1989 AUTOMATED AND DIURNAL NONMETHANE
 ORGANIC COMPOUND MONITORING PROGRAM
           SAMPLING STUDY
            FINAL REPORT
      CORPORATION

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DCN No. 89-203-080-60-05
Radian No. 203-080-6C
EPA No. 68-02-439?
                     1989 AUTOMATED AND DIURNAL NONMETHANE
                      ORGANIC COMPOUND MONITORING PROGRAM
                                SAMPLING STUDY
                                  FINAL REPORT
                                 Prepared for:

                              Mr.  Stanley  F.  Sleva
                      U.S.  Environmental  Protection  Agency
                  Research  Triangle  Park,  North  Carolina  27711
                                  Prepared  by:

                               Radian  Corporation
                                 P.O.  Box 13000
                  Research Triangle Park,  North Carolina 27709
                                November 7,  1989

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                               TABLE  OF  CONTENTS


Section                                                                 Page

1.0  Summary and Conclusions   	    1

2.0  Introduction  	    3

     2.1  Objectives	    4
     2.2  Experimental Approach    	  ....    4

3.0  Results	    8

     3.1  1989 Raleigh, NC Monitoring Program  	    8

     3.2  Diurnal  Samples	   12
          3.2.1  Raleigh Monitoring  Program Samples
                    vs. Diurnal Samples	   14
          3.2.2  Integrated Diurnal  Samples at Six
                    Sampling Periods  	   17
          3.2.3  APDFID Samples  Compared to Diurnal Samples  	   20

     3.3  APDFID Data  Characterization   	   22
          3.3.1  Correlations  Among  APDFID Data  	   30

4.0  Equipment  Performance   	   35

     4.1  Diurnal  Integrated Sampling System Description   	   35
          4.1.1  Three-hour  Integrated  Sampling  System   	   35
          4.1.2  Twelve-hour  Integrated Sampling System  	   36
          4.1.3  Twenty-four-hour  Integrated Sampling System  ....   36

     4.2  Automated Cryogenic  Preconcentration and
             Flame  lonization Detection  System    	   38
          4.2.1  Recommended modifications for the  APDFID  system  .  .   39

     4.3  APDFID Calibration,  Audit  and Zero Results   	   39
          4.3.1   Initial  Calibration of APDFID System  	   40
          4.3.2  Daily Response  Factor   	   40
          4.3.3  Audit Results	   40
          4.3.4  Daily Zero	    43

5.0  Conclusions	    45

6.0  References	    47
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                         TABLE  OF CONTENTS  (Continued)


Appendices

  A         Calculation of Time  in Minutes for the Diurnal Program

  B         1989 APDFID Diurnal  Monitoring Study, RLNC Site;
              Hourly Meterological and NMOC Concentration Data

  C         APDFID Diurnal Concentration and Meterological Data
              Averaged by Diurnal Sampling Periods

  D         APDFID NMOC Concentrations and Meterological Data
              Averaged for the 6:00 a.m. to 9:00 a.m. Time Interval

  E         APDFID NMOC Concentrations and Meterological Data
              Averaged for the 9:00 a.m. to Noon Time Interval

  F         APDFID NMOC Concentrations and Meterological Data
              Averaged for the Noon to 3:00 p.m. Time Interval

  G         APDFID NMOC Concentrations and Meterological Data
              Averaged for the 3:00 p.m. to 6:00 p.m. Time Interval

  H         APDFID NMOC  Concentrations and Meterological Data
              Averaged for the 6:00 p.m. to 6:00 a.m. Time Interval

   I         APDFID NMOC  Concentrations and Meterological Data
              Averaged for the 6:00 a.m. to 6:00 a.m. Time Interval
 jlh.006                               ii

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                                LIST OF  FIGURES
Figure

  1      Automated and diurnal nonmethane organic compound study
         sampling schematic	
  2      NMOC Monitoring Program concentrations for Raleigh, NC.

  3      NMOC Monitoring Program concentrations for Raleigh, NC -
         expanded scale	
  4      Stem-and-leaf plot of the PDFID NMOC concentrations for
         RLNC site, 6:00 a.m. to 9:00 a.m. samples  	
  5      Duplicate NMOC sample results comparing average concentration
         with absolute percent difference.   	
  6      Stem-and-leaf plot of the APDFID NMOC hourly and PDFID
         concentrations for the RLNC site	
  7      Hourly mean  NMOC concentrations	

  8      Hourly minimum, mean,  and maximum concentrations	

  9      Hourly median  NMOC  concentrations	

  10      Boxplots  of  NMOC concentrations  for each hour of the day  .

  11      Propane calibration curve for APDFID  apparatus    	

  12      Response  factors for APDFID  apparatus	

  13      Daily  zero for APDFID apparatus	
 jlh.006                              iii

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                                LIST OF TABLES


Table                                                                   Page

  1     Automated and Diurnal NMOC Monitoring Sampling Schedule  ....    5

  2     NMOC Monitoring Program   1989 RLNC Site	    13

  3     RLNC Samples vs.  Integrated Diunral Samples  	    15

  4     1989 Raleigh Diurnal Site Samples  	    18

  5     Comparison  of  Integrated Sampling  Period Means   	    19

  6     Comparison  of  PDFID  and APDFID Concentrations at  Various
        Sampling  Periods	    21

  7     1989 Raleigh APDFID  NMOC Data	    24

  8     Correlation Matrix for Diurnal Variables   	    32

  9     Results  of  Analyses  of Covariance  	    33

  10     Schedule  of Activity for Collection of  Integrated
        Samples	    37
 jlh.006                               iv

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                         1.0  SUMMARY AND CONCLUSIONS

      A study was performed to validate the automated cryogenic
preconcentration and direct flame ionization detection (APDFID) system to
measure ambient air nonmethane organic compound (NMOC) concentrations
continuously. The study was conducted during a four-week period in Raleigh, NC
between July 23 and August 19, 1989.  Additional  3-hour,  12-hour, and 24-hour
integrated canister samples were taken and analyzed for NMOC concentration by
the cryogenic preconcentration and direct flame ionization detection (PDFID)
method for comparative purposes.
      Temperature, barometric pressure, relative humidity, wind speed, wind
direction, solar radiation intensity, and N02 and  NOX  concentrations  were
recorded throughout the sampling period.  The overall 6:00 a.m. to 9:00 a.m.
concentration average was 0.159 ppmC.  No trends of NMOC concentrations as
functions of the meteorological variables or humidity were apparent.
      No significant differences were detected between APDFID NMOC
concentration measurements and the NMOC concentration measurements made by the
PDFID system using integrated ambient air canister samples.  NMOC
concentration measurements by the APDFID system averaged within 10%  of the
integrated PDFID measurements.
      The integrated 3-,  12-  and 24-hour diurnal canister sampling system
operated in  an  acceptable manner.  There was a significant difference between
the weighted average 3- and 12-hour NMOC measured concentrations when compared
to the 24-hour  sample concentration.
      Another objective of the study was to obtain ambient air NMOC
concentrations  throughout the day to help decide the  most appropriate time(s)
to sample air for NMOC concentration.   For both the 3-hour integrated canister
samples, and the APDFID results, the 6:00 a.m. to 9:00 a.m.  samples  appeared
to have the  highest average NMOC concentration of any of  the 3-hour  periods
during daylight hours.  Since the primary use of the  NMOC concentration  is  to
predict the  generation of ozone through the photolysis reactions,  it appears
that the 6:00 a.m. to 9:00 a.m. time period  is an appropriate  averaging
period.
jlh.006                                1

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      To determine whether a different time interval  is more appropriate,
would require comparing an ozone prediction model with actual NMOC, NOX,  and
03 data throughout daylight hours,  and/or predaylight hours,  to determine
which time interval resulted in the closest fit to the model.  Such a
comparison was beyond the scope of this study.
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                              2.0   INTRODUCTION

      From July 23 through August 19,  1989 Radian Corporation field tested two
approaches for obtaining NMOC concentrations throughout the 24-hour day.  The
first approach involved the use of an  APDFID instrument which was capable of
automatically acquiring, cryogenically preconcentrating, and analyzing ambient
air for NMOC.  The APDFID instrument had the capacity to take and analyze
about four NMOC concentration measurements per hour.  The instrument took an
integrated 9-minute sample and analyzed the sample during the next 6-minutes.
The complete sampling analysis cycle was about 15 minutes.  The instrument is
designed to operate unattended 24-hours per day.
      The second approach involved the use of SUMMA®-treated stainless steel
canisters to acquire six integrated ambient air samples for various segments
of the day.  Three-hour integrated whole ambient air samples were taken every
other day from 6:00 a.m. to 9:00 a.m., 9:00 a.m.  to noon, noon to 3:00 p.m.,
and 3:00 p.m. to 6:00 p.m.  A 12-hour sample was taken from 6:00 p.m. to
6:00 a.m., and a 24-hour sample was taken from 6:00 a.m. to 6:00 a.m.  These
six integrated samples were taken and analyzed to verify and confirm the
results of the APDFID instrument.
      All sampling was done at the U.S. Environmental Protection Agency 1989
Raleigh (RLNC) NMOC monitoring site.1   Both the automated and integrated
diurnal ambient air samples were taken from a common sampling manifold, and
analyzed by  the PDFID methodology described in Compendium Method TO-12.2
Samples collected and analyzed for the APDFID diurnal study and for the EPA
NMOC site at Raleigh were  included in this study for comparison purposes.  The
standard NMOC samples from the Raleigh site were included because they
represent data from a collocated site.  In addition to  the NMOC results,
meteorological data (wind  speed, wind direction, relative humidity, solar
radiation intensity, and temperature) were continuously  recorded for  the
entire duration of the  study.  Hourly station barometric  pressure readings
were obtained from the weather bureau at  the Raleigh-Durham airport.
      Three  types of samples  are discussed  in this  report:   (1) The  RLNC
samples came from the Raleigh, NC site and were  6:00 a.m. to  9:00  a.m.

jlh.006                                3

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integrated canister samples collected with separate NMOC Monitoring Program
samplers and analyzed by the PDFID method; (2) Integrated diurnal samples were
collected on the manifold diagrammed in Figure 1 and analyzed by the PDFID
method according to the schedule specified in Table 1; and (3) APDFID samples
(9-minute samples) were taken approximately four times per hour.  The APDFID
samples were integrated to one-hour averages.  The one-hour averages were also
averaged into various time intervals to compare the APDFID results with the
RLNC samples and the integrated diurnal samples.

2.1   OBJECTIVES
      The primary objectives of the automated and diurnal NMOC sampling
study were:
      1.    To  obtain the NMOC concentration data with integrated 3-hour,
            12-hour, and 24-hour samples  (and with automated 24-hour data),
            necessary to help decide the most appropriate time(s) during the
            day to  sample air for its NMOC concentration; and
      2.    To  validate the mechanical reliability, precision, and accuracy of
            the APDFID  instrument in sampling ambient air and analyzing its
            NMOC  concentration continuously  for a four-week period.

      An  additional  objective was to relate  the NMOC concentration to
temperature,  humidity,  solar radiation intensity, and a wind velocity vector
directed  from the  potential sources of air-borne organic chemicals to the
site.   The  main source  of  air-borne organic  chemicals near the RLNC  site was
from automobile traffic on  North Boulevard (U.S. 1) about 1500 feet  west of
the  site.

2.2    EXPERIMENTAL  APPROACH

      Table 1 gives the monitoring  sample  schedule  for both the  automated  and
integrated  diurnal  samples.  Both types of samples  were  obtained for a
four-week period.   The  automated unit was  calibrated  (zero and  span)  every
other day using a propane  standard  referenced to a  National  Institute of
Standards and Technology  (NIST).  The  automated  and diurnal  study sampling
device  was  separate from  the sampling manifold3 used for the  1989  Raleigh  NMOC
jlh.006                               4

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       TABLE 1.  AUTOMATED AND DIURNAL NMOC MONITORING SAMPLE SCHEDULE
Weekday
Sunday
Monday
Tuesday
Wednesday
Thursday
Friday
Saturday
Sample Numbers Scheduled to Beein Sampling
Week 1
4 7
258
3 6
1
8
*
147
258
3 6
]_
8
*
147
258
3 6
1
8
*
4 7
258
•5 C.
Week 2
8
*
147
258
3 6
1
8
*
147
258
3 6
1
8
*
147
258
3 6
8
-J-
Week 3
4 7
258
3 6
1
8
*
147
258
3 6
1
8
*
147
258
3 6
1
8
~k
4 7
258
•3 C
Week 4
8
*
147
258
3 6
1
8
*
147
258
3 6
1
8
*
147
258
3 6

Sample Numbers and Description:
   1.     6:00 a.m. to 9:00 a.m.  Raleigh Sample for NMOC Monitoring Program
   2.     6:00 a.m. to 9:00 a.m.   3-hour diurnal sample
   3.     9:00 a.m. to 12:00 Noon 3-hour diurnal sample
   4.     12:00 Noon to 3:00 p.m. 3-hour diurnal sample
   5.     3:00 p.m. to 6:00 p.m.   3-hour diurnal sample
   6.     6:00 p.m. to 6:00 a.m.  12-hour diurnal sample
   7.     6:00 a.m. to 6:00 a.m.  24-hour diurnal sample
   8.     APDFID NMOC instrument. 24-hour sampling daily
   *      Indicates calibration of APDFID instrument between 9:00 a.m. and
          6:00 p.m.
jlh.006

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Monitoring Program site.  Figure 1 shows a schematic diagram of the sample
manifold used for both the automated and integrated diurnal samples.  The
sampling manifold inlet for the automated and diurnal samples was collocated
with the sample inlet for EPA's 1989 Raleigh NMOC monitoring site, and was 12
feet above ground level.  Three-hour, 12-hour, and 24-hour integrated whole
ambient air samples were taken in 6-liter (L) stainless steel canisters.  The
RLNC samples were 3-hour integrated whole ambient air samples taken in
canisters from 6:00 a.m. to 9:00 a.m., Monday through Friday.  Simultaneously,
an APDFID instrument was used to acquire and analyze four 9-minute NMOC
samples per hour, 24 hours per day for the full 4-week sampling period.  The
APDFID system was not able to sustain 24-hour sampling for long periods of
time.  The reasons for  sampling interruptions are discussed below along with a
discussion of measures  which could overcome the problems and enable the
instrument to operate reliably over longer periods of time.  As noted in Table
1 the APDFID  instrument was calibrated every other day.  This caused a planned
one-hour  interruption in the APDFID sample acquisition schedule.
      The automated monitoring, and diurnal sampling matrix is given in
Table 1.  Sample  Numbers 1 through 8 distinguish between the several types of
samples being taken during the study.  Sample No. 1, the regular 6:00 a.m. to
9:00  a.m. NMOC Monitoring Program  (RLNC) sample was  collected at the Raleigh
site  and  analyzed at Radian's Research Triangle Park, NC laboratory.  Sample
No.  1 used  a  separate sampling train and inlet manifold, and samples were
acquired  Monday  through Friday from June 5,  1989, through  September 29,  1989.
       Integrated  diurnal samples  (Samples Nos. 2 through 7) were collected
every other day,  including Saturday  and Sunday, over the four-week  study
period.   Sampling times were  set  so  that "Sunday" samples, for example,  began
at  6:00  a.m.  on  Sunday.  The  24-hour  sample  scheduled to begin at 6:00  a.m.
Sunday  extended  to  6:00 a.m.  on Monday.  Likewise the  12-hour  integrated
sample  scheduled  to  begin on  Sunday  at  6:00  p.m. extended  to 6:00 a.m.  on
Monday.   Three-hour  diurnal  samples  were taken during daylight hours  according
to  the  schedules  shown  in Table  1.
 jlh.006

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                         Continuous
                           Sample
                           System
               24-hr Sample
                   System
             (6 a.m. - 6 a.m.)
                                  Automated
                               Preconcentration
                                 Direct Flame
                              lonization  Detector
(A)  Sample Manifold Inlet

@  2ft S.S. Filter Assembly

(C)  Standard 75mL/min Orifice

©  Metal  Bellows 151 Pump

(E)  Digital Timer

(F)  Micro  Metering  Valve set at
^   19mL/min

(5)  Micro  Metering  Valve set at
^   lOmL/min

@  Magnalatch Valve

(T)  6-L Sample Canister

(T)  Automated  NMOC Instrument

(K)  Slip Stream Pump
                         3 —hr Sample
                            System
                        (3 p.m. - 6 p.m.)
                  1 2 —hr Sample
                     System
                (6 p.m. — 6 a.m.)
  3-hr Sample
     System
3—hr Sample
  System
3-hr Sample
   System
(12  noon - 3 p.m.)  (9  a.m. - 12 noon)  (6 a.m. - 9  a.m.)
                            Figure 1.  Automated and diurnal nonmethane organic compound
                                                  study sampling schematic.
                                                                                                                          a.
                                                                                                                          T*
                                                                                                                          O
                                                                                                                          o>
                                                                                                                          M

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                                  3.0  RESULTS

The results for this study are discussed and compared in three ways.  The
results discussed in this section include those from the RLNC samples, the
integrated diurnal samples, and the APDFID samples.  The purpose of showing
all the data is to demonstrate how the 6 a.m.  to 9 a.m. NMOC concentrations
during the sampling interval for the diurnal sampling period (July 23 through
August 19) fit into the overall 6 a.m. to 9 a.m. NMOC concentrations for the
entire summer.
      NMOC concentrations for the 6 a.m. to 9 a.m. diurnal integrated samples
are compared to the RLNC NMOC concentrations in Table 3.  The APDFID data are
presented and compared to the data from integrated diurnal samples and the
RLNC  samples in Table 4.  Finally, the APDFID results are characterized by
hours, sample periods, and as functions of meteorological variables.

3.1    1989 RALEIGH, NC MONITORING PROGRAM

      The NMOC concentrations from the 1989 Raleigh, NC monitoring site are
given in  Figures  2, 3, and 4.  The RLNC samples include all the data from the
1989  NMOC Monitoring Program at Raleigh, NC for the period from June 5 through
September 29, 1989.  Figure 2 shows the NMOC concentrations on the vertical
axis  with the same  scale used for sites in the  1988 NMOC Monitoring Program
Final  Report/  This scale shows the relative magnitude of RLNC measurements
to the scale required to accommodate  other sites  around the U.S.  Two
horizontal  lines  are shown  in Figures 2 and 3 representing the RLNC mean NMOC
concentrations equal to 0.159 ppmC, and the overall mean NMOC concentration  of
0.583 ppmC  at 21  sites  in  the  1989 NMOC Monitoring  Program.  The  Raleigh 1989
NMOC  mean concentrations averaged about 1/3 the value  of the overall mean
concentrations at 21 sites  in  1989.
       Figures 2  and 3 also  show the period of time  in  which diurnal  sampling
took  place,  from  1989 Julian date 204 (July 23) through  1989 Julian date 230
(August  19).  Figure 4 displays the NMOC Monitoring  Program concentrations  at
the  1989  RLNC site  in a  stem-and-leaf plot.  The  column  of digits on  the  left
are  the  stems and the series of digits  on  the left  are the  leaves,  and  are
separated from the  stems by  an open channel.  The minimum  concentration  is  the
jlh.006                                8

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o

CL
d

cf
o
o;
o

o
O

O
O


z
      5.0 • —
               1989 RALEIGH NMOC MONITORING DATA

                        6:00 a.m. to 9:00 a. m  Canister Sample
      4.0
3.0 -
2.0 -
      1 0
      o.o
         150
                       Overall mean at 21 NMOC Monitoring sites for 1989
                                                            RLNC Overall Mean
             170
190
230
250
                      210


                  1989 Julian Date


Figure 2.  NMOC Monitoring Program concentrations for Raleigh, NC.
270

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o

a.
a.

fZ
o
i+-*
CO
+z

CD
O

O
O

O
O
      0.6
      0.5
0.4
0.3 -
      0.2 -
      0.1
      0.0
               1989 RALEIGH NMOC MONITORING DATA

                        6:00 a.m. to 9:00 a.m. Canister Sample
                          Overall mean at 21 NMOC Monitoring sites for 1989
               i     i

         150        170
                                —I	T

                                210
 I     l     i—

250        270
                    190        210        230


                          1989 Julian Date


Figure 3. NMOC Monitoring Program concentrations for Raleigh, NC-expanded scale

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    44444 55555 55555
    66667 7
          88899 9999
    00000 01111 1
0
0
0 H
1
1 M 23333
    44555 55
    66677
    8999
  H 00000
    22223
    55
    66677
    8
1
1
1
2
2
2
2
2
3
3
3
3
3
4
5
     22
     4

     889
     0
     25
                           Statistics
NMOC
Concentration
ppmC
                           Cases                94.

                           Minimum               0.043
                           Lower Hinge (H)       0.083
                           Median (M)            0.131
                           Mean                  0.159
                           Upper Hinge (H)       0.209
                           Maximum               0.551
                           Standard Deviation    0.101
                           Skewness              1.434
                           Kurtosis              2.143
         Figure  4.   Stem-and-leaf plot of the  PDFID NMOC  concentrations
             for the  1989  RLNC  site, 6:00 a.m. to 9:00  a.m.  samples.
jlh.006
                                       11

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first 4 in the first leaf (at the top of the plot)  and is equal  to 0.043 ppmC;
the maximum concentration is in the lowest leaf at  the bottom of the plot and
is equal to 0.551 ppmC.  Each NMOC concentration analyzed from the 94
integrated morning ambient air samples is plotted,  depending on  its magnitude
in one of the leaves of the plot.  "M" on the plot  locates the stem of the
median, which is 0.131 ppmC.  The median indicates  that 50% of the NMOC
concentrations are less than that of the median, while 50% are larger.  "H"
marks the stems for the upper and lower hinges.  The hinges divide the median
into half again, so that 25% of the NMOC concentrations are smaller than the
lower hinge (0.083 ppmC at the top part of the plot); and the upper hinge,
0.209 ppmC marks the concentration which is larger than 75% of the NMOC
concentrations measured.  The stem-and-leaf plot shows the data to be
approximately lognormally distributed which is consistent with the frequency
distributions found previously.4
      Table 2 summarizes the 1989 RLNC site data for several periods
throughout the summer.  The data were divided into months and statistics were
calculated for each month.  In addition, summary statistics are shown for the
period  of July 23 through August 19,  1989 which was the time period during
which  the diurnal sampling was taking place.  The results show that the NMOC
median  concentration was highest in June, declining every month through
September.  The median concentration  during the diurnal sampling period was  in
line with the concentrations throughout the remainder of the summer.

3.2    DIURNAL SAMPLES
       Two kinds of diurnal  samples were obtained and analyzed.  One type
included  the  3-,  12-,  and 24-hour ambient air samples, which we have  called
integrated diurnal samples, and which were taken in SUMMA* treated canisters
and  analyzed  by  PDFID.  The second type of diurnal samples were taken from the
sampling  manifold and  analyzed  by the APDFID system.  Hourly concentrations
for  the APDFID samples were numerically  integrated from
9-minute  sample  intervals,  and  then  appropriate 3-, 6-,  and 24-hour  averages
of the  hourly APDFID  results were compared to the NMOC concentrations from the
integrated diurnal canister samples.  The RLNC  6:00 a.m.  to 9:00  a.m.
integrated samples were compared to  the diurnal integrated  6:00 a.m.  to  9:00
a.m. canister samples  in Section 3.2.1.
jlh.006                               12

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                                                 TABLE 2.   1989 NMOC MONITORING PROGRAM -  1989 RLNC SITE
Time
Interva 1
June
June
July
Aug
Sept
5 - Sept 29
5 - June 30
1 - July 31
1 - Aug 31
1 - Sept 29
Win Median Mean
Cases ppmC ppmC ppmC
94 0.0430 0.1305 0.1592
20 0.0585 0.1839 0.2063
22 0.0515 0.1450 0.1771
28 0.0430 0.1145 0.1450
24 0.0463 0.0891 0.1200
Max
ppmC
0
0
0.
0
0.
.5505
.5505
.3865
.4050
5255
Std Dev Skewness
ppmC ppmC
0.1062 1.434
0.1093 1.597
0.0995 1.855
0.0983 1.232
0.1060 2.585
Kurtosls
ppmC
2
2.
-0.
0.
7.
.143
999
3670
869
030
 July 23 - Aug 19
                                     0.0430
                                                0.1145
                                                            0.1597
                                                                       0.4050
                                                                                   0.1163
                                                                                                 0.925
                                                                                                              -0.380
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      Each of the comparisons performed to evaluate the equivalency of the
integrated canister samples analyzed by the PDFID method with the APDFID
samples averaged over the same time periods,  is described in this section.

3.2.1    Raleigh Monitoring Program Samples vs. Diurnal Samples

      In Table 3, the 6:00 a.m. to 9:00 a.m.  NMOC concentrations for the
integrated diurnal samples are compared to the NMOC concentrations for the
RLNC samples (also 6:00 a.m. to 9:00 a.m.).  The second column in Table 3
gives NMOC concentrations for the RLNC samples and the third column gives the
integrated diurnal sample concentrations for the 6:00 a.m. to 9:00 a.m.
interval.  The fourth through the seventh columns give statistics comparing
the concentrations of the two samples.  Difference is defined relative to the
RLNC sample:

             Difference  =  (Diurnal   RLNC).                             (1)

Percent  difference is defined as:

             % Difference =  (difference/average) x 100,                  (2)

where  average is  the mean  of the RLNC and the diurnal  sample concentrations.
Absolute % difference is the absolute value of % difference.  Averages and
standard deviations of  all  columns  except the  first column are given.  By
inspection,  average difference,  average % difference, and average absolute %
difference are  not significantly different from zero.
       Average %  difference  and average absolute % difference may  be compared
to  similar statistics for  1988 NMOC Monitoring Program duplicate  samples/
For  the  1988 duplicate  samples average % difference was  equal to  0.313
compared to   1.524 for  the  duplicate pairs in  Table 3.   Absolute  % difference
for  the  1988 NMOC Monitoring  Program averaged  8.72 compared  to  12.82  for  the
RLNC-Diurnal samples.
       Figure 5  offers an explanation for the observed  behavior.   Duplicate
sample concentrations for  the  1988  Monitoring  Program  averaged  0.591  ppmC,
while  Table  3 shows the 6:00  a.m.  to 9:00  a.m. diurnal  samples  to average
jlh.006                                14

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            TABLE 3.   RLNC SAMPLES VS.  INTEGRATED DIURNAL SAMPLES
1989
Julian
Date
Sampled
206
208
212
214
218
220
224
226
228
228
230
Average =
Count =
Std Dev =

RLNC
NMOC
ppmC
0.258
0.089
0.204
0.113
0.079
0.054
0.083
0.201
0.405
0.391
0.056
0.1757
11
0.1287
Diurnal
6-9 a.m.
NMOC
ppmC
0.117
0.099
0.208
0.118
0.079
0.062
0.080
0.206
0.407
0.407
0.072
0.1686
11
0.1278


Difference
ppmC
-0.141
0.010
0.004
0.005
0.000
0.008
-0.003
0.005
0.002
0.016
0.016
-0.0071
11
0.0448


Average
ppmC
0.1875
0.0940
0.2060
0.1155
0.0790
0.0580
0.0815
0.2035
0.4060
0.3990
0.0638
0.1722
11
0.1263


V
10
Difference
-75.20
10.64
1.94
4.33
0.00
13.79
-3.68
2.46
0.49
4.01
24.45
-1.5243
11
25.6694

Absolute
%
Difference
75.20
10.64
1.94
4.33
0.00
13.79
3.68
2.46
0.49
4.01
24.45
12.8177
11
21.9261
jlh.006
                                        15

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                        DUPLICATE IMPRECISION
      16
                             1988 NMOC Concentration
CD
U
c
a>
i_
CD
Q



CD
15
o

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CD
D)
D
i_
CD
15 -


14 -


13 -

12 -

1 1 -

10 -

 9 -

 8 -

 7 -


 6 -

 5 -


 4 -


 3 -
       2
        0.0
                        Overall Average Absolute %  Difference
                1.0            2.0           3.0

                  Average NMOC Concentration (ppmC)
                                                                4.0
          Figure 5
              Duplicate  NMOC sample results comparing average
              concentration  with  absolute  percent difference.

-------
0.169 ppmC.   Figure 5 was taken from the 1988 NMOC Final Report4 and shows
that as the average NMOC concentration decreases below 0.5 ppmC, the average %
difference increases rapidly.  At an average duplicate sample concentration of
0.169 ppmC, Figure 5 shows an average % difference of about 12.75 which is in
line with the calculated average absolute % difference of 12.82.

3.2.2     Integrated Diurnal Samples at Six Sampling Periods

      Table 4 gives the results of the analysis of integrated ambient air
samples over the diurnal sampling periods shown.  The sample numbers shown in
Table 4 correspond with those indicated in Table 1.  Diurnal Sample #2
(D.S. #2) was the  integrated canister sample taken from 6:00 a.m. to 9:00 a.m.
Diurnal Average #9  is  a weighted 24-hour average calculated according to
Equation  2.

      Average #9 =  (3  x D.S.#2 + 3 x D.S.#3 + 3 x D.S.#4 + 3 x D.S.#5
                       + 12 x D.S.#6)/24.                                (3)

Weighted  24-hour average #9  (Equation 3) is compared to the measured 24-hour
average,  D.S. #7,  in  the last four columns of Table 4.  Column 9  is the
difference  between  average #9 and D.S. #7.  Columns 10,  11, and  12 are their
average,  % difference,  and absolute % difference respectively.   Although  the %
difference  ranges  from -3.93 to 31.58, the average % difference  is a moderate
13.30.   There appears  to be  a positive bias in  the difference,  however.
Student's t test,  testing  the hypothesis that the mean difference  is zero,
concludes by rejecting the null hypothesis  (Ho: pd = 0) at the 0.05 level of
significance.   If  the conclusion were reached that there was  a  positive bias
in the  average  differences,  the probability is  95% that  we  have  reached the
correct conclusion.
       This  means that the  weighted 3- and  12-hour  average  #9  gives  a
statistically significantly  higher average than the 24-hour D.S.  #7.   A
possible  explanation  for  this occurrence  is that the  samples  in  some  of  the
sampling  periods were not  fully  integrated  samples.   Another  explanation  may
be that the sampling  and  analytical  errors  in the  data  set  of this  study  were

jlh.006                               17

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                                                  TABLE 4.  1989 RALEIGH DIURNAL SITE SAMPLES
Diurnal Sample (D.



JuLLan
Date
Sampled
204
206
208
210
212
214
216
218
220
222
224
226
228
230
Average =
Cases =
Std Dev =
a Average
#2
Diurnal
6 a .m . -
9 a.m.
NMOC
ppmC

0.117
0.099

0.208
0.118

0.079
0.062
0.051
0.080
0.206
0.407
0.072
0.1362
11
0.1032
#9 = (3 x
#3
#4
Diurnal Diurnal
9 a.m.
Noon
NMOC
ppmC

0.060
0.156
0.081
0.145
0.110
0.194
0.062
0.046
0.052
0.090
0.066
0.192
0.064
0.1014
13
0.0528
D.S. #2 +
Noon
3 p.m.
NMOC
ppmC

0.077
0.119

0.079
0.103
0.129
0.048
0.046
0.059
0.098
0.059
0.065
0.085
0.0805
12
0.0270
3 x D.S #3 +
#5
Diurnal
3 p.m. -
6 p.m.
NMOC
ppmC

0.080
0.104
0.070
0.120
0.064
0.099
0.053
0.049
0.067
0.092
0.050
0.099
0.055
0.0771
13
0.0235
3 x D.S. #4
S.)
#6
Average3
*7
#9




Diurnal Diurnal
6 p.m.
6 a.m.
NMOC
ppmC
0.562
0.528
0.241
0.293
0.220
0.312
0.214
0.194
0.183
0.083
0.183
0.121
0.190
0.149
0.2481
14
0.1395
+ 3 x D.
6 a . m. -
6 a.m.
NMOC
ppmC
0.478
0.226
0.172
0.127
0.137
0.196
0.204
0.097
0.085
0.059
0.136
0.111
0.198
0.098
0.1660
14
0.1031
,S #5 + 12 x D.S.


NMOC
ppmC

0.3058
0.1803

0.1790
0.2054

0.1273
0.1169
0.0701
0.1365
0.1081
0.1904
0.1089
0.1571
11
0.0640
#6)/24

Difference
(#9-#7)
ppmC

0.0798
0.0083

0.0420
0.0094

0.0303
0.0319
0.0111
0.0005
-0.0029
-0.0076
0.0111
0.0194
11
0.0250

Average
(#7l#9)
NMOC
ppmC

0.2659
0.1761

0.1580
0.2007

0.1121
0.1009
0.0646
0.1363
0.1095
0.1942
0.1034
0.1474
11
0.0575



X
Difference

30.00
4.68

26.58
4.67

26.98
31.58
17.23
0.37
- 2.67
- 3.93
10.76
13.30
11
13.52


Absolute
X
Difference

30.00
4.68

26.58
4.67

26.98
31.58
17.23
0.37
2.67
3.93
10.76
14.50
11
12.12

jlh.006

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                 TABLE 5.   COMPARISON OF SAMPLING PERIOD MEANS
Null Hypothesis    Degrees of             Test                      Critical
      Ho           Freedom, df           Statistic  t                 tdf  0 975


M2 = M3                 22                  1.065                        2.074

M2 = /x4                 21                  1.807                        2.080

M2 = M5                 22                  2.012                        2.074

M  = M6                 23                  2.222                        2.069
 jlh.006
                                         19

-------
lower than the typical errors encountered in this kind of measurement, i.e.the
standard deviations were unusually low for the NMOC concentration range
encountered.
      Further comparisons of these data tested whether a significant
difference was apparent between the sampling periods.  Table 5 compares the
average NMOC concentrations for each sampling period (#3 through #6) with the
average concentration for the 6:00 a.m. to 9:00 a.m. period.  The Null
Hypotheses for these tests are shown in column one of the table.  The degrees
of freedom for the test, the test statistics,and the critical test statistic,
t are given in the remaining columns of Table 5.   The only null
hypothesis that can be rejected, at the 0.05 level of significance is the last
one M2 = M6>  because  the test statistic,  t = 2.222,  is greater than  the
critical statistic, t23> 0 975 = 2.069.   The results of this  study indicate that
the average concentration of NMOC collected  in the 6:00 p.m. to 6:00  a.m.
samples was significantly higher for this study than the average
concentrations of  the 6:00 a.m. to 9:00 a.m. samples.
      These results indicate that the  building of NMOC concentration  during
the night  is greater  than the average  NMOC  concentrations in the 6:00 a.m. to
9:00  a.m.  time period.   It  is to be noted that photochemical reactions in the
6:00  a.m.  to 9:00  a.m.  time  interval would  not be expected  to  be as  large as
in the  9:00 a.m. to 3:00  p.m. time period.

3.2.3    APDFID Samples  Compared to Diurnal  Samples

      Table 6 compares  the  average APDFID sample  concentrations with  the
integrated canister concentrations for the  same  sampling period, analyzed  by
PDFID.  The second column,  Wj, designates the weekday (Sunday,  Wj=l,  Monday,
Wj=2,  ...,  Saturday,  Wj=7).  The column marked Pk represents  different time
periods throughout the  day.  (Time  Period  Pk=l  is  for 6:00  a.m.  to 9:00 a.m.;
Pk=2  is for 9:00 to Noon; Pk=3 for Noon to  3:00  p.m.; Pk=4  for 3:00  p.m.  to
6:00  p.m.;  Pk=5 for 6:00  p.m. to 6:00  a.m.;  Pk=6  for 6:00  a.m.  to 6:00 a.m.).
      Difference,  % difference, and absolute % difference  are  calculated in  a
manner  similar to  the statistics  in Table 4 using the integrated  PDFID
concentration as the  reference value.  Percent difference  and  absolute %

jlh.006                               20

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               TABLE  6.   COMPARISON OF PDFID AND APDFID CONCENTRATIONS
                            AT VARIOUS SAMPLING PERIODS
1989
Julian
Date
208
208
208
212
212
212
212
212
212
212
216
216
216
218
218
218
218
219
220
220
220
220
220
220
220
222
222
222
222
228
228
228
228
229



Absolute

Wj Pk
5 1
5 2
5 3
2 1
2 1
2 2
2 3
2 4
2 5
2 6
6 1
6 2
6 2
1 3
1 4
1 5
1 6
2 1
3 1
3 1
3 2
3 3
3 4
3 5
3 6
5 3
5 4
5 5
5 6
4 3
4 3
4 6
4 6
5 1
Average =
Count =
Std Dev =
APDFID
ppmC
0.0436
0.0895
0.0855
0.1641
0.1641
0.1822
0.0936
0.0584
0.0861
0.1104
0.2625
0.3416
0.2823
0.0461
0.0304
0.1195
0.0924
0.0935
0.0542
0.0542
0.0691
0.0513
0.0573
0.1206
0.0736
0.0620
0.1217
0.0515
0.0657
0.0955
0.0955
0.1026
0.1026
0.1082
0.1068
34
0.0699
PDFID
ppmC
0.099
0.156
0.199
0.204
0.208
0.145
0.079
0.120
0.220
0.137
0.269
0.194
0.204
0.048
0.053
0.194
0.097
0.099
0.054
0.062
0.046
0.046
0.049
0.183
0.085
0.059
0.067
0.083
0.059
0.065
0.059
0.111
0.198
0.116
0.1173
34
0.0635
Average
ppmC
0.0713
0.1228
0.1023
0.1841
0.1861
0.1636
0.0863
0.0892
0.1531
0.1237
0.2658
0.2678
0.2432
0.0471
0.0417
0.1568
0.0947
0.0963
0.0541
0.0581
0.0576
0.0487
0.0532
0.1518
0.0793
0.0605
0.0944
0.0673
0.0624
0.0803
0.0773
0.1068
0.1503
0.1121
0.1120
34
0.0617
Difference % %
ppmC
-0.0554
-0.0665
-0.0335
-0.0399
-0.0439
0.0372
0.0146
-0.0616
-0.1339
-0.0266
-0.0065
0.1476
0.0783
-0.0019
-0.0226
-0.0745
-0.0046
-0.0055
0.0002
-0.0078
0.0231
0.0053
0.0083
-0.0624
-0.0114
0.0030
0.0547
-0.0315
0.0067
0.0305
0.0365
-0.0084
-0.0954
-0.0078
-0.0105
34
0.0513
Diff
-77.7
-54.2
-32.8
-21.7
-23.6
22.7
16.9
-69.1
-87.5
-21.5
2.4
55.1
32.2
4.0
-54.2
-47.5
4.9
5.7
0.4
-13.4
40.1
10.9
15.6
-41.1
-14.4
5.0
58.0
-46.8
10.7
38.0
47.2
7.9
-63.6
7.0
-10.23
34
38.18
Diff
77.7
54.2
32.8
21.7
23.6
22.7
16.9
69.1
87.5
21.5
2.4
55.1
32.2
4.0
54.2
47.5
4.9
5.7
0.4
13.4
40.1
10.9
15.6
41.1
14.4
5.0
58.0
46.8
10.7
38.0
47.2
7.9
63.5
7.0
30.99
34
24.01
jlh.006
                                      21

-------
difference reference the differences to the average of the two concentrations.
The average difference between the APDFID and PDFID concentrations is -0.0105
ppmC, which is not significantly different from zero at 0.05 level of
significance.  Likewise, the average % delta is -10.2, which is also not
significantly different from zero.  The absolute % difference is about 31%,
which appears to be large.  In view of the overall average NMOC concentration,
equal to about 0.11 ppmC, however, the precision of 31% is a reasonable value.
      Therefore, we conclude APDFID and integrated canister diurnal NMOC
concentrations are equivalent.  Likewise the APDFID instrument and the
canister 3-hour samples analyzed by the PDFID method give equivalent results.

3.3   APDFID DATA CHARACTERIZATION

      The APDFID NMOC  concentrations were obtained by the automatic analysis
of 9-minute  samples. The time  interval for the sampling/analysis cycle of the
APDFID  instrument varied from  16 to 19 minutes.  The data were numerically
integrated by the trapezoidal  rule to give hourly average NMOC concentrations.
The  hourly average NMOC concentrations determined by the integration of the
APDFID  measurements are shown  in the stem-and-leaf plot of Figure  6.
      Statistics for the 248 APDFID hourly measurements are shown  in Figure 6.
Also shown are  the 6:00 a.m. to 9:00 a.m. PDFID measurements taken at the RLNC
site for  the entire summer  monitoring program.  The PDFID statistics are seen
to be larger except for the number of cases, the maximum , the skewness, and
the  kurtosis.   The standard deviations of the APDFID hourly NMOC  concentration
are  about  equal  to the 3-hour  6:00 a.m. to 9:00 a.m.  integrated samples for
the  entire summer.  These observations regarding the 6:00 a.m. to  9:00 a.m.
RLNC Monitoring  Program NMOC concentration distribution as compared to the
PDFID measured  NMOC concentration distribution for all hourly  time intervals,
lend credence to the assertion made earlier  that the APDFID and the  integrated
canister  concentration (analyzed  by the PDFID method)  are equivalent.
      Table  7 shows various hourly  statistics for the  1989 Raleigh diurnal
APDFID  NMOC  data.  The first row  shows the same statistics given  in  Figure  6
for  all of the  combined APDFID data.  Subsequent rows  in Table  7  summarize  the
minimum,  the mean, the median, the maximum,  the range,  and  standard  deviations

jlh.006                               22

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1
2
3
4
5 H
6
7 M
8
9
10
11 H
i. 1 II
12
13
14
15
1 fi
1 U
17
18
19
20
21
22
24
25
26
27
29
31
34
36
38
44
47
48
49
50
53
66
82
7
23348
00112
00011
00111
01222
00000
00112
01233
11122
00012
v w W J. L.
23346
2357
0279
1348
01 146
v 1 1 "U
0088

9
19
8
5
1
0
089
49
6
8
1
8
0
08
568
8
2
5
8
1
9

9
35577 8889
33333 44555 56788 899
33334 44555 5666 67777 78899
22344 44444 55677 77999 99
03345 55566 66778 88899
23334 45667 77888 8999
44555 56788 8999
337
33344 789
*J *J +Ji ~ 1 \J 3
788





















99







Cases

Minimum



Lower Hinge (
Median (M)
Mean


Upper Hinge (
Maximum

Standard Devi
Skewness
Kurtosis




























jlh.006
              Figure 6.  Stem-and-leaf plot of the APDFID NMOC hourly
                    and PDFID concentrations for the RLNC site.
                                         23

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               TABLE 7.   1989 RALEIGH  DIURNAL APDFID  NMOC  DATA
Hour
1-24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Cases
248
12
10
10
9
10
7
7
7
6
4
4
12
8
10
12
12
14
15
15
15
14
14
14
13
Min
ppmC
0.0174
0.0456
0.0378
0.0408
0.0395
0.0438
0.0298
0.0330
0.0315
0.0782
0.0578
0.0590
0.0380
0.0444
0.0242
0.0382
0.0174
0.0355
0.0404
0.0235
0.0415
0.0239
0.0227
0.0284
0.0304
Mean
ppmC
0.1124
0.1260
0.1128
0.1150
0.1050
0.0921
0.0940
0.0974
0.1332
0.1563
0.0869
0.1173
0.0774
0.0720
0.0811
0.1313
0.1228
0.1028
0.1008
0.1133
0.1116
0.1394
0.1355
0.1120
0.1201
Median
ppmC
0.0784
0.0825
0.0744
0.0649
0.0759
0.0780
0.0849
0.0826
0.0740
0.1024
0.0852
0.1045
0.0746
0.0723
0.0685
0.0643
0.0625
0.0677
0.0761
0.0755
0.0870
0.1067
0.1082
0.0674
0.0947
Max
ppmC
0.8294
0.5389
0.4763
0.5055
0.3689
0.2506
0.1995
0.2692
0.3187
0.3415
0.1195
0.2014
0.1285
0.0957
0.2411
0.8294
0.6614
0.4922
0.4782
0.3803
0.2966
0.4480
0.4407
0.4755
0.4883
Range
ppmC
0.8120
0.4933
0.4385
0.4647
0.3294
0.2068
0.1697
0.2362
0.2872
0.2633
0.0617
0.1424
0.0905
0.0513
0.2169
0.7912
0.6440
0.4567
0.4378
0.3568
0.2551
0.4241
0.4180
0.4471
0.4579
Std Dev
ppmC
0.1110
0.1363
0.1301
0.1397
0.1029
0.0617
0.0628
0.0823
0.1149
0.1058
0.0258
0.0602
0.0376
0.0201
0.0586
0.2212
0.1730
0.1157
0.1063
0.0936
0.0657
0.1098
0.1125
0.1181
0.1172
jlh.006

-------
for each hour in the day.  Means from the table are plotted in Figure 7 for
each hour of the day.
      Figure 8 plots the minimum, mean and maximum for each hour of the day.
Figure 9 plots the median NMOC concentration for each hour of the day.
      Figures 7 and 8 show a significant increase in the average NMOC
concentration from 6:00  a.m. to 9:00 a.m. (hours 7,8, and 9), while the
average NMOC decreases,  as expected, for hours 12, 13,and 14.  For hours 15
through 4, Figure 8 shows that the maximum NMOC concentration for each hour
was greater than 0.3 ppmC, although the average hovered around 0.1 ppmC.  The
median followed the same trends except for hour 8 (7:00 a.m. to 8:00 a.m.)
which was below the overall average median.
      Figure 10 shows boxplots of the NMOC concentrations for each hour of the
day.  The rectangles for each hour show the midrange of the data.  The
horizontal line inside  the rectangle marks the NMOC concentration of the
median.  The upper  and  lower ends of the rectangle mark the upper and lower
hinges of the ranked data.  Three quarters of the data are smaller than the
upper hinge  and one quarter of the data  is smaller than the lower hinge.  The
absolute difference between the  upper and lower hinge is called the Hspread.
 Inner fences are  defined as follows:

             lower inner fence =  lower hinge    (1.5 x Hspread),  and       (4)
             upper outer fence =  upper hinge +  (1.5 x Hspread).           (5)

The outer  fences  are defined  as  follows:

             lower outer fence =  lower hinge -  (3  x Hspread),  and         (6)
             upper outer fence =  upper hinge +  (3  x Hspread).             (7)

 Values  outside  the inner fences  are  plotted with  asterisks.   Values  outside
 the outer  fences  are plotted  with  empty  circles.   Whiskers  extended  from the
 boxes  to  the extreme (maximum and  minimum)  values or to  the  inner fences,
whichever  give  shorter whiskers.   The  boxplots  give  a general  impression of
 the overall  level,  the amount  of spread  of  the  data,  symmetry,  and  the
 presence  or absence of outliers.   Figure 10  shows the presence  of outliers,
 some of which  are greater than  0.4 ppmC.   The  boxplots  show that the NMOC data
 jlh.006                               25

-------
o
c:
o
13

-------
o

-------
o
g
CD
O

O
O
—
o

O
O
rt
CD
0.110




0.105




0. 100




0.095




0.090




0.085




0.080




0.075




0.070




0.065 -
    0.060
         0
                     DIURNAL APDFID NMOC DATA
                               1989 Raleigh, NC Site
                         8
       Overall
                                               Mean
12
16
                                    Hour
20
24
                 Figure 9.  Hourly median concentrations.

-------
   1.0
   0.8
o

I

o
ID
O

O
O

8

z
0.4
   0.2
        O
             o
        o
                o
      :  I
              •T-

           e?
                                         ill]
                                                         i   i  i   I
                      T
                                 I
                        I
                    1   1  J_  1
                                              o
                                           o
                                                o
                                                o
o
                                                           o
                                                     o
o
                o  -
           T
         12   34  56  78   9  10 11  12 13  14 15 16 17  18 19  20 21 22 23  24


                                       Hour
                                                                         tr
                                                                         S
                                                                         s
      Figure 10. Boxplots of NMOC Concentrations for each hour of the day.

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are skewed, as confirmed by the stem-and-leaf plots (Figures 4 and 6).  The
boxplots for hours 8 and 9 show large spans of data, whereas for hour 10, 13,
and 14, the overall spans are much smaller.  The NMOC levels of the medians
for the boxplots should correspond to the medians plotted in Figure 9.
Boxplots are a compact way of indicating the character and distribution of the
hourly NMOC readings.

3.3.1   Correlations Among APDFID Data

      Nine-minute APDFID samples were taken at intervals ranging from 16 to 19
minutes.  As indicated earlier, the data were integrated to give hourly
averages.  The hourly averages are recorded in Appendix B along with hourly
average valves of wind speed, wind direction, temperature, solar radiation
intensity, percent relative humidity, and  station barometric pressure (at the
station at Raleigh-Durham airport).  Appendix B also indicates the 1989 Julian
date,  and  a column labeled "Diurnal Minutes."  Diurnal minutes were defined to
simplify the integration calculations as follows:

            Diurnal  minutes =  (Julian date   203) x 1440                 (8)
              +  (hour x  60).

Diurnal minutes  are  tabulated  as  a function of 1989 Julian date and hour
throughout the day  in Appendix A.
       The  hourly average data  were converted to absolute units: wind  speed and
wind  direction were  converted  to  hourly  average velocity vectors perpendicular
to  the  highway  (U.S.  1)  in the direction of the RLNC site; temperature was
converted  to  kelvins; solar radiation units were converted to  joules  per
square  meter  (J/m2)  and percent relative humidity was converted to mole
fraction water.   These  conversions were  made so that the variables could  be
used  in the various  correlations  and  analyses of covariance described  below.
The hourly average  concentrations were  averaged over the six  sampling  periods
(Pk)  given in Table  1.   The APDFID and  the PDFID (integrated)  concentrations
averaged over the  sampling periods were  given in Appendix C,  along with
diurnal minutes, temperature  (kelvins),  solar radiation  (J/m2), humidity  (mole
fraction), velocity  vector  (m/s), Si, Wk,  Pk, and  NMOC  concentration  (ppmC).
jlh.006                               30

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Variable Si is a fixed variable indicating whether the results were obtained
from APDFID (Si=l) or from the PDFID (Si=2) measurement.  Wk indicates the
weekday, Sunday, Wk=l, Monday, Wk=2, etc. through Saturday, Wk=7.
      Table 8 gives the correlation matrix for the diurnal variables and
includes data from PDFID as well as APDFID NMOC concentrations.  The table
gives binary correlation coefficients for the eight variables shown.  Only one
variable pair shows a significant correlation, and that is the T-H pair.
Because the temperature is used to calculate the vapor pressure of water used
to calculate the humidity, a correlation of these two variables is not
unexpected.  No other variable pair shows a significant correlation, with
r > 0.9.   The Bartlett chi-square statistic shown in Table 8 tests the global
hypothesis concerning the significance of all the correlations in the matrix.5
With the probability  in the Bartlett chi-square test equal to zero, the test
is significant which  indicates that there may be some real correlations among
the variables.  The relationship between temperature and  humidity have already
been cited.  One of the objectives of the study was to determine which among
the variables,  T,  SRAD, H, V,  S, W, and  P, might be significant independent
variables, using NMOC as  a dependent variable.  The bottom row in the
correlation of  matrix shown in Table 7 indicates that a correlation between
NMOC and other  variables  is not  likely.   In order for a correlation to be
likely, the correlation coefficients should be in the range between 0.75 and
1.0 and -0.75 to   1.0
      A number  of  analyses of  covariance  (ANOCOVA) were performed on the data
and their  results  are summarized in Table 9.  Variables S,P, and W were fixed
variables  while T, SRAD,  and  V were continuous variables.  The humidity
variable,  H, was  not  used as  an  independent variable because of  its dependence
on T.   As  seen  in  Table 8, H,  has the highest correlation with the other
variables, except  for NMOC.   Variable H  was therefore not used in the ANOCOVA,
where NMOC was  the dependent  variable.
       It  is difficult to  interpret  the results of the ANOCOVA.   The most
general conclusion that can be  reached is  that the NMOC concentration was  so
low, and the variability  was  also so low that assigning significant trends was
not possible.   The SP, or S x  P, interaction  term appeared to  be  significant
whenever S and  P  were used as  independent  variables.

jlh.006                               31

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Variable
           TABLE 8.  CORRELATION MATRIX FOR DIURNAL VARIABLES
                   SRAD
W
NMOC
T
SRAD
H
V
S
W
P
NMOC
Number of
Bartlett
1.000
0.730
0.978
0.500
-0.161
-0.287
0.212
0.086
1.000
0.799
0.264
-0.183
-0.179
0.131
-0.148
observations =
chi -square stati
1
0
-0
-0
0
0
172
sti
.000
.477
.177
.277
.243
.038

c
1.000
-0.010
0.028
-0.007
0.186

870.215

1
0
-0
0

}

.000
.155
.296
.146

df =


1
-0
0

28


.000
.027 1
.016 0

; Prob



.000
.047 1

= 0.00




.000


        Period  (P)  average  temperature,  kelvins;
        Period  solar  radiation  intensity, J/m2;
        Period  humidity,  mole fraction water  in  air  sample;
        Period  velocity  vector,  m/s;
        Measurement type   S=l  for  APDFID;  S=2  for  PDFID;
        Weekday   Sunday, W=l;  Monday, W=2  ...;  and  Saturday,  W=7;
        Sampling  period  for average   P=l,  6:00  a.m.  to  9:00  a.m.;
        P=2,  9:00 a.m. to Noon;  P=3,  Noon to  3:00  p.m.;  P=4,
        3:00  p.m. to  6:00 p.m.;  P=5,  6:00 p.m. to  6:00 a.m.;
        and  P=6,  6:00 a.m.  to 6:00  a.m.; and
 NMOC  =  NMOC  concentration, ppmC.
   T
SRAD
   H
   V
   S
   W
   P
 jlh.006
                                        32

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                 TABLE 9.  RESULTS OF ANALYSES OF COVARIANCE
Case
No.
1
2
3
4
5

6
7
8
9
10

11
Dependent
Variable
NMOC
NMOC
NMOC
NMOC
NMOC

NMOC
NMOC
NMOC
NMOC
NMOC

NMOC
Independent Significant
Variables Variable(s)
S,P,SP,T,SRAD,V
S,P,SP,T,SRAD
S,P,SP,T,V
S,W,SW,T,V
S,P,W,SP,SW,WP,
T,SRAD,V
W,P,WP,T,V
P,T,SRAD,V
W,T,SRAD,V
S,T,SRAD,V
S,W,SW,T,SRAD,V

S,P,SP,T2,SRAD,V
SP
SP
SP,P
s
Singular

P,T

T,SRAD
T,SRAD
S,T,SRAD

SP
Probabil ity(ies)
0.014
0.014
0.015, 0.00077
0.023
Matrix*

0.00019, 0.0014

0.005, 0.00012
0.005, 0.0022
0.02, 0.0023,
0.00025
0.014
Multiple
R
0.488
0.475
0.488
0.343


0.609
0.380
0.359
0.362
0.437

0.488
* A singular matrix occurred because there may have been  too few observations,
or too many missing cells in the analysis  of covariance.
jlh.006
                                       33

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Whenever P and SRAD were used as independent variables in the same ANOCOVA,
neither was significant.  However, T and SRAD appeared to be significant when
used as independent variables in the absence of P as an independent variable.
Using T2 in place of T as an independent variable did not appear to increase
the overall correlation  significantly.  In no case did V become a significant
variable.  Variable S was significant in only one case, Case No. 10.
      There were sufficient cases in the ANOCOVA in which one variable or
another was significant, to suggest that with NMOC data having a larger range
of variability and magnitude, there would be clearer trends of cause and
effect between the independent and dependent variables.
      Table 9 shows the  multiple correlation coefficients, R, to range between
0.343 to 0.609,  averaging about 0.44.   Such a range  indicates that additional
other independent and/or dependent variables need to be used to improve the
correlations.  Perhaps  a better dependent variable would be the ratio of
NMOC/NOX.  Using NMOC as one of the independent variables with NOX,  or  03  as
the dependent variable  may  also give better correlations.
 jlh.006                               34

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                          4.0  EQUIPMENT PERFORMANCE

      One of the primary objectives of the study was to validate the
mechanical reliability and precision of the APDFID apparatus.  Integrated 3-
hour, 12-hour, and 24-hour diurnal whole air canister samples were used to
validate the APDFID results.
      The diurnal sample collection system yielded a project completeness of
96.1%, whereas the APDFID system yielded a completeness of about 40%.  As a
result of the field test of the APDFID system a number of modifications were
suggested to improve the APDFID completeness.
      The diurnal sampling system will be described below and will be followed
by a description of the APDFID system.

4.1   DIURNAL INTEGRATED SAMPLING SYSTEM DESCRIPTION

      As  seen in Figure 1, the APDFID and the diurnal collection systems
shared a  common  1/4-inch outside diameter (o.d.) stainless steel sampling
manifold  having  an  inverted glass funnel at the inlet and a high flow slip-
stream pump at the  outlet.  The glass-funnel inlet for the diurnal sampling
system was placed within 6 inches of the inlet for the Raleigh, NC (RLNC) NMOC
Monitoring Program  site.  The slipstream pump for the diurnal sampling system
maintained at least 12  liters per minute (L/min) through the manifold.  The
diurnal  sample collection system consisted of three subsystems: (1)  a
subsystem for the 3-hour integrated samples, (2) a system for the  12-hour
integrated sample,  and  (3) a system for the 24-hour sample.

4.1.1    Three-hour  Integrated Sample Collection System

      The first  port on the sampling manifold from the sample manifold inlet
was  used  for  the 3-hour samples.  The collection system consisted  of a 2-
micron  (/x) stainless steel filter housed in a filter assembly,  a  fixed orifice
assembly, a Metal Bellows MB-151 pump, programmable electronic  timers, and  a
1/8-inch  o.d. manifold  from which were located four branches each  connected to
a 6-L stainless  steel canister through a separate Magnalatch latching solenoid

jlh.006                               35

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valve.  The fixed orifice assembly contained a 75-milliliter per minute
(mL/min) critical orifice.  The MB-151 pump provided the pressure drop for the
critical orifice and was started and stopped by its own dedicated programmable
electronic timer.  By the end of each sampling period, the MB-151 pump also
provided a pressure of about 15 psig in the sample canister.  The schedule of
activity for collection of integrated samples and operation of the Magnalatch
valves is given in Table 10.  The 6:00 a.m. to 9:00 a.m. sample was terminated
at 8:58 a.m., giving a 178-minute sample (out of 180-minute time period).  The
9:00 a.m. to Noon integrated sample began sampling at 9:01 a.m. and was
terminated at 11:58 a.m. giving a 177-minute sample out of a 180-minute time
period.  An interval of about three minutes was provided between the time one
sample collection was completed and another began.  This static period was
required because of the common delivery manifold shared by the diurnal
samples.  If the solenoid valves, on a system that had just collected sample
at (about 15 psig) and a system that had not collected sample  (under 15 mm Hg
vacuum absolute) were ever open at the same time, there would  be a flow of
sample from one canister to the other.  Both samples would be  contaminated in
reaching pressure equilibrium.

4.1.2   Twelve-hour  Integrated Sampling System

       Integrated samples were collected during the 12-hour period 6:00 p.m.
and 6:00 a.m.  (6:00  p.m. to 5:59 a.m.).  The collection system was the second
port  in the main sampling manifold shown in Figure 1.  The 12-hour sampling
system with a  stainless  steel filter, and micro-metering valve, had its own
programmable electronic  MB-151 pump, Magnalatch solenoid valve, and digital
timer.  The micro-metering valve was set for a flow of  19 mL/min and the timer
was set to activate  and  deactivate the MB-151 pump and  the Magnalatch solenoid
valve  both at  the times  shown in Table 10.

4.1.3   Twenty-four-hour  Integrated Sampling System

       The 24-hour sampling system was the third port  on the main sample
manifold from  the sample  inlet.  Integrated samples were collected in 6-L
canisters during one 24-hour period of each sampling  episode.  The collection
jlh.006                               36

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    TABLE 10.  SCHEDULE OF ACTIVITY FOR COLLECTION OF INTEGRATED SAMPLES
Day
n
n
n
n
n
n
n
n
n
n
n
n
n+1
Time
hh mm
05 59
06 00
06 00
08 58
09 01
11 58
12 01
14 58
15 01
18 00
18 00
18 01
05 59
System
no.
2,3,4,5
2
7
2
3
3
4
4
5
5
6
2,3,4,5
6
Activity (Refer to Figure 1)
Common Sampling Pump K activated.
Solenoid Valve H opened; first 3-hour
collection started.
Sampling pump activated; Solenoid Valve G
opened; 2-hour collection started.
Solenoid Valve H closed; first 3-hour
collection ended.
Solenoid valve opened; second 3-hour
collection started.
Solenoid valve closed; second 3-hour
collection ended.
Solenoid valve opened; third 3-hour
collection started.
Solenoid valve closed; third 3-hour
collection ended.
Solenoid valve opened; fourth 3-hour
collection started.
Solenoid valve closed; fourth 3-hour
collection ended.
Sampling pump activated; Solenoid Valve F
opened; 12-hour collection started.
Common Sampling Pump D deactivated.
Sampling pump deactivated; solenoid valve
                                    closed;  12-hour collection  ended.

n+l         05 59       7           Sampling pump deactivated;  solenoid  valve
                                    closed;  24-hour collection  ended.
jlh.006


                                    37

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system was configured exactly the same as the 12-hour collection system except
that the micro-metering valve was set for a flow of 10 mL/min.  As shown in
Table 9, the 24-hour sampling period was set for the integration period
between 6:00 a.m. on the day designated as the sampling date and 5:59 a.m.  the
next day.
      All of the diurnal integrated sample equipment operated as designed.
Completion in terms of % of valid samples was 96.1.  Three samples were voided
because of incorrect settings programmed into the timers.

4.2   AUTOMATED CRYOGENIC PRECONCENTRATION AND FLAME IONIZATION
      DETECTION SYSTEM

      The APDFID instrument operating cycle is described in a previous
report.6  One of the objectives of the study was to determine the reliability
of the  system under field conditions and how well the measurements of NMOC
concentration agreed with the measurements obtained from integrated canister
samples  analyzed by the PDFID method.
      Approximately 40% data capture was achieved with the APDFID instrument
during  the course of the study, but sufficient experience was gained to
develop  some solutions to of the problems causing data interruptions.  APDFID
operating limitations experienced in the field included excessive cryogen
usage,  ice accumulation, power outages  and computer lockups due  to noise
spikes.
      About one  tank of cryogen  (160 L) was used per day prior to finding
cryogen  leak at  the sample  trap.  Once  the leak was corrected, the amount of
cryogen  used to  maintain the trap temperature decreased to about one tank
every two days.
       Ice accumulation  around the cryogenic solenoid valve and cryogen  lines
leading  to the trap created  FID electronic noise problems.  The  signal  cable
leading  form the FID to the  electrometer, and the  FID support gas lines, were
often encased in ice.   This  problem was resolved after discovery by tightly
packing  the cryogen solenoid and  lines  with closed cell  insulation material.
      Power outages, although  infrequent, created  down time  because the gas
chromatograph's  operating method would  reset.  Once the method was reset no
other samples were  taken.   Short power  spikes often locked-up the computer,

jlh.006                              38

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but did not reset the GC.  The Nelson data system software interrupted the
signal transfer from the GC to the computer's hard drive.  Once the computer
was locked-up, the Nelson data system interface could not transfer any data to
the hard drive of the computer.  The Nelson interface would then store a
certain number of sample runs in its on-board memory buffer.  Once the on-
board buffer was full, no subsequent sample runs were stored.  Therefore, if
the computer was not able to download data, only a limited number of runs were
obtained by the interface.  If the power went out during the computer lockup
period, then all data in the interface were lost.

4.2.1       Recommended Modifications for the APDFID System

      Cryogenic sample trap modification could decrease the amount of cryogen
needed to maintain the temperature.  A change in the trap material to
aluminum, instead of copper, should  increase the cooling and heat-transfer
efficiency by 30%.  The reduction  in size of the insulated cavity around the
sample trap and increasing the volume of insulation encasing the trap chassis
should also decrease the cryogen use.
      Moving the cryogenic solenoid  valve and cryogen lines away from the GC
electronics area to a location outside of the GC will reduce FID electronic
noise.  Any ice accumulation and water due to frost formation and defrost will
not affect the  instrument operation  and electronics.
      An uninterruptible power supply to support the computer and Nelson
interface will  solve  any computer  lockup problems experienced by power spikes
that  do not reset the GC.  The proposed modifications to the APDFID system are
expected to reduce the cryogen usage by approximately 50%, and to increase the
data  capture to a goal of 70%.

4.3   APDFID CALIBRATION, AUDIT AND  ZERO RESULTS

      For  initial calibration  purposes, APDFID used propane  referenced to
National Institute of Science  and  Technology  (NIST) propane  standards, as
required by Compendium Method  TO-12.  Calibration checks of  response  factors
for propane and zeros, using zero-grade air, were performed  every other  day
throughout the  diurnal sampling project.
jlh.006                               39

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4.3.1  Initial Calibration of the APDFID system

      Initial calibration for the APDFID was performed using n-propane
standards referenced to NIST standards.  The propane calibration curve for the
APDFID apparatus is given in Figure 11.  Zero readings of the calibration
curve were measured using a zero-air cylinder.  The correlation coefficient
for the calibration curve was 0.99650.

4.3.2  Daily  Response  Factors

      Response  factors were measured every other day using propane with a
concentration was  about 3.0 ppmC.   Figure 12  shows response  factors measured
over  the  diurnal  sampling  period.   Four  horizontal lines  are shown on
Figure  12, /x +/-  2a,  and M +/-  3a.  The  n +/- 2a lines are called warning
 limits,  and  the n +/-  3a  lines  are  the control  limits.  The  response  factor
chart appears to  be showing a  rising  trend  in the  response factor with time.
The data, however, remain  within the  warning  limits.  The "runs", or
 consecutively increasing  measurements  appear  to be no more than  five,  so  the
 APDFID  measurement/calibration  check  systems  appear  to remain in  control.   For
 future  tests with the APDFID  system this increase  needs  to  be monitored
 closely.

 4.3.3  Audit Results

       Two audit samples containing propane  were supplied by the Quality
 Assurance Division of the U.S.  Environmental  Protection  Agency to determine
 accuracy of  the APDFID instrument.  The first audit  sample dated
 July 31, 1989, had a  concentration of 0.724 ppmC;  and the second audit sample
 had a concentration of 0.791  ppmC.  The analyses of these audit samples by the
 APDFID instrument showed a bias of +1.52% and  13.40% respectively, for an
 overall  average of -5.94%.
       Audit  (and  precision) results for the analyses conducted by the PDFID
 analyses of  integrated canister samples were periodically conducted on the

 jlh.006                               40

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0)
OJ
0)
      1.1
1.0 -


0.9 -


0.8 -


0.7 -


0.6 ~

0.5 -


0.4 -


0.3 -


0.2 -


0.1 ~
     0.0
~r
2
                          CALIBRATION CURVE
                                 APDFD Apparatus
™r
4
~T~
6
n   r
 8
                                           10
~r~
12
~~T~
14
                                                           l
                                                           16
18
                              Propane Concentration, ppmC
         Figure 11.  Propane calibration curve for APDFID apparatus.

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                         RESPONSE FACTORS
o
CO
 'ID
o
CL
 . co
c5 £
CD
CO
CD
QC
2.5

2.4

2.3 -

2.2 -

2.1 -

2.0 -

1.9 -

1.8 -

1.7

1.6

1.5

1.4

1.3

1.2 H

1  1

1.0
                                APDFD Apparatus
        204
                                    +30"
                                    +20
                                    -20
                                    -30
            208
212       216
220
224
228
                                 1989 Julian Date
             Figure 12.  Response factors for APDFID apparatus

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1989 NMOC Monitoring Program.  With this analytical instrumentation audit
results are typically less than +5%.  In 1988, for example, audit results for
the four Radian channels were +2.22%, +1,33%, +2.86%, and +4.51%.*  The
results from the audits will be reported in the 1989 NMOC Monitoring Program
final report, which is currently in preparation.

4.3.4  Daily Zero

      Zero measurements were performed every other day using zero-grade air
from a storage cylinder.  The daily zero results are shown in Figure 13.
Horizontal lines are also shown in Figure 13 at y. +/- 2a and /x +/- 3a for the
daily zero measurements.  Because the magnitude of the early "zero"
measurements (Julian dates 205 - 218) were in the same order of magnitude as
the  NMOC measurements at the Raleigh site, the "daily" NMOC measurements were
also plotted in Figure  13.  The zeros appear to show some carryover from the
NMOC measurements themselves.  Unfortunately it was not always possible to
plot the "Daily" NMOC measurement performed  immediately prior to  the zero
measurement.  The "daily" NMOC concentration shown in Figure 13 was either the
overall daily average NMOC, the 6:00 a.m. to 9:00 a.m., or sometimes the 3:00
p.m. to 6:00 p.m. NMOC  concentration measurement.
      Nevertheless, there appears to be  an approximate correlation between the
daily NMOC concentration measurement and the zero concentration,  perhaps with
some lag involved.  It  is to be emphasized,  however, that the concentrations
of  NMOC were generally  so low that  such  a correlation is tentative at this
time.  The fact that there  normally  is such  a short time between  APDFID
measurements, and that  purging the  cryogenic trap between sampling episodes
was  brief, could lead to the hypotheses  that there may be some carryover of
organic material from one sampling  episode to the next.  Before a more
definite evaluation of  this  phenomenon  is made,  it will be necessary to carry
out  additional  tests at higher overall NMOC  concentration  in the  range  of
average concentration above  0.750 ppmC.
jlh.006                                43

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-P-
         o
         cd
         O
              0.30
0.28 -

0.26 -

0.24 -

0.22

0.20 -

0.18 -

0.16

0.14

0.12 H

0.10

0.08 -

0.06 -

0.04 -

0.02

0.00
                  204
                                             DAILY ZERO
                                               APDFID Instrument
                                                               Daily NMOC
                                                               Daily Zero
               208
212         216

       1989 Julian Date
220
224
228
                               Figure  13.  Daily zero for APDFID apparatus

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                               5.0  CONCLUSIONS

The following is a summary of conclusions drawn from this study.

1.    Diurnal integrated samples compared well with APDFID samples.  The
      difference averaged 0.011 ppmC.   Percent differences ranged between
      -87.5 and +58.0 and averaged -10.23.  The average absolute % difference
      was 31.0.  No significant differences between the APDFID and the PDFID
      methods of measurement of NMOC concentration were detected.
2.    Diurnal 6:00 a.m. to 9:00 a.m. integrated sample concentration averaged
      significantly lower than diurnal integrated sample concentrations
      collected from 6:00 p.m. through 6:00 a.m., at the 0.05 level of
      significance.
3.    The average 6:00 a.m. to 9:00  a.m. NMOC concentration at the Raleigh, NC
      Monitoring Program site for the summer of 1989 was 0.159 ppmC, which was
      smaller than the site averages at any of the 38 morning monitoring sites
      during the summer of 1988.
4.    Hourly averages of NMOC concentrations measured by the APDFID system
      were approximately lognormally distributed and ranged from 0.017 ppmC to
      0.829  ppmC.  The average concentration was 0.112 ppmC and the median was
      0.078  ppmC.  The lower hinge was 0.056 ppmC and the upper hinge was
      0.114.
5.    No trends of NMOC concentration, measured by the APDFID system were
      discernable as functions of temperature, solar radiation  intensity,
      humidity, or wind velocity vector from the largest NMOC source in the
      vicinity  of the sampling site.
6.    The Raleigh NMOC Monitoring Program  sample concentrations compared
      favorably with the diurnal 6:00 a.m. to 9:00 a.m.  integrated whole
      ambient  air samples.  There was, on  the average, only a -0.007 ppmC
      difference which resulted  in  a -1.52% difference.  The average absolute
      % difference was 12.8.
7.    The weighted average of  the 3- and  12-hour integrated diurnal NMOC
      sample concentrations was  significantly higher than the average  of  the
      24-hour  sample concentrations.

jlh.006                               45

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8.    Hourly medians for 6th, 7th, 9th, 10th, 20th, 21st, 22nd, 13th, 14th,
      15th, 16th, and 17th hours were significantly less than the overall
      average medians.
9.    Hourly averages followed similar trends although the trends for hourly
      averages were less well defined because of the presence of a number of
      outliers among the hourly averages.
10.   The  low overall NMOC concentration during the study caused the
      interpretation of hourly NMOC trends to have large uncertainties.
11.   No differences in average NMOC concentration measured by the APDFID
      system were discernable among the days of the week.
12.   Zero air measurements  performed every other day during the APDFID
      sampling period suggested that there may be carryover from one nine-
      minute APDFID measurement to the next.  The magnitude and extent of the
      carryover was not possible  to determine because of the low overall NMOC
      concentration encountered in the study.
13.   The  1989 Raleigh Diurnal study with the APDFID apparatus suggested
      several changes in equipment and operating procedure that would improve
      the  data capture from  about 40% to a goal of 70%.
14.   The  average 6:00 a.m.  to 9:00 a.m. NMOC concentration for the  period
      from June  5 through  June 30, 1989 was  significantly higher than the
      average NMOC  6:00 a.m.  to 9:00 a.m. concentration for September 1989.
15.   The  average 6:00 a.m.  to 9:00 a.m. NMOC concentration decreased each
      month  from 0.2063 ppmC in June 1989 to 0.1200 for September.
16.   The  6:00 a.m.  to 9:00  .m. concentrations at the Raleigh, NC monitoring
      site during the period of the diurnal  sampling  (July 23  to
      August  19,  1989) was not a  significantly different from  the average
      NMOC concentration  for the  entire  summer of  1989.
 jlh.006                               46

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                                6.0   REFERENCES

1.     Aerometric Information Retrieval System (AIRS) Site No. 37-183-0014.
2.     Compendium Method TO-12, "Determination of Non-Methane Organic Compounds
      (NMOC) in Ambient Air Using Cryogenic Pre-Concentration and Direct Flame
      lonization Detection (PDFID)", Quality Assurance Division, Environmental
      Monitoring Systems Laboratory, U.S. Environmental Protection Agency,
      Research Triangle Park, NC, 27711, May 1988.

3.     "1989 Nonmethane Organic Compound Monitoring and Three-Hour Urban Air
      Toxics Monitoring Programs," Work Plan and Quality Assurance Project
      Plan.  Radian Corporation DCN No. 89-262-045-67, Research Triangle
      Park, NC, 27709, September 1989.

4.     McAllister, R.A., P.L. O'Hara, W.H. Moore, D-P. Dayton, J. Rice,
      R.F. Jongleux, R.G. Merrill, Jr., and J.T. Bursey, "1988 Nonmethane
      Organic Compound and Urban Air Toxics Monitoring Programs, Final Report
      Volume I.  Nonmethane Organic Compound and Three-Hour  Air Toxics
      Monitoring Programs", Radian Corporation, DCN No. 88-262-045-25.
      Prepared  for Dr. Harold G. Richter, Office of Air Quality planning  and
      Standards, U.S.  Environmental  Protection Agency, Research Triangle  Park,
      NC,  December 1988.

5.    Wilkinson, Leland,  SYSTAT: The  System for Statistics,  Evanston,  IL,
      SYSTAT,  Inc. 1988.

6.    McAllister, R.A., D-P.  Dayton,  J.  Rice, A. Sykes,  "Automated Nonmethane
      Organic  Compound Monitor", Radian  Corporation,  DCN No. 203-024-89-13,
      Prepared  for V.L. Thompson and  F.  McElroy,  Environmental  Monitoring
      Systems  Laboratory,  U.S.  Environmental Protection  Agency,  Research
      Triangle  Park,  NC 27709
 jlh.006                                47

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                                  APPENDIX A



            CALCULATION OF TIME  IN MINUTES FOR THE DIURNAL PROGRAM
jlh.006/cah

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APPENDIX A.  CALCULATION OF TIME IN MINUTES FOR THE DIURNAL PROGRAM

  1989                                       Minutes at End of Indicated Hour
 Julian  	-	-			-	
  Date       1      2     3     4     5     6     7     8     9    10    11     12    13     14     15     16     17     18    19    20    21    22    23    24
203
204
205
206
207
208
209
60
1500
2940
4380
5820
7260
8700
120
1560
3000
4440
5880
7320
8760
180
1620
3060
4500
5940
7380
8820
240
1680
3120
4560
6000
7440
8880
300
1740
3180
4620
6060
7500
8940
360
1800
3240
4680
6120
7560
9000
420
1860
3300
4740
6180
7620
9060
480
1920
3360
4800
6240
7680
9120
540
1980
3420
4860
6300
7740
9180
600
2040
3480
4920
6360
7800
9240
660
2100
3540
4980
6420
7860
9300
720
2160
3600
5040
6480
7920
9360
780
2220
3660
5100
6540
7980
9420
840
2280
3720
5160
6600
8040
9480
900
2340
3780
5220
6660
8100
9540
960
2400
3840
5280
6720
8160
9600
1020
2460
3900
5340
6780
8220
9660
1080
2520
3960
5400
6840
8280
9720
1140
2580
4020
5460
6900
8340
9780
1200
2640
4080
5520
6960
8400
9840
1260
2700
4140
5580
7020
8460
9900
1320 1380 1440
2760 2820 2880
4200 4260 4320
5640 5700 5760
7080 7140 7200
8520 8580 8640
9960 10020 10080
     210 10140 10200 10260 10320 10380 10440 10500  10560  10620  10680  10740  10800 10860 10920 10980 11040 11100 11160 11220 11280 11340 11400 11460 11520
     211 11580 11640 11700 11760 11820 11880 11940  12000  12060  12120  12180  12240 12300 12360 12420 12480 12540 12600 12660 12720 12780 12840 12900 12960
     212 13020 13080 13140 13200 13260 13320 13380  13440  13500  13560  13620  13680 13740 13800 13860 13920 13980 14040 14100 14160 14220 14280 14340 14400
     213 14460 14520 14580 14640 14700 14760 14820  14880  14940  15000  15060  15120 15180 15240 15300 15360 15420 15480 15540 15600 15660 15720 15780 15840
     214 15900 15960 16020 16080 16140 16200 16260  16320  16380  16440  16500  16560 16620 16680 16740 16600 16860 16920 16980 17040 17100 17160 17220 17280
     215 17340 17400 17460 17520 17580 17640 17700  17760  17820  17880  17940  18000 18060 18120 18180 18240 18300 18360 18420 18480 18540 18600 18660 18720
     216 18780 18840 18900 18960 19020 19080 19140  19200  19260  19320  19380  19440 19500 19560 19620 19680 19740 19800 19860 19920 19980 20040 20100 20160
     217 20220 20280 20340 20400 20460 20520 20580  20640  20700  20760  20820  20880 20940 21000 21060 21120 21180 21240 21300 21360 21420 21480 21540 21600
     218 21660 21720 21780 21840 21900 21960 22020  22080  22140  22200  22260  22320 22380 22440 22500 22560 22620 22680 22740 22800 22860 22920 22980 23040
     219 23100 23160 23220 23280 23340 23400 23460  23520  23580  23640  23700  23760 23820 23880 23940 24000 24060 24120 24180 24240 24300 24360 24420 24480
     220 24540 24600 24660 24720 24780 24840 24900  24960  25020  25080  25140  25200 25260 25320 25380 25440 25500 25560 25620 25680 25740 25800 25860 25920
     221 25980 26040 26100 26160 26220 26280 26340  26400  26460  26520  26580  26640 26700 26760 26820 26880 26940 27000 27060 27120 27180 27240 27300 27360
     222 27420 27480 27540 27600 27660 27720 27780  27840  27900  27960  28020  28080 28140 28200 28260 28320 28380 28440 28500 28560 28620 28680 28740 28800
     223 28860 28920 28980 29040 29100 29160 29220  29280  29340  29400  29460  29520 29580 29640 29700 29760 29820 29880 29940 30000 30060 30120 30180 30240
     224 30300 30360 30420 30480 30540 30600 30660  30720  30780  30840  30900 30960 31020 31080 31140 31200 31260 31320 31380 31440 31500 31560 31620 31680
     225 31740 31800 31860 31920 31980 32040 32100  32160  32220  32280  32340 32400 32460 32520 32580 32640 32700 32760 32820 32880 32940  33000 33060  33120
     226 33180 33240 33300 33360 33420 33480 33540  33600  33660  33720  33780 33840 33900 33960 34020 34080 34140 34200 34260 34320 34380  34440 34500  34560
     227 34620 34680 34740 34800 34860 34920 34980  35040  35100  35160  35220 35280 35340 35400 35460 35520 35580 35640 35700 35760 35820  35880  35940  36000
     228 36060 36120 36180 36240 36300 36360 36420  36480  36540  36600  36660 36720 36780 36840 36900 36960 37020 37080 37140 37200 37260  37320 37380  37440
     229 37500 37560 37620 37680 37740 37800 37860  37920  37980  38040  38100 38160 38220 38280 38340 38400 38460 38520 38580 38640  38700  38760  38820 38880
     230 38940 39000 39060 39120 39180 39240 39300  39360  39420  39480  39540 39600 39660 39720 39780 39840 39900 39960 40020 40080  40140  40200 40260 40320
     231  40380 40440 40500 40560 40620 40680 40740  40800  40860  40920  40980 41040 41100 41160 41220 41280 41340 41400 41460 41520  41580  41640 41700 41760

-------
                                  APPENDIX B

               1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
               HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
jlh.006/cah

-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
203
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
60
120
180
240
300
360
420
480
540
600
660
720
780
840
900
960
1020
1080
1140
1200
1260
1320
1380
1440
1500
1560
1620
1680
1740
1800
1860
1920
1980
2040
2100
2160
2220
2280
2340
2400
2460
2520
2580
2640
2700
2760
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure Average
m/s Degrees Deg. C Radiation Humidity in. Hg ppmC
2.50
2.63
1.63
1.50
1.25
0.75
0.50
1.25
0.75
1.25
1.38
2.00
2.75
2.38
1.75
1.38
1.75
2.00
2.25
1.88
1.13
1.25
1.38
0.13
0.25
0.13
0.50
0.25
1.25
1.88
0.50
0.38
0.63
1.88
2.25
1.88
1.50
1.25
2.00
1.38
1.88
2.00
2.38
1.75
1.75
1.50
202.5
222.5
230.0
207.5
237.5
292.5
47.5
35.0
345.0
0.0
237.5
255.0
222.5
212.5
235.0
150.0
150.0
150.0
150.0
150.0
137.5
120.0
120.0
107.5
205.0
30.0
356.3
28.8
68.8
152.5
120.0
185.0
153.8
163.8
207.5
205.0
220.0
265.0
242.5
37.5
88.0
125.0
190.0
205.0
222.5
255.0
25.00
24.00
23.00
22.50
22.00
21.50
20.00
20.75
23.00
25.25
26.75
27.75
29.00
29.75
30.50
30.00
29.00
28.00
26.50
24.25
23.75
23.00
23.00
23.00
23.00
21.75
21.25
21.00
21.00
20.25
20.25
21.50
23.50
25.50
27.25
28.00
28.25
29.50
30.75
31.00
30.50
30.75
31.75
30.50
29.25
27.75
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.250
0.750
2.250
4.000
4.250
5.000
3.750
4.375
1.250
1.250
0.300
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.375
1.125
2.500
3.688
4.250
4.250
5.625
4.625
3.000
3.500
2.250
1.500
0.750
0.000
0.000
64.00
62.00
60.00
60.00
60.00
60.00
60.00
60.00
61.50
66.50
72.00
72.50
74.00
75.50
76.50
74.50
71.50
69.50
67.00
64.50
63.00
62.00
62.00
62.00
62.00
61.00
60.00
58.50
58.00
58.00
58.00
60.00
62.00
66.00
70.00
72.00
70.50
73.00
74.00
76.50
78.50
80.00
79.50
77.00
76.00
73.50
29.725
29.725
29.735
29.745
29.760
29.770
29.780
29.795
29.805
29.815
29.825
29.835
29.820
29.815
29.800
20.810
29.805
29.810
29.815
29.805
29.810
29.840
29.865
29.850
29.840
29.840
29.830
29.830
29.840
29.850
29.870
29.870
29.875
29.875
29.870
29.865
29.855
29.835
29.815
29.795
29.780
29.775
29.775
29.770
29.780
29.795

-------
                                                  APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NMOC CONCENTRATION DATA

                     Wind     Wind                          %      Bar.
Julian      Diurnal  Speed  Direction    t      Solar   Relative  Pressure   Average
 Date  Hour Minutes   m/s    Degrees  Deg. C  Radiation Humidity   in.  Hg     ppmC
204
204
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
205
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
2820
2880
2940
3000
3060
3120
3180
3240
3300
3360
3420
3480
3540
3600
3660
3720
3780
3840
3900
3960
4020
4080
4140
4200
4260
4320
4380
4440
4500
4560
4620
4680
4740
4800
4860
4920
4980
5040
5100
5160
5220
5280
5340
5400
5460
5520
0.75
0.75
0.63
0.50
0.25
0.38
1.00
0.88
0.75
0.63
0.75
1.75
1.50
1.75
1.25
3.50
2.63
3.25
3.00
1.88
1.25
0.50
0.38
0.25
0.50
0.38
0.25
0.38
0.75
0.75
0.38
0.63
0.50
0.88
1.88
1.00
2.00
1.25
2.38
1.38
2.00
1.75
2.13
1.88
1.38
1.63
310.0
350.0
135.0
152.5
135.0
330.0
250.0
257.5
297.5
12.5
320.0
342.5
0.0
277.5
190.0
357.5
147.5
277.5
337.5
360.0
360.0
90.0
140.0
70.0
227.5
147.5
120.0
90.0
90.0
80.0
100.0
95.0
140.0
150.0
150.0
45.0
140.0
35.0
22.5
45.0
45.0
150.0
137.5
125.0
360.0
50.0
26.50
25.25
27.50
27.50
27.00
27.50
27.50
27.00
25.50
24.00
24.00
26.50
29.00
31.00
32.00
34.00
35.50
34.50
32.00
32.00
29.00
28.00
28.00
28.00
28.00
28.00
28.00
27.00
26.00
26.00
26.00
25.50
25.50
25.00
25.00
26.00
27.00
28.00
28.50
30.00
31.00
32.00
31.00
30.00
30.00
27.00
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
2.
3.
4.
000
000
000
000
000
000
000
000
000
125
125
125
250
000
5.125
5.500
5.500
4.625
4.250
3.125
2.625
0.625
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0
0
0
1
2
3
3
4
5
4
k
3
1
0
.000
.000
.000
.250
.875
.625
.625
.125
.750
.750
.000
.500
.125
.000
.875
.750
69.50
65.00
62.50
61.25
61.00
61.00
61.00
61.00
61.00
61.00
64.50
69.00
73.50
77.00
78.00
79.00
80.00
81.50
80.50
80.00
79.50
72.50
67.00
64.00
63.50
62.00
62.00
62.00
62.00
62.00
62.00
61.00
60.50
62.00
63.50
67.00
70.00
72.50
76.00
76.00
77.00
78.00
77.00
75.50
74.00
72.00
29.790
29.790
29.800
29.850
29.800
29.800
29.800
29.805
29.810
29.815
29.825
29.815
29.810
29.815
29.815
29.805
29.775
29.775
29.745
29.735
29.725
29.730
29.755
29.705
29.775
29.785
29.800
29.805
29.800
29.800
29.805
29.815
29.820
29.830
29.830
29.830
29.825
29.820
29.815
29.805
29.785
29.775
29.760
29.760
29.750
29.750














0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0





























.057562
.054007
.070276
.059004
.067600
.062102
.075598
.083180
.077769
.118937
.069907
.086711
.075990
.053487
.056635
.045167
.046845
















-------
                                                   APPENDIX  B
1989 APDFIO DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY METEROLOGICAL AND NHOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
206
206
206
206
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
207
208
208
208
208
208
208
208
208
208
208
208
208
208
208
208
208
208
208
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
5580
5640
5700
5760
5820
5880
5940
6000
6060
6120
6180
6240
6300
6360
6420
6480
6540
6600
6660
6720
6780
6840
6900
6960
7020
7080
7140
7200
7260
7320
7380
7440
7500
7560
7620
7680
7740
7800
7860
7920
7980
8040
8100
8160
8220
8280
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.38
1.13
1.50
1.75
3.63
2.50
1
1
1
2
0
0
0
0
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
2
3
3
3
3
3
4
3
3
.63
.25
.88
.63
.30
.10
.10
.80
.15
.00
.38
.25
.25
.38
.25
.00
.00
.38
.50
.00
.50
.25
.13
.88
.38
.63
.50
.88
.13
.38
.75
.63
.13
.13
.00
.00
.38
.50
.25
.13
132.5
147.5
77.5
2.5
25.0
50.0
77.5
120.0
80.0
150.0
245.0
110.0
45.0
20.0
155.0
300.0
360.0
232.5
225.0
112.5
150.0
175.0
172.5
170.0
165.0
170.0
180.0
225.0
0.0
337.5
252.5
250.0
240.0
360.0
360.0
360.0
360.0
315.0
290.0
260.0
215.0
200.0
215.0
220.0
220.0
197.5
27.00
27.00
27.00
27.50
26.00
24.50
24.00
24.00
24.00
23.50
21.00
22.50
25.00
26.00
28.00
30.50
31.50
31.00
33.00
32.00
32.00
33.00
31.50
29.50
28.00
27.50
26.00
25.75
23.50
22.00
22.00
22.00
22.00
22.00
22.00
23.00
25.00
28.00
29.50
31.00
27.50
26.00
27.00
28.50
30.00
30.00
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.750
1.625
2.500
3.625
4.125
3.125
3.375
2.625
2.375
2.250
1.375
0.500
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.500
1.500
1.750
2.500
2.500
4.375
5.000
3.250
3.125
1.125
71.00
68.50
65.50
63.00
62.00
61.50
60.00
60.00
60.00
60.00
59.00
58.00
61.00
67.00
72.00
77.00
77.50
77.50
78.50
78.00
77.00
77.00
74.00
71.00
69.50
68.00
67.00
65.50
62.00
60.00
60.00
60.00
60.00
60.00
60.00
60.00
60.00
61.00
62.50
66.50
68.00
70.50
74.00
74.50
74.00
73.00
29.765
29.765
29.765
29.765
29.775
29.780
29.770
29.770
29.765
29.760
29.765
29.770
29.775
29.765
29.755
29.755
29.745
29.730
29.710
29.695
29.670
29.655
29.645
29.655
29.670
29.670
29.675
29.725
29.685
29.685
29.635
29.625
29.655
29.665
29.655
29.660
29.650
29.645
29.625
29.620
29.605
29.580
29.565
29.535
29.515
29.525
Average
ppmC


















0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.






















056668
076619
067852
099407
260356
170896
164061
153958
151380
097590
050601
065502
064022
075926
056254
030304
037810
062805
078215
091741
098607
087067
.093347
076161





-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
208
208
208
208
208
208
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
209
210
210
210
210
210
210
210
210
210
210
210
210
210
210
210
210
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
8340
8400
8460
8520
8580
8640
8700
8760
8820
8880
8940
9000
9060
9120
9180
9240
9300
9360
9420
9480
9540
9600
9660
9720
9780
9840
9900
9960
10020
10080
10140
10200
10260
10320
10380
10440
10500
10560
10620
10680
10740
10800
10860
10920
10980
11040
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
2.13
2.38
2.00
1.50
3.38
1.13
0.75
1.00
1.50
1.50
1.63
1.75
2.00
2.63
2.63
3.00
3.63
3.63
1.00
1.00
1.38
1.63
1.63
1.00
0.88
0.25
0.00
0.75
0.38
0.13
0.25
1.25
1.25
0.63
0.63
0.88
0.50
0.50
1.50
2.00
2.38
2.00
1.63
3.25
3.38
2.63
270.0
270.0
270.0
260.0
250.0
250.0
260.0
257.5
270.0
255.0
265.0
270.0
270.0
320.0
320.0
360.0
360.0
360.0
360.0
345.0
345.0
280.0
280.0
280.0
280.0
280.0
280.0
280.0
360.0
265.0
315.0
337.5
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
50.0
50.0
50.0
50.0
30.00
27.50
26.00
26.00
24.50
24.00
24.00
23.50
23.00
23.00
23.00
22.00
22.00
23.25
25.25
26.25
28.50
28.75
30.75
32.00
32.00
32.00
32.00
32.00
32.00
31.50
30.50
28.75
24.25
24.25
26.00
26.00
26.00
25.00
24.00
23.00
22.00
22.00
26.00
28.00
28.00
28.00
29.50
30.00
28.50
26.00
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
2.
500
500
000
000
000
000
000
000
000
000
000
000
000
250
125
375
3.625
2.875
4.500
5.125
4.875
4.500
3.500
2.625
1.625
0.625
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0
0
1
2
2
1
2
2
2
3
.000
.000
.000
.250
.000
.000
.125
.750
.125
.500
.625
.250
70.00
70.00
68.00
67.00
64.00
63.00
62.00
62.00
62.00
62.00
62.00
61.25
61.00
62.75
67.00
69.00
73.75
74.00
74.50
74.00
74.00
74.00
74.00
74.00
74.00
72.00
70.00
70.00
63.50
62.00
62.00
61.25
61.00
60.75
60.00
60.00
59.25
59.50
60.50
63.25
64.00
64.00
64.50
66.00
69.25
71.00
29.520
29.515
29.520
29.525
29.500
29.460
29.480
29.490
29.480
29.465
29.465
29.455
29.465
29.470
29.470
29.465
29.470
29.460
29.455
29.460
29.440
29.435
29.425
29.405
29.395
29.395
29.425
29.460
29.470
29.485
29.485
29.485
29.485
29.495
29.495
29.505
29.535
29.560
29.575
29.595
29.600
29.605
29.605
29.600
29.580
29.570
Average
ppmC



















0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.



























077581
092860
059582
088724
099540
117756
128999
178093
158403
043925
070225 »
095936
083253
040857
039593
043861
029880
033063
031599









-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
210
210
210
210
210
210
210
210
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
211
212
212
212
212
212
212
212
212
212
212
212
212
212
212
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
11100
11160
11220
11280
11340
11400
11460
11520
11580
11640
11700
11760
11820
11880
11940
12000
12060
12120
12180
12240
12300
12360
12420
12480
12540
12600
12660
12720
12780
12840
12900
12960
13020
13080
13140
13200
13260
13320
13380
13440
13500
13560
13620
13680
13740
13800
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
2.50
1.88
2.50
3.00
3.00
1.75
1.50
2.50
2.38
3.00
2.50
1.75
0.88
1.13
1.38
1.50
2.38
2.38
2.50
2.00
2.63
2.00
1.13
2.00
1.88
1.13
1.00
1.25
1.63
1.50
2.00
1.38
2.25
0.75
1.00
0.88
1.38
0.75
2.00
1.25
1.00
1.00
1.00
1.75
1.00
1.50
50.0
50.0
75.0
50.0
75.0
100.0
67.5
45.0
25.0
105.0
100.0
30.0
60.0
127.5
82.5
60.0
37.5
102.5
97.5
120.0
130.0
130.0
142.5
180.0
167.5
130.0
130.0
130.0
130.0
130.0
200.0
200.0
200.0
200.0
245.0
295.0
335.0
22.5
67.5
147.5
180.0
180.0
195.0
215.0
222.5
222.5
25.50
26.00
25.25
24.50
24.00
24.00
23.00
22.00
20.50
21.00
21.00
19.00
18.00
18.00
18.00
18.00
19.00
21.50
23.00
25.00
26.00
27.00
26.50
26.00
28.00
26.00
26.50
27.50
26.00
26.00
25.00
25.00
25.75
27.00
27.00
26.25
24.00
24.00
24.00
24.00
24.00
24.50
25.25
26.25
27.75
28.75
3.000
2.375
1.500
0.625
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.250
0.875
1.500
2.250
3
4
5
4
2
2
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
4
2
.875
.500
.250
.250
.875
.625
.250
.250
.625
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.125
.750
.250
.625
.375
.750
.875
72.00
72.00
68.50
65.50
63.50
62.00
60.25
58.50
58.00
58.00
57.25
56.00
56.00
56.00
56.00
56.00
58.00
59.75
63.50
66.50
67.50
71.50
75.00
72.50
72.00
70.00
68.50
66.50
66.00
66.00
65.50
66.00
65.25
65.00
64.00
63.50
61.25
61.00
61.00
61.00
61.50
64.50
66.75
67.75
69.50
72.50
29.560
29.565
29.575
29.575
29.580
29.605
29.635
29.635
29.635
29.645
29.645
29.625
29.625
29.635
20.645
29.655
29.665
29.665
29.660
29.655
29.640
29.630
29.610
29.595
29.575
29.565
29.560
29.555
29.555
29.555
29.580
29.595
29.600
29.610
29.610
29.560
29.550
29.550
29.560
29.570
29.585
29.605
29.605
29.615
29.605
29.590
Average
ppmC




















0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




















063386
057273
058403
049973
050787
064703
069786
087065
103116
102530
099479
055975 *
056901
059464
0.064461
0.
0.
0.
0.
0.
0.
049620
082981
103095
114790
274410
225643
0.119554
0.
201435
0.110287
0.088580
0.081951

-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY, RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
212
212
212
212
212
212
212
212
212
212
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
213
214
214
214
214
214
214
214
214
214
214
214
214
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
a
9
10
11
12
13860
13920
13980
14040
14100
14160
14220
14280
14340
14400
14460
14520
14580
14640
14700
14760
14820
14880
14940
15000
15060
15120
15180
15240
15300
15360
15420
15480
15540
15600
15660
15720
15780
15840
15900
15960
16020
16080
16140
16200
16260
16320
16380
16440
16500
16560
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.13
1.50
1.75
1.25
0.38
1.13
2.50
1.50
1.88
2.13
0.750
0.625
1.000
0.750
0.750
0.625
2.250
1.250
0.500
0.500
0.500
0.500
0.650
1.000
0.875
0.750
1.000
1.500
1.500
0.500
1.000
2.125
1.250
0.625
0.500
1.750
1.875
1.500
1.000
1.000
1.000
1.250
2.000
2.000
1.500
1.500
290.0
325.0
337.5
332.5
225.0
270.0
352.5
25.0
50.0
90.0
22.5
107.5
67.5
225.0
257.5
360.0
360.0
360.0
360.0
67.5
45.0
135.0
135.0
135.0
135.0
135.0
360.0
360.0
360.0
7.5
360.0
257.5
300.0
360.0
130.0
182.5
170.0
170.0
182.5
220.0
250.0
250.0
260.0
260.0
260.0
260.0
29.00
29.75
30.75
30.00
30.00
29.75
28.50
27.50
26.25
22.75
23.00
24.00
24.00
24.00
24.00
24.00
24.00
24.00
24.00
24.00
24.00
24.00
24.50
26.25
27.00
29.00
28.00
28.00
26.75
26.00
26.00
25.25
24.25
24.00
25.75
24.25
24.00
24.00
24.00
24.00
24.00
24.00
24.25
25.00
25.00
25.75
2.750
4.125
2.875
2.125
0.875
0.125
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.375
0.375
0.750
2.500
2.625
4.125
3.000
2.000
0.875
0.500
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.625
1.125
1.000
2.375
74.00
75.25
76.50
78.00
78.50
78.00
76.00
70.75
66.50
62.25
60.00
60.00
60.00
60.00
60.00
60.00
60.00
60.00
60.00
60.50
61.00
61.00
61.75
66.75
70.00
68.00
71.50
72.00
70.50
68.00
66.50
66.00
65.00
63.50
62.25
62.00
61.25
60.00
60.00
60.00
60.00
60.00
60.75
64.25
67.00
69.50
29.565
29.545
29.530
29.520
29.515
29.525
29.535
29.555
29.595
29.585
29.580
29.585
29.580
29.570
29.575
29.590
29.610
29.625
29.640
29.655
29.655
29.655
29.650
29.640
29.620
29.600
29.585
29.585
29.580
29.585
29.605
29.605
29.600
29.595
29.605
29.580
29.570
29.560
29.575
29.580
29.570
29.590
29.590
29.600
29.600
29.590
Average
ppnC
0.048846
0.055810
0.070541
0.085906
0.073949
0.112876
0.156956
0.113947
0.028406
0.030402 *

















0.107169
0.132028
0.124116
0.268695
0.209387
0.154582
0.161132
0.166285 *












-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY METEROLOGICAL AND NHOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
214
214
214
214
214
214
214
214
214
214
214
214
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
216
216
216
216
216
216
216
216
216
216
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
16620
16680
16740
16800
16860
16920
16980
17040
17100
17160
17220
17280
17340
17400
17460
17520
17580
17640
17700
17760
17820
17880
17940
18000
18060
18120
18180
18240
18300
18360
18420
18480
18540
18600
18660
18720
18780
18840
18900
18960
19020
19080
19140
19200
19260
19320
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.500
1.250
1.125
2.400
1.500
1.000
1.000
0.750
0.250
0.250
0.250
0.750
0.125
0.500
0.500
0.250
0.375
0.500
0.250
0.500
0.750
1.250
1.875
1.250
1.750
1.875
2.625
2.500
2.500
2.625
2.500
2.000
1.750
0.750
0.750
0.500
0.500
0.875
0.625
0.750
0.875
0.875
1.375
0.875
1.125
1.375
222.5
225.0
242.5
250.0
160.0
225.0
225.0
165.0
55.0
220.0
60.0
7.5
67.5
90.0
67.5
0.0
90.0
40.0
22.5
30.0
0.0
0.0
0.0
292.5
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
240.0
210.0
192.5
240.0
245.0
245.0
125.0
267.5
250.0
337.5
270.0
275.0
290.0
310.0
26.00
26.50
27.00
22.25
24.00
24.75
25.00
24.00
23.75
22.25
21.50
21.00
20.25
20.00
20.00
18.50
18.00
18.00
18.25
19.50
21.50
23.50
25.00
27.00
28.00
28.50
29.25
30.00
31.00
32.00
31.75
30.75
30.00
29.25
28.00
26.75
26.00
25.00
23.00
23.25
23.00
22.00
22.75
23.00
23.75
27.50
3.375
3.375
2.000
1.125
2.375
1.875
0.875
0
0
0
0
0
0
0
0
0
0
0
0
0
1
2
3
4
4
4
4
4
3
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
2
.125
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.250
.000
.125
.125
.000
.750
.750
.700
.250
.500
.250
.375
.500
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.375
.125
.375
70.00
70.00
68.50
62.00
68.00
66.00
63.00
61.50
60.25
59.50
58.75
58.00
58.00
58.00
58.00
56.00
56.00
56.00
56.00
56.00
56.75
61.75
66.75
72.25
74.00
74.00
75.00
76.00
76.00
75.50
74.75
73.50
71.50
69.50
67.50
65.00
64.00
64.00
60.00
60.00
60.00
60.00
60.00
60.00
61.25
66.25
29.580
29.560
29.550
29.555
29.450
29.555
29.545
29.545
29.555
29.565
29.575
29.585
29.580
29.575
29.560
29.555
29.560
29.560
29.570
29.570
29.590
29.590
29.600
29.590
29.570
29.560
29.545
29.530
29.525
29.515
29.505
29.505
29.505
29.505
29.515
29.510
29.510
29.500
29.490
29.485
29.480
29.480
29.490
29.495
29.500
29.495
Average
ppmC


























0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0



























.829420
.661431
.492265
.478257
.380394
.296616
.448003
.440781
.475506
.488352
.538978
.476346
.505580
.368947
.250659
.199582
.269215
.318790
.341569


-------
                                                   APPENDIX  8
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NMOC CONCENTRATION DATA
	 ==— ======:==_===c==
Julian Diurnal
Date Hour Minutes
216
216
216
216
216
216
216
216
216
216
216
216
216
216
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
217
218
218
218
218
218
218
218
218
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
19380
19440
19500
19560
19620
19680
19740
19800
19860
19920
19980
20040
20100
20160
20220
20280
20340
20400
20460
20520
20580
20640
20700
20760
20820
20880
20940
21000
21060
21120
21180
21240
21300
21360
21420
21480
21540
21600
21660
21720
21780
21840
21900
21960
22020
22080
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure Average
m/s Degrees Deg. C Radiation Humidity in. Hg ppmC
1.
2.
2.
2.
2.
2.
2.
3.
750
250
875
250
500
500
625
500
3.750
2.750
2.125
1.750
1.
.375
1.500
1.750
3.000
2.750
2.500
2.375
3.000
3
2
2
2
1
1
2
2
2
2
3
1
1
1
0
0
0
1
1
1
2
2
1
2
2
2
.000
.000
.000
.125
.375
.938
.500
.625
.250
.500
.625
.625
.875
.125
.875
.500
.500
.125
.250
.875
.250
.000
.375
.000
.250
.000
335.0
355.0
330.0
320.0
320.0
320.0
295.0
270.0
270.0
280.0
290.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
270.0
287.5
340.0
337.7
335.3
90.0
345.0
270.0
325.0
282.5
245.0
143.8
118.8
312.0
353.3
279.0
272.3
292.5
294.8
276.8
245.3
316.0
306.5
328.5
31.00
33.00
34.00
34.75
35.00
34.75
34.00
33.00
32.00
31.50
30.75
30.00
29.25
28.75
28.00
27.25
26.50
26.00
26.00
25.25
25.00
25.00
25.75
26.00
28.25
30.63
33.00
33.25
33.00
33.00
30.00
26.50
28.00
28.25
26.75
26.00
25.50
26.75
26.75
27.00
27.00
26.25
26.25
26.00
25.00
25.25
3.
4.
5.
4.
4.
4.
3.
2.
1.
0.
500
250
000
875
875
250
375
375
250
250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.188
4.375
3.875
2.875
3.375
3.250
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.125
.750
.375
.125
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.375
70.
75.
78.
78.
80.
80.
82.
80.
79.
50
25
00
50
00
50
00
00
00
76.50
73.50
72.00
70.50
68.50
68.00
68.00
67.00
64.50
64.00
64.00
64.00
64.00
64.00
64.75
70.00
74.13
78.25
78.50
77
79
75
68
70
70
68
65
65
65
67
67
68
66
66
65
64
65
.25
.25
.00
.25
.00
.00
.25
.75
.25
.75
.00
.00
.00
.75
.00
.75
.50
.00
29.490
29.490
29.480
29.475
29.450
29.440
29.435
29.415
29.405
29.405
29.405
29.415
29.415
29.405
29.400
29.395
29.385
29.380
29.385
29.385
29.395
29.400
29.415
29.405
29.415
29.405
29.385
29.385
29.365
29.345
29.355
29.345
29.320
29.320
29.330
29.355
29.355
29.355
29.345
29.355
29.300
29.270
29.260
29.275
29.295
29.305

-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY, RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
218
218
218
218
218
218
218
218
218
218
218
218
218
218
218
218
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
219
220
220
220
220
220
220
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
22140
22200
22260
22320
22380
22440
22500
22560
22620
22680
22740
22800
22860
22920
22980
23040
23100
23160
23220
23280
23340
23400
23460
23520
23580
23640
23700
23760
23820
23880
23940
24000
24060
24120
24180
24240
24300
24360
24420
24480
24540
24600
24660
24720
24780
24840
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.500
1.875
3.000
2.625
2.375
2.750
2.000
2.750
2.625
2.625
2.750
0.625
0.250
0.250
1.000
0.750
1.375
1.750
1.500
1.125
0.875
0.750
0.500
0.625
0.625
0.375
2.500
2.000
1.875
2.375
2.375
2.625
2.500
3.375
2.375
1.500
2.500
2.750
2.000
1.750
2.250
2.000
1.625
1.625
1.875
1.500
344.3
317.3
324.0
339.8
342.0
339.8
339.8
335.3
330.8
355.5
6.8
27.0
15.8
114.5
348.8
33.8
225.0
306.0
321.8
4.5
328.5
2.3
355.5
15.8
321.8
265.5
348.8
180.0
273.8
330.5
353.3
342.0
342.0
357.8
360.0
330.8
333.8
15.8
18.0
18.0
20.3
13.5
20.3
20.3
13.5
22.5
27.75
29.50
31.00
31.75
32.00
32.00
32.25
33.00
33.00
33.00
32.50
31.25
28.75
27.75
27.00
27.00
25.75
27.00
26.00
24.50
24.00
23.50
23.00
24.00
26.00
27.00
29.00
30.50
31.00
31.75
31.25
31.25
31.50
31.25
30.00
26.50
25.00
23.50
22.75
21.50
21.00
20.25
19.50
19.00
19.00
18.25
1,
.625
2.750
3.750
4.625
5.125
5.250
5.000
4
.500
3.750
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
2
3
4
4
4
3
3
2
2
1
0
0
0
0
0
0
0
0
0
0
0
.625
.500
.375
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.500
.250
.375
.625
.375
.500
.500
.000
.000
.875
.375
.125
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
69.25
73.00
76.00
75.75
77.00
76.00
78.00
79.00
80.00
79.00
78.00
75.25
69.75
68.75
67.25
67.25
67.00
68.00
66.50
64.00
62.50
62.00
62.00
63.25
66.75
69.75
72.50
74.50
76.50
77.00
75.75
77.50
77.00
76.25
73.50
66.75
63.75
62.50
61.25
60.00
58.25
57.75
56.25
55.75
55.00
54.75
29.310
29.320
29.320
29.325
29.305
29.290
29.280
29.265
29.250
29.250
29.230
29.250
29.270
29.270
29.270
29.270
29.270
29.260
29.245
29.230
29.240
29.240
29.280
29.265
29.260
29.260
29.265
29.260
29.245
29.230
29.215
29.215
29.225
29.225
29.260
29.265
29.305
29.335
29.365
29.375
29.380
29.390
29.405
29.405
29.410
29.425
Average
ppmC



0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




0.
0.



062104
051890
024221
038264
017445
035570
040444
023514
070687
135696
279258
218372
161774
133111
101040
08S059
095621
086385
084986
082600
113020
114289




241149
122748
0.140472
0.080280
0.076112
0.098444
0.123469
0.094335
0.056040
0.064952
0.094719
0.089059
0.095650
0.065432
0.053167
0
.051665
0.061107

-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
220
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
221
222
222
222
222
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
24900
24960
25020
25080
25140
25200
25260
25320
25380
25440
25500
25560
25620
25680
25740
25800
25860
25920
25980
26040
26100
26160
26220
26280
26340
26400
26460
26520
26580
26640
26700
26760
26820
26880
26940
27000
27060
27120
27180
27240
27300
27360
27420
27480
27540
27600
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.375
1.125
2.000
1.250
2.250
2.125
1.500
1.500
0.750
1.125
1.500
0.875
0.500
0.750
0.625
0.750
0.500
0.125
0.375
0.750
0.250
0.250
0.500
0.500
0.750
1.250
1.500
1.125
1.250
2.625
2.250
2.750
2.625
2.000
1.625
0.875
0.500
1.625
2.000
0.875
0.500
0.625
1.250
0.750
1.500
0.625
27.0
24.8
18.0
18.0
13.5
18.0
22.5
27.0
135.0
112.5
130.5
60.8
58.5
94.3
85.5
65.3
101.3
69.8
45.0
20.3
36.0
123.8
9.0
36.0
27.0
22.5
22.5
103.5
292.5
148.5
83.3
117.0
121.5
121.5
63.0
162.0
33.8
126.0
123.8
58.5
67.8
51.8
15.8
51.8
31.5
40.5
17.75
17.25
18.25
19.75
21.75
23.00
22.50
22.00
22.00
22.00
22.50
23.00
22.75
21.50
20.75
20.00
19.75
19.50
19.50
19.00
19.00
18.75
18.00
18.00
18.00
17.75
18.50
20.00
21.75
22.25
23.75
24.00
24.00
23.75
23.75
22.50
22.00
21.25
19.50
19.00
19.00
18.25
18.00
18.00
17.50
17.00
0.000
0.250
0.875
2.000
3.125
4.000
2.500
1.625
1.500
1.625
2.125
1.
.250
1.000
0.125
0.000
0
.000
0.000
0
0
0
0
0
0
0
0
0
1
2
2
4
3
3
2
2
2
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.250
.000
.000
.875
.125
.625
.500
.875
.375
.625
.625
.250
.375
.000
.000
.000
.000
.000
.000
.000
.000
53.75
53.75
54.75
59.00
62.25
65.25
64.00
62.00
62.00
63.25
64.75
64.00
62.75
60.25
58.00
57.50
57.00
57.00
56.50
56.00
55.50
55.00
54.75
54.00
54.00
54.00
55.25
59.00
61.25
64.50
65.25
66.00
65.75
65.25
66.75
62.00
60.25
59.50
57.25
56.00
56.00
55.25
54.00
54.00
54.00
53.75
29.455
29.480
29.505
29.515
29.525
29.535
29.520
29.520
29.200
29.520
29.525
29.530
29.525
29.590
29.565
29.570
29.590
29.605
29.605
29.605
29.605
29.615
29.630
29.645
29.670
29.685
29.700
29.710
29.720
29.715
29.710
29.700
29.695
29.630
29.685
29.685
29.690
29.690
29.700
29.720
29.730
29.730
29.725
29.725
29.720
29.720
Average
ppnC
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0































.043690
.057904
.090524
.057898
.059019
.038853
.044494
.070486
.044008
.060449
.067580
.079614
.113730
.178660
.110325
































-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
222
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
223
224
224
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
27660
27720
27780
27840
27900
27960
28020
28080
28140
28200
28260
28320
28380
28440
28500
28560
28620
28680
28740
28800
28860
28920
28980
29040
29100
29160
29220
29280
29340
29400
29460
29520
29580
29640
29700
29760
29820
29880
29940
30000
30060
30120
30180
30240
30300
30360
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.
1.
000
875
2.500
3.250
4.000
2.500
2.625
2.625
3.625
3.500
2
2
2
3
3
2
2
3
2
3
2
2
2
2
2
2
1
1
1
2
2
2
1
2
1
2
2
1
1
2
1
1
1
1
1
1
.875
.500
.750
.375
.000
.750
.750
.125
.750
.375
.375
.750
.375
.625
.625
.375
.500
.625
.875
.250
.125
.000
.875
.375
.875
.000
.000
.875
.750
.000
.625
.750
.750
.625
.375
.250
20.3
13.5
18.0
18.0
18.0
22.5
24.8
18.0
11.3
20.3
15.8
15.8
18.0
13.5
18.0
13.5
13.5
15.8
11.3
11.3
9.0
9.0
4.5
2.3
11.3
11.3
15.8
9.0
13.5
2.3
6.8
18.0
11.3
2.3
0.0
4.5
13.5
6.8
11.3
13.5
9.0
6.8
6.8
13.5
6.8
15.8
17.00
16.75
16.00
16.00
16.00
16.50
17.00
17.00
17.00
17.25
18.00
18.00
17.25
17.00
17.00
17.00
17.00
17.00
16.00
16.00
16.00
16.00
16.00
16.00
16.00
16.75
17.00
17.00
17.00
18.00
18.00
18.25
19.00
19.00
19.00
19.50
20.00
19.00
19.00
19.00
19.00
19.00
19.00
19.00
18.00
18.25
0.000
0.000
0.000
0.000
0.250
0.375
0.375
0.750
0.875
0.750
0.750
0.625
0.375
0.250
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.125
0.375
0.625
0.500
0.750
0.750
0.875
0.875
0.750
0.500
0.125
0.125
0.000
0.000
0.000
0.000
0.000
0.000
53.00
52.00
51.75
51.00
50.50
51.25
51.00
51.00
53.25
55.50
56.00
56.50
56.00
55.50
54.50
54.00
54.00
54.00
54.00
54.00
52.00
51.50
52.00
52.00
52.00
52.00
52.00
52.00
53.00
54.00
54.25
55.00
56.00
56.00
56.00
56.75
58.00
57.25
56.00
56.00
56.00
56.00
56.00
56.00
56.00
56.00
29.725
29.725
29.730
29.730
29.745
29.750
29.760
29.760
29.745
29.740
29.730
29.720
29.715
29.705
29.710
29.715
29.700
29.710
29.710
29.700
29.695
29.670
29.660
29.655
29.645
29.645
29.655
29.665
29.665
29.670
29.675
29.675
29.675
29.665
29.650
29.635
29.640
29.640
29.640
29.645
29.650
29.655
29.660
29.660
29.660
29.645
Average
ppmC







0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0.











0,
0.
0
0
0
0
0
0
0








038033
081398
066588
078254
126759
160172
054354
032380
043275
031025
043080
055277
078572
047930
037823
069183

073195 *











.057431 *
.051915
.054847
.069100
.067650
.045249
.035892
.041771
.045607


-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NHOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
224
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
225
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
30420
30480
30540
30600
30660
30720
30780
30840
30900
30960
31020
31080
31140
31200
31260
31320
31380
31440
31500
31560
31620
31680
31740
31800
31860
31920
31980
32040
32100
32160
32220
32280
32340
32400
32460
32520
32580
32640
32700
32760
32820
32880
32940
33000
33060
33120
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
1.
375
1.250
1.625
1.750
1.625
2.125
2.625
2.375
2.125
2.625
2.125
2
2
1
1
1
1
1
0
0
0
0
0
0
0
0
1
0
0
1
0
1
1
1
1
2
1
1
1
1
1
0
1
1
0
0
.000
.125
.500
.500
.750
.750
.375
.750
.250
.500
.250
.250
.375
.000
.375
.000
.625
.625
.250
.750
.000
.000
.250
.250
.250
.625
.250
.750
.500
.125
.500
.000
.750
.500
.500
18.0
20.3
11.3
6.8
15.8
9.0
9.0
9.0
2.3
2.3
13.5
9.0
6.8
18.0
11.3
11.3
13.5
15.8
32.0
40.5
101.3
36.0
42.8
60.8
83.3
45.0
11.3
11.3
105.8
33.8
24.8
72.0
162.0
177.8
20.3
94.5
63.0
56.3
69.8
110.3
119.3
63.0
130.5
148. 5
153.0
96.8
19.00
19.00
19.00
19.00
19.00
19.00
19.75
20.00
20.00
20.50
21.50
22.50
23.25
23.50
23.00
23.00
22.50
21.75
20.75
20.00
20.00
19.25
19.00
19.00
19.00
19.50
19.50
20.00
20.00
20.00
20.25
21.25
22.75
25.25
27.00
27.25
28.25
27.75
29.00
28.25
27.50
25.25
25.00
24.00
23.50
22.25
0.
000
0.000
0.000
0.000
0.000
0.000
0.500
0.625
0.500
1.000
1.500
1.625
2.375
1.500
0.625
0.500
0.375
0.125
0.000
0.000
0.000
0.000
0.000
0
.000
0.000
0
0
0
0
0
0
0
1
3
4
5
4
3
3
2
1
0
0
0
0
0
.000
.000
.000
.000
.250
.625
.875
.750
.500
.125
.125
.500
.875
.250
.500
.125
.125
.000
.000
.000
.000
56.00
56.00
56.00
56.00
56.00
56.00
56.00
56.00
56.25
58.00
60.25
62.25
64.25
64.00
62.50
62.00
61.50
60.00
59.25
58.00
56.75
56.00
56.00
56.00
56.00
56.50
56.25
57.00
57.00
57.75
58.00
59.00
61.50
68.75
70.50
72.75
74.50
74.50
75.25
74.50
71.25
65.50
64.00
63.25
62.00
60.75
29.635
29.625
29.625
29.630
29.645
29.655
29.650
29.655
29.670
29.665
29.650
29.640
29.635
29.630
29.625
29.625
29.615
29.615
29.625
29.625
29.635
29.635
29.635
29.615
29.625
29.625
29.630
29.625
29.625
29.645
29.655
29.660
29.670
29.665
29.650
29.640
29.630
29.615
29.605
29.610
29.605
29.610
29.625
29.635
29.635
29.630
==========
Average
ppnC




































0.087817 *
0.101846
0.062548
0.075783
0.069509
0.064789
0.079699
0.070880
0.076975
0.098210

-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY,  RLNC SITE;
HOURLY HETEROLOGICAL AND NMOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
226
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
227
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
33180
33240
33300
33360
33420
33480
33540
33600
33660
33720
33780
33840
33900
33960
34020
34080
34140
34200
34260
34320
34380
34440
34500
34560
34620
34680
34740
34800
34860
34920
34980
35040
35100
35160
35220
35280
35340
35400
35460
35520
35580
35640
35700
35760
35820
35880
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure Average
m/s Degrees Deg. C Radiation Humidity in. Hg ppmC
0.500
0.375
0.500
0.500
0.500
0
.500
0.250
0
0
1
2
1
1
1
0
1
1
1
1
1
1
0
0
0
0
1
0
0
0
0
0
1
0
0
1
1
0
0
1
0
1
1
0
0
0
0
.625
.750
.125
.100
.000
.375
.750
.500
.125
.125
.000
.000
.375
.250
.375
.000
.375
.625
.125
.625
.250
.625
.875
.875
.000
.750
.750
.250
.250
.625
.625
.000
.750
.000
.250
.875
.000
.000
.375
40.5
96.8
20.3
38.3
49.5
24.8
42.5
15.8
47.3
67.5
144.0
42.3
18.0
20.3
105.8
13.5
27.0
13.5
9.0
85.5
128.3
65.3
102.8
54.0
76.5
42.8
31.5
27.0
18.0
11.3
6.5
22.5
13.5
22.5
18.0
6.8
47.3
108.0
31.5
76.5
36.0
78.8
24.8
24.8
92.3
81.0
21.25
21.25
21.00
21.00
21.00
21.00
21.00
21.00
22.00
22.50
21.75
21.00
22.00
22.75
23.00
23.75
24.00
24.00
23.50
22.75
22.00
22.00
21.25
21.00
21.00
21.00
21.00
21.00
21.00
21.00
21.00
21.00
21.25
22.00
22.25
23.25
24.50
25.25
26.75
27.00
27.00
27.50
27.50
25.25
23.50
23.00
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.500
0.625
0.250
0
0
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
2
2
2
1
1
1
.000
.750
.250
.375
.375
.250
.125
.375
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.250
.375
.750
.875
.000
.500
.250
.625
.250
.750
.875
.250
0.250
0.000
0
.000
60.
00
60.00
59.
59.
59.
59.
59.
59.
60.
61.
60.
59.
60.
61.
62.
63.
64.
64.
25
00
00
00
00
25
25
50
50
50
50
75
25
75
75
25
63.75
62.
60.
60.
60.
59.
59.
59.
59.
59.
59.
58.
58.
59.
25
50
00
00
50
00
00
00
00
00
50
50
25
60.00
60.00
61.25
62.00
64.00
68.00
70.00
70.75
71.75
72.75
72.00
67.50
63.00
62.00
29.630 0.064221
29.630 0.044420
29.620 0.058722
29.620 0.093819
29.620 0.102373 *
29.620
29.640
29.650
29.640
29.640
29.650
29.665
29.650
29.625
29.620
29.620
29.610
29.610
29.605
29.595
29.595
29.610
29.590
29.580
29.575
29.560
29.550
29.540
29.540
29.545
29.550
29.560
29.560
29.570
29.575
29.575
29.555
29.540
29.520
29.510
29.490 0.053576 *
29.485
29.465
29.465
29.475
29.500

-------
                                                   APPENDIX  B
1989 APDFID DIURNAL MONITORING STUDY, RLNC SITE;
HOURLY METEROLOGICAL AND NHOC CONCENTRATION DATA
Julian Diurnal
Date Hour Minutes
227
227
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
229
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
35940
36000
36060
36120
36180
36240
36300
36360
36420
36480
36540
36600
36660
36720
36780
36840
36900
36960
37020
37080
37140
37200
37260
37320
37380
37440
37500
37560
37620
37680
37740
37800
37860
37920
37980
38040
38100
38160
38220
38280
38340
38400
38460
38520
38580
38640
:=================:====:====:===================a=z===:r==:
Wind Wind % Bar.
Speed Direction t Solar Relative Pressure
m/s Degrees Deg. C Radiation Humidity in. Hg
0.125
0.125
0.625
0.375
0.000
0.000
0.000
0.000
0.375
0.500
1.250
1.125
1.750
1.500
1.000
1.375
2.125
1.000
2.125
2.500
1.000
1.375
1.500
1.375
1.750
1.625
1.250
1.625
0.375
0.750
0.625
0.625
0.625
1.000
0.625
0.750
1.125
1.625
0.750
1.500
2.000
2.375
1.000
0.750
1.125
2.250
74.3
87.8
27.0
105.8
60.8
63.0
56.3
78.8
78.8
36.0
9.0
78.8
339.8
274.5
277.8
87.8
128.3
171.0
220.5
234.0
344.3
56.3
9.0
92.3
189.0
220.5
98.8
4.5
65.3
42.8
193.5
189.0
78.8
144.0
72.0
85.5
63.0
146.3
128.3
139.5
108.0
132.8
117.0
13.5
15.8
27.0
22.50
22.00
21.25
21.00
21.00
21.00
20.00
20.00
20.00
21.50
24.25
26.50
27.50
28.75
29.50
29.50
30.00
28.75
29.00
28.00
25.25
24.50
23.75
23.25
23.00
23.00
22.50
22.00
22.00
22.00
22.00
22.00
22.00
22.00
22.25
24.25
26.50
27.25
29.00
29.50
29.75
30.00
29.00
27.75
25.25
24.00
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.250
1.500
2.500
1.375
4.125
4.375
2.750
3.125
2.250
1.875
2.000
0.250
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.625
1.500
3.250
4.250
4.750
4.750
2.250
3.625
1.750
0.750
0.250
0.000
61.75
60.75
60.00
60.00
58.50
58.00
58.00
57.50
57.25
60.00
63.50
68.25
71.25
75.75
74.25
75.00
75.75
71.25
73.75
71.25
65.50
64.75
63.00
62.00
62.00
62.00
61.75
61.00
60.25
60.00
60.00
60.00
60.00
60.00
61.50
65.00
71.50
73.25
75.00
75.00
74.50
75.50
72.25
69.25
66.00
64.00
29.
29.
29.
29.
29.
29.
29.
29.
29.
29.
29.
29.
29.
29.
500
500
500
485
475
470
470
470
485
490
495
525
510
495
29.485
29.470
29.450
29.440
29.425
29.435
29.445
29.455
29.490
29.500
29.505
29.515
29.515
29.515
29.495
29.550
29.515
29.515
29.515
29
.535
29.560
29
29
29
29
29
29
29
29
29
29
29
.565
.580
.585
.570
.560
.540
.530
.530
.535
.330
.550
Average
pproC












0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.












110367 *
128596
095726
062138
048826
064556
084478
089300
142864
080163
170107
083051
053432
096713
147274
111211
137027
123650
0.127107
0.149513
0.101127
0.074060
0.088094
0.078760







0
0
0







.048174
.055471
.041506

-------
                                                   APPENDIX B
1989 APDFID DIURNAL MONITORING STUDY, RLNC SITE;
HOURLY METEROLOGICAL AND NMOC CONCENTRATION DATA

Julian
Date H
229
229
229
229
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
230
231
231
231
231
231
231
231
231
Count
Minimum
Maximum
Average


our
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8





Diurnal
Minutes
38700
38760
38820
38880
38940
39000
39060
39120
39180
39240
39300
39360
39420
39480
39540
39600
39660
39720
39780
39840
39900
39960
40020
40080
40140
40200
40260
40320
40380
40440
40500
40560
40620
40680
40740
40800




Wind
Speed
m/s
1.375
2.500
3.875
1.875
1.250
1.125
0.625
0.750
0.750
1.375
1.125
1.750
2.000
1.625
1.250
1.250
1.250
1.125
1.625
0.875
0.875
1.250
1.000
0.625
0.500
0.500
0.750
0.875
0.500
0.750
0.875
0.500
0.875
0.625
0.500
0.750
680
0.000
4.500
1.477
Wind
Direction
Degrees
168.8
297.0
326.3
18.0
31.5
87.8
27.0
326.3
6.8
9.0
24.8
18.0
13.5
357.8
225.3
123.8
346.5
117.0
351.0
38.3
13.5
20.3
22.5
341.8
74.5
38.3
36.0
123.8
141.8
38.3
24.8
65.3
87.8
135.0
87.8
45.0
680




t
Deg. C
24.00
22.75
21.00
20.25
20.00
20.00
20.00
19.75
19.00
19.00
19.00
20.00
21.00
22.50
24.00
25.50
26.75
28.00
28.25
27.00
28.00
26.50
24.75
23.50
22.75
22.00
22.00
21.00
21.00
21.00
21.00
20.00
20.00
20.00
20.00
20.00
680
16.000
35.500
24.527

Solar
Radiation
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
0.750
1.500
1.750
1.875
3.900
3.375
2.875
2.000
1.375
1.500
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
680



%
Relative
Humidity
63.00
62.00
60.00
58.25
58.00
57.00
56.00
56.00
56.00
56.00
56.00
57.00
58.75
60.50
64.25
69.50
71.00
70.75
73.75
69.50
71.75
69.00
65.25
63.00
61.75
60.25
60.00
60.00
59.25
58.75
58.00
58.00
58.00
58.00
58.00
58.00
680
50.500
82.000
64.453
Bar.
Pressure Average
in. Hg ppnC
29.565 0.023981 *
29.615 0.022754 *
29.620 0.040294
29.640
29.640
29.605
29.605
29.605
29.605
29.635
29.655
29.660
29.665
29.660
29.675
29.675
29.665
29.655
29.650
29.645
29.635
29.635
29.625
29.625
29.635
29.660
29.650
29.680
29.670
29.660
29.670
29.680
29.650
29.640
29.660
29.685
680 249
20.645 0.017
29.875 0.829
29.563 0.113

-------
                                  APPENDIX  C

             APDFID DIURNAL CONCENTRATION AND METEROLOGICAL DATA
                     AVERAGED  BY DIURNAL  SAMPLING  PERIODS
jlh.006/cah

-------
                                                APPENDIX C
APDFID NMOC CONCENTRATION AND METEROLOGICAL DATA
AVERAGED BY DIURNAL SAMPLING PERIODS
Diurnal Temp.
Jdate minutes kelvins
204
204
205
205
205
205
205
205
206
206
206
206
206
206
206
207
207
207
207
208
208
208
208
208
208
208
208
208
208
208
209
209
209
209
210
210
210
210
210
210
211
211
211
211
212
212
2820
2460
3270
3270
3630
3810
4260
3900
4710
4710
4890
5070
5250
5700
5340
6150
6690
7140
6780
7590
7590
7590
7770
7770
7950
7950
8130
8580
8220
8220
9390
9570
10020
9660
10470
10650
11010
11460
11100
11100
12270
12450
12900
12540
13350
13350
301.38
300.44
298.65
298.65
305.48
307.15
300.98
301.86
298.48
298.48
299.15
301.98
304.48
299.65
300.34
295.48
305.48
299.21
300.18
295.48
295.48
295.48
300.65
300.65
301.32
301.32
301.65
298.53
299.15
299.15
303.65
305.15
300.67
300.86
295.48
300.48
299.82
295.50
297.51
297.51
299.15
299.98
299.15
297.65
297.15
297.15
Solar Humidity Velocity
Rad. mole Vector
J/m"2 fraction m/s Si Uj Pk
2091.5
8700.0
232.4
232.4
27189.2
26724.4
2962.9
9760.2
464.8
464.8
9527.8
21611.9
25330.1
2672.4
8453.1
232.4
15569.9
2033.4
6652.1
232.4
232.4
232.4
6971.6
6971.6
17429.0
17429.0
21147.2
987.6
6216.3
6216.3
23238.6
23935.8
2323.9
8772.6
464.8
9527.8
16499.4
2091.5
5838.7
5838.7
25330.1
18126.1
1917.2
7523.5
232.4
232.4
0.
0.
0.
0.
0.
0266
0254
0198
0198
0376
0.0427
0.0250
0.0280
0.0196
0.0196
0.0223
0.0295
0.0352
0.0231
0.0249
0.0158
0.0376
0.0232
0.0254
0.0161
0.0161
0.0161
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0226
.0226
.0261
.0261
.0290
.0216
.0225
.0225
.0326
.0353
.0250
.0262
.0161
.0228
.0248
.0169
.0197
.0197
.0230
.0258
.0221
.0207
.0182
.0182
0.2606
0.1735
0.4614
0.4614
0.7016
0.9866
-0.2715
0.1750
-0.4605
-0.4605
-0.9767
-0.8660
-1.2416
-1.1585
-1.0224
-0.3782
-0.5761
0.3836
0.1845
0.0000
0.0000
0.0000
1.5976
1.5976
1.9414
1.9414
2.3058
1.6190
1.5401
1.5401
0.0863
1.1855
0.3009
0.6063
0.0000
0.0000
-2.1705
-1.8267
-1.3403
-1.3403
-1.7583
-0.3636
-0.0432
-0.6951
-0.9355
-0.9355
2
2
2
2
1
1
1
1
2
2
2
2
2
2
2
2
1
1
1
2
1
2
2
1
1
2
2
2
1
2
1
1
1
1
1
2
2
2
1
2
1
1
1
1
2
2
1
1
2
2
2
2
2
2
3
3
3
3
3
3
3
4
4
4
4
5
5
5
5
5
5
5
5
5
5
5
6
6
6
6
7
7
7
7
7
7
1
1
1
1
2
2
5
6
1
1
3
4
5
6
1
1
2
3
4
5
6
1
4
5
6
1
1
1
2
2
3
3
4
5
6
6
3
4
5
6
1
2
4
5
6
6
3
4
5
6
1
1
NMOC
ppmC
0.562
0.478
0.208
0.153
0.056
0.066
0.071
0.068
0.117
0.258
0.060
0.077
0.080
0.528
0.226
0.386
0.067
0.117
0.107
0.099
0.044
0.089
0.156
0.090
0.086
0.119
0.104
0.241
0.073
0.172
0.078
0.080
0.092
0.089
0.032
0.081
0.070
0.293
0.032
0.127
0.060
0.053
0.075
0.069
0.204
0.208
Code
OK
OK
OK
OK
*
OK
OK
**
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
**
OK
OK
OK
OK
OK
OK
OK
OK
OK
**
OK
**
OK
OK
**
OK
OK
OK
OK
***
OK
*
OK
OK
**
OK
OK

-------
                                                APPENDIX C
APOFID NMOC CONCENTRATION AND METEROLOGICAL DATA
AVERAGED BY DIURNAL SAMPLING PERIODS
— ====-=-====-=========
Diurnal Temp.
Jdate minutes kelvins
212
212
212
212
212
212
212
212
212
212
212
213
213
213
213
214
214
214
214
214
214
214
215
215
215
215
216
216
216
216
216
216
216
216
216
217
218
218
218
218
218
218
218
218
218
218
13350
13530
13530
13710
13710
13890
13890
14340
14340
13980
13980
14790
14790
15780
15420
16230
16230
16410
16590
16770
17220
16860
17670
18210
13660
18300
19110
19110
19290
19290
19470
19650
20100
19740
19740
20550
21990
21990
22170
22350
22350
22530
22530
22980
22980
22620
297.15
297.73
297.73
300.73
300.73
302.98
302.98
299.30
299.30
299.47
299.47
297.15
297.15
298.34
298.36
297.15
297.15
297.90
299.23
297.57
294.73
296.35
291.73
303.23
300.55
299.33
295.73
295.73
300.57
300.57
307.07
307.73
302.23
302.50
302.50
298.23
298.57
298.57
302.57
305.07
305.07
305.90
305.90
301.03
301.03
302.03
Solar Humidity Velocity
Rad. mole Vector
J/mA2 fraction m/s Si Uj Pk
232.4
10457.4
10457.4
18590.9
18590.9
18126.1
18126.1
1510.5
1510.5
6681.1
6681.1
0.0
0.0
755.3
4066.8
232.4
232.4
5112.5
16964.2
10225.0
1336.2
4734.9
464.8
23145.7
1917.2
8499.5
697.2
697.2
13013.6
13013.6
26259.7
23238.6
1801.0
8801.6
8801.6
0.0
697.2
697.2
15105.1
27886.4
27886.4
24633.0
24633.0
2091.5
2091.5
9585.9
0.
0.
0.
0182
0199
0199
0.0258
0.
0.
0.
0.
0.
0258
0317
0317
0236
0236
0.0237
0.0237
0.0179
0.
0.
,0179
.0209
0.0207
0.0179
0.0179
0.0200
0.0236
0.0205
0.0155
0.0180
0
.0120
0.0323
0.0253
0.0239
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0165
.0165
.0247
.0247
.0411
.0446
.0292
.0305
.0305
.0205
.0213
.0213
.0303
.0364
.0364
.0396
.0396
.0270
.0270
.0294
-0.9355
0.0863
0.0863
0.8976
0.8976
0.8624
0.8624
-0.2038
-0.2038
0.0119
0.0119
0.0000
0.0000
0.1869
-0.0518
0.9190
0.9190
1.8055
1.1248
0.9134
-0.0492
0.5707
-0.2224
2.5417
0.9931
0.9856
0.8605
0.8605
0.9500
0.9500
1.0266
1.8643
2.4129
1.7941
1.7941
2.6667
1.4143
1.4143
1.1478
0.8648
0.8648
1.0421
1.0421
0.2306
0.2306
0.6739
1
2
1
2
1
1
2
1
2
2
1
2
2
1
1
2
2
2
2
2
2
2
2
1
1
1
2
1
2
1
2
2
2
1
2
2
2
2
2
2
1
1
2
2
1
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
4
4
4
4
4
4
4
5
5
5
5
6
6
6
6
6
6
6
6
6
7
1
1
1
1
1
1
1
1
1
1
1
2
2
3
3
4
4
5
5
6
6
1
1
5
6
1
1
2
3
4
5
6
1
4
5
6
1
1
2
2
3
4
5
6
6
1
1
1
2
3
3
4
4
5
5
6
NMOC
ppmC
0.164
0.145
0.182
0.079
0.094
0.058
0.120
0.086
0.220
0.137
0.110
0.054
0.043
0.165
0.165
0.118
0.113
0.110
0.103
0.064
0.312
0.196
0.277
0.661
0.429
0.475
0.269
0.263
0.194
0.342
0.129
0.099
0.214
0.282
0.204
0.120
0.079
0.079
0.062
0.048
0.046
0.030
0.053
0.194
0.119
0.097
S===S
Code
OK
OK
OK
OK
OK
OK
OK
**
OK
OK
**
OK
OK
**
***
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
**
OK
OK
OK
**
OK
OK
OK
***
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

-------
                                                APPENDIX C
APDFID NHOC CONCENTRATION AND METEROLOGICAL DATA
AVERAGED BY DIURNAL SAMPLING PERIODS
====================================================s:=s==============
                        Solar  Humidity Velocity
      Diurnal  Temp.    Rad.     mole    Vector            NHOC
Jdate minutes kelvins   J/mA2  fraction    m/s   Si Uj Pk  ppmC  Code
218
219
219
219
219
219
219
219
220
220
220
220
220
220
220
220
220
220
220
220
221
222
222
222
222
222
222
222
222
222
222
223
223
223
223
224
224
224
224
224
224
224
225
225
225
226
22620
23430
23430
23610
23790
23970
24420
24060
24870
24870
24870
25050
25050
25230
25410
25410
25860
25860
25500
25500
26310
27750
27930
28110
28110
28290
28290
28740
28740
28380
28380
29190
29730
30180
29820
30630
30630
30810
30990
31170
31620
31260
32610
33060
32700
33510
302.03
296.65
296.65
300.48
304.23
304.48
296.42
298.94
290.90
290.90
290.90
293.07
293.07
295.65
295.32
295.32
293.28
293.28
293.50
293.50
291.07
289.40
289.65
290.23
290.23
290.90
290.90
289.57
289.57
289.81
289.81
290.07
292.65
292.00
291.68
292.15
292.15
293.07
294.65
296.40
293.42
293.74
301.48
296.59
296.90
294.15
9585.9
929.5
929.5
13478.4
24865.3
16499.4
1626.7
7784.9
464.8
464.8
464.8
11154.5
11154.5
15105.1
9760.2
9760.2
1103.8
1103.8
5112.5
5112.5
464.8
0.0
1859.1
4415.3
4415.3
3253.4
3253.4
232.4
232.4
1307.2
1307.2
232.4
4647.7
348.6
1510.5
0.0
0.0
3021.0
7668.7
8365.9
464.8
2614.3
21611.9
1742.9
7349.2
232.4
0.
0.
0294
0183
0.0183
0.0257
0.0347
0.0356
0.0189
0.0237
0.0110
0.0110
0.0110
0,
.0138
0.0138
0.0174
0.0170
0.0170
0.0137
0.0137
0.0143
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0143
.0110
.0095
.0095
.0103
.0103
.0114
.0114
.0099
.0099
.0100
.0100
.0100
.0129
.0122
.0118
.0123
.0123
.0130
.0154
.0181
.0138
.0143
.0288
.0186
.0195
.0147
0.6739
-0.0533
-0.0533
0.5823
1.0135
0.6210
-0.2285
0.1562
-0.5564
-0.5564
-0.5564
-0.5099
-0.5099
-0.6372
-0.9034
-0.9034
-0.4006
-0.4006
-0.5262
-0.5262
-0.3709
-0.7382
-1.0973
-0.9099
-0.9099
-0.7696
-0.7696
-0.5538
-0.5538
-0.7163
-0.7163
-0.3749
-0.2079
-0.3124
-0.3063
-0.3264
-0.3264
-0.2885
-0.3040
-0.3353
-0.2731
-0.2933
-1.3764
-0.5660
-0.6933
-0.1826
1
2
1
1
1
1
1
1
2
1
2
2
1
1
2
1
1
2
1
2
2
2
2
1
2
2
1
1
2
1
2
2
1
1
1
2
2
2
2
2
2
2
1
1
1
2
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
4
5
5
5
5
5
5
5
5
5
5
6
6
6
6
7
7
7
7
7
7
7
1
1
1
2
6
1
1
2
3
4
5
6
1
1
1
2
2
3
4
4
5
5
6
6
1
1
2
3
3
4
4
5
5
6
6
1
4
5
6
1
1
2
3
4
5
6
4
5
6
1
0.092
0.099
0.094
0.114
0.241
0.115
0.080
0.097
0.054
0.054
0.062
0.046
0.069
0.051
0.049
0.057
0.121
0.183
0.074
0.085
0.046
0.051
0.052
0.062
0.059
0.067
0.122
0.051
0.083
0.066
0.059
0.074
0.057
0.052
0.052
0.083
0.080
0.090
0.098
0.092
0.183
0.136
0.084
0.075
0.077
0.201
**
OK
OK
**
**
OK
OK
**
OK
OK
OK
OK
OK
OK
OK
OK
**
OK
**
OK
OK
OK
OK
OK
OK
OK
OK
*
OK
**
OK
OK
**
**
***
OK
OK
OK
OK
OK
OK
OK
OK
OK
**
OK

-------
                                                APPENDIX  C
APOFID NHOC CONCENTRATION AND HETEROLOGICAL DATA
AVERAGED BY DIURNAL SAMPLING PERIODS
Diurnal Temp.
Jdate minutes kelvins
226
226
227
227
227
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
229
229
229
229
229
230
230
230
230
230
230
230
33510
33690
34950
35490
35580
36390
36390
36390
36570
36570
36750
36750
36750
36930
36930
36930
37380
37380
37380
37020
37020
37020
37830
37830
38010
38820
38460
39270
39270
39450
39630
39810
40260
39900
294.15
295.23
294.15
300.07
296.39
293.65
293.65
293.65
299.23
299.23
302.40
302.40
302.40
302.40
302.40
302.40
296.59
296.59
296.59
298.00
298.00
298.00
295.15
295.15
297.48
295.13
297.20
292.48
292.48
295.65
299.90
300.90
295.28
296.25
Solar Humidity Velocity
Rad. mole Vector
J /m^ fraction m/s Si Uj Pk
232.4
2556.2
464.8
12316.5
3950.6
464.8
464.8
464.8
9992.6
9992.6
20914.8
20914.8
20914.8
13478.4
13478.4
13478.4
1103.8
1103.8
1103.8
6158.2
6158.2
6158.2
232.4
232.4
9992.6
464.8
6477.8
232.4
232.4
7436.4
17010.7
11619.3
813.4
4944.0
0.0147
0.0161
0.0146
0.0252
0.0184
0.0141
0.0141
0.0141
0.0230
0.0230
0.0306
0.0306
0.0306
0.0301
0.0301
0.0301
0.0183
0.0183
0.0183
0.0214
0.0214
0.0214
0.0159
0.0159
0.0203
0.0163
0.0202
0.0126
0.0126
0.0167
0.0247
0.0267
0.0164
0.0183
-0.
-0.
-0.
-0.
-0.
-0.
1826
9415
2175
6132
3081
2206
-0.2206
-0.2206
-0.2311
-0.2311
0.3708
0.3708
0.3708
-0.
-0,
-0
.1484
.1484
.1484
-0.0996
-0
-0
-0
-0
-0
-0
-0
-0
0
-0
-0
-0
0
-0
-0
-0
-0
.0996
.0996
.0785
.0785
.0785
.3677
.3677
.7815
.0249
.4230
.4090
.4090
.1615
.5833
.1639
.4207
.3347
2
2
2
1
1
2
2
2
1
2
1
2
2
1
2
2
2
1
2
2
2
1
1
2
1
1
1
2
2
2
2
2
2
2
2
2
3
3
3
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
6
6
6
6
6
6
6
1
2
1
4
6
1
1
1
2
2
3
3
3
4
4
4
5
5
5
6
6
6
1
1
2
5
6
1
1
2
3
4
5
6
NMOC
ppmC
0.206
0.066
0.056
0.054
0.054
0.405
0.311
0.407
0.110
0.192
0.095
0.065
0.059
0.066
0.050
0.099
0.121
0.113
0.190
0.111
0.198
0.103
0.108
0.116
0.083
0.039
0.067
0.056
0.072
0.064
0.085
0.055
0.149
0.098
Code
OK
OK
OK
**
***
OK
OK
OK
**
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
**
OK
OK
*
***
***
OK
OK
OK
OK
OK
OK
OK
 *   One datum missing in the average.
 **  More than one datum missing in the average.
 *** So many data missing in the average that the statistic
     is probably not useful.

-------
                                 APPENDIX D

              APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
            AVERAGED FOR THE 6:00 a.m.  TO 9:00 a.m.  TIME INTERVAL
jlh.006/cah

-------
                                                APPENDIX D
APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
AVERAGED FOR THE 6:00 a.m. TO 9:00 a.m. TIME INTERVAL
Diurnal Temp.
Jdate minutes kelvins
210
213
208
221
222
220
213
220
230
227
220
230
223
218
218
224
224
208
219
208
219
229
214
229
206
214
217
205
212
226
212
226
205
212
206
216
216
215
228
207
228
228
10470
14790
7590
26310
27750
24870
14790
24870
39270
34950
24870
39270
29190
21990
21990
30630
30630
7590
23430
7590
23430
37830
16230
37830
4710
16230
20550
3270
13350
33510
13350
33510
3270
13350
4710
19110
19110
17670
36390
6150
36390
36390
295.48
297.
15
295.48
291.
289.
290.
297.
290.
292.
294.
290.
292.
290.
298.
07
40
90
15
90
48
15
90
48
07
57
298.57
292.15
292.15
295.48
296.65
295.48
296.65
295,
.15
297.15
295
.15
298.48
297.15
298
.23
298.65
297
294
297
294
298
297
298
295
295
291
293
295
293
.15
.15
.15
.15
.65
.15
.48
.73
.73
.73
.65
.48
.65
293.65
Solar Humidity Velocity
Rad. mole Vector
J/nT2 fraction m/s Si Uj Pk
464.8
0.0
232.4
464.8
0.0
464.8
0.0
464.8
232.4
464.8
464.8
232.4
232.4
697.2
697.2
0.0
0.0
232.4
929.5
232.4
929.5
232.4
232.4
232.4
464.8
232.4
0.0
232.4
232.4
232.4
232.4
232.4
232.4
232.4
464.8
697.2
697.2
464.8
464.8
232.4
464.8
464.8
0.
0161
0.0179
0.
0161
0.0110
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0095
0110
0179
0110
0126
0146
0110
0126
0100
0213
0.0213
0.0123
0.0123
0.0161
0.0183
0.0161
0,
.0183
0.0159
0.0179
0
0
.0159
.0196
0.0179
0
0
0
0
.0205
.0198
.0182
.0147
0.0182
0
0
0
0
0
0
0
0
0
0
0
.0147
.0198
.0182
.0196
.0165
.0165
.0120
.0141
.0158
.0141
.0141
0.0000
0.
0.
-0.
-0.
-0.
0.
-0.
-0.
-0.
-0.
-0.
0000
0000
3709
7382
5564
0000
5564
4090
2175
5564
4090
-0.3749
1.4143
1.4143
-0.3264
-0.3264
0,
.0000
-0.0533
0.0000
-0
.0533
-0.3677
0.9190
-0
.3677
-0.4605
0
2
0
-0
-0
-0
-0
0
-0
-0
0
0
-0
-0
.9190
.6667
.4614
.9355
.1826
.9355
.1826
.4614
.9355
.4605
.8605
.8605
.2224
.2206
-0.3782
-0.2206
-0.2206
1 7
2 3
1 5
2 4
2 5
2 3
2 3
1 3
2 6
2 3
2 3
2 6
2 6
2 1
2 1
2 7
2 7
2 5
1 2
2 5
2 2
1 5
2 4
2 5
2 3
2 4
2 7
2 2
1 2
2 2
2 2
2 2
2 2
2 2
2 3
1 6
2 6
2 5
2 4
2 4
2 4
2 4
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Minimum
Maximum
Average =
Median
Cases
Standard
Deviation
NMOC
ppmC Code
0.032
0.043
0.044
0.046
0.051
0.054
0.054
0.054
0.056
0.056
0.062
0.072
0.074
0.079
0.079
0.080
0.083
0.089
0.094
0.099
0.099
0.108
0.113
0.116
0.117
0.118
0.120
0.153
0.164
0.201
0.204
0.206
0.208
0.208
0.258
0.263
0.269
0.277
0.311
0.386
0.405
0.407
0.0315
0.4070
0.1431
0.1036
42
0.1038

-------
                                 APPENDIX  E

              APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
               AVERAGED FOR  THE  9:00  a.m. TO NOON TIME  INTERVAL
j1h.006/cah

-------
                                                APPENDIX  E
APDFID NMOC CONCENTRATIONS AND HETEROLOGICAL DATA
AVERAGED FOR THE 9:00 a.m. TO NOON TIME INTERVAL
Diurnal
Jdate minutes
220
222
206
218
230
226
220
210
229
208
224
214
228
219
212
208
212
228
216
216
25050
27930
4890
22170
39450
33690
25050
10650
38010
7770
30810
16410
36570
23610
13530
7770
13530
36570
19290
19290
Temp.
kelvins
293.07
289.65
299.15
302.57
295.65
295.23
293.07
300.48
297.48
300.65
293.07
297.90
299.23
300.48
297.73
300.65
297.73
299.23
300.57
300.57
Solar Humidity Velocity
Rad. mole Vector
J/mA2 fraction m/s Si Uj Pk
11154.5
1859.1
9527.8
15105.1
7436.4
2556.2
11154.5
9527.8
9992.6
6971.6
3021.0
5112.5
9992.6
13478.4
10457.4
6971.6
10457.4
9992.6
13013.6
13013.6
0.0138
0.0095
0.0223
0.0303
0.0167
0.0161
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0138
.0228
.0203
.0226
.0130
.0200
.0230
.0257
.0199
.0226
.0199
.0230
.0247
.0247
-0.
-1.
-0.
1.
0.
-0.
-0.
0.
-0.
5099
0973
9767
1478
1615
9415
5099
0000
7815
1.5976
-0.2885
1.8055
-0.2311
0.5823
0.0863
1.5976
0.0863
-0.2311
0
0
.9500
.9500
2
2
2
2
2
2
1
2
1
1
2
2
1
1
2
2
1
2
2
1
3
5
3
1
6
2
3
7
5
5
7
4
4
2
2
5
2
4
6
6
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
NMOC
ppmC Code
0.046
0.052
0.060
0.062
0.064
0.066
0.069
0.081
0.083 *
0.090
0.090
0.110
0.110 **
0.114 **
0.145
0.156
0.182
0.192
0.194
0.342 **
                                                  Minimum =  0.0460
                                                  Maximum -  0.3416
                                                  Average    0.1131
                                                   Median    0.0900
                                                    Cases        20
                                       Standard Deviation    0.0710

-------
                                  APPENDIX F

              APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
               AVERAGED FOR THE NOON  TO  3:00  p.m. TIME  INTERVAL
jlh.006/cah

-------
                                                APPENDIX F
APOFID NMOC CONCENTRATIONS AND HETEROLOGICAL DATA
AVERAGED FOR THE NOON TO 3:00 p.m. TIME INTERVAL
Diurnal
Jdate minutes
218
218
220
205
222
228
211
222
228
206
209
212
230
208
212
228
224
214
208
216
219
22350
22350
25230
3630
28110
36750
12270
28110
36750
5070
9390
13710
39630
7950
13710
36750
30990
16590
7950
19470
23790
Temp.
kelvins
305.07
305.07
295.65
305.48
290.23
302.40
299.15
290.23
302.40
301.98
303.65
300.73
299.90
301.32
300.73
32.40
294.65
299.23
301.32
307.07
304.23
Solar
Rad.
Humidity Velocity
mole Vector
J/m~2 fraction
27886.
27886.
15105.
27189.
4415.
20914.
4
4
1
2
3
8
25330.1
4415.3
20914.8
21611.9
23238.6
18590.9
17010
17429
18590
20914
7668
16964
17429
26259
24865
.7
.0
.9
.8
.7
.2
.0
.7
.3
0.
0.
0.
0.
0364
0364
0174
0376
0.0103
0.0306
0.
0.
0,
.0230
.0103
.0306
0.0295
0.0303
0
0
0
0
0
0
0
0
0

.0258
.0247
.0261
.0258
.0306
.0154
.0236
.0261
.0411

m/s
0.
0.
-0.
0.
-0.
0.
-1.
-0.
0.
8648
8648
6372
7016
9099
3708
7583
.9099
.3708
-0.8660
0,
.0863
0.8976
-0.5833
1
0
0
-0
1
1
1
1
.9414
.8976
.3708
.3040
.1248
.9414
.0266
.0135
Si Uj Pk
1 1
2 1
1 3
1 2
2 5
2 4
1 1
1 5
2 4
2 3
1 6
2 2
2 6
1 5
1 2
1 4
2 7
2 4
2 5
2 6
1 2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
Minimum
Maximum
Average


















Median
Cases


Standard Deviation
NMOC
ppmC Code
0.046
0.048
0.051
0.056 *
0.059
0.059
0.060 *
0.062
0.065
0.077
0.078 **
0.079
0.085
0.086
0.094
0.095
0.098
0.103
0.119
0.129
0.241 **
0.0480
0.2410
0.0852
0.0776
21
0.0425

-------
                                  APPENDIX  G

              APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
            AVERAGED FOR THE 3:00 p.m. TO 6:00 p.m. TIME INTERVAL
j1h.006/cah

-------
                                                APPENDIX G
APDF1D NMOC CONCENTRATIONS AND HETEROLOGICAL DATA
AVERAGED FOR THE 3:00 p.m. TO 6:00 p.m. TIME INTERVAL
Diurnal
Jdate minutes
218
220
228
218
211
227
230
220
223
212
214
205
228
222
207
210
206
209
225
224
228
216
208
219
212
222
215
22530
25410
36930
22530
12450
35490
39810
25410
29730
13890
16770
3810
36930
28290
6690
11010
5250
9570
32610
31170
36930
19650
8130
23970
13890
28290
18210
Temp.
kelvins
305.90
295.32
302.40
305.90
299.98
300.07
300.90
295.32
292.65
302.98
297.57
307.15
302.40
290.90
305.48
299.82
304.48
305.15
301.48
296.40
302.40
307.73
301.65
304.48
302.98
290.90
303.23
Solar
Rad.
Humidity Velocity
mole Vector
J/irT2 fraction
24633.
9760.
13478.
24633.
18126.
12316.
0
2
4
0
1
5
11619.3
9760.2
4647.7
18126.1
10225.0
26724.4
13478.4
3253.4
15569
16499
25330
23935
21611
8365
13478
23238
21147
16499
18126
3253
23145
.9
.4
.1
.8
.9
.9
.4
.6
.2
.4
.1
.4
.7
0.
0.
0.
0.
0.
0.
0.
0.
0396
0170
0301
0396
0258
0252
0267
0170
0.0129
0.0317
0.
,0205
0.0427
0.0301
0.0114
0.0376
0
0
0
0
0
0
0
0
0
0
0
0
.0248
.0352
.0353
.0288
.0181
.0301
.0446
.0290
.0356
.0317
.0114
.0323
m/s Si Wj Pk
1.
-0.
-0.
1.
-0.
-0.
0421
9034
1484
0421
3636
6132
-0.1639
-0.9034
-0.
.2079
0.8624
0.9134
0,
.9866
-0.1484
-0
-0
-2
-1
1
-1
-0
-0
1
2
0
0
-0
2
.7696
.5761
.1705
.2416
.1855
.3764
.3353
.1484
.8643
.3058
.6210
.8624
.7696
.5417
1 1
2 3
2 4
2 1
1 1
1 3
2 6
1 3
1 6
1 2
2 4
1 2
1 4
2 5
1 4
2 7
2 3
1 6
1 1
2 7
2 4
2 6
2 5
1 2
2 2
1 5
1 5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
Minimum
Maximum =
Average =
Median -









Cases

Standard Deviation =
NMOC
ppmC Code
0.030
0.049
0.050
0.053
0.053
0.054 **
0.055
0.057
0.057 **
0.058
0.064
0.066
0.066
0.067
0.067
0.070
0.080
0.080
0.084
0.092
0.099
0.099
0.104
0.115
0.120
0.122
0.661
0.0304
0.6610
0.0953
0.0670
27
0.1155

-------
                                  APPENDIX H

              APDFID NMOC CONCENTRATIONS AND METEROL06ICAL DATA
            AVERAGED FOR THE 6:00 p.m. TO 6:00 a.m. TIME INTERVAL
jlh.006/cah

-------
                                              APPENDIX  H
APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
AVERAGED FOR THE 6:00 p.m. TO 6:00 a.m. TIME INTERVAL
==========================================================================
                             Solar  Humidity Velocity
                             Rad.     mole    Vector            NMOC
                             J/m^2  fraction    m/s   Si Wj Pk  ppmC  Code
Jdate
Diurnal   Temp.
minutes  kelvins
229
222
223
205
211
225
219
222
212
209
228
207
218
220
228
230
213
224
220
228
218
216
212
208
210
214
215
206
204
38820
28740
30180
4260
12900
33060
24420
28740
14340
10020
37380
7140
22980
25860
37380
40260
15780
31620
25860
37380
22980
20100
14340
8580
11460
17220
18660
5700
2820
295.
289.
292.
300.
299.
296.
13
57
00
98
15
59
296.42
289.57
299.30
300.67
296.59
299.21
301.03
293.28
296.59
295
298
293
293
296
301
302
299
298
295
294
300
299
301
.28
.34
.42
.28
.59
.03
.23
.30
.53
.50
.73
.55
.65
.38
464.8
232.4
348.6
2962.9
1917.2
1742.9
1626.7
232.4
1510.5
2323.9
1103.8
2033.4
2091.5
1103.8
1103.8
813.4
755.3
464.8
1103.8
1103.8
2091.5
1801.0
1510.5
987.6
2091.5
1336.2
1917.2
2672.4
2091.5
0.
0.
0.
0.
0.
0.
0.
0163
0099
0122
0250
0221
0186
0189
0.0099
0.0236
0.
.0250
0.0183
0.0232
0,
.0270
0.0137
0.0183
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0164
.0209
.0138
.0137
.0183
.0270
.0292
.0236
.0216
.0169
.0155
.0253
.0231
.0266
0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
0249
5538
3124
2715
0432
5660
2285
5538
2038
0.3009
-0.0996
0.3836
0.2306
-0.4006
-0.0996
-0.4207
0.1869
-0
-0
-0
0
2
-0
1
-1
-0
0
-1
0
.2731
.4006
.0996
.2306
.4129
.2038
.6190
.8267
.0492
.9931
.1585
.2606
1 5
1 5
1 6
1 2
1 1
1 1
1 2
2 5
1 2
1 6
1 4
1 4
1 1
1 3
2 4
2 6
1 3
2 7
2 3
2 4
2 1
2 6
2 2
2 5
2 7
2 4
1 5
2 3
2 1
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Mimimum
Maximum -
Average =
Median









Cases
=
Standard Deviation =
0.039 ***
0.051 *
0.052 **
0.071
0.075
0.075
0.080
0.083
0.086 **
0.092
0.113
0.117
0.119
0.121 **
0.121
0.149
0.165 **
0.183
0.183
0.190
0.194
0.214
0.220
0.241
0.293
0.312
0.429
0.528
0.562
0.0387
0.5620
0.1779
0.1210
29
0.1348

-------
                                 APPENDIX I

              APDFID NMOC CONCENTRATIONS AND METEROLOGICAL DATA
            AVERAGED FOR THE 6:00 a.m.  TO 6:00 a.m.  TIME INTERVAL
jlh.006/cah

-------
                                                APPENDIX I
APDFID NMOC CONCENTRATIONS AND HETEROLOGICAL DATA
AVERAGED FOR THE 6:00 a.m. TO 6:00 a.m. TIME INTERVAL
Solar Hunidity Velocity
Diurnal Temp. Rad. mole Vector
Jdate minutes
210
223
227
222
222
229
205
211
208
220
225
220
209
218
218
219
230
228
207
212
228
210
224
212
213
208
214
228
216
206
216
215
204
11100
29820
35580
28380
28380
38460
3900
12540
8220
25500
32700
25500
9660
22620
22620
24060
39900
37020
6780
13980
37020
11100
31260
13980
15420
8220
16860
37020
19740
5340
19740
18300
2460
kelvins
297.
291.
296.
289.
289.
297.
301.
297.
51
68
39
81
81
20
86
65
299.15
293.50
296.90
293.50
300.86
302.03
302.03
298.94
296.25
298.00
300.18
299.47
298.00
297.51
293
299
298
299
296
298
302
300
302
299
300
.74
.47
.36
.15
.35
.00
.50
.34
.50
.33
.44
J/m^Z fraction
5838.7
1510.5
3950.6
1307.2
1307.2
6477.8
9760.2
7523.5
6216.3
5112.5
7349.2
5112.5
8772.6
9585.9
9585.9
7784.9
4944.0
6158.2
6652.1
6681.1
6158.2
5838.7
2614.3
6681.1
4066.8
6216.3
4734.9
6158.2
8801.6
8453.1
8801.6
8499.5
8700.0
0.
0.
0.
0.
0197
0118
0184
0100
0.0100
0.
0.
0.
0.
0202
0280
0207
0225
0.0143
0.0195
0.
.0143
0.0262
0.0294
0.0294
0.0237
0.0183
0.0214
0.0254
0.0237
0.0214
0.0197
0
0
0
0
0
0
0
0
0
0
0
.0143
.0237
.0207
.0225
.0180
.0214
.0305
.0249
.0305
.0239
.0254
m/s Si Uj Pk
-1.3403
-0.3063
-0.3081
-0.7163
-0.7163
-0.4230
0.1750
-0.6951
1.5401
-0.5262
-0.6933
-0.5262
0.6063
0.6739
0.6739
0.1562
-0.3347
-0.0785
0.1845
0.0119
-0.0785
-1.3403
-0.2933
0.0119
-0.0518
1.5401
0.5707
-0.0785
1.7941
-1.0224
1.7941
0.9856
0.1735
1 7
1 6
1 3
2 5
1 5
1 5
1 2
1 1
1 5
1 3
1 1
2 3
1 6
1 1
2 1
1 2
2 6
1 4
1 4
1 2
2 4
2 7
2 7
2 2
1 3
2 5
2 4
2 4
2 6
2 3
1 6
1 5
2 1
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
Minimum -
Maximum =
Average
















Median
Cases

=
Standard Deviation
NMOC

ppmC Code
0.032 ***
0.052 ***
0.054 ***
0.059

0.066 **
0.067 ***
0.068
0.069
0.073
0.074
0.077
0.085
0.089
0.092
0.097
0.097
0.098
0.103
0.107
0.110
0.111
0.127
0.136
0.137
0.165
0.172
0.196
0.198
0.204
0.226
0.282
0.475
0.478
0.0315
0.4780
0.1356
0.0980
33
0.1048
**
**
**
**
**

**
**

**

**
**
**




***





***
**








-------