c/EPA
United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EPA-453/B-95-001
April 1995
Air
A Guidebook on How to Comply
with the Chromium Electroplating
and Anodizing National Emission
Standards for Hazardous Air
Pollutants
SMALL BUSINESS ASSISTANCE PROGRAM
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EPA 453/B-95-001
A GUIDEBOOK ON HOW TO COMPLY
WITH THE CHROMIUM ELECTROPLATING
AND ANODIZING NATIONAL EMISSION STANDARDS
FOR HAZARDOUS AIR POLLUTANTS
Prepared for:
Organic Chemicals Group
Emission Standards Division
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
Federal Small Business Assistance Program
Information Transfer and Program Integration Division (ITPID)
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
Prepared by:
Midwest Research Institute
401 Harrison Oaks Boulevard, Suite 350
Gary, North Carolina 27513
April 1995
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This report has been reviewed by the Emission Standards Division and the
Information Transfer and Program Integration Division, Office of Air Quality Planning and
Standards (OAQPS), U. S. Environmental Protection Agency (EPA), and approved for
publication. Mention of trade names or commercial products is not intended to constitute
endorsement or recommendation for use. For more information on this regulation, or to
obtain additional copies of this guidebook, please call your State Small Business Assistance
Program, your State Small Business Ombudsman; your State or local air pollution control
agency; your local, regional, or national metal finishers trade association; or your EPA
Regional Office. Contact EPA's Control Technology Center (CTC) Hotline at
(919) 541-0800 to get information on your State small business and air program contacts, or
to order single copies of this guidebook. Copies are also available through the Library
Services Office (MD-35), U. S. EPA, Research Triangle Park, NC 27711; from the OAQPS
Technology Transfer Network (TTN), (919) 541-5742 via modem (for assistance with the
TTN, call (919) 541-5384); or, for a small fee, from the National Technical Information
Services, 5285 Port Royal Road, Springfield, VA 22161.
11
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TABLE OF CONTENTS
Page
CHAPTER 1 INTRODUCTION 1
CHAPTER 2 OVERVIEW OF THE REGULATION 3
CHAPTER 3 DOES THIS REGULATION APPLY TO ME? 5
CHAPTER 4 WHAT DO I NEED TO DO TO COMPLY? 9
CHAPTER 5 HOW WELL I DEMONSTRATE COMPLIANCE? 23
CHAPTER 6 WHAT RECORDKEEPING AND REPORTING WILL I NEED
TO DO? 31
CHAPTER 7 WHAT ARE MY POLLUTION PREVENTION OPTIONS? 37
CHAPTER 8 HOW DOES THIS REGULATION RELATE TO OTHER
FEDERAL AND STATE OR LOCAL REQUIREMENTS? 39
CHAPTER 9 HOW MUCH WILL IT COST? 43
CHAPTER 10 WHERE CAN I GO FOR MORE INFORMATION AND
ASSISTANCE? 47
APPENDIX A. FEDERAL REGISTER NOTICE; FINAL RULE
APPENDIX B. GLOSSARY OF TERMS
APPENDIX C. LIST OF KNOWN FACILITIES
APPENDIX D. DETAILED TABLE OF CONTENTS OF THE REGULATION
APPENDIX E. EXAMPLE FORMS
111
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LIST OF TABLES
TABLE 3-1.
TABLE 4-1.
TABLE 4-2.
TABLE 5-1.
TABLE 5-2.
TABLE 5-3.
TABLE 9-1.
TABLE 10-1.
FUNCTIONS AND PROCESS PARAMETERS OF THE TYPES
OF OPERATIONS
EMISSION LIMITS
SUMMARY OF WORK PRACTICE STANDARDS
INFORMATION REQUIRED IN INITIAL PERFORMANCE
TEST REPORT
METHODS USED TO ESTABLISH OPERATING PARAMETER
VALUES
SUMMARY OF ONGOING MONITORING REQUIREMENTS
ESTIMATED EMISSION CONTROL COSTS
EPA REGIONAL OFFICE CONTACTS
Page
8
10
20
24
25
27
44
48
LIST OF FIGURES
Pat
Figure 3-1. Approximate distribution of sources by State
Figure 4-1. Horizontal-flow, single packed-bed scrubber
Figure 4-2. Horizontal-flow, double packed-bed scrubber
Figure 4-3. Horizontal-flow chevron-blade mist eliminator with a single set
of blades
Figure 4-4. Mesh-pad mist eliminator
Figure 4-5. Schematic of a typical fiber-bed mist eliminator
Figure 5-1. Decision tree for decreasing the monitoring frequency of surface
tension or foam blanket thickness measurements
Figure 6-1. Timeline for reporting requirements
6
13
14
15
16
18
28
34
IV
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CHAPTER 1
INTRODUCTION
BACKGROUND
In November of 1994, the U. S.
Environmental Protection Agency (EPA) issued
national regulations to control air emissions of
chromium from chromium electroplating and
anodizing tanks. The regulation appeared in the
January 25, 1995 edition of the Federal Register
[volume 60, beginning on page 4948].
Why is EPA regulating chromium
electroplating and anodizing tanks? The Clean
Air Act as amended in 1990 (CAA) directs EPA
to regulate emissions of a number of toxic
chemicals, including chromium, from a wide
range of industrial sources. The EPA is
regulating emissions of chromium from
electroplating and anodizing tanks to meet the
requirements of the CAA.
The hexavalent form of chromium is highly
toxic and a known human carcinogen, causing
lung cancer; less is known about the cancer risk
of the trivalent form of chromium, but it can
accumulate in the lungs and may result in
decreased lung function after continuous
exposure. The regulatory requirements differ
for tanks that use a trivalent chromium bath
rather than a chromic acid (hexavalent
chromium) bath.
Chromium electroplating and anodizing
tanks are one of the largest sources of chromium
emissions in the United States. Over 5,000
facilities perform chromium electroplating
and/or anodizing in the United States. Many
facilities are small job shops that are located
near residential areas. The EPA estimates that
full compliance with its new regulation will
result in a reduction of about 173 tons of
chromium emitted into the air annually, or about
a 99-percent reduction from today's levels.
PURPOSE OF GUIDEBOOK
The purpose of this guidebook is to provide
a straightforward overview of this regulation and
to equip businesses with the basic information
they need to comply with the regulation. This
guidebook is not a complete and full statement
of the legal and technical requirements of the
regulation. See the Federal Register notice
(included as Appendix A to this guidebook) for
the complete text of the regulation.
ORGANIZATION
Chapter 2 presents an overview of the
requirements of the regulation, and Chapters 3
through 6 explain these requirements in more
detail. Chapter 7 discusses some pollution
prevention opportunities associated with the
regulation. Chapter 8 provides an explanation
of how this regulation relates to other Federal
and State or local requirements, including
permitting. Estimated costs for businesses to
comply with the regulation are provided in
Chapter 9. Sources of more information on the
regulation are provided in Chapter 10. A copy
Page 1
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INTRODUCTION CHAPTER I
of the regulation is included as Appendix A.
Appendix B contains a glossary of terms. A list
of known facilities affected by this regulation are
included as Appendix C. Appendix D provides
a detailed "table of contents" of the regulation.
Example forms for monitoring, recordkeeping,
and reporting are provided in Appendix E.
Page 2
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CHAPTER 2
OVERVIEW OF THE REGULATION
The regulation affects all facilities that use
chromium electroplating or anodizing tanks,
regardless of size. How you are affected
depends on the size and type (hard, decorative,
or anodizing) of operation you have and the
control technique(s) that you use to comply with
the regulation. In general, the regulation
specifies:
/ Emission limits
S Work practices
/ Initial performance testing
/ Ongoing compliance monitoring
./ Recordkeeping
• 0.03 mg/dscm for small, existing hard
chromium electroplating tanks (packed-
bed scrubber or "PBS");
»• 0.015 mg/dscm for all other hard
chromium electroplating tanks
(composite mesh-pad or "CMP"
system); and
»• 0.01 mg/dscm or a surface tension limit
of 45 dynes per centimeter (dynes/cm)
for decorative chromium electroplating
and chromium anodizing tanks (fume
suppressants or "FS").
WORK PRACTICES
The regulation specifies work practice
standards to ensure that air pollution control
systems and monitoring equipment are being
properly maintained and operated. The work
practice standards require that most facilities
develop an operation and maintenance (O&M)
plan for the facility. Additional work practice
requirements include quarterly inspections of
control devices, ductwork, and monitoring
equipment.
INITIAL PERFORMANCE TESTING
Initial performance testing is required (with
some exceptions noted below) to demonstrate
that you are meeting the emission limit for your
type of operation. This is a one-time test.
However, sources that meet the following
criteria do not have to perform the initial test:
Page 3
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OVERVIEW OF THE REGULATION
CHAPTER 2
»• Decorative chromium electroplating
tanks or chromium anodizing tanks that
use a wetting agent and limit the surface
tension of the bath to a maximum of 45
dynes/cm and
*• Decorative chromium electroplating
tanks that use a trivalent chromium
bath.
The regulation contains test methods (EPA
Reference Methods 306 and 306A) for
measuring the chromium concentration
discharged to the atmosphere.
ONGOING COMPLIANCE MONITORING
Continuous compliance with the regulation
is demonstrated through ongoing compliance
monitoring. Monitoring of specific operating
parameters that affect the performance of the
particular control technique you are using is
required to ensure continuous compliance with
the emission limits. Therefore, the monitoring
requirements vary depending on the type of
control technique that you use.
If you use an add-on air pollution control
device that is specified in the regulation, you
must monitor the pressure drop across the unit
daily. If you use a packed-bed scrubber, you
must also monitor the velocity pressure (i.e., the
velocity of the gas stream at the inlet of the unit)
daily. The surface tension of the bath or the
foam thickness must be monitored if you use
wetting agents or foam blankets, respectively.
The regulation contains a test method for
measuring the surface tension of the bath (EPA
Reference Method 306B). If you use a control
system not specified in the regulation, you must
determine the appropriate parameter(s) to
monitor and get EPA approval.
RECORDKEEPING
The regulation requires sources to keep
records to document compliance with the
regulation. The required documentation
includes: (1) inspection records; (2) equipment
maintenance records; (3) records of the
occurrence, duration, and cause of excess
emissions (see Chapter 5 for an explanation of
excess emissions); (4) performance test results;
and (5) monitoring data. All records must be
kept for 5 years. If you operate a decorative
chromium electroplating tank that uses a
trivalent chromium bath, you only need to keep
records of bath component purchases.
REPORTING
The extent and frequency of reporting
depends on the type and size of your source.
The regulation requires an initial notification that
you are subject to the regulation, a notification
of performance testing, and a report of the
performance test results and compliance status
after the test. In addition, you must prepare
reports that contain information on the ongoing
compliance status of your facility. If you
operate a decorative chromium electroplating
tank that uses a trivalent chromium bath, you
only need to submit the initial notification and an
initial compliance status report.
Page 4
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CHAPTERS
DOES THIS REGULATION APPLY TO ME?
APPLICABILITY OF THE REGULATION
The regulation applies to virtually all hard
and decorative chromium electroplaters and
chromium anodizers as defined in the regulation,
regardless of size (see exemptions listed below).
Both major and area sources are covered by the
regulation. (Major sources are sources emitting
10 tons per year or more of any hazardous air
pollutant or 25 tons per year or more of any
combination of hazardous air pollutants. Area
sources, also referred to as "nonmajor sources,"
are sources that do not qualify as major.) The
EPA believes that the high toxicity of chromium
compounds and the close proximity of many
small shops to residential areas warrant
regulation of all sources, even small businesses.
Hard chromium electroplating operations
deposit a thick layer of chromium directly on a
base metal to provide wear and corrosion
resistance, low friction, and hardness (for
hydraulic cylinders, industrial rolls, etc.).
Decorative chromium electroplating
operations deposit a thin layer of chromium on
a base material to provide a bright finish and
wear and tarnish resistance (for bicycles, auto
trim, tools, etc.). Decorative chromium
electroplating tanks may use a chromic acid bath
or a trivalent chromium bath.
Chromium anodizing operations form a
chromium oxide layer on aluminum to provide
corrosion resistance (for aircraft parts.
architectural structures, etc.).
See Appendix B of this guidebook for
complete definitions of these terms as they
appear in the regulation.
Are any sources exempt? The regulation
specifically exempts certain types of sources.
These sources are:
»• Process tanks that may contain low
concentrations of chromium but neither
chromium electroplating nor chromium
anodizing is taking place in the tank
(e.g., rinse tanks, etch tanks, and
cleaning tanks);
»• Tanks that contain a chromium solution,
but in which no electrolytic process
occurs (e.g., chrome conversion coating
tank); and
»• Tanks that are used for research and
laboratory operations.
How many facilities are affected and
where are they located? The EPA estimates
that there are about 5,020 affected facilities
nationwide. Of the estimated 5,020 facilities, an
estimated 1,540 are hard chromium electro-
platers, 2,800 are decorative chromium
electroplaters, and 680 are chromium anodizers.
Figure 3-1 shows the approximate distribution of
the facilities by State. Appendix C of this
PageS
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en
S
O
£
>
H
O
H
O
Figure 3-1. Approximate distribution of sources by State.
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CHAPTERS
DOES THIS REGULATION APPLY TO ME?
guidebook lists the known facilities that are
affected by this regulation.
How do you determine what type of facility
you have? The terms "hard chromium electro-
plating," "decorative chromium electroplating,"
and "chromium anodizing" are defined by
typical process parameters, as well as by
function. Therefore, regardless of what name
you assign to your process, you will be
regulated according to the functions and process
parameters of your tank. Process parameters
include the plating thickness, the current density
applied, and the plating time. Table 3-1
summarizes the functions and process parameters
associated with the three types of facilities.
Some facilities may have operations that do
not fit exactly into one of the definitions in the
regulation. In this case, judgement and
communication between the facility and its State
or local air pollution control agency is required.
For example... A facility that operates a
"black chromium electroplating process" may
qualify as either a decorative or a hard
chromium electroplater, depending on the
process parameters at the particular source. In
one case, a black chromium electroplating
process that calls for a current density of 40 to
90 amperes per square foot (A/ft2), a plating
time of 30 to 45 minutes (min), and a plate
thickness of 5 microns (^m) would best fit the
description of a hard chromium plating process.
However, another black chromium electroplating
operation that uses 144 to 288 A/ft2, a plating
time of 5 min, and a plate thickness of 0.13 to
0.51 jim would best fit the description of a
decorative chromium plating process. If you are
unsure about which definition fits your
operation, contact your State or local air
pollution control agency.
Page?
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DOES THIS REGULATION APPLY TO ME?
CHAPTER 3
TABLE 3-1. FUNCTIONS AND PROCESS PARAMETERS OF THE TYPES
OF OPERATIONS
Type of operation
Functions
Process Parameters
Hard (or "industrial")
chromium electroplating
Provides a surface with functional
properties such as:
• Wear resistance
• A low coefficient of friction
• Hardness
• Corrosion resistance.
Specified in regulation:
Plate thickness of 1.3 to 760 microns
Current density of 150 to 600 A/ft2
Plating time of 20 minutes to 36 hours
Others:
Chromic acid concentration of 30 to SO oz/gal
SuLfuric acid concentration of 0.3 to 0.5 oz/gal
Solution temperature of 120° to 150°F
Decorative chromium
electroplating
Provides a bright surface with
wear- and-tarnish resistance.
Specified in regulation:
Plate thickness of 0.003 to 2.5 microns (chromic
acid bath) or 0.13 to 25 microns (bivalent
chromium bath)
Current density of 50 to 220 A/ft2
Plating time of 0.5 to 5 minutes
Others:
Chromic acid concentration of 30 to 50 oz/gal
Sulfuric acid concentration of 0.3 to 0.5 oz/gal
Solution temperature oflOO°toll50F
Chromium anodizing
Provides corrosion resistance or
electrical insulation.
Specified in regulation:
Chromic acid concentration of 6.67 to 13.3 oz/gal
Others:
Film thickness of 0.02 to 0.05 microns
Current density of 144 to 720 A/ft2
Anodizing time of 30 to 60 minutes
Solution temperature of 90° to 95°F
pH of 0.5 to 0.85
Voltage of 20 or 40 volts
PageS
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CHAPTER 4
WHAT DO I NEED TO DO TO COMPLY?
SUMMARY OF THE REQUIREMENTS
The major requirements of the regulation
can be categorized as follows:
/ Emission limits
/ Work practices
/ Initial performance testing
/ Ongoing compliance monitoring
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WHAT DO I NEED TO DO TO COMPLY?
CHAPTER 4
TABLE 4-1. EMISSION LIMITS
Affected tanks
Control level3
Control technique
Hard Chromium Plating Tanks
Small, existing tanks"
Large, existing tanks
and all new tanks
0.03 mg/dscm
(1.3x 10'^ gr/dscf)
0.015 mg/dscm
(6.6 x 10"° gr/dscf)
packed-bed scrubber (PBS)
composite mesh-pad (CMP) system
Decorative Chromium Plating Tanks Using a Chromic Acid Bath
All tanks
0.01 mg/dscm
(4.4 x 10"6 gr/dscf) or
45 dynes/cm
(3.1 x I
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CHAPTER 4
WHAT DO I NEED TO DO TO COMPLY?
instead of large by using either of the following
procedures:
»> Using a nonresettable ampere-hr meter
on the tank(s) and keeping monthly
records to show that the actual rectifier
capacity (based on your facility's actual
operating schedule and tank utilization)
is below the cutoff or
*• Accepting a Federally-enforceable limit
on the rectifier capacity (contact your
EPA Regional Office or your State or
local air pollution control agency for
information on how to obtain a
Federally-enforceable limit).
How do I calculate the maximum
cumulative potential rectifier capacity? The
maximum cumulative potential rectifier capacity
is based on a maximum potential operating
schedule of 8,400 hours per year for the facility
and assumes that each tank is in operation for
70 percent of the total operating hours.
For example... To calculate the maximum
cumulative potential rectifier capacity for a
facility, sum the total installed rectifier capacities
associated with all hard plating tanks (EC^ in
amperes) and multiply this sum by 8,400 hours/
year and 0.7, as shown below:
(£C.X8.400)(0.7) = ampere-hours
*~ year
What is meant by "existing"? A tank
qualifies as "existing" if it was installed before
December 16, 1993, which was the date this
regulation was proposed in the Federal Register.
Which control technique should I use to
meet the emission limit? As mentioned above,
the emission limits are based on the level of
control that can be maintained using a certain
control technique. However, you may choose to
use another control technique, as long as you
can meet the emission limit for your type of
facility. The following paragraphs discuss the
control techniques in Table 4-1.
Typical control efficiencies are also given
in the following paragraphs. But, beware that
actual performance levels may vary from these
typical values, depending on such factors as the
inlet conditions and how well the control devices
are operated and maintained. For more
information on how these typical control
efficiencies were derived, see Chapters 4 and 5
of EPA's Chromium Emissions from Chromium
Electroplating and Chromic Acid Anodizing
Operations—Background Information for
Proposed Standards (Volume I) (EPA-453/R-93-
030a). For information on the availability of
this document, see Chapter 10 of this guidebook.
Packed-bed scrubbers are typically used to
reduce emissions of chromic acid mist from
electroplating and anodizing tanks. Both single
and double packed-bed designs are used.
Chromic acid mist is removed from the gas
stream primarily by droplets impacting on
packing media. First, the gas stream is wetted
by spraying water countercurrent to the gas flow
to enlarge the droplet size. The gas stream then
passes through the packed bed(s) where the
droplets impinge on the packing media. The
regulation requires periodic washing of packing
material using an overhead weir.
Page 11
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WHAT DO I NEED TO DO TO COMPLY?
CHAPTER 4
In most cases, the packed-bed section of the
scrubber is followed by a mist eliminator section
comprised of a single chevron-blade mist
eliminator. The mist eliminator removes any
water entrained from the packed-bed section.
Treated gases then pass through an induced draft
fan and out a stack or exhaust vent. The
scrubber water is usually recirculated and
periodically tapped and discharged to the
electroplating tanks as makeup solution.
Typical efficiencies of packed-bed
scrubbers are 97 percent for decorative
chromium electroplating and anodizing tanks and
99 percent for hard chromium electroplating
tanks. Schematics of a single packed-bed
scrubber and a double packed-bed scrubber are
provided in Figures 4-1 and 4-2, respectively.
Figure 4-3 is a schematic of a chevron-blade
mist eliminator.
Composite mesh pads consist of layers of
interlocked fibers densely packed between two
supporting grids. The composite mesh pad was
developed to remove small particles (< 5/tm or
0.2 mils) that were not effectively controlled by
conventional technologies. The layers of
material in composite pads are arranged with the
smallest diameter fiber layer located in the
center of the pad and progressively larger
diameter layers located on both sides of the
center. Particles collide with the fibers in the
pad and adhere to their surfaces. These
captured particles coalesce into larger droplets as
they travel through the small-diameter fiber
layers in the center of the pad. These enlarged
particles either drain to the bottom of the unit or
are reentrained in the gas stream. The
reentrained particles are then captured by the
large-diameter fiber layers in the back of the
pad. A schematic of a typical composite
mesh-pad is provided in Figure 4-4.
Composite mesh-pad systems incorporate a
larger particle removal system prior to the
composite mesh pad to reduce the plugging
potential of the pad. The large particle removal
system can either be a series of larger diameter
mesh pads or a packed-bed scrubber section.
Typical removal efficiencies associated with
this control device are greater than 99 percent.
Fume suppressants are compounds that are
added directly to the bath to reduce or inhibit
misting. Fume suppressants include: wetting
agents, foam blankets, and combinations that
include both a wetting agent and a foam blanket.
An important distinction between wetting agents
and foam blankets is how they reduce emissions.
Wetting agents reduce or inhibit misting by
lowering the surface tension of the bath. When
the surface tension of the solution is reduced,
gases escape at the surface of the solution with
less of a "bursting" effect, forming less mist.
Foam blankets do not preclude the formation of
chromic acid mist, but rather trap the mist
formed under a blanket of foam. The foam
blanket is formed by agitation produced by the
hydrogen and oxygen gas bubbles generated
during electroplating. Once formed, the foarn
blanket is usually maintained at a thickness of
1.3 to 2.5 cm (0.5 to 1.0 in.) and covers the
entire surface of the bath.
Fume suppressants typically reduce
chromium emissions by more than 99 percent.
Page 12
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1
PACKED
BED
MIST ELIMINATOR
SECTION
WATER SPRAY
SECTION
a?
*
c
MIST-LADEN
GAS STREAM
CONTROLLED
^GAS STREAM
INSPECTION
DOOR
RECIRCULATION
PUMP
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Figure 4-1. Horizontal-flow, single packed-bed scrubber.
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era
h-k
4t
MIST-LADEN
GAS STREAM
WATER SPRAY
SECTION
INSPECTION
DOOR
MIST ELIMINATOR
SECTION
M
O
H
O
O
O
CONTROLLED
*• GAS STREAM
RECIRCULATION
PUMP
Figure 4-2. Horizontal-flow, double packed-bed scrubber.
90
^
-------
SPRAY NOZZLE
WASH DOWN
MIST-LADEN
GAS STREAM
?*'
Iliiniin'
llllNllH
UlililHM
SPRAY NOZZLE
WASH DOWN
iONTROLLED
GAS STREAM
DRAIN
MIST-LADEN
GAS STREAM
CONTROLLED
GAS STREAM
DRAIN
H
O
O
SINGLE SET OF BLADES
DOUBLE SET OF BLADES
O
H
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g
3
n
o
Figure 4-3. Horizontal-flow chevron-blade mist eliminators.
-------
H
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ita^B
I-:**
HORIZONTAL MIST ELIMINATOR
1.
II
F&
§
H
O
n
o
WOVEN POLYPRO MESH PAD
CUTOUT IN CASING FOR
PAD REMOVAL
PRIMARY MESH PAD
SECONDARY MESH PAD
PVC CASING
WATER SPRAY
FOR MESH PAD
DRAIN (TO PLATING
TANK)
Figure 4-4. Mesh-pad mist eliminator.
1—i
5
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CHAPTER 4
WHAT DO I NEED TO DO TO COMPLY?
What if I want to use a different control
technique? You may use another control
technique, as long as you meet the emission
limit for your type of facility. You do not need
EPA approval to choose another technique;
however, you must get EPA approval on the
monitoring parameters and test methods that you
will use. An example of another control
technique that may be used is the fiber-bed mist
eliminator, which is described below.
Fiber-bed mist eliminators mostly have
been used to reduce acid mists from sulfuric,
phosphoric, and nitric acid plants. These
systems remove contaminants from a gas stream
through the mechanisms of inertial impaction
and Brownian diffusion. Fiber-bed units are
designed for horizontal, concurrent gas-liquid
flow through the bed. The contaminated gas
stream flows toward the downstream face of the
bed. The acid mist in the gas stream impacts on
the surface of the fibers and drains down the
outer face of the bed to the sump while the
cleaned gas flows up and out the top of the unit.
A schematic of a typical fiber-bed mist
eliminator is presented in Figure 4-5.
Fiber-bed mist eliminators are typically
installed downstream of an existing control
system. The upstream device removes the
majority of the emissions and thus prevents
plugging of the fiber bed.
Adequate test data are not available to
accurately quantify the control efficiency of
fiber-bed mist eliminators. However, EPA
believes that these systems can achieve the
emission limits that were based on the use of
composite mesh-pad systems and fume suppres-
sants based on qualitative data available.
WORK PRACTICES
Besides complying with the emission limits
discussed above, you will also be required to
perform work practice standards. Work practice
standards are required to ensure that the control
technique you use to comply with the regulation
is properly maintained. Poor maintenance could
result in system degradation over time, and
eventually lead to an increase in emissions.
Work practice standards must be performed
quarterly in most cases. The requirements vary
slightly depending on which control device you
use, as shown in Table 4-2.
In addition to these work practices, you
will also be required to write an operation and
maintenance (O&M) plan for your facility.
(Decorative chromium electroplating operations
that use a trivalent chromium bath do not have
to prepare an O&M plan.) The O&M plan must
be developed and implemented by the compli-
ance date for your facility. However,you do not
have to submit your plan to EPA. The O&M
plan will include:
> descriptions of the control device and
monitoring equipment in use;
*• a checklist to document the operation
and maintenance of the equipment (see
Appendix E of this guidebook, Opera-
tion and Maintenance Checklist, for an
example checklist);
»• a list of the work practice standards
from Table 4-2 that apply to your
facility;
Page 17
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WHAT DO I NEED TO DO TO COMPLY?
CHAPTER 4
GAS
LIQUID
f~ 1 COARSE FIBER DRAINAGE LAYER
FINE FIBER COLLECTION LAYER
Figure 4-5. Schematic of a typical fiber-bed mist eliminator.
Page 18
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CHAPTER 4
WHAT DO I NEED TO DO TO COMPLY?
>• procedures to follow to ensure that
equipment or process malfunctions due
to poor maintenance or other prevent-
able conditions do not occur; and
»• procedures for identifying malfunctions
and for implementing corrective actions.
You may use any standard operating procedure
(SOP) manuals, vendor O&M manuals, Occupa-
tional Safety and Health Administration (OSHA)
plans, or other existing plans as part of your
O&M plan, as long as they meet the criteria in
the regulation.
Page 19
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WHAT DO I NEED TO DO TO COMPLY?
CHAPTER 4
TABLE 4-2. SUMMARY OF WORK PRACTICE STANDARDS
Control technique
Packed-bed
scrubber (PBS)
Composite mesh-
pad (CMP) system
PBS/CMP system
Fiber-bed mist
eliminator0
Other air pollution
control device
(APCD)
Work practice standards
Visually inspect device to ensure there is proper drainage, no
chromic acid buildup on the packed beds, and no evidence of
chemical attack on the structural integrity of the device.
Visually inspect back portion of the chevron-blade mist
eliminator to ensure that it is dry and there is no breakthrough
of chromic acid mist. j
Visually inspect ductwork from tank or tanks to the control
device to ensure there are no leaks.
Add fresh makeup water to the top of the packed bed.a>')
Visually inspect device to ensure there is proper drainage, no
chromic acid buildup on the pads, and no evidence of
chemical attack on the structural integrity of the device.
Visually inspect back portion of the mesh pad closest to the
fan to ensure there is no breakthrough of chromic acid mist.
Visually inspect ductwork from tank or tanks to the control
device to ensure there are no leaks.
Perform washdown of the composite mesh-pads in accordance
with manufacturer's recommendations.
Same as for CMP system.
Visually inspect fiber-bed unit and prefiltering device to
ensure there is proper drainage, no chromic acid buildup in
the units, and no evidence of chemical attack on the structural
integrity of the devices.
Visually inspect ductwork from the tank(s) to the control
device to ensure there are no leaks.
Perform washdown of fiber elements in accordance with
manufacturer's recommendations.
To be proposed by the source for approval by the
Administrator.
Frequency
1 /quarter
1 /quarter
1 /quarter
Whenever
makeup is
added
1 /quarter
1 /quarter
1 /quarter
Per
manufacturer
Same as for
CMP system
1 /quarter
1 /quarter
Per
manufacturer
Proposed by the
source for
approval by the
Administrator
(continued)
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CHAPTER 4
WHAT DO I NEED TO DO TO COMPLY?
TABLE 4-2. SUMMARY OF WORK PRACTICE STANDARDS (continued)
Monitoring equipment
Pilot tube
Stalagmometerd
Work practice standards
Backflush with water, or remove from the duct and
rinse with fresh water. Replace in the duct and rotate
1 80 degrees to ensure that the same zero reading is
obtained. Check pilot tube ends for damage. Replace
pitol tube if cracked or fatigued.
Follow manufacturer's recommendations.
Frequency
1 /quarter
Per
manufacturer
alf greater lhan 50 percenl of Ihe scrubber water is drained (e.g., for maintenance purposes), makeup
water may be added to Ihe scrubber basin.
'•'For horizontal-flow scrubbers, top is defined as the section of the unit directly above the packing
media such that the makeup water would flow perpendicular to the air flow through the packing.
For vertical-flow units, the top is defined as the area downstream of the packing material such that
the makeup water would flow countercurrent to the air flow through the unit.
cWork practice standards for the control device installed upstream of the fiber-bed mist eliminator to
prevent plugging do not apply as long as the work practice standards for the fiber-bed unit are
followed.
^Device used to measure the surface tension of the bath.
Page 21
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WHAT DO I NEED TO DO TO COMPLY? CHAPTER 4
Page 22
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CHAPTERS
HOW WILL I DEMONSTRATE COMPLIANCE?
There are three components to demon-
strating compliance with the emission limits of
this regulation:
•/" Initial performance testing
/ Ongoing compliance monitoring
y Special compliance provisions
INITIAL PERFORMANCE TESTING
However, sources that meet the following
criteria do not have to perform testing:
>• Decorative chromium electroplating tanks or
chromium anodizing tanks that use a wetting
agent and limit the surface tension of the bath
to a maximum of 45 dynes/cm and
»• Decorative chromium electroplating tanks that
use a trivalent chromium bath.
What is the purpose of the initial
performance test? There are two reasons to
perform an initial performance test. First, an
initial performance test is necessary to determine
if the chromium emissions from the affected
source are the same or lower than the emission
limits set for the source. The emission limits for
the different chromium electroplating tanks and
chromium anodizing tanks were listed in
Table 4-1. Second, the initial performance test
establishes values or ranges of values for the air
pollution control system operating parameters.
Monitoring and recording these operating
parameters during tank operation will give you
an indication of whether or not you are in
compliance with the emission limits.
Summary of testing requirements. Except
for the situations noted below, you will be
required to perform an initial performance test.
This test must be conducted by July 23, 1996 for
decorative chromium electroplaters and by
July 24, 1997 for hard chromium electroplaters
and chromium anodizers.
A test plan that describes the proposed
initial performance testing program should be
developed prior to testing and may be requested
by EPA. The test plan should describe the
process to be tested, the conditions under which
testing is to be conducted, the sampling loca-
tions, and the test methods to be used. Also,
you must notify EPA in writing of your intent to
conduct a performance test prior to the test.
This notification is described in Chapter 6 of this
guidebook.
The performance test report is prepared by
the test contractor after testing has been
conducted. The test report must contain the
information listed in Table 5-1 and must be
submitted to EPA as part of the reporting
requirements described in Chapter 6 of this
guidebook.
Test methods. EPA Reference Method 306
or 306A, "Determination of Chromium Emis-
sions from Decorative and Hard Chromium
Electroplating and Anodizing Operations," must
Page 23
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HOW WILL I DEMONSTRATE COMPLIANCE?
CHAPTER 5
TABLE 5-1. INFORMATION
REQUIRED IN INITIAL
PERFORMANCE TEST REPORT
Process description
Sampling location descriptions
Sampling and analysis procedures
and any modifications to standard
procedures
Test results
Quality assurance procedures and
results
Records of:
- operating conditions during
testing
— preparation of standards
~ calibration procedures
Raw data sheets for:
— field sampling
— field and laboratory analyses
Documentation of calculations
Any additional information
required by the test method
be used to determine chromium emissions from
decorative or hard chromium electroplating tanks
or chromium anodizing tanks. Detailed
descriptions of these reference methods are
located in Appendix A of part 63 of the Code of
Federal Regulations. The EPA produced a
videotape on stack sampling and monitoring
entitled "Construction and Operation of the EPA
Method 306A Sampling Train and Practical
Suggestions for Monitoring of Electroplating and
Anodizing Facilities" that is available to you for
a nominal fee through North Carolina State
University, Raleigh, NC by calling
(919) 515-5875.
The California Air Resources Board
(CARB) Method 425 may also be used to
measure chromium emissions as long as the
analytical requirements listed in the regulation
are adhered to. Alternate test methods may also
be used as long as they have been validated
using EPA Reference Method 301.
EPA Reference Method 306B, "Surface
Tension Measurement and Recordkeeping for
Tanks Used at Decorative Chromium Electro-
plating and Anodizing Facilities'" must be used
to determine the surface tension of electroplating
and anodizing baths if you are complying with
the surface tension limit rather than the emission
limit.
Monitoring requirements. During perfor-
mance testing, applicable air pollution control
system operating parameters must be recorded.
These operating parameters are determined by
the air pollution control system you are using
and are listed in Table 5-2. At the conclusion of
testing, a range of acceptable values or a
maximum or minimum value for these
parameters can be established as described
below.
For pressure drop measurements, the range
can be established as the range of pressure drops
measured during multiple performance tests, or
as plus or minus 1 inch of water column about
the average pressure drop measured during three
compliant test runs (i.e., the source was at or
below the applicable emission limit).
For velocity pressure measurements, the
range can be established as the range of velocity
pressures measured during multiple performance
tests, or as plus or minus 10 percent about the
Page 24
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CHAPTER 5
HOW WILL I DEMONSTRATE COMPLIANCE?
TABLE 5-2. METHODS USED TO ESTABLISH OPERATING PARAMETER VALUES
Monitored parameter
Applicable air pollution
control systems
Method used to establish
acceptable values
Pressure drop
Composite mesh-pad system
Packed-bed scrubber
Fiber-bed mist eliminator
1. Range of values from
multiple performance tests
or
2. +.1 inch of I^O column
about the average pressure
drop measured during
three compliant test runs
Velocity pressure
Packed-bed scrubber
1. Range of values from
multiple performance tests
or
2. _+10 percent about the
average velocity pressure
measured during three
compliant test runs
Surface tension
Wetting agent
1. Use 45 dynes/cm or
2. Maximum surface tension
measured during at least
three compliant test runs
Foam blanket thickness
Foam blanket
Fume suppressant
1. Use 1 inch foam blanket
thickness or
2. Minimum foam blanket
thickness measured during
at least three compliant test
runs
Page 25
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HOW WILL I DEMONSTRATE COMPLIANCE?
CHAPTER 5
average velocity pressure measured during three
compliant test runs.
For surface tension, a maximum value can
be established during performance testing, or
you can forego testing (if you have a decorative
chromium electroplating or a chromium
anodizing operation) and accept 45 dynes/cm as
the maximum surface tension value.
For foam blanket thickness, a minimum
foam blanket thickness can be established during
performance testing or the facility can elect to
use 1 inch as the minimum foam blanket
thickness.
Applicability of previous test results. If
you have already conducted a performance test
to obtain an operating permit in your State, the
results of the testing can be used to demonstrate
compliance with this regulation only if each of
the following criteria is demonstrated'
> the appropriate test methods were used;
> the test was conducted under represen-
tative operating conditions;
> the test report contains the elements
listed in Table 5-1;
*• the test was conducted after
December 1991; and
*• you developed sufficient monitoring
data to establish the operating parameter
values that correspond to compliance
with the emission limits.
If any of these criteria are not met, then you will
have to retest.
ONGOING COMPLIANCE MONITORING
What is the purpose of ongoing monitor-
ing? You must continue to monitor the
operation of the air pollution control system to
ensure ongoing continuous compliance with the
emission limits. By monitoring and recording
the appropriate air pollution control system
parameters and comparing the monitored values
to the range of values, maximum value, or
minimum value established during the
performance test, you and the enforcing agency
can determine if you are in compliance with the
emission limits.
How do I know if I am out of compliance
with the emission limits? Monitored values that
fall outside of the range of values established for
pressure drop and velocity pressure, exceed the
maximum surface tension, or fall below the
minimum foam blanket thickness indicate that
the tank is out of compliance with the emission
limits (i.e., excess emissions). Table 5-3 sum-
marizes the ongoing monitoring requirements
including the monitoring frequency for the
various air pollution control systems.
Can I decrease the monitoring frequency
of monitored values? The monitoring frequency
for pressure drop and velocity pressure cannot
be changed. However, the frequency of moni-
toring surface tension and foam blanket
thickness can be decreased. Figure 5-1 is a
flowchart showing how the monitoring frequency
can be decreased for a wetting agent, a combina-
tion wetting agent/foam blanket-type fume
suppressant, or a foam blanket-type funje
suppressant. The information in Figure 5-] is
also described in the footnotes to Table 5-3.
Page 26
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CHAPTER 5
HOW WILL I DEMONSTRATE COMPLIANCE?
TABLE 5-3. SUMMARY OF ONGOING MONITORING REQUIREMENTS
Air pollution control system
Composite mesh-pad system
Packed-bed scrubber
Packed -bed scrubber /composite
mesh-pad system
Fiber-bed mist eliminator
Wetting agent or combination
wetting agent/foam blanket
fume suppressants
Foam blanket-type fume
suppressants
Fume suppressant/add-on
control device
Monitored parameter3
Pressure drop across system
Pressure drop across system
Velocity pressure at system inlet
Pressure drop across the mesh-pad
system
Pressure drop across the mist
eliminator
Pressure drop across the control
device located upstream of the fiber
bed that prevents plugging
Surface tension
Foam blanket thickness
As identified above
Monitoring
frequency
Daily
Daily
Daily
Daily
Daily
Daily
Every 4 hours'3'0
Every hourc'^
Acceptable values for these monitored parameters are established during initial performance testing.
"If there are no exceedances of the maximum surface tension after 40 hours of operation, then the
monitoring frequency can be decreased to once every 8 hours. If there are no exceedances for the
next 40 hours, then the frequency can be decreased to once every 40 hours. If an exceedance
occurs at any time after that, then the initial monitoring schedule (every 4 hours) must be resumed.
cThe initial schedule must be resumed for every new tank solution.
*% there are no exceedances of the minimum foam blanket thickness after 40 hours of operation, then
the monitoring frequency can be decreased to once every 4 hours. If there are no exceedances for
the next 40 hours, then the frequency can be decreased to once every 8 hours. If an exceedance
occurs after that, then the initial monitoring schedule (every hour) must be resumed.
Page 27
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HOW WELL I DEMONSTRATE COMPLIANCE?
CHAPTER 5
BEGINNING MONITORING:
EVERY 4 HOURS (SURFACE TENSION)
EVERY HOUR (FOAM BLANKET THICKNESS)
ANY EXCEEDANCES AFTER 40 HOURS OF MONITORING?
YES
NO
CONTINUE MONITORING:
EVERY 8 HOURS (SURFACE TENSION)
EVERY 4 HOURS (FOAM BLANKET THICKNESS)
ANY EXCEEDANCES AFTER 40 HOURS OF MONITORING?
YES
NO
*
CONTINUE MONITORING:
EVERY 40 HOURS (SURFACE TENSION)
EVERY 8 HOURS (FOAM BLANKET THICKNESS)
ANY EXCEEDANCES AFTER 40 HOURS OF MONITORING?
YES
NO
Figure 5-1. Decision tree for decreasing the monitoring frequency of surface tension or
foam blanket thickness measurements.
Page 28
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CHAPTER 5 ^ HOW WILL I DEMONSTRATE COMPLIANCE?
SPECIAL COMPLIANCE PROVISIONS
The regulation contains special compliance
provisions for determining compliance with the
emission limits under certain circumstances.
These special compliance provisions are applic-
able in the following situations involving
multiple tanks manifolded to one control system:
*• The multiple tanks include a chromium
electroplating or chromium anodizing
tank among other tanks not affected by
the regulation or
»• The multiple tanks include chromium
tanks performing different operations
subject to different emission limits (e.g.,
hard chromium electroplating and
anodizing) or hard chromium tanks
subject to different emission limits (e.g.,
a new tank and an existing small tank),
which may or may not be controlled
with nonaffected sources.
In these situations, it would be very difficult to
directly determine compliance with the emission
limits in the regulation. Therefore, section
63.344(e) of the final regulation provides
equations for verifying compliance with the
emission limits in both of these situations.
Page 29
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HOW WILL I DEMONSTRATE COMPLIANCE? CHAPTER 5
Page 30
-------
CHAPTER 6
WHAT RECORDKEEPING AND REPORTING WILL I
NEED TO DO?
RECORDKEEPING
The regulation requires that you keep
records to document compliance status with the
regulation. These records include:
/ Inspection and maintenance records
/ Malfunction records
/ Performance test results
/ Monitoring data records
/ Excess emissions records
•/ Process records
/ Miscellaneous records
The recordkeeping requirements are described
below.
Inspection and maintenance records.
Table 4-3 lists the various work practice
standards that apply to air pollution control
systems and monitoring equipment and the
frequency with which these practices are to be
conducted. Records must be maintained to show
that the work practices were conducted on
schedule. The records can take the form of a
checklist; an example checklist for a composite
mesh-pad system is provided in Appendix E of
this guidebook. Also, records of all
maintenance performed on the process, air
pollution control system, and monitoring
equipment must also be maintained; these
records could take the form of contractor
invoices that describe the work or simply
handwritten descriptions of the maintenance
performed.
Malfunction records. Records of the
occurrence, duration, and cause of any
malfunction of the process, air pollution control
device, and monitoring equipment must be
maintained. If the actions required to correct
the malfunctions were consistent with those
described in the operation and maintenance
(O&M) plan, then records of these actions need
not be maintained. However, records of the
actions taken to correct the malfunction when the
actions are inconsistent with the O&M plan must
be maintained, and the plan must be revised
accordingly.
An example of a control device malfunction
is the settling of packing material in a packed-
bed scrubber. After the initial installation of the
unit, the packing material settles which
sometimes opens up a gap in the top of
horizontal flow units. Settling of the packing
material should be indicated by a loss in
pressure drop across the unit because the air
flow is following the path of least resistance and
bypassing the packed bed. To correct this
problem, additional packing material should be
added to the top of the packed bed.
Performance test results. Test reports
documenting the results of performance tests
conducted on the affected source must be
Page 31
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WHAT RECORDKEEPING AND REPORTING WILL I NEED TO DO?
CHAPTER 6
maintained. The test report must contain
process and air pollution control system
operating parameter measurements obtained
during testing as described in Table 5-1. Any
additional measurements required for those
facilities using a common control system to
reduce emissions from multiple sources at a
facility should also be included in the test report.
Monitoring data records. Records of the
monitoring data used to determine compliance
with the emission limits must also be
maintained. Table 5-3 lists the monitoring
requirements for each of the air pollution control
systems. Monitoring data can be recorded on a
simple form that identifies the control system,
the monitored parameter(s), the value of the
monitored parameter(s), and the time and date
when the parameter was monitored. An
example of a monitoring data form developed
for a packed-bed scrubber is provided in
Appendix E of this guidebook.
Excess emissions records. Excess
emissions occur when the values of the
monitored parameters exceed the value or range
of values established under the performance test.
You must record the start and end times and
dates of each period of excess emissions,
regardless of the cause of the excess emissions.
The example monitoring data form in
Appendix E of this guidebook provides a space
to record the start and end times of excess
emissions episodes.
Process records. All tanks. The process
operating time for each chromium electroplating
or chromium anodizing tank must be recorded.
For those tanks using fume suppressants, the
date and time of each addition of fume
suppressants must be recorded.
Hard chromium tanks. If you are using the
actual rectifier capacity to demonstrate that your
facility is "small" (for purposes of the emission
limits), then the actual rectifier capacity
expended by month and the total capacity
expended for the reporting period (semiannual
for major sources and annual for area sources)
must be recorded.
Decorative chromium tanks. For decorative
chromium electroplating tanks using a trivalent
chromium bath, records of the bath components
purchased must be maintained with the wetting
agent clearly identified as a bath constituent
contained in one of the bath components. These
records may be invoices showing the bath
components (including the wetting agent),
quantities purchased, and date of purchase.
Miscellaneous records. You are required
to keep a copy of your O&M plan on record.
Records that support the reporting requirements
described below and that support any petitions to
the EPA (e.g., requests to waive the record-
keeping or reporting requirements of the
regulation) must also be maintained.
REPORTING
The regulation requires that sources submit
reports and notifications, which include:
/ Initial notification
-------
CHAPTER 6
WHAT RECORDKEEPING AND REPORTING WILL I NEED TO DO?
/ Notification of compliance status
• If construction or reconstruction com-
menced after January 25, 1995, a
notification of the date when construc-
tion or reconstruction commenced
within 30 calendar days after the com-
mencement date.
A notification of the actual startup date of the
source must be submitted within 30 calendar
days after that startup date.
Notification of construction/reconstruction.
After January 25, 1995, no one may begin
construction or reconstruction of new or
reconstructed sources without submitting a
notification of construction/reconstruction to the
Administrator. Construction or reconstruction
may begin as soon as the notification of
construction/reconstruction has been submitted;
approval by the Administrator is not required.
If construction or reconstruction commenced
before January 25, 1995, but startup did not
occur, then a notification of construction/
reconstruction must be submitted by March 26,
1995. An example form for notification of
construction/reconstruction is provided in
Appendix E of this guidebook.
Notification of initial performance test.
You must notify the Administrator in writing of
intent to conduct an initial performance test at
least 60 calendar days before the scheduled date
of the test to allow the Administrator to have an
observer present at the test. The Administrator
may or may not choose to have an observer
present. An example form for notification of
initial performance test is provided in
Appendix E of this guidebook.
Page 33
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WHAT RECORDKEEPING AND REPORTING WILL I NEED TO DO?
CHAPTER 6
TIMELINE
ALL SOURCES
1995
Regulation published in Federal Register (effective date) • • 1/25/95
Initial notification due • • 7/24/95
DECORATIVE
1996
Sources must be in compliance
Notification of compiance status due for sources that do not have to test
Notification of performance test due
Testing must be completed
1/25/96
2/2496
60 days before test
7/23/96
Notification of test results & compliance status due • • 90 days after test
HARD AND ANODIZING
1997
Sources must be In compliance • • 1/25/97
Notification of performance test due
Testing must be completed
60 days before test
7/24/97
Notification of test results & compliance status due • • 90 days after test
Figure 6-1. Timeline for reporting requirements.
Page 34
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CHAPTER 6
WHAT RECORDKEEPING AND REPORTING WILL I NEED TO DO?
If the scheduled date for the test is changed
for unforeseen reasons, you must inform the
Administrator within 5 calendar days of the
originally scheduled test date and must specify
the date of the rescheduled test.
Notification of compliance status. You
must submit a notification of compliance status
within 90 days after your initial performance test
(if testing is required) or no later than 30 days
after your compliance date (if testing is not
required). If testing is required, a copy of the
test report must be submitted as support for the
test results shown (see Table 5-1 for a list of
items to be included in the test report). If a
title V permit has not been issued to your
source, you should send the notification of
compliance status to the Administrator. If a
title V permit has been issued, you should send
the notification of compliance status to the
appropriate permitting authority. An example
form for notification of compliance status is
provided in Appendix E of this guidebook.
Ongoing compliance status reports for
major sources. If your source is located at a
major source site, you must submit ongoing
compliance status reports to the Administrator
every six months. The Administrator may
decide on a case-by-case basis to require a
source to submit ongoing compliance status
reports more frequently. Additionally, if a
source experiences exceedances of the emission
limits as indicated by ongoing monitoring of air
pollution control system operating parameters,
then the source will be required to submit
quarterly reports. An example form for
reporting ongoing compliance status is provided
in Appendix E of this guidebook.
Reduced reporting frequency. A source
that is required to submit ongoing status reports
on a quarterly or more frequent basis may
reduce the frequency of reporting to semiannual
if the following conditions are met:
* the ongoing compliance status reports
show that the source is in compliance
for a full year (e.g., four quarterly or
12 monthly reporting periods);
>• the source complies with all applicable
recordkeeping and monitoring require-
ments; and
>• the Administrator does not object to a
reduced reporting frequency.
To reduce the reporting frequency, the
source must notify the Administrator of its inten-
tion to make the change. This notification can
take the form of a simple letter to the Adminis-
trator that describes the initial exceedance (that
caused the source to have to report more
frequently), any actions taken to address the
exceedance, the subsequent period of compliance
(at least 1 year), and the intention of the
owner/operator to reduce the frequency of
submittals of ongoing compliance status reports.
The Administrator may review all previously
submitted reports or records kept by the source
to make a judgement on whether the reduced
frequency request should be approved.
Approval is automatically granted if the
Administrator does not issue a notice of
disapproval within 45 days after the request is
submitted.
Ongoing compliance status reports for
area sources. The owner/operator of an
affected area source must also prepare ongoing
Page 35
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WHAT RECORDKEEPING AND REPORTING WILL I NEED TO DO?
CHAPTER 6
compliance status reports that contain the same
information described above for major sources.
The reports must be prepared annually and
retained onsite and must be made available to
the Administrator on request. The example
form for an ongoing compliance status report
provided in Appendix E of this guidebook may
be used to fulfill this requirement.
However, if both of the following condi-
tions are met, then semiannual reports must be
prepared and submitted to the Administrator:
* the total duration of excess emissions
(as indicated by monitoring data) is
1 percent or greater of the total
operating time for the reporting period
and
> the total duration of malfunctions of the
add-on air pollution control equipment
and monitoring equipment is 5 percent
or greater of the total operating time.
Regardless if these conditions are met, the
Administrator or the permitting authority may
choose to require that ongoing compliance status
reports be completed more frequently (e.g.,
semiannuallyj and be submitted.
An area source may petition the Adminis-
trator (as described above for major sources) to
reduce the frequency of reporting and/or retain
the required reports onsite.
Reports associated with trivalent chromium
baths. If you use a trivalent chromium bath,
you must submit the following reports instead of
the reports described above:
> By July 24, 1995, an initial notification
(Appendix E of this guidebook provides
an example initial notification report)
and
*• By February 24, 1996, a notification of
compliance status that updates the
information in the initial notification or
a statement that the initial notification is
still accurate.
If you decide to change your process (e.g., from
using a trivalent chromium process to using a
hexavalent chromium process because of
problems with the plating quality), you must
submit a report within 30 days after the change
that includes:
> a description of the change and any
change in the emission limit and
* if a different emission limit applies, the
information required in the initial
notification described above.
In addition, you must submit all other applicable
notifications described above according to the
schedules shown.
Page 36
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CHAPTER 7
WHAT ARE MY POLLUTION PREVENTION OPTIONS?
What is Pollution Prevention? As stated in
the Pollution Prevention Act of 1990, Congress
has declared it to be the nation's policy that,
wherever feasible, pollution should be prevented
or reduced at the source. The Act states that
source reduction is more desirable than waste
management and pollution control. Source
reduction is defined as any practice that reduces
the amount of any hazardous substance entering
the waste stream or otherwise released into the
environment prior to recycling, treatment, or
disposal. Therefore, you must also consider
wastewater, hazardous waste, and solid waste
effects and regulations as well as air in selecting
any method of control.
What are my options? This regulation
allows for pollution prevention measures to be
used when complying with the requirements of
the regulation. There are two source reduction
alternatives available. The first is the use of
chemical fume suppressants to inhibit chromium
emissions at the source—the electroplating or
anodizing tank. The second source reduction
technique involves the use of a trivalent
chromium electroplating process instead of the
traditional hexavalent chromium (chromic acid)
process.
Even though add-on pollution control
measures are not considered source reduction
measures, the add-on pollution control
techniques described in the regulation (i.e.,
composite mesh-pad systems and packed-bed
scrubbers) have a pollution prevention aspect.
These pollution control measures allow closed-
loop recycling of all collected chromium as well
as concentration of process rinsewaters for some
decorative chromium plating operations.
Which method should I use? There are
advantages and disadvantages associated with
each pollution prevention method that you
should consider before selecting a method. The
advantages and disadvantages are summarized
below. In general, the advantages of a method
and the benefits of pollution prevention to the
owner or operator outweigh the disadvantages.
Fume suppressants. Fume suppressants are
used widely and effectively in decorative
chromium electroplating and chromic acid
anodizing operations and less frequently in hard
chromium electroplating operations. The
disadvantages of using fume suppressants are:
© some wetting agents have a tendency
to aggravate pitting and
© foam blankets that are too thick en-
trap hydrogen gas, which poses an
explosion hazard.
Page 37
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WHAT ARE MY POLLUTION PREVENTION OPTIONS?
CHAPTER 7
The advantages of using fume suppressants are:
© minimization of plating solution
evaporation losses;
© a very low-cost of chromium emission
control;
© no impact on energy consumption;
and
© no impact on solid waste generation.
Trivalent chromium process. Trivalent
chromium processes are very effective in
reducing chromium emissions from decorative
chromium electroplating operations. Disadvan-
tages of using trivalent chromium processes are:
© careful rinsing is required to minimize
bath contamination;
© the finish of satin nickel may appear
more gray than blue; and
© post treatment may be required to
passivate unplated areas for corrosion
resistance.
While there are some disadvantages and
problems associated with the use of trivalent
chromium processes, most can be overcome with
process adjustments (e.g., careful rinsing to
minimize bath contamination). The advantages
of using trivalent chromium processes are:
© lower toxicity than hexavalent
chromium;
© reduced waste disposal problems and
costs compared to use of hexavalent
chromium;
© provides better covering and throwing
power than hexavalent chromium;
© eliminates "burning;" and
© provides enhanced corrosion resist-
ance compared to hexavalent
chromium.
Page 38
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CHAPTERS
HOW DOES THIS REGULATION RELATE TO OTHER FEDERAL AND
STATE OR LOCAL REQUIREMENTS?
PERMITTING
Will I need a permit ? The final chromium
electroplating regulation that was published in
the Federal Register on January 25, 1995
required all sources, major and nonmajor (i.e.,
area), to obtain a title V operating permit.
However, the EPA is considering amending the
final regulation to:
* Allow States to defer for 5 years (i.e.,
up to December 1999) all nonmajor
hard chromium electroplating operations
from the requirement to obtain a title V
permit;
*• Exempt all nonmajor decorative
chromium electroplating and chromium
anodizing operations that use fume
suppressants as an emission reduction
technology from the requirement to
obtain a title V permit; and
*• Exempt all nonmajor decorative
chromium electroplating operations that
use a trivalent chromium bath that
incorporates a wetting agent as a bath
ingredient.
It should be stressed that EPA is considering this
deferral and these permanent exemptions for
nonmajor sources only. Under title V, all major
sources are required to obtain permits-no
deferrals or exemptions are allowed for these
major sources.
Title V operating permit program
background. Title V of the CAA Amendments
of 1990 required the establishment of State-
implemented operating permit programs with
Federal oversight. Prior to the 1990
amendments, sources were not required by
Federal law to obtain operating permits for air
emissions. However, many States issued their
own operating permits to certain sources. You
may have been required to obtain an operating
permit for your facility under a State permit
program in the past. Now, you may be required
to obtain a title V operating permit.
Permit requirements in general. The
operating permit program will incorporate all
applicable Federal CAA regulation requirements
and any State or local government requirements.
Therefore, permit requirements will be at least
as stringent as requirements mandated by the
Federal CAA regulations (e.g., the chromium
emission standards for electroplaters).
The basic format of operating permits is
detailed (codified) in a new part 70 of title 40 of
the Code of Federal Regulations (40 CFR
part 70). Owners or operators of facilities
subject to Federal CAA regulations will have to:
> submit a permit application;
* submit compliance plans and schedules;
> comply with all applicable air emission
limits and standards listed in the permit
Page 39
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HOW DOES THIS REGULATION RELATE TO OTHER
FEDERAL AND STATE OR LOCAL REQUIREMENTS?
CHAPTERS
(e.g., the chromium emission standards
for electroplaters);
* monitor actual emissions, submit moni-
toring reports, and make an annual
certification of the source's compliance
status;
»• submit applications for any permit
modifications;
*• submit applications for permit renewals
every 5 years; and
*• pay a permit or emission fee.
States are allowed to develop one general
permit to cover similar small businesses or
industrial processes. Thus, States may choose to
develop a "general permit" that would cover
chromium electroplating and anodizing facilities.
The EPA is currently developing a model
general permit for this source category.
Does my State have a permitting program?
All States must develop a title V operating
permit program. States were required to submit
their permitting programs to EPA for approval
by November 15, 1993. One year later, the
EPA was to have approved the States' permitting
programs and authorized the States to administer
their programs. As of November 1994, EPA
had proposed to approve only 12 State agency
programs and 7 local agency programs. The
EPA's Technology Transfer Network (TTN), an
electronic bulletin board system, has the latest
status of permit program submittals and
approvals. (See Chapter 10 for instructions on
how to access the TTN.) You may also contact
your State or local air pollution control agency
for more information on the status of your
State's title V operating permit program.
If a State does not develop an acceptable
title V operating permit program, the EPA will
implement a Federal permit program for sources
in that State.
When do I apply for my operating permit?
Your deadline for submitting a title V operating
permit application will depend on when your
State or local title V permitting program is
approved by the EPA. In general, your
application will be due within 12 months after
this approval date. However, some State and
local permitting authorities have shorter
deadlines. Regardless, you will be required to
submit your application by November 15, 1996
at the latest because title V requires either a
Federal or State program to be in place by
November 15, 1995. Once you have your
operating permit, it must be renewed or updated
at least every 5 years.
Where can I get help with my permit?
States are developing small business assistance
programs (SBAP's) to assist small businesses
with the permitting process. Contact EPA's
Control Technology Center (CTC) Hotline at
(919) 541-0800 for information on your State
SBAP contacts. Small businesses may also be
eligible for reduced permitting fees. You can
also contact your State or local permitting
authority for more information on small business
permitting assistance.
EPA's GENERAL PROVISIONS
On March 16, 1994, EPA published the
General Provisions for all regulations codified in
pan 63 (i.e., all NESHAP). These General
Page 40
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CHAPTER 8
HOW DOES THIS REGULATION RELATE TO OTHER
FEDERAL AND STATE OR LOCAL REQUIREMENTS?
Provisions were published in the Federal
Register in volume 59, beginning on
page 12408. When a source becomes subject to
a regulation in part 63, it automatically is
subject to the General Provisions as well.
However, individual regulations in part 63 may
override part or all of the General Provisions.
In the case of this regulation, EPA has over-
ridden some of the requirements of the General
Provisions. Table 1 of the chromium electro-
plating regulation (located in Appendix A on
pp. 4976-4979) explains in detail which sections
apply and which sections are overridden.
STATE OR LOCAL CHROMIUM
ELECTROPLATING REGULATIONS
State or local requirements that may have
affected you prior to the new Federal regulation
for chromium electroplaters and anodizers
continue to apply. The new Federal regulation
is the minimum emission control that is required
nationally. Some State and local agencies do
require stricter limits. If the current State or
local standard is less stringent than the Federal
regulation, the Federal regulation must be met.
The format of State or local standards may
be different also. For example, the California
Air Resources Board Airborne Toxic Control
Measure for this source category expresses
emission limits in terms of process emission
rates rather than emission concentrations.
Through source testing, you will be measuring
the concentration of emissions at the outlet in
mg/dscm, which is the format needed to comply
with EPA's regulation. From this, you may
convert to another format, such as mg/Amp-hr
required in the CARB regulation.
In addition to air pollution regulations,
chromium electroplating and anodizing opera-
tions may also be subject to wastewater and
solid waste disposal regulations.
Page 41
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HOW DOES THIS REGULATION RELATE TO OTHER
FEDERAL AND STATE OR LOCAL REQUIREMENTS? CHAPTER 8
Page 42
-------
CHAPTER 9
HOW MUCH WILL IT COST?
EMISSION CONTROL COSTS
The emission control costs for each of the
control technologies in the regulation are
summarized in Table 9-1. Ranges of costs are
presented in the table because actual control
costs will vary considerably depending on the
size of the facility. Also, separate cost ranges
are given for new versus existing facilities
because of the added cost to retrofit existing
facilities. For detailed cost information, refer to
the other EPA guidance materials listed in
Chapter 10 of this guidebook.
What do the capital costs include? The
installed capital costs include:
* the purchased cost of the control device
and cost for auxiliaries, such as inlet
and outlet transition zones, exhaust fans
and motors, and stack;
* direct installation costs for erection,
electrical panels and wiring, instru-
mentation and controls, and piping; and
»• startup costs.
What do the annualized costs include?
The annualized costs include:
* direct operating costs, such as utilities;
* labor and maintenance materials;
>• replacement parts;
* disposal and transportation of the used
impaction material;
>• indirect operating costs, such as
overhead, property taxes, insurance and
administration;
* capital recovery costs; and
>• chromic acid recovery credits.
SOURCE TESTING COSTS
As discussed in Chapter 5, initial
performance testing is required if you are using
a control device to comply with the regulation.
Ongoing testing is not required by the
regulation. The estimated cost to perform the
initial performance test using EPA Reference
Method 306 is about $4,500 per stack if you
hire an outside testing firm. However, you may
choose to do the testing inhouse using EPA
Reference Method 306A, which is simpler and
less expensive than Method 306. The costs
associated with performing one test using
Method 306A are shown below:
Sampling train
Pilot, manometer, chemicals
Labor
Analysis
TOTAL COST
If you conduct your own performance test, you
save an estimated $3,350 over having an outside
testing firm do the work. Besides this initial
Page 43
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HOW MUCH WILL IT COST?
CHAPTER 9
TABLE 9-1. ESTIMATED EMISSION CONTROL COSTS3
Control technology
Fume suppressants (FS)
Packed-bed scrubber
(PBS)
Composite mesh-pad
(CMP) system
Combination PBS/CMP
system
Fiber-bed mist eliminator
(FEME)
Capital costs, $
New
none
39,400
to 159,500
29,200
to 154,300
62,400
to 210,200
123,200
to 540,400
Existing
none
49,300
to 199,400
36,500
to 192,900
78,000
to 262,800
135,500
to 739,700
Annual ized costs, $
New
1,100
to 18,500
10,400
to 4 1,700
14,500
to 82,400
18,300
to 77,500
31,100
to 160,400
Existing
1,100
to 18,500
11,900
to 47,900
16,000
to 90,400
20,700
to 86,000
33,000
to 168,000
a!994 dollars.
cost savings, your company would also get to
keep the equipment. If any additional testing is
necessary, it would cost only about $510 (for
labor, analysis, and chemicals) rather than an
additional $4,500 per stack.
MONITORING EQUIPMENT COSTS
Stalagmometers, which are devices used to
measure the surface tension of the plating bath,
cost about $128.* Tensiometers may also be
used to measure surface tension and cost about
i-\
$80.z A stainless steel S-type pitot tube, used to
measure velocity pressure at the inlet of a
control device, costs from about $50 to $65
depending on the length of the tube. In this
application, pitot tubes may have to be replaced
about every 4 months due to corrosion. A
pressure gauge used to monitor pressure drop
(e.g., a magnehelic gauge) costs about $120.
Monitoring equipment are available from
numerous vendors. You may consult your fume
suppressant supplier for recommendations on
how to obtain the equipment.
1 Price quote from Lurex Scientific.
^Price quote from Fisher Scientific.
MONITORING, RECORDKEEPING,
AND REPORTING COSTS
The average ongoing annual cost for
monitoring, recordkeeping, and reporting is
about $2,300 per facility. (Sources that have to
perform initial testing will incur additional
upfront costs associated with the testing and
notification requirements.) This cost estimate is
an average for all types and sizes of operations;
small sources will incur lower costs due to the
reduced requirements for these sources.
Page 44
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CHAPTER 9
HOW MUCH WILL IT COST?
PERMITTING FEES
As discussed in Chapter 8, you may be
required by the regulation to obtain an operating
permit under title V of the CAA. If so, you will
be charged a permit or emission fee by your
State or local permitting authority when you
apply for your title V permit. This fee will vary
from State to State. For more information on
title V operating permit fees, contact your State
or local permitting authority or the EPA
Regional Office for your State.
Page 45
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HOW MUCH WILL IT COST? CHAPTER 9
Page 46
-------
CHAPTER 10
WHERE CAN I GO FOR MORE INFORMATION AND ASSISTANCE?
TELEPHONE CONTACTS
For more information on how to comply
with this regulation, please call:
» your State or local air pollution control
agency;
» your local, regional, or national metal
finishers trade association;
» your State Small Business Assistance
Program; or
« your State Small Business Ombudsman.
For information on your State Small Business
Assistance Program contacts, call EPA's Control
Technology Center Hotline at (919) 541-0800.
Also, for more information, you may call
the EPA Regional Office that serves your State
or territory. Table 10-1 lists the telephone
numbers of the 10 EPA Regional Offices and the
States and territories that they serve.
EPA's ELECTRONIC BULLETIN
BOARD SYSTEM
(919) 541-5742. Assistance with the TTN is
available by calling (919) 541-5384.
OTHER EPA GUIDANCE MATERIALS
In developing this regulation, EPA has
prepared other materials that provide more
information on the technical aspects of the
regulation. These include:
> Chromium Emissions from Chromium
Electroplating and Chromic Acid
Anodizing Operations—Background
Information for Proposed Standards
(Volumes I and II). EPA-453/R-93-030a
and 030b. July 1993.
*• Technical Assessment of New Emission
Control Technologies Used in the Hard
Chromium Electroplating Industry.
EPA-453/R-93-031. July 1993.
*• Chromium Emissions from Chromium
Electroplating and Chromic Acid Anod-
izing Operations-Background Informa-
tion for Promulgated Standards.
EPA-453/R-94-082b. November 1994.
The EPA operates an electronic bulletin
board, the Technology Transfer Network or
"777V," which contains copies of preambles and
regulations, background information documents,
policy memoranda, and other guidance
materials. You may access portions of the
EPA's TTN via modem by dialing
Copies of these reports are available through
EPA's Library Services Office (MD-35), U. S.
Environmental Protection Agency, Research
Triangle Park, North Carolina 27711,
(919) 541-2777; on EPA's TTN; or, for a fee,
from the National Technical Information
Services, 5285 Port Royal Road, Springfield,
Virginia 22161, (703) 487-4600.
Page 47
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WHERE CAN I GO FOR MORE INFORMATION AND ASSISTANCE?
CHAPTER 10
TABLE 10-1. EPA REGIONAL OFFICE CONTACTS
Region
1
2
3
4
5
6
7
8
9
10
Telephone #
(617) 565-3728
(212) 637-4023
(215) 597-3237
(404) 347-2864
(312) 886-6793
(214) 665-7225
(913) 551-7097
(303) 293-1886
(415)744-1143
(206) 553-1949
States covered
CT, ME, MA, NH, RI
& VT
NJ, NY, Puerto Rico
& Virgin Islands
DE, MD, PA, VA,
WV & District of
Columbia
AL, FL, GA, KY,
MS, NC, SC & TN
IL, IN, MI, WI, MN
&OH
AR, LA, NM, OK &
TX
IA, KS, MO & NE
CO, MT, ND, SD,
UT& WY
AZ, CA, HI, NV,
American Samoa &
Guam
AK, ID, WA & OR
Address
Director, Air, Pesticides and Toxics Division
J.F.K. Federal Building
Boston, MA 02203-2211
Director, Air and Waste Management Division
290 Broadway
21st Floor
New York, NY 10007-1866
Director, Air, Radiation and Toxics Division
841 Chestnut Street
Philadelphia, PA 19107
Director, Air, Pesticides and Toxics
Management Division
345 Courtland Street, NE
Atlanta, GA 30365
Director, Air and Radiation Division
77 West Jackson Blvd.
Chicago, IL 60604-3507
Director, Air, Pesticides and Toxics
1445 Ross Avenue
Dallas, TX 75202-2733
Director, Air and Toxics Division
726 Minnesota Avenue
Kansas City, KS 66101
Director, Air and Toxics Division
999 18th Street
1 Denver Place, Suite 500
Denver, CO 80202-2405
Director, Air and Toxics Division
75 Hawthorne Street
San Francisco, CA 94105
Director, Air and Toxics Division
1200 Sixth Avenue
Seattle, WA 98101
Also, EPA has developed a videotape to
assist sources in using EPA Reference
Method 306A entitled Construction and
Operation of the EPA Method 306A Sampling
Train and Practical Suggestions for Monitoring
of Electroplating and Anodizing Facilities. This
videotape is available for a nominal fee through
North Carolina State University, Registrar,
Environmental Programs, Box 7513, Raleigh,
North Carolina 27695-7513. The telephone
number is (919) 515-5875.
Page 48
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APPENDIX A
FEDERAL REGISTER NOTICE;
FINAL RULE
-------
Wednesday
January 25, 1995
Part II
Environmental
Protection Agency
40 CFR Parts 9 and 63
National Emission Standards for
Chromium Emissions From Hard and
Decorative Chromium Electroplating and
Chromium Anodizing Tanks; Final Rule
-------
4948
Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Parts 9 and 63
[AD-FRL-5115-7]
RIN 20CO-AC14
National Emission Standards for
Chromium Emissions From Hard and
Decorative Chromium Electroplating
and Chromium Anodizing Tanks
AGENCY: Environmental Protection
Agency (EPA).
ACTION: Final rule.
SUMMARY: Pursuant to section 112 of the
Clean Air Act as amended in 1990 (the
Act), this action promulgates final
standards that limit the discharge of
chromium compound air emissions
from existing and new hard chromium
electroplating, decorative chromium
electroplating, and chromium anodizing
tanks at major and area sources.
Chromium compounds are among the
189 hazardous air pollutants (HAP)
listed for regulation under section 112
of the Act. Hard and decorative
chromium electroplating and chromium
anodizing tanks have been identified by
the EPA as significant emitters of
chromium compounds to the
atmosphere. The purpose of the final
rale is to reduce chromium compound
air emissions from the source categories
identified above. All affected sources
must limit emissions to the level of the
maximum achievable control
technology (MACT). The EPA is also
finalizing Methods 306, 306A, and 306B
with these standards.
DATES: Effective Date: January 25. 1995.
Incorporation by Reference. The
incorporation by reference of certain
publications in this standard is
approved by the Director of the Office
of the Federal Register as of January 25,
1995.
Judicial Review. Under section
307(b)(l) of the Act, judicial review of
national emission standards for
hazardous air pollutants (N'ESHAP) is
available only by filing a petition for
review in the U.S. Court of Appeals for
the District of Columbia Circuit within
60 days of today's publication of this
final rule. Under section 307(b)(2) of the
Act, the requirements that are the
subject of today's notice may not be
challenged later in civil or criminal
proceedings brought by the EPA to
enforce these requirements.
ADDRESSES: Docket. Docket No. A-88-
02, containing information considered
by the EPA in developing the
promulgated NESHAP for hard and
decorative chromium electroplating and
chromium anodizing tanks is available
for public inspection and copying
between 8 a.m. and 5:30 p.m., Monday
through Friday, except for Federal
holidays, at the EPA's Air and Radiation
Docket and Information Center, Room
M1500, U. S. Environmental Protection
Agency, 401 M Street, S\V., Washington.
DC 20460; telephone (202) 260-7548. A
reasonable fee may be charged for
copying.
Background Information Document. A
background information document (BID)
for the promulgated NESHAP may be
obtained from the docket; the U. S. EPA
Library (MD-35), Research Triangle
Park, North Carolina 27711, telephone
(919) 541-2777; or from National
Technical Information Services, 5285
Port Royal Road, Springfield, Virginia
22161, telephone (703) 487-4650. Please
refer to "Chromium Emissions from
Chromium Electroplating and Chromic
Acid Anodizing Operations—
Background Information for
Promulgated Standards" (EPA-^SS/R-
94-=082b). The BID contains a summary
of the public comments made on the
proposed standards and EPA responses
to the comments.
FOR FURTHER INFORMATION CONTACT: Mr.
Lalit Banker of the Emission Standards
Division (MD—13), U. S. Environmental
Protection Agency, Research Triangle
Park. North Carolina 27711; telephone
(919) 541-5420.
SUPPLEMENTARY INFORMATION: The
information presented in this preamble
is organized as follows:
I. Background
II. Summary
A. Summary of Promulgated Standards
B. Summary of Major Changes Since
Proposal
III. Summary of Environmental, Energy. Cost.
and Economic Impacts
A. Environmental and Energy Impacts
B. Cost Impacts
C. Economic Impacts
IV. Public Participation
V. Significant Comments and Responses
A. Selection of Source Categories and
Pollutants to be Regulated
B. Selection of MACT/GACT Approach
C. Selection of MACT for Hard Chromium
Electroplating Tanks
, D. Selection of MACT for Decorative
Chromium Electroplating and Chromium
Anodizing Tanks
E. Selection of the Format of the Standard
F. Selection of the Emission Limits »
G. Selection of Compliance Dates
H. Selection of Monitoring Requirements_
I. Selection of Test Methods
J. Selection of Reporting and
Recordkeeping Requirements
K. Operating Permit Program
VI. Administrative Requirements
A. Docket
B. Executive Order 12866
C. Paperwork Reduction Act
D. Regulatory Flexibility Act
E. Miscellaneous
I. Background
Section 112(b) of the Act lists 189
HAP and requires the EPA to establish
national emission standards for all
major sources and some area sources of
those HAP. Among the listed pollutants
are chromium compounds. On July 16,
1992 (57 FR 31576)'. the EPA published
a list of major and area sources for
which NESHAP are to be promulgated
and on December 3,1993 (58 FR 83941).
the EPA published a schedule for
promulgation of those standards. The
hard and decorative chromium
electroplating and chromium anodizing
source categories are included in the list
of major and area sources for which the
EPA is to establish national emission
standards by November 1994.
This NESHAP was proposed in the
Federal Register on December 15, 1993
(58 FR 65768). A public hearing on this
rule was conducted on January 20, 1994.
In addition, 62 letters commenting on
the proposed rule were received during
the public comment period, and 3 late
comments were received.
II. Summary
A. Summary of Promulgated Standards
The final rule applies to major and
area sources performing hard chromium
electroplating, decorative chromium
electroplating, and chromium
anodizing. The affected source is each
chromium electroplating or chromium
anodizing tank. The emission
limitations for each of these source
categories are summarized in Table 1.
These emission limitations apply only
. during tank operation, including
periods of startup and shutdown. The
emission limitation for all new hard
chromium electroplating tanks, and for
existing hard chromium electroplating
tanks that are located at large, hard
chromium electroplating facilities is
based on the use of a composite mesh-
pad system. The emission limitation for
existing hard chromium electroplating
tanks located at small, hard chromium
electroplating facilities is based on the
use of a packed-bed scrubber. Fo>- all
existing and new sources performing
decorative chromium electroplating and
all existing and new sources performing
chromium anodizing, the standard is
based on the use of fume suppressants.
Even though these technologies formed
the bases for the standards, any
technology can be used as long as it is
demonstrated to meet the prescribed
emission limitation. All area and major
sources must limit emissions to the
level of the maximum achievable
control technology (MACT).
-------
Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations 494^
TABLE 1.—STANDARDS FOR CHROMIUM ELECTROPLATING AND CHROMIUM ANODIZING TANKS BASED ON MACT
Type of tank
Emission limitations
Small
Large
Hard Chromium Plating Tanks
All existing tanks
All new tanks
0.03 mg/dcsm (1.3x1Q-J gr/dscf) ..
0.015 mg/dcsm (6.6x10~6 gr/dscf)
0.015 mg/dscm (6.5x10"6 gr/dscf]
0.015 mg/dscm (6.6x10~6 gr/dscf)
Decorative Chromium Plating Tanks Using a Chromic Acid Bath
All new and existing tanks
0.01 mg/dscm->(4.4xlO-4 gr/dscf)
Chromium Anodizing Tanks
All new and existing tanks
0.01 mg/dscm1(4.4xlO"6 gr/dscf)
Mn accordance with §63.342(d){2), owners or operators using a fume suppressant containing a wetting agent as a control technique can meet
an alternate emission limitation of 45 dynes/cm (3.1x10~J Ibf/f!)-
Owners and operators of all affected sources are also subject to work practice standards, which require them to
complete an operation and maintenance (O&M) plan that contains the minimum elements of §63.342(f)(3) and Table
2.
TABLE 2.—SUMMARY OF WORK PRACTICE STANDARDS
Control technique
Work practice standards
Frequency
Composite mesh-pad (CMP) sys-
tem.
Packed-bed scrubber (PBS)
PBS/CMP system
Fic-er-bed mist eliminator«
Air pollution control device (APCD)
not listed in rule.
1. Visually inspect device to ensure there is proper drainage, no chro-
mic acid buildup on the pads, and no evidence of chemical attack
on the structural integrity of the device.
2. Visually inspect back portion of the mesh pad closet to the fan to
ensure there is no breakthrough of chromic acid mist.
3. Visually inspect ductwork from tank or tanks to the control device
to ensure there are no leaks.
4. Perform washdown of the composite mesh-pads in accordance
with manufacturers recommendations.
1. Visually inspect device to ensure there is proper drainage, no chro-
mic acid buildup on the packed beds, and no evidence of chemical
attack on the structural integrity of the device.
2. Visually inspect back portion of the chevron blade mist eliminator
to ensure that it is dry and there is no breakthrough of chromic acid
mist.
3. Same as number 3 above ;
4. Add fresh makeup water to the top of the packed bed *•»
1. Same as for CMP system
2. Same as for CMP system
3. Same as for CMP system
4. Same as for CMP system
1. Visually inspect fiber-bed unit and prefiltering device to ensure
there is proper drainage, no chromic acid buildup in the units, and
no evidence of chemical attack on the structural integrity of the de-
vices.
2. Visually inspect ductwork from tank or tanks to the control device
to ensure there are no leaks.
3. Perform washdown of fiber elements in accordance with manufac-
turers recommendations.
To be proposed by the source for approval by the Administrator
1. 1/quarter.
2. 1/quarter.
3. 1/quarier.
4. Per manufacturer.
1. 1/quarter.
2. 1/quarter.
3. 1/quarter.
4. Whenever makeup is added.
1. 1/quarter.
2. 1/quarter.
3. 1/quarter.
4. Per manufacturer.
1. I/quarter.
2. I/quarter.
3. Per manufacturer.
To be proposed by the source for
approval by the Administrator.
Monitoring Equipment
Pilot lube
Slalagmometer
Backflush with water, or remove from the duct and rinse with fresh
water. Replace in the duct and rotate 180 degrees to ensure that
the same zero reading is obtained. Check pilot tube ends for dam-
age. Replace pilot tube if cracked or fatigued.
Follow manufacturers recommendations.
1/quarter.
'II greater than 50 percent of the scrubber water is drained (e.g., for maintenance purposes), makeup water may be added to the scrubber
basin.
» For horizontal-flow scrubbers, top is defined as the section of the unit directly above the packing media such that the makeup water would
flow perpendicute' la Sue si flow tswough the packing. For vertical-flow units, the top is defined as the area downstream of the packing material
such that the makeisp wase* woufcJ flow countercurrent to the air flow through the unit.
'Work practice standards for the control device installed upstream of the fiber-bed mist eliminator to prevent plugging do not apply as long as
the work practice standards for the fiber-bed unit are followed.
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,950 Federal Register / Vol. 60, No. 16 / Wednesday, January 25. 1995 / Rules and Regulations
All existing sources performing hard
chromium electroplating and chromium
anodizing must comply with the
emission limitations within 2 years of
January 25, 1995. All existing sources
performing decorative chromium
electroplating must comply with the
emission limitations within 1 year of
January 25,1995. All new and
reconstructed sources must comply
immediately upon startup.
Sources must demonstrate initial
compliance with the prescribed
emission limitation in accordance with
§§ 63.343[b) and 53.344. Continuous
compliance is demonstrated through the
monitoring required by § 64.343(c), as
summarized in Table 3. As indicated in
this table, the type of compliance
monitoring performed is based on the
type of control technique used to
comply with the emission limitation,
not the type of source being controlled.
TABLE 3.—SUMMARY OF MONITORING REQUIREMENTS
Control
technique
Composite mesh-pad (CMP)
system.
Packed-bed scrubber (PSB)
P3S/CMP system
Fiber-bed mist eliminator
suppressant.
Foam blankets
Air pollution control device
(APCD) not listed in rule.
Initial compliance test
Yes
Yes
Y°s
Yes
§53.343;b)(2) are met).
Yes
Yes
Parameter(s) for compliance monitoring
Pressure drop across the unit -
Velocity pressure at the inlet of the control system and
pressure drop across the unit
Pressure drop across the unit
Pressure drop across the fiber-bed mist eliminator and
the pressure drop across the upstream control device
used to prevent plugging.
Foam thickness
To be proposed by the source (or approval by Adminis-
trator.
Frequency of compli-
ance monitoring
1/day.
1/day.
i/day
1/day.
Once every 4 hours.3
Once per hour.-1
N/A.
•Frequency can be decreased according to §63.343 (c)(5)(ii) and (c)(6)(ii) of subpart N.
Owners or operators of affected
sources are required to keep the records
required by § 63.346 to document
compliance with these standards.
Records include those associated with
the work practice standards,
performance test results, compliance
monitoring data, duration of
exceedances, and records to support a
Federally-enforceable limit on facility
size. Reports must also be periodically
submitted. Table 4 summarizes the
reports to be submitted and the
reporting timeframes.
TABLE 4.—SUMMARY OF REPORTING REQUIREMENTS
Section in
Sutpart N
I
Description
Timeframe for submirtal
§63.345(b)
§53.347(c)(1)
§63.347(c)(2)
§63.347(d)
§53.347(f) .
§63.347(S)
§53.347(h)
§63.347(i) .
Notification of constrjction or reconstruction
Initial notification
—Notification cf when construction commenced
—Notification of actual startup ...
Notification of performance test .
Notification of compliance status
Notification of performance test results .-
Compliance status reports for major sources
Compliance status reports for area sources .,
—Initial notification for users of TVC baths
—Notification of compliance status for users of TVC baths
—Notification of process change
Depends on when source was constructed—see
§63.345(b)(5).
180 days after the effective date.
—Within 30 days of commencement for sources Duii; after
effective date, or with notification required by §63.345(0) rf
built prior to effective date.
—Within 30 days of startup.
At least 60 days prior to test.
Within 90 days of performance test (if a test is conducted) or
within 30 days of compliance date.
Within 90 days of performance test.
2 times/yr. or 4 times/yr if exceedances occur or if requested
by Administrator.
Cornplete once/yr and maintain on site, or 2 times/yr if
exceedances occur or if requested by Administrator.
—Within 180 days of effective date.
—Within 30 days of compliance date.
—Within 30 days of process change.
B. Summon' of Major Changes Since
Proposal
In response to public comments
received and additional analyses
performed by the EPA. the following
changes have been made to the final
rule since proposal:
1. The emission limits associated with
the control technologies that form the
bases for the standards have been
revised. The emission limit based on the
use of a composite mesh-pad system is
0.015 milligrams of total chromium per
dry standard cubic meter (mg/dscm) of
exhaust air. The emission limit based on
the use of a fume suppressant is 0.01
mg/dscm. The emission limit based on
the use of a packed-bed scrubber if
unchanged (0.03 mg/dscm).
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Federal Register / Vol. 60, N7o. 15 / Wednesday, January 25. 1995 / Rules and Regulations 4951
TABLE 3.—SUMMARY OF MONITORING REQUIREMENTS
Control technique
into! compliance test
Parameter(s) tor compliance monitoring
Frequency of compfr-
arce monitoring
Composite mesh-pad (CMP)
system.
Packed-bed scrubber (PBS)
PBS/CMP system
Fiber-bed mist eliminator —
Wetting agent-type fume
suppressant
Foam blankets
Air pollution control device
(APCD) not fisted in nJe.
Yes
Yes
Yes
Yes
Yes (Unless the criteria of
§63343
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4952
Federal Register / Vol.
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No. 16 / Wednesday. January 25, 1995 / Rules and Regulations
are reduced from the nationwide annual
costs associated with monitoring.
reporting, and recordkeeping in the
proposed rule of 58.6 million for hard
chromium electroplaters. 51.6 million
for decorative chromium electroplaters
using a trivalent chromium plating
process.'S14 million for other decorative
chromium electroplaters, and 53.8
million for chromium anodizers.
C. Economic Impacts
The economic impacts for the sources
covered by this rulemaking are
unchanged from proposal because the
basis of the MACT standards have not
changed.
FV. Public Participation
Prior to proposal of the chromium
electroplating and anodizing rule.
meetings of the National ALr Pollution
Control Techniques Advisory
Committee (NAPCTAC) were held on
January 30 and November 19, 1991.
These meetings were open to the public,
and each attendee was given an
opportunity to comment on the draft
rule.
The proposed rule was published in
the Federal Register on December 16,
1993 (58 FR 65768). The preamble to the
proposal discussed the availability of
the proposal BID [Chromium
Electroplating NESHAP—Background
Information for Proposed Standards
(Volume I: EPA-153/R-93-030a and
Volume II: EPA-i53/R-93-030b)).
which describes in detail the regulatory
alternatives considered and the impacts
associated with those alternatives.
Public comments were solicited at the
time of proposal, and copies of the
proposal BID were made available to
interested parties.
The public comment period officially
ended on March 14. 1994. A public
hearing was held on January 20, 1994.
In addition, 62 comment letters were
received during the public comment
period: 3 late comments were also
received. The comments were carefully
considered, and where determined to be
appropriate by the Administrator.
changes wore made in the final rule.
V. Significant Comments and Responses
Comments on the proposed rule were
received from industry, environmental
groups, and State and local regulatory
agencies. A detailed discussion of these
comments and responses can be found
in the promulgation BID (see ADDRESSES
section). The summary of comments and
responses in the promuJgation BID
serves as the basis for the revisions that
have beeji made to the rule between
proposal and promulgation.
A. Selection of Source Categories and
Pollutants To Be Regulated
Six commenters said that maximum
cumulative potential rectifier capacity
was an inappropriate parameter for
determining facility size. Sources may
have excess rectifier capacity to handle
atypical applications, for safety
purposes, or for other reasons, but may
routinely operate at a significantly lower
rectifier output. Several commenters
urged the EPA to consider alternatives
to the maximum potential rectifier
capacity specified, such as actual
annual ampere-hour usage, raising the
maximum potential ampere-hour limit
for small sources to 100 million amp-hr/
yr, allowing sources to multiply the
maximum potential rectifier capacity by
0.75 to account for oversizing, or
allowing sources to accept Federally-
enforceable limits on their rectifier
capacity that would allow them to be
categorized as "small" facilities.
Although the cutoff between small
and large hard chromium electroplating
facilities has not been changed, the EPA
has included two provisions in the final
rule to allow sources to use actual
rectifier capacity or to limit their
potential rectifier capacity. The first
provision is available to facilities whose
production records show that the
previous annual, actual rectifier
capacity was less than 60 million amp-
hr/yr. Under this provision, hard
chromium electroplating facilities may
determine their size by using actual
cumulative rectifier capacity in lieu of
the maximum potential capacity if
noaresettable. amp-hr meters are used
on affected tanks. The final rule
(§ 63.346fb)(12) and § 63.347(c)(l)(vi))
requires that records of amp-hr usage be
kept.
The final rule also allows all sources
performing hard chromium
electroplating to establish Federally-
enforceable limits on their rectifier
capacity to allow facilities to comply
with the standards for small, hard
chromium electroplating'tanks, even if
.those facilities have potential rectifier
capacities that exceed the 60 million
amp-hr/yr cutoff. A Federally-
enforceable limit is obtained through
the title V permit that is rec/jired by
§63.340(e) of the final rule.'Records are
required in accordance with
§ 63.346fb)(12) and § 63.347(c)(l](viii) to
document that the Federally-enforceable
limit is being maintained.
The final rule has also been clarified
to state that only the rectifiers
associated with hard chromium
electroplating should be used to
determine maximum cumulative
potential rectifier capacity
Comments were received regarding
other processes conducted by this
source category that were not identified
in the process description. One
ccmmenter pointed out a distinction
among decorative chromium
electroplating processes: Black
chromium and white chromium. The
commenter stated that black chromium
electroplating is more like hard
chromium electroplating in terms of
process parameters, and the commenter
recommended that black chromium
electroplating be subject to the same
requirements as hard chromium
electroplating processes. Other
commenters noted that the proposed
rule did not cover a hard chromium
electroplating method that uses lower
amperage and a longer electroplating
time (less amperage per square foot than
decorative electroplating process) such
that emissions are lower.
In the final rule, the definitions of
hard chromium electroplating,
decorative chromium electroplating,
and chromium anodizing have been
expanded, and are now expressed in
terms of process parameters as well as
by function. Regardless of what name a
facility has assigned to its process, for
the purposes of the regulation, the
process will be regulated according to
its function, bath operating parameters.
and desired plating characteristics.
Therefore, black decorative chromium
electroplaters would likely be subject to
the standards for hard chromium
electroplaters based on plating
characteristics. The EPA will provide
States with additional guidance or. these
types of applicability issues in the
enabling document.
The commenters that use a low-
amperage electroplating process were
concerned that such a process would
not be allowed by the rule, even though
emissions from this process are low.
Although the process does differ from
other hard chromium electroplating
processes in that a lower amperage is
used, the rule does not preclude the use
of this process or any other technique to
meet the applicable emission limitation.
The rule does require that the technique
be demonstrated through performance
testing conducted in accordance with
the test methods and procedures
identified in the final rule, and that
compliance monitoring be conducted to
determine continuous compliance.
B. Selection of'MACT/GACT Approach
Ten commenters questioned the
Agency's decision to regulate area
sources with MACT. A number- of these
commenters disagreed that the
chromium compound toxicity data
alone was justification for regulating
-------
Federal Register / Vol. 60. No. 16 / Wednesday. January 25. 1995 / Rules and Regulations 4953
area sources as stringently as major
sources. Other commenters stated that
the costs to area sources regulated with
MACT was unduly burdensome.
particularly if those sources would be
subject to title V. Two commenters -
suggested that the EPA apply GACT
standards to small facilities to allow the.
Agency to focus its resources on
facilities posing the greatest impact, or
establish a threshold below which
sources would be subject to GACT.
Another commenter questioned the
EPA's decision to apply MACT to area
sources on the grounds that the Act does
not intend a residual risk analysis for
area sources. This commenter noted that
it was important to have separate
standards for area sources even if GACT
was as stringent as MACT to preserve
the intent of section 112(d).
In determining whether to apply
MACT or GACT to the area sources in
this source category, the EPA
considered the toxicity of chromium
compounds emitted from such sources
and.the availability of controls. The EPA
has concluded that MACT should be
applied to all area sources in all source
categories. The basis for this decision is
the toxicity of chromium compounds.
The potency of hexavalent chromium.
which is categorized as a Group A
carcinogen, is well documented, and at
least three epidemiological studies have
shown a strong association between
lung cancer and occupational exposures
to mixtures of bivalent and hexavalent
chromium. Therefore, the Agency has
concluded that all chromium
compounds emitted to the air should be
considered toxic until adequate data are
available to determine otherwise.
In selecting MACT over GACT for all
area sources, the EPA also evaluated the
availability of control technologies and
the cost of compliance for area sources.
The control technologies'that form the
bases for MACT are widely available.
Although § 112(d)(5) of the Act does
allow an alternative standard for area
sources, the EPA interprets this
paragraph as authorizing the
Administrator to establish GACT
standard for area sources when the
imposition of MACT is determined to be
unreasonable. For the source categories
subject to subpart N, the Agency
considers it reasonable to apply MACT
to area sources.
C. Selection of MACT for Hard
Chromium Electroplating Tanks
1. Selection of the MACT Floor
Four commenters suggested that the
MACT floor for new hard chromium
electroplating tanks should be based on
the use of a fiber-bed mist eliminator
(FEME) because this is the best
technology in use.
The EPA has gathered additional
information since proposal in response
to public comments received. Based on
this information, a total of five facilities
are known to be using FEME to control
chromium emissions from affected hard
chromium electroDlating and chromium
anodizing tanks. These five facilities
represent different sizes-of hard
chromium electroplating and chromium
anodizing operations.
Emission test data were obtained from
four of the five facilities using FEME
(see Item No. IV-B-01 of Docket A-88-
02). The emission test data available
from one facility were incomplete and
could not be used to assess the
performance of fiber-bed units. The test
results from the other facilities were
adequate to evaluate the performance of
FEME, However, after a thorough
evaluation, it was determined that the
limited data are not sufficient to
establish an emission limit which must
be met on a continuous long-term basis.
In one case, the data were inadequate
because only a single traverse was made
•when two should have been performed.
In the other cases, the quantity of
emissions captured during sampling
was too small to meet Agency
guidelines on minimum quantification
levels. These data, therefore, must be
treated as qualitative rather than
quantitative results and may not be used
to establish achievable emission limits.
Based on this qualitative issessment. it
appears that FBME offer excellent
control potential.
In evaluating control technologies, the
Agency also must consider the
sustainability of any performance level
The EPA is concerned with the long-
term performance of these systems
because of the tendency of the fiber beds
to plug. In other contexts, most vendors
of FEME systems do not recommend
their use as primary pollution control
systems. Rather, they recommend that
coarse prefiltering be provided upstream
of the fiber beds to prevent plugging.
The prefiltering devices range from a
series of mesh pads to a complete
packed-bed scrubber unit At present,
there are no long-term data available to
assess any actual deterioration or
operational problems associated with
FBME. Fiber-bed mist eliminators to
control chromium electroplating and
anodizing tanks have only recently been
installed as a result of local air district
requirements; therefore, it is unlikely
that any lon°-term data are available.
Because of the uncertainties in both
the measured FBME performance data
and the potential long-term variability
of the system performance, the
Administrator cannot at this time
determine that a more stringent
emission limit could be achieved based
on the application of FBME technology
for new hard chromium plating or
chromium anodizing operations.
Therefore, the final MACT performance
level of new hard chromium
electroplating and chromium anodizing
tanks is unchanged from the proposal.
However, the limited data do suggest
that FBME systems can achieve the
emission limits established for
composite mesh-pad systems and fume
suppressants. Because this standard is a
performance standard, the use of a
specific technology is not mandatory;
therefore, any system that meets or
exceeds the required performance level
may be used.
In order to facilitate the use of FEME
to achieve compliance with the
standard, monitoring provisions have
been included in the final rule for use
with FBME. (See discussion in section
V.H.) The test methods in the proposed
rule are suitable for demonstrating
compliance with the standard regardless
of the control technology employed.
2. Regulatory Alternatives Considered
Eight commenters suggested that the
EPA was too Limiting in the regulatory
alternatives for hard chromium
electroplating operations. These
commenters believed that the EPA
should allow sources in this subcategory
to use fume suppressants to comply
with the standard, instead of locking
sources into a control technology, such
as packed-bed scrubbers. Four of the
commenters also proposed that the EPA
allow new and existing hard chromium
electroplating operations the option of
meeting the same surface tension limit
allowed for decorative chromium
electroplating operations that use a
wetting agent-type fume suppressant.
The EPA has selected an emission
limit format to provide sources with the
flexibility to choose the emission
control strategy best suited to their
facility. The regulation only requires
that any strategy selected meet the
emission limits set out in the rule. As
such, hard chromium electroplating
sources can use fume suppressants to
achieve compliance with the standard.
as long as initial compliance testing
demonstrates that the emission limit
stipulated in the standard is being
achieved. As discussed later in this
preamble, however, on-going '
compliance monitoring is control-
technique specific. As such, the owner
or operator of any source that uses a
fume suppressant to comply with an
emission limitation shall monitor
surface tension or foam blanket
-------
4954 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
thickness, as appropriate, to
demonstrate continuous compliance.
3 Selection of MACT
Several commenters remarked that the
standard for existing hard chromium
electroplaters is inappropriate. Nine
commer.ters stated that the standard
was too stringent for large, hard
chromium electroplaters; small, hard
chromium electroplaters; or both. The
arguments against regulating existing
hard chromium electroplaters as
stringently as that proposed were
primarily that the costs associated with
the standard were unduly burdensome
and did not justify the resulting
environmental benefit, and the emission
concentration limits specified in the
proposed rule were not consistently
achievable using the control devices
upon which the standards are based.
Five commenters, on the other hand,
indicated lhat the standard for small,
hard chromium electroplaters was too
lenient. The arguments presented by the
commenters who supported a more
stringent standard for small, hard
chromium electroplaters were that the
residual risk associated with emissions
from these sources warranted more
stringent controls, the Agency's
interpretation of the MACT floor was
flawed (i.e.; should be based on a
straight average, not a median); and the
control efficiency for packed-bed
scrubbers is overstated, as are the cost
impacts for a standard based on the use
of composite mesh-pad systems.
In setting an emission standard, the
Act directs the Administrator to take
into account costs, nonair quality health
and environmental impacts, and energy
requirements. To fulfill this requirement
for existing hard chromium
electroplating sources, the EPA
evaluated the cost, impact, and benefit
of a standard based on the use of a
packed-bed scrubber as well as a
standard based on the use of a
composite mesh-pad system. The
Agency's estimate of the incremental
cost effectiveness of requiring all
sources to meet a standard based on
composite mesh-pad systems compared
to one based on packed-bed scrubbers is
approximately S3.7 million per
Megagram of chromium controlled (S/
Mg) for large sources and S10.7 million/
Mg for small sources.
Based on the EPA's economic .
analysis, a standard based on the use of
composite mesh-pad systems by all
sources would not cause adverse
economic effects on large sources that
currently use packed-bed scrubbers. Due
to economies of scale, the economic
impacts on larger facilities are
consistently less than those on small
facilities. As a result, larger facilities
will have a greater ability to pass on
control costs. Although these costs may
seem high, the EPA believes the toxicity
of chromium justifies these costs. In
consideration of the potential adverse
impacts to small sources, the final rule
requires a less stringent standard for
small sources than large sources, which
is based on the use of packed-bed
scrubbers rather than composite mesh-
pad systems. [See Chapter 5 of the New
Technology Document ("Technical
Assessment of New Emission Control
Technologies Used in the Hard
Chromium Electroplating Industry;"
EPA—J53/R-93-031) for a detailed
discussion of EPA's economic analysis
for these systems.]
The EPA considers the emission
limitation based on the use of composite
mesh-pad systems to be representative
of and consistently achievable with
well-maintained units. No data were
submitted to support an alternate
emission limitation. (For further
discussion of the emission limitations,
see section V.F.)
Regarding the comments that the
proposed standard for small, hard
electroplaters was too lenient, the
Agency believes that the MACT floor is
properly based on the use of packed-bed
scrubbers for this source category. The
EPA promulgated a final rule on June 6,
1994 (57 FR 29196) that presents the
Agency's interpretation of section
112(d)(A) of the Act regarding the basis
for the MACT floor. Under this
interpretation, the Agency considers the
emission limitations achieved by the
best performing 12 percent of existing
sources and arrives at the MACT floor
by selecting the median of the values,
rather than a straight average. This
interpretation was followed in
establishing the MACT floor for small,
hard chromium electroplaters. The
Agency considers any discussion of the
risk remaining from small, hard
chromium electroplaters to be
premature at this time.
In accordance with section 112(0 of
the Act, if a significant residual risk
from small, hard chromium
electroplating operations regulated by
MACT is found, the Agency is required
to promulgate standards to mitigate that
risk. The EPA recognizes the potential
hazards of chromium emissions from
small sources and has chosen to regulate
area sources with MACT rather than
GACT. The EPA also considers its cost
and impact analysis for small, hard
chromium electroplaters to be sound.
The EPA estimated retrofit costs based
on information from vendors who
supply the equipment to the industry,
and therefore estimates are
representative of the control costs
incurred by affected sources. The EPA
considers the efficiency assigned to
packed-bed scrubbers for purposes of
calculating impacts to be representative
of that achieved by well-maintained and
well-operated units controlling
emissions from hard chromium
electroplating tanks. As with comments
on the emission limit based on
composite mesh-pad systems, no data
supporting alternate emission limits for
a standard based on packed-bed
scrubbers were submitted.
D. Selection of MACT for Decorative
Chromium Electroplating and
Chromium Anodizing Tanks
1. Regulation of the Trivalent Chromium
Plating Process
Eleven commenters disagreed that
decorative chromium electroplating
tanks tha'. use a trivalent chromium
process should be regulated by the
proposed rule. Many of the commenters
felt that the EPA had insufficient data to
conclude-that the risk associated with
this process warranted regulation of
those sources. Four commenters found
fault with the EPA's supporting data
and noted that the level of hexavalent
chromium in a trivalent chromium bath
that corresponds to the EPA's estimate
of hexavalent emissions from that bath
would far exceed that level of
hexavalent chromium that would
destroy the trivalent bath. Three other
commenters stated that use of the
trivalent chromium process should be
encouraged by the EPA, because
trivalent processes result in less total
chromium in process wastewater and
less sludge generation. One of the
commenters suggested regulating
trivalent chromium electroplating
processes under GACT to eliminate
some of the burden associated with the
reporting, recordkeeping, and
monitoring requirements specified in
the proposed rule.
Twelve commenters responded to the
EPA's request for comment on whether
the trivalent chromium electroplating
process should be required for new
sources. The majority of these
commenters did not think that this
should be a requirement because the
process was not technically feasible for
the full range of decorative chromium
electroplating operations. Two
commenters pointed out inconsistencies
in the EPA's reasoning; the EPA can
only require trivalent chromium baths if
it recognizes the difference in toxicity
between hexavalent and trivalent-
chromium.
The EPA has reconsidered the
technical basis for regulating tanks
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Federal Register / Vol.
60
, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations 4955
using the trivalent chromium
electroplating process and the feasibility
of requiring such a process for new
sources. During development of the
proposed standards, the EPA evaluated
the trivalent chromium electroplating
process as a pollution prevention
alternative. Chromic acid is not present
in the plating solution in the trivalent
chromium processes, and hexavalent
chromium is regarded as a bath
contaminant in these processes. In
addition, all of the trivalent chromium
plating solutions with which EPA is
familiar contain a wetting agent as an
inherent bath component. That is, the
wetting agent is part of the plating
solution purchased from the vendor; it
is not added separately by the end user.
With a trivalent chromium plating
process, the potential emissions of
chromium in any form are much lower
because the concentration of total
chromium in trivalent chromium baths
is approximately four times lower than
the total chromium concentration in
chromic acid baths. Trivalent chromium
processes greatly reduce emissions of
the most potent'form of chromium
(hexavalent), and significantly lower
emissions of chromium in other forms.
In addition to reduction of air
emissions, the use of trivalent
chromium processes results in lower
•chromium concentrations in process
wastewaters and, consequently, reduces
the amount of sludge generated. Based
on a source test conducted by the EPA,
total chromium emissions from a
trivalent chromium bath are
approximately 99 percent less than
those from a traditional, uncontrolled
decorative hexavalent chromium bath.
Hexavalent chromium emissions from a
trivalent chromium ba!h were found to
be approximately equivalent to those
emitted from a decorative hexavalent
chromium bath controlled by adding a
wetting agent.
Although chromium emissions from
the trivalent chromium process were
low, the EPA had not anticipated the
presence of hexavalent chromium in
emissions from the trivalent
electroplating process nor the level of
total chromium emissions. Given that
the Act lists all forms of chromium on
the HAP list, the EPA considered the
trivalent chromium electroplating
process as a source of chromium
emissions as well as an emission control
alternative for the chromic acid
electroplating process. Based on the
emission test results, a decorative
hexavalent chromium bath controlled
by adding a wetting agent had
equivalent hexavalent chromium
emissions and less total chromium
emissions than a trivalent chromium
plating bath. (As previously stated, for
trivalent chromium baths, the wetting
agent is inherent to the solution; it does
not need to be added by the user.) In
addition, the trivalent chromium
process may not be technically feasible
for all decorative chromium
electroplating applications. Therefore,
the final rule does not require the use
of a trivalent chromium electroplating
process for either existing or new
decorative chromium electroplating
tanks.
The EPA has decided to regulate
sources that use trivalent chromium
baths in the final rule. It is not clear
whether the EPA data accurately reflect
emissions from the trivalent chromium
electroplating process, or if the
analytical integrity of the data is
suspect. In light of the ambiguity of the
air emissions data, and given the other
environmental benefits from the
trivalent chromium process, the EPA
has decided to regulate these baths
differently from hexavalent chromium
electroclating baths.
The final rule requires users of
trivalent chromium baths to submit an
initial notification and a notification of
compliance status certifying that a
trivalent chromium bath is being used
and identifying the bath components
(specifically, the wetting agent).
Subsequent notifications are required
only if the process is changed, or if a
new trivalent chromium process is
introduced. Users of trivalent chromium
baths must also keep records of bath
chemicals purchased so the EPA can be
assured that the bath contains a wetting
agent. These notification and
recordkeeping requirements apply only
to those trivalent chromium baths that
incorporate a wetting agent. The EPA
has evaluated baths with this
characteristic and found them to have_
the environmental benefits discussed
above. Although such baths are not
known to exist, the EPA has chosen to
regulate trivalent chromium baths that
do not incorporate a wetting agent in the
same manner as decorative chromium
baths using a chromic acid solution. The
EPA believes that this will discourage
the use of a trivalent chromium bath
that does not have a wetting agent as an
inherent bath component.
2. Selection of MACT for Decorative
Chromium Electroplating Tanks
Three commenters suggested that the
proposed emission limit of 0.003 mg/
dscm for decorative chromium
electroplaters using hexavalent
chromium baths was too stringent. Two
commenters did not think that a source
using either a fume suppressant or a
fume suppressant in conjunction with a
packed-bed scrubber could consistently
meet a limit of 0.003 mg/dscm.
In response to the comments received
at propo'sal. the EPA has reconsidered
the basis for the emission limit of 0.003
mg/dscm for decorative chromium
electroplating and chromium anodizing
tanks. As stated in the preamble to the
proposed rule, this emission limit was
based on tests of a decorative chromium
electroplating tank in which a
combination wetting agent/foam blanket
was used to control emissions. Tests
had also been conducted on a decorative
chromium electroplating tank using
only a foam blanket for control. The
chromium emission data for all types of
fume suppressants ranged from 0.001 to
0.007 mg/dscm, with the wetting agent/
foam blanket data ranging from 0.001 to
0,003 mg/dscm and the foam blanket
data "ranging from 0.003 to 0.007 mg/
dscm. In evaluc.'ing whether the
proposed emission limit of 0.003 mg/
dscm should be revised in the final rule.
the EPA reassessed the effect the test
methods may have had on the emission
data obtained. The analytical method
used for the fume suppressant test-was
colorimetric spectroscopy. As more
efficient control technologies (such as
composite mesh-pad systems) were
developed, a more sensitive analytical
method was needed to measure the
lower concentrations of chromium being
emitted. Therefore, the more sensitive
ion chromatography method was used
in the later phases of emission testing
for these standards involving add-on
control devices.
By using the less sensitive
colorimetric analytical method, it is
unclear whether the variation found
between the two types of fume
suppressants was due to a performance
difference in the fume suppressants or
was an artifact of the analytical method
used. The fact that there is overlap
between the foam blanket and wetting
agent/foam blanket data further
indicates that this could be ths case.
(Both were able to achieve a limit of
0.003 mg/dscm in one instance.)
Therefore, the EPA has concluded that
the emission limit in the final rule
should be based on the performance of
both foam blankets and wetting agents.
Accordingly, the emission limit selected
for decorative chromium electroplating
and chromium anodizing tanks in the
final rule is 0.01 mg/dscm. This
emission limit was selected by applying
a safety factor to the highest measured
data point (0.007 mg/dscm) to account
for variations in sampling and analytical
procedures. The selection of this
emission limit is consistent with the
methodology used to select emission
limits based on other control
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4956 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
techniques, as is further discussed in
section V.F
3. Selection pf MACT Floor/MACT for
Chromium Anodizing Tanks
Three commenters questioned the
MACT floor established by the EPA for
sources performing chromium
anodizing. The commenters stated that
it did not appear that the EPA had
sufficient data to perform a MACT floor
analysis for these sources. Commenters
stated thst chromium anodizers and
decorative chromium electroplaters that
cannot use fume suppressants should be
considered separately, and the MACT
floor for such sources should be based
on packed-bed scrubbers. Also,
according to six commenters, the
standard for chromium anodizing tanks
is not achievable in all situations,
especially when an add-on control
device is used in lieu of fame
suppressants. One commenter stated '
that unless the standard for chromium
anodizing tanks controlled with add-on
control devices is set at 0.03 mg/dscm,
sources will have to use an add-on
control device followed by a fiber-bed
mist eliminator to achieve the emission
limit.
The MACT floor for chromium
anodizing sources was based on
information available to the EPA on the
source category. Information on the
industry was obtained through survey
questionnaires to both industry
representatives and control system
vendors, site visit reports, and available
emission data. Although information
was not available from all sources in the
category, the EPA believes the
information was sufficient to satisfy the
requirements of section 112(d)(3) of the
Act. The survey responses, which
included some aerospace facilities,
indicated that fume suppressants were
the control technique used
predominantly in the industry. Section
112(d)(3) of the Act prohibits'the EPA
from establishing a standard that is any
less stringent than the MACT floor for
a category or subcategory of sources. No
technical reason was provided by
industry, nor is one known to the EPA,
for creating a separate subcategory of
sources for which fume suppressants are
not technically feasible. Thus, all new
and existing sources performing
chromium anodizing must meet either
an emission limit of 0.01 mg/dscm or
maintain the surface tension specified
in the rule. The EPA believes that the
revised chromium emission limit of 0.01
mg/dscm for chromium anodizing tanks
in the final rule is achievable by sources
using add-on control technology.
Alternatively, the EPA believes that the
compliance timeframe for existing
sources performing chromium
anodizing in the final rule (2 years) will
allow these sources to further
investigate the feasibility of using fume
suppressants.
E. Selection of the Format of the
Standard
Seven commenters stated that the
format of the standard should be
expressed as a process emission rate in
milligrams of chromium emitted per
amp-hour of operation (mg/amp-hr),
which would be consistent with
California rules, rather than as an
emission concentration (mg/dscm).
Accordinglo the commenters.
concentration-based standards are
flawed because they can be
circumvented by dilution, concentration
can vary from system to system, and
source test data indicate that outlet
concentrations vary widely for different
inlet conditions. Several commenters
also pointed out that emissions should
be correlated to production rates
because chromium emissions increase
proportionately with increased current.
Two other commenters suggested that
the final rule specify acceptable process
emission rates to avoid an equivalency
evaluation.
Based on the Agency's evaluation, the
available test data indicate that a
process emission rate format will not
ensure consistent compliance with the
control level required by the standard.
The concentration data collected by the
EPA for the composite mesh-pad and
packed-bed scrubber systems do not
overlap; that is, composite mesh-pad
systems consistently outperform
packed-bed scrubbers. The process
emission rate data, on the other hand do
overlap; even though composite mesh-
pad systems are a superior technology to
packed-bed scrubbers, both sometimes
achieve the same process emission rate.
This occurs because two sources can be
using the same control technology and
achieving the same outlet emissions
concentration, but the one with the
higher current loading will have a lower
process emission rate. Commenters
contend that this is reasonable because
the production rate, as measured in
ampere-hours, is related to emissions.
However, the amount of current
supplied to the tank is an indicator of
the amount of uncontrolled emissions
from the tank, not the controlled
emission level from the tank. Because of
the differences in process emission rate-
based and concentration-based
standards, and the source-specific
nature of process emission rate
standards, the EPA cannot cite an
equivalent process emission rate in the
final rule.
Regarding the issue of circumvention
of the standard through dilution of the
emission stream, the EPA believes that
dilution of the gas stream can be
determined by reviewing test and
permit data for a facility. The outlet air
flow rate measured during testing
should approximate the design air flow
rate for the control system reported on
the permit application. If the two values
differ significantly, then an inspection
of the control system can be made to
determine if dilution air is being
introduced. It is also possible for a
facility to dilute the inlet gas stream to
the control device by designing a system
to ventilate the electroplating tanks at
air flow rates substantially above those
required for adequate ventilation.
However, the increased installation and
maintenance costs associated with such
a system would outweigh the costs of
complying with the standard without
dilutio'n. Further, §63.4(b) of the
General Provisions expressly prohibits
dilution as a means to comply with an
emission limit. Therefore, concerns of
dilution of the air stream were not
considered to outweigh the benefits of a
concentration-based format for the
standard.
Eight commenters disagreed with the
EPA's decision to base the standard on
emissions of total chromium rather than
on emissions of hexava-lent chromium.
Two commenters suggested allowing
sources to demonstrate compliance by
testing for hexavalent chromium in lieu
of total chromium.
The EPA decided to base the standard
on total chromium because the HAP list
identifies all chromium compounds, not
just hexavalent chromium compounds.
In addition, based on testing conducted
by the EPA for these source categories,
the available test data indicate that
hexavalent and total chromium levels in
the emission stream were essentially the
same for chromic acid baths (varying
within ±10 percent in most instances).
Because the EPA data base is mainly
comprised of data measured as
hexavalent chromium, the final rule
does allow all sources using chromic
acid baths to demonstrate compliance
by measuring either hexavalent or total
chromium for all sources.
F. Selection of the Emission Limits
Many commenters stated that the
emission limit based on the use of
composite mesh-pad systems should be
changed. Three commenters suggested
lowering the emission limit that is based
on the use of composite mesh-pad
systems, stating that the EPA did not
test the best systems available, and
suggested levels ranging from 0.001 mg/
dscm to 0.009 mo/dscm. Other
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Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations 4957
commenters stated that the proposed
limit based on composite mesh-pad
systems (0.013 mg/dscm) was too low.
Five commenters stated that the
proposed emission limit for packed-bed
scrubbers was also too high, noting that
some units tested by the EPA did not
achieve this limit.
The proposed emission limit of 0.013
mg/dscm for large hard chromium
electroplaters was based on tests that
the EPA conducted on actual control
-devices operating under normal process
conditions. Lower limits than the one
selected for large sources were
measured from these devices, but the
EPA based the emission limit on the
highest measured data point and
believes that this limit is consistently
achievable. Regarding the emission limit
based on packed-bed scrubbers, the EPA
did test some packed-bed scrubber
systems that were not achieving the
level of 0.03 mg/dscm required by the
proposed standard. However, these
devices were not optimized to achieve
the higher removal efficiencies.
Specifically, when scrubbers were
operated with periodic or continuous
washdo%vn in which fresh water was
supplied as makeup to the top of the
bed, a limit of at least 0.03 mg/dscm was
achieved. The final rule includes work
practice standards that require the use
of fresh water added to the top of the
packed bed whenever makeup additions
occur. Thus, packed-bed scrubbers that
are operated in accordance with the
requirements of the rule should be able
to achieve a limit.pi 0.03 mg/dscm. The
EPA does not think it is appropriate to
substantially change the emission limits
based on the use of composite mesh-pad
systems or packed-bed scrubbers; the
commenters did not provide data that
supported their claim that different
emission limits are more appropriate.
As discussed previously, the emission
limit for decorative chromium
electroplating tanks and chromium
anodizing tanks has been changed to
0.01 mg/dscm in the final rule by
applying a safety factor to the highest
data point (0.007 mg/dscm) in the fume
suppressant data base. Similarly, the
emission limit that is based on packed-
bed scrubbers is based on rounding the
highest value (0.028 mg/dscm) in the
packed-bed scrubber data base to 0.03
mg/dscm to incorporate a safety factor.
Therefore, in the final rule, the emission
lim-it that is based on the use of
composite mesh-pad systems (0.013 mg/
dscm) has been adjusted to 0.015 mg/
dscm by applying a safety factor to the
highest value (0.013 mg/dscm) in the
data base to ensure that the limit is
achievable on a consistent basis.
C. Selection of Compliance Dates
Several commenters stated that the
proposed compliance dates for affected
existing sources did not allow sufficient
time to achieve compliance with the
proposed rule. The majority of these
commenters suggested compliance
timeframes of 2 to 3 years. According to
the commenters, the compliance period
specified in the proposed rule did not
allow enough time to inform and
educate affected owners and operators;
acquire capital; conduct research and
test systems; identify, purchase, and
install control equipment; develop
startup, shutdown, and malfunction
plans; train staff; build inventories; and
establish reporting and recordkeeping
systems.
[.The Agency agrees with the
commenters that the compliance
timeframes for affected sources should
be increased. The EPA recognizes that
some of the facilities within all of the
source categories will have to
investigate the technical feasibility of
installing control devices or using other
technologies at their facility to meet the
standards. Also, many area sources are
not yet aware that a rule is to be
promulgated for their industry, and time
is needed for them to be made aware of
the requirements of this rule. Therefore,
the EPA has extended the compliance
date to 1 year after the promulgation
date for existing decorative chromium
electroplaters and 2 years after the
promulgation date for existing hard
chromium electroplaters and chromium
ancdizers. The EPA believes that the 1
year timeframe for decorative chromium
electroplaters is sufficient because.
based on the EPA's survey data, 80
percent of existing sources already use
fume suppressants and very few will
need to install add-on air pollution
control devices. The EPA thinks that the
compliance timeframes in the final rule
will address commenters concerns and
still ensure implementation of controls
in a timely fashion. Due to the toxicity
of chromium compounds and the
importance of controlling chromium
emissions to protect human health and
the environment, the Agency decided
against a compliance time longer than 2
years for any of the source categories
affected.
To accommodate sources that cannot
comply with the standard by the
compliance date, §63.6(i) of the General
Provisions and § B3.343(a)(6) of subpart
N allows a source to request a 1-year
compliance extension, which must be
submitted 6 months in advance of the
compliance date identified in the
regulation. This extension combined
with the compliance timefrarnes in the
proposed rule could provide a total of
2 years for compliance for decorative
chromium electroplaters and 3 years for
compliance for hard chromium
electroplaters and chromium anodizers.
H. Selection of Monitoring Requirements
Section 114(a)(3) of the Act requires
enhanced monitoring and compliance
certification of all major stationary
sources. The annual compliance
certifications certify whether
compliance has been continuous or
intermittent. Enhanced monitoring shall
be capable of detecting deviations from
each applicable emission limit or
standard with sufficient •
representativeness, accuracy, precision.
reliability, frequency, and timeliness to
determine if compliance is continuous
during a reporting period. The
monitoring in this-regulation satisfies
the requirements of enhanced
monitoring.
1. Compliance Monitoring for Add-on
Air Pollution Control Devices
Eleven comments addressed the
suitability of measuring gas velocity to
demonstrate on-going compliance when
add-on air pollution control devices are
-used to comply with an emission limit.
The commenters stated that measuring
gas velocity is very complicated,
redundant with measuring pressure
drop, and not indicative of control
device performance. Two commenters
pointed out that no suitable testing
point may be accessible, and a'
permanent measurement device may be
fouled by chromic acid.
Several commenters remarked on the
requirement for measuring chromium
concentration in the scrubber water.
Four of these commenters stated that
there is no obvious relationship between
scrubber water chromium concentration
and scrubber performance. Other
commenters indicated that
measurement of chromium
concentration in scrubber water with a
hydrometer is not accurate.
In revising the proposed rule, the EPA
recognizes that the measurement of gas
velocity could be burdensome and that
other control system parameters could
potentially be used to determine on-
going compliance. Therefore, in the
final rule, sources using composite
mesh-pad systems are required to
monitor pressure drop across the device
for compliance purposes. Based on
information gathered by the EPA,"
pressure drop is directly related to
composite mesh-pad system
performance, measurement of pressure
drop is straightforward, and some users
of composite mesh-pad systems are
currently monitoring pressure drop. The
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4958 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
EPA believes that this change makes the
rule more flexible for regulated sources,
while still ensuring that the EPA has a
mechanism for determining compliance
with the emission limits at any given
time.
The final rule requires sources that
use a packed-bed scrubber to meet the
emission limit must measure the
velocity pressure at the inlet to the
control system as well as the pressure
drop across the device. The relationship
between pressure drop and packed-bed
scrubber performance is less reliable
than the relationship between pressure
drop and composite mesh-pad system
performance because of the lower
pressure drop in packed-bed scrubbers.
Therefore, the EPA also requires sources
using packed-bed scrubbers to monitor
the velocity pressure at the inlet to the
control device. This requirement will
ensure that the gas velocity through the
control system is maintained in
accordance with vendor
recommendations and, along with the
pressure drop monitoring, will ensure
that the control system is properly
operating.
The requirement that sources using
packed-bed scrubbers monitor the
chromium concentration in the scrubber
water has been eliminated, because the
EPA concluded that monitoring of the
velocity pressure at the control device
inlet and the pressure drop across the
device was sufficient to demonstrate
compliance with the emission limits
when packed-bed scrubbers are used.
Compliance monitoring requirements
for fiber-bed mist eliminators have been
added in the final rule because these
devices could likely be used to meet the
emission limitations, and some fiber-
bed mist eliminators are known to be in
use. Sources that use a fiber-bed mist
eliminator to meet the emission limit
must measure the pressure drop across
the fiber-bed unit,, as well as the
pressure drop across the control device
upstream of the fiber-bed unit that is in
place to prevent plugging.
As discussed above, several changes
have been made to the monitoring
requirements specified in the proposed
rule' based on the EPA's review of
comments received on the proposed
rule and further investigation of which
process parameters relate best to proper
performance of the control systems. The
final compliance monitoring
requirements are found in § 63.343{c) of
the final rule.
2. Work Practice Standards for Add-on
Air Pollution Control Devices
In the proposed rule, Operation and
Maintenance (O&M) requirements for
add-on air pollution control devices
consisted of adding makeup water to
packed-bed scrubbers, requiring
washdown of composite mesh pads, and
various inspections for both types of
control devices. The majority of
comments focused on the requirements
associated with makeup water for
packed beds and washdown for
composite mesh pads. Several
commenters suggested alternatives for
the requirements for adding makeup
water to packed-bed scrubbers. The
commenters disagreed that makeup
water can or should be added to the top
of the scrubber. Others questioned the
need to use fresh water in scrubbers and
composite mesh pads because doing so
increased wastewater flows. Other
commenters requested that the final rule
define the term "fresh water."
In the final rule, the O&M
requirements have been replaced with
work practice standards that address
O&M practices [§ 63.342(f)]. The final
rule continues to require sources using
packed-bed scrubbers to meet an
emission limit and ensure that all
makeup water is fresh and supplied to
the unit at the top of the packed bed.
The EPA considers this requirement
essential to meeting the prescribed
emission limit. During source testing
conducted by the EPA to establish the
performance level of packed-bed
scrubbers, it was noted that a system
equipped with an overhead spray
system that periodically cleaned the
packing with fresh water performed
much better than a system without such
cleaning. Based on those results, the
EPA believes that without the
requirement that makeup water be fresh
and added to the top of the packed bed,
scrubbers will not continuously meet
the required emission limit even if the
scrubber met the limit during the initial
performance test and is operated within
the appropriate ranges of pressure drop
and velocity pressure. For clarification,
the term fresh water is defined in the
final rule.
There were 11 comments on the
washdown requirements for composite
mesh-pad systems. Several of these
commenters indicated that the specified
washdown frequency was either
impractical, infeasible, or unnecessary.
Seven commenters suggested washdown
requirements for composite mesh-pad
systems be site-specific, as
recommended by vendors, or apply only
if pressure drop determinations indicate
the potential presence of chromic acid
buildup. Two commenters indicated
that the washdown water will likely
exceed the quantity of water that can be
recycled, thus resulting in a wastewater
stream that needs to be treated.
In the final rule, the EPA has revised
the requirement that sources complying
with an emission limit by using a
composite mesh-pad system perform
washdown of the pads. The EPA
•believes that washdown is an essential
part of composite mesh-pad system
operation; if proper system maintenance
such as washdown does not occur, there
will be a decline in system performance.
However, instead of specifying a
washdown frequency, the revised rule
specifies that washdown be conducted
in accordance with manufacturers'
recommendations as part of a facility's
O&M plan. The EPA recognizes that
vendor designs for these systems vary
significantly, and the requirements for
washdown are based on the design of
the unit and the operation of the plating
tanks. The frequency of washdown is
dependent upon the position of the pad
in the control unit. Pads located in the
front portions of the unit are exposed to
higher chromium concentrations and,
therefore, require washdowns more
frequently than those located in the
back of the unit. Washdown practices
recommended by manufacturers vary
from continuous in some cases to a
maximum of once every 1 to 2 weeks.
The EPA has also added work practice
standards for fiber-bed mist eliminators
in the final rule because these control
devices are likely to meet the emission
limitations, and are known to be in use
by sources affected by these standards.
The work practice standards identified
for fiber-bed mist eliminators are
analogous to those identified for the
composite mesh-pad system. Washdown
requirements for fiber-bed units will
depend on the efficiency of the
prefiltering device and the operation of
the plating tanks. Fiber-bed units
installed downstream of more efficient
prefiltering systems, such as packed-bed
scrubbers, will require less frequent
washdown than those using a less
effective prefiltering device because of
the lower inlet loading to the unit. Most
vendors of fiber-bed units recommended
monitoring of the pressure drop as a
means of gauging when the unit needs
to be washed down. If an increase in
pressure drop is observed, then the unit
will be washed down to remove any
chromium built up on the fiber
elements.
3. Frequency of Monitoring for Add-on
Air Pollution Control Devices
Fourteen commenters indicated that
the daily monitoring of add-on air
pollution control devices is
unnecessary, particularly for small
sources, and suggested that at least some
of the monitoring be required on only a
weekly, monthly, or quarterly basis.
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4959
Other commenters suggested that
monitoring be tied to production rate,
that monitoring be conducted only on
days when electroplating is taking
place, or that monitoring requirements
be reduced after the source has been in
compliance for 6 months. Commenters
also requested that monitoring be
required only during tank operation,
and that tank operation be defined.
Several commenters disagreed with the
proposed inspection frequency because
of increased exposure hazards to
persons conducting the inspections or of
anticipated down-time due to the
inaccessibility of control systems.
In response to these comments and to
minimize the burden on regulated
sources, the EPA has reduced the
burden associated with the compliance
monitoring and work practice standards
in the final rule. The final rule
continues to require daily monitoring of
pressure drop and velocity pressure for
compliance, but the monitoring
procedures specified in the rule are the
minimum required to determine
continuous compliance. Once the
monitoring devices are in place, the
only labor required is that needed to
read the gauges. The frequency of
inspections for compliance with the
work practice standards has also been
reduced or revised. In the final rule, the
frequency of inspections has been
reduced from monthly or daily to once
every 3 months. The EPA believes that
the inspections are still necessary to
ensure that system degradation is not
occurring over time, because gradual
degradation may not be apparent from
compliance monitoring alone. Some
commenters noted that their systems
were not accessible for inspection, or
that the inspection would result in
extended downtime. The compliance
timeframes in the final rule should
allow sources sufficient time to retrofit
their systems to facilitate inspections,
and the negative effects of any
downtime are minimized by the
reduced inspection frequency.
The final rule also has been clarified
so that monitoring requirements apply
only during tank operation; tank
operation is defined in § 63.341.
4. Compliance Monitoring Associated
With Fume Suppressants
Regarding the use of wetting agent-
type fume suppressants, seven
commenters indicated that the
requirement for maintaining surface
tension below 40 dynes/on for chromic
acid baths is inappropriate. The reasons
provided by the commenters were that
a surface tension standard may not be
prudent to demonstrate compliance, a
direct correlation between exceedance
of parameters and emission limits has
not been established, and the rule
should allow sources to set their own
compliance value for surface tension.
Other commenters noted that the
specified limit was either too low or was
not consistent with manufacturers'
recommendations.
Based on data collected by the EPA,
•the performance of an electroplating
bath controlled with a wetting agent-
type fume suppressant can be
determined by the surface tension of the
bath. Therefore, the EPA believes that
there is a direct link between surface
tension and emissions. The EPA also
believes that it is necessary and
appropriate to set a default value for
surface tension in the rule. Based on the
EPA's experience, many decorative
chromium electroplating tanks are not
ventilated, making source testing
impossible without considerable
retrofitting.
The EPA .has increased the default
surface tension limit from the proposed
40 dynes/cm to 45 dynes/cm based on
information received during the
comment period. However, if a facility
believes that a different surface tension
value is appropriate, the rule allows a
source to conduct a performance test
concurrently with surface tension
monitoring to establish the maximum
surface tension that corresponds to
compliance with the emission limits.
The source would subsequently monitor
surface tension, with an exceedance
occurring if the surface tension of the
bath exceeded the value measured
during the performance test.
Regarding foam blanket-type fume
suppressants, several commenters were
concerned about the technique for
measuring foam blanket thickness and
the potential hazards associated with
this measurement. Another commenter
stated that the stack testing requirement
is unreasonable due to its excessive
cost.
The EPA does not believe that it is
necessary to specify a procedure
because it is simply a depth
measurement. Specifying & technique
may also binder the development of
site-specific techniques to reduce
worker exposure. The EPA believes that
wetting agents are safer than foam
blankets because foam blankets present
a potential safety hazard. The foam traps
the hydrogen gas and chromic acid mist-
in the foam layer; if these gases build up
and a spark is generated, a hydrogen
explosion will result. As a means of
encouraging wetting agent use over
foam blankets, sources using wetting
agents do not have to conduct a
performance test unless they want to set
a surface tension limit other than the
default value of 45 dynes/cm. The EPA
believes that the compliance timeframes
in the final rule will allow sources that
currently use foam blankets the
opportunity to explore the use of
wetting agents. Sources that wish to
continue using foam blankets will be
required to conduct a performance test.
5. Frequency of Monitoring Associated
With Fume Suppressants
There were over 20 comments related
to the frequency of monitoring surface
tension. Several of these commenters
made recommendations for alternate
monitoring schedules, ranging from
daily to monthly monitoring, in place of
the 4-hour schedule. Among the reasons
cited for decreasing the surface tension
monitoring frequency were that surface
tension does not change on a daily or
weekly basis, measuring surface tension
is very time-consuming and could
require someone full-time if there were
multiple tanks, and frequent monitoring
results in increased worker exposure.
Thirteen commenters provided
remarks regarding the burden of hourly
testing for sources using foam blankets.
The commenters noted that foam
blankets that are used according to
manufacturer's instructions are
designed to last 24 hours provided the
air is not agitated at the surface near the
anodes and freeboard height is
adequate. Therefore, visual observation
is adequate for determining foam
blanket effectiveness. Other commenters
stated that the excessive monitoring
requirements for foam blankets
discourage their use, yet several States
recommend or require foam blankets
with less testing and recordkeeping than
that proposed by the EPA.
In response to comments and some
data received, the EPA recognizes that
the 4-hour surface tension monitoring
frequency specified in the proposed rule
may be burdensome, and in some cases,
unnecessary. The EPA has insufficient
data, however, to establish the
monitoring frequency that is appropriate
for each mode of bath operation.
Therefore, the final rule allows a
decrease in monitoring frequency if no
exceedances occur. Section
63.343(c)(5)(ii)(B) specifies that the
surface tension be measured once every
4-hours of tank operation for the first 40
hours of tank operation after the
compliance, date. If no exceedances •
occur, monitoring can occur once every
8 hours of tank operation. Once^here
are again no exceedances during 40
hours of tank operation, surface tension
measurement may be conducted once
every 40 hours of tank operation on an
on-going basis, until an exceedance
occurs. Once an exceedance of the
-------
4960
Federal Register / Vol. 60, No. 16 / Wednesday, January 25. 1995 / Rules and Regulations
standard occurs or the electroplating
soluLion is changed out. the original
monitoring schedule must be resumed
Likewise, the final rule contains
allowances to decrease the frequency of
monitoring foam blanket thickness. The
proposed hourly frequency is based on
the EPA's experience that foam blankets
can deplete quickly and must be closely
monitored. The final rule is unchanged"
in that sources using a foam blanket
must conduct a performance test, and
the initial monitoring frequency is once
per hour. However, as with wetting
agents, the final rule allows a decrease
in monitoring frequeficy if no
exceedances occur. Section
63.343{c)(5)(ii)(B) specifies that the
foam blanket thickness be measured
once every hour of tank operation for
the first 40 hours of tank operation after
the compliance date. If no exceedances
occur, the time between monitoring may
be increased to once every 4 hours of
tank operation. Once there are no
exceedances during 40 hours of tank
operation, foam blanket thickness
measurement may be conducted once
every 8 hours of tank operation on an
on-going basis. As with wetting agents,
if there is an exceedance or if the
electroplating bath is changed out, the
original monitoring schedule must be
resumed.
•*
I. Selection of Test Methods
Three commenters requested that
CARS Method 425 be evaluated for
equivalency, and if determined to be
equivalent, be identified as such in the
rule. These commenters also stated that
sources that have performed this test
should not have to retest. Four
commenters asked whether retesting
-will be required if sources have
conducted performance tests previously
using 306, 306A, or an equivalent test
method.
Section 63.344(c)(2) identifies the
conditions under which the CARB
Method 42-5 is considered equivalent.
Basically, the acceptability of this test
method will depend upon the analysis
rather than the sampling train or
sampling procedure. Regarding the issue
of whether retesting is required,
§63.344(b) of the final rule outlines the
criteria that must be met for a previous
source test to be acceptable.
Two commenters requested that the
rule provide guidance on how to verify
compliance when both chromium
anodizing and hard chromium
electroplating tanks are vented to a
comiaan control device. Three
commenteis pointed out that the
regulation does not account for the
situation in which chromium
electroplating sources share a
ventilation system with nonchromium
sources that could introduce dilution
air Three commenters noted that it is
extremely difficult to reconfigure some
existing systems in such a way that only
the emissions from chromium
electroplating or anodizing are tested.
There are basically two situations
involving multiple tanks manifolded to '
one control system: (1) The multiple
tanks include a chromium electroplating
or chromium anodizing tank among
other tanks not affected by the rule; or
(2) the multiple tanks include
chromium tanks performing different
operations (e.g..electroplating and
anodizing) or hard chromium tanks
subject to different emission limits (e.g.,
a new tank and an existing small tank),
which may or may not be controlled
with nonaffected sources. Section
63.344(e) of the final rule includes
compliance provisions for both of these
situations.
J. Selection of Reporting and
Recordkeeping Requirements
Several commenters stated that the
frequency of recordkeeping and
reporting outlined in the proposed rule
was overly burdensome and suggested
several alternatives. Seven commenters
stated that the types of recordkeeping
required by the rule are inappropriate.
In general, the commenters remarked
that records, such as the amount of
chemicals used and purchased and the
amount of fume suppressant material
added do not indicate compliance. Two
commenters stated that recordkeeping
requirements be limited to only surface
tension measurements because that
measurement is the basis of compliance.
One commenter indicated there is no
environmental benefit to keeping
records of gas velocities, pressure drops,
washdown conditions, and scrubber
water chromium concentrations. Two
commenters stated that maintaining
records at a facility for 5 years is
excessive; a more appropriate length of
time would be 3 years. One commenter
suggested a minimum of 2 years.
Two commenters suggested that the
reporting schedule be replaced with a
requirement that the source submit an
annual certification that necessary
control parameters have been met,
consistent with the annual certification
requirements of title V. Another
commenter indicated that sources
should not be required to submit
compliance reports if the source's
permitting agency inspects the onsite
records annually. Finally, one
commenter suggested that the rule allow
a reduced reporting frequency after 2
years if sources do not experience
exceedances of any State or Federal
emission standards
Seven commenters stated that the
costs associated with the monitoring
and recordkeeping constituted an
unnecessary burden to both large and
small facilities. These commenters also
noted that the EPA underestimated the
costs associated with monitoring,
reporting, and recordkeeping. Two of
the commenters stated that small
businesses do not have the resources to
keep extensive records. Another
commenter pointed out that the EPA has
recognized differences in large and
small facilities in selecting MACT
emission standards and should also
recognize differences between large and
small facilities in selecting reporting.
recordkeeping, and permitting
requirements.
To respond to comments received and
to reduce the burden on the many area
sources that will be subject to these
standards, the monitoring, reporting,
and recordkeeping requirements have
been reduced in the final rule to the
extent possible while still providing the
EPA with the ability to determine a
source's continuous compliance status.
The recordkeeping requirements are
contained in § 63.346 of the final rule.
The EPA concurs that the records
required to be kept should correspond
specifically to that which is required to
demonstrate compliance. As such,
recordkeeping associated with fume
suppressants requires only that sources
maintain records of the dale and time of
surface tension or foam blanket
thickness measurements, as appropriate,
the value measured, and the date and
time of additions of fume suppressant to
the bath. Likewise, the recordkeeping
associated with the add-on air pollution
control devices is reduced to the extent
that the monitoring requirements have
been reduced. Sources will have to keep
records of pressure drop and velocity
pressure, as appropriate, as well as
records to document adherence with the
O&M plan required by § 63.342(f)(3).
The final rule is unchanged from
proposal in that it requires that owners
or operators of affected sources maintain
records for a period of 5 years following
each occurrence, measurement,
maintenance, corrective action, report,
or record. This requirement is consistent
with the General Provisions and with
the title V permit program. The EPA
believes retention of records for 5 years
allows the EPA to establish a source's
history and pattern of compliance for
purposes of determining the appropriate
level of enforcement action.
The final rule also requires
submission of on-going compliance
status reports to document whether a
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Federal Register / Vol. 60. No. 16 / Wednesday, January 25. 1995 / Rules and Regulations 4961
source has been in continuous
compliance wiLh the standards. The
final rule contains different reporting
schedules for major and area sources.
Major sources are required to submit on-
going compliance status reports
semiannually, unless an exceedance
occurs, at which time quarterly reports
would be required. This change is
analogous to the requirements of the .
final General Provisions, which had
only been proposed at the time of this
proposed rulemaking.
In an effort to reduce the burden on
area sources, the final rule allows area
sources to complete an annual
compliance report, and allows the
source to maintain the report on site, to
be. made available to the Administrator
or permitting authority upon request.
The EPA recognizes that many
permitting authorities may not be
equipped to handle reports from area
sources, and that these sources may not
be the sources of primary concern to the
authority. However, the requirements in
the final rule do not alleviate affected
area sources from complying with the
reporting requirements of State or
Federal operating permit programs
under title V. The rule does require that
area sources submit reports
semiannually if exceedances occur, or if
required by the Administrator or
permitting authority.
Sources using a trivalent chromium
bath are only required to keep records
of the bath ingredients purchased. These
sources must submit an initial
notification and notification of
compliance status, but are not required
to submit on-going compliance status
reports.
As a result of the reduced monitoring,
reporting, and recordkeeping in the final
rule compared to the proposed rule, the
costs of these activities have also been
reduced. A comparison of the cost-of the
monitoring, reporting, and
recordkeeping associated with the final
and proposed rules was presented in
section UI.B of this preamble for each of
the regulated source categories.
One commenter requested that the
rule clearly state which sections of the
General Provisions apply to chromium
electroplating sources and which do not
apply. To eliminate confusion
concerning the applicability of the
General Provisions to this source
category. Table 1 of subpart N lists
which of the General Provisions to part
63 apply and which do not apply to
affected sources.
K. Operating Permit Program
Eleven commenters stated that area
sources should not be required to obtain
title V operating permits because the
costs for area sources to obtain title V
permits would be overly burdensome.
and the emissions from these sources
may be insignificant. Three of these
commenters suggested that the rule
explicitly state that a permit is required
only for applicable emissions units at
nonmajor sources. Two commenters
asked that a general permit be included
in the final rule to reduce the burden for
small facilities. Another commenter
stated that a title V permit is not
necessary because existing requirements
are enforceable through State and local
permits. This commenter and one other
commenter pointed out that because
area sources are not likely to be subject
to multiple MACT standards or to
employ emissions averaging and
complex alternate operating scenarios,
title V permits do not benefit the area
sources.
Two commenters stated that in
preparing their title V permit programs,
States did not anticipate a need for
emission-unit specific permits at
nonmajor sources, and inclusion of
nonmajor sources under title V will
require that many local agencies revise
their permit programs. Two other
commenters stated that States will not
have the resources for completing title
V permits for area sources; some states
have exempted nonmajor sources from
their permitting programs until the
nonmajor source permitting rule is
promulgated in the late 1990's.
The EPA believes that requiring all
sources that are subject to the standards,
including area sources, to obtain title V
operating permits is important because
of the toxicity of chromium compounds
and the close proximity of many of
these sources to residential areas. The
EPA believes that permitting area
sources will not be overly burdensome
to permitting authorities and affected
sources for the reasons given below.
First, many States are already
permitting these sources under their
State permit programs. The preamble to
the final part 70 rule states inat "some
nonmajor sources would already be
permitted at the State level, and
therefore would have some experience
with the permitting process and
completing permit applications."
Therefore, a State would have little
reason to defer title V permitting of
sources that already have State
operating permits. Second, the burden
may be reduced significantly by issuing
general permits to these sources.
According to the preamble to the final
part 70 rule, general permits "* * *
provide an alternative means for
permitting sources for which the
procedures of the normal permitting
process would be overly burdensome,
such as area sources under section
112* * *" Under this option. States _
would develop a single general permit
for this source category and issue it to
individual sources; or alternatively, a •
letter or certification may be used. The
burden would also be reduced by using
general permits because public
participation and the EPA and affected:"
State review is only necessary when the.
initial general permit is drafted and
issued. When subsequent general
permits are issued to individual sources,
these activities are not required. Finally.
States are developing small business
assistance programs (SBAP's) to assist
these types of sources with the
permitting process that will be funded
using the annual fees collected from
permitted sources. Small businesses
may also be eligible for reduced
permitting fees. Also, the EPA is
developing a guidance document,
scheduled to be completed by January
1995, which will include sample forms
for monitoring, recordkeeping, and
reporting requirements.'and a simplified
general operating permit.
Under title V, sources must include
information on all emission points
(except those considered insignificant
under the State or local permit program)
in their permit application. However,
only these emission points that are
subject to regulation will be addressed
in the permit.
VI. Administrative Requirements
A. Docket
The docket for this rulemaking is A-
8&-02. The docket is an organized and
complete file of all the information
submitted to or otherwise considered by
the EPA in the development of this
rulemaking. The principal purposes of
the docket are: (1) To allow interested
parties a means to identify and locate
documents so that they can effectively
participate in the rulemaking process;
and (2) to serve as the record in case of
judicial review (except for interagency
review materials) [section 307(d)(7)(A)
of the Act]. The docket is available for
public inspection at the EPA's Air and
Radiation Docket and Information
Center, the location of which is given in
the ADDRESSES section of this notice.
B. Executive Order 12B66
Under Executive Order 12866 [58 FR
51735 (October 4.1993)], the Agency
must determine whether the regulators1
action is "significant" and therefore
subject to OMB review and the
requirements of the Executive Order.
The Order defines "significant
regulatory action" as one that is likely
to result in a rule that may:
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4962 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
(1) Have an annual effect on the
economy of SlOO million or more, or
adversely affect in a material way the
economy, a sector of the economy,
productivity, competition, jobs, the
environment, public health or safety, or
State, local, or tribal governments or
communities;
(2) Create a serious inconsistency or
otherwise interfere with an action taken
or planned by another agency;
(3) Materially alter the budgetary
impact of entitlements, grants, user fees,
or loan programs or the rights and
obligations of recipients thereof; or
(4) Raise novel legal or policy issues
arising out of legal mandates, the
President's priorities, or the principles
set forth in the Executive Order.
Pursuant to the terms of the Executive
Order 12866. the Office of Management
and Budget (OMB) has notified the EPA
that this action is a "significant
regulatory action" within the meaning
of the Executive Order. For this reason,
this action was sent to OMB for review.
Changes made in response to OMB
suggestions or recommendations will be
documented in the public record.
C. Papenvork Reduction Act
Information collection requirements
associated with this rule have been
approved by OMB under the provisions
of the Paperwork Reduction Act of 1980,
44 U.S.C. 3501 et seq.. and have been
assigned OMB control number 2060-
0327. An Information Collection
Request (ICR) document has been
prepared by the EPA (ICR No. 1611.02)
Jo reflect the changed information
requirements of the final rule and has
been submitted to OMB for review. A
copy may be obtained from Sandy
Farmer, Information Policy Branch,
EPA. 401 M Street. SVV. (2136),
Washington. DC 20460, or by calling
(202) 260-2740.
The public reporting burden for this
collection of information is estimated to
average 34 hours per respondent in the
first year, 117 hours per respondent in
the second year, and 297 hours per
respondent in the third year. This
estimate includes the time required for
reviewing instructions, searching
existing data sources, gathering and
maintaining the data needed, and
completing and reviewing the collection
of information. The burden is greatest in
the second and third years because this
is when performance tests will be
conducted. An on-going burden of 104
hours per respondent is representative
of the burden following the third year.
Send comments regarding the burden
estimate or any other aspect of this
collection of information, including
suggestions for reducing this burden, to
Chief. Information Policy Branch, EPA,
401 M Street, SVV. (2136), Washington,
DC 20460; and to the Office of
Information and Regulatory Affairs,
Office of Management and Budget,
Washington, DC 20503, marked
"Attention: Desk Officer for EPA."
D. Regulatory Flexibility Act
The Regulatory Flexibility Act of 1980
(5 U.S.C. 601 et seq.) requires that a
Regulatory Flexibility Analysis be
performed for all rules that have
"significant impact on a substantial
number of small entities." If a
preliminary analysis indicates that a
proposed regulation would have a
significant economic impact on 20
percent or more of small entities, then
a regulatory flexibility analysis must be
prepared.
Present Regulatory Flexibility Act
guidelines define an economic impact
as significant if it meets one of the
following criteria:
(l) Compliance increases annual
production costs by more than 5
percent, assuming costs are passed on to
consumers;
(2) Compliance costs as a percentage
of sales for small entities are at least 10
percent more than compliance costs as
a percentage of sales for large entities;
(3) Capital costs of compliance
represent a "significant" portion of
capital available to small entities,
considering internal cash flow plus
external financial capabilities; or
(4) Regulatory requirements are likely
to result in closures of small entities.
Using the Small Business
Administration's definition of a small
business for SIC Code 3471 of less than
500 employees, it has been determined
that none of the above criteria are
triggered. In the hard chromium
electroplating source category, the
number of small businesses is estimated
to be 1,170. None of the regulatory
alternatives considered will
significantly impact 20 percent of this
operation. For example, the estimated
number of closures is approximated as
less than 5 percent. Likewise, the
standards for decorative chromium
electroplaters and chromium anodizers
would not cause any of the above
criteria to be triggered.
Pursuant to the provisions of 5 U.S.C.
605(b), I hereby certify that this rule will
not have a significant economic impact
on a substantial number of small
business entities because the number of
small business entities that would be
affected is not significant.
E. Miscellaneous
In accordance with section 117 of the
Act, publication of this promulgated
rule was preceded by consultation with
appropriate advisory committees,
independent experts, and Federal
departments and agencies.
This regulation will be reviewed 8
years from the date of promulgation.
This review will include an assessment
of such factors as evaluation of the
residual health risks, any overlap with
other programs, the existence of
alternative methods, enforceability.
improvements in emission control
technology and health data, and the
recordkeeping and reporting
requirements.
List of Subjects in 40 CFR Parts 9 and
63
Environmental protection, Air
pollution control. Hazardous
substances, Incorporation by reference.
Reporting and recordkeeping
requirements.
Dated: November 22, 1994.
Carol M. Browner,
Administrator.
For the reasons set out in the
preamble, title 40, Chapter I of the Code
of Federal Regulations is amended as set
forth below.
PART 9—[AMENDED]
1. The authority citation for part 9
continues to read as follows:
Authority: 7 U.S.C. 135 el seq.. 1235-136v;
15 U.S.C. 2001. 2003, 2005, 2006. 2601-267"l:
21 U.S.C. 331J. 346a, 348; 31 U.S.C 9701; 33 '
U.S.C. 1251 et seq.. 1311, 1313d, 1314, 1321,
1326.1330. 1344. 1345 (d) and (e), 1361: E.O.
11735. 38 FR 21243, 3 CFR, 1971-1975;
Comp. p. 973; 42 U.S.C. 241, 242b. 243, 2-16.
300f, 300g. 300g-l, 300g-2, 300g-3. 300g-4,
300g-5, 300g-6, 300J-1, 300J-2, 300|-3, 300J-
4. 300J-9, 1857 et seq., 6901-6992k, 7401-
7671q. 7542. 9601-9557. 11023, 1104S.
2. Section 9.1 is amended by adding
a new entry to the table under the
indicated heading in numerical order to
read as follows:
§ 9.1 OMB approvals under the Paperwork
Reduction Act
40 CFR citation
OMB con-
trol No.
National Emission Standards
for Hazardous Air Pollutants
lor Source Categories:
63.345-53.3-57 2060-0327
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Federal Register / Vol. 60, No. 16 /"Wednesday, January 25, 1995 / Rules and Regulations 4963
PART 63— {AMENDED]
1. The authority citation for part 63
continues to read as follows:
Authority: 42 U.S.C. 7401 et seq.
2. Section 63.14 is amended by
adding paragraphs fb) (4) and (5) to read
as follows:
§63.14 Incorporation by reference.
(4) ASTM D 1193-77, Standard
Specification for Reagent Water, IBR
approved for Method 306, section 4.1.1
and section 4.4.2, of appendix A to part
63.
(5) ASTM D 1331-69, Standard Test
Methods for Surface and Interfacial
Tension of Solutions of Surface Active
•Agents, IBR approved for Method 306B,
section 2.2, section 3.1, and section 4.2,
of appendix A to part 63.
» • • » *
3. By adding a new subpart N to read
as follows:
Subpart N — National Emission Standards
for Chromium Emissions From Hard and
Decorative Chromium Eisctroplating and
Chromium Anodizing Tanks
Sec.
63.340 Applicability and designation of
sources.
63.341 Definitions and nomenclature.
63.342 Standards.
63.343 Compliance provisions.
63.344 Performance test requirements and
test methods.
63.345 Provisions for new and
reconstructed sources.
63.345 Recordkeeping requirements.
63.347 Reporting requirements.
Table 1 to Subpart N" of Part 63—
General Provisions Applicability to
Subpart N
Subpart N — National Emission
Standards for Chromium Emissions
From Hard and Decorative Chromium
Electroplating and Chromium
Anodizing Tanks
§ 63.340 Applicability and designation of
sources.
(a) The affected source to which the
provisions of this subpart apply is each
chromium electroplating or chromium
anodizing tank at facilities performing
hard chromium electroplating,
decorative chromium electroplating, or
chromium anodizing.
(b) Owners or operators of affected
sources subject to the provisions of this
subpart must also comply with the
requirements of subpart A of this part,
according to the applicability of subpart
A of this part to such sources, as
identified in Table 1 of this subpart.
(c) Process tanks associated with a
chromium electroplating or chromium
anodizing process, but in which neither
chromium electroplating nor chromium
anodizing is taking place, are not subject
to the provisions of this subpart.
Examples of such tanks include, but are
not limited to; rinse tanks, etching
tanks, and cleaning tanks. Likewise,
tanks that contain a chromium solution,
but in which no electrolytic process
occurs, are not subject to this subpart.
An example of such a tank is a chrome
conversion coating tank where no
electrical current is applied.
(d) Affected sources in which research
and laboratory operations are performed
are exempt from the provisions of this
subpart when such operations are taking
place.
(e) The owner or operator of an
affected source subject to the
requirements of this subpart is required
to obtain a title V permit from the
permitting authority in which the
affected source is located.
§ 63".341 Definitions and nomenclature.
(a) Definitions. Terms used in this
subpart are defined in the Act, in
subpart A of this part, or in this section.
For the purposes of subpart N of this
part, if the same term is defined in
subpart A of this part and in this
section, it shall have the meaning given
in this section.
Add-on air pollution control device
means equipment installed in the
ventilation system of chromium
electroplating and anodizing tanks for
the purposes of collecting and
containing chromium emissions from
the tank(s).
Air pollution control technique means
any method, such as an-add-on air
pollution control device or a chemical
fume suppressant, that is used to reduce
chromium emissions from chromium
electroplating and chromium anodizing
tanks.
Base metal means the metal or metal
alloy that comprises the workpiece.
Bath component means the trade or
brand name of each component(s) in
trivalent chromium plating baths. For
trivalent chromium baths, the bath
composition is proprietary in most
cases. Therefore, the trade or brand
name for each component(s) can be
used; however, the chemical name of
the wetting agent contained in that
component must be identified..
Chemical fume suppressant means
any chemical agent that reduces or
suppresses fumes or mists at the surface
of an electroplating or anodizing bath;
another term for fume suppressant is
mist suppressant.
Chromic acid means the common
name for chromium anhydride (CrO3).
Chromium anodizing means the
electrolytic process by which an oxide
layer is produced on the surface of a
base metal for functional purposes (e.g.,
corrosion resistance or electrical
insulation) using a chromic acid
solution. In chromium anodizing, the
part to be anodized acts as the anode in
the electrical circuit, and the chromic
acid solution, with a concentration
typically ranging from 50 to 100 grains
p'er liter (g/L), serves as the electrolyte*
Chromium electroplating or
chromium anodizing tank means the
receptacle or container in which hard or
decorative chromium electroplating or
chromium anodizing occurs.
Composite mesh-pad system means
an add-on air pollution control device
typically consisting of several mesh-pad
stages. The purpose of the first stage is
to remove large particles. Smaller
particles are removed in the second
stage, which consists of the composite
mesh pad. A final stage may^emove any
reentrained particles not collected by
the composite mesh pad.
Decorative chromium electroplating
means the process by which a thin layer
of chromium (typically 0.003 to 2.5
microns] is electrodeposited on a base
metal, plastic, or undercoating to
provide a bright surface with wear and
tarnish resistance. In this process, the
part(s) serves as the cathode in the
electrolytic cell and the solution serves
as the electrolyte. Typical current
density applied during this process
ranges from 540 to 2,400 Amperes per
square meter (A/in1) for total plating
times ranging between 0.5 to 5 minutes.
Electroplating or anodizing bath
means the electrolytic solution used as
the conducting medium in which the
flow of current is accompanied by
movement of metal ions for the
purposes of electroplating metal out of
the solution onto a workpiece or for
oxidizing the base material.
Emission limitation means, for the
purposes of this subpart, the
concentration of total chromium
allowed to be emitted expressed in
milligrams per dry standard cubic meter
(mg/dscm), or the allowable surface
tension expressed in dynes per
centimeter (dynes/cm).
Facility means the major or area
source at which chromium
electroplating or chromium anodizing is
performed.
Fiber-bed mist eliminator means an
add-on air pollution control deVice that
removes contaminants from a gas stream
through the mechanisms of inertial
impaction and Brownian diffusion.
These devices are typically installed
downstream of another control device,
which serves to prevent plugging, and
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4964 Federal Register / Vol. 60, No. 16 / Wednesday. January 25. 1995 / Rules and Regulations
consist of one or more fiber beds. Each
bed consists of a hollow cylinder
formed from two concentric screens; the
fiber between the screens may be
fabricated from glass, ceramic plastic, or
metal
Foam blanket means the type of
chemical fume suppressant that
generates a layer of foam across the
surface of a solution when current is
applied to that solution.
Fresh water means water, such as tap
water, that has not been previously used
in a process operation or, if the water
has been recycled from a process
operation, it has been treated and meets
the effluent guidelines for chromium
wastewater.
Hard chromium electroplating or
industrial chromium electroplating
means a process by which a thick layer
of chromium (typically 1.3 to 760
microns) is electrodeposited on a base
material to provide a surface with
functional properties such as wear
resistance, a low coefficient of friction,
hardness, and corrosion resistance. In
this process, the part serves as the
cathode in the electrolytic cell and the
solution serves as the electrolyte. Hard
chromium electroplating process is
performed at current densities typically
ranging from 1,600 to 6,500 A/m- for
total plating times ranging from 20
minutes to 36 hours depending upon
the desired plate thickness.
Hexavalent chromium means the form
of chromium in a valence state of -f 6.
Large, hard chromium electroplating
facility means a facility that performs
hard chromium electroplating and has a
maximum cumulative potential rectifier
capacity greater than or equal to 60
million ampere-hours per year (amp-hr/
yr).
Maximum cumulative potential
rectifier capacity means the summation
of the total installed rectifier capacity
associated with the hard chromium
electroplating tanks at a facility,
expressed in amperes, multiplied by the
maximum potential operating schedule
of 8,400 hours per year and 0.7, which
assumes that electrodes are energized 70
percent of the total operating time. The
maximum potential operating schedule
is based on operating 24 hours per day,
7 days per week, 50 weeks per year.
Operating parameter value means a
minimum or maximum value
established for a control device or
process parameter which, if achieved by
itself or in combination with one or
more other operating parameter values,
determines that an owner or operator is
ini coDtsnaai compliance with the
applicable emission limitation or
standard.
Packed-bed scrubber means an add-on
air pollution control device consisting
of a single or double packed bed that
contains packing media on which the
chromic acid droplets impinge. The
packed-bed section of the scrubber is
followed by a mist eliminator to remove
any water entrained from the packed-
bed section
Research or laboratory operation
means an operation whose primary
purpose is for research and
development of new processes and
products, that is conducted under the
close supervision of technically trained
personnel, and that'is not involved in
the manufacture of products for
commercial sale in commerce, except in
a de minimis manner.
Small, hard chromium electroplating
facility means a facility that performs
hard chromium electroplating and has a
maximum cumulative potential rectifier
capacity less than 60 million amp-hr/yr.
StaJagmometer means a device used
to measure the surface tension of a
solution.
Surface tension means the property,
due to molecular forces, that exists in
the surface film of all liquids and tends
to prevent liquid from spreading.
Tank operation means the time in
which current and/or voltage is being
applied to a chromium electroplating
tank or a chromium anodizing tank.
Tensiometer means a device used to
measure the surface tension of a
solution.
Trivalent chromium means the form
of chromium in a valence state of +3.
Trivalent chromium process means
the process used for electrodeposition of
a thin layer of chromium onto a base
material using a trivalent chromium
solution instead of a chromic acid
solution.
Wetting agent means the type of
chemical fume suppressant that reduces
the surface tension of a liquid.
fb) Nomenclature. The nomenclature
used in this subpart has the following
meaning:
(1) AMR=the allowable mass emission
rate from each type of affected source
subject to the same emission limitation
in milligrams per hour (mg/hr).
(2) AMR,y,=the allowable mass
emission rate from affected sources
controlled by an add-on air pollution
control device controlling emissions
from multiple sources in mg/hr.
(3) EL=the applicable emission
limitation from § 63.342 in milligrams
per dry standard cubic meter (mg/
dscm).
(4) lAlotmj=the sum of all inlet duct
areas from both affected and nonaffected
sources in meters squared.
(5) IDA,=the total inlet area for all
ducts associated with affected so^irces
in meters squared
(6) IDA,.J=the total inlet duct area for
al! ducts conveying chromic acid from
each type of affected source performing
the same operation, or each type of
affected source subject to the same
emission limitation in meters squared.
(7) VR=the total of ventilation rates
for each type of affected source subject
to the same emission limitation in dry
standard cubic meters per minute
(dscm/min).
(8) VRmi«,=the total ventilation rate
from all inlet ducts associated with
affected sources in dscm/min.
(9) VRiniel.a=the total ventilation rate
from all inlet ducts conveying chromic
acid from each type of affected source
performing the same operation, or each
type of affected source subject to the
same emission limitation in dscm/rnin.
(10) VR,o<=the average total ventilation
rate for the three test runs as determined
at the outlet by means of the Method
306 in appendix A of this part testing in
dscm/min.
§ 63.342 Standards.
(a) Each owner or operator of an
affected source subject to the provisions
of this subpart shall comply with these
requirements on and after the
compliance dates specified in
§ 63.343(a). All affected sources arc
regulated by applying maximum
achievable control technology.
(b) Applicability of emission limits.
(1) The emission.limitations in this
section apply only during tank
operation, and also apply during
periods of startup and shutdown as
these are routine occurrences for
affected sources subject to this subpart.
The emission limitations do not apply
during periods of malfunction, but the
work practice standards that address
operation and maintenance and that are
required by paragraph (f) of this section
must be followed during malfunctions.
(2) If an owner or operator is
controlling a group of tanks with a
common add-on air pollution control
device, the emission limitations of
paragraphs (c), (d), and (e) of this
section apply whenever any one
affected source is operated. The
emission limitation that applies to the
group of affected sources is:
(i) The emission limitation identified
in paragraphs (c), (d), and (e) of this
section if the affected sources are
performing the same type of operation
(e.g., hard chromium electroplating), are
subject to the same emission limitation,
and are not controlled by an add-on air
pollution control device also controlling
nonaffected sources;
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Federal Register / Vo. 60. No 16 / Wednesday. January 25, 1995 • Rules and Regulations 4965
(ii) The emission limitation calculated
according to § 63 344(e)(3) if affected
iources are performing the same type of
operation, are subject to the same
emission limitation, and are controlled
with an add-on air pollution control
device that is also controlling
nonaffected sources; and
(iii) The emission limitation
calculated according to § 53.34-S(e)(4) if
affected sources are performing different
types of operations, or affected sources
are performing the same operations but
subject to different emission limitations.
and are controlled with an add-on air
pollution control device that may also
be controlling emissions from
nonaffected sources
(c)(l) Standards for hard chromium
electroplating tanks. During tank
operation, each owner or operator of an
existing, new. or reconstructed affected
source shall control chromium
emissions discharged to the atmosphere
from that affected source by not
allowing the concentration of total
chromium in the exhaust gas stream
discharged to the atmosphere to exceed:
(i) 0.015 milligrams of total chromium
per dry standard cubic meter (mgAdscm)
of ventilation air (6.6x10 ~6 grains per
dry standard cubic foo: [gr/dscf]); or
'(ii) 0.03 mg/dscm (1.3xlO~3 gr/dscf) if
the hard chromium electroplating tank
is an existing affected source and is
located at a small, hard chromium
electroplating facility.
(2)(i) An owner or operator mav
demonstrate the size of a hard
chromium electroplating facility-
through the definitions Li §63.341(a).
Alternatively, an owner or operator of a
facility with a maximum cumulative
potential rectifier capacity of 60 million
amp-hr/yr or more may be considered
small if the actual cumulative rectifier
capacity is less than 60 million amp-hr/
yr as demonstrated using the following
procedures:
(A) If records show that the facility's
previous annual actual rectifier capacity
was less than 60 million amp-hr/yr, by
using nonresettable ampere-hr meters
and keeping monthly records of actual
ampere-hr usage for each 12-month
rolling period following the compliance
date in accordance with § 63.346(b)(12).
The actual cumulative rectifier capacity
for the previous 12-month rolling period
shall be tabulated monthly by adding
the capacity for the current month to the
capacities for the previous 11 months;
or
(B) By accepting a Federally-
enforceable limit on the maximum
cumulative potential rectifier capacity
of a hard chromium electroplating
facility through the title V permit
required by § 63.340(e). and by
maintaining monthly records in
accordance with § 63 346(b)(12) to
demonstrate that the limit has not been
exceeded The actual cumulative
rectifier capacity for the previous 12-
month rolling period shall be tabulated
monthly by adding the capacity for the
current month to the capacities for the
previous 11 months
(ii) Once the monthly records
required to be kept by § 63.346(b)(12)
and by this paragraph show that the
actual" cumulative rectifier capacity over
the previous 12-month rolling period
corresponds to the large designation, the
owner or operator is subject to the
emission limitation identified in
paragraph (c)(l)(i) of this section, in
accordance with the compliance
schedule of §63.343(a)(5).
(d) Standards for decorative
chromium electroplating tanks using n
chromic acid bath and chromium
anodizing tanks. During tank operation.
each owner or operator of an existing.
new, or reconstructed affected source
shall control chromium emissions
discharged to the atmosphere from that
affected source by either:
(1) Not allowing the concentration of
total chromium in the exhaust gas
stream discharged to the atmosphere to
exceed 0.01 mg/dscm (4.4xlO~° gr/
dscf); or
(2) If a chemical fume suppressant
containing a wetting agent is used, by
not allowing the surface tension of the
electroplating or anodizing bath
contained within the affected source to
exceed 45 dynes per centimeter (dynes/
crn) (3.1xlO-J pound-force per foot [lb;V
ft]) at any time during operation of the
tank.
(e) Standards for decorative
chromium electroplating tanks using a
trivalent chromium bath. (1) Each owner
or operator of an existing, new, or
reconstructed decorative chromium
electroplating tank that uses a trivalent
chromium bath that incorporates a
wetting agent as a bath ingredient is
subject to the recordkeeping and
reporting requirements of
§§63.346(b)(14) and 63.347(i). but are
not subject to the work practice
requirements of paragraph (f) of this
section, or the continuous compliance
monitoring requirements in § 63.343(c).
The wetting agent must be an ingredient
in the trivalent chromium bath
comoonents purchased from vendors.
(2} Each owner or operator of an
existing, new, or reconstructed
decorative chromium electroplating
tank that uses a trivalent chromium bath
that does not incorporate a wetting
agent as a bath ingredient is subject to
the standards of paragraph (d) of this
section.
(3) each owner or operator of existing.
new, or reconstructed decorative
chromium electroplating tank that had
been using a trivalent chromium bath
that incorporates a wetting agent and
ceases using this type of bath must •
fulfill the reporting requirements of
§ 63.347(i)(3) and comply with the
applicable emission limitation within
the timeframe specified in
§63.343(a)(7)
(f) Work practice standards. The work
practice standards of this section
address'operation and maintenance
practices. All owners or operators
subject to the standards in paragraphs
(c) and (d) of this section are subject to
these work practice standards.
(l)(i) At all times, including periods
of startup, shutdown, and malfunction,
owners or operators shall operate and
maintain any affected source, including
associated air pollution control devices
and monitoring equipment, in a manner
consistent with good air pollution
control practices, consistent with the
operation and maintenance plan
required by paragraph (f){3) of this
section.
(ii) Malfunctions shall be corrected as
soon as practicable after their
occurrence in accordance with the
operation and maintenance plan
required by paragraph (f)(3) of this
section.
(iii) Operation and maintenance
requirements established pursuant to
section 112 of the Act are enforceable
independent of emissions limitations or
other requirements in relevant
standards.
(2)(i) Determination of whether
acceptable operation and maintenance
procedures are being used will be based
on information available to the
Administrator, which may include, but
is not limited to, monitoring results;
review of the operation and
maintenance plan, procedures, and
records; and inspection of the source.
(ii) Based on the results of a
determination made under paragraph
(f)(2)(i) of this section, the
Administrator may require that an
owner or operator of an affected source
make changes to the operation and
maintenance plan required by paragraph
(f)(3) of this section for that source.
Revisions may be required if the
Administrator finds that the plan:
(A) Does not address a malfunction
that has occurred;
(B) Fails to provide for the operation
of the affected source, the air pollution
control techniques, or the control
system and process monitoring
equipment during a malfunction in a
manner consistent with good air
pollution control practices; or
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4966 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
(C) Does not provide adequate
procedures for correcting
malfunctioning process equipment, air
pollution control techniques, or
monitoring equipment as quickly as
practicable.
(3) Operation and maintenance plan.
(i) The owner or operator of an affected
source subject to the work practices of
paragraph (f) of this section shall
prepare an operation and maintenance
plan to be implemented no later than
the compliance date. The plan shall be
incorporated by reference into the
source's title V permit and shall include
the following elements:
(A) The plan shall specify the
operation and maintenance criteria for
the affected source, the add-on air
pollution control device (if such a
device is used to comply with the
emission limits), and the process and
control system monitoring equipment,
and shall include a standardized
checklist to document the operation and
maintenance of this equipment;
(B) For sources using an add-on air
pollution control device or monitoring
equipment to comply with this subpart,
the plan shall incorporate the work
practice standards for that device or
monitoring equipment, as identified in
Table 1 of this section, if the specific
equipment used is identified in Table 1
of this section;
(C) If the specific equipment used is
not identified in Table 1 of this section,
the plan shall incorporate proposed
work practice standards. These
proposed work practice standards shall
be submitted to the Administrator for
approval as part of the submittal
required under §63.343(d);
(D) The plan shall specify procedures
to be followed to ensure that equipment
or process malfunctions due to poor
maintenance or other preventable
conditions do not occur; and
(E) The plan shall include a
systematic procedure for identifying
malfunctions of process equipment,
add-on air pollution control devices,
and process and control system
monitoring equipment and for
implementing corrective actions to
address such malfunctions.
(ii) If the operation and maintenance
plan fails to address or inadequately
addresses an event that meets the
characteristics of a malfunction at the
time the plan is initially developed, the
owner or operator shall revise the
operation and maintenance plan within
45 days after such an event occurs. The
revised plan shall include procedures
for operating and maintaining the
process equipment, add-on air pollution
control device, or monitoring equipment
'"3uring similar malfunction events, and
a program for corrective action for such
events.
(iii) Recordkeeping associated with
the operation and maintenance plan is
identified in §63.346(b). Reporting
associated with the operation and
maintenance plan is identified in
§ 63.347 (g) and (h) and paragraph
(f)(3){iv) of this section.
(iv) If actions taken by the owner or
operator during periods of malfunction
are inconsistent with the procedures
specified in the operation and
maintenance plan required by paragraph
(f)(3)(i) of this section, the owner or
operator shall record the actions taken
for that event and shall report such
actions within 2 working days after
commencing actions inconsistent with
the plan. This report shall be followed
by a letter within 7 working days after
the end of the event, unless the owner
or operator makes alternative reporting
arrangements, in advance, with the
Administrator.
(v) The owner or operator shall keep
the written operation and maintenance
plan on record after it is developed to
be made available for inspection, upon
request, by the Administrator for the life
of the affected source or until the source
is no longer subject to the provisions of
this subpart. In addition, if the
operation and maintenance plan is
revised, the owner or operator shall
keep previous (i.e., superseded) versions
of the operation and maintenance plan
on record to be made available for
inspection, upon request, by the
Administrator for a period of 5 years
after each revision to the plan.
(vi) To satisfy the requirements of
paragraph (f)(3) of this section, the
owner or operator may use applicable
standard operating procedure (SOP)
manuals, Occupational Safety and
Health Administration (OSHA) plans, or
other existing plans, provided the
alternative plans meet the requirements
of this section.
(g) The standards in this section that
apply to chromic acid baths shall not be
met by using a reducing agent to change
the form of chromium from hexavalent
to trivalent.
§63.343 Compliance provisions.
(a) Compliance dates. (1) The owner
or operator of an existing affected source
shall comply with the emission
limitations in § 63.342 as follows:
(i) No later than 1 year after January
25, 1995, if the affected source is a
decorative chromium electroplating
tank; and
(ii) No later than 2 years after January
25, 1995, if the affected source is a hard
chromium electroplating tank or a
chromium anodizing tank.
(2) The owner or operator of a new or
reconstructed affected source that has
an initial startup after January 25, 1995.
shall comply immediately upon startup
of the source. The owner or operator of
a new or reconstructed affected source
that has an initial startup after
December 16, 1993 but before January
25, 1995, shall follow the compliance
schedule of § 63.6(b) (3) and (4).
TABLE 1 TO §63.342.—SUMMARY OF WORK PRACTICE STANDARDS
Control technique
Composite mesh-pad (CMP) sys-
tem.
Packed-bed scrubber (PSB)
Work practice standards
1. Visuafly inspect device to ensure there is proper drainage, no chronic acid
buildup on the pads, and no evidence of chemical attack on the structural integ-
rity of the device.
2. Visualry inspect back portion of the mesh pad closest to the fan to ensure there
is no breakthrough of chromic acid mist.
3. Visualry inspect ductwork from tank to the control device to ensure there are no
leaks.
4. Perform washdown of the composite mesh-pads in accordance with manufac-
turers recommendations.
1. Visually inspect device to ensure there is proper drainage, no chromic acid
buildup on the packed beds, and no evidence ol chemical attack on the struc-
tural integrity ol the device.
2. Visually inspect back portion ol the chevron blade mist eliminator to ensure that
it is dry and there is no breakthrough of chromic acid misL
3. Same as number 3 above
Frequency
1. I/quarter.
2. 1/quarter.
3. 1/quarter.
4. Per manufacturer
1. I/quarter.
2. 1/quarter
3. I/quarter
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Federal Register / Vol. 60. No. 16 X Wednesday. January 25, 1995 / Rules and Regulations 496
TABLE 1 TO §63.342.—SUMMARY OF Woftx PRACTICE STANDARDS—Continued
Control technique
Work practice standards
Frequency
4. Add fresh makeup-water to the -top oHhe packed bed ** _..
PBS/CMP system
Fiber-tied mist eliminatorc
t Same as (or CMP system
2. Same -as for CMP system
3. Same as for CMP system _ _
4. Same as for CMP system .
Air pollution control device
(APCD) not fisted in rute.
1. VisuaBy inspect fiber-bed unfi and prefiftering device to ensure there is proper
drainage, no chromic acid buildup in the units, and no evidence oi chemical at-
tack on the structural integrity ci the devices.
2. Visually inspect ductwork from tank or tanks to the control device to ensure
there are no leaks.
3. Perform washdcwn cf fiber elements in accordance with manufacturers rec-
ommendations.
To be proposed by the source for approval by the Administrator „
4. Whenever makeup is
added.
1. 1/quarter.
2. Uquaner.
3. I/quarter.
4. Per manufacturer.
1.1/quarter.
2. 1/quarter.
3. Per manufaciurer.
To be proposed by the
source tor approval
by the Administrator.
Monitoring Equipment
Pilot tube
Stalagmometer
Backflush with water, or remove from the duct arxJ rinse with fresh water. Replace
in the duct and rotate 180 degrees to ensure that the same zero reading is ob-
tained. Check pilot tube ends for damage. Replace pilot tube if cracked or fa-
tigued.
Follow manufacturers recommendations : , _ ::_
1/quarter
•If greater than 50 percent ol the scrubber water is drained fe.g., for maintenance purposes), makeup water may be added to tne scrubber
basin.
b For horizoniaf-flow scrubbers, top is defined as the section of the unit directly above the packing media such that the makeup water would
flow perpendicular to the air flow through the packing. For vertical-flow unite, the top is defined as the area downstream of the packing maleriai
such that the makeup water would flow countercurrent to the air How through the unit.
< Work practice standarcs for the control -device instated upstream o< the -fiber-bed mist eliminator to prevent plugging da not appry as long as
the work practice standards for the fioer-bed unit are followed. -
(3) The owner or operator of an
existing area source that increases actual
or potential emissions of hazardous air
pollutants such that the area source
becomes a major source must comply
with the provisions for existing major
sources, including the reporting
provisions of § 63.34~(g), immediately
upon becoming a major source.
(4) The owner or operator of a new
area source (i.e., an area source for
which construction or reconstruction
was commenced after December 16,
1993) that increases actual or potential
emissions of hazardous air pollutants
such that the area source becomes a
major source must comply with the
provisions for new major sources,
immediately upon becoming a major
source.
(5) An owner or operator of an
existing hard chromium electroplating
tank or tanks located at a small, hard
chromium electroplating facility that
increases its maximum cumulative
potential rectifier capacity, or its actual
cumulative rectifier capacity, such that
the facility becomes a large, hard
chromium electroplating facility must
comply with the requirements of
§ 63.342(c}(l)[i) for all hard chromium
electroplating tanks at-the facility no
later than 1 yearafter the month in
which-morithly records required by
§§ 63.342(c)(2) and 63.346(b)(12) show
that the large designation is met
(6) Request for an extension of
compliance. An owner or operator of an
affected source or sources that requests
an extension of compliance shall do so
in accordance with this paragraph and
the applicable paragraphs of § 63.6(i).
When the owner or operator is
requesting the extension for more than
one affected source located at the
facility, then only one request may be
submitted for all affected sources at the
facility.
(i) The owner or operator of an
existing affected source who is unable to
comply with a relevant standard under
this subpart may request that the
Administrator (or a State, when the
State has an approved part 70 permit
program and the source is required to
obtain a part 70 permit under that
program, or a State, when the State has
been delegated the authority to
implement and enforce the emission
standard for that source] grant an
extension allowing the owner or
operator up to 1 additional year to
comply with the standard for the
affected source. The owner or operator
of an affected source who has requested
an extension of compliance under this
paragraph and is otherwise required to
obtain a title V permit for the source
shall apply for such permit or apply to
havethe title V permit revised to
incorporate-the conditions of the
extension of compliance. The
conditions of an extension of
compliance granted under this
paragraph will be incorporated into the
owner or operator's title V permit for thn
affected source(s) according to the
provisions of 40 CFR part 70 or 4 0 CFR
part 71, whichever is applicable.
(ii) Any request under this paragraph
for an extension of compliance with a
relevant standard shall be submitted in
writing to the appropriate authority not
later than 6 months before the affected
source's compliance date as specified in
this section.
(7) An owner or operator of a
decorative chromium electroplating
tank that uses a trivalent chromium bath
that incorporates a wetting agent, and
that ceases using the trivalent chromium
process, must comply with the emission
limitation now applicable to the tank
within 1 year of switching bath
operation.
(b) Methods to demonstrate initial
compliance. (Ij Except as provided in
paragraphs (b)(2) and (b)(3) of this
section, an owner or operator of an
affected source subject to the
requirements -of this subpart is required
to conduct an initial performance test as
required under § 63.7. using the
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4968 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
procedures and test methods listed in
•§63.7 and §63.344.
(2) If the owner or operator of an
affected source meets all of the
following criteria, an initial
performance test is not required to be
conducted under this subpart:
(i) The affected source is a decorative
chromium electroplating tank or a
chromium anodizing tank; and
(ii) A wetting agent is used in the
plating or anodizing bath to inhibit
chromium emissions from the affected
source; and
(iii) The owner or operator complies
with the applicable surface tension limit
of § 63.342(d)(2) as demonstrated
through the continuous compliance
monitoring required by paragraph
(c)(5)(ii) of this section.
(3) If the affected source is a
decorative chromium electroplating
tank using a trivalent chromium bath,
and the owner or operator is subject to
the provisions of § 63.342(e). an initial
performance test is not required to be
conducted under this subpart.
(c) Monitoring to demonstrate
continuous compliance. The owner or
operator of an affected source subject to
the emission limitations of this subpart
shall conduct monitoring according to
the type of air pollution control
technique that is used to comply with
the emission limitation. The monitoring
required to demonstrate continuous
compliance with the emission
limitations is identified in this section
for the air pollution control techniques
expected to be used by the owners or
operators of affected sources.
(1) Composite mesh-pad systems, (i)
During the initial performance test, the
owner or operator of an affected source,
or a group of affected sources under
common control, complying with the
emission limitations in § 63.342 through
the use of a composite mesh-pad system
shall determine the outlet chromium
concentration using the test methods
and procedures in § 63.344(c). and shall
establish as a site-specific operating
parameter the pressure drop across the
system, setting the value that
corresponds to compliance with the
applicable emission limitation, using
the procedures in § 63.344(d)(5). An
owner or operator may conduct multiple
performance tests to establish a range of
compliant pressure drop values, or may
set as the compliant value the average
pressure drop measured over the three
test runs of one performance test and
accept ±1 inch of water column from
this value as the compliant range.
(ii) On and after the date on which the
initial performance test is required to be
completed under § 63.7, the owner or
operator of an affected source, or group
of affected sources under common
control, shall monitor and record the
pressure drop across the composite
mesh-pad system once each day that
any affected source is operating. To be
in compliance with the standards, the
composite mesh-pad system shall be
operated within ±1 inch of water
column of the pressure drop value
established during the initial
performance test, or shall be operated
within the range of compliant values for
pressure drop established during
multiple performance tests.
(2) Packed-bed scrubber systems, (i)
During the initial performance test, the
owner or operator of an affected source,
or group of affected sources under
common control, complying with the
emission limitations in § 63.342 through
the use of a packed-bed scrubber system
shall determine the outlet chromium
concentration using the procedures in
§ 63.344(c), and shall establish as site-
specific operating parameters the
pressure drop across the system and the
velocity pressure at the common inlet of
the control device, setting the value that
corresponds to compliance with the
applicable emission limitation using the
procedures in § 63.344(d) (4) and (5). An
owner or operator may conduct multiple
performance tests to establish a range of
compliant operating parameter values.
Alternatively, the owner or operator
may set as the compliant value the
average pressure drop and inlet velocity
pressure measured over the three test
runs of one performance test, and accept
±1 inch of water column from the
pressure drop value and ±10 percent
from the velocity pressure value as the
compliant range.
(ii) On and after the date on which the
initial performance test is required to be
completed under §63.7. the owner or
operator of an affected source, or group
of affected sources under common
control, shall monitor and record the
velocity pressure at the inlet to the
packed-bed scrubber and the pressure
drop across the scrubber system once
each day that any affected source is
operating. To be in compliance with the
standards, the scrubber system shall be
operated within ±10 percent of the
velocity pressure value established
during the initial performance test, and
within ±1 inch of water column of the
pressure drop value established during
the initial performance test, or within
the range of compliant operating
parameter values established during
multiple performance tests.
(3) Packed-bed scrubber/composite
mesh-pad system. The owner or
operator of an affected source, or group
of affected sources under common
control, that uses a packed-bed scrubber
in conjunction with a composite mesh-
pad system to meet the emission
limitations of § 63.342 shall comply
with the monitoring requirements for
composite mesh-pad systems as
identified in paragraph (c)(l) of this
section.
(4) Fiber-bed mist eliminator, (i)
During the initial performance test, the
owner.or operator of an affected source.
or group of affected sources under
common control, complying with the
emission limitations in § 63.342 through
the use of a fiber-bed mist eliminator
shall determine the outlet chromium
concentration using the procedures in
§ 63.344(c), and shall establish as a site-
specific operating parameter the
pressure drop across the fiber-bed mist
eliminator and the pressure drop across
the control device installed upstream of
the fiber bed to prevent plugging, setting
the value that corresponds to
compliance with the applicable
emission limitation using the
procedures in § 63.344(d)(5). An owner
or operator may conduct multiple
performance tests to establish a range of
compliant pressure drop values, or may
set as the compliant value the average
pressure drop measured over the three
test runs of one performance test and
accept ± 1 inch of water column from
this value as the compliant range.
(ii) On and after the date on which the
initial performance test is required to be
completed under § 63.7, the owner or
operator of an affected source, or group
of affected sources under common
control, shall monitor and record the
pressure drop across the fiber-bed mist
eliminator, and the control device
installed upstream of the fiber bed to
prevent plugging, once each day that
any affected source is operating. To be
in compliance with the standards, the
fiber-bed mist eliminator and the
upstream control device shall be
operated within ±1 inch of water
column of the pressure drop value
established during the initial
performance test, or shall be operated
within the range of compliant values for
pressure drop established during
multiple performance tests.
(5) Wetting agent-type or combination
wetting agent-type/foam blanket fume
suppressants, (i) During the initial
performance test, the o%vner or operator
of an affected source complying with
the emission limitations in § 63.342
through the use of a wetting agent in the
electroplating or anodizing bath shall
determine the outlet chromium
concentration using the procedures in
§ 63.344(c). The owner or operator shall
establish as the site-specific operating
parameter the surface tension of the
bath using Method 306B, appendix A of
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Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
this part, setting the maximum value
that corresponds to compliance with the
applicable emission limitation. In lieu
of establishing the maximum surface
tension during the performance test, the -
owner or operator may accept 45 dynes/
cm as the maximum surface tension
value that corresponds to compliance
with the applicable emission limitation.
However, the owner or operator is
exempt from conducting a performance
test only if the criteria of paragraph
(b)(2) of this section are met.
(ii) On and after the date on which the
initial performance test is required to be
completed under §63.7, the owner or
operator of an affected source shall
monitor the surface tension of the
electroplating or anodizing bath.
Operation of the affected source at a
surface tension greater than the value
established during the performance test,
or greater than 45 dynes/cm if the owner
or operator is using this value in
accordance with paragraph (c)(5)(i) of
this section, shall constitute
noncomph'ance with the standards. The
.surface tension-shall be monitored
according to the following schedule:
" (A) The surface tension shall be
me'asured once every 4 hours during
operation of the tank with a
stalagmometer or a tensiometer as
specified in Method 3Q6B, appendix A
of this part.
(B) Tne time between monitoring can
be increased if there have been no
exceedances. The surface tension shall
be measured once every 4 hours of tank
operation for the first 40 hours of tank
operation after the compliance date.
Once there are no exceedances during
40 hours of tank operation, surface
tension measurement may be conducted
once every 8 hours of tank operation.
Once there are no exceedances during
40 hours of tank operation, surface
tension measurement may be conducted
once every 40 hours of tank operation
on an ongoing basis, until an
exceedance occurs. The minimum
frequency of monitoring allowed by this
subpart is once every 40 hours of tank
operation.
(C) Once an exceedance occurs as
indicated through surface tension
monitoring, the original monitoring
schedule of once every 4 hours must be
resumed. A subsequent decrease in
frequency shall follow the schedule laid
out in paragraph (c)(5)(ii)(8) of this
section. For example, if an owner or
operator had been monitoring an
affected source once every 40 hours and
an exceedance occurs, subsequent
monitoring would take place once e*ery
4 hours of tank operation. Oaoe an
exceedance does not occur for 40 hours
of tank operation, monitoring can occur .
once every 8 hours of tank operation.
Once an exceedance does not occur for
40 hours of tank operation on this
schedule, monitoring can occur once
every 4O hours of tank operation.
(iii) Once a bath solution is drained
from the affected tank and a new
solution added, the original monitoring
schedule of once every 4 hours must be
resumed, with a decrease in monitoring
frequency allowed following the
procedures of paragraphs (c)(5)(ii) (B)
and (C) of this section.
(6) Foam blanket-type fume
suppressants, (i) During the initial
performance test, the owner or operator
of an affected source complying with
the «nni«inn limitations in §63.342
through the use of a foam blanket in the
electroplating or anodizing bath shall
determine the outlet chromium
concentration using the procedures in
§ 63.344(c), and shall establish as the
site-specific operating parameter the
" thickness of the foam blanket, setting
the minimum thickness that
corresponds to compliance with the
applicable emission limitation. In lieu
of-establishing the minimum foam
blanket thickness during the : ;
performance test, the owner or operator
may accept 2.54 centimeters (1 inch) as
the minimum foam blanket thickness
that corresponds to compliance with the
applicable emission limitation. All foam
blanket measurements must be taken in
close proximity to the workpiece or
cathode area in the plating tank(s).
(ii) On and after the date on which the
initial performance test is required to be
completed under § 63.7, the owner or
operator of an affected source shall
monitor the foam blanket thickness of
the electroplating or anodizing bath.
Operation of the affected source at a
foam blanket thickness less than the
value established during the
performance test, or less than 2.54 cm ,
(1 inch) if the owner or operator is using
this value in accordance with paragraph
(c)(6)(i) of this section, shall constitute
noncomph'ance with the standards. The .
foam blanket thickness shall be
measured according to the following
schedule:
(A) The foam blanket thickness shall
be measured once every 1 hour of tank
operation.
(B) The time between monitoring can
be increased if there have been no
exceedances. The foam blanket
thickness shall be measured once every
hour of tank operation for the first 40
hours of tank operation after the
compliance date. Once there are no
exceedances for 40 hours of tank
operation, foam blanket thickness
measurement may be conducted once
- every .4 hours of tank operation. Once
there are no exceedances during 40
hours of tank operation, foam blanket
thickness measurement may be
conducted once every 8 hours of tank
operation on an ongoing basis, until an
exceedance occurs. The minimum
frequency of monitoring allowed by this
• subpart is once per 8 hours of tank
operation.
(C) Once an exceedance occurs as
indicated through foam blanket
thickness monitoring, the original
monitoring schedule of once every hour
must be resumed. A subsequent
decrease in frequency shall follow the
schedule laid out in paragraph
(c)(6)(ii)(B) of this section. For example,
if an owner or operator had been
monitoring an affected source once
even1 8 hours and an exceedance
occurs, subsequent monitoring would
take place once every hour of tank.
operation. Once an exceedance does not
occur for 40 hours of tank operation,.
monitoring can occur once every 4
hours of tank operation. Once an
.exceedance does not occur for 40 hours.
of tank operation on this schedule.
monitoring can occur once every 8
.hours of tank operation.
(iii) Once a bath solution is drained
from the affected tank and a new
solution added, the original monitoring
schedule of once every hour must be
resumed, with a decrease in monitoring
frequency allowed following the
procedures of paragraphs (c)(6)(ii) (B)
and (C) of this section. •'• -' •'
(7) Fume suppressant/add-on control
device, (i) If the owner or operator of an
affected source uses both a fume
suppressant and add-on control device
and both are needed to comply with the
applicable emission limit, monitoring
requirements as identified in paragraphs
(c) (1) through (6) of this section, and
the work practice standards of Table 1
of § 63.342, apply for each of the control
techniques used.
(ii) If the owner or operator of an
affected source uses both a fume
suppressant and add-on control device,
but only one of these techniques is
needed to comply with the applicable
emission limit, monitoring requirements
as identified in paragraphs (c) (1)
through (6) of this section, and work'
practice standards of Table 1 of
§ 63.342. apply only for the control
technique used to achieve compliance
(8) Use of an alternative monitoring
method, (i) Requests and approvals of
alternative monitoring methods shall ho
considered in accordance with
$ 63.8MU (f)(3). (0(4). and (f)(5).
(ii) After receipt and consideration of
an application for an alternative
monitoring method, the Administrate!
may app-ove sllemalives to anv
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'4970 -"-Federal -Register Y.^Vol.1 ^SOi' No-:--36 /-Wednesday,-January 25,' 1995 /-Rules'and 'Regulations'
monitoring methods or procedures of
this subpart including, but not limited
to, the'following:
(A) Alternative monitoring
requirements when installation or-use of
monitoring devices specified in.this
subpart would not provide accurate
•measurements due to interferences
caused by substances within the effluent
gases; or ' • " ~ " •
(B) Alternative locations for installing
monitoring devices when the owner or
operator can demonstrate that "•*": •
installation at alternate locations will
enable accurate and representative
-.measurements.. •.. ;- ..
(d) An owner or operator who uses an
air pollution control device not listed in
this section shall submit a description of
the device, test results collected in
accordance with § 63.344(c) verifying
the performance of the device for
reducing chromium emissions to the
atmosphere to the level required by this
subpart, a copy of the operation and
maintenance plan referenced in
§63.342(f) including proposed work
practice standards, and appropriate
operating parameters that will be
monitored to establish continuous
compliance with the standards. The
monitoring plan submitted identifying
the continuous compliance monitoring
is subject to the Administrator's
approval.
- § 63.344 . Performance test requirements
and test methods. ; . •--..-- *-.-•
(a) Performance test requirements,
Performance tests shall be conducted
using the test methods and procedures
in this section and § 63.7. Performance
test results shall be documented in
complete test reports that contain the
information required by paragraphs
(a)(l) through (a)(9) of this section, the
test plan to be followed shall be made
available to'the Administrator prior to
the testing, if requested. •_;
(1) A brief process description;
(2) Sampling location description(s);
(3) A description of sampling and
analytical procedures and any ••;"-;
modifications to standard procedures;
. : (4) Test results; ...... ..... . V- ...- • :
(5) Quality assurance procedures and
.results; •• - . ", •-.--
(6) Records of operating conditions
during the test, preparation of
standards, and calibration procedures;
(7) Raw data sheets for field sampling
and field and laboratory analyses;
(8) Documentation of.calculations;
and ; •
(9) Any other information required by
the test method.
- (b)(l) If-the owner or-operator of an. . ,
affected source conducts" performance -:"
testing at startup to obtain an "operating
•permit in the State in which the affected
-source is located, the results of such
testing may be used to demonstrate
compliance with this subpart if:
. (i) The test methods and procedures
identified iri paragraph (c) of this
section were used during the
performance test;
: (ii) The performance test was •"
conducted under representative
operating conditions for the source;
(iii) The performance test report
contains the elements required by
paragraph (a) of this section; and
(iv) The owner or operator of the
affected source for which the .
performance test was conducted has
sufficient data to establish the operating
parameter value(s) that correspond to
compliance with the standards, as
required for continuous compliance
monitoring under § 63.343(c).
(2) The results of tests conducted
prior to December 1991 in which
Method 306A, appendix A of this part,
was used to demonstrate the
performance of a control technique are
not acceptable.
(c) Test methods. Each owner or
operator subject to the provisions of this
• subpart and required by § 63.343 (b) to
conduct an initial performance test shall
use the test methods identified in this
section to demonstrate compliance with
the standards in § 63.342..
(1) Method 306 or Method 306A.
"Determination of Chromium Emissions
From Decorative and Hard Chromium
Electroplating and Anodizing
Operations," appendix A of this part
shall be used to determine the
chromium concentration from hard or
decorative chromium electroplating
tanks or chromium anodizing tanks. The
sampling time and sample volume for
each run of Methods 306 and 306A,
appendix A of this part shall be at least
120 minutes and 1.70 dscm (60 dsci],
respectively. Methods 306 and 306A,
appendix A of this part allow the
measurement of either total chromium
or hexayalent chromium emissions. For
the purposes of this standard, sources
using chromic acid baths can .
demonstrate compliance with the
emission limits of § 63.342 by -..-.-
.measuring either total chromium or
hexavalent chromium. Hence, the
hexavalent chromium concentration
measured by these methods is equal to
the total chromium concentration for
the affected operations;
(2) The California Air Resources
Board (CARS) Method 425 (which is
.available by contacting the California
Air Resources Board, 1102 Q Street,
• Sacramento, California 95814) may be
•'used to determine the chromium
• concentration from hard and decorative
chromium electroplating tanks and
chromium anodizing tanks if the
following conditions are met:
(i) If a colorimetric analysis method is
used, the sampling time and volume
shall be sufficient to result in 33 to 66
micrograms of catch in the sampling
train.
(ii) If Atomic Absorption Graphite
Furnace (AAGF) or Ion Chromatography
with a Post-column Reactor (ICPCR)
analyses were used, the sampling time
and volume should be"sufficient to
result in a sample catch that is 5 to 10
times the minimum detection limit of
.. the analytical method (i.e., 1.0
microgram per liter of sample for AAGF
and 0.5 microgram. per liter of sample
for ICPCR);
(iii) In the case of either paragraph
(c)(2) (i) or (ii) of this section, a
minimum of 3 separate runs must be
conducted. The other requirements of
§ 63.7 that apply to affected sources, as
indicated in Table 1 of this subpart, . -
must also be met. • "-
(3) Method 306B, "Surface Tension
Measurement and Recordkeeping for
Tanks Used at Decorative Chromium'
Electroplating and Anodizing • • "" • •
Facilities," appendix A of this part shall
be used to measure the surface tension
of electroplating and anodizing baths. . -.
(4) Alternate test methods may also be
used if the method has been validated
using Method 301, appendix A of this
part and if approved by the ' --'-'"
Administrator. Procedures for' ' " ' '_'''
requesting and obtaining approval are "
contained in §63.7(f).
(d) Establishing site-specific operating
parameter values. (1) Each owner or
. operator required to'establish site- •
specific operating parameters'shall ••-
follow the procedures in this section. •'
'(2) All monitoring equipment shall be
installed such that representative
measurements of emissions or process
parameters from the affected source are
obtained. For monitoring equipment
purchased from a vendor, verification of
the operational status of the monitoring'
equipment shall include execution of
the manufacturer's written
specifications or recommendations for
installation, operation, and califaratio'n
of the system. ' "'' ' " ; "'"
(i) Specifications for differential
pressure measurement devices used to
measure velocity pressure shall be. in
accordance with section 2.2 of Method
2 (40 CFR part 60. appendix A).
(ii) Specification tor differential
pressure measurement devices used to
measure pressure drop across a control-
system shall be in accordance with
manufacturer's accuracy specifications.
(3) The surface tension of "
electroplating and anodizing baths shall'
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Federal Register /-Vol. 60, No- 16./.-Wednesday, January 25, 1995 / Rules.and Regulations 4971
be measured using Method 306B,
"Surface Tension Measurement and
Recordkeeping for Tanks used at
Decorative Chromium Electroplating
and Anodizing Facilities," appendix A
of this part. This method should also be
followed when'wetting agent type or
combination wetting agent/foam blanket
type fume suppressants are used to
control chromium emissions from a
' hard chromium electroplating tank and
surface tension measurement is
conducted to demonstrate continuous
compliance.
. (4) The owner or operator of a source
required to measure the velocity
pressure at the inlet to an add:ori air
pollutio'n control device in accordance
with § 63.343(c)(2). shall establish the
site-specific velocity pressure as
follows:
(i) Locate a velocity traverse port in a
section of straight duct that connects the
hooding on the plating tank or tanks
with the control device. The port shall
be located as close to the control system
as possible, and shall be placed a
minimum of 2 duct diameters
downstream and 0.5 diameter upstream
of any flow disturbance such as a bend.
expansion, or contraction (see Method
1, 40 CFR part 60. appendix A). If 2.5
diameters x>f straight duct work does not
exist, locate the port 0.8 of the duct
diameter downstream and 0.2 of the
duct diameter upstream from any flow
disturbance.
(ii) A 12-point velocity traverse of the
duct to the control device shall be
conducted along a single axis according
to Method 2 (40 CFR part 60. appendix
A) using an S-type pilot tube;
measurement of the barometric pressure
and duct temperature at each traverse
point is not required, but is suggested.
Mark the S-type pilot tube as specified
in Method 1 (40 CFR part 60, appendix
A) with 12 points. Measure the velocity
pressure (Ap) values for the velocity
points and record. Determine the square
root of the individual velocity point Ap
values and average. The point with the
square root value that comes closest to
the average square root value is the
point of average velocity. The Ap value
measured for this point during the
. performance test will be used as the
reference for future mor-.itoring.
(5) The owner or operator of a source
required to measure the pressure drop
across the add-on air pollution control
device in accordance with § 63.343(c)
(1) through (4) may establish the
pressure drop in accordance with the
following guidelines:
(i) Pressure taps shall be installed at
any of the following locations:
(A) At the inlet and outlet of the
control system. The inlet tap should be
installed in the ductwork just prior to
the control device and the
corresponding outlet pressure tap
should be installed on the outlet side of
the control device prior to the blower or
on the downstream side of the blower;
(B) On each side of the packed bed
within the control system or on each
side of each mesh pad within the
control system; or
(C) On the front side of the first mesh
pad and back side of the last mesh pad
within the control system.
(ii) Pressure taps shall be sited st
locations that are:
(A) Free from pluggage as possible
and away from any flow disturbances
such as cyclonic demisters. .
(B) Situated such that no air
infiltration at measurement site will
occur that could bias the measurement.
{iii) Pressure taps shall be constructed
of either polyethylene, polybutylene, or
other nonreactive materials.
(iv) Nonreactive plastic tubing shall
be used to connect the pressure taps to
the device used to measure pressure
drop.
(v) Any of the following pressure
gauges can be used to monitor pressure
drop: a magnehelic gauge, an inclined.
manometer, or a "U" tube manometer.
(vi) Prior to connecting any pressure
lines to the pressure gauge(s), each
gauge should be zeroed. No calibration
of the pressure gauges is required.
(e) Special compliance provisions for
multiple sources controlled by a
common add-on air pollution control
device.
(1) This section identifies procedures
for measuring the outlet chromium
concentration from an add-on air
pollution control device that is used to
control multiple sources that may or
may not include sources not affected by
this subpart.
(2) When multiple affected sources
performing-the same type of operation
(e.g., all are performing hard chromium
electroplating), and subject to the same
emission limitation, are controlled wit])
an add-on air pollution control device
that is not controlling emissions from
any other type of affected operation or
from any nonaffected sources, the
applicable emission limitation
identified in § 63.342 must be met at th
outlet of the add-on air pollution contr
device.
(3) When multiple affected sources »
performing the same type of operation
and subject to the same emission
limitation are controlled with a commctj
add-on air pollution control device thai
is also controlling emissions from
sources not affected by these standards,;
the following procedures should be
followed to determine compliance with
the applicable emission limitation in
§63.342:
(i) Calculate the cross-sectional area of
each inlet duct (i.e., uptakes from each
hood) including those not affected by
the standard.
(ii) Determine the total sample lime
per test run by dividing the total iniel
area from all tanks connected to the
control system by the total inlet area for
all ducts associated with affected
sources; and then multiply this number
by 2 hours. The calculated time is the
minimum sample time required per lesr
run.
(iii) Perform Method 306 testing and
calculate an outlet mass emission rate.
(iv) Determine the total ventilation
rate from the affected sources bv usine
equation 1:
IDA..
.(IV
where VR,o, is the average total
ventilation rate in dscm/min for the
three test runs as determined at the
outlet by means of the Method 306
testing; ID A; is the total inlet area for all
ducts associated with affected sources,
lAiouj is the sum of all inlet duct areas
from both affected and nonaffeded
sources; and VRinle, is the total
ventilation rate from all inlet ducts
associated with affected sources.
(v) Establish the allowable mass
emission rate of the system (AMR^J in
milligrams of total chromium per hour
(mg/hr) using equation 2:
„ VRinJci x EL x 60minutes/hours = AMRSVS
(2)
where I VRmlei is the total ventilation
rate in dscm/min from the affected
sources, and EL is the applicable
emission limitation from § 63.342 in
rng/dscm. The allowable mass emission
rate (AMR,yJ calculated from equation 2
should be equal to or less .than'the outlel
three-run average mass emission rale
determined from Method 306 testing in
order for the source to be in compliance
with the standard.
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4972 Federal Reg&er / Vol.. 60. No. 16 / Wednesday. lanuary "25.-199S./..Rules and Regulations
(4). When multiple affected sources
performing different types of- operations
(e.g-»hard chromium electroplating.
decorative chromiumelectroplatingvor
chromium anodizing} are controlled: by
a common add-on air pollution control
device that may or may not also be
controlling emissions-from sources not
affected by these standards, or rf the
affected sources controlled by the
common add-on air pollution control
device perform the same operation but
are subject to different emission
limitations (e.g^. because one is a new
hard chromium, plating tank and one is
an existing small,hard chromium
plating tank), the folio-wing:procedures
should be followed to-determine
compliance with, the.applicable
emission limitation in § 63.342:
(i) Follow thesteps outlined in
paragraphs (e)(3)(i) through (e)(3)(iu) of
this section.
(ii) Determine the total ventilation
rate for each type of affected source
using equation 3:
IDA;.
-=VR.
inlet.a
(3).
where VRu* is the average total
ventilation rate in dscm/min for the
three test runs as determined at the
outlet by means of the Method 306
testing: IDA;., is the total'Inlet duct area
for all ducts conveying,chromic acid
from each type of affected source
performing the same operation, or. each
type of affected source subject to the
same emission limitation; IA,olj is the
sum of all duct areas from both affected
and nonaffected sources: and VR,nie,.3 is
the tola'ventilation rate from alli'nlet
ducts conveying chromic acid from each
type of affected source performing the
same operation,, or each type of affected
source subject to the same emission
limitation.
(iii) Establish the allowable mass
emission rate in mg/hr for each type of
affected.sou'rce that is controlled by the
add-on air pollution control device
using equation 4, 5, 6. or 7 as-
appropriate:
VRhc, x ELhcuX 60 minutes/hour. =
AMRhd. (4)
\"Rtw: x ELhc; x 60-minutes/hour =
AMRiK2 (5)
VRoc x ELoc x 60 minutes/hour = AMRjc
(6)
VTVM x EU-j x 60 minutes/hour = AMR.-.,
(7)
where "he" applies to the total of
ventilation rates for all hard chromium
electroplating taaks.sabjecttn the same
emission Iimitation^""dc'' applies to the
total of ventilation rates for the.
decorative chromium electroplating
tanks, "ca" applies-to the total of.. .
ventilation rates for the diroirunm-
anodiring tanks, and EL is-the
applicable emission-. Limitation from
§ 63.342 in rag/dscm. There are-two-
equations for hard chromium.
electroplating tanks because different
emission limitations may apply (e.g-.,a
new tank versus an existing, smafl tank).
(iv) Establish the allowable mass
emission rate (AMRJ in. mg/hr for the
system using equation 8, intruding.each
type of affected source as appropriate.
AMRhcr + AMR^ + AMJ^c -f AMRc* =
AMR^, (8)
The allowable mass emission- rate
calculated from equation 8 should be
equal to or less than the outlet three-run
average mass emission rate determined
from Method 306'testing in order for the
source to be in compliance with the
standards.
(5) Each owner or operator that uses
the special compliance provisions of
this paragraph to-demonstrate
compliance with the emission
limitations of §"6-3-342 shall'submit the
measurements and calculations to
support these compliance methods- with •
the notification of compliance status
required by §63.347(e).
(6) Each owner or operator that uses
the special compliance provisions of
this section to demonstrate compliance
u-ith the emission limitations of
§ 63.342 shall repeat these procedures if
a tank is added or removed from the
control system regardless of whether
that tank is a nonaffected source. If. the
new nonaffected tank replaces an
existing nonaffected'tank of the same
size and is connected1 to the control
systemjjirough the same size inlet duct
then this procedure does not have to be
repeated.
§ 63.345 Provisions for new and
reconstructed sources.
(a) This section identifies the-
preconstruction review requirements for
new and reconstructed affected sources
that are-subject to. or becomesufaject to.
this subpart..
(b) New or reconstructed affected
sources. The owner or operator of a new-
er reconstructed affected source is
subject to § 63.5(a). fb)flT. (b)(5). (b)(6).
and (f)(1), as well as the provisions of
this paragraph.
(1) After January 25.1995, whether or
not an approved permit program is
effective in the State in which an.
affected source is (or would be) located.
no person may construct a new affected
source or reconstruct an affected source
subject to this subpart, or reconstruct a-
source such that it becomes-an affected
source subject to this-subpart^ without
submitting.! notification-of coristructioa
or reconstruction tathe Administrator.
The notificatioc-shall contain, the-
information identified in,paragraphs (b)-
(2) and (3) of this section, as
appropriate.
(2) The notification of construction or
reconstruction required undec
paragraph (h)(l J-of this section shal 1
include:
(i) The owner or operator's name.
title, and address;
(ii) The address (Le.. physical
location), or proposed address of the
affected source if different from the
owner's or operator's;
(ifi-T A notification of intention to
construct a new affected source or make
any physical or operational changes to
an affected source that may meet or has
been determined to meet the criteria for
a reconstruction as defined in-§63.2;
(iv) An identification of subpart Mof
this part as the basis for the notification:
(v).The expected commencement and
completion dates of the construction or
reconstruction;
(vi) The anticipated date.of (initial)
startup of the affected source;
(vii) The type of process operation to
be performed (hard or decorative ' ;
chromium electroplating7or chromium
.anodizing);
(viii) A description of the air '
pollution control technique to be used
to control emissions from the affected
source.such as preliminary design
drawings and design capacity if an add-
on ah-pollution control device is used:
and
(ix) An estimate of emissions from the
source'based on engineering
calculations and-vendor information on
control device efficiency, expressed in
units consistent with the emission-
limits of, this subpart. Calculations of
emission estimates should be in
sufficient detail to permit assessment of
the validity of the calculations;
(3) If a reconstruction is to occur, the
notification required under paragraph
(b)(l)-of this section shall-include the
following in addition to the information
required in paragraph (b)(2) of this
section:
(i) A brief descriptionjof the affected
source and the components to be
replaced;.
(ii) A brief description of the present
and proposed emission control
technique, including the information
required by paragraphs (b)(2) (viii) and
(ix) of this section:
(iii) An estimate of the fixed capital
cost of the replacements and of
constructing a comparable entirely new
source:
(\vf The estimated lifeof theaffected-
source after the replacements: and
(v) A discussion- of any ecxmomicot
technical limitations- tbe source may •
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Federal Register / Vol. 60, No. 16-/ Wednesday. January 25, 1995 / Rules and-Regulations
have in complying with relevant
standards or other requirements after
the proposed replacements. The
discussion shall be sufficiently detailed
to demonstrate to the Administrator's
satisfaction that the technical or
economic limitations affect the source's
ability to comply with the relevant
standard and hoxv they do so.
.(vi) If in the notification of -
reconstruction, the owner or operator
designates the affected source as a
reconstructed source and declares that
there are no economic or technical
limitations to prevent the source from
complying with all relevant standards or
requirements, the owner or operator
need not submit the information
required in paragraphs (b)(3) (iii)
through (v) of this section.
(4) The owner or operator of a new or
reconstructed affected source that "
submits a notification in accordance
with paragraphs (b) (1) through (3) of
this section is not subject to approval by
the Administrator. Construction or
reconstruction is subject only to
notification and can begin upon
submission of.a complete notification.
(5) Submittal timeframes. After
January 25,1995, whether or not an
approved permit program is effective in
the State in which an affected source is
(or would be) located, an owner or
operator of a new or reconstructed
affected source shall submit the
notification of construction or
reconstruction required by paragraph
(b)(l) of this section according to the
following schedule:
(i) If construction or reconstruction
commences after January 25,1995, the
notification shall be submitted as soon
as practicable before the construction or
reconstruction is planned to commence.
(ii) If the construction or
. reconstruction had commenced and
initial startup had not occurred before
January 25,1995, the notification shall
be submitted as soon as practicable
before startup but no later than 60 days
after January 25,1995.
§ 63.346 Recordkeeping requirements.
(a) The owner or operator of each
affected source subject to these
standard* shall fulfill all recordkeeping
requirements outlined in this section
and in the General Provisions to 40 CFR
part 63, according to the applicability of
subpart A of this part as identified in
Table 1 of this subpart.
(b) The owner or operator of an
affected source subject to the provisions
of this subpart shall maintain the
following records for such source:
(1) Inspection records for the add-on
air pollution control device, if such a
device is used, and monitoring
equipment, to document that the
inspection and maintenance required by
the work practice standards of
§ 63.342(f) and Table 1 of § 63.342 have
taken place. The record can take the
form of a checklist and should identify
the device inspected, the date of
inspection, a brief description of the
working condition of the device during
the inspection, and any actions taken to
correct deficiencies found during the
inspection.
(2) Records of all maintenance
performed on the-affected source, the
add-on air pollution control device, and
monitoring equipment;
(3) Records of the occurrence,
duration, and cause (if known) of each
malfunction of process, add-on air
pollution control, and monitoring
equipment;
(4]tRecords of actions taken during
periods of malfunction when such
actions are inconsistent with the
operation and maintenance plan;
(5) Other records, which may take the
form of checklists, necessary to
demonstrate consistency with the
provisions of the operation and
maintenance plan required by
§63.342(f)(3);
(6) Test reports documenting results
of all performance tests;
(7) All measurements as may be
necessary to determine the conditions of.
performance tests, including
measurements necessary to determine •
compliance with the special compliance
procedures of § 63.344(e):
(8) Records of monitoring data
required by § 63.343(c) that are used to
demonstrate compliance with the
standard including the date and time
the data are collected;
(9) The specific identification (i.e., the
date and time of commencement and
completion) of each period of excess
emissions, as indicated by monitoring
data, that occurs during malfunction of
the process, add-on air pollution
control, or monitoring equipment;
(10) The specific identification (i.e.,
the date and time of commencement
and completion) of each period of
excess emissions, as indicated by
monitoring data, that occurs during
periods other than malfunction of the
process, add-on air pollution control, or
monitoring equipment;
(11) The total process operating time
of the affected source during the
reporting period;
(12) Records of the actual cumulative
rectifier capacity of hard chromium
electroplating tanks at a facility
expended during each month of the
reporting period, and the total capacity
expended to date for a reporting period,
if the owner or operator is using the
actual cumulative rectifier capacity!
determine facility size in accordant!
with §63.342(c)(2);
(13) For sources using fume
suppressants to comply with the
standards, records of the date and tii»
that fume suppressants are added to |
electroplating or anodizing bath;
(14) For sources complying with '
§ 63.342(e), records of the bath
components purchased, with the
wetting agent clearly identified as a bal
constituent contained in one of the
components;
(15) Any information demonstratiij
whether a source is meeting the '
requirements for a waiver of
recordkeeping or reporting
requirements, if the source has been
granted a waiver under § 63.10(f); ani
(16) All documentation supporting
the notifications and reports required b
§ 63.9, § 63.10, and § 63.347.
(c) All records shall be maintainedijq
a period of 5 years in accordance wit]} I
§63.10(b)(l).
§ 63.347 • Reporting requirements.
(a) The owner or operator of each
. affected source subject to these
standards shall fulfill all reporting
requirements outlined in this section
and in the General Provisions to 40 CH
part 63, according to the applicability^!
subpart A as identified in'Table 1 of till
subpart. These reports'shall be made til
the Administrator at the appropriate -'
address as identified in § 63.13 or to tta
'delegated State authority.
(1) Reports required by subpart A of"
this part and this section may be sent |j|
U.S. mail, fax, or by another courier.
(i) Submittals sent by U.S. mail shall
be postmarked on or before the specilfi
date.
(ii) Submittals sent by other methods n
shall be received by the Administrator
on or before the specified date.
(2) If acceptable to both the
Administrator and the owner or
operator of an affected source, reports
may be submitted on electronic media.;
(b) The reporting requirements of this
section apply to the owner or operator!
of an affected source when such sourc|
becomes subject to the provisions of iSs
subpart.
(c) Initial notifications. (1) The owner
or operator of an affected source that his
an initial startup before January 25,
1995, shall notify the Administrator in
writing that the source is subject to this
subpart. The notification shall be
submitted no later than 180'talendar
days after January 25.1995, and shall
contain the following information:
(i) The name, title, and address of th$
owner or operator; ''
(ii) The address (i.e., physics!
location) of each affected source;
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4974 Federal Register / Vot. 60. No. 16 / Wednesday. January 25. 199s / Rules and Regulations
(Lii) A statement that subpart N of this
part is the basis for this notification:
(iv) Identification of the applicable
emission limitation and compliance
date for each affected- source;
[y] A brief description; of each, affected
source, including the type of process
operation performed;.
(vi) For sources performing hard
chromium electroplating, the maximum
potential cumulative potential1 rectifier
capacity;
(vii) For sources performing hard
chromium electroplating, a statement of
whether the affected sourcefs) is located
at a small or a large, hard chromium
electroplating facility and whether this
will be demonstrated through actual or
maximum potential cumulative rectifier
capacity;
(viii) For sources performing hard
chromium electroplating tanks, a
statement of whether the owner or
operator of an affected source(sj will
limit the maximum potential
cumulative rectifier capacity in
accordance with §63.342(4(2^ such that
the hard chromium electroplating
facility is considered small; and
(i.x) A statement of whether the
affected source is located at a major
source or an area source as defined in
§63.2.
(2) The owner or operator of a new or
reconstructed affected source that has
an initial startup after January 25.1995
shall submit an initial notification, (in
addition to the notification of
construction or reconstruction, required
by § 63.345(b).as follows:
(i) A notification of the date when
construction or reconstruction was
commenced, shall be submitted
simultaneously with the notification of
construction or reconstruction, if
construction or reconstruction was
commenced before January 25, 1995;
(ii) A notification of the date when
construction orreconstruction was
commenced, shall be submitted no later
than. 30 calendar days after such date, if
construction or reconstruction was
commenced after January 25.1995; and
(iii) A notification of the actual date
of startup of the source shall be
submitted within 30 calendar, days after
such date.
(d) Notification of performance test.
(1) The owner or operator of an. affected
source shall notify the Administrator in
writing of his or her intention, to
conduct a performance test at least 60
calendar days before the test is
scheduled to begin to. allow the
Administrator tanave an observer
present curing the test. Observation of
the performance test by the
Administrator is optional
(2) In the event the owner or opera tor
is unable to conduct the- performance
test as scheduled, the provisions of
§63.7(b)(2l apply.
(e) Notification of compliance status-
(1) A notification, of compliance status
is required each time that an affected
source becomes subject to- the
requirements of this subpart.
(2) Before a title V permit has been
issued to the owner or operator of an
affected source, each time a notification
of compliance status is required under
this part, the owner or operator of an
affected source shall submit to the
Administrator a notification of
compliance status, signed by the
responsible official (as defined in §63.21
who shall certify its accuracy. attesting.
to whether the affected source has
complied with this subpart. After a title
V permit has been issued to the owner
or operator of an affected source, the
notification of compliance status shall
be submitted to the appropriate
permitting authority. The notification
shall list for each affected sources
(i) The applicable emission limitation
and the methods that were used to
determine compliance with this
limitation;
(iif If a performance test is required by
this subpart, the test report
documenting the results-of the
performance test, which, contains the
elements required by §63_344(a).
including measurements and
calculations to support the special
compliance provisions of §63.344(er if
these are being followed:
(iii)The type and quantityof
hazardous air pollutants emitted by the
source reported in mg/dscm or rrig/hx if
the source is using the-special
provisions of §63.344(e) to comply with
the standards. (If the owner or operator
is subject to the construction; and.
reconstruction provisions of §63-345
and had previously submitted emission
estimates, the owner or operator shall
state that this report corrects or verifies
the previous estimate.) For sources not
required to conduct a performance- test
in accordance- with. § 63>343(b)v the
surface tension- measurement may fulfill
this requirement;
(iv) For each monitored parameter for
which a compliant value-is to be
established under §63-343(c), the
specific operating parameter value, or
range of values^ that corresponds, to
compliance with the applicable
emission; limit;
(v) The methods that will be used to
determine continuous compliance,
including a description o£monitoring:
and reporting: requirements-, if methods
di ffer from those identified m this
subpart;
(vi) A description- of the air pollution
control technique for each emission
point:
(vii) A statement that the owner or
operator has completed and has on file
the operation and maintenance pianas
required by the work practice standards
in § 63.342(f)r
(viii) If the owner or operator is
determining facility size based on actual
cumulative rectifier capacity in
accordance with § 63.342(c)(2). records
to support that the facility issmalL For
existing sources, records from any 12-
month period preceding.the compliance
date shall be used or a description-of
how operations will change to meet a
small designation shall be provided. For
new sources, records of projected
rectifier capacity for the first 12-month
period of tank operation shall be used;
(ix) A statement by the owner or
operator of the affected source as to
whether the source has complied with
the provisions of this subpart.
(3) For sources required to conduct a
performance test by §63.3-i3(b). the
notification of compliance status shall
be submitted to the Administrator no
later than. 90 calendar days following
completion of the compliance
demonstration required by §63.7 and
§63.343(b).
(4) FOE sources that are not. required
to complete a performance test in
accordance with, § 63.343 (b). the
notification of compliance statusshall
be submitted to the Administrator no
later than 30 days after the compliance
date specified in §63.343(a)-
(f) Reports of performance test resu/ls.
(1) Before a. title V permit has been
issued to. the owner or operator of an
affected source, the owner or operator
shall report to-the Administrator the
results of any performance test
conducted as required by § 6-3.7 or
§ 63.343(b). After a title V permit has
been issued to the owner or operatorof
an affected source, theowner or
operator should report performance test
results to the appropriate permitting
authority.
(2) Reports of performance test results
shall be submitted no later than 90" days
following the completion of the
performance test, and shall be submitted
as part of the notification of compliance
status* required by paragraph- (e)- of this
section.
(g) Ongoing compliance status reports.
for major sources. (1) The owner or
operator of an affected source that is
located at a major source site shall'
submit a summary report to the
Administrator to document the ongoing-
compliance status of the affected source.
The report shall contain, the information
identified in paragraph (gj(3) of this
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Federal Register A Vol. 60, No. 16 / Wednesday, January 25, 1395 / Rules and Regulations
49/
section, and shall be submitted
semiannually except when:
(i) The Administrator determines on a
case-by-case basis that more- frequent
reporting is necessary to accurately
assess the compliance status of the
source; or
(ii) The monitoring'data collected fay
the owner or operator of the affected
source in accordance with § S3.343f.cJ
show that the emission limit has been.
exceeded, in. which case quarterly
report shall be submitted. Once an
owner or operator of an affected source
reports an exceedance, ongoing
compliance status reports shall be
submitted quarterly until a request to
reduce'reporting frequency under
paragraph (g](2) of this section is
approved.
|2) Request to reduce frequency of
ongoing compliance status reports, (i)
An owner or operator who is required
to submit ongoing compliance status
reports on a quarterly (or more frequent
basis) may reduce the frequency of
reporting to semiannual if all of the
following conditions are met:
(A) For 1 full year (e.g., 4 quarterly or
12 monthly reporting periods}, the
ongoing compliance status reports .
demonstrate that the affected source is
in compliance with the relevant
emission limit;
(B) The owner or operator continues
to comply with a!! applicable . .
recordkeepine and monitoring
requirements of subpart A of this part
and this subpart; and
'(C}The Administrator does not object
to a reduced reporting frequency for the
affected source, as provided in
paragraphs (g)|2) (ii) and (Hi) of this
section.
(ii) The frequency of submitting
ongoing compliance status reports may
be reduced only after the owaeror
operator notifies the Administrator in
writing of his or her intention to make
such a change, and the Administrator
does not object to the intended change.
In deciding whether to approve a
reduced reporting frequency, the
Administrator may review information
concerning the source's entire previous
performance history during the 5-year
recordkeeping period prior to the
intended change, or the recordkeeping
period since the source's compliance
date, whichever is shorter. Records
subject to review may include
performance test results, monitoring '
data, and evaluations of an owner or
operator's conformance with emission
limitations and work practice standards.
Such information may be used fay the
Administrator to make a judgment about
the source's potential for
• noncompliance in the future. If the
Administrator disapproves the owner ci
operator's request to reduce reporting
frequency, the Administrator will notify
the owner or operator in writing within
45 days after receiving notice of the
owner or operator's intention. The
notification from the' Administrator to
the owner or operator will specify the
grounds OB which the disapproval is
based. In the absence of a notice of
disapproval within 45 days, approval is
automatically granted.
[ii)} As soon as the monitoring data
required by §63.343(c) show that the
source is not in compliance with the
re levant, emission limit the frequency of
reporting shall revert to quarterly, and
the owner shall state this exceedance in
the ongoing compliance status report for
the next reporting period. After
demonstrating ongoing compliance with
the relevant emission Kmit for another
full year, the owner or operator may
again request approval from the
Administrator to reduce the reporting
frequency as allowed by paragraph (gj(2)
of this section. •
(3) Contents of ongoing compliance
statvs reports. The oxvner or operator of
an affected source for which compliance
monitoring is.required in accordance
with §63.343(c) shall prepare a
summary report to document the
ongoing compliance status of the source.
The report must contain the following
information:
(i) The company name and address of
the affected source;
(ii) An identification of the operating
parameter that is monitored for .
compliance determination, as required
by § 63.343(c):
(iii) The relevant emission limitation
for the affected source, and the
operating parameter value, or range of
values, that correspond to compliance
with this emission limitation as
specified in the notification of
compliance status required by
paragraph (e) of this section;
(ivj Toe beginning and ending dates
of the reporting period;
(v) A description of the type of
process performed in the affected
source;
(vi) The total operating time of the
affected source during the reporting
period;
(vii) If the affected source is a hard
chromium electroplating tank and the
owner or operator is limiting the
maximum cumulative rectifier capacity
in accordance with § 63.342(c)(2), the
actual cumulative rectifier capacity
expended during the reporting period,
on a month-by-month basis;
(viii) A summary of operating
parameter values, including the total
•duration of excess emissions during the
reporting period as indicated by those
values,the total duration of excess
emissions expressed as a percent of tii
total source operating time during thai
reporting period, andVoreakdon-n of
.the total-duration of excess emissions
during ihereporting.period into those
that are due to process upsets, control
equipment malfunctions, other known
causes, and unknown causes;
(Lx) A certification by a responsib?*
official, as defined in §63.2, that tee
work practice standards in 5 63.3-}2(f)
were followed in accordance with the
.operation and maintenance plan for the
source;
(x) if the operation and maintenance
plan required by § 63.342(f)(3) was cot
followed, an explanation of the reasons
for no* following the provisions, an
assessment of whether any excess
emission and/or parameter monitoring
exceedances are believed to have
occurred, and a copy of the report(s)
required by §63.342(f)(3)(iv)
documenting that the operation and
maintenance plan was not followed;
(xi) A description of any changes in
monitoring, processes, or controls since
the fast reporting period;
(xii) The name, title, and signature of
the responsible official who is certifying
the accuracy of the report: and
(xiii) The dale of the report.
(4) When more than one monitoring
device is used to comply with the
continuous compliance monitoring
required by § 63.343(c). the owner or
operator shall report the results as
required for each monitoring device.
However, when one monitoring device
is used as a backup for the primary
monitoring device, the owner or
operator shall only report the results
from the monitoring device used to meet
the monitoring requirements of this
subpart. If both devices are used to meet
these requirements, then the owner or
operator shall report the results from
each monitoring device for the relevant
compliance period.
(hj Ongoing compliance states repasts
for area sources. The requirements of
this paragraph do not alleviate affected
area sources from complying with the
requirements of State or Federal
• operating permit programs under 40
CFRpart?!.
(l}Tfceowner or operatorof an
affected source that is located at an area
source site shall prepare a summary
•report to document the ongoing
compliance status of the affected source.
The report shall contain the information
identified in paragraph (gj[3) of this
section, shall be completed annually
and retained on site, and made available
to the Administrator upon.request. Tb-*
report shall be completed annually
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4976 Federal Register / Vol. 60, No. 16 / Wednesday, January 25. 1995 / Rules and Regulations
except as provided in paragraph (hl(2)
of this section.
(2) Reports of exceedcnces. (i) If both
of the following conditions are met,
semiannual reports shall be prepared
and submitted to the Administrator:
(A) The total duration of excess
emissions (as indicated by the
monitoring data collected by the owner
or operator of the affected source in
accordance with § 63 343(c)) is 1
percent or greater of the total operating
time for the reporting period; and
(B) The total duration of malfunctions
•of the add-on air pollution control
device and monitoring equipment is 5
percent or greater of the total operating
time.
(ii) Once an owner or operator of an
affected source reports an exceedance as
defined in paragraph (h)(2)(i) of this
section, ongoing compliance status
reports shall be submitted semiannually
until a request to reduce reporting
frequency under paragraph (h)(3) of this
section is approved.
(iii) The Administrator may determine
on a case-by-case basis that the
summary report shall be completed
more frequently and submitted, or that
the annual report shall be submitted
instead of being retained on site, if these
measures are necessary to accurately
assess the compliance status of the -
source.
(3) Request to reduce frequency of
ongoing compliance status reports, (i)
An owner or operator who is required
to submit ongoing compliance status
reports on a semiannual (or more
frequent) basis, or is required to submit
its annual report instead of retaining it
on site, may reduce the frequency of
reporting to annual and/or be allowed to
maintain the annual report onsite if all
of the following conditions are met:
(A) For 1 full year (e.g., 2 semiannual
or 4 quarterly reporting periods), the
ongoing compliance status reports
demonstrate that the affected source is
in compliance with the relevant
emission limit;
(B) The owner or operator continues
to comply with all applicable
recordkeeping and monitoring
requirements of subpart A of this part
and this subpart; and
(C) The Administrator does not object
to a reduced reporting frequency for the
affected source, as provided in
paragraphs (h)(3) (ii) and (iii) of this
section.
(ii) The frequency of submitting.
ongoing compliance status reports may
be reduced only after the owner or
operator notifies the Administrator in
writing of his or her intention to make
such a change, and the Administrator
does not object to the intended change.
In deciding whether to approve a
reduced reporting frequency, the
Administrator may review information
concerning the source's previous
performance history during the 5-year
recordkeeping period prior to the
intended change, or the record-keeping
period since the source's compliance
date, whichever is shorter. Records
subject to review may include
performance test results, monitoring
data, and evaluations of an owner or
operator's conformance with emission
limitations and work practice standards.
Such information may be used by the
Administrator to make a judgement
about the source's potential for.
noncompliance in the future. If the
Administrator disapproves the owner or
operator's request to reduce reporting
frequency, the Administrator will notify
the owner or operator in writing within
45 days after receiving notice of the
owner or operator's intention. The
notification from the Administrator to
the owner or operator will specify the
grounds on which the disapproval is
based. In the absence of a notice of
disapproval within 45 days, approval is
automatically granted.
(iii) As soon as the monitoring data
required by §63.343(c) show that the
source is not in compliance with the
relevant emission limit, the frequency of
reporting shall revert to semiannual,
and the owner shall state this
exceedance in the ongoing compliance
status report for the next reporting
period. After demonstrating ongoing
compliance with the relevant emission
limit for another full vear, the owner or
operator may again request approval
from the Administrator to reduce the
'reporting frequency as allowed by
paragraph (h)(3) of this section.
(i) Reports associated mth trivalent
chromium baths. The requirements of
this paragraph do not alleviate affected
sources from complying with the
requirements of State or Federal
operating permit programs under title V.
Ov\Tiers or operators complying with the
provisions of § 63.342(e) are not subject
to paragraphs (a) through (h) of this
section, but must instead submit the
following reports:
(1) Within 180 days after January 25.
1995, submit an initial notification that
includes:
(i) The same information as is
required by paragraphs (c)(l) (i) through
(v) of this section; and
(ii) A statement that a trivalent
chromium process that incorporates a
wetting agent will be used to comply
with §63.342(e);and
(iii) The list of bath components that
comprise the trivalent chromium bath.
with the wetting agent clearly
identified; and
(2) Within 30 days of the compliance
date specified in § 63.343(a), a
notification of compliance status that
contains an update of the information
submitted in accordance with paragraph
(i)(l) of this section or a statement that
the information is still accurate; and
(3) Within 30 days of a change to the
trivalent chromium electroplating
process, a report that includes:
(i) A description of the manner in
which the process has been changed
and the emission limitation, if any, now
applicable to the affected source;
(ii) If a different emission limitation
applies, the applicable information
required by paragraph (c)(l) of this
section; and
(iii) The notification and reporting
requirements of paragraphs (d), (e), (f).
(g). and (h) of this section, which shall
be submitted in accordance with the
schedules identified in those
paragraphs.
TABLE 1 TO SUBPART N OF PART 63.—GENERAL PROVISIONS APPLICABILITY TO SUBPART N
General provisions
reference
63 Ha)(D
53 l(a)(2)
63 l(a)(3)
63 HaH4)
63 i(aU5)
63 1(a)(7)
firi iraHB*
Applies to
subpart N
Yes
Yes
Yes
Yes .
Yes
Yes
Yes
Comment
Additional terms defined in §63.341; when overlap between subpans A and N
takes precedence.
Subpart N clarifies the applicability of each paragraph in subpart A to sources
N.
occurs, subpan N
subject to subpart
-------
Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations 4977
TABLE 1 TO SUBPART N of PART 63.—GENERAL PROVSIONS APPLICABILITY TO SUBPART N—Continued
General provisions
reference
63.1(a)(10) ;
B3t{a}{11) , ,,
S"L-l(h}{1)
S3-1(h)p>)
63 tfhir-,1
63.1 (C)(2)
63.1 (cX4) _
63.1(e)
63.2 ..._ _
63.3 _
63.4 _
63 5 (a)
63.5(b)(l)
63.5(b)(3) ....
•63.5(b)'4} _ __
63.5{b)(5) .._.:..._ _ .. _...
63.5(b)(6)
63.5(d)0)(i)
6T "VrtVIWirt
63j«d)(2)
.63.5(6) ...:.._ _..: :...
63.5(f)(?)
63.6(a)
63.6(b)(1H2)
63.5(b)(3H4)
63.6(b)(5)
fi3.fi(h)(7)
63.5(c}(lH2>
63.5(cj(5) _
63.6(e)
63.6(0(1)
63.6(f)(2){iu)
63.6(f)(2)(iv)
63.6(0(2) (v)
63.6(f)(3) .
63.6(g) _..
63.6(h) _
63.6(i)(2)
63.6(')(3)
63.6(i)(4)fi) -
63.6(iM5)
63.6(i)(7) ...*~'.~~~~
Applies to
subpart N
Yes
Yes
(sin
Yes
No
Yes
Yes
w.-.
Yes
Yes —
Yes
Yes
Yes.
Yes
Yes
No.
Yes
Yes
YP<;
Yes
Yes .
Yes
Yes
Yc-,
Wo
Yes
Yes-
Yes
Yes
No .. .
NO
No
Yes
No
Yes
Yes
Yes
Yes
No
Yes-
Yes
Yes
No
Yes
Yes
Yes
Yes'
Comrrtent
§63-347 (a) of subpart N atso atows report submissions via tax and on electronic media.
§63340 at subpart N specifies appScabfflty.
This provision in subpart A is being deleted. Also, art-affected area and major sources are siajec
to sabpart N; there are no exemptions.
Sufcpart N riariffcs tf» iff*re»hi»y *" each Pafil9raPh '** s*-*part A to sources subject to subpart
N.
Subpart N specifies permit requirements for area sowces.
Subpart N clarifies that an area source that becomes a major source is subject to the recjiire-
ments tor major sources.
Additional terms defined in §63.341; when overlap between subparis A and rV occurs, subpart N
takes precedence.
Other units used in subpart N are defined in thai sufcpart.
Except replace the term "source" and "stationary source" in §63.5(a}(1) and (2) of- subpart A win
"affected resources."
Applies only to major affected sources.
Subpart N (§63.345) specifies requirements for the notification of construction or reconstruaxw
§63JJ45 <& subpart N. ;
Applies to major affected sources that are new or reconstructed except: (1) replace "source" in
§ S334d)<2) o( subpart A wdht "affected source"; and (2) actua) control efficiencies are submfted
with the NotfficaBon ol Compliance Status required by § 53.347(e).
Applies to major affected sources that are new or reconstructed.
Applies to major affected sources that are new or reconstructed.
Except replace "source" in § 63^ "afff*cff*d SO^JTCP "
Exceot replace "source" in §63-6(b)(5) of subpart A with, "affected source "
Provisions tor new area sources that become major sources are contented in § 63 343(a}(4) c!
subpart N.
Except replace "source" in §63.6fc)nW2) of subpart A with, "affected source."
Compliance provisions for existing area sources that become major sources are contained in
§63JJ«(a){3) ol subpart N.
§63.342(T) of miftfEjri N contains work pi'dctice standards (operation and maintenance rec(urfe-
mertfs) that override these provisions.
§ 63 34'{h) o' subpgi N sppcifie-s orfipn ih? s*a™^rri^ apply
§ 63.344(b) of subpart N specifies instances in which previous performance test res-jfrs tor exist-
ing sources are acceptaUe.
Subpart N does not contain any opacity or visible emission standards.
Except replace "source" in §63.6{i}{2)(i) and (f) of subpari A wr^i "affected source "
§63 3-^3(a)(5) of subpart N specifies the procedures fo* obtaining an exf€nsion of compliance and
the date by which such requests must be submitted. *
This paragraph onry references- "paraoraph (r}(4) 'ol this section** for compliance extension provv
sionS. But, §63.343(a)(6) ol subpart N also contains ptovisions tor requesting a compfiaiice e»-
lension. '•
-------
4978 Federal Register / Vql::60. No...l6 ./-Wednesday,--January 25, 1995-A Rules and-Regulations
TABLE l TO SUBPART.N OF PART.63.—GENERAL PROVISIONS APPLICABILITY TO SUBPART N—Continued
General provisions
reference
63.6(i)(8) .-.
63 6(i)(9)
63.6(0(1 0)(i)-(rv)
63.6(i)(10)(v)(A)
63.6(i)(10)(v)(B)
63.6(i)(11) ... .
63 6(0(12)0)
63.6(i)(12)(ii)-(ii')
63.6(0(13) .-.
• 63 6(i)(14)
63.6(0(16)
63 6(j) .
637(a)(1)
63.7(a)(2)(i)-(vi)
63.7(a)(2)(ix)
63.7(a)(3)
63.7(b)(l)
63.7(b)(2)
63.7(c)
63.7(d)
63.7(e) ..'
637(0
63.7(g)(l) _
63 7(Q)(3)
63.7(h)(1 H2)
63.7(h)(3)(i) _ .
63 7(h)(3)(ii)-(iii) :.
53 7(h)(4)-(5) v ..:.
63 B(a)(1)
63 8(a)(2)
63.8(a)(4) .....
638(b)(1)
63.8(b)(2)
63 B(b)(3) . . _
63 8(c)(1)(i)
63 8(c)(1)(ii)
638(c)(1)(iii)
63.8(c)(2)-{3) •- • -
63 8(c)(4V-f7) •. . .
63.8(d) :....:
63.8(6)
63.8(0(1) -
63.8(0(2) „
63.8(0(3)
63.8(0(4)
63.8(0(5)
63.8(0(6) :.:.
63 8(a) ' . . . -.
63 9(a)
63 9(b)(1Hi)-(ii)
63 9(b)(1)(iii)
63 9(b)(2)
63 9(b)(3)
Applies to
subpart N
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No :
Yes
No
Yes ..!
Yes ...
Yes
No
Yes
Yes
Yes -
Yes
Yes
Yes
No
No :
Yes
No ._ ......
No
No . _.'.
No '.'... ....
No
No
No
No
No
Yes
No _
Yes
Yes
Yes
No
No
Yes
No .
No
No ".
No
Comment
This paragraph only references "paragraphs (i)(4) through (i)(6) of this section" for compliance ex-
tension' provisions. But, §63.343(a)(6) of subpart N also contains provisions for requesting a
compliance extension.
This paragraph only references "paragraphs (i)(4) through (i)(6) of this section" and "paragraphs
(i)(4) and (i)(5) of this section" for compliance extension provisions. But, §63.343(a)(6) of sub-
part N also contains provisions for requesting a compliance extension.
This paragraph only references "paragraph (i)(4)" for compliance extension provisions But
§63.343(a)(6) of subpart N also contains provisions for requesting a compliance extension.
This paragraph only references "paragraph (i)(4)(i) or (i)(5) of this section" for compliance exten-
sion provisions. But, §63.343(a)(6) of subpart N also contains provisions for requesting a com-
pliance extension.
§63 347(d) of subpart N requires notification prior to the performance test §63 344 (a) of subpart
. N requires submission of a site-specific test plan upon request.
§63.344(a) of subpart N specifies what the test plan should contain but does not require test plan
approval Of performance audit samples.
Except replace "source" in the first sentence of §63.7(d) of subpart A with "affected source."
Subpart N also contains test methods specific to affected sources covered by that subpart
§63 344(c)(2) of subpart N identifies CARS Method 425 as acceptable under certain conditions
Subpart N identifies the items to be reported in the compliance test (§63.344(a)] and the time-
frame for submitting the resutts (§63.347(0].
This paragraph- only references "§63.6(0" for compliance extension provisions But §63.343(a)(6)
. ol subpart N also contains provisions for requesting a compliance extension
Work practice standards are contained in §63.342(0 of subpart N
. .
§63.344(d) of subpart N specifies the monitoring location when there are multiple sources.
§63.347(g)(4) of subpart N identifies reporting requirements when multiple monitors are used.
Subpart N requires proper maintenance of monitoring devices expected to be used by sources
. subject to subpart N. . ..-
§63J42(0(3)(iv) of subpart N specifies reporting when the O&W plan is not followed
§63.343(0(2) identifies tt>e criteria for whether O&M procedures are acceptable.
§63.344(d)(2) requires appropriate use of monitoring devices.
Maintenance of monitoring devices is required by §§63.342(0 and 63.344(d)(2) of subpart N
There are no performance evaluation procedures for the monitoring devices expected to be used
to comply with subpart N.
Instances in which the Administrator may approve alternatives to the monitoring methods and pro-
cedures of subpart N are contained in §63.343(c)(8) of subpart N.
Subpart N does not require the use of CEM's.
Monitoring data does not need to be reduced for reporting purposes because subpart N requires
measurement once/day. .
§63 343(a)(3) of subpart N requires area sources to comply with major source provisions if an in-
crease in HAP emissions causes them to become major sources.
§63347(c)(2) of subpart N specifies initial notification requirements for new 01 reconstructed af-
fected sources.
§63 347(c)(!) of subpart N specifies the information to be contained in the initial notification
§63347(c)(2) of subpart N specifies notification -requirements for new or reconstructed sources
that are not major affected sources.
-------
Federal Register / Vol. 60. No. 16 /Wednesday. January 25,-1995 /Rules and Regulations
TABLE 1 TO SUBPART N OF PART 63.—GENERAL PROVISIONS APPLICABILITY TO SUBPART f4—Continued
General provisions
reference
63.9(b}(4) • ...
63.9(b)(5)
63.9 (c) .
63.9(d)
63.9.'e)
63.9(0 - -
63.9(g)
63.9(h)C!}-(3)
63.9(h)(5) . .„.
63.9(h)(6)
63.9(i)
63.9{j) . ...
63.10(3)
63.10(b)(i) _..
63.10(b)(2)
63.10(b)(3)
63.10(c)
63.10(d)(i)
63.10(d}(2)
63.iO(d}(3)
63.10(d)(4)
63.iC(d)(5) _
63.10(6)
63.10(0
63.11
63.12-63.15
Applies to
subpart N
No
No
Yes
-Yes
No
No
No . ..
NO
No
Yes
Yes
Yes
Yes
Yes
No
No . ..
No
Yes
No
No
Yes
No
No
Yes
No
Yes
Comment
This paragraph onty references "§63.6(i)(4) through §53.6(i)(6)" for compliance extension p,m
sions. But, §63.343(a)(6) of subpart N also contains provisions tor requesting a compliance II
tension. Subpart N provides a different timeframe for submitting the request than §63.6(i)(4}.«
This paragraph only references "the notification dates established in paragraph (g) of this si
tion." But. §63.347 of subpart N also contains notification dates.
Notification of performance test is required by § 63.347(d) of subpart N.
Subpart N does not require a performance evaluation or relative accuracy test for monitoring a
vices.
§63.347(e) of subpart N specifies information to be contained in the notification ol compila?!
status and the timeframe forsubmitting this information. __
Similar language has been incorporated- into § 53.347(e)(2)(iii) of subpart N.
§ 63.346(b) of subpart N specifies the records that must be maintained.
Subpart N applies to major and area sources.
Applicable requirements of §63.iO(c) have been incorporated into §63.346(b) of sutpart N.
•
§63.347(f) of subpart N specifies the timeframe for reporting performance test resets.
Subpart N does not contain opacity or visible emissions standards.
§63.3J2(f)(3)(iv) and § 63.347(gJ(3) ol subpart N specify reporting associated with maKunc'.ions. 1
§ 63.347(g) and (h) of subpart N specify the frequency of periodic reports of monitoring data isii
to establish compliance. Applicable requirements of §63.10(e) have been incorporated in|
§ 63.347(g) and (h).
Flares will hot be used to compry with the emmission limits.
3. Appendix A to part 63 is amended
by adding Methods 306 and 306a in
numerical order to read as follows:
Appendix A to part 63—Test Methods
Method 306—Determination of Chromium
Emissions From Decorative and Hard
Chromium Electroplating and Anodizing
Operations
1. Applicability and Principle
1.1 Applicability. This method applies to
"he determination of chromium (Cr) in
emissions from decorative and hard chrome
electroplating facilities and anodizing
operations.
1.2 Principle, (a) A sample is extracted
isoldnetically from the source using an
uaheated Method 5 sampling train (40 CFR
, part 60, appendix A), with a glass nozzle and
probe liner, but with the filter omitted. The
Cr emissions are collected in an alkaline
solution: 0.1 N sodium hydroxide (NaOH) or
0.1 N sodium bicarbonate (NaHCOj). The
collected samples remain in the alkaline
solution until analysis. Samples with high Cr
concentrations may be analyzed using
inductively coupled plasma emission
spectrometry UCP) at 267.72 nm.
Alternatively, if improved detection limits
are required, a portion of the alkaline
impinger solution is digested with nitric acid
ond analyzed by graphite furnace atomic
absorption spectroscopy (GFAAS) at 357.9
nm.
fb) If it is desirable to determine hexavalent
chromium (Cr**) emissions, the samples may
be analyzed using an ion chromatogjaph
equipped with a post-column reactor (IC/
PCR) and a visible wavelength detector. To
increase sensitivity for trace levels of Cr"0,
a preconcentration system can be used in
conjunction with the IC/PCR.
2. Range, Sensitivity, Precision, and
Interferences
2.1 Range. The recommended analytical
range for each of the three analytical
techniques is given below. The upper limit
of all three techniques can be extended
indefinitely by appropriate dilution.
2.1.1 GFAAS Range. As reported in
Method 7191 of SW-846 (Citation 5 in
Bibliography), the optimum concentration
range for GFAAS is 5 to 100 jig Cr/1 of
concentrated analyte.
2.1.2 1CP Range. A linear response curve
for ICP can be obtained in the range of 10 to
at least 500 ug Cr/1 of absorbing solution.
2.1.3 1C/PCR Range. In 40 CFR part 266,
appendix IX, the lower limit of the detection
range for IC/PCR when employing a
preconcentration procedure is reported to be
about 0.1 MgO~*/l of absorbing solution.
2.2 Sensitivity.
2.2.1 Analytical Sensitivity.
2.2.1.1 ICP Analytical Sensitivity. The
minimum detection limit for ICP, as reported
in Method 6010A of SW-846, is 7 ug C-.'l.
2.2.1.2 GFAAS Analytical Sensitivity.
The minimum detection limit for GFAAS. si
reported in Method 7191 of SW-646, is 1 pgf
Cr/1. - ' '
2.2.1.3 IC/PCR Analytical Sensitivity.1 Tip
minimum detection limit for IC/PCR with a]
preconcentrator, as reported in 40 CFR part
266, appendix IX is 0.05 fig Cr-«/l.
2.2.2 ln-stadc Sensitivity. The in-slack
sensitivity depends upon the analytical
detection limit, the volume of stack gas
sampled, and the total volume of the
impinger absorbing solution plus the rinses.
Using the analytical detection limits given m
sections 2.2.1.1. 2.2.1.2, and 2.2.1.3; a s'.zc'i.
gas sample volume of 1.7 dscn; and 3 total
liquid sample volume of 500 ml; the
corresponding in-slack detection limits are
0.0021 mg Cr/dscm for ICP. 0.00015 mg C-/
dscra for.CFAAS, and 0.000015 mg Cf'l
dscm for IC/PCR with preconcentralion.
However, it is recommended that the
concentration of Cr in the analytical
solutions be at least five times the analytical
detection limit to optimize sensitivity in the
analyses. Using this guideline and ihe-sarr.e
assumptions for impinger sample volume
and stack gas sample volume (500 ml and 1 7
dscm, respectively), the recommended
minimum stack concentrations for optifn-" i
sensitivity are 0.0103 mg Cr/dscm for ICP. ;
0.00074 mg Cr/dscn for CFAAS, and
0.000074 mg Cr-«/dscm for IC/PCR with
preconcentration. If required, the in-slack
detection limits can be improved by'either'
increasing the stack gas sample volume,
-------
4S80 Federal Re^sier-/ Vol. 60;. No. 16. /- Wednesday. January 25v 198S /• Rules and Regulations
reducing.the volume^of the digested sample
for GFAks. taproviag the analytical"
detection limits, or any combination ofthe
three.
2.3 Precision.The following.precisian.
data have been reported for the three
analytical methods. In the case of the CFAAS
there is also bias.data-in.all cases*, when:
sain p ling, precision, is. combined with-
analytical precisionv tie, resulting, overall:
precision, may. belbu-er-
2.3.1 GFA-AS Precision. As reported in.
Method 7191 of SW-846. ircasiagle
laboratory (EMSL), using Cincinnati. Ohio
tap water spiked;atcanceattatioos-of 1-9-..48,
and 77 jig Cr/1. the standard deviations were
rO_l,.±0.2,.and.±Oi8,Bespectively- Recoveries
at these levels were 97 percent, 101 percent.
and 102 percent, respectively-
2.3.2 ICP Precision. As reported in
Method 6010A of SW-646. in an EPA round-
robin Phase 1 study, seven laboratories
applied the 1C? technique to acid/distilled
water matrices that had been spiked with
various metal concentrates.. For true-values-of
10. 50. and 150 ug Cr/1; the mean reported
values were lO^SQ^antfr 14fa-m-tne:li:ieeiais«fen.oF -
high-concentration- elements.
(b) Spectral overlap may be compensated
for by computer correcting ths ra-w data after
rnonitnTing anH Tnpagnrino thg interfering.
element. At the 267.72-nm Cr analytical
wavelength, iron, manganese, and uranium
•are potential interfering,elements;.
Background and stray Light interferences, ran,
usually be compensated foe by, a. background
correction adjacent to >R<»_ anaTy-t"-ar li n g
Unresolved;overlap.requires-tieseJection of.
an alternative Cr wave length-Consult, the
instrumenr manufacturer's operation manual
fbr interference correction procedures..
2.4.2'.2' ICP'Phy-icar Interferences. High.
levels of dissolved solids in the samples- may-
cause significant jnaccuracies.due to salt
buil'duparrhenebulizer and torch tips.This
problem 'can- be-controlled1 by diluting the
sample or providing for extended rinse times
between sample analyses. Standards are
prepared in the same matrix as the samples
(i.e.. 0.1 N NaOH or 0.1 N NaHCOj).
2.4.2.3 ICP Chemical Interferences..These
include-morecular compound- formation..
ionization effects and solute-vaporization
effects-, and are-usually not significant ITT ICP;
especially if the standards and samples a:e
marn;* matched-
2.413- IC/PGKtaterferenees. Components.
in the sample matrix may cause Cr*6 to
converttatriualeat chromiiim (Cr*3) or
cause.Cr"3 tb.convert to-Cr"*. The
csromalogranhic:separation- 06 Cr -|S us ing-
ion chromatography reduces- die potential- for
other metals to interfere with the post-
coliran.reacrion. For the IQtCR analysis.
only compounds that coelute with Cr*6 and
afreet the diphenylcarbazTde reaction will"
cause interference. Periodic analyses of
reagent, water blanks-are used to demonstrate
that the analytical system is essentially free.
of contamination. Sample cross-
contamination that can occur, (then higE.-
level andTow-leyel'sampres or standards are.
analyzed'alternately is eliminated By
thorough purging.of the sample loop. Purging
can easily, be achieved by. in creasing, the
injection volume of the samples to ten.ti*aes-
the size of the sample loop..
3. Apparatus
3.1 Sampling Train. A schematic.o£ the
sampling train used in this method Ls. shown
in Figure 306rT. The train is the. same as.
Methods, section.2.T (40CFR.part.60,.
appendix A), except that the. filter is omitted.
and quartz or borasilicate glass.must.be used
for the probe nozzle and liner in.place of
stainless steel. Lc is noL necessary to.neat the
probe liner. Probe fittings of plastic such as
Teflon, polypropylene, etc are necommended'-
over metal'fittings-to prevent coruaminalioa.
If desired, a single combined'probe nozzle.
and liner, may be used..buLsunh a.singie.glass
piece Ts not'a- requirement- oCthis.
me thodblbgy.. Use. 0.1N" NaQH or. 0.1N
NaKCOi in tha i'mpingers;Ln.pEace o£ water.
T.2' Sample.RfiCOvery..Sa*aa:as Methods^
section. 2.2. C-fO CFR part 6D..apDeadixAJ^
\virri rfie fbubvvihg.except-ions:.
3.211 Ptobe-Lirier arjJ Pr3be-"^>zzle
Brushes.. Brushes-are not necessary tor-
sample-recovery. If a probe brash-isus«d. it
must 5e-nonmetal!ic.
7.T.2' SamDleRecovery Solution. Use 0.1
NT NaOH or ff.T N XaHCOi. whichever was
used as the impinger absorbing solution, in.
pl-tcenf acetone to recover tae sampfe.
3.2.3 Sample Storage Containers.
Polyethylene,, with leak-free screw capi.500-
ml"or 1,000 ml.
3.2.4 Filtration Apparatus for IC'PCK-
Tefion. or equivalent, filter holder and 0. "5-
um acetate, or equivalent, filter.
3.3 Analysis; For analysis, the follo'.ving
equipment is seeded.
3.3.1 General.
3.3_L1_ PhiUips.Beaks.-s. (P-hillips-beakers
are preferred; but regular twakers-Gan also-be-
used.)
3.3.i:2 HotPlat^.
3.3.1.3 Volumetric Flasks. Class- A.
various sizes as appropriate.
"3-.3-.1.4 Assorted Pipettes.
3.3.2 Analysis-by GFAAS.
3;3-.2;l Chromium Hollow Cathode Lamp
ar Electrodeless Discharge Lamp.
3:3.2'.2- Graphite Furnace Atomic.
.Absorption S'pecL-ophotor-'.eter. i
3.3.3 Analysis by ICP.
3.3.3.1- ICP Spectrometer. Computer-
cur.trolled emission spectrometer with
background correction and radio frequency
generator.
3.3.3.2' Argon Gas Supply. VTelidJng grade
or better..
3.3.4 Analysis by IC/PCR.
3.3.4.1 IC/PCR System. High, performance
liquid'chromatograph pump, sample
injection valve, post-column reageTTf delivery
and mixing-system, and a-vijibfe-detecror.
capable of operating at 520 r.m..aU with a
nornnetattic (or irrertl'rToivparrr. An
electronic peak area mode is recommended.
but other recording devices and integration
techniques are acceptable- provided' the-
repeatability criteria-and the-lmearftj'-critcria
for the-calibratiorrcur.-e-described hr section
6.4.1 can be satisfied. A sample loading-
system will be required ifpreconcenlratio:: is
employed.
3.3.4.J . AnalyticalColuzz-A high.
performance ion. chrorna^3graQh.(HPlC)
nonmetalliccolumn. wi;h aaioa sepnration
characteristics and a high loading capacity
designed forseparauo:Lof rnemlchelating:
com pou nds. to.- prevent mera L ir.terferenci:.
Resolution describe'd in.-sectiorD5.Smust be-
obtained A: non-naaliic.guard column wUh
the sarae:ion.-«xcrrange-marenal:is.
recommended
3'.3;4".3' Preconcentration Column. An-
HPIC nonme
-------
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o
Tomporaturo
Sonsor
•n
H-
IQ
C
M
ft)
u>
o
M-
3
U)
tn
n
y
fD
n
TypaS'
Pilot Tubo
Glass
Nozzle
Probo
Tomporaturo
Sonsor
Implnger Train
Stack
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Tubo
Vacuum
Uno
-------
4382. Federal Register / Vol. 68. No. 16 t Wednesday. January 25. 1995 / Rules and. Regulations
3.3.4.4 0.45-um Filter Cartridge. For the
removal of insoluble material. To be used just
prior to sample injection/analysis.
•4. Reagents
Unless otherwise indicated, all reagents
shall conform to the specifications
established by the Committee on Analytical
Reagents of tie American Chemical Society
(ACS reagent grade). Where such
specifications are not available, use the best
available grade.
4.1 Sampling.
4.1.1 Water. Reagent water that conforms
to ASTM Specification D.U93-77, Type tt
(incorporated by reference—see §63.14). Iris
recommended that water-blanks be checked
prior to preparing samplfng.D»agents to
ensure that the Cr content is. less than, tie-
analytical detection limir.
4.1.2 Sodium Hydroxide (NaOH)
Absorbing Solution, 0.1 N or Sodium
Bicarbonate (NaHCQj).' Absorbing.Solution.
0.1 N. Dissolve 4.0 g of'sodium.hydroxide in
1 1 of water, or dissolve 8.5 g-of sodium
bicarbonate in 1 1 of water.
4.2 Sample Recovery.
4.2.1 0.1 N NaOH or" 0.1 N NaHCOj. See
section 4.1.2. Use the same solution for
recover)' as was used in the impingers.
4.2.2. pH Indicator Strip, for E/PCR. pH
indicator capable of determining;thepH of
solutions between the pH range of 7 and 12,
at 0.5 pH intervals.
4.3 Sample Preparation and Analysis'.
4.3.1 Nitric Acid (HNOj)-, Concentrated.
for CFAAS. Trace metals grade or better
HNOj must be used for reagent preparation.
The ACS reagent grade HNOj is acceptable
for cleaning glassware.
4.3.2 HNOj. 1.0 percent fv/vj-. for GFAAS.
Add. with stirring. 10 ml of concentrated
HNOj to 800 ml of water. Dilute to 1,000 ml
with water. This reagent shall contain less-
than 0.001 mgCr/1.
4.3.3 Calcium Nitrate Ca(NOj)2 Solution
(10 ug Ca/ml) for GFAAS. Prepare the
solution by weighing 36 rag of Ca(NOjh into
a 1 I volumetric flask. Dilute with water to
1 1
4.3.4 Matrix Modifier, for GFAAS. See
instrument manufacturer's manual for
suggested matrix modifier.
4.3.5 Chromatographic Eluent. for IC/
PCR. The eluent used in the analytical
system is ammonium sulfate based. Prepare
by adding 6.5 ml of 29 percent ammonium
hydroxide (NR»OH) and 33 g of ammonium
sulfate ((Nl-UhSOJ to 500 ml of reagent
water. Dilute to 1 1 with reagent water and
mix well. Other combinations of eluents and/
or columns may be employed provided peak
resolution, as described in section 5.5.
repeatability and linearity, as described in
section 6.4.1, and analytical sensitivity are
acceptable.
4.3.6 Post-Column Reagent. ForlC/PCR.
An effective post-column reagent for use with
the chromatographic eluent described in
section 4.3.5 is a diphenylcarbazide (DPC)
based system. Dissolve 0.5 g of 1.5-
diphenyicarbazide in 100 ml of ACS grade
methanol. Add 500 ml of reagent water
containing 50 ml of 96 percent
spectrophotometricgrade sulfuric acid.
Dilute to 1 1 wills reagent water.
4.3.7 Chromium-Standard Stock Solution
(1.000 mg/1). Procure a certified aqueous
standard or dissolve 2.829 g.of potassium
dichzornate-(K:Cr:C>7.)'fn water and dilute to
11.
4.3.B Calibration Standards for GFAAS.
Chromium solutions for GFAAS calibration
shall be prepared to contain l.ffpercent (vi
vJ.HNO3. The zero standard shall be 1.0
percent (v/v) HMQj ralihratJnn.ttanffai-H*-
should be prepared daily by diluting the Cr
standard-stock solution (section 4.3-Zr1 ««<•!>
1.0 percent R\Oj. Use. aL least four standards
to make the calibration- curve;. Suggested
levels are 0, 5.50. and 100 jigCc/t.
4.3.9 Calibration Standard^ for ICP or IC/
PCR. Prepare calibration standards-for TCP or
1C/PCR byrd-Uutingithe Crstandard stock-
soliition (section 4.3.71 with Oi N NaOH or
0\1 N NaHCOj,. whichever was used as the.
impinger absorbing soLutfonvto achieve-a-
matrix similar CCT the acrnzl: field samples.
Suggested:levels-are-9-, 25-. SfkandTOO'ug-Cr/
1 for ICP. and0.0.5, 5, and lOiigCr-'/l for
IC/PCR.
4.4" Glassware-Cleaning. Reagents.
4,4.1 HNOo. ConcentratEtiTheACS
reagent grade or. equivalent.
4.4.2 Water. Reagent water that conforms
to ASTNtSpecification D1193-77. Type IL
(incorporated by reference—see §63.14).
4.4.3'HNQj-10 percent (v/v). Add with
stining-SDO'mJ of concentrated HNOj to-a
flask containing approximately 4,000, mi of
water. Dilute ID 5,000 ml with water. Mix
Well. The r»ag«»nt 'hall rnntain iixre-than ? |]^
Cr/1.
5. Procedure
5.1 Sampling, (a) Same asMethod 5,.
section 4.1 G*0 CFR parr60. appendix Al.
except omit the filter and filter holder from.
the sampling train, use a glass:nozzleaud
probe liner, do not neat the probe.place 100
ml of 0.1 N NaOH or O.T N' NaHCOj in each
of the first two impingers, and record the
data for each run on a data s&eet such as the
one shown in Figure 306-2.
fb) Clean all glassware prior to sampling in
hot soapy water designed1 for laboratory
cleaning of glassware. Next, rinse the
glassware three times with tap water,
followed by threeadditional rinses with
reagent water. Ttren soak all glassware in 10
percent (v/v) HNOj solution fora minimum
of 4 hours, rinse three times with reagent
water, and allowed to air dry. Cover all
glassware openings where contamination can
occur with Parafilm. or equivalent, until the
sampling train is assembled for sampling.
(c) If the sample is going to be analyzed for
Cr * 6 using IC/PCR. determine the pH of the
solution in the first impinger at the end of the
sampling run-using.a.p.H indicator strip. The.
pHofthe-scrfiTtion.sTiwrtibe'greater than »5-.
if not. the concentration of the NaOH or
NaHCOj impinger absorbing solution should
be increased to 0.5 N and the sample should
be rerun.
5.2 Sample Recover)-. Follow the basic
procedures of'Method's, section 4.2. with the
exceptions noted below, a filter is cot
recovered from this train.
5.2.1 Container No. 1. Measure the
volume of the liquid in the first, second, and
third impingers and quantitatively transfer
into a labelled sample container. Use
approximately 200 to 300 ml of 0.1 N NaOH
or 0.1 N NaHCOj to rinse the probe nozzle.
probe liner, three impingers. and connecting
glassware; add this rinse to the same
container.
5.2i2 Container No. 2 (Reagent Blank).
Placeapproximately 500 ml of 0.1 N NaOH
or 0.1 N NaHCOj absorbing solution in a
labeled sample container.
5.2".3 Sample Filtration for IC/PCR- If the
sample is to be analyzed for Cr"4 by IC/PCR.
it must be filtered immediately following
recovery to remove any insoluble matter.
Nitrogen gas may be used as a pressure assist
to the filtration process. Filter the entire
Gontents-of Container No. 1 through a 0.45-
jun acetate filter (or equivalent), and collect
the filtrate irta 1,000 ml graduated cylinder.
Rinse the sample container with reagent
water three separate times, pass these rinses
through the filter, and add the rinses to the
sample filtrate. Determine the final volume of
the filtrate and rinses and return them to the
rinsed polyethylene sample container.
5.2.4 Sample Preservation. Refrigerate
samples upon receipt. (Containers Nos. 1 and
2).
5.3 Sample Preparation and Analysis for
CFAAS. For analysis by GFAAS. an acid
digestion of the alkaline impinger solution is
required. Two types of blanks are required
for the analysis. The calibration blank is used
in establishing the analytical curve, and the
reagent blank is used to assess possible
contamination resulting from the sample
processing. The 1.0 percent HNOj is the
calibration blank. The 0.1 N NaOH solution
or the 0.1 N NaHCOj from section 5.2.2 is the
reagent blank. The reagent blank must be
carried: through the complete analytical
proceriiim. including the acid digestion, and
must contain the same acid concentration in
the fmal:5olution as the sample solutions.
5.3.1 Acid Digestion for GFAAS. (a) In a
beaker, add 10 ml of concentrated HN'Oj to
a sample aliquot of 100 ml taken for analysis.
Cover the beaker with a vtatch glass. Place
the beaker on a hot place and reflux the
sampfe down tn-neardiyness. Add another
5 ml of concentrated HKOj to complete the
digestion-. CarefuDy reflnxthe sample volume
down to near dryness. Wash down the beaker
walls and watch glass with reagent water.
The final concentration of HNOj in the
solution should be 1 percent (v/v}. Transfer
the digested sample to a 50 ml volumetric
flask. Add 0.5 ml of concentrated HNOj. and
1 mtof the ISO |ig/ml of Ca (NOj):.
fb) Dilute to 50 ml with reagent water. A
different final volume may be used, based on
the expected Cr concentration, but the HNOj
concentration must be mainfaiaesiai t
percent (v/v).
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Figure 306-2. Chromium Field Data Sheet.
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-------
4984 Federal Register / Vol; 60, No. 16 / Wednesday, January 25, 1995 / Rules and Regulations
5.3.2 Sample Analysis by GFAAS. (a) The
357.9-nm wavelength line shall be used.
Follow the manufacturer's operating
instructions for all other spectrophotometer
parameters.
(b) Furnace parameters suggested by the
manufacturer should be employed as
guidelines. Since temperature-sensing
mechanisms and temperature controllers can
vary between instruments and/or with time,
the validity of the furnace parameters must
• be periodically confirmed by systematically
altering the furnace parameters while
analyzing a standard. In this manner, losses
of analyte due to higher-than-necessary
temperature settings or losses in sensitivity
due to less than optimum settings can be
minimized. Similar verification of furnace
parameters may be required for complex
sample matrices. Calibrate the GFAAS
system following the procedures specified in
section 6.
(c) Inject a measured aliquot of digested
sample into the furnace and atomize. If the
concentration found exceeds the calibration
range, the sample should be diluted with the
calibration blank solution (1.0 percent HNOj)
and reanalyzed. Consult the operator's
manual for suggested injection volumes. The
use of multiple injections can improve
accuracy and help detect furnace pipetting
errors.
(d) Analyze a minimum of one matrix-
matched reagent blank per sample batch to
determine if contamination or any memory
effects are occurring. Analyze a calibration
blank and a midpoint calibration check
standard after approximately every 10 sample
injections. =
(e) Calculate the Cr concentrations:
(1) By the method of standard additions
(see operator's manual),
(2) From the calibration curve, or
(3) Directly from the instrument's
concentration readout. All dilution or
concentration factors must be taken into
account. All results should be reported in |jg
Cr/ml with up to three significant figures.
5.4 Sample Analysis by ICP. (a) The ICP
measurement is performed directly on the
alkaline impinger solution; acid digestion is
not necessary provided the samples and
standards are matrix matched. However. ICP
should only be used when the solution
analyzed has a Cr concentration greater than
35 tig/1.
(b) Two types of blanks are required for the
analysis. The calibration blank is used in
establishing the analytical curve, and the
reagent blank is used to assess possible
contamination resulting from sample
processing. Use either 0.1 N NaOH or 0.1 N
NaHCOj, whichever was used for the
impinger absorbing solution, for the
calibration blank. The calibration blank can
be prepared fresh iri the laboratory: it does
not have to be from the same batch of
solution that was used in the Held. Prepare
a sufficient quantity to flush the system
between standards and samples. The reagent
blank (section 5.2.2) is a sample of the
impinger solution used for sample collection
thaj i:son>"ecied in the field drrir.g the testing
program.
(c) Set up the instrument wi:h proper
opfirati.-.g parameters ir.cludir.g wavelength.
background correction settings (if necessary'),
and interfering element correction settings (if
-necessary). The instrument must be allowed
to become thermally stable before beginning
performance of measurements (usually
requiring at least 30 min of operation prior
to calibration). During this warraup period,
the optics] calibration and torch position
optimization may be performed (consult the
operator's manual).
(d) Calibrate the instrument according to
the instrument manufacturer's recommended
procedures, and the procedures specified in
section 6.3. Before analyzing the samples,
reanalyze the highest calibration standard as
if it were a sample. Concentration values
obtained should not deviate from the actual
values by more than 5 percent, or the
established control limits, whichever is lower
(see sections 6 and 7). If they do, follow the
recommendations of the instrument
manufacturer to correct for this condition.
(e) Flush the system with the calibration
blank solution for at least 1 min before the
analysis of each sample or standard. Analyze
the midpoint calibration standard and the
calibration blank after each 10 samples. Use
the average intensity of multiple exposures
for both standardization and sample analysis
to reduce random error.
(0 Dilute and reanalyze samples that are
more concentrated lhan the linear calibration
limit or use an alternate, less sensitive Cr
wavelength for which quality control data are
already established.
(gj If dilutions are performed, the
appropriate factors must be applied to
sample values. All results should be reported
in jig Cr/ml with up to three significant
figures.
5.5 Sample Analyses by IC/PCR. (a) The
Cr*6 content of the sample filtrate is
determined by IC/PCR. To increase
sensitivity for trace levels of chromium, a
preconcentration system is also used in
conjunction with the IC/PCR.
(b) Prior to preconcentration and/or
analysis, filter all field samples through a
0.45-ura filter. This filtration should be
conducted just prior to sample injection/
analysis.
(c) The preconcentration is accomplished
by selectively retaining the analyte on a solid
absorbent (as described in section 3.4.3.3),
followed by removal of the analyte from the
absorbent. Inject the sample into a sample
loop of the desired size (use repeated
loadings or a larger size loop for greater
sensitivity). The Cr"* is collected on the
resin bed of the column. Switch the injection
valve so that the eluent displaces the
concentrated Cr*4 sample, moving it off the
preconcentration column and onto the 1C
anion separation column. After separation
from other sample components, the Cr" 6
forms a specific complex in the post-column
reactor with the DPC reaction solution, and
the complex is detected by visible absorbance
at a wavelength of 520 nm. The amount of
absorbance measured is proportional to the
concentration of the Cr*6 complex formed.
Compare the 1C retention time and the
absorbance of the Cr*6 complex with known
Cr*6 standards analyzed under identical
conditions to provide both qualitative and
quantitative analyses.
(d) Two types of blanks are required for the
analysis. The calibration blank is used in
establishing the analytical curve, and the
reagent blank is used to assess possible
contamination resulting from sample
processing. Use either 0.1 N NaOH or 0.1 N
NaHCOj, whichever was used for the
impinger solution, for the calibration blank.
The calibration blank can be prepared fresh
in the laboratory; it does not have to be from
the same batch of solution that was used in
the field. The reagent blank (section 5.2.2) is
a sample of the impinger solution used for
sample collection that is collected in the field
during the testing program.
(e) Prior to sample analysis, establish a
'stable baseline with the detector set at the
required attenuation by setting the eluent
flow rate at approximately 1 ml/min and the
post-column reagent flow rate at
approximately 0.5 ml/min. Note: As long as
the ratio of eluent flow rate to PCR flow ra'.e
remains constant, the standard curve should
remain linear. Inject a sample of reagent
water to ensure that no Cr"6 appears in the
water blank-
(f) First, inject the calibration standards
prepared, as described in section 4.3.9 to
cover the appropriate concentration range,
starting with the lowest standard first. Next,
inject, in duplicate, the calibration reference
standard (as described in section 7.3.1),
followed by the reagent blank (section 5.2.2),
and the field samples. Finally, repeat the
injection of the calibration standards to
assess instrument drift. Measure areas or
heights of the Cr*6/DPC complex
chromatogram peaks. The response for
replicate, consecutive injections of samples
must be within 5 percent of the average
response, or the injection should be repeated
until the 5 percent criterion can be met. Use
the average response (peak areas or heights)
from the duplicate injections of calibration
standards to generate a linear calibration
curve. From the calibration curve, determine
the concentrations of the field samples
employing the average response from the
duplicate injections.
6. Calibration
6.1 Sampling Train Calibration. Perform
all of the calibrations described in Method 5,
section 5 (40 CFR part 60. appendix A). The
alternate calibration procedures described in
section 7 of Method 5 (40 CFR part 60,
appendix A) may also be used.
6.2 GFAAS Calibration. Either run a
series of chromium standards and a
calibration blank and construct a calibration
curve by plotting the concentrations of the
standards against the absorbencies, or using
the method of standard additions, plot added
concentration versus absorbance. For
instruments that read directly in
concentration, set the curve corrector to rcsd
out the proper concentration, if applicable.
This is customarily performed automatically
with most instrument computer-based dn:a
systems.
6.2.1 GFAAS Calibration Curve. If a
calibration curve is used, it should be
prepared daily with a minim-urn of a
calibration blank and three standards.
Calibration standards for total chromium
should start with 1 percent v/v HN'Cs wi:!i
-------
Federal Register / VoK 60. No. 16 / Wednesday. January 25. 1995. / R^fes: aad Regubtiore
r.O r'nrnmiiiTTi tnr thg patihgafiryq KJanV- wiA
appropriate increases'in total ciiromium
concentration for the ot&ercaEbralfon m
stan cards; (-see sectfon 1.3.9J- Cafibratioa
standarrfs jcoriW te piey«ue(J fiw>li daily.
e.3 ICPCafifcratistt. CaEferate-tne-
LLJ>I—nuttagacrtiitfiag to the fesaunrenf
tzanafaetuceEs: •"- IUHIIU»«T<*«»J procedures,
using a catibratioa Ma
for the initial calibration. Calibration:
standards should be prepared fresh daily, as
described: in. secfroa 4. 15. Be- sare'tSaf
samples and calibration standards are- matrix
matched. Flush, the. system with, the
calibration blank between each standard. Use
the average intensity of multiple exposures
for both standardization and sample azalysfs
to reduce random error.
6'A IOPCR Calibration. Prepare a
calibratftm orrve using the calibration blank
and three- eatibidtiuii stJuuVJs prepared
fresh- daily 39 deser&ed Frt sectfon 4.3.9. Rnn
the-stantrards with- The
described hi sectina 5-5.
~. QuaiP.y Ccn':o[
7 J . GEAASQuaiitt Control
7.1.1. Cf.iAS.CaiiaialiDa Reference
Standards. rf a, calibration curve is used.it -
must be verified by use ofat Feast one
calibration: reference standard (made from a
rsfererrie- material1 or other independent
standard nraterre IT er or neer-the. mid-range of
the-caUcratioa curre. The-cafibratioTi .
reference staraiacd msst be measured wShfn
1 ft percent; of it's traE«aJae.fcr the. curve- to-
be considered, valid. Ihe curve most be
validated before. sacio.ie analyses- are
"r.l.2 CEAAS rJip,- k Standards. (a.1 Run a
check standard and a calibration. biaak.after
approximately. every 10 sample infections..
ar.d at The end of the ar.afytical run. These
standards are rue, ur- parr. to monitor the liTe
and perrbrmenee-ofthe grzpfrrte- Rrbe. Lack
of refwoeucibrTrryor a sfgnfffcartt change- in
the signal fo: the check standard indicates
that the graphite tube should be replaced.
Check standards can be the mid-range
calibration standard or the reference
standard. The results of the check standard
shall agree within 10 percent of the expected
value. If not. terminate the analyses, correct
the problem, recalibrate the instrument, and
reanalyze al! samples analyzed subsequent to
the last acceptable check standard analysis.
(b) The results of the calibration blank are
to agree within three standard deviations of
the mean blank value. If not. repeat the
analysis two more times and average the
results. If the average is not within three
standard deviations of the background mean.
terminate the analyses, correct the problem.
recalibrate, and reanalyze all samples
analyzed subsequent to the last acceptable
calibration blank analysis.
7.1.3- GFAAS Duplicate Samples. Run one
duplicate sample for every 20 samples, (or
one per source test, whichever is more-
frequent). Duplicate samples are brought
through the whole sample preparation and
analytical process separately. Duplicate
samples shall agree within 10 percent.
7.1.4 GFAAS Matrix Spiking. Spiked
samples shall be prepared and analyzed daily
to ensure lhat.correct procedures are being
followed and that-all equipment is operating
properlv. Spiked sample recovery analyses
should iudicaJfi a recovery for the-Cr spifce-
of between 75 and IZSpercenLSpSeaare
added prior to any sample preparation- Or
levels in the spiked sampfe.sao**l<£ pnwfde
final solution concentrations that fall within.
the linear oortion-of the calibration curve.
7.T.5 GTAASMethod of Standard
Additions. Whenever sampfe matrix "
problems are suspected aid standard/sample
matrix matching is not possible or whenever
a new sampfe matrix fs being analyzed, the-
method of standard additions.shall be used
for the analysis of aU extracts. Section. 5.4_2
of Method 12" t^tJ CFK part 60.appendlxAJ
specifies a performance, test to determine if
the method of standard additions is-
necessary.
7.1.6 GFAAS Reagent Blank Samples^
Analyze a minimum of one Datrix-matched.
reagent blank (section 5.2.21 per sample batch
to determine if contamination or. rfrrcfiry
effects are occurring. The results should
agree within three standard deviations of the
mean: biank vatae.
7.2 ICPQbaiitjrOmlial-
7.iJ. ICP Imerfereccer Check. Prepare an-
interference check solution to contaie known
concentrations of iriter£ering.elemen£s that
will provide an adequate test of the
correction factors in- the event of ptrteiUial-
spectral interferences; Two potential
interferences, aott and manganese-, mar be
prepared as 1,00(J pg/mJ aorf 2O& ng-feF
solutions; respecrfvevy. Thesofutiocs-shoulrf
be prepared in ditute-RNOi ft-5 percent?.
Particular care-must be token-to enstrre that
the solnrieDs-and/or salts used to prepare the
solutions-are-eflCPgrade-purity (r.e>.. thatno-
rr.easurabfe Cr cont-anunettbtr exists- itr tire-
salts^solutions). Consfnerciafly prepared
interfering-element check standards- are-
available. Verify the interelement coueerie 11
factors every three months by znalyzing rtre
interference c&«dt solution-. The correction
factors are-cateulated according to- the-
instrument manufacturer's directions-. If
iaterelement' correction factors are-osed
properly, no false Cr should be detected.
7.2.2 ICP Calibration Reference
Standards. Prepare a calibration reference
standard in the same alkaline matrix as the
calibration standards; it should be at least 10
times the instrumental detection limit This
reference standard should be prepared from
a different Cr stock solution source than that
used for preparation of the calibration curve
standards and is used to verify the accuracy
of the calibration curve. Prior to sample
analysis, analyze at least one reference
standard. The calibration reference standard
must be measured within 10 percent of it's
true value for the curve to be considered
valid. The curve must be validated before
sample analyses are performed.
7.2.3 ICP Check Standards. Run a check
standard and a calibration blank after every
10 samples, and at the end of the analytical
run. Check standards can be the mid-range
calibration standard or the reference
standard. The results of the check standard
shall agree within 10 percent of the expected
value; if not. terminate the analyses, correct
the problem, recalibrate the instrument, and
rerun all samples analyzed subsequent to the
last accepeabhtcheck standard smafwet-nu
results of the calibration Wanft are- *> •».»",
within three, ssmdard de^fKms-of u^
Want «ahit If not; repeat the anafysfrewo
ocre-times and avenge the-resuhs. rTlhe- -•'.
average isnot withfe three-standard "•• -,
deviations oi the bacJsgroanrf near;.
terminate the analyses, correct the- probrenj.
recalibrate, and reanalyze aft samples
analyzed subsequent to the last acceptable
calibration blank analysis.
7.2.-5 ICP Duplicate SampBes. Analyze ona
duplicate sample- for erery 2O sarmptes, for
one-per source test, whichever rs more
frequent). Duplicate samples are. farougfil
through the- whofe- sample preparation and
analytical-process. Dnptrcate sarnptesshall
agree within 1» percent.
7.2.5 ICP Reagent Blank Samples.
Analyze- a. mjmmani o£ one matrix-matched
reagent blank (section 5.2.2) per sample batdi
to-detennLne: i£ contamination or memory-
effects are occurring. The results sisoubd
agree within three standard delations of the
mean blank ralue-
713 IC/PCR Qna^ty Co turot
7.3.1 IC/PCR Calibration Reference
Standards. Prepare a calibration refereace
standard in the same- atkaJEne- matrix as the
calibration standards at a concentration that
isat or near the mid-peintof the calibration
curve. This-reference standard should be
prepared Jrom a different Cr slock solution
source; than that used for preparing the
calibration curve.standards..The reference
standard is. used to- verify the. accuracy ct the
calibration curvet. Prior to sample anafysis,
analyze at least, one reference; standard. The
results of tins analysis of the reference
standard must be within KX percent of the-
true- value of the.reference standard for the
•calibration curve to be considered valid. The
curve must be validated before-sampie.
analyses, are performed-
7.3.2 IC/PCR Check Spaniards, (a; Run
the calibration blank and calibration
standards with trie faeldsampfes as described
rrr section 5.5. Fbreach standard^determine
the peak areas (recommended! or' the peal:
heights, calculate the average response from
the duplicate injections, and plot the average
response against the Crt-6 concentration in
ug/1. The individual responses for each
calibration standard determined before and
after field sample analysis must be within 5
percent of the average response for the
analysis to be.valid. If the 5 percent criteria .
is exceeded, excessive drift and/or
instrument degradation may have occurred.
and must be corrected before further analyses
are performed.
CD) Employing linear regression, calculates
predicted value for each calibration standard
using the average response for the duplicate
injections. Each predicted value must be •
within 7 percent of the actual value for the
calibration curve to be considered acceptable.
If not acceptable, remake and/or rerun the
calibration standards. If the calibration curve
is still unacceptable, reduce the range of the
curve. . '
7.3.3 IC/PCR Duplicate Samples. Analyze
one duplicate sample for every 20 samples,
(or one per source test, whichever is more
frequent). Duplicate samples are brought
through the whole sample preparation and
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4986 Federal Register-/ VoL 60,'No. 16 /-.Wednesday, -January 25, 1995V Kules and "Regulations-
analytical process. Duplicate samples shall
agree within 10 percent.
7.3.4 1CP Reagent Blank Samples.
Analyze a minimum of one matrix-matched
reagent blank (section 5.2.2) per sample batch
to determine if contamination or memory
effects are occurring. The results should
agree within three standard deviations of the
mean blank value.
8. Emission Calculations
Carry out the calculations, retaining one
extra decimal figure beyond that of the
acquired data. Round off figures after fina]
calculations.
8.1 Total Cr in Sample. Calculate Mo. the
total pg Cr in each sample, as follows:
Mo = (V^)(Cs)(F)(D)' Eq.306-1
where:
V'mi = Volume of impinger contents plus
rinses, ml. .
Cs = Concentration of Cr in sample solution,
|jg Cr/ml.
F = Dilution factor.
= Volume ofaliquol after dilution, ml:
Volume of aliquot before dilution, ml
D = Digestion factor.
= Volume of sample aliquot after digestion,
ml; Volume of sample aiiquot submitted
to digestion, ml
8.2 Average Dry Gas Meter Temperature
and Average Orifice Pressure Drop. Same as
Method 5, section 6.2.
8.3 Dry Gas Volume. Volume of Water
Vapor, Moisture Content. Same as Method 5,
sections 6.3, 6.4, and 6.5, respectively.
8.4 Cr Emission Concentration. Calculate
Co, the Cr concentration in the stack gas, in
rog/dscm on a dry basis, corrected to
standard conditions, as follows:
Co^lO-' mg/pg} (Mo/Vm.4U.,) Eq. 306-2
where:
Vm<,uj»=Gas sample volume measured by the
dry gas meter, corrected to dry standard
conditions, dscm.
8.5 Isokinetic Variation, Acceptable
Results. Same as Method 5, sections 6.11 and
6.12, respectively.
9. Bibliography
1. "Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods," U. S.
Environmental Protection Agency
Publication SW-846, 2nd Edition, July 1982.
2. Cox, X.B., R.W. Linton, and F-E. Butler.
Determination of Chromium Speciation in
Environmental Particles—A Multitechnique
Study of Ferrochrome Smelter Dust.
Accepted for publication in Environmental
Science and Technology.
3. Same as Bibliography of Method 5,
Citations 2 to 5 and 7."
4. California Air Resources Board,
"Determination of Total Chromium and
Hexavalent Chromium Emissions from
Stationary Sources." Method 425, September
12,1990.
5. "Test Methods for Evaluating Solid
Waste, Physical/ Chemical Methods", U. S.
Environmental Protection Agency
Publication SW-846, 3rd Edition, November
1986 as amended by Update I . November
1990.
Method 306A—Determination of Chromium
Emissions From Decorative and Hard
Chromium Electroplating and Anodizing
Operations
J. Applicability and Principle
1.1 Applicability. This method applies !o
the determination of chromium (Cr) in
emissions from decorative and hard
chromium electroplating facilities and
anodizing operations. The method is less
expensive and less complex to conduct than
Method 306 of this appendix. Correctly
applied, the precision and bias of the sample
results will be comparable to those obtained
with the isokinetic Method 306 of this
appendix. This method is applicable under
ambient moisture, air, and temperature
conditions.
1.2 Principle. A sample is extracted from
the source at a constant sampling rate
determined by a critical orifice and collected
in a probe and impingers. The sampling time
a: the sampling traverse points is varied
according to the stack gas velocity at each
po^nt to obtain a proportional sample. The
concentration is determined by the same
analytical procedures used in Method 306 of
this appendix: inductively-coupled plasma
emission spectrometry (1CP), graphite furnace
atomic absorption spectrometry (GFAAS), or
ion chroraatography with a post-column
reactor (IC/PCR).
2. Range, Sensitivity,.Precision, and
Interferences
Same as Method 306, section 2 of this
• appendix.
3. Apparatus
Note: Mention of trade names or specific
products does not constitute endorsement by
the Environmental Protection Agency.
3.1 Sampling Train. A schematic of the
sampling train is shown in Figure 306A-1.
The components of the train are available
commercially; but some fabrication and
assembly are required. If Method 306
equipment is available, the sampling train
may be assembled as specified in Method 306
of this appendix and the sampling rate of !he
meter box set at the delta Hg> specified for
the calibrated orifice; this train is then
operated as specified in this method.
3.1.1 Probe Nozzle/Tubing and Shealh.
Use approximately 1/4 in. inner diameter (ID)
glass or rigid plastic tubing about 6 in. long
with a short 90° bend at one end to form the
nozzle. Grind a slight taper on the nozzle end
before making the bend. Attach the nozzle lo
flexible tubing of sufficient length to collect
a sample from the stack. Use a straight piece
of larger diameter rigid tubing (such as metal
conduit or plastic water pipe) to form a
'sheath that begins about 1 in. from the 903
bend on the nozzle and encases the flexible
tubing.
BILLING CODE eSfiO-60-P
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Probe/Nozzlo Sheath Assombly
(1/4(1.D. Tubing) ' '
0.1 N NaOH
or
0.1 NNnHCO
Plastic Tubing
• ]
Critical Orifice
Mason Jar Implngers
Vacuum Gauge
(optional) ;
Temperature
Sensor
Vacuum ;. ; ;
Pump :• ; .
I
,1 :.,-.
I
§-
to
en
ID
5°
Cn
A
en
pj
3',
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4988 Federal Register / Vol. 60, No. 16 / Wednesday, January 25, 1995 /-Rules and Regulations
3.1.2 S-Type Pitot. Same as Method 2,
section 3 (40 CFR part 60, appendix A).
3.1.3 Sample Line. Use thick wall flexible
plastic tubiag'(e.g., polyethylene,
polypropylene, or polyvinylchloride) about
'A in. to Va in. ID to connect the train
components. A combination of rigid plastic
tubing and thin wall flexible tubing may be
used as long as neither tubing collapses wben
leak-checking the train. Metal tubing cannot
be used.
3.1.4 Irnpingers. One quart capacity
"Mason" glass canning jars with vacuum seal
lids are used. Three impingers are required:
the first is for collecting the absorbing
solution, the second is empty and is used to
collect any absorbing solution carried over
from the first impieger, and the third
contains the drying agent. Install bleak-tight
inlet and outlet tubes in the lids of each
irr.pinger for assembly with the train. The
tubes may be made of approximately 'A in.
ID glass or rigid plastic tubing. For the inlet
tube of the first impinger, heat the glass or
plastic tubing and draw until the tubing
separates. Cut the tip off until the tip orifice
is VD; in. in diameter. When fabricating the
firs! impinger. place the tip orifice Vie in.
above the bottom of the jar when assembled.
For the second irnpinger, the inlet rube need
not be drav.-n and sized, but the tip should
be approximately 2 in. above the bottom, of
the jar. The inlet tube of the third impinger
should extend to about 'A in. above the
bottom of the jar. Locate the outlet tube end
of all impingers about Vi in. beneath the
bottom of the lid.
3.1.5 Manometer. Inclined/vertical type,
or equivalent device, as described in section
2.2 of Method 2 (40 CFR part 60, eppecdix
A).
3.1.6 Critical Orifice. The critical orifice
is a small restriction in the sample line
(approximately Vie in. in diameter) that is
located upstream of the vacuum pump and
sets the sample rate at about 0.75 cfm. An
orifice can be made of ^12 in, brass tubing
approximately Vi* in. long sealed inside
larger diameter, approximately Vie in., brass
tubing to serve as a critical orifice giving a
constant sample flow. Materials other than
brass can be used to construct the critical
orifice as long as the flow through the
sampling train is approximately 0.75 cfen.
3.1.7 Connecting Hardware. Standard
pipe and fittings, V< in. or >A in., are used
to install the vacuum pump and dry gas
meter in the sampling train.
3.1.8 Pump Oiler. A glass oil reservoir ••
with a wick mounted at the vacuum pump
inlet lubricates the pump vanes. The oiler
should be an inline type and not vented to
the atmosphere.
3.1.9 Vacuum Pump. Cast Model 0522-
V103-G18DX, or equivalent, capable of
delivering at least 1.5 cfm at 15 in. Kg
vacuum.
3.1.10 Oil Trap. An empty glass oil
reservoir without wick is mounted at pump
outlet to prevent oil from reaching the dry
gas meter.
3.1.11 Dry- Gas Meter. A Rockwell model
175-s test meter, or equivalent, with a
thermometer installed to monitor meter
temperature. The dry gas meter must be
capable of measuring volume to within 2
percent.
3.2 Sample Recovery.
3.2.1 Wash Bottles. These are glass or
inert plastic, 500 or 1000 ml, with spray tabe.
3.2.2 Sample Containers. The first mason
jar impinger of the sampling train serves as
the sample container. A new lid and plastic
wrap are substituted for the impinger inlet/
outlet assembly.
3.3 Analysis. Same as Method 306, -
section 3.3 of this appendix.
J.
4.1 Sampling. Same as Method 306,
section 4.1 of this appendix.
4.2 Sample Recovery. Same as Method
306, section 4.2 of this appendix.
5. Procedure
5.1 Sampling.
5.1.1 Pretest Preparation.
5.1.1.1 Port Location. Locate the sampling
ports as specified in section 2.1 of Method 1
(40 CFR part 60, appendix A).Use a total of
24 sampling points for round ducts and 25
points for rectangular ducts. Locate the
sampling points as specified in section 2.3 of
Method 1 (40 CFR part 60, Appendix A).
Mark the pilot and sampling probe with thin
strips of tape to permit velocity and sample
traversing. For ducts less than 12 in. in
diameter, use a total of 16 points.
5.1.1.2 Velocity Pressure Traverse, (a)
Perform a velocity pressure traverse before
the first sample run. Figure 306A-2 may be
used to record velocity pressure data. If
testing occurs over several days, perform the
traverse at the beginning of each day. Perform
velocity pressure traverses as specified in
section 3 of Method 2 (40 CFR part 60,
appendix A), but record only the Ap (velocity
head) values for each sampling point.
(b) Check for cyclonic flow during the first
traverse to verify that it does not exist; if
cyclonic flow does exist.'make sure that the
absolute average angle of misalignment does
not exceed 20°. If the average angle of
misalignment exceeds 20° at an outlet
location, install straightening vanes to
eliminate the cyclonic flow. If it is necessary
to test an inlet location where cyclonic flow
exists, it may not be possible to install
straightening vanes. In this case, a variation
of the alignment method must be used. This
must be approved by the Administrator.
BILLING CODE «S«0-40--P
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Federal Register / Vol. 60. No. 16 / Wednesday. j^. 2 5 , ^^ ^ Reguiations
Plant.
Date.
Time
Location _
Operators) --
Beginning slack temperature, *F-
stack temperature, *F -
Average stack temperature, °E
Schematic of Points
Circle one:
Before Run I
Before Run 2
Before Run 3
After Run No.
Traverse
Point
Number
Cyclonic
Flow
Angle
(Degrees)
Ap
V2p
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4990 Federal Roister / Vol. 60, No. 16 / Wednesday. January 25, 1995 / Kuies and Regulations
5 : 1.3. Point Sampling Times. Since the
sampling rare-of the train is hefd constant by
the criricai orifice, it is necessary to calculate
specific sampling times far each point in
order to obtain a proportional sample If a!!
sampling can be completed in a single day,
it ii necessary to calculate the point sampling
times only once. II" sampling occurs over
several days, recalculate the point sample
times each day usin-3 velocity traverse data
•obtained earlier in ihe-day Determine the
average of the Ap values obtained dicing the
velocity traverse (Figure. 3C6A-2). Calculate
the samplirtR times for each point using
Equation 306A-1 Convert lie decimal par;s
of minutes to seconds, if the stack diameter
is less than 12 in., we 7.5 minu-ies in place
of 5 minutes :3 the equation and 16 sampling
points.
JPoint n Ap
Minutes at point n = • x5 minutes E
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Federal Register / Vol.- 60
.' No. 16 J Wednesday. January 25
-- * '
Stark radius, r. in
Ayg sq. rt. Ap,
Total Cr catch, M
Avg dry gas meter temp, T
r-> ID'
Meter correction factor,
Meter volume, Vffl, fp.
Barometric press, I
Start crock thne
Stop clock time
, b. Hg.
Irak nle before run, cfm_
Leak rate after run, cfm_
Stop "meter volume, fr _
Start meter volume, ft^ _
REMARKS:
Poini No.
Sample
(Mia'Sec)
Gas Meter
Temp(eF)
"
ffl + 460)
Point No.
Sample
(Min/Sec) ''
-
Gas Meter
TempCF)
(499.6)
j (VJ (P
AST'
(0.0001597)
:(TS
(28.73)
mg'cubic meter,
(Optiooal) -kg.lir
figure 30SA-3. Chronrium Constant Sampling Hate Field
Data Sheet,
BILLING CODE AMO-SO-C
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4992 Federal Register-/ Vol. 60.'No.'16 /Wednesday. January 25. 1995 / Rules and Regulations
5.1.2.2 • Place the probe/nozzle into the
duct a! the first sampling point and turn on
the pump. A minimum vacuum of 15 in. Hg
or 0.47 atmosphere between the critical
orifice and pump is required to maintain
critical flow. Sample for the time interval
previously determined for that point. Move
to the second point and sample for the time
interval determined for that point; sample all
points on the traverse in this manner. Keep
ice around the impingers during the run.
Complete the traverse and turn off the pump.
Move to the next sampling port and repeat.
Record the final dry gas meter reading.
(NOTE: If an approximate mass emission rate
is desired, record the stack temperature
before and after the run.)
5.1.2.3 Post Test Leak Check. Remove the
probe assembly and flexible tubing from the
first irnpinger. Do not cover the nozzle. Seal
the inle; tube of the first impinger with a.
finger covered by clear plastic wrap and turn
on the pump. The vacuum in the line
between the pump and the critical orifice
must be at least 15 in. Hg. Observe any leak
rate on the dry gas meter. If the leak rate
exceeds 0.02 cfm. reject the run. If the leak
rate is acceptable, take the probe assembly
and impinger assembly to the sample
recovery area.
5.2 Sample Recovery.
5.2.1 Container No. 1. (a) After the train
has been moved to the sample recovery area,
disconnect the tubing that joins the first
impinger with the second.
(b) The first impinger jar is also used as the
sample container jar. Unscrew the lid from
the first impinger jar. Lift the inlet/outlet
tube assembly almost out of the jar, and using
the wash bottle, rinse the outside of the
impinger tip that was immersed in the
impinger jar with extra absorbing solution.
rinse the inside of the tip zs well.
(c) Recover the second impinger by .
removing the lid and pouring any contents
from the second impinger into the first
impinger. Rinse the second impinger
including the inside and outside of the
impinger stem as well as any connecting
plastic tubing with extra absorbing solution
and place the rinse into the first impinger.
(d) Hold the nozzle and connecting plastic
tubing in a vertical position so that the tubing
forms a "U." Using the wash bottle, partially
fill the tubing with sampling reagent. Raise
and lower the end of the plastic tubing
several times to cause the reagent to contact
the major portion of the internal parts of the
assembly thoroughly. Do not raise the
solution level too high or part of the sample
will be lost Place the nozzle end of the
assembly over the mouth of the first impinger
jar (sample container) and elevate the plastic
tubing so that the solution flows rapidly out
of the nozzle. Perform this procedure three
times. Next, repeat the recovery procedure
but allow the solution to flow rapidly out the
open end of the plastic tubing into the first
impinger jar.
(e) Place a piece of clear plastic wrap over
the mouth of the first impinger jar. Use a
standard lid and band assembly to seal the
jar. Label the jar with the sample number and
mark the liquid level to gauge any losses
during handling.
5.2.2 Container No. 2 (Reagent Blank).
Place approximately 500 ml of the 0.1 N
NaOH or 0.1 N NaHCOj absorbing solution
in a labeled sample container.
5.2.3 Sample Filtration for IC/PCR. If the
sample is to be analyzed for Cr*« by IC/PCR,
it must be filtered immediately following
recover.' as described in section 5.2.3 of
Method 306 of this-appendix.
5.3 Analysis. Sample preparation and
analysis procedures are identical to Method
306, section 5.3 of this appendix.
6. Calibration
6.1 Dry Gas Meter, (a) Dry gas meter
calibrations may be performed by either the
manufacturer, a firm who provid'es
calibration services, or the tester. The dry ges
meter calibration coefficient (Ym) must be
determined prior to initial use of the meter.
and must be checked following each field
use.
(b) If the dry gas meter is new, the
manufacturer will have specified the Ym for
the meter. The manufacturer may also have
included a calibration orifice and a data sheet
with the meter that may be used for
calibration purposes. The sheet will specify
a standard cubic foot volume and a sample
time, and these values were determined
when the orifice was used to set the initial
Ym for the meter. The Ym may be checked by
disconnecting the critical orifice in the
sampling train and replacing it with the
calibration orifice. The inlet side of the
calibration orifice is open to the atmosphere
and is.not reconnected to the sample train.
Record the initial dry gas meter volume and
meter temperature. Turn on the pump and
operate it for the number of minutes
specified by the manufacturer's data sheet.
Stop the pump and record the final dry gas
meter volume and temperature. Subtract the
start volume from the stop volume and
average the temperatures. Check the Ym for
the dry gas meter after the test by using the
following equation:
= Ft.3m(Tm+460)
I7.647(Ft3P,)(Ptar)
Where:
Ft.:!m=Cubic feet given by meter manufacturer
Tm=Ternperat-jre of meter in degrees
Fahrenheit
Ft3p,=Cubic fe«t from dry gas meter, post test
Pbir= Barometric pressure in inches of
mercury
Compare the Ym just calculated with the
Ym given by the manufacturer:
Y (manufacturer)
Ym (calculated after test)
If this value is between 0.95 and 1.05, the
Ym of the meter is acceptable. If the value lies
outside the specified range, the test series
shall either be voided, or calculations for the
test series shall be performed using
whichever meter coefficient value (i.e., before
and after) that gives the lower value of total
sample volume. Return the dry gas meter to
the manufacturer for recalibration. The
calibration may also be conducted as
specified in section 5.3.1 or section 7 of
Method 5 (40 CFR part 60. appendix A).
except that it is only necessary to check the
calibration at an approximate flow rate of
0.75 cfm. The calibration of the dry gas meter
must be checked after each field use in the
same manner. If the values of Ym obtained
before and after a test series differ by more
than 5%, the test series shall either be
voided, or calculations for the test series
shall be performed using whichever meter
coefficient value (i.e., before or after) that
gives the lower value of total sample volume.
6.2 GFAA Spectrometer. Same as Method
306, section 6.2 of this appendix
6.3 ICP Spectrometer. Same as Method
306, section 6.3 of this appendix
7. Quality Control
Same as Method 306, section 7 of this
appendix.
8. Calculations
8.1 Pollutant Concentration. Calculate
Co, the Cr concentration in the stack gas, in
mg/dscrn on a dry basis as follows:
(499.8) (1
Eq.306A-2
Mcr=Amount of Cr in sample from Method
• 306 of this appendix, Eq. 306-1, ug.
Tm=Dry gas meter temperature, CF.
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Federal Register / Vol. 60, No. 16 / Wednesday. January.25. 1995 / Rules and Regulations
4993
Ym=Dry gas meter correction factor.
dimeasiordess.
gas meter volume, ft5.
Pa^Barometric pressure, in. Hg.
8.2 Approximate Mass Emission Rate
(Optional). Calculate an approximate mass
emission rate of Cr in kg/hr using the
following equation:
= (0.0001 597) (C0
*• A o
-r460)
'
) (28.73)
Eq.306A-3'
w r, s re:
r=Radius of stack, in.
(v'ip),Yi=Average of Vip values.
Ts=Stack temperature, °F.
Po^Barometric pressure, in. Hg.
Ccr=Concentration of Cr, mg/dscm.
Note: The emission rate calculated using
Equation 306A-3 is based on an assumed
moisture content of 2%.
9. Bibliography
1. Clay. F.R. Memo, Impiager Collection
Efficiency—Mason Jars vs. Creenburg-Smiih
Irr.pingers. Dec. 1989.
2. Segal!. R.R., VV.C. DeWees. F.R. Clay,
and J.W. Brown. Development of Screening
Methods for Use in Chromium Emissions
Measurement and Regulations Enforcement.
In: Proceedings of the 1939 EPA/A&WMA
International Symposium—Measurement of
Toxic and Related Air Pollutants, AiWMA
Publication VIP-13, EPA Report No. 600/9-
89-060. p. 785.
3. Clay. F.R. Chromium Sampling Method.
In: Proceedings of the 1990 EPA/AiWMA
International Symposium—Measurement of
Toxic and Related'Air Pollutants. A&VVMA
Publication VIP-17. EPA Report No. €00/9-
90-026. p. 576.
•4. Clay. F.R. Proposed Sampling Method
306A for the Determination of Hexavalent
Chromium Emissions from Electroplating
and Anodizing Facilities. In: Proceedings of
the 1992 EPAM&WMA International
Symposium—Measurement of Toxic and
Related Air Pollutants. A&WMA Publication
VIP-25. EPA Report No. 600/R-92/131, p.
209.
Method 306-E—Surface Tension
Measurement and Recordkeeping for
Chromium Plating Tanks Used at
Electroplating and Anodizing Facilities
!. Applicability and Principle
1.1 Applicability. This method is
applicable to all decorative plating and
anodizing operations where a wetting agent
is used in the tank as the primary mechanism
for reducing emissions from the surface of
the solution.
1.2 Principle. During an electroplating or
anodizing operation, gas bubbles generated
during the process rise to the surface of the
tank liquid and burst. Upon bursting, tiny
droplets of chromic acid become entrained in
ambient air. The addition of a wetting agent
to the tank bathreduces the surface tension of
the liquid and diminishes the formation of
these droplets.
2. Apparatus
2.1 Stalagrnometer. Any commercially
available stalagmometer or equivalent surface
tension measuring device may be used to .
measure the surface tension of the plating or
anodizing tank liquid.
2.2 Preciser tensiometer. A Preciser
tensiometer may be used to measure the
surface tension of the tank liquid provided
the procedures specified in ASTM Method D
1331-69. Standard Test Methods for Surface
and Interfacial Tension of Solutions of
Surface Active Agents (incorporated by
reference—see § 63.14) are followed.
3. Procedure
3.1 The surface tension of ths tank bath
may be measured by using a Preciser
teasiometer. a stalagmometer or any other
device suitable for measuring surface tension
in dynes per centimeter. If the Preciser
tensiometer is used, the instructions given in
ASTM Method D 1331-B9, Standard Test
Methods for Surface and Interfacial Tension
of Solutions of Surface Active Agents
(incorporated by reference—see § 63.14) must -
be followed. If a Stalagrnometer or other
device is used to measure surface tension, the
instructions that came with the measuring
device must be followed.
3.2 (a) Measurements of the bath surface
tension are done using a progressive system
which minimizes the number of surface
tension measurements required when the
proper surface tension is maintained.
Initially, measurements must be made every
•4 hours of tank operation for the first 40
hours of tank operation after the compliance
date. Oace there are no exceedacces during
40 hours of tank operation, measurements
may be conducted once every 8 hours of tank
operation. Once there are no exceedances
during 40 hours of tank operation.
measurements may be conducted once every
40 hours of tank operation on an on-going
basis, until an exceedance occurs. The
maximum time interval for measurements is
once every 40 hours of tank operation.
(b) If a measurement of the surface tension
of the solution is above the 40 dynes per
centimeter limit, the lime interval reverts
back to the original monitoring schedule of
once every 4 hours. A subsequent decrease in
frequency would then be allowed according
to the previous paragraph.
•i. Recordkseping
4.1 Log book of surface tension
measurements and fume suppressant
additions. The surface tension of the platir.g
or anodizing tank bath must be measured as
specified in section 3.2. The measurements
must be recorded in the log book. In additio:
to the record of surface tension
measurements, the frequency of fume
suppressant maintenance additions and the
amount of fume suppressant added during
each maintenance addition will be recorded
in the log book. The log book will be readily
available for inspection by regulatory'
personnel.
4.2 Instructions for apparatus used i:1.
measuring surface tension. Also included
with the log book must be a copy of the
instructions for the apparatus used for
measuring the surface tension of the plating
or anodizing bath. If a Preciser tensiometer is
used, a copy of ASTM Method D 1331-89,
Standard Methods for Surface and Interfacia!
Tension of Solutions of Surface Active
Agents (incorporated by reference—see
§ 63.14) must be included with the log book.
[FR Doc. 95-65 Filed 1-24-95: 6:45 anil
BILLING CODE 6S60-SO-P
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APPENDIX B
GLOSSARY OF TERMS
-------
APPENDIX B
GLOSSARY OF TERMS
Add-on air pollution control device
(APCD) means equipment installed in the
ventilation system of chromium electroplating
and anodizing tanks for the purposes of
collecting and containing chromium emissions
from the tank(s).
Administrator means the Administrator of
the United States Environmental Protection
Agency or his or her authorized representative
(e.g., a State that has been delegated the
authority to implement the provisions of
40 CFR part 63).
Air pollution control technique means any
method, such as an add-on air pollution control
device or a chemical fume suppressant, that is
used to reduce chromium emissions from
chromium electroplating and chromium
anodizing tanks.
Area source means any stationary source of
hazardous air pollutants that is not a major
source as defined below in this appendix.
Another term for area source is "nonmajor
source."
Base metal means the metal or metal alloy
that comprises the workpiece.
Bath component means the trade or brand
name of each component(s) in trivalent
chromium plating baths. For trivalent chromium
baths, the bath composition is proprietary in
most cases. Therefore, the trade or brand name
for each component(s) can be used; however, the
chemical name of the wetting agent contained in
that component must be identified.
Chromic acid means the common name for
chromium anhydride
Chromium anodizing or chromic acid
anodizing means the electrolytic process by
which an oxide layer is produced on the surface
of a base metal for functional purposes (e.g.,
corrosion resistance or electrical insulation)
using a chromic acid solution. In chromium
anodizing, the part to be anodized acts as the
anode in the electrical circuit, and the chromic
acid solution, with a concentration typically
ranging from 50 to 100 grams per liter (g/L),
serves as the electrolyte.
Chromium electroplating or chromium
anodizing tank means the receptacle or container
in which hard or decorative chromium
electroplating or chromium anodizing occurs.
Composite mesh-pad (CMP) system means
an add-on air pollution control device typically
consisting of several mesh-pad stages. The
purpose of the first stage is to remove large
particles. Smaller particles are removed in the
second stage, which consists of the composite
mesh pad. A final stage may remove any
reentrained particles not collected by the
composite mesh pad.
Decorative chromium electroplating means
the process by which a thin layer of chromium
(typically 0.003 to 2.5 microns) is
electrodeposited on a base metal, plastic, or
undercoating to provide a bright surface with
wear and tarnish resistance. In this process, the
part(s) serves as the cathode in the electrolytic
cell and the solution serves as the electrolyte.
Typical current density applied during this
Page B-l
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GLOSSARY OF TERMS
APPENDIX B
process ranges from 50 to 220 Amperes per
square feet (A/ft2) for total plating times ranging
between 0.5 to 5 minutes.
Electroplating or anodizing bath means the
electrolytic solution used as the conducting
medium in which the flow of current is
accompanied by movement of metal ions for the
purposes of electroplating metal out of the
solution onto a workpiece or for oxidizing the
base material.
Emission limitation means, for the
purposes of this regulation, the concentration of
total chromium allowed to be emitted expressed
in milligrams per dry standard cubic meter
(mg/dscm), or the allowable surface tension
expressed in dynes per centimeter (dynes/cm).
Facility means the major or area source at
which chromium electroplating or chromium
anodizing is performed.
Fiber-bed mist eliminator (FEME) means
an add-on air pollution control device that
removes contaminants from a gas stream through
the mechanisms of inertial impaction and
Brownian diffusion. These devices are typically
installed downstream of another control device,
which serves to prevent plugging, and consist of
one or more fiber beds. Each bed consists of a
hollow cylinder formed from two concentric
screens; the fiber between the screens may be
fabricated from glass, ceramic plastic, or metal.
Foam blanket means the type of chemical
fume suppressant that generates a layer of foam
across the surface of a solution when current is
applied to that solution.
Fresh water means water, such as tap
water, that has not been previously used in a
process operation or, if the water has been
recycled from a process operation, it has been
treated and meets the effluent guidelines for
chromium wastewater.
Fume suppressant (FS) means any
chemical agent that reduces or suppresses fumes
or mists at the surface of an electroplating or
anodizing bath; other terms for fume suppressant
are chemical fume suppressant and mist suppres-
sant.
Hard chromium electroplating or industrial
chromium electroplating means a process by
which a thick layer of chromium (typically 1.3
to 760 microns) is electrodeposited on a base
material to provide a surface with functional
properties such as wear resistance, a low
coefficient of friction, hardness, and corrosion
resistance. In this process, the part serves as the
cathode in the electrolytic cell and the solution
serves as the electrolyte. Hard chromium
electroplating process is performed at current
densities typically ranging from 150 to 600 A/ff
for total plating times ranging from 20 minutes
to 36 hours depending upon the desired plate
thickness.
Hexavalent chromium means the form of
chromium in a valence state of +6.
Large, hard chromium electroplating
facility means a facility that performs hard
chromium electroplating and has a maximum
cumulative potential rectifier capacity greater
*
than or equal to 60 million ampere-hours per
year (amp-hr/yr).
Page B-2
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APPENDIX B
GLOSSARY OF TERMS
Major source means any stationary source
or group of stationary sources located within a
contiguous area and under common control that
emits or has the potential to emit considering
controls in the aggregate, 10 tons per year or
more of any hazardous air pollutant, or 25 tons
per year or more of any combination of
hazardous air pollutants.
Maximum cumulative potential rectifier
capacity means the summation of the total
installed rectifier capacity associated with the
hard chromium electroplating tanks at a facility,
expressed in amperes, multiplied by the
maximum potential operating schedule of
8,400 hours per year and 0.7, which assumes
that electrodes are energized 70 percent of the
total operating time. The maximum potential
operating schedule is based on operating
24 hours per day, 7 days per week, 50 weeks
per year.
Operating parameter value means a
minimum or maximum value established for a
control device or process parameter which, if
achieved by itself or in combination with one or
more other operating parameter values,
determines that an owner or operator is in
continual compliance with the applicable
emission limitation or standard.
Packed-bed scrubber (PBS) means an add-
on air pollution control device consisting of a
single or double packed bed that contains
packing media on which the chromic acid
droplets impinge. The packed-bed section of the
scrubber is followed by a mist eliminator to
remove any water entrained from the packed-bed
section.
Research or laboratory operation means an
operation whose primary purpose is for research
and development of new processes and products,
that is conducted under the close supervision of
technically trained personnel, and that is not
involved in the manufacture of products for
commercial sale in commerce, except in a
de minimis manner.
Small, hard chromium electroplating
facility means a facility that performs hard
chromium electroplating and has a maximum
cumulative potential rectifier capacity less than
60 million amp-hr/yr.
Stalagmometer means a device used to
measure the surface tension of a solution.
Surface tension means the property, due to
molecular forces, that exists in the surface film
of all liquids and tends to prevent liquid from
spreading (expressed in dynes/cm).
Tank operation means the time in which
current and/or voltage is being applied to a
chromium electroplating tank or a chromium
anodizing tank.
Technology Transfer Network (TTN)
means a network of electronic bulletin boards
developed and operated by EPA's Office of Air
Quality Planning and Standards. The network
provides information and technology exchange in
different areas of air pollution control, ranging
from emission test methods to regulatory air
pollution models. The service is free, except for
the cost of the phone call. The TTN may be
accessed from a computer through the use of a
modem and communications software.
Page B-3
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GLOSSARY OF TERMS APPENDIX B
Tensiometer means a device used to
measure the surface tension of a solution.
Trivalent chromium means the form of
chromium in a valence state of +3.
Trivalent chromium process means the
process used for electrodeposition of a thin layer
of chromium onto a base material using a
trivalent chromium solution instead of a chromic
acid solution.
Wetting agent means the type of chemical
fume suppressant that reduces the surface tension
of a liquid.
Page B-4
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APPENDIX C
LIST OF KNOWN FACILITIES
-------
APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION*
CHROME DEPOSIT, AL
UNITED CHAIR CO, IRONDALE, AL
HAGER HINGE COMPANY, MONTGOMERY, AL
JR SMITH MFC, MONTGOMERY, AL
MONROE AUTO EQUIPMENT, PARAGOULD, AR
OSBORN PRODUCTS, INC, PHOENIX, AZ
TREFFERS PRECISION, INC, PHOENIX, AZ
MCCLELLAN AFB, CA
ROLL TECH WEST, CA
NAVAL AVIATION DEPOT, ALAMEDA, CA
PEMACO METAL PROCESSING, ALHAMBRA, CA
SCIENTIFIC HARD CHROME PLATING, ALHAMBRA, CA
AMERICAN PRECISION METAL WORKS, ANAHEIM, CA
CANYON PRECISION PLATING, ANAHEIM, CA
PORTER PLATING CO, INC, ANAHEIM, CA
PRECISION ANODIZING & PLATING, ANAHEIM, CA
ROCKWELL INTERNATIONAL, ANAHEIM, CA
TECHPLATE ENGINEERING, ANAHEIM, CA
BROTHERS PLATING, AZUSA, CA
OPTICAL RADIATION CORPORATION, AZUSA, CA
A & A PLATING, BAKERSFIELD, CA
AC PLATING, BAKERSFIELD, CA
BAKERSFIELD CHROME & BUMPER, BAKERSFIELD, CA
BROOKSHIRES PLATING, BAKERSFIELD, CA
STANDAFER ENTERPRISES, BALDWIN PARK, CA
CHROME CRANKSHAFT CO, BELL GARDENS, CA
DYNA-CHROME ENGINEERING, BELL GARDENS, CA
J & S CHROME PLATING CO, INC, BELL GARDENS, CA
MODEL PLATING CO, INC, BELL GARDENS, CA
ELECTRO-COATINGS INC, BERKELEY, CA
LAWRENCE BERKELEY LABORATORY, BERKELEY, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-l
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LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION**
3EVERLY HILLS PLATING WORKS, BEVERLEY HILLS, CA
WEST COAST PLATING, BUELLTON, CA
A-H PLATING, BURBANK, CA
ACCESSORY PLATING, BURBANK, CA
AVIALL, INC, BURBANK, CA
CARTER PLATING, BURBANK, CA
CRANE CO, HYDRO-AIRE DIVISION, BURBANK, CA
KAHR BEARING, BURBANK, CA
LOCKHEED CALIFORNIA CO, BURBANK, CA
MAGNA PLATING CO, INC, BURBANK, CA
MENASCO OVERHAUL DIVISION, BURBANK, CA
MESTAS PLATING, BURBANK, CA
SPENCE ELECTRO PLATING CO, BURBANK, CA
SUN ART PLATING CO, BURBANK, CA
CHATSWORTH PLATING CORP, CANOGA PARK, CA
ROCKWELL INTERNATIONAL CORP, CANOGA PARK, CA
ROHR INDUSTRIES INC, CHULA VISTA, CA
CONSOLIDATED DEVICES, INC, CITY OF INDUSTRY, CA
PLATO PRODUCTS INC, CITY OF INDUSTRY, CA
SPECIALIZED HARD CHROME, CLOVIS, CA
EMPIRE PLATING INC, COLTON, CA
ALLIED PLATING WORKS, COMPTON, CA
BOWMAN PLATING CO, COMPTON, CA
CAL-STYLE FURNITURE MFC CO, COMPTON, CA
S & K PLATING, INC, COMPTON, CA
LE MANS PLATING INC, CORONA, CA
BROWN INTERNATIONAL CORP, COVINA, CA
CACO PACIFIC CORP, COVINA, CA
INTERMETRO INDUSTRIES, CUCAMONGA, CA
ROBERT MFC CO, CUCAMONGA, CA
MCDONNELL DOUGLAS HELICOPTERS, CULVER CITY, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-2
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APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
PACIFIC PISTON RING CO, INC, CULVER CITY, CA
BRICO METAL FINISHING, DOWNEY, CA
FEDERAL-MOGUL CORP, DOWNEY, CA
JAYDIE, DOWNEY, CA
SPECIALIZED PROCESSING CO, INC, EL CAJON, CA
CENTRAL PLATING SERVICE, EL MONTE, CA
CROWN CITY PLATING CO, EL MONTE, CA
EL MONTE PLATING CO, EL MONTE, CA
FIELD MANUFACTURE CORP, EL SEGUNDO, CA
GAR HONING SERVICE, INC, EL SEGUNDO, CA
SUPERIOR QUALITY PLATING INC, EL SEGUNDO, CA
WYREFAB INC, EL SEGUNDO, CA
CHROMEX, EMERYVILLE, CA
ANODIZING SPECIALIST, ESCONDIDO, CA
ROBBINS & MYERS, FAIRFIELD, CA
RUTTER ARMEY, FRESNO, CA
KRYLER CORP, FULLERTON, CA
PCA METAL FINISHING INC, FULLERTON, CA
WESTERN ROTO ENGRAVERS INC, FULLERTON, CA
ANGELUS PLATING WORKS, GARDENA, CA
JAMES G. LEE RECORD PROCESSING, GARDENA, CA
LOS ANGELES PLATING, GARDENA, CA
DRILUBE COMPANY, GLENDALE, CA
ITT GENERAL CONTROLS, GLENDALE, CA
PENNOYER-DODGE CO, GLENDALE, CA
PLATO PRODUCTS, GLENDORA, CA
BUMPERLINE INC, HARBOR CITY, CA
DYNAMARK, LTD, HARBOR CITY, CA
QUALITY HARDWARE MFC CO, HAWTHORNE, CA
VEILING PLATING CO, INC, HOLLYWOOD, CA
ANO D' ART INC, HUNTINGTON BEACH, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-3
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LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION*
PRODUCTION PLATING, HUNTINGTON BEACH, CA
TARBY INC, HUNTINGTON BEACH, CA
WEISER LOCK CO, HUNTINGTON BEACH, CA
CHROMPLATE CO, INGLEWOOD, CA
MICROPLATE CO INC, INGLEWOOD, CA
PRINTRONK, IRVINE, CA
STERLING ELECTRIC, INC, IRVINE, CA
LA HABRA PLATING CO, LA HABRA, CA
EQUALITY PLATING CO, LA MESA, CA
SIGMA PLATING CO, LA PUENTE, CA
SIZE CONTROL PLATING CO, LA PUENTE, CA
LAWRENCE LIVERMORE NATL LAB, LIVERMORE, CA
VALLEY IND INC, LODI, CA
CAL BUMPER CO, INC, LONG BEACH, CA
DOUGLAS AIRCRAFT, LONG BEACH, CA
LONG BEACH PLATING, LONG BEACH, CA
NAVAL SHIPYARD/P.W./ENGR, LONG BEACH, CA
NOVA TECHNO CORP, LONG BEACH, CA
U.S. CHROME CORP OF CALIF, LONG BEACH, CA
ACE PLATING COMPANY INC, LOS ANGELES, CA
ACME METAL FINISHING, LOS ANGELES, CA
ALL AMERICAN MANUFACTURING, LOS ANGELES, CA
AMERICAN ELECTROPLATING, LOS ANGELES, CA
ANGELUS SANITARY CAN MACHINE, LOS ANGELES, CA
ARROWHEAD BRASS PRODUCTS, LOS ANGELES, CA
AUTOMOTIVE BATTERY PRODUCTS CO, LOS ANGELES, CA
BARRY AVENUE PLATING CO, INC, LOS ANGELES, CA
BATHROOM JEWELERY INC, LOS ANGELES, CA
BRTTE PLATING CO INC, LOS ANGELES, CA
BRONZE WAY PLATING CORP, LOS ANGELES, CA
BUMPER SHOP, LOS ANGELES, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
PageC-4
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APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION*
CALIFORNIA ELECTRO PLATING, LOS ANGELES, CA
CALIFORNIA METAL PROCESSING CO, LOS ANGELES, CA
CERTIFIED CADMIUM PLATING WORK, LOS ANGELES, CA
CHAS P. YOUNG, LOS ANGELES, LOS ANGELES, CA
CHEMPLATE CORPORATION, LOS ANGELES, CA
CHROMAL PLATING CO, LOS ANGELES, CA
CONTINENTAL AIRLINES, LOS ANGELES, CA
CUSTOM PLATING CORP, LOS ANGELES, CA
ELECTROL1ZING, INC, LOS ANGELES, CA
EXCELLO PLATING CO, INC, LOS ANGELES, CA
FAITH PLATING CO, LOS ANGELES, CA
GENE'S PLATING WORKS, LOS ANGELES, CA
HARDEN INDUSTRIES, LOS ANGELES, CA
HENRY SOSS & CO INC, LOS ANGELES, CA
IDEAL PLATING, LOS ANGELES, CA
METCOR MFC, LOS ANGELES, CA
MODERN PLATING CO, LOS ANGELES, CA
MULTICHROME CO INC, LOS ANGELES, CA
NU-WAY PLATING CO, LOS ANGELES, CA
PHYLRICH INTERNATIONAL, LOS ANGELES, CA
ROYAL PLATING WORKS CO, LOS ANGELES, CA
SERVICE PLATING CO, INC, LOS ANGELES, CA
STANDARD NICKEL CHROMIUM PLATING, LOS ANGELES, CA
STANDARD PLATING, LOS ANGELES, CA
SUPERCHROME PLATING & ENGR CO, LOS ANGELES, CA
V&M PLATING, LOS ANGELES, CA
VALLEY PLATING WORKS INC, LOS ANGELES, CA
VIRCO MFC CORP, LOS ANGELES, CA
ALAMEDA PLATING & POLISHING, LYNWOOD, CA
CHROME NICKEL PLATING, LYNWOOD, CA
L.G. TURNER HARD CHROME PLATING, LYNWOOD, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-5
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LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION"
MCDONNELL DOUGLAS ELECTRONIC SYSTEMS CO, MONROVIA, CA
THE CHROME SHOP, NAPA, CA
LEMON GROVE PLATING INC, NATIONAL CITY, CA
WESTERN INDUSTRIAL & MARINE, NATIONAL CITY, CA
NEWPORT PLATING, NEWPORT BEACH, CA
ALLIED/BENDK ELECTRODYNAMICS, NORTH HOLLYWOOD, CA
CASA DE CHROME, NORTH HOLLYWOOD, CA
WESTERN PLATING, NORTH HOLLYWOOD, CA
J&K AEROCHROME, NORWALK, CA
LOGO PARIS, NOVATO, CA
BARRETT METAL FINISHING INC, OAKLAND, CA
CAL TECH METAL FINISHERS, OAKLAND, CA
DOLSBY INC, OAKLAND, CA
ESPOSITO PLATING CORP, OAKLAND, CA
JOHNSON PLATING WORKS INC, OAKLAND, CA
K L PLATING CO, OAKLAND, CA
ALUMIN-ART PLATING CO, ONTARIO, CA
DYNAMARK, ONTARIO, CA
GARY'S GRINDING & HARD CHROME, ONTARIO, CA
KEYSTONE PLATING, ONTARIO, CA
TMC PLATING, ONTARIO, CA
ORANGE COUNTY PLATING CO INC, ORANGE, CA
PAMARCO PACIFIC INC, ORANGE, CA
LIMON METAL FINISHING, OXNARD, CA
MULITCHROME-OXNARD PLATING DIV, OXNARD, CA
PRICE PFISTER, INC, PACOIMA, CA
G.Q.I. CLASSIC, PALM SPRINGS, CA
CALIFORNIA POLISHING & PLATING, PARAMOUNT, CA
LEAvrrrs METAL FINISHING, PARAMOUNT, CA
WALLY'S METAL POLISH & PLATE, PARAMOUNT, CA
MONITOR POLISHING & PLATING, PASADENA, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
PageC-6
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APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION*
USS-POSCO INDUSTRIES, PITTSBURG, CA
CHROME MASTERS PLATING CO, POMONA, CA
HOOKER INDUSTRIES, POMONA, CA
PACIFIC POLISHING AND PLATING, POMONA, CA
POLYCHROME-METALLURGISTS, REDWOOD CITY, CA
ELECTRO FORMING CO, RICHMOND, CA
BIGGERS INDUSTRIAL GERLINGER, SACRAMENTO, CA
CHROME-CRAFT, SACRAMENTO, CA
PRECISION PLATING & GRINDING, SACRAMENTO, CA
HOAK BROS PLATING, SAN BERNADINO, CA
CALIFORNIA PLATING, SAN CARLOS, CA
INDUSTRIAL PLATING CO, INC, SAN CARLOS, CA
AEROSPACE COATINGS & TECHNOLOGY, SAN DIEGO, CA
CALIFORNIA PLATING, SAN DIEGO, CA
GENERAL DYNAMICS, CONVAIR DIV, SAN DIEGO, CA
KEYSTONE AUTOMOTIVE IND INC, SAN DIEGO, CA
MASTER PLATING, SAN DIEGO, CA
PACIFIC PLATING, SAN DIEGO, CA
WEST COAST PLATING (S.D.), SAN DIEGO, CA
CROPPER'S PLATING CO, SAN DIMAS, CA
CALIFORNIA TECHNICAL PLATING, SAN FERNANDO, CA
SANTEE IND, SAN FERNANDO, CA
C & M PLATING WORKS, SAN FRANCISCO, CA
J & J PLATING WORKS, SAN FRANCISCO, CA
UNITED AIRLINES MAINTENANCE, SAN FRANCISCO, CA
WESTERN ROTO, SAN FRANSICO, CA
ARCATA GRAPHICS/SAN JOSE, SAN JOSE, CA
FAITH T&R PLATING, SAN JOSE, CA
T & B AUTO BUMPER SERVICE, SAN JOSE, CA
DEL RAY CHROME, SANTA ANA, CA
EMBEE PLATING, SANTA ANA, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-7
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LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION8
===;
.EAR SEIGLER, INC, SANTA ANA, CA
REID METAL FINISHING, SANTA ANA, CA
S&G TUBE CO INC, SANTA ANA, CA
SANTA ANA PLATING, SANTA ANA, CA
A-l CHEMNETICS, SANTA CLARA, CA
A-l METAL FINISHING, INC, SANTA FE SPRINGS, CA
CAL-TRON PLATING, SANTA FE SPRINGS, CA
ELECTRONIC CHROME AND GRINDING CO, SANTA FE SPRINGS, CA
FOSS PLATING CO, INC, SANTA FE SPRINGS, CA
GELARDI'S PLATING INC, SANTA ROSA, CA
SANTA ROSA PLATING WORKS, SANTA ROSA, CA
ARTISTIC POLISHING & PLATING, SOUTH EL MONTE, CA
MIL-SPEC PLATING CORP, SOUTH EL MONTE, CA
ANADITE, INC, SOUTH GATE, CA
DOMAR PRECISION, SOUTH GATE, CA
UNITED PLATING INC, SOUTH SAN FRANCISCO, CA
STANFORD LINEAR ACCELERATOR, STANFORD, CA
STOCKTON PLATING INC, STOCKTON, CA
DKON HARD CHROME, INC, SUN VALLEY, CA
FLIGHT ACCESSORY SERVICES, SUN VALLEY, CA
VALLEY TODECO CO, SYLMAR, CA
BORG WARNER, TEMECULA, CA
PICHEL INDUSTRIES INC, TEMECULA, CA
DOUGLAS AIRCRAFT CO, TORRANCE, CA
MCDONNELL DOUGLAS, TORRANCE, CA
THE TORRINGTON CO, TORRINGTON, CA
BUCK'S OF UPLAND, UPLAND, CA
MARE ISLAND NAVAL SHIPYARD, VALLEJO, CA
THE MARQUARDT CO, VAN NUYS, CA
THE MASTER PLATING, INC, VENTURA, CA
CHRISTENSEN PLATING INC, VERNON, CA
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION. ^
Page C-8
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APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
FRANCIS PLATING, VERNON, CA
ELECTRO-COATINGS, INC, WEST SACRAMENTO, CA
WASHINGTON PLATING, WHITTIER, CA
REMCO HYDRAULICS, INC, WILLITS, CA
C&R RECONDITIONING CO, INC, WILMINGTON, CA
AXELSON, INC, COLORADO SPRINGS, CO
SUNDSTRAND AVIATION OPERATIONS, DENVER, CO
TOOLS FOR BENDING, INC, DENVER, CO
KAMAN, BLOOMFIELD, CT
RELIABLE PLATING AND POLISHING CO, BRIDGEPORT, CT
PRATT AND WHITNEY, EAST HARTFORD, CT
HAMILTON STANDARD SERVICES, EAST WINDSOR, CT
AEROTECH, HARTFORD, CT
KAMAN, MOOSHAP, CT
WARING PRODUCTS DIVISION D.C.A., NEW HARTFORD, CT
A-l CHROME, NEWINGTON, CT
SANITARY-DASH MFC CO INC, NO. GROSVENORDALE, CT
PRATT-WHITNEY, NORTH HAVEN, CT
THE PERKIN-ELMER CO, NORWALK, CT
LIGHTOLIER, INC, NORWICH, CT
PITNEY BOWES, INC, STAMFORD, CT
SIKORSKY AIRCRAFT DIVISION, STRATFORD, CT
WHYCO CHROMIUM COMPANY, INC, THOMASTON, CT
NUTMEG CHROME CORP, WEST HARTFORD, CT
HAMILTON STANDARD, WINDSOR LOCKS, CT
HOLLY CHEMICAL CO, WOODBURY, CT
GULF PLATING, FT. CAUDI, FL
NAVAL AVIATION DEPOT, JACKSONVILLE, FL
AEROTHRUST, MIAMI, FL
PERKO, INC, MIAMI, FL
MARTIN MARIETTA AEROSPACE, ORLANDO, FL
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-9
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LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION*
PENSACOLA NAVAL AIR REWORK FACILITY, PENSACOLA, FL
GULF COAST PLATING, INC, PENSACOLA, FL
FLORIDA PLATING, INC, PINELLAS PARK, FL
HUGHES HARD CHROME CO, TAMPA, FL
PRECISION INDUSTRIES, GA
MACGREGOR GOLF COMPANY, ALBANY, GA
UNITED STATES PLATING & BUMPER SERVICE, ALTANTA, GA
WESTERN ROTO, ALTANTA, GA
U.S. PLATING, ATLANTA, GA
CUMMINS ENGINE COMPANY, INC, FLOWERY BRANCH, GA
VERMONT AMERICAN CORP, TOCCOA GA
UNIVERSAL GYM AND NISSEN CO, CEDAR RAPIDS, IA
DU PAGE PLATING CO, ADDISON, IL
QUALITY METAL FINISHING CO, BYRON, IL
ACME SCIENTIFIC, INC, CHICAGO, IL
BILBO PLATING CO, CHICAGO, IL
BROOKLINE INDUSTRIES, INC, CHICAGO, IL
CHICAGO MODERN PLATING CO, CHICAGO, IL
CHROMIUM INDUSTRIES, INC, CHICAGO, IL
DRISCOLL, CHICAGO, IL
DURO-CHROME CORP, CHICAGO, IL
ECONOMY PLATING, INC, CHICAGO, IL
EMPIRE HARD CHROME, INC, CHICAGO, IL
JENSEN PLATING WORKS, INC, CHICAGO, IL
MOSCHIANO PLATING, INC, CHICAGO, IL
NOBERT PLATING COMPANY PLANT NO. 2, CHICAGO, IL
YALE POLISHERS AND PLATERS, INC, CHICAGO, IL
CJ SAPORITO PLATING (ACCURATE ANODIZING), CICERO, IL
WEST TOWN PLATING, INC, CICERO, IL
INDUSTRIAL HARD CHROME, INC, ELK GROVE VILLAGE, IL
PRECISION CHROME INC, FOX LAKE, IL
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-10
-------
APPENDIX C LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
BELMONT PLATING WORKS, FRANKLIN PARK, IL
NOVA-CHROME, INC, FRANKLIN PARK, IL
SLOAN VALVE CO, FRANKLIN PARK, IL
MODERN PLATING CORP, FREEPORT, IL
DEEVE AND CO, MOLINE, IL
ARLINGTON PLATING CO, PALATINE, IL
ROCKFORD PRODUCTS CORP, ROCKFORD, IL
CASTLE METAL FINISHING CORP, SHILLER PARK, IL
PRECISION PLATING DIVISION, R&R SALES, SOUTH CHICAGO HEIGHTS, IL
AL-BAR LABS WILMETTE PLATERS, WILMETTE, IL
WOODSTOCK DIE CAST, INC, WOODSTOCK, IL
BASTIAN PLATING CO INC, AUBURN, IN
PALMER INDUSTRIES, AURORA, IN
COSCO, INC, COLUMBUS, IN
MCDOWELL ENTERPRISE, INC, ELKHART, IN
WAYNE BLACK OXIDE, INC, FORT WAYNE, IN
NEO INDUSTRIES, GARY, IN
DELTA FAUCET CO, GREENSBURG, IN
B&B CUSTOM PLATING, HOAGLAND, IN
CITY PLATING COMPANY, INC, INDIANAPOLIS, IN
WILLIAMSON POLISHING & PLATING, INDIANAPOLIS, IN
BAYCOTE METAL FINISHING, MISHAWAKA, IN
SHERRY LABORATORIES, MUNCI, IN
C&M PLATING CO, INC, ROANOKE, IN
SHELBYVILLE PLATING-POLISHING CO, SHELBYVILLE, IN
PRECISION INDUSTRIES, MCPHERSON, KS
KANSAS PLATING, INC, WICHITA, KS
UNIVERSAL FASTNERS, INC, LAWRENCEBURG, KY
CUSTOM PLATING OF LOUISVILLE, LOUISVILLE, KY
KENTUCKY PLATING COMPANY, INC, LOUISVILLE, KY
N.I. INDUSTRIES, NICHOLASVILLE, KY
THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-ll
-------
LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION8
FENWAL INC, ASHLAND, MA
WALTON AND ONSBURY, INC, ATTLEBORO, MA
FOXBORO CO, FOXBORO, MA
NEPONSET, FOXBORO, MA
ADTEC INDUSTRIES, INC, LAWRENCE, MA
CIRCLE FINISHING, INC, NEWBURY, MA
FREDERICK R. GROVER COMPANY, INC, ROCKPORT, MA
NOMETCO, INC, WARE, MA
FOUNTAIN PLATING CO, WEST SPRINGFIELD, MA
WESTFIELD ELECTROPLATING CO, WESTFIELD, MA
ACME PLATING CO., INC, BALTIMORE, MD
ALLIED METAL FINISHING CORP, BALTIMORE, MD
ALMAG PLATING CORP, BALTIMORE, MD
MUFFOLETTO OPTICAL COMPANY, INC, BALTIMORE, MD
METAL FINISHING, INC, HAGERSTOWN, MD
SACO DEFENSE, INC, SACO, ME
SILVEX, INC, WESTBROOK IND. PARK, ME
BELLEVILLE PLATING, BELLEVILLE, MI
BRONSON PLATING CO, BRONSON, MI
BUICK-OLDSMOBILE-CADILLAC GROUP, DETROIT, MI
CHRYSLER CORP, DETROIT, MI
GENERAL PLATING, INC, DETROIT, MI
STANLEY TOOLS DIVISION, FOWLERVILLE, MI
BISSELL INC, GRAND RAPIDS, MI
FCM PLASTICS DIVISION OF PLASTICS TECHNOLOGY, GRAND RAPIDS, MI
KEELER AUTOMOTIVE HARDWARE, GRAND RAPIDS, MI
CHROME CRAFT CORP, HIGHLAND PARK, MI
OTTAWA GAGE, INC, HOLLAND, MI
DIAMOND CHROME PLATING, INC, HOWELL, MI
KEELER BRASS AUTOMOTIVE - KENTWOOD PLANT, KENTWOOD, MI
CHEVROLET-PONTIAC-CANADA GROUP, LIVONIA, MI
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-12
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APPENDIX C LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
ATTWOOD CORP, LOWELL, MI
LEAR SIEGLER PLASTICS CORP, MENDON, MI
CRECO, INC, OWOSSO, MI
AUTOMATIC DIE CASTING SPECIALTIES, ST CLAIR SHORES, MI
LECO PLATING DIVISION, LECO CORP, ST JOSEPH, MI
C.S. OHM MANUFACTURING CO, STERLING HEIGHTS, MI
CHRYSLER CORP, STERLING HEIGHTS, MI
CHRYSLER CORP, WARREN, MI
MODERN HARD CHROME SERVICE CO, WARREN, MI
UNISYS PARK, EAGAN, MN
NAVAL INDUSTRIAL RESERVE ORDNANCE PLANT, FRIDLEY, MN
DOUGLAS CORP, MINNEAPOLIS, MN
CHROMOCRAFT FURNITURE, SENATOBIA, MS
LUFKIN RULE, APEX, NC
CONSOLIDATED ENGRAVERS CORP, CHARLOTTE, NC
GIBBS PLATING CO, CHARLOTTE, NC
STORK SCREEN, CHARLOTTE, NC
C&R CHROME SERVICES, INC, GASTONIA, NC
GREENSBORO INDUSTRIAL PLATERS, GREENSBORO, NC
UNITED METAL FINISHING, INC, GREENSBORO, NC
CUSTOM PROCESSING CO, HIGH POINT, NC
SWAIM METALS, INC, HIGH POINT, NC
PIEDMONT INDUSTRIAL PLATING, STATESVILLE, NC
NORTH AMERICAN ROTO, WINSTON SALEM, NC
MONROE AUTO EQUIPMENT, COZAD, NE
PLATING PRODUCTS, NJ
MILLER AND SON, INC, BELLEVILLE, NJ
KAEHR CORP.(KAEHR PLATING AND METAL FIN), ALBUQUERQUE, NM
LEVCO METAL FINISHERS, NY
HUDSON CHROMIUM COMPANY, INC, ASTORIA, NY
CHROMIUM PLATING & POLISHING CORP, BROOKLYN, NY
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION. ___
Page C-13
-------
LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION8
JAYAR METAL FINISHING CORP, BROOKLYN, NY
NORWOOD ELECTROPLATING, INC, BROOKLYN, NY
GENERAL SUPERPLATING CO, EAST SYRACUSE, NY
HYGRADE POLISHING AND PLATING, LONG ISLAND CITY, NY
KINGS/KINGSLEY CORP, MASPETH, NY
P.J. VERNEUIL ELECTROPLATING, MT. VERNON, NY
ERIC S. TURNER & CO, INC, NEW ROCHELLE, NY
CHROMIUM PLATING POLISHING, NEW YORK, NY
CATARACT METAL FINISHING, INC, NIAGARA FALLS, NY
MCGRAW-EDISON POWER SYSTEMS, OLEAN, NY
RAYCO OF SCHENECTADY, SCHENECTODY, NY
ANOPLATE CORP, SYRACUSE, NY
NATIONAL PLATING CO, INC, SYRACUSE, NY
BENET LABORATORIES, WATERULIET, NY
VERNON PLATING WORKS, INC, WOODSIDE, NY
PRECISION PLATING CO, AKRON, OH
ACME HARD CHROME, ALLIANCE, OH
BELLAFONTAINE PLATING MANUFACTURING CO, BELLEFONTAINE, OH
OLYMCO, INC, CANTON, OH
UNITED HARD CHROME CORP, CANTON, OH
CINCINNATI MILACRON, OAKLEY, CINCINNATI, OH
SMITH ELECTROCHEMICAL CO, CINCINNATI, OH
THOMPSON CONSUMER ELECTRONICS, CIRCLEVILLE, OH
C. T. INDUSTRIES, INC, CLEVELAND, OH
CHROME INDUSTRIES, INC, CLEVELAND, OH
CRAFT MASTERS, CLEVELAND, OH
METALS APPLIED, INC, CLEVELAND, OH
MR. GASKET COMPANY, CLEVELAND, OH
FRANKLIN PLATING, COLUMBUS, OH
OI-NEG, COLUMBUS, OH
HOHMAN PLATING & MANUFACTURING, INC, DAYTON, OH
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION. ^
Page C-14
-------
APPENDIX C
LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
K&F METAL FINISHERS, INC, DAYTON, OH
MIAMI PRECISION CHROME, DAYTON, OH
STANDARD REGISTER, DAYTON, OH
U.S. CHROME CORP OF OHIO, DAYTON, OH
PLATERS SERVICE, INC, ENGLEWOOD, OH
CASE PLATING, LORAIN, OH
DELCO-MORAINE, MORAINE, OH
NORTH CANTON PLATING CO, NORTH CANTON, OH
WHITAKER PLATING, NORTHWOOD, OH
CHAMPION SPARK PLUG COMPANY, TOLEDO, OH
PLATING PERCEPTIONS INC, TWINSBURG, OH
FULTON INDUSTRIES, INC, WAUSEON, OH
YOUNGSTOWN HARD CHROME, YOUNGSTOWN, OH
COOPER TOOLS, PA
AMERICAN BANKNOTE, HORSHAM, PA
PAUL'S CHROME PLATING, INC, MARS, PA
FRANKLIN MINT HARING PL, PHILADELPHIA, PA
Ol-NEG, PITTSTON, PA
METALIFE INDUSTRIES INC, RENO, PA
ARMOLOY OF WESTERN PA, INC, TURTLE CREEK, PA
CATEPILLAR, INC, YORK, PA
GARROD HYDRAULICS, INC, YORK, PA
HARD CHROMIUM SPECIALISTS, YORK, PA
MICROFIN CORP, PROVIDENCE, RI
SURFACE COATING DIV WESTNELL IND, PROVIDENCE, RI
B&E, SC
CONSOLIDATED ENGRAVERS CORP, CHESTER, SC
PROGRESS LIGHTING, COWPINS, SC
GENERAL ELECTRIC CO, FLORENCE, SC
CAROLINA PLATING CO, GREENVILLE, SC
ROLL TECHNOLOGY, INC, GREENVILLE, SC
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-15
-------
LIST OF KNOWN FACILITIES APPENDIX C
FACILITY NAME, LOCATION8
STEEL HEDDLE CO, GREENVILLE, SC
TRUE TEMPER SPORTS, SENECA, SC
SAXONIA FRANKE OF AMERICA, SPARTANBURG, SC
ABLE MACHINE CO, TAYLORS, SC
T&S BRASS AND BRONZE WORKS, TRAVELERS REST, SC
HARMAN AUTOMOTIVE, INC, BOLIVAR, TN
MURRAY OHIO MANUFACTURING CO, LAWRENCEBURG, TN
MAREMONT CORP, PULASKI, TN
COASTAL PLATING, CORPUS CHRISTI, TX
MENASCO, EULESS, TX
TEXAS PRECISION PLATING, INC, GARLAND, TX
FUSION, INC, HOUSTON, TX
PRECISE PRODUCTS, WACO, TX
PRECISION INTERNATIONAL CO, WACO, TX
HILL AFB, OGDEN, UT
QUALITY PLATING CO, SALT LAKE CITY, UT
ALEXANDRIA METAL FINISHERS, LORTON, VA
NEWPORT NEWS SHIPBUILDING/DRY DOCK CO, NEWPORT NEWS, VA
NORFOLK NAVAL AIR REWORK FACILITY, NORFOLK, VA
NORFOLK NAVAL SHIPYARD, NORFOLK, VA
WESTERN ROTO, RICHMOND, VA
MARTIN MARIETTA ARMAMENT SYSTEMS, BURLINGTON, VT
SIMMONDS PRECISION, VERGENNES, VT
BOEING, AUBURN, WA
N.U.W.E.S., KEYPORT, WA
BOEING-FABRICATION DIVISION, S.W. AUBURN, WA
BOEING, SEATTLE, WA
PRECISION ENGINEERING, SEATTLE, WA
HARRIS & GALLOB, BELGIUM, WI
BRIGGS AND STRATTON, GLENDALE, WI
ULTRA PLATING CORP, GREEN BAY, WI
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-16
-------
APPENDIX C LIST OF KNOWN FACILITIES
FACILITY NAME, LOCATION8
SNAP-ON TOOLS CORP, KENOSHA, WI
KOHLER CO, KOHLER, WI
JAGEMANN PLATING CO, MANITOWOC, WI
E.F. BREWER CO, MENOMONEE FALLS, WI
ACME GALVANIZING INC, MILWAUKEE, WI
ASTRA PLATING, INC, MILWAUKEE, WI
EASTON CORP, MILWAUKEE, WI
G.E. MEDICAL SYSTEMS, MILWAUKEE, WI
JOHNSON CONTROLS, INC, MILWAUKEE, WI
MILWAUKEE PLATING CO, MILWAUKEE, WI
RELIABLE PLATING WORKS, MILWAUKEE, WI
CHF INDUSTRIES, RACINE, WI
PRECISION MACHINE AND HYDRAULICS, INC, WORTHINGTON, WV
aNOTE: THIS LIST IS INCOMPLETE AND DOES NOT INCLUDE ALL SOURCES AFFECTED
BY THE REGULATION. ALSO, SOME COMPANIES ON THIS LIST MAY NO
LONGER BE IN OPERATION.
Page C-17
-------
APPENDIX D
DETAILED TABLE OF CONTENTS OF
THE REGULATION
-------
APPENDIX D
DETAILED TABLE OF CONTENTS OF THE REGULATION
TABLE D-l. DETAILED TABLE OF CONTENTS OF THE REGULATION
Requirement
Location in regulation
Applicability and designation of sources
Applicability of the regulation
List of what portions of EPA's General Provisions regulation (subpart A) apply to
sources covered under this regulation
Sources that are specifically exempted from the regulation
Requirement to obtain a permit under title V of the CAA
§ 63.340(a)
§ 63.340(b)
§ 63.340(c)-(d)
§ 63.340(e)
Definitions and nomenclature
Definitions of terms used in the regulation
Nomenclature for the special compliance provision calculations
§ 63.341(a)
§ 63.341(b)
Standards
When the emission limits apply
What emission limits apply when a group of tanks is controlled by one control
device
Emission limits for hard chromium electroplating tanks
Procedure for demonstrating the size of a hard chromium electroplating facility
Emission limits for decorative chromium electroplating tanks using a chromic acid
bath and chromium anodizing tanks
Emission limits for decorative chromium electroplating tanks using a trivalent
chromium bath
Work practice standards
Operation and maintenance plan requirements
Standards must not be met by using a reducing agent
§ 63.342(a)-(b)(l)
§ 63.342(b)(2)
§ 63.342(c)(l)
§ 63.342(c)(2)
§ 63.342(d)
§ 63.342(e)
§ 63.342(f)
§ 63.342(f)(3)
§ 63.342(g)
Compliance provisions
Compliance dates
Request for an extension of the compliance date
Methods to demonstrate initial compliance
Monitoring to demonstrate continuous compliance:
Composite mesh-pad systems
Packed-bed scrubber systems
Packed-bed scrubber/composite mesh-pad systems
Fiber-bed mist eliminators
Wetting agent-type or combination wetting agent-type/foam blanket fume
suppressants
Foam blanket-type fume suppressants
§ 63.343(a)
§ 63.343(a)(6)
§ 63.343(b)
§ 63.343(c)
§ 63.343(c)(l)
§ 63.343(c)(2)
§ 63.343(c)(3)
§ 63.343(c)(4)
§ 63.343(c)(5)
§ 63.343(c)(6)
Page D-l
-------
DETAILED TABLE OF CONTENTS OF THE REGULATION
APPENDIX D
TABLE D-l. (continued)
Requirement
Monitoring to demonstrate continuous compliance (cont.):
Fume suppressant/add-on control device
Use of an alternative monitoring method
Submittal of information for sources using an air pollution control device not listed
above
Location in regulation
§ 63.343(c)(7)
§ 63.343(c)(8)
§ 63.343(d)
Performance test requirements and test methods
Performance test methods including the required contents of the test plan
When previous performance testing may be used to demonstrate compliance with
this regulation
Test methods (cited here, but actual methods are placed in 40 CFR part 63,
Appendix A)
How to establish site-specific operating parameters
Special compliance provisions for multiple sources controlled by a common control
device
§ 63.344(a)
§ 63.344(b)
§ 63.344(c)
§ 63.344(d)
§ 63.344(e)
Provisions for new and reconstructed sources
Notification requirements for new or reconstructed sources that become subject to
the regulation
§ 63.345
Recordkeeping requirements
Lists records that must be kept by the source for 5 years
§ 63.346
Reporting requirements
How the reports should be sent (e.g., U.S. mail, fax, or by another courier)
When these reporting requirements apply
Initial notification
Notification of performance test
Notification of compliance status
Reports of performance test results
Ongoing compliance status reports for major sources
Ongoing compliance status reports for area sources
Reports associated with trivalent chromium baths
§ 63.347(a)
§ 63.347(b)
§ 63.347(c)
§ 63.347(d)
§ 63.347(e)
§ 63.347(f)
§ 63.347(g)
§ 63.347(h)
§ 63.347(i)
Page D-2
-------
APPENDIX E
EXAMPLE FORMS
CONTENTS:
OPERATION AND MAINTENANCE CHECKLISTS
MONITORING DATA FORM
INITIAL NOTIFICATION REPORT
NOTIFICATION OF CONSTRUCTION/RECONSTRUCTION
NOTIFICATION OF PERFORMANCE TEST
NOTIFICATION OF COMPLIANCE STATUS
ONGOING COMPLIANCE STATUS REPORT
-------
Applicable Rule:
OPERATION AND MAINTENANCE CHECKLIST
(for composite mesh-pad systems or
combination packed-bed scrubber/composite mesh-pad systems)
40 CFR Part 63, Subpart N--National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
Plant Name/Location:
Control Device ID #:
Installation Date: / /
Date of Last Performance Test: / /
Tanks Ducted to Control System:
Tank ID #
Type of tank (i.e., hard chrome, decorative
chrome, or chrome anodizing)
Inspection/Maintenance Checklist (insert inspector's initials in boxes):
Control Device
Inspection
inlet and outlet
transition zones
spray nozzles
packed-bed section
mesh pads
drain lines
fan motor
fan vibration
Date: / /
Date: / /
Date: / /
Date: / /
Page 1 of 2
-------
OPERATION AND MAINTENANCE CHECKLIST (continued)
Monitoring Equipment
Inspection
pressure lines connected
pressure drop monitor
calibrated
Control Device
Maintenance
washdown of pads
other: (specify)**
Date: / /
Date: / /
Date: / /
Date: / /
Date: / /
Date: / /
Date- / /
Date: / /
"Examples: replaced nozzles, adjusted fan motor, replaced recirculation pump, etc.
Corrective Actions:
Describe actions taken and maintenance performed to correct any deficiencies.
Date: / / Initials:
Supervisor informed (Y/N): _
Date: / / Initials:
Supervisor informed (Y/N): _
_Date: / / Initials:
Supervisor informed (Y/N): _
NOTE: THIS CHECKLIST CONTAINS ONLY THE MINIMUM REQUIREMENTS AND DOES NOT INCLUDE ALL OF
THE SYSTEM CHECKS THAT NEED TO BE PERFORMED TO ENSURE PROPER OPERATION OF THE CONTROL
SYSTEM. FACILITIES SHOULD INCORPORATE INFORMATION RECOMMENDED BY THE CONTROL SYSTEM
VENDOR.
Page 2 of 2
-------
OPERATION AND MAINTENANCE CHECKLIST
(for packed-bed scrubbers)
Applicable Rule: 40 CFR Part 63, Subpart N--National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
Plant Name/Location:
Control Device ID #:
Installation Date: / /
Date of Last Performance Test: / /
Tanks Ducted to Control System:
Tank ID #
Type of tank (i.e., hard chrome, decorative
chrome, or chrome anodizing)
Inspection/Maintenance Checklist (insert inspector's initials in boxes):
Control Device
Inspection
inlet and outlet
transition zones
spray nozzles
packed-bed section
overhead weir
drain lines
fan motor
fan vibration
Date: / /
Date: / /
Date: / /
Date: / /
Page 1 of 2
-------
OPERATION AND MAINTENANCE CHECKLIST (continued)
Monitoring Equipment
Inspection
pressure lines connected
pressure drop monitor
calibrated
pilot tube3
Control Device
Maintenance
other: (specify)'-'
Date: / /
Date: / /
Date: / /
Date: / /
Date: / /
Date: / /
r»atft- / /
Date: / /
aBackflush with water, or remove from the duct and rinse with fresh water. Replace in the duct and
rotate 180 degrees to ensure that the same zero reading is obtained. Check pilot tube ends for
damage. Replace pilot tube if cracked or fatigued.
"Examples: replaced nozzles, adjusted fan motor, replaced recirculalion pump, elc.
Corrective Aclions:
Describe aclions laken and maintenance performed to correct any deficiencies.
Date: / / Initials:
Supervisor informed (Y/N): _
.Date: / / Initials:
Supervisor informed (Y/N): _
.Date: / / Initials:
Supervisor informed (Y/N): _
NOTE: THIS CHECKLIST CONTAINS ONLY THE MINIMUM REQUIREMENTS AND DOES NOT INCLUDE ALL OF
THE SYSTEM CHECKS THAT NEED TO BE PERFORMED TO ENSURE PROPER OPERATION OF THE CONTROL
SYSTEM. FACILITIES SHOULD INCORPORATE INFORMATION RECOMMENDED BY THE CONTROL SYSTEM
VENDOR.
Page 2 of 2
-------
OPERATION AND MAINTENANCE CHECKLIST
(for fiber-bed mist eliminators)
Applicable Rule: 40 CFR Part 63, Subpart N-National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
Plant Name/Location:
Control Device ID #:
Installation Date: / /
Date of Last Performance Test: / /
Tanks Ducted to Control System:
Tank ID #
Type of tank (i.e., hard chrome, decorative
chrome, or chrome anodizing)
Inspection/Maintenance Checklist (insert inspector's initials in boxes):
Control Device
Inspection
inlet and outlet
transition zones
spray nozzles
fiber beds
prefiltering device
drain lines
fan motor
fan vibration
Date: / /
Date: / /
Date: / /
Date: / /
Page 1 of 2
-------
OPERATION AND MAINTENANCE CHECKLIST (continued)
\4nnitnrinp TCnninment
Inspection
pressure lines connected
pressure drop monitors
calibrated
fontrnl T)pvirp
Maintenance
washdown of fiber beds
other: (specify)3
Date- / /
Date- / /
Date: / /
Date: / /
Date: / /
Date: / /
nate- / /
Date: / /
aExamples: replaced nozzles, adjusted fan motor, replaced recirculation pump, etc.
Corrective Actions:
Describe actions taken and maintenance performed to correct any deficiencies.
Date: / / Initials:
Supervisor informed (Y/N): _
Date: / / Initials:
Supervisor informed (Y/N): _
Date: / / Initials:
Supervisor informed (Y/N): _
NOTE: THIS CHECKLIST CONTAINS ONLY THE MINIMUM REQUIREMENTS AND DOES NOT INCLUDE ALL OF
THE SYSTEM CHECKS THAT NEED TO BE PERFORMED TO ENSURE PROPER OPERATION OF THE CONTROL
SYSTEM. FACILITIES SHOULD INCORPORATE INFORMATION RECOMMENDED BY THE CONTROL SYSTEM
VENDOR.
Page 2 of 2
-------
MONITORING DATA FORM
Applicable Rule:
40 CFR Part 63, Subpart N~National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
Plant Name/Location:
Air Pollution Control System:
Control System ID #:
Monitoring Data:
Pressure drop across system3
Inches of
t^O column
Date
recorded
Initials
Applicable range established during initial
performance test:
Velocity pressure of system inlet"
Inches of
H2O column
Date
recorded
Initials
Applicable range established during initial
performance test:
aPressure drop monitoring is required for composite mesh-pad (CMP) systems, packed-bed scrubbers
(PBS), combination PBS/CMS, and fiber-bed mist eliminators (including the upstream control device
used to prevent plugging). A continuous strip recorder may be added to the AP monitor to
continuously record pressure drop.
"Velocity pressure monitoring is required for PBS only.
Page 1 of 2
-------
MONITORING DATA FORM (continued)
Periods of Excess Emissions:
Start: Start:.
End: End:
Corrective action taken: Corrective action taken:
Initials: Initials:
Start: Start:.
End: End:
Corrective action taken: Corrective action taken:
Initials: Initials:
Start: Start:.
End: End:
Corrective action taken: Corrective action taken:
Initials: Initials:.
Start: Start:.
End: End:_
Corrective action taken: Corrective action taken:
Initials: Initials:
Page 2 of 2
-------
INITIAL NOTIFICATION REPORT
Applicable Rule: 40 CFR Part 63, Subpart N~National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
1. Print or type the following for each plant in which chromium electroplating and/or chromium
anodizing operations are performed.
Owner/Operator/Title
Street Address
City
State
Zip Code
Plant Name
Plant Phone Number
Plant Contact/Title
Plant Address (if different than owner/operator's):
Street Address
City State
Zip Code
2. Complete this section for all affected tanks using a chromic acid bath. If only trivalent chromium
baths are used at the facility, go to No. 3.
A. Complete the following table. If additional lines are needed, make copies of this page.
Tank
ID#
Type of tank
Startup
date1
Total
installed
rectifier
capacity
(amperes)
Description of parts plated
Applicable
emission limit
Compliance
date2
*New or reconstructed tanks with an initial startup date after 1/25/95 must submit a NOTIFICATION OF
CONSTRUCTION/RECONSTRUCTION form and notify the Administrator of the date
construction/reconstruction commenced and the actual startup date in accordance with 40 CFR 63.347(c)(2).
Page 1 of 4
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INITIAL NOTIFICATION REPORT (continued)
^Compliance dates for existing tanks (i.e., tanks for which operation commenced on or before 12/16/93):
Hard chromium plating tanks => 1/25/97
Decorative chromium plating tanks =» 1/25/96
Chromium anodizing tanks =* 1/25/97
Compliance dates for new tanks (i.e., tanks for which construction or reconstruction commenced
after 12/16/93):
If initial startup occurred between 12/16/93 and 1/25/95 =» 1/25/95
If initial startup occurred after 1/25/95 =» upon startup
EXAMPLE RESPONSE:
Tank
ID#
1
2
3
4
Type of tank
Chrome anodizing
Hard chrome plating
Hard chrome plating
Hard chrome plating
Startup
date
1/1/85
1/1/85
1/1/95
3/1/95
Total
installed
rectifier
capacity
(amperes)
5,000
10,000
12,000
12,000
Description of parts plated
Aircraft landing gear
pistons
pistons
pistons
Applicable
emission limit
45 dynes/cm or
0.01 mg/dscm
0.015 mg/dscm
0.015 mg/dscm
0.015 mg/dscm
Compliance
date
1/25/97
1/25/97
1/25/95
3/1/95
B. Check the box that applies.
D Tanks are located at a facility that is a major source.
D Tanks are located at a facility that is an area source.
NOTE: A major source is a facility that emits greater than 10 tons per year of any one hazardous
air pollutant (HAP) or 25 tons per year of multiple HAPs. All other sources are area sources.
The major/area source determination is based on all HAP emission points inside the facility
fenceline. not iust the chromium electroplating and anodizing tanks.
C. Complete the following if hard chromium electroplating tanks are operated. Check the
box(es) that apply.
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is greater than or equal to 60 million amp-hr/yr. This was determined by taking the
sum of the total installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7
for each tank.
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is less than 60 million amp-hr/yr. This was determined by taking the sum of the total
installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7 for each tank.
D Records show that the facility's previous 12-month cumulative current usage for the hard
chromium electroplating tanks was less than 60 million amp-hr.
Page 2 of 4
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INITIAL NOTIFICATION REPORT (continued)
D The facility wishes to accept a Federally-enforceable limit of less than 60 million amp-hr/yr
on the maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks.
3. Complete this section for all decorative chromium electroplating tanks using a trivalent chromium
bath. If only chromic acid baths are used at the facility, go to No. 4.
A. Complete the following table. If additional lines are needed, make copies of this page.
Tank ID #
Startup date1
Description of parts plated
Compliance date2
or reconstructed tanks with an initial startup date after 1/25/95 must submit a NOTIFICATION OF
CONSTRUCTION/RECONSTRUCTION form and notify the Administrator of the date
construction/reconstruction commenced and the actual startup date in accordance with 40 CFR 63.347(c)(2).
^Compliance date for existing tanks (i.e., tanks for which operation commenced on or before 12/16/93) =»
1/25/96
Compliance dates for new tanks (i.e., tanks for which construction or reconstruction commenced
after 12/16/93):
If initial startup occurred between 12/16/93 and 1/25/95 =» 1/25/95
If initial startup occurred after 1/25/95 =» upon startup
B. Provide a brief description of the trivalent chromium electroplating process used at your
facility. Attach process flow diagrams for each plating line.
C. Check the box that applies.
D The trivalent process used at the facility incorporates a wetting agent.
D The trivalent process used at the facility does not incorporate a wetting agent.
Page 3 of 4
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INITIAL NOTIFICATION REPORT (continued)
D. List below (or attach a list of) the trivalent chromium bath components and clearly identify the
wetting agent.
4. Print or type the name and title of the Responsible Official for the plant:
(Name) (Title)
A Responsible Official can be:
* The president, vice-president, secretary, or treasurer of the company that owns the plant;
* The owner of the plant;
* The plant engineer or supervisor;
* A government official if the plant is owned by the Federal, State, City, or County
government; or
* A ranking military officer if the plant is located on a military base.
I Certify The Information Contained In This Report To Be Accurate And True To The Best Of
My Knowledge.
I /
(Signature of Responsible Official) (Date)
Page 4 of 4
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NOTIFICATION OF CONSTRUCTION/RECONSTRUCTION
Applicable Rule: 40 CFR Part 63, Subpart N-National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
1. This form is being completed because (check box(es) that apply):
D A chromium electroplating and/or chromium anodizing tank is being constructed.
D A chromium electroplating and/or chromium anodizing tank is being reconstructed.
2. Print or type the following for each plant in which a chromium electroplating and/or chromium
anodizing tank is being constructed or reconstructed.
Owner/Operator/Title
Street Address ^____
City
State
Zip Code
Plant Name
Plant Phone Number
Plant Contact/Title
Plant Address (if different than owner/operator's):
Street Address
City State
Zip Code
3. Complete the following table for each tank for which construction or reconstruction is planned. If
additional lines are needed, make copies of this page.
Tank
ID#
Type of tank
Expected beginning
date for
const/reconst
Expected
completion date
for
const/reconst
Anticipated
startup
date
Type of control
technique to be
used1
Control
System ID #
Estimated total
chromium
emissions after
control is applied^
* Attach design information from vendor, including design drawings and design capacity.
•^Attach engineering calculations to support estimate. These calculations may be from the vendor.
Emissions estimates should be expressed in units consistent with the emission limits in the regulation.
Page 1 of 3
-------
NOTIFICATION OF CONSTRUCTION/RECONSTRUCTION (continued)
EXAMPLE RESPONSE:
Tank
tt>#
1
2
Type of tank
Hard chrome
plating
Decorative
chrome plating
Expected beginning
date for
const/reconst
10/94
2/95
Expected
completion date
for
const/reconst
1/95
6/95
Anticipated
startup
date
1/95
6/95
Type of control
technique to be
used1
Composite mesh-
pad system
Wetting-agent
fume suppressant
Control
System ID #
5
N/A
Estimated total
chromium
emissions after
control is applied2
0.01 mg/dscm
Will meet
45 dynes/cm
4. Check the box that will apply after construction/reconstruction occurs.
D Tanks are located at a facility that is a major source.
D Tanks are located at a facility that is an area source.
NOTE: A major source is a facility that emits greater than 10 tons per year of any one hazardous
air pollutant (HAP) or 25 tons per year of multiple HAPs. All other sources are area sources.
The major/area source determination is based on all HAP emission points inside the facility
fenceline. not just the chromium electroplating and anodizing tanks.
5. Complete the following if hard chromium electroplating tanks are being constructed/reconstructed.
Check the box(es) that apply.
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is greater than or equal to 60 million amp-hr/yr. This was determined by taking the
sum of the total installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7
for each tank.
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is less than 60 million amp-hr/yr. This was determined by taking the sum of the total
installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7 for each tank.
D Records show that the facility's previous 12-month cumulative current usage for the hard
chromium electroplating tanks was less than 60 million amp-hr.
D The facility wishes to accept a Federally-enforceable limit of less than 60 million amp-hr/yr
on the maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks.
6. Attach a brief description of the proposed emission control technique(s), including design
drawings, design capacity, and emissions estimates with supporting calculations.
7. If reconstruction is to occur, attach a brief description of the source and the components to be
replaced.
Page 2 of 3
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NOTIFICATION OF CONSTRUCTION/RECONSTRUCTION (continued)
8. Complete the following if reconstruction is to occur, and the facility believes that there are
economic or technical limitations to prevent the facility from complying will all relevant standards
or requirements.
A. Attach a discussion of any economic or technical limitations of complying with the relevant
standards or requirements. The discussion must be sufficiently detailed to demonstrate how
these limitations will affect the facility's ability to comply.
B. Provide an estimate of the fixed capital cost of the replacements and of constructing a
comparable entirely new source: Replacements $ ; New source $ .
C. Provide the estimated life of the source after the replacements:
9. Print or type the name and title of the Responsible Official for the plant:
(Name) (Title)
A Responsible Official can be:
* The president, vice-president, secretary, or treasurer of the company that owns the plant;
* The owner of the plant;
* The plant engineer or supervisor;
* A government official if the plant is owned by the Federal, State, City, or County
government; or
* A ranking military officer if the plant is located on a military base.
I Certify The Information Contained In This Report To Be Accurate And True To The Best Of
My Knowledge.
(Signature of Responsible Official) (Date)
Page 3 of 3
-------
NOTIFICATION OF PERFORMANCE TEST
(This notification is not required if you do not have to
conduct a performance test under the regulation.)
Applicable Rule: 40 CFR Part 63, Subpart N~National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
1. Print or type the following for each plant in which chromium electroplating and/or chromium
anodizing operations are performed:
Owner/Operator/Title
Street Address
City
State
Zip Code
Plant Name
Plant Phone Number
Plant Contact/Title
Plant Address (if different than owner/operator's):
Street Address
Citv State Zip Code
2. Complete the following table. If additional lines are needed, make copies of this page.
Type of control
technique
Control
System ID #
ID # of tank ducted
to control system
Type of tank
Date of
performance test
Page 1 of 2
-------
NOTIFICATION OF PERFORMANCE TEST (continued)
EXAMPLE RESPONSE:
Type of control
technique
Composite mesh-pad
system
Packed-bed scrubber
Wetting agent fume
suppressant
Control
System ID #
10
11
N/A
ID # of tank ducted
to control system
1
2
3
4
5
6
Type of tank
Hard chrome plating
Hard chrome plating
Hard chrome plating
Hard chrome plating
Hard chrome plating
Chrome anodizing
Date of
performance test
5/15/97
5/18/97
none required
Page 2 of 2
-------
NOTIFICATION OF COMPLIANCE STATUS
Applicable Rule: 40 CFR Part 63, Subpart N-National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
1. Print or type the following for each plant in which chromium electroplating and/or chromium
anodizing operations are performed.
Owner/Operator/Title
Street Address
City
State
Zip Code
Plant Name
Plant Phone Number
Plant Contact/Title
Plant Address (if different than owner/operator's):
Street Address
City State
Zip Code
2. Complete the following table. If additional lines are needed, make copies of this page.
Tank
ro#
Type of tank
Applicable
emission limit
Type of control
technique
Control
system
ro#
Method to
determine
compliance
Test method
followed
Type and quantity
of HAP emitted2
hf a performance test was conducted, submit the test report containing the elements required by
40 CFR 63.344(a).
2If the compliance procedures of 40 CFR 63.344(e) are being followed, attach the calculations needed
to support the emission limit expressed in mg/hr.
EXAMPLE RESPONSE:
Tank
ro#
1
2
3
Type of tank
Hard chrome
plating
Chrome anodizing
Decorative chrome
plating
Applicable
emission limit
0.015 mg/dscm
45 dynes/cm
0.01 mg/dscm
Type of control
technique
Composite mesh-
pad system
Wetting agent
fume suppressant
Foam blanket
Control
system
ID#
10
N/A
N/A
Method to
determine
compliance'
Performance test
Surface tension
measurement
Performance test
Test method
followed
EPA Method 306
EPA Method 306B
EPA Method 306A
Type and quantity
of HAP emitted2
Cr 0.009 mg/dscm
Cr 40 dynes/cm
Cr 0.005 mg/dscm
Page 1 of 3
-------
NOTIFICATION OF COMPLIANCE STATUS (continued)
3. Complete the following table for each control technique used. If additional lines are needed,
make copies of this page
Control
system ID #
Tank
ID #(s)
Range of site-specific operating parameter values1
Pressure drop
Velocity pressure
Surface tension
Foam blanket
thickness
* If the applicable monitoring and reporting requirements to demonstrate continuous compliance differ
from those in 40 CFR Part 63, subpart N, attach a description. Parameter value ranges are
established through initial performance testing and are those that correspond to emissions at or below
the level of the standard(s).
EXAMPLE RESPONSE:
Control
system ID #
10
N/A
N/A
Tank
ID #(s)
1
2
3
Range of site-specific operating parameter values1
Pressure drop
7 in. w.c.
± 1 in.
N/A
N/A
Velocity pressure
N/A
N/A
N/A
Surface tension
N/A
<45 dynes/cm
N/A
Foam blanket
thickness
N/A
N/A
>1 inch
4. Complete the following if hard chromium electroplating tanks are operated (check the box(es)
that apply):
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is greater than or equal to 60 million amp-hr/yr. This was determined by taking the
sum of the total installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7
for each tank.
D The maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks is less than 60 million amp-hr/yr. This was determined by taking the sum of the total
installed rectifier capacity (amperes) multiplied by 8,400 hours/yr and by 0.7 for each tank.
D Records show that the facility's previous annual actual rectifier capacity of the hard chromium
electroplating tanks was less than 60 million amp-hr/yr. If so, submit the records that support
this rectifier capacity for any 12-month period preceding the compliance date, or submit a
description of how operations will change to meet this rectifier capacity limit. For new.
sources, the capacity can be that projected for the first 12-month period of tank operation.
Page 2 of 3
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NOTIFICATION OF COMPLIANCE STATUS (continued)
D The facility has accepted or will accept a Federally-enforceable limit of 60 million amp-hr/yr
on the maximum cumulative potential rectifier capacity of the hard chromium electroplating
tanks.
5. Check one of the following boxes that describes the facility's compliance status:
D The facility is in compliance with the provisions of 40 CFR part 63, subpart N.
D The facility is not in compliance with the provisions of 40 CFR part 63, subpart N.
6. Print or type the name and title of the Responsible Official for the plant:
(Name) (Title)
A Responsible Official can be:
* The president, vice-president, secretary, or treasurer of the company that owns the plant;
* The owner of the plant;
* The plant engineer or supervisor;
* A government official if the plant is owned by the Federal, State, City, or County
government; or
* A ranking military officer if the plant is located on a military base.
I Certify That An Operation And Maintenance Plan Has Been Completed And The Plan And
Other Work Practice Standards Of 40 CFR 63.342(f) Are Being Followed.
(Signature of Responsible Official) (Date)
I Certify That The Information Contained In This Report Is Accurate And True To The Best Of
My Knowledge.
(Signature of Responsible Official) (Date)
Page 3 of 3
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ONGOING COMPLIANCE STATUS REPORT
Applicable Rule: 40 CFR Part 63, Subpart N-National Emission Standards for Chromium
Emissions from Hard and Decorative Chromium Electroplating and Chromium
Anodizing Tanks
1. Print or type the following for each plant in which chromium electroplating and/or chromium
anodizing operations are performed:
Owner/Operator/Title
Street Address
City
State
Zip Code
Plant Name
Plant Phone Number
Plant Contact/Title
Plant Address (if different than owner/operator's):
Street Address
City State
Zip Code
2. Complete the following table. If additional lines are needed, make copies of this page.
Tank
ro#
Type of tank
Applicable
emission limit
Type of
control technique
Control
system
n>#
Operating parameter
monitored to
demonstrate
compliance
Acceptable value or
range of values for
monitored parameter(s)
Total operating
time during
reporting period
EXAMPLE RESPONSE:
Tank
n>#
1
2
3
Type of tank
Hard chrome
plating
Chrome
anodizing
Hard chrome
plating
Applicable
emission limit
0.015 mg/dscm
45 dynes/cm
0.015 mg/dscm
Type of
control technique
Composite mesh-
pad system
Wetting agent
fume suppressant
Composite mesh-
pad system
Control
system
ID#
10
N/A
10
Operating parameter
monitored to
demonstrate
compliance
pressure drop
surface tension
pressure drop
Acceptable value or
range of values for
monitored
parameter(s)
7 in. w.c. ± 1 in.
<45 dynes/cm
7 in. w.c. ± 1 in.
Total operating
time during
reporting period
l,040hr
l,040hr
l,040hr
Page 1 of 3
-------
ONGOING COMPLIANCE STATUS REPORT (continued)
3. Identify the beginning and ending dates of the reporting period:
Beginning / / Ending / /
4. For hard chromium electroplating tanks that are limiting their maximum cumulative rectifier
capacity in accordance with 40 CFR 63.342(c)(2), complete the following table for this reporting
period:
Tank
ID#
Total for all
tanks
Ampere-hours consumed by month
Month 1
Month 2
Month 3
Month 4
Month 5
Month 6
-
Total ampere-hours
consumed during
reporting period
EXAMPLE RESPONSE
Tank
ID#
1
3
Total for all
tanks
Ampere-hours consumed by month
Month 1
400,000
F 300,000
700,000
Month 2
400,000
300,000
700,000
Month 3
400,000
300,000
700,000
Month 4
200,000
300,000
500,000
Month 5
200,000
300,000
500,000
Month 6
200,000
300,000
500,000
Total ampere-hours
consumed during
reporting period
1,800,000
1,800,000
3,600,000
5. Attach all MONITORING DATA FORMs for the reporting period. Based on the data on excess
emissions and the data on operating times, calculate the following hours:
Hours
Percent of total
operating time
Duration of excess emissions caused by:
Process upsets
Control equipment malfunctions
Other known causes
Unknown causes
Total duration of excess emissions
Page 2 of 3
-------
ONGOING COMPLIANCE STATUS REPORT (continued)
6. Check the box that applies.
D During this reporting period, the work practices identified in 40 CFR 63.342(f) were followed
in accordance with the operation and maintenance plan for this source.
D During this reporting period, the work practices identified in 40 CFR 63.342(f) were not
followed in accordance with the operation and maintenance plan for this source.
7. If the operation and maintenance plan was not followed during the reporting period, please
provide an explanation of the reasons for not following the provisions in the plan, an assessment
of whether any excess emissions and/or parameter monitoring exceedances are believed to have
occurred, and a copy of the appropriate records documenting that the operation and maintenance
plan was not followed. Please state whether or not the plan is being revised accordingly.
8. Please describe any changes in monitoring, processes, or controls since the last reporting period.
9. Print or type the name and title of the Responsible Official for the plant:
(Name) (Title)
A Responsible Official can be:
* The president, vice-president, secretary, or treasurer of the company that owns the plant;
* The owner of the plant;
* The plant engineer or supervisor;
* A government official if the plant is owned by the Federal, State, City, or County
government; or
* A ranking military officer if the plant is located on a military base.
I Certify That The Information Contained In This Report Is Accurate And True To The Best Of
My Knowledge.
(Signature of Responsible Official) (Date)
Page 3 of 3
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TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO.
EPA-453/B-95-001
2.
4. TITLE AND SUBTITLE
A Guidebook on How to Comply with the Chromium
Electroplating and Anodizing National Emission Standards for
Hazardous Air Pollutants
7. AUTHOR(S)
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Emission Standards Division
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
12. SPONSORING AGENCY NAME AND ADDRESS
Federal Small Business Assistance Program
Information Transfer and Program Integration Division
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
April 1995
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
13. TYPE OF REPORT AND
Final
PERIOD COVERED
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
National emission standards to control emissions of chromium compounds from new and existing
chromium electroplating and chromium anodizing tanks were promulgated under Section 112 of the
Clean Air Act in January 1995. This document presents guidance for businesses on how to comply with
the regulation.
17.
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Air pollution control
Anodizing
Chromium
Electroplating
Environmental protection
Hazardous air pollutants
National emission standards
18. DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
Air pollution control
Chromium
Stationary sources
19. SECURITY CLASS (Report)
Unclassified
20. SECURITY CLASS (Page)
Unclassified
c. COSATI Field/Group
21. NO. OF PAGES
150
22. PRICE
EPA Form 2220-1 (Rev. 4-77)
PREVIOUS EDITION IS OBSOLETE
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