-------
Table 1: Concentrations of contaminants
EC Dust and Soil/Sediment
range average
EC Dust (ppm)
Cadmium 217 - 956
Lead 7520 - 27,600
Zinc 55,200 - 242,000
449
15,384
129,200
Soil/Sediment (ppm)
Cadmium 2 - 380
Lead 4 - 17,000
Zinc 32 - 110,000
PCBs 1 - 1,100
82
1,391
27,922
37
Volume of Contaminants (estimated):
EC dust and soil/sediment contaminated
with metals and low level PCBs 26,000 cubic yards
Soil/sediment contaminated with PCBs
above 50 ppm 600 cubic yards
PCB incinerator ash contaminated with
metals 10,700 cubic yards
5.4 Groundwater Contamination
During the Phase I Remedial Investigation, groundwater samples
from two wells were analyzed for the CLP/HSL constituents. The
wells were M-50, near the center of the plume, and M-20,
downgradient from the scrapyard. The CLP/HSL analyses identified
the same contaminants of concern in groundwater for which
monitoring has been performed since November 1985. The Consent
Agreement of September 1985 between FDER and FSC provided for
semi-annual sampling for these parameters until June 1990, at
which time samples were collected and analyzed annually. Because
PCBs have never been detected in the monitoring wells, analyses
for this parameter are presently performed annually. The
location of the 24 existing permanent wells are shown on Figure
12.
A groundwater plume extends south from the vicinity of the brine
discharge from the plant's former water softener to a distance of
approximately 600 feet beyond the southern property line. The
plume extends to a depth of approximately 35-40 feet. The extent
-21-
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LEGEND
LOCATION Of MONITOHIN* Wtll»
LOCATION Ot OICOUHIMIONIO UONITONINO OfLL*
/-10— |M a«-a CONDUCTIVITY CONTOUH fO«
(CONDUCTIVITY IN MILLIMHOt/MITINt
O LOCATION Of NIW MOMTONINO WILL*
LOCATION or raoouCTKm wtu*
ttM'ACf WAT1K MIMIM rOMT
•OHIBO
IM7
LOCATION OF GROUNDWATER MONITORING WELLS AND
EM 34 CONDUCTIVITY CONTOURS _,
-------
of the plume has been defined by. analytical data and
electromagnetic geophysical surveys. Water quality in the plume
is characterized by elevated concentrations of the following
parameters:
Table 2: Groundwater contaminant concentrations
Contaminant
Range
Average
Cadmium ( ppb )
Lead ( ppb )
Zinc (ppm)
Radium 226 (pCi/L)
228
1
7
.11 -
1
38
742
13
91
12
50
3
25
3
.6
Estimated volume of contaminated groundwater: 365 million gallons
Several uncertainties exist with regard to the radium detected in
the groundwater. Radium-228 was measured in concentrations
substantially less than the radium-226. However, its source is
uncertain given its short half-life. Another uncertainty is the
mechanism that resulted in the elevated radium-226 concentrations
in groundwater.
Two related theories may explain the occurrence of elevated
radium levels and subsequently high gross alpha levels. First,
leaching tests with a sodium chloride solution performed on
native soil, EC dust, lime and slag indicate that the presence of
dissolved radium in the ground water plume could be a result of
the dissolved sodium chloride causing naturally occurring radium
to leach from the soil. Secondly, it is possible that naturally
occurring radium in the groundwater withdrawn by the former
production well was concentrated by cation exchange with the
column resin in the water
softener.
5.5 Surface Water Contamination
During the Phase I Remedial Investigation, a surface water sample
was collected at the only point where the off-site flow from the
property intermittently occurs, a drainage ditch on the southwest
border of the property. The sample was collected in August
because there was no off-site surface water flow when the soil
and groundwater samples were collected in May.
Class M surface water standards for zinc and iron were exceeded.
Volatile, acid or base neutral extractable organics, pesticides,
or PCBs were not detected in the sample.
During Phase II, additional surface water samples were collected
from on-site and off-site locations. Lead was detected in one
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sample, collected on-site from the "polishing pond." The
concentration of lead/ 31 ppb, was above existing Florida surface
water standards. Other surface water samples, collected from
private and county maintained drainage ditches, had lower lead
concentrations that decreased to a level of 8 ppb at a point near
the St. Lucie Canal.
Zinc exceeded surface water standards in three out of the seven
Phase II surface water samples. The highest zinc concentration
in the on-site samples -was 155 ppb; the highest zinc
concentration in off-site surface water samples was 45 ppb.
5.6 Potential Routes of Contaminant Migration
Groundwater is a migration route from the site. Groundwater at
depths of approximately 30 feet or more is reportedly used for
drinking water at some residences about 1/2 mile from the site.
Metals have been detected in surface water in the borrow pit.
However, surface water samples taken from the borrow pit were
either at or slightly above existing standards. Metals were
detected in surface water in drainage ditches south of the site.
The metals concentrations decreased with increasing distance from
the site.
Surface water runoff from the contaminated soil at the Site can
contain metals and is one migration route from the site. On-site
actions are expected to reduce metals concentrations in the
runoff.
Runoff from the site does provide some water to seasonal wetlands
located south/southwest of the site.
6.0 SUMMARY OF SITE RISKS
CERCLA directs that EPA must protect human health and the
environment from current and potential exposure to hazardous
substances at Superfund sites. In order to assess the current
and potential future risks for the Florida Steel Site, a risk
assessment was conducted. This section summarizes the findings
concerning the risks from exposure to soil and groundwater at the
Site. However, the treatment and disposal of contaminated
groundwater will be addressed in the second operable unit for
this Site.
6.1 Identification of Contaminants of Concern
At this Site the contaminants of concern in soil are cadmium,
chromium, lead, zinc, and PCBs. These contaminants are present
in site soils because of the on-site disposal of EC dust and from
leaks of hydraulic fluid containing PCBs. The contaminants of
concern in groundwater are cadmium, lead, and radium-226 and 228.
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The presence of metals in groundwater is due to the leaching of
metals from the soil and EC dust; therefore, soil cleanup levels
have been developed for the protection of groundwater. The
presence of radium in groundwater may be due to the discharge
from a water softening system which may have increased leaching
from native soils. Table 4 provides the reasonable maximum
exposure concentrations for the contaminants of concern.
6.2 Exposure Assessment Summary
Exposure pathways are identified which consist of four elements:
1) a source and mechanism of chemical release to the environment,
2) an environmental transport media (e.g., air, ground water,
surface water) for the release chemical, 3) a point of potential
human contact with the contaminated medium (referred to as an
exposure point), and 4) a human exposure route (e.g., drinking
water). Each pathway therefore describes a particular route by
which a. population or individual may be exposed to contaminants
originating from a site. Once the exposure pathways have been
identified and adequately described, receptor populations can be
identified, exposure point concentrations determined, doses and
intakes can be calculated, and any uncertainties can be
described.
The potential exposure pathways considered for the FSC site under
the no-action scenario for present and future land use are:
1) Dermal contact and ingestion of contaminated soil by
industrial workers under current and* future use conditions at the
site.
2) Non-potable use of groundwater, such as hand washing, for
future conditions at the site.
3) Residential drinking water, residential bathing and showering
at nearby off-site locations in the future if contaminated
groundwater was not treated.
Residential uses of the site were not evaluated in the risk
assessment. Deed restrictions on the use of the site have been
filed with the Martin County Clerk of Circuit Court. The deed
restrictions limit use of the site to mostly industrial or
commercial activities. The restrictions are already in effect
and will remain in effect regardless of the cleanup activities
that occur.
In addition, a coal fired power plant is to be built on adjoining
property southwest of the site. A 500-KV electric power line
will likely be erected across the western portion of the site.
Given these conditions, the existing zoning laws, and the deed
restrictions, future residential use of the site is not
anticipated.
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Exposure to contaminated sediment and surface water was not
evaluated because the.chance of exposure is very low at the site.
The site is located in a relatively isolated area and a fence
around the site limits the access of people who pass by.
The nearest downgradient potable well is over 1,400 feet from the
plume's boundary and is currently not impacted by the
contamination plume. Therefore, exposure to groundwater under
current conditions is not quantitatively assessed. No potable or
non-potable wells are currently in use on the site and
consequently are not assessed under the current use scenario.
With respect to future use, the locations of water supply wells
downgradient from the site are shown on Figure 9. Private and
commercial downgradient wells are reported to range in depth from
30 to 100 feet below land surface. The nearest well is more than
1,400 feet from the downgradient edge of the contaminated
groundwater plume. Groundwater samples were collected from the
two domestic wells nearest the site during the June 1987
sampling. One well is reported to be 104 feet deep and the other
well is over 100 feet deep. Concentrations of cadmium, chloride,
iron, lead, sodium, total dissolved solids, and gross alpha were
at background levels in the two domestic wells.
Given an average flow velocity of 40 feet/year and a distance of
approximately 1400 feet from the edge of the contaminated
groundwater plume to the nearest residential well, it would take
about 35 years for the plume to reach the nearest well.
Inhalation of contaminants volatilizing from the surface soil,
sediment in drainage ditches or other surface waters is not
considered to be significant at the FSC site due to the low
volume of the only contaminant, PCBs, which could potentially
volatilize.
Air sampling was conducted in the EC dust area on two consecutive
days during the Phase I investigation. The sampler was placed
immediately downwind of Area B. Wind speed varied from calm to
very windy during the 9 hour collection period on May 26, 1988
and varied from calm to breezy during the 12-hour collection
period on May 27, 1988. The results of the analyses and the OSHA
permissible exposure limits are presented in the following table:
Table 3:
Air Sampling Results (units expressed in mg/m3)
Analyte
Lead
Cadmium
Chromium
May 26, 1988
0.290
0.011
0.008
May 27,1988
0.040
0.002
0.003
8 hr. Occupational
Limits
30
200
NA
-26-
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The groundwater concentrations used in calculations of chemical
intakes were based on the 95% upper confidence limit (UCL) of
measured concentrations from the wells most strongly influenced
by the high total dissolved solids (TDS) plume. Flow from the
current plume boundary to potential receptors has been assumed to
follow a plug flow pattern with no attenuation or dilution.
Several assumptions and constants used to evaluate the exposure
and calculate site risk are presented in Appendix C.
6.3 Toxicity Assessment
To assess the possible toxicological effects from exposure,
health effects criteria are derived from a review of health and
environmental standards and published toxicological studies.
For risk assessment purposes, individual pollutants are separated
into two categories of chemical toxicity, depending on whether
they exhibit carcinogenic or nonearcinogenic effects.
Cancer potency factors(CPFs) have been developed by EPA's
Carcinogenic Assessment Group for estimating excess lifetime
cancer risks associated with exposure to potentially carcinogenic
chemicals. CPFs, which are expressed in units of (mg/kg-day)'1,
are multiplied by the estimated intake of a potential carcinogen,
in mg/kg-day, to provide an upper-bound estimate of the excess
lifetime cancer risk associated with exposure at that intake
level. The term "upper bound" reflects the conservative estimate
of the risks calculated from the CPF. Use of this approach make
underestimation of the actual cancer risk highly unlikely.
Cancer potency factors are derived from the results of human
epidemiological studies or chronic animal bioassays to which
animal-to-human extrapolation and uncertainty factors have been
applied.
Reference doses (RfDs) have been developed by EPA for indicating
.the potential for adverse health effects from exposure to
chemicals exhibiting nonearcinogenic effects. RfDs, which are
expressed in units of mg/kg-day, are estimates of lifetime daily
exposure levels for humans, including sensitive individuals, that
is not likely to be without an appreciable risk of adverse health
effects. Estimated intakes of chemicals from environmental media
(e.g., the amount of a chemical ingested from contaminated
drinking water) can be compared to the RfD. RfDs are derived
from human epidemiological studies or animal studies to which
uncertainty factors have been applied. Uncertainty factors are
used to account for the use of animal data to predict effects on
humans. These uncertainty factors help ensure that the RfDs will
not underestimate the potential for adverse noncarcinogenic
effects to occur.
-27-
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The applicable RfDs and CPFs are:
RfDs (mg/kg/day) CPFs (mg/kg/day)-l
Cadmium
Chromium
Chromium
Lead
Zinc
(III)
(VI) .
5
1
5
4
2
x 10-"
x 10°
x 10'3
.28 x 10'4 **
x 10'1
PCBs 7 . 7
**No cancer potency factor or reference dose has been determined
by EPA. The reference dose noted above was presented in the risk
assessment for comparative purposes only and was derived using
EPA's action level of 15 ppb for lead in drinking water.
6.4 Summary of Baseline Risk Characterization
A characterization of risk was performed in the risk assessment
to address potential risk and hazards to human health posed by
the Site in the absence of remedial action. The risk
characterization is based on identifying potential chemicals of
concern and developing exposure scenarios for each of the
potential and future exposure pathways.
Excess lifetime cancer risks are determined by multiplying the
intake level with the cancer potency factor. These risks are
probabilities that are generally expressed in scientific notation
(e.g., lxlO~6 or IE'6). An excess lifetime cancer risk of 1x10"6
indicates that, as a plausible upper bound, an individual has a
one in one million chance of developing cancer as a result of
site-related exposure to a carcinogen over a 70-year lifetime
under the specific exposure conditions at a site.
Potential concern for non-carcinogenic effects of a single
contaminant in a single medium is expressed as the hazard
quotient (HQ) or the ratio of the estimated intake derived from
the contaminant concentration in a given medium to the
contaminant's reference dose. By adding the HQs for all
contaminants within a medium or across all media to which a given
population may reasonably be exposed, the Hazard Index (HI) can
be generated. The HI provides a useful reference point for
gauging the potential significance of multiple contaminant
exposures within a single medium or across media.
This risk associated with the various exposure pathways is
summarized in Table 4. A range of 95% UCL concentrations in soil
and groundwater is often presented because subsections of the
site were each evaluated for their contribution to the risk.
However, the risk or hazard index values presented in the tables
represent a total site risk for each contaminant for each
exposure pathway.
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Table 4 shows that pathways which indicate the greatest concern
are dermal contact and incidental ingestion of soils and future
ingestion of the groundwater. The chemicals which drive the risk
in the soil related pathways are lead and PCBs. Lead drives the
risk in the groundwater pathway.
Cleanup levels were derived for those scenarios which, based on
the quantitative risk assessment, may adversely impact the health
of exposed individuals. The exposure pathways which were
evaluated and determined to pose either potential carcinogenic
risks greater than 10~6 and/or a hazard index exceeding one are
listed below:
1) Dermal contact and ingestion of contaminated soil by
industrial workers under current and future use conditions at the
site.
2) Ingestion of contaminated water at nearby off-site locations
in the future if contaminated groundwater was not treated.
Of the most toxic metals on-site, lead is present in the highest
concentrations. In addition, the highest potential risk is
associated with ingestion of contaminated groundwater.
Therefore, it is appropriate to base the final soil cleanup level
upon the soil lead concentration that would be protective of
groundwater. The soil lead cleanup level, 600 ppm, was
determined to be the level that would ensure that the underlying
groundwater would contain no more than 15 ppb of lead, and would
thus be protective of future residents drinking groundwater.
-29-
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Table 4: Summary of Baseline Risk
Current and Future Use Industrial Scenario Noncarcinogenic Risk
Soil Ingestion
Contaminant Range of 95% UCL
Exposure concentrations
Cadmium 8 - 482
Chromium 294 - 1,460
Lead 43 - 9,760
Zinc 4090 -• 134,000
TOTAL HAZARD INDEX FOR PATHWAY
Range of Chronic
(ppm) Daily Intake Values
(mg/kg/day)
3.6x10-6/1.1x10-4
6.9x10-5/1.2x10-4
1.0x10-5/2.3x10-3
9.6x10-4/3.1x10-2
Reference Dose
(mg/kg/day)
5x10-4
1x10°
4.28x10-4*
2.0x10-1
HQ
• .12
.0007
6.9
7.18
*Reference dose for lead was calculated for comparison purposes only.
EPA reference dose.
It is not an appn
Current and Future Use Industrial Scenario Noncarcinogenic Risk
Soil Dermal Contact
Contaminant Range of 95% UCL
Exposure concentrations
Cadmium 8 - 482
Chromium 294 - 1,460
Lead 43 - 9,760
Zinc 4090 - 134,000
TOTAL HAZARD INDEX FOR PATHWAY
Range of Chronic
(ppm) Daily Intake Values
(mg/kg/day)
6.6x10-7/3.9x10-5
2.3x10-5/1.2x10-4
4.4x10-6/7.8x10-4
1.6x10-3/5.3x10-2
Reference Dose
(mg/kg/day)
1x10-3
1x10°
4.28x10-4 2
2.0x10-1
2
HQ
.04
.0002
.3
^05.
.39
-30-
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Table 4: Summary of Baseline Risk (cont.)
Future Use Industrial Scenario Noncarcinogenic Risk
On-site Dermal Contact with Groundwater (handwashing)
Contaminant 95% UCL Exposure
Concentrations (ppm)
Cadmium 20
Lead 80
TOTAL HAZARD INDEX FOR PATHWAY
Chronic Daily
Intake Values
(mg/kg/day)
2.8x10-8
1.1x10-7
Reference Dose
(mg/kg/day)
5x10-4
4.28x10-4*
HQ
.0001
.0003
.0004
Future Ingestion of groundwater by nearby residential adult and child, Noncarcinogenic Risk
Contaminant 95% UCL Exposure
Concentrations (ppm)
Child
Cadmium 20
Lead 80
TOTAL HAZARD INDEX FOR CHILD PATHWAY
Adult
Cadmium 20
Lead 80
TOTAL HAZARD INDEX FOR ADULT PATHWAY
TOTAL HAZARD INDEX FOR PATHWAY
Chronic Daily
Intake Values
(mg/kg/day)
1.2x10-3
4.7x10-3
5.7x10-4
2.3x10-3
Reference Dose
(mg/kg/day)
5x10-4
4.28x10-4*
5x10-4
4.28x10-4*
HQ
2.4
11.0
13.4
1.1
5^4
6.5
19.9
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Table 4: Summary of Baseline Risk (cont.)
Current and Future Use Industrial Scenario Carcinogenic Risk
Soil Ingestion
Contaminant Range of 95% UCL
Exposure concentrations
(ppm)
PCS 1248
PCB 1254
8.0 - 16
.78 - 5.3
TOTAL RISK FOR PATHWAY
Range of Lifetime
Avg. Daily Dose
(mg/kg/day)
1.2x10-6/3.7x10-6
1.0x10-7/2.2x10-6
Cancer Potency
Factor (mg/kg/day)-1
Risk
7.7
7.7
3.-67x10-5
6.3x10-6
4.3x10-5
Current and Future Use Industrial Scenario Carcinogenic Risk
Dermal Contact with Soil
Contaminant Range of 95% UCL
Exposure concentrations
(ppm)
PCB 1248
PCB 1254
8.0 - 16
.78 - 5.3
TOTAL RISK FOR PATHWAY
Range of Lifetime
Avg. Daily Dose
(mg/kg/day)
1.9x10-6/3.7x10-6
1.2x10-6/1.8x10-7
Cancer Potency
Factor (mg/kg/day)-l
7.7
7.7
Risk
6.2x10-5
1.1X10-5
7.3x10-5
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Table 4: Summary of Baseline Risk (cont.)
Future Ingestion of Groundwater; Nearby Residential Carcinogenic Risk
Contaminant Average Exposure
Concentrations (pCi/L)
Radium 226 24.6
Radium 228 2.9
TOTAL RISK FOR PATHWAY
Lifetime Dose
(pCi/lifetime)
538,740
63,510
Cancer Slope
Factor (pCi/l)-l
1.0x10-10
1.2x10-10
•
Risk
6x10-6
6.5x10-5
7.1x10-5
Current and Future Industrial Scenario Carcinogenic Risk
Dermal contact with groundwater (handwashing)
Contaminant
Average Exposure
Concentrations (pCi/L)
Radium 226 24.6
Radium 228 2.9
TOTAL RISK FOR PATHWAY
Lifetime Dose
(pCi/lifetime)
34.9
4.1
Cancer Slope Risk
Factor (pCi/l)-l
1.0x10-10 4.1x10-10
1.2x10-10 4.6x10-9
5.0x10-9
Future Use Nearby Residential Carcinogenic Risk
Dermal contact with groundwater (bathing)
Contaminant
Radium 226
Radium 228
Average Exposure
Concentrations (pCi/L)
24.6
2.9
Lifetime Dose
(pCi/lifetime)
1212
143
Cancer Slope
Factor (pCi/l)-l
1.0x10-10
1.2x10-10
TOTAL RISK FOR PATHWAY
Risk
1.4x10-8
1.5x10-7
1.6x10-7
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6.5 Environmental Risks
To date, no endangered or threatened species or associated
habitats have been identified on-site.
Site contaminants have been detected at low levels in surface
water from a retention pond on-site. Fish are present in the
pond; ducks and other birds have been seen occasionally at the
pond. The pond received some runoff from a portion of the
contaminated areas of the site.
Site contaminants have been detected in the sediment and surface
water of seasonally flooded wetlands adjacent to the site. On-
site cleanup of contaminated soil is expected to reduce the
metals levels in surface water runoff and ultimately improve
surface water quality in the on-site pond and the off-site
wetlands. Sampling will be required to document changes in
surface water quality. Contaminated wetland sediment and
contaminated groundwater will be evaluated in a second operable
unit.
6.6 Risk Uncertainty
There is a generally recognized uncertainty in human risk values
developed from experimental data. This is primarily due to the
uncertainty of extrapolation in the areas of (1) high to low dose
exposure and (2) animal data to values that are protective of
human health. The site specific uncertainty is mainly in the
degree of accuracy of the exposure assumptions. Most of the
exposure assumptions used in this and any risk assessment have
not been fully verified. For example, the degree of chemical
absorption from the gut or through the skin or the amount of soil
contact that may occur is not known with certainty. Generally
accepted default values provided in Agency guidance were used
when available.
In the presence of such uncertainty, the Agency and the risk
assessor have the obligation to make conservative assumptions
such that the chance is very small, approaching zero, for the
actual health risk to be greater than that determined through the
risk assessment process. On the other hand, the process is not
intended to yield absurdly conservative risks values that have no
basis in reality. That balance was kept in mind in the
development of exposure assumptions and pathways and in the
interpretation of data and guidance for this baseline risk
assessment.
For this site-specific risk assessment, a quantified risk
analysis for the trespasser exposure scenario was not conducted.
The risk to a trespasser was deemed to be negligible at the
Florida Steel Site compared to the risk to current and future
workers because it is an industrial site in an isolated area
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(that is zoned industrial) and the site is completely fenced. In
addition, the risk assessment was first submitted in November
1989 which was prior to the release of EPA's present guidance
which recommends that this pathway be quantified in the risk
assessment.
6.7 Risk Conclusion
Actual or threatened releases of hazardous substances from this
site, if not addressed by implementing the response action
selected in this ROD, may present an imminent and substantial
endangerment to public health, welfare, or the environment.
The exposures that are of greatest concern are dermal contact and
incidental ingestion of soils and future ingestion of the
groundwater. The chemicals which drive the risk for the soil
related exposures are lead and PCBs. Lead drives the risk for
the groundwater exposure.
7.0 SUMMARY OF ALTERNATIVES
The remedial alternatives developed in the FS report for this
site are divided into two groups: 1) treatment for PCB
contaminated soils and sediment; and 2) treatment for EC dust
and metal contaminated soils or sediment. This section of the
ROD presents a summary of each of the alternatives.
ALTERNATIVES FOR PCB CONTAMINATED SOIL
Alternative 1-P: No Action
Capital Costs: $ None
O&M Costs: None
Total Present Worth: None
The Superfund program requires the "No Action" Alternative to be
evaluated at every site to serve as a baseline for comparison
with the other alternatives. Under this alternative, no further
action would be taken to minimize the impact of site
contaminants.
Alternative 2-P: Excavation, Off-site disposal; On-site
Solidification/disposal
Capital Costs: $ 306,750
O&M Costs: None
Total Present Worth: $ 306,750
Time to Complete: Six months
Under this alternative, PCB contaminated soils would be addressed
by two different methods. For soil with PCB levels greater than
50 ppm, the soil would be excavated and shipped off-site to a
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RCRA/TSCA approvecl disposal facility. For soil with PCB levels
between 25 and 50 ppm, the contaminated soil would be solidified
and placed in the on-site landfill with the metal contaminated
soil. Excavation would continue until the cleanup goals are met
or the water table is encountered. The excavated areas would be
graded and grass*ed.
The soil with PCB concentrations above 50 ppm also contains
metals. Any necessary treatment will be dependent upon the
chosen disposal facility. Treatment is not expected to
significantly increase overall site cleanup costs because of the
small estimated volume of affected soil (600 cubic yards).
ALTERNATIVES FOR EC DUST, LEAD CONTAMINATED SOIL, SEDIMENT, AND
ASH
Alternative 1-S: No Action
Capital Costs: $12,000
O&M Costs: $25,000/year for 30 years
Total Present Worth: $345,000
No further action would be taken to minimize the impact of site
contaminants. Monitoring of air and groundwater quality would be
conducted for up to 30 years to document changing site conditions.
Alternative 2-S: Excavation, Off-site
Treatment and Disposal
Capital Costs: $20,990,000
O&M Costs: $12,800/year for 30 years
Total Present Worth: $21,160,000
Time to complete: 15 months
This alternative involves excavation of residual EC dust, soil with
lead levels above 600 ppm, and slag with total lead levels above
1360 ppm or above the Toxicity Characteristic Leaching Procedure
(TCLP) standards noted on page 38. The lead level of 1360 ppm was
derived in the risk assessment as an allowable value for direct
contact in an industrial setting. In addition, incinerator ash
would be removed from its current location in a covered building
on-site. All material described above would be shipped to an EPA
approved High Temperature Metal Recovery facility for treatment
and disposal. This process heats the contaminated material to a
temperature high enough to volatilize the individual metals which
are collected in baghouses. Zinc can usually be collected in
sufficient quantities for recycling.
The excavated area would be graded and grassed. Surface water
runoff from the site would be retained on-site until remedial
activities were complete and surface water quality was sufficient
to allow a flow off site. Groundwater quality would be monitored
for up to 30 years.
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Alternative 3-S: Excavation, On-site solidification and
disposal in an on-site Double Lined RCRA Landfill with RCRA cap
Capital Costs:$6,456,000
O&M Costs: $18,200/year for 30 years
• Total Present Worth: $6,698,000
Time to Complete: 12 months
This alternative involves excavation of residual EC dust, soil
with lead levels above 600 ppm, and slag with total lead levels
above 1360 ppm or above the TCLP standards noted on page 38. No
excavation below the water table would occur. In addition,
incinerator ash would be removed from its current location, a
covered building on-site. The material would then be treated on-
site by solidification. Solidification involves mixing the
contaminated material to achieve a hardened mass. The hardened
mass reduces the mobility of the contaminants. Compliance with
RCRA Land Disposal Restriction (LDR) treatment standards for EC
dust, which is the listed RCRA waste K061, would be achieved by
meeting levels specified in the treatability variance for
contaminated soil and debris.
The solidified material would be placed in an on-site RCRA
landfill with double liners and a leachate collection system and
covered with a RCRA cap. The base may be constructed from slag
that passes the cleanup goals specified for slag. Such a base
would elevate the solidified material above the surrounding land
surface, thus increasing the distance between the water table and
solidified material. The base would not substitute as bottom
liner of the landfill unless it met the requirements for bottom
liners found at 40 C.F.R 264.301 (c).
The excavated area would be graded and grassed. Surface water
runoff from the site would be controlled and routed to the
stormwater retention pond on-site until remedial activities were
complete and surface water quality was sufficient to allow a flow
offsite. Groundwater quality would be monitored for up to 30
years.
Alternative 4-S: Excavation, Solidification
Solidification, On-site Disposal in Single Lined Landfill with
RCRA Cap
Capital Costs: $5,856,000
O&M Costs: $18,200/year for 30 years
Total Present Worth: $6,098,000
Time to complete: 9 months
This alternative is similar to alternative 3-S except for
differing landfill design requirements. Under this alternative,
the landfill would have only one liner and would not have a
leachate collection system. The landfill would be covered with a
RCRA cap.
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For each alternative considered for metals contaminated material
at this site, all visually distinguishable EC dust remaining at
the site would be excavated and treated. Soil contaminated with
lead above 600 ppm would also be excavated and treated. Also,
drainage ditch sediments with lead levels above 600 ppm would be
excavated and treated.
Zinc, the most common metal contaminant at the site, is generally
present at levels 8 times higher than lead. Therefore, based on
the lead cleanup goal of 600 ppm, the zinc cleanup level would be
approximately 4800 ppm. For comparison, an estimated acceptable
soil zinc level in a residential setting would be approximately
50,000 ppm (EPA Risk Assessment Guidance for Superfund).
For the alternatives involving on-site treatment of metal
contaminated material, compliance with the LOR treatment levels
specified for EC dust, which is a RCRA listed waste K061, would
be achieved by meeting the standards specified in the
treatability variance for contaminated soil and debris. A
comparison of the treatability variance levels for contaminated
soil and debris (EPA 9347.3-06FS, 09-90) and the LDR levels for
low zinc EC dust is presented below:
Table 5: Treatment Levels for K061 Wastes (in mg/1 TCLP extract)
Treatability Variance Levels LDR treatment standards
Cadmium
Chromium
Lead
Nickel
.2
.5
.1
.5
- 2
- 6
- 3
- 1
.14
5.2
.24
.32
Cleanup standards for slag are the TCLP standards for substances
listed in RCRA Section 261.24, Table 1 and a total lead level no
greater than 1360 ppm. The applicable TCLP standards for slag
include, but are not limited to:
Cadmium 1 mg/1
Chromium 5 mg/1
Lead 5 mg/1
Silver 5 mg/1
Given the TCLP values presented in the FS, the leachability of
slag is expected to be very low. TCLP values ranged from less
than .5 mg/1 to 1.3 mg/1 of lead for slag samples containing
total lead concentrations of 545 to 758 ppm.
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The single lined landfill was originally presented in the FS as
an appropriate option. However, it has since been determined
that a facility specific delisting for the stabilized K061 would
be required in order for the waste to be disposed of in a
landfill meeting subtitle D design requirements.
•
The cleanup standard for PCB contaminated soil is based on the
TSCA Spill Cleanup Policy for areas with restricted access. The
standard, 25 ppm, does not apply to those areas previously
cleaned to a level of 50 ppm.
Some bench scale testing has been performed on varying mixtures
of EC dust, soil, and cement to evaluate the effectiveness of
solidification. These initial results were presented in the
Phase II RI Report. As part of the testing, unconfined
compressive strength, permeability and EP toxicity were measured.
8 out of 12 samples of "pure" EC dust mixed with varying amounts
of cement yielded EP toxicity values less than 3 mg/1.
Additional treatability testing will be required to refine the
mix of ingredients that will ensure that the solidified material
will meet the TCLP standards noted in the treatability variance
for contaminated soil and debris and in Table 5.
Additional standards for the solidified material will be
developed during the remedial design. These standards may
include:
- permeability less than or equal to 10"6 cm/sec
- unconfined compressive strength
-r satisfactory performance during the American Nuclear Society
(A.N.S.) 16.1 leach test procedure.
Another factor that will be evaluated during the treatability
study will be the potential for volatilization of PCBs during the
solidification process. Soil containing PCBs between 25 and 49
ppm will be solidified and disposed of in the on-site landfill.
Groundwater use restrictions may be needed to prevent
disturbances of the off-site groundwater plume until the
groundwater cleanup is completed. Possible disturbances may
include the installation of water supply wells or excavation
below the water table.
8.0 COMPARATIVE ANALYSIS
The alternatives are evaluated against one another by using the
following nine criteria:
•Overall protection of human health and the environment
•Compliance with Applicable or Relevant and Appropriate
Requirements (ARARs): meeting requirements of other laws that
relate to the actions proposed for the site.
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•Long term effectiveness and permanence
•Reduction of toxicity, mobility, or volume through treatment
•Short term effectiveness
•Implementability: being technically and administratively
possible
•Costs
•State Acceptance
•Community Acceptance
Overall Protection; The "No Action" alternative, would not
protect human health and the environment and will not be
evaluated further in the selection of cleanup alternatives.
The remaining alternatives would provide protection of human
health and the environment by utilizing treatment to minimize or
control the risk associated with exposure to Site contamination.
Alternative 2-P would greatly reduce the risk of dermal contact
and ingestion of PCB contaminated soil.
Alternative 3-S would greatly reduce the risk of dermal contact
and ingestion of metal contaminated soil, including EC dust, by
solidifying the waste and disposing it in an on-site landfill.
The landfill design would provide a high degree of protection for
groundwater.
Compliance with ARARS: The alternatives considered for the site
would meet their respective applicable or relevant and
appropriate requirements (ARARs) of Federal and State
environmental laws or justify a variance from those laws.
As part'of alternatives 3-S and 4-S (EC dust and metal
contaminated soil), compliance with the RCRA LDR treatment
standards for the EC dust (RCRA listed waste K061) would be
achieved by meeting the treatment levels specified in the
treatability variance for contaminated soil and debris.
Long term effectiveness and permanence; All remedial
alternatives considered, except the no-action alternative, offer
long term effectiveness and permanence. Alternative 2-S, off-
site treatment of the EC dust and lead contaminated soil,
represents an effective method to reduce the risk associated with
that material. The metals in the EC dust and lead contaminated
soil would be separated by the HTMR process and recycled.
Alternative 3-S and 4-S, solidification of EC dust and metals
contaminated soil, is an effective and permanent method of
reducing the risk associated with the EC dust and metals
contaminated soil and ash because the contaminants are
permanently bound in a cement matrix.
These alternatives would also serve to limit, to the extent
practicable, the source of metals contamination in the
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groundwater. Alternative 3-S, solidification and disposal in the
on-site RCRA double lined landfill, provides an extra.measure of
protection for groundwater.
Alternative 2-P, off-site disposal of soil containing greater
than 50 ppm of PCBs would offer protection by proper disposal in
a permitted hazardous waste facility. Solidification of the low
level PCB contaminated soil is an effective and permanent
treatment method for the remediation of the Florida Steel Site.
Reduction of Toxicitv, Mobility, or Volume Through Treatment;
Use of HTMR, as described in Alternative 2-S, will greatly reduce
the toxicity of EC dust and lead contaminated soil. Alternative
3-S, solidification of the EC dust, lead contaminated soil and
ash will increase the volume of material that would be placed in
the on-site vault. However, mobility of the metals will be
greatly reduced because they will be permanently bound up in a
cement matrix.
Alternative 2-P includes off-site disposal of high levels of PCB
contaminated soils and on-site solidification of low level
contamination. Off-site disposal of PCB contaminated soil will
indirectly reduce the mobility of the contaminants by isolating
the material in a secure landfill, thus reducing the forces which
drive mobility. On-site solidification of the lower level
contaminated soil would increase the volume of the material to be
placed in the on-site vault, but the mobility would be
substantially reduced by the cement matrix.
Short-term effectiveness; After implementation, all of the soil
and ash alternatives, 2-S, 3-S, 4-S, and 2-P, will remove the
risk associated with direct exposure to the contaminated
material. However, cleanup workers could experience a short term
risk due to direct contact, inhalation, or ingestion during
excavation and movement of the soil, ash, and EC dust. Airborne
emissions of dust will be monitored and controlled to minimize
exposure off-site.
Alternative 2-S, HTMR, is not as effective in the short term
because of the possibility of traffic accidents with trucks
hauling EC dust and metal contaminated material off-site. In
addition, the capacity of HTMR facilities is not certain; costs
and time required for cleanup could increase depending on
capacity of the HTMR facilities. For these reason, HTMR may have
a reduced implementability.
Implementability; Alternative 2-S (off-site disposal of EC dust
and metal contaminated soil and ash) will take longer to
implement since it is dependent upon the rate at which the off-
site treatment facility can accept the materials. Alternatives
3-S and 4-S (solidification of EC dust and metal contaminated
soil and ash) could be implemented more quickly.
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Alternative 2-P (off-site disposal/on-site solidification for PCB
contaminated soil) would not be difficult to implement. The
volume of soil involved is relatively small so the disposal
facility should be able to quickly accept the material. The
solidification of low level PCBs is an established technology and
is implementable,.
Costs; The estimated total present worth costs of each remedy is
discussed in this section. The cost associated with Alternative
1-S, the no action alternative for lead contaminated soils is
$345,000. The cost for Alternative 2-S is $21,160,000. The cost
for Alternative 3-S is $6,698,000. The cost for Alternative 4-S
is $6,098,000. The cost for Alternative 1-P, the no-action
alternative for PCB contaminated soil, is zero. The cost for
Alternative 2-P is $306,750.
The action alternatives have substantially higher costs due to
increased efforts to permanently treat the contamination present
in the soil and groundwater. This includes on-site
solidification of the EC dust and metals contaminated soil and
ash (Alternative 4-S), off-site disposal of PCB contaminated soil
with concentrations above 50 ppm, and on-site solidification of
PCB contaminated soil with concentrations between 25 and 50 ppm
(Alternative 2-P).
State Acceptance; The State of Florida has concurred with this
Record of Decision.
Community Acceptance; The Martin County Board of Commissioners
and local citizens agree that site remediation is necessary;
however they are currently opposed to a possible discharge of
treated groundwater to the St. Lucie Canal as was stated in EPA's
Proposed Plan (see Section 11 - Explanation of Significant
Changes).
9.0 SELECTF-n Rgamnv
Based upon consideration of the requirements of CERCLA, the
detailed analysis of the alternatives, and public comment, EPA
has selected the following remedy for the site:
•Excavation and off-site disposal at an EPA approved facility of
approximately 600 cubic yards of soil contaminated with PCB
levels equal to or greater than 50 ppm.
•Excavation and on-site solidification of approximately 37,000
cubic yards of the following:
-EC dust and metals contaminated soil and ash. All EC dust
and ash would be excavated and treated; soil containing lead
above 600 ppm would be excavated and treated.
-soil containing PCB levels between 25 and 50 ppm;
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No excavation below the water table will occur unless- the water
treatment system anticipated for the second operable unit is
operational. However, at this time it is not anticipated that
excavation below the water table will be required.
•Control of surface water runoff from the site during remediation
of on-site soils.
•Compliance with Resource Conservation and Recovery Act (RCRA)
Land Disposal Restriction treatment standards for EC dust/ which
is a listed RCRA waste, K061, by meeting levels specified in the
treatability variance for contaminated soil and debris.
•Disposal, in an on-site double lined RCRA landfill with a RCRA
cap, of all solidified material. The landfill would meet the
provisions of 40 C.F.R. Subpart N landfill requirements and would
be built above the water table.
•Periodic monitoring of surface water and groundwater quality.
The quality of surface water runoff should be consistent with
possible future criteria developed for the adjacent wetlands in
the second operable unit for this site. Groundwater quality
would be monitored for up to 30 years.
Appropriate dust control measures shall be used to reduce the
potential for airborne transport of site contaminants during the
remedial action, especially during the excavation of EC dust and
contaminated soil. Similar steps will also be taken during
removal of the incinerator ash for solidification.
PCB contaminated soils that are excavated and temporarily stored
on-site pending final treatment and/or disposal roust be stored in
a manner that will prevent the PCBs from being carried away in
surface water runoff. For example, stockpiled soil should be
covered with tarps or be contained within berms. In addition,
any temporary storage of PCB contaminated soils may be subject to
TSCA requirements limiting storage to 30 days or less.
Groundwater monitoring will be performed to ensure that soil lead
cleanup levels and the proposed landfill measures will remain
protective of groundwater. However, if suggested by results of
the monitoring, additional site cleanup may be necessary. This
additional site cleanup may include, but not be limited to,
additional soil excavation and treatment, modifications to the
landfill cover, etc.
As part of the remedial action, all surface water runoff will be
controlled and routed to the on-site surface water retention
pond. Surface water samples will be collected and analyzed for
the site contaminants. The control of surface water runoff and
analysis of surface water samples may continue for at least two
years after all on-site construction has been completed. This
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should allow time to determine the effect of controlling the
source of metals contamination upon surface water quality.
The total present value cost of the selected remedy is
approximately $7 million dollars. For the EC dust and
contaminated soij., this cost includes O&M costs of $l8/200/year
for up to 30 years. The volume of soil that would be treated
under the selected remedy would be approximately 37,600 cubic
yards.
9 .1 Remediation goals
Based on the results of the RI/ FS reports and the risk
assessment, remediation levels were developed that would be
protective of human health and the environment. These levels
form the basis for the remedial activity to be taken at this
site.
EPA and FDER derived a soil lead cleanup level of 600 ppm. This
value is based upon, .the leachability of lead from soil into the
underlying groundwater and is a level calculated to be protective
of groundwater. EPA's recommended cleanup level for lead in
groundwater, 15 ppb, was used as the basis for the derivation of
this lead soil cleanup level.
This value was calculated by first determining an average soil
lead concentration and an average groundwater lead concentration
for an area of the site where a cause and effect relationship
could be established. In addition, EPA arrived at a similar
cleanup value for lead in soil by using the Summers model and
site specific parameters.
Slag, which contains lead, will be cleaned up to 1360 ppm, a
level protective of human health in an industrial setting. Slag
may not be subject to the cleanup level based on groundwater
protection because it produces low levels of lead in leachate and
is not a threat to groundwater for levels below 1360 ppm.
Toxicity Characteristic Leaching Procedure (TCLP) results are
included in the FS (see also Section 5.1 of ROD). However,
additional TCLP testing will be conducted during the remedial
design.
Some treatment of the soil containing PCBs above 50 ppm may be
necessary before disposal in the offsite RCRA/TSCA approved
landfill. Some of the PCB contaminated soil contains elevated
levels of metals. The disposal facility will be responsible for
ensuring that the PCB and metal contaminated soil is disposed of
in accordance with appropriate regulations. Treatment and
disposal costs of these soils are not expected to significantly
increase because of the limited volume (600 cubic yards) of
affected soil.
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The PCB cleanup level of 25 ppm .is based on the regulations
referred to in the Toxic Substances Control Act PCB Spill Cleanup
Policy for areas with restricted access.
10.0 STATUTORY DETERMINATIONS
Under its legal authorities, EPA's primary responsibility at
Superfund sites is to undertake remedial actions that achieve
adequate protection of human health and the environment. In
addition, Section 121 of CERCLA establishes several other
statutory requirements and preferences. These specify that, when
complete, the selected remedial action for this site must comply
with applicable or relevant and appropriate environmental
standards established under Federal and State environmental laws
unless a statutory waiver is justified. The selected remedy also
must be cost-effective and utilize permanent solutions and
alternative treatment technologies or resource recovery
technologies to the maximum extent practicable. Finally, the
statute includes a preference for remedies that employ treatment
that permanently and. significantly reduce the volume, toxicity,
or mobility of hazardous wastes as their principal element. The
following sections discuss how the selected remedy meets these
statutory requirements.
10.1 Protection of Human Health and the Environment
The selected remedy, including solidification of EC dust, metals
contaminated soil and ash, and soil with PCB concentrations
.between 25 ppm and 50 ppm will eliminate the source of
contamination. The selected remedy will also greatly reduce the
threat of dermal contact with contaminated soil.
Excavation and proper off-site disposal of soil with PCB
concentrations above 50 ppm will also greatly reduce the threat
of dermal contact with contaminated soil.
Eliminating the source of contamination will result in improved
surface water quality thereby reducing the amount of
contamination that could be carried away in site runoff. In
addition, the metals that could leach into the groundwater will
be removed.
10.2 Compliance with ARARs
The select remedy will meet the following ARARs:
Resource Conversation and Recovery Act (RCRA)
- Compliance with federal RCRA LDRs for RCRA listed waste
K061 (EC dust) will be achieved by meeting treatment levels
specified in the treatability variance for contaminated soil
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and debris. The treatment standards are listed in Table 5
on page 38..
- 40 C.F.R. Part 261 Subpart C: Characteristics of Hazardous
Waste
The preliminary TCLP results for slag presented in the FS
indicate that slag does not exhibit the characteristic of
toxicity. Additional TCLP sampling will be conducted as
part of the remedial design.
- 40 C.F.R. Part 264 Subpart N: Landfill Requirements
- 40 C.F.R. Part 268 Subpart C: Prohibitions on Land
Disposal
- 40 C.F.R. Part 268 Subpart D: Treatment Standards
EC dust is a listed RCRA waste, K061. According to the
LDRs, a listed, .waste must be treated to its specific
treatment standards before disposal. At this site, the EC
dust is considered "low zinc." Five samples of EC dust were
analyzed during the RI. The average zinc concentration was
129,320 ppm or 12.9% zinc. Standard deviation was 70,000
ppm.
As noted previously, compliance with the LOR treatment
levels specified for EC dust, which is a RCRA listed waste
•K061, would be achieved by meeting the standards specified
in the treatability variance for contaminated soil and
debris (OSWER 9347.3-06FS, 09/90).
Placement, as defined in the RCRA LDRs, will occur as part
of the on-site actions. However, the material will be
treated to the levels specified in the variance before its
disposal in the on-site landfill.
Toxic Substances Control Act (TSCA)
40 C.F.R. Part 761 Subpart D: Storage and Disposal of
PCBs
- 40 C.F.R. Part 761 Subpart G: PCS Spill Cleanup Policy
- 40 C.F.R. Part 761 Subpart K: PCB Disposal Record Keeping
Other:
- Federal Occupational Safety and Health Administration Act
(OSHA): The selected remedial action contractor will develop
and implement a health and safety program for its workers.
All on-site workers will meet the minimum training and
medical monitoring requirements outline in 40 CFR 1910.
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- National Ambient Air Quality Standards (NAAQS)
- Florida Department of Environmental Regulations - Class
III Surface Water Quality Standards
To Be Considered (TBC):
- 06/21/90 OSWER recommendation: a protective cleanup level
for lead in water of 15 ppb.
10.3 Cost effectiveness:
The selected remedy has an estimated total present worth of
approximately $7 million dollars. The selected remedy affords
overall effectiveness proportional to its costs. When the
relationship between cost and overall effectiveness of the
selected remedy is viewed in light of the relationship between
cost and overall effectiveness of the other alternatives, the
selected remedy is cost effective.
Capital costs:
-Disposal of soil contaminated with PCBs > 50 ppm: $306,750
-Solidification of EC dust, metal contaminated
material, and soils with PCB levels between
25 and 50 ppm : $6,456,500
O&M costs per year (for up to 30 years) : $18,200
EC dust and metal contaminated material represent the largest
volume of site contaminants and the a source for continuing
groundwater contamination. Solidification and disposal of this
material in an on-site RCRA landfill is an effective method to
address the principal source of contamination.
10.4 Utilization of Permanent Solutions and Alternative
Treatment or Resource Recovery Technologies to the Maximum
Extent Practicable
EPA has determined that the selected remedy provides the best
balance among the nine evaluation criteria for the alternatives
evaluated. The remedy uses permanent solutions and treatment
technologies to the maximum extent practicable. The EC dust,
soil, and groundwater remedy provides short and long term
protection for human health and the environment, is readily
implementable, is cost effective and is consistent with future
response actions that may be undertaken at the site.
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10.5 Statutory Preference for Treatment as a Principal
Element .
The statutory preference for treatment of soil contamination will
be met at this site. The principal threat at this site is
ingestion and dermal contact with contaminated soil and the
future migration of contaminants from soil into groundwater. The
selected remedy will use treatment for the metal contaminated
material (EC dust, soil, ash), which represents the largest
source of contamination. Treatment of the metal contaminated
material will greatly reduce the risk associated with ingestion
and contact with contaminated soil, sediment, and ash and will
remove the source of future groundwater contamination.
On-site treatment of soil with PCB concentrations above 50 ppm
was not considered worthwhile because of the small volume of
contaminated media relative to the high costs of effective
technologies. However, some treatment may be required before
disposal in the RCRA/TSCA approved landfill because of the
presence of metals an some of the PCB contaminated soil.
11.0 EXPLANATION OF SIGNIFICANT CHANGES
The Proposed Plan was released for public comment in April 1992.
The Proposed Plan identified a combination of Alternative 3-S:
excavation, onsite solidification and disposal in an on-site
double lined RCRA landfill; Alternative 2-P: Excavation and
offsite disposal for soils with PCB concentrations above 50 ppm
and excavation, on-site solidification and disposal in the
planned landfill noted above for soils containing PCBs between 25
and 50 ppm; and Alternative 2-GW: groundwater treatment and
discharge to the St. Lucie Canal or the POTW or an industrial
user.
EPA reviewed all written and verbal comments submitted during the
public comment period. Upon review of these comments, EPA, in
consultation with the State of Florida, decided to defer the
groundwater component of the proposed remedy to the second
operable unit for this site. This will allow EPA to initiate
cleanup of the contaminated soils which are a source of
groundwater contamination, while a further evaluation is
conducted of discharge methods for treated groundwater. EPA will
issue a second proposed plan for the second operable unit at the
Site and will again seek community input prior to the selection
of a remedial action for the contaminated groundwater and
wetlands.
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References
Completion Report, Task I PCB Remedial Action Plan, Florida
Steel Corporation Indiantown Mill, Indiantown, Florida,
dated October 2, 1986, Ardaman and Associates.
Phase I Remedial Investigation Report, Florida Steel
Corporation Indiantown Mill Site, dated September 30, 1988,
Ardaman and Associates.
Phase II Remedial Investigation Report, Florida Steel
Corporation Indiantown Mill Site, dated October 17, 1989,
Ardaman and Associates.
Human Health and Environmental Risk Assessment of the
Florida Steel Corporation Indiantown Mill Site, dated
January 1991, Envirologic, Inc.
Results of Groundwater Sampling Through June 1991, Florida
Steel Corporation Indiantown Steel Mill, dated December 19,
1991, Mark Schultz Associates
Feasibility Study Report, Florida Steel Corporation
Indiantown Mill Site, dated March 13, 1992, Ardaman and
Associates.
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APPENDIX C: RISK CALCULATION CONSTANTS
Several assumptions and constants used in determining exposure
and calculating site risks and are presented in the following
tables:
Current and Future Use Scenarios
Soil Ingestion
Relative Absorption
Ingestion Rate
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
1 (unitless)
50 rag/day
120 days/year
40 years
70 kilograms (kg)
14,600 days
1 (unitless)
50 mg/day
120 days/year
40 years
70 kg
25,500 days
Current and Future Use Scenarios
Soil Dermal Contact
Noncarcinogenic
chronic effects
Carcinogenic
effects
Adherence factor
Relative absorption*
Skin Surface Area
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
1 mg/cm2
.01 unitless
1700 cm2
120 days/year
40 years
70 kg
14,600 days
1 mg/cm2
.05 unitless
1700 cm2
120 days/year
40 years
70 kg
25,500 days
* .01 - inorganics
.05 - PCBs
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APPENDIX C (cont.)
Future Use Scenarios
Dermal Contact with Groundwater (handwashing)
Nonearcinogenic
chronic effects
Carcinogenic
effects
Skin Surface Area
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
1700 cm2
.167 hrs/day
120 days/year
40 years
70 kg
14,600 days
1700 cm2
.167 hrs/day
120 days/year
40 years
70 kg
25,500 days
Nearby Residential Future Use
Ingestion of Groundwater
Noncarcinogenic
chronic effects
Carcinogenic
effects
Body weight Adult
child
Ingest ion rate Adult
Child
Relative absorption
Exposure Frequency
Exposure Duration
Adult
Child
Averaging Time Adult
Child
Lifetime Dose
70 kg
17 kg
2 I/day
1 I/day
1 unitless
365 days /year
30 years
6 years
10,950 days
2,190 days
538,740
63,510
70
17
2
1
NA
365
30
6
pCi/L (Ra-226)
pCi/L (Ra-228)
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APPENDIX C (cont.)
Nearby Residential Future Use
Dermal contact with groundwater (bathing)
Exposed Skin Surface Area Adult
Child
Exposure Time (hours/day)
Exposure Frequency (days /year)
Exposure Duration (years) Adult
Child
Averaging Time (days) Adult
Child
Permeability Rate (cm/hr)
18,000 cm2
5,760
.33
365
30
6
10,950
2,190
5.0E-4
18,000
5,760
365
30
6
10,950
2,190
cm2
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