RESEARCH TRIANGLE INSTITUTE
STATUS REPORT #4
STABILITY OF PARTS-PER-BILLION HAZARDOUS ORGANIC
CYLINDER GASES AND PERFORMANCE AUDIT RESULTS
OF SOURCE TEST AND AMBIENT AIR MEASUREMENT SYSTEMS
by
R. K. M. Jayanty
C. K. Sokol
C. E. Decker
Center for Environmental Measurements
Research Triangle Institute
Research Triangle Park, North Carolina 27709
EPA Contract No.: 68-02-4125
D. J. von Lehmden
Quality Assurance Division
Environmental Monitoring Systems Laboratory
Research Triangle Park, North Carolina 27711
Environmental Monitoring Systems Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
January, 1988
POST OFFICE BOX 12194 RESEARCH TRIANGLE PARK, NORTH CAROLINA 27709-2194
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/Wailability of PPB Hazardous Organic Cylinder Gases for Performance Audits:
A. During RCRA Hazardous Waste Trial Burns for POHC
Dul"in9 Ambient Air Measurements of Toxic Organics
The USEPA has available, at no charge, cylinder gases of hazardous organics at the
ppb level that may be used to audit the performance of ambient air and stationary source
measurement systems. Each audit cylinder contains 5 to 18 hazardous organics in a balance
of N2 gas. Audit cylinders are available 1n several concentration ranges. The concentra-
tion of each hazardous organic 1n the audit cylinder is within the range shown. Groups I,
II, III, IV and'V cylinders contain the following hazardous organics:
Group I Compounds
^/Carbon
tetrachlorfde"
vChloroform ^
w Perchloroethylene
vV1nyl chlorld.e \^
Benzene fb
Group II Compounds
x/Trlchloroethylene T
/>• > v.
<£i,2-dlchloroethaneJ "
;. (Ttgnjjbromoethaney
Acetonltrlle
Group I Ranges
roup I
Tto"
90 ppb
90 to 430 ppb
430 to 10.000 ppb
TMchl oro fl uoromethane
(Freon-11)
»
D1chlorod!f1uoromethane
(Freon-12)
Bromomethane
Methyl ethyl ketone
v/l,l,l-tr1chloroethane^
Group II Ranges
7 to 90 ppb
90 to 430 ppb
Group III Compounds
Pyrldlne (In Group III
cylinders but not certified)
Vinyl1dene chloride
I,l,2-tr1chloro-l,2,2-
trlfluoroethane (Freon-113)
1.2-d1chloro-l,l,2,2-
tetrafluoroethane (Freon-114)
Acetone
1-4 Oloxane
^ x
/Tojjjene)
Chlorobenzene
Group III Ranges
7 to 90 ppb ~7
90 to 430 ppb-/
Group IV Compounds
Acrylonltrlle
l,3-Butad1ene
thylene oxide*
Methylene chloride
Pro'pylene oxide*
Ortho-xylenel
-- , .^-^
Mn "Group IV
cylinders, but
not certified
Group IV Ranges
7 to 90 ppb
430 to 10,000
Carbon-terrachlorlde
Chloroform
Perchloroethylene
Vinyl chloride
Benzene
Trlchloroethylene <
l,2-d1chloroethane
,1-trlchloroethane v
Methyl ene' chloride
Trl chl oro fl uoromethane
(Freon 11)
Broraomethane
Toluene
Chlorobenzene
1,3-Butadlene
Ortho-xylene
Ethyl benzene
1,2-dlchloropropane
Group V Rano
i to 4
ppb
The attached Status Report #4 describes results from ambient air and stationary
source measurement audits in Tables 3 and 4. Appendix A shows stability data on some
Groups I, II, III, IV and V cylinders currently available for audits. All audit cylinders
are periodically analyzed to assure that cylinder concentrations have remained stable.
Also, all stability analyses in Appendix A include simultaneous quality control analyses
of ppb hazardous organic gas standards prepared by the National Bureau of Standards for
USEPA.
Recommended procedures are shown in Appendix B for auditing stationary source methods
used for RCRA hazardous waste trial burns. The recommended procedure for auditing the
combined sampling and analyses using a bag collection technique is described in Instruc-
tion Set No. 1. The recommended procedures for auditing combined sampling and analysis
using the Volatile Organic Sampling Train (VOST)2 is described in Instruction Set No. 3.
For the VOST audits, a heated manifold audit gas delivery system (shown as Figure 1 of
Instruction Set No. 3) is also provided with the audit cylinder.
USEPA Program/Regional offices, state/local agencies, and their contractor may
obtain audit cylinders (and audit gas delivery system, 1f applicable) by contacting:
Robert L. Lampe (Phone: Commercial 919-541-4531 or FTS .629-4531)
USEPA, Atmospheric Research and Exposure Assessment Laboratory
Quality Assurance Division (MD-77B)
Research Triangle Park, NC 27711
1 Group V cylinders are available only for ambient air measurement audits
and not RCRA trial burn audits.
2 When a cylinder gas is requested for auditing the VOST method, ask for a
cylinder in the range of 7 to 90 ppb.
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STATUS REPORT #4
STABILITY OF PARTS-PER-BILLION HAZARDOUS ORGANIC
CYLINDER GASES AND PERFORMANCE AUDIT RESULTS
OF SOURCE TEST AND AMBIENT AIR MEASUREMENT SYSTEMS
by
R. K. M. Jayanty
C. K. Sokol
C. E. Decker
Center for Environmental Measurements
Research Triangle Institute
Research Triangle Park, North Carolina 27709
EPA Contract No.: 68-02-4125
D. J. von Lehmden
Quality Assurance Division
Environmental Monitoring Systems Laboratory
Research Triangle Park, North Carolina 27711
Environmental Monitoring Systems Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
January, 1988
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NOTICE
This document has been reviewed in accordance with U.S. Environmental
Protection Agency policy and approved for publication. Mention of trade
names or commercial products does not constitute endorsement or recommenda-
tion for use.
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FOREWORD
Source measurement and monitoring efforts are designed to anticipate
potential environmental problems, to support regulatory actions by develop-
ing data bases needed in developing regulations and to provide means of mon-
itoring compliance with regulations. The Environmental Monitoring Systems
Laboratory, Research Triangle Park, North Carolina, has the responsibility
for implementation of agency-wide Quality Assurance programs for air pollu-
tion measurement systems; and supplying technical support to other groups in
the Agency including the Office of Air and Radiation, the Office of Toxic
Substances, and the Office of Enforcement.
The need for reliable standards for auditing and documenting the accu-
racy of source emission measurement of organic hazardous pollutants is well
established. The Quality Assurance Division of EPA's Environmental Monitor-
ing Systems Laboratory has responded to this need through the development of
compressed gas cylinders containing gaseous organic compounds in parts-per-
billion (ppb) levels. The primary objectives of this on-going project are
(1) to evaluate the quality of measurements made by EPA, state/local agen-
cies, or their contractors, by using ppb gas cylinders for performance au-
dits during hazardous waste trial burn tests and ambient air monitoring
programs; (2) to verify the manufacturer's certified analysis of the multi-
component gas mixtures, (3) to determine the stability of the gas mixtures
with time, and (4) to develop new audit materials as requested by EPA. This
report describes the current status of this project. Included in the report
are (1) a description of the experimental procedures used for the analyses
of multi-component ppb level gas mixtures; (2) a description of the audit
procedure, and (3) currently available audit results and stability data.
Gary 0. Foley.Ph.D.
Director
Environmental Monitoring Systems Laboratory
Research Triangle Park, Nortn Carolina
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ABSTRACT
The U.S. Environmental Protection Agency (USEPA) has evaluated the
suitability of 29 gaseous organic compounds at parts-per-billion (ppb) lev-
els in compressed gas cylinders for use as audit materials during hazardous
waste trial burn tests and ambient air measurements. The primary objectives
of this on-going project are: (1) to evaluate the quality of measurements
made by USEPA, state/local agencies, or their contractors by using ppb gas
cylinders for performance audits during hazardous waste trial burn tests and
ambient air monitoring programs; (2) to verify the manufacturer's certified
analyses of the multi-component gas mixtures; (3) to determine the stability
of the gas mixtures with time; and (4) to develop new audit materials as
requested by USEPA.
The cylinders consist of five mixtures of five, six, eight, nine, and
eighteen organic compounds each. These mixtures were blended by a commer-
cial gas supplier in aluminum cylinders in a balance gas of nitrogen. The
five-component mixture (Group I) contains carbon tetrachloride, chloroform,
tetrachloroethylene (perchloroethylene), vinyl chloride and benzene. The
nine-component mixture (Group II) includes trichloroethylene, 1,2-dichloro-
ethane (ethylene dichloride), 1,2-dibromoethane (ethylene dibromide), aceto-
nitrile, trichlorofluoromethane (F-ll), dichlorodifluoromethane (F-12),
bromomethane (methyl bromide), methyl ethyl ketone and 1,1,1-trichloro-
ethane. The eight-component mixture (Group III) includes pyridine*, vinyl-
idene chloride, l,l,2-trichloro-l,2,2-trifluoroethane (F-113), 1,2-dichloro-
1,1,2,2-tetrafluoroethane (F-114), acetone, 1,4-dioxane, toluene, and
chlorobenzene. The six-component mixture (Group IV) includes acrylonitrile,
1,3-butadiene, ethylene oxide, methylene chloride, propylene oxide, and
o-xylene. The eighteen-component mixture (Group V) includes vinyl chloride,
1,3-butadiene, bromomethane, trichlorofluoromethane (F-ll), methylene
chloride, chloroform, 1,2-dichloroethane, 1,1,1-trichloroethane, benzene,
carbon tetrachloride, 1,2-dichloropropane, trichloroethylene, toluene,
1,2-dibromoethane, tetrachloroethylene, chlorobenzene, ethylbenzene, and
o-xylene. To date 198 performance audits have been initiated and 172 are
*Although Group III cylinders contain pyridine, the concentrations are not
certified due to severe analytical difficulties.
IV
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complete. The results of these audits and a description of the experimental
procedures used for analyses and available stability data are presented in
this status report. Generally, the results of the audits show reasonable
agreement (plus or minus 50 percent) with the audit material concentrations
measured by Research Triangle Institute (RTI), considering the low concen-
trations of the organics and the anticipated uncertainty associated with
independent analyses conducted by an audit laboratory.
Quality assurance of the concentrations of the organics in Groups I - V
is provided by EPA auditing of the audit laboratory (RTI) using NBS-trace-
able standards for these Groups prepared by NBS under a EPA-NBS Interagency
Agreement, and by the subsequent use of the NBS-traceable standards to as-
sign the concentrations in the cylinders obtained from the commercial gas
supplier that are used in this audit program. The NBS-traceable standards
also are used by RTI to ensure quality control in reanalyses conducted over
time to verify the long-term stability of the audit cylinders.
Stability studies for all Group I, Group II, Group III, Group IV and
Group V compounds have been performed. Results have established that all
the compounds tested are suitably stable for use as reliable audit materi-
als except ethylene oxide and propylene oxide at low concentrations.
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CONTENTS
NOTICE ii
FOREWORD i i i
ABSTRACT i v
FIGURES .' i iv
TABLES i i 1v
1. INTRODUCTION 1
OBJECTIVES 1
AUDIT MATERIALS CURRENTLY AVAILABLE 1
2. EXPERIMENTAL PROCEDURES 3
INSTRUMENTATION 3
CALIBRATION 9
SAMPLE ANALYSIS PROCEDURE 9
QUALITY CONTROL PROCEDURES 10
3. PERFORMANCE AUDITS 11
4. STABILITY STUDIES 92
5. SUMMARY AND CONCLUSIONS 95
APPENDIX A STABILITY STUDY FOR GROUP I COMPOUNDS
STABILITY STUDY FOR GROUP II COMPOUNDS
STABILITY STUDY FOR GROUP III COMPOUNDS A-l
STABILITY STUDY FOR GROUP IV COMPOUNDS
STABILITY STUDY FOR GROUP V COMPOUNDS
APPENDIX B AUDIT INSTRUCTIONS 8-1
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FIGURES
Number Page
1 Schematic of the Gas Chromatographic System 4
2 Schematic of the Permeation System 5
3 Schematic of the New Gas Chromatographic System 1
VII
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TABLES
Number Page
1 PPB Level Organic Gases Currently Available 2
2 GC Conditions for Analysis of PPB-Level Cylinder Gases §
2A GC Conditions for Analysis of PPB-Level Cylinder Gases
by Automated Cryogenic Preconcentration 8
3 Summary of Sampling and Analysis Methods Used During
Performance Audits 12
4 Summary of Performance Audit Results 37
VI 1 1
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SECTION 1
INTRODUCTION
OBJECTIVES
The application of Quality Assurance practices is important to the gen-
eration of high-quality environmental data. The Quality Assurance Division
of USEPA's Environmental Monitoring Systems Laboratory has initiated a pro-
gram to supply audit materials for use during hazardous waste trial burn
tests and ambient air measurements. RTI, under contract with USEPA, has
responded to this need through development of cylinder gases containing 29
gaseous organic compounds at ppb levels. The main objectives of this pro-
ject are: (1) to evaluate the quality of measurements made by USEPA, state/
local agencies, or their contractors, by using ppb gas cylinders for per-
formance audits to assess the relative accuracy of source measurement
systems during hazardous waste trial burn tests and ambient air monitoring
programs; (2) to verify the manufacturer's certified analysis of the multi-
component gas mixtures; (3) to determine the stability of the gas mixtures
over time; and (4) to develop new audit materials as requested by USEPA.
This report describes the current status of the project. Included in
the report are: (1) a description of the experimental procedures used for
the analyses of multi-component ppb level gas mixtures; (2) a description of
the audit procedure; and (3) currently available audit results and stability
data.
AUDIT MATERIALS CURRENTLY AVAILABLE
Currently, 29 gaseous compounds selected on the basis of the antici-
pated needs of USEPA's Office of Solid Waste and Office of Air Quality Plan-
ning and Standards have been investigated for suitability as audit materi-
als. Table 1 lists the 29 organic compounds, the concentration ranges, and
the number of cylinders for each group currently available in the ppb level
cylinder gases. Group I cylinders each contain five (5) compounds; Group II
cylinders each contain nine (9) compounds; Group III cylinders each contain
eight (8) compounds; Group IV cylinders each contain six (6) compounds; and
Group V cylinders each contain eighteen (18) compounds. The audit cylinders
fall into three concentration ranges, depending upon the group to which the
cylinder belongs. Each compound in the low concentration range is between 7
and 90 ppb and in the intermediate concentration range is between 90 and 430
-------
ppb. In addition, Group I and Group IV cylinders are available in a high
concentration range between 430 and 10,000 ppb. The Group V cylinders are
available in the concentration range between 1-40 ppb. The balance gas for
all gas mixtures is nitrogen, and the cylinder construction material is
aluminum.
Table 1. PPB Level Organic Gases Currently Available
Group
Group I*
Group II**
Group III***
Group IV****
Group V*****
No. of Cylinders
29
12
12
12
6
14
3
12
6
6
Concentration Range of
Each Compound (ppb)
7-90
90-430
430-10,000
7-90
90-430
7-90
90-200
7-90
430-10,000
1-40
*Group I Compounds: Carbon tetrachloride, chloroform, tetrachloroethyl-
ene, benzene, and vinyl chloride.
**Group II Compounds: Trichloroethylene, 1,2-dichloroethane, 1,2-dibro-
moethane, acetonitrile, trichlorofluoromethane (F-ll), dichlorodifluo-
romethane (F-12), bromomethane, methyl ethyl ketone, and 1,1,1- tri-
chloroethane.
***Group III Compounds: Pyridine(l), Vinylidene Chloride, 1,1,2-
trichloro-l,2,2-trifluoroethane (F-113), l,2-dichloro-l,l,2,2-tetra-
fluoroethane (F-114), acetone, 1,4-dioxane, toluene, and chlorobenzene.
(l)pyridine concentrations are not certified due to analytical
problems
****Group IV Compounds: Acrylonitrile, 1,3-butadiene, ethylene oxide,
methylene chloride, propylene oxide, and o-xylene.
*****Group V Compounds: Vinyl chloride, 1,3-butadiene, bromomethane, tri-
chlorofluoromethane (F-ll), .methylene chloride, chloroform,
1,2-dichloroethane, 1,1,1-trichloroethane, benzene, carbon
tetrachloride, 1,2-dichloropropane, trichloroethylene, toluene,
1,2-dibromoethane, tetrachloroethylene, chlorobenzene, ethylbenzene,
and o-xylene.
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SECTION 2
EXPERIMENTAL PROCEDURES
Accurate analyses of the cylinder gases are required (1) to verify the
concentrations reported by the specialty gas company which prepared the gas
mixtures, and (2) to assess the long-term stability of the concentrations of
the compounds.
INSTRUMENTATION
Analyses of Group I, II and III mixtures are performed prior to 1987
using a Hewlett-Packard 5880A gas chromatograph equipped with flame ioniza-
tion and electron capture detectors. The electron capture detector (ECD) is
used principally for measurement of all the halogenated hydrocarbons except
vinyl chloride. The flame ionization detector (FID) is used for the analy-
sis of vinyl chloride, benzene, methyl ethyl ketone,. acetonitrile, all Group
III compounds, and all of the Group I compounds in the high concentration
range cylinders. The gaseous samples are injected onto the gas chromato-
graphic column by means of two Valco six-port gas sampling valves mounted
near the injection port. One valve is equipped with interchangeable sam-
pling loops (1 cc and 3 cc) to allow the injection of different volumes of
the gas mixtures. A schematic of the gas chromatographic system is shown in
Figure 1. A schematic of the system used for generation of calibration
standards is shown in Figure 2.
The gas chromatographic parameters used in the measurement of individu-
al compounds in Group I, Group II and Group III are listed in Table 2.
Within the past year, a new method was developed for the analysis of
all the ppb level cylinder gases. This method employs automated cryogenic
preconcentration with cryofocusing and flame ionization detection. Analyses
of Group I, II, III, IV, and V mixtures are now performed using a Nutech
automated cryotrapping apparatus configured to. a Hewlett-Packard 5880A gas
chromatograph equipped with a flame ionization detector (FID). A schematic
of the gas chromatographic system is shown in Figure 3.
The gas chromatographic parameters used in the measurement of individu-
al compounds in Group I, Group II, Group III, Group IV and Group V using
this new method are listed in Table 2A.
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Carrier Gas Inlet
Vent
Needle
Valve
High Purity, -n
High Pressure
Needle Valve
Rotameter
(Sample)
GC Oven
ToECD
< or
Nx
FID
GC Column
Valve 2
! ^- Sample Loop
or (Standard)
Permeation System
PPB-Level
Repository Cylinder
Metal Bellows
Sampling Pump (for
use with
Permeation System,
not samples)
Figure 1. Schematic of the Gas Chromatographic System
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Copper
Preheater
Tube for
Nitrogen
Gas
Permeation Vessel
Insulation
30" CESS 100° C
Permeation
Tubes
Mass Flow
Controller
for
Permeation
Chamber
Mass Flow
Controller
(Dilution
Flow)
30° C ± 0.05° C
Large Water Bath/Pump
with Heating/Cooling
Capability
To
Sampling
Valve
GC
Vent for
Excess
Flow
Figure 2. Schematic of the Permeation System
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Table 2. GC Conditions for Analysis of PPB-Level Cylinder Gases
Compounds
Injector
Detector Temp.
Column Temp./
Carrier Gas
Column Type
Comments
GROUP I
Vinyl chloride
Benzene
FID at 200"C
35 cc/min Hydrogen
500 cc/min Air
100°C 80°C, Isothermal/
Nitrogen at 55 cc/min
10 ft. x 1/8" stain-
less steel column
packed with 20% SP
2100 w/0.l% Carbowax
1500, 100/120 mesh
3.0 cc aluminum sample
loop used
Chloroform
Carbon tetrachloride
Perchloroethylene
*ECO at 330°C
100°C 100°C, Isothermal/
Argon w/5% Methane;
at 40 cc/min
10 ft. x 1/8" stain-
less steel column
packed with 20% SP
2100 w/0.1% Carbowax
1500, 100/120 mesh
1.0 cc sample loop used
CT>
GROUP II
Freon 12
Freon 11
Bromomethane
Trichloroethylene
1,2-Dibromoethane
1,2-Dichloroethane
1,1,1-Trichloroethane
ECD at 330°C
100'C 80°C, Isothermal/
Argon w/5% Methane
at 2 cc/min
30 cc/min make-up
60 m x 0.32 mm OB-1
Capi1lary Column
1.0 cc sample loop used
Acetonitrile and
Methyl Ethyl Ketone
FID at 200"C
35 cc/min Hydrogen
500 cc/min Air
100'C 170°C, Isothermal/
Nitrogen at 35 cc/min
6 ft. x 1/8" stain-
less steel column
packed with Porapak Q,
60/80 mesh
3.0 cc aluminum sample
loop used; conditioned
the column 1 day
GROUP III
Freon 114
Freon 113
Vinylidiene
Chloride
Acetone
Toluene
1,4-Dioxane
Chlorobenzene
FID at 200°C
35 cc/min Hydrogen
500 cc/min Air
150°C 120°C, Isothermal/ 20 ft. x 1/8" stain-
Nitrogen 40 cc/min less steel column
packed with 10% SP-
1000, 80/100 Supelco-
port
3.0 cc aluminum sample
loop used
*The ECU was necessary only for low concentration level cylinders. For intermediate and high level cylinders, FID at the stated
conditions was used.
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Cryogenic Preconcentration Apparatus
Carrier
Gas
Inlet
Single Stage,
High Purity,
High Pressure
Regulator
Cryofocusing
Trap
I
Mass Flow
Controller
*
FID
GC Oven
Cryogen Trap/Sample Loop
PPB-Level
Repository
Cylinder
Figure 3. Schematic of the gas chrbmatographic system.
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CO
Table 2A. GC Conditions for Analysis of PPB-Level Cylinder Gases by Automated Cryogenic Preconcentration*
Groups Detector
I, II, III, IV and V FID at 275°C
30 cc/ini n Hydrogen
360 cc/inin Air
Injector Temp, program/
Temp. Carrier Gas
100°C 35°C for 4 min
6°C/min to 90°C
15°C/min to 170°C
Helium at 2 cc/min
Column Type
Chrompack •
WCOT Fused Silica
50 m x 0.32 mm ID.
CP-SIL-5 CB Coating
Comments
1.5 cc Stainless Steel
loop used. 100 ml of
sample concentrated.
*Analyses described in Table 2 were discontinued during 1987 for Groups I, II and III. The cryogenic system described here is used now
for the analyses of Groups I, II, III, IV and V.
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CALIBRATION
Calibration of the gas chromatograph involves measurement of known con-
centrations of organic gases in nitrogen. A custom-designed permeation sys-
tem which produces known concentrations of organics in nitrogen had been
used for all previous analyses of Group I and II cylinders prior to 1987.
The details of the calibrations performed using permeation tubes are
described previously (3). Currently, NBS-traceable standards developed and
characterized by the National Bureau of Standards (NBS) under an EPA-NBS
Interagency Agreement are being used for calibration for all five groups and
a similar NBS standard cylinder mixture is used for Quality Control for all
the analyses with the cryogenic preconcentration system. One NBS-traceable
standard is used as a calibration cylinder that is analyzed at the beginning
of each analysis day and a second similar NBS-traceable standard is used as
a Quality Control cylinder that is subsequently analyzed on each analysis
day.
SAMPLE ANALYSIS PROCEDURE
Figures 1 and 2 depict the entire analytical system used for the cali-
bration and analysis of the gas mixtures prior to 1987.
Figure 3 depicts the analytical system that is used for calibration and
analysis of the gas mixtures by automated cryogenic preconcentration with
cryofocusing. All analyses are now done with this method. The procedure
used for the sample analysis by this method is as follows: The gaseous sam-
ple is taken from the high pressure cylinder via a one-stage high pressure
regulator. Sampling rate is controlled by a mass flow controller. Sample
is delivered to the cryogenic preconcentration apparatus using a six-port
gas sampling valve mounted on the inside of the apparatus. A second six-
port gas sampling valve is used to direct sample flow through a 1.5 cc
stainless steel loop packed with 60-80 mesh glass beads. Initially, the
sample loop is purged with cylinder gas sample at approximately 100 cc/min
for 5 minutes. After purging the sample trap, the gas flow is shut off at
the second six-port gas sampling valve. The sample trap is then cooled down
to a selected temperature (approx. -150°C). Once the sample trap has
reached this selected temperature, gas flow is allowed to pass through the
sample trap and trapping of the gas mixture begins. After a pre-determined
time, injection is made automatically onto the column by heating the sample
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trap. The concentrated sample is then re-focused at the head of the capil-
lary column for two minutes. The cryofocusing trap is then heated and the
actual injection is made. Triplicate injections of the sample are made to
determine the measurement precision. Generally, the measurement precision
is within three percent.
QUALITY CONTROL PROCEDURES
On each analysis day, the cryogenic analysis system is calibrated with
either a Group I, II, III, IV or V primary gas standard prepared and anal-
yzed by the National Bureau of Standards as part of an Interagency Agreement
with USEPA. Following the calibration, a second NBS primary gas standard is
analyzed as a quality control check to verify the accuracy of the calibra-
tion. These RTI quality control results are shown in Appendix A (stability
study). Appendix A contains a summary table for each Group I, II, III, IV
and V cylinder analyzed. Included in each summary table are the RTI stabil-
ity analysis and the RTI quality control result on the day the stability
analysis was conducted.
10
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SECTION 3
PERFORMANCE AUDITS
Research Triangle Institute supplies cylinder gases for audits upon
request from USEPA, state or local agencies or their contractors. A con-
tractor must be performing hazardous waste trial burn tests or ambient air
measurements at the request of USEPA, a state or local agency in order to
qualify for the performance audit. When a request is received, the cylinder
pressures are measured and the cylinders are shipped by overland carrier.
When a cylinder gas is used to audit the VOST system for a trial burn test,
an aluminum suitcase is also sent. The aluminum suitcase contains a gas .
regulator, a heated glass manifold, and necessary tubing and fittings to
draw the cylinder gas sample into the glass manifold. The audit gas is then
drawn at atmospheric pressure from the manifold into the VOST system. A
schematic of this audit gas delivery system is shown in Appendix B, Figure
1. A letter is included with the audit cylinder which gives general
instructions for conducting the audit (see Appendix B). Detailed instruc-
tions are shown in Appendix B for conducting an audit of VOST (Instruction
No.- 3) and bag measurements (Instruction No. 1) during a hazardous waste
trial burn. The audit gas concentration for each compound and cylinder gas
pressure are provided to the requesting agency audit coordinator. There is
no charge for the audit, except for the cost of returning the audit cylin-
der.
To date, 198 performance audits have been initiated; 170 are complete.
The sampling and analysis methods used by auditees during performance audits
are summarized in Table 3. The audit results currently available are pre-
sented in Table 4. The audit results are usually within +_ 50 percent of the
audit concentrations measured by RTI.
11
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Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits
Audit No.
Client*
Use of Audit Material
Measurement System Audited
1A A
IB A
2A B
2B B
3 C
4 D
5 Region V
U.S. EPA
6 Combustion
Research
Facil ity
U.S. EPA
VOST method evaluation
BAG method evaluation
(RCRA testing)
VOS.T method evaluation
BAG method evaluation
(RCRA testing)
VOST method evaluation
VOST method evaluation
Hazardous waste in-
cineration trial burn
analysis evaluation
VOST method evaluation
Sampling by VOST method
Analysis by GC/MS
Sampl ing by BAG
Analysis by GC/FID-ECD
Sampling by VOST method
Analysis by GC/MS
Sampling by BAG
Analysis by GC/ECD-PID
Sampling by VOST
Analysis by GC/P ID-Hall Detector
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Hazardous waste in-
cineration burn analysis
evaluation
Direct analysis by GC/ECD
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No. Client*
8 F
9 Region III
U.S. EPA
10 . C
11 B
12 . B
13 E
Use of Audit Material
VOST method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
VOST method evaluation
VOST method evaluation
Hazardous waste incinera-
Measurement System Audited
Sampling by VOST
Anlysis by GC/MS
Sampling method unknown
Analysis by GC/FID
Sampling method unknown
Analysis by GC/FID
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Direct analysis by GC/ECD
14
15
16A
Region VI
U.S. EPA
G
tion trial burn anaysis
evaluation
Hazardous waste incinera-
tion trial burn analysis
evaluation
Ambient air monitoring
instrument checkout
Ambient air measurement
method evaluation
Direct analysis by GC/ECD
Analysis by ambient hydrocarbon
analyzer
Analysis by cryogenic preconcen-
tration followed by GC/FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
16B
17
ISA
188
G
H
I
I
Ambient air measurement
method evaluation
Hazardous waste in-
cineration trial burn
Ambient air measurement
method evaluation
Ambient air measurement
Analysis by cryogenic preconcen-
tration followed by GC/FID
Sampling by VOST
Analysis by GC/MS
Analysis by direct injection
followed by GC/ECD
Method 1 sampling by Tedlar bags
method evaluation
and Tenax-charcoal with analysis
by GC/ECD
Method 2 sampling by Tenax-
charcoal with analysis by GC/FID
18C I
19 B
20 J
21 K
Ambient air measurement
method evaluation
Hazardous waste in-
cineration trial burn
Hazardous waste in-
cineration trial burn
Hazardous waste in-
cineration trial burn
Analysis by cryogenic preconcen-
tration followed by GC/FID
Sampling by VOST
Analysis by GC/MS
Direct analysis by MS/MS
Sampling method unknown
Analysis by GC/ECD or FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used Duriny Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
22
23
24
25
26
27A
27B
27C
M
G
I
N
I
Hazardous waste incinera-
tion trial burn
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Hazardous waste in-
cineration trial burn
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Sampling by VOST
Analysis by GC/MS
Sampling method unknown
Analysis by GC/FID/ECD/PID/Hall
detectors
Analysis by cryogenic preconcen-
tration followed by GC/FIO
Sampling method unknown
Analysis method unknown
Sampling by glass bulb
Analysis by GC/Hall detector
Sampling into Tedlar bags followed
by cryogenic preconcentration
analysis by GC/ECD
Sampling by Tedlar bags
Analysis by direct injection into
GC/ECD
Method 1: sampling by Tedlar bags
and Tenax trap with analysis by
GC/FID Method 2: sampling by
Tedlar bag with analysis by
direct injection into GC/ECD
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
28
29
30A
308
31
32
33
34
0
B
P
P
Q
B
Hazardous waste in-
cineration trial burn
Hazardous waste incinera-
tion sampling method
evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Hazardous waste incinera-
tion sampling method
evaluation
Hazardous waste incinera-
tion sampling method
evaluation
Ambient air measurement
method evaluation
Sampling
Analysis
Sampling
Analysis
by VOST
by GC/MS
by
by
VOST
GC/MS
Sampling method unknown
Analysis by GC/ECD
Sampling method unknown
Analysis by GC/ECD
Sampling method unknown
Analysis method unknown
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Tenax-charcoal tubes
Analysis method unknown
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
35
36
37
38
39
40
Client*
C
C
S
L
L
T
Use of Audit Material
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Hazardous waste incinera-
tion VOST method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
Measurement System Audited
Sampling by Direct injection and
cryotrap with Analysis by MS
Sampling by Direct injection and
cryotrap with Analysis by MS
Sampling by VOST
Analysis by GC/FID
Direct analysis by GC/FID
Sampling on charcoal
Analysis by GC/MS
Sampling by Tenax loading
41
42
(Lab A)
42
(Lab A)
method evaluation (haz-
ardous waste landfill)
Ambient air measurement
method evaluation (haz-
ardous waste landfill)
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Analysis by GC/MS
Sampling by Tenax loading
Analysis by GC/MS
Sampling by Tedlar bags
Analysis by GC/ECD/PID
Sampling by Tedlar bags
Analysis by GC/ECD/FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
42
(Lab B)
42
(Lab B)
42
(Lab C)
42
(Lab C)
42
(Lab D)
42
(Lab D)
43
(Lab A)
43
(Lab A)
I
P
GG
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Sampling into Tedlar bags followed
by preconcentration on Tenax-char-
coal trap
Analysis by GC/FID and GC/ECD
Sampling by Tenax-charcoal trap
Analysis by GC/FID and GC/ECD
Sampling into Tedlar bags followed
by cryogenic preconcentration
Analysis by GC/PID
Sampling into Tedlar bags followed
by cryogenic preconcentration
Analysis by GC/PID
Sampling into Tedlar bags followed
by cryogenic preconcentration
Analysis by GC/ECD
Sampling by Tedlar bags followed
by cryogenic preconcentration
Analysis by GC/ECD and GC/PID
Analysis by direct injection into
GC/ECD
Analysis by GC/ECD
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
44
45
46
47
48
49
50
51
(Lab A)
51
(Lab B)
U Hazardous waste incinera-
tion trial burn
U Hazardous waste incinera-
tion trial burn
V Ambient air analysis
method evaluation
H Hazardous waste incinera-
tion trial burn
Region III Ambient air measurement
U. S. EPA method evaluation
Region III Ambient air measurement
U. S. EPA method evaluation
V Ambient air measurement
method evaluation
I Ambient air measurement
at hazardous waste land-
fill
I Ambient air measuranent
at hazardous waste land-
fill
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Tedlar bags
Analysis by portable GC/PID
Sampling by Tedlar bags
Analysis by portable GC/PID
Analysis by cryogenic trapping
followed by GC/ECD/FID
Sampling by Tedlar bags
Analysis by GC/PID
Sampling by Tedlar bags
Analysis by GC/PID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
1X1
o
52
53
54
55
56
57
58
59
Region II
U. S. EPA
Region II
U. S. EPA
Y
V
I
Ambient air measurement
at hazardous waste land-
fill
Hazardous waste incinera-
tion trial burn
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air analysis
method evaluation
Ambient air measurement
method evaluation
Ambient air analysis
method evaluation
Ambient air measurement
method evaluation at haz-
ardous waste landfill
Sampling by Tedlar bags
Analysis by GC/PID
Sampling by VOST
Analysis by GC/MS
Analysis by direct injection
using CI/MS/MS
Analysis by direct injection
using CI/MS/MS
Direct analysis by portable
GC/PID
Sampling by Tenax cartridges
Analysis by GC/FID
Analysis by cryogenic trapping
followed by GC/FID/ECD
Direct analysis by portable
GC
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
60
(Lab A)
6U
(Lab A)
60
(Lab B)
60
(Lab C)
60
(Lab D)
61
62
ASRL
U. S. EPA
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste 1 and-
fill
Ambient air analysis
method evaluation
Sampling into Tedlar bags
Analysis by GC/ECD
Sampling into Tedlar bag
Analysis by GC/ECD
Sampling into Tedlar bag
Analysis by GC/ECD
Analysis by cryogenic trapping
followed by GC/PID/ECD
Analysis by cryogenic trapping
followed by GC/ECD
Direct analysis by portable
GC
Direct analysis by
GC/F ID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
no
63
64
65
66
67
68
69
70
JJ
JJ
JJ
KK
KK
Z
Z
AA
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measuranent
at hazardous waste land-
fill
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Direct analysis by TAGA 6000
MS/MS system
Direct analysis by TAGA 6000
MS/MS system
Direct analysis by TAGA 6000
MS/MS system
Direct analysis by TAGA 6000
MS/MS system
Direct analysis by TAGA 6000
MS/MS system
Sampling into Tedlar bags
Analysis by GC/ECD
Sampling by VOST
Analysis by GC/ECD
Sampling by VOST
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
CO
Audit No.
71
72
73
74
75
Cl i ent*
HH
HH
HH
USEPA
ASRL (RTP)
II
Use of Audit Material
Hazardous waste incinera-
tion (boiler)
Hazardous waste incinera-
tion (boiler)
Hazardous waste incinera-
tion (boiler)
Ambient air analysis
method evaluation
Ambient air measurement
Measurement System
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Direct analysis by
GC/FID
Direct analysis by
Audited
TAGA 6000
76
77
78
C
C
at hazardous waste land-
fill
Ambient air analysis
method evaluation
Ambient air analysis
method evaluation
Ambient air analysis
method evaluation
MS/MS
Analysis by cryogenic pre-
concentration followed by
GC/FID/ECD
Analysis by cryogenic trapping
followed by GC/FID
Analysis by cryogenic trapping
followed by GC/FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No. Client*
79 H
80 H
81 H
82 CC
83 DO
84 DD
85 DD
86 EE
87 FF
88 H
Use of Audit Material
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Hazardous waste incinera-
tion trial burn
Ambient air measurement
at hazardous waste landfill
Hazardous waste incinera-
tion trial burn
Measurement System Audited
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Tedlar bags
Analysis by GC/FID
Sampling by Tedlar bags
Analysis by GC/FID
Sampling by VOST
Analysis by GC/FID
Sampling by VOST
Analysis by GC/ECD
Direct analysis by TAGA 6000
MS/MS system
Sampling by VOST
Analysis by GC/ECD
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
9b
96
97
98
Client*
MM
VV & NN
VV £ NN
00
Use of Audit Material
Measurement System Audited
89 Z
90 Z
91 LL
92 LL
93 W
94 H
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
i
Hazardous waste incinera-
tion trial burn
Hazardous waste incinera-
tion trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Sampling by Tedlar bag
Analysis by GC/ECD
Sampling by Tedlar bag
Analysis by GC/ECD
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by cryogenic preconcen-
tration with Analysis by GC/FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
99
100
(Lab A)
100
(Lab B)
100
(Lab C)
100
(Lab D)
100
(Lab E)
100
(Lab F)
100
(Lab G)
101
102
00
I
I
I
I
I
I
I
H
H
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Sampling by cryogenic preconcen-
tration with Analysis by 6C/FID
Sampling by Tedlar bag
Analysis by GC/PID/ECO
Sampling by Tedlar bag
Analysis by GC/PID/ECO
Sampling by Tedlar bag
Analysis by GC/PID/ECO
Sampling by Tedlar bag
Analysis by GC/PID/FID/ECD
Sampling by Tedlar bag
Analysis by GC/ECD
Sampling by Tedlar bag
Analysis by GC/PID/ECD
Sampling by Tedlar bag
Analysis by GC/PID/ECD
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
103
104
105
106
107
108
109
110
111
112
Client*
HH
HH
PP
I
HH
HH
QQ
QQ
RR
W
Use of Audit Material
Hazardous
Hazardous
Hazardous
Hazardous
emissions
Hazardous
Hazardous
Hazardous
Hazardous
Hazardous
emissions
Hazardous
waste
waste
waste
trial
trial
trial
waste landfi
monitoring
waste
waste
waste
waste
trial
trial
trial
trial
waste landfi
monitoring
waste
trial
burn
burn
burn
11
burn
burn
burn
burn
11
burn
Measurement
Sampl ing
Analysis
Sampling
Analysis
Sampl ing
Analysis
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampl ing
Analysis
Sampling
Analysis
Sampl ing
Analysis
Sampling
Analysis
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
System
VOST
GC/MS
VOST
GC/MS
VOST
GC/MS
Audited
Tedlar bag
GC/FID/ECD
Tedlar
GC/ECD
VOST
GC/MS
Tedl ar
GC/FID
Tedlar
GC/FID
Tedlar
GC/Hall
VOST
GC/MS
bag
bag
bag
bag
/PID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
ro
oo
Audit No.
113
114
115
116
117
118
(Lab A-F)
119
120
121
122
Client*
W
V
V
H
TT
I
SS
ww
XX
XX
Use of Audit Material
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Measurement System Audited
Sampling by VOST
Analysis by GC/MS
Di rect Analysis
by GC/MS
Di rect Analysis
by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Direct injection
Analysis by GC/FID/ECD
Sampling by Tedlar bag
Analysis by GC/PID/FID/ECD
Sampling by Direct injection
Analysis by GC/PID
Sampling by Direct injection
Analysis by GC/PID
Sampling by Tedlar bag
Analysis by GC/ECD
Sampling by Tedlar bag
Analysis by GC/FID
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
ro
Audit No.
130
(Lab A-F)
131
132
Client*
I
H
Use of Audit Material
Measurement System Audited
123
124
125
126
127
128
129
TT
YY
YY
ZZ
HH
KK
KK
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste landfill
emissions monitoring
Hazardous waste landfill
Sampling by Tedlar bag
Analysis by GC/FID/ECD
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Tenax cartridge
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Charcoal tube,
Analysis by GC/MS
Sampling by Charcoal tube,
VOST
VOST
emissions monitoring
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Analysis by GC/MS
Sampling by Tedlar bag
Analysis by GC/ECD/PID/FID
Sampling by Tedlar bag
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
133
134
135
136
137
138
139
140
141
142
Client*
RR
UU
UU
UU
0
0
HH
Region VII
Region VII
Q
Use of Audit Material
Hazardous waste landfill
emissions monitoring
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Measurement System Audited
Sampling by Tedlar bag
Analysis by GC/Hall/PID
Sampling by Tenax cartridge
Analysis by GC/FID/ECD/PIO
Sampling by Tenax cartridge
Analysis by GC/FID/ECD/PID
Sampling by Tenax cartridge
Analysis by GC/FID/ECD/PID
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Cryogenic trap
Analysis by GC/FID
Sampling by Cryogenic trap
Analysis by GC/FID
Sampling by VOST
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
143
144
145
146
147
148
149
150
151
152
Client*
AC
VV
VV
AE
AE
AE
A
A
AH
AH
Use of Audit Material
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Measurement System Audited
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Tedlar bag
Analysis by col ori metric method
Sampling by Tedlar bag
Analysis by col ori metric method
Sampling by Tedlar bag
Analysis by col ori metric method
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by Direct injection
Analysis by TAGA MS/MS
Sampling by Direct injection
Analysis by TAGA MS/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
OJ
ro
Audit No.
153
154
155
156
157
158
159
160
161
162
Client*
HH
HH
AI
AI
AI
X
AF
AJ
AG
AG
Use of Audit Material
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Measurement System Audited
Sampl ing by VOST
Analysis by GC/MS
Sampl ing by VOST
Analysis by GC/MS
Sampling by Tenax/carbon molecular
sieve with Analysis by GC/MS
Sampling by Tenax/carbon molecular
sieve with Analysis by GC/MS
Sampling by Tenax/carbon molecular
sieve with Analysis by GC/MS
Sampling by Direct injection
Analysis by GC/PID
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
00
CO
163
164
HH
HH
Hazardous waste landfill
emissions monitoring
Hazardous waste landfill
Sampling by Tenax/canister
Analysis by GC/MS
Sampling by Tenax/canister
165
(Lab A-E)
166
167
168
169
170
171
172
USEPA-ERT
Edison, NJ
USEPA-ERT
Edison, NJ
USEPA-ERT
Edison, NJ
USEPA-ERT
Edison, NJ
AK
AK
AL
emissions monitoring
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial
burn
Hazardous waste trial
burn
Ambient air monitoring
method evaluation
Analysis by GC/MS
Sampling by Tedlar bag
Analysis by GC/PID/ECD/FID
Sampling by Tedlar bag
Analysis by GC/FID
Sampling by Tedlar bag
Analysis by GC/FID
Sampling by Tedlar bag
Analysis by GC/FID
Sampling by Tedlar bag
Analysis by GC/FID
Sampling by Direct injection
Analysis by GC/ECD
Sampling by Direct injection
Analysis by GC/ECD
Sampling by Tedlar bag
Analysis by GC/MS
(Conti nued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
173
174
175
176
177
178
179
180
181
182
Client*
AL
AL
I
I
I
AM
AM
QQ
W
RR
Use of Audit Material
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste landfill
emissions monitoring
Measurement
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampling
Analysis
Sampl ing
Analysis
Sampling
Analysis
Sampling
Analysis
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
by
System Audited
Tedlar bag
GC/MS
Tedlar bag
GC/MS
Tedlar bag
GC/PID/Hall
Tedlar bag
GC/PID/Hall
Tedlar bag
GC/PID/Hall
Tedlar bag
GC/MS
Tedlar bag
GC/MS
VOST
GC/MS
VOST
GC/MS
Tedlar bag
GC/PID/Hall
detector
detector
detector
detector
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
183
184
185
186
187
188
189
190
191
Client*
HH
A
0
0
A
QQ
AN
AN
JJ
Use of Audit Material
Hazardous waste landfill
emissions monitoring
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste trial burn
Hazardous waste landfill
emission measurements
Measurement System Audited
Sampling by Tenax/canister
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by cryogenic trap
Analysis by GC/FID/ECD/PID
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
Sampling by direct injection
Analysis by GC/MS
(Continued)
-------
Table 3. Summary of Sampling and Analysis Methods Used During Performance Audits (Continued)
Audit No.
Client*
Use of Audit Material
Measurement System Audited
00
en
192
193
194
195
196
197
198
JJ
KK
KK
A
AD
Hazardous waste landfill
emissions monitoring
Hazardous waste landfill
emissions monitoring
Hazardous waste landfill
emissions monitoring
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Ambient air monitoring
method evaluation
Hazardous waste trial burn
Sampling by direct injection
Analysis by GC/MS
Sampling by stainless steel
canister
Analysis by GC/MS
Sampling by stainless steel
canister
Analysis by GC/MS
Sampling by tedlar bag
Analysis by GC/PID/Hall Detector
Sampling Method 1: Tenax
cartidge
Sampling Method 2: Carbosive/
carbotrap in series
Anlaysis, both GC/MS
Sampling by Tenax Cartridge
Analysis by GC/MS
Sampling by VOST
Analysis by GC/MS
*Whenever the auditee is known, an alphabetical letter is shown. Whenever the auditee is unknown,
the name of the agency requesting the audit is shown.
-------
Table 4. Summary of Performance Audit Results
Audit
No. Client*** Use of Audit Material Audit Material
1A A VOST method evaluation Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
IB A BAG method evaluation Carbon Tetrachloride
(RCRA Testing) Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
2A B VOST method evaluation Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
28 B BAG method evaluation Carbon Tetrachloride
(RCRA Testing) Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
3 C VOST method evaluation Carbon Tetrachloride
Chloroform
Benzene
RTI Audit
Cone, (ppb)
21.0 ± 1.0
23.0 ± 1.0
29.0 ± 2.0
18.0 ± 1.0
31.0 ± 1.0
141 ± 3.0
120 ± 3.0
126 ± 3.0
133 ± 3.0
154 ± 3.0
21.0 ± 1.0
23.0 ± 1.0
29.0 ± 2.0
18.0 ± 1.0
31.0 ± 1.0
141 ± 3.0
120 ± 3.0
126 ± 3.0
133 ± 3.0
154 ± 3.0
21.0 ± 1.0
23.0 ± 1.0
18.0 ± 1.0
Client
Audit
% Bias
(avg.)*
-50
0
+17
+31
-50
+60
+34
+31
+18
-33
+27
+28
+34
+32
-66
-13
-16
-44
-27
-34
+10
+20
-9
Status
of
Audit**
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
CD
Audit
No. Client***
4 D
5 Region V
U.S. EPA
6 Combustion
Research
Facility
U.S. EPA
7 E
8 F
Use of Audit Material
VOST method evaluation
Hazardous waste in-
cineration trial burn
analysis evaluation
VOST method evaluation
Hazardous waste in-
cineration burn analy-
sis evaluation
VOST method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
21.0 ± 1.0
23.0 ± 1.0
29.0 ± 2.0
18.0 ± 1.0
31.0 ± 1.0
11.0 ± 0.3
45.0 ± 0.9
20.5 ± 0.7
9.9 ± 0.3
42.0 ± 0.9
9.6 ± 0.2
20.0 ± 0.6
11.8 ± 0.4
10.5 ± 0.2
21.0 ± 1.0
23.0 ± 1.0
29.0 ± 2.0
18.0 ± 1.0
31.0 ± 1.0
Client
Audit Status
% Bias of
(avg.)* Audit**
-14 B
-20
+17
+6
-10
-31 B
+200
+7
+22 B
0
+40
+3
-3 B
+86
NA C
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material
9 Region III Ambient air measure-
U.S. EPA ment method evaluation
10 C Ambient measurement
method evaluation
11 B VOST method evaluation
12 B VOST method evaluation
13 E Hazardous waste in-
cineration trial burn
analysis evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
RTI Audit
Cone, (ppb)
9.3 ± 0.3
40.0 ± 0.8
9.4 ± 0.2
20.0 ± 0.6
19.0 ± 0.6
323 ± 9.7
128 ± 2.7
119 ± 2.9
379 ± 12.1
403 ± 12.1
11.0 ± 0.3
47.4 ± 1.0
11.3 ± 0.3
25.2 ± 0.8
19.8 ± 0.6
6.6 ± 0.2
7.4 ± 0.2
21.9 ± 0.5
26.0 ± 0.8
29.6 ± 0.9
11.6 ± 0.4
10.2 ± 0.2
Client
Audit Status
% Bias of
(avg.)* Audit**
NA C
NA
NA
NA
NA
+6 B
+4
-3
-2
-3
+5 B
+3
+5
-7
-85
+21 B
+ 12
+56
+47
-52
+11 B
+100
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
Mo. Client*** Use of Audit Material
14 E Hazardous waste in-
cineration trial burn
analysis evaluation
15 Region V Ambient air monitoring
U.S. EPA instrument checkout****
16A G Ambient air measure-
ment method evaluation
16B G Ambient air measure-
ment method evaluation
17 H Hazardous waste in-
cineration trial burn
Audit Material
Carbon Tetrachloride
Chloroform
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chi orof orm
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chi orof orm
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
24.0 ± 0.7
16.0 ± 0.3
11.0 ± 0.3
47.4 ± 1.0
11.3 ± 0.3
25.2 ± 0.8
13.4 ± 0.4
12.4 ± 0.3
75.6 ± 1.8
51.2 ± 1.6
29.6 ± 0.9
13.4 ± 0.4
12.4 ± 0.3
75.6 ± 1.8
51.2 ± 1.6
29.6 ± 0.9
9.9 ± 0.3
42.0 ± 0.9
9.6 ± 0.2
20.0 ± 0.6
19.8 ± 0.6
Client
Audit
% Bias
(avg.)*
-25
+31
-45
+58
-68
-56
+1
+5
+18
-9
+7
+98
+140
+13
-8
+6
-19
-32
-14
-21
-41
Status
of
Audit**
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
18A I Ambient air measurement
method evaluation
ISA I Ambient air measurement
method evaluation
18B I Ambient air measurement
method evaluation
18B I Ambient air measurement
method evaluation
18C I Ambient air measurement
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
132 ± 4.0
129 ± 2.7
136 ± 3.3
9.5 ± 0.3
40.6 ± 0.9
9.5 ± 0.2
132 ± 4.0
129 ± 2.7
136 ± 3.3
146 ± 4.7
153 ± 4.9
9.5 ± 0.3
40.6 ± 0.9
9.5 ± 0.2
19.4 ± 0.6
20.6 ± 0.7
132 ± 4.0
129 ± 2.7
136 ± 3.3
146 ± 4.7
153 ± 4.9
Client
Audit Status
% Bias of
(avg.)* Audit**
-17 B
+16
+18
-23 B
+1
+16
+38 B
+27
+34
+11
-5
+58 B
+35
+332
+240
-3
NA C
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
18C I Ambient air measurement
method evaluation
19 B Hazardous waste in-
cineration trial burn
20 J Hazardous waste in-
cineration trial burn
21 K Hazardous waste in-
cineration trial burn
22 L Hazardous waste in-
cineration trial burn
Audit Material
Benzene
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
19.4 ± 0.6
11.6 ± 0.3
11.6 ± 0.3
10.2 ± 0.2
67.7 ± 1.6
45.2 ± 1.4
29.8 ± 1.0
10.8 ± 0.3
47.1 ± 1.0
10.3 ± 0.2
23.2 ± 0.7
20.1 ± 0.6
12.7 ± 0.4
12.3 ± 0.3
62.2 ± 1.5
48.0 ± 1.5
31.3 ± 1.0
Client
Audit Status
% Bias of
(avg.)* Audit**
-2 B
+28 B
NA C
NA
NA
NA
NA
NA C
NA
NA
NA
NA
-21 B
-27
-44
-63
-81
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
23 M Ambient air measurement
method evaluation
24 G Ambient air measurement
method evaluation
25 I Ambient air measurement
method evaluation
26 N Hazardous waste in-
cineration trial burn
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Methyl Ethyl Ketone
Trichl oroethyl ene
1 ,2-Dichl oroethane
1 ,1 ,1-Trichl oroethane
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Tri chl orof 1 uoromethane
Di chl orod i f 1 uoromethane
RTI Audit
Cone, (ppb)
15.7 ± 0.5
15.2 ± 0.3
15.7 ± 0.4
18.2 ± 0.6
15.4 ± 0.5
19.4 ± 1.1
14.7 ± 0.7
14.4 ± 0.7
14.5 ± 0.7
7.1 ± 0.2
8.1 ± 0.2
21.1 ± 0.5
29.9 ± 1.0
32.0 ± 1.0
15.4 ± 0.5
16.6 ± 0.7
Client
Audit
% Bias
(avg.)*
-5
+5
+2
-12
-29
+18
+16
+164
+110
-16
-26
+4
-20
-31
-42
-10
Status
of
Audit**
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
27A I Ambient air measurement
method evaluation
27A I Ambient air measurement
method evaluation
278 I Ambient air measurement
method evaluation
27B I Ambient air measurement
method evaluation
27C I Ambient air measurement
method evaluation
Audit Material
Trichloroethylene
1 ,2-Dichloroethane
1,2-Dibromoethane
Trichl oroethyl ene
1 ,2-Dichl oroethane
1,2-Dibromoethane
1,1,1-Trichloroethane
Trichl oroethyl ene
Trichlorofluoromethane
Dichlorodifluoromethane
1 ,2-Dibromoethane
Tri chl oroethyl ene
1 ,2-Dichloroethane
Trichlorofluoromethane
Dichlorodifluoromethane
1,2-Dibromoethane
1 ,1 ,1-Trichl oroethane
Methyl Ethyl Ketone
Trichloroethylene
Trichl orof 1 uoromethane
Dichlorodifluoromethane
RTI Audit
Cone, (ppb)
145 ± 7
157 ± 8
196 ± 8
15.1 ± 0.7
14.7 ± 0.7
16.8 ± 0.7
14.8 ± 0.7
145 ± 7
155 ± 5
170 ± 7
196 ± 8
15.1 ± 0.7
14.7 ± 0.7
15.5 ± 0.5
16.7 ± 0.7
16.8 ± 0.7
14.8 ± 0.7
170 ± 9
145 ± 7
155 ± 5
170 ± 7
Client
Audit Status
% Bias of
(avg.)* Audit**
+17 B
-5
+63
+10 B
+54
+16
+19
-30 B
-3
-75
-52
-52 B
-93
-16
-71
-73
-16
+2 B
+36
-63
-2
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
27C I Ambient air measurement
method evaluation
28 0 Hazardous waste incin-
eration trial burn
29 B Hazardous waste in-
cineration sampling
method evaluation
Audit Material
Methyl Ethyl Ketone
Trichloroethylene
Trichl orof 1 uoromethane
D i chl orod i f 1 uoromethane
1 ,1 ,1-Trichl oroethane
Carbon Tetrachloride
Chloroform
Perchl oroethy 1 ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
RTI Audit
Cone, (ppb)
8.5 ± 0.5
15.1 ± 0.7
15.5 ± 0.5
16.7 ± 0.7
14.8 ± 0.7
9.5 ± 0.3
40.6 ± 0.9
9.5 ± 0.2
19.4 ± 0.6
20.6 ± 0.7
11.4 ± 0.3
43.9 ± 0.9
10.3 ± 0.2
19.9 ± 0.6
Client
Audit Status
% Bias of
(avg.)* Audit**
+124 B
-1
+158
+8
+42
+22 B
+9
+16
+17
-13
+5 B
+8
+20
+23
30A
30B
P
P
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Trichloroethylene
Trichloroethylene
15.1 ± 0.7
15.1 ± 0.7
+12
+70
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
31 Q Ambient air measurenent
method evaluation
32 B Hazardous waste in-
cineration sampling
method evaluation
33 B Hazardous waste in-
cineration sampling
method evaluation
34 R Ambient air measurement
method evaluation
35 C Ambient air measurement
method evaluation
Audit Material
Carbon Tetrachloride
Chi orof orrn
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Chloroform
Perchl oroethyl ene
Benzene
RTI Audit
Cone, (ppb)
299 ± 9.0
126 ± 2.6
103 ± 2.5
378 ± 12.1
9.6 ± 0.3
37.1 ± 0.8
9.1 ± 0.2
19.4 ± 0.6
37.7 ± 1.1
8.3 ± 0.2
8.4 ± 0.2
40.7 ± 1.3
9.6 ± 0.3
37.1 ± 0.8
9.1 ± 0.2
19.4 ± 0.6
20.4 ± 0.7
43.9 ± 0.9
10.3 ± 0.2
19.9 ± 0.6
Client
Audit
% Bias
(avg.)*
-56
-33
-60
+18
-1
+11
-18
+7
-25
-24
-17
-26
NA
NA
NA
NA
NA
+25
+25
+25
Status
of
Audit**
B
B
B
C
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
36 C Ambient air measurement
method evaluation
37 S Hazardous waste in-
cineration VOST
method evaluation
38 L Ambient air monitoring
measurement method
evaluation
39 L Ambient air measurement
method evaluation
RTI Audit
Audit Material Cone, (ppb)
Trichloroethylene
1 ,1 ,1-Trichl oroethane
Acetonitrile
Trichloroethylene
Trichl orof 1 uoromethane
1,2-Dibromoethane
1 ,1 ,1-Trichl oroethane
Carbon Tetrachloride
Chloroform
Perchl oroethy 1 ene
Benzene
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Trichloroethylene
1 ,2-Dichloroethane
Trichl orof 1 uoromethane
Bromomethane
Dichlorodifluoromethane
1,2-Dibromoethane
15.1 ± 0.7
14.8 ± 0.7
7.9 ± 0.6
9.0 ± 0.4
9.4 ± 0.3
10.2 ± 0.4
10.1 ± 0.5
386.2 ± 2.6
331.0 ± 7.0
107.0 ± 7.4
137.0 ± 4.4
150.0 ± 4.8
106 ± 7
123 ± 7
142 ± 7
139 ± 7
161 ± 6
168 ± 1
170 ± 7
192 ± 8
Client
Audit
% Bias
(avg.)*
+20
+29
+377
+39
+3
+1
+7
-100
-96
-40
+13
-39
-100
-65
-67
-17
+248
-100
-79
-86
Status
of
Audit**
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client***
40 T
41 T
42 I
(Lab A)
42 I
(Lab A)
42 I
(Lab B)
Use of Audit Material
Ambient air measurement
method evaluation (haz-
ardous waste landfill)
Ambient air measurement
method evaluation (haz-
ardous waste landfill)
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Trichloroethylene
1,2-Dichloroethane
1,1,1-Trichloroethane
Carbon Tetrachloride
Chi orof orm
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
11.4 ± 0.3
43.9 ± 0.9
10.3 ± 0.2
19.9 ± 0.6
15.1 ± 0.7
14.7 ± 0.7
14.8 ± 0.7
9.5 ± 0.3
37.3 ± 0.8
10.0 ± 0.2
19.7 ± 0.6
20.6 ± 0.7
14.5 ± 0.4
3.7 ± 0.1
14.2 ± 0.3
12.2 ± 0.4
11.6 ± 0.4
9.5 ± 0.3
37.3 ± 0.8
10.2 ± 0.2
19.7 ± 0.6
20.6 ± 0.7
Client
Audit
% Bias
(avg.)*
-29
-14
-15
-5
-7
-2
-3
+16
-4
0
-19
-13
+10
+8
+6
-10
-22
-5
+2
-20
-9
-8
Status
of
Audit**
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client***
42 I
(Lab B)
42
(Lab C) I
42 I
(Lab C)
42 . I
(Lab D)
42 I
(Lab D)
43A P
43B P
Use of Audit Material
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Benzene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Trichl oroethyl ene
Trichl oroethyl ene
RTI Audit
Cone, (ppb)
14.5 ± 0.4
3.7 ± 0.1
14.2 ± 0.3
12.2 ± 0.4
11.6 ± 0.4
19.7 ± 0.6
12.2 ± 0.4
9.5 ± 0.3
37.3 ± 0.8
10.0 ± 0.2
19.7 ± 0.6
14.5 ± 0.4
3.7 ± 0.1
14.2 ± 0.3
12.2 ± 0.4
142 ± 7.0
142 ± 7.0
Client
Audit
% Bias
(avg.)*
-17
-14
-15
-10
-5
-9
-18
+47
+18
+50
+2
+52
-5
+34
-2
+1
+44
Status
of
Audit**
B
B
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Ul
o
Audit
No. Client*** Use of Audit Material
44 U Hazardous
cineration
45 U Hazardous
cineration
46 V Ambient ai
waste in-
trial burn
waste in-
trial burn
r analysis
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Acetonitrile
Methyl Ethyl Ketone
Trichloroethyl ene
1 ,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Uichlorodifl uoromethane
1 ,2-Dibronioethane
1,1,1-Trichloroethane
Perchl oroethyl ene
Benzene
RTI
Cone.
11
43
10
19
13
8
15
14
15
15
16
16
14
21
25
Audit
(ppb)
.4
.9
.3
.9
.8
.5
.1
.7
.5
.4
.7
.8
.8
.1
.9
±
±
±
±
±
+
±
±
±
±
±
±
±
±
+
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
.3
.9
.2
.6
.0
.5
.7
.7
.5
.6
.7
.7
.7
.5
.8
Client
Audit
% Bias
(avy.)*
-68
-25
+8
-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
+118
+8
Status
of
Audit**
B
C
B
47 H Hazardous waste in-
cineration trial burn
48 EPA Ambient air measurement
Region III method evaluation
Annapolis, MD
Toluene
Chloroform
Perchloroethyl ene
Benzene
Vinyl Chloride
12.1
9.5 ± 0.3
10.0 ± 0.2
19.7 ± 0.6
20.6 ± 0.7
NA
-54
+60
+42
+70
C
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No.
49
50
51
(Lab A)
51
(Lab A)
51
(Lab B)
52
53
Client*** Use of Audit Material
EPA Ambient air measurement
Region III method evaluation
Annapolis, MD
V Ambient air measurement
method evaluation
I Ambient air measurement
at hazardous waste land-
fill
I Ambient air measurement
at hazardous waste land-
fill
I Ambient air measurement
at hazardous waste land-
fill
I Ambient air measurement
at hazardous waste land-
fill
W Hazardous waste in-
cineration trial burn
Audit Material
Trichloroethylene
1,1,1-Trichloroethane
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Benzene
Benzene
Vinyl Chloride
Vinyl Chloride
Benzene
Vinyl Chloride
Carbon Tetrachloride
Client
Audit
RTI Audit % Bias
Cone, (ppb) (avg.)*
14.2
13.3
9.6
37.1
9.1
19.4
20.4
18.6
44.2
48.5
48.5
44.2
48.5
12.3
± 0.7
± 0.7
± 0.3
± 0.8
± 0.2
± 0.6
± 0.7
± 0.6
± 1.4
± 1.6
± 1.6
± 1.4
± 1.6
± 0.4
+13
-10
-5
+4
+1
+2
-2
+24
+6
+65
-1
NA
NA
+24
Status
of
Audit**
B
B
B
B
B
C
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
on
Audit
No. Client*** Use of Audit Material
54 Region II Ambient air measurement
U.S. EPA at hazardous waste land-
fill
55 Region II Ambient air measurement
U.S. EPA at hazardous waste land-
fill
56 X Ambient air analysis
method evaluation
57 Y Ambient air measurement
method evaluation
Client
Audit
RTI Audit % Bias
Audit Material Cone, (ppb) (avg.)*
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Trichl orof 1 uoromethane
Bromomethane
Dichlorodifl uoromethane
1,2 Dibrornoethane
1 ,1 ,1-Trichloroethane
Vinyl Chloride
Carbon Tetrachloride
Chi orof orm
Perchl oroethyl ene
Benzene
Vinyl Chloride
46.0 ± 1.4
10.3 ± 0.2
10.7 ± 0.3
49.0 ± 1.6
50.1 ± 1.6
24.2 ± 1.7
29.0 ± 1.6
29.5 ± 1.0
31.4 ± 1.2
29.4 ± 1.2
32.6 ± 1.3
27.7 ± 1.4
50.3 ± 1.6
12.0 ± 0.4
12.0 ± 0.3
64.3 ± 1.5
44.7 ± 1.4
29.0 ± 0.9 .
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-1
NA
NA
NA
NA
NA
Status
of
Audit**
C
C
B
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No. Client***
58 V
59 I
60A I
(Method 1)
60A I
(Method 2)
608 I
Use of Audit Material
Ambient air analysis
method evaluation
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
fill
Ambient air measurement
at hazardous waste land-
Ambient air measurement
at hazardous waste land-
fill
Audit Material
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchloroetliylene
Benzene
Vinyl Chloride
Trichloroethylene
1,2-Dichloroethane
1,2 Dibromoethane
1 ,1 ,1-Trichloroethane
Trichl oroethyl ene
1,2 Dichloroethane
1 ,1 ,1-Trichloroethane
Trichloroethylene
1,2-Dichloroethane
Trichl orofluoromethane
Bromomethane
1 ,2-Dibromoethane
1 ,1 ,1-Trichloroethane
RTI Audit
Cone, (ppb)
9.6 ± 0.3
37.1 ± 0.8
9.1 ± 0.2
19.4 ± 0.6
20.4 ± 0.7
15.4 ± 0.5
14.8 ± 0.3
15.9 ± 0.4
16.9 ± 0.5
15.4 ± 0.5
9.5 ± 0.5
8.5 ± 0.4
8.5 ± 0.3
9.4 ± 0.5
9.5 ± 0.5
8.5 ± 0.4
9.4 ± 0.5
9.5 ± 0.5
8.5 ± 0.4
9.7 ± 0.3
11.4 ± 0.4
8.5 ± 0.3
9.4 ± 0.5
Client
Audit
% Bias
(avg.)*
-5
+4
+1
+2
-2
NA
NA
NA
NA
NA
+10
+34
+14
+10
+6
+35
+10
+58
+41
+24
+5
+64
+60
Status
of
Audit**
B
C
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No. Client*** Use of Audit Material
60C I Ambient air measurement
at hazardous waste land-
fill
60D I Ambient air measurement
at hazardous waste land-
fill
61 I Ambient air measurement
at hazardous waste land-
fill
62 USEPA Ambient air analysis
ASRL method evaluation
Audit Material
Tri chl oroethyl ene
1 , 2-Di chl oroethane
1,2-Dibromoethane
1,1, 1-Tri chl oroethane
Tri chl oroethyl ene
1, 2-Di chl oroethane
1,2-Dibromoethane
1,1, 1-Tri chl oroethane
Freon 114
Freon 113
Vinylidene Chloride
Acetone
Tol uene
1,4 Dioxane
Chlorobenzene
Benzene
RTI Audit
Cone, (ppb)
9.5 ± 0.5
8.5 ± 0.4
8.5 ± 0.3
9.4 ± 0.5
9.5 ± 0.5
8.5 ± 0.4
8.5 ± 0.3
9.4 ± 0.5
7.2 ± 1.0
10.2 ± 1.0
12.5 ± 1.3
6.7 ± 2.1
10.5 ± 1.2
10.1 ±3.3
10.8 ± 1.3
12.2 ± 0.4
Client
Audit Status
% Bias of
(avg.)* Audit**
-34 B
+14
-7
+17
+26 B
+6
-7
+4
NA C
NA
NA
NA
NA
NA
NA
-26 B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
en
Audit
No. Client*** Use of Audit Material
63A JJ Ambient air measurement
method evaluation
63B JJ Ambient air measurement
method evaluation
63C JJ Ambient air measurement
method evaluation
630 JJ Ambient air measurement
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chi oroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Client
Audit
RTI Audit % Bias
Cone, (ppb) (avg.)*
86.2 ± 2.6
331 ± 7.0
307 ± 7.4
137 ± 4.4
150 ± 4.8
132 ± 4.0
128 ± 2.7
137 ± 3.3
138 ± 4.4
153 ± 4.9
281 ± 8.4
223 ±4.7
347 ± 8.3
302 ± 9.7
308 ± 9.9
47.8 ± 1.5
10.8 ± 0.2
11.7 ± 0.3
52.3 ± 1.7
50.4 ± 1.6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
C
C
C
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material Audit Material
64A JJ Ambient air measurement Acetonitrile
method evaluation Methyl Ethyl Ketone
Trichl oroethyl ene
1,2-Dichloroethane
Trichl orofluoromethane
Bromomethane
D i chl roedi f 1 uoromethane
1,2-Dibromoethane
1 ,1 ,1-Trichloroethane
64B JJ Ambient air measuranent Acetonitrile
method evaluation Methyl Ethyl Ketone
Trichl oroethyl ene
1,2-Dichloroethane
Trichl orof 1 uoromethane
Broinoethane
Di chl orodifl uoromethane
1 , 2 -D i bromoeth ane
1 ,1 ,1-Trichl oroethane
64C JJ Ambient air measurement Acetonitrile
method evaluation Methyl Ethyl Ketone
Trichloroethylene
1,2-Dichloroethane
Trichl orof 1 uoromethane
Bromoethane
Di chl orodifl uoromethane
1,2-Dibromoethane
1 , 1 ,1-Trichl oroethane
RTI Audit
Cone, (ppb)
112 ± 7.8
140 ± 7.7
141 ± 6.8
135 ± 6.9
161 ± 5.5
168 ± 6.6
164 ± 6.7
174 ± 7.1
0
24.1 ± 1.7
28.0 ± 1.5
27.6 ± 1.3
26.3 ± 1.3
29.7 ± 1.0
31.3 ± 1.2
29.7 ± 1.2
33.7 ± 1.4
27.5 ± 1.4
37.6 ± 2.6
18.5 ± 1.0
38.4 ± 1.8
39.3 ± 2.0
38.5 ± 1.3
22.0 ± 0.9
20.8 ± 0.9
21.7 ± 0.9
18.2 ± 0.9
Client
Audit Status
% Bias of
(avg.)* Audit**
NA C
NA
NA
NA
NA
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
64D JJ Ambient air measurement
method evaluation
65A JJ Ambient air measurement
method evaluation
65B JJ Ambient air measurement
method evaluation
Audit Material
Acetonitrile
Methyl Ethyl Ketone
Trichl oroethyl ene
1,2-Dichloroethane
Trichl orof 1 uoromethane
Bromomethane
Dichlroedifl uoromethane
1,2-Dibromoethane
1 ,1 ,1-Trichl oroethane
Freon 114
Freon 113
Vinyl idene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
Freon 114
Freon 113
Vinyl idene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
RTI Audit
Cone, (ppb)
24.2 ±
29.0 ±
28.2 ±
27.3 ±
29.5 ±
31.4 ±
29.4 ±
32.6 ±
27.2 ±
27.6 ±
10.3 ±
32.4 ±
7.1 ±
33.5 ±
10.4 ±
29.6 ±
25.7 ±
9.6 ±
31.8 ±
9.9 ±
33.5 ±
10.2 ±
29.8 ±
1.7
1.6
1.4
1.4
1.0
1.2
1.2
1.3
1.4
5.2
1.3
4.5
2.2
11.2
0.7
5.0
4.9
1.2
4.4
3.1
11.0
0.7
5.0
Client
Audit
% Bias
(avg.)*
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
C
C
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CJ1
oo
Audit
No. Client*** Use of Audit Material
65C JJ Ambient air measurement
method evaluation
66 KK Ambient air measurement
at hazardous waste land-
fill
67 KK Ambient air measurement
at hazardous waste land-
fill
68 I Hazardous waste in-
cineration trial burn
69 Z Hazardous waste in-
cineration trial burn
Audit Material
Freon 114
Freon 113
Vinylidene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Trichloroethylene
1,2-Dichloroethane
Trichlorofluoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 ,2-Dibromoethane
Carbon tetrachloride
Chloroform
Trichl oroethyl ene
RTI Audit
Cone, (ppb)
24.6 ± 4.6
30.2 ± 3.9
30.7 ± 4.2
8.6 ± 2.6
10.0 ± 3.2
12.3 ± 0.8
10.7 ± 1.8
265 ± 8.0
208 ± 4.4
295 ± 7.1
277 ± 8.9
302 ± 9.7
109 ± 7.6
128 ± 7.0
139 ± 6.7
139 ± 7.1
158 ± 5.4
164 ± 6.4
148 ± 6.1
164 ± 6.7
12.3 ± 0.4
12.2 ± 0.3
9.6 ± 0.5
Client
Audit Status
% Bias of
(avg.)* Audit**
NA C
NA
NA
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA
NA
NA
-43 B
+15
-6 B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
70 AA Hazardous waste in-
cineration trial burn
71 HH Hazardous waste in-
cineration (boiler)
72 HH Hazardous waste in-
cineration (boiler)
73 HH Hazardous waste in-
cineration (boiler)
74 USEPA Ambient air analysis
ASRL method evaluation
75 II Ambient air measurement
at hazardous waste land-
fill
RTI Audit
Audit Material Cone, (ppb)
Trichloroethylene
1,2-Dichloroethane
Trichl orof 1 uoromethane
Bromomethane
Di chl orod i f 1 uoromethane
1,1,1-Trichloroethane
Carbon Tetrachloride
1 ,1 ,1-Trichl oroethane
Toluene
Benzene
Carbon Tetrachloride
Chl orof orrn
Perchl oroethyl ene
Benzene
Vinyl Chloride
15.1 ± 0.7
15.8 ± 0.8
16 .-2 ±0.5
14.0 ± 0.5
16.0 ± 0.7
14.0 ± 0.7
6.4 ± 0.2
13.3 ± 0.7
10.3
19.4 ± 0.6
306 ± 9.2
223 ± 4.7
398 ±9.6
325 ±10.4
308 ± 9.9
Client
Audit
% Bias
(avg.)*
+92
+27
-26
-57
+256
+71
+30
+31
+21
-8
NA
NA
NA
NA
NA
Status
of
Audit**
B
B
B
B
B
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CTV
O
Audit
No. Client*** Use of Audit Material
76 V Ambient air analysis
method evaluation
77 C Ambient air analysis
method evaluation
78 C Ambient air analysis
method evaluation
79 H Hazardous waste in-
cineration trial burn
80 H Hazardous waste in-
cineration trial burn
Audit Material
Freon 114
Freon 113
Vinyl idene Chloride
Toluene
Chlorobenzene
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Trichl oroethyl ene
1 ,2-Dichloroethane
1,2-Dibromoethane
1,1,1-Trichloroethane
Carbon Tetrachloride
Perchloroethylene
Trichl oroethyl ene
1,1 ,1-Trichloroethane
RTI Audit
Cone, (ppb)
9.1 ± 1.3
10.2 ± 1.0
8.7 ± 0.9
10.6 ± 1.3
11.1 ± 1.5
46.0 ± 1.4
10.3 ± 0.2
10.7 ± 0.3
49.0 ± 1.6
50.1 ± 1.6
9.4 ± 0.5
7.7 ± 0.4
7.8 ± 0.3
9.3 ± 0.5
6.4 ± 0.2
21.1 ± 0.5
14.2 ± 0.7
13.3 ± 0.7
Client
Audit Status
% Bias of
(avg.)* Audit**
+34 B
+8
+1
+10
+11
+6 B
+1
-19
-9
-24
-5 B
+21
-18
+17
-67 B
-86
+20 B
+20
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Cft
Audit
No. Client*** Use of Audit Material
81 H Hazardous waste in-
cineration trial burn
82 CC Hazardous waste in-
cineration trial burn
Audit Material
Freon 114
Freon 113
Vinyl idene Chloride
Acetone
Toluene
1,4-Dioxane
Chlorobenzene
Carbon Tetrachloride
Chi oroform
RTI Audit
Cone, (ppb)
8.5 ± 1.3
10. I ± 1.0
10.9 ± 1.0
27.6 ± 5.7
30.8 ± 3.6
28.8 ± 8.9
31.4 ± 3.6
37.2 ± 1.1
8.1 ± 0.2
Client
Audit
% Bias
(avg.)*
+131
0
-16
-18
+78
-79
+49
-5
+10
Status
of
Audit**
B
B
83
84
DD
DD
Ambient air measurement
method evaluation
Ambient air measurement
method evaluation
Carbon Tetrachloride
Toluene
86.2 ± 2.6
10.3 ± 1.2
+7
+11
85 DD Ambient air measurement Acetonitrile
method evaluation Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Trichlorofluoromethane
Bromomethane
Dichlorodifluoromethane
1,2-Dibromoethane
1,1,1-Trichloroethane
12.2 ± 0.8
7.5 ± 0.4
15.1 ± 0.7
15.8 ± 0.8
16.2 ± 0.5
14.0 ± 0.5
16.0 ± 0.7
11.8 ± 0.5
14.0 ± 0.7
NA
NA
NA
NA
NA
NA
NA
NA
NA
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
cr>
ro
Audit
Mo. Client*** Use of Audit Material
86 FF Hazardous
cineration
87A FF Ambient ai
waste in-
trial burn
r measurement
at hazardous waste land-
fill
87B FF Ambient ai
r measurement
at hazardous waste land-
fill
88 H Hazardous
cineration
89 Z Hazardous
cineration
waste in-
trial burn
waste in-
trial burn
RTI Audit
Audit Material Cone, (ppb)
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Trichloroethylene
1 ,2-Dichloroethane
Trichl orof 1 uoromethane
Bromomethane
D i chl orod i f 1 uoromethane
1,2-Dibromoethane
Carbon Tetrachloride
Chl orof orm
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Perchl oroethyl ene
Carbon Tetrachloride
Chloroform
11.0
43.6
11.6
23.0
20.5
112
140
141
135
161
168
164
174
132
128
137
138
153
6.4
21.1
9.6
37.1
±
+
+
+
±
±
±
+
±
±
+
+
±
±
+
±
+
±
+
+
±
±
0.
0.
0.
0.
0.
7.
7.
6.
6.
5.
6.
6.
7.
4.
2.
3.
4.
4.
0.
0.
0.
0.
5
9
3
7
7
8
7
8
9
5
6
7
1
0
7
3
4
9
2
5
3
8
Client
Audit
% Bias
(avg.)*
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
+33
+33
+6
-2
Status
of
Audit**
C
C
C
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material
90 Z Hazardous waste in-
cineration trial burn
91 LL Hazardous waste in-
cineration trial burn
92 LL Hazardous waste in-
cineration trial burn
93 W Hazardous waste trial
burn
94 H Hazardous waste trial
burn
95 MM Hazardous waste trial
burn
96 NN Hazardous waste trial
burn
97 NN Hazardous waste trial
burn
Audit Material
Trichloroethylene
Carbon Tetrachloride
Tri chl oroethyl ene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Freon 113
RTI Audit
Cone, (ppb)
13.2 ± 0.7
16.9 ± 0.5
13.2 ± 0.7
73.9 ± 2.2
349.8 ±7.4
319.9 ± 9.9
126.9 ± 4.1
160.3 ± 5.2
11.4 ± 0.3
4474 ± 135
3336 ± 71
1659 ± 169
3348 ± 109
3342 ± 108
47.8 ± 1.5
30.2 ± 3.9
Client
Audit
% Bias
(avg.)*
+5
-22
-1
+14
-6
-6
+13
+53
-4
NA
NA
NA
NA
NA
+47
+48
Status
of
Audit**
B
B
B
B
B
C
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
98 00 Ambient air monitoring
method evaluation
99 00 Ambient air monitoring
method evaluation
100A I Ambient air monitoring
method evaluation
100B I Ambient air monitoring
method evaluation
100C I Ambient air monitoring
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Vinyl Chloride
Trichloroethylene
1,2 Dichloroethane
Trichl orof 1 uoromethane
Dichlorodifluoromethane
1 ,1,1-Trichloroethane
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
14.4 ± 0.4
14.4 ± 0.3
31.3 ± 1.0
15.3 ± 0.7
15.4 ± 0.8
16.3 ± 0.6
16.3 ± 0.7
13.9 ± 0.7
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
Client
Audit Status
% Bias of
(avg.)* Audit**
+63 B
+234
+3
+154 B
+135
-100
+31
+96
+16 B
-14
+10
-13
-1
-30 B
+7
0
-10
+26 B
+25
+27
-9
-2
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
cr>
en
Audit
No.
100D
100E
100F
100G
101
102
Client*** Use of Audit Material
I Ambient air monitoring
method evaluation
I Ambient air monitoring
method evaluation
I Ambient air monitoring
method evaluation
I Ambient air monitoring
method evaluation
H Hazardous waste trial
burn
H Hazardous waste trial
burn
Audit Material
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Chloroform
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Vinylidene Chloride
Tol uene
Chlorobenzene
RTI Audit
Cone, (ppb)
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
8.1 ± 0.2
39.1 ± 1.3
9.6 ± 0.3
37.1 ± 0.8
9.1 ± 0.2-
19.4 ± 0.6
20.4 ± 0.7
8.5 ± 1.1
10.5 ± 3.4
10.8 ± 1.8
Client
Audit
% Bias
(avg.)*
-9
+52
+3
-9
-2
-9
+52
+20
+12
+5
+19
-10
+22
-6
-23
+108
+69
+60
+34
+67
+79
+57
+47
Status
of
Audit**
B
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No.
103
104
105
106A
Client*** Use of Audit Material Audit Material
HH Hazardous waste trial Carbon Tetrachloride
burn Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
HH Hazardous waste trial Freon 114
burn Freon 113
Vinyl Chloride
Acetone
Toluene
1,4-Dioxane
Chlorobenzene
PP Hazardous waste trial Acetonitrile
burn Methyl Ethyl Ketone
Trichl oroethyl ene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 ,2-Di bromoethane
1 , 1 , 1-Tri chl oroethane
I Hazardous waste landfill Tri chl oroethyl ene
emissions monitoring 1,2-Dichloroethane
1,1,1 -Tri chl oroethane
RTI Audit
Cone, (ppb)
307 ± 9.1
114 ± 2.4
102 ± 29
289 ± 12.5
423 ± 13.8
125 ± 23
143 ± 18
123 ± 17
114 ± 35
161 ± 11
125 ± 41
152 ± 26
11.3 ± 0.8
30.0 ± 1.6
10.2 ± 0.5
9.7 ± 0.5
10.1 ± 0.3
30.0 ± 1.3
26.3 ± 1.0
32.0 ± 1.3
31.7 ± 1.7
39.4 ± 1.9
37.4 ± 1.9
19.1 ± 1.0
Client
Audit Status
% Bias of
(avg.)* Audit**
NA C
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA
NA
-64 B
-23
-11
-6
-29
-97
-69
-20
-9
+12 B
+17
-1
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No.
106B
106C
107
108
109
110
Client*** Use of Audit Material
I Hazardous waste landfill
emissions monitoring
I Hazardous waste landfill
emissions monitoring
i
HH Hazardous waste trial
burn
HH Hazardous waste trial
burn
QQ Hazardous waste trial
burn
QQ Hazardous waste trial
burn
Audit Material
Trichloroethylene
1,2-Dichloroethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
Tri chl oroethyl ene
1,2-Dichloroethane
1, 2-Di bromoethane
1,1,1 -Tri chl oroethane
Carbon Tetrachloride
Perchl oroethyl ene
Tri chl oroethyl ene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethylene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
39.4 ± 1.9
37.4 ± 1.9
20.3 ± 0.8
20.8 ± 0.9
19.1 ± 1.0
39.4 ± 1.9
37.4 ± 1.9
20.8 ± 0.9
19.1 ± 1.0
13.7 ± 0.4
69.9 ± 1.7
10.1 ± 0.5
46.0 ± 1.4
10.3 ± 0.2
10.7 ± 0.3
49.0 ± 1.6
50.1 ± 1.6
73.9 ± 2.2
350 ±7.4
320 ± 7.9
127 ± 4.1
160 ± 5.2
Client
Audit
% Bias
(avg.)*
-1
-38
-6
-28
+5
+12
+50
+6
-27
-12
-4
_j
NA
MA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
B
B
B
B
C
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material Audit Material
111 RR Hazardous waste landfill Carbon Tetrachloride
emissions monitoring Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
112 W Hazardous waste trial Carbon Tetrachloride
burn with VOST Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
113 W Hazardous waste trial Acetonitrile
burn with VOST Methyl Ethyl Ketone
Trichl oroethyl ene
1,2-Dichloroethane
Tri chl of 1 uoroemethane(Fll
Bromothane
1,2-Dibromoethane
1 11 -Tri chl oroethane
114 V Ambient air monitoring Carbon Tetrachloride
method evaluation Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
13.7 ± 0.4
13.3 ± 0.3
69.9 ± 1.7
46.6 ± 1.5
31.3 ± 1.0
10.5 ± 0.3
40.5 ± 0.9
11.2 ± 0.3
19.7 ± 0.6
19.4 ± 0.6
37.3 ± 2.6
17.7 ± 0.9
41.9 ± 2.1
38.0 ± 2.0
)42.0 ± 1.3
25.4 ± 1.0
22.2 ± 0.9
21.2 ± 1.1
12.3 ± 0.4
48.3 ± 1.0
13.3 ± 0.3
24.6 ± 0.8
21.1 ± 0.71
Client
Audit Status
% Bias of
(avg.)* Audit**
-39 B
-42
-54
-27
-20
+10 B
14
+3
+41
+8
-59 B
-56
+32
+24
-38
+43
+75
+22
MA C
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client**** Use of Audit Material
115 V Ambient air monitoring
method evaluation
116 H Hazardous waste trial
burn
117 TT Ambient air monitoring
method evaluation
118A I Ambient air monitoring
method evaluation
Audit Material
Acetonitrile
Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
Carbon Tetrachloride
Perchl oroethyl ene
Tri chl oroethyl ene
1,2-Dichloroethane
1, 2-Di bromoethane
1 , 1 , 1-Tri chl oroethane
Tri chl oroethyl ene
1 , 2-Di chl oroethane
1, 2-Di bromoethane
1,1,1 -Tri chl oroethane
RTI Audit
Cone, (ppb)
13.1 ± 0.9
10.9 ± 0.6
14.4 ± 0.71
12.5 ± 0.61
15.6 ± 0.5
10.4 ± 0.4
16.4 ± 0.6
12.1 ± 0.5
14.8 ± 0.8
37.2 ± 1.1
9.0 ± 0.2
13.2 ± 0.7
16.7 ± 0.9
16.2 ± 0.7
16.3 ± 0.9
10.2 ± 0.5
9.7 ± 0.5
32.0 ± 1.3
31.7 ± 1.7
Client
Audit
% Bias
(avg.)*
NA
NA
NA
NA
NA
NA
NA
NA
NA
+40
+22
-31
-64
-100
-81
+28
+34
+19
-2
Status
of
Audit**
C
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No.
11881
118B2
118C
118D
Client*** Use of Audit Material Audit Material
I Ambient air monitoring Trichloroethylene
method evaluation 1,2-Dichloroethane
Trichlorofluoromethane
Bromomethane
Dichlorodifluoromethane
1 ,2-Dibromoethane
1,1,1-Trichloroethane
I Ambient air monitoring Trichloroethylene
method evaluation Trichlorofluoromethane
1,2-Dibromoethane
1 ,1,1-Trichloroethane
I Ambient air monitoring Trichloroethylene
method evaluation Trichlorofluoromethane
Dichlorodifl uoromethane
1 ,2-Dibromoethane
1 ,1 ,1-Trichloroethane
I Ambient air monitoring Methyl Ethyl Ketone
method evaluation Trichloroethylene
1,2-Dichloroethane
Trichlorofluoromethane
Bromomethane
1 ,2-Dibromoethane
1,1,1-Trichloroethane
RTI Audit
Cone, (ppb)
10.2 ± 0.5
9.7 ± 0.5
10.1 ± 0.3
30.0 ± 1.2
26.3 ± 1.0
32.0 ± 1.3
31.7 ± 1.7
10.2 ± 0.5
10.1 ± 0.3
32.0 ± 1.3
31.7 ± 1.7
10.2 ± 0.5
10.1 ± 0.3
26.3 ± 1.0
32.0 ± 1.3
31.7 ± 1.7
30.0 ± 1.6
10.2 ± 0.5
9.7 ± 0.5
10.1 ± 0.3
30.0 ± 1.2
32.0 ± 1.3
31.7 ± 1.7
Client
Audit Status
% Bias of
(avg.)* Audit**
+1 B
+13
+1
+33
+ 33
+9
+4
-2 B
+9
+28
+4
+10 B
-42
+12
-38
-12
0 B
+37
+24
+39
+43
+19
+23
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
118E I Ambient air monitoring
method evaluation
118F I Ambient air monitoring
method evaluation
119 USEPA Region Ambient air monitoring
III method evaluation
120 WW Ambient air monitoring
method evaluation
121 XX Hazardous waste trial
burn
122 XX Hazardous waste trial
burn
Audit Material
Trichloroethylene
1,2-Dichloroethane
Trichlorofluoromethane
Bromomethane
Di chl orod i f 1 uoromethane
1,2-Dibromethane
1 ,1 ,1-Trichl oroethane
Trichl oroethyl ene
1 ,1 ,1-Trichloroethane
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Trichloroethylene
1,2-Dichloroethane
0 i chl orod i f 1 uoromethane
1 ,1,1-Trichl oroethane
Carbon Tetrachloride
Toluene
RTI Audit
Cone, (ppb)
10.2 ± 0.5
9.7 ± 0.5
10.1 ± 0.3
30.0 ± 1.2
26.3 ± 1.0
32.0 ± 1.3
31.7 ± 1.7
10.2 ± 0.5
31.7 ± 1.7
45.8 ± 1.5
153.7 ± 10.6
167.2 ± 8.8
147.5 ± 7.2
154.7 ± 8.0
160.7 ± 6.2
152.1 ± 8.0
310 ± 9.2
11.6 ± 0.8
Client
Audit Status
% Bias of
(avg.)* Audit**
+63 B
+47
+53
+251
+43
+7
-87
+30 B
-87
+5 B
-19 B
-76
+154
-25
+3
-16
-7 B
-11 B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
123 TT Ambient air monitoring
method evaluation
124 YY Hazardous waste trial
burn
125 YY Hazardous waste trial
burn
126 II Ambient air monitoring
method evalution
127 HH Hazardous waste trial
burn
Audit Material
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Acetonitrile
Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Toluene
RTI Audit
Cone, (ppb)
56.9 ± 1.7
11.4 ± 0.3
43.9 ± 0.9
10.3 ± 0.2
22.3 ± 0.7
19.8 ± 0.6
38.4 ±2.7
16.1 ± 0.8
39.4 ± 1.9
37.4 ± 1.9
40.8 ± 1.3
23.1 ± 0.9
20.3 ± 0.8
20.8 ± 0.9
19.1 ± 1.0
13.7 ± 0.4
13.3 ± 0.3
69.9 ± 1.7
46.6 ± 1.5
10.2 ± 0.7
Client
Audit Status
% Bias of
(avg.)* Audit**
MA C
NA C
NA
NA
NA
NA
NA C
NA
NA
NA
NA
NA
NA
NA
NA
-27 B
-2
-38
+3
-12 B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
. CO
Audit
No. Client*** Use of Audit Material
128 KK Hazardous waste landfill
emissions monitoring
129 KK Hazardous waste landfill
emissions monitoring
130A I Ambient air monitoring
method evaluation
130B1 I Ambient air monitoring
method evaluation
130B2 I Ambient air monitoring
method evaluation
130C I Ambient air monitoring
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
1,2-Dichloroethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
Carbon Tetrachloride
Chloroform
Perchl oroethylene
Benzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Benzene
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
7340 ± 222
9521 ± 203
4739 ± 115
4784 ± 152
9142 ± 294
154.7 ± 8.0
158.4 ± 6.6
152.1 ± 8.0
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
49.0 ± 1.6
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
49.0 ± 1.6
49.0 ± 1.6
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
49.0 ± 1.6
45.8 ± 1.5
Client
Audit
% Bias
(avg.)*
+47
+16
-7
+28
+37
-56
-83
-12
-3
-1
-15
+8
-4
-7
-5
+9
-18
-15
-17
-28
-4
+4
Status
of
Audit**
B
B
B
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
130D I Ambient air monitoring
method evaluation
130E I Ambient air monitoring
method evaluation
130F I Ambient air monitoring
method evaluation
131 H Hazardous waste trial
burn
132 W Hazardous waste trial
burn
Audit Material
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchloroethylene
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
49.0 ± 1.6
45.8 ± 1.5
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
49.0 ± 1.6
45.8 ± 1.5
54.5 ± 1.6
12.2 ± 0.3
13.6 ± 0.3
839 ± 25
1492 ± 32
832 ± 20
1560 ± 50
834 ± 27
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
Client
Audit
% Bias
(avg.)*
-16
-16
-27
+3
+7
-17
-9
-20
+18
-8
-12
+2
-53
NA
NA
NA
NA
NA
+1
+22
+51
-27
-53
Status
of
Audit**
B
B
B
C
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material Audit Material
133 RR Hazardous waste landfill Carbon Tetrachloride
emissions monitoring Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
134 UU Ambient air monitoring Carbon Tetrachloride
method evaluation Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
135 UU Ambient air monitoring Acetonitrile
method evaluation Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Trichloroethane
1,2-Dibromoethane
1,1,1 -Tri chl oroethane
136 UU Ambient air monitoring Freon 114
method evaluation Freon 113
Vinylidene Chloride
Acetone
1,4-Dioxane
Tol uene
Chlorobenzene
RTI Audit
Cone, (ppb)
14.4 ±
14.4 ±
70.1 ±
45.7 ±
31.3 ±
16.9 ±
15.3 ±
78.0 ±
52.6 ±
31.8 ±
27.1 ±
27.4 ±
29.6 ±
28.6 ±
32.1 ±
30.4 ±
30.1 ±
7.6 ±
10.3 ±
11.7 ±
24.7 ±
33.7 ±
33.5 ±
30.8 ±
0.4
0.3
1.7
1.5
1.0
0.5
0.4
1.9
1.7
1.0
1.9
1.4
1.5
1.5
1.0
1.3
1.6
1.4
1.3
1.6
7.7
11.1
2.3
5.2
Client
Audit
% Bias
(avg.)*
-24
-10
+3
+27
+5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
B
C
C
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
en
Audit
No. Client*** Use of Audit Material
137 0 Hazardous waste trial
burn
138 0 Hazardous waste trial
burn
139 HH Hazardous waste trial
burn
140 Region VII Ambient air monitoring
method evaluation
141 Region VII Ambient air monitoring
method evaluation
142 Q Hazardous waste trial
burn
143 AC Hazardous waste trial
burn
Audit Material
Carbon Tetrachloride
Toluene
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Vinyl Chloride
Trichloroethylene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Di chl orodi f 1 uoromethane
1 , 1 , 1-Tri chl oroethane
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
70.0 ± 2.1
32.8 ±2.3
10.5 ± 0.3
1584 ± 48
844 ± 18
1585 ± 51
29.5 ± 1.5
27.8 ± 1.4
32.9 ± 1.0
26.2 ± 1.0
29.8 ± 1.6
15.4 ± 0.5
37.2 ± 1.1
8.1 ± 0.2
9.0 ± 0.2
39.1 ± 1.3
50.3 ± 1.6
Client
Audit
% Bias
(avg.)*
-21
-13
-3
-4
+17
-8
+28
+51
+5
+3
+39
NA
NA
NA
NA
NA
NA
Status
of
Audit**
B
B
B
B
B
C
C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No.
144
145
146
147
148
149
150
151
151
Client*** Use of Audit Material
VV Hazardous waste trial
burn
VV Hazardous waste trial
burn
AE Ambient air monitoring
method evaluation
AE Ambient air monitoring
method evaluation
AE Ambient air monitoring
method evaluation
A Hazardous waste trial
burn
A Hazardous waste trial
burn
AH Ambient air monitoring
method evaluation
(Method A)
AH Ambient air monitoring
method evaluation
(Method B)
Audit Material
Carbon Tetrachloride
Perchl oroethyl ene
Carbon Tetrachloride
Perchl oroethyl ene
Vinyl Chloride
Acetonitrile
To! uene
Carbon Tetrachloride
Carbon Tetrachloride
Carbon Tetrachloride
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethylene
Client
Audit
RTI Audit % Bias
Cone, (ppb) (avg.-)*
10.5 ±
11.2 ±
310 ±
122 ±
423 ±
112 ±
161 ±
8.0 ±
2968 ±
79.6 ±
75.6 ±
69.3 ±
79.6 ±
72.2 ±
79.9 ±
0.3
0.3
9.2
3.0
13.8
7.8
11
0.2
58
2.3
2.4
2.2
2.3
1.5
2.0
NA
NA
NA
NA
NA
NA
NA
-12
+12
+7
-2
+4
-10
Status
of
Audit**
C
C
C
C
C
C
C
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material
152 AH Ambient air monitoring
method evaluation
(Method A)
(Method B)
153 HH Hazardous waste trial
burn
154 HH Hazardous waste trial
bum
155 AI Ambient air monitoring
method evaluation
156 AI Ambient air monitoring
method evaluation
157 AI Ambient air monitoring
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Pe rch 1 oroet hy 1 ene
Carbon Tetrachloride
Chlorofrom
Perchl oroethyl ene
Carbon Tetrachloride
Acetonitrile
Freon 114
Freon 113
Vinylidene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
Acetonitrile
Freon 114
RTI Audit
Cone, (ppb)
134 ± 4.0
137 ± 4.4
151 ± 4.9
134 ± 4.0
129 ± 2.7
139 ± 3.4
12.3 ± 0.4
13.1 ± 0.9
7.2 ± 1.4
10.2 ± 1.3
12.5 ± 1.7
6.7 ± 2.1
10.1 ± 3.3
10.5 ± 0.7
10.8 ± 1.8
13.1 ± 0.9
7.2 ± l'.4
Client
Audit Status
% Bias of
(avg.)* Audit**
+8 B
+35
+15
+10
+16
-24
NA C
NA C
NA C
NA
NA
NA
NA
NA
NA
NA C
NA C
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material
158 X Ambient air monitoring
method evaluation
159 AF Hazardous waste trial
burn
160 AJ Hazardous waste trial
burn
161 AG Hazardous waste trial
burn
162 AG Hazardous waste trial
burn
Audit Material
Carbon Tetrachloride
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Freon 114
Freon 113
Vinylidene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
RTI Audit
Cone, (ppb)
14.4 ± 0.4
291 ±8.7
232 ± 4.9
365 ± 9.0
300 ±9.7
21.4 ± 2.4
10.6 ± 0.6
20.6 ± 1.0
10.3 ± 0.5
29.4 ± 2.5
9.5 ± 2.6
40.6 ± 0.9
10.1 ± 2.7
19.2 ± 0.6
20.1 ± 0.6
21.8 ± 4.1
28.9 ± 3.7
33.3 ±4.6
9.2 ± 2.5
11.4 ± 3.7
11.6 ± 0.8
11.7 ± 1.9
Client
Audit
% Bias
(avg.)*
MA
-21
-25
-28
+23
+12
+19
-5
+59
-46
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
C
B
B
A
A
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CD
O
Audit
No. Client*** Use of Audit Material Audit Material
163 HH Hazardous waste landfill Carbon Tetrachloride
emissions monitoring Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
164 HH Hazardous waste landfill Acetonitrile
emissions monitoring Methyl Ethyl Ketone
Trichl oroethyl ene
1 , 2-Di chl oroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1,2-Dibromoethane
1,1,1 -Tri chl oroethane
165A I Ambient air monitoring Tri chl oroethyl ene
method evaluation 1,2-Dichloroethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
16513 I Ambient air monitoring Tri chl oroethyl ene
method evaluation Tri chl orof 1 uoromethane
1,2-Dibromoethane
1 , 1 , 1-Tri chl oroethane
RTI Audit
Cone, (ppb)
46.0 ± 1.4
10.3 ± 0.2
10.7 ± 0.3
49.0 ± 1.6
50.1 ± 1.6
14.9 ± 1.1
18.1 ± 1.0
13.2 ± 0.7
16.7 ± 0.9
15.9 ± 0.5
12.6 ± 0.5
15.5 ± 0.6
16.2 ± 0.7
16.3 ± 0.9
10.1 ± 0.5
10.5 ± 0.5
31.8 ± 1.3
33.9 ± 1.8
10.1 ± 0.5
9.8 ± 0.3
31.8 ± 1.3
33.9 ± 1.8
Client
Audit
% Bias
(avg.)*
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
+7
-7
-16
-14
+6
+3
+2
-8
Status
of
Audit**
A
A
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
Audit
No. Client*** Use of Audit Material Audit Material
165C I Ambient air monitoring Methyl Ethyl Ketone
method evaluation Trichloroethylene
Tri chl orof 1 uorpmethane
Bromomethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
1,1,1 -Tri chl oroethane
165D I Ambient air monitoring Methyl Ethyl Ketone
method evaluation Trichloroethylene
1 , 2-Di chl oroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1, 2-Di bromoethane
1,1,1 -Tri chl oroethane
165E I Ambient air monitoring Trichloroethylene
method evaluation 1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
1 , 1 , 1-Tri chl oroethane
166 USEPA-ERT Ambient air monitoring Carbon Tetrachloride
Edison, NJ method evaluation Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
29.0 ± 1.5
10.1 ±0.5
9.8 ± 0.3
39.1 ± 1.6
27.7 ± 1.1
31.8 ± 1.3
33.9 ± 1.8
29.0 ± 1.5
10.1 ± 0.5
10.5 ± 0.5
9.8 ± 0.3
39.1 ± 1.6
27.7 ± 1.1
31.8 ± 1.3
33.9 ± 1.8
10.1 ± 0.5
10.5 ± 0.5
9.8 ± 0.3
39.1 ± 1.6
27.7 ± 1.1
31.8 ± 1.3
33.9 ± 1.8
4308 ± 130
3200 ± 68
6765 ± 164
3283 ± 104
3122 ± 101
Client
Audit Status
% Bias of
(avg.)* Audit**
0 B
+2
-6
-25
+6
-24
-39
+7 B
-4
-24
+12
-2
-10
-10
-3
+23 B
-31
+28
+42
-43
-43
+17
NA A
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
ro
Audit
No. Client*** Use of Audit Material Audit Material
167 USEPA-ERT Ambient air monitoring Acetonitrile
Edison, NJ method evaluation Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1 , 2-Di bromoethane
168 USEPA-ERT Ambient air monitoring Freon 114
Edison, NJ method evaluation Freon 113
Vinylidene Chloride
Acetone
1,4-Dioxane
Toluene
Chlorobenzene
169 USEPA-ERT Ambient air monitoring 1,3-Butadiene
Edison, NJ method evaluation Ethyl ene Oxide
Propylene Oxide
Methyl ene Chloride
Acrylonitrile
Ortho-xylene
RTI Audit
Cone, (ppb)
140 ± 9.9
159 ± 8.4
143 ± 7.0
161 ±8.3
168 ± 5.3
178 ± 7.1
168 ± 6.5
206 ±8.5
125 ± 23
123 ± 17
114 ± 35
125 ± 41
161 ± 11
152 ± 26
5780 ± 208
5430 ± 230
8080 ± 319
5930 ± 248
5800 ±233
8440 ± 707
Client
Audit Status
% Bias of
(avg.)* Audit**
NA A
NA
NA
NA
NA
NA
NA
NA
NA A
NA
NA
NA
NA
NA
NA A
NA
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
co
CO
Audit
No. Client*** Use of Audit Material
170 AK Hazardous waste trial
burn
171 AK Hazardous waste trial
burn
172 AL Ambient air monitoring
method evaluation
173 AL Ambient air monitoring
method evaluation
174 AL Ambient air monitoring
method evaluation
Audit Material
Acetonitrile
Acrylonitrile
Carbon Tetrachloride
Chloroform
Perch loroethylene
Benzene
Vinyl Chloride
Acetonitrile
Tri chl oroethylene
1 , 2-Di chl oroethane
Tri chl orof 1 uoromethane
Di chl orodi f 1 uoromethane
1,1,1 -Tri chl oroethane
Freon 114
Freon 113
Vinylidene Chloride
Toluene
Chlorobenzene
RTI
Cone.
119
29.3
12.3
48.3
13.3
24.6
21.1
9.3
8.6
10.5
9.4
10.6
8.5
142
155
157
162
161
Audit
(ppb)
± 8.3
± 2.0
± 0.4
± 1.0
± 0.3
± 0.8
± 0.7
± 0.7
± 0.4
± 0.5
± 0.3
± 0.4
± 0.4
± 26
± 20
± 22
± 11
± 27
Client
Audit Status
% Bias of
(avg.)* Audit**
+13 B
+199 B
-19 B
-9
-25
-31
-10
-100 B
+6
+6
-14
-14
+18
-13- B
-27
-23
-15
-8
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material
175 I Ambient air monitoring
method evaluation
176 I Ambient air monitoring
method evaluation
177A I Ambient air monitoring
method evaluation
177B I Ambient air monitoring
method evaluation
177C I Ambient air monitoring
method evaluation
Audit Material
Carbon Tetrachloride
Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
Acetonitri le
Methyl Ethyl Ketone
Tri chl oroethyl ene
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1,2-Dibromoethane
1,1,1 -Tri chl o roethane
1,3-Butadiene
Methyl ene Chloride
1,3-Butadiene
Methyl ene Chloride
Ortho-xylene
Methyl ene Chloride
Ortho-xylene
RTI
Cone.
129
123
131
130
153
137
155
148
152
153
185
158
162
149
12.6
10.7
12.6
10.7
11.2
10.7
11.2
Audit
(ppb)
± 3.8
± 2.6
± 3.2
± 4.2
± 5.0
± 9.4
± 8.2
± 7.2
± 7.8
±4.7
± 7.4
± 6.1
± 6.8
± 7.8
± 1.7
± 1.1
± 1.7
± 1.1
± 1.1
± 1.1
± 1.1
Client
Audit
% Bias
(avg.)*
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-21
-15
+3
-32
+25
-29
+4
Status
of
Audit**
A
A
•
B
B
B
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
en
Audit
No. Client*** Use of Audit Material
17 7D I Ambient air monitoring
method evaluation
178 AM Hazardous waste trial
burn
179 AM Hazardous waste trial
burn
180 QQ Hazardous waste trial
181 W Hazardous waste trial
burn
Audit Material
Methyl ene Chloride
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
1,3-Butadiene
Ethyl ene Oxide
Propylene Oxide
Methyl ene Chloride
Acrylonitrile
Ortho-xylene
Chlorobenzene
Carbon Tetrachloride
Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
10.7 ± 1.1
307 ± 9.1
114 ± 2.4
120 ± 2.9
389 ± 12.5
423 ± 13.8
940 ± 34
700 ± 30
960 ± 38
840 ± 35
1010 ± 41
1090 ± 42
28.5 ± 4.8
291 ± 8.6
123 ± 2.6
104 ± 2.6
367 ± 11.8
416 ± 13.6
Client
Audit Status
% Bias of
(avg. )* Audit**
-6 B
NA A
NA
NA
NA
NA
NA A
NA
NA
NA
NA
NA
-8 B
-74 B
-61
-52
-84
-32
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
Audit
No. Client*** Use of Audit Material Audit Material
182 RR Hazardous waste landfill Acetonitrile
emissions monitoring Methyl Ethyl Ketone
Tri chl oroethyl ene
1 , 2-Di chl oroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1,2-Dibromoethane
1 ,1 , 1-Tri chl oroethane
183 HH Hazardous waste landfill Freon 114
emissions monitoring Freon 113
Vinylidene Chloride
Acetone
1 ,4-Dioxane
Toluene
Chlorobenzene
184 A Hazardous waste trial Carbon Tetrachloride
burn Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
36.2 ± 2.5
18.0 ± 0.9
41.1 ± 2.1
40.7 ± 2.1
39.4 ± 1.2
24.5 ± 1.0
22.4 ± 0.8
22.7 ± 0.9
20.3 ± 1.1
22.5 ± 4.1
11.0 ± 1.3
35.2 ± 4.9
9.0 ± 2.7
26.0 ± 8.0
11.1 ± 0.8
29.0 ± 4.6
79.6 ± 2.3
72.2 ± 1.5
79.6 ± 2.0
75.6 ± 2.4
69.3 ± 2.2
Client
Audit Status
% Bias of
(avg. )* Audit**
-17 B
NA
-10
+3
+17
NA
+38
-10
-6
NA A
NA
NA
NA
NA
NA
NA
NA A
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
CO
Audit
No. Client*** Use of Audit Material Audit Material
185 0 Hazardous waste trial Trichloroethylene
burn
186 0 Hazardous waste trial Toluene
burn
187 A Ambient air monitoring Bromomethane
method evaluation Trichlorofluoromethane
1,1,1-Trichloroethane
1 , 2-Di chl oropropane
1,2-Dibromoethane
Toluene
Chlorobenzene
Ethyl benzene
. Ortho-xylene
188 QQ Hazardous waste trial Carbon Tetrachloride
burn Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
189 AN Hazardous waste trial Carbon Tetrachloride
burn Chloroform
Perchloroethylene
Benzene
Vinyl Chloride
RTI Audit
Cone, (ppb)
10.
10.
5.
4.
5.
5.
5.
4.
5.
4.
5.
37.
8.
9.
39.
50.
9.
40.
10.
19.
20.
1
2
60
80
17
20
10
96
18
80
21
2
1
0
1
1
45
6
1
2
1
+
+
+
+
+
+
+
+
±
±
±
±
±
±
±
±
±
±
+
+
+
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
1.
0.
0.
0.
0.
0.
5
7
6
6
5
5
4
4
3
3
3
1
2
2
3
6
3
9
3
6
6
Client
Audit
% Bias
(avg.)*
+14
+3
NA
NA
NA
• NA
NA
NA
NA
NA
NA
-13
-22
-11
-27
-44
NA
NA
NA
NA
NA
Status
of
Audit**
B
B
A
A
A
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
OD
00
Audit
No. Client*** Use of Audit Material Audit Material
190 AN Hazardous waste trial Carbon Tetrachloride
burn Chloroform
Perchl oroethylene
Benzene
Vinyl Chloride
191 JJ Ambient air monitoring Carbon Tetrachloride
method evaluation Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
192 JJ Ambient air monitoring Acetonitrile
method evaluation Methyl Ethyl Ketone
Tri chl orof 1 uoromethane
1,2-Dichloroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1,2-Dibromoethane
1,1,1 -Tri chl oroethane
193 KK Ambient air monitoring Carbon Tetrachloride
method evaluation Chloroform
Perchl oroethyl ene
Benzene
Vinyl Chloride
RTI
Cone.
307
114
120
389
423
133
132
139
134
152
140
142
152
146
151
178
155
152
146
7114
7984
4687
4017
8014
Client
Audit
Audit % Bias
(ppb) (avg.)*
± 9.1
± 2.4
± 2.9
± 12.5
± 13.8
± 4.0
± 2.8
± 3.4
± 4.3
± 5.0
± 9.7
± 7.5
± 7.4
± 7.6
± 4.7
± 7.2
± 6.0
± 6.0
± 7.7
± 118
± 213
± 129
± 152
± 133
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
. NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
A
A
A
A
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
oo
Audit
No. Client*** Use of Audit Material Audit Material
194 KK Ambient air monitoring 1,3-Butadiene
method evaluation Ethylene Oxide
Propylene Oxide
Methyl ene Chloride
Acetonitrile
Ortho-xylene
195 I Ambient air monitoring Vinyl Chloride
method evaluation Chloroform
Carbon Tetrachloride
Methyl ene Chloride
1 , 2-Di chl oroethane
Trichloroethylene
Benzene
Tetrachloroethylene
1,3-Butadiene
Bromomethane
Tri chl orof 1 uoromethane
1,1,1 -Tri chl oroethane
1 , 2-Di chl oropropane
1,2-Dibromoethane
Toluene
Chlorobenzene
Ethyl benzene
Ortho-xylene
Client
Audit Status
RTI Audit % Bias of
Cone, (ppb) (avg. )* Audit**
923 ±
697 ±
932 ±
823 ±
1080 ±
1130 ±
9.80 ±
10.5 ±
10.0 ±
10.3 ±
9.84 ±
10.6 ±
9.27 ±
10.1 ±
10.1 ±
5.60 ±
4.80 ±
5.17 ±
5.20 ±
5.10 ±
4.96 ±
5.18 ±
4.80 ±
5.21 ±
35
30
36
36
50
98
1.2
0.6
0.8
1.1
0.8
0.7
0.9
0.9
1.2
0.6
0.6
0.5
0.5
0.4
0.4
0.3
0.3
0.3
MA A
NA
NA
NA
NA
NA
NA A
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material Audit Material
196 A Ambient air monitoring Chloroform
method evaluation Carbon Tetrachloride
(Method 1) Methylene Chloride
Tri chl oroethyl ene
Tetrachl oroethyl ene
1 , 1 , 1-Tri chl oroethane
196 I Ambient air monitoring Chloroform
method evaluation Carbon Tetrachloride
(Method 2) Methylene Chloride
Tri chl oroethyl ene
Tetrachl oroethyl ene
1,1,1 -Tri chl oroethane
197 A Ambient air monitoring Vinyl Chloride
method evaluation Chloroform
Carbon Tetrachloride
Methylene Chloride
1 , 2-Di chl oroethane
Tri chl oroethyl ene
Benzene
Tetrachl oroethyl ene
1,3-Butadiene
RTI Audit
Cone, (ppb)
4.95 ±
4.67 ±
5.00 ±
5.61 ±
5.02 ±
4.67 ±
4.95 ±
4.67 ±
5.00 ±
5.61 ±
5.02 ±
4.67 ±
4.83 ±
4.85 ±
4.99 ±
5.12 ±
4.86 ±
5.47 ±
4.88 ±
5.13 ±
6.05 ±
0.6
0.5
0.6
0.3
0.3
0.3
0.6
0.5
0.6
0.3
0.3
0.3
0.5
0.3
0.4
0.6
0.3
0.4
0.3
0.3
1.3
Client
Audit
% Bias
(avg.)*
+11
+50
+28
+11
-24
+31
-1
+5
-2
-25
-2
+14
NA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
B
B
A
(Continued)
-------
Table 4. Summary of Performance Audit Results (Continued)
Audit
No. Client*** Use of Audit Material Audit Material
198 AD Hazardous waste trial Acetonitrile
burn Methyl Ethyl Ketone
Tri chl oroethyl ene
1 , 2-Di chl oroethane
Tri chl orof 1 uoromethane
Bromomethane
Di chl orodi f 1 uoromethane
1,2-Dibromoethane
1,1,1 -Tri chl oroethane
Client -Measured Concentration - RTI-Measured
RTI Audit
Cone, (ppb)
9.30 ± 0.7
12.7 ± 0.7
8.6 ± 0.4
10.5 ± 0.5
9.40 ± 0.3
10.1 ± 0.4
10.6 ± 0.4
9.30 ±0.4
8.50 ± 0.4
Concentration
Client
Audit
% Bias
(avg.)*
MA
NA
NA
NA
NA
NA
NA
NA
NA
Status
of
Audit**
A
RTI-Measured Concentration
**Status Codes: A = Audit not complete
B = Audit complete
C = Audit completed without results
NA = Not analyzed by auditee
***Whenever the auditee is known, an alphabetical letter is shown. Whenever the auditee is unknown or the
audit is a self-audit, the name of the agency requesting the audit is shown.
****Audit of instrument calibration procedure.
-------
SECTION 4
STABILITY STUDIES
An ideal calibration standard or audit material should be stable over
its total time of usage. Such standards or materials may be considered
stable if the results of reanalyses over time fall within the 95% confidence
limits of the combined uncertainty for the preparation and analysis of the
analyte concentrations.
The gas mixtures were generally analyzed twice by the manufacturer
before shipment to RTI. These analyses were performed to verify that the
components in the cylinder were stable at the manufacturing facility before
shipment to RTI. The gas mixtures are then analyzed at RTI upon receipt
from the specialty gas vendor to corroborate the vendors analysis. The gas
mixtures are again analyzed by RTI at 2 months, 6 months, 12 months, and on
an annual basis thereafter following the initial RTI analysis to determine
the long term stability of the gas mixtures. The results of the analyses of
the cylinder gases by the manufacturer and by RTI, along with the results
for the RTI analysis of NBS primary standards are summarized in the stabil-
ity data tables shown in Appendix A.
Relative accuracies of the cylinder gas analyses for Group I, Group II,
Group III, Group IV and Group V compounds have been determined using NBS
primary standards on each day of RTI analysis. The method used by NBS to
estimate the total uncertainty of NBS primary standards at the 95 percent
confidence level has been reported.1 The NBS concentrations and their
total uncertainties at 95% confidence limits for Group I, Group II, Group
III, Group IV and Group V compounds are included in the stability data
tables in Appendix A. These primary standards have been assessed for sta-
bility by NBS, and no change in concentrations has been observed that has
exceeded the 95% confidence limit of the concentrations. The NBS maintains
a continued QA program for these primary standards in which reanalyses are
conducted over time to verify that the concentrations have not changed.
An examination of the stability data for the cylinders gases in Appen-
dix A shows that values for the Group I, Group II and Group III compounds
usually vary by less than 10 percent for 4 or 5 analyses over a 2-year peri-
od. This variation includes the uncertainty of the NBS primary standards
and precision of the RTI measurement process. The possible sources of
92
-------
experimental error in the measurement process that contribute to this vari-
ability include: (1) the variability of the sampling injection technique
used for analyses of the primary standards and the audit cylinders; and (2)
the instrumental variability in operating and detector parameters. Each of
these sources of variability contributes to the total uncertainty of the
resulting data presented in Appendix A.
The procedure used for the determination of day-to-day measurement un-
.certainty (repeatability when NBS primary gas standards are used for
calibration is different then the procedure used when calibration was
performed with permeation devices. The total uncertainty calculation
procedure when using permeation devices was described in Status Report
#3.3 The total uncertainty for the measurements when calibration is with
an NBS primary gas standard is arrived at by summing in quadrature the
estimates of error from several sources. These sources of error include:
1. NBS uncertainties associated with concentration values reported by
NBS for the primary standard cylinder;
2. Uncertainties associated with the RTI injection of the primary NBS
calibration cylinder, and the error associated with peak area meas-
urement;
3. Uncertainties associated with the RTI injection of the sample cyl-
inder and the error associated with the peak area measurement.
The analytical results are reported as the mean parts-per-billion value
for three replicate injections of a given sample cylinder plus or minus the
calculated total uncertainty in parts-per-billion. The total uncertainty at
the 95% confidence limits is calculated as follows:
u (95% confidence) = x * 2 (a/2)2 + b2 + C2)
where: x = Mean concentration in ppb;
a = Uncertainty (95% confidence) associated with the concentra-
tion value of a given organic, reported by NBS for the NBS-
traeable standard mixture, expressed as relative standard
deviation;
b = Uncertainty associated with the RTI analysis imprecision
(one standard deviation) of the NBS-traceable standard used
for calibration, expressed as relative standard deviation.
c = Uncertainty associated with the RTI analysis imprecision
(peak area, one standard deviation) of the sample cylinder,
expressed as relative standard deviation.
93
-------
In this manner, the total uncertainty at the 95% confidence limit is
assigned to the concentration of each organic determined in the audit cylin-
der mixtures.
The question of whether the uncertainties expressed in the above equa-
tion should be pooled in quadrature or linearly to obtain the total uncer-
tainty is currently under statistical evaluation by NBS/EPA/RTI. Any
modification to this equation, including the consideration of the number of
analyses involved in the b and c terms, will be addressed in the future
report.
94
-------
SECTION 5
SUMMARY AND CONCLUSIONS
Cylinder gases containing 29 gaseous organic compounds at parts-per-
billion levels have been used successfully in audits to assess the relative
accuracy of analytical systems, especially those used during hazardous waste
trial burn tests and ambient air monitoring. The cylinder gases contain
five mixtures of five, six, eight, nine and eighteen organic compounds each.
These mixtures were blended by a commercial specialty gas supplier in alumi-
num cylinders in a balance gas of nitrogen. The five component mixture
(Group I) contains carbon tetrachloride, chloroform, tetrachloroethylene
(perchloroethylene), vinyl chloride and benzene. The nine component mixture
(Group II) includes trichloroethylene, 1,2-dichloroethane, 1,2-dibromo-
ethane, acetonitrile, trichlorofluoromethane (F-ll), dichlorodifluoromethane
(F-12), bromomethane, methyl ethyl ketone and 1,1,1-trichloroethane. The
eight component mixture (Group III) includes pyridine*, vinylidene chloride,
1,1,2-trichloro 1,2,2-trifluoroethane (F-113), 1,2- dichloro 1,1,2,2-tetra-
fluoroethane (F-114), acetone, 1,4-dioxane, toluene, and chlorobenzene. The
six component mixture (Group IV) includes acrylonitrile, '1,3-butadiene,
ethylene oxide, methylene chloride, propylene oxide, and o-xylene. The
eighteen component mixture (Group V) includes vinyl chloride, chloroform,
carbon tetrachloride, methylene chloride, 1,2-dichloroethane, trichloroeth-
ylene, benzene, tetrachloroethylene, 1,3-butadiene, bromomethane, trichloro-
fluoromethane (F-ll), 1,1,1-trichloroethane, 1,2-dichloropropane, 1,2-dibro-
moethane, toluene, chlorobenzene, ethylbenzene and o-xylene.
Stability studies for 29 compounds (Group I, Group II, Group III, Group
IV and Group V) have been performed to determine the feasibility of using
them as audit materials. Results indicate that all of the organics tested
(with the exception of ethylene oxide and propylene oxide) are stable enough
to be used as reliable audit materials.
Subsequent to completion of the stability studies, 198 performance
audits have been initiated to date with Group I, Group II and Group III
cylinders and 172 are complete. Generally, the audit results are within +_
50 percent of the audit concentrations measured by RTI.
*Although Group III cylinders contain pyridine, it is not included in the
cylinder gases due to severe analytical difficulties.
95
-------
REFERENCES
1. Rhoderick, G. C., W. F. Cuthrell and W. L. Zielinski, Jr., "A Gravi-
metric Technique for the Preparation of Accurate Trace Organic Gas Stan-
dards", Proceedings APCA International Specialty Conference on Quality
Assurance in Air Pollution Measurements, PP 239-246, 1985.
2. Jayanty, R. K. M., S. W. Cooper, C. E. Decker and D. J. von Lehmden,
"Evaluation of Parts-Per-Billion (PPB) Organic Cylinder Gases for Use as
Audits During Hazardous Waste Trial Burn Tests". J. Air Pollution Con-
trol Association, Vol. 39, November 1985.
3. Allen, J. M., C. K. Sokol, R. K. M. Jayanty and C. E. Decker, "Stability
of Parts-Per-Bi11 ion Hazardous Organic Cylinder Gases and Performance
Audit Results of Source Test and Ambient Air Measurement Systems --
Status Report #3". EPA-600/4-87-007, March 1987.
96
-------
APPENDIX A
STABILITY STUDY FOR GROUP I COMPOUNDS
STABILITY STUDY FOR GROUP II COMPOUNDS
STABILITY STUDY FOR GROUP III COMPOUNDS
STABILITY STUDY FOR GROUP IV COMPOUNDS
STABILITY STUDY FOR GROUP V COMPOUNDS
A-l
-------
STABILITY STUDY FDR GROUP I COMPOUNDS***
CYLINDER I-C1
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(305)
10/13/83
(300)
12/14/83
(269)
(302)
10/13/83
(220)
12/14/83
(253)
(305)
10/13/83
(317)
12/14/83
(298)
(305)
IV 15/83
(269)
12/12/83
(282)
—
IV 15/83
(310)
12/12/83
(314)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTT Analysis Day*
PPB
12/30/83
(283 + 8.5)
62
(300 + 9.0)
241
(277 + 8.3)
404
(277 + 8.3)
on audit
833
(279 + 8.3)
on audit
12/30/83
(222 + 4.7)
62
(228 + 4.8)
241
(221 + 4.6)
404
(224 + 4.7)
on audit
833
(220 + 4.7)
on audit
12/30/83
(373 + 9.0)
62
(375 + 9.0)
241
(347 + 8.3)
404
(356 + 8.5)
on audit
833
(359+8.8)
on audit
1/12/84
(289 + 9.2)
62
(287 + 9.2)
235
(304+9.7)
378
(286 + 9.2)
(302 + 9. 7)
810
(297 + 9.6)
on audit
1/12/84
(325+10.4)
62
(328 + 10.5)
235
(325 + 10.4)
378
(334+ 10.7)
(319 + 10.2)
810
(338 + 11.1)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB NA
NBS Concentration
PPB
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
NA
(192+4.0)
NA
(192 + 4.0)
(Continued)
A-2
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C1
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
62 62 62
(164 + 4.9) (130 + 2.7) (151 + 3.6)
62 62
(192+6.1) (192 + 6.1)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192 + 4.0) (192+4.0)
3rd RTI Analysis Day
PPB
241 241 241
(156 + 4.7) (132 + 2.8) (147 + 3.5)
235 235
(191+6.1) (191 + 6.1)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192+4.0) (192+4.0)
4th RTI Analysis Day
PPB
404 404 404
(156+4.7) (128 + 2.7) (143 + 3.4)
378 378
(200 + 6.4) (195 + 6.2)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192 + 4.0) (192 + 4.0)
5th RTI Analysis Day
PPB
500 500 500
(141 + 4.2) (115 + 2.4) (128+3.1)
505 505
(139 + 4.4) (149 + 4.8)
NBS Concentration
PPB
(141+3.0) (115 + 3.0) (128 + 3.0) (133 + 3.0) (154+3.0)
6th RTI Analysis Day
PPB
833 833 833
(166 + 5.0) (130 + 2.7) (144 + 3.5)
810 810
(143 + 4.6) (156 + 5.1)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day
PPB
1350 D50 1350
(154 + 3.0) (131 + 2.4) (146 + 3.0)
1350 1350
(191+6.0) (191+4.0)
NBS Concentration
PPB
(155 + 5.0) (134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-3
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C2
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(319)
10/13/83
(301)
12/14/83
(295)
(316)
10/13/83
(243)
12/14/83
(258)
(319)
10/13/83
(356)
12/14/83
(342)
(319)
12/12/83
(317)
12/14/83
(294)
—
12/12/83
(292)
12/14/83
(293)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(315 + 9.5)
62
(327 +9.8)
241
(305 + 9.2)
404
(305 + 9.2)
500
(306 + 9.2)
on audit
12/30/83
(226+4.7)
62
(233 + 4.9)
241
(230 + 4.8)
404
(229 + 4.8)
500
(223 + 4.7)
on audit
1350 1350
(320 + 22.3) (227 + 9.0)
12/30/83 1/12/84
(425 + 10.2) (305 + 9.8)
1/12/84
(295 + 9.4)
62 62 62
(436 + 10.5) (314 + 10.0) (303 + 9.7)
241
(406 + 9.7)
404
(407 + 9.8)
500
(398 + 9.6)
on audit
1350
(400 + 19)
235 235
(326 + 10.4) (304+9.7)
378 378
(313 + 10.0) (309 + 9.9)
502 502
(325 + 10.4) (308 + 9.9)
on audi t
on audi t
1350 D50
(305 + 26.5) (318 + 30.6)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
NA
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
NA
(192+4.0)
NA
(192 + 4.0)
(Continued)
A-4
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C2
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
(155 + 3.0)
241
(156 + 4.7)
(155 + 3.0)
404
(156 + 4.7)
(155 + 3.0)
500
(141+4.2)
(141+3.0)
833
(166 + 5.0)
(155 + 3.0)
1350
(154 + 3.0)
(155 + 5.0)
62
(130 + 2.7)
(134 + 3.0)
241
(132 + 2.8)
(134 + 3.0)
404
(128 + 2.7)
(134 + 3.0)
500
(115 + 2.4)
(115 + 3.0)
833
(130 + 2.7)
(134 + 3.0)
1350
(131+ 2.4)
(134 + 5.0)
62
(151 + 3.6)
(146 + 3.0)
241
(147 + 3.5)
(146 + 3.0)
404
(143 + 3.4)
(146 + 3.0)
500
(128 + 3.1)
(128 +3.0)
833
(144 + 3.5)
(146 + 3.0)
1350
(146 + 3.0)
(146 + 3.0)
62
(192 + 6.1)
(192+4.0)
235
(191 + 6.1)
(192 + 4.0)
378
(200 + 6.4)
(192 +4.0)
502
(137 + 4.4)
(133 + 3.0)
810
(143 + 4.6)
(133 + 3.0)
1350
(191 + 6.0)
(192+3.0)
62
(192 + 6.1)
(192 + 4.0)
235
(191 + 6.1)
(192 + 4.0)
378
(195 + 6.2)
(192 + 4.0)
502
(145 + 4.6)
(154+3.0)
810
(156 + 5.1)
(154+3.0)
1350
(191+4.0)
(190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-5
-------
STABILITY STUDY FDR GROUP I COMPOUNDS***
'CYLINDER
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(294)
10/13/83
(308)
12/14/83
(272)
(291)
10/13/83
(223)
12/14/83
(256)
(293)
10/13/83
(321)
12/14/83
(299)
(294)
11/15/83
(271)
12/12/83
(284)
(290)
11/15/83
(287)
12/12/83
(290)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(287 + 8.6)
62
(303 + 9.1)
241
(283+8.5)
404
(280 + 8.4)
500
(281 + 8.4)
833
(291+8.7)
on audit
12/30/83
(224+4.7)
62
(234 + 4.9)
241
(230+4.8)
404
(229+4.8)
500
(223 + 4.7)
833
(232+4.9)
on audit
12/30/83
(373 + 9.0)
62
(369+8.9)
241
(352 + 8.4)
404
(354 + 8.5)
500
(347+8.3)
833
(365 + 9.0)
on audit
V 12/84
(288 + 9.2)
62
(289 + 9.2)
235
(300 + 9.6)
378
(289 + 9.2)
502
(302 + 9.7)
810
(300 + 9.7)
on audi t
1/12/84
(295 + 9.4)
62
(302 + 9.7)
235
(306+9.8)
378
(308 + 9.9)
502
(308 + 9.9)
810
(312 + 10.2)
on audi t
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
m
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
NA
(192+4.0)
NA
(192 + 4.0)
(Continued)
A-6
-------
STABILITY STUDY FOR (SOUP I COMPOUNDS*** (Continued)
CYLINDER I-C3
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
62
(130 + 2.7)
(155 + 3.0) (134 + 3.0)
241 241
(156 + 4.7) (132 + 2.8)
(155 + 3.0)
404
(156 + 4.7)
(155 + 3.0)
500
(141 + 4.2)
(141 + 3.0)
833
(166 + 5.0)
(155 + 3.0)
1350
(154 + 3.0)
(155 + 5.0)
(134 + 3.0)
404
(128 + 2.7)
(134 + 3.0)
500
(115 + 2.4)
(115 + 3.0)
833
(130 + 2.7)
(134 + 3.0)
1350
(131 + 2.4)
(134 + 5.0)
62
(151 + 3.6)
(146 + 3.0)
241
(147 + 3.5)
(146 + 3.0)
404
(143 + 3.4)
(146 + 3.0)
500
(128 +3.1)
(128+3.0)
833
(144 + 3.5)
(146 + 3.0)
1350
(146 + 3.0)
(146 + 3.0)
62
(192 + 6.1)
(192 + 4.0)
235
(191 + 6.1)
(192 + 4.0)
378
(200 + 6.4)
(192+4.0)
502
(137 + 4.4)
(133 + 3.0)
810
(143 + 4.6)
(133 + 3.0)
1350
(191 + 6.0)
(192 + 3.0)
62
(192 + 6.1)
(192 + 4.0)
235
(191 + 6.1)
(192 + 4.0)
378
(195 + 6.2)
(192 + 4.0)
502
(145 + 4.6)
(154+3.0)
810
(156 + 5.1)
(154 + 3.0)
1350
(191 + 4.0)
(190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-7
-------
STABILITY STUDY FOR GROUP I (DMPOUNES***
CYLINDER I-C4
AaiVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(268)
12/09/83
(267)
12/14/83
(256)
(271)
12/09/83
(232)
12/14/83
(241)
(271)
12/09/83
(281)
12/14/83
(259)
(274)
12/02/83
(248)
12/12/83
(262)
-?-
12/02/83
(283)
12/12/83
(287)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTT Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(270 + 8.1)
62
(278 + 8.3)
241
(267 + 8.0)
404
(266 + 8.0)
500
(265 + 8.0)
on audi t
1350
(261 + 7.9)
12/30/83
(211 + 4.4)
62
(214 + 4.5)
241
(214 + 4.5)
404
(216+4.5)
500
(208 + 4.4)
on audit
1350
(216+4.6)
12/30/83
(308 + 7.4)
62
(317 + 7.6)
241
(299 + 7.2)
404
(311 + 7.5)
500
(295 + 7.1)
on audit
1350
(289 + 7.0)
V 12/84
(263 + 8.4)
62
(263 + 8.4)
235
(281 + 9.0)
378
(266 + 8.5)
502
(277 + 8.9)
on audit
1350
(261 + 8.1)
1/12/84
(291 + 9.3)
62
(296 + 9.5)
235
(300 + 9.6)
378
(301 + 9.6)
502
(302 + 9.7)
on audit
1350
(289 + 9.3)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
NA
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
NA
(192+4.0)
NA
(192 + 4.0)
(Continued)
A-8
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C4
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
etnylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 62 62 62 62 62
PPB (164+ 4.9) (130 + 2.7) (151 + 3.6) (192 + 6.1) (192 + 6.1)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192+4.0) (192 + 4.0)
3rd RTI Analysis Day • 241 241 241 235 235
PPB (156+4.7) (132 + 2.8) (147 + 3.5) (191 + 6.1) (191 + 6.1)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192 + 4.0) (192 + 4.0)
4th RTI Analysis Day 404 404 404 378 378
PPB (156 + 4.7) (128+2.7) (143 + 3.4) (200 + 6.4) (195 + 6.2)
NBS Concentration
PPB
(155 + 3.0) (D4 + 3.0) (146 + 3.0) (192+4.0) (192+4.0)
5th RTI Analysis Day 500 500 500 502 502
PPB (141+4.2) (115+2.4) (128+3.1) (137 + 4.4) (145 + 4.6)
NBS Concentration
PPB
(141 + 3.0) (115 + 3.0) (128+3.0) (133 + 3.0) (154 + 3.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (161+4.8) (132 + 2.8) (148+3.6) (139+4.5) (153 + 5.0)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day 1350 1350 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191+6.1) (191+4.0)
NBS Concentration
PPB
(155 + 5.0) (134 + 5.0) (146 + 3.0) (192 + 3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-9
-------
STABILITY STUDY FOR GROUP I (DMPOUNDS***
CYLINDER I-C5
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(133)
10/3 1/83
(122)
12/10/83
(118)
(132)
10/31/83
(123)
12/10/83
(130)
(133)
10/31/83
(124)
12/10/83
(119)
(134)
IV 16/83
(127)
12/13/83
(131)
150
IV 16/83
(143)
12/13/83
(146)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(133 + 4.1)
62
(139+4.2)
242
(132+4.0)
404
(124 + 3.7)
501
(132 + 4.0)
833
(137+4.1)
1350
(133 +4.0)
12/30/83
(125 + 2.6)
62
(130 + 2.7)
242
(129+2.7)
404
(125 + 2.6)
501
(128 + 2.7)
833
(132 + 2.8)
1350
(132 + 2.8)
12/30/83
(138 + 3.3)
62
(144 + 3.5)
242
(136 + 3.3)
404
(135 + 3.2)
501
(137 + 3.3)
833
(142 + 3.5)
1350
(139+3.4)
1/17/84
(132 + 4.2)
54
(139 +4.4)
230
(146 + 4.7)
374
(140 + 4.5)
498
(139 + 4.4)
810
(137 + 4.4)
1350
(134 + 4.3)
1/17/84
(154 + 4.9)
54
(152 + 4.9)
230
(153+4.9)
374
(154 + 4.9)
498
(154 + 4.9)
810
(149+4.9)
1350
(152 + 5.0)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
__«_
NA
(155 + 3.0)
«••
NA
(134 + 3.0)
....
NA
(146 + 3.0)
1/17/84
(135)
(133 + 3.0)
1/17/84
(155)
(154 + 3.0)
(Continued)
A-10
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C5
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
(155 + 3.0)
242
(157 + 4.7)
(155 + 3.0)
404
(156 + 4.7)
(155 + 3.0)
501
(142 + 4.3)
(141 + 3.0)
833
(161+4.8)
(155 +3.0)
1350
(154 + 3.0)
(155 + 5.0)
62
(130 + 2.7)
(134 + 3.0)
242
(133 + 2.8)
(134 + 3.0)
404
(128 + 2.7)
(134 + 3.0)
501
(115 + 2.4)
(120 + 3.0)
833
(132 + 2.8)
(134 + 3.0)
D50
(131 + 2.4)
(134 + 5.0)
62
(151 + 3.6)
(146 + 3.0)
242
(144 + 3.5)
(146 + 3.0)
404
(143 + 3.4)
(146 + 3.0)
501
(126 +3.0)
(126 + 3.0)
833
(148 + 3.6)
(146 + 3.0)
1350
(146 + 3.0)
(146 + 3.0)
54
(141 + 4.5)
(133 + 3.0)
230
(147 + 4.7)
(133 + 3.0)
374
(147 + 4.7)
(192+4.0)
498
(139 + 4.4)
(133 + 3.0)
810
(139+4.5)
(133 + 3.0)
1350
(191 + 6.1)
(192 + 3.0)
54
(153 + 4.9)
(154 + 3.0)
230
(153 + 4.9)
(154 + 3.0)
374
(152 + 4.9)
(192 + 4.0)
498
(154 + 4.9)
(154 + 3.0)
810
(153 + 5.0)
(154 + 3.0)
1350
(191+4.0)
(190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Penreation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-H
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C6
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(134)
10/31/83
(126)
12/10/83
(115)
(133)
10/31/83
(126)
12/10/83
(129)
(134)
10/31/83
(128)
12/10/83
(114)
(135)
11/16/83
(128)
12/12/83
(133)
(15)
IV 16/83
(142)
12/12/83
(143)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(134 + 4.0)
62
(137 + 4.1)
242
(131 + 3.9)
404
(129+3.9)
501
(132 + 4.0)
833
(134 + 4.0)
1350
(133 + 4.0)
12/30/83
(124 + 2.6)
62
(128 + 2.7)
242
(129+2.7)
404
(126 + 2.6)
501
(128 + 2.7)
833
(129 + 2.7)
1350
(128+2.7)
12/30/83
(137 + 3.3)
62
(140+ 3.4)
242
(135 + 3.2)
404
(135 + 3.2)
501
(137+3.3)
833
(137 + 3.4)
1350
(135 + 3.3)
1/17/84
(136 + 4.4)
54
(138+4.4)
230
(147 + 4.7)
374
(140 + 4.5)
498
(138+4.4)
810
(139 + 4.5)
1350
(136 + 4.3)
1/17/84
(155+ 5.0)
54
(150 + 4.8)
230
(152 + 4.9)
374
(148 + 4.7)
498
(153+4.9)
810
(151 + 4.9)
1350
(154+5.0)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
NA
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
1/17/84
(135 + 4.3)
(133 + 3.0)
1/17/84
(155+ 5.0)
(154 + 3.0)
(Continued)
A-12
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C6
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
(155 + 3.0)
242
(157 + 4.7)
(155 + 3.0)
404
(156 + 4.7)
(155 + 3.0)
501
(142 + 4.3)
(141 + 3.0)
833
(161+4.8)
(155 + 3.0)
1350
(154 + 3.0)
(155 + 5."0)
62
(130 + 2.7)
(134 + 3.0)
242
(133 + 2.8)
(134 + 3.0)
404
(128 + 2.7)
(134 + 3.0)
501
(115 +2.4)
(120+3.0)
833
(132 + 2.8)
(134 + 3.0)
1350
(131 + 2.4)
(134 + 5.0)
62
(151 + 3.6)
(146 + 3.0)
242
(144 + 3.5)
(146 + 3.0)
404
(143 + 3.4)
(146 + 3.0)
501
(126 + 3.0)
(126 + 3.0)
833
(148 + 3.6)
(146 + 3.0)
1350
(146 + 3.0)
(146 + 3.0)
54
(141 + 4.5)
(133 + 3.0)
230
(147 + 4.7)
(133 + 3.0)
374
(147 +4.7)
(192+4.0)
498
(139+4.4)
(133 + 3.0)
810
(139+4.5)
(133 + 3.0)
1350
(191 + 6.1)
(192+3.0)
54
(153 + 4.9)
(154 + 3.0)
230
(153 + 4.9
(154 + 3.0)
374
(152 + 4.9)
(192 +4.0)
498
(154 + 4.9)
(154 + 3.0)
810
(153 + 5.0)
(154 + 3.0)
1350
(191+4.0)
(190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-13
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C7
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theore tical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(134)
10/31/83
(122)
12/10/83
(117)
(132)
10/31/83
(124)
12/10/83
(126)
(133)
10/31/83
(124)
12/10/83
(113)
(134)
12/01/83
(127)
12/13/83
(131)
(150)
12/01/83
(146)
12/13/83
(143)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(132 + 4.0)
62
(135 +4.1)
242
(133 + 4.0)
404
(128 + 3.8)
501
(131 + 3.9)
833
(134 + 4.0)
on audit
12/30/83
(125 + 2.6)
62
(127 + 2.7)
242
(129+2.7)
404
(125 + 2.6)
501
(125 + 2.6)
833
(129 + 2.7)
on audi t
12/30/83
(139 + 3.3)
62
(142 + 3.4)
242
(135 + 3.2)
404
(140 + 3.4)
501
(137+3.3)
833
(139+3.4)
on audi t
1/17/84
(132 + 4.2)
54
(138+4.4)
230
(145 + 4.6)
374
(141 + 4.5)
498
(137+4.4)
810
(137+4.4)
on audit
V 17/84
(155 + 5.0)
54
(152 + 4.9)
230
(154 + 4.9)
374
(156 + 5.0)
498
(156 + 5.0)
810
(151 +4.9)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB NA
NBS Concentration
PPB
NA
(155 + 3.0) (134 + 3.0)
NA
(146 + 3.0)
1/17/84
(135+4.3)
(133 + 3.0)
1/17/84
(155 + 5.0)
(154 + 3.0)
(Continued)
A-14
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C7
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
CMoride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
(155 + 3.0)
242
(157 + 4.7)
(155 + 3.0)
62
(130 + 2.7)
(134 + 3.0)
242
(133 + 2.8)
(134 + 3.0)
62
(151+3.6)
(146 + 3.0)
242
(144 + 3.5)
(146 + 3.0)
54
(141 + 4.5)
(133 + 3.0)
230
(147 + 4.7)
(133 + 3.0)
54
(153 + 4.9)
(154 + 3.0)
230
(153 + 4.9)
(154 + 3.0)
404 404 404 374 374
(156 + 4.7) (128+2.7) (143 + 3.4) (147 + 4.7) (152+4.9)
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192+4.0) (192+4.0)
501 501 501 498 498
(142 + 4.3) (115 + 2.40 (126 + 3.0) (139+4.4) (154 + 4.9)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
833 833 833 810 810
(161+4.8) (132 + 2.8) (148 + 3.6) (139+4.5) (153+5.0)
(155 + 3.0) (134 + 3.0) (146 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day 1350
PPB (154 + 3.0)
NBS Concentration
PPB (155 + 5.0)
1350 1350 1350 1350
(131 + 2.4) (146 + 3.0) (191 + 6.1) (191+4.0)
(134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Nun±>er of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic precconcentration with cryofocusing followed'
by GC/FID. Previous analysis were performed by direct injection.
A-15
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C8
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(128)
10/31/83
(117)
12/10/83
(113)
(126)
10/3 V83
(119)
12/10/83
(126)
(127)
10/31/83
(125)
12/10/83
(116)
(128)
IV 16/83
(121)
12/13/83
(125)
(150)
IV 16/83
(147)
12/13/83
(148)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
12/30/83
(127 + 3.8)
62
(131 + 3.9)
242
(127+3.8)
404
(124 + 3.7)
on audit
833
(129+3.8)
on audi t
12/30/83
(119 + 2.5)
62
(122 + 2.6)
242
(123 + 2.6)
404
(117+2.5)
on audit
833
(123 + 2.6)
on audit
12/30/83
(131 + 3.1)
62
(134 + 3.2)
242
(129+3.1)
404
(131 + 3.1)
on audit
833
(131 + 3.2)
on audit
1/17/84
(127 +4.1)
54
(133 + 4.3)
230
(140 + 4.5)
374
(143 + 4.6)
on audit
810
(130 + 4.2)
on audit
1/17/84
(158 + 5.1)
54
(154 + 4.9)
230
(153 + 4.9)
374
(154 + 4.9)
on audit
810
(153+5.0)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
NA
(155 + 3.0)
NA
(134 + 3.0)
NA
(146 + 3.0)
V 17/84
(135 + 4.3)
(133 + 3.0)
1/17/84
(155 + 5.0)
(154 + 3.0)
(Continued)
A-16
-------
STABILITY STUDY FDR GROUP I CDMPOUNES*** (Continued)
CYLINDER I-C8
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
62
(164 + 4.9)
(155 + 3.0)
242
(157 + 4.7)
(155 + 3.0)
404
(156 + 4.7)
(155 + 3.0)
501
(142 + 4.3)
(141 + 3.0)
833
(161 + 4.8
(155 + 3.0)
1350
(154 + 3.0)
(155 + 5.0)
62
(130 + 2.7)
(134 + 3.0)
242
(133 + 2.8)
(134 + 3.0)
404
(128 + 2.7)
(134 + 3.0)
501
(115 + 2.4)
.(120 + 3.0)
833
(132 + 2.8)
(134 + 3.0)
1350
(131 + 2.4)
(134 + 5.0)
62
(151 + 3.6)
(146 + 3.0)
242
(144 + 3.5)
(146 + 3.0)
404
(143 + 3.4)
(146 + 3.0)
501
(126 + 3.0)
(126 + 3.0)
833
(148 + 3.6)
(146 + 3.0)
1350
(146 + 3.0)
(146 + 3.0)
54
(141 + 4.5)
(133 + 3.0)
230
(147+4.7)
(133 + 3.0)
374
(147 + 4.7)
(192 + 4.0)
498
(139+4.4)
(133 + 3.0)
810
(139 + 4.5)
(133 + 3.0)
1350
(191 + 6.1)
(192+3.0)
54
(153 + 4.9)
(154 + 3.0)
230
(153 + 4.9)
(154 + 3.0)
374
(152 + 4.9)
(192 + 4.0)
498
(154 + 4.9)
(154 + 3.0)
810
(153 + 5.0)
(154 + 3.0)
1350
(191+4.0)
(190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-17
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C9
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(70.8)
10/25/83
(72.5)
12/12/83
(68.3)
(70.0)
10/25/83
(68.9)
12/12/83
(72.3)
(70.6)
10/25/83
(72.7)
12/12/83
(69.8)
(71.0)
11/28/83
(67.2)
12/13/83
(73.1)
(70.0)
11/28/83
(70.6)
12/13/83
(69.6)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/04/84
(72.8 + 2.2)
58
(73.7 + 2.2)
on audit
on audit
497
(71.7 + 2.2)
833
(79.6+2.3)
on audit
V04/84
(65.3 + 1.4)
58
(68.6 + 1.4)
on audit
on audit
497
(68.8 + 1.4)
833
(72.2 + 1.5)
on audit
1/04/84
(74.6 + 1.8)
58
(76.2 + 1.8)
on audit
on audit
497
(71.6 + 1.7)
833
(79.6 + 2.0)
on audi t
1/17/84
(76.2 + 2.4)
51
(73.2+2.3)
on audit
on audit
499
(72.6+2.3)
810
(75.6 + 2.4)
on audi t
1/17/84
(72.9 + 2.3)
51
(73.1 + 2.3)
on audit
on audi t
499
(71.0 + 2.3)
810
(69.3 + 2.2)
on audi t
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/04/84
(144 + 4.3)
(141+3.0)
1/04/84
(114 + 2.4)
(120 + 3.0)
1/04/84
(127 + 3.0)
(126 + 3.0)
1/17/84
(135 + 4.3)
(133 + 3.0)
1/17/84
(155 + 5.0)
(154 + 3.0)
(Continued)
A-18
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C9
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 58 58 58 51 51
PPB (147 + 4.4) (116 + 2.4) (134 + 3.2) (17.0 + 0.5) (15.0 + 0.5)
NBS Concentration**
PPB (141 + 3.0) (120 + 3.0) (126 + 3.0) (17 + 1.0) (15 + 1.0)
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration**
PPB
240 240 240 231 231
(146 + 4.4) (120 + 2.5) (131 + 3.1) (146 + 4.7) (152 + 4.9)
(141 + 3.0) (120 + 3.0) (126+3.0) (133 + 3.0) (154 + 3.0)
401 401 401 377 377
(142 + 4.3) (120 + 2.5) (127+3.0) (136+4.4) (150 + 4.8)
(141 + 3.0) (120 + 3.0) (126+3.0) (133 + 3.0) (154 + 3.0)
497 497 497 499 499
(141 + 4.2) (116+2.4) (129+3.1) (136 + 4.4) (149 + 4.8)
(141 + 3.0) (120 + 3.0) (126+3.0) (133 + 3.0) (154 + 3.0)
833 833 833 810 810
(144 + 4.3) (119+2.5) (135 + 3.3) (139+4.5) (153+5.0)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day 1350 1350 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191+4.0)
NBS Concentration
PPB
(155 + 5.0)
(134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Nurriber of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-19
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C10
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(66.0)
10/25/83
(65.2)
12/12/83
(62.5)
(65.2)
10/25/83
(64.8)
12/12/83
(66.1)
(65.8)
10/25/83
(67.9)
12/12/83
(64.6)
(66.2)
1V28/83
(61.0)
12/13/83
(66.0)
(70.0)
1V28/83
(70.1)
12/13/83
(67.5)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/04/84
(66.5 + 2.0)
58
(65.8+2.0)
240
(67.6 + 2.0)
401
(65.2 + 2.0)
497
(64.0 + 1.9)
833
(70.0 + 2.1)
on audit
1/04/84
(58.6 + 1.2)
58
(60.6 + 1.3)
240
(64.6 + 1.4)
401
(63.6 + 1.3)
497
(62.7 + 1.3)
833
(64.3 + 1.4)
on audit
1/04/84
(67.7 + 1.6)
58
(68.4 + 1.6)
240
(69.4 + 1.7)
401
(71.7 + 1.7)
497
(64.3 + 1.5)
833
(72.3 + 1.8)
on audit
1/17/84
(68.7 + 2.2)
51
(66.4 + 2.1)
231
(72.0 + 2.3)
377
(70.4 + 2.3)
499
(66.0 + 2.1)
810
(68.2 + 2.2)
on audit
1/17/84
(71.3 + 2.3)
51
(71.5 + 2.3)
231
(71.6 + 2.3)
377
(68.5 + 2.2)
499
(69.0 + 2.2)
810
(71.7 + 2.3)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/04/84
PPB (144 + 4.3)
MBS Concentration
PPB
(141 + 3.0)
1/04/84
(114 + 2.4)
(120 + 3.0)
1/04/84
(127 + 3.0)
1/17/84
(135 + 4.3)
(126 + 3.0) (133 + 3.0)
1/17/84
(155 + 5.0)
(154 + 3.0)
(Continued)
A-20
-------
STABILITY STUDY FDR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C10
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 58 58 58 51 51
PPB (147+4.4) (116+2.4) (134 + 3.2) (17.0 + 0.5) (15.0 + 0.5)
NBS Concentration**
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0)
(17 + 1.0)
(15 + 1.0)
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
240 240 240 231 231
(146 + 4.4) (120 + 2.5) (131 + 3.1) (146 + 4.7) (152 + 4.9)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
401 401 401 377 377
(142+4.3) (120 + 2.5) (127 + 3.0) (136 + 4.4) (150 + 4.8)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154+3.0)
5th RTI Analysis Day
PPB
NBS Concentration
PPB
497 497
(141 + 4.2) (116+2.4)
(141 + 3.0) (120 + 3.0)
497 499 499
(129 + 3.1) (136 + 4.4) (149 + 4.8)
(126+3.0) (133 + 3.0) (154 + 3.0)
6th RTI Analysis Day
PPB
NBS Concentration**
PPB
833 833 833 810 810
(144 + 4.3) (119+2.5) (135 + 3.3) (139+4.5) (153 + 5.0)
(141 + 3.0) (120 + 3.0)
(126 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day 1350 1350 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191+4.0)
NBS Concentration
PPB
(155 + 5.0) (134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-21
-------
STABILITY STUDY FDR CROUP I OOMPOUNE6***
CYLINDER I-C11
ACTIVITY
COMPOUND
Carbon tetra-
chlorlde
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(66.6)
10/25/83
(65.4)
12/12/83
(62.3)
(65.8)
10/25/83
(62.4)
12/12/83
(65.1)
(66.3)
10/25/83
(65.5)
12/12/83
(64.8)
(66.7)
12/02/83
(61.7)
12/13/83
(65.3)
(70.0)
12/02/83
(66.5)
12/13/83
(67.7)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
* PPB
1/04/84
(66.5 + 2.0)
58
(67.5 + 2.0)
240
(68.2+2.0)
401
(65.2 + 2.0)
497
(65.3+2.0)
833
(70.8 + 2.1)
on audit
1/04/84
(58.1 + 1.2)
58
(60.5 + 1.3)
240
(64.6 + 1.4)
401
(63.6 + 1.3)
497
(62.7 + 1.3)
833
(60.3 + 1.3)
on audit
1/04/84
(66.4 + 1.6)
58
(70.0 + 1.7)
240
(69.6 + 1.7)
401
(71.7 + 1.7)
497
(63.5 + 1.5)
833
(70.1 + 1.7)
on audi t
1/17/84
(67.4 + 2.2)
51
(64.8 + 2.1)
231
(71.1+2.3)
377
(70.4 + 2.3)
499
(69.1 + 2.2)
810
(69.9 + 2.2)
on audit
1/17/84
(69.7 + 2.2)
51
(69.2 + 2.2)
231
(69.8 + 2.2)
377
(68.5 + 2.2)
499
(68.7 + 2.2)
810
(69.3 + 2.2)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/04/84 1/04/84 1/04/84 1/17/84 1/17/84
PPB (144 + 4.3) (114 + 2.4) (127+3.0) (135 + 4.3) (155 + 5.0)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
(Continued)
A-22
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C11
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
e thy lene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 58 58 58 51 51
PPB (147+4.4) (116 + 2.4) (134 + 3.2) (17.0 + 0.5) (15.0 + 0.5)
NBS Concentration**
PPB (141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0)** (15.0 + 1.0)*
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration**
PPB
240 240 240 231 231
(146 + 4.4) (120 + 2.5) (131 + 3.1) (146 + 4.7) (152 + 4.9)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
401 401 401 377 377
(142 + 4.3) (120 + 2.5) (127 + 3.0) (136 + 4.4) (150 + 4.8)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
497 497 497 499 499
(141 + 4.2) (116 + 2.4) (129+3.1) (136 + 4.4) (149+4.8)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
833 833 833 810 810
(144 + 4.3) (119+2.5) (135 + 3.3) (139+4.5) (153+5.0)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
7th RTI Analysis Day 1350 1350 1350 1350 1350
PPB (154+3.0) (131 + 2.4) (146 + 3.0) (191+6.1) (191+4.0)
NBS Concentration
PPB (155 + 5.0) (134 + 5.0) (146+3.0) (192+3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis unless
otherwise indicated. Several different NBS primary standards were used.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-23
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-C12
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(75.3)
10/31/83
(73.4)
12/12/83
(72.1)
(74.4)
10/31/83
(73.5)
12/12/83
(74.2)
(75.1)
10/3 1/S3
(74.1)
12/12/83
(73.6)
(75.6)
11/28/83
(71.0)
12/13/83
(76.4)
(70.0)
11/28/83
(70.1)
12/13/83
(68.9)
RTI ANALYSIS
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
1/04/84
(76.0 + 2.3)
58
(77.0 + 2.3)
240
(79.1 + 2.4)
401
(74.5 + 2.2)
497
(74.0 + 2.2)
empty
1/04/84
(70.7 + 1.5)
56
(71.8 + 1.5)
240
(75.3 + 1.6)
401
(72.6 + 1.5)
497
(70.9 + 1.5)
empty
1/04/84
(80.7 + 1.9)
58
(80.4 + 1.9)
240
(81.7 + 2.0)
401
(80.7 + 1.9)
497
(73.3 + 1.8)
empty
1/17/84
(79.0 + 2.5)
51
(76.6 + 2.5)
231
(82.3 + 2.6)
377
(79.0 + 2.5)
499
(74.6+2.4)
empty
1/17/84
(72.9+2.3)
51
(72.1+2.3)
231
(73.4 + 2.3)
377
(71.3+2.3)
499
(70.4 + 2.3)
empty
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/04/84
PPB (144 + 4.3)
NBS Concentration
PPB
(141 + 3.0)
1/04/84
(114 + 2.4)
(120 + 3.0)
1/04/84
(127 + 3.0)
(126 + 3.0)
1/17/84
(135 + 4.3)
(133 + 3.0)
1/17/84
(155 + 5.0)
(154 + 3.0)
(Continued)
A-24
-------
STABILITY STUDY FOR GROUP I CDMPOUNE6 (Continued)
CYLINDER I-C12
ACTIVITY
COMPOUND
Car ben tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day 58 58 58 51 51
PPB (147+4.4) (116 + 2.4) (134 + 3.2) .(17.0 + 0.5) (15.0 + 0.5)
NBS Concentration**
PPB (141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0)** (15.0 + 1.0)*
3rd RTI Analysis Day 240 240 240 231 231
PPB (146 + 4.4) (120 + 2.5) (131 + 3.1) (146 + 4.7) (152 + 4.9)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126+3.0) (133 + 3.0) (154 + 3.0)
4th RTI Analysis Day 401 401 401 377 377
PPB (142+4.3) (120 + 2.5) (127+3.0) (136+4.4) (150 + 4.8)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
5th RTI Analysis Day 497 497 . 497 497 497
PPB (141+4.2) (116 + 2.4) (129 + 3.1) (136 + 4.4) (149+4.8)
NBS Concentration
PPB
(141+3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119 + 2.5) (135 + 3.3) (16.9+0.5) (14.7 + 0.5)
NBS Concentration**
PPB (141 + 3.0) (120 + 3.0) (126+3.0) (17.0 + 1.0) (15.0 + 1.0)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis unless
otherwise indicated. Several different NBS primary standards were used.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-25
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C13
ACTIVnY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(15.4)
10/25/83
(12.4)
12/13/83
(11.5)
(15.3)
10/25/83
(13.6)
12/12/83
(11.9)
(15.6)
10/25/83
(12.7)
12/12/83
(11.6)
(15.6)
11/29/83
(10.8)
12/14/83
(11.3)
(15.0)
11/29/83
(13.6)
12/14/83
(14.3)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/05/84
(15.7 + 0.5)
57
(16.2+0.5)
238
. (15.7 + 0.5)
400
(15.2 + 0.5)
501
(15.4 + 0.5)
on audit
on audit
1/05/84
(14.6 + 0.3)
57
(15.4 + 0.3)
238
(15.2+0.3)
400
(14.7 + 0.3)
501
(14.8 + 0.3)
on audit
on audit
V05/84
(17.2 + 0.4)
57
(17.2 + 0.4)
238
(15.7 + 0.4)
400
(16.0 + 0.4)
501
(15.9 + 0.4)
on audi t
on audit
1/23/84
(16.2 + 0.5)
45
(15.8+0.5)
226
(18.2+0.6)
374
(17.4 + 0.6)
507
(16.9 + 0.5)
on audit
on audit
1/23/84
(15.2 + 0.5)
45
(16.1 + 0.5)
226
(15.4 + 0.5)
374
(14.4+0.5)
507
(15.4 + 0.5)
on audit
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/05/84 1/05/84
PPL (20.4 + 0.6) (22.8 + 0.5)
NBS Concentration
PPB
1/05/84
(30.7+0.7)
1/23/84
(17.5+0.6)
1/23/84
(14.3+0.5)
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
(Continued)
A-26
-------
STABILITY STUDY K)R GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C13
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 45 45
PPB (147 + 4.4) (116 + 2.4) (134 + 3.2) (16.8 + 0.5) (15.1 + 0.8)
NBS Concentration**
PPB (141 + 3.0)** (120 + 3.0)** (126 + 3.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (20.3 + 0.6) (23.6 + 0.5) (28.3+0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 400 400 400 374 374
PPB (20.1 + 0.6) (22.7 + 0.5) (28.5 + 0.7) (18.4 + 0.6) (14.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTT Analysis Day 501 501 501 507 507
PPB (20.0+0.6) (22.8+0.5) (28.1 + 0.7) (18.2+0.6) (15.2 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119+2.5) (135 + 3.3) (16.9 + 0.5) (14.7 + 0.5)
NBS Concentration**
PPB (141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis E&y 1350 1350 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191 + 4.0)
NBS Concentration
PPB
(155 + 5.0) (134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was ?nal"zed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-27
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-C14
ACTIVITY
CDMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(19.6)
10/25/83
(16.2)
12/13/83
(15.2)
(19.4)
10/25/83
(15.9)
12/13/83
(15.2)
(19.9)
10/25/83
(15.7)
12/13/83
(14.5)
(19.8)
11/29/83
(13.8)
12/14/83
(14.5)
(15.0)
11/29/83
(14.0)
12/14/83
(14.4)
RTT ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/05/84
(19.2 + 0.6)
57
(20.0 + 0.6)
238
(19.9 + 0.6)
400
(19.3 + 0.6)
501
(19.6+0.6)
833
(24.2+0.7)
on audit
V05/84
(18.4 + 0.4)
57
(18.5 + 0.4)
238
(19.1 + 0.4)
400
(18.3 + 0.4)
501
(18.1 + 0.4)
833
(21.6 + 0.5)
on audit
1/05/84
(21.1 + 0.5)
57
(21.2 + 0.5)
238
(20.2 + 0.5)
400
(20.7+0.5)
501
(20.3 + 0.5)
833
(24.5 + 0.6)
on audit
1/23/84
(20.8 + 0.7)
45
(20.2 + 0.6)
226
(22.0 + 0.7)
374
(20.6 + 0.7)
507
(21.2 + 0.7)
810
(21.7+0.7)
on audit
V23/84
(15.5 + 0.5)
45
(15.6 + 0.5)
226
(17.0 + 0.5)
374
(15.0 + 0.5)
507
(16.1 + 0.5)
810
(16.7 + 0.5)
on audit
RTI QUALITY CDNTRDL**
1st RTI Analysis Date 1/05/84 1/05/84
PPB (20.4 + 0.6) (22. 8 + 0.5)
NBS Concentration
PPB
1/05/84
(30.7+0.7)
1/23/84
(17.5 + 0..6)
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0)
1/23/84
(14.3 + 0.5)
(15.0 + 1.0)
(Continued)
A-28
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Contiiued)
CYLINDER I-C14
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 45 45
PPB (147 + 4.4) (116 + 2.4) (134 + 3.2) (16.8 + 0.5) (15.1 + 0.8)
NBS Concentration**
PPB (141 + 3.0)** (120 + 3.0)** (126 + 3.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (20.3 + 0.6) (23.6+0.5) (28.3 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 400 400 400 374 374
PPB (20.1 + 0.6) (22.7 + 0.5) (28.5 + 0.7) (18.4 + 0.6) (14.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 501 501 501 507 507
PPB (20.0 + 0.6) (22.8 + 0.5) (28.1+0.7) (18.2+0.6) (15.2 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119+2.5) (135 + 3.3) (16.9+0.5) (14.7 + 0.5)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1350 D50 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191 + 4.0)
NBS Concentration
PPB (155 + 5.0) (134 + 5.0) (146 + 3.0) (192 + 3.0) (190 + 3.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control m each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-29
-------
STABILITY STUDY FDR GROUP I COMPOUNDS***
CYLINDER I-C15
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(18.1)
10/25/83
(14.0)
12/13/83
(12.9)
(17.9)
10/25/83
(14.3)
12/13/83
(13.0)
(18.3)
10/25/83
(13.8)
12/13/83
(12.6)
(18.3)
11/29/83
(11.9)
12/14/83
(12.7)
(15.0)
11/29/83
(13.8)
12/14/83
(14.2)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
1/05/84
(17.2 + 0.5)
57
(17.2+0.5)
238
(17.6+0.5)
400
(17.0 + 0.5)
501
(15.9 + 0.5)
on audit
on audit
1/05/84
(16.2 + 0.3)
57
(16.7 + 0.4)
238
(17.0+0.4)
400
(16.4 + 0.3)
501
(16.4 + 0.3)
on audit
on audit
V05/84
(19.3 + 0.5)
57
(19.4 + 0.5)
238
(17.9 + 0.4)
400
(18.3 + 0.4)
501
(17.4 + 0.4)
on audi t
on audit
V23/84
(18.1 + 0.6)
45
(17.5 + 0.6)
226
(19.8 + 0.6)
374
(18.8 + 0.6)
507
(18.6 + 0.6)
on audi t
on audit
V23/84
(14.9 + 0.5)
45
(14.8 + 0.5)
226
(15.6 + 0.5)
374
(14.9 + 0.5)
507
(15.4 + 0.5)
on audi t
on audi t
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/05/84
(20.4 + 0.6)
(21.0 + 1.0)
1/05/84
(22.8 + 0.5)
(23.0 + 1.0)
1/05/84
(30.7+0.7)
(29.0 + 1.0)
1/23/84
(17.5 + 0.6)
(17.0 + 1.0)
1/23/84
(14.3 + 0.5)
(15.0 + 1.0)
(Continued)
A-30
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-C15
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTT Analysis Day 57 57 57 45 45
PPB (147 + 4.4) (116+2.4) (134 + 3.2) (16.8+0.5) (15.1 + 0.8)
NBS Concentration**
PPB (141 + 3.0)** (120 + 3.0)** (126 + 3.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (20.3+0.6) (23.6 + 0.5) (28.3+0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 400 400 400 374 374
PPB (20.1 + 0.6) (22.7 + 0.5) (28.5 + 0.7) (18.4 + 0.6) (14.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 501 501 501 507 507
PPB (20.0 + 0.6) (22.8+0.5) (28.1 + 0.7) (18.2+0.6) (15.2+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119+2.5) (135 + 3.3) (16.9 + 0.5) (14.7 + 0.5)
NBS Concentration , .
'PPB (141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1350 1350 1350 1350 1350
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191+4.0)
NBS Concentration
PPB (155 + 5.0) (134 + 5.0) (146 + 3.0) (192 + 3.0) (190 + 3.0)
*Nunber of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS prinary standard was used for calibration for 7th RTI Analysis. Peimeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-31
-------
STABILITY STUDY TOR GROUP I COMPOUNDS***
CYLINDER I-C16
AcrivrrY
COMPOUND
Carbon tetra-
chloride
Chlorofonn
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(20.9)
11/11/83
(15.6)
12/13/83
(14.2)
(20.7)
11/1V83
(11.1)
12/13/83
(8.10)
(21.2)
11/11/83
(12.5)
12/13/83
(11.7)
(21.2)
11/29/83
(9.10)
12/14/83
(9.40)
(15.0)
11/29/83
(13.9)
12/14/83
(13.8)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
V05/84
(17.9 + 0.5)
57
(17.4 + 0.5)
238
(16.2 + 0.5)
400
(14.9 + 0.4)
501
(14.5 + 0.4)
833
(15.4 + 0.5)
on audit
1/05/84
(9.0 + 0.2)
57
(7.9 + 0.2)
238
(6.0 + 0.1)
400
(4.8 + 0.1)
501
(3.7 + 0.1)
833
(3.2 + 0.1)
on audit
1/05/84
(16.5 + 0.4)
57
(15.4 + 0.4)
238
(14.6 + 0.4)
400
(14.6 + 0.4)
501
(14.2+0.3)
833
(16.1 + 0.4)
on audit
V23/84
(13.8 + 0.4)
45
(13.2 + 0.4)
226
(14.6+0.5)
374
(13.6 + 0.4)
507
(12.2 + 0.4)
810
(12.7 + 0.4)
on audit
1/23/84
(14.9+0.5)
45
(14.8 + 0.5)
226
(15.8+0.5)
374
(12.3 + 0.4)
507
(11.6 + 0.4)
810
(13.2+0.4)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/05/84
PPB (20.4+0.6)
MBS Concentration
PPB
(21.0 + 1.0)
1/05/84
(22.8 + 0.5)
(23.0 + 1.0)
1/05/84
(30.7+0.7)
(29.0+ 1.0)
1/23/84
(17.5 + 0.6)
(17.0 + 1.0)
1/23/84
(14.3 + 0.5)
(15.0 + 1.0)
(Continued)
A-32
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Contimed)
CYLINDER I-C16
ACTIVnY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 45 45
PPB (147 + 4.4) (116+2.4) (134 + 3.2) (16.8 + 0.5) (15.1 + 0.8)
NBS Concentration**
PPB (141 + 3.0)** (120 + 3.0)** (126 + 3.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (20.3 + 0.6) (23.6 + 0.5) (28.3 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 400 400 400 374 374
PPB (20.1 + 0.6) (22.7 + 0.5) (28.5+0.7) (18.4 + 0.6) (14.3 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 501 501 501 507 507
PPB (20.0 + 0.6) (22.8 + 0.5) (28.1 + 0.7) (18.2+0.6) (15.2+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119 + 2.5) (135 + 3.3) (16.9+0.5) (14.7 + 0.5)
NBS Concentration
PPB
(141 + 3.0)- (120 + 3.0) (126 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1350 1350 1350 1350 D50
PPB (154 + 3.0) (131 + 2.4) (146 + 3.0) (191 + 6.1) (191+4.0)
NBS Concentration
PPB
(155 + 5.0) (134 + 5.0) (146 + 3.0) (192+3.0) (190 + 3.0)
*Ninrber of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS prinary staniard was used for calibration for 7th RTI Analysis. Peimeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was perfonned by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were perfonned by direct injection.
A-33
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A1
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(9.70)
11/16/83
(8.30)
12/16/83
(7.30)
(40.5)
IV 16/83
(42.9)
12/16/83
(41.6)
(9.60)
1V16/83
(10.2)
12/16/83
(7.3.0)
(19.3)
12/06/83
(16.0)
12/15/83
(16.8)
(20.0)
12/06/83
(18.8)
12/15/83
(19.2)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/06/84
(9.8 + 0.3)
59
(9.9 + 0.3)
on audit
404
(9.9 + 0.3)
497
(9.5 + 0.3)
on audit
on audit
V06/84
(40.4 + 0.8)
59
(42.0 + 0.9)
on audit
404
(37.6 + 0.8)
497
(37.3+0.8)
on audit
on audit
1/06/84
(10.8 + 0.3)
59
(9.6 + 0.2)
on audit
404
(9.1 + 0.2)
497
(10.0+0.2)
on audit
on audit
1/23/84
(19.6 + 0.6)
49
(20.0 + 0.6)
on audit
375
(19.4 + 0.6)
508
(19.7 + 0.6)
on audit
on audit
V23/84
(20.3 + 0.6)
49
(19.8 + 0.6)
on audit
375
(20.2 + 0.6)
508
(20.6+0.7)
on audi t
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/06/84
PPB (20.6+0.6)
NBS Concen. PPB
V06/84
(22.8 + 0.5)
(21.0 + 1.0) (23.0 + 1.0)
1/06/84
(31.7 + 0.8)
(29.0 + 2.0)
1/23/84
(17.5 + 0.6)
(17.0 + 1.0)
1/23/84
(14.3+0.5)
(15.0 + 1.0)
(Continued)
A-34
-------
STABILITY STUDY FOR (SOUP I COMPOUNDS*** (Contimed)
CYLINDER I-A1
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chlorofoim
Perchloro-
ettylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 59 59 59 49 49
PPB (20.3 + 0.6) (8.90 + 0.2) (23.6 + 0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concen.** PPB (19.0 + 1.0)** (9.00 + 1.0)** (22.0 + 1.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (21.1 + 0.6) (24.3 + 0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concen.
PPB
(21.0 + 1.0) (23.0+ 1).0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTT Analysis Day 404 404 404 375 375
PPB (20.6 + 0.6) (23.2 + 0.5) (28.7 + 0.7) (18.1 + 0.6) (14.1 + 0.5)
NBS Concen.
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 497 497 497 508 508
PPB (19.9 + 0.6) (22.9 + 0.5) (28.8 + 0.7) (18.5 + 0.6) (15.2+0.5)
NBS Concen.
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0+1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5 + 0.5) (32.7 + 0.8) (16.9 + 0.5) (14.7 + 0.5)
NBS Concen.
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 1337 1337 1337 1337
PPB (18.7+0.9) (9.80 + 0.4) (23.0 + 0.6) (17.3+0.5) (16.6+0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for ali previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-35
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A2
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
' Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(9.50)
1V17/83
(7.70)
12/16/83
(7.10)
(39.6)
IV 17/83
(42.1)
12/16/83
(41.2)
(9.40)
IV 17/83
(9.20)
12/16/83
(7.70)
(18.9)
12/06/83
(15.8)
12/15/83
(19.6)
(20.0)
12/06/83
(18.3)
12/15/83
(19.2)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/06/84
(9.30 + 0.3)
59
(9.30 + 0.3)
238
(9.50 + 0.3)
404
(9.60 + 0.3)
on audit
833
(10.5 + 0.3)
1337
(9.45 + 0.3)
V06/84
(40.0 + 0.8)
59
(38.7 + 0.8)
238
(40.6 + 0.9)
404
(37.1 + 0.8)
on audit
833
(40.5 + 0.9)
1337
(40.6+0.9)
V06/84
(9.40 + 0.2)
59
(10.3+0.2)
238
(9.50 + 0.2)
404
(9.10 + 0.2)
on audit
833
(11.2 + 0.3)
1337
(10.1 + 0.3)
1/23/84
(19.6 + 0.6)
49
(20.0 + 0.6)
226
(19.4 + 0.6)
375
(19.4 + 0.6)
on audit
810
(19.7 + 0.6)
1337
(19.2 + 0.6)
V23/84
(20.2 + 0.6)
49
(19.0 + 0.6)
226
(20.6+0.7)
375
(20.4 + 0.7)
on audit
810
(19.4 + 0.6)
1337
(20.1 + 0.6)
RTI QUALITY CONTROL**
1st RTI Analysis^ Date
PPB
NBS Concen. PPB
1/06/84
(20.6 + 0.6)
(21.0 + 1.0)
1/06/84
(22.8 + 0.5)
(23.0 + 1.0)
1/06/84
(31.7 + 0.8)
(29.0 + 2.0)
V23/84
(17.5 + 0.6)
(17.0 + 1.0)
1/23/84
(14.3 + 0.5)
(15.0 + 1.0)
(Continued)
A-36
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A2
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concen.** PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5th RTI Analysis Day
PPB
NBS Concen. PPB
6th RTI Analysis Day
PPB
NBS Concen. PPB
7th RTI Analysis Day
PPB
NBS Concen. PPB
59
(20.3 + 0.6)
59
(8.90 + 0.2)
59
(23.6 + 0.6)
49
(18.6 + 0.6)
(19.0 + 1.0)** (9.00+1.0)** (22.0 + 1.0)** (17.0 + 1.0)
238 238 238 226
(21.1 + 0.6) (24.3+0.5) (29.5 + 0.7) (19.0 + 0.6)
(21.0 + 1.0)
404
(20.6 + 0.6)
(21.0 + 1.0)
497
(19.9 + 0.6)
(21.0 + 1.0)
833
(22.4 + 0.7)
(21.0 + 1.0)
1337
(18.7 + 0.9)
(19.3 + 1.0)
(23.0 + 1.0)
404
(23.2 + 0.5)
(23.0 + 1.0)
497
(22.9 + 0.5)
(23.0 + 1.0)
833
(25.5 + 0.5)
(23.0 + 1.0)
1337
(9.80 + 0.4)
(9.60 + 0.2)
(29.0 + 2.0)
404
(28.7+0.7)
(29.0 + 2.0)
497
(28.8 + 0.7)
(29.0 + 2.0)
833
(32.7 + 0.8)
(29.0 + 2.0)
1337
(23.0 + 0.6)
(22.8 + 0.2)
(17.0 + 1.0)
375
(18.1 + 0.6)
(17.0 + 1.0)
508
(18.5 + 0.6)
(17.0 + 1.0)
810
(16.9 + 0.5)
(17.0 + 1.0)
1337
(17.3 + 0.5)
(16.8+0.5)
49
(15.0 + 0.5)
(15.0 + 1.0)
226
(15.3 + 0.5)
(15.0 + 1.0)
375
(14.1 + 0.5)
(15.0 + 1.0)
508
(15.2 + 0.5)
(15.0 + 1.0)
810
(14.7 + 0.5)
(15.0 + 1.0)
1337
(16.6 + 0.6)
(16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Penneation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-37
-------
STABILITY STUDY TOR GROUP I COMPOUNDS***
CYLINDER I-A3
ACTIVITY
COMPOUND
Carbon tetxa-
chloride
Chloroform
Perchloro-
e thylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(11.4)
12/09/83
(9.50)
12/16/83
(8.90)
(47.3)
12/09/83
(47.2)
12/16/83
(48.7)
(11.2)
12/09/83
(9.40)
12/16/83
(8.60)
(22.5)
12/07/83
(18.7)
12/15/83
(20.3)
(20.0)
12/07/83
(15.8)
12/15/83
(19.4)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/06/84
(11.5+0.3)
59
(11.0 + 0.3)
on audit
404
(11.4 + 0.3)
497
(11.0 + 0.3)
833
(12.3 + 0.4)
on audit
1/06/84
(46.6 + 1.0)
59
(47.4 + 1.0)
on audit
404
(43.9 + 0.9)
497
(43.6 + 0.9)
833
(48.3 + 1.0)
on audit
V06/84
(12.0 + 0.3)
59
(11.3+0.3)
on audit
404
(10.3 + 0.2)
497
(11.6 + 0.3)
833
(13.3+0.3)
on audit
1/23/84
(23.2 + 0.7)
49
(25.2 + 0.8)
on audit
375
(23.0 + 0.7)
on audit
810
(24.6 + 0.8)
on audit
V23/84
(20.3 + 0.6)
49
(19.8 + 0.6)
on audit
375
(20.5+0.7)
on audit
810
(21.1 + 0.7)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/06/84 _
PPB (20.6 + 0.6)
NBS Concen. PPB
(21.0 + 1.0)
1/06/84 1/06/84
(22.8 + 0.5) (31.7 + 0.8)
(23.0 + 1.0)
(29.0 + 2.0)
1/23/84
(IV. 5 + 0.6)
(17.0 + 1.0)
V23/84
(14.3+0.5)
(15.0 + 1.0)
(Continued)
A-38
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Contimed)
CYLINDER I-A3
ACTIVITY
(DMFOUND
Carbon tetra-
chlorlde
Chlorofoim
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day 59 59 59 49 49
PPB (20.3 + 0.6) (8.90 + 0.2) (23.6+0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concen.** PPB (19.0 + 1.0)** (9.00 + 1.0)** (22.0 + 1.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (21.1 + 0.6) (24.3 + 0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concen.
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 404 404 404 375 375
PPB (20.6 + 0.6) (23.2+0.5) (28.7+0.7) (18.1 + 0.6) (14.1 + 0.5)
NBS Concen. PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 497 497 497 508 508
PPB (19.9 + 0.6) (22.9 + 0.5) (28.8 + 0.7) (18.5 + 0.6) (15.2+0.5)
NBS Concen. PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5+0.5) (32.7+0.8) (16.9 + 0.5) (14.7+0.5)
NBS Concen. PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day . 1337 1337 1337 1337 1337
PPB (18.7+0.9) (9.80 + 0.4) (23.0 + 0.6) (17.3+0.5) (16.6 + 0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS prinary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-39
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A4
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(10.9)
12/09/83
(9.00)
12/16/83
(8.60)
(45.3)
12/09/83
(46.5)
12/16/83
(51.1)
(10.8)
12/09/83
(9.60)
12/16/83
(10.1)
(21.5)
12/07/83
(18.6)
12/15/83
(19.5)
(20.0)
12/07/83
(18.3)
12/15/83
(19.2)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/09/84
(11.0 + 0.3)
59
on audit
238
(10.8 + 0.3)
404
(11.4 + 0.3)
on audit
on audit
1337
(10.8+0.3)
1/09/84
(45.0 + 0.9)
59
on audit
238
(47.1 + 1.0)
404
(43.9+0.9)
on audit
on audit
1337
(43.3 +0.9)
1/09/84
(12.0 + 0.3)
59
on audit
238
(10.3 + 0.2)
404
(10.3+0.2)
on audit
on audit
1337
(10.6 + 0.2)
1/23/84
(22.3 + 0.7)
59
on audit
226
(23.2 + 0.7)
375
(19.9 + 0.6)
508
(22.3 + 0.7)
on audi t
1337
(21.8+0.7)
1/23/84
(20.5 + 0.7)
59
on audit
226
(20.1+0.6)
375
(22.1 + 0.7)
508
(19.8 + 0.6)
on audit
1337
(19.7 + 0.6)
RTI QUALITY CONTROL**
1st RTI Analysis Date 1/06/84
PPB (20.6 + 0.6)
MBS Concentration
PPB
(21.0 + 1.0)
V06/84
(22.8 + 0.5)
(23.0 + 1.0)
— 1/06/84
(31.7+0.8)
(29.0 + 2.0)
1/23/84
(17.5 + 0.6)
(17.0 + 1.0)
V23/84
(14.3+0.5)
(15.0+ 1.0)
(Continued)
A-40
-------
STABILITY STUDY TOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A4
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day 59 59 59 49 49
PPB (20.3 + 0.6) (8.90 + 0.2) (23.6 + 0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concentration**
PPB (19.0 + 1.0)** (9.00 + 1.0)** (22.0 + 1.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 226 226
PPB (21.1 + 0.6) (24.3 + 0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 404 404 404 375 375
PPB (20.6 + 0.6) (23.2 + 0.5) (28.7 + 0.7) (18.1 + 0.6) (14.1 + 0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 497 497 497 508 508
PPB (19.9 + 0.6) (22.9+0.5) (28.8+0.7) (18.5 + 0.6) (15.2 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5 + 0.5) (32.7+0.8) (16.9 + 0.5) (14.7 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.a) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 1337 1337 1337 1337
PPB (18.3+0.9) (9.54 + 0.2) (22.7 + 0.6) (16.6 + 0.5) (15.8 + 0.5)
NBS Concentration
PPB
(19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Penneation tubes were used for
calibration for all previous analyes.
****Seventh analysis was perforated by automated cryogenic preconcentration with ciyofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-41
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A5
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(48.4)
12/09/83
(46.6)
12/20/83
(47.8)
(10.6)
12/09/83
(9.70)
12/20/83
(9.00)
(10.6)
12/09/83
(9.50)
12/20/83
(8.70)
(48.4)
12/07/83
(45.1)
12/15/83
(46.0)
(50.0)
12/07/83
(47.5)
12/15/83
(49.8)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
1/09/84
(47.7 + 1.4)
57
(51.1 + 1.5)
235
(50.9 + 1.5)
402
(47.2 + 1.4)
494
(46.0 + 1.4)
on audit
7th RTI Analysis Day* on audit
PPB
1/09/84
(10.5 + 0.2)
57
(9.3 + 0.2)
235
(10.5 + 0.2)
402
(10.2 + 0.2)
494
(10.3 + 0.2)
on audit
on audit
1/09/84
(11.2 + 0.3)
57
(9.0 + 0.2)
235
(10.5+0.3)
402
(10.4 + 0.2)
494
(10.7 + 0.3)
on audit
on audit
1/19/84
(51.6 + 1.7)
53
(52.0 + 1.7)
229
(54.0 + 1.7)
375
(53.8 + 1.7)
497
(49.0 + 1.6)
on audit
on audi t
1/19/84
(53.0 + 1.7)
53
(50.0 + 1.6)
229
(52.8 + 1.7)
375
(50.8 + 1.6)
497
(50.1 + 1.6)
on audit
on audit
RTI QUALITY ODNTRQL**
.1st RTI Analysis Date 1/09/84 1/09/84 1/09/84 1/19/84 1/19/84
PPB (18.9 + 0.6) (9.40 + 0.2) (24.4 + 0.6) (20.2 + 0.6) (16.3 + 0.5)
NBS Concentration
PPB
(19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
(Continued)
A-42
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A5
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 53 53
PPB (21.5+0.6) (10.1 + 0.2) (26.1 + 0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 235 235 235 229 229
PPB (21.1 + 0.6) (24.3 + 0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration**
PPB (21.0 + 1.0)** (23.0 + 1.0)** (29.0 + 2.0)** (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 402 402 402 375 375
PPB (18.9 + 0.6) (9.20+0.2) (21.9 + 0.5) (17.8 + 0.6) (14.8+0.5)
NBS Concentration
PPB
(19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 494 494 494 497 497
PPB (19.9 + 0.6) (22.9 + 0.5) (28.8 + 0.7) (18.5 + 0.6) (29.4 + 0.9)
NBS Concentration**
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0+2.0) (18.0 + 1.0) (31.0 + 2.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4+0.7) (25.5 + 0.5) (32.7 + 0.8) (16.9 + 0.5) (14.7+0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 D37 D37 1337 1337
PPB (18.7+0.9) (9.80+0.4) (23.0 + 0.6) (17.3 + 0.5) (16.6 + 0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS prims .y standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-43
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A6
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chlorofonn
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(38.8)
12/09/83
(38.0)
12/20/83
(37.5)
(8.50)
12/09/83
(6.90)
12/20/83
(6.70)
(8.50)
12/09/83
(8.80)
12/20/83
(8.10)
(38.8)
12/07/83
(35.0)
12/15/83
(34.5)
(50.0)
12/07/83
(47.1)
12/15/83
(49.3)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTT Analysis Day*
1/09/84
(38.6 + 1.2)
57
(41.0 + 1.2)
235
(40.4 + 1.2)
402
(37.7 + 1.1)
494
(37.2 + 1.1)
on audit
on audit
V09/84
(8.20 + 0.2)
57
(7.30+0.2)
235
(8.20 + 0.2)
402
(8.30+0.2)
494
(8.10 + 0.2)
on audit
on audit
V09/84
(8.50 + 0.2)
57
(7.90 + 0.2)
235
(8.20 + 0.2)
402
(8.40+0.2)
494
(9.00 + 0.2)
on audit
on audit
V 19/84
(41.9 + 1.3)
53
(41.1 + 1.3)
229
(43.1 + 1.4)
375
(40.7 + 1.3)
497
(39.1 + 1.3)
on audit
on audit
1/19/84
(53.0 + 1.7)
53
(49.8 + 1.6)
229
(51.9 + 1.7)
375
(50.8 + 1.6)
497
(50.3 + 1.6)
on audit
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
V09/84
(18.9+0,6)
(19.0 + 1.0)
1/09/84
(9.40 + 0.2)
(9.00 + 1.0)
1/09/84
(24.4 + 0.6)
(22.0 + 1.0)
V 19/84
(20.2+0.6)
(17.0 + 1.0)
V 19/84
(16.3 + 0.5)
(15.0 + 1.0)
(Continued)
A-44
-------
STABILITY STUDY FOR (SOUP I COMPOUNDS*** (Continued)
CYLINDER I-A6
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
. Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 53 53
PPB (21.5 + 0.6) (10.1 + 0.2) (26.1 + 0.6) (18.6+0.6) (15.0 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 235 235 235 229 229
PPB (21.1 + 0.6) (24.3 + 0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration**
PPB (21.0 + 1.0)** (23.0 + 1.0)** (29.0 + 2.0)** (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 402 402 402 375 375
PPB (18.9 + 0.6) (9.20 + 0.2) (21.9 + 0.5) (17.8 + 0.6) (14.8 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 494 494 494 497 497
PPB (19.9+0.6) (22.9 + 0.5) (28.8+0.7) (18.5 + 0.6) (29.4 + 0.9)
NBS Concentration**
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (18.0 + 1.0) (31.0 + 2.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5+0.5) (32.7+0.8) (16.9 + 0.5) (14.7 + 0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 1337 1337 1337 1337
PPB (18.7+0.9) (9.80+0.4) (23.0 + 0.6) (17.3+0.5) (16.6 + 0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8+0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calil ration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FTD. Previous analysis were performed by direct injection.
A-45
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A7
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(51.1)
12/09/83
(49.2)
12/20/83
(49.9)
(11.2)
12/09/83
(10.4)
12/20/83
(9.50)
(11.2)
12/09/83
(10.4)
12/20/83
(9.30)
(51.1)
12/07/83
(47.1)
12/15/83
(48.5)
(50.0)
12/07/83
(48.6)
12/15/83
(48.5)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/09/84
(49.2 + 1.5)
57
(54.0 + 1.6)
235
(53.3 + 1.6)
402
(49.6 + 1.5)
494
(47.8 + 1.5)
833
(54.5 + 1.6)
1337
(56.0 + 1.6)
1/09/84
(11.1+0.2)
57
(9.7+0.2)
235
(11.0 + 0.2)
402
(10.7 + 0.2)
494
(10.8 + 0.2)
833
(12.2+0.3)
D37
(11.0 + 0.3)
1/09/84
(11.8 + 0.3)
57
(9.7 + 0.2)
235
(11.2 + 0.3)
402
(11.1+0.3)
494
(11.7 + 0.3)
833
(13.6 + 0.3)
1337
(11.9 + 0.3)
1/19/84
(54.1 + 1.7)
53
(54.8 + 1.8)
229
(56.2 + 1.8)
375
(53.8 + 1.7)
497
(52.3 + 1.7)
810
(49.0 + 1.6)
B37
(51.3 + 1.7)
V 19/84
(53.4 + 1.7)
53
(49.7 + 1.6)
229
(51.9 + 1.7)
375
(50.8 + 1.6)
497
(50.4 + 1.6)
810
(45.8 + 1.5)
1337
(54.4 + 1.8)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/09/84
(18.9+0.6)
(19.0 + 1.0)
1/09/84
(9.4+0.2)
1/09/84
(24.4 + 0.6}
(9.00 + 1.0) (22.0 + 1.0)
1/19/84
(20.2+0.6)
(17.0 + 1.0)
1/19/84
(16.3 + 0.5)
(15.0+1.0)
(Continued)
A-46
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A7
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 53 53
PPB (21.5 + 0.6) (10.1+0.2) (26.1 + 0.6) (18.6+0.6) (15.0 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 235 235 235 229 229
PPB (21.1 + 0.6) (24.3+0.5) (29.5 + 0.7) (19.0 + 0.6) (15.3 + 0.5)
NBS Concentration**
PPB (21.0 + 1.0)** (23.0 + 1.0)** (29.0 + 2.0)** (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 402 402 402 375 375
PPB (18.9 + 0.6) (9.20 + 0.2) (21.9 + 0.5) (17.8 + 0.6) (14.8 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 494 494 494 497 497
PPB (19.9 + 0.6) (22.9 + 0.5) (28.8 + 0.7) (18.5+0.6) (29.4 + 0.9)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (lfl.0 + 1.0) (31.0 + 2.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4+0.7) (25.5+0.5) (32.7+0.8) (16.9+0.5) (14.7+0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 1337 1337 1337 1337
PPB (18.3+0.9) (9.54 + 0.2) (22.7+0.6) (16.6 + 0.5) (15.8 + 0.5)
NBS Concentration
PPB (19.3 + 1.0) (9.60+0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-47
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A8
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(55.1)
12/09/83
(52.6)
12/20/83
(53.2)
(12.1)
12/09/83
(7.90)
12/20/83
(6.30)
(12.1)
12/09/83
(10.5)
12/20/83
(9.50)
(55.1)
12/07/83
(42.7)
12/15/83
(43.9)
—
12/07/83
(48.4)
12/15/83
(48.3)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/09/84
(53.5 + 2.7)
57
(59.0 + 1.8)
on audit
402
(51.3 + 1.5)
494
(50.1 + 1.5)
833
(56.9 + 1.7)
on audit
1/09/84
(7.40+0.2)
57
(6.00 + 0.1)
on audit
402
(4.30 + 0.1)
494
(4.10+0.1)
833
(3.90 + 0.1)
on audit
1/09/84
(11.3+0.3)
57
(10.5+0.3)
on audit
402
(10.3 + 0.2)
494
(11.4 + 0.3)
833
(13.3 + 0.3)
on audit
1/19/84
(48.3 + 1.5)
53
(48.1 + 1.5)
on audit
375
(46.3 + 1.5)
497
(44.2 + 1.4)
810
(43.4 + 1.4)
on. audit
1/19/84
(51.7 + 1.7)
53
(49.2 + 1.6)
on audit
375
(49.0 + 1.6)
497
(48.5 + 1.6)
810
(45.8 + 1.5)
on audit
RTI QUALITY CONTROL**
1st RTT Analysis Date
PPB
NBS Concentration
PPB
1/09/84
(18.9+0.6)
(190 + 1.0)
1/09/84
(9.40+0.2)
(9.00 + 1.0)
V09/84
(24.4 + 0.6)
(22.0 + 1.0)
1/19/84
(20.2 +0.6)
(17.0 + 1.0)
1/19/84
(16.3 + r>.5)
(15.0 + 1.0)
(Continued)
A-48
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A8
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 53 53
PPB (21.5 + 0.6) (10.1+0.2) (26.1+0.6) (18.6+0.6) (15.0 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 235 235 235 229 229
PPB (21.1 + 0.6) (24.3+0.5) (29.5+v0.7) (19.0+0.6) (15.3 + 0.5)
NBS Concentration**
PPB (21.0 + 1.0)** (23.0 + 1.0)** (29.0 + 2.0)** (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 402 402 402 375 375
PPB (18.9 + 0.6) (9.20 + 0.2) (21.9 + 0.5) (17.8 + 0.6) (14.8 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 494 494 494 497 497
PPB (19.9+0.6) (22.9 + 0.5) (28.8 + 0.7) (18.5 + 0.6) (29.4 + 0.9)
NBS Concentration**
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (18.0 + 1.0) (31.0+2.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5 + 0.5) (32.7 + 0.8) (16.9 + 0.5) (14.7+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day L337 1337 L337 D37 1337
PPB (18.7 + 0.9) (9.80 + 0.4) (23.0 + 0.6) (17.3 + 0.5) (16.6+0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60+0.2) (22.8+0.2) (16.8+0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-49
-------
STABILITY STUDY FOR GROUP I OOMPOUNDS***
CYLINDER I-A9
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(13.6)
12/08/83
(11.1)
12/19/83
(11.8)
(13.4)
12/08/83
(11.3)
12/19/83
(11.4)
(68.4)
12/08/83
(63.5)
12/19/83
(63.8)
(48.3)
12/09/83
(41.8)
12/16/83
(43.9)
(30.0)
12/09/83
(29.0)
12/16/83
(28.5)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/05/84
(13.0 + 2.7)
60
(11.8 + 0.4)
238
(12.7+0.4)
407
(12.5+0.4)
496
(12.0 + 0.4)
833
(13.7 + 0.4)
on audit
V05/84
(11.9+0.2)
60
(10.5+0.2)
238
(12.3+0.3)
407
(11.8 + 0.2)
496
(12.0 + 0.3)
833
(13.3+0.3)
on audit
1/05/84
(69.6 + 1.7)
60
(67.6 + 1.6)
238
(62.2 + 1.5)
407
(63.7 + 1.5)
496
(64.3 + 1.5)
833
(69.9 + 1.7)
on audit
V20/84
(46.8 + 1.5)
52
(46.4 + 1.5)
228
(48.0 + 1.5)
374
(45.8 + 1.5)
496
(44.7 + 1.4)
810
(46.6 + 1.5)
on audit
1/20/84
(31.1 + 1.0)
52
(29.3+0.9)
228
(31.3 + 1.0)
374
(29.9 + 1.0)
496
(29.0 + 0.9)
810
(31.3 + 1.0)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
V05/84
(20.4 + 0.6)
(21.0 + 1.0)
1/05/84
(22.8+0.5)
(23.0 + 1.0)
1/05/84
(30.7 + 0.7)
(29.0 + 2.0)
V20/84
(18.4+0.6)
(17.0 + 1.0)
1/20/84
(14.8 + 0.5)
(15.0 + 1.0)
(Continued)
A-50
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A9
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 60 60 60 52 52
PPB (20.3+0.6) (8.90+0.2) (23.6+0.6) (18.6+0.6) (15.0+0.5)
NBS Concentration**
PPB (19.0 + 1.0)** (9.00 + 1.0)** (22.0 + 1.0)** (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 228 228
PPB (20.3+0.6) (23.6 + 0.5) (28.3 + 0.7) (19.0+0.6) (14.8 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 407 407 407 374 374
PPB (20.7 + 0.6) (23.3 + 0.5) (29.0 + 0.7) (17.8 + 0.6) (14.8 + 0.5)
NBS Concentration
PPB
(19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 496 496 496 504 504
PPB (20.3+0.6) (23.4 + 0.5) (30.6+0.7) (18.6 + 0.6) (14.7 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5+0.5) (32.7 + 0.8) (18.9 + 0.6) (15.2+0.5)
NBS Concentration (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
PPB ~ ~ ~ ~ ~~
7th RTI Analysis Day 1337 D37 1337 1337 1337
PPB (18.7+0.9) (9.80+0.4) (23.0+0.6) (17.3+0.5) (16.6 + 0.6)
NBS Concentration
PPB
(19.3 + 1.0) (9.60+0.2) (22.8+0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st KTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-51
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A10
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(13.3)
12/08/83
(11.1)
12/19/83
(11.8)
(13.1)
12/08/83
(11.8)
12/19/83
(11.1)
(67.0)
12/08/83
(75.1)
12/19/83
(64.1)
(47.3)
12/09/83
(41.0)
12/16/83
(43.3)
(30.0)
12/09/83
(28.9)
12/16/83
(28.3)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th KTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
V05/84
(12.6 + 2.7)
60
(11.6 + 0.3)
238
(12.5 + 0.4)
407
(12.5 + 0.4)
496
(12.3+0.4)
833
(14.4 + 0.4)
on audit
1/05/84
(11.6+0.2)
60
(10.2 + 0.2)
238
(12.2+0.3)
407
(11.7+0.2)
496
(12.2+0.3)
833
(14.4 + 0.3)
on audit
1/05/84
(68.6 + 1.6)
60
(67.7 + 1.6)
238
(62.2 + 1.5)
407
(62.1 + 1.5)
496
(65.1 + 1.6)
833
(70.1 + 1.7)
en audit
1/20/84
(46.1 + 1.5)
52
(45.2 + 1.4)
228
(47.3 + 1.5)
374
(45.4 + 1.5)
504
(43.9 + 1.4)
810
(45.7 + 1.5)
on audit
V 20/84
(31.6 + 1.0)
52
(29.8 + 1.0)
228
(32.0 + 1.0)
374
(30.4 + 1.0)
504
(29.9+1.0)
810
(31.3 + 1.0)
en audit
RTT QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
V05/84
(20.4 + 0.6)
(21.0 + 1.0)
1/05/84
(22.8 + 0.5)
(23.0 + 1.0)
1/05/84
(30.7 + 0.7)
(29.0 + 2.00
1/20/84
(18.4 + 0.6)
(17.0 + 1.0)
1/20/84
(14.8+0.5)
(15.0 + 1.0)
(Continued)
A-52
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A10
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTT QUALITY CONTROL**
2nd RTI Analysis Day 60 60 60 52 52
PPB (20.3+0.6) (8.90 + 0.2) (23.6 + 0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concentration
PPB
(19.0 + 1.0) (9.00+1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 228 228
PPB (20.3+0.6) (23.6+0.5) (28.3 + 0.7) (19.0+0.6) (14.8+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 407 407 407 374 374
PPB (20.7+0.6) (23.6 + 0.5) (28.3 + 0.7) (19.0 + 0.6) (14.8+0.5)
NBS Concentration**
PPB (19.0 + 1.0)** (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 496 496 496 504 504
PPB (20.3 + 0.6) (23.4 + 0.5) (30.6 + 0.7) (18.6+0.6) (14.7 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5 + 0.5) (32.7 + 0.8) (18.9+0.6) (15.2+0.5)
NBS Concentration
PPB (21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day D37 D37 D37 D37 D37
PPB (18.7+0.9) (9.80+0.4) (23.0+0.6) (17.3+0.5) (16.6 + 0.6)
NBS Concentration
PPB
(19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was .-Jial/zed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for" 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-53
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A11
. ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(11.7)
12/08/83
(5.70)
12/19/83
(6.70)
(11.5)
12/08/83
(7.30)
12/19/83
(6.20)
(59.0)
12/08/83
(25.9)
12/19/83
(20.6)
(41.6)
12/09/83
(22.1)
12/16/83
(23.2)
(30.0)
12/09/83
(28.5)
12/16/83
(28.6)
KTI ANALYSIS****
1st KIT Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/05/84
(7.80 + 2.7)
60
(6.60 + 0.2)
238
(7.10+0.2)
407
(7.00 + 0.2)
496
(6.40 + 0.2)
833
(8.00 + 0.2)
on audit
1/05/84
(7.80+0.2)
60
(7.40 + 0.2)
238
(8.10 + 0.2)
407
(7.80+0.2)
496
(7.90 + 0.2)
833
(9.40 + 0.2)
on audit
1/05/84
(22.8+0.5)
60
(21.9+0.5)
238
(21.1 + 0.5)
407
(21.5+0.5)
496
(21.1+0.5)
833
(24.4 + 0.6)
on audit
1/20/84
(26.2 + 0.8)
52
(26.0 + 0.8)
228
(29.9 + 1.0)
374
(29.8 + 1.0)
504
(25.9+0.8)
810
(26.5+0.7)
on audit
1/20/84
(31.4 + 1.0)
52
(29.6+0.9)
228
(32.0 + 1.0)
374
(32.0 + 1.0)
504
(30.1 + 1.0)
810
(32.1 + 1.0)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/05/84
(20.4+0.6)
(21.0 + 1.0)
1/05/84
(22.8 + 0.5)
(23.0 + 1.0)
1/05/84
(30.7 + 0.7)
(29.0 + 2.0)
1/20/84
(18.4 + 0.6)
(17.0 + 1.0)
1/20/84
(14.8 + 0.5)
(15.0 + 1.0)
(Continued)
A-54
-------
STABILITY STUDY TOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A11
QOMPOUND
ACTIVITY
Carbon tetra-
chloride
Chlorofoim
Perchloro-
ethylene
Benzene
Vinyl
Chloride
m QUALITY CONTROL**
2nd RTI Analysis Day 60 60 60 52 52
PPB (20.3+0.6) (8.90 + 0.2) (23.6 + 0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3th RTI Analysis Day 238 238 238 238 238
PPB (20.3 + 0.6) (23.6+0.5) (28.3 + 0.7) (19.0 + 0.6) (14.8+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 407 407 407 374 374
PPB (20.7+0.6) (23.3 + 0.5) (29.0+0.7) (17.8 + 0.6) (14.8+0.5)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 496 496 496 504 504
PPB (20.0+0.6) (22.8 + 0.5) (28.1+0.7) (18.6 + 0.6) (14.7+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (22.4 + 0.7) (25.5 + 0.5) (32.7 + 0.8) (18.9+0.6) (15.2 + 0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 D37 D37 1337 1337
PPB (18.7+0.9) (9.80+0.4) (23.0 + 0.6) (17.3 + 0.5) (16.6+0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8+0.2) (16.8 + 0.5) (16.1+1.0)
*Number of days after Is t RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-55
-------
STABILITY STUDY FDR GROUP I COMPOUNDS***
CYLINDER I-A12
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(14.3)
12/08/83
(12.7)
12/19/83
(12.6)
(14.0)
12/08/83
(13.2)
12/19/83
(12.9)
(71.8)
12/08/83
(70.9)
12/19/83
(68.3)
(50.7)
12/09/83
(46.5)
12/16/83
(48.9)
(30.0)
12/09/83
(28.1)
12/16/83
(28.5)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/05/84
(14.2 + 2.7)
60
(13.4 + 0.4)
on audit
on audit
on audit
833
(16.9+0.5)
on audit
1/05/84
(13.0+0.3)
60
(12.4 + 0.3)
on audit
on audit
on audit
833
(15.3+0.4)
on audit
1/05/84
(74.3 + 1.8)
60
(75.6+1.8)
on audit
on audit
en audit
833
(78.0 + 1.9)
on audit
1/20/84
(51.9 + 1.7)
52
(51.2 + 1.6)
en audit
on audit
en audit
810
(52.6+1.7)
en audit
1/20/84
(31.1 + 1.0)
52
(29.6+0.9)
on audit
on audit
on audit
810
(31.8 + 1.0)
on audit
RTI CJJALrTY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/05/84
(20.4+0.6)
(21.0 + 1.0)
1/05/84
(22.8+0.5)
(23.0 + 1.0)
1/05/84
(30.7+0.7)
(29.0 + 2.0)
1/20/84
(18.4 + 0.6)
(17.0 + 1.0)
1/20/84
(14.8 + 0.5)
(15.0 + 1.0)
(Continued)
A-56
-------
STABILITY STUDY FOR GKOUP I COMPOUNDS*** (Continued)
CYLINDER I-A12
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chlorcform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
KTI OJUALITY CONTROL**
2nd RTI Analysis Day 60 60 60 52 52
PPB (20.3 + 0.6) (8.90 + 0.2) (23.6+0.6) (18.6 + 0.6) (15.0 + 0.5)
NBS Concentration**
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
3rd RTI Analysis Day 238 238 238 228 228
PPB (20.3+0.6) (23.6 + 0.5) (28.3+0.7) (19.0+0.6) (14.8+0.5)
NBS Concentration
PPB
(21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
4th RTI Analysis Day 407 407 407 374 374
PPB (20.7+0.6) (23.3+0.5) (29.0+0.7) (17.8+0.6) (14.8+0.5)
NBS Concentration
PPB
(19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (17.0 + 1.0) (15.0 + 1.0)
5th RTI Analysis Day 496 496 496 504 504
PPB (20.0+0.6) (22.8+0.5) (28.1+0.7) (18.6+0.6) (14.7+0.5)
NBS Concentration
PPB ('21.0 + 1.0) (23.0 + 1.0) (29.0 + 2.0) (17.0 + 1.0) (15.0 + 1.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (144 + 4.3) (119 + 2.5) (D5+3.3) (18.9 + 0.6) (15.2 + 0.5)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 1337 1337 1337 1337
PPB (18.7 + 0.9) (9.80+0.4) (23.0+0.6) (17.3+0.5) (16.6 + 0.6)
NBS Concentration
PPB (19.3 + 1.0) (9.60 + 0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentraticn with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-57
-------
STABILITY STUDY FDR GROUP I (DMPOUNDS
CYLINDER I-AD
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chlorofonn
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(89.0)
12/07/83
(83.3)
12/15/83
(81.0)
(353)
12/07/83
(369)
12/15/83
(371)
(313)
12/07/83
(297)
12/15/83
(315)
(134)
12/08/83
(133)
12/19/83
(139)
(150)
12/08/83
(136)
12/19/83
(145)
RTI ANALYSIS
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
1/09/84
(91.6 + 2.7)
57
(97.0 + 2.9)
231
(94.7 + 2.8)
395
(86.7 + 2.6)
491
(86.2+2.6)
enpty
1/09/84
(351 + 7.4)
57
(354 + 7.4)
231
(334 + 7.0)
395
(325+6.8)
491
(331 + 7.0)
enpty
1/09/84
(332 + 8.0)
57
(359 + 8.6)
231
(323 + 7.8)
395
(322 + 7.7)
491
(313 + 7.5)
enpty
1/20/84
(140 + 4.5)
54
(139 +4.4)
225
(145 + 4.6)
370
(138 +4.4)
497
(138+4.4)
enpty
V20/84
(156 + 5.0)
54
(152+4.9)
225
(153 + 4.9)
370
(153 + 4.9)
497
(146 +4.7)
empty
RTI QUALITY CONTROL**
1st RTI Analysis Date
-PPB
NBS Concentration
PPB
V09/84
(18.9+0.6)
(19.0 + 1.0)
1/09/84
(9.40+0.2)
(9.00 + 1.0)
1/09/84
(24.4+0.6)
(22.0 + 1.0)
1/20/84
(18.4 + 0.6)
(17.0+1.0)
1/20/84
(14.8 + 0.5)
(15.0 + 1.0)
(Continued)
A-58
-------
STABILITY STUDY FOR GROUP I COMPOUNDS (Continued)
CYLINDER I-A13
ACTIVITY
COMPOUND
Carboa tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
KTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 54 54
PPB (21.5 + 0.6) (10.1 + 0.2) (26.1 + 0.6) (192 + 6.1) (192 + 6.1)
NBS Concentration**
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (192 + 4.0)** (192 + 4.0)**
3rd RTI Analysis Day 231 231 231 225 225
PPB (155+4.7) (132 + 2.8) (147+3.5) (191 + 6.1) (191 + 6.1)
NBS Concentration
PPB
(155+3.0) (134 + 3.0) (146 + 3.0) (192+4.0) (192 + 4.0)
4th RTI Analysis Day 395 395 395 370 370
PPB (154 + 4.6) (135 + 2.8) (145 + 3.5) (200 + 6.4) (195 + 6.2)
NBS Concentration
PPB
(155 + 3.0) (134+3.0) (146 + 3.0) (192+4.0) (192 + 4.0)
5th RTI Analysis Day 491 491 491 497 497
PPB (142 + 4.3) (115+2.4) (126 + 3.0) (139+4.4) (149+4.8)
NBS Concentration
PPB
(141+3.0) (120 + 3.0) (126+3.0) (D3 + 3.0) (154+3.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (166 + 5.0) (130 + 2.7) (144 + 3.5) (18.9+0.6) (15.2 + 0.5)
NBS Concentration
PPB
(155+3.0) (134 + 3.0) (146 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis unless
otherwise indicated. Several different NBS primary standards were used.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-59
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A14
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(91.5)
12/07/83
(81.6)
12/15/83
(78.3)
(362)
12/07/83
(373)
12/15/83
(367)
(321)
12/07/83
(301)
12/15/83
(312)
(138)
12/08/83
(130)
12/19/83
(135)
(150)
12/08/83
(137)
12/19/83
(145)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/09/84
(90.5 + 2.7)
57
(90.6 + 2.7)
231
(92.3+2.8)
395
(85.7+2.6)
(86.2+2.6)
833
(73.9 + 2.2)
on audit
1/09/84
(339 + 7. 1)
57
(345 + 7.2)
231
(326 + 6.8)
395
(335 + 7.0)
(331 + 7.0)
833
(350 + 7.4)
on audit
1/09/84
(324 + 7.8)
57
(342 + 8.2)
231
(317 + 7.6)
395
(322 + 7.7)
(307 + 7.4)
833
(320 + 7.9)
on audit
1/20/84
(138+4.4)
54
(135 + 4.3)
225
(140+4.5)
371
(137 +4.4)
(137 +4.4)
810
(127+4.1)
.on audit
1/20/84
(154 + 4.9)
54
(151+4.8)
225
(153+4.9)
371
(152+4.9)
(150 + 4.8)
810
(160 + 5.2)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/09/84
(18.9 + 0.6)
(19.0 + 1.0)
1/09/84
(9.4 + 0.2)
1/09/84
(24.4+0.6)
(9.00 + 1.0) (22.0 + 1.0)
V 20/84
(18.4 + 0.6)
(17.0 + 1.0)
1/20/84
(14.8+0.5)
(15.0 + 1.0)
(Continued)
A-60
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A14
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 54 54
PPB (21.5+0.6) (10.1 + 0.2) (26.1+0.6) (192+6.1) (192 + 6.1)
NBS Concentration
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (192 + 4.0)** (192 + 4.0)**
3rd RTI Analysis Day 231 231 231 225 225
PPB (155 + 4.7) (132 + 2.8) (147+3.5) (191 + 6.1) (191+6.1)
NBS Concentration
PPB
(155+3.0) (134 + 3.0) (146+3.0) (192 + 4.0) (192 + 4.0)
4th RTI Analysis Day 395 395 395 371 371
PPB (155 + 4.6) (D5 + 2.8) (146+3.5) (199 + 6.4) (187+6.0)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146+3.0) (192 + 4.0) (192+4.0)
5th RTI Analysis Day 491 491 491 497 497
PPB (142+4.3) (115+2.4) (126+3.0) (D9+4.4) (149+4.8)
NBS Concentration
PPB
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
6th RTI Analysis Day 833 833 833 810 810
PPB (166 + 5.0) (130 + 2.7) (144 + 3.5) (18.9 + 0.6) (15.2+0.5)
NBS Concentration
PPB
(155 + 3.0) (134 + 3.0) (146 + 3.0) (17.0 + 1.0) (15.0 + 1.0)
7th RTI Analysis Day 1337 D37 D37 D37 1337
PPB (18.7 + 0.9) (9.80 + 0.4) (23.0 + 0.6) (17.3 + 0.5) (16.6 + 0.6)
NBS Concentration
PPB
(19.3 + 1.0) (9.60+0.2) (22.8 + 0.2) (16.8 + 0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as Internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentraticn with cryofocusing followed
by GC/FID. Previous analysis were performed by direct Injection.
A-61
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A15
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(307)
12/07/83
(301)
12/15/83
(293)
(126)
12/07/83
(130)
12/15/83
(143)
(102)
12/07/83
(98.3)
12/15/83
(119)
(364)
12/02/83
(350)
12/19/83
(360)
(400)
12/02/83
(397)
12/19/83
(393)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
V09/84
(317 + 6.7)
57
(327 + 9.8)
231
(299 + 9.0)
395
(299 + 9.0)
491
(297 + 8.9)
833
(310 + 9.2)
D37
(291 + 8.6)
1/09/84
(125+2.6)
57
(133 + 2.8)
231
(126+2.6)
395
(126 + 2.6)
491
(123 + 2.6)
833
(117+2.5)
B37
(123 + 2.6)
1/09/84
(108 + 2.6)
57
(119 + 2.9)
231
(100 + 2.4)
395
(103 + 2.5)
491
(104 + 2.5)
833
(121+3.0)
1337
(104+2.6)
1/20/84 1/20/84
(382 + 12.2) (418 + 13.4)
51 51
(387 + 12.4) (404 + 12.9)
227 227
(391 + 12.5) (404 + 12.9)
370 370
(378 + 12.1) (409 + 13.1)
on audit
en audit
810 810
(392 + 12.6) (426 + 13.9)
D37 D37 .
(367 + 11.8) (416 + 13.6)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/09/84
(162+4.9)
(154 + 3.0)
1/C9/84
(130 + 2.7)
(134+3.0)
1/09/84
(148+3.6)
(145 + 3.0)
1/20/84
(18.4+0.6)
V 20/84
(14.8+0.5)
(17.0+1.0)** (15.0+1.0)*-
(Continued)
A-62
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A15
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
KTI CJJALIIY CONTROL**
2nd RTI Analysis Day
PPB
NBS Concentration**
PPB
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
57 57 57 51 51
(21.5+0.6) (10.1 + 0.2) (26.1+0.6) (192 + 6.1) (192 + 6.1)
(19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (192+4.0)** (192+4.0)**
231 231 231 227 227
(155 + 4.7) (132 + 2.8) (147+3.5) (191 + 6.i) (191 + 6.1)
(155 + 3.0) (134 + 3.0) (146 + 3.0) (192 + 4.0) (192+4.0)
395 395 395 370 370
(154+4.6) (135+2.8) (145 + 3.5) (200 + 6.4) (195+6.2)
(155 + 3.0) (134 + 3.0) (146+3.0) (192+4.0) (192+4.0)
491 491 491 497 497
(142 + 4.3) (115+2.4) (126+3.0) (139+4.4) (149+4.8)
(141 + 3.0) (120 + 3.0) (126 + 3.0) (133 + 3.0) (154 + 3.0)
833 833 833 810 810
(166 + 5.0) (DO+ 2.7) (144+3.5) (143+4.6) (156+5.1)
(155 + 3.0) (134+3.0) (146+3.0) (133+3.0) (154 + 3.0)
D37 1337 B37 D37 D37
(18.3+0.9) (9.54 + 0.2) (22.7 + 0.6) (16.6+0.5) (15.8+0.5)
(19.3 + 1.0) (9.60+0.2) (22.8+0.2) (16.8+0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal qual'.ty control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by QC/FID. Previous analysis were performed by direct injection.
A-63
-------
STABILITY STUDY FOR GROUP I COMPOUNDS***
CYLINDER I-A16
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(304)
12/05/83
(297)
12/15/83
(293)
(125)
12/05/83
(120)
12/15/83
(135)
(101)
12/05/83
(91.5)
12/15/83
(87.9)
(360)
12/12/83
(344)
12/19/83
(355)
(400)
12/12/83
(397)
12/19/83
(382)
RTI ANALYSIS****
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5th RTI Analysis Day*
PPB
6th RTI Analysis Day*
PPB
7th RTI Analysis Day*
PPB
1/09/84
(314 + 9.4)
57
(323 + 9.7)
on audit
395
(296 + 8.9)
491
(295 + 8.9)
833
(307 + 9. 1)
on audit
1/09/84
(122 + 2.6)
57
(128 + 2.7)
on audit
395
(126 + 2.6)
491
(121 + 2.5)
833
(114 + 2.4)
on audit
1/09/84
(107 + 2.6)
57
(119 + 2.9)
on audit
395
(103+2.5)
491
(104 + 2.5)
833
(120.3 + 2.9)
on audit
1/20/84 1/20/84
(377 + 12.1) (418 + 13.4)
51 51
(379 + 12.1) (403 + 12.9)
on audit
on audit
370 370
(368 + 11.8) (408 + 13.1)
on audit
on audit
810 810
(389 + 12.5) (423 + 13.8)
on audit
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concentration
PPB
1/09/84
(162+4.9)
(154 + 3.0)
1/09/84
(130+2.7)
(134+3.0)
V09/84
(143+3.6)
(145+3.0)
1/20/84
(18.4+0.6)
1/20/84
(14.8+0.5)
(17.0 + 1.0)** (15.0 + 1.0)**
(Continued)
A-64
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*** (Continued)
CYLINDER I-A16
COMPOUND
ACTIVITY
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
RTI QUALITY CONTROL**
2nd RTI Analysis Day 57 57 57 51 51
PPB (21.5 + 0.6) (10.1+0.2) (26.1 + 0.6) (192 + 6.1) (192 + 6.1)
NBS Concentration**
PPB (19.0 + 1.0) (9.00 + 1.0) (22.0 + 1.0) (192 + 4.0)** (192 + 4.0)**
3rd RTI Analysis Day
PPB
NBS Concentration
PPB
4th RTI Analysis Day
PPB
NBS Concentration
PPB
5th RTI Analysis Day
PPB
NBS Concentration
PPB
6th RTI Analysis Day
PPB
NBS Concentration
PPB
7th RTI Analysis Day
PPB
NBS Concentration
PPB
231 231 231 227 227
(155+4.7) (132 + 2.8) (147+3.5) (191 + 6.1) (191 + 6.1)
(155+3.0) (134 + 3.0) (146+3.0) (192+4.0) (192 + 4.0)
395 395 395 370 370
(154+4.6) (135 + 2.8) (145+3.5) (200 + 6.4) (195 + 6.2)
(155 + 3.0) (134 + 3.0) (146+3.0) (192+4.0) (192+4.0)
491 491 491 497 497
(142+4.3) (115+2.4) (126+3.0) (139+4.4) (149 + 4.8)
(141+3.0) (120 + 3.0) (126+3.0) (133 + 3.0) (154 + 3.0)
833 833 833 810 810
(166+5.0) (130 + 2.7) (144 + 3.5) (143+4.6) (156+5.1)
(155 + 3.0) (134 + 3.0) (146+3.0) (133+3.0) (154 + 3.0)
D37 1337 D37 1337 D37
(18.7+0.9) (9.80 + 0.4) (23.0 + 0.6) (17.3 + 0.5) (16.6+0.6)
(19.3 + 1.0) (9.60 + 0.2) (22.8+0.2) (16.8+0.5) (16.1 + 1.0)
*Number of days after 1st RTI analysis date.
**A different NBS standard was analyzed as internal quality control on each day of RTI analysis.
***A NBS primary standard was used for calibration for 7th RTI Analysis. Permeation tubes were used for
calibration for all previous analyes.
****Seventh analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. Previous analysis were performed by direct injection.
A-65
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A17
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(1500)
9/26/85
(1502)
(800)
9/26/85
(837)
(1500)
9/26/85
(1441)
(800)
9/26/85
(805)
(1500)
9/26/85
(1489)
KTI ANALYSIS***
1st KTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(1585 + 48)
68
(1584 + 48)
153
(1565 + 29)
507
(1554 + 30)
5/07/86
(904 + 19)
68
(844 + 18)
153
(859 + 21)
507
(840 + 22)
5/07/86
(1642 + 40)
68
(1645+40)
153
(1468 + 47)
507
(1614 + 48)
5/07/86
(904 + 29)
68
(881 + 28)
153
(808 + 11)
507
(883 + 12)
5/07/86
(1648 + 53)
68
(1585 + 51)
153
(1542 + 25)
507
(1527 + 26)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
MBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Ccncen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
507
(2472 + 26)
(2486 + 27)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
507
(2272 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
507
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
507
(2821 + 8.0)
(2830+9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486+27)
153
(2472 + 42)
(2469 + 27)
507
(2472 + 28)
(2486+27)
*Number of days after 1st KIT analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed ty automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-66
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A18
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(8000)
9/26/85
(8400)
(4000)
9/26/85
(3877)
(8000)
9/26/85
(7938)
(8000)
9/26/85
(7960)
(6000)
9/26/85
(6061)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(9386 + 284)
68
(9400 + 285)
153
(8041 + 161)
506
(8082 + 162)
5/07/86
(4418 + 94)*
68
(4318 + 92)*
153
(3991 + 108)
506
(4111 + 109)
5/07/86
(9486 + 231)
68
(9617 + 234)
153
(8906 + 256)
506
(8938 + 255)
5/07/86
(9458 + 301)
68
(9359 + 297)
153
(9056 + 105)
506
(9082 + 106)
5/07/86
(6555 + 211)
68
(6641 + 214)
153
(6461 + 101)
506
(6468 + 102)
RTI OJJAL1TY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
506
(2100 + 17)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
506
(2259 + 9)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
506
(2109 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
506
(2833 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2436 + 27)
153
(2472 + 42)
(2469 + 27)
506
(2493 + 28)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-67
-------
STABILITY STUDY FOR GROUP I (DMPOUNDS
CYLINDER I-A19
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(6000)
9/26/85
(6084)
(8000)
9/26/85
(7854)
(4000)
9/26/85
(4155)
(4000)
9/26/85
(4069)
(8000)
9/26/85
(7824)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(8062 + 244)
68
(7240 + 219)
153
(7118 + 120)
498
(7270 + 121)
5/07/86
(9593 + 205)
68
(9730 + 208)
153
(8886 + 213)
498
(8987 + 214)
5/07/86
(4121 + 100)
68
(4579 + 111)
153
(4131 + 132)
498
(4160 + 133)
5/07/86
(4065 + 129)
68
(4667 + 148)
153
(4072 + 53)
598
(4084 + 54)
5/07/86
(9463 + 304)
68
(8999 + 290)
153
(8957 + 134)
598
(9024 + 154)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
49S
(2278 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
498
(2105 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
498
(2839 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486+27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
498
(2482 + 26)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed ty automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-68
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A20
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(6000)
9/26/85
(6012)
(8000)
9/26/85
(7829)
(4000)
9/26/85
(4103)
(4000)
9/26/85
(4055)
(8000)
9/26/85
(7841)
RTI ANALYSIS***
IstRTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(6731 + 204)
68
(7340 + 222)
153
(6913 + 118)
498
(7114 + 119)
5/07/86
(9356 + 200)
68
(9521 + 203)
153
(7904 + 213)
498
(7984 + 214)
5/07/86
(4764 + 116)
68
(4739 + 115)
153
(4618 + 129)
498
(4687 + DO)
5/07/86
(4295 + 137)
68
(4784 + 152)
153
(3998 + 52)
498
(4017 + 152)
5/07/86
(9064 + 292)
68
(9142 + 294)
153
(7844 + 133)
498
(8014 + 133)
KTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
498
(2278 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
498
(2105 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
498
(2839 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
498
(2482 + 26)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-69
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A21
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(3000)
9/26/85
(2990)
(6000)
9/26/85
(5979)
(3000)
9/26/85
(3D1)
(6000)
9/26/85
(6139)
(4000)
9/26/85
(4010)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(3220 + 98)
68
(3246 + 98)
153
(2968 + 59)
on audit
5/07/86
(6277 + 134)
68
(6808 + 145)
153
(5950 + 161)
on audit
5/07/86
(3157 + 77)
68
(3416 + 83)
153
(2940 + 94)
on audit
5/07/86
(7127 + 227)
68
(7008 + 223)
153
(6024 + 78)
on audit
5/07/86
(39% + 129)
68
(4238 + 137)
153
(3983 + 68)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
498
(2278 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
498
(2105 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526+8.0)
498
(2839 +; 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472+42)
(2469 + 27)
498
(2482 + 26)
(2436 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-70
-------
STABILITY STUDY TOR GROUP I COMPOUNDS
CYLINDER I-A22
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(800)
9/26/85
(7%)
(1500)
9/26/85
(1461)
(800)
9/26/85
(795)
(1500)
9/26/85
(1497)
(800)
9/26/85
(783)
KTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(854 + 26)
68
(839 + 25)
153
(774 + 15)
on audit
5/07/86
(1365 + 29)
68
(1539 + 33)
153
(1506 + 41)
on audit
5/07/86
(784 + 19)
68
(846 + 21)
153
(840 + 27)
on audit
5/07/86
(1533 + 49)
68
(1587+51)
153
(1559+20)
on audit
5/07/86
(813 + 26)
68
(823 + 27)
153
(805 + 14)
on audit
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
498
(2278 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
498
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830+9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
498
(2839 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486+27)
153
(2472 + 42)
(2469 + 27)
498
(2482 + 26)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocuslng followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-71
-------
STABILITY STUDY R)R GROUP I COMPOUNDS
CYLINDER I-A23
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(800)
9/26/85
(789)
(1500)
9/26/85
(1431)
(800)
9/26/85
(789)
(1500)
9/26/85
(1459)
(800)
9/26/85
(780)
RTI ANALYSIS***
1st RTI Analysis Date
PP3
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(822 + 25)
68
(839 + 25)
153
(783 + 16)
498
(780 + 15)
5/07/86
(1313 + 28)
68
(1492 + 32)
153
(1453 + 39)
498
(1421 + 38)
5/07/86
(789 + 19)
68
(832 + 20)
153
(806 + 26)
498
(813 + 27)
5/07/86
(1560 + 50)
68
(1560 + 50)
153
(1486 + 19)
498
(1474 + 18)
5/07/86
(857 + 28)
68
(834 + 27)
153
(800 + 14)
498
(786 + 15)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284+48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
498
(2278 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
63
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
498
(2105 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
498
(2839 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
498
(2482 + 26)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by au tana ted cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
-------
STABILITY STUDY TOR GROUP I COMPOUNDS
CYLINDER I-A24
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(1500)
9/26/85
(1480)
(800)
9/26/85
(811)
(1500)
9/26/85
(1495)
(800)
9/26/85
(798)
(1500)
9/26/85
(1491)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th KTI Analysis Day*
PPB
5/07/86
(1582 + 48)
68
(1571+47)
153
(1553 + 29)
507
(1555 + 30)
5/07/86
(803 + 17)
68
(830 + 18)
153
(784 + 21)
507
(801 + 20)
5/07/86
(1534 + 37)
68
(1530 + 37)
153
(1503+46)
507
(1512+47)
5/07/86
(760 + 24)
68
(852 + 27)
153
(824 + 11)
507
(815 + 12)
5/07/86
(1492+48)
68
(1535+50)
153
(1498+25)
507
(1481 + 24)
RTI QUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
507
(2472 + 26)
(2486 + 27)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
507
(2272 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
507
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
507
(2821 + 8.0)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
507
(2472 + 28)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FTD. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-73
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A25
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(4000)
9/26/85
(4166)
(3000)
9/26/85
(2986)
(6000)
9/26/85
(6095)
(3000)
9/26/85
(3014)
(3000)
9/26/85
(2932)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(4582 + 138)
68
(4308 + 130)
153
(3918 + 78)
on audit
5/07/86
(3032 + 66)
68
(3200 + 68)
153
(2924 + 39)
en audit
5/07/86
(6770 + 165)
68
(6765 + 164)
153
(5881 + 188)
on audit
5/07/86
(3047 + 97)
68
(3283 + 104)
153
(2964 + 39)
en audit
5/07/86
(3574 + 116)
68
(3122 + 101)
153
(2952 + 50)
en audit
RTI OJUALITY CONTROL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RT Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
507
(2472 + 26)
(2486 + 27)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284+48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
507
(2272 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
507
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526+8.0)
507
(2821+8.0)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
507
(2472 + 28)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control en each day of RTI analysis.
***Fourth analysis was performed by autcroated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-74
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A26
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(8000)
9/26/85
(8506)
(4000)
9/26/85
(3892)
(8000)
9/26/85
(7810)
(8000)
9/26/85
(7951)
(6000)
9/26/85
(6037)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(9734 + 294)
68
(9632 + 291)
154
(8028 + 161)
498
(8076 + 162)
5/07/86
(4243 + 90)
68
(4405 + 94)
154
(3992 + 108)
498
(4160 + 109)
5/07/86
(9753 + 236)
68
(9788 + 237)
154
(8209 + 250)
498
(8406 + 251)
5/07/86
(9540 + 302)
68
(9491 + 301)
154
(9116 + 104)
498
(9209 + 105)
5/07/86
(7229 + 234)
68
(7009 + 227)
154
(6952 + 101)
498
(6914 + 102)
RTI QUALITY ODNTRQL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Tiy
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2509 + 50)
(2513 + 19)
498
(2092 + 15)
(2095 + 16)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2980 + 80)
(2988 + 13)
"498
(2278 + 11)
(2269 + 10)
5/07/86
(2044 _+ 49)
(2096 + 13)
68
(2194 + 53)
(2096 + 13)
153
(2794 + 89)
(2800 + 17)
498
(2105 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2533 + 33)
(2526 + 8.0)
498
(2839 + 10)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486+27)
68
(2484 + 80)
(2486 + 27)
153
(2465 + 42)
(2469 + 27)
498
(2482 + 26)
(2486 + 27)
*Nuirber of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of KTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-75
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A27
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(3000)
9/26/85
(2953)
(6000)
9/26/85
(5942)
(3000)
9/26/85
(3143)
(6000)
9/26/85
(6119)
(4000)
9/26/85
(3947)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
PPB
4th RTI Analysis Day*
PPB
5/07/86
(3421 + 103)
68
(3231 + 98)
154
(2998 + 60)
498
(2987 + 59)
5/07/86
(6435 + 137)
68
(7191 + 153)
154
(5880 + 159)
498
(6097 + 160)
5/07/86
(3239 + 79)
68
(3345 + 81)
154
(2951 + 94)
498
(3230 + 95)
5/07/86
(6820+216)
68
(7177 + 227)
154
(5989 + 71)
498
(6058 + 72)
5/07/86
(4049 + 131)
68
(4158 + 135)
154
(3917 + 67)
498
(4093 + 68)
RTI QUALITY CDNTRDL**
1st RTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
507
(2472 + 26)
(2486 + 27)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 +81)
(2988 + 13)
507
(2272 + 11)
(2269 + 10)
5/07/86
(2044 + 49)
(20% + 13)
68
(2194 + 53)
(2096 + 13)
153
(2784 + 89)
(2800 + 17)
507
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9.0)
68
(2909 + 93)
(2830 + 9.0)
153
(2534 + 33)
(2526 + 8.0)
507
(2821 + 8.0)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486 + 27)
153
(2472 + 42)
(2469 + 27)
507
(2472 + 28)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-76
-------
STABILITY STUDY FOR GROUP I COMPOUNDS
CYLINDER I-A28
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(4000)
9/26/85
(4041)
(3000)
9/26/85
(2915)
(6000)
9/26/85
(6105)
(3000)
9/26/85
(3013)
(3000)
9/26/85
(2937)
RTI ANALYSIS***
1st RTI Analysis Date
PPB
2nd RTI Analysis Day*
PPB
3rd RTI Analysis Day*
4th RTI Analysis Day*
PPB
5/07/86
(4305 + DO)
68
(4474 + 135)
on audit
507
(4432 + 130)
5/07/86
(3076 + 65)
68
(3336 + 71)
on audit
507
(3287 + 70)
5/07/86
(6937 + 168)
68
(6959 + 169)
on audit
507
(6940 + 166)
5/07/86
(3100 + 98)
68
(3448 + 109)
en audit
507
(3396 + 100)
5/07/86
(3412 + 110)
68
(3342 + 108)
on audit
507
(3385 + 102)
KTI OJUALITY CONTROL**
1st KTI Analysis Date
PPB
NBS Concen. PPB
2nd RTI Analysis Day
PPB
NBS Concen. PPB
3rd RTI Analysis Day
PPB
NBS Concen. PPB
4th RTI Analysis Day
PPB
NBS Concen. PPB
5/07/86
(2279 + 68)
(2095 + 16)
68
(2226 + 67)
(2095 + 16)
153
(2505 + 50)
(2513 + 19)
507
(2472 + 26)
(2486 + 27)
5/07/86
(2328 + 49)
(2269 + 10)
68
(2284 + 48)
(2269 + 10)
153
(2985 + 81)
(2988 + 13)
507
(2272 + 1.1)
(2269 + 10)
5/07/86
(2044 + 49)
(2096 + 13)
68
(2194 + 53)
(20% + 13)
153
(2784 + 89)
(2800 + 17)
507
(2106 + 14)
(2096 + 13)
5/07/86
(2868 + 92)
(2830 + 9)
68
(2909 + 93)
(2830 + 9)
153
(2534 + 33)
(2526 + 8.0)
507
(2821+8.0)
(2830 + 9.0)
5/07/86
(2363 + 76)
(2486 + 27)
68
(2484 + 80)
(2486+27)
153
(2472 + 42)
(2469 + 27)
507
(2472 + 28)
(2486 + 27)
*Number of days after 1st RTI analysis date.
**NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
***Fourth analysis was performed by automated cryogenic preconcentration with cryofocusing followed
by GC/FID. The remaining analysis was performed by direct injection. Calibrations was performed
using a NBS primary standard.
A-77
-------
STABILITY STUDY TOR (SOUP I COMPOUNDS*
CYLINDER I-A30
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(19.6)
3/13/87
(18.8)
(9.82)
4/30/87
(9.61)
(19.6)
4/30/87
(18.1)
(9.84)
4/30/87
(9.91)
(30.0)
4/30/87
(26.9)
KTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/06/87
(20.8 + 2.0)
50
(20.7 + 2.0)
7/06/87
(10.1+0.3)
50
(9.50 + 0.3)
7/06/87
(20.7+0.6)
50
(20.7+0.6)
7/06/87
(9.79+0.4)
50
(9.51+0.4)
7/06/87
(28.0 + 1.9)
50
(27.0 + 1.9)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/06/87
(20.6+2.0)
(21.0 + 1.0)
50
(17.7 + 1.7)
(19.3 + 1.0)
7/06/87
(23.1+0.7)
(23.0+0.2)
50
(8.00 + 0.2)
(9.60 + 0.2)
7/06/87
(30.0 + 0.8)
(29.0 + 1.0)
50
(20.7+0.6)
(22.8 + 0.2)
7/06/87
(19.0 + 0.8)
(18.0 + 0.5)
50
(14.4+0.6)
(16.8+0.5)
7/06/87
(24.5 + 1.7)
(31.0 + 1.0)
50
NA
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
NA = Not Analyzed.
A-78
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*
CYLINDER I-A31
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(20.0)
3/13/87
(18.8)
(10.0)
4/30/87
(9.83)
(20.0)
4/30/87
(19.0)
(10.0)
4/30/87
(10.1)
(30.0)
4/30/87
(27.3)
KTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/06/87
(21.1 + 2.0)
63
(21.1 + 2.0)
7/06/87
(10.2 + 0.3)
63
(10.2 + 0.3)
7/06/87
(21.0+0.6)
63
(20.6+0.6)
7/06/87
(10.0 + 0.4)
63
(10.0+0.5)
7/06/87
(27.1 + 1.9)
63
(27.0 + 1.9)
RTI OJJALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/06/87
(20.6 + 2.0)
(21.0 + 1.0)
63
(17.6 + 1.7)
(19.3 + 1.0)
7/06/87
(23.1 + 0.2)
(23.0 + 0.2)
63
(9.50+0.3)
(9.60 + 0.2)
7/06/87
(30.0+0.8)
(29.0 + 1.0)
63
(22.7+0.6)
(22.8 + 0.2)
7/06/87
(19.0+0.8)
(18.0 + 0.5)
63
(16.6 + 0.7)
(16.8 + 0.5)
7/06/87
(24.5 + 1.7)
(31.0 + 1.0)
63
(15.7 + 1.1)
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTT analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of KTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentraticn with cryofocusing followed
by GC/FID.
A-79
-------
STABILITY STUDY FOR OlOUP I (IMPOUNDS*
. CYLINDER I-A32
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PEB
1st Analysis Date
PPB
(20.1)
3/23/87
(19.7)
(10.1)
V 10/87
(9.67)
(20.1)
V 10/87
(18.2)
(10.1)
4/10/87
(10.3)
(30.0)
4/10/87
(26.9)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/07/87
(20.4 + 1.9)
62
(20.8 + 2.0)
7/07/87
(10.1+0.3)
62
(10.3+0.3)
7/07/87
(20.8 + 0.6)
62
(20.3+0.6)
7/07/87
(9.72+0.4)
62
(10.4 + 0.5)
7/07/87
(26.8 + 1.8)
62
(30.5 + 2.1)
RTI QUALITY CONTROL*** .
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/07/87
(21.7+2.0)
(21.0 + 1.0)
62
(17.6 + 1.7)
(19.3 + 1.0)
7/07/87
(24.8+0.7)
(23.0+0.2) '
62
(9.50 + 0.3)
(9.60+0.2)
7/07/87
(30.1+0.8)
(29.0 + 1.0)
62
(22.7+0.6)
(22.8 + 0.2)
7/07/87
(19.1 + 0.8)
(18.0+0.5)
62
(16.6 + 0.7)
(16.8 + 0.5)
7/07/87
(29.5 + 2.0)
(31.0 + 2.5)
62
(15.7 + 1.1)
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of KTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentraticn with cryofocusing followed
by GC/FID.
A-80
-------
STABILITY STUDY TOR GROUP I COMPOUNDS*
CYLINDER I-A33
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(20.1)
3/12/87
(19.5)
(10.1)
4/08/87
(10.3)
(20.2)
4/08/87
(19.7)
(10.1)
4/08/87
(10.7)
(30.0)
4/08/87
(26.0)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/07/87
(21.4 + 2.0)
on audit
7/07/87
(10.6+0.3)
en audit
7/07/87
(20.6+0.6)
on audit
7/07/87
(10.3 + 0.5)
on audit
7/07/87
(29.4+2.0)
on audit
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/07/87
(21.2 + 2.0)
(21.0 + 1.0)
62
(17.6 + 1.7)
(19.3 + 1.0)
7/07/87
(24.8 + 0.7)
(23.0 + 0.2)
62
(9.50 + 0.3)
(9.60+0.2)
7/07/87
(30.1+0.8)
(29.0 + 1.0)
62
(22.7+0.6)
(22.8+0.2)
7/07/87
(19.1+0.8)
(18.0 + 0.5)
62
(16.6+0.7)
(16.8+0.5)
7/07/87
(29.5 + 2.0)
(23.0 + 1.0)
62
(15.1 + 1.1)
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st KTI analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
A-81
-------
STABILITY STUDY FDR GROUP I COMPOUNDS*
CYLINDER I-A34
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(10.2)
3/12/87
(9.48)
(15.2)
5/01/87
(15.2)
(10.2)
5/01/87
(9.67)
(10.2)
5/01/87
(10.2)
(15.0)
5/01/87
(14.0)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/07/87
(10.8 + 1.0)
62
(9.50 + 0.9)
7/07/87
(16.1+0.5)
62
(14.9 + 0.4)
7/07/87
(11.1 + 0.3)
62
(11.5 + 0.3)
7/07/87
(10.3+0.5)
62
(10.4 + 0.5)
7/07/87
(15.2 + 1.0)
62
(14.6 + 1.0)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/07/87
(21.2 + 2.0)
(21.0 + 1.0)
62
(17.6 + 1.7)
(19.3 + 1.0)
7/07/87
(24.8 + 0.7)
(23.0 + 0.2)
62
(9.50 + 0.3)
(9.60 + 0.2)
7/07/87
(30.1+0.8)
(29.0+1.0)
62
(22.7+0.6)
(22.8+0.2)
7/07/87
(19.1+0.8)
(18.0 + 0.5)
62
(16.6 + 0.7)
(16.8 + 0.5)
7/07/87
(29.5+2.0)
(31.0 + 1.0)
62
(15.7 + 1.1)
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as an Internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
A-82
-------
STABILITY STUDY FOR GROUP I COMPOUNDS*
CYLINDER I-A35
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(10.3)
3/03/87
(9.85)
(30.9)
5/01/87
(30.3)
(10.3)
5/01/87
(9.85)
(30.9)
5/01/87
(31.1)
(20.0)
5/01/87
(18.2)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/06/87
(9.69+0.9)
50
(9.66+0.9)
7/06/87
(31.4 + 0.9)
50
(30.9 + 0.9)
7/06/87
(10.9 + 0.3)
50
(10.9+0.3)
7/06/87
(30.8+1.4)
50
(30.6 + 1.3)
7/06/87
(21.5 + 1.5)
50
(21.2 + 1.5)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/06/87
(20.6 + 2.0)
(21.0 + 1.0)
50
(17.7 + 1.7)
(19.3 + 1.0)
7/06/87
(23.1 + 0.7)
(23.0 + 0.2)
50
(8.00+0.2)
(9.60+0.2)
7/06/87
(30.0 + 0.8)
(29.0 + 1.0)
50
(20.7+0.6)
(22.8 + 0.2)
7/06/87
(19.0 + 0.8)
(IB. 0 + 0.5)
50
(14.4 + 0.6)
(16.8+0.5)
7/06/87
(24.5 + 1.7)
(31.0 + 1.0)
50
NA
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
NA = Not Analyzed
A-83
-------
STABILITY STUDY TOR GROUP I COMPOUNDS*
CYLINDER I-A36
AcnvnY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(10.3)
3/14/87
(10.3)
(30.9)
4/07/87
(23.9)
(10.3)
4/07/87
(8.65)
(30.9)
4/30/87
(30.7)
(20.0)
4/07/87
(18.2)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/06/87
(10.8 + 1.0)
50
(11.1 + 1.1)
7/06/87
(23.3 + 0.7)
50
(22.5 + 0.6)
7/06/87
(7.58 + 0.2)
50
(7.60+0.2)
7/06/87
(30.4 + 1.3)
50
(29.1 + 1.3)
7/06/87
(22.2 + 1.5)
50
(21.5 + 1.5)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
MBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/06/87
(20.6 + 2.0)
(21.0 + 1.0)
50
(17.7 + 1.7)
(19.3 + 1.0)
7/06/87
(23.1+0.7)
(23.0+0.2)
50
(8.00+0.2)
(9.60 + 0.2)
7/06/87
(30.0 + 0.8)
(29.0 + 1.0)
50
(20.7 + 0.6)
(22.8 + 0.2)
7/06/87
(19.0+0.8)
(18.0 + 0.5)
50
(14.4+0.6)
(16.8+0.5)
7/06/87
(24.5 + 1.7)
(31.0 + 1.0)
50
NA
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RII analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
NA = Not Analyzed
A-84
-------
STABILITY STUDY KIR GROUP I COMPOUNDS*
CYLINDER I-A37
ACTIVITY
COMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(10.0)
3/04/87
(9.71)
(30.1)
4/07/87
(29.2)
(10.0)
4/07/87
(8.80)
(30.1)
4/30/87
(30.4)
(20.0)
4/07/87
(20.3)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/08/87
(9.83+0.9)
48
(10.1 + 1.0)
7/08/87
(30.8+0.9)
48
(29.6 + 0.8)
7/08/87
(10.7+0.3)
48
(10.8+0.3)
7/08/87
(30.9 + 1.4)
43
(30.1 + 1.3)
7/08/87
(22.6+1.6)
43
(22.0 + 1.5)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/08/87
(20.6+2.0)
(19.3 + 1.0)
48
(17.7 + 1.7)
(19.3 + 1.0)
7/08/87
NA
(9.60 + 0.2)
43
(8.00+0.2)
(9.60 + 0.2)
7/08/87
NA
(22.8 + 0.2)
43
(20.7+0.6)
(22.8+0.2)
7/08/87
(18.7+0.8)
(16.8 + 0.5)
43
(14.4 + 0.6)
(16.8 + 0.5)
7/08/87
NA
(16.1 + 1.0)
43
NA
(16.1+1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
NA = Not Analyzed
A-35
-------
STABILITY STUDY FOR GROUP I ODMPOUNES*
CYLINDER I-A38
ACTIVITY
(DMPOUND
Carbon tetra-
chloride
Chloroform
Perchloro-
ethylene
Benzene
Vinyl
Chloride
MANUFACTURER ANALYSIS
Theoretical
PPB
1st Analysis Date
PPB
(10.1)
3/03/87
(9.55)
(30.3)
4/06/87
(31.2)
(10.1)
4/06/87
(10.3)
(30.3)
4/06/87
(29.1)
(20.0)
4/06/87
(18.8)
KTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/08/87
(9.74 + 0.9)
61
(10.5 + 1.0)
7/08/87
(30.9 + 0.9)
61
(30.7 + 0.9)
7/08/87
(11.1 + 0.3)
61
(11.3+0.3)
7/08/87
(30.5 + 1.3)
61
(30.4 + 1.3)
7/08/87
(20.2 + 1.4)
61
(19.8 + 1.4)
KTI QUALITY (DNTRDL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/08/87
(21.2+2.0)
(19.3 + 1.0)
61
(17.6 + 1.7)
(19.3+1.0)
7/08/87
NA
(9.60 + 0.2)
61
(9.50 + 0.3)
(9.60 + 0.2)
7/08/87
NA
(22.8 + 0.2)
61
(22.7+0.6)
(22.8 + 0.2)
7/08/87
(19.1+0.8)
(16.8 + 0.5)
61
(16.6+0.7)
(16.8+0.5)
7/08/87
NA
(16.1 + 1.0)
61
(15.7 + 1.1)
(16.1 + 1.0)
*An NBS primary standard was used for calibration.
**Number of days after 1st KTI analysis.
***A different NBS primary standard vas analyzed as an internal quality control on each day of RTI
analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed
by GC/FID.
NA = Not Analyzed
A-86
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A1
ACTIVITY
Theoretical PPB
1st Analysis Date
• PPB
2nd Analysis Date
PPB
COMPOUND
Acetoni trile
(161)
3/05/84
(144)
4/03/84
(133)
Me thy 1
Ethyl Ketone
(164)
3/05/84
(167)
4/03/84
(168)
Trichloro-
e thy lene
(164)
3/05/84
(152)
4/03/84
(148)
1,2-Dichloro-
e thane
MANUFACTURER
(161)
3/05/84
(167)
4/03/84
(141)
Trichloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(149)
3/05/84
(152)
4/03/84
(143)
Bromome thane
(150)
3/07/84
(161)
4/04/84
(170)
Dichlorodi-
f luorome th-
ane (F-12)
(151)
3/07/84
(153)
4/04/84
(148)
1,2-Dlbro-
moe thane
(162)
3/05/84
(201)
4/03/84
(192)
1,1,1-
Trlchloro-
e thane
NC
NC
NC
RTI ANALYSIS*****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB
5/28/84 5/28/84 5/14/84
(145+10.2)t (194 + 10.7)t (147 + 7.1)
82
(130 + 9.1)t
302
(110 + 7.7)
449
(112 + 7.8)
750
on audit
901
(126 + 16.9)
82 98
(187 + 10.3)t (145 + 7.0)
302
(144 + 7.9)
449
(140 + 7.7)
750
on audit
901
(154 + 7.4)
287
(140 + 6.7)
452
(141 + 6.8)
775
on audit
901
(142 + 4.4)
5/14/84
(156 + 8.0)
99
(150 + 7.7)
302
(146 + 7.4)
452
(135 + 6.9)
771
on audit
901
(142 + 4.4)
5/14/84**
(130 + 4.4)t
98
(153 + 5.2)
287
(160 + 5.4)
452
(161 + 5.5)
775
on audit
901
(156 + 13.3)
5/14/84
(172 + 6.7)
98
(170 + 6.6)
287
(168 + 6.6)
452
(168 + 6.6)
775
on audi t
901
(176 _+ 7.5)
5/08/84**
(143 + 5.9)t
104
(168 + 6.9)
293
(173 + 7.1)
458
(164 + 6.7)
775
on audit
901
NA
5/08/84**
(157 + 6.4)t
104
(183 + 7.5)
293
(177 + 7.3)
458
(174 + 7.1)
771
on audit
901
(184 + 7.4)
NC
NC
NC
NC
765
on audit
901
NC
00
-J
(Continued)
*Calibratlon was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 6th analysis.
**Callbra tion was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis. No Quality Control with NBS primary
standards was performed during RTI 1st and 2nd analysis.
*****Sixth RTI analysis was performed using automated cryogenic preconcentration with cryofocuslng followed by GC/FID.
t = Questionable value.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A1
ACTIVITY
COMPOUND
Ace tonl trlle
Methyl
Ethyl Ketone
Trichloro-
e thy lene
1,2-Dichloro-
e thane
Trlchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dlchlorodl-
f luorome th-
ane (F-12)
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
ethane
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
5th Analysis Day
PPB
NBS Concen. PPB
6th Analysis Day
PPB
NBS Concen. PPB
302
(78.5 -f 5.5)
(82.7 + 9.6)
449
(85.2 + 6.0)
(82.7 -f 9.6)
750
(13.0 + 0.9)
(12.1 + 1.9)
901
(12.8 + 1.7)
(12.1 + 1.9)
302
.(132 + 7.3)
(137 + 6.0)
449
(130 + 7.2)
(137 + 6.0)
750
(16.0 + 0.9)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
287
(118 + 5.7)
(118 + 1.0)
452
(120 + 5.8)
(118 + 1.0)
775
(11.5 + 0.5)
(11.6 + 0.3)
901
(11.5 + 0.4)
(11.6 + 0.3)
302
(131 + 6.7)
(123 + 2.0)
452
(120 + 6.1)
(123 t 2.0)
771
(9.5 + 0.4)
287
(153 + 5.2)
(151 + 5.0)
452
(154 + 5.2)
(151 + 5.0)
775
(10.7 + 0.4)
(9.14 + 0.59) (11.3 + 0.6)
901
(8.90 + 0.3)
(9.14 + 0.6)
901
(10.8 + 1.0)
(11.3 + 0.6)
287
(190 + 7.4)
(193 + 3.0)
452
(190 + 7.4)
(193 + 3.0)
775
(20.4 + 0.8)
(23.0 + 0.6)
901
(17.5 + 0.7)
(23.0 + 0.6)
293
(112 + 4.6)
(116 + 4.0)
458
(119 + 4.9)
(116 _+ 4.0)
775
(10.6 + 0.4)
293
(149 + 6.1)
(150 + 2.0)
458
(132 j+ 5.4)
(150 + 2.0)
771
(9.70 + 0.4)
302
(149 + 7.5)
(147 + 3.0)
452
(139 + 7.0)
(147 + 3.0)
765
(11.8 + 0.6)
(9.41 + 0.37) (9.61+0.29) (11.9+0.3)
901
NA
(9.41 + 0.6)
901
(9.80 + 0.4)
(9.61 + 0.3)
901
(11.7 + 0.4)
(11.9 + 0.3)
CO
00
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 6th analysis.
**Callbration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis. No Quality Control with NBS primary
standards was performed during RTI 1st and 2nd analysis.
*****Sixth RTI analysis was performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
t = Questionable value.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR CROUP II COMPOUNDS*
CYLINDER I1-A2
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonltrile
(167)
3/16/84
(110)
4/03/84
(107)
Methyl
Ethyl Ketone
(169)
3/16/84
(140)
4/03/84
(146)
Trichloro-
ethylene
(169)
3/16/84
(135)
4/03/84
(144)
1,2-Dlchloro-
ethane
MANUFACTURER
(167)
3/16/84
(108)
4/03/84
(139)
Trichloro-
fluoro-
methane
(F-ll)
ANALYSIS
(149)
3/16/84
(147)
4/03/84
(141)
Broraoraethane
(150)
3/20/84
(163)
4/05/84
(165)
Dlchlorodi-
f luorometh-
ane (F-12)
(151)
3/20/84
(152)
4/05/84
(147)
1,2-Dibro-
moethane
(168)
3/16/84
(175)
4/03/84
(184)
1,1,1-
Trichloro-
ethane
NC
NC
NC
RTI ANALYSIS
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB
5/28/84
(124 + 8.7)
5/28/84
(161 + 8.9)
82 82
(146 + 10.2)t (178 + 9.8)t
302
(107 + 7.5)
449
(109 + 7.6)
749
. (119 + 8.3)
on audit
302
(130 + 7.2)
449
(128 + 7.0)
749
(159 + 8.4)
on audit
5/14/84
(146 + 7.0)
98
(143 + 6.9)
287
(141 + 6.8)
452"
(139 + 6.7)
777
(141 + 6.9)
on audit
5/14/84
(158 + 8. 1)
98
(150 + 7.7)
302
(136 + 6.9)
452
(139 + 7. 1)
777
(156 + 8.1)
on audit
5/14/84**
(129 + 4.4)t
98
(152 + 5.2)
287
(158 + 5.4)
452
(158 + 5.4)
777
(163 + 5.1)
on audit
5/14/84
(169 + 6.6)
98
(167 + 6.5)
287
(165 + 6.4)
452
(164 + 6.4)
777
(178 + 7.1)
on audit
5/08/84**
' (141 + 5.8)t
104
(166 + 6.8)
293
(167 + 6.8)
458
(148 + 6.1)
783
(163 + 6.3)
on audit
5/08/84**
(163 + 6.7)t
104
(189 + 7.7)
293
(186 + 7.6)
458
(164 + 6.7)
783
(197 + 8.1)
on audit
NC
NC
NC
NC
NC
NC
CO
VD
(Continued)
•Calibration was performed using permeation devices unless otherwise specified.
**Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis unless otherwise Indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not Included in this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A2
ACTIVITY
COMPOUND
Acetonitrlle
Methyl
Ethyl Ketone
Trlchloro-
e thy lene
1,2-Dlchloro-
e thane
Trichloro-
f luoro-
tne thane
(F-ll)
Bromotne thane
Dlchlorodl-
f luorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e thane
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
5th Analysis Day
PPB
NBS Concen. PPB
6th Analysis Day
PPB
NBS Concen. PPB
302
(78.5 + 5.5)
(82.7 + 9.6)
449
(85.2 + 6.0)
(82.7 + 9.6)
749
(13.6 + 0.9)
(12.1 + 1.9)
901
(12.8 +1.7)
(12.1 + 1.9)
302
(132 + 7.3)
(137 + 6.0)
449
(135 + 7.4)
(137 + 6.0)
749
(16.1 + 0.9)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
287
(118 + 5.7)
(118 + 1.0)
452
(120 + 5.8)
(118 + 1.0)
777
(119 + 6.0)
(118 + 1.0)
901
(11.5 + 0.4)
(11.6 + 0.3)
302
(131 + 6.7)
(123 ± 2.0)
452
(120 + 6.1)
(123 + 2.0)
777
(126 + 7.0)
(123 + 2.0)
901
(8.90 + 0.3)
(9.14 + 0.6)
287
(153 + 5.2)
(151 + 5.0)
452
(154 + 5.2)
(151 + 5.0)
777
(157 + 5.0)
(151 + 5.0)
901
(10.8 + 1.0)
(11.3 + 0.6)
287
(190 + 7.4)
(193 + 3.0)
452
(190 + 7.4)
(193 + 3.0)
777
(180 + 7.0)
(193 + 3.0)
901
(17.5 + 0.7)
(23.0 + 0.6)
293
(112 + 4.6)
(116 + 4.0)
458
(119 + 4.9)
(116 + 4.0)
783
(116 + 4.0)
(116 + 4.0)
901
NA
(9.41 + 0.6)
293
(149 + 6.1)
(150 + 2.0)
458
(132 + 5.4)
(150 + 2.0)
783
(158 + 7.0)
(150 + 2.0)
901
(9.80 + 0.4)
(9.61 + 0.3)
302
(149 + 7.5)
(147 + 3.0)
452
(139 + 7.0)
(147 + 3.0)
783
(154 + 8.0)
(147 jf 3.0)
901
(11.7 + 0.4)
(11.9 + 0.3)
Calibration was performed using permeation devices unless otherwise specified.
"Calibration was performed using stainless steel sphere dilution method.
***Number of aays after 1st RTI analysis date.
****NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis unless otherwise indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not Included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A3
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonitrile
(166)
3/16/84
(120)
4/03/84
(104)
Methyl
Ethyl Ketone
(168)
3/16/84
(133)
4/03/84
(138)
Trlchloro-'
ethylene
(168)
3/16/84
(142)
4/03/84
(151)
1 , 2-Dlchloro-
e thane
MANUFACTURER
(166)
3/16/84
(111)
4/03/84
(143)
Trichloro-
fluoro-
methane
(F-ll)
ANALYSIS
(149)
3/16/84
(154)
4/03/84
(144)
Bromome thane
(150)
3/07/84
(169)
4/05/84
(172)
Dichlorodi-
f luorometh-
ane (F-12)
(151)
3/07/84
(161)
4/05/84
(153)
1,2-Dibro-
moethane
(167)
3/16/84
(205)
4/03/84
(208)
1,1,1-
Trichloro-
ethane
NC
NC
NC
RT1 ANALYSIS
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB
5/28/84
(107 + 7.5)
82
(146 + 10.2)
302
(106 + 7.4)
on audit
749
(140 + 9.9)
on audit
5/28/84
(151 + 8.3)
82
(170 + 9.4)
302
(123 + 6.8)t
on audit
749
(159 + 8.4)
on audit
5/14/84
(147 + 7.1)
98
(145 + 7.0)
287
(142 + 6.8)
on audit
777
(143 + 7.0)
on audit
5/14/84
(163 + 8.3)
98
(157 + 8.0)
302
(139 + 7.1)
on audit
777
(161 + 8.3)
on audit
5/14/84**
(131 + 4.5)t
98
(155 + 5.3)
287
(161 + 5.5)
on audit
777
(168 + 5.3)
on audit
5/14/84
(173 + 6.7)
98
(170 + 6.6)
287
(168 + 6.6)
on audit
777
(178 + 7.1)
on audit
5/08/84**
(144 + 5.9)t
104
(170 + 7.0)
293
(170 + 7.0)
on audit
783
(168 + 6.5)
on audit
5/08/84**
(165 + 6.8)t
104
(196 + 8.0)
293
(192 + 7.9)
on audit
783
(206 + 8.5)
on audit
NC
NC
NC
NC
NC
NC
(Continued)
*Calibratlon was performed using permeation devices unless otherwise specified.
"Calibration was performed using stainless steel sphere dilution method.
***Nuraber of days after 1st RTI analysis date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis unless otherwise indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not Included in this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A3
ACTIVITY
COMPOUND
Acetoni trlle
Me thy 1
Ethyl Ketone
Trlchloro-
e thy lene
1,2-Dichloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodi-
f luorometh-
ane (F-12)
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
ethane
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
5th Analysis Day
PPB
NBS Concen. PPB
6th Analysis Day
PPB
NBS Concen. PPB
302
(78.5 + 5.5)
(82.7 + 9.6)
449
(85.2 + 6.0)
(82.7 _+ 9.6)
749
(13.6 + 0.9)
(12.1 + 1.9)
901
(12.8 + 1.7)
(12.1 + 1.9)
302
(132 + 7.3)
(137 _+ 6)
449
(135 + 7.4)
(137 + 6)
749
(16.1 + 0.8)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
287
(118 + 5.7)
(118 + I)
452
(120 + 5.8)
(118 + 1)
777
(119 + 6)
(118 + 1)
901
(11.5 + 0.4)
(11.6 + 0.3)
302
(131 + 6.7)
(123 + 2)
452
(120 + 6.1)
(123 + 2)
777
(126 + 7)
(123 + 2)
901
(8.90 + 0.3)
(9.14 + 0.6)
287
(153 + 5.2)
(151 + 5)
452
(154 + 5.2)
(151 + 5)
777
(157 + 5)
(151 + 5)
901
(10.8 + 1.0)
(11.3 + 0.6)
287
(190 + 7.4)
(193 + 3)
452
(190 + 7.4)
(193 + 3)
777
(180 + 7)
(193 _+ 3)
901
(17.5 + 0.7)
(23.0 + 0.6)
293
(112 + 4.6)
(116 + 4)
458
(119 + 4.9)
(116 + 4)
783
(116 + 4)
(116 + 4)
901
NA
(9.41 + 0.6)
293
(149 + 6.1)
(150 + 2)
458
(132 + 5.4)
(150 + 2)
783
(158 + 7)
(150 jf 2)
901
(9.80 + 0.4)
(9.61 _+ 0.3)
0
(149 + 7.5)
(147 + 3)
452
(139 + 7.0)
(147 + 3)
783
(154 + 8)
(147 + 3)
901
(11.7 + 0.4)
(11.9 + 0.3)
*CalibratIon was performed using permeation devices unless otherwise specified.
"Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis unless otherwise indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not incluoeo in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A4
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
•
Acetonitrile
(15.4)
3/15/84
(14.0)
4/02/84
(14.0)
Methyl
Ethyl Ketone
(15.8)
3/15/84
(16.3)
4/02/84
(16.2)
Trichloro-
ethylene
(15.7)
3/15/84
(16.3)
4/02/84
(17.5)
1,2-Dichloro-
e thane
MANUFACTURER
(15.5)
3/15/84
(10.7)
4/02/84
(11.5)
Trichloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(14.9)
3/21/84
(11.5)
4/05/84
(13.3)
Bromome thane
(15.0)
3/21/84
(11.9)
4/05/84
(12.5)
Dichlorodi-
fluorometh-
ane (F-12)
(15.1)
3/21/84
(15.0)
4/05/84
(14.6)
1,2-Dibro-
moe thane
(15.7)
3/15/84
(17.8)
4/02/84
(16.1)
1.1,1-
Trichloro-
ethane
' (15.3)
3/15/84
(11.6)
4/02/84
(15.3)
RTI ANALYSIS
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB .
5/24/84
(16.2 + 1.1)
87
(17.6 + 1.2)
on audit
454
(15.9 + 1.1)
749
(14.9 + 1.1)
on audit
5/24/84
(20.2 + 1.1)
87
(19.4 + 1.1)
on audit
454
(19.0 + 1.0)
749
(18. 1 + 1.0)
on audit
5/14/84
(14.6 + 0.7)
98
(14.7 + 0.7)
on audit
449
(14.2 + 0.7)
772
(13.2 + 0.7)
on audit
5/14/84
(15.3 + 0.8)
93
(14.4 + 0.7)
on audit
443
(15.5 + 0.8)
772
(16.7 + 0.9)
on audit
5/14/84 5/14/84
(13.1 + 0.4)** (15.2 + 0.6)
98
(15.1 + 0.5)
on audit
449
(16.0 + 0.5)
772
(15.9 + 0.5)
on audit
98
(15.4 * 0.6)
on audit
449
(15.0 + 0.6)
772
(12.6 + 0.5)
on audit
5/14/84**
(13.7 + 0.6)t
98
(16.3 + 0.7)
on audit
449
(15.6 + 0.6)
772
(15.5 + 0.6)
on audit
5/14/84**
(11.3 + 0.5)t
98
(16.5 + 0.7)
on audit
449
(14.5 + 0.6)
772
(16.2 + 0.7)
on audit
5/20/84
(16.9 + 0.8)t
93
(14.5 + 0.7)
on audit
443
(13.3 + 0.7)
766
(16.3 + 0.9)
NC
VO
OJ
*Calibration was performed using permeation devices unless otherwise specified.
**Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis unless otherwise Indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not Included in this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A4
ACTIVITY
COMPOUND
Ace tonl trlle
Me thy 1
Ethyl Ketone
Trichloro-
ethy lene
1,2-Dlchloro-
e thane
Trlchloro-
fluoro-
me thane
(F-ll)
Bromome thane
Dlchlorodl-
f luorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e tha ne
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
Sth Analysis Day
PPB
NBS Concen. PPB
6th Analysis Day
PPB
NBS Concen. PPB
309
U4.1 + 1.0)
(12.1 + 1.9)
454
(14.0 + 1.0)
(12.1 + 1.9)
749
(13.0 + 0.9)
(12.1 + 1.9)
901
(12.8 + 1.7)
(12.1 + 1.9)
309
(16.9 + 0.9)
(15.8 + 2.0)
454
(16.9 + 0.9)
(15.8 + 2.0)
749
(16.1 + 0.8)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
297
(10.9 + 0.5)
(11.6 + 0.3)
449
(11.6 + 0.6)
(11.6 + 0.3)
772
(10.9 + 0.5)
(11.6 + 0.3)
901
(11.5 + 0.4)
(11.6 + 0.3)
310
(8.8 + 0.4)
(9. 14 + 0.59)
443
(9.1 + 0.5)
(9. 14 + 0.59)
772
(9.5 + 0.5)
(9.14 + 0.59)
901
(8.90 + 0.3)
(9.14 + 0.6)
297
(10.7 + 0.4)
(11.3 + 0.6)
449
(11.0 + 0.4)
(11.3 + 0.6)
772
(10.6 + 0.3)
(11.3 + 0.6)
901
(10.8 + 1.0)
(11.3 + 0.6)
297
(19.4 + 0.8)
(23.0 + 0.6)
449
(19.3 + 0.8)
(23.0 + 0.6)
772
(19.9 + 0.8)
(23.0 + 0.6)
901
(17.5 + 0.7)
(23.0 + 0.6)
297
(8.2 _+ 0.3)
(9.41 + 0.37)
449
(8.4 + 0.3)
(9.41 + 0.37)
772
(10.8 + 0.4)
(9.41 + 0.37)
901
NA
(9.41 + 0.6)
297
(9.5 + 0.4)
(9.61 + 0.29)
449
(8.8 + 0.4)
(9.61 + 0.29)
772
(9.7 + 0.4)
(9.61 + 0.29)
901
(9.80 + 0.4)
(9.61 + 0.3)
310
(11.4 + 0.6)
(11.9 + 0.3)
443
(11.3 + 0.6)
(11.9 + 0.3)
766
(11.8 + 0.6)
(11.9 + 0.3)
901
(11.7 + 0.4)
(11.9 + 0.3)
*Calibratlon was performed using permeation devices unless otherwise specified.
**Calibratlon was performed using stainless steel sphere dilution method.
***Number of oays after 1st RTI analysis date.
****NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis unless otherwise Indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.'
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A5
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonltrile
(15.5)
3/14/84
(8.90)
4/02/84
(8.80)
Methyl
Ethyl Ketone
(16.0)
3/14/84
(7.80)
4/02/84
(7.40)
Trichloro-
ethylene
(15.9)
3/14/84
(16.9)
4/02/84
(18.2)
1,2-Dlchloro-
ethane
MANUFACTURER
(15.7)
3/14/84
(11.2)
4/02/84
(11.8)
Trichloro-
fluoro-
me thane
(F-ll)
ANALYSIS
(15.0)
3/21/84
(9.60)
4/05/84
(15.6)
Broraomethane
(15.0)
3/21/84
(11.3)
4/05/84 •
(12.7) '
Dichlorodl-
fluorometh-
ane (F-12)
(15.0)
3/21/84
(16.0)
4/05/84
(15.1)
1,2-Dibro-
moe thane
(15.9)
3/14/84
(18.2)
4/02/84
(16.0)
1,1.1-
Trichloro-
ethane
(15.5)
3/14/84
(11.3)
4/02/84
(15.2)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB
5/24/84
(13.4 + 0.9)t
87
(13.8 + 1.0)t
309
(10.3 + 0.7)
454
(10.8 + 0.8)
749
(13.1 + 0.9)
on audit
5/24/84
(10.6 + 0.6)t
87
(8.50 + 0.5)
309
(8.00 + 0.4)
454
(9.30 + 0.6)
749
(12.7 + 0.7)
on audit
5/14/84
(15.1 + 0.7)
98
(15.1 ± 0.7)
on audit
449
(15.3 + 0.7)
773 .'
(15.1 + 0.7)'
on audit
5/20/84
(14.6 + 0.7)
93
(14.7 + 0.7)
310
(14.2 + 0.7)
443
(15.4 + 0.8)
767
(14.2 + 0.7)
on audit
5/14/84**
(13.5 + 0.5)t
98
(15.5 + 0.5)
on audit
449
(16.3 + 0.6)
773
(16.3 + 0.5)
on audit
5/14/84
(15.5 _+ 0.6)
98
(15.4 + 0.6)
on audit
449
(14.6 ± 0.6)
773
(17.4 + 0.7)
on audit
5/14/84**
(13.8 + 0.6)t
98
(16.7 + 0.7)
on audit
449
(16.3 + 0.7)
773
(16.4 + 0.6)
on audit
5/20/84**
(16.2 + 0.7)
98
(16.8 + 0.7)
on audit
449
(14.1 + 0.6)
773
(15.0 + 0.6)
on audit
5/20/84
(16.8 + 0.8)t
98
(14.8 + 0.7)
310
(14. 1 +0.7)
443
(13.9 + 0.7)
767
(15.7 -f 0.8)
NC
(Continued)
*Calibration was performed using permeation devices unless otherwise specified.
**Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis unless otherwise Indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not included in this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A5
ACTIVITY
COMPOUND
Acetonitrlle
Methyl
Ethyl Ketone
Trichloro-
e thylene
1,2-Dlchloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dlchlorodi-
fluorome th-
ane (F-12)
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
e thane
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
Ath Analysis Day
PPB
NBS Concen. PPB
5th Analysis Day
PPB ,
NBS Concen. PPB
6 tli Analysis Day
PPB
NBS Concen. PPB
309
(14.1 + 1.0)
(12.1 + 1.9)
454
(14.0 + 1.0)
(12.1 + 1.9)
749
(13.0 + 0.9)
(12.1 + 1.9)
901
(12.8 + 1.7)
(12.1 _+ 1.9)
309
(16.9 + 0.9)
(15.8 + 2.0)
454
(16.9 + 0.9)
(15.8 + 2.0)
749
(16.1 + 0.8)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
297
(10.9 + 0.5)
(11.6 + 0.3)
449
(11.6 + 0.6)
(11.6 + 0.3)
773
(11.5 + 0.6)
(11.6 + 0.3)
901
(11.5 + 0.4)
(11.6 + 0.3)
310
(8. 80.+ 0.4)
(9.14 + 0.6)
. 443
(9.10 + 0.5)
(9.14 + 0.6)
767
(9.80 _+ 0.5)
(9.14 + 0.6)
901
(8.90 + 0.3)
(9.14 + 0.6)
297
(10.7 + 0.4)
(11.3 + 0.6)
449
(11.0 + 0.4)
(11.3 + 0.6)
773
(10.7 + 0.3)
(11.3 + 0.6)
901
(10.8 + 1.0)
(11.3 + 0.6)
297
(19.4 + 0.8)
(23.0 + 0.6)
449
(19.3 + 0.8)
(23.0 + 0.6)
773
(20.4 + 0.8)
(23.0 + 0.6)
901
(17.5 + 0.7)
(23.0 + 0.6)
297
(8.20 + 0.3)
(9.41 + 0.4)
449
(8.40 + 0.3)
(9.41 + 0.4)
773
(10.6 + 0.4)
(9.41 + 0.6)
901
NA
(9.41 + 0.6)
297
(9.50 + 0.4)
(9.61 + 0.3)
449
(8.80 + 0.4)
(9.61 + 0.3)
773
(10.2 _+ 0.4)
(9.61 + 0.3)
901
(9.80 + 0.4)
(9.61 + 0.3)
310
(11.4 + 0.6)
(11.9 + 0.3)
443
(11.3 + 0.6)
(11.9 + 0.3)
767
(11.7 + 0.6)
(11.9 + 0.3)
901
(11.7 + 0.4)
(11.9 + 0.3)
vO
ON
alibratlon was performed using permeation devices unless otherwise specified.
"Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis unless otherwise indicated. No Quality Control with NBS
primary standards was performed during RTI 1st and 2nd analysis.
t = Questionable value.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed. . ..
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A6
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Ace tonltrlle
(15.9)
3/14/84
(8.60)
3/30/84
(8.00)
Methyl
Ethyl Ketone
(16.3)
3/14/84
(7.00)
3/30/84
(7.10)
Trichloro-
e thylene
(16.2)
3/14/84
(15.8)
3/30/84
(18.3)
1,2-Dlchloro-
e thane
MANUFACTURER
(16.0)
3/ 14/84
(11.4)
3/30/84
(12.7)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(15.0)
3/20/84
(10.8)
4/06/84
(13.9)
Bromome thane
(15.0)
5/14/84
(13.3)
8/19/84
(12.2)
Dlchlorodl-
f luorome th-
ane (F-12)
(15.0)
3/20/84
(15.5)
4/06/84
(14.2)
1,2-Dlbro-
moe thane
(16.2)
3/14/84
(17.5)
3/30/84
(18.2)
1,1,1-
Trlchloro-
e thane
(15.8)
3/14/84
(11.1)
3/30/84
(14.4)
RTI ANALYSIS*****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
5th Analysis Day***
PPB
6th Analysis Day***
PPB
5/24/84
(12.0 + 0.8)
87
(11.6 + 0.8)
309
(12.6 + 0.9)
454
(12.2 + 0.8)
749
(13.1 + 0.9)
901
(12.8 + 1.7)
5/24/84
(7.50 + 0.4)
87
(6.70 + 0.4)
309
(7.30 + 0.4)
454
(7.50 + 0.4)
749
(10.9 + 0.6)
901
(7.50 + 0.4)
5/14/84
(15.6 + 0.7)
98
(15.4 + 0.7)
on audit
449
(15.1 + 0.7)
772
(14.4 + 0.7)
901
(15.6 + 0.5)
5/20/84
(14.2 + 0.7)
93 .
(15.7 + 0.8)
310
(14.2 + 0.7)
443
(15.8 + 0.8)
766
(12.5 -1- 0.6)
901
(14.8 + 0.5)
5/14/84**
(13.4 + 0.5)
98
(15.4 + 0.5)
on audit
449
(16.2 + 0.5)
772
(15.6 + 0.5)
901
(16.9 + 1.4)
5/14/84
(15.2 + 0.6)
98
(14.9 + 0.6)
on audit
449
(14.0 + 0.5)
772
(10.4 + 0.4)
901
(13.0 + 0.6)
5/14/84**
(13.6 + 0.6)
98
(16.6 + 0.7)
on audit
449
(16.0 + 0.7)
772
(16.4 + 0.6)
901
NA
5/14/84**
(16.6 + 0.7)
98
(16.0 + 0.7)
on audit
449
(11.8 + 0.5)
772
(12.1 +0.5)
901
(13.6 + 0.5)
5/20/84
(17.4 + 0.9)t
93
(15.3 + 0.8)
310
(14.3 + 0.7)
443
(14.0 + 0.7)
766
(14.8 + 0.8)
901
(14.4 + 0.4)
(Continued)
'Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 6th analysis.
**Ca libra tion was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis. No Quality Control with NBS primary
standards was performed during RTI 1st and 2nd analysis.
*****Slxth RTI analysis was performed using automated cryogdnic preconcentratlon with cryofocuslng followed by GC/FID.
t = Questionable value.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A6
ACTIVITY
COMPOUND
Ace ton! trile
Methyl
Ethyl Ketone
Trichloro-
e thylene
1,2-DIchloro-
e thane
Trtchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodl-
fluorometh-
ane (F-12)
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
e thane
RTI QUALITY CONTROL****
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
5th Analysis Day
PPB
NBS Concen. PPB
6th Analysis Day
PPB
NBS Concen. PPB
309
(14.1 + 1.0)
(12.1 + 1.9)
454
(14.0 + 1.0)
(12 1 -f 1.9)
749
(13.0 + 0.9)
(12.1 + 1.9)
901
(12.8 + 1.7)
(12.1 + 1.9)
309
(16.9 + 0.9)
(15.8 + 2.0)
454
(16.9 + 0.9)
(15.8 + 2.0)
749
(16.1 •*• 0.8)
(15.8 + 2.0)
901
(17.0 + 0.8)
(15.8 + 2.0)
297
(10.9 + 0.5)
(11.6 + 0.3)
449
(11.6 + 0.6)
(11.6 + 0.3)
772
(10.9 + 0.5)
(11.6 + 0.3)
901
(11.5 + 0.4)
(11.6 + 0.3)
310
(8.80 + 0.4)
(9.14 + 0.6)
443
(9.10 + 0.5)
(9. 14 + 0.6)
766
(9.50 + 0.5)
(9.14 + 0.6)
901
(8.90 + 0.3)
(9.14 + 0.6)
297
(10.7 + 0.4)
(11.3 + 0.6)
449
(11.0 + 0.4)
(11.3 + 0.6)
772
(10.6 + 0.3)
(11.3 + 0.6)
901
(10.8 + 0.9)
(11.3 + 0.6)
297
(19.4 + 0.8)
(23.0 + 0.6)
449
(19.3 + 0.8)
(23.0 + 0.6)
772
(19.9 + 0.8)
(23.0 + 0.6)
901
(17.5 + 0.7)
(23.0 + 0.6)
297
(8.20 + 0.3)
(9.41 + 0.4)
449
(8.40 + 0.3)
(9.41 + 0.4)
772
(10.8 + 0.4)
(9.41 + 0.6)
901
NA
(9.41 + 0.6)
297
(9.50 + 0.4)
(9.61 + 0.3)
449
(8.80 ± 0.4)
(9.61 _+ 0.3)
772
(9.70 + 0.4)
(9.61 + 0.3)
901
(9.80 + 0.4)
(9.61 + 0.3)
310
(11.4 + 0.6)
(11.9 + 0.3)
443
(11.3 + 0.6)
(11.9 + 0.3)
766
(11.8 + 0.6)
(11.9 + 0.3)
901
(11.7 + 0.4)
(11.9 + 0.3)
I
.0
30
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 6th analysis.
**Calibra tlon was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis. No Quality Control with NBS primary
standards was performed during RTI 1st and 2nd analysis.
*****Slxth RTI analysis was performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
t *= Questionable value.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A7
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Ace tonltrlle
(10.0)
11/13/84
(11.7)
1/02/85
(8.70)
Methyl
Ethyl Ketone
(10.0)
11/13/84
(9.30)
1/02/85
(9.10)
Trichloro-
ethylene
(10.0)
11/13/84
(9.10)
1/02/85
(9.30)
1,2-Dlchloro-
e thane
MANUFACTURER
(12.0)
11/13/84
(8.60)
1/02/85
(8.30)
Trlchloro-
f luoro-
me thane
(F-H)
ANALYSIS
(10.1)
12/12/84
(9.90)
1/18/85
(8.30)
Bromome thane
(10.4)
12/12/84
(9.50)
1/18/85
(8.10)
Dichlorodi-
f luorome th-
ane (F-12)
(9.90)
12/12/84
(8.70)
1/18/85
(9.50)
1,2-Dibro-
moe thane
(10.0)
11/13/84
(10.4)
1/02/85
(10.7)
1,1,1-
Trl'chloro-
e thane
(10.0)
11/13/84
(10.0)
1/02/85
(10.4)
RTI ANALYSIS
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/29/85
(7.90 + 0.6)
on audit
439
(9.30 + 0.7)
emp ty
3/29/85
(9.60 + 0.5)
on audit
439
(12.7 + 0.7)
empty
3/07/85
(9.00 + 0.4)
on audit
474
(8.60 + 0.4)
empty
3/15/85
(9.80 + 0.5)
on audit
466
(10.5 + 0.5)
empty
3/07/85
(9.40 + 0.3)
on audit
474
(9.40 + 0.3)
empty
3/07/85
(10.8 + 0.4)
on audit
474
(10. I + 0.4)
empty
3/07/85
(9.90 + 0.4)
on audit
474
(10.6 + 0.4)
empty
3/07/85
(10.2 + 0.4)
on audit
474
(9.30 + 0.4)
empty
3/15/85
(10.1 + 0.5)
on audit
466
(8.50 + 0.4)
empty
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3/29/85
(14.1 + 1.0)
(12.1 + 1.9)
147
(12.0 + 0.8)
(12.1 + 1.9)
439
(13.0 + 0.9)
(12.1 -f 1.9)
749
(14.0 + 1.0)
(12.1 + 1.9)
3/29/85
(16.9 + 0.9)
(15.8 + 2.0)
147
(14.1 + 0.8)
(15.8 + 2.0)
439
(16.1 + 0.8)
(15.8 + 2.0)
749
(16.9 + 0.9)
(15.8 + 2.0)
3/07/85
(10.9 + 0.5)
(11.6 + 0.3)
152
(11.6 + 0.6)
(11.6 + 0.3)
474
(10.9 + 0.5)
(11.6 + 0.3)
772
(11.6 + 0.5)
(11.6 + 0.3)
3/15/85
(9.30 + 0.5)
(9.14 + 0.6)
144
(9.10 + 0.5)
(9.14 + 0.6)
466
(9.50 + 0.5)
(9.14 + 0.6)
766
(9.10 + 0.5)
(9.14 + 0.6)
3/07/85
(10.7 + 0.4)
(11.3 + 0.6)
152
(11.0 + 0.4)
(11.3 + 0.6)
474
(10.6 + 0.3)
(11.3 + 0.6)
722
(11.0 + 0.4)
(11.3 + 0.6)
3/07/85
(19.4 + 0.8)
(23.0 + 0.6)
152
(19.3 + 0.8)
(23.0 + 0.6)
474
(19.9 + 0.8)
(23.0 + 0.6)
722
(19.3 + 0.8)
(23.0 + 0.6)
3/07/85
(8.20 + 0.3)
(9.41 + 0.4)
152
(8.40 + 0.3)
(9.41 + 0.4)
474
(10.8 + 0.4)
(9.41 + 0.6)
722
(8.40 + 0.3)
(9.41 + 0.4)
3/07/85
(9.50 + 0.4)
(9.61 + 0.3)
152
(8.80 + 0.4)
(9.61 + 0.3)
474
(9.70 + 0.4)
(9.61 + 0.3)
722
(9.50 + 0.4)
(9.61 + 0.3)
3/15/85
(11.9 + 0.6)
(11.9 + 0.3)
144
(11.3 + 0.6)
(11.9 + 0.3)
466
(11.8 + 0.6)
(11.9 + 0.3)
722
(11.4 + 0.6)
(11.9 + 0.3)
*Callbration was performed using permeation devices unless otherwise specified.
"Calibration was performed using stainless steel sphere dilution method.
***Number of days after 1st RTI analysts date.
****NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis
unless otherwise Indicated.
NC
This compound was not Included in this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A8
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonitrile
(10.0)
11/06/84
(8.40)
12/28/84
(H.O)
Methyl
Ethyl Ketone
(10.0)
11/06/84
(9.40)
12/28/84
(9.20)
Trichloro-
e thylene
(10.0)
11/06/84
(9.30)
12/28/84
(9.40)
1,2-Dlchloro-
e thane
MANUFACTURER
. (10.0)
11/06/84
(8.70)
12/28/84
(8.70)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(10.1)
12/11/84
(9.80)
1/15/85
(11.9)
Bromome thane
(10.0)
12/11/84
(8.70)
1/15/85
(9.20)
Dichlorodi-
£ luorome th-
ane (F-12)
(9.90)
12/11/84
(9.20)
12/28/84
(9.60)
1,2-Dibro-
moe thane
(10.0)
11/06/84
(10.5)
12/28/84
(11.2)
1,1,1-
Trlchloro-
e thane
(10.0)
11/06/84
(10.3)
1/02/85 .
(10.6)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/29/85
(10.7 + 0.7)
147
(10.1 + 0.7)
442
(10.2 + 0.7)
852
NA
3/29/85
(9.60 + 0.5)
147
(9.00 + 0.5)
442
(9.70 -f 0.5)
852
(8.80 + 0.4)
3/07/85
(9.20 + 0.4)
152
(9.50 + 0.5)
474
(8.90 + 0.4)
852
(10.5 + 0.3)
3/15/85
(10.3 + 0.5)
144
(8.50 + 0.4)
466
(12.6 + 0.7)
852
(10.4 + 0.3)
3/07/85
. (9.60 + 0.3)
152
(9.70 + 0.3)
474
(10.3 + 0.3)
852
(10.0 + 0.9)
3/07/85
(10.6 + 0.4)
152
(11.4 + 0.4)
474
(11.0 + 0.4)
852
(11.4 + 0.5)
3/07/85
(9.90 + 0.4)
152
(10.5 + 0.4)
474
(11.8 + 0.5)
852
NA
3/07/85
(10.2 + 0.4)
152
(8.50 + 0.3)
474
(10.1 + 0.4)
852
NA
3/15/85
(10.1 + 0.5)
144
(9.40 + 0.5)
466
(10.5 + 0.6)
852
(10.0 + 0.3)
o
o
*Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard w<
**Fourth analysis was performed using automated cryogenic preconcentra tion with cryof ocusing.
***Number of days after 1st RTI analysts date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
NC = This compound was not Included in this cylinder.
NA = Not Aualy ed.
(Continued)
s used for calibration for 4th analysis.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A8
ACTIVITY
COMPOUND
Acetonl trlle
Methyl
Ethyl Ketone
Trlchloro-
ethylene
1,2-Dlchloro-
e thane
Trlchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodl-
f luorome th-
ane (F-12)
1.2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3/29/85
(14.1 + 1.0)
(12.1 + 1.9)
147
(12.0 + 0.8)
(12.1 + 1.9)
442
(13.6 + 0.9)
(12.1 + 1.9)
852
(13.2 ± 1.8)
(12.1 + 1.9)
3/29/85
(16.9 + 0.9)
(15.8 + 2.0)
147
(14.1 + 0.8)
(15.8 + 2.0)
442
(16.0 + 0.8)
(15.8 + 2.0)
852
(17.2 + 0.8)
(15.8 + 2.0)
3/07/85
(10.9 + 0.5)
(11.6 + 0.3)
152
(11.6 + 0.6)
(11.6 + 0.3)
474
(10.9 + 0.5)
(11.6 + 0.3)
852
(11.7 + 0.4)
(11.6 + 0.3)
3/15/85
(9.30 + 0.5)
(9.14 + 0.6)
144
(9.10 + 0.5)
(9.14 + 0.6)
466
(9.50 + 0.5)
(9.14 + 0.6)
852
(9.40 + 0.3)
(9.14 + 0.6)
3/07/85
(10.7 + 0.4)
(11.3 + 0.6)
152
(11.0 + 0.4)
(11.3 + 0.6)
474
(10.6 4- 0.3)
(11.3 + 0.6)
852
(11.4 + 1.0)
(11.3 + 0.6)
3/07/85
(19.4 + 0.8)
(23.0 + 0.6)
152
(19.3 + 0.8)
(23.0 + 0.6)
474
(19.9 + 0.8)
(23.0 + 0.6)
852
(18.6 + 0.8)
(23.0 + 0.6)
3/07/85
(8.20 + 0.3)
(9.41 + 0.4)
152
(8.40 + 0.3)
(9.41 + 0.4)
474
(10.8 + 0.4)
(9.41 + 0.6)
852
NA
(9.41 + 0.6)
3/07/85
(9.50 + 0.4)
(9.61 ± 0.3)
152
(8.80 + 0.4)
(9.61 + 0.3)
474
(9.70 + 0.4)
(9.61 + 0.3)
852
(10.6 + 0.4)
(9.61 + 0.3)
3/15/85
(11.9 + 0.6)
(11.9 + 0.3)
144
(11.3 + 0.6)
(11.9 + 0.3)
466
(11.8 + 0.6)
(11.9 + 0.3)
852
(12.0 + 0.4)
(11.9 + 0.3)
'Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
"Fourth analysis was performed using automated cryogenic preconcentra tlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A9
ACTIVITY
Theoretical PPB
Is t Analys Is Da te
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonl trlle
(10.0)
11/07/84
(8.40)
12/31/84
(8.80)
Methyl
Ethyl Ke tone
(10.0)
11/07/84
(9.20)
12/31/84
(9.00)
Trichloro-
e thy lene
(10. 0)
11/07/84
(9.10)
12/31/84
(9.10)
1,2-Dichloro-
e thane
MANUFACTURER
(10.0)
11/07/84
(8.10)
12/31/84
(8.50)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(10.1)
12/01/84
(11.8)
1/15/85
Ul. 9)
Bromome thane
(10.2)
12/01/84
(8.90)
1/15/85
(8.40)
Dichlorodl-
f luorome th-
ane (F-12)
(9.90)
12/01/84
(9.40)
1/15/85
(12.1)
1,2-Dibro-
moe thane
(10. 0)
11/07/84
(10.4)
12/31/84
(10.6)
1,1,1-
Trichloro-
e thane
(10.0)
11/07/84
(10.2)
12/31/85
(10.4)
RTI ANALYSIS**
Is t Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/29/85
(10.7 + 0.7)
147
(10. 1 + 0.7)
443
(10.2 + 0.7)
852
NA
3/29/85
(9.60 + 0.5)
147
(8.90 + 0.5)
443
(11.3 + 0.6)
852
(8.20 + 0.4)
3/07/85
(9.00 + 0.4)
152
(9.40 + 0.5)
474
(9.30 + 0.5)
852
(9.20 + 0.3)
3/15/85
(10.0 + 0.5)
144
(7.70 + 0.4)
466
(9.20 + 0.5)
852
(8.98 + 0.3)
3/07/85
(9.50 + 0.3)
152
(9.60 + 0.3)
474
(9.70 + 0.3)
852
(9.60 + 0.8)
3/07/85
(10.7 + 0.4)
152
(11.2 + 0.4)
474
(9.30 + 0.4)
852
(8.90 + 0.4)
3/07/85
(9.50 + 0.4)
152
(10.4 + 0.4)
474
(12.2 + 0.5)
852
NA
3/07/85
(10.3 + 0.4)
152
(7.80 + 0.3)
474
(10.7 + 0.4)
852
(10.8 + 0.4)
3/15/85
(10.0 + 0.5)
144
(9.30 +0.5)
466
(9.80 + 0.5)
852
NA
o
fo
*Callbratlon was performed using permeation devices unless otherwise specified. An NBS primary standard wag
**Fourth analysis was performed using automated cryogenic preconcen tra tlon with cryof ocus Ing.
***Number o£ days after 1st RTI analysis date.
»***A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
(Continued)
used for calibration for 4th analysis.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A9
ACTIVITY
COMPOUND
Ace tonl trlle
Methyl
Ethyl Ketone
Trlchloro-
e thy lene
1,2-Dichloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dlchlorodl-
fluorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. TPB
3/29/85
(14.1 + 1.0)
(12.1 + 1.9)
147
(12.0 -f 0.8)
(12.1 + 1.9)
443
(13.6 + 0.9)
(12.1 + 1.9)
852
(13.2 + l.'B)
(12.1 + 1.9)
3/29/85
(16.9 + 0.9)
(15.8 + 2.0)
147
(14.1 + 0.8)
(15.8 + 2.0)
443
(16.1 + 0.8)
(15.8 + 2.0)
852
(17.2 + 0.8)
(15.8+2.0)
3/07/85
(10.9 + 0.5)
(11.6 + 0.3)
152
(11.6 + 0.6)
(11.6 + 0.3)
474
(10.9 + 0.5)
(11.6 + 0.3)
852
(11.8 + 0.4)
(11.6 + 0.3)
3/15/85
(9.30 + 0.5)
(9.14 + 0.6)
144
(9.10 + 0.5)
(9.14 + 0.6)
466
(9.50 + 0.5)
(9.14 + 0.6)
852
(9.36 + 0.3)
(9.14 + 0.6)
3/07/85
(10.7 + 0.4)
(11.3 + 0.6)
152
(11.0 + 0.4)
(11.3 + 0.6)
474
(10.6 + 0.3)
(11.3 + 0.6)
852
(11.4 + 1.0)
(11.3 + 0.6)
3/07/85
(19.4 + 0.8)
(23.0 + 0.6)
152
(19.3 + 0.8)
(23.0 + 0.6)
474
(19.9 + 0.8)
(23.0 + 0.6)
852
(18.4 + 0.4)
(23.0 + 0.6)
3/07/85
(8.20 + 0.3)
(9.41 + 0.4)
152
(8.40 + 0.3)
(9.41 + 0.4)
474
(10.8 + 0.4)
(9.41 + 0.6)
852
NA
(9.41 + 0.6)
3/07/85
(9.50 + 0.4)
(9.61 + 0.3)
152
(8.80 + 0.4)
(9.61 + 0.3)
474
(9.70 + 0.4)
(9.61 + 0.3)
852
(10.6 + 0.4)
(9.61 + 0.3)
3/15/85
(11.9 + 0.6)
(11.9 + 0.3)
144
(11.3 + 0.6)
(11.9 + 0.3)
466
(11.8 + 0.6)
(11.9 + 0.3)
852
(12.0 + 0.4)
(11.9 + 0.3)
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentra tlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR CROUP II COMPOUNDS*
CYLINDER II-A10
ACTIVITY
Theoretical PPB'
1st Analysis Data
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonitrile
(30.1)
11/14/84
(27.7)
1/04/85
(34.3)
Methyl
Ethyl Ketone
(30.0)
11/14/84
(27.8)
1/04/85
(29.0)
Trichloro-
ethylene
(30.0)
11/14/84
(27.7)
1/04/85
(26.8)
1,2-Dichloro-
e thane
MANUFACTURER
(30.0)
11/14/84
(24.9)
1/04/85
(26.8)
Trichloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(30.9)
12/26/84
(25.4)
1/22/85
(27.7)
Bromo methane
(30.0)
12/26/84
(29.3)
1/22/85
(30.1)
Dichlorodi-
f luorometh—
ane (F-12)
(29.2)
12/26/84
(26.2)
1/22/85
(27.9)
1,2-Dibro-
moethane
(30.0)
11/14/84
(32.4)
1/04/85
(33.3)
1,1,1-
Trichloro-
ethane
(30.0)
11/14/84
(30.1)
1/04/85
(31.7)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/27/85
(26.8 + 1.9)
147
(24.2 + 1.7)
445
(27.1 + 1.9)
on audit
3/27/85
(28.0 + 1.5)
147
(29.0 + 1.6)
445
(27.4 + 1.4)
on audit
3/05/85
(28.8 + 1.4)
155
(28.2 + 1.4)
472
(29.6 + 1.5)
on audit
3/13/85
(30.2 + 1.5)
147
(27.3 + 1.4)
464
(28.6 + 1.5)
on audit
3/05/85
(29.7 + 1.0)
155
(29.5 + 1.0)
472
(32. 1 + 1.0)
on audit
3/05/85
(32. 1 + 1.3)
155
(31.4 + 1.2)
472
(30.5 + 1.2)
on audit
3/05/85
(31.4 + 1.3)
155
(29.4 + 1.2)
472
(26. 1 + 1.0)
on audit
3/05/85
(30.8 + 1.3)
155
(32.6 + 1.3)
472
(30.4 + 1.3)
on audit
3/13/85
(30.6 + 1.5)
147
(27.7 + 1.4)
464
(30.1 + 1.6)
on audit
t—»
o
-P-
*Calibratton was performed using permeation devices unless otherwise specified. An NBS primary standard
**Fourth analysis was performed using automated cryogenic preconcentratlon with cryofocusing.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
(Continued)
was used for calibration for 4th analysis.
NC
This compound was not Included In this cylinder.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A10
ACTIVITY
COMPOUND
Acetonitrile
Methyl
Ethyl Ketone
Trlchloro-
ethylene
1,2-Dichloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodi-
f luorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
. ethane
RTI QUALITY CONTROL****
1st Ana lysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB .
4th Analysis Day .
PPB
NBS Concen. PPB
3/27/85
(13.2 + 0.9)
(12.1 + 1.9)
147
(12.5 + 0.9)
(12.1 + 1.9)
445
(13.6 + 0.9)
(12.1 + 1.9)
852*
(13.2 + 1.8)
(12.1 + 1.9)
3/27/85
(16.8 + 0.9)
(15.8 + 2.0)
147
(16.9 + 0.9)
(15.8 + 2.0)
445
(16.1 + 0.8)
(15.8 + 2.0)
852
(17.2 + 0.8)
(15.8 + 2.0)
3/05/85
(11.4 + 0.5)
(11.6 + 0.3)
155
(11.3 + 0.5)
(11.6 + 0.3)
472
(11.5 ± 0.6)
(11.6 + 0.3)
852
(11.8 + 0.4)
(11.6 + 0.3)
3/13/85
(9.50 + 0.5)
(9.i4 + 0.6)
147
(8.60 + 0.4)
(9.14 + 0.6)
464
(9.80 + 0.5)
(9.14 + 0.6)
852
(9.36 + 0.3)
(9. 14 + 0.6)
3/05/85
(11.1 + 0.4)
(11.3 + 0.6)
155
(11.2 + 0.4)
(11.3 + 0.6)
472
(10.7 + 0.3)
(11. 3 + 0.6)
852
(11.4 + 1.0)
(11.3 + 0.6)
3/05/85
(21.0 + 0.8)
(23.0 + 0.6)
155
(18.9 + 0.7)
(23.0 jf 0.6)
472
(20.4 + 0.8)
(23.0. + 0.6)
852
(18.4 + 0.4)
(23.0 + 0.6)
3/05/85
(9.10 + 0.4)
(9.41 + 0.4)
155
(8.30 + 0.3)
(9.41 + 0.4)
472
(10.6 + 0.4)
(9.41 + 0.6)
852
NA
(9.41 + 0.6)
3/05/85
(10.0 + 0.4)
(9.61 + 0.3)
155
(9.10 + 0.4)
(9.61 + 0.3)
472
(10.2 + 0.4)
(9.61 + 0.3)
852
(10.6 + 0.4)
(9.61 + 0.3)
3/13/85
(12.5 + 0.6)
(11.9 + 0.3)
147
(11.3 + 0.6)
(11.9 + 0.3)
464
(11.7 + 0.6)
(11.9 + 0.3)
852
(12.0 + 0.4)
(11.9 + 0.3)
•Calibration was performed using permeation devi'ces unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
***Number of days af^r 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A11
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Ace tonl trlle
(30.1)
11/28/84
(30.9)
1/04/85
(27.1)
Methyl
Ethyl Ketone
(30.0)
11/28/84
(24.9)
1/04/85
(29.3)
Trlchloro-
ethylene
(30.0)
11/28/84
(27.8)
1/04/85
(27.1)
1 ,2-Dlchloro-
e thane
MANUFACTURER
(30.0)
11/28/84'
(24.4)
1/04/85
(25.3)
Trichloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(30.3)
12/21/84
(31.6)
1/22/85
(28.0)
Brornome thane
(30.0)
12/21/84
(29.0)
1/22/85
(29.7)
Dlchlorodi-
f luorome th-
ane (F-12)
(29.7)
12/21/84
(24.9)
1/22/85
(29.3)
1,2-Dlbro-
moe thane
(30.0)
11/28/84
(32.2)
1/04/85
(32.4)
1,1,1-
Trichloro-
e thane
(30.0)
11/28/84
(30.0)
1/04/85
(30.8)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/27/85
(26.1 + 1.8)
147
(24.1 + 1.7)
444
(27.1 + 1.9)
852
(26.9 + 3.6)
3/27/85
(26.7 + 1.5)
147
(28.0 + 1.5)
444
(25.8 + 1.4)
852
(25.9 + 1.2)
3/05/85
(28.9 + 1.4)
155
(27.6 + 1.3)
476
(29.5 + 1.5)
852
(28.2 + 0.9)
3/13/85
(30.2 + 1.5)
147
(26.3 + 1.3)
470
(27.8 + 1.4)
852
(28.3 + 0.9)
3/05/85
(30.5 _+ 1.0)
155
(29.7 + 1.0)
476
(32.9 + 1.0)
852
(32.0 + 2.7)
3/05/85
(32.4 ^ 1.3)
155
(31.3 + 1.2)
476
(30.7 + 1.2)
852
(30.1 + 1.3)
3/05/85
(32.2 + 1.3)
155
(29.7 + 1.2)
476
(26.2 + 1.0)
852
NA
3/05/85
(31.1 + 1.3)
155
(33.7 + 1.4)
476
(30.4 _+ 1.3)
852
(30.9 + 1.2)
3/13/85
(30.6 + 1.5)
147
(27.5 + 1.4)
470
(29.8 + 1.6)
852
(28.9 + 0.9)
o
ON
. *Callbratlon was performed using permeation devices unless otherwise specified. An NBS primary standard was used for
**Fourth analysis was performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
(Continued)
calibration for 4th analysis.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A11
ACTIVITY
COMPOUND
Acetoni trlle
Methyl
Ethyl Ketone
Trichloro-
ethylene
1,2-Dichloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodi-
fluorome th-
ane (F-12)
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3/27/85
(13.2 + 0.9)
(12.1 + 1.9)
147
(12.5 + 0.9)
(12.1 + 1.9)
444
(13.6 + 0.9)
(12.1 + 1.9)
852
(13.2 + 1.8)
(12.1 + 1.9)
3/27/85
(16.8 + 0.9)
(15.8 + 2.0)
147
(16.9 + 0.9)
(15.8 + 2.0)
444
(16.0 + 0.8)
(15.8 + 2.0)
852
(17.2 + 0.8)
(15.8 + 2.0)
3/05/85
(11.4 + 0.5)
(11.6 + 0.3)
155
(11.3 + 0.5)
(11.6 + 0.3)
476
(11.5 + 0.6)
(1.1.6 + 0.3)
852
(11.8 + 0.4)
(11.6 + 0.3)
3/13/85
(9.50 + 0.5)
(9.14 + 0.59)
147
(8.60 + 0.4)
(9.14 + 0.6)
470
(9.80 + 0.5)
(9.14 + 0.59)
852
(9.36 + 0.3)
(9.14 + 0.6)
3/05/85
(11.1 + 0.4)
(11.3 + 0.6)
155
(11.2 + 0.4)
(11.3 + 0.6)
476
(10.7 + 0.3)
(11.3 + 0.6)
852
(11.4 + 1.0)
(11.3 + 0.6)
3/05/85
(21.0 + 0.8)
(23.0 + 0.6)
155
(18.9 + 0.7)
(23.0 + 0.6)
476
(20.4 + 0.8)
(23.0 _+ 0.6)
852
(18.4 + 0.8)
(23.0 + 0.6)
3/05/85
(9.10 + 0.4)
(9.41 + 0.4)
155
(8.30 + 0.3)
(9.41 + 0.4)
476
(10.6 + 0.4)
(9.41 + 0.6)
852
NA
(9.41 + 0.6)
3/05/85
(10.0 + 0.4)
(9.61 + 0.3)
155
(9.10 + 0.4)
(9.61 + 0.3)
476
(10.2 + 0.4)
(9.61 + 0.3)
852
(10.6 + 0.4)
(9.61 + 0.3)
3/13/85
(12.5 + 0.6)
(11.9 + 0.3)
147
(11.3 + 0.6)
(11.9 + 0.3)
470
(11.7 + 0.6)
(11.9 + 0.3)
852
(12.0 + 0.4)
(11.9 + 0.3)
h-'
O
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
NC = This compound was not Included in this cylinder.
NA = Not Analyzed. •
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER 1I-A12
ACTIVITY
Theoretical PPB •
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Acetonltrlle
(10.0)
12/03/84
(7.60)
1/08/85
(8.70)
Methyl
Ethyl Ketone
(29.9)
12/03/84
(27.1)
1/08/85
(28.1)
Trichloro-
ethylene
(10.0)
12/03/84
(9.40)
1/08/85
(9.70)
1,2-Dichloro-
e thane
MANUFACTURER
(9.90)
12/03/84
(9.40)
i/08/85
(8.90)
Trlchloro-
fluoro-
me thane
(F-ll)
ANALYSIS
(9.9)
12/12/84
(7.80)
1/21/85
(9.70)
Bromoraethane
(29.6)
12/12/84
(27.4)
1/21/85
(27.4)
Dichlorodt-
f luorometh-
ane (F-12)
(29.8)
12/12/84
(36.2)
1/21/85
(33.2)
1,2-Dibro-
moethane
(29.9)
12/03/84
(32.1)
1/08/85
(34.1)
1,1,1-
Trichloro-
ethane
(29.9)
12/03/84
(32.7)
1/08/85
(32.5)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/29/85
(10.4 + 0.7)
146
(10.4 + 0.7)
442
(10.2 + 0.7)
on audit
3/29/85
(26.4 + 1.5)
146
(27.2 + 1.5)
442
(29.0 + 1.5)
on audit
3/07/85
(9.60 + 0.5)
153
(9.60 + 0.5)
474
(10.1 + 0.5)
on audit
3/14/85
(10.3 + 0.5)
146
(10.3 + 0.5)
469
(10.5 + 0.5)
on audit
3/07/85
(9.70 + 0.3)
153
(9.20 + 0.3)
474
(9.80 + 0.3)
on audit
3/07/85
(31.0 + 1.2)
153
(31.5 + 1.2)
474
(39.1 + 1.6)
on audit
3/07/85
(31.0 + 1.3)
153
(30.5 + 1.3)
474
(27.7 + 1. 1)
on audit
3/07/85
(30.4 + 1.2)
153
(31.3 + 1.3)
474
(31.8 + 1.3)
on audit
3/14/85
(30.2 + 1.5)
146
(29.3 + 1.5)
469
(33.9 + 1.8)
on audit
o
00
(Continued)
*Ca11brat ton was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentration with cryofocusing.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A12
ACTIVITY
COMPOUND
Acetonl trlle
Methyl
Ethyl Ketone
Trlchloro-
ethy lene
1,2-Dlchloro-
e thane
Trlchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodl-
fluorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trtchloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3/29/85
(14.1 + 1.0)
(12.1 + 1.9)
146
(13.3 + 0.9)
(12.1 + 1.9)
442
(13.6 + 0.9)
(12.1 + 1.9)
852
(13.2 + 1.8)
(12.1 + 1.9)
3/29/85
(16.1 + 0.9)
(15.8 + 2.0)
146
(17.0 + 0.9)
(15.8 + 2.0)
442
(16.0 + 0.8)
(15.8 + 2.0)
852
(17.2 + 0.8)
(15.8 + 2.0)
3/07/85
(10.9 + 0.5)
(11.6 -1- 0.3)
153
(11.3 + 0.5)
(11.6 + 0.3)
474
(11.5 + 0.6)
(11.6 + 0.3)
852
(11.8 + 0.4)
(11.6 + 0.3)
3/14/85
(8.80 + 0.4)
(9.14 + 0.59)
146
(8.60 + 0.4)
(9.14 + 0.6)
469
(9.80 + 0.5)
(9.14 + 0.6)
852
(9.36 + 0.3)
(9.14 + 0.6)
3/07/85
(10.7 + 0.4)
(11.3 -1- 0.6)
153
(11.2 + 0.4)
(11.3 + 0.6)
474
(10.7 + 0.3)
(11.3 + 0.6)
852
(11.4 + 1.0)
(11.3 + 0.6)
3/07/85
(19.4 + 0.8)
(23.0 + 0.6)
153
(18.9 + 0.7)
(23.0 + 0.6)
474
(20.4 + 0.8)
(23.0 + 0.6)
852
(18.4 + 0.8)
(23.0 + 0.6)
3/07/85
(8.20 + 0.3)
(9.41 + 0.4)
153
(8.30 + 0.3)
(9.41 + 0.4)
474
(10.6 + 0.4)
(9.41 + 0.6)
852
NA
(9.41 + 0.6)
3/07/85
(9.50 _+ 0.4)
(9.61 + 0.3)
153
(9.10 + 0.4)
(9.61 + 0.3)
474
(10.2 + 0.4)
(9.61 + 0.3)
852
(10.6 + 0.4)
(9.61 + 0.3)
3/14/85
(11.4 + 0.6)
(11.9 + 0.3)
146
(11.3 + 0.6)
(11.9 + 0.3)
469
(11.7 -f 0.6)
(11.9 + 0.3)
852
(12.0 + 0.4)
(11.9 + 0.3)
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NA
Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A13
ACTIVITY
Theoretical PPB
Is t Analysis Da te
PPB
2nd Analysis Date
PPB
COMPOUND
Ace ton I tr lie
(10.0)
12/04/84
(10.2)
1/09/85
(9.60)
Methyl
Ethyl Ketone
(30.3)
12/04/84
(30.2)
1/09/85
(30.0)
Trlchloro-
e thy lene
(10. 0)
12/04/84
(10.0)
1/09/85
(9.20)
1,2-Dlchloro-
e thane
MANUFACTURER
(10.0)
12/04/84
(9.10)
1/09/85
(9.10)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(10. 0)
12/21/84
(10.7)
1/21/85
(10.1)
Broraome thane
(30,2)
12/21/84
(29.8)
1/21/85
(28.9)
Dichlorodi-
f luorome th-
ane (F-12)
(30.0)
12/21/84
(31.5)
1/21/85
(31.9)
1,2-Dibro-
moe thane
(30.0)
12/04/84
(35.0)
1/09/85
(35.1)
1,1,1-
Trlchloro-
e thane
• (30.0)
12/04/84
(32.8)
1/09/85
(32.2)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB .
4th Analysis Day***
PPB
3/29/85
(10.6 + 0.7)
146
(10.4 + 0.7)
443
(11.3 + 0.8)
851
NA
3/29/85
(28.7 + 1.6)
146
(26.9 + 1.5)
443
(30.0 + 1.6)
851
(29.7 -»- 1.4)
3/07/85
(9.90 + 0.5)
153
(9.80 + 0.5)
474
(10.2 + 0.5)
851
NA
3/14/85
(10.3 + 0.5)
146
(9.80 + 0.5)
469
(9.70 + 0.5)
851
NA
3/07/85
(10. I + 0.3)
153
(10.6 + 0.4)
474
(10. I + 0.3)
851
(10.8 + 0.9)
3/07/85
(33.3 + 1.3)
153
(32.8 + 1.3)
474
(30.0 + 1.2)
851
(34.3 + 1.5)
3/07/85
(32.2 + 1.3)
153
(31.4 + 1.3)
474
(26.3 + 1.0)
851
NA
3/07/85
(32.1 + 1.3)
153
(32.9 + 1.3)
474
(32.0 + 1.3)
851
(32.5 + 1.3)
3/14/85
(30.4 + 1.5)
146
(29.3 + 1.5)
469
(31.7 + 1.7)
851
NA
*Callbratlon was performed using permeation devices unless otherwise specified. An NBS primary standard was used for
"Fourth analysis was performed using automated cryogenic preconcen tra tlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
(Continued)
calibration for 4th analysis.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A13
ACTIVITY
COMPOUND
Acetonltrlle
Methyl
Ethyl Ketone
Trichloro-
ethylene
1,2-Dlchloro-
e thane
Trlchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dlchlorodl-
fluorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3/29/85
(14.1 + 1.0)
(12.1 + 1.9)
146
(13.3 + 0.9)
(12.1 + 1.9)
443
(13.6 + 0.9)
(12.1 + 1.9)
851
(13.1 + 1.8)
(12.1 + 1.9)
3/29/85
(16.1 + 0.9)
(15.8 + 2.0)
146
(17.0 + 0.9)
(15.8 + 2.0)
443
(16.1 + 0.8)
(15.8 + 2.0)
851
(17.2 + 0.8)
(15.8 + 2.0)
3/07/85
(10.9 + 0.5)
(11.6 + 0.3)
153
(11.3 + 0.5)
(11.6 + 0.3)
474
(11.5 + 0.6)
(11.6 + 0.3)
851
(11.8 + 0.4)
(11.6 + 0.3)
3/14/85
(8.80 + 0.6)
(9.14 + 0.6)
146
(8.60 + 0.4)
(9.14 + 0.6)
469
(9.80 + 0.5)
(9.14 + 0.6)
851
(9.70 + 0.3)
(9.14 + 0.6)
3/07/85
(10.7 + 0.6)
(11.3 + 0.6)
153
(11.2 + 0.4)
(11.3 + 0.6)
474
(10.7 + 0.3)
(11.3 + 0.6)
851
(11.8 + 1.0)
(11.3 + 0.6)
3/07/85
(19.4 + 0.8)
(23.0 + 0.6)
153
(18.9 + 0.7)
(23.0 + 0.6)
474
(20.4 + 0.8)
(23.0 + 0.6)
851
(20.4 + 0.9)
(23.0 + 0.6)
3/07/85
(8.20 + 0.8)
(9.41 + 0.4)
153
(8.30 + 0.3)
(9.41 + 0.4)
474
(10.6 + 0.4)
(9.41 + 0.6)
851
NA
(9.41 + 0.6)
3/07/85
(9.50 + 0.4)
(9.61 + 0.3)
153
(9.10 + 0.4)
(9.61 + 0.3)
474
(10.2 + 0.4)
(9.61 _+ 0.3)
851
(10.2 + 0.4)
(9.61 + 0.3)
3/14/85
(11.4 + 0.6)
(11.9 + 0.3)
146
(11.3 + 0.6)
(11.9 + 0.3)
469
(11.7 + 0.6)
(11.9 + 0.3)
851
(12.0 + 0.4)
(11.9 _+ 0.3)
"Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER 11-A 14
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Ace tonl trlle
(41.6)
12/05/84
(47.7)
1/11/85
(43.9)
Methyl
Ethyl Ketone
(20.0)
12/05/84
(17.7)
1/11/85
(16.7)
Trlchloro-
ethylene
(40.1)
12/05/84
(35.9)
1/11/85
(35.0)
1,2-Dlchloro-
e thane
MANUFACTURER
(40.1)
12/05/84
(33.0)
1/11/85
(33.4)
Trichloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(40.1)
12/26/84
(27.4)
1/23/85
(33.7)
Bromome thane
(20.1)
12/26/84
(19.8)
1/23/85
(19,2)
Dichlorodl-
f luorome th-
ane (F-12)
(20.1)
12/26/84
(19.3)
1/23/85
(20.8)
1,2-Dlbro-
moe thane
(20.2)
12/05/84
(21.3)
1/11/85
(22.2)
1,1,1-
Trlchloro-
e thane
(20.1)
12/05/84
(19.9)
1/11/85
(19.9)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/27/85
(37.3 + 2.6)
148
(38.1 _+ 2.7)
445
(38.4 + 2.7)
854
(38.2 + 5.2)
3/27/85
(16.4 + 0.9)
148
(16.4 + 0.9)
445
(16.1 + 0.8)
854
(16.6 + 0.8)
3/05/85
(37.9 + 1.8)
156
(38.0 + 1.8)
476
U9.4 + 1.9)
854
(39.2 + 1.3)
3/13/85
(41.0 + 2.1)
148
(38.8 + 2.0)
470
(37.4 + 1.9)
854
(39.8 + 1.2)
3/05/85
(36.8 + 1.3)
156
(38.6 + 1.3)
476
(40.8 + 1.3)
854
(33.5 + 2.9)
3/05/85
(21.9 + 0.9)
156
(21.8 + 0.8)
476
(23. 1 + 0.9)
854
(24.1 + 1.0)
3/05/85
(21.8 + 0.9)
156
(20.6 + 0.8)
476
(20.3 + 0.8)
854
NA
3/05/85
(21.9 + 0.9)
156
(24.7 + 1.0)
476
(20.8 + 0.9)
854
NA
3/13/85
(19.8 + 1.0)
148
(18.2 + 0.9)
470
(19.1 + 1.0)
854
(19.8 + 0.6)
*Calibratlon was performed using permeation devices unless otherwise specified. An NBS primary standard was used for
**Fourth analysis was performed using automated cryogenic preconcentra tlon with cryofocusing followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not Included In this cylinder.
NA = Not Analyzed.
(Continued)
calibration for 4th analysis.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A14
ACTIVITY
COMPOUND
Ace tonl trl le
Methyl
Ethyl Ketone
Trichloro-
e thy lene
1,2-Dichloro-
e thane
Trlchloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodi-
f luorome th-
ane (F-12)
1,2-Dlbro-
moe thane
1,1,1-
Trlchloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPE
NBS. Concen. PPB
3/7/85
(13.2 + 0.9)
(12.1 + 1.9)
148
(13.3 + 0.9)
(12.1 + 1.9)
445
(13.6 + 0.9)
(12.1 + 1.9)
854
(11.6 + 1.6)
(12.1 + 1.9)
3/7/85
(16.8 + 0.9)
(15.8 + 2.0)
148
(17.0 + 0.9)
(15.8 + 2.0)
445
(16.1 + 0.8)
(15.8 + 2.0)
854
(16.4 + 0.8)
(15.8 + 2.0)
3/7/85
(11.4 + 0.5)
(11.6 + 0.3)
156
(11.2 + 0.5)
(11.6 + 0.3)
476
(11.5 + 0.6)
(11.6 + 0.3)
854
(10.5 + 0.3)
(11.6 + 0.3)
3/05/85
(9.50 + 0.5)
(9.14 + 0.6)
148
(8.50 + 0.4)
(9.14 + 0.6)
470
(9.80 + 0.5)
(9.14 + 0.6)
854
(8.60 _+ 0.3)
(9.14 + 0.6)
3/05/85
(11.1 + 0.4)
(11.3 + 0.6)
156
(11.2 + 0.4)
(11.3 + 0.6)
476
(10.7 + 0.3)
(11.3 + 0.6)
854
(8.9 + 0.8)
(11.3 + 0.6)
3/05/85
(21.0 + 0.8)
(23.0 + 0.6)
156
(18.9 + 0.7)
(23.0 + 0.6)
476
(20.4 + 0.8)
(23.0 + 0.6)
854
NA
(23.0 + 0.6)
3/05/85
(9.10 + 0.4)
(9.41 + 0.4)
156
(8.50 + 0.3)
(9.41 + 0.4)
476
(10.6 + 0.4)
(9.41 + 0.6)
854
NA
(9.41 + 0.6)
3/05/85
(10.0 + 0.4)
(9.61 + 0.3)
156
(9.30 + 0.4)
(9.61 + 0.3)
476
(10.2 + 0.4)
(9.61 + 0.3)
854
(9.45 + 0.4)
(9.61 + 0.3)
3/13/85
(12.5 + 0.6)
(11.9 + 0.3)
148
(11.3 + 0.6)
(11.9 _+ 0.3)
470
(11.7 + 0.6)
(11.9 + 0.3)
854
(10.2 + 0.3)
(11.9 + 0.3)
•Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
***Number of days after 1st RTI analysis aate.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
NC = This compound was not included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A15
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date •'
PPB
COMPOUND
Ace tonitrl le
(41.5)
12/07/84
(45.1)
1/14/85
(43.9)
Methyl
Ethyl Ketone
(20.0)
12/07/84
(18.8)
1/14/85
(18.4)
Trichloro-
e thylene
(40.0)
12/07/84
(36.6)'
1/14/85
(38.4)
1,2-Dlchloro-
e thane
MANUFACTURER
(40.0)
12/07/84
(33.2)
1/14/85
(34.4)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(40.0)
12/27/84
(35.1)
1/23/85
(33.8)
Bromome thane
(20.1)
12/27/84
(19.7)
1/23/85
(19.2)
Dichlorodl-
fluorome th-
ane (F-12)
(20.0)
12/27/84
(22.2)
1/23/85
(16.1)
1,2-Dlbro-
moe thane
(20.1)
12/07/84
(22.4)
1/14/85
(23.1)
1,1,1-
Trlchloro-
e thane
(20.0)
12/07/84
(19.9)
1/14/85
(20.3)
RTI ANALYSIS**
1st Analysis Date
PPB
2nd Analysis Day***
PPB
3rd Analysis Day***
PPB
4th Analysis Day***
PPB
3/27/85
(36.3 + 2.5)
148
(37.6 + 2.6)
445
(37.3 + 2.6)
851
(35.7 + 4.8)
3/27/85
(18.3 + 1.0)
148
(18.5 + 1.0)
445
(17.7 + 0.9)
851
(18.0 + 0.9)
3/05/85
(38.4 + 1.8)
156
(38.4 + 1.8)
476
(41.9 + 2.1)
851
(41.1 + 1.3)
3/13/85
(40.7 + 2.1)
148
(39.3 + 2.0)
470
(38.0 + 2.0)
851
(40.7 + 1.3)
3/05/85
(36.6 + 1.2)
156
(38.5 + 1.3)
476
(42.0 + 1.3)
851
(39.4 + 3.4)
3/05/85
(21.9 + 0.9)
156
(22.0 + 0.9)
476
(25.4 + 1.0)
851
(24.5 + 1.0)
3/05/85
(21.9 + 0.9)
156
(20.8 + 0.9)
476
(21.0 + 0.8)
851
NA
3/05/85
(21.9 + 0.9)
156
(21.7 + 0.9)
476
(22.2 + 0.9)
851
(22.7 + 0.9)
3/13/85
(20.1 + 1.0)
148
(18.2 + 0.9)
470
(21.2 + 1.1)
851
(20.3 + 0.6)
*Callbratlon was per^irmed using permeation devices unless otherwise specified. An NBS primary standard was used for
**Fourth analysis was performed using automated cryogenic preconcentra tlon with cryofocuslng followed by GC/FID.
***Number of days after 1st RTI analysis date.
****A different NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
(Continued)
calibration for 4th analysis.
NC = This compound was not included In this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS* (Continued)
CYLINDER II-A15
ACTIVITY
COMPOUND
Ace tonl trile
Methyl
Ethyl Ketone
Trichloro-
ethylene
1,2-Dichloro-
e thane
Trichloro-
f luoro-
me thane
(F-ll)
Bromome thane
Dichlorodi-
fluorome th-
ane (F-12).
1,2-Dibro-
moe thane
1,1,1-
Trichloro-
e thane
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Ana ly si's Day
PPB
NBS'Concen. PPB
3/27/85
(13.2 + 0.9)
(12.1 + 1.9)
148
(13.3 + 0.9)
(12.1 + 1.9)
445
(13.6 + 0.9)
(12.1 + 1.9)
851
(13.2 + 1.8)
(12.1 + 1.9)
3/27/85
(16.8 + 0.9)
(15.8 + 2.0)
148
(17.0 + 0.9)
(15.8 + 2.0)
445
(16.1 + 0.8)
(15.8 + 2.0)
851
(17.2 + 0.8)
(15.8 + 2.0)
3/05/85
(11.4 + 0.5)
(11.6 + 0.3)
156
(11.2 + 0.5)
(11.6 + 0.3)
476
(11.5 -f 0.6)
(11.6 + 0.3)
851
(11.8 + 0.4)
(11.6 + 0.3)
3/13/85
(9.50 + 0.5)
(9.14 + 0.6)
148
(8.50 + 0.4)
(9. .14 + 0.6)
470
(9.80 + 0.5)
(9.14 + 0.6)
851
(9.40 + 0.3)
(9.14 + 0.6)
3/05/85
(11. I + 0.4)
(11.3 + 0.6)
156
(11.2 + 0.4)
(11.3 + 0.6)
476
(10.7 + 0.3)
(11.3 + 0.6)
851
(11.4 + 1.0)
(11.3 + 0.6)
3/05/85
(21.0 + 0.8)
(23.6 + 0.6)
156
(18.9 + 0.7)
(23.0 + 0.6)
476
(20.4 + 0.8)
(23.0 + 0.6)
851
(18.4 + 0.8)
(23.0 + 0.6)
3/05/85
(9.10 + 0.4)
(9.41 + 0.4)
156
(8.50 + 0.3)
(9.41 + 0.4)
476
(10.6 + 0.4)
(9.41 + 0.6)
851
NA
(9.41 + 0.6)
3/05/85
(10.0 + 0.4)
(9.61 + 0.3)
156
(9.30 + 0.4)
(9.61 + 0.3)
476
(10.2 + 0.4)
(9.61 + 0.3)
851
(10.2 + 0.4)
(9.61 + 0.3)
3/13/85
(12.5 + 0.6)
(11.9 + 0.3)
148
(11.3 + 0.6)
(11.9 + 0.3)
470
(11.7 + 0.6)
(11.9 + 0.3)
851
(12.0 + 0.4)
(11.9 + 0.3)
Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 4th analysis.
**Fourth analysis was performed using automated cryogenic preconcentra tion with cryofocusing followed by GC/FID.
***Number of days after 1st RTI analysis date.
l***A different NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
NC = This compound was not Included in this cylinder.
NA = Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A16
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Acetoni trile
(150)
5/09/86
(87.0)
Methyl
Ethyl Ketone
(150)
5/09/86
(134)
Trichloro-
ethylene
(150)
5/09/86
(137)
1,2-Dlchloro-
e thane
MANUFACTURER
(150)
5/09/86
(128)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(150)
5/09/86
(153)
Bromome thane
(150)
5/09/86
(139)
Dichlorodi-
fluorome th-
ane (F-12)
(150)
5/09/86
(147)
1,2-Dibro-
moe thane
(150)
5/09/86
(153)
1,1,1-
Trichloro-
e thane
(150)
5/09/86
(144)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
6/17/86
(154 + 11)
408
(146 + 19.7)
6/17/86.
(167 + 8.8)
408
(144 + 6.9)
7/01/86
(148 + 7.2)
408
(158 + 4.7)
7/01/86
(155 £ 8.0)
408
(150 + 4.7)
7/01/86
(155 + 4.8)
408
(152 + 13.0)
7/01/86
(184 + 7.4)
408
MA
7/01/86
(161 + 6.2)
408
NA
7/01/86
(158 + 6.6)
408
(159 + 6.4)
7/01/86
(152 + 8.0)
408
(149 + 4.5)
RTI QUALITY CONTROL**
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
6/17/86
(13.6 + 0.9)
(12.1 + 1.9)
408
(12.8 + 1.7)
(12.1 + 1.9)
6/17/86
(16. I + 0.8)
(15.8 + 2.0)
408
(17. A + 0.8)
(15.8 + 2.0)
7/01/86
(120 + 6.0)
(118 + 1.0)
408
(11.6 + 0.4)
(11.6 + 0.3)
7/01/86
(126 + 7.0)
(123 + 2.0)
408
(9.30 + 0.3)
(9.14 + 0.6)
7/01/86
(157 + 5.0)
(151 + 5.0)
408
(12.5 + 1.1)
(11.3 + 0.6)
7/01/86
(181 + 7.0)
(193 + 3.0)
408
(25.1 + 1.1)
(23.0 + 0.6)
7/01/86
(116 + 5.0)
(116 + 4.0)
408
NA
(9.41 + 0.4)
7/01/86
(159 + 7.0)
(150 + 2.0)
408
(9.80 + 0.4)
(9.61 + 0.3)
7/01/86
(154 + 8.0)
(147 + 3.0)
408
(11.9 + 0.3)
(11.9 + 0.3)
•Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 2nd analysis.
**NBS primary standard was analyzed as internal Quality Control on each day of RTI analysis.
***Number of days after 1st RTI analysis date.
****First RTI analysis was performed using direct injection. Second RTI analysis was performed using automated cryogenic preconcen tra tlon with
cryofocusing followed by GC/FID.
NA
Not Analyzed.
-------
STABILITY STUDY FOR GROUP II COMPOUNDS*
CYLINDER II-A17
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Acetoni trile
(150)
5/09/86
(51. A)
Methyl
Ethyl Ketone
(150)
5/09/86
(106)
Trlchloro-
ethylene
(150)
5/09/86
(135)
1,2-Dlchloro-
e thane
MANUFACTURER
(150)
5/09/86
(127)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(150)
5/09/86
(158)
Bromo me thane
(150)
5/09/86
(136)
Dlchlorodl-
f luorome th-
ane (F-12)
(150)
5/09/86
(142)
1,2-Dibro-
moe thane
(150)
5/09/86
(152)
1,1,1-
Trichloro-
e thane
(150)
5/09/86
(138)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
6/17/86
(47.1 + 3.3)
408
NA
6/17/86
(112 + 5.9)
408
NA
7/01/86
(148 + 7.3)
408
(153 + 4.8)
7/01/86
(154 + 8.0)
408
(143 -f 4.5)
7/01/86
(156 + 4.9)
408
(156 + 13.4)
7/01/86
(163 + 6.3)
408
NA.
7/01/86
(160 + 6.2)
408
NA
7/01/86
(163 + 6.7)
408
(154 + 6.1)
7/01/86
(152 + 8.0)
408
(140 + 4.2)
RTI QUALITY CONTROL**
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
6/17/86
(13.6 + 0.9)
(12.1 + 1.9)
408
(12.8 + 1.7)
(12.1 + 1.9)
6/17/86
(16.1 + 0.8)
(15.8 + 2.0)
408
(17.4 + 0.8)
(15.8 + 2.0)
7/01/86
(120 + 6.0)
(118 + 1.0)
408
(11.6 + 0.4)
(11.6 + 0.3)
7/01/86
(126 + 7.0)
(123 + 2.0)
408
(9.30 + 0.3)
(9.14 + 0.6)
7/01/86
(157 + 5.0)
(151 + 5.0)
408
(12.5 + 1.1)
(11.3 + 0.6)
7/01/86
(181 + 7.0)
(193 + 3.0)
408
(25.1 + 1.1)
(23.0 + 0.6)
. 7/01/86
(116 + 5.0)
(116 + 4.0)
408
NA
(9.41 + 0.4)
7/01/86
(159 + 7.0)
(150 + 2.0)
408
(9.80 + 0.4)
(9.61 + 0.3)
7/01/86
(154 + 8.0)
(147 + 3.0)
408
(11.1 + 0.3)
(11.9 + 0.3)
•Calibration was performed using permeation devices unless otherwise specified. An NBS primary standard was used for calibration for 2nd analysis.
**NBS primary standard was analyzed as Internal Quality Control on each day of RTI analysis.
***Number of days after 1st RTI analysis date.
k***Flrst RTI analysis was performed using direct Injection. Second RTI analysis was performed using automated cryogenic preconcentratlon with
cryofocuslng followed by GC/FID.
NA = Not Analyzed.
-------
STABILITY STUDY FOR CROUP 11 COMPOUNDS*
CYLINDER I1-A18
ACTIVITY
Theoretical PPB
1st Analysis Date
I I'D
COMPOUND
Ace tonl trl le
(150)
5/09/86
(82. A)
Methyl
Ethyl Ketone
(150)
5/09/86
(132)
Trlchloro-
ethy lene
(150)
5/09/86
(137)
1,2-Dlchloro-
e thane
MANUFACTURER
(150)
5/09/86
(128)
Trlchloro-
f luoro-
me thane
(F-ll)
ANALYSIS
(150)
5/09/86
(145)
Dromome thane
(150)
5/09/86
(138)
Dichlorodl-
f luorometh-
ane (F-12)
(150)
5/09/86
(146)
1,2-Dlbro-
moe thane
(150)
5/09/86
(154)
1,1,1-
Trlchloro-
e thnne
(150)
5/09/86
(146)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day***
PPB
6/17/86
(140 + 9.7)
408
( 135 + 18.3)
6/17/86
(159 + 8.4)
408
(147 + 7.1)
7/01/86
(148 + 7.3)
408
NA
7/01/86
(154 + 7.9)
408
(145 + 4.6)
7/01/86
(153 + 4.8)
408
NA
7/01/86
(186 + 7.4)
408
NA
7/01/86
(161 + 6.2)
408
NA
7/01/86
(163 + 6.7)
408
NA
7/01/86
(151 + 8.0)
408
(150 + 4.5)
RTI DUALITY CONTROL**
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
Pl'B
NBS Concen. PPB
6/17/86
(13.6 + 0.9)
(12.1 + 1.9)
408
(12.8 + 1.7)
(12.1 + 1.9)
6/17/86
(16.1 + 0.8)
(15.8 + 2.0)
408
(17.4 _+ 0.8)
(15.8 _+ 2.0)
7/01/86
(120 + 6.0)
(118 + 1.0)
408
(11.6 + 0.4)
(11.6 + 0.3)
7/01/86
(126 + 7.0)
(123 + 2.0)
408
(9.30 + 0.3)
(9.14 + 0.6)
7/01/86
(157 + 5.0)
(151 + 5.0)
408
(12.5 + l.l)
(11.3 + 0.6)
7/01/86
(181 + 7.0)
(193 + 3.0)
408
(25.1 + I. 1)
(23.0 + 0.6)
7/01/86
(116 + 5.0)
(116 + 4.0)
408
NA
(9.41 + 0.4)
7/01/86
(159 + 7.0)
(150 + 2.0)
408
(9.80 + 0.4)
(9.61 + 0.3)
7/01/86
(154 + 8.0)
(147 + 3.0)
408
(11.2 + 0.3)
(11.9 + 0.3)
••*Ca Libra tlon was performed ustng perinea ticm devices uu Les s otherwise specified. An NUS primary s tanda rd was used for calibration for 2nd analysis.
**NBS primary standard was analyzed as internal Qua li ty Con t rol on each day of RTI ana lysis.
***Number of days af ter 1st RTI ana lysis da te.
****First KT1 analysis was performed using direct injection. Second RTI ana ly s is was pe r formed us Ing au toina ted cryogenic preconcentratlon with
cryofocuslng followed by GC/Fill
NA = Not Ana lyzed.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder II1-A1
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(30.0)
4-24-85
(27.2)
6-1-85
(28.3)
Freon
113
(30.0)
4-24-85
(27.9)
6-1-85
(27.8) '
Vinylldlene
Chloride
MANUFACTURER
(30.1)
4-24-85
(26.9)
6-1-85
(28.8)
Acetone
ANALYSIS
(10.0)
4-24-85
(10.0)
6-1-85
(9.00)
1,4-
Dloxane
(10.0)
4-24-85
(9.00)
6-1-85
(9.00)
To luene
(10.1)
4-24-85
(8.60)
6-1-85
(9.00)
Chloro-
benzene
(10.1)
4-24-85
(9.50)
6-1-85
(8.00)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-27-86
(24.0 + 3.4)
52
(21.9 + 3.1)
150
(24.6 + 4.6)
385
(21.8 + 3.9)
3-27-86
(30.2 + 3.0)
52
(29.2 + 2.9)
150
(30.2 + 3.9)
385
(28.9 + 3.8)
3-27-86
(29.5 + 3.0)
52
(31.2 + 3.2)
150
(30.7 + 4.2)
385
(33.3 + 4.7)
3-27-86
(10.0 + 3.0)
52
(11.0 _+ 3.0)
150
(8.60 + 2.6)
385
(9.20 + 2.4)
3-27-86
(8.00 + 4.0)
52
(9.00 + 5.0)
150
(10.0 + 3.2)
385
(11.4 + 3.6)
3-27-86
(9.80 + 1.1)
52
(10. 1 + 1.1)
150
(12.3 + 0.8)
385
(11.6 + 0.7)
3-27-86
(10.8 + 1.3)
52
(10.6 + 1.3)
150
(10.7 + 1.8)
385
(11.7 + 1.9)
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder III-A1
N3
O
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
Chloride
Acetone
1,4-
Dioxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-27-86
(11.6 + 1.7)
(10.6 + 1.0)
52
(15.0 + 2.1)
(18.1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + 1. 1)
(10.6 + 1.0)
3-27-86
(20.1 + 1.8)
(20.2 + 1.2)
52
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 _+ 1.2)
3-27-86
(8.30 + 0.9)
(9.20 + 0.5)
52
(21.5 + 2.2)
(20.8 + l.l)
150
(16.3 _+ 2.2)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-27-86
(12.0 + 3.0)
(14.0 + 3.0)
52
(47.0 + 14)
(47.0 + 8.0)
150
(13.0 + 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-27-86
(13.0 + 8.0)
(15.0 + 6.0)
52
(42.0 + 21)
(42.0 + 17)
150
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 1. 1)
(15.0 + 6.0)
3-27-86
(15.7 + 1.6)
(13.2 _+ 1.1)
52
(10.3 -1- 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 _+ 0.6)
385
(13.4 + 1.1)
(13.2 + 1.1)
3-27-86
(7.90 + l.l)
(8.10 + 0.5)
52
(11.4 + 1.4)
(11.2 + 0.7)
150
(11.9 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis
**** All RTI analyses were performed using cryogenic preconcentration followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A2
ACTIVITY
Theoretical PPB
1st Analysis Date
' PPB
2nd Analysis Date
PPB
COMPOUND
Freon
ii4
(10.0)
4-22-85
(9.00)
6-3-85
(8.40)
Freon
113
(10.0)
4-22-85
(10.5)
6-3-85
(8.90)
Vlnylldlene
Chloride
MANUFACTURER
(10.2)
4-22-85
(10.7)
6-3-85
(10.7)
Acetone
ANALYSIS
(32.0)
4-22-85
(21.0)
6-3-85
(19.0)
1,4-
Dloxane
(30.0)
4-22-85
(33.0)
6-3-85
(29.0)
Toluene
(30.0)
4-22-85
(27.0)
6-3-85
(27.4)
Chloro-
benzene
(30.0)
4-22-85
(30.2)
6-3-85
(30.6)
: RT1 ANALYSIS****
1st Analysis Date
PPB
2nd Ann lysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-9-86
(8.40 _+ 1.2)
70
(7.80 -f 1.1)
150
(7.60 + 1.4)
385
(6.80 + 1.2)
3-9-86
(9.30 + 1.0)
70
(9.30 + 0.9)
150
(9.60 + 1.2)
385
(10.5 + 1.3)
3-9-86 '
(9.50 + 1.0)
70
(9.70 + 1.0)
150
(10.6 + 1.5)
385
(10.8 + 1.5)
3-9-86
(24.0 + 6.0)
70
(27.0 + 8.0)
150
(25.3 + 7.9)
385
(24.8 + 7.7)
3-9-86
(29.0 + 16)
70
(28.0 + 14)
150
(32.2 + 11)
385
(26.0 + 8.0)
3-9-86
(27.5 + 3.2)
70
(28.3 + 3.2)
150
(32.8 + 2.3)
385
(28.0 + 2.0)
3-9-86
(30.4 + 3.5)
70
(29.1 + 3.5)
150
(28.3 + 4.8)
385
(28.5 + 4.6)
(Continued)
-------
STABILITY STUDY FOR CROUP III COMPOUNDS* (Continued)
Cylinder III-A2
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
Chloride
Acetone
1,4-
Dloxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-9-86
(11.9 + 1.7)
(10.6 + 1.0)
70
(15.0 + 2.1)
(18.1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + 1. 1)
(10.6 4- 1.0)
3-9-86
(20.4 + 1.8)
(20.2 + 1.2)
70
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-9-86
(8.80 + 0.9)
(9.20 + 0.5)
70
(21.5 + 2.2)
(20.8 + 1.1)
150
(16.3 + 2.2)
(16.0 + 1.0)
385
(9.70 -»- 0.5)
(9.20 + 0.5)
3-9-86
(11.0 + 3.0)
(14.0 + 3.0)
70
(47.0 + 14)
(47.0 + 8.0)
150
(13.0 + 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-9-86
(14.0 + 8.0)
(15.0 + 6.0)
70
(42.0 + 21)
(42.0 + 17)
150
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-9-86
(13.5 + 1.6)
(13.2 + 1.2)
70
(10.3 + 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 + 0.6)
385
(13.4 + 1.1)
(13.2 + 1.1)
3-9-86
(8.10 + 1.1)
(8.10 + 0.5)
70
(11.4 -f 1.4)
(11.2 + 0.7)
150
(11.8 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentration followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A3
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(29.9)
7-24-85
(28.3)
8-28-85
(27.7)
Freon
113
(10.0)
7-24-85
(8.50)
8-28-85
(9.10)
Vinylidiene
Chloride
MANUFACTURER
(30.8)
7-24-85
(29.4)
8-28-85
(29.5)
Acetone
ANALYSIS
(10.0)
7-24-85
(8.00)
8-28-85
(7.00)
1,4-
Dioxane
(30.0)
7-24-85
(28.0)
8-28-85
(25.0)
Toluene
(10.2)
7-24-85
(8.80)
8-28-85
(8.60)
Chloro-
benzene
(30.0)
7-24-85
(31.0)
8-28-85
(30.7)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-27-86
(24.5 + 3.5)
52
(22.8 + 3.2)
150
(27.6 + 5.2)
385
(23.5 + 4.1)
3-27-86
(9.40 + 1.0)
52
(10.5 + 1.0)
150
(10.3 + 1.3)
385
(11.0 + 1.3)
3-27-86
(30.6 + 3.1)
52
(32.0 + 3.2)
150
(32.4 + 4.5)
385
(35.2 -f 4.9)
3-27-86
(10. 0 + 3.0)
52
(9.00 + 3.0)
150
(7. 10 + 2.2)
385
(9.00 + 2.7)
3-27-86
(27.0 + 15)
52
(26.0 + 13)
150
(33.5 + 11)
385
(26.0 + 8.0)
3-27-86
(10.0 + 1.1)
52
(9.90 + 1.1)
150
(10.4 + 0.7)
385
(11.1 + 0.8)
3-27-86
(31.4 + 3.6)
52
(29.5 + 3.6)
150
(29.6 + 5.0)
385
(29.0 + 4.6)
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder III-A3
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
Chloride
Acetone
1,4-
Dloxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-27-86
(11.6 + 1.7)
(10.6 + 1.0)
52
(15.0 + 2.1)
(18. 1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + 1.1)
(10.6 + 1.0)
3-27-86
(20.1 + 1.8)
(20.2 + 1.2)
52
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-27-86
(8.30 + 0.9)
(9.20 + 0.5)
52
(21.5 + 2.2)
(20.8 + 1.1)
150
(16.3 + 2.2)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-27-86
(12.0 + 3.0)
(14.0 + 3.0)
52
(47.0 + 14)
(47.0 + 8.0)
150
(13.0 -f 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-27-86
(16.0 + 8.0)
(15.0 + 6.0)
52
(42.0 + 21)
(42.0 + 17)
150
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-27-86
(12.7 + 1.6)
(13.2 + 1.1)
52
(10.3 + 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 _+ 0.6)
385
(13.4 + 1.1)
(13.2 + 1.1)
3-27-86
(7.90 + 1.1)
(8.10 + 0.5)
52
(11.4 + 1.4)
(11.2 + 0.7)
150
(11.8 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using N6S primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary s tandard was analyzed as an internal quality con trol on each day of RTI analys is.
**** All RTI ana lyses were performed using cryogenic preconcen tra tlon fo1lowed by GC/FIU.
-------
STABILITY STUDY FOR CROUP III COMPOUNDS*
Cylinder III-A4
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(10.0)
4-15-85
(9.90)
6-3-85
(9.40)
Freon
113
(10.1)
4-15-85
(10.2)
6-3-85
(9.70)
Vinylidiene
Chloride
MANUFACTURER
(10.3)
4-15-85
(10.2)
6-3-85
(11.8)
Ace tone
ANALYSIS
(33.0)
4-15-85
(23.0)
6-3-85
(22.0)
1,4-
Dioxane
(30.0)
4-15-85
(33.0)
6-3-85
(29.0)
Toluene
(30.3)
4-15-85
(29.7)
6-3-85
(29.5)
Chloro-
benzene
(3.03)
4-15-85
(32.8)
6-3-85
(33.1)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-9-86
(9.20 -t- 1.4)
70
(8.50 + 1.2)
150
(7.60 + 1.4)
385
(7.20 + 1.3)
3-9-86
(10.2 + 1.4)
70
(10.1 + 1.0)
150
(10.3 + 1.3)
385
(11.3 + 1.4)
3-9-86
(10.4 + 1.0)
70
(10. 9.+ 1.1)
150
(11.7 + 1.6)
385
(12.8 + 1.8)
3-9-86
(25.0 + 6.0)
70
(28.0 + 8.0)
150
(24.7 + 7.7)
385
(30.4 + 9.4)
3-9-86
(30.0 + 17)
70
(29.0 + 15)
150
(33.7 + 11)
385
(31.8 + 10)
3-9-86
(29.0 + 3.4)
70
(30.8 + 3.5)
150
(33.5 -1- 2.3)
385
(31.4 + 2.2)
3-9-86
(32,1 + 3.7)
70
(31.4 + 3.8)
150
(30.8 + 5.2)
385
(30.2 + 4.8)
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder III-A4
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
Chloride
Ace tone
1,4-
Dloxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-9-86
(11.9 + 1.7)
(10.6 + 1.0)
70
(15.0 + 2.1)
(18.1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + l.l)
(10.6 + 1.0)
3-9-86
(20.4 + 1.8)
(20.2 + 1.2)
70
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-8-86
(8.80 + 0.9)
(9.20 + 0.5)
70
(21.5 + 2.2)
(20.8 + 1.1)
150
(16.3 + '2.2)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-9-86
(11.0 + 3.0)
(14.0 + 3.0)
70
(47.0 + 14)
(47.0 + 8.0)
150
(13.0 _+ 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-9-86
(14.0 + 8.0)
(15.0 + 6.0)
70
(42.0 + 21)
(42.0 + 17)
150
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-9-86
(13.5 + 1.6)
(13.2 + 1.2)
70
(10.3 + 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 + 0.6)
385
(13.4 + 1.1)
(13.2 + 1.1)
3-9-86
(8.10 + 1.1)
(8.10 + 0.5)
70
(11.4 -f 1.4)
(11.2 + 0.7)
150
(11.8 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8. 10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentratlon followed by GC/FID.
-------
STABILITY STUDY FOR CROUP III COMPOUNDS*
Cylinder III-A5
ACTIVITY
Theoretical! PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(10.1)
4-12-85
(9.30)
5-29-85
(9.60)
Freon
113
(10.2)
4-12-85
(10.0)
5-29-85
(9.80)
Vinylidiene
Chloride
MANUFACTURER
(10.1)
4-12-85
(8.70)
5-29-85
(9.30)
Ace tone
ANALYSIS
(10.0)
4-12-85
(9.40)
5-29-85
(9.30)
1,4-
Dioxane
(10.1)
4-12-85
(9.00)
5-29-85
(8.60)
Toluene
(10.1)
4-12-85
(9.00)
5-29-85
(9.20)
Chloro-
benzene
(10.1)
4-12-85
(9.70)
5-29-85
(8.90)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
on audi t
on audit
151
(7.20 + 1.4)
385
(7.30 + 1.4)
on audit
on audit
151
(10.2 + 1.3)
385
(11.2 + 1.4)
on audi t
on audit
151
(12.5 + 1.7)
385
(9.60 + 1.3)
on aud i t
on audit
151
(6.70 + 2.1)
385
(8.30 + 2.6)
on audi t
on audit
151
(10.1 + 3.3)
385
(10.5 + 3.4)
on audi t
on audit
151
(10.5 + 0.7)
385
(11.1 + 0.8)
on audit
on audit
151
(10.8 + 1.8)
385
(9.80 + 1.6)
(Continued)
-------
STABILITY STUDY FOR CROUP III COMPOUNDS* (Continued)
Cylinder III-A5
• ACTIVITY
COMPOUND
Freon
114
Freon
113
Vinylidiene
Chloride
Ace tone
1,4-
Dioxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-9-86
(11.9 + 1.7)
(10.6 + 1.0)
70
(15.0 + 2.1)
(18.1 + 1.8)
151
(11.9 + 2.2)
(10.8 _+ 1.4)
385
(9.60 + 1.1)
(10.6 + 1.0)
3-9-86
(20.4 + 1.8)
(20.2 + 1.2)
70
(15.8 + 1.6)
(15.7 + 0.9)
151
(15.1 _+ 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-9-86
(8.80 + 0.9)
(9.20 + 0.5)
70
(21.5 + 2.2)
(20.8 + 1.1)
151
(14.8 + 2.0)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-9-86
(11.0 + 3.0)
(14.0 + 3.0)
70
(47.0 + 14)
(47.0 + 8.0)
151
(12.3 + 3.8)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-9-86
(14.0 + 8.0)
(15.0 + 6.0)
70
(42.0 + 21)
(42.0 + 17)
151
(16.5 + 5.4)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-9-86
(13.5 + 1.6)
(13.2 + 1.2)
70
(10.3 + 1.2)
(10.8 + 0.9)
151
(9.60 + 0.7)
(9.90 -f 0.6)
385
(13.4 + 1.1)
(13.2 H- 1.1)
3-9-86
(8.10 + 1.1)
(8.10 + 0.5)
70
(11.4 + 1.4)
(11.2 + 0.7)
151
(12.0 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentratlon followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A6
>
1—'
NJ
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(30.0)
7-23-85
(28.6)
8-27-85
.(31.6)
Freon
113
(10.0)
7-23-85
(9.60)
8-27-85
(9.10)
Vinylldlene
Chloride
MANUFACTURER
(30.9)
7-23-85
(29.6)
8-27-85
(29.8)
Acetone
ANALYSIS
(10.0)
7-23-85
(8.00)
8-27-85
(8.00)
1,4-
Dloxane
(30.0)
7-23-85
(26.0)
8-27-85
(26.0)
Toluene
(10.2)
7-23-85
(8.60)
8-27-85
(8.70)
Chloro-
benzene
(30.0)
7-23-85
(30.4)
8-27-85
(31.0)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-27-86
(23.7 + 3.4)
52
(21.4 + 3.0)
150
(25.7 + 4.9)
on audit
3-27-86
(9.70 + 0.9)
52
(10.1 + 1.0)
150
(9.60 + 1.2)
on audit
3-27-86
(30.1 + 3.0)
52
(32.4 _+ 3.3)
150
(31.8 + 4.4)
on audit
3-27-86
(10.0 + 3.0)
52
(10.0 + 3.0)
150
(9.90 + 3.1)
on audit
3-27-86
(26.0 + 15)
52
(29.0 + 15)
150
(33.5 + 11.0)
on audit
3-27-86
(9.80 _+ l.l)
52
(10.5 4; 1.2)
150
(10.2 jf 0.7)
on audit
3-27-86
(30.2 + 3.4)
52
(30.3 + 3.6)
150
(29.8 + 5.0)
on audit
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder III-A6
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
. Chloride
Ace tone
1,4-
Dloxane
Toluene
Chloro- :
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
•
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-27-86
(11.6 + 1.7)
(10.6 + 1.0)
52 .
(15.0 + 2.1)
(18.1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + l.l)
(10.6 + 1.0)
3-27-86
(20.1 + 1.8)
(20.2 + 1.2)
52
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-27-86
(8.30 + 0.9)
(9.20 + 0.5)
52
(21.5 + 2.2)
(20.8 + 1.1)
150
(16.3 + 2.2)
(16.0 + 1.0)
385*
(9.70 + 0.5)
(9.20 + 0.5)
3-27-86
(12.0 + 3.0)
(14.0 + 3.0)
52
(47.0 + 14)
(47.0 + 8.0)
150
(13.0 + 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-27-86
(16.0 + 8.0)
(15.0 + 6.0)
52
(42.0 _+ 21)
(42.0 + 17)
rso
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-27-86
(12.7 + 1.6)
(13.2 + 1. I)
52
(10.3 + 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 + 0.6)
385
(13.4 4; 1.1)
(13.2 + 1.1)
3-27-86
(7.90 + 1.1)
(8.10 + 0.5)
52
(11.4 + 1.4)
(11.2 + 0.7)
150
(11.8 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8. 10 + 0.4)
OJ
O
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentration followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A7
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(10. 0)
4-10-85
(9.90)
5-22-85
(9.80)
Freon
113
(10.2)
4-10-85
(9.60)
5-22-85
(9.80)
Vinylldiene
Chloride
MANUFACTURER
(10. 1)
4-10-85
(8.90)
5-22-85
(9.30)
Ace tone
ANALYSIS
(10.0)
4-10-85
(11.0)
5-22-85
(8.00)
1.4-
Uloxane
(10.0)
4-10-85
(9.00)
5-22-85
(7.00)
Toluene
(10.1)
4-10-85
(9.00)
5-22-85
(9.00)
Chloro-
benzene
(10.1)
4-10-85
(9.70)
5-22-85
(8.80)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-9-86
(9.10 + 1.3)
72
(8.60 + 1.2)
150
(8.30 + 1.6)
385
(7.20 + 1.4)
3-9-86
(10.2 + 1.0)
72
(10. 0 + 1.0)
150
(10.3 + 1.3)
385
(11.3 + 1.4)
3-9-86 .
(8.70 + 0.9)
72 ,
(9.50 jh 1.0)
150
(8.90 + 1.2)
385
(9.60 + 1.2)
3-9-86
(9.00 + 3.0)
72
(9.00 + 3.0)
150
(9.90 + 3.1)
385
(8.70 + 2.7)
3-9-86
(10.0 + 6.0)
72
(11.0 + 6.0)
150
(13.0 + 4.2)
385
(10.8 + 3.5)
3-9-86
(10.6 + 1.3)
72
(10.6 + 1.2)
150
(10.9 + 0.8)
385
(11. I + 0.8)
3-9-86
(U.I + 1.5)
72
(10.9 + 1.3)
150
(11.7 + 2.0)
385
(10.8 + 1.7)
(Continued)
-------
STABILITY STUDY FOR GROUP HI COMPOUNDS* (Continued)
Cylinder III-A7
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vinylldiene
Chloride
Acetone
1,4-
Dloxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-9-86
(11.9 + 1.7)
(10.6 + 1.0)
72
(14.6 + 2.0)
(18.1 + 1.8)
150
(8.70 + 1.6)
(10.8 + 1.4)
385
(9.60 + 1.1)
(10.6 + 1.0)
3-9-86
(20.4 + 1.8)
(20.2 + 1.2)
72
(15.8 + 1.6)
(15.7 + 0.9)
150
(14.8 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-9-86
(8.80 + 0.9)
(9.20 + 0.5)
72
(21.5 + 2.2)
(20.8 + 1.1)
150
(16.3 + 2.2)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-9-86
(11.0 + 3.0)
(14.0 + 3.0)
72
(48.0 + 14)
(47.0 + 8.0)
150
(13.0 + 4.0)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-9-86
(14.0 + 8.0)
(15.0 + 6.0)
72
(42.0 + 21)
(42.0 _+ 17)
150
(20.5 + 6.7)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-9-86
(13.5 + 1.6)
(13.2 + 1.1)
72
(10.5 + 1.2)
(10.8 + 0.9)
150
(10.0 + 0.7)
(9.90 + 0.6)
385
(13.4 + 1.1)
(13.2 + 1.1)
3-9-86
(8.10 + 1.1)
(8.10 + 0.5)
72
(11.0 + 1.4)
(11.2 + 0.7)
150
(11.8 + 2.0)
(12.3 _+ 0.7)
385
(7.80 + 0.4)
(8. 10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentratlon followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A8
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(10.0)
4-10-85
(9.90)
5-22-85
(9.80)
Freon
113
(10.2)
4-10-85
(9.60)
5-22-85
(9.80)
Vinylidiene
Chloride
MANUFACTURER
(10. I)
4-10-85
(8.90)
5-22-85
(9.30)
Acetone
ANALYSIS
(10.0)
4-10-85
(11.0)
5-22-85
(8.00)
1,4-
Dioxane
(10.0)
4-10-85
(9.00)
5-22-85
(7.00)
Toluene
(10.1)
4-10-85
(9.00)
5-22-85
(9.00)
Chloro-
benzene
(10.1)
4-10-85
(9.70)
5-22-85
(8.80)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-9-86
(9.10 + 1.3)
70
(8.60 + 1.2)
151
(9.30 + 1.8)
385
(7.80 + 1.5)
3-9-86.
(10.0 + 1.0)
70
(10.1 + 1.0)
151.
(9.70 + 1.3)
385
(10.3 + 1.5)
3-9-86
(8.70 + 0.9)
70
(9.30 + 0.9)
151
(8.50 + 1.1)
385
(10.6 + 1.3)
3-9-86
(9.00 + 3.0)
70
(11.0 + 3.0)
151
(8.80 + 2.7)
385
(9.00 + 2.8)
3-9-86
(10.0 + 6.0)
70
(12.0 + 6.0)
151
(10.5 + 3.4)
385
(10.6 + 3.4)
3-9-86
(10.3 + 1.2)
70
(10.6 + 1.2)
151
(10.7 + 0.7)
385
(11.3 + 0.7)
3-9-86
(10.9 + 1.4)
70
(12.1 + 1.5)
151
(10.8 + 1.8)
385
(11.2 + 1.8)
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder III-A8
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vlnylldlene
Chloride
Ace tone
1,4-
Dioxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-9-86
(11.9 + 1.7)
(10.6 + 1.0)
70
(15.0 + 2.1)
(18.1 + 1.8)
151
(11.9 + 2.2)
(10.8 + 1.4)
385
(9.60 + l.l)
(10.6 + 1.0)
3-9-86
(20.4 + 1.8)
(20.2 + 1.2)
70
(15.8 + 1.6)
(15.7 + 0.9)
151
(15.1 + 1.9)
(15.4 + 1.6)
385
(20,.9 + 1.2)
(20.2 + 1.2)
3-9-86
(8.80 + 0.9)
(9.20 -t- 0.5)
70
(21.5 _+ 2.2)
(20.8 + 1.1)
151
(14.8 + 2.0)
(16.0 + 1.0)
385
(9.70 + 0.5)
(9.20 + 0.5)
3-9-86
(11.0 + 3.0)
(14.0 + 3.0)
70
(47.0 + 14)
(47.0 -f 8.0)
151
(12.3 + 3.8)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-9-86
(14.0 + 8.0)
(15.0 + 6.0)
70
(42.0 + 21)
(42.0 + 17)
151
(16.5 + 5.4)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-9-86
(13.5 + 1.6)
(13.2 + 1.1)
70
(10.3 + 1.2)
(10.8 + 0.9)
151
(9.60 + 0.7)
(9.90 + 0.6)
385
(13.4 + l.l)
(13.2 + 1.1)
3-9-86
(8. 10 + 1.1).
(8.10 + 0.5)
70
(11.4 + 1.4)
(11.2 + 0.7)
151
(12.0 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentratlon followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A9
ACTIVITY
1
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
COMPOUND
Freon
114
(30.0)
4-23-85
(27.6)
6-4-85
(27.3)
Freon
113
(30.0)
4-23-85
(28.9)
6-4-85
(28.7)
Vinylidiene
Chloride
MANUFACTURER
(30.1)
4-23-85
(28.0)
6-4-85
(27.2)
Ace tone
ANALYSIS
(10.0)
4-23-85
(10.0)
6-4-85
(5.00)
1,4-
Dioxane
(10.0)
4-23-85
(9.00)
6-4-85
(9.00)
Toluene
(10.1)
4-23-85
(8.80)
6-4-85
(8.80)
Chloro-
benzene
(10.1)
4-23-85
(9.60)
6-4-85
(8.30)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
4th Analysis Day**
PPB
3-27-86
(24.8 + 3.5)
on audit
151
(29.7 + 5.6)
on audit
3-27-86
(31. 1+3.1)
on audit
151
(31.8 +4.1)
on audit
3-27-86
(31.3 + 3.1)
on audit
151
(33.0 + 4.6)
on audit
3-27-86
(10.0 + 3.0)
on audi t
151
(6.70 + 2. I)
on audit
3-27-86
(10.0 + 5.0)
on audi t
151
(14.9 + 4.9)
on audit
3-27-86
(10.1 + 1.2)
on audit
151
(11.6 + 0.8)
on audit
3-27-86
(10.2 + 1.4)
on audit
151
(11. I + 1.9)
on audit
(Continued)
-------
STABILITY STUDY FOR GROUP III COMPOUNDS* (Continued)
Cylinder I11-A9
ACTIVITY
COMPOUND
Freon
114
Freon
113
Vinylldlene
Chloride
Acetone
1,4-
Dloxane
Toluene
Chloro-
benzene
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Conccn. PPB
4th Analysis Day
PPB
NBS Concen. PPB
3-27-86
(11.7 + 1.7)
(10.6 + 1.0)
52
(15.0 + 2.1)
(18.1 + 1.8)
151
(11.9 + 2.2)
(10.8 -1- 1.4)
385
(9.60 + l.l)
(10.6 + 1.0)
3-27-86
(20.5 + 1.8)
(20.2 + 1.2)
52
(15.8 + 1.6)
(15.7 + 0.9)
151
(15.1 + 1.9)
(15.4 + 1.0)
385
(20.9 + 1.2)
(20.2 + 1.2)
3-27-86
(8.50 + 0.9)
(9.20 + 0.5)
52
(21.5 + 2.2)
(20.8 + 1.1)
151
(14.8 + 2.0)
(16.0 + 1.0)
385
(9.70 + 0.50
(9.20 + 0.5)
3-27-86
(12.0 + 3.0)
(14.0 + 3.0)
52
(47.0 + 14)
(47.0 + 8.0)
151
(12.3 + 3.8)
(13.8 + 2.2)
385
(11.4 + 2.4)
(14.0 + 3.0)
3-27-86
(14.0 + 8.0)
(15.0 + 6.0)
52
(42.0 + 21)
(42.0 + 17)
151
(16.5 + 5.4)
(15.9 + 3.0)
385
(14.3 + 5.7)
(15.0 + 6.0)
3-27-86
(14.2 + 1.6)
(13.2 + 1.1)
52
(10.3 + 1.2)
(10.8 + 0.9)
151
(9.60 + 0.7)
(9.90 -f 0.6)
385
(13.4 + 1.1)
(13.2 + l.l)
3-27-86
(8.00 + 1.1)
(8.10 + 0.5)
52
(11.4 + 1.4)
(11.2 + 0.7)
151
(12.0 + 2.0)
(12.3 + 0.7)
385
(7.80 + 0.4)
(8.10 + 0.4)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcen tra tlon followed by GC/F1D.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A10
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(140)
5-9-86
(140)
Freon
113
(140)
5-9-86
(138)
Vlnylldlene
Chloride
MANUFACTURER
(120)
5-9-86
(117)
Ace tone
ANALYSIS
(100)
5-9-86
(94.2)
1,4-
Dloxane
(100)
5-9-86
(107)
Toluene
(150)
5-9-86
(152)
Chloro-
benzene
(150)
5-9-86
(181)
RTI ANALYSIS****
1st Analysis Date
1 PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
5-21-86
(137 + 19)
97
(125 + 23)
331
(141 + 25)
5-21-86
(152 + 15)
97
(143 + 18)
331
(159 + 19)
5-21-86
(122 + 12)
97
(123 •+• 17)
331
(131 + 17)
5-21-86
(112 + 33)
97
(114 + 35)
331
(107 + 33)
5-21-86
(114 + 57)
97
(125 + 41)
331
(145 + 46)
5-21-86
(159 + 18)
97
(161 + 11)
331
(167 + 12)
5-21-86
(153 + 19)
97
(152 + 26)
331
(173 + 29)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
5-21-86
(14.6 + 2.0)
(18.1 + 1.8)
97
(11.9 + 2.2)
(10.8 + 1.4)
331
(11.0 + 1.0)
(10.6 + 1.0)
5-21-86
(15.8 + 1.6)
(15.7 + 0.9)
97
(15.1 + 1.9)
(15.4 + 1.0)
331
(21.0 + 1.3)
(20.2 + 1.2)
5-21-86
(21.5 + 2.2)
(20.8 + l.l)
97
(14.8 + 2.0)
(16.0 + 1.0)
331
(9.60 + 0.52)
(9.20 + 0.5)
5-21-86
(48.0 + 14)
(47.0 + 8.0)
97
(12.3 + 3.8)
(13.8 -1- 2.2)
331
(12.1 + 2.6)
(14.0 + 3.0)
5-21-86
(42.0 + 21)
(42.0 4- 17)
97
(16.5 + 5.4)
(15.9 + 3.0)
331
(15.9 + 3.2)
(15.0 + 3.0)
5-21-86
(10.5 + 1.2)
(10.8 + 0.9)
97
(9.60 + 0.7)
(9.90 + 0.6)
331
(13.9 + 1.2)
(13.2 + l.l)
5-21-86
(11.0 + 1.4)
(11.2 + 0.7)
97
(12.0 + 2.0)
(12.3 -f 0.7)
331
(8.80 + 0.6)
(8.10 -1- 0.5)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of KTI analysis.
**** All RTI analyses were performed using cryogenic preconcentration followed by GC/FID.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder Ill-All
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(140)
5-9-86
(139)
Freon
113
(140)
5-9-86
(140)
Vlnylidlene
Chloride
MANUFACTURER
(140)
5-9-86
(142)
Acetone
ANALYSIS
(120)
5-9-86
(111)
1,4-
Dloxane
(120)
5-9-86
(116)
Toluene
(150)
5-9-86
(155)
Chloro-
benzene
(150)
5-9-86
(182)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
5-21-86
(139 + 20)
97
(131 + 24)
331
(141 + 25)
5-21-86
(155 + 15)
97
(148 + 19)
331
(156 + 19)
5-21-86
(148 + 15)
97
(152 + 20)
331
(154 + 20)
5-21-86
(109 + 32)
97
(93.0 4 29)
331
(89.0 + 24)
5-21-86
(134 + 67)
97
(152 + 49)
331
(162 + 52)
5-21-86
(169 + 19)
97
(169 + 12)
331
(172 + 12)
5-21-86
(167 + 20)
97
(156 + 26)
331
(169 + 27)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
5-21-86
(14.6 + 2.0)
(18.1 + 1.8)
97
(11.9 -1- 2.2)
(10.8 + 1.4)
331
(11.0 + 1.0)
(10.6 + 1.0)
5-21-86
(15.8 + 1.6)
(15.7 + 0.9)
97
(15.1 + 1.9)
(15.4 + 1.0)
331
(21.0 + 1.3)
(20.2 _+ 1.2)
5-21-86
(21.5 + 2.2)
(20.8 + 1.1)
97
(14.8 + 2.0)
(16.0 + 1.0)
331
(9.60 + 0.5)
(9.20 + 0.5)
5-21-86
(48.0 + 14)
(47.0 + 8.0)
97
(12.3 + 3.8)
(13.8 + 2.2)
331
(12.1 + 2.6)
(14.0 + 3.0)
5-21-86
(42.0 + 21)
(42.0 + 17)
97
(16.5 + 5.4)
(15.9 + 3.0)
331
(15.9 + 3.2)
(15.0 + 3.0)
5-21-86
(10.5 + 1.2)
(10.8 + 0.9)
97
(9.60 + 0.7)
(9.90 + 0.6)
331
(13.9 + 1.2)
(13.2 + 1.1)
5-21-86
(11.0 + 1.4)
(11.2 + 0.7)
97
(12.0 + 2.0)
(12.3 + 0.7)
331
(8.80 + 0.6)
(8.10 + 0.5)
U)
00
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTi analysis.
**** All RTI analyses were performed using cryogenic preconcentratlon followed by GC/F1U.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A12
u>
VO
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(140)
5-9-86
(143)
Freon
113
(140)
5-9-86
(139)
Vlnylldlene
Chloride
MANUFACTURER
(140)
5-9-86
(138)
o
Ace tone
ANALYSIS
(120)
5-9-86
(118)
1,4-
Dioxane
(120)
5-9-86
(113)
Toluene
(150)
5-9-86
(148)
Chloro-
benzene
(150)
5-9-86
(175)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
5-21-86
(138 + 20)
97
(128 + 24)
331
(142 + 26)
5-21-86
(151 + 15)
97
(145 + 19)
331
(155 + 20)
5-21-86
(148 + 15)
97
(152 + 21)
331
(157 + 22)
5-21-86
(143 + 43)
97
(152 + 47)
331
(144 + 44)
5-21-86
(134 + 67)
97
(154 + 50)
331
(164 + 53)
5-21-86
(163 + 18)
97
(165 + 11)
331
(162 + 11)
5-21-86
(157 + 19)
97
(157 + 27)
331
(161 _+ 27)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Conce.n. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
3rd Analysis Day
PPB
NBS Concen. PPB
5-21-86
(14.6 + 2.0)
(18.1 + 1.8)
97
(11.9 + 2.2)
(10.8 + 1.4)
331
(11.0 + 1.0)
(10.6 + 1.0)
5-21-86
(15.8 + 1.6)
(15.7 + 0.9)
97
(15.1 + 1.9)
(15.4 + 1.0)
331
(21.0 + 1.3)
(20.2 + 1.2)
5-21-86
(21.5 + 2.2)
(20.8 ± 1.1)
97
(14.8 + 2.0)
(16.0 + 1.0)
331
(9.60 + 0.5)
(9.20 + 0.5)
5-21-86
(48.0 + 14)
(47.0 + 8)
97
(12.3 + 3.8)
(13.8 + 2.2)
331
(12.1 + 2.6)
(14.0 + 3.0)
5-21-86
(42.0 + 21)
(42.0 + 17)
97
(16.5 + 5.4)
(15.9 + 3.0)
331
(15.9 + 3.2)
(15.0 + 3.0)
5-21-86
(10.5 + 1.2)
(10.8 + 0.9)
97
(9.60 + 0.7)
(9.90 + 0.6)
331
(13.9 + 1.2)
(13.2 + 1. I)
5-21-86
(11.0 + 1.4)
(11.2 + 0.7)
97
(12.0 + 2.0)
(12.3 + 0.7)
(8.80 + 0.6)
(8.10 + 0.5)
* Ca L ibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analys is.
**** All RTI analyses were performed using cryogenic preconcentration followed by GC/F1U.
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A13
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
Freon
114
(10.0)
4/28/87
(9.60)
. Freon
113
(20.3)
4/28/87
(19.1)
Vlnylldlene
Chloride
MANUFACTURER
(10.2)
4/28/87
(9.89)
COMPOUND
Ace tone
ANALYSIS
(20.4)
4/28/87
(20.5)
1,4-
Dloxane
(20.4)
4/28/87
(18.0)
Toluene
(10.3)
4/28/87
(10.8)
Chloro-
benzene
(10.2)
4/28/87
(12.1)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/10/87
(11.0 + 2.8)
25
NA
7/10/87
(22.0 -4- 4.4)
25
(20.2 + 4.1)
7/10/87
(11.9 + 2.5)
25
(11.2 + 2.4)
7/10/87
(17.8 _+ 3.9)
25
(17.2 + 3.8)
7/10/87
(22.9 + 5.1)
25
(22.8 + 5.1)
7/10/87
(11.1 + 1.0)
25
(11.2 + 1.0)
7/10/87
(10.9 + 1.1)
25
(11.0 + 1.2)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen.' PPB
7/10/87
(11.4 + 2.9)
(10.6 + 1.2)
25
NA
(10.6 + 1.2)
7/10/87
(16.4 + 3.3)
(15.4 + 1.0)
25
(15.4 + 3.1)
(15.4 + 1.0)
7/10/87
(15.7 + 3.3)
(16.0 + 1.0)
25
(15.1 + 3.2)
(16.0 + 1.0)
7/10/87
(13.8 + 3.1)
(13.8 + 2.2)
25
NA
(13.8 + 2.2)
7/10/87
(16.7 + 3.7)
(15.9 + 3.0)
25
(15.9 + 3.5)
(15.9 + 3.0)
7/10/87
(10.2 + 0.9)
(9.90 + 0.6)
25
(9.48 + 0.8)
(9.90 + 0.6)
7/10/87
(12.2 + 1.3)
(12.3 + 0.7)
25 '
(11.8 + 1.2)
(12.3 + 0.7)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/F1D.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A14
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
Freon
114
(10.0)
4/29/87
(9.92)
Freon
113
(10.0)
4/29/87
(9.88)
Vlnylldlene
Chloride
MANUFACTURER
(10.2)
4/29/87
(9.91)
COMPOUND
Ace tone
ANALYSIS
(20.0)
4/29/87
(17.7)
1,4-
Dloxane
(20.0)
4/29/87
(17.0)
Toluene
(10.1)
4/29/87
(10.3)
Chloro-
benzene
(10.0)
4/29/87
(11.7)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/13/87
NA
21
NA
7/13/87
(9.73 + 2.0)
21
(10.4 +' 2. I)
7/13/87
(9.54 + 2.0)
21
(10.4 + 2.2)
7/13/87
(16.8 + 3.7)
21
(16.3 + 3.6)
7/13/87
(18.4 + 4.1)
21
(18.8 + 4.2)
7/13/87
(10.3 + 0.9)
21
(10.1 + 0.9)
7/13/87
(10.6 + 1.1)
21
(10.3 + 1.1)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/13/87
NA
(10.6 + 1.2)
21
NA
(10.6 + 1.2)
7/13/87
(16.1 + 3.2)
(15.4 + 1.0)
21
(15.4 + 3.1)
(15.4 + 1.0)
7/13/87
(16.2 + 3.4)
(16.0 + 1.0)
21
(15.1 + 3.2)
(16.0 + 1.0)
7/13/87
(14.5 ± 3.2)
(13.8 + 2.2)
21
(12.8 + 2.8)
(13.8 + 2.2)
7/13/87
(16.7 + 3.7)
(15.9 + 3.0)
21
(15.9 + 3.5)
(15.9 + 3.0)
7/13/87
(10.9 + 0.9)
(9.90 + 0.6)
21
(9.48 + 0.8)
(9.90 + 0.6)
7/13/87
(12.6 + 1.3)
(12.3 + 0.7)
21
(11.8 + 1.2)
(12.3 + 0.7)
* Calibra tton was pe rformed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internaI qua 1i ty con trol on each day of RTI ana lysis.
**** ^ 11 RTI ana lyses were performed using a'u tomated cryogenic preconcentration with c ry of oc using fol lowed by GC/FID.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A15
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(10.0)
4/29/87
(9.93)
Freon
113
(20.7)
4/29/87
(19.3)
Vinylldlene
Chloride
MANUFACTURER
(10.4)
4/29/87
(9.99)
Ace tone
ANALYSIS
(20.7)
4/29/87
(18.0)
1,4-
Dloxane
(20.7)
4/29/87
(17.0)
Toluene
(10.4)
4/29/87
(10.8)
Chloro-
benzene
(10.3)
4/29/87
(11.8)
I RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/16/87
(11.1+ 2.8)
19
NA
7/16/87
NA
19
NA
7/16/87
NA
19
(9.40 _+ 2.0)
7/16/87
(16.6 + 3.7)
19
(15.8 + 3.5)
7/16/87
(18.9 + 4.2)
19
(19.2 + 4.3)
7/16/87
(10.0 + 0.9)
19
(10. 1 + 0.9)
7/16/87
(9.71 + 1.0)
19
(10.2 + 1.1)
RTI QUALITY CONTROL***
1st Analysis Da te
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/16/87
(11.4 + 2.9)
(10.6 + 1.2)
19
NA
(10.6 + 1.2)
7/16/87
NA
(15.4 + 1.0)
19
(15.4 + 3. 1)
(15.4 + 1.0)
7/16/87
NA
(16.0 + 1.0)
19
(15.1 + 3.2)
(16.0 + 1.0)
7/16/87
(15.1 + 3.3)
(13.8 + 2.2)
19
(12.8 + 2.8)
(13.8 + 2.2)
7/16/87
(16:3 + 3.6)
(15.9 + 3.0)
19
(15.9 + 3.5)
(15.9 + 3.0)
7/16/87
(10.3 + 0.9)
(9.90 + 0.6)
19
(9.48 + 0.8)
(9.90 j; 0.6)
7/16/87
(12.6 + 1.3)
(12.3 + 0.7)
19
(11.8 + 1.2)
(12.3 + 0.7)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using automated cryogenic preconcentra tlon with cryofocuslng followed by GC/FID.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP III COMPOUNDS*
Cylinder III-A16
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(10.0)
4/28/87
(9.24)
Freon
113
(20.3)
4/28/87
(19.1)
Vinylidiene
Chloride
MANUFACTURER
(10.2)
4/28/87
(10.0)
Ace tone
ANALYSIS
(20.3)
4/28/87
(18.7)
1,4-
Dioxane
(20.3)
4/28/87
(18.4)
Toluene
(10.2)
4/28/87
(10.7)
Chloro-
benzene
(10.1)
4/28/87
(12.0)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/16/87
(11.3 -f 2.9)
19
(10.6 + 2.7)
7/16/87
(21.3 + 4.3)
19
(21.3 + 4.3)
7/16/87
(11.5 + 2.4)
19
NA
7/16/87
(16.7 + 3.7)
19
(17.5 + 3.9)
7/16/87
(19.0 + 4.2)
19
(20.4 + 4.6)
7/16/87
(9.58 + 0.8)
19
(10.0 + 0.9)
7/16/87
(10.0 + 1.1)
19
(10.2 + 1.1)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen'. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/16/87
(11.4 -t 2.9)
(10.6 + 1.2)
19
NA
(10.6 + 1.2)
7/16/87
NA
(15.4 + 1.0)
19
(15.4 + 3.1)
(15.4 + 1.0)
7/16/87
NA
(16.0 + 1.0)
19
(15.1 + 3.2)
(16.0 + 1.0)
7/16/87
(15.2 + 3.5)
(13.8 + 2.2)
19
(12.8 + 2.8)
(13.8 + 2.2)
7/16/87
(16.3 + 3.6)
(15.9 + 3.0)
19
(15.9 + 3.5)
(15.9 + 3.0)
7/16/87
(10.3 + 0.9)
(9.90 + 0.6)
19
(9.48 + 0.8)
(9.90 + 0.6)
7/16/87
(12.6 + 1.3)
(12.3 + 0.7)
19
(11.8 + 1.2)
(12.3 + 0.7)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an Internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
NA = Not Analyzed
-------
STABILITY STUDY FOR CROUP III COMPOUNDS*
Cylinder III-A17
-P-
-p-
ACTIVITY
Theoretical PPB
1st Analysis Date
PPB
COMPOUND
Freon
114
(10. 0)
4/27/87
(9.10)
Freon
113
(20.3)
4/27/87
(19.1)
Vinylldiene
Chloride
MANUFACTURER
(10.2)
4/27/87
(9.94)
Acetone
ANALYSIS
(20.4)
4/27/87
(20.0)
1,4-
Dioxane
(20.4)
4/27/87
(18.4)
Toluene
(10.3)
4/27/87
(10.3)
Chloro-
benzene
(10.2)
4/27/87
(U.l)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/16/87
NA
18
(10.0 + 2.5)
7/16/87
NA
18
(20.6 + 4.1)
7 716/87
NA
18
(10.6 + 2.2)
7/16/87
(17.8 + 4.0)
18
(18.0 + 3.9)
7/16/87
(20.9 + 4.7)
18
(21.6 + 4.8)
7/16/87
(10.8 + 0.9)
18
(10.8 + 0.9)
7/16/87
(10.7 + 1.1)
18
(10.8 + 1.1)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/16/87
(11.4 + 2.9)
(10.6 + 1.2)
18
NA
(10.6 + 1.2)
7/16/87
NA
(15.4 '+ 1.0)
18
(15.4 + 3.1)
(15.4 _+ 1.0)
7/16/87
MA
(16.0 + 1.0)
18
(15.1 + 3.2)
(16.0 + 1.0)
7/16/87
(15. 1 + 3.3)
(13.8 + 2.2)
18
(12.8 + 2.8)
(13.8 + 2.2)
7/16/87
(16.3 + 3.6)
(15.9 + 3.0)
18
(15.9 + 3.5)
(15.9 + 3.0)
7/16/87
(10.7 + 0.9)
(9.90 + 0.6)
18
(9.48 + 0.8)
(9.90 + 0.6)
7/16/87
(12.6 + 1.3)
(12.3 + 0.7)
18
(11.8 + 1.2)
(12.3 + 0.7)
* Calibration was performed using NBS primary standard.
** Number of days after 1st RTI analysis date.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using automated cryogenic preconcentratlon with cryofocusing followed by GC/FID.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A1
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
8/14/86
(10.1)
2/26/87
(10.8 + 0.7)
169
(10.2 + 0.7)
(16)
8/14/86
(10.3)
RTI
2/26/87
NA
169
NA
(35)
8/14/86
(29.7)
ANALYSIS***
2/26/87
NA
169
NA
(30)
8/14/86
(25.0)
2/26/87
(30.9 + 3.0)
169
(28.2 + 2.6)
(10)
8/14/86
(8.42)
2/26/87
(9.70 + 0.7)
169
(9.73 + 0.7)
(30)
8/14/86
(31.2)
2/26/87
(31.5 + 3.5)
169
(31.6 + 3.7)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
2/26/87
(18.8 + 1.3)
(19.0 + 1.0)
169
(20.0 + 1.4)
(19.0 + 1.0)
2/26/87
NA
(7.70 + 1.5)
169
NA
(7.70 + 1.5)
2/26/87
NA
(6.50 + 1.3)
169
NA
(6.50 + 1.3)
2/26/87
(18.8 + 1.7)
(19.8 + 1.8)
169
(19.6 + 1.8)
(19.8 + 1.8)
2/26/87
(20.1 + 1.4)
(19.0 + 1.2)
169
(20.0 + 1.4)
(19.0 + 1.2)
2/26/87
(19.4 + 2.1)
(19.1 + 1.9)
169
(18.9 + 2.1)
(19.1 + 1.9)
-P-
Ul
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis,
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A2
ACTIVITY
COMPOUND
1 ,3-Bu tadiene
Ethylene
Oxide
Propylene
Oxide
Methylene
Chloride
Aery Ion itrile
Or tho-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(30)
9/17/86
(32.2)
5/07/87
(27.8 + 1.9)
102
(26.7 + 1.8)
(35)
9/17/86
(13.4)
RTI
5/07/87
NA
102
NA
(15)
9/17/86
(12.3)
ANALYSIS***
5/07/87
NA
102
NA
(10)
9/17/86
(8.62)
5/07/87
(10.7 + 1.0)
102
(10.8 + 1.0)
(30)
9/17/86
(23.9)
5/07/87
(20.4 + 1.4)
102
(19.6 + 1.4)
(10)
9/17/86
(10.7)
5/07/87
(11.5 + 1.3)
102
(11.6 + 1.3)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/07/87
(21.7 + 1.5)
(19.0 + 1.0)
102
(20.5 + 1.4)
(19.0 + 1.0)
5/07/87
NA
(7.70 + 1.5)
102
NA
(7.70 + 1.5)
5/07/87
NA
(6.50 + 1.3)
102
NA
(6.50 + 1.3)
5/07/87
(20.7 + 1.9)
(19.8 + 1.8)
102
(21.2 + 2.0)
(19.8 + 1.8)
5/07/87
(20.5 + 1.4)
(19.0 + 1.2)
102
(20.0 + 1.4)
(19.0 + 1.2)
5/07/87
(17.6 + 1.9)
(19.1 + 1.9)
102
(18.4 + 2.0)
(19.1 + 1.9)
-P-
ON
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis,
***** Compound unstable.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A3
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propy lene
Oxide
Me thy lene
Chloride
Aery loni trile
Ortho-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
8/05/86
(10.5)
5/04/87
(10.8 + 0.7)
101
NA
(15)
8/05/86
(11.0)
RTI
5/04/87
NA
101
NA
(15)
8/05/86
(15.1)
ANALYSIS***
5/04/87
NA
101
NA
(10)
8/05/86
(10.8)
5/04/87
(10.4 + 1.0)
101
(11.0 + 1.0)
(10)
8/05/86
(7.67)
5/04/87
(10.7 + 0.8)
101
(10.1 + 0.7)
(10)
8/05/86
(9.57)
5/04/87
(11.0 + 1.2)
101
(11.5 + 1.3)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/04/87
(21.8 + 1.5)
(19.0 + 1.0)
101
(20.4 + 1.4)
(19.0 + 1.0)
5/04/87
NA
(7.70 + 1.5)
101
NA
(7.70 + 1.5)
5/04/87
NA
(6.50 + 1.3)
101
NA
(6.50 + 1.3)
5/04/87
(20.6 + 1.9)
(19.8 + 1.8)
101
(19.1 + 1.8)
(19.8 + 1.8)
5/04/87
(18.8 + 1.3)
(19.0 + 1.2)
101
(19.1 + 132)
(19.0 + 1.2)
5/04/87
(18.1 + 2.0)
(19.1 + 1.9)
101
(18.4 + 2.0)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
***** Compound unstable.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A4
ACTIVITY
COMPOUND
1 , 3-Bu tadiene
Ethy lene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
i
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
8/06/86
(10.2)
7/20/87
(11,9 + 0.8)
23
(11.8 + 0.8)
(16)
8/06/86
(12.3)
RTI
7/20/87
NA
23
NA
(37)
8/06/86
(37.8)
ANALYSIS****
7/20/87
NA
23
NA
(32)
8/06/86
(23.9)
7/20/87
(32.8 + 3.0)
23
(33.1 + 3.1)
(11)
8/06/86
(8.84)
7/20/87
(10.1 + 0.7)
23
(10.0 + 0.7)
(32)
8/06/86
(29.4)
7/20/87
(33.1 + 3.7)
23
(33.2 + 3.7)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
7/20/87
(20.0 + 1.4)
(19.0 + 1.0)
23
(19.7 + 1.3)
(19.0 + 1.0)
7/20/87
NA
(7.70 + 1.5)
23
NA
(7.70 + 1.5)
7/20/87
NA
(6.50 + 1.3)
23
NA
(6.50 + 1.3)
7/20/87
(20.0 + 1.8)
(19.8 + 1.8)
23
(18.9 + 1.7)
(19.8 + 1.8)
7/20/87
(18.1 + 1.3)
(19.0 + 1.2)
23
(19.2 + 1.4)
(19.0 + 1.2)
7/20/87
(18.2 + 2.0)
(19.1 + 1.9)
23
(19.4 + 2.1)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** All RTI analyses were performed1 using cryogenic preconcentration with cryofocusing followed by GC/FID.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A5
-P-
vO
ACTIVITY
COMPOUND
1,3-Butadiene
Ethy lene
Oxide
Propy lene
Oxide
Me thy lene
Chloride
Acryloni trlle
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
(6006)
7/09/86
(5692)
10/22/86
(5826 + 220)
91
(5780 + 220)
301
(5800 + 221)
(6002)
7/09/86
(4827)
RTI
10/22/86
(6252 + 235)
91
(5430 + 230)
301
(5538 + 240)
(8038)
7/09/86
(7687)
ANALYSIS****
10/22/86
(8404 + 318)
91
(8080 + 320)
301
(8215 + 330)
(6027)
7/09/86
(6038)
10/22/86
(6267 + 260)
91
(5930 + 250)
301
(6127 + 270)
(8037)
7/09/86
(8057)
10/22/86
(5413 + 310)
91
(5800 + 330)
301
(5729 _+ 320)
(8038)
7/09/86
(8378)
10/22/86
(9122 + 230)
91
(8440 + 210)
301
(8521 + 220)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
3rd Analysis Day**
PPB
NBS Concen. PPB
10/22/86
(2942 + 100)
(2510 + 20)
91
(2500 + 90)
(2510 + 20)
301
(2490 + 87)
(2510 + 20)
10/22/86
(2878 + 130)
(2770 + 80)
91
(2710 -f 110)
(2770 + 80)
301
(2730 + 100)
(2770 + 80)
10/22/86
(2338 + 95)
(2360 + 70)
91
(2380 + 90)
(2360 + 70)
301
(2300 + 80)
(2360 + 70)
10/22/86
(2214 + 98)
(2260 + 80)
91
(2250 + 90)
(2260 + 80)
301
(2225 + 85)
(2260 + 80)
10/22/86
(1996 + 81)
(2020 + 60)
91
(1990 + 80)
(2020 + 60)
301
(2000 + 57)
(2020 + 60)
10/22/86
(1975 + 166)
(1840 + 180)
91
(1910 + 160)
(1840 + 180)
301
(1880 + 156)
(1840 + 180)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** First and 2nd analyses were performed using cryogenic preconcentration. Third RTI analysis was performed
using automated cryogenic preconcen tra tion with cryot'ocusing followed by. CC/t'ID.
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A6
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Me thylene
Chloride
Acrylonitrile
Or tho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
| PPB
2nd Analysis Day**
PPB
(30)
7/23/86
(31.9)
7/20/87
(38.6 + 2.6)
22
(38.2 + 2.6)
(20)
7/23/86
(12.5)
RTI
7/20/87
NA
22
NA
(20)
7/23/86
(15.0)
ANALYSIS****
7/20/87
NA
22
NA
(30)
7/23/86
(23.4)
7/20/87
(29.5 + 2.7)
22
(27.9 + 2.6)
(10)
7/23/86
(8.69)
7/20/87
(9.90 + 0.7)
22
(9.00 + 0.6)
(30)
7/23/86
(31.2)
7/20/87
(31.8 + 3.5)
22
(30.8 + 3.4)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
7/20/87
(20.0 + 1.4)
(19.0 + 1.0)
22
(19.5 + 1.3)
(19.0 + 1.0)
7/20/87
NA
(7.70 + 1.5)
22
NA
(7.70 + 1.5)
7/20/87
NA
(6.50 + 1.3)
22
NA
(6.50 + 1.3)
7/20/87
(20.0 + 1.8)
(19.8 + 1.8)
22
(19.6 + 1.8)
(19.8 + 1.8)
7/20/87
(18.1 + 1.3)
(19.0 + 1.2)
22
(19.1 + 1.3)
(19.0 + 1.2)
7/20/87
(18.2 + 2.0)
(19.1 + 1.9)
22
(19.3 + 2.1)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis,
**** All RTI analyses were performed using cryogenic preconcentration with cryofocusing.
NA = Not Analzyed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A7
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(30)
7/23/86
(32.1)
2/20/87
(29.6 + 2.0)
173
(30.9 + 2.1)
(20)
7/23/86
(12.9)
RTI
2/20/87
NA
173
NA
(21)
7/23/86
(16.0)
ANALYSIS***
2/20/87
NA
173
NA
(31)
7/23/86
(24.6)
2/20/87
(29.7 + 2.7)
173
(29.5 + 2.7)
(10)
7/23/86
(8.71)
2/20/87
(10.3 + 0.7)
173
(10.5 + 0.7)
(31)
7/23/86
(38.7)
2/20/87
(34.2 + 3.8)
173
(33.1 + 3.7)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
2/20/87
(18.6 + 1.3)
(19.0 + 1.0)
173
(19.7 + 1.3)
(19.0 + 1.0)
2/20/87
NA
(7.70 + 1.5)
173
NA
(7.70 + 1.5)
2/20/87
NA
(6.50 + 1.3)
173
NA
(6.50 + 1.3)
2/20/87
(18.9 + 1.7)
(19.8 + 1.8)
173
(18.9 + 1.8)
(19.8 + 1.8)
2/20/87
(19.1 + 1.3)
(19.0 + 1.2)
173
(19.2 + 1.4)
(19.0 + 1.2)
2/20/87
(18.9 + 2.1)
(19.1 + 1.9)
173
(19.4 + 2.1)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A8
Ln
Ni
ACTIVITY
COMPOUND
1 ,3-Butadiene
Ethylene
Oxide
Propy lene
Oxide
Methylene
Chloride
Aery Ion it rile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPD
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
(6006)
7/09/86
(5722)
10/22/86
(5922 + 225)
91
(5890 + 220)
301
(5901 + 210)
(6002)
7/09/86
(5072)
.RTI
10/22/86
(6500 + 260)
91
(5800 + 250)
301
(6000 + 270)
(8014)
7/09/86
(7609)
ANALYSIS****
10/22/86
(8333 _+ 350)
91
(8120 + 320)
301
(8205 + 330)
(6009)
7/09/86
(6068)
10/22/86
(6200 + 249)
(8013)
7/09/86
(8129)
10/22/86
(8487 + 360)
91 91
(5700 + 240) (7860 + 330)
301 301
(5850 + 250) (7900 + 335)
(8013)
7/09/86
(8396)
10/22/86
(9065 _+ 725)
91
(8300 + 710)
301
(8501 + 726)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Cone en. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
3rd Analysis Day**
PPB
NBS Concen. PPB
10/22/86
(2942 + 100)
(2510 + 20)
91
(2500 + 90)
(2510 + 20)
301
(2490 t 87)
(2510 + 20)
10/22/86
(2878 _+ 130)
(2770 + 80)
91
(2710 _+ 110)
(2770 + 80)
301
(2730 _+ 100)
(2770 + 80)
10/22/86
(2338 j* 95)
(2360 + 70)
91
(2380 + 90)
(2360 + 70)
301
(2300 + 80)
(2360 + 70)
10/22/86
(2214 + 98)
(2260 + 80)
91
_ (2250 + 90)
(2260 + 80)
301
(2225 + 85)
(2260 + 80)
10/22/86
(1996 + 81)
(2020 + 60)
91
(1990 + 80)
(2020 + 60)
301
(2000 _+ 57)
(2020 + 60)
10/22/86
(1975 +_ 166)
(1840 + 180)
91
(1910 + 160)
(1840 + 180)
301
(1880 jf 156)
(1840 + 180)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** First and 2nd analyses were performed using cryogenic preconcentrat ion. Third RTI analysis was performed
using automated cryogenic preconcentrat ion with cryofocusing followed by GC/FID.
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A9
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propy lene
Oxide
Me thy lene
Chloride
Aery Ion itrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(30)
7/22/86
(32.1)
5/04/87
(30.3 + 2.1)
102
(30.7 + 2.1)
(20)
7/22/86
(12.8)
RTI
5/04/87
NA
102
NA
(20)
7/22/86
(14.9)
ANALYSIS***
5/04/87
NA
102
NA
(30)
7/22/86
(23.8)
5/04/87
(24.5 + 2.3)
102
(24.7 + 2.3)
(10)
7/22/86
(9.37)
5/04/87
(10.7 + 0.8)
102
(9.31 + 0.7)
(30)
7/22/86
(37.1)
5/04/87
(33.9 + 3.8)
102
(33.7 + 3.7)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/04/87
(21.8 + 1.5)
(19.0 + 1.0)
102
(20.0 + 1.4)
(19.0 + 1.0)
5/04/87
NA
(7.70 + 1.5)
102
NA
(7.70 + 1.5)
5/04/87
NA
(6.50 + 1.3)
102
NA
(6.50 + 1.3)
5/04/87
(20.6 + 1.9)
(19.8 + 1.8)
102
(19.6 + 1.8)
(19.8 + 1.8)
5/04/87
(18.8 + 1.3)
(19.0 + 1.2)
102
(20.0 ± 1.4)
(19.0 + 1.2)
5/04/87
(18.1 + 2.0)
(19.1 + 1.9)
102
(18.9 + 2.1)
(19.1 + 1.9)
. * An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A10
ACTIVITY
COMPOUND
1,3-Butadiene
Ethy lene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(30)
9/16/86
(32.6)
5/04/87
(28.4 + 1.9)
98
(28.5 + 1.9)
(35)
9/16/86
(16.7)
RTI
5/04/87
NA
98
NA
(15)
9/16/86
(10.7)
ANALYSIS***
5/04/87
NA
98
NA
(10)
9/16/86
(9.06)
5/04/87
(10.4 + 1.0)
98
(10.4 + 1.0)
(30)
9/16/86
(24.2)
5/04/87
(28.2 + 2.0)
98
(29.3 + 2.1)
(10)
9/16/86
(10.9)
5/04/87
(11.5 + 1.3)
98
(11.5 + 1.3)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/04/87
(21.8 + 1.5)
(19.0 + 1.0)
98
(19.9 + 1.3)
(19.0 + 1.0)
5/04/87
NA
(7.70 + 1.5)
98
NA
(7.70 + 1.5)
5/04/87
NA
(6.50 + 1.3)
98
NA
(6.50 + 1.3)
5/04/87
(20.6 + 1.9)
(19.8 + 1.8)
98
(19.0 + 1.8)
(19.8 + 1.8)
5/04/87
(18.8 + 1.3)
(19.0 + 1.2)
98
(18.6 + 1.3)
(19.0 + 1.2)
5/04/87
(18.1 + 2.0)
(19.1 + 1.9)
98
(18.9 + 2.1)
(19.1 + 1.9)
Ln
-P-
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis,
***** Compound unstable.
NA = Not Analzyed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A11
Oi
Ui
ACTIVITY
COMPOUND
1 ,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Methylene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Dace
PPB
(800)
7/07/86
(811)
(800) .
7/07/86
(595)
(1021)
7/07/86
(873)
(816)
7/07/86
(826)
(1020)
7/07/86
(1044)
(1020)
7/07/86
(1069)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
10/22/86
(803 +_ 30)
91
(940 .+ 40)
302
(923 _+ 35)
10/22/86
(694 +_ 28)
91
(700 _* 30)
302
(697 + 30)
10/22/86
(917 +_ 31)
91
(960 + 40)
302
(932 + 36)
10/22/86
(814 _+ 33)
91
(840 + 40)
302
(823 + 36)
10/22/86
(1180 + 62)
91
(1010 + 40)
302
(1080 + 50)
10/22/86
(1211 +_ 110)
91
(1090 +_ 90)
302
(1130 + 98)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
3rd Analysis Day**
PPB
NBS Concen. PPB
10/22/86
(2942 _+ 100)
(2510 + 20)
91
(2500 + 90)
(2510 _+ 20)
302
(2496 + 86)
(2510 + 20)
10/22/86
(2878 + 130)
(2770 t 80)
91
(2710 + 110)
(2770 + 80)
302
(2720 + 112)
(2770 + 80)
10/22/86
(2338 _+ 95)
(2360 + 70)
91
(2380 + 90)
(2360 + 70)
302
(2350 + 70)
(2360 + 70)
10/22/86
(2214 _+ 98)
(2260 + 80)
91
(2250 + 90)
(2260 jt 80)
302
(2245 + 88)
(2260 + 80)
10/22/86
(1996 _+ 81)
(2020 +_ 60)
91
(1990 +• 80)
(2020 _* 60)
302
(2000 +• 82)
(2020 + 60)
10/22/86
(1975 j* 166)
(1840 + 180)
91
(1910 + 160)
(1840 _+ 180)
302
(1900 +_ 155)
(1840 + 180)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** First and 2nd analyses were performed using cryogenic preconcentrat ion. Third RTt analysis was performed
using automated cryogenic preconcentrat ion with cryofocusing followed by GC/FID.
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A12
ACTIVITY
COMPOUND
1 ,3-Butadiene
Ethylene
Oxide
Propy lene
Oxide
Methylene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
(2000)
7/08/86
(1995)
10/22/86
(2040 _+ 71)
91
(2070 + 80)
302
(2060 + 75)
(2000) .
7/08/86
(1564)
RTI
10/22/86
(1848 jf 86)
91
(1790 + 80)
302
(1805 _+ 81)
(2987)
7/08/86
(2520)
ANALYSIS****
\
10/22/86
(2759 jf 111)
91
(2750 + 110)
302
(2752 + 110)
(1991)
7/08/86
(1977)
10/22/86
(1999 + 110)
91
(1890 + 80)
302
(1920 _+ 85)
(2984)
7/08/86
(2951)
10/22/86
(2961 +_ 120)
91
(2960 + 120)
302
(2958 + 120)
(2988)
7/08/86
(2932)
10/22/86
(3358 _+ 240)
91
(3540 jf 300)
302
(3480 + 260)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
3rd Analysis Day**
PPB
NBS Concen. PPB
10/22/86
(2942 + 100)
(2510 + 20)
91
(2500 +_ 90)
(2510 + 20)
302
(2496 + 86)
(2510 _+ 20)
10/22/86
(2878 _+ 130)
(2770 + 80)
91
(2710 _+ 110)
(2770 JH 80)
302
(2720 + 112)
(2770 + 80)
10/22/86
(2338 _+ 95)
(2360 + 70)
91
(2380 jt- 90)
(2360 + 70)
302
(2350 + 70)
(2360 _+ 70)
10/22/86
(2214 _+ 98)
(2260 + 80)
91
(2250 + 90)
(2260 + 80)
302
(2245 * 88)
(2260 +_ 80)
10/22/86
(1996 + 81)
(2020 + 60)
91
(1990 _+ 80)
(2020 + 60)
302
(2000 + 82)
(2020 ^ 60)
10/22/86
(1975 _+ 166)
(1840 +_ 180)
91
(1910 +_ 160)
(1840 + 180)
302
(1900 + 155)
(1840 +_ 180)
* An NBS primary standard was used for calibration.
-A* Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** First and 2nd analyses were performed using cryo^onic preconcentrat ion. Third RTI analysis was performed
using automated cryogenic preconcentrat ion with cryofocusing followed by GC/FID.
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A13
ACTIVITY
COMPOUND
1 ,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Methylene
Chloride
Acrylonitrile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
3rd Analysis Day**
PPB
(1997)
7/08/86
(1960)
10/22/86
(2019 + 80)
91
(2020 + 80)
302
(2018 jf 79)
(2002)
7/08/86
(1546)
RTI
10/22/86
(1889 + 120)
91
(1760 jf 80)
302
(1800 + 82)
(3027)
7/08/86
(2678)
ANALYSIS****
10/22/86
(3012 + 125)
91
(2770 + 110)
302
(2790 + 112)
(2017)
7/08/86
(1998)
10/22/86
(1987 _+ 90)
91
(1910 4 80)
302
(1923 _+ 81)
(3024)
7/08/86
(3048)
10/22/86
(2973 4- 125)
91
(2940 _4 120)
302
(2960 4 123)
(3028)
7/08/86
(3257)
10/22/86
(3388 + 270)
91
(3480 _+ 300)
302
(3390 + 289)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
3rd Analysis Day**
PPB
NBS Concen. PPB
10/22/86
(2942 _+ 100)
(2510 + 20)
91
(2500 + 90)
(2510 + 20)
302
(2496 + 86)
(2510 + 20)
10/22/86
(2878 jf 130)
(2770 _* 80)
91.
(2710 +_ 110)
(2770 _+ 80)
302
(2720 + 112)
(2770 + 80)
10/22/86
(2338 _+ 95)
(2360 + 70)
91
(2380 + 90)
(2360 +_ 70)
302
(2350 + 70)
(2360 4- 70)
10/22/86
(2214 _+ 98)
(2260 4 80)
91
(2250 + 90)
(2260 4 80)
302
(2245 4 88)
(2260 + 80)
10/22/86
(1996 * 81)
(2020 _+ 60)
91
(1990 *_ 80)
(2020 + 60)
302
(2000 + 82)
(2020 + 60)
10/22/86
(1975 _+ 166)
(1840 + 180)
91
(1910 _+ 160)
(1840 + 180)
302
(1900 + 155)
(1840 +• 180)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** First and 2nd analyses were performed using cryogenic preconcentrat ion. Third RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A14
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Me thylene
Chloride
Acrylonitrile
Or tho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
8/13/86
(9.51)
5/07/87
(12.3 + 0.8)
102
(12.3 + 0.8)
(16)
8/13/86
(12.9)
RTI
5/07/87
NA
102
NA
(36)
8/13/86
(37.5)
ANALYSIS***
5/07/87
NA
102
(9.74 + 2.3)
(31)
8/13/86
(27.8)
5/07/87
(30.9 + 2.9)
102
(27.6 + 2.5)
(10)
8/13/86
(10.4)
5/07/87
(11.7 + 0.8)
102
(10.0 + 0.7)
(31)
8/13/86
(36.1)
5/07/87
(31.0 + 3.4)
102
(34.2 + 3.7)
RTI QUALITY CONTROL****
Is t Analys is Da te
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/07/87
(20.0 + 1.5)
(19.0 + 1.0)
102
(20.5 + 1.4)
(19.0 + 1.0)
5/07/87
NA
(7.70 + 1.5)
102
NA
(7.70 + 1.5)
5/07/87
NA
(6.50 + 1.3)
102
NA
(6.50 + 1.3)
5/07/87
(20.7 + 1.9)
(19.8 + 1.8)
102
(21.2 + 2.0)
(19.8 + 1.8)
5/07/87
(20.5 + 1.4)
(19.0 + 1.2)
102
(20.0 + 1.4)
(19.0 + 1.2)
5/07/87
(17.6 + 1.9)
(19.1 + 1.9)
102
(18.4 + 2.0)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis,
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A15
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Aery loni trile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
8/28/86
(10.3)
7/20/87
(12.3 + 0.8)
28
(12.0 + 0.8)
(20)
8/28/86
(14.5)
RTI
7/20/87
NA
28
NA
(20)
8/28/86
(17.8)
ANALYSIS****
7/20/87
NA
28
NA
(10)
8/28/86
(12.6)
7/20/87
(11.4 + 1.1)
28
(10.4 + 1.0)
(10)
8/28/86
(8.22)
7/20/87
(9.95 + 0.7)
28
(9.93 + 0.7)
(10)
8/28/86
(8.84)
7/20/87
(11.4 + 1.3)
28
(11.2 + 1.2)
RTI QUALITY CONTROL***
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
7/20/87
(20.0 + 1.4)
(19.0 + 1.0)
28
(20.5 + 1.4)
(19.0 + 1.0)
7/20/87
NA
(7.70 + 1.5)
28
NA
(7.70 + 1.5)
7/20/87
NA
(6.50 + 1.3)
28
NA
(6.50 + 1.3)
7/20/87
(20.0 + 1.8)
(19.8 + 1.8)
28
(21.2 + 2.0)
(19.8 + 1.8)
7/20/87
(18.1 + 1.3)
(19.0 + 1.2)
28
(20.0 + 1.4)
(19.0 _+ 1.2)
7/20/87
(18.2 + 2.0)
(19.1 + 1.9)
28
(18.4 + 2.0)
(19.1 + 1.9)
01
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
**** All RTI analyses were performed using cryogenic preconcentration with cryofocusing followed by GC/FID.
***** Compound unstable.
NA = Not Analzyed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-AL6
ACTIVITY
COMPOUND
1,3-Butadiene
Ethy lene
Oxide
Propylene
Oxide
Me thy lene
Chloride
Acrylonitrile
Or tho-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(30)
9/16/86
(31.4)
2/20/87
(29.4 + 2.0)
171
NA
(35)
9/16/86
(25.2)
RTI
2/20/87
NA
171
NA
(15)
9/16/86
(13.3)
ANALYSIS***
2/20/87
NA
171
NA
(10)
9/16/86
(8.60)
2/20/87
(11.7 + 1.1)
171
(11.2 + 1.0)
(30)
9/16/86
(25.3)
2/20/87
(20.6 + 1.5)
171
NA
(10)
9/16/86
(10.3)
2/20/87
(9.20 + 1.0)
171
NA
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
2/20/87
(18.6 + 1.3)
(19.0 + 1.0)
171
(19.9 + 1.3)
(19.0 + 1.0)
2/20/87
NA
(7.70 + 1.5)
171
NA
i
(7.70 + 1.5)
2/20/87
NA
(6.50 + 1.3)
171
NA
(6.50 + 1.3)
2/20/87
(18.9 + 1.7)
(19.8 + 1.8)
171
(19.0 + 1.8)
(19.8 + 1.8)
2/20/87
(19.1 + 1.3)
(19.0 + 1.2)
171
(18.6 + 1.3)
(19.0 + 1.2)
2/20/87
(18.9 + 2.1)
(19.1 + 1.9)
171
(18.9 + 2.1)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
***** Compound unstable.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP IV COMPOUNDS*
Cylinder IV-A17
ACTIVITY
COMPOUND
1,3-Butadiene
Ethylene
Oxide
Propy lene
Oxide
Me thy lene
Chloride
Acryloni trile
Ortho-Xylene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
1st Analysis Date
PPB
2nd Analysis Day**
PPB
(10)
7/24/86
(9.91)
5/04/87
(12.0 + 0.8)
99
(12.6 + 0.9)
(20)
7/24/86
(14.4)
RTI
5/04/87
NA
99
NA
(20)
7/24/86
(16.8)
ANALYSIS***
5/04/87
NA
99
NA
(10)
7/24/86
(10.2)
5/04/87
(10.9 + 1.0)
99
(10.7 + 1.0)
(10)
7/24/86
(7.46)
5/04/87
(10.0 + 0.7)
99
(9.9 + 0.7)
(10)
7/24/86
(8.24)
5/04/87
(11.9 + 1.3)
99
(11.2 + 1.2)
RTI QUALITY CONTROL****
1st Analysis Date
PPB
NBS Concen. PPB
2nd Analysis Day**
PPB
NBS Concen. PPB
5/04/87
(21.8 + 1.5)
(19.0 + 1.0)
99
(19.5 + 1.3)
(19.0 + 1.0)
5/04/87
NA
(7.70 + 1.5)
99
NA
(7.70 + 1.5)
5/04/87
NA
(6.50 + 1.3)
99
NA
(6.50 + 1.3)
5/04/87
(20.6 + 1.9)
(19.8 + 1.8)
99
(19.6 + 1.8)
(19.8 + 1.8)
5/04/87
(18.8 + 1.3)
(19.0 + 1.2)
99
(19.1 + 1.3)
(19.0 + 1.2)
5/04/87
(18.1 + 2.0)
(19.1 + 1.9)
99
(19.3 + 2.1)
(19.1 + 1.9)
* An NBS primary standard was used for calibration.
** Number of days after 1st RTI analysis.
*** First RTI analysis was performed using cryogenic preconcentration. Second RTI analysis was performed
using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
**** A different NBS primary standard was analyzed as an internal quality control on each day of RTI analysis.
NA = Not Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A1
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Carbon
Tetrachlorlde
Me thy lene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/19/87
(4.55)
3/19/87
(4.12)
(5.00)
2/19/87
(5.04)
3/19/87
(5.13)
(5.00)
12/23/86
(4.10)
3/25/87
(3.80)
(5.00) •
2/19/87
(4.89)
3/19/87
(4.99)
1,2-Dlchloro-
e thane
ANALYSIS
(5.00)
2/19/87
(5.24)
3/19/87
(5.47)
Trichloro-
e thy lene
(5.00)
2/19/87
(5.70)
3/19/87
(6.07)
Benzene
(5.00)
2/19/87
(4.32)
3/19/87
(4.52)
Te trachloro-
e thy lene
(5.00)
2/19/87
(5.69)
3/19/87
(5.80)
1,3-Butadlene
•
(5.00)
2/19/87
(5.31)
3/19/87
(3.99)
RTI ANALYSIS****
1st Analysis Date
PPB (5
2nd Analysis Day**
PPB
1st Analysis Date
PPB (9
NBS Concen. PPB (9
2nd Analysis Day
PPB
NBS Concen. PPB (9
6/30/87
.15 + 0.3)
49
NA
6/30/87
.48 + 0.6)
.69 + 0.5)
49
NA
.69 + 0.5)
6/30/87
(4.77 + 0.3)
49
(4.95 + 0.3)
6/30/87
(10.6 + 0.7)
(10.8 + 0.5)
49
(10.7 + 0.7)
(10.8 + 0.5)
6/30/87 6/30/87
(4.9 + 0.3) (4.97 + 0.6)
49 49
(4.67 + 0.3M5.00 + 0.6)
RTI QUALITY
6/30/87 6/30/87
(10.6 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (
10.6 + 1.1)
49 49
(10.7 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
6/30/87 6/30/87
(4.87 + 0.3) (5.47 + 0.3)
49 49
(4.90 + 0.3) (5.61 + 0.4)
CONTROL***
6/30/87 6/30/87
(10.0 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
49 49
(10.6 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
6/30/87
(4.08 + 0.2)
49
(4.18 + 0.3)
6/30/87
(8.92 + 0.5)
(9.36 + 0.5)
49
(9.00 4- 0.5)
(9.36 + 0.5)
6/30/87
(5.06 + 0.4)
49
(5.02 + 0.3)
6/30/87
(9.89 + 0.7)
(9.96 + 0.5)
49
(9.93 + 0.7)
(9.96 + 0.5)
6/30/87
(5.84 + 0.6)
49
(5.02 + 0.5)
6/30/87
NA
(8.76 + 0.9)
49
NA
(8.76 + 0.9)
*Callbration was performed using an NBS primary standard.
**Number of c'ays after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed by CC/FID.
"NA" - Not Analyzed
(Continued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A1
ACTIVITY
COMPOUND
Broraome thane
Trichloro-
f luorome thane
1, 1,1-Tri-
chloroe thane
1,2-Dlchloro-
propane
1,2-Dibromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/19/87
(A. 85)
3/19/87
(4.78)
(5.00)
12/23/86
(4.72)
3/25/87
(4.69)
(5.00)
2/19/87
(5.20)
3/19/87
(5.12)
(5.00)
2/19/87
(5.57)
3/19/87
(5.73)
(5.00)
2/19/87
(6.25)
3/19/87
(6.18)
(5.00)
2/19/87
(5.19)
3/19/87
(5.41)
(5.00)
2/19/87
(5.85)
3/19/87
(5.98)
(5.00)
2/19/87
(5.59)
3/19/87
(5.57)
(5.00)
2/19/87
(6.20)
3/19/87
(5.91)
RTI ANALYSIS****
1st Analysis Hate
PPB
2nd Analysis Day**
PPB
6/30/87
(5.32 4- 0.6)
49
(5.42 + 0.6)
6/30/87
(5.23 + 0.6)
49
(4.92 + 0.5)
6/30/87
(4.81 + 0.3)
49
(4.67 -f 0.3)
6/30/87
(4.87 + 0.3)
49
(4.81 + 0.3)
6/30/87 6/30/87
(4.79 + 0.3) (4.74 + 0.3)
49 49
(4.84 + 0.4) (4.60 + 0.3)
6/30/87
(4.89 + 0.3)
49
(4.91 + 0.3)
6/30/87 6/30/87
(4.46 + 0.25).(5.02 + 0.3)
49
(4.81 + 0.3)
49
(5.10 + 0.3)
RTI QUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
6/30/87
(9.72 + 1.0)
(10.6 + 1.0)
49
(9.68 + 1.0)
(10.6 + 1.0)
6/30/87
(8.70 + 1.0)
(9.39 + 0.9)
49
(8.65 + 1.0)
(9.39 + 0.9)
6/30/87
(10. 1 + 0.6)
(10.2 + 0.5)
49
(10.1 + 0.6)
(10.2 + 0.5)
6/30/87
(10.5 + 0.6)
(10.6 + 0.5)
49
(10.4 + 0.6)
(10.6 + 0.5)
6/30/87 6/30/87
(9.52 + 0.6) (9.98 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
49 49
(9.48 + 0.6) (10. 0 + 0.6)
(9.92 4- 0.5) (10.0 + 0.5)
6/30/87
(9.58 + 0.6)
(9.80 + 0.5)
49
(9.62 + 0.6)
(9.80 + 0.5)
6/30/87
(9.56 + 0.5)
(10.1 4; 0.5)
49
(9.63 + 0.5)
(10.1 + 0.5)
6/30/87
(9.65 + 0.5)
(9.96 + 0.5)
49
(9.72 + 0.5)
(9.96 + 0.5)
'Calibration was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
"NA" - Not Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A2
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Carbon
Tetrachloride
Me thy lene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/23/87
(4.46)
3/23/87
(5.08)
(5.00)
2/23/87
(5.29)
3/23/87
(5.10)
(5.00)
12/23/86
(4.47)
3/25/87
(4.21)
(5.00)
2/23/87
(5.12)
3/23/87
(5.19)
1,2-Dichloro-
e thane
ANALYSIS
(5.00)
2/23/87
(5.35)
3/23/87
(5.71)
Trlchloro-
e thy lene
(5.00)
2/23/87
(5.89)
3/23/87
(5.52)
Benzene
(5.00)
2/23/87
(4.54)
3/23/87
(4.76)
Te trachloro-
e thy lene
(5.00)
2/23/87
(5.51)
3/23/87
(5.81)
1 , 3-Bu tadiene
(5.00)
2/23/87
(5.16)
3/23/87
(5.64)
RTI ANALYSIS****
1st Analysis Date
PPB (5
2nd Analysis Day**
PPB (5
1st Analysis Date
. PPB (9
NBS Concen. PPB (9
2nd Analysis Day
PPB
NBS Concen. PPB (9
6/30/87
.13 + 0.3)
49
.28 + 0.3)
6/30/87
.48 + 0.6)
.69 + 0.5)
49
NA
.69 + 0.5)
6/30/87
(4.95 _+ 0.3)
49
(5.10 + 0.3)
6/30/87
(10.6 + 0.7)
(10.8 -f 0.5)
49
(10.7 -f 0.7)
(10.8 + 0.5)
6/30/87 6/30/87
(4.72 + 0.3) (5. 10 + 0.6)
49 49
(5.00 + 0.3) (5. 16 + 0.6)
RTI QUALITY
6/30/87 6/30/87
(10.6 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
49 49
(10.7 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
6/30/87 6/30/87'
(5.16 + 0.3) (5.85 + 0.4)
49 49
(5.21 + 0.3) (5.83 + 0.4)
CONTROL***
6/30/87 6/30/87
(10.0 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0,5)
49
(9.95 + 0.6) (
49
10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
6/30/87
(4.14 + 0.2)
49
(4.23 + 0.3)
6/30/87
(8.92 + 0.5)
(9.36 + 0.5)
49
(9.00 + 0.5)
(9.36 + 0.5)
6/30/87
(5.22 + 0.4)
49
(5.21 + 0.4)
6/30/87
(9.89 + .07)
(9.96 + 0.5)
49
(9.93 + 0.7)
(9.96 + 0.5)
6/30/87
(5.53 + 0.6)
49
(5.75 + 0.6)
6/30/87
NA
(8.76 + 0.9)
49
NA
(8.76 + 0.9)
•Callbratlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
•****A11 analyses were performed using automated cryogenic preconcentratlon with cryofocusing followed by GC/FID.
NA - Not Analyzed
(Con tinued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A2
ACTIVITY
COMPOUND
Bromome thane
Trlchloro-
f luorome thane
1,1,1-Trl-
chloroe thane
1,2-Dlchloro-
propane
1,2-Dlbromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/23/87
(5.46)
3/23/87
(5.64)
(5.00)
12/23/86
(4.49)
3/25/87
(4.75)
(5.00)
2/23/87
(5.08)
3/23/87
(5.86)
(5.00)
2/23/87
(5.52)
3/23/87
(5.43)
(5.00)
2/23/87
(6.24)
3/23/87
(6.17)
(5.00)
2/23/87
(5.14)
3/23/87
(5.48)
(5.00)
2/23/87
(5.74)
3/23/87
(6.08)
(5.00)
2/23/87
(5.24)
3/23/87
(5.60)
(5.00)
2/23/87
(5.58)
3/23/87
(6.00)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
6/30/87
(5.68 + 0.6)
49
(5.73 + 0.6)
6/30/87
(4.44 + 0.5)
49
(4.86 + 0.6)
6/30/87
(5. 10 + 0.3)
49
(5.20 + 0.3)
6/30/87
(5.24 + 0.3)
49
(5.30 + 0.3)
6/30/87 6/30/87
(5.24 + 0.3) (5.01 + 0.3)
49 49
(5.16 + 0.3) (5.07 + 0.3)
6/30/87
(5.20 + 0.3)
49
(5.20 + 0.3)
6/30/87
(4.66 + 0.3)
49
(4.79 + 0.3)
6/30/87
(5.25 + 0.3)
49
(5. 10 + 0.3)
RTI QUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
i
NBS Concen. PPB
6/30/87
(9.72 + 1.0)
(10.6 + 1.0)
49
(9.68 + 1.0)
(10.6 + 1.0)
6/30/87
(8.70 + 1.0)
(9.39 + 0.9)
49
(8.65 + 1.0)
(9.39 + 0.9)
6/30/87
(10. I + 0.6)
(10.2 + 0.5)
49
(10.1 4 0.6)
(10.2 + 0.5)
6/30/87
(10.5 + 0.6)
(10.6 + 0.5)
49
(10.4 + 0.6)
(10.6 + 0.5)
6/30/87 6/30/87
(9.52 + 0.6) (9.98 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
49 49
(9.48 + 0.6) (10.0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
6/30/87
(9.58 + 0.6)
(9.80 + 0.5)
49
(9.62 + 0.6)
(9.80 + 0.5)
6/30/87
(9.56 + 0.5)
(10. I + 0.5)
49
(9.63 + 0.5)
(10.1 + 0.5)
6/30/87
(9.65 + 0.5)
(9.96 + 0.5)
49
(9.72 + 0.5)
(9.9 + 0.5)
*Ca libra tl'on was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****All analyses were performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/F1D.
"NA" - Not Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A3
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Carbon
Tetrachlorlde
Me thy lene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/17/87
(4.91)
3/17/87
(5.21)
(5.00)
2/17/87
(5.12)
3/17/87
(4.61)
(5.00)
1/27/87
(4.36)
3/25/87
(4.01)
(5.00)
2/17/87
(5.38)
3/17/87
(4.91)
1,2-Dichloro-
e thane
ANALYSIS
(5.00)
2/17/87
(5.39)
3/17/87
(4.72)
Trichloro-
e thy lene
(5.00)
2/17/87
(5.34)
3/17/87
(4.80)
Benzene
(5.00)
2/17/87
(5.13)
3/17/87
(4.84)
Tetrachloro-
e thy lene
(5.00)
2/17/87
(5.75)
3/17/87
(4.71)
1,3-Butadiene
(5.00)
2/17/87
(5.77)
3/17/87
(5.85)
RTI ANALYSIS****
1st Analysis Date
PPB (4
2nd Analysis Day**
PPB (5
1st Analysis Date
PPB (9
NBS Concen. PPB (9
2nd Analysis Day
PPB (9
NBS Concen. PPB (9
7/1/87
.98 + 0.3)
50
.33 + 0.3)
7/1/87
.40 + 0.6)
.69 + 0.5)
50
.45 + 0.6)
.69 + 0.5)
7/1/87
(4.92 + 0.3)
50
(4.85 + 0.3)
7/1/87
(10.5 + 0.8)
(10.8 + 0.5)
50
(10.6 + 0.7)
(10.8 + 0.5)
7/1/87 7/1/87
(4.96 + 0.3) (5.21 + 0.6)
50 50
(4.99 + 0.3) (5.12 + 0.6)
RTI QUALITY
7/1/87 7/1/87
(10.4 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
50 50
(10.5 + 0.7) (10.6 -1- 1.2)
(10.9 + 0.6) (10.6 + 1.1)
7/1/87 7/1/87
(5.03 + 0.3) (5.44 + 0.3)
50 50
(4.86 + 0.3) (5.47 _+ 0.3)
CONTROL***
7/1/87 7/1/87
(10.2 + 0.6) (10.5 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
7/1/87
(4.78 + 0.3)
50
(4.88 + 03)
7/1/87
(8.96 + 0.5)
(9.36 + 0.5)
50 50 50
(9.94 + 0.6) (10.04 + 0.7)(9.03 + 0.5)
(9.95 + 0.5) (10.5 + 0.5) (9.36 + 0.5)
7/1/87
(5.16 + 0.4)
50
(5.13 + 0.4)
7/1/87
(10.1 + 0.7)
(9.96 + 0.5)
50
(9.85 + 0.7)
(9.96 + 0.5)
7/1/87
(6.00 + 0.7)
50
NA
7/1/87
NA
(8.76 + 0.9)
50
(8.40 + 0.9)
(8.76 + 0.9)
OS
*Callbratlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
****All analyses were performed using automated cryogenic preconcentration with cryofocusing followed by GC/F1U.
"NA" - Not Analyzed
(Continued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A3
ACTIVITY
COMPOUND
Bromome thane
Trichloro-
f luorome thane
1,1,1-Tri-
chloroe thane
1,2-Dlchloro-
propane
1 ,2-Dlbromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(10.0)
2/17/87
(9.41)
3/17/87
(9.47)
(10.0)
1/27/87
(9.41)
3/25/87
(10.8)
(10.0)
2/17/87
(10.9)
3/17/87
(11.2)
(10.0)
2/17/87
(11.6)
3/17/87
(10.5)
(10.0)
2/17/87
(12.8)
3/17/87
(10.4)
(10.0)
2/17/87
(10.2)
3/17/87
(8.80)
(10.0)
2/17/87
(12.0)
3/17/87
(9.39)
(10.0)
2/17/87
(11.1)
3/17/87
(9.35)
(10. 0)
2/17/67
(14.3)
3/17/87
(11.6)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/1/87
(9.74 + 1.0)
50.
NA
7/1/87
(9.43 + 1.0)
50
(9.62 + 1.1)
7/1/87
(10.3 _+ 0.6)
50
(10.0 + 0.6)
7/1/87
(10.6 + 0.6)
50
(10.3 + 0.6)
7/1/87 7/1/87
(10.4 + 0.6) (9.34 + 0.5)
50 50
(10.2 + 0.6) (9.25 + 0.5)
7/1/87
(10. 1 + 0.6)
50
(9.92 + 0.6)
7/1/87
(9.40 + 0.5)
50
(9.56 + 0.5)
7/1/87
(12.3 + 0.7)
50
(12.0 + 0.7)
RTI DUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/1/87
(9.80 + 1.0)
(10.6 + 1.0)
50
(9.73 + 1.0) •
(10.6 + 1.0)
7/1/87
(8.65 + 1.0)
(9.39 + 0.9)
50
(8.80 + 1.0)
(9.39 + 0.9)
7/1/87
(10.1 + 0.6)
(10.2 + 0.5)
50
(10.1 -f 0.6)
(10.2 + 0.5)
7/1/87
(10.6 + 0.6)
(10.6 + 0.5)
50
(10.5 + 0.6)
(10.6 + 0.5)
7/1/87
(9.92 + 0.6) (
7/1/87
10.0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
50 50
(9.61 -f 0.6) (10. 0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
7/1/87
(9.73 + 0.6)
(9.8 + 0.5)
50
(9.66 + 0.6)
(9.80 + 0.5)
7/1/87
(9.80 -f 0.5)
(10.1 4 0.5)
50
(9.59 + 0.5)
(10.1 + 0.5)
7/1/87
(10.0 + 0.6)
(9.96 + 0.5)
50
(9.83 + 0.6)
(9.96 + 0.5)
'Calibration was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocusing followed by GC/FID.
"NA" - Not Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A4
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Ca rbon
Tetrachlorlde
Me thylene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/13/87
(4.91)
3/16/87
(5.16)
(5.00)
2/13/87
(4.85)
3/16/87
(4.48)
(5.00)
1/27/87
(4.27)
3/25/87
(4.32)
(5.00)
2/13/87
(5.15)
3/16/87
(4.99)
1,2-Dlchloro-
e thane
ANALYSIS
(5.00)
2/13/87
(5.16)
3/16/87
(4.95)
Trlchloro-
e thy lene
(5.00)
2/13/87
(5.12)
3/16/87
(4.94)
Benzene
(5.00)
2/13/87
(4.98)
3/16/87
(4.92)
Te trachloro-
e thy lene
(5.00)
2/13/87
(5.15)
3/16/87
(4.67)
1,3-Butadiene
(5.00)
2/13/87
(5.60)
3/16/87
(5.65)
RTI ANALYSIS****
1st Analysis Date
PPB (5
2nd Analysis Day**
PPB (4
1st Analysis Date
PPB (9
NBS Concen. PPB (9
2nd Analysis Day
PPB
NBS Concen. PPB (9
6/30/87
.08 + 0.3)
49
.93 + 0.3)
6/30/87
.48 + 0.6)
.69 + 0.5)
49
NA
.69 + 0.5)
6/30/87
(4.86 + 0.3)
49
(4.76 + 0.3)
6/30/87
(10.6 + 0.7)
(10.8 + 0.5)
49
(10.7 + 0.7)
(10.8 + 0.5)
6/30/87 6/30/87
(4.60 + 0.3) (5.13 + 0.6)
49 49
(4.88 + 0.3) (5. 18 + 0.6)
RTI QUALITY
6/30/87 6/30/87
(10.6 + 0.7) (10.6 + 1.2)
(11.0 + 0.6) (10.6 + 1. 1)
49 49
(10.7 + 0.7) (10.6 + 1.2)
(10.9 _+ 0.6) (10.6 + 1. I)
6/30/87 6/30/87
(5.10 + 0.3) (5.39 + 0.3)
49 49
(5.00 + 0.3) (5.40 + 0.3)
CONTROL***
6/30/87 6/30/87
(10.0 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
49 49
(9.95 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
6/30/87
(4.66 + 0.3)
49
(4.72 + 0.3)
6/30/87
(8.92 + 0.5)
(9.36 + 0.5)
49
(9.00 + 0.5)
(9.36 _+ 0.5)
6/30/87
(5.21 + 0.4)
49
(5.22 + 0.4)
6/30/87
(9.89 + 0.7)
(9.96 + 0.5)
49
(9.93 + 0.7)
(9.96 + 0.5)
6/30/87
(5.52 + 0.6)
49
NA
6/30/87
NA
(8.76 + 0.9)
49
NA
(8.76 + 0.9)
00
*Callbratlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****All analyses were performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/F1D.
"NA" - Not Analyzed
(Continued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A4
ACTIVITY
COMPOUND
Bromome thane
Trichloro-
f luorome thane
1,1,1-Trl-
chloroe thane
1,2-Dlchloro-
propane
1,2-Dlbromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(10.0)
2/13/87
(8.99)
3/16/87
(8.81)
(10.0)
1/27/87
(9.39)
3/25/87
(11.0)
(10.0)
2/13/87
(10. I)
3/16/87
(10.8)
(10.0)
2/13/87
(11.0)
3/16/87
(10.6)
(10.0)
2/13/87
(H.I)
3/16/87
' (H.O)
(10.0)
2/13/87
(9.57)
3/16/87
(9.10)
(10.0)
2/13/87
(10.7)
3/16/87
(9.97)
(10.0)
2/13/87
(9.60)
3/16/87
(9.69)
(10.0)
2/13/87
(11.7)
3/16/87
(12.0)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
6/30/87
(8,72 + 0.9)
49
(8.36 + 0.9)
6/30/87
(8.90 + 1.0)
49
(9.13 + 1.0)
6/30/87
(10.1 + 0.6)
49
(10. 1 + 0.6)
6/30/87
(10.5 + 0.6)
49
(10.5 + 0.6)
6/30/87 6/30/87
(9.88 + 0.6) (9.34 + 0.5)
49 49
(9.52 + 0.6) (9.62 + 0.5)
6/30/87
(9.95 + 0.6)
49
(10.0 + 0.6)
6/30/87
(9.06 + 0.5)
49
(9.78 + 0.5)
6/30/87
(11.6 + 0.7)
49
(11.8 + 0.7)
RTI QUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
6/30/87
(9.72 + 1.0)
(10.6 + 1.0)
49
(9.68 + 1.0)
(10.6 + 1.0)
6/30/87
(8.70 + 1.0)
(9.40 + 0.9)
49
(8.65 -f 1.0)
(9.39 + 0.9)
6/30/87
(10.1 + 0.6)
(10.2 + 0.5)
49
(10.1 + 0.6)
(10.2 + 0.5)
6/30/87
(10.5 -f 0.6)
(10.6 + 0.5)
49
(10.4 + 0.6)
(10.6 + 0.5)
6/30/87 6/30/87
(9.52 + 0.6) (9.98 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
49 49
(9.48 + 0.6) (10.0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
6/30/87
(9.58 + 0.6)
(9.80 + 0.5)
49
(9.62 + 0.6)
(9.80 + 0.5)
6/30/87
(9.56 + 0.5)
(10. 1 + 0.5)
49
(9.63 + 0.5)
(10. 1 + 0.5)
6/30/87
(9.65 + 0.5)
(9.96 + 0.5)
49
(9.72 jj; 0.5)
(9.96 + 0.5)
•Calibration was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentration with cryofocuslng followed by GC/FID.
"NA" - Hot Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A5
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Carbon
Tetrachlorlde
Me thy lene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Da te
PPB
2nd Analysis Date
PPB
(10.0)
2/18/87
(9.98)
3/18/87
(10.3)
(10.0)
2/18/87
(10.8)
3/18/87
(11. I)
(10.0)
12/23/86
(9.98)
3/24/87
(9.47)
(10.0)
2/18/87
(10.5)
3/18/87
(10.6)
1,2-DIchloro-
e thane
ANALYSIS
(10.0)
2/18/87
(11.2)
3/18/87
(11.4)
Trichloro-
e thy lene
(10.0)
2/18/87
(11.4)
3/18/87
(11.6)
Benzene
(10.0)
2/18/87
(9.93)
3/18/87
(10.3)
Tetrachloro-
e thy lene
(10.0)
2/18/87
(11.4)
3/18/87
(11.7)
1,3-Bu tadlene
(10.0)
2/18/87
(10.7)
3/18/87
(10.9)
RTI ANALYSIS****
1st Analysis Date 6/30/87
PPB (10.2 + 0.6)
2nd Analysis Day**
PPB
1st Ana lysis Da te
PPB (9
NBS Concen. PPB (9
2nd Analysis Day
PPB
NBS Concen. Pt-B (9
49
NA
6/30/87
.48 + 0.6)
.69 + 0.5)
49
NA
.69 + 0.5)
6/30/87
(10.2 +. 0.7)
49
(10.6 + 0.7)
6/30/87
(10.6 _+ 0.7)
(10.8 + 0.5)
49
(10.7 + 0.7)
(10.8 + 0.5)
6/30/87 6/30/87
(10.0 + 0.6) (11.1 + 1.3)
49 49
(9.94 + 0.6) (10.8 + 1.2)
RTI QUALITY
6/30/87 6/30/87
(10.6 + 0.7) (10.6 + 1.2)
(11.0 + 0.6) (10.6 +1.1)
49 49
(10.7 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
6/30/87 6/30/87
(10.5 _+ 0.6) (11.0 + 0.7)
49 49
(9.90 -f 0.6) (10.8 + 0.7)
CONTROL***
6/30/87 6/30/87
(10. 0 + 0.6) (10.4 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
49 49
(9.95 + 0.6) (10.4 + 0.7)
(9.95 _+ 0.5) (10.5 + 0.5)
6/30/87
(9.24 + 0.5)
49
(9.23 + 0.5)
6/30/87
(8.92 + 0.5)
(9.36 + 0.5)
49
(9.00 + 0.5)
(9.36 + 0.5)
6/30/87
(10.6 + 0.8)
49
(10.5 + 0.8)
6/30/87
(9.89 + 0.7)
(9.96 + 0.5)
49
(9.93 + 0.7)
(9.96 + 0.5)
6/30/87
(10.6 + 1.2)
49
NA
6/30/87
NA
(8.76 + 0.9)
49
NA
(8.76 + 0.9)
'Calibration was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentratlon with cryofocusing followed by GC/F1D.
"NA" - Not Analyzed
(Continued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A5
ACTIVITY
COMPOUND
Broraome thane
Trlchloro-
fluoroine thane
1,1,1-Trl-
chloroe thane
1,2-Dlchloro-
propane
1,2-Dibromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPD
2nd Analysis Date
PPB
(5.00)
2/18/87
(4.84)
3/18/87
(4.87)
(5.00)
12/23/86
(5.31)
3/24/87
(5.04)
(5.00)
2/18/87
(5.38)
3/18/87
(5.68)
(5.00)
2/18/87
(5.84)
3/18/87
(5.99)
(5.00)
2/18/87
(6.37)
3/18/87
(6.45)
(5.00)
2/18/87
(5.39)
3/18/87
(5.57)
(5.00)
2/18/87
(5.96)
3/18/87
(6.22)
(5.00)
2/18/87
(5.52)
3/18/87
(5.86)
(5.00)
2/18/87
(5.79)
3/18/87
(6.18)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
6/30/87
(5.08 + 0.5)
49
(4.96 + 0.5)
6/30/87
(5.18 + 0.6)
49
(5.26 + 0.6)
6/30/87
(5.25 + 0.3)
49
(5.12 + 0.3)
6/30/87
(5.51 + 0.3)
49
(5.40 + 0.3)
6/30/87 6/30/87
(5.48 + 0.3) (5.38 + 0.3)
49 49
(5.50 + 0.3) (5.24 + 0.3)
6/30/87
(5.44 + 0.3)
49
(5.50 + 0.3)
6/30/87
(5.14 + 0.3)
49
(5.21 + 0.3)
6/30/87
(5.78 + 0.3)
49
(5.48 + 0.3)
RTI QUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
6/30/87
(9.72 + 1.0)
(10.6 + 1.0)
49
(9.68 + 1.0)
(10.6 + 1.0)
6/30/87
(8.70 + 1.0)
(9.39 + 0.9)
49
(8.65 + 1.0)
(9.39 + 0.9)
6/30/87
(10.1 + 0.6)
(10.2 + 0.5)
49
(10. I _+ 0.6)
(10.2 + 0.5)
6/30/87
(10.5 + 0.6)
(10.6 + 0.5)
49
(10.4 + 0.6)
(10.6 + 0.5)
6/30/87 6/30/87
(9.52 + 0.6) (9.98 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
49 49
(9.48 + 0.6) (10. 0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
6/30/87
(9.58 + 0.6)
(9.80 + 0.5)
49
(9.62 + 0.6)
(9.80 + 0.5)
6/30/87
(9.56 + 0.5)
(10.1 + 0.5)
49
(9.63 + 0.5)
(10.1 + 0.5)
6/30/87
(9.65 + 0.5)
(9.96 + 0.5)
49
(9.72 + 0.5)
(9.96 + 0.5)
*Ca libra tlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of KTI analysis.
****A11 analyses were performed using automated cryogenic preconcentratlon with cryofocuslng followed by CC/FIU.
"NA" - Not Analyzed
-------
STABILITY STUDY FOR GROUP V COMPOUNDS*
Cylinder V-A6
ACTIVITY
COMPOUND
Vinyl
Chloride
Chloroform
Ca rbon
Te trachlorlde
Me thy lene
Chloride
MANUFACTURER
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(10.0)
2/17/87
(9.66)
3/24/87
(10.3)
(10.0)
2/17/87
(10.5)
3/24/87
(10.6)
(10.0)
12/23/86
(9.83)
3/24/87
(9.31)
(10.0)
2/17/87
(10.2)
3/24/87
(10.3)
1,2-Dlchloro-
e thane
ANALYSIS
(10.0)
2/17/87
(10.8)
3/24/87
(10.8)
Trlchloro-
e thy lene
(10.0)
2/17/87
(11.1)
3/24/87
(11.0)
Benzene
(10.0)
2/17/87
(9.74)
3/24/87
(9.78)
Te trachloro-
e thy lene
(10.0)
2/17/87
(11.5)
3/24/87
(10.8)
1,3-Butadlene
(10.0)
2/17/87
(11.8)
3/24/87
(12.4) -
RTI ANALYSIS****
1st Analysis Date
PPB (9
2nd Analysis Day**
PPB (9
1st Analysis Date
PPB (9
NBS Conceri. PPB (9
2nd Analysis Day
PPB (9
NBS Concen. PPB (9
7/1/87
.71 + 0.6)
50
.80 + 0.6)
7/1/87
.40 + 0.6)
.69 + 0.5)
50
.45 + 0.6)
.69 + 0.5)
7/1/87
(10.2 + 0.7)
50
(10.5 + 0.7)
7/1/87
(10.5 + 0.8)
(10.8 + 0.5)
50
(10.6 + 0.7)
(10.8 + 0.5)
7/1/87 7/1/87
(9.73 + 0.6) (10.1 + 1.2)
50 50
(10.0 + 0.6) (10.3 + 1.2)
RTI QUALITY
7/1/87 7/1/87
(10.4 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
50 50
(10.5 + 0.7) (10.6 + 1.2)
(10.9 + 0.6) (10.6 + 1.1)
7/1/87 7/1/87
(10.1 + 0.6) (10.7 + 0.7)
50 50
(9.84 + 0.6) (10.6 + 0.7)
CONTROL***
7/1/87 7/1/87
(10.2 + 0.6) (10.5 + 0.7)
(9.95 + 0.5) (10.5 + 0.5)
50 50
(9.94 + 0.6) (10,4 +0.7)
(9.95 + 0.5) (10.5 + 0.5)
7/1/87
(9.00 + 0.5)
50
(9.27 + 0.5)
. 7/1/87
(8.96 + 0.5)
(9.36 + 0.5)
50
(9.03 + 0.5)
(9.36 + 0.5)
in/6i
(10.2 + 0.7)
50
(10.1 + 0.7)
7/1/87
(10.1 + 0.7)
(9.96 + 0.5)
50
(9.85 + 0.7)
(9.96 + 0.5)
7/1/87
(10.5 -1- 1.1)
50 .
(10.1 + 1.1)
•7/1/87
NA
(8.76 + 0.9)
50
(8.40 + 0.9)
(8.76 + 0.9)
*Callbratlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****All analyses were performed using automated cryogenic preconcentratlon with cryofocuslng followed by GC/FID.
"NA" - Not Analyzed
(Continued)
-------
STABILITY STUDY FOR GROUP V COMPOUNDS* (Continued)
Cylinder V-A6
ACTIVITY
COMPOUND
Bromome thane
Trlchloro-
fluorome thane
1,1,1-Trl-
chloroe thane
1,2-Dichloro-
propane
1 , 2-Dibromo-
e thane
Toluene
Chloro-
benzene
Ethyl-
benzene
o-Xy lene
MANUFACTURER ANALYSIS
Theoretical PPB
1st Analysis Date
PPB
2nd Analysis Date
PPB
(5.00)
2/17/87
(5.57)
3/24/87
(5.77)
(5.00)
12/23/86
(4.45)
3/24/87
(4.30)
(5.00)
2/17/87
(5.18)
3/24/87
(5.38)
(5.00)
2/17/87
(5.82)
3/24/87
(5.65)
(5.00)
2/17/87
(6.10)
3/24/87
(5.99)
(5.00)
2/17/87
(5.28)
3/24/87
(5.24)
(5.00)
2/17/87
(5.52)
3/24/87
(5.68)
(5.00)
2/17/87
(5.53)
3/24/87
(5.34)
(5.00)
2/17/87
(6.18)
3/24/87
(5.50)
RTI ANALYSIS****
1st Analysis Date
PPB
2nd Analysis Day**
PPB
7/1/87
(5.70 + 0.6)
50
(5.60 + 0.6)
7/1/87
(4.70 + 0.5)
50
(4.80 + 0.5)
7/1/87
(5. 10 + 0.3)
50
(5.17 + 0.3)
7/1/87
(5.32 + 0.3)
50
(5.20 + 0.3)
7/1/87 7/1/87
(5.27 + 0.3) (5.06 + 0.3)
50 50
(5.10 + 0.3) (4.96 + 0.3)
7/1/87
(5.14 + 0.3)
50
(5.18 + 0.3)
7/1/87
(4.97 + 0.3)
50
(4.80 + 0.3)
7/1/87
(5.23 ± 0.3)
50
(5.21 + 0.3)
RTI QUALITY CONTROL***
1st Analysis Day
PPB
NBS Concen. PPB
2nd Analysis Day
PPB
NBS Concen. PPB
7/1/87
(9.80 + 1.0)
(10.6 + 1.0)
50
(9.73 + 1.0)
(10.6 + 1.0)
7/1/87
(8.65 + 1.0)
(9.39 + 0.9)
50
(8.80 _+ 1.0)
(9.39 + 0.9)
7/1/87
(10.1 + 0.6)
(10.2 + 0.5)
50
(10.1 + 0.6)
(10.2 + 0.5)
7/1/87
(10.6 -1- 0.6)
(10.6 + 0.5)
50
(10.5 + 0.6)
(10.6 + 0.5)
7/1/87 7/1/87
(9.92 + 0.6) (10.0 + 0.6)
(9.92 -1- 0.5) (10.0 + 0.5)
50 50
(9.61 + 0.6) (10.0 + 0.6)
(9.92 + 0.5) (10.0 + 0.5)
7/1/87
(9.73 + 0.6)
(9.80 + 0.5)
50
(9.66 +0.6)
(9.80 + 0.5)
7/1/87
(9.80 + 0.5)
(10.1 + 0.5)
50
(9.59 + 0.5)
(10. 1 + 0.5)
7/1/87
(10.0 + 0.5)
(9.96 + 0.5)
50
(9.83 + 0.6)
(9.96 + 0.5)
*Callbratlon was performed using an NBS primary standard.
**Number of days after 1st RTI analysis.
***A different NBS primary standard was analyzed as Internal quality control on each day of RTI analysis.
****A11 analyses were performed using automated cryogenic preconcentra tlon with cryofocuslng followed by GC/FID.
"NA" - Not Analyzed
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APPENDIX B
AUDIT INSTRUCTIONS
B-l
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Memorandum
To: Date:
From: Cynthia Sokol, RTI
This suitcase kit is provided in conjunction with
audit gas cylinder(s) which are arriving simultaneously
via Overnite Transportation Company.
A letter accompanying the audit cylinder(s) describes
their purpose and origin.
The audit gas from the cylinder running through the
kit'-s manifold simulates the ambient emission from the
stack through your probe. Follow instructions attached
to use the kit materials for your audit.
Please return the suitcase in its shipping box, at
yourcost, through United Parcel Service (UPS). I have
included an address label for the outside of the box.
Insure the suitcase kit for $1000 (only a $2.25 charge)
Thank you!.
Research Triangle Institute
RTI-31 (rev. C. 11-83)
B-2
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YOST AUDIT KIT INVENTORY
QTY DESCRIPTION
1 GLASS MANIFOLD with Teflon nut and ferrule on one end
1 HEATING TAPE (wrapped around manifold)
1 1/8" TEFLON TUBING (about 3 feet) with:
1/4 to 1/8" brass Swage! ock1" union, one end
1/4" brass Swagelock™ nut, other end
1 REGULATOR, 2 stage, high purity, 350 GCA fitting, with
female connector
1 3/8" TEFLON TUBING, "SHORT" with:
3/8" brass Swagelock111 nut
1 ROTAMETER, 3/8" Swagelock1" female connectors on both ends
1 3/8" TEFLON TUBING, "LONG" with:
3/8" brass Swagelock1" nut
1 THERMOMETER, DIAL FACE, 8", 0-150°C
2 TWO-PRONG EXTENSION CLAMPS, 8"
2 RIGHT-ANGLE CLAMP HOLDERS, aluminum thumbscrew type
1 BASE SUPPORT, 4" x 6"
1 ROD FOR BASE SUPPORT, 5/16" diameter, 18" long
1 CYLINDER CLAMP SUPPORT WITH NYLON STRAP
1 HEATER CONTROLLER, for connection to heating tape
1 INSTRUCTION SHEET
Please notify me at once if an item is missing or defective.
Thank you for CAREFULLY repackaging all items.
Cynthia Sokol
(919) 541-6772
B-3
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INSTRUCTIONS FOR USE OF VOST AUDIT KIT
1. Assemble the support stand (base and rod). Using the clamps supplied,
secure the manifold and rotameter vertically to the stand. The larger
end of the manifold should be temporarily up, so the thermometer can be
inserted.
2. Connect the heating controller to the tape and adjust the dial to heat
the manifold to approximately 1008C.
On assemblies with 1" tape (closely wrapped), a
setting of 5 is sufficient to attain 100°C.
On assemblies with 1/2" tape (loosely wrapped), a
setting of 7-1/2 is required.
3. After the manifold temperature has become stable, remove the
thermometer, invert the manifold (larger end down) and attach the
shorter 3/8" 00 tubing by sliding the end sleeve-wise over the glass.
4. Attach the 1/8" tubing (union end) to the teflon nut on the top of the
manifold. The 3/8" Swagelock"1 nut-end connects to the regulator at the
reduced-end fitting.
5. Consult diagram for attaching rotameter, longer exhaust tubing, and
audit cylinder.
6. Adjust the regulator to start the gas flow. The audit kit-supplied
rotameter is downstream of the manifold and is used to monitor excess
gas flow.
7. The rotameter will present negligible back pressure to the manifold.
AP for 5 L/min is 1 inch of water column.
8. After sampling is completed, allow the manifold to cool, disassemble
and repackage the audit kit into the case. Remember to include the
teflon nut on the end of the manifold. The tubing can lie flat on top
of the repackaged kit, loosely coiled.
9. Ship the case inside the box it came in, by United Parcel Service
(UPS)
B-4
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INSTRUCTION SET NO. 1
INSTRUCTIONS FOR THE SAMPLING AND ANALYSIS OF VOLATILE POHC
FROM QUALITY ASSURANCE AUDIT CYLINDERS USING THE BAG TECHNIQUE
1.0 PURPOSE
This audit is intended to assess and document the accuracy and precision
of the principal organic hazardous constituents (POHC) using the bag
technique during trial burns at hazardous waste burning facilities. This
audit also can be used to determine the proficiency of source testing
organization prior to the actual trial burn tests.
2.0 PRINCIPLE
A gas sample containing POHC 1s drawn from an audit gas cylinder into a
bag. The collected POHC are analyzed by gas chromatography according to the
method specifications and procedures.
3.0 AUDIT MATERIAL (GAS CYLINDERS)
The audit material is contained in gas cylinders. A maximum of 5 L of
audit gas is to be used for each test run. A two-stage gas regulator,
1/4-inch male/female glass joints, and Teflon tubing are supplied for use
with the gas cylinder.
4.0 PROCEDURES
The following step-by-step procedures should be used for sample
collection and analysis using the bag technique.
Step A. Evacuate the bag with a vacuum pump and fill the bag with
approximately 5 L of organic-free nitrogen from a gas
cylinder. Tedlar bags are recommended. Determine the
hazardous constituents of interest by gas chromatography.
Report the concentrations determined as Blank Value 1. The
blank value must be not more than twice the detection limit.
If it is higher, the bag cleaning procedure should be
repeated.
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Step B. After the blank analysis, evacuate the bag with a vacuum pump
and fill the bag with approximately 5 L of audit gas from the
audit cylinder. The 1/4 inch male/female glass joints that
are supplied should be used as connections to the bag and the
audit cylinder. Minimum Teflon tubing should be used.
Determine the POHC of interest by gas chromatography. Report
the concentrations of each constituent as Analysis Result 1.
Step C. Evacuate the bag contents and fill the bag with organic free
nitrogen (Cleaning Step 1). After 3 minutes, evacuate the
bag contents and fill the bag again with nitrogen (Cleaning
Step 2). After three minutes, repeat the evacuation
procedure and fill the bag with 5 L of nitrogen (Blank 2).
Determine the concentration of the bag contents by gas
chromatography and report the measured concentration as Blank
Value 2. The blank value must not be more than twice the
detection limit. If it is higher, the bag cleaning procedure
should be repeated.
Step D. Evacuate the bag contents and fill the bag with approximately
5 L of audit gas from the audit cylinder. Determine the POHC
of interest by gas chromatography. Report the concentrations
determined as Analysis Result 2.
Step E. Repeat Step C and report the measured concentration of the
bag contents as Blank Value 3. The blank value must not be
more than twice the detection limit. If it is higher, the
bag cleaning procedures should be repeated.
Step F. Evacuate the bag contents and fill the bag with approximately
5 L of audit gas from the audit cylinder. Determine the POHC
of interest by gas chromatography. Report the concentrations
determined as Analysis Result 3.
5.0 SAMPLE ANALYSIS
Follow the procedures described in the method used for sample analysis,
calibration, and calculations. Submit the results to the Project Officer and
to the audit supervisor for evaluation.
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INSTRUCTION SET NO. 3
INSTRUCTIONS FOR THE SAMPLING AND ANALYSIS OF VOLATILE POHC FROM QUALITY
ASSURANCE AUDIT CYLINDERS USING THE VOLATILE ORGANIC SAMPLING TRAIN
1.0 PURPOSE
This audit is intended to assess and document the accuracy and precision
of the volatile organic sampling train (VOST) when used during trial burns at
hazardous waste burning facilities. This audit also can be used to determine
the proficiency of source testing organization prior to the actual trial burn
tests.
2.0 PRINCIPLE
A gas sample containing principal organic hazardous constituents (POHC)
is passed from an audit gas cylinder into a glass manifold and is used in
place of the test site stack sample, while the POHC gas is being passed into
the glass manifold, a major portion of the gas is drawn through a VOST
according to the method specifications and procedures. The collected POHC
are analyzed by thermal desorption, purge and trap, and gas chromatography/
mass spectrometry (GC/MS) or an equivalent method approved by the EPA.
3.0 APPARATUS
3.1 GLASS MANIFOLD
A glass manifold is supplied. One side of the glass manifold is
connected with Teflon tubing to the audit cylinder. The other end of the
glass manifold should be connected with Teflon tubing to a rotameter and the
excess gas from the rotameter should be vented into a hood. The glass
manifold is heated to 100°C with heating tape. The heating tape, rotameter,
1/4-inch male/female glass joints, and Teflon tubing are also supplied. One
port of the glass manifold should be connected to the VOST probe with
1/4-inch male/female glass joints. A schematic diagram of the glass manifold
is shown in Figure 1.
3.2 VOST COMPONENTS
The sampling train component parts, except for the glass manifold, are
the same as those used for VOST.
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3.3 ANALYSIS
Refer to the method specifications and procedures for the VOST method.
4.0 AUDIT MATERIAL (GAS CYLINDER)
The audit material is supplied in gas cylinders. A maximum of 50 L of
gas is to be used for each test run. A two-stage gas regulator is supplied
for use with the gas cylinder.
5.0 PROCEDURES
5.1 SAMPLING
5.1.1 Preparation of VOST
All train components should be cleaned and assembled as described in the
VOST method use.
5.1.3 Sample Generation
The gas sample from the audit cylinder is passed through the glass
manifold at a flow rate of 2 L/min for 3 minutes to condition the glass
system. A glass rotameter is supplied to measure the flow rate at the end of
the glass manifold. The VOST probe then should be connected to one port of
the glass manifold with 1/4 inch male/female joints and the probe should be
purged with audit gas for an additional 2 minutes so that the probe is purged
of ambient air before initiation of sample collection. This can be
accomplished either by attaching a pump to a three-way stop-cock above the
first condenser and drawing audit gas through the probe via the three-way
stop-cock or by any other suitable method.
5.2 SAMPLE COLLECTION
After leak-checking and conditioning the glass probe, sample collection
is accomplished by opening the valve at the inlet to the first condenser,
turning on the pump and sampling at a rate of 0.5 L/min for 20 minutes or
IL/min for lOmin. The sampling rate is measured with the rotameter which is
part of the VOSt. The volume of sample for any pair of the traps should not
exceed 10 L. The temperature of the gas stream at the inlet to the first
sorbent cartridge must be maintained at 20°C during sample collection.
After the collection of 10 L of sample, the train is leak-tested using
the procedures described in the method used. If leak-test criteria as
described in the method are not met, the samples should not be analyzed. If
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leak-test criteria are met, the train is returned to atmospheric pressure,
the two sorbent cartridges are removed, the end caps are replaced, and
analysis of cartridges is performed.
Repeat the sample collection procedure tow more times with two new pan's
of sample cartridges in the VOST, collect 10 L of sample each time, and
perform the analysis.
5.3 SAMPLE ANALYSIS
Follow the procedures described in the method for sample analysis,
calibration, and calculations. Report the amount of each constituent in the
three samples and the blank values to the Project Officer and the audit
supervisor for evaluation.
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1/8 to 1/4"
Union
1/8" Teflon
Audit
Tank
00
I
Cylinder
Strap
Glass Manifold
& Heat Tape
Long 3/8"
Tube
Output from Variable
Excess
to Hood
3/8" Swagelok
Rotometer
3/8" Swagelok
Variable
Transformer
Mounted in Case
: 110 VAC
Line Cord
Travel Case
Figure 1. Schematic Diagram of Audit Material Delivery System
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