EPA-450/3-74-056<
 JULY 1973
HACKENSACK MEADOWLANDS
     AIR POLLUTION STUDY
               DEVELOPMENT
             AND VALIDATION
 OF A MODELING TECHNIQUE
             FOR PREDICTING
         AIR QUALITY  LEVELS
   U.S. ENVIRONMENTAL PROTECTION AGENCY
      Office of Air and Waste Management
   Office of Air Quality Planning and Standards
   Research Triangle Park, North Carolina 27711

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                            EPA-450/3-74-OJ6-C
HACKENSACK MEADOWLANDS


  AIR  POLLUTION STUDY -


        DEVELOPMENT


       AND  VALIDATION


OF A MODELING TECHNIQUE


       FOR  PREDICTING


     AIR QUALITY LEVELS




                by

      James R. Mahoney, Bruce A. Egan, and
          Edward C. Reifenstein, III

    Environmental Research and Technology, Inc.
             429 Marrett Road
        Lexington, Massachusetts 02173


          Contract No. EHSD 71-39


        EPA Project Officer: John Robson



             Prepared for

    .  ENVIRONMENTAL PROTECTION AGENCY
        Office of Air and Waste Management
     Office of Air Quality Planning and Standards
       Research Triangle Park, N. C. 27711

              July 1973

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This report is issued by the Environmental Protection Agency to report technical
data of interest to a limited number of readers.  Copies are available free
of charge to Federal employees, current contractors and grantees,  and nonprofit
organizations-as supplies permit-from the Air Pollution Technical Information
Center, Environmental Protection Agency, Research Triangle Park, North
Carolina 27711; or, for a fee, from the National Technical Information Service,
5285 Port Royal Road, Springfield, Virginia  22161.
This report was furnished to, the Environmental Protection Agency by the
Environmental Research and Technology, Inc.,  in fulfillment of Contract
No. EHSD-71-39.  The contents of this report are reproduced herein as received
from the Environmental .Research and Technology,  Inc.  The opinions', findings,
and conclusions expressed are those of the author and not necessarily those
of the Environmental Protection Agency.  Mention of company or product
names is not to be considered as an endorsement by the .Environmental Protection
Agency.                 . •'  ,   ,:   .  :..•'••  i'.  '.;   ••,'•:"• .
                   Publication No. EPA-450/3-74-056-C
                                   11

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                                 PREFACE





     The Hackensack Meadowlands Air Pollution Study final report consists


of a summary report, five task reports, and three appendices, each bound


separately.  This report is the second of the five task reports.  Its


purpose is to describe the mathematical basis for predicting air quality


levels for the New Jersey Hackensack Meadowlands.  The report discusses


both the development of the model and its validation and calibration.  The
                      '-       '

preparation of model emissions input data is discussed extensively in the


first task report, and the procedures for operating the software components


of the model are discussed in the fifth task report.
                                    iii

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                             ACKNOWLEDGEMENTS








     The work upon which' this report is based was performed pursuant to




contract No. EHSD-71-39 with the Environmental Protection Agency, and




Contract No. IP-290 with the New Jersey Department of Environmental Pro-




tection.




     The cooperation and assistance of the many personnel from EPA and



NJDEP contributed greatly to the success of this study.  The special



assistances of Mr. Roland S. Yunghans, and Dr. Edward B. Feinberg, En-




vironmental Scientists, Office of the Commissioner, NJDEP, and Mr. John




Robson, Land Use Planning Branch, Office of Air Programs, EPA, is



appreciated.
                                    IV

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                             TABLE OF CONTENTS
                                                                      Page


PREFACE



ACKNOWLEDGEMENTS            .                                           iv



LIST OF ILLUSTRATIONS                                                 vii



LIST OF TABLES



SUMMARY                                                                ix




1.    INTRODUCTION                             '                        1



     1.1  Definition of the Problem



2.    DESCRIPTION OF THE DISPERSION MODEL                              3



     2.1  General Comments
                        i


     2.2  Principal Modifications Incorporated in the ERT



          MARTIK Model                                                4



     2.3  Basis of the Model:  The Gaussian Plume Equation            5



     2.4  Geometrical Details of the ERT/MARTIK Model                 17



     2.5  Operation of the Model                                      27



3.    DATA USED IN THE MODEL ANALYSES                                  29



     3.1  Introduction                                                29



     3.2  Meteorological Data                                         30



     3.3  Emission Data                                               37



     3.4  Air Quality Monitoring Data



4.    MODEL VALIDATION PROCEDURES AND RESULTS                          53



     4.1  Introduction                                                53



     4.2  Procedures for Validating Models



          4.2.1  Selection of Data for Purposes of Validation



          4.2.2  Preliminary Runs to Assess the Initial Agree-



                 ment Between' Predicted and Observed Values          53

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                   TABLE  OF  CONTENTS,  contd.




                                                                Page






     4.2.3  Sensitivity Analyses and Identification of




            Possible Model Improvements                        ' 59




     4.2.4  Modifications Made to Model and Final




            Calibration of Model Results                        67




     4.2.5  Final Calibration of the Model                      69




4.3  Discussion                                                 71



REFERENCES                                                      75




GLOSSARY                                                        76

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                          LIST OF ILLUSTRATIONS
Figure                                                            Page
  1       Coordinate System Showing Gaussian Distributions in
          the Horizontal and Vertical                               7
  2       Geometry of the Linear Interpolation Between Adjacent
          Wind Direction Sectors          .                         11
  3       Geometry for Area Source with Dimensions g1  and g? in
          the Horizontal Plane, Shown in the Receptor-Centered
          Wind Oriented Coordinate System                          21
  4       Integration Over Source Cell Area By Summation of
          Elemental Strips from X  to X                            23
  5       Geometry for Determination of Concentration Due to
          Point and Line Sources                                   25
  6       The Four Geographical Zones Used in the Development
          of the Emission Inventory                                44
  7       New Jersey State Bureau of Air Pollution Control
          Continuous Air Monitoring Network                        50
  8       New Jersey High-Volume Sampler Network                   51
  9       Highly Correlated Regression Line Fits                   54
  10      Validation Sites Surrounding the Meadowlands Region      57
                                    vn

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                              LIST OF TABLES

Table                                                             Page
  1       Functions k and d of Stability Class                     14
  2       Glossary of Terms for Area Source Geometrical
          Description                         .   -   ,               19
  3       Values f., r  and r.. for Winter, Summer and
          Annual Time Periods                                      62
  4       Vertical Spread Statistic Constants (a  = kxd)           63
  5       Predicted and Observed Validation Data                   70
  6       Ratios of Observed to Predicted Values by Pollu-
          tant and Time Period                                     72
                                   Vlll

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                                  SUMMARY






     This report describes the development and validation of the atmospheric




diffusion model used as the tool for calculating the air quality concentra-




tion patterns expected in the Meadowlands planning area in 1990.  The model




has been designed specifically to operate on the computing equipment of the




New Jersey Department of Health, and the model has been specialized to pro-




vide input data to the ERT/AQUIP program for the evaluation of total antici-




pated air quality impact.  Thus the model is useful both as a stand-alone




tool and as an element within the framework of a total land use planning-




air pollution impact evaluation system.




     The model was run for validation and calibration purposes for summer,




winter and annual time periods using meteorological input data from Newark




Airport and the point, line and area source emission inventory developed for




the year 1969.  Initial comparison of the model results with measured data




indicated that the accuracy could be improved by some modifications to the




model.




     Specific modifications made to the model included the adoption of a




half-life for SO- emissions, the inclusion of dispersive spread statistics




more characteristic of urban areas, and incorporation of wind speed




variations with height above ground.  The final calibration of the model




utilized pollutant measurement data from five stations surrounding the




Meadowlands region to develop calibration factors applicable to the individual




locations and for the Meadowlands region in general.




     The diffusion model development and validation has followed "standard"




procedures wherever possible.  This was done both to assure the future use-




fulness of the model in the Meadowlands area, and to establish a methodology




which might be copied, and improved upon, in future related studies.

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                            1.  INTRODUCTION








Definition of the Problem






     The basic goal of the model development and validation effort has been




the calculation of seasonal and annual average concentrations for the pol-




lutants of interest (S02, CO, NOX, hydrocarbons and particulates) expected




within the planning region for the emission patterns associated with various




possible land use distributions which may exist in 1990.




     An important secondary goal has been the documentation and reporting




of the modeling and validation schemes for two purposes: (1)  so that the




model and its associated data might be used for future studies of expected



air pollution impact in the Meadowlands area;  and (2)  so that the experience




gained in the present applications study might be made available for similar




studies in other regions.




     The model used in this study has been developed from the basic form




described by Martin and Tikvart (1968) , and documented in the report on




the Air Quality Display Model (NAPCA, 1969).   To preserve standard model




notation wherever possible, the definitions of model parameters and variables




adopted in the AQDM have been retained.  However, several modifications to




the Martin-Tikvart model have been incorporated into this study.  The




modifications provide for controllable computational accuracy (as a function




of computation time and therefore cost), and increased flexibility in the




treatment of area sources of various geometrical shapes.  These model fea-




tures are particularly desirable for planning studies, where many different




combinations of emission patterns must be evaluated.  The details of the




model adopted for use in this study are described in Section 2.

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     The model analysis incorporates several types of data: emission patterns,




meteorological data and topographical data are required as model inputs, and




air quality measurements are required for model validation and for the




development of calibration parameters where appropriate;  The details of




the data requirements, and a summary of the data selected for use in this




study, are described in Section 3.




     Section 4 contains a description of the model validation scheme adopted




for use in the planning projections.  Various other validation techniques




which were considered but not used are also described, because they may




have application in similar studies for other regions.



     Section 5 contains a summary statement on the modeling procedures




adopted for use in preparing projections of concentration levels expected




in the planning region by 1990.

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                 2.  DESCRIPTION OF THE,.DISPERSION MODEL


2.1  General Comments .           .                       .

     The model used for the dispersion calculations  is called MARTIK  in  the
ERT program library.  It is a gaussian plume model which follows  the  physical
and mathematical basis described by Martin and Tikvart (1968).  The model
has been modified to improve computational accuracy  for receptors near
           •  •   ' • '  '•..'•  ' .. <*••"•.  -  T'".•.'  '">'. '•:••.'•-    '  .
source areas, to permit tradeoffs between accuracy requirements and compu-
tation time, arid to permit  improved flexibility .in the treatment  of rectangu-
lar area sources of any size and location.
     The model has also been specially modified to permit  its use on  the
RCA SPECTRA 70 computer operated by the New Jersey Department of  Health.
                      l'
Specially designed data storage and data  flow routines have been  developed
to comply with the core limitations of the SPECTRA 70.  Also, the model
input and output routines have been integrated into  the AQUIP software
system (for example, the LANTRAN  program which computes emissions source
distributions from given planning parameters, and the SYMAP computer  graphics
program, which provides general display capabilities for land use, emissions
and air quality data).
     Detailed descriptions  of all programs, including the  version of  the
                                     . -   -  i                                  .,
MARTIK program used in the  present study, are presented in the  User's Manual
document.  Readers interested in detailed reviews or operational  use  of  the
model should refer to the User's Manual,  as a supplement to the following
text.
     The  general  MARTIK program provides for calculations both  in an
averaging"mode and in an instantaneous mode.   In the instantaneous case,

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fixed values of the meteorological parameters (wind speed and direction,



and stability class) are used, to determine the concentration pattern



expected at a specific time.  The description of the model in this section



is restricted to the time-average mode, because the planning forecasts



required are the seasonal and annual average cases.
                                                •




2.2  Principal Modifications Incorporated in the ERT/MARTIK Model





     The principal modifications of the basic model reported by Martin and



Tikvart (1968), incorporated into the ERT/MARTIK model are listed here.





     1.  Treatment of Area-Source Emissions
     A major improvement of accuracy of representation was made by replacing



the virtual point source approximation to area source emissions with a



numerical integration procedure over the area source.  The use of a virtual



point source representation for area sources results in a "sawtooth" concen-



tration profile in the crosswind direction at short distances downwind from



a group of area source cells.  The numerical integration scheme avoids this



difficulty.  The integration is accomplished by summation of elemental strips



of the area source and may be used for any specified source height and any



wind direction.  For efficiency of calculation, the computation routine uses



fewer elemental strips when the source receptor distance is large and where



finer elements would not significantly change the computed concentrations.



The maximum number of elemental strips to be used is externally specified



as part of a set of input parameters which control computational accuracy.





     2.  Treatment of Line-Source Emissions




     Emissions from roadways may be represented as if from line-type sources.



In order to estimate the downwind concentration from these sources for any

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possible wind direction and elevation, another numerical integration routine




was developed.  This procedure involves approximating short segments of the





line representation with upwind virtual point sources.  In a manner similar




to that of the area source integration, the number of virtual points per




unit length used depends upon the distance to the receptor and the accuracy




selected.





     3.  Flexibility of Operating Mode and Output Format





     A major feature of the MARTIK system is the ability to isolate the




contributions to the concentration at receptors by simp]e choices of input




parameters.  Thus, for example, the contributions from individual sources,




wind directions or stability classes may be easily isolated.










     4.  Computational Efficiency Features





     In addition to the controlled accuracy capabilities discussed in terms




of the integration routines for line and area type sources, a number of




other specific improvements have been made to keep computation time low.




These include:  (1) input specification of argument value ranges for which




exponentials may be approximated by simple functions;  (2) simple inverse




scaling of concentration contributions as a function of wind speed, for




sources with  zero effective plume rise; (3) optimization of the number of




source-receptor geometry calculations for a given run.
2.3  Basis of the Model:  The Gaussian Plume Equation






     The model calculations are based upon multiple applications, and inte-




grated forms, of the gaussian plume equation which represents the concentra-

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 tion pattern downwind from a point source.  The general form of the equation


 is
 where
                              exp  _




                  •    exp [-1/2 (i-^Ji )  ]  t exp [-1/2 (i-i-S. )  ]   J.     (1)
                                   ° z                     °z
      (x,y,z)      are the (upwind,  cross-wind and vertical)


                  components  of a cartesian coordinate system,  such


                  that the receptor point is located at or vertically


                  above the origin (expressed in units of length)  and


                  the source  at the point (x,y,H)


          H       is  the effective  height of emission and therefore


                  the centerline height of the plume (length)




          q       is  source strength (mass/time)




     a , a        are dispersion  coefficients  that are measures of


                 cross-wind and  vertical plume spread.  These two


                 parameters are  functions of  downwind distance and


                 atmospheric stability  (length)


         u       is average wind speed  (length/time)




     Figure 1 illustrates the geometry for the plume equation.   The source


base is at z = 0 in the coordinate system, and the plume center-line reaches


an equilibrium height H at some distance downwind from the source.

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(x,-y,o)
                                                    (x,o,o)
                                                                        Plume Axis
                                                                         {downwind)
                                                                                       y
                                                                                 (crosswind)
                                         X   (upwind)
               Figure  1   Coordinate System Showing Gaussian Distributions
                          in  the  Horizontal and Vertical

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 The most  important assumptions upon which the equation is based are the

 following:


      1.   The  wind  speed  and  direction  in  the vicinity of  the  point  source

 are constant  throughout  the  period of  interest.


      2.   mien the  effluent enters the  atmosphere,  the plume rises until  it

 reaches an  equilibrium altitude; the plume  er-nterline height  remains  constant

 at all downwind  distances after the equilibrium height is reached.


      3.   At any  downwind distance, the maximum concentration  occurs at the

 plume centerline.  The distribution of concentration values off the center-

 line  is given by the  product of two gaussian, or bell-shaped  curves.


      4.   The  concentration profiles described by the gaussian form  arc not

 "instantaneous"  plume profiles.  Instead  they represent concentrations

 averaged  over a  short time,  such as 10 minutes.


      5.   None of the  effluent is lost from  the plume.  Therefore when the

 plume boundary intersects the ground surface, it is assumed that all material

 is reflected  back  above  the  ground.


     6.   The effluent emission  rate  is  constant,  and the  meteorological

parameters determining plume  form  are  constant; (i .e. ,  the equation represents

steady state conditions) .

     Ground-level concentration estimates are obtained by setting  z =  0 in

Eq.   (1),  resulting in
                                            2                  2
       X(0,0,H)   =   ^-u  exp [-1/2 (Jl)  ]  exp [-1/2 (~ )  ] .      (2)
                       y z               y                  z

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     Eq.  (2)  can be modified to yield estimates of long-term average




concentrations (e.g., seasonal and annual concentrations), when applicable




stability wind rose data are available.  A stability wind rose is a tabula-




tion of the joint frequency of occurrence of wind speed, wind direction and




atmospheric stability category at a specific location.




     Although the probability of all wind directions is a continuous function




over the long time periods, for computation purposes discrete wind directions




are specified with respect to a 16-point compass, corresponding to 22.5




angular sectors.  For annual periods it is often assumed that all wind




directions within a given 22.5  sector occur with equal frequency.  Thus




the effluent could be assumed to be uniformly distributed in the horizontal




within the sector.  However, this assumption would result in discontinuities




in calculated .concentrations at sector boundaries.  A more reasonable distri-




bution is obtained by using a linear interpolation between sector center




lines.  In this case, the concentration at a given receptor location is




composed of proportional contributions from both the sector containing the




receptor and from the nearest adjacent sector.  The linear interpolation




term is given by




     K(c-y)/c,






where



     y   =   crosswind distance between the receptor and the sector




             centerline




     c   =   sector width at the receptor location = 2x tan (11.25 ) -




             0.398x



     K   =   a constant to be determined

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      The  geometry  of  the  interpolation  is  illustrated  in  Figure  2.   Note

 that  an SSW wind affects  the  receptor to the  NNE  of the source.

      The  linear interpolation is  applied to the crosswind integrated form

 of  the ground  level plume equation,  and the constant K is determined by

 the condition  that, when  the  frequency  of  occurrence of wind direction is

 the same  in all 16 sectors, the  long time  average concentration  at  any

 given downwind distance away  from the source  must be the  same, regardless

 of  direction.  Therefore,
 and  the  time-averaged  equation used  in  the  computations becomes
                              exp  [-1/2  (^ ) ].                         l  }
                 U     'c"             '  '  2  ••  ••     '         •'  '


      It  should be noted  that  Eq.   (3)   is  different  from  the analogous

 equation in AQDM by  a  factor  of '(2irx/16)/c w 0.99.

      Vertical diffusion  of  the plume is inhibited by the  existence  of a

 stable atmospheric layer having a base  lower than the effective  stack height

 (the  layer elevation will generally range  between 100 and 3,000  feet).  The

 rate  of  vertical mixing  is  greatly reduced in  such a layer, and  the base

 of  the layer can thus  be considered as  an  effective  "lid" on vertical trans-

 port  of  pollutants..         ,             ...,.-

     When an elevated stable layer occurs  locally,  the estimated pollutant

concentrations  can be calculated with the assumption that  all  the effluent

remains within a mixing layer  depth D defined as the vertical  distance from

the ground to the base of the  stable layer.  For the mode.l calculations,
                                    10

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North
                                                                           East
         Figure 2   Geometry of the.Linear  Interpolation
                    Between Adjacent Wind Direction Rectors
                                     11

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 a  is considered to increase in the downwind direction until it reaches a

 distance x,,  at which a  = 0.47 D.   At this distance, pollutant concentration

 at the base  of the stable layer will be one-tenth that at the plume center-

 line.  Up to this distance,  the gaussian vertical distribution is assumed,

 and Eq.  (3)  is appropriate.     At  distance x  the trapping effect of the

 elevated stable layer begins to be effective, and uniform mixing below

 the base of  the stable layer is assumed to occur at downwind distance 2x_,.

 For distances x >_ 2x_,  the  average concentration is calculated with the

 assumption of full mixing in the mixing layer:


      v   _   Q (c-y)                   - •   ' '            .              (4)
      A   ~~       n   >
               Due


     For distances between XT and 2x •, x is determined by a, linear inter-

 polation between Eq. (3), evaluated at 'x  and Eq.  (4), evaluated at
      For a specific source-receptor configuration, an estimate of x is

 obtained by choosing a representative  wind speed for each wind speed class

 and solving the appropriate  equation for all  wind speed and stability

 classes  appropriate for the  time period in the geographical area of interest.

 The average concentration, x", is obtained by summing all concentrations

 and weighting each one according to its frequency for the particular wind

 direction,  wind speed class,  and stability class.  The average concentration

 is

     X   =   2 Z  I F(J,K,L) X (J.K.L)                                (5)
             K  L  J        .                •

where

     F(J,K,L)=   normalized frequency during the period of interest

                 for wind direction interval K, wind speed class J, and
                                            /
                 stability class L

                                     12

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      X(J,K,L)  =   average  ground-level  concentration  calculated from




                  Eq.  (3)  or  (4)  as  appropriate







      The  total concentration at  a specific, receptor  is obtained by summing




the results of Eq.  (5) over all  sources.  For each of the  16 wind direction




intervals, wind  speed is  defined in 6  categories and stability class in 5




categories.  Thus a three-dimensional  array of 480 categories is established.




(However, only a  few wind directions result in nonzero contributions for




specific source-receptor pairs.  Thus the computation time is reduced signi-




ficantly.)  Vertical variations in wind direction are not accounted for in




the calculation of x«   (However, the ERT/MARTIK model does permit vertical




variability of wind speed in both the calculation of plume rise and of




average transport rates.)




     The representative speeds adopted for the six climatological wind




speed categories  (0-3, 4-6, 7-10, 11-16, 17-21 and >21 knots),  are




0.67, 2.46, 4.47, 6.93, 9.61 and 12.52 meters per second.   (A modification




of the 0.67 value to 0.89 was  later made for purposes of model validation.




This  subject is discussed later  in this report.)





     The five stability categories (L= 1,2,3,4 and 5, in order of increasing




atmospheric stability) are derived from surface level meteorological obser-




vations, as defined by Turner  (1964).  Stability in the lowest part of the




atmosphere is determined primarily by the net heating (or cooling) of the
                                       13

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ground surface, and by local wind speed.  Turner's classification is based




upon surface wind speed, cloud cover and ceiling, supplemented by solar ele-




vation data (latitude, time of day, and time of year); thus the stability




estimates can be obtained for any Weather Bureau station at which continuous




surface  level observations have been made.




     The values of a  (x,L) used in the program are those of McElroy and



Pooler (1968).  For computation these are represented in the power law form
               •  xd,
where
     x   is the downwind distance in meters
and
k and d  are functions of the Stability Class L as given in Table 1.
                                  TABLE  1
L
k
d
1
.072
1.22
2
.072
1.22
3
.169
1.01
4
1.07
.682
5
1.01
.554
                                    14

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     The miriini^m  v&lue  of- ^ used in calculating q_ is 100 meters.   When




x, <  lOO/meters, the  program sets x, =? 1,00 meters, prioi; to the  o   calculation.
                        1 '•        •               ...         •  Z



This simulates  initia.}  mixing, of the effluent by. perturbed  wind  flow  in the




vicinity-of the source,  and* it eliminates £he .possibility of  unrealistically




large values of con9pntr:>.'it:ir.n. corresponding to npar-zcro values of o .




     The mixing layer depth, I),  varies greatly from season  to season,  day




to d\   Since it i.s impractical to account  for all  these




variations! a procedure  reflecting only major changes is used ir) the  model.




The procedure determines  an effective mixing depth hy modifying  the average




aftern.oon mix|n,g  dep£h valuers, as t'atuijnted. hy Hpl^worth (}964), according




to the stability  class be.fn.a considered,.  Stability classes L -  1,2,  and 3




are afternoon conditions,  with L =* 1- corresponding to very  unstable condi-




tions.  When I- w  lh  the  va|ue of 1,1 i,s asstped ^o be 50?n greater  than  the




climatologies! value, tabulated by Holzwflrj:h;. when I = 2 or  3,, the cjimatolp-




gical ya,lja.e $$, adopted1.   Aecording to Turnery's critteria^ L  *  5 c.an  pcfur




only when nighttime  ground-based, inversion conditions exist.  Since a




shallow layer of  neutral  or weak lapse conditions has b^en  found to occur




over urban areas  (pv.en with strong nocturnal surface inversions  in  the




surrounding rural .areas),  a mixing d.epth af D =s. ]00 meters  is adopted for




stability cl'ass L ~  5,. wt|en this class is indicated b,y the  Jurner selection




rules.  The- :1.00rrme:ter yaltje \s. based upon observations of Clarke  (1969).




Stability clas.s L •«=  4 is  a neutral stability condition which  occurs either




with high wind, speeds during the day or with high negative  net radiation




during the night.  The^ mixing depth for stability class 1*4 is taken




to be 80v .o.f the  c.l:ini.ato.logi(;al  value (class L = 3.) and 20% of the  class




L = S value.
                                     15

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     The  effective stack height>  appearing  in  Eq.  (3) is defined as the



height of the plume centerline when it becomes  horizontal.  Thus h = h  + Ah,
                                                            . i.   . .   .     s
    •. .• .   ,   .,  .: ,'   f "•• ..'. ;  . '• ••.••.'.. '•'    ••    •-'•':''  "•• • ... For shqrt



stacks, and for line and  area, sources, .this .correction is rn.o.t--, important ,.



but it is significant for elevated point  sources., .For the. rnode.1.  studies



reported  in this document,  the value qf u,* was obtained ...from   ,i; ;.. ...;/
     u



where
              wind speed measured at height z  ,
                                      16

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     z,  =?   6.0 meters, which  is  the  height  of the  standard anemometer...



             at Newark Airport


and  e   =   0.2      .        '


   ^


     The plume rise equation is appropriate for the  neutral  stability condition,


but it must be modified for application over  a  range of stability conditions.



The following modification is used  to  allow for a  range of from 1.3 Ah for


very unstable conditions to Ah  for  neutral stability.





     h   =   h  + Ah  (1.4 - 0.1LD..




     The Holland plume rise equation Eq,.  (-6)  frequently underestimates the


effective height of 'emission; thus  its .use often .provides  .a  slight "safety"


factor.  For .some point spurees (e.g.., power  plants  .with ta.lj  stacks), the


effective emission height will be  ab,pve the mixing ;ftep'th when  the mixing


depth is low.  Based  on the assumption .that the p}ume wil;l not disperse


downward through the  stable layer, these  cases  are identified  and eliminated


from consideration -by the .prpgram.  For ,(irea  sources an avenge .•effective
                                                   !

height of emission is estimated, and is ,'^ntered-;as input dat;a,r



2.4  Geometrical Details pf the ERT/MARTIK;;Model




     1.  Treatment of Area Sources
             -          - -  . . .    ( ,


     The treatment of area sources  is  described here firsti  so that the


 geometry defined for the area  source  case qan  be  used in  the point and


 line cases  also.  Two types of orientation must b^  consi4ered in the


 description of the .area ;sourc^ case.  These  are,:


          a.  Geographic orientation:  based  upon  nprth--south and


              west directions.
                                     17

-------
          b.   Receptor  centered  wind-oriented system:   based on  the wind



      '•'•'  !  '; direction categories'reported  in climatological data records.




     The symbols used in the description of  the area source case  are defined
                                                                     :\


in  Table 2.




     The downwind concentration  ;x :(o.,:o.,z.).. at: the .receptor .point '(0,0,2)



in. the, w.ind-orie.nted coordinate system-, is! given;-for .a'paint source- located



at ,(x,,y,H). by  the. Giffo:cd-.pasquill :fprmula i(Eq.  4} .•<<;:••;.:  ;••.-  •-.•'•••:<..•".





     In the case of the  an  area source,  the  contribution  of each element



of  area is summed in the integration  over area:




                    r    r     QACx,y,H)                    2        '

       xCo,o,z)  =  / dx   dy   ,-£	  exp \-  1/2 (-£-)  1
     .              ./    ./, „... ,2ir. a. a   u   . -^.  ; •  .... .a-. ..  ••-.. ,; ••   .  ....'.:  .•:•;.
   -..•."  •'•'.;• .•:•-•. V..:!1..- J ' ..;:,'.....: V 'Z'.  '  ... 1-.•'•>•./• ••  v   J
. V.. :>.'.; *l ' :;;':','.....'•: y

      y
                                                                             (8)
    ' . •    ..' • •-. ,:.  j  - '. • jf.v,:. •  '.'.'!•  :•'•-.•   V :'  '•'<.'"  ,'•  .

     In  the present application, a rectangular  area source  is  assumed,




with  a'uniform'Source distribution' Q'.   See Figure 3 for  the  geometry
                                        i\

                  ;;.?:,r '. ^/r-.-i ;  , ;.: '.--'ri •"' ":-'i:> -:.- :.-";--  ,'-1:..' M I  ;':•::.•  •: '  ••:'•'•••.• i

applicable to this discussion.  Eq.  (8)  becomes:






              /X2                             /max



              d*2. a  a  u    FZ(Z'H'X)    /  dy.«?,.- "V? ^    . • •
                      y z                  ^   ..-':'.i. -..'...''.^'.    .y •  .....'
                                            y
                                             mm
where
                                  2
                                      18

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                                 TABLE 2
          GLOSSARY OF TERMS FOR AREA SOURCE GEOMETRICAL DESCRIPTION
RH, RV    receptor coordinates in horizontal (east-west) and vertical
          (north-south)directions, meters (system a)
SH, SV    horizontal and vertical coordinates of the source center,
          meters (system a)
g,         dimension of rectangular area source in horizontal (east-
          west) direction, meters (system a)
g~        dimensions of source in vertical  (north-south) direction,
          meters (system a)
x         upwind direction and coordinate, meters (system b)

y         cross-wind direction and coordinate,  meters
          (system b)

x,, x_    projection of maximum and minimum cell extent upon x-axis,
 1   i.
          meters (system b)
y ->-y      parallel  lines y = y(x) defining boundaries of cell  (system b)

8         wind source direction angle, measured clockwise from vertical
          (north) direction, radians
u         wind speed, meters/sec
o  ,a      variances of plume concentration  in x,y direction, meters
 x  y
c,d       coefficients for determination of a  in meters
                                             Li
z         receptor  height coordinate, meters
H         source height coordinate, meters
X         integrated concentration due to source distribution  in source,
          g/meter
          point source emission rate, g/sec
                                      19

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                              TABLE 2  Contd
Q.        source emission density for source (assumed uniform),
                 2
          g/meter -sec for area source
V         transfer function:  concentration due to unit
          source distribution (seconds per meter):
          X = Q-V
Ax        increment in x for numerical summation along down-
          wind axis, meters
M         number of x increments within source
N         number of x increments in maximum .downwind
          displacement
                                    20

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                  Crosswind  A

                  Position
       Receptor


          Point
                                                                                  X2


                                                                                  Upwind

                                                                                  Position
       Figure 3   Geometry  for  Area Source with Dimensions g  and g  in the Horizontal

                  Plane,  Shown  in the Receptor-Centered Wind Oriented Coordinate  System
o
r-
                                                 21

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and y    and y .  ,  the crosswind integration limits, are functions of the
     max      mm


integration variable x, and represent the intersection of the midpoint of



the elemental strip with the geometrical boundary of the area source.



Computer realization of Eq. (9) may be efficiently achieved by sum-



mation of elemental strips (see Figure 4) from the limits x  to x .



Note that if Xj is negative, the limits are from 0 to x , and that if



x? is less than or equal to zero, the entire source is downwind of the



receptor point, and the integral vanishes.



     For numerical evaluation the integration over x in Eq. (9) is



replaced by a summation over a total of M discrete intervals from



x.. to x«.  With this substitution Eq. (9) becomes
                 M
x. = v = —
0.      u
 A
                                                                         U0)
where
     F  =
      z
            2ir a
             1

             D'
                  exp
                                                                2-,
                            [-1/2  (fi)  ]*«,  [-1/2  tfS
                                                                        ClOa)
                                                             x > 2 x™,
     F  is given by a linear interpolation between the two cases



        above for x_ < x < 2 x™.



     D  = mixing layer depth
 and
     x_ = trapping distance, such that a  = 0.47 D.
                                   22

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          Crosswind
              Direction
                           y
                           4
        Receptor_
          Point
                                                                                  Upwind
                                                                                  Direction
                   Figure  4    Integration Over Source  Cell Area by Summation
                               of Elemental Strips  from x  to x_
N
1-
in
                                                 23

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    In this area source case the y-interpolation function, F  in


Eq. (10), is given by the following integral form  (see Figure 5),



                      "iiaA


                                       ly-y'l
     F (x) =
      y
                max


      -i      f

      "e     J
                     rain
                                               dy'
                                                                       (11)
or
                   ycf(y   ) - ycf(y  . )   ,  (y    , y  .  of same sign)
                   J   v"'viiov/   J   w mi r\'   *  wTnav*'rn-ir\
                        max'
                               mm
                                         max
      F  (x) =
       y
                   ~ycf(ymax) + ycf(ym. J   ,  (ymax, ymin of opposite  sign)
                                     mm
where
ycf (y) =
                  y

                 j
dy = y - %r,
                                           0 <  y < c
                 ycf(y) = 1/2,            y > c



     In order to avoid insignificant computations, several tests are



provided in the program to cut off the summation indicated in Eq.  (10),



or to bypass terms whose contribution lies  below a threshold value.





     2.  Treatment of  Point and Line Sources
     The concentration x(°,o,z) at the receptor point  (0,0,z) in the



wind-oriented system is given for an elemental point source at x,y,H



by the Gifford-Pasquill formula (Eq. 1).



For a line source distribution, the concentration at the point (0,0,2)



is thus the integral along the line of elemental strips of length da
                    x2,y2
     X(o,o,z) =

     line
                 r
                J
                                                                      (12)
                   Xl'yl
                                      24

-------
                Crosswind Direction
                                                  Virtual Point Source
                                                                               Upwind


                                                                                  Direction
                    Receptor Point

-------
                           1  ,z-H,2        r   1  sZ+H,2-}-,

                         -  2  (— }   +  6XP [-2  <>— )  J}
                               z



where Q.(x,y,H) becomes  the  line  source  emission density in g /m-sec.
        lj                                                 '


     The  concentration  for constant  emission density Q  may be written
                                                       LI


as :
                 Q     X2'72

     X(o,o,z)  =  -k     /   V(o,o,z;  x,y,H)  d£                          (13)
with the transfer  function  V given for time average calculations by
     V(o,o,z; x,y,H)  =  F  (x,y)    FZ(X,Z,H)
where
    c(x) = 0.398  .x



      with  F2  as  given in Eq.  (lOa) .



      The numerical  integration of Eq.  (13)  is obtained by representing



the line integral as  a summation  over  a  set  of M virtual  points,  and



displaced, upwind by an amount  which  increases the sector  width c  by
                         M
        QL      y
,o,z)  = —- A£   *-<
     X(o,o,z) = —- A£    *-<  V(o,o,z; x,, y  , H)

     line               k?l    .    •-   k   k



The modified sector width c' is then given by




    c1 = 0.398 •  x + |Ay| .'    ,    .
                                     26

-------
     The geometry for determination of x(o,o,z) due to a point source




at (x,y,H) is shown in Figure 5.  For point sources, y is determined




by straightforward solution of Eq. (lOa)




     X(o,o,z) = J -  Fy(x,y.) Fz(x,z,H)






with q the total source emission rate in grams/sec and F  and F  as




defined in Eqs. (lOa) and (13a).
2.5  Operation of the Model







     A detailed description of the operational instructions for the model,




including specifications for input data and interfacing with the data output




routines, is contained in the User's Manual.
                                        27

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                    3.  DATA USED IN THE MODEL ANALYSES









3.1  Introduction






     Three principal types of data are required for any atmospheric disper-




sion model analysis.  These are:





     1.  Source Data





     Emission data for all pollutants of interest must be available.  Five




pollutants were considered in these model projections: S02, CO, nitrogen




oxides, particulates, and hydrocarbons.  The emission data log may contain




a combination of point, line and area sources.  Information required for




each source includes emission rate, location of the source, and engineering




data necessary to determine plume rise.






     2.  Transport Data





     This generally includes meteorological data and information on ground




topography in the region of interest.  The model requires climatological




records indicating the joint frequency of occurrence of wind speed, wind




direction, and atmospheric stability classes, appropriate for the model




region.   The influence of topographic features is  generally treated by




appropriate modifications to available wind speed  and direction data.




In the present analysis,  data from Newark Airport  were judged  to be rep-




resentative of the model  region and were used without modification.





     3.  Concentration Data





     Air quality measurement data must be used for validation of the model




calculations.  If it were possible to model atmospheric transport and dis-




persion processes with great reliability, it would not be necessary to




incorporate ambient atmosphere monitoring data in  the model program.





                                     29

-------
However, current capabilities with models require direct evaluation of




model results to actual measurement data.  For the present study an array of




air quality monitoring data gathered by the New Jersey Department of Health




at several locations near the planning region was used as the basis for




model validation.




     This section of the report serves three purposes:  First, the criteria




for selection of the appropriate data of each type are identified.  Second,




the actual choices of data used in the present study are identified.   Third,




suggestions concerning other possible uses of data to support the modeling




effort are summarized.  Reasons for rejection of these analyses in the




present case are also identified.  It is hoped that the discussion of




criteria for data selection, and the suggestions for use of alternative




data types may be useful to other investigators involved in similar modeling




studies dealing with air pollution impact expected in areas under planning




or development.






3.2  Meteorological Data






     1.  The Uses of the Meteorological Data in the Model Study





     Three separate uses of meteorological data arise when a modeling project




is undertaken.  These are:





         a.   Initial Definition of the Influence Region





     The influence region for a study area is defined as the geographical




region containing the emission sources responsible for at least 90% of the




ground level concentrations (averaged throughout the study area)  of all pol-




lutants considered. Emissions data from the entire influence region will be




included as  input data to model calculations.
                                     30

-------
     The meteorological data required to determine the influence region is




either a stability wind rose (expressing the joint frequency of occurrence




of wind speed, wind direction and stability class) or a simple wind direc-




tion rose.  The most important meteorological information entering the deter-




mination of the influence region is the frequency of occurrence of each wind




direction in the vicinity of the model region.






         b.  Model Validation






     The full set of meteorological data required for model calculations (i.e.,




a stability wind rose) must be available for the time period used for




model validation studies.   In the present case validation was carried




out for the 1969-1970 period, and the 1970 meteorological data was used




as input to these model calculations.






         c.  Model Projections to Future Times





     The desired output from the model calculations are estimates of air




quality corresponding to land use patterns expected in 1990.  The meteoro-




logical data input to the model should represent stationary values, not the




record of a single year.  In this study a 10-year average record of meteoro-




logical data has been used for the projection studies.





     2.  Criteria for Selection of Meteorological Data





     There are three principal criteria for the selection of meteorological




data for model use:  representativeness, reliability and completeness.  A




final choice* of data will reflect a balance among these three.
                                     31

-------
         a.  Representativeness





     The ERT/MARTIK model, in common with all gaussian plume dispersion




models, normally employs a constant set of meteorological parameters through- .




out the model region.  Therefore the climatological data used in the calcu-




lations must be chosen for good representativeness within the region.   (It




should be noted that there ore no wind trajectory data available on a clima-




tological basis which might be used in the calculations.  Therefore, if the




model were modified to incorporate variable winds and stability within the




planning region, there would be no suitable input data for calculations.)




     The requirement of representative meteorological data demands that an




observing site close to or in the planning region be chosen,  and that the




site have exposure (relative to local  topographical features) which is




typical of conditions within the planning region.  When topographical  features




change significantly within the planning region,  model sensitivity calculations




can be used to estimate the range of error associated with this variability.






         b.  Reliability






     The requirement of reliability in the meteorological data normally




favors the choice of records from official National Weather Service observing




stations.  When data from other sources is considered, the questions of




instrument exposure and calibration in the field should be investigated




carefully.





         c.  Completeness




     Records from first order National Weather Service stations will normally




be complete and available.  Since a multiple-year average is  required for
                                     32

-------
model projections, the availability of such an extended record should be




investigated before any meteorological data from other sources is used.






     In summary, the usual choice of meteorological data will be that of




the most representative, long-term record available from a local National




Weather Service observing station.  Other sources of data may occasionally




be chosen because of better representativeness within the model region, but




such data must be reviewed carefully for reliability and completeness before




it is selected.






     3.  Data Selected for Use in the Present Study





     After a review of several possibilities (discussed in the following




section) it was determined that the National Weather Service records for




Newark Airport should be used as the meteorological data input in this




study.  The Newark Airport location is approximately 5 km from the south-




western corner of the Meadowlands planning region.




     For determination of the influence region the  Newark wind direction




rose data for 1956-1965 were examined.




     For model validation studies, the stability wind rose data (available




as output from the STAR program at the National Climatic Center, Asheville,




North Carolina) for the Calendar Year 1970 were employed.



     For model projections to 1990,  the STAR program climatological  data




for the 10-year period 1956-1965 were used.  This period was selected be-




cause the National Weather Service changed its practice at the beginning




of 1966.  Prior to that time climatological data for each hour was logged




at Asheville.  Since that time data records have been kept on a three-hourly




basis.  The 1956-1965 record represents the most recent, 10-year record of




hourly observations available for use in the model  projections.






                                     33

-------
     4.  Other Meteorological Data and Analysis Methods Considered for




         Use in the Model Studies





     Several other sources of data were investigated for possible use in the




model studies.  The most important are summarized here:





         a.  Secaucus Data





     A limited set of meteorological observations (together with air quality




observations) were taken by the U. S. Public Health Service at Secaucus,




within the planning region.  These data were collected during most of a




one-year period, beginning in March 1969.  While these data have benefit




because of the location of the observations, they were not selected for use




because of the lack of: (1) a complete annual record;  (2) a long enough




record for the 1990 projections; and (3) information on calibration and




maintenance of the equipment...





         b.  New Jersey Air Monitoring System Data





     New Jersey has been operating wind equipment as part of its air moni-




toring system at sites in Newark and Bayonne.  These data were not selected,




because of the greater reliability of the Newark Airport data.





         c.  Teterboro Airport Data





     Teterboro Airport is at the northern edge of the  planning region.




However,  it was decided that the more complete record  at Newark Airport was




a better choice.





         d.  Other National Weather Service Stations in New York and New Jersey





     The possibility of using data from a more extensive array of National




Weather Service stations was considered.   However,  it  was decided that,  to
                                    34

-------
favor procedures readily applicable to other regions, it would be better




to use the single record from the station at Newark Airport.




     In addition to the other sources of data described here, the possibility




of alternative analysis techniques was considered.   These techniques included:





         (1) Use of an average stability wind rose  from two or more




             National Weather Service stations.





             The use of such average data would favor a better represen-




             tation of the entire model region, and would reduce the




             possible impact of unusual instrument  exposures  at a single




             site.  However, it was decided that it is preferable to




             favor standard procedures, and therefore to adopt the data




             record from the single, most representative station (Newark).





         (2) Use of actual mixing layer distributions from JFK upper




             level data or from the Environmental Meteorological Support




             Unit (EMSU) station at LaGuardia Airport.  Standard upper




             level data are taken at JFK Airport, and twice daily vertical




             soundings have been initiated at the EMSU at LaGuardia Air-




             port.  These data would be more representative of actual




             vertical mixing conditions in the greater New York City




             area than the standard distributions of mixing depth adopted




             in the MARTIK model.  However, for the present study these




             data were not used because:  (a) It would be very expensive




             to,compute an appropriate data set from a long-term record.
                                     35

-------
            (b)  The model does not treat the relationship between




            emission rate and meteorological variables (except for




            the basic seasonal differences in emission rates) and this




            limitation makes it unrealistic to attempt greater accuracy




            in the treatment of mixing depth.








        (3) Use of "typical" mesoscale wind trajectories  in the planning '




            region.




            There are no standard approaches available at this time which




            would permit the use of wind trajectory patterns, instead of




            constant wind estimates.  Future model studies may incorporate




            such standard trajectories, but this is a development area at




            the present time.





     In summary, a large number of "nonstandard" meteorological data sources




and analysis techniques were considered for use in the model program.  All




were rejected in the present case, in favor of a standard technique, suited




to the limitations of the model, which can be applied readily in similar




studies for other regions.




     Two ad-hoc modifications to the meteorological data  were considered




during  the model validation studies.  These were (1) the use of lower




wind speeds to represent additional frictional drag in built-up areas;  and




(2) the use of larger nighttime mixing depths, reflecting the urban heat




island effect.  These are discussed in the model validation section.
                                     36

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3.3  Emission Data






     This section discusses the criteria for selection of emission data




used in the model, but not the methodology for development of the emission




estimates.  The general description of the development of the emission data




base is contained in the Task 1 report.





     1.  Criteria for Selection of Emission Data





     Five separate criteria for the selection of emission data to be used




in the model calculations are discussed here.  The final choice of a data




set will reflect a balance among these criteria.





         a.  Accuracy





     Generally the accuracy of the emission data should be related to




the accuracy desired in the air quality projections.  The accuracy of




the model results is usually no greater than that of the input data.








     However, there are three other considerations which determine the




accuracy requirements.  First, because of the uncertainties in other ele-




ments of the model calculations, there is no benefit resulting from improved




accuracy in the emission data, beyond that which matches the accuracy of




the remainder of the model elements.  In the present case (calculations of




seasonal and annual concentration levels in a region with total linear




dimensions of several kilometers) it is not useful to develop area source




emission data for cell sizes of less than one kilometer in linear dimension.
                                    37

-------
In the case of point sources, all sources of smaller size (for example,




having emission rates of less than 100 tons of pollutant per year)  will




have no significant influence upon the long time average model calcul-




ations, except in the case of sources which are near (within 1000 meters)




specific receptor points.





     Second, the accuracy of any set of emission data is controlled by the




reliability of the basic engineering and planning data.  In most cases the




specification of accuracy for the emission estimates is in fact determined




by the availability and accuracy of the basic data.




     Third, more detailed emission data should be prepared, when possible,




for the region near the central planning area.  Because nearby sources




always account for a major part of the average concentrations observed at




a single site, it is useful to treat the near-field emission data with




optimum accuracy.






         b.  Completeness






     The diffusion model requires a complete set of emission data in the



model region.  Therefore the emission data base must include estimates  for




all defined locations.  Because the basic planning and engineering data may




not be complete, a method for estimating missing data, for substituting




"default parameters" for missing information, must be available.






         c.  Consistency






     When emission data is gathered for a large region, the estimates are




frequently based on a variety of sources.  These may  include direct




measurements, fuel use data, process output data, materials balance calcu-
                                    38

-------
lations, heating demands, population density, and others.  It is important




that data from such widely varied sources be examined carefully for internal




consistency, so that local anomalies in the estimated emission patterns do




not result from the variability in this initial data analysis step.






         d.  Geometry and Resolution of the Sources






     The ERT/MARTIK model is capable of treating, at the same time, a




general array of point and line sources, and rectangular area sources of




any dimension.  The basic question to be resolved in the choices among




these source geometries is "How many sources should be treated as specific




point and line sources, and how many should be aggregated with the general




area source data?"




     For calculation of annual average concentration patterns the following




guidelines may aid in the choice of the number of point and line sources




selected for direct representation in the model calculations.





     •   For a single model area the total number of point and line




         sources treated individually will normally be of the order




         of 100 (i.e., between 50 and 200).  If more than 200 sources




         are treated individually in the model, computation time becomes




         large, with little benefit in improved model accuracy.   (The




         basic accuracy limitations of the model prevent useful  reso-




         lution of larger numbers of individual sources.)






     •   It is.useful to treat point and line sources in greater detail




         in the central planning region, where the most accurate concen-




         tration estimates are desired.
                                    39

-------
     •   Smaller sized area sources are also recommended for use in




         the central area.






         e.  Geographical Coverage






     Ideally, emission data to he used in a model calculation should be




available for the entire area which contributes significantly to the observed




or estimated concentrations.  (When such data arc not available, the model




must permit treatment of "background" concentrations, arising from areas




not included in the model calculation.)  The definition and evaluation of an




"influence region" for emissions data is described in the following subsection,






     2.   Estimation of the Emissions Influence Region






         The air pollution concentration observed at a point for a specific




time period is composed of contributions from all nearby upwind sources.




Sources  nearest the receptor point will have a much stronger effect than




those further upwind because of wind direction variations in time, dilution




by horizontal and vertical turbulent mixing, and because of possible removal




and transformation processes.   Therefore, for uniform accuracy of estimate




of the concentration field, the distribution of sources near the receptor




must be  treated in more detail than the distribution further away.




     For efficiency in the determination of an emission inventory,for use




in regional modeling, it is necessary to estimate the extent of the surround-




ing area which includes the significant sources of emission affecting the




receptor concentrations.  The influence region is generally related to the




local meteorology (for example,  skewed toward the prevailing wind direction),




the regional distribution of source strengths, and the pollutant removal
                                    40

-------
or transformation rates.  In order to form a practical measure of the


influence region, the region must be defined as that from which some high


percentage (less than 100%) of the observed concentrations arise.  In this


study the influence region is defined as the 90% contribution area.


     The  influence region must be determined separately  for each wind


direction sector defined in this study by the upwind 22-1/2  wedge-shaped


area whose emissions can contribute, to the concentration at the receptor.


Observed  values of the  wind direction are expected  to be representative of


the average only over a mesoscale range of up to perhaps 100 km.  They


would not be expected to be representative of the average over a synoptic


scale of  the order of several-hundred kilometers.


     For  a continuous distribution of emission density in the upwind sector,


the concentration at the receptor can be expressed  as a function of the


influence radius, R, as



              R   IT/16

     X(R) =  f    /"    Q(r,e)-V(r,6)-T(r) rdGdr                     (14)

            J     J
             O   -TT/16


where

                                           2
     Q(r,6)  is emission rate density  (g/m  sec)


     V(r,6)  is the transfer function relating the mean transport


             velocity and source strength parameters


and


     T(r)    is a decay term related to the source-receptor


             travel time, but expressible as a function of


             distance for a given transport velocity.  (The


             decay term is frequently expressed as  a exponential


             which decreases with increasing time).



                                    41

-------
     Since Q(r,9) is not known at the beginning, the equations cannot be




solved directly, and it is necessary either to solve for the influence



region boundary iteratively, or to .use equation (14) as a qualitative




guideline for evaluating the boundary.  One approach which permits consider-




able insight into the problem of influence region  definition is discussed




here.  If we begin with an approximation of the near-field emissions (i.e.,




those within the first few kilometers) in the vicinity of the Meadowlands,




we can calculate the approximate contribution to the total concentration




from these sources.  Then we can consider the influence from more distant




sources, by assuming (with uniform mixing and no decay) that these sources




will add in inverse proportion to their distance from the Meadowlands.  At




larger distances (for example, greater than 50 kilometers) the effects of




decay or removal processes will become important,  and will cause the impact




of contributions to fall off even more rapidly.  A distance scaling system




can be developed to incorporate these cases and, for the Meadowlands region,




it is possible to make a reasonably good evaluation of the 90% emissions




influence region.  We have concluded that, for the planning region itself,




over 90% of the expected concentrations arise from within the 17-county




interstate planning region, including the counties in Connecticut.  The




only possible important influence from outside this region is the greater




Philadelphia area, which might contribute several  percent to the background




concentrations observed in the planning region.  Because any contribution




arising from the Philadelphia area would have a nearly uniform effect




throughout the planning region, it was decided that this contribution would




be treated adequately by the model validation, and that the incorporation of




a Philadelphia source in the model calculations would not improve the accu-




racy or representativeness of the results.
                                    42

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     3.  Emission Data Selected for Use in the Present Study





     The emission data selected for use in the model study is defined




 ^cording to four geographical zones.  These zones are defined as:






     Zone 1:     Meadowlands plan boundary




     Zone 2:     Outside of Zone 1 to approximately 1 mile beyond the Meadow-




                 lands plan boundary; defined by town lines  except  to the




                 south (Newark and Jersey City, and includes Secaucus).




     Zone 3:     Outside of Zone 2 to approximately 5 miles  beyond  the




                 Meadowlands plan boundary;  defined by town  lines;




                 includes Manhattan in the New York part of  the region.




     Zone 4:     Remaining  New Jersey and  New York  counties  in  the




                 Abatement  Region (1955/1966).




      Other:     Connecticut counties in  the New York -  New  Jersey-




                 Connecticut Abatement Region.







Figure 6  Illustrates these four zones.




     The selection rules for point sources in the model are:






     Zone 1:     All sources with rates greater than 100 tons/year




                 (for any one single pollutant); all stacks  considered




                 to be separate point sources; where stacks  have exactly




                 the same parameters, a stack multiplier notation is used.






     Zone 2:     Same as Zone 1, except all stacks at each source are




                 aggregated into one  (or, more if more than  one pre-




                 dominant set of stack parameters exist) source using




                 the major stack parameters.
                                    43

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                                                                   LITCHFIELD
                                                                  CONN
N  E  W     Y/O  R  K
              JE  R^SEY
                                7
     (URLINGTON       ,              / I


    Figure 6   The Four Geographical Zones Used in the Development

               of the Emission  Inventory
                                     44

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     Zone 3:     Same as Zone 2, except much of the data are estimated




                 according to fue] use, process output and other para-




                 meters .






     Zone 3:     Manhattan -  Same,  except for cutoff at 500 tons/year




                 The area sources for Manhattan have greater emissions




                 than other areas; therefore, 100 tons/year is less




                 significant as a point source.






     Zone 4a:    Remainder of Bergen, Passaic, F.ssex, and Union counties-




                 Same except for 500 tons/year cutoff.






     Zone 4:     Remainder of 17 county region -  Same except for




                 1000 tons/year.




     Other:       Connecticut counties in 1969 area of Air Quality




                 Control Region - Same except for 1000 tons/year.





     Line sources were included in the model only for major links,  as




identified by the New Jersey Department of Transportation.   For most of




the model case studies,  a total of 50 line source elements  were included.




Line sources were included explicitly only in Zones 1 and 2.   In the other




regions, all line source data was aggregated into the area  source distributions.




     The area source data has been organized as follows:





     Zones 1 through 3 fand part of Zone 4):





     Area cells of 8 x 8 km dimension were used for general calculations.




     Sensitivity studies, and detailed studies in the vicinity of the




     Meadowlands region  used  1x1, 2x2 and 4x4 kilometer cells.
                                      45

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     Zone 4:  (The portion which is greater than 8 km from the planning
     region)


     Area cells of 16 x 16 kilometer dimensions were used for general

     calculations.



     Counties in Connecticut:


     Area sources were not included. . (Only major point sources were

     included from this region.)


     A more detailed discussion of the choice of emission data, and a

listing of data used in the model studies, appear in the Task 1 report.


     4.  Other Emission Data Considered for Use in the Model Study


     Two other types of emission data were considered for possible use in

the model study.  These are:


         a.  Sources Near Receptors


     In order to investigate the importance of sources very near the

measurement sites (i.e., within the first several hundred meters), a number

of special calculations were performed, incorporating near-field sources.

These investigations were directed in particular toward the question of the

influence of adjacent roads on the measurements of CO, NO,, and hydrocarbons,

It was decided that, for the long time average cases being considered, it

was not necessary (nor possible) to incorporate the influence of emissions

from adjacent, medium-duty roads.

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          b.   Sources Correlated With Meteorological  Parameters






      Many sources have nonzero correlations  with the meteorological  para-




 meters treated by the model.   For example, winter space  heating  demand  is




 above average on days with  northerly winds.   Also, motor vehicle emissions




 are greater  during the daytime, when mixing  depths are greater.




     Model accuracy  would certainly  be improved  if the joint frequency




 distribution  of  meteorological  parameters and emissions rates were treated




 specifically.  However, it was  considered to be  outside the scope of the




 present work  to  accumulate the  necessary data base,  and to make  the required




 model  modifications,  in order  to  include this improvement.  (However, it




 should be noted  that  gross meteorological variability related to winter-




 summer differences in  emission  rates was included specifically in the model




 studies.)





 3.4  Air Quality Monitoring Data






     1.  Criteria for Selection of Air Quality Data




     Monitoring data must  be used to evaluate and refine  the performance of




the diffusion model and  its input data.   In  most cases the principal




criteria for selection of  monitoring data for model validation is availability:




the total number of monitoring sites in any single region is usually  very




limited.  The Meadowlands  planning region itself dr.es not contain any con-




tinuously operated air quality monitoring site.   However, there  are  a large




number of monitoring stations, of various types, within  50 miles  from the




planning region.   Also, observations were carried out for a single location




within the planning region,  in Secaucus,  for  slightly less than  one  year in




1969-70.
                                     47

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     Several of the criteria for selection of air quality monitoring data




 are  similar to those for the meterological data, and are mentioned only




 briefly here.





         a.  Representativeness





     The question of representativeness is particularly difficult to evaluate




 for air quality monitoring data.  Mahoney et al (1969), in a study of multiple




 station SO- observations in the Boston region, showed that local variability




 in concentrations (on a scale of 2 miles or less)  is at least as important



 as variability on a regional scale of several miles, in multiple-source




 regions.  Most monitoring stations are placed in areas where high concentra-




 tions are expected, and data from all of these stations will not be repre-




 sentative of the lower concentrations expected in the areas between observing



 stations.



     Because of the small amount of monitoring data available, it is usually




not possible to eliminate data from use because of lack of representativeness.



 Instead, the available data are normally used, with the understanding that



 they frequently reflect near-maximum concentrations in central urban locations,








         b.  Reliability





     The types of monitoring equipment used for all pollutants except particu-



 lates have changed rapidly during the past few years.  Only equipment of



 recent manufacture should be considered of good reliability, particularly



 for the recording'of relatively low level concentrations.  Instrument reli-



 ability is especially important for the examination of long period average



 concentrations, because of the possibility of bias errors in the lower



 concentration ranges.
                                      48

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         c.  Length of Record




     For the present study a full year's record is necessary for model




validation.  Longer records are desirable, to permit checking for internal




consistency in the data, anil to examine for trend:, corresponding to known




(or estimated) emission reductions over the past few years.




     2.  Data Selected for Use





     Data sources evaluated during the present  study include the following:





         a.  The New Jersey continuous air mcrdtoring network, including




two major trailer sites (at Newark and Bayonne) nc;:r the planning region




and other satellite monitoring stations near the region.  The general loca-




tions of these sites are identified in Figure 7.





         b.  The New Jersey high-volume .sampler network, including a large




number of sites in the northern part of the state.  Locations of these




stations are  shown in Figure 8.  Observations are made  for one day each




week at these sites.





         c.  The 38 station air quality monitoring network operated by New




York City.





         d.  Data obtained at Secaucus by the U. S. Public Health Service




between March 1969 and February 1970.





         e.  Measurements during the summer of  1966 made ir, support of the




New York-New Jersey Interstate Abatement Activity.





         f.  Other data in southern New York and northern New Jersey avail-




able in the National Acrometric Data Bank.





     Several types of data from these sources were employed during trial




calculations, and were examined extensively during initial validation studies,







                                     49

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                                                               Morristown
      Phillipsburg
         Somervifle
Jems Grove
\ncora
      Paterson

      Hackensack

      NEWARK TRAILER

      Jersey City


BAYONNE TRAILER
Elizabeth

      Perth Amboy
         Camden
         CAMDEN TRAILER
         Paulsboro
      Asbury Park

      Freehold


      Toms River
                                                            •Atlantic City
                  Figure 7   New Jersey State Bureau  of Air Pollution
                             Control  Continuous Air Monitoring Network
                                                50

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                                                             Orange
Dover-
Morristown
Livingston
Irvington
Newark
Roselle
Linden
Rawray
Somerville
Bound Brook
Rutgers
Edison
Sayreville
Trenton I
Trenton 2
Trenton 3
Trenton 4
Trenton A
Trenton B
Ancora
Paterson
Westwood
Passaic
Hackensack
Fort Lee
Bloomfield
East Orange
Union City
Hoboken
Jersey City
Jersey City - Hudson
Bayonne
Carteret
Woodbridge
Perth Amboy
Red Bank
South Amboy
Asbury Park
Roosevelt
                Figure 8    New Jersey High-Volume  Sampler Network
                                                  51

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     For specific calibration of the model, it was decided to use data only




of the same type, (from the New Jersey network) and from locations nearest




to the planning region.  Therefore, data from five stations in the New




Jersey network (Newark, Bayonne, Jersey City, Hackensack and Paterson)




were chosen.  Model calibration parameters were developed for summer,




winter and annual cases/from these five locations.





     3.  Other data considered for Use





     Several combinations of the available monitoring data were in fact



used during the model, validation studies.  These are described in the next



section, which discusses the model validation procedures.
                                     52

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                4.  MODEL VALIDATION PROCEDURES AND RESULTS








4.1  Introduction






     In this section we discuss the approach adopted to validate the air




pollution dispersion model employed for the Hackensack Meadowlands project.




     The primary objective of the validation effort was to assure that the




model adequately predicted concentration values over the time and space




scales of interest and over the range of expected input data values.  For




purposes of definition, a distinction should be made between "calibrating"




a model with observed data and "validating" a model with observed data.




The former operation can be as simple as determining "calibration factors"




defined as the ratio of observed values to predicted values or determining a




least-square regression line relating predicted to observed values.  If the




calibration factors or regression line slopes have values that are not near




unity, or if intercept values imply a negative background pollution level,




there is a strong implication .that the model is inadequately representing




some important phenomena.  It  is important to note in this regard that good




correlation (high positive values of the correlation coefficient) is not




necessarily evidence of realistic modeling of phenomena.  High correlation




can even be obtained when highly variable model results are compared with




nearly constant observed values (see Figure 9a) or conversely, when nearly




constant model results are compared with highly variable observed values



(see Figure 9b).  .
                                      53

-------
                                                                               B
T3
O)
Q>
(A
JD

O
                                                         O)
                   Predicted
                                                                             1
  ./
  /
/
                                                                     ./
                                                                     /
   Predicted
                           Figure 9    Highly Correlated Regression Line Fits

-------
     The judgment of model performance thus needs to include consideration




of the intercept values and slope of the least-squares regression line.




Positive intercept values should have a physical interpretation as the




contribution of "background" levels of air quality associated with emissions




from all the other sources not incorporated in the model.  Non-unity regres-




sion line slope should have a physical interpretation in terms of systematic




over or under prediction of some input parameters.




     Validating a model implies a detailed investigation of the model results




and a comparison of those results with measured values in order to identify




and evaluate discrepancies.  If the model results compare well with the




observed data or if, for the applications to be made, simple correction




factors are deemed appropriate, the model may then be simply calibrated with




the observed data.  On the other hand, if systematic discrepancies are found,




the investigation may suggest alterations of model parameters or of the




model mechanics which would improve the representativeness of the model.




A final calibration is generally required as the'last stage of the validation




procedure to best adjust for remaining discrepancies between observed and




predicted results.






4.2  Procedures for Validating Models






     The procedures for validating models will differ somewhat from applica-




tion to application depending upon the nature and purpose of the study and




depending upon the quality of the available data.  The validation procedure




will normally require a thorough study of the implications of model assump-




tions and the performance of "sensitivity" studies for various input para-




meters.  The following sections describe the various steps taken to validate




the dispersion model- developed for the Meadowlands study.




                                     55

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     4.2.1  Selection of Data for Purposes of Validation






     Because the planning project is concerned with the prediction of air




quality levels within and near the Meadowlands for winter, summer, and annual



time periods, data for validation was chosen for the same time durations.




Model predictions are expected to be most representative in the near region




of the Meadowlands, where the source inventories developed are most detailed.




For this reason, only data from the five monitoring stations nearest the region




were used for validation purposes.  (These are the stations at Bayonne,



Jersey City, Newark, Paterson and Hackensack).  See Figure 10.




     The emissions inventory for the validation study was based on estimates



for the year 1969.  However, among the five stations chosen for validation,



only Newark and Bayonne have data for all pollutants of interest for 1969.




Measurements of SCL, CO and particulates are available for most of 1970 and



the entire year of 1971 at the other three stations.  The trends in average



concentration levels from 1969 to 1971 observed at Newark and Bayonne were




used to extrapolate the 1971 measurements at the other three stations back to



1969 levels.  This procedure permits the use of a much expanded data base in




the validation but introduces some additional uncertainty.  In the final



calibration, because of the additional uncertainty, the calibration factors



from Newark and Bayonne were weighted more heavily than those of the other




stations.   Table 5 includes a summary of the air quality data used.



      As previously noted, meteorological data for 1970 were used in the



validation studies.  The 1970 meteorological data were adopted for use



instead of the 1969 data for the following reasons:



      1.  Because only two stations (Newark and Bayonne) reported concen-



          tration measurements in 1969, all of the initial evaluation
                                     56

-------
                                HACKENSACK
                                MEADOWLANDS
                                DISTRICT
Validation Sites
  Figure 10   Validation Sites Surrounding the Meadowlands Region
                                57

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         studies and most of the validation studies involved comparison



         of model predictions with 1970 air quality measurements, at all




         five of the stations mentioned above.



     2.  The year-to-year variability in the seasonal and annual wind




         rose data at Newark Airport is small compared to the variability




         in concentrations measurements among the five stations used in




         the validation studies. • Therefore it was preferable to intro-




         duce some uncertainity into the meteorological data, in order




         to incorporate all five stations into the validation procedure.




     3.  Although the measured concentration data for Jersey City,  Pater-




         son and Hackensack were extrapolated back to 1969,  these values



         are directly representative of meteorological conditions in



         1970 and 1971.




It should be enphasized that, whenever data, from an adequate network of



air quality monitoring stations are available for the time period of the




emission inventory, the meteorological data from the same time period



should be used.   The use of differing time basis was required in this



case only because of the lack of sufficient air quality measurement



data for 1969.






     4.2.2  Preliminary Runs to Assess the Initial Agreement Between




            Predicted and Observed Values




     Computer runs were made using the point and line source inventories and



a crude area source inventory to make an initial comparison of the values



predicted by the MARTIK model with observed data.  The inventory included





 192 point  sources,  50  line sources and  35  area sources.   The Newark wind



 rose and the standard  Pasquill-Gifford-Turner stability  class  dispersion-
                                     58

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rate relations were used.  These tests indicated that the model generally



overpredicted concentration values of S0_ and NOY.  It predicted spatially
                                        4       A


averaged concentrations of CO and hydrocarbons well, but the individual data



points did not correlate well with the observed values.  Predictions of



particulate levels were in good agreement with the observed averages.





     4.2.3  Sensitivity Analyses and Identification of Possible Model



            Improvements




     A number of model mechanisms which could account for discrepancies



between the calculated and observed values were investigated.   These mechanisms



are listed and discussed here.  Sensitivity tests were made to investigate the



effect of some of the model modifications above on the receptor points chosen



for validation.  Results for these arc also presented below.




     1.   Inclusion of Pollutant Half Lives




      The  gross  effects  of removal processes  for  gaseous pollutants can



be  simulated  by  the  inclusion of an  exponential time  decay  term in  any



one of Equations  2,3,  or  4.   The effect  of  incorporating a  half-life  of



concentration values  to  simulate removal processes was  investigated



specifically  for  the  S0_  emissions.  Test runs were made with  a three-



hour half-life and with  a one-hour half-life.  The three-hour  half-



life caused a 47% reduction of the calculated values while the one-hour



half-life caused  an 85% reduction.
                                     59

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     2.  Refinement of Area Source Grid and Inclusion of Nearby Roadways





     Minor sources in the immediate vicinity of the sampling locations will




have a strong influence on the sampling locations.  In order to improve the




representation, the area source grid was refined into smaller source grids




in the neighborhood of the receptors and roadways adjacent to the receptors




were included as line sources.






     Nine 16-km area source cells in the neighborhood of the Meadowlands




were subdivided into 36 8-km squares and new emission rates were calculated



for the new cells.  The average levels of concentration were not changed



by this alteration, but correlation between observed and computed was




somewhat improved.  Further refinement of the area source inventory was




not thought to be justified using the county-based emission data on area-



type emissions.



     The effect of adding short line-source segments in the near field of



the receptors at Bayonne, Jersey City and Newark was investigated to repre-



sent the effect on concentrations of small but nearby roadways.  The local



contributions increased the concentrations by a maximum of 5%.  As a result



of this relatively small influence and the inability to predict the level of




detail for the year 1990, it was decided not to incorporate the additional



roadways into the final emission inventory.






     3.  Incorporation of the Effects of Correlation Between Diurnal



         Meteorological Variations and Pollutant Emission Rates





     Emission rates of transportation and industrial related pollutants




are lower during nighttime hours.  Because the atmosphere is on the average
                                     60

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more stable at night, models which do not include diurnal variations in

source strength tend to overpredict seasonal and annual average pollutant

levels.  The effect of diurnal variations in source strength combined with

a systematic association of stable atmospheric conditions with nighttime

was investigated by postulating a difference between day and night emis-

sion rates and analyzing the concentration contributions by stability

class.  By definition, occurrences of stability class 5 are only associ-

ated with nighttime conditions.

     The frequency of occurrence of stability class 4 includes the wind

speed and direction statistics of the remaining nights.  If we assume that

the nighttime hours are one half of all hours, and that the nighttime

emission rate is A times the daytime rate, where A is expected to be

0 < A < 1, an estimate of the effects of the diurnal variation of

emission rate on long-term averaged concentrations is given by
where


     X   is the concentration calculated assuming that there is no


         diurnal variability

     f.  are the frequencies of occurrence of stability class i

and
     r   and rM are the fractional times of day and night occurrence

         in stability class 4.


Values of f . , r,, and r  for winter, summer and annual time periods are

given below in Table 3.
                                     61

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                                   TABLE 3
       VALUES OF £.,  TD and r  FOR WINTER,  SUMMER AND  ANNUAL TIME PERIODS
Season
Winter
Summer
Annual
fl + f2 * f3
.041
.243
.130
f4
.703
.489
.617
fs
.256
.268
.253
rD
.655
.525
.600
rN
.345
.475
.400
Values of x were computed for values of A between 0 and 1 for S0« and CO and the




results compared with the measured values.  Although overall reductions of




computed values could be as large as 40%, no improvement of correlation between




observed and computed was found.  For this reason and because of the uncer-




tainty in assigning values to A a decision was made to not include this




correction mechanism in the model.  Since observed correlation was not



altered, a simple scaling in the final calibration seemed to have equal



merit in accounting for the diurnal effect.





     4.  Incorporation of Effects of Correlation Between Wind Direction



         and Emission Rates





     Winter emission rates associated with space heating are expected to be



positively correlated with the cooler northerly winds.  Neglect of this




mechanism causes models to overpredict space heating related pollutant levels.



On the basis of the insensitivity of the model correlation results to the



diurnal variability and recognizing the inability to specify the relation



between wind direction and emission rates, this effect was not formally



investigated and was left to be corrected by the final calibration.
                                     62

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     5.  Modification of Dispersive Spread Statistics

     Because of reduced evaporative cooling and increased capture of incoming
solar radiation in urbanized areas, thermal convection from the ground
is more vigorous than in rural areas.  In addition, because of their
built-up nature, urban areas are aerodynamically rougher than rural areas.
These two factors cause enhanced mixing of pollutants and increased plume
dispersion spread rates.  Unfortunately, data on dispersion rates in urban
areas are not as extensive for rural areas.  The study by McElroy and
Pooler (1968) in St. Louis provides some measures of the increased disper-
sion rate expected.  The table below compares the McElroy-Pooler vertical
dispersion coefficients after Koch and Thayer (1971)  with the Pasquill-
Gifford-Turner values.
                            TABLE 4
             VERTICAL SPREAD STATISTIC CONSTANTS (a  = kxd)
Stability
Class (L)
1
2
3
4
5
Pasquill-Gif ford -Turner
k
.022
.064
.150
.270
.372
d
1.44
1.12
.860
.680
.580
McElroy-Pooler
k _j
-
.072
.169
1.07
1.01
d
-
1.22
1.01
.682
.554 |
The net effect on ground-level concentrations of utilizing the McElroy-Pooler
coefficients depends upon the mixing depth and the height of the source
emissions.  For stability classes 4 and 5 and for low-level area and line
source emissions, the McElroy-Pooler a  values will cause concentration
contributions in the near field to be nearly 1/3 the values obtained using
                                     63

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the Pasquill-Gifford-Turner values.  On the other hand, for upper-level




sources, ground level contributions will increase because of the increased




vertical mixing rate.  At some distance downwind (of the order of 10 km for




the prevailing meteorological conditions), material is expected to be mixed




nearly uniformly from ground-level to the top of the mixing layer.  Beyond



that distance the choice of the vertical spread rate statistic does not




alter concentrations.  The net effect on total concentration will therefore




depend strongly on the spatial distribution of the sources.  A comparison




of runs made with both sets of dispersion coefficients for annual cases



showed that the net result of utilizing the McElroy-Pooler coefficients




was to reduce the average predicted concentration for the five validation




receptors by about 40% for S0_ emissions and by about 30% for CO emissions.




     6.   Modification of Assumed Mixing  Depths




     For the same reasons as in item 5 above,  the mean mixing depth for urban




areas is expected to be larger  than that assumed for  rural  areas.   The  dif-



ference  is expected to be largest and to influence  ground-level  concentration




the most under nominally stable atmospheric  conditions.



     Sensitivity test runs were made for assumed mixing  depths of 100,  200



and 300  meters for stability Class 5. Changing  the average mixing  depth



associated with the most stable stability class, from 100  to 200 meters reduced




concentrations at the five receptors on  the  average by about 7%.  This  rela-



tively low sensitivity is caused by the  fact that major  sources  contributing



to the concentrations are in the near field  of the receptor and  within the



distance that the finite mixing depths act as a lid to vertical  diffusion of



pollutants.  Increasing the height from 200  to 300 had hardly any effect on



the five receptors.
                                     64

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     7.  Modification of Airport Velocity Measurements


     Several possible modifications to the airport wind speed measurements

were investigated and are discussed below:


         a.  The low level measurements of wind velocity at Newark airport

are on the average lower than wind speeds existing at higher levels.  This

will have two  (partially compensating) effects on ground-level concentrations,

     The use of the surface level winds in the plume rise equations for stack

emissions causes an overestimate of plume rise and thus contributes to an

underestimate of ground-level contributions.  On the other hand, the use of

the low-level wind speed underestimates the average transport rate for pol-

lutants from elevated sources and thus contributes to an overestimate of

ground-level concentrations.  Concentrations resulting from low-level emis-

sions from area sources or roadway line sources are not expected to be

altered significantly by the variation of wind speed with height.

     To improve the model representation of these phenomena, power law

increases of velocity with height were postulated.  The velocity calculated

for use in the computation of plume rise was


       u  =  U


where

     u    was the value measured at the anemometer height z,,

         and the exponent e is a function of stability class.


Velocities for use in the computation of a "ventilation" velocity were

calculated from the equation

                (h/z )e
         u = u  	i—                                             (17)
                  1-t-e
                                     65

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where




     h   is the effective stack height.




This formula estimates the mean velocity averaged iron < :•. und level to the




plume height.





         b.  The wind speed frequency records ci a?;, i i y : he .lowest speed




cases (calm) as values between 0 and 3 knots.  The avenge wind speed which




really occurs during "calm" conditions (velocities too .Low to be reliably




read by the anemometer) is likely to be skewed toward the 3-l.nct limit.




Instead of utilizing the average of the windspeed class limits (i.e., 1.5




knots) to characterise the wind speed of this lowest  class we chose the




slightly higher value of 1.75 knots or .89 m sec  .  The net effect on long-




term average concentrations is quite small because of the small difference




and the small portion of the time that calm conditions are observed.





         c.  The possibility of simulating an effect  of the increased




"roughness" of urban areas by reducing wind speeds in the lower boundary




layer was considered.  Because the model  was tending  to generally over-




predict, and because this type of modification would  cause the model to




overpredict even further, it was not investigated in  specific detail.  We




note that the incorporation of the power law variation of velocity with




height in the calculation of a ventilation velocity does cause the average




velocity for low level emissions to be lower than the  velocity at emission




height by the factor of l/(l+e).
                                     66

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     4.2.4  Modifications Made to the Model and the Final Calibration

            Model Results


     There were three fundamental criteria used to determine which modifica-

tions or parameter changes actually to incorporate.

     1.  Modifications or parameter charges must be-physically realistic

which requires that parameters chosen must be within the range of experi-

mentally measured values.

     2.  Modifications or parameter changes must be appropriate for use in

the planning year 1990.  This criterion restricted the incorporation of

emission rate dependent modifications such as items 2, 3 or 4 in Section 4.2.3.

     3.  The evaluation of modifications or parameter changes must be based

primarily on their effect on the regionally averaged agreement of calculated

vs. observed values, rather than on agreement for individual stations.  We

expect that measurements at the individual monitoring stations will be

strongly dependent upon the fine details of the location and operating modes

of the nearest (though perhaps small) sources.  Because of the nature of the

applications of the dispersion model in this study, it is more important

that the model predict concentrations accurately over a regional scale rather

than accurately predict concentrations at specific monitoring sites.  By

averaging measured values at a number of sites within a region, the effect

of local sources will be minimized, so that a meaningful'regional average

can be formed.

     On the basis of these criteria, only changes in the meterological

parameters were finally adopted in the model.  The emission rate dependent

modifications were not appropriate for the seasonal and annual average

calculations, and their effects were left to be corrected by the final

calibration.
                                     67

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Sensitivity analyses performed on the meteorological parameters were studied




from the points of view of seasonal variations, differences of influence of




near and far sources, and effects on dispersions fro- lo'-- and high level




sources.  The final decisions on specific changes to 'ie implemented were




based on our best judgment of the results of the se;;si'  \-ii:y tests and




experience in other mode] studies,  've were purposeful;   conservative in




incorporating model changes.  The modifications made arc- listed here:





     1.  A half-life of 5 hours was assigned to S09 emissions.  An estab-




lished procedure for simulating removal processes in large-scale dispersion




studies does not exist.  The problem is complicated by the dependence of




removal processes on precipitation, atmospheric interactions with other




pollutants, and reactions with buildings and other surfaces.  To simulate




average effects of removal processes for SO., a .three-hour half-life is a




reasonable number.





     2.  Vertical spread statistics were adopted from the McIUroy-Pooler




study in St. Louis.  These values better simulate the increased turbulance




expected in urbanized areas.





      3.  Velocities for use  in the computation of plume rise were computed




from Eq.  (16) using  the Newark Airport  anemometer height of 2=6 meters




and e = 0.2.  Velocities for use in the computation of a ventilation velocity




were calculated using Eq. (17) with the same values of z  and e.




     The value of e = 2 was chosen for purposes of validation as a value




representative of the most commonly occurring stability classes..4 and S.
                                     68

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     The value of .89 m sec   was chosen as representative of the wind speed




in the lowest wind speed class and incorporated into the final model vali-




dation runs.






     4.2.5  Final Calibration of the Model






     With the parameter modifications implemented in tiu1 model, final vali-




dation runs were made for the five receptors for the writer, summer and




annual cases.  The results were then compared with the observed or extra-




polated-observed air quality data for 1969.  Table 5 summarizes the observed




and predicted data.  The ratio of the predicted to ''observed" was then calcu-




lated for each station, for each season, and for each pollutant for which data




was measured.  For the sites used in the validation, we recommend the use of




these ratios as simple calibration factors.  For estimation of concentrations




at any other location and, specifically, in the planning region, an average




of the calibration factors for the entire region was derived.  As noted in




Section 4.2.1, the validation air quality data for SO- and CO for the




Jersey City, Paterson and Ilackensack sites was extrapolated backwards to




1969 from the 1971 values.  In order to discount this added uncertainty in




determining a regional calibration factor, the Bayonne and Newark data were




weighted more heavily.  The weighting factors were determined simply by




requiring that the average of predicted and observed values for Bayonne




and Newark sites be weighted equally with the average for the Bayonne, New-




ark, Jersey City, Paterson and Hackensack sites.  Thus, for both predicted




and observed values the regional average values foi- SO,, and CO were deter-




mined by the formula




    p  •    i A         1 /B * VN    VR + VN + VJ + VP + \
    Regional Average =   [	-^	  + 	p	J
                                     69

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                                                                TAB Lii 5




                                              PREDICTS AND OBSERVED VALIDATION  DATA


WINTER !
|

POLLUTANT i Bn>'°;;nC
;j /;•._. ;,v.t,..j ! Cbv.'ivei!
SO, (ppnO i .13"! j .067
'- 1 1 '
HC (ppra) i 1.31 j 2.03
NOX (ppm) .257 j .097
"('articulates (yg/m ) \ 132. / | 77.6
'i 1
SO (iT:-0 ; .041 i .042
^ !
CO (pp-n) ; 1.7J j .97
HC (pprcl i l.rC j 1.S7
i i
NO. fpp;n) .157 i -OSS
s ; i
"Partiu.lstos ing/rr,' > . 7J :) • 09.-:
i |
SO, ipi'M : .C7>/ j .032
CO (r,p.ii !i .:.'•: J • 1.28
nc (pp--) j 1.46 I j..y::
N'O... (p;>;;0 ;' . !94 i .067
A. ' _ ' ; i
"Particuiat.es Cyg/"'-') i S<:-.i i 3.-'.8
: I
.lor-.-
rr,:0:.:tvJ
. JO7
2 , S 3
• f';T
' ' *-
179.9
.0,0
4.S5
l.A.1
. 296
.13(1
2 . '" 2
,' ("sty i N'.-v.:irK !'A*!'rs;i;; j Ifackonsack
•!':u-r\^J* ' . ,-.-J. ,-. i-;J ;U Hc:'t-;:..i ;"iej-.'-.; i ->hscrvf?ci* , i.rt..j ; ,. r . Obs'M'vcJ'* i
i ! : .!'".."' ':' !
.091 • .n:1^ : .OMV .OS'S i .0)1 i .121 | .048
N A. '• .5^0 : ;.'.i? .SJ'O ' 'C. A. i .7:53 N. A.
; ! ! !
v. A, ,i£r- ! .;-.• .:,-! ' r. . A. : .c.s-1 >;. A.
! ' ;
112.0 i UJ.O ; N. A. 101.?, i v,. A. 1 130.1 175.0
.(is: ' .c:.: ..MS .0:; ! .01.3 ! .033 i .012
i 1 '
S.f. ! i.70 3..',3 1.7.5 1 3.07 ; 2.->7, \ 1.27
i '
N. A. j .525 1 .:-.v .^9 j N. •'• . ' .790 N. A.
N. A. j .iJ8 .:^ .U'J j N. A. 1 .1-7 N. A.
i i , j
.or-',, i .Oi-o .or; i-.:o .a::' 1 .075 ! ,o/s
! 1
7.s i ; .'.LI 4. i1"7 , .(•-,' i ' .-' j - -f'^ -----1
• .. i
11?. 0 ! b.l.O 136. ; 84.2 . > '. "' 7 : 142.9
L_ 1 i
 'Extrapolated backwards  fron 1970 ancl 1971 value? to I'JO1.




  values  (except for particulates).




**0bserved values of particulates are 1970 values.




  Observed values for Sayonne and Newark are  1969 values.

-------
where V  denotes the  value  under  consideration  and  the  subscript,




the site location,  '['able 6 summarizes the calibration  i'a.Mors




calculated.







4.3  Discussion






     The final calibration factors for the ilackensafk :  •.-.;; on given in




Table 0 show that the model underpredi cts CO and hydr.v:: rbons ,  and over-




predicts SO., and NO  for all averaging times.   rart.icui.ites arc undorprcdicted




in the summer and in the annual average, hut ovorprcdicted in the winter.




The overall agreement is thought to be quite satisfactory and well within




the accuracy typically found Kith long averaging-tine period projections.




     It should he pointed out that although considerable smoothing of data




is inherent in both long-time averaged predicted values and observed values,




the agreement between predicted and observed values is  not. necessarily




improved by the averaging processes.  Tor example, systematic associations




of emission rates with different meteorological conditions will cause syste-




matic disagreements between observed and predicted values over long averag-




ing times.   On the other hand, agreement is expected to be better when




short-time period observations of air quality (such as  over several hours)




are compared with model projections using observed values of meteorological




conditions (and possibly observed values of emission rates) for input.  Thus,




when strong diurnal effects on concentration patterns arc observed, hourly




values are expected to he well correlated with model -results which incorpor-




ate nighttime and daytime variations in emission rate.  .Since the model




developed in this study is to be used primarily for the  longer averaging




time applications,  it needs to be validated with corresponding long-time




averaged data sets.
                                     71

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                                                  TABLE 6

                    RATIOS OF OBSERVED  TO PREDICTED VALUES, BY POLLUTANT AND TIME PERIOD



c
—


JH
 i ~ '' " 1 Q
J, * \.) — *..»..'-' ( ~
; ... .._ _.. _ . _. i 	
*"0bserved" values for Jersey City,  Paterson  and  Hackensack were  extrapolated  backward  from 1971
 measurements to provide estimates  for  the  emission  inventory  year  1969.

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      There are several reasons why, for the final calibrations,  the deter-




 mination  of a regional-average calibration factor for  each pollutant  and




 for each  season was most  appropriate.   These reasons are discussed below.




      1.   By averaging over the five stations around the  Hackensack Meadow-




 lands,  errors introduced  by the presence or absence of numerous  smal]  local




 emission  sources tend to  cancel.





     2.  The  number of data points did not warrant a least-squares regres-




sion line fit  (note that annual values aie not independent of the summer




and winter values and cannot be used as  independent data points).





     3.  Because the  emissions  inventory influence region  accounts for




nearly all of the concentration observed at a point, and since large changes




in emission rates are postulated for the year 1990, a forced fit of the




calibration lines through zero seemed mandatory;   (i.e.,  a line with a




slope equal to the calibration factor and with a  zero intercept value.)




Only in this way can we be assured that an ncross-thc-board reduction of




all emission rates will result in a tori' \pondinp reduction of predicted




concentrations in the same fraction.





     4.  The  limited amount of data available did not warrant the generation




of a spatially varying calibration factor over the region.  A regionally




varying calibration factor would tend to Has the impact  results  of alter-




native land use plans spatially throughout the region.   Another level  of




study effort with more air quality measurements and emission inventory




detail would be required in order to determine physical explanations for and




confidence in other than a regionally averaged calibration factor.
                                     73

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                               REFERENCES


Clarke, T. F., 1969: "Nocturnal Urban Boundary Layer ove.'- Cincinnati, Ohio."
     Mon. Wea. Rev. 97_, pp. 582-589.
Gifford, F. A., 1961:  "Use of Routine Meteorological 01' nervations for
     Estimating Atmospheric Dispersion,  Nuclear Safety, 2(4), pp. 47-51.
Holzworth, G. C., 1964: "Estimates of Mean Maximum Mixing Depths in the
     Contiguous United States," Mon. Wea. Rev. 92, pp. 235-242.
Koch, R. C.,  and S. D. Thayer, 1971: Validation and Sensitivity Analysis  of
     the Gaussian Plume Multiple-Source  Urban Diffusion Model, GEOMET Report
     No. EF-60, Rockville, Maryland.
McElroy, T. L., and F. Pooler, 1968: St. Louis Dispersion Study, Vol. II  -
     Analysis, NAPCA Publication No. AP-53.
Mahoney, J. R., W. 0. Maddaus and J. C.  Goodrich, 1969: "Analysis of
     Multiple-Station Urban Air Sampling Data,"Proc. of Symposium on
     Multiple-Source Urban Diffusion Models, APCO Publication, No. AP-86.
Martin, D. 0. and T. A. Tikvart, 1968: A General Atmospheric Diffusion Model
     for Estimating the Effects of One or More Sources on Air Quality,
     presented at the 61st Annual Meeting of the APCA, St. Paul, Minn.
NAPCA, 1969:   Air Quality Display Model, National Air Pollution Control
     Administration, Washington, D. C,
Pasquill, F., 1961:  "The Estimation of the Dispersion of Windborne Material,"
     Meteorological Magazine, 90^1063, pp. 33-49.
Turner, D. B., 1969: Workbook of Atmospheric Dispersion Estimates, PHS.
     publication No. AP-26.
Turner, D. B., 1964: "A Diffusion Model  for an Urban Area, J. of Appl.
     Meteor., 3(83).
                                     75

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                                   GLOSSARY









Activity, Activity Level - basic land use and transportat:on planning




     units of intensity of use - vehicles per day on a highway, acres




     of residential land use, square feet of industrial • Jant space.




Activity Index - a numerical conversion factor to transform the level of




     activity specif.i.ed for a land use category into demand for fuel for




     heating purposes.




Air Quality Contour - a contour line in a plane (usually the horizontal




     or vertical) representing points of equal concentrations for a specified




     air pollutant.




Air Quality Criteria - factors used in this study that represent a basis




     for decision-making,  for example ambient air quality standards.




Air Quality Prediction - the calculation of current or future air pollutant




     concentrations at specified receptor points resulting from the action




     of meteorological conditions on source emissions.




Albedo - the fraction of solar radiation reflected from the ground surface.




Ambient Air - that portion of the atmosphere, external to buildings, to




     which the general public has access.




Ambient Air Quality - concentration levels in ambient air for a specified




    pollutant and a specified averaging time period within a given geographic




     region.




Ambient Air Quality Standard - a level of air quality established by federal




     or state agencies which is to be achieved and maintained; primary




     standards are those judged necessary, with an adequate margin of




     safety, to protect the public health; secondary standards are those




     judged necessary to protect the public welfare from any known or




     anticipated adverse effects of a pollutant.






                                      76

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AQUIP  - an acronym  for Air Quality  for Urban and Jndustri :1 planning,




     a computer-based tool for  incorporating air pollution considerations




     into the  land  use and transportation planning process.




Atmospheric Boundary Layer - the  lower region of the .m •:<-;phere  (to




     altitudes of 1 to 2 km) where  meteorological cor;d".  I ens are  strongly




     influenced by  the ground surface features.




Atmospheric Dispersion Model -  a  mathematical procedure for calculating




     air pollution  concentrations that result from a ••:•<: ecif led array of




     emission  sources and a specified set of meteorological conditions.




Average Receptor Exposure -  a measure of the average impact of air quality




     levels on specific receptors; the measure is based on  the integrated




     receptor exposure divided by the total number of receptors in the




     study region.




Background Air Quality -  levels of pollutant concentrations within a study




     region which are the result of emissions from all  other squrces not




     incorporated in the  model  for the study region.




Background Emissions - the emissions inventory applicable to the background




     region;  that is,  all emission sources not explicitly included in the




     inventory for the study region.




Climatology -  the study of long term weather as  represented by statistical




     records  of parameters such as winds, temperature,  cloud cover, rainfall,




     and humidity which determine the characteristic climate of a region;




     climatology is distinguished from meteorology in that  it is primarily




     concerned with average,  not actual,  weather conditions.




Concentrations - a measure of the average density of pollutants usually




     specified in terms of pollutant weight per unit (typically in units




     of micrograms per cubic meter), or in terms of relative volume of pollutant




     per unit  volume of air  (typically in units  of parts per million).

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Default Parameters - values associated with a parameter for a category of

     activities (such as heavy manufacturing) assigned to the activity para-

     meter for a subcategory of activities (such as electrical machinery

     production) when the actual value for the subcatogory is not known.

Degree Days - the number of degrees the average temperature is below 65°

     each day; used to determine demand for fuel for heating purposes.
                                                          v
Effective Stack Height - the height of the plume center-line when it be-

     comes horizontal.

Emission Factor - a numerical conversion factor applied to fuel use and

     process rates to determine emissions and emission rates.

Emissions - effluents into the atmosphere, usually specified in terms of

     weight per unit time for a given pollutant from a given source.

Emissions Inventory - a data set describing the location and source strength

     of air pollution emissions within a geographical region.

Emissions Projection - the quantitative estimate of emissions for a specified

     source and a specified future time.

Equivalent Ambient Air Quality Standards - air quality levels adopted in

     this study to permit analysis of all air pollutants in terms of annual

     averages; in cases where state and federal annual standards do not exist,

     the adopted levels are based on the extrapolation of short period stan-

     dards.

Fuel Related Sources, Fuel Emissions - fuel related sources use fuel to heat

     area, or to raise a product to a certain temperature during an industrial

     process, or for cooking in the house; they produce fuel emissions.

     (See also Non-Fuel Related Sources.)
                                        78

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Fuel Use Propensity, Fuel Demand - the total heat requirement (space




     heating plus process heating) determines the fuel demand; the propensity




     to use a particular fuel or fuels determines the actual amounts of various




     fuels used to satisfy the heat requirement.




Heating Requirements - the demand for fuel is specified in terms of the




     heating requirements:




         space heating - the fuel used to heat area, such as the floor space




         of a school in the winter, is that required for space heating; the




         heat content or value of that fuel defines the space heating re-




         quirement (BTUs, British Thermal Units of heating content).




         non-space heating, process heating - the fuel used to raise a pro-




         duct to a certain temperature during an industrial process or for




         cooking (with gas) in the home is that required for process heating




         or non-space heating.  It is generally not related to outside tempera-




         ture whereas space heating requirements are.




         percent space heating,  percent process heating - the relative pro-




         portion of a fuel or its heat content that is used for space heating




         or process heating defines.respectively, the percent space heating




         or percent process heating.




Impact Measure (or Parameter) -  a quantitative representation of the degree




     of impact on air quality or specific receptors resulting from concentrations




     of specified pollutants.




Influence Region - the influence region for a study area is the geographical




     region containing the emission sources responsible for at least 90% of




     the ground level concentrations  (averaged throughout the study area) of




     all pollutants considered.
                                      79

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Integrated Receptor Exposure - a measure of the total impact of air quality




     levels on specific receptors; the measure is based on the summation




     within the study region of the number of receptors times the concentration




     levels to which they are exposed.




Inventories - the aggregation of ail fuel and process c.-issions sources is




     called the emissions inventory; the components for use with the model:




         current inventory - all sources for 1969




         background inventory - all sources for 1990 not directly related




         to the meadowlands plans.




         plan inventories - all sources for 1990 related to the Meadowlands




         plans; this excludes any source outside the Meadowlands boundary




         and also excludes existing major single sources and the highway




         network.




Isopleth - the locus of points of equal value in a multidimensional space.




Land Use Intensity - the level of activity associated with a given land use




     category, for example the population density of residential areas.




Land Use Mix - the percent of total study region area allocated to specific




     land use categories.




Meteorology - the study of atmospheric motions and phenomena.




Microscale Air Quality - the representation of air quality in a geographical




     scale characterized by distances between source and receptor ranging




     from a few meters to a few tens of meters.




Mixing Depth - the vertical distance from the ground to the base of a stable




     atmospheric layer (also called inversion height).




Model Calibration - the process of correlating model projections with observed




     (measurements) data, usually to determine calibration factors relating




     predicted to observed values for each pollutant.
                                      80

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Model Validation  - the detailed  investigation of model results by comparison




     with measured values to  identify systematic discrepancies that may be




     conected by  alterations  of  model parameters or model mechanics.




Non-Fuel Related  Sources, Process Emissions, Separate Process Emissions -




     non-fuel related sources do not burn fuel primarily for heating purposes




     or do not burn fuel at all; these include transportation sources, in-




     cineration,  and certain  industrial processes; they produce process or




     separate process emissions. (See also Fuel Related Sources.)




Ranking Index - a quantitative representation of the net impact on air




     quality or specific receptors resulting from all pollutants being con-




     sidered.




Receptor - a physical object which is exposed to air pollution concentrations;




     objects may be animate or inanimate, and may be arbitrarily defined in




     terms of size, numbers, and degree of specificity of the object.




Receptor Point - a geographical point at which air pollution concentrations




     are measured or predicted.




Regional Air Quality - the representation of air quality in a geographical




     scale characterized by large areas,  for example, on the order of 50




     square kilometers or greater.




Schedule - number of hours per year a fuel burning activity will consume fuel;




     used to determine heating requirements.




Source - any stationary or mobile activity which produces air pollutant




     emissions.




Source Geometry - all sources for modeling purposes are considered to exist




     as a point,  line, or area,  defined as follows:




         point source - a single major emitter located at a point.




         line source - a major highway link,  denoted by its end points.
                                         81

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         area source - a rectangular area referenced to a grid system; in-



         cludes not only area-wide sources,,' such as residential emitters,




         but single emitters and highway links deemed too small to be con-




         sidered individual point or line sources by the model.




Stability Category - a classification of atmospheric stability conditions




     based on surface wind speed, cloud cover and ceiling, supplemented by




     solar elevation data (latitude, time of day, and time of year).




Stability Wind Rose - a tabulation of the joint frequency of occurrences of




     wind speed and wind direction by atmospheric stability class at a



     specific location.




Total Air Quality - the air quality at a receptor point resulting from back-



     ground emission sources and from emission sources specifically within




     the study region.




Trapping Distance - the distance downwind of a source at which vertical



     mixing of a plume begins to be significantly inhibited by the base




     of the stability layer, and gaussian vertical distribution can no



     longer be assumed.




Wind Sector - a 22-1/2  degree wind direction range whose center-line is one




     of the sixteen points of the compass.
                                        82

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                                   TECHNICAL REPORT DATA
                            (Please read lustructions on the reverse before co»i/>/cliii[;J
 1. REPORT NO.
 EPA-450/3-74-056-C
                                                           3. RECIPIENT'S ACCESSIOI*NO.
4. TITLE AND SUBTITLE
  HACKENSACK  MEADOWLANDS AIR POLLUTION  STUDY
 Development  and Validation of a Modeling
 Technique  for Predicting Air Quality Levels
             5. REPORT DATE
              July  1973
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
  James R. Mahoney,  Bruce  A.  Egan, and
  Edward C. Reifenstein,  III
             8. PERFORMING ORGANIZATION REPORT NO.
              ERT  Project P-244-2
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Environmental  Research and Technology,  Inc.
 429 Marrett  Road
 Lexington, Massachusetts  02173
                                                           10. PROGRAM ELEMENT NO.
             11. CON TRACT/GRANT NO.
                                                            EHSD 71-39
 12. SPONSORING AGENCY NAME AND ADDRESS

 Environmental  Protection Agency
 Office of  Air  Quality Planning and Standards
 Research Triangle Park, North Carolina   27711
             13. TYPE OF REPORT AND PERIOD COVERED

               Final	
             14. SPONSORING AGENCY CODE
 15. SUPPLEMENTARY NOTES
 Prepared in  cooperation with the New Jersey  Department of Environmental  Protection,
 Office of the  Commissioner. Labor and  Industry Building, Trenton, N. J.   08625
16. ABSTRACT
      The Hackensack  Meadowlands Air Pollution  Study consists of a summary  report and

 five task  reports.   The summary report  discusses  the procedures developed  for con-

 sidering air  pollution in the planning  process and the use of these  procedures to

 evaluate four alternative land use plans  for the  New Jersey Hackensack  Meadowlands for

 1990.  The task  reports describe (1) the  emission projection methodology and its

 application to the Hackensack Meadowlands;  (2) the model for predicting air quality

 levels and its validation and calibration:  (3) the evaluation and ranking  of the land

 use plans; (4) the planning guidelines  derived from the analysis of  the plans; and,

 (5) the software system.
17.

I.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
 Land Use
 Planning and Zoning
 Local Governments
 County Governments
 State Governments
 Regional Governments
 Air Pollution r.nntrnl
b. IDENTIFIERS/OPEN ENDED TERMS  C. COSATI Field/Group
13. DISTRIBUTION STATEMENT
                                              19. SECURITY CLASS (This Report/
                                                Uncalassified
                           21. NO. OF PAGES
                             91
 Unlimited
20. SECLIRIT Y. CLASS (This page!
  un clas si fied
                                                                         22. PRICE
EPA Form 2220-1 (9-73)
                                            83

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