Untied States
                         Control Technology Center
           EPA-600/8-90-085a
December 1990
&EPA
      LANDFILL AIR EMISSIONS ESTIMATION MODEL



                  USER'S MANUAL
           control  ^ technology center

-------
                                                EPA-600/8-90-085a
                                                December 1990
LANDFILL AIR  EMISSIONS  ESTIMATION  MODEL

                    USER'S  MANUAL
                            by:

                       W. Richard Pelt II
                        Robert L Bass
                         Irene R. Kuo
                        A. L Blackard
                      Radian Corporation
                     Post Office Box 13000
                Research Triangle Park, NC 27709
                    EPA Contract 684)2-4286
                      Work Assignment 48
                        Project Officer

                      Susan A. Thomeloe
           Air and Energy Engineering Research Laboratory
               U.S. Environmental Protection Agency
                Research Triangle Park, NC 27711
                        Prepared for

               U. S. Environmental Protection Agency
               Office of Research and Development
                    Washington, O.C. 20460

-------
   CONTROL TECHNOLOGY CENTER

               Sponsored by:
         Emission Standards Division
  Office of Air Quality Planning and Standards
     U.S.Environmental Protection Agency
      Research Triangle Park, NC 27711
Air and Energy Engineering Research Laboratory
     Office of Research and Development
     U.S.Environmental Protection Agency
      Research Triangle Park, NC 27711
 Center for Environmental Research Information
     Office of Research and Development
     U.S.Environmental Protection Agency
            Cincinnati, OH 45268
                    11

-------
                                    PREFACE

      The  Control  Technology  Center  (CTC) was established by  the U.S.
Environmental  Protection Agency's  (EPA's) Office of Research  and Development
(ORD) and  Office of Air Qxiality Planning and Standards  (OAQPS) to provide
technical  assistance  to state and  local air pollution control agencies.  Three
levels  of  assistance  can be accessed through the CTC.   First, a CTC HOTLINE
has been established  to provide telephone assistance on matters relating to
air pollution  control technology.  Second, more in-depth engineering
assistance can be  provided when appropriate.  Third, the CTC  can provide
technical  guidance through publication of technical guidance  documents,
development of personal computer software, and presentation of workshops on
control technology matters.

      The  personal computer software projects, such as  this one, focus on
topics  of  national or regional interest that are identified through contact
with state and local  agencies.  In this case, the CTC became  interested in
assisting  state and local agencies in estimating landfill air emission rates.
This interest  was  prompted by numerous requests for technical assistance from
state and  local agencies on how to estimate landfill air emissions and
guidance on how the gas can be collected and controlled.  This interest was
also prompted  by the  upcoming New Source Performance Standard (NSPS) and
lll(d)  Guidelines  for Municipal Solid Waste Landfill Air Emissions, which are
expected to be proposed later this year.

      This  document is a user's guide for the program,  "Landfill Air Emissions
Estimation Model."  This estimation model is based on the Scholl Canyon Gas
Generation Model,  which was used in the development of  the soon-to-be proposed
Clean Air  Act  (CAA) regulations for landfills.  The Scholl Canyon model is
described  in Reference 26.  The recommended default values provided in the
program as  input variables for the Scholl Canyon Model were developed for the
draft NSPS  and guidelines.  These values are based on test data collected for
landfill regulation development.  Development of these  default values is
outlined in Reference 20.  The test data are summarized in Chapter 3 of
Reference  1.

      It should be noted that the default input values provided by the program
and the user's guide  may be revised depending on any future information
collected by the Agency.
                                      ill

-------
                                   ABSTRACT

      This document is a user's guide for a computer program entitled,
"Landfill Air Emissions Estimation Model."  This manual provides step-by-step
guidance for using this program to estimate landfill air emissions.  The
purpose of this program is to aid local and state agencies in estimating
landfill air emission rates for nonmethane organic compounds and individual
air toxics.  This program will also be helpful to landfill owners and
operators affected by the upcoming New Source Performance Standard and
Emission Guidelines for Municipal Solid Waste Landfill Air Emissions.

      The model is based on the Scholl Canyon Gas Generation Model, which was
used in the development of the soon-to-be proposed regulation for landfill air
emissions.  The Scholl Canyon Model is a first order decay equation that uses
site specific characteristics for estimating the gas generation rate.  In the
absence of site-specific data, the program provides conservative default
values taken from the soon-to-be proposed NSPS for new landfills and emission
guidelines for existing landfills.  These default values may be revised based
upon any future information collected by the Agency.
                                     IV

-------
                              EPA REVIEW NOTICE

     This report has been reviewed by the U.S.  Environmental Protection
Agency and approved for publication.   Approval  does not signify that the
contents necessarily reflect the views and policy of the Agency, nor does
mention of trade names or commercial  products constitute endorsement or
recommendations for use.

     This document is available to the public through the National  Technical
Information Service, Springfield,  Virginia  22161.

-------
                                   Contents
Section                                                                 Paj


Preface	     iii
Abstract	     iy
Figures	     vi
Tables	     vi
Terms	    vii
Acknowledgment	   viii

1.0   Introduction	      1

2.0   Installation	      2

      Floppy Drive  Installation	      2

      Hard Disk  Installation	      2

3.0   Operation	      3

      Running  the Program	      3
      The Model  Help  System	      3
      Main Menu	      4
         Specify Study.	      4
         Edit  Study Data	'.	      7
               Chemical Composition	      7
                          Air Toxics	      9
               Methane Rate Constant	     12
               Methane Generation Potential	     12
               Operational Data	     15
                          Year Open/Current Year	     15
                          Design Capacity	     15
                          Entering Refuse in Place	     15
                          Predicted Closure Year	     15
         Calculate  Air Emissions	     17
         Display Results	     17
         Configure  Program	     21
         Exit	     21

4.0   References	     23

      APPENDIX - Example User Session	     25

-------
                                    Figures

Number                                                                 Page

3-1   Introductory Screen	        5
3-2   Main Menu	        5
3-3   Specify Study Type Sub-Menu	        5
3-4   Specify Study Name Entry Screens	        6
3-5   Choose a Study to Edit Window	        6
3-6   Edit Study Data Sub-Menu	        8
3-7   Edit Chemical Composition Data Entry Screen	        8
3-8   Edit Air Toxics Concentration Entry Screen	       10
3-9   Warning Screen Prior to Returning Air Toxics to Their
      Default Values	       10
3-10  Edit Methane Generation Decay Rate Constant Sub-Menu	       13
3-11  Methane Generation Rate Constant Entry Screen	       13
3-12  CFR Method 2E Warning Screen	       14
3-13  Calculate Methane Gas Generation Constant Data Entry Screen.       14
3-14  Methane Generation Capacity Data Entry Screen	       14
3-15  Edit Refuse Data Periods Data Entry Form	       16
3-16  Closure Periods Screen	       16
3-17  Calculation in Progress Screen	       18
3-18  Calculation Summary	       18
3-19  Display Results Sub-Menu	       18
3-20  Choose a Chemical to Report Screen	       19
3-21  Example Graphics Display	       19
3 - 22  Tabular Report Menu	       20
3-23  Output Filename Entry Screen	       20
3-24  Example Model Results Output	       20
3-25  Edit System Configuration Screen	       22
3-26  Save Study Menu	       22
3-27  Exit Screen	       22


                                    Tables

Number

3-1   Format of AIRTOXIC.TXT	
                                      VI

-------
                                     Terms
Term

Nonmethane Organic Compounds (NMOC)
Potential Methane Generation Capacity (Lo)
Methane Generation Rate Content (k)
Landfill Capacity
Year of Closure
Air Toxics
            Definition

NMOC is specified in this
program as the fraction of
landfill gas containing
nonmethane organic compounds
expressed as hexane.   This
includes air toxics and
volatile organic compounds
which are precursors of ozone.
NMOC concentration can be
measured using guidance
provided by the soon-to-be
proposed EPA Method 25C.

Value for the potential amount
of methane generated.  Lo
varies by refuse type.

A constant that determines the
rate of gas generation.  The
Scholl Canyon model assumes
that k prior to the peak and k
after the peak are the same.
k is a function of moisture
content, availability of
nutrients for methanogens, pH,
and temperature.
The total amount of refuse
be disposed of in the
landfill.
to
The year in which the landfill
ceases, or is expected to
cease, accepting waste.

Compounds found in landfill
gas that are classified as
toxic, such as vinyl Chloride
and benzene.
                                      vn

-------
                                ACKNOWLEDGMENT
      The author of the program was Robert Bass of Radian Corporation.  Also
serving on the EPA project team were W. Fred Dimmick and Mark Najarian of the
Office of Air Quality Planning and Standards.
                                     Vlll

-------
                               1.0  INTRODUCTION

      In the past year, the Environmental Protection Agency (EPA) has
responded to over 100 requests  for technical assistance from state and  local
regulatory agencies on how to estimate landfill air emissions and guidance on
how gaseous emissions can be collected and controlled.

      The Landfill Air Emissions Estimation Model Program is a computer
program for state and local regulatory agencies to use as a tool for
estimating landfill air emissions.  This program will also be of help to
landfill owner/operators responding to the requirements resulting from the
soon-to-be proposed New Source  Performance Standards (NSPS) and Emission
Guidelines for Municipal Solid  Waste (MSW) Landfills.  Additional information
on the model and the model inputs is provided in Chapter 3 of the Background
Information Document (BID) for  Municipal Landfill Air Emissions.1  This method
for estimating landfill air emissions is based on a first order decay equation
that employs site specific characteristics such as the year the landfill
opens, the amount of refuse in  place and the design capacity.   The program
also suggests default values for inputs when site specific information is
unavailable.

      This manual presents a reference for the features and commands for the
program.  The user's guide specifically addresses the operation of the
software, and additional information concerning the development and
theoretical basis of the calculations used in the program can be found in
References 1, 24, 25, and 26.   Section 2 explains the procedures for
installing the program on a personal computer.  Section 3 discusses the
commands needed to use the program.   An example user session is outlined in
the Appendix.  This manual should be thoroughly read before using the program.

-------
                               2.0  INSTALLATION

      The  Landfill Air  Emissions  Estimation Model requires an IBM compatible
model of a personal  computer  running DOS 2.0 or higher.  The computer must
also have  at  least one  floppy disk drive and 512 kilobytes or more of main
system memory.

      Before  installing or using  the program, make a backup copy of the
program and its  data files (AIRTOXIC.TXT. MSHERC.COM, LANDFILL.HLP, and
LANDFILL.CFG).   Store this backup copy in a safe place for use only if
something  were to happen to the working copy of the program.

      The  program may be run  either from a floppy disk or from a hard disk.
However, hard disk installation is recommended as information can be accessed
more quickly.


FLOPPY DRIVE  INSTALLATION

      For  floppy drive  use, no special installation steps are required.
Simply insert a  working copy  of the program diskette into the disk drive
whenever the  program is to be run.

HARD DISK  INSTALLATION

      To install the Landfill Air Emissions Estimation Model program on a hard
disk, first create a directory by using the following command:

      MD \LANDFILL

Then, copy all of the files from  the program diskette to the new directory by
typing :

      COPY A:*.* \LANDFILL

Finally, before  trying  to run the program, change to the LANDFILL directory by
typing:

      CD \LANDFILL

The program may  be activated  from any directory on the system by specifying
the full path (i.e.,  c:\LANDFILL\LANDFILL) or by adding the landfill directory
to the system search path (Path - ).

-------
                                 3.0  OPERATION

       This  section is a detailed guide  to  the Landfill Air Emissions
 Estimation  Model program.   Suggestions  and hints  intended to help the user
 take  full advantage of the program also are  included.

 RUNNING  THE PROGRAM

       For most users, running the program  is as simple as typing the program
 name  'LANDFILL'  at the DOS prompt.   However, for  users with HERCULES GRAPHICS
 CARDS (HGC),  the driver MSHERC.COM must be loaded prior to running  the
 program.  Failure to do so will prohibit displaying graphical  information with
 HGC cards.

       To load the MSHERC driver, type  'MSHERC' at the DOS prompt and press
 [ENTER].  The message

             HERCULES RESIDENT VIDEO  SUPPORT ROUTINE.  Section  1.11

 should appear.  The driver software  is  a terminate and stay resident (TRS)
 application and need not be loaded again if DOS has continued  to execute since
 MSHERC was  loaded.  However,  attempting to load MSHERC again is harmless and
 will  result in the message

             HERCULES VIDEO SUPPORT ROUTINES are already installed

 being displayed.  If at any time the system  requires rebooting or power is
 interrupted,  the MSHERC must be reloaded.


       If a  hardcopy of graphical information is needed, the user must activate
 the graphics  utility GRAPHIC.COM prior  to  running the program.  This will
 allow the user to print any graphical  information from the screen to a printer
 by simply pressing the print screen  key.

       To load the GRAPHICS utility,  type 'GRAPHICS' at the DOS prompt and
 press [ENTER].

       To activate the Landfill Air Emissions Estimation Model  program, type

                                   LANDFILL

 at the DOS  prompt.  If the disk directory  in which the model resides is not
 being occupied and the system search path  (set by the PATH - command) does not
 contain  the directory in which the program resides, it is necessary to enter
 the entire  path  to the program (e.g., c:\LANDFILL\LANDFILL) to activate the
 program.

       Once  the program has been activated, the system will display  an
 introductory  message as shown in Figure 3-1  and will pause until the user
 presses any key.   After pressing a key,  the program will display the main menu
 of choices  available.   The Main Menu is shown in  Figure 3-2.

 THE MODEL HELP SYSTEM

       Help  information is  available  for most of the menus and  data  entry
 screens.  To view the help available for a given  menu, press the  [Fl] key.
The help screen  will display  all the available  information concerning that
menu  or data entry screen.  Help information may  contain several screens of

-------
 information and  the current offset of this information is depicted by the
 small arrows  in  the left margin.  In addition to the full help screens, a
 reminder  of the  function keys  is provided at the bottom of each menu or data
 entry form.

 MAIN MENU

      The program uses bar menus, which appear in the center of the computer
 display to control the actions of the program.  You may select an entry from
 the menu  by using the cursor motion keys ([up arrow] and  [down arrow]) to
 highlight the desired entry and pressing [ENTER] .  After an entry has been
 selected, the program will either perform some action or present another menu
 of options (a sub - menu) .  To exit a sub-menu and return to the previous menu,
 press [ESC] .


      The selections available in the Main Menu are listed below:

                              Descrition
      Specify Study*          Designates a study name to revise or create.
      Edit Study Data         Edits model parameters and operational data.
      Calculate Air Emissions Calculates the air emissions estimates.
      Display Results         Prints the report of the emission estimates.
      Configure Program       Allows designation of the working directory.
      Exit                    Exits the program and returns to DOS .

      * A study name must be  specified before any other function can by
        performed.

Specify Study

      This selection causes the Specify Study sub-menu to be displayed, as
shown in Figure 3-3, that lets the user choose between either naming a new
study to create or recalling  an old study to update.  Upon making a selection
from this sub -menu, one of the study name entry screens displayed in
Figure 3-4 will appear.  A listing of the old studies on file can be viewed by
pressing [F2] .  An example of this window is shown in Figure 3-5.  A study can
be selected from this window  by using the cursor motion keys ([up arrow] and
[down arrow]) and then pressing [ENTER] to enable the study.  The user may
create a new study by typing  the desired name while within the specify New
Study Name entry screen, and  then simply pressing [ENTER] to return to the
main menu.  The study name can be up to 8 characters in length.

-------
                Landfill
              Air Emissions
             Estimation Model
               Version 1.0
    Figure 3-1.  Introductory Screen
                Main Menu
              Specify Study
             Edit Study Data
         Calculate Air Emissions
             Display Results
            Configure Program

                  Exit
         Figure 3-2.  Maj.n Menu
              Specify Study
                New Study
                Old Study
Figure 3-3.  Specify Study Type Sub-Menu

-------
            Specify New  Study  Name
            Specify  Old  Study Name
Figure 3-4.  Specify Study Name Entry Screens
            Choose  a  Study  to  Edit
              LANDFIL1
              LANDFIL2
              LANDFIL3
              LANDFIL4
              LANDFIL5
 Figure 3-5.   Choose a Study to Edit Window

-------
 Edit Study Data

       The Edit Study Data option causes  the  sub-menu shown  in Figure  3-6  to
 appear.

       The selections available  in this sub-menu are:

       Command                Description

       Chemical Composition   Edits  the  composition of the  landfill gas.
       Methane Rate  Constant   Edits  the  methane generation  rate constant.
       Methane Potential       Edits  the  methane potential constant.
       Operation Data         Edits  the  landfill operational data.

 Chemical  Composition--

       Landfill gas  is generated from the anaerobic decomposition of refuse in
 Municipal Solid Waste Landfills.   The gas composition is typically about
 50 percent methane  (CH4)  and 50 percent  carbon dioxide (C02) with  trace
 amounts of nonmethane organic compounds  (NMOCs) and air toxics species.

       The Chemical  Composition  option from the Edit Study Data sub-menu
 displays  the  landfill gas Chemical Composition data entry form as shown in
 Figure 3-7.   Data entry  forms are used to obtain input values from the user.
 A data entry  form consists of several data entry fields, each of which accepts
 a specific piece of information.   A  different field may be  selected by using
 the  cursor motion keys  ([up arrow] and [down arrow]) to highlight the desired
 field.  A default value  may be  displayed in  the field, but  this value may be
 overwritten.   Once  the desired  value has been entered, simply press [ENTER] to
 proceed to the next field.

       There are three data entry fields  for  the Chemical Composition data
 entry  form: methane,  NMOC, and  air toxics.   The default composition for CHA
 and  C02 is  50  percent each.  The  default concentration of NMOCs is 8000 ppmv
 as hexane.  Additional information concerning the rationale for selecting the
 default NMOC  concentration, is  provided  in Reference 20.  Concentrations at
 individual NMOCs were obtained  from  46 landfills for the upcoming Clean Air
Act  regulations.  The median non-zero values for the nine air toxics were
 selected  as the suggested default values.  For additional information
 concerning NMOC and air  toxics  concentration data, refer to the Background
 Information Document (BID).1  The  concentration of methane may be entered by
 the  user.   The corresponding concentration of C02 will automatically be
calculated assuming that C02 is the  remainder of the landfill gas.  At any
point  during  data entry  into the  Chemical Composition data  entry form, the
highlighted field may be returned to its default value by pressing [F2] .

       Landfill gas  also  contains  trace levels of NMOC.  The NMOC concentration
determines  the NMOC emission rate once the landfill gas flowrate has been
estimated.  The NMOC concentration is a  function of the types of refuse in the
landfill  and  the extent  of the  reactions which produce various compounds  from
the  anaerobic  decomposition of  municipal refuse.   Data were collected from
emission  test  reports from industry,  state and local regulatory agencies,
including the  South Coast Air Quality Management District (SCAQMD),2'8"19  The
data from 23  landfills range from 237 to 14294 ppmv.  Based on an analysis
conducted for  the soon-to-be proposed regulation, the suggested default value
for NMOC  is 8000 ppmv.   This analysis is documented in Reference  20.   This
memorandum  can be found  in the  Public Docket, No. A-88-09.  Because the NMOC
concentration  does  vary,  collection  of site-specific data using soon-to-be-
proposed  EPA method 25C  is encouraged.21

-------
                     Edit Study Data
                   Chemical Composition
                Methane Rate Constant  (k)
                  Methane Potential  (Lo)
                     Operational Data

                      Previous Menu
          Figure 3-6.   Edit Study Data Sub-Menu
                Edit Chemical Composition
     jj    NMOC  : 8000.000000

          CH    : 50.000000
            4
                           ppm Volume

                           % Volume
          CO    : 50.000000
            2
                           % Volume


Include Individual Air Toxics :    YES
Figure 3-7.  Edit Chemical Composition Data Entry Screen

-------
      Air Toxics--

      Air toxics may be included in the analysis.  The space bar toggles the
Include Air Toxics option within the Chemical Composition data entry form.
After the desired values have been selected from the Chemical Composition data
entry form, [F10] must be pressed in order to accept the data.  If air toxics
were chosen to be included in the study, then upon accepting the data, the
data entry form shown in Figure 3-8 will appear with the list of air toxics
along with their default concentrations.  As stated previously, the suggested
default concentrations for the air toxics are the median non-zero values
obtained from 46 landfills.  This data was collected for the upcoming Clean
Air Act (CAA) regulations.  A more complete description of the air toxics data
can be found in Chapter 3 of the Background Information Document.1  Again,  the
default concentrations can be overwritten.  Air toxics can be added or deleted
from this list by pressing [F5] or [F6], respectively.  The default air toxics
and their concentrations can be retrieved by pressing [F2].  The warning
screen shown in Figure 3-9 will appear prior to retrieving the default air
toxics and the default concentrations.  As in other data entry screens, [F10]
must be pressed for the data to be accepted.  Air Toxics may be added
permanently to the default list by editing the file AIRTOXIC.TXT with a text
editor or a word processor in non-document mode.  The format for entering data
into this file is shown in Table 3-1.  The format consists of 30 characters
for the chemical name, 10 digits for molecular weight, and 9 digits for the
concentration.  Codisposal or Superfund sites should use the upper end of the
range of air toxics concentrations.  However, it is recommended that all
facilities obtain toxic composition data using EPA Method 18, which can be
found in reference 22, as previously recommended by EPA's Emissions
Measurement Branch of the Office of Air Quality Planning and Standards.
Additional information concerning Codisposal or Superfund sites is provided in
Reference 23.

-------
                       Edit Air Toxics Concentrations
            Chemical
              Molecular Wt.     Concentration  (ppm V)
 Benzene
 Carbon Tetrachloride
 Chloroform
 Ethylene Dichloride
 Methylene Chloride
 Perchloroethene
II Trichloroethene
IIVinyl Chloride
jj 1,1 -Dichloroethylene
                 78.120000
                153.810000
                119.380000
                 98.960000
                 84.930000
                165.830000
                131.290000
                 62.500000
                 96.940000
 2.65
15.00
 0.08242
 1.85
20.00
 6.82
 2.02
 5.61
 0.292
         Figure  3-8.   Edit Air Toxics Concentration Entry Screen
                                 CAUTION
                   The action you are taking will reset
                    the ENTIRE air toxics list to its
                              default state.
        Figure 3-9.
Warning Screen Prior to Returning Air Toxics
    to their Default Values
                                    10

-------
                Table 3-1.  Format of AIRTOXIC.TXT

Air Toxic Chemical            Molecular Wt      Concentration (ppmv)

Benzene                       78.12             2.65
Carbon Tetrachloride          153.81            15.00
Chloroform                    119.38            0.08242
Ethylene Dichloride           98.96             1.85
Methylene Chloride            84.93             20.00
Perchloroethene               165.83            6.82
Trichloroethene               131.29            2.02
Vinyl Chloride                62.50             5.61
1,1-Dichloroethylene          96.94             0.292
                                11

-------
 Methane Rate Constant--

       This selection causes  the  Edit Methane  Generation Rate Constant  sub-menu
 to appear as shown in Figure 3-10.   This  screen  allows for  the selection of
 the following three methods  for  setting the methane generation rate constant:

       Use Default Value  of k (0.02   1/yr)
       Supply a Value of  k
       Calculate a Value  of k

 The first option allows  the  use  of  a default  k value of 0.02.  Further
 information is provided  in the Background Information Document, Reference 1,
 as well as References 24 and 25.  The next option allows entry of an
 alternative decay rate constant.  The data entry form for this option appears
 in Figure 3-11.

       The third selection branches  to a data  entry screen allowing the entry
 of parameters specific to the draft and soon-to-be proposed CFR method 2E
 testing procedures.   Prior to this  screen, another screen will appear
 informing the user that  CFR  method  2E testing or comparable testing must have
 been performed in order  to perform  the calculations.  This  screen is shown in
 Figure 3-12.   If the Calculate a Value of k option is chosen, the Calculate
 Methane Gas Generation Constant  data entry screen, presented in Figure 3-13,
 will be displayed.   All  of the parameters  must be non-zero  in order for a
 value  of k to be calculated.  A  value of  k will  appear once all parameters are
 non-zero.   The calculated value  of  k can  be changed simply  by changing one of
 the input parameters and pressing  [ENTER].  Again, the default values may be
 overwritten and [F10] must be pressed in  order to accept the value of k that
 has been calculated.

       The  methane generation rate constant, k, determines the methane
 generation rate (for each submass of refuse).  The higher the value of k, the
 faster the methane  generation rate  increases  and decreases  over time.  The
 value  of k is a function of  the  following factors: (1) refuse moisture
 content,  (2)  availability of the nutrients for methanogens, (3) pH, and
 (4)  temperature.   The k  values obtained from  the data collected for the
 upcoming CAA regulation  for  municipal solid waste landfill  air emissions from
 SCAQMD data (1982-1986),  section 114 letter responses range in value from
 0.003  to 0.21.1  These values were  obtained from both theoretical models using
 field  test data as well  as from  actual measurements.  The suggested default
value  for  k is  0.02,  and the method for deriving this value is outlined in
Reference  20.

Methane  Generation Potential--

       This  option allows the user to input a  Methane Generation Potential
Constant(Lo).   The suggested default value of 8120 ft3/Mg already in place may
be  overwritten.   Press [ENTER] in order to accept the chosen value.  The data
entry  screen  for  the  Methane Generation Potential Constant  is shown in
Figure  3-14.

      The  value  for  the  Methane  Generation Potential Constant(Lo) of refuse
depends  only  on the  type of  refuse  present in the landfill.  The higher the
cellulose  content of  the refuse, the higher the  value of Lo.  The values of
theoretical  and obtainable Lo reported in Reference 22 range from 220  to 9540
ft3 CH4/Mg refuse.  The default  value of  Lo is 8120  ft3/Mg,  and the method for
deriving  this value  is outlined  in  Reference  20.
                                       12

-------
         Edit Methane Generation Decay Rate Constant
             Use Default Value of k  (0.02 yr"-l)
                     Supply a Value of k
                   Calculate a Value of k
Figure 3-10.  Edit Methane Generation Decay Rate Constant Sub-Menu
                  Methane Generation Rate Constant
             I   k :   0.020000
  A m
yr -1
   Figure 3-11.  Methane  Generation Rate  Constant Entry  Screen
                                13

-------
                     To calculate a k value,  you must have
                     performed the field tests as outlined
                     in Method 2E (to be proposed Fall
                     1990).   Press ESCAPE to  return to the
                     previous menu.
               Figure 3-12.  CFR Method 2E Warning Screen.
                  Calculate Methane Gas Generation Constant
          Average Well Depth            0.000000          ft
          Average Stabilized
               Radius of Influence      0.000000          ft
          Refuse Density                0.650000          Mg/ft"3
          Fraction of
               Decomposable Refuse      1.000000
          Methane Generation Potential  8120.000000       ft*3/Mg
          Stabilized Flow Rate          0.000000          ft"3/min
          Average Age of Refuse         0.000000          yr
             Calculated Value of k   0.020000
                                                         yr
Figure 3-13.  Calculate Methane Gas Generation Constant Data Entry Screen
                   Methane Generation Capacity of Refuse
Lo :   8120.000000
                                                    3
                                                  ft /Mg
       Figure 3-14.  Methane Generation Capacity Data Entry Screen
                                    14

-------
 Operational Data--

       The Operational Data selection causes  the  Edit Refuse Data Periods  data
 entry screen,  presented in Figure 3-15,  to appear.  This data entry  screen
 allows the user to enter the operational history of a  landfill.  Data  entry
 occurs in two  distinct parts:  landfill  operational parameters and  specific
 landfill history.

       Year Open /  Current Year--

       Upon activation of the entry screen, the user is permitted to  change the
 landfill opening year and current year  parameters.  For a new study, the
 default  current year is determined from the  computer system clock  and  the
 opening  year defaults to 10 years prior to that  year.  Both of  these
 parameters can be  changed by the  user.

       Design Capacity--

       Upon keying  the year open and current  year into  the entry screen, the
 design capacity of the landfill may then be  entered.   For a new study  the
 maximum  capacity of the landfill  is initialized  to zero, and a  value must be
 entered  before proceeding further.   The value in place for an old  study may be
 changed  in order update the study.   After accepting this information by
 pressing [F10]  or  [ENTER],  the operational parameters  are verified for
 appropriateness.   The design capacity of the landfill  cannot be zero and  the
 operating life of  the landfill must be  less  than the computer program memory
 limitation of  300  years.

       Entering Refuse in Place--

       After successful validation of the landfill operating parameters, the
 user will be permitted to enter the landfill history consisting of yearly
 total  refuse-in-place information for the years  of operation.   The list of
 years  may be scrolled up or down  using  the cursor motion keys ([up arrow],
 [down  arrow],  [page up],  or [page down]).  Initially,  all data  is  zero.  The
 user should enter  the refuse-in-place for all years known.  The [up  arrow] key
 can be used to go  back to and correct previously entered values.   If any value
 (except  the current year which cannot be zero) is zero, the program  will
 interpolate using  surrounding values after the list is accepted.   The  last
 value  entered  does not require [ENTER]  to be pressed for it to  be  accepted.
 Instead,  "F10)  must be  present to accept all values.   The list  may be  returned
 to its all-zero state by pressing [F2].

      After accepting the history data  by pressing [F10] , the data will be
verified  for validity.   Each successive year cannot be less than the previous
year (except in the zero case,  which indicates unknown data) and must  always
be less  than or equal to the design capacity.

      Predicted Closure Year--

      Successful entry  of the  operational data will cause the program  to
determine  refuse in place for  all years listed as zero.  The program then
determines  the  acceptance rate for the  last  one  year period entered  in the
history list and uses this  rate to project the closure year.  Finally, the
screen presented in Figure  3-16 will appear.  If the landfill has  not  reached
the design  capacity,  the user  will be given  the  choice of either accepting or
altering  the calculated year of closure.  If the landfill has already  reached
capacity,  the user will not be permitted to  change the closure  year.
                                       15

-------
               Edit  Refuse  Data  Periods
   Year  Opened :  1980    ||  Current  Year  :  1990
   	                 n

       Capacity :  0.000000               Mg
        Year             Refuse  In Place  (Mg)
Figure 3-15. Edit Refuse Data Periods Data Entry Form
              For  the  period data  entered,
       the  expected year  of closure  is  determined
                         to be

                         1992

         assuming a refuse acceptance  rate  of

                  10000.000000     Mg/year

           from  current year to  closure year.
        Figure  3-16.   Closure  Periods  Screen
                          16

-------
       If the year of closure is changed and accepted by pressing  either  [F10]
 or [ENTER],  the program will verify that the period  of operation  of  the
 landfill is  less than the program limitation of  300  years.   If  the closure
 year is valid,  the program will recalculate the  refuse acceptance rate
 necessary to reach design capacity by the entered year of closure.
 Operational  data must be entered for each new  study  in order for  calculations
 to take place.   If no other data is entered into the model,  default  parameters
 will be used in the calculations.   Once the operational data has been entered
 and accepted by the program,  the Edit Study Data menu will reappear.  If  all
 of the study data has been entered, simply select the Previous  Menu  option  to
 return to the Main Menu.

 Calculate Air Emissions

       This selection from the Main Menu causes the program to perform the air
 emissions calculations.   While the calculations  are  taking place, the
 Calculation  in  Progress screen shown in Figure 3-17  will appear.  After the
 calculations are complete a Calculation Summary  will appear;  an example
 Calculation  Summary is shown in Figure 3-18.   Pressing any key  will  cause the
 Main Menu to reappear.

 Display Results

       The Display Results selection from the Main Menu will  cause the sub-menu
 shown to Figure 3-19 to appear,  which gives the  user the option of presenting
 the data in  a Tabular Report or On-Screen Graphic format.  If the On-Screen
 Graphic option  is selected and a Hercules Graphics Card is being used then
 MSHERC must  be  activated prior to running the  program.  This  is done by typing
 MSHERC while in the sub-directory containing the program and pressing [ENTER].
 Once the On-Screen Graphic option is selected, the screen shown in
 Figure 3-20  will allow the user to select a chemical to view in graphic form.
 An example graphics display is presented in Figure 3-21.  The on-screen
 graphics display may be dumped to a dot matrix printer for a hardcopy, if the
 GRAPHICS.COM utility was  loaded prior to running the program.   Also, the
 tabular report  file can be imported into Lotus 1-2-3 by using the file import
 function (/FIN).   Some of the data at the top  of the spreadsheet will appear
 muddled;  however,  the tables of data used to generate the graphical  analysis
 will  remain  applicable,  and can be used to generate  Lotus graphs.

       If the Tabular Report option is chosen,  then the Tabular  Report sub-menu
 shown in Figure 3-22 will appear.   This sub-menu gives the user the  option of
 sending the  report to the screen,  printer,  or  to a file.  If the Output to
 File  option  is  chosen,  the entry form shown in Figure 3-23 will appear.   This
 entry form lets the user  enter the filename under which the  report is to  be
written.  The file will be written to the current working directory; this can
be viewed or changed by selecting the Configure  Program option  from  the Main
Menu.   Once  an  option is  chosen then as described before, Figure  3-20 will
appear  so that  a chemical for reporting can be chosen.  After a selection has
been  made, the  report will be displayed on the screen, printed  by the printer,
or written to a file.   If the report will not  be printed by  the printer then
see  the  Configure Program section for details.   An example report is shown  in
Figure  3-24.
                                       17

-------
                           Calculation  in Progress
                              Current Year

                            Please Wait  ...
               Figure  3-17.  Calculation  in Progress  Screen
                             Calculation  Summary
    Current Year Results  : 1990
                           Maximum Year Results :  1992
Methane
Carbon Dioxide
NMOC
 3.651E+002  Mg/yr
 1.933E+007  Cft/yr

1.002E+003  Mg/yr
1.933E+007  Cft/yr
Methane
4.115E+002  Mg/yr ||
2.178E+007  Cft/yr ||
Carbon Dioxide :  1.129E+003  Mg/yr ||
                 2.178E+007 Cft/yr||
 3.139E+001  Mg/yr   ||  NMOC
 3.092E+005  Cft/yr  ||
                 3.538E+001  Mg/yr1
                 3.486E+005 Cft/yr ||
                     Figure 3-18.  Calculation Summary
                           Display Results Menu
                              Tabular Report
                             On-screen Graphic

                               Previous Menu
                  Figure 3-19.  Display  Results  Sub-Menu
                                     18

-------
                           Choose a Chemical  to Report
                       Methane
                       Carbon Dioxide
                       NMOC
                       Benzene
                       Carbon Tetrachloride
                       Chloroform
                       Ethylene Dichloride
                       Methylene Chloride
               Figure 3-20.   Choose a Chemical to Report Screen
!i
H>
t*
14.8-
13.8-
12.8-
11.8-
18.8-
 9.8-
 i.B-
 7.8-

 3.8-
 4.8-
 3.8-
 2.8-
 1.8-
 8.8
                                          Inissi«n IUt«
        1980 1982 1984 198C 1981 1998 1992 1994 199f 1998 2000 2002 2004 200C 2008 2818
                                 y»«r <• = Cunwnt V*ar>
               	  KstiiMtvA lulsilons  	  Pr>oJ»ct»J Iiilsslons	
                    Figure  3-21.   Example  Graphics Display
                                       19

-------
                       Tabular Report Menu
                        Output  to  Screen
                        Output  to  Printer
                         Output to File

                          Previous Menu
               Figure 3-22.  Tabular Report Menu
                      Enter Output Filename
           Figure  3-23.  Output Filename Entry Screen
                        View Model Results
                        Model Parameters
Lo  : 8120.000000 Cft / Mg
k : 0.020000 1/yr

NMOC : 8000.000000 ppmv
Methane  : 50.000000 % volume
Carbon Dioxide  : 50.000000 % volume
                      Landfill Parameters
Year Opened  : 1980    Current Year  : 1990    Year Closed  : 1992
Capacity  : 150000.000000  Mg
Average Acceptance Rate  : 13000.000000  Mg/year
Average Acceptance Rate Required from
   Current Year to Closure Year :   10000.000000 Mg/year
          Figure 3-24.  Example Model Results Output
                              20

-------
        ^ Pro
      The Configure Program option from the Main Menu allows the user to
select the working directory for the program and the Default Print Device.
The Edit System Configuration screen is shown in Figure 3-25.  The working
directory is the directory from which all study files are loaded and save
study parameters' are placed.  There are four options for the Default Print
Device: LPT1, LPT2, COM1, and COM2.  A different option may be viewed by
pressing the space bar; once the desired Default Print Device is shown, simply
press [ENTER] to accept the device and return to the main menu.

Exit

      The Exit program option allows the user to exit the program.  Before
exiting, the user will be asked if the current study is to be saved.  This
screen is shown in Figure 3-26.  Next, the screen shown is Figure 3-27 will
appear asking the user if the program is to be exited.
                                       21

-------
            Edit System Configuration
 Working Directory :  C:\LANDFILL\

 Default Print Device :   LPT1
Figure 3-25.  Edit System Configuration Screen
            Do you wish to save the
                current study?
                     Yes
                     No
         Figure  3-26.   Save  Study Menu
         |   Do you wish to exit?
                     Yes
                     No
          Figure  3-27.   Exit  Screen
                      22

-------
                                4.0  REFERENCES
1.



2.


3.


4.



5.



6.



7.



8.


9.


10.


11.


12.


13.


14.


15.


16.


17.
U.S. Environmental Protection Agency.  Air Emissions From Municipal
Solid Vaste Landfills.  Background Information for Proposed Standards
and Guidelines.  March 12, 1990.  (Draft)

South Coast Air Quality Management District.  Landfill Gas Emissions.
Report of the Task Force.  July 1982.

SCS Engineers.  Gas Emission Rates from Solid Waste Landfills.  Memo to
Allen Geswein, EPA-OSW.  November 17, 1986.

Pohland, F.G., and Harper, S.R.  Critical Review and Summary of Leachate
and Gas Production from Landfills.  EPA/600/2-86/073 (NTIS PB86-240181).
August 1986.

Blanchet, M.J. and Staff of the Pacific Gas and Electric Company.
Treatment and Utilization of Landfill Gas.  Mountain View Project
Feasibility Study.  EPA-530/SW-583, 1977.

Bogner, J.E.  The U.S. Landfill Gas Resource:  Low-cost Biogas from
Municipal Solid Vaste.  Argonne National Laboratory, Argonne, IL.
Prepared by U.S. Department of Energy.  January 11, 1988.

DeValle, F.B., Chian, E.S.K., and E. Hammerberg, 1978, Gas Production
from Solid Waste in Landfills, J. Environmental Engineering Division
ASCE, 104(EE3):415-432.

South Coast Air Quality Management District.  Source Test Report.
85-592.  El Monte, CA.  December 1985.
South Coast Air Quality Management District.
84-496.  El Monte, CA.  October 1984.

South Coast Air Quality Management District.
85-511.  El Monte, CA.  November 1985.
Source Test Report.


Source Test Report.
South Coast Air Quality Management District.  Source Test Report.
86-0342.  El Monte, CA  July 1986.

South Coast Air Quality Management District.  Source Test Report.
85-102.  El Monte, CA.  February 1985.

South Coast Air Quality Management District.  Source Test Report.
87-0391.  El Monte, CA.  December 1987.

South Coast Air Quality Management District.  Source Test Report.
86-0220.  El Monte, CA.  May 1986.

South Coast Air Quality Management District.  Source Test Report.
87-0110.  El Monte, CA.  April 1987.

South Coast Air Quality Management District.  Source Test Report.
87-0318.  El Monte, CA.  October 1987.

South Coast Air Quality Management District.  Source Test Report.
87-0329.  El Monte, CA.  October 1987.
                                      23

-------
18-   South Coast Air Quality Management District.  Source Test Report.
      87-0376.  El Monte, CA.  November 1987.

19.   South Coast Air Quality Management District.  Source Test Report.
      85-461.  El Monte, CA.  September 1985.

20.   Memorandum. Kuo, I.R., Radian Corporation, to Alice Chow, EPA.
      "Rationale for Selecting Tier 1 Default Values".   April 18,  1990.
      Docket A-88-09.

21.   Regulatory Package for New Source Performance Standards and lll(d)
      Guidelines for Municipal Solid Waste Air Emissions.  Public Docket No.
      A-88-09.

22.   Title 40 Code of Federal Regulations (CFR) Part 60, Appendix A.

23.   Memorandum, Kuo, I.R., Radian Corporation, to Anne Pope, EPA.  Subject:
      Air Emission from Codisposal Superfund Site - Phase I.  February 8,
      1990.

24.   Memorandum.  McGuinn, Y.C., Radian Corporation, to Susan Thorneloe, EPA.
      Subject:  Use of Landfill Gas Generation Model to Estimate VOC Emissions
      from Landfills.  June 21, 1988.  Docket A-88-09.

25.   Memorandum. McGuinn, Y.C., Radian Corporation, to Susan Thorneloe, EPA.
      Subject:  Sensitivity Analysis of Landfill Gas Generation Model.
      June 21, 1988.  Docket A-88-09.

26.   Emcon Associates.  Methane Generation and Recovery from Landfills.
      1982.
                                      24

-------
                                   APPENDIX


                              EXAMPLE USER SESSION

 SCENARIO-

 Landfill Design Capacity:           1,000,000 Mg

 Annual Acceptance  Rate:             35,000 Mg/yr  from  1980  to 1990

 Year Open:                          1975

 Refuse in place in 1980:            150,000 Mg

 STEPS:

 1.        At  the Main Menu select  the  Specify  Study option.

 2.        Select New Study.

 3.        Enter "test" for the  study name for  this example.

 4.        Select the Edit  Study Data option from the  Main  Menu.

 5.        Select Chemical  Composition  from the Edit Study  Data sub-menu.

 6.        Since site-specific data on  methane  NMOC concentration, and toxics
          concentrations are  not specified for this example landfill, use the
          suggested default chemical compositions provided.

 7.        Accept the chemical composition data by pressing F10.

 8.        Use  the  suggested default toxics concentrations  provided.  (For this
          example  it is assumed that Method 18 testing has not been done.)

 9.        Accept the air toxics concentrations by pressing F10.

 10.       Select the Methane  Rate  Constant (k) option from the Edit Study Data
          sub-menu.

 11.       Since site-specific testing  was not  performed for this example
          landfill,  select the  Use Default Value of k (0.02 1/yr).

 12.       Select the Methane  Potential (Lo) option.

13.       Accept the suggested  default for Methane Generation Capacity
          (8120 ft3/Mg).

14.       Select the Operational Data  option from the Edit Study Data sub-
          menu.

15.       Enter 1975 as the year open.


                                       25

-------
16-       Enter 1990 current year.


17-       Enter the design capacity of 1,000,000 Mg.

18.       Enter 150,000 Mg of refuse in place for 1980, and add 35,000 Mg each
          year until 1990.  For this example: 150,000 Mg in 1980 then an
          additional 35,000 Mg each year.  The refuse-in-place for 1990 will
          be 500,000 Mg.

19.       Accept these data by pressing F10.

20.       The expected year of closure should be 2005 assuming an acceptance
          rate of 33333.3 Mg/year from the current year to closing year.

21.       Accept the generated year of closure and refuse acceptance rate by
          pressing F10.  For this example it is assumed that the year of
          closure calculated was acceptable.

22.       Select the Previous Menu option from the Edit Study Data sub-menu to
          return to the Main Menu.

23.       Select the Calculate Air Emissions option.

24.       A calculation summary with the following results should appear:

     Current Year Results: 1990                 Maximum Year  Results  2005

Methane        1.234E+003 Mg/yr           Methane        2.335E+003 Mg/yr
               7.120E+007 Cft/yr                         1.236E+008 Cft/yr

Carbon Dioxide                            Carbon Dioxide
               3.691E+003 Mg/yr                          6.407E+003 Mg/yr
               7.120E+007 Cft/yr                         1.236E+008 Cft/yr

NMOC           1.156E+002 Mg/yr           NMOC           2.007E+002 Mg/yr
               1.139E+006 Cft/yr                         1.978E+006 Cft/yr


25.       Press any key to return to the Main Menu.

26.       Select the Display Results option.

27.       Select the Tabular Report option.

28.       Select the Output to Screen option.

29.       Select Benzene as a chemical to report.

30.       A detailed report of benzene emissions for  the study results  may
          then be reviewed on the computer screen.  For benzene, the emissions
          in the year 2015 should be 4.935 x 10'2 Mg or 5.364 x 102 cubic
          feet.
                                       26

-------
31.       Return to the Tabular Report Menu by pressing ESC.

32.       Return to the Display Results Menu by pressing ESC.

33.       Return to the Main Menu by pressing ESC.

34-       Select the Configure Program option.

35.       Make sure the Working Directory is the desired directory to which
          the study should be saved.

36.       Select the Exit option.

37.       Save the current study.

38.       The study has been saved and the program has been exited.

39.       If the study needs to be used again, then simply go into the program
          and select the Old Study option under the Specify Study Type sub-
          menu.

40.       Now enter "test."

41.       Study name "test" is now enabled and can be revised or accessed to
          make new reports.
                                       27

-------
                                 TECHNICAL REPORT DATA
                          (Please read Inamctions on the reverse before completing!
1. REPORTNo	'—'	
 EPA-600/8-90-085a
              3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
 Landfill Air Emissions Estimation Model User's
 Manual
              5. REPORT DATE
               December 1990
              6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)             ~~~
 W. R. Pelt II. R.L.Bass, I. R.Kuo,  and A. L. Blackard
              8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Radian Corporation
 P. O. Box 13000
 Research Triangle Park, North Carolina 27709
              10. PROGRAM ELEMENT NO.
              11. CONTRACT/GRANT NO.
               68-02-4286, Task 48
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA,  Office of Research and Development
  Air and Energy Engineering  Research Laboratory
  Research Triangle Park,  North Carolina  27711
              13. TYPE OF REPORT AND PERIOD COVERED
               Task Final;  2-9/90
              14. SPONSORING AGENCY CODE

               EPA/600/13
15.SUPPLEMENTARY NOTES> AEERL grpjpct officer is SusanA. Thorneloe,  Mail Drop 63. 919/
 541-2709. EPA-600/8-90-085b is related disk.                            K
16.ABSTRACT The document is a user's guide for the computer program,  Landfill Air
 Emissions Estimation Model." It-provides step-by-step guidance for using the pro-
 gram to estimate landfill air  emissions. The purpose of this program is to aid local
 and state agencies in estimating landfill air emission rates for nonmethane organic
 compounds and individual air toxics.  This program will also be helpful to landfill
 owners and operators affected by the upcoming New Source Performance Standard
 (NSPS) and Emission Guidelines for  Municipal Solid Waste Landfill Air Emissions.
 The model is based on the Scholl Canyon Gas Generation Model, used in the develop-
 ment of the soon-to-be-proposed regulation for landfill air emissions.  The Scholl
 Canyon Model is a first order decay equation that uses site-specific  characteristics
 for estimating the gas generation rate.  In the absence of site-specific data, the  pro-
 gram provides conservative default values from the soon-to-be-proposed NSPS for
 new landfills  and emission guidelines for  existing landfills.  These default values may
 be revised based on future information  collected by the Agency.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                           b.lDENTIFIERS/OPEN ENDED TERMS
                          c.  COS AT I Field/Group
Air Pollution      Organic Compounds
Mathematical Models
Emission          Toxicity
Earth Fills
Estimates
Waste Disposal
 Air Pollution Control
 Stationary Sources
                                                                     13B   07C
                                                                     12A
                                                                     14G   06T
                                                                     13 C

                                                                     15 E
8. DISTRIBUTION STATEMENT
Release to Public
                                           19. SECURITY CLASS (ThisReport)
                                           Unclassified      	
                                                                       NO. OF PAGES
                                36
                                           20. SECURITY CLASS (This page)
                                           Unclassified
                                                                    22. PRICE
  Form 2220-1 (9-73)
28

-------