EPA-600/4-77-018
April 1977
Environmental Monitoring Series
REGIONAL AIR POLLUTION STUDY
Non-Criteria Pollutant
Inventory
Environmental Sciences Research Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
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RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development. U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the ENVIRONMENTAL MONITORING series.
This series describes research conducted to develop new or improved methods
and instrumentation for the identification and quantification of environmental
pollutants at the lowest conceivably significant concentrations. It also includes
studies to determine the ambient concentrations of pollutants in the environment
and/or the variance of pollutants as a function of time or meteorological factors.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
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EPA-600/4-77-017
April 1977
REGIONAL AIR POLLUTION STUDY
Non-Criteria Pollutant Inventory
by
Fred E. Littman
Harry W. Wang
John Piere
Air Monitoring Center
Rockwell International
11640 Administration Drive
Creve Coeur, MO 63141
Contract No. 68-02-1081
Task Order 54
Project Officer
Francis A. Schiermeier
Regional Air Pollution Study
Environmental Sciences Research Laboratory
11640 Administration Drive
Creve Coeur, MO 63141
ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
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DISCLAIMER
This report has been reviewed by the Environmental Sciences Research
Laboratory, U.S. Environmental Protection Agency, and approved for publication.
Approval does not signify that the contents necessarily reflect the views and
policies of the U.S. Environmental Protection Agency, nor does mention of
trade names or commercial products constitute endorsement or recommendations
for use.
ii
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ABSTRACT
In conjunction with the Regional Air Pollution Study (RAPS) being
conducted in the St. Louis Air Quality Control Region (AQCR), an inventory
of non-criteria pollutants was assembled for point sources. The inventory
was based on the following data:
1. The National Emissions Data System (NEDS) inventory for the AQCR.
This inventory is based largely on 1971 and 1972 data.
2. Emission factors listed in the several reports in the series entitled
"National Inventory of Sources and Emissions," which list estimated
emission factors for the following 21 compounds: Arsenic, Abbestos,
Barium, Beryllium, Boron, Cadmium, Chromium, Copper, Lead, Magnesium,
Manganese, Mercury, Molybdenum, Nickel, Phosphorus, Selenium, Silver,
Titanium, Vanadium, Zinc, and BaP.
The non-criteria emission factors are being incorporated into the RAPS
Data Handling System, and yearly point source inventories for non-criteria
pollutants are available.
iii
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CONTENTS
Abstract HI
Figures vl
Tables Yt
1.0 Introduction 1
2.0 Scope of the Non-criteria Inventory 2
3.0 Approach and Methodology 3
4.0 Data Handling 8
5.0 Representative Emission Inventories 10
6.0 Summary and Conclusions . 13
References 14
Appendices 15
I. Point Sources (By SCC Codes) and Associated
Sets of Pollutants 15
II. Emissions (In Lbs.) per Designated Unit for
Each Source Type 19
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FIGURES
Number Page
1 Example of Codint Sheet 9
TABLES
Number Page
1 National Emissions Data System (NEDS) Source
Classification Code (SCC) Report 4
2 Emission Factors , 5
3 ' National-'Emission Data System Point Source Listing 7
4 Emission Inventory for Selected Compounds for AQCR 70 11
v1
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1.0 INTRODUCTION
The "Clean Air" Act of 1970, as amended, establishes the achievement of
clean air as a national goal. In pursuance of this goal, Air Quality Criteria
were developed and Air Quality Standards established for five pollutants:
sulfur dioxide, carbon monoxide, particulate materials, hydrocarbons and oxidants.
These pollutants are frequently termed "criteria pollutants".
It is well known, however, that a large number of other substances occur
in polluted air, some of which have known toxic or carcenogenic properties, such
as mercury, asbestos or beryllium. The Clean Air Act requires the Administrator
to consider other pollutants and to determine whether they are hazardous. Such
a determination is conditioned on the magnitude of the health and welfare effect;
it, in turn, is a function of the occurrence of the pollutant as well as its
intrinsic toxicity.
Thus, one input into these considerations is an assessment of the sources
of such pollutants, as well as the pollution burden they create. For this reason,
a series of studies has been performed for the Environmental Protection Agency,
which were issued under the general heading of "National Inventory of Sources
and Emissions". C1) In this series, some 21 compounds were examined, and
emission factors and emission inventories were developed. Though no high degree
of accuracy is claimed for these factors, they can serve as a useful basis for
first approximations of the emissions in a given area.
In conjunction with the Regional Air Pollution Study (RAPS) being conducted
currently in the St. Louis Air Quality Control Region (AQCR), an inventory of
these "non-criteria" pollutants was assembled.
See page 14 for reference
-1-
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2.0 SCOPE OF THE NON-CRITERIA INVENTORY
The non-criteria inventory is based on the following data:
The National Emissions Data System (NEDS) inventory for the AQCR 70
(St. Louis). This inventory lists some 1300 individual sources. It
is based largely on 1971 and 1972 data.
Emission factors listed in the several reports in the series entitled
"National Inventory of Sources and Emissions", which lists estimated
emission factors for all sources of the 21 compounds discussed. There
is a considerable degree of uncertainty in the values of the emission
factors, and this uncertainty is reflected in the values reported in
this inventory.
• • -• - :••.(!„• A •' • ..*-.-.
The following pollutants are included:
Arsenic Mercury
Asbestos Molybdenum
Barium Nickel
Beryllium Phosphorus
Boron Selenium
Cadmium Silver
Chromium Titanium
Copper Vanadium
Lead Zinc
Magnesium Bap
Manganese
-2-
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3.0 APPROACH AND METHODOLOGY
The starting point for this stady was the emission factors listed in
the 21 publications referred to above. These factors are the best available
estimates relating the uses of these materials, from mining to processing
and ultimate consumption or disposal, with their release to the atmosphere.
A discussion of the estimated accuracy of these factors is contained in each
of the reports.
Each emission factor delineated in the reports was assigned one or sev-
eral Source Classification Codes (SCC).* The SCC is an identification system
developed for NEDS, upon which the point source hierarchy is structured. Any
plant or process which causes air pollution can be represented by one or sev-
eral SCC numbers. Table 1 shows a typical sample of SCC numbers. The SCC num-
bers consist of four groupings. For example:
Group I - a single digit (3) - designates "industrial processes"
Group II - two digits (03) - designates "primary metals"
Group III - three digits (014) - designates "barium"
Group IV - two digits (03) - designates "driers/calciners"
In addition the base unit upon which the emission factors are based is given;
in this case, "tons processed".
Table 2 shows an example of a table of emission factors (for lead) taken
from APTD 1543 "Emission Study of Industrial Sources of Lead Air Pollutants",
with the appropriate SCC codes added. It indicates, for example, that in the
Primary Lead Production, which in NEDS is coded 3-03-010-01 through 3-03-010-
05, an emission of 5 Ibs.of lead per ton of product occurs. Adding the SCC
codes to the information in the "Emission Study" made it possible to determine
which of these sources actually exist in the St. Louis AQCR.
A listing of emission sources for the St. Louis AQCR ordered by SCC codes,
was then obtained from.NEDS, and a cross-tabulation prepared, which assigned
to each source category in the region a set of emission factors. These sets
are shown in Appendix I. The emission factors were then transformed to cor-
respond with the production or consumption units which appear in the NEDS
t2) See page 14 for reference
-3-
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TABLE 1
NATIONAL EMISSIONS DATA SYSTEM (NEDS)
SOURCE CLASSIFICATION CODE (SCC) REPORT
I
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
?
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
SCC
II
03
03
03
03
03
03
03
03
03
03
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
0«
04
04
04
04
04
04
0.
ID
III
014
014
030
030
030
030
030
030
030
999
001
001
001
001
001
001
001
001
001
0-02
002
002
002
002
002
002
003
003
001
003
003
003
003
004
004
004
004
004
00-
005
005
006
00»>»EN MtARTM FNC ITONS
IQfEN MfAUTH LANCDITQNb
MtAT-T-EAT FNC I TONS
(INDUCTION FURNACE I TONS
IOTH1R/MOT CLASIFDlTONs
IHf TORT FNC I 'ONs
i-GE
"GE
»GE
UNITS
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PRODUCED
PRODUCED
MET«L PRODUCED
MEUL PRODUCED
METiL PRODUCED
PRODUCT
PROOUCEO
PRODUCED
PRODUCED
PRODUCED
CM
CM
CM
CM
CH
CM "GE
PRODUCED
METAL CHANGE
METAL CMAWGE
MET.L CHA»r,E
METAL CHARGE
PROCESSED
PROCESSED
METAL CHARGE
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PMUCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
^ROCESStD
PROCESSED
PROCESSED
PROCESSED
PROCESSED
PROCESSED
-4-
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TABLE 2
en
Source
Mining & Milling
Metallurgical Industries
Primary Lead Production
Primary Copper Production
Primary Zinc Production
Secondary Lead Production
Lead Oxide Processing
Consumer Product Manufacturing
Storage Batteries
Storage Batteries
Gasoline Additives
Solder
Cable Covering
Type Metal
Brass & Bronze
EMISSION FACTORS
Factor
0.2 Ib/ton lead mined(controlled)
3-03-010-99
5.0 Ib/ton of product(controlled)
3-03-010-01 3-03-010-03 3-03-010-05
3-03-010-02 3-03-010-04
0.6 Ib/ton of Cu concentrates(controlled)
3-03-005-02 3-03-005-04
3-03-005-03
0.3 Ib/ton of In concentrates(controlled)
3-03-030-02 3-03-030-04 3-03-030-06
3-03-030-03 3-03-030-05
0.7 Ib/ton of product(controlled)
3-04-004-01 3-04-004-03 3-04-005-01
3-04-004-02 3-04-004-04
0.7 Ib/ton of lead oxide(controlled)
3-04-004-08
3-04-005-01
8.0 Ib/ton of lead processed(uncontrolled)
1.3 Ib/ton of lead processed(controlled)
3-04-005-01
14.0 Ib/ton of lead processed(controlled)
2-02-003-01 2-03-999-98
3.0 Ib/ton of lead processed(controlled)
3-04-999-99
2.0 Ib/ton of lead processed(controlled)
3-04-999-99
17.0 Ib/ton of lead processed(controlled)
3-04-999-99
4.0 Ib/ton of lead processed(controlled)
3-04-002-02 3-04-002-06 3-04-002-05
Qualifier
Plant visit
Questionnaires
Estimate
Estimate
Questionnaires
Questionnaires
Questionnaires
Questionnaires
Questionnaires
Estimate
Questionnaires
Questionnaires
Questionnaires
-------
printout, as, for example, the source shown in Table 3 which shows the
"Annual Operating Rate" in the lower right hand corner. The final cor-
relation is listed on the tables shown in Appendix II.
-6-
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FILE CREATED ON THURSDAY
STATEfjui: ILLINOIS
f? IflDI ! MONROE CO
TABLE 3
JUNE 17. I97S
N A • T i o M A, L EMISSION OAT*,- SYSTEM _
POINT SOU«cE L I S T I A/ G
&QCDi07ri: METROPOLITAN ST. iouis CITYIOOOOI: MISSIWS NA-E
10: oooi POIVT to: oj • . -
PAGE 603
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PERSONAL CONTACT: SCCO-OS-DZO-OI i: INDUSTRIAL PROCES -MINERAL PRODUCTS -STONE (JDARY/PROC -PRI«APY CRUSHING
UTM
>'! I 9 7 2
! PRIVATE
! STACK
CALCULAT^P EMISSION E«;TIM4TES
• •••••••••••••••«*•*•••••••••••••••
» .PARTICULATE: 23
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MOPI70HTAI.: 735.3
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4.0 DATA HANDLING
In order to include the information thus obtained in the RAPS data
base, it was transferred to RAPS coding sheets and from there to a set of
punched cards. A typical coding sheet is shown in Figure 1.
For the system to be compatible with the handling procedures developed
for other facets of RAPS, the following information has to be entered for
each source:
Card 1
State Code
County Code
Plant ID
Plant Name
Street Address
Zip Code
SIC
Ownership Code
Card 2
Stack ID
UTM Zone
UTM Coordinates
Area ID
Temperature
Stack Height
Boiler Design Capacity
Stack Diameter
Flow Rate
Card 3
Control Equipment and Efficiency
for all Criteria Pollutants
Card 4
Point ID
Fuel Heat Content
Sulfur
Ash
Estimation Method
Pollutant
Units
-8-
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STATE COUNTY
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1 1 1
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L=Local
S=State
F=Federal
U=Uti li ty
PLANT
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1 1 1
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1 1 1
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ID
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1 1 1
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EMISSION FACTOR
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TANT UNITS Tl(2) START DATE(3) START STOP DATE (}) STOP THERMAL
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(1) Tons, I03gal, lOcu.ft. 2. Material balance
.... . . ). Emission factor (AP-W)
(2) Time Interval (A,M,W,D,S ,H) J G(jess
,3) Year. Julian Date (YYDDD) |j ^^^^ '«""
7- Faci 1 i ty closed
8. Calculated mass emissions
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2. Emission data
3. Annual pattern
I). Non-criteria pollutants
5. Heat emissions
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-------
Card 4 (Continued)
Time Increment
Start Date
Start Hour
Stop Date
Stop Hour
SCC Number
Card 5
Annual Operating Rate
An emission factor file, consisting of the 19 sets of factors for the
non-criteria pollutants as shown in Appendix II, is also input into the sys-
tem. This file is keyed to SCC numbers. When requested by the output pro-
gram, the computer will calculate the emissions for any pollutant for a giv-
erv source by multiplying its annual operating rate by the appropriate fac-
tor. It can also provide the total amount of any one pollutant by area code,
county, state and AQCR. A set of punched cards representing the emission
sources and the emission factor file is submitted with this report. Retrieval
procedures will be described in the forthcoming RAPS Data Handling Users
Manual (EPA )*
*Document number to be assigned.
-10-
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5.0 REPRESENTATIVE EMISSION INVENTORIES
Emission inventories for five compounds were hand-calculated. The
results are shown in Table 4.
-11-
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TABLE 4
Emission Inventory for Selected Compounds for AQCR 70
(Based on 1972 NEDS Data)
Compound Emissions
(Ibs/year)
Arsenic 166,400
Cadmium 270,400
Lead 3,234,800
Mercury 5,600
Benz(a)pyrene 12,600
-------
6.0 SUMMARY AND CONCLUSIONS
An emission inventory of 21 "non-criteria" pollutants for the St. Louis
AQCR has been assembled and formatted for inclusion in the RAPS data base.
The inventory covers some 1300 sources. Information on the contribution
of each source, the sources of any one pollutant, and the total amount of any
pollutant in a given grid square, county, state and AQCR can be obtained from
the memory bank of the Univac computer at EPA-Research Triangle Park.
-13-
-------
7.0 REFERENCES
(1) National Inventory of Sources and Emissions
Arsenic APTD-1507
Asbestos APTD-70
Barium APTD-1140
Beryllium APTD-1508
Boron APTD-1159
Cadmium APTD-68
Chromium EPA-450/3-74-012
Copper APTD-1129
Emission Study"1
of Industrial ^ APTD-1
Sources of 7 Anu l
Lead Air
Pollutants
Magnesium EPA-450/3-74-010 ,.
Manganese APTD-1509
Mercury APTD-1510
Molybdenum EPA-450/3-74-009
Nickel APTD-69
Phosphorus EPA-450/3-74-013
Selenium APTD-1130
Silver EPA-450/3-74-011
Titanium EPA-450/3-74-008
Vanadium APTD-1511
Zinc APTD-1139
Preferred Standards Path Report for Polycylic
Organic Matter October 1974
Emission Factors for Trace
Substances EPA-450/2-73-001
(2) NEDS Source Classification Codes and Emission Factor Listings
EPA-Office of Air Quality Planning and Standards
Research Triangle Park, July 1974
£uide for Compiling a Comprehensive Emission Inventory
EPA-APTD-1135 (1973)
Compilation of Air Pollutant Emission Factors
£PA-AP42, Appendix C
,-14-
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APPENDIX I
POINT SOURCES (BY SCC CODES)
AND ASSOCIATED SETS OF POLLUTANTS
-15-
-------
SCC CODE
1 -01 -001 -02
1-01-002-01
1-01-002-02
1-01-002-03
1-01-002-08
1-01-004-01
1-01-005-01
1-01-005-02
1-01-005-03
1-02-002-01
1-02-002-02
1-02-002-04
1-02-002-08
1-02-002-09
1-02-002-11
1-02-002-12
1-02-002-13
1-02-004-01
1-02-004-02
1-02-004-03
1-02-005-01
1-02-005-02
1-02-005-03
SET
01
01
01
01
01
02
03
03
03
01
01
01
01
01
01
01
01
02
02
03
03
03
03
COAL (ANTHRACITE)
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
RESIDUAL OIL
DISTILLATE OIL
DISTILLATE OIL
DISTILLATE OIL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
BITUMINOUS COAL
RESIDUAL OIL
RESIDUAL OIL
RESIDUAL OIL
DISTILLATE OIL
DISTILLATE OIL
DISTILLATE OIL
-16-
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SCC CODE
1-02-009-02
1-02-009-03
1-03-002-09
1-03-002-13
1-03-004-01
1-03-004-02
1-03-004-03
1-03-005-02
1-03-005-03
2-01-001-01
2-01-003-01
3-01-014-01
3-01-014-02
3-01-018-99
3-03-003-01
3-03-003-02
3-03-003-03
3-03-003-04
3-03-003-99
3-03-005-99
3-03-008-01
3-03-008-03
3-03-009-03
3-03-009-05
3-03-t)10-01
SET
04
04
01
01
02
02
02
03
03
03
05
06
06
07
08
08
08
08
08
09
10
11
12
13
14
WOOD/BARK WASTE
WOOD/ BARK WASTE
BITUMINOUS COAL
BITUMINOUS COAL
RESIDUAL OIL
RESIDUAL OIL
RESIDUAL OIL
DISTILLATE
DISTILLATE
DISTILLATE OIL
DIESEL
PAINT MFG.
PAINT MFG.
PLASTICS
COKE MET. BYPRODUCT
COKE MET. BYPRODUCT
COKE MET. BYPRODUCT
COKE MET. BYPRODUCT
COKE MET. BYPRODUCT
COPPER SMELTING
IRON PRODUCTION
IRON PROD. SINTER
STEEL PROD. :BOF
STEEL PROD. :ELEC. ARC
LEAD SMELTERS
-17-
-------
SCC CODE
3-04-002-02
3-04-003-01
3-04-003-03
3-04-003-30
3-04-004-03
3-05-006-03
3-05-006-99
3-05-007-01
3-05-007-02
3-05-013-01
3-05-014-01
3-06-002-01
3-90-002-01
3-90-004-01
3-90-004-99
3-90-005-01
3-90-005-05
3-90-005-99
4-02-001-01
4-02-999-99
5-01-001-01
5-01-001-02
5-02-001-02
5-03-001 -01
5-03-001 -02
5-03-001-05
'SET
15
16
16
16
17
18
18
18
18
1.9
20 ,
21
01
02
02
03
03
03
22
23
24
24
24
24
24
24
BRASS/BRONZE MELT
GRAY IRON
GRAY IRON
GRAY IRON
LEAD SMELT SEC
CEMENT: KILN: OIL-FIRED
CEMENT: OTHER/NOT CLASSIFIED
CEMENT MFG. WET
CEMENT MFG. WET
FRIT MFG.
GLASS MFG. J
GEN. FLUID CRACKER
BITUMINOUS COAL (CEMENT KILN/DRYER)
RESIDUAL OIL (ASPHALT DRYER)
RESIDUAL OIL (OTHER/NOT CLASSIFIED)
DISTILLATE OIL (ASPHALT DRYER)
DISTILLATE OIL (METAL MELTING)
DISTILLATE OIL (OTHER/NOT CLASSIFIED]
PAINT
OTHER/NOT CLASSIFIED
INCINERATOR (MUNICIPAL)
INCINERATOR (MUNICIPAL)
GENERAL INCINERATOR
INCINERATOR
INCINERATOR
INCINERATOR
-18-
-------
APPENDIX II
EMISSIONS ( IN IBS. ) PER
DESIGNATED UNIT FOR EACH SOURCE TYPE
-19-
-------
COAL
SET
01
01
01
01
01
01
01
*
01
01
01
01
01
01
01
01
01
01
01
01
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.0029
.015
. 00058
.018
.0039
.004
.0022
.105
.0077
.001
.0015
.0026
.051
.0025
.001
.018
.0069
.017
. 000007
UNITS: PER
TON COAL BURNED
«f
*
-------
RESIDUAL OIL
SET
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP _..
(Pounds)
QUANT.
.0007
.010
.0038
.9524
.012
.0004
.008
.4048
.072
.0050
.004
.0044
1.2143
.0333
.000033
UNITS: PER
1000 GAL OIL BURNED
v
-21-
-------
DISTILLATE OIL
SET
03
03
03
03
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.0024
.00051
. 11 90
UNITS: PER
1000 GAL OIL BURNED
-22-
-------
WOOD BOILER
SET
04
04
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.0019
UNITS: PER
TON
-------
DIESEL
SET
05
05
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.000136
UNITS: PER
w'i *
•
1000 GAL
-24-
-------
PLASTICS
SET
07
07
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.0006
UNITS: PER
TON
-25-
-------
COKE
SET
08
08
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
Tt
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.0055
UNITS: PER
TON COKE PRODUCED
-26-
-------
IRON PROD.
SET
10
10
10
10
10
10
10
10
10
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.015
.022
.019
.0225
.0015
.052
.0001
.0014
.020
UNITS: PER
TON IRON PRODUCED
TON PIG IRON
TON PIG IRON
TON PIG IRON
TON IRON
TON IRON
TON PIG IRON
TON PIG IRON
TON PIG IRON
-27-
-------
IRON PROD. SINTER
SET
11
* -
11
11
11
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.06
.052
.0002
UNITS: PER
w -
TON SINTER
1
-28-
-------
STEEL PROD. (BASIC OXYGEN FURNACE)
SET
12
12
12
12
12
12
12
12
12
12
12
12
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.015
.002
.180
.002
.044
.068
.0015
.0087
.0004
.0003
.067
UNITS: PER
TON STEEL PRODUCED
*
-29-
-------
STEEL PRODUCTION ELEC ARC
SET
13
13
13
13
13
13
13
13
13
13
13
13
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.015
.007
.036
.10
.078
.0025
.0015
.0087
.0011
.0004
.74
UNITS: PER
TON STEEL PRODUCED
i
i
-30-
-------
LEAD SMELTERS
SET
14
14
14
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.8
.3275
5
UNITS: PER
TON LEAD
TON
TON LEAD
-31-
-------
BRASS/BRONZE MELT
SET
15
15
15
15
15
15
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.30
.20
.40
.02
.50
UNITS: PER
TON
i
'
-32-
-------
GRAY IRON
SET
16
16
16
16
16
16
16
16
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.011
.005
.00022
.005
.003
.33
.000018
.00072
.00017
UNITS: PER
TON METAL CHRG
TON PROC. WT.
TON CAST IRON
TON GRAY IRON PRODUCED
TON IRON
TON CAST IRON
TON CAST IRON
TON
TON
-33-
-------
LEAD SMELT (SEC)
SET
17
17
17
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.8
.7
.0015 .
UNITS: PER
TON LEAD
TON PROD.
TON PROD.
-34-
-------
CEMENT, DRY
SET
18
18
18
18
18
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
0.13
.120
.012
.003
UNITS: PER
TON
•
(1 BBL = 376 LBS.)
-35-
-------
GLASS MFG
SET
20
20
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.154
.010
UNITS: PER
TON
TON
**>
-36-
-------
FLUID CRACKER
SET
21
21
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.006
UNITS: PER
1000 BBL
(1 BBL = 42 GAL.)
-37-
-------
INCINERATOR
SET
24
24
24
24
24
24
24
24
24
24
POLLUTANT
ARSENIC
ASBESTOS
BARIUM
BERYLLIUM
BORON
CADMIUM
CHROMIUM
COPPER
LEAD
MAGNESIUM
MANGANESE
MERCURY
MOLYBDENUM
NICKEL
PHOSPHORUS
SELENIUM
SILVER
TITANIUM
VANADIUM
ZINC
BAP
(Pounds)
QUANT.
.055
.003
.2
.0014
.046
.00002
.004
.252
.013
UNITS: PER
TON SEWAGE BURNED
SOLID^ WASTE
CHRG.
.._ . »
' +
-38-
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/4-77-018
3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
REGIONAL AIR POLLUTION STUDY
Non-Criteria Pollutant Inventory
5. REPORT DATE
April 1977
6. PERFORMING ORGANIZATION CQDE
7. AUTHOR(S)
Fred E. Littman, Harry Wang, and John Piere
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Air Monitoring Center
Rockwell International
11640 Administration Drive
Creve Coeur, MO 63141
10. PROGRAM ELEMENT NO.
1AA603
11. CONTRACT/GRANT NO.
68-02-1081
Task Order 54
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Sciences Research Laboratory - RTP, NC
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, N.C. 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/600/09
15. SUPPLEMENTARY NOTES
16. ABSTRACT
In conjunction with the Regional Air Pollution Study (RAPS) being conducted
in the St. Louis Air Quality Control Region (AQCR), an inventory of non-criteria
pollutants was assembled for point sources. The inventory was based on the
following data:
The National Emissions Data System (NEDS) inventory for the AQCR.
inventory is based largely on 1971 and 1972 data.
This
2. Emission factors listed in the several reports in the -series entitled
"National Inventory of Sources and Emissions," which list estimated emission
factors for the following 21 compounds: Arsenic, Asbestos, Barium, Beryllium,
Boron, Cadmium, Chromium, Copper, Lead, Magnesium, Manganese, Mercury,
Molybdenum, Nickel, Phosphorus, Selenium, Silver, Titanium, Vanadium, Zinc,
and BaP.
The non-criteria emission factors are being incorporated into the RAPS Data
Handling System, and yearly point source inventories for non-criteria pollutants
are available.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COS AT I Field/Group
*Air pollution
*Estimates
*Environmental surveys
St. Louis, MO
Non-criteria pollutants
13B.
05J
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