ENVIRONMENTAL HEALTH SERIES
Air Pollution
            Air Pollution in the
            Roasting Industry
            U.S. DEPARTMENT OF HEALTH,
            EDUCATION, AND WELFARE
            Public Health Service

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               AIR POLLUTION

                     IN THE

      COFFEE ROASTING INDUSTRY
                     Frank Partee

               Technical Assistance Branch
                 Division of Air Pollution
U.S. DEPARTMENT OF HEALTH, EDUCATION; AND WELFARE

                  Public Health Service

                 Division of Air Pollution

                    Cincinnati, Ohio

                    September 1964

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     The ENVIRONMENTAL HEALTH SERIES  of reports was established
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vironment:  The  community,  whether  urban,  suburban, or  rural, whe re
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        Public Health Service Publication No,  999-AP-9

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                           CONTENTS

FOREWORD .   .    .,	      	          .   iv
ABSTRACT	               	     v
INTRODUCTION    ....     .            	       ....   1
SUMMARY  ...       	          	        .  .   1
PROCESSING COFFEE  . .             	           	   2
     Preparing the coffee cherry. .     	         ....      2
     Regular coffee .          	         	     2
         Cleaning the  green beans .  .       	          2
         Blending ...      	         	      4
         Roasting.    ...    	            	       .     4
         Cooling   	        	     	   5
         Stoning  ...      .    	      	      .   6
     Instant coffee   	    	      ....     6
         Unit operation	       	      .    ....   6
         Disposal of spent grounds   	   7
     Decaffeinated  coffee  .     	      7
NATURE AND  EXTENT OF AIR POLLUTION	   9
     Chemistry of coffee	    	   9
     Coffee  roasting .  .          	   9
         Stack  emissions	   10
     Instant coffee	    	       	     12
     Decaffeination . .     .        	    	        12
METHODS OF  CONTROLLING  EMISSIONS	     12
     Particulate and smoke emissions	      .   ...      12
     Soluble coffee emissions        	      .    ....     13
REFERENCES	           	       .  .      15

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                              FOREWORD
    This pamphlet is one of a series of studies undertaken by the Public
Health Service to provide information concerning air pollution encounter-
ed in  specific industries.  It is intended as a compilation of facts regard-
ing the nature and extent of air pollution resulting from the processing
of coffee and current methods available for control of atmospheric
emissions  from typical installations.
    Many people have contributed their time and knowledge toward
making the publication of this pamphlet possible.  Gratitude is extended
to all; in particular to Messrs. Frank A.  Bell,  Jr. and "Walter Smith,
Public Health Service; The National Coffee Association, for guidance
and photographs of plant operations; Jabez Burns -- Gump Division of
Blaw-Knox Company, for technical information on modern processing
and control equipment;  members  of the industry for their  counsel; and
all the state and local health officials who generously relayed their
knowledge  and experience in this  area.

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                           ABSTRACT
    This review provides a guide for the inventorying and control of
emissions arising from coffee processing.  Information -was collected
from published literature and other sources.   Emission factors -were
established for the various processes  involved, i.e. roasting,  stoning,
and cooling.  The  air pollution aspects of the production of regular
grades, instant, and decaffeinated coffee are discussed.  Also  discussed
are the types and operating characteristics of control equipment used.

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                     AIR  POLLUTION


                             IN  THE


          COFFEE  ROASTING INDUSTRY


                            INTRODUCTION
    Coffee is  roasted from coast to coast and from the northern tier
of states to the Rio Grande.  The extent of possible air pollution from
this industry is of general interest in the United States, although the
bulk of the coffee is processed in and around New York, Los Angeles,
Chicago, and New Orleans.  During November and December 1961,
city air pollution control and health agencies were queried in regard
to their experiences with air pollution caused by the processing of
coffee.  The survey indicated that of 37 cities responding 18 cities have,
or have had,  problems with that source of air pollution. Some indicated
the problem was of relatively minor importance to them.   Officials  in
15 cities reported receiving no complaints.   Four of the responses
gave no information about the complaints.
    Coffee roasters are finding that although they may have been located
on the outskirts of communities at one time, they now are  being engulfed
by burgeoning residential growth.   This has created pollution "receptors"
where formerly there were none and a concomitant demand for control.
    Coffee processing produces four types of emissions:  dust,  chaff,
odor, and smoke.   Dust is generated in the  handling of green beans,
which are bagged in cloth.  Chaff consists of the  outer covering, or
skin,  that bursts when the  bean swells during roasting.  The odor and
smoke are combinations of organic constituents volatilized at roasting
temperatures  and steam produced when the  roast is quenched with water.
Further processing to produce instant coffee causes an additional emis-
sion in the form of powdered coffee, which escapes during the drying
process.  During decaffeination, odors can  be produced by trichloro^
ethylene,  the solvent used in extracting caffeine from the green coffee
beans.

                               SUMMARY
    Emission inventory factors are presented in Table 1.  These fac-
tors  can be used to approximate the gross amount of particulate matter
emitted from a typical roasting plant with or without control equipment.

    Particulate emissions are held well within generally prescribed
limits when cyclone collectors are employed.  Odor-laden smoke pre-
sents  a more difficult problem,  however.   Smoke density often exceeds
No. 2 Ringelmann (black smoke) or 40 percent opacity  (other than black
smoke), the limit usually established in smoke regulation codes.  Smoke
emissions have been lessened by the development of a roaster that re-
circulates effluent gases through the flame of the roaster burner. Cur-
rently, the best method of  smoke elimination involves use  of a separate

                                  1

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afterburner.  Powdered coffee particulate, being highly soluble, can be
effectively controlled by means of a simple water scrubber.

    Table 1.  EMISSION INVENTORY FACTORS FOR COFFEE
              PROCESSING
                         Solid emissions,  lb/1000 Ib green beans
           Process	•	—	•	"	
                              With no control  With usual control
    Roaster
         Direct fired                3. 8             1. la
         Indirect fired               2. 1             0. 6a

    Stoner and cooler               0. 7             .0. 2a

    Instant coffee spray       Control always        0.7
       dryer                     employed

    a                               Vi
     Cyclone.                        Cyclone and wet scrubber.

    In summary,  the most effective means of control now available are
centrifugal collectors for dust and chaff, afterburners for smoke and
oior, and water scrubbers for instant coffee particulate,

                          PROCESSING COFFEE

PREPARING THE COFFEE CHERRY
    Before arrival at a roasting plant in the  United States,  the coffee
cherry (the fruit) is prepared by one of two methods.    The older,  "dry"
method consists of spreading the cherries on flat, drying grounds called
"barbecues, " which often have brick or  cement surfaces.  The cherries
are raked until they are dried thoroughly by the wind  and sun.  Artifi-
cial drying has supplanted natural sun drying on many plantations.
    The  modern,  "wet" method utilizes a fermentation process.
Cherries are depulped in  water,  and the mixture of pulp and liberated
seeds is  allowed to ferment for periods  lasting from hours to days.
This loosens the tough, parchment shell of the beans  (See Figure 1).
Then,  the beans are dried and the shell and silver skin removed by
mechanical rubbing.

REGULAR COFFEE
    A  flow diagram for a typical coffee roasting operation is shown in
Figure .2.

Cleaning Green Beans
    Although the beans are cleaned before they are exported to this
country,  dirt enters the bags  during transit.  Other trash accumulates
from repeated  handling.   Dust,- lint, and strings become mixed with the
beans when the bags are opened.   This trash must be removed at the
plant not only to ensure a quality product, but to eliminate hazards in

 9                                          AIR POLLUTION IN THE

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the roasting process.   Bits of combustible material can cause serious
fires in the roasters,  clog up  conveyors and piping, and otherwise re-
duce production efficiency.  Small  stones and pieces of  metal,  if not
eliminated,  could ruin the grinders.
   Figure I. Cross section of a coffee cherry showing outer skin, mucilaginous matter,  or
          pulp, (dotted); parchment cover (white); silver skin (shaded); and coffee bean
          (black). (Reference I).
                                         POINTS OF EMISSION

                                      	USUAL OR POSSIBLE CC
                                       *  ALTERNATE CONTROL
                  Figure 2. Flow diagram of coffee roasting plant.

     Much dust is generated in dumping the green coffee from coarse,
cloth bags.  Dust from the dumping pit can be controlled by means of
a hood and exhaust system vented to a cyclone collector.

     Cleaning was formerly carried out by screening methods dependent
on the difference in the size of the green beans and attendant trash.
These inefficient methods were unsatisfactory.   Presently, excellent
separation is achieved by utilizing differences in specific gravity of
the beans  and that of foreign materials.   Before  roasting,  only those
materials lighter than the bean, i.e., dust, string, etc., are  removed.
An air stream, at a carefully regulated pressure, is drawn up through  a
rectangular duct.   The beans are  introduced into this air  stream through
a slit  in the duct.   As the beans fall through the duct to a.  bin below,
material lighter than the beans is carried up the duct and discharged
from the process.  '

COFFEE ROASTING INDUSTRY                                         3

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    During roasting, the coffee beans  lose weight while gaining about
50 percent in volume, thus the specific gravity of the bean is decreased
by about one-half.  Those pieces  of material that closely matched the
specific  gravity of the green bean and, therefore, escaped the first
cleaning step would,  after roasting,  be about twice as dense as the bean.
This new disparity in the density  of the "stones" and the roasted beans
is employed to remove these  materials during a  "stoning"  operation,
which is described later.

Blending
    After the green beans have been cleaned, they are generally lifted
by bucket conveyor to the highest point in the plant to permit gravity
feed to succeeding operations.  The blender consists of a  hollow cylin-
der, mounted horizontally. '   The proper weight of each grade of
coffee for the blend is charged and the cylinder  is rotated.  The batch
is mixed in a few  minutes by  helical flanges inside the  blender.  Any
dust or  chaff loosened by the  mixing is removed  by an exhaust system.
The blended coffee then goes  to holding bins or to feed  hoppers over
the roasters.

Roasting
    Roasting is the  most important step in coffee making  because it
develops the flavor.  For the average  roast,  about 370 Btu of heat
energy is required per pound of green  coffee. More than  95 percent
of modern roasters  are gas-fired; the  remainder are oil-fired.  '
    A roaster  consists of a perforated, horizontal cylinder with internal
helical flanges enclosed in  a metal jacket.  Of the three types  of roasters
in use,  two are batch-fed.  They  roast up to  1, 500 pounds per hour in
500-pound batches that require  15 to 20 minutes  of roasting time each.
The older,  direct-fired roasters  utilize a gas jet inside the cylinder,
which operates at  an air temperature of about 2,  000°F (Figure 3), and
         FEED BIN
                                                         EXHAUST
                                                         GASES
                 Figure 3. Simplified drawing of direct fired roaster.
                                             AIR POLLUTION IN THE

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heats the  roaster by radiation.   In the newer, indirect-fired roasters,
the gas burner is located in a separate chamber behind the cylinder.
Hot combustion gases are recirculated, thus effecting more efficient
heat transfer.  This reduces the operating temperature  range to 850° to
900°F and produces a more uniform, higher quality roast (Figure 4).
                  EXHAUST GASES

                          FEED BIN
    FUEL AND AIR
                                      RECIRCULATED GASES
              Figure 4. Simplified drawing of indirect fired roaster.

 The third type,  and the most modern,  is a continuous roaster with a
 rated capacity of up to 10, 000 pounds per hour and a roasting time of
 only 5 minutes; it is  operated at 450° to 500°F. 3

     During the  first  10 minutes of batch-fed roasting,  the charge heats
 at a fairly uniform rate and moisture is driven off.   In the  last 5 to 10
 minutes,  the temperature rises rapidly and the chemical degradation,
 which produces the familiar odor and flavor,  occurs.  The beans swell
 and turn brown.  While the beans are roasting, the operator  constantly
 compares  samples from the roaster with beans of a standard prescribed
 by  cup testers as having the desired flavor.  At the moment the color
 of the roasting beans matches that of the standard beans, the operator
 applies a water quench to  stop the roasting action.  Because  of the high
 temperature in  the roaster, the water flashes  off and passes out of the
 stack as steam.  Roasters that perform the roasting operation auto-
 matically, i. e. , that heat to a predetermined temperature  and then
 quench the batch, are also used extensively.  The changes  that occur
 in the chemical composition of the coffee beans during  roasting are
 listed in Table 2.
     When the roasting process has been completed,  the batch is dumped
into a cooler where the temperature of the brown beans drops until no
further chemical changes occur.    The cooler usually consists of a bin
wherein the beans can  be agitated while a draft of cool air is drawn
through them.  Chaff and residual smoke are picked up by the air
stream and discharged from the cooler.
COFFEE ROASTING INDUSTRY

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Table 2.  CHANGES IN COFFEE COMPOSITION ON ROASTING3-
                      Solids on basis of dry weight of green coffee,  %
                               Before                After
Water
Sugar
Crude fiber
Ether extract
Water extract
Ash
Caffeine
Chlorogenic acid
Trigonelline
Total nitrogen
Total sulfur
10.
8.
24.
11.
30.
3.
1.
7.
1.
2.
0.
73
62
00
08
35
00
22
8
02
34
10
2.
0.
13.
13.
12.
4.
1.
4.
0.
2.
0.
16
75
03
75
62
03
31
5
73
45
11
aReferences 3 and 4.

Stoning

     This  step would more properly be called "de-stoning" because
heavy materials, which were not removed in the green bean cleaner,
are removed during the stoning operation.  The principle is the same
as that used to remove light-weight debris.  The actual operation is
different in that the air flow is regulated to lift the roasted beans and
leave the  bits of rock and metal behind.  The  "stones"  fall into a recep-
tacle and  the beans are  "airveyed" up the duct to bins above the grinders.
The  air is then discharged from the process.

INSTANT  COFFEE

Unit Operation

     Production of instant coffee  is an extension of the roasting process.
The  operation basically is an extraction.  Apparently,  all instant coffee
installations are  custom designed; however,  enough similarities exist
to allow general treatment.

     About 3. 5  pounds  of green coffee  are required to make 1 pound
of instant  coffee.  The roasted beans are  ground very coarsely. The
moisture  is allowed to remain much higher than that of beans used to
make regular grades of coffee; this promotes immediate dissolution of
the coffee solubles.

     Stainless-steel cylinders, some as large as  2 feet in diameter,  with
a capacity of 10, 000 pounds of coffee, are filled with the coarse grounds.
(Figure 5).  Zeolite-softened water at 300°F is introduced under pres-
sure, usually. 10 to 12 atmospheres,  at the top of the cylinder.   The
water travels through the bed, extracting the  solubles.  Leaving the
bottom of  the first cylinder,  the  stream of liquor  enters the top of the

 6                                           AIR POLLUTION IN THE

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cylinder.  The "water travels through the bed, extracting the solubles.
Leaving the bottom of the first cylinder,  the  stream of liquor enters the
top of the second cylinder.  The liquor stream always enters a cylinder
of fresher grounds.  This provides a maximum concentration gradient
at all points in the system.  When a cylinder is exhausted,  after about
6 hours  of extraction, it is bypassed in the line and the spent grounds
are blown out with steam.
                  GROUND
                  COFFEE
      HOT _
     WATER
                    JL
         SPENT
        GROUNDS
E




| FILTER ]

XT R ACTION
TOWER
S
"x
[PA
1 |
SPRAY
DRYER
^
CKAGI
HOT AIR
^
TO SP
NG~|
INSTANT
COFFEE
                                                     " © POINTS OF EMISSION
                     Figure 5. A typical instant coffee process.

     Concentrated liquor is drawn off in 500- to 600-pound batches.
At this point, the extract is a brownish fluid containing 30 to 35 percent
solids.  It is filtered to remove residual grounds, and sometimes further
purified by use of a centrifugal clarifier.

     In the final step, the coffee concentrate is spray-dried and becomes
a  powder recognizable as the familiar instant coffee.  The liquor is
sprayed through an atomizer into a huge metal chamber.   The evapor-
ator chamber may be as tall as  80 feet and have a diameter as great as
20 feet.   Figure 6 is a schematic diagram showing such a  drying process.
As the droplets enter the chamber, they meet a. blast of hot air and are
dried  as they fall.   Inlet and outlet temperatures  of the drying air,
which range respectively from 500° to  700°F and 200° to 400°F, deter-
mine the color, taste,  and final moisture content of the product.  To
prevent  the moistened,  hot air from rewetting the dried powder, cold
air is introduced near the bottom of the evaporator.  This  forms a
"dam" that diverts the hot air and creates a calm zone where the par-
ticles settle out.  To recover fines, the exiting air stream is passed
through  a cyclone collector and a high-efficiency  multiple-cyclone  in
series.  Effluent from the secondary collector is usually exhausted into
the atmosphere.  The powdered coffee  is screened to remove lumps,
and stored under controlled humidity (35 to 50 percent at 75°F) until
it is packaged.
               6,7
Disposal of Spent Grounds
     Disposal of spent grounds has been a major problem to the industry.
The most prevalent method is simple elimination into a sewer.  A less
economical alternative is transferring  the waste to a sanitary landfill.
Another method, under  study recently,  is an incineration process.

DECAFFEINATED COFFEE

     Decaffeinated coffee represents only a small fraction of the in-
dustry's total production and is limited to only a few major plant sites,
COFFEE ROASTING INDUSTRY

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          COFFEE
       CONCENTRATE
      HOT AIR STREAM
                                   SPRAY NOZZLE
   COOL AIR "DAM"
       POWDERED COFFEE
                                             EFFLUENT TO MULTIPLE CYCLONES
                          DEHUMIDIFIED COOL AIR
                         —      STREAM
                            J77T
                                 TO STORAGE


               Figure  6. Schematic diagram of instant coffee spray-dryer.
and therefore will be discussed briefly.  Figure 1 shows the process
units used in extracting the caffeine.  The procedure consists of five
main steps:
      SOLVENT
                WASTE
                WATER
                                  CONDENSER
                                    CONDENSER
                                                                 CAFFEINE TO
                                                                  REFINING
                                                      EVAPORATOR
  WATER
SEPARATOR
                                                   SOLVENT
                                                                 COFFEE TO
                                                                  ROASTERS
              Figure 7. Decaffeinated coffee process (W, water; S, steam}.
                                                 AIR POLLUTION IN THE

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     1.   Raising the moisture content of the green bean from 10 percent
         to about  18 percent.
     2.   Extraction with trichloroethylene at 160°F.
     3.   Removal of the  solvent by steaming the coffee for several
         hours.
     4.   Drying the extracted beans.
     5.   The  usual  roasting process.
     Approximately 97 percent of the caffeine is removed and is re-
 covered from the solvent as a valuable byproduct.


               NATURE AND EXTENT OF AIR POLLUTION

 CHEMISTRY  OF COFFEE

     The characteristic odor and flavor of coffee result from the forma-
 tion of esters of chlorogenic acid, furfuryl derivatives,  and other aro-
 matic substances.  Coffee  contains  1 to 2 percent caffeine  (trimethyl-
 xanthin).  The caffeine seems to occur in combination with tannic  and
 caffetannic acids  rather  than alone.   Five crystalline derivatives of
 coffee that are important in its use  as a beverage are caffeine, potas-
 sium chlorogenate, caffalic acid,  valeric acid, and trigonellin.  There
 are also some pyridine-like bodies, furfural,  furfuralcohol,  and cer-
 tain others described generally as "caffeol, " which may be a  pure  sub-
 stance or,  more likely,  a mixture of volatile alcohols and  derivatives.
     As shown in Table 2, many changes occur in coffee  during roasting.
 There is a great loss of  water; the sugar is caramelized and largely
 disappears; and there is a  considerable loss of crude fiber, caused by
 destructive distillation.  About 90 percent of the loss in  weight results
 from elimination of wa-ter vapor and crude  fiber. Also,  during roast-
 ing, there is  a slight gain in the percentage composition of nitrogenous
 substances, sulfur, and  caffeine because they are not broken  down or
 driven off at  roasting temperature.

     Oils and  fatty substances are present in considerable quantity.
 These fats, mostly olein with small amounts of palmitin and  stearin,
 are of both the saturated and unsaturated varieties.  Of the saturated
 fats, which make up about  40 percent of the total fatty matter, the
 compounds of palmitic acid comprise 25 to 28  percent of the  total;
 compounds of carnaubic  acid, 20 percent; capric acid, 5 percent; and
 daturic acid,  1 percent.  Of the unsaturated, fatty acids, compounds
 of oleic and linoleic acids comprise  the greater portion,  linoleic and
 its compounds making up 50  percent of the total fatty material.  ' '• 1(-)

     The ash of coffee is  alkaline, consisting largely of phosphate and
 carbonate  of potash; in Mocha coffee,  salts of magnesium and calcium
 also are found.

 COFFEE ROASTING

     Coffee chaff is  similar to peanut skin and is dark brown.  The
 particles are  large  in relation to most airborne particulates,  attaining
 a maximum size of about 0. 5 inch.   Probably 80 to 90 percent of the

COFFEE ROASTING INDUSTRY                                      9

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 lacroparticles are in the order of 0. 125 inch in diameter.  Smoke and
odor are also produced in the roaster.  These are emitted intermittently
because of the cyclic nature of the roasting process and are composed
of minute droplets  of condensed, organic volatiles.  A weight loss of
about 16 percent  occurs during roasting, of which 2 to 5 percent is dry
weight loss.   The amount of emission is a  function of the grades of
coffee, the method of curing, and the degree and type of roasting.
Stack Emissions
    Data available concerning emission rates from coffee roasters are
limited.  Emissions from different sources in several plants are com-
pared in Table 3.
Table 3.  PARTICULATE EMISSIONS FROM THE COFFEE ROASTING PROCESS
Processes
Direct-fired roaster
Indirect-fired roaster
Cooler
Stone r
Stoner and cooler
combined
Run
1
I
Avg
1
L
3
Avg
1
1
1
2.
Avg
Solid emissions
gr/scf
0.213
0. 173
0. 193
0. 137
0.091
0. 153
0. 127
0. 036
0. 097
0. 026
0. 008
0.017
lb/100'0 Ib
of
green beans
1.26
0. 97
1. 12
0. 44
0. 29
1. 00
0. 58
0. 29
0. 37
0. 22
0. 10
0. 16
Condensed
tar, %
75
87
8J
36
36
-

16
38
27
Control
equipment
Cyclone
Cyclone
Cyclone
Cyclone
Cyclone
Cyc lone
Cyclone
None
None
Cyclone
Cyclone
Cyclone
Reference
number
10
10

12
12
13

10
10
10
13

    As shown in Table 3, the use of low-draft-loss cyclone collector
to treat the effluents of the  cooler and stoner reduces total emissions
by about 70 percent, as compared with corresponding effluents dis-
charged directly into the atmosphere.


    Smoke emission from plants, with and without cyclone collectors,
has been studied.  Typical smoke desities are illustrated in Figure 8.
In general,  during each cycle, which averages  15  minutes, the opacity
is 0-1 Ringelmann at the beginning of each roast; this opacity increases
10
                                            AIR POLLUTION IN THE

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gradually for about 10 minutes, then rapidly for 1  to 3 minutes.  At the
end of the cycle,  characterized by a large cloud of steam from the
•water quench, the smoke density returns to 0-1  Ringelmann.   In con-
trast with indirect-fired units (Figure 8), the 1- to 3-minute peak smoke
emission from direct-fired roasters usually does not exceed No.  2
Ringelmann.
          of  4
          a.  I
                          I      I      1
                       Direct-fired roaster
                          10    15    20    25    30     35    40

                               TIME, minutes
                         10    15    20    25     30     35    40
        Figure  8. Variation of smoke with time batch roasters (References 10 and 12).


     Kuratsune   analyzed soot deposits taken from roaster stacks for
various polycyclic, aromatac hydrocarbons; he discovered the presence
of benzopyrene (about 0. 2 ppm by weight),  a substance known to produce
cancer in experimental animals.
COFFEE ROASTING INDUSTRY
                                                                      11

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INSTANT COFFEE

         The effluent stream from the  spray dryer used in the produc-
tion of instant coffee contains fine,  particulate matter.  The amount
emitted is dependent on the efficiency of the multicyclone  collection
system through which the effluent stream passes and the rate of plant
production.  Naturally, this emission is held to a minimum, as  any loss
is loss of salable product.  This resolves to a  consideration of the  cost
of a highly efficient  collection system versus economic return.  For a
plant producing 1 ton of soluble coffee  per hour,  the particulate  loading
of exit streams would be about 0. 02 grains per cubic foot  at 60°F and
1 atmosphere,  or 0.7 pounds of particulate  per 1,000 pounds of  green
beans.
    In operations where spent coffee grounds are disposed of by in-
cineration,  smoke and odor problems are likely to occur.

DECAFFEINATION

    Loss of solvent is the only emission from  the decaffeination pro-
cess.  This solvent,  trichloroethylene, is a colorless, nonflammable
liquid, has an odor like chloroform, and is  a narcotic and anesthetic.
In a closed plant  operation,  this  would be of more concern to the indus-
trial hygienist  than to air pollution  control personnel.  It should be  re-
membered that in both decaf feination and production of instants the
roasting  process is  also employed and that its  attendant emissions  may
be expected to  be present in these operations.
                METHODS OF CONTROLLING EMISSIONS

PARTICULATE AND SMOKE EMISSIONS

     Because of the size and nature of the dust and chaff particulate,
cyclone collectors provide a simple, economic means of emissions con-
trol.  A simple cyclone will handle, with  great efficiency, emissions
of a size greater than 20 to 40 microns.   It can tolerate temperatures
to 750°F and accommodate flow rates in excess of 25, 000 cfm. 14  Care
must be exercised in removing the  collected solids so that another air
pollution problem is not generated.  In some locations,  the chaff is
burned, with the inherent possibility of creating more smoke and odor.
     Even where cyclones are employed, the submicron particles in
the smoke and the odor leaving the  roaster are not controlled.  There
is, however,  the so-called "smokeless  roaster."  Its manufacturers
claim that this roaster eliminates smoke  and odor completely; however,
all do not accept this claim as entirely true.  A damper system recircu-
lates the combustion gases that are ordinarily vented directly into the
atmosphere through the gas flame of the roaster.   The additional heat
required increases fuel consumption about 40 percent.    This modifi-
cation is shown in Figure 4.  Better smoke control is experienced with
an afterburner in the roaster stack, but fuel requirements are increased
100 to 150 percent over that for a conventional roaster.

12                                           AIR POLLUTION IN THE

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     Other methods of emission control,  such as catalytic oxidation,
scrubbers, and ultrasonic agglomeration of submicron particles to the
point that they be handled by conventional collection equipment, have
been attempted.  They have failed for various reasons,  usually poor
economics or poor performance.

     In modern coffee plants, cyclones are included as an integral part
of the roaster design.  Particularly in installations of small capacity,
however, the effluent air streams from the cleaning,  cooling, and
stoning processes may have no such individual collection system.   In
general, these can be connected in manifold to a common exhaust stack
and  serviced by a single  cyclone  collector.  Efficiency ratings as high
as 97 percent may be expected from such devices.  In some communi-
ties, however, the remaining 3 percent may constitute a nuisance prob-
lem. In such situations, water scrubbers have been used to eliminate
the remaining emission.

SOLUBLE COFFEE EMISSIONS

     Emissions from the production of soluble coffee consist of the  fine,
spray-dried particles that escape the multicyclone system.   This col-
lecting  device has an expected efficiency of 95 percent for particles with
a median diameter greater than  10  to 30 microns. ^   Thus,  the particu-
lates emitted would be expected to be smaller than 10 microns.  Mea-
surements have shown that these particles range from 2 to 10 microns.
The  powder is  very hygroscopic,  which precludes the use of a bag filter
installation since the porosity of  any cloth filter would be  seriously im-
paired by the sticky particles covering its surface.  Cleaning the filters
would be impractical by conventional methods.  The control method
currently used is water scrubbing.  This  takes the form of a simple,
gravity scrubber in which the particle-laden effluent rises countercur-
rently to water droplets falling through an empty tower.   Such a scrub-
ber  is usually constructed of corrosion-resistant material,  such as
stainless steel, because the dissolved coffee is  slightly acidic (pH 4. 8
to 5. 2)  and can cause corrosion.
     The efficiency of the gravity scrubber,  which is dependent on -water
droplet size  and contact time, decreases  rapidly for particles smaller
than 5 microns.  More effective treatment is produced by a  Venturi
scrubber,  which costs more  initially but consumes only half as much
water as the gravity  scrubber and controls the smaller particulates
with a higher efficiency than a gravity scrubber.
COFFEE ROASTING INDUSTRY                                     13
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                            REFERENCES
 1. MacKaye,  Payson.  The  Coffee Man's Manual.  Spice Mill Publish-
    ing Co. , New York.  1942.  pp.  7-17.

 2. Lockhart,  Dr. Ernest E.  Coffee Processing.  McGraw-Hill Ency-
    clopedia of Science and Technology.   I960.   3:265-266.

 3. R. E. Kirk and D. F.  Othmer.  Coffee.  Encyclopedia of Chemical
    Technology.   Inter-Science Encyclopedia Inc. , N. Y.  1954.   4:216.

 4. Bailey, E.H. S.  Food Products,  Their Source, Chemistry and Use.
    Third edition,  Blakiston, New York.   1928.  p. 468.

 5. Annual Coffee Statistics.  Bulletin 25.  Pan American Coffee Bureau.
    1961.  p. 32.

 6. Lawler, Frank K.  Kroger develops instant coffee process.   Food
    Eng. 30:57.  April 1958.

 7. Ritchey, Burton  B.   Controls process for top quality.  Food Eng.
    31:77.  November 1959.

 8. R. E. Kirk and O. F.  Othmer.  Caffein   Extraction  from Coffee.
    Encyclopedia of Chemical Technology.  Inter Science Encyclopedia
    Inc. , N. Y.   1948.  2:741.

 9. Statistical Abstract of the United States.  82nd edition.  U.S. Bureau
    of Census.   1961.  pp.  886-891.

10. Menardi &; Co.  Sampling of emissions and determination of air con-
    taminants.  Los Angeles.  June  9, 1948.  pp. 1-15.   San Francisco
    Bay Area Control District, Uniterm Library No. 3462.

11. Kuratsune, Masaneri.  Polycyclic aromatic hydrocarbons in coffee
    soots.  Proceedings of the American Assoc.  for Cancer Research.
    1957.  pp.  223-224.

12. Menardi & Co.  Sampling roaster stack emissions.  Los Angeles,
    Calif.   Oct.  18,  1948.  San Francisco Bay Area Control District,
    Uniterm Library No. 3508.

13. ibid,  Sampling emissions from coffee roasting plant, Los Angeles,
    Calif. ,  March 10, 1949.  San Francisco Bay Area Control District,
    Uniterm Library No. 3489.

14. Control Equipment for Industrial Particulate Emissions.  Commun-
    ity Air Pollution  Course Manual,  U.S. Department of Health, Edu-
    cation,  and Welfare Public Health Service, Robert A. Taft Sanitary
    Engineering  Center,  Cincinnati,  Ohio.  pp.  1-37.  1961.

15. Robinson, J. L.   What's  new in coffee processing?   Coffee and Tea
    Industries.   82:85.  December 1959.

16. Ukers , H.  International Tea and Coffee Buyers' Guide.  20th
    edition, Tea  and  Coffee Trade Journal,  New  York.  1957.

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