JZ**^
                                                               r*4t.
                                B-200

-------
Client   tos
f»N
                            LABORATORY DATA
                                        Analysis
              Date
Analyst
Calibration number
                        AIR SAMPLE ANALYSES
                             SF6 TRACER

































Sample I.D.
SM PL. t- PLATFW n ( /» /^ /s / f^ r)
^no/ary L'lHflmT OncT

Pk -1*
PR.~ /B
^A - ^^
^/^-«?C
r R • 3 fl
M-3/0^
pK-^n
PR- V6





















Atten.
/
/

2
A
2
0.
V
V
?
?





















Peak
Height
/SL
/a-3

C.I
HI
S'35"
595-
^0
10
:r?r
£(?.5





















Response
/2.
/*-3

I?**
^^
107
If 9
3s?
35 9r
V7A
y?^





















Concen-
tration
v/v
^C^/^'/;>
t-CX/O'1*

0.\».&.
0. w. ft..
0.IAJ.K-
0.IAJ.A
l*lK\0^
2.9LH/0~1
707 X /O"'
3-/y < /o"1























































































            OP

-------
Client
PN_
                   a I to It
                           LABORATORY DATA
                                        Analytic
Analyst
                                        Calibration Number   HL -H> -|
                        AIR SAMPLE ANALYSES
                            SF6  TRACER

































Sample I.D.
PR- rr
Pk'lT
PK -7T
PK'ZT
PR-I
rn-io
PR.- n
PR'I^
























Atten.
IL
Ib
It,
11,
3^
33-
32-
3^
























Peak
Height
90
70S
&f.S
7/7. r
vr
yv .5-
u
vv
























Response
mo
II 2 1
III3L
112.2
/yvo
/y/4
/V7^
/voo
























:oncen-
tration
v/v
?'« */0"y
£.M*rc~*
C-tZXfD*
6f?*to'1
9.(2X(0~1
ff ,fr* ^o"f
f.3yx/o"7
f.tYxio'*


























































































                                  3-202

-------
Client _Jii
      LABORATORY DATA

                  Analysis
             Oite
Analyst   6/tfc'G
                  Calibration Number
                       AIR  SAMPLE  ANALYSES
                            SF6  TRACER
Sample I.D.
At ten.
 Peak
Height
Response
Concen-
tration
  v/v
    (LPft - I
                          J-fstx/
    cm -
    CPfi ' 3
                          I.OO
    CPfl
           S3L
    cm -c
                                       /66V
                                                        /A/
         - 3
 3*
                 1.07*10'*
                      32
           /. 7
                      to
                                                     "9
                      32.
                   ICJ3L
                               B-203

-------
Client _JiL
Analyst
                           UBORATORY DATA

                                       Analysis
                                       Calibration Kuaber
                       AIR SAMPLE ANALYSES
                            SF6 TRACER
Sample I.D.
                    Atten.
 Peak
Height
Response
:oncen-
tration
  v/v
     0*CT
                               '3.0
        -\3
        -  /
-------
Client
PN
                             LABORATORY DATA
                                         Analysis
                Date
   Analyst   6ft te 6  n
                 Calibration Number
                          AIR SAMPLE  ANALYSES
                              SF6 TRACER
   Sample I.D.
                    At ten.
         Peak
        Height
Response
Concen-
tration
  v/v
      AC.-I
                       32,
                 113 (
         -3
                      35L
                         Usxto't
                                 5TV. 7
                                               1.60*10
                                                        -&
                                          /77f
                                               103*.
                                          1710
                                               i.ni
(AtJ
        ' 3
35.
                                           HO
                                 B-205

-------
Client  t/fs fe'/v? / fi
      4ABORATOKY DATA

                  Analysis
             Date
Analyst
                  Calibration Hunter  A* Va -fa.
                       AIR SAMPLE ANALYSES
                            SFg  TRACER
Sample I.D.
At ten.
 Peak
Height
Response
:oncen-
tration
  v/v
   /9c/3 -
                            VOIQ
         -/
           11,
         - c\ - 1
                                        ILK
                                        ftgo
                               V7
                      33-
                      33.
                   Ml
                               V7-3
                   istz.
                 t.
                      32.
                      Ik
                      It*
                   /67V
                               73
                      n
                      33.
           77, r
             -3-
                               3V. 7
                                       7733
                                       /67S-
    ut,f/T
                   /(.Xt
           re/1-/
                               2*5-

-------
Client
PN 3VJP-?  Date

Analyst
      MOMTORY MTA
                 Analysis
                 Calibration HuBbar
                      AIR SAMPLE ANALYSES
                          SF6 TRACER
Sample I.D
At ten.
 Peak
Height
Response
concen-
tration
  v/v
                             SO
                  /too
         -3
          SO
         /t>0t>
  /?££'-/}/-•/
                     ft,
                                     ii n
                             11
                     H*
          70
          //a?
           - 1
          70 .4
         f/30
                     Ik
          ?/•*
                     ri
          7/a.
                6 -29 x
                     IL
                  161?
                                     ins
                                     13-51
                     72-
      : - ni-l
                         f.aox
        ~ QI-3
                  isn
                                /
                     32
        - 03 •/
   Jb
  7/
                             61-7
                  H7.1
                      It,
          71 
-------
   Client
      US •;//! / /? ?/?.
LABORATORY DATA
            Analysis
PN  ?V
                 Date
   Analyst
 Calibration Number
                           AIR SAMPLE ANALYSES
                               SF6 TRACER
                                         A UK'S
   Sample  I.D.
                    Atten.
    Peak
   Height
Response
Concen-
tration
  v/v
                                   7
                                               41
                                                S'.Sy/e'
L' Tf nnu IT
                                                         -9
           -A/- 6
                                   YO
                                                  j. 00X10*
                          30
         /3
                          3 ^L
                               V/-7
                                   y/.r
                                       7777
                          33-
                                3/
             ft*
                          3P-
                                           1 Li'l "'
                                           / 7 / o^-
                                      6'
          C ?' 6
                                ro
            it, oo
          cy- r
                                                         '
          C
              -6
                                  B-208

-------
Client _kl
PN^2±L
Analyst
                           LABORATORY DATA

                                       Analysis
                   15- -
                  Calibration Number /3~f)-%2
                        AIR SAMPLE ANALYSES
                            SF6 TRACER
Sample I.D.
Atten.
                               Peak
                              Height
Response
Concen-
tration
  v/v
                      3P-
      0 1 -  4,
        0
                  /j- 6> V
     Ml-
                  L/0/O
                              OFF
                       t
           -76
                               77
                              B-209

-------

B-210

-------

-------
 Mlllll'Himui HIM Illilllll Mill riTTTIITITIIIIfTTlllTTIiriTTtirnhliil-llllllll-m
111111111111111111111111111111 Mj>l tf Kidu 11 n 111111111111II1111 n 11111111111 ii 1111111 M 111 n

-------
rrrTTTtinnnrnnn-ffhnnmTr.

-------

-------

-------
i  I   I  :  1_LLL    ,.'   '  ...'_!...'	...'-1-.  '  '....•_!_'_'        .

-------

-------

-------

-------
       Ut £Pf\  A*A* C6
                    LABORATORY DATA
                               Bottle Volume:
 Analyst
                               Gas Change Time
                               Initial Cone. (Co) '•
                SF6 CALIBRATION BY
               EXPONENTIAL DILUTION
                                                          O.Shi
                                                               -N
                                                       C • C0E
Time
Time
(Decimal)
   N

(TD/TGC)
Atten
 Peak
Height
Response
                                                         Cone
                               5" /A
                               ST/3.
                                77, a
                               IT/A
                                7^.7
                                        rr.3
                                        At. lit
                                                17,101
 i
                                         f.Silt
                                     futo'*
 1C
                                 ^' 7
                                         y/7
 /a.
 /J
 /r
 17
                                                1.91* to'u
 H
                                                3.61 mo
                                                              -II
ar
it,
                                                S-'Jff
10
                                                  /9
                                   B-220

-------
                            100,000
                             10,000
w
 I
to
K)
                              1000
                               100
                                10
                                                      TYPICAL WORKING RANGE
-10
                 10
-9
                                                                                       SF6 CALIBRATION
                                                                                       RUNS *1  &  2  12/13/82
                                                                                       BAKED OUT  12/12/82
                                                                                        I
                                                                        I
                                                                             m =  .92924198
                                                                             b =  10.606476
                                                                             r =  .99998
10"              10
SF6 CONCENTRATION,  v/v
                    -7
                                                    10
-6
                                                                                        10'
.-5
                                                             Example SFg calibration curve

-------
w
 I
M
to
ro
                    1,000,000
                      100,000
                       10,000
                       . 1000
                         100
                          10
                                                      I        I
                                           io-13      io-'2
11     ]0-10     10-9      1Q-8

 SF6 CONCENTRATION, v/v
10"7    10'6
                                                                                                                   10
-5
                                                 Example SFg calibration - full  scale

-------
S02 ~ CEM DATA AND EXAMPLE
   STRIP CHART PRINTOUTS
          B-223

-------
Operation
                          PnOOCOS DATA
                                       Date
                                       Page
                                                        of
                                       Observer
                                               Pf M
                              Co
                                                ±
G
   ^T
   rr
ZC.L&.
                                               -£
                                               ILL
                                                    '4*4
                 ?.zl
                                               22.
                                                    96,0
                     ll.
                                        /S
                4-3Z
                                            222.
                                    122.
                              LO
                             Ik
                                                       7g2^
                     \1 '
                                Mi
                                                            y^-^4
                                            6*7
                                                       g^.^
                     /8V 2.
                                                         JL
                JLJL
                              Hi'
                                        AS
29
    z^L
                    •1^20
                                        9.^7
        777-6
                                             £,6
                                        /
                                                                1*8
                              B-224

-------
Plant
City  7/Oc.o/?//?
Operation
                                          DATA
                     7
                                                  Date
                                                  Page
Observer
                  of
     /'/«
                                                                    . t
                            30:4$
                                                 2?
       lit
                                                        It,
                                                                           14. Og
                              1 '30
                                                                           M./6
                                                                  1 17
                            2/.S7
                                               2Z-
                            2.2 :
                              : if
                                      B-225

-------
Plant
City  //
-------
  A
                                   o+*~4 >L~
                                  PWW55 DATA
Plant /HS/0&CO

City
» A
Operation Con/MET?Ff7?   7  L^L
                          /)/? 6t
                              "XT^"
Date

Page
                                                             ''2-
                                                                           of
                                                       Observer
C
  onvr??
                                          Xl.r
                                          Cw.»-
                                          TUrvj l?t. W.
                                                                     £0
 TU a
                                  -II
                                                                        28
                                                -fZS
                                      Co
                                                                a
                  AT
                              to  ^(>
                                           'It-
                            >7Z7
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                           1 o :
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         L.
                               ,'/ ' OO
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                                       14,'
                                                    > 1 o \o
                                       i-o
                                                    20
                                                                /I
 r      &,
 l^^ry^/kS^l / UH
       :_f^
                                                            70
                                                                     3.2.
                                                           
-------
Plant


City'
Operation (^
                                PKS6ESS DATA
                             .^ '-,...
                                                Date
                                                     Page     /
                                                Observer
                                                                   of    3
                                       ' l?c-
                                                           pf «
                                     I-/.
                         21-44
                                                             97
1'-, "- C Q-;
                             -2/.TJ
                                          14.'
                                              10
                                                             lot
                                                                  //•T.Z
 .   .   ,
 I1' 5, t^- L \jurfr-*'
                                     Lt.
                                                   2-3
                                                                       43. Z

C
                          12:14
                                          /J
                          2:22.
                                                            .
                                                        3Z
                          13:* 8
                                                                                 It, U
                         il'/l
S'a? C
                                13.
                          13
   r. -' it-
                                                             //f
                                                          1.0

                           7.
 Ct', \'j-tA
                            ' 
-------
Plant
City~
                             W8W5S DATA
Operation
            T?  7
                         3^:
                         T* ^1**
Date
Page
                                                 Observer
                                                             of
                                                                        3
     J Ll.1 U-
         -V.
                                 M'
                                                       7?
                                                                    2-
c -o^
                            IT-**
                                                                  o
                                                                3/34
                                Uo
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                       /8-*y
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                                 lit'
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                                                                                                   IM»IMCOI
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 I
to

-------
    APPENDIX C




LABORATORY RESULTS
       C-l

-------
PARTICULATE
   C-2

-------
               BLANK ANALYTICAL DATA FORM
Plant
               0
Sample location   f/)COn/3    fifR  C a/? 7/9/A/ G*HA«<>T
Relative humidity
Liquid level marked and container  sealed 	J/
Density of acetone  (pa) 	.j90%	
Blank volume  (Va)  CWT• # YZQafi /  C T ' J36 I
                                                            _g/ml
                                                              ml
                                                                  ,
                                                                  3-7C.>*»
Date and time of wt   2/7/P3 & i?930  Gross wt   /Q 3
Date and time of wt   «?//? y /&^ ^7/3^  Gross wt
                                                           fi -'nig /Q ^ ^ p 7 /}
                                                     J
                                                             'mg
                                Average gross wt
                                         Tare wt
                           Weight  of  blank (ma)
                                                  /Q
                                                             'mg
                                                             _mg
                                                              mg
                        m.
                      va  Pa
                                                  0.
                                                            mg/g
Note;  In no case should a blank  residue  greater than 0.01 mg/g)
or 0.001% of the blank weight be  subtracted  from the sample
weight.
Filters Cf»~.ft
                               Filter  number
                                                  170 > 9
                                                  379.?
                                                              mg
Date and time of wt   3///g3- @0?C>6  Gross  wt
Date and time of wt   3-/
-------
 Plant
          METHOD 5  TRAIN ANALYTICAL PARTICULATE DATA
                                              Run No.
Sample location
Relative humidity
Density of acetone  (pa)
                            A/e . i
                                                      g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
v/
tec
Liquid level at mark
and/or ^container sealed
•/
Y££
 Acetone rinse container no.
•
 Acetone rinse volume (Vaw)
                                          CT-
                                                  ml
Acetone blank residue concentration  (Ca)    Q, &
Wa = Ca Vaw pa «  (.0/0  ) Ui'4~ ) ( 7^tf ) «     <,", c
Date and time of wt  ^/f/g"> @. 0?3O    Gross wt
Date and time of wt  "Z//cfe~i P. @%1>O    Gross wt
                               Average gross wt
                                        Tare wt 	
                     Less acetone blank wt  (Wa) 	£
         Weight of particulate in acetone rinse /O/.g y
Filter(s) container no.
Date and time of wt 	A
Date and time of wt
                                                         mg/g
                                                         mg

& O9oo
fi o9o°
                                         lFH-Tt-*> -ft-
                                       Gross wt
                                       Gross wt
                                                   6 ?£
 mg
 mg
J7
 mg
'mg
                               Average  gross  wt
                                         Tare  wt
             Weight of particulate on filter(s)
         Weight of particulate in acetone  rinse
                    Total weight of  particulate
                                                   /?/.
                             mg
 Note:  In no case shall a blank residue greater than  (.01 mg/g) or
 .001%  of the weight of acetone used be subtracted from the sample
 weight.
 Remarks:
      Signature of analyst
      Signature of reviewer


                               C-4

-------
Plant
         METHOD 5 TRAIN ANALYTICAL PARTICULATE DATA
                 Run No.
Sample location
Relative humidity
Density of acetone  (pa)
                            /\Jo-
      St-ICbN QfifiY
                        g/mi
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
i/
K^-6
Liquid level at mark
and/or container sealed
i/
Yt'S
Acetone rinse container no.
Acetone rinse volume  (Vaw)
                                 G/O
                     ml
                                             - 0/0
Acetone blank residue concentration  (Ca)
Wa = Ca Vaw pa «=  (.0/v ) ( f- to   ) ( -7^2 ) «     ¥.
Date and time of wt   .?/>/(? 3  & O95O  Gross wt
                    ^^^^ "~  —
Date and time of wt
                           mg/g
                                                       / mg
                                                         X,
                                                          mg
/&
  ^
                                       Gross wt  j.Dtr5^.J
                               Average gross wt
                                        Tare wt
                     Less acetone blank wt  (Wa)
         Weight of particulate in acetone rinse
Filter (s) container no.    $ £ yt/ I /AJ^  C T"
                                                          ~tng
                       V.g>
                                                           mg
                                                           mg
time of wt £///? 3 $ OJoc Gross wt
time of wt ?/s/?3 £) Ofoo Gross wt
' / C-^"
Average gross wt
Tare wt
Weight of particulate on filter (s)
Weight of particulate in acetone rinse
t17,l -• mg
V/7'/ "'' mg
V^7 / "^'mg
J ? ?. ? ^mg
/3i?- P-^mg
&9.(/ " mg
Total weight of particulate 	 o?P7-6_ mg
Note: In no case shall a blank  residue  greater than (.01 mg/g)  or
.001% of the weight of acetone  used  be  subtracted from the sample
weight.
Remarks:
     Signature of analyst
     Signature of reviewer
                              C-5

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         METHOD 5 TRAIN ANALYTICAL PARTICULATE DATA
Plant
                                              Run No. PfiTC. -
Sample location
Relative humidity
Density of acetone (pa)
                           N*  i
                                                     g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
V
n^
Liquid level at mark
and/or container sealed
i/
n-*
Acetone rinse container no.
Acetone rinse volume (Vaw)
                                                  ml
                                             .0/0
Acetone blank residue concentration (Ca)
Wa = Ca Vaw pa « ( .0/0 ) (V/o  ) ( -7W* ) « 	3^
Date and time of wt _ ;7/?/f 3 <& o??C>    Gross wt
Date and time of wt
                                                        mg/g
                                                        mg
                               0%3O
                                       Gross wt
                               Average gross wt
                                        Tare wt
                     Less acetone blank wt  (Wa) 	
         Weight of particulate in acetone rinse 	
Filter(s) container no. T&,siLflfcft CT- YS6/ !-/<-Tt'*. it
Date and time of wt   Z///Z 3 (p O900    Gross wt
Date and time of wt
                                                     7/27
                                                   35"
                                                          mg
                                                     '.
-------
         METHOD 5 TRAIN ANALYTICAL PARTICULATE DATA
Plant
                                              Run No.  PA
Sample location
Relative humidity 	
Density of acetone  (pa)
                            Mo.  y
                           7o
                                                      g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
i/
Yi/s
Liquid level at mark
and/or container sealed
(/
Yes
Acetone rinse container no.
Acetone rinse volume  (Vaw)
                                       ft  I
                                                   ml
Acetone blank residue concentration  (Ca)
Wa = Ca Vaw pa «=  (.C-IO   ) C/3*  ) ( .7?C?)  •=
                                                010
                                                         mg/g
                                                        -'ing
Date and time of wt
Date and time of wt
                          '-')  &
                          ^^—
                      Sl//e/z'i ,/
                                        Gross wt
                                        Gross wt
                                                  /c>2
                               Average gross wt
                                         Tare wt
                     Less acetone  blank wt (Wa)
         Weight of particulate in  acetone rinse
Filter (s) container no.  57,7^ /Lt)A# C T-W3/F"*TC'**
Date and time of wt   3/i/Z3 P. O9a0     Gross wt
                       T 1^ ^^
Date and time of wt  «V//f ?  £> O90Q     Gross wt
                               Average gross wt
                                         Tare wt
             Weight of particulate on filter(s)
         Weight of particulate in  acetone rinse
                    Total weight of particulate
                                                     7O/.J
                                                  /p*

                                                    "3 . <-/
                                                         •^ ng
                                                         /ing
                                                         >
                                                         /mg
                                                         ;_'' mg
                                                         '  mg
                                                        9
                                                   lit-?,
                                                           mg
Note: In no case shall  a  blank  residue greater than (.01 mg/g) or
.001% of the weight of  acetone  used be subtracted from the sample
weight.
Remarks:
     Signature of analyst
     Signature of reviewer
                               C-7

-------
         METHOD 5 TRAIN ANALYTICAL PARTICULATE DATA
Plant
                                              Run No. PflTC -3
Sample location  -r/Kin/3  Me. V £t:JiMK?
Relative humidity
Density of acetone (pa)
                                                     g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
J
V^S
Liquid level at mark
and/or container sealed
•/
hf<,
Acetone rinse container no.
Acetone rinse volume (Vaw)
                                        C.T-
                                  ¥00
                                                  ml
Acetone blank residue concentration
Wa = Ca Vaw pa = ( ^/,
Date and time of wt
Date and time of wt
                                     (Ca)
                                             .0/0
      mg/g
      mg
                                       Gross wt
                                       Gross wt
                                                 Jo ty
                               Average gross wt
                                        Tare wt
                     Less acetone blank wt  (Wa)
         Weight of particulate in acetone rinse
Filter (s) container no.  y//7/
Date and time of wt
Date and tine of wt
                                                    0%?:l '
                                                 /Of
                                                          mg
                                                          ,s
                                                   3$~3C>
-------
         METHOD 5 TRAIN ANALYTICAL PARTICULATE DATA
Plant
                                              Run No./)/9<:/1 -3
Sample location  fft ton ft
Relative humidity
Density of acetone (pa)
                                                     g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
/
J
Yii<>
Liquid level at nark
and/or container sealed
S
Yt-s,
Acetone rinse container no. 	
Acetone rinse volume  (Vaw) 	
Acetone blank residue concentration  (Ca)
                                         / cr~
                                              '.0/0
Wa = Ca Vaw pa -=  ( .
Date and time of wt
Date and time of wt
                       ) (
                              ) ( .
                                     )
                                           _ _
                      p/f/?3 ^5 093O   Gross wt  //?/
                      P//Q/ZJ (& O&3O   Gross wt  /0*J
_ mg/g
 •'mg
                               Average gross wt
                                        Tare wt
                     Less acetone blank wt  (Wa)
         Weight of particulate in acetone rinse
                                                 /^ L/
                                                          mg
                                                    ?
                                                          mg
Filter (s) container no.  */2C3 /{./)£ & CT- ift/l j pit-Tun. 4- if
Date and time of wt
Date and time of wt
                            (£>
                                       Gross wt
                                       Gross wt
                                                      -1 - ">9
                                                  393- I
                               Average gross wt
                                        Tare wt
             Weight of particulate on filter(s)
         Weight of particulate in acetone  rinse
                    Total weight of particulate
                                                   33.3
                                                           mg
                                                          ^
                                                           m
Note: In no case shall a blank  residue  greater  than  (.01  mg/g)  or
.001% of the weight of acetone  used  be  subtracted  from the sample
weight.
Remarks:
     Signature of analyst
     Signature of reviewer
                              C-9

-------
PARTICLE SIZE DISTRIBUTION
        C-10

-------
                  ANDERSON IMPACTOR ANALYTICAL DATA
   Plant
                                                    Run No. PS ft "I bLflWK
  Sample location
                                /L/-  V
   Relative humidity
   Density of acetone (pa)
                               6. We
                                                         _g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
,/
,/
Liquid level at mark
and/or container sealed
J
t/
  Acetone rinse container  no .
  Acetone rinse volume  (Vaw)
                                  V / 7 7 /9
                                                Lab no.
                                                 inl
                                                 0.0 IP
Acetone blank residue  concentration (Ca)	
Wa = Ca Vaw pa «=  (£.010)  ( iytj )  (s.tfeft  = 	/. /   	
Date and time of wt  «?/?//3 /P. 23'3O    Gross wt  //Q 3-3(J.3
                     I i
Date and time of wt 3/tf/f 5 (£? 9$ 1C*   Gross wt
                                                               mg/g
                                                                mg
                                                   //#
                                                               mg
                                Average gross wt_
                                         Tare wt_
                     Less  acetone blank wt (Wa)_
         Weight of particulate in acetone rinse
  Filters
  Stage    Filter No.
                                                                mg
                                                    //3 /V3 g 113-J -0-1'.
Cf- IC•
cT-3a<~ fj?>1 /V? V -5.A'-
Cl'3d& /£?'6 I&2-G O'C)'
Cl-307 if3 O 1*3- 0 0-0 -
C7-J09 3/9,0 217. ? /'2
                                                   P/^,3
                     Weight of particulate  in acetone rinse
                                                       Total
   Signature of analyst

   Signature of reviewer
                                  c-li

-------
                 ANDERSON IMPACTOR ANALYTICAL DATA
  Plant
                                                    Run
  Sample location
                                 L/
  Relative humidity
  Density of acetone (pa)
                                                         _g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
I/
i/
Liquid level at nark
and/or container sealed
I/
S
 Acetone  rinse container no.
 Acetone  rinse volume (Vaw)
                                                  Lab no.   Cr-¥/?
                                                 ml
 Acetone  blank residue concentration  (Ca)     QmQ I 0
 Wa  =  Ca  Vaw pa = (fl.r-io ) (-^V )  (O.l-^) = 	,
 Date  and time of wt 2/?/<<'<.  $ ft?30   Gross  wt
                                                               ng/g
                                                              /mg
                                                               mg
 Date  and  time of wt x//://3
                               	^2	 Gross  wt   ffO  7/?,'?  l mg
                               Average gross  wt   //fl  ~$l ?>0  * mg
                                        Tare  wt
                     Less acetone blank wt  (Wa)_
         Weight of particulate in acetone rinse_
 Filters
 Stage     Filter No.
Yf  0
                                                   I/O  ?/// •' mg
                                                     /. C    "  mg
                                                          £.3 '
                                      mg
                         Lab No.   Gross,mg     Tare, mg    Net, mg
    2
    3
    4
    5
  '/ 7
^ Backup
Q--309
C7- 7/0
CT-3/1
C.T- 7/3L
             flr. -
C7-J/4
C7•3/7
/40'V
3.~jQ' 6
                                                               f.
                                                  142. I
                                     5". 3
                                                              AT.
                    Height of particulate in acetone rinse
                                                      Total
  Signature of analyst
  Signature of reviewer_
                                 C-12

-------
                ANDERSON IMPACTOR ANALYTICAL DATA
Plant   fit ft A CO
                                                   Run No.
. 'Sample location
                             /(Jc
 Relative humidity    :X
 Density of acetone  (pa)
                                                        jg/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
/
^
Liquid level at nark
and/or container sealed
,/
i/
 Acetone rinse container no .
 Acetone rinse volume  (Vaw)
                                 / 7 ? /9
   Lab no.
                                 // £->
 Acetone blank residue concentration (Ca)	
 Wa = Ca Vaw pa =  (.£/{•• )  (//£ )  (.7?'1£)  c 	
 Date and time of wt  .,7/V?*  /£? /?^3^  Gross wt
£jnl
  .010
                                                0.1
                                        Tare wt  //?/ ^
                     Less acetone blank wt  (Wa)	^7.
        Weight of particulate in acetone rinse	Q'• ^
 Filters
 Stage    Filter No.     Lab No.   Gross,mg    Tare,  mg
   0
                        CT-JJfc
  2
           AT-
     » c
  ?7t:-7 •*
  777^ 6
  377' 7
777^ Backup
           6J-/57
   /W-f
   /.•s'J V
             A/4/
                                     /J7
           AT -
                                                 319.3.
                                                              mg/g
Date and time of wt  3//4/?J fi JglC*  Gross wt   /?/ $>£%
                              Average gross wt   /Qj (->%
                                                              ing
                                                           Net, mg
                                                            3.3-
                                                              1-3
               S-S
                   Weight of particulate in  acetone rinse
                                                     Total
                                                              73
                                                              (?. <
Signature of analyst
Signature of reviewer
                                C-13

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                 ANDERSON  IMPACTOR ANALYTICAL DATA
  Plant
                                                  Run
Sample location  Tnc.QKA   No V
Relative humidity
                              lo
  Density of acetone  (pa)
                                                       _g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
/
i/
Liquid level at mark
and/or container sealed
I/
^
Acetone rinse container no.	4"/ 7-?
Acetone rinse volume  (Vaw)	//3 ^
                                                  Lab no. CT-J3.1/
                                                jol
                                                 •010
Acetone blank residue concentration (Ca)	
Wa = Ca Vaw pa =  ( >0\b )  ( i)3  )  (-7^)  = 	0. 1 -	
Date and time of wt  2/?/«3 & o93O  Gross wt   /0f  7~32..
                                                             mg/g
                                                               /
                                                               mg
Date and time of wt  2 //•'>/?'
                                        Gross vt
                              Average gross wt
                                       Tare wt_
                   Less acetone  blank wt (Wa)_
       Weight of particulate  in  acetone rinse
                                                       7^ £3
                                                               mg
                                                     3-3
                                                             mg
Filters
Stage    Filter No.    Lab No.    Gross,mg    Tare, mg    Net, mg
           A/-/ -il       £7- 3*3     777,2.       /£ 7 
-------
               ANDERSON IMPACTOR ANALYTICAL DATA

Plant  ftsftRC.0	__	 Run No.
Sample location  r/9co/1/3    A/0   H
Relative humidity	3^ /<;	
Density of acetone (pa)	0 • ~~lCtctf
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
V
J
Liquid level at mark
and/or container sealed
i/
i/
Acetone rinse
Acetone rinse
Acetone blank
Wa = Ca Vaw pa
Date and time
Date and time
container no. *S/ ?2- tf
volume (Vaw) //!? ^
residue concentration (Ca)
= (-C'lO ) (11* ) (.7?W) «
of wt 3/?/s3 P. 0?3& Gross wt
of wt 2 //c>f? 3 K 0t~$° Gross wt
Average gross wt
Tare wt
Less acetone blank wt (Wa)
Weight of particulate in acetone rinse
Filters
Stage Filter No. Lab No. Gross, mg
Lab no.
ml
.010
0.1
fal . 0 -
W 1 /3fi
r.o^2 £z-
?*3 3 br-
"f.:1) 4 y3w~
-7? . CT-311 HC=-%
-63 cr-37.2. iGf-?
13- LT-'J7~5 /J^.Pv
-J5" r.r- J?y /r/C-6
/y&-ls •
/s j. y
/J7 • y
fsa.g
6 O -•
//. y -
y.v •
?..>?-
s'~?5 CiT'iH (..T-Trtr /32-Y tjf'f j-£)*-
PPi 6 f$fi-£3 C-f-3fte f&t-C) f$J $ y> Q ~
'^77 _b^-0f> ^.7"--?fZ r!9. Y fJ'Lf ¥-£~ "
^Backup /3-f>"^/ r T-itZ ?.?&(> ^y^-^- V-1/ '

                  Weight of particulate in acetone rinse   .?-"?
                                                   Total   C
Signature of analyst	
                       S
Signature of reviewer	
                              C-15

-------
               ANDERSON  IMPACTOR ANALYTICAL DATA

Plant  nsRRCd	__	 Run No./W
Sample location  TfiConft    NO  j $U'
Relative humidity_
Density of acetone  (pa)    0- i t£  07 W " mg
Date and time of wt  •?/£/?3 ^7 ^/JO Gross wt	
                              Average gross wt	
                                       Tare wt
                   Less acetone  blank wt (Wa)	/ 0     -  mg
       Weight of particulate  in  acetone rinse	9- - */    '  mg
Filters
Stage    Filter No.
  o
  1
  2
  3
5- 4
3 5
  6        fi>LL ~
Lab
CT-i
No.

Gross, mg
lt,o 7 •
Tare, mg Net,
if? 7 /i.o
mg

C.T if1-? H7. h iij y~ s"- V •'
CT-
CT'~
y//^
•///
Ho. Q
rtt-Ji
IJif. lc • V ?•
sn 2 2 y
'v, •
.
cr-f/z 113. i i-tf. C, J-/ --
cr-
CT-
CT-
C-7 -
y/j
y/y
y/r
y/f
I3?.k
/VCj(o -
/37V
237.? •
/P?.7 J?. ?
/ J / • 7 / • c^-
/3*.f • y-6
3o~} v • ^r
^
-
^
•*•
                  Weight of particulate in acetone rinse
                                                    Total
Signature of analyst	
                            ^\~^     r^1                  • / //
Signature of reviewer	J^<-  £JL..\^\uJct	(ML-
                               C-16

-------
                ANDERSON IMPACTOR ANALYTICAL DATA
 Plant
                                                  Run
 Sample location  Tfl cof\ A
                                              . Y £> /y/?  »  m'g
                                 __^	mg
                                  ^  -  s
   3
   4
   5
733 7
-Backup
                         C.7-7/?
                         cr- 3^^:
                                        9
                 II
            /3 g-- 9 v
            AC- yf
                                      ^- /
            A-
CT-
                        IHl, 4
? ,0 ? .
^
                                                              y . a.
ZC-7'
                   Weight of particulate in acetone rinse
                                                     Total
 Signature of analyst

 Signature of reviewer
                                C-17

-------
               ANDERSON IMPACTOR ANALYTICAL DATA
Plant  ft Sfl ft CO
                                                   Run No.
   Sample  location^

   Relative  humidity	

   Density of acetone (pa)
                            l\Jp. H
                              Ci
                             ' '°
                              0 •
                                                         g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
J
i/
Liquid level at mark
and/or container sealed
/
j
Acetone rinse  container no.

Acetone rinse  volume (Vaw)
                                   $0
                                                    Lab no.  C.T
                                 10 J l/
                                                  . o
                                                              mg/g
                                                0.?
                                                              mg
                                                              mg
   Acetone  blank residue concentration  (Ca)	

   Wa = Ca  Vaw pa = ( .-c/c )  (/ QUO   Gross wt
                          .. T[
   Date and time of wt .?//*/>? P, 0?3O   Gross wt   /&ty 12 £2 - rog
                           /                                        .
                                 Average gross wt   /OJ j'2 f.7-'" mg

                                           Tare wt_/^/ ^ S.7

                       Less acetone blank wt  (Wa)	

          Weight of particulate in acetone rinse	

   Filters
                                                               /
                                                    /),?
                                                              mg
                                                               /
                                                              mg
Stage
 775-31
 ?7? y 2
 77 i- r 3
 37?£ 4
 j>7?7 5
 37£?6
 3??? 7
-? 7 ff Backup
         Filter  No.
           &F-7C
                           Lab No.   Gross,mg
                        cr- ~>i
                      Tare, mg

                        /f,z.y.
                       Net, mg

                         7.7 ,
             6 -//
CT-3Yf
CT-350
CT-^iTl
                                    767.
                        cr- J*~J
177-1
Ibl.O
211. (r

                                                   * V
                                                  04.7
                   Weight of particulate  in  acetone rinse
                                                     Total
                                                                   s
Signature of analyst
Signature of reviewer
                                C-18

-------
                ANDERSON IMPACTOR ANALYTICAL DATA


 Plant /95/9^w	Run  Ho.Ps5S'3

• Sample location   TflCQtifi   /I/?,  tf  <,£co/vj)fi#r t^XilfttflT	

 Relative humidity	i>i 70	
 Density of acetone  (pa)	'• • n^x	g/nl
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
•/
\/
Liquid level at mark
and/or container sealed
V
L/
 Acetone rinse container  no.      *// ?f //	 Lab no.  C.T'-	

 Acetone rinse volume  (Vaw)	l^1-/   ^	ml

 Acetone blank residue  concentration (Ca)	#/0	mg/g

 Wa  = Ca Vaw pa =  ( ^l!:  )  ( /yy  )   ( 7/Y£ )  e 	/. /  "'	^_mg

 Date and time of wt 3/9/?'j  &2 093°  Gross wt
 Date and time of wt 2//a/f 3 P. 0??°  Gross wt   /Ol
                      /  /    '—•'
mg
                               Average gross wt   /OI  ?{2.7 "'mg
                                                                j
                                        Tare wt    //?/ y?%3 ^ mg

                    Less  acetone blank wt  (Wa)	/- /	-  mg

        Weight of particulate in acetone rinse	3-3     " mg

 Filters

 Stage    Filter No.    Lab No.   Gross>mg    Tare/ mg    Net, mg
   1       AF- OJ        C~--J->3      13d-I
   2       /?»f'-_22__    c7-?;-7      /V,?-g>
               10	    cr-'J7i~      fl^.3.        '33 7      	/_
   4         n>n - n       t-r- ??£>      /'•
   6        Af-,' y3       r r- 37%     SVC-i        /£•?• «/        '? O -
            A/T - IT V	    <^r> 11?     /Tjr.Z.        I'7-P,        /<"'• J '
                   _    C.T- *?Q     itb 3.        /?&.
-------
                 ANDERSON IMPACTOR ANALYTICAL DATA
  Plant
  Sample location  7flt.0nfi    A/a.  V St
                                                  Run No.
Relative humidity
                          ^1- /c
  Density of acetone  (pa)
                                                        a/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
i/
\/
Liquid level at mark
and/or container sealed
l/
i/
  Acetone rinse container  no.
  Acetone rinse volume  (Vaw)
                                    b  A
                                                Lab no.  CT-
                                "77- *
                                at-01
                       ml
Acetone blank residue  concentration (Ca)	
Wa = Ca Vaw pa =  (.0/0  )  (?2£ )  (Ti'"l)  = 	
Date and time of wt J/-J//3 & 0:':O   Gross wt
                                                   .010
                                                            _mg/g
                                                   /- £.
                                                            ' mg
                                                   I/O 6^(>3  L mg
  Date and time of wt 2/W71-  P.  o?3i>   Gross wt   I/O 03.6.Y " mg
                               Average gross wt
                                         Tare wt
                     Less  acetone blank wt (Wa)
         Weight of particulate in acetone rinse
  Filters
I/O 03 L
/Of ?$
/\y
• 0
?,*/ v mg
~£2 ' »g
1 mg
  Stage
 .?i- 0
 ^ 1
37^7 2
         Filter No.
             - 07
Lab No.
C7-327
 Cr-33?
Gross,mg
 /ST- y
                                              Tare , mg
37/f 4
37 ff> 5
                          L-T-33&
                                   /5V.
                        CT-33
  Backup
                          (.T-33i
                                    IZ.I ,Q
                                   nt
Net, mg
  /- 3- -
  0-3 -
  0,L •
  /.^L
                    Weight  of particulate in acetone rinse
                                                      Total
  Signature of analyst
  Signature of reviewer
                                 C-20

-------
                  ANDERSON  IMPACTOR ANALYTICAL DATA
   Plant
                                                  Run No.
Sample location
                                 /1/v V  ?1O  Gross wt
                                 Average gross wt_
                                          Tare wt_
                       Less acetone blank wt  (Wa)_
          Weight of particulate in acetone rinse_
   Filters
   Stage    Filter No.    Lab No.   Gross,mg
                                                    .0(0
                                                             jng/g
                                                             mg
                                                                mg
                                                          7 C,
                                                             mg
                                                      /.
                                                             mg
                                                      W.
                                                             mg
3773 0
?77%. I
                                                             Net, mg
  /£>
                                                /£,? I
                * ' S X
?7 s /Backup
                           c r- JA a
                                                            J-O
                     Weight of  particulate in acetone rinse
                                                       Total
   Signature of analyst_
   Signature of reviewer
                                  C-21

-------
                 ANDERSON IMPACTOR ANALYTICAL DATA
  Plant
                                                  Run No.
  Sample location

  Relative humidity
  Density of acetone (pa)
                                                        g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
t/
\.'
Liquid level at nark
and/or container sealed
i'
\/
Acetone rinse container no. L//?3 A
Acetone rinse volume (Vaw) /%*} '
Lab no. £7~-
t/2£.
S ml
Acetone blank residue concentration (Ca)
Wa = Ca Vaw pa = ('CiiO ) (/?/ ) ( 11o%)
Date and time of wt 2/J/f3 {&). 093°
Date
and time of wt ^"///y/f 7 f) O
Average
Less acetone blank
B
Gross wt
Gross wt
gross wt
Tare wt
wt (Wa)
Weight of particulate in acetone rinse
.010
/, S' -
//557" ^7;^/
/^f ^7^
JC>$ 0700
/./?£"" ^/^1.3
/. r -
tr P ~2.
-J (> * **1^
mq/q
•/'
mg
.- mg
-mg
x
"mg
s
mg
mg
 Filters
 Stage     Filter No.
•?f o        r\r~^i
    2
    3
    4
                         Lab No.   Gross,mg    Tare, mg     Net,  mg
                         e.T'3?t
                         c r-
            y-
           AT- .CS
C. T- ??V
            /yp-f
            J^2-&
J ?•/.'- 7
/; Backup
v o
           2 Of- 2-
                                                303.
                    Weight of particulate in acetone  rinse
                                                      Total
 Signature  of analyst.
 Signature  of reviewer
                                 C-22

-------
                 ANDERSON IMPACTOR ANALYTICAL DATA
 Plant
                                                  Run No.
Sample location
                                                  /-'/
Relative humidity
                            i-
 Density of  acetone (pa)
                                                        a/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
i/
i/
Liquid level at nark
and/or container sealed
i/
v/
 Acetone rinse  container no.
 Acetone rinse  volume (Vaw)
                                                Lab no.
Acetone blank  residue concentration  (Ca)	
Wa = Ca Vaw  pa = (.O'C )  (211 ) (7?-?) - 	
Date and  time  of wt 2J?/? 3 h) 0 j 3C>    Gross wt_
Date and  time  of wt 2//[>/?3 £) QZ5O    Gross wt
                                                  .0(0
                                                             ng/g
                                                  A 7
                                                             mg
                                                       1H.2* -mg
                                                              'mg
                                                    /. 7
                              Average gross wt   /OQ  3 J(.->.
                                       Tare wt
                    Less acetone blank wt  (Wa)
       Weight  of particulate in acetone rinse
Filters
Stage    Filter No.
?6 o
                                                               mg
                                                              "
                                                               mg
                                                       • 1
Lab No.
                         C.T-3??
Gross,mg
    '•f
                                               Tare,  mg
             /3C-76
                                     130-3
                                                 130-3
                                                 I Yt>. 0
                          C '-
                                       .0
•3
 fc'V
 Backup
             Rl- - V3
                        C~-
                                                /
-------
S02 MANUAL TESTS
   C-24

-------
     PLANT
                           SULFUR  DIOXIDE ANALYTICAL DATA
                                  DATE
     SAMPLE LOCATION  /-
                      ..,-^^ -
                                  ANALYST
NORMALITY OF BARIUM PERCHLORATE    2
                                                  ^L ml  .irr^H  N
                                           3 & /.Q ml ifp%x'  N

Run
No.
-,
_c_ ^
2
3
4
5
6

Sample
No.
^_^^c^.
_, C^ (> / i
<^A - ?^23
£*>*_- £fl-|




Total
volume
of sample
	
'
£S^*
/0ZXO




Sampl e
aliquot
	 t^_ji_
*^
2o
7^>



Vol ume
1st
titration
--44
1 ' i
f2.ir
O -3



of titrant \
2nd
titration
4- ~)
/• LS
/2.3
o.?C



't» ml
Average
•+-&£:'-
T •
'3*?f
O'tLt*



^'
     Blank analysis  -  volume  of titrant    1st titration
                                          2nd titration
                                          Average 	
     2nd  titration  =  °'99  to  ^^ or lst titration ' 2nd ttfration = 0.2 ml
     Signature  of analyst
     Signature  of reviewer or  supervisor
                                         C-25

-------
PLANT
                      SULFUR DIOXIDE  ANALYTICAL DATA
                                       DATE
SAMPLE LOCATION
                                      ANALYST
                                            <4 ml ,00°; 7 N
NORMALITY OF BARIUM PERCHLORATE 2 £?<2<5"~ml 0Otf£ N <6o?7N

Run
No.
1
2
3
4
5
6
Sample
No.
M«k£0«
P£OZ- 1

-psoz- z-
p^o^-3>
"pS02-^
Total
volume
of sample
SW0.0/W
IfrZrO

too
/Oz>0
rcrr^>
3 ^C?/^m^ -ooc/k N

Sample
aliquot
x.o
^0

?.o
2.0
io

Volume of titrant Vt, ml
1st
titration
?o.?f
/.ir
/•7S~
3.?tT^
gf/<-
/.^r"
2nd
titration
2^,/
/C
t^ * f~)
/, ^"
^.%o
o.-<^
1.^
Average
^^.23
3pBfeS*V
J-T ^^V-'

5s. £^
5-.«
/.£^
Blank analysis - volume of titrant 1st titration ^-2^^.
2nd titration O, /
Average & . /*•>
2nd titration = 0>" to 1>01  or lst  titration  '  2nd  titration  = 0.2 ml
Signature of analys
Signature of reviewer or supervisor
                                   c-26

-------
                     SULFUR DIOXIDE ANALYTICAL DATA
PLANT
DATE
i/n i n    *
1//4/&
SAMPLE LOCATION
ANALYST
                                     1
     NORMALITY OF BARIUM PERCHLORATE   2
                                     3
         ml
         ml
         ml
            N.
            N
            N
Run
No.
1
2
3
4
5
6
Sample
No.
^02,-S-
$
(>•*




Average
r.t>
t-^>




Blank analysis - volume of titrant    1st  titration
                                    2nd  titration
                                    Average
2nd titration = °'99 to  1>01 or 1st titration - 2nd titration = 0.2 ml
Signature of analyst
Signature of reviewer or  supervisor
                                  C-27

-------
                               PEDCO ENVIRONMENTAL, INC.
                                                   1 1499 CHESTER ROAD
                                                 CINCINNATI. OHIO 45246
                                                       (513)782-4700
                                               TELECOPIER (513) 782-48O7
                      LABORATORY REPORT
                          U.S. EPA
                           ASARCO
                         PN: 3490-9
                        IPA Impingers
                       H2S04 Analysis
  Sample ID

  S02-BM-1
  PS02-1
  PS02-2
  PS02-4
  PS02-5
  PSO2-6
PEDCO No

 CT455
 CT456
 CT457
 CT458
 CT459
 CT460
                  Total Sample
                   Volume, ml

                      164
                       92
                       98
                      163
                      120
                      127
 H2S04,
Total mg

  0.12
  0.11
  0.16
  0.17
  0.26
  0.18
     Normality of  barium perchlorate -  0.0098425
     Analyst:

     Reviewer:
- 'J  //*':..^
                  Date of Analysis:  ^'tf-?

                  Date of Review:  ^_ 9-65
       IPA impinger 1-22-83 (CT482) and  2nd and 3rd impinger
  water 1-22-83  (CT483)  were not to be analyzed per M. Phillips,
                               BRANCH OFFICES
CHESTER TOWERS
                      DALLAS. TEXAS

                   KANSAS CITY. MISSOURI
                       COLUMBUS. OHIO

                    DURHAM. NORTH CAROLINA
                              C-28

-------
                                                LABORATORY REPORT
                                                U.S.  EPA - ASARCO
                                                    PN 3490-9
                                             Process Sample Analysis
Sample
I.D.
CW852
CW853
CW854
CW855
CW856
o CW857
NJ CW858
w CW859
CW860 .
CW860R3
CW861
CW862
CW863
CW864







Sample description
Test
Test
Test
Test
Test
Test
Test
Test
Test
Test
Test
Test
Test
Test
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
1
1
1
1
2
2
2
2
2
2
3
3
3
3
(1/19)
(1/19)
(1/19)
(1/19)
(1/20)
(1/20)
(1/20)
(1/20)
(1/20)
(1/20)
(1/22)
(1/22)
(1/22)
(1/22)
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
- Charge
79
79
79
79
80
80
80
80
80
80
81
81
81
81
- cleanup blow
- 2nd blow
- 3rd blow
- 4th blow
- cleanup
- 1st blow
- 2nd blow
- 3rd blow
- 4th blow
- 4th blow
- cleanup
- 3rd skim
- 4th skim
- 5th skim
CW865     Reverberatory matte - composite as  received
          from ASARCO
Sample
weight, g
0.4895
0.6165
0.5549
0.5300
0.5027
0.5182
0.5072
0.5062
0.5044
0.5222
0.5138
0.4992
0.5063
0.5058
Arsenic,
mg/g
0.91
1.50
1.31
1.77
0.72
1.74
2.18
1.50
1.30
1.30
1.89
1.18
1.36
2.37
Lead,
mg/g
47.77
35.00
44.98
29.45
28.54
10.56
16.37
27.62
23.47
23.28
6.83
36.56
22.15
19.42
% by
As
0.09
0.15
0.13
0.18
0.07
0.17
0.22
0.15
0.13
0.13
0.19
0.12
0.14
0.24
weight
Pb
4.8
3.5
4.5
2.9
2.9
1.1
1.6
2.8
2.3
2.3
0.7
3.6
2.2
1.9
0.4973
7.01
29.86
0.70    3.00
(continued)

-------
        PROCESS SAMPLE ANALYSIS (continued)
 i
u>
o
        Sample
         I.D.
        CW866
        CW867
        CW868
        CW869
        CW869R*
            Sample description
Gibraltar concentrations
Lornex concentrates
El Indio concentrates
Le Panto concentrates
Le Panto concentrates
         Replicate.
Sample Arsenic,
weight, g mg/g
0.2043 0.08
0.2200 0.80
0.2154 107.7
0.1993 111.3
0.2180 107.4
^/3_ f\
' ^: M/7 y/4f
Lead, % by weight
mg/g As Pb
0.39 0.008 0.05
0.32 0.08 0.03
0.90 10.8 0.09
1.30 11.1 0.13
1.34 10.7 0.13
7l<^<^
                                                          Date:  May 2, 19831
                                                                               T

-------
                    LABORATORY REPORT
                    U.S.  EPA - ASARCO
                        PN 3490-9
Arsenic and Trace Metals Analyses of Method 5-108 Samples

                         Arsenic
Test No.
Blank
PASM-1
PASM-2
PASM-3
r PATC-1
» *
H PATC-2
PATC-3

Blank
PASM-1
PASM-2
PASM-3
PATC-1
PATC-2
PATC-3
(continued)
Sample
I.D.
430/448
442/449
443/450
445/451
445/452
446/453
447/454

430/448
442/449
443/450
445/451
445/452
446/453
447/454

Acetone/Filter,
mg
1.3
17.2
17.3
4.8
24.5
26.2
11.3

<0.7
32.9
35.4
13.8
53.4
58.1
25.6

Sample
I.D.
479
461
462
463
464
465
466

479
461
462
463
464
465
466

NaOH probe
rinse, mg
0.007
1.4
1.0
0.047
1.3
1.0
0.12
Lead
<0.06
0.07
0.23
0.06
0.35
0.39
0.12

Sample
I.D.
480
467
468
469
470
471
472

480
467
468
469
470
471
472

Back-Half,
mg
0.006
3.0
8.9
0.16
3.2
33.4
3.3

<0.06
<0.06
<0.06
<0.06
<0.06
<0.06
<0.06


-------
Arsenic and Trace Metals Analyses of Method 5-108 Samples
                         Cadmium
Test No.
Blank
PASM-1
PASM-2
PASM-3
PATC-1
PATC-2
PATC-3
r
i
u>
to
Blank
PASM-1
PASM-2
PASM-3
PATC-1
PATC-2
PATC-3
(continued)
Sample
I.D.
430/448
442/449
443/450
445/451
445/452
446/453
447/454
430/448
442/449
443/450
445/451
445/452
446/453
447/454

Acetone/Filter,
mg
<0.001
0.64
0.33
0.06
0.91
0.58
0.123
<0.003
0.56
0.116
0.037
1.64
0.299
1.27

Sample
I.D.
479
461
462
463
464
465
466
479
461
462
463
464
465
466

NaOH probe
rinse, mg
<0.008
0.017
< 0.008
<0.008
0.028
0.016
<0.008
Selenium
< 0.0029
0.0042
0.0042
<0.0029
0.0235
0.0079
0.0042

Sample
I.D.
480
467
468
469
470
471
472
480
467
468
469
470
471
472

Back-Half,
mg
<0.008
< 0.008
<0.008
<0.008
< 0.008
< 0.008
<0.008
< 0.0029
2.90
0.0123
0.0260
2.58
0.0319
0.479


-------
n

u>
u>
                                     Arsenic and Trace Metals Analyses of Method 5-108 Samples


                                                             Antimony
Test No.
Blank
PASM-1
PASM-2
PASM-3
PATC-1
PATC-2
PATC-3

Blank
PASM-1
PASM-2
PASM-3
PATC-1
PATC-2
PATC-3

Sample
I.D.
430/448
442/449
443/450
445/451
445/452
446/453
447/454

430/448
442/449
443/450
445/451
445/452
446/453
447/454

Acetone/Fil
mg
<0.002
1.76
2.69
0.478
2.51
5.38
1.12

<0.002
0.581
0.719
0.695
1.383
1.909
0.747

ter, Sample
I.D.
479
461
462
463
464
465
466

479
461
462
463
464
465
466
Reviewed by:
NaOH probe
rinse, mg
< 0.0023
0.0029
0.0198
<0.0023
0.0141
0.0233
0.0029
Bismuth
<0.0013
<0.0013
0.0031
<0.0013
0.0016
0.0078
0.0013 ^
^ff( , .1
nftwk
Sample
I.D.
480
467
468
469
470
471
472

480
467
468
469
470
471
472
MJUI^
Back-Half,
mg
< 0.0023
0.0039
< 0.0023
< 0.0023
< 0.0023
< 0.0023
< 0.0023

<0.0013
<0.0013
< 0.0013
<0.0013
<0.0013
<0.0013
<0.0013

                                                 Date:  May 2, 198

-------
Matte Charge

PSMC-1
                                                LABORATORY  REPORT
                                                U.S.  EPA -  ASARCO
                                                    PN 3490-9
                              Particle Size Fraction  Trace Metal  Analytical  Results

                         Pb, mg         As, mg         Cd, mg         Sb,  mg         Bi,  mg
Se, mg
CT418/CT309
1st cut
CT310/CT312
2nd cut
CT313/CT317
3rd cut
o
i PAMC-2
*• CT421/CT336
1st cut
CT337/CT339
2nd cut
CT340/CT344
3rd cut
PSMC-3
CT424/CT363
1st cut
CT364/CT366
2nd cut
CT367/CT371
3rd cut
1.9

1.9

17.6



0.28

0.26

2.0


0.53

0.42

5.1

1.11

1.00

11.98



0.19

0.14

1.26


1.43

1.33

16.87

0.036

0.04

0.567



0.0045

0.0050

0.07


0.0082

0.0085

0.115

0.145

0.125

0.87



0.024

0.014

0.051


0.088

0.064

1.124

0.0359

0.0358

0.36



0.0093

0.0095

0.0609


0.0158

0.0135

0.135

0.0137

0.0078

0.0793



0.0026

0.0014

0.0136


0.0032

0.0021

0.0325

(continued)

-------
o
I
en
        (continued)
                                      Particle Size Fraction Trace Metal  Analytical  Results
                                 Pb, mg         As, mg         Cd, mg         Sb, mg         Bi, mg         Se, mg
        Matte Charge (cont'd)
PSCM-4
CT427/CT390
1st cut
CT391/CT383
2nd cut
CT354/CT398
3rd cut
PSCM-5
CT429/CT408
1st cut
CT409/CT411
2nd cut
CT412/CT416
3rd cut
Slag Skim Mode
PSS-1
CT418/CT318
1st cut
CT310/CT321
2nd cut
CT322/CT326
3rd cut
0.06
0.72
1.9
0.66
0.51
2.6
0.63
0.89
11.9
0.60
0.61
3.02
0.41
0.53
2.76
0.28
0.34
4.94
0.0064
0.0064
0.015
0.0074
0.0039
0.0091
0.0050
0.0062
0.040
0.056
0.083
0.144
0.057
0.04
0.12
0.08
0.085
0.324
0.0184
0.0195
0.0377
0.0146
0.0103
0.0273
0.0133
0.0189
0.4303
0.0034
0.0031
0.0066
0.0056
0.0028
0.0125
0.0147
0.04
5.76
        (continued)

-------
o
        (continued)
                                     Particle Size Fraction Trace Metal  Analytical  Results
                                Pb, mg         As, mg         Cd, mg         Sb, mg         Bi, mg         Se, mg
        Slag Skim Mode
(cont'd)
PSS-2
CT422/CT345
1st cut
CT346/CT348
2nd cut
CT349/CT353
3rd cut
PSS-3
CT425/CT372
1st cut
CT373/CT375
2nd cut
CT376/CT380
3rd cut
Blowing Mode
PSB-1
CT420/CT327
1st cut
CT328/CT331
2nd cut
CT332/CT335
3rd cut

0.75 0.36 0.0065 0.048 0.0191 0.0053
1.10 0.48 0.0094 0.079 0.0276 0.0055
16.0 4.58 0.127 0.65 0.478 0.0252
0.32 0.17 0.0019 0.022 0.0081 0.0020
0.45 0.19 0.0029 0.02 0.0093 0.0016
11.7 3.25 0.049 0.389 0.298 0.0329
1.36 0.39 0.0072 0.22 0.0202 0.0158
0.1 0.08 <0.0013 0.004 0.0025 <0.0012
0.7 0.65 0.011 0.042 0.0142 0.0045
        (continued)

-------
(continued)
                              Particle  Size Fraction  Trace  Metal  Analytical Results
                         Pb,  mg         As, mg          Cd,  mg          Sb, mg          Bi, mg
Blowing Mode (cont'd)
PSB-2
Se, mg



0
1
U)
CT-423/CT354
1st cut
CT355/CT358
2nd cut
CT359/CT363
3rd cut

1.5 1.12 0.012 0.199 0.0364
0.53 1.62 0.0074 0.072 0.0189
4.7 15.04 0.0061 1.038 0.171
, /
Reviewed byt*X/ / £ ^ //-r •*<--< 	
May 2, 1983 J
0.0108
<0.0012
0.0023



-------
            APPENDIX D




SAMPLING AND ANALYTICAL PROCEDURES
                D-l

-------
               SAMPLING AND ANALYTICAL PROCEDURES


     This section describes the test methods, sampling equipment,

and analytical techniques used during this test program.


SAMPLING METHOD FOR THE DETERMINATION OF PARTICULATE AND ARSENIC
EMISSIONS

     The following method was used during this test program.

Sampling procedures followed those described in Methods 5 and

108.*  Tests were conducted to determine filterable particulate,

particulate arsenic, and gaseous arsenic emissions using a single

sampling train.

     During each converter cycle two separate particulate/arsenic

sampling trains were run.  One of the sampling trains was oper-

ated continuously during the converter cycle, except when the

converter was idle.  The second sampling train was run only when

the primary hooding system had been removed  (charging, slagging,

and pouring).  A description of the sampling and analytical

procedures is provided below.

Sampling Apparatus

     The sampling train used in these tests met design specifica-

tions established by the U.S. EPA and was assembled by PEDCo

personnel.  It consisted of:
*
 EPA Method 108 has not been proposed and is presently in draft
 form.
                              D-2

-------
     Nozzle - Stainless steel (316) with sharp, tapered leading
     edge and accurately measured round opening.

     Probe - Borosilicate glass with a heating system capable of
     maintaining a minimum gas temperature of 250°F at the exit
     and during sampling.

     Pitot Tube - Type S pitot tube that met all geometry stan-
     dards and was attached to the probe to monitor stack gas
     velocity.

     Filter Holder - Pyrex glass with heating system capable of
     maintaining a filter temperature of approximately 250°F.

     Draft Gauge - An inclined manometer made by Dwyer with a
     readability of 0.01 inches H_O in the 0 to 10 inch range was
     used.

     Impingers - Six impingers connected in series with glass
     ball joints.  The first, third, fourth, fifth, and sixth
     impingers were the Greenburgh-Smith design, modified by
     replacing the tip with a 1/2 inch I.D. glass tube extending
     to 1/2 inch from the bottom of the flask.  The second
     impinger was a Greenburg-Smith design with the standard tip.

     Metering System - Vacuum gauge, leak-free pump, thermometers
     capable of measuring temperature to within 5°F, dry gas
     meter with 2 percent accuracy, and related equipment, to
     maintain an isokinetic sampling rate and to determine sample
     volume.  The dry gas meter is made by Rockwell and the fiber
     vane pump is made by Cast.

     Barometer - Aneroid type to measure atmospheric pressures to
     ±0.1 inch Hg.

     Thermocouple - Type K thermocouple capable of measuring
     stack gas temperature within 2 percent.

Sampling Procedure

     After selecting the sampling site and the minimum number of

traverse points, the stack pressure, temperature, moisture, and

range of velocity head were measured according to procedures

described in the Federal Register.*
 40 CFR 60, Appendix A, Reference Methods 1 through 4, July 1,
 1982.
                              D-3

-------
     For each sampling train approximately 300 grains of silica


gel was weighed and placed in a sealed impinger prior to each


test.  Glass fiber filters* (3-in. diameter)  were desiccated for


at least 24 hours and weighed to the nearest 0.1 mg on an ana-


lytical balance.  One hundred and fifty ml of deionized, dis-


tilled water was placed in each of the first two impingers, and


two hundred ml of 10 percent H202 was placed in the third,


fourth, and fifth impingers.  The train was set up with the probe


as shown in Figure D-l.  The sampling train was leak checked at


the sampling site prior to each test run by plugging the inlet to


the nozzle and pulling a 15 inch Hg vacuum, and at the conclusion


of the test by plugging the inlet to the nozzle and pulling a


vacuum equal to the highest vacuum reached during the test run.


     The pitot tube and lines were leak checked at the test site


prior to each test run and at the conclusion of each test run.


The check was made by blowing into the impact opening of the


pitot tube until 3 or more inches of water was recorded on the


manometer and then capping the impact opening and holding it for


15 seconds to assure it is leak free.  The static presssure side


of the pitot tube was leak checked using the same procedure,


except suction was used to obtain the 3 in. H~0 manometer read-


ing.  Crushed ice was placed around the impingers to keep the


temperature of the gases leaving the last impinger at 68°F or


less.  The nozzle size was selected to maintain the isokinetic


sampling rate below 1.0 cfm.
*
 Whatman Reeve Angel 934AH.
                              D-4

-------
o
 I
                  THERMOMETER
                    SENSOR
                            STACK
                            MALL
                 r
            REVERSE TYPE
             PI TOT TUBE
 THERMOMETER
                                      PROBE
                                                                                                  THERMOMETER
                                                                            IMPINGERS (6)
HEATED
FILTER
HOLDER
                                        PI TOT
                                      MANOMETER
                                                          150
                                                          H,0
           0 ml_V"   ?00 ml.
^          ?00 9 J
                                                                THERMOMETERS
                                          SILICA
                                          GEL
                                 BYPASS
                                 VALVE
                    VACUUM
                    GAUGE
                                                   ORUICE
                                                  MANOMETER
                                                                               AIR TIGHT
                                                                                  PUW*
                                                                                                               VACUUM
                                                                                                                LINE
                                       Figure  D-l.   Participate and arsenic  sampling  train.

-------
     The particulate/arsenic sampling train which was operated

continuously during the converter cycle was sampled across the

duct using 6 sampling points on each traverse for a total of 12

sampling points.  The length of testing each sampling point

varied depending on the length of the converter cycle.  The

particulate/arsenic train operated during the specific process

operating modes was run at a single point of average velocity.

     During sampling, stack gas and sampling train data were

recorded every 10 minutes and when significant changes in stack

flow condition occurred.  Isokinetic sampling rates were set

throughout the sampling period with the aid of a nomograph or

calculator.  All sampling data were recorded on the Particulate

Field Data Sheet.

Sample Recovery Procedure

     The sampling train was moved carefully from the test site to

an office provided by ASARCO for a cleanup area.  The weight of

each impinger was determined prior to recovery for moisture

determination.  Sample fractions were recovered as follows:

     Container No. 1 - The filter was removed from its holder and
     placed in a petri dish and the petri dish was sealed.

     Container No. 2 - Loose particulate and acetone washings
     from all sample-exposed surfaces prior to the filter were
     placed in a polyethylene container.  Particulate was removed
     from the probe with the aid of a brush and acetone rinsing
     and added to the same polyethylene container.  The liquid
     level was marked and the container was sealed.

     Container No. 3 - After the probe and all sample-exposed
     surfaces prior to the filter were rinsed with acetone,
     additional rinses with 0.1 N NaOH were performed, placed in
     a polyethylene container, sealed, and labeled.  The liquid
     level was marked after the container was sealed.  No more
                               D-6

-------
     than 150 ml of 0.1 N NaOH was used (maximum volume in
     Container No. 3, 150 ml).

     Container No. 4 - The contents of the first two impingers
     were transferred to a polyethylene container.  Each impinger
     was rinsed twice with 30 ml of 0.1 N NaOH and the rinse
     added to the container.  The back-half of the filter holder
     and connecting glassware were rinsed twice with 0.1 N NaOH
     and the rinse added to the container.  The container was
     then sealed, labeled, the liquid level marked, and then
     stored.  No more than a total of 150 ml of 0.1 N NaOH was
     used for all the rinses  (maximum volume in Container No. 4,
     500 ml).

     Container No. 5 - The contents of the third, fourth, and
     fifth impingers were transferred to a polyethylene con-
     tainer.  Each impinger was rinsed twice with deionized,
     distilled water, the connecting glassware rinsed twice with
     deionized, distilled water, and the rinses added to the
     container.  The container was sealed, labeled, the liquid
     level marked, and then stored.  No more than a total of 250
     ml of deionized, distilled water was used for all rinses
     (maximum volume in Container No. 5, 900 ml).

     Container No. 6 - A minimum of 500 ml of the acetone was
     taken for blank analysis.  The blank was obtained and
     treated in the same manner as the rinse.

     Container No. 7 - A minimum of 500 ml of deionized, dis-
     tilled water was taken for blank analysis.  The blank was
     obtained and treated in the same manner as the rinse.

     Container No. 8 - A minimum of 500 ml of H«0_ was taken for
     blank analysis.  The blank was obtained and treated in the
     same manner as the rinse.

     Container No. 9 - A minimum of 500 ml of 0.1 N NaOH was
     taken for blank analysis.  The blank was obtained and
     treated in the same manner as the rinse.

     The silica gel from the sixth impinger was weighed and this

value was recorded on the Sample Recovery and Integrity Data

Sheet with other pertinent data.

     After recovery of all containers the entire train except for

the silica gel impinger was rinsed with deionized, distilled

water to remove any residual NaOH prior to preparation for the

next run.  This rinse was discarded.
                               D-7

-------
Analytical Procedures

     The following procedures were used and followed the methods

described in EPA Methods 5 and 108.

     Container No. 1 - The filter and any loose particulate were
     desiccated for 24 hours to a constant weight and weighed to
     the nearest 0.1 mg.  After a final weight had been obtained
     the filter was digested in a 150 ml beaker using 0.1 N NaOH
     followed by concentrated HNO...  The solution was filtered.
     The filtrate was boiled and evaporated to dryness.  Nitric
     acid was then added and the sample diluted before analysis
     by atomic absorption spectrophotometry.   If any solids
     remained on the filter, the filter was digested in a PARR
     acid digestion bomb using HNO^ and HF prior to analysis.

     Container No. 2 - The acetone washings of the nozzle probe
     and front half of the filter holder were transferred to a
     tared glass beaker, evaporated to dryness at ambient temper-
     ature and pressure, desiccated for 24 hours to a constant
     weight, and weighed to the nearest 0.1 mg.  The residue was
     combined with the contents of Container No. 1 and analyzed
     for arsenic.

     Container No. 3 - The 0.1 N NaOH rinses of the probes and
     exposed surfaces were diluted to 200 ml and a 50 ml aliquot
     was removed and digested using HNCu before arsenic analysis.
     Solids were combined with the contents of Container No. 1
     and analyzed for arsenic.

     Container No. 4 - The contents were diluted to 500 ml.  An
     aliquot was taken and digested with HNO^ before final
     dilution and atomic absorption analysis for arsenic.

     Container No. 5 - The contents were diluted to 1 liter.  An
     aliquot of this solution was removed and titrated with NaOH
     to a phenolphthalein endpoint for the determination of S0_.

     The term "constant weight" means a difference of no more

than 0.5 mg or 1 percent of total weight less tare weight,

whichever is greater between two consecutive readings, with no

less than 6 hours of desiccation between weighings.  All analyt-

ical data are recorded on the Analytical Data Sheet and appro-

priate Blank Data Sheet.
                               D-8

-------
     All blanks were digested and analyzed using the same proce-



dures as the corresponding sample fractions.



     The samples were analyzed on an atomic absorption spec-




trophotometer.  The solutions were first analyzed using the flame



techniques as outlined in EPA Method 108.  However, if the



samples were below the flame detection limit, the furnace tech-




nique (heated graphite furnace) was employed.  Possible matrix



effects for either method were checked using the "Method of



Additions".



     During the test series the EPA (Office of Air Quality



Planning and Standards, Emission Measurement Branch) collected



samples under an associated test program which PEDCo digested and



split with ASARCO for arsenic analysis.  PEDCo analyzed the one



portion of the samples following the procedures outlined in EPA



Method 108.  ASARCO analyzed its samples using a colorimetric



method and atomic absorption.  After the results of these anal-



yses had been compared and EPA had decided on the most accurate



analytical method, PEDCo analyzed the samples collected during



the test series for arsenic following the instructions of EPA.






PARTICLE SIZE AND TRACE METAL SAMPLING



     During each test run the same particle sizing methods were



used to collect samples during the various segments of the



converter cycle.  An Andersen Mark III impactor and cyclone



precutter combination were utilized to collect a single composite



particle size sample during the slag blowing, finish blowing, and
                              D-9

-------
silica charging segments of the converter cycle.  Since about 80

percent of the total converter cycle was comprised of these

modes, the majority of the test runs were conducted during these

segments.

     Andersen Mark III impactors were also used to collect

samples during the other selected converter modes, charging

(matte and cold dope addition) and skimming (slag skimming and

blister pouring).   The particle size tests conducted during these

specific operating modes were run during the entire operation

(from when it was initiated until it was completed as long as the

flow rate was maintained in the high mode).  A description of the

sampling and analytical procedures is provided below.

Sampling Apparatus

     The source sampling train used in these tests met the design

specifications established by the U.S. EPA.  It consisted of:

     Nozzle - Stainless steel (316) with sharp, tapered leading
     edge and accurately measured round opening.

     Metering System - Vacuum gauge, leak-free pump, thermometers
     capable of measuring temperature to within 5°F, dry gas
     meter with 2 percent accuracy, and related equipment, to
     maintain an isokinetic sampling rate and to determine sample
     volume.  The dry gas meter is made by Rockwell and the fiber
     vane pump is made by Cast.

     Condenser - Capable of maintaining a temperature of 68°F
     with an attached thermometer to monitor temperature.

     Impactors - A 15-ym cutpoint cyclone precutter attached to
     the Andersen Mark III impactor with eight stages plus the
     backup filter was used to test over the blowing and silica
     charging segments of the converter cycle.  An Andersen Mark
     III impactor with eight stages plus the backup filter was
     also used to test during the other selected converter modes.
                               D-10

-------
Sampling Procedure



     After a sampling site was selected, the stack pressure,



temperature, and moisture content were measured according to



procedures described in the Federal Register.*



     The sampling trains were assembled as shown in Figures D-2



and D-3.  They were checked for leaks at the sampling site before



each test run by plugging the inlet to the impactor and pulling



10-in.Hg vacuum.  Once the desired vacuum was reached, the



leakage rate was checked at the dry gas meter for 1 minute.  If



the leak rate was less than 0.02 cfm, the sampling trains were



used to obtain the samples.  Excessive leaks were corrected prior



to sampling.



     The particle size sampling runs conducted during the se-



lected converter modes were run at a single point of average



velocity.  As expected the emissions generated by the various



operating modes varied throughout the converter cycle.  During



the testing period none of the operating modes  (blowing, skim-



ming, or charging) generated enough emissions during a single



segment to collect enough particulate for a particle size test.



It was therefore necessary to test the operating modes more than



once with the same impactor to collect the proper amount of



sample.



     During sampling, stack gas and sampling train data were



recorded at intervals depending on the length of the operating
 40 CFR 60, Appendix A, Reference Methods 1 through 4, July 1981.
                               D-ll

-------
                                     METER BOX
         PROBE TUBE
                                                15 um CYCLONE
                                                  PRECUTTER
Figure D-2.   Andersen  Mark  III  impactor sampling train
             shown  with  cyclone precutter.
                          D-i;

-------
            PROBE TUBE
                                        METER BOX
                                     IMPACTOR
Figure D-3.   Particle  size  distribution sampling train.
                       D-13

-------
mode being tested and when significant changes in stack flow



conditions occurred.  The isokinetic sampling rate was set



initially, and a constant sampling rate was maintained throughout



the sampling period.  All sampling data were recorded on an



Emission Testing Field Data Sheet.



Sample Recovery Procedure



     After completion of the test, the impactor assembly was



removed from the probe and carefully moved to the office provided



by ASARCO as a cleanup area with the impactor maintained in an



upright position.  Each filter was removed from its holder and



carefully placed in its respective container.  Any particulate



collected on the surface of the collection plates directly above



and below the filter media was brushed into the same container



with the filter media.  Prior to the first collection stage,



loose particulate from all sample-exposed surfaces of the im-



pactor were brushed and then rinsed with acetone into a container



(front rinse).   For the impactor runs using the cyclone precut-



ter, the particulate caught in the cyclone precutter was brushed



and then rinsed with the acetone into the same container as the



front rinse, sealed and labeled.



Analytical Procedures



     Each sample fraction and any loose particulate matter from



its sample container were placed into a tared glass weighing



dish, desiccated for 24 hours to a constant weight, and weighed



to the nearest 0.1 mg.  The acetone washings were transferred to



a tared beaker, evaporated to dryness at room temperature and
                              D-14

-------
pressure, desiccated to a constant weight, and weighed to the

nearest 0.1 mg.

     The term "constant weight" means a difference of no more

than 0.5 mg between two consecutive readings, or 1 percent of

total weight less tare weight, whichever is greater, with no less

than 6 hours of desiccation between weighings.

     Upon completion of the gravimetric analysis the samples were

analyzed by atomic absorption spectrometry (AA) to determine the

concentrations of selected trace metals (arsenic, cadmium, lead,

antimony, selenium, and bismuth) in the gas stream.  A Perkin

Elmer Model 550 spectrophotometer was used to analyze the samples

for the selected trace metals.


SAMPLING METHOD FOR DETERMINATION OF SULFUR DIOXIDE EMISSIONS BY
MANUAL TESTING

     The following method was used in this test program.  Sam-

pling procedures followed those described in Method 6 of the

Federal Register.*

Samping Apparatus

     The SO. sampling train used in this test series met design

specifications established by the U.S. EPA and was assembled by

PEDCo personnel.  It consisted of:

     Probe - Borosilicate glass with a heating system capable of
     maintaining a minimum gas temperature of 250°F at the exit
     end.  A plug of glass wool was placed in the end of the
     probe to remove particulate matter.
 40 CFR 60, Appendix A, Reference Method 6, July 1981.
                               D-15

-------
     Impingers - Four impingers connected in series with glass
     ball joints.  The first and third impingers are of the
     Greenburg-Smith design.  The second and fourth are modified
     by replacing the tip with a 1/2 inch I.D. glass tube ex-
     tending to within 1/2 inch from the bottom of the flask.
     Glass wool was placed in the first U-joint to prevent
     sulfuric acid mist carryover.

     Metering System - Vacuum gauge, leak-free pump, thermometers
     capable of measuring temperature to within 5°F, dry gas
     meter with 2 percent accuracy, and related equipment, to
     maintain a constant sampling rate and to determine total
     sample volume.

     Barometer - Aneroid type to measure atmospheric pressure to
     +0.1 inch Hg.

Sample Reagents

     Water - Deionized, distilled to conform to ASTM specifica-
     tions D1193-74, Type 3.

     Isopropanol, 80%

     Hydrogen Peroxide, 10%

     Potassium Iodide Solution, 10%

Analytical Reagents

     Water - Deionized, distilled.

     Isopropanol, 80%

     Isopropanol, 100%

     Thorin Indicator

     Barium Perchlorate Solution, 0.0100 N

Sampling Procedure

     After selecting the sampling site and the number of traverse

points necessary, the stack pressure, temperature, moisture, and

range of velocity head were measured according to procedures

described in the Federal Register.*
*
 40 CFR 60, Appendix A, Reference Methods 1 through 4, July 1981.
                              D-16

-------
     One sampling point was chosen and the train was assembled as



follows:  100 ml of 80 percent isopropanol in the first impinger,



100 ml of 10 percent hydrogen peroxide in both the second and



third impingers, and 200 g of silica gel in the fourth impinger.



A portion of each reagent was retained for use as a blank.  The



train was assembled as shown in Figure D-4.  The sampling train



was leak checked at the sampling site before and after each test



by plugging the inlet to the first impinger and pulling a 10



in.Hg vacuum.  All leaks were corrected before sampling com-



menced.  The probe heater setting was adjusted during sampling to



prevent any visible condensation.  Crushed ice was placed around



the impingers and more ice was added during the test to keep the



temperature of the gases leaving the last impinger at 68°F or



less.



     A total of 7 manual SO,, runs were conducted during the



testing period.  For each run, the data was recorded at 5 minute



intervals with a total test run of at least 20 minutes.  During



the test period at least one run was conducted during each seg-



ment of the converter cycle except for the copper pour, silica



charging, and finish blow modes.



     At the completion of each test, the probe was removed from



the stack and the train was purged for 15 minutes by drawing



ambient air through the system.



Sample Recovery



     The contents of the first impinger were measured and placed



in a leak free polyethylene container.  The first impinger was
                              D-17

-------
   HEATED PROBE
   (END PACKED
   WITH GLASS WOOL)
               STACK WALL
o
i
M
00
                          IMPINGERS CONTENT

                    1.  100 ml 80% ISOPROPANOL
                    2.  100 ml 10% H202
                    3.  100 ml 10% H?02
                    4.  200 g SILICA GEL
IMPINGERS
                                                                                                  THERMOMETER
                                                                         THERMOMETERS
        BYPASS
        VALVE
                                                                                                                    VACUUM
                                                                                                                    LINE
VACUUM
GAUGE
                                                               ^       /DRY   \
                                                                   I       I   6AS    I
                                                                   U        ^
                                                                           \	/   •
                                          Figure D-4.  Manual method S09  sampling  train.
               AIR TIGHT
                 PUMP

-------
then rinsed with 80 percent isopropanol and this rinse was added



to the same polyethylene container.  The contents of the second



and third impingers were measured and placed in a leak free



polyethylene container.  The second and third impingers were then



rinsed with distilled, deionized water and this rinse was added



to the same polyethylene container.  Both containers were sealed



and identified, and the liquid levels were marked.



Analytical Procedures



     The SO- analysis was performed on site in the mobile labora-



tory.  The volume of each sample was recorded and diluted to 1000



ml with deionized, distilled water.  A 20 ml aliquot of this



solution was pipetted into a 250 ml Erlenmeyer flask.  Eighty ml



of 100 percent isopropanol and two to four drops of thorin indi-



cator were added.  The solution was titrated to a pink end point



using 0.0100 N barium perchlorate.  A blank was titrated in the



same manner as the samples.





SAMPLING METHOD FOR THE DETERMINATION OF SO- BY THE CEM



     A continuous extractive S0_ monitoring system was assembled



on site.  This system included a sample interface designed to



provide the conditioned sampled gas or a selected calibration gas



to the Thermo Electron Model 40 Pulse Fluorescence S0» Analyzer.



A diagram showing the important features of this system is shown



in Figure D-5.



Equipment Sample Interface



     The sample was withdrawn from the stack through an unheated



stainless steel probe at a representative sampling point.  The
                                D-19

-------




























































CAL GAS T"? Cf~fC






t
1
pc
TEFLON CAL GAS LINE c/
1/4 1n. O.D. c c
i



l


APPROX. 50 ft ^
I
NEEDLE
VALVE





CYLINDERS M M M
NEEDLE VALVE;




>
>



DETECTION
Y CHAMBER


.-jJ^QjNt
Lyl ^3-VM
BALSTON
COALESING
a .-' ' FILTER

T/
SAMPLE LINE 1/4
y O.D.
RUBBER HOSE TO
IOBE - STACK
8 1n. HALL
. TUBE
IEATED
f VALVE



'///////// L °
/////////. P| ATPOPM
in.
TEFLON

PROTECT SAMPLE LINES
HICUBE VAN


MANOMETER
=
A.
3-WAY
VALVE
\
r(( (PMt( d*
l V V V ' ' ' ! V \|
WflMpT J 1
IMHh.J^
METER

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LIGHT
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«



i~4| •*•
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^
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- — ^— —
' PERMATION
DRYER



-------
sampling gas passed through an unheated coalescing filter to



remove particulate matter and moisture droplets, and then into



the Teflon sample line for transport to the analyzer.  The sample



line pressure was indicated on the manometer placed just prior to



the analyzer.



     Calibration gas was introduced at two points in the sample



line.  A three-way valve placed before the sample line manometer



was used to inject gas into the sample line for routine calibra-



tion.  (The manometer was observed and the flow of calibration



gas was regulated in order to maintain a pressure consistent with



that of the sample gas.)   A second three-way valve, placed



between the sampling probe and the coalescing filter, was used



for system integrity checks.



Analyzer



     The Thermo-Electron Model 40 SO_ Analyzer operated on the



principle of pulsed fluorescence.  In the detection chamber the



sample was exposed to a short burst of ultraviolet light.  This



excited the SO,, molecules which then fluoresced at a character-



istic wavelength in the range of 190 nm to 230 nm.  The emitted



light was detected by a photomultiplier tube and this signal was



converted to S0_ concentration.



     The Model 40 contained an internal pump, pressure gauge, and



rotameter and permeation dryer prior to the detection chamber.



The pump provided the pressure differentiation for the sample



acquisition as well as the increase in pressure required, for the



operation of the permeation dryer.  The rotameter monitors sample
                               D-21

-------
flow and the pressure gauge indicates sample pressure at the



inlet of the dryer.



     After leaving the dryer and passing through the detection



chamber the sample stream was expanded across a pressure regula-



tor.  This dried and expanded exhaust gas now at ambient pressure



was passed through the permeation dryer on the opposite side of



the membrane with respect to the incoming sample.  This provides



the pressure differentiation for the operation of the permeation



dryer, and carried the moisture transferred across the membrane



to the exhaust.



Calibration



     The analyzer was calibrated during the initial setup period



using commercial standards with a guaranteed analysis ±2 percent.



Triplicate injections of each standard were made and the average



value was calcualted.  For each range three standards were used



to plot a calibration curve.  In this manner, instrument linear-



ity was demonstrated for the following ranges, 0 to 100 ppm, SO-;



0 to 1000 ppm, S02; and 0 to 5000 ppm, S02.



     During these calibrations the gas was introduced at the



three-way valve just prior to the manometer.  The calibration gas



pressure and flow rate were carefully adjusted in order to main-



tain a pressure consistent with that pressure observed when



sampling.



     A daily calibration was performed by injecting the appro-



priate span calibration gas.  If the instrument showed more than



10 percent drift, a complete 3 point calibration was conducted.
                               D-2?

-------
     A daily sample line integrity check was conducted by intro-



ducing a calibration gas at the three-way valve located at the



end of the probe.  This flow was maintained until a stable chart



trace was obtained.  This value was compared to the appropriate




calibration curve to insure that the sample interface did not



degrade the sample.  Agreement within ±5 percent was considered




acceptable.



Data Collection



     The SO- monitoring system was operated on a continual basis



during the entire testing period.  The SO- analyzer output was



recorded on a Heath Schlumberger strip chart recorder at a con-



stant rate of 0.05 inches per minute.  The data were identified



by noting the time (military), the date, and the run number on



the strip chart at regular intervals.  Sample interface and



analyzer operating parameters such as sample line pressure,



sample flow rate, and internal analyzer pressure were noted in



separate CEM status logs.



     The collected data were manually reduced for maximum peak



height, peak width at one-half peak height, and peak base using



and engineering scale with 50 divisions per inch.  The peak



height was multiplied by the daily calibration response factor to



determine the maximum SO^ concentration.  This value was multi-



plied by the ratio of peak width at one-half height to the peak



base to determine the average S0_ concentration during each



event.  The average SO- concentration, the peak base and the
                               D-23

-------
average stack velocities were used to calculate the mass emission

rate of S02 in terms of pounds of SO. captured per event.

     The SO- reduction was difficult due to the extremely abrupt

nature of the emission episodes.  The output signal from the

analyzer was recorded on a strip chart recorder.  The tracer were

very sharp and frequently distorted peaks.  The conventional

method of data reduction, relating concentration directly to the

average chart response over a selected time period was not appli-

cable for this situation.  It was necessary to integrate the area

under each peak in order to determine the amount of S02 captured

by the air curtain for any given period.

     The actual data reduction was carried out in five steps as

follows:

          Peak identification
          Peak measurement
          Area integration
          Calculation of SO- concentration and emission rates
          Formulation of emission factors

     The peak identification was accomplished by comparing the

notes made by the CEM operator and the PEDCo testing coordinator

to the events recorded on the strip chart.  The ASARCO No. 4

converter operating logs and the No. 4 converter blower air

charts were then compared to the events identified by PEDCo.

Once the four sources were synchronized they were in reasonably

good agreement on the number and duration of events.  The ASARCO

logs and charts were then used to label the events which occurred

during the unmanned periods of CEM operation.
                               D-24

-------
     Peak measurement was performed manually utilizing an engi-



neering scale with 50 divisions per inch.  The strip chart trace



was arbitrarily subdivided into uniform geometric shapes that



most nearly approximated the shape of the trace.  Each shape was



then measured and the height, width at one-half height, and base



were recorded on the strip chart.



     The area integration simply calculated the area of the



shapes for each identified event.  Most events consisted of a



single sharp peak and were approximated by an isoceles triangle.



Integration of the distorted peaks however required the calcula-



tion and summation of a combination of rectangles and triangles.



The maximum S0_ concentration was calculated by multiplying the



height by the calibrated chart response factor.  The average S02



concentration was calculated by dividing the total area by the



summed based for each event and then multiplying by the response



factor.  The average S0~ concentration was multiplied by the



average stack flow rate to determine the SO  emission rate in



Ib/h.  (The average stack flow rates determined for the SF,



tracer study were used.)  The pounds of SO- captured per event



was then calculated from the emission rates and the event dura-



tion.



     The emission factor development was carried out in two



separate approaches.  First the events for each cycle were



grouped into six modes.  The matte charge, slag skim, and copper



pour modes are explanatory.  The copper slag skims, which were



carried out just prior to the final copper pour, were included
                               D-25

-------
with the copper pour.  The cold addition mode included all mate-



rial additions other than copper matte.  The blow/standby mode



includes the converter blows and the periods when the converter



was idle.  Long periods of converter standby due to weather holds



or plant repairs were not included unless measurable emissions



occurred during that time.  The converter roll mode is required



to account for the large SO,, emissions which occurred as the



primary hood was raised or lowered before and after a converter



blow.  The emission episodes were highly variable in nature and



appear to be largely dependent on the converter operators' con-



trol over the tuyere lines and converter angle.  As a rule, any



large narrow peak which preceeded or followed a converter blow



was labeled and evaluated as a converter roll.



     Occasionally the peaks from two events were superimposed.



Most commonly this occurred when a slag skim closely followed a



converter roll out.  These double events were treated as a single



event.  The average values of all similar events for each cycle



and mode were calculated.  Emission factors were calculated based



on this average and the total tons of copper blister produced per



cycle.





HOOD CAPTURE EFFICIENCY USING A TRACER GAS



     The following procedures were employed to quantify hood



capture efficiency using a tracer gas.



Injection and Sample Collection



     Injection points were selected so as to yield multiple



traverse planes in the area above the converter and also at
                               D-26

-------
selected points near the converter mid-line to characterize



control area capture efficiency.



     SF, was injected into the controlled area of the air curtain



at a constant rate.  Figure D-6 illustrates the equipment used to



inject the SF, at the selected injection points.  A constant



pressure was maintained on the limiting orifice to ensure a



constant injection flow rate.  The injection system was cali-



brated prior to and after each sustained injection by using a



bubble meter.  SF, injection rates were determined based on the



preliminary test results.  An injection rate of 40-50 cc/min was



employed.  Also, the temperature at each injection point was



monitored during the injection of SF, to ensure that decomposi-



tion was avoided.  The tracer was injected over a selected time



period or operation mode as required.



     Single point samples of the secondary hood flue gas were



collected at the downstream sampling location.  Samples were



obtained by pulling a constant rate at Traverse Point No. 3 in



exhaust duct into a leak-free 15 liter Tedlar bag.  Samples were



collected over a selected time period or operational mode as



required.  Figure D-7 shows the sampling train used to collect



the samples.  The sample bags were transferred to the on-site



laboratory for immediate analysis.



Analytical Procedure



     SF, analysis was performed using a Perkin-Elmer Model 3920



gas chromatograph equipped with a Ni-63 electron capture detector
                               D-27

-------
to
00
                       ^°
                              PRESSURE REGULATOR

                                   TEFLON SAMPLE LINE
          I
CYLINDER
 OF SF,
\
                LIMITING
                ORIFICE
                                                 THERMOCOUPLE
                                                  LEAD WIRE
                                   DIGITAL
                                   READOUT
  INJECTION PROBE
(3/8  1n. STAINLESS
     TUBING)
                                                                        THERMOCOUPLE
                                            Figure D-6.   SFg injection apparatus,

-------
                                                                                     STAINLESS
                                                                                    STEEL PROBE
f^ ^
LEAK FREE
TEDLAR BAG
A
M
;
FLOW CONTROL
fl VALVE
tJ& O
1 *• y
-• Ten nu i turn
                                                                             TEFLON
                                                                           SAMPLE  LINE
o

M
VD
DIAPHRAM PUMP
                                               Figure D-7.  SFg sampling train.

-------
and a Valco gas sampling valve with a 1 ml sampling loop.  Oper-



ating conditions were 95 percent Argon, 5 percent methane (P-5)



carrier gas (120 ml/min), 200°C injector and oven heated to



100°C, and detector heated to 275°C with the interface at 250°C.



The analytical column was an 8 ft long by 1/8 in. diameter nickel



tube packed with 70/80 mesh molecular sieve 5A.  All sampling



lines and connectors were Teflon or stainless steel.



     An exponential dilution system was used in constructing



calibration curves.  Equipment required for the system calibra-



tion included vacuum pump, a bubble flow meter, a magnetic



stirrer and stirbars, a Pyrex 1 liter round bottom flask, a tank



of zero grade nitrogen, and miscellaneous glass and Teflon tubes



and fittings.



     The electron capture detector has a linear response to


                                         -7          -9
concentrations of SF, ranging from 1 x 10   to 1 x 10  .  The



minimum detectable level of 5 x 10    is not in the linear re-



sponse range with the argon/methane carrier.  An exponential



dilution system (as shown in Figure D-8) was used to prepare



standards over this concentration range.  A 1 liter round bot-



tomed flask was used as a mixing chamber with a magnetically



driven stirrer to assure good agitation.  Zero nitrogen flowed



through the system at a constant rate.  A known amount of gaseous



SF, was then injected into the flask and the time recorded.  The



concentration of SF, in the flask at any time was then calculated



from the equation:
                               D-30

-------
                                         SAMPLE
                                          LOOP
                             EXCESS
                             FLOW
                             VENT,,
            SAMPLING
            VALVE

  ZERO
NITROGEN
             DILUTION
             FLASK
                        O
PERKIN-ELMER
     GAS
CHROMATOGRAPH
                     MAGNETIC
                      STIRRER
                    Figure  D-8.  Expontential dilution system.
                                  FINE
                                METERING
                                  VALVE
                                   D-31

-------
where C  is the initial concentration of SF, in the flask, N is
       O                                   b


the number of gas changes, and e is a constant 2.7183.  Calibra-



tions were performed daily and took approximately 2 hours to



generate the calibration curve.



     In use, instrument response (peak height) was plotted



against calculated concentration of log-log paper to obtain



calibration curves.  Actual sample concentrations were then found



by comparing responses to the curve, as a check, calculated from



the slope of the curve and sample response.



     After the daily calibrations were completed, samples were



analyzed approximately every 5 minutes.
                              D-32

-------
                    OPACITY TEST METHODOLOGY






     The Lear Siegler Model RM4 transmissometer was chosen to



measure the opacity of emissions which escaped the air curtain



and exited through the slot in the secondary hood.



     The RM4 utilizes a focused, autocollimated optical system




and a chopped, dual-beam measurement technique.  Light emitted by



an incandescent source in the transceiver is split into a refer-



ence beam and a measuring beam.  Each beam is modulated at sepa-



rate frequencies by a rotating disc so that they can be detected



by a common photocell.  The measuring beam is projected across



the entire diameter or width of the smoke channel to a retro-



reflector which directs the beam back through the smoke channel



to the photocell detector.  Within the hermetically-sealed trans-



ceiver casing, the reference beam is projected onto the same



photocell detector.  Signals generated by the photocell detector



are electronically separated according to their respective fre-



quencies.  The system is totally insensitive to ambient light



because it responds only to light chopped at either of the two



frequencies.  The electronic unit compares the signal obtained



from the attenuated measuring beam with that obtained from the



reference beam and provides an output signal proportional to the



attenuation of the measuring beam  (in terms of double pass opti-



cal density).
                              D-33

-------
     The optical system of the RM4 is designed to respond to a




narrow range of light wavelengths, corresponding to the sensi-




tivity of the light-adapted human eye; this is known as




"photopic" spectral response.  This characteristic response




includes wavelengths from 400 to 700 nanometers with a maximum



between 500 and 600 nanometers.  Light beams of such wavelengths




are attenuated by particulate matter as small as 0.2 microns, and




they are not subject to interference from near infrared absorp-



tion by water vapor.




     Instrument calibration which includes zero and span checks




can be performed while the instrument is on line.  The calibra-



tion checks are accomplished by inserting a solenoid-activated




reflector into the measuring beam so as to simulate zero opacity;



i.e., a clear-stack condition.  Next, a solenoid-activated neu-




tral-density filter is inserted into the beam to provide a mea-



surement value corresponding to a preselected span calibration



point that depends upon the individual measurement range of the



instrument.  Since the optical density scale is linear, these two



calibration points suffice as a check of calibration across the



entire measurement range.



     The RM4 provides a 0 to 20 milliampere output signal.  This



output signal can be connected directly to a chart recorder or



other remote readout device.  This output signal is linear with



respect to optical density and includes a 10 percent  (2 milliam-



pere) zero offset.  The 10 percent zero offset allows detection



of any negative zero drift.
                              D-34

-------
     The transmissometer is equipped with an optical bulls-eye



and an alignment device which allows alignment, verification of



alignment and, if necessary, realignment at any time without



disturbing instrument operation.



     Alignment variation of up to ±0.4 degrees, equivalent to a



beam movement of 1 to 3 inches at distances of 10 to 30 feet, is



tolerated without affecting instrument performance.  This toler-



ance results from the focused light beam which provides very



uniform illumination (maximum variation of ±2 percent)  of the



retroreflector and a large ratio of illuminated area to effective



reflector area.  Furthermore, the measuring beam is reflected



back to the transceiver unit by a corner-cube reflector that is



relatively insensitive to the angle of incident light.



     Air-purging systems which provide an air window for the



optics to keep exposed optical surfaces clean and protect the



optical surfaces from condensation are provided with each instru-



ment.  A standard installation consists of one air-purging system



for the transceiver unit and another air-purging system for the



reflector unit, each equipped with a side channel blower that



provides approximately 50 cubic feet per minute of double fil-



tered air.



     The instrument used in this test program was equipped with a



multirange circuit card which was set on range 5.  This gave the



instrument a measurement range of 0 to 98.4 percent opacity



(single pass).  Prior to installing the instrument on the sec-



ondary hood, the instrument was setup in a smoke-free environment
                               D-35

-------
at a distance equal to the measurement distance across the sec-



ondary hood.  Optical and electronic alignments were then checked



and adjustments made as needed.  The transmissometer was then



installed on the secondary hood and again optical and electronic



alignments checked and any needed adjustments made.  Installation



of the instrument on the secondary hood and alignment checks were



accomplished while the No. 4 converter was down for repair.



     Prior to each test run, a zero and calibration check along



with an optical alignment check was performed.  The instrument



then operated continuously throughout the test.  During periods



that tests were not being run, the instrument was turned off and



channels to the optics sealed to protect the instrument and



optics from the dusty environment in the smelter.
                              D-36

-------
            APPENDIX E




CALIBRATION PROCEDURES AND RESULTS
                E-l

-------
               CALIBRATION PROCEDURES AND RESULTS



     All of the equipment used was calibrated according to the


procedures outlined in Maintenance,  Calibration, and Operation of


Isokinetic Source-Sampling Equipment.*



NOZZLE DIAMETER


     The nozzles were calibrated by  making three separate measure-


ments using different inside diameters and calculating the aver-


age.  If a deviation of more than 0.002 inches was found the


nozzle was either discarded or reamed out and remeasured.  A


micrometer was used for measuring.  This calibration data is


shown in Figure E-l.



PITOT TUBE CALIBRATION


     The pitot tubes used in sampling were constructed by PEDCo


Environmental and met all requirements of Method 2, Section 4.1


of the Federal Register.**  Therefore, a baseline coefficient of


0.84 was assigned to each pitot tube.  See Figures E-2 and E-3


for alignment requirements of Method 2, and Figures E-4 through


E-7 for actual calibration and inspection data of the pitot tubes


used during the test program.
 *
  Office of Air Programs Publication No. APTD-0576.

  40 CFR 60, Appendix A, Reference Method 2, July 1981.
                              E-2

-------
Date   //
                             Calibrated by
   Nozzle
identification
   number
                    DI, in.
                              D2, in
D3, in.
AD, in.
           avg
            ( B '
                                 Jt
                               .113
                                                    .eo£
                                                    ,001

                                                   ,061
                                                    ,00 Z-
                    .il D
           6.0
                                                             VJf
whe
   ?e*/l1
             -III
D,  2 ~  = nozzle diameter measured on a different  diameter,  in,
  '  '  '    Tolerance = measure within 0.001  in.

     AD = maximum difference in any two measurements,  in.
          Tolerance = 0.004 in.

   D    = average of D,, D_, and D-.
    SVCJ               J.   £       J
               Figure E-1.  Nozzle calibration data.
                         E-3

-------
                 TRANSVERSE
                  TUBE  AXIS
                           \
                                     FACE
                                *~ OPENING ~
                                    PLANES

                                 (a)  ENDVIEW
   LONGITUDINAL
    TUBE AXIS
                                    A-SIDE  PLANE
     ;         —•
a	t
0.48 cm < Dt  < 0.95 cm
(3/16 in.)     (3/8 in.)
                                                           NOTE:
                                             1.05 Dt <  P  <  1.50  Dt
                                                                PA=PB
                      B-SIDE PLANE

                     (b)
                                  A or B
                                   (c)
  Figure  E-2.   Properly constructed Type S pitot tube,  shown  in:   (a) end view;
  face  opening  planes  perpendicular to  transverse axis;  (b) top view; face open-
  ing planes  parallel  to  longitudinal axis;  (c) side view; both legs of equal
  length  and  center!ines  coincident, when viewed from both sides.  Baseline
  coefficient values of 0.84 may  be assigned  to pitot tubes constructed this way.
                                    E-4

-------
                           al/
                •RANSVERSE   /
                TUBE AXIS  |/
                                (a)
LONGITUDINAL
   TUBE AXIS
                                            (e)
                                        (f)
                                                               B2  (+  or  -)
                                                               Bl (+  or  -)

   Figure E-3.  Types of face-opening misalignment that can result from field
   use or improper construction of Type S pitot tubes.   These will  not  affect
   Cp so long as a-| and a? <10°, Bi and B? <5°, z <0.32 (1/8 in.)  and w <0.08
   cm (1/32 in.).
                                   E-5

-------
Pilot Tube No.
Date
Inspector

Degrees
/"
<10°
°2
Degrees
^
<10°
Degrees
J°
<5°
Degrees
^
<5°

Dt
Inches
,31$
0.185 < Pt <0.380
P
Inches
,W^
-
1.05 Dt
Inches
A^-
-
1.50 Dt
Inches
,-:TUS
-

Y
Degrees
i?°
-
Degrees
^O
^^**
-
Inches
,6^
<0.125
P • (<*>)
sin vv/
Inches
.030^
<0. 03125
Pl
Inches
.^3>^
1.05
3 


-------
Pilot Tube No.
                             Date   /M'fJL    Inspector

Degrees
•£°
<10°
Degrees
J*
<10°
Degrees
1-°
<5°
Degrees
V-°
<5°

Dt
Inches
• 373"
0.185 < Pt <0.380
P
Inches
. A^
-
I. 05 Dt
Inches
iW-
-
I. 50 Dt
Inches
,SL-3
-

Y
Degrees
v— *
-
Degrees
fl 0
-
Inches
, 075"
<0.l25
P • (<•)
SHI w/
Inches
, o3D
<0.03l25
Inches
/ f6~V
1. 05 D. 
-------
Pilot Tube No.    J7Q
Date
                                    / /7/eJ-      Inspector J?.  A-~
7
ai
Degrees
2 ^
<10°
a2
Degrees
i Q
<10°
6i
Degrees
0.0
<5°
62
Degrees
2.0
<5°
Dt
Inches
0-3 ? f
0.185 <. Pt <0.380
P
Inches
o. ?<**-
-
1.05 Dt
Inches
0. 3^y
-
1.50 Dt
Inches
0.SCS
-
Y
Degrees
/ .C
-
Degrees
OrP
-
Inches
O.oi 7
<0.125
P • (4>)
sin
Inches
0. oo 0
<0. 03125

Inches
o.^eo
1.05 Dt 
-------
Pi tot Tube  No.-
                                     '-
                                                 Insped
for   ^^S^T/

Degrees
/*
<10°
°2
Degrees
?'
<10°
Degrees
r>°
<5°
Degrees
/°
<5°

Dt
Inches
0&1&
0.185 < Pt <0.380
P
Inches
,, tf-?3~
-
1.05 Dt
Inches
.-; J?^^/
-
1.50 Dt
Inches
& . ^^ ^_
-

Y
Degrees
C. :--> °
-
Degrees
/r
-
Inches
.0037
<0.125
P • U)
SHI w/
Inches
-COM
<0. 03125
Inches
TA V^?^*
1.05 Dt 
-------
DRY GAS METER AND ORIFICE METER

     Figure E-8 was the set-up used for the initial and post-test

calibration.  A wet test meter with a 2-cubic-feet-per-minute

capacity and +1 percent accuracy was used.  The pump was run for

approximately 15 minutes at an orifice manometer setting of 0.5

inch of water to heat up the pump and wet the interior surface of

the wet test meter.  The information on Figure E-9 (example
                                                      \
calculation sheet) was gathered for the initial calibration and

then, the ratio of accuracy of the wet test meter to the dry test

meter, and the AH@ were calculated.



POST-TEST METER CALIBRATION CHECK

     A post-test meter calibration check was made on the meter

box used during the test to check its accuracy against its last

calibration check.  This post-test calibration must be within _+5

percent of the initial calibration.  The initial calibration was

performed as described in APTD-0576.  The post-test calibration

was performed using the same method as the initial calibration.

Three calibration runs were made using the average orifice

setting obtained during each test run and with the vacuum set at

the average value obtained during each test run.  After running

the post-test calibration check all three runs were within the +5

percent range allowed by the Federal Register.*

     The initial and post-test meter box calibration data are

presented in Figures E-10 through E-13.
 40 CFR 60, Appendix A, Reference Method 2, July 1981.
                              E-10

-------
            o
                          UMBILICAL I
                                   I
                                      /GLASS TUBE
                                     ( THERMOMETER
                                      V
                                        \
METER BOX *»^
                                  PRESSURE
                                  CONTROL
                                  VALVE
                                                              U - TUBE
                                                              MANOMETER
                                                WET TEST METER
                    Figure  E-8.   Calibration  setup.
DATE
                                       KCTER BOX NO.
•AROHFTRIC PRESSURE,PK
                     in.  Hq.
                                       DRY GAS METER HO.
Orifice
Mnonwter
•etting
fiH
in. H20
0.5
1.0
1.5
2.0
3.0
4.0
Cat volume
wet test
meter
v ,
w
ft3
5
5
10
10
10
10
Gas volume
dry 9»B
•eter
V
ft3












Met te»t Dry gaa neter
•eter
V
•r












Inlet
*«'
•r












outlet
ldn'
•T












Avrr«ge
ld'
•r






Ti»e
e,
•in






T






AHC






                                                             Average.

AH

0.5
1.0
1.5
2.0
1.0
4.0

6H
n~z

0.0366
0.0737
0.110
0.147
0.221
0.294
>
VW PK (td * «00'
vd (pb * TTT«> (t« * "°>






6H*
0.0317 AH [ (t«* 4'0) 6V
Pfc (ttf * 460) [ V^ J






   1 • lUtio of  accuracy of wet  teat Meter to dry teat awter.  Tolerance • •» 0.01
 tut * Orifice of preature differential  that give* 0.75 Cf» of air at 70*F and 29.92 inchea of
       •ercury.  in H^).  Tolerance • »0.15.
                 Figure E-9.   Calibration  data sheet.

                                    E-ll

-------
DATE:
                                             KTER IOX NO.
CALIBRATOR:    A.  A>
                                             IAROMETR1C PRESSURE (P J   2 9. 6S~&   In. Hg
                                                                 P  «^
Lett:  Checks:

     Positive (minimum 5 1n. H?0):
     Negative (within 3 in. Hg of absolute):
   *hot to eaceei O.OQl cfm.
                                                                      1n.
Orifice
manometer
setting
6H
In H-0
0.5
1.0
1.5
2.0
3.0
4.0
Volume
wet test
meter
V*
ft3
iyt ooO
I3,e>t>0
;3, PifO
ft, ODt>
i^.OOO
1?.°*°
Volume
dry gas
meter
Vd
ft3
/ 2.106
it y/r
ft. 30°
i2. D**
2r,9oo
3B.6&2.
}3. DDt>
i£. 7*0
fd. ?oo
//, tyo
Af.t<^
te. 3°tf
Temperatures
Wet test
meter
\
•F
7f. 0
7i. »
7i. C
?<.o
tf.O
-71.0
-)i.O
•)t..C
7/. o
•>/. o
~il. 0
7,.o
Dry gas meter
Inlet
71
•F
Kfe
hH
sa
66
fi-ft
86
se
98
&7
*7
•?^
«7
Outlet
To
•F
7eJ
77
7^
7B
7tf
78
^7
7K
7L
77
7fe
7^
Average
Td
•F
82. S
feio
620
52.8
&/.&
g/.3
Duration
of
test
f
•1n
y*
««f
n»J
**%
«'%
»*£
Vacuum
setting
1n
Hg
/o.O
/1.o
IS
lf>,0
(0.O
(f.o
t must not deviate by more than +0.0? Y. Average
AHP must not deviate by more than 0.15 In H^O.
•Y
l.o fi
I.eW
(.&
1.037
l.*32
l.o$3
/.fc57
AHP
In N20
l'8i
\.1B
/.S9
/.fs>
/.^r
m
y,y?
AH
                           )(Td * 460)
       (   Vd   )(Pb * AH/13.6) (Tw * 460)
(0.0317H  AH    )

(  Pb   )(Td * 460)
                                                                           460)(f
                                                                                  f|2
0.5
1.0
                                                            Ao
l.S
       f/2. 7*2. H 2*.
2.0
        ?. ooc)(
                                                  (0-3/7 )( 2.
                                                                                  r»2
3.0
                            Hc?/.o
                                                                         I.
4.0
       (/2r »o If  .2*.
                                                  («>. »?
-------
DATE:   /*£•&£»*£•/  /.

BAROMETRK PRESSURE (Pbar):

PLANT:  J^4/3 QJC, -H"*. c- (»\ b
                                    . Hg
                                 METER BOX NO.

                                 PRETEST Y:
                                 PROJECT NO
PROJECT MANAGER:  /?
                                V
                                                           . >
                             /   Temperatures
Orifice
manometer
setting
  *•
  AH
in. H20
Wet test
 meter
volume

  V
           ft
Dry gas
 meter
vol ume
 Vd

 ft3
Wet  est
 meter

  Tv
  •F
                                       Dr
Inlet
 Tai
 •F
        gas meter
                                           OutletAverage
                                  di
                                 •F
''d
•F
      Vacuum
      setting
                                                          **
in.  Hg
Duration
 of run

  0

 min
AHP
                            13
                                                                                V
                                            Post-test average***
     w
               bar
                         Td4460
                                        (0.0317)(  AH   )
                  AH/13.6)(TW4460)
                                                ~(Tw+460)(
                                                                  w
                         )( 533.0)
                                             j>) (  A 0  )
  *To be the average AH used during the test series.
 **To be the highest vacuum used during the test series.
***Post-test Y must be within the range, pre-test Y *0.05y
   Post-test AH? must be within the range, pre-test AHP +0.15
                            Figure  E-10  (continued)

                                     E-13

-------
DATE
CALIBRATOR:
                                     METER BOX NO
                                     .  fi&fs
                                     IAROMETR1C PRESSURE (P^)    ,37,'V   In. Hg
Leak  Checks
     Positive  (minimum 5 1n. HzO):              	
     negative  (within 3 in. Hg of absolute)://  &OVU  cfff*
        to exceed O.OOi. cfm.
                                                             in. Mg
Orifice
manometer
setting
  AH
1n
    Volume
   vet test
    meter
     ft
 Volume
dry gas
  meter
   ft
       Temperatures
Met test
 •eter
  Dry gas meter
nle
T1
•F
€
tlet
To
•F
Average
  7d
Duration
  Of
  test
   f
  •in
Vacuum
letting
  1n
                                                     AHP
                                                    In H20
  0.5
                            &•
                                          Si
  1.0
                                    fz
                                                          /o.o
  1.5
   /o.
                             Jc.S
                                              /O
  2.0
                                    f?
                                          fc.o
  3.0
  4.0
  /0.0
                                              /v.o
t nust not deviate by more than +0.02 \.
AHP nust not deviate by more than" 0.15 In H.O.
                                                       Average
                                                                AH«
AH
                           )(Td 4 460)
      (   Vd   )(Pb * AH/13. 6) (Tw* 460)
                              (0.03U)(  AH    )

                              (  Pb  )(Td 4 460)
                                                            (T   *  460) (f
0.5
£. /T4J(  -^
                                                  25", /
1.0
                                                                  .(
1.5
                                                 (7V, i
                                                           .(
2.0
               )(   ?f.
                                          (.«'?)(
                                                                  .(
3.0
                                                 ( 24.1
                                                           .(
                                                                            ft
4.0
              M
                                                                  .(
   Figure E-ll.   Particulate sampling meter box calibration data  sheet.
                                       E-14

-------
DATE:

BAROMETRIC PRESSURE

PLANT:
                      A /
                        METER BOX NO.
                         l;.P?.£3
  *To be the average AH used during the test  series.
 **To be the highest vacuum used during the test  series.
***Post-test Y must be within the range, pre-test Y +0.05y
   Post-test AH9 must be within the range, pre-test AHP *0.

                           Figure E-ll  (continued)
                                       E-15

-------
BATE:
CALIBRATOR:
                        JL
                                              KTER BOX NO.
                           BAROMETRIC PRESSURE
                                                                                     u  Hg
Leak Checks:

     Positive (minimum 5 In.  H?0): ^_^__^
     Negative (within 3 in. Hg  of absolute):
    •Not to exceed 0.005 cfm.
                                           Co o i
                                                      cfm*
                                                    In. Hg
Orifice
nanometer
setting

  AH

1n H.O
           Volume
          wet test
            •eter
             ft
 Volume
dry gas
  •eter
   ft
                                   T«niperatures
                            Net test
                            •eter
  Dry gas meter
nlet

T1

•F
£
ou
tlet
To
•F
Average
Duration
   of
  test
Vacuum
setting
  1n
  Hg
                                                                                   AHP
                                                                                  In H20
  0.5
                   •>&.<) 00
                                     77
                            7o . o
  1.0
                                            7V
                            76*0

                                                                    /o. c-
                                                               1,1-
  1.5
                                           76
                            ?0: 0
                                           So
                                                                   I Z.I
  2.0
                                            30
                            70-
  3.0
                                      fCO
                                            82-
  4.0
                   tfrt.ort
          ID,
                                           el
                                                          **

                                                /o.o
                                                                            o.vn
T must  not deviate by more than +0.02 >.
AHP must not deviate by more thaK 0.15 In H.O.
                                                                 Average
                                                                   AH?
AH
                            )(Td + 460)
       (   Vd   )(Pfc + AH/13. 6)(Tw + 460}
                                                   (0.0317)(  AH    )

                                                   {  Pfc   )(Td * 460)
                                                  (TM  •»  460)(g)"l2
                                                      ( V   )
0.5
        T.O(
                                                                          y. ix
1.0
       (13.
1.5
                                                                     L (   /.?.
2.1
                                                            2.0
                                                                            . OUO  ).
3.0
4.0
       (10.
                                                                     -J
     Figure E-12.   Particulate sampling meter  box calibration  data sheet.
                                          E-16

-------
DATE:
BAROMETRIC PRESSURE  (Pbar):

PLANT :      *Vte ««= - "M ^ — A,
                                   .  Hg
                        METER BOX NO. £_

                        PRETEST Y:
                        PROJECT NO.
                                  AHP:
PROJECT MANAGER:
                                                                r rfr
Orifice
manometer
setting
  *-
  AH
in. H20
         Wet test
          meter
         volume
          ft
Dry gas
 meter
volume
 ft
       Temperatures
e   es
meter
    Dr
3nlet
 Tdi

 •F
 gas meter
OutletAveragc
Vacuum
setting
                                                         **
                               . Hg
Duration
 of run
                      min
                        4HI?
          /0.0
                            93,
                                                -o
          /O. a
                  3/1. 3'
          73
                                                                           ,0
                                            Post-test average
                                                             ***
                                                     flmp
                         V460
                                       (0.0317)(  AH  )
    Vd   )tphar * AH/13. 6)(Tw + 460)
                                      "(Tw+460)(  e
(/c- /o/  )(
                                                                   0    X
                                                                        n   2

         )(
         )(
                         )(
                                                  fg^F]
                                                      )
  *To be the average AH used during the test  series.
 **To be the highest vacuum used during the test  series.
***Post-test Y "Hist be within the range, pre-test y ^O.
   Post-test AH? must be within the range, pre-test AH@ +0.15
                             Figure  E-12 (continued)
                                       E-17

-------
WTE:

CAlIIWTC
                         ItTW IOX DO. 	

                         lAROMTMlC WSSUtt
                                                                                  Ng
LMk ClttCks:
    Positive (»1nlMn S 1n.
    Ntgittve (vUtrin ) in. Ng of •biolutt) :
        to ticeed 0.005 cfm.
                                          43. OOC   Cf»*
                                                 in. Ho
OHfke
•inometer
(Citing
  AH
1n
          Volume
         vet test
           •eter
            ft
 Volume
dry 9*1
  •eter
   ft
lett
•eter
 Dry g«s aeter
ne
T1
•r
£
tlet
\
Average
Duration
  Of
  ten
   t
Vtcuum
•ettlng
  1n
  M0
                                                                              AM
         6.0 \
                                   91
  1.0
                  •366
                                          •3D
                                   •31
                       •BO
  1.5
                                                                 /.o
  2.0
          /o.O
  3.0
                                                &,*
                                                             .
                                                .O
  4.0
                  mm
t Bust not deviate by «ore than *0.02 >.
AW Bust not deviate by «ore than 0.15 In
                                                             Average
                                                               AH*
AH
        )(Td * 460)
                  * AH/13.6)(T 4 166)
                                                (0.0317)(  AM    )
                                                                 (T.,  *  460) (I
                                                                     < V, )
                                                    I
0.5
1.0
      ( -SsQ  j(
                          \t
                                                                 .(
1.S
      ( // 0 )(
              )(
                                                                 .(    //• 0
                                                          •ff
2.(
      i /co
                                                                 .(    /O
                                                                            ^T
1.0
             Jf_
                                                                 .(    /£?,»
4.0
      I//,V  ^f
                         Jl
    Figure E-13.   Participate  sampling meter  box calibration  data  sheet.
                                        E-18

-------
DATE: _

BAROMETRIC PRESSURMPbar): 2< $,!*,
                                                               <5.0
  *To be the average AH used during the test series.
 **To be the highest vacuum used during the test series.
   Post-test Y must be within the range, pre-test Y +0.05-y
   Post-test AHP must be within the range, pre-test AH@ +0.15

                              Figure E-13  (continued)
                                     E-19

-------
THERMOCOUPLES




     Thermocouples were calibrated by comparison against an




ASTM-2F thermometer at approximately 32°F, ambient temperature,



100°F, and 500°F.  The thermocouples read within 1.5 percent of



the reference thermometer throughout the entire range when ex-




pressed in degrees Rankine.  If the thermocouple did not read




within 1.5 percent, a correction formula based on a least squares




analysis of the data was utilized.  The correction formula cor-



rected the data 1.5 percent.  The thermocouple was checked at



ambient temperature at the test site to verify the calibration.



Calibration data is presented in Figures E-14 through E-17.






DIGITAL INDICATOR FOR THERMOCOUPLE READOUT




     A digital indicator was calibrated by feeding a series of



millivolt signals to the input, and comparing the indicator



reading with the reading the signal should have generated.  Error



did not exceed 0.5 percent when the temperatures were expressed



in degrees Rankine.  Calibration data are shown in Figures E-18



and E-19.






DRY GAS THERMOMETERS



     The dry gas thermometers were calibrated by comparison



against an ASTM-2F thermometer at approximately 32°F, at ambient



temperature, and at approximately 110°F.  The thermometer agreed




within 5°F of the reference thermometer.  The impinger thermom-



eters were calibrated in a similar manner at approximately 32°F



and at ambient temperature.  The thermometers agreed with 2°F of
                               E-20

-------
Date:
          fhil
Ambient temperature:

Calibrator:  Q   ^
                       7* _
  Thermocouple No.:	

°F  Barometric pressure:

  Reference:     /Q3T/*-
                                                    113
                                                               Hy

Reference
point
No.
/
2
?
V

.
Source,*
(specify)
2
1
3
3
Reference
thermometer
temperature,
op* * *
76
3~
)37
YV
Thermocouple

temperature,
Op
?y
3i
I$J
^iz.


Difference,
%**
0 37
~ 0.7°
o.i7
?,V<>
Correction factor****:  Slope;  /. i>
                                          Intercept;

Reference
point
No.
1
z
3
1
Reference
thermometer
temperature,
Op
7t
?r
137
Y^^i
Corrected
thermocouple
temperature,
Op
7^
J-/
HO
1.5T?
Q.fC>
                                                 x 100?-
Critical test points are 32°, 100°, and 500°.

   *Source:  1) Ice bath
             2) Ambient
             3) Furnace

  **Percent difference
      Reference temp. °F - thermocouple temp. °F
             (Reference temp. °F + 460°F)

        Each percent difference must be less than or equal to 1.5%

 ***Reference thermometer must be ASTM.

****Correction factor must be determined if any percent difference
    is >1.5%.
           Figure E-14.  Thermocouple calibration data sheet.

                               E-21

-------
Date:
                               Thermocouple No.:
Ambient temperature:   7/    °F   Barometric pressure:

Calibrator:  /?.  /4/>»,5f c>
£>. Ot?
Correction factor****:  Slope:
                                           Intercept:
Reference
point
No.




Reference
thermometer
temperature,
oF




Corrected
thermocouple
temperature,
°F




Difference,
%**




Critical test points are  32°,  100°,  and 500°.

   *Source:  1) Ice bath
             2) Ambient
             3} Furnace
  **Percent difference
      Reference temp. °F - thermocouple temp.  °F
              (Reference temp.  °F  +  460°F)
                                                  x 100%

        Each percent difference must  be less than or equal to 1.5%

 ***Reference thermometer must be  ASTM.

****Correction factor must be determined if any percent difference
    is >1.5%.
         Figure E-15.  Thermocouple calibration data sheet.
                             E-22

-------
Date: O/3/<%® Thermocouple No.: x*. ^^>
Ambient temperate e: "7^ °T Barometric pressure: 5£ ?Y " H
Calibrator
Reference
point
No.
/
^,
3
V
Correction
: Z*7 /\r*~ *\'~v ^ j Reference: ~fAer^~ <. — -v'/£ f3^
1
Source , *
(specify)
£
i
Rc-ferencc
, thermometer
temperature ,
°p* « *
^° ^-7^
Thcrmocoup] t
temperature, Daf f cre-ncu ,
* "
7) -&.(*{
f ?i (7i^ ' ^/ o. ,?^
3 /^° £s~?

Reference
thermometer
temperature,
CF
TO
Corrected
thermocouple
temperature, Difference,
°F ^**
i
£i \ O. **T
j~r 3j : *.y1.5%.
           Figure E-16.  Thermocouple calibration data sheet.
                                E-23

-------
Date:
                               Thermocouple No.:
Ambient temperature:    7^   °F   Barometric pressure:  3*1.2.   /W^lrc,-    Reference:	A5TW -3Lf-	
Reference
point
No .
/
^
?
U
Source, *
(specify)
2
/
Reference-
thermometer
temperature,
op* * *
7*1
3i
3 HO
3 J

- C, M
                                                  x 100V
Critical test points are  32°,  100°,  and 500°.

   *Source:  1} Ice bath
             2) Ambient
             3) Furnace

  **Percent difference
      Reference temp. CF  -  thermocouple temp. °F
             (Reference temp.  °F  +  460°F)

        Each percent difference must be less than or equal to  1.51

 ***Reference thermometer must be ASTM.

****Correction factor must  be  determined if any percent difference
    is >1.5%.

         Figure E-17.  Thermocouple calibration data sheet.
                               E-24

-------
Date
' A
                       Indicator Ho.
Opera
Test Point
No.
0
1
2
3
4
Millivolt
signal*
**




Equivalent
temperature.
•F*
96.
_§-z..o
/02*~l
K/.l
/Pl°
Digital Indicator
temperature reading,
•F
73.*
3^-6
/06,l
*feo.'
//J4.5
Difference,
X
Ml%
o.tt%
V»3?l
0,111*
o,/fo
Percent difference must be less than or equal to 0.5%.

Percent difference:

  (Equivalent temperature °R- Digital Indicator temperature reading *R)(100S)
                              (Equivalent temperature *R)
Where °R » °F * 460DF
 *See thermocouple digital Indicator calibration verification device calibra-
  tion for these values.

**Th1s point 1s ambient temperature.  The device 1s off and therefore Is
  supplying no signal other than ambient temperature.

        Figure E-18.   Thermocouple  digital  indicator calibration data sheet.
                                     E-25

-------
                       Indicator No.
Operator
Test Point
No.
1
2
3
4
Millivolt
signal*
O OOO
/.sit
#*$$
£5, ^5
Equivalent
temperature,
°F*
3c^°
/fcp.,z
^57- /
//.??.
Digital Indicator
temperature reading,
°F
-32-
yoe
4z/
//*%
Difference,
%
<^oo
<9,0^
0,o/
-O.O&
Percent difference must be less than or equal  to 0.5%.
Percent difference:
  (Equivalent temperature °R - Digital indicator temperature reading °R)(100%)
                              (Equivalent temperature °Rj
Where °R = °F + 460°F
  These values are to be obtained from the calibration data  sheet for the
  calibration device.
      Figure E-19.   Thermocouple  digital  indicator calibration data sheet.
                                       E-26

-------
the reference thermometer.  The thermometers were checked prior




to each test series at ambient temperature to verify calibration.



Calibration data are included in Figures E-20 through E-23.






TRIP BALANCE




     The trip balance was calibrated by comparison with a Class-S



standard weight and agreed within 0.5 g.  Calibration data are



shown in Figure E-24.






BAROMETER




     The field barometer was calibrated to within 0.1 in.Hg of an



NBS-traceable mercury-in-glass barometer before each test series.



The field barometer was checked against the mercury-in-glass



barometer after each test series to determine if it read within



0.2 in.Hg.  If it did not reading within 0.2 in.Hg, a correction



factor was determined for the last test series.  Calibration data




are included in Figure E-25.
                             E-27

-------
pate:
  Meter Box No.:
Calibrator;
  Inlet
Reference:
Reference
point
No.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
72 o
32. 7
/^7.<2
Dry gas
thermometer
temperature ,
•F
72.
12
///
Difference,
•F**
o.o
6.7
3.0
  Outlet
Reference
point
No.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
•72.0
22.7
(((>. o
Dry gas
thermometer
temperature ,
•F
73
?V
/'f
Difference,
1.0
1.3
/.o
  •Source:  1)  Ice bath
            2)  Ambient
            3)  Water bath

 ••Difference must be less than or  equal to +5'F.


          Figure E-20.  Dry gas thermometer calibration  data sheet.
                                E-28

-------
Date:
  Meter Box No.
Calibrator;  8.
  Inlet
Reference;
Reference
point
No.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
•?2.o
37 ?
(O8.o
Dry gas
thermometer
temperature ,
•F
•?£
?
Difference,
•p..
y.o
7.3
2.0
  Outlet
Reference
point
No.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
72 0
32.7
K7. f
Dry gas
thermometer
temperature ,
•F
75
3*
Iff
Difference,
•F*«
/. o
/.3
2.^
  •Source:  1)  Zee bath
            2)  Ambient
            3)  Water bath

 ••Difference must be less than or  equal to +5'F.


          Figure E-21.  Dry gas thermometer calibration data sheet.
                                E-29

-------
Date:
                   Meter  Box No
Calibrator:


  Inlet
B .
                       T^-o^
                          g
                               Reference;
Reference
point
No.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
7^.0
33.5"
//?. 
-------
Date:
                                 Meter Box No.:
FQ-1
Calibrator:^


  Inlet
                       • Sj.
                               Reference:
Reference
point
Mo.
1
2
3
Source *
2
1
3
Reference
thermometer
temperature ,
•F
75". o
32-0
/2f- °
Dry gas
thermometer
temperature,
•F
7S
21
/2Z
Difference,
•F**
/- £>
/.^
Ac?
  Outlet

Reference
point
Mo.
1
2
3


Source *

2
1
3
Reference
thermometer
temperature ,
•F
7*.0
3*.o
uv.c
Dry gas
thermometer
temperature ,
•F
7/
31
123


Difference,
•F**
/.**
/.c
f. 0
  •Source:  1) Ice bath
            2) Ambient
            3) Water bath

 "Difference must be less than or equal to  +5*F.

         Figure E-23.  Dry gas thermometer calibration  data sheet.
                                E-31

-------
Balance
  No.
Date-
Calibrator
                                   Mass  determined  for
Error
50 g  Error
100 g
Error

                  /L
                                                              .AT
          i   I
         //
 /V/
                                        .7
                                                                        c>.
                  c
                                                   »~e*
                                                                /C,
Error must not exceed 0.5 grams at each  point.


             Figure E-24.  Trip balance  calibration data sheet.
                                    E-32

-------
BAROMETER
   NO.
PRETEST
                       vseM
BAROMETER
READING
REFERENCE
BAROMETER
READING
DIFFERENCE
            0,01-
                    /'.r
0,02.
DATE
                                         12tc
                                                     fe~/-3-fe
CALIBRATOR <:
POST-TEST
BAROMETER
READING
30.02.
REFERENCE
BAROMETER
READING
7.9- 9
DIFFERENCE
          **
                         00
DATE
CALIBRATOR
 *Barometer is adjusted so that difference does  not exceed 0.05 in. Hg.
**Barometer is not adjusted.  If difference exceed 0.10 in. Hg, inform project
  manager imnedTately.

                    Figure  E-25.  Barometer calibration  log.
                                  E-33

-------
         APPENDIX F




QUALITY ASSURANCE PROJECT PLAN
             F-l

-------
         QUALITY ASSURANCE PROJECT PLAN

          AIR CURTAIN HOOD TEST PROGRAM
            AT ASARCO TACOMA SMELTER
                 Prepared by

          PEDCo Environmental, Inc.
             11499 Chester Road
           Cincinnati, Ohio  45246
           Contract No. 68-03-2924
              Work Directive 9
                  PN 3490-9
                Prepared for

    U.S. ENVIRONMENTAL PROTECTION AGENCY
Industrial Environmental Research Laboratory
              Cincinnati, Ohi<
                 (.
Approved by:     .- //tSAjLu'  /{AJ ' /:JCMt/W Project  Director,  PEDCo

                                          , QA Officer,  PEDCo

                           	, Project  Director,  EPA

                           	, QA Officer,  EPA


                            July  1982

                               F-2

-------
                            CONTENTS
Section                             Pages   Revision     Date
 1.   Project Description              3         1      09-10-82

 2.   Project Organization and
     Responsibilities                 3         0      07-20-82

 3.   QA Objectives for Measure-
     ment Data in Terms of Preci-
     sion, Accuracy,  Completeness,
     Representativeness, and
     Comparability                    5         1      09-10-82

 4.   Sampling Procedures              4         1      09-10-82

 5.   Sample Custody                   1         0      07-20-82

 6.   Calibration Procedures and
     Frequency                        1         1      09-10-82

 7.   Analytical Procedures            2         0      07-20-82

 8.   Data Analysis, Validation,
     and Reporting                    5         0      07-20-82

 9.   Internal Quality Control
     Checks and Frequency             1         0      07-20-82

10.   Performance and Systems
     Audits and Frequency             4         1      09-10-82

11.   Preventive Maintenance
     Procedures and Schedules         1         0      07-20-82

12.   Assessment of Data Precision,
     Accuracy, and Completeness       1         0      07-20-82

13.   Corrective Action                2         0      07-20-82

14.   Quality Assurance Reports
     to Management                    1         0      07-20-82
                               F-3

-------
                      CONTENTS (Continued)


Section                             Pages   Revision     Date
Appendix A - Test and Analytical
  Procedures                         24         0      07-20-82

Appendix B - Emission Measurement
  Quality Assurance Plan             35         0      07-20-82

Appendix C - Laboratory Quality
  Assurance Plan                     38         0      07-20-82

List of Individuals Receiving Project QA Plan:

          John O. Burckle, U.S. EPA
          Guy Simes, U.S. EPA
          Richard W. Gerstle, PEDCo Environmental
          Charles L. Bruffey, PEDCo Environmental
          Thomas J. Wagner, PEDCo Environmental
          Craig H. Caldwell, PEDCo Environmental
          Larry V. Yerino, PEDCo Environmental
                             F-4

-------
                                        Section No.       1
                                        Revision No.T
                                        Date:    September 10, 1982
                                        Page    1      of      3
                            SECTION 1

                       PROJECT DESCRIPTION


     This project will evaluate the effectiveness of the air

curtain hooding system installed on the primary copper converter

at ASARCo's Tacoma,  Washington smelter.  The primary objectives

of the test program are to:

     1.   Estimate the air curtain capture efficiency; overall
          and during selected converter operational modes.

     2.   Estimate the converter emission factors for the overall
          cycle and selected operational modes for:

          a.   sulfur dioxide (802)
          b.   filterable particulate
          c.   arsenic emissions
          d.   inhalable particulate, and
          e.   selected trace elements

     3.   Evaluate the air curtain operation for labor and main-
          tenance requirements, operator accessibility, visibility
          improvement, power requirements, and cost information.

     This air curtain hooding system is the first of its kind to

control fugitive emissions from a primary copper converter.  The

data from these tests will be used to evaluate this system and

determine if it is best available technology for the control of

these fugitive emissions.

     The fugitive emissions collection efficiency of the air

curtain hooding system will be estimated by performing a tracer

study and performing visible emissions observations during the

test program.  Sulfur hexafluoride  (SF,) will be injected into
                              F-5

-------
                                         Section No. 	1
                                         Revision No.   	1
                                         Date:   September 10. 1982
                                         Page    2     of     3
the fugitive emission plume and the amount of SFfi captured by

the collection system will be measured using a gas chromato-

graph equipped with an electron capture detector.  Visible

emissions will be performed by certified observers using EPA

Reference Methods 9 and 22.

     Filterable particulate and arsenic emissions will be mea-

sured using EPA Methods 5 and 108.  A single sampling train will

be used to obtain the filterable particulate and arsenic samples.

Sampling will be performed over the entire converter cycle and

during selected operational modes.

     Inhalable particulate (IP) measurements will be made using

the guidelines in the Procedures Manual for Inhalable Particulate

Sampler Operation  recently developed for EPA by Southern Research

Institute.

     Trace element analysis will be performed on each particle

size fraction using atomic absorption analytical techniques.

Each size fraction will be analyzed for arsenic, cadmium, lead,

antimony, selenium, and bismuth.

     The tentative schedule for this project is 1) a presurvey

late in September, 2) SF, tracer study in October, and 3) full
 Southern Research Institute.  Procedures Manual for  Inhalable
 Particulate Sampler Operation.  Prepared for EPA under Contract
 No. 68-02-3118.  November 1979.
                             F-6

-------
                                          Section No.       1
                                          Revision No.       1
                                          Date:   September 10. 1982
                                          Page    3     of     3
scale test program in November.  This schedule  is  dependent upon

plant operations.   As of late August, the furnace  was being

rebuilt and  the  shake-down period for the air curtain had not

been completed.
                               F-7

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                                         Section No. 	2	
                                         Revision No.      0	
                                         Date:     July 20, 1982
                                         Page     1    of    3
                             SECTION 2

             PROJECT ORGANIZATION AND RESPONSIBILITIES


 2.1   PROJECT MANAGEMENT

      The  proposed  staffing  of  this project is shown in Figure 2-

 1.  The Project  Director  will  be Mr.  Richard Gerstle who has had

 extensive experience  in source testing  and related engineering

 activities.   He  has the administrative  responsibility for the

 successful completion of  the project.   His duties  include schedul-

 ing of personnel,  setting deadlines and seeing that they are met,

 and overseeing the  budget.  Mr.  Charles Bruffey, as Project

 Manager, has  the responsibility  for the technical  management of

 the project.  His duties  include the  division of labor among the

 project's various tasks,  the implementation  of quality control

 procedures, the  supervision of all  field activities,  the final

 review and reporting of all data.   Mr.  Wade  Mason,  who has exten-

 sive experience  in  emission and  fugitive testing,  will serve as

Technical Advisor.   Mr.  Thomas Wagner,  as  Quality  Assurance

Coordinator, is responsible for  the development and implementa-

tion of the Quality Assurance Project Plan.
                               F-8

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                                               Section No. 	2	
                                               Revision No.      0
                                               Date:     July  20, 1982
                                               Page      2     of    3
Field Sampling
   Clarke
   Sander
   Phillips
   Hershey
   Scheffel
   Osterhout
   Fitzgerald
   Antesberger
                                 EPA -  IERL
                               Project  Officer

                                John Burckle
                                    PEDCo
                              Project Director

                                R.W.  Gerstle
                                    PEDCo
                               Project Manager

                                C.L.  Bruffey
Laboratory Analysis

    C.  Caldwell
    I.  Bennett
    C.  Jones
    K.  Mueller
                                  EPA  -  IERL
                                  QA Officer

                                  Guy  Simes
                                                                 PEDCo
                                                               QA Officer

                                                             T.J. Wagner
                                    PEDCo
                               Technical  Advisor

                                  K.W.  Mason
Process Monitoring

    L.  Yerino
                     Figure 2-1.   Project organization.
                                    F-9

-------
                                        Section No. 	2	
                                        Revision No. 	Q	
                                        Date:     July 20,  1982
                                        Page     3    of    3
2.2  PROJECT STAFF


     The staff selected for this project  were  chosen because of


their experience in emission measurement  including manual sampling


and continuous monitors, field operation  of  gas  chromatographs,


laboratory analysis, and process monitoring.
                               F-10

-------
                                        Section No. 	3
                                        Revision No. 	1
                                        Date:    September 10. 1982
                                        Page    1      of      5
                             SECTION 3


    QA OBJECTIVES FOR MEASUREMENT DATA IN TERMS OF PRECISION,
  ACCURACY, COMPLETENESS, REPRESENTATIVENESS AND COMPARABILITY



     The objectives of precision, accuracy, and completeness for

the specific emission measurements are listed in Table 3-1.

Testing will be performed over the complete process cycle and

selected process operational modes.  Process operations and

testing coordination will be accomplished by the process engineer


responsible for logging process data in order to ensure the


representativeness of the data.  All data will be reported in the

units specified in the methods to ensure comparability of the

data.


     No reliable estimates for the precision and accuracy are

available for the overall sampling and analysis of the trace


metals.  The objectvies for these parameters listed in Table 3-2

are for the analytical procedures.

     The objectives for precision and accuracy listed in Table

3-2 were developed from duplicate analyses of wastewater samples

and the analysis of standard reference solutions  (as separate

samples) in PEDCo's laboratory.  These quality control procedures

are described in Sections 5.1 and 5.2 of the PEDCo Environmental

Laboratory Quality Assurance Plan  (LQAP) contained in Appendix  C.

The minimum objectives for completeness are also contained in

Table 3-2.
                               F-ll

-------
    TABLE 3-1.   PRECISION.  ACCURACY. AND  COMPLETENESS  OF EMISSION  MEASUREMENTS
Measurement parameter
Gas volume
Gas velocity
Stack temperature
Partlculate weight
Gas composition,
CO- and 02
so2
so2
Particle size
(Inhalable partlcu-
late) weight
Measurement method
Dry gas meter
Method 5
S-type pi tot tube
Method 2
Thermocouple and
digital volt meter
Met tier balance
Orsat (Method 3)
Continuous Emis-
sion monitor (CEM),
pulse fluoresence
Bar1um-thor1n
titratlon
Method 6
Mettler balance
Cal 1brat1on device
Wet test meter and
critical orifice
EPA design specifi-
cations and stan-
dard pilot tube
Mercury In glass
thermometer and
mill ivolt source
Class S weights
NBS traceable gas
cylinders
NBS traceable S02
in air calibration
gases
QAD audit sample
Class S weights
Expected
Precision
+ 2%a
+ 18%a
ina
+ 0.5mga
* 0.5%a
~95% of
full scale
<4%a
+ 0.2mga
Accuracy
!«•
* 10%a
±1.5%a
+ 0.5mga
i 0.5,'
20%b or
better
t6%a
+ 0.5mga
Completeness
100%
100%
100%
100%
100%
90% or
better
100%
100%
8 As  listed 1n EPA QA Handbook, Volume III.



  As  listed in 40 CFR Appendix B, Performance  Specification No. 2.
                                                                                                       "O O 3D W»
                                                                                                       Q> Ol (D (D
                                                                                                       fD -»• r*
                                                                                                           -* O
                                                                                                           O 3
                                                                                                         ft O
                                                                                                              u>

-------
                           TABLE 3-2.   PRECISION, ACCURACY,  AND  COMPLETENESS OF  METAL  ANALYSIS
 i
\~>
to
Analyses
Arsenic (furnace)
Antimony (flame)
Antimony (furnace)
Bismuth (flame)
Bismuth (furnace)
Cadmium (flame)
Cadmium (furnace)
Lead (flame)
Selenium (furnace)
Precision
Average coefficient
of variation (CT)
.139
**
.070
**
**
.018
.077
.042
.055
Accuracy*
True value
(ppm)
.0750
15.0
.150
-
-
1.00
.0100
5.00
.0500
Mean (X)
(ppm)
.0762
15.0
.149
-
-
.981
.0100
5.03
.0492
Standard
deviation (o)
(ppm)
.0047
.75
.015
-
-
.034
.0006
.106
.0022
Completeness
(*)
100
100
100
100
100
100
100
100
100
                    * Mg/1  unless otherwise stated.


                    ** Insufficient amount of data  to determine a value.


                    - No SRS currently available.
                                                                                                                         TJO 30 V)
                                                                                                                         tu at n> n>
                                                                                                                         (O c* < O
                                                                                                                         rt> n> -*«-»•
                                                                                                                              _,. o
                                                                                                                              O 3

-------
                                         Section No. 	3
                                         Revision No.      1
                                         Date:   September 10. 1982
                                         Page    4     of     5
     Duplicate analyses are conducted at a minimum rate of 10

percent in the laboratory.  The coefficient of variation  (CV)  is

calculated for each analysis pair according to the equation in

Section 5.2 (page 5-3) of the Laboratory Quality Assurance Plan

(Appendix C).   The value for the CV must be within the 99.5

percentile (upper control limit = 2.8 x CV) or the analysis is

voided and the entire batch of samples is reanalyzed.

     Accuracy is monitored by the analysis of a standard reference

solution  (SRS).   Standard Reference Solutions are available for

almost every analysis routinely conducted in the inorganic labor-

atory.  These SRS's are prepared independently of the calibration

solutions.  For example, there are two solutions used as SRS's

for metals.  These two solutions contain all the metals analyzed

by atomic adsorption in the laboratory and are prepared from the

pure metals as salts as described in "Methods for Chemical

Analysis of Water and Wastes"  (MCAWW), EPA-600/4-79-020.  The

standards used for calibration are NBS traceable and are store

bought 1000 ppm solutions of the individual metals.  The values

determined for the SRS are plotted on control charts and upper

and lower control limits are set at + 2 a.  If the analysis of a

SRS (analysis rate 10 percent minimum) is outside the control
 The coefficient of variation is expressed as a decimal  fraction
 (dimentionless).  Reference Statistical Methods, G.W. Snedecon and
 W.G. Cochran, 6th Ed., Iowa State University Press, 1967, p.  62.

                              F-14

-------
                                         Section No. 	£
                                         Revision No. 	1
                                         Date:    September 10. 1982
                                         Page     5     of      5
limits, the entire  analytical run is voided and that batch of

samples is reanalyzed.   The  concentration values chosen for the

SRS are approximately  the  mid point of the optimum range of the

individual metal  listed  in MCAWW.


     The values of  precision were  obtained from and used for

samples ranging from 20  times the  method detection (MCAWW)  and

up.  The accuracy limits apply to  the same range.
                              F-15

-------
                                         Section No. 	4
                                         Revision No. 	1
                                         Date:    September 10. 1982
                                         Page    1     of     4
                            SECTION 4

                       SAMPLING PROCEDURES



     Where applicable, standard EPA test methodology will  be

used.  EPA Test Methods 1 through 6* are used to determine flue

gas velocity, temperature, composition  (0- and CO.), moisture

content, particulate concentration, and sulfur dioxide  content.

An SO- continuous emissions monitor  (TECO pulse fluorescense)

will also be used to determine SO- gas content.  Sample, analy-

tical, and data reduction techniques will follow those  described

in 40 CFR, Appendix B, Performance Specification 2.

     Inhalable particulate measurements  (particle  size) will be

made using the sample and analytical procedures described  in the

Procedures Manual for Inhalable Particulate Sampler Operation

developed by Southern Research Institute for the U.S. EPA.

Particulate and gaseous arsenic content will be determined

using a combination of proposed EPA Method 108 and Method  5

analytical procedures as described in Appendix A.

     A preliminary sampling plan is contained in Table  4-1 and

the corresponding analytical plan in Table 4-2.  These  sampling

and analytical plans may be revised based upon the results of the

presurvey and the Phase I SF., tracer study.  In any case,  a
                            b
  40 CFR, Appendix A, Methods 1-6, July 1982.

                               F-16

-------
                                                                               T
Section  No.
Revision No."           	
Date:      September  10.  1982"
Page       2
                                                                            of
     TABLE 4-1.    ASARCO PRELIMINARY  SAMPLING  PLAN
Sample
activity
•Phase 1 A
Tracer study (SFfi)
•Phase 11 °
TSP - arsenic
(combined Methods
S and 108)
SO, concentration
f exhaust gas)
Visible emissions
•Method 9
•Method 22
Particle size
distribution
1PM emission factor
Tracer quantity (SFJj
Baseline
X





Presurvey
X





Process operation nodes
Converter cycle
Blister
Charge - pour
X
X
X
X
X
X
X
X
Slag and
finish
blowing
X
X
X
X
X
X
X
X
No. Of
Tests
.
4
4
Min. S
days
observa-
tion -
2-3 cycles
4
4
-
A  Tracer gas  techniques will  be  used to evaluate  the air capture efficiency
   of the secondary control  system for both test phases.  Sulfur hexafluorlde
   (SF,) will  be used as the tracer gas with analysis by Gas Chronatography
   witn Electron Capture Detector (GC-ECD).  Known concentrations of SF. will
   be Injected at various points  in and around the secondary control system
   while integrated bag samples are collected downstream and analyzed by
   GC-ECD.

O  Total suspended paniculate and gaseous arsenic emissions will be deter-
   mined using a Method & sample  train modified by adding two 1mp1ngers and
   placing  200 ml of 5 percent H?0. 1n the third,  fourth, and fifth Inpingers
   to facilitate analysis for  arsenic.  One sample train will be run over
   the entire  converter cycle  and a second sample  train run only during the
   converter blowing modes.   At least four tests over four separate converter
   cycles are  recommended.

O  SO. concentration in the  exhaust gas stream will be monitored continuously
   over four separate converter cycles.  A Teco continuous emission monitoring
   system will be used for this task.

A  Visible  and fugitive emission  observations will be made concurrent with the
   TSP/arsenic tests.  Method  22  will be used to qualify fugitive emissions
   around the  converter and  Method 9 for quantification of visible emissions
   above the secondary control system.

•  Particle size distribution  and the subsequent Inhalable paniculate emis-
   sion factors will be Measured  concurrent with the TSP/arsenic tests.
   Andersen Heavy Grain Load and  Mark 111 Inpactors will be used for this
   task. One  inpactor will  run over the entire converter cycle and a second
   Inpactor run only during  the converter blowing  mode.  At least four tests
   during four separate converter cycles are recommended.
                                   F-17

-------
                                                Section No. 	
                                                Revision No. 	
                                                Date:    SeDlember
1982
                                                                of
                      TABLE  4-2.  ASARCO ANALYTICAL PLAN
Sample
type
TSP
Arsenic
so2
Particle3
size
distribu-
tion
Visible and
fugitive
emissions
Tracer
quantity
EPA
Method 5
X
(8 sets)





Proposed
EPA
Method 108

X
(8 sets)




CEM System
(Pulse-
fluoresce)


X
(Continuous
+ Method 6
manual )



EPA
Methods
9 and 22




X
(5 days)

Gravimetric
Trace
metals
by size
fraction



X
(8 sets)


GC-
ECD
(SF6)





X
Upon completion of the gravimetric  analysis,  each  size  fraction will  be
analyzed for select trace metals  (arsenic,  cadmium,  lead,  antimony,  selenium,
and bismuth) by Atomic Absorption techniques.
                                     F-18

-------
                                          Section No. 	4
                                          Revision No. 	1
                                          Date:    September 10. 1982
                                          Pa9e     4     of     4
detailed  sampling plan will be prepared and approved  by the EPA

Project Officer prior to the Phase  II testing program.
                                F-19

-------
                                         Section No. 	£_
                                         Revision No.    Q_
                                         Date:    July 20  1982
                                         Page     1     of    1
                             SECTION  5

                         SAMPLE  CUSTODY



     Samples will be recovered,  identified,  and stored by the

procedures described in Section  4.0  of  the  PEDCo Environmental

Emission Measurement Quality Assurance  Plan which is contained

in Appendix B of the Quality Assurance  Program Plan.

     Samples are received,  logged, and  tracked in the laboratory

by the procedures described in Section  4.1  of  the PEDCo Environ-

mental Laboratory Quality Assurance  Plan  contained in Appendix C.
                               F-20

-------
                                        Section No. 	fc.
                                        Revision No.  	1
                                        Date:    September 10. 1982
                                                1     of      1
                            SECTION 6

              CALIBRATION PROCEDURES AND FREQUENCY



     All manual sample equipment to be used is calibrated before

and after each test program according to the procedures outlined

in Maintenance, Calibration, and Operation of Isokinetic Source

Sampling Equipment.   Additionally, onsite calibration checks

will be made prior to the start of testing to preclude the possi-

bility of equipment damage from packaging and transport.  The  S0»

CEM system will be calibrated daily using procedures described in

Performance Specification 2, Appendix B, 40 CFR.  The Perkin-

Elmer GC used for the SF, tracer study is calibrated daily as

described in Appendix A.

     Analytical instruments to be used such as the atomic absorp-

tion (AA) spectrophotometer will be calibrated for the specific

analysis each time a batch of samples is analyzed.  The standards

(minimum of four concentrations plus a blank) used for calibra-

tion are prepared from NBS traceable 1000 ppm solutions of the

individual metals.  These 1000 ppm stock solutions are purchased

from a commercial supplier.
*
  Office of Air Programs Publication No. APTD-0576.
                               F-21

-------
                                        Section No.      7
                                        Revision No.     0	
                                        Date:    July 20. 1982
                                        Page    1     of    2
                            SECTION  7

                      ANALYTICAL PROCEDURES



     The analytical procedures  specified  in  the  applicable EPA

Reference Methods will be followed as presented  in  the  methods.

Audit samples for the Method 3  (orsat) and Method 6 (S02)  analy-

sis will be supplied to PEDCo by the EPA.  In  addition,  PEDCo

will employ its own internal standard samples  for checking

accuracy and precision of the analytical  procedures used.   The

inhalable particulate (particle size) analytical procedures will

follow those described in Southern Research  Institute's Procedures

Manual for Inhalable Particulate Sampler  Operation.   The trace

metal analytical procedures are listed in Table  7-1.
                               F-22

-------
Section No.       7	
Revision No.      o	
Date:   July 20.  1982
Page    2
                                                             of
              TABLE 7-1.   TRACE METAL ANALYTICAL  PROCEDURES
Series/Analysis
Arsenic
Cadmium
Lead
Antimony
Selenium
Bismuth
Method No.1'2
206.2
213.1, 213.2
239.1, 239.2
204.1, 204.2
207.2
303A3
Methods for Chemical  Analysis of Water  and  Wastes,  U.S.  EPA,  EMSL,
Cincinnati, Ohio 45268,  March 1979,  Publication  No.  EPA-600/4-79-020.


Standard Methods for  the Examination of Water  and Wastewater,  15th ed.,
1980, American Public Health Association,  1015 18th Street  NW, Washington,
DC 20005.


If furnace techniques are required,  the procedures  used  are similar  to
those used for antimony  and the optimum range  is obtained from the Perkin-
Elmer methods supplied with the HGA-2200 Model Furnace.
                                   F-23

-------
                                         Section No. 	s_
                                         Revision No. 	n
                                         Date:    .Tilly 20   1 982
                                         Page    i   "   of    5
                             SECTION  8


            DATA ANALYSIS, VALIDATION,  AND REPORTING



     Where applicable,  all data will be calculated according to


the appropriate Reference Method  procedures.   A validated com-


puter program performs  most  test  method calculations.   The field


data sheets used are set up  on standard computer cards  to allow


accurate date input.  The data printout is then validated by


comparison with the field and analytical  data  sheets.   In addi-


tion, hand calculation  checks will be made onsite after each


emission test to verify that reference  method  criteria  regarding

isokinetics, etc., are met.  Figure  8-1 presents an  example

onsite calculation form.  Relative to the  SF,  tracer study,  the

hood collection efficiency will be calculated  as follows:

     Hood Collection Efficiency (E)  =


                          SFg injected  -  SFg measured
                                  SF6 injected
                                                       x  10°
     where:  SFg injected = fixed flow  (cc/min) x time  (minutes)

             SF  measured = concentration x gas flow rate
                            (ftVmin) x constant  (2.8317 x  10
                            cc/ft3)
                               F-24

-------
                                               8
Section No. 	
Revision No.      o	
Date:     July  20, 1982
Page     2     of     5

1 Vein"* of dr. gil ll«plW COrrfttfd to lUnd«rC Condi-
CAM "1
^^J •



?. Vcljmf O4 vatrr vIPC" «t iUifli'-d COfldMloni, ft .
v • o.wo'., •
'S13 '!
.
V
"i-e
B.l V - V
m •
StC ilO


0 i I i

5 Hr.let-li'- •fig'", o* stac» g*i
", • "o "-B.s' • le B« •

! 0
v . 8i.49Cr (^) "«• V rV •




7. ItokinelU »*riitiOn
\t, • \ • "•»
it - >td

», . D/ • 0 . F, . (l-lw)
'rp»

T
'b.r' '"' "«
TM. lr. H^O
TS. •(
V . DiC'
ltd
¥\' '
v . ft3
"lid

B.s
'••«
• co,
to,
• K^ • • '•?
«d. It). Ib-wrlf
«i. it>'ib-f!»ie
f . IP ft. ;

',• "- "'
T;.-R
7*
Cp
V%. FPS
D . ln-
1
, «iir.

1 1
««r 1



























lu> ?



























«u- }



























Figure 8-1.  Onsite calculation form.
                   F-25

-------
                                         Section No. 	8
                                         Revision No.      o
                                         Date:   July  20, 19R2
                                         Page    3     of    5
     All data generated by the laboratory is checked for techni-

cal accuracy by the analysts' supervisor.  This involves veri-

fying that the appropriate analytical method was used, the detec-

tion limit is appropriate, the proper number of significant

figures are reported, and the data were calculated properly  (this

is done by repeating the calculations for several samples).  The

data are then given to a second independent person  (Data Clerk)

who repeats all hand calculations and verifies all data entries

into computer programs.  The data is then reviewed by the Quality

Assurance Coordinator who reviews the data and the results of the

standard reference solutions and the results of duplicate analyses,

If these values are in control and the data is acceptable, he

initials the data sheets and returns them to the project manager.

If these QC values are not in control or the data is unacceptable

for any other reason, the Quality Assurance Coordinator discusses

the analysis with the project manager, and they determine the

appropriate action.
                               F-26

-------
                                          Section No. 	g_
                                          Revision No. 	Q_
                                          Date:    July 20,  1982
                                          Page     4     of    5
                         RAW DATA FLOW SCHEME
                              Analysts
                             Supervisor
                             Data  Clerk
                     Quality Assurance Coordinator
                           Project Manager
     All data summaries and  final reports will  be  reviewed and

approved by  the Project Director prior to release.   The final

report will  contain all of the  QA data generated during the course

of the project.  Figure 8-2  illustrates the report format and an

example Table of Contents.
                               F-27

-------
                                                Section No.       8
                                                Revision No.      0
                                                Date:   July  20. 1982
                                                Page    5        of    5
                                  CONTENTS


Figures

Tables

Quality Assurance Element Finder

1.   Introduction

2.   Project Data Summary

3.   Process Description and Operation

4.   Sample Locations and Test Methods Used

5.   Quality Assurance

6.   Discussion of Results

Appendix A - Computer Printouts and Sample Calculations

Appendix B - Raw Field Data

Appendix C - Laboratory Data

Appendix D - Sampling and Analytical  Procedures

Appendix E - Calibration Procedures and Results

Appendix F - Quality Assurance Summary

Appendix G - Project Participants and Activity Log
                           Figure 8-2.  Contents.
                                     F-28

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                                         Section No. 	9_
                                         Revision No.     0
                                         Date:    July 20. 1982
                                         Page    1     of	]_
                             SECTION  9


          INTERNAL QUALITY CONTROL CHECKS  AND FREQUENCY



     The routine emission measurement  and  laboratory quality


control procedures are contained  in  the  quality assurance plans


of these groups  (Sections 5  of Appendices  B and C).   In addition


all suggested quality control procedures contained  in Volume III


of the "Quality Assurance Handbook for Air Pollution Measurement


Systems - Stantionary Source Specific  Methods" are  followed in


both the field and laboratory.
                               F-29

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                                        Section No.      10
                                        Revision No.      1
                                        Date:    September  10. 1982
                                        Page    1      of      4
                           SECTION 10


                 PERFORMANCE AND SYSTEMS AUDITS



     Relative to the manual emission sampling associated with

this project, a total system audit technique is not presently

available.  However, an on-site qualitative inspection and review

of each manual measurement system will be performed by the PEDCo

project manager.  Although this inspection would normally be

performed by the quality assurance officer, the project manager

will perform this inspection for this project because of the cost

involved for an additional person on site.  During the systems

audit, the procedures and techniques of the field team will be

observed in the following areas:

     0    Sample train set-up and leak checks

     0    Isokinetic sample checks

     0    Final leak check and sample train disassembly

     0    Sample recovery and storage for shipment

     The SO  CEM system audit will be performed daily using

procedures described in Performance Specification 2  (40 CFR,

Appendix B).  Additionally, manual S0_ testing will be performed

simultaneously with monitor data collection to insure proper CEM

operation.  S02 audit samples supplied by EPA will be used to

check the accuracy of onsite S0_ titrations.
                               F-30

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                                         Section No. 	10
                                         Revision No. 	1
                                         Date:    September  10. 1982
                                         Page     2     of       4
     Figure  10-1  presents the onsite QA checks to be made on all

equipment used  in this  sample program.

     PEDCo Environmental  Laboratory voluntarily participates in

many externally administered  audit programs as described in

Section 5.4, page 5-9,  of the Laboratory Quality Assurance Plan.

In addition, the  Quality  Assurance Coordinator periodically sub-

mits sample(s)  to the laboratory for internal accuracy checks.

These samples may be for  a single analysis or for multi-

component analysis.
                               F-31

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                                             Section No.          10	
                                             Revision No.  	]	
                                             Date:      September 10.  1982
                                             Pa9e      3        of    4
                        ON-SITE  AUDIT DATA SHEET
Audit Name:
Date:
Auditor:
Equipment
Meter box
inlet thermo.
Meter box
outlet thermo.
Impinger
thermometer
Stack
thermometer
or
Thermocouple
Orsat
analyzer
Trip
balance
Barometer
Reference
ASTM-3F at
ambient temp.
ASTM-3F at
ambient temp.
ASTM-3F at
ambient temp.
ASTM-3F at
ambient temp.
ASTM-3F at
stack temp.
% Oj in
ambient air
IOLM std.
weight
Corrected*
NWS value
Reference
Value





20.8"


Value
Determined








Deviation








Max. Allowable
Deviation
5°F
5°F
2°F
7CF
See table
0.7'*
0.5 grams
0.20 in. Hg
Reference temp. °F
Max. deviation CF
32-140
7
141-273
9
274-406
11
407-540
13
541-673
15
674-760
17
 * Correction factor:

     NWS value (in. Hg) - [Altitude (ft)/1000(ft/in. Hg)]  +  0.74 in.  Hg**

** 0.74 in. Hg is the nominal  correction factor for the reference barometer
   against which the field barometer was calibrated.

If it is not feasible to perform the audit on  any piece of equipment, record
"N/A" in the space provided for the data.
                  Figure  10-1.   Onsite  QA checks.
                               F-32

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                                          Section No.        10	
                                          Revision No.	]	
                                          Date:     September  10.  1982
                                          Page     4        of      4
DATE: 	
BAROMETRIC PRESSURE (Pbar):
ORIFICE NO.
AUDIT REPORT DRY GAS METER
                 CLIENT:
ORIFICE K FACTOR:
         in. Ng   METER BOX NO.
        	   PRETEST  Y: _
                 AUDITOR:
Orifice Dry gas Temperatures
manometer meter Ambient Dry gas meter
reading reading T»
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                                          Section No.  	n
                                          Revision No. 	o
                                          Date:     July 20. 19R2
                                          Page     i    of    i
                            SECTION 11

            PREVENTIVE MAINTENANCE PROCEDURES AND SCHEDULES



      Section  7.0  of  the PEDCo Emission Measurement Quality

Assurance  Plan  describes in detail the routine activities per-

taining  to equipment maintenance.   Relative to this specific

project, daily  checks of sample  equipment accuracy and operation

will  be  made.   As  is standard procedure,  sufficient spare equip-

ment  will  be  shipped to the test site so  that if replacement of

defective  equipment  is  necessary,  it  will be accomplished with

minimum  downtime.


      Preventive maintenance schedules recommended by the  manu-

facturers  are followed  and  documented in  maintenance log  books

with  each major analytical  instrument.  Expendable  items  and

routine spare parts  are  also maintained with each instrument.

Non-routine items are covered under maintenance  contracts  with

instrument manufacturers which guarantee  rapid service.
                                F-34

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                                         Section No. 	12.
                                         Revision No. 	0
                                         Date:   July 20. 1982
                                                1      of	]_
                           SECTION 12


   SPECIFIC ROUTINE PROCEDURES USED TO ASSESS DATA PRECISION,
                   ACCURACY, AND COMPLETENESS
     Standard statistical techniques will be utilized  to  calcu-

late the accuracy, precision, and completeness of the  test  data.

Precision will be calculated on the standard deviation for  each

run and, if appropriate, for all samples collected by  a specific

method over the entire test period.  Precision estimates  will  be

used with standard statistical techniques to identify  outliers.

     The accuracy and precision of the arsenic test  (Proposed  EPA

Method 108) method has not been determined by EPA.   Additionally,

the accuracy and precision of the method used for the  tracer

study has not been established by EPA.  Data obtained  from  this

test project can be used to establish these criteria.   The  com-

pleteness of the measurements will be made using check-off  sheets

and through the tabulation of the data.

     The methods used to determine the precision and accuracy  of

the analytical methods are described in Sections 5.1 and  5.2 of

the Laboratory Quality Assurance Plan  (Appendix C).  Completeness

of the sample analysis will be based on the percent  of valid

analytical data obtained for the number of samples received.
                               F-35

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                                        Section No. 	U_
                                        Revision No.     0
                                        Date:    July 20. 1982
                                                1      of2.
                           SECTION 13

                        CORRECTIVE ACTION



     Section 5.6, page 5-8, of PEDCo's Emission Measurement

Quality Assurance Plan describes the routine approach to correc-

tive action relative to emission measurements.  Any samples not

collected according to an applicable Reference Method or other

approved means will be voided.  Any equipment found to be out of

calibration or not operating properly will be repaired or

replaced before additonal measurements are made.

     The analytical control limits for acceptable precision and

accuracy are given in Section 3.  If one or both of these values

are out of control, the Quality Assurance  (QA) Coordinator and

Project Manager will review the analysis and determine the

appropriate action to be taken.

     In all cases where standard procedures cannot resolve the

problem, the QA Coordinator and the Project Manager will deter-

mine the appropriate action.  This joint effort has several

advantages in troubleshooting an analysis.  The Project Manager

has daily contact with the procedures in the laboratory and

offers the detailed familiarity required.  The QA Coordinator

offers a broad general background and a fresh outlook, taking

nothing for granted.  This combination has proven itself in

giving rapid and reliable solutions to various problems.  The



                               F-36

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                                         Section No. 	13_
                                         Revision No.      0
                                         Date:   July 20, 1982
                                         Page    2      of   2
Project Manager will  be responsible for initiating the  action

and the QA Coordinator  is responsible for determining if  this

action has resolved the problem.
                               F-37

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                                         Section No. 	14.
                                         Revision No. 	0
                                         Date:    July 20. 1982
                                         Page     1     of	]_
                            SECTION 14


             QUALITY ASSURANCE REPORTS TO MANAGEMENT



     All quality assurance  procedures and results associated


with this project will  be  included in the final report.  Other


internal procedures are described in the appropriate quality


assurance plans  (Section 5.4,  page 5-8, of Appendix B and Section


5.6, page 5-9, of Appendix  C).
                               F-38

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          APPENDIX A




TEST AND ANALYTICAL PROCEDURES
             F-39

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                                         Section No.  Appendix A
                                         Revision No.      n	
                                         Date:   July 20. 1982
                                         Page    i     of  24
      SULFUR DIOXIDE CONTINUOUS EMISSION MONITORING SYSTEM


     The continuous emission monitoring system  (CEMS) is utilized

to continuously extract flue gas from the process and determine

the concentrations of sulfur dioxide  (S0~).

     The accuracy of the data provided by the CEM system is

dependent upon the gaseous stream analyzed as well as the correct

operation of the individual components of the system.  This

section describes the CEM system and the techniques which are

employed to ensure that a representative sample is extracted,

analyzed and reported with a high degree of accuracy.  The

extractive monitor to be used in this study for SO^ is listed

below.

   Gaseous Species  Principle of Operation  Vendor and Model No.

         S02          Pulse fluorescence          TECO 40


SAMPLING PROCEDURE

     The following are the five general functions that are per-

formed  during the testing period to assure representative data

by the  CEM system.

     1.    Extract a representative sample from the stack.

     2.    Condition the sample for the monitors by filtering out
          the particulate and removing moisture to provide a
          clean,  dry sample gas stream.

     3.    Transport the sample from the sampling port to the
          instruments without loss of sample integrity.
                               F-40

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                                        Section No.   Appendix A
                                        Revision No.     0	
                                        Date:   July 20, 1982
                                        Page    2      of  24
     4.   Provide for the introduction of calibration gases with-
          out disrupting sample flow.

     5.   Insure that the monitors will be sampling at a constant
          pressure, slightly above ambient.
SAMPLING METHOD

     The CEM sample is continuously drawn through a glass-lined

probe.  A sintered steel cylinder on the probe acts as a coarse

filter and a fine filter is placed just before the dryer.  Both

the probe and the fine filter are heated, and the intervening

line is insulated to prevent condensation and possible loss of

sample.  A blow back system is used to periodically clean the

coarse filter, and the fine filter is inspected daily and replaced

as necessary.  The dryer to be used is a Perma Pure Model PD

1000-24PS, located as near as possible to the sample port.  Com-

pressed air and a permeation tube type dryer provide an unter-

rupted stream of dry air.  Only Teflon sample lines are used, and

the exposed line is covered by a flexible sheath to prevent dam-

age.

     A one horsepower diaphragm pump is used to draw the sample

through the sampling interface and deliver it in excess to a

glass manifold.  The oversize pump guarantees rapid system

response to changes in stack conditions.  The monitor draws its

sample from the manifold and the excess is vented.  By restricting
                               F-41

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                                        Section No.   Appendix A
                                        Revision No.       0
                                        Date:    July  20,  1982
                                        Page     3     of    24
 the  flow at the vent,  a slight positive pressure (2.5 - 7.5 cm

 H20)  is  maintained  within  the manifold.  If the pressure drop

 across the  sampling interface changes during sampling,  a minor

 adjustment  at  the vent maintains  the manifold pressure.

      A second  manifold is  used for  the introduction of  calibra-

 tion  gases.  This calibration manifold pressure is  regulated to

 match the sample manifold  and thus  eliminate any pressure bias.

 The monitor  sample  line  has  a selection valve that  permits it to

 draw  from either manifold.   Thus  the monitor can be taken off

 line, calibrated and returned to  operation  without  interrupting

 the sample  flow.


      The monitors are  subjected to  a multi-point calibration at

 the start of the sampling  period.   The operator performs a zero

 and span check daily.  Any values that exceed + 5 percent of the

 expected reading results in  readjustment of  the monitor.   A

 second multi-point calibration is performed  at the  end of the

 sampling day to insure that  no deterioration  of monitor  response

 has occurred.


     Quality assurance procedures for  continuous monitors are

designed to insure:

     0    Sample integrity,

          Accurate monitor response, and

          Precise and complete data  capture.
o
o
                              F-42

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                                        Section No.   Appendix A
                                        Revision No.      Q	
                                        Date:   July 20. 1982
                                        Page   4	of  24
      The  sample  integrity is  demonstrated first by leak checking

 the  sampling  interface  from probe  to distribution manifold.   The

 absolute  leak rate  is not to  exceed  0.0005 m3  per minute.  Next,

 a known concentration of  S02  is  introduced at  the probe.   The

 analyzer  response to this gas is recorded for  at least  one

 sampling  cycle.  The same gas is introduced directly  into  the

 analyzer  and  compared with the response  of the sample line integ-

 rity  tests.   The two values must agree to within + 5  percent  or

 corrective action is taken.

      Assessment of  the  accuracy  of the analyzer is accomplished

 by introducing know concentrations of the appropriate gas

 directly  to the analyzer.


      Field data is  continuously  recorded  by HEATH/SCHLUMBERGER

Model SR-204  strip  chart  recorders.  The  field operator validates

the chart with date and time  during  the daily  calibrations.

Calibration values  as well  as  comments and  observations are

recorded  in the operator's  log book  for future reference.
                               F-43

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                                        Section No.  Appendix A
                                        Revision No.0
                                        Date:  July 20, 1982
                                        Page   a      of z*
         PROPOSED SAMPLING METHOD FOR THE DETERMINATION
   OF PARTICULATE AND ARSENIC EMISSIONS FROM A COPPER SMELTER


     The following method will be used in this test program.

Sampling procedures follow those described in Methods 5 and 108.

Tests will be conducted to determine filterable particulate

emissions and particulate and gaseous arsenic emissions using a

single sampling train.


SAMPLING APPARATUS

     The sampling train to be used in these tests will meet

design specifications established by the Federal EPA and will be

assembled by PEDCo personnel.  It will consist of:

     Nozzle - Stainless steel (316) with sharp, tapered leading
     edge and accurately measured round opening.

     Probe - Borosilicate glass with a heating system capable of
     maintaining a minimum gas temperature of 250°F at the exit
     and during sampling.

     Pitot Tube - Type S pitot tube that will meet all geometry
     standards and will be attached to the probe to monitor stack
     gas velocity.

     Filter Holder - Pyrex glass with heating system capable of
     maintaining a filter temperature of approximately 250°F.

     Draft Gauge - An inclined manometer made by Dwyer with a
     readability of 0.01 inches H20 in the 0 to 1 inch range
     will be used.
*
  EPA Method 108 has not been proposed and is presently  in  draft
  form.
                               F-44

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                                          Section No.  Appendix A
                                          Revision No.      0
                                          Date:   July 20, 1982
                                          Page    6     of  24
      Impincfers - Six impingers connected in series with glass
      ball joints.  The first, third, fourth, fifth, and sixth
      impingers will be the Greenburgh-Smith design, modified by
      replacing the tip with a 1/2 inch I.D. glass tube extending
      to 1/2 inch from the bottom of the flask.  The second impin-
      ger will be a Greenburgh-Smith design with the standard tip.

      Metering System - Vacuum gauge, leak-free pump, thermometers
      capable of measuring temperature to within 5°F, dry gas
      meter with 2 percent accuracy, and related equipment, to
      maintain an isokinetic sampling rate and to determine sample
      volume.  The dry gas meter is made by Rockwell and the fiber
      vane pump is made by Cast.

      Barometer - Bourden tube type to measure atmospheric pres-
      sures to + 0.1 inch Hg.


 SAMPLING PROCEDURE

      After selecting the sampling site and the minimum number of

 traverse points, the stack pressure, temperature, moisture, and

 range of velocity head will be measured according to procedures

 described in the Federal Register.*

      Approximately 200 grams of silica gel will be weighed and

 placed in a sealed impinger prior to each test.  Glass fiber

 filters** (3-in. diameter) will be desiccated for at least 24

 hours and weighed to the nearest 0.1 mg on an analytical balance.

 One hundred and fifty ml of deionized, distilled water will be

 placed in each of the first two inpingers, and 200 ml of 10 per-

 cent H202 will be placed in the third, fourth, anf fifth impin-

 gers.  The train will be set up with the probe as shown in Figure


   Federal Register,  Vol.  42, No. 160, August 18, 1977.
** Reeve Angel 934 AH.

                              F-45

-------
                                         Section No.   Appendix A
                                         Revision No.      0
                                         Date:   July 20, 1982
                                         Page   7      of 24
 1.  The sampling train will be  leak  checked  at  the  sampling  site

 prior to each test run by plugging the  inlet to the nozzle and

 pulling a 15 inch Hg vacuum, and at  the conclusion  of  the test  by

 plugging the inlet to the nozzle and pulling a  vacuum  equal  to

 the highest vacuum reached during the test run.

     The pitot tube and lines will be leak checked  at  the test

 site prior to each test run and at the  conclusion of each test

 run.  The check will be made by blowing into the impact  opening

 of the pitot tube until 3 or more inches of  water are  recorded  on

 the manometer and then capping  the impact opening and  holding it

 for 15 seconds to assure it is  leak  free.  The  static  pressure

 side of the pitot tube will be  leak  checked  using the  same pro-

 cedure, except suction will be used  to  obtain the 3 in.  H20

manometer reading.  Crushed ice will be placed  around  the impin-

gers to keep the temperature of the  gases leaving the  last

 impinger at 68°F or less.  The nozzle size will be  selected  to

maintain the isokinetic sampling rate below  1.0 cfm.

     During sampling, stack gas and  sampling train  data  will be

recorded at each sampling point and when significant changes in

stack flow condition occur.  Isokinetic sampling rates will  be

set throughout the sampling period with the  aid of  a nomograph

or calculator.   All sampling data will  be recorded,  on  the

Particulate Field Data Sheet (see Figure 2).
                              F-46

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     THCIWnCTCR
       SENSOR
REVERSE TYPE
 PI TOT TUBE
                                                                                THERMOMETER

                                    ORIFICE
                                    MANOMETER
                                                                                                               to ID  •*» <
                                                                                                                 ..  VI .
^ o •
                   Figure 1.   Particulate  and arsenic sampling  train.
                                                                                                               SJ

-------
                                                        EMISSION TESTING FIELD DATA
                                                           n« 1 Ml  1 IIMK I

                                                           11*1 m»  mtt

                                                           I'll '|l. -,!1 l» -ytll

                                            1 • I 1 I • I > 1 I I I i 1 1 I
                                                  l  t> -.n..^ l .j». ^(j2t«r«;Tr1,"il»l-ij-2*^—I  ,£m \mm\'m' ,|JT .1 "' I™

 I


00

                                                                   irirc >M«M
                                                                                iisa
                                                                                      1KH
                                                                                            vranr
                                                                                            •».  i.
                                                   Figure  2.   Emission  testing  field data.
                                                                                                                                       c* < O
                                                                                                                                       
-------
                                        Section No.   Appendix A
                                        Revision No.      o	
                                        Date:   July 20.  1982
                                        Page   10     of  24
SAMPLE RECOVERY PROCEDURE

     The sampling train will be moved carefully from the test

site to the cleanup area.  The weight of each impinger will be

determined prior to recovery for moisture determination.  Sample

fractions will be recovered as follows:

     Container No. 1 - The filter will be removed from its holder
     and placed in a petri dish and sealed.

     Container No. 2 - Loose particulate and acetone washings
     from all sample-exposed surfaces prior to the filter will be
     placed in a polyethylene container, sealed, and labeled.
     Particulate will be removed from the probe with the aid of
     a brush and acetone rinsing.  The liquid level will be
     marked after the container is sealed.

     Container No. 3 - After the probe and all sample-exposed
     surfaces prior to the filter have been rinsed with acetone,
     an additional rinse with 0.1 N NaOH will be performed,
     placed in a polyethylene container, sealed, and labeled.
     The liquid level will be marked after the container is
     sealed.

     Container No. 4 - The contents of the first two impingers
     will be transferred to a polyethylene container.  Each
     impinger will be rinsed twice with 30 ml of 0.1 N NaOH and
     the rinse added to the container.  The back-half of the
     filter holder and connecting glassware will be rinsed twice
     with 0.1 NaOH and the rinse added to the container.  The
     container will then be sealed, labeled, the liquid level
     marked,  and then stored.

     Container No. 5 - The contents of the third, fourth, and
     fifth impingers will be transferred to a polyethylene con-
     tainer.   Each impinger will be rinsed twice with deionized,
     distilled water, the connecting glassware rinsed twice with
     deionized, distilled water, and the rinses added to the
     container.  The container will be sealed, labeled, the
     liquid level marked, and then stored.
                                F-49

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                                         Section NO.  Appendix A
                                         Revision No.     o	
                                         Date:   July 2nr 19R2
                                         Page   11     of  24
     Container No. 6 - A minimum of 200 ml of the acetone will be
     taken for blank analysis.  The blank will be obtained and
     treated in the same manner as the rinse.

     Container No. 7 - A minimum of 200 ml of ieionized, distilled
     water will be taken for blank analysis.  The blank will be
     obtained and treated in the same manner as the rinse.

     Container No. 8 - A minimum of 200 ml of H2C>2 will be taken
     for blank analysis.  The blank will be obtained and treated
     in the same manner as the rinse.

     Container No. 9 - A minimum of 200 ml of 0.1 N NaOH will be
     taken for blank analysis.  The blank will be obtained and
     treated in the same manner as the rinse.

     The silica gel from the sixth impinger will be weighed and

recorded on the Sample Recovery and Integrity Data Sheet with

other pertinent data.


ANALYTICAL PROCEDURES

     The following procedures will be used.  These are  fully

described in EPA Methods 5 and 108.

     Container No. 1 - The filter and any loose particulate will
     be dessicated for 24 hrs. to a constant weight and weighed
     to the nearest 0.1 mg.  After a final weight has been
     obtained the filter will be digested in a 150 ml beaker
     using 0.1 N NaOH followed by concentrated HN03.  The solu-
     tion will be filtered.  The filtrate will be boiled and
     evaporated to dryness.  Nitric acid will then be added and
     and the sample diluted before analysis by atomic absorption
     spectrophotometry.  If any solids remain on the filter, the
     filter will be digested in a PARR acid digestion bomb using
     HNO., and HF prior to analysis.

     Container No. 2 - The acetone washings of the nozzle probe
     and front half of the filter holder will be transferred to
     a tared glass beaker, evaporated to dryness at ambient
     temperature and pressure, dessicated for 24 hours  to a
     constant weight, and weighed to the nearest 0.1 mg.
                                F-50

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                                         Section No.   Appendix A
                                         Revision No.     0
                                         Date:   July  20,  1982
                                         Page    12      of  24
      Container  No.  3  -  The o.l  N NaOH  rinses  of  the  probes  and
      exposed  surfaces will be combined with the  residue  from
      Container  No.  2.   The resulting solution will be diluted and
      a  50 ml  aliquot  will  be removed and  digested using  HNO,
      before arsenic analyses.

      Container  No.  4  and No. 5  - The contents of these two  con-
      tainers  will be  diluted.   An aliquot will be taken  and
      digested with  HN03 before  final dilution and atomic absorp-
      tion analysis.

      The term "constant weight"  means  a difference of no more

than  0.5 mg or  1 percent of total weight  less tare weight,  which-

ever  is greater between two consecutive readings, with no less

than  6 hours  of desiccation between weighings.   All  analytical

data  are recorded on  the Analytical Data  Sheet and appropriate

Blank Data Sheet.

     All blanks will  be digested and analyzed using  the  same

procedures as the corresponding  sample fraction.

     The samples will be analyzed on an atomic absorption

spectrophotometer.  The solutions will first  be  analyzed using

the flame techniques  as outlined in EPA Method 108.  However, if

the samples are below the  flame  detection limit, the furnace

technique (heated graphite  furnace) will  be employed.  Possible

matrix effects  for either method will  be  checked using the

"Method of Additions".
                                 F-51

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                                        Section No.   Appendix A
                                        Revision No.     Q	
                                        Date:   July 20. 1982
                                        Page   13     of  24
                        SF6 TRACER STUDY



     A tracer mass balance study will be conducted to estimate

the capture efficiency of the air curtain control system.  A

suitable tracer will be quantitatively injected in selected

locations within the controlled area.  Measurements of the tracer

concentration at the sampling point, combined with flow rate

measurements, will permit the calculation of the amount passing

the sampling point (i.e., the amount collected by the hood).  The

collection efficiency can then be calculated from the amount

injected and the amount captured.  The tracer technique, if

proven successful, could be utilized to quantitatively optimize

the secondary hood operation.  Also, if successful, the tracer

will be used during the full field tests conducted in Phase II

to assure that a reasonable collection efficiency is being

achieved during the sampling program for SC>2 / particulate, and

arsenic capture efficiency and loadings.

     Sulfur hexafluoride (SF,) has been selected as the tracer.
                            b

SF, is a colorless, odorless, tasteless gas  that is not flam-

mable and is completely nontoxic.  Also SF,  is stable up to a

temperature of 500°C (932°F).  Additionally, the minimum detec-

tion limit for SF, is 5 parts per trillion using GC electron

capture analytical technique.  Information furnished by Asarco
                               F-52

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                                         Section No.   Appendix A
                                         Revision No.     0
                                         Date:    July  20,  1982
                                                 14    of   24
 regarding the temperatures expected within the controlled area

 indicate that thermal decomposition could not be expected.

      SF6 analysis will be performed using a Perkin-Elmer Model

 3920 gas chromatograph equipped with a Ni-63 electron capture

 detector and a Valco gas sampling valve with a 1 ml sampling

 loop.   Operating conditions will be:  nitrogen carrier gas (120

 ml/min),  injector and oven heated to 55°C,  and detector heated

 to 250°C.   The analytical column will be an 8 ft.  long by 1/8 in,

 diameter  nickel tube packed with 70/80 mesh molecular sieve 5A.

 All  sampling lines and connectors will be Teflon or stainless

 steel.


     An exponential dilution system will be used in constructing

 calibration  curves.   Equipment  required for the  system calibra-

 tion will  include  a mass  flow meter,  a magnetic  stirrer and

 stirbars,  a  Pyrex  1 liter  round  bottom flask,  a  tank of zero

 grade nitrogen,  and miscellaneous  glass and Teflon  tubes  and

 fittings.


     The electron  capture  detector's  response  to SF,  will  be
                                                    6

determined with  a  conventional strip  chart  recorder.   Peak

heights will be measured to  determine  response and  compared to

calibration curves  prepared  using  the  exponential dilution sys-


tem immediately prior to analysis  to determine actual  concentra-

tions of SF,.
           D
                               F-53

-------
                                         Section No.   Appendix A

                                         Revision No.       0
                                         Date:  July 20, 1982

                                               15     of 24
      The  electron capture detector has a linear response to



 concentrations  of SFg  ranging from 10~7 to the minimum detectable



 level of  approximately 5  x 10~12.   An exponential Dilution System



 (as  shown in  Figure  1)  will be used to prepare standards over



 this  concentration range.   A one  liter round bottomed flask is



 used  as a mixing  chamber  with a magnetically driven stirrer to



 assure good agitation.  Zero nitrogen flows through the system



 at a  constant rate.  A known amount of gaseous SF, is then
                                                  6


 injected  into the flask and the time recorded.   The concentration



 of SFg in the flask  at any time can then be calculated from the



 equation:



                             -N
                    C = C  -e
                         o
where CQ is the initial concentration of  SF   in  the  flask,  N  is



the number of gas changes, and e  is a constant 2.7183.   Calibra-



tions will be performed daily and will take approximately two



hours to generate the calibration curve.



     In use, instrument response  (peak height) is plotted against



calculated concentration on semi-log paper to obtain  calibration



curves.  Actual sample concentrations then can be found  by  com-



paring responses to the curve, or more accurately, calculated



from the slope of the curve and sample response.
                              F-54

-------
                                                          Appendix A
       Section No. 	
       Revision No. 	0
       Date:   July  20.  1982
       Page    16      of  24
                                        SAMPLE
                                         LOOP
           ACTIVATED
            CARBON
            FILTER
  ZERO
NITROGEN
             DILUTION
             FLASK
            SAMPLING
            VALVE
                       O
                     MAGNETIC
                     STIRRER
PERKIN-ELMER
     GAS
CHROMATOGRAPH
                                                        MASS FLOWMETER
               Figure 1.   Exponential dilution system.
                                F-55

-------
                                         Section No.  Appendix A
                                         Revision No.0
                                         Date:  July  20,  1982
                                         Page   17      of 24
     After the daily calibrations are completed, samples can be

analyzed approximately every 5 minutes.  Numerous samples can be

analyzed daily.

     A brief laboratory evaluation will be performed to determine

if SF, losses occur in the Tedlar bags to be used to collect the

actual samples.  SF, will be placed in the sample bags and ana-

lyzed over a period of time to determine any losses.  Moisture

should not be a problem since only ambient air moisture will be

in the gas.

     Background tests to determine the presence of any SF6 will

be performed prior to the hood capture efficiency tests.  Back-

ground tests will be obtained by collecting flue gas samples from

the exhaust duct and from the air around the converter mouth in

Tedlar bags and analyzing for SF,.

     Tracer recovery tests will be performed by quantitatively

injecting a constant rate of SF, directly into the secondary

(capture) hooding and determining the SF, concentration and air

flow rates at the exhaust sampling location.  This data will be

used to account for any system or measurement biases.  Ideally

the amount injected should equal the amount measured in the

exhaust duct at the sampling point.  About 2.5 cc/min of tracer

gas are needed to yield 1 ppb in 100,000 acfm.
                               F-56

-------
                                        Section NO.    Appendix A
                                        Revision No.      0
                                        Date:   July 20.  1982
                                               18    of   24
     Figure 2 illustrates the equipment to be used to inject the

SFg at the designated traverse points.  A constant pressure will

be maintained on the limiting orifice to ensure a constant injec-

tion flow rate.  The limiting orifice will be calibrated prior to

and after each test run by using a bubble meter.  SFfi injection

rates will be determined based on the air flow rate in the

secondary hood duct and the desired SFg concentration for accu-

rate analysis.  Also, the temperature at each injection point

will be monitored during the injection of SFg to ensure that

decomposition is avoided.  The tracer will be injected over a

selected time period or operation mode as required.

     Integrated samples of the secondary hood flue gas will be

collected at the downstream sampling location.  Samples will be

obtained by pulling a constant rate at the point of average

velocity in the exhaust duct into a leak-free Tedlar 15 liter

bag.  Samples will be collected over a selected time period or

operational mode as required.  Sampling rates will be dependent

on the selected sampling period.  Figure 3 shows the sampling

train to be used to collect the samples.  The sample bags will be

transferred to the onsite laboratory for immediate analysis.
                              F-57

-------

                        PRESSURE REGULATOR

                             TEFLON SAMPLE LINE
I
  INJECTION PROBE
(3/8 1n. STAINLESS
      TUBING)
 i
un
oo
                                 LIMITING
                                 ORIFICE
                                             THERMOCOUPLE
                                             THERMOCOUPLE
                                               LEAD WIRE
               CYLINDER
                OF SF,
   DIGITAL
   READOUT
                                        -OO
                                        tu o>
                                                                                                               r* < O
                                                                                                             n> n> ->. <-*•
                                                                                                                 VI -*.
                                                                                                                 _•. o
                                                                                                                 o 3
                                                                                                               c,3*
                                                                                                               C zo
                                                                                                               K)
                                                                                                               O
                                                                                                             ro
                                                                                                             *.
                               Figure  2.   SFg  injection apparatus.
                                                                                     vo
                                                                                     CO
                                                                                     M
                                              (0

                                              Cb
                                              H-
                                              X

-------
                                             STAINLESS
                                            STEEL  PROBE
'•$
1
\,3
f
LEAK FREE
TEDLAR BAG
\ J



FLOW CONTROL
1 VALVE
t
-1 Trn r
                                    TEFLON
                                  SAMPLE LINE
     TEFLON LINED
     DIAPHRAM PUMP
                                                                           T3O JO CO
                                                                           o> o>  o> n>
                                                                           ua r* < o
                                                                           ro ep  -«•«-»•
                                                                             ..(/!-••
                                                                                -*• o
                                                                                O 3
                                                                           NJ
                                                                           O
r7 Z O
  O •
                                                                              N)
                                                                                0(D
                                                                              ID
                                                                              00
                                                                              to
Figure 3.   SF, sampling  train.

-------
                                        Section No.    Appendix A
                                        Revision No.       Q	
                                        Date:   July 20.  1982
                                        Page    2]	of  24
        PARTICLE SIZING AND SELECTED TRACE METAL ANALYSIS



     A particle size run will be performed simultaneously with

a particulate sample run during an entire converter cycle.  A


total of four entire converter cycles will be sampled during the

testing period.  In addition particle size runs will be separately

performed during the slag blow and finish blow portions of each

converter cycle.

     Sampling will be conducted following essentially the pro-

cedures outlined in the IP Protocal.  Due to the nature of the

process some modifications to the IP Protocol will have to be

made, i.e. a reduction in the number of sample runs due to the

length of each converter cycle.

     An Andersen heavy grain loading impactor  (HGLI) attached to

a 15 ym cyclone precutter as shown in Figure A-l will be used to

collect samples over the entire converter cycle.

     The Andersen HGLI and cyclone precutter combination separate

the particulate emissions into a total of five separate size

ranges which are approximately >15 ym, 15 ym to 11 ym, 11 ym to

6 ym, 6 ym to 1.5 ym, <1.5 ym.  Each sample run will consist of

testing four sampling points of average velocity for about the

same period of time  (- 2.5 hours each)


     The five sample fractions collected during each sample run

will be separately recovered and each fraction will initially be
                             F-60

-------
                   Section No.    Appendix A
                   Revision No.  	0	
                   Date:    July 20,  1982
                   Page     22
                                                                of   24
                                  METER BOX
                                                             ACCELERATION
                                                    VENT TUBE-\  /-JET
          PROBE TUBE
GLASS-FIBER
  THIMBLE
                                                                     »- FLOW
                ISOKINETIC
 SECOND-^ L FIRST     PROBE
IMPACT ION IMPACT ION
  STAGE   STAGE
Figure A-l.   Andersen  Heavy Grain  Loading  impactor sampling train.
                                 F-61

-------
                                         Section No.  Appendix A
                                         Revision No.     o	
                                         Date:    July 20, 1982
                                         Page    23    of   24
gravimetrically  analyzed  to  determine  the  percent of the total

particulate  in each  size  range.   Each  sample  fraction will  then

be analyzed  by atomic  absorption  spectrometry (AA)  to determine

the concentration of six  selected metals  (arsenic,  cadmium,  lead,

antimony, selenium,  and bismuth)  in  the gas stream.   A Perkins-

Elmer Model  550  will be used to analyze the samples for the

selected trace metals.

     During  the  slag blow and  finish blow  portions  of each

converter cycle  separate  Andersen Mark III impactors (Figure

A-2)  attached to a 15  ym  cyclone  precutter will  be  used to per-

form particle size runs.  The  Andersen Impactor  and cyclone

precutter combination  provides mine  sample fractions.   At the

completion of each sample run  the nine sample  fractions will be

separately recovered and  each  sample fraction  will  be analyzed

following the same procedure used for the  Anderson  HGLI sample

runs.

     If the grain loading is heavy and causes  overloading of

any stages of either impactor during a sample  run it  will be

replaced by another impactor cyclone combination  sampler and

sampling continued.
                              F-62

-------
                                 Section No.   Appendix  A
                                 Revision No.       0
                                 Date:   July 20,  1982
                                 Page    24      of  24
                                KETER BDX
                            PRE1HPAC10R
Figure A-2.   Andersen  Mark  III impactor sampling train
          with  preimpactor  and heating system.
                     F-63

-------
                               PEDCO ENVIRONMENTAL, INC.
                                                   1 14B9 CHESTER HO AD
                                                 CINCINNATI. OHIO 48246
                                                       (813)782-4700
                                               TELECOPIER (813) 782-48O7
                      PEDCo  ENVIRONMENTAL, INC.

                        EMISSION MEASUREMENT

                       QUALITY ASSURANCE PLAN
 Approved by:
^2^^/^
                          ,  Senior Vice  President,
                            Corporate Quality
                            Assurance Coordinator
                                          Division Director
                                         , Division Quality
                                          Assurance Coordinator
                         Revised January  1982
                               •RANCH OFFICES
CHESTER TOWERS
                      DALLAS. TEXAS

                   KANSAS crnr. MISSOURI
                           COLUMBUS. OHIO

                        DURHAM. NORTH CAROLINA
                                ?-64

-------
                            CONTENTS
Figures                                                     iii
Tables                                                      iv
List of Individuals Receiving the Emission Measurement       v
 Quality Assurance Plan

1.0  Introduction                                           1-1

2.0  Organization and Responsibilities                      2-1

     2.1  Director                                          2-1
     2.2  Associate Director                                2-1
     2.3  Group Supervisor                                  2-3
     2.4  Associate Group Supervisor                        2-3
     2.5  Quality Assurance Coordinator                     2-3
     2.6  Associate Quality Assurance Coordinator            2-4
     2.7  Group Leaders                                     2-4
     2.8  Project Managers                                  2-5
     2.9  Quality Control Technician                        2-5
     2.10 Technicians                                       2-5

3.0  Methods                                                3-1

4.0  Chain of Custody                                       4-1

5.0  Quality Control                                        5-1

     5.1  Accuracy                                          5-1
     5.2  Precision                                         5-5
     5.3  Data validation                                   5-5
     5.4  Reports                                           5-9
     5.5  Performance evaluations                           5-9
     5.6  Corrective action                                 5-9

6.0  Calibration                                            6-1

7.0  Preventive Maintenance                                 7-1

     7.1  Short Interval Inspection                         7-1
     7.2  Replacement of Damaged or Obsolete Components     7-1
     7.3  Scheduled Disassembly and Overhaul                7-2

8.0  Training                                               8-1
                               F-65

-------
                             FIGURES

Number                                                      Page

 1-1      Organization of Corporate Quality Assurance       1-2

 2-1      Organizational Chart                              2-2

 4-1      Three Part Sample Label                           4-2

 4-2      Particulate Sample Recovery and Integrity Sheet   4-3

 5-1      Audit Report of Method 5 Meter Box                5-2

 5-2      Example On-Site Quality Assurance Checklist       5-7

 5-3      Example Emission Test Report Table of Contents    5-9

 5-4      Example Emission Test Report Quality Assurance
            Element Finder                                  5-10

 6-1      Full-Scale Dry Gas Meter Calibration Data Sheet   6-3

 6-2      Post Test Dry Gas Meter Calibration Data Sheet    6-4
                               F-66

-------
                             TABLES




Number                                                      Page
 5-1      Reagent Blank Analysis                            5-4



 6-1      Field Equipment Calibration                       6-5
                              F-67

-------
     LIST OF INDIVIDUALS RECEIVING THE
EMISSION MEASUREMENT QUALITY ASSURANCE PLAN
    Charles E. Zimmer
    Lawrence A. Elfers
    Thomas J. Wagner
    K. Wade Mason
    Chuck L. Bruffey
    Phillip J. Schworer
    Dale A. Hershey
    John W. Prohaska
    Thomas R. Clark
    William G. DeWees
    James L. Iverson
    Bruce A. Armstrong
                   F-68

-------
                        1.0  INTRODUCTION






     Figure 1-1 presents the corporate quality assurance organiza-



tion and illustrates the relationship of the emission measurement



group's quality assurance activities to the total corporate



quality assurance effort.  Mr. Zimmer is the Senior Vice President



of PEDCo Environmental.  Mr. Zimmer is trained in statistics and



has over 20 years experience in the environmental field.



     The principal function of the PEDCo Environmental Emission



Measurement Group is to provide reliable assessments of emissions



from stationary sources.



     Quality assurance is the sum of all those activities in



which the emission measurement group is engaged in that will



ensure the validity of the data generated.



     Quality assurance is not restricted to the development and



retention of quality control (QC) charts, but rather includes all



activities that affect the results produced.  These activities



include, but are not restricted to, procurement of equipment and



supplies, maintenance and calibration of equipment, education of



personnel, sample handling, and reporting of results.



     The purpose of this manual is to outline the quality assur-



ance activities of the PEDCo Environmental Emission Measurement



Group.
                              F-69

-------
Tl

-j
o
              Field Studies
              and Labortory
                T.  Wagner
                                                  Quality  Assurance  Activity
                                                   C.E.  Zimmer,  Coordinator
                                               E.W.  Koesters,  Ass't.  Coordinator
Engineering
  D.  Henz
Data Reduction,
 Presentation
 and Analysis
  C. Zimmer
                                                       PEDCo


                                                     President
  Report
Preparation
M. Phillips
                                   Figure 1-1.  Organization of corporate quality assurance.

-------
             2.0  ORGANIZATION AND RESPONSIBILITIES


     The organization of the PEDCo Environmental Emission Measure-

ment Group is designed to provide an efficient flow of admini-

strative, technical, quality assurance, and advisory activities

throughout its operation.

     The organization chart is presented as Figure 2-1,  and the

responsibilities of the staff are outlined below.


2.1  DIRECTOR

     The responsibilities of the Director are as follows:

     0    Set objectives for the Field Studies/Laboratory Division.

     0    Plan the Division's course and policies.

     0    Organize the personnel, facilities, equipment, and
          materials into a coherent organization that can fulfill
          the Division's plans.

     0    Integrate the various parts of the organization.

     0    Measure the success in achieving the objectives.

     0    Resolve problems.


2.2  ASSOCIATE DIRECTOR

     The responsibilities of the Associate Director are as follows:

     0    Coordinate the activities of the Field Studies/Laboratory
          Division.

     0    Primary administrative contact with regulatory and
          accreditation agencies.
                            F-71

-------
I
«J
N)
                W.  DeWees
            Training Director
L. Elfers, Director
E. Koesters, Assoc. Director



W. Mason
Group Supervisor



C. Bruffey
Associate Group Supervisor




T. Wagner
Quality Assurance Coordinator


T. Clark
Associate
Quality Assurance Coordinator


B. Armstrong
Quality Control Technician


P. Schworer
Group Leader
Compliance Testing


Project Managers



D. Hers hey
Group Leader
Organics

Project

Managers



J. Iverson
Group Leader
Technical Support


Technicians



J. Prohaska
Group Leader
Source Test Related

Project

Managers
                                             Figure 2-1.  Organizational chart.

-------
          Assist the Director in the implementation and supervi-
          sion of administrative operations.

          Provide liaison with clients.
2.3  GROUP SUPERVISOR

     The responsibilities of the Group Supervisor are as follows:

     0    Set objectives for the Emission Measurement Group.

     0    Plan the Group's course and policies.

     0    Organize the personnel, facilities, equipment, and
          materials into a coherent organization that can fulfill
          the Group's plans.

     0    Integrate the various parts of the organization within
          the Group, Division, and Company.

     0    Measure the success in achieving objectives.

     0    Resolve problems.


2.4  ASSOCIATE GROUP SUPERVISOR

     The primary responsibilities of the Associate Group Super-

visor are as follows:

     0    Coordinate the activities of the Emission Measurement
          Group.

     0    Assist the Group Supervisor in the implementation and
          supervision of administrative operations.

     0    Provide liaison with clients.

     0    Evaluate performance of the Group and advise Group
          Supervisor of overall activities and performance.


2.5  QUALITY ASSURANCE COORDINATOR

     The responsibilities of the Quality Assurance Coordinator

are as follows:

     0    Develop, coordinate, and evaluate the quality assurance
          plans within the Division.
                             F-73

-------
     0    Review performance evaluation results.

     0    Evaluate methods and procedures.

     0    Act as technical advisor to Group Supervisors.

     0    Issue, prepare, and evaluate audit samples.

     0    Develop quality assurance plans for special  projects.


2.6  ASSOCIATE QUALITY ASSURANCE COORDINATOR

     The responsibilities of the Quality Assurance Coordinator

are as follows:

     0    Develop, coordinate, and evaluate the quality assurance
          program for the Group.

     0    Conduct routine checks on quality assurance  items.

     0    Review performance evaluation results.

     0    Evaluate methods and procedures.

     0    Act as technical advisor to Group Leaders.

     0    Develop quality assurance plans for special  projects.


2.7  GROUP LEADERS

     The primary responsibilities of the Group Leaders are as

follows:

     0    Coordinate activities of the specific group  in the
          areas of personnel assignments and project participa-
          tion.

     0    Provide technical guidance as required for project
          managers.

     0    Train Group personnel.

     0    Perform as project directors and project managers.

     0    Provide liaison with clients.
                             F-74

-------
2.8  PROJECT MANAGERS

     The primary responsibilities of the Project Manager are as

follows:

     0    Manage day to day activities of on-going projects.

     0    Provide technical support to other groups as required.

     0    Participate as a team member on selected projects.


2.9  QUALITY CONTROL TECHNICIAN

     The primary responsibilities of the Quality Control Techni-

cian are as follows:

     0    Oversee or perform all equipment calibrations.

     0    Maintain all quality control charts and records.

     0    Develop and revise quality control procedures.


2.10 TECHNICIANS

     The primary responsibilities of the technicians are as

follows:

     0    Participate as a team member on assigned projects.

     0    Perform equipment calibrations, data collection, main-
          tain records, etc., as required.

     0    Perform assignments as assigned by project managers.
                             F-75

-------
                          3.0  METHODS






     The PEDCo Environmental  Emission Measurement Group normally



uses published test methods;  e.g., New Source Performance Test



methods published in the Federal Register (40 CFR Part 60),  and



methods adopted for state and local code enforcement.  Specialized



test work often requires the  development of special test methods



or modifications of methods that were developed for purposes



other than stationary source  evaluation.



     The most often used methods are reviewed and modified as



necessary.  New Source Performance Test methods are kept current



through the use of the PEDCo  Environmental Library which tabu-



lates changes to the New Source Performance Standards Compilation



Manual.  Copies of the compilation manual are provided to all



Project Managers and Supervisory personnel in the Emission Mea-



surement Group.  State and local regulations are kept current by



procuring copies from each subject agency whenever changes are



made.  Copies of these regulations are maintained in a file cab-



inet located in the clerical  area which supports the Emission



Measurement Group.
                              F-76

-------
                      4.0  CHAIN OF CUSTODY






     Samples are recovered from the sampling train after each



test.  Sample recovery is carried out in a suitable area shel-



tered from wind and dust to prevent contamination of samples.



Sample recovery procedures outlined in the applicable test



method are followed in detail (usually 40 CFR, Part 60).  All



sample containers are identified using the appropriate section of



the three-part sample label (Figure 4-1).  One section of the



sample label is attached to the field test data sheet for positive



identification purposes.  After recovery, all sample containers



are sealed.  The height of the liquid level is marked on all



containers containing liquid samples to indicate if any sample



was lost during shipment and to assist in quantitatively deter-



mining the correct sample volume when sample is lost.  Data



relative to samples, collected during each test, are recorded on



a sample recovery and integrity data sheet (Figure 4-2).  Samples,



along with the sample recovery and integrity data sheets, are



under the custody of the Project Manager until custody is trans-



ferred when samples are turned over to the laboratory.  Sample



storage boxes with padlocks are used to store samples in the



field and to transport samples to the laboratory.  Custody pro-



cedures followed in the laboratory are presented in the PEDCo



Environmental Laboratory Quality Assurance Plan.
                             F-77

-------
 I
~J
00
PLANT CITY 54
PN: SAMPIE TYPE
DATE RUN NUMBER
FRONT RINSE D FRONT FILTER Q FRONT SOLUTION D
BACK RINSE D BACK FILTER D BACK SOLUTION D
RINSE IFVFI MARKED
VOLUME: INITIAI FTNAI







to
Cl EAN-IIP RY £


y
CORRESPONDING BIANK CONTAINER NO, , #







.



o


o



z
CO
or -
LLJ
t—
_j
li.

a




i
ac
tt
•8

CO *^ CO
co •«*• z *V
3 10 = 10
mm
                                              Figure 4-1.  Three part sample label.

-------
                  PARTICULAR SAMPLE RECOVERY AND INTEGRITY SHEET
Plant
Simple location
Run number
Filter number(s)
Impingers
Final volume (wt)
Initial volume {wt)
Net volume (wt)
Description of Impinger water

Total moisture
Sample date
Recover^ date
Recovered by

MOISTURE
Silica gel
nl(g) Final wt
»l(g) Initial wt
»l(g) Net wt
% spent

8



9
9
9

   Filter container number(s) 	

   Description of partlculate on filter
 RECOVERED SAMPLE

	 Sealed
   Probe  rinse
   container no. 	

   	blank
   container no. 	

   Impinger contents
   container no.   	

          blank
   container no. 	

   Samples stored and locked

   Remarks 	
    Liquid level
    narked

    Liquid level
    Burked

    Liquid level
    marked

    Liquid level
    wrked
                                LABORATORY CUSTODY
   Received by

   Remarks
                  Date
Figure  4-2.   Particulate  sample recovery and  integrity sheet.
                                   F-79

-------
                       5.0  QUALITY CONTROL






     Reliability in stationary source testing is maintained



through strict adherence to quality control procedures.  PEDCo's



procedures are designed to control both the accuracy and preci-



sion of the test results.





5.1  ACCURACY



     Accuracy is maintained through rigorous calibration proce-



dures using the standards specified in the methods and/or Volume



III of the Quality Assurance Handbook for Air Pollution Measure-



ment Systems, use of control samples where appropriate, and per-



formance and systems audits.  The accuracy of source test capa-



bilities is monitored through voluntary participation in EPA's



stationary source audits for coal and Methods 3, 5, 6, and 7.



5.1.1  Performance Audit



     Performance audits are conducted during the sampling and



analytical phases of the test program.  The volumetric flow



metering device is audited during the sampling phase using a



critical orifice.  This audit is conducted once on each metering



device during each field test,  using procedures outlined in



Volume III of the Quality Assurance Handbook for Air Pollution Mea-



surement Systems.  Figure 5-1 illustrates the data presentation and



calculations format for a critical orifice audit of a Method 5
                              F-80

-------
DATE:
AUDIT REPORT DRY GAS METER



                CLIENT:
BAROMETRIC PRESSURE (Ph.r): 1n.
ORIFICE NO.

Ng NETER BOX NO.
PRETEST v

ORIFICE K. FACTOR: AUDITOR:

Orifice Dry gas
manometer meter
reading reading
AH VVf
in H20 ft3





Temperatures
Ambient Dry gas meter
T.i/Taf T ™fi
"F »F


Outlet
To/7of


Duration
of
run
9
min


Dry gas Average temperatures
meter Ambient
volume
V T,
in a
ft3 -F


Dry gas V
meter m$td
°F ft3

V",c,
ft3

Audit
>

deviation


"std
07.647)( Vm )(Pbar * AH/13.6)
(Tm * 460)

Audit -y
y
in
y

Xct
(1203H


p
(7a
)( * >
*460)'^"


•Y deviation, J
(T audit
• Y pre-test)(100'.)
(> audit)

Audit i Dust  be In the range, pre-test y *0.05
      Figure 5-1.   Audit report of Method 5 meter box.
                                F-81

-------
meter box.  Barometers, thermometers, nozzles, and other equip-

ment used during the field test phase are audited to ensure the

collection of acceptable data.  Copies of all internal quality

control procedures and data sheets are contained in the PEDCo

Environmental Emission Measurements Quality Control Procedures

Manual.

     Blanks of reagents used to collect, recover, and analyze

samples are collected to check the quality and ensure that

reagents meet criteria established in the test methods.  Table

5-1 presents results of the analyses of acetone and water blanks

that were collected during a particulate test program.

     When analyses are conducted in the field, audit and control

samples are analyzed to ensure the accuracy of results.  Samples

analyzed in the laboratory are subject to the stringent quality

controls exercised in the laboratory.  (See PEDCo Environmental

Laboratory Quality Assurance Plan.)

5.1.2  Systems Audit

     The systems audit consists of an on-site qualitative inspec-

tion and review of the total measurement system.  This inspection

is conducted on a random basis by the quality assurance coordi-

nator or another senior individual with extensive background

experience in source sampling.  During the systems audit, the

auditor observes the procedures and techniques of the field team

in the following general areas:

     0    Setting up and leak testing the sampling train
     0    Isokinetic sampling check of the sampling train
                              F-82

-------
                    TABLE 5-1.  REAGENT BLANK ANALYSIS
Type of blank
Particulate blanks:
Acetone
Water
Particle size blanks:
Acetone
Analytical blanks:
Ether/chloroform
Container
No.
1228A
1229A
3823A
BU630
Volume of
blank, ml
537
500
221
150
Weight after
evaporation and
desiccation,
mg/ga
+0.0061
+0.0052
+0.0074
0.004
Comments



Tolerance:  +_0.01 mg/g.
                                   F-83

-------
     0    Final leak check of train
     0    Sample recovery

Results of the systems audit are summarized in a written report

and the Quality Assurance Coordinator initiates any needed cor-

rective actions.


5.2  PRECISION

     Acceptable precision is maintained through strict adherence

to acceptable limits of difference in replicate measurements at

each step of the procedure from initial calibration of sampling

equipment to the final analytical determinations.  These limits

are specified in the methods and in Volume III of the Quality

Assurance Handbook.


5.3  DATA VALIDATION

     Data validations are accomplished by using internal quality

control checks and performing internal systems, performance, and

data audits.  For each major measurement parameter, the frequency

and type of quality control checks with control limits and cor-

rective action are established.  An example of an internal quality

control check would be to analyze a standard solution after every

tenth analysis for projects requiring a large number of repeti-

tious analyses.  Audit samples  (such as those available from

EMSL/RTP) are used in projects where only a few analyses are

performed in the project.  If the control sample analytical

results are not within the control limits, corrective action has

to be taken to identify and resolve the problem before continuing

with analyses.
                               F-84

-------
     PEDCo performs an internal system audit on every source test



project.  Field calibration checks are performed on the control



module  (using a critical orifice), thermometer, thermocouples,



and digital readouts.  Visual inspections of pitot tubes, glass-



ware, and other equipment are also made.  Figure 5-2 is a check-



list for on-site calibrations for typical source test projects.



The main purpose of a systems audit is to insure that the measure-



ment system will generate valid data if operated properly.  By



performing pretest, on-site, and post-test calibrations of the



measurement systems, data validation checks on the performance of



the test equipment can be easily performed.



     Data reduction and reporting have been shown to be great



potential sources of system error.  Most of PEDCo"s test method



calculations are performed by a validated computer program to



minimize error.  The field data sheets are also set up on a



standard computer card to allow accurate input of data into the



computer by individuals unfamiliar with testing procedures.  The



data printout is then validated by comparison with the field and



analytical data sheets.  In addition, hand calculation checks are



generally made to validate the computer output.



     All data generated by each phase of a laboratory or field



sampling program are reviewed by a senior reviewer.  The data



must be signed off by the senior reviewer prior to releasing the



data for report preparation.



     Material balances (such as water, sulfur, etc.) can be



performed on certain sources to validate measured data.  For
                               F-85

-------
Audit Name:
                          ON-SITE AUDIT DATA SHEET
Date:
Auditor:
Equipment
Meter box
Inlet thermo.
Meter box
outlet thermo.
Impinger
thermometer
Stack
thermometer
or
Thermocouple
Orsat
analyzer
Trip
balance
Barometer
Reference
ASTM-3F at
ambient temp.
ASTM-3F at
ambient temp.
ASTK-3F at
ambient temp.
ASTM-3F at
ambient temp.
ASTM-3F at
stack temp.
% 02 in
ambient air
IOLM std.
weight
Corrected*
NWS value
Reference
Value





20.8°*


Value
Determined








Deviation








Max. Allowable
Deviation
56F
5°F
2°F
7°F
See table
0.7%
0.5 grams
0.20 in. Hg
Reference temp. °F
Max. deviation CF
32-140
7
141-273
9
274-406
11
407-540
13
541-673
15
674-760
17
 * Correction factor:

     NWS value (in.  Hg) - [Altitude (ft)/1000(ft/in.  Hg)] + 0.74 in.  Hg**

** 0.74 in. Hg is the nominal  correction factor for the reference barometer
   against which the field barometer was calibrated.

If It is not feasible to perform the audit on any piece of equipment, record
"N/A" in the space provided for the data.


                Figure  5-2.  Checklist for on-site calibrations.
                                       F-86

-------
example, the F-factor Method can be used to relate the fuel feed



to a combustion source and the measured flue gas flow rate.  Data



validation methods have been documented for other types of sources



also.





5.4  REPORTS



     All final reports are reviewed by the Group Supervisor.



Each report contains all the quality assurance data generated



during the course of the project.  In essence, each emission test



report is also a quality assurance report to management.  Figure



5-3 illustrates the Table of Contents and Figure 5-4 illustrates



the Quality Assurance Element Finder present in each emission



test report.





5.5  PERFORMANCE EVALUATIONS



     PEDCo Environmental participates in EPA's audit program for



stationary source measurements.  These audits include combustion



gas samples for Method 3; samples of coal, S09, and NO  for
                                             £*        yv


analysis; and a critical orifice for Method 5.  The results of



these audits are reviewed by the Division Director and the Quality



Assurance Coordinator and discussed with the Group Supervisor and



the analysts.





5.6  CORRECTIVE ACTION



     PEDCo has two methods for corrective action.  The first is



the use of control limits.  Examples of control limits are audit



sample results, control sample results, and calibration results.
                               F-87

-------
                            CONTENTS

                                                           Page

Figures                                                       v
Tables                                                       vi
Quality Assurance Element Finder                             i*

1.   Introduction                                          1-1

2.   Project Summary                                       2-1

3.   Process Operation                                     3-1

     3.1  Process description                              3-1
     3.2  Environmental control devices tested             3-1"?
     3.3  Process data                                     3-16

4.   Sample Locations and Test Methods                     4-1

      .1  Barton oxide process baghouses No.  1 and No.  2    4-1
      .2  Entoleter scrubber outlet                        4-3
      .3  Baghouse No. 1                                   4-5
      .4  Baghouse No. 2                                   4-5
      .5  Baghouse No. 3                                   4-7
      .6  Carter-Day baghouse                              4-8
      .7  Velocity and gas temperature                     4-6
      .6  Molecular weight                                 4-6
      .9  Particulate matter                               4-10
      .10 Lead                                             4-10

     Summary of Results                                    5-1

     5.1  Barton oxide process baghouses                   5-2
     5.2  Entoleter scrubber outlet                        5-7
     5.3  Baghouse No. 1 outlet                            5-11
     5.4  Baghouse No. 2 outlet                            5-12
     5.5  Baghouse No. 3 outlet                            5-16
     5.6  Carter-Day baghouse outlet                       5-20

     Quality Assurance                                     6-1
Appendix A     Computer printout and sample calculations     A-l

Appendix B     Field data                                   B-l

Appendix C     Laboratory results                           C-l

Appendix D     Sampling and analytical procedures           D-l

Appendix E     Calibration procedures and results           £-1

Appendix F     Quality assuranr* summary                    F-l

Appendix G     Project participants and activity loej        C-l
  Figure 5-3.  Example Emission  Test Report  Table of Contents
                                F-88

-------
                QUALITY ASSURANCE CLEMENT FINDER
(1)   Title page
(2)   Table of contents
(3)   Project description
(4)   Project organization and responsi-
     bilities
(5)   QA objective for measurement data
     in terms of precision,  accuracy, com-
     pleteness, representativeness and
     comparability
(6)   Sampling procedures
(7)   Sample custody
(6)   Calibration procedures and frequency
(9)   Analytical procedures
(10)  Data reduction,  validation, and
     reporting
(11)  Internal quality control checks and
     frequency
(12)  Performance and  system audits and
     frequency
(13)  Preventive maintenance procedures and
     schedules
(14)  Specific routine procedures used
     to assess data precision, accuracy and
     completeness of  specific measurement
     parameters involved
                                                   Location
                                               Section    Page
             ii
   1        1-1
Appendix F  F-3
Appendix F   F-3
Appendix D   D-l
Appendix C   C-l
Appendix E   E-l
Appendix D   D-l

Appendix F   F-4

Appendix F   F-5

Appendix F   F-4

Appendix F   F-6
 Appendix F  F-5
 Appendix F  F-6
(15)  Corrective action
(16)  Quality assurance reports to management   Appendix F  P-7
 Figure 5-4.  Example emission test report quality assurance element finder
                               F-89

-------
                        6.0  CALIBRATION




     All sample train components requiring calibration are cali-



brated at the recommended interval using approved methods.



Calibration procedures for all components are documented and are



contained in the PEDCo Environmental Emission Measurements



Quality Control Procedures Manual.  Standardized calibration



procedures are in accordance with calibration criteria outlined



in the test method and Volume III of the Quality Assurance



Handbook for Air Pollution Measurement Systems, EPA-600/4-77-027b,



The following sample train components are calibrated using



standardized procedures.



     0    Pitot tube



     0    Differential pressure gauge



     0    Barometer



     0    Rotameter (rate meter)



     0    Low temperature thermometer



     0    Stack temperature thermometer



     0    Digital indicator



     0    Thermocouple



     0    Dry gas meter thermometer



     0    Method 7 collection flask



     0    Wet test meter



     0    Sampling nozzles
                             F-90

-------
     0    Orsat analyzer



     0    Method 5 meter box



     0    Method 6 meter box



Calibration procedures for special equipment and components such



as the analytical system used in EPA test Method 25 are calibrated



using procedures tailored to the specific system based on accepted



methods published in the literature or manufacturer's specifica-



tions.  These special purpose calibration procedures are docu-



mented in the Quality Control Procedures Manual.



     The general calibration program consists of conducting a



full-scale laboratory calibration procedure on each new or re-



paired component requiring calibration, prior to its use in the



field.



     At the completion of a field test, each component requiring



calibration receives a post-test calibration check.  Any com-



ponent not meeting the calibration criteria is thoroughly checked



and calibrated using the full-scale laboratory procedure.



Figures 6-1 and 6-2 present example data sheets for a full-scale



laboratory calibration and a post-test calibration check,



respectively, for a dry gas meter used in Method 5 testing.



Each calibration data sheet contains the criteria that must be



met.



     The results of equipment calibrations are included in each



test report.  Table 6-1 summarized the calibration data for



equipment used for a Method 5 test.
                               F-91

-------
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                                  Tn.Tig
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( \ )( ffc )(% • «*0)
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( H 1( )
{ )( J( )
( )( )( )
( 11 )( )
( )( )( )
( )( tt )
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1 J( Jl }
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(O.OJ17)( «H )
I % )t% « «*o>
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If »f
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Figure 6-1.   Full-scale dry  gas meter calibration data sheet.
                                F-92

-------
                      PARTICIPATE SAMPLING METER BOX
                          POST-TEST  CALIBRATION
BATE: .

IAROHETR1C  PRESSURE

PLANT:
         In. Hg
PROJECT MANAGER:
METER BOX  NO.

PRETEST V: _
PROJECT NO. _

CALIBRATOR:
AH*:
Orifice
nanometer
setting
•
AH
1n. H20



Met test
meter
volume
V.
ft3



Dry gas
•eter
volume
Vd
ft3






Temperatures
Net test
•eter
\
•F






Dn
•Jnlet
Td1
•F






i gas meter
Outlet
7dl
•F






Average
\
•F



Vacuum
setting
••
1n. Hg



Duration
of run
f
inin



Post-test average***
V




AHP




              bar
T, * 460  )
 o	
                                      (0.0317)(  AH
                            * 460)
                 *460)(  0  )|
                                            )(
                               H
                           _)

                            X
                                            )(
                                     )(
                                            )(
                                            )(
                                     )(
  •To be  the average AH used  during the test series.
 ••To be  the highest vacuum used during the test series.
•••Post-test Y nust be within the range, pre-test y *O.C
   Post-test AH9 must be within the range, pre-test AH? *0.15
     Figure 6-2.   Post  test dry gas meter calibration data  sheet.
                                        F-93

-------
                                      TABLE 6-1.  FIELD EQUIPMENT CALIBRATION
Equipment
Meter box
Meter box
Meter box
Meter box
Meter box
Pi tot tube
Pi tot tube
Pi tot tube
Pi tot tube
Pi tot tube
Pi tot tube
I.D.
No.
FB-2
FB-3
FB-4
FB-6
FB-8
179
180
185
187
189
192
Calibrated
against
Wet test meter




Standard pi tot tube





Allowable
deviation
AY prea + 0.020
AH
-------
TABLE 6-1  (continued)
Equipment
Thermocouple
Thermocouple
Thermocouple
Thermocouple
Digital
indicator
Orsat
analyzer
Trip balance
Barometer
I.D.
No.
129
164
256
259
124
125
219
232
198
225
Calibrated
against
ASTM reference
thermometer



Millivolt signals
Standard gas
Type S weights
NBS traceable
barometer
Allowable
deviation
+ 1.5*



0.5*
+0.5%
+0.5 g
0.20 in. Hg
post-test
Actual
deviation
0.70
1.1
0.5
0.07
Avg. 0.13%
Avg. 0.22%
Avg. -0.10%
0.1%
0.0 g
0.00 in.
Hg
Within
allowable
1 imits
/
/
/
/
/
/
/
/
/
/
Comments





)2 and C02 are the
higher deviation


(continued)

-------
      TABLE 6-1 (continued)
Equipment
Dry gas
thermometer



Probe nozzle




I.D.
No.
FB-2
FB-3
FB-4
FB-6
FB-8
CIM-3
6XXX
C2M-4
C2M-2
C2M-P
2-103
CIH-3
Calibrated
against
Reference thermom-
eter type ASTM 2F
or 3F
•


Caliper




Allowable
deviation




Dn +_ 0.004 in.




Actual
deviation
I 1.2°F
0 1.4°F
I 1.1°F
0 2.0°F
I 1.1°F
0 1.0°F
I 0.8°F
0 1.4°F
I 1.0'F
0 2.1°F
0.002
0.000
0.000
0.001
0.001
0.002
0.002
Within
allowable
1 imits
/
y
Jj
/

/
'
^
/
Comments
I = inlet thermom-
eter
0 = outlet thermom-
eter



Nozzles for particle-
size tests were
labeled according to
run numbers




 I
vo

-------
                   7.0  PREVENTIVE MAINTENANCE





     All equipment used in emission measuring systems must be



maintained in good operating order.  In order to achieve this



objective a good preventive maintenance program is necessary.



PEDCo's preventive maintenance program is composed of 3 major



components consisting of:  short interval inspection; replacement



of obsolete or damaged components; and scheduled disassembly and



overhaul.  Procedures used in this program follow those outlined



in Maintenance Calibration and Operation of Isokinetic Source



Sampling Equipment, Publication No. APTD-05-76 and Volume III of



the Quality Assurance Manual.





7.1  SHORT INTERVAL INSPECTION



     The short interval inspection program consists of inspecting



each component of the sampling train after each job.  This



inspection is accomplished after the post-test calibration check



and includes operating and inspecting each component to detect



damage.





7.2  REPLACEMENT OF DAMAGED OR OBSOLETE COMPONENTS



     Replacement of damaged, worn-out or obsolete components are



made whenever required.  A red tag system is also used which



alerts maintenance personnel to damaged or worn-out components
                             . F-97

-------
detected in the field.  The red tag contains a written description



of the problem along with the equipment operator's name.





7.3  SCHEDULED DISASSEMBLY AND OVERHAUL



     All mechanical components in the sampling systems are dis-



assembled,  inspected, cleaned, and overhauled annually or more



frequently, if necessary.
                             F-98

-------
                          8.0  TRAINING





     It is corporate policy that each year each professional



employee is encouraged to attend one short course or its equivalent



specific to the employee's professional responsibilities.



     Each new employee undergoes an orientation and on-the-job



training period before being assigned independent duties.  Addi-



tionally, institution of new techniques, modification of proce-



dures, or the acquisition of new equipment is accompanied by



appropriate in-house, or if necessary, extramural training.



     Selected personnel are also trained in tasks different from



their regular assignments.
                             F-99

-------
                                 PEDCO ENVIRONMENTAL. INC.
                                                     1 1499 CHESTER ROAD
                                                    CINCINNATI. OHIO 45246
                                                          1513)782-4700
                                                 TELECOPIER (513) 762-4BO7
                 PEDCo ENVIRONMENTAL, IMC.  LABORATORY


                        QUALITY ASSURANCE  PLAN
                AMERICAN  INDUSTRIAL HYGIENE ASSOCIATION
                          ACCREDITATION NO.  49
                 '•/   i-  '-   •'
Approved  by:    / ///f / a j/,  V ; ->j ? i '•• u _ ,  Senior Vice  President
                           ,  .'                Corporate Quality
                           '-/                Assurance Coordinator


               >r-~#*^~±+~e^   A  E&.^i^ i  Division Director
                                           ,  Division Quality
                                             Assurance Coordinator
                          Revised January  1982
                                 BRANCH OFFICES
                        DALLAS. TEXAS           COLUMBUS. OHIO

  CHESTER TOWERS      KANSAS CITY. MISSOURI      DURHAM. NORTH CAROLINA


                                 F-100

-------
                        TABLE OF CONTENTS
List of Figures

List of Individuals Receiving the Laboratory  Quality
 Assurance Plan

1.0  Introduction                                            1-1

2.0  Laboratory Organization and Responsibilities             2-1
     2.1  Director                                           2-1
     2.2  Associate Director                                 2-3
     2.3  Quality Assurance Coordinator                       2-3
     2.4  Senior Industrial Hygienist (CIH)                   2-3
     2.5  Group Supervisor                                   2-3
     2.6  Group Leaders                                      2-5
     2.7  Sample Custodian/Quality Control  Clerk              2-5
     2.8  Analysts                                           2-5
     2.9  Laboratory Clerk                                   2-7

3.0  Methods                                                 3-1

4.0  Chain of Custody                                        4-1
     4.1  Sample Receiving                                   4-1
     4.2  Sample Analyses                                    4-1
     4.3  Sample Record Keeping                              4-6

5.0  Quality Control                                         5-1
     5.1  Accuracy                                           5-1
     5.2  Precision                                          5-3
     5.3  Corrective Measures                                5-3
     5.4  Performance Evaluation                             5-9
     5.5  Data Validation                                    5-9
     5.6  Reports                                            5-9

6.0  Training                                                6-1

7.0  Instrument Maintenance and Calibration                  7-1
     7.1  Inorganic Section                                  7-1
     7.2  Organic Section                                    7-1

8.0  Glassware Cleaning Procedures                           8-1
     8.1  Inorganic Section                                  8-1
     8.2  Organic Section                                    8-1

9.0  Safety Procedures                                       9-1
     9.1  Laboratory Conduct                                 9-1
     9.2  Fire Prevention                                    9-1
     9.3  Prevention of Poisoning                            9-2
     9.4  Personal Safety                                    9-2
     9.5  Safety Equipment                                   9-3
     9.6  General                                            9-3
                              F-101

-------
                             FIGURES


Number                                                      Page

1-1       Organization of Corporate Quality Assurance       1-2

2-1       Organizational Chart                              2-2

2-2       Quality Assurance Checklist                       2-4

2-3       Example of Reagent Procurement Record             2-6

4-1       Example of Sample Receipt and Record Sheet        4-2

4-2       Example of Sample Analysis Requisition and        4-3
          Record Sheet

4-3       Example of Sample Control Record                  4-4

4-4       Example of Laboratory Data Record                 4-5

5-1       Accuracy Control Chart                            5-2

5-2       Precision Control Chart                           5-4

5-3       Quality Control Report - Matrix Spike             5-5

5-4       Quality Control Report - Duplicate Analysis -     5-6
          Organic

5-5       Quality Control Report - Charcoal Tubes           5-7

5-6       Quality Control Report of Accuracy - Inorganic    5-8

5-7       Quality Control Report of Precision - Inorganic   5-8
                              F-102

-------
      LIST OF INDIVIDUALS RECEIVNG THE
      LABORATORY QUALITY ASSURANCE PLAN
Charles E. Ziiraner
Lawrence A. Elfers
Eugene W. Koesters
Thomas J. Wagner
Craig H. Caldwell
Harry W. Jess
Ida J. Bennett
Dwight R. Hayes
                  F-103

-------
                        1.0  INTRODUCTION
     Figure 1-1 presents the corporate quality assurance organiza-
tion and illustrates the relationship of the Laboratory Group's
quality assurance activities to the total corporate quality
assurance effort.  Mr. Zimmer is the Senior Vice President of
PEDCo Environmental.  Mr. Zimmer is trained in statistics and has
over 20 years experience in the environmental field.

     The principal function of the PEDCo Environmental Laboratory
is to provide data that is:

     0    representative,
     0    accurate,
     0    precise,
     0    complete,
     0    comparable,
     0    defensible, and
     0    on time.

The management of PEDCo Environmental is committed to these
objectives and has a policy of producing data of documented high
quality.

     Quality assurance is the sum of all those activities in
which the laboratory is engaged that will ensure the validity of
the information generated.

     Quality assurance is not restricted to the development and
retention of quality control (QC)  charts for precision and accu-
racy, but rather includes all laboratory activities that affect
the results produced.  These activities include, but are not
restricted to, the choice of methods, education of personnel,
handling of specimens, and reporting of results.

     The purpose of this manual is to outline the quality assu-
rance activities of the PEDCo Environmental Laboratory.
                               F-104

-------
I
M
O
Field Studies
and Labortory
             T. Wagner
                                               Quality Assurance Activity
                                                C.E.  Zimner, Coordinator
                                            E.W. Koesters, Ass't.  Coordinator
                                         Engineering
                                D.  Henz
Data Reduction,
 Presentation
 and Analysis
  C. Zimmer
  Report
Preparation
M. Phillips
                                Figure 1-1.   Organization  of corporate quality assurance.

-------
        2.0  LABORATORY ORGANIZATION AND RESPONSIBILITIES


     The organization of the PEDCo Environmental Laboratory is
designed to provide an efficient flow of administrative,  tech-
nical, quality assurance, and advisory activities throughout its
operation.

     The organizational chart is presented as Figure 2-1, and the
responsibilities of the staff are outlined below.


2.1  DIRECTOR

     The responsibilities of the Director are as follows:

     0    Set objectives for the Field Studies/Laboratory Division.

     0    Plan the Division's course and policies.

     0    Organize the personnel, facilities, equipment,  and
          materials into a coherent organization that can fulfill
          the Division's plans.

     0    Integrate the various  parts of the organization.

     0    Measure the success in achieving the objectives.

     0    Resolve problems.


2.2  ASSOCIATE DIRECTOR

     The responsibilities of the Associate Director are as follows:

     0    Coordinate the activities of the Field Studies/Laboratory
          Division.

     0    Primary administrative contact with regulatory and
          accreditation agencies.

     0    Assist the Director in the implementation and supervision
          of administrative operations.

     0    Provide lia.ison with clients.
                             F-106

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                                                       LABORATORY
                                                    L.  ELFERS,  DIRECTOR

                                               E.  KOESTERS, ASSOC.  DIRECTOR
                                   M.  KARAFFA  (CIH)
                                   SR.  INDUSTRIAL
                                     HYGIENIST
                                     S. GORSKI
                                   CLERK/TYPIST
                                         J_
i
M
o
  C. CALDWELL
GROUP SUPERVISOR
  INORGANIC
                                   GROUP  LEADER
                                     INORGANIC
                                     •ANALYSTS
                                            T. WAGNER
                                         QUALITY ASSURANCE
                                           COORDINATOR
                                             D. WHITE
                                         SAMPLE CUSTODIAN
 H. JESS (ACTING)
GROUP SUPERVISOR
     ORGANIC
                                                                            J_
                                     GROUP LEADER
                                         AIR
                                                                   _L
                   GROUP LEADER
                      WATER
                                                                      1
                                       ANALYSTS
                                                              I
                     ANALYSTS
                                            Figure  2-1.   Organizational  chart.

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2.3  QUALITY ASSURANCE COORDINATOR

     The responsibilities of the Quality Assurance Coordinator
are as follows:

     0    Develop,  coordinate,  and evaluate the quality assurance
          program.

     0    Conduct routine checks on quality assurance items
          (Figure 2-2).

     0    Review performance evaluation results.

     0    Evaluate  methods and  procedures.

     0    Act as technical advisor to Group Supervisors.

     0    Issue, prepare, and evaluate audit samples.

     0    Develop quality assurance plans for special projects.


2.4  SENIOR INDUSTRIAL HYGIENIST (CIH)

     The responsibilities of the Senior Industrial Hygienist are
as follows:

     0    Interpret AIHA accreditation requirements and establish
          appropriate company policy.

     0    Advise Group Supervisors on all industrial hygiene
          activities of the laboratory.

     0    Assist the Quality Assurance Coordinator in the
          design of the entire  Laboratory Quality Assurance
          Plan.


2.5  GROUP SUPERVISOR

     The responsibilities of the Group Supervisors are as follows:

     0    Set objectives for the laboratory.

     0    Plan the  laboratory's course and policy.

     0    Organize  the laboratory personnel and facilities.

     0    Evaluate  the success  of the laboratory.

     0    Serve as  project director.
                            F-108

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      QUALITY ASSURANCE CHECKLIST
ITEM
SAMPLE LOG
ANALYSIS REQUISITION BOOK
PROCUREMENT LOG
DATA FILES
Q.C. CHARTS
REAGENTS :
A) NEW ITEMS DATED
B) OUTDATED ITEMS REMOVED
MAINTENANCE & CALIBRATION RECORDS
A) AA SPECTROPHOTOMETERS
B) BALANCES
C) HYDROTHERMOGRAPH
D) BOMB CALORIMETER
E) SPECTROPHOTOMETERS
F) GC, GC/MS
METHODS MANUALS
Q.A. MANUAL UPDATE
TRAINING RECORDS
GENERAL PROCEDURES
CLEANLINESS
SAFETY
PERFORMANCE EVALUATION RESULTS
(PAT, WP, SO,, NO , DGM, COAL,
METHOD 3)
FREQUENCY DATE
MONTHLY
MONTHLY
MONTHLY
MONTHLY
MONTHLY

MONTHLY
MONTHLY

MONTHLY
MONTHLY
MONTHLY
MONTHLY
MONTHLY
MONTHLY
YEARLY
YEARLY
YEARLY
RANDOM
RANDOM
RANDOM
AS RECEIVED

Figure 2-2.  Quality assurance checklist,
                  F-109

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2.6  GROUP LEADERS

     The responsibilities of the Group Leaders are as follows:

     0    Determine the technical methods to be used.

     0    Direct the day-to-day work.

     0    Handle personnel matters.

     0    Anticipate problems.

     0    Troubleshoot.

     0    Review reports for technical accuracy.

     0    Manage projects as assigned.

     0    Train the analysts.


2.7  SAMPLE CUSTODIAN/QUALITY CONTROL CLERK

     The responsibilities of the Sample Custodian/Quality Control
Clerk are as follows:

     0    Receive and log samples entering the laboratory.

     0    Maintain custody records.

     0    Proper storage of samples.

     0    Document custody changes in the laboratory.

     0    Receive and log reagents entering the laboratory
          (Figure 2-3).

     0    Maintain Quality Control Charts.

     0    Alert Quality Assurance Coordinator to any unusual
          trends on Quality Control Charts.


2.8  ANALYSTS

     The responsibilities of the Analysts are as follows:

     0    Perform sampling and analyses according to approved
          PEDCo methods.
                              F-110

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Item Description






















Qty.






















P.O.
No.





















PEDCo ENVIRONMENTAL LABORATORY
Reagent Procurement Record
Date
Ord . Rec .











































Lot No.





















Vendor





















Expiration
Date





















Comments





















Figure 2-3.   Example of reagent procurement record.

-------
          Alert the Group Leader to any analytical problems and
          document the problems on the data sheet.

          Perform routine maintenance and calibration of instru-
          ments.

          Prepare reagents.
2.9  LABORATORY CLERK

     The responsibilities of the Laboratory Clerk are as follows:

     0     Maintain records.

     0     Maintain the Project Status Board.

     0     Perform general clerical duties.
                            F-112

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                         3.0  METHODS
     The PEDCo Environmental Laboratory normally uses published
methods, e.g., Federal Register methods for Environmental Pro-
tection Agency (EPA) Compliance analyses, NIOSH publications for
industrial hygiene samples, and various other regularly accepted
analytical references such as those of the ASTM.  If a different
method, or a change to an existing method is needed, the altera-
tion is documented in the PEDCo Laboratory Method Series Manual.
Each procedure accepted for use in the PEDCo Environmental Lab-
oratory is entered in the manual along with the following legend:


               PEDCo ENVIRONMENTAL METHOD CONTROL

          Parameter              Method
          Use approved by	Date	
          Termination approved by	Date
The most often used methods are reviewed and changed as necessary.
These accepted methods have been collected in two identical
sets:  one as the master laboratory control document, the other
as the working copy in the laboratory.  As new individual methods
attain more frequent use, they are reviewed, changed as necessary,
and included as PEDCo approved methods.  All PEDCo approved
methods are reviewed at least annually and reapproved for use.
The front page of each approved method tracks the dates at which
changes to the method have been introduced and dates on which
the method has been reviewed.

     The methods which PEDCo Environmental, Inc. routinely uses
for analysis are selected from these publications:

     1.   Methods for Chemical Analysis of Water and Wastes.
          U.S. EPA, Cincinnati, Ohio, 1979, Publication No.
          EPA-600/4-79-020.

     2.   Test Methods for Evaluating Solid Waste, Physical/Chemical
          Methods.  U.S. EPA SW-846, 1980.
                             F-113

-------
 3.    Quality Assurance Handbook for Air Pollution Measurement
      Systems, Volumes I,  II,  iTflEPA-600/9-76-005,  EPA-
      600/4-77-027a,  and EPA-600/4-77-027b.

 4.    Guidelines Establishing  Test  Procedures for the  Analysis
      of Pollutants.   Federal  Register,  December 3,  1979,
      Vol.  44, No.  233, Part 3,  pp.  69464-69575.

 5.    NIOSH Manual  of Analytical Methods.   U.S.  Department  of
      Health, Education and Welfare; Public Health Service,
      Center for Disease Control, National Institute for
      Occupational  Safety and  Health, Cincinnati, Ohio.
      Second Edition.  Vols. 1,  2,  3; April 1977.  Vol.  4,
      August 1978.  Vol. 5, August  1979. Vol. 6, August  1980.

 6.    Annual Book of  ASTM Standards, Part 26, Gaseous  Fuels;
      Coal  and Coke;  Atmospheric Analysis.  American Society
      for Testing and Materials. Philadelphia,  Pennsylvania,
      1980.

 7.    Annual Book of  ASTM Standards, Part 31, Water.  American
      Society for Testing and  Materials.  Philadelphia,
      Pennsylvania, 1979.

 8.    Methods of Air  Sampling  and Analysis.   2nd ed.,  APHA
      Intersociety  Committee,  1977.

 9.    Standard Methods for the Examination of Water and  Waste-
      Water. 14th ed., American Public Health Assn., Washington,
      D.C., 1975.

10.    Handbook for  Analytical  Quality Control in Water and
      Wastewater Laboratories.  EPA-600/4-79-019, 1979.
                         F-114

-------
                      4.0  CHAIN OF CUSTODY
     This section contains custody procedures used in the labora-
tory.  Custody procedures used during sampling are contained in
the quality assurance plans for the field groups and the complete
procedure is compiled in a separate document.


4.1  SAMPLE RECEIVING

     Every sample entering the lab for analysis is assigned a
unique alphanumeric identity on the Sample Receipt and Record
Sheet  (Log).  In the sample log-in book, the number is correlated
with the client's identification and with the number of the
analysis requisition form.  A copy of the sample receipt and
record sheet is shown in Figure 4-1.

     The analysis requisition is a triplicate form that lists the
client, project number, type and number of samples submitted, and
analyses required.  It also assigns analysts to specific tasks
and shows the number of hours estimated for those tasks.

     The white (top) sheet of the requisition form is placed in
the requisition binder; the pink sheet is placed with the samples
and later with the raw data.  The yellow sheet is given to the
person requesting the analyses.  In some cases, the yellow copy
may accompany some of the samples if a batch includes both inor-
ganic and organic analyses.  A copy of the sample analysis
requisition and record sheet is shown as Figure 4-2.

     The samples remain in the locked sample storage room until
removed for analysis.  This transfer is documented on a Sample
Control Record (Figure 4-3) which is maintained by the sample
custodian.  The Sample Control Record documents all custody
changes which occur in the laboratory and each procedure per-
formed on the sample.
4.2  SAMPLE ANALYSES

     Prior to the analyst receiving the sample from the sample
custodian, a laboratory data sheet is prepared by the analyst.
                               F-115

-------
I
I-1
M

ftOCo eNV 1 RONMCNTAL LABORATORY
SAMPLE BlttlPT AND Ultimo blli:l:T
^•«it>l«<
MiMbcr

























Rebuts i t ion
NiMiber

























Cl ttrnt
Ndnc


























Client's Sjmplt*

























Tro n'crl
NumlM-i

























OJK-
Rl'Cf 1 VIM|

























Cunt J i ni*r
Humbct

























U*lr
Repur ted

























Month
Billed

























D«t«
Discarded



















t-«
Ol
-+
•0
•^
>

                       Figure 4-1.  Example of Sample  Receipt and Record Sheet.

-------
              PEOCo ENVIRONMENTAL LABORATORY
       SAMPLE ANALYSIS REQUISITION AND RECORD SHEET  N?    1252
Client:	
Project no.:	
Date results needed:	
Type and number of  samples:
            .Date:.
.Requested by:.
Analyses Required










Ref. Method










Special  Instructions:.
Retain  samples until:.
   .Budget:
Cost:
                        RESOURCES
Personnel








Man-hours
Est.








Act.








Date
done








Activity








    Figure  4-2.   Example of Sample  Analysis
           Requisition and  Record Sheet.
                             F-117

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                                  SAMPLE CONTROL RECORD
LABORATORY
SAMPLE NO.
REMOVED
  BY
             DATE fc TIME REMOVED
                                                              REASON
DATE  t TIME
 RETURNED
                  Figure 4-3.   Example of  Sample Control  Record.

-------
The laboratory data sheet  (Figure 4-4) includes the following
information:

      0    Sample numbers
      0    Date sample received by the analyst
      0    Analysis and method number
      0    Portion required for analysis
      0    Signature of analyst
      0    Signature of chemist checking calculations

      Release of samples requires annotation of the Sample Control
Record and verification of information and sample container condi-
tion.   If the sample is to be transferred between two persons
(i.e., two analysts), the transfer must take place through the
sample custodian.  In other words, the sample must be returned to
the sample custodian and it is then reissued.

     After obtaining the sample from the laboratory sample custo-
dian,  the analyst verifies the data and makes appropriate annota-
tion of the records.  If a question arises, it is first discussed
with the sample custodian.  If this does not resolve the problem,
it is brought to the attention of the person submitting the
sample for analysis.  If the problem cannot be resolved, the
sample is voided.  The analyst keeps the samples in view or under
limited-access locked storage.  The analyst visually inspects the
sample to determine that the physical condition is suitable for
analysis.  For any sample for which the condition is questionable
or the method of collection was inappropriate, such as the pres-
ence of an inappropriate interference, the samples are not ana-
lyzed, and the data sheet is annotated.  The analyst must maintain
proper custodial procedures while analyzing a sample.  Samples or
intermediate solutions must be in the analyst's physical posses-
sion,  in view, or in limited-access locked storage.  The labora-
tories are locked so that only authorized personnel have access.

     Analyses should be conducted in accordance with the proce-
dures specified in the contract statement of work and referenced
by number to the standard method in the laboratory procedures
manual.  Any deviation from these procedures must be annotated,
and the analyst must be prepared to justify deviations under
oath.   All data are recorded on the data sheet.  All measurements
associated with the sample must be traceable in accordance with
good quality assurance record-keeping procedures.  Thus, asso-
ciated calibrations must be recorded either directly on or
attached to the data sheet or indirectly by reference to the
standard solution number or instrument number.

     All of the columns used on a data sheet must be labeled.
Extra columns may be used for intermediate results of calculations
if that will make for clearer understanding.
                             F-119

-------
                         lAJOMTO*'
  CUtnt
             Dttr
  Analyst
Method
Checker
SAMPLE NUMBERS
  Figure  4-4.  Example of Laboratory  Data Record,
                           F-120

-------
     The axes of all graphs are labeled as follows:  micrograms
and ppm are the x, or horizontal axes; O.D. and scale divisions
are the y, or vertical axes.  If the least squares fit is cal-
culated, indicate this on the data sheet and record the slope,
y-intercept, and the correlation coefficient.

     Sample calculations should be included so a reviewer at a
later date can ascertain immediately what was done.
4.3  SAMPLE RECORD KEEPING

     The PEDCo alphanumeric identification is used on all data
sheets, containers, beakers, etc.  The client's sample number or
name can be used for extra information, if desired.  Exceptions
are instances in which a set of numbered containers, such as
Kjeldahl flasks or ashing crucibles, is used; here the container
number must be matched on the data sheet with the PEDCo alpha-
numeric identification.

     All raw data for analyses in progress are kept in project
folders in a rack when not actually being used.  When all the
tests on a set of samples are completed, all of the raw data
sheets with the pink requisition form attached are placed in the
appropriate Group Leader's "In" basket.

     Associated calibration curves and charts should be signed
and dated; a system of positive identification and controlled
storage is used.  The exact method of analysis must be readily
ascertainable.  This is most easily done by making reference to
the standard analytical procedure used when a method allows for a
choice of procedures.  If any portion of the sample remains after
analysis is completed and if storage is required, the analyst
must reseal the sample, and return it to the laboratory sample
custodian.  Appropriate annotations are made in the transfer
records and the sample is stored in accordance with specified
procedures.

     The analyst's calculations are checked as required by inter-
nal audit.  The person checking the calculations signs and dates
the data sheet.  The data sheet is returned to the file.  All
records must be in ink.  Errors are corrected by drawing a
straight line through the error and initialing.  Completed rec-
ords are maintained by the laboratory sample custodian.  Use of
records other than official records is prohibited.

     When all analyses are completed, the report is prepared and
delivered.  A copy of the report, the raw data, and other docu-
ments are placed in the laboratory files which are kept in a
locked, limited access area.  The filing system utilizes a client
                               F-121

-------
or activity numbering system indicating the type of client or
activity, the specific client or activity, and dates of a specific
task.  The system uses a number, set off by multiple decimal
points; e.g., 5.2.21, where the 5 indicates Quality Assurance/
Quality Control, the 2 indicates PAT analyses, and the 21 indi-
cates Round 46.   The master log gives the client's identity and
the date of each file entry.  This is the same client identifica-
tion number that is plotted on the individual QC charts for each
type of analysis.
     ALL DEVIATIONS,  DISCREPANCIES OR ERRORS,  WHETHER NOTED
     BY SAMPLING PERSONNEL,  BY CUSTODIAN,  BY ANALYST OR BY
     CHECKER,  MUST BE RECORDED.
                              F-122

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                      5.0  QUALITY CONTROL
     Reliability in analytical determinations is maintained
through strict adherence to quality control procedures.  PEDCo's
procedures are designed to control both the accuracy and pre-
cision of analytical results.


5.1  ACCURACY

     When the analytical procedure is appropriate, a known refer-
ence standard is routinely analyzed to ensure the accuracy of
results.  This standard may be spiked into a separate aliquot of
a sample or analyzed as a separate sample itself.  The procedure
is to run this standard with each lot of samples sent to the
laboratory.  In addition, if more than 10 individual analyses
are made, additional standards will be analyzed at the rate of 1
standard per 10 analyses.

     Control charts are prepared using an estimate of the method
variability (i.e., standard deviation) obtained from the litera-
ture, or determined by repeated duplicate analyses run in the
laboratory.  A control chart for accuracy is shown as Figure
5-1.  Each time the analyst runs a reference standard, the
result is entered on the control chart.  If the analytical
procedure is in control, the estimate of the standard should lie
within the +2o control limits.  The results should be random,
and tend to fall above and below the true value for the standard.
If an individual analysis of the reference standard falls outside
the 2o limits, the analyst is required to repeat the analysis of
the standard.   Should this second result also fall outside the
2o limits, the group leader determines the cause of the discrepancy
and makes the necessary corrections in procedure or technique.

     The control chart also provides a means of detecting bias
in results.  Evidence of bias is obvious when the individual
analyses of the reference standard tend to be all above (or
below) the true value, or begin to show a definite trend in the
amount of departure from the true value.  When this situation
occurs, the sample custodian notifies the group leader and the
quality assurance coordinator even before the 2o limit is exceeded.
Again, routine sample analysis is not continued until the source
of bias has been identified and corrected.
                            F-123

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     IinCRNAL STANDARD QC CHART . ACCURACY
                                 fort ma




                           Throrruc*) Val
             Act*
                   IB »o,
Figure  5-1.   Accuracy  control  chart.
              F-124

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5.2  PRECISION

     Replicate analyses are performed on at least 10% of the
samples processed by the laboratory.  A record of the precision
of most analyses is kept by calculating and plotting the coeffi-
cient of variation (CV) of the pairs.  The coefficient of varia-
tion is defined by the equation:
                                    o"U/2
                    CV = - =
                         X
     where X  and X

                  s

                  X
values of the given parameter for
the replicates,
the standard deviation of the rep-
licates, and
the mean of the replicates
     The mean CV for an appropriate number of sample pairs
(usually 20) is determined, and the upper control_limit (UCL)
at the 99.5 percentile is calculated (UCL = 2.8 CV for duplicate
values).  The mean and control limit values are plotted on the
chart shown as Figure 5-2.

     The analysts report the results of replicate analyses each
day to the sample custodian on forms provided.  The sample
custodian calculates and plots CV along with the date and client
code.

     Quality Control data sheets for the organic group are shown
as Figures 5-3, 5-4, and 5-5, and for the inorganic group as
Figures 5-6 and 5-7.


5.3  CORRECTIVE MEASURES

     When the sample custodian records a value that is out of
specification (for either accuracy or precision), the group
leader is immediately notified.  A series of steps are then taken
to correct the deficiency:

     0    The data are examined for calculation error.

     0    The group leader discusses the test with the analyst to
          see if a procedural error was made.

     0    The reagents used are examined to see if any were out
          of date or used in error.

     0    The instrument, if one was used, is examined for
          defects or improper calibration.
                              F-125

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N)
Oi
COEFFICIENT OF VARIATION
p^B^MrtTR METHOD NUMBER UHIT<
MTt
VM.UC 1
VMlUt ?
cv
CLIENT 1


COEFFICIENT OF VARIATION










































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































































                                  Figure 5-2.  Precision control chart.

-------
»TJ

M
to
Simple N
-------
M
00

Sample Not



Lab Standard to:
QUALITY CONTROL REPORT
B. DUPLICATE ANALYSIS

COV.POL'ND (including surrogate*)
P. P. *
















































































COMPOUND NAME




















CONCENTRATION (uR/l)
Aliquot 1 (D|)




















Aliquot 2 (D2)




















Coefficient
of variation




















Tin QC Report also covers the following sample numbers:


                   Fiqure  5-4.  Quality control report - duplicate analysis  -  orqanic,

-------
Additional Sample Calculation*:
Quality Control Calculations

Parameter
















PRECISION

Sample No.

















Values
Obtained
















                                                   ACCURACY
                                       Date
Theor.
Val.
Exp.
Val.
 I of
Thesr.
     Figure  5-5.   Quality  control report -  charcoal tubes
                                  F-129

-------
                STANDARD REFERENCE MATERIAL REPORTING FORM
                    (INTERNAL STANDARD TOR ACCURACY)
        Method No.
        Working Range
        Client 	
        Values determined
Parameter
Unit» 	
PN
Date
Figure 5-6.   Quality  control  report of  accuracy - inorganic
REPLICATE
Method No.
Working Range
Client
Values determined
ANALYSIS REPORTING FORK
Parameter
Unite
PN Date
A B Difference




Figure 5-7.   Quality control  report of precision  - inorganic,
                                 F-130

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     If the error is corrected by recalculation, no further
steps are taken.  If the error was due to one of the other
causes, the test is rerun to obtain answers within specifications.
Should the results again be out of specifications, the above
procedures are followed in greater detail and the test rerun by
another analyst and/or with freshly prepared reagents.


5.4  PERFORMANCE EVALUATION (Audits)

     The PEDCo Environmental Laboratory participates in the
Proficiency Analytical Testing Program administered by NIOSH; the
Water Pollution Performance Evaluation Program administered by
the U.S. EPA; and the U.S. EPA Stationary Source Quality Assurance
Program for S02» NOX, DGM, coal, and Method 3.  The audit results
are reviewed by the Division Directors and the Quality Assurance
Coordinator and discussed with the Group Supervisors and the
analysts.

     The PEDCo Laboratory also has been approved by the U.S. EPA
Environmental Monitoring and Support Laboratory in Las Vegas,
Nevada for the analysis of priority pollutants from hazardous
waste sites.  PEDCo has participated successfully in various
preaward performance surveys and ongoing performance audits under
existing contracts.
5.5  DATA VALIDATION

     All data generated by the laboratory is checked for technical
accuracy by the Group Leaders.  This involves verifying that the
appropriate analytical method was used, the detection limit is
appropriate, the proper number of significant figures are reported,
and the data were calculated properly  (This is done by repeating
the calculations for at least one sample).  The data is then
given to the Data Clerk who redoes all hand calculations and
verifies all data entries into computer programs.  The data is
then reviewed by the Quality Assurance Coordinator before the
report is issued.


5.6  REPORTS

     Analytical reports are typed by the Laboratory Clerk and
checked by the Data Clerk before being signed by the appropriate
supervisor.  Major reports include summaries of all quality con-
trol data.

     Twice weekly status reports of all laboratory projects (by
Analysis Requisition number) are prepared and submitted to the
Division Director.  These reports include:
                              F-131

-------
     0    date samples received
     0    date analysis started
     0    date report due
     0    percent completed
     0    appropriate remarks (problems and corrective actions)

These reports also include the status of all major instrumentation,
                              F-132

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                          6.0  TRAINING


     It is corporate policy that each year each professional
employee is encouraged to attend one short course or its equivalent
specific to the employee's professional responsibilities.

     Each new employee undergoes an orientation and on-the-job
training period before being assigned independent duties.  When
reproducible results are routinely obtained by the analyst, he or
she is considered fully trained.

     Additionally, institution of new techniques, modification of
procedures, or the acquisition of new equipment is accompanied by
appropriate in-house, or if necessary,  extramural training.

     Selected personnel are also trained in tasks different from
their regular assignments.
                              F-133

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           7.0  INSTRUMENT MAINTENANCE AND CALIBRATION
     PEDCo Environmental, Inc. maintains Preventive Maintenance
and Service Contracts with the manufacturers of all major instru-
ments in use in the laboratory (Finnigan Corporation, Hewlett-
Packard Company, Perkin-Elmer Corporation).   Maintenance logs are
compiled for each major instrument.
7.1  INORGANIC SECTION

     The following calibration procedures are followed:

     0    Analytical balances are checked with class S weights
          each day that they are used.  If a trend in inaccuracy
          is found,  and cannot be corrected by PEDCo personnel,
          professional service is obtained.  The balances are
          serviced and checked by an NBS certified service agent
          each year.

     0    Atomic absorption spectrophotometers are calibrated for
          each metal analyzed and a record kept of instrument
          response.   Should a lack of sensitivity or other mal-
          function be detected that cannot be corrected in-house,
          professional service is obtained.

     °    Ultraviolet/visible spectrophotometers are checked with
          standard color cuvettes each day they are used, and
          checked for mirror and grating alignment monthly.
          Service criteria are as described for the other in-
          struments.

     0    The bomb calorimeter is calibrated monthly as recom-
          mended by the manufacturer.


7.2  ORGANIC SECTION

     Gas chromatographs and the gas-chromatograph-mass spectrom-
eters are calibrated when used, for sensitivity, accuracy and
accurate mass assignment.  If the required sensitivity cannot be
obtained, prescribed maintenance procedures are initiated.  If
these do not enhance the instrument response to the level desired,
professional service is obtained.
                               F-134

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               8.0  GLASSWARE CLEANING PROCEDURES
8.1  INORGANIC SECTION

     Glassware is routinely cleaned with an alkaline detergent,
rinsed with hot tap water, and oven dried.   Before use, each
item is rinsed with deionized water and/or  the solution to be
used.  Glassware to be used for trace metal analyses is cleaned
in either alcoholic sodium hydroxide or chromic acid, followed
by a soak in 1:1 nitric acid and a rinse with deionized water
(ASTM TYPE I).
8.2  ORGANIC SECTION

     In the organic laboratory involved in the analysis of sam-
ples containing residues in the parts per billion range, the
preparation of scrupulously clean glassware is mandatory.  Par-
ticular care must be taken with glassware such as Kuderna-Danish
flasks, evaporative concentrator tubes, or any other glassware
coming in contact with an extract that will be evaporated to a
lesser volume.

     Basic cleaning steps are as follows:

     0    Remove surface residuals immediately after use.

     0    Hot soapy soak to loosen and flotate most of residue.

     0    Hot water rinse to flush away flotated residue.

     0    Soak with deep penetrant or oxidizing agent to destroy
          traces of organic residue.

     0    Hot water rinse to flush away materials loosened by
          deep penetrant soak.

     0    Rinse with distilled water to remove metallic deposits
          from the tap water.

     0    Rinse with high purity acetone followed by high purity
          methylene chloride.

     0    Bake in a muffle furnace at 400°C for 30 minutes.

     0    Flush the glassware just before using with the same
          solvent to be used in the analysis.


                              F-135

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                     9.0  SAFETY PROCEDURES


9.1  LABORATORY CONDUCT

     0     Follow instructions exactly.

     0     Perform only authorized experiments.

     0     Protect eyes, face, hands and body.

     0     Practice good housekeeping.

     0     Learn basic first aid.

     0     Know where to get help quickly.

     0     Know location of first aid and fire  fighting equipment.

     0     Report all accidents and unusual occurrences immedi-
          ately.

     0     Be professional.


9.2  FIRE PREVENTION

     0     Store all flammable liquids in the fireproof cabinets.

     0     Whenever possible,  and always when large quantities are
          involved, use flammable liquids in a fume hood.   When
          it is necessary to use flammables  on an open bench, be
          certain that there are no open flames nearby.

     0     Place waste flammable liquids in the appropriate
          safety cans for disposal.

     0     Dispose of solid and liquid oxidants, such as perox-
          ides, perchlorates, and nitrates,  by flushing down the
          sink with water.  Keep these materials away from flam-
          mable items such as wood and paper.

     0     Be certain not to overload electrical circuits.   Do not
          use equipment with worn or bare wiring.
                              F-136

-------
          Be aware of the two types of fire extinguishers in the
          laboratories.  The dry chemical (ABC)  type is for use
          on paper, liquid, or electrical fires.   The C02 (BC)
          type is for use on liquid or electrical fires.

          Know the location of the fire alarms on the hall wall
          near the northeast exit stairwell and in the elevator
          area.
9.3  PREVENTION OF POISONING
          Use toxic materials such as chlorine gas,  cyanides,  and
          bromine in a hood only.   These are inhalation hazards,
          and some are toxic by skin absorption.   Use gloves when
          handling bromine.

          Some compounds in use in the lab are slow-acting
          poisons when ingested or absorbed in small amounts.
          Among these are arsenic, mercury, lead,  and hexavalent
          chromium compounds.  Wear gloves when handling these
          compounds in high concentrations and wash  hands thor-
          oughly after use.

          Clean up all chemical spills,  even of seemingly harm-
          less materials.  One spill may react with  another.
          Neutralize concentrated  acids  with sodium  carbonate
          (Na2C03), and bases with boric acid (H3B04) before
          cleaning up.

          Always use a rubber bulb to pipet.

          Exercise care in handling of all samples.   Their
          contents are unknown.

          Do not eat, drink, or smoke in the lab work areas.

          If you have any questions about handling a particular
          compound or reaction, consult  your supervisor, the wall
          chart, or the CRC Handbook of  Laboratory Safety.
9.4  PERSONAL SAFETY

     0    Clean up all water spills on the floor.

     0    Use only equipment and tools suited to the job at hand.

     0    Dispose of broken glass only in the marked container.
                             F-137

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          Do not wear loose clothing or open-top shoes.   Wear a
          laboratory coat at all times and a rubber apron,  gog-
          gles,  or gloves when indicated.
9.5  SAFETY EQUIPMENT
          Know how to use the following items in the laboratory:
          fire extinguishers, fire blankets,  safety showers,  eye
          wash stations,  first aid kits and the rescue air pack.
9.6  GENERAL
          Protective Clothing - Each employee will  be provided a
          sufficient number of laboratory garments  (i.e.,  lab
          coats,  smocks,  etc.)  to be worn at all  times while in
          the laboratory.   Care of these  garments by  the  laundry
          service company is the responsibility of  the employee.
          Each employee should have one clean garment available
          at all  times.

          Eye Protection  - Safety glasses are required under
          Federal law and must be utilized.   Custom-fit safety
          glasses or corrective lenses are furnished  by PEDCo.

          Foot Protection - Conventional  street-type  footwear is
          sufficient.   Sandals,  canvas, or similar  footwear
          should  not be worn in the laboratory.

          Miscellaneous - Rubber,  cloth,  or  leather gloves are
          available  for hand protection and  must  be worn  whenever
          the occasion warrants.

          Exits - Be conscious at all times  of the  nearest lab-
          oratory exit and nearest building  exit.
                           F-138

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     APPENDIX G




PROJECT PARTICIPANTS
          G-l

-------
           TABLE G-l.  PROJECT PARTICIPANTS AND RESPONSIBILITIES
  Name
      Title
     Field test assignment
C. Bruffey
D. Osterhout
D. Scheffel


R. Antesberger



P. Clarke



G. Meiners


D. Fitzgerald


M. Phillips
Mr. Melvin Belich


Mr. Robert Budd


Mr. John Burckle

Mr. Al Vervart

Mr. James Nolan
 Project Manager
    Engineer
   Technician


   Technician



    Engineer



   Technician


   Technician


    Engineer




    ASARCO


    ASARCO


U.S. EPA - IERL

U.S. EPA - OAQPS

    PSAPCA
Coordinate test activity, process
monitoring, liaison with plant
and EPA personnel

Site leader; filterable particu-
late/arsenic and particle size
tests at air curtain hooding
system test site;  meter reader
particle size trains

Filterable particulate/arsenic
tests; meter reader

Assist at sample site with par-
ticle size and filterable par-
ticulate/arsenic tests

S02 continuous monitor operator;
obtain manual and perform titra-
tions for S02 analysis

Perform tracer study tests, SFg
injections, and GC analysis

Assist with tracer study, per-
form SF, injections

Setup and recovery of filterable
particulate/arsenic and particle
size sampling trains, assist with
particle size tests

Coordinate test activity relative
to process operation

Coordinate test activity relative
to process operation

Observer

Observer

Observer
                                     G-2

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       APPENDIX H




VISUAL OBSERVATION LOGS
           H-l

-------
                LOG KEPT BY

              ALFRED VERVAERT
EMISSION STANDARDS AND ENGINEERING DIVISION
   U.S. ENVIRONMENTAL PROTECTION AGENCY
     RESEARCH TRIANGLE PARK, NC  27711

          PHONE:  (919) 541-5601
                     H-2

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                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 18, 1983

0802      Started on finish blow; two ladles of cold dope were added at
          about 0815; observer was not present to view;  Jim Nolan observed
          additions; capture <50%; Burckle says limit switch was not acti-
          vited; switch reactivated manually

0845      No. 4 on Cu blow; no visible emission from 1°  hood; no visible
          emission from 2° hood; observer location directly across aisle
          from No. 4 converter; eye level with upper part of 1°; lighting
          conditions generally poor; no light above No.  4 converter, heavy
          overcast; light background visible emission due to balloon flue
          leakage.  Observer:  Alfred E. Vervart

0851      Started punching, no visible emission out of 1° hood

0900      No visible emission from 1° or 2° hoods; finish blow continues

0916      1° roll out; heavy visible emission for 15 seconds during roll
          out; 75% effective; 100% capture while awaiting crane; moderate
          visible emission from mouth

0910      No. 4 partially rolled out; awaiting ladle

0911      Cu pour slow; moderate to heavy visible emission; little or no
          spillage or penetration; capture 95%

0914      End Cu pour; No. 4 still partially rolled out; low to moderate
          visible emission; capture 100%

0915      Cu pour (1 minute in duration); moderate visible emission; slight
          spillage out of front of 2° hood; capture 95%  or better; little
          or no penetration

0916      No. 4 still partially rolled out; light emission; capture >98%

0921      Small ladle of blister Cu charged to No. 4; moderate to heavy
          visible emission; capture >95%

          Note:  Blister returned, not blown enough; will resume Cu blow

(continued)
                                   H-3

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Log Book No.  1                                           No. 4  Converter

0923      No.  4 rolled in partially -  on  idle;  plugged  instrument  line at
          S02  plant, should take 25-30 minutes  to  fix and go back  on  line.

0950      No.  4 on hold,  should resume at 1100  a.m. when  instrument lines
          are  repaired;  no visible emission  from 1° or  2° hood

1000      Stopped observing

1025      Returned to observation site; No.  4 still on  hold; no visible
          emission from 1° or 2° hood

1045      1°  hood raised; No. 4 rolled in/l° hood  lowered and blowing
          commenced; light visible emission; capture  100%

1100      Cu  blow continues;  no visible emission from 1°  or 2°  hood

1109      Cu  pour - visible emission heavy for  about  12 seconds during
          initial roll out; 30% OP, escaping capture; capture 70%; moderate
          visible emission during actual  skim;  no  visible emission seen
          spilling out front  or penetrating  air curtain;  capture >95%

1113      Cu  pour completed;  No. 4 continues to be rolled out awaiting
          crane and ladle

1115      Cu  pour, moderate to heavy fume; no spillage  observed; perhaps
          slight penetration; very light  <10% OP;  capture >95%

1116      End  Cu pour; No. 4  awaiting  ladles; 100% capture of visible
          emission from 1° hood mouth

1122      Cu  pour (30 seconds in duration);  slight spillage, 10% OP out
          front for about 5 seconds; felt strong breeze;  capture >95%
          overall; 100% capture after  pour while awaiting ladle

1130      Cu  pour (30 seconds duration);  moderate  to  heavy emission;
          spillage out front  of hood (upper  right, 20%  OP); felt wind
          currents through aisle; overall effectiveness,  90%

1131      Cu  pour (30 seconds); heavy  fume;  spillage  out  of front right
          side; 30% OP;  quantity judged to be moderate  amount;  worst  pour
          observed by far; appear to be wind currents running from left  to
          right; overall  effectiveness, 80%; some  penetration through air
          jet  but light

(continued)
                                  H-4

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Log Book No. 1                                           No.  4  Converter

1137      Cu pour (40 seconds in duration);  moderate  to  heavy fume;  spill-
          age out right front for 15 seconds;  capture 80%;  appears that
          greater rotation of converter due  to lowering  of  Cu content
          creates a horizontal  thermal  effect  which pushes  fume out

1142      Cu pour (10 seconds); spillage seen  out  front;  maximum 30% OP;  no
          penetration of air jet; capture 80-90%

          Emissions following pour are  light;  capture 100%

1146      Cu pour (1 minute); fume moderate; little or no spillage or
          penetration; pour appeared to be better  controlled  (i.e.,  poured
          more slowly); may have effect on emissions; capture >95%

          Awaiting ladle;  little or no  visible emission  from  No.  4 mouth;
          ASARCO informed  me that that  was end of  cycle  (at 1150); No. 4
          now on idle

1200      Cu pour (10 seconds); fume light to  moderate;  no  front spillage
          or penetration evident; capture 100%

1204      Ladle brought in place; Cu pour (1 minute); visible emission
          light to moderate; little or  no spillage or penetration observed;
          if so, only slight; capture >95%

1210      Cu pour, final;  visible emission light to moderate; no spillage
          or penetration observed

1235      Notified that matte ladles would be  charged; one  was  charged
          while we were not present, communication breakdown; PEDCo  started
          testing on time, however

1237      Matte charge No. 2 (5 minutes); fume heavy  to  very  heavy;  slight
          penetration of air jet; however, emissions  seem to  be swept back
          in; capture >95%; fire in No. 4 heavy; crane operator swinging
          ladle to open mouth and charge skulls; fume from  ladle while
          swinging discharged out front; hold  fire in No. 4;  very light
          visible emission; capture 100%

1240      No. 3 matte charge (30 seconds); fume heavy to very heavy; cap-
          ture >95%; some  penetration,  but slight; somewhat higher penetra-
          tion when ladle  is removed; essentially  complete  capture while  on
          hold fire

(continued)
                                  H-5

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Log Book No. 1                                           No.  4  Converter

1243      Cu slag charge, material  is very flammable and  fumes  severely;
          extremely heavy fume and  fire;  capture >90%;  however, substantial
          quantity of fume penetrating air jet

          System appears to be overwhelmed by both amount of  fume  and high
          temperatures (deviation 15 minutes); opacity  of escaping fume,
          40-50%; severe leakage was sighted behind the 2° hood, source
          unknown; also leakage out of silica charge chute; end at 1258

1300      No.  4 matte charge (10 seconds); some penetration;  too fast to
          assess capture effectiveness; check Nolan's log

1305      Anode slag; again fire in converter very heavy; fume  extremely
          heavy; some penetration;  90% capture at worst;  >95% at best;
          opacity of escaping emissions 10-20%; very small quantity com-
          pared to volume of fume generated; time 3 minutes;  some  pene-
          tration when ladle retracted, 10 ft plume at  30% OP for  5
          seconds; hood performance pretty outstanding  considering duty

1311      Moderate to light 1° hood leakage; slight penetration; <5% OP;
          capture 90%

1313      No.  5 matte charge (15 seconds); fume very heavy; some penetra-
          tion for 5 seconds; 30% OP close to top of hood; appears most  is
          swept back in, however; capture >95%; 1° continued  to leak mod-
          erately; slight penetration <10% OP; capture  95%

1325      Light fume from hold fire; slight penetration due to  turbulence;
          capture >95%

1327      No.  6 matte charge (30 seconds); very heavy fume; slight losses
          through air jet; <20% OP; capture >95%; fume  continues to leak
          out of 1° hood during hold fire; slight losses; capture  >95%

          Note:  Lighting conditions have improved; sun is coming  out

1335      Leakage at mid-point of 1° hood continues; 2° hood  gets  nearly
          100% of 1° hood leak; wisps escaping

1340      No.  7 matte charge (30 seconds); heavy fume;  slight wisps es-
          caping through top; >95%  capture; truly remarkable  considering
          thermal draft and mechanical forces at play

1344      1° hood raised heavy fire; ladle of Cu slag added (1  minute
          duration); fume extremely heavy; some penetrating air jet; system
          gets overwhelmed with time (cannot clear all  fume generated in
          time); capture 95%

(continued)
                                   H-6

-------
Log Book No. 1                                           No.  4  Converter

1558      Skim No.  3 (duration 60 seconds);  heavy spillage  out  front;  looks
          like fume is affected by wind currents; spillage  from both  sides
          but right side predominant;  >30%OP;  capture  <60%

          Note:   Ladle location okay

          No. 4  remains rolled out; light fuming from  mouth;  capture  100%;
          no visible emission escaping

1546      Matte  charge (10 seconds); heavy fume; 95% capture; slight  wisps
          penetrating air jet; especially when lade is retracted

          No. 4  awaiting additional charge

          Note:   No. 4 will  be held overnight; expansion  joint  leak at acid
          or S02 plant causing curtailment

1617      Matte  charge (10 seconds); visible emission  penetrating  air jet;
          20% OP and for about 1-2 seconds;  capture >90%; No. 4 fuming from
          mouth  while awaiting charge; capture 100%; slight wisps  escaping;
          aisle  seems windy

1620      Matte  charge; fume heavy; spillage from front and penetration for
          3 seconds; 20-30% OP; capture >80%;  feels windy

1622      No. 4  rolled in/on hold; blowing will  resume in a.m.
                                 H-7

-------
                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 19,  1983

          Slag blowing on No.  4 will resume at 0730

0722      No.  4 on hold;  no visible emission from 1°  or 2°  hoods;  no  visi-
          ble  emission from converter mouth

          Observer location directly across asile from No.  4  converter;
          lighting conditions  poor; sky is overcast and predawn

0725      1° hood raised; ladle of shell  slag charged (duration  li  min-
          utes); light to moderate fume or dust; no spillage  or  penetration
          observed; capture 100%; No. 4 back on idle

0729      No.  4 rolled in and  slag blowing commenced; little  or  no visible
          emission observed

0732      1° hood leakage; light; capture 100%; reset watch

          Silica charging started at 0732

0734      Stopped silica  charging

0740      Tuyere punching started; no visible emission; punching stopped at
          0741.5

0745      No.  4 on slag blow;  no visible emission sighted

0756      Tuyere punching; no  visible emission

0800      No visible emission  sighted during previous 15 minutes

0804      Tuyere punching; no  visible emission

0807      Skag skim (2i minutes); very heavy fume during roll  out;  capture
          <50%; 2° hood system overwhelmed for 5-10 seconds;  heavy penetra-
          tion; 40-50% OP; during actual  skim spillage out  front,  but rela-
          tively light; penetration moderate to heavy; it appears  that
          thermal currents, etc., create too much turbulence;  capture <70%;
          No.  4 awaiting  ladle for additional skimming; visible  emission
          from mouth; capture  100%

(continued)
                                   H-8

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Log Book No. 1                                           No.  4 Converter

0815      Slag skim (2i minutes); best skim viewed thus far;  fume generated
          was moderate to heavy; some spillage out front of hood; 20% OP;
          spillage light, however

          Note:  It appears that some of the spillage is recaptured by the
          hood

          Penetration through air jet light; capture effectiveness ranged
          from 85-90%

0823      Slag skim (3 minutes); slag poured out slowly; spillage out front
          generally light; some penetration on occasion, but light; capture
          ranged from <80-90%

          Note:  Rate of pouring seems to have a significant affect on gas
          volume and fume generated

          No. 4 back on hold; 1° hood partially up; light visible emission
          from mouth; capture 100%

0830      Matte charge (30 seconds); heavy fume; little on no penetration;
          capture >95%

0834      Matte charge (30 seconds); again, little or no penetration; only
          slight wisps; capture >95%; OP of wisps <20%

0836      Shell slag ladle (30 seconds); fume ranged from moderate to
          extremely heavy; system overwhelmed for brief period of about 5
          seconds; moderate penetration at 30% OP; light to moderate spill-
          age at right front for about 2 seconds (20% OP); capture effec-
          tiveness 85-95%; overall 90%

0840      Shell slag ladle (1 minute); fuming was light; capture 100%

0842      No. 4 rolled in, resumed slag blow; visible emission during roll
          in moderate to heavy; capture >95%

0854      Very light fume leaking from 1°; capture 100%; duration 5 seconds

0856      Slight puffing from 1°; no visible emission from 2° hood

0902      Blowing/tuyere punching; no visible emission from 1° or 2° hood

0905      Condition unchanged; tuyere punching discontinued

(continued)
                                 H-9

-------
Log Book No. 1                                           No.  4 Converter

0910      Condition unchanged; tuyere punching repeated

0912      No. 4 roll  out, slag skim; poured slag rapidly (1 minute);  fume
          heavy to very heavy; spillage out front, 20-30% OP; penetration
          about the same; substantial turbulence within confines of the 2°
          hood; system overwhelmed; appears to be dead spot across front of
          hood; visible emission observed escaping capture during entire
          slag skim;  No. 4 remained rolled out; light fuming from mouth;
          capture 100%

          Note:  Fume always moves from left to right; cause unknown

0922      Slag skim (3i minutes in duration); pouring rate moderate;  fuming
          moderate to heavy; spillage front right front continues; also
          penetration of air jet; penetration light except for 5 seconds;
          fume rolling back into front is evident again; 20-30% OP; end
          skim at 0926

          Capture ranged from <80-90% as skimming proceeded;  pouring  rate
          appears to  affect emissions; No. 4 awaiting ladle

0932      Matte charge (15 seconds duration); slight penetration; capture
          95%; penetration consisted of light wisps; 1° hood completely
          retracted;  fuming from converter mouth light; no visible emission
          from 2° hood; capture 100%

0936      Shell slag  charge (15 seconds); initially fume extremely heavy
          and dusty;  system overwhelmed for 2-5 seconds; thermal rise of
          fume very fast; penetration heavy; 60% OP; capture range 40-95%;
          overall - 85%

0939      Matte charge (18 seconds); capture >95%; light wisps at top

0940      Roll in and commence slag blow

          Note:  1° hood has very good draft; little or no visible emission
          from 1° hood during roll in
0945      Light visible emission from 1°; no visible emission from 2

1005      No visible emission from 1° or 2° hood

(continued)
                                                                    o
                                    H-10

-------
Log Book No. 1                                           No.  4  Converter

1007      Slag skim (3 minutes);  No.  4 rolled  out quickly;  blowing  air
          still  on; very heavy fuming overwhelmed air jet;  capture  <50%;
          By end of skim, capture improved to  80%; penetration  and  spillage
          from upper right front  continued over entire skim;  skimming rate
          was very fast

          At end of skim, No.  4 rolled in and  blowing air activated; devia-
          tion 2 seconds; capture 90%
                                                                   o
1015      Skimming ladle returned;  no visible emission  from 1°  or  2

1020      Slag skim;  control  over initial  roll  out  was  poor again; capture
          over roll  out <50%; heavy visible emission  above  2° hood;  30-40%
          OP; fume during actual  skim, heavy; pouring rate  slow to moder-
          ate; fume  escaping  out  front on  right side; 20-30% OP of fume;
          some penetration through  top, especially  top  front

          Condition  fairly constant throughout skim

          Duration of skim -  7 minutes

          No. 4 will  be on standby  for 2 hours

1127-     Two cold additions  (scrap)
1135

1143      Begin finish blow

1200      Blowing; no visible emission from 1° or 2°  hood

1228      Roll out of converter for scrap  charge; observed  medium  to light
          emission ~20% OP for 30 seconds  leaving hood  about 15% escaping

          Scrap charge 1229;  heavy  emission, 90% OP within  hood; emission
          generated  for about 30  seconds;  opacity of  about  60-70%; esti-
          mated capture eff.  for  this period was 70-80%; penetration quickly
          ceased and cap. eff. "90-95% observed

          Ladle No.  2 charged at  1235; heavy emissions  within hood for
          15-20 seconds; approximately 15-20% escaping  through  ac  slot
          during this time; opacity of escaping fume  50-60% (i.e., lighter
          or less dense than  first  ladle); a.c. quickly cleared at top and
          penetration ceased; Remainder of fume cleared quickly and  effec-
          tively; hood closed at  ~1238; return to blowing;  no visible
          emission within 1°  or 2°  hood
          Two preceeding charges were observed under improved  lighting
          conditions;  sun is out
(continued)
                                    H-n

-------
Log Book No.  1                       .                    No.  4  Converter

1245      No  visible emission observed  from either 1°  or  2°  hood  since  roll
          in

1300      No  visible emission observed  from 1°  or 2° hood since 1245

1312      No.  4 roll out (5 seconds); moderate  to heavy fume  for  5  seconds
          during roll  out period;  fume  penetrated air  jet; moderate at  30%
          OP;  2° hood capture improved  immediately after  blowing  air  was
          shut off

1315      Converter mouth fuming;  100%  capture

1316      Scrap charge (1 minute);  fume heavy to very  heavy;  some penetra-
          tion but light, 20% OP;  capture >90%

1317      Scrap charge;  large piece of  scrap dropped into bath; very  heavy
          fume; light penetration;  capture >90%

1319      No.  4 rolled in and continued blowing; some  penetration during
          roll in when blast air activated; capture >90%

1330      No  visible emission from 1° or 2° hood since roll  in

1345      No  visible emission from 1° or 2° hood since 1330

1356      Light fume from primary  hood  leak; capture 100%

1358      Moderate fuming from 1°  hood; capture 100%;  cause  unknown

          Took a break;  returned at 1415; scrap charge took  place prior to
          return; Jim Nolan observed; No. 4 still on Cu blow; no  visible
          emission from 1° or 2°

          Note:  Stopped sampling  at 1400; end  of previous Cu blow if this
          Cu  blow considered representative
                                      H-12

-------
                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 20, 1983

0704      No. 4 has hold fire; met conditions are not favorabe for smelt-
          ing; lighting in aisle is poor, predawn; observer location
          directly across No. 4 converter

0822      Matte charge (45 seconds); fuming from No.  4 extremely heavy,
          prior to actual charge; cause unknown; heavy visible emission
          above 2° hood; capture <50%; during the actual  charge, emissions
          continued to penetrate the air jet; capture during actual  charge
          90%

          Hold fire on No. 4; generating moderate emissions; capture 100%

          Note:  Jim Nolan said that matte was actually being poured into
          No. 4 when heavy fuming started

0833      Hold fire continues to generate moderate fuming;  capture 100%;  no
          visible emission observed escaping 2° hood

          Note:  Lighting conditions improving; sky is overcast, therefore,
          no direct sunlight

0840      Matte charge 1 (20 seconds); fuming moderate to heavy; light
          visible emission (15% OP) seen penetrating  the air jet; fuming
          within the 2° hood appears more turbulent than usual; capture
          >90%

          Fuming from hold fire continues; slight wisps of fume may be
          escaping through the air jet; 1° hood was partially lowered;
          reduced hold fire fuming substantially (75%)

0854      Matte charge 2 (20 seconds); fuming moderate to heavy; light
          wisps appear to be escaping through air jet; capture 95%

0909      Matte charge 3 (25 seconds); fuming moderate to heavy; visible
          emission seen above air jet for 5 seconds at heaviest point in
          fuming; >20% OP; again, conditions within the 2°  hood seem more
          turbulent than previously observed; capture >90%; range 85-95%

0915      Fuming from hold fire continues; capture >95%; a  barely percepti-
          ble quantity of fume seems to be escaping due to  turbulence above
          the air jet

(continued)
                                      H-13

-------
Log Book No.  1                                           No.  4  Converter

0926      Matte charge 4 (25 seconds);  fuming moderate  to heavy;  overall
          capture >90%; large puffs of  fume penetrated  air jet  at right
          rear of the hood;  opacity of  puff 30%;  additional  fume  penetrated
          the air jet when the ladle was  withdrawn

0930      Hold fire fuming moderately;  light wisps appear to be escaping;
          capture 95%

0939      Moved closer to No. 4 converter;  light  fuming out of  2° hood
          definitely observed

0944      Matte charge 5 (25 seconds);  fuming moderate  to heavy;  again,
          puff of fume penetrated jet at  right rear;  believe this is  due  to
          unused block and hook blocking  air jet; capture 95%

0947      Ladle of slage shells; fume heavy to very heavy; substantial
          penetration at rear right again;  large  emission, 40%  OP;  overall
          capture nevertheless was 95%; some spillage out the front upon
          withdrawing the ladle

0952      Ladle of slag shells (28 seconds); event identical  to 0947  charge
          of slag shells; fume escaping may have  been denser (60% OP); took
          several minutes for air jet to  catch up with  escaping fume  and
          achieve >95% capture

0958      Hold fire reduced  substantially;  little or no fume evident; matte
          charge 6 (18 seconds); fume heavy to very heavy; capture 95%
          overall; however,  large puffs at  rear right occurred  again

1000      Commenced blowing; heavy fuming from primary  hoods for  about 2
          minutes; capture 95%; some losses evident above air jet

1005      Moderate to heavy  1° hood leakage is continuing; 2° hood capture
          95%; some losses out of top;  fume appears to  roll  back  over air
          jet

1008      Silica addition; heavy leakage  out of 1° hood; capture  95%

1009      Substantial fuming behind the 2°  hood;  source is unknown

1011      1° hood leakage continuing; fume  very dense,  80%; capture >95%;
          fume behind hoods  less substantial

1014      Silica charging stopped; 1° hood  leakage abating

1015      Heavy leakage reappeared for  about 5 seconds

(continued)
                                    H-14

-------
Log Book No. 1                                           No.  4  Converter

1016      Heavy leakage reappeared for abuot 30 seconds;  capture  >95%

1018      Heavy 1° hood leakage continues to occur for 30 seconds every
          minute; capture 95%; cause of leakage unknown;  may  be problem
          with 1° draft or too high blowing rate

1023      1° hood leakage appears to be predictable;  15 seconds,  no  leaks;
          then heavy leakage for 40 seconds; (basis:   stopwatch timing of
          event); capture >95%

1031      Cycle of 15 seconds, no 1° leakage followed by  40 seconds  1°
          leakge is continuing; 2° hood capture >95%; light wisps escaping
          from top

1035      1° hood leakage appears to be stopped; no visible emission from
          1° or 2°

1044      Extremely heavy leakage from all  parts of 1° hood and converter;
          capture effectiveness of 2°, >95%; rolled out No. 4 at  1045 and
          proceeded with a small skim; visible emission seen  at top  of hood
          and spilling out front; capture >80%

1049      Slag skim continued; this time ladle held up by crane nearer to
          mouth; pouring rate was moderate; fume moderate to  heavy;  spill-
          age out of front during most of skim (20% OP);  light  penetration
          at air jet; capture 90%; duration skim 3 minutes

1054      Slag skim (2 minutes); initial skimming resulted in moderate
          plume escaping unit front for 5-10 seconds; opacity of  plume 30%;
          pouring rate was relatively fast; spillage out  front  continued
          for most of skim; capture 70-80%; overall 80%

1059      Slag skim (2 minutes); visible emission observed spilling  out
          front and some penetration of air jet; opacity  20%; ladle  was
          only partially filled; overall capture 85%; range 80-90%

1110      Matte charge 6 (15 seconds); fume moderate to heavy,  brief
          puffing at right rear at end of charge; capture >95%

          Note:  Spare block on crane was raised

1111      Matte charge 7 (18 seconds); fume moderate to heavy;  capture >95%

1114      Matte charge 8 (20 seconds); fume heavy; little or  none escaping;
          capture >95/c

1117      Slag shells (20 seconds); fume moderate; capture 100%

(continued)
                                      H-15

-------
Log Book No.  1                                           No.  4  Converter

1118      Slag shells (20 seconds);  fume moderate;  capture  100%

1119      Roll in of No.  4; very heavy to extremely heavy fume; no spill-
          age, some air jet penetration; capture  during  roll  in >95%

1120      1°  hood down; heavy leakage; turbulence and some  penetration  of
          air jet at top; capture >95%; heavy background visible emission

          Heavy visible emission from silica feed chute; 1° hood leakage
          continuing to be very bad; fume turning yellow; system completely
          overwhelmed; 100% OP everywhere

1125      Rolled out No.  4; placed on hold;  obviously there is  a problem at
          the acid and S02 plants; no 1° hood draft

1129      Rolled No. 4 in; 100% OP cloud overwhelmed the system; rolled out
          No. 4 immediately; this is an upset condition

1214      Attempted to roll in No. 4; damper problem still  evident; tremen-
          dous quantity of fume generated when No.  4 returned to blowing
          status; rolled No. 4 back  out at 1215

          No. 4 converter rolled in  on slag  blow  at 1350

1400      No  visible emission from 1° or 2°  hood

1405      Tuyere punching; no visible emission from 1° or 2°  hood

1413      Tuyere punching; no visible emission from 1° or 2°  hood

1417      Tuyere punching; no visible emission from 1° or 2°  hood

1424      Slag skim (less than 2 minutes); visible  emission heavy during
          roll out; slag flow is very fast;  spillage from front (right
          side) substantial; also, some penetration of air  jet; overall
          capture 70%

1430      No. 4 on idle awaiting slag ladle; no visible  emission from mouth
          on  2° hood

1433      Slag skim (li minutes); skimming rate very fast;  visible emission
          seen at front and above 2° hood; fuming moderate  to heavy;  cap-
          ture effectiveness 70%; opacity of escaping emission  20-30%;
          visible emission at front  moving from left to  right;  turbulence
          within hood very substantial

(continued)
                                     H-16

-------
Log Book No. 1                                           No.  4  Converter

1439      Slag skim (2 minutes 45 seconds);  skimming  rate fast;  fuming
          heavy/turbulent; fume escaping from right side of 2°  hood;  opac-
          ity 10-20%; some penetration,  difficult to  judge opacity; capture
          ranged from 70-80%

          Note:   1° hood all the way up

1449      Matte charge 9 (30 seconds);  fuming is heavy;  some spillage due
          to swinging of ladle to break  skull;  duration  of spillage 5
          seconds; capture effectiveness 90-95%; little  or no penetration
          observed

1452      Matte charge 10 (25 seconds);  fuming  was heavy; no spillage
          observed during actual charging;  slight wisps  at top  of  air jet;
          capture 95%

1454      Slag shells (18 seconds); very heavy  fume;  some penetration for
          about 3 seconds; opacity 30-40%;  capture effectiveness >95%

1457      Shell  slag (25 seconds); fuming light to moderate; no escaping
          emission observed; capture >95%

1500      No. 4 rolled in; slag blowing  resumed; fume heavy; some  escaping
          on two occasions from upper middle of opening; similar to being
          wind blown; opacity 20%; capture  95%

1505      Silica addition; no visible emission  from 1° or 2° hood

1510      Silica addition completed; no  visible emission observed  at  any
          time

1515      Tuyere punching; no visible emission  from 1° or 2°

1525      Tuyere punching; no visible emission  from 1° or 2°

1530      Tuyere punching; no visible emission  from 1° or 2°

1537      Slag skim (50 seconds); extremely  heavy fuming; operator did  not
          cut back on blast air until skimming  began; fume overwhelmed  2°
          hood;  capture effectiveness undetermined; skim pouring rate very
          fast;  fume heavy; fume spilling out from front of hood (right
          side); capture estimated at 70%

          No. 4 awaiting slag ladle; fume light; capture 100%

1545      Slag skim (54 seconds); fume heavy; pouring rate very fast;
          losses out front substantial,  30-40%  OP; capture 70%

(continued)
                                   H-17

-------
Log Book No.  1                                           No.  4  Converter

1554      Matte charge 11 (20 seconds);  fume  heavy;  light penetration
          through air jet; no spillage from front; capture >95%

1608      Matte charge 12 (15 seconds);  fume  heavy;  light wisps escaping
          through air jet; no spillage out front;  capture >95%

1615      Roll in No. 4; capture 100%

1655      Slag skim; air curtain damper setting  backed  off to 0% (closed)
          to  determine if air jet actually exacerbates  control  problem;
          fume moderate to heavy; spillage out front less than  usual,  20%
          OP; some penetration but not much;  fume  moves from  right  to  left
          and into exhaust hood; capture judged  to be 80-90%

1703      Slag skim with air curtain  damper closed;  skim rate is fast; fume
          heavy; fume moving up right side of hood;  spillage  20-30% OP;
          penetration difficult to determine  because of darkness above 2°
          hood; turbulence inside of  hood reduced  but increase  in capture
          effectiveness unknown; capture 80%

          Note:  Next skim will have  air curtain activated

1732      Rolled No. 4 back in; slag  blow moderate fume, 100% capture

1735      Tuyere punching; no visible emission from  1°  or 2°

1756      Roll out for slag skimming; skimming rate  moderate  (3i minutes);
          very heavy fume or roll out; overwhelmed 2° hood; heavy fume on
          skimming; large quantity of spillage out the  front; fume  going
          out to middle of aisle; penetration undetermined due  to fume in
          front of hood; capture ranged from  40-70%

1808      Added a large piece of scrap (blister);  heavy fume  generated;
          light penetration of air jet;  95% capture  overall

1810      Added another piece of blister to cool bath;  fuming moderate;
          capture >95%

1812      Third piece of blister added;  fume  moderate;  light  wisp escape;
          capture >95%

1814      Fourth piece of blister added; fume light; capture  100%

(continued)
                                    H-18

-------
Log Book No. 1                       .                    No.  4  Converter

1815      Rolled in No.  4 to start finish blow (duration  5  seconds);  heavy
          fume; fume at  20-30% OP; penetrated the  air jet for about 2
          seconds; capture 90%

          Note:  Did not observe from 1830 to 1900

          Returned at station at 1900;  No.  4  on hold; no  visible  emission
          from 1° or 2°  hood

          Copper blow restarted at 1921

1945      No.  4 still on copper blow; no visible emission from  1° or  2°
          hood

1959      No.  4 rolled out; light visible emission seen over  top  of hood
          for  10 seconds; fume moderate; capture effectiveness  90% during
          roll out; No.  4 in hold mode  due to SCS
                                    H-19

-------
                TEST ON  SECONDARY  HOOD
                    NO.  4  CONVERTER

                   January 21,  1983

No testing was conducted on the  21st  due to weather
(curtailment)
                          H-20

-------
                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 22, 1983

0827      No. 4 on hold; 1° hood partially down; no visible emission from
          1° or 2°

          Note:  Will attempt to sample only slag skims when No.  4 is
          rolled out for TSP, AS, and particle size

          Status:  No. 4 on third slag blow

0905      Lighing, overcast sky; 1° hood raised; hold fire off;  No.  4 on
          idle

0907      Slag shell addition (20 seconds); heavy fume; spillage out front
          (upper right) for about 2 seconds; 30% OP; penetration at  air
          jet, 30% OP; duration, 5 seconds; capture effectiveness, range
          90-95%; overall 95%; fume opacity, 40-60-100%

0911      Slag shell addition (40 seconds); fume light to moderate (black);
          no spillage or penetration; capture 100%

0913      Rolled No. 4 in and commenced slag blow; fume moderate; some
          penetration of air jet; duration 10-15 seconds; capture effec-
          tiveness 90%

          Note:  Relatively heavy fugitives from right side of converter;
          source unknown; background fugitives fairly high (smokey or hazy
          in aisle); source of fugitives appears to be right rear of No. 4
          converter; fugitives moving from left to right in front of No. 4

0920      Tuyere punching; no perceptible visible emission from 1° to 2°;
          fugitives from side of No. 4 continuing

0930      No visible emission from 1° or 2° hood; fugitives continuing but
          abating somewhat

0937      Tuyere punching; no visible emission from 1° or 2°

0940      Tuyere punching; no visible emission from 1° or 2°

0945      No visible emission from 1° or 2°; fugitives from right side of
          No. 4 have lightened up substantially; draft through aisle now
          from left to right

(continued)
                                H-21

-------
Log Book No.  1                                           No. 4  Converter

0952      No.  4 rolled out;  fume very heavy  for 5  seconds until  tuyeres out
          of  bath; fume penetrated air curtain; 40-60%  OP;  capture  60-70%

0955      No.  4 idling; light visible emission  from mouth;  capture  100%

0959      Slag skim (45 seconds); skimming rate fast; fume  moderate to
          heavy; no spillage; light penetration at right  rear of slot;
          capture 95%; best  skim thus far

          Note:  Ladle held  by crane very close to No.  4

1002      Slag skim (1:45 minutes); skimming rate  moderate; fume moderate
          to  heavy; no spillage; continuous  light  penetration at right rear
          of  air jet;  20% OP; capture 95%

          Note:  Fume  pattern different than previous day;  fume rising
          straight up  rather than impinging  on  right wall as previously;
          Major reason for better capture; capture 95%

1012      Slag skim (partial pot 45 seconds);  skimming  rate moderate; fume
          moderate to  heavy; spillage out at left  front of  hood; fume
          rising and impinging in left wall; 20% OP; capture 90%

          Note:  Placement of ladle close to under converter seems  to help
          reduce emissions;  also, it appears that  air currents  in the aisle
          may be important

          Note:  1020  sunshine; No. 4 idling,  no visible  emission from 1°
          or  2°

1030      No.  4 on idle; no  visible emission from  1° or 2°; maintenance
          crew out apparently repairing source  of  fugitives from right rear
          of  No. 4

1048      Matte charge (20 seconds); fume heavy; spillage out front of
          hood, none;  penetration,light;  20% OP; capturre 95%

1047      Matte charge (20 seconds); fume moderate to heavy; spillage,
          none; penetration  light; 20% OP; capture 95%

          Note:  Matte charges fume heavily  when retracted; also, retracting
          ladle results in turbulence; ladle draws fume out from hood

1051      Ladle on slag shells (10 seconds); fume  light;  spillage,  none;
          penetration  light  upper right rear;  capture >95%
          Note:   Reverts ladle appears smaller and can almost be placed in
          mouth  of converter
(continued)
                                 H-22

-------
Log Book No. 1                                           No.  4 Converter

1055      Ladle of slag shells (20 seconds);  fume light;  no spillage  or
          penetration; capture 100%

          Note:  Much of fume and dust goes  into 1°  hood

1057      Rolled No. 5 back in for slag blow; fume light  to moderate;  no
          spillage or penetration; capture 100%

1138      No.  4 rolled out (10 seconds); fume heavy  to very heavy;  spillage
          some at right front; 20% OP; penetration fairly heavy;  40-60% OP;
          capture 70%

1139      Slag skim; started skimming with ladle on  floor; very heavy  fume
          impinging on right wall; spillage  and penetration of air  jet;
          capture 70-80%; stopped skimming;  restarted with ladle  raised by
          crane; marked difference in both the quantity of fume generated
          and capture effectiveness;  fume heavy; spillage light at  right
          front (OP <20%); penetration light to moderate  (20% OP);  capture
          effectiveness 70-90%

1147      Slag skim (2 minutes 43 seconds);  ladle raised; skim rate moder-
          ate; fume moderate to heavy; spillage, yes; some fume rises  out-
          side of hood; fume impinging on right wall; <20% OP; penetration
          very slight, <20% OP; capture ranged from  80-95%; overall 90%

1149      Slag skim (3 minutes 53 seconds);  skim rate moderate; fume  moder-
          ate to heavy; penetration,  none observed;  spillage intermittent
          for about 1 minute in duration out of right side; 10-20-30%  OP;
          capture ranged from 80-95%; overall 90%

          Note:  Draft in aisle has increased

1206      Matte charge (20 seconds);  fume moderate to heavy;  no spillage or
          penetration observed; capture 100%

1209      Matte charge (15 seconds);  fume moderate to heavy;  spillage,
          none; penetration, wisps; capture  >95%

          Note:  It takes 1 minute for ladle to essentially stop  fuming
          after being withdrawn from hood

1210      No.  4 on hold; curtailment

1600      No.  4 put on slag blow

1605      Silica addition; no visible emission from  1° or 2° hood

(continued)
                                    H-23

-------
Log Book No.  1                                           No.  4  Converter
1622      Slag skim (2 minutes);  pouring rate fast;  ladle on  aisle  floor;
          fume heavy and impinging on left wall;  spillage light,  20%  OP;
          penetration moderate throughout skim,  20%  OP;  capture 80%
          Note:   Operator did not let bath cool  before  pouring  and  ladle on
          ground
1628      No.  4  on idle; moderate fume from mouth; capture 90%; a lot of
          turbulence due to draft
1630      Slag skim (2 minutes 10 seconds); fume  heavy;  pouring rate  fast;
          a lot  of turbulence in  hood; continuous spillage and  penetration
          substantial; 20-40% OP; capture 70%
          Note:   Crane operator has ladle too low and distant from  No.  4
1635      No.  4  placed on idle due to smoke curtailment
1700      No.  4  rolled in for cleanup slag blow
1705      Silica addition; no visible emission from  1°  or 2°  hood
1716      Roll out No. 4; fume very heavy during  roll out; capture  <50%
1718      Slag skim (3 minutes 35 seconds); fume  heavy;  pouring at  moderate
          rate;  spillage moderate to light and intermittent,  30%  of time
          (20% OP); penetration continuous but light (20%); capture ranged
          from 80-90%; overall 85%
          Note:   Ladle well  located this time; also  some delay  before
          pouring
1726      Adding large blocks of  blister Cu; method:  drop in with  chain;
          fume light to moderate  for 5 seconds;  capture 100%
1728      Blister addition;  same  as above
1731      Blister addition;  same  as above
1733      Blister addition;  same  as above
1735      Blister addition;  same  as above
1736      Roll in for finish blow; capture 100%
1823      No.  4  roll out for smoke
(continued)
                                   H-24

-------
Log Book No. 1                                           No.  4  Converter
1827      Charged ladle of Cu spills (15 seconds);  fume  heavy to  very
          heavy; spillage, none; penetation light;  capture 95%
1832      Blister addition; fume heavy;  penetration out  of top; capture  90%
1834      Blister addition; dropped piece of blister;  fume very heavy;
          light penetration/no spillage; capture 95%
1900      No. 4 rolled back in on finish blow
1905      Tuyere punching; no visible emission from 1° or 2°
1931      No. 4 rolled out for smoke; capture >60%
2000      No. 4 rolled back in for finish blow
2033      Ladle of powdered scrap; fume  extremely heavy; some escaping at
          air jet; scrap caught fire; fume completely  engulfed  the  con-
          verter and the 2° hood; capture 80% prior to fire
2035      No. 4 rolled back in for finish blow
2100      No. 4 still  on finish blow
2115      No. 4 roll out; heavy fume for about 5 seconds; penetration
          initially about 40%; overall  capture 60%
2116      Charged powdered scrap; caught fire; fume and  smoke incredible;
          capture undeterminable?
                                 H-25

-------
               LOG KEPT BY

               JAMES  NOLAN
PUGET SOUND AIR POLLUTION CONTROL AGENCY
              P.O.  BOX  9863
           SEATTLE, WA   98125

         PHONE:  (206)  344-7355
                 H-26

-------
                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 18, 1983

0805      Roll in and blow
          Small amount of smoke (<10% OP) out the slot

0815      2 ladles of scrap charged
          Black smoke out the slot (100% OP), smoke out the front of the
          hood ranged from 10-13%.  Scrap on fire in the converter mouth,
          flames almost to the slot in the hood.  (According to John Burckle,
          the limit switch on the primary hood did not trip.  Therefore,
          during the scrap charge the hood was on the hold and blow setting.)
          Switch manually tripped, improved the capture efficiency dramati-
          cally (<10% OP from slot and front).

0835      Hold and blow - no smoke

0900      Hold and blow - no smoke

0907      Roll out (primary back 20-30%; \ minute (~70-80% capture) (maybe
          it took a while for limit switch to kick on); 0% rest of time
          (>90% capture)

0911      Slag skim - small puffs out front under sheet metal (>90%
          capture)

0913      End pour, still rolled out
          Some fume dragged out of front by crane
          Very low smoke out of hood

0915      Blister skim
          Small puffs - 10-20% OP out front under sheet metal (>90%
          capture)

0916      End blister skim
          No visible emissions from hood
          Copper not ready

0921      Charge back to converter
          Small puffs out front

0922      Roll in

(continued)
                                   H-27

-------
Log Book No.  2                                           No.  4  Converter

0923      1°  hood down (converter on idle)

0940      Converter on idle to repair leak  at SCL  plant  - no  smoke

0950      Still  on hold; estimated that repairs will  be  completed at  1100

1030      Still  on hold; blow scheduled for 1040

1046      Roll in (no smoke) hold and blow

1100      Hold and blow (no smoke 1° or 2°)

1109      Roll out - blister skim
          20-30% OP out of top for 10 seconds
          5-10% out of top right during entire skim
          Large ladle on ground
          Capture - >90%
          Thermal seems to bring smoke further into aisle

1112      End skim (>90% capture)
          5-10% OP out the front as the crane pulls out

1115      Blister skim (no smoke visible out front)
          Crane holding small ladle (>90%)

1116      End skim, converter still rolled  out
          No  visible smoke out of hood

1122      Blister skim (crane holding small ladle)
          5-10% out front right below sheet metal
          ~90% capture

1123      End skim
          Some drag out by crane (>90% capture)

1128      Blister skim (crane holding small ladle)
          10-20% out of top right (fairly continuous; one large puff  35%)
          80% capture

1129      End skim

1131      Blister skim
          70% capture
          5-10% OP out slot
          40-50% OP out right front
          Substantial amount of smoke out the front right

(continued)
                                   H-28

-------
Log Book No. 2'                                          No.  4 Converter

Matte Charging

1200      Missed the first charge

1230      Matte charge
          Large volumes of smoke from the charge
          Small 5% OP puffs from front
         . >90% capture

1240      Primary hood partially down - no smoke

1248      Matte charge
          5% OP from front
          >95% capture
          5-10« from top
          Quite a bit of drag out by crane

1249      Hood partially down

1251      Copper slag charge
          Huge volumes of smoke
          80% OP from top of hood
          Seems to be leaking from inspection doors on side;  perhaps from
          behind the primary hood
          Probably 80-90% capture

1258      End

1300      Matte charge
          >90% capture
          5-10% OP from top

1305      Small anode slag
          20-30% OP constant from slot
          Some as high as 80%
          >90% capture
          Huge volumes of smoke
          Some drag out by crane

1308      1° hood partially down
          Fume released into 2° completely captured
          Extremely good shear

1313      Matte charge
          >90% capture - constant 20% from slot
          Few 10-20% puffs from front as ladle was brought in
          Quite a bit of drag out caused by crane

(continued)
                                   H-29

-------
Log Book No.  2                                           No.  4  Converter

1520      Si02 charge complete
          Smoke from back of 2° hood has abated
          Small smoke plume (10-20%)
          3'  x 3"  from top left rear

1524      Still 5-10% OP from left,  top rear of 2°  hood

1525      20-30% OP from left rear of 2° hood
          Continuous emission

1530      Still smoking - 10-20% OP  from left rear  of 2°  hood

1532      Smoke has subsided

1544      Pull out and slag skim
          Large volumes of smoke (100% OP for a minute)
          50-70% capture; most of smoke leaking from front  of 2°  hood,
          thermal  blast is too much  for hood

1547      Skimmed  too much, slag poured over pot
          90% capture
          Much lower smoke volumes

1552.5    Slag skim (1 minute)
          90% capture
          60-80% OP from front right part of 2° hood
          Thermal  blast breaks through hood

1554      After skim is complete the 2° hood settles down and performs
          properly; converter is up, 1° hood up, no visible smoke from  2°
          hood

1558      Slag skim (2 minutes)
          50-70% capture
          80% OP out front of hood
          Large volumes of smoke coming out below the converter mouth

          Slag return hood on reverb not operating

(continued)
                                   H-30

-------
Log Book No. 2                                           No. 4 Converter

1355      Inspected rear of converter to  find  leak.  A welded plate on the
          balloon flue had come loose and was  the  source  of  the emission.
          No repair anticipated at this time

1408      Roll out
          10 seconds, 40% OP puff through slot (70%  capture)
          >90% after air is off

1410      Scrap charge (1 minute)
          Shook scrap around to release from  ladle,  heavy smoke and flame
          >90% capture, some puffs through slot

1411      Roll in and blow
          Pour copper and hold for tomorrow a.m.

          The hood looked much better today.   It seems the crane operator
          has a lot to do with how much smoke  is generated.  The operators
          who are slower and more deliberate  improve the  hood's per-
          formance.
                                H-31

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                          TEST ON SECONDARY  HOOD
                              NO. 4 CONVERTER

                             January 20,  1983

0700      On hold

0823      Matte charge (H minutes)
          Puff from top 10% of face (40-60%  OP)
          Fairly constant, 50% OP from slot
          80% capture overall  (lots of crane drag  out)
          Unusually smokey charge
          Gas is on too, creating more heat

0826      Charge complete
          >95% capture
          Gas still on, some smoke from converter  mouth  captured  by  2°

0840      Matte charge (25 seconds)
          Much better
          Almost no smoke from face (some drag out by crane)
          10-20% OP puff from slot
          >90% capture

0841      >90% capture
          Gas still on, converter mouth open

0854      Matte charge (15 seconds)
          >90% capture
          Very little smoke from face except crane drag  out;  could  not  see
          slot from right hand side

0855      >95% capture
          Gas still on

          What is face velocity of exhaust vs. air jet?
          Looks like it might eliminate eddys if velocities were  matched
          better

0910      Matte charge (15 seconds)
          10-20% OP from slot
          No visible smoke from face except  crane  drag out
          >90% capture
          Crane movement really disturbs  air flow  for 10-15  seconds, small
          puffs leak out slot in top of 2° hood

(continued)
                                 H-32

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Log Book No. 2                                           No.  4  Converter

1607      Matte charge (15 seconds)
          >95% capture
          No visible smoke from hood
          Crane drag out moderate

1613      Roll in

1636      No visible emissions from  1°  or 2°

1645      No visible emissions from  1°  or 2°

1653      Roll out and skim (H minutes)  (jet off)
          50% capture
          Large amount of fume through  front  of hood

1656      Slag skim (li minutes)
          40% OP through slot (fairly continuous)
          Puffs of 60-80% from 20% of face area
          80/c capture (pretty good considering air  jet  is off)

          Draft on slag spoon hood needs  to be increased

1702      Slag skim (3i minutes)
          80-90% capture
          Hood has problems when the wind kicks up  or when the  operator
          pours too fast
          Plume going up the right inside of  hood
          Some of plume exits hood and  is drawn in  again
          20% OP through slot
          40% OP out 50% of face (most  is drawn back  in near  top)
          Air jet fan still of

1730      Roll in and blow (finish)

1758      Complete cleanup blow
          Roll out
          Emissions heavy and substantial amount escapes  air  curtain
          "50-60% capture for a "45  second
          Blowing air turned off; substantial  emissions continue for
          "60-90 seconds and then moderate somewhat

1800      Emissions escaping capture; "20% OP and overall capture
          "75%

1803      Pouring stops.  Fume inside hood "20% OP; capture eff. now
          about 95%; hood open awaiting charge

(continued)
                                   H-33

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Log Book No. 2                                           No.  4 Converter
1810-     Charge blister block - very little smoke; essentially all
1815      captured
1817      Roll back into 1° hood; small  amount of smoke escapes at top
          due to blowing air
1830-     Curtailed due to weather (on-hold)
1915
1915      Resume blowing - roll  in very  clean as compared to roll  out;
          essentially 99% capture
2000      Curtail - roll out and put on  hold
                                  H-34

-------
                          TEST ON SECONDARY HOOD
                              NO. 4 CONVERTER

                             January 22, 1983

0905      Shell charge (20 seconds)
          >90% capture
          One small puff of 60% OP from right front face
          50% OP puffs through slot

0908      Shell charge (30 seconds)
          Low smoke
          100% capture

0910      Roll in and blow
          >90% capture
          Large leak from back of converter (lower right)

0920      Leak continues
          No smoke from 1° or 2°

0934      Leak has lessened quite a bit
          Seems to be from end plate of the converter

0950      Roll out
          90% capture

0954      Slag skim (50 seconds) (ladle up)
          >90% capture
          Small 40% OP puffs from right front of hood drawn back into
          hood

          The combination of waiting a bit after the roll  out and holding
          the ladle off the floor really seems to help;  2° hood performed
          best I have seen on a slag skim

0959      Slag skim (1 minute 45 seconds) (ladle up)
          >90% capture
          No fume visible out 2° hood front
          Seems to be some leakage through slot

1005      Slag skim (2 minutes 45 seconds) (ladle up)
          >90% capture
          Slight puffs through slot (10-20% OP)
          If smoke gets in between the air jet and the front left plate it
          tends to float out of the hood rather than entering the exhaust

(continued)
                                  H-35

-------
Log Book No.  2                                           No.  4  Converter

1153      Slag skim (4 minutes)  (ladle up)
          >90% capture
          Some 40% OP puffs out  front
          Ladle should be a bit  higher and  closer to  the  converter;  looks
          like it is 2 feet off  the ground  and  a  foot away  from the  con-
          verter

1204      Matte charge (15 seconds)
          Crane held in a bit; moderate drag  out
          >90?0 capture
          No  visible from 2° during charge
          Crane needs to hold a  bit longer

1208      Matte charge (20 seconds)
          >90% capture
          No  visible from 2° during charge
          Moderate drag out, crane needs to hold  longer (maybe  20-30
          seconds)

1210      Gas on; converter on  idle; curtailment
                                   H-36

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            APPENDIX I

INTERLABORATORY COMPARISON STUDY OF
     PROPOSED EPA METHOD 108
                1-1

-------
                INTERLABORATORY COMPARISON STUDY






     An interlaboratory comparison study was conducted as a



preliminary check on the analysis procedure used in U.S. EPA




Method 108 because a previous study indicated that the atomic




absorption (AA) method used in Method 108 gave lower results (by



a factor of two) than the colorimetric method routinely used by



ASARCO.  During the current test program, seven filter samples




and a dust sample from the roaster baghouse were collected




strictly for analytical comparison.



     PEDCo digested the one inlet filter, six outlet filters, and




four separate portions of the dust sample according to Method



108.  Portions of these samples, the reagent blanks, and the



undigested dust were sent to ASARCO for analysis.  ASARCO ana-



lyzed these samples using their colorimetric method and atomic



absorption; both flame and furnace techniques were used.  Table I



contains the results of the ASARCO analysis of the solutions



extracted by PEDCo.



     ASARCO also digested and analyzed duplicate portions of the




dust sample using different acid matrices.  The results of these



analyses are compared with the results ASARCO obtained for the



dust samples digested by PEDCo in Table II.  The results compare



very well; neither the digestion matrix nor the analytical method



seem to affect the analysis of these samples.





                               1-2

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            TABLE  I.   ASARCO'S RESULTS  FOR INTERLABORATORY SAMPLES
                                                    Arsenic,
   Sample Description

   agent Blank Ml 08
 Reagent Blank M108  Bomb
 CT501 M108
 CT501 M108 Bomb
 CT502 Ml08
 CT502 M10B Bomb
 CT503 M108
 CT503 M108 Bomb
 CT504 M108
 CT504 M108 Bomb
 CT505 K108
 CT505 Ml08 Bor.b
 CT506 M108
 CT506 M108 Bomb
 CT507 M108
 CT507 Ml08 Bomb
 CT508 M108
 CT50B M108 Bomb
 CT509 M108
 CT509 M108 Bomb
 CT510 M108
 CT510 M108 Bomb
 C7511A M108
 CT511A M108 Bomb
 CT511B M108
 CT511E Ml 08 Bomb
.£T511C M108
 CT511C M108 Bomb
 CT511D M108
 CT511D M108 Bomb
1983
ASARCO
Lab No.
475
476
477
478
479
480
481
482
483
484
485
486
487
488
489
490
491
492
493
494
495
496
497
498
499
500
501
502
503
504

Colormetric
HNO^/HClOi
11.2
.22
.19
.24
1.1
.09
1.3
1.5
1153.
3.6
24.5
.68
19.2
.33
14.9
.31
63.0
1.0
46.3
.58
37.0
.78
268.
2.8
268.
5.0
245.
2.3
275.
4.3
Flame
AA
HaOH/HNCh
12.1
<3.
<3.
<3.
<3.
<3.
<3.
<3.
1238.
3.5
27.
<3.
20.
<3 .
17.
<3.
71.
3.
53.
<3.
35.
<3.
261.
3.
272.
5.4
259.
<3.
270.
5.2

Graphite
HaOH/HNO^
9.75

.22

1.08

1.42

1269.

24.8

18.6

15.6

65.0

45.3

34.8

243.

260.

257.

280.


Furnace
HNO^/HCIO
9.7
.52
.42
.70
1.25
-
.30
1.05
1146.
2.25
22.5
.92
17.5
.90
14.7
.63
62.2
1.27
48.1
.83
35.9
.90
275.
2.51
254.
4.43
229.
2.14
229.
3.97
                                     1-3

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    TABLE II.   ASARCO'S  COMPARISON  OF VARIOUS  DIGESTION  MATRICES
Sample
Descrip-
tion
CT511 Bulk
CT511A
CT511B
CT511C
CT511D
                505
              497 t 498
              499 t  500
              501 t  502
503 t 504
                                               Arsenic,
                                               Percent
                                Ooloraetric
               *aOH/HH03/    HHOj/HCl
               •C1CU         BT/HClOd
12.5




13.2



13.4


12.3



13.5
MOH/HHOj



  12.7*




  13.0



  13.6



  12.9



  13.3
                                        HM03/HC1
                                                                       12.6
       •  Average of two replicates
                                 1-4

-------
     PEDCo analyzed the split samples using atomic absorption;



both flame and furnace techniques were employed.  The results are



contained in Tables III and IV, respectively.  A good correlation



was found between the different laboratories, different methods,



and different digestion procedures.  For example, a 16 percent



difference was found between PEDCo's and ASARCO's analyses by



flame AA based on the average value of the dust sample and a 15



percent difference was found in the inlet filter sample.



     Based on the results of this interlaboratory study, approval



was given for the digestion and analysis of the Method 108 sam-



ples obtained during the current test program.  These samples



were digested by PEDCo and split with ASARCO.  Table V lists the



results of the flame AA analyses.  The ASARCO data listed in this



table are preliminary results obtained by telephone.  ASARCO is



currently verifying their results.
                              1-5

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TABLE III.   PEDCo'S ARSENIC CONCENTRATIONS
           FLAME ATOMIC ABSORPTION
Sample No.
CT501
CT502
CT503
CT504
CT505
CT506
CT507
CT508
CT509
CT510
CT511A
CT511B
CT511C
CT511D
Reagent blank
Volume each
extract, ml
50
50
50
250
50
50
50
50
50
50
250
250
250
250
50
Net
weight, mg
0.3
0.9
0.8
721.4
3.4
1.7
3.7
8.2
9.6
7.7
508.8
508.5
501.6
515.9
-
NaOH
extract,
-
-
-
1470
-
-
-
-
-
-
325
335
314
320
13.6
mg/1
1.0
2.3
1.5
1400
29.1
21.6
17.6
71.8
53.9
43.4
301
313
287
311
11.5
HF/HNO.
mg/1 J
3.92
2.93
2.93
4.16 4.72
6.50
6.10
5.31
5.11
3.13
5.31
4.36 3.53
4.75 7.10
3.77 4.12
4.16 5.51
3.77 4.52
                    1-6

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TABLE IV.   PEDCo'S ARSENIC CONCENTRATIONS
    GRAPHITE FURNACE ATOMIC ABSORPTION
Volume each
Sample No. extract, ml
CT501
CT502
CT503
CT504
CT505
CT506
CT507
CT508
CT509
CT510
CT511A
CT511B
CT511C
CT511D
Reagent blank
50
50
50
250
50
50
50
50
50
50
250
250
250
250
50
Net
weight, mg
0.3
0.9
0.8
721.4
3.4
1.7
3.7
8.2
9.6
7.7
508.8
508.5
501.6
515.9
-
NaOH
extract, mg/1
1.09
1.64
2.23
-
28.8
22.9
17.8
-
-
-
305.6
268.5
265.7
281.4
12.6
0.29
1.22
1.58
1410
-
-
-
69.6
48.4
41.3
265.0
287.6
239.6
278.4
-
HF/HNO,
mg/1 J
0.23
0.26
0.10
2.64
0.59
0.36
0.36
0.82
0.50
0.52
1.94
3.84
1.61
3.07
<0.23
0.20
0.15
0.13
2.66
0.67
0.36
0.32
1.11
0.76
0.95
2.59
4.84
2.17
3.77
0.26
                  1-7

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                   TABLE V.  COMPARISON OF METHOD 108 RESULTS
Sample No.

CT442/449
CT443/450
CT444/451
CT445/452
CT446/453
CT447/454
CT448/430

CT461
CT462
CT463
CT464
CT465
CT466
CT479

CT467
CT468
CT469
CT470
CT471
CT472
CT480

Reagent Blank
Reagent Blank
ASARCO,
nig/liter

  50
  51
 12.1
  82
  82
  34
  <2

   2
  <2
   3
   2
   2
  <2
  <2

  8.1
  24
  <2
  9.6
  114
  9.8
  <2

  <2
  <2
 PEDCo,
mg/IJter

   65
   66
  19.1
   93
   96
   44
   4.5

   5.6
   3.9
  <3.4
   5.4
   3.9
  <3.4
  <3.4

  11.9
   36
  <3.4
  12.7
  134
  13.2
  <3.4

  <3.4
  <3.4
  Type
of sample

 Filter
 Filter
 Filter
 Filter
 Filter
 Filter
 Filter (blank)

 Probe rinse
 Probe rinse
 Probe rinse
 Probe rinse
 Probe rinse
 Probe rinse
 Probe rinse (blank)

 Impinger
 Impinger
 Impinger
 Impinger
 Impinger
 Impinger
 Impinger (blank)
                                    1-8

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