PB95-964030
                                EPA/ROD/R04-95/245
                                February 1996
EPA Superfund
      Record of Decision:
       USDOE Oak Ridge Reservation,
       Kerr Hollow Quarry, Oak Ridge, TN
       9/29/1995

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                                     DOE/OR/02-1398&D2
               Record of Decision
                      for
Kerr Hollow Quarry at the Oak Ridge Y-12 Plant,
             Oak Ridge, Tennessee


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                          PREFACE
This record of decision for Kerr Hollow Quarry (DOE/OR/02-1398&D2)
was prepared in accordance with requirements under the Comprehensive
Environmental Response, Compensation, and Liability Act to present the
selected remedy to the public.  The approved Resource Conservation and
Recovery Act closure has been  accepted as being protective of human
health and the  environment.  This work was performed under Work
Breakdown Structure  1.4.12.1  (Activity  Data 2306  "Kerr Hollow
Quarry").  This document provides the  Environmental  Restoration
Program with information about the selected remedy for Kerr Hollow
Quarry, which involves no further action to achieve protection of human
health and the environment at the Kerr Hollow Quarry.

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                  ACRONYMS AND ABBREVIATIONS
 CERCLA

 CFR
 DOE
 Energy Systems
 EPA
 ft
 gal
 ha
 kg
 km
 L
 m
 NPDES
 ORO
 RCRA
 ROD
 TDEC
 Y-12 Plant
 yd
Comprehensive Environmental Response, Compensation, and Liability
Act
Code of Federal Regulations
U.S. Department of Energy
Lockheed Martin Energy Systems
U.S. Environmental Protection Agency
foot
gallon
hectare
kilogram
kilometer
liter
meter
National Pollutant Discharge Elimination System
Oak Ridge Operations
Resource Conservation and Recovery Act
record of decision
Tennessee Department of Environment and Conservation
Oak Ridge Y-12 Plant
yard
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                                       111
                                                                     September 20. 1995

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                   PART 1. DECLARATION
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                      SITE NAME AND LOCATION

      U.S. Department of Energy
      Kerr Hollow Quarry at the Oak Ridge Y-12 Plant
      Oak Ridge Reservation
      Oak Ridge, Tennessee


               STATEMENT OF BASIS AND PURPOSE

      This  document presents the decision for no further action at the Oak Ridge Y-12 Plant
(Y-12 Plant) Kerr Hollow Quarry in Oak Ridge, Tennessee.  The U.S. Environmental Protection
Agency (EPA) has accepted the approved Resource Conservation and Recovery Act (RCRA)
closure as being protective of human health and the environment. The closure also satisfies the
requirements of the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA), as amended, and to the extent  practicable, the National Oil and  Hazardous
Substances Contingency Plan.  This  record of decision (ROD) provides the public  with a
consolidated source of information about Kerr Hollow Quarry.

      The state of Tennessee and EPA concur with the U.S. Department of Energy (DOE) in
this decision for no further action at Kerr Hollow Quarry.


               DESCRIPTION OF SELECTED  REMEDY

      Previous action taken was under an approved RCRA closure plan and approved by the
Tennessee Department of Environment and Conservation (TDEC), and is protective of human
health and the environment. Therefore, no further action is necessary under CERCLA. These
closure activities were conducted as part of the RCRA closure, which fits with DOE's cleanup
strategy to perform all response actions at the Oak Ridge site in accordance with federal and state
laws, standards, limitations, and criteria.


                     DECLARATION STATEMENT

      Kerr Hollow Quarry was closed according to RCRA regulatory guidance.  Restricted
access provides the necessary protection of human health and the environment, thus no further


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remedial action is necessary under CERCLA to ensure adequate protection of human health and
the environment.  The status of this site under CERCLA will be reviewed every 5 years.  Also,
the status of this site will be reviewed as a pan of the RCRA postelosare permit process at least
every  10 years.  Ground water will be monitored as pan of the RCRA  postctostite permit
requirements.  Surface water contamination will be periodically monitored at the surface water
discharge point  from the  quarry  as a best management practice.  If statistically significant
contamination is detected in groundwater or surface water at the site, any remediation, if
necessary, will be addressed under CERCLA.


                                   APPROVALS
 James^mll, Manager                                    Date
 DCS. Department of Energy
 Oak Ridge Field Office
 Earl C. Leming, Director^———Date
 U.S. Department of Energy Oversight Division
 Tennessee Department of Environment and Conservation
 John Hankinson, Regional Administrator                  Date
 Region IV
 U.S. Environmental Protection Agency
JT9S0706.1DH/OE                               1-3                               September X, 1995

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                PART 2.  DECISION SUMMARY
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             SITE NAME, LOCATION, AND DESCRIPTION

       The Y-12 Plant occupies approximately 320 ha (800 acres) of the DOE reservation .and
was built for the U.S. Army Corps of Engineers in the 1940s to support the Manhattan Project.
Figure 2.1 shows a map of the site.

       Kerr Hollow Quarry is a 1.2 ha (3-acre), flooded limestone rock quarry on the Oak Ridge
Reservation about 2.5 km (1.5 miles) south of the Y-12 Plant and approximately 320 m (350 yd)
north of Bethel Valley Road. Kerr Hollow Quarry is approximately 16.8 m (55 ft) deep and
sheltered on three sides by 18.3-m (60-ft)-high cliffs. It was operated during the 1940s as a rock
and gravel quarry, but was abandoned in the late 1940s and allowed to fill with water.


                                 SITE HISTORY

       In the early 1940s, Clinton Engineering Works leased the Kerr Hollow Quarry site to
Ralph Rogers Company, Inc., to provide rock and gravel for construction on the Manhattan
Project. In the late 1940s, the quality of the stone degraded, the quarry was abandoned, and the
quarry eventually filled with  water.

       The quarry was used as a treatment site for water-reactive, corrosive, or ignitable wastes
from the Y-12 Plant and the Oak Ridge  National Laboratory from 1951 until 1988.  The site
received containers  of waste in various sizes consisting mainly  of gas cylinders, drums, and
buckets.

       No disposal records are available for activities performed before 1957.   Kerr Hollow
Quarry was not intended for use as a hazardous waste storage or disposal facility. Instead,  it was
used to treat the wastes  and effectively  eliminate the hazardous characteristics  of  reactivity,
corrosivity, and ignitability.

       Records for Kerr Hollow Quarry,  dating from 1957, show that approximately  45,450 kg
(50 tons) of hazardous and nonhazardous waste were treated at the site. The estimated amount
generally included the weight of the containers and the materials inside.  There is no documented
record of any enriched radiological material in the inventory.

       Water-reactive materials such as lithium and sodium were normally packed in 20-, 120-,
or 220-L (5-, 30-, 55-gal) containers. After arriving at the quarry, the containers were placed


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v
u>
                                                                                                                             2.5      0      2.5      5
                                                                                                                                   S=2=
                                                                                                                                   SCALE IN MILES
                    Fig.  2.1
            Regional  location  map
DOE - Y-12 Plant. Kerr  Hollo*  Quarry  -  Oak Ridge. Tennessee
DOCUMENT ID  35H830
1900-10 / ROD
DRAWING DATE
AUGUST 10. 1995 TR

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on a chute and dropped into the water. Rifle fire from a protected location was used to puncture
the containers, allowing water to enter and to react with the contents.  A complete reaction of the
metal was expected because of the violent nature of the explosion or violent burning that followed
as the container sank below  the surface of the water.  Potentially explosive chemicals such as
picric acid were suspended above the water surface, and their containers were punctured by rifle
fire before being  dropped into the water.   Large pressurized vessels containing sodium were
placed in the quarry with their valves and vent pipes in the open position, which allowed water
to enter and react with the sodium as the vessel  sank.  Gas cylinders with frozen valves were
vented on the bank of the quarry by puncturing the cylinder wall by rifle fire. After the early
1970s, the cylinders were returned to the Y-12  Plant for disposal;  before then, the breached
cylinders were discarded in the quarry.

       Treatment  activities at Kerr Hollow Quarry ceased on November 7, 1988. Effluent from
Kerr  Hollow Quarry has been monitored under  the National Pollutant Discharge Elimination
System (NPDES), Permit No.  TN 0002968 - Outfall 301, as prescribed in the Clean Water Act,

       During preparation for the RCRA closure in March 1989, a remotely operated underwater
vehicle equipped  with a camera surveyed the bottom of the quarry.  Follow-up surveys were
conducted in the spring and  summer of 1990.  From these surveys and  inventory records, the
containers, cylinders, and other materials viewed on the bottom of the quarry were documented
as the baseline condition expected to be present.  From  1991 through 1993, containers  and
materials at the bottom of Kerr Hollow Quarry were shredded, removed, evaluated by health
physics personnel, and placed  in B-25 boxes.  Containers and other objects from the bottom of
the quarry were shredded underwater to treat any reactive materials that  might remain, thereby
minimizing the hazardous effects from potential release of the residual material. Shredded debris
from the quarry was placed in concrete vaults and placed adjacent to the Walk-in Pits in the Bear
Creek Burial Grounds.  The  concrete vaults were subsequently covered with  a RCRA cap
according to the approved closure plans for both  of those units.

       Removal operations  were  stopped  numerous times to evaluate  and change operating
procedures.  Most of these procedural changes were for safety reasons.  Because 10-15 percent
of the gas  cylinders in Kerr  Hollow Quarry was still pressurized, a special procedure  was
developed for inspecting, breaching (if necessary),  and  removing cylinders.

       Final removal and inspections began in January  1993, which required tracking the items
removed and identifying the items that remained  in Kerr Hollow Quarry. Items that could not
shield reactive material from the water and prevent it from reacting (e.g., solid objects, metal and
plastic sheets,  container lids, broken glass, wire, and pieces of  wood) and that  were not

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hazardous to human health and the environment were left in the quarry. Final waste removal and
inspection were completed October 22, 1993.  The last of the operating equipment was removed
from the quarry November 11, 1993.


                           COMPLIANCE HISTORY

       On October 11, 1987, in a letter to the deputy assistant manager for defense programs,
the TDEC advised DOE-Oak Ridge Operations (ORO)  that disposal into the quarry after
November 7, 1988, could not be allowed under the Tennessee Water Quality Control Act. As
determined by TDEC, Kerr  Hollow Quarry was a surface impoundment subject to the 1984
Hazardous and Solid Waste Amendments of RCRA; consequently, the quarry either had to be
retrofitted to meet technological requirements or be closed.  In either case, further disposal was
prohibited after November 7.  DOE-ORO directed Lockheed Martin Energy Systems (Energy
Systems) to submit a schedule of its closing by January  8, 1988,  in a manner adequate to meet
the closure  requirements of a surface  impoundment  as  specified  in 40 Code of Federal
Regulations (CFR) 265.

       To comply with the TDEC directive, Energy Systems began a study of alternative methods
of closure.  An initial option of no action was eliminated after study.  Lining the quarry was
rejected on economic and technological bases. Removing all the water from the spring fed quarry
was  without  precedent  and immediately dismissed as a viable course  of action.   Some
consideration was given to filling the quarry with rock, an alternative repudiated for cost and
safety factors.

       The original closure plan called for work to be performed in two phases: a survey (which
would supplement the one done in 1987) to determine the extent of the debris in the quarry, and
the subsequent removal, shredding, and disposal of the debris.

       The closure plan for  Kerr Hollow Quarry was  submitted to TDEC and conditionally
approved September 28,  1988, but was subsequently revised to reflect  changes, as necessary.
The  changes  were made and documented as Rl.   That  document constitutes  the base plan
authorized by TDEC  in 1988.

       The D2 version of the Kerr Hollow Quarry closure plan was approved in April 1993 to
clarify  the short-term storage of shredded debris and to more clearly identify the partial closure
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and final closure requirements.  The closure classification was changed from "clean" to "dirty"
due to the possibility that some contaminated material may remain buried in sediment at the
bottom of the quarry.

       The D3  version to the  closure plan was approved July 6, 1993, which  reflects the
reclassification of the  shredded debris from RCRA to non-RCRA status based on statutory
interpretation and the disposition of the debris at the Walk-in  Pits in the Bear Creek Burial
Ground at the Y-12 Plant.  Reclassification of the shredded debris was drawn from 40  CFR
268.42. From that interpretation, the shredded debris, having received water-reactive treatment
through shredding, met the technology-based standard.  Thus, it was not subject to further land
disposal restrictions.


          HIGHLIGHTS  OF COMMUNITY PARTICIPATION

      The public comment period for the Kerr Hollow Quarry no further action proposed plan
began June 12, 1995. This proposed plan was made available in the Administrative  Record File
maintained at the DOE  Information Resource Center beginning the first day  of the public
comment period.  The notice of availability was published in the Knoxville News-Sentinel June
19, 1995.  The notice included  a statement that a public meeting concerning the proposed plan
would be arranged, if requested, by June 26, 1995. A public meeting was not requested.  The
public comment period was held from June 12 through July 18, 1995.  No comments  were
received.


                     SCOPE AND ROLE OF THE SITE

      The selected  RCRA remedies involved  removing the containers,  cylinders, and other
materials from the bottom of the quarry.  The RCRA remedies prevent physical exposure to
contaminants  and  mitigate further migration of  contaminants  from Kerr Hollow Quarry to
groundwater or  surface water runoff. These RCRA closure activities fit into DOE's cleanup
strategy to undertake response actions at the Oak Ridge site in accordance with federal and state
laws, standards, limitations, and criteria.
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               SUMMARY OF SITE CHARACTERISTICS

      Containers and materials at the bottom of Kerr Hollow Quarry were shredded, removed,
and evaluated  by health physics personnel, and placed in B-25 boxes.  Final removal and
inspections were begun January 1993, which required tracking the items removed and identifying
the items that remained in Kerr Hollow Quarry. Items that could not shield reactive material
from the water and prevent it from reacting (e.g., solid objects, metal and  plastic sheets,
container lids,  broken glass, wire, and pieces of wood), and that were not hazardous to human
health and the environment, were left in the quarry.

      Wells around Kerr Hollow Quarry were sampled before and during the removal operations
as part of detection monitoring requirements.  Results  from monitoring the groundwater and
quarry water have not shown contaminant concentrations in excess of regulatory standards. The
surface water flowing from Kerr Hollow Quarry was also monitored adjacent to the quarry under
an NPDES permit.


                         SUMMARY  OF SITE RISKS

      Kerr Hollow Quarry is within a remote, protected area of the Y-12 Plant across Chestnut
Ridge from the main plant. Only designated and trained DOE or Energy Systems employees or
subcontractors  are allowed access to the quarry.  Wildlife has access to the area and may use the
water in and from Kerr Hollow Quarry.

      Even though small quantities of contaminants may remain within Kerr Hollow Quarry,
direct human exposure pathways do  not exist and are not likely to exist in the foreseeable future
because of the  security fencing, locked gates, deed restrictions, and limited access that are part
of the postclosure maintenance requirements (Rivera 1994).  Some contaminants may be buried
in sediments that are under 16.8 m (55 ft) of water, but making direct exposure to the public to
such deep sediments is highly unlikely.

      Data are insufficient to quantitatively document  an ecological risk assessment for Kerr
Hollow Quarry.  However, a qualitative evaluation of potential ecological  risks indicates  no
apparent ecological concern for Kerr Hollow Quarry, based on historical surface water analyses
from NPDES Outfall No. 301. Because of its proximity to Kerr Hollow Quarry, this outfall was
representative of Kerr Hollow Quarry surface and groundwater quality.  To ensure continued
protection of human health and the environment and to meet post-ROD requirements, DOE will


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monitor groundwater and surface water quality. Groundwater monitoring will meet pertinent
RCRA permit requirements and surface water monitoring will be conducted as a best management
practice.   The  latest quarterly sampling results from monitoring  indicate that groundwater
contaminants are below levels of regulatory concern.

       Beyond the potential risk from chronic exposure to contaminants in the Kerr Hollow
Quarry sediments, there is also a potential acute  risk from release of the contents from an
unknown  intact container that  could remain in  the quarry.   The  subsequent  release of
contaminants from such a cylinder or container degraded by  rust could result in a significant,
short-term release.  Procedures required by the RCRA Closure Plan would not allow unacceptable
risks to human health and the environment. A short-term release could result in a short duration
ecological event, which is not anticipated because closeout activities indicate  no such items were
detected.


                     STATUTORY DETERMINATIONS

       Kerr  Hollow Quarry was closed  according to RCRA regulatory guidance.  Restricted
access provides the necessary protection of human health and the environment  to satisfy CERCLA
requirements. Thus, no further remedial action is necessary under CERCLA to ensure adequate
protection of human  health and the  environment.   Under these circumstances, the statutory
cleanup standards of CERCLA, Section 121, for example, are not triggered.

       The status of this site under CERCLA will be reviewed every 5 years. Also, the status
of this  site will be reviewed as a part of the RCRA postclosare permit process at least every 10
years.  Groundwater will  be monitored under the  RCRA postclosure permit requirements.
Surface water will also be monitored at the  surface water  discharge  point from the quarry
periodically  as  a best management  practice  for contaminants.   If  statistically significant
contamination is detected in groundwater or surface water  at the site, any remediation will be
addressed under CERCLA.


             EXPLANATION OF SIGNIFICANT  CHANGES

       No significant changes have been made  to the no further  action decision selected in the
proposed plan through the regulatory and public comment periods.
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           PART 3. RESPONSIVENESS SUMMARY
JT950706.1DH/CIE                                              September 20, 1995

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                     RESPONSIVENESS SUMMARY

      DOE established a public comment period from June 12,  1995, through July 18, 1995,
for interested parties to comment on DOE's proposed plan for Kerr Hollow  Quarry.   The
proposed plan states that no further remedial action is necessary to protect human health and the
environment at Kerr Hollow Quarry.

      The 30-day comment period ended July 18,  1995.  No comments on the Kerr Hollow
Quarry proposed plan were available by that date and  no comments were received by July 25,
1995, the latest date to accept mailed comments.  In addition, no public meeting was requested;
therefore, none was held.


                                REFERENCES

DOE (U.S. Department of Energy).  1995. Proposed Plan for the Kerr  Hollow Quarry at the
      Y-12 Plant, Oak Ridge,  Tennessee, DOE/OR/02-1352&D2. Oak Ridge, TN.

Rivera, Fernando. December 8, 1994. "Record of Decision for the following Y-12 Plant RCRA
      Closures:   (1) Kerr Hollow Quarry, (2) Oil  Retention Ponds, and (3) Oil Landfarm,"
      letter from  Fernando Rivera, EPA Region IV, to  W. Nelson Lingle, Environmental
      Restoration Division, DOE/ORO.

Energy Systems (Martin Marietta Energy Systems, Inc.). December 1993. Closure Certification
      Report for the Kerr Hollow Quarry Site at the Oak Ridge  Y-12  Site,  Oak Ridge,
      Tennessee, Y/PF/01561.  Oak Ridge, TN.
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