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SAMPLING AND ANALYSIS
TO DETERMINE SOURCE SIGNATURES
IN "THE PHILADELPHIA AREA
by
J. A. Cooper and J. E. Houck
NEA, Inc.
Beaverton, Oregon -97005
and
J. E. Howes, Jr.
Battelle-Columbus Laboratories
Columbus, Ohio 43201
*---<^»r*^*hx,i
«*v-7=W**Vfti
'SOsSte.,^^
&SaE^.^*~
;rer.-3
SsssSHBalslSiis^^
-------
SAMPLING AND ANALYSIS
TO DETERMINE SOURCE SIGNATURES
IN THE PHILADELPHIA AREA
by
J. A. Cooper and J. E. Houck
NEA, Inc.
Beaverton, Oregon 97005
and
J. E. Howes, Jr.
Battalia-Columbus Laboratories
Columbus, Ohio 43201
EPA Contract No. 68-02-3745
Work Assignment No. 2
Project Officer
R. L. Bennett
Environmental Measurement and Characterization Division
Environmental Sciences Research Laboratory
Research Triangle Park, North Carolina 27711
ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U. S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
-------
DISCLAIMER
The information in this document has been funded wholly or in part by
the United States Environmental Protection Agency under Contract No. 68-
02-3745. It has been subject to the Agency's peer and administrative
review, and it has been approved for publication as an EPA document.
11
-------
ABSTRACT
During July and August 1982, the U.S. Environmental Protection Agency
conducted a major field study in the Philadelphia, PA area to gather field
data to evaluate the predictive capabilities of receptor modeling. As part
of this study, Battelle-Columbus Laboratories and NEA, Inc., conducted a
program to obtain source emission or signature data for the receptor modeling
effort. The program involved collection of particulate emission samples from
major sources in the Philadelphia urban area and analysis of the samples for
particle mass and chemical composition. Sampling was performed with a NEA-
developed Dilution Source Sampling (DSS) system which provided for dilution
of the source emissions with ambient air followed by collection of the
particulate matter in <2.5 [Jm and 2.5 to 10 \Js& size ranges with dichotomous
samplers. During the period that source signature sampling was performed by
NEA, EPA/RTP and other EPA contractor personnel collected ambient air and.
other source emission data required to assess the efficacy of receptor
modeling.
Industrial processes that were sampled during the study included an
antimony oxide roasting operation, a coal-fired power plant, two oil-fired
power plants with different types of particulate emission controls, a
petroleum catalytic cracking unit, a municipal refuse incinerator, and a
secondary aluminum smelter. Source emission samples collected at each source
were analyzed gravimetrically to determine particle mass and elemental
composition of the particles collected on the filters was determined by
energy dispersive X-ray fluorescence (XRF) analysis. The chemical
composition data will form the basis for identifying elements unique to
specific sources that can be used as tracers in the source apportionment
work.
111
-------
CONTENTS
Abstract iii
Figures v
Tables v
1. Introduction k 1
2. Conclusions * - 3
3. Recommendations 4
4. Experimental Procedures 5
General experimental approach 5
Sampling site descriptions............... e 5
Source signature sampling................................ 5
XRF analysis .......................... ................... 9
Gravimetric analysis of DSS filters...................... 25
5. Results and Discussion 26
6. Quality Assurance Summary 36
Deviations from quality assurance plan 36
Accuracy and precision of gravimetric
analysis of filters 36
Accuracy and precision of X-ray fluorescence
analysis 38
References 42
Appendices
A. Southern Research report on evaluation of NEA
dilution source sampler <,.... 43
B. Dilution source sampler (DSS) - Standard
operating procedure 63
C. Energy Dispersive X-Ray fluorescence analysis of
air filters - Standard operating procedure 71
D. Teflon filter handling and storage - Standard
operating procedure 91
E. XRF analysis of source emission samples 110
IV
-------
FIGURES
Number Page
1 Dilution source sampler (DSS) 8
TABLES
1 Source Signature Sampling Protocol 6
2 Source Signature Sampling Sites 7
3 Source Signature Sampling Data 10
4 Source Sampling Data - Harshaw/Antimony Oxide
Roasting Operation 12
5 Source Sampling Dj:ta - Eddystone/Coal-Fired Power Plant 14
6 Source Sampling Data - Schuylkill/Oil-Fired Power Plant 16
7 Source Sampling Data - Eddystone/Oil-Fired Power Plant 18
8 Source Sampling Data - British Petroleum/Catalytic
Cracker 20
9 Source Sampling Data - Atlantic Metals Sec.
Aluminum Sraelter 22
10 Source Sampling Data - East Central Incinerator 23
11 Chemical Composition of Particulate Emissions
Source - Harshaw/Antimony Oxide Roasting 27
12 Chemical Composition of Particulate Emissions
Source - Eddystone/Coal-Fired Power Plant 28
-------
TABLES (Continued)
Number Page
13 Chemical Composition of Particulate Emissions
Source - Schuylkill/Oil-Fired Power Plant 29
14 Chemical Composition of Particulate Emissions
Source - Eddystone/OIl-Fired Power Plant 30
15 Chemical Composition of Particulate Emissions
Source - British Petroleum/Catalytic Cracker... 31
16 Chemical Composition of Particulate Emissions
Source - Atlantic Metals/Secondary Aluminum Smelter 32
17 Chemical Composition of Particulate Emissions
Source - East Central Incinerator , ...... 33
18 Accuracy and Precision of Gravimetric Analysis of Filters 37
19 Accuracy and Precision of XRF Analysis of QA Standard 38
20 Results of Analysis of QA Standard 39
-------
SECTION 1
INTRODUCTION
Over the past several years, receptor modeling has evolved as a distinct
discipline to apportion source contributions to ambient air particulates.
The concept which has been discussed by Cooper^' involves measurement of
specific features of ambient particulates and use of these features to
apportion the contribution to various sources which impact on a receptor
site. Chemical and physical properties of the ambient particulate samples
such as chemical composition, particle morphology, size distribution, etc.,
may be employed in receptor modeling. In order to employ receptor models, it
is necessary to have information on specific characteristics of both ambient
aerosols collected at receptor sites and particulate emissions from major
sources which impact the receptor sites. Ideally, source emission samples
should be acquired after mixing and cooling with ambient air so that they
more closely approximate the size distribution and chemical composition of
the particulate material after it has entered the ambient environment.
Furthermore, it is highly desirable to collect both ambient and ^ource
aerosols using the same sampling technique so that size distribution and
other characteristics will be similar for the two types of samples.
During July and August 1982, the U.S. Environmental Protection Agency
conducted a major field study in the Philadelphia, PA area to gather field
data to evaluate the predictive capabilities of receptor modeling. As part
of this study, Battelle-Columbus Laboratories (BCL) and NEA, Inc., conducted
a program to obtain source emission data for the receptor modeling effort.
The program involved collection of particulate emission samples from major
sources in the Philadelphia urban area and analysis of the samples for
particle mass and chemical composition. Sampling was performed with a NEA-
developed Dilution Source Sampling (DSS) system. This system provided for
dilution of the source emissions with ambient air followed by collection of
the particulate matter in <2.5 [Jm and 2.5 to 10 [Jm size ranges with
dichotomous samplers. Thus, source emission samples and samples collected at
ambient receptor sites during the study were obtained under similar
conditions.
Source emission samples collected during the program were analyzed
gravimetrically to determine particle mass and elemental composition of the
particles collected on the filters was determined by energy dispersive X-ray
fluorescence (XRF; analysis. After completion of the gravimetric and XRF
analyses by NEA, the filter samples were submitted to Dr. T. G. Dzubay,
EPA/RTP for additional physical and chemical analyses required to support the
receptor modeling study.
1
-------
During the period that source signature sampling was performed by NEA
and BCL, EPA/RTP and other EPA contractor personnel collected ambient air and.
other source emission data required to assess the efficacy of receptor
modeling.
-------
SECTION 2
CONCLUSIONS
The study has provided source emission data to support EPA's receptor
modeling/source apportionment work. Source signature data were obtained for
an antimony oxide roasting operation, a coal-fired power plant, two oil-fired
power plants with different types of particulate emission controls, a
petroleum catalytic cracking unit, a municipal refuse incinerator, and a
secondary aluminum smelter. Based on replicate measurements, it is concluded
that the data for all sources except the secondary aluminum smelter are
reliable and representative. The aluminum smelter data are too limited to
judge the quality of the measurements made at this source. Measurements for
a few specific elements in some of the source emissions may be subject to
errors for various reasons. These cases are identified in the
Recommendations Section and the text of the report.
-------
SECTION 3
RECOMMENDATIONS
The elemental composition data obtained in this study are considered to
be reliable and representative of the <10 |im particulate emissions from the
respective sources. Therefore.,. the data with the following limitations are
recommended as suitable for use in EPA's receptor modeling/source
apportionment programs.
1) Antimony levels in the Eddystone coal-fired power plant are
questionable. Residual contamination in the sampling system may
have yielded erroneously high antimony values.
2) Copper values for the Schuylkill oil-fired power plant are
questionable since it was necessary to use a copper inlet line on
the sampling system because of the high stack gas temperature. A
teflon inlet line was used for all the other sources.
3) The secondary aluminum smelter emission data are too limited to
provide an adequate characterization of this source type. The
extremely low stack parti'culate loading and, thus, the long sampling
times required precluded adequate replication of the emission
measurements at this source.
4) Significant compositional differences between the resuspended
baghouse catch and the actual emission samples from the secondary
aluminum smelter suggest that the former approach may not provide
representative emission data. However, the data obtained in this
study are limited and additional work would be necessary to resolve
this issue. .
5) The XRF method did not yield reliable measurements of barium in the
coal-fired power plant emissions. In future studies, if barium is
selected as a tracer for coal combustion sources, the XRF method
should be improved, if possible, or an alternate analytical method
should be employed for this element.
In general, the sampling and analytical methodology used in this study
performed well and is recommended without any major changes or modifications
for tuture source apportionment work. Future emission measurement studies
should obtain additional data for sources that have not been well
characterized, e.g., catalytic cracking units and for all sources over a
sufficient time period to account for process variability.
-------
SECTION 4
EXPERIMENTAL PROCEDURES
GENERAL EXPERIMENTAL APPROACH
Source signature sampling was performed at seven sites in the
Philadelphia urban area over the period July 26 - August 18, 1982.
Particulate emission sampling was performed at each site with the NEA
Dilution Source Sampling (DSS) system according to the general protocol shown
in Table 1. All sampling at each site was performed at a point downstream of
particulate control devices. During the tests at each site, particulate
emission samples were collected on Teflon, Nuclepore, or quartz fiber filter
media to provide samples for the various analyses required for implementation
and evaluation of the receptor model.
Following acquisition, the particle mass collected on each filter was
determined gravimetrically and the elemental composition of the particulate
catch on the Teflon and Nuclepore filters was determined by energy dispersive
XRF. The samples were then sent to Dr. T. G. Dzubay, EPA/RT? for additional
analyses (NAA, XRD, SEM, 1C, etc.) required for the receptor modeling effort.
SAMPLING SITE DESCRIPTIONS
Source signature sampling was performed at the seven sites identified in
Table 2. The sites were selected from a list of candidate sources developed
by Engineering Sciences (ES) for the Philadelphia Modeling Study. Operators
of at least 15 other sources on the ES list were contacted by BCL or ES;
however either permission to sample at the site was denied, the plant was
shut down, or the plant production was significantly curtailed during the
study period.
SOURCE SIGNATURE SAMPLING
The dilution source sampling system shown in Figure 1 was used to
collect particulate samples of the stack emissions for source signature
characterization. Additional details of the system are reported by Houck, et
al(2, 3)4
-------
TABLE 1. SOURCE SIGNATURE SAMPLING PROTOCOL
Sampling
Period
1
2
3
4
5
6
Dichotomous
Sampler
A
B
A
B
A
B
A
B
A
B
A
B
Fine (<2.5
Teflon
Quartz
Teflon
Teflon
Teflon
Quartz
Teflon
Teflon
Teflon
Quartz
Teflon
Teflon
Filter Medium
(Jra) Coarse (2.5 - 10 Mm)
Teflon (oil-coated)
Quartz
Teflon (oil-coated)
Nuclepore (oil-coated)
Teflon (oil-coated)
Quartz
Teflon (oil-coated)
Nuclepore (oil-coated)
Teflon (oil-coated)
Quartz
Teflon (oil-coated)
Nuclepore (oil-coated)
-------
TABLE 2. SOURCE SIGNATURE SAMPLING SITES
Site/Address
Process Type
Emission Control
Period Sampled
llarshaw Chemical Co.
Gloucester, NJ
Philadelphia Electric Co.
Eddys tone Station
Philadelphia, PA
Philadelphia Electric Co.
Schuykill Station
Christian St.
Philadelphia, PA
Philadelphia Electric Co.
Eddys tone Station
Eddystone, PA
British Petroleum Co.
Marcus Hook Refining
Marcus Hook, PA
Atlantic Metals Co.
Orthodox & Delaware River
Philadelphia, PA
City of Philadelphia
Eadt Central Incinerator
Philadelphia, PA
Antimony Oxide Roasting
Coal-fired power plant
Oil-fired power plant
Oil-fired power plant
Catalytic Cracker
Secondary Aluminum
(Rotary Aluminum Dross
Furnace)
i
Municipal Refuse Incineration
Baghouse/Wet Scrubber (wet
scrubber not in operation
during sampling)
Electrostatic precipitator
Mechanical (cyclone) collector
Electrostatic precipitator
Electrostatic precipitator
Baghouse
Electrostatic precipitator (not
in operation during sampling)
July 26-28
July 29 - August 2
August 2-6
August 9-10
August 11 - 13
August 16 - 17
August 17 - 18
-------
Temperature Sensor
Velocity Sensor
Pressure Sensor
To
Vacuum Blower
8" x 10" Outlet
Filter Holder
Dichotomous
Sampler If2
Sample Lines
to Dichotomous
Sampler
Controls
v 10" Inlet
Filter Holder
To
Inlet
Blower
(Dilution
air)
Sample Lines
to Dichotomous
Sampler Controls
Sampling Probe
Figure 1. NEA dilution source sampler.
-------
particulate material in the <2.5 [im and 2.5-10 pm size ranges. The
performance of the system has been characterized in laboratory studies
conducted by Southern Research. The results of the Southern Research study
are presented in Appendix A.
The operating procedures used to collect the source signature samples
with the DSS are given in Appendix B. Table 3 provides data on the source
and sampling system operation characteristics for each of the sites.
Sampling data for the DSS filters collected at the various sites are given in
Tables 4 through 10. The materials used for sample collection were:
Membrana Teflon filters, 37 mm, 2 |0m pore size, Nuclepore filters, 37 mm,
0.4 [Jm pore size, and Pallflex 2500 QAST quartz fiber filters, 37 mm. All
Teflon and Nuclepore filters used for sampling the coarse particle fractions
(2.5-10 |Jm) were oil-coated to prevent particle loss. The mass of particu-
late material collected on each filter is given in the last column of the
tables.
XRF ANALYSIS
Elemental analysis of the DSS dichotomous sampler filters was performed
by energy-dispersive X-ray fluorescence (EDXRF) with an EG&G Ortec TEFA III
system. The procedures used to perform EDXRF analyses are given in Appendix
C.
A block diagram showing the major components of the EDXRF system is
shown below.
Excitation Chamber
(sample presentation
X-Ray Tube
(excitation
X-Ray Spectrometer
(measurement of X-ray
Computer
(quantitative calculation
and instrument control)
-------
TABLE 3. SOURCE SIGNATURE SAMPLING DATA
Site Stack i;.as Teinpi-e aturea , °C
(fio during e.implo
collection, strong SOj odor fro* port opculnga, 10 |iu
prcfeparator uncd. Method 5, SU2, &nd NOR measurement a
jde by Cnglueer t ng Sc lencea aflci source algtiatur^
aamplIng peiIoJ.
la Elec. Co.
Station
t'owtir flant J
Duct after eciiautcag coUcctor
prtor ft a pre-hcater e inlet 66 ca
from Inside of stack wall.
Hftthort % and SO^ mcaiure««nt B «ddc concur rent I y by
B-.ttelU C.-lumLue, 6CO HW pia.it operating at 46U hJ
during saaple col leetIon. oil fuel piped STO» ARCO
refllnery, used copper 1ined inlet hose cather than
tcHon I Ined liotte d>i« tu> hijjh temperature of duct p.au.
10 MB preneparatoir rouU not be used due to nwall E.D,
of Inlet port, 1/4" button'liook nozz le , Isok I net Ic
sampling conditions aiiJ s JOi I ratio were used.
-------
TABLE 3. (Continued)
Site Slack Caa
(Prnceaa) Velocity, u/s Stack Oil. Cl,amber Ambient Sanpllng Location Cimmcnls
Philadelphia Elec. Co. 10.2 195-265 28*40 25-38 Breach to stack alter Induced draft 39) MW plant. Operating at 3/5 MU at tine of svinple
Eddy a tone Scat I on f an, ru*ovcd opacity Meter Co uau col lectlun started; load varlt'd during sample ci»l led I (in.
(Oil-flrcd Cower Plant) Ita port. Inlet 96 CM frosi inalde 10 \im preaepar.itnr used,
of breach.
British PetioloiiBi Co. 10.2 245-2SO 26-41 22-1S Hoith breach to alack, 2-1/4" port Hethod S( S02 and NO, Me.isurenents Made concurrently by
(Catalytic Cracker) above opacity neter, Inlet ll/ CM Engineering Science In stack, two Identical breaches fru«
iron Ina ide of breach. ESP to stack, Inadequate apace to share sampling plat fora
with Engineering Science | hence 4 Inch port* rould not b'.
uaed, laohlnetlc savple collected fro* one breach with
1/4'* bujto.i-tiook nozzle withouc 10 UM preseparator. 20:1
dilution ratio, data supplied by HP person .el from previous
Method 5 testa: 0.0102 gratna/DSCF front half. 0.0614
gralna/DSCF total.
Atlantic Ho i a I a Co. 14.7 72-BS 21-17 15-29 Breach to atack before Induced draft Paniculate grain loading very luu at lamp I ing point,
(Sec. Aluminum) fan after baghauue, Inlet 102 CM two tack a weie used, one alack by-paaaed tho baglioitdD.
fro* Inalde of breach. On both aampling daya heavy emlaalona were noted In I be
even Ing a f ron the bypass atack, nuneroua leaks were
alao noted in duct Ing to aLacfca, A baghouui* duar a ample
waa collected tra* aubtequent reauapenalon due to
light loadings anticipated on filtcra. 10 un preacparntor
uaed on probe Inlet,
City of Philadelphia 12.9 92-107 27-32 18-22 Ilorth. porta, second part fro* ejat, **o powei gcnemttnn from aysteia, volunc i eduction only,
E.ial Central Incinerator breach before Induced draCt fan, sampling platform ? 10 meters above ash/uaite loadlnf,
(Municipal refuse south stack. Inlet 102 CM frnn itatloi^ dtlullun air Inlet filter would be good
loclneral Ion)- Inside of breach wall. fugitive eaUulon sanpU.
-------
TABLE 4. SOURCE SAMPLING DATA - HARSHAW/ANTIMONY OXIDE ROASTING OPERATION
K>
Test No. Filter Type)
Fraction
C
F
C
F
C
F
C
F
C
f
C
F
C
F
C
F
C
F
C
F
Samp] Ing
Date
7/27/82
7/27/82
7/27/82
7/27/82
7/27/82
7/27/82
7/28/82
7/28/82
7/28/82
7/28/82 '
Sampling Period, hr EDT^
Start
1052
1052
1342
1342
1640
1640
0831
0831
1041
1041
End
1314
1314
1621
1621
1904
1904
1032
1032
124
124
") " " T<0
Sampling Time, Particle Mass
hrs Collected, ng
2.33
2.33
2.33
2.33
2.67
2.67
2.67
2.67
2.40
2.40
2.40
2.40
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
260
1107
533
1811
485
1816
399
2639
987
2169
358
1519
726
1159
-------
TABLE 4. (Continued)
Test No.
6-A
-B
Field
Blanks
Filter Type(a)
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon
Teflon (OC)
Huclepore
Quartz
Quartz
fa\
'OC indicates that filter
(b)F - Fraction <2.5Mm: C -
it would not fit through
^C ' m ~~L t-i*
Filter No.
AC006
AF134
CCO 8 3
AF133
AF245
AC080
CC125
DC285
DF325
Plze(b) Sampling Sampling Period, hr EDT^ fi^piipg T1""-,(d) Pnri-I^V M»s«
Fraction Date Start End hrs Collected, Mg
C 7/28/82 1303 1503 2.02 307
F 2.02 1356
C 7/28/82 1303 1503 2.02 709
F 2.02 1009
was oil-coated to retain coarse' particles.
Fraction 2.5
the sampling
- ~7um. Probe inlet preseparator was not used at this source because
port. D,fl for isokinetic sampling is ~7Mm; see Appendix A.
(d)
From dlchotomous sampler timers
-------
TABLE 5. SOURCE SAMPLING DATA - EDDYSTONE/COAL-FIRED POWER PLANT
-fs
Test No.
1-A
-B
2-A
-B
3-A
-B
4-A
-B
5-A
-B
Filter Type(a) Filter No.
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Nuclepore
Teflon
AC007
AF135
DC250
DF289
AC008
AF136
DC251
DF290
AC009
AF137
DC252
DF291
AC010
AF138
CCO 84
AF139
AC011
AF140
CCO 8 5
AF141
Size(b)
Fraction
C
f
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
F
Sampling
Date
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
8/2/82
1
Sampling Period, hr EOT
Start
0627
0627
0658
0658
0726
0726
0759
0759
0821
0821
End
0647
0647
0718
0718
0746
0746
0814
0814
0831
0831
c ) ""
Sampling Time,d Particle Mass
hrs Collected, pg
0.35
0.35
0.35
0.35
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.28
0.28
0.28
0.28
0.16
0.16
0.16
0.16
4981
1580
4074
1506
3230
1114
3381
989
3783
674
1683
442
1995
306
-------
TABLE 5. (Continued)
Test No.
6-A
-B
Field Blanks
(a)
Filter Type
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Nuclepore
Quartz
Quartz
Size( Sampling Sampling Period, hr EDT ° Sampling Time. Particle Mass
Filter No. Fraction Date Start End hrs Collected, U8
AC012 C 8/2/82 0839 0849 0.17 1773
AF142 F 0.17 491
CC086 C 8/2/82 0839 0849 0.17 . 2055
AF143 F 0.17-316
AC079
AF244
CC124
DC284
DF324
(a)
(b)
(c)
(d)
OC Indicates that filter was oil-coated to retain coarse particles.
F - Fraction <2.5wra; C - Fraction 2.5 - 10pm. Preseparator used on probe inlet.
Clock time
Based on dichotomous sampler timers (
-------
TABLE 6. SCHUYLKILL/OIL-FIRED POWER PLANT
Test No.
1-A
-B
2-A
-B
3-A
-B
4-A
-B
5-A
-B
(a)
Filter Type Kilter No.
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Nuclepore
Teflon
AC013
Al"144
DC253
DF292
AC014
AF145
DC254
DF293
AC015
AF146
DC255
DF294
AC016
AF147
CCO 8 7
AF148
AC017
AF149
CCO 8 8
AF150
o, (b)
bize
FractJ on
C
F
C
F
C
F
C
f
C
F
C
F
C
F
1 C
F
C
F
C
F
Sampling
Date
8/4/82
8/4/82
8/4/82
8/4/82
8/4-5/82
8/4-5/82
8/5/82
8/5/82
8/5/82
8/5/8^
Sampling Period, hr EOT (c) Si
Start
1953
1953
2133
2133
2337
2337
0153
0153
0346
0346
End
2123
2123
2333
2333
0137
0137
0324
0324
0646
0646
(d)
impllng Time, Particle Haas
hrs Collected, |jg
1.52
1.52
1.52
1.52
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
1.52
1.52
1.52
1.52
3.01
3.01
3.01
3.01
49
801
20.
656
5
178
17
539
33
544
22
428
24
417
-------
TABLE 6. (Continued)
Test No.
6-A
-B
7 A
-B
7B
(Repeat)
Field Blanks
(a)
Filter Type Filter No.
Teflon (OC)
Teflon
Nuclepore
Quartz
Teflon (OC)
Teflon
Nuclepore
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Nuclepore
Quartz
Quartz
AC018
AF151
CCO 89
DF295
AC019
AF153
CC090
API 32
CC09 1
AF154
AC078
AF243
CC123
DC283
DF323
Si~e (b) Sampling Sampling Period, hr EOT (c) KamnMM Ti»
Fraction Date Start
C 8/5/82 1629
F
C 8/5/82 1629
F
C 8/5-6/82 2041
F
C 8/5-6/82 2041
.F
C 8/6/82 0302
F
End h rs
1950 3.35
3.35
1950 3.35
3.35
0603 (e) 8.38
8.38
0203 5.37
5.37
0603 -3.03
3.03
(d)
, Particle Mass
Collected, (Jg
90
1762
234
156
3911
102
3186
3
517
(c)
(d)
OC indicates that filter was oil-coated to retain coarse particles.
F - Fraction <2.5 ym; C - Fraction 2.5 7ym. Preseparator on probe inlet was not used at
this source because it would not fit through the sampling port
is ~7 ym; see Appendix A.
Clock time !
Based on dichotomous sampler timers
D _ for isokinetic sampling
Sampler not operated from 0230 to 0300 hours
-------
TABLE 7. SOURCE SAMPLING DATA - EDDYSTONE/OIL-FIRED POWER PLANT
CD
'[Yst No. Filter Type
1-A Teflon (OC)
Teflon
-B Quartz
Quartz
2 -A Teflon(OC)
Teflon
-B Quartz
Quartz
3-A Teflon(OC)
Teflon
-B Quartz
Quartz
4-A Teflon(OC)
Teflon
~B Nuclepore
Teflon
5-A TeflontOC)
Teflon
-B Nuclepore
Teflon
Filter No.
AC020
AF155
DC256
DF296
AC021
AF156
DC257
DF297
AC022
AF157
DC25B
DF298
AC023
AF158
CC092
AF159
AC024
AF160
CC093
AF161
Size(a)
Fraction
C
F
C
F
C
F
C
K
C
F
C
F
C
F
C
F
C
F
C
F
Sampling
Date
8/10/82
8/10/82
8/10/82
8/10/82
8/10/82
8/10/82
8/10/82
8/10/82
8/10/82
1
ayio/82
Sampling Period, hr EOT Sa
Start
1447
1447
1554
1554
1703
1703
1845
1845
2003
2003
End
1547
1547
1654
1654
1833
1833
1945
1945
2133
2133
mpling Time
hrs
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.50
1.50
1.50
1.50
1.00
1.00
1.00
1.00
1.50
1.50
1.50
1.50
, Particle Mass
Collected, ug
63
639
48
546
100
1079
10
190
14
181
92
1389
110
1473
-------
TABLE 7. (Continued)
(a)
Test No. Filter Type Filter No.
6-A Teflon (OC)
Teflon
-B Nuclepore
Teflon
Field Blanks Teflon (OC)
Teflon
Nuclepore
Quartz
Quartz
AGO 2 5
AF162
CCO 9 4
AF163
AC026
AF164
CC095
DC259
UF299
Size (b) Sampling Sampling Period, hr EDT(c) Samoline Time
Fraction Date Start
C 8/10/82 2140
F
C 8/10/82 2140
F
End lirs
2340 2.00
2.00
2340 " 2.00
2.00
(d)
, Particle Mass
Collected, pg
24
700
26
736
(a)
OC indicates that filter was oil-coated to retain coarse particles.
(b)
(c)
(d)
F - Fraction <2.5pm; C - Fraction 2.5 - 10 pro. Preseparator used on probe inlet.
Clock time.
Baaed on dichotomous sampler timers.
-------
TABLE 8. SOURCE SAMPLING DATA - BRITISH PETROLEUM/CATALYTIC CRACKER
(a)
T- sc No. Kilter Type
1-A Teflon (OC)
Teflon
~B Quartz
Quartz
2-A Teflon (OC)
Teflon
-B Quartz
Quartz
3-A Teflon (OC)
Teflon
~B Nuclepore
Teflon
4-A Teflon (OC)
Teflon
~B Nuclepore
Teflon
5-A Teflon (OC)
Teflon
-B Nuclepore
Teflon
Filter No.
AC027
AF165
DC260
DF300
AC028
AF166
DC261
DF301
AC029
AF167
CCO 9 6
AF168
AC031
AF169
CCO 9 7
AF170
AC032
AF171
CC098
AF172
Size(b)
Fraction
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
f
C
F
C
F
Sampling
Date
8/12/82
8/12/82
8/12/82
8/12/82
8/12/82
8/12/82
8/12/82
8/12/82
8/12/82
8/12/fl2
Sampling Period, hr EUT
Start
0927
0927
1135
1135
1343
1343
1556
1556
1802
1802
End
1128
1128
1335
1335
1543
1543
1756
1756
2002
2002
Sampling Time
hrs
2.01
2.01
2.01
2.01
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
(d)
, Particle Mass
Collected, ug
358
6421
309
6101
342
7386
220(e)
7636
319
8221
260(e)
8127
359
7924
374(e)
7907
-------
TABLE 8. (Continued)
Test No.
6-A
-B
Field Blanks
(a)
Filter Type
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Nuclepore
Quartz
Quartz
Filter No.
AC033
AF173
DC 26 2
DF302
AC077
AF242
CC122
DC282
DF322
Size(b) Sampling Sampling Period, l,r EOT (c)
Fraction - Date Start End
C 8/12/82 2009 2323(f)
F
C 8/12/82 2009 2323(f)
F
(d)
Sampling Time, Particle Mass
hrs Collected, pg
3.09 612
3.09 10087
3.09
3.09
^
(b)
(c)
(d)
(e)
(f)
OC indicates that filter was oil-coated to retain coarse particles.
F - Fraction <2.5»im - «7|im. Preseparator on probe inlet was not used at this source because it would not fit through
the sampling port. DSQ for isoklnetic sampling Is -7pm; see Appendix A.
Clock time.
Based on dichotomous sampler timers.
Particle mass incorrect due apparently to weighting error.
Sampler off from 2239 to 2248 hours.
-------
TABLE 9. SOURCE SAMPLING DATA - ATLANTIC METALS SEC. ALUMINUM SMELTER
NJ
to
(a)
Test No. Filter Type
1-A Teflon (OC)
Teflon
-B Quartz
Quartz
2-A Teflon (OC)
Teflon
-B Nuclepore
Quartz
I a\
RS-11*' Teflon (OC)
Teflon
RS-2 Nuclepore
Teflon
KS-3 Quartz
Quartz
Field Blanks Teflon
Teflon (OC)
Nuclepore
Quartz
Quartz
Filter No.
AGO 34
AF174
DC263
DF303
AC035
AF175
CC100
DF304
AC042
AF183
CC111
AF184
DC266
DF306
AF241
AC076
CC121
DC281
DF321
. (b)
Size
Fraction
C
F
C
F
C
F
C
F
C
F
C
F
C
F
1
SampHng Sampling Period, hr EOT L sa,npU,,g Tim*,
Date Start End hrs
8/16/82 1430 1952(e) 5.52
5.52
8/16/82 1430 1952(e) 5.52
5.52
8/17/82 1018 2004(f) 9.61
9.61
8/17/82 1018 2004(f) 9.61
9.61
-
Particle Masa
Collected, MB
24
110
153
604
208
4939
624
2916
187
(a)
(b)
(c)
(d)
(e)
(f)
(g)
OC indicates that filter was oil-coated to retain coarse particles.
F - Fraction <2.5um; C - Fraction 2.5 - lOpra. Preaeparator used on probe inlet.
Clock time.
Based on dichotoraous sampler timers.
Sampler off from 1937 to 1944 hours.
Sampler off from 1228 to 1238 hours.
Samples generated by resuspension and sampling of Atlantic Metals baghouse hopper dust.
-------
TABLE 10. SOURCE SAMPLING DATA - EAST CENTRAL INCINERATOR
to
Test No.
1-A
-B
2-A
-B
3-A
-B
4-A
-B
5-A
-B
Filter Type
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Quartz
Quartz
Teflon (OC)
Teflon
Nuclepore
Teflon
Teflon (OC)
Teflon
Quartz
Quartz
fr
Filter No.
AC036
AF176
DC264
DF305
AC037
AF177
CC101
AF178
AC038
AF179
DC265
DF309
AC039
AF180
CC102
AF181
AC046
AF182
DC269
DFHO
Size(b)
Fraction
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
F
C
F
Sampling
Date
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
8/18/82
1
Sampling Period, hr EOT (c'
Start
1153
1153
1301
1301
1407
1407
1617
1617
1653
1653
End
1253
1253
1401
1401
1607
1607
1647
1647
1823
1823
Sampling Time
hrs
2.00
2.00
2,00
2.00
1.00
1.00
1.00
1.00
2.00
2.00
2.00
2.00
0.50
0.50
0.50
0.50
'1.50
1.50
1.50
1.50
, Particle Mass
Collected, ug
131
1016
220
1579
168
1672
287
2783
128
1028
105
1143
313
2882
-------
TABLE 10, (Continued)
(a)
Test No. Filter Type Filter No.
6-A Teflon(OC)
Teflon
-B Nuclepore
Teflon
7-A Teflon
-------
Atoms in the sample are excited from their ground state to higher energy
levels by radiation from a X-ray tube. These excited atoms emit X-rays of
discrete energies as they return to their normal ground, state energy level.
The energy of the X-rays is characteristic of the emitting element and is
used to qualitatively identify the element while the number of observed X-
rays, which is proportional to the number of atoms, is used to quantitatively
determine a specific element's concentration through a direct comparison with
standards.
There are a number of potential spectral interferences possible with
EDXRF because of its low resolution relative to the number and spacing of
possible X-ray lines. Correction factors are determined by analyzing single
element standards and quantifying their interference with other elements.
Samples exhibiting chemical composition uncharacteristic of normal samples
may require additional corrections.
Most of the background counts in a region of interest are due to the
scattering of primary radiation from the sample. A blank filter is run under
each excitation condition and the background in each region of interest is
linearly related to a high energy incoherent scatter peak due to the primary
radiation. The same scatter peak is measured on all samples and the
relationship is used to estimate the background in the analyte line region of
Interest.
GRAVIMETRIC ANALYSIS OF DSS FILTERS
The procedures used for handling the DSS dichotoraous sampler filters and
for gravimetric analysis of the filter samples are given in Appendix D.
25
-------
SECTION 5
RESULTS AND DISCUSSION
The elemental compositions of the source signature samples determined by
XRF analysis are presented in Appendix E. Data, at the top of each page gives
the sampling site and Test No.,, particle size fraction (C -1 2.5 to 7 or 10
Hm, F - <2.5 pm) , the filter number and type, and the mass of particulate
material collected on the filter (in ]ig). Elemental compositions are
reported as concentration per unit filter area (jig/cm^), total quantity of
the element in the particulate material, and percentage by weight of the
element in the particulate sample. Estimated uncertainties are reported for
each measurement.
Summaries of the elemental composition of the particulate emissions from
each of the sources are provided in Tables 11 through 17. These tables show
the weighted average composition of the emissions calculated from all valid
tests performed at a given site. The standard deviation (n-1) is also given
to provide an indication of the variability in the measurements.
Following is a brief discussion of the results of the source signature
measurements made at each site.
Harshaw Chemical (Antimony Roasting)
The emissions from this source were composed primarily of Sb. The Sb
concentration found in the samples was generally about 80 percent with a
minimum of 67 percent and a maximum of 87 percent. The deposits ranged from
a few hundred to a few thousand micrograms per filter. Only a few other
elements (S, Cl, Fe, Ni, Cu, Zn and As) were observed, and these were
typically at concentrations less than 1 percent. Field blanks were
essentially at background levels.
Philadelphia Electric and Gas (Coal Fired Power Plant)
The composition of the coal fired power plant emissions was similar to
that previously reported for flyash. Elements such as P, S, Ge, As and Se
were enriched in the fine particle fraction. The composition for most of the
elements was reasonably constant for all samples.
The variability of the barium content in the samples is due mainly to
difficulties in the XRF analysis. Background subtraction in the region of
the barium X-ray is r.ot very precise, particularly for sampler with such
unusual chemical composition. Barium concentrations must be twice
26
-------
TABLE 11. CHEMICAL COMPOSITION OF PARTICIPATE EMISSIONS
Source: Harshaw/Antimony Oxide Roasting No. Tests jj
Element
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition
Fine Fraction, <2.5
ND
ND
, ND
1.28 + 0.07
0.74 + 0.03
ND
ND
ND
ND
<0.01
<0.01
0.10 + 0.02
0.01 + 0.0008
0.01 + 0.0008
0.01 + 0.0005
<0.01
0.12 + 0.05
<0.01
<0.01
-------
TABLE 12. CKtlHTGA.1. COMPOSITION OF PARTICULATE EMISSIONS
Sources Eddystone/Coal-Fired Power Plant No, Tests 6
Element
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition
Fine Fraction, <2.
14.46 + 0.74
21.77 + 1.23
0.62 + 0.06
3.51 + 0.51
0.06 + 0.02
1.22 + 0.04
1.22 + 0.03
0.88 + 0.05
0.07 + 0.02
0.06 + 0.01
0.04 + 0.002
8.16 + 0.30
0.04 + 0.005
0.03 + 0.001
0.07 + 0.007
0.02 + 0.001
0.08 + 0.004
0.04 + 0.005
ND
<0.01
0.13 + 0.009
0,01 + 0.002
0.05 + 0.02
0.02 + 0.008
<0.01
<0.01
<0.01
0.01 + 0.003
0.01 + 0.02
1.84 + 1.04
0.14 + 0.12
0.02 + 0.03
ND
0.04 + 0.002
of Particulate Emission, % ±SD^a^
5 jJm Coarse Fraction, 2.5-10 \im
11.99 + 1.73
19.08 + 2.76
0.22 + 0.03
0.55 + 0.07
0.10 + 0.004
1.34 + 0.08
1.46 + 0.05
0.96 + 0.04
0.06 + 0.005
0.05 + 0.002
0.04 + 0.002
9.15 + 0.34
0.03 + 0.002
0.0_2_ + 0.001
0.04 + 0.002
0.02 + 0.001
0.04 + 0.002
<0.01
O.01
0.01 + 0.0008
0.16 + 0.003
0.02 + 0.001
0.03 + 0.003
0.02 + 0.002
<0.01
<0.01
<0.01
0.01
O.01
0.06 + 0.03
0.11 + 0.02
O.01
ND
0.03 + 0.0008
a) ND - not detected.
28
-------
TABLE 13. CHEMICAL COMPOSITION OF PARTICULATE EMISSIONS
Source: Schuylkill/Oil-Fired Power Plant No. Tests JJ
Element
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition
Fine Fraction, <2.5
1.75 + 0.24
2.94 + 0.46
1.03 + 0.14
13.21 + 0.51
ND
0.21 + 0.03
1.90 + 0.53
0.12 + 0.03
1.41 + 0.24
0.05 + 0.009
0.03 + 0.006
1.77 + 0.36
2.07 + 0.38
0.14 + 0.10
0.85 + 0.21
0.01 + 0.004
0.01 + 0.007
<0.01
<0.01
<0.01
0.03 + 0.007
<0.01
0.02 + 0.03
0.14 + 0.05
<0.01
<0.01
<0.01
<0.01
0.02 + 0.02
0.12 + 0.03
0.19 + 0.12'
0.23 + 0.30
<0.01
1.11 + 0.31
of Particulate Emission, % ±SD^a^
\isn. Coarse Fraction, 2.5-7 \im^°
10.46 + 2.71
21.72 + 5.96
1.40 + 0.25
9.06 + 1.50
<0.01
0.32 + 0.08
8.37 + 1.96
1.02 t- 0.17
1.61 + 0.35
0.17 + 0.06
0.07 + 0.05
3.69 + 0.63
1.76 + 0.35
2.36 +__2.83-
0.91 + 0.14
0.03 + 0.03
0.09 + 0.11
<0.01
<0.01
<0.01
0.-13 + 0.07
<0.01
0.08 + 0.08
0.07 + 0.06
0.03 + 0.04
0.09 + 0.14
0.39 + 0.41
0.32 + 0.21
0.39 + 0.39
0.30 + 0.23
0.22 -* 0.36
1.90 + 2.18
<0.01
0.51 + 0.27
a) ND - not detected, b) Does not include data from Tests 3A, 5B, 7B, or 7B
(repeat).
29
-------
TABLE 14. CHEMICAL COMPOSITION OF PARTICULATE EMISSIONS
Source: Eddystone/.Oil-Fired Power Plant No. Tests 6
Element
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition of Particulate Emission, % ±SD^a)
Fine Fraction, <2.5 pm
1.24 + 0.26
2.21 + 0.49
1.70 + 0.35
12.01 + 1.67
ND
0.20 + 0.05
2.54 + 0.59
0.04 + 0,04
0.81 + 0.18
0.04 + 0.01
.0.04 + 0.01
1.94 + 0.42
1.83 + 0.47
0.12 + 0.03
1.49 + 0.37
<0.01
<0.01
<0.01
0.01 + 0.006
<0.01
0.02 -t- 0.004
<0.01
0.03 + 0.05
0.10 + 0.02
0.01 + 0.008
<0.01
0.01 + 0.005
<0.01
0.05 + 0.04
0.19 + 0.10
0.40 + 0.18
0.27 + 0.20
<0.01
2.29 + 0.57
Coarse Fraction, 2.5-10 pm
4.73 + 1.27
9.37 + 2.59
2.34 + 0.25
9.13 + 1.26
0.01 + 0.03
0.34 + 0.14
10.63 + 2.35
0.83 * 0.24
1.80 + 0.38
0.11 + 0.02
0.08 + 0,03
3.56 + 0.75
2.28 + 0.43
0.15 + 0.02
1.84-7 0.35
0.03 + 0.03
0.03 + 0.03
0.01 + 0.02
0.01 + 0.02
0.05 + 0.07
0.15 + 0.08
0.02 + 0.02
0.07 + 0.11
0.14 + 0.08
0.09 + 0.07
0.24 + 0.33
0.18 + 0.29
0.08 + 0.12
0.04 + 0.07
0.09 + 0.21
1.20 + 1.18
1.10 + 1.49
0.02 + 0.04
2.78 + 0.50
a) ND - not detected.
30
-------
TABLE 15. CHEMICAL COMPOSITION OF PARTICULATE EMISSIONS
Source: British Petroleum/Catalytic Cracker No. Tests _6
Element
Al
Si
. P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition
Fine Fraction, <2.
4.14 H- 0.73
10.41 + 1.25
0.01 + 0.03
4.20 + 0.47
ND
0.03 + 0.006
0.03 + 0.005
0.11 + 0.03
ND
ND
ND
0.22 + 0.03
0.02 + 0.004
<0.01
<0.01
<0.01
ND
<0.01
<0.01
<0.01
<0.01
0.01 + 0.001
ND
ND
ND
ND
ND
<0.01
<0.01
<0.01
ND
0.22 + 0.04
ND
<0.01
of Particulate Emission^ % ±SD^a^
5 Mm Coarse Fraction,. 2.5-7 |Jm(b
24.19 + 1.35
50.37 + 3.78
ND
3.97 + 1.61
ND
0.12 + 0.02
0.17 + 0.04
' 0.28 + 0.04
ND
ND
ND
0.59 + 0.03
0.06 + 0.01
<0.01
0.01 + OJ)D3
<0.01
ND
<0.01
<0.01
<0.01
0.01 + 0.003
0.03 + 0.005
0.01 + 0.01
<0.01
<0.01
0.02 + 0.02
0.01 + 0.01
<0.01
ND
0.01 + 0.03
0.10 -t- 0.11
0.65 + 0.17
ND
0.03 + 0.01
a) ND - not detected, b) Does not include data from Tests 3B, 4B, and 5B.
31
-------
TABLE 16. CHEMICAL COMPOSITION OF PARTICULATE EMISSIONS
Sources Atlantic Metals/Secondary Aluminum Smelter No. Tests
Average Composition of Particulate Emissions, % iSD^3'
Element
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Fine Fraction
Source
1.88 + 0.62
4.40 + 2.84
0.65 + 0.40
22.00 + 27.03
13.44 + 13.81
11.14 + 1.56
0.15 + 0.09
0.02 + 0.005
0.01 + 0.006
0.01 + 0.02
0.01 + 0.004
0.19 + 0.08
0.02 + 0.02
0.07 + 0.04
0.16 + 0.11
<0.01
0.02 + 0.008
<0.01
0.06 + 0.01
<0.01
<0.01
<0.01
<0.01
ND
0.03 + 0.04
0.01 + 0.01
ND
0.11 + 0.14
0.14 + 0.13
0.58 + 0.03
0.51 + 0.67
0.31 + 0.44
ND
0.10 + 0.03
, <2.5 iJm
Baghouse RS
ND
ND
ND
4.30 + 0.008
40.95 + 1.51
12,73 + 1.95
0.19 + 0.03
0.13 + 0.0
<0.01
<0.01
<0.01
0.10 + 0.01
<0.01
0.03 + 0.0
0.08 + 0.006
<0.01
0.05 + 0.01
<0.01
0.04 + 0.004
<0.01
0.01 + 0.008
0.01 + 0.008
0.05 + 0.07
0.04 + 0.04
<0.01
<0.01
0.07 + 0.05
0.09 0.10
0.02 + 0.02
0.07 + 0.10
0.23 + 0.33
0.18 + 0.26
<0.01
2.23 + 0.62
Coarse Fraction, 2.5-10 pm
Source
4.72 + 0.17
7.32 + 2.17
0.33 + 0.09
1.27 + 1.79
23.41 + 0.95
7.39 + 5.21
0.95 + 0.34
0.16 + 0.06
0.01 + 0.006
0.11 + 0.10
0.01 + 0.02
1.64 + 0.72
0.10 + 0.08
0.14 + 0.07
0.25 + 0.08
<0.01
<0.01
0.03 + 0.007
0.05 + 0.0
<0.01
<0.01
<0.01
0.29 + 0.37
<0.01
<0.01
0.02 + 0.02
0.13 + 0.13
0.09 + 0.06
0.02 + 0.02
0.69 + 0.28
0.03 + 0.05
3.19 + 4.51
<0.01
0.16 + 0.08
Baghouse RS
ND
ND
ND
2.92 + 0.19
36.73 + 1.52
11.65 + 0.84
0.13 + 0.007
0.01 + 0.001
<0.01
<0.01
<0.01
0.04 + 0.004
<0.01
0".02 + 0.001
0.05 + 0.001
<0.01
ND
O.01
0.03 + 0.001
0.01 + 0.0
<0.01
<0.01
ND
0.02 + 0.004
<0.01
<0.01
<0.01
<0.01
<0.01
0.03 + 0.01
<0.01
0.01 + 0.02
<0.01
0.74 + 0.08
a) ND - not detected.
32
-------
TABLE 17. CHEMICAL COMPOSITION OF PARTICULATE EMISSIONS
Source: East Central Incinerator No. Tests 7
Element
Al
Si ,
P
"S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
Average Composition of Particulate
Fine Fraction, <2.5 \ua Coarse
1.45 + 0.61
1.79 + 0.56
0.65 + 0.12
2.94 + 0.80
25.31 + 3.18
8.46 + 2.51
0.28 + 0.06
0.04 + 0.01
0.01
0.02 + 0.002
0.02 + 0.003
0.33 + 0.08
.0.03 + 0.004
0.15 + 0.02
10.97 + 2.15
0.02 + 0.01
<0.01
<0.01
0.30 -i- 0.14
0.02 + 0.004
<0.01
ND
<0.01
0.02 + 0.01
0.03 + 0.01
0.02 + 0.009
0.26 + 0.05
0.01 + 0.01
0.79 + 0.18
0.25 + 0.11
0.04 + 0.04
<0.01
<0.01
6.08 + 1.39
Emission, % ±SD
-------
the standard deviations (see data in Appendix E) before the data is
considered reliable.
Antimony was unusually high in the fine fraction, ranging from 0.98
percent to 3.8 percent. Although the entire sampler was thoroughly washed
and scrubbed with brushes, soap, water and methanol between each source
sampled, there is a remote possibility that metallic Sb condensed on the
surface of the probe and was later volatilized during the coal fired power
plant test. This hypothesis has been evaluated from several directions, but
it has not been possible to definitively say that this was or was not a
problem. Because of the unusual nature of the Sb results and the previously
sampled source, it is recommended that Sb not be included in the receptor
modeling data base or a footnote about the potential contamination be made.
Philadelphia Electric and Ga-s (Schuylkill Oil-Fired Power Plant)
The deposits collected with these samples were, in general, less than
those collected at the coal-fired boiler. Deposit loadings ranged from less
than 10 (ig filter in the coarse fraction to almost 4,000 [ig/filter even
though sampling times were as long as 8 hours. Although some of the same
elements such as V and Ni that have been previously reported were observed in
the emissions from this boiler and the one at Eddys tone, many other elements
not previously reported such as Al, Si, P, S, Ca, Fe, Cu, Zn and Pb were
found at concentrations greater than 1 percent. Also of interest was the
presence of Mo at about one or two tenths of a percent. Mo may be useful as
a tracer for oil combustion since it is relatively uncommon in most emissions
and is typically at the nanogram level in urban aerosols. S is slightly
enhanced in the fine fraction while most of the other elements are depleted
in the fine fraction. The largest difference is in the Al, Si and Ca which
are about 5 fold more abundant in the coarse fraction than in the fine
fraction.
Substantial amounts of Sb were not observed, suggesting that the Sb
observed in the coal-fired power plant emissions may have been real or that
any Sb contamination had been removed from the sampling system.
Philadelphia Electric and Gas (Eddystone Oil-Fired Power Plant Station)
These samples were also more lightly loaded than those collected at the
coal-fired power plant. Even though sampling times between about 1 hour and
8 hours were used, deposit loadings ranged from 20 [ig to about 1,500
|ig/filter. The elements Ni and V usually associated with residual oil
combustion were abundant in both the fine and coarse fractions. Other
elements present at concentration greater than 1 percent included Al, Si, P,
S, Ca, V, Fe, Ni, Zn and Pb. The concentration of Al, Si and Ca were several
fold lower in the fine fraction than in the coarse fraction. Sulfur was the
only element substantially enriched in the fine fraction while V, Fe, Ni, Zn
and Pb were depleted in the fine fraction. Sb was not enriched in the'se
emissions as was observed with the coal flyash. Mo was found in the fine and
coarse fractions at concentrations similar to those observed in the Eddystone
oil-fired power plant samples, i.e., 0.1 percent. This observation provides
additional support for the suggestion that Mo may be a suitable tracer
element for oil combustion. (Also see comments on individual data sheets).
34
-------
City of Philadelphia, East Central Incinerator (Municipal Refuse
Incineration)
The chemical composition of these incinerator samples was relatively
constant during the sampling period. Most of the mass was in the fine
fraction and the chemistry was similar in both fractions. Al, Si, Ca and Ti
were generally more abundant in the coarse fraction while Cl, K, Zn, Cd, Sn,
Sb and Pb were substantially enriched in the fine fraction. Cl was the most
abundant element in both the fine and the coarse fraction.
British Petroleum (Catalytic Cracker)
These results represent some of the first detailed elemental analysis of
this type of emissions and, thus there is very little data for comparison.
The high Al and Si, however, is in agreement with literature values. The Al
and Si are about 4 fold greater in the coarse fraction than in the fine
fraction. The only other element greater than 1 percent was S which was
about 4 percent in the fine fraction and about 3 percent in the coarse
fraction. The most notable feature about the chemistry of these emissions
was the high abundance of La, Ce and Nd, all of which were about the same
concentration, a few tenths of a percent. Since standards were not available
Ce and Nd concentrations in the samples could not be quantified. Their
spectral intensities, however, suggested concentrations similar to those of
La.
The mass loadings on the three coarse samples collected oh tiuclepore are
incorrect as is obvious from the over 150 percent of the mass explained by
the Al and Si. This is about a factor of 2 more than was observed for the
other coarse samples collected from this source. Although a fac'tor of two is
suggestive of a weighing or calculational error, the source of the error
could not be identified.
Atlantic Metals (Rotary Aluminum Dross Furnace)
The most abundant elements present in these deposits are S, Cl and K.
The next most abundant are Al and Si at a few percent. The concentration
variability between samples, however, is much more substantial than had
previously been observed with the other samples collected in Philadelphia.
The S, for example, is 41 percent in the fine fraction filter AF 174, but
only 2.8 percent on filter AF 175.' This is a secondary Al smelter plant
which processes metal in batches. It is possible that the 5 to 8 hour
sampling periods integrated different stages of the batch operation.
Unfortunately, a smaller number of replicates were obtained at this site due
to the long sampling times required. Data are also presented for the
composition of the baghouse collector dust which was resuspended and
collected with dichotomous samplers. There are significant differences in
the elemental composition of the resuspended samples and the actual source
emission samples. For example, Al and Si present in percent levels in the
emission samples were not detected in the resuspended baghouse dust samples
and the concentrations of several other elements were considerably lower in
the latter samples. The dissimilarity in the two types of samples suggests
that the resuspended samples may not be representative of the source
emissions. However, the data obtained in this study are too limited to
substantiate this conclusion.
35
-------
SECTION 6
QUALITY ASSURANCE SUMMARY
DEVIATIONS FROM QUALITY ASSURANCE PLAN
Gravimetric Analysis of Filters
The Standard Operating Procedure for weighing the fragile quartz fiber
filters was modified when determining net weight because of material loss
during handling and changes in humidity. The calculations of the net weight
were made as follows to incorporate a correction due to handling and humidity
effects.
Net weight = Gross weight - Tare weight - Correction value of material
loss and humidity effects.
The correction value was determined by the mean weights of all of the
field blanks and unused filters. The correction value was determined by the
mean net weights of all of the field blanks and unused filters. The
correction value for the fine quartz filters was - 42 ug. The correction
value for the coarse filters was - 22 \ig.
Filter Handling
Quartz fiber filters were not stored in metal dishes immediately after
assigning ID numbers. They were stored in plastic petri dishea for about 1
week. (The metal cans did not arrive in time). It was decided that loading
them into holders and wrapping with aluminum foil would cause more problems,
since they would have to be unloaded for tare weighing, and the excess
handling would result in loss of material from the filters. The effect of
plastic petri dishes was thought to be insignificant, since the filters come
wrapped in plastic, are held in plastic holders and were to be used for
source sampling in which the organic deposits were expected to be high.
ACCURACY AND PRECISION OF GRAVIMETRIC ANALYSIS OF FILTERS
Precision of mass measurements, W , is determined for each filter type
by calculating the mean of the absolute value of the difference in replicate
weighings, W , for n replicate weighings.
36
-------
,
d
1 = 1
Accuracy is assessed by determining the percent error, % E., for each
weighing set i, where x
E. = 100 X
i
measured tare weight - true tare weight
true tare weight
The overall percent error, % E, is the average percent error from each
weighing set,
n
These results are summarized in Table 18.
TABLE 18. ACCURACY AND PRECISION OF GRAVIMETRIC
ANALYSIS OF FILTERS
Filter Type
Oil Coated
Nuclepore
Teflon Membrane
Quartz
Precision
W in [ig
3.4
3.4
3.2
56.1
(n =
(n =
(n =
(n =
13)
8)
18)
13)
Accuracy
% E
0.001
0.015
0.001
.001
Completeness
100
100
100
100
37
-------
ACCURACY AND PRECISION OF X-RAY FLUORESCENCE ANALYSIS
Precision for the XRF analysis was determined by calculating the mean
and standard deviation of the QA standard in each analysis run. These
results are summarized in Table 19. The QA data for each X-ray analysis run
are listed in Table 20.
TABLE 19. ACCURACY AND PRECISION OF XRF
ANALYSIS OF QA STANDARD
Element
Si
Ti
Fe
Cd
Pb
Mean Value Standard Deviation
Hg/cm2 tig/ cm2
26.35
10.96
30.55
32.78
25.71
0.24
0.06
0.19
0.11
0.13
Relative Standard Accuracy
Deviation % Avg. % Error
0.91
0.55
0.62
0.34
0.50
1.3
-0.3
0.5
0.9
0.8
Average Relative Standard Deviation, % = 0.58
38
-------
TABLE 20. RESULTS OF ANALYSIS OF QA STANDARD
181/95-3
QA STANDARD QS116
EL CONCENTRATION
7. ERROR
181/95-7
QA STANDARD QS116
EL
SI
TI
FE
CD
PB
ACTUAL
26.00
1 1 . 00
30 . 40
32 . 50
25.50
MEASURED
26.
10.
30.
O
25.
40+-
98+-
72+-
76+-
30+-
1.33
0.55
1.55
1 . 66
1.30
1.5
- 0.2
1.0
O.S
1.2
SI
TI
FE
CD'
PB
ACTUAL
26.00
1 1 . 00
30.40
32 . 50
25.50
MEASURED
25.
11.
30.
32.
25.
92+-
04+-
55+-
79+-
71+-
1.31
0.56
1.54
1 . 66
1.29
- 0.3
0 . 3
0. 5
0.9
0 . 3
181/95-4
QA STANDARD GSM 6
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
181/95-8
QA STANDARD QS116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
SI
TI
FE.
CD
PB
26.00
11 .00
30 . 40
32.50
25.50
26.24+-
10.91+-
30.31+-
32.71+-
25.76+-
1.32
0.55
1.53
1.66
1.30
0
- 0
- 0
0
1
m o
.S
.3
.6
.0
SI
TI
FE
CD
PB
26.00
1 1 . 00
30.40
32.50
25.50
26.
10.
30.
t"~>
w*.
25.
33+-
93+-
55+-
71+-
64+-
1.33
0.55
1.54
.1 . 66
1.29
1.3
- 0.6
0.5
0.6
0.6
131/95-5
QA STANDARD QS116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
181/95-9
QA STANDARD QS116
EL
SI
TI
FE
CD
PB
26.
11.
30.
32.
25.
00
00
40
50
50
26.
10.
30..
32.
34+-
92+-
76+-
63+-
75+-
1.
0.
1.
1.
1.
33
55
55
66
30
1.
- 0.
1.
0.
1.
3
8
2
4
0
SI
TI
FE
CD
PB
26.
11.
30.
32.
25.
00
00
40
50
50
CONCENTRATION 7. ERROR
ACTUAL MEASURED
26.19+- 1.32 0.7
11.04+- 0.56 0.4
30.5S+- 1.55 0.6
32.73+- 1.66 0.8
25.76+- 1.30 1.0
181/95-6
GA STANDARD QS116
EL
SI
TI
FE
CD
PB
CONCENTRATION 7. ERROR
ACTUAL
26. 00
11. 00
30. 40
32.50
181/95-10
QA STANDARD QS116
EL CONCENTRATION
7. E==:OR
MEASURED
26.
11.
30 .
32.
14+-
00+-
69+-
93+-
59+-
1 . 32
0.55
1.55
1.67
1.29
0.
- 0.
1.
1.
0.
6
0
0
3
4
SI
TI
FE
CD
PB
ACTUAL
26.
11.
30 .
32.
25.
00
00
40
50
50
MEASURED
26.
10.
30 .
32.
25 .
01+-
97+-
39+-
67+-
57+-
1.31
0.55
1.54
1 . 66
1 . 29
0 .- 0
- 0.3
- 0.0
0. 5
0 . 3
39
-------
TABLE 20. (Continued)
181/95-11
QA STANDARD GS116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
26.00 26.19.-i~ 1.32
11.00 10.98-* 0.55
30.40 30.22*- 1.53
32.50 32.74+- 1.66
SI
TI
FE
CD
PB
25.50 25.52+- 1.29
0.7
- 0.2
- 0.6
0.8
0. 1
SI
TI
FE
CD
PB
26.00
11.00
30.40
32.50
25.50
181/95-15
QA STANDARD OS116
EL CONCENTRATION 7. ERROR-
ACTUAL MEASURED
26.37+- 1.33 1.4
10.99+- 0.55 - 0.1
30.34+- 1.53 - 0.2
32.98+- 1.67 1.5
25.89+- 1.30 1.5
181/95-12
QA STANDARD QS116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
181/95-16
QA STANDARD GS116
EL
SI
TI
FE
CD
PB
26.
11.
30.
32,
25.
00
00
40
50
50
26.
10.
30.
32.
25.
52+-
96+-
54+-
97+-
69+-
1
0
1
1
1
.34
ejej
.54
.67
. 29
->
- 0.
0.
1.
0.
0
**!
4
4
7
SI
TI
FE
CD
PB
i-i'_- 1
26
1 1
.30
^>b?
oc;
fe-o'
'.'I-1U
.00
.00
. 40
. 50
.50
CONCENTRATION 7. ERROR
ACTUAL MEASURED
26.36+- 1.33 1.4
11.00+- 0.55 0.0
30.78+T 1.56. 1.3
32.62+- 1.66 0.4
25.77+- 1.30 1.1
181/95-13
QA STANDARD 08116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
SI
TI
FE
CD
PB
26.
11.
30 .
^2.
25.
00
00
40
50
50
26.
10.
30.
W«I
^e?
_~< .
23+-
03+-
66+-
33+-
S3+-
1.
0.
1.
1.
1.
32
c-(c^
erje;
67
30
0.
- 0.
0.
1.
1.
9
6
9
0
3
181/95-17
QA STANDARD QS116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
26.76+- 1.35 2.°
10.93+- 0.55
30.61+- 1.55
32.74+- 1.66
SI
TI
FE
CD
PB
26. 00
11. 00
30.40
32.50
25.50 25.67+- 1.29
0.6
0.7
0. 8
0.7
181/95-14
QA STANDARD QS116
EL
SI
TI
FE
CD
'PB
CONCENTRATION
ACTUAL MEASURED
26.4A+- 1.33
10.95-r- 0.55
30.74+- 1.55
32.88+- 1.67
26. 00
11 . 00
30. 40
32.50
25.50 25.°!+-
'/. ERROR
1.7
-0.5
1. 1
1.2
1.6
l'Sl/95-18
QA STANDARD QS116
EL
SI
TI
FE
CD
PB
CONCENTRATION
ACTUAL MEASURED
26 . 69+- 1 . 34
11.04+- 0.56
80.67+- 1.55
32.87+- 1.67
25.84-1 1.30
26 . 00
11.00
30.40
32.5
7. ERROR
2 . 7
0.4
O.'r'
1.1
40
-------
TABLE 20. (Continued)
131/95-20
QA STANDARD OS 116
EL CONCENTRATION 7. ERROR
ACTUAL MEASURED
SI 26.00 26.75+- 1.35 2.9
TI 11.00 10.S1+- 0.55 - 1.7
FE 30.40 30.17+- 1.52 - 0.8
CD 32.50 32.70+- 1.66 0.6
PB 25.50 25.42+- 1.23 - 0.3
41
-------
REFERENCES
1. Cooper, J. A. and Watson, J. G., Jr., "Receptor Oriented Methods of Air
Particulate Apportionment", APCA Journal, 30, No. 10, Pgs 1116-1125
(October 1980).
2. Houck, J. E., Core, J. E., and Cooper, J. A., "Source Sampling for
Receptor Oriented Source Apportionment" NEA, Inc. 8310 S.W. Nimbus Ave.,
Beaverton, Oregon 97005.
3. Houck, J. E., Cooper, J. A., and Larson, E. R., "Dilution Sampling for
Chemical Receptor Source Fingerprinting", Paper 82-61M.2 presented at the
75th Annual Meeting of the Air Pollution Control Association. New
Orleans, LA. June 20-25, 1982.
42
-------
APPENDIX A
SOUTHERN RESEARCH REPORT
ON EVALUATION OF NEA
DILUTION SOURCE-SAMPLER
SORI-EAS-83-201
Contract Number 68-02-3118
Technical Directive 139
FINAL REPORT
DEVELOPMENT AND EVALUATION OF DILUTION PROBES USED FOR
SAMPLING TO DETERMINE SOURCE SIGNATURES
Joseph D. McCain
Ashley D. Williamson
Southern Research Institute
2000 Ninth Avenue, South
P.O. Box 55305
Birmingham, Alabama 35255-5305
March 10, 1983
Roy L. Bennett, Task Officer
Environmental Sciences Research Laboratory (MD-46)
Research Triangle Park, North Carolina 27711
D. Bruce Harris, Project Officer
Industrial Environmental Research Laboratory (MD-62)
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Project 4181-69 FR
43
-------
INTFCDUCTION
Source apportionment studies based on chemical element balance tech-
niques require elemental composition signatures for the sources involved. '2
Ideally, the same, or similar, sampling methodologies would be used in ob-
taining source samples as those used in obtaining samples from the ambient
air. NEA, Inc., designed a sampler for this purpose which uses a slightly
modified ambient air "dichotomous sampler" to provide source samples in two
size fractions (0-2.5 um and 2.5-10 lam) corresponding to those taken in the
ambient.3 The samples are obtained on the same' filter media used for ambient
sampling. The NEA system is illustrated in Figure 1. In operation, a sample
is withdrawn continuously from the stack (source) via the nozzle (1) and
probe (2) and conveyed via the flexible hose (3) to a dilution device (4).
In the dilution device the sample stream is diluted by mixing with a measured
flow of filtered ambient air'provided by the blower and filter (5). A por-
tion of the diluted stream is withdrawn via the inlet tube (6) to the di-
chotomous sampler (7).
This system has two major advantages over conventional sampling
methods for obtaining source signature analyses. First, the sample is ob-
tained with the same size fractionation method as is used in many ambient
air receptor studies; and second, the dilution process mimics to some extent
the processes which actually take place as the flue gases are discharged to
the atmosphere, including condensation of certain species which may be
wholly or largely in the vapor phase at stack conditions. The time available
for such condensation processes in the NEA system is, however, r-ather short
(one to two seconds) and consequently the mixing occurs more rapidly than in
the "real world". As a result of the short mixing time the final aerosol
properties may not be quite those of the actual plume. Nonetheless, samples
obtained with the dilution system are probably more similar with respect to
condensible components to those downwind in the plume than samples taken at
flue gas conditions.
The problem of most concern with regard to samples obtained with the
NEA system is the possibility of size dependent particle losses in its various
components. Losses could bias the size distribution of the samples obtained,
and, if the elemental composition of the particles emitted by a source was
strongly size dependent, the source signature derived from the sample might
not be valid. Southern Research Institute was asked to: (1) evaluate the
representativeness of samples taken using the system with regard to particle
size bias and (2) if such biases were a problem, to rectify them insofar as
possible, or (3) suggest alternative procedures for obtaining representative
samples. Two laboratory calibration studies of the system were performed
which revealed (1) substantial losses of .large particles from inertial effects,
and (2) other size-dependent losses which resulted from electrostatic charge
effects. The following sections detail the experimental procedures used in
carrying out the evaluation, the results of the tests, and our conclusions and
recommendations with regard to the use w? the system.
44
-------
SYSTEM OPERATION
In field operations the system is set up at the sampling location and
the velocity at the selected sampling point is measured. A nozzle and sampling
rate are selected for isokinetic sampling and a total flow of sarr.ple plus dilu-
tion air is selected to obtain the desired dilution factor. The probe and
hose are brought to operating temperatures by means of permanently wrapped
heating tapes and the dichotomous sampler is loaded with a pair of filters.
The probe is then inserted into the stack and sampling is begun. The sample
flow is set and monitored by means of the pressure drop from the nozzle tip
to the interior of the diluterlaboratory calibrations being used to establish
the relationship between the pressure differential and the sampling flow rate.
(The pressure differential used must include the velocity pressure of the gas
.stream at the sampling point. > The sampling rates and the total flow through
the diluter are adjusted by varying the fan speeds of the dilution air inlet
blower and the exhaust air blower. The total flow (sample plus dilution air)
is measured by means of a thermal anemometer located in the second half of the
main body of the diluter.
EXPERIMENTAL METHODOLOGY
System losses by particle size were examined over the range from 1.5 ym
to 15 urn by challenging the system in a series of tests with monodisperse par-
ticles generated using a spinning disk aerosol generator. The particles were
introduced to the system by sampling from a small (10 cm) diameter-wind tunnel
into which the probe end and sampling nozzle could be introduced. The gas
velocities in the tunnel ranged from 5 to 20 m/s, spanning the range commonly
encountered in actual field conditions. The test particles were made of
ammonium fluorescein, which forms dry, relatively hard, non-hygroscopic par-
ticles. System losses were determined by breaking the system down into its
component pieces and washing each internal surface with dilute ammonium
hydroxide. The amounts of fluorescein in the washes were then measured by
fluorimetry. In order to be able to account for all the aerosol sampled, a
modified hi-volume filter assembly was used at the exhaust end of the system
in addition to the blower as was shown in Figure 1. Washes of this filter
together with those from the system itself made a complete mass balance possi-
ble.
Investigation of electrostatic effects in the sampling system was not
planned as a part of the program, however, a charge neutralizer in the aerosol
generator failed after much of the testing had been completed, resulting in
dramatic increases in the losses (and much frustration in identifying the
cause of the sudden increase in losses over those which had previously been
measured)- A total of 16 calibration runs were made with the complete system
with neutral aerosols, 14 runs were made with the complete system with charged
particles, and an additional 11 runs were made with the nozzle, probe and hose
only to further characterize the electrostatic effects and look into the effec-
tiveness of inlet charge neutralizers for alleviating the electrostatic losses.
45
-------
41I1-404
Height approx
Diluter (pipe) diameter
Dilution path approx
Dichotomous inlet (pipe) diameter
Dilution ratio (typical)
Residence time
2 m
10.2 cm
3 m
0.64 to 2.54 cm I.D.
20:1
1-3 sec
Figure 1. NEA Dilution Sampling System. 1. Nozzle, 2. Probe. 3. Hose, 4. Diluter, 5. Blower
and Filter, 6. Dichotomous Sampler Inlet, 7. Dichotomous Sampler.
A6
-------
RESULTS OF THE EXPERIMENTS
TESTS WITH NEUTRAL PARTICLES
The results of the first series of tests, those involving the full
system and neutral particles, are summarized in Table 1 and Figures 2, 3
and 4. In this series of tests, particles ranging in size from 1.3 to 17 ur,
were used with sampling rates of 14 and 76 1/rnin and gas velocities from 8
to 17 m/s. A second, isokinetic sampler, consisting simply of a nozzle and
filter assembly, was operated in parallel with the NEA system to provide
reference values of the true concentrations of the test aerosols for compari-
sons with concentrations derived from the dichotomous sampler filters.
Very low losses were measured on surfaces within the diluter body
proper during this series (e.g. 0.7% at 10 ym, with similar, negligible
losses found for the body at the other sizes used). However, losses in the
nozzle, probe and hose were unacceptably large when the system was operated
under the initial protocol specified by NEA. The protocol called for very
high sampling rates (approx. 75 1/min) .and a three meter hose was used to
permit as much flexibility as possible in setting the equipment up in the
(usually cramped) sampling areas found at industrial sites. Under these con-
ditions, losses in the hose alone ranged from 45% to 2 ym to 99% at 15 urn as
shown in Figure 2. At the 75 1/min sample .flow,., the Reynolds number of the
flow in the hose and probe was approximately 8000, indicating that the flow
would be turbulent. Because particle losses are expected to be greater under
conditions of turbulent flow than in laminar flow, the sample flow was reduced
to 14 1/min. At this sampling rate the Reynolds number was reduced to about
1500.
One test was made at the reduced flow using 7 ym particles as the test
aerosol. Some reduction in the losses was obtained compared to the 75 1/mir..
value as is also shown in Figure 2. However, the reduction was not great
enough to make the system useful for particle sizes larger than about three
to five micrometers while satisfactory operation up to 10-15 ym as was needed
to support the "Inhalable Particulate" program. The nozzle losses remained
about the same as on the previous 75 1/min runs, the probe losses increased
somewhat (probably from increased settling at the lower flow), and the losses
in the hose declined significantly. However, losses in the hose were still un-
acceptably large.
Although the flow rate had been reduced, losses in the nozzle were still
high, and for gas streams having velocities in the range of 20 to 40 m/s, which
are commonly encountered in industrial gas streams, even larger nozzle losses
would be expected to occur. **' As an example, the Dso of a 4.75 mm gooseneck
nozzle sampling at isokinetic rates from a 40 m/s gas stream is about 1.5 ym.
A right angle precollector, developed at Southern Research to minimize nozzle
losses in sampling with cascade impactors, produces a moderately sharp, pre-
dictable particle cutoff diameter in the range of 10 to 15 urn at a sampling rate
of 14 1/min. Thus the use of the precollectcr would reduce particle losses at
the entry to the probe to acceptable levels under almost any sampling circum-
stances envisioned for the use of this system. For the conditions at which the
47
-------
r * * Hl«tl«* fl««
OO
1M1
wit
Wit
l/ 1*
l/io
Wio
t/ii
in
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Irwi Uii
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10.*
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SI. I
11. 1
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11. 1 :*.*
11.4 1 ~t
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w
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00
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i.i
t*p<*M4a
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)' IMM fepwtl^
»«00 I. pr.W.
I ( »M-1»(*|
1 < pOtlUU <
I ' dlcfcoiM..
-------
100
80
V)
1/9
O
ID
(J
cr
60
40
20
76 Ipm 14 Ipm
O NOZZLE
O PROBE
A A HOSE (10 FT)
O INLET TUBE
? DILUTERBODY
10
AERODYNAMIC PARTICLE DIAMETER,
20 30,
4 J 11-10 5
Figure 2. Percentage losses by particle size for systems components at sampling
flow rates of 76 and 14 Ipm using 10 foot hose.
49
-------
100
V)
Q
z
LU
O
LU
80
60
40
20
PRECOLLECTOR
§ ssg
O RIGHT ANGLE PRECOLLECTOR
D PROBE
A HOSE (5 FT)
^ DILUTER INLET TUBE & BODY
PROBE AND HOSE
1.0
10
TRUE PARTICLE DIAMETER, pm (p - 1.35)
20
30
figure 3. Percentage losses by panicle size for system components at a flow rate
of 14 Ipm using 5 foot hose.
-50
-------
1.00
0.80
<
tr
u
o
u
K
u
o
u.
o
z
o
H
u
cc
0.60
0.40
0.20
0.5
A 10 FT HOSE. 76 Ipm ISOKINETIC SAMPLING^
RIGHT ANGLE PRECOLLECTOR (RAPC)
O 5 FT HOSE, 14 Ipm ISOKINETIC SAMPLING
V THEORETICAL CONCENTRATION FRACTION
USING NON-ISOKINETIC SAMPLING
5 FT HOSE, 14 Ipm, 15.5 fpj NOZZLE
VELOCITY, 50 fp$ DUCT VELOCITY
MEASURED CONCENTRATION FRACTION
AT CONDITIONS OF THEORETICAL
NON-ISOKINETIC CASE
I
1.0
AERODYNAMIC PARTICLE DIAMETER,
20 30
4111-401
Figure 4. Fraction of duct concentration, corrected for dilution, at dichotomous sampler inlet
by particle size. I. 10 foot hose, 76 Ipm samp/ing rate isokinetic sampling. II. 5 foot
hose; 14 Ipm sampling rate, isokinetic sampling. III. 5 foot hose, 14 Ipm sampling
rate non-isokinetic sampling to compensate for losses. 5 foot probe used on all runs.
51
-------
evaluation was done, the precollector DSo was estimated to be 12.5 Urn on an
aerodynamic basis. During the remainder of the evaluations the "gooseneck"
nozzles were replaced with this precollector.
In order to further reduce the losses in the hose, a second hose with a
sliyhtly larger bore and a length of 1.5 m was substituted for the original
(both were of the same nominal bore size and were made by the same manufacturer).
Particle losses by diameter in the precollector, probe and hose when operated
with the revised setup and flow rate are shown in Figure 3. By both reducing
the sampling flow rate to 14 1/min., and reducing the length of the hose to
1.5 m, the losses approached acceptable levels, as illustrated in Figure 3.
However, samples obtained in this fashion would have still been significantly
depleted in the 5 to 10 Urn interval.
The net penetration, by particle size, to the plane of the-inlet of the
dichotomous sampler is shown in Figure 4 for each of the test conditions and
protocols previously described. By using the shorter hose, lower sampling
rate, and the precollector, the overall system penetration was improved from
the lower curve (I) shown in Figure 4 to the levels shown by the center curve
(II). However, a large bias still existed for particles in the upper end of
the size range to be covered, with losses approaching 70% at a diameter of
10 un. At this point it appeared unlikely that any further significant re-
ductions in the losses could be made by means of hardware modifications.
The possibility of compensating for the greater losses of larger particles
by sampling at anisokinetic conditions was then investigated. "If a nozzle lar-
ger than that required for isokinetic sampling at a given flow rate were used
then the larger particles would be oversampled with respect to the smaller ones.
Theoretical calculations of the effect of oversampling large particles through
nonisokinetic sampling showed a potential for compensating for the system losses.
The aspiration ratio, A, for nonisokinetic sampling as Belyaev and Levin1 give
A =
- l
v
(2
(2 + 0.62 v/W) St
w
where W = duct velocity,
v = velocity in sampling nozzle,
Stw = Stokes number of the nozzle, particle, duct velocity system,
Pd2w
18 n D
P = particle density (=1.0 for aerodynamic diameters),
n = gas viscosity,
d = particle diameter, and
D = nozzle diameter.
Figure 4 also shows, as curve (III), the product of the measured penetration,
curve (II), and the theoretical aspiration ratio (A) for W = 15 m/s, v = 4.65
m/s, and D = .794 cm. The potential for loss compensation is clearly evident.
Two sar.ple runs were made using 10 ym particles under the conditions for
which curve III was calculated with results as shown in Figure 4 also. As show:
52
-------
in Figure 4, the measured values fell within +/-10* of the theoretical
predictions at this particle size.
Further verification of a revised sampling protocol which incorporated
the anisokinetic compensation scheme was desired; however, a requirement for
immediate use of the system in a field program halted further testing for a
period of several months.
RESULTS OF SAMPLING CHARGED PARTICLES
The NEA dilution sampler was returned to Southern Research for further
evaluation following modifications to the system and a period of field use.
Most of the modifications were related to splitting the diluted flow so that
simultaneous operation of two dichotomous samplers would be possible. The
primary purposes of this second round of calibrations were (1) to determine
whether the introduction of additional bends and a reduction in the diameter
of the diluter piping following the flow split would cause significant losses
and (2) to demonstrate that the two dichotomous samplers received similar
samples. A secondary goal was to evaluate the effectiveness of the anisoki-
netic sampling scheme suggested as a method for compensating for particle
losses in the system upstream of the -dichotomous sampler.
Initial tests of the modified system revealed increased losses in vir-
tually every part of the system compared to those of the earlier tests. Very
high losses were now found in the flexible hose which connects the diluter
to the probe. Examination of the hose revealed that it had been overheated
during a field -sampling run, resulting in partial closure of the tubing and
the creation of multitudinous fingerlike projections into the gas stream. At
this point work was suspended until a duplicate hose could be obtained from
the manufacturer.
After replacing the hose, subsequent runs produced data that showed
losses that were less than those found with the bad hose but still much higher
than those measured in the original evaluation. Figure 5 illustrates the data
taken with the modified system, increased losses were found in the probe, hose
and diluter, including the front end of the diluter and the first bend. Except
for the replacement of the damaged hose, it was presumed that none of these
components had been modified since the earlier laboratory testing. Electro-
static effects were suspected since the greatest increases in the losses
occurred in the non-conducting PVC and teflon portions of the train and did
not seem to be related to inertial deposition in bends.
The data from calibration trials at a number of particle sizes are sum-
marized in Table 2. Particle deposition as a percentage of the material reach-
ing the component is plotted for the probe and hose in Figure 5. Table 2 in-
cludes the amounts of material collected by the various surfaces, the percen-
tages of the material arriving at each part of the train that was retained by
it, the sampling efficiencies of the dichotomous samplers from the diluted
streams, and comparisons of the measured and theoretical biases resulting
from anisokinetic sampling. Larger anisokinetic biases were intended but
were not obtained because the actual flows used were higher than intended as
discussed below. The dichotomous samplers were found to obtain practically
identical samples at near 100% sampling efficiency from the diluted stream.
53
-------
Table 2. HE* Dilution System IVr I f.rmjM.-e With rharqrd AcroKnl »t A S«n,ilin.
1696954 '.',16
66.71 75. -11
406475 28545
2B.94 127.65
496950
24.04
54917
11.16
48)129 15950
26.41 40.70
511575 10415
J6. 6B 74.1!
916192 41410
18.19 9V 16
Hl'lht
III i:liot
Hl.li/ lilter
1 Ol Catrh/
Theo, \ Pent*.
4065 817062
55.16 20.77
9410 960000
lll.l" 14.56
157nlJ5
70. ft
417160
6.72
25990 1104812
67. II 11. M
16700 1)11025
'11.61 14. in
r
U7'.0 1401800
80.45 10.29
Prob«-
I'ltot Run
Total Of|t» p Tim
Catrh In. wr . Kin.
4n?'I465 .2 60
15I.J-.00
1 . ».'>F7 .2 60
15r.IX>OO
Nominal
i'luv
LPM
14.00
12.70
14.00
12.70
14.00
12.70
16.10
12.70
9.10
12.70
14.00
11.80
14.00
11.80
I'm!,. ,1-1. Cone.
Flow HI A* /
LPM mi
(14.001 18772)
4176
114.00) (mil)
952)
(14. no) 191691
5700
116.00! (1041)
1740
26.61 6697
1692
11.00 419B
5012
il.no 6912
5014
Cons.
Bat 60 1
»**.«a./
Thca.
12.09)
11.521
(1.61)
(2.421
l.B!
1.69
0.95
1.27
1. IB
1.27
flatbed on probable flow.
)~ Beit estimate of uncerttin v«|ue.
-------
Table 2 IConfd.)
Part.
Pi..
Pun Micron
9NEH S
9 KEF
IONEA 5
10MT
IIHEA S
imcr
I2NCA S
I2HEF
11NEA 1
1 1KF.F
14NEO I.S
14REF
I5NEA I.S
ISRXF
Pre-CDl
C«tch/
1675000
)8. 81
2206000
41.81
117)950
I). 92
1570000
44.64
140500
11.11
64278
17.11
)1975
8.14
Prolx-
f.'jlch/
4275000
16. I1)
T.OOOO
7f. . 6O
55 1000
17.15
56)550
28.95
52500
4.77
7950
2. 55
10450
2.80
Hot*
Catch/
510000
21.94
56OOOO
27.06
78OOOO
W.97
560000
40.48
292SOO
27.88
120811
19.81
125000
14.46
Ol luler
Catch/
124660
1.40
261121
11. 10
2)9591
11.78
1901 BO
21.10
187217
24.75
622B6
14.10
41914
17.64
Iftl
Dlrhnl
Catch/
% Of
18240
12H.42
KI7'.0
04. (. 1
1742%
flr, . in
20150
109. K
15400
92.16
45'.]
129.98
4214
11.14
HI. ho I
Cut ch/
\ of
444'.»
100.44
11400
14.7".
It'll)
Rh.Hl
20254
111.51
15750
91.71
1550
105. 11
1B84
6'.l.*>r.
filter
Catch/
1416160
)4.2I
II 84 400
71. M
142497'.
17.H7
592825
16. H6
5)8168
4). 11
112274'
29. HR
1B7750
40.11
Tul.il
4IK.2IO
147OOOO
502'.f.7 1
1 VISOftO
44410211
1'. 40(100
1516959
1007500
1242055
rtfiooo
I7M24
115900
407207
99175
ritnt Run
Delta r Tl«e
.2 60
.2 60
.1 60
.4 60
.2 68
.2 BO
.2 70
Niminal '
Flow
14.00
11. 80
14.00
II. nn
7.00
11.80
28.00
11.80
14.00
11.80
14.00
11.80
14.00
n. ao
Pri^.Al'le Cone*
Flow HE*.'/
11.00 7180
2076
Jl.OO 2S18
1970
21.11 1174
2|7r.
46.67 1256
142)
11.00 554
486
11.00 142
12)
11.00 176
120
Cbnc.
Ratio:
1.05
1.11
1.29
1.17
1.46
1.65
0.88
0.91
1.14
1.08
1.16
1.02
1.47
1.02
Based on probable flow.
-------
so
40
30
20
10
PROBE
A HOSE
0 DILUTER
I I I
2 345
PARTICLE DIAMETER. Mm
6 7 8 9 10
Figure 5. Probe, hose, and diluter tosses by particle size for modified dilution system.
Charged particles at ~-33 Ipm samp/ing rare.
-------
At this point the diluter was returned to N2A because it was needed
for a field program which they had scheduled. The replacement hose was re-
tained and a substitute probe was fashioned from a length of stainless steel
tubing of the same ID as that of the NEA probe. A series of experiments
were then carried out to look into the possibility of electrostatic effects
causing the increase in losses as compared to the first series of tests.
Measurements of the net charge/mass ratio showed that the particles
carried a high unipolar charge at the inlet to the sampler while those which
exited the hose carried no detectable net charge. A series of paired runs
were then made in which tests were made with a Polonium 210 charge neutralizer
mounted on the probe inlet nozzle alternating with duplicate tests without
the neutralizer. The results of these tests are given in Table 3. Losses
by particle size for the probe and hose, with and without charge neutraliza-
tion, are shown in Figure 6. In comparing Figures 3 and 6 it is apparent
that the differences in losses between the first evaluation and the second
were indeed the result of electrostatic effects. The losses measured in the
tests made with the charge neutralizer agree with the results from the tests
of the original, unmodified diluter.
The severe charge effects in the second test series were found to have
been caused by the failure of a Krypton 85 charge neutralizer which is an inte-
gral part of the aerosol generator. Evidently the tube containing the Krypton
gas developed a leak in the time between the two tests, resulting in the pro-
duction of a highly charged aerosol by the generator during the second test
series. In addition, the original evaluation was carried out in June when
the air in the laboratory was relatively moist while the second test series
was done in November when the air was drier. The lower humidity may have also
played a role in the charge effects.
FLOW MEASUREMENT
The tests conducted with the diluter in the second round of calibrations
were all carried out with the same mechanical setup and under the same operat-
ing conditions as in the previous tests with the exception of the diluter modi-
fications. The pitot-to-diluter pressure differential was set at the same
value used in the previous tests in order to presumably reproduce the sampling
flow rate that had been used in the earlier calibrations. The sampling nozzle
was selected to produce an anisokinetic sampling condition which would theo-
retically result in over-sampling large particles by approximately the amounts
required to make up for the anticipated losses in the precollector, probe and
hose (approximately 2.5X at 10 um), A reference isokinetic sampler was run in
parallel to provide data on the true particle concentrations. The results of
the tests revealed that the theoretical and measured sampling biases did not
agree well, contrary to previous experience. Further, too large a fraction cf
the particles entering the nozzle were retained by the precollector. The mea-
sured precollector efficiencies fell in line with what would have been expected
for flow rates about twice those at which the system had been set up to run
(approximately 33 1/min veirjus 14 1/min) . If the higher flows indicated by the
precollector performance were used in calculating concentrations, the discrepan-
cies between the measured and predicted sampling biases largely vanished.
Subsequent conversations with NEA personnel revealed that the fittings used
57
-------
Table 3. Hose and Probe Losses At 14 ipm With Charged and
Uncharged Particles
Rur.
16
17
18
19
20
21
22
23
24
25
26
27
Part.
Dia.
Micron
5
5
5
5
3
5
C
5
2
2
7
7
Pre-Col
Charge Catch/
Neut. % Loss
139860
30.91
135000
19.14
161250
33.70
77500
19.95
X 177500
13.42
55000
30.54
X 34000
8.13
X 105000
21.35
X 4160
4.69
15330
7.44
X 504000
34.40
258000
36.66
Probe
Catch/
% Loss
28600
9.15
54375
9.54
61000
19.23
38000
12.22
125000
10.91.
31500
25.19
37500
9.76
48000
12.41
4080
4.83
1820
0.95
162500
16.91
51333
11.51
Hose
Catch/
% Loss
117500
41.37
228384
44.27
93757
36.59
110383
40.45
130345
12.77
31069
33.20
39238
11.32
43725
12.91
2388
2.97
56836
30.10
142280
17.82
152525
38.66
Filter
Catch/
% Per.e.
166500
36.80
2875CO
4C.77
1625CO
33.96
ie:5C'C
41.84
89:::o
6-.2S
625JG
34.71
3:75:0
73.52
295300
59.99
73000
88.01
132000
64.08
656250
44.79
2420CO
34.38
Total
Catch
452460
705259
478517
388383
1322845
180069
418238
491725
88628
205986
1465030
703858
Run
Time
Min.
(20)'
38
(30)
30
50
30
30
30
40
60
30
(15)
- Best estimate of uncertain value.
58
-------
50
40
30
§
s.
V)
V)
O
20
10
I I I I I I
A HOSE \
PROBE f
O HOSE )
O PROBE J
WITHOUT CHARGE NEUTRALIZER
WITH CHARGE NEUTRALIZER
O
a
P
I |_
8
I I 1
6 7 8 9 10
2 34
PARTICLE DIAMETER,
Figure 6. Probe and hose losses by particle size for charged and neutralized particles at a
sampling rate of 14 Ipm.
59
-------
in attaching the hose to the probe and diluter had been changed in order to
eliminate some minor flow restrictions. The elimination of the restrictions
would have the effect of causing an increase in flow for any given probe/hose
pressure drop. Attempts were made to measure the flow pressure drop charac-
teristics of the system; however, perturbations introduced by the available
calibration devices interfered too much to make the data meaningful. The
operating pressure differential between the probe tip and the diluter is
only about two to five mm of water The previous flow calibrations were made
using a venturi-based mass flow meter belonging to NEA which was assumed to
produce no permanent pressure drop. Thus in the tests with neutral particles,
the actual flows may have differed somewhat from the nominal values quoted as
a result of similar, but probably smaller, errors in setting the sampling rates,
CONCLUSIONS AND RECOMMENDATIONS
The tests of the system in its original form revealed that serious
biases would occur with respect to the size distribution of samples obtained
with the system. Mechanical modifications were made which, together with a
reduction in sample flow rate, reduced the losses substantiallybut the re-
duction in losses was not sufficient for truly satisfactory field application.
However, compensation for mechanical losses was found to be possible through
oversampling of the larger particles at the probe inlet. This compensation
can be achieved by sampling anisokinetically using an oversize inlet nozzle.
Reproducibility of the flow-pressure drop characteristics of the probe
and hose have been found to be poor. The use of this pressure drop for setting
the sample flow does not appear to be accurate or reproducible. This is par-
ticularly true in light of our experience with the damaged hose. Even in the
absence of such permanent damage, minor distortions and "kinks" in the hose
can result in significant flow errors. Therefore it is recommended that a
venturi type flow meter be installed at the probe exit or diluter inlet so
that a more reproducible and certain flow measurement can be made. Thermostat-
ic control of the hose heater is also recommended so as to avoid the over-
heating problems to which the hose supplied by NEA had been subjected.
Although no solution can be suggested at present, the problem of elec-
trostatic losses in the hose and diluter can be serious. One can certainly
expect charged particles to be present when sampling the exhausts of elec-
trostatic precipitators and it has also been noted that very high, unipolar,
charge levels can be present on particles in the exhaust of a boiler, upstream
of any control device.8 The possibility of strong, size dependent, biases
in the samples obtained using the apparatus as a result of particle charge
should always be considered. The data do suggest that the electrostatic
deposition problems may largely be avoided if only conducting components are
used throughout the system.
The diluter inlet pipe to which the hose is connected has no provision
for heating. If condensibles are to be properly handled by the system, this
pipe should be heated in order to avoid losses by condensation on the walls of
the pipe.
60
-------
The samples obtained by the two dichotoraous samplers in the modified unit
were found to ba reasonably like one another and to fairly represent the con-
centrations of particles in the diluted stream. A few samples were taken of
redispersed flyash in a simulated field environment using a larger wind tunnel
than that used in performing the calibrations. In these runs it was noted that
the particles in the.larger (2-10 Um) size fraction did not adhere at all well
to the membrane filter. Any slight jostling of the filters or breezes passing
over them could, cause much of the sample to be lost. Thus special provisions
may be necessary for handling the coarse fraction filters when aerosols similar
to this are sampled.
With the exceptions of the potential problems arising from electrostatic
charge effects, and the possible problems related to retaining the retention
of some types of particles by the filters, the system appears to provide a
reasonable method for collecting samples for defining source signatures.
61
-------
REFERENCES
1. Watson, John G. and Judith Co Chow. An Overview of Source-Receptor
Source Apportionment. In: Proceedings of the 74th Annual Meeting of
the Air Pollution Control Association, Sessions 58 and 64, Philadelphia,
Pennsylvania, June 1981.
2. Core, John E. and Thompson G. Pace. Receptor Models - How Great Thou
Art!(?). In: Proceedings of the 74th Annual Meeting of the Air Pollution
Control Association, Sessions 58 and 64, Philadelphia, Pennsylvania,
June 1981.
3. Houck, James, John A. Cooper, and Eric R. Larson. Dilution Sampling For
Chemical Receptor Source Fingerprinting. Presented at the 1982 Annual
Meeting of the Air Pollution Control Association, New Orleans, Louisiana,
July 1982.
4. Knapp, K. T.. The Effects of Nozzle Losses on Impactor Sampling.
In: Proceedings, Advances in Particle Sampling and Measurement,
W.B. Smith, Editor. U.S. Environments T Protection Agency Report EPA
600/9-80-004, January 1980.
5. Felix, L.G., and McCain, J.D.. Errors in Recovered Size Distributions
Caused by Impactor Sampling with Bent No.zzles. Presented at the 74th
Annual Meeting of the Air Pollution Control Association, Philadelphia,
Pennsylvania. Paper 81-7.4 (1981).
6. Felix, L.G., D.H. Hussey, and J.D. McCain. Development, Design, And
Operation Of A Cascade Impactor To Collect Aerosol Samples For Wavelength
Dispersive X-Ray Fluorescence Analysis. EPA Contract Number 68-02-2992,
U.S. Environmental Protection Agency, Research Triangle Park, North
Carolina, December 1982. 44 pp.
7. Belyaev, S.. and Levin, L.M.. J. Aerosol Sci. _5, 325-338 (1974).
8. Felix, L.G., Personal communication.
62
-------
APPENDIX B
DILUTION SOURCE SAMPLER (DSS)
Standard Operating Prodedure
1. Measure stack gas velocity at point of sample collection with a pitot
tube/manometer system.
2. Measure stack temperature at point of sample collection with a bi-metal
thermometer or other temperature measuring device.
3. Estimate gas viscosity using the empirical equation:
0.068T + 7.8'
where n is in micropoises.
4. Calculate the Stokes number for the available sampling nozzle diameters by
the equation:
-
w i8nD*
where St is the Stokes number,
p is the particle density (p=l g/cm3 since aerodynamic
diameters have been used in the calibration tests
and calculations) ,
n is gas viscosity,
d is the particle diameter (10 u for this calculation) ,
D is the nozzle diameter (1/8", 3/16", 1/4", 5/16", 3/8"),
and
w is the stack velocity .
5. Referring Co Table A-l, obtain the sampling nozzle linear velocity
corresponding to the volumetric velocity of 14 1pm for each sampling
nozzle diameter. (Approximately 14 1pm is required Co maintain the
correct 10 u cut-point in the preseparator.)
63
-------
TABLE A-l. LINEAR VELOCITIES AND PRESSURE DIFFERENTIALS. CORRESPONDING
TO VOLUMETRIC FLOWS AND NOZZLE DIAMETERS
Nozzle Diameter
(inchea)
i/a
3/16
1/4
5/16
3/8
12 1pm
MPS FPM AP(in)
25.1 4940 1.6
11.2 2204 0.80
6.33 1246 0.27
4.04 795 0.20
2.81 553 0.15
14 1pm
MPS FPM AP(ln)
29.2 5746 1.95
13.1 2578 1.15
7.37 1450 0.40
4.71 927 0.25
3.27 643 0.17
16 1pm
MPS FPM AP(in)
33.6 6612 2.6
15.0 2952 1,35
8.44 1661 0.52
5.39 1061 0.30
3.75 738 0.22
-------
6. Calculate the aspiration ratio for each nozzle using the following
equation:
(2 + 0.62 v/w) St
A -
+ (2 + 0.62 v/w) St j'
where A is the aspiration ratio. An aspiration ratio of 2.2
has been determined to provide the best non-lsokinetic
sampling velocity co oversample larger particles and
compensate for their potential loss in the dilution
. sampling system,
w is the stack velocity,
7 is the nozzle velocity, and
St is the Stokes number.
w
7. Select the nozzle diameter which best approximates an aspiration ratio
of 2.2 at 14 1pm. A compromise between the preseparator cut-point and
the aspiration ratio may be necessary. The linear velocity of the
sampling nozzles at 12 and 16 1pm are given in Table A-l should a minor
adjustment in the experimental aspiration ratio be required. _
8. Install correct sampling nozzle as determined from steps 1-7 and install
a dichotomous inlet pipe to provide internal isokinetic conditions
(17mm ID for 1.2 m/sec). Record nozzle and inlet pipe diameters chosen.
9.. Assemble pre-cleaned dilution sampling chamber.
10. Connect total stack pressure sensor to probe.
11. Insert probe and pressure sensor into stack a measured distance from the
stack wall. Record distance and identify port (e.g., south port).
12. Plug in probe, connecting hose and inlet pipe heating tapes. Allow a
minimum of 15 minutes warm-up time prior to sampling.
13. Install a clean glass fiber filter into the inlet 8" x 10" filter housing.
Install a clean, preweighed numbered quartz filter into the outlet 3" x 10"
filter housing. Record the quartz filter number.
14. Install 37 mm filters into dichotomous sampler units. Record filter numbers.
Return numbered petri dish containers to filter field transport box.
15. Refer to Table A-l to select correct pressure drop for the desired nozzle
flow rate.
65
-------
16. Simultaneously adjust the pressure drop between the dilution chamber
and the stack and the total gas flow within the dilution chamber
with variable transformers connected to an inlet blower and an outlet
(vacuum) blover. The pressure drop is given by the equation:
AP - P + 4 P V - P , ,
3,3 KS S d,3
where, P is the static pressure within the stack,
3,3
p is' Che density of gas within the stack,
V is the linear velocity of gas within the stack, and
P, is the static pressure within the dilution chamber.
0,3
Adjust the linear velocity within the 4 inch (10.2 cm) dilution chamber
eo 1.2 m/se>_ -hich corresponds to a dilution ratio of approximately 42:1
with a stack sampling velocity of 14 1pm.
17. Turn-on dichotomous samplers. Adjust the total flow to 16.7 1pm and the
coarse flow to 1.67 1pm using previously calibrated rotometers. Note
start time on dichotomous sampler timers.
18. Readjust the pressure drop and dilution chamber gas flow described in
step 16 after dichotomous samplers are running.
19. Disconnect thermal anemometer and install plug.
20. After 15 minutes of sampling time, measure the ambient temperature, dilution
chamber temperature and re-measure stack temperature. Record temperature
data. Re-install thermal anemometer and adjust the pressure drop and the
dilution chamber flow if necessary. Disconnect thermal anemometer
and Install plug.
21. Estimate sampling duration from previous data on stack particulate loading,
the experimental sampling dilution ratio and the mass of particles which
is desired to be collected. The desired mass for Teflon and quartz filters
is between 0.5 and 2 mg and for Nuclepore filters between 0.3 and 0.3 tag.
22. Visually inspect dichotomous filters intermittently to estimate the
amount of mass collected and to estimate the length of time which
sampling shall continue. Also readjust flow rates if necessary at these
intermittant inspections.
23. When sufficient sample is collected, measure and record the pressure drop
between, the dilution chamber and stack, the velocity in the dilution
chamber and the dichotomous sampler rotometar readings. Then turn off
dichotonous samplers and immediately replace loaded filters into their
original labeled petri dish containers. Record dichotomous sampler
timer readings. Measure and record ambient, in-stack and dilution
chamber temperatures. Record stop time.
66
-------
24. Three replicate sample runs will be made of each filter loading
configuration. Filter loading configuration A will have Teflon filters
for collection of both fine and coarse particles in one dichotomous
sampler and quartz filters for collection of both fine and coarse
particles in the other. Filter loading configuration B will have
Teflon filters for collection of both fine and coarse particles in one
dichotomous sampler and a Teflon filter for collection of fine particles
and a Nuclepore filter for collection of coarse particles on the other.
25. After all runs are completed at a given stack, the 8" x 10" quartz outlet
filter will be removed, folded and placed into its glassine-lined,
numbered envelope and the dilution chamber will be dismantled, returned
to the staging area and thoroughly cleaned prior to subsequent use.
67
-------
NEA,INC
DILUTION SAMPLING FIELD DATA SHEET
Start
Dichotomous Sampler (R)
timer reading
Dichotomous Sampler (L)
'timer reading
Serial #
Serial #
Start time
AP (dilution chamberstack)
Inner velocity dilution chamber
Distance inlet from stack wall
Sample port description
Stack temperature
Stack velocity
(calculations on reverse side)
Dichotomous Sampler (R) Rotometer Readings
total coarse
Dichotomous Sampler (L) Rotometer Readings
total __ coarse
Dichotomous Sampler (R) filter ID's, Filter type
fine coarse fine
Outlet Quartz 8" x 10" filter ID
Inlet nozzle diameter
Inlet nozzle volumetric velocity
Dichotomous Sample inlet ID
Comments:
Dichotomous Sampler (L) filter ID's, Filter type
fine coarse fine
coarse
coarse
Inlet nozzle linear velocity
________ Aspiration ratio
Page 1 of 3
68
-------
15 Minutes after Start-up and Intermittent Inspection
Time
Stack temperature
Ambient temperature
Dilution chamber temperature
Intermittent inspectioncomments (include time)
Page 2 of 3
69
-------
StOT
Dichotomous Sample (R) AP (dilution chamberstack)
timer reading
Linear velocity dilution chamber
Dichotomous Sample (L)
timer reading Ambient temperature .
Stop time Dilution chamber temperature
Stack temperature
Dichotomous Sample (R) Rotometer Readings
total coarse
Dichotomous Sample (R) Rotameter Readings
total coarse
Comments:
Page 3 of 3
70
-------
APPENDIX C
STANDARD OPERATING PROCEDURE
ENERGY DISPERSIVE X-RAY FLUORESCENCE ANALYSIS OF AIR FILTERS
1. General Discussion
1. Analytical problem: Analysis of aerosols deposited on membrane
type filters for the elements listed in Table A-2. Typical
atmospheric concentrations and ranges are indicated in Figure' A-4.
2. Principle: Atoms in the sample are excited from their ground
state to-higher energy levels by x-radiation from an X-ray tube.
These excited atoms emit discrete energy X-rays as they return to
their normal ground state energy level. The energy of these
emitted X-rays is characteristic of the emitting element and is used
to qualitatively identify the element while the number of observed
X-rays, which is proportional to the number of atoms, is used to
quantitatively determine a specific element's concentration
through a direct comparison with standards.
3. Interferences: There are a number of potential spectral interferences
possible with EDXRF because of its low resolution relative Co the
number and spacing of possible X-ray lines. The elements subject co
potential spectral interferences in normal ambient aerosols, along
with the corresponding interfering elements and correction factors are
listed in Table A-3. Correction factors, F. , are determined by
im
analyzing single element standards of elements i and applying the
formulas
V-A-
i
where F. « the fraction of counts due to element i that interfere
with the counts for element at
N background subtracted counts in region of interest a
u
H background subtracted counts in region of interest i
(Rev. August, 1981)
71
-------
TABLE A-2. X-RAY FLUORESCENCE
MINIMUM DETECTABLE CONCENTRATIONS*
(ng/cm2)
STANDARD ANALYSES*
Clenrac
U
Si
P
s
a.
t
c*
TI
7
Cr
Ma
F«
Hi
Cu
In
C*
i>
S«
Br
Kb
Sr
T
Zr
Pd
U
Cd
In
So
Sb
&*
U
HI
Pb
1
42
35
43
140
90
30
30
10
6
6
9
12
10
10
10
3
8
8
12
20
20
40
160
43
70
70
90
90
90
100
300
20
23
2
30
24
30
90
60
20
20
«
4
4
6
8
6
6
«
6
6
6
S
14
16
30
120
39
4«
30
60
60
60
360
360
16
20
3
30
18
23
70
43
13
13
3
3
3
5
6
i
3
3
4
4
4
6
10
10
22
84
22
H
36
44
44
44
260
260
11
14
4
18
12
IS
47
32
U
11
3
2
2
3
4
3
3
3
3
3
3
4
7
8
13
&0
13
24
23
30
30
30
180
180
8
10
5**
10
8
10
30
20
6
&
2
1
1
1
2
1
1
1
1
1
1
2
4
4
8
30
3
12
14
13
13
13
100
100
4
3
Thr«« »ijm« ine«rf«r«nc»-fr«« KDC for particulars d«poslc«4 on filters with 1 a;/ en2
such as Mucl«por« *od ion c«LluloM and caflos filears MDC "
* For scr»ceh«d s«flon filesrs
+ Cuacoa ujklysia for jpacific (luaau a- spaciai SDC's ivaiiabit upon r«qi»sc.
(Rev. August, 1981)
72
-------
FIGURE A-'iH
10s
K |03
W
h-
Ul
o I0a
-j ?
w r;
K I01
Ul
CO
19
O
'2
lO
IO-»
8
TYPICAL VALUE
flu
M
*0.
?
V
k
T
'*
n n
ATOMIC NUMBER
3
dO
-------
TABLE A-3. Potential Spectral Interferences
Element of Interest
Element of Interest
'im
Element
Mg
Al
Al
Si
Si
P
K
K
Ca
S
Cl
Cl
K
Ca
Ti
V
7
Cr
Mn
Fe
As
3r
Cu
Zn
Ga
Ga
HS
Hg
As
Se
Br
Se
Rb
Rb
Sr
Sr
Y
Y
Y
Y
Zr
Zr
Zr
Sb
Excitation Line
Condition
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
I
1
' 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
La
La
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Ka
Element
Br
Br
K
Br
Sr
Ca
' Ca
Cd
K
Pb
S
Pb
Cd
K
Ba
Ba
Ti
7
Cr
Mn
Pb
Pb
Ni
Cu
Zn
Pb
Pb
Br
Pb
Pb
Pb
Br
Br
Pb
Pb
Br
Rb
.Pb
Br
Sr
Sr
Pb
Br
Cd
Excitation Line
Condition
1
1
2
1
1
2
2
1
2
3
3
3
1
3
1
1
3
3
3
3
3
3
1
1
1
1
1
1
I
1
1
1
1
1
I
1
1
1
1
1
1
1
1
1
La
La
escape
La
La
escape
Ka
L8
KB
M
Ka
M
L8
KS
La
LS
KS
KB
KB
KB
La
L8
KB
KS
KB
La
La
Ka
La
La
LS
Ka
KB
LS
LY
KS
KS
LY
KS
KS
KS
I-Y
KB
KS
0.0098 ± 0.0003
0.176 £ 0.001
0.0047 t 0.0005
0.0028 ± 0.0003
0.285 £ 0.002
0.0137 £ 0.0009
0.0121 ± 0.0008
1.116 ± 0.006
0.0309 ± 0.0008
0.19 ± 0.02
0.026 £ 0.005
0.073 ± 0.002
0.401 ±0.003
0.070 ± 0.002
4.52 ± 0.04
2.38 ± 0.02
0.127 ± O.OU2
0.132 ± 0.002
0.130 £ 0.001
0.116 -±_0.001
l.li £ 0.01
0.014 ± 0.001
0.065 £ 0.002
0.0376 £ 0.0006
0.0149 £ 0.0004
0.060 £ 0.001
0.0033 £ 0.0002
0-.00063+ 0.00006
1.196 ± 0.005
0.007-6 £ 0.0004
0.0140 £ 0.0005
0.0012 £ 0.0001
0.156 £ 0.001
0.0107 £ 0.0004
0.0073 £ 0.0007
0.0008 £ 0.0002
0.170 £ 0.001
0.121 £ 0.002
0.0008 i 0.0002-
0.0025 £ 0.0003
0.166 £ 0.001
0.0088 £ 0.0009
0.0009 £ 0.0003
0.0245 £ 0.0008
(Rev. August, 1931)
74
-------
and
oF
im -
oN
oN,
where aF uncertainty in F
im
oN
tn
aN,
uncertainty in
uncertainty in N
Samples exhibiting chemical composition uncharacteristic of normal
ambient aerosols may require additional corrections.
4. Minimum Detectable Concentrations (MDC) on filters are determined
by the formula
MDC,
- 3
N,
where
MDC.,
Che mi
m detectable, concentration of element-i
M. - known concentration of element i
N. Net number of counts measured when element i is
analyzed under standard conditions
B. Number of background counts subtracted from total
counts in region of interest i to obtain N .
Table A-2 lists MDC's for 5 standard analysis conditions.
Background Subtraction: Most of the background counts in a region
of interest are due to the scattering of primary radiation from the
sample. The amount of this scattering depends upon the mass of the
sample presented to the primary excitation beam. A blank filter is
run under each excitation condition and the background in each region
of interest is linearly related to a high energy incoherent scatter
peak due to the primary radiation. The same scatter peak is
monitored on all loaded samples and the linear relationship is used
to estimate the background in the analyte line region of interest.
(Rev. August, 1981)
75
-------
2.
6. Precision and Accuracy: Count variations of less than 1% are typical
over 24 hour periods. Figure A-5 shows the variability of the QC filter
for the analysis of 630 filters over a period of 2 months (< ±1.5%).
All results are reproducible to within 12 when counting statistics are
not the primary source of uncertainty. The accuracy in terms of the
deposit on the filter is primarily limited by the uncertainties in the
standard values which are typically 52. Errors in the absorption cor-
rections for the low atomic number elements (Z<20) may approach the
same order of magnitude as sampling errors.
Apparatus
The x-ray fluorescence analyzer used for the analysis is an Ortec
TEFA III system. A block diagram of its major components is shown below:
X-Ray Tube
(Excitation)
Excitation Chamber
(sample presentation)
X-JUy Spectrometer
(Measurement at X-Ray
Intensity and Energy)
Computer U
(Quantitative Calculations) |
The primary function of the excitation system is to generate inner
shell electron vacancies which result in the emission of x-rays character-
istic of the sample elements. The TEFA system has a dual anode Mo/W
x-ray tube. Mo and Cu primary x-ray filters can be used to obtain
monochromatic excitation.
Air filters are presented to the excitation radiation and spectrometer
in an evacuated excitation chamber.
The x-ray spectrometer consists of a Si(Li) x-ray detector amplifier
and pulse height analyzer which measures the energy and intensity of the
characteristic x-rays generated in the above excitation procedure.
(Rev. August, 1981)
76
-------
2O
19
18
17
16
15
' i i | I I i i | 1 I i I | i i i » | i i r r | i i i i | i T-I t~|~i "|-T~I~ \ T i I i | I I I I | 1 T'l" i '| "' 'i~' "I l'~r-|
FIGURE A-5. X-RAY FLUORESCENCE QUALITY CONTROL DATA
IRON CONCENTRATION ON QUALITY CONTROL FILTER
(XRF-3)
Number Fillers Analyzed: 630
Maximum Deviation: QQOr»Q Q o ° Q r>' n r> O onnr>r
-U00 u 0»j u u
~L3.0%
r
»0°Q o°onoO°o OOOOUO0O"UIJ
0
u
in
IO 15 2O 25 3O 35
RUN NUMBER
4O
50
55
60
-------
3. Calibration
The instrument is calibrated with single element thin film vapor
deposited standards obtained from Micromatter Co., Eastaound, WA. , and
with multielement solution deposited standards obtained from Columbia
Scientific Industries, Austin, T2C. Particle standards obtained from
Columbia Scientific Industries are used for Al and Si calibration.
Plots of instrument response versus atomic number should yield smooth
curves, and are used to validate standard concentrations. The surface
concentration relevant to a specific excitation condition for each
standard element ia listed in the Standards Notebook.. The standards
are kepc permanently mounted in clean, closed containers and are labelled
with an 10 number.
Standard concentration values are entered into the computer and
stored on floppy disk, by the ORACL program MAKSTD. The instrument is
then calibrated by proceeding with a normal run, and using an "S" prefix
for each of the standard ID numbers. Details of software usage are in
the TEPA Software Notebook. Calibration should be .performed only by
supervisory personnel.
(Hav. August, 1981)
78
-------
4. Flowchart Summary
Filters from
storage
^^
*"^
Load filters
as per XRF
and place in case
holders
V
Load filters into TEFA
\
/
Start analysis program
and enter data from
XRF LOG SHEET
Data printout
\
<
Analysis
f *
Data QC
/
Transfer filters
TEFA to case
from
V
Unload filters from
holders to petri
dish as per XRF LOC SHEET
V
Filters to storage
Fill out
XRF LOG SHEET
(Bev. August, 1981)
79
-------
5. Operating Procedure
The TEFA operating manual should be reviewed before operating
Che instrument. One should be familiar wich the hazards of incorrect
operation and the safety systems of the TEFA. Only designated personnel
should operate the instrument and no procedures other than the ones
described here should be performed unless instructed otherwise by the
laboratory supervisor.
5=1 TEFA SCart-up
1. Obtain TEFA key from the standards cabinet and switch CONTROL POWER
to ON.
2. Press the SYSTEM POWER ON button.
3. Obtain the XR program disk from storage and insert in drive 0
(left hand drive).
4. Press the PWR button on the EEDS II control panel.
5. Adjust the MARKER joystick so chat elapsed time is displayed on
Che CRT.
6. Turn on che printer, sec to ON LIUE, and switch to 8 LPI. Advance
paper Co cop of page using che FORM ALIGN controls.
7. Press HV1 on the EEDS II control panel.
8. Press che DATA .ENTRY X-RAYS butcon. A data parameter is selected by
first pressing che RETURN key uncil che cursor is opposice che ~"
desired parameter, chen pressing che space bar. Valid entries are
displayed on che CRT. Sec TUBE VOLTAGE to 5.0 Kv and TRAY SIZE co 12.
9. Press che SYiTEM CONTROL STANDBY button. Make sure the excitation
chamber cover is closed.
10. After waiting 3 minutes, press che SYSTEM CONTROL ON button. This
turns on the x-rays. The 3 red X-RAYS ON lights in che RADIATION
section will come on, che graen X-RAYS OFF lighe will go out, X-RAYS
ON will flash on Che CRT and che red X-RAYS ON light in the SYSTEM
CONTROL section will flash. The excitation chamber cover must remain
closed whenever Che x-rays are being produced.
11. The TEFA should be allowed to warm up for 30 minutes before
' beginning analysis.
5.2 Filter Loading
1. Fill out an XRF LOG (Figure A-6) with PROJECT NAME, INITIAL, ID
numbers and particle size codes (S). If there are also customer
ID numbers, record them in Che comments column. ID numbers and
particle size codes axe obtained from che sample LOG Book. Record
the dace in che XRF column in che Sample Log Book for all samples
loaded. All 12 positions need not be filled. Position 1 nust be a
blank of che same type and preferably Che same manufacturing loc as
Che filters Co be analyzed. The blank ID must begin wich "B".
The lasc position must be a quality control standard. Obtain its
ID number from che laboratory supervisor.
(Rev. August, 1981)
80
-------
KTfiURK A-6. XKF LOG
PROJECT NAME
DATA DISK
DATE
TIME
ANALYSIS SEQUENCE
INITIAL:
LOAD
ANALYZE
UNLOAD
QA
oo
POSITION
5
0
10
11
12
ID
COMMENTS
-------
2. Filter loading is done in Che laminar flow hood. Turn the hood
blower and lights on and clean Che work surface with a Kaydry
towel and mechanol. Lay ouc a Kaydry towel in Che hood. Clean a
pair of forceps and che filcer loading block wich K-lmwipes and
nethanol and place on che couel. Clean an XRF sample case inside
and ouc and place in che hood. Ob Cain che filters Co be analyzed
from Che sample storage cabinet. Place Che filters Co be loaded,
a set of numbered filter holders, a box of Kimwipes, a mechanol
container, the XRF LOG and a pen in the hood. 'The filter containers
should be labelled wich their ID numbers.
3. Clean the filter holders with Kimwipes and mechanol. Pay particular
attention to surfaces which the filters will contact. Wear
disposable jloves to avoid excess contact wich methanol. When
finished cleaning che filcer holders, remove gloves and rinse hands
if gloves are of the calced variecy.
4. Select filcer holder 1,'place on Che filter loading block, and
remove che retaining ring. If che blank has already been loaded
from a previous run, select filcer holder 2 inscead of 1.
5. Select che filcer whose position number as indicated on che XRF LOG
corresponds co che filcer holder. Mote the condition of the filcar
and record any comments on che XRF LOG chat may apply co XRF analysis
such as uneven deposic, wrinkled filcer, wacar spot on filter, ace.
Filters wich loose deposits should not be analyzed.
6. Remove che filcer from ics container and place deposit side down
in Che filter holder. Use forceps and handle Che filcar only around
its perimeter. If che deposic is touched by che forceps, clean chem
before proceeding.
7, Replace che retaining ring so chat the filter is held in place -
without any wrinkles or other misalignment.
8. Place the numbered filcer holder inco che like numbered location in
the sample case and che filcer container in che proper numbered
location in che filcer container Cray. The blank filcer holder and
container can both be placed in che large section of the filcer
container Cray.
9. Repeat steps 4-8 for the remaining filters. The quality control
standard is permanently loaded and is"not put into the sample case.
10. Verify Chat che sample ID number co position number relationship is
correct. Each filter holder number ausc match ics position number
in the sample case. The ID number on each filcer container muse
correspond co ics position in the filter container tray exactly as
on the XRF LOG.
11. Place the filter container Cray on cop of the filter holders in che
sample case, put the XRF LOG in the sample case, and transfer co
Che TEFA.
12. Clean up che laminar flow hood.
(Rev. August, 1981)
82
-------
5.3 Analyzing Filters
1. Verify that TUBE VOLTAGE is 5.0 Kv and TOTE CURRENT is 1 uamp.
Press Che SYSTEM CONTROL STANDBY button. Make certain the red
X-RAYS ON lights are out and the green X-RAYS OFF light is on.
Never open the excitation chamber cover unless this is the case.
2. Life the excitation chamber cover to its open position.
3. Open the Simple case and place the filter container tray in the lid.
4. Transfer each filter holder in sequence to the like numbered
position in the TEFA sample tray. Make sure the seating is
proper by rotating the filter holder and align the holder so
that its indicating line points toward the center of the tray.
Close the sample case. If the standard is not already in
position, obtain it from the standard cabinet and place in position
on the sample tray.
5. Verify that all samples are correctly loaded in their designated
positions on the sample tray.
6. Make sure the excitation chamber gasket is properly seated and
close the cover.
7. Push the X-RAY PATH PUMP button. The pump will quiet down after
10-20 seconds if the chamber is properly sealed.
8. Press the SYSTEM CONTROL ON button. The red^ X-RAYS ON lights
will come on and the green X-RAYS OFT light will go out.
9. Select a formatted, zeroed disk and write the PROJECT SAME on the
dlslc label. Use a felt tipped pen. Record the data disk
number on the XRF LOG, as veil as INITIAL, DATE,
TIME, and ANALYSIS SEQUENCE. Obtain the analysis sequence numoer
from the laboratory supervisor. Insert the data disk into
drive 1 (right hand side).
10. Record the date, project, initial, and data disk number in the
TEFA Log Book.
11. Press the DATA ENTRY X-RAYS button to return to spectrum mode, then
press OPERATING MODE TERMINAL. Type "C" while holding down the
CTRL key. Type R ORACL . Type RUN XR . Enter data
as requested by the program and displayed on the CRT. If there are
less than 12 samples, simply press return when asked for the next
sample. Before verifying the particle size codes, check to see
that the X-RAY PATH VACUUM READY light is on. Sample analysis begins
when the particle size codes are verified and proceeds automatically
from sample to sample for each excitation condition.
12. When analysis is complete, indicated by 5 beeps, press the DATA ENTRY
X-RAYS button and verify that tube voltage is 5.0 Kv and cube current
is 1 uamp. Press the X-RAY PATH OFT and SYSTEM CONTROL STANDBY
buttons. The green X-RAYS OFT light should come on and the red
X-RAYS ON lights should go out.
(Rev. August, 1981)
83
-------
13. Remove che data disk and place in storage. Advance che princouc
EO cop of che page and give princouc co laboratory supervisor
for review.
14. When excication chamber has reached room pressure, check chac red
X-RAYS ON lights are ouc and green X-RAYS OFT lighc is on, and
open chamber cover.
15. Transfer in sequence each filter holder from che TEFA sample tray
Co its like numbered position in che sample case. If che next
run will use che same blank and/or qualicy concrol .standard, they
may be left in the sample Cray. Otherwise recurn che blank to
Che sample case and che-standard co its container in the standards
cabinet.
16. Close che excieacion chamber cover, place che XRF LOG in the
sample case and transfer co che laminar flow hood for unloading.
5.4 Unloading Filcers
1. FtlCer unloading is done in che laminar flow hood. Turn on the
hood blower and lights and clean che work surface with a Kaydry
towel and aechanol. Lay out a Kaydry towel in Che hood. Clean a
pair of forceps and che filcer loading block with Kimwipes and
mechanol and place on che cowel. Place Che sample case in che
hood,, Record your initial on che XRF LOG.
2. Select a filcer holder and Che corresponding filcer container from
the sample case. Check chac che sample ID matches position number
exactly as on che XB.F LOG. Place che filcer holder on che loading
block and che filcer container next co ic.
3. Remove che reGaining ring and cransfer che filcer co its container.
Usually ic is -easiest to hold che filcer holder over che open filcar
container and carefully invert che filcer holder so chac che filter
drops deposit side up into ics container. Sometimes use of che
forceps is necessary. Replace che filcer concainer lid and sec
aside. See the filcer holder aside.
4. Repeat steps 2 and 3 for che remaining filters.
5. Recurn che filcers co che sample storage cabinec, che filter
holders Co che standards cabinet and che XR.F LOG co che laboratory
supervisor.
6. Clean up che laminar flow hood.
5.5 TEFA Shucdown
1. Verify chac cube voltage is 5.0 Kv, and Cube currenc is 1 uamp.
2. Press che SYSTEM CONTROL STANDBY and Chen SYSTEM CONTROL OFF buccons.
3. Press HV1 on che EEDS II concrol panel co curn off che high voltage.
(Rev. Augusc, 1981)
84
-------
4. Turn off che princer.
5. Press che PWR button.on che EEDS II concrol panel Co curn off
power.
6. Press the SYSTEM POWER OFF button,
7. Switch CONTROL POWER co OFF asd place key in che scandards cabinec.
8. Return che XR program disk. Co storage, and close che disk drive
doors.
6. Calculations
The count race, I., of x-ray phocon events from element i measured by
the Si (Li) dececcor is proportional co che mass of element i, M , times an
attenuation factor, A., which takes inco consideracion che absorpcion
of the primary excitation and characteristic x-rays in the sample.
That is,
- KiMiAi
(1)
where K. is a proportionality constant. An unknown mass, M. ,
may be determined by comparing che count race measured for' che
unknown wich che count rate, I , measured with a known standard
mass
V
M,
rtCi
A,
(2)
where C is a calibration factor,
(3)
The uncertainties in M. and C are given by
and
oM,
/ .
aC.
ci
. ,
3 1
-
A i j
2
^,
' \
ali 1
I ^
i
2
.
JfH «1
s
\ rJ I .
(A)
(5)
aM!
0.05 per manufacturers specifications.
(Rev. August, L981)
85
-------
Attenuation factors for elements of atomic number <15 can be
substantial. A' is corrected for by using particle size selected
standards validated by neutron activation analysis.. A is then
determined emperieally by intercomparison with neutron activation
analysis for each particle size range. For Z >_ 15, A. 1 for chin
aerosol deposits.
The sample count rate I is determined by measuring the cocal
counts in region of interest i, subtracting the background, subtracting
spectral interferences, and then dividing by the analysis live time.
The channels and energies for each region of interest are shown in Table A-4
Background subtraction is accomplished by subtracting the product of
total counts In region of interest I for a blank filter, and the ratio of
the sample to blank Ho Ka scatter peak countss from the total counts in
region of interest i. That is,
»i - Gi - Bi -fr (6)
where N. is background subtracted counts, G is total counts,
B, is total counts from a blank fitter in region of interest i,
B
and S and S are counts in the Mo Ka region for sample and blank,
respectively. The uncertainty in background subtracted counts is
given by
r
(7)
After the background is subtracted, corrections are-
made for spectral interferences.
a
where a number of interfering elements, and T. and T
i m
are both background and spectral interference subtracted counts.
Spectral correction factors, F (section 1.3), are shown in Table A-3.
The uncertainty in T is estimated by
~~ " 4 (9)
(Rev. August, 1981)
86
-------
TABLE A-4.
oo
EXCITATION CONDITION: i
ANODE: MO
FILTER: MO
VOLTAGE: 5O
CURRENT: 2OO
ENERGYid- 40
SPECTRUM REGIONS OF INTEREST
REG I ON f:HANNFl ENERGY
ELEMENT
1
2
3
4
«±J
6
7
9
9
10
) 1
12
13
14
15
16
17
13
19
20
21
22
23
» 56-
183-
197-
212-
227-
247-
258-
276-
29'^-
310-
329-
348-
369-
389-
41?-
521-
544-
563-
597-
623-
657-
790-
627-
164
191
205
220
235
251
269 1
2:51
302
320
339
358
?.79
399
426
537 ;
560 :
5:34 :
613 :
639 :
664 :
803 C
845 C
6.24-
7 . 32-
7.88-
8.48-
9.08-
9.88-
O. :':?-
i.04-
1 . 68-
2.40-
3. 16-
3.92-
4 . 76-
5.56-
6.48-
iO.84-
J1.76-
J2.72-
>3.S8-
24 . 92-
?6.28-
51.60-
J3.08-
6.
7.
8.
8.
9.
JO.
10.
11.
12.
12.
13.
14.
15.
15.
17.
21.
->-
23.
24.
25.
26.
32.
33.
56
A 4
2C»
80
4O
O4
76
24
08
80
56
32
16
96
04
48
40
36
52
56
56
32
80
FE
NT
CU
ZN
OA
HO
AS
SE
ER
PB
RB
SR
Y
ZR
MS*
Pfi
AG
CD
IN
, SN
SB
BA
LA
EXCITATION CONDITION: 2
ANODE: MO
FILTER:
VOLTAGE: 15
CURRENT: 2OO
ENERGYlO- 1O
SPECTRUM REGIONS OF INTEREST
1
2
3
4
5
6
7
118-
141-
167-
193-
324-
365-
631-
132
155
181
209
338
376
649
1.18-
1.41-
1 . 67-
1 . 93-
3.24-
3.65-
6.31-
1 . 32
1.55
1.81
2.09
3.38
3.76
6.49
MO
AL
SI
P
l<
CA
FE
EXCITATION CONDITION: 3
ANODE: W
FILTER: CU
VOLTAGE: 35
CURRENT: 200
ENERGYlO- 2O
SPECTRUM REGIONS OF INTEREST
REGION CHANNEL
ENERGY
ELEMENT
1
2
3
4
5
A
7
3
9
10
11
12
112-
127-
1 62-
180-
221-
243-
266-
29O-
313-
520-
585-
620-
120
135
1 7O
1 90
231
253
276
30O
326
534
605
640
2.24-
2.54-
3.24-
3.60-
4.42-
4 . 86-
5.32-
5.80-
6.26-
10.40-
1 1 . 70-
12.40-
2.4O
2.70
3.4O
3.8O
4 . 62
5.06
5.52
6.00
6.52
1O.68
12.10
12.80
S
CL
K
CA
TI
V
CR
MN
FE
AS
BR
PB
* Mo Ka scatter
(Rev. August. 1981)
-------
Finally. the corrected counts are divided by analysis live .time, L,
to obtain the count rate,
. . Ti
*i ~ (10)
. _ a Ti . (ID
and al.
i t
Calculations for instrument calibration are similar except that C
is solved for in eq. 3. Also, since single element and cion-interfering
multi-element standards are used for calibration, spectral corrections are
not made and T. » ti and aT. uN .
7. Quality Control
The filters are loaded and unloaded into specially machined
acrylic holders. Filter loading is done in the laminar flow hood and the
filters themselves are handled with forceps, out of the analysis and
deposit area. The loaded filters are transported to and frLi the TEFA in
covered sample cases, and the filter holders are cleaned between each use.
These procedures prevent the possibility of sample contamination. "
To prevent confusion in identification of the samples when they
are out of their IB coded filter containers, a sample position number versus
ID number relationship used. This relationship is established by the XRF LOG
before the filters are removed from their containers and it is verified after
each handling step in the procedure.
For each XRF analysis batch of 10 samples, one blank and a quality
control standard is analyzed. Measured concentrations of the quality control
standard, which contains several key elements, are compared with actual
'concentrations (Figure A-7). If the deviation is more than + 2%, all samples
of that run mist be reanalyzed. The results of the quality control standard
over a number of runs provides a measure of the XRF analysis precision. If the
results show a trend in drift, recalibration is required.
Several elements, including K, Ca, Fe, As, Br and Pb are measured
under more than one of che three excitation conditions normally used for each
run. Results of these elements are compared for each of the excitation
conditions under which they are measured. If agreement is for outside the
calculated uncertainties, the sample must be reanalyzed.
(Rev. August, 1981)
88
-------
PPRT
ftA :-.
frl
TI
S!
7.N
CD
PAST S
TANDARD Q^O4f!
ONCENTRATION
ACTUAL
40.30
44.30
44.90
47.30
44. SO
49.70
'/. ERROR
MEASURED
41.19+- 2.07 1.0
44.79+- .70 4'9.70+- 2.54 - 0.0
(Rev. August, 1981)
89
-------
8o Quality Assurance
Calibration of the instrument is by chin film standards prepared
by Mieromatter, Inc., Eastsound, WA., and by solution deposited and
particle standards made by Columbia Scientific Industries, Austin, IX.
Plots of instrument response versus atomic number should yield smooth
curves, and are used to validate standard concentrations.
laeerlaboratory comparisons are used to check accuracy of the
instrument calibration. Several techniques have been used in interlaboratory
comparisons in addition to energy dispersive x-cay fluorescence, including
neutron activation analysis, optical spectroscopy, wavelength dispersive
x-ray fluorescence, and ion chromotography.
la house internethod comparison vith neutron activation analysis is
done routinely. This independent method provides comparison with XHF on
about 20 elements.
Results from each analysis run are reviewed by the laboratory super-
visor. The inter-excitation and quality control standard results are checked
as described in section 7. tha laboratory supervisor must Initial the
XRF LOG before results of chat run are considered valid. Periodic audits
of the TEFA startup, filter loading and unloading, analysis, and TEFA
shutdown procedures insure compliance with the Standard Operating Procedure.
(Rev. August, 1981)
90
-------
APPENDIX D
TEFLON FILTER HANDLING AND STORAGE
Standard Operating Procedure
1. General Discussion
Teflon filters used for parriculate collection consist of a polyolefin
supporting ring bonded to the top (particle collection) surface of a
Teflon membrane. Two sizes, 47 and 37 mm diameter, are used for TSP
and dichotomous samples, respectively. Sample ID codes have a two-
letter prefix followed by a three-digit number.
All filter handling procedures are to be done in the laminar flow hood.
Clean the work area with a methanol dampened Kaydry towel, then lay out
a clean Kaydry towel to use as a work surface before all handling
procedures. The filters must be handled only by the supporting ring
with clean forceps.
Filters are stored in individual PetriSlides, which in turn are placed
in numerical order in plastic trays. Cardboard boxes each holding two
PetriSlide trays are placed in the sample storage cabinet to insure
secure storage.
2. Materials and Equipment
Nulcepore aerosol filter holders with quick-disconnect fittings
Sierra Model FH-240-P filter cassettes
Millipore A9 x 9 mm plastic petri dishes
« Millipore 47 mm PetriSlides and trays
Membrana Corp. Teflon filters, 47 and 37 mm diameter
Sample transport boxes for both sample types
forceps
Kaydry towels
methanol
Baggies
waterproof fine point markers
. 2-3/8" Caplugs
adhesive labels
Nuclepore 47 nan drain disks
' ' (Rev. July, 1982)
Ziploc bags
91
-------
3. Filter Coding
1. Lay out a series of 5 - 10 PetriSlides on the work surface, label
with the next sample ID numbers in sequence and remove Cheir lids,
2. Select a new filter and inspect both sides for foreign particles,
pin holes, discolorations, or other imperfections. Some particles
may be carefully blown off with a photographic lens cleaning
blower. Discard the filter if defective. Otherwise, place top
side up in an open PetriSlide.
3. Repeat step 2 until' all PetriSlides contain a filter.
4. Steady the filter in the PetriSlide by pressing down on the plastic
ring of the filter with forceps. Write the ID number as recorded on
the PetriSlide on the plastic ring of the filter using a fine point
waterproof marker.
5. Repeat step 4 until all filters are coded with an ID number.
6. Check that the ID numbers on the filters correspond to those on
the PetriSlides, wait a few seconds for the ink to dry, then replace
the PetriSlide lids.
7. Return th« coded filters and PetriSlida* to Cha Cray In numerical _
8. Repeat steps 1 - 7 as necessary.
9. Recocd the,ID numbers, lot number, and pore size of all filters
coded in the Sample Log Book.
10. Place loaded trays in boxes and store in sample storage cabinet.
4. Loading - Diehotomous Samples
1. Obtain filters to be loaded from the sample storage cabinet.
2. Select a tared filter from the sample tray and place PetriSlide on
work surface. Write the ID number on an adhesive label using a
waterproof marking pen and stick to the lid of a clean 49 x 9 am
petri dish. Check that the ID number.on the filter, the PetriSlide,
and the petri dish natch.
(Rev. July, 1932)
92
-------
3. Place'the bottom half (female part) of a clean Sierra filter
cassette on the work, surface and transfer the filter from its
PetriSlide to the filter cassette. It should be placed top side
up. Place the top half (male part) of a clean Sierra filter cassette
in position over the bottom half and press down so that it snaps
into proper alignment.
4. Transfer the loaded filter cassette into the labeled petri dish top
side up and set aside.
5. Return the empty PetriSlide to its place in the tray.
6. Repeat steps 2 - 5 as necessary.
7. Return trays to boxes and sample storage cabinet.
3. Continue with the Filter Shipping Standard Operating Procedure.
5. Loading - TSP Samples
1. Obtain filters to be loaded from the sample storage cabinet.
2. Select a tared filter from the sample tray and place PetriSlide on
work surface. Write the ID number on an adhesive label using a
waterproof marking pen and stick on the base of a clean Nuclepore
filter holder. Check that the ID number on che filter, the PetriSlide,
and the filter holder base match.
3. Using the forceps place a single drain disk on the filter holder
base. Transfer the filter from its PetriSlide into position (top
side up) on the drain disk. Place a clean locking ring into position,
making sure proper alignment of filter holder base, drain disk, filter
and locking ring is achieved. Screw the top tightly into position,
being careful not to disturb alignment. Place a clean Baggie over
the filter holder and a Caplug on top.
4. Place the loaded filter into the sample transport box.
5. Return the empty PetriSlide to its place in the tray.
6. Repeat steps 2 - 5 as necessary.
7. Return trays to boxes and sample storage cabinet.
8. Continue with the Filter Shipping Standard Operating Procedure.
(Rev. July, 1982)
93
-------
6. Unloading - Dichotomous Samples
1. Check that samples have been logged in according to the Filter
Shipping Standard Operating Procedure. Obtain PetriSlide trays
from sample storage cabinet.
2. Select a petri dish containing an exposed filter from the sample
transport box and place on work surface. Obtain the PetriSlide
with matching ID number from the tray and place on work surface.
3. Remove the petri dish lid and, being careful not to touch the filter,
use a pair of forceps to remove the filter cassette assembly from the
petri dish. Carefully separate the cassette assembly by sliding
thumbnail between the top and bottom and prying apart. Then using
a second pair of forceps, transfer the filter to its PetriSlide.
4. Make sure the ID number on the filter matches the others. Return
the PetriSlide and filter to its place in the tray.
5. Record any unusual appearance or condition of the filter in the
Sample Log Book.
6. Repeat steps 2-5 until filters are all unloaded.
7. Return trays to boxes and sample storage cabinet.
7. Unloading - TSP Samples
This Section is the same as Section 6, except for steps 2 and 3:
2. Select a sample from the sample transport box and set upright on the
work surface. Obtain the PetriSlide with matching ID number from
the eray and place on work surface.
3. Remove Caplug. Remove Baggie and discard. Unscrew top and lift
off locking ring, being careful not to touch the filter. Transfer
the filter to its PetriSlide.
8. Equipment Cleaning
1. After sample unloading, clean the sample transport boxes using a
asethanol dampened Kaydry towel. Clean both inside and outside
surfaces.
(Rev. July, 1982)
94
-------
2. Remove drain disks and adhesive labels from filcer holders and pecri
dishes. Clean all pares (filcer holder base, locking ring, screw cop,
Capug, filcer cassecce and petri dish) with a mechanol dampened
Kaydry towel. Pay particular attention Co surfaces chat contact the
filter, and do not Couch those surfaces after cleaning.
3. Place cleaned filter holder bases, screw cops, and Caplugs in sample
transport box.
4. Place cleaned locking rings, filter cassettes, and petri dishes in
Ziploc Bags.
(Rev. July, 1982)
95
-------
GLASS AND QUARTZ FIBER FILTER HANDLING AND STORAGE
Standard Operating Procedure
1. General Discussion
Glass and quartz fiber filters are used for particulate collection
primarily when carbon analysis is required. Two sizes, 47 and 37 mm
diameter, are used for TSP and dichototnous samples, respectively.
Sample ID codes have a two-letter prefix followed by a three-digit
number.
All filter handling procedures are to be done in the laminar flow
hood. Clean the work area with a methanol dampened Kaydry towel,
then lay out a clean Kaydry towel to use as a work surface before
all handling procedures. The filters must be handled only by the edge
with clean forceps. Use wide tipped, non-serrated forceps to avoid
damaging the fragile filters.
Filters are stored in individual PetriSlides, which in turn are placed
in numerical order in plastic trays. Cardboard boxes each holding
two PetriSlide trays are placed in the sample storage cabinet to
insure secure storage.
2. Materials and Equipment
Nulcepore aerosol filter holders with quick-disconnect fittings
Sierra Model FH-240-P filter cassettes
Millipore 49 x 9 mm plastic petri dishes
Millipore 47 am PetriSli'des and trays
Membrana Corp. Teflo filters, 47 and 37 mm diameter
Sample transport boxes for both sample types
forceps
Kaydry towels
methanol
Baggies
waterproof fine point markers
. 2-3/8" Caplugs
adhesive labels
Nuclepore 47 mm drain disks
Zlploc bags
(Rev. July, 1982)
96
-------
3. Filter Coding
1. Lay out a series of 5 - 10 PetriSlides on Che work surface, label
with the next sample ID numbers in sequence and remove their lids.
2. Select a new filter and inspect both sides for foreign particles,
pin holes, discolorations, or other imperfections. Some particles
may be carfully blown off. Discard the filter if defective.
Otherwise, place top side up in an open PetriSlide and replace the
lid.
3. Repeat step 2 until all PetriSlides contain a filter.
4. Return the coded filters and PetriSlides to the tray in numerical
order.
5. Repeat steps 1 - 4 as necessary.
6. Record the ID numbers and lot number of all filters coded in the
Sample Log Book.
7. Place loaded trays in boxes and store in sample storage cabinet.
4. Loading' - DichotOTnous Sam-pies
1. Obtain filters to be loaded from the sample storage cabinet.
2. Select a tared filter from the sample tray and place PetriSlide on
work surface. Write the ID number on an adhesive label using a
waterproof marking pen and stick to the lid (the portion without the
embossed marking) of a clean 49 x 9 mm patri dish. Check that the
ID number on the filter, the PetriSlide, and the petri dish match.
3. Place the bottom half (female part) of a clean Sierra filter cassette
on the work surface and transfer the filter from its PetriSlide to
the filter cassette. It should be placed top side up. Place the
top half (male part) of a clean Sierra filter cassette in position
over the bottom half and press down so that it snaps into proper
alignment.
4. Transfer the loaded filter cassette into the labeled petri dish top
side up and set aside.
5. Return the empty PetriSlide to its place in the tray.
6. Repeat steps 2 - 5 as necessary.
7. Return trays to boxes and sample storage cabinet.
8. Continue with the Filter Shipping Standard Operating Procedure.
(Rev. July, 1982)
97
-------
5. Loading - TS? Sa.ap.las
lo Obcain filters to be loaded from the sample storage cabinet.
2. Select a tared filter from the sazaple trav and place a PetriSlide or.
work surface. Write the ID number on an adhesive label using a
waterproof marking per. and stick or. the base of a clear. N
-------
5. Record any unusual appearance or condition of Che filcer in tha Sacple
Log Book.
6. Repeat steps 2-5 until filters are all unloaded.
7. Return crays to boxes and sample storage cabi-ec.
7. Unloading - TS? Samples
This Section is the sane as Section 6, except for steps 2 and 3:
2. Select a sample from the sanpla transport box and set upright on
the work surface. Obtain the PetriSlide with aatching ID number from
the tray and place on work surface.
3. Remove Caplug. Remove Saggie and discard. Ur.screw top and lift
off locking ring, being careful not to touch che filter. Transfer
the filter to its-PetriSlide.
8. Equipment Cleaning
1. After sample unloading, clean the 'sample transport boxes using a
methanol dampened Kaydry towel. Clean both inside and outside
surfaces.
2. Remove drain disks and adhesive labels from filter holders and
petri dishes. Clean all parts (filter holder base, locking ring,
screw top, Caplug, filter cassette and petri dish) with a nechanol
dampened Kaydry towel. Pay particular attention to surfaces Chat
contact the filter, and do not touch those surfaces after cleaning.
3. Place cleaned filter holder bases, screw tops, and Caplugs in
sample transport box.
4. Place cleaned locking rings, filter cassettes, and petri dishes in
Ziploc bags.
(Rev. July, 1982)
99
-------
FILTER SHIPPING
Standard Operating Procedure
1. General Discussion
Unexposed filters are shipped from NEA, Inc. Co Che field site for
sample collection. After sampling, Che exposed filters are return
shipped to NEA for processing and analysis. This procedure describes
the steps necessary to insure the integrity of the samples.
Sample logging procedures and forms filled out at both the shipping
and receiving points provide chain of custody documentation. Filters are
shipped in petri dishes or preloaded into holders that prevent chemical
contamination or physical damage. The shipping container is designed
to keep samples upright and cushioned from mechanical shock during
shipment.
2. Equipment
1. Sample Transport Box to hold dichotomous and/or lovol TSP samples.
2. Nuclepore, Corp. Aerosol Holders, no. 430400.
3. Millipore plastic petri dishes, no. PD1004700.
4. Millipore PetriSlides, no. PD1504700.
5. Sierra Instruments Filter Holder, no. FH-240-P.
6. Plywood shipping container with flanged base.
7. Specification Packaging Corp. Tip (N) Tell indicator.
3. Shipping Filters to Sampling Site
1. Select samples to be shipped and record date in the "LOG OUT" column
in Che Sample Log Book.
2. Fill out a Chain of Custody fora (Figure A-l). The person responsible
for sample custody at the sampling site must be identified.
3. Load samples into a Sample Transport Box, or another container that
will insure the samples are held securely and upright.
4. Pack Che samples and Chain of Custody form in the shipping box and
affix proper address label.
5. When samples are picked up by carrier, sign initials in Sample Log
Book next to date recorded in step I.
(Rev. July, 1982)
100
-------
6. Notify Che person to receive the samples of the date and carrier of
the shipment.
7. When samples are received at the sampling site, the responsible
person must complete the Chain of Custody form. If there are
any discrepencies, notify the NEA Laboratory Supervisor.
4. Return Shipping of Exposed Samples
1. Select the samples to be shipped.
2. Fill out a Chain of Custody form (Figure A-l)
3. Load samples into the Sample Transport Box or other suitable
container.
4. Pack the samples and Chain of Custody form in the shipping box.
Include completed Chain of Custody forms as well, and address to
NEA, Inc., 8310. S.W. Nimbus, Beaverton, OR 97005, attn: Laboratory
Supervisor.
5. Attach a Tip N Tell indicator to the shipping box and remove wire.
The Tip N Tell should be taped or stapled on, as the adhesive
backing does not stick well to the varnished shipping box.
6. Notify the Laboratory Supervisor that a shipment has been made.
7. When shipment is recieved at NEA, fill in the Chain of Custody form
and record date, initials, and condition of Tip N Tell in the
Sample Log Book.
3. Precede with the sample unloading procedure and give the Chain of
Custody forms to the Laboratory Supervisor.
5. Optional Shipping Procedure
In some circumstances, such as when NEA personnel are travelling to or
from the sampling site, it is desirable to hand carry the samples. In
general, the procedures as in sections 3 and 4 should be followed except
that the shipping box is not required.
(Rev. July, 1982)
101
-------
FIGURE A-l. FILTER CUSTODY/SHIPPING FORM
Sample Shipping
Date
Carrier
Sample ID"s
Shipped by
Sample Receiving
Dace
Carrier
Sample ID's
Received by
Laboratory Supervisor
(Figure 1)
(Rev. July, 1982)
102
-------
FILTER WEIGHING USING THE CAHN 27 ELECTROBALANCE
Standard Operating Procedure
General Discussion
1. Analytical Problem:
The mass of particles collected on filters must be determined. Two sizes
of filters are commonly used, 37 and 47 mm diameter. A variety of. filter
media are used, such as teflon, Nuclepore, cellulose ester, glass Jiber,
and quartz. A deposit of at least 100 ug is required to acheive an
accuracy of ± 10Z, relative (400 ug for glass or quartz filters).
2. Interferences:
Electrostatic charge on the filter is one possible source of inter-
ference. This is eliminated by use of a. beta source charge neutralizer.
Humidity changes may affect the weight of deposit and filter veighc Ear
some types of filter media. Humidity changes are minimized by performing
the weighing procedures in an air conditioned laboratory.
3. Mlniimim Detectable Quantity: 15 ug (three sigma), 50 ug for glass fiber
and quartz filters.
4. Precision and Accuracy:
The balance is calibrated with class M weights. Uncertainty in net weight
is ± 10 ug (* 40 ug for glass or quartz filters).
5. The technician should read the Cahn 27 Instruction Manual entirely before
using the balance, paying close attention to Section 3, Balance Operation.
The balance is always left ON to provide maximum stability.
6. Keep the calibration weights clean and store in their proper container.
Handle them only with the cleaned weight forceps (non-serrated stainless
steel) and do not use the weight forceps for any other job.
(Rev. 6/28/82)
103
-------
2. Equipment and Materials
Cahn 27 Electrobalance with custon 60 mm open stirrups
Po210 charge aeutralizer
Calibration weights, 10, 20, 50 and 100 mg Class M
Tare weights, 20, 50 and 100 ng Class C
weight forceps
filter forceps
Kaydry towels
Kimwipes
Methanol
3. Operating Procedure
3.1 Start Up;
1. Remove the stirrups from the weighing chamber as in Section 3.1.2 of
the Cahn 27 Instruction Manual and set aside on a clean SCimwipe.
Clean the weighing chamber with a methanol dampened Kiavipe. Replace
the stirrups, one on the A side and one of the TARE side. Place che
charge aeutralizer in the center of the weighing chamber. Clean che
area around the balance and lay out a clean Kaydry towel in front of
the weighing chamber. Clean the weight forceps (non-serrated stain-
less, steel) and filter forceps using a methanol dampened Kimwipe.
2. Obtain the calibration weights and the filters to be weighed from
the sample storage cabinet.
3. Record technician, date and' filter lot number on the data sheet.
4. Determine approximate weight of one of the filters by weighing on
the A200 range. Select the 10, 20, 50 and 100 mg calibration
weights in combination such that their combined weight equals
within + 3 and - 12 mg of the filter weight. (When doing gross
weights or reweights, use the same weights as for the tare
weighing).
5. Set the balance controls to RANGE: A 20 and RESPONSE: 0. Make
sure CALIBRATE, COARSE and FINE ZERO controls are locked. Press
TARE twice to untare the balance.
6. Place the selected calibration weights on the A pan and balance
with appropriate tare weights on the TARE pan so that the display
reads 0 ± 20 mg.
(Rev. 6/28/32)
104
-------
7. When Che display stabilizes (after at least 30 seconds), press TARE
Co zero the balance.
8. Add the 20 mg calibration weight the the A pan (or remove it if
already there). Display should read + 20.000 ± 0.001 (or
- 20.000 * 0.001) when it stabilizes. If not, adjust CALIBRATE
accordingly.
9. Remove (or replace) calibration weight and note than 0.000 £ 0.001 is
displayed. If not, repeat steps 7 and 3. Record tare weight as che
sum. of the calibration weights ± display reading, and the calibration
reading on the calibration log, as well as the other required
information.
10. Remove calibration weights to their container.
3.2 Weighing Filters;
1. When weighing the filters, note any defects (torn, particles falling
off, etc.) on the data sheet.
2. Place the first filter Co be weighed on the charge neutralizer. After
a few seconds, transfer the filter to the A platform and place Che
next filter to be weighed on the charge neutralizer.
3. When che display stabilizes (after at least 30 seconds), record
the filter ID number and weight reading including + or - sign on the
data sheet(Figure A-2)
4. Transfer the filter from the A platform co its container, transfer
Che filter on the charge neutralizer to the A platform, and place che
next filter in sequence on the charge neutralizer.
5. Repeat steps 3 and 4 until all filters are weighed or until a total of
50 filters have been weighed.
6. Place the claibration weight(s) on the A pan. On che calibration
logs record the care weight as che sum of che calibration weights
± display reading. Press TARE if che reading is not 0.000.
7. Add Che 20 mg calibration weight co the A pan (or remove it if
already there). Record calibration reading(Fizure A-3)
8. Place calibration and tare- weights in cheir containers.
3.3 Replicates;
1. Replicate weighings should be performed on 10Z of che filters (both
tare and gross weighings), selected at random. They should be
reveighed Ly a technician other Chan che one who did che original
weighing.
(Rev. 6/28/82)
105
-------
2. Beigh che filters using che procedures in sections 3.1 and 3.2.
Indicate chat che weighings are replicates on che data sheet.
3. Calculate che difference, B., between che original and replicate
weighings, and record on che reweight data sheet.
3.4 Shutdown;
L. Replace the filters chat were weighed in che sample storage
cabinet.
2. Clean che balance as in 3.1.1.
3. Return che data sheets co the laboratory supervisor.
3«5 Calculations;
B - (W - B ) Z 1000,
a g c
where, B nee deposit in ug
B - gross weight reading in mg
B tare weight reading in sg
y m (W - B ) X 1000
d Z f
or
y . (W - B ) I 1000,
a t r
whore, B difference betva«n original and replicate weights in use
d
B - replicate weight reading in og.
3.6 Quality Control:
1. The care and calibration weight checks at che and of a weighing set
must be within i 0.004 mg of cheir correct values or che entire set
nuac be reweighed.
2. Replicate weighing differences, B , muse be _< ± 10 ug or < 2%.of B or
Che entire set must be reweigheH ~ a
(^ s 40 ug for glass or quartz filters).
(Rev. 6/28/82)
106
-------
3.7 Quality Assurance:
1. Class M weights are used for calibration. According Co NBS
circular 547, they are "...designed for use as reference standards,
for work of the highest precision, and for investigations demanding
a high degree of constancy over a period of time."
2. 10Z replicate weighings by another technician ensures that weighing
is without operator bias and precision is within limits.
3. Calibration and tare operations are performed before each set
of _< SO filters and are 'checked for accuracy after each set.
4. Results or replicate weighings and calibration and tare weight checks
are reviewed by the laboratory supervisor. He must initial Che
calibration data sheet before Che data is considered valid.
(Rev. 6/28/82)
107
-------
T.ca.
FIGURE A-2. FILTER HEIGHT DATA SHEET
t.D.
1
TIT
(
««>
' '
r
t
(u?)
I I
I I I
I I
I I
I ' I
I I I
I ! I
File«c Lac
(Rev. 7/7/82)
108
-------
FIGURE A-3. CAIIN 27 ELECTROBALANCE FILTER WEIGHING CALIBRATION
Date
Tech.
Filters Weighed
Tare, Cross
or Rewplglita
1
i
Tare and Calibrate
Initial
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C,
T
U
I
1
I
1
1
I
1
1
1
1
1
1
1
a
4
.
.
.
.
.
f
m
.
.
.
.
.
,
.
.
Final
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
T
C
1
1
1
1
1
1
1
1
1
1
1
1
1
.
f
.
.
.
.
.
.
.
.
,
,
.
.
.
.
,
,
.
.
*
.
QA
-------
APPENDIX E
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING
PARTICLE SIZE: C
ANALYSIS ID: AC001 - Teflon
- TEST NO. 1A
EXPOSED AREA:
MASS:
6.42 SQUARE CM
260-1 10 MICROGRAM::
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZM
GA
AS
SE
BR
PB
SR
Y
ZR
MO
PD
AG
CD
IN
SM
SB
BA
LA
HG
PB
0.
0.
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("I
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
. , . ,
0.
0 .
0.
0.
000+-
00 OH
OOOH
555+-
315+-
OOOn
000+
000 +-
OOOH
00 1 +
000 +-
074H
008+-
007+
004+-
002+
070+-
OOr'-.H
OOOH
002 H
OOOH
OOO+-
OOOH
01S+-
OOOH
OOOH
000+
OOOn
OOOH
434+-
00 OH
1S7+-
000 H
046+-
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
("1
0.
0.
0.
0.
0.
0.
0.
0.
"!
0.
0.
0.
0.
OSS
'"'42
025
054
032
375
172
303
003
002
002
O0:=:
002
002
00 1
00 1
OOS
002
OOS
002
OO:-;
003
014
0 1 0
009
014
0 1 8
021
140
553
099
161
003
OOS
0.
0.
0.
o .
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
o
fl
214.
0
1.
C")
0.
000+-
000+ -
OOOn
560+-
021+-
OOOn
000 +
OOOn
OOOn
00 7 H
00 3n
475+-
043+-
044+-
025+-
01 1+-
447+-
037+-
OOO-i
015+-
000+-
000 + -
000 +
112+-
00 OH
000+
CrOO-f
OOOn
OOOH
64?+-
OOOn
202-+-
OOOn
292n
0.
1.
0.
0.
0.
'"'
39 .
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
16.
0.
1.
0.
0.
568
553
161
34 -'
207
405
622
947
0 1 9
0 1 0
0 1 0
049
0 1 3
0 1 2
009
009
051
0 1 0
051
0 1 5
0 1 9
02 1
088
063
060
039
117
136
9OO
637
033
02u
052
0.
0.
0.
1.
0 .
(")
0.
0.
0.
1")
0.
o .
0.
0.
0.
0.
0.
0.
t")
0.
(")
("1
0.
0.
0.
0.
0 ,
0 .
0 .
82.
O
0.
0 .
0.
OOO-i
OOOn
000+
367+-
776+-
OOOH
OOOn
000+-
000+
OO:-H
00 1 H
1 33 H
0 1 9+-
017+-
010+
004 H
172+-
014+-
OOC'H
006 +-
OOOH
OOOH
OOOH
04 3 H
OOOH
000+-
OOOn
000+
OOOn
452+-
OOOH
462+-
00 OH
112+-
0.23 8
0. 596
0. 062
0. 144
0. OS 5
0 . 924
15.22
OV743
0 . 00 "7
0. 004
0. 004
o . 02 o
0 . 005
o . OOF;
0 . 003
0 . 003
0. 021
0 . 004
0 . 020
0. d) 06
0 . 007
0 . 003
0. 034
0. 024
0. 023
0. 034
( J . 045
0. 052
0. 346
7.047
0. 245
0.397
0 . 008
0. 020
110
-------
SAMPLE IDs HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 1A
PARTICLE SIZE: F
ANALYSIS ID: AF126 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1107+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
C'
CL
K
CA
Tl
V
CR
MIM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
. ,
^
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
a.
0.
0.
0.
137.
0.
0.
0.
0.
000-*
000+-
000+-
20:3+-
240+-
000+-
00 OH
000+-
000+-
009+-
013+-
1 14+-
024+-
015+-
016+-
003+-
340+-
017+-
000+-
000-(
OOOn
000+-
OOO-i
000+-
000 +-
000+ -
OOO-i
OOOH
000 +-
33 2 H
080+-
000+-
OOO-i
277+-
0.
0.
0.
0.
0.
0.
16.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
o
0.
252
272
066
115
070
936
400
S05
007
002
002
009
003
002
002
002
01S
002
002
003
004
004
015
012
012
016
024'
029
053
430
107
165
oos
0 1 6
0.
0.
0.
14.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
SSI .
0.
0.
0.
1.
000+-
000+-
000+-
173+-
961+-
000+-
000 +-
OOOH
000+-
057+-
OS6+-
733H
155+-
095+-
102+-
049+-
1S3+-
10S+-
00 OH
000-t
OOOH
OOO-i
OOO-i
000+-
000+-
OOO-i
OOOH
OOOH
OOO-i
992+-
511+-
000+-
OOOn
779+-
1
1
0
0
0
(-.
10
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
41
0
1
0
0
.615
.744
. 426
. 740
. 446
. 007
5.29
. 1 63
. 045
.015
.013
. 055
. 0 1 S
.014
. 0 1 3
.012
. 114
. 0 1 4
.015
.017
. 024
. 026
. 093
. 073
. 076
. 1 02
. 154
. 135
. 340
. 273
. 637
. 059
. 029
.101
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
79.
0.
0.
(")
0.
000+-
000+-
000+-
2S1+-
719+-
000+-
000+-
000 +-
000+-
005 + -
OOS+-
066+-~
0 1 4+-
009+-
009+-
004 -f
197+-
010+-
000+-
000 +-
OOO+-
000+-
000+-
000+-
000+-
000+ -
OOO-i
OOO-i
000+
69S+-
046+-
000+-
OOO+-
161+-
o. 146
o. 153
( ) . 033
c.063
0.041
0.543
9.514
0.467
0.004
0.001
0.001
-o. OOF;
0. 002
0 . 00 1
o.OOl
( » . 00 1
« i.Ol 0
o.OOl:
0 . 00 1
0. 002
0.002
0. 002
0. 009
0.007
0.007
0 . 009
0 .014
0 . 0 1 7
0.031
3.799
0 . 062
0 . (".'96
O, O <"):-:
0. 009
111
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 2A
PARTICLE SIZE: C
ANALYSIS ID: AC002 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 513+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
Zt
n
- >..
).:;;
CA
TI
v
CR
MN
FE
NI
CLl
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SM
SB
BA
LA
HG
PB
0.
0.
ft
0.
o
V D
Co
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
65.
0.
0.
0.
0.
OOOn
00 OH
OOfH
974+-
5&5H
OOOH
OOOH
00 OH
OOOH
006+-
00=;+-
1 50+-
008+-
0 1 0+-
010+-
O04+_
095n
008 H
022n
00 9 H
000+
OOOH
OOOn
042+-
00 OH
000+-
000+-
OOOn
OOOn
294+-
000+-
000+-
00 OH
103+-
0.
0.
0.
0.
o
*./
0.
11.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
214-
235
055
OS2
OSl
*_' _' -L
652
ISO
566
005
002
00 1
012
002
002
002
002
0 1 0
002
004
002
Ofr~:
003
012
009
0 1 0
0 1 3
01 S
023
270
671
079
125
003
012
0.
ft
0.
6.
.-,
0 .
0.
0.
0.
0.
0.
0.
0.
0.
('1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
n
0.
419.
0.
0.
0.
0.
OOOn
OOO+-
00 OH
254+-
62Sn
000+
OOOn
OOOn
000+
035+-
033+-
965+-
05 1 +-
062+-
OAci+-
025+-
6 12+-
05 1 +-
142+-
060n
OOOH
OOOH
000+-
270+-
000+-
000+
000+-
OOfH
000 +-
190+-
00 OH
000+-
000+-
663+-
1.
1 .
it
0.
0.
4.
71.
*«'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
29.
0.
0.
0.
0.
377
507
^ss
525
324
1S4
774
632
03 1
Oil
009
07S
0 1 3
012
01 1
0 1 0
06:3
0 1 0
027
0 1 3
0 1 7
C) 1 S
074
056
064
086
115
145
734
990
506
803
020
074
0.
0.
ft
1.
{).
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
-0.
0.
0.
0.
0.
0.
0.
o
0.
0.
81.
0.
0.
0.
0.
OOOn
000+-
OOfH
2 1 9+-
707+-
OOO+-
OOO+-
000+
OOOn
007+
007+-
18C+-
0 . 26:5
0.294
0 . 069
0. 105
O. O/-.5
0 8 1 6
13.99
0.708
O. DO A
0. 002
0. 002
0 . 0 1 A
01 OH 0. 002
012+-
013+
OOS4 -
119+-
0 10+-
02S+-
0 1 2+-
00 f.H
OOOH
000+-
053 +-
OOOn
000+-
f)OfH
000+
OOOH
731+-
00 OH
OOOn
000+-
1 29+-
0. 002
0 . 002
0 . 002
0 . 0 1 3
0. 002
0= OO5
0. 002
(") f) ("):"-:
0. 004
0 . 0 1 4
0 .011
0 . 0 1 3
0 .017
O O2 2
0 . (")2'~!
0.338
6.060
0. 099
0. 156
0.004
0 . 0 1 5
112
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF127 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1811+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
FB
0.
0.
0.
3.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
222.
0.
0.
0.
0.
000+-
000+-
000+-
373+-
014+-
000+-
OOO-i
000+-
000+-
018+-
019+-
312+-
033+-
025+-
026+-
017+-
432+-
023+-
000+-
000+-
000+-
000+-
000+-
233+-
000+-
OOO-i
OOO+-
000+-
OOO-i
020-1
000+-
000+-
000+-
617+-
0.
0.
0.
0.
0.
1.
26.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
10.
0.
0.
0.
0.
392
423
106
170
103
509
160
791
Oil
003
002
017
003
003
002
003
023
002
033
003
004
004
018
015
015
020
026
037
078
377
095
144
005
031
0.
0.
0.
21.
12.
0.
0.
0.
0..
0.
0.
4^.
0.
0.
0.
0.
.*!
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1425
0.
0.
0.
w*
000+-
000+-
000+-
653+-
932+-
000+-
000+-
000+-
000+-
114+-
121+-
006+-
245+-
161+-
169+-
1 1 H
771+-
146+-
000+-
000+-
000+-
000+-
000+-
527+-
000+-
OOO-i
OOOn
OOO-i
ooo-i
. 37+-
000+-
000+-
000+-
964+-
2.519
2.713
0 . 679
1 . 093
0.692
9 . 689
167.95
1 1 . 498
0.069
0.020
0 . 0 1 3
0. 110
0.022
0 . 0 1 6
0,016
0.017
0. 145
0.016
0.213
0.019
0.026
0.026
0. 112
0 . 097
0 . 094
0. 128
0. 166
0 . 237
0.502
66.619
0.603
0.924
0.035
0. 197
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
73.
0.
0.
0.
0.
000+-
000+-
000+-
196+-
714+-
000+-
OOO-i
OOO-i
OOO-i
006+-
007-1
11 1+-
0 1 A +=.
009+-
009+-
006+-
153+-
003+-
000+-
OOO-i
000+-
OOO-i
000+-
084+-
000 +
OOO-i
000+-
000+-
OOfH
701+-
000+-
000+-
000+-
219+-
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
o
t{
0.
0.
0.
0.
139
150
037
061
038
535
273
635
004
001
001
006
00 1
00 1
00 1
00 1
008
00 1
012
00 1
00 1
001
006
005
005
007
009
0 1 3
(")'"'!-!
704
034
051
002
Oil
113
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING
PARTICLE SIZE: C
ANALYSIS ID: AC003 - Teflon
- TEST NO. 3A
EXPOSED AREA:
MASS:
6.42 SQUARE CM
435+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
»;
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
T1
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
50.
0.
0.
0.
0.
300n
000+-
00 OH
90 IH
458+-
000 +
00 _
9_
0.
0.
0.
4.
61.
J 0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
oer
0.
1.
0.
0.
365
635
292
512
294
639
295
624
033
013
012
471
014
014
014
Oil
064
0 1 0
067
0 1 6
025
021
088
067
062
090
119
155
OI^ICT
046
640
003
025
033
1.
. .
' v
0.
1.
0.
0.
0.
0.
0.
o.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
66.
0.
0.
0.
0.
719+-
967+-
000+-
192+-
606 +-
OOOH
000+'
OOOn
OOOn
014+-
012+-
S1S+- _
0 11+-
014+-
022 +-
007+-
12S+-
006+-
OOOn
OOOn
057+-
000 + -
000+-
051+-
000+-
OOOn
OOOn
OOOH
OOOH
577+-
163+-
207+-
025+-
115+-
0.797
1 . 936
0 . 060
0. 108
0. 062
0. 966
12.63
0.747
0 . 007
0. 003
0. 003
0. 104
o. 003
(") . On:":
O. OO:"i
0. 002
0 . 0 1 3
0. 002
0 .014
0 . 003
0 . 005
0 . 004
0 . 0 1 8
0 .014
O. f)ir=:
0 . 0 1 9
0.025
0. 032
0. 265
5.339
0. 132
0.207
0. 005
0 .017
114
-------
SAMPLE ID.: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 3A
PARTICLE SIZE: F
ANALYSIS ID: AF123. - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1316+- 10 MICROGRAM::
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
~-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MG
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0
0
0
3
2
0
0
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
o
0
0
0
o
0
o
217
o
o
0
0
. 000+-
. 000+-
. 000+-
. 495+-
. 045+-
. 000+-
. 000+-
. 000+-
.000+-
.016+-
. 022+-
.221+-
. 042+-
. 029+-
. 027+-
. 009+-
. 365+-
. 027+-
. 00 OH
.000+-
. OOOn
. 000+-
. 000+-
.213+-
. 000+-
. 000+-
. 000+ -
. 000+-
. 000+-
. 649+-
. OOOn
. OOOn
. 000+-
t'C'C'"^""
0 . 443
0.433
0 . 1 04
0, 173
0. 110
1 . 549
26. 160
1 . 76 1
0 . 0 1 0
0.003
0 . 002
0.013
0.004
0.003
0 . 003
0.003
0.021
0 . 003
0. 029
0.003
0.004
0.005
0.013
0.015
0.014
0 . 020
0.030
0 . 033
0.073
10. 173
0. 103
0. 159
0.005
0.042
0.
0.
0.
22.
13.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
*i
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1397
0.
0.
0.
5.
000+-
000+-
000+-
433+-
1314
OOOn
000+-
000+-
000+-
100+-
143+-
416+-
270+-
1S9+-
176+-
053+-
345+-
174+-
00 OH
000+-
000+-
000+-
OOOn
402+-
000+-
000+-
OOOH
000+-
OOOn
.31+-
000+
ooo+-
000+-
575+-
^l'
4^
0.
1.
0.
9.
167
11.
0.
0.
0.
0.
0.
o;
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
65.
0.
1 .
0.
0.
342
773
667
1 40
705
943
.95
304
067
0 1 9
014
035
023
013
0 1 6
017
133
0 1 9
137
02 1
027
030
113
096
093
127
195
243
503
3 1 0
66 1
022
034
270
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
o
o
76.
Ci
0.
0.
0.
000+-
000+-
000+-
236+-
723+-
00 OH
000+-
000+-
000+-
006+-
003+ -
073+-
0 1 5+-
0 1 0+-
010+-
003+ -
129+-
010+-
OOOH
000+-
000+-
OOOH
000+-
077+-
00 On
000+-
000+-
OOf*H
OOOH
963+-
OOOH
000+-
000+-
307+-
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
6,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(-)
o
o.
o
0.
0.
157
153
037
063
039
543
251
623
004
00 1
001
005
00 1
00 1
001
001
007
00 1
0 1 0
00 1
001
002
006
005
005
007
Oil
0 1 ;-;
622
Ci :":,-'-
002
015
115
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 4A
PARTICLE SIZE: C
ANALYSIS ID: AC004 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 399+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
(")
C)
0.
0.
0.
0.
0.
o
0 .
0.
51.
0.
0.
0.
0.
250+-
40 OH
000+-
773+-
483+-
000 H
OOOn
OOOn
00 OH
006+-
003+-
233+-
009+-
004 H
00 6 H
00 3 H
071+-
007+
00 OH
OOO +
OOOH
000 H
000+ -
039+-
00 OH
000+-
OOOn
OOOn
OOOn
126+-'
111+-
OOOn
000+
037+-
0.
0.
0.
0.
0.
0.
11.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 ,
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
1 36
210
04S
OS: 3
053
673
361
572
005
002
002
020
002
002
002
002
009
002
01 1
003
003
004
014
Oil
Oil
0 1 6
020
025
200
671
104
159
004
013
1.
2 .
0.
4.
t;
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
323.
0.
0.
0.
0.
605n
563+-
00 OH
503-1-
101+-
000+-
OOOn
OOOn
OOOn
039+-
022+-
847+-
061+-
027+-
040+-
019+-
458+-
043+-
00 OH
OOO+
OOOn
00 OH
000+-
253+-
000+-
000+-
000+
000+-
000+-
22S+-
715+-
OOOn
OOOn
559+-
0.374
1.351
0.307
0 . 536
0.. 34 1
4.323
72.940
3. 673
0.033
0.01 3
0..012
0.131
0 .015
0.01 2
0.011
0 .011
0 . 053
0 . 0 1 1
0.071
0 . 0 1 6
0 . 02 1
0 . 023
0.091
0.072
0 . 069
0. 100
O 1 ^'P:
V J- j_ '_.'
0. 159
1 . 236
29 . 937
0.671
1.01 3
0. 026
0 . OS 1
0
o
0
1
0
o
o
o
o
0
o
o
0
o
0
o
o
<5
O
o
o
».'
0
0
0
0
0
(")
n
o
32
0
o
0
0
. 402n
. 643+-
. OOOn
.251+-
.777+-
. 00 OH
. OOOn
. OOOH
. OOOn
. 0 1 0+-
. 006n
. 463+-
.015+-
. 007+-
..010+-
. OOFiH
. 115+-
.011 +-
. O O(")+-
. ooo+
OOO+
. 000+-
. OOOn
. 063+-
. OOOn
. OOO+-
OOO+
. OOOH
. OOOn
. 240+-
. 1 79+-
. 000 +-
. 000+-
. 140+-
0.
0.
0.
0.
0.
1.
13
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
(") _
o
*_'
0.
0.
0.
0.
o
(-)
l.'
n
0.
7.
0.
0.
0.
0 .
219
339
077
133
088
033
jL. O
920
008
003
003
035
004
003
003
003
015
00"-;
0 1 8
OO4
OO5
006
023
0 1 8
017
O21=;
(") 1~! '"'
040
791
1 63
255
007
02 1
116
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 4A
PARTICLE SIZE: F
ANALYSIS ID: AF130 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
2639-t 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
5.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
329.
0.
0.
0.
0.
000+-
000+-
OOO-i
032+-
038+-
000+-
000+-
000+-
000+-
024+-
03 1 +-
524+-
058+-
037+-
043+-
013+-
372+-
032+-
000+-
000+-
000+-
000+-
000+-
308+-
000+-
000+-
000+-
000+-
000+-
259+-
000+-
000+-
055+-
800+-
0 . 584
0.594
0. 151
0.247
0. 159
2. 153
37.027
1.710
0.017
0.004
0.003
0.027
0.004
0.003
0.003
0.003
0.02.1
0.003
0.041
0.004
0.005
0.005
0.021
0.013
0.019
0. 024
0.032
0.047
0. 106
15.37S
0. 106
0. 164
0.006
0.039
0.
0.
0.
32.
19.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
2113
0.
0.
0.
5.
000+-
000+-
000+-
305+-
505+-
000+-
000+-
000+-
000+-
157+-
200+-
363+-
372+-
236+-
273+-
116+-
336+-
20S+-
000 H
000+-
00 OH
000+-
000+-
977+-
000+-
000+-
000+-
000+-
000+-
. S5+-
000+-
000+-
351+-
133+-
ti
- »
si'
0.
1.
1.
13.
237
10.
0.
0.
0.
0'.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
98.
0.
1.
0.
0.
747
811
971
584
0 1 8
, , .-, .-,
C'ji.0
-71
981
112
028
016
173
028
020
021
013
1 33
019
265
023
033
035
132
117
122
154
205
300
633
727
68 1
050
038
250
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(')
0.
0.
0.
80.
0.
0.
0.
0.
000+-
000+-
000+-
224+-
739+-
000+-
000+-
000+-
000+-
006+-
008+-
127+-
014+-
009 +-
010+-
004+-
090+-
008+-
000+-
OOOn
000 H
00 OH
000+-
075+-
000 H
OOOH
000+-
000+-
000+-
104+-
000+-
000+-
013+-
195+-
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
~0.
0.
o,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
'"I
0.
0.
0.
0.
142
144
037
060
03'?
524
008
416
004
001
00 1
007
00 1
001
00 1
001
005
00 1
0 1 0
001
001
001
005
004
005
006
003
Oil
026
754
026
040
001
009
117
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 48
PARTICLE SIZE: C
ANALYSIS ID: CCOS1 - Nuclepore
DARK PARTICLES ON BACK OF FILTER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 937+- 10 MICROGRAMS
ELEMENT
AL
' SI
F
S
CL
K
CA
TI
V
CR
MN
FE
NI
CIJ
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB :
BA
LA
HG
PB
UG/CM2
UG/FILTER
PERCENT
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Oc
0.
0.
0.
0.
0.
0.
0.
0.
0.
:2.
0.
0.
0
0.
250+-
350-1
000+-
000+-
000+-
000+
000+-
000+
000+
009+-
382+-
023+-
009+
0 1 5+-
007+-
144+-
0 1 1 +-
OOO-i
OOO-i
034 +
025-i
OOO-i
119+-
OOO-i
000 +-
000+-
000+
OOO-i
631+-
000+-
029-i
OOfH
209-1
0.
0.
0.
0.
0.
1.
19.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
()
o.
0.
0.
0.
0.
0.
0.
0.
0.
7.
0.
0.
0.
0.
334
473
053
131
088
217
314
915
003
003
002
025
003
002
002
002
012
002
0 1 8
OO:~:
004
004
017
0 1 5
014
0 1 9
026
034
066
823
119
1 36
005
01 S
1.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^ .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
737.
0.
0.
(-)
1.
605+-
247+-
000+-
000+
000+-
OOO-i
000+-
ooo-<
OOO-i
039+-
055+-
455+-
150+-
055+-
093+-
043+-
923+-
072+-
000+
000+
221+-
1 58+-
000+-
765+-
000+-
OOO-i
OOO-i
OOO-i
OOO-i
239+-
OOO-i
136+-,
OOfH
343+-
T»
^~
3.
0.
0.
0.
7.
123
5 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
50 .
0.
1 .
0.
0.
466
038
374
340
563
810
. 99
376
053
013
0 1 3
1 58
020
015
014
0 1 3
079
015
1 1 6
02 1
027
028
107
094
089
125
170
220
421
256
764
191
032
117
0.
0.
0.
0.
0.
0.
0*
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o".
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
79.
0.
0.
0.
0.
1 63+-
228+-
000 +-
OOO-i
00 0+ -
000+-
000+ -
OOO-i
00 OH
004 +
006+-
249+-
015+-
006+-
010+-
004+-
094H
007-i
000+
OOO-i -
022+-
016+-
OOO-i
077+-
OOO-i
00 OH
OOO-i
000+-
000+
757+-
000+-
019+-
()(-iO+_
136+-
0.
0.
0.
0.
0.
0.
12
0.
fi
0.
0.
0."
0.
0.
0 .
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
IT
0.
0.
("I
o.
250
3 OS
038
085
057
791
. 56
595
oos
002
001
0 1 6
002
002
001
001
003
001
012
002
003
003
0 1 1
0 1 0
009
0 1 3
017
022
043
155
077
121
Of)'"1
012
118
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO.
PARTICLE SIZE: F
ANALYSIS ID: AF129 - Teflon
4B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
2169+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
C;
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
4.
~'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
265.
0.
0.
0.
0.
000+-
000+-
000+-
247+-
532+-
000+-
OOO-i
000+-
000+-
018+-
026-1
428+-
048+-
036+-
033+-
017+-
283+-
023+-
074+-
042+-
067+-
057+-
235+-
277+-
180+-
222+-
320+-
652+-
795+-
790+-
188+-
496+-
064+-
751+-
0.
0.
0.
0.
0.
1.
31.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
12.
0.
0.
0.
0.
503
503
126
211
134
811
392
509
0 1 3
004
003
023
004
003
003
003
017
003
005
004
005
005
020
018
016
021
029
043
094
418
113
181
007
037
0.
0.
0.
27.
16.
0.
0.
0.
0.
0.
0.
2..
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
1.
1.
1.
rfil
4.
11.
1 706
1.
3.
0.
4.
000+-
000+-
000+"-
264+-
253+-
000+-
000+-
000+-
000+-
114+-
164+-
749+-
306+-
230+-
213+-
109+-
817+-
177+-
476+-
271+-
432+-
367+-
510+-
777+-
155+-
422+-
055+-
189+-
526+-
. 37+-
206+-
135+-
414+-
823+-
3.230
3. 230
0.807
1 . 354
0.358
1 1 . 627
201.54
9.689
0 . 08 1
0.023
0.016
0. 146
0.025
0.021
0.018
0 . C,} i ,3
0.111
0 . 0 1 9
0.030
0 . 023
0 . 03 1
0 . 033
0. 127
0.115
0. 104
0. 133
0. 139
0.273
0.606
79.724
0 . 758
1 . 1 64
0.043
0.237
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
"o:
0.
0.
0.
0.
0.
0.
0.
73.
0.
0.
0.
0.
000+-
000+-
000+-
257+-
749+-
000+-
OOO-i
000 +
000+-
005+-
008+-
127+-
014+-
01 !+-_
0 1 0+-
00=;+-
034+-
003+-
022+-
013+-
020-1
017+-
070+-
032+-
C53+-
066+-
095+-
1 93+-
531+-
675+-
056+-
147+-
019+-
222+-
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
149
149
037
063
040
536
292
447
004
00 1
00 1
007
00 1
00 1
00 1
001
005
001
00 1
001
00 1
002
006
005
005
006
009
0 1 3
028
694
035
054
002
Oil
119
-------
SAMPLE ID= HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 5A
PARTICLE SIZE: C
ANALYSIS ID: AC005 - Teflon
LARGE BLACK PARTICLE NEAR EDGE OF FILTER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 353+- 10 MICROGRAM3
ELEMENT
SI
p
0
CL
K
CA
TI
V
CR
MN
FE
IMI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
41.
((
0.
0.
0.
UG/C.M
000+-
000+-
OOOH
654+-
344+-
OOO-i
OOO-i
000+
000+-
003-1
001+-
049+-
006-1
004+-
003-1
002-i
044+-
003 H
016+-
004+
000+-
OOO-i
OOO-i
026+-
00 0+
OOO-i
OOO-i
OOO-i
000+-
541+-
OOOH
000+-
00 OH
051+-
2 UG /FILTER
0.
0.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
146
136
033
065
033
474
800
400
004
002
002
007
002
002
00 1
00 1
007
002
003
002
003
004
014
Oil
Oil
015
020
023
170
257
107
166
004
009
0.
0.
0.
4.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
- 0.
0.
0.
0.
0.
0.
0.
0.
0.
266.
0.
0.
0.
0.
OOO-i
OOO-i
000+-
197+-
206+-
000+
000+-
000+
000+-
018+-
003+-
317+-
038+-
027+-
017+-
015+-
232+-
020+-
100+-
029+-
OOO-i
OOOH
00 OH
170+-
000+-
000+-
00 0+
000+-
000+-
693+-
OOO+
000+-
000+-
32C+-
0.
0.
0.
0.
0.
-'
50 .
2.
0.
0.
0.
0.
0.
'0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
20.
0.
1.
0.
0.
935
871
214
417
244
042
073
563
023
Oil
01 1
045
013
012
009
009
042
010
020
0 1 6
020
023
092
070
069
093
126
146
092
909
686
063
025
057
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
- o.
0.
0.
0.
0.
0.
0.
("1
0.
74.
0.
0.
0.
0.
PERCENT
OOO-i
000+-
OOO-i
1 72+-
616+-
OOOH
000+-
OOO-i
OOOn
005+-
001+-
089+
011+-
008+-"
005+-
004 H
079+-
006+-
023+-
OO8+
000+-
000 +-
000+-
047+-
000+-
OOO-i
000+-
(")OOH
000+-
472+-
OOO-i
OOO-i
000+-
091+-
0
0
0
o
0
o
1
o
0
o
o
o
0
o
0
o
o
o
0
o
0
o
0
0
0
0
0
o
o
6
o
0
(I)
o
. 26 1
.243
. 060
. 121
. 070
. 849
3. 93
.717
. 006
. 003
. no:';
. 0 1 3
. 004
. 003
. 003
. 003
.012
. 003
. 006
. 004
. 006
. 006
. 026
. 020
. 0 1 9
. 026
. 035
. 04 1
. 305
. 1 93
1 V~>
i .' J__
. 297
. 007
. 0 1 6
120
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 5.A
PARTICLE SIZE: F
ANALYSIS ID: AF132 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1519-1 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
C;
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
3.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
184.
0.
0.
0.
0.
000+-
000+-
000+-
069+-
810+-
000+-
000-*
000+-
000+-
013+-
019+-
200-f
030+-
020+-
021+-
0 1 3+-
131 +-
017+-
000+-
000-f
000-t
000+-
000+-
173+-
000+-
000+-
OOO-i
000+-
000+-
327+-
000+-
OOOH
000+-
351+-
0.
0.
0.
0.
0.
1.
22.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
362
352
037
155
097
301
317
530
009
003
002
012
003
002
002
002
012
002
013
003
003
004
0 1 6
012
0 1 3
017
022
032
067
642
063
127
005
019
0.
0.
0.
19.
11.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1 1 36
0.
0.
0.
2 m
000+-
OOO+-
000+-
702+-
613+-
000+-
000+-
000+-
000+-
086+-
1 2 1 +-
28 1 +-
191+-
130+-
134+-
081+-
159+-
1 1 0+-
OOO-i
000+-
000-(
000+-
(-)() (-)_4
146+-
000+-
000+-
OOOn
OOO-i
OOO-i
. 59+-
000+
000+-
000+-
256+-
2
^
0
0
0
11
14
10
o
0
0
0
0
'0
o
0
o
0
0
0
0
0
o
0
o
0
o
0
0
55
0
0
0
0
. 325
.261
.561
.992
.625
. 563
3 . 27
. 141
. 053
.017
. 0 1 2
.077
.013
.014
. 0 1 3
.013
. 074
.013
.116
.016
. 022
. 023
. 101
. 073
. 035
. 107
. 140
. 203
. 433
. 483
. 534
.317
. 030
. 119
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
- 0.
0.
o
0.
0.
0.
0.
0.
0.
73.
0.
0.
0.
0.
000+ -
OOO-i
000+-
297+-
765+-
000+-
OOO-i
OOO-i
000+-
006+-
003+-
084+-
013+-
009+"=-"
009-1
005+-
076+-
007 + -
000+-
OOO-i
000+-
000+-
OOOH
075+-
000 + -
000 +-
000 H
000 +-
000-t
122+-
000+-
000+-
000+-
149+-
0. 153
0. 149
0 . 0:37
0. 066
0.041
0.761
9.433
0.663
0.004
0 . 00 1
0. 001
0 . 005
0. 001
0. 001
0 , 00 1
0 . 00 1
0, 005
0. 001
0. 003
0.001
0 . 00 1
0.002
0. 007
0 . 005
0.006
0 . 007
O. ("X") 9
0.013
0. 028
3.689
0.035
0.054
0. 002
0.008
121
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 5B
PARTICLE SIZE: C
ANALYSIS ID: CCOS'2 - Nudepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
726-1 10 MICROGRAM:;
ELEMENT
UG/CM:
UG/FILTER
PERCENT
AL
rn U
SI
P
s
CL
i..
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
O
»-'
0.
0.
1.
0.
(-J
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
93.
0.
0.
O
0.
[-)(-) (]-!
000+ -
OOO-i
43?+-
917+-
[-)(-,() +
OOO-i
OOOH--
000+-
003n
011+-
106-1
012+-
0 1 0+-
003-i
004-1
035+-
007+-
023 +-
OOO-i
OOOn
000+-
OOO-i
OOOH
000+-
OOO-i
OOO-i
OOO-i
000 +
239+-
00 OH
000+
OOO + -
151 +-
0.
0.
0.
0.
0.
0.
14.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
212
19'":'
043
101
066
343
1 37
697
006
002
002
0 1 0
003
002
002
002
009
002
003
003
004
004
016
0 1 3
012
0 1 6
023
029
049
637
117
1 S:]:
004
0 1 3
o.
0.
0.
9.
5 .
0 0
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
(>.
0.
0.
0.
0.
0.
0.
0.
0.
593.
0.
0.
0 .
0.
OOO-i
OOOH
000+-
236+-
335+-
000+
OOO-i
000+-
000 H
01 9-i
069 H
631+-
075+-
O^SH--
053+-
028-1
546+-
047+-
150+-
OOO-i
000+
000+-
OOO-i
00 0+
000+-
000+-
OOO-i
000+
000 +
597+-
OOO-i
000+-
OOOn
971+-
1 .
1.
0.
0.
0.
5.
9 0 .
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
36 .
0.
1.
0 .
o
364
236
277
652
423
443
763
472
039
015
012
062
0 1 3
0 1 3
Oil
Oil
056
012
022
020
025
026
102
034 -
075
105
145
133
3 1 6
1 9 1
751
1 76
027
O i-::":
O
0.
0.
1.
0.
o
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
(-)
32.
o
0.
(")
*-' B
0.
OOO+-
000 + -
OOO-i
272+-
810+-
OOO + -
000 H
000+-
000-f-
003+ -
0 1 OH
094+-
0 10+-
00 9n
007+-
004+--
075+-
006+-
021+-
OOO-i
000 +-
OOOn
OOO-i
000+
000+-
000+-
000+-
OOO+-
OOOH
439+-
OOO-l
000+ -
,,,-,.-.,
134+-
0 . 1 38
0. 170
0.033
0.091
0. 059
0. 750
12. 50
0 . 6 1 6
0. 005
0. 002
0 . 002'
0. 009
O. 002
0 . 002
0. 002
0. 00 1
0 . 003
0. 002
0 . 0 0 3
0. 003
O . O O:"::
0 . 004'
0 .014
0 . 0 1 2
0 . 0 1 0
0 . 0 1 4
0 . 020
0. 026
0. 044
5. 112
0. 103
0. 162
O . OO4
0 .012
122
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 5B
PARTICLE SIZE: F
ANALYSIS ID: AF131 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1159+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
C- T
_ A.
P
C'
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
TI
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
147.
0.
0.
0.
0.
000+-
000+-
000+-
427+-
456+-
000+-
000+-
000+-
000+-
009H
011+-
172+-
023+-
022+-
017+-
OO/-.H
146+-
013+-
OOOn
000+
000 +-
00 OH
OOOH
136+-
QQQ + -
000+-
000+
OOOH
000+-
733+-
070+-
000+-
000+-
3 1 3+-
0.
0.
0.
0.
0.
1.
17.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
292
-H-I.-.
^-'-'j.
.076
125
oso
036
809
865
007
002
002
Oil
003
002
002
002
0 1 0
002
015
003
003
004
014
Oil
012
0 1 6
021
023
056
912
089
143
004
017
0.
0.
0.
15.
9.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
o..
0.
0..
0.
0.
0.
0.
0.
0.
943.
0.
0.
0.
o
j. .
000+-
000+-
000 H
582+-
346+-
00 OH
000+-
000+-
000+-
057+-
071+-
105+-
146+-
138'+-
112+-
033+-
939+-
081+-
000 H
00 0+
OOOH
OOOn
000+-
874+-
000+
000+-
00 OH
OOOn
000+-
444+-
449+-
000+-
000+-
012+-
1 . 873
1 . 309
0.487
0.803
0.511
6.653
114.33
5.555
0.047
0 .014
0 . 0 1 1
0. 070
0 . 0 1 6
0 . 0 1 5
0 . 0 1 3
0 .011
0.066
0.012
0.097
0 . 0 1 6
0.022
0.023
0 . 093
0.072
0.074
0 . 1 05
0. 136
0. 132
0.357
44.377
0.569
0 . 9 1 3
0 . 023
0. 109
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
o
0.
" 0.
0.
0.
0.
0.
0.
o
o
0.
81.
0,
0.
0.
0.
OOOn
000+-
000 H
345+-
806 +-
000+ -
OOOn
000+-
000+-
005+-
006+ -
09 5+ -
013+-
012+-"
010+-
003n
OS1+-
00.7 +-
OOOH
000+-
000 H
OOOn
00.0+-
075+-
OOOn
OOOH
OOOH
OOO+-
OOOH
341+-
039 H
000 +-
OOOn
174+-
0.
0.
0.
0.
0.
0.
9<
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
o
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
'
0.
0.
0.
0.
1 62
156
042
070
045
574
866
479
004
001
00 1
006
(1)0 1
00 1
00 1
00 1
006
001
(>(">:-;
001
002
002
003
006
Of) A
009
0 1 2
0 1 6
0:3 1
894
049
079
002
0 1 0
123
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 6A
PARTICLE SIZE: C
ANALYSIS ID: AC006 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
307+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
42.
0.
0.
0.
0.
OOOn
000+-
000+
715+-
376+-
000+-
00 OH
000+-
000+-
004+-
004H
060n
005+-
002+
OOAn
002+-
043+-
004+-
00 OH
OOOH
OOOn
OOOn
00 OH
03 1 +-
OOOn
OOOn
000+-
000+-
000 H
0 1 1 +-
OOOH
063+-
014+-
050+-
0.
0.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
' '
0.
0.
0.
0.
134
134
032
066
OSS
44S
704
'"3SS
004
002
002
008
002
002
00 1
00 1
006
002
OO:=:
002
003
003
014
Oil
010
014
0 1 9
023
170
1 33
102
163
004
OOS
0.
0.
0.
4.
2
0.
0.
0.
0.
0.
0.
0.
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
269-
o.
0.
0.
0.
000+-
000+-
000+-
539+-
4 16+-
00 OH
000+-
000+-
OOOn
024+-
024+-
O^plH
O3OH
015+-
036+-
014+-
276+-
025+-
00 OH
000 H
OOOn
000+-
000+
196+-
OOOn
000+-
OOOn
000+-
OOOn
70 9 H
OOOn
439+-
OS7+-
31S+-
0.
0.
0.
0.
0.
^1 0
49.
"T-'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
1.
20.
0.
1.
0.
0.
863
363
204
423
245
876
463
474
023
Oil
Oil
049
013
Oil
0 1 0
009
040
010
053
016
020
022
089
06S
065
091
121
149
092
115
653
048
023
053
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
<)
0.
"o.
0.
0.
0.
0.
0.
0 .
0.
0.
87.
0.
0.
0.
0.
000+-
OOO+-
000+-
493+-
786+-
OOOn
OOOn
OOOH
000+
00 SH
003 + -
125+-
010+-=-
OOS-t
012+-
004+-
09 OH
008+-
OOOn
000+-
000+-
OOOn
000+
064+-
000+-
000 + -
000+-
OOOn
000+-
726+-
000+-
143+-
023+-
103+-
0 . 28 1
0 . 28 1
0 . 066
0. 146
0. 084
0. 935
1 6 . 09
0.805
0.007
0.004
0 . 004
0.01 6
0.004
0 . 004
0. 003
0. 003
0 . 0 1 3
0.003
0 .017
0 . 005
0 . 007
0.007
0 . 029
0.022
0 . 02 1
0.029
0 . 039
0.049
0. 355
7- 133
0 .212
0.341
0 . 007
0 . 0 1 8
124
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS ID: API34 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1356+- 10 MICRQGRAIti
ELEMENT
UG/CM2
UO/FILTER
PERCENT
AL
SI
P
!
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
2.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
161.
0.
0.
0.
0.
000+-
000+-
000+-
817+-
592-1
000+-
000+-
000+-
000+-
011+-
012+-
229+-
03 1 +-
023H
015+-
010+-
166+-
017+-
000+-
000+-
000+-
000+-
000+-
151+-
000+-
000+-
OOQ+-
000+-
OOO-i
844+-
000+-
000+-
000+-
269+-
0.
0.
0.
0.
0.
1.
19.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
7.
0.
0.
0.
0.
312
312
079
142
087
137
419
976
008
002
002
0 1 3
003
002
002
002
Oil
002
0 1 6
003
C)03
004
014
Oil
012
016
023
029
057
570
082
130
004
015
0.
0.
0.
18.
10.
0.
0.
0.
0.
0.
0.
1 .
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
1039
0.
0.
0.
1.
000+-
000+-
000+-
087+-
219+-
000+-
000+-
000+-
000+-
071+-
078+-
469+_
201+-
147+-
096+-
067+-
064+-
112+-
000-t
000+-
000+-
000+-
000+-
968+-
000+-
000+-
000+-
000+-
000+
.04+-
000+-
000+-
OOO-i
729+-
2.
o
Ji. .
0.
0.
0.
7.
124
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
43.
0.
0.
0.
0.
002
002
505
914
558
299
.67
266
053
0 1 6
0 1 0
086
019
015
Oil
0 1 2
068
013
1 03
0 1 6
020
023
093
072
075
101
146
139
363
602
529
C;C;=;
024
096
0.
0.
0.
1.
0.
0.
0.
0.
'-'..
0.
0..
0.
0.
0.
0.
0.
0.
0.
0
0.
o-.
0.
0.
0.
0.
0.
0.
0.
o
76.
0.
0.
0.
0.
000+-
000+-
000+-
334+-
754+-
OOO-i
000+-
000+-
OOO-i
005 +-
00 6+ -
108+-
015+-
0 1 1 +-
007+-
005-1
078+-
008 +-
OOCn
000 + -
OOO-i
000+-
000+-
071+-
000+-
000+ -
000+-
000+-
(")O(")H
651+-
OOOH
00 0+ -
000+-
12S+-
0 . 1 48
0. 148
0.037
0 . 063
0.042
0.533
9. 197
0.462
0 . 004
0 . 00 1
0 . 00 1
O. DC)/-.
0 . 00 1
OY001
0. 001
0 . 00 1
0 . 005
0 . 00 1
0 . 003
0 . 00 1
0 . 00 1
0.002
0.007
0 . 005
0.006
0 . 007
0.011
0.014
O O27
3.630
0.039
0 . 062
0 . 002
0. 007
125
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 6B
PARTICLE SIZE: C
ANALYSIS IDs CCOS3 - Nuclepore
MASS:
ELEMENT
SI
p
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
AREA:
6,42 SQUARE
709+- 1-0
UG/CM2
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
("1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
84.
0.
0.
0.
0 =
00 CH
000+-
000+-
366+-
901+-
0 0 o+
OOOn
000+-
000+-
014+-
010+-
115+-
008+-
0 1 1 +-
007+-
OOS + -
071+-
012+-
O(")(")H
013+-
OOOn
OOOn
000+-
102+-
000+-
000+-
OOOn
000+-
000+-
123+-
071+-
000 +-
000+-
135+-
a.
0.
0.
0.
0.
0.
13.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
1 O'~'
162
044
096
064
767
114
656
006
002
002
0 1 0
003
002
002
002
OOS
002
0 1 0
00:3
004
004
0 1 6
0 1 3
012
0 1 6'
022
023
049
056
US
1 32
004
012
0.
0.
0.
8.
«,' M
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
540 .
0.
0.
0.
0.
CM
MICROGRAMS
UG /FILTER
000+-
000+-
000+-
767+-
732+-
000 +
000+-
000+
000+-
088+-
062+-
741+-
054+-
07 1 +-
047+-
031+-
457+-
076+-
000+-
086+-
00 OH
000+-
OOOn
655+-
000+-
000+-
000+-
000+-
OOOn
071+-
457+-
000+-
000+-
367+-
1.
1.
0.
0.
0.
4.
S4.
4.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^2.
0.
1.
0.
Oc
1 69
043
"» " "
ji. O -'
618
409
922
1 89
209
036
0 1 5
012
065
017
0 1 3
Oil
01 1
051
013
065
018
024
025
1 0 1
085
075
106
1 43
181
313
456
760
170
026
077
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
76.
0.
0.
0.
0.
PERCENT
00 OH
00 OH
000 H
236+-
815+-
000+-
000 H
00 0+ -
000+
012+-
009 +-
104+-
008+-
010+-
007+-
004n
064+-
0 1 1 +-
000 +
0 1 2+-
OOOn
000+-
000+-
092+-
OOOn
00 OH
00 OH
00 OH
00 OH
162+-
064+-
000+-
000 +-
1 "'"? -4__
1 i.^.^
0.
0.
0.
0.
0.
0.
11
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("I
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
165
147
040
039
059
694
.37
594
005
002
002
009
002
002
001
002
007
002
DO'-'
003
003
004
014
012
Oil
015
020
025
045
701
107
165
004
0 1 1
126
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - TEST NO. 6B
PARTICLE SIZE: F
ANALYSIS ID: AF133 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1009+- 10 MICROGRAM:;
ELEMENT
UC-/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI.
V
CR
MN
FE
IMI
CU
ZN
CA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0 . 000+-
0.000+-
0.000+-
2.250+-
1.272+-
0. 000 H
0.000+-
0.000+-
0.000+-
0.01 0+-
0.011+-
0. liB7+-
0 . 022+-
0.014+-
0.015+-
0.007+-
0. 1 13+-
0.011+-
0 . OOOn
0 . 000+-
0 . 000+-
0 . 000+-
0 . OOO-i
0. 131+-
0.000+-
0.000+-
0 . 000+-
0 . OOO-i
0. OOO-i
1 27.631+-
0. OOO-i
0. OOQH
0 . 000+-
0.252+-
0.252
0.252-
0.065
O . 1 1 6
0.071
0.916
15.595
0.775
0.007
0.002
0.002
0 .011
0 . 002
0.002
0.002
0 . 002
0 . 009
0 . 002
0.015
0 . 002
0 . 003
0 . OO:":
0 .014
0.011
0.010
0.014
0 . 020
0.027
0.04S
5.975
o . oss
O. 1.^3
0 . 004
0 .014
0 . 000+-
0.000+-
0.000+-
14.446+-
S. 163+-
0.000+-
0 . OOO-i
0.000+-
0.000+-
0.064+-
0.071+-
1. 199+-
0. 142+-
0.08S+-
0.09S+-
0. 047 +-
0.725+-
0.074+-
0 . 000+-
0.000+-
0 . 000+-
0.000+-
0. 000+
O.S41+-
0.000+-
0.000+-
0. 000+ -
0. 000+-
0.000+-
S19.3SS+-
0. OOO-i
0. OOO-i
0.000+-
1.61 7+-
1.615
1.615
0.415
0.74S
0.455
5'. S7S
100. 12
4.974
0.043
0 .014
0.010
0. 074
0.016
0.012
0.012
0.011
0 . 056
0 .011
0.097
0.013
0.019
0 . 022
n . O9O
0 . 070
0.067
0 . 093
0. 127
0. 171
0.311
oo -'<=.-
-,'1-' . -.»_' _'
n . SAP;
0 . S55
0.026
0.092
0 . 000+-
0. 000+-
0. 000+ -
1 . 432+-
O.S09+-
0. 000 +-
0. 000+ -
0. 000 +-
0. OOO-i
0.006+-
0.007+-
0. 119+-
0.014+-
0. 009-1
0.010+-
0.005+-
0. 072-t
0.007+-
0. 000+ -
0. OOOn
0". OOOn
0. 000+-
0. OOO-i
O.OS3+-
0. OOO-i
0 . 000+-
0 . OOO-i
0. OOO-i
0. 000 H
81.217+-
0. OOO-i
0. OOO-i
0 . OOO-i
0. 160+-
0. 160
0. 160
0.041
0.075
0.046
0 . 583
9.924
0.493
0.004
0. 001
0. 001
0.007
0. 002
0.001
0. 001
0 . 00 1
D. OD A
0. 001
0 .010
0.001
0. 002
0 . 002
0 . 009
0 . 007
0.007
0 . 009
0.013
0 .017
0 . 03 1
3. S3 6
0. 056
O. Oft 5
0 . 003
O . OO9
127
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - FIELD BLANK
PARTICLE SIZE: F
ANALYSIS ID: AF245 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
C'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
2N
GA
AS
SE
BR
R5
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
013+-
00 SH
002+-
OOO-i
000+-
OOO-i
000 H
001+-
000+-
OOO-i
001+-
005+-
000+-
001+-
000 i
001 + -
000 H
000 H
001+-
O(")<"H
001+-
00 1 +-
015+-
000+
00 0+
002+-
002 H
013+-
000+-
051+-
233-1
140+-
OOl-i
00 1 +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0 1 0
007
003
019
006
002
002
00 1
001
00 1
00 1
003
00 1
00 1
001
00 1
003
00 1
00 1
002
002
002
0 1 0
007
006
00 S
012
014
0 1 6
03 1
080
120
002
004
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
099-i
052+-
011+-
OOO-i
000+ -
000+-
OOO-i
006-1
003+-
OOO-i
009-1
033+ -
OOO-i
008+'-
000+
00 7 H
000+-
002+-
007H--
003 H
005+
007+-
096 +-
000 -f
OOO-i
015+-
011+-
115+-
000+-
325+-
527+-
897+-
007+-
004+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0'.
0.
0.
0.
()
0.
o
\>' «
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
065
043
022
1 20
038
0 1 3
Oil
007
005
006
007
0 1 9
(ID/-.
003
005
005
0 1 6
O(V-,
003
0 1 (.">
0 1 2
015
064
044
037
054
076
037
105
200
512
772
Oil
027
128
-------
SAMPLE ID: HARS.HAW/ANTIMONY OXIDE ROASTING - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC080 - Teflon
PIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
C;
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0 . 000,+-
0.001+-
O.OQO+-
0.000+-
0.011+-
0 . 000+-
0. 000+-
0.000+-
0.000+-
0. 000 +-
0 . 000+-
0 . 003+-
0. 000+ -
0.000+-
0.001+-
0.002+-
0 . 000+-
0 . 000+-
0. 000+-
0. 000 +
0. 000 +-
0 . 000+-
0. 000+-
0 . 000+-
0.000+-
0 . 000+-
0.017+-
0.019+-
0.000+-
0 . OOOn
0. 112+-
0. 000+-
0.000+-
0.006+-
0.013
0.010
0.004
0.021
0.007
0.003
0.002
0.001
0.001
0 . 00 1
0.001
0 . 003
0 . 00 1
0 . 00 1
0.001
0.001
0 . 003
0 . 00 1 '
0.001
0 . 002
0 . 002
0.003
0 .011
0 . OOS
0.006
0.010
0.013
0 . 0 1 6
0.019
0.034
O.OS?
0. 135
0 . 002
0 . 005
0.000+-
0.004+-
0 . 000+-
0.000+-
0.072+-
0.000+-
0.000+-
0.000+-
0.003+'-
0.003+-
0.000+-
0.021+-
0. 0<">fK
0.000+-
0.007+-
0.010+-
0 . 000+-
0. 000+-
0. 000 H
0.003+-
0. 00 OH
0. 000 H
0, 000+-
0. 000+-
0. 000+
0. 00 OH
0. 107+-
0. 122+-
0. 000+-
0. OOOn
0.719+-
0.000+-
0.000+-
0.033+-
0. 034
0 . 06 1
0.025
0. 135
0.. 046
0.013
0.012
0 . 003
0.006
0.007
O. OOP:
0.020
p. 007
O. O C)!-:
0 . 007
0 . 006
0 . 0 1 9
0.007
0 . 009
0 . 0 1 2
0 .015
0 .017
0.072
0.051
0.042
0.064
0 . 086
0. 105
0. 122
0.217
0 . 57 1
0 . 867
0.015
0.032
129
-------
SAMPLE ID: HARSHAW/ANTIMONY OXIDE ROASTING - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: CC125 - Nuclepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
C;
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000+-
006+-
000+-
000 H
000+
000+-
000+
000 +-
001+-
000+ -
OOOH
00 1 +-
000+-
000+-
000 -t
001+-
010+-
000+-
001+-
004+-
001+-
OOOn
OOO+-
000+-
000+-
017+-
00 1 +-
OOOn
OOOn
OOOn
OOOn
OOOH
OOOn
OOOn
0.
'0.
0.
0.
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
024
0 1 9
0 1 0
022
009
003
002
001
001
002
00 1
004
00 1
002
001
00 1
004
001
002
002
003
00:3
014
010
009
012
0 1 S
020
024
043
103
170
003
006
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
(-,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000+-
037+-
ooo +
000+-
000+-
000+-
000+-
000 H
OOS+-
000+-
00 OH
010+-
(1OO+
000+-
OOt'H
005+-
062+-
000+-
00 4 H
027+-
OOS+
OOOH
000+
000+-
OOOn
10S+-
00 7 +-
OOOn
00 OH
OOOn
000+-
000+-
000+
OOOn
0.
0.
0.
0.
0:
0.
0.
0.
0.
0.
o.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
().
o.
0.
t).
1.
0.
0.
157
122
062
140
060
0 1 3
0 1 4
009
006
Oil
0 1 0
024
OO9
0 1 0
006
007
025
0 1 0
014
015
0 1 9
021
OSS
066
056
076
114
126
156
277
694
OS9
0 1 6
040
130
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 1A
PARTICLE SIZE: C
ANALYSIS ID: AC007 - Teflon
DEPOSIT BUILT-UP AT PERIMETER-
EXPOSED AREA: 6.42 SQUARE CM
MASS: 49S1+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZM
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SM
SB
BA
LA
HG
PB
73.
119.
1.
-
0.
9.
10.
6.
0.
0.
0.
66 .
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
859+-
165+-
378+-
487+-
706+-
327+-
502+-
954+_
421+-
360+-
3 1 6+-
114+-
230H
1 79+-
317+-
123+-
243+-
.033+-
OOOn
092 +-
1 32+-
1 1 0+-
219+-
094+-
000+-
007+-
OOOn
005+-
038+-
359+-
352+-
000+-
OOOH
2 00+-
3.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^-!.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
890
202
307
237
073
489
577
364
040
021
017
444
014
Oil
0 1 8
003
0 1 6
003
017
006
062
007
036
0 1 3
0 1 0
015
021
022
028
133
1 39
185
1 00
014
474
758
8
22
4
59
67
44
^
^i
^1
424
1
1
-i
A.
0
1
0
0
0
7
0
1
0
0
0
0
0
o
5
5
0
0
1
. 175+-
. 62 1 +-
. 846+-
. 335+-
. 536+-
. 832+-
. 424+-
. 646+-
.704+-
.314+-
.027+-
. 450+-
.474+-
. 149+-
.-038+-
. 823+-
. 562+-
.210+-
. 000+-
. 590+-
. 589n
. 708+-
. 409+-
. 602+-
. 000 H
. 048+-
. 000+-
. 035+-
. 243+-
.512+-
. 470+-
. 000+-
. 000 *
. 283+-
24.
39.
1.
1.
0.
3.
~s
'
2,
0.
0.
0..
.-^.-,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
974
320
974
520
467
137
703
333
259
132
112
108
090
070
117
052
101 '
022
1 09
039
396
043
234
085
066
094
133
142
177
853
895
189
642
092
9.
15.
0.
0.
0.
1.
1.
0.
0.
0.
0.
8.
0.
0.
0.
0.
0.
-0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
520+-
230+-
178+-
449+-
09 1 +-
202+-
354+-
396+-
054+-
046+-
0.502
0. 800
0.040
0 . 03 1
0 . 009
0 . 063
0 .074
0. 047
O . (")f)S
0 . 003
041+- i'. 002
521+-
030H
023+-
04 1 +-
017+-
031+-
004+-
000+-
012+-
152+-
0 1 4+-
028+-
012+-
000+.-
00 1 +-
000+-
00 1 +-
005+-
111+-
110+-
000+-
000+-
02 6+-
0.444
0 . 002
0 . 00 1
0 . 002
0.001
0.002
0 . 000
0. 002
0. 001
0 . 008
0 . 00 1
0.005
0.002
0.001
0. 002
0. 003
0. 003
0 . 004
0 .017
0 . 0 1 8
0.024
0.013
0.002
131
-------
SAMPLE ID: EDDYSTONE/COAL FIRED POWER PLANT - TEST NO. Ifi
PARTICLE SIZE: F "
ANALYSIS ID: AF135 - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1580+- 10 MI CROC-RAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
c-
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
A »-
MO
SE.
BP
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
34.
51.
1.
7.
0 .
-t>
jlv
2.
0.
0.
0.
20.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
ft
0.
0.
9.
0.
0.
0.
0.
535+-
633+-
437+-
929+-
215+-
056+-
978+-
173+-
179+-
1 42+-
115+-
531+-
088+-
074+-
155+-
055+-
200+-
OSOn
00 OH
026+-
334+-
03 5+-
1 1 H
055+-
000+-
00 OH
OflfH
02 OH
00 OH
422+-
595+-
165+-
OOOn
09'"'+
1.
+L m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0..
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
578
354
261
377
094
150
268
111
013
003
006
941
006
005
008
004
Oil
005
005
003
0 1 6
003
015
009
007
010
014
0 1 5
021
462
097
131
0 1 0
008
222.
331.
9.
50.
1.
19.
19.
13.
1.
0.
0.
131.
0.
0.
0.
0.
1.
0.
0.
0.
ji.
0.
0.
0.
0.
0.
0.
0.
0.
60 .
3.
1.
0.
0.
038+-
803+-
227+-
901+-
33 1 +-
617+-
117+-
931+-
148+-
909+-
741 + -
808+-
566+-
474+-
994+-
353+-
286+-
512+-
OOOn
167+-
144+-
222+-
711+-
353H
000 H
000+-
000 H
126+-
000+-
487+-
820+-
056+-
00 OH
634+-
10.
15.
1.
2.
0.
0.
1.
0.
0.
0.
0.
6,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
*« a
0.
0.
0.
0.
131
110
676
413
602
962
723
710
116
050
040
040
037
031
054
024
071
030
032
0 1 6
103
021
099
055
045
065
087
099
134
963
621
842
064
O5.O
14.
21.
0.
""I
0.
i.
i.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
ft
0.
0.
0.
0.
o
0.
0.
0.
0.
053+-
00 OH
534+-
222+-
087+-
242+-
210+-
835+-
073+-
058 +-
04"7+-
342+-
036+-
030+-
06 3+-
022n
081+-
032+-
OfiOn
0 1 1 +-
136+-
014 + -
045+-
022+-
f)Of)H
000 + -
f)(")( )+
OOSn
00 OH
323+-
242+-
067+-
00 OH
O4fH
0.647
0. 966
0. 106
0 . 1 54
0. 038
0.061
0. 109
0.045
0.007
0 . 008
0. 003
0 . 336
0 . 002
0 . 002
0.003
0 . 002
0. 004
0. 002
0. 00 '2
0 . 00 1
0. 007
0 . 00 1
0. 006
0. 003
0 . 003
0. 004
0. Of) 6
0 . 006
0. 009
0 . 1 89
0. 039
0. 053
0 . 004
ft. OO:":
132
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 2A
PARTICLE SIZE: C
ANALYSIS ID: AC008 - Teflon
DEPOSIT BUILT UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 4074+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
69.
109.
1.
3.
0.
i-*i
c« .
9.
6.
0.
0.
0.
58.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
081+-
938+-
327+-
295+-
583+-
344+-
357+-
123+-
392+-
315+-
273+-
443+-
206+-
156+-
292+-
114+-
220+-
024+-
000+-
078+-
017+-
107+-
196+-
084+-
014+-
033+-
042+-
OOS+-
023+-
333+-
726+-
164+-
000+-
165+-
3 . 638
5.772
0.294
0.219
0.065
0.438
0.500
0.322
0.037
0.013
0.015
3 . 050
0.013
0.010
0.017
0.007
0.014
0.003
0.017
0.005
0.053
0.007
0.032
0.012
0.009
0.014
0.019
0.020
0.025
0.065
0.127
0. 176
0.014
0.013
443.
705.
8.
21.
o
«'
53.
60.
39.
2.
2.
1.
375.
1.
1.
1.
0.
1.
0.
0.
0.
6.
0.
1.
0.
0.
0.
0.
0.
0.
/^l
4^
4.
1.
0.
1.
502+-
801+-
519+-
153+-
777+-
570+-
070+-
344+-
519+-
020+-
783+-
205+-
324+-
003+-
877+-
730+-
413+-
155+-
OOOn
503+-
523+-
687+-
260+-
542+-
092+-
211+-
269+-
050+-
150+-
141+-
664+-
051+-
OOO-i
057+-
23.
37.
1.
1.
0.
2.
o
.t .
2.
0.
0.
0.
19.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
359
059
386
405
419
813
208
066
235
117
099
584
082
063
108
047
092
019
109
034
343
046
207
073
058
092
123
131
161
420
313
131
083
080
10.
17.
0.
0.
0.
1.
1.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
- 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
885+-
323+-
209+-
519+-
093+-
315+-
474+-
966+-
062n
050+-
044+-
209^^-
032+-
025+-
046+-
013+-
035+-
004+-
OOOn
012+-
160+-
017+-
031+-
013+-
002+-
005+-
007+-
Q01+-
004+-
053+-
114+-
026+-
000+-
026+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
574
911
046
035
010
069
079
05 1
006
00:3
002
481
002
002
003
001
002
000
003
001
008
00 1
005
002
001
002
003
003
004
0 1 0
020
028
002
002
133
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF136 - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1506+- 10 MICRGGRAMS
ELEMENT
UG/CM2 .
UG/FILTER
PERCENT
AL
SI
P
'o
CL
K.
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
-~l '"I
-'ji
48.
1.
6.
0.
*L o
--.
2. m
0.
0.
0.
19.
0.
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
"'
0.
0.
O
0.
266+-
425+-
283+-
664+-
153+-
367+-
933+-
033+-
172+-
134+-
1 04+-
325+-
079+-
062+-
1 48+-
052+-
173+-
087+-
OOOH
025+-
322+
029+-
072+-
060+-
008+-
000+-
000 H
026+-
000+-
236+-
421+-
117+-
OOOH
104+-
1.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
473
206
"' '"; ;~;
-; j ;q
079
136
1 63
101
014
007
006
336
005
004
OOS
004
0 1 0
005
005
003
015
003
016
010
007
Oil
015
0 1 3
020
1 O.n_
104
150
0 1 0
00:=:
207.
310.
J-!
42.
0,
ie.
is.
13.
1.
0.
0.
124.
0.
0.
, 0.
0.
1.
0.
0.
0.
2.
0.
0.
0.
0.
0.
n
0.
0.
14.
->
0.
0.
0.
148+-
890H
234+-
786+-
979+-
404+-
832+-
054+-
106+-
863+-
667+-
067+-
504+-
401+-
953+-
334+-
142+-
560+-
00 OH
160+-
064+-
189+-
461+-
388+-
050+-
000 +-
OOOn
1 65+-
000+-
673+-
704+-
74S+-
OOOn
668+-
9.
14.
1.
jL= e
0.
0.
1.
0.
0.
0.
0.
C1
~' .
0.
0.
0.
0.
00
0.
Oo
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("1
0.
455
159
496
045
503
;-;7'~'
08 1
643
088
043
037
637
034
02S
052
023
066
033-
032
017
099
022
101
063
045
071
098
114
131
84S
663
962
O /-,:-:
054
13.
20.
0.
^ 0
0.
1.
1.
0.
0.
0.
0.
o
'«' n
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
o.
759+-
650+-
547+-
342+-
065+-
222+--
251+-
867+-
073+-
057+-
04^r+-
241+-
033+-
027+-
063+-
022+-
076+-
037+-
OOCH
0 1 1 +-
137+-
013+-
031+-
026+-
003+-
000 H
000+
01 1+-
000+-
975+-
180+-
050+-
O(")O-(-
O44-i--
0. 635
0. 950
0 . 099
0. 137
0 . 034
0.058
0.072
0 . 043
0. 006
0. 003
0. 002
0.332
0. 002
0 . 002
0. 003
0. 002
0. 004
0 . 002
0 . 002
0. 001
0. 007
0.001
0. 007
0 . 004
0 . 003
O . OO5
0 . 006
O. OOP:
0 . 009
0. 057
0. 044
0 . 064
0 . 0 0 4
O . OO4
134
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 3A
PARTICLE SIZE: C
ANALYSIS ID: AC009 - Teflon
DEPOSIT BUILT UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 3230+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MIM
FE
NI
CU
ZN
GA
AS
3E
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
61.
97.
1.
o
0.
6.
7.
4.
0.
0.
0.
47.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
444+-
674+-
148+-
838+-
466+-
702+-
351+-
794+-
312+-
258+-
214+-
4 10+-
1 63+-
118+-
225+-
092+-
177+-
023+-
000+-
061+-
792+-
083+-
137+-
075+-
009+-
000+-
0 1 6+-
030+-
025+-
198+-
637+-
000+-
000+-
124+-
3.220
5. 101
0.253
0. 18S
0 . 055
0.352
0 . 39 1
0.253
0.030
0.015
0.012
2.471
0.010
O.OOS
0.013
0.006
0.012
0.003
0.015
0 . 005
0.042
0.006
0.027
0.012,
0.009
0.014
0 . 0 1 9
0.022
0 . 026
0.059
0.1 28
0. 180
0.012
0.011
394.
627.
7.
18.
2.
43.
47.
30.
2.
1.
1.
304.
1.
0.
1.
0.
1'.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
o
*'
1.
4.
0.
0.
0.
469+-
065+-
373+-
220+
994+-
025+-
194+-
778+-
003+-
656+-
371+-
373+-
044+-
758+-
443+-
590+-
1 36+-
1 46+-
000+-
393H
083+-
530+-
880+-
480+-
060+-
000+-
102+-
191+-
1 6 1 H
274+-
092+-
000+-
000+-
793+-
20.
»T'
1.
1.
0.
"T1
rfL. m
1.
0.
0.
0.
15.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0'.
0.
0.
0.
0.
0.
1.
0.
0.
675
746
624
209
355
260
509
626
193
097
07S
861
067
050
086
040
077
018
096
029
267
040
175
079
059
087
123
140
1 68
381
819
155
077
069
12.
19.
0.
0.
0.
1.
1.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
0.
0.
0.
0.
214+-
416+-
228+-
564+-
093+^-
332+-
461+-
953+-
062+-
05 1 +-
042+-
425+-
032+-
023+-
045+-
0 1 8+-
035+-
005+-
000+-
012+-
157+-
0 1 6+-
027+-
015+-
002+-
000+-
003+-
006+-
OOFi-i
039+-
127+-
OOOn
000+-
025+-
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
641
016
050
037
Oil
070
078
050
006
003
002
492
002
002
003
00 1
002
00 1
003
00 1
008
00 1
005
002
002
003
004
004
OOFi
012
025
036
002
002
135
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 3A
PARTICLE SIZE: F
ANALYSIS ID: AF137 - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1114+- 10 MICROGRAMS
ELEMENT
UG/CM;
UG/FILTER
PERCENT
AL
SI
P
c-
w>
CL
K
CA
TI
v
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
FE
25.
37.
1.
5.
0.
~i
-.
1.
0.
0.
0.
14.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
501+-
646+-
054+-
506+-
089+-
189n
089+-
633+-
14 1 -i
098+-
032+-
793+-
070+-
055+-
131+-
042+-
140+-
063+-
OOO+-
019+-
226+-
029+-
080+-
037+-
007+-
000+-
000+-
012+-
OOOn
314+-
000+-
000+-
OOO-i
070+-
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
165
716
191
265
065
105
123
077
0 1 o
006
005
679
005
004
007
003
008
004
005
002
Oil
003
013
007
006
009
012
013
017
108
078
123
008
006
163.
241.
6.
33.
0.
14.
13.
10.
0.
0.
0.
94.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
11.
0.
0.
0.
0.
715+-
685+-
766+-
346+-
569+-
053+-
411+-
486+-
904-t
632+-
526+-
974+-
451+-
35 1 +-
842+-
273+-
896+-
402+-
OOOn
122+-
452+-
188+-
512+-
240+-
046,+-
000+-
000+-
077+-
000+-
647+-
000+-
000+-
000+-
451+-
7.
11.
1.
1.
0.
0.
0.
0.
0.
0.
'0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
482
014
?:'-/
700
418
672
791
496
067
037
030
357
031
025
047
020
053
025
032
014
071
019
08 1
048
036
056
077
087
1 09
695
504
792
050
041
14.
21.
0.
3.
0.
1.
1.
0.
0.
0.
0.
«".
o *
0.
0.
0.
0.
0.
- 0 .
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
69CH
687+-
607+-
172+-
051+-
261+-
203+-
941+-
06: H
057+-
047+
522+-
040+-
031+-
076+-
024+-
080+-
036-f
(~>O("H
0 1 1 +-
130+-
017+-
046+-
022+-
004+-
000+-
OOO-i
007+-
000+-
045+-
000+-
OOOn
OOO-i
040-f
0.6S4
1 . 007
0. 110
0 . 1 5?
0.03W
0. 061
0. 07:;
0. 04';:
(") OO.'.
0. 00
0 . 00
0. 3?'
0. 00-
0. OC
0. O'."--
0. OC'
0. 00
0 o 0;.
0. 0!-
0 . 0-:"
0 . O1
0. 0"
0. O''-
0.0'
0. 0'."
0 . Of" '
0. O1"1
0. O1.' '
o.o-
0. O'.
0.0
0. O"/ -
o. oor.
0. 00-
136
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 4A
PARTICLE SIZE: C
ANALYSIS ID: AGO 10 - Teflon
DEPOSIT BUILT UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 3381+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
2N
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
61.
97.
1.
2.
0.
7.
7.
5.
0.
0.
0.
49.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
605+-
932+-
154+-
917+-
537+-
182+-
826+-
312+-
369+-
269+-
237+-
502n
182+-
125+-
240+-
093+-
195+-
024+-
000+-
066+-
841+-
080+-
122+-
075+-
013+-
000+-
026+-
000+-
000+-
366+-
451+-
000+-
000+-
133+-
3.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
215
09S
252
190
05S
375
418
275
031
016
013
567
Oil
008
014
006
013
003
014
005
044
006
028
013
010
015
020
022
027
073
130
1 89
012
012
395.
628 .
7.
18.
3.
46.
50 .
34.
2.
1.
1.
317.
1.
0.
1.
0.
1.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
2,
2.
0.
0.
0.
507+-
724+-
409+-
727+-
450+-
106+-
240+-
101+-
371+-
725+-
522+-
802+-
171+-
800+-
544+-
599+-
250+-
153+-
000+-
423+-
400+-
517+-
734+-
479+-
084+-
000+-
170+-
000+-
000+-
347+-
894+-
000+-
000+-
883+-
20.
32.
1.
1.
0.
2.
2.
1.
0.
0.
' 0.
16.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
640
727
617
T-'T.""1
371
407
686
769
198
100
086
482
073
052
090
040
083
018
090
031
282
040
182
082
063
094
132
141
172
468
834
211
078
074
11.
18.
0.
0.
0.
1.
1.
1.
0.
0.
0.
9.
0.
0.
0.
0.
0.
-' o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
&9I3+-
595+-
219+-
554+-
102+-
364+-
486+-
009+-
070+-
051+-
045-f-
399+-
035+-
024+-
046+-
018+-
037+-
005+-
000+-
013+-
1 60+-
015+-
023+-
014+-
002+-
000+-
005+-
000+-
000+-
069+-
086+-
000+-
000+-
026 +-
0 .613
0.970
0 . 048
0.036
0.011
0 . 07 1
0 . 080
0.052
0 . 006
0.003
0.003
0.483
0 . 002
0.002
0 . 003
0 . 00 1
0.002
0.001
0 . 003
0 . 00 1
0 . 008
0.001
0 . 005
0 . 002
0 . 002
0.003
0.004
0 . 004
0 . 005
0.014
0.025
0.036
0. 002
0.002
137
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO.
PARTICLE SIZE: F
ANALYSIS ID: AF1SS - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 989+- 10 M1CROGRAMS
4A
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
22 . 900+-
34 . 574+-
0.950+-
5 . 1 43+-
0. 075-*
1.944+-
1 . 944+-
1 . 32 2 H
0. 120+-
0 . 083-1
0.073+-
13.1 20+-
0.053+-
0.047+-
0. 101+-
0 . 03 8+-
0. 121+-
0 . 060-1
0. OOO-i
0.0 15+-
0. 201+-
0 . 022+-
0. 084+-
0.029+-
0. 003H
0.000+-
0.000+-
0.0 14+-
0 . 000+-
2.897+-
0.372+-
0 . 000+-
0 . 00 0+
0.068+-
1 . 047
1 . 576
0. 173
0.24S
0 . 06 1
0.094
0 .131
O. O/-,:-:
0.012
0.005
0. 004
0. 602
0.004
0.004
0. 006
0 . 003
0.007
0 . 004
(") OOA
6.002
0 . 0 1 0
O . on:":
0.012
0 . 007
0 . 005
0.009
0 .011
0 . 0 1 3
0 .017
0. 158
0.079
0. 114
0.007
0 . 006
147.0 16+-
22 1. 967+-
6.097+-
33. 015+-
0. 479-1
12.483+-
12.433+-
8 . 439+-
0.770+-
O.5AA+-
0. 469+-
84.227+-
0.375+-
0.304+-
0.647+-
0.245+-
0.779+-
0. 383-1
0. OOO-i
0. 096+-
1 . 289+-
0. 144+-
0.537+-
0. 134+-
0. 020-1
0 . 000+-
0.000+-
0.092+-
0. 000+-
18.600+-
2.3S9+-
0 . 000+-
0. 000 +
0.434+-
6.724
10. 117
1 . 1 08
1 . 593
0 . 390
0 . 606
0.844
0. 433
0 . 075
0 .034
0 . 027
3 . 866
0.028
0.023
0. 033
0 . 0 1 9
0 . 048
0.024
0 . 03'?
0 . 0 1 2
0.064
0 .017
0.077
0 . 044
O . O :"::"-:
0.055
0.072
0.033
0. 112
1.015
0.503
0.734
0 . 047
0 . 039
14.867+- 0.696
22.446+- 1.048
0.617+- 0. 112
3.339+- 0. 165
0. O4:-:+ ("). 0:":9
1 . 262+- 0.063
1 . 262+ 0. OS6
0.858+- 0.045
0. 078H 0. OOS
0. 057-i 0. 003
0.047H 0.003
8. 5 17+- 0.400
-0.038H 0.003
0.031+- 0.002
0. 065n 0. 004
0 . 025-1 0 . 002
0. 079-i 0. 005
0.039+- 0.002
O. OOOn O. OO4
0.0 10+- 0.001
0. 130+- 0. 007
0 . 0 1 5-i 0 . 002
0.054+- 0.008
0.019-1 0.004
0. 002-1 0. 003
0.000+- 0.006
0.000+- 0.007
0.009+- O.OOS
0.000+- 0.011
1.881+- 0. 104
0.242+- 0.051
O.OOO-i 0.074
O.OOO-i 0.005
0.044+- 0.004
138
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 4B
PARTICLE SIZE: C
ANALYSIS ID: CC084 - Nudepore
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 3783+- 10 MICROGRAMS
ELEMENT
UO/CM2
UG/FILTER
PERCENT
AL
SI
P
C*
'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
66.
104.
1.
3.
0.
7.
S.
5.
0.
0.
0.
S3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
517+-
976+-
048+-
122+-
563+-
892+-
368+-
54 1 +-
348+-
293+-
261+-
556+-
205+-
135+-
276+-
109+-
228+-
021+-
046+-
084+-
388+-
092+-
197+-
116+-
007+-
000+-
026+-
000+-
007+-
373+-
019+-
069+-
000+-
161+-
3.412
5 . 378
0 . 225
0.197
0.060
0 . 406
0.440
0.287
0.034
0.017
0.014
2.741
0.012
0.009
0.016
0.007
0.015
0.003
0.014
0.006
0.046
0 . 007
0 . 03 1
0.015
0.011
0.016
0.022
0.025
0.030
0.072
0.153
0.210
0.012
0.013
427.
673.
6.
20.
J .
50.
53.
35.
2.
1.
1.
343.
1.
0.
1.
0.
1.
0.
0.
0.
5.
0.
1.
0.
0.
0.
0.
0.
0.
2.
6.
0.
0.
1.
042+-
943+-
725+-
042+-
647+-
668+-
721+-
576+-
235+-
873+-
675+-
33 1 +-
316+-
870+-
773+-
701+-
462+-
1 33+-
297+-
537+-
701+-
590+-
267+-
745+-
047+-
000+-
1 68+-
000+-
045+-
392+-
543+-
441+-
000+-
032+-
21.
34.
1.
1.
0.
2.
2.
1.
0.
0.
0.
17.
0.'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
908
525
444
268
387
608
325
843
217
107
092
599
080
055
100
045
093
019
090
036
295
044
199
096
072
102
143
161
192
464
980
351
079
083
11.
17.
0.
0.
0.
1.
1.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
290+-
817+-
173+-
530+-
096+-
340+-
420+-
941+-
059+-
050+-
044+-
090+-
035+-
023+-
047+-
0 1 9+-
039-1
004+-
008+-
014+-
151+-
0 1 6+-
033+-
020+-
001+-
000+-
004+-
000+-
001+-
063+-
173+-
012+-
OOOn
027+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-o-.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
580
914
038
034
0 1 0
069
075
049
006
003
002
466
002
001
003
00 1
002
000
002
001
008
00 1
005
003
002
003
004
004
005
012
026
036
002
002
139
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO
PARTICLE SIZE: F
ANALYSIS ID: AF139 ' Teflon
EXPOSED AREA:
1*1 A S3:
6.42 SQUARE
674+- 10
CM
MICROGRAMS
ELEMENT
AL
SI
F'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
V
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
UG/CM2
UG/FILTER
PERCENT
13.
20.
0.
4.
0.
1.
1.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
416+-
323+-
662+-
261+-
030+-
101+-
122+-
347+-
03 IH
051+-
040-t
182+-
034+-
029+-
06 1 +-
027+-
093+-
051+-
00 CH
005-i
117+-
014+-
062+-
020+
009-i
012+-
OOO-i
014+-
000+-
966+-
000-t
OOOH
000+-
037+-
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
617
923
120
207
050
054
03 1
042
006
004
003
331
003
(Vr-i
004
002
006
003
005
002
006
002
Oil
007
005
003
Oil
013
0 1 6
115
076
117
006
005
36.
130.
4.
27.
0.
7.
7.
5.
0.
0.
0.
46.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
12.
0.
0.
0.
0.
132+-
474+-
243+-
354+-
195+-
07 1 +-
205+-
436+-
Cj -~.i () .(. _
329+
259-1
103+-
220-1
1S5+-
339+-
172+-
596+-
323+-
00 OH
035+-
754+-
090+-
400+-
127+-
060+-
076+-
000+-
037+-
000+-
62 1 +-
000+-
OOOH
OOOH
239+-
3.
5.
0.
1.
0.
0.
0.
0.
0.
0.
0.
jd m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
959
959
773
' -L-
324
346
520
267
041
023
0 1 3
125
020
017
026
0 1 5
039
022
032
0 1 0
040
0 1 5
069
043
035
051
072
033
101
733
490
749
036
032
12.
19.
0.
4.
0.
1.
1.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
o
0.
0.
771+-
345+-
630+-
056+-
029+-
048-1
068+-
806n
077+-
049H
033+-
336^-
033+-
027+-
053+-
026+-
OS3+-
049+-
OOOH
00 5+-
112+-
013+-
059+-
019+-
009+
011+-
000+-
013+-
000+-
371+-
OOO-i
OOO+
OOO-i
035+-
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
617
92'"'
115
206
048
054
079
041
on A
003
003
331
003
003
004
002
006
003
005
002
006
002
0 1 0
006
005
003
Oil
012
015
113
073
111
005
005
140
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 5A
PARTICLE SIZE: C
ANALYSIS ID: AC01 1 - Teflon
DEPOSIT BUILT UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
: 1683+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
O
CL
K
CA
TI
V
CR
MM
FE
NI
CLI
ZN
GA
AS
SE
BR
RE
SR
V
ZR
MO
PD
AG
CD
IN
3N
SB
BA
LA
HG
PB
35.
56.
0.
1.
0.
3.
o
v'
2_
0.
0.
0.
j.--' .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
661+-
993H
667+-
621+-
269+-
553+-
937+-
567+-
182+-
113+-
117+-
833+-
OS4+-
063+-
116+-
050+-
089+-
011+-
000+-
034+-
397+-
039+-
053+-
031+-
012+-
007+-
000+-
016+-
019+-
000+-
030+-
000+-
OOOn
070+-
1.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
854
952
144
103
033
137
206
134
016
003
007
236
006
005
007
004
008
002
005
003
021
004
019
Oil
009
013
018
020
024
048
120
180
007
009
223.
365.
4.
10.
1.
22.
25.
16.
1.
0.
0.
153.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
946+-
897+-
282+-
404+-
725+-
813+-
278+-
477+-
171+-
757+-
751+-
010+-
542+-
407+-
746+-
320+-
571+-
073+-
000+
221+-
546+-
253+-
372+-
1 98+-
074+-
047+-
000+-
104+-
121+-
000+-
190+-
ooo+_
00 OH
451+-
11.
13.
0.
0.
0.
1.
1.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
904
949
Q^O
692
211
201
324
859
102
050
045
933
04 1
032
048
025
049
012
032
021
136
029
123
072
056
084
113
123
156
311
769
1 58
043
055
13.
21.
0.
0.
0.
1.
1.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
605+-
744+-
254+-
618+-
102+-
356+-
502'H
979+-
070+-
045+-
045+-
093+-
032+-
024+-
044 +-
0 1 9+-
034+-
004+-
OOO+-
013+-
151+-
015+-
022+-
012+-
004+-
003+-
000+-
006+-
007 +-
000+-
011+-
000+-
000 H
027+-
0.712
1 . 1 33
0 . 055
0 . 04 1
0.013
0.072
0.079
0.051
0. 006
0.003
0. 003
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO, 5A
PARTICLE SIZE: F
ANALYSIS ID: AF140 - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 442+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
!~!
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
11.
16.
0.
!b» a
0.
0.
0.
0.
0.
0.
0.
5.
0.
. 0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
277+-
343+-
453+-
360+-
030+-
893+-
834+-
536+-
027-1
059-t
032+-
947+-
033-1
0 1 9+-
047+-
013+-
051+-
023+-
OOO-i
004-t
09 l-i
01 OH
054 +-
0 1 1 +-
004+-
003+-
0 1 6-1
OOO-i
021+-
314+-
404 +-
OOO-i
000+-
029-i
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
519
770
084
120
029
044
054
035
008
004
002
275
003
002
003
002
004
002
001
001
005
002
o i < :>
006
005
007
0 1 0
012
015
06 1
077
109
005
005
72.
108.
^1
15.
0.
5.
5.
--' a
0.
0.
0.
'"!!-;
0.
0.
0.
0.
0.
0.
O
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
c=j
2.
0.
0.
0.
398+-
1 63+-
943+-
149+-
195+-
734+-
678+-
759+-
1 72+-
382+-
203-1
1 79+-
210+-
119+-
304 + -
115+-
325+-
1 45+-
OOO-t-
023+-
534+-
064+-
349+
072+-
028+-
02 1 +-
1 00+-
OOOH
133+-
224+-
593+-
OOO-i
000+-
186+-
:^.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
335
945
537
769
185
235
343
225
054
025
0 1 6
763
019
013
022
012
027
0 1 3
009
0 1 0
033
014
063
040
031
046
066
075
095
393
492
702
03 1
029
16.
24.
0.
* '
0.
1.
1.
0.
0.
0.
0.
C;
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0 .
371+-
459+-
666+-
426+-
044+-
297+-
234+-
850-i
039+-
086+-
047+-
633+-_
047+-
027+-
069+-
026+-
074+-
033+-
OOO-i
132+-
014+-
079+-
016+-
00 6+-
005-1
023+-
OOO-i
030+-
131+-
536+-
000+
00 0+
042+-
0 . 840
1 . 243
0. 122
0. 190
0 . 042
0.071
0.034
0. 054
0.012
0. 006
0 . 004
0.444
0 . 004
0 . 003
0. 005
0 . 003
0 . 006
0 . 008
0. 002
0. 002
0 . 003
0. 003
0 .014
0. 009
0 . 007
0 . 0 1 0
0 .015
0.017
0 . 022
0.093
0 . 1 1 2
0. 159
0 . 007
0. 007
142
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 5B
PARTICLE SIZE: C
ANALYSIS ID: CCOS5 - Nuclepore
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1995+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
43.
63.
0.
1.
0.
4.
4.
2.
0.
0.
0.
27.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
314+-
254+-
706+-
311+-
306+-
297+-
537+-
948+-
177+-
159+-
1 35+-
949+-
103+-
076+-
151+-
056+-
118+-
010+-
024+-
040+-
475+-
050+-
071+-
062+-
000+-
000+-
000+-
000+-
000+-
1S7+-
638+-
000+-
000+-
080+-
2.217
3.4S7
0. 150
0. 113
0.036
0.223
0.233
0. 156
0.021
0.010
0 . 003
1 . 432
0.007
0.006
0.009
0 . 004
0 . 009
0.002
0.007
0.004
0.025
0.005
0.021
0.013
0.010
0.014
0.019
0.022
0.027
0.053
0. 133
0. 193
O.OOS
0.00 9
273.
43:3.
4.
11.
1.
27.
29.
IS.
1.
1.
0.
179.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
1.
4.
0.
0.
0.
076+-
188+-
531+-
626+-
965+-
534+-
451+-
927+-
137+-
019+-
365+-
435+-
664+-
439+-
963+-
353+-
759+-
06 1 +-
151+-
257+-
043+-
320+-
457+-
401+-
000+-
000+-
000+-
000+-
000+-
199+-
096+-
002+-
000+-
512+-
14.
22.
0.
0.
0.
1.
1.
0.
0.
0.
0.
9,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
232
336
961
760
233
430
=->=;
O ji. _'
999
135
063
05 1
,191
046
036
053
027
053
014
046
024
161
032
136
031
064
090
125
142
175
373
356
233
050
060
13.
21.
0.
0.
0.
1.
1.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0'.
0.
0.
0.
0.
(1
0.
0.
0.
0.
0.
0.
0.
0.
0.
936+-
959+-
227+-
583+-
098+-
332+-
476+-
949+-
057+-
051+-
043+-
992+-
033+-
024+-
043+-
0 1 8+-
038+-
003+-
00 8+-
013+-
153+-
016+-
023+-
020+-
(")(") OH
OOOH
000+-
000+-
000+-
060+-
205+-
000+-
000+-
026-t
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o_.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
717
127
048
0:53
012
072
077
050
007
(JO 3
003
463
002
002
003
001
003
00 1
002
001
003
002
007
004
003
005
006
007
009
019
043
062
002
003
143
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 5B
PARTICLE SIZE: F
ANALYSIS ID: AF141 - Teflon
EXPOSED AREA?
MASS:
6.42 SQUARE CM
306+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
w
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
7.
11.
0.
«,
«1
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
132+-
048+-
354+-
163+-
025+-
560+-
579+-
360+-
012+-
033+-
019+-
635+-
020+-
015+-
023+-
012+-
041+-
025+-
000+-
00 3 H
063+-
007+-
057+-
005+-
021+-
015+-
002+-
013+-
039+-
029+-
00 OH
000+-
000+-
022+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
331
507
065
111
027
029
043
027
OOS
003
002
171
002
002
002
00 1
004
002
005
002
004
002
0 1 0
006
006
OOS
0 1 0
013
016
071
077
115
004
004
45.
70.
7
13.
0.
O
=»' e
'-> .
te a
0.
0.
0.
"^^"i
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
7S7+-
929+-
275+-
SS5+-
160+-
595+-
716+-
309+-
076+-
210+-
120+-
656+-
129+- '
096+-
1 S 1 +-
074+-
266+-
160+-
000+
019+-
405+-
046+-
367+-
035+-
134+-
097+-
016+-
OS1+-
250+-
608+-
OOOn
OOOn
000+-
142+-
.^t
<-m* m
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
127
253
416
710
171
1S7
276
174
051
017
012
099
015
012
0 1 6
009
025
0 1 3
032
010 "
025
014
064
040
039
051
064
08 1
102
459
496
736
025
023
14.
, .-,
0.
4.
0.
1.
1.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
"7-*
0.
0.
0.
0.
985+-
213+-
745+-
544+-
052+-
177+-
216+-
756+-
025+-
069 + -
03 9 H
742±-
042+-
032+-
059+-
024+-
087+-
052+-
000-t
006+-
132+-
0 1 5+-
120+-
011+-
044+-
032+-
005+-
027+-
082+-
163+-
000+-
000 H
OOOn
04 6+-
0.351
1 . 308
0. 138
0.276
0.056
0 . 072
0. 099
0 . 062
0 .017
0 . 006
0. 004
0 .440
0. 005
0. 004
0. 005
<") . (")O:-:
0. 009
o . oof1;
0 .011
0.003
0. 009
0 . 005
0 . 02 1
(5.01 3
0.013
0.017
0.021
0.026
0. 033
0 . 1 66
0. 162
0.241
0. 008
0. 009
144
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: C
ANALYSIS ID: AC012 - Teflon
DEPOSIT BUILT UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1773+- 10 MICROGRAM3
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
39.
63.
0.
1.
0.
3.
4.
«-.
Ji m
0.
0.
0.
26 .
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
227+-
1 62+-
769+-
812+-
282+-
967+-
1S1+-
783+-
183+-
141+-
126+-
299+-
088+-
073+-
123+-
058+-
101+-
012+-
000+-
034+-
440+-
044+-
093+-
027+-
009+-
005+-
000+-
022+-
031+-
099-t
270+-
073 +-
000+-
068+-
""'
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
037
268
165
118
035
208
219
145
017
009
007
363
007
005
008
004
008
002
005
003
023
004
019
010
008
012
016
018
022
047
110
161
007
008
251.
405.
4.
11.
1.
25.
26.
17.
1.
0.
0.
168.
0.
0.
0.
0.
0.
0.
0.
0.
->
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
835+-
503+-
938+-
630+-
811+-
466+-
845+-
869+-
172+-
906+-
807+-
842+-
565+-
471+-
792+-
373+-
647+-
080+-
000+-
217+-
S22+-
284+-
62S+-
1 70+-
055+-
033+-
000+-
141+-
197+-
633+-
735+-
469+-
000+-
434+-
13.
20.
1.
0.
0.
1.
1.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
075
Cl O^'
056
759
226
337
406
933
107
056
048
750
042
034
050
028
050
012
032
020
150
028
123
063
050
075
106
115
140
303
704
031
046
051
14
22
0
0
0
1
1
1
0
0
0
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 205+-
. 872+-
. 279+-
. 656+-
. 102+-
. 436+-
.514+-
. 008+-
. 066+-
. 05 1 +-
. 046+-
. 524+-
. 032+-
. 027+-
. 045+-
.021+-
. 036+-
. 005+-
. 000+-
..012+-
. 159+-
.016+-
. 035+-
.010+-
. 003+-
. 002+-
. 000+-
. 008+-
.011+-
. 036+-
. 098+-
. 026+-
. OOOn
. 025+-
0.742
1. 191
0.060
0 . 043
0.013
0 . 076
0.080
0.053
0 . 006
0 . 003
0 . 003
0.496
0 ^.002
0 . 002
0.003
0 . 002
0 . 003
0.001
0 . 002
0.001
0. 009
0.002
0.007
0 . 004
0.003
0 . 004
0.006
0 . 006
0.008
0.017
0.040
0 . 058
0 . 003
C . 003
145
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS IDs AF142 - Teflon
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 491+- 10 MICROGRAMS
ELEMENT
UG/CM2
IJG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
11.
IS.
0.
2.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
I")
0.
994+-
234+-
476+-
523+-
072+-
998+-
944+-
740+-
061+-
044+-
033+-
496+-
037+-
023+-
053+-
021+-
062+-
023+-
000+
007+-
095+
011+-
05S+-
005+-
007+-
017+-
009+-
OOO-i
000+-
905+-
000+-
OOO-i
OOO+
02S+-
0.552
0 . 333
O.OS7
0. 127
0.031
0.049
0.05S
0.035
0.005
0.003
0.002
0 . 300
0. 003
0.002
0. 004
0. 002
0 . (505
0 . 002
0 . 005
0. 002
O. On f=l
0.002
0.010
0.006
0 . 005
0 . 003
0.010
0.013
0.015
0.066
0.075
0. 110
0.004
0.005
77.
117.
O
16.
0.
6.
6.
4.
0.
0.
0.
41.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
00 1 +-
065+-
055+-
230+-
459+-
4 06+-
06 3 H
750+-
3 90+-
"""-' i _i_
i.o4H
209+-
702+-
240+-
150+-
339+-
1 32+-
393+-
177+-
000+
043+-
609+-
069+-
372+-
029-1
04S+-
10S+-
05S+-
000+-
OOO-i
307+-
000+-
000+-
000+-
179+-
$
*
5 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0'.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
544
349
557
SIS
201
315
373
227
035
020
0 1 6
924
021
015
023
013
030
014
032
0 1 0
034
014
065
040
033
051
066
OS2
093
422
430
709
02S
029
15.
'?:";
0.
O
'
0.
1.
1.
0.
0.
0.
0.
S,
0.
0.
0.
0.
0.
0.
0.
e.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
679+-
337+-
622+-
305+-
094+-
304+-
235+-
967+-
079+-
05S+-
043-1
491+-
049 H
031+-
069+-
027+-
OS 1 +-
036+-
00 OH
009-i
124-1
014+-
076+-
006+-
010+-
022+-
012+-
OOO-i
000+-
132+-
000+ -
OOOn
000-t
036 +-
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
T> .
0.
0.
0.
0.
0.
0.
0.
( j .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
M
0.
739
192
114
ISO
041
069
OSO
050
007
004
(DOS
4'"'!-!
004
003
005
003
006
003
007
002
007
003
0 1 3
OOS
007
010
013
017
020
OS9
09S
144
on A
(306
146
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: CCOS6 - Nudepore
BUILD UP AT EDGES
EXPOSED AREA: 6.42 SQUARE CM
MASS: 2055-1 10 MICROGRAMS
- TEST NO. 6B
ELEMENT
UG/CM2
UG /FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
C'J
ZN '
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
44.
70.
0.
+1 m
0.
4.
4.
3.
0.
0.
0.
30.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
409+-
671+-
711+-
029+-
312+-
630+-
782+-
241+-
235+-
155+-
147+-
001+-
114+-
079+-
153+-
065+-
1 1 5+-
009+-
025+-
045+-
497+-
052+-
093+-
076+-
007+-
000+-
0 1 3+_
001+-
000+-
139+-
434+-
084+-
000+-
091+-
2.270
3.605
0. 150
0.131
0.039
0 . 239
0.243
0. 167
0. 020
0.010
0 . 003
1 . 535
0 . 003
0.006
0 . 009
0. 005
0 . 009
0 . 002
0.007
0. 004
0.026
0.005
0.022
0 . 0 1 3
0.010
0.014
0. 020
0.022
0.027
0 . 057
0. 129
0. 194
0 . 009
0.010
285.
453.
4.
13.
rfv-
29.
30 .
20.
1 .
0.
0.
192.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^ m
0.
0.
0.
103+-
70S+-
565+-
024+-
001+-
728+-
701+-
310+-
511+-
995+-
943+-
604+-
729+-
506+-
982+-
414+-
739+-
058-1
157+-
290+-
1 90+-
333+-
600+-
487+-
044+-
000+-
082+-
003+-
000+-
890+-
735+-
542+-
000 +-
t^o-r.^
14.
23 .
0.
0.
0.
1.
1.
1.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
574
147
966
840
250
537
589
072
126
06 1
055
355
049
036
060
030
057
014
046
025
167
033
139
083
066
089
1 30
143
174
364
827
245
053
063
13
22
0
0
0
1
i
1
o
0
o
9
0
0
0
0
o
0
o
0
0
o
o
0
o
0
o
0
0
0
0
0
0
o
. 8/1+-
. 073+-
. 2J22+-
. 634+-
. 097-i
. 446+-
. 4,94+-
.012+-
. 074-)
. 043 +-
. 0,46+-
. 370+-
. 03 5 H
. 025+-
. 043+-
. 020 +-
. 086+-
. 003+
. 008+-
."014+-
. 155+-
.016+-
. 0'29-i
. 024+-
. 002+-
. 000+
. 004-1
. 000+-
. 0:00+-
. 043+-
. 135+-
. 026+-
. 000+-
. 023 +-
0.
1.
0.
0.
0.
0.
0.
0.
o
0.
0.
li..
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
()
712
131
047
041
012
075
078
052
no/-,
003
003
432
002
002
003
00 1
003
00 1
002
001
008
002
007
004
003
004
no/-.
007
008
013
040
06 1
003
O O-":
147
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - TEST NO. 6B
PARTICLE SIZE: F
ANALYSIS ID: AF143 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
316+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i~-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB'
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
6.
10.
0.
- .
^l>
0.
0.
0.
0.
0.
0.
0.
'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
(1
0.
0.
:=:-'-+-
475+-
337+-
430-i
00 1 H
561+-
590+-
444+-
042+-
03 1 +-
019+-
673+-
013+-
014+-
042+-
0 1 1 H
046+-
027 +-
000 -i
002-1
052+-
004H
OOO-i
00 1 +-
010+-
007+-
021+-
012+-
0 1 1 +-
060-<
00 OH
OOOH
OOOn
026+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
317
48 1
062
123
029
029
044
022
004
003
002
171
002
002
003
002
004
002
003
002
004
002
0 1 0
007
006
OOS
012
014
017
074
OS2
127
004
005
43.
67.
]^ .
15.
0.
^i
'
.-.
0.
0.
0.
k'3 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
797+-
246+-
1 6 1 +-
599+-
008+-
601+-
733+-
S50+-
271+-
20 OH
122+-
577+-
113+-
092+-
269+-
074-t
293+-
175+-
00 OH
014+-
333+-
025+-
000+
007+-
062+-
046+-
1 33+-
079+-
070+-
S06n
000+-
00 OH
OOOn
170+-
2.
. .
m
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
n
>-'
0.
0.
036
035
395
790
1 39
137
^T i~i j^
140
026
016
012
096
014
012
020
0 1 0
027
014
019
Oil
023
0 1 5
067
045
033
053
076
039
107
475
529
R 1 /-.
' ' J, '_'
025
031
13.
21.
0.
4.
0.
1.
1.
0.
0.
0.
0.
7.
0.
0.
("i
C.) .
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
I
,*_
0.
o
V.'
0.
0.
979+-
3 1 1 +-
635+-
943n
002n
141+-
200+-
903+-
03 6 H
063+
039+-
472+-
03~6+-
029-t
OP.5-1
023+-
093+-
nc:;i=;+-
000-f
004 H
1O5+-
003H
OOO-i
002-1
020+-
015+-
042+-
025+-
022+-
157+-
000+-
f),OO+
0,00+-
054+-
0.731
1. 133
0. 127
0.295
O. OAO
0.070
0. 097
0.053
0. 009
0. 006
0 . 004
0. 420
0 . 005
0. 004
O OO7
O . OO:":
0 . 009
0. 005
0 . 006
0.003
0.003
0.005
0.021
0 .014
0 .012
0.017
0.024
0.023
0.034
0. 165
0 . 1 63
0. 259
0.003
0 . 0 1 0
148
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC079 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
C;
CL
K,
CA
TI
V
CR
MN
FE
NI
CU
ZM
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0 . 008+-
0.001+-
0 . 000+-
0 . OOOH
0.014+-
0.000+-
0.000+-
0. OOOn
0 . 000+-
0.001+-
0. OOOn
0 . 006+-
0.002+-
0. 00 H
0 . 000+-
0.000+-
0 . 000+-
0 . 000+-
0. 000+-
0 . 002+-
0 . OOOH
0 . OOOn
0. 000+-
0.0 00+-
0. 006+-
0 . OOOn
0.034+-
0 . OOOn
0 . 000+-
0. OOOn
0. lOOn
0. 125+-
0. 000+-
0 . 005n
0.013
0 . 009
0.004
0 . 020
0 . 007
0 . 003
0 . 002
0.001
0. 001
0 . 00 1
0 . 00 1
0 . 003
0 . 00 1
0 . 00 1
0.001
0 . 00 1
0 . 003
0 . 00 1
(I) . 00 1
0 . 002
0.002
O. 00 :-:
0.011
0.008
0 . 007
0.010
0.013
0.015
0.013
0.033
0.085
0. 132
0.002
0 . 005
0.051+-
0.008+-
0.000+-
0 . (")OO+
0 . 089+-
0 . 000+-
0. 000+-
0 . 000+-
0.000+-
0 . 009+-
0 . 000+-
0.035+-
0.011+-
0.006+-
0.000+-
0.000+-
0. 000+-
0.000+-
0. 000+-
0.012+-
0. 000+-
0 . 000+-
0.000+-
0.000+-
0.038+-
0.000+-
0.217+-
0.000+-
0 . 000+-
0.000+-
0.640+-
0 . 805+-
0 . 000+-
0 . 035+-
0.033
0 . 053
0.024
A 1 -/
'.' . 1 -i O
0.045
0 . 0 1 8
0.012
0 . 007
0.006
0.007
0 . 003
0 . 020
0.008
0 . 009
0.006
0 . 005
0 . 0 1 8
0 . 007
0 . 00?
0 .011
0 . 0 1 4
0.016
0. 070
0.043
0.045
0.064
0.087
0.094
0.11 9
0 .210
0.544
0.847
0 . 0 1 3
0. 030
149
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZES F
ANALYSIS ID: AF244 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
31
P
C1
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.011+-
0. 023+-
0 . 00 1 +-
0. 029 +-
Q.OOO+-
0. 000+-
0. 000+-
0 . 000+-
0.001+-
0.001+-
0. 00 OH
Ov 003-1
0. 003 +-
0.001+-
0. OOO-i
0 . 00 1 +-
0 . 00 1 +-
0. 001+-
0. OOO-i
0 . OOO-i
0. OOCH
0.000+-
0. 000+-
0.002+-
0. 004 +-
0 . OOO-i
0.0 13+-
0.01 5+-
0 . 007+-
0. 037+-
O.OS3+-
0. 295+-
0 . 000 +
0 . 000-t
0.010
0.007
0. 003
0.014
0 . 006
0.003
0.002
0.001
0.001
0 . 00 1
0.001
0.003
0.001
0 . 00 1
0.001
0 . 00 1
O. OO:~:
0 . 00 1
0 . 00 1
0.002
0= 002
0.002
0 . 0 1 0
0.007
0.006
0.009
0.012
0.015
0.017
0.031
0.082
0 . 1 30
0. 002
0. 004
0.069-1
0. 14?+-
0.008+-
0. 1S3+-
0 . 000+-
0. 002-1
0. OOO-i
0. 000 H
0. 00 8 H
0. 006+-
0. OOO-i
0.020+-
0. 016+-
0 . 008+-
0. 003+-
0 . 009+-
0.004+-
0.010+-
0. 000+
0. 000+-
0. 000+-
0.001+-
O. (')() OH
0.015+-
0.027+-
0. 000+-
0. 082'H
0.096+-
0 . 048+-
0.237+-
0.565+-
1 . 896+
0. 00 1 +
0. 002-1
0.067
0. 043
0.021
0.037
0.039
0.017
0 . 0 1 0
0.007
0 . 006
0 . 007
O. OOfi
0 . 020
0. 008
0. 008
0. 005
0 . OO5
0 .017
0 . 006
0. 009
0.011
0 .014
0 .015
0 . 0/o6
0.047
0.037
0. 060
0. 073
0 . 095
0.112
0 . 20 1
0.523
0 . 335
Ci 0 1 S
*-' *..' X '
0 . 023
150
-------
SAMPLE ID: EDDYSTONE/COAL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: CC124 - Nudepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UO/CM2
UG/FILTER
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.002+-
0 . 022+-
0.000+-
0 . 000+-
0 . 000+-
0.001+-
0.000+-
0 . 000+-
0 . 00 1 +-
0.000+-
0.000+-
0.005+-
0.001+-
0 . 000+-
0 . 00 1 +-
0.000+-
0.006+-
0.000+-
0.005+-
0 . QOO+-
O.OOO-i
0.001+-
0 . 000+-
O.OOO-i
0.007-1
0.016-1
0.005+-
0.000+-
0.000+-
0.036+-
0.1 16+-
0 . 070-1
0.001+-
0.000-f
0.025
0.019
0 . 0 1 0
0.022
0 . 009
0.003
0.002
0.001
0.001
0.002
0 . 00 1
0.004
0.001
0.002
0 . 00 1
O.OO1
0.004
0 . 002
0.002
0.002
0 . 003
0.003
0.014
0.011
0.009
0.012
0.0 IS
0 . 020
0.024
0 . 045
0. Ill
0. 174
0.003
0.006
0.016-1
0. 141+-
0. OOO-i
0.000+-
0.000+-
0.007+-
0.000+-
0 . 000+-
0.005-1
0 . OOO-i
0 . 000+-
0.031+-
0.004+-
0 . 000+-
0.005+-
0.002+-
0.03S+-
0. OOO-i
0.031+-
0. 00 OH
0 . 000+-
0.003+-
0.000+-
0 . 000+-
0 . 042-1
0 . 1 05+-
0.030+-
0 . 000+-
0.000+-
0.229+-
0.747+-
0.450+-
0.004+-
0. OOO-i
0. 161
0. 125
0.062
0. 144
0.059
0.020
0.014
0 . 009
0 . 006
0.011
0.010
0.025
O.'"009
0.010
0.007
0 . 006
0.025
0 . 0 1 0
0.015
0.015
0 . 0 1 9
0.022
0.089
0 . 063
0.059
0.076
0.116
0. 126
0. 154
0.291
0.712
1.117
0.017
0 . 04 1
151
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: AC013 - Teflon
- TEST NO. 1A
EXPOSED AREA: 6.42 SQUARE CM
MASS: 49+- 10 MICROGRAM'.;
ELEMENT
UG/CM2
UC/FILTER
PERCENT
AL
SI
P
.;.
CL
K
CA
TI
V
CR
MN
FE
Ml
CL!
ZN
GA
AS
SE
BR
RB
C T
V
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PP.
0.
1.
0.
C'.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
C'.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
705+-
5 1 0+-
032 H
509+
000 +
025+-
443+-
063H
082+-
016+-
006-i
233+-
141+-
037+-
064n
000+
OOOH
OOOn
001+-
OOOH
007-1
OOO-i
000+
OOOH
006+-
OOOn
024+-
03 OH
023n
023+-
035+-
00 OH
OOOn
043 H
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0 =
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
059
106
050
143
034
006
040
006
0 1 9
004
002
030
029
007
Oil
001
OO A
001
00 1
002
002
002
0 1 0
003
006
OOS
012
014
017
032
080
126
002
014
4.
9 m
0.
'»'
0 .
0.
.li.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
523+-
69 1 +-
526+-
269+-
000+
162+-
343-1
405n
523+-
106+-
033+- .
527+-
90 4 H
560+-
409+-
OOOn
OOOn
OOOn
006 H
OOO-i
04 3+-
00 OH
000+-
000+-
033+-
00 OH
156+-
194+-
151+-
147+-
226+-
000 H
OOOn
276+-
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
377
683
320
9 1 5
220
04 1
254
036
122
024
Oil
194
134
044
074
009
037
006
009
0 1 (".>
014
015
065
043
038
054
078
09 1
107
207
514
SOS
015
089
9.
19.
1.
6.
O
0.
ET
0.
1.
0.
0.
3.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
262+-
323+-
076+-
686+-
OOOH
332'H
8 1 5+-
92'9n
081+-
216+-
077±-
124+-
849+-
146+-
337+-
00 OH
OOOH
OOOn
013+-
000 H
037 H
OOOH
OOOH
000+-
073+-
00 OH
319+-
397+-
308+-
300+-
463+-
00 OH
OOOH
564+-
2.045
4 . 289
0.691
2.313
0. 450
0 . 1 0:3
1 . 293
0. 135
0 . 333
0 . 066
0. 027
0 . 753
0 . 533
0.251
0.228
0 . 0 1 9
0. 075
0 . C> 1 3
0 . 0 1 9
0. 021
0. 034
0. 031
0 . 1 34
0.099
0.079
0.111
0. 172
0 . 202
0 . 228
0 . 427
1 . 056
1 . 652
0 . 0 3 1
0.21 6
152
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 1A
PARTICLE SIZE: F
ANALYSIS ID: AF144 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: SOU 10 MICROGRAMS
ELEMENT
UO/CM2
UG/FILTER
PERCENT
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
->
d±»
4.
1.
15.
0.
0.
'Tr
+-
0.
2.
0.
0.
2.
"-'
%-<
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
629+-
532+-
235+-
6 1 0+-
000+-
297+-
493+-
1 36+-
073+-
073+-
048+-
433+-
017+-
1 1 S+-
080+-
013+-
024+-
OOO-i
OOS+-
000+-
035+-
002n
000+-
254+-
007+-
013+-
000+-
015+-
023+-
188+-
395+-
260+-
005+-
377+-
0. 127
0.211
0.233
0 . 733
0 . 1 32
0.0 IS
0. 119
0.013
0.097
0 . 0 1 3
0.003
0. 117
0. 139
0.010
0.051
0.004
0.014
0.002
0.002
0. 002
0 . 003
0 . 004
0.012
0.015
0 . 007
0.010
0.014
0.016
0.01S
0.040
0.092
0. 131
0.003
0.065
16.
29.
8.
100.
0.
1.
16.
0.
13.
0.
0.
15.
19.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
o
1.
0.
S.
876+-
097+-
247+-
2 14+-
000+-
905+-
007+-
S70+-
311+-
471+-
309+-
974+-
368+-
760+-
936+-
1 1 3+-
152+-
000+-
050+-
00 OH
226+-
013+-
OOO-i
629+-
043+-
OS1+-
000+-
096+-
179+-
207+-
534+-
672+-
032+-
939-1
0.
1.
1.
4.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
814
353
49S
705
168
1 1 6
762
031
621
087
022
743
fl'T/t;
065
324
024
089
016
015
012
020
023
076
099
044
067
OSS
1 00
119
25S
591
843
020
417
-i
3 .
1.
12.
0.
0.
1.
0.
1.
0.
0.
1.
-.
<>
11.
0.
o.
u.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
107+-
632+-
029+-
509+-
OOO-i
238+-
993+-
1 09+-
662+-
059 +-
03 9 H
994+-
41S+-
095+-
366+-
0 1 4+~
019+-
000 H
006+-
0^1) OH
023 H
002+-
000+-
203n
005+-
0 1 0+-
OOO-i
012+-
022+-
151+-
316+-
209+-
004+-
103+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
105
175
187
60S
146
01?
09S
0 1 0
OSO
Oil
003
097
ri5
oos
042
003
Oil
002
002
002
OCv':
003
009
0 1 3
006
OOS
Oil
012
015
032
074
105
00:3
054
153
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: AGO 14 - Teflon
- TEST NO. 2A
EXPOSED AREA: 6.42 SQUARE CM
MASS: 20+- 10 M1CROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERGENT
AL
SI
p
GL
«
GA
TI
V
GR
Mr-4
FE
NI
GU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
447+-
922+-
04 3 H
322+-
000+-
00 S-i
270+
037n
053+-
OOS-i
001+-
124+-
072 +-
051+-
023+-
003+-
OOS-i
OOO-i
000+-
OOO+
007+-
000 +
005-i
OOOn
002n
000-f
029 +-
0 1 5+-
033+-
02 1 +-
00 OH
04?+-
00 OH
016-1
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
041
06S
O ;";
117
02 3
005
024
004
012
003
00 1
013
017
OOS
007
001
005
001
002
002
002
003
01 1
003
006
0 1 0
0 1 4
015
019
036
OS1?
1 33
002
009
.i
^> e
'
0.
J^, D
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
37 1 +-
922+-
274+-
06 3+-
00 OH
050+-
734+-
239+-
341+-
053+-
00 6 H
795+-
464+-
331+-
1 80+-
017+-
05 1 +-
O O :"-:+
002n
OOO+
043+-
000+
029+-
000+-
0 1 5+-
000+
130+-
097+-
210+-
1 37+-
OOOH
313+-
!")OO-i
1 05+-
0.264
0.434
0.21 0
0.750
Oc 130
0. 030
0. 155
0. 027
0 . 075
0 .017
0 . 0 1 0
0. 117
0. Ill
0 . 030
0. 044
0 . 009
0. 032
0 . 007
0 . 0 1 0
< j .012
0 . 0 1 5
0 .017
0 . 072
0.054
0.042
0. 062
0.033
0 . 099
0. 123
0.233
0.574
0.337
0 . 0 1 4
0.061
14.
23 .
1 .
10.
0.
0.
3 .
1 .
1.
0.
0.
Jj
. .
1 .
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
0.
0.
041+-
966+-
339+-
114+-
OOOn
246+-
434+-
171+-
663+-
257+-
03 1 +-
390+-
270n
617+-
033+-
243+-
015+-
OOSn
00 OH
203+-
OOOH
143+-
000+
074+-
000+-
330+-
476+-
027+-
&/-.'->+-
000+-
532+-
00 OH
515+-
6.
14
1.
6.
0.
0.
4o
i")
0.
0.
0.
1_.
1.
0 .
0.
0.
0.
0.
0 .
o .
0.
0.
o
0.
0.
0.
0.
0.
0.
1.
*il o
4.
0.
0.
9RP.
. :~i~!
2 1 !:!
159
88 1
191
2 1 9
=;ft!=:
395
152
049
937
236
305
432
061
197
035
049
057
127
085
";SP:
265
206
302
610
533
734
1 35
303
403
066
390
154
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF145 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
636+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
,--
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
r>
*u
0.
13.
0.
0.
1.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
683+-
89 1 +-
901+-
095+-
000+-
190+-
389+-
141+-
217+-
034+-
029+-
467+-
803+-
085+-
644+-
016+-
0 1 7+-
004+-
004+-
OO3+-
013+-
000+-
000+-
144+-
005+-
002+-
003+-
026+-
015+-
140+-
000+-
000+-
003 +-
8 15+-
0.084
0. 136
0. 164
0.616
0. 152
0.012
0.068
0 . OOS
0 . 037
0 . 008
0.002
0.070
0.084
0.007
0.031
0.003
0.010
0.002
0.002
0 . 002
0 . 002
0 . 003
0 . 009
0.010
0.005
0.008
0.011
0.014
0.015
0 . 033
0 . 073
0. 113
0 . 002
0 . 039
10.
18.
5.
84.
0.
1.
8.
0.
7.
0.
0.
9.
11.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
837+-
558+-
782+-
06S+-
000+-
220+-
917+-
904+-
8 15+-
220+-
1 86+-
42 1 +-
573+-
547+-
136+-
103+-
1 1 0+-
02S+-
029+-
022+-
117+-
000+-
000+-
923+-
035+-
010+-
0 1 9+-
169+-
098+-
90 1 +-
000+-
000+-
017+-
231+-
0.
0.
1.
-'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
539
874
051
953
977
079
436
051
363
05:3
015
449
539
046
197
019
067
Oil
Oil
0 1 0
015
017
060
067
035
050
071
087
099
*"> 1 "!»
472
727
0 1 6
253
1.
-»
»!
0.
12.
0.
0.
1.
0.
1.
0.
0.
1.
1 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
653+-
33 1 +-
8S2+-
824+-
000+-
186+-
360+-
1 38+-
192+-
034+-
028+-
437+-
765+-
083+-
631+-
016+-
017+-
004 +-
004-1
003+-
013+-
000+-
000-(
141+-
005+-
002+-
003+-
026+-
015+-
137+-
000+-
000+-
003+-
798+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
n
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
086
140
161
634
149
012
070
008
058
008
002
072
OP:/-.
f*(--lT
032
003
0 1 0
002
002
001
002
003
009
0 1 0
005
008
Oil
013
015
032
072
111
002
04 0
155
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO.
PARTICLE SIZE: C
ANALYSIS ID: AGO 15 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: - 5+- 10 MICROGRAMS
3A
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
t~-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZIM
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
153+-
31?+-
021-t
183+-
OOO-i
009+-
105+-
013+-
020+-
003-f
002-1
055+-
022+-
016+-
005-t
OOO+
000+-
00 1 +-
000 -f
002+-
00 6+-
OOO-i
OOO-i
000+-
002+-
003+-
013+-
005 H
000+-
023+-
000 H
OS4-I
OOO-i
Ol'?-i
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
022
027
012
047
012
004
Oil
002
005
002
002
009
007
003
003
001
004
001
002
002
003
003
012
009
007
Oil
014
016
020
039
096
151
003
007
1.
O
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 1 4+-
049-1
137-t
210+-
000+
059+-
676+-
08 1 +-
123+-
0 1 6+-
014+-
354+- .
144+-
105+-
030-1
OOO-i
000+-
009-1
000+
0 1 5+-
041+-
OO'.'H
OOO-i
000+-
015+-
0 1 9+-
113+-
035+-
OOO-i
132+-
000+-
537+-
000+-
125+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
141
174
07S
304
076
023
06S
014
029
012
0 1 0
056
042
017
0 1 S
007
026
007
Oil
0 1 3
0 1 6
0 1 9
07S
057
045
069
093
105
127
~\ C" -"I
.l^-J-ll.
615
972
017
0^5
-21.
-42.
^L .
_ -7.it;
0.
- 1.
-14.
- 1.
'"i
j^
- 0.
- 0.
- 7.
- 3.
_ '"'
- 0.
D
0.
- 0.
o.
- 0.
- 0.
0 .
0.
o
- 0.
- 0.
2 .
- 0.
0.
3.
0.
-11.
0.
_ ">
231+-
393-f
863+-
325+-
OOO-i
232+-
155+-
689-1
684+-
341+-
292+-
403-+-
013+-
194+-
623+-
OOO-l
000-t
196+-
000+-
307+-
354+-
00 OH
000+-
OOOn
315+-
406+-
360+-
724+-
OOO-i
810+-
000+-
244+-
OOO-i
6 1 6+-
44 . 53
39.85
6.212
S'"; '"!'-''
ilsii
2.630
29 . 66
3.543
5.651
0.753
0. 644
15.55
6 . 367
4.604
1 . 369
0. 150
0 . 546
0.439
0 . 223
0 . 693
1.321
0. 394
1 . 624
1 . 192
1. 149
1 . 634
5.308
2.670
2. 653
9.553
12.83
31.1 0
0 . 35 1
c° trrr--i
156
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED
PARTICLE SIZE: F
ANALYSIS ID: AF146 - Teflon
POWER PLANT - TEST NO. 3A
EXPOSED AREA:
MASS:
6.42 SQUARE CM
173+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
*-l
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
563+-
939+-
272+-
935+-
00 OH
055+-
505+-
039+-
382+-
014+-
003+-
483+-
558+-
023+-
214+-
005+-
007+-
00 1 +-
002+-
00 OH
OOS+-
OOOn
018+-
029'H
00 1 +-
000+-
012+-
00 0+ -
000+-
049+-
024+-
244+-
004+-
263+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
034
043
050
196
047
006
025
003
0 1 9
003
002
025
027
004
Oil
002
006
00 1
002
002
002
003
0 1 1
009
007
0 1 0
015
017
019
033
091
140
003
015
~<
'
6.
1.
25.
0.
0.
,
' *
0.
~l
4- *
0.
0.
3.
. ,
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
1.
6 1 6+-
031+-
746+-
583+-
000+-
355+-
245n
249+-
453+-
OS7+-
049+-
104+-
582+-
1 30+-
372+-
031+-
04 6H
006+-
015+-
000+-
055+-
00 OH
116+-
138+-
005+-
000+-
074+-
000+-
000+-
3T4+-
157+-
569+-
027+-
686+-
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
216
305
320
256
302
037
1 63
022
119
022
Oil
161
175
023
071
Oil
041
003
Oil
0 1 2
0 1 6
0 1 3
074
057
043
065
095
1 06
125
242
582
901
0 1 3
096
-»
^
3
0
14
O
0
1
o
1
0
(I)
1
"l
Jl.
0
0
o
o
o
o
("1
0
o
o
0
0
o
0
0
0
0
0
0
0
/")
. 0,3 4 H
. 393+-
.9824-
. 390+-
. rifx'H
. 2JOO+-
. 325+-
.1:40+-
.3,80+-
. Q49+-
. 027n
. 7,46+-
.015+-
. 101+-
. 772+-
.dl7+-
. 026+-
. 003+-
. dos+-
."O(")("H
. 031+-
. OOOn
. u/-,5+-
. i;o6+-
. 003+-
. doo+-
. CJ42+-
. QOO+-
. 000+-
. l!76+-
. qs3+-
. 832+-
.015+-
. 943+-
0. 167
0 . 257
0. 133
1 . 075
0. 170
0 .024
0. 133
0 .014
0. 103
0.013
0. 006
Oj.133
0. 150
0 .014
0.059
0. 006
0. 023
0 . 005
0. 006
0. 007
0. 009
0 . 0 1 0
0.042
0 . 032
0.024
0 . 037
0 .054
O. O/-.O
0.070
0. 136
0.327
0 . 5 1 0
0 . 0 1 0
0 . 076
157
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 4A
PARTICLE SIZE: C
ANALYSIS ID: AGO 16 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 17+- 10 MICROGRAMS
ELEMENT
AL
SI
P
CL
K
CA
TI
V
CR
MN
FE
NI
C'J
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MG
PD
AG
CD
IN
3N
SB
BA
LA
HG
PB
UG/CM2
0 . 376+-
0, 389+-
0. 055+-
0 . 436+-
0 . 00 OH
0. 016+-
0.296+-
0.034+-
0. 053+-
0 . 004+-
0. 004+-
0. 151+-
0 . 06S+-
0. 072+-
0 . 04 1 +-
0. 00 OH
0. 003+-
0. 00 1+
0= OOOH
0. OOOH
0. 004+-
("). OOOH
0. 000+-
0. OOOn
0 . 00 1 +-
0. 006H
0. 009n
0.017+-
0.038+-
0 . OOOH
0. 000+
0.221+-
0. OOOn
0 .011 +-
0.035
0.062
0. 030
0. 109
0. 026
0.005
0 . 025
0.004
0 . 0 1 0
0. 002
0. 001
0 . 0 1 S
0.014
0 . 006
0.007
0. 001
0.004
0 . 00 1
0 . 00 1
0. 001
0. 002
0. 002
0 , 009
0.006
0.005
0 . OOS
0 . 0 1 0
0 . 0 1 2
0.015
0. 029
0.070
0. 108
0.002
0 . OOS
UG/FILTER
PERCENT
2.416+-
5.705+-
0. 351 +-
3.119+-
0. 000+-
0.103+-
1. 399+-
,219+-
, 371 +-
, 025+-
, 025+-
, 972+-
, 439+-
, 465+-
,261+-
, 000+-
,021+-
, 003+-
, 003+-
, 000+-
, 023+-
, 000+-
0. 000+-
0. 000+-
0. 006+-
040+-
055+-
, 111 +
244+
000+
000+
,413+
0.000+
0.069+
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
,226 14.117+-
- o
193
701
165
030
159
024
066
015
008
113
089
036
043
007
027
0.006
0. 008
0.009
0.011
0.013
0. 056
0.040
0. 031
0. 050
0.063
076
0. 096
0. 136
443
695
013
052
0.
0.
33.341+
2.050+
13.226+
0.000+
0.603+
11.097+
1-. 230+
2.169+
14.7+
147 +
680+
565+
713+
526+
, 002+
121 +
, 050+
, 016
, 000+
, 134+
, 000+
, 000+
, 000+
, 034+
-'"-'. ?-(.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
8. 356
19.62
1. 647
11.41
0. 964
O. :~:9:":
- 0.761
1. 325
0. 122
0. 098
1.
1 . 0».'0
0-927
0.042
0. 172
0.044
045
, :J23+-
,651+-
, 425+-
0. 000+-
0 000+-
8.237+-
0.002+-
0.403+-
- ()
- 0.050
- 0.103
- 0.074
_' ^L. ,-"
232
132
321
416
0. 584
1. 005
1. 090
2.619
6. 321
0. 074
0. 334
158
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 4A
PARTICLE SIZE: F
ANALYSIS ID: AF147 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
539+- 10 MICROGRAM'c
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL-
SI
P
s
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
*!
Z.
0.
11.
0.
0.
1.
0.
0.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
436+-
253+-
734+-
098+-
000+-
152+-
2fiftH
111+-
975+-
033+-
022+-
204-f
332+-
083+-
542+-
010+-
009+-
002+-
003+-
002+-
016+-
OOO-i
000+-
091+-
005+-
011+-
000+--
000+-
010+-
057+-
152+-
141+-
001+-
729+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
073
107
134
524
129
Oil
06 1
007
046
007
002
053
063
007
026
003
0 1 0
002
002
002
002
003
Oil
0 1 0
006
0 1 0
013
015
018
034
083
124
003
036
9.
14.
4.
71.
0.
0.
8.
0.
6.
0.
0.
7.
P;
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
221+-
464+-
714+-
247+-
000+-
979+-
269+-
711+-
261+-
214+-
140+-
733+-
549+-
567+-
482+-
065+-
057+-
014+-
017+-
010+-
104+-
000+-
OOO-i
587+-
032+-
071+-
000+-
000+-
064+-
363+-
974+-
906+-
009-t
678+-
0.
0.
0.
3 .
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
467
689
857
362
328
063
394
043
292
044
014
372
40 1
043
167
017
064
010
Oil
Oil
0 1 6
0 1 8
069
06 1
040
062
083
094
115
220
536
793
017
vj^jy
i.
^ .
0.
13.
0.
0.
1.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
"o .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
711+-
684+-
375+-
221+-
000+-
132+-
534+-
132+-
162+-
040n
026+-
435+-
536+-
1 05+-
646+-
012+-
0 1 1 +-
003-1
003+-
002-1
019+-
OOOn
OOO-i
1 09+-
006+-
013+-
00 OH
000+-
012+-
067+-
131+-
163+-
002+-
363+-
0.092
0. 137
0. 160
0.670
0. 154
0 . 0 1 3
0.07S
0. 003
0 . 058
0.003
0. 003
0.074
0 . 030
"o.oos
0 . 033
0.003
0 . 0 1 2
0 . 002
0.002
0 . 002
0 . 003
O . (V):"i
0 . 0 1 3
0 .012
0.007
0.011
0.015
0 . 0 1 8
0.021
0. 04 1
0. 100
0 . 1 48
0 . 003
0 . 045
159
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 4B
PARTICLE SIZE: C
ANALYSIS ID: C-COS7 - Nuclepore
EXPOSED
MASS:
AREA:
6=42 SQUARE
AL
SI
F
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
UG/CM2
656+-
259'H
041+-
131+-
OOO-i
014+-
433+-
056+-
073+-
0. 006-1
0.007+-
199+-
064+-
093-i
025-i
OOO-i
0. OOO-i
0. OOO-i
0. OOO-i
0.OOOn
0.010+-
001+-
OOOH
OOOH
OOO-i
OOOH
01 7+-
00 OH
000+-
OOO-i
0.000+
0.000+-
0. 021-i
0.053
0.031
0.030
0. 102
025
005
0:33
005
Oil
00:3
0. 002
0.020
015
007
006
001
005
001
002
002
003
003
014
Oil
003
012
0.013
0.019
0.024
0. 046
0.111
0. 173
0. 003
0. 010
:E CM
0 MICROGRAMS
UG/FILTER
4.
p __
0.
1.
0.
0.
7l
0.
0.
0.
0.
1.
0.
0.
0.
0 .
0.
0.
(-,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
208+-
OS2+-
266+-
162+-
OOO-i
092+-
114+-
361+-
471+-
039+
045+-
28 1 +-
414+-
599+-
1 6 1 +-
00 OH
OOO-i
OOO-i
OOO-I
00 0+ -
0/-.4+-
006-1
OOO-i
06 1 +-
000+-
000 +-
000+-
106+-
000+-
OOOn
000+-
000+-
OOO-i
133+-
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0 .
0 .'
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
34 1
522
194
656
160
035
213
032
073
019
Oil
130
096
043
042
OO:~:
034
009
014
0 1 5
019
021
033
063
052
073
113
121
152
293
714
1 09
017
064
12.
24.
0.
-i
0.
0.
9.
1.
1.
0.
0.
O
1.
1.
0.
0.
O
0.
O
0".
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
('1
0.
PERCENT
927+-
826+-
813+-
570+-
000 H
234-1
566+-
103+-
446+-
120+-
139+-
934+-
271+-
339+-
493+-
OOO-i
OOOH
000+-
OOO-I
OOO-i
193 + -
01S+-
OOO-i
136+-
000+
OOOH
OOO-i
326+-
OOO-i
OOOH
OOO-i
000+-
OOOH
40 S+-
4.
7.
0.
i
+i e
0.
0.
I*
0.
0.
0.
0.
JL.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
h_
<_'
0.
0.
1 06
792
647
293
491
1 37
0 1 1
354
498
063
054
273
439
580
193
026
103
026
044
047
085
066
269
217
161
240
347
386
466
915
192
407
054
234
160
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 4B
PARTICLE SIZE: F
ANALYSIS ID: AF14S - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
544+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZIM
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
1.
0.
11.
0.
0.
1.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
246+-
890+-
768+-
534+-
000+-
153+-
148+-
099n
039+-
027+-
023-1
203+-
496+-
079+-
602+-
003+-
004+-
005+-
003+-
003+-
0 1 9+-
OOOH
016+-
092+-
OO5+-
009+-
001+-
000+-
005+-
112+-
092+-
045+-
003 +-
785+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
064
091
140
546
135
0 1 1
056
006
04S
007
002
058
070
007
029
003
010
002
002
002
003
003
Oil
010
007
010
014
0 1 6
020
039
090
135
003
033
8.
12.
4.
74.
0.
0.
7.
0.
6.
0.
0.
7.
9.
0.
O
* *
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5 .
000+-
1 36+-
934+-
371+-
000+-
984+-
369+-
635+-
667+-
175+-
147+-
756+-
604+-
510+-
864+-
052+-
023+-
030+-
016+-
018+-
121+-
000+-
105+J
589+-
031+-
061+-
008+-
000+-
031+-
721+-
590+-
286+-
0 1 9+-
040+-
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
413
585
~"~/~T
' ' . /
507
864
068
362
040
311
046
015
373
449
043
185
017
067
012
012
012
018
020
074
065
044
067
092
103
126
252
581
866
0 1 9
245
1.
2.
0.
13.
0.
0.
1.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
CU
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
469+-
OO-T/J
*.+, ..'T
906+-
660+-
000+-
181+-
353+-
117+-
225+-
032+-
027+-
425+-
764+-
094+-
710+-
010+-
004+-
006+-
003+-
003+-
022+-
000 H
019+-
108+-
006+-
011+-
002+-
000+-
006+-
132+-
108+-
053+-
004+-
926+-
0.080
0. 115
0. 166
0.691
0. 159
0 . 0 1 3
0 . 07 1
0.003
0.061
n . OOP:
0.003
0.073
di (5:39
0.008
0.036
0.003
0 . 0 1 2
0. 002
0.002
0.002
0.003
0 . 004
0.014
0 .012
0.008
0.012
0.017
0.01 9
0. 023
0 . 046
0. 107
0 . 1 59
0.003
0 . 04:3
161
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: AC017 - Teflon
- TEST NO. 5A
EXPOSED
MASS:
ELEMENT
AL
SI
p
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
AREA: 6.42 SQUARE
22+-
UG/CM2
279+-
532+-
043+-
297+-
OOO-i
009-i
231 +-
032+-
045-1
006-1
000+-
121+-
056-1
275+-
039-1
002-i
007+-
0.000+-
O. 0(")O-i
OUU+-
00 1 +-
000+-
001+-
006+-
000+-
013+-
032+-
015+-
006+-
015+-
000+-
175+-
0.001+-
0. 006-1
0.030
0.045
0.027
0.091
0.021
0.004
0=021
0. 003
0.009
0.002
0.001
0.015
0.012
0.017
0.007
0.001
0.004
0. 001
0. 001
0. 002
0.002
0.002
0. 009
0. 007
0. 005
0. 009
0. 012
0.013
0.016
0. 030
0.076
0. 119
0. 002
0.003
5E CM
.0 MICROGRAMS
UG /FILTER
1.
o
0.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
1.
0.
0.
789+-
739+-
306+-
90S+-
000+-
057+-
435+-
204+-
2S7+-
040+-
003n
773+-
36 1 +-
763+-
25 1 +-
012+-
043+-
OOO-i
OOO-i
003+-
004+-
000+-
007+-
037+-
Ot'u'H
205+-
097+-
041+-
093+-
000+-
123+-
007+-
040 +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
190
292
172
53 1
137
026
133
022
055
014
003
096
077
110
042
003
027
006
OOS
0 1 0
012
014
060
046
034
057
073
034
101
194
491
766
0 1 5
049
3.
16.
1.
8.
0.
0.
6.
0.
1.
0.
0.
-'
1.
7.
1.
0.
0.
0.
0.
"0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
5.
0.
0.
PERCENT
049 +-
327+-
373+-
533-1
OOO-i
255+-
631+-
917+-
293+-
132+-
0 11+-
501+-
623+-
957+-
129+-
053+ -
216+-
OOOn
000+-
0 1 3+-
0 1 6+-
000+-
033+-
1 66+-
OOO-i
363+-
921+-
434+-
133+-
443+-
OOO-i
051+-
029+-
179+-
"j
'
7.
0.
4.
0.
0.
3 .
0.
0.
0.
0.
1 .
0.
"'
'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
£ m
4.
0.
0.
721
635
992
666
613
164
065
425
632
104
036
A "!'"!
803
615
543
042
155
025
037
045
056
065
271
213
154
306
543
425
460
397
210
129
063
233
162
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 5A
PARTICLE SIZE: F
ANALYSIS ID: API49 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
423+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i--
-.'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
1.
0.
9.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
204+-
978+-
656+-
590+-
000+-
123+-
152+-
080+-
811+-
031+-
021+-
989+-
1 35+-
330+-
511+-
006+-
010+-
00 3 H
003+-
000+-
016+-
000+-
O'":l+-
063+-
009+-
001+-
002+-
000+-
039+-
041+-
255+-
000+-
002H
636+-
0*062
0.095
0. 119
0.454
0. Ill
0. 009
0.055
0.006
0.038
0.006
0.002
0.043
0.054
0.017
0.025
0.002
0.009
0.002
0.002
0.002
0.002
0.003
0.010
0.009
0.006
0.009
0.013
0.015
0.019
0.034
0.086
0. 127
0 . 0(1)3
0 . 03 1
7.
12.
4.
61.
0.
0.
7.
0.
5 .
0.
0.
6.
7.
2.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
4.
727+-
702+-
211+-
570+-
000+-
789+-
397+-
514+-
207 +-
1 98+-
133+-
349+-
289 H
116+-
231+-
042+-
063+-
013+-
021+-
002 <
103+-
000+-
137+-
404+-
056+-
006+-
014+-
000+-
253+-
265+-
637+-
OOOn
010+-
OS5+-
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
ol"
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
399
609
766
916
715
059
354
040
246
039
0 1 3
309
344
108
153
015
060
010
Oil
0 1 1
016
0 1 8
067
056
041
059
084
096
120
216
550
816
017
202
1.
-.
0.
14.
0.
0.
1.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
806+-
969+-
984+-
393+-
000+-
184+-
729+-
120+-
217+-
04 6 H
031+-
484+-
704+-
495+-
767+-
010+-
015+-
004+-
005-1
001+-
024+-
000+-
032+-
094+-
0 1 3+-
00 1 +-
003+-
000+-
059+-
062+-
333+-
000+-
002+-
955+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
102
158
181
760
167
0 1 4
092
0 1 0
064
009
003
030
090
028
041
004
014
002
003
00:":
004
004
016
013
0 1 0
014
020
022
023
051
1 29
191
004
052
163
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: CC033 - Nuclepore
- TEST NO. 5B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
24+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
AL
SI
p
'
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
ER-
RS
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
563H
159+-
047+-
39 1 +-
00 OH
0 1 OH
430n
050+-
083 +
007+-
008 +
206+-
091+-
435+-
061+-
00 1 +-
00 OH
0044
002 H
000+
016+-
001+-
000+
006+
001+-
000+-
000+-
02S+-
OOOn
OOOn
00 0+
00 OH
001+-
033 +-
0.
0.
0.
.0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
04S
075
02S
098
024
005
029
005
0 1 0
003
002
0 1 9
014
025
OOS
001
005
002
002
002
003
003
014
Oil
00:!:
012
0 1 8
0 1 9
025
045
112
174
003
0 1 0
l
=* B
7.
0.
'"'
0.
0.
"'
0.
0 .
0.
0.
1.
0.
"Tl
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
645+-
444+-
300n
507+-
OOOn
065+-
761-1
324+-
565+-
042+-
051+-
324+-
585+-
921+-
392+-
009n
000+-
026+-
012+-
OOOn
100+-
004+-
00 OH
039+-
00 6 H
000 H
OOO-i
1S2+-
000+-
000+ -
00 OH
00 OH
004+-
214+-
0.
0.
0.
0.
0.
0.
0.
0.
(I).
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
311
479
179
630
154
032
1S7
029
066
0 1 S
Oil
121
087
162
049
009
033
0 1 0
015
015
020
022
089
063
054
073
1 15
125
153
291
719
116
0 1 3
062
-15.
-31.
- 1.
-10.
0.
- 0.
-11.
- '1.
__ .-,
- 0.
- 0.
_ =1
_ -.
*
-12.
- 1.
- 0.
0.
- 0.
- _ 0 .
0 .
- 0.
- 0.
0 .
- 0 .
- 0.
0.
0.
- 0.
0.
0.
0.
0.
- 0.
- 0.
400+-
453+-
267+-
594+-
000+-
274+-
665+-
369n
177+-
215+-
594+
470+-
344+-
656+-
039 H
000+-
109n
050+-
000+
422+-
015+-
000 H
163+-
023+-
000+-
00 OH
767+-
OOOn
000 +-
000 H
000+-
017+-
90 3 H
6 . 63S
13.44
0.926
5 . 209
0.652
0. 17S
4 o 992
0 . 592
1 . 047
0 .107
0. 102
-2.41 S
1. 106
5.260
0.729
0.043
0. 141
0.063
0. 066
("> (V-.Fi
0. 197
0 . 0'? 1
0 .377
0 . 297
0.223
0.331
0 . 488
0 . 6 1 9
0. 669
1 . 23 1
O t~\ '"' /
'_' O O
4.715
0. 076
0. 464
164
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 5B
PARTICLE SIZE: F
ANALYSIS ID: AF150 - Teflon
EXPOSED AREA:
MASS:
.42 SQUARE CM
417+- 10 MICROGRAPH;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
Z>
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
1.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
054+-
509+-
642+-
781+-
000+-
122+-
929+-
081+-
769+-
031+-
015+-
924+-
122+-
158+-
486+-
006+-
004+-
002+-
007+-
005+-
012+-
000+-
010+-
082+-
006+-
004+-
006+-
00 OH
032+-
084+-
087+-
224+-
000+-
639+-
0 . 056
0.074
0.117
0 . 463
0.114
0.009
0.04?
0.005
0.036
0 . 006
0 . 002
0.045
0.053
0.009
0.024
0 . 002
0 . 009
0 . 002
0.002
0.002
0 . 003
0 . 003
0.011
0.010
0.007
0.010
0.014
0 . 0 1 6
0.020
0.037
0.083
0. 135
0.003
0 . 032
6.
9.
4.
62.
0.
0.
5.
0.
4.
0.
0.
5.
7.
1.
3.
0.
. o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
4.
768+-
689+-
124+-
797+-
000+-
785+-
966+-
520+-
935+-
202+-
097+-
931+-
202+-
015+-
122+-
038-f
027+-
015+-
043+-
030+-
077+-
OOOn
063+-
527+-
037+-
029+-
040+-
QQ(-)+_
204+-
539+-
558+-
437+-
000+-
105+-
0.
0.
0.
2 .
0.
0.
0.
0.
0.
0.
0.
0.
.0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
357
474
751
972
730
053
2 :=;£;
034
2'-'""'
037
012
290
340
060
151
015
060
0 1 0
0 1 2
012
016
0 1 9
071
062
043
064
091
1 03
127
240
566
865
017
203
1.
^i
0.
15.
0.
0.
1 ,.
0.
1.
0.
0.
1.
1.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
624+-
325+-
990H
071+-
000+-
188+-
432+-
125+-
184+-
043 +
023H
424+-
729+-
244+-
749+-
OO9H
OC>6+-
004+-
010+-
007+-
018+-
000+-
015+-
126+-
009+-
007+-
009+-
OOOH
049H
129+-
134+-
345+-
OOOn
935+-
0
0
0
0
o
o
o
o
0
o
o
0
. 0
o
0
o
0
0
0
o
0
o
o
o
o
0
0
o
0
0
0
0
0
0
. 094
. 127
. 1 32
. 800
. 175
.015
. 077
. 009
. 063
. 009
. 003
. 077
.-092
.016
. 040
. 004
. 0 1 4
. 002
. 003
. 003
. 004
. 005
.017
.015
.010
.015
. 022
. 025
. 030
. 058
. 136
. 203
. 004
. 054
165
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: C
ANALYSIS IDs AC01S - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 90+- 10 MICRGGRAM3
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
Z'
ri_
'-, l_
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
'AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
FB
1.
2.
0.
1.
o
»«/ o
0,
1.
0.
0.
0.
o
*'
0.
0.
0.
0.
0.
0.
0.
0.
n
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
316+-
673+-
299-1
033+-
OOO+
033+-
354+-
157+-
274+-
013+-
Ol "'+-
v_' X J '
436+-
221+-
04?+-
124+-
OOO-i
000+-
001+-
00 IH
Oi") OH
023+-
002+-
034-i
007 +-
003n
002 H
013+-
017+-
037+-
045+-
% -. ^i , _
152+-
OOOn
111+-
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
101
138
150
290
071
0 1 0
113
012
047
007
002
069
054
007
030
002
0 1 0
002
002
002
003
003
0 1 0
003
005
003
Oil
012
0 1 6
031
079
113
002
039
3.
17.
1.
6.
0.
0.
C;o
1.
1.
0.
0 .
3.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
1.
0.
0.
0.
452+-
191+-
920-1
952+-
000+
247+-
690+-
QG7+-
761+-
1 1 5+-
075-1
11.7+- .
417+-
317+-
793+-
000+-
00 0+
009+
003-t
000+
150+-
014+-
217+-
043+-
021+-
014+-
034+-
107+-
237+-
233+-
430+-
975+-
OOO+
713+-
0.
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
649
210
962
£:, '-.'"'
457
066
760
075
299
046
015
441
343
042
190
015
062
0 1 0
0 1 0
0 1 0
0 1 9
017
063
054
034
051
069
030
103
197
503
726
0 1 5
247
9.
19.
.i
7.
O
0.
9.
1.
1.
0.
o
'
1.
0.
0.
(")
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0 .
0.
414+-
149+-
139+-
743+-
OOO-i
275+-
679+-
121+-
962-1
123+-
flfiXH
472+-
573+-
353+-
334+-
("M'K'H
000 + -
010+-
009-i
O (")(")+
167+-
015+-
242+-
043+-
024+-
016+-
093-1
120+-
264+-
321+-
593+-
037+-
OOOH
794+-
1.274
".' CT -^i ~~t
1 . 093
2.246
0.51 0
0 . 079
1 370
0 . 1 50
0.393
0. 053
0 . 0 1 9
0.625
0.426
0 . 06 1
0 . 233
C> .017
0.069
0 .011
0.012
0 .011
0. 023
0.019
0.075
0 . 06 1
0 . 03:3
0.057
0. 077
0. 090
0.11 3
0 . 223
0.593
0.313
0 .017
0. 239
166
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS ID: AF151 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1762-f 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
S
CL
K
CA
TI
i i
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
FB
4 . 739+-
8.680+-
3.564+-
32.841+-
0.000+-
0.692+-
7.958+-
0.296+-
4.847+-
0. 161+-
0. 110+-
6.507+-
6.205+-
0.298+-
-' -'i- -+""
0.033+-
0 . 050+-
0. 002+-
0 .011 +-
0 . 005+-
0. 102+-
0 . OOOn
0.046+-
0.531+-
0.011+-
0. 022+-
0 . 007+-
0.018+-
0.096+-
0.243+-
0.306+-
0.470+-
0 .007+-
4.549+-
0.224
0.399
0.646
1 . 334
0.384
0. 037
0.371
0.033
0 . 225
0.030
0.007
0.300
0.284
0 . 020
04 C*- i
. 15,i
0. OO3
0.023
0.007
0.005
0.002
0 . 006
0.007
0 .015
0.028
0.008
0.012
0.015
0.018
0.023
0 . 046
0.112
0. 152
0 . 005
0.209
30.553+-
55.726+-
22.881+-
210.837+-
0.000+-
4.444+-
51.089+-
1 . 897+-
31. 116+-
1 . 034+-
0.706+-
41.772+-
39.833+-
1.911+-
21 .335+-
0.226+-
0.321+-
0.011+-
0.074+-
0.033+-
0 . 657+-
0. OOO+-
0.294+-
3.412+-
0.068+-
0. 144+-
0.045+-
0. 119+-
0.6 13+-
i c=;=;c.4.^
X M -'-l'_'^
5. 173+-
3.018+-
0.044+-
29.204+-
1 . 435
2.564
4. 150
9. 843
2.467
0. 240
2 . 332
0.227
1 . 446
0. 192
0.043
1 . 927
J £;"'":;
0. 131
0 . 979
0 . 050
0. 180
0. 043
0.034
0.015
0.039
0.042
0. 098
0. 177
0.043
0.075
0 . 099
0. 116
0. 149
0'* 1 t""l "*!
- . 2V -
0.721
0 . 975
0. 030
1 . 344
1.734+- 0.082
3. 162+- 0. 147
1 . 298+- 0 . 236
11.964+- 0.563
0 . 000+- 0 . 1 40
0.252+- 0.014
2.399+- '0. 136
0. l("'3-i O. 03 :~;
1.766+- 0.083
0. 05 9 H 0, 03 1
0.040+- 0.003
2.370+- 0. 110
2. 26 IH OTl 04
0. 103+- 0. 007
1'T' 1 1 J f "l f-\ CT /
m J, i i.1 >J U ' -
0.0 13+- 0.003
0.0 18+- 0.010
O.OOlH 0.002
0. 004+ 0. 002
O."002+- 0.001
0.0 37+- 0.002
O.OOO-i 0.002
0.0 17+- 0.006
0. 194+- 0.010
0.004+- 0.003
0.003+- 0.004
0.003+- 0.006
0.0 07+- 0.007
0.033+- 0.008
0.088+- 0.017
0.294+- 0.041
0. 171+- 0.055
0.002+- 0.002
1.657+- 0.077
167
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 6B
PARTICLE SIZE: C
ANALYSIS ID: CC089 - Nudepore
PAIRED W/ QUARTZ
EXPOSED AREA: 6.42 SQUARE CM
MASS GF DEPOSIT: 234+- 23 MICROGRAMS
ELEMENT
UG/CM2'
UG/FILTER
PERCENT
AL
SI
P
C;
CL
K
CA
TI
V
OR
MN
FE
NI
CLi
ZN
GA
AS
SE
ER
RE
SR
y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
*"'
4.
0.
3.
0.
0.
b-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
241+-
155+-
505+-
269+-
023+-
09 6 H
358+-
217+-
£,49+-
036-1
024+-
014+-
670+-
063+-
346+-
003+-
00 OH .
000 H
00 IH
000+-
040H
002-i
017+-
053+-
003 +-
0 1 5+-
000+-
027+-
000+-
OOO-i
045+-
114+-
000+
425+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
123
215
102
1 S 1
044
009
122
013
034
006
002
054
036
006
0 1 9
002
OOS
002
002
002
004
004
014
012
009
013
0 1 S
020
024
047
115
179
003
024
14.
26.
o
20.
0.
0.
15 =
1.
4.
0.
0.
6.
4.
0.
^ m
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
~l
-1 1-1 -. L _
O '-' '-' r
672+-
240+-
937+-
149+-
613+-
136+-
396+
169+-
232+-
152+-
511+-
301-t
436+-
221 + -
0 1 SH
OOO-i
OOO-i
OO5+-
000-t
254+-
0 1 1 +-
1 1 1 +-
375+-
013+-
097+-
OOO-i
175+-
OOO-i
000+-
23 S+-
734+-
OOO-i
730-1
0.
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
7SS
Z-T'-I
-' / -
655
159
2S5
060
7SO
031
217
033
015
347
?>:>
035
121
014
054
0 1 0
0 1 5
0 1 6
025
023
092
074
055
034
117
126
157
300
736
152
C> 1 9
156
6.
11.
1.
jCj
0.
0 .
6.
0.
1.
0.
0.
2.
1.
0.
0.
("i
0.
0.
0 .
0.
0.
0.
0.
0.
o
0 .
0.
0.
0.
0.
0.
0.
0.
1.
149+-
399-1
335+-
969+-
064+-
264+-
463+-
597+-
73 1 +-
099+-
065+-
7S1T+-
S33+-
136+-
949+-
OO:-:H
OOO-i
OOO-i
002'+
OOO-i
103+-
005-i
047+-
1 60+-
OOP.+-
04 1 +-
00 OH
075+-
OOOn
OOO-i
123+-
313+-
OOO-i
167+-
0 . 692
1 . 266
0.311
1.011
0. 122
0.036
0.713
0 . 063
0. 19S
0 . 0 1 9
0. 009
0 .311
0 . 205
0.024
0. 107
!") . (")(')/-,
0. 023
0 . 004
0. 007
0.007
0 .015
0 . 0 1 C>
0. 040
0.035
0 023
O.O ;-:/-,
O.ORCo
0 .054
0.067
0. 123
0 . 3 1 5
0 . 4'? 3
0 . 003
0. 133
168
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7A
PARTICLE SIZE: C
ANALYSIS ID: AGO 19 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
156+- 10 MICRO-GRAMS
ELEMENT
AL
SI
P
(--
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB-
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
UG/CM2
2.
4.
0.
2.
0.
0.
-t
4. m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
459+-
934+-
603+-
360+-
000+-
094+-
624+-
272+-
472+-
031+-
017+-
902+-
293+-
214+-
172+-
007+-
005+-
000+-
002+-
000+-
038+-
001+-
040+-
021+-
OOO+-
009+-
000+-
000+-
000+-
056+-
000+-
000+-
000+-
1 02+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1S2
339
274
587
146
013
220
020
085
012
003
128
101
017
055
004
013
002
002
002
004
003
Oil
012
006
009
012
014
017
035
087
128
003
067
15.
31.
3.
15.
0.
0.
16.
1.
3.
0.
0.
5.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
UG /FILTER
735+-
678+-
873+-
1 49+-
000+-
601+-
845+-
749+-
030+-
199+-
1 07+-
791+-
883+-
376+-
106+-
047+-
034+-
000+-
015+-
000+-
247+-
004+-
259+-
133+-
000+-
058+-
000+-
000+-
000+-
359+-
000+-
000+-
000+-
658+-
1.
"»
1.
o
v1
0.
0.
1.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
169
174
760
771
937
112
413
130
544
077
022
821
646
107
353
023
083
015
014
Oil
027
021
072
077
040
059
078
OS9
110
226
559
824
018
432
10.
20.
2.
9.
0.
0.
10.
1.
1.
0.
0.
-;__
1.
0.
0.
0.
0.
0.
0.
" 0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
PERCENT
126+-
321+-
484+-
718+-
000+-
386+-
805+-
122+-
944+-
127+-
069+-
715+-
203+-
883+-
710+-
030+-
022+-
000+-
010+-
000+-
159+-
002n
166+-
085+-
000+-
037+-
000+-
000+-
000+-
23 OH
000+-
000+-
000+-
422+-
0.
1.
1.
2
0.
0.
1.
0.
0.
0.
0.
0.
"o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
992
909
140
498
601
076
141
110
370
050
015
578
422
089
231
015
053
0 1 0
009
007
020
014
047
050
026
038
050
057
070
145
353
cr --I i~.
-' JL. '-'
0 1 2
273
169
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7A
PARTICLE SIZE: F
ANALYSIS ID: AF153 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
3911+- 10 MICROGRAMS
ELEMENT
AL
SI
p
i
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RB
SR
V
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PS
UG/CM2
.-,
1^
6.
67.
0.
1.
14.
0.
9.
0.
0.
12.
12.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
1.
0.
()
'->'
942+-
":(>=;+-
166+-
177+-
00 0+
321+-
336+-
7S7+-
1 64+-
313+-
233+-
443+-
404+-
637+-
673+-
06 1 +-
050+
013+-
027+-
0 13+
192+-
000+
020-i
027+-
019+-
013+-
010+-
OOO-i
1 1 6+-
454+-
332+-
273+-
OOfH
667+-
0.
0.
1.
-I
*
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
414
701
113
123
734
067
666
033
413
054
0 1 3
572
566
040
305
013
044
013
0 1 ("J
004
0 1 0
01 1
023
050
010
015
020
023
030
063
152
192
0(1)7
397
57.
93 .
431.
0.
S.
92.
C
«'
.'C1
v .
1.
79.
79.
4.
42.
0.
0.
0.
0.
0.
1.
0.
0.
6.
0.
0.
0.
0.
0.
-.'
ft.
1.
o.
55.
UGY FILTER
4 1 0+-
'"'=i':>+
534+-
277+-
000+-
432+-
034 H
050+-
334+-
010+-
530 -i
917+-
637+-
091+-
341+-
394+-
322+-
117+-
172+-
113+-
23 1 +-
000+-
126+-
593+-
125+-
037+-
063+-
OOO-i
742+-
913+-
553+-
755+-
000+
644+-
2.
4.
7.
20.
=!
0 ,
4.
0.
-i
0.
0.
'
o *>
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
(-) _
655
493
177
047
034
430
277
342
637
349
033
670
631
257
956
032
230
031
062
023
066
072
145
"~! '""' '""'
064
094
1 30
149
191
402
977
235
045
543
1.
"'
1.
11.
0.
0.
o
JU, 0
0.
1.
0.
0.
^ m
*1
0.
1.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(-)
V.'
1.
PERCENT
463+-
512+-
012+-
02 7+ -
OOO-i
217+-
^;<=;;-;j
129 + -
504 + -
051+-
039+-
043-1
036+-
105+-
095+-'
010+-
003 +-
003 H
004-1
003-i
031+-
Ot'H'H
00 3 -f
169+-
003+-
002+-
002+
OOO-i
0 19+-
074+-
2 1 9+-
045+-
Of) OH
423+-
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
T:r.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
{")
V.' »
0.
063
1 15
134
513
129
Oil
1 1 0
009
069
009
002
094
093
007
050
'.") o 2
007
002
002
00 1
002
002
004
003
002
002
003
004
005
0 1 0
025
032
OO 1
065
170
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7B
PARTICLE SIZE: C
ANALYSIS ID: CC090 - Nudepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
- 102+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
*"'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
O
*
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
239+-
432+-
000+-
000+-
000+-
000+-
004+-
135+-
000+-
004+-
004+-
000+-
000+-
038+-
000+-
000+-
OOO-i
001+-
004+-
000+-
019+-
005+-
000+-
000+-
000+-
OOS+-
000+-
00 1 +-
000+-
000+-
000+-
000+-
000 H
000+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
116
20S
155
346
086
Oil
131
013
051
OOS
003
074
061
007
033
002
009
002
003
003
004
004
014
0 1 3
OOS
013
01S
019
025
047
114
179
003
042
7.
15.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
957+-
614+-
000+ -
OOO-i
000+-
OOO-i
444+-
866+-
000+-
024+-
027+-
000+-
000+-
243+-
000+-
000+ -
OOOn
006+-
024 +-
OOOn
121+-
032+-
000+-
000+-
000+-
049+-
000+-
005+-
o<:>o+-
000+-
00 0+-
OOOH
000+-
000+-
0.
1.
0.
-I
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
748
334
99 S
219
553
069
841
084
323
049
017
4-75
390
046
214
015
057
0 1 3
017
016
025
024
092
08 1
052
083
118
123
159
303
734
151
017
269
- 7
-15
0
0
0
0'
- 6
- 0
0
- 0
- 0
0
0
- 0
0
0
o
- 0
- 0
0
- 0
- 0
0
0
0
- 0
0
- 0
0
0
0
0
0
0
. 835+-
. 374+-
. 000+-
. 000-t
. 000+-
. 000+-
. 345+-
. 853+-
. 000+-
. 024H
. 026+-
. 000+-
. 000+-
. 239+-
. 000 +-
. OOOn
. OOO+-
. 006+-
.-024+-
. 000 +-
. 119+-
. 032+-
. OOO-i
. 000+-
. OOO-i
. 043+-
. 000+-
. 005+-
. OOO-i
. OOO-i
. 000+-
. 000+-
. 000+-
. 00 OH
1 . 066
2. 004
0.982
2. 135
0.545
0. 06S
1 . 037
0.11 3
0 . 323
0.043
0 . 0 1 7
0-468
0.334
0.051
0.211
0 .014
O. 057
0.013
0.017
0.016
0.027
0.024
0.091
0.079
0 . 052
0.032
0.11 6
0. 121
0. 157
0.293
0.722
1. 133
0.017
0.265
171
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7B
PARTICLE SIZE: F
ANALYSIS ID: AF152 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 3186+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i^-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
EA
LA
HG
PB
7.
13.
5.
e;o
-"-.'
0.
i =
12.
0.
7.
0.
0.
10.
10.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
7.
416+-
514+-
667+-
769+-
000-i
163+-
223+
710+-
766+-
265+-
196+-
327+-
203+-
482+-
521+-
055+-
094+-
OOS+-
0 1 5+-
004-(
166+-
00 OH
055+-
843+-
0 1 7+-
OOO-i
023+-
023+-
086-1
452+-
126+-
224+-
005 H
147+-
0.
0.
1.
'^ m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
344
619
023
732
6S5
05.9
569
045
355
046
Oil
475
466
032
- cr -,
Oil
03S
0 1 0
003
003
009
009
0 1 3
041
008
0 1 0
015
0 1 3
022
052
119
142
006
. "' U *~I
47.
C'/_
'->_'
36 .
377 .
0.
7.
73.
4.
49.
1.
1.
66.
65.
3 .
35.
0.
0.
0.
0.
0.
1.
0.
0.
._! g
0.
0.
0.
0.
0.
2 .
7.
1.
0.
45.
609+-
763+-
335+-
296+-
OOOn
469H
474+-
553+-
356+-
703+-
257+-
3 00+- ,
535+-
097 H
448+-
356+-
603+
054+-
095+-
023+-
064+-
000+-
352+-
414+-
1 1 0+-
OOOn
145+-
145+-
553+-
904n
229n
439+-
034+-
3S4+-
!ki
*T'
6 .
17.
4.
0.
3.
0.
'"!"
0.
0.
*z?
-»
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Tl
209
975
597
540
"~* *~f *~f
330
653
239
278
297
069
047
99 1
205
620
071
245
067
051
017
057
059
117
265
049
067
099
113
143
336
765
912
036
103
1.
*Ti
1.
11.
0.
0.
ji!
0.
i.
0.
0.
rfL
!*i «
0.
i.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
495+-
724+-
142+-
344+-
000+-
234+-
463+-
143+-
565+-
053+-
03'"'+-
081-1
057+-
09 7 H
113+-
011+-
019n
002+-
003'H
001+-
03 3 H
O(VH
0 11+-
170+-
003+-
OOO-i
005-1
005+-
017+-
09 1 +-
227+-
045+-
00 1 H
440+-
0.070
0. 125
0.207
0.552
0 . 1 38
0 .. 0 1 2
0 .115
0 . OO9
0. 072
0. 009
0. 002
0. 096
0. 094
0 . 006
0 . 05 1
0. 002
0 . 008
0. 002
0.002
0.001
0. 002
0. 002
0 . 004
0 . 008
0.002
0 . 002
0 . 003
0.004
0 . 004
0.011
0. 024
0 . 02'?
(I) . 00 1
n. OA/-,
172
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7B REPEAT
PARTICLE SIZE"- C
ANALYSIS ID: CC091 - Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
3+- 10 MICRGORAMS
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
-'
CL
K.
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
570+-
236+-
084+-
286+-
OOQ+-
018+-
642+-
078+-
114+-
003+-
007+-
219+-
07?+-
112+-
035+-
000+-
001+-
002 +-
000 +-
000+-
01?+-
003+-
000+-
007+-
001+-
007+-
000+-
017+-
000+-
000+-
035+-
000+-
000+-
022+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
04?
080
043
10?
027
006
043
006
014
003
002
022
015
008
008
001
006
002
002
002
003
003
014
Oil
008
013
017
01?
024
046
114
173
003
012
3.
7.
0.
1.
0.
0.
4.
0.
0.
0.
0.
1.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
662+-
?33+-
542+-
834+-
000+-
114+-
11?+-
502+-
733+-
054+-
047+-
403+-
50?H
720+-
224+-
003+-
007+-
015+-
000+-
000+-
123+-
0 1 7+-
000+-
047+-
008+-
046+-
000+-
112+-
000+-
OOOn
228+-
000+
000+-
144+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
314
513
274
702
171
037
276
038
037
02 1
Oil
144
0?3
04?
052
0 1 0
036
0 1 0
014
016
021
022
08?
06?
054
082
111
123
157
2?3
733
114
017
073
-137
-2?7
-20.
-68.
0.
- 4.
-154
-13.
-27.
- 2.
- 1.
-52.
-1?.
-26.
""" C1 «
- 0.
- 0.
- 0.
0.
'0.
- 4.
- 0.
0.
- 1.
- 0.
- 1.
0.
- 4.
0.
0.
I"'.
6".
0.
- 5.
. 34+-
. 50+-
333+-
731+-
000+-
264+-
. 46+-
83?+-
505-t
013+-
760+-
624+-
0?2+-
??7+-
40?+-
11?+-
260n
566+-
OOO-i
OOO+-
600+-
626+-
000+-
748+-
284+-
740+-
000+-
196+-
000+-
000+-
544+-
000+ -
000+ -
381+-
515.2
1116
76 . ?4
25? . 3
6.413
16.05
57?. 3
70.66
103.2
7.590
6.613
1 97 . 4
71-69
101.3
31 .59
0 . 572
1 . 67?
2. 155
0.543
0.590
17.27
2.438
-1 -! ^ -!
_' _'-'_'
7 . 050
2 . 290
7.217
4. 163
16.40
5.894
1 1 . 00
42.20
41.76
0 . 635
-jt-\ r.'~!
x.U . _ /
173
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - TEST NO. 7B REPEAT
PARTICLE SIZE: F
ANALYSIS IB: AF154 - Teflon
EXPOSED AREA:
MASS:
6=42 SQUARE CM
5l7-( 10 MICROGRAM
ELEMENT
AL
SI
P
C-
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
UG/CM2
1.
1.
0.
12.
O
0.
1.
0.
1.
0.
0.
1.
1 .
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
10S+-
SOO-i
963+-
001+-
OOO+
167+-
474+-
047-1
072+-
043+-
026+-
395+-
456+-
773+-
0 1 1 +-
002-i
007-1
003+
002-(
01S+-
OOO-i
046+-
113+-
005+-
013+-
OOO-i
OOO-i
0 1 7+-
115+-
244+-
OOO-i
OOO-i
037+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
'0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
053
037
176
566
140
0 1 1
071
007
051
003
002
067
OAfi
007
037
003
012
002
002
001
002
003
009
00'?
005
003
Oil
0 1 2
015
031
072
111
002
049
7.
11.
6.
77.
0.
9.
0.
6.
0.
0.
' ' «
9,
0.
4.
0.
0.
0.
o .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
6.
IJG /FILTER
1 14+-
556+-
215+-
047+-
OOO-i
070+ -
466+-
300-1
334+-
273+-
165+-
957+-
-;4C;_|
514+-
962+-
07 1 +-
015+-
042'+-
02 2 -i
014+- '
114+-
OOO-i
296+-
757+-
031+-
03 1 H
OOO-i
OOO-i
107+-
739+-
565+-
000+-
000+-
655+-
0.
0.
1.
;: .
0.
0.
0.
(-)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
370
556
129
634
£','-><'-.
072
459
043
326
0 4 9
014
423
433
042
235
0 1 9
075
0 1 3
Oil
0 1 0
014
0 1 3
060
061
034
053
068
O7'r>
097
202
465
714
014
313
1.
'ii .
1 .
14.
0.
0.
1.
(-)
1
0.
0.
1 .
1 .
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
1 .
PERCENT
377+-
237+-
*i' v.-' --' ~^~ ~"
912+-
000 +-
207+-
33 2 H
O5:-: + -
332 + -
054+-
032H
734 + -
30-9+
960 +-
014 + -
003+
003+-
004-)
00 3+ -
022-i
OOO-i
057+-
147+-
006-1
016+-
OOO-i
OOO-i
021+-
143+-
303-1
OOO-i
000+-
233+
0.
0.
0.
0.
0.
0.
0.
1")
0 .
0.
0.
0.
0 .
0.
0 .
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
076
116
220
760
174
0 1 5
096
OOP:
063
0 1 0
003
039
092 -
003
049
004
0 1 5
003
002
002
003
003
012
0 1 2
007
0 1 0
013
015
019
039
090
133
003
066
174
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC07S _ Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM;
UG/FILTER
AL
SI
P
0
CL
K
CA
TI
V
CR
MN
FE
NI
CU
IN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
P3
0.000+-
0 . 000+-
0.000+-
0.000+-
0 . 000+-
0.001+-
0. OOOn
0 . 000+-
0.0 00+-
0 . 000+-
0 . 00 1 +-
0 . 003+-
0.000+-
o.ooi+-
0 . 000+-
0.000+-
0 . 000+-
0.000+-
0 . 000+-
0. 000 H
0 . 000-t
0.000+-
0 . 000+-
O.OOG+-
0.000+-
0 . 000+-
0 . 000+-
0 . OOOn
0 . 000+-
0.009+-
0.0 20+-
0 . 099+-
0.000+-
0.005+-
0.013
0.009
0.004
0 . 020
0.006
0.003
0.002
0.001
0.001
0 . 00 1
0.001
0.003
0 . 00 1
0 . 00 1
0 . 00 1
0.001
0.003
0.001
0.001
0.002
0.002
0 . 003
0.011
0 . 003
0.007
0.010
0.012
0.015
0.019
0.036
O.OS6
0. 136
0.002
0.005
0.000-*
0 . 000+-
0 . 000+-
0.000*-
0.000+-
0.007+-
0. 000+-
0 . 000+-
0.000+-
0.000+-
0 . 006+-
0.021+-
0 . 000+-
0.003+-
0 . 000+-
0.003+-
0.000+-
0.000+-
0 . 000+-
0. OOO-i
0. 000+-
0. 000-(
0.000+-
0.000+-
0 . 000+-
0 . 000+-
0.000+-
0. 000+-
0.000+-
0.060+-
0. 126+-
0.637+-
0. 000+-
0 . 032+-
O.OS2
0 . 059
0.024
0. 130
0.041
0.019
0.012
0 . 008
0 . 006
0.007
0.009
0 . 020
0 . OOS
0.009
0. 006
0.005
0.019
0.007
0.009
0.011
0 .014
0.017
0 . 073
0.051
0.042
0.063
0.030
0.097
0. 122
0.231
0.555
O.S75
0.014
0.031
175
-------
SA iF-'LE ID: SCHUYLKILL/OIL-FIRED POWER PLANT - FIELD BLANK
P,<---:TICLE SIZE: F
ANALYSIS ID: AF243 -
FIELD BLnNK
EXPOSED AREA:
Teflon
6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
31
P
:-:
CL
K
CA
TI
V
CR
11 N
FE
MI
CU
Z.M
GA
AS
SE
BR
RB
' ' C:
_ ' \
Y
ZR
no
Fi r~i
D
AG
. ^.
L-D
IN
SN
SB
BA
LA
HG
PB
0 . 00 1 +-
0. 004+-
0. 002 +-
0. OOOn
0. 000 +-
0. 000+-
0. 000 +-
0 . 000+-
0. 000+
0. 002+-
0. 000+-
0. 006+-
0. 002'H
0 . 002+-
0. OOOH
0. 002+-
0. OOOn
0 . 00 H
0. 001+-
0 . OOOn
0. 00 OH
0. OOOn
0. 009n
0. OOOn
0. 002+-
0. 003+-
0. OOOH
0. 012+-
0. 013+-
0. 026+-
O. O:~:On
0 . 000+-
0. 001+-
0 . 00 1 H
0 . 0 1 0
0 . 007
0. 004
0. 020
0. 007
0. 002
0. 002
0 . 00 1
0 . 00 1
0 . 00 1
0. 001
0. 003
0 . 00 1
0 . 00 1
0. 001
0 . 00 1
O. OO:~;
0 . 00 1
0. 001
0. 002
0 . 002
0. 002
0 .011
0. 007
0. 007
0. 009
0 . 0 1 2
0 . 0 1 4
0 .017
0. 032
0. OSO
0. 124
0 . 002
0. 004
0. 007+-
0.026*-
0 . 0 10+-
0. OOOH
0. 002+-
0.000+-
0. OOO+-
0. 003+-
0. 002-f
0.014+-
0. 003H
0. 036n
0. 012+-
0. OK>+-
0. 000+-
0. 016+-
(") O O U H
0 . 008-1
0. 003+-
C). OOOH
0 . OOOn
0. 00 0-f
0. 06 OH
0. 000+--
0.012+-
0. 03 OH
0. OOOH
0.076+-
0. 116+-
0. 169+-
0. 1914-
0. OOOn
0. 005+-
0. 004+-
0.065
0.045
0. 02:4
0. 127
0. 044
0 . 0 1 4
0 0 1 0
0 . 007
(") . ("; O 5
0. 007
0. 003
0. 020
0. 003
' 0 . 009
0 . 003
0. 006
Or"* 1 ~7
- . O 1 /
0. 007
O O '")'"'
0 .011
0 . 0 1 3
0 . 0 1 !
0 . 063
0. 047
0. 043
0. 059
0. 079
0 . 09 1
0. 107
0 205
(") ^i 1 1
»-; > * ±, j.
0.795
0 .011
O.. (')"""'
176
-------
SAMPLE ID: SCHUYLKILL/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: CC123 - Nuclepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
- FIELD BLANK
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
*--
J
CL
K
CA
TI
V
CR
MIM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HO
FB
0.0 17+-
0 . 023+-
0.000+-
0. OOOH
0.011+-
0.000+-
0.001+-
0.000+-
0.001+-
0.000+-
0.000+-
0 . 002+-
0 . 000+-
0.000+-
0 . 000+-
0.001+-
0.007+-
0.000+-
0 . 000+-
0 . 002+-
0.000+-
0 . 00 1 +-
0 . 000+-
0 . 000+-
0 . 000+-
0.015+-
0.000+-
0.011+-
0. 000+-
0.005+-
0.056+-
0.096+-
0.000+-
0 . 000+-
0.025
0 . 0 1 9
0.010
0 . 022
0.010
0 . 003
0.002
0 . 00 1
0 . 00 1
0.002
0.002
0.004
0 . 00 1
0.002
0.001
0.001
0.004
0 . 00 1
0.002
0 . 002
0 . 00:3
0.003
0.014
0.010
0.009
0.012
0.01S
0.020
0 . 024
0 . 044
0. 109
0. 173
0.003
0.006
0. 111+-
0. 146+-
0.000+-
0.000+-
0 . 073+-
0 . 00 1 +-
0.005+-
0. 000+-
0.003+-
0.000+-
0 . 000+-
0.013+-
. 0.000+-
0 . 000+-
0. 00 OH
0 . 003+-
0.048+-
0.000+-
0.001+-
0. 010+-
0. 000+-
0.006+-
0. 000+-
0 . OOOn
0. 000+-
0.095+-
0.000+-
0.072+-
0.000+-
0 . 035+-
0 . 358+-
0.619+-
0. 000+-
0 . 000+-
0. 161
0. 124
0.062
0 .143
0.063
0.020
0.015
0 . 009
0. 006
0 .011
0 . 0 1 0
0.024
0. 009
0 . 0 1 0
0.006
0 . 006
0 . 025
0. 009
0.014
0.015
o.Ol 9
0.022
0.088
0.067
0 . 056
0 . 075
0.11 3
0. 129
0 . 1 52
0.284
0.701
1. 112
0 . 0 1 6
0.041
177
-------
SAMPLE ID: EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 1A
PARTICLE SIZE: C
ANALYSIS ID: AC020 - Teflon
FLAKE NEAR CENTER OF FILTER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 63+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
i *
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
IK
MO
PD
AG
CD
IN
3N
SB
BA
LA
HG
PB
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("I
0.
449+-
306 +-
230n
336+-
OOOn
034-1
925+-
069+
153+-
01 IH
005 +
3 15+-
1 90 H
016+-
170+-
003-i
005+-
00 1 +-
00 1 H
OOOH
010+
OOO-i
029H
OOO-i
009-1
002+
00 1 +-
OOO-i
OOOn
051+-
00 2 H
OOO-i
OOOn
3 10+-
0.
0.
0.
0.
0.
0.
0.
0 0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
039
059
037
133
034
007
066
006
0 1 4
003
001
03 1
023
003
0 1 9
002
0 1 0
001
002
001
002
OO:";
009
007
006
008
0 1 0
0 1 2
014
030
071
117
002
036
^
5.
1.
5.
O
0.
5.
0.
1.
0.
0.
1.
0 .
1.
0.
0.
0.
o
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
383+-
177+-
476+-
633+-
OOOn
221+-
94 OH
445+-
012+-
070+-
034+-
019+-
220+-
100+-
093+-
020H
034 +-
007-1
OO5IH
OOO+
062+-
000+-
139+-
OOO-i
056+-
014+-
004+
OOO-i
00 1 +-
324+-
010+
OOO-i
OOO-i
991+-
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
251
380
561
337
215
042
421
( '35
i >9 1
ol9
0 1 0
199
1 46
022
12.1
015
062
009
0 1 0
0 1 0
013
0 1 6
060
042
0:36
050
064
080
091
196
459
748
0 1 3
22'"'
4.
8.
<*. *
9.
0.
0.
9 .
0.
1.
0.
0 .
o .
1.
0.
1.
0.
0.
0.
0.
0.
0.
o
0.
O
0.
0.
0.
0.
0.
0.
0.
ft
0.
T*
569+-
203-1
339-i
012+--
OOO+-
351+-
4 12+-
704 +-
604+ -
lll-i
054+-
20OH
933+-
158+-
731-i
031+-
054 +-
011+-
003-t
000 +
098 +-
OOOH-
299-i
OOOH
039 H
022+-
007+-
00 OH
002-1
514+-
016+-
OOOH
OOO-i
154+-
0.826
1 . 433
0. 963
2. 003
0. 341
0.087
1 . 634
0. 125
0 . 292
0. 035
0 . 0 1 7
0.397
0 . 384
0. 043
(") '"* '~' ~
0. 024
0. 093
0.015
0 . 0 1 6
0 .015
0. 026
0. 026
0. 106
0. 067
0 . 059
0 . 080
0 . 1 02
0. 126
0. 145
0.321
0.727
1 . 185
0. 020
0 .617
178
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 1A
PARTICLE SIZE: F
ANALYSIS ID: AF155 - Teflon
DEPOSIT SMEARED
EXPOSED AREA: 6.42 SQUARE CM
MASS: 639+- 10 MICROGRAM3
ELEME1M-
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
i^-
CL
K
Cft
TI
V
CR
MM
FE
IMI
CU
IN
GA
AS
.-c*
-'C.
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
~j
1.
12.
0.
0.
+L m
0.
0.
0.
0.
7'
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-I
467+-
368+-
697+-
078+-
000+-
23 1 +-
393+-
000+-
844+-
047+-
03S+-
050+-
840+-
141+-
470+-
008+-
000+-
00 1 +-
006+-
000+-
021+-
000+-
000 +-
118+-
0 1 4+-
012+-
014+-
0 1 5+-
000+-
217+-
4 1 3+-
30 1 +-
002+-
!=:*P,-i--
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
074
112
3 OS:
579
144
015
1 38
021
043
007
003
097
086
009
068
005
021
004
004
002
003
005
Oil
0 1 0
006
009
012
0 1 3
017
03d.
081
113
003
134
9_
15.
10.
77.
0.
1.
13.
0.
5.
0.
0.
13.
11.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
^
1.
0.
1F:
419+-
204+-
894+-
533+-
OOO+-
484+-
575+-
OOOH
421+-
300+-
243-f
163+-
312+-
907+-
439+-
049+-
000+-
009+ -
037+-
000+-
137+-
000 +
OOOn
756+-
088+-
074+-
092+-
099+-
OOO-i
396+-
637+-
933+-
010+-
542+-
0.
0.
1.
«>
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
A 76
722
977
716
927
095
335
133
273
045
0 1 9
620
55-0
060
433
0:33
134
023
023
Oil
0 1 7
029
071
061
038
053
076
036
106
229
521
760
022
8 5:-;
1.
JL. .
1.
12.
0.
0.
2.
0.
0.
0.
0.
ji. .
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
*1
474+-
38 OH
705+
136+-
000+-
232'H
90 7+ -
000 +-
349+-
Q47+-
038 + -
060 + -
349 i
142+-
477+-
003+-
OOOn
00 1 +-
006-1
000 +-
021+-
000+--
00 OH
1 1 3+-
014+-
012+-
014+-
015+-
000 -i
219+-
42 1 +-
303 +-
002 + -
9O2 H
0.073
0. 119
0.311
0.612
0. l^-
0 . 0 1 5
0. 146
0 . 022
O.045
0. 007
0.003
0. 102
0 .-09 1
0 , 0 1 0
0.072
0. 005
0.021
0. 004
0. 004
0 . 002'
0. 00?
0. 005
0 . 0 1 1
0 . 0 1 0
0.006
0 . 009
0.012
0 . 0 1 4
0 . 0 1 7
0 . 036
0 . 032
0. 119
0 . 003
0. 142
179
-------
SAMPLE ID: EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 2A
PARTICLE SIZE: C
ANALYSIS ID: AC021 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
43+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
n
0.
0.
0.
0.
0.
0.
0.
0.
0.
()
0.
311+-
606+-
171+-
67 1 +-
000-(
030+-
712+-
062 +
125+-
00 7 H
005+-
2 18+-
1 53+-
013+-
121+-
000+-
000 +-
OOO-i
OOO-i
00 IH
006+-
003 +
OOfH
00 7 H
003+-
015+-
010+-
000 H
000+-
000+-
173+-
274+-
(")(") :"n
249+-
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0 .
0.
0.
0,
0 =
0.
0.
0.
0.
0.
0.
0.
0.
o.
031
047
072
120
02S
O <">/-,
052
005
01 1
003
00 1
024
019
003
0 1 5
002
oos
001
00 1
00 1
002
002
009
0(36
005
OOS
Oil
012
015
029
072
115
002
02?
1.
'
1.
4.
0.
0.
4.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
1.
993-1
390-f
097 +-
308-1
000+-
193+-
573+-
393+-
305+-
043-1
033+-
402+- .
935+-
083-1
774+-
001+-
OOOn
00 OH
00 OH
009+
037+-
018+-
OOO-i
047+-
C 1 6+-
099n
067+-
000+-
000+
000+-
141+-
757+-
017+-
598+-
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
197
304
462
770
133
039
~i er
033
074
0 1 6
009
157
122
020
095
012
054
008
009
009
0 1 3
0 1 5
060
041
032
051
069
075
094
1 83
459
738
015
1 33
4.
o
*L.
' *
0.
o.
9.
0.
1.
0.
0.
2
2.
0.
1.
0.
("i
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
ji. .
* '
("1
123+-
030-1
265+-
393+-
000-f
399+-
440+-
822+-
662n
089 +-
063n
394H-
034+-
171+-
597+-
002-1
OOi'lH--
OOO-i
000+
013 + -
076+-
036+-
OOO-i
097+-
034+-
205+-
138+-
OOO-i
000+-
OOO-i
356+-
627+-
():.«=;+_
299 + -
0.943
1 . 773
1 . 063
" 4'~"~'
0. 377
0 .115
2 . 063
0 . 1 83
0.375
0. 039
0 .024
0 . 680
0 . 489
0.055
0.3S4
0.026
0 . 112
0 .017
0 . 0 1 9
0 - 0 1 9
0.031
0.033
0 . 1 24
0. 087
0 . 066
0.11 3
0. 146
0. 154
0. 194
0.379
1 066
1 . 693
0 . 032
0.779
180
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF136 - Teflon
DEPOSIT SMEARED
EXPOSED AREA: 6.42 SQUARE CM
MASS: 546+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
2.
1.
10.
0.
0.
'"!'
0.
0.
0.
0.
1.
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2 .
137+-
110+-
522+-
874+-
000+-
194+-
439+-
000+-
671+-
034-1
032+-
752+-
522+-
117+-
209+-
008H
000 H
000+-
007+-
001+-
019+-
OOO-i
000+-
099+-
004+-
002+-
012+-
019+-
039+-
117+-
364+-
314+-
000+-
244+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
059
101
276
520
129
0 1 3
116
021
035
006
003
OS3
071
008
056
004
0 1 8
003
003
002
002
004
010
009
005
009
012
014
016
031
080
119
003
104
7.
13.
9.
69.
0.
1.
15.
0.
4.
0.
0.
11.
9.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.-,
.b.
o
+-,
0.
14.
299+-
547+-
773+-
814+-
000+-
243+-
65S+-
000+-
309+-
221+-
207+-
251+-
771+-
749+-
765+-
OSO-i
000+-
002+-
043+-
004+-
122+-
OOO-i
000+-
632+-
029+-
0 1 3+-
076+-
121+-
251+-
752+-
337+-
0 1 4+-
000+-
409-1
0.
0.
1.
'
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
380
647
774
339
.- -! .".
O *1 0
085
745
1 36
224
038
017
532
457
051
362
028
116
022
019
Oil
0 1 6
025
067
057
034
056
075
037
103
202
513
764
0 1 3
670
1.
2.
1.
12.
0.
0.
. i
jL.
0.
0.
0.
0.
.ti.
1.
0.
1.
o
("1
0.
_'-''
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
jj *
333+-
483+-
791+-
797+-
000+-
229+-
870+-
OOO-i
790+ -
04 1 +-
038+-
062+--
791+--
137+-
423+-
OO9+-
Ot')OH
OOO-l
OOS-i
001+-
022n
OOO-i
000+-
1 1 6+-
005+-
002+-
0 1 4+-
022+-
046+-
133+-
423+-
369+-
000+-
641+-
0.074
0. 127
0.327
0 . 655
0. 152
0 . 0 1 6
0. 146
0.025
0. 044
0 . 007
0. 003
0. 105
0. 090
0.01 0
0 . 07 1
O. OOFI
0 . 02 1
0.004
0.003
0. 002
0 . OO3
("). OO!=1
0.012
0 .011
0.006
0 . 0 1 0
0.014
0 . 0 1 6
0.019
0.037
0.094
0. 140
0. 003
0. 132
181
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 3A
PARTICLE SIZE: C
ANALYSIS ID: AC022 - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 100+- 10 MICROGRAMS
ELEMENT
UG/CM2
IJG/FILTER
PERCENT
AL
SI
P
i^-
CL
K
CA
TI
V
OR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
1.
0.
1.
O
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
573+-
230+-
343+-
'"iiCi !-;+
(")(") ("H
052+-
405+-
09S+-
236+-
017+-
009 + -
4?6+-
323-1
019-t
252+-
004-1
000+-
001+-
000+-
002 +-
015+-
001+-
009-t
02S+-
OOO-i
016+-
019+-
OOO-i
006 H
000 -i
20 6+-
127+-
000-(
439+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
049
OSS
137
207
051
009
098
008
021
004
002
046
035
004
02S
DO--;
012
002
002
002
003
003
012
009
006.
0 1 0
014
015
0 1 9
037
09 1
141
003
052
'O
7.
2 .
fl.
0.
0.
9
0.
1.
0.
0.
-'
j± m
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
--1
682+-
893+-
205-i
077+-
00 OH
--. --i --i . _
021+-
631+-
512+-
107+-
053-1
185+-
072+-
121+-
613+-
025+-
00 OH
007 +-
OOO-i
015+-
099+-
005+-
059+-
1S2+-
000 -i
1 0 1 +-
120+-
000+
037+-
000+-
324+-
S16+-
000+
13S+-
0.
0.
0.
1.
0.
t).
(1.
M.
().
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
317
562
879
331
325
056
631
049-
1 36
026
0 1 3
29 8
224
029
17S
0 1 8
077
013
0 1 3
012"
0 1 8
02 1
074
056
039
063
090
096
123
*.--!.-
582
904
0 1 8
334
'
7.
jL .
C;
0.
0.
9.
0.
1.
0.
0.
~;
Jl! a
0.
1.
0.
0.
0.
O
0.
0.
(")
0
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
' "
678+-
889+-
202 +-
069-t
000+-
332+-
0 1 1 +-
630-i
5 1 0+-
107+-
058 -i
181+-
070+-
121 +-
616+-
02 5+-
OOO-i
007-t
OOO-t
0 15+-
099 H
OO5 + -
05Q+-
132+-
000+-
101 +-
120+-
000+-
037+-
OOO-i
323-1
815+-
000 H
134+-
0.485
0.967
0.905
1 . 555
0 . 325
0. 065
1 o 099
0.079
0.203
0 . 028
0 .014
0.435
On 305
0. 031
0. 240
0 . 0 1 9
0. 076
0 . 0 1 3
0 . 0 1 3
0 .012
0. 021
O. 021
0 . 075
0. 059
0 . 039
0 . 063
0.090
0.096
0. 123
0.23S
0 . 596
0. 907
0 . 0 1 3
0.457
182
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 3A
PARTICLE SIZE: F
ANALYSIS ID: AF157- Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1079+- 10 MICRO-GRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
S
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
^r
3.
2.
19.
0.
0.
4.
0.
1.
0.
0.
3.
2.
0.
v m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
028 +-
571+-
734+-
379+-
000+-
353+-
392+-
1.06+-
385+-
069+-
067+-
098+-
743+-
204+-
240+-
013+-
002+-
001+-
016+-
000+-
040+-
00 OH
024n
184+-
016+-
OOOn
0 1 5+-
003 H
074+-
137+-
570+-
117+-
003+-
107+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 00
167
505
918
230
021
206
025
065
0 1 0
004
144
127
013
103
007
026
006
005
002
003
006
013
012
007
009
013
014
019
035
092
126
004
1 39
13.
22.
17.
124.
0.
2.
7 pi
0.
P..
0.
0.
1 9 .
17.
1.
14.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
o.
0.
0.
*
0.
0.
26.
018+-
929+-
375+-
414+-
000+-
263+-
198+-
678+-
895+-
444+-
427+-
339+-
613+-
313+-
380+-
083H
016+-
004+-
100+-
000+-
259+-
000+-
154+-
180+-
1 0 1 +-
000+-
09'? H
0 1 6+-
477+-
379+-
65S+-
751+-
017+-
370+-
0.
1.
-*
5.
1.
0.
1.
0.
0.
0.
0.
0.
o..
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
1.
639
073
242
895
474
1 36
324
158
416
063
026
927
8 1 3
082
663
043
167
039
031
0 1 3
022
033
032
080
042
060
084
O'-''"-!
120
223
593
811
026
215
1.
.*!.
1.
11.
0.
0.
2.
0.
0.
0.
0.
1.
1.
0.
1.
o
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
207+-
125+-
657+-
532+-
OOOn
210+-
614+-
063-1- -
324+-
04-1+-
040+-
343+-
633+-
122+-
333-f
(-)(-) C;.j
001+-
000+-
009 +-
OOOn
024+-
OOOn
014+-
109+-
009+-
000+-
009+-
002+-
044+-
081+-
339 H
070+-
002+-
444+-
0.060
0. 101
0.301
0 . 557
0. 137
0.013
0. 125
0.015
0.039
0. 006
0.002
0. 088
_0. 077
0. 003
0. 063
0. 004
0 . 0 1 6
0. 004
0.003
0. 001
0 . 002
0. 004
0. 008
0.007
0.004
0 . 006
0.003
0.009
0 .011
0.021
0 . 055
0.075
0. 002
0.115
183
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED
PARTICLE SIZE: C
ANALYSIS ID: AC023 - Teflon
LARGE BLACK PARTICLE ON FILTER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 10+- 10 MICROGRAMS
POWER PLANT - TEST NO. 4A
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SP
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
C).
0.
056+-
192+-
038 +-
115+-
000+-
003-i
199+-
01?+-
038 +-
00 3 H
OOO-i
079-1
043+-
OOO-i
037+-
002-1
002-i
002+-
00 IH
006 H
004+-
001+-
000+-
002+-
006 +-
023+-
024-1
000+-
000+-
OOO-i
022+-
OOO-i
OOO-i
061+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
01 S
021
025
050
012
004
0 1 8
003
005
002
002
0 1 1
00 S
002
006
001
005
00 1
002
002
003
003
012
oos
007
0 1 1
015
016
020
040
093
147
002
Oil
0.
1.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
C.
362+-
235+-
246+-
741+-
000 +-
02 1 +-
275+-
123+-
241+-
016+-
003+-
504+-
275+-
002+-
235+-
0 15-i
013-i
0 1 1 +-
003+'-
038-1
024+-
005+-
OOO-i
015+-
036+-
149+-
151+-
000+-
000+-
000+-
140+-
OOO-i
OOO-i
39 1 +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
115
134
159
320
076
025
115
020
031
012
0 1 0
072
052
013
041
009
034
( >08
oil -
013
0 1 6
0 1 S
07S
054
045
069
097
103
129
259
593
942
014
069
3.
12.
.
JL m
7.
0.
'"' .
12.
1.
r>
J m
0.
0.
5.
*^»
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
0.
0.
1.
0.
n
'_' »
624+-
346-H
465-1
407+-
OOO-i
215+-
754+-
233-1
411+-
162+-
028 +-
04 l-i"-
748+-
022+-
354+-
146+-
127+-
113+-
035+-
376+-
242+-
0474-
000+-
1 46+-
356+-
487+-
510+-
OOO-i
OOO-i
OOO-i
403-1
OOO-i
OO(")H
908-1
3 . 803
12.42
2 . 934
8 .071
0.762
0 . 327
1 2 . 3 1
1 . 250
2.431
0. 200
0 . 1 0 1
5 . 092
2.797
0. 135
"' '1' O O
0. 170
0 . 367
0. 140
0 . 11 6
0.397
0 . 292
0. 189
0.776
0 . 564
0.570
1 . 64 1
1 . 795
1 . 03 1
1 . 29 1
.-. c t-i --
6. 139
9 .415
0. 141
3. 969
184
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT
PARTICLE SIZE: F
ANALYSIS ID: AF15S - Teflon
- TEST NO. 4A
EXPOSED AREA:
MASS".
6.42 SQUARE CM
190+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
c-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
FD
AG
CD
IN
SN
SB
BA
LA
1_ ~
HG
PB
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0-.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
o
V
0.
0.
452+-
842+-
632+-
962+-
000+-
062+-
941+-
000+-
297+-
019+-
014+-
687+-
652+-
043+-
520+-
002+-
009+-
001+-
006+ -
000 +-
00 4 H
002+-
031+-
020+-
004+-
000+-
007+-
002+-
023+-
097+-
356+-
175-1
OO2+-
731+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
*-*
0.
0.
023
043
115
197
047
006
047
019
016
003
002
034
032
004
025
002
010
00 1
002
00 1
002
002
009
006
005
008
010
012
014
028
074
002
036
4^.
5.
4.
25.
0.
0.
6.
0.
1.
0.
0.
4.
4.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
1 .
0.
4.
901+-
408+-
059+-
433+-
000+-
399+-
04 2+-
OOO-i
905+-
121+-
093+-
4 12+-
1 85+-
273+-
340+-
014+-
060+-
003+-
041+-
000-i
023+-
014+-
200+-
130+-
024+-
000+-
04 6+-
015+-
148+-
625+-
284+-
122-1
013+-
69 1 +-
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
130
273
739
265
305
041
300
123
105
021
0 1 0
220
203
02'6
161
015
063
009
Oil
009
0 1 2
0 1 6
056
040
03 1
050
067
076
091
1 83
473
677
014
'*' ""' !~!
i.
2.
v m
13.
0.
0.
If m
0.
1.
0.
0.
2.
^ .
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
o
0.
ii
5J27+-
8J4 6 +-
J_|3£, + _
3S6+-
oioo+-
2)10-1
1J80+-
o!oo+-
o;02+-
06 4 H
049+-
322+-
203+-
1,46+-
753+-
OJ07+-
032 +-
002+-
021+-
OOO-i
OI12+-
007 +-
105+-
068+-
01 2+-
opo+-
0^24+-
0[03+-
073+-
329+-
202+-
FI9O-1
007+-
469+-
0. 124
0 . 203
0 . 405
0.969
0. 160
0 . 024
0. 230
0 . 065
0.077
0 .011
0. 006
0 . 1 68
0. 158
0.016
0 . 1 25
0.003
0. 033
0. 005
O. rx")/-.
0 . 005
0 . 006
0.003
0. 030
0.021
0 . 0 1 6
0.026
0.035
0.040
0.043
0.093
0.257
0 . 357
0.007
0. 177
185
-------
SAMPLE ID: OIL-EDDYSTONE/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: CC092 - Nuclepore
- TEST NO. 4B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
14+- 10 MICROGRAM:;
ELEMENT
IJG/CM2
UC/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
A 6
CD
IN
SN
SB
Bft
LA
HG
PB
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Oc
0.
0.
0.
0.
0.
0»
0.
0.
0.
0.
0.
0.
0.
(-,
0 .
124+-
206 +-
041+-
219+-
000+-
OOO-i
28 1 +-
014+-
044+-
00 1 +-
004 +-
08 1 +-
054+-
005+-
040+-
000+-
OOO-i
OOO-i
002-1
OOO-i
007-1
000+-
000 +
005+-
OOO-i
007+-
000+
010+-
000 +-
00 OH
000+-
000+-
OOOn
OS7+-
0.
0.
0.
0.
Oc
0.
Oc
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
029
023
026
053
014
004
021
003
005
002
002
Oil
009
002
006
00 1
006
001
002
002
003
003
014
Oil
00:3
0 1 3
0 1 8
0 1 9
025
045
112
174
003
012
0.
1.
0.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
793+-
320+-
261+-
408-)
000+-
000 +-
802-1
090+-
234+-
005+-
026+-
523+
344+-
034 +-
255-1
000 +-
OOO-i
OOO-i
0 1 1 +-
000+-
042+-
OOO-i
OOO-i
034-1
000+-
043-1
OO(~H
065+-
000+-
000+-
OOO-i
000+-
000+-
557+-
0.
0.
0.
0.
0.
0.
Oc
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Oc
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0 .
0.
136
177
165
342
089
026
137
016
033
014
0 1 0
073
055
014
041
009
033
009
015
0 1 6
0 1 9
022
089
068
052
083
115
123
158
292
719
119
017
079
5.
9.
1.
10.
0.
0.
12.
0.
2 .
0.
0.
.*
2.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
n
0.
(-,
4.
744+-
507+-
876+-
136+-
OOO-i
OOO-i
974+-
649+-
045+-
037+-
135+-
766+-
474+-
243+-
835+-
OOO-i
000 H
000-(
083+-
000+
302+
000+-
OOO-i
247+-
000+-
30 7+-
OOO-i
468+-
000+-
OOO-i
(-)(-|(-,^
000+
OOfn
011+-
4 . 343
6.963
1 . 80 1
7.702
0.640
0. 187
9 . 393
0.482
1.491
0 . 1 04
0.151
2.762
1 . 825
0.204
1 . 354
0. 067
0 . 275
0. 064
0. 123
0=11 4
0.257
0. 157
0 . 643
0.523
0.376
0 . 634
(") OTO
0. 945
1. 138
2. 103
5. 178
8 . 057
0 . 121
2.943
186
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT
PARTICLE SIZE: F
ANALYSIS ID: AF159 - Teflon
- TEST NO. 4B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
181+- 10 MICRQGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
CL
K
f~. /\
CA
1" T
TI
V
CR
MN
FE
NI
. , I
L.IJ
ZN
GA
AS
SE
BR
RB
SR
T ^>
ZR
MO
^iT"i
FD
AG
CD
IN
I* h I
!r.N
SB
BA
LA
HG
riT~i
PE
0.362+-
0.781+-
0.599+-
3.892+-
0 . 000+-
0.074+-
0.838+-
0.033+-
0.298+-
0.009+-
0 . 0 1 6+-
0. 676+-
0.629+-
0.045+-
0.491+-
0 . 00 1 +-
0. 000+-
0.000+-
0.004+-
0. 000+-
0.007+-
0.003+-
0.050+-
0.013+-
0.0 12+-
0 . 009+-
0.000+-
0 . 000+-
0.044+-
0. 101+-
0.057+-
0. 172+-
0.003+-
0.7 19+-
0. 024
0 . 040
0. 109
0. 194
0.047
0.007
0 . 04:3
0.004
0.013
0.003
0.002
0.034
0.031
0.004
0.024
0.002
. 0.010
0.001
0.002
0.002
0 . 002
0.003
0 . 0 1 0
0.007
0.006
0.009
0.011
0.013
0.016
0.031
0.072
0. 113
0.002
0.035
2.322+-
5.013+-
3.S44+-
24 . 986+-
0.000+-
0.478+-
5.379+-
0.371+-
1.916+-
0.056+-
0. 101+-
4.340+-
4.036+-
0.287+-
3. 155+-
0 . 008+-
0.000+-
0.000+-
0.029+-
0.000+-
0.044+-
0.018+-
0.322+-
0. 11S+-
0.075+-
0.061+-
0.000+-
0.000+-
0 . 28 1 +-
0.650+-
0.367+-
1 . 1 06+-
0.021+-
4.613+-
0. 156
0 . 257
0 . 700
1 . 245
0 . 300
0.047
0.273
0 . 027
0.095
0.013
0.011
0.217
0. 196
0:026
0. 152
0.015
0 . 063
0.009
0 .011
0 . 0 1 0
0 . 0 1 3
0.017
0 . 063
0.043
0.037
0. 057
0.070
0 . 03 1
0 . 1 03
0. 196
0 . 462
0.736
0 . 0 1 6
0.225
1 . 2R2-I O 1 1
«* W A~ ' *_* i i j^,
2.768+- 0.209
2.123-1 0.404
13.796+- 1.026
0.000+- 0. 166
0.264+- 0.030
2.970-1 0.223
0. 205-1 0. 019
1.058+- 0.078
0 . 03 1 +- 0 . 0 1 0
0. 056+ 0. 007
2. :~:9/-.H o 1 TO
*- * ._'' \_' , X / i_i
2. 223+- 0. 164
O. 1 5ftH -f-} <")1 7
- " J- W _* i/ a */ J_ /
1 74-T'j r-) < -,.-,
1 . /*t*.1 IJ. l^o
0.0 04+- 0.0 Of:
0.0 00+- 0.035
0.000+- 0.00-5
0.0 16+- 0.006
0.000+- 0.005
0.025+- 0.007
0.0 10+- 0.009
0. 173+- 0.036
0.065+- 0.024
0.042+- 0.021
0.034+- 0.032
0.000+- 0.038
0.000+- 0.045
0. 155+- 0.058
0. 359+- 0. 1 10
0 . 203-( 0 . 255
0.6 10+- 0.403
0.0 12+- 0.009
2.550+- 0. 188
187
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 5A
PARTICLE SIZE: C
ANALYSIS ID: AC024 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 92+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
!;i
CL
K
CA
TI
V
CR
MN
FE
NI
CL!
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
1.
0.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5/.,4+_
013+-
307+-
5 16+-
00 OH
045 +-
1 9 1 +-
037+-
205+-
017+-
003n
443+-
296+-
020 H
2 16+-
OOOn
OOOn
OOOn
00 IH
002n
016+-
00 OH
02 OH
016n
014+-
016+-
025+-
OOOn
011+-
011+-
00 OH
0 1 1 +-
00 OH
333+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
047
074
119
213
053
003
03 1
006
0 1 3
004
002
040
03 1
004
025
002
0 1 0
002
002
002
003
003
Oil
003
006
009
013
014
017
035
OS 1
126
002
039
' »
6.
1.
9.
0.
0.
7.
0.
1.
0.
0.
2.
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2 .
621+-
538+-
969+-
731+-
00 OH
236+-
643+-
559+-
319+-
110+-
054+-
845+-
900n
130+-
386n
002+
OOOn
000+-
005+
0 1 1 +-
103+-
00 OH
1 26+-
lOSn
091+-
104+-
153+-
000+-
073+-
069+-
000+-
070+-
002+-
460+-
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
"0.
0.
0.
0.
'0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
300
473
766
399
340
043
cr " -~i
041
114
023
012
253
199
027
160
0 1 5
065
0 1 0
Oil
Oil
0 1 6
0 1 8
063
CISC)
041
053
083
037
112
-I -! /
er --i -»
307
0 1 6
249
i
7.
.i
10.
0.
0.
.-t
0.
1.
0.
0.
o
jL> m
0.
1.
0.
0.
("1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^1
931+-
0984
13S + -
565+-
00 OH
311+-
298n
607+-
432+-
119+-
059+-
03S + -
063+-
141+-
50 4 H
003 +-
OOOn
OO <"n
OO5-i
011+-
111+-
OOOn
137H--
1 1 1+-
093n
113+-
171+-
000+
079+-
075+-
00 OH
076+-
002+
671+-
0.537
0.926
0.363
1 . 903
0.369
0 . 062
1 . 065
0 . 080
0. 199
0 . 023
0 .014
0 . 437
0.311
(5 . 033
0 . 238
0 .017
0 . 070
0 . < J 1 1
0 . 0 1 2
0.012
0. 022
0 . 0 1 '?
0 .075
0 . 055
0.046
0 . 064
0. 092
0.094
0. 122
0.245
0 . 566
0.376
0 .017
0.396
188
-------
ANALYSIS ID: AF160 - Tefl OH
- EDDYSTONE/OIL-FIRED POWER-PLANT - TEST NO. 5A
P
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1339+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
K I V
Nl
CU
7 K 1
ZN
GA
AS
i pP~
SE
fi r**r
BR
RB
, . p..
bR
\/
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PE
1.713+-
3. 000 -<
-; --.-f 1 .
J- . -' / i T
19. 672+-
0 . 000+-
0.243+-
3.351+-
0.0 13+-
1 . 054+-
0.047+-
0 . 050+-
2.530+-
2 . 353+-
0. 169+-
2. 063+-
0.0 12+-
0. 014+-
0. OOS+-
0.012+-
0.004+-
0.025+-
0. 000-f
0.033+-
0. 164+-
0.009+-
0 . 009+-
0 . 000+-
0.017+-
0.042+-
0.236+-
0.357+-
0.2S1+-
0.003+-
2.S47+-
0.033
0. 141
0.430
0.924
0.230
0.016
0. 160
0 . 022
0.052
0 . OOS
0.003
0 . 1 1 S
0. 109
0.011
0.095
0 . 005
0.021
0.004
0.004
0 . 002
0.003
0 . 005
0.011
0.011
0 . 006
0 . 009
0.011
0.013
0.016
0.039
0.079
0.11 3
0.003
0 . 1 32
10.997+-
19.259+-
15.221+-
1 26. 297+-
0. OOOH
1.591+-
21.514+-
0. OS6+-
6.770+-
0.300+-
0.321+-
16.242+-
15. 105+-
1 . OS6+-
13.243+-
0. 079+-
0. 090-1
0.054+-
0. 076 +-
0 . 023+-
0. 161+-
0. 00 OH
0.210+-
1.051+-
0.059+-
0.05S+-
0.000+-
0 . 1 03+-
0.272+-
1 . 334+-
2.290+-
1 . 306+-
0.020+-
13.279+-
0.547
0 . 906
2.761
5.933
1.477
0. 103
1 . 023
0 . 1 33
0.332
0.052
0.022
0.760
0.699
0.070
0.611
0 . 034
0. 133
0.023
0.023
0.012
0.017
0.029
0.070
0.072
0.036
0 . 053
0.071
0.037
0. 104
0.247
0.510
0.756
0.022
0.346
0.7 92+- 0.040
1 . 337+- 0.066
1 . 096+- 0. 199
9.093+- 0.432
0 . 000+- 0 . 1 06
0. 1 15+- 0. 007
1.549+- 0.075
0.006+- 0.010
0.437+- 0.024
0.022+- 0.004
0.023+- 0.002
1. 169+- 0.055
1 O.':::rn o OS1
A *.."..* ' '~ V.' m >_'' J.
0.073+- 0.005
0.9 54+- 0.045
0. 006 H 0. 002
0.006H 0.010
0.004+- 0.002
0.003+ 0.007.'
0.002+- 0.001
0 .012+- 0 . 00 1
0.0 00+- 0.002
0.0 15+- 0.005
0.076+- 0.005
0.004+- 0.003
0.004+- 0.004
0.000+- 0.005
0.003+- 0.006
0.020-1 0.007
0 . 1 32+- 0 . 0 1 3
0. 165+- 0.037
0. 130-1 0. 054
0.001+- 0.002
1.316-1 0.062
189
-------
^PLE ID: QiL-EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 5B
PARTICLE SIZE: C
ANALYSIS ID: CC093 - Nuclepore
DARK PARTICLE NEAR CENTER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 110+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
'
PL
' L_
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RE
SR
Y
ZR
MO
FD
AG
CD
IN
SN
SE
EA
LA
HG
PB
0.
1.
0.
. 1
{")
*-'
0 =
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
0 .
0 .
0 .
0.
u
0.
o
0.
0.
0.
O
0.
0.
0.
0.
0.
733+-
243+-
392+-
157+-
000~i
044+-
572+-
103+-
252+-
019+-
015+-
516+-
351+-
023+-
230 H
00 OH
OOO-i
OOOn
00 OH
000+
021+-
000+-
(")O("n
035+-
OOO+
OOC'H
000 H
001+-
<"><"> OH
000+
000 +
000+
OOO-i
449+-
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
059
088
137
251
062
003
100
007
020
004
002
044
034
004
023
003
0 1 1
002
003
003
003
004
014
012
008
012
0 1 3
019
025
047
116
173
003
043
4.
!~!
T'
*_
13.
0.
0.
10.
0.
1.
0.
0.
«,' D
n
*~ e
0.
1.
0.
0.
0.
(")
("1
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
v t
736+-
009 H
513+-
351+-
OOO-i
234+-
090+-
664+-
620+-
119+-
096-i
315+-
251+-.
150+-
799+-
00 3 H
OOO-i
00 1 +-
OO OH
OOO+-
OOO-i
OOO-i
227+-
OOO-i
000+-
000 H
OQ5+_
000-(
OOO-i
000 +
OOO-i
OOO-i
834+-
0.
0.
0 .
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
1.
0.
0.
330
562
379
6 1 0
395
052
640
047
1 3 1
027
014
jU."C''-1
221
023
131
017
071
0 1 3
0 1 7
0 1 6
022
024
092
074
053
080
113
123
159
305
744
141
020
276
4.
r
/ m
"~J
*!.
12.
("i
0.
9.
0.
1.
0.
0.
*'
jL.
0.
1.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
313+-
303-1
296+-
630+-
<"><") ("H
259+-
200-i
605+-
477+-
109-1
037+-
023-i
053'+-
136+-
640+-
002-1
OOfH
001+--
OOOn
OOO-i
121+-
00 OH
OOO-i
207+-
000 H
00 OH
OOO-i
004+-
OOOn
000 H
OOO-i
000+-
000 H
630-1
0.525
0 . 840
0 .829
1 . 366
O. 3. '-,!")
0=053
1 . 022
0. 070
0 . 1 80
0. 027
0. 015
0.373
0.275
0 . 028
0. 223
0 . 0 1 6
0 . 065
0 . 0 1 2
0 . 0 1 5
0 .015
0.023
0 .022
0 . 084
0. 070
0. 048
0.073
0 . 1 03
0. 112
0. 145
0.273
0 . 673
1 . 040
0 . 0 1 8
0 . 343
190
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 5B
PARTICLE SIZE: F
ANALYSIS ID: AF161 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1473+- 10 MI CROC-RAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
O
CL
K
CA
TI
V
CR
M!M
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
I
_'
2,
20.
0.
0.
3.
0.
1.
0.
0.
-i
2.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
634+-
049+-
43 1 +-
1 43+-
000+-
256+-
237+-
077+-
1 23+-
06£n
043+-
573+-
462+-
153+-
114+-
009+-
000+-
002+-
013+-
000+-
027+-
000+-
014+-
1 63n
013+-
000+-
009+-
000+-
049+-
190+-
357+-
215+-
000+-
934+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
OS2
143
441
946
2 '"!<'
016
154
009
053
OOS
003
121
114
0 1 0
093
005
021
004
004
002
003
005
Oil
Oil
006
009
012
014
017
036
033
122
004
133
10.
19.
15.
129.
0.
1.
20.
0.
7.
0.
0.
16.
15.
0.
13.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
. ,
*1 .
1.
0.
19-
490H
576+-
606+-
318+-
OOOn
64 1 +-
779+-
492+-
212+-
435+-
273+-
551+-
303+-
9£;2H
573+-
053n
OOOn
010+-
033+-
000+-
175+-
000+-
033+-
047+_
114+-
00 OH
057+-
000+-
317+-
219+-
290+-
33 1 +-
000+-
15S+-
0.
0.
2.
6.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
525
921
331
075
512
105
936
06 1
:-;4:~;
054
020
775
731
0,67
626
035
137
029
024
012
013
030
072
07:3
041
057
073
OS 7
1 1 0
-V-n-i
«ta.,*U'_'
532
782
025
C;C;7
o
1
1
s
0
0
1
o
0
0
0
1
1
0
0
0
0
o
o
0
0
0
o
o
o
0
0
0
0
0
0
0
0
1
.712+-
. 329+-
. 059+-
. 777+-
. 000+-
. 111+-
.410+-
. 033+-
. 439+-
. 03 OH
.019+-
. 123+-
. 073+-
. 067+-
.921+-
. 004+-
. 000+-
. 00 1 +-
. 006+-
. 000+-
.012+-
. OOOn
.006+-
.071+-
. OOS+-
. 000+-
. 004+-
. 000+-
.021+-
. 033+-
. 155+-
. 094+-
. 000+-
. 300+-
O . O:~;/-.
0.063
0. 192
0.417
0. 103
0.007
0 . 068
0.004
0.024
0.004
0 . 00 1
0.053
0 . 050
O._005
0.043
0.002
0 . 009
0.002
0.002
0 . 00 1
0.001
0. 002
0 . 005
O. OOFi
0.003
0.004
0.005
0.006
0.007
0.015
0.036
0 . 05:3
0 . 002
0.061
191
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: C
ANALYSIS ID: AC025 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 24+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
'^i
CL
K
CA
TI
V
CR
MN
FE .
NI
CU
ZN
GA
AS
SE
ER
RE
SR
Y
ZR
no
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
239+-
449+-
122+-
354+-
OOOn
026+-
464+-
039H
077 +-
010+-
002+-
171+-
114+-
006 +
095 +-
003 H
003 +-
00 H
OOOn
00 2n
00 3H
004-1
001+-
000-t
013+-
0 1 0+-
OOO-i
002+-
013+-
000+-
208+-
160+-
004 +
091+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 ,
030
042
077
130
031
006
042
004
Oil
003
002
027
025
003
021
002
007
00 1
002
002
"002
003
Oil
003
007
009
013
014
019
035
037
136
003
021
1.
.hi
0.
2 m
0.
0.
-ii 0
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
0.
532+-
883+-
735+-
271+-
OOO-i
1 67+-
981+-
24?+-
492-1
063+-
016+-
097+-
735+-
037+-
6 11+-
02 1 +-
016+-
004-1
000+ -
0 1 3+-
022+-
025+-
00 7 H
00 OH
082+-
067+-
OOO-i
015+-
035-1
OOO-i
335+-
026+-
027+-
533+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o,.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
191
267
496
336
200
039
267
023
071
0 1 8
0 1 0
171
162
020
1 33
012
046
008
0 1 0
0 1 1
015
017
069
049
043
059
032
093
1 19
224
557
S72
017
136
6.
12.
_'
9.
0.
0.
12.
1.
2
0.
0.
4.
o
0.
v m
0.
0.
0.
0.
0.
"b.
0.
0.
0.
0.
0.
0.
0.
o
0.
5.
4.
0.
!h-
385+-
014+-
272+-
464+-
000+
697+-
420+-
033+-
048 +
260-1
067 +-
57 0+ -
061+-
153+-
543+-
036+-
068 +-
0 1 5H
000-)
053+-
09 2 H
103+-
027+-
00 OH
342+-
279+-
000+-
064+-
OCT-T.^
00 OH
563+-
276+-
112+-
428+-
2.777
5. 123
2 . 474
5.261
0 . 832
0. 332
5.294
0. 443
0 . 903
0. 131
0 . 052
2 . 0:3:3
_1.442
0. 106
1 . 1 97
0. 063
0. 195
(-) ()': cr
0 .044
0. 051
0. 073
0. 084
0 . 239
0.205
0.229
0.272
0.340
0. 337
0.51 9
0.933
3 . 279
4.046
0 . 036
1. 15?
192
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS ID: AF162 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
700+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i-.
CL
K
CA
TI
V
CR
MN
FE
Nl
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
4w
ite
14.
0.
0.
^
0.
0.
0.
0.
2.
"*'
0.
!ii .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
395+-
344+-
027+-
408 +-
OOOn
200+-
636+-
072+-
960+-
055+-
052+-
337+-
673+-
125+-
217+-
018H
GOSH
004+-
020+-
OOO-i
026+-
OOOn
032+-
109+-
015+-
009+-
027+-
004+-
086+-
329+-
352+-
133+-
00 1 +-
149+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
072
111
36S
681
169
014
128
02 1
045
007
003
112
124
0 1 0
102
005
0 1 3
003
003
002
003
004
0 1 0
009
006
009
012
013
017
040
077
111
003
100
8.
15.
13.
92.
0.
1.
16.
0.
6.
0.
0.
15.
17.
0.
14.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
->
j^ m
jl_
0.
0.
13.
957+-
050+-
016+-
50 1 +-
000+-
234+-
92 OH
464+-
1 66+-
354+-
333+-
322+-
190+-
302+-
232+-
116+-
049+-
025+-
126+-
00 OH
1 64+-
000+-
207+-
703+-
093+-
055+-
173+-
023+-
550+-
109+-
257+-
837+-
009 H
799+-
0.
0.
*! *
4.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
459
715
361
371
0:34
092
O " ^
133
292
047
021
713
794
063
656
031
113
022
020
Oil
017
025
065
053
037
056
076
03 1
110
-!=;/.
495
710
0 1 9
643
1.
2 .
1.
13.
0.
0.
^i
0.
0.
0.
0.
J^ .
J^' a
0.
->
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
230+-
150+-
859+-
214+-
000 +-
183+-
417+-
066+-
8S1+-
05 1 +-
043n
189+-
456+-
115+-
033+-
017+-
007+-
004+-
013+-
000+-
023+-
000+-
03 OH
1 00+-
014+-
008+-
025+-
003H
079+-
30 1 +-
322+-
127+-
00 1 +-
971+-
0.063
0. 107
0.333
0 .652
0 . 1 55
0.013
0. 123
0 . 0 1 9
0 . 044
0.007
0 . 003
0 .107
0.11 9
0. 009
0 . 093
0. 004
0 . 0 1 6
0. 003
0. 003
0. 002
0.002
0. 004
0. 009
0 . 008
0. 005
0.003
0.011
0.01 2
0.016
0.037
0 . 07 1
0. 102
0 . 003
0. 096
193
-------
SAMPLE ID: OIL-EDDYSTONE/OIL-FIRED POWER PLANT
PARTICLE SIZE: C
ANALYSIS ID: CC094 - Nuclepore
EXPOSED AREA:
MASS:
6.. 42 SQUARE CM
26+- 10 MICROGRAM:;
TEST NO. 6B
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i~-
CL
K
CA
TI
V
CR
MN
FE
NI
CL1
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0 =
0.
( .
(. .
I .
( .
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
n.
0.
().
331+-
654+-
099-1
305+-
006+-
016+-
667+-
060-1
106+-
002-i
008-i
192+-
121+-
003+
09 6+-
00 1 +-
OOOn
000+-
000+-
002+-
016+-
OOO-i
OOO-i
017 + -
OOO-i
OOOH
000+-
015+-
000+-
000 H
OOO-i
OOO-i
004+-
1 0 1 +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
041
056
074
131
032
006
051
005
012
00^3
002
023
026
003
021
002
00:3
002
002
003
003
003
014
Oil
008
012
013
019
025
045
113
175
00:3
022
2.
4.
0.
1.
0.
0.
4.
0 c
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
()
, 0.
0.
0.
0.
0.
0.
0.
0.
0.
125+-
199-t
636+-
960+
042+-
103+-
f* " j_
*1 0 - "*"
388+-
633+-
015+-
054+-
234+-
773+-
050 +
6 13+-
006-1
OOO-i
OOO-i
000 +
0 10+-
102+-
000+-
OOO-i
OOOn
00 0+
00 OH
097+-
OOO-i
000+-
000+-
000+-
023 + -
651+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0 .
261
361
476
341
207
039
325
035
080
0 1 9
012
131
1 63
021
133
0 1 3
050
0 1 0
015
0 1 6
020
022
089
070
049
030
114
123
159
292
726
121
020
144
]3j
15.
.i
7 .
0.
0.
16.
1.
2 .
0.
0.
4.
*J
0.
.i
0.
0.
0.
0 .
0.
0.
o
o
0.
0 .
0.
0.
0.
0.
0.
0.
0 =
0.
2 a
035+-
379+-
406+-
413+-
157+-
389+-
193+-
467+-
532H
058+-
205+
666-1
941+-
190+-
336+-
022+-
000+-
OOfH
000+-
038+-
386+-
OOO + -
OOt'H
419+-
OOO-i
000 +-
OOO-i
367+-
000+-
OOO-i
OOO-i
000+-
039+-
464+-
3. 194
6. 158
2 . 0 1 6
4.240
0 786
0.21 0
6.247
0 . 570
1 . 022
0. 076
0. 090
1 . 392
1 . 230
0 . 1 03
1 . 026
0 . 049
0. 138
C) . O :"::":
0. 057
0. 063
0. 165
0 . 085
0 . 338
0 . 309
0. 187
0 . 302
0.431
0.486
0.601
1. 104
2.745
4.241
0.034
1 . 079
194
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT
PARTICLE SIZE: F
ANALYSIS ID: AF163 - Teflon
- TEST NO. 6B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
736+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
O
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PE
1.
2.
i. .
14.
0.
0.
1^! n
0.
0.
0.
0.
V m
*(
0.
">
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-'
433+-
415+-
037+-
784+-
OOOH
228+-
523+-
043+-
963+-
051+-
054+-
458+-
769+-
132+-
331+-
010+-
019+-
005H
021+-
000+-
020n
000 H
024+-
111+-
009+-
013+-
011+-
000+-
069+-
236+-
391+-
180+-
004+-
224+-
0 . 073
0. 1-15
0 . 370
0.698
0. 173
0.015
0. 123
0 . 02 1
0.046
0.007
0 . 003
0. 115
0. 123
0.010
0. 107
0.005
0.018
0 . 003
0. 003
0 . 002
0.002
0 . 004
0.010
0.009
0 . 006
0 . 009
0.012
0 . 0 1 3
0.017
0.033
0 . 030
0. 115
0.003
0. 103
9.
15.
13.
94.
0.
1.
16.
0.
6.
0.
0.
15.
17-
0.
14.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
-I
1.
0.
14.
197+-
501+-
073+-
915+-
000+-
462+-
200+-
307+-
2 1 5+-
323+-
344+-
781+-
774+-
847+-
Q,i2H
066+-
119+-
033+-
135+-
000+-
126+-
000+-
153+-
712+-
060 *
033+-
069+-
000+-
444+-
S34+-
510+-
156+-
023+-
279+-
0.
0.
T"
4.
1.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
471
735
373
432
111
093
737
1 36
~>-.in
.ho .' T1
047
022
739
321
065
639
031
115
022
021
Oil
0 1 6
025
066
060
036
059
074
032
1 09
247
515
739
021
664
1.
~t
jL.
1.
12.
0.
0.
j_! .
0.
0.
0.
0.
o
T-*
0.
7*
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
250+-
107+-
778+-
904+-
000+-
199+-
202+-
042+-
345+-
045+-
047+-
145+-
416+-
115+-
034+-
009+-
016+-
005+-
018+-
000-<
017+-
00 OH
021+-
097+-
003n
011+-
009 +-
OOOH
060+-
249+-
341+-
157+-
004+-
941+-
Q
Ci
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
0
o
o
0
0
o
0
o
0
o
0
. 066
. 104
C'jL-O
. 634
. 151
. 0 1 4-
.111
.019
.042
. 006
. 003
. 105
.-1-lfc
. 00'?'
. 093
. 004
. 0 1 6
. 003
. 003
.001
. 002
. 003
. 009
. 008
. 005
. 008
. 0 1 0
.011
. 0 1 5
. 034
. 070
. 1 00
. 003
. 094
195
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC026 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMEN"
UG/CM2
UO/FILTER
AL
SI
P
C'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
EA
LA
HG
FB
0. 000+-
0.005+-
0.000+-
0. 000 +-
0. OOOH
0 . 000+
0 . 000+
0.002+-
0.001+-
0. 000 +-
0. OOOn
0. 001+-
0. 001+-
0. 001+-
0 . OOOn
0 . 001 H
0.002+-
0. OOOn
0. OOOH
0 . OOOn
0. 000+-
0 . 004+-
0 . 03 1 H
O. OOOH
0. 002 +-
0. 012+-
0. 002+-
0. 00 9 H
0 . 000+-
0 . OOOn
0. 093+-
0. 136+-
0. 002+-
0 . 000+-
0.011
0 . 003
0. 004
0 . 0 1 3
0. 006
0.002
0. 002
0. 001
0. 001
0 . 00 1
0. 001
0 . 00:2:
0.001
0 . 00 1
O O O 1
^-' . >_' »_' J.
0. 001
0. 003
0 . OO 1
0.001
0. 001
0.002
0.002
0.01 0
n.007
o. 005
O.003
0.012
0.013
0.016
0 . 032
0.076
0. 124
0. 002
0.004
0. OOO+-
0.035+-
0. 000+-
0. OOOn
0 . OOOn
00 000+-
0 . OOO+-
0 .Oil +-
0. 007 H
O. OOO+-
0. 000+-
0. 00 SH
0.005+-
0. 007+-
t_) . OUOH
0. 004n
0 . 0 1 3+-
O . O(")'")H
0 . 00 1 H
O. OOO+-
0. 00 OH
0. 023 +-
0. 197+-
0. 000+-
0. 013+-
0.07S+-
0.011+-
0.061+-
0. 000+-
0. 000+-
0.595+-
1. 193+-
0. 01 1+-
0 . 000+-
0. 073
0. 049
0.023
0.11 6
Ur\ '" '-
^.- _' -'
0 .015
0.011
0. 007
0 . 005
0. 006
0. 007
0 . 0 1 9
0.007
0. 009
0. 005
0. 004
0 . 0 1 6
O OO/-
'-' . *.' *-* '_'
0. 009
0. 009
0.013
0 .015
0. 065
0. 043
0. 035
0.054
0.074
0. OS6
0. 103
0.204
0. 436
0 . 796
0 . 0 1 3
0.026
196
-------
SAMPLE ID: OIL - EDDYSTONE/OIL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: F
ANALYSIS ID: AF164 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
s
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
A3
SE
BR
RE
SR
Y
ZR
MG
PD
AG
CD
IN
SN
SB
BA
LA
HO
PB
0 . OOO-i
0.013+-
0.001+-
0.0 17+-
0. 001+-
0.000+-
0.000+-
0. 000+
0 . 000+-
0.000+-
0 . OOO-i
0.008+-
0 . 000+-
0.003+-
0.000+-
0. 002-i
0.000+-
0 . 00 1 +-
0 . 000+-
0. 000+-
0.000+-
0.000+-
0.000+-
0. 000+
0 .011 +-
0.009+-
0.006+-
0 . 0 1 0+-
0.020+-
0.007+-
0. 126+-
0 . OOOH
0.003+-
0 . 003+-
0.007
0.005
0 . 002
0.011
0.004
0.002
0 . 00 1
0.001
0.001
0 . 00 1
0.001
0.003
0 . 00 1
0. 001
0 . 00 1
o . oo i
0 . 002
0 . 00 1
0.001
0.001
0. 001
0.002
0 . OOS
0.005
0.005
0 . OOS
0.010
0.011
0.013
0.022
0 . 062
0. 104
0.002
0 . 003
0. 000+-
O.OS7+-
0.006+-
0. 109+-
0.005+-
0.000+-
0 . 000+-
0. 000 +-
0 . 000+-
0.000+-
0. OOO-i
0.051+-
0 . 00 1 +-
0. 019+-
0.003+-
0 .011 -i
0.000+-
0.006+-
0. 000+-
0. 000+-
0 . 000+ -
0.000+-
0.000+-
0.000+-
0. 070+-
0.055+-
0.042+-
0.066+-
0. 129+-
0 . 043+-
O.S06+-
0.000+-
0.022+-
0.016+-
0.047
0.033
0.015
0.063
0.023
0 .011
0.007
0 . 005
0.004
0.005
0 . 006
0 . 0 1 6
0. 005
n. rx') '/-.
0.004
0. 005
0 . 0 1 3
0.004
0.006
0 . OOS
0 . 0 1 0
0 .011
0. 053
0. 032
0.032
0 . 04S
0 . 06 1
0.071
O.OS3
0 . 1 42
0.396
0.670
0 . 0 1 2
0.021
197
-------
SAMPLE ID: OIL- EDDYSTONE/OIL-FIRED POWER PLANT - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: CC095 - Nuclepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
p
CL
K
CA
TI
V
CR
MM
FE
NI
CD
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0. 003+-
0. 013+-
0. 00 0+
0 . 027n
0. OOO-i
0. OOO-i
0 . OOO-i
0. 004-1
0. 000+
0. OOO-i
0. 000+-
0 . 002-t
0. OOO-i
0 . 000+-
0 000+-
0 . OOO-i
0. OOO-i
0. 000+-
0 . OOO-i
0. 000+-
0. 001 H
0 . 005-t
0 . 000+-
0. 003 +
0. 012+-
("). OOfH
0.0 16+-
0 . 009+
0. 000+-
0.0 17+-
0. 058 +-
0. 114+-
0. 001+-
0.01 1+-
0. 025
0 . 0 1 9
0 . 0 1 0
0 . 022
0 . 009
0.003
0 . 002
0 . 00 1
0 . 00 1
0 . 002
0 . 00 1
0 . 004
0.001
0 . 002
0 . 00 1
0.001
0. 004
0.001
0. 002
0 . 002
0 . 003
0. 003
0.014
0 . 0 1 0
0.003
0.01 3
0.017
0 . 020
0.024
0.043
0 . 1 09
0. 171
0.003
0 . 006
o.Ol 7+-
o. 113+-
("). O!~M~H
0. 177+-
0 . 000+-
0 . 000+-
0. 000+
0. 027 +-
0. 000+
0. OOO-i
0. OOO-i
0. 016-i
0 . 000+
0. OOO-i
0. OOO-i
("). OO("H
0 . OOO-i
0. OOO-i
0. OOO-i
0. OOO-i
0. 005+-
0.032+-
0. OOO-i
0 . 02 1 +-
0.079+-
O f'O (")-(
0. 104+-
0 . 055+-
0 . 000+-
0. 107+-
0.370+-
0 . 730+-
0 . 004-1
0. 070+-
0. 160
0. 122
0 . 06 1
0. 143
0 . 057
0=013
0 . 0 1 3
0 . 009
0.006
0.011
0. 009
0.023
0. 00 S
' 0 . 0 1 1
0. 006
0. 006
0 . 024
0. 009
0 . 0 1 4
0 . 0 1 5
0 . 0 1 9
0.021
0.03 3
0.066
0 . 050
0 . 082
0 . 11 0
0. 127
0. 153
0 . 279
0.699
1. 100
0.017
0 . 040
198
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 1A
PARTICLE SIZE: C
ANALYSIS ID: AC027 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
353+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL.
SI
P
'
CL
K
CA
TI
V
CR
MM
FE
Nl
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
13.
2 P..
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
339+-
621+-
00 OH
5 10+-
OOO-i
057+-
120+-
157+-
000+-
000 +
OOO-i
331+-
029+-
012+-
005-(
003+-
OOO-i
OOt'n
OOO-i
006+-
006+-
016+-
014+-
012+-
010+-
029+-
000+-
01 OH
OO2H
000+-
031+-
291+-
00 1 -i
0 10+-
0.
^ f
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
965
125
1 60
371
091
009
Oil
164
066
031
Oil
036
005
002
002
001
004
001
002
002
003
003
013
009
007
Oil
015
017
021
041
096
167
003
006
C'C"
183.
0.
9.
0.
0.
0.
1.
0.
0.
0.
jL.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
638+-
744+-
000+-
696+-
000+-
365+-
773+-
006+-
000+-
00 0+
000+-
126+-
187+-
079+-
032-1
021+-
000-i
002-1
000+-
039n
0^ 0+-
1 0 1 +-
OS9+-
075+-
064+-
1S7+-
000+-
067+-
014+-
000+-
197+-
370+-
009-1
067+-
6.
13.
1.
2.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
n
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
194
641
02S
379
532
053
069
054
422
196
070
232
032
0 1 6
012
003
024
OOft
01 1
0 1 3
013
022
081
057
047
073
095
110
135
261
614
074
017
033
^,.-,
51.
0.
*!.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
o
0.
0.
0,,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
929+-
341+-
000+-
709+-
OOO+-
102+-
216+-
23 1 +~
000 H
OOO-i
000+-
594-t
052+-
022+-
009-1
006-1
OOO-i
001+-
OOO+-
011+-
011+-
023-i
025+-
021+-
013+-
052+-
OOO-i
019+-
00 4+ -
OOO-i
055+-
523+-
OO:":H
019+-
1 . 355
4.073
0 . 237
0 . 669
0. 163
0 . 0 1 6
0. 020
0 . 295
0.11 3
0. 055
0 . 020
0 . 067
0. 009
0. 004
0 . 003
0 . 002
0.007
0. 002
0 . 003
0 . 004
0 . 005
0 . 006
0.023
0 . 0 1 6
0 . 0 1 3
0.020
0.027
0.031
0 . 033
0 . 073
0. 172
0 . 30 1
0. 005
0 . 0 1 1
199
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO.
PARTICLE SIZE: F
ANALYSIS ID: AF163 - Teflon
1A
EXPOSED AREA:
6.42 SQUARE CM
642 1-t 10 MICROGRAM
ELEMENT
UG/CM2
UG/FILTER-
PERCENT
AL
SI
F'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
IN
GA
AS
SE
BR
RE
SR
Y
ZR
no
PD
AG
CD
IN
SN
SB
BA
LA
HG
PI;
50.
119.
("i
41.
0.
0.
0.
1.
0.
0.
0.
*^ 0
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
2.
0.
0.
549+-
030+ -
OOO+-
949*-
000+-
443+-
403+-
333+-
00 OH
000 H
000 +
703+-
293+-
029+-
071+-
020+
00 OH
021+-
OO7-I
00 8 -t
043+-
109H
000+-
00 IH
003+-
OOO-t-
00 OH
026+-
OOOn
001+-
000 +-
330+-
00 7 H
107+-
j^.
5.
0.
1.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
303
416
704
944
483
024
021
604
241
1 11
040
127
013
003
00=;
002
003
002
0 0 2
002
004
007
015
0 1 0
009
013
0 1 S
020
023
044
110
247
004
009
324.
764.
0 .
269.
0.
v m
^3 «J
'-,'
0.
0.
0.
17.
1 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
("I
0.
0.
0.
0.
0.
0.
0.
0.
1 3 .
0.
0.
522+-
4*1+-
000 H
3 1 3+-
000+-
846+-
601+-
560+-
00 OH
00 OH
OOOH
337+-
910+-
134+-
454+-
130 + -
000 -<
132+-
046+-
032+-
310+-
698+-
OOO+
006+-
020 +-
000+-
000+-
163+-
002+-
009H
OOOn
1 63+-
043+-
633+-
14.
34.
4.
12.
U' »
0.
0.
^1
I.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
736
771
522
4SO
101
153
I 35
376
550
71 1
258
3 1 3
099
021
030
015
033
014
0 1 4
0 1 6"
026
042
095
067
053
035
115
127
147
231
706
^ c< c*
024
039
er
'
11.
0.
4.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
(").
0.
()
0.
0.
0.
0.
0.
(")
" '
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
054+-
906+-
00 0+
194+-
OOO+-
044+-
04 1+-
133 + -
OOOn
O (")(") H~ -
000+--
271+-
03 0+
00 3 H1
OO7-i
002+ -
OOO+
002+-
00 1 H
00 1 H
005+ -
0 11+-
OOOH
*»' «' *,' '
OOOn
000+-
OOO-i
00 OH
003+-
OOO-i
OOO-i
00 OH
233+-
001+-
0 1 1 +-
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("l
»_'
0.
0.
0.
0.
0.
0 .
0 .
("t
^_- .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
230
542
07O
194
043
002
002
060
024
01 1
OO-1
0 1 3
002
000
'.">< iO
000
00.1
000
000
000
000
00 1
(")(") l[
001
001
00 1
002
002
002
004
0 1 1
025
000
00 1
200
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 2A
PARTICLE SIZE: C
ANALYSIS ID: AC028 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
309+- 10 MICRQGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
. -
CL
K
CA
TI
V
CR
MN
FE
NI
CU
IN
GA
AS
SE
BR
RE
SF;
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
11.
24.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
292+-
33 1 +-
000+-
07 6+-
OOOH
056+-
074+-
1 39+-
000+-
00 OH
OOOn
273+-
023+-
002 H
006+-
003 H
OOOH
003n
00 1 +-
00 1 +-
003+-
017+-
012+-
000+-
001+-
021+-
009+-
OOS+-
00 OH
OOOH
143+-
3 1 0+-
003+-
011+-
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
S45
S75
151
359
OSS
OOS
003
132
OSS
026
009
03 1
005
002
002
001
003
00 1
002
002
003
003
012
OOS
007
Oil
015
017
020
038
094
161
003
006
72.
156.
0.
6.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
493+-
205+-
000+-
911+-
000+-
361+-
473+-
892+-
000+-
000+-
000+-
750+-
1 S2+-
014+-
036n
016+-
000+-
021+-
OOS+-
OOS+-
020+-
10S+-
079+-
000+-
004+-
137+-
059+-
053+-
000+-
000+-
95 1 +-
991+-
0 1 9+-
070+-
5.
12.
0.
*i~
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
427
033
973
307
564
054
052
S49
375
170
056
199
030
013
Oil
007
022
009
Oil
012
017
021
07S
054
043
069
093
106
129
247
604
03 1
017
036
.£.'-<
50.
0
-'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
469+-
570+-
O(')(")+-
237+-
000+-
117+-
155+-
239+-
000+-
000 H
OOOH
567+-
059+-
005+-
0 1 2+-
005+-
000+-
007+-
003+-
00 3n
006+-
035+-
026 +-
OOOn
001+-
045+-
019+-
017+-
OOOn
OOOH
303+-
645+-
006+-
023+-
1.914
4.227
0 .315
0 . 750
0. 1S3
0 . 0 1 S
0.01S
0.275
0. 121
0. 055
0 . 0 1 3
0 . 06 7
0 . 0 1 0
0. 004
0 . 003
0. 002
0. 007
0. 003
0 . 004
0 . 004
0..005
0 . 007
0 . 025
0.017
0 .014
0 .022
0.030
0. 034
0.042
0. 030
0. 196
0 . 334
0 . 006
0 .012
201
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS IDs AF166 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE
61 OH 10
CM
MICROGRAM
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
1=:E
BR
RB
SR
Y
ZP
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PE
47.
112.
i j .
42.
0.
0.
0.
1.
0.
0.
0.
J^.
0.
0.
0.
0.
0.
0.
0 .
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
214+-
102+-
000 H
369+-
00 0+
360 +-
342+-
111+-
000+-
000+-
00 OH
343+-
234+-
03 1 +-
043n
013+-
OOOn
019+-
00 SH
009 + -
04 3+-
091+-
000 +
000+-
00 OH
OOO-i
000+-
066+-
009 + -
023+-
000+-
341+-
002n
OS 1 +-
^i
'
o .
1.
0.
< '. C
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
152
099
704
C'O/l,
493
020
0 1 3
503
221
101
030
110
0 1 4
003
004
002
003
002
002
003
004
006
0 1 6
Oil
009
014
0 1 9
022
025
047
1 16
004
009
303.
719.
O
-i^tr
0.
_^ s
";.
7.
0.
0.
0.
15.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
13.
0.
0.
112+-
697+-
OO("H
220+-
000+
308+-
1 97+-
133+-
OOOn
000+-
00 OH
052+-
631+-
19S+-
305+ -
116+-
00 OH
119+-
021+-
05S+-
275+-
5S7+-
OOOn
000+-
000+-
00 OH
000+-
421+-
056+-
1 46+-
OO(")H
031+-
01 OH
51S+-
1 3 .
.-, .-,
4.
12.
"'
0.
0.
.1
c>
i .
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
314
735
er -, -,
752
16S
129
117
230
421
646
194
706
OS7
022
023
014
O :"::";
0 1 4
014
0 1 7^
026
039
100
070
059
092
1 23
141
137
302
744
531
024
055
4.
11.
i")
4.
0.
0.
0.
0.
(")
0.
0.
0.
0.
o
0.
0.
o
0.
(")
0.
O
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
963+-
796+-
OOOn
511+-
00 OH
03:3+-
036+-
117+-
OfH'H
00 OH
OOOn
247+-
027+-
OO:";H
00 SH
002+ -
OOfH
002 +-
OOOH--
00 IH
OO5+-
010+-
O(")OH
00 OH
00 OH
00 OH
000+-
007+-
00 1 +-
002n
00 OH
246+-
OOOn
008 H
0.227
0.537
0 . 074
0. 209
0.032
0. 002
0 . 002
0.053
0 . 023
0.011
0 . 003
0 . 0 1 2
0. 001
(") . OOf)
(j . 000
0. 000
0 . 00 1
0. 000
0. 000
0 - 000
0 . 000
0 . 00 1
0 . 002
0.001
0 . 00 1
0.002
0. 002
0. 002
0.003
0 . 005
0 . 0 1 2
0 . 023
0 . 000
0. 001
202
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 3A
PARTICLE SIZE: C
ANALYSIS ID: AC029- Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
342+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
i--
--.«
CL
l<
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
Hfi
IT1
PB
13.
23.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
*.*
0.
0.
0.
()
>_'
0.
730+-
570+-
000+-
325+-
000 +-
061+-
032+-
153+-
OOOn
000+-
000+-
321+-
033+-
000+-
009+-
00 5-i
000+-
002-1
000+-
004+-
003+-
012+-
000+-
002+-
013+-
009+-
016+-
OOOn
000 H
000+-
000+-
244+-
004-1
009-t
0.972
2. 123
0. 174
0 . 450
0. 110
0.009
0.009
0. 155
0.063
0.029
0.010
0 . 034
0.005
0 . 002
0 . 002
0 . 00 1
0.004
0 . 00 1
0.002
0 . 002
0.003
0 . 003
0.013
0 . 009
0.003
0 .011
0.016
0.017
0 . 02 1
0.041
0.097
0. 171
0 . 003
0 . 006
RS .
1S3.
0.
11.
0.
0.
0.
1.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
o
\»*
0.
1 49+-
417+-
000+-
713+-
000+-
392+-
526+-
013+-
OOO-i
000+-
00 OH
063-t
243+-
OOO-i
056+-
029+-
000+-
012+-
OOO-i
025+-
020-1
076+-
OOO-i
012+-
030+-
06 1 +-
102+-
000+-
OOO-i
OOO-i
000+-
569+-
o-~'c;+-
'.' -*~ ' ' '
059+-
6.
13.
1.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
q.
o'.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0,
0.
237
66:3
119
8S7
703
057
055
996
407
137
064
220
034
012
012
009
024
009
012
013
013
022
033
053
050
070
101
111
135
261
626
098
0 1 9
040
25 .
53 .
0.
«.'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
741+-
561+-
OOO-i
422+-
OOO-i
114+-
154+-
296+-
000-(
OOO-i
OOO-i
602 +-
071+-
OOO-i
016+-
009+-
000 -i
004+-
000+-
007-1
006+-
022+-
OOO-i
003+-
023-<
01S+-
030-i
OOO-i
OOO-i
OOO-i
OOO-i
453+-
007-1
017+-
1
4
0
0
0
o
o
o
0
0
0
o
o
o
o
o
0
o
o
o
0
o
0
0
o
0
0
o
0
o
o
o
o
o
. 970
. 236
";""?
. 349
. 207
.017
.017
.291
. 1 1 9
. 055
.019
^0_67
. 0 i 0
. 004
. 003
. 003
. 007
. 003
. 00:3
. 004
. 005
. 007
. 024
.017
.014
. 020
. 030
. 033
. 039
. 076
. 133
.321
. OOF!
. 0 1 2
203
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 3A
PARTICLE SIZE: F
ANALYSIS ID: AF167 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
73S6+- 10 MICFOGRAM3
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
\~,
CL
K
CA
TI
V
CR
M!M
FE
IMI
CU
ZN
GA
AS
C'd
E~;
RB
'- rv
V
ZR
r-io
F'D
AC
CD
IN
SIM
SB
BA
LA
HG
PE
48.
120.
0.
51.
0.
0.
0.
1.
0.
0 .
0.
v B
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
557+-
034+
00 OH
271+-
000+-
0;;;=;_|
361+-
222n
000+-
OOOn
OOOn
501+-
273+-
017+-
041+-
01 6+ -
OOOH
025+-.
OOS-i
009n
044+-
113+-
006+-
000 +
004+-
000 +
OO(")H
03 3 H
059+-
041+-
00 OH
959+-
002+-
159+-
2.
5.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
213
459
305
"' ~V "
590
021
0 1 9
604
231
101
040
117
014
O'T-:
00:3
002:
006
002
002
003
004
007
0 1 6
Oil
009
015
019
02 1
025
047
116
259
004
Oil
311.
770 .
0.
329.
0.
'"*J
4~ a
**"»
7.
0.
0.
0.
16.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
IS.
0.
1.
737+-
619+-
00 OH
163+-
000+ -
469+-
319+-
847+-
000+-
OOOn
00 OH
055+-
752+-
103+-
262+-
106+-
000+-
159+-
050+-
055+-
O C1 '"' ^, _
724+-
039n
OOOn
029+-
000+-
000+-
214+-
379+-
261+-
00 OH
999 +_
0 1 5+-
021+-
14.
35.
5.
15.
'
0.
d).
'^; .
1.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
On
0.
0.
0.
0.
0.
0.
0.
(I).
0.
0.
0.
0.
1.
0.
0.
205
049
163
23S
739
1 36
122
376
436
646
" C7 C'
752
092
0 1 8
02]
014
037
0 1 6
0 1 5
017
026
044
101
070
061
093
120
135
1 62
302
747
660
024
073
4.
10.
0.
4.
0.
0.
0.
0.
0.
("1
0.
0.
0.
0.
0.
0.
0.
0.
0.
"0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
221+-
434+-
000+-
457+-
OOOH
033 +
031+-
1 06+-
OOOn
no OH
000+
217+-
024+-~
001+-
004 H
001+-
00 OH
00 2 -s
00 H
001+-
004+-
010+-
001+-
000+-
OOOn
000 H
000+-
003 H
005n
004+-
OOfiH
257+-
00 OH
014+-
0. 192
0.475
0. 070
0 . 206
0 . 05 1
0. 002
0 . 002
0 . 052
0 . 020
0. 009
0. 003
0 . 0 1 0
"0. 001
0. 000
0 . 000
0. 000
0 . 00 1
0. 000
0. 000
0 . 000
0. 000
0. 001
0 . 00 1
0. 001
0. 001
0 . 00 1
0. 002
0. 002
0. 002
0. 004
(") . O 1 (")
0. 022
0 . d) (") 0
0. 001
204
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 3B
PARTICLE SIZE: C
ANALYSIS ID: CC096 - Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
220+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
,-
CL
K
CA
TI
V
CR
MN
FE
NI
CLJ
ZN
GA
AS
SE
BR
R-B
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
19.
44.
0.
.-,
**
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
320+-
519+-
000+-
509+-
000+-
112+-
095+-
289+-
000 H
000+-
000+-
553+-
043+-
001+-
007+-
005+-
000+-
001+-
000+-
002H
012+-
033+-
014+-
000+-
013+-
000+-
003+-
016+-
000+-
026+-
061+-
725+-
000-t
024+-
1.
^t
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
260
865
156
557
137
0 1 1
009
203
034
041
0 1 1
044
006
002
002
001
004
002
002
003
004
004
015
012
009
014
0 1 3
022
026
043
119
205
003
007
127.
235.
0.
--<
A.J- m
0.
0.
0.
1.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
245+-
811+-
000+-
526+-
000+-
71S+-
607+-
855+-
000+-
000+-
000+-
534+-
3 1 0+-
005+-
046+-
030+-
OOOn
005+-
OOOn
014+-
075+-
212+-
08S+-
000+-
031+-
000+-
017+-
101+-
000+-
167+-
393n
652+-
000+-
155+-
3.
18.
1.
'
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
092
391
003
573
331
071
059
^i:"::":
537
265
063
--, o e^
037
0 1 3
012
009
029
Oil
015
017
022
029
093
075
055
090
118
140
165
303
766
314
021
047
57.
129
0.
10.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.1
0.
0.
722+-
1 . 65+-
000+-
219+-
000+-
326+-
276+-
341+-
000+-
000+-
000+-
626+-
141+-
002'H
021+-
013+-
000+-
002+-
000+-
006H
034+-
096+-
040+-
000+-
037+-
000+-
003+-
046+-
000+-
076+-
178+-
110+-
000+-
070+-
4 . 509
10.21
0 . 455
1 . 636
0.400
O . O :-:/-.
0 . 029
0. 606
0 . 244
0. 120
0 . 03 1
0. 149
0.018
0. 006
o . no A
0. 004
0 . 0 1 3
0. 005
0 . 007
0.003
0 . 0 1 0
0 .014
0.045
0. 034
0 . 025
0.041
0 . 053
0.063
0.075
0. 140
0.343
0.604
0 . 009
0.022
205
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 38
PARTICLE SIZE: F
ANALYSIS ID: AF163 - Teflon
SHINY FLAKES ON SURFACE
EXPOSED AREA: 6.42 SQUARE CM
MASS: 7636-*-- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ft' i
i_i *
GA
AS
c-cr
' l~
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
46.
113.
0.
56 .
0 .
0.
0.
1 .
0.
0.
0.
v .
0.
0.
0.
0.
0.
0.
0.
0.
!'
<)
0.
0
o
0.
0.
0.
0.
0.
0.
2.
0.
0.
992+-
264+-
000+-
303+ -
000 -i
349+-
335+-
111+-
OOOH
OOO-i
00 OH
317+-
253+-
00 9 H
037+-
016-i
OOOn
023+-
00 6+
003 -f
044 -i
09 2n
000+-
<")O("n
OOOn
000 H
OOO-i
OOO-i
021+-
043+-
00 OH
117+-
00 2 H
0944
.-i
cr
0.
V B
Cj
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
o
0.
Oo
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
142
152
906
605
643
020
018
503
221
09 1
030
1 09
014
003
003
002
006
003
003
OO:T:
004
006
019
0 1 3
Oil
017
023
024
029
056
139
260
004
0 1 0
301.
727.
0.
361.
0
v m
7.
0.
0.
0.
14.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
o
0.
0.
0.
0.
1 3 .
0.
0.
686+-
157+-
00 OH
431+-
00 OH
238+-
151+-
133+-
000 +
000+-
OOO-i
872+-
655+-
055+-
240+-
103+-
00 OH
179+-
040+-
054+-
2SO+-
592+-
000+-
OOOn
00 OH
OOO-i
OOO-i
OOO-i
137+-
306+-
OOO-i
589+-
010+-
603+-
13.
;~; ;t;
5.
16.
4.
0.
0.
= o
1.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
749
074
SI 4
727
161
127
115
230
423
58 1
194
693
088
0 1 8
02 1
014
037
013
017
020
029
042
119
084
072
111
145
156
189
362
889
670
023
064
~i
9.
0.
4.
O
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
o
0.
0.
0.
o
0.
0.
o
0.
0.
o
951+-
523-t
OOOn
734+-
OO("H
029+-
023+
093+-
00 OH
000+-
OOO-i
195 + -
022-1
oo i +-
003+-
001+-
OOOH
002 +-
001 +-
00 IH
004n
0<">8n
000+
OOO+
000+
000 H
000-i
OOO +
002H
004H
OO OH
178+-
OOOn
OOI-:H
0. 180
0 . 433
0 . 076
0.21 9
0. 054
0. 002
0 . 002
0. 04?
0 . 0 1 9
0,. 008
0. 003
0 . 009
0. 001
0 . 0(1)0
0. 000
o. ooo
o ooo
0. 000
o . ooo
o. ooo
o ooo
0 . 00 1
0. 002
0 . 0 0 1
0 . 00 1
0. 001
0 . 002
0. 002
0. 002
0 . 005
0 . 0 1 2
0.022
0 . 000
0 . 00 1
206
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 4A
PARTICLE SIZE: C
ANALYSIS ID: AC031 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
319+- 10 MICROGRAMS
ELEMENT
UO/CM2
UO/FILTER
PERCENT
AL
SI
P
,-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
no
FD
AG
CD
IN
SN
SB
BA
LA
HG
PB
12.
26..
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
594-1
553+-
000+-
845+-
000+-
073+-
114+-
143+-
000+-
00 OH
000+-
316+-
024+-
003+-
007+-
005+-
000+-
003+-
OOO-i
002-1
007+-
0 1 4+-
006+-
017+-
000+-
010+-
000+-
008+-
008+-
OOOH
059+-
458+-
000+-
0 1 2+-
0.
2,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
915
042
1 65
433
119
009
010
141
063
027
009
034
005
002
002
001
003
001
002
002
003
003
012
009
007
0 1 0
014
016
020
035
091
164
002
006
80.
170.
0.
11.
0.
0.
0.
0.
0.
f>
0.
"!'
X-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.->
0.
0.
854+-
504+-
OOO-i
843+-
000+-
463+-
731+-
949+-
000+-
OOO+-
OOO-i
030+-
151+-
022+-
046+-
033+-
000+-
01S+-
000+-
014+-
044 +-
09 1 +-
040H
109+-
000+-
062+-
000+-
053+-
048+-
000+-
377+-
941+-
000+-
076+-
5.
13.
1.
'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
376
111
059
099
761
059
065
908
404
176
059
219-
030
012
Oil
009
022
009
01 1
012
017
021
077
055
042
064
089
104
129
228
535
050
015
036
25.
53.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
355+-
468+-
000+-
715+-
000+-
147+-
229+-
2 '-/f; +
000+-
OOOn
000+-
637+-
047+-
007+ -
014+-
010+-
000+-
006-1
0.0 0+-
004-1
014+-
029-1
013+-
034+-
000+-
0 1 9+-
OOOn
017+-
0 1 5+-
000+-
113+-
922+-
000+
024n
2 . 007
4.440
0 . 332
0.979
0.239
0 .019
0.022
0.285
0 . 1 27
0 . 055
0 n 0 1 8
0 . 07-1
0. 009
0. 004
0 . 003
0.003
0 . 007
O. Of:.:";
o. OO:":
0. 004
0.005
0. 007
0 . 024
0.017
0.013
0. 020
0.028
0. 033
0 . 04 1
0 . 07 1
0. 134
0. 330
0.005
0 .011
207
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 4A
PARTICLE SIZE: F
ANALYSIS ID: AF169 - Teflon
AIR LEAK, SHINY FLAKES ON SURFACE
EXPOSED AREA: 6.42 SQUARE CM
MASS: 8221+- 10 MICRCGRAMS
.EMENT
AL
SI
F1
c
CL
K
CA
TI
V
CR
MN
FE
N I
CU
ZM
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
43.
121.
1.
55.
0.
0.
0.
1.
0
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
o
0.
0.
0.
0.
0.
0.
0.
*- .
0.
0 .
UG/CM2
359+-
697+-
996-t
32 OH
00 OH
372+-
34°+-
222+-
(-)() ("H
00 0+
Of) OH
509+-
278+-
011+-
034-t
013+-
00 OH
024 H
007n
0 11+-
04-0+-
09 5n
00 OH
OOOn
011+-
000+
OOOn
016+-
03 OH
029+-
00 OH
621+-
OOSn
0 9 3 +
.-,
5 .
0.
-£_ a
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
< j .
204
535
362
533
643
021
019
503
221
101
040
118
015
003
003
002
005
003
002
003
004
006
017
012
0 1 0
0 1 6
020
022
027
051
125
253
004
0 1 0
310.
731.
12.
353.
0.
^1 e
ji. e
7.
0
0 .
0.
1 6 .
1.
0.
0.
0.
(-)
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
16.
0.
0.
UG/FILTER
464+-
297+-
817+-
365+-
000 H
OOOj
243+-
847+-
OOOn
00 0+
000-!--
107+-
784+-
072+-
219+-
115+-
OOOn
155+-
044+-
070+-
256+-
6 12+-
("»"» OH
000 H
071+-
OOOn
000+-
104+-
192+-
133+-
00 OH
826+-
022n
626+-
14.
35.
-i.
1 6 .
4.
0.
0.
-'
1 .
0.
(D.
0,
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
1.
0.
0.
148
535
.-, -! cr
533
125
133
119
230
421
646
258
755
094
0 1 3
019
014
035
0 1 6
0 1 6
0 1 8
026
041
1 09
076
067
101
123
143
172
.-i --j C-
302
659
026
061
3,
9 _
0.
4,
0.
o .
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
o.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
PERCENT
776+-
504+-
156+-
359+-
000+-
029-!
027+-
095+-
OOOn
OOO+-
OOOn
196+-
022+
00 1 +
003n
00 1 +-
OOOn
00 2 H
001 + -
001+-
003 H
00 7+-
OOOn
000 +
00 1 +-
OOOn
000+-
001+-
002 H
002 H
000 +-
205n
000+
(-)() C;H
0.
0.
0.
0.
0.
0.
0 .
0 .
0.
f ) .
0.
-0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0 ,
o
*-*
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
172
432
023
202
050
002
00 1
03'~'
017
OOF:
003
009
00 1
000
000
000
000
OOO
000
000
000
000
00 1
OO 1
*' v. x
00 1
001
002
002
002
004
0 1 0
020
d) 00
OO l
208
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 4B
PARTICLE SIZE: C
ANALYSIS ID: CC097 Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
260+- 10 MICROGRAMS
ELEMENT
UG/CM2
UO/FILTER
PERCENT
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
20.
47.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
f)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
206+-
442+-
OOOn
240-1
OOO+-
105+-
096+-
303+-
000+-
OOO-i
000+-
534+-
055+-
00 1 +-
003 H
005+-
O<")O-t
00 1 +-
OOO-i
004+-
OOS+-
034+-
000+-
032+-
011+-
OOOH
003+-
000+ -
00 1 +-
030+-
027+-
72S+-
000+-
027+-
1.263
2.937
0. 172
0.627
0. 155
0.011
0. 009
0.203
0 . OS3
0 . 04 1
0.011
0.044
0.006
0 . 002
0.002
0 . 00 1
0.004
0 . 002
0 . 002
0 . 003
0 . 003
0.004
0 . 0 1 5
0.011
0.0 OS
0.014
0.01S
0.020
0.026
0.047
0. 117
0.202
0.003
0.007
129.
304.
0.
33.
0.
0.
0.
1.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
724+-
576+-
000+-
644+-
000+-
674+-
616+-
947+-
000+-
000+
OOO-i
747+-
350+-
005+-
0 1 7+-
031+-
000+-
OQ3+-
OOO-i
027+-
04S+-
220+-
000+-
207+-
C72+-
000+-
017+-
000+-
004+-
191+-
171+-
676+-
000+-
171+-
C'
* '
IS.
1.
4.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
122
854
105
024
992
068
059
318
531
-,.: -,
063
284
033
0 1 3
Oil
009
023
0 1 0
015
017
022
023
096
073
054
083
116
130
166
303
752
300
013
047
49.
114
0.
12.
0.
0.
0.
0.
0.
o
0.
1.
0.
0.
0.
0.
0.
0.
0-.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
330+-
..99+-
000-)
923+-
00<">+-
259+-
237+-
748+-
OOOn
(")<"> OH
OOO+-
4 ."-! '~> -!
135-1
002+-
006H
012+-
000-i
00 1 +-
000**
010+-
019+-
084+-
OOO-i
079+-
028 +-
OOO-i
006-1
00 0+
002-*
074+-
066+-
796+-
000+-
066+-
O
c-
'-'
0.
1.
(')
0.
0.
0.
0.
0.
0.
0;
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
660
523
424
623
~"ri 1
023
025
507
204
101
026
122
016
005
004
004
Oil
004
006
006
008
Oil
037
023
021
034
045
050
064
116
289
504
007
013
209
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 4B
PARTICLE SIZE: F
ANALYSIS IDS AF170 - Teflon
NON-UN IFORM COLOR OF DEPOSIT
EXPOSED AREA: 6.42 SQUARE
MASS: 3127+- 10
CM
MICROGRAMS
ELEMENT
JG/CM2
UG/FILTER
PERCENT
AL
SI
F'
CL
K
CA
TI
V
CR
MN
FE
MI
CU
ZN
GA
AS
SC
BR
RE
'~,r-'
Y
ZR
f!G
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
44.
100.
0.
55.
0.
0.
0.
0.
0.
0
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
(")
0.
0.
0.
0.
0.
-I
0.
0.
529+-
967+-
000+
3 13+-
00 OH
3 16+-
34 1 +-
967+-
000 +-
HO OH
OOOn
075+-
229+-
025+-
060 +
017+-
OOO-i
023-i
007 +
013+-
041+-
OS 1 +-
OOO-i
(")(")(")+
OOO-i
no OH
000 +
032-1
011+-
000+-
000+ -
134+-
00 IH
113+-
j!_ u
4.
0.
"'
0.
0.
0 .
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
030
=\ '"''-;
906
560
637
0 1 3
0 1 3
423
191
O:=:O
030
093
012
003
004
002
006
002
("JO 2
003
004
006
0 1 6
012
0 1 0
015
020
022
026
043
123
241
004
0 1 0
2S^i
643.
0.
355 .
0.
2.
*L *
6.
0.
O
O
13.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0
0.
0.
0.
0.
0.
I")
0.
14.
0.
0.
879+-
205+-
OOO-i
112+-
000+-
031+-
1S8+-
206+-
00 OH
OOOH
O(")("H
319+-
472+-
163+-
336+-
106+-
000+-
151+-
047+-
OS6+-
262+-
523+-
00 0-t
OO OH
OOOH
OOOH
0(1)0-1
204H
072+-
OOO-i
OOOH
023+-
00 5 H
760+-
13.
29.
5.
16.
4.
0.
0.
^ m
1.
0.
0.
0.
0.
0.
0.
0.
1")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
1.
0.
O
031
436
314
433
037
117
1 1 6
713
227
517
194
030
020
027
014
IT-:,'-.
0 1 6
015
0 1 8
026
037
105
074
063
097
126
143
166
31 1
791
550
025
OAS
_'
7.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
O
O
0.
0.
0.
0.
(")
0.
0 .
0.
0.
0.
0.
513+-
976+-
000+ -
370n
000+-
025-t
027+-
076 +-
OOOn
000+--
000+-
1 64+-
013+-
002 +-
005 H
001+-
000+-
002+-
00 1 +
00 1+-
003 +
OO/-H
OOOn
OOOH
OOOH
OOOH
OOOn
OO:":n
001 H
OOOH
OOOn
173+-
00 OH
00'?+
0. 160
0.363
0.072
0. 202
0. 050
0. 001
0 . 00 1
0 . 033
0 .015
O. OO/-.
0 . 002
0. 003
0. 001
0 . 000
0 . 000
O . OOO
0 . 000
0. 000
0. OOO
0 . 000
0. 000
O . OOO
0. 001
0. 001
0 . 00 1
0. 00 1
0 . 002
O. OO2
0 . 002
0 . 004
0 . (".) 1 0
0 . 0 1 9
0 . 000
0. 001
210
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 5A
PARTICLE SIZE: C
ANALYSTS ID: AC032 - Teflon
EXPOSED AREA:
MASS:
ELEMENT
AL
C T
' j.
P
S
CL
(.:;
CA
TI
V
CR
Mr-
FE
MI
CU
Zl\
GA
AS
O C
gz
R5
'- ~
V
ZR
p. j
FT-
A:-.
CD
j\
sr>
SE
BA
LA
H-.
_
FE-
13.
27.
G.
2.
G.
0.
G.
G.
G.
0.
0.
G.
G.
G.
G.
G.
G.
0.
0.
G.
0.
0.
0.
0.
G.
0.
0.
G.
G.
G.
G.
G.
.-.
0.
6.42 SQUARE
354+- jo
UG/CM2
562+-
548+-
GGOn
904+-
GGO+-
054 +-
07 1 +-
153+-
GGOH
GOO+-
000+-
324+-
033+-
005+-
G07+-
GOSn
OOOH
GOGH
004+
OOO-i
QQ7H
013+-
GG2+-
000+-
004+-
000+-
G01+-
000+ -
000+-
GGGH
068+-
325+-
.-..-. . , _
027+-
G.
- 1
G.
G.
G.
G.
G.
G.
G.
G.
0.
0.
0.
0.
G.
0.
G.
0.
0.
G.
0 .
0.
0.
0.
G.
G.
0.
0.
G.
G.
G.
G.
G .
0.
959
114
183
483
119
008
GGS
155
069
023
Oil
035
005
002
002
001
003
00 1
002
002
003
003
012
(JOS
007
010
014
016
021
035
092
149
003
006
87.
176.
G.
18.
G.
G.
G.
1.
G.
G.
G.
"^ .
0.
G.
0.
0.
G.
G.
0.
G.
G.
G.
G.
0.
0.
0.
G.
G.
G.
0.
0.
2.
0.
0.
CM
MICROGRAMS
UG /FILTER
07 1 +-
856+-
000 +-
641+-
GGO+-
344+-
456+-
0 1 3+-
GGO+-
OOOn
GGO+-
G82+-
247+-
035+-
G42+-
018+-
GOG+-
OOOn
024+-
00 OH
()44 -|
OS7+-
013+-
000+-
G27+-
GGO+-
G08+-
GOO+-
000+
OGO+-
437+-
039+ -
00 5 H
173+-
6 .
13.
1.
3.
G.
O
G.
G.
G.
0.
G.
G.
G.
G.
0.
G.
0.
0.
0.
G.
G.
G.
G.
G.
G.
0.
0.
G.
0.
G.
0.
0.
0.
0.
155
570
175
103
761
(-jcr -.
05 1
99/-.
445
182
070
j«!lilli!
034
012
Oil
00'?
022
008
01 1
012
0 1 6
021
074
052
046
067
09 1
1 02
132
224
590
957
0 1 S:
033
24.
50.
G.
cr
0.
0.
0.
0.
0.
G.
G.
0.
0.
0.
0.
0.
0.
0.
G.
0.
0.
0.
0.
0.
0.
G.
0.
G.
G.
0.
G.
G.
0.
0.
PERCENT
627+-
022+-
OGO+-
272+-
GGG+-
(-j.r/y^
129+-
286+-
GGGH
OOOn
000+-
589+-
070 +-
010+-
012+-
00 5 H
OOOH
000 +-
007 H
OGG+-
012+-
024n
004 +-
OOOn
008 +-
OOOn
002n
GOO+-
GGOH
000+-
124+-
591+-
001+-
049+-
1 . 375
4 . G9 1
0 . 332
0. 390
0.21 5
0 . 0 1 5
0 . G 1 5
(_) m V) !-! V'
0. 126
0 . 05 1
G . 020
G-,065
0 . 0 1 0
0. 004
0. 003
0. 002
O . OOA
0 . 002
(") O O '":
0. 003
O . <")>:"> 5
0 . OO/-.
0.021
0.015
0.013
0.019
0 . 026
0.029
0.037
0 . 063
G. 167
0 . 27 1
0 . GO 5
0 .011
211
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 5A
PARTICLE SIZE: F
ANALYSIS ID: AF171 - Teflon
SHINY FLAKES ON SURFACE
EXPOSED AREA: 6.42 SQUARE CM
MASS: 7924+- 10 MI CROC-RAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
."
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
FD
AG
CD
IN
SN
SB
BA
LA
HG
PB
47.
125.
0.
49.
0.
0.
0.
1.
0.
<"i
0.
A_
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
*i
0.
0.
803H
537+-
00 OH
533 +-
00 OH
382+-
358+-
222+~
000+
OOl'H
OOOH
521+-
281+-
012+-
040+ -
016+-
000 H
025+-
005n
009 H
044 + -
103+-
OOO-i
OOOn
OOOn
OOO-i
000 +-
0 11+-
010+-
OOOn
000+ -
290-1
004-t
095 H
.I
C|
0.
^ 0
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
( 5
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
179
70'-'
805
296
571
021
0 1 '?
604
241
101
040
113
0 1 5
003
003
002
006
003
002
003
004
007
017
012
0 1 0
0 1 6
02 1
023
027
049
127
250
004
0 1 0
306.
305.
0.
318.
0.
+L o
A a
7.
0.
0.
0.
16.
1.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
14.
0.
0.
927+-
947+-
000+-
354+-
00 OH
452+-
300-1
347+-
000+-
00 OH
OOOH
30 4+-
073+-
256+-
102+-
OOOn
160+-
034+-
057+-
280+-
664+-
000 +-
OOO-i
000+-
OOO-i
00 OH
072+-
065+-
OOOn
000+-
702+-
02 6+ -
612+-
13.
36.
5.
14.
O 0
0.
0.
~»
' ' 0
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(I).
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0 .
937
655
1 63
740
665
136
122
376
550
646
.-terc.
753
095
0 1 3
021
0 1 4
036
017
0 1 6
013
027
043
1 09
073
066
102
134
145
172
3 1 6
315
603
027
061
-' .
10.
0.
4.
0-
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
(")
0 .
_0.
0.
0.
0
0.
0.
0.
0.
0.
0.
0.
o
0.
n.
o.
0.
37 3 H
170+-
00 OH
0 1 7+-
OOOn
031+-
029-1
099 H
000+ -
OOOH
00 0+ -
204H
02 3+ -
00 1 H
003n
00 1 H
OO OH
002H
000 +-
00 IH
004H
rtni-iH
OOOH
000 +-
OOO-i
000+-
OOO-i
OOl-i
001+-
O(")fH
000+-
1 36+-
000 +-
003+-
0.
0.
0.
(j.
0.
0.
0.
0.
0.
0 .
o
-0.
0.
o
0.
0.
0 .
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0 .
177
463
065
136
046
002
002
04 v
020
003
on-";
0 1 0
00 1
OO(')
000
000
000
000
Of)!")
000
000
001
00 1
00 1
00 1
001
002
002
002
004
0 1 0
020
000
00 1
212
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 5B
PARTICLE SIZE: C
ANALYSIS ID: CC09S - Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
374+- 10 MICROCRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MC
PD
AG
CD
IN
SN
SB
BA
LA
HG
PP
24.
56.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
[")
707+-
639+-
000+-
1 23+-
000+-
1 39+-
111+-
379+-
000+-
000+-
000+-
768+-
082+-
004+-
008+-
007+-
000+-
002+-
000+-
004+-
010+-
042H
020+-
000+-
020+-
000+-
002+-
020+-
011+-
006+-
000+-
759+-
002+-
,-,-:.(-) j~
1 . 497
3.446
0. 1S9
0.670
0 . 1 65
0.012
0.010
0.256
0 . 1 02
0 . 05 1
0.020
0 . 054
0.007
0.002
0 . 002
0 . 002
0 . 005
0 . 002
0.002
0 . 003
0 . 003
0 . 005
0.016
0.012
0.009
0 . 0 1 4
0.019
0 . 022
0 . 027
0.048
0.119
0 . 209
0 . 003
O . OO7
158.
363.
0.
39.
0.
0.
0.
->
^> .
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
O.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
621+-
621+-
000+-
307+-
000+-
392+-
7 1 6+-
432+-
000+-
000+-
000+-
933+-
525+-
022+-
050+-
048+-
000+-
010+-
000+-
U2S+-
064+-
268+-
129+-
000+-
126+-
000+-
011+-
1 29+-
069+-
037+-
000+-
874+-
0 1 5+-
131 +-
9.
0-7-
1.
4.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
u.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
611
124
211
301
062
080
065
644
658
327
1 30
349
047
014
012
010
029
Oil
015
U17
022
03 1
100
075
058
090
119
143
173
308
766
340
020
047
42.
97.
0.
10.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0
374+-
1 33+-
000+-
500+-
000+-
238+-
191+-
650+-
000+-
OOOn
000+-
318+-
140+-
006+-
0 1 3+-
013+-
000+-
003+-
OOO-i
008+-
017+-
072+-
034+-
000+-
034+-
000+-
003+-
034+-
0 1 8+-
010+-
000+-
302+-
004+-
(-)--; =;+-
2
6
0
1
0
0
o
0
o
0
o
o
0
0
o
0
0
0
o
0
0
0
o
0
o
0
o
o
0
0
o
0
0
o
. 806
.455
O -.' A
l-fc-~
. 1 83
.234
.022
. 0 1 8
. 440
. 176
. 037
. 035
. 100
.-013
.004-
. 003
. 003
. 003
. 003
. 004
. 005
. 006
. 003
. 027
. 020
.015
. 024
. 032
. 038
. 046
.032
.205
. 360
. 005
. 0 ' 3
213
-------
SAMPLE ID: BP/CATALYTIC CRACKER
PARTICLE SIZE: F
ANALYSIS ID: AF172 - Teflon
- TEST NO. 5B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
7907+- 10 MICRCiGRAM'.!
EMENT IJG/CM2
AL
SI
P
t~-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MiD
PD
AG
CD
I N
SN
SB
BA
LA
HG
PB
46.
110.
0.
55.
0.
0.
0.
1 .
0.
0.
0.
^1
rfi.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
0.
('1
0.
0.
0.
0.
0.
0.
0.
o
0.
143+-
35 SH
OOO-i
733+-
OOO-i
350+ -
345+-
1 1 1 +-
00 OH
000+-
000+-
253+-
234+-
011+-
03 7 H
016+-
(')OOH
024+-
007n
0 1 0+-
035+-
095n
OOO-i
f)O(~H
004+-
OOO-i
000+-
013+-
029 +-
000 +
000-(
313+-
OOOn
089+-
2 . 1 03
5. 020
0. 906
2.579
0.642
0. 020
0 . 0 1 3
o. 5O:":
0. 20 1
0 . 09 1
0 . 030
0. 106
0.013
0. 003
0 . 003
0.002
0 . 005
0. 003
0. 002
0. 003
0. 004
0. 006
0 .017
0.012
0.01 0
0 . 0 1 6
0.021
0.023
0.027
0. 050
0. 126
0.251
0. 004
0 . 009
^'9/-,
703.
0.
357.
0.
"^i
*^ 0
7,
0.
0.
(")
14.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
14.
(1
(")
UG /FILTER
235+-
50 1 +-
000 +-
337+-
OOO-i
245+-
215+-
133+-
000+
00 OH
OOO-(
494+-
505+-
06S+-
239+
1 05+ -
OOO-i
153+-
044+-
066+-
225+-
603+-
00 OH
000+-
027+-
000+-
000+-
114+-
137+-
OOOH
000+-
OOO+
=;/-:;+
13.
-'l^!
5.
16.
4.
0.
0.
~;
1 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
0.
(")
501
227
314
559
119
127
113
230
531
194
63 1
03 1
017
020
0 1 4
035
0 1 6
0 1 6
0 1 9
026
041
1 09
073
067
100
132
146
175
324
3 OS:
6 1 4
025
O/-.O
~i
_ e
o
0.
4.
0.
0.
0.
0.
(")
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
PERCEIMT
747+-
961+-
000+-
526+-
000 +-
023 +
023 +-
09 OH
OOO+-
000 + -
OOO-)--
1S3+-
019+-
OOH
00 3 H
001+-
00 OH
002-1
001+-
001+-
00 SH
00 3 H
OOOn
00 OH
00 OH
OOCH
000 H
00 1 +-
002-1
000 +
OOO-i
00 OH
007H
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
(";i~
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0 .
0.
171
403
074
210
052
002
00 1
041
0 1 6
O07
002
00'"'
00 1
000
000
000
000
000
000
000
000
00 1
001
00 1
00 1
00 1
002
002
002
004
0 1 (")
020
000
001
214
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO.
PARTICLE SIZE: C
ANALYSIS ID: AC033 - Teflon
6A
EXPOSED AREA:
MASS:
6.42 SQUARE CM
612+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
3R
Y
ZR
MG
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
21.
41.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
023+-
261+-
000+-
191+-
000+-
119+-
126+-
1 96+-
000+-
000+-
000+-
542+-
052n
005+-
008 +-
006H
000+-
003+-
00 2 H
003+ -
0 1 0+-
023+-
020+-
000+-
002+-
007+-
009+-
000+-
OOOH
080+-
010+-
716+-
000+-
037 +-
1.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
344
020
260
645
159
012
012
252
102
044
015
051
007
002
002
002
004
00 1
002
002
003
004
012
008
007
Oil
015
0 1 6
021
039
093
166
003
007
134.
264 .
0.
39 .
0.
- 0.
- 0.
1.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
969+-
896+-
000+-
745+-
000+-
762+-
312+-
255+-
00 OH
000+-
000+-
432+-
33£..,._
029+-
04 9 H
037+-
000+-
020+-
012+-
019n
067+-
1 83+-
127+-
000+-
C 1 1 +-
045+-
056+-
000+-
000+-
514+-
065+-
598n
00 OH
238+-
'8 .
19.
1.
4.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
623
391
669
141
021
079
074
6 1 6
657
232
097
si< '^1 y
044
0 1 3
014
010
025
009
0 1 0
013
018
025
077
054
046
070
094
101
134
250
595
063
017
043
22.
43.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
042+-
260+-
000+-
49 IH
00 OH
125+-
133+-
205n
000+ -
OOOn
000+-
569+-
(-,crcr^
005+-
003H--
006+-
OOOn
003+-
002+-
003+-
011+-
030n
021+-
000+-
002+-
007+-
009+-
000+-
OOOn
084H
0 1 1 +-
751+-
00 OH
039+-
1 . 454
3.245
0.273
(") AffS
0. 167
0 . 0 1 3
0.012
0.264
0. 107
0 . 046
0.016
0.054
17. 007
0 . 002
0. 002
0.002
0. 004
0.001
0.002
0 . 002
0 . 003
0.004
0.013
0.009
0.008
0.011
0.015
0.016
0 . 022
0.041
0.097
0. 175
0. 003
0. 007
215
-------
SAMPLE ID: BP/CATALYTIC CRACKER - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS ID: AF173 - Teflon
SHINY FLAKES ON SURFACE, BUILD UP AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 10037+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
51.
1 65 .
(")
51.
0.
0.
0.
_£_ 0
0.
(")
0.
^
*
0.
0 0
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
()
0.
0.
"'
' e
0.
0.
165+-
122+-
OOO+
571+-
000+-
502+-
439+-
444+-
00 OH
(")O OH
OOOH
479+-
394+-
021+-
031+-
019+-
00 OH
023+-
01 OH
0 ion
065+-
1 36+-
OOOn
023+-
OOOn
OOOH
OOOn
01 OH
OOOH
OOOH
OOOn
217+-
00 OH
1S7+-
-^i
7.
0 .
<->
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
o
0.
o.
0.
0.
o.
0.
0.
0.
0.
0.
0.
Oc
0.
331
SOS
906
337
594
027
025
107
322
141
050
162
020
003
005
003
007
00:3:
003
OO:~:
OO5
003
020
014
012
0 1 8
024
026
03 1
059
143
305
005
0 1 3
323.
1060
0 .
"-' 1
OO 1 .
0.
«>' >
o
15.
0.
0.
0.
^^^
jl* m
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
o
0.
0.
20.
0 .
1.
432+-
. 09+-
000 +
033+-
000+
223+-
140+-
693n
OOOn
OOOn
OOOH
335+-
529+-
134+-
513+-
124+-
000+-
1S1+-
064+-
066+
417+-
372+-
00 OH
150n
000+-
OOOn
000+
062+-
OOOn
000+-
OOOn
650+-
00 OH
20O -i
14.
43.
cr
15.
--i
_'
0.
0.
7.
-i
0.
0.
, 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
(I).
0.
966
204
31 4
327
312
172
160
105
067
904
--, --, .-,
039
123
022
033
016
045
0 1 9
019
021
034
053
126
092
074
1 17
154
1 .63
193
373
947
957
029
037
O
10.
o
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("1
0.
257+-
5 1 0+-
OOOn
2S2+-
00 OH
032+-
031+-
156+-
00 OH
OOOn
OOOn
22 1 +_-
025+-
001+-
005+ -
00 IH
OOOn
002n
00 H
001+-
00 4 H
009n
000+-
00 1 +-
OOOn
OOOn
OOOn
00 IH
OOOn
OOOH
000+
205+-
OOOn
012+-
0. 143
0.473
O . O <=;:-:
0 . 1 52
0. 033
0 . 002
0. 002
0.070
0. 020
0 . 009
0 . 003
0 . 0 1 0
0 . 00 1
O. OOO
0. 000
On 000
0 . 000
O. OCx"'
0. 000
0 . ( I> O 0
O. OOO
0. 001
0. 001
0 . 00 1
0 . 00 1
0. 001
0 .002
0. 002
0 . 002
0. 004
0 . 009
0 . 0 1 9
0 . 000
0 . 00 1
216
-------
SAMPLE ID: BP/CATALYTIC CRACKER - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC077 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
s
CL
K
CA
TI
V
C.R
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.000+-
O . OOO-i
0.004+-
0.000+-
0.000+-
0 . OOO-i
0 . 000+-
0. 000+ -
0.001+-
0 . 00 1 +-
0 . 000+-
0.003+-
0.001+-
0. OOO-i
0. 001+-
0.001+-
0. 002+-
0. OOO-i
0. OOO-i
0. 000+-
0. 000+-
0. OOO-i
O. OOOH
0 . OOO-i
0.000+-
0 . OOO-i
0.024+-
0. 000+-
0.012+-
0.000+-
0. 156+-
0. 130+-
0. 000+-
O . OO<~H
0.012
0 . 009
0 . 004
0 . 020
0.006
0. <")O:~:
0 . 002
0 . 00 1
0.001
0.001
0 . 00 1
0 . 003
0.001
0 . 00 1
0 . 00 1
0.001
0.003
0.001
0.001
0.002
0 . 002
0.002
0 .011
0 . 007
0.006
0.009
0.013
0.015
0.019
0.033
O.OS5
0 .131
0 . GO2
0 . 004
0.000+-
O O Of)*
».' V >.' %,' *
0. 025+-
0. 000+ -
0. 000+-
0 . 000 H
0. 000+-
O. (">O("H
0.003+-
0.006+-
0. 000+-
0.019+-
0.005+-
0.002+-
0.005+-
O.OOS+-
0.011+-
0. OOO-i
0. 000+-
0. OOO-i
0.000+-
0. 000+-
0. OOOn
0.000+-
0.000+-
0.000+-
0. 154+-
0.000+-
0.076+-
0.000+-
1 . 004+-
O.S37+-
C . 000+-
0. OOO-i
o.oso
() m O5=;/-,
0.025
0. 126
0.039
0 .017
0.012
0 . OOS
0.006
0. OO7
0 . OOS
0 .019
o.oos
0. 009
0. 006
0.005
0 .017
0. 006
0. 009
0 . 0 1 1
0 .014
0.016
0. 069
0 . 047
0.040
0.059
O.OS3
0.094
0. 121
0.214
0.546
0 . 839
0 . 0 1 3
0 . 029
217
-------
SAMPLE ID: BP/CATALYTIC CRACKER - FIELD BLANK
PARTICLE SIZE: F
ANALYSIS ID: AF242 . Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
Z> A
F,
':'
CL
K
C-A
TI
V
CR
MN
FE
NI
CU
ZN
i- A
L>n
AS
i -r-
oE
BR
RB
I- f.
i.R
ZR
tvi i~"i
rlU
PD
AG
CD
IN
SN
SB
Bft
LA
HG
FB
0. 000+ -
0. 000+-
O . (")<") O+
0. 00 OH
0. OOOH
0. 00 2 +-
0. 000+ -
0. 00 1+
0. 000+
0. 00 OH
0. 000+ -
0. 000 +-
0 . 00 1 +-
0. 000 H
O. OOOH
0 . 00 1 H
0 . 00 OH
0. OOOn
0. 00 IH
0 . OOOH
0. 005n
0 . OOOn
0. OOOn
0. 00 3 H
0 . 00 OH
0. 016n
0. OOS+-
0. 014+-
0. 037+-
0 . 020n
O. oOOn
0. OOOn
0 . 003n
0. 001 H
0 . 0 1 3
0. 009
0 . 004
0.023
0. 009
0. 003
0. 002
0.001
0. 001
0.001
0 . 002
0. 004
0. 002
0.002
0.001
0.001
0. 004
0 . 00 1
0. 002
0. 002
0.003
0 . 003:
0.01 4
0 . 0 1 0
0. 009
0.012
0 .017
0 . 0 1 3
0 . 022
0 . 04 1
0. 102
0 . 1 6 1
0. 002
0. 006
0. OOOn
0.000+-
0. 000+
0. OOOn
0. 000-t--
0. 010+-
0. 000+-
0. 003+-
0. 000+
0. OOOn
0. 00 O-H
(">. OOOH
0 . 009+-
0. 000+-
0. 00 0+
0 . 003+-
0. OOOn
0. 002 +-
0. 006+-
0 . 0 0 0 +
0. 033+-
0. 000 +
O. OOO+-
0.017+-
0. OOOH
0. 103+-
0.051+-
0 O!ZI:Z;H
0. 238+-
0. 12S+-
0. OOOn
0. 000 +-
0.018+-
0 . OO.S+-
0. (>S 4
0.0157
0. 028
0. 163
0. 053
0. 020
0 . 0 1 4
0 , 0 1 0
0. 007
0 . 009
0 . 0 1 0
0. 023
0 . Q i Q
0 . 0 1 0
0. 007
0 . 006
0. 023
0. OOS
0 . 0 1 1
0 . 0 1 4
0 , 0 1 S
0.021
0. OS 7
('). O /-,:";
0. 055
O. 07 ft
0. 108
01 1 '-
. i 1 O
0. 142
0. 265
0.657
1 . 033
0 . 0 1 6
0. 033
218
-------
SAMPLE ID: BP/CATALYTIC CRACKER - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: CC122 - Nuclepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UO/FILTER
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
R"B
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.000+-
0 . 000+-
0 . 000+-
0 . 000+-
O.OO4+-
0.000-f
0 . 000+-
0.001+-
0 . 00 1 +-
0 . 000+-
0.000+-
0.006+-
0.000+-
0 . 000+-
0 . 00 1 +-
0.000+-
0 . 006+-
0.000+-
0 . 002+-
0.003+-
0.000+-
0.000+-
0.000+-
0.001+-
0.001+-
0.0084
0 . 000+-
0 . 000+-
0. 000+-
0. 000+-
0. 103+-
0. OOOH
0.000+-
O. OOOH
0.025
0.019
0.010
0 . 023
0.010
0 . 003
0.002
0.001
0 . 00 1
0.002
0.001
0.004
0.001
0.002
0 . 00 1
0 . 00 1
0.004
0 . 00 1
0. 002
0.002
0.003
0 . 003
0.014
0.010
0.009
0.011
0.017
0.019
0.024
0.044
0. 110
0. 171
0 . 003
O. c") (V-,
0.000+-
0.000+-
0.000+-
0.000+-
0.027+-
0 . 000+-
0 . 000+-
0 . 009+-
0 . OOS+-
0 . 000+-
0.000+-
0.039+-
O.OOO-i
0. OOOH
0.008+-
0.001+-
0.040+-
0 . 000+-
0.015+-
0.019+-
0 . 000+-
0. OOOn
0.000+-
0.008+-
0.007+-
0.052+-
0.000+-
0.000+-
0.000+-
0 . 000+-
0 . 658+-
0.000+-
0. OOOn
0 . 000+-
0. 158
0 . 1 20
0 . 06 1
0 . 1 45
0.062
0 . 0 1 9
0.014
0 . 009
0. 006
0 .011
0.009
0.025-
0 . 009
0 . 0 1 0
0.007
0 . 006
0.025
0 . 009
0 .014
0 . 0 1 5
0 . 0 1 9
0.021
0 . 089
0 . 067
0 . 058
0.074
0. 112
0. 124
0. 156
0 . 280
0 . 706
1 . 097
0 . 0 1 7
0.041
219
-------
SAMPLE ID: ATLANTIC METALS/SEC.
PARTICLE SIZE: C
ANALYSIS ID: AC034 - Teflon
ALUMINUM SMELTER - TEST NO. 1A
EXPOSED AREA: 6.42 SQUARE CM
MASS: 24+- 10 MICROGRAM1.;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
IN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HO
PB
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
172+-
2 16+-
01 CH
00 OH
350+-
13?+-
044 +
008+-
00 1 H
007n
00 0+
030n
00 6H
007+-
0 1 1 +-
00 OH
000 H
00 1 H
002n
00 OH
000 H--
OOOn
020 H
000+-
00 OH
00 OH
008+ -
005n
OOOn
033+-
OOOn
238+-
000+
0 0 8 H"
0.
0.
0 .
0.
0.
0.
(")
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0 .
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
020
0 1 9
0 0 7
045
054
024
tVt=;
002
001
001
001
007
00 1
002
002
001
00:3
On ]
00 1
002
002
002
0 1 0
007
O !")/-,
008
012
014
0 1 8
032
076
120
002
004
1.
1.
0
0.
5 .
0.
0 .
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
105+-
38?H
OAf=H
OOOn
457+-
391+-
285+-
04'r'H
00 4 H
043 +-
00 OH
515+-
036+-
045+-
073+-
00 H
00 OH
007 +-
0 1 2+-
00 OH
OfH'H
00 OH
132 + -
000 H
000 H
000 H
054+-
032+-
000+-
2 1 3+-
000 H
53 1 +-
OOOn
051+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
t")
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 30
123
047
347
152
032
0 1 0
006
008
007
045
0 1 0
Oil
0 1 3
006
017
O(V:.
009
0 1 0
0 1 3
0 1 4
064
044
037
054
079
088
1 15
203
489
771
0 1 3
023
4.
5.
0.
0.
jd'^1
' n
1 .
0.
0.
0.
O
-t
0.
0.
0.
0.
C)
0.
o.
0.
0.
0.
0.
o
0.
0.
0..
0.
o
0.
0.
6.
0.
0 .
602+-
736+-
263+-
000 +
737+-
712+-
187+-
203 + -
018+-
177n
OOOn
148+--
152+-
13*+-
306+-
003 +
O<">OH
030-i
050+-
OOO-i
000 H
00 OH
543+-
OOOH
000+
OOOn
226+-
132+-
OOOH
00 OH
379+-
OOH
2 1 4 +-
1 . 992
2.465
0. 224
1 . 206
9.533
1 /-,"~ t
0 .513
0. 094
0 . 026
0. 082
0, 030
0 . 9 1 4
0.075
0. 091
0 . 1 38
0. 024
0. 072
0. 029
0 . 042
0. 04 I
0. 052
0. 059
0 . 35 1
0. 135
0. 154
0.227
0.340
0. 370
0 . 480
0.924
2.037
4.17 1
0 . 056
0. 147
220
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - TEST NO. 1A
PARTICLE SIZE: F
ANALYSIS ID: AF174 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 110+- 10 MICRO-GRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
C T
_.' -L
P
1;',
CL
K
CA
TI
V
CR
MIM
FE
NI
CU
ZN
GA
AS
I'd.
ER
RB
SR
Y
ZR
tm 1 \
MO
PD
AG
CD
IN
SN
SB
BA
LA
LJ|~-
ML?
PB
0.
0.
0.
7.
0.
.-,
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
*.'
0.
0.
0.
0.
0.
0.
0.
0.
0.
O~
.
0.
393+-
409+-
1 60+-
045+-
630+-
097+-
036-1
003+-
003+
OOOn
003-*
023+-
002-t
017+-
041+-
002+-
004 +-
OOO-i
009-1
000+-
002+-
000 +
(")C~H~H
*_' *_/ ^' »
000+-
010+-
000+-
000+-
036+-
040+-
096+-
163+-
106+-
/~w"w"\_i._
\J \,i \J ~
020+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
C)
*' N
0.
0.
0.
0.
0.
0.
0.
0.
o.
(-)
*-' »
0.
02S
024
030
336
OS9
099
003
001
00 1
00 1
00 1
004
00 1
002
003
00 1
004
00 1
002
002
002
003
0 1 "
*-' X J
009
OOS
012
015
017
020
040
096
147
()():;
V.' ' -'
006
"".'
£-:?
0 . 00 G
0 . 0 1 6
0. 023
0 . 007
0.021
0. 007
O . f i 1 2
0 . 0 1 2
0 .014
0.017
0. 071
0.051
0.046
0. 063
0. 090
0. 102
0. 120
0 . 238
0 . 56:3
0 . 359
0 . 0 1 5
0. 035
221
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - TEST NO. 2A
PARTICLE SIZE: C
ANALYSIS ID: AC03S - Teflon
EXPOSED AREA
MASS:
6.42 SQUARE CM
153+- 10 M1CROGRAM
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
IMI
C-U
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
on
i i-1
AG
CD
IN
SN
SB
BA
LA
HG
PE
1.
O
A. *
0.
0.
4.
.te. e
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("t
0.
c")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
154+-
733+-
03 9 -t
465+-
217+-
446+-
132+-
027+-
002-f
015+-
009+-
3 13+
0 1 2+-
025+ -
043+-
OOO-i
001+-
O ("):":+
009 -t
OOO+
00 1 -i
OOOn
009-1
000+-
007+-
014+-
020+-
0 1 3+-
OOO-i
084-i
OOO-i
000 H
OOO-i
022+-
0.
0.
0.
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
075
175
027
054
349
131
01 S
003
001
002
002
020
002
003
004
001
003
00 1
002
002
002
002
Oil
007
007
0 1 0
014
015
0 1 9
OSS
OS2
1 30
002
005
7.
17.
0.
ji e
27.
15.
1.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0 .
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
410+-
545+-
57 1 +-
933+-
073+-
705+-
166+-
171+-
016+-
096-1
(IS/-.+-
012+-
079+-
159+-
30 3+ -
000-t
003-t
020-f
059+-
00 0+
00 4 H
OOO-t-
060+-
000+-
04S+-
093-1
126+-
035-i
000+-
539+-
000+-
000+-
000+-
143+-
0.
1.
0.
0.
v c
1.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
479
125
170
347
244
160
115
0 1 9
003
0 1 2
0 1 0
'1 --'O
1 *.-
0 1 4
0 1 S
027
00.6
021
00 S
0 1 3
01 1
0 1 4
015
063
043
044
066
037
095
120
244
529
'-' J' ^L
015
0:34
4.
11.
0.
1.
17.
10.
0,
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0 .
0;
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0 .
357+-
50 1 +-
374+-
959+-
746+-
295+
764+-
112+-
0 1 0 + -
063 + -
037 + -
319+-
052 + -
104+-
20 2 -t -
000+-
00 5 H
0 13+-
039+--
000+-
O ("):": 4
000+
039--
OOO-i
03 1 +-
061+-
OS3+-
056-1
OOOn
353+-
000+-
00 OH
OOO +
Q94+-
0.447
1 . 055
0.11 4
0.261
1 . 375
1.017
0. 090
0 . 0 1 5
0. 005
0. 009
0 . 007
0."120
0 . 0 1 0
0 .014
0 . 022
0 . 004
0 .014
O. DOS
0. 009
0. 007
0. 009
0 . 0 1 0
0. 044
0. 032
0 . 029
0.043
0.057
0. 063
0 . 079
0 . 1 62
0.347
0.545
t") . ("i i f)
0. 023
222
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF175 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
604-1 10 MICROGRA*v;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
IMI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
FD
AG
CD
IN
SN
SB
BA
1 A
UR
Hl~i
n11
PB
1.
6.
0.
2.
21.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
O"
(~)
*.'
0.
362+-
037+-
351+-
714+-
854+-
443+-
074+-
023+-
006+-
027+-
010+-
236+-
031+-
039+-
074+-
000+-
010+-
015+-
062+-
003-1
004+-
0 1 4+-
002 +-
OOO-i
000+-
019+-
000+-
004+-
045+-
562+-
034+-
()[-) n-i-
ij \j i j T
(-JO (~H
\,' *-**-' '
074+-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0"
.
0.
0.
074
279
064
140
009
434
028
003
00 1
003
002
014
003
00:3
005
00 1
005
002
004
002
003
003
014
010
003
013
018
0 1 9
023
063
107
1 /- °
X '_" '
003
COS
o
'_
-O
"!«
17.
140.
60 .
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
" '
0.
(-)
*..'
(")
0.
746+-
760+-
252+-
426+-
302+-
655+-
473+-
150+-
036+-
172+-
06 1 +-
516+-
20 OH
251+-
477+-
001+-
067+-
095+-
395+-
021+-
029H
09 l-i
011+-
000 +-
OOO-i
123+-
000+-
023+-
286+-
606+-
2 1 6+-
000+
OOOH
476+-
0.
1.
0.
0.
6.
^ t
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
o.
0.
476
791
412
896
480
786
173
020
009
0 1 6
0 1 3
089
020
021
031
009
032
012
026
0 1 6
0 1 9
022
090
064
054
033
115
122
150
404
'-, !-! "!
076
0 1 8
052
1.
6.
0.
2.
'~!"-\ ,
10.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o-.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
447+-
412+-
373+-
833+-
212+-
035+-
079+-
025+-
006+-
023+-
01 OH
251+-
033 +-
042+-
079+-
000+-
011+-
0 1 6+-
065+-
004 H
005 +-
015+-
002+-
000+-
000+-
020+-
000+-
004H
047+-
597+-
036+-
(")O(")H
OOOH
079n
0.082
0 .315
0.068
0. 156
1 . 1 39
0.490
0. 030
0.003
0 . 00' 1
0.003
0. 002
a; 01 5
0 . (1)0:3
0. 004
0.005
0 . 00 1
0 . 005
0 . 002
0. 004
0.003
0.003
0. 004
0 .015
0.011
0.009
0 .014
0.019
0. 020
0.025
0.063
0. 113
0. 173
0. 003
0 . 009
223
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER
PARTICLE SIZE: C
ANALYSIS ID; CC100 - Nuclepore
PAIRED W/ QUARTZ
EXPOSED AREA; 6.42 SQUARE CM
MASS OF DEPOSIT: 203+- 21 MICROGRAMS
- TEST NO. 2B
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
;-;
CL
K
CA
TI
V
CR
MN
FE
MI
CU
ZN
GA
AS
SE
BP
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
7)
*
0.
1.
.'
""'
'
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0
C).
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
(")
564+-
OOS-i
133+-
009+-
357+-
3404
214+-
04 1 +-
002n
007-t
010+-
301+-
OOS+-
023+-
061+-
00 1 +-
OO OH
009-t
019 +
OOSn
00 OH
00 4 H
005n
007 +
00 1 +-
00 2 H
OOOn
014+-
020+-
207 +-
042n
OOOn
004+
o ":/-, +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
091
107
029
066
506
197
020
004
001
002
002
0 1 S
002
003
004
001
004
002
003
OO:~:
003
003
014
Oil
003
013
017
020
025
05 1
112
175
003
OO7
10.
12.
0.
6.
63.
24.
1.
0.
0.
O
0.
1 .
0.
0.
o.
0.
0.
0.
0.
c>.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
04 0+-
892+-
353+-
479+-
23 OH
655+-
374+-
262+-
014+-
O43+-
062 + -
931+- '
05 OH
130+-
394+-
005+-
OOOn
057+-
125+-
051+-
OOOn
023n
035+-
042n
005+-
0 1 1 +-
00 0+
093+-
125+-
323 H
267+-
000+
026+-
22Sn
0.
0.
-o.
0.
.
o ,
1.
0.
0.
0.
.0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
0 .
0.
535
639
135
422
250
jL. t1 '
130
024
009
0 1 3
Oil
117
0 1 3
019
029
007
023
Oil
013 -
017
i~) 1 9
022
09 1
063
049
035
110
132
161
324
720
122
020
045
4.
6.
0.
*O
' a
30.
11.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
S27+-
19S+-
4 1 0+-
1 1 5+-
423+-
353+-
661+-
126+-
00 7 H
O21+-
03 OH
923+-
02 4+ -
037+-
139+-
002+-
OOO-+-
027 +
060+-
024+-
000 H
014+-
017+-
020+-
OO2n
005+-
OOOn
044+-
060H
639+-
123+-
000 +
012+-
1 10+-
0.563
0.703
0. 093
0.374
3. 446
1 . 342
0 09 1
0 .017
0. 004
O . OO A
0. (I> 06
0. 109
0.007
0 . C! 1 3
0. 024
0. 003
0 . 0 1 :":
0. 006
0 .011
O (")(") R
0. 009
0 . C> 1 0
0.044
0 . 033
0 . 023
0.041
0 , 05:3
0 . 063
0. 073
0. 169
0 . 346
0. 539
0. 009
0. 024
224
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - TEST NO. RS-1A
PARTICLE SIZE: C
ANALYSIS ID: AC042 - Teflon
ATLANTIC BAGHOUSE RESUSPENSI fiN
EXPOSED AREA: 6.42 SQUARE CM
MASS: 4939+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
Z*
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BP
RB
SR
Y
ZP
fc> i \
MO
PD
AG
CD
IN
'-'M
-'1 M
SB
BA
LA
HG
PB
0.
0.
0.
21.
274.
rf-.r
C'--'
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(-)
V.'
0.
o
I.'
0.
0.
0.
0.
0.
O~
0.
0.
0.
0.
6.
000+-
000+-
000+-
412+-
377+-
073+-
014+-
076 +-
019+-
022-1
05 1 +-
355+-
031+-
133+-
384+-
OOO-i
000+-
029+-
263+-
074 +-
O15!'"'-!
\^i ._) ..' i
009+-
OO'"H
V_* \^i '.^j i
152+-
045+-
037+-
093+-
035+-
OO-r-j._
_'^^.
320-1
000+-
183+-
015+-
1 1 9+-
1.
0.
0.
1.
14.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(-)
*_*
0.
(-)
'
0.
0.
0.
0.
0.
(-)
\.1 m
0.
0.
0.
0.
0.
1 00
720
360
1 40
000
313
2^2
006
002
003
004
021
003
003
021
009
037
0 1 C)
0 1 6
006
DOS
*-**.'*
009
O"?l
*-' -ta- JL
014
Oil
015
020
020
O'~7
V.'^ r
057
119
133
006
314
0.
0.
0.
137.
1761
546.
6.
0.
0.
0.
0.
2.
0.
0.
. ,
*H
0.
0.
0.
1.
0.
o.
0.
0.
0.
0.
0.
0.
0.
o
*-*
"^1
0.
1.
0.
39 .
000+-
000 H
OOO-i
464+-
. 50+-
200+-
5 1 0+-
490+-
121+-
143+-
330+-
232+-
201+-
353+-
467+-
000+-
000+-
133+-
638+-
477+-
38 1 +-
057+-
OOO-i
976+-
289+-
240+-
593+-
222+-
526+-
053-i
000+-
207+-
093+-
236+-
7.
4.
2.
7.
39.
27.
1.
0.
0.
0.
0.
0.
0.'
0.
0.
0.
0.
0.
0.
0.
o
*-'
0.
0 .
0.
0.
0.
0.
0.
o.
0.
0.
1.
0.
"Tl
063
623
312
320
330
719
483
037
014
0 1 6
024
1 36
022
053
134
060
236
066
1 03
036
033
060
134
09 1
074
096
132
131
172
366
762
175
040
0 1 S
0.
0.
0.
±.
-.^
_'-'
11.
0.
0.
0.
0.
0.
0.
).
).
) .
n.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000+-
00 OH
000+-
733+-
667+-
05S+-
132+-
010+-
002+-
003+
007-!--
046+-
004+-
017+-
050+-
000+-
000+-
004+-
03 4+ -
010+-
008 H
001+-
000 -i
020+-
006H
005+-
012+-
004 +-
01 H
042+-
OOO-i
024 +-
002+-
795+-
0. 143
0.094
0.047
0. 143
1 . 32 1
0.562
0 . 030
0.001
0. 000
0. 000
0 . 000
0 . 003
0". 000
0. 001
0. 003
0 . 00 1
0. 005
0. 001
0. 002
0 . 00 1
0 . 0 (J 1
0.001
0 . (1)03
0 . 002
C' . 00 1
0. 002
0.003
0.003
0. 003
0.007
0 . 0 1 5
0.024
0. 001
0 . 04 1
225
-------
SAMPLE ID: ATLANTIC METALS/SEC.
PARTICLE SIZE: F
ANALYSIS ID: AF1S3- Teflon
ATLANTIC METALS B. H. RESUSP
EXPOSED AREA: 6=42 SQUARE
MASS: 624+- 10
ALUMINUM SMELTER - TEST NO. RS-1A
CM
MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
'
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RB
SR
V
ZR
r",o
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
4.
-;C;
13.
0.
0.
0.
0.
0.
0.
0 .
0.
O
0.
0.
0.
0.
0 .
0.
do
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
1.
000+-
00 OH
000+-
173+-
737+-
714+-
1 58+-
012+-
003n
002 H
005n
085+-
005+-
032+-
lV-,VH
00 2+ -
033 + -
009+ -
035n
009n
00 8 H
005n
000+-
011+-
009+-
017+-
033+-
021+-
032+-
139+-
000+-
OOu+
004H
7 40+-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
' ' 4hi!
241
1 3 1
217
736
623
036
002
00 1
00 1
00 1
007
00 1
003
004
004
0 1 6
003
003
002
002
004
Oil
007'
006
009
012
013
016
034
076
120
003
031
0.
0.
0.
26.
249.
I-i:~! .
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
11.
000+-
000+-
000+-
790+-
013+-
045+-
013+-
073+-
021+-
014+-
035+-
545+-
032 H
205n
444+-
013+-
243+-
05S+-
225+-
o=;s+-
051+-
032 H
OOOn
06S+-
057+-
110+-
209 H
133+-
205+-
S90+-
000+-
000 +
023 H
163+-
-%
1.
1.
1.
11.
4.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
455
550
163
394
466
034
"' '" '"'
012
006
007
OOS
042
009
0 1 8
023
022
1 0 1
0 1 9
02 1
012
0 1 3
023
O /-.:=:
042
041
053
077
03 1
1 04
219
490
771
020
tr--.-;i
0.
0.
0.
4.
39 .
14.
0.
0.
0.
0.
0.
0.
O
0.
0 .
0.
0.
0.
("i
0 .
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
o
^.'
0.
1.
OOO-i
OOOn
000+ -
291+-
332+-
101+-
162+-
013+
003 +
002 + -
00 6+
OS 7 H
On^-f-
033+-
071 H
002n
039 + -
009 +--
O:-:/-.H
009 +
008+-
005+-
00 OH
0 11+-
009+-
013+-
033+-
021+-
033+-
142+-
000+-
00 OH
004 H
739+-
0. 393
0.243
0. 186
0.234
1 . 944
0. 634
0. 037
0 . 002
0. 001
0. 001
0 . 00 1
0 . 007
0.. 001
0. 003
0. 005
0 . 004
0 . 0 1 6
0. 003
0 » 003
0. 002
0. 002
0 . 004
0 . 0 1 1
0. 007
0. 007
C). 009
0 .012
0 . 0 1 3
0 .017
0.035
0. 079
0. 124
0. 003
0. 039
226
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER
PARTICLE SIZE: C
ANALYSIS ID: CC111 - Teflon
ATLANTIC METALS BH DUST RESUSPENSION
EXPOSED AREA: 6.42 SQUARE CM
MASS: 2916+- 10 MICROGRAMS
- TEST NO. RS-2A
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
C'Tj
0.
0.
0.
13.
171.
55.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
<-]
*-'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1
000+-
000+-
000+-
331+-
732+-
632+-
553+-
048+-
008+-
007+-
022-!
180+-
016+-
071+-
2 1 6+-
004+-
000+-
021+-
146+-
045-1
024+-
OOO-i
000+-
070+-
000 +-
020-1
000+-
000+-
000+-
109+-
071+-
000+-
007+-
1 '-'A-l
1 . 400
0.830
0 . 6-60
0.73S
S.765
2. SIS
0. 150
0.004
0 . 002
0.002
0 . 003
0 .012
0. 003
0. 0*05
0 .012
0. 006
0.024
0 . 006
0. 009
0. 004
0 . 004
0. 006
0 . 0 1 S
0 . 0 1 3
0.011
0.016
0.021
0.024
0.027
0.054
0. 127
0. 193
0 . 005
n _ 1 A.':
0.
0.
0.
89.
1 1 02
357.
~'
'
0.
0.
0.
0.
1 .
0.
0.
1.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
20.
000+-
000+-
000+-
1 1 6+-
.52+-
1 57+-
565+-
311+-
049+-
044+-
141+-
156+-
104+-
455+-
387+-
02S+-
000+-
137+-
93S+-
2S8+-
157+-
O »">(") H
OOOH
449+-
000+-
123+-
000+-
000+-
000+-
697+-
456+-
000+-
042+-
054+-
C1
' '
5.
4.
4.
56.
IS.
0.
0.
0.
0.
0.
()
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
1.
9SS
650
">':; 7
737
270
093
963
026
on
014
0 1 6
Oir:r>
017
034
OSO
037
153
037
061
027
026
040
118
OS5
063
102
135
1 56
176
345
S17
271
032
04S
0.
0.
0.
3.
37.
12.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
OOOH
OOO-i
000 -i
056 + -
805+-
247+-
122+-
011+-
002-1
00 2 H
005+ ~
040 +
004 i-
016+-
04S + -
00 1 +-
OOO-i
005+-
032 +-
OlO-i
005+-
000 +-
OOO-i
015+-
OOO-i
004+-
OOO-i
000+-
000+-
024 +-
0 1 6+-
000+-
001 + -
688+-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
o.
0 ,
0.
0 .
0.
0.
0.
0.
{-) _
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
30S
194
145
1 63
934
,'-, ^ V|
033
001
000
00'")
00 1
Cw53
00 1
00 1
003
00 1
005
001
!"! O 2
00 1
00 1.
00 1
004
003
002
004
005
005
006
012
023
044
001
ft -'-.
227
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - TEST NO. RS-2A
PARTICLE SIZE? F
ANALYSIS IDs AF1S4 - Teflon
ATLANTIC. METALS B. H. RESUSP-
EXPOSED AREA: 6.42 SQUARE CM
MASS: 137+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG /FILTER-
PERCENT
AL
SI
P
s
CL
L:'
CA
TI
V
CR
MM
FE
NI
CLI
ZN
GA
AS
SE
ER
RB
C;F'
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
1.
12.
-' D
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00 OH
000 H
000+
251+-
214-t
30 OH
06 1 +-
004 H
002+
000+
001+-
031+-
003+-
010+-
023 H
Of) OH
017+-
00 2 H
012+-
003 H
006+-
005 + -
030+-
019-i
002+-
00 OH
029+-
043+-
00 3 H
000 H
135-!
107+-
OOO-i
776+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
131
074
061
OS2
567
205
013
001
00 1
00 1
001
004
001
002
002
002
0 1 0
002
002
002
002
00:3
Oil
OOS
007
0 1 0
013
015
01 S
033
087
130
O ("):":
033
0.
0.
0.
!*!
73 .
21.
0.
0.
0.
0
0 .
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
o.
o.
4.
00 OH
000 +-
00 OH- -
029+-
412+-
134+-
392n
024 +
012+-
OOO +
009 H
20 0+
02 OH
061+-
147+-
Ot'H'H
111+-
013+-
073+ -
020n
036+-
031+-
193+-
121+-
014+-
00 OH
1S6+-
310+-
019+-
000+-
S65+-
635+-
002+ -
930 +-
0.
0.
0.
0.
- ' m
1.
0.
0.
0.
0.
0.
01
0.
0.
0.
o .
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
S40
473
.394
^^'O
642
-; 1 ;O
OS 6
OOS
006
007
OOS
027
009
0 1 1
014
014
066
0 1 1
0 1 3
012
0 1 4
0 1 9
071
050
045
061
OS6
099
114
213
557
!-! '~l "'
017
242
0.
0.
0.
4.
42 .
11 .
0.
0.
0.
()
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0 .
0.
0.
0.
()
0.
0.
0.
0.
0.
0.
o.
4L, .
OOOH
OOCH
000-t
30 2 H
011+-
350+-
210+-
013+-
00 6 H
("X'M'H
005n
107+-
01 1+-
033 H
079+-
00 OH
059+-
00 7+-
04 2 H
010+-
019+-
017+-
104+-
065+-
OOSn
O(">OH
100+-
1 66+-
0 1 0+-
000+
464 +-
367+-
001 +
66S+-
0.450
0.256
0.21 1
0.365
2.979
0.932
0. 047
0. 004
0 . 003
0 . 004
0 . 004
"0.016
0 . 005
0 . 006
0. OOS
0 . OOS
0 . 036
0 . 006
6 . 007
0. 006
0. OOS
0 . 0 1 0
0. OSS
0.027
0.024
O. Of-;:"1;
0.047
0.054
0 . 06 1
0.114
0.299
0. 446
0 . 0 0 9
0. lir>3
228
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - FIELD BLANK
PARTICLE SIZE: F
ANALYSIS ID: AF241 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
£
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER-
RS
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.003+-
0.000+-
0.000+-
0.000+-
0.000+-
0.004+-
0.000+-
0 . OOO-i
0 . 00 1 +-
0. 000+-
0 . 000+-
0. 000 H
0.000+-
0. 000 H
0. 00 OH
0 . 000+-
0. 000 +-
0 . 00 1 +-
0 . 00 1 +-
0 . 000+-
0.006+-
0. OOO-i
0.000+-
0.000+-
0 . 000+-
0.011+-
0.006+-
0 . 026+-
0.019+-
0.026+-
0 . 000+-
0. OOO-i
0 . 00 1 H
0.007+-
0.014
0.009
0.004
0.026
0.010
0.003
0.002
0 . 00 1
0.001
0 . 00 1
0 . 002
0 . 004
0 . 00 1
0. 002
0 . 00 1
0 . 00 1
0.004
0 . 00 1
0.002
0 . 002
0 . 003
0 . 003
0.014
0.01 0
0 . 009
0 .012
0.017
0.019
0 . 022
0 . 042
0. 104
0. 166
0 . 002
0 . 006
0 . 022+-
0 . 000+-
0.000+-
O.OOO-i
0.002-t
0 . 026+-
0. OOO-i
0 . 000+-
0.009-t
0. 00 OH
0.000+-
0.000+-
0 . 000+-
0 . 000 H
0. 000+-
0.002+-
0. OOO-i
0. 009n
0.006+-
0.001+-
0. 03 9+-
0. 000+ -
0. 000+-
0.000+-
0.000+-
0.069+-
0.03S+-
0 . 1 65+-
0. 125+-
0. 163+-
0. 000+-
0.000+-
0. 009+-
0 . 043+-
O.OS7
0.053
0 . 029
0. 165
0.062
0.021
0.015
0. 009
0. 007
0.003
0 . 0 1 0
0.024.
0. 003
0.011
0. 007
0. 006
0.024
0. 009
0 . 0 1 1
0 .015
0 . 0 1 3
0. 021
0.039
0.064
0 .055
0.073
0. 109
0 . 1 22
0. 142
0.271
0.670
1 . 063
O.O15
0. 039
129
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER
PARTICLE SIZE: C
ANALYSIS ID: AC076 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
- FIELD BLANK
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
-r*
CL
K
CA
TI
V
CR
MN
_» |^L
FE
NI
CU
ZN
GA
AS
SE
BR
RB
C-C'
C>r\
Y
ZR
(Vlt~t
nU
PD
AG
|~. ^-r
L-D
IN
j*». i, i
bN
SB
E'A
LA
HG
rj ri
PB
0. 005 H
0. OOOn
0. OOOn
0 . OOOn
0. 00 IH
0. OOOH
O. Of) OH
0. 00 0+
0. 000 +-
0 . 00 1 +-
0. OOOn
0 . 00 1 +-
0.001+-
0. 000 +-
0. OOOn
0 . 000+-
0 . OOOH
0. OOOn
0. 000+ -
0. 001+-
0. 00 OH
0. OOOn
0. OOOH
0 . OOOn
0.001+-
0 . OOOn
0. 029+-
0. 000+-
0. 002n
0. OOOn
0. 094+-
0. 094 +-
0. 002'n
0. 009 +-
0 .013
0. 009
0 . 004
0.019
0. 006
0.002
0. 002
0 . 00 1
0 . 00 1
0 . 00 1
t'l l~)t~'i 1
<-J vv 1
0 . 003
0.001
0.001
0 . 00 1
0 . 00 1
0.003
0. 001
0. 001
0. 002
0. 002
0 . 003
0 .011
0.008
0.007
0 . 009
0.013
0 .015
0.019
0.034
0.084
0 .131
0. 002
0 . 005
0.034+-
0 . 000+-
0. OOOH
0. OOOH
0.009+-
0. 000 +-
0. OOOn
0 . 000+-
0. 002'H
0. 00 7 H
- _ .
O . OOOH
0. 006H
0. 00 8+ -
0. 000+-
0. OOOn
0. OOOn
0. 000+-
0. 000+-
0. OOOn
0. 009 +
0. 001+-
0. OOOn
0. 000+-
0. 000+-
0.004+-
0, 000+-
0. 189+-
0. OOOn
0.015+-
0. 000+-
0.606+-
0.601+-
0 .011 +-
0. 055n
0. 082
0 . 058
0. 024
0 . 1 25
0 .041
0 . 0 1 6
0 .011
0. 008
0. 006
0. ill 07
0. 008
0 . 0 1 9
0 . Oi~>8
0. 008
0. 005
O . (") O F!
i") o i ::;
*-' v' i ' '
0. 007
0. 009
0 . 0 1 1
0 . 0 1 4
0 . 0 1 6
0. 070
0. 049
0.043
0 . 060)
0.085
0. 096
0. 120
O "' 1 A
*' ^_ Jm ' '
O S41"1
*-' * 1~ j^
0. 840
0 . 0 1 6
0. 031
230
-------
SAMPLE ID: ATLANTIC METALS/SEC. ALUMINUM SMELTER - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: CC121 - Nuclepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
s
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MG
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.002+-
0.000+-
0 . 000+-
0. 000+-
0.0 00+-
0 . 000+-
0. 000+-
0 . 00 1 +-
0.0014
0. 000 H
0. OOOn
0 . 00 OH
0 . 00 1 +-
0.000+-
0 . 002+-
0 . 00 1 +-
O. 006+-
0.000+-
0 . 003-1
0.003+-
0. 00 0+-
0 . OOOH
0. OOO-i
0. 000 H
0.000+-
0.0 19+-
0 . 000+-
0. 002+-
0 . 003+-
0 . 000+-
0.090+-
0. 00 OH
O.OOOH
0 . 000+-
0.025
0.019
0.010
0.023
0.009
0.003
0 . 002
0.001
0 . 00 1
0.002
0. 002
0 . 004
0 . 00 1
0.002
0 . 00 1
0.001
0 . 004
0 . 00 1
0 . 002
0.002
0.003
0 . 003
0 . 0 1 4
0.010
0.009
0.012
0.01S
0 . 020
0.025
0.044
0. 110
0. 171
0 . 003
0.006
0.010+-
0.000+-
0. OOOH
0.000+-
0. 000+-
0.000+-
0.000+-
0 . 007+-
0.003+-
0. OOOH
0. 000+-
0 . 003+-
0. 005+-
0 . 000+-
0.015+-
0.004+-
0 . 039+-
0.000+-
0.019+-
0.022+-
0. 000+-
0. 000+-
0.000+-
0.000+-
0.000+-
0. 120+-
0 . 000+-
0.014+-
0.022+-
0.000+-
0.576+-
0. 000+-
0 . 000+-
0.000+-
0 . 1 60
0. 122
0.062
0. 145
0 . 060
0.019
0 . 0 1 4
0.009
0.006
0 .011
0.010
0.023
0 . 009
0.010
0 . 007
0.007
0 . 025
0 . 009
0 .014
0.015
0 . 0 1 9
0.021
0 . 089
0.067
0.057
0.076
0. 113
0. 12S
0 . 1 57
0 . 2S2
0.706
1 . 093
0.017
0. 041
231
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 1A
PARTICLE SIZE: C
ANALYSIS ID: AC03t - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED AREA: 6=42 SQUARE CM
MASS: 131+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
3
CL
K
CA
TI
V
CR
MN
FE
NT
CU
ZN
OA
AS
SE
BR
RB
C;p
Y
ZR
MO
PD
AG
CD
I H
SN
SB
BA
LA
HH-;
PB
1 . 431-1
2.094+-
0 . 22S+-
0.769+-
2. 849-1
1. 123+-
1.451+-
0 . 273+-
0. 002-1
0. 062-1
0. 026-1
0.47?+-
0 . 03 1 +-
0. 025+-
0.345+-
0. 006-i
0.0 16+-
0. 003 +
0. 037 +-
0. OOO-i
0 . 009'H
0 . OOOH
0 . 0 1 2n
0. 00 3 H
0. OOOn
0. 009+
0. 01S+-
0 . OOOH
0. 006-1
0 . OOO-i
0. 036+-
0. OOOH
O. OOO-i
0 . 29 9 H
0.
0.
0.
0.
0.
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
099
1 36
074
107
422
131
080
016
002
004
003
029
003
004
167
004
0 1 3
002
007
002
002
003
C) 1 0
007
006
009
0 1 5
0 1 3
022
031
076
121
003
065
o
1 3 .
1.
4.
13.
7.
9 .
1.
0.
0.
0 .
t;
0.
0.
5.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
1.
< ;^C;^
446+-
463+-
940+-
289+-
203+-
317+-
750+-
014+-
393+-
170+-
077-1
20 OH
163+-
424+-
033+-
101+-
020-i
236+-
00 1 H
06 1 +-
OOOn
OSO+-
016+-
00 IH
057+-
116+-
OOOn
042+-
000 H
233+-
00 OH
00 CH
923-i
0 .
0.
0.
0.
ji.
1.
0.
0.
0.
0.
0.
Q-
0.
0.
i.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
636
O-7--'
'_' / .i-
475
690
703
162
514
101
0 1 5
027
0 1 6
138
022
026
075
027
084
0 1 5
045
C> 1 3
014
020
065
044
039
059
093
083
140
196
437
776
0 1 8
417
6.
10.
1.
o
1 3 .
5.
7.
1.
0.
0.
0.
*^
0.
0.
4.
0.
0.
0.
0.
0.
0.
O
0.
0.
0.
0.
0.
o
0.
0.
0.
(-,
o
1.
O'Ol'i-l
230 +
1 1 3+-
75S+-
914+-
433+ -
088 +-
331+--
0 1 IH- -
303+-
1 29+-
34 1 +-_
152+-
124+-
126+-
029+-
077+-
0 1 5+-
179+-
00 1+
O4 AH
OOO + -
061+-
012+-
00 1 +-
044+-
03S+-
OOOn
032 H
OOOH
177+-
OOOH
OOOH
463+-
0 . 7 1 9
1 . 023
0 . 37 1
0 . 593
2 . 3 1 6
0 . 9 7 7
0. 666
0. 127
0 .Oil
0. 031
0 . 0 1 6
-0 . 223
0 020
0. 022
0.376
0 . 02 1
0. 064
0 .012
0. 037
C) . 0 1 0
0 .012
0 .015
0 . 050
0 . 034
0.029
0 . 045
0.071
O . O/-.3
0. 107
0. 149
0 .371
0 . 590
(-) o 1 4
'..' -' -L ~
0 . 336
232
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 1A
PARTICLE SIZE: F
ANALYSIS ID: AF176 - Teflon
EXPOSED AREA: 6.42 SQUARE
MASS: 1016+- 10
CM
MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
F'
!~i
CL
K
CA
TI
V
CR
MM
FE
NI
CLI
ZN
GA
AS
SE
BR
RE
SR
V
I
ZR
MO
PTi
p u
AG
CD
IN
SN
SB
BA
LA
HG
PB
2.
4.
1.
6.
42.
IS.
0.
0.
0.
0.
0.
0.
0.
0.
IS.
0.
0.
0.
0.
0.
0.
o
».*
0.
0.
O~
0.
0.
0.
0.
0.
0.
0.
0.
7.
520+-
640+-
183+-
091+-
1 37+-
633+-
433+-
087+-
009+-
029+ -
039+-
417+-
050+-
236+-
804+-
023+-
025+-
003 + -
644+-
031 + -
013+-
OOOn
04S+-
000+-
(-)O -j J
V^*1 A '
035+-
412+-
000+-
998+-
264+-
000+-
000+-
0 1 7+-
V . ^I .^J -r
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(-)
*'
0.
0.
()
V .
0.
0.
0.
0.
0.
0.
0.
0.
0.
179
215
216
393
909
363
06 1
006
002
002
003
022
004
012
856
015
033
010
03 1
004
003
009
016
007
Of) 7
*.' *.' f
0 1 0
030
015
056
042
030
131
006
332
16.
29-
7.
39.
270.
119.
o
«* .
0.
0.
0.
0.
2.
0.
1.
120.
0.
0.
0.
4.
0.
0.
0.
0.
0.
o
*.' B
0.
2.
0.
6.
1.
0.
0.
0.
46.
130+-
7S7+-
629+-
103+-
517+-
626+-
132+-
556+-
057+-
189+-
24*+-
680+-
323+-
512+-
720+-
147+-
157+-
016+-
136+-
199+-
084H
OOO-i
308+-
000+ -
1 QQH
A .
227+-
644+-
000+-
408+-
692+-
000+-
000+-
103+-
437+-
1.
1.
1.
'".»
12.
5.
0.
0.
0.
0.
0.
0.
0.
0.
s'
' '
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
jL.
147
- II -.
-."-' -.0
333
533
'~IC=I'~'
=;;-;;;;
339
037
0 1 0
015
017
141
025
073
496
094
243
067
200
026
020
059
105
048
043
065
190
094
362
263
512
340
033
123
1.
-i
0.
-i
o .
26.
11.
0.
0.
0.
0.
0.
0.
0.
0.
11.
0.
0.
0.
0.
0;
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
593+-
933+-
751+-
850+-
637+-
779+-
303+-
.055+-
006 + -
019+-
024 + -
2A4H
032+-
149+-
337+-
014+-
015+-
002n
407+-
02 OH
003+ -
OOfJH
030+-
000+-
020-i
022+-
260 +-
OOO-i
631+-
1 67+-
00 OH
OOO-i
011+-
573+-
0.114
0. 139
0, 137
0 . 252
1 . 235
0 . 553
0. 033
0 . 004
(j . 00 1
0. 002
0. 002
0 .014
OV003
0 . 008
0 .554
0 . 009
0.024
0. 007
0. 020
0 . 003
0. 0
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 2A
PARTICLE SIZES C
ANALYSIS ID: AC037 - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASSs 220+- 10 MICROGRAMS
ELEMENT
AL
SI
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
V
ZR
MO
PD
AG
CD
IN
SN
SE
BA
LA
HO
PB
UG/CM2
1.
O
0.
1.
4.
1.
*_'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 »
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
730+-
345+-
297+-
255+-
511+-
377+-
349+-
33 1 +-
003H
070+-
023+-
645+-
034 +
028-f
915+-
000+-
OOOn
002 -<
030+
002-i
0 1 5+-
OOOH
017+-
002+-
000+-
OOO-i
02 1 +-
009+-
032+-
035+-
025+-
OOO-i
009n
545+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
119
146
099
1 66
662
.-, ., .-,
J^-Zfji,
131
0 1 9
003
005
003
040
004
006
210
006
020
005
006
002
003
005
0 1 2
OOS
007
0 1 0
017
015
030
0:36
033
129
004
1 39
11.
15.
1.
(-,
C< a
"'C'
o
15.
Ji! H
0.
0.
0.
4.
0.
0.
e-
0.
(")
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
«' .
UG /FILTER
425+-
052+-
90 6n
060+-
953+-
S40+-
OS2+-
123+-
02 1 +-
450+-
179+-
142+-
219+-
173+-
874+-
OOOn
f)O(~H
012+-
190+-
011+-
095n
OOi'iH
110+-
013+-
001+-
OOO-i
137+-
056+-
206+-
223+-
153+-
000+-
057+-
497+-
o.
o.
n.
1.
4.
1.
0.
0.
0.
0.
0 .
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
761
937
639
063
252
439
344
121
017
031
0 1 8
254
024
036
349
033
130
029
0:33
0 1 4
017
030
077
049
044
062
106
095
192
231
530
!-i '"' !-!
026
890
5.
6.
0.
O
13.
4.
6.
0.
0.
0.
0.
1.
0.
0.
f"^
O
0.
o«.
0.
0.
0
o .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
PERCENT
191+-
333H
366+-
662+-
1 56+-
016+-
852+-
964+-
010-i
204 +-
082-t
882+
099+-
031+-
663+-
OOO-t
OOO-i
006-1
036+ -
005-1
043-f
000+
050-1
006 +-
00 OH
000+-
062+-
025+-
094+-
103+-
072+-
00 OH
026+-
539+-
0.
0.
0.
0.
.fal B
0 .
0.
0.
0.
0.
0-.-
0.
0.
0.
0.
(")
0.
0 .
0.
0.
0.
(-)
v-'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
413
527
2 9 3
513
022
701
494
070
00:3
017
009
144
012
017
,':.ocr;
O17
059
0 1 3
0 1 8
007
003
("1 1 4
\.J J. ~
035
022
020
023
043
043
038
105
241
376
0 1 2
411
234
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 2A
PARTICLE SIZE: F
ANALYSIS ID: AF177 _ Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1579+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UC/FILTER
PERCENT
AL
SI
P
c-
»
CL
K
CA
TI
V
CR
MN.
FE
Nl
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SIM
SB
BA
LA
HG
PB
o .
4.
1.
7.
65.
24.
1.
0.
0.
0.
0.
0.
0.
0.
24.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.^l
0.
0.
0.
0.
16.
29S+-
225+-
673+-
147+-
910+-
030-1
OOS+-
114+-
020+-
040+-
059+-
784+-
065+-
433+-
505+-
025+-
034+-
000+-
405+-
047+-
025+-
OOO-i
000+-
QOO+-
084+-
051+-
605+-
039+-
145+-
537+-
054+-
174+-
000+ -
296+-
0.
0.
0.
0.
o .
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 39
197
304
691
050
120
099
007
002
003
004
039
005
021
115
024
071
023
026
005
006
019
031
012
012
015
041
021
1 1 0
064
112
131
0 1 0
744
21.
27.
10.
45.
423.
154.
6.
0.
0.
0.
0.
5.
0.
2.
157.
0.
0.
0.
. ,
0.
0.
0.
0.
0.
0.
0.
.-,
-'
0.
13.
3.
0.
1.
0.
104.
174+-
12S+-
740+-
583+-
142+-
273+-
470+-
735+-
123+-
254+-
332+-
036+-
415+-
3 1 1 +-
320+-
163+-
216+-
000+-
599+-
30 1 +-
153+-
000+-
000+-
000+-
53S+-
330+-
SS2+-
247+-
774+-
450+-
344+-
119+-
000+-
623+-
1.
1.
1.
4.
19.
7.
0.
0.
0.
0.
0 .
0.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
4.
210
263
949
434
534
137
634
047
015
020
025
249
03 1
133
160
154
454
149
1 66
035
037
1 23
202
076
073
094
263
133
705
414
722
165
062
773
1.
1.
0.
7,
26.
9.
0.
0.
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
34 1 +-
71S+-
630+-
906+-
30 O-i
771+-
410+-
047+-
003+ -
016+-
024+-
319+-
026+-
173+-
964+-
010+-
014+-
000+-
165-.
019+-
010+-
000 H
OOO-i
OOO-i
034+-
021+-
246+-
016+-
372+-
219+-
022+-
07 1 +-
00 OH
626+-
0.077
0.031
0. 124
0 . 23 1
1 . 252
0.459
0 . 04 0
0 . 003
0. 001
0 . 00 1
On "00 2
0 . 0 1 6
('; _ (")'.") 2
0. 009
0. 458
0 . 0 1 0
0. 029
0. 009
0.011
0. 002
0. 002
0 . 008
0.013
0. 005
0.005
0.006
0.017
0 . 003
0. 045
0 . 026
0. 046
0.074
0. 004
0 . 305
235
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 2B
PARTICLE SIZE: C
ANALYSIS IDs ccioi - Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
16S+- 10 MICROGRAM:;
ELEMENT
UG/CM:
UG/FILTER
PERCENT
AL
SI
P
C-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
1.
0.
0.
1.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
431+-
815+-
159+-
395+-
850+-
433+-
190+-
254+-
002+-
06 1 H
021+-
515+-
023+-
005+-
00 H
002-i
016-1
001+-
015+-
000-t
007+-
006+-
00
14.
1.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(I).
0.
187+-
655+-
021+-
745+-
879+-
777+-
059+-
632-i
014+-
394-t-_
135+-
30S+-
149+-
031+-
009-1
014+-
100+-
006 +-
09 9+
OOO-i
047+-
039+-
OOO-i
112+-
023+-
000-t
000+-
007+-
OOO-i
242+-
498+-
OOO-i
075+-
OOO-i
0.
0.
0.
0.
*"'
%_' m
1.
0.
0.
0.
0.
0.
0'.
0.
0.
1 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
0.
0.
667
7S7
515
999
898
365
772
096
015
029
017
213
021
033
244
035
1 19
027
037
0 1 8
021
032
096
070
052
OSS
127
1 30
206
303
724
123
029
SO 6
r
_'
6.
0.
"!
7.
1.
.3
0.
0.
0.
0.
1.
0.
0.
O
0.
(")
0.
0.
O
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
o
0 .
0.
476+-
947+-
60S+-
424+-
080+
655+-
380+-
973+-
009+-
235+-
080 -i
971-t
089-t
019+-
OO5+-
008-1
O/-.OH
004+
059-1
O OO-t--
028+-
023+-
000+-
066+-
014+-
OOOn
OOOn
004 +-
OO OH
144+-
297+-
OOO-l
045+-
OOO-i
0.514
0.626
0. 309
0 . 629
2.361
0 . 8 1 9
0.679
0. 081
0. 009
0.022
0.011
0. 173
0 .014
0 . 0 1 9
0. 742
0.021
0 . 071
0 . 0 1 6
0.022
0 .011
0 . 0 1 3
0 . 0 1 9
0 . 057
0.042
0.031
0 . 05 1
0 . 075
0 . 077
0 . 12 3
0. 1S1
0 . 432
( > . 669
( > . 0 1 3
( ) . 4SO
236
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 2B
PARTICLE SIZE: F
ANALYSIS ID: AF17S - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1672+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
3
CL
K
CA
TT
1 J.
V
CR
MN
FE
NI
CU
ZN
GA
AS
Cjpr
BR
RE
SR
Y
T
7q.
L r>
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
FB
*'
'
4.
1.
tm.t
74.
26.
0.
0 .
0.
0.
0.
0.
0.
0.
27.
0.
0.
0.
0.
0.
0.
O
*»' .
(-)
V.'
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
IS.
2 ft'~H
552+-
830+-
574+-
002+-
774+-
301+-
1 OC'H
016+-
038+-
060+-
774+-
073+-
493+-
144+-
043+-
053n
006-1
445+-
062+-
031+-
(";(") f"H
v_* ».* ** *
("H"K")+
V V.' V.' ^^
084+-
073+-
077+-
664+-
010+-
332+-
517+-
081+-
OOO-i
040H
033 +-
0.
0.
0.
0.
J*
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
(-)
*'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
194
213
34 1
776
407
246
097
007
002
003
004
03:3
005
024
2:~;rr;
026
077
026
023
006
006
021
035
0 1 3
012
016
044
022
119
067
121
191
Oil
323
21.
29.
12.
55.
475.
171.
5.
O
*'
0.
0.
0.
4.
0.
'' *
174.
0.
0.
0.
'T-'
0.
0.
0.
0.
0.
0.
0.
4.
0.
14.
^i
'
0.
0.
0.
115.
1 1 3+-
224+-
067+-
044+-
092 +-
892+-
143+-
642+-
1 00+-
243-!
385+-
972+-
472+-
196+-
262+-
27S+-
372+-
035+-
856+-
;-;ir,"p + _
1 97+-
000 + -
00 OH
540+-
470+-
496+-
260+-
067+-
972+-
320+-
519+-
000+-
255+-
771+-
1.
1.
2.
4.
21.
(~i
0.
0.
0.
0.
0.
0.
0.
0.
-7
/ .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
o
er
_ .
243
365
1 39
98:2:
375
002
623
043
014
020
025
247
034
155
930
169
493
165
1 33
040
040
135
^ --t ->
030
078
105
283
139
762
423
777
223
(')*:=:
t "*! C"
^1 l~. . 1
1
1
o
t;
T"C<
10
o
o
0
o
0
0
0
o
10
o
0
o
0
0
0
o
o
0
0
o
0
0
0
o
0
o
o
6
. 263+-
. 748+-
.722+-
. 292+-
.411+-
. 279+-
.-308+-
, 038+-
. 00 6-f
.015+-
. 023 +-
. 297+-
. 023+-
. 191+-
.421+-
.017+-
. 022+-
. 002+-
."l71+-
. 024+-
.012+-
. OOOn
. OOOH
. 032+-
. 023+-
. 030+-
. 255+-
. 004+-
. 395+-
. 199+-
.031+-
. OOOn
. 015+-
. 923+-
0.075
0.032
0. 131
0.299
1.319
0. 432
0 . 037
0. 003
0. 001
0. 001
QUO 02
0 . 0 1 5
0. 002
0. 009
.0.478
O . O 1 O
0.030
0 . 0 1 0
0 . 0 1 1
0. 002
0. 002
0 . 008
0 . 0 1 3
0. 005
0.005
0 . 006
0 .017
0.003
0.046
0.026
0.046
0.073
0. 004
i :> . 3 1 9
237
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 3A
PARTICLE SIZE: C
ANALYSIS ID: AC033 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 287-1 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
*~i
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
'*d
4.
0.
1.
S.
-.
' f
0.
0.
0.
7.
0.
0.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
4.
5 1 0+-
823+-
911+-
181+-
331+-
717+-
946+-
233+-
100+-
317+-
103+-
325+-
193+-
177+-
009+-
049+-
00 3+-
366+-
026-i
089+-
OOO-i
161 +-
OOO-i
OOO-i
029-1
1 39+-
OS5+-
133+-
563+-
229+-
377+-
120+-
226+-
1.
1 =
0.
1.
7.
1.
1.
0.
0.
0.
0.
Q.
0.
0.
1.
0.
0.
0.
o .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
''' ";"'
576
9S2
520
362
9S3
062
199
025
035
025
450
031
044
826
047
155
037
069
0 1 7
018
036
081
043
041
063
124
092
224
257
517
792
032
170
6.
9.
1.
~'
18.
4.
6.
1.
n
0.
0.
">
0.
0.
2.
0.
0.
0 .
0.
"o.
0.
0.
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
457+-
008+
016+-
552+-
OSO-i
735+-
609+-
12S+-
rr?s+-
1S7+-
110+-
47S+-_
113+-
067+-
504+-
003-t
017+-
OO 1 H
123+-
009+-
031+-
000+
ri=;A+-
000 H
000+-
0 1 OH
04S+-
03 OH
047+-
197+-
OSO-i
43 OH
042+-
474+-
0 . 435
0.633
0.345
0 . 54 5
2.645
0.71 2
0.436
0. 080
0. 009
0 ., 0 1 4
0 . 0 1 0
p. 179
0 .011
0 . 0 1 6
0 . 643
0 . 0 1 6
0.05-1
f) m ("j 1 3
0 . 025
0. 006
0 . 006
(') (') 1 ";
*-' *.-' i '
0 . 023
0 . 0 17
0 . 0 1 4
0.022
0.043
0.032
0.073
0. 090
0. 180
0.277
0 .011
(') .411
238
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 3A
PARTICLE SIZE: F
ANALYSIS ID: AF179 - Teflon
VERY HEAVY DEPOSIT-^ NON-UNIFORM
EXPOSED AREA: 6.42 SQUARE CM
MASS: 2783+- 10 MICROGRAMC
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
o
OL
K
CA
TI
V
CR
MN
FE
IMI
CU
ZN
GA
AS
SE
BR
RB
SR
y
ZR
MO
PD
AG
CD
TM
± 1 «t
SN
SB
BA
LA
HG
PB
6.
7.
2.
14.
113.
30 .
1.
0.
0.
0.
0.
'*l!
0.
0.
10
..' ' .
0.
0.
0.
0.
0.
0.
()
*-' *
0.
0.
0.
0.
1.
o
*»'
3.
1.
0.
0.
0.
21.
046+-
122+-
615+-
380+-
460+-
233+-
089+-
194+-
030+-
056+-
092+-
083+-
099-*
611+-
921+-
052+-
013+-
005+-
962+-
077+-
039+-
00 OH
000+-
132+-
099+-
096+-
139+-
OOO-t
_' V *' l
092+-
082+-
233+-
OOOH
000+-
852+-
0.
0.
0.
1.
5.
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
347
329
474
033
217
412
125
Oil
003
004
005
09S
006
029
543
032
090
03 1
050
007
Q07
025
040
014
013
017
065
024
153
OSS
126
196
012
;97
33.
45.
16.
92.
723.
194.
6.
1.
0.
0.
0.
13.
0.
o
217.
0.
0.
0.
6.
0.
0.
Ci
0.
0.
0.
0.
7.
0.
19.
6.
1.
0.
0.
1 40 .
317+-
720+-
739+-
317+-
412+-
098+-
991+-
248+-
193+-
357+-
589+-
373+-
634+
922+-
770+-
331+-
115+-
035+--
173+-
495+-
250+-
OOOn
000+-
S45+-
635+-
618+-
3 1 0+-
000+-
353+-
945+-
493+-
000+-
000 +-
237+-
. ,
jL.
^_
'"Z'
' H
6.
33.
9.
0.
0.
0.
0.
".
n.
().
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
6.
230
114
045
629
492
065
802
073
0 1 9
025
034
630
041
183
907
203
578
1 99
"J22
043
047
162
260
089
086
111
414
155
933
567
812
-i=;C|
077
40 1
1.
1.
0.
3.
26.
6.
0.
0,
0.
0.
0.
0.
0.
0.
7.
0.
0.
0.
0.
0".
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
395+-
643+-
60 3 H
317+-
170+-
974+-
251+-
045+-
007+-
013-1-
021+-
43 OH
023+-
14J+-
824+-
012+-
004+-
001 +-
222'H
013+-
009+-
OOO-i
000+--
OSO-i
023+-
022+-
263+-
000+-
713+-
250+-
054+-
OOO-i
00 OH
040+-
0 . 030
0.076
0. 109
0.23S
1 . 207
0 . 327
0 . 029
0.003
0.001
0. 001
0,001
0 . 023
0 . 00 1
0. 007
0.357
0.007
0 . 02 1
0 . OO7
0 .012
0.002
0 . 002
0 . 006
0. 009
0 . 00:?
0.003
0.004
0.015
O . (")!")/-.
0.035
0 . 020
0 . 029
0.045
0. 003
0 .231
239
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 4A
PARTICLE SIZE: C
ANALYSIS ID: AC039 - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED AREA: 6.42 SQUARE CM
MASS: 123+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
i~-
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
3R
V
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
*i!
0.
0.
o
> o
0.
1.
Go
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
646+-
303+-
176+-
593+-
233+-
906+-
023+-
138+-
OOC'H
037 + -
013+-
401+-
042+-
019+-
376+-
(")(") ("H
COS -i
004-i
02 OH
O02'-i
002-t
00 OH
003-i
00 OH
OOO-i
OOO-i
028+-
OOO-i
028 +-
024-i
215+-
263-1
006 -f
501+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
o.
o.
o.
U.
0.
0.
0.
0.
0.
0.
0.
0'.
0.
0.
0.
084
1 36
062
110
434
1 33
060
012
002
003
002
026
004
004
147
OO5
0 1 6
(Vf-;
OO5
002
002
004
Oil
007
006
009
015
014
025
033
03:3
122
004
095
4.
14.
1.
3.
21.
e°
6.
0.
0.
0.
0.
4^.
0.
0.
C|
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
"3
147+-
7S3+-
133+-
310+-
077+-
817+-
566+-
336+-
OOO-i
239+-
117+-
577+-
271+-
123+-
623+-
000 +
050-f
026+-
130+-
014+-
014+-
OOO-i
022+-
000+-
OOO-i
OOO-i
132+-
000-t
181+-
152+-
379+-
688+-
03 6+-
220+-
0.
0.
0.
0.
*^»
J^,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
539
376
399
704
736
352
:"::-;:-:
077
014
020
014
165
026
025
941
029
105
02 1
032
0 1 3
014
024
063
045
033
058
095
037
153
2 1 3
530
734
023
611
«'
11.
0.
. i
16.
4.
C|
0.
0.
0.
0.
2 m
0.
0.
4.
0 .
0.
0 .
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
^
234+-
533+-
383+-
971+-
438+-
537+-
120+-
691+-
000-t
136+-
091+-
010+-=-
211+-
09 6 H
335+-
QQ(-jj
039-1
O'"''l H
v>' j J. '
1 0 1 +-
011+-
0 1 1 +-
OOOn
017+-
000+-
000+-
OOO+-
142+-
OOO-i
141+-
118+-
076+-
3 1 6+-
023+-
511+-
0.490
1. 129
0 .319
0. 596
'"' 5 '"' '";
0.753
0.501
0.031
0 .011
0 . 02 1
0 . 0 1 3
-0. 203
0. 026
0 . 02 1
0 . 3 1 0
0 . O 2 3
0 . 082
(") 0 1 7
l-' l..' iL /
0.026
0 . 0 1 0
0 .011
0 . 0 1 9
0. 053
0.035
0.030
0.045
0.075
0. 063
0. 124
0. 167
0 . 422
0 . 620
0 . 0 1 3
0.515
240
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 4A
PARTICLE SIZE: F
ANALYSIS ID: AF1SO - Teflon
NOIM-UNIFORM DEPOSIT
EXPOSED AREA: 6.42 SQUARE CM
MASS: 1028+- 10 MICROGRAMS
Test No. 4
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
If
CL
K
CA
TI
V
CR
MN
FE
IMI
CU
Z!M
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
i LJ
AG
CD
IN
SN
SB
BA
LA
HG
PB
6.
->
J^ m
1.
4.
40.
12.
0.
0.
0.
0.
0.
0.
0.
o.
13.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
v
0.
0.
0.
1.
0.
0.
0.
0.
10.
557+-
967+-
1 06+-
461+-
839+-
739+-
573+-
070+-
0 1 3+-
032-1
032+-
480+-
056+-
259+-
620+-
014+-
000+-
027+-
332+-
028+-
016+-
000+-
000+-
070+-
030H
027+-
330+-
008+-
324+-
399+-
120+-
000+-
010+-
362+-
0.317
0. 140
0.201
0.430
1 . S3 3
0.597
0 . 053
0.005
0.002
0.003
0.003
0.025
0.004
0 . 0 1 3
0.711
0 . 0 1 6
0 . 050
0 .015
0.021
0.004
0.004
0.013
0 . 023
0.011
0 . 0 1 0
0.014
0.030
0 . 020
0.073
0 . 059
0.112
0. 176
0. 007
0.474
42.
19.
7.
23.
262.
81.
3.
0.
0.
0.
0.
o m
0.
1 .
100.
0.
0.
0.
^
0.
0.
0.
0.
0.
0.
0.
2.
0.
8.
2.
0.
0.
0.
66 .
099+-
046+-
099+-
639+-
1S3+-
784+-
6S1+-
449+-
086+-
205+-
202+
080+-
358+-
662+-
27S+-
08S+-
000+-
176+-
455+-
179+-
105+-
000+-
000+-
450+-
1 93+-
171+-
116+-
053+-
493+-
559+-
773+-
000+-
063+-
525+-
j^
0.
1.
">
4^
12.
3.
0.
0.
0.
0.
0.
0.
0.
0.
4,
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
.-.
'
036
396
290
764
092
333
374
033
012
018
01S
160
02S
035
567
1 03
3 1 9
096
137
023
023
032
147
073
064
033
192
123
470
380
721
129
046
043
4.
1.
0.
2.
25.
7.
0.
0.
0.
0.
0.
0.
0.
0.
9_
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
096+-
C;cr't;4._
69 1 +-
787+-
510+-
9574 -
358+-
044+-
003H
020-)-
020+-
300-1
035+-
162+-
757+-
009'H
000+-
OJ. 7+-
239-1
017+-
010+-
OOO-i
000+-
044-H
019+-
017+-
206+-
005-I--
827+-
249+-
075+-
000+-
006-1
473+-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
202
039
126
270
202
331
037
003
001
002
002
0 1 6
003
Of-)fi
454
0 1 0
031
009
014
003
003
003
0 1 4
007
OO,'-,
009
0 1 9
0 1 2
046
037
070
110
004
303
241
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 4B
PARTICLE SIZE: C
ANALYSIS ID: CC102 - Nuclepore
EXPOSED AREA:
MASS:
6.42 SQUARE CM
105+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
C;
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HO
PB
1.
£_ m
0.
0.
7."
0,
I.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 06+-
063+-
137+-
673+-
774+-
692+-
234+-
203+-
OOS-i
03S+-
015+-
419+-
033+-
013+-
524+-
003+-
000 +-
008 +-
01?+-
003-i
00 6 H
000+-
000 H
000+-
016+-
000+-
0 1 7+-
012+-
010+-
030+-
OOO-i
000+-
QOS-i
255+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0*
Oo
0.
0.
OS3
126
05S
119
473
1 43
072
012
002
003
002
027
004
004
155
005
017
004
006
OH) 3
003
005
015
Oil
OOS
013
020
020
031
047
109
173
004
101
7.
13.
0.
4.
17.
4.
3.
1.
0.
0.
0.
-..
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
101+-
276+-
377+-
319+-
SOS+-
443+-
245+-
304+-
049+-
241+-
099+-
692+-
20 9+
OS 1 +-
365+-
021+-
000+-
049-i
123+-
022+-
036+-
000+-
000+-
00 OH
106+-
000+
103+-
07S+-
066+-
193+-
OOO-i
000+
053+-
637+-
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
535
306
374
767
035
9 1 5
464
07S
015
022
014
173
024
026
997
03 1
107
024
037
0 1 3
021
029
093
069
054
034
126
130
196
300
699
107
027
646
6.
12.
0.
4.
17.
4.
7.
1.
0.
0.
0.
o
jl. «
0.
0.
-1J
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
1.
734+-
&P4+-
333 H
127+-
014+-
245+-
37S+-
246+-
047+-
230-1
095+-
572+~-
200-i
077+-
215+-
020-(
000 H
047+-
117+-
021+-
035-i
OOO-i
OOO-i
000+-
1 0 1 +-
OOOn
103+-
075+-
063+-
134+-
OO(")H
OOO-i
05 1 -i
564+-
0.325
1 . 436
0.366
0 . 332
3.324
0.964
0.374
0. 140
0 . 0 1 5
0. 030
0 . 0 1 6
0.296
0 . 030
0 - 026
1 . 00 1
0 . 029
0. 102
0.023
0.037
O.ol?
0 . O20
0.023
0. o39
0 . L>66
0.053
0 . 030
0. 121
0 . 1 25
0. 137
0 . 237
O. A/-.R
1 . 053
0.026
0.635
242
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 4B
PARTICLE SIZE: F
ANALYSIS ID: AF1S1 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
1143+- 10 MICROGRAM:;
ELEMENT
UO/CM2
UG/FILTER
PERCENT
AL
SI
F
\~t
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PE
2.
"T-*
1.
C1
-' .
49.
13.
0.
0.
0.
0.
0.
0.
0.
0.
IS.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
12.
267+-
907+-
207-t
443+-
623+-
330+-
457+-
05S+-
012+-
029+-
036+-
521+-
053+-
290-1
927+-
023+-
007+-
027+-
456+-
039-i
015+-
000+-
000+-
000+-
040+-
031+-
549+-
004+-
643+-
5364
076+-
000+-
024+-
531+-
0.
0.
0.
0.
-,
.*. .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
150
137
219
523
-.pC;
721
062
005
002
003
003
027
004
015
362
019
057
013
025
005
005
015
026
Oil
Oil
014
039
020
033
065
115
1 30
003
573
14.
IS.
7.
34.
-. 1 C'
-' 1 '_'
98.
o
JM-
0.
0.
0.
0.
"Z*
*'
0.
1.
121.
0.
0.
0.
.ti.
0.
0.
0.
o
0.
0.
0.
*^'
0.
10.
3.
0.
0.
0.
30 .
554+-
664+-
746+-
945+-
612+-
740+-
932H
371+-
073+-
134+-
234+-
344+-
373+-
S60+-
509 H
146+-
045+-
175+-
923+-
249+-
094+-
000 +
OO OH
000+-
257+-
200+-
526+-
025+-
533+-
443+-
490+-
000+-
152+-
449+-
0.
0.
1.
0
14.
4.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
-'
965
379
407
'-!!:ll-!
636
/ '"' /-.
399
030
012
017
019
172
029
094
532
122
T'/C '
*> ,
116
163
032
03 1
097
1 63
073
06:3
09 1
249
131
563
413
733
154
053
677
1
1
0
;*»
->-7
A. /
o
-.'
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
. 273+-
. 632+-
. 673+-
. 056+-
. 367+-
. 636-1
. 256+-
. 032+-
. 007+-
.016+-
. 020+
. 292+-
. 033+-
. 1 63+-
. 623+-
.013+-
. 004+-
.015+-
.2:56+-
. 022-1
. 003+-
. 000 +-
. 000+-
. 000+-
. 022+-
.017+-
. 30S+-
. 002+-
. 926+-
.301+-
. 043+-
. 000+-
. 0 1 3+-
. 036+-
0.035
0.073
0. 123
0.293
1 . 307
0.41 2
0. 035
0 . 003
0. 001
0 . 002
0. 002
o7o 1 5
0. 003
0 . 003
0 493
0 . 0 1 1
0 . 032
0 . 0 1 0
0 . 0 1 4
0 . 003
0. 003
0. 009
0 . 0 1 5
0 . 006
0 . 006
0 . 006:
0.022
0 .011
0. 050
0 . 037
O. OA5
0. 101
0 . 005
0 .327
243
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 5A
PARTICLE SIZE: C
ANALYSIS ID: AC046 - Teflon
EXPOSED AREA: 6.42 SQUARE CM
MASS: 313+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
p
s
CL
K
CA
TI
v
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER-
RS
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
2.339+-
4. 175+-
0.436+-
1 699+-
8. 125+-
2. 133+-
2. 360+-
0. 535+-
0.01 2+
0. 054+-
0.044+-
0.9 13+-
0. 042+-
0.026+-
1 . 955+-
0. OOOn
0. OOO-i
0. 002n
0. 133+-
0. 002+
0 .011 +-
0. 000 H
0 . 000+-
0. 002+-
0 . 000+-
0. 00 OH
0.0 12+-
0. 000+-
0 . 002+-
0. 042+-
0. 000+-
0 . 000+-
0. 005+-
1. 133+-
0 . 203
0.250
0. 145
0 . 233
1 . 023
0.304
0. 162
0 . 029
0. 004
0 . 004
0 . 004
0.056
0.005
0 . 007
0.443
0.011
0 . 035
0.01 0
0 . 027
0. 004
o . o<".> 4
0.009
0 . 0 1 9
0.011
0 .010
0 .013
0. 024
0.021
0.043
0.055
0.11 3
0. 174
0.006
0 . 306
IS. 224+-
26 . 305+-
2.796+-
10.907+-
52. 164+-
14.043+-
13.359+-
3.432+-
0. 075+-
0. 343+-
0.235+-
5.363+-
0. 266+-
0 . 1 67+-
12.543+-
0 . 00 OH
0. 000 H
0. 010+
1. 174+-
0. 016+-
0.071+-
0. 000+-
0.000+-
0. 010+-
0. 000+-
0.000+-
0.075+-
0 . 00 OH
0 . 0 1 3+-
0.269+-
0. 000+-
0. 000-t
0. 035+-
7 . 595+-
1 . 337
1 . 604
0.932
1.347
6.599
1 . 950
1 . 037
0. 136
0. 024
0.027
0 . 025
0 . 353
0 . 030
0.046
2.342
0.069
0.222
0. 062
0. 174
0 025
0. 025
0 . 057
0.121
0.071
0.062
0 . 0:36
0 . 1 54
0 . 1 34
0 . 273
0.354
0.753
1. 119
0.033
1 . 965
5.S27+-
3.570+-
0. 394+-
3.437+-
16.673+-
4 . 49 1 +-
5. 370+-
1 . 097+-
0. 024 H
0 . 1 1 1 +-
0 . 09 1 +-
1.374+-'
0.035+-
0.053+-
4.012+-
0. 00 OH
0. OOO-i
O. (")('):-:-!
0. 00 5 H
0.023+-
0 . OOOn
0. OOO-i
0. 003 +
0. 000+
0. 000+-
0.024+-
0. 000+-
0.004+-
0 . 036+-
0 . 000-f
0. 000 H
0.011+-
2.423+-
0. 466
0. 531
0 . 299
0 60 1
.2. 176
0. 640
0 . 33 1
0 . 069
O . O (");=!
0. 00'?
0. 003
0. 129
0 . 0 1 0
0 .015
0.913
0.022
0.071
0.020
0 .057
('). OOP:
0 . 003
0 . 0 1 3
0 . 039
0 . 023
0. 020
0 . 027
0.049
0. 043
0 . 039
0.11 3
0.242
0.353
0 .012
0 . 633
244
-------
SAMPLE ID: E.C. INCINERATOR - TEST NO. 5A
PARTICLE SIZE: F
ANALYSIS ID: AF132 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
2332+- 10 MICROGRAM
ELEMENT
UC/CM2
UG/FILTER
PERCENT
AL
SI
F'
o
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
-j
w
6.
**i
*H "
3.
95 .
29.
1.
0.
0.
0.
0.
1.
0.
0.
51.
0.
0.
0.
V ^
0.
0.
0.
0.
0.
0.
0.
1.
0.
3.
1.
0.
0.
0.
36.
676+-
475+-
437+-
559+-
619+-
019+-
003+-
054+-
OOOn
063+-
032+-
253+-
144+-
664+-
642+-
071+-
000+-
014+-
529+-
073+-
040+-
000+-
000+-
163+-
252+-
000+-
275+-
151+-
720+-
9S4+-
507+-
039+-
039+-
433+-
0.
0.
0.
1.
4.
1.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
523
299
442
t'=;--
_ -_' --»
411
36-1
1 36
012
003
004
005
060
009
032
349
050
1 40
052
122
0 1 1
0 1 1
041
064
015
020
019
070
025
132
125
130
193
017
661
23.
41.
15.
54.
613.
136.
6.
0.
0.
0.
0.
o
' ' *
0.
4.
33 1 .
0.
r>
0.
16.
0.
0.
0.
0.
1.
1.
0.
3.
0.
-'O
^-' .
1 "!'
l^i. .
-:>
' '
0.
0.
.-,.-,,-,
603+-
571+-
643+-
947+-
375+-
30 1 +-
441+-
350+-
000+-
435+-
527+-
043+-
927+-
262+-
540+-
455+-
OOfn
09 OH
233+-
463+-
257+-
00 OH
000+-
045+-
617+-
OOOn
132+-
971+-
334+-
737+-
254+-
573+-
253+-
934+-
'"[
1.
.-,
Ji.
O *
~. .~.
*!'-'
' '
0.
0.
0.
0.
0.
0.
0.
0.
15.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
0.
10.
353
920
333:
634
3 1 6
755
373
076
019
027
032
337
055
204
073
3 1 3
90 1
33 1
~T'i~\'~-j,
063
069
263
403
095
127
120
452
164
1 66
304
PI '"!/-.
263
109
665
0.
1.
0.
1.
21.
6.
0.
0.
0.
0.
<).
".
u.
0.
11.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
'_'
319+-
442+-
543+-
906+-
299+-
464+-
223+
012+-
000 + -
015+-
018 + -
279+-
032+-
143H--
503+-
016+-
000+-
003n
563+-
016+-
009+-
00 OH
00 OH
036+ -
056+-
000+-
234+-
034+ -
329H
442+-
113+-
02 OH
009n
116+-
0. 117
0 . 067
0.093
0.301
0 . 935
0 . 305
0. 030
0. 0(1)3
0 . 00 1
0. 001
0 .-00 1
0.013
0. 002
0. 007
0,525
0 .011
0 . 03 1
0 .011
n.027
o. 002
o. 002
0. 009
0 .014
0.003
0. 004
0.004
0.016
0. 006
0.041
0 . 028
0.029
0. 044
0 . 004
0 . 37 1
245
-------
SAMPLE IDs E.G. INCINERATOR - TEST NO.
PARTICLE SIZE: C
ANALYSIS IDs AC047 - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED
MASS:
ELEMENT
AL
SI
P
c-
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
6A
Kb
1.
1.
0.
0.
*1 0
0.
1.
0.
0.
0.
0.
0.
0.
0.
0 .
("1
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
Pi'
UG/CM
131+-
473+-
153+-
49 1 +-
3 1 9+-
342+-
230+-
207+-
002-1
022+-
016+-
372+-
015+-
011+-
609+-
("M'H'H
023+-
002-1
025+-
00 l-i
006+-
002-1
000+-
OOO-i
000+-
OOO-i
000+-
0 1 0+-
000+-
000+-
000+-
072+-
002-1
302-i
£.. *
1
^ >-U(_
3S+-
iHKt
10
i.-n
MICROGRAMS
2 UG /FILTER
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
033
096
060
106
413
149
072
012
002
002
002
025
003
003
129
004
015
003
005
002
003
004
013
009
007
Oil
017
013
023
0:39
097
143
004
033
7.
9.
1 .
3.
13.
S
3.
1.
0.
0.
0.
J^
0.
0.
. ,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
532+-
453+-
017+-
150+-
1 00+-
404+-
213+-
326+-
0 1 6+-
141+-
101+-
3S3+-
099+-
069+-
913+-
000+-
145+-
010+-
1 60+-
004+-
O39+-
( ) 1 0+-
000+-
000+-
000+-
OOO-i
000+-
067 +-
OOO-i
000-f
000+-
461+-
012+-
9394
0.
0.
0.
0.
.to
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-0.
0.
0.
0.
0 .
531
614
T1 0 er
673
651
955
462
030
014
015
014
160
017
022
330
027
097
0 1 9
031
015
013
025
082
053
047
073
109
112
177
253
622
953
024
531
5.
6.
0.
2.
13.
-' a
5.
0.
0.
0.
0.
1.
0.
0.
.-.
o.
0.
- 0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
1.
PERCENT
512+-
376+-
739+-
290 +-
15S+-
923+-
974+-
964+-
012+-
102+-
074+=-
736+-
072+-
050+-
S45+-
000+
105+-
007 +
116+-
n o ';+
023+-
007+-
OOO-i
000+-
00 OH
000 H
000+-
049+-
000+-
000+-
O("K")H
335+-
003-f
410+-
0.
0.
0.
0.
~ .
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
t j .
0.
0.
556
670
'"' ;-' S
520
151
751
549
09 1
0 1 0
0 1 3
012
172
013
0 1 6
/-,;:-:
(j 1 9
071
0 1 4
024
01 1
0 1 3
0 1 9
059
042
034
()«?, 1;
030
032
1 23
134
452
693
017
~* Cy O
246
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 6A
PARTICLE SIZE: F
ANALYSIS ID: AF192 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
944+- 10 MICROGRAM:!
ELEMEiMT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
c-
_>
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
2_
3.
1.
BT
J .
40.
15.
0.
0.
0.
0.
0.
0.
0.
0.
14.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
~1
1 94+-
008+-
146+-
393+-
766+-
433+-
500+-
087 +-
010+-
022+-
039-f
605+-
042+-
219+-
733+-
017+-
047+-
003+-
325+-
030-1
013+-
00 OH
041+-
033+-
037+-
025+-
462+-
000+-
527+-
420+-
000+-
000+-
023+-
727+-
0. 132
0. 141
0.20S
0 . 44 1
1 . S80
0.724
0 . 06 1
0.006
0 . 002
0.002
0.003
0 . 030
0. 004
0 .011
0.671
0 .015
0 . 047
0.014
0 . 0 1 9
0. 004
0 . 004
0.012
0 . 0 1 9
0.007
0 . 008
0 . 009
0 . 032
0.014
0.080
0 . 047
0.076
0. 121
0. 007
0.445
14.
19.
7.
34.
261.
99 .
-I
'
0.
0.
0.
0.
o
'
0.
1.
94.
0.
0.
0.
-I
0.
0.
0.
0.
0.
0.
0.
.-}
d^>
0.
9.
"j
h-
0.
0.
0.
62.
083+-
3 1 2+-
356+-
622+-
716+-
403+-
2 10+-
556+-
064+-
140+-
253+-
883+-
269+-
406+-
538+-
109+-
302+-
0 1 3+-
085+ -
1 9 1 +-
031+-
003+-
262+-
242+-
239+-
161+-
965+-
OOOH
son
695+-
000+-
000+-
147+-
449+-
0.
0.
1.
-.:
12.
4.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
0.
0.
9
847
907
3:36
832
071
649
395
037
0 1 0
013
0 1 3
196
022
073
303
093
304
089
1 20
024
023
076
125
047
049
060
203
092
515
^0=;
490
774
04 5
357
1
2
0
:.
27
10
0
0
0
0
o
0
0
o
10
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
6
.493+-
. 045+-
. 779+-
. 666+-
-711+-
.525+-
. 340+-
. 059+-
. 007+-
.015+-
. 027+-
.411+-
m Q2irn
. 149+-
.015+-
.012+-
. 032+-
.'002-1
."221+-
. 020+-
. 009 +-
. 000+ -
. 02S+-
. 026+-
. 025-1
. 0 1 7+-
.314+-
. 000+-
. 03S+-
. 235+-
. 000-f
. 000+-
. 016+-
.612+-
0.
0.
0.
0.
1 .
0.
0,
0.
0.
0.
("l f
0.
0.
(-'
.' .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
o
0.
091
093
142
302
31 1
c=lf-
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 68
PARTICLE SIZE: C
ANALYSIS ID: CC103 - Nudepore
EXPOSED AREA:
hASS:
6.42 SQUARE CM
101+- 10 MICROGRAM:;
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
C;
CL
K
CA
TI
V
OR
MN
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZP
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
1.
1.
0.
0.
~J
0.
1.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
034+-
398+-
151+-
643+-
051+-
728+-
332+-
189+-
004-t
014+-
016+-
366+-
0 1 3-1
009 +-
474+-
OOO-i
001+-
OOO-i
032-i
002+
007 +-
(JO 3-i
OOO-i
000+-
OOO-i
OOO-i
041+-
002-1
013+-
03 1 +-
134+-
150-1
005+
241+-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
079
093
060
110
433
149
074
0 1 1
002
002
002
025
003
003
129
004
015
003
005
003
003
004
0 1 4
on
008
013
020
020
031
047
113
177
004
034
6.
o
' '
0.
4.
19.
4.
8.
1.
0.
0.
0.
^L m
0.
0.
1
'
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
633+-
973+-
970+-
125+-
586+-
674+-
551+-
215+-
025-i
093+-
106+-
35 1 +-
084 +
060 +-
046 +-
00 3+-
004-1
003+-
203+-
0 1 5+-
042-1
021+-
000 +-
OOOH
002-i
OOO-i
266+-
011+-
113+-
199+-
360-1
966+-
032-1
547+-
0.
0.
0.
0.
2 B
0.
0.
0.
0.
0.
,0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
507
599
385
705
795
955
473
074
0 1 3
015
014
159
017
022
830
027
097
020
035
017
021
028
09:]:
070
049
085
131
1 30
197
299
723
1 38
024
541
6.
8.
0.
4.
19 o
4,
i'
1.
0.
0.
0.
£
0.
0.
"'
' ' *
0.
0.
. o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
551+-
355+-
937+-
071+-
-I -! t~l 1
«.' -*L. ' ' '
613+-
439 +_
199+-
025+-
091-1
1 04+
320+-
033+-
059+-
005+
003-1
004 H
003-1
201+-
015+-
041+-
021+-
000 H
OOO-i
002-1
000+-
262+-
0 1 1 +-
117+-
1 96+-
843+-
953+-
031+-
52A +
0.817
1 . 055
0.391
0 . 803
;-; _ 3PJ4
1 .047
0 = 957
0 . 1 39
0 . 0 1 4
0 . 0 1 3
0 .017
0 . 277
0 . 0 1 8
0 . 023
0 . 87 1
0 . 026
0. 096
0 . 0 1 9
0 . 04 0
0 . 0 1 7
0 . 02 1
0.027
0. 091
0 . 069
0.049
0.084
0 . 1 32
0. 123
0. 194
0.296
0.723
1. 127
0. 024
0.554
248
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO.
PARTICLE SIZE: F
ANALYSIS ID: AF193 - Teflon
6B
EXPOSED AREA:
MASS:
6.42 SQUARE CM
937+- 10 MICROGRAM:;
ELEMEN'
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
s
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
L ft
^r^
HG
PB
"»
i.
T«
J'
1.
5.
42.
16.
0.
0.
0.
0.
0.
0.
0.
0.
15.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
1.
0.
a.
o
V*
0.
10.
091+-
009+-
170+-
345+-
544+-
119+-
330+-
061+-
009+-
023+-
039+-
606+-
043+-
226+-
514+-
010+-
022-t
000+-
347+-
033+-
010+-
00 OH
026+-
043+-
029+-
034+-
503+-
037+-
589+-
433+-
000+-
()(-) (-H
v.' * ' %-'
000 +-
290H
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
().
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
131
141
212
457
962
754
059
005
002
002
003
0:3 1
004
012
707
0 1 6
049
015
020
004
004
012
020
007
007
0 1 0
033
014
053
043
075
122
007
471
13.
1 9 .
7.
34.
273.
103.
2.
0.
0.
0.
0.
'"«
_'
0.
1.
99 .
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
3.
0.
10.
^L m
0.
0.
0.
66.
426+-
321+-
50S+-
315+-
132+-
4S3+-
440+-
392+-
057+-
14S+-
251+-
889+-
275+-
449+-
593+-
063+
141+-
000+-
230+-
209+-
063+-
OOOn
166+-
277+-
137+-
213+-
230+-
240+-
199+-
779+-
000 +-
00 OH
000+-
062+-
0.
0.
1.
+L m
12.
4.
0.
0.
0.
0.
0.
0.
b.
0.
4.
0.
0.
0.
0.
0.
0.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.-,
340
907
363
936
596
343
379
030
0 1 0
013
017
196
023
075
<=: : /-
-> - -'
102
317
094
1 23
025
023
OftO
1 29
043
046
063
215
089
533
303
431
731
047
022
1.
^,
0.
o
'
29.
11.
0.
0.
0.
0.
0.
0 .
0.
0.
1 0 .
0.
0.
0.
0.
" 0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
7.
433+-
063H
S02+-
/-./-A+-
160+-
048+-
260n
042H
006 H
016+-
027+-
415+-
029+-~
1 SS-i-1-
63 3 H
007+-
015+-
00 OH
233+-
022+-
007+-
00 OH
013+-
03 OH
020+-
023+-
345+-
026+-
089+-
297+-
000+-
OOOH
000+-
053+-
0.091
0.099
0. 146
0.316
1 . 330
0. 530
0 . 04 1
0.003
0.001
0.001
0.002
0 . 02 1
0.002
0. 003
0.497
0 . 0 1 1
0 . 034
0 . 0 1 0
0 . 0 1 4
0.003
0. 002
0 . 009
0.014
0.005
0.005
0 . 007
0 . 023
0. 009
0 . 053
0. 033
0.051
(") . Oft:";
0 . 005
0 . 33 1
249
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 7A
PARTICLE SIZE? C
ANALYSIS IDs AC043 - Teflon
BUILD UP OF DEPOSIT AT PERIMETER
EXPOSED AREA: 6.42 SQUARE en
MASS: 263+- 10 MICROGRAMS
ELEMENT
UG/CM2
UG/FILTER
PERCENT
AL
SI
P
3
CL
K
CA
TI
V
CR
MN
FE
NI
CLI
IN
GA
A i-
l-i C'
SE
ER
RB
SR
Y
ZR
MO
PD
AO
CD
IN
SN
SB
BA
LA
HG
PB
'2. .
^
_'
0.
1.
Pi
1.
"'
0.
0.
0.
0.
0.
0.
0.
'
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0.
0.
0.
0_
0.
1 .
724+-
316+-
426+-
794+-
333-1
973+-
367+-
363+-
000-i
043 +-
03 4 H
653-t
019-1
03 1 +-
244+-
00 OH
022+-
OOO-i
09l-i
005+-
013+-
OO<"H
013+-
006-1
000+-
003+
023+-
014+-
10S+-
042+-
240+-
219+-
012+-
O<-)4 +
0.
0.
0.
0.
1 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0 =
0 =
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 =
0.
0.
0.
181
239
142
j^o-j
103
271
134
024
003
004
003
043
004
007
672
01 1
026
007
0 1 4
003
003
006
014
003
007
Oil
017
016
036
033
036
131
005
205
17.
24.
^ .
11.
S'~;
12.
15.
*L .
0.
0.
0.
4.
0.
0.
20.
O
0.
("i
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
6.
433+-
493+-
732+-
516+-
354+-
701+-
199+-
365+-
000+
306 +-
215+-
192+-
122+-
197+-
325+-
OO(~H
139+-
OOO+-
536+-
029+-
034 + -
000+-
OS3+-
038 +-
000+-
054+-
180+-
093n
695+-
267+-
540+-
406+-
075+-
447+-
1.
1.
0.
1.
7.
1 .
0.
0.
0 .
0.
0.
'0.
o.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1 .
161
536
9 1 3
494
079
741
362
156
022
024
021
277
024
045
3 1 4
069
169
042
0 1 3
0 1 9
0 4 0
037
050
045
070
111
100
-.--,--.
242
554
343
033
315
6.
9p
1.
4.
20.
4.
5.
0.
ft
0.
0.
1.
0.
0.
7,
u
0.
0.
0.
0.
0 =
o .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
^~ e
652+-
319+-
039+-
331+-
485+-
33 1 +-
732+-
900 H
Oofn
1 1 6+-
032 + -
595+-"
046+-
075+-
922+-
OOO+
053+-
000-(
223+-
0 1 1 +-
03 2+-
000-<
032+-
014+-
OOO-i
021+-
069+-
035+-
265+-
102+-
536+-
535+-
029-i
452+-
0. 509
0 . 633
0. 349
0 . 592
2.303
0. 687
0. 395
0.069
0. 008
0 . 0 1 0
0. 009
0. 122
0. 'JO 9
0 . 0 1 7
1 . 663
0 . 026
0.064
0 . 0 1 6
0 . 035
0. 007
0. 007
0 . 0 1 5
0. 033
0 0 1 9
0 .017
0 .027
0. 042
0 . 03 '3
0. 039
0 . 092
0.21 2
0.321
0 . 0 1 2
0. 50 9
250
-------
SAMPLE ID: E.G. INCINERATOR - TEST NO. 7A
PARTICLE SIZE: F
ANALYSIS ID: AF194 - Teflon
EXPOSED AREA:
MASS:
6.42 SQUARE CM
3321+- 10 MICROGRAM:;
ELEMENT
UG/CM2
LIG/FILTER
PERCENT
AL
SI
F.
Z>
CL
K
CA
TI
V
CR
Mr-;
FE
NI
CU
zu
GA
AS
SE
ER
RE
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PE
4 . 637+-
7.797+-
2.393-r
9.520+-
105.045+-
25.247+-
0.936+-
0. 166+-
0.029+-
0.074+-
0. 103+-
1 . 340+-
0. 131+-
0.619+-
76.363+-
0.221+-
0. OOO-i
0. 020 +-
1. 135+-
0. 04?+-
0.040+-
0. OQO+-
0.055+-
0. 116+-
0.204+-
0. 137+-
0.8 14+-
0 . 035+-
2.773+-
0.575+-
0.000+-
O.OOQ+-
0.064+-
23. 060+-
0.326
0.360
0 . 435
0.947
4.331
1 . 1 33
0. 104
0.010
0.003
0.004
0 . 006
0.064
0.010
0 . 030
3.495
0.049
0.094
0 . 033
0. 060
0 . 007
0.007
0. 026
0 . 04 1
0.011
0.016
0.015
0 . 043
0.013
0. 133
0.056
0.094
0. 144
0.013
1 . 052
30.094+-
50.055+-
15.395+-
61. 116+-
674. 336 +-
162.0S4+-
6.006+-
1 . 063+-
0. 1S5+-
0.472+-
'0.659+-
3 . 606+-
1. 162+-
3.976+-
493. 46 H
1.41S+-
0. OOOn
0. 131+-
7.607+-
0.315+-
0 . 255+-
0 . OOOn
0.354+-
0.743+-
1.313+-
O.S77+-
5.226+-
0.545+-
17.337+-
3.691+-
0.000+-
0 . 000-+ -
0,41 2+-
1 43.045+-
2.095
2 . 309
2.792
6.077
3 1.01 5
7.593
0.669
0 . 062
0.017
0.023
0. 036
0.412
0.065
0. 191
22.433
0.315
0 . 605
0.21 0
0.384
0.045
0.046
0. 169
0.263
0.069
0. 105
0.099
0.307
0. 114
0.333
0.362
0 . 606
0 . 926
0 . OS 1
6.754
0.906+- 0.063
1.507+- 0.070
0.4 64+- 0.084
1 . 84 OH 0. 133
20.30 6 + - 0 . 9 3 f:
4.330+- 0.229
0. 181 +~ 0. 020
0. 032+- 0. 002
0.006H 0.001
0.014-i 0.001
0.020+- Q-,001
0. 25'"'H 0. 012
0.035-!-- 0.002
0. 12 OH 0. 006
14.S53+- 0.677
0.043+- 0.009
0.000+- 0.013
0.004+- 0.006
0.229+- 0,012
0.009-i 0.001
O.OOS+- 0.001
0.000+- 0.005
0.011+- 0.003
0.023+- 0.002
0.040+- 0.003
0.026-1 0.003
0. 157+- 0.009
0.0 16+- 0.003
0.537+- 0.027
0 . 1 1 1 +- 0 . 0 1 1
0.000+- 0.013
0. OOO-i-- 0. 023
0.0 12+- 0.002
4. 453H 0. 204
251
-------
SAMPLE ID: E.G. INCINERATOR - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: AC073 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
p
CL
K
CA
TI
V
CR
MN
FE
Nl
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
3N
SB
BA
LA
HG
PB
0.
0.
(-)
0 .
0.
("1
0.
0.
0.
0.
0.
0.
0.
I")
0.
0.
()
0 .
0.
0.
0.
0.
c> .
o .
0.
0.
0.
0.
(-,
(-,
0.
0.
0.
0.
OOO-i
OOO-i
(")O(";H
OOCH
OOCH
OOO-* -
002-1
000+-
OOCH
00 1 H
00 1 +-
002-1
00 1 +-
OO(~H
000+-
OOCH
CiOOH
OOCH
001+-
OC)0-i
002 -i
00 1 +-
ooo-<
003+-
000+-
OOCH
010+-
00 CH
OOC)-i
OfH'H
OOO+
lll-i
002-i
004+-
0.
0.
(-J
0.
0.
0.
0.
0.
0.
0.
0.
0.
c».
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
015
0 1 1
005
024
oos
003
002
002
001
00 1
OO2
004
001
002
003
00 1
00:3
001
002
002
003
003
0 1 3
0 1 0
OOS
012
0 1 6
0 1 9
023
041
104
1 63
003
006
0.
0.
C).
O
0.
0.
0.
0.
0.
O
O
0.
0.
0.
0.
0.
0.
Oc
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
OOCH
000 -^
000 -I
OOO-i
OOCH
014-t
00 CH
OOOn
<"><") 9 H
016+-
005+-
OOCH
OOCH
002-t
000+-
003-1
OOS-i
0 0 CH-
OI 3+-
009 H
OOCH
035+-
OOO-i
OOCH
067+-
OOO-i
OOO-i
OOOH
OOCH
713+-
013+-
024-1
0.
0.
( )
U.
()
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
C'.
o
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
096
070
029
153
051
022
016
010
007
009
0 1 0
024
0 1 0
0 1 0
006
006
022
on 9
012
014
C> 1 3
021
037
062
053
073
100
119
147
266
666
059
020
037
252
-------
SAMPLE ID: E.G. INCINERATOR - FIELD BLANK
PARTICLE SIZE: F
ANALYSIS ID: AF240 - Teflon
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
'"*
CL
K
CA
TI
V
CR
MN
FE
NI
CU
ZN
GA
AS
SE
ER
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.002+-
0. 000 +-
0. 000+-
0. 000+-
0 . 000+-
0.002+-
0.000+-
0. 001+-
0 . 00 1 +-
0 . 002+-
0.001+-
0. 00 OH
0. 000+-
0. 000+-
O. OfH'H
0. OOO-i
0. 000-t
0. 002-f
0. 000+-
O. OO OH
0 . 005+-
0. 000+-
0 . OOO-i
0. 000 +-
0 . 000+-
0.000+-
0.003+-
0.020+-
0.022+-
0.000+-
0. 064+-
0.000+-
0.001+-
0. 007+-
0.014
0.009
0.005
0.026
0.009
0 . 003
0 . 002
0.001
0 . 00 1
0.001
0.002
0 . 004
0.001
0. 002
0. 001
0.001
0.004
0 . 00 1
0 . 002
0. 002
0.003
0.003
0.014
0 . 0 1 0
0.009
0.011
0.017
0.019
0.022
0 . 040
0 . 1 06
0 . 1 65
0. 002
0. 006
0.014+-
0.000+-
0. 000+-
0. 000-t
0 . 000+-
0.015+-
0. 000+-
0.006+-
0 . 004+-
0.014+-
0. 007-1-
0 . 000+-
0. 003+-
0 . 000+
0. OOO-i
0.001+-
0. 000+-
0 .011 +-
0.000+-
0. 002+-
O.OS2+-
0. 000+-
0. 000+'-
0.000+-
0. 000+-
0. 000+-
0.01S+-
0. 126+-
0. 143+-
0. 000+-
0.411+-
0. 000+-
0.009+-
0. 044 +-
O.OS7
0 . 057
0. 029
0 . 1 65
O . OSS
0. 021
0 . 0 1 5
0 . 0 1 0
0. 007
0. 009
0 . 0.1 0
0.023
0 . 0 1 0
0 . 0 1 0
0. 007
0 . 006
0.024
0 . 009
0 .011
0 . 0 1 4
0 . 0 1 S
0.021
0. OS7
0 . 063
0. 055
0. 072
0. 10S
0. 121
0. 142
0.259
0.6S1
1 . 053
0.015
0 . 039
253
-------
SAMPLE ID: E.G. INCINERATOR - FIELD BLANK
PARTICLE SIZE: C
ANALYSIS ID: C-C12C - Nudepore
FIELD BLANK
EXPOSED AREA: 6.42 SQUARE CM
ELEMENT
UG/CM2
UG/FILTER
AL
SI
P
.;.
CL
K
CA
TI
V
CR
MM
FE
NI
CU
ZN
GA
AS
SE
BR
RB
SR
Y
ZR
MO
PD
AG
CD
IN
SN
SB
BA
LA
HG
PB
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
(")
0.
0.
0.
0.
0.
0.
0..
0.
0.
0.
0 .
0 .
0.
(1
0.
0.
0.
0.
0.
0.
0.
0.
0.
007+-
031+-
OOO+-
OOOH
000+-
006+ -
000+
000+-
002n
000+
OOO +
006+
00 1 +
000 +-
OOOn
OOOn
000+-
00 OH
000 +
003n
000 +
OOO"1
OOOn
006H
OOO+
009+
OOO+-
000+-
OOO+-
007+-
169+-
335+-
001-(
002+
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
025
020
0 1 0
023
009
003
002
001
00 1
002
002
004
001
002
001
001
004
00 1
002
002
003
00:3
014
0 1 1
009
012
017
020
024
045
112
179
003
007
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
("I
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o
0.
0.
o
0.
0.
0.
0.
0.
1.
2.
0.
0.
045+-
201+-
000+-
00 OH
000+-
039 +
000+
000+
010+-
OOOn
OOfH
037H
005+-
00 OH
000+ -
OOOn
00 OH
000+
000+-
022+-
000 + -
OOO+
Od'OH
039 +-
OOfM
056+-
00 OH
000+-
OOOn
047+-
087+-
14S+-
006+
0 1 1 +-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
1.
0.
0.
162
127
062
147
06 1
022
0 1 4
009
007
01 1
0 1 0
025
009
0 1 0
006
007
026
009
014
0 1 6
0 1 9
022
090
06S
057
075
112
123
156
237
722
151
0 1 3
043
254
------- |