United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-002a
February 1999
AIR
©EPA
Final Report - Volume I of
Emissions Testing of Combustion
Stack and Pushing Operations at
Coke Battery No. 5/6 at ABC Coke
in Birmingham, Alabama
-------
FINAL REPORT
EMISSIONS TESTING OF COMBUSTION STACK AND
COKE PUSHING OPERATIONS AT COKE BATTERY NO. 5/6
AT ABC COKE
IN BIRMINGHAM, ALABAMA
Volume I
Report Body and Appendices A, B and C
EPA Contract No. 68-D-98-004 W&&& tT
Work Assignment No. 2-02 ' * U.S. ^ rR ^\G
•;t, IN. '^•T;';1^1
Prepared for:
John C.Bosch, Jr. (MD-19)
Work Assignment Manager
SCGA, EMC, EMAD, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
February 1999
p:\s512.000\fmrpt.wpd
Submitted by:
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333 FAX (919) 941-0234
US EPA-AWBERC LIBRARY
30701 10060609 1
-------
DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D98004, Work Assignment No. 2-02. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.
-------
TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 FILTERABLE PARTICULATE MATTER, METHYLENE CHLORIDE
EXTRACTABLE MATTER (MCEM), AND METALS 2-1
2.3 POLYCYCLIC AROMATIC HYDROCARBONS (PAHs) 2-27
2.4 NON-PUSHING AND NON-CHARGING COKE OVEN BATTERY
OPERATION - UNDERFIRE STACK 2-32
3.0 PROCESS AND CONTROL EQUIPMENT OPERATION 3-1
3.1 INTRODUCTION 3-1
3.2 PROCESS DESCRIPTION 3-1
3.3 PROCESS AND CONTROL DEVICE MONITORING 3-3
4.0 SAMPLING LOCATIONS 4-1
4.1 COKE OVEN BATTERY NO. 5/6 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE 5-3
5.3 DETERMINATION OF STACK GAS EMISSION RATE CORRECTION
FACTORS, DRY MOLECULAR WEIGHT, AND EXCESS AIR 5-3
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-3
5.5 DETERMINATION OF PARTICULATE MATTER/METHYLENE
CHLORIDE EXTRACTABLE MATTER/METALS 5-4
5.6 POLYCYCLIC AROMATIC HYDROCARBONS 5-6
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES AND RESULTS 6-1
6.1 CALIBRATION OF APPARATUS 6-1
111
-------
TABLE OF CONTENTS (Concluded)
Eage
6.2 ON-SITE MEASUREMENTS 6-5
6.3 LABORATORY ANALYSES 6-9
APPENDIX A PROCESS DATA
APPENDIX B RAW FIELD DATA
APPENDIX C ANALYTICAL DATA (Except CARB 429)
APPENDIX D ANALYTICAL DATA (CARB 429)
APPENDIX E CALCULATIONS
APPENDIX F QA/QC DATA
APPENDIX G PARTICIPANTS
APPENDIX H SAMPLING AND ANALYTICAL PROCEDURES
IV
-------
LIST OF TABLES
Page
Table 2.1 Emissions Test Log, ABC Coke, Birmingham, Alabama 2-2
Table 2.2 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-4
Table 2.3 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-6
Table 2.4 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-7
Table 2.5 Multiple Metals Concentrations and Emission Rates - Baghouse Inlet,
ABC Coke, Birmingham, Alabama 2-8
Table 2.6 Particulate Matter/MCEM/Metals Emission Sampling and Flue Gas
Parameters - Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-11
Table 2.7 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-12
Table 2.8 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-13
Table 2.9 Multiple Metals Concentrations and Emission Rates - Baghouse Outlet,
ABC Coke, Birmingham, Alabama 2-14
Table 2.10 Baghouse Dust Multiple Metals Concentrations, ABC Coke,
Birmingham, Alabama 2-18
Table 2.11 Filterable Particulate Matter and Methylene Chloride Extractable
Matter Removal Efficiencies, Coke Oven Battery No. 5/6 Baghouse,
ABC Coke, Birmingham, Alabama 2-19
Table 2.12 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Underfire Stack, ABC Coke, Birmingham, Alabama 2-20
Table 2.13 Filterable Particulate Matter Concentrations and Emission Rates -
Underfire Stack, ABC Coke, Birmingham, Alabama 2-21
Table 2.14 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Underfire Stack, ABC Coke, Birmingham, Alabama 2-23
Table 2.15 Multiple Metals Concentrations and Emission Rates - Underfire Stack
ABC Coke, Birmingham, Alabama 2-24
Table 2.16 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Inlet
ABC Coke, Birmingham, Alabama 2-28
Table 2.17 PAH Concentrations and Emission Rates, Baghouse Inlet,
ABC Coke, Birmingham, Alabama 2-29
-------
LIST OF TABLES (Continued)
Paige
Table 2.18 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Outlet
ABC Coke, Birmingham, Alabama 2-33
Table 2.19 PAH Concentrations and Emission Rates, Baghouse Outlet,
ABC Coke, Birmingham, Alabama 2-34
Table 2.20 PAH Emissions Sampling and Flue Gas Parameters - Underfire Stack
ABC Coke, Birmingham, Alabama 2-37
Table 2.21 PAH Concentrations and Emission Rates Underfire Stack
ABC Coke, Birmingham, Alabama 2-38
Table 2.22 Particulate Matter/MCEM/Metals and PAH Emissions Sampling
and Flue Gas parameters - Underfire Stack Non-pushing and Non-charging
Operation, ABC Coke, Birmingham, Alabama 2-42
Table 2.23 Particulate Matter/MCEM Concentrations and Emission Rates -
Underfire Stack Non-pushing and Non-charging Operation, ABC Coke,
Birmingham, Alabama 2-43
Table 2.24 Multiple Metals Concentrations and Emission Rates -
Underfire Stack Non-pushing and Non-charging Operation, ABC Coke,
Birmingham, Alabama 2-44
Table 2.25 PAH Concentrations and Emission Rates - Underfire Stack Non-pushing and
Non-charging Operation, ABC Coke, Birmingham, Alabama 2-45
Table 3.1 A Pushing Control Device Parameters: Test Run No. 1, 9/21/98 3-4
Table 3. IB Pushing Control Device Parameters: Test Run No. 2, 9/22/98 3-5
Table 3.1C Pushing Control Device Parameters: Test Run No. 3, 9/23/98 3-6
Table 3.2A Combustion Stack Parameters: Test Run No. 1, 9/24/98 3-8
Table 3.2B Combustion Stack Parameters: Test Run No. 2, 9/24/98 3-8
Table 3.2C Combustion Stack Parameters: Test Run No. 3, 9/25/98 3-9
Table 3.2D Combustion Stack Parameters: Test Run No. 4, 9/25/98 3-9
Table 3.3 Combustion Stack Opacity Readings 3-10
Table 5.1 Summary of Sampling Locations, Test Parameters, Sampling Methods,
and Number and Duration of Tests, ABC Coke, Birmingham, Alabama 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-2
Table 6.2 Summary of Pitot Tube Dimensional Data 6-4
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-6
Table 6.4 Summary of EPA Method 315 and CARB Method 429 Field Sampling
QA/QC Data 6-8
Table 6.5 Summary of EPA Method 315 Analytical QC Data Lab Blank Analysis 6-10
Table 6.6 Summary of EPA Method 315 Analytical QC Data Field Blank Analysis ... 6-11
Table 6.7 Summaryof EPA Method 29 Analytical QC Data Lab Control Sample
(LCS) Recovery and Duplicate Analysis 6-13
Table 6.8 Summary of CARB Method 429 Analytical QC Data Field Blank
Results 6-14
VI
-------
LIST OF TABLES (Concluded)
Page
Table 6.9 Summary of CARB Method 429 Analytical QC Data Lab Control
Sample (LCS) 6-15
Table 6.10 Summary of CARB Method 429 Analytical QC Data Surrogate
Standard Recoveries 6-17
VII
-------
LIST OF FIGURES
Page
Figure 1.1 Key Personnel and Responsibility for Testing at ABC Coke, Birmingham,
Alabama 1-2
Figure 4.1 Baghouse Inlet Sample Location, ABC Coke, Birmingham, Alabama 4-2
Figure 4.2 Method 1 Calculation Sheet, Baghouse Inlet, Method 315, ABC Coke,
Birmingham, Alabama 4-3
Figure 4.3 Method 1 Calculation Sheet, Baghouse Inlet, Method CARB 429,
ABC Coke, Birmingham, Alabama 4-4
Figure 4.4 Baghouse Outlet, Sampling Location, ABC Coke,
Birmingham, Alabama 4-5
Figure 4.5 Method 1 Calculation Sheet, Baghouse Outlet, ABC Coke,
Birmingham, Alabama 4-6
Figure 4.6 Combustion (Uhderfire) Stack Sampling Location, ABC Coke,
Birmingham, Alabama 4-8
Figure 4.7 Method 1 Calculation Sheet, Combustion Stack, ABC Coke,
Birmingham, Alabama 4-9
Figure 5.1 Sampling Train Schematic for EPA Method 315 5-5
Figure 5.2 Sampling Train Schematic for CARB Method 429 5-7
Figure 5.3 CARB Method 429 Sample Recovery Schematic 5-8
Figure 5.4 CARB Method 429 Analytical Schematic 5-9
via
-------
1.0 INTRODUCTION
The United States Environmental Protection Agency (EPA) is investigating the coke
manufacturing industry to characterize hazardous air pollutants (HAPs) emitted from coke oven
pushing operations. This test report addresses pushing emissions from a coke oven and emissions
from the combustion (underfire) stack that serves coke Battery No. 5/6 at ABC Coke in
Birmingham, Alabama.
The purpose of this test program was to quantify emissions from the inlet and outlet of
the baghouse controlling emissions from the coke oven pushing operation and to quantify
emissions from the combustion stack outlet. The data may be used by EPA in the future to
support a residual risk assessment for coke oven facilities.
The testing was performed to quantify uncontrolled and controlled air emissions of
filterable particulate matter (PM), methylene chloride extractable matter (MCEM) and 19
polycyclic aromatic hydrocarbons (PAHs) [acenaphthene, acenapthylene, anthracene,
benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(e)pyrene,
benzo(k)fluoranthene, benzo(ghi)perylene, chrysene, dibenzo(a,h)anthracene, fluoranthene,
fluorene, indeno(l,2,3-cd)pyrene, 2-methylnapthalene, napthalene, perylene, phenanthrene, and
pyrene]. In addition, following the PM and MCEM analyses, the samples were analyzed to
screen for the presence of 17 trace metals. Baghouse dust samples were also collected and
analyzed for 16 trace metals. Simultaneous testing was performed at the inlet and outlet of the
baghouse controlling emissions from the coke oven pushing operation. Outlet sampling was also
performed on the combustion outlet stack during both coke pushing and non-pushing conditions.
In addition to pollutant testing, oxygen (02) and carbon dioxide (CO2) were measured at each
location. During the sampling program, Research Triangle Institute (RTI), another EPA
contractor, monitored and recorded process and emission control system operating parameters.
PES used three subcontractors for this effort: DEECO provided technical assistance in
preparation of the Quality Assurance Project Plan (QAPP) and assisted in the field sampling,
Eastern Research Group (ERG) prepared filter media and analyzed the EPA Method 315 samples
for PM and EOM, and Atlantic Technical Services, Inc. (ATS) assisted PES in the custody and
transport of the PAH samples from the field to Quanterra.
In addition, PES used three contract laboratories for analytical services: Quanterra
Environmental Services (Quanterra) provided PAH analyses using California Air Resources
Board (CARB) Method 429, First Analytical Laboratories (FAL) provided metals analyses of the
PM/MCEM sample residues and baghouse dust samples, and Laboratory Corporation of America
(LabCorp) provided PAH analyses using National Institute for Occupational Safety and Health
(NIOSH) Method 5506. The test program organization and major lines of communication are
presented in Figure 1.1.
1-1
-------
Survey
PES
AB
Mar
(205)
CCoke
849-1342
1
PES
QA/QC Coordinator
Dennis P. Holzschuh
(919)941-0333
>ite
t
I
SSTP
PES
EPA/EMC
Work Assignment Manager
John C. Bosch, Jr.
(919)541-5583
PES
Program Manager
John T. Chehaske
(703)471-8383
PES
Project Manager
Franklin Meadows
(919)941-0333
1
QAPP
PES
EPA/ESD
Lula Melton
(919)541-2910
Contractor
Research Triangle Institute
Marvin Branscome
(919)990-8643
Field Testing
PES
Analyses
PES
Report
Preparation
PES
Subcontractor
DEECO
Subcontractor
DEECO
ATS
Subcontractor
ERG
Quanterra
FAL
LabCorp
Figure 1.1 Key Personnel and Responsibility for Testing at ABC Coke, Birmingham, Alabama
1-2
-------
2.0 SUMMARY OF RESULTS
This section provides test result summaries obtained from the ABC Coke testing.
Included in this summary are results of the tests conducted for filterable particulate matter (PM),
methylene chloride extractable matter (MCEM), multiple metals and polycyclic aromatic
hydrocarbons (PAHs) at the baghouse inlet and outlet, and the outlet stack of the combustion
(underfire) stack.
2.1 EMISSIONS TEST LOG
Sampling at the coke oven baghouse used to control pushing emissions was conducted on
September 21, 22, and 23,1998. Sampling on the combustion stack was conducted on
September 24 and 25, 1998. Table 2.1 summarizes the emissions test log. Presented are the run
numbers, test dates, pollutants, run times and downtime for filter and sampling port changes.
2.2 FILTERABLE PARTICULATE MATTER, METHYLENE CHLORIDE
EXTRACTABLE MATTER (MCEM), AND METALS
EPA Method 315 procedures were used to determine PM, MCEM, and 17 metals at the
baghouse inlet and outlet and underfire stack. The target metals included: antimony (Sb), arsenic
(As), barium (Ba), beryllium (Be), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), lead
(Pb), manganese (Mn), mercury (Hg), nickel (Ni), phosphorous (P), selenium (Se), silver (Ag),
thallium (Tl), and zinc (Zn). PM and MCEM are withdrawn isokinetically from the source. The
PM mass includes any material removed in the probe acetone rinse and material on the filter.
The MCEM is determined by adding a methylene chloride rinse of the probe and filter holder,
extracting the condensible hydrocarbons collected in the impinger water, adding an acetone rinse
followed by a methylene chloride rinse of the sampling train components after the filter and
before the silica gel impinger, and determining residue gravimetrically after separating the
solvent. The metals analyses consisted of a nitric acid digestion of the filters and impinger
residues described above. The metals analysis was by Direct Aspiration Flame Atomic
Absorption Spectrophotometry (FLAAS), Graphite Furnace Atomic Absorption
Spectrophotometry (GFAAS), and Inductively Coupled Plasma - Optical Emission (ICP).
Mercury analysis was by Cold Vapor Atomic Adsorption Spectrophotometry (CVAAS). The
baghouse inlet and outlet were sampled simultaneously to determine PM, MCEM, and metals.
Sampling on the underfire stack was performed after the baghouse sampling effort.
2-1
-------
TABLE 2.1
EMISSIONS TEST LOG
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Pollutant
Run Time
Coke Oven Battery No. 5/6 Baghouse Inlet
A-I-M315-1
A-I-M429-1
A-I-M5506-1
A-I-M315-2
A-I-M429-2
A-I-M5506-2
A-I-M315-3
A-I-M429-3
A-I-M5506-3
09/21/98
09/21/98
09/21/98
09/22/98
09/22/98
09/22/98
09/23/98
09/23/98
09/23/98
MCEM/Metals
PAHs
PAHs
MCEM/Metals
PAHs
PAHs
MCEM/Metals
PAHs
PAHs
1128-1911
1128-1912
1147-1847
1018-1816
1018-1816
1022-1753
1016-1800
1019-1810
1022-1724
Downtime, minutes
5.0
6.0
--
52.6
56.0
-
29.0
36.0
-
Coke Oven Battery No. 5/6 Baghouse Outlet
A-O-M315-1
A-0-M429-1
A-O-M5506-1
A-O-M315-2
A-O-M429-2
A-O-M5506-2
A-O-M315-3
A-O-M429-3
A-O-M5506-3
09/21/98
09/21/98
09/21/98
09/22/98
09/22/98
09/22/98
09/23/98
09/23/98
09/23/98
MCEM/Metals
PAHs
PAHs
MCEM/Metals
PAHs
PAHs
MCEM/Metals
PAHs
PAHs
1126-1911
1126-1911
1138-1914
1028-1819
1028-1819
1039-1747
1020-1806
1020-1806
1020-1805
53
53
0
67
71
1
46
46
-
Coke Oven Battery No. 5/6 Combustion Stack
A-U-M315-1
A-U-M429-1
A-U-M315-2
A-U-M429-2
A-U-M315-4
A-U-M429-4
A-U-M5506-1
09/24/98
09/24/98
09/24/98
09/24/98
08/25/98
09/25/98
09/25/98
MCEM/Metals
PAHs
MCEM/Metals
PAHs
MCEM/Metals
PAHs
PAHs
1025-1344
1025-1345
1443-1806
1443-1812
1110-1428
1110-1427
1444-1602
19
20
23
29
18
17
0
2-2
-------
The pushing operation necessitated adjusting sampling rates for maximum air flow during the
actual pushing of coke. The pushing process occurred roughly once every 15 minutes, and lasted
approximately two minutes. This required a maximum sample rate during the two minute push
and a much lower sample rate during the idle time. This sample approach was used for all the
isokinetic sample systems. The isokinetics were based on time weighted averages of pressure
drops (delta p), stack temperatures, and meter temperatures.
The following notes were recorded during the field sampling effort and analysis of
samples. Events were discussed with the WAM and BSD personnel when modifications to the
test plan were required.
• The ductwork at the baghouse inlet sampling site had to be patched prior to the start
of sampling. There was a concern with dilution air entering the inlet duct upstream of
the sampling location.
• Cyclonic flow checks were conducted and flow patterns were non-cyclonic.
Scaffolding at the inlet location was strapped down to steel I-beams as a safety
precaution. Mr. John Bosch requested securing the scaffolding due to the vibration
caused by the process.
• Inlet sample run 1 had an inlet glass nozzle break during port change. Nozzle
replaced and continued with sample run, no effect on sample run.
• Darkness became a safety issue at the end of the sample run 1. It was decided that all
future sample runs would be stopped by 1830 so that personnel would be off
platforms prior to darkness.
• Sampling continued at maximum flow rate for extended periods of time due to
process problems. Normally a push lasted approximately 90 seconds with the fan
operating at maximum flow from two to five minutes. When a push was "stuck", the
fan remained at maximum flow as did our sampling system.
• Calculations of isokinetic sampling rates would be based on time weighted averages
of velocity pressure (delta p), stack temperatures, and meter temperatures.
• The EPA WAM, Mr. John Bosch, requested a thorough review of laboratory sample
handling and analyses procedures.
2.2.1 Coke Oven Battery No. 5/6 Baghouse Inlet
Table 2.2 summarizes the EPA Method 315 baghouse inlet sample times and flue gas
parameters. The total sampling time varies for each test run with an average of 438 minutes.
The average sampling rate was 0.313 dry standard cubic feet per minute (dscfm). The average
sample volume was 138.139 dry standard cubic feet (dscf) or 3.912 dry standard cubic meters
2-3
-------
TABLE 2.2
PARTICULATE MATTER/MCEM/METALS EMISSIONS SAMPLING
AND FLUE GAS PARAMETERS - BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Coke Oven Pushes
Tons of Coke Pushed per Hour
Avg. Sampling Rate, dscfm"
Sample Volume:
dscf*
dscrn0
Avg. Flue Gas Temp, °F
O2 Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfmd
dscfm"
dscmrn'
Isokinetic Sampling Ratio, %
A-I-315-1
09/21/98
458
21
33.3
0.387
177.437
5.024
138
20.2
0.2
3.0
74,526
62,426
1,768
100.3
A-I-315-2
09/22/98
421.4
21
35.4
0.226
95.274
2.698
154
20.3
0.2
2.2
44,982
37,181
1,053
98.3
A-I-315-3
09/23/98
435
22
34.9
0.326
141.706
4.013
137
20.3
0.2
1.9
63,350
53,989
1,529
97.6
Average
-
438
21
34.5
0.313
138.139
3.912
143
20.3
0.2
2.4
60,953
51,199
1,450
98.7
"Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
"Dry standard cubic meters at 68°F (20°C) and 1 atm.
dActual cubic feet per minute at flue gas conditions.
'Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-4
-------
(dscm). The average flue gas temperature was 143 degrees Fahrenheit (°F). The flue gas
contained 0.2 percent (%) carbon dioxide (C02), 20.3 % oxygen (O2) and 2.4 % moisture. The
average flue gas volumetric flow rate was 60,953 actual cubic feet per minute (acfin) or 51,199
dscfrn, or 1,450 dry standard cubic meters per minute (dscmm).
Table 2.3 summarizes the flue gas PM concentrations and emission rates at the baghouse
inlet. The average concentration was 0.122 grains per dry standard cubic foot (gr/dscf) or
1.74E-05 pounds per dry standard cubic foot (Ib/dscf) or 2.78E+05 micrograms per dry standard
cubic meter (/^g/dscm). The average emission rate was 50.6 pounds per hour (Ib/hr) or 2.30E+10
micrograms per hour Gug/hr) or 1.46 pounds per ton of coke pushed (Ib/ton pushed).
Table 2.4 summarizes the flue gas MCEM concentrations and emission rates at the
baghouse inlet. The average MCEM concentration was 8.33E-04 gr/dscf or 1.19E-07 Ib/dscf or
1.90E+03 Aig/dscm. The average MCEM emission rate was 0.356 Ib/hr or 1.61E+08 /^g/hr or
1.04E-02 Ib/ton pushed.
Table 2.5 summarizes the flue gas metals concentrations and emission rates. The PM and
MCEM residues were analyzed for 17 metals. Measured inlet metals concentrations were blank
corrected based on the quartz filter blank results. Average concentrations ranged from
0.032/^g/dscm for silver to 16.6 /zg/dscm for phosphorous.
2.2.2 Coke Oven Battery No. 5/6 Baghouse Outlet
Table 2.6 summarizes the EPA Method 315 baghouse outlet sample times and flue gas
parameters. The total test time varied for the three test runs, with an average time of
412 minutes. The average sampling rate was 0.330 dscfm. The average sampling volume was
136.209 dscf or 3.857 dscm. The average flue gas temperature was 124 °F, with average stack
gas compositions of 20.4 % O2 and 0.2 % CO2. Moisture content of the flue gas averaged 2.5 %.
Flue gas volumetric flow rates averaged 62,687 acfm or 55,107 dscfm or 1,561 dscmm. The
isokinetic sampling rate averaged 94.9 %.
Table 2.7 summarizes the PM concentrations and emission rates for the baghouse outlet.
The average PM concentration was 1.20E-03 gr/dscf or 1.71E-07 Ib/dscf or 2.74E+03 Aig
The average emission rate was 0.552 Ib/hr or 2.50E+08 /^g/hr or 1.59E-02 Ib/ton pushed.
Table 2.8 summarizes the MCEM concentrations and emission rates for the baghouse
outlet. Concentrations averaged 6.97E-04 gr/dscf or 9.96E-08 Ib/dscf or 1.60E+03 //g/dscm.
Emission rates averaged 0.350 Ib/hr or 15.9E+07 Mg/hr or 1.04E-02 Ib/ton pushed.
Table 2.9 summarizes the multiple metals concentrations and emission rates for the
combined PM and MCEM fractions collected with the EPA Method 315 sampling trains.
Several of the 17 target metals were found to be non-detectable.
2-5
-------
TABLE 2.3
FILTERABLE PARTICIPATE MATTER CONCENTRATIONS
AND EMISSION RATES - BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
lb/dscf
Mg/dscmc
Emission Rate:
Ib/hr*
//g/hr*
Ib/ton pushed'
A-I-315-1
09/21/98
1628-1911
0.083
1.19E-05
1.90E+05
44.4
2.01E+10
1.33E+00
A-I-315-2
09/22/98
1018-1816
0.160
2.29E-05
3.66E+05
51.0
2.32E+10
1.44E+00
A-I-315-3
09/23/98
1016-1800
0.122
1.74E-05
2.79E+05
56.4
2.56E+10
1.62E+00
Average
-
-
0.122
1.74E-05
2.78E+05
50.6
2.30E+10
1.46E+00
"Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
'Pounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
cMicrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
cMicrograms per hour.
"Pounds per ton of coke pushed.
2-6
-------
TABLE 2.4
METHYLENE CHLORIDE EXTRACTABLE MATTER CONCENTRATIONS
AND EMISSION RATES - BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
lb/dscf
yug/dscmc
Emission Rate:
Ib/hr*
yUg/hl*
Ib/ton pushedf
A-I-315-1
09/21/98
1128-1911
9.74E-04
1.39E-07
2.23E+03
0.521
2.36E+08
1.56E-02
A-I-315-2
09/22/98
1018-1816
10.9E-04
1.55E-07
2.48E+03
0.346
1.57E+08
0.98E-02
A-I-315-3
09/23/98
1016-1800
4.36E-04
0.62E-07
l.OOE+03
0.202
0.91E+08
0.58E-02
Average
-
-
8.33E-04
1.19E-07
1.90E+03
0.356
1.61E+08
1.04E-02
'Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
bPounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
°Micrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
'Micrograms per hour.
fPounds per ton of coke pushed.
2-7
-------
TABLE 2.5
MULTIPLE METALS CONCENTRATIONS AND EMISSION RATES
BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Antimony
Atg/dscnv1
Mg/hr"
Ib/hr*
Ib/ton pushedd
Arsenic
Aig/dscm"
Mg/hr"
Ib/hr"
Ib/ton pushedd
Barium
Aig/dscm"
Aig/hr11
lb/hr°
Ib/ton pushedd
Beryllium
Aig/dscma
Atg/hr11
Ib/hr"
Ib/ton pushed*
Cadmium
Aig/dscnf1
Aig/hr"
Ib/hr*
Ib/ton pushed11
Chromium
Aig/dscma
Mg/hr*
Ib/hr1
Ib/ton pushedd
Cobalt
A/g/dscma
A^g/hr6
Ib/hr"
Ib/ton pushedd
Copper
Mg/dscma
Pg/hr11
Ib/hr*
Ib/ton pushed1*
A-I-315-1
09/21/98
1128-1911
0.100
10.6E+03
2.32E-05
6.96E-07
3.3
3.55E+05
7.80E-04
2.34E-05
7.20
7.64E+05
1.68E-03
5.04E-05
0.070
7.39E+03
1.63E-05
4.87E-07
0.076
8.02E+03
1.76E-05
5.29E-07
2.57
2.72E+05
5.99E-04
1.80E-05
0.498
52.8E+03
1.16E-04
3.48E-06
3.20
3.40E+05
7.48E-04
2.24E-05
A-I-315-2
09/22/98
1018-1816
ND
ND
ND
ND
4.3
2.69E+05
5.92E-04
1.67E-05
15.5
9.79E+05
2.15E-03
6.09E-05
0.174
ll.OE+03
2.42E-05
6.84E-07
0.133
8.43E+03
1.85E-05
5.24E-07
4.37
2.76E+05
6.08E-04
1.72E-05
0.741
46.8E+03
1.03E-04
2.91E-06
4.23
2.67E+05
5.87E-04
1.66E-05
A-I-315-3
09/23/98
1016-1800
ND
ND
ND
ND
2.4
2.22E+05
4.88E-04
1.40E-05
8.87
8.14E+05
1.79E-03
5.13E-05
0.120
ll.OE+03
2.41E-05
6.92E-07
2.54
233E+03
51.3E-05
147E-07
2.44
2.24E+05
4.93E-04
1.41E-05
0.399
36.6E+03
0.805E-04
2.31E-06
6.40
5.87E+05
12.9E-04
3.70E-05
Average
-
-
0.030
3.51E+03
0.77E-05
2.32E-07
3.3
2.82E+05
6.20E-04
1.80E-05
10.5
8.52E+05
1.87E-03
5.42E-05
0.121
9.79E+03
2.15E-05
6.21E-07
0.917
83.2E+03
18.3E-05
52.5E-07
3.13
2.58E+05
5.67E-04
1.64E-05
0.546
45.4E+03
0.999E-04
2.90E-06
4.61
3.98E+05
8.76E-04
2.54E-05
2-8
-------
TABLE 2.5 (cont'd)
Run No.
Lead
//g/dscm"
Mg/hr"
Ib/hr*
Ib/ton pushed*
Manganese
Mg/dscnf1
Mg/hr"
Ib/hr*
Ib/ton pushedd
Mercury
^g/dscnr1
Mg/hr11
Ib/hr0
Ib/ton pushedd
Nickel
yug/dscm3
Aig/hr"
Ib/hr"
Ib/ton pushed"1
Phosphorus
^g/dscm"
jig/hr11
lb/hr°
Ib/ton pushed11
Selenium
Mg/dscma
Mg/hr11
Ib/hr"
Ib/ton pushedd
Silver
^g/dscm"
/Jg/hr*
Ib/hr*
Ib/ton pushed"1
Thallium
^g/dscm"
Mg/hr11
Ib/hr6
Ib/ton pushedd
A-I-315-1
4.1
4.35E+05
9.57E-04
2.87E-05
6.1
70.9E+04
15.6E-04
4.68E-05
ND
ND
ND
ND
3.9
41.4E+04
9.10E-04
2.73E-05
11.7
1.25E+06
2.74E-03
8.22E-05
0.88
92.9E+03
2.04E-04
6.13E-06
0.060
6,333
13.9E-06
4.18E-07
0.22
23.2E+03
5.11E-05
1.53E-06
A-I-315-2
6.5
4.12E+05
9.07E-04
2.56E-05
5.9
37.5E+04
8.24E-04
2.33E-05
ND
ND
ND
ND
5.2
32.8E+04
7.21E-04
2.04E-05
20.8
1.31E+06
2.88E-03
8.15E-05
1.33
84.3E+03
1.85E-04
5.24E-06
0.037
2,341
5.15E-06
1.46E-07
0.41
25.8E+03
5.67E-05
1.60E-06
A-I-315-3
4.3
3.91E+05
8.60E-04
2.46E-05
4.5
41.6E+04
9.15E-04
2.62E-05
ND
ND
ND
ND
6.1
55.5E+04
12.2E-04
3.50E-05
17.4
1.60E+06
3.52E-03
10.1E-05
1.07
98.3E+03
2.16E-04
6.20E-06
ND
ND
ND
ND
0.30
27.4E+03
6.03E-05
1.73E-06
Average
5.0
4.13E+05
9.08E-04
2.63E-05
5.7
50.0E+04
ll.OE-04
3.21E-05
ND
ND
ND
ND
5.0
43.2E+04
9.51E-04
2.76E-05
16.6
1.39E+06
3.05E-03
8.82E-05
1.09
91.8E+03
2.02E-04
5.86E-06
0.032
2,891
6.36E-06
1.88E-07
0.31
25.5E+03
5.60E-05
1.62E-06
2-9
-------
TABLE 2.5 (concluded)
Run No.
Zinc
Mg/dscma
Mg/hr11
Ib/hi*
Ib/ton pushedd
A-I-315-1
12.9
1.37E+06
3.02E-03
9.05E-05
A-I-315-2
15.6
0.983E+06
2.16E-03
6.12E-05
A-I-315-3
12.2
1.12E+06
2.46E-03
7.06E-05
Average
13.6
1.16E+06
2.55E-03
7.41 E-05
"Micrograms per dry standard cubic meter.
bMicrograms per hour.
"Pounds per hour.
^Pounds per ton of coke pushed.
ND - non detected, counted as "zero".
2-10
-------
TABLE 2.6
PARTICULATE MATTER/MCEM/METALS EMISSIONS SAMPLING AND
FLUE GAS PARAMETERS - BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Coke Oven Pushes
Tons of Coke Pushed per Hour
Avg. Sampling Rate, dscfm"
Sample Volume:
dscf*
dscmc
Avg. Flue Gas Temp, °F
Oz Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfm"
dscfm"
dscmm"
Isokinetic Sampling Ratio, %
A-0-315-1
09/21/98
412
20
33.2
0.409
168.639
4.775
118
20.4
0.2
2.8
73,527
64,792
1,835
99.6
A-O-315-2
09/22/98
404
23
35.9
0.257
103.955
2.944
133
20.4
0.2
2.7
47,139
40,579
1,149
100.0
A-O-315-3
09/23/98
420
22
34.7
0.324
136.034
3.852
120
20.4
0.1
1.9
67,395
59,951
1,698
85.2
Average
-
412
22
34.6
0.330
136.209
3.857
124
20.4
0.2
2.5
62,687
55,107
1,561
94.9
'Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
'Dry standard cubic meters at 68°F (20°C) and 1 atm.
•"Actual cubic feet per minute at flue gas conditions.
"Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-11
-------
TABLE 2.7
FILTERABLE PARTICIPATE MATTER CONCENTRATIONS
AND EMISSION RATES - BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
Ib/dscf
Aig/dscmc
Emission Rate:
Ib/hr4
Mg/hr"
Ib/ton pushedf
A-0-315-1
09/21/98
1126-1911
0.567E-03
0.81E-07
1.30E+03
0.315
1.43E+08
0.95E-02
A-O-315-2
09/22/98
1028-1819
1.28E-03
1.82E-07
2.92E+03
0.444
2.01E+08
1.24E-02
A-O-315-3
09/23/98
1020-1806
1.75E-03
2.50E-07
4.0E+03
0.898
4.07E+08
2.59E-02
Average
-
~
1.20E-03
1.71E-07
2.74E+03
0.552
2.51E+08
1.59E-02
"Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
•"Pounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
cMicrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
"Micrograms per hour.
"Pounds per ton of coke pushed.
2-12
-------
TABLE 2.8
METHYLENE CHLORIDE EXTRACTABLE MATTER CONCENTRATIONS
AND EMISSION RATES - BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
lb/dsci*
yug/dscmc
Emission Rate:
Ib/hr*
^g/hr"
Ib/ton pushedf
A-O-315-1
09/21/98
1126-1911
14.3E-04
20.4E-08
3.27E+03
0.793
36.0E+07
2.39E-02
A-O-315-2
09/22/98
1028-1819
5.05E-04
7.21E-08
1.16E+03
0.176
7.96E+07
0.49E-02
A-O-315-3
09/23/98
1020-1806
1.59E-04
2.27E-08
0.36E+03
0.082
3.70E+07
0.24E-02
Average
-
-
6.97E-04
9.96E-08
1.60E+03
0.350
15.9E+07
1.04E-02
"Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
•"Pounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
cMicrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
"Micrograms per hour.
fPounds per ton of coke pushed.
2-13
-------
TABLE 2.9
MULTIPLE METALS CONCENTRATIONS AND
EMISSION RATES - BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Antimony
pg/dscma
Aig/hr1'
Ib/hr*
Ib/ton pushed1*
Arsenic
Hg/dscm"
A*g/hr"
Ib/hr"
Ib/ton pushed"1
Barium
/^g/dscnr1
Mg/hr1'
Ib/hr"
Ib/ton pushed*
Beryllium
/ug/dscm"
Aig/hr"
lb/hr°
Ib/ton pushed11
Cadmium
/ug/dscma
/ig/hi^
Ib/hr*
Ib/ton pushed*
Chromium
^g/dscma
Mg/hr"
lb/hr*
Ib/ton pushed*
Cobalt
Aig/dscma
^g/hr"
Ib/hr*
Ib/ton pushed*
Copper
^g/dscma
/^g/hH1
Ib/hr1
Ib/ton pushed*
A-O-315-1
09/21/98
1126-1911
ND
ND
ND
ND
0.63E-01
6,916
1.52E-05
4.58E-07
1.03
1.13E+05
2.49E-04
7.48E-06
ND
ND
ND
ND
1.88E-02
2,075
4.56E-06
1.37E-07
0.398
4.38E+04
0.96E-04
2.90E-06
ND
ND
ND
ND
0.586
6.45E+04
1.42E-04
4.27E-06
A-O-315-2
09/22/98
1028-1819
ND
ND
ND
ND
1.36E-01
9,369
2.06E-05
5.74E-07
2.34
1.61E+05
3.56E-04
9.90E-06
1.02E-02
703
1.55E-06
4.30E-08
4.08E-02
2,811
6.18E-06
1.72E-07
1.019
7.03E+04
1.55E-04
4.30E-06
ND
ND
ND
ND
1.22
8.43E+04
1.85E-04
5.16E-06
A-O-315-3
09/23/98
1020-1806
ND
ND
ND
ND
1.30E-01
13,221
2.91E-05
8.38E-07
2.02
2.06E+05
4.54E-04
13.1E-06
1.04E-02
1,058
2.33E-06
6.70E-08
1.82E-02
1,851
4.07E-06
1.17E-07
0.909
9.25E+04
2.04E-04
5.87E-06
ND
ND
ND
ND
1.14
11.63E+04
2.56E-04
7.37E-06
Average
-
-
ND
ND
ND
ND
1.10E-01
9,835
2.15E-05
6.23E-07
1.80
1.60E+05
3.53E-04
10.1E-06
0.682E-02
587
1.29E-06
3.67E-08
2.59E-02
2,245
4.94E-06
1.42E-07
0.775
6.89E+04
1.52E-04
4.36E-06
ND
ND
ND
ND
0.984
8.84E+04
1.94E-04
5.60E-6
2-14
-------
TABLE 2.9 (cont'd)
Run No.
Lead
Aig/dscnv1
Mg/hr"
Ib/hr*
Ib/ton pushed"1
Manganese
Mg/dscnr1
Mg/hr1"
Ib/hr^
Ib/ton pushedd
Mercury
Mg/dscma
Mg/rir11
Ib/hr"
Ib/ton pushed1*
Nickel
Aig/dscm"
^g/hr"
Ib/hr*
Ib/lon pushed"1
Phosphorus
Aig/dscm"
/^g/hr1"
Ib/hr1
Ib/ton pushedd
Selenium
^g/dscnv1
^g/hr"
Ib/hr"
Ib/ton pushedd
Silver
/ig/dscma
^g/hr"
Ib/hr1
Ib/ton pushed"1
Thallium
Mg/dscm"
Mg/hr1"
Ib/hi*
Ib/ton pushed"1
A-O-315-1
0.251
2.77E+04
6.09E-05
1.83E-06
0.524
0.576E+05
1.27E-04
3.82E-06
ND
ND
ND
ND
ND
ND
ND
ND
3.35
3.69E+05
8.11E-04
2.44E-05
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
A-O-315-2
0.849
5.86E+04
12.9E-05
3.59E-06
1.53
1.05E+05
2.32E-04
6.46E-06
ND
ND
ND
ND
0.611
4.22E+04
9.27E-05
2.58E-06
5.10
3.51E+05
7.73E-04
2.15E-05
0.204
1.41E+04
3.09E-05
8.61E-07
ND
ND
ND
ND
ND
ND
ND
ND
A-O-315-3
0.415
4.23E+04
9.31E-05
2.68E-06
1.40
1.43E+05
3.14E-04
9.05E-06
ND
ND
ND
ND
0.312
3.17E+04
6.98E-05
2.01E-06
5.19
5.29E+05
11.6E-04
3.35E-05
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
0.505
4.28E+04
9.43E-05
2.70E-06
1.15
1.02E+05
2.24E-04
6.44E-06
ND
ND
ND
ND
0.308
2.46E+04
5.42E-05
1.53E-06
4.55
4.16E+05
9.I6E-04
2.65E-05
0.068
0.468E+04
1.03E-05
2.87E-07
ND
ND
ND
ND
ND
ND
ND
ND
2-15
-------
TABLE 2.9 (concluded)
Run No.
Zinc
//g/dscma
Mg/nrb
Ib/hi*
Ib/ton pushed11
A-O-315-1
2.30
2.54E+05
5.58E-04
1.68E-05
A-O-315-2
4.42
3.04E+05
6.70E-04
1.86E-05
A-O-315-3
3.89
3.97E+05
8.73E-04
2.51E-05
Average
3.54
3.18E+05
7.00E-04
2.02E-05
"Micrograms per dry standard cubic meter.
bMicrograms per hour.
'Pounds per hour.
dPounds per ton of coke pushed.
ND - non detected, counted as "zero".
2-16
-------
Table 2.10 summarizes the multiple metals concentrations from the baghouse dust
samples collected during each baghouse sample run. Baghouse samples were collected from the
dust hoppers at the beginning, middle, and end of each run.
Table 2.11 summarizes the PM and MCEM removal efficiencies for the Coke Oven
Battery No. 5/6 baghouse. PM removal efficiencies averaged 98.9 %. The MCEM data showed
a negative removal efficiency for Run 1 and an average removal efficiency of 54.3% for Runs 2
and 3.
The following notes were recorded during the field sampling effort and analyses of
samples. Events were discussed with the WAM and ESD personnel when modifications to the
test plan were required.
• Cyclonic flow checks were conducted and flow patterns were non-cyclonic.
• As discussed previously, maximum process air flow rates continued for extended
periods as did the sampling train sample rates.
• Calculation of isokinetics, as discussed previously, also applies to the outlet
location.
• Darkness became a safety issue at the end of sample run 1. It was decided that all
future sample runs would be stopped by 1830 so that personnel would be off
platforms prior to darkness.
2.2.3 Underfire Stack
The combustion or underfire stack was sampled for PM and MCEM concentrations and
emission rates, as well as multiple metals analysis on the MCEM filters and residue. A total of
four, 180 minute sample runs were conducted at this test location.
Table 2.12 summarizes the EPA Method 315 underfire stack sample times and flue gas
parameters measured. Four sample runs were conducted over the course of two days. Run No.
A-U-315-3 was conducted during an operational period that did not include any coke oven
charging or pushing. Data presented in the following tables is from periods of coke oven
charging and pushing (test Run Nos. A-U-315-1, 2, and 4). The average sampling time was 180
minutes. The average sampling rate was 0.628 dscfm. The average sample volume was
113.032 dscf or 3.201 dscm. Flue gas temperatures averaged 454 °F, with an average stack gas
composition of 2.8 % CO2 and 14.4 % O2. Flue gas moisture content averaged 14.1 %. The flue
gas volumetric flow rate averaged 81,155 acfm or 40,071 dscfm or 1,135 dscmm. Isokinetic
sampling rates for the sample runs averaged 100 %.
Table 2.13 summarizes the PM concentrations and emission rates for the underfire stack.
Concentrations averaged 1.94E-02 gr/dscf or 2.77E-06 dscf or 4.45E+04 ^g/dscm. Emission
2-17
-------
TABLE 2.10
BAGHOUSE DUST MULTIPLE METALS CONCENTRATIONS
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Antimony, Mg/gf
Arsenic, A
-------
TABLE 2.11
FILTERABLE PARTICIPATE MATTER AND METHYLENE CHLORIDE
EXTRACT ABLE MATTER REMOVAL EFFICIENCIES
COKE OVEN BATTERY NO. 5/6 BAGHOUSE
ABC COKE, BIRMINGHAM, ALABAMA
Test Set No.
Date
M315-1
09/21/98
M-315-2
09/22/98
M315-3
09/23/98
Average
-
Filterable Paniculate Matter
Emission Rate, Ib/hr"
Inlet
Outlet
Removal Efficiency, %b
44.4
0.315
99.3
51.0
0.444
99.1
56.4
0.898
98.4
50.6
0.552
98.9
Extractable Organic Matter
Emission Rate, Ib/hr"
Inlet
Outlet
Removal Efficiency, %b
0.521
0.793
0
0.346
0.176
49.1
0.202
0.082
59.4
0.356
0.350
36.2
"Pounds per hour.
bRemoval Efficiency, % = Inlet. Ib/hr - Outlet. Ib/hr x 100
Inlet, Ib/hr
2-19
-------
TABLE 2.12
PARTICULATE MATTER/MCEM/METALS EMISSIONS SAMPLING AND
FLUE GAS PARAMETERS - UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Tons of Coal Charged per Hour
Avg. Sampling Rate, dscfm"
Sample Volume:
dscf
dscrn'
Avg. Flue Gas Temp, °F
O2 Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfmd
dscfm"
dscmm'
Isokinetic Sampling Ratio, %
A-U-315-1
09/24/98
180
50.8
0.638
114.814
3.251
449
14.7
2.7
13.9
77,737
38,682
1,095
105
A-U-315-2
09/24/98
180
54.4
0.631
113.638
3.218
437
15.0
3.0
15.0
82,178
40,898
1,158
98.6
A-U-315-4
09/25/98
180
37.2
0.615
110.643
3.133
476
13.5
2.8
13.3
83,514
40,634
1,151
96.6
Average
-
180
47.5
0.628
113.032
3.201
454
14.4
2.8
14.1
81,155
40,071
1,135
100
"Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
"Dry standard cubic meters at 68°F (20°C) and 1 atm.
d Actual cubic feet per minute at flue gas conditions.
cDry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-20
-------
TABLE 2.13
FILTERABLE PARTICIPATE MATTER CONCENTRATIONS
AND EMISSION RATES - UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
Ib/dscf
^g/dscm<
Emission Rate:
Ib/hr"
A^g/hr*
Ib/ton charged'
A-U-315-1
09/24/98
1025-1344
1.55E-02
2.21E-06
3.55E+04
5.1
2.33E+09
1.01E-01
A-U-315-2
09/24/98
1443-1806
1.91E-02
2.73E-06
4.38E+04
6.7
3.04E+09
1.23E-01
A-U-315-4
09/25/98
1110-1428
2.36E-02
3.38E-06
5.41E+04
8.2
3.73E+09
2.21E-01
Average
~
~
1.94E-02
2.77E-06
4.45E+04
6.7
3.03E-K)9
1.49E-01
"Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
'Pounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
cMicrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
'Micrograms per hour.
*Pounds per ton of coal charged.
2-21
-------
rates averaged 6.7 Ib/hr or 3.03E+09 Aig/hr or 1.49E-01 pounds per ton of coal charged (Ib/ton
charged).
Table 2.14 summarizes the MCEM concentrations and emission rates for the three sample
runs. Concentrations averaged 5.02E-04 gr/dscf or 7.18E-08 Ib/dscf or 1.15E+03 //g/dscm.
Emission rates averaged 0.17 Ib/hr or 7.78E+07 ,ug/hr or 3.50E-03 Ib/ton charged.
Table 2.15 summarizes the multiple metal concentrations and emission rates from the PM
and MCEM residues of the EPA Method 315 samples. Measured underfire metals
concentrations were blank corrected based on the blank quartz filter results. Several of the target
analytes were below detectable quantities for most of the test runs.
The following notes were recorded during the field sampling effort and analysis of
samples. Events were discussed with the WAM and ESD personnel when modifications to the
test plan were required.
• Cyclonic flow checks were conducted and flow patterns were non-cyclonic.
• Scaffolding at the underfire location was strapped to the stack and additional tie
downs were used to insure safety. Special brackets were fabricated onsite to
allow for sampling with a 11 foot glass lined probe.
• Preliminary flows were measured all the way across both traverse cross-sections
to insure laminar-consistent flow throughout the full traverse. A specially
designed traverse system was used to measure these flows. The result of the
traverses showed consistent measurements throughout the traverse.
• The official sample was traversed % of the stack through the two available sample
ports. It was not possible to sample the other two ports due to physical constraints
and safety concerns.
• Mark Poling of ABC Coke requested an additional sample run be performed on
the Underfire Stack during nonpushing and noncharging process operations.
EMC and ESD discussed this recommendation and it was agreed to. The non-
pushing and non-charging run was sample run 3.
Ports were thoroughly cleaned out by plant personnel and CCC Group (facility
contractor) prior to our sampling efforts.
The Method 429 sample system measured flow rate inaccurately during the first
part of sample run 1. Flows were biased low due to misreading the manometer.
This caused isokinetics to be slightly low at 87.6 %.
2-22
-------
TABLE 2.14
METHYLENE CHLORIDE EXTRACTABLE MATTER CONCENTRATIONS
AND EMISSION RATES - UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
Ib/dscf*
^g/dscm"
Emission Rate:
Ib/hr11
Mg/hr"
Ib/ton chargedf
A-U-315-1
09/24/98
1025-1344
6.85E-04
9.79E-08
1.57E+03
0.23
10.3E+07
4.47E-03
A-U-315-2
09/24/98
1443-1806
5.70E-04
8.15E-08
1.31E+03
0.20
9.07E+07
3.67E-03
A-U-315-4
09/25/98
1110-1428
2.51E-04
3.59E-08
0.58E+03
0.09
3.97E+07
2.35E-03
Average
-
-
5.02E-04
7.18E-08
1.15E+03
0.17
7.78E+07
3.50E-03
"Grains per dry standard cubic foot at 68°F (20°C) and 1 atm.
••Pounds per dry standard cubic foot at 68°F (20°C) and 1 atm.
"Micrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
•"Pounds per hour.
"Micrograms per hour.
"Pounds per ton of coal charged.
2-23
-------
TABLE 2.15
MULTIPLE METALS CONCENTRATIONS AND
EMISSION RATES - UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Antimony
^g/dscm"
Mg/hr"
Ib/hr"
Ib/ton charged*
Arsenic
Mg/dscm'
Mg/hr"
Ib/hr*
Ib/ton charged*
Barium
Mg/dscm"
Mg/hr1"
Ib/hr*
Ib/ton charged*
Beryllium
/^g/dscm"
^g/hr11
Ib/hr1
Ib/ton charged*
Cadmium
^g/dscm"
jug/hr1"
Ib/hr"
Ib/ton charged*
Chromium
Mg/dscma
Aig/hr''
Ib/hr1
Ib/ton charged*
Cobalt
A
-------
TABLE 2.15 (continued)
Run No.
Lead
Aig/dscm"
Aig/hr"
Ib/hr*
Ib/ton charged11
Manganese
/^g/dscm"
Aig/hr*
Ib/hr*
Ib/ton chargedd
Mercury
/ug/dscma
A'g/hr'1
Ib/hr1
Ib/ton charged1*
Nickel
A(g/dscma
Mg/hr"
Ib/hr*
Ib/ton charged"1
Phosphorus
Aig/dscm"
Aig/hr"
lb/hi*
Ib/ton charged"1
Selenium
Atg/dscm"
Aig/hr1"
Ib/hr*
Ib/ton charged"1
Silver
Aig/dscm"
Aig/hr1"
Ib/hr"
Ib/ton charged"1
Thallium
Hg/dscm*
Atg/hr11
Ib/hi*
Ib/ton charged"1
A-U-315-1
7.39E-03
53.2E+04
10.7E-07
2.11E-08
2.19E-03
15.8E+04
3.17E-07
0.62E-08
ND
ND
ND
ND
l.OOE-03
7.22E+04
1.45E-07
2.86E-09
1.37E-02
9.85E+05
1.98E-06
3.90E-08
1.83E-03
13.1E+04
2.64E-07
0.52E-08
ND
ND
ND
ND
8.22E-04
59.2E+03
1.I9E-07
2.34E-09
A-U-315-2
7.25E-03
58.4E+04
11.1E-07
2.04E-08
4.84E-03
38.9E+04
7.39E-07
1.36E-08
ND
ND
ND
ND
2.50E-03
20.2E+04
3.83E-07
7.03E-09
3.11E-02
25.0E+05
4.75E-06
8.73E-08
3.71E-03
29.9E+04
5.68E-07
1.04E-08
ND
ND
ND
ND
8.63E-04
69.5E+03
1.32E-07
2.43E-09
A-U-315-4
4.61E-03
36.6E+04
7.00E-07
1.88E-08
5.39E-03
42.8E+04
8.18E-07
2.20E-08
ND
ND
ND
ND
1.39E-03
ll.OE+04
2.HE-07
5.68E-09
2.61E-02
20.7E+05
3.96E-06
10.7E-08
4.52E-03
35.9E+04
6.86E-07
1.85E-08
ND
ND
ND
ND
6.95E-04
55.2E+03
1.06E-07
2.84E-09
Average
6.42E-03
49.4E+04
9.59E-07
2.01E-08
4.14E-03
32.5E+04
6.25E-07
1.39E-08
ND
ND
ND
ND
1.63E-03
12.8E+04
2.46E-07
5.19E-09
2.36E-02
18.5E+05
3.56E-06
7.76E-08
3.35E-03
26.3E+04
5.06E-07
I.14E-08
ND
ND
ND
ND
7.93E-04
61.3E+03
1.19E-07
2.54E-09
2-25
-------
TABLE 2.15 (concluded)
Run No.
Zinc
Aig/dscm"
Aig/hr1"
Ib/hr*
Ib/ton chargedd
A-U-315-1
2.37E-02
1.71E+06
3.43E-06
6.76E-08
A-U-315-2
2.76E-02
2.22E+06
4.22E-06
7.76E-08
A-U-315-4
2.61E-02
2.07E+06
3.96E-06
10.7E-08
Average
2.58E-02
2.00E+06
3.87E-06
8.39E-08
"Micrograms per dry standard cubic meter.
bMicrograms per hour.
"Pounds per hour.
^Pounds per ton of coal charged.
2-26
-------
• It was not possible to run the NIOSH Method 5506 sample system due to the limited
number of ports (2). One NIOSH method 5506 sample was performed at the end of the
Method 429 and 315 sampling.
2.3 POLYCYCLIC AROMATIC HYDROCARBONS (PAHs)
The polycyclic aromatic hydrocarbons (PAHs) were collected using CARB Method 429,
"Determination of Polycyclic Aromatic Hydrocarbons from Stationary Sources." This method
was used to determine 19 individual PAHs. Particulate and gaseous phase PAHs were extracted
isokinetically from each source and collected in the probe, Teflon® filter, XAD® resin and
impinger portions of the sampling train. The baghouse inlet and outlet were sampled
simultaneously for the measurement of PAHs. The underfire stack PAHs were sampled
concurrently with the EPA Method 315 sampling train, and was performed after the baghouse
sampling effort. The concentrations at all three sample locations were corrected for the method
blank.
A NIOSH Method 5506 sample system was used to scan for gaseous phase PAHs at the
baghouse inlet/outlet and underfire stack. The NIOSH approach was used as a backup approach
to the CARB Method 429 sampling system. The PAHs had never been sampled at these sample
locations and there was no previous records of PAH detectable limits or quantities. The NIOSH
analytical results are presented in Appendix C. The majority of the NIOSH Method 5506 PAH
results were at the method detection limits.
2.3.1 Coke Oven Battery No. 5/6 Baghouse Inlet
Table 2.16 summarizes the CARB Method 429 sample times and flue gas parameters at
the baghouse inlet. One sample run was conducted per day. The average length of the sample
runs was 438 minutes. The average sampling rate was 0.305 dscfm. The average sample volume
was 134.585 dscf or 3.811 dscm.
The average flue gas temperature was 130 °F, with a stack gas composition of 0.2 % CO2
and 20.3 % O2. Moisture content averaged 3.1 %. Flue gas volumetric flow rates averaged
62,574 acfm or 53,246 dscfm or 1,508 dscmm. The isokinetic sampling rate averaged 101 %.
Table 2.17 summarizes the PAH concentrations and emission rates for the baghouse inlet.
All compounds were found in detectable levels for the three test runs. Naphthalene was found in
the highest concentrations, at an average of 53.7 ^g/dscm. Acenphthylene and
2-methylnaphthalene were the other two compounds occurring in high concentrations (relative to
the other compounds).
2-27
-------
TABLE 2.16
PAH EMISSIONS SAMPLING AND FLUE
GAS PARAMETERS - BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Coke Oven Pushes
Tons of Coke Pushed Per Hour
Avg. Sampling Rate, dscfm*
Sample Volume:
dscf
dscmc
Avg. Flue Gas Temp, °F
O2 Cone., % by Volume
C02 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfmd
dscfm"
dscmm"
Isokinetic Sampling Ratio, %
A-I-429-1
09/21/98
458
21
33.3
0.363
166.098
4.703
120
20.3
0.2
3.3
75,215
64,724
1,833
99.7
A-I-429-2
09/22/98
422
21
35.4
0.219
92.605
2.622
136
20.3
0.2
3.1
52,375
44,174
1,251
88.4
A-I-429-3
09/23/98
435
21
34.4
0.333
145.053
4.107
135
20.3
0.2
2.9
60,131
50,842
1,440
116
Average
--
438
21
34.3
0.305
134.585
3.811
130
20.3
0.2
3.1
62,574
53,246
1,508
101
"Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
cDry standard cubic meters at 68°F (20°C) and 1 atm.
dActual cubic feet per minute at flue gas conditions.
'Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-28
-------
TABLE 2.17
PAH CONCENTRATIONS AND EMISSION RATES
BAGHOUSE INLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Naphthalene
Aig/dscm"
Mg/hr*
Ib/hr"
Ib/ton pushedd
2-Methyl naphthalene
Mg/dscm"
Mg/hr"
Ib/hr"
Ib/ton pushed11
Acenaphthylene
^g/dscma
^g/hH"
lb/hc
Ib/ton pushedd
Acenaphthene
^g/dscm'
^g/hr*
Ib/hf-
Ib/ton pushed"1
Fluorene
Aig/dscm"
/^g/hrb
lb/hi*
Ib/ton pushedd
Phenanthrene
/^g/dscm"
Aig/hr1"
Ib/hr*
Ib/ton pushed"1
Anthrancene
^g/dscm1
Mg/hr6
Ib/hr*
Ib/ton pushedd
Fluoranthene
^g/dscm*
Aig/hr41
Ib/hr1
Ib/ton pushedd
A-I-429-1
09/21/98
1128-1912
76.5
8.41E+06
18.5E-03
5.57E-04
16.2
1.78E+06
3.92E-03
11.8E-05
18.7
2.06E+06
4.54E-03
13.6E-05
3.19
35.1E+04
7.73E-04
23.2E-06
0.72
7.95E+04
1.75E-04
0.53E-05
34.0
3.74E+06
8.25E-03
24.8E-05
3.40
3.74E+05
8.25E-04
2.48E-05
10.6
11.7E+05
2.58E-03
7.74E-05
A-I-429-2
09/22/98
1018-1816
45.6
3.42E+06
7.55E-03
2.13E-04
9.14
0.686E+06
1.51E-03
4.28E-05
13.7
1.03E+06
2.27E-03
6.42E-05
1.64
12.3E+04
2.71E-04
7.67E-06
6.10
45.8E+04
10.1E-04
2.85E-05
20.2
1.51E+06
3.34E-03
9.45E-05
1.64
1.23E+05
2.71E-04
0.77E-05
6.86
5.15E+05
1.14E-03
3.21E-05
A-I-429-3
09/23/98
1019-1810
38.9
3.36E+06
7.40E-03
2.15E-04
9.98
0.862E+06
1.90E-03
5.53E-05
8.03
0.694E+06
1.53E-03
4.45-E05
1.53
13.2E+04
2.92E-04
8.50E-06
4.38
37.9E+04
8.35E-04
2.43E-05
16.1
1.39E+06
3.06E-03
8.90E-05
2.22
1.91E+05
4.22E-04
1.23E-05
6.09
5.26E+05
1.16E-03
3.37E-05
Average
-
-
53.7
5.06E+06
11.2E-03
3.28E-04
11.8
1.11E+06
2.44E-03
7.19E-05
13.5
1.26E+06
2.78E-03
8.16E-05
2.12
20.2E+04
4.46E-04
13.1E-06
3.74
30.5E+04
6.73E-04
1.94E-05
23.4
2.21E+06
4.88E-03
14.4E-05
2.42
2.30E+05
5.06E-04
1.49E-05
7.86
7.37E+05
1.62E-03
4.77E-05
2-29
-------
TABLE 2.17 (continued)
Run No.
Pyrene
Aig/dscma
Afg/hr11
Ib/hi*
Ib/ton pushed11
Benzo(a) Anthrancene
Aig/dscm"
Mg/hr"
Ib/hr*
Ib/ton pushedd
Chrysene
Aig/dscm1
Mg/hr"
Ib/hr"
Ib/ton pushed11
Benzo(b) Fluoranthene
Mg/dscma
Mg/hH1
lb/hr*
Ib/ton pushed1*
Benzo(k) Fluoranthene
/ug/dscm"
Mg/hr1'
Ib/hr"
Ib/ton pushed11
Benzo(e) Pyrene
^g/dscm"
Mg/hr"
Ib/hr1
Ib/ton pushedd
Benzo(a) Pyrene
fj.g/dscm'
A'g/hr11
Ib/hr*
Ib/ton pushed1*
Perylene
Ajg/dscm"
/ug/hr1"
Ib/hr"
Ib/ton pushedd
Indeno(l,2,3-cd) Pyrene
Mg/dscm'
A'g/hr1'
lb/hi*
Ib/ton pushed1*
A-I-429-1
7.02
7.72E+05
17.0E-04
5.11E-05
3.19
3.51E+05
7.73E-04
2.32E-05
5.53
60.8E+04
13.4E-04
4.02E-05
3.61
39.7E+04
8.76E-04
26.3E-06
1.96
21.5E+04
4.74E-04
14.2E-06
1.38
15.2E+04
3.35E-04
10.1E-06
1.34
14.7E+04
3.25E-04
9.75E-06
0.234
25.7E+03
5.67E-05
17.0E-07
2.34
25.7E+04
5.67E-04
17.0E-06
A-I-429-2
4.96
3.72E+05
8.20E-04
2.32E-05
2.67
2.00E+05
4.42E-04
1.25E-05
4.58
34.3E+04
7.57E-04
2.14E-05
1.98
14.9E+04
3.28E-04
9.27E-06
1.41
10.6E+04
2.33E-04
6.60E-06
0.992
7.44E+04
1.64E-04
4.64E-06
0.725
5.44E+04
I.20E-04
3.39E-06
0.110
8.01E+03
1.77E-05
4.99E-07
1.64
12.3E+04
2.71E-04
7.67E-06
A-I-429-3
4.38
3.79E+05
8.35E-04
2.43E-05
2.68
2.31E+05
5.10E-04
1.48E-05
4.38
37.9E+04
8.35E-04
2.43E-05
1.49
12.8E+04
2.83E-04
8.23E-06
0.876
7.57E+04
1.67E-04
4.86E-06
0.803
6.94E+04
1.53E-04
4.45E-06
0.438
3.79E+04
0.84E-04
2.43E-06
0.070
5.89E+03
1.30E-05
3.78E-07
0.949
8.20E+04
1.81E-04
5.26E-06
Average
5.45
5.07E+05
11.2E-04
3.28E-05
2.85
2.61E+05
5.75E-04
1.68E-05
4.83
44.3E+04
9.77E-04
2.86E-05
2.36
22.5E+04
4.96E-04
14.6E-06
1.41
13.2E+04
2.92E-04
8.56E-06
1.06
9.86E+04
2.17E-04
6.38E-06
0.834
7.98E+04
1.76E-04
5.19E-06
0.136
13.2E+03
2.91E-05
8.60E-07
1.64
15.4E+04
3.40E-04
9.98E-06
2-30
-------
TABLE 2.17 (concluded)
Run No.
Dibenz(a,h) Anthracene
Mg/dscm"
^g/hr1"
Ib/hr1
lb/ton pushedd
Benzo(g,h,i) Perylene
/^g/dscma
/^g/hr"
Ib/hr*
Ib/ton pushedd
A-I-429-1
0.532
58.5E+03
12.9E-05
3.87E-06
2.34
25.7E+04
5.67E-04
17.0E-06
A-I-429-2
0.419
31.5E+03
6.49E-05
1.96E-06
1.45
10.9E+04
2.40E-04
6.78E-06
A-I-429-3
0.239
20.6E+03
4.54E-05
1.32E-06
0.974
8.41E+04
1.85E-04
5.40E-06
Average
0.397
36.8E+06
8.12E-05
2.38E-06
1.59
15.0E+04
3.31E-04
9.73E-06
"Micrograms per dry standard cubic meter.
bMicrograms per hour.
'Pounds per hour.
dPounds per ton of coke pushed.
2-31
-------
2.3.2 Coke Oven Battery No. 5/6 Baghouse Outlet
The baghouse outlet was sampled simultaneously with the baghouse inlet. Table 2.18
summarizes the Method 429 sample times and flue gas parameters measured at the baghouse
outlet. The average sampling length of the three tests was 411 minutes. The average sampling
rate was 0.323 dscfm. Sampling volumes averaged 133.174 dscf or 3.771 dscm.
Flue gas temperatures averaged 123 °F, with an average stack gas composition of 0.2 %
CO2 and 20.4 % O2. Moisture content averaged 2.5 %. Flue gas volumetric flow rates averaged
62,193 acfm or 54,620 dscfm or 1,547 dscmm. The isokinetic sampling rate averaged 95.6 %.
Table 2.19 summarizes the PAH concentrations and emission rates for the baghouse
outlet. Naphthalene and phenathrene were the compounds found in the highest concentration of
the 19 compounds analyzed for, at 42.1 /zg/dscm and 9.95 yUg/dscm, respectively. All of the
other compounds were detected in lower concentrations than naphthalene and 2-methyl
naphthalene. Several of the compounds were non detectable.
2.3.3 Underfire Stack
The underfire or combustion stack was sampled over the course of two days. Sample
runs were 180 minutes in length. Four sample runs were conducted, of which three were during
coke oven charging and pushing operations. One run was conducted during non-charging and
pushing operations. Table 2.20 summarizes the CARS Method 429 sample times and flue gas
parameters measured at the underfire stack. The average sampling rate was 0.604 dscfm, with an
average sampling volume of 108.740 dscf or 3.079 dscm. Flue gas temperatures averaged
450 °F. Flue gas composition averaged 2.8 % CO2 and 14.4 %O2, with an average moisture
content of 14.9 %. Flue gas volumetric flow rates averaged 82,704 acfm or 40,655 dscfm or
1,151 dscmm. Isokinetic sampling rate averaged 95.1 %.
Table 2.21 summarizes the PAH concentrations and emission rates for the underfire
stack. Many of the target PAH analytes were detected in the analyzed samples with the
exception of perylene, indeno (1,2,3-cd), benzo(g,h,i) perylene, and dibenz(a,h) anthracene.
Naphthalene and acenaphthylene were present in the highest concentrations.
2.4 NON-PUSHING AND NON-CHARGING COKE OVEN BATTERY OPERATION
- UNDERFIRE STACK
On September 25,1998, one sample run was conducted at the underfire stack for
particulate, MCEM/metals and PAHs prior to the start of coke oven pushing and charging
operations. Sampling was conducted for comparative purposes to emissions measured during
coke oven pushing and charging operations. Currently there is no known emission data for the
non-pushing and non-charging condition. It was attempted to conduct sampling at the underfire
stack for the same length of time as during the other underfire stack sampling runs.
2-32
-------
TABLE 2.18
PAH EMISSIONS SAMPLING AND FLUE
GAS PARAMETERS - BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Coke Oven Pushes
Tons of Coke Pushed Per Hour
Avg. Sampling Rate, dscfnV
Sample Volume:
dscf"
dscnf
Avg. Flue Gas Temp, °F
02 Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfm"
dscfm"
dscmm"
Isokinetic Sampling Ratio, %
A-O-429-1
09/21/98
412
20
33.2
0.381
157.065
4.448
117
20.4
0.20
3.2
72,960
64,153
1,817
96.3
A-O-429-2
09/22/98
400
23
35.9
0.241
96.553
2.734
128
20.4
0.20
2.7
46,062
39,996
1,133
97.8
A-O-429-3
09/23/98
420
23
34.7
0.347
145.903
4.132
125
20.4
0.10
1.7
67,558
59,710
1,691
92.6
Average
-
411
22
34.6
0.323
133.174
3.771
123
20.4
0.20
2.5
62,193
54,620
1,547
95.6
"Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
cDry standard cubic meters at 68°F (20°C) and 1 atm.
•"Actual cubic feet per minute at flue gas conditions.
"Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-33
-------
TABLE 2.19
PAH CONCENTRATIONS AND EMISSION RATES
BAGHOUSE OUTLET
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Naphthalene
/^g/dscm"
Mg/hr11
Ib/hr"
Ib/ton pushed11
2-Methyl naphthalene
/ig/dscm"
Mg/hr"
lb/hi*
Ib/ton pushedd
Acenaphthylene
/^g/dscma
Mg/hr1'
Ib/hr"
Ib/ton pushedd
Acenaphthene
Aig/dscma
/ig/hr"
Ib/hr*
Ib/ton pushed*
Fluorene
//g/dscm"
Mg/hr'
Ib/hi*
Ib/ton pushed1
Phenanthrene
Aig/dscm"
Mg/hr1'
Ib/hr*
Ib/ton pushedd
Anthrancene
/jg/dscma
^g/hr"
Ib/hr*
Ib/ton pushedd
Fluoranthene
fj.gfdscm'
Aig/hr*
Ib/hi*
Ib/ton pushedd
A-O-429-1
09/21/98
1126-1911
65.1
7.10E+06
15.6E-03
4.71E-04
12.4
13.5E+05
2.97E-03
8.94E-05
11.2
12.3E+05
2.70E-03
8.13E-05
1.57
17.2E+04
3.78E-04
11.4E-06
4.72
5.15E+05
11.3E-04
3.42E-05
14.8
1.62E+06
3.56E-03
I0.7E-05
4.50
49.0E+04
10.8E-04
32.5E-06
4.50
49.0E+04
10.8E-04
32.5E-06
A-O-429-2
09/22/98
1028-1819
34.6
2.35E+06
5.19E-03
1.44E-04
8.77
5.96E+05
1.31E-03
3.66E-05
8.05
5.47E+05
1.21E-03
3.36E-05
0.914
6.21E+04
1.37E-04
3.81E-06
2.74
1.86E+05
4.11E-04
1.14E-05
16.5
1.12E+06
2.46E-03
6.86E-05
1.21
8.20E+04
1.81E-04
5.03E-06
1.21
82.0E+04
1.81E-04
5.03E-06
A-O-429-3
09/23/98
1020-1806
26.5
2.69E+06
5.94E-03
1.71E-04
8.71
8.83E+05
1.95E-03
5.61E-05
4.11
4.17E+05
0.92E-03
2.65E-05
0.847
8.59E+04
1.89E-04
5.46E-06
2.13
2.16E+05
4.76E-04
1.37E-05
6.50
0.662E+06
1.46E-03
4.21E-05
1.23
12.5E+04
2.76E-04
7.95E-06
1.23
12.5E+04
2.76E-04
7.95E-06
Average
-
-
42.1
4.05E+06
8.92E-03
2.62E-04
9.95
9.42E+05
2.08E-03
6.07E-05
7.80
7.30E+05
1.61E-03
4.71E-05
1.11
10.7E+04
2.35E-04
6.89E-06
3.20
3.06E+05
6.74E-04
1.98E-05
12.6
1.13E+06
2.50E-03
7.27E-05
2.31
23.2E+04
5.12E-04
15.2E-06
2.31
23.2E+04
5.12E-04
15.2E-06
2-34
-------
TABLE 2.19 (continued)
Run No.
Pyrene
Atg/dscma
Mg/hr*
Ib/hi*
Ib/ton pushed*
Benzo(a) Anthrancene
Atg/dscm'
A^g/hr"
Ib/hi"
Ib/ton pushedd
Chrysene
/^g/dscm"
Mg/hr11
Ib/hr0
Ib/ton pushed1*
Benzo(b) Fluoranthene
//g/dscma
jug/hr1"
Ib/hr*
Ib/ton pushedd
Benzo(k) Fluoranthene
^g/dscms
Mg/hr"
Ib/hr*
Ib/ton pushed11
Benzo(e) Pyrene
^g/dscm"
Mg/hr"
Ib/hr*
Ib/ton pushedd
Benzo(a) Pyrene
^g/dscm"
^g/hr"
Ib/hi*
Ib/ton pushed11
Perylene
^g/dscma
Mg/hr"
Ib/hr"
/^g/pushd
Indeno(l,2,3-cd) Pyrene
/^g/dscm1
Mg/hr"
Ib/hr'
Ib/ton pushedd
A-O-429-1
3.60
3.92E+05
8.64E-04
2.60E-05
0.07
7.11E+03
1.57E-05
4.72E-07
0.166
18.1E+03
4.00E-05
1.20E-06
0.045
4,901
1.08E-05
3.25E-07
0.045
4,901
10.8E-06
3.25E-07
0.029
3,186
7.02E-06
2.11E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
A-CM29-2
2.96
2.01E+05
4.44E-04
1.24E-05
0.09
5.97E+03
1.32E-05
3.66E-07
0.234
15.9E+03
3.51E-05
0.98E-06
0.066
4,474
0.99E-05
2.75E-07
0.059
3,977
8.77E-06
2.44E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
A-O-429-3
1.55
1.57E+05
3.46E-04
l.OOE-05
0.06
5.89E+03
1.30E-05
3.74E-07
0.167
I6.9E+03
3.74E-05
1.08E-06
0.051
5,156
1.14E-05
3.27E-07
0.034
3,438
7.58E-06
2.18E-07
0.027
2,701
5.95E-06
1.72E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
2.70
2.50E+05
5.52E-04
1.61E-05
0.07
6.32E+03
1.39E-05
4.04E-07
0.189
17.0E+03
3.75E-05
1.09E-06
0.054
4,844
1.07E-05
3.09E-07
0.046
4,105
9.05E-06
2.63E-07
0.019
1,962
4.33E-06
1.28E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-35
-------
TABLE 2.19 (concluded)
Run No.
Dibenz(a,h) Anthracene
^g/dscm"
Mg/hrb
\b/hf
A
-------
TABLE 2.20
PAH EMISSIONS SAMPLING AND FLUE GAS
PARAMETERS - UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Tons of Coal Charged Per
Hour
Avg. Sampling Rate, dscfrn'
Sample Volume:
dscf1
dscrn0
Avg. Flue Gas Temp, °F
O2 Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow
Rate:
acfind
dscfrn'
dscmm'
Isokinetic Sampling Ratio, %
A-U-429-1
09/24/98
180
50.6
0.579
104.145
2.949
435
14.7
2.7
16.3
85,825
42,176
1,194
87.6
A-U-429-2
09/24/98
180
52.9
0.616
110.807
3.138
454
15.0
3.0
14.8
80,320
39,328
1,114
100
A-U-429-4
09/25/98
180
37.4
0.618
111.269
3.151
460
13.5
2.8
13.5
81,996
40,461
1,146
97.6
Average
~
180
47.0
0.604
108.740
3.079
450
14.4
2.8
14.9
82,704
40,655
1,151
95.1
•Dry standard cubic feet per minute at 68°F (20°C) and 1 arm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
cDry standard cubic meters at 68°F (20°C) and 1 atm.
dActual cubic feet per minute at flue gas conditions.
"Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-37
-------
TABLE 2.21
PAH CONCENTRATIONS AND EMISSION RATES
UNDERFIRE STACK
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Naphthalene
^g/dscm"
Mg/hr*
Ib/hr*
Ib/ton charged1*
2-Methyl naphthalene
^g/dscm"
A^g/hr*
Ib/hr*
Ib/ton charged"1
Acenaphthylene
,ug/dscma
Mg/hr11
Ib/hr"
Ib/ton charged1*
Acenaphthene
/^g/dscm"
//g/hr"
Ib/hi*
Ib/ton chargedd
Fluorene
^g/dscm"
^g/hr"
Ib/hi*
Ib/ton charged11
Phenanthrene
fig/dscm*
Mg/hr1
Ib/hr"
Ib/ton chargedd
Anthrancene
//g/dscma
^g/hi-"
lb/hr°
Ib/ton chargedd
Fluoranthene
Aig/dscm1
/^g/hr"
Ib/hr*
Ib/ton charged11
A-U-429-1
09/24/98
1025-1345
33.8
2.42E+06
5.34E-03
1.05E-04
0.970
69.9E+03
1.54E-04
3.04E-06
5.43
3.89E+05
8.57E-04
1.69E-05
0.09
6.80E+03
1.50E-05
2.96E-07
0.315
22.6E+03
4.98E-05
9.84E-07
3.72
26.7E+04
5.88E-04
1.16E-05
0.105
7.53E+03
1.66E-05
3.28E-07
1.83
13.1E+04
2.89E-04
5.71E-06
A-U-429-2
09/24/98
1443-1812
41.3
2.76E+06
6.09E-03
1.15E-04
0.725
48.4E+03
1.07E--04
2.02E-06
21.7
14.5E+05
31.9E-04
6.04E-05
0.08
5.11E+03
1.13E-05
2.13E-07
0.220
14.7E+03
3.24E-05
6.13E-07
6.37
42.5E+04
9.38E-04
1.77E-05
0.147
9.80E+03
2.16E-05
4.09E-07
3.82
25.6E+04
5.63E-04
10.7E-06
A-U-429-4
09/25/98
1110-1427
31.3
2.15E+06
4.75E-03
1.27E-04
1.39
95.5E+03
2.10E-04
5.63E-06
ND
ND
ND
ND
0.08
5.24E+03
1.15E-05
3.09E-07
0.413
28.4E+03
6.25E-05
16.7E-07
0.564
3.87E+04
0.85E-04
0.23E-05
0.089
6.11E+03
1.35E-05
3.60E-07
2.25
I5.5E+04
3.42E-04
9.13E-06
Average
-
-
35.5
2.44E+06
5.39E-03
1.16E-04
1.03
71.3E+03
1.57E-04
3.56E-06
13.5
9.18E+05
20.2E-04
2.58E-05
0.08
5.72E+03
1.26E-05
2.73E-07
0.316
21.9E+03
4.82E-05
I0.9E-07
3.55
24.4E+04
5.37E-04
1.05E-05
0.114
7.81E+03
1.72E-05
3.66E-07
2.64
18.1E+04
3.98E-04
8.50E-06
2-38
-------
TABLE 2.21 (continued)
Run No.
Pyrene
,ug/dscma
Mg/hr"
Ib/hr1
Ib/ton charged1*
Benzo(a) Anthrancene
//g/dscm3
/ug/hi
Ib/hr5
Ib/ton charged1*
Chrysene
/ug/dscm°
Mg/hr"
Ib/hr*
Ib/ton charged11
Benzo(b) Fluoranthene
yug/dscm"
Mg/hr"
Ib/hr*
Ib/ton charged1*
Benzo(k) Fluoranthene
/ug/dscm"
/ug/hr11
Ib/hr1
Ib/ton charged1*
Benzo(e) Pyrene
ng/dscm*
yug/hr1"
Ib/hr"
Ib/ton charged**
Benzo(a) Pyrene
/ug/dscm"
Aig/hr1"
lb/hr°
Ib/ton charged1*
Perylene
/ug/dscm"
/ug/hr1"
Ib/hr*
Ib/ton charged1*
Indeno(l,2,3-cd) Pyrene
Aig/dscm"
/ug/hr1"
Ib/hr1
Ib/ton charged1*
A-U-429-1
0.916
0.66E+05
1.45E-04
2.86E-06
5.43E-02
3.89E+03
8.57E-06
1.69E-07
0.129
9.23E+03
2.04E-05
4.02E-07
0.09
6.56E+03
1.45E-05
2.86E-07
ND
ND
ND
ND
0.10
7.05E+03
1.55E-05
3.07E-07
0.08
5.59E+03
12.3E-06
2.43E-07
ND
ND
ND
ND
ND
ND
ND
ND
A-U-429-2
6.69
4.47E+05
9.86E-04
18.7E-06
3.19E-02
2.13E+03
4.69E-06
0.89E-07
0.147
9.80E+03
2.16E-05
4.09E-07
0.13
8.94E+03
1.97E-05
3.73E-07
4.14E-02
2.77E+03
6.10E-06
1.15E-07
0.45
29.8E+03
6.57E-05
12.4E-07
0.07
4.47E+03
9.86E-06
1.87E-07
ND
ND
ND
ND
ND
ND
ND
ND
A-U-429-4
1.46
l.OOE+05
2.21E-04
5.92E-06
4.76E-02
3.27E+03
7.22E-06
1.93E-07
0.165
11.3E+03
2.50E-05
6.69E-07
0.08
5.67E+03
1.25E-05
3.34E-07
3.49E-02
2.40E+03
5.29E-06
1.42E-07
0.10
6.55E+03
1.44E-05
3.86E-07
0.05
3.49E+03
7.70E-06
2.06E-07
ND
ND
ND
ND
ND
ND
ND
ND
Average
3.02
2.04E+05
4.51E-04
9.14E-06
4.46E-02
3.10E+03
6.83E-06
1.50E-07
0.147
10.1E+03
2.23E-05
4.93E-07
0.10
7.06E+03
1.56E-05
3.31E-07
2.54E-02
1.72E+03
3.80E-06
0.86E-07
0.21
14.5E+03
3.19E-05
6.45E-07
0.07
4.51E+03
9.96E-06
2.12E-07
ND
ND
ND
ND
ND
ND
ND
ND
2-39
-------
TABLE 2.21 (concluded)
Run No.
Dibenz(a,h) Anthracene
^g/dscma
A^g/hr5
Ib/hr*
Ib/ton chargedd
Benzo(g,h,i) Perylene
Aig/dscma
Mg/hr1'
Ib/hr*
Ib/ton chargedd
A-U-429-1
ND
ND
ND
ND
ND
ND
ND
ND
A-U-429-2
ND
ND
ND
ND
ND
ND
ND
ND
A-U-429-4
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
aMicrograms per dry standard cubic meter.
bMicrograms per hour.
'Pounds per hour.
dPounds per ton of coal charged.
ND - non detected, counted as "zero".
2-40
-------
Table 2.22 summarizes the EPA Method 315 and CARS Method 429 flue gas parameters
for the sample runs. The tests were run for a minimum of 171 minutes for both sampling trains.
One sampling port was traversed with each sample train to maximize length of time for sampling
prior to the start of coke oven pushing and charging for the day.
Table 2.23 summarizes the results of the particulate matter/MCEM concentrations and
emission rates for the EPA Method 315 sampling train. Particulate matter concentrations were
0.020 gr/dscf or 2.86E-06 Ib/dscf or 4.59E+04 /^g/dscm. Emission rate of particulate matter was
7.20 Ib/hr or 3.28E+09 yug/hr. MCEM concentrations averaged 0.001 gr/dscf or 0.14E-06 Ib/dscf
or 0.23E+04 //g/dscm. Emission rate of MCEM was 0.36 Ib/hr or 0.17E+09 /ug/hr.
Table 2.24 summarizes the metals concentrations and emission rates from the EPA
Method 315 particulate/MCEM analysis. Antimony, cobalt, mercury, and silver were not
detected in this sample. Zinc, phosphorus, and chromium were present in the greatest quantities.
Table 2.25 summarizes the PAH concentrations and emission rates for the CARB Method
429 sample run. The majority of the compounds were detected in the sample, with naphthalene,
acenaphthylene and penanthrene in the greatest quantity. Seven of the target analytes of 19 total
were not detected in the sample.
2-41
-------
TABLE 2.22
PARTICULATE MATTER/MCEM/METALS AND PAH EMISSIONS
SAMPLING AND FLUE GAS PARAMETERS - UNDERFIRE STACK
NON-PUSHING AND NON-CHARGING OPERATION
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Total Sampling Time, minutes
Avg. Sampling Rate, dscfm"
Sample Volume:
dscf1
dscmc
Avg. Flue Gas Temp, °F
O2 Cone., % by Volume
CO2 Cone., % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfmd
dscfm*
dscmm*
Isokinetic Sampling Rates, %
A-U-315-3
09/25/98
171.4
0.642
110.010
3.115
480
13.2
2.7
14.4
87,884
42,039
1,190
97.5
A-U-429-3
09/25/98
172.5
0.545
93.963
2.661
465
13.2
2.7
14.0
72,571
35,427
1,003
98.2
"Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
bDry standard cubic feet at 68°F (20°C) and 1 atm.
cDry standard cubic meters at 68°F (20°C) and 1 atm.
d Actual feet per minute at flue gas conditions.
'Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-42
-------
TABLE 2.23
PARTICULATE MATTER/MCEM CONCENTRATIONS AND EMISSION RATES
UNDERFIRE STACK
NON-PUSHING AND NON-CHARGING OPERATION
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Concentration:
gr/dscf
Ib/dscf5
Aig/dscmc
Emission Rate:
Ib/hr*
Mg/hi*
Filterable Particulate Matter
MCEM
A-U-315-3
09/25/98
0738-1029
0.020
2.86E-06
4.59E+04
7.20
3.28E+09
0.001
0.14E-06
0.23E+04
0.36
0.17E+09
"Grains per dry standard cubic feet at 68°F (20°C) and 1 atm.
•"Pounds per dry standard cubic foot at 68°F(20°C) and 1 atm.
'Micrograms per dry standard cubic meter at 68°F (20°C) and 1 atm.
dPounds per hour.
'Micrograms per hour.
2-43
-------
TABLE 2.24
MULTIPLE METALS CONCENTRATIONS AND EMISSION RATES
UNDERFIRE STACK
NON-PUSHING AND NON-CHARGING OPERATION
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Antimony
/^g/dscma
^g/hr"
lb/hr°
Arsenic
Aig/dscm"
^g/hr"
Ib/hi*
Barium
Mg/dscma
Aig/hrb
lb/hr°
Beryllium
^ig/dscma
yug/hr"
Ib/hr"
Cadmium
A
-------
TABLE 2.25
PAH CONCENTRATIONS AND EMISSION RATESUNDERFIRE STACK
NON-PUSHING AND NON-CHARGING OPERATION
ABC COKE, BIRMINGHAM, ALABAMA
Run No.
Date
Clock Time, 24 hr Clock
Naphthalene
^g/dscm"
Mg/hrb
Ib/hr*
2-Methylnaphthalene
^g/dscma
^g/hr11
Ib/hr*
Acenaphthylene
/ig/dscm1
^g/hr11
Ib/hi*
Acenaphthene
^g/dscm"
^g/hr'
Ib/hr"
Fluorene
//g/dscma
Aig/hr11
Ib/hr*
Phenanthrene
/^g/dscma
Aig/hr6
Ib/hr*
Anthrancene
^g/dscma
^g/hr11
Ib/hr"
Fluoranthene
A
-------
3.0 PROCESS AND CONTROL EQUIPMENT OPERATION
3.1 INTRODUCTION
ABC Coke in Birmingham, Alabama produces foundry coke from three coke oven
batteries. Battery No. 1A is a 5-meter Wilputte battery with 78 ovens built in 1967. Batteries
No. 5 and No. 6 are 4-meter Koppers-Becker batteries with 25 and 29 ovens, respectively.
Battery No. 5 was built in 1941, and Battery No. 6 was built in 1951. Both use coke oven gas
(COG) to fuel a gun flue underfiring system. The batteries are end-to-end and are operated as one
battery (Battery No. 5/6). They share a baghouse and combustion stack and are served by a
common rail.
Batteries No. 1A and No. 5/6 each capture pushing emissions with a moveable Trav-L-
Vent Flakt hood and fixed duct capture system vented to a baghouse. ABC Coke was selected
for testing from the foundry coke producers because the hoods used to capture pushing emissions
have good capture efficiency and the pushing emission control system is representative of the
industry. Battery No. 5/6 was selected because it reportedly has better capture efficiency than
Battery No. 1 A, and when the site was selected for testing, repairs (which could interfere with
testing) were anticipated on Battery No. 1 A.
3.2 PROCESS DESCRIPTION
3.2.1 Pushing
The pushing sequence used at ABC Coke is the "Koppers" system, in which ovens 1,11,
21... are pushed, followed by ovens 3, 13, 23.... The even-numbered ovens, 2,22, 32...through 8,
18, 28...are pushed after the odd-numbered ovens. Since there are no zeros in any of the oven
numbers, the battery's 54 ovens number from 1 to 59, with oven No. 1 being farthest from the
quench tower. At the time of testing ovens No. 51 - No. 54 were empty as a result of a through-
wall being replaced between ovens No. 52 and No. 53.
An average of 15.33 tons of coal is charged into each oven, and an average of 12.26 tons
of coke is produced per coking cycle. Two crews work to push and charge ovens from 10:00
a.m. to 6:00 p.m. and from 10:00 p.m. to 6:00 a.m., 7 days a week.
Pushing emissions are captured by a moveable hood attached to a fixed duct system. The
hood is connected to a tripper car which moves under the belt that seals the top of the duct. The
hood lines up with the hooded coke guide and covers the quench car during pushing. When the
dampers are open, the duct is open to the baghouse where a fan evacuates emissions from the
hood.
3-1
-------
Typically two ovens in advance of the oven being pushed are dampered off the collecting
main. The standpipe cap and mini-standpipe cap are then opened to relieve pressure and vent
coke oven gas. The coke oven gas is lighted if it does not self ignite. Just prior to pushing, the
oven doors are removed, the coke guide is positioned, the capture hood is aligned, and the
exhaust fan on the baghouse is activated. The pushing ram pushes the coke from the push side of
the battery out the coke side into a traditional quench car which slowly moves along the rail
during the push to catch the falling coke. The time from the removal of the doors to the
completion of the push is typically two minutes; however, on occasions when the quench car is
not immediately available, this period is longer. The quench car remains stationary under the
hood for about 30 seconds, then travels to the quench tower without the hood. The fan on the
baghouse is placed on idle between pushes. A push typically occurs every 15 to 20 minutes.
After an oven is pushed, the door jambs are cleaned on both the pusher and coke sides, and the
doors are replaced. The ovens are charged in the order in which they were pushed. Typical
coking tune (from coal charge to coke push) is 24 hours.
Pushing emissions captured by the hood travel through the fixed duct to a 4-compartment
pulse jet baghouse. The baghouse was installed in 1986 and has a design volumetric flow rate of
130,000 acfm. Each compartment houses 352 singed polyester bags. Pressure drop (delta P) is
measured across each compartment and across the baghouse and equals (-8) inches of water. Air
temperature in the baghouse does not exceed 275 °F. The air-to-cloth ratio is 6.46 acfm/ft2.
3.2.2 Underfiring
The combustion, or underfiring, system regulates COG, air, and waste gas. Prior to
being used for combustion, raw COG is processed in a by-product recovery plant where tar and
naphthalene are removed and ammonia is recovered as ammonium sulfate. COG is not
desulfurized prior to being used for underfiring.
Battery No. 5/6 is equipped with a gun flue combustion system. Draft created by the
battery stack is drawn into the battery, where it is warmed and introduced at the base of the
alternating flues. A gas nozzle at the flue base injects fuel gas which combusts when it contacts
the introduced air. Waste gas is formed as a product of combustion and flows downward in
every other pair of heating flues through the regenerators and out the battery stack. Gas flow is
automatically reversed between adjacent flues every 20 minutes to promote even heating and
prevent damage to the brickwork. Once stack draft is set, individual oven drafts can be manually
adjusted at the air-intake box as needed. The average flue temperature is 2,080 °F.
Several factors can affect emissions from the combustion stack, including incomplete
combustion in the flues or cracks in the brickwork between an oven chamber and flue.
Incomplete combustion is typically the result of excess gas and/or insufficient air in the system.
Excess emissions from damaged brickwork or overly decarbonized ovens is most notable just
after an oven is charged because gases from combusted coal dust are forced through cracks
during charging.
ABC Coke practices periodic silica dusting - the spraying of a silica-containing dust
inside an oven before charging it with coal. The dust fuses to the silica brick which lines the
3-2
-------
oven, sealing small cracks. In addition, fuel gas nozzles and piping are cleaned regularly.
Repairs to brickwork, jambs, through-walls and end flues are conducted as needed.
3.3 PROCESS AND CONTROL DEVICE MONITORING
3.3.1 Pushing
Several parameters were monitored during each test run. Process parameters monitored
included the identification of each oven being pushed and the total quantity of coke pushed
during each run. Approximately 15.06 tons of coal was charged to each oven after pushing.
Control parameters monitored included: percentage fan damper was open, inlet pressure, duct
velocity, fan amps, change in pressure (delta P) for each compartment, and delta P over the
entire baghouse. The chart recorder for change in pressure over the baghouse was not operating
during Run No. 1. Fan amp readings were also unavailable at the very start of testing.
Approximately 15.06 tons of coke were charged to each oven. Coking time for all ovens
was approximately 24 hours. The following summarizes readings taken when the fan damper
was 100% open: inlet pressure ranged from 10 to 22 inches of water, duct velocity ranged from
48 to 72, pressure drop over the entire baghouse ranged from 6.75 to 8 inches of water, fan amps
ranged from 31 to 48. Control parameters recorded during testing are presented on Tables 3.la
through 3. Ic.
Visual observations of pushes were made during all three test runs to assess opacity and
capture efficiency of the hood and to note any differences in uncontrolled emissions. See field
observations in Appendix A on pages labeled "Pushing Parameters - Capture Observations:
Alabama By-Product Coke, Birmingham, AL". Pushing opacity was relatively low during most
pushes. However, after 7 (out of 64 total) monitored pushes, thick, dark emissions were
observed indicative of undercoking, at least in spots. One of these pushes involved an oven
adjacent to an oven that was cold due to through-wall repair. Very good capture efficiency of the
hood was observed. Most fugitive emissions escaped the capture system via two gaps - one
between the coke guide and the hood and one between the coke guide and the battery.
3.3.2 Underfilling
Control parameters monitored during combustion stack testing included: opacity, stack
draft, fuel gas flow rate, fuel gas pressure and waste heat temperature. All of these parameters
except opacity are continuously monitored at the plant. Opacity from the stack is read manually
at least once a month for an hour by a certified opacity reader. Process parameters monitored
during testing included the number of each oven charged and the approximate quantities of coal
charged and coke produced during each run. Maintenance was performed during the week of
testing which may have affected stack opacity. Maintenance included oven dusting, through-
wall replacement, gun flue repair, nozzle punching and swabbing of gas piping.
3-3
-------
TABLE 3.1A
PUSHING CONTROL DEVICE PARAMETERS: TEST RUN NO. 1,9/21/98
Time
11:34
12:04
12:16
12:31
12:42
12:51
1:11
1:43
2:09
2:19
2:36
3:36
3:50
4:04
4:19
4:27
4:42
4:59
5:15
5:34
5:45
6:06
6:23
6:43
6:58
Oven
No.
U
U
U
U
U
U
U
31
41
3
13
23
33
5
15
25
35
45
55
7
17
27
37
47
57
Fan
Damper
(% open)
—
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Inlet
Pressure
(in. of
water)
22
18
19
19
19
19
19
14
18
19
18
16
20
20
18
20
14
14
12
20
18
18
16
14
12
Duct
Velocity
—
65
63
64
60
57
58
69
54
58
62
56
54
54
62
58
66
66
64
54
58
62
68
72
72
Delta P
for
Entire
Bag-
house
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
Pressure Drop (Delta P) for
Compartments 1 - 4 (inches of H2O)
1
—
—
—
4.5
4.5
4.5
4.75
4.5
5
4.5
4.25
4.25
4
4.25
4.25
5.5
4.5
5.5
4.5
5
4.5
4.5
5.5
5.5
4.5
2
—
—
—
5
5
5
5
5
5.5
5
5
4.25
4.25
4.5
5
6
5
6
5
5.5
5
5
6
6
5
3
—
—
—
4.75
4.75
4.75
4.75
4.75
5
4.5
4.25
4
4.25
4
4.5
6
5
5.5
4.5
5
4.5
5
5.5
5.5
5
4
—
—
—
4.5
4.5
4.5
4.5
5
5
5
5
4
4.25
4
4.5
6
4.25
5
5
5
4.5
4.5
5.5
5.5
5
Fan
Amps
—
—
—
—
—
—
—
—
—
48
46
31
48
46
48
46
48
40
45
46
48
48
46
46
48
U = unknown; from approximately 11:50 A.M. to 1:14 P.M. there were no pushes due to the derailment of the door
luting machine on the push side of the battery.
3-4
-------
TABLE 3.1B
PUSHING CONTROL DEVICE PARAMETERS: TEST RUN NO. 2,9/22/98
Time
11:21
11:50
12:39
12:41
12:52
1:05
1:07
2:09
2:19
2:35
2:50
3:06
3:33
3:49
4:00
4:36
4:50
5:02
5:35
6:06
6:14
Oven
No.
28
38
58
58
1
11
21
31
41
3
13
23
33
5
15
25
35
45
55
17
27
Fan
Damper
(% open)
4
100
60
50
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Inlet
Pressure
(in. of
water)
0
14
16
8
20
18
16
14
14
22
20
18
14
20
18
16
14
14
10
18
19
Duct
Velocity
2
62
42
22
54
54
52
56
56
48
48
50
60
52
50
52
62
72
60
60
58
Delta P
for
Entire
Bag-
house
0
7
5
3.8
7
7
8
8
8
7
7
7
7.5
7
7.5
7.75
7
7.25
8
7
7.25
Pressure Drop (Delta P) for
Compartments 1 - 4 (inches of H20)
1
1
4.5
4
2
5
4.5
5
5
5.5
7
5
7
5.25
4.75
5.25
5.5
5
5
5.5
4.5
4.75
2
1
5
4.5
2
5
5
5
5
6
5
5.75
5
5.5
5
5.75
6
5.5
5.5
5.75
4.75
5
3
0
4.5
4.5
2
5
4.75
5.75
4.75
6
5.5
5.5
5.75
5
4.5
5.5
5.5
5.25
5.25
5
4.5
5
4
0
4.5
4.5
1.8
5
4.5
5.5
4.75
6
5.75
5.5
5.5
5.25
4.5
5.5
5.5
5.5
5.5
5
4.75
5
Fan
Amps
20
48
45
20
46
48
38
40
43
45
46
45
40
38
46
38
45
45
38
48
46
3-5
-------
TABLE 3.1C
PUSHING CONTROL DEVICE PARAMETERS: TEST RUN NO. 3,9/23/98
Time
10:30
10:54
11:21
11:40
11:57
12:14
12:30
12:45
1:20
1:59
2:12
2:39
2:59
3:12
3:26
3:41
4:09
4:24
4:41
5:01
5:13
5:25
5:32
Oven
No.
36
56
8
18
28
38
58
1
11
21
31
41
3
13
23
33
5
15
25
35
45
55
7
Fan
Damper
(% open)
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Inlet
Pressure
(in. of
water)
16
10
20
20
16
14
12
21
20
16
16
16
22
20
18
16
22
20
18
16
12
12
12
Duct
Velocity
66
50
52
54
56
62
56
50
51
80
60
62
52
58
60
64
56
58
62
66
64
68
70
Delta P
for
Entire
Bag-
house
7
8
7.75
8
8
7
8
7
7
7.75
7.75
7.5
7
7
7
7
7
7
6.75
7
7.75
7
7.75
Pressure Drop (Delta P) for
Compartments 1-4 (inches of H2O)
1
4.25
5
4.5
6
5.5
4.75
5
4.25
5.25
5
5
5.5
5
5
5
4.5
4.75
4.75
4.25
4.5
5.5
4.5
5
2
4.5
5
4.75
6.5
6
5
5.75
5
5.75
5.25
5.5
5
5.5
5.5
5.5
5
5.25
5.5
4.5
5
5.75
5
5.25
3
4.25
5
4.75
6
6
4.5
5.5
4.25
5.75
5.5
5.25
6
5.5
5.25
5.25
4.75
5
5.25
4.5
5
5.5
4.5
5
4
4.25
4.5
4.5
6.25
6
5
5.75
4.25
6
5.5
5.5
6
5.5
5.5
5.5
5
5.25
5.5
4.5
5
5.5
4.75
5
Fan
Amps
50
38
46
46
46
48
46
48
45
48
48
46
46
46
46
48
45
46
48
46
41
48
48
3-6
-------
Three 3-hour test runs (Runs No. 1,2, & 4) were conducted while ovens were being
pushed and charged. An additional run (Run No. 3) was conducted before pushing operations
began for the day, while all ovens in operation were full and coking. During each run, control
parameter values were recorded during each push, or if push times were unknown, approximately
every 10 to 15 minutes; these values are presented in Tables 3.2a through 3.2d.
For all four test runs, stack draft ranged from 24 to 25 millimeters of water, and the waste
heat temperature ranged from 560 to 650°F; underfire gas pressure ranged from 82 to 91
-millimeters of water. The underfire gas flow rate was recorded during Runs No. 2 and No. 4, and
ranged from 78,100 to 99,100 kscfh (1,000 standard cubic feet per hour). The amount of dry coal
charged per oven was approximately 15.33 tons (coal charge is not weighed). The approximate
amount of coke produced per oven was 12.26 tons. A total of 134.86 tons of coke was produced
from the ovens charged during Run No. 1,159.38 tons during Run No. 2, and 147.12 tons during
Run No. 4 (no ovens were pushed during Run No. 3), for a total of 441.36 tons of coke produced
during all four test runs.
Stack opacity during testing ranged from 0 to 30%, with the majority of readings ranging
from 0-5%. A summary of opacity readings for all 4 test runs is presented in Table 3.3.
The actual opacity readings recorded by individual observers using EPA Method 9 are shown in
Appendix A on pages labeled Visible Emissions Observation Report.
3-7
-------
TABLE 3.2A
COMBUSTION STACK PARAMETERS TEST RUN NO. 1, 9/24/98
Time
10:20
10:30
10:45
11:00
11:15
11:25
11:45
12:05
12:15
12:35
12:45
01:05
01:15
01:30
01:45
Oven
6
—
—
16
26
36
—
18
—
—
—
58
1
—
—
Underfire Gas Flow Rate
(kscfh)
Battery #5
—
—
—
—
—
—
—
' —
—
—
—
—
—
—
—
Battery #6
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
Underfire Gas Pressure
(mm H20)
Battery #5
57
60
60
64
60
62
61
65
58
64
61
60
59
56
60
Battery #6
78
79
76
57
56
56
56
57
57
58
56
58
79
76
75
Stack Draft
(mm H2O)
25
25
25
25
25
25
24
25
25
25
24
25
25
25
25
Waste Heat
Battery #5
620
630
610
640
600
620
610
650
580
640
610
600
600
630
610
remperature
F)
Battery #6
560
580
560
570
560
560
560
570
570
580
560
580
570
580
560
TABLE 3.2B
COMBUSTION STACK PARAMETERS: TEST RUN NO. 2,9/24/98
Time
2:45
3:00
3:15
3:30
3:54
4:09
4:27
4:37
5:03
5:19
5:43
5:45
5:59
Oven Pushed
31
41
3
13
23
33
5
15
25
35
—
45
55
Underfire Gas Flow Rate
(kscfh)
Battery #5
94,000
94,100
94,700
95,000
88,700
86,900
87,700
94,000
94,600
89,100
93,400
—
93,400
Battery #6
91,600
91,700
90,600
84,400
91,600
94,600
94,900
87,100
92,100
95,000
84,500
—
78,800
Underfire Gas Pressure
(mm H2O)
Battery #5
57
60
60
64
60
62
61
65
58
64
—
60
Batterv #6
78
79
76
57
56
56
56
57
57
58
—
58
Stack Draft
(mm H2O)
25
25
25
25
25
25
24
25
25
25
—
25
Waste Heat Temperature
(°F)
Batterv #5
620
630
610
640
600
620
610
650
580
640
—
600
JJattery #6
560
580
560
570
560
560
560
570
570
580
~
580
3-8
-------
TABLE 3.2C
COMBUSTION STACK PARAMETERS: TEST RUN NO. 3,9/25/98
(NO PUSHING OR CHARGING)
Time
7:35
7:45
8:05
8:15
8:35
8:45
9:00
9:15
9:30
9:45
10:00
10:15
10:30
Underfire Gas Flow Rate
(kscfh)
Battery #5
—
—
—
—
—
—
—
—
—
—
—
—
—
Battery #6
—
—
—
—
—
—
—
—
—
—
—
—
—
Underfire Gas Pressure
(mm H2O)
Battery #5
61
60
60
69
63
60
61
63
63
62
61
66
63
Battery #6
76
78
65
78
77
77
78
78
76
80
78
79
77
Stack Draft
(mm H2O)
25
25
25
25
25
25
25
25
25
25
25
25
25
Waste Heat Temperature
(°F)
Battery #5
640
600
650
600
640
610
640
600
630
610
640
600
630
Battery #6
590
570
580
570
590
570
580
570
590
570
570
570
580
TABLE 3.2D
COMBUSTION STACK PARAMETERS: TEST RUN NO. 4,9/25/98
Time
11:22
11:30
11:40
12:00
12:20
12:40
1:00
1:20
1:40
2:00
2:10
2:30
Oven
Pushed
26
36
56
8
18
28
38
—
11
21
—
31
Underfire Gas Flow Rate
(kscfh)
Battery #5
—
—
—
90,900
94,100
81,200
99,000
97,700
99,100
98,900
90,300
95,100
Battery #6
—
—
—
78,100
94,100
90,300
85,800
84,500
79,900
84,300
94,800
88,800
Underfire Gas Pressure
(mm H2O)
Battery #5
60
64
73
70
63
65
71
62
62
68
64
62
Battery #6
80
76
78
87
69
84
91
85
80
87
82
79
Stack Draft
(mm H2O)
25
25
25
25
25
25
25
25
25
25
25
25
Waste Heat Temperature
(°F)
Battery #5
620
640
600
650
620
600
650
610
600
650
600
640
Battery #6
570
590
580
580
580
590
570
570
590
570
570
590
3-9
-------
TABLE 3.3
COMBUSTION STACK OPACITY READINGS
Test Run
#1 9/24/98
#2 9/24/98
#3 9/25/98
#4 9/25/98
Number of Opacity Readings:
0%
609
443
447
519
5%
87
117
144
83
10%
48
37
33
0
15%
13
0
20
0
20%
15
0
13
0
25%
0
0
5
0
30%
0
0
5
0
Total
772
597
667
602
3-10
-------
4.0 SAMPLING LOCATIONS
Source sampling was be conducted at Coke Oven Battery No. 5/6 at the ABC Coke
facility in Birmingham, Alabama. Prior to sampling all locations were checked for the presence
of non-parallel or cyclonic flow as outlined in Section 2.4 of EPA Method 1. At all three
sampling locations, the average rotation angle for a null reading was well below the EPA Method
1 criteria of 20°. Therefore, sampling at each location was conducted without site modifications.
Brief descriptions and schematic diagrams of the sampling locations are presented below.
4.1 COKE OVEN BATTERY NO. 5/6
4.1.1 Baghouse Inlet
The baghouse inlet test location was be located in a 96-1/2 inch wide x 48-1/2 inch deep
rectangular horizontal duct which leads from the coke oven pushing operation to the inlet of the
baghouse. This location was upstream of the dilution air damper. This duct had an equivalent
diameter of 64.6 inches. Two sets of five sample ports were positioned as shown in Figure 4.1.
One set was used for the EPA Method 315 sampling and the other set was used for the CARB
Method 429 sampling. The EPA Method 315 sample ports were located 300 inches (4.6
equivalent duct diameters) downstream of the nearest flow disturbance (45 degree elbow) and
70.5 inches (1.1 equivalent duct diameters) upstream of the nearest flow disturbance (45 degree
elbow). The CARB Method 429 sample ports were located 324 inches (5.0 equivalent duct
diameters) downstream and 46.5 inches (0.7 equivalent duct diameter) upstream of the same flow
disturbances. For isokinetic testing, EPA Method 1 required 25 sample traverse points using a
5x5 traverse-point matrix. The results of the EPA Method 1 calculations and the locations of the
sample traverse points are showed in Figures 4.2 and 4.3, respectively.
4.1.2 Baghouse Outlet
The baghouse outlet sampling location was located in a 89-3/8 inch inside diameter (ID)
round vertical stack which was downstream of the baghouse. Four sampling ports were located
on the duct as shown hi Figure 4.4. The sample ports were located 300 inches (3.4 stack
diameters) downstream of the nearest flow disturbance (duct intersection) and 58 inches (0.7
stack diameter) upstream of the atmosphere. For isokinetic sampling, EPA Method 1 required 24
sample traverse points, six in each of the four sample ports. The results of the EPA Method 1
calculations and the locations of the traverse points are presented in Figure 4.5.
4-1
-------
2 sets of sampling ports
for isokinetic sampling
M •*—
o
0
o
o
jhouse Q
-X^ A .4—
/ /
B O
C O
D O
E O
"X
46.5"
300"
324"
AC
BC
cc
DC
EC
48.5"
96.5"
Section A
Figure 4.1 Baghouse Inlet Sampling Location, ABC Coke, Birmingham, Alabama
-------
Rectangular Stack Method 1 Calculation Results
Date: 12/09/98 Time: 13:33:00
Facility: ABC COKE
Source ID: BH Inlet "A"
Source Name: BH Inlet Batt. #5/6 "A" Ports
Date: 12/07/98
Calculated By: F. Meadows
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 52 even (inches)
Nipple Length: 31/2 (inches)
Distance from Upstream Disturbance: 300 even (inches)
Distance from Downstream Disturbance: 70 1/2 (inches)
Duct Width: 961/2 (inches)
Equivalent Diameter: 64.555172 (inches)
Upstream Duct Diameters: 4.64
Downstream Duct Diameters: 1.09
Mininum Traverse Points: 25
Resultant Matrix: 5 Ports X 5 Points
A
B
C
D
E
0.100
0.300
0.500
0.700
0.900
96 1/2
96 1/2
96 1/2
96 1/2
96 1/2
9 5/8
28 15/16
48 1/4
67 9/16
86 7/8
0.100
48 1/2
4 7/8
3 1/2
8 3/8
0.300
48 1/2
14 9/16
3 1/2
18 1/16
0.500
48 1/2
24 1/4
3 1/2
27 3/4
0.700
48 1/2
33 15/16
3 1/2
37 7/16
0.900
48 1/2
43 5/8
3 1/2
47 1/8
Figure 4.2 Method 1 Calculation Sheet, Baghouse Inlet, Method 315,
ABC Coke, Birmingham, Alabama
4-3
-------
Rectangular Stack Method 1 Calculation Results
Date: 12/09/98 Time: 13:33:37
Facility: ABC COKE
Source ID: BH Inlet B
Source Name: BH Inlet Batt.#5/6 B Ports
Date: 12/07/98
Calculated By: F. Meadows
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 52 even (inches)
Nipple Length: 31/2 (inches)
Distance from Upstream Disturbance: 324 even (inches)
Distance from Downstream Disturbance: 46 1/2 (inches)
Duct Width: 96 1/2 (inches)
Equivalent Diameter: 64.555172 (inches)
Upstream Duct Diameters: 5.01
Downstream Duct Diameters: 0.72
Mininum Traverse Points: 25
Resultant Matrix: 5 Ports X 5 Points
A
B
C
D
E
0.100
0.300
0.500
0.700
0.900
96 1/2
96 1/2
96 1/2
96 1/2
96 1/2
9 5/8
2815/16
48 1/4
67 9/16
86 7/8
0.100
48 1/2
4 7/8
31/2
8 3/8
0.300
48 1/2
14 9/16
3 1/2
18 1/16
0.500
48 1/2
24 1/4
3 1/2
27 3/4
0.700
48 1/2
3315/16
3 1/2
37 7/16
0.900
48 1/2
43 5/8
31/2
47 1/8
Figure 4.3 Method 1 Calculation Sheet, Baghouse Inlet, CARB 429,
ABC Coke, Birmingham, Alabama
4-4
-------
360° Platform
From
Baghouse
o
58"
89.375"
300"
Ground
Figure 4.4 Baghouse Outlet Sampling Location,
ABC Coke, Birmingham, Alabama
4-5
-------
Circular Stack Method 1 Calculation Results
Date: 12/07/98 Time: 15:57:34
Facility: ABC COKE
Source ID: BH Outlet
Source Name: BH Out. Batt. #5/6
Date: 12/07/98
Calculated By: F. Meadows
••i ;\
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 89 3/8 (inches)
Nipple Length: 3 5/8 (inches)
Distance from Upstream Disturbance: 300 even (inches)
Distance from Downstream Disturbance: 58 even (inches)
Number of ports: 4 ports at 90 degrees
Inside Diameter: 85.7500
Upstream Duct Diameters: 3.49
Downstream Duct Diameters: 0.67
Mininum Traverse Points: 24
(inches)
fcofn* -
Number"
0.021
85 3/4
1 13/16
3 5/8
5 7/16
0.067
85 3/4
5 3/4
3 5/8
9 3/8
0.118
85 3/4
10 1/8
3 5/8
13 3/4
0.177
85 3/4
15 3/16
3 5/8
1813/16
0.250
85 3/4
21 7/16
3 5/8
25 1/16
0.356
85 3/4
30 1/2
3 5/8
34 1/8
Figure 4.5 Method 1 Calculation Sheet, Baghouse Outlet,
ABC Coke, Birmingham, Alabama
4-6
-------
4.1.3 Combustion (TJnderfire) Stack
The combustion (underfire) stack test location was on a 187-inch ID round vertical stack
at the sample port location. This was a double wall stack with a slightly decreasing diameter
with the increase of vertical stack height. Four sampling ports were positioned as shown in
Figure 4.6. These sample ports were located 720 inches (3.9 stack diameters) downstream of the
nearest flow disturbance (elbow) and 2,040 inches (10.9 stack diameters) upstream of the
atmosphere. For isokinetic sampling, EPA Method 1 required 24 sample traverse points, six in
each of the four sample ports. The results of the EPA Method 1 calculations and the locations of
the sample traverse points are presented in Figure 4.7.
Due to safety issues, only two of the four sample ports could be used for sampling. Also,
it was not possible to sample across the entire stack cross-section because the required sample
probe lengths were too long for using glass liners. Therefore, it was decided to conduct velocity
measurements at each of the 24 traverse points and if the velocity profile was found to be
uniform (within 10%), then sampling would be conducted at six traverse points in each of the
two sample ports. The average square root of the velocity pressure for the 24 points was 0.085
with a standard deviation of 0.017 compared to 0.091 (+7%) and a standard deviation of 0.016
for the 12 points selected for testing.
4-7
-------
tA I
2040"
720"
Process Emissions
187"
4 22-inch deep
nipples
Section A
Figure 4.6 Combustion (Underfire) Stack Sampling Location,
ABC Coke, Birmingham, Alabama
4-8
-------
Circular Stack Method 1 Calculation Results
Date: 12/07/98 Time: 16:49:47
Facility: ABC COKE
Source ID: UF Stack "B"
Source Name: Beckers Underfire Stack Port B
Date: 12/07/98
Calculated By: F. Meadows
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 212 even (inches)
Nipple Length: 25 even (inches)
Distance from Upstream Disturbance: 720 even (inches)
Distance from Downstream Disturbance: 2040 even (inches)
Number of ports: 4 ports at 90 degrees
Inside Diameter: 187
Upstream Duct Diameters: 3.85
Downstream Duct Diameters: 10.90
Mininum Traverse Points: 24
(inches)
0.021
187 even
315/16
25 even
2815/16
0.067
187 even
12 1/2
25 even
37 1/2
0.118
187 even
22 1/16
25 even
47 1/16
0.177
187 even
33 1/8
25 even
58 1/8
0.250
187 even
46 3/4
25 even
71 3/4
0.356
187 even
66 9/16
25 even
91 9/16
Figure 4.7 Method 1 Calculator! Sheet, Combustion Stack,
ABC Coke, Birmingham, Alabama
4-9
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES
Source sampling was performed at the locations described in the preceding section to
determine the concentrations and mass emission rates of filterable particulate matter (PM),
methylene chloride extractable matter (MCEM), and polycyclic aromatic hydrocarbons (PAHs).
In addition, once the MCEM analyses were completed, the MCEM samples were also analyzed
to determine 17 trace metals. Three test runs were conducted at each of the locations (the
baghouse inlet and outlet testing was conducted simultaneously). Four test runs were conducted
at the underfire stack, one test run during a period of non-charging and non-pushing operations.
The underfire stack test was conducted separately from the baghouse test.
Each test run covered approximately an 8-hour period for the baghouse sampling, one test
run per day. Due to the frequency and duration of each coke oven pushing event, isokinetic
sampling was conducted as follows:
• During each oven push, a maximum air flow to and from the baghouse is achieved
when dampers are opened for a period of approximately 90 seconds, resulting in
significantly higher stack gas differential pressures than at idle periods. Maximum air
volumes were metered through the sample trains during each oven push. During idle
periods, isokinetic sampling was maintained at a much lower sampling rate. The
dampers on the baghouse remain open at approximately 10% during idle periods.
Sampling on the underfire stack resulted in test runs of approximately three hours
duration. Testing was conducted over two days.
In Table 5.1, the parameters measured, the sampling methods, the number of tests
performed, and the duration of each test are summarized. Brief descriptions of the sampling and
analysis procedures used are presented below.
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS
EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
establish velocity and sample traverse point locations. The process ductwork, and the locations
of measurement sites and sample traverse points are discussed in Section 4.0 of this document.
5-1
-------
TABLE 5.1
SUMMARY OF SAMPLING LOCATIONS, TEST PARAMETERS,
SAMPLING METHODS, AND NUMBER AND DURATION OF TESTS,
ABC COKE, BIRMINGHAM, ALABAMA
Sampling
Location
Coke Oven
Battery No. 5/6
Baghouse
Inlet
Coke Oven
Battery No. 5/6
Baghouse
Outlet
Beckers
Underfire
Stack
Test Parameter
Exhaust gas flow rate
CO2 and O2 content
Moisture content
Particulate/MCEM/metals
PAHs
Exhaust gas flow rate
CO2 and 02 content
Moisture content
Particulate/MCEM/metals
PAHs
Exhaust gas flow rate
C02 and 02 content
Moisture content
Particulate/MCEM/metals
PAHs
Sampling Methods
EPA Method 2
EPA Method 3B
EPA Method 4
EPA Method 315
CARD Method 429
NIOSH Method 5506
EPA Method 2
EPA Method 3B
EPA Method 4
EPA Method 3 15
CARB Method 429
NIOSH Method 5506
EPA Method 2
EPA Method 3B
EPA Method 4
EPA Method 315
CARB Method 429
NIOSH Method 5506
Number
of Tests
3
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
1
Avg. Duration
Per Test (min.)
438
438
438
438
438
438
412
412
412
412
411
424
180
180
180
180
180
76
5-2
-------
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE
EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type
S Pilot Tube)," was used to determine exhaust gas velocity. A Type S Pitot tube, constructed
according to Method 2 criteria and having an assigned coefficient of 0.84, is connected to an
inclined-vertical manometer. The pitot tube was inserted into the duct and the velocity pressure
(Ap) was recorded at each traverse point. The effluent gas temperature was also recorded at each
traverse point using a Type K thermocouple. The average exhaust gas velocity was calculated
from the average square roots of the velocity pressure, average exhaust gas temperature, exhaust
gas molecular weight, and absolute stack pressure. The baghouse sampling required using time
weighted averages of velocity pressure, exhaust gas temperatures, and meter temperatures to
calculate volumetric flow rates. The volumetric flow rate is the product of velocity and the stack
cross-sectional area of the duct at the sampling location. Because of limited accessibility with
the proximity of the coke oven battery pushing mechanism, only two of four sampling ports were
sampled on the combustion stack. A specially constructed pitot tube was used to conduct a
complete velocity traverse across the underfire stack diameter to verify that stack gas differential
pressures were similar for all four sampling ports.
5.3 DETERMINATION OF STACK GAS EMISSION RATE CORRECTION
FACTORS, DRY MOLECULAR WEIGHT, AND EXCESS AIR
EPA Method 3B, "Gas Analysis for the Determination of Emission Rate Correction
Factor or Excess Air," was used to determine stack gas emission rate correction factors and
molecular weight. Bag samples were collected and analyzed for each measurement run using an
Orsat® combustion gas analyzer which read ±0.1% concentrations of carbon dioxide and
oxygen. One integrated bag sample was collected per each 120 minutes of sampling time at the
baghouse inlet and outlet, as well as the underfire stack.
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT
EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine the flue gas moisture content. EPA Method 4 was performed in conjunction with each
EPA Method 315 and CARB Method 429 test run. Integrated, multi-point, isokinetic sampling
was performed. Condensed moisture was determined by recording pre-test and post-test weights
of the impingers, reagents, and silica gel. XAD® adsorbent traps were also pre- and post-test
weighed and included in the CARB Method 429 moisture determination.
5-3
-------
5.5 DETERMINATION OF PARTICULATE MATTER/METHYLENE CHLORIDE
EXTRACT ABLE MATTER/METALS
EPA Method 315, "Determination of Particulate and Methylene Chloride Extractable
Matter (MCEM) from Selected Sources at Primary Aluminum Production Facilities" was used to
determine PM, MCEM, and metals.
This method is applicable for the simultaneous determination of PM and MCEM. PM
and MCEM are withdrawn isokinetically from the source. PM is collected in the probe and on a
tared glass fiber filter at 248 ± 25 °F. A schematic of the MCEM sample train is shown in
Figure 5.1. The sampling train consisted of a glass nozzle, a heated glass lined probe, a heated
tared quartz fiber filter, two impingers each containing 100 milliliters of Type II distilled, de-
ionized water, an empty impinger, and an impinger containing approximately 250 grams of
indicating silica gel. The glass nozzle was joined to the probe using a Teflon®-coated stainless
steel union and Teflon® or graphite ferrules. At the underfire stack sampling location, two of
four sampling ports were utilized because of limited sampling access. The sampling probes
traversed half of the stack diameter. ERG submitted tared, quartz fiber filters to PES for
sampling, which were returned after the test program for PM and MCEM analysis. The PM mass
was determined gravimetrically after removal of combined water. MCEM was then determined
by performing a methylene chloride extraction of the sample train fractions and determining the
residue gravimetrically after evaporating the solvents.
Following completion of the MCEM analyses by ERG, the PM and MCEM samples were
submitted to FAL where they were digested and analyzed for the presence of 17 trace metals
using three different analytical techniques. This analysis provided an approximation of the trace
metals present in the stack gases. The target metals include antimony (Sb), arsenic (As), barium
(Ba), beryllium (Be), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), lead (Pb),
manganese (Mn), mercury (Hg), nickel (Ni), phosphorous (P), selenium (Se), silver (Ag),
thallium (Tl), and zinc (Zn). Cadmium, manganese, lead (inlet), and zinc were determined by
Direct Aspiration Flame Atomic Absorption Spectrophotometry (FLAAS). Antimony, arsenic,
beryllium, lead (other sources and blanks), nickel, selenium, silver, and thallium were
determined by Graphite Furnace Atomic Absorption Spectrophotometry (GFAAS). Barium,
chromium, cobalt, copper and phosphorus were determined by Inductively Coupled Plasma -
Optical Emission (ICP). Mercury was determined by Cold Vapor Atomic Adsorption
Spectrophotometry (CVAAS).
Baghouse dust samples were collected and composited in sample containers for each test
run. Composites were collected at the beginning, middle, and end of the individual sample runs.
FAL analyzed the three samples for the same number and type of analytes as for the EPA
Method 315 samples with the exception of cobalt which was inadvertantly omitted from the
analyte list provided to the analytical laboratory. Samples were prepared by nitric acid digestion,
followed by analysis by FLAAS, GFAAS, ICP and CVAAS.
5-4
-------
Temperature
Sensor
Temperature
Sensor
Temperature
Sensor
Gooseneck
Nozzle
HeatTraoad
Glass-toad
Probe
Type 8 Pilot Tub*
Vacuum
Una
ManometB/
Orifloa
' . ' . L
• DryQa*
Meter
I
i i
\
Air-Tight
Pump
Figure 5.1 Sampling Train Schematic for EPA Method 315
-------
5.6 POLYCYCLIC AROMATIC HYDROCARBONS
CARS Method 429, "Determination of Polycyclic Aromatic Hydrocarbon (PAH)
Emissions from Stationary Sources," was used to determine PAHs. This method is applicable for
the determination of 19 PAHs. Quanterra submitted solvent extracted XAD-2® resin sorbent
cartridges and untared Teflon® filters for sampling purposes. The sampling train consisted of a
glass nozzle, a heated glass lined or Teflon® probe, a heated precleaned, untared Teflon® mat
filter, a water-cooled coil condenser, and an adsorbent trap containing approximately 40 grams of
XAD-2® adsorbent resin. The first impinger was empty, the next two each contained 100
milliliters of 3 mM sodium bicarbonate and 2.4 mM sodium carbonate. The next impinger was
empty, followed by the last impinger which contained approximately 250 grams of indicating
silica gel. At the underfire stack sampling location, two of four sampling ports were utilized
because of limited sampling access. The sampling probes traversed half of the stack diameter.
Particulate and gaseous phase PAHs were extracted isokinetically from the source and collected
in the probe and filter, XAD® resin, and impinger portions of the sample train. A schematic of
CARS Method 429 is shown in Figure 5.2. Figure 5.3 is a schematic of the GARB Method 429
sample recovery process. Analysis was accomplished by isotope dilution mass spectrometry
combined with high resolution gas chromatography. Figure 5.4 is a schematic of the CARB
Method 429 analytical process.
NIOSH Method 5506 was also used to scan for gaseous phase PAHs at the baghouse
inlet, outlet, and underfire stack. Only one sample run was conducted at the underfire stack
sampling location due to limited accessibility of the sampling ports. The samples were collected
at each location using an in-stack filter followed by a series of three out-of-stack XAD-2®
sorbent tubes. Sampling was performed continuously throughout the pushing operations and
during idle periods at a sample rate of 1.5-2 liters per minute. The samples were analyzed using
high performance liquid chromatography and fluorescence/UV detection. The NIOSH 5506
method was used to scan for PAHs in the event CARB Method 429 results were below analytical
detection limits. The NIOSH results were not intended to be compared to CARB 429 results.
5-6
-------
Condeneer
Button Hook
Nozzle
Temperature
Sensor
Inclined Reclrculatlon
Manometer Pump
Empty 100 ml HPLC Water Empty Silica Gel
Oat
Exit
Vacuum
Line
Inclined
Manometer
Vacuum
Pump
Figure 5.2 Sampling Train Schematic for CARB Method 429
5-1
-------
Rlnsa with known volume:
1. acetone
2. melhylene chloride
3. hexane
Nozzle and
Probe Liner
(
Container
Mark liquid level.
Store at
-------
Surrogate Standards
Added to XAD-2 Resin
Recovery Standards
Containers No. 1 and No. 3
G.C7 Mass Spec.
Figure 5.4 CARB Method 429 Analytical Schematic
5-9
-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL
PROCEDURES AND RESULTS
This section describes the specific QA/QC procedures employed by PES in performing
this series of tests. The procedures contained in the "Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume III, Stationary Source Specific Methods," EPA/600/R-
94/038c, and in the reference test methods served as the basis for performance for all testing and
related work activities in this project.
6.1 CALIBRATION OF APPARATUS
The preparation and calibration of source sampling equipment is essential in maintaining
data quality. Brief descriptions of the calibration procedures used by PES follow.
6.1.1 Barometers
PES used aneroid barometers which are calibrated against a station pressure value
reported by a nearby National Weather Service Station corrected for elevation.
6.1.2 Temperature Sensors
Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Section 3.4.2 of the Quality Assurance Handbook, Volume III, 1994.
Each temperature sensor was calibrated over the expected range of use against an ASTM 3C or
3F thermometer. Table 6.1 summarizes the type of calibrations performed, the acceptable levels
of variance, and the results. Digital thermometers were calibrated using a thermocouple
simulator having a range of 0-2400°F.
6.1.3 Pitot Tubes
Type S pitot tubes constructed to EPA Method 2 specifications were used. Pitot tubes
meeting these specifications are assigned a baseline coefficient of 0.84 and need not be
calibrated. The dimensional criteria and results for each pitot tube used are summarized in
Table 6.2.
6-1
-------
TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp. Sensor
I.D.
4A
4B
4E
5E
12A
RP20
RP21
MB-1
MB-2
Usage
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Gas Meter Inlet
Gas Meter Outlet
Gas Meter Inlet
Gas Meter Outlet
Temperature, °F
Reference
72
52
195
284
74
36
208
307
74
38
203
339
74
46
200
318
72
31
205
352
72
32
210
74
32
208
75
38
190
75
37
190
70
34
160
70
34
160
Sensor
72
51
194
283
74
42
204
309
74
38
202
340
74
46
200
318
72
32
206
352
69
32
208
75
32
209
75
38
190
74
37
190
69
34
159
70
33
160
Temperature
Difference, %
0.0
0.2
0.15
0.13
0.0
0.0
0.0
0.0
0.0
0.0
0.15
0.13
0.0
0.0
0.0
0.0
0.0
0.2
0.15
0.0
0.7
0.0
0.3
0.2
0.0
0.2
0.0
0.0
0.0
0.2
0.0
0.0
0.2
0.0
0.2
0.0
0.2
0.0
Calibration
Tolerances
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
-------
TABLE 6.1 (concluded)
Temp. Sensor
I.D.
MB-3
MB-5
MB-6
Usage
Gas Meter Inlet
Gas Meter Outlet
Gas Meter Inlet
Gas Meter Outlet
Gas Meter Inlet
Gas Meter Outlet
Temperature, °F
Reference
74
30
190
73
32
190
70
34
160
70
34
160
68
33
155
68
33
155
Sensor
74
31
190
72
31
190
69
34
159
71
33
161
67
34
155
68
34
156
Temperature
Difference, %
0.0
0.2
0.0
0.2
0.2
0.0
0.2
0.0
0.2
0.2
0.2
0.2
0.2
0.2
0.0
0.0
0.2
0.2
Calibration
Tolerances
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±l%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
<±1%
6-3
-------
TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
Measurement
«1
«2
PI
P2
Y
1
A
Z
w
D,
A/2/D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
s 0.125 in.
<, 0.03125 in.
0.1 875" sD.s
0.375"
l.OSD.s As
1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
4A
1.1
0.8
0.5
0.3
0.8
0.7
0.967
0.014
0.012
0.375
1.29
Yes
0.84
4B
3
2
0
1
1
1
0.949
0.017
0.017
0.375
1.27
Yes
0.84
4E
0
I
1
3
0
1
0.973
0
0.017
0.375
1.30
Yes
0.84
5C
0
1
1
1
1
1
0.948
0.017
0.017
0.375
1.26
Yes
0.84
5E
1
1
1
3
0
1
1.122
0
0.020
0.375
1.49
Yes
0.84
12A
4
5
3
0
2
1
0.936
0.033
0.016
0.375
1.25
Yes
0.84
RP20
0
1
1
0
1
0
1.023
0.017
0
0.375
1.36
Yes
0.84
RP21
0
1
1
0
1
0
1.023
0.017
0
0.375
1.36
Yes
0.84
6-4
-------
6.1.4 Differential Pressure Gauges
PES used Dwyer inclined/vertical manometers to measure differential pressures. The
differential pressures measurements included velocity pressure, static pressure, and meter orifice
pressure. Manometers are selected with sufficient sensitivity to accurately measure pressures
over the entire range of expected values. Manometers are primary standards and require no
calibration.
6.1.5 Dry Gas Meters and Orifices
The EPA Method 315 and CARB Method 429 dry gas meters and orifices were calibrated
in accordance with Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure involves direct
comparison of the dry gas meter to a reference dry test meter. The reference dry test meter is
calibrated annually using a wet test meter. Before its initial use in the field, the metering system
was calibrated over the entire range of operation as specified in EPA Method 5. After field use,
the metering system was calibrated at a single intermediate setting based on the previous field
test. Acceptable tolerances for the initial and final dry gas meter factors and orifice calibration
factors are ± 0.05 and ± 0.20 from average, respectively. The calibration results for the gas
meters and orifices used in this test program are summarized in Table 6.3. In all cases, the dry
gas meter and orifice calibrations met the method requirements.
6.2 ON-SITE MEASUREMENTS
The on-site QA/QC activities include:
6.2.1 Measurement Sites
Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axis to ensure uniformity of the stack/duct inside diameter. The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest 1/8
inch.
6.2.2 Velocity Measurements
All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each determination. The static pressure was determined at a single
point near the center of the stack or duct cross-section.
6-5
-------
TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
MB-1
MB-2
MB-3
MB-5
MB-6
Gamma
Pre-test
1.012
1.002
1.004
0.981
1.005
Post-test
1.003
0.986
0.997
0.994
0.992
% Diff.
0.9
1.6
0.7
1.3
1.3
EPA Criteria
±5%
±5%
±5%
± 5%
± 5%
Orifice Coefficient
Average
1.954
1.797
1.784
1.770
1.778
Range
1.916-2.013
1.719-1.852
1.749-1.835
1.719-1.830
1.680-1.850
EPA Criteria
1.954 ±0.20
1.797 ± 0.20
1.784 ± 0.20
1.770 ± 0.20
1.778 ± 0.20
6-6
-------
6.2.3 Flue Gas Composition
Integrated, multi-point, flue gas samples were collected in Tedlar® gas bags from the
baghouse inlet and outlet and underfire stack. Prior to use the bags were leak checked and
purged with nitrogen to ensure cleanliness. Prior to and after completion of each sampling run,
the entire sampling system was leak checked from the tip of the probe. The bag samples were
analyzed on-site using an Orsat® analyzer within four hours after sample collection, in
accordance with EPA Method 3B. Prior to use the Orsat® analyzer was assembled and
replenished with fresh reagents and leak checked using the manufacturer's procedures.
6.2.4 Moisture
The EPA Method 315 and GARB Method 429 sampling trains were used to determine the
flue gas moisture content. During sampling, the exit gas of the last impinger was maintained
below 68 °F to ensure complete condensation of flue gas water vapor. The total moisture was
determined gravimetrically using an electronic platform balance with 0.1 gram sensitivity. The
XAD® adsorbent modules from the CARB Method 429 sampling trains were also weighed and
their weights included in the moisture catch.
6.2.5 EPA Method 315 and CARB Method 429
The field sampling QA/QC for the EPA Method 315 and CARB Method 429 sampling
trains were similar. Table 6.4 summarizes the critical measurements made and EPA's critical
acceptability criteria. All pre- and post-test sample train leak checks met the acceptance criteria.
Most of the isokinetic sampling rates deviated by no more than ±10% thereby meeting the
method criteria of 90-110%. There were four sample runs slightly outside of this range, two at
the baghouse inlet and one at the baghouse outlet. These are not believed to have had an impact
on sample results.
The EPA Method 315 and CARB Method 429 field blanks were collected near each of
the sampling locations to check for any sample contamination at the sites. Sample trains were
assembled and pre- and post-test leak checks were conducted. The sample trains were recovered
in the same manner as the actual sample runs. Each field blank train was subjected to a
minimum of one leak check in the laboratory (filter holder assembly) and a minimum of three at
the sampling site.
An acetone and methylene chloride blank and tared quartz fiber filter were taken as
control samples for the particulate/MCEM analysis and subsequent analysis for metals. Blanks
were taken of the impinger and recovery reagents.
6-7
-------
TABLE 6.4
SUMMARY OF EPA METHOD 315 AND CARB METHOD 429 FIELD SAMPLING QA/QC DATA
Date
09/21/98
09/22/98
o^s
09/24/98
09/25/98
Site
Baghouse Inlet
Baghouse Outlet
Baghouse Inlet
Baghouse Outlet
Baghouse Inlet
Baghouse Outlet
Underfire Stack
Run No.
A-I-315-1
A-I-429-1
A-O-315-1
A-O-429-1
A-I-315-2
A-I-429-2
A-O-315-2
A-O-429-2
A-I-315-3
A-I-429-3
A-O-315-3
A-O-429-3
A-U-315-1
A-U-315-2
A-U-429-1
A-U-429-2
A-U-315-3
A-U-3I5-4
A-U-429-3
A-U-429-4
Pre-Test
Leak Rate
acfm
0.005 @1 5" Hg
0.003 @ 15" Hg
0.002 @1 5" Hg
0.004 @1 5" Hg
0.004 @1 5" Hg
0.006 @ 14" Hg
0.004 @1 5" Hg
0.006 @1 5" Hg
0.002 @1 5" Hg
0.003 @1 5" Hg
0.009 @1 5" Hg
0.004 @1 5" Hg
0.005 @1 5" Hg
0.002 @1 5" Hg
0.003 @ 15" Hg
0.009 @1 5" Hg
0.002 @l 5" Hg
0.002 @ 1 5" Hg
0.006 @1 5" Hg
0.002 @ 12" Hg
Post-Test
Leak Rate
acfm
0.002 @ 10" Hg
0.002 @ 10" Hg
0.001@6"Hg
0.005 @1 5" Hg
0.001 @ 10" Hg
0.001@8"Hg
0.005 @ 14" Hg
0.002 @1 5" Hg
0.001@6"Hg
0.001 @ 8" Hg
0.003 @ 15" Hg
0.002 @ 16" Hg
0.007 @ 8" Hg
0.004 @ 8" Hg
0.001 @ 14" Hg
0.002 @ 8" Hg
0.007 @ 7" Hg
0.002 @ 9" Hg
0.001 @ 7" Hg
0.002@12" Hg
EPA
Criteria
acfm
s 0.020
s 0.020
s 0.020
s 0.020
s 0.020
sO.020
s 0.020
sO.020
<0.020
sO.020
sO.020
sO.020
sO.020
sO.020
<0.020
< 0.020
sO.020
<0.020
<0.020
< 0.020
Percent
Isokinetic
100.3
99.7
99.6
96.3
98.3
88.4
100.0
97.8
97.6
116.7
85.2
92.6
105.3
98.6
87.6
100.0
97.5
96.6
98.2
97.6
EPA
Criteria
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
6-8
-------
CARB 429 control samples consisted of acetone, methylene chloride and hexane, as well as an
untared Teflon® filter and XAD® resin trap.
6.3 LABORATORY ANALYSES
The EPA Method 315 and CARB Method 315 samples were hand delivered to FES'
contract laboratories for analyses. Upon delivery, the samples were transferred to the laboratory
sample custodian, where they were unpacked and inspected for damage, status, and chain-of-
custody documentation. All samples were received by the laboratories in good condition. The
PES Project Manager and Field Team Leader then contacted the laboratory analysts and
discussed the samples and the analyses required.
PES also conducted a follow-up visit to three of the four laboratories to review
procedures for sample handling and tracking, sample preparation and analyses, data reporting,
and quality control. Visits were made to ERG, FAL and Quanterra. A visit was not made to
LabCorp. The results of these visits are summarized in Appendix E. It is the opinion of PES that
the analytical laboratories selected to support this assignment were well staffed, used state-of-
the-art equipment, followed rigorous QA/QC procedures, and submitted accurate reports of the
anlaytical results.
6.3.1 EPA Method 315 Filterable Particulate and Methvlene Chloride Extractable Matter
Filterable PM and MCEM analysis consisted of front half acetone and methylene chloride
sample rinses and quartz fiber filters. Back half MCEM analysis consisted of acetone and
methylene chloride rinses of impingers containing distilled, deionized water. Prior to the field
testing program, the filters were tared in the ERG laboratory, stored in glass petri dishes and
sealed with Teflon® tape. Upon receipt of the samples in the ERG laboratory, the acetone rinses
were placed in tared beakers and evaporated to dryness at room temperature. The filters and
beakers were dessicated and weighed to a constant weight. Table 6.5 summarizes the EPA
Method 315 lab blank QC data results. Table 6.6 summarizes the EPA Method 315 field blank
QC data results.
The front half samples were re-dissolved in methylene chloride, filtered, and the filtered
liquid dessicated to dryness for MCEM determination. The backhalf impinger fraction was
extracted with several portions of methylene chloride and placed in a beaker. The solvent is
evaporated and dessicated to dryness for weighing. Criteria of acceptance of gravimetric analysis
is ± 0.5 milligrams between two weights, taken at least six hours apart.
6.3.2 EPA Method 29 - Multiple Metals
FAL analyzed the filterable particulate catch of the quartz filters and also the particulate
and extracted organic matter residue of the EPA Method 315 samples. A total of 17 metals were
analyzed for. Analysis followed EPA Method 29 analytical procedures. A total of 13 samples
6-9
-------
TABLE 6.5
SUMMARY OF EPA METHOD 315 ANALYTICAL QC DATA
LAB BLANK ANALYSIS
Sample Fraction
Quartz Filter
Acetone
Methylene Chloride
Distilled Water
Particulate,
grams
0.0002
0.0003
0.0001
0.0003
MCEM,
grams
0.0001
—
—
-
6-10
-------
TABLE 6.6
SUMMARY OF EPA METHOD 315 ANALYTICAL QC DATA
FIELD BLANK ANALYSIS
Sample Fraction
Filter- PM
MCEM
Acetone FHR,
PM
Methylene Chloride FHR,
MCEM
Acetone BHR,
MCEM
Methylene Chloride BHR,
MCEM
H2O Impinger Rinses,
MCEM
Baghouse Inlet
B-I-315-FB,
grams
0.0001
0.0000
0.0002
0.0000
0.0000
0.0001
0.0001
Baghouse Outlet
B-0-315-FB,
grams
0.0000
0.0000
0.0001
0.0000
0.0012
0.0077
0.0001
Underfire Stack
B-U-315-FB,
grams
0.0000
0.0000
0.0002
0.0000
0.0001
0.0003
0.0002
6-11
-------
were analyzed. Nine were stack gas samples, three were field blanks and one was a reagent
blank. Cadmium, manganese, lead (inlet samples) and zinc were analyzed by Direct Aspiration
Flame Atomic Absorption Spectrophotometry (FLAAS). Antimony, arsenic, beryllium, lead,
nickel, selenium, silver, and thallium were determined by Graphite Furnace Atomic Absorption
Spectrophotometry (GFAAS). Barium, chromium, cobalt, copper, and phosphorus were
determined by Inductively Coupled Plasma - Optical Emission (ICP). Specific QA and QC
activities for the analyses consisted of a reagent blank (quartz filter and pan) and spike recoveries
of 16 of the analytes. Recoveries ranged from 83 to 113%. Duplicate analysis on several metals
were within the acceptable limit of 20%. Table 6.7 summarizes the EPA Method 29 analytical
recovery and duplicate analyses QC results.
6.3.3 CARE Method 429
PAHs were analyzed following the procedures of CARB Method 429. All fractions of
the sampling train were combined for a single extract which was analyzed by high resolution gas
chromatography/high resolution mass Spectrophotometry (HRGC/HRMS). Nine stack gas
samples were analyzed, along with three field blanks, a method blank and lab blank. The XAD®
resin cartridges were spiked with surrogate standards prior to use for field sampling to
demonstrate overall sampling and analytical recovery efficiency. After samples were received in
the laboratory and prior to sample extraction, a laboratory control sample was prepared with two
levels of surrogate standards to monitor the precision and accuracy of the analytical process
independently of sample matrix effects. Table 6.8 summarizes the CARB Method 429 field
blank QC results. Table 6.9 summarizes the CARB Method 429 lab control sample QC results.
Table 6.10 summarizes the CARB Method 429 surrogate standards recoveries for 17 analytes for
all nine field sample runs.
6-12
-------
TABLE 6.7
SUMMARY OF EPA METHOD 29 ANALYTICAL QC DATA
LAB CONTROL SAMPLE (LCS) RECOVERY AND DUPLICATE ANALYSIS
Analyte
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Manganese
Mercury
Lead
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
Spike Amount,
A«8/l
92.7
116.5
518
4.2
6.4
64.7
873
492
434
5.2
104.9
105.1
1902
52.1
9.2
50.1
518
LCS Recovery,
%
92.7
113.4
93.8
83.2
92.2
92.4
87.3
92.8
95.5
103.7
93.0
105.1
87.0
104.2
91.7
100.2
90.8
Recovery
Limit,
%
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Duplicate RPD,
%
-
-
6.0
-
--
--
3.0
37
10.2
-
-
-
8.8
-
--
-
7.0
RPD Limit,
%
-
--
± 20%
--
-
-
± 20%
± 20%
± 20%
-
-
-
± 20%
-
--
--
± 20%
6-13
-------
TABLE 6.8
SUMMARY OF CARD METHOD 429 ANALYTICAL QC DATA
FIELD BLANK RESULTS
Analyte
Naphthalene
2-MethyInaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a) anthracene
Chrysene
Benzo(b) fluoranthene
Benzo(k) fluoranthene
Benzo(e) pyrene
Benzo(a) pyrene
Perylene
Indeno(l,2,3-cd) pyrene
Dibenz(a,h) anthracene
Benzo(g,h,i) perylene
Baghouse Inlet
Mg/sample
1.600
0.200
ND
ND
ND
0.210
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Baghouse Outlet
Atg/sample
1.000
ND
ND
ND
ND
0.270
ND
0.190
0.150
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Underfire Stack
/jg/sample
0.980
ND
ND
ND
ND
0.120
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6-14
-------
TABLE 6.9
SUMMARY OF CARB METHOD 429 ANALYTICAL QC DATA
LAB CONTROL SAMPLE (LCS)
Analyte
Naphthalene
2-Methylnapthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno( 1 ,2,3-cd)py rene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-d 1 0
Phenanthrene-dlO
Fluoranthene-d 1 0
Pyrene-d 1 0
Benzo(a)anthracene-d 1 2
Spike Amounts,
Atg/sample
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
50
50
50
50
50
50
50
50
LCS Recovery,
%
90
100
100
92
77
81
78
80
64
87
77
76
66
73
68
79
90
76
88
27
31
31
28
38
24
26
31
Recovery Limits,
%
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-15
-------
TABLE 6.9 (concluded)
Analyte
Chrysene-dl2
Benzo(b)fluoranthene-d 1 2
Benzo(k) fluoranthene-dl2
Benzo(a)py rene-d 1 2
Perylene-dl2
Indeno( 1 23-cd)py rene-d 1 2
Dibenz(a,h) anthracene-d!4
Benzo(g,h,i) perylene-d!2
Spike Amounts,
Mg/sample
50
50
50
50
50
50
50
50
LCS Recovery,
%
43
36
44
45
32
59
56
54
Recovery Limits,
%
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-16
-------
TABLE 6.10
SUMMARY OF CARB METHOD 429 ANALYTICAL QC DATA
SURROGATE STANDARD RECOVERIES
Analyle
l3C-Fluorene
Naphthalene-d8
Acenaphlhylene-d8
Acenaphthene-d 1 0
Fluorene-dlO
Phenanthrene-d 1 0
Fluoranlhene-dlO
Pyrcne-dlO
Benzo(a)anlhraccne-d 1 2
Perylene-d 1 2
Indeno( 1 23cd)pyrene-d 1 2
Chrysene-d 1 2
Benzo(b)fluoranthene-d 1 2
Benzo(k)fluoranthene-d 1 2
Benzo(a)pyrene-d 1 2
Dibenz(a,h)anlhracene-d 1 4
Benzo(j>,h,i)perylene-d 1 2
A-I-429-1,
%
82
58
50
45
53
81
48
51
61
58
91
72
87
86
78
83
64
A-I-429-2,
%
103
75
58
64
43
98
62
73
64
53
95
66
103
70
75
91
80
A-I-429-3,
%
94
77
58
70
50
99
49
80
75
54
90
68
99
73
68
87
68
A-O-429-1,
%
124
92
90
74
69
99
69
70
81
60
81
79
88
87
77
77
69
A-O-429-2,
%
112
46
75
72
75
88
58
56
75
58
73
80
94
88
76
64
76
A-CM29-3,
%
117
65
85
82
75
107
69
63
80
58
80
85
88
87
73
81
66
A-U-429-1,
%
119
46
5
50
81
94
70
57
52
14
70
80
79
80
18
77
58
A-U-429-2,
%
99
42
4
49
78
95
65
55
61
12
52
76
74
66
17
56
40
A-U-429-3,
%
104
52
9
59
73
88
77
64
75
20
77
95
93
90
22
79
57
Recovery
Limits,
%
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-17
-------
APPENDIX A
PROCESS DATA
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALThl
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
r\ > i i/ , I r
Comp
Sourc
Date
Evalu
Highe
Min. E
Direct
Stack
Plurm
iany
y c
/ r --•/ /,- ^
t (JndtA\ r<.', ^Jf^cX a
:/ <^
.'
\
•r
Plant ID #
O
o
'?Hj 4 ' Point
/ */
,--/ .
Start/StOD Time /O - ,- '/' / $•• ^ '/
126 £2.7 C?
Min. Avg:
^
2nd:
Exceeding: 20% Opacity =
ion from Source 7* ..
Hei
3 CO
3ht r^-O
or t
0' ft
v/? /
O
, Stack Heig
Seconds
Mm
0
1
2
3
4
5
6
n
8
9
10
11
12
13
14
0
^T
l"™"""
/ O
//')
/<£,
tfU
^'( )
$o
?Q
ID
'^"
c,
C-2
Cs
c>
15
^
S
/D
/£)
y<
-'.-/^
xO
'SO
/s
/^
5
S
o
•C^
O>
45
5
^~
//J
/A
yX** r y
'9(9
9L)
sfa
/D
f'
bs. I^O
nd *-> /•
ft. -M
'"' ( - V-
^ind
u
Seconds
Min
15
16
17
18
19
*£~20
' 21
22
23
24
25
26
27
28
29
SYMBOLS
sun * wind -»
plume and stack t^X \'i/
stack > f
0
/%-
L~J
(^~)
C^
O
&
<^>
C13
>
J>
£l_^
30
O
ci)
.-^
^7
<^>
^
O
^
(O
ci^
.">
5
-^
45
O
O
) o
r,
(O
?**>
2)
(^V
/•*-}
o
CJ>
>
^S -
o
__^
2>
ID#
^
^/j
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Regulation Nbr.
/
0 °
<0
^
'\-
M
/
7
V
Vapor/Steam Plume Visible ?
Direction ^
Sky Conditi
Seconds
Mm
30
31
32
33
34
35
36
^37
38
39
40
41
42
43
44
0
f-9
o*-
/'->
/{ 3
/^
/ r:-)
^?
/(_s
JT
u
a
^~~)
<^?
,^;>
(O
15
CO
f")
/O
//}
/*?
Z "j
y^
A'J
o
c->
c"--5
(^>
(^>'
O
c~)
3U
,--••)
Cj
In
/ , ;
/C
/^>
/C)
<^
c3
o>
(J
(^>
(~~>
/ )
rS
45
C^
/6^
lo
/u
/^
/ C,
/O
s •
C-}
_O
(~~~)
o
&
C~)
(—)
w
on
Plume
nd Spec
Detatched ?
:d
-
Seconds
Min
45
46
47
48
49
50
51
52
Mir53'
54
55
56
57
58
t>y
0
O
f~)
C3
d>
( )
&
^")
f)
*O
r'y
,'- <
7"}
&
<"
j^
15
O
^O
o
£*~>
-------
ABC Coke
Run No.
A-I-M315-1
A-I-M429-1
A-I-M5506-1
A-I-M315-2
A-I-M429-2
A-I-M5506-2
A-I-M315-3
A-I-M429-3
A-I-M5506-3
A-O-M315-1
A-O-M429-1
A-O-M5506-1
A-O-M315-2
A-O-M429-2
A-O-M5506-2
A-0-M315-3
A-O-M429-3
A-O-M5506-3
A-U-M315-1
A-U-M429-1
A-U-M315-2
A-U-M429-2
A-U-M315-4
A-U-M429-4
A-U-M5506-1
Date
09/21/98
09/21/98
09/21/98
09/22/98
09/22/98
09/22/98
09/23/98
09/23/98
09/23/98
09/21/98
09/21/98
09/21/98
09/22/98
09/22/98
09/22/98
09/23/98
09/23/98
09/23/98
09/24/98
09/24/98
09/24/98
09/24/98
09/25/98
09/25/98
09/25/98
Run Time
1128-1911
1128-1912
1147-1847
1018-1816
1018-1816
1022-1753
1016-1800
1019-1810
1022-1724
1126-1911
1126-1911
1138-1914
1028-1819
1028-1819
1039-1747
1020-1806
1020-1806
1020-1805
1025-1344
1025-1345
1443-1806
1443-1812
1110-1428
1110-1427
1444-1602
No. Of Ovens
Charged
21
21
19
23
23
22
22
22
21
21
21
21
23
23
21
22
22
22
11
11
12
12
8
8
Total Coal
Charged (tons)
316.26
316.26
286.14
346.38
346.38
331.32
331.32
331.32
316.26
316.26
316.26
316.26
346.38
346.38
316.26
331.32
331.32
331.32
168.63
168.63
183.96
183.96
122.64
122.64
Total Coke Pushed
(tons)
257.46
257.46
232.94
281.98
281.98
269.72
269.72
269.72
257.46
257.46
257.46
257.46
281.98
281.98
257.46
269.72
269.72
269.72
134.86
134.86
147.12
147.12
98.08
98.08
The number of coal charged for the last run (A-U-M-5506-1) was 15.33 tons per oven, and the amount of coke
produced was 12.26 tons per oven.
-------
Company Name
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Plant ID
Source/Control Equipment
Date
r
9'
/^
;
'/
7
r
0 '
Start/Stop Time
o
^
&
Point ID #
0
0
o
/
o
7
Evaluation Reg.
O
(o
O
7
O
%
Highest 6 Min. Avg:
2nd:
Min. Exceeding: 20% Opacity =
Direction from Source _,„,
Stack Height
Plume Color
Evaluation Method
Standard Exceeded ?
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Regulation Nbr.
% Opacity =
Distance
ftv Stack Height Rel. to Obs.
^ Background
m Source
ft. Wind Direction
Sky Condition.
Vapor/Steam Plume Visible ?
Plume Detatched ?
Wind Speed
Seconds
Seconds
Seconds
Seconds
Min
0
15
30
45
Min
0
15
30
45
n
0 15 30 45
Min
0
30
4b
C)
15
O
O
30
45
O
O
CJ)
o
16
0
O
31
46
17
0
o
47
£
C
18
33
48
o
O
D
19
o
34
49
O
o
C')
20
CJ
o
35
o
50
21
36
o
o
0
51
22
o
37
o
52
23
0
38
i
53
0
39
54
o
o
40
o
O
55
o
11
26
o
o
O
o
41
o
O
56
12
r?
27
O
42
57
o
/O
13
rO
28
r>
43
58
o
o
14
29
59
SYMBOLS
sun * wind
plume and stack
Results, Recommendations and Comments:
Draw North
Arrow
x-^ji
O
Received By
Date
Observer F
Municipality Code
Time Analysis
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM •
VISIBLE EMISSIONS OBSERVATION REPORT
v Company Name T 4 fc--'
• !/ v
L a
Plant ID #
Source/Control Equipment
fl \,r,r..
£
c?
£?
Point ID #
£>
£>
0
O
7]
[7|
Start/Stop Ti
Evaluation Reg.
£C7 C
Highest 6 Min. Avg:
Min. Exceeding: 20% Opacity =
Evaluation Method
Standard Exceeded ?
Total Minutes Observed
Highest Allowable 6 Min. Avg.
OR
Direction from Sou
rce5r>
Distance from Source
Stack Height / ^^. ft. Stack.Height Rel. to Obs. I Z>LJ ft.x Wind Direction
Plume Color i-'J h: '•& * Background -%•. /•'•"(.* Sky Condition
Regulation Nbr. 000000
Vapor/Steam Plume Visible ? [__)
Plume Detatched ? |_J
Wind Speed
Seconds
Seconds
Seconds
Seconds
Min
0 ^5 30 45
Min
0 15 30 45
n
0^ 15 30 45
n
15
30
4b
15
o
c
30
45
O
CJ
O
P
16
o
o
46
c )
O
o
o
O
17
o
32
47
o
18
o
33
48
CJ
s
19
o
34
49
o
20
35'
50
/o
21
O
o
36
>
51
O
0
'7
o
22
O
r
37
o
52
C.
O
23
38
n
,o
53
24
o
39
O
54
O
10
n
25
o
40
55
11
26
o
L>
41
12
27
o
42
o
n
57
CJ
13
28
43
58
14
44
59
SYMBOLS
sun * wind
plume and stack
North
Arrow
Observer
Results, Recommendations and Comments:
5
Received By
Date
Municipality Code
Time Analysis
ENV-AP-008-Revised 7/97
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Company Name // ""> ^ £ & ^*£f Plant ID#
/ / f *" ' ^ •- ^r X j£*-~^ -X*^X
Source/Control Equipment i^/yc'f^'.-^i^'.^.^'^ 5 s^'&'j'? ^
&
^
&
Point ID #
4?
&-
t-
&
/
7
Date
&
^_z_
Start/Stop Time^
Evaluation Reg.
6
Highest 6 Min. Avg:
Min. Exceeding: 20% Opacity =
Direction from Source j
Stack Height.
Plume Color
OR
A/ Regulation Nbr.
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Standard Exceeded ?
Distance from Source /x *•
ft. Stack Height Rel. to Obs.
Wind Direction
Vapor/Steam Plume Visible ?
Plume Detatched ?
Wind
/
Sky Condition j^V"
Seconds
Seconds
Seconds
Seconds
in
0 15 30 45
Min
0 T5 3lJ
45
Mn
0 15 30 45
Min
0
1b
30
4b
15
30
&
45
O
16
31
46
o
2
17
32
0
47
18
33
48
^
/e?
£>
19
34
0
£*>
49
20
35
O
50
?
21
36
o
C?
c?
51
22
37
52
23
38
n
53
s
24
39
54
10
25
40
?
55
,-T
1
r
26
Cf
&
41
&
o
56
12
27
>
42
*
57
13
28
>
43
o
&
58
14
0
44
r?
t>y
SYMBOLS
sun * wind
plume and stack
Results, Recommendations and Comments:
Draw North
Arrow
Received By
Date
Observer
Municipality Code
•2
f
Time Analysis^
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Company Name
Source/Control
Date
Plant ID #
-,—
^ / (ff
Point ID # \0
olmSEZIE
Evaluation Reg.
0
6
0
A14? , Background '?*/C.'^J
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Regulation Nbr. [HEI1DZEI3
Vapor/Steam Plume Visible ? Q
Plume Detatched?[_j
Sky Condition
Wind Speed
Seconds
Min
0
1
2
3
4
b
tt
'/
5
5
T
T?
13
T4
0
O
(J>
r j
(^
CJ
s
J>
/°
^
CJ
c^
.' ^
<" ^
c^>
c >
( j>
^>
•=>
^
/^
s
^
0^>
.' -^
^>
^
d_>
30
S>
C^>
CJ
c ;
S"
/^
/^
C->
C_J
C_-l
cO
^v
<~J
C_->
45
O
<^>
O
C>
.S
.3
/CJ
/o
( ;
o
L_-J
O
<->
W*
IV
1U
iy
20
21
22
23
24
25
~~2l}
27
TET
Zff
0
/O
r~>
^ ^
CJ
15
O
c±D
O
r-)
02
r">
(O
r ;
^V
45
r~>
o
f^>
r)
if*}
^0
Seconds
MTn
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
0
15
30
45
Seconds
Min
4J>j
46
47
™4"8
-TS
50
... ,5<|
52
' 53
~W
55
56
""57
"58
~59
0
1b
3U
4b
SYMBOLS Results, Recommendations and Comments:
sun * wind -»
plume and stack cq^ ^y ^^
Arrow
Received By.
Date '
Observer.
1
Municipality Code
Time Analysii
ENV-AP-008-Revised 7/97
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Company Name /J./5 <~ C"^-/^^ Plant ID #
Source/Control Equipment
^
c?
&
Point ID #
£•
£>
&
Z?
/
F
Date
&
Start/Stop Time
Evaluation Reg.
7
Evaluation Method
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Highest 6 Min. Avg:
2nd:
Standard Exceeded ? 4s
Regulation Nbr.
Min. Exceeding:
20% Opacity =
O
-£?
OR
% Opacity =
Vapor/Steam Plume Visible ?
Distance from Source
^«&>
Direction from Source J>
Stack Height X^v-P ft. Stack Height Rel. to Obs. ^& ft. Wind Direction
Plume Color Jwfs.re . .^•f-^y Background^ Sky Condition
Plume Detatched 7
Wind Speed *£~-^
Seconds
Mm
0
1
2
3
4
5
6
7
8
y
10
11
12
13
14
0
c?
Q
&
£}
S"
J~
tf
\s
£?
D
f~?
o
c?
(^>
o
15
&
c?
£>
£2
^"
f
JF
3"
€2
O
O
c>
p
^~
c?'
30
c?
£2
/">
c?
,-r
*3*
J&"
^
G?
r?
o
(D
C?
^s^
&
45
£?
£>
£3
jf
,-T
jr
jr
J?~
o
2>
SYMBOLS
sun * wind -»
plume and stack <*^X
Seconds
Mm
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
0
c?
o
n>
f~}
io
^>
Z>
f~>
C?
c?
f"~>
o
€?
£?
&
15
£?
£2
Z>
&
O
c?
£?
^>
c>
£?
/?
£.-?>
s>
/o
f:~>
30
£2*
A
o
£}
O
£?
O
C?
fy
0
&
/">
^ji
C7
<^>
45
£s>
t>
£?
O
C?
£?
c?
O
£?
&
£?
O
£>
s~>
Seconds
Min
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
0
15
30
45
Seconds
Min
45
46
47
48
49
50
51
52
53
54
55
56
57
58
by
0
16
|:
^
30
c>
45
Results, Recommendations and Comments:
— ' PL mrati/KWth "
^^jf4^,
Arrow
Received By
Date
Observer
CKIW AD_nnR-Re\/is*»d 7/97
Municipality Code
Time Ana
-------
Company Name
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Plant ID # | &
Source/Control Equipment
Date
3' .
Start/Stop Time
Evaluation Method
Standard Exceeded ?
Regulation Nbr.
Evaluation Reg.
Highest 6 Min. Avg:
Min. Exceeding: 20% Opacity =
Direction from Source &/*"
Stack Height JW> ft. Stack Height Rel. to Obs. J&£> ft. Wind Direction
Plume Color jf^.^y. Q/irSr Background .5Vfry Sky Condition
OR
% Opacity =
Distance from Source
Total Minutes Observed
Highest Allowable 6 Min. Avg.
DD
Vapor/Steam Plume Visible ?
Plume Detatched ?
Wind Speed j£ *• ./*
SYMBOLS
sun * wind
plume and stack
Results, Recommendations and Comments:
Draw North
Arrow
Received By
Date
Observer
ENV-AP-008-Revised 7/97
Municipality Code
Time Analyse
-------
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Comp
Sou re
Date
Evalu
Highe
lany Name
//<5<
C- . £t&€"
Plant ID #
e/Control Equipment £/M£)££fr//l£ STdtk & <£
£
f
&
ation Reg.
st 6 Min.
0
Avg:
S
&
9
8
o 3_
2nd:
6
Start/Stop Time /e} ',${,1 / It
Q Evaluation Method I
Standard Exceeded ?
&
r>
/>
Point ID #
&
ft
^ Total Minutes Observed
£*• Highest Allowable 6 Min. Avg.
Regulation Nbr.
r;
/>
fa
1
7
O
Min. Exceeding: 20% Opacity =
Direction from Source
Stack Height. **"
Plume Color
OR
% Opacity =
Vapor/Steam Plume Visible ?
Distance from Source
ft. Stack Height Rel. to Obs. £<*> ft Wind Direction VsJ
Background S/sY Sky Condition
Plume Detatched ?
Wind Speed J/"
Seconds
Seconds
Seconds
Seconds
n
0
15
30
45
Min
0
15
30 ^^5
M
0 ^T5^30 45
n
0 15 ^30 45
O
"=
20
(
o
35
50
^
21
36
51
22
37
52
*
23
38
53
24
39
54
10
25
40
55
11
26
41
56
12
27
42
57
13
28
43
58
14
29
c? c?
44 Q
&9 o _o
SYMBOLS
sun * wind
plume and stack
Results, Recommendations and Comments:
Draw North
Arrow
Received By
Date '
Observer
Municipality Code
Time Analysis
-------
Company Name.
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Plant ID #
Source/Control Equipment
Date
4.
XJL2M
Start/Stop Time.
Evaluation Reg.
8
Highest 6 Min. Avg:
Min. Exceeding: 20% Opacity
Evaluation Method
Standard Exceeded ?
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Regulation Nbr.
% Opacity =
Distance from Source ^
Vapor/Steam Plume Visible ?
Direction from Source O _
Stack Height &&> ft. Stack Height Rel. to Obis. Sloo' ft. Wind Direction:; £)
Plume Color U*ti (T£&&m Background
-------
VISIBLE EMISSIONS OBSERVATION REPORT
Company Name
Plant ID #
Source/Control Equipment
Date
4"
0
2 6
Start/Stop Time <7'-tf3^vL - $',tt5
*-**-
Evaluation Reg.
Highest 6 Min. Avg:
Min. Exceeding: 20% Opacity =
Evaluation Method
Standard Exceeded ?
Total Minutes Observed
Highest Allowable 6 Min. Avg.
Regulation Nbr.
OR
% Opacity =
Vapor/Steam Plume Visibfe ?
Direction from Source ^Utitfc Distance from Source "" l^fJU' Plume Detatched ?
Stack Height 2&D ft. Stack Height Rel. to Obs. I'pO ft. Wind Direction Wind Speed
Plume Color
Background faJUu.
Sky Condition
Seconds
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
0
0
0
o
0
n
0
o
o
p
Q
O
c,
1b
O
V
0
0
r>
0
o
o
Q
O
0
o
o
3U
O
O
O
4
^
o
P
o
o
o
0
5
o
5
45
U
n
o
o
o
o
c)
o
o
o
o
£5
O
<=>
SYMBOLS
sun * wind -»
plume and stack s^X
Seconas
Min
15
16
17
1b
19
20
21
22
23
24
25
26
2/
28
u
O
O
IO
<~)
15
3
5
5
o
o
o
o
2* Q
15
O
O
If)
IO
.5
_j>>o
5
"5
Q
f?
o
o
o
O
30
5
o
ID
|5
5
o
3o
ID
£$
O
0
o
ft
o
0
4o
a
o
5
IP
)5
)5
r^
o
a
o
&
o \
o
Seconas
Mm
30
31
32
33
34
35-
36
3/
38
39
40
41
42
0
5'
O
O
o
0
0
O
o
,5
c>
S)
O
o
43 0
I 44I IO
15
o
O
O
o
o
o
o
o
O
0
h
O
(0
30
O
0
o
0
C)
o
o
F>
0
o
o
o
5
JO
45
£)
O
ft
o
6
o
o
o
o
0
O
*=>
}Q
Seconas
Mm
45
46"
41
48
49
50
51
52
53
54
55
58
57
58
59
0
5-
/*>
".3>e>
y«^
3£>
,S?£>
^5-
/5^
if)
Q
Q
fj
n
£>
15
5"
r?^
^?/0
/S~
^?<
^~
3tD
G
IO
)*z
j^cz;
ft
n
n
0
O
o
6
45
5"
PS"
^fj
'35
^>T
ff-
jg
J&
ft
£>
Q
£>
Q
t>
o
Results, Recommendations and Comments:
*/~j /• \
— / -S I --^ nra<«i Kl/trtk
stack
Arrow
observer
Received By
Date
Observer
L
Municipality Code
Time Analysis
ENV-AP-008-Revised 7/97
-------
Company Name.
JEFFERSON COUNTY DEPARTMENT OF HEALTH
ENVIRONMENTAL HEALTH
AIR POLLUTION CONTROL PROGRAM
VISIBLE EMISSIONS OBSERVATION REPORT
Plant ID
Source/Control Equipment
Date
Point ID #
L
_fi.
G
Q
O
O
5?
o
&
30
o
^
-&
o
I<^
^>
^
45
0
0
o
2
o
o
o
-fi.
o
o
o
o
o
o
o
Seconds
Mm
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
0
ft
O
0
6
O
o
9
0
o
6
Q
\
o
0
o
o
SYMBOLS
sun * wind -»
plume and stack eQZC
15
<7
4.
I/
O
0
Q
Q
Q
Q
Q
Q
Q
ti
30
^7
o
0
O
q
$
0
$
Q
O
45
0
9
Q
O
6
o
0*
-%
o
0
9
o
Seconds
Min"
30
31
32
33
34
35
36
F37
38
39
40
41
42
43
44
0
e
o
15
0
&
30
0
O
45
&
Q
Seconds
Min
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
0
15
30
45
Results, Recommendations and Comments:
I a*\ n_.. ki.^i.
Arrow
Observer
Received By
Date '
Municipality Code
Time Analysis
ENV-AP-008-Revised 7/97
-------
Company Name
VISIBLE EMISSIONS OBSERVATION REPORT
CAj
Plant ID #
Source/Control Equipment LjtfVl- b U VfYffTl
Point ID #
Date
Evalu
0
15
o
0
o
o
Q
o
£>
o
o
o
5
^
^
c^
o
30
(9
p
0
a
o
o
o
o
0
o
n
t^
n
s
45
D
0
0
O
o
G
O
o
O
O
t=^
•=7
CJ
Q
SYMBOLS
sun * wind -»
plume and stack Q^X.
Seconds
Mm
1b
16
1/
18
19
20
21
22
23
24
25
26
2/
2B
0
0
^
s
lo
Jo
ID
^
%o
15
o
0
o
0
o
'& 0
15
O
5
5
(0
(0
)D
3(0
3(0
$
O
o
o
o
o
o
30
6
to
10
>$
16
10
)5
)^
o
O
O
i o
n
Q
4o
10
g
s
JO
ac>
)%
20
a^
o
Q
o
o
o
n i D
Seconds
Min
30
31
32
33
34
35-
36
37
38
39
40
41
42
43
44
0
0
o
0
o
5
G
o
o
0
ft
/o
c>
o
(3
5
15
0
o
0
o
o
o
G
0
0
o
£)
o
s"~i
^
^
30
o
f)
o
c;
0
5
O
£>
O
o
o
O
^
•5
45
O
^5
G
o
0
£)
G
^
^
5
o
5
o
^
5 i .5
Seconds
Min
4b
46'
4/
48
49
50
51
52
53
b4
5o
55
57
58
59
0
5
5
c^
,*>
.<=)
^
^
15
/€>
e=j
1=5
5
5
o
G
5
f~>
I
30
6
I&
c^
10
c$
1=)
o
^3
£>
45
g
S
5
5
«=:,
O
c;
^
O
Results, Recommendations and Comments:
—I s*y ( ^-Xnra\A/ KJnrth
stack
^ — Arrow
observer
Received By
Date
Observer
J7^^
^U/L
s~7
ENV-AP-008-Revised 7/97
Municipality Code
Time Analysis
-------
VISIBLE EMISSIONS OBSERVATION REPORT
Company Name AM. //>A& Plant ID #
Snurre/nnntrnl Equipment (^^J^f^^Dyi ^lAAnL- \ Point ID #
D
n
Date
Evalu
0
4
3-
ation Reg.
g
a
$
Start/Stoo Time %\>j?} ' tf'.T^t
Evaluation Method
n
0
o
*>
o
o
o
o
o
6
15
O
o
o
o
o
o
o
o
•=)
o
*)
0
5
o
s
30
0
o
V
f)
o
o
5
f)
*>
o
«7
o
o
*^
o
45
Q
o
(9
o
o
ft
ft
^
f)
o
^
r>
0
^
0
Seconds
Mm
0
M>\ $
16| o
17
18
19
20
21
22
23
24
25
26
2i
28
0
*i
*=)
\**>
.«>
5
O
O
O
o
o
o
^9 ^
SYMBOLS
sun * wind -> j
plume and stack o^^.
stack > *(
15
5
0
O
^
s
^
*)
(~)
0
o
o
Q
0
&
o
30
5
o
0
$
^
y
Seconds
Mm
30
31
32
33
34
35'
36
37
38
39
40
41
42
0
0
O
O
o
o
o
o
o
o
*)
?=>
rt
0
43 5
I 44I 5
15
o
o
c>
o
r>
o
o
0
o
r>
^
5
f?
^
o
30
O
O
0
o
D
n
O
f?
o
O
O
o
0
*>
45
O
d
o
o
t>
o
0
/">
,5
O
3
,5
c>
r?P
/^
,*=T
O
^
^
«0
0
£>
30
p
,-s
*
n
5-
^
/,o
^
o
,*>
^>
f-^Draw North
^-* Arrow
5
Aj
observer
Received By
Date
Observer
\K. /Alfi
Municipality Code
Time Analysis
ENV-AP-008-Revised 7/97
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL
Time
b:w
n;rt
Oven ID
H1
57
Capture Emissions Observations
J ^ CdiLU^C)
~Tfrt rifliAA 4ft i-t JLL.^
Travel Emissions Observations
. btruj 1 dJLUL^^>
Pa8e -2. of
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL
Time
Oven ID
Capture Emissions Observations
Travel Emissions Observations
uaaf.
Jl'.fr
II
31
3
37
33
!<•
15
L-cn^O
4:2$
=f
h^l
7
5-. 52
n
f_4^ O4JLJL4*
3-7
Jitru)
Page / of
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL,
Time
Oven ID
Capture Emissions Observations
Travel Emissions Observations
5*.
Date:
t
Page £*_ of
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL
Time
Oven ID
Capture Emissions Observations
Travel Emissions Observations
MID
I'
n
t '
/i
^Aj^^-^i-
tr
f^
n
n
U
4;
J3
'. -\-
QUU\
3- 33.
33
3 '-
5~
3-56
n* A
35"
JLeru)
Date:
Page / of.
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL
Time
Oven ID
Capture Emissions Observations
Travel Emissions Observations
35
is 102
55
i
Date:
Page <>doF
-------
PUSHING PARAMETERS - CAPTURE OBSERVATIONS: ALABAMA BY-PRODUCT COKE, BIRMINGHAM, AL
Time
Oven ID
Capture Emissions Observations
Travel Emissions Observations
JD: 33
au
)b: 53
QA Q
13bcn
. btru)
ki /
JiOAf^
L^.
II- 51
„
\ ;
II
) ',20
-f-
£'51
L>
1
/3
I'
ol
-J-2.
2—%
J
IS
U
^—r
Page / of_c»Z.
-------
APPENDIX B
RAW FIELD DATA
-------
h
?a*
TRAVERSE POINT LOCATION FOR RECTANGULAR DLJ
Plant: _
Date: _
Sampling Location:.
Duct Width, inches:.
Inside of Far Wail to Outside of Nipple:.
? Inside of Near Wall to Outside of Nipple (Nipple Length):
Duct Length, inches:
//
Equivalent Diameter = 2xLxW/(L + W)=
Distance Downstream from Flow Disturbance (Distance B):
fa 3cc" B^ T&H " jncne8 y Equiva|ent Diameter = fc/f.b dd
Distance Upstream from Flow Disturbance (Distance A):
t*~- 70'k" B-^'4" inches / Equivalent Diameter = /.'/fl.12 dd
Calculated By:
Schematic of
Sampling Location
Traverse
Point
Number
i
2,
•v
¥
6
Fraction
of
Length
(9<(
f)'t
O/*
on
n.<\
Length
(inches)
#Z&^
Y^.^
/
/
i
Product of
Columns 2 & 3*
(To nearest 1/8")
Y, **
(t,*f
W,l$
W.W
H-h ^
Nipple
Length
(inches)
^"
1
V
i
Traverse Point
Location
(Sum of Col. 4 & 5)
2^
17, *$
27. 2>*
K 9*
VCe,(a $
If No Ports, Calculate Distances From Stack Walls For Port Locations
Number
of
Ports
Fraction
of
Width
Width
(inches)
Port Location
Product of Col. 2 & 3*
(To Nearest 1/8")
* All points or ports should be an equal distance from each other (D) and 1/2 of
~that distance from the stack walls (D/2), where D = Width / # of points or ports
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant- f\^£, Car-e> Date: T--3^--72>
Sampling Lo
Run#: Oy<
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travaraa
Point
Numbar
A. ^
1.
^
H
_5?
B '
z.
3,
y
^
^^ static Pressure, in. I-UO: -~-S". 9
Molecular wt.. Drv: Z8- Pitot Tube. CD: • fr*
sion, in. Diameter or Sid<
': Dry E
Anofo £>,r«/;^
Velocity
Haad
H
H
^
~s
C
o
0
L)
^
g
^
^
^i
^
^
J-?
£
C?
t?
&
^
^ST
^
^
. £>
^P -
* ^ Stack
°Ps> -f£
C.t^—
^.^l^
w ^ ft ***
^^^
^ ^
^ C-v
^ ,^-
^ ^^
S c^
* ^
S i~
*- <^
^ t^s
V^^-
3ulbtOF: '
Md = (0.44 x %CO2) + (0.32 X %O2) + (0.28 X %r^)
Md - (0.44 x ) + (0.32 X ) + (0.28 X )
Md -
% HO % HO
M« v M/-4 v M ^xIR/ \
1 00 1 00
Te- °F- °R (°F f 460)
13.8 ' ' 13.8
Pa - in. Hg
£? =
/ Ts <°R)
u Ps X MS
1 M I ^
Va- ft/a
A.- ft2
Qa - VaxAax60a/m
Qa - x x60
Qa • adm
Pa *H,0
O*-rf=« Qa x 17.847 x x (1 • — *— )
•" Te 100
Q*^^* « 17.647 X X ( 1 - )
•td 100
-------
, 1.05*5
*" ' V A"V ; o
? /
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: #BC CoKe, Date: ^-,20-92
Sampling Lo
Run#: ^
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Tr«v*rs«
Point
Numb«r
A /
Z
3
H
5
8 I
2.
3
V
5
£. )
2
3
-v
5
D i
2.
3
V
5
£ )
Z.
3
4
£>
cation: B
(.WV.&KV/ "" Ooerators: ~r^hbJ(yCr
ressure, in. F
s
^q: 'Z'A.biH Static Pressure, in. hUO: ^9
Molecular wt.. Drv: Pitot Tube. Co: -^V
sion, in. Diameter or Sid<
: Drvf
Vtloctty
In. H2O
^."7
•2- V
^-Z
2.j5"
2.0
^../
/. f
A "7
A-5"
;._£•
/ ."7
y. 5
)• -2
y, /
I/O
£•/
r^
/.(<,
/i6?
/- U?
•2.2.
^.3
2-2,
l.l
•Z-O
^F -/i53
Stack
T«mp.
°F
nb
/7Z
/^
/at
Mo
31: %. 5 Side 2: *tt* S
3ulb.°F:
Md - (0.44 x %COo) + (0.32 x %O2) + (0.28 x %NU) • .. _
» ,i.-^yRvv
Md - (0.44 x ) -I- (0.32 X ) -I- (0.26 X )
% H,0 % HO
MB • MH v (1 . ^ + 1R 1 . „ . ^
100 100
• -( )X(1 - 10Q + 18( 1QO )
16
Ta- /"7^ °F- °R(°F-t-460)
Pa - Pb + S'P' - ( ) + ^ ,^-
13.8 ' 13.6
Pa - v) •) 1 in. Hg
^ VSF= /^^
= J Ts (°R)
v.-«b.4y«Cux^Px ^ P3XM8
V/f,-B«J49»( )si( )XAJ ' -"" "-
Vt " *&n *l ft/a
At - "^ 2 . S ft2
Qt - Va x As x 60 a/m
Qt - x xOO
Qt» /6?56oC acfm
Qt . .= Ot x 1 7.647 x x (1 • —-2— )
•" Tt 100
ttd X * 100
dtefm
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Proiect:
Date/Time:
Sample Type:
Ambient Temp. °F
4/tt/fg
Orsat No.
Operator:
Comments:
Site Location:
o-i
aw
&**S*»t -^
Run No.(s)
fr*
lfH-1
£
Gas
•
C02
02'
CO"
N2°
Run 1
Actual
Oft
fa*
Net
o.W
to.$
Run 2
Actual
0.1^
2o.4
Net
0.*>
2o.3
Run 3
Actual
Net
Average
Net
Volume
%
0,1
^o.2>
Multiplier
0.44
0.32
0.28
0.28
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
A*"?' '
V
Gas
CO,
02'
CO"
NZC
Run 1
Actual
O.to
w{
Net
0.1*
m
Run 2
Actual
^. 2^
JZ*/
Net
O.ZJO
fat
Run 3
Actual
Net
Average
Net
Volume
%
0.2.
2.6.2-
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
•
C02
02'
CO"
N2°
Ru
Actual
n 1
Net
Ru
Actual
n2
Net
Ru
Actual
i3
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Md =
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
* 02 Net Volume is 02 actual reading minus CO2 actual reading.
" CO Net Volume is CO actual reading minus O2 actual reading.
c N2 Net Volume is 100 minus CO actual reading.
O»AC*IC EHvmoHMwiAL >emccn INC.
-------
Pacific Environmental Services, Inc.
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Dry Molecular Weight Determination
Orsat No. O ~ /
Operator.
Comments:
Site Location:
Run No.(s)
intt
a
fa?
m
C02
02'
CO"
N2°
Run 1
Actual
£>. 2
20. f
Net
°'l
30.3
Run 2
Actual
#2
2a<
Net
0.1.
36.-^
Run 3
Actual
Net
Average
Net
Volume
%
0,2
2D->
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s) Gas
Run 1
Actual
COj
0.2
Net
O-l
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
o/z
Multiplier
0.44
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
o/
. .2
0.32
CO"
0.28
0.28
Md =
Run No.(s)
Gas
C02
Oa1
CO"
N2C
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.26
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
' 02 Net Volume is 02 actual reading minus CO2 actual reading.
e CO Net Volume is CO actual reading minus O2 actual reading.
c N2 Net Volume is 100 minus CO actual reading.
'ACVICtMVlllONUaiTALieRVICtKINC.
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
OrsatNo. 6—!._
Operator:
Comments:
Site Location:
TrV
Ba»li/>.i
Run No.(s)
f>-Z-
124-3
fel
Gas
•
C02
02'
CO"
N2<
Run 1
Actual
0^
iL6 ^
Net
G-^
20.2-
Run 2
Actual
6-2.
20- V
Net
0. 2-~
20>2_
Run3
Actual
Net
Average
Net
Volume
%
O-2-
%>.i-
Multiplier
0.44
0.32
0.2S
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
(V.I'
H^-3
%*
Gas
•
CO2
Oj1
CO"
N2e
Run 1
Actual
0.2-
20.5
Net
O.Z,
lf>.2>
Run 2
Actual
O.I
X).5
Net
O.L,
20-3
Run 3
Actual
Net
Average
Net
Volume
%
0-1-
20.3
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
C02
-------
a
I
1
(
I
1 "\. ^. fl _
r*/"l G>
;/6'7 >c
iO
/2-'i :>c?
Lp
li-17 'LO
^$2- 1O
so
/>e
//J
i6£
;.C
Jt>
;«D
llo
*J&
22D
%2£>
JLSO
-i-70
Pfc>
•^ftO
3eo
3ic>
J>U3
?
slant: /fee
Date. '*?--
_ocation: 73<
Run #: A
Stack I.D.:
•^L^-.-. O^3
-'oar. -i"-
3amp!e Tube
Dperators:
_eak Check:
Time
— .
—
. . — —
_ .. — - -
~
V^vl
^^ravfrsd
Point
Nurno^r
/^S .'S(b
_/t>^s
:C* if*.
]*I2>3
j
lLDl-2>
2^5"
2£^'6"
-X ] ; z.
.i.! 50
2-1 71
^./0"7
•2/2- 3da
2^5~7
•72 ?^
X3> /-^
^"355
tj^'7
I2r\)^1
1^ 45
i^0<7
7.6^0
f
- Cft^^L £
-^ X> —
?O ""^T c|' >
tc 6erf*_ ^
*$' S K. -Vf.
"~7/N
/o
*#\4-X--l 1
Jl / C^k
' n~ /\So
Pte: ' i^^ F
A) /7"^
Gauge
Vacuum
(Hg)
. — ~-~~
--- --
— — •
Vet£-
>\V«loeity
^/
'V
*-/
'-i
hf
ty
^
/y
*i
*~!
*-j
*-,'
<-/
f-/
4
+1
-7
~\
7
7
7
^'
^
°(
q
METHOD 18
?PA
7 1 /I— y^S~^
' I ' */P> uVL<
^>Lrf
- /
£
1 /? C
Dost: ^
;•€" A '
Flow
Setting
^
1 — -^.
— -
— — _
/iC^i~
i^mp.
-z.
-z.
2^
^
T_
?
"2.
•2-
•f
Z
"Z_
7,
—>
'"2-
2_
-L-
^2
1
*'£=-
2^
-2__
2
X
2
-z
FIELD DATA SHEET
Tested Analyte: /^/V
Orifice Tank #: ^
Pump/Rotometer #: t/<5S7" */
Pf Pretest (mm Hg): /-y " Mj
Post-Test fmm Hq): /^" ^<
Tt: Pretest i R: - —
Post-Test |°R: -<•
Time: Start: — Finish: — Total:- —
W/B: ^D/B: — O«: — CO«:
X
Md = (0.44 x %CO2) + (0.32 x %O2) -r (0.28 x "/oN^
Md =
Ms = Md x(1 • ) -r 18 ( )
100 100
^
1 00 1 00
Ms =
Ts - °F = °R (°F * 460)
"7> _ pu ^ S.P. ,
13.6 13.6
Ps = in. Hg
S"'2- JAP =
?•< ,.._ .
§U = I Ts(°R)
^ Vs 0b.4»xCpXVA y PsxMs
*?2
^3 v, »A«;A9x( )»( )*•»/ ._ .
••v V
Vs • ft/s
47 2
9-7 A» " ft
^
i(j5" Qs » Vs x As x 60 s/m
3'3>
W Qs - x x 60
^
>*/ Qs » acfm
'^ Ps % H-0
^v Qs ..= Q«x 17.647 x x(1- =— )
8td T. inn
^G?
AO std ' 1QO
i ' ^rtd* a di?''TI_J, /v/s o Q Q
-------
METHOD 18 FIELD DATA SHEET
[
I
f
i
1
i
(
I
;*-K_£
/o a z-
-to-4-t •iA
n £«- ^
//z-1- ^c
;/56 9C
/od
A33 /i6>
,«o
t&
'*e>
2eo
TLTJ3
•24'0
2&0
J«6
3£p
'~bW
™%
'3&>
753 ^
!)ate- Qr-ZZ-IZ Orifice Tank #:
nratinn- /5<*^<:^0 3V
T>c>'/7
:-v 3,0
3^7 6>
liJ.y/
•225^
3209
33 32-
1)21 1
V//D
Ti1^
^ ^- Qs « Vs x As x 60 s/m
//3
lit, Q« * x x60
ti2.
t/7 Qs - acfm
/"3 Ps % H_O
//2, Q»8td=Qsx17.647x — x<1.-^-)
Q.9td= x 17.847 x x(1- 1M )
0»8td" dsefm
-------
METHOD 18 FIELD DATA SHEET
F
[
L
F
c
F
c
(
L
u
p-^
Tirti-e.
in 7 •?
1047.2
/AQ-Z, i£.
, l -L. li Tq/LC
7°R» s>
•utjTtoS
=lant: ^ IV. -
Date: " (0 4
^Z~i3 1
360 7. -7
3. fr&d,. S
^ -j |£> ^
*£**T
~\—>cr7- i d
i"7P^ /f
"^/^ ?cT j
7 /»-? ^ . .7
^94 ft/ J.
9M/7 1
^Whs~. 9
*ytox c"*^
*y ^) ^ <*. /
*/ / /^ y. f
V/. 'Jf.fjf
r^k^. E-
*-?#
fj Af'^ "T^;
t- S^Ob-_
6. 5 " *- y^1.
*:A -"f-^5
ofTA
P're: ^ F
/7" h^.
Gauge
Vacuum
(Hg)
/ y
' /
/
/
f
/
/
/
^ as
JJiT
H
f
c
"5"
/o
(j
U3
La
-
—
(a
to
il
(a
H
K
o
p
7
j^A
Is-t
I
£""
'«., -i/i/6 f
'
ost: •«*£*
Flow
Setting
/ y
/
/
/
/
[_
&et
j£%^^
a
^
^j
j>
^
&
Si
A
^
'Ti-r
a_
—
— •
-z.
j.
X
1^
A
^
3^.
Sv
J
Tested Analyte: rft f] -
Orifice Tank #:
Pump/Rotometer #:. fd-s^ /
Pt- Pretest (mm Hg): ~
Post-Test (mm Hg): —
Tt- Pretest (°R: -
Post-Test f F)1- ~~
Time: Start: — Finish: — Total: —
W/B: — D/B: - O«: — CO«: -^
Md = (0.44 x %CO2) -t- (0.32 x %O2) -t- (0.28 x%Nj)
Md =
o/ u n % H n
Ma ~ Md x ( 1 - ) ^ 1 8 ( • ... )
100 100
Ms = ( )x(1- ) t- 18 ( )
100 100
Ms =
Ts- °F- °R(°F*460)
I'M n. pi. . S.P. . .
13.6 13.6
Ps = in. Hq
I 3-
$8 ftp =
W I T ft*
' ' — I Ts (°R)
10 A. /
1 / I
lot\ Vs • 85.49 x( )x( ) x -11 . _
\j
/o ~7 '
lO'j Vs » ft/s
AS » n
|OT
Qs » Vs x As x 60 s/m
1 « 1
/ j 7 Qs • x x 60
i/S"
. t ^ Qa • acfrn
7/5* Ps %H2°
/y«a Qs ..= Qs xi 7.647 x x(i- =— )
' ' i sto T. ino
>l^ Q (1 )
//~7 >8td x 100
Qsg^^w dscfm
-------
a
(
t
1
i
(
t
•
METHOD 1 8 FIELD DATA SHEET
slant- Aftc-covc* TesteH Analyte- XTFj/ X/^k eeVA
Date: ^ - i«.
ocatiorr Oo^
~ix Orifice Tank ^- AO|^
L^.V*^ 3 ^v^-4 PumD/Pntnmeter #\ \Iv^\ $c** 1
=Iun#' A-X°- rOifo-b^ F'fe Pf PretPQt (mm Hg)- f^> * -»/V*ee»
Stack I.D.:
=bar: tf\.P>6
Sample Tube #
Dperators: Vs .
_eak Check: Pr«
Time
/4.' 30
Traverse
Point
Number
V
-
Post-Test (mm Hg) : v i 5 -c
-------
1 o
,•>•*(
Plant
•Y Sampling Location
FIELD DA i A SHEET
Sample Type: rV\2>/S Operator. 7~/f/^& Nozzle ID: .» / 7 j£ Thermocouple #: S~£=-
&
Run Number: 4-jT-/w>-JDate: ^-2.
Pretest Leak Rate: tooj> cfm @ /jfT
Pretest Leak Check: Pitot: _l£/f Orsat:
Pbar
C02:
.Ps:.
O2:
~5. 9
in. Hg.
Probe Length/Type:
Stack Diameter:
fj Pitot #: S"j£
As: 37. 5
Assumed Bws: 3& Filter #:
Meter Box #: 3 Y: /.ocy AH@:
Post-Test Leak Rate: /OQ-^ cfm @ /Q in. Hg.
Post-Tesl Leak Check: Pitot: / _^ Orsat: -—
Traversa
Point
Number
Sampling
• Tim*
(mln)
QockTima
(24-hour
dock)
nm
Gas Meter
Reading
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg^
-Z-8T
2,
2-5-2-
GO
. /o
0./2
2-O
^26
2.0
/.-T
(t-7
ta
2,*
2JSO
^L
III,
I'f
^l^L
/<>&
sol
HO
/ .3-
/ 2-
o OS
a -0
c-cs
'J±.
.5V
/
Z/^_
TT
t'C,
r't,
MS
7-.-50
//z.
!2iL
1-1
^Z.
±L
/Wm-
ho
M
23
146
"7
Ml
-------
Page
of 3
Plant Name:
Run Number:
- r~ AH - /
Test Date: _
Operator:
3. JO. •/
ZW.Z
Traverse
Point
Number
Sampling
Time,
(min
ing /
e, /
.) /
dock Time
(24-hour
clock)
Gas Meier
Reading
Velocity
Head £ P,)
iiLlhO
Orifice Pres. Differential
Desired
Actual
Stack
Temp. • F
Probe
Temp./ Filter
Temp." F
Impinger
Temp.
•F
Dry Gas Meter Temp.
Inlel
UUIICl
Pump
Vacuum
In. llg
7&
/.O
in
J iV
AC
in
eSf 1 i
"7
It"-/
lu,
0-03
a.o"?
/at
23O4 1
J
/£#
0.05"
a
//o
' &J
f
Si /
t n
s/o
t s /
0.03
O.06
2LL
^SL
<" y
*LL
A 5-
3V
I/S
-303
- -2
COS
0-06
//L
3/7
.63,
PC,
W.
tf A3
-------
Page
of
Plant Name:
Run Number:
Test Date: ___JL^L=3LL
Operator: ~7#/SB
Traverse
Point
Number
Sampling /dock Time
Time, / (24 -hour
(min.) / clock)
Ga$ Meier
Reading
Velocity
Header,)
in.lhO
Orifice Pics. DiKctcntial
(All) In. 11,0
Desired
Actual
Stack
Temp. • F
m
Probe
Temp./ Filler
Temp.' F
Impingcr
Temp.
•F
Dry Oas Meter Temp.
Inlet
Uullcl
Pump
Vacuum
In. ilg
O./
1L
ILL
Z5z
ity
,0,1
&L£
/ '
Of/
f/C,
1L5L
ft-
35 °l I 1-730
1.5
//c.
tf7
//JS
,5
/(x
t<3
A-3-3
1 /80ft
dos
O.OL,
hi
f'3
Ml '
[,•72,0
. 0,5
5-2.
/f?
6-73.3
/,
//f
1 /$/<*
//
f
i
1/75
O.O.-S-
96
00%
25V ' 25-2.
£L
f
1I&
O.O6
9*
O.ot
tl
9-7
2
1 1
/ X*//
At
2*
3L
-------
smi
n
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
DPACinC ENVIRONMENTAL SERVICES, INC
Sampling Location: J.*- g-T
Sample Train Recovery Data
f fiL
Of
Date:
Sample Recovery Person:.
Sampling Method Type:1
Run Number:
Job Number:
H '3 }
. Field Team Leader:
,,
jl - \
Impinger Train ID
: A/"C
5^0 .5* 0 ft n
Comments:
>/? /€ f
Filter No.:
~3 Q
Front Half Data
Filter Media Tvoe: 7~rCcx.Teei
Filter Description: A/ea.i/y
Filter No.: •
Filter Description:,
Filter Media Type:
Impinger Purge-
Start Time:
Flow Rate:
Bick Half Data
Stop Time:.
Purge Gas:.
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):.
Description of Impinger catch:.
Impinger 1
Impinger 4
,5/e^nfe.^: ^
Impiner 2
Impinger 5
Impinger 3
.
Silica Gel
5; \ £
(9):_
to>: 31 ..7
<-Jl~
-------
FIELL>DAiASHEET
Plant: ^ffl A
Sampling Location
Run Number: A-T-
Sample Type:
Pbar
CO2:
/
/ 5 Operator:
Ps: ~^-
O2:
Nozzle ID: ,
Thermocouple #:
Filter #: OgQgq?- CT[
Pretest Leak Rate: . QQ/ dm @ /S in. Hg.
Pretest Leak Check: Pitot: I/ Orsat: —
Probe Length/Type:
Stack Diameter: %
Pitot #:
Assumed Bws: ^
Meter Box #: 3 Y: ;.cc.yAH@: /. 7
£ Post-Test Leak Rate: t(^o/ cfm @ /& in. Hg.
Post-Test Leak Check: Pitot: ^x^ Orsat: —-
Number
Sampling
Time
(min)
QockTime
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Stack
Temp.
(Ts)
Temperature
°F
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
/O?
Pump
Vacuum
fm. Hg)
,03
C-z-
S't
2*5
00
HZ
F/fA/
/.
A^L
^
•2.^-0
.02
.03
/'T
CLS&
/ >^7
/oo
.-77
2^-0
oo
(3V
JZ-33
,03
,03
3 7
,0-3
^01
,**
Z5&
^OJ_
y
•03
c?
AO
,<*<>
/"73
/oc,
^1L
-t
•63
/O/
AH=
Ts=
tis=_ir>
-------
Plant Name:
Run Number:
ft -T-
- Z
Test Date:
Operator:
Page 2- of 3
9-2Z-??
Mr
Traverse
Point
Number
Sampling / dock Time
Time, / (24-hour
(mm.) / clock)
Gas Meier
Reading
Velocity
lleaJ^P,
ilLlljO
Orifice Pic*. Differential
(All) In. 11,0
Deal red
Actual
Slack
Temp. • F
m
Piobe
Temp. / Filler
Temp." F
Impingcr
Temp.
•F
Dry Gas Meter Temp.
Inet
Uiillcl
Pump
Vacuum
In llg
A2.
Lo
ix--
.03
•730,
/-7V
2 So '
A f
'^3/257
-5-y
ft?-
Z.
75V. ? 77
,03,
hi
f/S
7
766- >
1.-)
.OJ
us
1.5
A 5
'2/1
1/7
/•S
AS
/• -5"
267
03
.01
2*7
234 /
7/752,2
l.s
J.5
Zoc,
A5^L
-Oj
ZSO '
/t.5-7
755".^
273 /
.63
52.
22^.
y
1 ,£57
750 ^3
/
•7/V,
Z2&
I is/
,03
25^
.an
/.T
I-1'
5-7
-------
Page
of 3
Plant Name:
Run Number:
A-
- *» 3/ ff -
Test Date:
Operator:
Traverse
Poinl
Number
Sampling /dockTime
Time, / (24-hour
iJL
(mln.)
clock)
Oat Meter
Reading
Velocity
lca
377
/5
225
/o -7
7^3.7
/Of
/o
03
X
/ 3
/ 3
,o~7
SQl
sz,
/<*?-
so-?
^
-------
D PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant: A 6 ^ (C^ /AP.
I"1 ^r^ /^ J
^= Date
, 7/zi
Sampling Location: Is/I l& 1
f f
Sample Recovery Person:
Sampling Method Type:
Run Number: ^
Job Number:
Field Team Leader:
Comments:
. Impinger Train ID:_
J5"7)
le.t'
"3
IS~ A-AA-y?
Filter No.:
~O"~1
Front Half Data
Filter Media Type:
Impinger Purge-
Start Time:
Flow Rate:
Back Half Data
Stop Time:_
/CUffr
Filter Description: k ~ K -{>*>
Filter Media Tvoe: •
'A &• & I* C'U— j9& f Tit. u \c.h\
Purge Gas:.
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
ImpingeM
Impinger 4
Impinger 2
. fc.
Impinger 5
Impinger 3
Silica Gel
(9):.
(9):.
-------
A K -
Plant:
Sampling Location
Run Number: ft-i-
)e/-
FIELD DA i A SHEET
Sample Type: rnAiS— Operator: <>
- ^Date: r>3_ cfm @ |5 in. Hg.
Pretest Leak Check: Pttot: ./"Great:
Probe LengbVType:
Stack Diameter: te.
01j Pitot #:
As:
Nozzle ID: f ffi JL Thermocouple #: £ £
Assumed Bws: jya Filter #:
Meter Box #: mfl^ Y: I .oo*j AH@:
Post-Test Leak Rate: ,QQ) cfm @^>jn. Hg
Post-Test Leak Check: Prtot: L^- Orsat: ^
Traverse
Point
Number
Sampbifl
Tim*
(mln)
aockTime
(24-hour
dock)
Gas Meier
Reading
(Vm)ft3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
fTs)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
"80Q.
_ol
ML
IOO
J_u_
.10-
loo
fV-
.01
111
loS"
(O/
/P i
n
la O
tox
2JJL.
gofi.
A
.0)
tn
£,0
F
f
F
F
P
9
F
p
(,1
iO-
^oL
^oL
L^o_
log
iii^:
^i
lot
IMQ
,/T/
1/5
£
(l-fO
o
LI
ZtB
-z. 41
/id-
/li-
ft 20. I
.of
241
in
|0 O
. 0
/
**-,
/So
Jn
mo
J_Lk
-Ji
X2J1
jjt)
uv
_ioj
_Ifi_
ill
. 0
(O/
132-
JO O
Qil.
/ OQ
_M2_
11
0
O
lot,
.e1"
. /
J^k.
LC.
^z.
I^a.
loO
(OCc
^U.
-&T
AVm«
T5-
-------
of
Plant Name:
Run Number:
Test Date: _
Operator:
Traverse
Point
Number
Sampling
Time,
(min.)
/
/
/
dock Time
(24-hour
clock)
Gas Meier
Reading
Velocity
Header,
itulljO
Orifice Prcs. Diffeiential
(All) in. 11,0
Desired
Actual
Slack
Temp. • F
Probe
Temp./ Filter
Temp* F
Impinger
Temp.
•F
Diy Oaa Meter Temp.
inlet
UUIICl
Pump
Vacuum
.8
Zo
8
' -355
ML
?
X|A
-------
Page •? of 3
Plant Name: fiw.r«l* E~M Test Date:
/ / flw i f> £.& *~~ r i i
f
£
f
P
Run!
Traverse
Point
Number
/K~ ^
At- ^
/qi -^
A/- 3
A/-4
A I C~
lumber: ft - ~L- m?i£- 1 O
Sampling /dock Time
Time, / (24 -hour
(min.) / clock)
4 3 J ' /60V*
^3? / f^2f
'•^^O ' /fc-ZS
3<^^p / ju?^
-2>"g / /£,0!"t * /Jao
1 --S
4-2>5 'fB^o
/
/
/
/
/
/
/
/
/
/
/
/
Gas Meter
Reading
#77-6
*?O J ^
fo? ^"
^^. t?
^6^,<^
7/y; o
^7^". //
^/6. ^
tyy.ji*
110.0
^.
qj^T^i^c,
Velocity
llead£P,)
in.lhO
, «? /
J.o
• a/
3 J
,0 (
3*2"
Orifice Pies. Differential
(All) In. 11,0
Desired
,0 /
3.L-I
,ot
3.*? .
3 .(f>
. o/
2.° '
,of •
3-1
tf
T-v"?
X
~ •.
Actual
. o/
^ .«-/
. o /
P 9
- of
?.o
, o/
pi c>
. O/
•D ~]
1-7
Slack
Temp. • F
lo^l
/ /o
/o 3
IB °
/n6
tfZ'
JD(S
/f c>
/og
/o "Z-
(<=>!
perator:
Probe
Temp./ Filler
Temp.' F
o??/ ' ^T£>
^3/ / ^^ /
•*) "7 s-\ 1 OJ3^3
(7- ^w* /7^^ r
^
^0
S~8
&o
, &
t>0
&o
J??f
Go
Dry Gas Meter Temp.
Inlet
//v
//*/
7/5"
//r
//o
fflj
i if
//v
//«/
# 3
mt^A
\( ~b>
Uullcl
///
/Sl-
it)
H-2
((•*-
//3
f /^_
/ / "u
//5L,
(fl-<
ISf^
I 1 1_
Pump
Vacuum
In.llg
/
O
/
If
(
%
t
fC
I
$
$±4
r
i
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
O PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Samplina Location: ^Z-^x?
Sample Recovery Person:
Sampling Method Type: A
Run Number: £\ O •**
Job Number: s *5O 55
i& *f~~
£\*>l i _
fr-r ^
/^- 2~3/g'-'3>
&OC3
< '
Field Team Leader /-> _5
Impinqer Train ID: //I/ ~~ /
Comments: ^T^llf^-T r~^- € 1 ^dd £-* /_5>
"S?\/rl0ie P £{c^L vi*^{sir>,f< 0qf T~i <:&
Filter No.r _ Filter Media Type: "
Filter Description:
&.
Impinger Purge-
Start Time:
Back Half Data
Flow Rate:
"Stop Time:_
^_ Purge Gas:.
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
Impinger 1
Impinger 4
Impinger 2
1. 7
Impinger 5
ger
rr
Impinger 3
Silica Gel
(9):_
(9):.
(g):.
V
\*
-------
£l S c. -
Plant:
Sampling Location
Run Number: ft-z-^/s-FfePate:
Pretest Leak Rateffic^^ago cfm
/^\ l~i-iir*~
Pretest Leak Cr
FIELD DA IA SHEET
? /S Operator:
-<=v S>
Sample Type:
Pbar: gp
CO2: —•
Ps:
O2:
Nozzle ID:
Assumed Bws:
Meter Box #:
^_Thermocouple #: A-3
3_ Filter #:
Y:
- /O
Probe LengbYType:
Stack Diameter: /^
As:
/J/A
. oo J-
Post-Test Leak Rate
Post-Test Leak Check: Pilot:
AH@: /. ~i8
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
O PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Plant:
Dae:
Sampling Location:.
Sample Recovery Person:
Sampling Method Type:
Run Number:.
Job Number:
Ue>u.$,£
f7
Field Team Leader:
. Impinger Train ID: A/
Comments:
£ r le
Filter No.:
Filter Description:
Filter No.:
Filter Description: ^
Front Half Data
Filter Media Type:
Filter Media Type:
Impinger Purge-
Start Time:_y^V_ Flow
Back Half Data
Stop Time:_
Purge Gas:_
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:
<) i
Impinger 1
O
Impinger 4
O
o
Impinger 5
Impinger 3
0
Silica Gel
(9):.
(9):.
-------
FIELD DATA SHEET
a c co
Plant: _
Sampling Location ? *v/, f T
Run Number: AT I -^-y Date: ?* M?
Pretest Leak Rate: j Or> ^ cfm @ /5 in. Hg.
Pretest Leak Check: Pitot: M
Meter Box #: Z, Y: /.ool AH@: I. 7 f 7
Post-Test Leak Rate: ,0^-^cfm @]Q_ in. Hg.
Post-Test Leak Check: Pilot: t^ Orsat:
-------
Page
of
Plant Name:
Run Number:
Test Date: _.
Operator: _
Traverse
Point
Number
Sampling /dockTime
Time, / (24-hour
fmin.) / clock)
Gas Meier
Reading
Velocity
I lead ^P,
in-lhO
Orifice Pics. Differential
Desired
Actual
Slack
Temp. • F
m
Probe
Temp./ Filler
Temp.' F
Impinger
Temp.
•F
Dry Gas Meter Temp.
inet
Uullcl
Pump
Vacuum
In. llg
1401
CO
1C 0
T7
Z-
/ (Ho
i-V
-ex
' UfL
.Tft fc
' 1413
.Of
etc,
Tfo.D
7-T-
0 o
lo-x
' 14-24-
l.tf.
5-
Sl^.Ool
1-L
1.0
to 4
10 \_
8
5 \
'0
.b!
1 bo
0 ?
-rtf
104
5-7
'
IT
JT-?
fb
' \4-39
/C 1
'
\,<>
10 /
•*"*
\447_
,0
•01
s
•T5
f
lol-
•l
. Ok
U
r
3±
i.
\
O
/ WM
-------
Page
of
Plant Name:
Run Number:
r\
Test Date: JL:1L1L_..
Operator:
Traverse
Point
Number
Sampling / Qock Time
Time. / (24-hour
(min.) / clock)
Oas Meter
Reading
Velocity
1 lead^P.)
IlLlllO
Orifice Pics. Dillerenlial
In. 11,0
Desired
Actual
Slack
Temp. • F
Jli
Probe
Temp./ Filler
Temp* F
Impinge r
Temp.
•F
Dry Oaa Meier Temp.
Inlet
Uullcl
Pump
Vacuum
In.llg
CoJT
•"T^-M
-O
J-J-
*JL
r
F
3
3-0
1 1553
-o
.0 t
'
Jx-
1-0
i 1
i.v
7-S 5 2-S7
10,
1 fe V
/O
M
?$ 1 >.$J
1
iO
' \tot-
.0 |
lo V
V
P.
to x_
JL
'•
ti
X
' VtoSJ
» ,1.
U
(04
-------
Page 4- of S_
Plant Name:
Run Number:
Test Date: _.
Operator: _
Traverse
Point
Number
Sampling / dock Time
Time, / (24-hour
(mln.) / clock)
Gas Meier
Reading
Velocity
llead^P,
Orifice Prcs. Differential
Desired
Actual
Slack
Temp. • F
m
Probe
Temp./ Filler
Temp.' P
Impinger
Temp.
•F
Dry Gas Meter Temp.
Inc
Uullcl
Pump
Vacuum
In.llg
fr»
1 HoO
o\
17
.5%
/
I -7
LSL
\ So
In
lo/
C/
' 1703
,01
Cf*,
' I1H-
-01
' nit
n
M
/o r
3-70-5?^
11:
3%
.ol
-0 1
o
5-7 T».
-o;
(01
' llif-
1,4-
7*7
SY
10 ?
•of
.o\
\0
\0<*
' lit
V
3-7.
> .-1S4-
H
Jl
to
L0_l
JOS_
•ON
_£L
_LJ2_
^_L.
a
. o\
vol
,01
Ok?
rs
(01
ov
o
-------
Page
of
Plant Name:
Test Date: ___5iZMjL__..
Run!
Traverse
Point
Number
4-
j
V*>tr
1
fyv
pL6rt
dumber: foT-i- c?
2-0
Actual
>o)
0 I
1- *'-
ol
?..-
^
perator:
Probe
Temp./ Filler
Temp.' F
as$> ; ic,-,
%r? ; v?
Jy ~^(o(J
•*-Co ' ^^ j^
1$6 '^57
osn ' ^51
^v^cc^l i *i_<*
r~*^ I * <^~"C) /^
/
/
/
/
/
/
>
/
/
/
/
/
/
/
'
'
'
C^*»
\y ^*^
Itnpinger
Temp.
•F
rf:
J5
^"^
T^-
^
Dry Gas Meier Temp.
Inlet
*l*\
W
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Plant
: ft Rf
Sampling Location: "L-/1 / €- i
Sample Recovery Person: ) S
Comments:
AL Date: 1/J/ /ff
Field Team Leader:
. Impinger Train ID: Al~ lO
^Ct*»>nu'
Filter No
...A)
Filter Description: f-f e.*.\j \J
Filter No.:
Filter Description:,
Front Half Data
. Filter Media Type:
rffc^UJ-c. £r
K. e
. Filter Media Type:.
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (nM)r_
Description of Impinger catch:_
XAD-Trap
&H) -2
17,
Impinger 3
607,
Impinger 1
. I
Impinger 4
y-r
Impinger 2
Silica Gel
(9):_
(av. .77-
-------
FIELD DA IA SHEET
Plant
Sampling Location
Run Number: A -T-wVjfcSDate:
Pretest Leak Rate: , pot* cftn @ H in. Hg,
Pretest Leak Check: Pilot: Xbrsat: *X
Sample Type: oy'fcffi Operator:
Pbar 23-7*1 Ps: - V.. f>
CO2. / O2:
Probe Length/Type: ^'j.
Stack Diameter:
Nozzle ID: . /j? 3 Thermocouple #:
Assumed Bws: *>% Filter #:
Meter Box #: ivxfhl Y:^0<2
Post-Test Leak Rate: ,£0 cfm @ in. Hg.
*: . /£A * Post-Test Leak Check: Pilot: uXOrsat:
-------
Page
of 3
Plant Name:
Run Number:
Test Date: _
Operator:
Traverse
Point
Number
Sampling
Time
(min.)
ng /
, /
) /
dock Time
(24-hour
clock)
Gas Meier I Velocity
I lead $P,
Orifice Pres. Differential
(£11)111.11,0
Desired
Actual
Slack
Temp. • F
m
Probe
Temp./ Filler
Temp* F
Impinger
Temp.
•n
Dry Gas Meter Temp.
Inle
Uullci
Pump
Vacuum
In.llg
£>
/ D
oS
fa /
1,0
o/
Of
0
>
/f D
f
/
.o
.O/
.o
/O
.01
ol
/ o
J-7&
•JLL
JO if
U2=L-
1
d?c/
££
^JL
t£l
%
*/
te8
^
-*4
_LOS_
5
/OC
-x^
//d
-------
Page
of I"?
Plant Name:
Run Number:
- IT-
Test Date: _52z
Operator:
Traverse
Point
Number
Sampling
Time,
(mln.)
"g /
LI
dock Time
(H-hour
clock
f
Gas Meter
Reading
Velocity
leadtP.
iiLlhO
OriHce Pics. Differential
(All) In. 11,0
Desired
Actual
Slack
Temp. • F
Jil
Probe
Temp./ Filler
Temp." P
Impinger
Temp.
•F
Dry Gas Meier Temp.
Inlet
Uullci
Pump
Vacuum
In. llg
26
I
422,
jiL
JV3=
jkL
/fl te
j^^.
4
P
f
f
f
2 ' (, ?/
^£X
Z2.
°L
*J°LL
Jo£_
/off
'
SO?
ioL
ttm
Ai
*>(
itr
,0\
(01
//&<;(,
& 9o.fr
3.0
D
sen
&
/of
^
-£l
J2/_
.ol
"7^7"
/ ol
37
-
'-
/off
^
.•g>/
6y
0
^21
/
-^
y^
i
/Ot^
"702 .
^1
I IX ov
ill
702.
^1L
So 7
6,
/gy
-------
7CZ7
f PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Date:
Sampling Location: J^vl
Sample Recovery Person:
Sampling Method Type: /
Run Number: A ' T"
Job Number: ,f <7) "7~ -fa LrtA^ /I/I-.**
K-\r i\ { Field Team Leader: OJ5
H^^ ''M Impinqer Train ID: -r/^< f
>/?£>
Comments: Ut** &
/7 /T" /" , . /L^.-^.
^y"^i*c.^ ^^L - j f^l^j'^ Tw f\*£ "^'i^^- ^ ^^v^^^—
O^'«*£A-
Filter No.:
/t//f
Filter Description:,
Filter No.:
Filter Description: .^
Front Half Data
Filter Media Type:_
. Filter Media Type^
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
XAD-Trap
/W ^ "X
g4V
i.7
Impinger 3
/u HU^/AftG
c^T
0,4
(e?t Q
CJ-£&sr
Impinger 1
Impinger 4
r/r.
Impinger 2
Silica Gel
(a): KM. r,
(g):_/&L
-------
FIELD DA I A SHEET
I •'}
Plant /\fe
Sampling Location 3^
Run Number:?? £ 3 -4>*) Date.
Pretest Leak Rate: iOo 3 elm
Sample Type: 4.
Pbar 3^.*?
C02: /
Operator:
Ps:
O2:
Nozzle ID: ; / V
Assumed Bws:
Meter Box #: 2,
Thermocouple #:
Filter #: T /=
Y: l.oo
Pretest Leak Check: Pilot:
15 in. Hg.
^_
\o\
VS
JL1_L
ru
\.
re
\A
AVm-
AH-
tl-
Tm-
-------
Page
of
Plant Name:
Run Number:
CO VI
Test Date: _.
Operator: _
< -
Traverse
Point
Number
Sampling /aockTIrae
Time. / (24-hour
) /
fmin.)
clock)
Oas Meter
Reading
Velocity
llcad^P,
in. IhO
Orifice Pics. Diffeienlial
Desired
Actual
Slack
Temp. • F
Probe
Temp./ Filler
Temp* P
Impingcr
Temp.
•F
Dry Gas Meier Temp.
net
Uullcl
Pump
Vacuum
In.llg
JG
-Of
o±
Jj.
.£1
1 0
•Of
0 (
Of
1.01
1 !
P^/J
S (-
7
-ol
loy
I/
$3
lilt,
V 1,
1C
1*7
/o
7
>M
JTT
4LS.
G
&t
H*P
JL
3-5
JLk
Irf-
57
01
(31
TVl.
no
ids
\\
\t
11
£} 1
\.\.\
113
\S
I.S
19V1
_LL
2.
R4.i
Mi
Hi.
•2^0
-3T
54
"6
if
51
-2X.
tft
Qt
i
u\
C'7
_U_L
i
VI
.ON
\10.
M«sr
-------
Page
of
Plant Name:
Test Date: _fL-_HJLL___...
Run Number: ^v> u< O
Traverse
Point
Number
fojfc
P>d3L v
*v9H>
4-
#=^o
Sampling /dock Time
Time, / (24 hour
(min.) / clock)
P^rt /VGQ-S
/ \G^ 1
f0\\ / \^ I7o<:
Poi w ' \ ~\ \4
/ nib
^pBgjk/ \127
£Srf£) 194P
/
4-^)5 /
/
/
/
/
/
/
/
/
/
/
/
1
Gas Meier
Reading
t( b f ^
vii n(D.
^i5,5^> i)
tf J 1 C >-Z,
WCTl^V
jjV
*" o /M Vt/
u»
Velocity
llead^P,)
liLlhO
!."%
Of
\ ,«\
n I
l-°l '
-0 I
M
.<=>!
U?
"i-o
Orifice Prcs. Differential
Desired
f.Y
0|
\-°(
0|
I *i
Ol
uy
•
1-0
Stack
Temp. • F
m
Ul
liL
18 >
101
\VO
L«t
io.5
I?O
iperalor:
Probe
Temp./ Filler
Temp." F
>J"J ; ;«;
•>GO / aj-^
•?4^ ' US
75^ / 75 1
-^^ ' ->c0
?$•/ 7 ^
75> ' ~>±-\
tr*" J $ iriG W'
^^r~ i / ^-/ J
*feo '^fic,
/
/
/
'
/
/
/
1
1
1
1
1
1
GC*V
Impinger
Temp.
•F
su
-fG
s-7
J"-T
^"7
•r-i
St
o ^
3i w
5-7
Dry Gas Meier Temp.
Inlet
(I 5
\ 1*
\(5
\lfa
II 1
t< ")
M *
i/y
if-f
II 5-
UUllCl
ItT
/I ^
/xo
1 *-!
1 > >
1?- 3.
\ a ^
1 ?- }>
((Cj
in
Pump
Vacuum
In. llg
9
I
-------
a ea
DPAC
I—7
PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
Sample Train Recovery Data
"/^/•/^
Sampling Location:
Sample Recovery Person:.
Sampling Method Type:. Ql£ 8
Run Number: /}" •
Job Number:
...
^tttu
Date:
Field Team Leader: D.
Comments:
. Impinger Train ID: A "Z-
Filter No.:
Front Half Data
. Filter Media Type: /tr&t*
Filter Descriotion: /i/^-*. \j
Filter No.:— '•
Filler Description. •
^ lol t^o J- #W T r> o. (&. ^~O
Filter Media Tvoe: ~
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents: //t
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:
r;l> $fl
Back Half Data
pv,*jC«A«f /^(/^OOy//^\ C0\
XAD-Trap Impinger 1 / Impinger 2
v>4p- 2 ftk1* £**yfc^
^^/-~> 5^?/. *7 c/i^<5V^
itf&d 'Wtf.ty* &/£>„ $
1 3 . 7 ^ * °i - ^ .(j#rik-£tJ'P3
Impinger 3 Impinger 4 Silica Gel
*7o '"5 /•/ ' /fYl'~J — v •^' ^
ffJefff (rtf.t (a): /.
Oleo.r- " '
^ J^-ST <^&sj-t-
/
-------
Plant A6C- <
Sampling Location
Run Number: M:- u^y*-rebate: 9 ~^<, -5'5
/*/OD
l^tt
/'//D
Gas Meter
Reading
(Vm)ft3
?5,p. 5 3> 0
953. p / U
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
FUter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
y/////y//////////////////////////////////////////////////////,.
^if\
\
7
0/i\
V
r^|K
V
rO|Pt
V
c95o
^50
^>r>e>
JSO
j*o
,550
-70
-70
>^
S>l
Si
8 I
So
So
/O/IN
/
1
V
AH-
Ta=
-------
/II n i
D PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant
Date:
tr
Sampling Location:,
Sample Recovery Person:
Sampling Method Type:
Run Number:^
Job Number:
/"
1 '
TT
Field Team Leader:
-T
3- 6 $&&>."?
Initial Volume: (ml) Ln$ .& £O(» » L
•T f<«& /^) n t
Net Volume: (ml) <# . ^ t'&**s*'^>t /
Total Moisture Collected (ml): ^ ^
Description of Impinqer catch: (~ 1 e*^f 4
47^.^
x9 , O
Silica Gel
s:i tef
(a): *t/77
(q): ^11, tT
(a):^ - /
4
/)
LJA
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant: ftktr Cnl^ \
Date: ?/Wf0
Sampling Locauon: p^6^
-^> J incha./ Stack 10, = ^,9 ^d I
Distance Uostream from Flow
XG4O
Calculated By: 12K /l~)S
Dbturbance (Distance A): 1
_ inches /Stack I.D. = /0.9 ad I
» &
i1 f
1 $
* if
to flA
v i y
V •* *^ /^/
^r /«?• ' /A1
J^lo^ ^
'' / Schematic of ^
i
Sampling Location
Traverse
Point
Numoer
r
i>
•?
y
^
/,
7
*
^
lQ
'/
fJX
Fraction
of
Length
h.OT^I
n.oiel
f)*tft
0s(77
0,?t0
6.W
D.W
^1^0
fi. W
fi,MT-
bW
O.W
Length
(inches)
/g7/x
J
Proaua of
Columns 2 & 3
(To nearest 1/8")
3 7?
/2 5^3
22cO-7
J^JO
yb.it
io(p ti
/w.y?>
tio.i?
/fWo
SW.M
nwi
/W.o7
Nippie
Length
(inches)
^^/
Traverse Point
Location
(Sum of Col. 4 & 5)
1&13
!>7 *?J>
t7,&7
f$,/o
1(.7f
f/5"7
PfZW
/bFi$
/7ft W
fn.v
/MM 7
2£)«o7
-------
FIELD DA i A SHEET
i KIIII. /\L5t^ ( ./^>K.«. odinpie i ype.w*^»/j upeidiui. A. ~u^/^t
Sampling Location (J*jDe(it=iizc "XTAC-I^
Run Number: Date: <)-2.£-<3&
Pretest Leak Rate: cfm @ in. Hg.
Pretest Leak Check: Pitot: Orsat:
Pbar: 21.8^ Ps: - 1 . £>
CO2: _3 O2: /-?
Probe Length/Type: jO' <&io.&4 Pitot #:
Stack Diameter: As:
Nozzle ID:^,
Thermocouple #:
Assumed Bws: />/ Filter #:
Meter Box #:/q& fc Y:
Post-Test Leak Rate:
AH@: /.77o
cfm @ in. Hg.
Post-Test Leak Check: Pilot: Orsat:
Traverse
Point
Numbe
0 /
2
?
/
s
t*
~l
8
1
ID
II
/i
A I
2
3
V
^
{?
7
8
°l
/t>
/^
fe
Sampling
• Time
(mln)
/y/ysf
/ Y-r54
/5-V5-
/5'.2^
aockTime
(24-hour
dock)
j
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH20
Orifice Pressure Differential
(AH) in H20
Desired
Actual
Stack
Temp.
fTs)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
y///////////////////////////////////////////////////////////^
o.ooi-
a . ootf
O -old
fi.Ol'Z-
£>.£>f/
D.&rf
^.toOtj-
£>. O£>3
6 .003
t>. D&l
O-OIO
O . &£>&
o , ooS
0 > 00 &
r> . DO A
b . oo 4,
a . 0/3
b,t>it>
o . D£>&
& . r>{>~7
0 .055
0 , (sol
rt . 0 1 0
0,00^
^VZ5
AVm-
AH«*
Ts-
O.Cffl
,0{ (a
-------
/
FIELD DA IA SHEET
Plant //£c 6»fe.
Sampling Location (JJL-k* $*+&
Run Number: I/ i£*tXv f Date:
/
Pretest Leak Rate: cfrn @ in. Hg.
Pretest Leak Check: Pilot: Orsat:
Sample Type: Operator:
Pbar Ps:
CO2: O2:
Probe Length/Type: Pitot # :
Stack Diameter: As:
Nozzle ID: Thermocouple #:
Assumed Bws: Filter #
Meter Box #: Y:
Post-Test Leak Rate:
Post-Test Leak Check: Prtot:
AH@:
cfm @ in. Hg.
Orsat:
Traverse
Point
Number
£ 0
I
1
7
V
k
7
^
te
cY
(V
4 '
p ^
u
•f
1
7
5
19
It
IV
Sampling
Time
(mln)
dock Time
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
A?
0»004
o.oos
£>.£>&
D.oob
$.00~7
0.0&B-
v.oof
0.9 ft
0.00?
9.00$
fitffa
Q.Pc£
P.OOf
Or 00 3
O'OoH
o.oob
9'OQb
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
A9£ CoK&/
°i/^ / ffl
Otafr ~
15
Orsat No.
Operator:
Comments:
Site Location:
O- 1
7A
— ^_
\\«Lrk<^
Run No.(s)
ft- l>- Mzfl-
1
a«*>\
Gas
•
C02
02'
cob
N:e
Ru
Actual
2>f
177
n 1
Net
2.V
/.^
Run 2
Actual
i.H
P-1
Net
*-H
\55
Run 3
Actual
Net
Average
Net
Volume
%
id
16-1
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas, Md
(Ib/Mole)
Md =
RunNo.(s)
R-U4X-
t
b*j 1^
Gas
CO,
02'
CO"
N2C
Run 1
Actual
2.0
/7,0
Net
3. c>
W6
Run 2
Actual
3.0
n.o
Net
3.0
W&
Run 3
Actual
Net
Average
Net
Volume
%
3,0
HO
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas, Md
(Ib/Mole)
Md =
Run No.(s)
Gas
•
C02
02'
CO"
N2e
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
• Oj Net Volume is O, actual reading minus CO2 actual reading.
" CO Net Volume is CO actual reading minus O2 actual reading.
c Nj Net Volume is 100 minus CO actual reading.
OPMFICCNVIXONIIB«TAI.«CIMC!»INC.
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
ABC
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No.
Operator
Comments:
Site Location:
o-l
,V-g.
Run No.(s)
/r-u-^
_2.
&<;(
Gas
C02
02'
CO"
N2C
Run 1
Actual
2.1
n i
Net
?.~1
is.o
Run 2
Actual
1 9
n.9
Net
*?
/S-0
Run 3
Actual
Net
Average
Net
Volume
%
2&
16,0
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
&-V-H*
-•2-
A^
Gas
CO,
02'
CO"
N2C
Run 1
Actual
3.2-
/^T-
Net
1-Z
^o
Run 2
Actual
3-0
/ill
Net
3-0
tf.t
Run 3
Actual
Net
Average
Net
Volume
%
3./
tf.f
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
~
Gas
•
CO2
-------
Client/Project:
Date/Time
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No
Operator:
Comments.
Site Location:
0-\
Run No.(s)
ft.tmzA"
n
fl*?«il
Gas
•
C02
o,'
CO"
N2<
Ru
Actual
1-1
i/,/1
n 1
Net
2.1
i*,S
Ru
Actual
2.1
/k.l-
n2
Net
2.~>
'*'*
Ru
Actual
13
Net
Average
Net
Volume
%
Z.I
Its
Multiplier
0.44
0.32
0.28
0.28
Md =
Molecular Weight
of
Stack Gas, Md
(Ib/Mole)
Run No.(s)
/llMtf-
M
6^-jT.
/
Gas
C02
02'
CO"
Njc
Run 1
Actual
^.1
|6.3
Net
2.
-------
VOLATILE ORGANIC SAMPLING TRAIN (VOST) SAMPLING DATA
COMPANY:.
DATE:
TIME:
CITY:.
METER #-.
RUN#:—^.1
,.,_._ Y-FACTOR:—
BAROMETRIC PRESSURE, in. Hg: 7#*f OPERATOR:-
AMBIENT TEMPERATURE,°F: Wf PURGE TIME:.
LEAK CHECK DATA
Vacuum
Initial, (in. Hg) Final, (in. Hg) Time, (min.)
Pre-test:
Post-test:
Sample
Time
(min)
^
&
•u
S3
<*\
1 I
It,
Clock
Time,
(24-hr)
/w
1*0
ffallll-
/S:37
K ^
\ r:ri
1 6.b i.
Meter
Volume,
(liter)
y^io^o
toff. S?o
f'Wo
^^\.^
1-o(ob,l
4-0 £^ |
4-07 3,7^
Rotometer
Setting
^/
-?/
2^
/0/«
\ lift
\<-jn
I 6/^1
Dry Gas
Meter Temp.,
(°F)
fr
/4&
/&0
/£>/
\ Do
1 frc.;
10 V
Vacuum,
(in. Hg)
/"
to
te>
/4
n
i °>
i °t
Nitrogen purge/activated carbon packing in sample holding container:
V8td= Vm(liters) xYx^ Pb(i""g)
vrtd=
-------
FIELD DA i A SHEET
Plant: ABA
Sampling Location
Run Number: A-u-3ts-
Pretest Leak Rate:
Date: ^-3.'
_ cfm @ jjj;_ in. Hg.
Pretest Leak Check: PHot: y Orsat:
Sample Type:/Vt-3l5 Operator:
Pbar: 23. B£ Ps: - (
CO2: ~5 O2: ~ Ik
Probe Length/Type: _^
Stack Diameter: /%7
Nozzle
Thermocouple #: J£ft
Assumed Bws: 7 Filter #: Qgo&lg- //
Y: o3
Pilot #:
K.- 3-61.1
As: /»~1 cfm @ j^_ in. Hg.
Post-Test Leak Check: Pilot: y/Oreat: —'
Traversa
Point
Number
Sampling
Time
(mln)
Qockrirrw
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Temperature
°F
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
O PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Plant:
Date:
Sampling Location:.
Sample Recovery Person:
Sampling Method Type:
Run Number: n^LA-
Job Number:
'cD
£,C_t
Field Team Leader:
Impinger Train ID:_
Comments:
Filter No.:
Filter Description:,
Filter No.:
Filter Description:.
Impinger Purge-
Start Time:
- \ I
Front Half Data
. Filter Media Type: / rc*.r& (L^
. Filter Media Type:.
Back Half Data
Flow Rate:
Stop Time:.
Impinger 1
Impinger 2
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
Impinger 4
39V- 6,
'Purge Gas:.
Impinger 3
Impinger 5
Silica Gel
(9):_
(9):_
(9):_
-------
FIELD DA IA SHEET
Plant: ABC
Sampling Location /itjp6ttj=4g£
Run Number: A.-U- 31^-2. Date: ^-^y.ffg
Pretest Leak Rate: o.^ast. clrn @ /y in. Hg.
Pretest Leak Check: Pilot: ,/ Orsat: xM
Sample Type:
Pbar:
C02: <-
Operator:
_Ps:
_02:
Probe Length/Type: /&',
Stack Diameter: /?*?
Pilot #: 12ft
As: —
Nozzle ID: A 7V Thermocouple #: /I A
Assumed Bws: /V Filter #: D8&B3&- /2.
Meter Box #:#&& Y: ^^/ AH@: /,77. 0/£>
/oe>
/£>?-
82. S
231°
3
1 fa)
-73
237
/»&
2,5
. 0-2-
(£>
MB.
.eM4~a
D.DO?)
/>,£/
/(,:?/
BSS.
6.45'
Vte
MLL_
22-
431
/&-*>
3.5
£^
Ay; /j/1
^ ^ • jfjj
g!3.
-2-38
215
/QS
43
135,6
ST8.72,
237
£_
Wrt*> 884.03
1.51-
234
/04
3.3
ISP.O
0.013
/.^5
^22.
233
(c>0
J^
157,5
t>.0\1.
/.BO
/,&>
232.
13.
y
IL5.P
/.24
^31
_2.i.
3
I7*.S
532
J27L
180.0
0 .(>! 0
.2 O
/0/.6
-------
I II
D PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
: f/l5(L
Sample Train Recovery Data
Sampling Location:
Sample Recovery Person:.
Sampling Method Type: /fie, Th0r
Run Number A - U ~ 3 / D ~~
Job Number: .5509 .
Date:
Field Team Leader:
DA.
. Impinger Train ID:_
Comments:
Filter No.:
Filter Description:.
Filter No.:
Filter Description:,
- /
Front Half Data
. Filter Media Type:_
. Filter Media Type:.
^
Impinger Purge-
Start Time:
Back Half Data
Flow Rate:
Stop Time:_
"Purge Gas:
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
Impinger 1
Impinger 4
Impinger 2
. \
\\eic.
Impinger 5
Impinger 3
Silica Gel
(9):.
(g):_
(g):_
.•3
-------
Plant:
Sampling Location U MngRj=\tie
FIELD DA IA SHEET
Sample Type: ryy-'3'is Operator: P.
Run Number: t^-o--±\z>-?, Dale: 9-2.5-98
Pretest Leak Rate: 0.002. cfm @ /5" in. Hg.
Pretest Leak Check: Pitot: \/ Orsat:
C02: ? %
O2: /7%
Probe Length/Type: [0' <
Slack Diameter: tf "1
Pilot #:
As:
Nozzle ID:
75,0
8:53
0-013
/.**
/,8f,
487
238
233
se>
93
^8^_^
¥.5
0.D/0
Z4O
23 /
14
.37
Q.OQt*
2.4 /
233.
14
37
2..S
fl-7.5
2. 4O
232.
43
57
2,5
105.0
io .
LIB
2+2.
ho
^A
157-5
0 -
J^
2.+I
2.34-
0 -GO
1,1,0
4B4
2&L
233
N ' " ' •*•
^nl.»
_23i.
^i.
^
IBO.Q
, 230
AH
Ti
-------
n
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Plant:
Ct>L
Sampling Location:
Sample Recovery Person: T/V #
Sampling Method Type: fir ft
Run Number: /} - U" ft 3» l£~ 3
Job Number:
Date:
Field Team Leader:
: . LJ
Impinger Train ID: /)• *!/'!***
Comments:
Filter No.:
Filter Description:
Filter No.:
Filter Description:,
Front Half Data
. Filter Media Type:_
k—'
-------
FIELB PATA SHEET
Plant:
nPt Cvl*- 'T^ft«~t . A(-l~~*. Sample Type: )^3/ < Operator: fl/^**^"
Sampling Location UvdsA/x, £A<^ Pbar: V7-0/ Ps:
Run Number: >
^V'^f'tftDate: *!/£<, /1* CO2: O2:
/
Pretest Leak Rate: cfm @ in.
Pretest Leak Check: Pitol: „/ Orsat: »
Traverse
Point
Number
Sampling
Time
(mln)
0
$
ID
l$
aockTime
(24-hour
dock)
om
otf$
0£*> Phot #:
As:
Nozzle ID: 0. "fy'O Thermocouple #: £TP
Assumed Bws: Filter #: fifto^JB ^ ®t
Meter Box #: V
Y:/*/tAH@: £>. ^
fr /2- *'
r /I" /
- /Z" A
/f^%^^
fir
s*'
Zt/(*
Ifr
zr?
2^7
^>
ZV8
;z-
l^
fZ-^
Tm=
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant:
Date: 1-3.5-98
*~A'
Sampling Location:_
Sample Recovery Person:_
Sampling Method Type: M 2> 15
. Field Team Leader:
Run Number: A- \J- 3/5-
Job Number:
. Impinger Train ID:
Aj—
Comments:
Front Half Data
Filter
Filter Description:
Filter No.: _
Filter Description:.
. Filter Media Type:
. Filter Media Type:_
Back Half Data
Impinger Purge-
Start Time:
Flow Rate:
Stop Time:_
Purge Gas:
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:
Impinger 1
Impinger4
L
Impinger 2
lmpinger/6
Impinger 3
577. 'r
Silica Gel
(9):.
(9):.
(9):.
-^
-------
V\ ^ C Co\<*
Plant:
Sampling Location h-joco. £\«-*-
Run Number: |V U-**«V-bate:
FIELD DATA SHEET
Sample Type: h 4 3 -^ Operator: (^
Pbar: 7-°l-$r^ Ps: -"").&
CO2: O2:
/y -
7
Nozzle ID:« / 4" Thermocouple #:
Assumed Bws: "1 Filter #: ~~*~F
Pretest Leak Rate: .0^3 cfm @ | Z, in. Hg:
Pretest Leak Check: Pitot: fX Orsat:
Probe Length/Type:
Stack Diameter: 1 97
As:
Meter Box #: 7_ Y: / .QolAH®: f. 7^7
#: ^ Tp Zc, Post-Test Leak Rate: ,po) cfm @ jj- in. Hg.
p>-] Post-Test Leak Check: Pitot: >/ Orsat: _^"
Traverse
Point
Number
Sampling
Time
(min)
QockTime
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H20
Stack
Temp.
(Ts)
. Temperature
°F
knpinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outiet
(Tm out°F)
Pump
Vacuum
On.Hg)
D
tj Q \ i
•go / .til
ft
•oo I -0
1
JU_
(,0
8*5
c c>
VI
7.
3
iTU
Afel
JLL
-15
\\4-\
O-
°| 01 .
. olD
'0(0
i.V
fa-
ffif
I 0
o~).OO
act?
V
f
f
\es
^TX
\oo
/o
.ILL:
,o!L?
10 |
_LOk
I,V
iot
c?
. n t 15
4-1
I o
n
(n t,
^O^
/ 6
nlQ
10 b
0
'7-4
I. 0V
2-6
(05
L>
lo-i
S
n\ o
-14-
^s
tm-
-------
L
j
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
D PACIFIC ENVIRONMENTAL SERVICES, INC
Plant:
Sampling Location:
Sample Recovery Person:
Sampling Method Type:
Run Number: fj '
Job Number:
Sample Train Recovery Data
Comments:
-/
Date:
Reid Team Leader:
.ImpingerTrain ID:
P/?//s
Filter No.:
~ V ~
Filter Description: . ^ f#/ //*• C o
Filter No.: —-
Front Half Data
Filter Media Type:.
Filter Description: ^
Filter Media Type:.
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
Back Half Data
XAD-Trap
Impinger 3
Impinger 1
362.5
Impinger 4
0.\
r Impinger 2
H
-IO.--4-
Silica Gel
5. <£
(9):_
(9):_
-------
K- ^
FIELD DATA SHEET
Plant:
tX & c C. a K c Sample Type: iVH Operator: G^--
Sampling Location v>^^Cv £m«. Pbar: ^^~> Ps: — \,o
Run Number: (X \) ^i^-l Date: c\->^-ci% CO2: 3> O2: /^
Pretest Leak Rate: , ^o^ cfm @ \S in.
Pretest Leak Check: Pitot: ; /Orsat: /
Traverse
Point
Number
A- '
?
3
4.
r
k
£
r
>,
•^
1
e/ f
L.
TL,
(J.
s
(>
G
f
4.
3
9-
1
Sampling
Time
(min)
0
i*5
IS
•JT<
.i 0
"bi.i
$.< -S3
$'*•<>
to
tl.S
-15-Sj
•jAX,
<^0
c
Q7
Vfl^
inS
Ml-S
\ Lo
1?TS
IbJ
1 <•}(,,
\So
lH.5
{<•<>
O >- .5
i b o
dock Time
dock)
U<*
\*^ b
^ JfO
^54
I fa °fc
\V? \ J
' 6 ^ to
I '•a'*-./
(bSo
\ts^
nos
ii\>-
h>o?
i 1^-1
H^ ^~
iH>-
\"7*1
nsi
^o^
\V \L
Hg. Probe Length/Type
Stack Diameter: x
: V^"r Pilot #:
O ^ '' Ae* \ ^ 0
5 »*2>. l 1 '
Nozzle ID: , n ^ Thermocouple #: ^ (ft lc
Assumed Bws:^_ Filter #:
Meter Box #: >- Y: l.ocr
p TH -tt> Post-Test Leak Rate: ,00^
•>
u
Gas Meter
Reading
(Vm)«3
^^,^7^.,^'
CA^O ^
qqo,4-
c\ t, ^, |
Oo o.^-
OOtfvT
0 \ o,°\
00) G, . 'L
0 2. o . 4-
o 1-r-f
*o^>\ • V1^0
0 '3 | , q 24-
O "$(* $\ 0
C=) 56q i o
O <\-> • i
6 f-b> I
05
lii)
K3
1,5
7- "*-
\< 1
(. 5
LS
l,j-
\,S
\.£
l's
f"5
3»^"o
i/-3o
4 f
47S
•fk 1
46 "i
4 77
46
4 70
^5X
4f C*
^•4-5
/I TO
^7<=5
4-5 ?
ffefe
vf7>
'4-^^
4-C4-
V >~
^ 1
H^
• —
3-Ui-.
is /
76 !
70 ^
•J& i
'Mo
1/"1
'3-S s^
7-6 0
•?^y
•X4 o
ost(
1-Sl
">^7
Z fa 1
^0 c.
•76o
?5v
^4/
16!
^ 3"B
7t ,
"3-C.O
a^v
a^
?<: Y
^~la i
ajr^c
2&1
7 J"*j
^Go
"?> 7
'^
057
7) c/
"*•*&
>Sg-
^5^
"3^. >
7^0
75^
">TS
35*,
>t>-
lt»l
~>L^
^S^
"i-S1^
'
t^
J~^
5" «
J"«
Jo
•5 \
J" 2-
^ 4-
5 I
J- )
f i_
,5&-
jr>-
J>
J l
^3
J v,
JS
Jt,
T"?
j--)
J5-
-T1
TT
—
tol
i 0 1
11
TS
10 J
\o>
1 Ob
! 04.
I 06
frvc.
101
/Oi.
to I
I 60
{Oo
|o)
10)
XDl
10 ^
(o \
I to ^
v«o ~s
-~^
foz
'0 'L
lOo
/O 1
I 05
/0£
'07
to3> ^
td°i
In T
(o 7
to-s
'°)
f 0 (^
^'0^
(0 C.
tot
lol
ll}7
i Ok
us
1 e>J~
(Of
— •
•L.
f
<_
6
s?
/ Z,,
\
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
f e
Field Team Leader:
Plant:_
Sampling Location:
Sample Recovery Person'.
Sampling Method Type: £c. r & We T/?& A
Run Number: /J/vterA'i-g- (L n'lJl-43°!-3- Impinger Train ID:_
Job Number:
Date:
Comments:
( /
Filter No
.: /V Iff
Filter Description:,
Filter No.:
Filter Description :_
Front Half Data
Filter Media Type:
o '5 c& loco. lj
Filter Media Type:
Back Half Data
XAD-Trap
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch: c_
fl.4-
Impinger 3
Impinger 1
Impinger 4
S-L,
Impinger 2
^
Silica Gel
(Q):
(Q):
-------
FIELD DATA SHEET
If--
Plant: (\ 6 c
Sampling Location
Run Number: flu -t^i,3 Date: 1- M •< y
Pretest Leak Rate:
cfrn @ \S in. Hg.
Pretest Leak Check: Pilot: •/ Orsal: ^
Sample Type:
Operator:
Nozzle ID: , ? f
Ps: ~
C02: 3 2/& O2:
Probe Length/Type:
Stack Diameter: 1 § 7
jl
Assumed Bws:
Meter Box #:
Thermocouple #:
—;V5 fc
-" Filter *: T/^
Y:
Pilot #:
As: / <* c. 7
Post-Test Leak Rate: ,oo ] cfm
in. Hg.
_
Post-Test Leak Check: Pilot: "^ Orsat:
Point
Number
Samping
Tim*
(mln)
QockTmrw
(24-hour
dock)
Gas Meter
Reading
(Vm)«3
Velocity
Head (Ap)
inH20
Otifice Pressure Differential
(AH) in H2O
Desired
Actual
Slack
Temp.
(Ts)
Temperature
°F
Probe
Ftlter
knpinger
Temp.
°F
Dry Gas Meter Temp.
Net
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
f«.Hg)
a i
01 i
on.
Y//////////////////////////: Y/ '//////////////////////////////.
'?.
,oo?>
< ooS
\ 1 S.
,0 I
OoG
. Oo 5
bo
. too 5
U
oQ-5
,73
J-4i-
-Ub
> ")
11-
4^3-
>70
Me-
-ft
rV
17
"]
75
\
fc
"7
•3
6 IS
oot-
4% 7
£0
\b ) ,b
4-
l/f
7
,1 3-
Si.
4-
s-v
10$
00
i .-
y-i
i/z-S
^^
; Ol
\,
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
C
Sampling Location:.
Sample Recovery Person:.
Sampling Method Type:
Run Number: Q-lf'
Job Number:
Comments:
Sample Train Recovery Data
AM-
Date:
Field Team Leader: 0.
. Impinger Train ID:
Car L
Filter No.:
Filter Description:,
Filter No.:
Filter Description:.
Front Half Data
Filter Media Type:.
. Filter Media Type:_
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Deschption of Impinger catch:.
XAD-Trap
Impinger 3
-7
\-
I v
Impinger 1
-0*
Impinger 4
3.6%
Impinger 2
Silica Gel
(g):^
(9):
(g):_
-------
Plant: t\ ft c
Sampling Location
Run Number: (\ v -4
FIELD DATA SHEET
*, vs Operator: . Q,
Pretest Leak Rate:
Pretest Leak Check: Pilot:
Date.
cfm (
Sample Type:
Pbar: 1°\.u
C02: ~i
.P«:.
02:
Nozzle ID: . t
Assumed Bws:
Meter Box #: 1.
Thermocouple #:
Filter #:
Y: Uy?.
in. Hg.
Orsat:
Probe Length/Type: gV Pilol #
Slack Diameler: W As: I "I C.
Post-Test Leak Rate: ,00 ^- cfm @ [ i_in. Hg.
Post-Test Leak Check: Pilot: tX Orsal^/
TraverM
Point
Number
Sampling
Tim*
(mln)
Qockrmrw
(24-hour
dock)
Gas Meter
Reading
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
V////////////////////////77
Temperature
°F
Probe
Filter
knpinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in.Hg)
y'/////////////////////////777T/,
fl 1
5
O
HID
n
, 005
IS
37.5
jt^_
ri.5
(-, 0
•o/-S
. OO
b
t 0 0
, T,
- 007
t o
0-1,3.
1 7 o
i.o
I 5
1- 0
Zcf-
5
(Oi.
1
-T
C,
7
7-*
_^£_
26
ro
Io5
, 0 t> 5
7
.7
, o
7
(0)
106
. Oo
3o
a
(01
s
1 0.5
.3
r t
( ox
7
/f Z.J'
,0
1,5
4-7*1
>*-
-------
L II \( /
D PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
Sample Train Recovery Data
Date:
Sampling Location:
Sample Recovery Person:.
Sampling Method Type:
Run Number: LA ~~^
Job Number:
fl l^
Field Team Leader:
Impinger Train ID:
5
Comments: (A-t/l def -A rg__ /%7/fld
7
Filter No.:
/I/4
Filter Description:.
Filter No.:
Filter Description:.
Front Half Data
. Filter Media Type: / ^T/g
Filter Media Type:_
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
XAD-Jrap
Impinger 3
M
Impinger 1
Impinger 4
A*/
Impinger 2
kDfr.
Silica Gel
(9):_
(9):_
(0):.
/ *0 / //<
f /
-------
FIELD DA i A SHEET
Plant:
rt&t' tefa. Sample Type: -7 7™ Operator: 'fifi*'*'
Sampling Location t/t~&/£.'i+ 5-faJ?. Pbar: 'Ltf- *^ Ps:
Run Number:/M/'|tt7-r0
Gas Meter
Reading
(Vm) ft3
^f^. (il ~? £
^vV. 7<2-
>vY ^/
Hg. Probe Length/Type
Stack Diameter:
Velocity
Head (Ap)
inH2O
: /6 '96** Pilol#:
' As:
H£
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
fjs)
Nozzle ID: - /To Thermocouple #: fClK
Assumed
Bws: Filter #:
/I- k-*
Lf^£
Meier Box #: ^ Y: /^ 672 AH@: £97?
Posl-Test Leak Rate:
Post-Test Leak Check: Pitol:
Temperature
°F
Probo
Filter
Impinger
Temp.
°F
cfm @
in. Hg.
•^ Orsal: vX
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
y////////////////////////////////////////////////////////////,
n.oo^ A/
D.Oo 1 ,.*-
/Z " A
/2" *\
' *~ " /-b
/
'
tf
S
z^£
1X9
2,^5
z?/
2yf
Z.Y?
AVm-
Tm=
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
O PACIFIC ENVIRONMENTAL SERVICES, INC
Plant:
Sampling Location: LA "
Sample Recovery Person:_
Sampling Method Type:
Run Number: IA
Job Number:
Sample Train Recovery Data
±+
vi Je
ef~
Field Team Leader: T) S
- P/3
Impinger Train ID:_
Comments:
Filter No.:
' ^
Filter Description:,
Filter No.:
Filter Description:,
Front Half Data
Filter Media Type:
Filter Media Type:_
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:
XAD-Trap
Impinger 3
, /
Impinger 1
Impinger 2
Impinger 4
Silica Gel
. 7
' <->
(g)L
(9):.
(9):_
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:.
Date:
O9- 7 dd
Calculated Bv: £>e<\<\is b. \\c,
Schematic of
Sampling
or
Traverse
Point
Number
i
J
3
H
<.
(p
Fraction
of
Length
x O.2> \
.OCs"?
. // S
. / -?~?
. ^-so
• 35C=
Length
(inches)
*sV
S&H*
€5^"
<&%"
Kty1
-85^"
Product of
Columns 2 & 3
(To nearest 1/8")
I .*0 " '- . V
5.-?5rc«V
^ "
/O "8 -ft, n"
i- " ii
/5- * : '$.«•>
Al.i/Si'il'-i
36.61 ; soii"
Nipple
Length
(inches)
3**"
3%"
3 ^"
3 %"
3^"
3^'1
Traverse Point
Location
(Sum of Col. 4 & 5)
rV
t.
12.
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: /9$C
Sampling Location:
Run #:
Date: 9.
Clock Time:
Operators:
Barometric Pressure, in. Hq: ^.So Static Pressure, in. I-UO:
Moisture, %: ^/ Molecular wt., Dry: Pitot Tube,
Stack Dimension, in. Diameter or Side 1: Side 2:
Wet Bulb, F:
°
Dry Bulb, °F:.
CvvOOtv^C
Travsraa
Point
Numb«r
A 1
c>
3
#
<
&
fe i
^
3
q
5
(a
C_ 1
^
3
^/
5
£.
"b i
^>
3
^
S
G
Velocity
Hsad
In. H20
t-4
-f '/
1-4
O
r^l
o
f--V
^6
f>^
o
<±>
c=>
+ *>
^-3>
^r ^
t^>
O
O
. +^
^^
/-_5
O
(9
0
£P-
Stock
Tamp.
°F
T«-
Md m (0.44 x ftCOg) + (0.32 X %O2) + (0.28 X %N^)
Md-(0.44x £> ) + (0.32 X aOA) + (0.28 xT^.f
Md-
% H,O % HO
M» - Mdx(1 - —) + 18( — )
100 100
M«-(>S.^ )X(1- —3 ) + 1B(-f2—)
100 100
'F-
S.P.
13.8
P«-Pb
Ps-
13.6
In. Hg
Vs - 85.49 x Cp x
Vs - 85.49 x ( ) x (
Vs- ft/a
A.- n2
Q» - VaxAaxeOs/m
Pax Ma
)x
xeo
0* -
BCfm
Qt ..= Q«x 17.847x
•n
*«•-£->
X 17.047 x-
100
dMfm
-------
DP s
Plant:
Sampling Location:
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Date: ^
Clock Time:
Barometric Pressure, in. Hg: 23. tM
Moisture, %: 2 -H<%> Molecular wt.f Dry:,
Stack Dimension, in. Diameter or Side 1:
Wet Bulb, °F: Dry Bulb.°F:
Operators:
Static Pressure, in. H2O:__
_PitotTube,Cp:.
_ Side 2:
t- .
1E5.
TrovtrM
Point
Mum tar
Velocity
Head
In.HjO
. e>
. o
. O
/. 0
. ca.
Stack
Temp.
°F
/ /
^ /
Md«
Md-(0.44x
Md«
Ma-
(0.32x
(0.2Bx
100
li- °l
Pt-Pb+^--
13.6
Pa*
if-
V»-85.48 xCpX
Vi-85.48 X(
°R (°F + 400)
13.6
In. Hg
r:-i tLi<
_ "
)X(
)x
Q»-VtxA»x60t/m
Q«- X
0,. /V 3,^20
X60
100
X 17.647 X-
Q«ttd- <7Z ~H-£ dmefm
©.-213
100
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Run No.(s)
y +4~ j
A
Run No.(s)
n~0*
Ytf-'
J
•
C02
o,1
CO"
N2'
i55O7. COO/ /7P
*?/*«/ 1%
0r<*+
7? '»'
Run 1
Actual
«« &*
7
Average
Net
Volume
0-2
10 >^
Gas
CO,
02'
CO"
N2<
Run 1
Actual
o, z*
W.b
Net
&.Z*
fypif
Run 2
Actual
fli 2^
to £
Net
#u>
U>tf
Run 3
Actual
PJ^O
a/).<^
Net
<5/Sfr
Slfl ^^
\
Average
Net
Volume
C).^
I/*** .
^
Multiplier
0.44
0.32
0.28
0.28
^
of
Stack Gas. Md
(Ib/Mole)
Md =
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
•
CO,
cy
CO"
N,c
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
* O2 Net Volume is O2 actual reading minus CO; actual reading.
" CO Net Volume is CO actual reading minus 02 actual reading.
c N2 Net Volume is 100 minus CO actual reading.
OPACVICENVmoNUBITAKEIMCtK INC.
-------
Client/Prelect:
Date/Time:
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No.
Operator
Comments:
Site Location:
Run 1
Actual
Net
OJO
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
o.z
Multiplier
0.44
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
0.32
0.28
0.2S
Md
Run No.(s)
T&ffii
^1
Gas
CO,
,(e
Net
0,20
J*M
Run 2
Actual
Q'l
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No.
Operator
Comments:
Site Location:
"BanheoSe,
Run No.(s)
A-0-
^ I
Gas
•
C02
4
Run 2
Actual
o.i
^0.5
Net
o.l
10^
Run3
Actual
Net
Average
Net
Volume.
%
O.I
30.4
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas, Md
(Ib/Mole)
Md =
Run No.(s)
fi-t>-
Hrt-2
<*>«£
Gas
COj
.5
Net
0-\
Q£>.^
Run 3
Actual
Net
Average
Net
Volume
%
o.\
20. Aj
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
CO2
02'
CO"
N2C
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Md =
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
•
* 02 Net Volume is O2 actual reading minus CO2 actual reading.
0 CO Net Volume is CO actual reading minus O2 actual reading.
" N2 Net Volume is 100 minus CO actual reading.
OMWIC cNvmoMUNTM. iciMcti INC.
-------
[
I
f
1
(
I
dCU>VA
4
y
4
y
«/
4/
tl
y
2.
2-
2.
^
!
£/
£/
METHOD 1 8 FIELD DATA SHEET
^ant.^lbc. CDK£ Tested Analyte: PAW 's
Date: 1 - ii -<3£ Orifice Tank *: \/*.-« Box 2
.ocation: BA^we^^e oi^-ruer Pump/Rotometer #:
Run #• A- o - 55-Ob - I Pf Pretest (mm Hg)-
Stack I.D.: 85 % " Post-Test (mm Hg):
=bar: 21. 7& Tt: Pretest f°R:
Sample Tube
Operators :_/
_eak Check:
^TS Time: Start: Finish: Total:
Pre: v/ Post: W/B: D/B: O«: CO«:
» ^^J ^ ^£? /^ " /^
Gauge F^w
Time Vacuum CQHir,r,
/ii-_\ OwlLlDQ
I'lyj
Traverse
Point
Number
//•'J £>
// •' £"£
/z :/8
/2 :38
/2 ; s£
/3 ' /-^
/3-" 3&
/3 '-s&
/4 : i &>
1-f : 38
/i/ : ^£>
75" -'/^
7.5" ,' 3&
/S '• £8
/A
si*4 y • t>
/*j 4t>. 3
7787- 8 3. 0
2(2.5.2.
a ne.o
2 2 ol. 7
33-<4l ,~l 8
Tamp.
°F
*7^ */^
g^
&*?
•92.
?
4-)
^l~)
3 7
^ 7
v ^
/Q"Z-
/o*S
/o*S
/a*.
/Ot-
to /
//)&
33
H
47
& ^^
& ^T"
33
tL e.
Md = (0.44 x %C02) + (0.32 x %O2) T (0.28 x %N.j)
Md = (0.44 x ) -t- (0.32 X ) -i- (0.28 x )
Md =
% HO % HO
Ma ~ Md x (1 ) -r- 18 ( ••• • )
100 " ' 100
Ms = ( )x(1 )*18( )
100 100
Ms =
Ts- °F - °R (°F + 460)
^ p
L/ 13.6 13.6
Ps = in. Hg
2.0 JAP =
i.O : •£
i.O r— ,1 TsrR)
^^ vs - bb.4» x up * VAP » y PsxMs
5 .^) V5 - «549x( ) it{ ) v -\l
Z.tf V
2-0 Vs- ft/s
2.0
2 .D 2
7 /s As • ft
2. a 0» « Vs x As x 60 s/m
2.0
2 , <5> Q« - x x 60
2 ^ Qs « acfm
2.0 p, %WO
1,O Qa . ,= Qsx 17.647 x x(1 - ^— )
std T, IQO
2,<9 Ts 10°
2.0
2.0 ^std X17.847X x(1- 10Q )
2.
-------
VOLATILE ORGANIC SAMPLING TRAIN (VOST) SAMPLING DATA
CITY'
DATE:
TIME:
LOCATION'
RUN #: V
METER #: Voyr Box
BAROMETRIC PRESSURE, in. Hg:
AMBIENT TEMPERATURE,°F:
Y-FACTOR:—
OPERATOR:—
PURGE TIME:.
LEAK CHECK DATA
Vacuum
Pre-tesf
Post-test1
Sample
Time
(min)
O
2o
4t>
Lo
&-7
/£>/
f J £/
/ yy f\
/4>Z>
/00
2CO
220
/&,* t/A
ao^ ad
*
Clock
Time,
(24-hr)
/^-•^^
/-o '•!&
//:,4
// '• 3
/2:2£>
/3'-43
/3:/'*f7
S5:t>7
£>. 66
&.£>€>
Meter
Volume,
(liter)
22**•. o-S
2534 7^
3S7t,.4Z.
2t>tB.*+
2b(?/,8
270*1 U
Mers
/'/^
Rotometer
Setting
2.0
2.o
2.0
2.0
2.0
*.t>
2.f>
2.0
2.O
2,0
2,6
2.0
/ /tfl/iu.T€.
/ ' 4*.
Dry Gas
Meter Temp.,
7<7
38
42
75"
48
/£>£>
/t>/
/A/
/O /
/o/
,43
/6
s.»
S.o
5,0
-r.o
*Z. 5"
4-,5"
5.S
3.0
3.0
.3.0
3.1
, /
Nitrogen purge/activated carbon packing in sample holding container:.
Y*- Vm(liters) x Y x 17.647 x Pb(i
-------
DOC
VOLATILE ORGANIC SAMPLING TRAIN (VOST) SAMPLING DATA
COMPANY'
HATF' :
METER #:_
BAROMETRIC PRESSURE, in.
AMBIENT TEMPERATURE,°F:.
RUN #: *-
Y-FACTOR:
PURGE TIME:
LEAK CHECK DATA
Vacuum
Initial, (in. Hg) Final, (in. Hg) Time, (min.)
Pre-test:
Post-test:
Sample
Time
(min)
-zyo
2&*V^
x
°^ Q\ 7**}
360
A±o
340
3LD
380
—
—
Clock
Time,
(24-hr)
X5" ' ^ ^
5V
/^ ''^ 7
/&: 2-7
/£ ' Ol4\e,*bS
Rotometer
Setting
z.o
2.0
2.0
2.0
2.0
2.0
2.0
1.0
—
— •
Dry Gas
Meter Temp.,
/'7
/0&
/OS
/t>7
/oB
/oB
/o&
/07
Vacuum,
(in. Hg)
jr. 5-
z.g
5.^5
g.t>
5.0
S.o
£.0
<$-.&
1\£±£.
pr<-£<±
3,/
3,0
3,0
3.0
3./
^•/
3,0
3,0
Nitrogen purge/activated carbon packing in sample holding container:.
vstd= vm(liters) x Y x 17.647 x -
-------
L^M^^BHM
VOLATILE ORGANIC SAMPLING TRAIN (VOST) SAMPLING DATA
C-ITY"
. At-
TIME: '*
METER #:.
BAROMETRIC PRESSURE, in. Hg:.
AMBIENT TEMPERATURE,°F:
LOCATION: TWiHwsg ^"P-yr
RUN #: * -° -
Y-FACTOR:
OPERATOR:
PURGE TIME:—
Pre-test:
Post-test:
LEAK CHECK DATA
Vacuum _
Initial, (in. Hg) Final'. (In. Hg) Time, (min.)
Sample
Time
(min)
O
.50
,/0
^n
S>0
/oe>
/ JO
/ Vo
/G.O
/ $0
Joe,
^0
Clock
Time,
(24-hr)
/6£0
/C3*/G
; i oo
//JO
H40
/ 3 OO
/Je,0
/J^/C
/ -300
/3 JO
IVQB
/W
Meter
Volume,
(liter)
J3o47.47
ioS? • oc>
S/5S./rt
3 1 ~Ho- d l
3J/^.j |
3 3 6/ . £> o
33o*l. 13
33'/fe-3V
33^3. 7S
3*1 3L. 3>5
3^7fl 3o
i5.*.ii
Rotometer
Setting
2.0
cJ.O
^> . o
3.0
J . O
«5. cs
O.o,
cP-0
-
^ CD
^ o
. c?.0
Dry Gas
Meter Temp.,
77
?v
si
-------
VOLATILE ORGANIC SAMPLING TRAIN (VOST) SAMPLING DATA
COMPANY:.
DATE:
TIME: U2.
r:iTV-
METER *•
BAROMETRIC PRESSURE, in. Hg-
AMBIENT TEMPERATURE,°F:
RUN #:—£ii
Y-FACTOR:—
OPERATOR:-
PURGE TIME:.
Pre-test:
Post-test:
LEAK CHECK DATA
Vacuum
Initial, (in. Hg) Final, (in. Hg) Time, (min.)
Sample
Time
(min)
J^/O
<3CoO
>h^
Clock
Time,
(24-hr)
/
J.o
b> .0
=?.o
rJ.O
2 -0
O-o
Dry Gas
Meter Temp.,
(°F)
S^i
<^^
9 S1
t^i
^i
^S
?*/
9^
^•=1
^
Vacuum,
(in. Hg)
*/
9
^/ '
^
•?
f
*t
4
4
«
Nitrogen purge/activated carbon packing in sample holding container:
Pb('n.Hg)
Vm(liters) x Y x 17.647 x
3 .
Tm(°R)
-------
FIELD DATA SHEET
Plant:
Sampling Location
Run Number:A-Q-3IS-I Date:
_ Operator:
Ps: 4o. vg
02:
Probe Length/Type:
Stack Diameter:
P'tot
H
As:
&
Nozzle ID: A a Ik Thermocouple #: *//-
Assumed Bws: V Filter #: Q&Q-74&- O&
Meter Box #: rufe b Y: |.o&5 AH@: i."77^
Post-Test Leak Rate: Q.^Q/ cfm @_&_ in. Hg.
Post-Test Leak Check: Pitot: y^ Orsat:
Traversa
Point
Numbe
Desired
Filter
Sampling
Time
(mln)
aockTime
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differentia)
(AH) in H2O
Stack
Temp.
(Ts)
Temperature
°F
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
Jt.35
2. 35
2.3$
10
3-0
*£>
-2.3S
70
/2V
£-2
/27
7Z.
3 -'
Rl> S, o i
2.0~)
//#
-238
71
. 21
,02.
J237
If
40
06.8,
£>. £>2-
.<)
/3:V3
,5U
/-I
2.5
2.41
lab
23
40
0,62.
234
/.D
^_
//&
^1
0. 07.
^37
103
0,02
o,o4
2.-2F)
233
63
f/
nu
/Ib
1,7 f>
^L,
QO_
^>g<^
-------
Page 2. of
Plant Name:
Run Number:
A- 0-3IS -
Test Date:
Operator:
Traverse
Point
Number
Sampling /dockTime
Time, / (24 hour
(mln.) / clock)
Gas Meter
Reading
Velocity
I lead ^P.
IfulliO
Orifice Prci. Dilfereolial
In. 11,0
Desired
Actual
Slack
Temp. • F
Probe
Temp./ Filler
Temp.' F
Impinger
Temp.
•F
Dry Oas Meier Temp.
Inlci
Uullcl
Pump
Vacuum
In.llg
D-
0,0-2-
, 0V
1L
h-z-
1
0,01
7.
'
£&.
t>-3
'/*;: 12.
#&
, 01
o. of
V-4
2.3S
17
93
-3
230
19
93
23
1 /I, fo 3
3 43
±22.
0.0?-
237 '
JtJL
£7_
2.
2. .1
23$
63
17
2.-?
/ /£ •' 3 V
/
*• "
5 -
A-
27^9
/t,:S0
*>/.
Z%1 1 /7.W
D.02.
2 '¥7
A -2.
/.
13
A-3
*>,!>/
331* 1/7-5^
o.o4
4 B '
A-U
/./&
2.32.
2,3
p. 0-2
Z33>
1 /B'ZI
i.o
/3>0
3
-------
Page
of
Plant Name:
Run Number:
Test Date: _.
Operator: _
Traverse
Point
Number
A-lo
A^<5
A. -4
Sampling / dock Time
Time. / (24-hour
(min.) / clock)
3&t> ' /£:z4
3B2> f /%:3& //^-'^7
V/Z. '/^.'//
/
/
/
/
/
/
/
/
/
/
/
1
1
1
1
1
1
1
1
Oas Meier
Reading
Ofc)fti
2^3.38
95S.t>/
9&./1*
<£&),& 7
311.263
Velocity
llead£P,
iiulhO
O.D'Z.
/./
£,&*-
/.&
Orifice Piei. Dilfctcnlial
(AlUilLlljO
Desired
0,£>¥
2..Z4
£>,*>{
J.£>?
Actual
0,&^
5,2.
£>,f>4
=?'/
Slack
Temp. • F
m
/J2^
/26
/^y
/*1
Probe
Temp. / Filler
Temp.' F
J?V^ ' -?37
j?3^ ' 232
^V^'^33
J?Vz'<33B
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
Impingcr
Temp.
•F
1*2.
L-3
£>£>
hi
Dry Gas Meier Temp.
Inlet
(TS.h)'F
*v
1/
4f
If
uuiici
(Ti™,)'F
^^
^/
^^
3$
Pump
Vacuum
In.llg
2.
3
2.
3
•
i
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
PACIFIC ENVIRONMENTAL SERVICES, INC
Plant:
Sample Train Recovery Data
z
Sampling Location:,
Sample Recovery Person:
Sampling Method Type:
Run Number: O -
Job Number ^
-f If f- iff
Date:
Field Team Leader:
Impinger Train ID:
Comments:
07*7% "OS
Filter No.:_
Filter Description: I jah'h
j
Filter No.: -
Front Half Data
Filter Media Type: /.
Filter Description:.
Impinger Purge-
Start Time:
trt
. Filter Media Type:.
Flow Rate:
Back Half Data
Stop Time:_
<9 (Xjfl.r
"f
qcn.*\-
Purge Gas:
Ti C.//I ;
-------
FIELD DATA SHEET
Plant _
Sampling Location
Run Number: A-o-315-7.0 Date:
Pretest Leak Rate: D.tf/'y elm @ V'p in
Pretest Leak Check: Pilot: ^ Orsal:
Sample Type:
Pbar:
CO2:
.P*.
O2:
Operator:
4, t*
Hg.
Probe Length/Type: _s[_£JAii Pilot #:
Slack Diameter: £5 3^" As:
Nozzle ID: O.£\lo Thermocouple #: ^£
Assumed Bws: V Filter #: O&OB4& -2.O
Meter Box #:/^_£_ Y: <£A0£_AH@: /.77&
Post-Test Leak Rate: 0,o0G cfm @'2B
y////////////////////////^^^
A 1
97-2.
23*?
'3
2 -
y
47 */
,0-2.
£2-
J27
, 80
/. O
2.0
£7
45"
S2.
£>. 02-
/
£>,£><{
^3.375
2.15
235
237
(04
6.02.
frQt
?<&
3.805
K&Jt
G.&02.
fc-i
LG
D z
fDO
I.D
J.Dl
2.0
238
/1 :38
0.62-
'll
43
. 36.S*
/-O
331
^34
ll'-SS"
//B
-23*?
»ob~).5l
13
235
IMo
loll. II
1-2.
11.0
I1O
to
t / P.QM
LL
/.D
235
4
Oi
o.oi
6.DZ
^7_
-------
FIELD DA I A SHEET
Plant:
Sampling Location
Run Number: A.-O-
Date:
-9£
Pretest Leak Rate: — cfm @ — in. Hg.
Pretest Leak Check: Pilot: — Orsat: —
Sample Type: j?/_5" Operator:
Pbar: J>?,?y Ps: •?- £>,/£-
CO2: a, ?i O2: j? i Vo
Probe LengbVType: 5-'
Stack Diameter:
\D.£.2/& Thermocouple #:
Assumed Bws: 4^ Filter #:
Meter Box
Pilot #:
As: 4Q.I
:/.OO£ AH@:
Post-Test Leak Rate: ^ cfm @ -_ in. Hg.
Post-Test Leak Check: Pilot: — Orsat: —
O
Desired
Actual
Probe
Filter
Traverse
Point
Number
Sampling
Time
(mln)
25O
dock Time
(24-hour
dock)
Gas Meter
Reading
(Vm)«3
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Stack
Temp.
fTs)
Temperature
°F
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm oul°F)
Pump
Vacuum
(in. Hg)
JIQ O.OOt
(d. \DIAV
A, 07.
0.64
241
211
Lt.
17
l*'5Q
-A£_
2-*tf
,D3_
o.o4
/38
231
2.2-
247
4JL
JL
o.oi.
0.04
3 7
18
iao
; 5.
Z38
JO
/.A
23B
96
sonn
2.H-2.
2.2.L,
»T. 60
0.0Z
231
_iZ
n:o3
I Ml
^2A.
3L
(2.6
D-&Z.
f-5%
zso
23-7
(,2-
Ibkl .10
o.
11
. 08
2 .01
to-1
91
65"
AVm-
T«=
-------
Plant: AB/1. CPK,£
Sampling Location
Run Number: A-o-3>is-^-Date:
Pretest Leak Rate: — cfm @ •— in. Hg.
Pretest Leak Check: Pilot: — Orsat: —
FIELD DA i A SHEET
PAbe 3
Sample Type: 315- Operator: /?3/£~<
404
QockTime
(24-hour
dock)
/7/*tf
/y-'j-/
/B:c>S
/fii/9
Gas Meter
Reading
(Vm)ft3
/&£,& 7, 6S
/orf.OI.
/eg/. o
Velocity
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
y////////////////////////////////////////////////////////////.
/,£
0 . 02-
/.2.
2,03
£>,0^
.Z,<9
0.0^
2.50
/3$
/40
/2/
13?
2.3-7
348
2J6
232.
239
£7
U
1*0
/6>O
/Of)
/&&
1?
/OG
94
y
/
y
-------
£
Jl JL
J
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
O PACIFIC ENVIRONMENTAL SERVICES, INC
Sample Train Recovery Data
Plant:
okf.
Date:
&. f A- "T
Sampling Location:_
Sample Recovery Person:
Sampling Method Type:___2_/_5—
Run Number: ,
Field Team Leader:
Impinger Train ID:.
Job Number: 5
Comments:
Me ha A
Filter No.:
Front Half Data
Filter Media Type: <7/*
Net Volume: (ml) Y <^ - ' <2. 0
Impinger 4 Impinger 5
Contents: — —
Final Volume: (ml)
Initial Volume, (ml) •• —
Net Volume: (ml) •*•"
Total Moisture Collected (ml): f*2.O
Descriotion of Imoinaer catch: C / c^ *—
S* \ \ *~l s*~ o > i 1 "
/I fte.1 o/5 /o gpe-^r . /7/rt^L, MJH^-Af A
Impinger 3
£mf/i/
?T^&/
$£3.t
<->. <^
Silica Gel
5,7 ^e/
(a): f^/, 3
(a): <5%.J2
(a): /-^ , /
1 1^ (_
-------
Plant: fl&C * <^o ]L*>
Sampling Location (-^v^y^..* c._T_
Run Number: <\-c>->S-3 Dale: p*?-^-^
Pretest Leak Rale: .ocf\ y elm @ iS in. Hg.
Pretest Leak Check: PHot: u/Orsat: ^>)^
FIELD DATA SHEET
Sample Type: 315 Operator:
Pbar: ^S.go Ps: t . '
CO2: — o
O2:
jo .
Nozzle ID: .• alt. Thermocouple #:
Assumed Bws: «/ Filter #:
Meter Box #:
Y:
AH@:
Probe Length/Type: -S '-&*#, Pilot #:
Slack Diameter: gsv« As: clm @ I5"in. Hg.
Post-Test Leak Check: Pilot: / Orsat:
Traverae
Pblnl
Numbw
Samplin)
Thrw
(mln)
CtodcTkm
(244iour
dock)
GM Mater
fUading
(Vm)f|3
V.btity
HMd (Ap)
hH2O
Grille* Prauur* Dlflaranbal
(AH) in H2O
Dasirvd
Actual
Stack
Temp.
(I*)
Tamparatui*
°F
Probe I FOtef
Impingar
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmln°Fl
Outlet
(Tm out°F)
Pump
Vacuum
f«.Hg)
O
10
/ . ? o
. .300
/c?)
S" I
. oo
So
5«
i (
. 0
. oV
?=>
£-0
•s't
I \
s
/OS.
0
J.05
•5 I
05-
.of/
/ 1 I .
i .00
/O'f
.oi
•off
0*45
-So
3 (
/IU.5C.O
. &•*-
0V
5 i
. 700
/. OO
< a
(70
' dtp
/.ID
fffl
i.oD>
ft'l
a'/ a
.
.00
J.IO
10
a'/ 3
HO
-------
Page
of
Plant Name:
Run Number:
-3
Test Date: _
Operator:
Traverse
Point
Number
Sampling /dockTime
Time, / (24-hour
(min.) / clock)
Gas Meier
Reading
Velocity
llcadfP.)
in. IhO
Orifice Pies. Differential
(All) in. 11,0
Desired
Actual
Slack
Temp. * F
_JSI
Probe
Terop. / Filler
Temp* F
Impinger
Temp.
•F
Dry Gas Meier Temp.
Inlet
f*!.)* F
Pump
Vacuum
'
/. 10
10
OJ)
It
5*7
I - 10
j i. 7
oV
/. OO
•J^L
f 0
_LO.
/ . 6O
50
_*-
.0*
5o
316,
i -j 5 .
/ . (O
•S L
/(.
uc. »-•
.0*1
//iJC.
I-JS./45
l.iQ
5o
_S2±L
\, 'ft
_1Q_
O*/
/ . OO
J.Q-7
ILL
St
_3£X
3C.-7
-no
//T
•b-70
/-7/S
t.Od
3.0-7
_2_
3 7 3 / / 7
50
VOS
1750
v.V/o
/.OO
p.o 7
56
£/
v
-------
D PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant:
Sampling Location:,
g
O •>,\ I
Sample Recovery Person:,
Sampling Method Type: fi?ft
Run Number:
Job Number:
Date: 3/2 7
. Field Team Leader: p.
.ImpingerTrain ID:
Comments:
Filter No.:
Filter Description:,
Filter No.: —•
Filter Description:,
Front Half Data
Filter Media Type:,
. Filter Media Type:_
Impinger Purge-
Start Time:
Flow Rate:
Back Half Data
Stop Time:
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch: C l&
Purge Gas:
Impinger 1
"faffitE. uto
"^f"£/7, 2
Impinger 2
7^*t I ffi.o
y"*l C.
Impinger 3
/
£9£.b (ffttf.Q 502.7
c?3,/^
Impinger 4
• —
• ,
— :
^ C'
(a): 82£?
ta): l7- ^
-------
FIELD DA IA SHEET
Plant: Afe£. £.one
Sampling Location LtMDeaFie.t=
Run Number: A-o-;u5-4 Date:
Pretest Leak Rate: -
cfm @ /5" in. Hg.
Pretest Leak Check: Pitot: y/Orsat:
Sample Type: (V\.-3IS Operator: P,
Pbar: 2^,85 Ps: -!.£»
C02: .3 % 2-1 Q2: n % '3''5
Probe Length/Type: 10'
Slack Diameter:
Nozzle ID: o .~H£> Thermocouple #: lift
Assumed Bws: (4 'JP.gJjf'*) O&o&^Q- |2>
Meter Box #:Mfe*gr: £%#/_ AH@:
Pilot #:
As:
Post-Test Leak Rate: #t £>£>?_cfm @ y in. Hg.
Post-Test Leak Check: Pitot: vX Orsat:
Traverse
Point
Number
Outlet
247")
Sampling
Tbna
(min)
Clock Time
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocrty
Head (Ap)
inH2O
Orifice Pressure Differential
(AH) in H20
Stack
Temp.
fTs)
Temperature
°F
Impinger
Temp.
°F
Dry Gas Meter Temp.
Pump
Vacuum
(in. Hg)
233
-=77
/Oh
/DO
i.S
0 ,OO\
(£> 8
B5.U45
0 . C.O |
A I
eA. 2.6
4.7 f
/&/
/&£>
z.z
&.£>/&
/.sz.
22>7
3.1$
f-?>7/0
/. »g
2.2.8
3.5
/21.S
/.¥*>
23"?
24
^4.
jro4_
I3>6,o
o.o/o
5/2
237
241-
/AS
/42,S
*ol
242.
JJO_
2.42-
J£3-
157.6
A.
22-
13 7.
n.tiz
1.75
23>7
^z.
JjSL
I
/72.S
0,008
/>2Q
.23?
/0t)
\(/Z}\/&o.o\rt-'Z& \I41.I4B
0.13
237
2-2,5
/o/
AVm-
AH
" I PI. I
-------
L it if /
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant:.
Sampling Location
Sample Recovery Person: 7/r~
>' c*5~&
-------
FIELD DA i A SHEET
Plant:
AWA'JQ^ . Sample Tvpe: &f^ Operator: iWL
Sampling Loca
Run Number: (^
Pretest Leak Ri
twn^idhCkLM CWStOJC Pbar &\tt' Ps:
•0-315 '6$ Date: C((lAt(q& CO2: O 02: ,01 /Xl
ate^aOCA cfm ® \ft in.
Pretest Leak Check: Pilot: S Orsat: (/
Point
Number
Sampling
TbTM
(mln)
.^VV5L
ololS ' ^>"H
A /v ,^ /I O/^
pA^O>% t/l /J-^l
Hg. Probe Length/Type: flflflNS Pitot #:l/fl ttfl.
0
\2y6
\?v5
loU"
Ift
\s>
\^>^
*"|f}
1^
11
Outlet
(Tm out°F)
^ \
no
^o
Pump
Vacuum
(in. Hg)
\^
ll.
^
AVm-
AH-
Ts-
Tm=
-------
b
ii /r I
PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant:
Sampling Location:,
Sample Recovery Person:,
: /V\
(3 iJ
Field Team Leader: O .J
Sampling Method Type: /
Run Number:
Job Number: ,*
Comments:
Impinger Train ID:.
Filter No.:
Filter Description:
Filter No.: —
Filter Description:
Impinger Purge-
Start Time:
Front Half Data
/? Filter Media Tvoe:
Filter Media Type:_
Flow Rate:
Back Half Data
Stop Time:.
Purge Gas:_
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
/£/ A%
Impinger 1
Impinger 4
Impinger 2
T
Impinger 5
Impinger 3
Silica Gel
(9):_
-------
FIELD DATA SHEET
Plant
Sampling Location
Hun Number: /q-o-^n-< Date:
Sample Type:
Pbar
C02: -
Operator:
Ps:.
02:
4- -IS
Thermocouple »:
Filter #:
Pretest Leak Rate: .oe.^ elm @ _/s in. Hg.
Pretest Leak Check: Pitot: -' Orsat: *--
Probe Length/Type:
Stack Diameter: i
Pilot #:
As: »e»
to
Nozzle ID: .j
Assumed Bws:
Meter Box «: /
-\ Y: /.
Post-Test Leak Rale: ,oog cfm @^4(j. Hg.
Post-Test Leak Check: Pilot: iX" Orsat:
^ a) ~
Traverse
Point
Numlm
SampBng
Tkm
(mln)
QocfcTfcTM
(24-hour
dodt)
GaaMetar
FWading
V.lodty
HMd (Ap)
InHZO
Grille* Pressure Dlftorantel
(AH) in H2O
Deslrsd
Actual
Stack
Temp.
(Ts)
Tamperatur*
°F
Probe I Fatar
bnpinger
Tamp.
°F
Dry Gas Motor Tamp.
Inlet
(Tmln°F)
Outlet
(Tm out°F)
Pump
Vacuum
.(in.Hg)
A
. 7O6.
1 . 0
9 » 8 -5 30
• <=o
.ov
.o'/
/<-=».
//g3
/ -o
5-0
5-0
•50
n
SS
S3
1 . /to
Si
/ -oo
/DA
30
41
'S'S
So
83
»:•»*
o-V
5'
. <=» a
//J
. *0
3 Co
5o
JSO
So
of
SI
•go
/OS
Si
.oV
/33
: 37:00
I?
VO.
10
*'*
Of
-0 ,
3-.
J.
10
.<=>*
/ IS
So
"8V.
l./g
-B-
)O
D ,PO I
Ji!L
%
l£> ,».»*'
t_L
: 15
if
*T
If
3:^4
J-S1
X^L
is
/?. ic
fc V
10
AH-
fi-
lm- ST.
-------
Plant Name:
Run Number:
Page j_
Test Date: 2_:£Ar.l
Operator:
of
Traverse
Point
Number
Sampling /dockTime
Time, / (24-hour
(rain.) / clock)
Gas Meier
Reading
Velocity
llcad^P,)
in. Hi O
Orifice Pics. Differential
Desired
Actual
Slack
Temp. * F
_JII
Probe
Temp./ Filler
Temp' F
Iropingcr
Temp.
•F
Dry Gas Meier Temp.
net
Pump
Vacuum
In. llg
X&£x
-^
VF
•*r
^
V
5C?
. 3.7
I.IO
'&•*
l.ltJ
I.I
IVX
.04
^L
I -vfo
V V
l»i ?^*-'
11 U
l. DO
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Sample Train Recovery Data
Plant:
J? £ & U.
AL
Date:
Sampling Location: ^t^ r /£- > */ Om^J/^LS^
Sample Recovery Person: £w- /TsD
Sampling Method Tvoei;^ 6/ 'J ^
Run Number # - £> ' ^S/t " (
Job Number: £> 5"& £ OOC)
^ Field Team Leader D> -S
Impinger Train ID: A/" <3
Comments: LX^A^ T. 2*^ ^/v^fc >CK
Mfi*
^
Filter No.:
/V l4
Filter Description:.
Filter No.:
Filter Description:.
Front Half Data
Filter Media Type:.
/ 6-p/
O/l
-f^-
Filter Media Type:.
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
XAD-Trap
Impinger 3
6,77.
.7
no.z.
Impinger 1
Impinger 4
Impinger 2
Silica Gel
(9):.
(9):.
• >/*e~*'
-------
Plant:
Sampling Location
Run Number:&~(V
Pretest Leak Rate:
Pretest Leak Check: Pilot:
FIELD DATA SHEET
Operator:
Great:
Sample Type:
Pbar:
CO2:
Probe Length/Type:
Stack Diameter:
Nozzle 10:
n$.T^
r>
Ps:
O2:
CU5
1\
...
Thermocouple 0: Hrr
Pilot
Assumed Bws: ^ Filler #:fl-Q. *rZf)-2.
Meter Box #:
Post-Test Leak Rate:
Post-Test Leak Check: Pilot:
- 7. >
Traverse
Point
Numb*
Sampling
Tim*
(mln)
Clock Tim*
(244iou
dock)
GM Meter
rVading
(Vm)n9
V*k>ctly
HMd(Ap)
lnH20
Orile* Preuur* DHtarantial
(AH) In HZO
Oaslrad Actual
• • •-^••—i^yu^i—•
Stack
T»mp.
(Ts)
Tamparatur*
°F
Proba | Filter
Impingar
Tamp.
°F
Dry Gas Malar Tamp.
Inlet
(Tmln°n
Outlet
(Tm out°
Pump
Vacuum
f«.Hg)
75"
y////////w////^^^^
o.oa
•VI
(
tl
4-/
4(
42.
a^
38
ci>&
df
^
-fo
40
^,
0
43
o.ov
o-o
\.\
<**>
0,0
0-
O.O4-
hZO
O-Ol
O.O3
\A
/22
41
H4O
o.o^
/.o
a.
['.Z\
ac\
\[ *
o.oa
l
11:18
£>. Dpi
0-05
ss
^
-1
l:0
tti
3.3
n.
0.0.
\.a
(fl
.4-
01
(0(0
.o
lao
\Oi.A-
ft.OI
0.00
D.D^
(•o
lao
Ql
o.a
^
40
O.O\
n.oa
\Ma
\Qft.i
JLb.
c)
JL
o.o-a
iO.CA
-------
Page
of
Plant Name:
Run Number: .>4~Q
Test Date: _.
Operator: _
4O
-------
Page
Plant Name:
Run Number:
Cab
Test Date: __°1.
Operator:
Traverse
Point
Number
ft -5
VV-4
Sampling /dock Time
Time. / (24-hour
(rain.) / clock)
s : si ' n?/7
u>'- eft i rw\
(o-ll / H51
/o>4O ' te\°l
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
1
Gas Meier
Reading
\40 ft
^yji50
Slack
Temp. • F
j*p317
\4o
Iciq
i-2,2
\aa
Piobe
Temp./ Filler
Temp." F
s\r\C\ 1 l^f^."~t
aoH' o«Q /
pao/35l
olSlQ ' ^6^1
25O/ 2^3
^ad ^^5
/
/
/
/
/
/
i
i
i
1
1
I
1
1
1
I
I
I
I
Irapingcr
Temp.
•F
tff^C
/0O
fofS
tffi
Dry Gas Meier Temp.
Inlet
C>*»v
O"^
tfl
9©
^"7
uuuei
q;7
^(^
Q\p
^{&
/~\ i
^i i^
Pump
Vacuum
In.llg
&
*~1
X
C(
^C
40
4O
42.
-------
PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
:: ABC
Sampling Location: Cx
Sample Recovery Person:
Sampling Method Type:
Run Number:
Job Number:
Sample Train Recovery Data
Date: 9/g.Z/flg
Field Team Leader:
Impinger Train ID
: f~ I I
Comments:
A/ In
Filter No.:_
Filter Description: V/fr ^
Filter Nc.:
Filter Description:,
Front Half Data
Filter Media Type:
<7
. Filter Media Type:_
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
'~-fr
XAD-Trap
Impinger
0.0
$-7.7.
5p«i
Impinger 1
32./
Impinger 4
Impinger 2
Silica Gel
(9):_
(9):.
(9):.
-------
Sampling Location'
Run Number: K.O-,
(\\3Ao \
Pretest Leak Rate:
Date: C\
Pretest Leak Check: Pitot:
•j^ elm @ \^-) in. Hg.
Orsat: •^
FIELD DATA SHEET
Sample Type: ^2^ Operator:
Pbar. ffl. 8Q Pa: 0> /6
CO2: Q
Probe Length/Type:
Stack Diameter:
O2:
Nozzle ID: Q. £15 Thermocouple #:
Assumed Bws: 4- F'lter
.' ' I ' » ^*
Pilot #:
As: 4OJ
Meter Box #: _\ Y:\.Q\X
Post-Test Leak Rate:Q,flp£. cfm@H4> in. H
Post-Test Leak Check: Pilot:
TravtfM
Pohl
Number
H
^±
-
-l
SVfl
Sampling
Tim
(mln)
01
10
!•=>
OockTInM
(244)ou
doc*)
IO-2C
10,53
H n
1151
iwn
1500?
GasMetar
Itoading
(Vm)n3
102
L7
2*5.
Velocity
Head(Ap)
VU-3LS
Orilca Pressure Differential
(AH) In H2O
Desired
-09.
M.
0-O
n.o/
O
0.01
WE
\/L
-CL
^
-OI
I- 3.
o.a
\A
y
Actual
Stack
T«mp.
(Ts)
Temperature
°F
Piobe
Filter
knpinger
Temp.
°F
Dry Gas Meter Temp.
Intel
(Tmln0F)
Ouflel
(Tm oul°F)
Pump
Vacuum
f«.Hg)
Y////////////////^^^
O.n^
2.. S3
2. 10
aoz.
(D.OZ.
2.
O.OZ
!.(
aoz
o.ov
5,0
o.oz
n./oz
JZJl
2.36
rO-OZ
O.O2.
n.Q2,
0,02-
a oz.
Izo
2JO
1
m
/2/ ^
/
/
ZS5
2.3O
^^c{
223
262.
^v-^i
(o?
Sto
SB
(l
^Z
i. \
foO
oa
-77
o-
7
#72
I
J£L
2
•z.
2,
/O
/O
43
4-7
45
-------
Page £. of 3
Plant Name:
Run Number:
ftfo
Test Date: _.
Operator: _
Travene
Point
Number
Sampling / Clock Time
Time, / (24 hour
(mln.) / dock)
M
Gas Meter
Reading
Velocity
Header,
IfLlllO
Orifice Pics. Dilfcrenlial
(All) In. 11,0
Desired
Actual
Stack
Temp. • F
m
Prnbc
Temp./ Filler
Temp.' F
Impinger
Temp.
•F
Dry Gas Meter Temp.
Inlet
Uullcl
mp
Vacuum
In. llg
3'
2,4
/07
'/
J10L
HJ^
QQZ.
93
-iil
H
O.D2-
0,0V
O.CA-
2,
9
2.
C-4
A',
4.^26.'
A 01
0.04
O.O4
&I.Q
001
OOZ
23 f '".
.
2.
•230 ; 257
9-6
4^4
JH1.Q.
DDL
O.O2
-
/5-lV '
n.o\
.OZ
z.
K-.V6/
qiiia .HK
235
_LU
0.01
0.0 Z
D.OZ.
Ifit
a
I.-2
/an
Q.O^
o.o z.
JL
Az
2.5-
,22^
^Q.
n.oz
O.D2-
1.2.
JO
0,07,
0,04
J4Q_
/ riv5
a
P-5
\p-\fc
0,07
o-
30V \
10
-------
Page 3 of v3
Plant Name:
Run Number:
Cdtu.
Test Date:
Operator:
Traverse
Point
Number
b-5
Sampling /Clock Time
Time, / (24-hour
fmin.) / clock)
T-CO / wnu>
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
. /
/
Oas Meier
Reading
Ht)ftJ
*&&£&>
tf|-7.ft26
Velocity
lleadtP,
in. IhO
'1.4-
Orifice PICI. DiHcicolial
(All) In. 11,0
Desired
A.O
Actual
^.O
Slack
Temp. • F
«)
[OS
Probe
Temp./ Filler
Temp." F
23Q24*z
i
t
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
Impinger
Temp.
•F
,<#
Dry Gas Meier Temp.
Inlet
rtta)'F
qtc
UUIICI
ff-J-F
V1L
Pump
Vacuum
In. llg
to
•
I
-------
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
PACIFIC ENVIRONMENTAL SERVICES, INC
Plant:
Sample Train Recovery Data
'/kx-W. -
Sampling Location:,
Sample Recovery Person:
Sampling Method Type:
Run Number:
Job Number:
3
>, ooo
Comments:
•rn~.'».
f~
Date:
Field Team Leader
. Impinger Train ID:
Front Half Data
Filter No
: A'Q-
Filter Media Type:
Filter Description: h ft*. v
-------
FIELD DA i A SHEET
Plant: WcCL LO«&& i Sample Type: £& Operator: jltfL
Sampling Loo
Run Number:1
•tfcn^J^lftJftU^O -Cil^OV pbar oR-^S Ps:
V-0-M^§fcDate: ^1-74^6 CO2: O O2: Si \
(t) f\f\f> '
Pretest Leak RateTO.QQ/. cftn @ \i?. in. Hg. Probe Length/Type: oiQj£> Pilol #: 4-£
Pretest Leak Check: Pilot: " Orsat: / Stack Diameter: <
TroverM
Pobt
NunilM
Sampling
Time
(mln)
D
€
/O
ffi
aockTime
(24-hour
dock)
Gas Meter
Reading
(Vm) ft3
^n.^ioo
sfjg;^
*>^ iP1} . 2i&fl
Velocity
Head (Ap)
inH2O
*£>T& As: At I
Ori6ce Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
Nozzle ID: 0- 9l>3 Thermocouple #: 4fc
Assumed Bws: 4 Filter #:
Meter Box #: | Y: L01'
\w*biux!iA
LAH@:
.^54
Post-Test Leak Raf?:QQD2.dm @\1 in. Hg.
Post-Test Leak Check: Pilot: u^ Orsal: <-"
Temperature
°F
Probe
FUter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
y/y/// ////yy/y/y/yyy//yyy/yy/y/////yyyyyyy/y/////// y/yy//// y/
® kotvSB-
Miis C
.C302
A-Li/i(/^(y\ i^c*
f »62> ft 13D
1 12SBI iftO
^Tl
-11
no
ho
11
\'JL
r-i
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC
4700 Duke Drive, Suite 150
Mason, Ohio 45040
513.398.2556 FAX: 513.398.3342
Plant:
Sample Train Recovery Data
Date:
: Our IQ^'T"
Sampling Location
Sample Recovery Person:
Sampling Method Type: , ..,
Run Number: fi~ O~ 4 ^°\ - fft
Job Number:
Comments:
Field Team Leader:
Impinger Train ID:.
Filter No.: "
Filter Description:,
Filter No.:
Filter Description:,
Front Half Data
Filter Media Type:_
Filter Media Type:_
Back Half Data
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Contents:
Final Volume: (ml)
Initial Volume: (ml)
Net Volume: (ml)
Total Moisture Collected (ml):
Description of Impinger catch:.
XAD-Trap
35 /.
0
Impinger 3
7/75
7/7V
Impinger 1
Impinger 4
, O
Impinger 2
r)
Silica Gel
(9):.
(9):_
(g)--.
-------
APPENDIX C
ANALYTICAL DATA
(Except GARB 429)
-------
P.O. Box 2010
Morrisville, NC 27560
EASTERN RESEARCH GROUP. INC. Ph. (919) 468-7800
Narrative
Site: ABC Coke
Prepared for: Frank Meadows (PES)
Prepared by: Link Nguyen
Description of Procedures for EPA Method 315 and Observations:
Filters -
Procedure:
The filters (including any loose particles) were transferred to a tared amber jar. The amber jars were placed into
a desiccator overnight in a temperature controlled environment. The following day, the samples were weighed
and initial weights were taken. To ensure that all conditions remained the same, the samples were placed back
into the desiccator and allowed to sit overnight and the second weighings were taken at the same time the next
day. Once constant weight had been attained, 100 mL of methylene chloride was added to each jar. The jars
were placed in a sonicator and allowed to sonicate for 3 minutes. After sonication was complete, the samples
were taken out of the sonicator. Each sample was filtered through a buchner funnel reinforced with an additional
Whatman 934-AH filter to prevent cross contamination on the buchner funnels. Once the solutions were
vacuum filtered, the extract was placed into a triple rinsed beaker (methylene chloride solvent). The beaker
containing the extract was placed onto a hotplate at low heat and the solvent was allowed to evaporate. Once the
samples almost reached dryness, the samples were taken off the hotplate and poured into a tared aluminum pan.
The beakers were triple rinsed with methylene chloride and then the solvent was poured into the aluminum pan.
The rinse was performed to ensure that no material remained in the beaker. The aluminum weighing pan was
heated to complete dryness, placed into a desiccator and allowed to sit in the desiccator overnight. The
following day, the samples were weighed and the weights recorded.
Observations:
The filters had a lot of loose, black particles which were also placed into the jars for PM weights. This was seen
mostly on the Inlets.
Acetone Front Half Rinse-
Procedure:
The rinses were taken and poured into tared 400 mL beakers. The beakers were triple rinsed with MeCI2. The
weights of the beakers including the rinses were taken. This gives an initial and a final weight to which the
volumes of the rinses were calculated. A separate sheet is attached explaining how the volumes were calculated.
The beakers containing the rinses were allowed to sit overnight in a hood to allow the acetone solvent to
evaporate. The next day the beakers, which now contain no solvent, were taken and placed into the dessicator.
The beakers were allowed to sit in the dessicator overnight. The next day, initial weighings for the samples were
taken. The samples were then allowed to sit in the dessicator again for 24 hours. The next day at approximately
the same time, the samples were weighed again for the second weighings. Once constant weight had been
Page 1 of 3
-------
attained, the weights were recorded for the Paniculate Mass (PM) portion of the analysis. Next, the beakers
were taken and 25 mL of MeCl2 was added to each beaker. Aluminum foil was placed over the tops of the
beakers. The beakers were then placed into a sonicator and allowed to sonicated for 3 minutes. This fraction will
be combined with the MeCl2 Front Half Rinse.
Observations:
No observations out of the ordinary were noted.
Methylene Chloride Front Half Rinse-
Procedure:
The rinses were taken and poured into tared 400 mL beakers. The beakers were triple rinsed with MeCl2. The
weights of the beakers including the rinses were taken. This gives an initial and a final weight to which the
volumes of the rinses were calculated. At this point, the extracts from the Acetone Front Half Rinse were
combined with this fraction. The combined fractions were placed onto a hotplate and allowed to heat gently at a
low temperature setting. Once the solution has almost reached dryness, the solution was poured into a tared
aluminum pan. The pan was then was placed back onto the hotplate and taken to complete dryness. The pans
were then transferred to the dessicator and allowed to sit overnight. The following day, the samples were
weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Impinger, Back Half Water-
Procedure:
Each sample was then poured into a clean, 1000 mL separatory funnel. Once in the separatory funnel, the amber
jars containing the original samples were triple rinsed with MeCl2 and then poured into the separatory funnel.
The approximate volume of this rinse is 50 mL. The samples were then shaken for 1 minute. After 1 minute, the
bottom MeCl2 layer was drained into a clean, 250 mL beaker. After the MeCl2 was drained, an additional 25 mL
of MeCl2 was added. The solution was then shaken for another minute and the bottom MeC12 layer was drained
into the same 250 mL beaker. This was repeated once more. Once the third shake was completed, and the
MeC12 was drained into the 250 mL beaker, the beaker was placed onto a hotplate and was gently heated to
evaporate the solvent. Once the solution was almost to dryness, the solution was transferred to a tared aluminum
pan. The pan was then placed back onto the hotplate and heated to complete dryness. Afterwards, the pans were
placed into the dessicator to sit overnight. The following day, the pans were weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Acetone, Back Half Rinse-
Procedure:
The exact same procedure was used for the Back Half Rinse as was used for the Front Half Rinse. The only
difference was that since PM analysis was not required, when the solvent dried down in the beaker, constant
weight was not taken for these samples. After the solvent had evaporated, 25 mL of MeC12 was added to each
Page 2 of 3
-------
beaker and sonicated for 3 minutes each. The rest of the procedure was the same as that of the Acetone Front
Half Rinse.
Observations:
No observations out of the ordinary were noted.
Methylene Chloride, Back Half Rinse-
Procedure:
The solution was poured into a tared beaker. After the solution had been poured into the beaker, another weight
was taken to calculate the volume. Once the volume had been determined, the sample was filtered through the
buchner funnel. The extract was placed into a clean, 250 mL beaker. The beaker containing the rinse was placed
onto a hotplate and gently heated almost to dryness. Once the rinse was almost dry, the solution was transferred
to a tared aluminum pan. The pans were placed back onto the hotplate and the solution heated to complete
dryness. Once the pans were dry, the aluminum pans were transferred to a desiccator and allowed to sit
overnight. The following day, the pans were weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Field Reagent Blanks-
Procedure:
The samples were poured into tared beakers. Weights were taken after the reagent blank rinses were poured in.
These final weights were used to calculated the volumes of the reagent blanks. The reagent blanks were allowed
to sit on a hotplate at low heat. After the solvents had evaporated, the final weights of the beakers with any
contents remaining were taken. Paniculate Mass was calculated. For the filter blank, 100 mL of methylene
chloride was added to the beaker and sonicated for 3 minutes. Afterwards, the methylene chloride was filtered
and poured into a clean beaker. The beaker containing the solvent was heated down to near dryness. The solvent
was then transferred to a tared aluminum pan. The pan was placed onto the hotplate and reduced to dryness. The
pan was desiccated and weights recorded the next day.
Observations:
There was a lot of particulate matter in the Outlet portion of the MeC12 BHR Blank.
Laboratory Reagent Blanks-
Procedure:
The same procedures were used for Laboratory Reagent blanks as for the Field Reagent Blanks. Solvents that
were used during the extraction process were tested in the reagent blank. A filter from the same lot that was sent
to the field was used to go through the extraction process.
Observations:
No observations out of the ordinary were noticed
Page 3 of 3
-------
EASTERN RESEARCH CROUP. INC.
P.O. Box 2010
Morrisville, NC 27560
Ph.(919)468-7800
Meadows (ABC Coke)
Matrix =
Method =
Sample ID:
FILTERS
PM
A-I-M315-1 -F (080798-20)
A-I-M315-2-F (080898-07)
A-I-M315-3-F (080898-16)
A-I-M315-FB-F (080898-03)
A-O-M315-1-F (080798-08)
A-O-M315-2-F (080898-20)
A-O-M315-3-F (080898-24)
A-O-M315-FB-F (080798-13)
A-U-M315-1 -F (080898-11)
A-U-M315-2-F (080898-12)
A-U-M315-3-F (080898-17)
A-U-M315-4-F (080898-13)
A-U-M315-FB-F (080898-08)
Weight of
Amber jar (g)
160.3937
159.0294
159.2766
168.5301
158.6706
159.4988
159.1533
167.1656
167.5069
167.9281
166.7330
167.1268
167.1157
Filter Pre-weight
(g)
0.32121
0.33624
0.32869
0.33476
0.32736
0.33727
0.32882
0.31986
0.33611
0.34986
0.33930
0.33162
0.33071
Avg. wt. Of
filter+jar (g)
161.59030
160.22695
160.63200
168.86500
159.00000
159.83995
159.49325
167.48550
167.91045
168.36170
167.14735
167.57910
167.44640
Final weight of
filter PM (g)
0.8754
0.8613
1.0267
0.0001
0.0020
0.0039
0.0111
0.0000
0.0674
0.0837
0.0751
0.1207
0.0000
Method =
Sample ID:
A-I-M315-1-F
A-I-M315-2-F
A-I-M315-3-F
A-I-M315-FB-F
A-O-M315-1-F
A-O-M315-2-F
A-O-M315-3-F
A-O-M315-FB-F
A-U-M315-1-F
A-U-M315-2-F
A-U-M315-3-F
A-U-M315-4-F
A-U-M315-FB-F
MCEM
Weight of
Alum, pan (g)
1
2
3
4
5
6
7
8
9
10
11
12
13
1 .6384
1.6719
1.6480
1.6657
1.6562
1 .6565
1.6499
1 .6601
1.6560
1.6398
1.6524
1 .6435
1.6358
Weight after
evaporation (g)
1.6393
1.6722
1.6482
1.6657
1.6562
1.6565
1.6499
1.6601
1.6560
1.6398
1.6525
1.6435
1.6358
Final weight of
MCEM (g)
0.0009
0.0003
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0000
Page 1 of 4
-------
EASTERN RESEARCH GROUP. INC.
P.O. Box 2010
Morrisville, NC 27560
Ph.(919)468-7800
Meadows (ABC Coke)
Matrix =
Method =
Sample ID:
A-I-M315-1-FH-A
A-I-M315-2-FH-A
A-I-M315-3-FH-A
A-I-M315-FB-FH-A
A-O-M315-1-FH-A
A-0-M315-2-FH-A
A-0-M315-3-FH-A
A-0-M315-FB-FH-A
A-U-M315-1-FH-A
A-U-M315-2-FH-A
A-U-M315-3-FH-A
A-U-M315-4-FH-A
A-U-M315-FB-FH-A
Matrix =
Method =
Sample ID:
A-I-M315-1-FH-M
A-I-M315-2-FH-M
A-I-M315-3-FH-M
A-I-M315-FB-FH-M
A-O-M315-1-FH-M
A-0-M315-2-FH-M
A-O-M315-3-FH-M
A-O-M315-FB-FH-M
A-U-M315-1-FH-M
A-U-M315-2-FH-M
A-U-M315-3-FH-M
A-U-M315-4-FH-M
A-U-M315-FB-FH-M
Acetone FHR
PM
Volume of
liquid (ml)
151.8
121.2
179.3
65.8
122.4
173.2
145.1
113.3
160.2
117.0
203.8
135.3
143.1
Methvlene Chloride
MCEM
Volume of
liquid (ml)
14 143.7
15 164.2
16 112.8
17 89.5
18 102.1
19 191.9
20 89.9
21 154.3
22 82.5
23 103.6
24 98.3
25 91.7
26 163.2
Weight of beaker
(9)
178.6432
178.0182
177.3675
178.0854
173.2616
175.0847
165.7398
177.5533
175.1573
164.5483
170.4723
178.4886
177.2716
FHR
Weight of Alum.
pan (g)
1.6616
1.6589
1.6636
1.6564
1.6587
1.6518
1.6254
1.6625
1.6722
1.6625
1.6631
1.6630
1.6588
Avg. weight of
rinse (g)
178.72260
178.14590
177.46000
178.08555
173.26590
175.08950
165.74420
177.55335
175.20535
164.60570
170.54025
178.53745
177.27185
Weight after
evaporation (g)
1.6624
1.6592
1.6638
1.6564
1.6598
1.6523
1.6259
1.6625
1.6755
1.6630
1.6659
1.6637
1.6588
Final weight of
filter PM (g)
0.0794
0.1277
0.0925
0.0002
0.0043
0.0048
0.0044
0.0001
0.0481
0.0574
0.0680
0.0489
0.0002
Final weight of
MCEM (g)
0.0008
0.0003
0.0002
0.0000
0.0011
0.0005
0.0005
0.0000
0.0033
0.0005
0.0028
0.0007
0.0000
Page 2 of 4
-------
EASTERN RESEARCH CROUP. INC.
P.O. Box 2010
Morrisville, NC 27560
Ph.(919)468-7800
Meadows (ABC Coke)
Matrix =
Method =
Sample ID:
A-I-M315-1-BH-A
A-I-M315-2-BH-A
A-I-M315-3-BH-A
A-I-M315-FB-BH-A
A-O-M315-1-BH-A
A-0-M315-2-BH-A
A-0-M315-3-BH-A
A-0-M315-FB-BH-A
A-U-M315-1-BH-A
A-U-M315-2-BH-A
A-U-M315-3-BH-A
A-U-M315-4-BH-A
A-U-M315-FB-BH-A
Matrix =
Method =
Sample ID:
A-I-M315-1-BH-M
A-I-M315-2-BH-M
A-1-M315-3-BH-M
A-I-M315-FB-BH-M
A-0-M315-1-BH-M
A-O-M315-2-BH-M
A-O-M315-3-BH-M
A-O-M315-FB-BH-M
A-U-M315-1-BH-M
A-U-M315-2-BH-M
A-U-M315-3-BH-M
A-U-M315-4-BH-M
A-U-M315-FB-BH-M
Acetone BHR
MCEM
Volume of
liquid (mL)
1 75.3
2 89.4
3 71.6
4 66.2
5 131.4
6 126.7
7 168.4
8 74.3
9 82.6
10 142.4
11 72.9
12 146.0
13 52.8
Methvlene Chloride
MCEM
Volume of
liquid (mL)
14 234.1
15 182.2
16 181.6
17 96.8
18 205.9
19 240.2
20 196.7
21 101.4
22 172.6
23 101.5
24 53.7
25 173.3
26 57.9
Weight of Alum.
pan (g)
1.7408
1.7404
1.7517
1.7522
1.7433
1.7652
1.7650
1.7633
1.7560
1.7402
1.7294
1.7158
1.7255
BHR
Weight of Alum.
pan (g)
1.7355
1.7231
1.7516
1.7556
1.7641
1.7535
1.7631
1.7531
1.7555
1.7441
1.7486
1.7338
1.7425
Weight after
evaporation (g)
1.7413
1.7405
1.7524
1.7522
1.7442
1.7655
1.7650
1.7645
1.7563
1.7404
1.7295
1.7161
1.7256
Weight after
evaporation (g)
1.7439
1.7290
1.7545
1.7557
1.7787
1.7573
1.7652
1.7608
1.7573
1.7480
1.7530
1.7350
1.7428
Final weight of
MCEM (g)
0.0005
0.0001
0.0007
0.0000
0.0009
0.0003
0.0000
0.0012
0.0003
0.0002
0.0001
0.0003
0.0001
Final weight of
MCEM (g)
0.0084
0.0059
0.0029
0.0001
0.0146
0.0038
0.0021
0.0077
0.0018
0.0039
0.0044
0.0012
0.0003
Page 3 of 4
-------
EASTERN RESEARCH GROUP. INC.
P.O. Box 2010
Morrisville, NC 27560
Ph.(919)468-7800
Matrix =
Method =
Sample ID:
A-I-M315-1-IMPH20
A-I-M315-2-IMPH20
A-I-M315-3-IMPH20
A-I-M315-FB-IMPH20
A-0-M315-1-IMPH20
A-0-M315-2-IMPH20
A-0-M315-3-IMPH20
A-0-M315-FB-IMPH20
A-U-M315-1-IMPH20
A-U-M315-2-IMPH20
A-U-M315-3-IMPH20
A-U-M315-4-IMPH20
A-U-M315-FB-IMPH20
Matrix =
Method =
Sample ID:
A-LB-F
Sample ID:
A-LB-Acetone
A-LB-MeCI2
A-LB-H20
Sample ID:
Lab Blank - Filter
Lab Blank - Acetone
Lab Blank - MeCI2
Method =
Sample ID:
A-LB-F
Meadows (ABC Coke)
H20 Imoinaer rinses
MCEM
27
28
29
30
31
32
33
34
35
36
37
38
39
Volume of
liquid (mL)
466.7
321.9
316.6
181.7
383.4
354.5
221.0
271.0
581.3
596.3
627.8
556.5
222.4
Blanks
PM
Weight of
Amber jar (g)
167.7995
Volume of
liquid (mL)
93.6
96.3
99.2
Volume of
liquid (mL)
107.0
100.9
MCEM
Weight of
Alum, pan (g)
27
1.6667
Weight of Alum.
pan (g)
1 .7392
1 .7290
1.7432
1.7382
1.7439
1.7405
1.7516
1.7507
1 .7386
1 .7395
1 .7347
1.7333
1 .7294
Avg. wt. Of
filter+jar (g)
168.1222
Avg. wt. Of
beaker+cont. (g)
104.9438
116.2450
114.1338
Avg. wt. Of
beaker+cont. (g)
1.7259
116.0317
1 1 1 .4530
Weight after
evaporation (g)
1.6668
Weight after
evaporation (g)
1 .7400
1 .7293
1 .7434
1 .7383
1.7444
1.7408
1.7519
1.7508
1 .7389
1 .7397
1.7351
1 .7335
1 .7296
Final weight of
MCEM (g)
0.0008
0.0003
0.0002
0.0001
0.0005
0.0003
0.0003
0.0001
0.0003
0.0002
0.0004
0.0002
0.0002
Final weight of
filter PM (g)
0.0002
Final weight of
filter PM (g)
0.0003
0.0001
0.0003
Final weight of
PM(g)
0.0002
0.0001
0.0002
Final weight of
MCEM (g)
0.0001
Page 4 of 4
-------
EASTERN RESEARCH GROUP. INC.
Eastern Research Group
Sample Chain of Custody
81101
Contents in Aluminum Pans for "FILTERS"
represent MCEM from the filter Matrix
Sample ID
A-I-M315-1-F
A-I-M315-2-F
A-I-M315-3-F
A-I-M315-FB-F
A-O-M315-1-F
A-O-M315-2-F
A-0-M315-3-F
Aluminum Pan #
1
2
3
4
5
6
7
Contents in Aluminum Pans for MeCI2 FHR
represent MCEM from the MeCI2 Matrix
Matrix = Methylene Chloride FHR
Sample ID
A-I-M315-1-FH-M
A-I-M315-2-FH-M
A-I-M315-3-FH-M
A-I-M315-FB-FH-M
A-O-M315-1-FH-M
A-O-M315-2-FH-M
A-O-M315-3-FH-M
A-O-M315-FB-FH-M
A-U-M315-1-FH-M
A-U-M315-2-FH-M
A-U-M315-3-FH-M
A-U-M315-4-FH-M
A-U-M315-FB-FH-M
Aluminum Pan #
14
15
16
17
18
19
20
21
22
23
24
25
26
Contents in Aluminum Pans for "Acetone BHR"
represent MCEM from the Acetone BHR Matrix
Matrix = Acetone BHR
Sample ID
A-I-M315-1-AH-A
A-I-M315-2-AH-A
A-I-M315-3-AH-A
A-I-M315-FB-BH-A
A-O-M315-1-AH-A
A-O-M315-2-AH-A
A-0-M315-3-AH-A
A-O-M315-FB-BH-A
A-U-M315-1-AH-A
A-U-M315-2-AH-A
A-U-M315-3-AH-A
A-U-M315-4-AH-A
A-U-M315-FB-BH-A
Relinquished by:
Received by:
/ Aluminum Pan #
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample ID
A-O-M315-FB-F
A-U-M315-1-F
A-U-M315-2-F
A-U-M315-3-F
A-U-M315-4-F
A-U-M315-FB-F
Aluminum Pan #
8
9
10
11
12
13
Contents in Aluminum Pans for H2O Imp Rinses
represent MCEM from the H20 Imp Rinse Matrix
Matrix = H20 Impinger Rinses
Sample ID
A-I-M315-1-IMPH20
A-I-M315-2-IMPH20
A-I-M315-3-IMPH20
A-I-M315-FB-IMPH20
A-O-M315-1-IMPH20
A-O-M315-2-IMPH20
A-O-M315-3-IMPH20
A-O-M315-FB-IMPH20
A-U-M315-1-IMPH20
A-U-M315-2-IMPH20
A-U-M315-3-IMPH20
A-U-M315-4-IMPH21
A-U-M315-FB-IMPH20
Aluminum Pan#
27
28
29
30
31
32
33
34
35
36
37
38
39
Contents in Aluminum Pans for MeCI2 BHR
represent MCEM from the MeCI2 BHR Matrix
Matrix = Methylene Chloride BHR
Sample ID
A-I-M315-1-AH-M
A-I-M315-2-AH-M
A-I-M315-3-AH-M
A-I-M315-FB-BH-M
A-0-M315-1-AH-M
A-O-M315-2-AH-M
A-O-M315-3-AH-M
A-O-M315-FB-BH-M
A-U-M315-1-AH-M
A-U-M315-2-AH-M
A-U-M315-3-AH-M
A-U-M315-4-AH-M
A-U-M315-FB-BH-M
Aluminum Pan
14
15
16
17
18
19
,20
21
22
23
24
25
26
Date:
.*»=
1 1/24!
-------
EASTERN RESEARCH GROUP.
Eastern Research Group
Sample Chain of Custody
81101
Contents in Amber jars
represent samples taken from filters
I Matrix = Filters
Sample ID
A-I-M315-1-F "
A-I-M315-2-F *
A-I-M315-3-F -
A-I-M315-FB-F
A-0-M315-1-F
A-0-M315-2-F
A-0-M315-3-F
A-0-M315-FB-F
A-U-M315-1-F l
A-U-M315-2-F ,
A-U-M315-3-F
A-U-M315-4-F
A-U-M315-FB-F
A-F-RB u
Contents in Amber Jars for MeCI2 FHR
represent Particulates from the MeCI2 Matrix
Matrix = Methylene Chloride FHR
Sample ID
A-I-M315-1-FH-M
A-I-M315-2-FH-M
A-I-M315-3-FH-M
A-I-M315-FB-FH-M
A-O-M315-1-FH-M
A-O-M315-2-FH-M
A-O-M315-3-FH-M
A-O-M315-FB-FH-M
A-U-M315-1-FH-M
A-U-M315-2-FH-M '
A-U-M315-3-FH-M
A-U-M315-4-FH-M
A-U-M315-FB-FH-M
.
cX
Contents in Amber Jars for "Acetone BHR"
represent Particulates from the Acetone BHR Matrix
Matrix = Acetone BHR
Sample ID
A-I-M315-1-AH-A
A-I-M315-2-AH-A
A-I-M315-3-AH-A
A-I-M315-FB-BH-A
A-0-M315-1-AH-A
A-0-M315-2-AH-A
A-0-M315-3-AH-A
A-0-M315-FB-BH-A
A-U-M315-1-AH-A
A-U-M315-2-AH-A
A-U-M315-3-AH-A
A-U-M315-4-AH-A .
A-U-M315-FB-BH-A
Contents in Amber Jars for MeCI2 BHR
represent Particulates from the MeCI2 BHR Matrix
Matrix = Methylene Chloride BHR
Sample ID
A-I-M315-1-AH-M
A-I-M315-2-AH-M
A-I-M315-3-AH-M
A-I-M315-FB-BH-M
A-O-M315-1-AH-M
A-O-M315-2-AH-M
A-O-M315-3-AH-M
A-O-M315-FB-BH-M
A-U-M315-1-AH-M
A-U-M315-2-AH-M
A-U-M315-3-AH-M
A-U-M315-4-AH-M
A-U-M315-FB-BH-M
Relinquished by:
Received by:
-------
First Analytical Laboratories
ANALYSIS REPORT
Metals Residues
Project # S512.000
Prepared for:
Pacific Environmental Services, Inc.
5001 S. Miami Blvd.; Suite 300
Research Triangle Park, NC 27711
Reviewed and Approved by:
William H. Wadlin, Ph. D.
Laboratory Manager
November 16, 1998
-------
First Analytical Laboratories
CASE NARRATIVE
Project #: 81101 Report Date: 16-Nov-98
Client: Pacific Environmental Services, Inc.
Client Project ID: S512.000
Samples:
Thirteen sets of samples were submitted for determination of various metals.
A blank filter was also provided which required the same analyses. Each set
consisted of a filter and several aluminum pans in which extracts of the filters had
been dried for a gravimetric measurement already performed by another laboratory.
The target elements were antimony, arsenic, barium, beryllium, cadmium,
chromium, cobalt, copper, lead, manganese, mercury, nickel, phosphorus,
selenium, silver, thallium and zinc. All of the samples were hand delivered hi good
condition, with no apparent damage.
Preparation:
The preparation procedure was that developed for Project # S511.000 which
was reported last month. The procedure adopted was to wrap a portion of one of
the sample filters around the end of a clean spatula, and use this assembly to swab
all of the residue out of all of the corresponding pans of the sample subset. It was
then possible to use another filter portion for a second cleaning, taking up any film
of desired residue missed by the first swab.
When the pans were cleaned of residue in this way, and all of the residue was
on the filters, the filter portions used and any remaining unused were placed in a
beaker for digestion. The samples were then prepared according to EPA Method
3050A, which is a nitric acid digestion.
Analysis:
Manganese and zinc were determined by Direct Aspiration Flame Atomic
Absorption Spectrophotometry (FLAA). Antimony, arsenic, beryllium, cadmium,
chromium, lead, nickel, selenium, silver and thallium were determined by Graphite
Furnace Atomic Absorption Spectrophotometry (GFAA). Barium, cobalt, copper
and phosphorus were determined by Inductively Coupled Plasma - Optical Emission
(ICP).
-------
Results:
The results are reported as total micrograms in the whole combination of
original samples for each subset. Mercury was not found in any of the samples.
Antimony and silver were found in one or two of the inlet runs, barely above the
detection limit, but not in any of the other samples. Cobalt was measurable in all
of the inlets, but in none of the other samples.
A most unusual observation is that cadmium in inlet #3 is about thirty times
the other two inlets. We believe this result should be discarded as significantly
different from the correlative results, and probably not representative of the system
under test. We suspect this unusual result is due to contamination either in the lab
or in the field. The digestate was run three times with consistent results.
Quality Control:
Traces of manganese and zinc were found in the blank filter, which is not
unusual. They are commonly found on blank filters at these low levels. The spike
recoveries were all within the normal range of 70% to 130%. The duplicates were
all within the normal limit of 20% for all cases in which the sample level is more
than five times the detection limit. If the sample level is lower than this it is not
possible to make a meaningful evaluation of the deviation between the duplicates.
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 27514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81101
Client: Pacific Environmental Services
Client Project 10:5512.000
Report Date: 16-Nov-98
Date Received: 02-Nov-98
Sample
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
A-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
Total Micrograms in Combined Sample
Sb
GFAA
<0.3
< 0.3
<0.3
< 0.3
<0.3
<0.3
< 0.3
<0.3
< 0.3
0.5
< 0.3
< 0.3
<0.3
As
GFAA
0.3
0.4
0.5
<0.3
2.8
5.1
4.1
4.7
0.4
16.8
11.5
9.7
<0.3
Ba
ICP
4.9
6.9
7.8
5.6
5.4
12.1
7.8
8.3
4.3
36.2
41.8
35.6
3.8
Be
GFAA
<0.02
0.03
0.04
0.02
0.02
0.07
0.03
0.03
<0.02
0.35
0.47
0.48
< 0.02
Cd
GFAA
0.09
0.12
0.07
0.03
0.31
0.35
0.45
0.47
0.16
0.38
0.36
10.20
0.04
Cr
GFAA
1.9
3.0
3.5
1.9
5.2
10.7
6.7
5.8
1.4
12.9
11.8
9.8
1.2
< 0.3 < 0.3 < 2.0 < 0.02 < 0.02 < 0.5
Spikes
% Recovery
QC SUMMARY
93% 113% 94% 83% 92% 92%
Duplicates
%RPD
6.0%
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 27514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81101
Client: Pacific Environmental Services
Client Project ID: S512.000
Report Date: 16-Nov-98
Date Received: 02-Nov-98
Sample
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
A-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
Total Micrograms in Combined Sample
pg
Co
ICP
< 1.5
< 1.5
< 1.5
< 1.5
< 1.5
< 1.5
< 1.5
< 1.5
< 1.5
2.5
2.0
1.6
< 1.5
Cu
ICP
2.8
3.6
4.4
2.5
4.9
5.1
4.6
5.7
2.4
16.1
11.4
25.7
1.5
Mn
FLAA
5.2
7.2
8.1
4.9
5.1
8.3
5.5
8.9
3.6
36.3
18.7
20.9
4.0
Hg
CVAA
< 0.2
< 0.2
< 0.2
< 0.2
<0.2
< 0.2
<0.2
< 0.2
<0.2
<0.2
< 0.2
<0.2
<0.2
Pb
GFAA
1.2
2.5
1.6
1.2
8.1
8.4
4.3
5.3
0.9
20.6
17.6
17.1
0.8
Ni
GFAA
< 1.0
1.8
1.2
< 1.0
1.1
2.9
1.9
1.6
< 1.0
19.6
14.0
24.3
< 1.0
2.7 < 0.2
< 0.3 < 1.0
Spikes
% Recovery
Duplicates
%RPD
QC SUMMARY
87% 93% 96% 104% 93% 105%
NA
NA 10.2%
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 27514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81101
Client: Pacific Environmental Services
Client Project ID: S512.000
Report Date: 16-Nov-98
Date Received: 02-Nov-98
Sample
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
A-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
Total Micrograms in Combined Sample
pg
p
ICP
16
15
20
16
15
36
18
30
11
59
56
70
< 10
Se
GFAA
<0.4
0.6
<0.4
<0.4
2.0
4.3
4.5
5.2
<0.4
4.4
3.6
4.3
< 0.4
Ag
GFAA
0.3
0.1
Tl
GFAA
0.9
1.0
0.6
0.8
0.2
i
1.1
1.1
1.2
Zn
FLAA
16
18
20
8
31
37
34
35
11
70
47
54
12
< 10 < 0.4 < 0.1 < 0.1
Spikes
% Recovery
Duplicates
%RPD
QC SUMMARY
87% 104% 92% 100% 91%
8.8%
7.0%
-------
ANTIMONY
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
IDL = 3.0
Postdig'n spike cone. 100.0 pg/L
Sample ID
Client
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
B-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
SPIKE
FAL
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
81101
.01
.02
.03
.OB
.Ul
.U2
.113
.114
.UB
.11
.12
.13
.IB
.BF
.01 s
Calibration Data
Blank
Test
Sol'n
M/L
1.5
1.5
0.6
2.0
1.4
2.9
2.0
0.3
1.5
5
.3
2.2
-0
0
-1
92
.1
.0
.6
.7
Abs.
0.000
Standard 1
Standard 2
Standard 3
Standard 4
0.025
0.085
0.160
0.283
Digte
Cone
MJ/L
1.
1.
0.
2.
1.
2.
2.
0.
1.
5.
2.
-0.
0.
-1.
5
5
6
0
4
9
0
3
5
3
2
1
0
6
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n
Factor
1
1
1
1
1
1
1
Init. Vol. Total
Vol. Dig'd yg
ml ml
< 0.30
< 0.30
< 0.30
< 0.30
< 0.30
< 0
.30
< 0.30
1 < 0.30
1
1.0
1.0
1.0
1.0
1
% REC
< 0
.30
0.53
< 0
< 0
< 0
< 0
92.7%
.30
.30
.30
.30
True cone., fJg/L
0.0
10.0
50.0
100.0
200.0
Calibration Verifications
ICV =
ICB =
CCV1
CCB1
100
0
= 100
= 0
103
1
102
0
.9
.9
.3
.8
CCV2 =
CCB2 =
CCV3 =
CCB3 =
100
0
100
0
108.1
0.9
110.0
0.5
-------
ARSENIC
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
IDL = 3.0 pg/L
Postdig'n spike cone. 1 00.0 pg/L
Date: 16-Nov-98
Sample ID
Client
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
B-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
SPIKE
FAL
81101.O1
81 101. 02
81101.O3
81101.OB
81101. Ul
81101.U2
81101.U3
81101. U4
81101. UB
81101.11
81101.12
81101.13
81101.IB
81101. BF
81101.O1 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Test
Sol'n
M9/L
3.1
4.3
4.7
0.6
28.3
50.6
41.4
46.6
3.8
67.1
114.7
96.9
0.2
-0.6
116.5
Abs.
0.000
0.018
0.120
0.237
0.465
Dig'te
Cone
pg/L
3.1
4.3
4.7
0.6
28.3
50.6
41.4
46.6
3.8
167.8
114.7
96.9
0.2
-0.6
True cone
0.0
10.0
50.0
100.0
200.0
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.,pg/L
Dil'n
Factor
1
1
1
1
1
1
1
1
1
2.5
1.0
1.0
1.0
1
% REC
Init. Vol. Total
Vol. Dig'd pg
ml ml
0.31
0.43
0.47
< 0.30
2.83
5.06
4.14
4.66
0.38
16.78
11.47
9.69
< 0.30
< 0.30
113.4%
Calibration Verifications
ICV= 100
ICB = 0
CCV1 = 100
CCB1 = 0
100.7
0.2
106.9
-0.3
CCV2 =
CCB2 =
CCV3 =
100
0
100
107.0
2.9
CCB3 = 0
-------
BARIUM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
IDL = 20 /jg/L
Postdig'n spike cone. 500 /L/g/L
Date: 16-Nov-98
Sample ID
Client
A-O-M315-1
A-O-M315-2
A-O-M315-3
A-O-M315-FB
A-U-M315-1
A-U-M315-2
A-U-M315-3
A-U-M315-4
B-U-M315-FB
A-I-M315-1
A-I-M315-2
A-I-M315-3
A-I-M315-FB
BLANK FILTER
SPIKE
DUPLICATE
FAL
81101.O1
81101.O2
81101.O3
81101.OB
81101.U1
81101.U2
81101. U3
81101.U4
81101. UB
81101.11
81101.12
81101.13
81101. IB
81101. BF
81101.O1 S
81101.O2 D
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Test
Sol'n
pg/L
49
69
78
56
54
121
78
83
43
362
418
356
38
19
518
65
Emiss.
17
54
136
1158
2403
Digte
Cone
MJ/L
49
69
78
56
54
121
78
83
43
362
418
356
38
19
True cone
0
20
100
1000
2000
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
,/jg/L
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1 <
% REC 93.8%
%RPD 6.0%
Calibration Verifications
ICV= 1000
ICB = 0
CCV1 = 1000
CCB1 = 0
1059
13
1159
21
CCV2 =
CCB2 =
1000 963
0 16
964
16
Total
4.9
6.9
7.8
5.6
5.4
12.1
7.8
8.3
4.3
36.2
41.8
35.6
3.8
2.0
-------
BERYLLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #-.81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.01 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 5
ICB = 0
CCV1 = 5
CCB1 = 0
test
Sol'n
P9/L
0.1
0.3
0.4
0.2
0.2
0.7
0.3
0.3
0.2
3.5
4.7
4.8
0.1
0.0
4.2
Abs.
0.000
0.014
0.047
0.104
0.141
5.24
0.04
4.41
0.05
Digte
Cone
M/L
0.1
0.3
0.4
0.2
0.2
0.7
0.3
0.3
0.2
3.5
4.7
4.8
0.1
0.0
True cone
0.0
0.5
2.0
5.0
10.0
IDL =
Postdig'n spike cone.
Dil'n Init.
FV Factor Vol.
ml ml
100 1
100 1
100 1
100 1
100
100
100
100
100
100 1.0
100 1.0
100 1.0
100 1.0
100 1
% REC 83.2%
-,pg/L
CCV2 = 5 4.32
CCB2 = 0 0.03
CCV3 = 5
CCB3 = 0
0.2 pg/L
5.0 pg/L
Vol. Total
Dig'd pg
ml
< 0.02
0.03
0.04
0.02
0.02
0.07
0.03
0.03
< 0.02
0.35
0.47
0.48
< 0.02
< 0.02
-------
CADMIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.O1 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 6
ICB = 0
CCV1 = 6
CCB1 = 0
IDL =
Postdig'n spike cone.
Test
Sol'n
P9/L
0.89
1.21
0.70
0.34
3.08
3.51
4.52
4.74
1.57
1.52
3.56
5.09
0.41
0.10
6.42
Abs.
0.000
0.024
o.m
0.333
0.526
6.05
-0.07
6.61
-0.03
Dig'te
Cone FV
/jg/L ml
0.89 100
1.21 100
0.70 100
0.34 100
3.08 100
3.51 100
4.52 100
4.74 100
1.57 100
3.80 100
3.56 100
101.80 100
0.41 100
0.10 100
True cone., ng/L
0.0
0.5
2.0
6.0
10.0
CCV2 =
CCB2 =
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
2.5
1.0
20.0
1.0
1
% REC 92.2%
6 6.40
0 -0.18
0.2 ng/l
6.0 //g/L
Vol. Total
Dig'd /vg
ml
0.089
0.121
0.070
0.034
0.308
0.351
0.452
0.474
0.157
0.380
0.356
10.180
0.041
< 0.020
CCV3 = 6 6.42
CCB3 =
0 -0.15
-------
CHROMIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.01 S
IDL = 5.0
Postdig'n spike cone. 50.0
Test
Sol'n
18.5
30.2
34.7
19.0
51.6
107.1
67.2
57.6
14.2
51.4
47.2
39.3
12.1
Dig'te
Cone
M/L
18.5
30.2
34.7
19.0
51.6
107.1
67.2
57.6
14.2
128.5
118.0
98.3
12.1
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
2.5
2.5
2.5
1.0
3.6
64.7
3.6 100
%REC
92.4%
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 50
ICB = 0
CCV1 = 50
CCB1 = 0
Abs. True cone., ng/l
0.000
0.072
0.159
0.398
0.841
50.9
1.0
49.8
0.0
0.0
10.0
20.0
50.0
100.0
CCV2 = 50
CCB2 = 0
CCV3 = 50
CCB3 = 0
50.8
1.0
Total
1.9
3.0
3.5
1.9
5.2
10.7
6.7
5.8
1.4
12.9
11.8
9.8
1.2
0.5
-------
COBALT
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.01
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
DUPLICATE
81101.O1 S
81101.O2 D
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 500
ICB = 0
CCV1 = 500
CCB1 = 0
IDL= 15/jg/L
Postdig'n spike cone. 1000 £/g/L
Test
Sol'n
M/L
2
-4
-10
0
-3
-1
1
1
-5
25
20
16
-6
-4
873
-3
Emiss.
395
482
681
1669
2940
498
3
593
5
Digte
Cone
MI/L
2
-4
-10
0
-3
-1
1
1
-5
25
20
16
-6
-4
True cone
0
20
100
500
1000
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.,/ig/L
CCV2 =
CCB2 =
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1
1
1
1 <
1 <
% REC 87.3%
%RPD NA
500 607
0 6
Total
V9
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
2.5
2.0
1.6
1.5
1.5
-------
COPPER
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.113
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
DUPLICATE
81101.O1 S
81101.O2 D
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 500
ICB = 0
CCV1 = 500
CCB1 = 0
IDL= 15/^g/L
Postdig'n spike cone. 500 fjg/l
Test
Sol'n
28
36
44
25
49
51
46
57
24
161
114
257
15
9
492
37
Emiss.
1229
1564
2760
9073
17578
499
8
574
11
Dig'te
Cone
28
36
44
25
49
51
46
57
24
161
114
257
15
9
True cone,
0
20
100
500
1000
Dil'n Init. Vol. Total
FV Factor Vol. Dig'd pg
ml ml ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
1
. , t/g/L
CCV2 =
CCB2 =
1
1
1
1
1
1
1
1
1
1
1
1
1
1
% REC 92.8%
%RPD NA
500 513
0 13
2.8
3.6
4.4
2.5
4.9
5.1
4.6
5-7
2.4
16.1
11.4
25.7
1.5
< 1.5
-------
LEAD
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.01
A-O-M315-2 81101.02
A-O-M315-3 81101.03
A-O-M315-FB 81101.OB
A-U-M315-1 81101.Ill
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
IDL =
Postdig'n spike cone.
Test
Sol'n
P9/L
11.9
25.4
15.5
11.8
81.3
84.4
43.0
53.3
8.8
82.2
175.7
170.6
7.5
Digte
Cone
M/L
11.9
25.4
15.5
11.8
81.3
84.4
43.0
53.3
8.8
205.5
175.7
170.6
7.5
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
2.5
1.0
1.0
1.0
3.0
100.0
Vol.
Dig'd
ml
Total
1.19
2.54
1.55
1.18
8.13
8.44
4.30
5.33
0.88
20.55
17.57
17.06
0.75
BLANK FILTER 81101.BF
2.5
2.5 100
0.30
SPIKE
81101.O1 S
104.9
%REC
93.0%
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 1 00
ICB = 0
CCV1 = 100
CCB1 = 0
Abs. True cone., fJg/\-
0.000
0.024
0.118
0.237
0.409
99.6
2.0
98.5
1.2
0.0
10.0
50.0
100.0
200.0
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
103.2
1.4
-------
MANGANESE
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.Ol
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
DUPLICATE
81101.O1 S
81101.O2 D
Test
Sol'n
52
72
81
49
51
83
55
89
36
363
187
209
40
27
434
65
Digte
Cone
52
72
81
49
51
83
55
89
36
363
187
209
40
27
IDL = 25
Postdig'n spike cone. 400
Dil'n Init. Vol.
FV Factor Vol. Dig'd
ml ml ml
100 1
100 1
100 1
100 1
100 1
100 1
100
100
100
100
100
100
100
100 1
% REC 95.5%
%RPD 10.2%
P9/L
^gA
Total
/jg
5.2
7.2
8.1
4.9
5.1
8.3
5.5
8.9
3.6
36.3
18.7
20.9
4.0
2.7
-------
Client: PES
Proj. #: 81101
Date: 16-Nov-98
MANGAN ESE
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
Abs. True cone., j/g/L
0.000
0.009
0.014
0.028
0.066
0.132
0
50
100
200
500
1000
509
13
CCV2 = 500
CCB2 = 0
504
11
CCV1 = 500
CCB1 = 0
536
24
-------
MERCURY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.01
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
IDL =
Postdig'n spike cone.
Test
Sol'n
pg/L
-0.03
-0.02
-0.06
-0.09
-0.06
-0.07
-0.06
-0.04
-0.04
0.01
0.01
-0.07
-0.03
Dig'te
Cone
pg/L
-0.03
-0.02
-0.06
-0.09
-0.06
-0.07
-0.06
-0.04
-0.04
0.01
0.01
-0.07
-0.03
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
Init.
Vol.
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
0.20 IJC
5.00 pc
Aliquot
Dig'd
ml
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
10 <
I/L
I/L
Total
P9
0.20
0.20
0.20
: 0.20
0.20
0.20
0.20
0.20
0.20
0.20
: 0.20
: 0.20
: 0.20
SPIKE
81101.O1 S
-0.07 -0.07
5.19
100 1
% REC
100
103.7%
10
0.20
-------
Client: PES
Proj. #: 81101
Date: 16-Nov-98
MERCURY
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 5
ICB = 0
CCV1 = 5
CCB1 = 0
0.000
0.012
0.026
0.052
0.131
0.253
5.08
-0.11
5.19
-0.06
0.0
0.5
1.0
2.0
5.0
10.0
CCV2 = 5
CCB2 = 0
CCV3 = 5
CCB3 = 0
4.99
-0.14
-------
NICKEL
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.03
A-O-M315-FB 81101 .OB
A-U-M315-1 81101 .Ul
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.114
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101 .IB
BLANK FILTER 81101.BF
Test
Sol'n
7.8
18.0
12.1
5.5
10.9
28.6
18.9
15.9
2.3
78.3
139.8
97.3
1.8
Dig'te
Cone
7.8
18.0
12.1
5.5
10.9
28.6
18.9
15.9
2.3
195.8
139.8
243.3
1.8
Postdig'n
IDL =
spike cone.
Dil'n Init.
FV Factor Vol.
ml ml
100
100
100
100
100
100
100
100
100
100 2.
100 1.
100 2.
100 1.
1
1
1
1
1
1
1
1
1
5
0
5
0
10.0 jug/L
100.0 lig/l
Vol. Total
Dig'd pg
ml
< 1.00
1.80
1.21
< 1.00
1.09
2.86
1.89
1.59
< 1.00
19.58
13.98
24.33
< 1.00
SPIKE
81101.O1 S
0.0
105.1
0.0 100
1.00
%REC 105.1%
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 100
ICB = 0
CCV1 = 100
CCB1 = 0
Abs. True cone., Hg/L
0.000
0.019
0.101
0.201
0.396
101.7
-1.4
95.9
-4.3
0.0
20.0
50.0
100.0
200.0
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
105.8
1.0
-------
PHOSPHORUS
RUN 1
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.01
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.Ul
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
DUPLICATE
81101.O1 S
81101.O2 D
IDL = 100 pgfL
Postdig'n spike cone. 2000 pg/L
Test
Sol'n
^g/L
163
152
195
156
113
84
54
1902
166
Digte
Cone
M/L
163
152
195
156
0
0
0
0
113
0
0
0
84
54
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
1
1
1
1 <
1 <
% REC 87.0%
%RPD 8.8%
Total
16.3
15.2
19.5
15.6
11.3
10.0
10.0
-------
Client: PES
Proj. #:81101
Dale: 16-Nov-98
PHOSPHORUS
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emiss. True cone.,/jg/L
252 0
292 200
451 1000
669 2000
1280 5000
Calibration Verifications
ICV = 2000 1976
ICB = 0 79
CCV2 = 2000
CCB2 = 0
CCV1 = 2000
CCB1 = 0
2368
11
-------
PHOSPHORUS
RUN 2
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81100
Date: 16-Nov-98
IDL =
Postdig'n spike cone.
100//g/L
2000 /*g/L
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101 .111
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
Test
Sol'n
^9/L
149
359
175
301
593
558
700
Dig'te
Cone
MiA
0
0
0
0
149
359
175
301
0
593
558
700
0
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
14.9
35.9
17.5
30.1
59.3
55.8
70.0
-------
Client: PES
Proj. #: 81101
Date: 16-Nov-98
PHOSPHORUS
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 2000
ICB = 0
CCV1 = 2000
CCB1 = 0
Emiss. True cone., jug/L
276 0
329 200
513 1000
748 2000
1419 5000
2095
88
2205
88
CCV2 = 2000
CCB2 = 0
-------
SELENIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101.Ill
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.O1 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 50
ICB = 0
CCV1 = 50
CCB1 = 0
IDL =
Postdig'n spike cone.
Test
Sol'n
WJ/L
0.6
5.9
1.5
3.6
20.2
43.2
44.6
52.2
3.3
17.6
35.5
43.3
-1.5
1.9
52.1
Abs.
0.000
0.021
0.048
0.100
0.194
53.0
-3.8
57.0
-1.7
Digte
Cone
0.6
5.9
1.5
3.6
20.2
43.2
44.6
52.2
3.3
44.0
35.5
43.3
-1.5
1.9
True cone
0.0
10.0
25.0
50.0
100.0
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.f/lg/L
CCV2 =
CCB2 =
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
2.5
1.0
1.0
1.0
1
%REC 104.2%
50 58.0
0 3.3
4 fjg/l
50 pg/L
Vol.
Dig'd
ml
<
<
<
<
<
<
Total
0.4
0.6
0.4
0.4
2.0
4.3
4.5
5.2
0.4
4.4
3.6
4.3
0.4
0.4
-------
SILVER
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-0-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.O1 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 20
ICB = 0
CCV1 = 20
CCB1 = 0
IDL = 1 .0 //g/L
Postdig'n spike cone. 10.0 /*g/L
Test
Sol'n
0.6
0.3
0.2
0.3
0.8
0.5
0.4
0.8
0.4
2.8
1.4
0.3
0.1
0.1
9.2
Abs.
0.000
0.093
0.186
0.364
0.547
21.2
0.3
20.5
-0.1
Digte Dil'n Init. Vol.
Cone FV Factor Vol. Dig'd
/jg/L ml ml ml
0.6 100
0.3 100
0.2 100
0.3 100
0.8 100
0.5 100
0.4 100
0.8 100
0.4 100
2.8 100
1.4 100
0.3 100
0.1 100
0.1 100
<
True cone., pg/L
0.0
5.0
10.0
20.0
30.0
CCV2 =
CCB2 =
CCV3 =
CCB3 =
1
1
1
1
1
1
1
1
1
1.0
1.0
1.0
1.0
1
&REC 91.7%
20 19.6
0 -0.1
20 18.1
0 -0.6
<
<
<
<
<
<
<
<
<
<
<
<
Total
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.3
0.1
0.1
0.1
0.1
-------
THALLI UM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81101
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.O1
A-O-M315-2 81101.02
A-O-M315-3 81101.O3
A-O-M315-FB 81101.OB
A-U-M315-1 81101 .111
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101.UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
81101.O1 S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 50
ICB = 0
CCV1 = 50
CCB1 = 0
IDL =
Postdig'n spike cone.
1.0 j/g/L
50.0
Test
Sol'n
M/L
0.3
0.6
0.6
0.5
9.1
10.3
6.1
8.4
1.9
10.9
11.2
11.6
0.7
0.1
50.1
Abs.
0.000
0.022
0.042
0.102
0.186
51.3
0.2
48.9
0.1
Digte
Cone
A^g/L
0.3
0.6
0.6
0.5
9.1
10.3
6.1
8.4
1.9
10.9
11.2
11.6
0.7
0.1
True cone
0.0
10.0
20.0
50.0
100.0
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.,M/L
CCV2 =
CCB2 =
CCV3 =
CCB3 =
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1.0
1.0
1.0
1.0
1
%REC 100.
50 5
0
50
0
52.8
0.3
Total
<
<
<
<
<
0.10
0.10
0.10
0.10
0.91
1.03
0.61
0.84
0.19
1.09
1.12
1.16
0.10
0.10
-------
ZINC
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81100
Date: 16-Nov-98
Sample ID
Client
FAL
A-O-M315-1 81101.Ol
A-O-M315-2 81101.02
A-O-M315-3 81101.03
A-O-M315-FB 81101.OB
A-U-M315-1 81101.U1
A-U-M315-2 81101.U2
A-U-M315-3 81101.U3
A-U-M315-4 81101.U4
B-U-M315-FB 81101 .UB
A-I-M315-1 81101.11
A-I-M315-2 81101.12
A-I-M315-3 81101.13
A-I-M315-FB 81101.IB
BLANK FILTER 81101.BF
SPIKE
DUPLICATE
81101.O1 S
81101.O2 D
IDL =
Postdig'n spike cone.
Test
Sol'n
MJ/L
155
177
204
82
312
373
342
354
110
700
470
540
121
47
518
165
Digte
Cone
pg/L
155
177
204
82
312
373
342
354
110
700
470
540
121
47
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
% REC 90.8%
%RPD 7.0%
15 j/g/L
400 /jg/L
Vol. Total
Dig'd pg
ml
15.5
17.7
20.4
8.2
31.2
37.3
34.2
35.4
11.0
70.0
47.0
54.0
12.1
4.7
-------
Client: PES
Proj. #: 81101
Date: 16-Nov-98
ZINC
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., fJg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
CCV1 = 500
CCB1 = 0
0.000
0.021
0.041
0.081
0.194
0.359
486
5
514
4
0
50
100
200
500
1000
CCV2 = 500
CCB2 = 0
520
12
-------
Element File: SB.GEL
Date: 11/05/98
Data File:
rechniaue: HGA
Element: Sb
Time: 12:O1
ID/Wt File: 81101.IDW
Calib. Type: Linear
Wavelength: 217.6
Slit: 0.7 L
Lamp Current: 0
Energy: 37
Sb
ID: BLANK
Sep. No,
Replicate 1
Peak Area (A-s): -0.000
Background Pk Area (A-s): 0.138
Blank Corrected Pk Area (A-s): O.007
Concentration (ug/L ): 4.9
Reoiicate 2
Peak Area (A-sJ: -O.004
Background Pk Area (A-s): 0.125
Blank Corrected Pk Area (A-s): O.O03
Concentration iua/L ): 2.3
OOOB6 A/S Pos.: O Date: li/05/'
Time: 12:01
Peak Height (A): 0.027
Background Pk Height (A): 0.073
Time: 12:04
Peak Height (A): O.O26
Background Pk Height (A): 0.071
Mean Cone (ua/L ):
3.6
SD: 1.86
RSD(7.): 51.87
Auto-zero performed.
Sb
ID: 10 PPB
Sea. No.: 00087
Renlicate 1
Peak Area
-------
Blank Corrected Pk Area (A-s): 0.023
Concentration (ug/L ): 16.5
Replicate 2
Peak Area (A-s): O.O24
Backqround Pk Area (A-s): 0.099
Blank Corrected Pk Area (A-s): 0.026
Concentration (uo/L ): IB.8
Mean Cone (ua/L ):
17.7
Standard number 1 applied. ("10.01
Correlation coef-f icient: l.OOOOO
Time: 12:23
Peak Height (A): O.O45
Backaround Pk Heiaht (A): 0.069
SD: 1.60
Slope: 0.0024
RSD(yi): 9.O7
••v. '\f -V 'V '
Sb
ID: 5O PPB
Sea. Mo,
Replicate 1
Peak Area (A-s): O.OB2
Background Pk Area (A-s): O.1O7
Blank Corrected Pk Area (A-s): 0.084
Concentration (ug/L ): 34.6
Keolicate 2
Peak Area (A-s): O.O83
Background Pk Area (A-s): 0.108
Blank Corrected Pk Area (A-s): 0.085
Concentration (uo/L ): 35.1
Mean Cone (ug/L ):
34.9
Standard number 2 applied. [50.0]
Correlation coefficient: 0.98908
OO090 A/S Pos.: 2
Date: 11/05/
Time: 12:26
Peak Height (A): 0.143
Background Pk Height (A): 0.070
Time: 12:29
Peak Height (A): O.140
Background Pk Height (A): 0.071
SD: O.32
Slope: 0.0017
RSD C/.): 0.93
Sb
ID: 100 PPB
Sea. No,
Replicate 1
Peak Area (A-s): 0.155
Background Pk Area (A-s): O.112
Blank Corrected Pk Area (A-s): 0.157
Concentration (ug/L ): 91.1
icate 2
Peak Area t A-s ) : O.161
Background Pk Area (A-s): 0.107
Blank Corrected Pk Area (A-s): 0.163
Concentration (ua/L ): 94.6
Mean Cone (ug/L ):
92.9
Standard number 3 applied. [100.0]
Correlation coefficient: O.99643
00091
A/S Pos.: 3
Date: 11/O5/
Time: 12:32
Peak Height (A): 0.256
Background Pk Height (A): O.073
Tame: 12:35
Peak Height (A): O.266
Background Pk Height (A): O.O68
SD: 2.47
Slope: 0.0016
RSD (7.): 2.66
Sb ID: 2OO PPB
Replicate 1
Peak Area (A-s): O.283
Sea. No
00092
A/S Pos.: 4
Date: 11/05/
Time: 12:38
Peak Height (A): 0.400
-------
Background Pk Area (A-s): 0.123
Blank Corrected Pk Area (A-s): 0.285
Concentration (ug/L ): 175.1
Reoiicate 2
Peak Area (A-s): 0.279
Background Pk Area (A-s): 0.120
Blank Corrected Pk Area (A-s): 0.2BO
Concentration (uo/L ): 172.1
Mean Cone (uo/L ):
173.6
Standard number 4 applied. [200.0]
Correlation coefficient: 0.99419
Background Pk Height (A): 0.071
Time: 12:41
Peak Height (A): 0.412
Backoround Pk Heiaht (A): 0.075
SD: 2.O9
Slope: 0.0015
RSD C/.): 1.21
*Bi
lo. »»*,
i*
i
0.
.splay Calibration -C:\fifl USERXAfl F
^--^"
4+^
. _X^
r—r-'" Nonllnaar
2Tsi C»cr. C&ef.: D.»»»«l
.-^~ FlfE-e: £?.COZ?
0 ccnc4nvrat3«n £00.8
*
4,
Sb ID: ICV
Replicate 1
Concentration (ug/L ): 1O5.3
Replicate 2
Concentration (ua/L ): 1O2.5
Sep. No.: 00093 A/S Pos.: 5
Time: 12:53
Time: 12:56
Date: 11/05/
Mean Cone (ug/L ): 103.9 SD: 1.98
QC sample is within ranoe 79.5 - 120.49
RSD ('/.): 1.90
Sb ID: ICB
Replicate 1
Concentration (ug/L ): 2.0
Replicate 2
Concentration (uo/L ): l.B
Sep. No.: OOO94 A/S Pos.: 0
Time: 13:00
Time: 13:03
Date: 11/05/
Mean Cone luq/L ): 1.9 SD: 0.18
UC sample is within range -15.49 - 15.49
RSD C/.): 9.41
-------
Sb ID: 81101.B-F
Reolicate 1
Concentration (ua/L
Sea. No.
) : -1-4
Concentration tug/L
Mean Cone (ua/L ):
•1.8
-1.6
00095 A/S Pos,
Time: 13:06
Time: 13:09
SD: 0.24
Date: 11/05/
RSD(7.): 15.01
Sb ID: 81101.OB
Reolicate 1
Concentration tug/L
Keolicate ^
Concentration (uq/L
Mean Cone (ua/L ):
Sea. No.:
) : 1.7
j : 2.3
2.0
OOO96 A/S Pos,
Time: 13:12
Time: 13:15
SD: 0.45
'V '\t 'V 'V 'V 'V 'V 'V "
Sb ID: 81101.UB
Reolicate 1
Concentration (uq/L
Reoiicate z
Concentration iug/L
Mean Cone lua/L ):
Sea. No,
) : 2.3
) : O.7
1.5
00097 A/S Pos,
Time: 13:19
Time: 13:22
SD: 1.14
8
Date: il/05/
RSD ('/.): 22 . 5C
Date: 11/05/
RSD ('/.): 75.32
Sb ID: 81101.IB
Reolicate 1
Concentration (ua/L
Sea. No.:
) : 1.7
icate -:
Concentration iug/L ): -1.5
Mean Cone (ua/L ):
O.O
00098 A/S Pos,
Time: 13:25
Tame: 13:28
SD: 2.22
Date: 11/O5/
RSD(X): 1948.
Sb ID: 81101.01
Reolicate 1
Concentration (ug/L
Reelicate 2
Concentration lug/L
Mean Cone (ua/L ):
) : 4.O
): -0.8
Sea. No.: 00099 A/S Pos
Time: 13:31
Time: 13:35
10 Date: 11/05/
1.5
SD: 3.40
RSD ('/.): 210.1
Sb TD: 81101.01
Reolicate 1
Sea. No.: 00100 A/S Pos.: 10 Date: 11/05/
Time: 13:38
-------
Concentration tug/L ): 90.2
fteolicate 2 Time: 13:41
Concentration iug/L ): 95.2
Mean Cone (ug/L ): 92.7 SD: 3.58 RSD(7.): 3.B6
Recovery is 91.27.
•"*• "V'V A. **v'\t "\f *V *V 'Vj *\j *V '\* *\j *V r\t *\f *\rf '\j "\» *V *V 'V *V *V *V *V *^/ *^ *V ^» ^» ^ ^^ ^ "V ^ ^ 'V ^> *V ^ ^* ^^ ^ ^ ^ ^ ^ ^ ^ ^ ^^ ^ ^* *\» ^* ^ ^/ ^ ^»^» ^ ^* ^ ^* ^t^t ^« ^^ ^^ •V'V'
Sb ID: 81101.02 Sea. No.: 00101 A/S Pos.: 11 Date: 11/05/1
Reolicate 1 Time: 13:44
Concentration (uo/L ): 1.3
-------
Element File: SB.GEL
Date: 11/05/98
Data File:
Technioue: HGA
Element: Sb
Time: 17:45
ID/Wt File: 81101.IDW
Calib. Tvoe: Nonlinear
Wavelength: 217.
Slit: 0.7 L
Lamo Currents 0
Energy: 38
Sb ID: 81101.02
Reolicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (uo/L ):
Sea. No
): 2.6
): O.5
00102 A/S Pos.: 11 Date: 11/05
Time: 17:45
Time: 17:48
1.5
SD: 1.46
RSD ('/.) : 94 .6
Sb ID: 811O1.D3
Reolicate 1
Concentration (ug/L
Sea. No,
icate 2
Concentration (ug/L
Mean Cone (uo/L ):
) : 1.8
): -O.6
00103 A/S Pos.: 12 Date: 11/05
Time: 17:51
Time: 17:54
0.6
SD: 1.70
RSD ( 7.) : 283.
Sb ID: CCV
Reolicate 1
Concentration (ug/L ): 102-9
Reolicate 2
Concentration (ua/L ): 101.7
Sea. No.: 00104 A/S Pos.
Time: 17:57
Time: 18:00
Mean Cone (uo/L )
102.3
SD: 0.86
QC samole is within ranee 79.5 - 120.49
Date: 11/05
RSD (V.): O.84
Sb ID: CCB
Reolicate 1
Concentration (ug/L ): 3.5
Realicate 2
Concentration (ua/L ): -1.6
Sea. No.: 00105 A/S Pos.: 0
Time: 18:03
Time: 18:06
Mean Cone (ug/L ): 0.8 SD: 3.59
QC sample is within ranae -15.49 - 15.49
Date: 11/05,
RSD (7.) : 377 .1
Sb ID: 81101.Ul
Reolicate 1
Concentration (ua/L ): -2.3
Sea. No.: 00106 A/S Pos.: 13
Time: 18:09
Date: 11/05/
-------
-eolicate 2
Concentration (ug/L ): 6.1
Mean Cone (ua/L ):
i-4
Time: 18:12
SD: 5.94
RSDC/.): 317.23
5b ID: 81101. U2
V
Replicate 1
Concentration (ug/L ): 4.8
Reoiicate 2
Concentration (ug/L ): 1.1
Mean Cone (ug/L ):
Sb ID: 81101. LJ3
Reolicate 1
Concentration (ug/L ): 1.9
Reolicate 2
Concentration (ug/L ): 2.1
Mean Cone (ug/L ):
Sea. No.: 00107 A/S Pos
Time: 18:15
Time: 18:18
2.9 SD: 2.61
'V'V'V'V'V'V'V'V'V'V'V^A^'V'V'V 'W^*W^**VV*\»^*V»
Sea. No.: 00108 A/S Pos.
Time: 18:21
Time: 18:24
14 Date: 11/05/9!
RSDC/.): 89.32
15 Date: 11/05/91
2.0
SD: 0.20
RSDC/.): 10.01
Sb ID: 81101. 1)4
Reolicate 1
Concentration (ug/L ): l.O
Reolicate 2
Concentration (ug/L ): -0.3
Mean Cone (ug/L ): 0.3
Seo . No.: 001O9 A/S Pos.: 16 Date: 11/05/9'
Time: 18:27
Time: 18:30
SD: 0.94
RSD(7.): 271.59
Sb ID: 81101.11X2.5
Reolicate 1
Concentration (ug/L ): 0.8
Reolicate 2
Concentration (ug/L ): 2.9
Mean Cone (ug/L ): 1.8
Corrected Cone (ug/L ): 4.5
Sea. No.: OO11O A/S Pos.: 17 Date: 11/05/9
Time: 18:33
Corrected Cone (ug/L ): 2.O
Time: 18:36
Corrected Cone (ug/L ): 7.2
SD: 1.47
RSD (X) :• 79.97
Sb ID: 81101.12
Reolicate 1
Concentration (ug/L ): 3.6
fieolicate 2
Concentration (ug/L ): O.8
Sea. No.: 00111 A/S Pos.: 18
Time: 18:39
Time: 18:42
Date: 11/05/
-------
Mean Cone (ua/L ):
2.2
SD: 1.98
RSD(X): 89-5
Sb ID: 81101.13X2.5
Reolicate 1
Concentration (ug/L ): 4.6
Replicate 2
Concentration (ua/L ): 0.8
Mean Cone (ug/L ): 2.6
Corrected Cone (ua/L ): 6.6
Sea. No.: 00112 A/S Pos.: 19 Date: 11/05,
Time: 18:45
Corrected Cone (ug/L ): 11.4
Time: 18:49
Corrected Cone (ug/L ): 2.1
SD: 2.64
RSD (7.): 97.3.
Sb ID: CCV
Reolicate 1
Concentration (ug/L ): 107.4
Replicate 2
Concentration (ua/L ): 108.9
Sea. No.: OO113 A/S Pos
Time: 18:52
Time: 18:55
Mean Cone (ug/L ): 108.1 SD: 1.09
QC sample is within ranae 79.5 - 120.49
Date: 11/O5
RSD C/.): 1.01
Sb ID: CCB
Replicate 1
Concentration (ug/L ): -0.5
Reolicate 2
Concentration (ua/L ): 2.3
Sea. No.: 00114 A/S Pos
Time: 18:58
Time: 19:01
Mean Cone (ug/L ): 0.9 SD: 2.01
QC sample is within ranae -15.49 - 15.49
Sh TD: 81101.11
Replicate 1
Concentration (ug/L ): 6.3
Date: 11/05,
RSD (7.): 217.:
i i cate 2
Concentration (ug/L ): 4.4
Mean Cone (ua/L ):
Sea. No.: 00115 A/S Pos
Time: 08:39
Time: O8 : 42
17 Date: 11/06>
5.3
SD: 1.32
RSD (7.): 24.6E
Sb ID: 81101.13
Replicate 1
Concentration (ug/L ): -0.3
Replicate 2
Concentration lug/L ): O.O
Sea. No.: OO116 A/S Pos
Time: 08:45
Time: 08:48
19 Date: 11/06/
-------
Mean Cone (uq/L ):
-0.1
SD: O.23
RSDC/C): 154.7
5b ID: CCV
Reolicate 1
Concentration (uq/L ): 109.0
Reoiicate 2
Concentration (ug/L ): 111.1
Sea. No.: 00117 - A/S Pos.
Time: 08:51
Time: OB:54
Mean Cone (uq/L ): 110.O SD: 1.47
QC samole is within ranqe 79.5 - 120.49
"V "V 'V 'V "V *V '\>
Sb ID: CCB
Reolicate 1
Concentration (uq/L ): 3.2
Sea. No.: 00118 A/S Pos.
Time: O8:57
Time: O9:00
Concentration (ug/L ): -1.9
Mean Cone (ug/L ): 0.5 SD: 3.55
QC sample is within ranqe -15.49 - 15.49
Date: ll/06/<
RSD ('/.): 1.34
Date: 11/06/'
RSD(7.): 539. 51
-------
Element File: AS.GEL
Date: 11/04/98
Data File:
Technique: HBA
Element: As
Time: 14:00
ID/Wt File: 811O1.IDW
Calib. Type: Linear
Wavelength: 193,
Slit: 0.70 L
Lamp Current: 0
Energy: 32
As
ID: BLANK
Sea. No.: 00027
Replicate 1
Peak Area (A-s): O.O04
Background Pk Area (A-s): O.O63
Blank Corrected Pk Area (A-s): 0.004
Reolicate 2
Peak Area (A-s): -O.OO5
Background Pk Area (A-s): O.O71
Blank Corrected Pk Area (A-s): -0.005
Mean Pk Area (A-s):
Auto-zero performed.
-0.000
A/S Pos.: 0
Date: 11/04/
Time: 14:00
Peak Height (A): 0.044
Background Pk Height (A): O.087
Time: 14:03
Peak Height (A): O.O4O
Background Pk Height (A): 0.079
SD: O.OO62
RSD C/.): 1609.
As
ID: 10 PPB AS
Sea. No.: OOO28
Reolicate 1
Peak Area (A-s): O.O23
Background Pk Area (A-s): 0.060
Blank Corrected Pk Area (A-s): 0.023
A/S Pos.: 1
Date: 11/04/
Time: 14:06
Peak Height (A): O.O78
Background Pk Height (A): O.O72
Reolicate 2
Peak Area (A-s): O.O12
Background Pk Area (A-s): O.082
Blank Corrected Pk Area (A-s): 0.012
Mean Pk Area (A-s):
0.018
Standard number 1 applied. CIO.00]
Correlation coefficient: 1.OOOOO
Time: 14:09
Peak Height (A): O.O78
Background Pk Height (A): O.078
SD: 0.0080
Slope: O.0018
RSD (7.): 45.14
As
ID: 50 PPB AS
Sea. No.
Replicate 1
Peak Area (A-s): 0.119
Background Pk Area (A-s): O.077
Blank Corrected Pk Area (A-s): 0.120
Concentration (ug/L ): 67.91
Reolicate 2
Peak Area (A-s): 0.119
Background Pk Area (A-s): O.OB2
Blank Corrected Pk Area (A-s): 0.119
Concentration (ug/L ): 67.68
Mean Cone (ug/L ):
67.79
O0029
A/S Pos.: 2
Date: 11/04/
Time: 14:12
Peak Height (A): 0.296
Background Pk Height (A): O.OS6
Time: 14:16
Peak Height (A): 0.322
Background Pk Height (A): O.O7B
SD: 0.164
RSD C/.>: 0.24
Standard number 2 applied. [50.00]
-------
Correlation coefficient: 0.99578
Slope: O.0024
ID: 100 PPB AS
Sea. No.: O0030 A/S Pos.: 3
Replicate 1
Peak Area (A-s): 0.235
Background Pk Area (A-s): 0.084
Blank Corrected Pk Area (A-s): 0.236
Concentration (ug/L ): 99.37
Reolicate 2
Peak Area (A-s): 0.237
Background Pk Area (A-s): O.082
Blank Corrected Pk Area (A-s): O.237
Concentration (uo/L ): 10O.14
Date: il/04/<;
Time: 14:19
Peak Height (A): 0.549
Background Pk Height (A): O.O94
Time: 14:22
Peak Height (A): 0.576
Background Pk Height (A): 0.09S
Mean Cone (ua/L ):
99.75
Standard number 3 applied. [1OO.OO]
Correlation coefficient: 0.99917
SD: 0.546
Slope: O.0024
RSD(7.): 0.55
As
ID: 200 PPB AS
Sea. No.
Replicate 1
Peak Area (A-s): 0.438
Background Pk Area (A-s): 0.085
Blank Corrected Pk Area (A-s): O.438
Concentration (ug/L ): 185.07
Eeolicate 2
Peak Area (A-s): O.491
Background Pk Area (A-s): O.O83
Blank Corrected Pk Area (A-s): 0.491
Concentration (ua/L ): 2O7.55
Mean Cone (ua/L ):
196.31
Standard number 4 applied. [200.001
Correlation coefficient: O.99975
00031 A/S Pos.: 4
Date: li/04/'
Time: 14:25
Peak Height (A): 1.O29
Background Pk Height (A): O.131
Time: 14:28
Peak Height (A): 1.185
Background Pk Height (A): 0.117
SD: 15.895
Slope: O.OO23
RSD(7.): 8.10
-------
1 £j in
a
0.
LSDlag Calibration - C:\fifi USER\fi
^'^
^••^
^ji^' Llncor
O Concentration 200.00
*
^
As ID: ICV
Reolicate 1
Concentration (ug/L ): 1O4.96
Reolicate 2
Concentration lua/L ): 96.37
Sea. No.: 00032 A/S Pos.: 5
Time: 14:36
Time: 14:39
Mean Cone (ug/L ): 1O0.67 SD: 6.069
QC sample is within ranoe 79.50 - 120.49
Date: ll/04/c
RSDC/.): 6.03
As ID: ICB
Reolicate 1
Concentration (ug/L ): 2.O7
Reoiicate 2
Concentration (uo/L ): -1.63
Seo. No.: OOO33 A/S Pos.: O
Time: 14:42
Time: 14:45
Mean Cone (ug/L ): O.22 SD: 2.622
QC samole is within ranoe -5.49 - 5.49
As ID: 81101.B-F
Replicate 1
Concentration (ug/L ): 1.64
Reolicate 2
Concentration (ua/L ): —2.85
Sea. No.: 00034 A/S Pos.: 6
Time: 14:48
Time: 14:51
Mean Cone (ug/L ):
-O.61
SD: 3.178
Date: 11/04/'
RSDC/.): 1196. (
Date: 11/04/'
RSDC/.): 522.9'
-------
hlement File: AS.GEL
Date: ii/04/98
Data File:
Techniaue: HGA
Element: As
Time: 15:16
ID/Wt File: 811O1.1DW
Calib. Type: Linear
Wavelength: 193.7
Slit: 0.70 L
Lamp Current: 0
Energy: 31
As ID: 81101.OB
Replicate 1
Concentration (ug/L ): 1.O3
Reolicate 2
Concentration (ua/L ): 0.09
Sea. No
Mean Cone (ua/L ):
0.56
OO037 A/S Pos.: 7
Time: 15:16
Time: 15:19
SD: O.664
Date: 11/04^
RSD C/.): 118.00
As ID: 81101.UB
Reolicate 1
Concentration (ug/L ): 2.O7
Reolicate 2
Concentration (uo/L ): 5.53
Sea. No.
00038 A/S Pos.: 8 Date: 11/04/9
Time: 15:22 .
Time: 15:25
dean Cone (ua/L ):
3.80
SD: 2.441
RSD(7.): 64.22
As ID: 81101.IB
Reolicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (uo/L ) :
Sea. No,
): -0.65
): 1.O2
O.18
00039 A/S Pos.: 9
Time: 15:28
Time: 15:32
SD: 1.175
Date: 11/04/s!
RSD (7.): 635.85
As ID: 811O1.01
Replicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (ua/L ) :
As ID: 81101.01
Sea. No,
): 4.58
) : 1.54
3.O6
00040 A/S Pos.: 10 Date: 11/04/9
Time: 15:35
Time: 15:38
Sea. No.
Reolicate 1
Concentration (ug/L ): 120.26
Reali cate 2
Concentration lug/L ): 112.76
SD: 2.152
00041 A/S Pos,
Time: 15:41
Time: 15:44
RSD(X): 70.28
1O Date: 11/04/9
-------
Mean Cone (ug/L ):
Recovery is 113.4/1
116.51
SD: 5.304
RSD C/.): 4.55
As ID: 81101.02
Reolicate 1
Concentration (uo/L
Sea. No
icate 2
Concentration (ug/L
Mean Cone (uo/L ):
): 3.25
): 5.35
4.3O
00042 A/S Pos
Time: 15:47
Time: 15:50
SD: 1.485
11 Date: 11/04/
RSDC/.) : 34.52
As
ID: 81101.O3
Sea. No,
Reolicate 1
Concentration (ug/L
neolicate 2
Concentration (ug/L
Mean Cone (ua/L ):
) s 4.47
): 4.92
4.7O
OOO43 A/S Pos,
Time: 15:53
\
Time: 15:57
SD: O.318
12 Date: li/04/
RSD(7.>: 6.77
3 Date: il/04/
As ID: CCV
Replicate 1
Concentration (ug/L ): 105.89
Replicate 2
Concentration (uo/L ): 107.80
Sea. No.: OOO44 A/S Pos,
Time: 16:00
Time: 16:03
Mean Cone (ug/L ): 106.85 SD: 1.349
QC samble is within ranoe 79.50 - 12O.49
RSD (7.) : 1.26
As ID: CCB
Replicate 1
Concentration (ug/L ): -0.18
Replicate 2
Concentration (ua/L ): -0.50
Sea. No.: 00045 A/S Pos.
Time: 16:06
Time: 16:09
Mean Cone (ua/L )
-0.34
SD: 0.229
QC sample is within range -5.49 - 5.49
Date; 11/04/
RSD(7.): 67.71
As ID: 81101.Ul Sea. No.
Replicate 1
Concentration (ua/L ): 28.18
OOO46 A/S Pos,
Time: 16:12
13 Date: 11/04/
Replicate 2
Time: 16:15
-------
Concentration (ug/L ): 28.50
Mean Cone (uq/L ): 28.34
As ID: 81101. U2
Reolicate 1
Concentration (ug/L ): 50.54
Reolicate 2
Concentration (ug/L ): 50.60
Sea. No.
Mean Cone (ug/L ):
50 . 57
SD: 0.223
~~~~~~~~^~~~~~^~
O0047 A/S Pos
Time: 16:18
Time: 16:21
SD: O.O44
RSDC/.): 0.79
14 Date: 11/04/f;
RSD(7.): 0.09
As ID: 81101. U3
Reolicate 1
Concentration (ug/L ): 38.35
Replicate 2
Concentration (ug/L ): 44.35
Sea. No.: 00048 A/S Pos.: 15 Date: 11/04/9
Time: 16:24
Time: 16:27
Mean Cone (ug/L ): 41.35
"V '\* 'V 'V *V 'V 'V *V *V *V ^> ^* ^ ^/*V 'V* 'V 'W ^ ^ ^* *V A* 'V ^ ^ ^ ^ ^ 'V ^ *V ^ ^ *V ^^^ ^
As ID: 81101. U4 Sea. No.:
Reolicate 1
Concentration (ug/L ): 45.67
Replicate 2
Concentration (ug/L ): 47.43
SD: 4.243
RSDC/.): 10.26
00049 A/S Pos.: 16 Date: 11/04/9
Time: 16:30
Time: 16:33
Mean Cone (ug/L ):
46.55
SD: 1.24O
RSDC/.): 2.66
As ID: 81101.11X2.5
Reolicate 1
Concentration (ug/L ): 61.59
Reolicate 2
Concentration (ug/L ): 72.67
Mean Cone (ug/L ): 67.13
Corrected Cone (ug/L ): 167.83
Sea. No.: 00050 A/S Pos.: 17 Date: 11/04/9
Time: 16:36
Corrected Cone (ug/L ): 153.98
Time: 16:39
Corrected Cone (ug/L ): 181.68
SD: 7.835
As ID: 81101.12
Reolicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (ug/L ):
Sea. No.
): 115.51
): 113.86
114.68
00051 A/S Pos,
Time: 16:42
Time: 16:45
SD: 1.164
RSDC/.): 11.67
18 Date: 11/04/9
RSDC/.): 1.02
-------
As ID: 81101.13
Replicate 1
Concentration (ug/L ): 99-73
Reolicate 2
Concentration (ua/L ): 94.06
Sea. No.: 00052 A/S Pos,
Time: 16:48
Time: 16:51
19 Date: li/04/
Mean Cone (ua/L ):
96.90
3D: 4.011
RSD(7.): 4.14
ID: CCV
Reolicate 1
Concentration (ua/L ): 108.50
Sea. No.: 00053 A/S Pos.
Time: 16:54
3 Date: il/04/
icate 2
Concentration (ua/L ): 105.44
Times 16:57
Mean Cone (ug/L )s 106.97 SD: 2.167
QC samole is within ranae 79.50 - 120.49
RSD(7.)i 2.03
As IDs CCB
Replicate 1
Concentration (ua/L ): 2.40
Replicate 2
Concentration (ug/L
Mean Cone (ua/L ):
Sea. No.: OO054 A/S Pos.
Time: 17sOO
Time: 17:03
): 3.37
2.88
SD: 0.689
Date: 11/04/
RSD(7.)s 23.89
QC samole is within ranae -5.49 - 5.49
-------
SMA 400 Analysis Ver. 4.10 Fri 11/13/98 - 09:52:42
hod File
arks: BA
Wt file
PAME>£
PAIMD*
TAMO*
rANE><=
TAMO*
r AlNlD^
*"AMI>£
r AME>^
Name: BA
ONLY
is 81101
*RD 4*1
BA455 EM
*RE> 4* 1
BA455 EM
*Rr> 4*1
BA455 EM
BA455 AV
*RID 4*2
BA455 EM
*RD 4*2
BA455 EM
*RD 4*2
BA455 EM
BA455 AV
*RE> 4*3
BA455 EM
*RD 4*3
BA455 EM
*RD 4*3
BA455 EM
BA455 AV
*RD 4*-*
BA455 EM
*RD 4*-*
BA455 EM
*RD 4*-^
BA455 EM
BA455 AV
Repl icates:3
54
REI=-L_ I GATE
52
55
53.7 SD 1.5
137
REf=-l_ I GATE
132
REF^L I GATE
139
136. 0 SD 3.6
REF>I_ I GATE
1153
REF>L_ I GATE
1187
REF>L_ I GATE
1135
1158.3 SD 26.4
2478
REF>I_ I GATE
2367
2364
2403. O SD 65.0
Read Delay: 65
Data File:
4*± O957 11/13/98
peak— noisy
peak— noisy
4*3
peak-noisy
CV 2.8 CONC O.0200
4*1 O959 11/13/98
4*2
4*3
CV 2.7 CONC O.1000
4*1 1001 11/13/98
~^
4*3
CV 2.3 CONC 1.0000
4*1 10O3 11/13/98
4*2
4*3
CV 2.7 CONC 2.0000
BA455
BA455
EM
EM
15
REF»L_ I GATE
19
4*1 1005 11/13/98
4*2
-------
BA455
BA455
BA455 AV
BA455 CC
EM 1198
EM 1323
BA455 EM
BA455
BA455
16
16.7 SD 2.1 CV 12.5 CONC O.OOOO
0.9997 SLOPE 1184.2531 INT 14.5595
RER1!—I GATE 4*1 1OO7 11/13/98
0.9993 mg/L
REff^L. I CATI
1.1049 mg/L
REF^L. I Cl=fcTI
1.0719 mg/L
1284
AV 1268.3 EM SD
AV 1.O587 mg/L SD
4*S
4*3
64.O CV
0.0540 CV
5.O
5.10
BA455 EM
B
BA455 EM
Bt
BA455 EM
BA455
BA455
28
30
31
REF>1_ I GATE 4*1 10O9 11/13/98
0.0113 mg/L peak-noisy
REF=>L_ I GATE 4*S
0.0130 mg/L peak-noisy
REF=-LIC*=lTE 4*3
0.0139 mg/L peak-noisy
AV 29.7 EM SD
AV 0.0128 mg/L SD
1.5 CV
O.O013 CV
5.1
10.11
t 1 Ol
BA455
1 1O1
BA455
1101
BA455
EM
EM
EM
BA455
BA455
AV
AV
35
I GATE
0.0173 mg/L
4*1
1O11 11/13/98
I GATE
0.0164 mg/L
42
0.0232 mg/L
37.O EM SD
O.O189 mg/L SD
0.0561 mg/L
0.0578 mg/L
BA455 EM 81
BA455 EM 83
BA455 EM 80 0.0553 mg/L
BA455 AV 81.3 EM SD
BA455 AV 0.0564 mg/L SD
BA455 EM 68 0.0451 mq/L
peak-noisy
4*3
peak-noisy
4.4 CV
0.0037 CV
4*1
4*3
1.5 CV
0.0013 CV
E 4* 1
11.8
19.42
1O13 11/13/98
1.9
2.29
1O15 11/13/98
-------
BA455
EM
0.0401 mg/L
BA455
EM 68
BA455 AV
BA455 AV
BA455
BA455
BA455
EM
EM
66
57
EM 56
BA455 AV
BA455 AV
BA455
BA455
BA455
EM
EM
71
7S
EM 69
BA455 AV
BA455 AV
78
EM y^ 69
BA455 AV
RER-LICft-
0.0451 mg/L
66.0 EM SD
0.0434 mg/L SD
0.0434 mg/L
0.0358 mg/L
RER-L. I Crf=V
0.0350 mg/L
59.7 EM SD
0.0381 mg/L SD
0.0477 mg/L
RER-l_IC#V
0.0544 mg/L
REF>l_IC#V
0.0460 mg/L
73.0 EM SD
0.0493 mg/L SD
0.0536 mg^C
TE 4*3
peak -noisy
3.5 CV 5.2
0.0029 CV 6.73
TE 4*1 1018 11/13/98
TE 4*2
TE 4*3
5.5 CV 9.2
O.OO47 CV 12.21
TE 4*1 102O 11/13/98
TE 4*2
peak -noisy
TE 4*3
5.3 CV 7.2
0.0045 CV 9.05
TE 4*1 1O22 11/13/98
peak-noisy
jr
RER-L/CC*=!kTE >*2
0.043j/mg/L /
./i\0460 mg/L >
TTE: 4*3
peak— noisy
AV
P1.0 EM >SD
0.0477 mg/L SD
BA455
BA455
BA455
EM
EM
97
88
0.0696 mg/L
0.0620 mg/L
EM 102
BA455 AV
BA455 AV
0.0738 mg/L
95.7 EM SD
0.0685 mg/L SD
BA455
6.2 CV
O.OO53 CV
E 4*1
I 4*2
=L 4*3
peak-
7.1 CV
O.OO60 CV
Z 4*1
8.8
11.06
1O24 11/13/98
EM
90
0.0637 mg/L
•noisy
7.4
8.75
1026 11/13/98
-------
2D
BA455
BA455
BA455
BA455
:S/
BA455
:V
BA455
:V
BA455
:B
BA455
:O
BA455
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
91
AV
AV
0.0645 mg/L
91.3 EM SD
0.0648 mg/L SD
4*3
peak-noisy
1.5 CV
0.0013 CV
4*1
1.7
1.99
1O2B 11/13/98
106
106
0.0772 mg/L
0.0772 mg/L
REF>l_ICrf=fcTI
0.0789 mg/L
1. 1369 mg/L
108
AV 106.7 EM
AV 0.0778 mg/L
1432
1397 1.1674 mg/L
REF>I_ I
1333 1.1133 mg/L
AV 1387.3 EM SD
AV 1.1592 mg/L SD
34
49
34
RER-U. I
0.0164 mg/L
0.0231 mg/L
AV
AV
O.0164 mg/L
39.0 EM SD
0.02O6 mg/L SD
0.0527 mg/L
REF»I_I
0.0569 mg/L
BA455
EM
77
82
77 0.0527 mg/L
AV 78.7 EM SD
AV 0.0541 mg/L SD
166
4*3
peak-noisy
SD 1.2 CV
SD 0.0010 CV
4*1
1.1
1.25
1O3O 11/13/98
4*3
5O.2 CV
0.0424 CV
3.6
3.66
4*1 1O32 11/13/98
peak-noisy
peak-noisy
4*3
peak-noisy
8.7 CV
0.OO73 CV
E 4* 1
22.2
35.43
1O34 11/13/98
i C^TE:
0. 1279 mg/L
4*3
2.9 CV
0.0024 CV
4*1
3.7
4.50
1O36 11/13/98
4*2
-------
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA4S5
BA455
EM
EM
EM
BA455
BA455
EM
EM
161
I CftTE 4*3
0.1237 mg/L
AV
AV
157.7 EM
0.1208 mg/L
SD 1C.4 CV
SD O.OO88 CV
4*1
6.6
7.27
1038 11/13/98
104
117
0.0755 mg/L
RrEF>L_ I C*=fcTE 4*2
0.0865 mg/L peak
-noisy
100
AV
AV
111
121
REF=-L_I
0.0721 mg/L
107.0 EM SD
0.0781 mg/L SD
REF=>L_I
0.0814 mg/L
E 4*3
8.9 CV
O.OO75 CV
4*1
I C*=fcTE 4*2
0.0899 mg/L
107
REF^L- I
0.0781 mg/L
AV
AV
113.0 EM
0.0831 mg/L
SD
SD
E 4*3
7.2 CV
O.OO61 CV
413
426
REF=>L_ I
0.3474 mg/L
490
AV
AV
499
499
I CftTE 4*±
0.3364 mg/L
4*2
4*3
41.2 CV
0.0348 CV
I C*=fcTE 4*1
0.4091 mg/L
0.4015 mg/L
443.0 EM SD
O.3618 mg/L SD
F>EI=>L- 1
0.4091 mg/L
531
AV
AV
0.4361 mg/L
509.7 EM SD
0.4181 mg/L SD
439
442
IC<=fcT
0.3584 mg/L
REF=>I_I
0.3609 mg/L
4*2
E 4*3
18.5 CV
0.0156 CV
4*1
4*2
8.3
9.62
1040 11/13/98
6.4
7.33
1042 11/13/98
9.3
9.62
1044 11/13/98
3.6
3.73
1047 11/13/98
-------
BA455
BA455
^
BA455 EM
BA45J
EM
-r^, 0.3483 mg/L
AV 436.0 EM SD
AV 0.3559 mg/L SD
1145
1149
7.9 CV
0.OO67 CV
E 4*1
1.8
1.88
1O49 11/13/98
0.9546 mg/L
RE:F>I_ i C^TE:
0.9579 mg/L
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
*MF>L_E:
BA455 EM
1171
AV 1155.0 EM
AV O.9630 mg/L
33
33
I CftTE!
0.9765 mq/L
4*2
4*3
SD 14.0 CV
SD 0.0118 CV
4f=±
1.2
1.23
1O51 11/13/98
0.0156 mg/L
peak-noisy
0.0156 mg/L
33
i C*=»TE:
0.0156 mg/L
peak-noisy
4*3
peak-noisy
AV
AV
33.0 EM
0.0156 mg/L
SD O.O CV
SD 0. OOOO CV
O.O
o.oo
1O53 11/13/98
BA455 EM
mg/L
BA455 EM
636
i c<=n~E!
0.5138 mg/L
RE:F=-I_I
0.5248 mg/L
4*12
4*3
BA455
BA455
AV
AV
O
628.
3
.5183
EM
mg/L
IMF>I_E: 4*2^ REIF-L
BA455
EM
1179
0
.9833
.H
SD
SD
C£*-
6.8 CV
O.OO57 CV
TE: 4*1
1.1
1.11
1O55
mg/L
IMF>I_E: 4*2-i L\J' RE:F>I_IC<=>TE: 4*2
BA455
EM'
1129
) — '
--
kMF>l_E: 4*2-*
BA455
EM-'
BA455
BA455
1162
AV
AV
1
L.
0
156.
0
. 94 1 0
REIR-L
7
.9644
0
. 9689
EM
^
mg/L
.11
C<=T
TE: 4*3
mg/L
\s-
mg/L
SD
SD
25.4 CV
0.0215 CV
2.2
2.23
IMF>I_E: 4*2^
BA455 EM
»MF>L_E: ^
BA455 EM
i C^TE:
0.0189 mg/L
4*±
1O57 11/13/98
33
0.0156 mg/L
peak-noisy
peak-no isy
-------
BA455
BA455
: *t=
BA455 EM
BA455 EM
BA455/ EM
X*
BA455
BA455
BA45
EM
BA455 EM
BA455 EM
BA455
BA455
AV .rz 33.7 EM SD
£^
AV 0.0161 mg/L SD
36 0.0181 mg/L
/-? REF^L
38 // O.O198 mg/L
,43 O.O240 mg/L
'
AV 39. 0 EM SD
AV 0.02O6 mg/L SD
RE:F>L_
39 0.0206 mg/L
/O.O164 mg/L
33 O.O156 mg/L
AV 35.3 EM SD
AV 0.0175 mg/L SD
3.1 CV
O.O026 CV
9.1
15.99
± 1059 11/13/90
window-edge
peak-noisy
=11=3
peak-noisy
3.6 CV
O.OO3O CV
9.2
14.75
± 1101 11/13/93
peak-noisy
peak-noisy
=11=3
peak-noisy
3.2 CV
O.OO27 CV
9.1
15.47
-------
Element File: BE.GEL
Date: 11/10/9S
Data File:
Technioue: HGA
Element: Be
Time: 15:33
ID/Wt File: 81017.IDW
Calib. Type: Linear
Wavelength: 234.9
Slit: 0.~7 L
Lamp Current: 30
Energy: 65
Be
ID: BLANK
Sea. No.: O0177
Replicate 1
Peak Area (A-s): -0.001
Backaround Pk Area (A-s): 0.003
Blank Corrected Pk Area (A-s): -0.001
Reolicate 2
Peak Area (A-s): -0.003
Backaround Pk Area (A-s): O.O03
Blank Corrected Pk Area (A-s): -O.003
Mean Pk Area (A-s):
Auto-zero performed.
-O.OO2
A/S Pos.: 0
Date: 11/1O/
Time: 15:33
Peak Height (A): 0.003
Background Pk Height (A): O.OO5
Time: 15:36
Peak Height (A): O.OO3
Backaround Pk Heiaht (A): O.OO6
SD: O.OO13
RSD ( 7.) : 70 . 52
•V 'V 'V 'V 'V 'V "
Be
ID: 0.5 PPB
Sea. No.: 0017B
Reolicate 1
Peak Area (A-s): 0.012
Background Pk Area (A-s): 0.028
Blank Corrected Pk Area (A-s): 0.014
1 i cate 2
Peak Area (A-s): 0.013
Background Pk Area (A-s): O.O28
Blank Corrected Pk Area (A-s): 0.014
Mean Pk Area (A-s):
O.O14
Standard number 1 applied* [0.50]
Correlation coefficient: l.OOOOO
A/S Pos.: 1
Date: 11/10/
Time: 15:39
Peak Height (A): 0.045
Background Pk Height (A): 0.092
Time: 15:42
Peak Height (A): 0.040
Backaround Pk Heiaht (A): 0.087
SD: O.OO07
Slope: O.O280
RSD (7.): 4. S3
Be
ID:
PPB
Sea. No.: O0179
Reolicate 1
Peak Area (A-s): 0.043
Background Pk Area (A-s): O.104
Blank Corrected Pk Area (A-s): 0.045
Concentration (ua/L ): 1.60
Peak mrea 4 H-S j :
-------
Correlation coefficient: 0.99549
Slope: 0.0235
ID: 5 PPB
Sep. No.: O0180
A/S Pos.: 3
Date: ll/10/i;
Reolicate 1
Peak Area (A-s): O.O99
Background Pk Area (A-s): 0.257
Blank Corrected Pk Area (A-s): 0.100
Concentration (ug/L ): 4.28
Fteoi icate 2
Peak Area lA-s>: 0.104
Background Pk Area (A-s): O.272
Blank Corrected Pk Area (A-s): 0.106
Concentration (ua/L ): 4.50
Mean Cone lua/L ):
4.39
Standard number 3 applied. [5.00]
Correlation coefficient: O.99634
Time: 15:51
Peak Height (A): 0.268
Background Pk Height (A): 0.846
Time: 15:54
Peak Height (A): 0.265
Background Pk Height (A): O.895
SD: 0.156
Slope: 0.0211
RSD(%): 3.56
Be
ID: 10 PPB
Sea. No,
Replicate 1
Peak Area (A-s): 0.142
Background Pk Area (A-s): 0.477
Blank Corrected Pk Area (A-s): 0.144
Concentration (ua/L ): 6.84
OO181 A/S Pos.: 4
Date: 11/10/
Time: 15:57
Peak Height (A): O.255
Background Pk Height (A): 1.365
Peak Area iA-s): 0.142
Background Pk Area (A-s): 0.500
Blank Corrected Pk Area (A-s): 0.144
Concentration (ua/L ): 6.84
Mean Cone (ua/L ):
6.84
Standard number 4 applied. [10.001
Correlation coefficient: O.96222
Time: 16:OO
Peak Height (A): 0.251
Background Pk Height (A): 1.456
SD: 0.001
Slope: 0.0164
RSD(7.): 0.02
ID: 1O PPB
Sea. No.: OO182
Replicate 1
Peak Area (A-s): O.136
Background Pk Area (A-s): 0.504
Blank Corrected Pk Area (A-s): 0.138
Concentration (ug/L ): 8.42
A/S Pos.: 4
Date: 11/10/
Time: 16:04
Peak Height (A): O.253
Background Pk Height (A): 1.498
ica te 2
Peak rtrea i tt-s ) : O.141
Background Pk Area (A-s): 0.500
Blank Corrected Pk Area (A-s): 0.143
Concentration (ug/L ): 8.72
Time: 16:07
Peak Height (A): 0.251
Background Pk Height (A): 1.461
Mean Cone (ua/L ):
8.57
SD: 0.212
RSD(7.):
-------
Standard number 4 applied. [10.00]
Correlation coefficient: 0.95673
Slope: 0.0162
•V "V-~V "v "u -\f 'V*V 'V '*- "V -i- "V 'V **
Be
ID: 5 PPB
Sea. No,
Reolicate 1
Peak Area lA-sj: O.1O3
Background Pk Area (A-s): 0.265
Blank Corrected Pk Area (A-s): 0.105
Concentration (ug/L ): 5.43
Replicate 2
Peak Area iA-s): O.1O1
Background Pk Area (A-s): 0.263
Blank Corrected Pk Area (A-s): 0.103
Concentration (ua/L ): 5.26
Mean Cone (ua/L ):
5.34
Standard number 3 applied. [5.00]
Correlation coefficient: 0.99885
00183
A/S Pos.: 3
Date: 11/10/'
Time: 16:12
Peak Height (A): 0.264
Background Pk Height (A): 0.833
Time: 16:15
Peak Height (A): 0.259
Background Pk Height (A): 0.824
SD: 0.123
Slope: 0.0279
RSD (*/.): 2.3O
"{Display Calibration - C:\AA U5ER\
.141,
D.
X
j— ,•"' Norlln^cr
0 r«r>c
-------
K«=D! i cate 2.
Concentration \uq/L ): O.06
Time: 16:28
Mean Cone (uq/L ): O.04 SD: 0.018
QC samole is within ranae -1.49 - 1.49
RSD(7.): 40.82
Be ID: 81017^CS
Reolicate 1
Concentration (ua/L
Sea. No.: 00186 A/S Pos.
21 Date:
Concentration Udq/L ): 5.16
hean Cone Cua/L ): 5.20
Be ID: B1O17.1-7
Replicate 1
Concentration (i
Keol i cate
Concentration iua/L
Sea. No.: 00187 A/S Pos,
/
Time: 16:37
RSD C/.): 1.09
22 Date: il/10/'
): 0.07
): O.1O
Mean
iuo/L ) :
'.): 21.251
Date: 11/10/1
ID7: 810.17 .1-102S
ID: 81O17.1-7S
Replicate 1
Concentration (uq/.
Replicate 2
Concentration •/uq/L ): 4.72
Mean Cone /ua/L ):
j -V 'V- "«• 'V •"!•'*• "v 'V/V 'V
Be
Reolicate 1
Concentration (uq/L ): 4.22
Pieo i i cate 2
Concentration (ua/L ): 4.35
Mean Cone (ua/L ):
Time: 16:53
SD: 0.097
RSD(*/.): 2.26
ID: 81011. BF
Reolicate 1
Concentration (uq/L ): O . 04
«eoiicate 2
Concentration luq/L ): O . O3
Sea. No
00192 A/S Pos.: 6
Time: 17:02
Time: 17:05
Date: 11/iO/
-------
Mean Cone iua/L ):
O.04
SD: 0.005
R5D(7.) : 12.65
Be ID: 81101.OB
Reolicate 1
Concentration (ug/L ): 0.21
neoiicate 2
Concentration iua/L ): 0.26
Sea. No.
Mean Cone (ua/L )s
0.23
00193 A/S Pos.: 7
Time: 17:08
Time: 17:11
SDs 0.036
Be ID: 81101.UB
Reolicate 1
Concentration (ug/L ): 0.17
Reali cats 2
Concentration (uo/L ): 0.14
Sea. No.: OO194 A/S Pos.: 8
Time: 17:14
Time: 17:17
Mean Cone (ua/L ):
O.16
SD: 0.016
Date: 11/10/
RSD (7.): 15.63
Date: 11/10/
RSD(7.): 10.5=5
Date: 11/10/
Be ID: 81101 , IB
Reolicate 1
Concentration (ug/L
Sea. No.
1 i ca te 2
Concentration (uq/L
Mean Cone iua/L ):
): 0.O6
): O.08
O. O7
00195 A/S Pos,
Time: 17:2O
Time: 17:23
SD: 0.013
• -V 'V *V "v "V 'V-
RSDC/.): 20.2S
Be ID: 81101.01
Reali cate 1
Concentration (uq/L
Sea. No,
i i i c=> te 2
Concentration (ug/L
Mean Cone (ua/L ):
): 0.09
): O.ll
O.1O
00196 A/S Pos,
Time: 17:26
Time: 17:29
SD: O.021
1O Date: 11/1O/
RSD (7.): 21.01
Be ID: 811O1.01
Reolicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean cone tug/L ):
Recovery is 81.27.
Sea. No,
) : 4.19
) : 4.13
4.16
00197 A/S Pos,
Time: 17:32
Times 17:35
SD: O.039
1O Date: 11/10/
RSD(7.): 0.93
-------
Be
ID: CCV
Sea. No,
Replicate 1
Concentration luq/L ): 4=37
i i cate 2
Concentration lug/'L ): 4.45
Mean Cone luo/L ): 4.41
QC sample is within ranae 3.5 - 6.49
00198 A/S Pos,
Time: 17:37
Time: 17:40
SD: 0.06O
•V -V 'V 'V "V 'V.- 'V '\"'\- r-j ~v 'V '
Be ID: CCB
Reolicate 1
Concentration (uq/L ): O.05
rtc?D 1 i cate 2
Concentration lua/L ): O.05
Sea. No.:
Mean Cone (uo/L )
0.05
00199 A/S Pos,
Time: 17:43
Time: 17:46
SD: 0.005
0
QC sample is within ranae -1.49 - 1.49
Date: ll/10/c
RSD ('/.): 1.35
Date: 11/10/
RSD C/.): 10.53
Re ID: 81101.02
Replicate 1
Concentration (uq/L
Kepiicate 2
Concentration (uq/L
Mean Cone tua/L ):
Sea. No,
): 0.24
): 0.30
0.27
OO20O A/S Pos,
Time: 17:49
Time: 17:52
SDj O.O45
11
Date: 11/10/
RSD C/.): 16.79
Be
ID: 81101.03
Replicate 1
Concentration
-------
Be ID: 81101.U2
Reolicate 1
Concentration (ug/L ): 0.74
Reolicate 2
Concentration iuo/L ): 0.74
Sea. No.
Mean Cone (uo/L ):
0.74
00203 A/S Pos,
Time: 18:O6
Time: 18:09
5D: O.OO6
14 Date: 11/1Q/
RSDC/.): 0.76
Be ID: 81101.U3
Replicate 1
Concentration (ug/L ): 0.29
Reoiicate 2
Concentration (uo/L ): 0.29
Sea. No.:
Mean Cone (uo/L ):
0.29
00204 A/S Pos.
Time: 18:12
Time: 18:15
SD: O.005
15 Date: 11/10;
RSDC/.): 1.80
Be ID: 81101.U4
Replicate 1
Concentration (ug/L ): 0.37
Replicate 2
Concentration (ua/L j: 0.30
Seo. No.: 00205 A/S Pos,
Time: 18:18
Time: 18:21
16 Date: 11/10,
Mean Cone iua/'L ):
0.34
SD: O.O49
Be ID: 81101.11
Reolicate 1
Concentration (ug/L ): 3.43
Rep 1 a cate 2
Concentration (ua/L ): 3.50
Sea. No.
Mean Cone lua/L ):
3.47
00206 A/S Pos,
Time: 18:24
Time: 18:26
SD: 0.050
Be ID: 81101.12
Replicate 1
Concentration (ug/L ): 4.70
Reolicate 2
Concentration (uo/L ): 4.62
Sea. No.
Mean Cone iua/L ):
4.66
00207 A/S Pos
Time: 18:29
Time: 18:32
SD: 0.056
Re ID: 81.101.1:
Reolicate 1
Sea. No.
00208 A/S Pos,
Time: 18:35
RSDC/.): 14.4
17 Date: 11/10
RSDC/.): 1.44
IB Date: 11/10
RSD.C/.): 1.20'
19 Date: 11/10
-------
Concentration (ua/L ): 4.68
n cate 2.
Concentration iua/L ): 4.81
Mean Cone (ua/L ):
4.75
Time: 18:38
SD: O.091
Be ID: CCV
Reolicate 1
Concentration (ug/L ): 4.21
RSD(7.): 1.91
Date: 11/10/9
i cate 2
Concentration (ug/L ): 4.43
Sea. No.: OO209 A/S Pos.
Time: 18:41
Time: 18:44
Mean Cone (ug/L ): 4.32 SD: O.158
QC samole is within ranae 3.5 - 6.49
RSD (*/.): 3.66
Be ID: CCB
Reolicate 1
Concentration (ug/L ): O. O4
Replicate 2
Concentration iug./L ): O.O1
Sea. No.: 00210 A/S Pos.
Time: 18:47
Time: 18:49
Date: 11/10/S
Mean Cone lug/L ): . O.03 SD: 0.020
QC samole is within ranae -1.49 - 1.49
RSD (•'/.): 73.96
Be ID: 81017.LB
Realicate 1
Concentration (ug/L /} i -O.O1
fieo1icate
Concentration
Mean Cone ./fuo/L
Sea. No.: 00211 A/S Pos.
Time: 18:52
20 Date: ll/10/(
RSD C/.): 197.0:
Be ./ID: 81O17
Date: 11/10/
Reolicate 1
Concentration (ua/L
Iicate
Concentration
Mean Cone
Re ID: 81017
Date: 11/10/
Reolicate 1
Time: 19:04
-------
Element File: CD.GEL
Date: 11/09/98
Data File:
Techniaue: HGA
Element: Cd
Time: 15:26
ID/Wt File: 81017.IDW
Calib. Type: Linear
Wavelength: 228.8
Slit: 0.7 L
Lamp Current: 5
Energy: 38
Cd
ID: BLANK
Sea. No.: OOO60
A/S Pos.: 0
Date: 11/09/S
Replicate 1
Peak Area (A-s): 0.166
Backoround Pk Area (A-s): 0.062
Blank Corrected Pk Area (A-s): 0.166
Concentration (uq/L ): 3.87
Reolicate 2
Peak. Area (A-s): O.172
Background Pk Area (A-s): 0.086
Blank Corrected Pk Area (A-s): O.172
Concentration (ua/L ): 4.00
Time: 15:26
Peak Height (A): 0.286
Background Pk Height (A): O.051
Time: 15:2B
Peak Height (A): 0.294
Background Pk Height (A)
0.055
Mean Cone (ua/L ):
3.93
SD: 0.093
RSD(7.): 2.37
Auto-zero performed.
Cd
ID: BLANK
Sea. No.: OO061
A/S Pos.: 0
Date: li/09/
Replicate 1
Peak Area (A-s): 0.159
Background Pk Area (A-s): O.OB1
Blank Corrected Pk Area (A-s): -0.011
Concentration (ug/L ): -0.25
Time: 15:31
Peak Height (A): O.296
Background Pk Height (A): 0.047
Cd
ID: BLANK
Sea. No.: OO062
A/S Pos.
Reolicate 1
Peak Area (A-s): 0.098
Backaround Pk Area (A-s): 0.065
Blank Corrected Pk Area (A-s): -0.071
Concentration (ua/L ): -1.66
Time: 15:34
Peak Height (A): O.166
Background Pk Height (A)
Date: 11/09/
0.037
Rf?ol i cate 2
Peak Area (A-s): O.O99
Background Pk Area (A-s): O.O7O
Blank Corrected Pk Area (A-s): -0.07O
Concentration (ua/L ): -1.64
Time: 15:37
Peak Height (A): O.171
Background Pk Height (A)
O.041
Mean Cone (ug/L ):
Auto-zero performed.
-1.65
SD: O.011
RSD(7.): 0.65
Cd
ID: 0.5 PPB CD
Seo. No.: OOO63
A/S Pos.: 1
Date: li/09/
Replicate 1
Peak Area (A-s): 0.124
Time: 15:40
Peak Height (A): O.219
-------
Background Pk Area (A-s): 0.066
Blank Corrected Pk Area (A-s): O.O26
Concentration (ua/L ): 0.60
Background Pk Height (A): 0.038
S
-------
Cd
ID: 10 PPB CD
Sea. No.: OOO66
A/S Pos.: 4
Date: 11/09/
Replicate 1
Peak Area (A-s): 0.630
Backoround Pk Area (A-s): 0.154
Blank Corrected Pk Area (A-s): 0.532
Concentration
-------
Mean Cone lug/L ): -0.07
QC samole is within range
Huto—zero performed.
SD: 0.09
-------
Mean Cone (ua/L ):
4.11
SD: O.267
RSDC/.): 6.50
Date: 11/09/S
Cd
ID: 81017. 2-l<
Reolicate 1
Concentration^ (ua/L ): -O.25
Sea. No.: OOO74 / A/S Pos.: B
9
Time-/ 16:47
Not detected, duolicate is not p"eauired.
Concentration (uq/L }jr -O.15
Mean Cone (ua/L ): -0.20
': 0.071
RSDC/.): 35.48
Cd ID: 81101.11X2.5
Reolicate 1
Concentration (uo/L ): 1.36
Reelicate 2
Concentration (uo/L ): 1.67
Sea. No.: O0075 A/S Pos.: 17 Date: 11/09/
Time: 16:55
Corrected Cone (ug/L ): 3.41
Time: 16:57
Corrected Cone (ua/L ): 4.17
Mean Cone (uq/L ): 1.52
Corrected Cone (ua/L ): 3.79
SD: 0.216
RSDC/.): 14.2
RSDC/.): 10. If
Cd
ID: 81101.OB
Sea. No.
Reolicate 1
Concentration (ua/L
Reolicate 2
Concentration (uq/L
Mean Cone (ua/L ):
Cd ID: CCV
Reolicate 1
Concentration (ua/L
): 0.29
): 0.40
0.34
00078 A/S Pos,
Time: 17:08
Time: 17:11
SD: 0.074
Sea. No
OO079 A/S Pos.: 3
Time: 17:13
Date: 11/09/
RSDC/.): 21.
Date: 11/09-
) : 6.52
Reolicate 2
Time: 17:16
-------
Concentration (ug/L ): 6.70
Mean Cone (ug/L ): 6.61
OC sample is within range
3D: 0.125
Cd
ID: CCB
Sea. No.
Reolicate 1
Concentration (ug/L ): 0.06
Reolicate 2
Concentration (ua/L
)
-0.11
Mean Cone (ug/L ): -0.03
QC sample is within ranae
O008O A/S Pos.: 0
Time: 17:19
Time: 17:22
SD: 0.123
RSD 17.) s 1. 90
Date: ll/09/c
RSD C/.): 472.2
Cd
ID: 81101. UB
Sea. No,
Replicate 1
Concentration (ug/L
Replicate 2
Concentration (ug/L
Mean Cone (ua/L ):
): 1.40
) : 1.75
1 .57
00081 A/S Pos.: 8
Time: 17:24
Time: 17:27
SD: 0.245
Date: 11/09/
RSD C/:): 15.55
Cd
ID: 81101. IB
Reolicate 1
Concentration (ug/L ): O.46
Reolicate 2
Concentration (ua/L ): O.36
Sea. No.: 00082 A/S Pos,
Time: 17:3O
Time: 17:33
Mean Cone (ua/L ):
0.41
SD: 0.073
Date: 11/O9/
RSDC/.): 17. B3
10 Date: 11/O9/
Cd
ID: 81101.01
Sea. No,
Replicate 1
Concentration (ug/L
Reol i cate 2
Concentration (ug/L
Mean Cone (ua/L ):
): O.96
): O.82
0.89
O0083 A/S Pos,
Time: 17:36
Time: 17:38
SD: 0.098
RSDC/.): 11.
Cd
ID: 81101.01
Replicate 1
Concentration (ua/L
Sea. No.: OO084 A/S Pos
Time: 17:41
10 Date: 11/09/
): 6.37
Reoli cate
Time: 17:44
-------
Concentration (uq/L ): 6.48
Mean Cone (ug/L ): 6.42
Recovery is 92.27.
SD: 0.077
RSD C/.): 1.20
Cd ID: 81101.02
Reolicate i
Concentration (ug/L ): 1.20
Realicate 2
Concentration (ua/L ): 1.22
Sea. No.: 00085 A/S Pos.
Time: 17:47
Time: 17:50
11 Date: 11/09/
Mean Cone (uo/L ):
1.21
SD: 0.015
RSD C/.): 1.26
Cd ID: 81101.03
Renlicate 1
Concentration (ug/L ): 0.79
Sea. No.
i cate 2
Concentration (ua/L ): 0.60
Mean Cone
-------
Mean Cone (ua/L ):
4.52
SD: 0.114
RSD C/.): 2.53
Cd
ID: B1101.U4
Reolicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (ua/L ):
Sea. No,
); 4.56
): 4.92
4.74
00090 A/S Pos,
Time: 18:14
Time: 18:17
SD: 0.255
16
Date: 11/O9/C
RSD (7.): 5.39
Cd ID: CCV
Reolicate 1
Concentration (ug/L ): 6.32
Reolicate 2
Concentration (ua/L ): 6.48
Mean Cone (ug/L ): 6.40
QC samole is within range
Sea. No.: OOO91 A/S Pos.: 3
Time: 18:20
Time: 18:22
SD: O.113
Date: 11/O9/'
RSD (7.): i.76
Cd ID: CCB Sea. No.
Replicate 1
Concentration (ug/L ): -0.07
Reelicate 2
Concentration (ug/L ): -0.29
Mean Cone (ug/L ): -0.1B
QC samole is within ranae
00092 A/S Pos,
Time: 18:25
Time: 18:28
SD: O.I53
Date: 11/O9/'
RSD(7.): 86.69
Cd ID: 811O1.I2
Reolicate 1
Concentration (ug/L ): 3.56
Reolicate 2
Concentration (ua/L ): 3.56
Sea. No.:
Mean Cone (ua/L ):
3.56
OOO93 A/S Pos,
Time; 18:30
Time: 18:33
SD: 0.001
IB
Date: li/09/
RSD(7.): O.03
Date: 11/09/
Cd
ID: 81101.13
Sea. No.: OOO94
A/S Pos.: 19
Samole abs. is greater than that of the largest standard.
Reolicate 1 Time: 18:36
Concentration (ug/L ): 27.84
Samo]e abs. is greater than that of the largest standard.
Reolicate 2 Time: 18:39
-------
Cd
ID: 81017.5-7
Reolicate 1
Concentration (uo/L
Sea. No.: OO10O A/S Pos,
Time: 19:10
28 Date: 11/09;
RSD ('/.): 0.08
1icate 2
Concentration (
Date: 11/09/
ea. No.: 00101 A>S Pos.
Time: >9:15
Reolicate 2
Concentration (u
RSD (7.): 94.
SD: O.195
Mean Cone (ua/L ):
Cd
ID: CCV
Reolicate 1
Concentration (ua/L ): 6.3O
Reel. icate 2
Concentration (uq/L ): 6.54
Sea. No.: 00102 A/S Pos.
Time: 19:21
Time: 19:23
Mean Cone (uq/L ): 6.42
QC samole is within ranoe
SD: 0.165
Date: ll/09i
RSD(7.): 2.57
Cd
ID: CCB
Reolicate 1
Concentration (uq/L
Reolicate 2
Concentration (ua/L
Sea. No.: OO103 A/S Pos,
Time: 19:26
): -O.29
): -0.01
Mean Cone (ua/L ): -O.15
DC samole is within ranoe
Time: 19:29
SD: 0.196
Date: 11/09;
RSD (7.): 132.
Cd
Realicate 1
Concentration (uq/L
Reolicate
ConcentrationXlig/L ) :
Mean Cone (ua/L ):
-0.12
A/S Pos.: 30 Date: 11/09
me: 19:31
SD: 0.040
RSD (7.): 42.4
-------
Concentration (ua/L ): -0.27
Reoli ca te 2
Concentration (uq/L
Mean Cone (ua/L ):
Time: 20:07
SD: 0.030
RSD ('/.): 1O.38
Cd
ID: 81017.8-1O2
Sea. No.
Reolicate 1
Concentration (ua/L /):
Reellea te I
Concentration (uq/?L ):
Mean Cone (ua
RSD(X): 8.46
00111 A/S Pos.: 37 Date: 11/09/
Cd
ID: 81017.10-102
Reolicatfe 1
Concentration (uq/L )s
Reolicate 2
Concentration (uq/L ):
Mean Cone (ua/L ):
tb.: 00112 A/S Pos. : 38 Date: 11/O97
Time: 20:15
RSD (7.1: 3.33
Cd
ID: 81017.11/103
Reolicate 1
Concentration (uq/L )s
Replicate 2
Concentration (ua/L ):
Mean Cone (ua/L ):
-0.31
-0.39
OOllX A/S Pos,
"ime: 20:21
Time: 2O:23
SD: O.115
39 Date: 11/09/
RSD (7.): 29.35
Cd ID: CCV
Reolicate 1
Concentration (uq/L ): 6.58
Reoli cate 2
Concentration (ua/L ): 6.4O
Sea, No.
Mean Cone (ua/L )
QC samole is within ranae
6.49
00114 A/S Pos,
Time: 20:26
Time: 2O:29
SD: 0.131
Date: 11/09/
RSD ('/.): 2.02
Date: 11/09/
Cd ID: CCB
Reolicate 1
Concentration (uq/L ): -0.17
Sea. No.: 00115 A/S Pos.: 0
Time: 20:32
-------
Reoil cats 2
Concentration (ug/L ): -0.06
Mean Cone (ug/L ): -0.12
QC sample is within range
Time: 20:34
SD: 0.080
RSD(7.) : 68.12
ID: 81.101.13X5
Sea. No.: 00116 A/S Pos. : 19 Date: 11/10/
Sample abs. is greater/than that
Replicate 1
Concentration (ug/L./): 15.85
Sample abs. is greater than th;
Replicate 2
Concentration/1 uo/L ): 15..
Sample abs/ is greater tnan that
Mean Cone (ug/L ): / 15.81
Corrected Cone (ua/L ): 79.1
of the largest standarc
Time: 08:34
Corrected Copfc (ug/L ): 79.3
of the largest/standard.
Time:yOB:37
Corr^ected Cone (uo/L ): 78.8
of
largest standard.
SD: 6.063
RSD (*/.): 0.40
Cd
ID: 81101.13X20
Sea. No.
Replicate \
Concentration (ug/L
Replicate 2
Concentration (ug/L
Mean Cone (ug/L ):
Corrected Cone (ua/L
): 5.11
): 5.06
5.09
): 1O1.7
00117 A/S Pos.: 19 Date: 11/10/
Time: 08:40
Corrected Cone (ug/L ): 102.3
Time: 08:42
Corrected Cone (ua/L ): 101.2
SD: 0.038
RSD CO: 0.75
Cd
ID: CCV
Sea
Replicate 1
Concentration (ua/L ): 6.96
Concentration (ug/L ): 6.36
Mean Cone (ug/L ): 6.66
QC sample is within ranae
No.: 00118 A/S Pos.: 3
Time: O8:45
Time: 08:48
SD: 0.422
Cd
ID: CCB
Replicate 1
Concentration (ug/L ): O.ll
Replicate 2
Concentration (ua/L ): O.O9
Mean Cone (ug/L
Sea. No.: 00119 A/S Pos.: 0
Time: 08:51
Time: 08:53
0.10 SD: 0.016
Date: 11/10/
RSDC/.): 6.34
Date: 11/10/i
RSD C/.): 15.65
QC sample is within ranae
-------
Element File: CR.GEL
Date: 11/10/98
Data File:
Techniaue: HGA
Element: Cr
Time: 09:16
ID/Wt File: 81017.IDW
Calib. Type: Linear
Wavelength: 357.9
Slit: 0.7 L
Lamp Current: 14
Energy: 56
Cr
ID: BLANK
Sea. No.: 00120
Replicate 1
Peak Area (A-s): 0.02B
Background Pk Area (A-s): 0.030
Blank Corrected Pk Area (A-s): 0.028
Reolicate 2
Peak Area (A-s): 0.014
Background Pk Area (A-s): 0.034
Blank Corrected Pk Area (A-s): 0=014
Mean Pk Area (A-s):
Auto-zero performed.
O.O21
A/S Pos.: 0
Date: 11/10/
Time: 09:16
Peak Height (A): 0.020
Background Pk Height (A): O.O32
Time: 09:19
Peak Height (A): 0.02O
Background Pk Height (A): O.026
SD: O.OO99
RSD (•/.): 46.92
Cr
ID? 1O PPB
Sea. No,
Reolicate 1
Peak Area (A-s): 0.091
Backoround Pk Area (A-s): 0.029
Blank Corrected Pk Area (A-s): 0.07O
Reolicate 2
Peak Area (A-s): 0.094
Background Pk Area (A-s): 0.032
Blank Corrected Pk Area (A-s): 0.073
Mean Pk Area (A-s):
O.O72
Standard number 1 applied. [1O.O]
Correlation coe-f i i cient: 1 . OOOOO
O0121
A/S Pos.: 1
Dates 11/1O/
Time: 09:22
Peak Heiaht (A): 0.064
Backaround Pk Heiaht (A): O.O26
Times 09:25
Peak Height (A): 0.065
Backaround Pk Heiaht (A): O.O21
SD: 0.002O
Slope: O.OO72
RSD C/.)'. 2.86
Cr
ID: 20 PPB
Sea. No,
Replicate 1
Peak Area (A-s): 0.178
Background Pk Area (A-s)s 0.03B
Blank Corrected Pk Area (A-s): 0.157
Concentration (ug/L ): 21.9
Reali cate 2
Peak Area (A-s): 0.182
Background Pk Area (A-s): O.O4O
Blank Corrected Pk Area (A-s): 0.161
Concentration (uo/L ): 22.5
Mean Cone (ug/L ): 22.2
Standard number 2 applied. £20.01
O0122
A/S Pos.: 2
Date: 11/1O/
Time: 09:29
Peak Height (A): 0.115
Background Pk Height (A): O.023
Time: 09:32
Peak Height (A): 0.117
Backaround Pk Heiaht (A): O.O29
SD: 0.39
RSD ( 7.) : 1 . 76
-------
Correlation coe-f f icient: O. 99168
Slope: O.007B
Cr
ID: 50 PPB
Sea. No.: 00123
A/S Pos.: 3
Date: 11/10/
Replicate 1
Peak Area (A-s): 0.415
Background Pk Area (A-s): O.048
Blank Corrected Pk Area (A-s): O.393
Concentration (ug/L ): 5O.4
Replicate 2
Peak Area (A-s): 0.424
Background Pk Area (A-s): O.049
Blank Corrected Pk Area (A-s): O.4O2
Concentration (uo/L ): 51.6
Time: 09:35
Peak Height (A): O.274
Background Pk Height (A): 0.024
Time: 09:38
Peak Height (A): O.258
Background Pk Height (A): O.O26
Mean Cone (ug/L ):
51.0
SD: 0.82
RSD(7.): 1.61
3 §pp}ipd. [50.O]
Correlation coefficient: O.99943
Slope: O.0079
Date: 11/10/'
Cr
ID: 100 PPB
Sea. No,
00124
A/S Pos.: 4
Replicate 1
Peak Area (A-s): 0.840
Backaround Pk Area (A-s): O.066
Blank Corrected Pk Area (A-s): O.819
Concentration (ug/L ): 103.2
Replicate 2
Peak Area (A-s): 0.883
Background Pk Area (A-s): O.069
Blank Corrected Pk Area (A-s): O.862
Concentration (ug/L ): 1O8.6
Time: 09:41
Peak Height (A): 0.483
Background Pk Height (A): 0.031
Time: 09:44
Peak Height (A): 0.502
Background Pk Height (A): O.O33
Mean Cone (ug/L ):
105.9
Standard number 4 applied. [100.0]
Correlation coefficient: O.99914
SD: 3.83
Slope: O.0083
RSDC/.): 3.62
*iOispiay CaliEfation - C:\ftft USERXftfi
b.*40
£3*4
„-"
.*£!.
0.0
Iriear
100.0
-------
Cr ID: ICV
Reolicate i
Concentration (uq/L ): 52.3
Reolicate 2
Concentration (ua/L ): 49-5
Sea. No.: 00125 A/S Pos.
Time: 09:57
Time: 10:OO
Mean Cone (uq/L ): 50.9 SD: 1.94
QC sample is within ranae 39-51 - 60.49
Date: ll/10/c
RSD C/.): 3.81
Cr ID: ICB
Reolicate 1
Concentration (uq/L ): 2.0
Reoi i cate 2
Concentration (ua/L ): -0.0
Sea. No.: O0126 A/S Pos.
Time: 10:03
Time: 10:06
Mean Cone (ug/L ): 1.0 SD: 1.42
QC samole is within ranae -1O.49 - 10.49
Date: 11/10/
RSD(7.) : 143.1
Date: 11/10/
Cr ID: 81101.BF
Reolicate 1
Concentration (ug/L ): 3.6
Reolicate 2
Concentration (uq/L ): 3.5
Mean Cone (ua/L ):
Sea. No.: O0127 A/S Pos.
Time: 10:O9
Time: 10:12
3.6
SD: 0.05
RSD C/.): 1.40
Cr ID: 81101.OB
Reolicate i
Concentration (uq/L ): 18.8
Reelicate 2
Concentration (ua/L ): 19.2
Sea. No.: OO128 A/S Pos.
Time: 10:15
Time: 1O:18
Mean Cone (ua/L ):
19.0
SD: 0.27
Date: 11/iO/
RSD (7.): 1.40
Date: 11/10/
Cr ID: 81101.UB
Reolicate i
Concentration (uq/L
Reo1icate 2
Concentration (uq/L
Mean Cone (ug/L ):
Sea. No,
): 14.8
): 13.5
14.2
00129 A/S Pos,
Time: 10:22
Time: 10:25
SD: 0.89
8
RSD (7.): 6.31
-------
Cr ID: 81101.IB
Replicate 1
Concentration (ua/L ): 12.3
Reolicate 2
Concentration (ug/L ): 11-9
Sea. No.
Mean Cone (ua/L ):
12.1
00130 A/S Pos.: 9
Time: 10:28
Time: 10:31
SD: 0.26
Date: 11/iO/i
RSD(7.): 2.12
Cr ID: 81101.01
Replicate 1
Concentration (ug/L ): 18.2
Replicate 2
Concentration (ua/L ): 18.8
Sea. No.: 00131 A/S Pos.: 10
Time: 10:34
Time: 10:37
Date: 11/10/1
Mean Cone (ua/L ): 18.5
SD: 0.43
RSD ('/.)! 2.35
Date: 11/10/1
Cr ID: 811O1.D1
Replicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (ug/L ):
Recovery is 92.57.
Sea. No,
): 63.3
) : 66.1
64.7
00132 A/S Pos.: 10
Time: 10:40
Time: 10:44
SD: 1.96
RSD (7.): 3.04
Cr ID: 81101.02
Replicate 1
Concentration (ua/L
Sea. No.
): 3O.4
Reolicate 2
Concentration (ua/L ): 30.0
Mean Cone (ua/L ):
30.2
00133 A/S Pos,
Time: 10:47
Time: 10:50
SD: 0.29
11
Date: 11/10/
RSD (7.): 0.97
Date: 11/10/i
Cr ID: 81101.03
Reolicate 1
Concentration (ug/L ): 34.7
Replicate 2
Concentration (ua/L ): 34.7
Sea. No.: 00134 A/S Pos,
Time: 10:53
Time: 10:56
12
Mean Cone (ua/L
34.7
SD: 0.01
RSD(7.): 0.03
-------
Cr ID: CCV
Replicate i
Concentration (ua/L ): 49.0
Reali cate 2
Concentration (ua/L ): 50. 5
Sea. No.: 00135 A/S Pos.
Time: 10:59
Time: 11:02
Mean Cone (ua/L )
49.8
SD: 1.02
QC sample is within ranae 39.51 - 6O.49
Date: 11/10/'
RSD(7.): 2.04
Cr ID: CCB
Replicate 1
Concentration (ua/L ): 0.7
Rep j i cate 2
Concentration (ua/L ): -0.6
Sea. No.: 00136 A/S Pos,
Time: 11:05
Time: 11:OB
Mean Cone (ug/L ): 0.0 SD: 0.92
QC sample is within ranae -10.49 - 10.49
Date: 11/107
RSD (7.): 2O47.
Cr ID: 81101.Ul
Replicate 1
Concentration (ug/L
Replicate 2
Concentration (ug/L
Mean Cone (ua/L ):
Sea. No,
): 50.6
): 52.6
51.6
00137 A/S Pos,
Time: 11:11
Times 11:14
SD: 1.40
13 Date: 11/1O/
RSDC7.): 2.72
Cr ID: 81101.U2 Sea. No.
Replicate 1
Concentration (ug/L ): 106.0
Replicate 2
Concentration (ua/L ): 108.2
Mean Cone (ua/L
107.1
00138 A/S Pos,
Time: 11:17
Time: 11:20
SD: 1.52
14 Date: 11/1O/
RSD (7.): 1.42
Cr ID: 81101.U3
Replicate 1
Concentration (ug/L
Replicate 2
Concentration (ug/L
Mean Cone (ug/L ):
Sea. No,
): 67.7
): 66.7
67.2
00139 A/S Pos.: 15
Time: 11:23
i
Time: 11:26
SD: 0.69
Date: 11/1O/
RSD (7.): 1.O3
-------
Cr ID: 81101. U4 Sea. No.: O014O A/S POB . : 16 Date: 11/10/
Reolicate 1 Time: 11:29
Concentration (ug/L ): 57.8
Replicate 2 Time: 11:32
Concentration (ug/L ): 57.4
Mean Cone (ug/L ): 57.6 SD: O.24 RSDC/.): 0.42
Cr ID: 81101.11X2.5 Sea. No.: 00141 A/S Pos.: 17 Date: 11/10/
Replicate 1 Time: 11:35
Concentration (ug/L ): 52.4 Corrected Cone (ug/L ): 131.0
Replicate 2 Time: 11:38
Concentration (ug/L ): 50.5 Corrected Cone (ug/L ): 126.2
Mean Cone (ua/L ): 51.4 SD: 1.34 RSDC/.): 2.61
Corrected Cone (ug/L ): 128.6
Cr ID: 81101.12X2.5 Sea. No.: O0142 A/S Pos.: 18 Date: 11/10/i
Replicate 1 Time: 11:41
Concentration (ug/L ): 45.6 Corrected Cone (ug/L ): 114.1
Replicate 2 Time: 11:44
Concentration (ug/L ): 48.8 Corrected Cone (ug/L ): 122.1
Mean Cone (ug/L ): 47.2 SD: 2.26 RSDC/.): 4.79
Corrected Cone (ug/L ): 118.1
Cr ID: 81101.13X2.5 Sea. No.: 00143 A/S Pos.: 19 Date: 11/10/i
Replicate 1 Time: 11:47
Concentration (ug/L ): 39.8 Corrected Cone (ug/L ): 99.4
Replicate 2 Time: 11:50
Concentration (ug/L ): 38.9 Corrected Cone (ug/L ): 97.2
Mean Cone (ug/L ): 39.3 SD: 0.63 RSDC/.): 1.61
Corrected Cone (ua/L ): 98.3
. 'V -V 'V -V -V <
Cr ID: CCV Sea. No.: O0144 A/S Pos.: 3 Date: 11/10/1
Reolicate 1 Time: 11:53
Concentration (ug/L ): 50.1
icate 2 Time: 11:57
Concentration vuo/L ): 51.5
Mean Cone (uq/L ): 50.8 SD : 0'.96 RSDC/.): 1.90
DC samole is within range 39.51 - 60.49
-------
Cr ID: CCB
Reolicate 1
Concentration (ug/L ): 1.9
Keelicate 2
Concentration tua/L ): O.2
Sea. No.: 00145 A/S Pos.: 0
Time: 12:00
Times 12:03
Date: 11/10/
Mean Cone (uq/L ): 1.0 SD: 1.20
QC samole is within ranae -10.49 - 10.49
RSD ('/.): 117.6
Cr TD: 81017. LB
Sea. No.: 0014
-------
3MA 400 Analysis Ver. 4.10 Tue 11/10/98 - 11:45:05
od File Name: CO
rks:
t file is 81101
tf=kNE>tf=kRr> 4*1
C0228 EM
AMDARD 4*1
C0228 EM
AIMDARD 4*1
C0228 EM
C0228 AV
tf=*NDARE> 4+2
C0228 EM
AMDARD 4+2
C0228 EM
ANDARD 4+2
C0228 EM
CO228 AV
AMDARD 4*3
C0228 EM
AMDARD 4*3
C0228 EM
AMDARD 4*3
CO228 EM
CO228 AV
ANDARD 4+-*
C0228 EM
AND<=kRE> 4+-*
C0228 EM
ANDARD 4*-*
C0228 EM
C0228 AV
Repl icates:3
REF*!- I Crf=fcTE
474
REF>L_ I C*=*TE
491
REF"L_ I Crf=*nTE
482
482.3 SD 8.5
REF*I_ I C^TE
691
REF"!— I Crf=fcTE
663
REF^L. I CftTE
690
681.3 SD 15.9
REF>I_ I C^TE
1694
REF>L I C*=*nTE
1659
REF>I_ I C^TE
1655
1669.3 SD 21.5
REF"!— I CftTE
2896
REF>1_ Z C«TE
2936
REF>I_ I C^TE
2988
2940.0 SD 46.1
Read Delay: 60
Data File:
4*1 1148 11/10/98
peak -noisy
4+2
4+3
CV 1.8 CONC 0.0200
4+± 1150 11/10/98
peak -noisy
4+2
4+3
peak-noisy
CV 2.3 CONC 0.1000
4+1 1152 11/10/98
4+2
4+3
CV 1.3 CONC 0.5000
4+1 1153 11/10/98
4+2
4+3
CV 1.6 CONC 1.0000
C022B
EM
36
1155 11/1O/98
C022B
EM
I CftTE 4+2
436
-------
i-=:t=.»—'i i*_-*-^» i t=- :tf^=i
C022B EM 385
C0228 AV 395.3 SD 36.6 CV 9.3 CONC
C0228 CC 0.9999 SLOPE 2520.5386 INT 417.0122
o.oooo
+1= ±
1157 11/1O/98
C0228 EM
V
C0228 EM
iv>
C0228 EM
C0228
CO228
B
C0228 EM
B
C0228 EM
C0228
C0228
C0228
C0228
EM
EM
EM
C0228
C0228
EM
0.5102 mg/L
RE:F>I_I
0.4709 mg/L
1703
1604
1708 0.5122 mg/L
AV 1671.7 EM SD
AV 0.4978 mg/L SD
436
419 0.0008 mg/L
RE:F>I_ i GATE:
I 4*3
58.7 CV
0.0233 CV
3.5
4.67
0.0075 mg/L
4*± 1159 11/10/98
peak-noisy
peak -noisy
C0228
1 Ol
C0228
±O1
C0228
1O±
C0228
EM
C0228
CO228
_ BF-
EM
. BF-
EM
- BF-
EM
CO228
C0228
417 -0 . 0000
AV 424.0 EM
AV O.O028 mg/L
REIF*!.
4 1 5 -0 . 0008
FSETF^L.
4 1 9 0 . 0008
REIF*!-
390 -0.0107
AV 4O8.0 EM
AV -0.0036 mg/L
mg/L
SD
SD O.
. IC*=*TE;
mg/L
IC^TE:
mg/L
. IC^TE:
mg/L
SD
SD 0.
peak -noisy
10.4 CV 2.5
0041 CV 149.41
4*± 12OO 11/1O/98
peak -noisy
4*S
peak -noisy
4*3
peak -noisy
15.7 CV 3.9
0062 CV 174.39
RE:F>I_ i C^TE: 4*1
1202 11/10/99
417
408
426
-0.0000 mg/L
REIF>1_
-0.0036 mg/L
peak -noisy
0.0036 mg/L
AV 417.0 EM SD
AV -0.0000 mg/L SD
402 -0.0060 mg/L
peak -noisy
4*3
window-edge
9.O CV 2.2
0.0036 CV 73912.78
E 4*1 12O4 11/10/98
window-edge
-------
C0228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228 EM
CO228
C0228
I C*=*TE 41=3
398 -0.0075 mg/L peak-noisy
AV 4O3.3 EM
AV -0.0054 mg/L
411
400
SD 6.1 CV 1.5
SD O.O024 CV 44.67
-0.0024 mg/L
± 1206 n/io/98
peak-noisy
i GATE:
-0.0067 mg/L
REF>I_ I
-0.0087 mg/L
AV 4O2.0 EM
AV -O.O060 mg/L
peak-noisy
4*3
peak-noisy
SD 8.2 CV 2.O
SD 0.0032 CV 54.52
C0228 EM
C0228 EM
C0228 EM
CO228
C0228
S
C0228 EM
S
CQ22S EM
S
C0228 EM
C0228
CO228
437
412
O.0079 mg/L
REF>L_ i
-0.0020 mg/L
4* ± 12O7 11/1O/98
peak-noisy
peak-noisy
I Crf=fcTE 41=3
416 -0.0004 mg/L peak-noisy
AV 421.7 EM
AV O.O018 mg/L
2608
2617
SD
SD
0.8693 mg/L
13.4 CV
0.0053 CV
E 4*±
4*12
0.8728 mg/L
i GATE:
0.8780 mg/L
2630
AV 2618.3 EM SD
AV 0.8734 mg/L SD
11.1 CV
O.O044 CV
3.2
288.51
12O9 11/10/98
O.4
O.5O
C0228 EM
C0228 EM
C0228 EM
C0228
C0228
407
410
FS
-0.0040 mg/L
RE:F>I_ i
-0.0028 mg/L
RE:F>I_ i
-0.0060 mg/L
402
AV 4O6.3 EM SD
AV -O.O042 mg/L SD
F?EF*I_ I
41= ± 1211 11/1O/98
window-edge
peak-noisy
41=3
peak-noisy
4.0 CV
0.0016 CV
I 41= 1
1.0
37.85
1213 11/.10/98
-------
C022S EM
C0228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228 EM
C0228
C0228
:V
C0228 EM
:V
C0228 EM
:V
C0228 EM
C0228
C0228
:B
C0228 EM
C0228 EM
:B
C0228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228 EM
C0228
C0228
40;
I GftTE 4*:2
-0.0060 mg/L peak-noisy
424
AV 4O8.7 EM
AV -O.OO33 mg/L
391
391
I C^TE 4*3
0.0028 mg/L peak -noisy
SD 13.3 CV 3.3
SD O.OO53 CV 159.57
I Cl=*"TE
-0.0103 mg/L
± 1214 11/1O/98
peak-noisy
394
AV 392.O EM
AV -O.OO99 mg/L
1905
1907
I GATE
-0.0103 mg/L
RERLI
-0.0091 mg/L
peak-noisy
4*3
peak-noisy
SD 1.7 CV
SD O. OO07 CV
I GATE 4* 1
0.5903 mg/L
O.4
6.92
1216 11/1O/98
RERL- I
O.5911 mg/L
RERl_IGrf=k~TE 4*3
0.5971 mq/L
1922
AV 1911.3 EM SD
AV O.5929 mg/L SD
9.3 CV
O.OO37 CV
RERL-I GATE 4*1
0.5
0.62
1218 11/10/98
421
441
0.0016 mg/L
425
AV 429.0 EM
AV O.OO48 mg/L
389
408
0.0095 mg/L
RERLI
0.0032 mg/L
window-edge
4*2:
peak-noisy
4*3
peak-noisy
SD 1O.6 CV 2.5
SD O.OO42 CV 88.28
-0.0111 mg/L
4*± 122O 11/1O/98
window-edge
REF>L I C*=fcTE 4*2
434
AV 41O.3 EM
AV -O.OO26 mg/L
-0.0036 mg/L
RER*I_ I
0.0067 mg/L
peak-noisy
4*3
peak-noisy
SD 22.6 CV
SD 0.0090 CV
ICftTE 4*1
5.5
338.24
1221 11/1O/98
-------
C022S EM
406
-0.0044 mg/L
peak-noisy
C0228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228 EM
C0228
CO228
C0228 EM
C0228 EM
C0228 EM
CO228
CO228
C0228 EM
C0228 EM
C0228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228 EM
C0228
C0228
C0228 EM
425
AV 415.7 EM
AV -0.0005 mg/L
414
443
i CATE: 4*3
0.0032 mg/L peak-noisy
SD 9.5 CV 2.3
SD 0.0038 CV 706.37
-0.0012 mg/L
4*1 1223 11/10/98
peak-noisy
0.0103 mg/L
404
AV
AV
-0.0052 mg/L
42O.3 EM SD
O.O013 mg/L SD
peak-noisy
4*3
peak-noisy
2O. 3 CV
O.OO8O CV
4.8
6O9.93
408
419
-O.O036 mg/L
4*1 1225 n/io/98
peak -noisy
431
RE:F>I_ i C^TE: 4*2
0.0008 mg/L window-edge
4*3
peak-noisy
AV
AV
0.0055 mg/L
419.3 EM SD
O.OO09 mg/L SD
11.5 CV
O.OO46 CV
2.7
495.60
525
446
I C«=kTI
0.0428 mg/L
RE:F>I_ i
0.0115 mg/L
4*1 1227 11/1O/98
peak-noisy
465
I GATE 4*3
0.0190 mg/L peak-noisy
AV
AV
478.7 EM SD
0.0245 mg/L SD
REF>l_I
0.02.O2 mg/L
41.2 CV
0.0164 CV
8.6
66.88
0.0186 mg/L
468
464
468 0.0202 mg/L
AV 466.7 EM SD
AV 0.0197 mg/L SD
REF>I
444 0.0107 mg/L
44= ± 1228 11/10/98
peak-noisy
I 4*3
peak-noisy
2.3 CV O.5
0.0009 CV 4.65
4*1 123O 11/1O/98
peak-noisy
-------
l.l . 1.11 •+ / IllQ/ U
— I'lO i iiy
C0228
:V
C0228
C0228
EM
CO228
C0228
EM
EM
470
AV
AV
0.0210 mg/L
456.0 EM SD
O.O155 mg/L SD
1918
1969
4*3
peak-
13.1 CV
0.0052 CV
I C*=kTE 4*1
0.5955 mg/L
RER-L. i c*=fc-TE 4*2
0.6157 mg/L
4*3
•noisy
2.9
33.64
1232 11/10/98
C0228
;B
C0228
XB
C0228
:B
C0228
*MF>I_E
C0228
*MI=I_E
C0228
*MF»I_E
C0228
*MF>I_E
C0228
*MF>L_E
C0228
*MF>L_E
C0228
kMR-LE
C0228
EM
CO22B
CO228
EM
EM
EM
CO228
C0228
E 4*23
EM
E 4*23
EM
E 4*23
EM
CO228
C0228
E 4*2^
EM
E 4*2-*
EM
E 4*2-*
EM
CQ228
C0228
E 4*25
EM
1957 0.6110 mg/L
AV 1948.0 EM SD
AV 0.6074 mg/L SD
F£EF>i_ I C<=fc
433 0.0063 mg/L
REF>I_ I C<=V
427 0.0040 mg/L
RERI_IC:<=k
439 0.0087 mg/L
AV 433.0 EM SD
AV O.O063 mg/L SD
REF>L_IC*V
443 0.0103 mg/L
REF"I_ I C#V
433 0.0063 mg/L
RER-|_ICrf=V
433 O.OO63 mg/L
AV 436.3 EM SD
AV 0.0077 mg/L SD
REF"I_ I C*V
442 0.0099 mg/L
REF"I_ I Crf=T
440 0.0091 mg/L
26.7 CV 1.4
0.01O6 CV 1.74
TE 4*1 1234 11/1O/98
peak -noisy
TE 4*2
peak -noisy
TE 4*3
peak-noisy
6.0 CV 1.4
O.O024 CV 37.53
TE 4*1 1236 11/1O/98
peak -noisy
TE 4*2
peak -noisy
TE 4*3
peak-noisy
5.8 CV 1.3
O.O023 CV 29.88
TE 4*1 1237 11/1O/9B
peak -noisy
TE 4*2
peak-noisy
REF>L_ICftTE 4*3
444 0.0107 mg/L
AV 442. O EM SD
AV O.0099 mg/L SD
REF>l_ICrf=^
435 0.0071 mg/L
peak -noisy
2.0 CV O.5
O.0008 CV 8.0O
TE 4*1 1239 11/1O/98
peak -noisy
-------
3MA 400 Analysis Ver. 4.10 Tue 11/10/98 - 10:35:45
od File Name: CU
rks: CU ONLY
t file is 81101
^^. BV • T^ J^N. rr^ w"\ i i *f
W~t m ^9 M^f W*~m m^t. JL-J 'WT JL.
CU324 EM
CU324 EM
CU324 EM
CU324 AV
CU324 EM
CU324 EM
CU324 EM
CU324 AV
ANE>AR£> 4*3
CU324 EM
ANDARD 4*3
CU324 EM
ANDARD 4*3
CU324 EM
CU324 AV
ANDARD 4*<*
CU324 EM
ANE>tf=kRD 4*4
CU324 EM
ANDARD 4*-*
CU324 EM
CU324 AV
ANK
Repl icates:3
1584
1541
1566
1563.7 SD 21.6
RER-L I CATE
2695
2822
2763
276O.O SD 63.6
f ^ f^^ t' ^ • ^f ^™^ ^^^_ ^^r* cm^
• "^ C^^. W ^^^ J» ^ ~ V^^ • K^«_
9111
8706
9401
9072.7 SD 349.1
17138
17811
RERL_ I Cft~TE
17786
17578.3 SD 381.5
RER-I- I CftTE
Read Delay: 60
Data File:
4*1 1O39 11/1O/98
peak -noisy
4*2
4*3
CV 1.4 CONC O.0200
4*1 1O41 11/1O/98
4*2
4*3
CV 2.3 CONC O.1000
4*1 1O42 11/10/98
4*2
4*3
CV 3.8 CONC O.5OOO
4*1 1O44 11/10/98
4*2
4*3
CV 2.2 CONC 1.0000
4*1 1046 11/10/98
CU324 EM 1262
CU324 EM
RER-L I
1156
4*2
-------
- - III
.268
CU324 AV
CU324 CC
1228.7 SD 63.0 CV 5.1 CONC O.OOOO
0.9998 SLOPE 16298.754 INT 1159.8701
4* ± 1048 11/10/98
CU324
CU324
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
9139
9198
RE:F>L_ i C^TE:
0.4896 mg/L
R:E:F>I_ i C^TE:
0.4932 mg/L
REIFJ-L i C*=ITE:
0.5151 mq/L
4*12:
4*3
9555
AV 9297.3 EM SD
AV O.4993 mg/L SD
225.1 CV
O.O138 CV
2.4
2.77
1296
126
R£EIF>1_ I C<=lTE
0.0084 mg/L
RE:F>L_ I Crf=»TE:
0.0063 mq/L
4*1 1049 11/10/98
peak-noisy
4*:2
peak-noisy
CU324
. ±O±
CU324
. ±O ±
CU324
L ±O ±
CU324
EM
CU324
CU324
EM
. BF~
EM
_ BF"
EM
CU324
CU324
1328
AV
AV
1329
1313
1299
AV
AV
0.0103 mg/L
1295.3 EM SD
O.OO83 mg/L SD O.
F^EZF*!— i C^TE:
0.0104 mg/L
RE:F>I_ i C^TE:
0.0094 mg/L
REIF^L, i C^TE:
0.0085 mg/L
1313.7 EM SD
O.OO94 mg/L SD O.
peak -noisy
33 . 0 CV
2
0020 CV 24 .:
4* 1 1
4*2
peak-noi
4*3
15. O CV
0009 CV
05
sy
1
9.
1051 11/1O/98
1053 11/10/98
CU324
CU324
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
1576
1536
0.0255 mg/L
1578
AV 1563.3 EM
AV 0.0248 mg/L
1560
1553
0.0231 mg/L
REZF>1_ I CftTEI 41=3
0.0257 mq/L
SD
SD
23.7 CV
0.0015 CV
E: 4*1
1.5
5.87
1055 11/10/98
0.0245 mg/L
F>E:F>I_ i C^HTE: 4*12
0.0241 mq/L
-------
CU324
CU324
CU324
CU324
CU324
CU324
S
CU324
S
CU324
S
CU324
CU324
CU324
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
AV
AV
1412
1359
1418
AV
AV
1588
1 605
1634
AV
AV
9207
9255
9070
AV
AV
1747
1 740
1731
AV
AV
1546.0 EM
O.O237 mg/L
0.0155
0.0122
0.0158
1396.3 EM
O.O145 mg/L
0 . 0263
0 . 0273
0.0291
16O9.0 EM
O.O276 mg/L
0 . 4937
REF>L_
0 . 4967
0 . 4853
9177.3 EM
0.4919 mg/L
0 . 0360
0 . 0356
0 . 0350
1739.3 EM
O.O356 mg/L
SD
SD
ICrf=V
mg/L
IC#V
mg/L
mg/L
SD
SD
I Crf=V
mg/L
18.5 CV 1
O.O011 CV 4.1
TE 41= dL 1O5I
TE 4*2
TE 4*3
32.5 CV 2
0.0020 CV 13.;
TE 4* 1 1051
ICrtTE 41=2:
mg/L
mg/L
SD
SD
ICrf=T
mg/L
IC*=T
mg/L
mg/L
SD
SD
i c*==r
mg/L
mg/L
ICft-
mg/L
SD
SD
TE 4*3
23.3 CV 1
O.OO14 CV 5.
TE 4*± 110<
TE 4*2
TE 4*3
96.0 CV 1,
O.OO59 CV 1.;
TE: 4*± no:
peak -noisy
TE 4*3
8.0 CV O,
O.OOO5 CV 1 '
CU324 EM
20
CU324 EM
1O56 11/1O/98
1058 11/1O/98
11OO 11/10/98
11O2 11/1O/98
1720
1788
0.0344 mg/L
HO4 11/10/98
0.0385 mg/L
I
4*3
-------
CU324
CU324
CU324 EM
CU324 EM
i
CU324 EM
CU324
CU324
CU324 EM
:V
CU324 EM
:V
CU324 EM
CU324
CU324
:B
CU324 EM
;B
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
»
CU324 EM
•
CU324 EM
41.8 CV
0.0026 CV
i C^TE: 4*1
0.0407 mg/L
AV 1768.O EM SD
AV 0.0373 mg/L SD
1824
1962
1825 0.0408 mg/L
AV 1870.3 EM SD
AV 0.0436 mg/L SD
0.0492 mg/L
10699
10313
10556
AV 1O522.7 EM
AV O.5744 mg/L
F>EF>LIC«T
0.5853 mg/L
REF^I—I
0.5616 mg/L
0.5765 mg/L
SD
SD
79.4 CV
0.0049 CV
4*1
4*2
4*3
195.1 CV
0.012O CV
REIF^L I CftTE 4*1
0.0087 mg/L
0.0150 mg/L
1301
1404
1300 0.0086 mg/L
AV 1335.0 EM SD
4*3
59.8 CV
0.0107 mg/L
0.0496 mg/L
AV
1969
1915
1993 0.0511 mg/L
AV 1959.0 EM SD
SD O.O037 CV
I C<=kTI
0.0463 mg/L
4*1
4*2:
4*3
39.9 CV
AV 0.049O mg/L
1975
REF>1_ I
0.0500 mg/L
SD O.0025 CV
4*1
2O09
0.0521 mg/L
2.4
6.87
1105 11/10/98
4.2
11.17
11O7 11/10/98
1.9
2.08
1109 11/10/98
4.5
34.12
1111 11/1O/98
2.0
5.00
1112 11/1O/9B
4*3
-------
1 / . O w V
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
0.0441 mg/L
AV 0.0512 mg/L
REIF"
1901 0.0455 mg/L
I
1878
I
1932 0.0474 mg/L
AV 19O3.7 EM SD
AV O.O456 mg/L SD
2104
I
2059 0.0552 mg/L
SD 0.0011 CV
4*1
0.0579 mg/L
REF^LI
2093 0.0573 mg/L
AV 2O85.3 EM SD
AV 0.0568 mg/L SD
REIF>1_
3721 0.1571 mg/L
I
3798
3814 0.1628 mg/L
AV 3777.7 Eh SD
AV 0.1606 mg/L SD
RETF>l_I
0.1158 mg/L
0.1619 mg/L
4*3
27.1 CV
0.0017 CV
E: 4*1
4*3
23.5 CV
0.0014 CV
4*1
49.7 CV
O.O031 CV
4*1
0.1133 mg/L
3O48
3006
3012 0.1136 mg/L
AV 3O22.O EM SD 22.7 CV
AV O.I142 mg/L SD O.OO14 CV
=: 4*1
5298
5274
5453
0.2539 mg/L
RE:F>I_ i C<=*TE:
0.2524 mg/L
RE:F>L_ i C^TE: 41=3
0.2634 mg/L
2.13
1114 11/1O/98
1.4
3.64
1116 11/1O/98
1.1
2.53
1118 11/10/98
1.3
1.9O
1119 11/1O/98
0.8
1.22
1121 11/1O/98
-------
CU324
AV
0.2566 mg/L
SD 0.OO60 CV
2.32
:V
CU324 EM
CU324 EM
:V
CU324 EM
CU324
CU324
:B
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
0.5060 mg/L
RSEF^L. I CftTI
9723 0.5254 mg/L
I
9407
9408 0.5061 mg/L
AV 9512.7 EM SD
AV 0.5125 mg/L SD
4*1
4*2
1123 11/10/98
182.2 CV
0.0112 CV
1.9
2.18
IC^TE: 4*± 1125 n/io/98
1346 0.0114 mg/L peak-noisy
0.0174 mg/L
1444
I
1318 0.0097 mg/L
AV 1369.3 EM SD
AV O.O129 mg/L SD
peak-noisy
4*3
peak-noisy
66.2 CV
0.0041 CV
4.8
31.59
-------
iement File: PB.GEL
ate: 11/06/98
ata File:
echniaue: HGA
Element: Pb
Time: 09:12
ID/Wt File: B11O1.IDW
Calib. Type: Linear
Wavelength: 283.3
Slit: 0.7 L
Lamp Current: 10
Energy: 46
ID: BLANK
Seo. No.: 00119
A/S Pos.: O
Date: 11/06/98
eolicate 1
eak Area (A-s): 0.112
ackqround Pk Area (A-s): O.O60
lank Corrected Pk Area (A-s): 0.109
oncentration (ug/L ): 43.8
eolicate 2
eak rtrea (A-s): O.002
ackqround Pk Area (A-s): O.OO3
lank Corrected Pk Area (A-s): -0.001
oncentration (ua/L ): -0.5
Time: 09:12
Peak Height (A): 0.211
Background Pk Height (A): 0.092
Time: 09:15
Peak Height (A): O.O15
Background Pk Height (A): O.009
ean Cone (ua/L ):
21.7
SD: 31.39
RSD C/.): 144.95
ID: BLANK
Sea. No.: 0012O
A/S Pos.: O
Date: 11/06/91
eolicate 1
eak Area (A-s): 0.002
ackqround Pk Area (A-s): O.001
lank Corrected Pk Area (A-s): -O.001
oncentration (ua/L ): -0.3
Time: 09:19
Peak Height (A): O.O13
Background Pk Height (A): O.009
ID: BLANK
Sea. No.: 00121
A/S Pos.: 0
Date: 11/06/9E
eolicate 1
eak Area (A-s): O.007
;ackground Pk Area (A-s): 0.037
ilank Corrected Pk Area (A-s): O.004
:oncentration (ug/L ): 1.4
eo i i cate 2
eak Area (A-s): 0.007
iackqround Pk Area (A-s): O.044
Hank Corrected Pk Area (A-s): 0.004
Concentration (ug/L ): 1.5
Time: 09:21
Peak Height (A): 0.017
Background Pk Height (A): 0.043
Time: 09:24
Peak Height (A): O.O14
Background Pk Height (A): 0.039
lean Cone (ug/L ) :
luto-zero oerf ormed .
1.5
SD: 0.05
RSD (7.): 3.73
'b
ID: 10 PPB PB
'N*^^'V*V'V*V' '
Sea. No.: O0122 A/S Pos.: 1
Date: 11/06/9^
ieolicate 1
'eak Area (A-s): 0.032
Iackqround Pk Area (A-s): 0.046
Ilank Corrected Pk Area (A-s): 0.025
loncentration (ug/L ): 10.2
Time: 09:27
Peak Height (A): 0.063
Background Pk Height (A): 0.039
-------
enlicate 2
eak Area ('A-s ) : 0.030
ackground Pk Area (A-s): O.O46
lank Corrected Pk Area (A-s): 0.023
oncentration (uo/L ): 9.3
ean Cone (uo/L
9.7
tandard number 1 applied. [1O.O]
orrelation coefficient: 1.OOOOO
Time: 09:3O
Peak Height (A): 0.055
Background Pk Height (A): O.039
SD: 0.64
Slope: O.OO24
RSD(X): 6.57
ID: 50 PPB PB
Sea. No,
:eolicate i
'eak Area (A-s): 0.117
lackground Pk Area (A-s): 0.074
tlank Corrected Pk Area (A-s): O.lll
ioncentration (uq/L ): 45.7
;eoi icn te 2
'eak Area ( A-s j s O.131
lackground Pk Area (A-s): 0.068
Hank Corrected Pk Area (A-s): O.125
)oncentration (ug/L ): 51.4
lean Cone (ug/L ):
48.5
Standard number 2 applied. F50.01
:orrelation coefficient: 0.99994
00123
A/S Pos.: 2
Date: 11/06/9E
Time: 09:33
Peak Height (A): 0.218
Background Pk Height (A): O.054
Time: 09:36
Peak Height (A): O.229
Background Pk Height (A): O.056
SD: 4.06
Slope: O.OO24
RSD ( 7.) : 8.36
ID? 100 PPB PB
Sea. No,
Jeolicate 1
5eak Area (A-s): 0.242
Jackground Pk Area (A-s): O.095
Hank Corrected Pk Area (A-s): O.236
Concentration (ug/L ): 100.1
: O.245
Background Pk Area (A-s): 0.095
31ank Corrected Pk Area (A-s): O.238
Concentration (ua/L ): 101.2
'lean Cone (ua/L ):
100.7
00124
A/S Pos,: 3
Date: 11/06/9E
Time: 09:39
Peak Height (A): O.413
Background Pk Height (A): 0.096
Time: O9:42
Peak Height (A): 0.417
Background Pk Height (A): 0.099
SD: O.80
RSD(V.): O.79
Standard number 3 applied. [100.0]
lorrelation coefficient: 0.99998
Slope: 0.0024
ID: 200 PPB PB
Sea. No,
00125
A/S Pos.: 4
Date: 11/06/9S
^eolicate 1
3eak Area (A-s): 0.415
Background Pk Area (A-s): 0.148
Blank Corrected Pk Area (A-s): O.408
Concentration (ua/L ): 172.5
Time: O9:45
Peak Height (A)s 0.685
Background Pk Height (A): 0.180
-------
eo iica te ^
eak Area {A-sJ: 0.416
ackaround Pk Area (A-s): O.143
lank Corrected Pk Area (A-s): 0.409
concentration (uo/L ): 172.9
ean Cone (uq/L ):
172.7
tandard number 4 applied. [200.0]
orrelation coefficient: 0.99452
Time: 09:48
Peak Height (A): O.666
Background Pk Height (A): 0.179
SD: 0.26
Slope: O.OO21
RSDC/.) : 0.15
"feisfilay Calibfafisn -C:\flfl USERXAfi F
(,,„.
i
d
c.
^^-^
..x*""'
.iCJC1! SJ«B< : "c .CCS4
o c«nc«ntraca»n Sffff.ff
*
li
'b ID: ICV
leolicate 1
-oncentration (ua/L ): 97.0
ieoiicate 2
.oncentration iua/L j:
Sea. No.: OO126 A/S Pos.
Time: 09:55
1ime: 09:5B
lean Cone lug/L ): 99.6 SD: 3.71
JC sample is within ranae 79.5 - 12O.49
5b'
ID: ICB
ieplicate i
Concentration (ug/L ): 2.6
-------
.on cent rat ion lua/L ): 2.0
eo iicate ^
oncentration iuq/L J: 3.1
lean uonc lua/L ):
2.5
Tame: IO:1O
SD: 0.77
R5D C/.): 30.46
'b ID: 81101.OB
ieolicate 1
loncentration (ua/L ): 10.9
Sea. No,
(.eoj icate i
.oncentration (uq/L
lean Cone i uo/L ) :
OO129 A/S Pos.: 7 Date: 11/06/9;
Time: 10:13
fime: 10:
) : 12.6
11 .8
SD: 1.21
Jb ID: 81.101.UB
Jeol icate 1
Concentration (uq/L
Seo r No,
icate 2
Concentration iuq/L
lean Cone (ua/L j;
) : 8.9
) : 8.7
8.8
OO130 A/S Pos.: 8
Time: 10:19
Time: 10:22
SD: 0.16
RSD C/.): 10.33
Date: 11/06/9
RSD(X): 1.86
=b IDs 811O1.IB
^eolicate i
Concentration (ua/L ): 6.7
Sea. No,
Concentration iuq/L )r 8.4
lean Cone (uo/L ): 7.5
OO131 A/S Pos.s 9
Time: 10:25
Time: 10:28
SD: 1.21
Date: 11/06/9
RSD C/.): 16.11
=b IDs 81101.01
^eolicate 1
-oncentration (ua/L
-»eo i i ca te 2
Concentration lug/L
'"lean Cone >ua/L )
Sea. No,
) : 12.8
): 1O.9
11 -9
00132 A/S Pos.: 10 Date: 11/06/9
Time: 10:31
Time: 10:34
SD: 1.35
RSD (7.): 11.41
Pb TD; 81101.01
Reolicate 1
Concentration (ug/L ): 104.3
Dedicate 2
Concentration IUQ/L ): 1O5.6
Sea. No.: 00133 A/S Pos.: 10 Date: 11/06/5
Time: 10:37
Time: 10:4O
-------
:ean i_onc i ug/ u )
ecovery is 93. I'/.
1O4 .9
SD: 0.93
b ID: 81101.02
eplicate 1
oncentration (ua/L
Sea. No,
): 27.0
ecuicate ±
oncentration (ua/L ): 23.8
lean Cone (ua/L ):
25.4
OO134 A/S Pos.: 11
Time: 10:43
Time: lO:4b
SD: 2.22
RSD ('/.): O . 88
Date: 11/06/9$
RSD C/.): 8.76
'b ID: 61101.03
:eolicate 1
.oncentration (ua/L ): 15.1
icate z
:oncentration (ua/L ): 16.6
Sea. No.: 00135 A/S Pos.: 12
Time: 1O:49
Time: 1O:52
lean Cone iua/L ):
15.5
SD: O.63
• ~v "v "v • w 'V ••„ 'V- f
-------
oncentration lug/L >: 81.7
lean Cone luo/L ): 81.3
SD: 0.63
RSD ('/.): 0.77
'b ID: 81101. U2
.enlicate 1
.oncentration (uq/L ): 82.1
eoiica te 2
.oncentration iua/L ): 86.7
Sea. Mo,
00139 A/S Pos.: 14 Date: 11/06/96
Time; 11:13
Time: 11: lo
lean Cone iua/L ):
84.4
SD: 3.30
RSD (7.): 3.92
'b ID: 81101.U3
leolicate 1
Concentration (ug/L ): 44.1
ieoi icate 2
.oncentration iua/L ): 41,9
Sea. No,
OO140 A/S Pos.: 15 Date: 11/06/9E
Time: 11:20
Time: 11:23
lean Cone b IDs 81101.U4
ieolicate 1
Concentration (uq/L ): 54.6
ieoi icate 2
Concentration iug/L ): 51.9
Sea. No.
O0141 A/S Pos.: 16 Date: 11/06/9E
Time: 11:26
Time: 11:29
lean Cone i ua/L ) :
53.3
SD: 1.91
RSD C/.): 3 . 59
'b ' ID: 81101.11X2.5 .
ieolicate 1
Concentration tuq/L ): 82.7
-------
h ID: 81101.13
ieolicate 1
Concentration iua/L ): 169.3
;eo 11 cate ^
Concentration iua/L j: 1/2.0
lean Cone iua/L > : 1/0.6
Sea. No.: O0144 A/S Pos.
Time: 11 :44
19 Date: 11/06/9J
Time: 11:47
SD: 1.B5
"V *V 'W "** "V ''.^ ' \f ' \j 'V '\. *V\* '
>b ID: CCV
ieolicate 1
:oncentration (ucp/L ): 103.8
ieoiicste 2
Concentration luq/L ): 1O2.6
Sea. No.: O0145 A/S Pos.
Time: 11:50
Time: 11:53
lean Cone (uq/L >i 103.^ SD: 0.84
)C sample is within ranae 79.5 - 120.49
>b ID: CCB
Jeolicate 1
Concentration (ug/L ): 2.O'
-------
:iN--El.MER
M i i 00
98/11/1.1. PAGE
AA AA
!: 0.001 MG/L HO 0-000 MAIN: 0.006 MG/L HO 0.001
MEAN: 0.003 MG/L EDs 0.003 RSD: 99.9 AUTO ZERO O.OOO
AA AA
I: 0.057 MG/L HO 0.008 MAIN: 0.068 MG/L HO 0.009
MEAN: 0,063 MG/L BD: 0.006 RSD: 12.4 1.STANDARD 0,052 MG/L
AA AA
1: 0.082 MG/L HO 0,0.13 MAIN; 0.089 MG/L HO 0.014
MEAN: O.OB'5 MG/L EDj 0.005 RBD: 5.8 2. STANDARD 0.09O MG/L
AA AA
4: 0.185 MG/L HO 0.028 MAIN: 0.185 MG/L HO 0.028
MEAN: 0.185 MG/L BD: 0.000 RSD: 0.2 3. STANDARD 0.1BB MG/L.
Aft A A
J: 0.006 MG/L HO 0., 001 MAIN: O.OO9 MG/L HO O.OOO
MEAN: 0.007 MG/L SD: 0.002 RSD: 28.9 AUTQZERO 0.000
AA AA
si: 0.464 MG/L HO 0.065 MAIN: 0.475 MG/L HO 0,. 067
MEAN: 0.469 MG/L SD: 0.008 RSD: 1.7 4.STANDARD 0.471 MG/L
A A A A
vl: 0.996 MG/L HO 0.130 MAIN: 1-024 MG/L HO 0.134
MEAN: 1.010 MG/L SD: O.O20 RSD: 2.0 5.STANDARD 1.041 MG/L
FLAME DISPLAY CALIBRATION MODE
ELEMENT: MM
REPL, 0 OF 2
0.132
ABS.
PRINTER: ON
B6 CORR: OFF
UNITS : MG/L
1,041
READ
flBS. READING
S5 AA
9.134
S2
SI
CONCENTRATION (MG/L )
1.000
STATISTICS
MEAN: 1.010
5D: 0.023
R3D(%): 2.3
32H2: 2.5 L/MIN OX I CANT; 3.0 L/MIN
FLAME: CZHE-AIR
-------
PERKIN-ELMER M 1100 98/11/11 PAGE 3
AA AA
MAIN: -0.014 MG/L HO-0.002 MAIN: -0.018 MB/I. HO-0.000
MN MEAN: -0.016 MB/L SDs 0.003 RSDr 15.8 ALJTOZERD 0.000
AA AA
MAIN: 0.513 MG/L HO 0.068 MAIM: 0.504 MG/L HO 0,067
MN. o/ MEANs 0,509 MB/L BD; 0.007 RED: 1.3
AA AA
MAIM: 0.016 MG/L HO O.OO2 MAIN: 0.010 MG/L HO 0.001
MEAN:- 0.013 MG/L. BDs 0.004 RED; 32.2
AA AA
MAIN: 0.004 MG/L HO 0.001 MAIM: 0.003 MG/L HO--O.OOO
MN - MEAN: 0.003 MB/L SD : 0.001 RSD: 15.3 AUTOZERO 0.000
A A A A
MAINE 0.028 MG/L HO 0,004 MAIN: 0.025 MG/L HO 0.003
MN gf- MEAN: 0,027 MB/L SD; 0.002 RBD: 6.0
AA AA
MAIN: 0.046 MB/L HO 0.006 MAIN: 0.053 MG/L HO 0.007
MN 0£ MEAN: 0.049 MG/L BD: 0.004 RSD: 8.9
A A A A
MAIN: 0.040 MG/L HO 0.005 MAIN: 0.. 033 MG/L HO O.004
MN ^(7 MEAN: 0.036 MG/L SDs 0.004 RBDj 12.0
AA AA
MAIN: 0.038 MG/L. HO 0.005 MAIN: 0.011 MG/L HO 0..005
MN
-------
PERK IN--ELMER M 1100 98/11/11 PAGE 4
AA AA
MAIN: 0,435 MG/L HO 0.058 MAIN: 0.433 MG/L HO 0,057
MN 0/5 MEAN:; 0.434 MG/L BD; 0.001 RSD: 0.2
AA AA
MAIN: 0.072 MG/L HO 0.009 MAIN: 0.071 MG/L HO O.OO9
MN £>1_ MEAN: 0.072 MG/L. SDs 0.000 RSD: 0.3
A A A A
MAIN: 0.066 MG/L. HO 0.009 MAIN: 0.063 MG/L HO 0,008
MN £>2£> MEANs 0.065 MG/L BD: O.O02 RSD: 3.1
A A A A
MAIN; 0.081 MG/L HO 0.011 'MAIN: 0.081 MG/L. HO 0.011
MN O' MEAN: 0,081 MG/L BD: 0.000 RSD: 0.2
Aft A A
MAINE 0.538 MG/L HO 0.071 MAINs 0.533 MG/L HO 0.071
MN \ MEAN: 0.536 MG/L BD; O.O04 RSD: 0.7
A A A A
MAIN: O.023 MG/L HO O.003 MAIN: O.026 MG/L HO 0.003
MM cc.fi MEAN; 0.024 MG/L SD: 0.003 RSD: 10.7
AA AA
MAINs O.O20 MG/L HO 0,. 003 MAIN: 0.017 MG/L. HO--0.000
MN f&2= MEAN: 0.018 MG/L SD: O.OO2 RSD: 12.2 AUTOZERO O.OOO
A A A A
MAIN; 0.04.1 MG/L HO 0.005 MAIN: 0.062 MG/L HO 0.008
MN MEAN : 0 „ 05 1 MB / L 3D : 0 . 0 1 5 RSD ; 30 . 0
/
A A A A
MAIN: 0.084 MG/L HO 0,011 MAIN: 0.081 MG/L HO O.011
MN 42- MEAN: 0.083 MG/L SD: 0.002 RSD: 2.1
A A A A
MAIN: 0.048 MB/L HO 0.006 MAIN: 0.061 MG/L HO 0.008
MN ^^ MEAN: 0.055 MG/L BD: 0.009 RSD: 16.8
-------
PERK I N-ELMER H 1 100 98/ i 1 / 1 J PAGE 5
A A A A
MAIN: 0.088 MG/L HO 0.01.2 MAIN: O.091 MG/L HO 0.012
MN frLf MEAN: 0.089 MG/L SD: 0.002 RBD: 2.3
A A A A
MAIN: O.362 MB/L HO 0.048 MAIN: 0.363 MG/L HO 0.049
MN ,-r / MEAN: 0.363 MB/L. SD: 0.001 RSDs 0.2
A A A A
MAIN: O. 185 MB/L HC 0,024 MAINs 0. 189 MG/L HO 0.025
MN "St *- MEAN: 0.187 MB/L SD:; 0.003 RSDs 1.6
A A A A
MAIN: O.209 MB/L HO 0.028 MAIN: 0.2O9 MG/L HO O.028
MN <£3 MEAN; 0..2O9 MB/L SD: 0.000 RSDs 0.1
A A A A
MAIM; 0.024 MG/L HO 0.003 MAIN: 0.026 MG/L HO 0.003
MN MEAN: 0.023 MB/L SDs 0.00:1 RSD: 5.7 AUTOZERO 0.000
A A A A
MAIMr 0.498 MG/L HO 0.066 MAIN: 0.510 MG/L HO O.O68
MN <<-W MEANs 0. 504^6/1... SD: 0.009 RSD; 1.8
AA AA
MAIN: 0.006 MB/L HO O.OO.I MAINs 0.0:1.7 MG/L HO O.O02
MN
-------
PABF: io
0. 002
AA-BG BG
PA O,015 —O.004
PH 0.OO2 0.001
AUTOZERO
HO
MAIN: 0,012
AA-BG EG
PA 0,234 0., 005
PH 0. 012 --0. 000
HG
MAIN;:
.STANDARD
AA-BG BG
1 . OS UG/L PA 0., 428 0,004
P!-! 0., 026 -O.OOi
E 61 S a m p 1 t? c o n c o n t r a t i CD ri q r G a t & r i. h a n h i q h e> c t s t a n cl a r d
1,. 01 2, STANDARD
HG
MAINl:
AA-BG BG
2.0-1 UG/L. PA 0.822 0.008
PH 0.052 -0.001
E61 Barnpltf concentration greater than highest standard
2.01 3,, STANDARD
MAIN:-
03 UG/L
'" " n:": ••":• o
f?!;'.,: ;?:,.;..•.,.:•.;:.;' ..: ij ;uor;trati on greater than highest standard
5.STANDARD
-------
PERK1W--R. MFR
M i 1 00
98/11/11 PAGE 11
HGA DISF
ELEMENT :
0.253~
ABS.
HB *£e\)
MAIN;; 5.
HB &F
MAINt -0.
HB 6.S
MAIN? -0.
HG # g
MAT hi:: --0..
HG XG
MAIN: -0.
HG O '
MAIN:- -0
HG cJ /
MAT Ms: -O,
HG O ^-
MA I N r 0 .
:••!? 0 2.
:V;A?:N;: • o.
HG C£ r
MAThJ; 0
•LAY CALIBRATION MODE
HG - PEAK HEIGHT
_^K~JB2
Si
S
PRINTER; ON
BG CORR: ON
UNITS : UG/L
CH.MAS3:
CONCENTRATION
:>A UG/L P
F'
H-
A-
H-
0 ,
0.
AA
0,
0.
AA
0,
0.
ooe
oco
-BG
006
00 1
-BG
023
002
-•0
0
-0
•-0
o
0
BG
„ 024
. 000
BG
. 007
. 000
BG
. 002
. 000
BG
. 002
. 001
BG
. 0 1 5
ooo
BG
,019
. 001
EG
.. 0 1 4
. 000
BG
, 0 1 7
. 005.
BG
., 00.2
. 002
BG
, 002
. 000
)
HB
MAIN:
HB
MA I M :
HG
MAIN:
HB
MAIN?
MB
|.-;A, T hj »
9,91
j^-"+ PEAK AREA (A-S)
^^ S5 AA-BG: 3.941
BG: ^.357
PEAK HEIGHT (A)
AA-BG: 0.253
EG: 0.003
1
13.03
^C^ AA-BB BG
-0.11 UG/L PA-0, 036 0., 020
PH-O.O03 0.002
AA-BB
•-0,06 UG/L PA-0. 016
PH-0.002
AA-BB
-0.09 UB/L PA-0.. 048
PH-0.002
-0.03 UB/L PA
l"*i ! I
r l'V"
-0,03 UG/L. PA
AA-BG
0., 001
0. 001
AA-BG
0.015
PH-OU 001
HB
MAINt
HP C
jvjif.-j T ;\| ];
HB
MAIN:
0^
5.30 UG/L PA
PH
>(^
5.07 UG/L PA
PH
-0.06 UG/L PA--
AA-BB
2 , 082
0. 135
AA-BG
1,915
0. 129
AA-BB
0,O16
PH-0.002
HG
MAIN:
i-ie (
MAINr
^
5. 19 UG/L PA
PH
>3.
AA-BB
2.219
0. 132
AA-BB
O.O9 UG/L... PA-0. 01 9
PH-
0. 002
BG
-0.004
-0.002
BG
0.019
0.. 002
BG
-0
... Q
. 009
. 001
BG
-0
... Q
.,012
. 000
BG
0
O
0
0
.0
-0
0
0
0
-0
, 027
. 000
BG
. 02S
.. 000
BG
,014
. 000
BG
. 036
.001
BG
., 000
. 001
-------
PLRKTM--F1 M [;•!•"•
M I i 00
98/1 :i /il
PAHE 12
un
MAIN:
KG
HAINr
HG
MA I N :;
HG
MAINE
HG
MA I N r
HG
MAIN;
HG
MAIN:,
HG
MAINE
U ( AA-BG
--O.O6 UG/L PA-0,, OOO
PH-O., 002
U 2- AA-BG
•-0.03 UG/L PA 0.. O06
PH-0. 001
H 3 AA-BG
• O..OG UG/L PA-0. 024
PH-O . 002
b *-( AA-BG
-0., 05 UG/L PA 0,003
PH-0. 001
"£1 AA-BG
0. 1 1. UG/L PA-0., 004
PH 0.003
•^ 2- AA-BG
0 . 0 3 U G / L PA- 0 ., 0 1 0
PH O.001
^•3 AA-BG
• - 0 , O 5 ! i G / L. P A - 0 , 0 1 0
PH--O. Ool
C
-------
lement File: NI.GEL
ate: 11/05/98
ata File:
echniaue: HGA
Element: Ni
Time: 08:49
ID/Wt File: 811O1.IDW
Calib. Type: Linear
Wavelength: 232.0
Slit: 0.~2O L
Lamp Current: 25
Energy: 49
ID: BLANK
eolicate 1
eak Area (A-s): 0.01,8
ackaround Pk Area (A-s): 0.049
lank Corrected Pk Area -(A-s): 0.018
eo iidate 2 .
eak Area iA-s): O.O12
ackground Pk Area (A-s): 0.041
lank Corrected Pk Area (A-s): 0.012
ean Pk Area (A-s):
uto-zero performed.
0.015
Seq. No,: 00055
A/S Pos.: 0
Date: 11/05/S6
Time: 08:49
Peak Height (A): 0.035
.Background >k Height (A): 0.049
Time: O8:52
Peak .Height (A): 0.024
Background Pk Height (A): O.O43
SD: 0.0043
RSD(7.): 28.67
ID: 20 PPB NI
Sea . No
eolicate 1
eak Area (A-s): O.O27
ackaround Pk Area (A-s): 0.05O
lank Corrected Pk Area (A-s): 0.012
OO056
A/S Pos.: 1
Date: 11/05/1)
Time: O8:55
Peak Height (A): 0.028
Background Pk Height (A): O.046
ID: BLANK
Sea. No.: 00057
eolicate 1
eak Area (A-s): O . 006
ackaround Pk Area (A-s): O.042
lank Corrected Pk Area (A-s): -0.009
A/S Pos.: 0
Date: 11/05/1
Time: OB:59
Peak Height (A): O.011
Background Pk Height (A): O.048
eoiicate 2
eak Area (A-s): O.OO6
ackaround Pk Area (A-s): 0.045
:lank Corrected Pk Area (A-s): -0.009
lean- Pk Area (A-s):
luto-zero performed.
-O.O09
Time: 09:02
Peak Height (A): 0.017
Background Pk Height (A): 0.048
: o.ooor
RSD(7.) : 0.58
ID: 20 PPB NI
Sea. No.: OO058
A/S Pos.: 1
Date: 11/05/
leolicate 1
'eak Area (A-s): 0.026
lackground Pk Area (A-s): 0.048
Hank Corrected Pk Area (A-s): 0.019
Time: 09:05
Peak Height (A): O.O25
Background Pk Height (A): 0.047
;eoiicate 2
'eak Area (A-s): 0.024
lackoround Pk Area (A-s): O.O46
Time: 09:08
Peak Height (A): 0.026
Background Pk Height (A): 0.040
-------
lank Corrected Pk Area (A-s): 0.018
ean Pk. Area (A-s): 0.019
V
tandard number 1 applied. [20.0]
orrelation coefficient: l.OOOOO
SD: O.O011
Slope: O.OOO9
RSD (V.): 5. 70
ID: 5O PPB NI
Sea. No.: 00059
eolicate 1
eak Area (A-s): 0.111
ackground Pk Area (A-s): 0.066
lank Corrected Pk Area (A-s): 0.105
oncentration (ug/L ): 111.5
eoli cate 2
eak Area (A-s): 0.11O
ackground Pk Area (A-s): O.066
lank Corrected Pk Area (A-s): 0.104
oncentration (ua/L ): 111.0
ean Cone (ug/L ):
111.:
tandard number 2 applied. [50.0]
orrelation coefficient: O.85962
A/S Pos.: 2
Date: 11/05/9E
Time: O9:ll
Peak Height (A): 0.078
Background Pk Height (A): O.O49
Time: O9:14
Peak Height (A): 0.075
Background Pk Height (A): O.O51
SDj 0.39
Slopes 0.0020
RSD ( 7.) : 0.35
li
ID: 1OO PPB NI
Sea. No,
:epl icate 1
'eak Area (A-s): 0.210
iackground Pk Area (A-s): 0.088
Hank Corrected Pk Area (A-s): 0.204
ioncentration (ug/L ): 101.5
:eol i cate 2
'eak Area (A-s): 0.204
lackorouna Pk Area (A-s): O.086
Hank Corrected Pk Area (A-s): 0.198
loncentration (ug/L ): 98.6
lean Cone (ua/L ) :
100.1
itandard number 3 applied. [100.0]
iorrelation coefficient: O.98185
00060
A/S Pos.: 3
Date: 11/05/9E
Time: O9:17
Peak Height (A): 0.136
Background Pk Height (A): 0.063
Time: O9:20
Peak Height (A): 0.134
Background Pk Height (A): O.O64
SD: 2.11
Slope: 0.0020
RSD (7.): 2.10
li
ID: 200 PPB NI
Sea. No.
leol icate 1-
'eak Area (A-s): 0.400
Iackground Pk Area (A-s): 0.136
tlank Corrected Pk Area (A-s): 0.394
loncentration (ug/L ): 196.3
Ueoiicate 2
'eak Area (A-s): O.403
iackground Pk Area (A-s): 0.142 t
00061
ft/S Pos.: 4 .. Date: ll/05/9€
Time: 09:23
Peak Height (A): 0.243
Background Pk Height (A): 0.09O
Time: 09:26
Peak Height (A): 0.244
Background Pk Height (A): 0.090
-------
lank Corrected Pk Area (A-s): 0.397
oncentration (ua/L ): 197.7
ean Cone (ua/L ):
197.0
tandard number 4 applied. T200.0]
orrelation coefficient: 0.99679
SD: 1.O5
Slope: O.OO2O
RSD C/.): 0.53
ID: 2O PPB NI
Sea. No,
eplicate 1
eak Area (A-s): O.034
ackground Pk Area (A-s): O.053
lank Corrected Pk Area
-------
Ji
ID: ICB
Sea
ieolicate 1
Concentration (uq/L ): -O . 5
Concentration (uq/L ): -2.3
lean Cone iuq/L )s -1.4
3C samole is within ranoe -15.49
No.: OOO64 A/S Pos.: 0
Time: 09:42
Time: 09:45
SD: 1.2B
- 15.49
Date: 11/O5/9
RSD C/.): 92.42
Ji ID: 811O1.B-F
*eolicate 1
Concentration (uq/L ): -2.0
-------
i ID: 81101.01 Sea,
eolicate 1
oncentration (uq/L ): 8.3
eo i i cate 2
oncentration (uq/L ): 7.3
ean Cone (ua/L ): 7.8
No.: OO069 A/S Pos,
Time: 10:11
Time: 10:13
SD: 0.69
10 Date: 11/05/91!
i ID: 811O1.01
eolicate 1
oncentration (uq/L ): 105.4
eoiicace 2
oncentration (uq/L ): 1O4.8
ean Cone (uq/L ):
ecoverv is 97.3"/i
Sea. No.: OO070 A/S Pos,
Time: 10:16
Time: 10:19
1O5.1 SD: 0.41
1O
i ID: 811O1.02
eolicate 1
oncentration (uq/L ): 18.9
eoi icate 2
oncentration (ua/L ): 17.2
ean Cone lua/L j:
Sea. No.: OOO71 A/S Pos.
Time: 10:22
Time: 10:25
18.0 SD: 1.21
RSDC/.): 8.84
Date: li/05/"?^
RSDC/.): 0.39
11 Date: 11/05/9
RSDC/.): 6.70
i ID: 81101.03
eoli cate i
oncentration (uq/L ): 12.1
eoiicate 2
oncentration (ua/L ): 12.2
ean Cone (ua/L ) :
Sea. No.: OOO72 A/S Pos,
Time: 10:28
Time: 10:31
12.1 SD: O.O7
12 Date: ll/05/9f
:i ID: CCV Sea
eolicate 1
oncentration (uq/L ): 93.0
eoJicate 2
.oncentration (ua/L ): 98.8
No.: OOO73 A/S Pos
Time: 10:34
Time: 10:37
lean Cone (uq/L ): 95.9 SD: 4.14
[C sample is within ranoe 79.5 - 120.49
RSD C/.) : 0.57
Date: 11/05/9J
RSDC/.): 4.32
-------
•li ID: CCB
Jeolicate 1
:on cent rat ion (ug/L
): -4.1
icate 2
Concentration iuq/L ): -4.5
lean Cone tug/L ): —4.3
3C samole is within ranae -15.49
Sea. No.: OOO74 A/S Pos,
Time: 10:4O
Time: 10:42
SD: 0.30
- 15.49
Date: 11/O5/9
• "v PV ""u 'V *V "V *
Ji
ID: 811O1.U1
Sea. No.
Concentration (ua/L )s 1O.5
-------
i ID: SI101.I1X2.5
eolicate 1
oncentration lug/L ): 76.6
eoii cate 2
oncentration (ua/L ): 79-9
ean Cone (ua/L ): 78.3
orrected Cone (ua/L ): 195.7
Sea. No.: OO079 A/S Pos.: 17 Date: 11/05/96
Time: 11:09
Corrected Cone (ug/L
Time: 11:12
Corrected Cone (ug/L
SD: 2.30
): 191.6
): 199.7
RSDC/.): 2.94
:i
ID: 81101.12
:eolicate 1
oncentration (ug/L
eo iica te 2
.oncentrataon (ug/L
lean Cone (ua/L ):
Sea
): 136.7
): 142.9
139.8
No.: OO080 A/S Pos.: 18
Time: 11:15
Time: 11:18
SD: 4.34
Date: 11/05/9E,
RSDC/.) : 3.11
li
ID: 81101.13
iamole abs
ieol icate
No.: 00081 A/S Pos.: 19
of the' largest standard
Times-^ii :21
Date: 11/05/9S
iamol e/abs
ieoi i
Concentration/ (ua/L
iamole abs
lean Cone (ua/L ^ ) :
tha/> that
225.4
i the/largest standard.
Time: 11:24
of the largest standard.
SD: 6.61
Ji
ID: 81101.13X2.5
Sea. No.: 00083
A/S Pos. : 19
ieolicate 1
Concentration (ug/L ): 97.4
-------
JC samoie is within ranae 79.5 - 120.49
Ji
ID: CCB
-------
It file is 81101
ANDARD 4*1
P214
EM
292
P214
ANDARD 4*1
P214
P214
ANDARE> 4*2
P214
ANDARD 41=2
P214
P214
P214
AINIDARD 4*3
P214
ANDARD 4*3
P214
ANDARD 41=3
P214
P214
P214
P214
P214
P214
AIMK
P214
AIMK
P214
AIMK
P214
P214
P214 CC
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
288
295
291.7 SD
449
RER-LI
453
451
451.0 SD
667
RER-L. I
663
REF>I_ I
676
668.7 SD
1261
RER*l_ I
1274
REF>L_ I
1305
1280.0 SD
REF>i_I
256
249
RER-L.Z
252
252.3 SD
0 . 9999 SLOPE
GATE
GATE
3.5
C«TE
GATE
C«TE
2.0
GATE
GATE
GATE
6.7
GATE
GATE
GATE
22.6
GATE
C«TE
GATE
3.5
P'
4*3
CV
4*1
4*2
4*3
CV
4* 1
4*2
4*3
CV
4* 1
4*2
4*3
CV
4* 1
4*2
4*3
CV
206.0664 I
I GATE 4*1 1345 11/1O/98
peak-noisy
peak-noisy
1.2 CONC O.2000
1347 11/1O/98
0.4 CONC l.OOOO
1349 11/1O/98
l.O CONC 2.0000
1351 11/1O/98
1.8 CONC 5.0000
1353 11/10/98
P214
EM
657
I GATE 4*1
1.9713 mq/L
1.4 CONC O.OOOO
250.7845
1355 11/10/98
-------
P214
EM
675
2.0586 mq/L
:V
P214
:B
P2 1 4
:B
P214
:B
P214
± O ±
P214
±O1
P214
1 O ±
P214
I
P214
c
P214
I
P214
»
P214
»
P214
*
P214
EM
P214
P214
EM
EM
EM
P214
P214
- BF=-
EM
EM
- BF~
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
RE:F>I_ i c<=n~E:
658 1 .9761 mg/L
AV 663.3 EM SD
AV 2.0020 mg/L SD O.
264 0.0641 mg/L
270 0.0932 mg/L
283 O.t-S&tT mg/L
AV 272.3 EM SD
AV O.1O46 mg/L SD O.
REIF^L. I C^TFZ
264 0.0641 mg/L
265 0.0690 mg/L
RE:F>I_ i C^TE:
257 0.0302 mg/L
AV 262.0 EM SD
AV O.O544 mg/L SD O.
B~~^ f^^ L_J* 1 *^T ri " ta ^^N. ^T^ K-— "
•^S. • • L—^ ^L * ~ B • • ^^^_
279 0.1369 mg/L
290 0. 1903 mg/L
REIF^L I CftTFZ
280 0. 1418 mg/L
AV 283.0 EM SD
AV 0.1563 mg/L SD O.
263 0.0593 mg/L
41=3
10.1 CV 1.5
O491 CV 2.45
41= ± 1357 11/10/98
peak -noisy
peak-noisy
wi ndow-edg(j?
9.7 CV 3.6
0471 CV 45.07
4*± 1359 11/10/98
peak-noisy
peak -noisy
41=3
peak -noisy
4.4 CV 1.7
O212 CV 38.86
41= ± 1401 11/1O/98
peak -noisy
peak -noisy
4*=3
peak-noisy
6.1 CV 2.1
0295 CV 18.88
4* ± 1403 11/1O/98
peak-noisy
RE:I=>I_ i C*=*TE: 4*12
282 0.1515 mg/L window-edge
277 0. 1272 mg/L
AV 274.0 EM SD
AV 0.1127 mg/L SD 0.
4*3
peak-noisy
9.B CV 3.6
O478 CV 42.42
CTM
0.0981 mq/L
4* ± 1405 11/10/9B
peak-noisy
-------
tri
I_I
0. 1O30 mg/L
=t*± 14O7 11/10/98
peak-noisy
peak-noisy
REF>I_ i
1.8645 mg/L
peak-noisy
12.5 CV 4.4
0.0607 CV 37.27
*!= ± 14O9 11/10/98
1.8694 mg/L
12.4 CV
0.0603 CV
1.9
3.17
297
272
I
284 0.1612 mg/L
AV 284.3 EM SD
AV 0.1628 mg/L SD
635
636
I
657 1.9713 mg/L
AV 642.7 EM SD
AV 1.9017 mg/L SD
287
276
283 0.1563 mg/L peak-noisy
AV 282.O EM SD 5.6 CV 2.O
AV 0.1515 mg/L SD 0.0270 CV 17.84
275
299
I
281 0.1466 mg/L
AV 285.0 EM SD
AV O.I660 mg/L SD
0.1757 mg/L
0.1224 mg/L
*= ± 1411 11/10/98
peak-noisy
peak-noisy
I GATE =* 1 1413 11/10/98
0.1175 mg/L peak-noisy
REF>1_
0.2340 mg/L
peak-noisy
111
REF>1_ I
0.2922 mq/L
peak-noisy
12.5 CV 4.4
O.O6O6 CV 36.SO
=**= 1 1415 11/1O/98
-------
P214
EM
0.1224 mg/L
P214 EM
P214
P214
P214
P214
EM
EM
2.4129 mg/L
P214 EM
P214
P214
B
P214 EM
>ma has gone off.
286 0.1709 mg/L
AV 291.0 EM SD
AV O.I952 mg/L SD
748
733
735 2.3498 mg/L
AV 738.7 EM SD
AV 2.3676 mg/L SD
REF>I
253 0.0108 mg/L
.3401 mg/L
peak-noisy
=1*3
18.O CV
O.O875 CV
8.1 CV
0.O395 CV
4* ±
£.2
44.83
1417 11/10/98
1.1
1.67
1419 11/10/98
-------
3MA 400 Analysis Ver. 4.10 Tue 11/10/98 - 14:41:48
lod File
a r k s :
•Jt file
•ANr>£
•rf=klNir>£
~£*r*r>f
*=klN|Z>£
•rf=*ND£
*=*|Nir>£
-f*Nr>t
•*=MMD£
•*=HME><=
~ft!ME>£
"rf=HMr><=
-*=kiME>i=
Name: P
is PART2
*RE> 4* 1
P214
*RD 4* 1
P214
*RD 4*1
P214
P214
*RD 4*2
P214
*RD 4*2
P214
*RD 4*2
P214
P214
*RD 4*3
P214
*RD 4*3
P214
*F>D 4*3
P214
P214
^R!D 4*4
P214
^FI_ I C«=»TE
733
REF=-l_ I C<=*TE
759
RERL I CftTE
752
748.0 SD 13.5
REF>I_ I CftTTE
1424
REF>L_ I C^TTE
1407
RERL. I C^TE
1426
1419.0 SD 10.4
Read Delay: 65
Data File:
4*1 1443 11/10/98
4*2
4*3
peak -noisy
CV 2.7 CONC 0.2000
4*1 1445 11/1O/98
4*2
4*3
CV 2.2 CONC 1.0000
4*1 1447 11/10/98
4*2
4*3
CV 1.8 CONC 2.0000
4* 1 1449 11/10/98
4*2
4*3
CV 0.7 CONC 5.0000
P214
P214
EM
EM
276
4*1 1451 11/10/98
4*2
278
-------
P214
P2 1 4
P214
EM
EM
EM
P214
P214
P214 EM 275
P214 AV 276.3 SD
P214 CC 0.9999 SLOPE
826
720
REF>L_ I
2.3816 mg/L
RER-L:
1.9166 mg/L
REF>I_ I
736 1.9868 mg/L
AV 760.7 EM SD
AV 2.0950 mg/L SD
1.5 CV 0.6 CONC O.OOOO
227 .9741 I1MT 283 .0558
4* 1 1453 11/10/98
4*2
57.1 CV
0.2507 CV
7.5
11.96
P214
P214
EM
EM
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
288
301
REF>I_ i
0.0217 mg/L
RER-L-I
0.0787 mg/L
4*1 1455 11/10/99
window-edge
4*2
peak-noisy
I CftTE 4*3
P214
1 O 1
P214
1O1
P214
101
P214
EM
P214
P214
» LJ 1
EM
- LJ1
EM
. LJ1
EM
P214
P214
320 0.1621
AV 3O3.O EM
AV O.0875 mg/L
REF>L
326 0.1884
REF>I_
319 0.1577
REF-L.
306 0.1 O06
AV 317.0 EM
AV O.1489 mg/L
mg/L
SD
SD
mg/L
mg/L
. I C*=V
mg/L
SD
SD
peak-noisy
16.1 CV
O.O706 CV
5.3
80.69
TE 4*1 1457 11/10/98
peak-noisy
TE 4*2
peak -noisy
TE 4*3
10.1 CV
O . O445 CV
3.2
29. 9O
364
361
370
REF"!— I
0.3551 mg/L
REF^L I CrfSfcTE
0.3419 mg/L
REF>I_ I
0.3814 mg/L
4*1 1459 11/1O/98
peak-noisy
peak-noisy
4*3
AV
AV
365.0 EM SD
0.3594 mg/L SD
4.6 CV 1.3
0.0201 CV 5.59
318
REF>I_ I CPlTE 4*1 15O1 11/1O/98
0.1533 mg/L peak-noisy
-------
FJEF>L_ I CATE 4*3
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
324 0
AV 323. O
AV 0.1752
. 1 796
EM
mg/L
REF>L_
342 0 . 2586
R
337 0
ER-L-
. 2366
RER-L-
376 0 . 4077
AV 351.7
AV 0.3O1O
R
418 O
410 0
427 0
AV 418.3
AV 0.5934
R
406 0
R
412 0
R
413 0
AV 410.3
AV 0 . 5583
447 0
EM
mg/L
ER-L.
.5919
.5568
.6314
EM
mg/L
EF>1_
. 5393
ERI_
.5656
ERl_
. 5700
EM
mg/L
.7191
mg/L
SD
SD 0.
I GATE
mg/L
mg/L
I GATE
mg/L
SD
SD 0.
mg/L
mg/L
I GATE
mg/L
SD
SD 0.
mg/L
mg/L
mg/L
SD
SD O.
mg/L
REF>I_ I GATE
441 0.6928 mg/L
R
440 0
AV 442.7
AV 0.7001
ER-L
.6884
EM
mg/L
I GATE
mg/L
SD
SD 0.
peak -noisy
4.6 CV 1.4
02O1 CV 11.47
4* ± 1503 1
peak -noisy
4*2
peak -noisy
4*3
peak -noisy
21.2 CV 6.O
0931 CV 30.93
4* ± 15O5 1
peak -noisy
peak -noisy
4*3
peak -noisy
8.5 CV 2.O
0373 CV 6.29
4*± 1507 1
4*2
4*3
3.8 CV O.9
0166 CV 2.97
4* 1 15O9 1
4*2
4*3
3.8 CV 0.9
0166 CV 2.37
1/10/98
1/1O/98
1/1O/9S
1/10/98
EM
EM
762
826
2.1009 mg/L
RER-LIC
2.3816 mq/L
4* ±
4*2:
1511 11/10/98
-------
RE:F=-L_ i
0.0524 mg/L
rl'it EM 769 2.1316 mg/L
P214 AV 785.7 EM SD
P214 AV 2.2047 mg/L SD
P214 EM 295
P214 EM 296 O.O568 mg/L
REF>I_ I
P214 EM 318 0.1533 mg/L
P214 AV 303.0 EM SD
P214 AV O.OB75 mg/L SD
35.1 CV 4.5
0.1540 CV 6.98
+1=1 1513 n/io/sa
peak-noisy
peak-noisy
=1*3
peak-noisy
13.0 CV
0.0570 CV
4.3
65.18
-------
iement File: SE.GEL
ate: 11/06/98
ata File:
?chniaue: HGA
tlement: Se
Time: 12:32
ID/Wt File: B1101.IDW
Calib. Type: Linear
Wavelength: 196.0
Slit: 2.00 L
Lamp Current: 0
Energy: 37
ID: 0 PPB
Seq. No.: 00148
A/S Pos.: 0
Date: ll/06/9g
=olicate 1
=ak Area (A-s): O.OO2
ackoround Pk Area (A-s): O.213
lank Corrected Pk Area (A-s): O.O05
Dncentration (ug/L ): 2.73
?Di.icate 2
=ak Area (A-s): 0.006
ackground Pk Area (A-s): 0.211
lank Corrected Pk Area (A-s): 0.009
^ncentration (uo/L ): 4.91
Time: 12:32
Peak Height (A): O.027
Background Pk Height (A): O.09B
Time: 12:35
Peak Height (A): 0.036
Background Pk Height (A): 0.096
?an Cone (ug/L ):
-tto-zero performed.
3.82
SD: 1.539
RSD('/.): 40.28
ID: 10 PPB
Sea. No.: OO149
A/S Pos.: 1
Date: 11/06/S
=olicate 1
=ak Area (A-s): 0.024
ackground Pk Area (A-s): 0.212
lank Corrected Pk Area (A-s): 0.020
Dncentration (ug/L ): 11.17
Time: 12:38
Peak Height (A): O.04B
Background Pk Height (A): 0.092
=ol icate 2
eak Area (A-s): 0.026
ackground Pk Area (A-s): 0.212
lank Corrected Pk Area (A-s): 0.022
oncentration (uo/L ): 12.25
Time: 12:41
Peak Height (A): O.057
Background Pk Height (A): 0.090
ean Cone (ua/L )
11.71
tandard number 1 applied. [1O.OO]
orrelation coefficient: l.OOOOO
SD: 0.76O
Slope: O.OO21
RSD (7.): 6.49
ID: 25 PPB
Sea. No
001 5O
A/S Pos.: 2
Date: il/06/f
eolicate 1
eak Area (A-s): 0.048
ackground Pk Area (A-s): 0.207
lank Corrected Pk Area (A-s): 0.044
oncentration (ug/L ): 20.63
eolicate 2
eak Area (A-s): 0.055
ackground Pk Area (A-s): 0.204
lank Corrected Pk Area (A-s): 0.052
oncentration (ug/L ): 24.22
Time: 12:44
Peak Height (A): 0.104
Background Pk Height (A): 0.091
Time: 12:47
Peak Height (A): 0.097
Background Pk Height (A): 0.089
-------
ean Cone lua/L
22.43
SDs 2.539
RSDC/.): 11.32
tandard number 2 applied. [25.00]
orrelation coefiicient: O.99510
Slope: O.O019
ID: 50 PPB
Sea. No,
00151
A/S Pos.: 3
Date: 11/06/9E
eplicate 1
eak Area (A-s): 0.104
ackground Pk Area (A-s): 0.208
lank Corrected Pk Area (A-s): 0.100
oncentration (UQ/L ): 51.32
Time: 12:50
Peak Height (A): 0.173
Backaround Pk Height (A)s 0.106
eo iicate 2
eak Area (A-s): 0.103
ackground Pk Area (A-s): O.194
lank Corrected Pk Area (A-s): O.O99
oncentration (ug/L ): 50.83
ean Cone (uo/L ):
51.07
Time: 12:53
Peak Height (A): O.178
Background Pk Height (A): 0.096
SD: 0.351
RSD C/.): 0 .69
tandard number 3 applied. [50.OO]
orrelation coefficient: 0.99917
Slope: 0.0020
ID: 1OO PPB
Sea. No,
eplicate 1
eak Area (A-s): 0.196
ackaround Pk Area (A-s): 0.211
lank Corrected Pk Area (A-s): 0.192
pncentration (uo/L ): 96.88
00152
A/S Pos.: 4
Date: 11/O6/9E
Time: 12:57
Peak Height (A): 0.316
Background Pk Height (A): 0.127
eplicate 2
eak Area .(A-s): 0.20O
ackaround Pk Area (A-s): O.214
lank Corrected Pk Area (A-s): 0.196
pncentration (ua/L ): 98.91
iean Cone (ua/L ):
97.89
Time: 13:00
Peak Height (A): 0.329
Background Pk Height (A): 0.130
SD: 1.436
RSDC/.): 1.47
'tandard number 4 applied. [100.001
Correlation coefficient: 0.99974
Slope: 0.0019
-------
H Display tliifcmion - Cl\tt USERMUI FILBX
0. 1?4-
«
i
ii
^J??>*4
^
^'"
a*?*""'
.-«•*'
,-~~
^JZ&
J2i'» !:S???r=»a,-.; s.***?*
*~ Vlf>*<*: 0.0019
0.0 coftconerataan 100.00
i
4
e ID: ICV
eolicate 1
oncentration lug/L ): 56.62
eDlicate 2
oncentration tua/L ): 49.30
ean Cone (ua/L )
C sample is within ranae
Sea. No.: 00153 A/S Pos,
Time: 13:12
Time: 13:15
52.96 3D: 5.174
e ID: ICB
Sea
eolicate 1
oncentration (uq/L ): -5.23
eo i icate 2
oncentration (ug/L
ean Cone lua/L )
): -2.42
-3.82
No.: 00154 A/S Pos.
Time: 13:18
Time: 13:21
SD: 1-989
C samole is within range
-------
s ID: 81101.OB
eolicate 1
oncentration luq/L ): 5.10
solicate 2
oncentration lug/L ): 2.14
Sea. No
ean Cone (ug/L ):
3.62
00156 A/S Pos.: 7
Time: 13:31
Time: 13:34
SD; 2.095
Date: 11/06/9B
'V 'V 'V "V "V *V *V '
e ID: 811O1.UB
eolicate 1
oncentration (ug/L ): 6.13
eoiicate 2
oncentration (ug/L ): 0.53
Sea. No.: 00157 A/S Pos.: 8
Time: 13:37
Time: 13:4O
ean Cone (uo/L ):
3.33
SD: 3.962
e ID: 81101.IB
eolicate 1
oncentration (uo/L
Sea. No
): -O.41
eoiicare ^
oncentration lug/L ): -2.63
ean Lone tuo/L ): -1.52
e ID: 811O1.01 Sea. No.
eolicate 1
oncentration (ug/L ): -0.37
eoi icate 2
oncentration (uo/L ): 1.51
ean Cone
-------
• e ID: 81101.02
!eol icate 1
loncentration (uq/L ): 3.81
•en 1 icate 2
•oncentration iua/L ): 7.89
lean Cone (ua/L )
Sea. No.: O0161 A/S Pos,
Time: 14:02
Time: 14:05
5.85 SD: 2.889
, ,v »v »W "W ~ *v ~ ~ ~ ~ ~ *>> "V "V "V n,,
11 Date: 11/06/s
RSD C/.): 49.39
ie ID: 81101.03
leolicate 1
:oncentration (uo/L ): 0.04
.eoi icate 2
ioncentration (ua/L ): 3.04
lean Cone (ua/L )
Sea. No.: 00162 A/S Pos,
Time: 14:08
Time: 14:11
1.54 SD: 2.118
12 Date:
RSD C/.): 137,
ie ID: CCV Sea.
leolicate 1
)oncentration (uq/L ): 57.31
ieoiicate 2
loncentration (uq/L ): 56.59
lean Cone (uq/L ): 56.95
1C sample is within ranqe
No.: O0163 A/S Pos,
Time: 14:14
Time: 14:17
SD: O.508
Date: 11/06/1
RSD C/.): O.B9
!e ID: CCB Sea. No.
Jeolicate 1
;oncentration (uq/L ): -3.05
ieo i i cate 2
,oncentration (uq/L ): -0.27
lean Cone luq/L ): -1.66
1C sample is within ranoe
00164 A/S Pos,
Time: 14:20
Time: 14:23
SD: 1-966
0 Date: 11/06/i
< "v "w 'V "v "*• '\' '\- '
ie ID: 81101. Ul
ieolicate 1
loncentration (uq/L ): 20.52
-------
s ID: 81101.U2 Sea. No.: 00166 A/S Pos.: 14 Date: 11/06/9B
solicate 1 Time: 14:33
Dncentration (ug/L ): 44.91
=olicate 2 Time: 14:36
sncentratzon lug/L ): 41.69
ean Cone (ug/L ): 43.3O 3D: 2.276 RSD (7.): 5.26
•V 'V "k. PV "V '
s ID: 81101.U3 Sea. No.: 00167 A/S Pos.: 15 Date: 11/O6/9E
eolicate 1 Time: 14:39
oncentration (ug/L ): 44.62
eoiicate 2 Tame: 14:42
oncentration (ua/L ): 44.48
ean Cone (ug/L ): 44.55 SD: 0.103 RSD (7.): 0.23
e ID: 811O1.U4 Sea. No.: 00168 A/S Pos.: 16 Date: 11/06/9E
eolicate 1 Time: 14:45
oncentration (ug/L ): 55.16
soilcate 2 Time: 14:48
oncentration (ug/L ): 49.25
ean Cone (ug/L ): 52. 2O SD: 4.177 RSD (7.): 8.0O
e ID: 811O1.I1X2.5 Sea. No.: 00169 A/S Pos.: 17 Date: 11/06/9E
eolicate 1 Time: 14:51
oncentration (ug/L ): 20.08 Corrected Cone (ug/L ): 50.19
eoiicate 2 Time: 14:54
oncentrataon i'uq/L ): 15.08 Corrected Cone (ug/L ): 37.71
iean Cone (ug/L ): 17.58 SD: 3.531 RSD (7.): 20.08
orrected Cone (ua/L ): 43.95
ie ID: 81101.12 Sea. No.: 00170 A/S Pos.: 18 Date: 11/O6/9E
teolicate 1 Time: 14:57
Concentration (ug/L ): 33=23
ieolicate 2 Time: 15:00
Concentration (uq/L ): 37.75
lean Cone (uq/L ): 35.49 SD: 3.196 RSD(7.): 9.00
-------
e ID: 81101.13 Sea. No.
eolicate 1
oncentration (uo/L ): 43.52
eoi.irate 2
oncentration iug/L ): 42.98
ean Cone (uo/L ): 43.25
O0171 A/S Pos,
Time: 15:03
Time: 15:06
SD: 0.381
19 Date: 11/06/96
RSD(7.): 0.88
Date: 11/06/9&
e ID: CCV Sea. No.:
eolicate 1
oncentration (ug/L ): 55.14
eolicate 2
oncentrataon (ua/L ): 60.78
ean Cone luo/L )
C samole is within ranae
57.96
O0172 A/S Pos,
Time: 15:09
Time: 15:12
SD: 3.985
RSDC/.): 6.87
Date: 11/06/9!
e ID: CCB Sea. 'No. :
eolicate 1
oncentration (ug/L ): 2.62
eolica te 2
oncentration (ug/L ): 4.03
ean Cone (ug/L ): 3.33
C sample is within ranae
00173 A/S Pos.: 0
Time: 15:15
Time: 15:18
SD: 0.997
RSDC/.): 29.97
-------
Element File: AG.GEL
Date: 11/O9/98
Data File:
Techniaue: HGA
Element: Ap
Time: 09:26
ID/Wt File: 81J.OJL.IDW
Calib. Type: Linear
Wavelength: 328.1
Slit: 0.7 L
Lamp Current: 10
Energy: 56
Aa
TD: BLANK
Sea. No.: 00001
A/S Pos.: 0
Date: 11/09/'
Replicate 1
Peak Area (A-s): 0.079
Backaround Pk Area (A-s): O.058
Blank Corrected Pk Area (A-s): -0.016
Concentration (ug/L ): -1.13
Replicate 2
Peak Area (A-s): 0.076
Backaround Pk.Area (A-s): 0.062
Blank Corrected Pk Area (A-s): -0.019
Concentration (ua/L ): -1.31
Time: 09:26
Peak Height (A): O.O95
Background Pk Height (A): 0.028
Time: 09:29
Peak Height (A): O.091
Background Pk Height (A): 0.027
Mean Cone (ug/L ):
Auto-zero performed.
-1.22
SD: 0.129
RSD(7.): 10.58
TD: 5 PPB AG
Sea. No,
OO002
A/S Pos.: 1
Date: 11/O9/'
Replicate 1
Peak Area (A-s): 0.171
Background Pk Area (A-s): 0.069
Blank Corrected Pk Area (A-s): 0.093
Concentration (ua/L ): 4.82
Time: 09:32
Peak Height (A): 0.197
Background Pk Height (A): O.029
ica te *.
Peak Area (A-s): 0.171
Backaround Pk Area (A-s): O.072
Blank Corrected Pk Area (A-s): 0.093
Concentration (ug/L ): 4.81
Time: 09:35
Peak Height (A): 0.201
Backaround Pk Heiaht (A): O.O31
Mean Cone (ua/L )
4. 82
Standard number 1 applied. [5.0O]
Correlation coefficient: l.OOOOO
SDs O.O06
Slope: O.0186
RSD (V.): 0.12
Int: -O.OOO
ID: 10 PPB AG
Sea. No.:- 00003 A/S Pos.: 2
Date: il/09/'
Reali cate 1
Peak Area (A-s): 0.259
Background Pk Area (A-s): 0.076
Blank Corrected Pk Area (A-s): 0.181
Concentration (ug/L ): 9.73
Reo iica te L
Peak Area (A-s): 0.269
Backaround Pk Area (A-s): O.O77
Blank Corrected Pk Area (A-s): O.191
Concentration (ua/L ): 10.27
Time: 09:38
Peak Height (A): 0.297
Backaround Pk Heiaht (A): O.033
Time: 09:41
Peak Height (A): O.311
Background Pk Height (A): O.O33
-------
Mean Cone (ug/L ):
10.00
3D: 0.380
RSDC/.): 3.80
Standard number 2 applied. [10.001
Correlation coefficient: l.OOOOO
Slope: O.O186
Int: -0.000
ID: 20 PPB AG
Sea. Mo.
Replicate 1
Peak Area (A-s): 0.437
Background Pk Area (A-s): 0.088
Blank Corrected Pk Area (A-s): 0.359
Concentration (ua/L ): 19.32
OOO04
A/S Pos.: 3
Date: 11/09/
Time: 09:44
Peak Height (A).: 0. 5O2
Backaround Pk Height (A): 0.046
Characteristic Mass = 2.4 DD/O.OO44 A-s
Reolicate 2
Peak Area (A-s): 0.446
Background Pk Area (A-s): O.087
Blank Corrected Pk Area (A-s): 0.36B
Concentration (ua/L ): 19.79
Time: 09:47
Peak Height (A): 0.513
Background Pk Height (A): 0.045
Mean Cone (ua/L
19.56
SD: 0.330
RSDC/.): 1.69
Standard number 3 applied. [20.00]
Correlation coefficient: 0.99992
Slope: 0.0182
Int: 0.002
Aa
ID: 3O PPB A6
Sea. No
Reolicate 1
Peak Area (A-s): 0.622
Background Pk Area (A-s): 0.099
Blank Corrected Pk Area (A-s): 0.545
Concentration (ua/L ): 29.89
00005 A/S Pos.: 4
Date: il/09/
Time: 09:50
Peak Height (A): 0.699
Background Pk Height (A): 0.058
M<=O iica te 2
Peak Area IH-SJ: O.627
Backaround Pk Area (A-s): 0.102
Blank Corrected Pk Area (A-s): 0.549
Concentration (ua/L ): 30.15
Time: 09:53
Peak Height (A): 0.712
Background Pk Height (A): 0.06O
Mean Cone (uo/L ):
30.02
Standard number 4 applied. [30.00]
Correlation coefficient: 0.99997
SD: 0.179
Sl-ooe: O.O182
RSDC/.): 0.60
Int: 0.002
-------
»|Dj
J.H7-,
IB
*
a
Lsoiay Calibration - ti\M USERVAfi
J7j5ji
^^
^. £3sa
._,--'"
*'-*' intercept: C.OCi
o T*o.:»ntrat:ior» IIKOO
4-
1,
Aa
ID: I CV
Heoiicate I
Concentration ^a/L
Mean Cone iua/L )
Sea
Keolicate 1
Concentration tug/L ): 21.59
No.: 00006 A/S Pos,
Times 09:59
~ime: 10:02
: U . / /
21 .18
SD: O.575
UC samole is within ranae 15.5 - 24.49
Date: 11/09/
RSD (•/.): 2.72
Aa
ID: ICB
Reolicate 1
Concentration lup/L ): 0.42
Reoiicate 2
Concentration iup/L )i 0 , 20
Seo. No.: 00007 A/S Pos,
Time: 10:05
Time: 1O:08
Mean Cone lug/L ): 0.31
QC samole is within range -5.49 - 5.49
3D: 0.156
'V "v '\- '\f 'V *\- "V "V "V «
Aa ID: 81101.B-F
Reoli cate 1
Concentration (ua/L
Sea.
): 0.13
i iicate I
Concentration iug/L i: 0.11
Mean Cone (ua/L ): 0.12
No.: 00008 A/5 Pos,
Time: 10:11
Times 10:14
SD: 0.010
An
ID: 81101.OB
Reolicate 1
Concentration (ua/L ): 0.20
Sea. No.: 00009 A/S Pos
Time: 10:17
Date: 11/09/
RSD (7.): 5O.27
Date: 11/09/
RSDC/.) : 8.57
Date: li/09/
-------
•^.eo 1 i ca te 2
Concentration (ug/'L
Mean Cone (ua/L )
): 0.29
0.25
Time: 10:20
SD: O.O60
RSD(7.): 24.56
Aq ID: 811O1.UB
Reolicate 1
Concentration (ua/L
Sea. No.
Concentration luq/L
Mean Cone (ua/L ) i
): 0.41
): 0.32
O.36
OO010 A/S Pos,
Time: 10:24
Time: 10:27
SD: O.063
B Date: 11/09/?
RSD C/.): 17.61
Aa ID: 81101.IB
Reolicate 1
Concentration (ug/L
neolicate 2
Concentration (ug/L
Mean Cone tua/L ):
Sea. No,
): 0.08
): O.02
O.O5
00011 A/S Pos,
Time: 10:30
Time: 10:33
SD: O.043
Date: 11/09/9
RSD (7.): 81.3B
Aa ID: 811O1.01
Reolicate 1
Concentration (uo/L
Sea. No,
i cate 2
Concentration lug/L
Mean Cone (ua/L ):
): 0.74
): O.5O
0.62
00012 A/S Pos.
Time: 10:36
Time: 10:39
SD: 0.171
10 Date: 11/09/9
i 'V 'V '\i *V *V "V "V-
Aa ID: 811O1.O1
Reolicate 1
Concentration (ug/L
"eoiicate 2
Concentration tug/L
Mean Cone (ug/L );
Recovery is B5.4X
Sea. No.: OOO13 A/S Pos,
Time: 10:42
RSD<•/.): 27.50
10 Date: 11/09/1
): 9.03
J: 9.31
9.17
Time: 10:45
SD: 0.199
RSD (7.): 2.17
Aq ID: 81101.02
Reolicate 1
Concentration (ug/L ): 0.29
Reo1i cate 2
Concentration lug/L ): O.38
Sea. No.: OOO14 A/S Pos,
Time: 10:49
•Time : 10 : 52
11 Date: 11/09/1
-------
Mean Cone (ua/L )
0.33
SD: O.O63
RSD C/.): 19.
Ao ID: 81101.03
Replicate 1
Concentration (ug/L
Peolicate 2
Concentration (ua/L
Mean Cone (ua/L )
Sea. No,
): 0.14
): 0.24
O.19
00015 A/S Pos
Time: 10:55
Time: 10:58
SD: O.O68
12 Date: 11/09/
'V -V 'V 'VS.- "
Aa ID: CCV
Replicate 1
Concentration (ug/L
Replicate 2
Concentration (uq/L
Mean Cone (uq/L )
QC sample is within
): 20.76
Sea. No.: OOO16 A/S Pos.
Time: 11:01
Time: 11:04
): 20.20
20.48 SD: 0.394
ranae 15.5 - 24.49
RSD C/.): 35. 80
Date: 11/O9/
RSD (7.): 1.92
Aq ID: CCB
Replicate 1
Concentration (uq/L
Repli cate 2
Concentration (uq/L
Mean Cone (uq/L );
QC sample is within
): 0.03
Sea. No.: OO017 A/S Pos
Time: 11:07
Time: 11:10
): -0.12
-0.05 SD: O.104
ranae -5.49 - 5.49
Date: 11/09/
RSD (7.): 228.9
Aq ID: 811O1.U1
Replicate 1
Concentration (ua/L
Replicate 2
Concentration (uq/L
Mean Cone (ua/L ):
Aq ID: 81101.U2
Replicate 1
Concentration (ua/L
) : 0.75
): O.75
0.75
Sea, No.: OO018 A/S Pas
Time: 11:13
Time: 11:16
SD: O.O01
13 Date: 11/09/
RSD (7.): O.1O
i icate 2
Concentration
-------
Mean Cone (uo/L ):
0.52
SD: 0.087
RSD C/.): 16.58
Ag ID: 81101.U3
Replicate 1
Concentration (ug/L
Reolicate 2
Concentration (ug/L
Mean Cone (ua/L ):
Sea. Mo,
): 0.37
): 0.38
0.37
OO020 A/S Pos.: 15 Date:
Time: 11:25
Time: 11:28
SD: 0.003
RSD (7.): 0.84
AQ
ID: 81101.U4
Seo. No,
Reolicate 1
Concentration (ug/L
Real i cate 2
Concentration (ug/L
Mean Cone (ua/L ):
): 0.87
00021 A/S Pos.: 16 Date: 11/09/1
Time: 11:31
Time: 11:34
): 0.7;
O.80
SD: O.O99
RSD C/.): 12.27
Reolicate 1
Concentration (Xg/L ): 7.61
Reo1icate
Concentration (ua/L ): 7.84
Mean Cone (ua/L ): 7.
Sea. No.: OOO22 A/S Pos.: 21 Date: 11/09/1
me: 11:37
RSDC/y/): 2.08
Time: 11:40
OOO24 A/S Pos.: 22
Time: 11:44
Time: 11:47
SD: 0.100
ID: 81017.1-7S
A/S Pos.: 23
: 11 : 50
Time: 11:53
SD: O.O59
ID: 81017.1-7
Reolicate 1
Concentration (ug/L yf: 0.24
Reolicate 2
Concentration (u^VL ): 0.38
Mean Cone
ate: li/09/
/ "V "V "V "V -"V 'V*
Aa
Reolicate 1
Concentration (u
Reolicate 2
Concentration (ug/L ): 7.98
Mean Cone lug/L ):
RSDC/.)X 32.65
ate: 11/09/'
RSD C/.): 0.73
-------
-, -V"
Aa
ID: 81O17.1-102
Sea. No.:
Replicate i
Concentration (ug/L
Keel i ca te 2
Concentration
00028 A/S Pos
Time: I1:58
Reo
Concentration (ug/L '):
fieo iicate
Concentration (ua/L/ ): 7.54
Mean Cone (ua/L ):
7.7O
SD: 0.238
•V '\/ *V 'V "V 'V 'V *
Aa ID: CCV
Reolicate i
Concentration (ua/L ): 19.9O
«eolicate 2
Concentration (ua/L ): 19.36
Sea, No.: OO030 A/S Pos,
Time: 12:11
Time: 12:15
Mean Cone lug/L ): 19.63 SD: 0.381
QC sample is within ranae 15.5 - 24.49
Date: ll/09/c
ID': 81017.1-102S
. No.: OO029
Time: K2:05
RSD (7.)i 3. O9
Date: 11/O9/C;
RSD C/.): 1. 94
Aa ID: CCB
Replicate 1
Concentration (ua/L ): 0.00
Sea. No.: 00031 A/S Pos
Time: 12:18
Time: 12:21
Concentration (ug/L ): -O.25
Mean Cone (ua/L ): -0.13 SD: 0.183
QC sample is within ranae -5.49 - 5.49
Date: 11/09/S
RSDC/.): 146.02
Ag ID: 811Oi.il
Replicate 1
Concentration (ug/L
Sea. No.: 00032 A/S Pos,
Time: 12:24
17 Date: 11/09/5
): 2.66
1 1 ca te ^
Concentration tuq/L
Mean Cone (ua/L ):
).: 2.85
2.75
Time: 1^:27
SD: 0.134
RSDC/. )i 4.86
-------
>a ID: 81101.12
Reolicate 1
Concentration (ua/L ): 1.35
Sea. No.: OO033 A/S Pos.: 18
Time: 12:3O
Date: 11/09/9]
Concentration (ug/L ): 1.4O
Mean Cone tua/L ): 1.38
Time: 12:33
SD: O.034
RSD C/.): 2.49
AQ ID: B11O1.I3
Replicate 1
Concentration (ug/L ): 0.25
Reoiicate
Concentration iua/L ): 0.35
Sea. No.: OO034 A/S Pos.: 19
Time: 12:36
Time: 12:39
Date: 11/09/
Mean Cone t'ua/L ):
O.30
SD: 0.069
RSDC/.) : 23.23
Aa --^ID: 81O17.2-102
Reolicate 1
Concentration (uq/L )>/-!.42
« e D i i c a t e 2
Concentration iua/sL ): -O.48
~, ~t -^i -„ ->i ~n ~li ~n ~u
Date: 11/09/'
Sea. No.: OO035 A/S Pos.: 8
Time: 12:46
T/me: 12:49
Mean Cone iua
SD: 0.66O
RSDC/.): 69.52
Date: 11/09/'
ID:x61017.2-102D
No.: OO036 A/S
Time: 12:
Realioete
Concentration (ua/L )
iicate 2
Concentration (ua/L
Time:/I2
Mean Lone iuo/L )
52: O.O94
C/.): 9.07
ID: 81017/3-102
Sea. No/: OO037 A/S Pos
Time: 12:58
Date: 11/09/1
Time: 13:02
SD: O.OS1
Reolicate 1
Concentration (ug/L )
Reoiica te
Concentration luq/L j
Mean cone (ua/L ):
Aa ID: 81017.5-103
Reolicate 1
Sea. No.: OOO^B A/S Pos.: 11
"ime: 13:05
RSDC/.) : 7.06
Date: 11/09/*
-------
Concentration (ua/L ): -0.50
Rea1icate ^
Concentration (uq/L
Mean Cone (ua/L
Time: 13:OB
SD: Oil26
Aa / ID: 81017.B-102
RSD r/.): 21.53
Aa
ID: 81017.7-7102
Replicate 1
Concentration/( ua/L ): -1.08
Sea. No.: OOO39 A/S Pos.
ime: 13:11
12 Date: li/09/
t-"=ol i cate
Concentration (uq/L ): -1.42
Mean Corfc (ua/L ) :
rime: 13:14
SD: 0.241
Reolicate 1
Concentration (ua/L /f: -1,48
Peolicate 2
Concentration (ua/L ): -1.O4
Sea. No.: OO04O
Time:
11/O9/
Time: 13:20
SD: O.310
RSD C/.)j 24.57
Aa ID: CCV
Reolicate 1
Concentration (uq/L ): 17-98
f- : IB.23
Sea. No.: 00041 A/S Pos.
Time: 13:23
Time: 13:26
Date: 11/09/
Mean Cone (uq/L ): 18.10 SD: 0.1BO
QC samole is within ranae 15.5 - 24.49
RSD <"/.): O.99
Aa ID: CCB
Reolicate 1
Concentration (uq/L ): -0.54
^eolicate 2
Concentration (ua/L ): -O.66
Sea. No.: OO042 A/S Pos.
Time: 13:29
Time: 13:32
Date: 11/09/
Mean Cone (uq/L ): -O.60 SD: 0.089
QC samole is within ranqe -5.49 - 5.49
No.: OO043 A/S Pos.
Time: ^£i 35
RSD C/.): 14.76
Ao --TD: B.1017.1O-;
Reo1i cate
14 Date: 11/09/'
-------
ilement File: TL.GEL
)ate: 11/O4/98
>ata File:
'echniaue: HGA
Element: Tl
Time: 10:58
ID/Wt File: UNTITLED
Calib. Type: Linear
Wavelength: 276.8
Slit: 2.00 H
Lamp Current: 7
Energy: 44
ID: BLANK
Sea. No.: 00001
iepl icate 1
>eak Area (A-s): -O.OOO
iackaround Pk Area (A-s): 0.045
Hank Corrected Pk Area (A-s): -O.OOO
ieol icate 2
'eak rtrea < A-s j : O.OO1
iackaround Pk Area (A-s): 0.057
ilank Corrected Pk Area (A-s): O.OO1
lean Pk Area (A-s):
»uto-zero performed.
O.OOO
A/S Pos.: 0
**V *W *W*V ^"VVWivivri,
Date: 11/04/91
Time: 10:58
Peak Height (A): O.O13
Background Pk Height (A): 0.031
Time: 11:O1
Peak Height (A): O.017
Background Pk Height : O.025
Jackground Pk Area (A-s): 0.074
31ank Corrected Pk Area (A-s): O.024
lean Pk Area (A-s):
O.O22
Standard number 1 applied. [10.00]
Correlation coefficient: l.OOOOO
Time: 11:07
Peak Height (A): O.O43
Background Pk Height (A): 0.036
SD: O.O030
Slope: O.0022
RSD (7.): 13.22
ID: 20 PPB TL
Sea. No,
Jeplicate 1
3eak Area (A-s): 0.045
background Pk Area (A-s): 0.096
Hank Corrected Pk Area (A-s): O.045
:oncentration (ug/L ): 20.14
-------
'Correlation coefficient: 0.99561
Slope: 0.0021
ID: 50 PPB TL
Sea. No.
00004
A/S Pos.: 3
Date: 11/04/9
ieplicate 1
!eak Area (A-s): O.1O3
jackaround Pk Area (A-s): 0.137
ilank Corrected Pk Area (A-s): 0.103
Concentration (uq/L ): 48.83
Time: 11:16
Peak Height (A): 0.172
Background Pk Height (A): 0.121
ieoi i cate 2
'eak Area (A-sj: 0.1OO
lackaround Pk Area (A-s): 0.136
Ilank Corrected Pk Area (A-s): 0.10O
ioncentration (ua/L ): 47.26
Time: 11:19
Peak Height (A): 0.166
Background Pk Height (A): 0.121
lean Cone ( ug/L
48.05
SD: 1.115
RSD(7.)i 2.32
itandard number 3 applied. C5O.O01
lorrelation coefficient: 0.99935
Slope: 0.0020
ID: 1OO PPB TL
Sea. No,
OOOO5
A/S Pos.: 4
Date: 11/O4/9
ieplicate 1
'eak Area (A-s): 0.185
lackaround Pk Area (A-s): 0.214
Ilank Corrected Pk Area (A-s): 0.185
loncentration (ua/L ): 9O.4B
Time: 11:22
Peak Height (A): O.28O
Background Pk Height (A): 0.243
:eoi i cate 2
'eak Area i rt-s ) s O.188
lackaround Pk Area (A-s): 0.203
Ilank Corrected Pk Area (A-s): 0.187
loncentration (ua/L ): 91=81
Time: 11:25
Peak Height (A): 0.299
Background Pk Height (A): 0.238
lean Cone (ua/L
91.1'
SDs 0.945
BSD ('/.)! 1.04
itandard number 4 applied. [100.00]
lorrelation coefficient: 0.99776
Slope: 0.0019
"Display Calibration -C:\ftft US!
.»»»*
0.0022
100.00
-------
1 ID: ICV Sea. No,
eol icate 1
oncen tration iua/L ): 52.24
eo i
oncentration IUQ/L ): 50.36
iean Lone lug/L ): 51.30
!C samole is within ranqe
O0006 A/S Pos
Time: 11:32
~ime: i1:35
SD: 1.331
5 Date: li/Q4/^j
1 ID: ICB Sea. No,
leolicate 1
:oncentration (ug/L ): -0.15
i cate 2
.oncentrataon (uq/L ): O.61
lean Cone (ua/L ): O.23
1C samole is within range
00007 A/S Pos,
Time: 11:38
Time: 11:41
SD: 0.539
1
ID: 811O1.B-F
Sea. No.:
ieolicate 1
ioncentration (uq/L ): 0.33
.oncentration iug/L ): -0.18
lean Cone iua/L ): 0.08
OOOO8 A/S Pos,
Time: 11:44
Time: 11:47
SD: 0.360
"v "v 'V '^ ' V 'V' PV <^« *
"1 ID: 81101.DB
ieolicate 1
ioncentration (ug/L
ieoiicate 2
Concentration (ua/L
lean Cone (ua/L >:
Sea. No.
): -0.75
) : 1.73
0.49
OOOO9 A/S Pos,
Time: 11:50
Time: 11:53
SD: 1.756
"1 ID: 81101.UB
ieolicate 1
Concentration (uq/L
teolicate 2
Concentration (uq/L
lean Cone i ua/L ) :
Sea. No,
): 1.04
j: 2.85
1.94
00010 A/S Pos,
Time: 11:56
Time: 11:59
SD: 1.282
B
RSD(7.): 2.59
Date:. 11/04/1?
RSD ('/.): 231.2S
Date:
RSD ('/.): 452.84
Date: 11/04/1!
RSD(7.): 357.OC
Date:
RSD(7.): 66.04
-------
"1 ID: B11O1.IB
(eol i cate 1
Concentration (uq/L
: 878.83
"1 ID: 81101.01 Sea. No
ieolicate 1
Concentration (uo/L ): 49.94
i: 52.18
51.06
00013 A/S Pos.: 10 Date: 11/O4/9I
Time: 12:15
Time: 12:18
loncentration (ug/L
lean Lone (uq/L ) :
iecoverv is 101.67.
SD: 1.578
RSD ( 7.) : 3.09
'I IDs 81101.02
ieolicate 1
)oncentration (uq/L
-------
"1 ID: CCV
ieol i cate 1
Concentration (tia/L
Sea. No,
): 49.28
-------
"1 ID: 81101.U4 Sea, No.
ieol icate 1
loncentration (ug/L ): 9.00
ieol a ca te 2
,oncentration lug/L ): 7.74
lean Cone lug/L ): 8.37
"1 ID: 81101.11 Sea. No.
ieolicate 1
loncentration (ua/L ): 11.77
ieolicate 2
Concentration (ua/L j: 9.95
lean Cone (ua/L ):
10.86
OOO21 A/S Pos,
Time: 13:O3
Time; 13:05
SD: 0.888
00022 A/S Pos.
Time: 13:08
Time: 13:11
SD: 1.291
16 Date: 11/04/9
'1 ID; 81101.12 Sea. No,
leolicate 1
)oncentration (ug/L ): 12.53
ieoiicate 2
Concentration (ua/L ): 9.97
lean Cone i ua/L ) :
11.24
OO023 A/S Pos,
Time: 13:14
Tame : 13 :17
SDs 1.810
RSD ('/.): 10.60
17 Date: ll/04/9f
RSD (•/.): 11.89
IB Date: 11/O4/9!
RSD (7.): 16.10
'I
ID: 81101.13
Sea. No,
teolicate 1
Concentration (ua/L ): 12.11
ieoiicate 2
Concentration (ua/L ): 11.12
lean Cone ( ua/L
11 .61
00024 A/S Pos,
Time: 13:20
Time: 13:23
SD: 0.694
19 Date: 11/O4/9
"1
ID: CCV
Sea. No,
ieolicate 1
Concentration (ug/L ): 54.72
-------
'1 ID: CCB Sea. No.: 00026 A/S Pos. : 0 Date: 11/04/!
ieolicate 1 Time: 13:32
Concentration (uq/L ): 0.21
ieolicate 2 Time: 13:35
-oncentrataon (uq/L ): 0.3B
lean Cone (uq/L ): 0.29 SD: 0.120 RSDC/.): 40.90
)C samole is within ranqe
-------
PARKIN • Ei .MER
I'i i .i 00
98/11/11 PAGE 6
MAIM: 0.001
ZN MEAN: 0,001
AA
HO 0.001
A A
HO 0,000
MAIN; 0.001
SDr 0.000 RSDr 11.5 AUTOZERO 0.000
MA.! Mr. 0.020
ZN MEAN;: 0.020
AA
HO 0,020
A A
MAI Mi 0.021 HO 0.021
SDt 0.000 RGD: 0.3 1.STANDARD 0.050 MG/L
A A
AA
MAIN:: 0.100 MG/L HO 0,041 MAINt 0.101 MG/L HO 0.041
ZN MEANs 0.101 MG/L SD: 0.001 RSD; 0.. 8 2. STANDARD 0.100 MG/L
A A
AA
MAIM;: 0.195 MD/L. HO 0.080 MAIN: 0,196 MG/L HO 0.081
ZN MEANE O.I 96 MB/L BD; O.OO1 RBD: 0.4 3. STANDARD 0.199 MG/L.
A A
AA
MAIN;; 0.479 MG/L HO 0,194 MAIN: 0.478 MG/L HO 0,193
ZN MEANs 0.479 MG/L GD: 0.001 RSDr 0.2 4.STANDARD 0.496 MG/L
A A
AA
MAI Mr 0., 913 MG/L HO 0.356 MAIN: 0.927 MG/L HO 0.362
ZN MEAN:; 0,920 MG/L BD: 0.010 RSDr 1.1 5. STANDARD 0.979 MG/L
FLAME DISPLAY CALIBRATION MODE PRINTER: ON
ELEMENT: ZN EG CORR: OFF
REPL, 8 OF
0
3 «*
READ
" ABS. READING
S5 AA : 0.362
ABS.
SA
B2
31
CONCENTRATION (M3/L )
i.00i3
STATISTICS
MEAN: 0.920
SD: 0.S10
RSD(%): 1.1
C2H2: 2.5 L/MIN OX IDANT: 8.3 L/MIN FLAME: C2H2-AIR
A A
MAIM; O „ 0O9 MB /L HO 0. 000
A A
MAIN: 0.010 MG/L HO 0,000
-------
M 11 CO 90/11/11 PAGR
A A A A
AIN:- 0,489 MG/L USD 0,189 MAIN: 0.4B3 MG/L HO 0., 187
MEANs 0.436 MG/L 3D:: 0.005 RED: 1.0
AA AA
IAIN: 0.005 MG/L. HO 0.002 MAIN: 0.005 MG/L HO O.OO2
MEAN;; 0.005 MG/L CDs O.OOO RSD: 6.1
AA AA
MAIM: 0.044 MG/L HO 0,018 MAIN: 0.049 MB/L. HO 0.020
7N S MEAN; 0.047 MB/L GDs 0,004 RBD; 7,9
AA AA
MAIM; 0,032 MB/L. HO 0,. 034 MAIN; 0,. OBI MG/L HO 0.033
ZN OR, MEANs 0, OB2 MG/L SD: 0.001 RRDs 0.9
AA AA
MAIN: 0.102 MB/L HO 0,042 MAIN: 0.1 IB MG/L HO 0.048
MEAN: 0.110 MG/L SDs 0.01.1 RSD: 9,. 7
AA AA
MAIM;: 0.123 MG/L HO 0., 050 MAINs 0.119 MG/L HO 0.. 049
MEAN: 0,121 MG/L BD:: 0.002 RBD; 2.0
AA AA
MAIN; 0.015 MG/L HG 0.006 MAIN: 0,,015 MB/L HO 0,006
ZN A 3. MEANs 0.015 MG/L SD: 0.000 RSD: 0,£3 AUTOZERO 0.000
A A A A
MAIN: 0.154 MG/L. HO 0.062 MAIN: 0.157 MG/L HO 0.064
ZN £>( MEAN: 0.155 MG/L BD: 0.002 RBD: 1.2
A A A A
MAIN: 0.525 MG/L HO 0.202 MAIN: 0.511 MG/L HO 0.197
~l t.
''J IS> MniflNi: Q.,518 MG/L SD: 0.01O RSD ;• 1.9
AA AA
HA IN: 0.157 MG/L !--C 0., 063 MAIN: 0.198 MB/L HO 0.080
ZN O i- MEANr 0.177 MG/L SD: 0.. 030 RSDr 16.. 7
-------
9B/!J./Jl PAGE S
AA AA
MAIN;: 0 L62 MG/L. HO 0.065 MAIN: 0.169 MG/L HO 0.068
MEAN:- 0.165 MG/L BD: 0.005 RED: 3,. 2
A A A A
0.201 MG/L HO 0.. 081 MAIN; 0.206 MB/L HO 0.083
ZN £ 2> MEAN: 0., 204 MG/L BO; 0.003 RBDr 1.5
AA AA
MAIIMs 0.002 MG/L HO 0.001 MAIM: 0,002 MB/L HO 0.001
ZN AZr- MEAN? 0,002 MB/L ED: 0.000 RSD: 1,3 AUTOZERQ 0.000
A A A A
MAIN; 0,. [510 MB/L HO 0.196 MftlNr 0.518 MB/L HO 0.199
ZM C^^ MEAN;: 0..514 MB/L SDs 0.005 RBD: 1,0
A A A A
MAINs 0,002 MB/L HO O.OO1 MAIN:: 0.007 MB/L. HO 0..003
ZN cc_2> MEAN; 0.004 MB/L 8D; 0.004 RGD: 88.9
AA AA
MAIN: 0,. 305 MB/L HO 0.121 MAIN: 0.319 MG/L HO 0..126
ZN // / MEAN',1 0.312 MB/L BD: 0.010 RSD: 3., 1
A A A A
MAINr 0.359 MB/L HO 0., 141 MAIN: 0.388 MG/L HO 0.152
7 N 2_- ME AN : 0.373 MG/L. S D: 0.021 RSD r 5. 6
A A A A
MAIN:: 0.345 MB/L HO 0.136 MAIN: 0,339 MB/L HO 0.134
ZN MEAN: 0.. 342 MG/L BDr 0,,004 RBD: 1.2
A A A A
MAIN: 0.361 MG/L HO 0.142 MAIN: 0.346 MB/L HO 0.136
N MEAN: 0.354 MB/L SD: 0.010 RSD: 2.9
A A A A
MAIN: 0.258 MB/L HO 0.103 MAIN; XO6B MG/L HO 0.028
"MM t(&± MEAN; 0.162 MB/L Sr>r O.J34 RCD^ B2.3
-------
>•-' 1 :i 00 '?n/:i. :i /11
A A A A
0..•?••::[ MR/i. HO 0.263 MATNs 0.699 MG/L HO 0.262
«*JWtMiTANs 0.700 MB/L BD: 0.002 RSD: 0.2
A A A A
MAIN; 0,. 460 MG/L HO 0.181 MAIN: 0.472 MG/L HO 0.183
AN; 0.470 MG/L SDi 0.003 RSD: 0.6
AA AA
MAIN:; 0.529 MG/L HO 0.203 MAIN: O.. 550 MG/L HO 0.210
ZN <££ i-iEANt 0.540 MG/L GD: 0.015 RSD? 2.7
A A A A
0.523 MG/L HO 0.201 MAINt 0.517 MG/L HO 0,199
MEAN;: 0.520 MG/L BDs 0.004 RBDi O.S
AA AA
MAIN: 0.012 MG/L HO 0.005 MAIN: 0.011 MG/L HO 0., 005
MEAN;: 0.012 MG/L BD; 0..000 RSD; 3.4
-------
r- Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
1INNATI, OH 45249-1030
Final Report
i Received: 10/09/98
ile Type: 12 Air Sample (s)
ect: 5512.000
.ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
A-I-5506-1 Samp Date: 09/21/98 MALEIC ANHYDRIDE
Acnapth- Front
Acnapth-Rear
Acnapht- Total
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt- Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Bzpery-Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt-Front
Bz (k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Page
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
1
< 5.0 ug
ND
<5.0ug -___
13.9 ug
ND
13.9 ug -- --
1.95 ug
ND
1.95 ug -- --
< 1.0 ug
ND
< 1 . 0 ug --__
< 1.0 ug
ND
<1.0ug -_-_
< 1.0 ug
ND
< 1 . 0 ug -__-
< 1.0 ug
ND
< 1 . 0 ug -___
< 1.0 ug
ND
< 1 . 0 ug --__
2.37 ug
-------
S-. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
TNNATI, OH 45249-1030
Final Report
Received: 10/09/98
•le Type: 12 - Air Sample (s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Chy-Rear
Chy-Total
Db z anthr - Front
Db z anthr - Rear
Dbzanthr-Total
Flanthr-Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene - Rear
Fluorene-Total
Indpyene- Front
Indpyene-Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
Volume
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
Amount
ND
2.37 ug
< 1.0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
31.3 ug
4 .6 ug
35.9 ug
16.2 ug
ND
16.2 ug
40.4 ug
ND
40.4 ug
Concentration
-- --
__ __
__ __
__ __
__ __
— —
— —
-- --
> A-I-5506-2 Samp Date: 09/22/98 MALEIC ANHYDRIDE
Acnapth-Front < 5.0 ug
Acnapth-Rear ND
Page 2
-------
=r Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
1INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concent rat i on
Acnapht - Tot al
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b) fnt- Front
Bz(b) fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz(k) fnt -Front
Bz (k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Db z ant hr- Rear
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
<5.0ug ----
< 5,0 ug
ND
<5.0ug _---
< 1.0 ug
ND
< 1 . 0 ug _-_-
< 1 . 0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
< 1 . 0 ug -___
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
< 1.0 ug ----
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
< 1 . 0 ug _---
< 1.0 ug
ND
Page 3
-------
^ Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
ZHEFFEL
FIG ENVIRONMENTAL SERVICES
3CHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene - Rear
Fluorene -Total
Indpyene - Front
Indpyene - Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth-Total
Pant hr- Front
Pant hr- Rear
Panthr- Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
Volume
NVG
NVG
NVG
NVG
NVG
NVG
NVG
Amount Concentration
<1.0ug _--_
< 5.0 ug
ND
<5.0ug ---_
< 5.0 ug
ND
<5.0ug ---_
< 1.0 ug
ND
< 1 . 0 ug ---_
< 5.0 ug
ND
<5.0ug ---_
< 1.0 ug
ND
< 1.0 ug ---_
< 1.0 ug
ND
< 1 . 0 ug --__
A-I-5506-3 Samp Date: 09/23/98 MALEIC ANHYDRIDE
Acnapth- Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Page
NVG
NVG
4
< 5.0 ug
ND
<5.0ug --__
< 5.0 ug
ND
<5.0ug --__
-------
r Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34-419005
Report Date: 10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant-Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt-Front
Bz (b)fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz(k)fnt- Front
Bz (k) fnt-Rear
Bz (k)fnt-Total
Chy- Front
Chy-Rear
Chy- Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
Page 5
-------
Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Fluorene - Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene - Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
NVG
NVG
NVG
NVG
NVG
A-O-5506-1 Samp Date: 09/21/98 MALEIC
Acnapth- Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Ant hr- Front
Anthr-Rear
Anthr-Total
Bz( a) ant -Front
Page
0
0
0
6
< 5.0 ug
ND
<5.0ug --__
< 1.0 ug
ND
< 1 . 0 ug ---_
< 5.0 ug
ND
<5.0ug ---_
< 1.0 ug
ND
< 1 . 0 ug ---_
< 1.0 ug
ND
<1.0ug ---_
ANHYDRIDE
< 5.0 ug
ND
< 5 . 0 ug < 1
< 5.0 ug
ND
< 5.0 ug < 5
< 1.0 ug
ND
< 1.0 ug < 1
< 1.0 ug
-------
sr Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
iCHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
• EAST KEMPER RD
IINNATI, OH 45249-1030
Final Report
i Received: 10/09/98
ile Type: 12 - Air Sample (s)
ect: 5512.000 PO Number
.ytical Results
Client ID Parameter Volume
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a) pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b) fnt- Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt -Front
Bz (k) fnt-Rear
Bz (k) fnt-Total
Chy- Front
Chy-Rear
Chy- Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene -Rear
Fluorene -Total
Indpyene - Front
Page
0
0
0
0
0
0
0
0
0
7
Amount
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 5
ND
< 5
< 5
ND
< 5
< 1
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
Concentration
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 5
< 5
-------
r. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Indpyene - Rear
Indpyene-Total
Napth- Front
Napth-Rear
Napth- Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
Volume
0
0
0
0
Amount
ND
< 1.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
Concentration
ug < 1
ug
ug < 5
ug
ug < 1
ug
ug < 1
A-O-5506-2 Samp Date: 09/22/98 MALEIC ANHYDRIDE
Acnapth- Front
Acnapth-Rear
Acnapht- Total
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant-Front
Bz (a) ant -Rear
Bz (a) ant-Total
Bz(a)pyr-Front
Bz(a)pyr-Rear
NTG
NTG
NTG
NTG
< 5.0
ND
< 5.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
Page 8
-------
S-. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Bz (a)pyr-Total
Bz(b)fnt-Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz(k)fnt-Front
Bz (k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Chy-Rear
Chy- Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene-Rear
Indpyene -Total
Napth- Front
Napth-Rear
Volume
NTG
NTG
NTG
NTG
NTG
NTG
NTG
NTG
NTG
Amount Concentration
< 1 . 0 ug ----
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
< 1 . 0 ug -___
< 1.0 ug
ND
< 1 . 0 ug -___
< 1.0 ug
ND
< 1 . 0 ug -___
< 1.0 ug
ND
< 1 . 0 ug --_-
< 5.0 ug
ND
<5.0ug -_--
< 5.0 ug
ND
<5.0ug ----
< 1.0 ug
ND
< 1 . 0 ug - - - -
6.58 ug
ND
Page 9
-------
sr. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Napth-Total
Panthr- Front
Pant hr- Rear
Panthr-Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
Volume
NTG
NTG
NTG
Amount Concentration
6.58 ug -- --
4 .0 ug
ND
4 . 0 ug - - - -
9.2 ug
ND
9.2 ug __ __
A-O-5506-3 Samp Date: 09/23/98 MALEIC ANHYDRIDE
Acnapth- Front
Acnapth-Rear
Acnapht- Total
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr -Total
Bz (a) ant-Front
Bz (a) ant -Rear
Bz (a) ant-Total
Bz (a) pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt- Front
Bz (b) fnt-Rear
Bz (b) fnt-Total
Page
0
0
0
0
0
0
10
< 5.0 ug
ND
< 5 . 0 ug < 1
< 5.0 ug
ND
< 5 . 0 ug < 5
< 1.0 ug
ND
< 1 . 0 ug < 1
< 1.0 ug
ND
< 1 . 0 ug < 1
< 1.0 ug
ND
< 1.0 ug < 1
< 1.0 ug
ND
< 1.0 ug < l
-------
r. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
2HEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
SCt: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt- Front
Bz (k) fnt -Rear
Bz(k)fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene-Rear
Indpyene-Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Page
0
0
0
0
0
0
0
0
0
11
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
8.87 ug
ND
8.87 ug
3.78 ug
ND
3.78 ug
< 1
< 1
< 1
< 1
< 5
< 5
< 1
--
—
-------
ir. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Pyrene-Front
Pyrene-Rear
Pyrene-Total
A-U-5506-1 Samp Date: 09/25/98
6.34 ug
ND
6.34 ug
MALE1C ANHYDRIDE
Acnapth-Front < 5.0 ug
Acnapth-Rear ND
Acnapht-Total NVG < 5.0 ug
Acnthy-Front < 5.0 ug
Acnthy-Rear ND
Acnthy-Total NVG < 5.0 ug
Anthr-Front < l.O ug
Anthr-Rear ND
Anthr-Total NVG < 1.0 ug
Bz(a)ant-Front < 1.0 ug
Bz(a)ant-Rear ND
Bz(a)ant-Total NVG < 1.0 ug
Bz(a)pyr-Front < i.o ug
Bz(a)pyr-Rear ND
Bz(a)pyr-Total NVG < 1.0 ug
Bz(b)fnt-Front < l.O ug
Bz(b)fnt-Rear ND
Bz(b)fnt-Total NVG < 1.0 ug
Bzpery-Front < l.O ug
Bzpery-Rear ND
Bzpery-Total NVG < 1.0 ug
Bz(k)fnt-Front < i.o ug
Page 12
-------
£r- Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
'INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Bz (k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene-Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene- Front
Pyrene-Rear
Pyrene-Total
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 5,0
ND
< 5.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
Page 13
-------
^. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
IINNATI, OH 45249-1030
Final Report
: Received: 10/09/98
>le Type: 12 - Air Sample (s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
A-I-5506-FB Samp Date: 09/23/98 MALEIC
Acnapth- Front
Acnapth-Rear
Acnapht- Total 0
Acnthy- Front
Acnthy-Rear
Acnthy-Total 0
Anthr- Front
Anthr-Rear
Anthr -Total 0
Bz (a) ant-Front
Bz (a) ant-Rear
Bz (a) ant-Total 0
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total 0
Bz(b) fnt- Front
Bz (b) fnt-Rear
Bz (b) fnt-Total 0
Bzpery- Front
Bzpery-Rear
Bzpery- Total 0
. Bz(k) fnt -Front
Bz(k) fnt-Rear
Bz(k) fnt-Total 0
Chy- Front
Chy-Rear
ANHYDRIDE
< 5
ND
< 5
< 5
ND
< 5
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
< 1
< 1
ND
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
< 1
< 5
< 1
< 1
< 1
< 1
< 1
< 1
Page 14
-------
r. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concent rat i on
Chy- Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene - Rear
Fluorene-Total
Indpyene - Front
Indpyene -Rear
Indpyene -Total
Napth- Front
Napth- Rear
Napth- Total
Pant hr- Front
Panthr-Rear
Panthr-Total
Pyrene - Front
Pyrene -Rear
Pyrene -Total
0
0
0
0
0
0
0
0
< 1
< 1
ND
< 1
< 5
ND
< 5
< 5
ND
< 5
< 1
ND
< 1
< 5
ND
< 5
< 1
ND
< 1
< 1
ND
< 1
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
< i
< i
< 5
< 5
< 1
< 5
< 1
< 1
LAB BLANK 1
Samp Date: 09/28/98 BLANK
Acnapth-Front
Acnapth-Rear
Acnapht-Total 0
Page 15
MALEIC ANHYDRIDE
< 5.0 ug
ND
< 5.0 ug
-------
£-. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Ant hr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt-Front
Bz (b) fnt-Rear
Bz (b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt- Front
Bz (k) fnt-Rear
Bz (k) fnt-Total
Chy- Front
Chy-Rear
Chy- Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Page
Volume
0
0
0
0
0
0
0
0
0
16
Amount
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
Concentration
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
-------
Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
:HEFFEL
FIG ENVIRONMENTAL SERVICES
3CHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
2Ct: 5512.000
/tical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene-Rear
I ndpyene - To t a 1
Napth- Front
Nap th- Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr- Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
0
0
0
0
0
0
< 5.0 ug
ND
< 5 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
LAB BLANK 2 Samp Date: 09/28/98 BLANK
Acnapth-Front
Acnapth-Rear
Acnapht-Total 0
Acnthy-Front
Acnthy-Rear
Acnthy-Total 0
Anthr-Front
Page 17
MALE1C ANHYDRIDE
< 5.0 ug
ND
< 5,
< 5
ND
< 5.0 ug
< 1.0 ug
, 0 ug
. 0 ug
-------
Isr. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Cone ent rat i on
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt-Front
Bz(b)fnt-Rear
Bz(b) fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz(k) fnt- Front
Bz (k) fnt-Rear
Bz(k) fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Fl anthr - Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
0
0
0
0
0
0
0
0
0
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1.0 ug
< 1 . 0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 5.0 ug
Page 18
-------
^r. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received; 10/09/98
le Type: 12 Air Sample (s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Fluorene - Rear
Fluorene -Total
Indpyene- Front
Indpyene -Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
SPIKE 1 Samp Date: 09/28/98 SPIKE
Acnapth- Front
Acnapht -Total
Acnthy- Front
Acnthy- Total
Anthr- Front
Anthr-Total
Bz (a) ant-Front
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Total
Bz(b)fnt-Front
0
0
0
0
0
MALEIC
0
0
0
0
0
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
ANHYDRIDE
23.9 ug
23.9 ug
31.4 ug
31.4 ug
1.35 ug
1.35 ug
2.16 ug
2.16 ug
0.73 ug
0.73 ug
1.85 ug
Page 19
-------
^r Analytics Division "~
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
PO Number:
Client ID Parameter
Bz(b)fnt-Total
Bzpery- Front
Bzpery- Total
Bz (k) fnt- Front
Bz(k)fnt-Total
Chy- Front
Chy- Total
Dbzanthr- Front
Dbzanthr-Total
Flanthr- Front
Flanthr-Total
Fluorene - Front
Fluorene-Total
Indpyene - Front
Indpyene- Total
Napth- Front
Napth-Total
Panthr- Front
Panthr-Total
Pyrene- Front
Pyrene- Total
SPIKE 2 Samp Date: 09/28/98 SPIKE
Acnapth- Front
Acnapht- Total
Acn thy -Front
Acnthy- Total
Volume
0
0
0
0
0
0
0
0
0
0
0
MALEIC
0
0
Amount
1.85 ug
0.96 ug
0.96 ug
1.71 ug
1.71 ug
2.10 ug
2.10 ug
1.43 ug
1.43 ug
1.20 ug
1.20 ug
18.3 ug
18.3 ug
1.29 ug
1.29 ug
33.3 ug
33.3 ug
1.31 ug
1.31 ug
11.0 ug
11.0 ug
ANHYDRIDE
24.8 ug
24.8 ug
33.1 ug
33.1 ug
Concentration
--
--
--
--
--
—
--
--
--
—
--
Page 20
-------
r. Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentrat ion
Anthr- Front
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Total
Bz(b)fnt-Front
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Total
Bz(k)fnt- Front
Bz(k)fnt-Total
Chy- Front
Chy- Total
Dbzanthr- Front
Dbzanthr-Total
Flanthr- Front
Flanthr-Total
Fluorene - Front
Fluorene -Total
Indpyene - Front
Indpyene- Total
Napth- Front
Napth-Total
Panthr - Front
Panthr-Total
Pyrene- Front
0
0
0
0
0
0
0
0
0
0
0
0
0
1.40 ug
1.40 ug
2.24 ug
2.24 ug
0.73 ug
0.73 ug
2.06 ug
2.06 ug
1.00 ug
1.00 ug
1.95 ug
1.95 ug
1.22 ug
1.22 ug
1.49 ug
1.49 ug
1.24 ug
1.24 ug
19.1 ug
19.1 ug
1.35 ug
1.35 ug
34.8 ug
34.8 ug
1.44 ug
1.44 ug
6.72 ug
Page 21
-------
S-- Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C282090
Account No. 34419005
Report Date: 10/19/98
CHEFFEL
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 - Air Sample(s)
ect: 5512.000
ytical Results
Client ID
Parameter
PO Number:
Volume Amount
Concentration
Pyrene-Total
0
6.72 ug
aviations: ug = micrograms,, mg = milligrams, mg/M3 = milligrams per
ic meter of air, g = grams, ug/M3 = micrograms per cubic meter of air,
liters, w/w = percent weight basis, all Volumes given in liters,
= parts per million, ppb = parts per billion, Areas given in square
t; ND = Not Detected.
iary of Analytical Methods
ound Name
Analytical Method
Abbreviation
.aphthene
.aphthylene
.racene
(a) anthracene
o ( a ) pyrene
o (b) f luoranthene
o (ghi)perylene
o (k) f luoranthene
•sene
nz (a,h) anthracene
•ranthene
•rene
no ( 1 , 2 , 3 - cd) pyrene
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
NIOSH 5506
Acnapht
Acnthy
Anthr
Bz (a) ant
Bz(a)pyr
Bz(b)fnt
Bzpery
Bz(k)fnt
Chy
Dbzanthr
Flanthr
— — _ —
Indpyene
Page 22
-------
^r: Analytics Division
Laboratory Corporation of America™ Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date:
C282090
34419005
10/19/98
CHEFFEL
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
EAST KEMPER RD
INNATI, OH 45249-1030
Final Report
Received: 10/09/98
le Type: 12 Air Sample(s)
ect: 5512.000
PO Number:
ytical Method - continued
thalene NIOSH 5506
anthrene NIOSH 5506
ne NIOSH 5506
Napth
Panthr
Attached are the results we obtained on the analysis of your
samples. Any Chains-of-Custody associated with this sample
group are also enclosed. Air concentrations are calculated
as a convenience to the client and the overall accuracy of
this result depends on both the accuracy of the air volume and
the amount found by analysis. Theoretical Air Volumes for
passive monitors are calculated using the sampling time
submitted and the manufacturer's listed sampling rate for each
compound.
We appreciate your confidence in allowing Analytics to be your
testing laboratory. Any questions regarding this report can
be addressed by calling our client services department
(800-888-8061).
Page
pin, CIH
irector
-------
OPAC
PACIFIC ENVIRONMENTAL SERVICES, INC.
Chain of Custody Record
Cincinnati, OH 45249-1030
513.489.6611
FAX: 513.489.6619
Samplers:
PES Field Sample ID
Date
Purchase Order No.:
Time
Sample Description
Number
of
Containers
Analysis Requested
Comments
-MS*,- I
X
.4
JA/Zd
X
K
Md 4/ZZK// /XtW /
3
3
X
Ou
3
X
9/JS/W
3
X
3
X
X
nfffA/
nfi+4*
~~^'2
•yv/Vi
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time Received by: (Signature)
Dale/Time
Received for lab by: (Signature)
REMARKS
^^=» --s«>
_0^_
•7 ^/ /c«_ ^^
C^c»/
-------
TABLE 4.3
PAH IN-STACK DETECTION LIMITS
t->
y-
V
y-
y-
X
c_
z
<:
X
>
x
s^_
XL
Analyte
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
fluorene
Phenanthree
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno( 1 ,2,3 -cd)pyrene
Dibenz£a,h)anthracene
Benzo(g,h,i)perylene
In-Stack Detection Limit ng/dscma
Sample Volume, dscm
1
1,000
1,000
2-10
2-10
200
500
2-10
100
2-10
100
2-10
2-10
2-10
2-10
2-10
2-10
2-10
2-10
2-10
2
500
500
1-5
1-5
100
250
1-5
50
1-5
50
1-5
1-5
1-5
1-5
1-5
1-5
1-5
1-5
1-5
Nanograms per dry standard cubic meter.
4-4
-------
J:
JO? -
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Page
Client
of
/
/H^>O L^3A£ c>Lf'h'f'inabrf\riL
a
Prepared By
Date Checked By Date Shoot Titlo
Me
WASHINGTON, DC • RESEARCH TRIANGLE PARK, NC • LOS ANGELES, CA- C^UINNAI I. UN
-------
First Analytical Laboratories
ANALYSIS REPORT
Metals in Dust
Project # S512.000
Prepared for:
Pacific Environmental Services, Inc.
7209 E. Kemper Road
Cincinnati, OH 45249
Reviewed and Approved by:
William H. Wadlin, Ph. D.
Laboratory Manager
October 27, 1998
-------
First Analytical Laboratories
ANALYSIS REPORT
Metals in Dust
Project # S512.000
Prepared for:
Pacific Environmental Services, Inc.
7209 E. Kemper Road
Cincinnati, OH 45249
Reviewed and Approved by:
William H. Wadlin, Ph. D.
Laboratory Manager
October 27, 1998
-------
Quality Control:
The spike recoveries were all within the normal range of 70% to 130%,
except that beryllium and silver were slightly low, which is not unusual. The
duplicates were all within the normal limit of 20% for all cases in which the sample
level is more than five times the detection limit. Below this level it is not possible
to make a meaningful evaluation of the deviation between duplicates.
-------
First Analytical Laboratories
/ ».•»-» .M-A^U (giQ) 942-8607
1126 Burning Tree Dr. Chapel Hill, NC 27514 FAX (919) 929-8688
*
ANALYSIS REPORT
Project #: 81006
Client: Pacific Environmental Services
Client Project ID: S512.000
Parts per million
pg/g
Sample Sb As
GFAA GFAA
BD-AC-1 <0.2 13.4
BD-AC-2 <0.2 11.2
BD-AC-3 < 0.2 9.1
QC SUMMA
Spikes
% Recovery 102% 102%
Duplicates
%RPD
Report Date: 27-Oct-98
Date Received: 09-Oct-98
in original sample
Ba Be Cd
ICP GFAA FLAA
27.6 0.33 1.2
37.1 0.36 1.0
27.6 0.35 1.2
RY
80% 61% 96%
4.2% 10.5%
Cr
ICP
16.3
10.2
10.0
76%
9 A%
-------
First Analytical Laboratories Tel (919) 94M607
1126 Burning Tree Dr. Chapel Hill, NC 27514 FAX (919) 92^8688
ANALYSIS REPORT
Project #: 81006 Report Date: 27-Oct-98
Client: Pacific Environmental Services Date Received: 09-Oct-98
Client Project ID: S512.000
Parts per million in original sample
Sample
BD-AC-1
BD-AC-2
BD-AC-3
Cu
ICP
10.6
9.5
9.4
Mn
FLAA
24.1
16.1
16.6
Hg
CVAA
<0.07
< 0.07
< 0.07
Pb
FLAA
21
16
16
Ni
GFAA
20
13
13
QC SUMMARY
Spikes
% Recovery 83% 94% 98% 84%
Duplicates
%RPD 1.0% 0.0% 6.1%
-------
First Analytical Laboratories Tel 94M60,
1126 Burning Tree Dr. Chapel Hill, NC 27514 FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81006 Report Date: 27-Oct-98
Client: Pacific Environmental Services Date Received: 09-Oct-98
Client Project ID: S512.000
Parts per million in original sample
pg/g
p
ICP
39
41
36
Se
GFAA
3.8
3.2
3.7
Ag
GFAA
<0.1
< 0.1
< 0.1
Tl
GFAA
0.84
0.73
0.61
Zn
FLAA
50.0
33.2
34.5
Sample
BD-AC-1
BD-AC-2
BD-AC-3
QC SUMMARY
Spikes
% Recovery 115% 89% 62% 78% 98%
Duplicates
%RPD 4.2% 0.7%
-------
ANTIMONY
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
Sample ID
Client FAL
BD-AC-1 81006.1
BD-AC-2 81006.2
BD-AC-3 81006.3
Test
Sol'n
3.2
-3.2
0.6
Digte
Cone
3.2
-3.2
0.6
Postdig'n spike
Dil'n
FV Factor
ml
100 1
100 1
100 1
IDL =
cone.
Init.
Vol.
ml
2.0915
2.0800
2.1574
5 /^g/L
100 /jg/L
Vol. ppm
Dig'd ng/g
ml
< 0.24
< 0.24
< 0.23
SPIKE
81006.1 S
101.5
%REC 101.5%
-------
ARSENIC
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81006
Date: 26-Oct-98
IDL = 5 A/g/L
Postdig'n spike cone. 100 //g/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
FAL
81006
81006
81006
.1
.2
.3
Test
Sol'n
55.
46.
39.
9
4
4
Dig'te
Cone
279.
232.
5
0
197.0
FV
ml
100
100
100
Dil'n
Factor
5
5
5
Init.
Vol.
ml
2.0915
2.0800
2.1574
Vol.
Dig'd
ml
ppm
pg/g
13.36
11.15
9.13
SPIKE
81006.3 S
157.8
%REC 101.9%
-------
BARI UM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL = 2
Postdig'n spike cone. 1000
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81 006.3 S
81006.2 D
Test
Sol'n
M/L
578
111
596
1378
740
Digte
Cone
MA
578
772
596
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
% RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2,1574
80.0%
4.2%
ppm
pg/g
27.64
37.12
27.63
-------
BERYLLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL= 0.15
Postdig'n spike cone. 5.00 fJg/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
FAL
81006.1
81006.2
81006.3
Test
Sol'n
M9/L
7.00
7.40
7.52
Digte
Cone
A/g/L
7.00
7.40
7.52
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Init.
Vol.
ml
2.0915
2.0800
2.1574
Vol.
Dig'd
ml
ppm
/^g/g
0.33
0.36
0.35
SPIKE
81006.1 S
10.05
% REC
61.0%
-------
CADMIUM
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL =
Postdig'n spike cone.
3 //g/L
1 00
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81006.1 S
81 006.2 D
Test
Sol'n
P9/L
25
20
25
409
18
Digte
Cone
M/L
25
20
25
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
%RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
96.0%
10.5%
nTtlifl
pg/e
1.20
0.96
1.16
-------
CHROMIUM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL = 25
Postdig'n spike cone. 2000 pg/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81 006.3 S
81006.2 D
Test
Sol'n
MA
341
213
215
1729
208
Digte
Cone
M/L
341
213
215
Dil'n
FV Factor
ml
100 1
100 1
100 1
% REC
%RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
75.7%
2.4%
ppm
M/9
16.30
10.24
9.97
-------
COPPER
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81006
Date: 26-Oct-98
IDL = 20
Postdig'n spike cone, 2000
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006,1
81006.2
81006.3
81 006.3 S
81 006.2 D
Test
Sol'n
MA
221
197
203
1881
199
Digte
Cone
MA
221
197
203
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
% RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
83.0%
1 .0%
ppm
M/g
10.57
9.47
9.41
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81006.1 S
81006.2 D
Test
Sol'n
WJA
430
340
350
2380
320
Digte
Cone
pg/L
430
340
350
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
%RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
97.5%
6.1%
ppm
/yg/g
20.56
16.35
16.22
-------
MANGANESE
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81006
Date: 26-Oct-98
IDL = 3
Postdig'n spike cone. 100 //g/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81006.1 S
81006.2 D
Test
Sol'n
MJ/L
505
334
358
882
334
Digte
Cone
M/L
505
334
358
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
% RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
94.3%
0.0%
ppm
pg/g
24.15
16.06
16.59
-------
MERCURY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL = 0.20 //g/L
Postdig'n spike cone. 5.00 pg/L
Sample ID
Client
BD-AC-1
BD-AC-1
BD-AC-2
BD-AC-2
BD-AC-3
BD-AC-3
FAL
81006.1
81006.1
81006.2
81006.2
81006.3
81006.3
Test
Sol'n
M/L
0.03
0.09
0.01
0.12
0.09
-0.01
Digte
Cone
WJ/L
0.03
0.09
0.01
0.12
0.09
-0.01
FV
ml
100
100
100
100
100
100
Dil'n
Factor
1
1
1
1
1
1
Init. Vol.
Vol. Dig'd
ml ml
0.2284 <
0.3054 <
Average = <
0.3874 <
0.2626 <
Average = <
0.3017 <
0.2843 <
Average = <
ppm
M/9
0.07
0.07
0.07
0.07
0.07
0.07
0.07
0.07
0.07
-------
NICKEL
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL =
Postdig'n spike cone.
5 pg/L
1 00
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
FAL
81006,
81006
81006
.1
.2
.3
Test
Sol'n
M/L
82.
56.
58.
2
0
2
Digte
Cone
M9/L
411.
280.
291.
0
0
0
FV
ml
100
100
100
Dil'n
Factor
5
5
5
Init.
Vol.
ml
2.0915
2.0800
2.1574
Vol.
Dig'd
ml
ppm
^9/9
19.65
13.46
13.49
SPIKE
81006.1 S
166.1
% REC
83.9%
-------
PHOSPHORUS
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL= 100/lg/L
Postdig'n spike cone. 1000 pg/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81006.3 S
81006.2 D
Test
Sol'n
P9/L
815
859
779
1960
896
Digte
Cone
pg/L
815
859
779
FV
ml
100
100
100
Dil'n
Factor
1
1
1
% REC
%RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
114.5%
4.2%
ppm
pg/g
38.97
41.30
36.11
-------
SELENIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
Sample ID
Client FAL
BD-AC-1 81006.1
BD-AC-2 81006.2
BD-AC-3 81006.3
Test
Sol'n
80.3
67.3
79.9
Digte
Cone
80.3
67.3
79.9
Postdig'n
spike
Dil'n
FV Factor
ml
100
100
100
1
1
1
IDL =
cone.
Init.
Vol.
ml
2.0915
2.0800
2.1574
3 i*g/\.
50 //g/L
Vol. ppm
Dig'd /•fg/g
ml
3.84
3.24
3.70
SPIKE
81006.1 S
124.5
% REC
88.5%
-------
SILVER
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL =
Postdig'n spike cone.
2
1 0 /jg/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
FAL
81006.1
81006.2
81006.3
Test
Sol'n
pg/L
-0.44
-1.06
-0.67
Dig'te
Cone
^g/L
-0.44
-1.06
-0.67
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Init.
Vol.
ml
2.0915
2.0800
2.1574
Vol.
Dig'd
ml
ppm
M/g
< 0.10
< 0.10
< 0.09
SPIKE
81006.1 S
6.24
%REC
62.4%
-------
THALLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL = 3 /ug/L
Postdig'n spike cone. 50 jug/L
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
FAL
81006.
81006.
81006.
1
2
3
Test
Sol'n
M/L
17.
15.
13.
6
1
2
Digte
Cone
MA
17.
15.
13.
6
1
2
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Init.
Vol.
ml
2.0915
2.0800
2.1574
Vol.
Dig'd
ml
ppm
P9/9
0.84
0.73
0.61
SPIKE
81006.3 S
56.4
% REC
77,6%
-------
ZINC
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81006
Date: 26-Oct-98
IDL = 3
Postdig'n spike cone. 100 ng/\.
Sample ID
Client
BD-AC-1
BD-AC-2
BD-AC-3
SPIKE
DUPLICATE
FAL
81006.1
81006.2
81006.3
81006.1 S
81006.2 D
Test
Sol'n
M/L
209
138
149
600
137
Dig'te
Cone
pg/L
1045
690
745
FV
ml
100
100
100
Dil'n
Factor
5
5
5
% REC
%RPD
Init. Vol.
Vol. Dig'd
ml ml
2.0915
2.0800
2.1574
97.8%
0.7%
ppm
A*9/9
49.96
33.17
34.53
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
ANTIMONY
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 1 00
ICB = 0
CCV1 = 100
CCB1 = 0
0.000 0.0
0.016 10.0
0.081 50.0
0.153 100.0
0.285 200.0
97
3
97
-3
.3
.2
.6
.9
CCV2
CCB2
CCV3
CCB3
CCV4
CCB4
= 100
= 0
= 100
= 0
= 100
= 0
104.1
-0.8
111.0
-5.7
101.0
-5.9
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
ARSENIC
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., /vg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 1 00
ICB = 0
CCV1 = 100
CCB1 = 0
0.000
0.028
0.128
0.238
0.441
103.1
2.1
110.0
0.9
0.0
10.0
50.0
100.0
200.0
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
107.2
4.6
111.2
2.8
-------
Client: PES
Proj. #: 81002 and 81006
Date: 26-Oct-98
Calibration Data
BARIUM
QUALITY CONTROL DATA
Emiss. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
32
54
739
1397
2754
0
20
500
1000
2000
Calibration Verifications
ICV=1000 967
ICB = 0 0
CCV2 = 1000 1116
CCB2 = 0 0
CCV1 = 1000 1057
CCB1 = 0 1
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
Calibration Data
BERYLLIUM
QUALITY CONTROL DATA
Abs. True cone., pg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
0.000
0.012
0.043
0.105
0.175
0.0
0.5
2.0
5.0
10.0
Calibration Verifications
ICV = 5
ICB = 0
5.07
0.16
CCV2 = 5
CCB2 = 0
5.15
0.05
CCV1 = 5
CCB1 = 0
4.83
-0.01
CCV3 = 5
CCB3 = 0
5.07
0.08
CCV4 = 5
CCB4 = 0
-------
CADMIUM
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEE
Client: PES
Proj. #: 81002
Date: 26-Oct-98
Calibration Data
Abs. True cone., /jg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
CCV1 = 500
CCB1 = 0
0.000
0.017
0.032
0.064
0.151
0.295
522
3
495
1
0
50
100
200
500
1000
CCV2 = 500
CCB2 = 0
511
3
-------
Client: PES
Proj. #: 81002 and 81006
Date: 26-Oct-98
CHROMIUM
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 2000
ICB = 0
CCV1 = 2000
CCB1 = 0
Emiss. True cone.,
603 0
758 TOO
3049 1000
5860 2000
13550 5000
1829
-14
2124
-9
CCV2 = 2000 2107
CCB2 = 0 -14
-------
Client: PES
Proj. #: 81002 and 81006
Date: 26-Oct-98
CHROMIUM
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emiss. True cone.,
510 0
679 100
2957 1000
5337 2000
12453 5000
Calibration Verifications
ICV = 2000 1981
ICB = 0 -20
CCV2 = 2000 2121
CCB2 = 0 -25
CCV1 = 2000 1842
CCB1 = 0 -24
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
COPPER
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emiss. True cone., //g/L
1285 0
2949 100
18473 1000
36484 2000
89349 5000
Calibration Verifications
ICV = 2000 1998
ICB = 0 8
CCV2 = 2000 2248
CCB2 =0 11
CCV1 = 2000 2127
CCB1 =0 13
CCV3 = 2000 2106
CCB3 = 0 13
CCV4 = 2000 2017
CCB4 = 0 11
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81002
Date: 26-Oct-98
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 2000
ICB = 0
CCV1 = 2000
CCB1 = 0
0.000
0.003
0.007
0.015
0.029
0.073
1950
10
1950
-20
0
200
500
1000
2000
5000
CCV2 = 2000
CCB2 = 0
CCV3 = 2000
CCB3 = 0
1940
-30
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEE
Client: PES
Proj. #:81002
Date: 26-Oct-98
Calibration Data
Abs. True cone., /Jg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV= 100
ICB = 0
CCV1 = TOO
CCB1 = 0
0.000
0.022
0.120
0.233
0.414
101.4
1.6
101.7
-1.4
0
10
50
100
200
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
99.4
1.1
107.4
5.1
-------
Client: PES
Proj. #: 81002 and 81006
Date: 26-Oct-98
MANGANESE
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
Abs. True cone., /jg/L
0.000
0.006
0.013
0.026
0.065
0.125
0
50
100
200
500
1000
496
0
CCV2 = 500
CCB2 = 0
497
-7
CCV1 = 500
CCB1 = 0
483
1
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
MERCURY
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,/vg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 5
ICB = 0
CCV1 = 5
CCB1 = 0
0.000
0.010
0.025
0.042
0.125
0.278
4.79
-0.13
4.53
-0.18
0.00
0.50
1.00
2.00
5.00
10.00
CCV2
CCB2
CCV3
CCB3
CCV4
CCB4
= 5
= 0
= 5
= 0
= 5
= 0
4.76
-0.06
4.42
-0.09
4.95
-0.09
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
NICKEL
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV= 100
ICB = 0
CCV1 = 100
CCB1 = 0
0.000
0.030
0.082
0.173
0.340
108.0
3.1
87.4
-1.0
0.0
20.0
50.0
100.0
200.0
CCV2 o 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
89.7
-3.3
88.4
-4.2
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Od-98
PHOSPHORUS
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 2000
ICB = 0
CCV1 = 2000
CCB1 = 0
Emiss. True cone., jug/L
316 0
369 200
558 1000
518 2000
1567 5000
6099 20000
2010
21
1934
99
CCV2 = 2000 2043
CCB2 = 0 61
CCV3 = 2000 2039
CCB3 = 0 -56
CCV4 = 2000 1960
CCB4 = 0 -43
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
SELENIUM
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
fications
ICV = 50
ICB o 0
CCV1 = 50
CCB1 = 0
0.000
0.017
0.049
0.097
0.206
50.4
-4.3
51.7
2.1
0.0
10.0
25.0
50.0
100.0
CCV2 = 50
CCB2 = 0
CCV3 = 50
CCB3 = 0
53.3
-0.3
54.1
6.4
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
SELENIUM
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., pg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
ifications
;ICV = 50
ICB = 0
CCV1 =,50
CCB1 = 0
0.000
0.008
0.046
0.086
0.171
50.8
2.1
50.9
1.7
0.0
10.0
25.0
50.0
100.0
CCV2 = 50
CCB2 = 0
CCV3 = 50
CCB3 = 0
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
SILVER
QUALITY CONTROL DATA
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
fications
ICV = 20
ICB = 0
CCV1 = 20
CCB1 = 0
0.000
0.096
0.191
0.383
0.544
20.2
-1.0
19.5
-1.1
0.0
5.0
10.0
20.0
30.0
CCV2 = 20
CCB2 = 0
CCV3 = 20
CCB3 = 0
18.6
-1.1
18.6
-1.3
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
THALLIUM
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., jjg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
fications
ICV = 50
ICB = 0
CCV1 = 50
CCB1 = 0
0.000
0.017
0.030
0.079
0.149
48.9
-2.6
48.6
-0.3
0.0
10.0
20.0
50.0
100.0
CCV2
CCB2
CCV3
CCB3
CCV4
CCB4
= 50
= 0
= 50
= 0
= 50
= 0
49.7
-0.5
46.9
-0.3
54.3
-2.0
-------
Client: PES
Proj. #: 81002 and 81006
Date: 26-Oct-98
ZINC
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
Abs. True cone., /jg/L
0.000
0.035
0.056
0.091
0.205
0.367
0
50
100
200
500
1000
488
3
CCV2 = 500
CCB2 = 0
478
0
CCV1 = 500
CCB1 = 0
501
-4
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Chain of Custody Record
Cincinnati, OH 45249-1030
513.489.6611
FAX: 513.489.6619
££72- M*"1*
Samplers:
PES Field Sample ID
Dale
Project Name:
0
-
Purchase Order No,
_ ^ ^
Time
Sample Description
Number
of
Containers
Analysis Requested
Comments
1
fe
oua*.
* -
.^ ,'S
n«v
K?J / 0'V nt
Lt toe -t-h-e.
. ,
A S-S!£ D c? r, D,H 0
a
>,'// D-
: (Signatured
>. A^U^L
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Dale/Time
Received for lab by: (Signature
REMARKS
Iiasuu.^ y__ot.._Jir
-------
f'i 1100 9P/JC/15 PAbu 2'
AA AA
MAINr 0. 13C' MG/L HO O.064 MAIN: 0.136 MG/I_ HO 0..062
MEAN: 0.537 MG/L GD: 0.002 RfoD; 1.5
AA AA
MAIN: O. 1153 iviG/L HG 0,,070 MAIN: 0.146 MG/L HG O.067
Z!''J x !V!EAN!: °- 149 MG/L ED: O.O05 RSD:
A A A A
MAIN; 0.507 MG/L HO 0.210 MAIN: 0.515 MG/L HO 0.212
ZN ''^ MEAN; 0.511 MG/L SD; 0.005 RSD; 1.0
AA AA
MAIN: -0.004 MG/L HG--0.002 MAIN:- -0.003 MG/L HO--O.OO2
?•!''•! ff MEAN:;-0.. 003 MG/L BD: 0.000 RSD: 7,, 9
-------
PFF:i"Ti--l--FL.hER 'vl 1100 98/10/15 RAPE 22
AH A A
MAINE 0,. 104 MG/L HO 0.. 048 MA I Ms 0.099 MG/L HQ 0.046
ZN t"l MEAN;: 0.101 MG/L SD: 0.003 RSD^ 3.2
, AA AA
MAIN; 0,480 MG/L HO 0.200 MAIN: 0.477 MG/L HO 0.199
ZN CL^ MEAN: 0.479 MB/L SD: 0.002 RSD: 0.5
A A A A
MAIN: 0.000 MG/L HO 0.000 MAIN: -0,001 MG/L HO-0.000
ZN MEAN i-0. 000 MG/L EDs 0.001 RSD: 99.9
A A A A
MAIN: 0.357 MG/L HC! 0,154 MAIN: 0.356 MG/L HO 0.153
5>
MEANr 0..356 MG/L BDs 0.001 RSD: 0.2
AA AA
MAINc 0,774 M3/L HG 0.299 MAIN: 0,770 MG/L HO 0.297
ZN ^j/C-^ MEAN; 0.772 MG/L SD: 0.003 RSD; 0.4
AA AA
MAIN: 0.490 MB/L HO 0.204 MAIN: 0.476 MG/L HQ 0.198
MEAN;: 0.483 MG/L BD: 0.010 RSD: 2.1
AA AA
MAIN: 0.45H MG/L HO 0.19.1. MAIN: 0.454 MG/L HO 0.191
ZN xMEAlvh 0,455 MG/L SD: 0.000 RBD: 0.1
A A A A
MAIN: 0.209 MG/L HO 0.094 MAIN: 0,. 209 MG/L HO 0.094
ZN /^i^MEANr, 0.209 MG/L SD: 0.000 RSD: 0.0
AA AA
MAINE 0,593 MG/L HO 0,240 MAIN: 0.607 MG/L HO 0,244
N /S^S^MEANt 0.600 MB/L SD: 0.010 RSD: 1.7
AA AA
MAINi 0, 139 MG/L HO 0. 064 MAIN: 0.138 MG/L HOO.,063
M 2_./<> MEAN;; 0.138 MG/L. SD: 0.001 RSD: 0.6
-------
M jioo 9B/io/i5 PABF 19
AA AA
MAIM;, 0.500 MG./L HO 0,207 MAIN: 0.. 475 MB/L HO 0.198
MEAN: 0. 48B MB/L SD: 0.018 RSD: 3.6
AA AA
MAIN: 0,005 MB/L i-IG 0,002 MAIN: O.OO1 MG/L HO O.001
ZN xj^ {2, MEAN: 0.003 MB/L SD; 0.002 RED: B6..6
AA AA
MAIN: 0.380 MG/L. HO 0.163 MAIM: 0.400 MG/L HO 0,. 170
/ MEAN: 0.390 MG/L BD: 0.014 RSD: 3,. 6
A A A A
MAIN; 0,272 MB/L HO 0.120 MAIN: 0.263 MB/L HO O.J.16
ZN r~-\ MEAMs 0.267 MB/L GD: 0.006 RSD: 2.4
AA AA
MAIN: 0,654 MB/L HO 0,260 MAIN: 0.679 ME/L HO 0.268
ZN 9-l5»MEANs 0.666 MG/L GD: 0.018 RSD: 2.7
AA AA
MAIN: 0.358 MB/L HO 0.154 MAIN: 0.3E34 MG/L HO 0.164
— I MEAN: 0.3
ZN — MEAN: 0.371 MB/L BD: 0.01B RBD: 4.9
A A A A
MAIN; 0.360 MB/L. HO 0,. 155 MAIN: 0.353 MG/L HO 0.152
ZN 7-U> MEAN: 0.356 MB/L ED: 0.006 RSD: 1 .. 6
A A A A
MAIN; 0..-126 MB/L HO 0.1SO MAIN: 0.439 MB/L HO 0.115
ZN /0-\ MEAN; 0,433 MG/L BD: 0.009 RBD; 2."
A A A A
MAIN: 0.013 MB/L HO O.C06 MAIN: 0.014 MB/L HO 0,007
~ "~~ Jttt
IN a3&* MEAN: 0,. 0:13 MB/L SD: O.OOO RSD: 2.3 AUTDZERO 0.000
A A A A
MAIN: 0.115 MB/L HO 0.053 MAIN: 0.. 114 MG/L HO 0.053
7"\ ¥>-i~* MflftN: 0.115 MB/L ED: 0.00.1 RSD: 0.6
-------
Tl TD: 81O06.i
^eoi icate 1
Concentration (uq/L )
"eolie-sts- 2
"on cent rat ion i'ua/L )
v'ean Cone (ua/L ) :
recovery is 77.67.
ea. No,
56.27
56.46
56.37
00099 A/'S Pas
Time: 08:40
Time: OS: 43
SD: 0.139
28 Date: 10/20
RSD C/.): 0.25
'1 T D : 8 L 0 <"> r>. 2
*=D1ieate 1
Concentration i'ua/L
Ion cent ration >. ua/L
"lean Cone iua/L )
Sea. Mo,
): 13.37
): 16.79
1 5. OB
00100 A/S Pos
Time: O8:46
Time: O8:50
SD: 2.419
29 Date: 10/20,
RSD ('/.): 16.0'
^ TP; 81006.3
^eoli cate 1
.oncentration (uo/L
; ^= 17.!. 1 c => t e 2
li^ncent r ation \ua/L
lean Cone iua /L )
Sea. No.
): 15.00
i: 11.38
13.18
00101 A/S Pos,
Time: OS:53
Time: 08:56
SD: 2.561
30 Date: 10/20/
RSDC/. ): 19.42
<"• ID: CCV
'eol i cate I
Concentration (uo/L
Sea. Mo,
): 54.96
T.oncent ration >. ua/L )s 53.69
lean Cone (uo/L ) : 54.32
3C sample is within ranae
00102 A/S Pos,
Time: 08:59
T ime: 09? 02
SD: O.899
Date: 10/20/
RSDC/.): 1.65
r i T r..; r r R
••'eo 1 i ea te i
Toncentration (ua./L
on e en t r a 11 en i ua / L
lean Cone ( no ^L )
Sea. Mo.
): -3.09
): -0.94
-2.02
00103 A/S Pos,
Time: 09:06
Time: 09:09
SD: 1.525
0 Date: 10/20/
RSDC/.): 75.7C
-------
A A
93/50/15 PAGE IB
A A
MAIN: 0.003 MG/L HO 0,001 MAIN; 0.002 MG/L HO O.001
?N MEAN:. 0.002 MG/L ED: 0.001 RSD: 21.8 AUTOZERO 0.000
A A
A A
MAIN:: 0.09C MG/L HG 0., 039 MAIN: O.OS2 MG/L HO 0.032
ZN MEAN; 0,090 MG/L ED; 0.0:12 RSD: 12. S 1.STANDARD 0.090 MG/L.
A A
AA
MAIN;. 0.145 MG/L HO 0.057 MAIN: 0.137 MG/L HO O. 054
ZN MEAN;: 0.141 MG/L GD: 0.006 RSD: 4.1 2. STANDARD 0.140 MG/L
A A
AA
MAIN; 0.. 220 MG/L HO 0,083 MAIN: 0.235 MG/L HO O. 093
ZN MEAN;: 0.. 22S MS/L. GDv 0.05.0 RBD: 4.6 3. STANDARD 0.227 MG-'L
A A A A
MAIN; 0,5:16 MG/L HO 0., 206 MAIN: 0.512 MG/L HO 0.204
ZN MEAN;. 0.514 MG/L SDi 0.003 RSD: 0.6 4. STANDARD 0.513 MP/L
AA
AA
MAIN;. 0.919 MG/L HO 0.368 MAIN: 0.910 MG/L HO 0.365
ZN MEANc 0.915 MG/L GD: 0.006 RGD: 0.7 5.STANDARD 0.959 MG/L
FLriME DISPLAY CALIBRATION MODE
ELEMENT: ZN
REPL, 3 OF 2
0.368
nBS.
PRINTER: ON
B6 CORR: OFF
UNITS : MG/L
0,959
READ
nBS. READING
S5 ftft : 0.365
STATISTICS
MEAN: 0.915
SD: B.086
RSD (JO: 0.7
CONCENTRATION (MG/L >
1.005
C3H2; 2.5 L/MIN OXIDflNT: 3.0 L/MIN FLAME: C2H2-AIR
A A
0. '"'•"'] NG •'[. HO 0 . 001
AA
M A Tilt - 0. 0 0 1. M G /1.. HO - 0 . 0 0 0
-------
'i Tr; rrp
Sea. Mo,
Concentration iua''L ): -0.00
Concentration '.uq/L ): -C1. 49
•lean Cone iua/L ): -O.25
3C sample is within ranae
00094 A/S Pos
Time: 08:07
T Lme: 08:10
SD: 0.344
Date: 1Q/20/
RSDC/.): 139.1
M ID: 81003.11
Concentration iuq/L ): 35.62
"* = ».i' 1 '-. ~ r11 e ~
loncen tr at ion iua/'L j: 37.38
•'lean Cone 'ua/L ) :
Sea. No,
36.50
00095 A/S Pos.
Time: 08:14
Time: 08:17
SD: 1.249
25 Date: 10/20/
RSDC/:): 3.42
r1 TP; B1003.T2 Sea. Mo,
•
-------
Concentration (uo/L ): 3.90
lean Cone fuq/L ): 3.54
;orrected Cone (uq/L ): 17.7
Corrected-Cone (uq/L ): 19-5
SD: 0.513 RSD(X): 14.51
TD: 81006.3x5
icate 1
Concentration (ua/L ): 5.05
*eo 1 i cats 2
Ioncentration (ua/L
4.46
Sea. No.: 0009O A/S Pos.: 3O Date: 10/19/9E
Time: 21:17
Corrected Cone (uq/L ): 25.2
Time: 21:20
Corrected Cone (ua/L ): 22.3
"lean Cone (ua/L ): 4.75
2orrected Cone (ua/L ): 23.8
SD: O.412
RSD (7.): 8.66
T D : C C V
9ea. No,
9eol icate 1
Zoncentrat ion (uq/L
): 49.51
Toncentration (uq/L ): 49.92
lean Cone (ua/L ): 49.71
3C sample is within ranae
00091 A/S Pos,
Time: 21:23
Time: 21:27
SD: 0.287
Date: 10/19/9£
RSD (7.) i 0.58
ri
TD: CCB
i cate 1
Concentration (ua/L
Sea. Mo,
): -2.06
Toncentration (uq/L ): 0.99
lean Cone (ua/L ): -0.54
3C sample is within ranae
00092 A/S Pos,
Time: 21:30
Time: 21:33
SD: 2.163
Date: 10/19/9C
RSD (7.): 404.62
r"' TD: CCV Sea. No.
^eolicate 1
Toncentration (ua/L ): 48.50
loncentration (ua/L ): 45.22
ean Cone (ua/L )
46.85
00093 A/S Pos
Time: OB:01
Time: 08:04
SD: 2.318
Date: 10/20/9E
RSD (7.): 4.95
3C samole is within ranae
-------
"! TD: CCV Sea. Mo,
eo1i cate 1
oncentration (uo/L ): 44.91
1 ? D 1 i ™ ? t ~ 2
'oncentration (ua/L ): 46.38
lean Cone iuq/L ): 45.64
1C sample is within ranae
00085 A/S Pos
Time: 20:45
Time: 20:48
SD: 1.038
Date: 10/19/
RED (7.): 2.27
'1 ID: CCB Sea. No,
lealicate 1
Concentration (ua/L ): 1.10
delicate 2
Concentration (ua/L ): -0.06
lean Cone (ug/L ): 0.52
5C sample is within ranae
00086 A/S Pos.: 0
Time: 20:51
Time: 20:55
SD: 0.821
Date: 10/19/
RSDC/.): 156.;
"1 ID: 81006.1x5
?eolicate 1
.Concentration (ug/L ): 0.53
' ^? D ] i c 3. te 2
:oncentration (ua/L ): 3.14
lean Cone (ug/L ): 1.83
lorrected Cone (ua/L ); 9.2
Sea. No.: 00087 A/S Pos.: 28 Date: 10/19/
Time: 20:58
Corrected Cone (ua/L ): 2.6
Time: 21:O1
Corrected Cone (ua/L ): 15.7
SDs 1.848
RSD (V.): 100.7
!"! ID: 81006.1x5
?eolicate 1
Toncentration (ua/L )
51-97
:c
-------
;*iDisplay Calibration - CiXAfl USIR
_.-*"
Sflr
«tf.: 0.
!: C.301 C
Concentration
'1 ID: ICV Sea. No.
-------
Blank Corrected Pk Area (A-s): 0.023
Concentration (ua/L ): 16.61
•lean Cone (ua/L )J
17.47
Standard number 2 applied. [20.00]
Correlation coefficient: 1.00000
SD: 1.226
Slooe: O.0020
RSD(X): 7.02
ID: 50 PPE TL
Sea. No.
'eolicate 1
3eak Area (A-s): O.OBO
Background Pk Area (A-s): 0.093
Blank Corrected Pk Area (A-s): 0.078
Concentration (Lia/L ): 115.22
J = ak Area (A-s>: 0.082
Background Pk Area (A-s): 0.093
Blank Corrected Pk Area (A-s): 0.08O
Concentration (ua/L ): 123.13
lean Cone (ua/L ):
119.09
00064
A/S Pos.: 3
Date: 10/19/
Time: 18:30
Peak Heiaht (A): 0.080
Backaround Pk Heiaht (A): 0.056
Time: 18:34
Peak Heiaht (A): 0.081
Backaround Pk Heiaht (A): 0.061
SD: 5.597
RSDC/.) : 4.70
3-shaoed calibration curve detected. 2-coef. equation used.
Standard number 3 applied. [50.00]
Correlation coefficient: 0.99809 Slooe: O.0017
ID: IOC PPB TL
Sea. No.: 00065
reoli
-e-ak Area (A-s): 0.153
Backaround Pk Area (A-s): 0.146
Blank Corrected Pk Area (A-s): 0,151
Concentration (ua/L ): 103.58
A/S Pos.: 4
Date: 10/19/
Time: 18:37
Peak Height (A): 0.147
Background Pk Heiaht (A):
0.114
-eak Area >A-s): O.148
Background Pk Area (A-s): 0.147
Blank Corrected Pk Area (A-s): 0.146
Concentration (ua/L ): 99.58
Time: 19:40
Peak Height (A): 0.131
Backaround Pk Heiaht (A): 0.104
lean Cone (ua/L
101.57
3-shaoed calibration curve detected.
Standard number 4 applied* [100.00]
Torrelation coefficient: 0.99970
SD: 2.829
2-coef. eauation used
Slope: 0.0016
RSDC/.): 2.79
-------
Element File: TL.GEL Element: Tl Wavelength: 276.B
Date: 10/19/9S Time: 18:11 Slit: 2.00 H
Data File: ID/Wt File: B1O02.IDW Lamp Current: 7
rechniaue: HGA Calib. Type: Nonlinear Energy: 45
ri ID: BLANK Sea. No.: 00061 A/S Pos.: 0 Date: 10/19/9E
Replicate 1 Time: 18:11
=eak Area (A-s): 0.003 Peak Height (A): 0.015
3ackarbund Pk Area (A-s): 0.013 Background Pk Height (A): 0.012
Blank Corrected Pk Area (A-s): 0.003
~srli-iat=2 Time: 18:14
=sak Area (A-s): -0.000 Peak Height (A): 0.016
3ackaround Pk Area (A-s): O.022 Backoround Pk Height (A): 0.015
Blank Corrected Pk Area (A-s): -O.OOO
lean Pk Area (A-s): 0.002 SD: 0.0022 RSD ('/.): 142.94
performed.
ID: 10 PPB TL
Sea. Mo.: 00062
A/S Pos.: 1
Date: 10/19/9E
Deak Area (A-s): 0.016
Backaround Pk Area (A-s): 0.039
Blank Corrected Pk Area (A-s): 0.015
Time: 18:17
Peak Heiaht (A): 0.026
Backaround Pk Heiaht (A): 0.021
Characteristic Mass = 29.B oa/0.0044 A-s
Peak Area (A-s): 0.021
Backaround Pk Area (A-s): 0.037
Blank Corrected Pk Area (A-s): 0.019
Mean Pk Area (A-s
0.017
Time: 18:21
Peak Height (A): 0.027
Backaround Pk Heiaht (A): 0.023
SD: O.0033
RSD (7.): 19.47
Standard number 1 aoolied. [.10.00]
Correlation coefficient: l.OOOOO
Slooe: 0.0017
•aractsristic Mass = 22.6 Da/0.0044 A-s
ID: 20 PPB TL
Sea. Mo,
Replicate 1
Peal- Area (A-s): 0.033
Backoround Pk Area (A-s): 0.055
Blank Corrected Pk Area (A-s): 0.031
Concentration (ug/L ): 18.34
0006:
A/S Pos.: 2
Date: 10/19/9E
Time: 18:24
Peak Heiaht (A): 0.034
Backaround Pk Height (A): O.O31
pea> Area (A-s): 0.030
BackaroLind Pk Area (A-s): 0.059
Time: 18:27
Peak Heiaht (A): 0.040
Backaround Pk Heiaht (A): O.O32
-------
An TO: S10O6.3 Sea. No..
Reeli cate 1
Concentration (uq/L ): -0.72
•~ *? c11 i r = t. = ^2
Con rent rat ion i ua/L ') ', -0.62
Mean Cone i'ua/L )s -0.67
00234 A/S Pos
Times 20:17
Time: 20:20
SD: 0.068
30 Date: 10/15/c
RSD(7.): 10.16
An TO: CCV
Reo 1 i cate i
Concentration i ua/L ): 18.13
Sen. No.: O0235 A/S Pos.
Time: 20:23
Time: 20;26
Concentration i'ua/L ): 19.10
(lean Cone (ua/L
18.62
SDi 0.691
QC samole is within ranae 15.5 - 24.49
Date: 10/15/c
RSD(7.) : 3.71
An
IPs CCB
R'eolicate 1
Concentration Cug/'L ): -1=28
' => n 1 .i c 5 t =• 2
Concentration (ua/L ): -1.31
Sea. No.: O0236 A/S Pos.
Time: 20:29
Time: 20;32
Cone ('ua/L )
-1 .30
SD: 0,024
Date: 10/15/
RSD ('/.): 1.86
QC sample is within ranae -5.49 - 5.49
-------
Qn TD : 9 L0i''3 . 1 2
Peo1i ca te 1
Concentration ( ua/'L ): 6.09
~ = o 1 i c 5 t e 2
Concentration i'ua/L ): 5.76
Sea. No,
00229 A/S Pos.: 26 Date: 10/15/9E
Time: 19:44
Time: 19:47
Mean Cone (uo/L ):
5.9;
SD: 0.23B
RSD(7.): 4.01
•^r, T D : 8 l<~>03 . T7
Peoli cate 1
Concentration (ua/L ): 4.31
R = n ] i - a ^ s ?
Concentration (ua/L ): 3.77
Sea. No
Mean Cone (ua/L ):
4.04
00230 A/S Pos.: 27
Time: 19:51
Time: 19:54
SD: 0.379
Date: 10/15/96
RSD C/.): 9.38
An TO: 81OO6.1 Sea. No,
Reoli cate 1
Concentration ('ug/L ): -0.42
Concentration i'ua/L ): -0.46
Mean Cone t'ua/L ): -O.44
OO231 A/S Pos.: 28 Date: 1O/15/9E
Time: 19:57
Time: 20:00
SD: 0.030
RSD ('/.): 6.76
An TD: 81006.
Sea. Mo,
i ca te 1
Concentration (ua/L
"^ = n 1 i ~ B T E I'
Concentration i'ua/'L
Mean Cone (ua/L ):
Recoverv is 66.8V.
): 6.19
j: 6.29
6.24
00232 A/S Pos.: 28 Date: 1O/15/96
Time: 20:O4
Time: 20:07
SD: 0.071
RSD (7.): 1.14
3n TT>: 9K>O6.2
Reo 1 i cate 1
Cone en t r a t i on \ LI a /L
Sea. No,
) : -1 . 06
00233 A/S Pos.: 29 Date: 1O/15/9E
Time: 20:10
T ime: 20:13
Concentration i'ua/L ): -1.06
Cone i LIQ /L ) : -i .06
SD: 0.001
RSD (7.): O.O6
-------
~v ^v *V *V *V -v fv "V "V *V 'V "V*V- *
An TT;: CCV
Pen] icate 1
Concentration (ua/L ): 19.12
Sea. Mo.: 00224 A/S Pos.
Time: 19:12
Time: 19:15
Concentration iua/L ): 18.08
Mean Cone (uo/L )
18.60
SD: 0.738
QC samole is within range 15.5 - 24.49
Date: 10/15
RSD(%): 3.97
ID:
Real icate 1
Concentration (ua/L ): -1.13
R = r, 1 i c a t •? I.'
Concentration Cua/L ): -1.06
Sea. Mo.: 00225 A/S Pos.
Times 19:18
Time: 19:21
Mean Cone
-------
IN Display Calibration • C;\HH USERXHH £116
iO-S-4-4-. JH,—
i
1
i
1
i r -
i
i
i
i
..-^'
,->*;* •" •*
^^'
JZ'Z'
_.-C3.< 1 i-inaac
•*•• ii?l&p&" 5 Ij^v2
IritsriiB-t: P.PCf
o tenc4mra«i»r. *fl.aa
i
*
%
^a ID: ICV
Concentration (uq/L ): 20.25
'eo 1 i ca te 2
Concentration iua/L ): 20.13
lean Cone (ua/L i
Sea. No.: 00200 A/S Pos.
Time: 16:35
Time: 16:3"
20. 19
SD: 0.OB3
3C samole is within ranae 15.5 - 24.49
Date: 10/15/9E
RSD C/.): 0.41
in T D : T CB
-------
ean Con c i ua/L )
9.96
SD: 0.244
RSD (7.): 2.45
tandard number 2 applied. [10.00]
correlation coefficient: 1.00000
Slope: 0.0190
Int: 0.000
Date: 10/15,
ID: 20 PPB AG
5ea. No,
eolicate 1
eak Area iA-s 1 : 0.482
ackaround Pk Area (A-s): 0.152
lank Corrected Pk Area (A-s): 0.387
oncentration (uq/L ): 20=33
*?• D ^ i c B t e Z'
eak Area (A-s): O.471
;ackoround Pk Area (A-s): 0.159
;lank Corrected Pk Area (A-s): 0.376
oncentration (ua/L ): 19.76
lean Cone C ua /L ) :
20.04
00198
A/S Pos.: 3
Time: 16:21
Peak Heiqht (A): 0.724
Backaround Pk Height (A): 0.068
Time: 16:24
Peak Heiqht (A): 0.721
Backaround Pk Heiaht (A): 0.067
SD: 0.402
RSD C/.): 2.01
'tandard number 3 aoolied. [20.0O1
orrelation coefficient: 1.OOOOO
Slope: 0.0191
Int: -0.000
TD: 30 PPB AG
Sea. No,
00199
A/S Pos.: 4
Date: 10/15/
i cate 1
'eak Area (A-s): 0.641
iackaround Pk Area (A-s): 0.168
Hank Corrected Pk Area (A-s): 0.546
:oncentration (uq/L ): 28.65
'eak Area (A-s J : O . 636
iackaround Pk Area (A-s): 0.162
Hank Corrected Pk Area (A-s): 0.541
loncentration (ua/L ): 28.39
lean Cone (ua/L ):
28.52
Standard number 4 applied. F30.00]
lorrelation coefficient: 0.99938
Time: 16:28
Peak Heiqht (A): 0.955
Backaround Pk Heiaht (A): 0.085
Time: 16:31
Peak Heiaht (A): 0.947
Backaround Pk Heiaht (A): 0.086
SD: 0.184
Slope: 0.0182
RSD(7.) : 0.64
Int: 0.005
-------
lement File: AG.GEL
ate: 10/15/98
ata File:
ecnnioue: HGA
Element: Aa
Time: 16:02
ID/Wt File: 81002.IDW
Caiib. Type: Linear
Wavelength: 32B.1
Slit: 0~7 L
Lamp Current: 10
Enerqy: 55
ID: BLANK
Sea. Mo
eolicate 1
eak Area (A-s): 0.1O2
ackaround Pk Area (A-s): 0.150
lank Corrected Pk Area (A-s): 0.007
concentration (ua/L ): 0.10
00195
A/S Pos.: 0
Date: 10/15/98
Time: 16:02
Peak. Height (A): 0.15S
Background Pk Height (A): 0.062
= D 1 i - =• t e 2
eak Area (A-s): 0.OSB
ackaround Pk Area (A-s
lank Corrected Pk Area
oncentration (ua/L ):
ean Cone (ua/L ):
uto-zero performed.
: 0.133
(A-s): -0.007
-0.71
-0.30
Time: 16:05
Peak Heiaht (A): 0.139
Backaround Pk Heiaht (A): 0.061
BD: 0.568
RSDC/.) : 186.82
ID:
PPB AG
Sea. No
00196
A/S Pos.: 1
Date: 10/15/93
eoli cats 1
eak Area (A-s): 0.194
ackaround Pk Area (A-s): 0.136
lank Corrected Pk Area (A-s): 0.099
oncentration (ua/L ): 5.37
Time: 16:08
Peak Heiaht (A): 0.290
Backaround Pk Heiaht (A): 0.06O
eak Area (A-si: 0.187
ackaround Pk Area (A-s): 0.129
lank Corrected Pk Area (A-s): 0.092
oncentration (ua/L ): 5.01
ean Cone (ua/L
5. 19
Time: 16:12
Peak Height (A): 0.283
Backaround Pk Heiaht (A): 0.057
SD: 0.254
RSDC/.): 4.90
tandard number 1 applied. [5.00]
orrelation coefficient: 1.OOOOO
Slope: 0.0191
Int: O.OOO
ID: 10 PPB AG
Seg. No
enlicate 1
eak Area < A-s) : 0.282
.ackaround Pk Area (A-s): 0.143
'lank Corrected Pk Area (A-s): 0.187
•oncen tra tion tuo/L ): 9.79
•? o 1 i - a t e 2
'eat- Area >' A—= > : 0.288
'ackaround Pk Area (A-s): 0.148
Hank Corrected Pk Area (A-s): 0.194
'oncentration ino/L ): 10.13
00197
A/S Pos.: 2
Date: 10/15/98
Time: 16:15
Peak. Height (A): 0.42B
Backaround Pk. Heiaht (A): 0.062
Time: 16:18
Peak Height (A): 0.435
Background Pk Height (A): 0.065
-------
3C sample is within ranae
•;= TO: CHE Sea. No.: 00280 A/S Pos. : O Date: 10/1£
^eolicate i Time: 17:39
Concentration (uq/L ): 4=44
-c.nli.rz.t? ~2 Time: 17:42
Concentration Cua/L ): -1.54
Cone (uo/L ): 1.45 SD: 4.227 RSD(7.): 291.
samole is within ranae
-------
TD: 810O6.1
i icate 1
Concentration (ua/L
Sea. Mo
i c a t. = 2
Concentration \'uq/L
'lean Cone (ua/L ) :
) : 79.56
): 80.96
80.26
OO275 A/S Pos
Time: 17:05
Time: 17:08
SD: 0.98B
28 Date: 10/16/9t
RSD C/.): 1.23
TD: 8.1006.1
Sea. No.: 00276 A/S Pos.: 28 Date: 10/16/9E
Sample abs. is areater than that oi the larctest standard.
3eDlicate 1 Time: 17:12
Concentration (uq/L ): 122.48
e abs. is areater than that of the largest standard.
^eolicate 2 Time: 17:15
Zoncentration (Lia/L ): 126.54
3amole abs. is oreater than that of the largest standard.
Mean Cone (uq/L ): 124.51 SD : 2.871
Recovery is 88 . 5'/.
RSD C/.): 2.31
~e ID: R1006.2 Seo. No
Reolicate 1
Concentration (ua/'L ): 68.55
Rf=ol i.cate "2
Concentration t'ua/L ): 65.96
Mean Cone (ua/L ): 67.25
00277 A/S Pos,
Time: 17:19
Time: 17:22
SD: 1.828
29 Date: 10/16/9C
RSD(X): 2.72
^O6.3
Reolicate 1
Concentration I'ua/L
cen tr s t ion (ua/L
Mean Cone (ua/L )
Sea. No.: 00278 A/S Pos,
Time: 17:25
30 Date: 1O/16/9&
81.60
78.09
79.85
Time: 17:29
SD: 2.487
RSD ( 7.) i 3.11
^e TD: HCV
Renlicate 1
Concentration (uo/L
(3 o i-, 1 i .- r, f 5 ~
Concentration (ua/L
Mean Cone i'uo/L ):
Seo. No
): 54.22
): 50.46
52.34
00279 A/S Pos
Time: 17:32
Time: 17:35
SD: 2.664
Date: 10/16/9E
RSD (7.): 5.09
-------
afnole abs. is Greater.than that oi the laraest standard.
ean Cone (ua/L ): 125.74 SD: 5.114
RSD ('/.): 4.07
•3 ID: SJ003. 12
amole abs. is areater
eblicate 1
oncentration (uq/L );
i^mnle ebs. is \areater
eolicate 2'
oncentration (ua/L );
amole abs. is areater
ean Cone iua/L ):
, Sea. No.: OO271 A/S Pos.: 26 ' Date: 10/16/
than that of the largest standard.
Time: 16:38
195.59
than that of the largest standard.
Time: 16:42
193.25
than that of the largest standard.
194.42 SD: 1.65O
RSD(7.): 0.85
Date: 10/16
e ID: 81003.13
iamole abs. is areater
:eol i cate 1
oncentration (ua/L ):
e abs. is areater
.eol i cate 2
loncentration (ua/L ):
iamole abs. is areater
lean Cone (ua/L ):
Sea. No.: 00272 A/S Pos.: 27
than that of the largest standard.
Time: 16:45
175.49
than that of the largest standard.
Time: 16:48
182.48
than that of the largest standard.
178.99 SD: 4.945
RSD C/.): 2.76
:e TD: CCV
!eolicate 1
loncentration (uq/L
Sea. No
): 54.81
loncentration (ua/L ;: 53.45
lean Cone (ua/L ): 54.13
1C samole is within ranae
00273 A/S Pos
Time: 16:52
Time: 16:55
SD: 0.965
: 3
Date: 10/16
RSD C/.): 1.78
:= TD: CCE
Jeol i cate 1
Concentration (ua/L
Sea. No
): 7,29
Concentration (ua/L ): 5.46
lean Cone (ua/L ); 6.37
5C sample i= within ranae
00274 A/S Pos
Time: 16:59
Time: 17:02
SD: 1.293'
Date: 10/16
RSD (7.): 20.J
-------
* iOisplay CaliSraEion - tiviSO
3.S t-
I L 1
d.D
.11] 3 *
Lln«sr
Concentration
Se ID: ICV
Reolicate 1
Concentration (ua/L
Seo. No
): 49.40
Concentration (ua/'L ): 51.48
Mean Cone I'ug/L 1: 50.44
QC sample is within ranoe
00242 A/5 PCS
Time: 13:23
Time: 13:26
SD: 1.466
GS 1 0 : ICB
Bpnlicate 1
Concentration (uo/L
Sea. Mo,
): -5.35
Concentration (ua/L ): -3.31
Mean Cone i'uQ/L ): -4.33
QC samole is within ranae
oerformed.
00243 A/S Pos.: 0
i
Time: 13:29
Time: 13:33
SD: 1.438
Date: 10/16/9;
RSDC/.): 2.91
Date: 10/16/95
RSD (*/.): 33.22
TO: 81OO2.B-1
Sea. No.: O0244 A/S Pos.: 6
Concentration (LIQ/L ): -1.13
Conraen tr at ion tua/L ): 1.78
Mean Cone i ua/L i : 0.32
Time: 13:37
T ime: 13:41
SD: 2.058
Date-. 10/16/9E
RSDf/.): 633.88
TO: 8K>07.8-1
Sea. No.: 00245 A/S Pos.: 7 Date: 1O/16/96
-------
Mean Cone (ua/L )
8.36
5D: 0.950
RSDC/.): 3.3S
Standard number 2 aoolied. [25.00]
Correlation coefficient: 0.99443
Slope: O.OO19
TD:
PPB
Sea. No,
Reol icate 1
Peak Area (A-s): 0.106
Backaround Pk Area (A-s): 0.174
Blank Corrected Pk Area (A-s): 0.097
Concentration (ua/L ): 50.42
Peak Area (A-s): 0.105
Backaround Pk Area (A-s): 0.17B
Blank. Corrected Pk Area (A-s): 0.096
Concentration (ua/L ): 49.81
Mean Cone (ua/L ):
50.1!
Standard number 3 aoolied. [50.OO"]
Correlation coefficient: O.99923
00240
A/S Pos.: 3
Date: 10/16
Time: 13:02
Peak Height (A): 0.169
Backaround Pk Heiaht (A): 0.091
Time: 13:05
Peak Height (A): 0.152
Backaround Pk Heiaht (A): 0.1O1
SD: 0.432
Slooe: 0.0019
RSD(7.): O.B6
se
ID: 1OO PPB
Sea. No
Reelicate 1
Peak Area (A-s): 0.212
Backaround Pk Area (A-s): 0.193
Blank Corrected Pk Area (A-s): O.2O4
Concentration (ua/L ): 105.48
P a — 1 i r =, r a ~]
Peak Area (A-s): 0.216
Backaround Pk Area (A-s): 0.191
Blank Corrected Pk Area (A-s): 0.208
Concentration (ua/L )s 107.39
Mean Cone (ua/L ):
106.43
Standard number 4 aoolied. T100.001
Correlation coefficient: 0.99888
00241
A/S Pos.: 4
Date: 10/16
Time: 13:09
Peak. Heiaht (A): 0.297
Backaround Pk Height (A): 0.109
Time: 13:12
Peak Height (A): 0.341
Backaround Pk Height (A): 0.119
SD: 1,354
Slope: 0.0020
RSD ('/.): 1.27
-------
Element File: SE.GEL
Date: 10''16/96
Data File:
Techniaue: HGA
Element: Se
Time: 12:42
ID/Wt File:
81002. I DW
Calib. Type: Linear
Wavelength: 196.0
Slit: 2.00 L
Lamp Current: 0
Energy: 38
ID: 0 PPB
Sea. No.: 00237
A/S Pos,
Date: 10/16/9(
^eolicate 1
=eak Area (A-s): 0.006
Background Pk Area (A-s)
Blank. Corrected Pk Area
Concentration (ua/L ):
: 0.183
(A-s): 0.010
5.34
Time: 12:42
Peak Height (A): 0.037
Backaround Pk Height (A):
0.084
= <=ak Area (A-s'i: O.011
Sackaround Pk Area (A-s): 0.192
Blank Corrected Pk. Area (A-s): O.O15
Concentration (ua/L ): 8.28
Time: 12:45
Peak Heiaht (A): 0.028
Backaround Pk Heiaht (A)
0.082
"lean Cone (ua/L ):
3uto-zero performed.
6.81
SD: 2.081
RSD C/.): 30 . 56
ID: 1C
Sea. Mo
00238
A/S Pos.
Date: 1O/16/9E
Dedicate 1
=>eak Area (A-s) : 0.024
Backaround Pk. Area (A-s): O.184
Blank Corrected Pk Area (A-s): 0.015
Concentration (ua/L ): 8.27
Time: 12:49
Peak Heiaht (A): 0.046
Backaround Pk Heiaht (A)
0.072
°eak Area (A-s): 0.028
Backaround Pk Area (A-s): O.181
Blank Corrected Pk Area (A-s): 0.019
Concentration (ua/L ): 10.35
"lean Cone (ua/L
9.31
Time: 12:52
Peak Height (A): O.O5O
Backaround Pk Heiaht (A)
0.072
SD: 1.469
RSD (7.) : 15.77
Standard number 1 applied. [10.OO]
Correlation coefficient: 1.00000
Slooe: 0.0017
25 PPB
Sea. No
Dedicate 1
Peak Area (A-s): 0.059
Back around Pk Area (A-s): 0.183
Blank Corrected Pk Area (A-s): 0.05O
Concentration (ua/L ): 29.03
00239
A/S Pos.: 2
Date: 10/16/9E
Time: 12:55
Peak Height (A): 0.087
Backaround Pk Heiaht (A): 0.087
•=pak Area iA-s i : O.O56
Backaround Pk Area (A-s): 0.173
Blank Corrected Pk Area (A-s): 0.048
Concentration (ua/L ): 27.69
Time: 12:59
Peak Heiaht (A): 0.099
Backaround Pk Height (A)
0.080
-------
P2 1 4
P2 1 4
P2 1 4
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
: 4*4"3
EM
: 4*4-3
EM^
: 4*Xs
EM
P214
P214
.
^^^^^^•^^^^^
EM
: 4*44
EM
: 4*^4
EM
P214
P214
AV 914.3 EM
AV 2.3946 mg/L
REF>I_
821 2.0217
REF>L_
791 1.9018
REF=-L_
805 1 . 9578
AV 805.7 EM
AV 1.9604 mg/L
REF>L_
301 -0.0558
REF>1_
293 -0 . 0878
REF3"!—
319 0.0161
AV 3O4.3 EM
AV -O.O425 mg/L
SD
SD 0.
IC<=k-TE
mg/L
ICrf=kTE
mg/L
IC^TE
mg/L
SD
SD 0.
IC^-TE
mg/L
IT f~*~ v^ | •
.•• " ~ W^^ 9 ™
mg/L
ICftTE
mg/L
SD
SD O.
(L^"^? REF»l_ I CftTE
2'BB -0.1078
REF>L_
302 -0.0518
REF>I_
297 -0.0718
AV 295.7 EM
AV -0.0771 mg/L
.x*""""*^^.
313 -0.0079
REP"!—
312 -0.0119
REF>L_
319 0.0161
AV 314.7 EM
AV -O.0012 mg/L
mg/L
ICl=kTE
mg/L
ICftTE
mg/L
SD
SD 0.
"5Tc*vtre
mg/L
Irf"™*3 ^TV • •---"
•- --- V 1 • ^^-
mg/L
ITT M"1^ ^N. — r f '
-•• * - r i • *^_
mg/L
SD
SD O.
3.5 CV 0.4
0140 CV 0.59
4* 1 1457 10/22/98
4*2
4*3
15. O CV 1.9
O600 CV 3.O6
4*± 1459 10/22/98
window-edge
4*2
peak -noisy
4*3
peak-noisy
13.3 CV 4.4
O532 CV 125.14
4*± 15O1 10/22/98
wi n do w -edge
4*2
4*3
peak-noisy
7.1 CV 2.4
0283 CV 36.74
-^_^~^^
-"4* ± 15O3 10/22/98
peak -noisy
4*2
4*3
peak -noisy
3.8 CV 1.2
0151 CV 1227.44
EM
EM
P214
EM
314
309
308
-0.0039 mg/L
-0.0239 mg/L
-0.0279 mg/L
4*± 15O5 10/22/98
peak -noisy
4*2
peak-noisy
4*3
peak -noisy
-------
OO&
P214
00&
P214
00&
P2 1 4
P214
P214
. 1
EM
_ 1
EM
P214
P214
AV 301.0 EM
AV -O.O558 mg/L
RSEIF^L
521 0.8231
REIF"!-
518 0.8111
RE:I=L
518 0.8111
AV 519. O EM
AV 0.8151 mg/L
SD
SD
7.8 CV
0.0312 CV
.IC^TE: 4*1
mg/L
2.6
55.89
1447
_IC<=kTE: 4*2
mg/L
-i GATE: 4*3
mg/L
SD
SD
1.7 CV
O.OO69 CV
0.3
O.85
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
P214 EM
P214
P214
EM
EM
54:
RE:F>L_ i
0.9110 mg/L
4*±
1449 1O/22/98
peak-noisy
528
i C^TE: 4*2
0.8511 mg/L
RE:F=-I_ i C^TE: 4*3
0.8151 mg/L
AV
AV
530.O EM
O.8591 mg/L
SD 12.1 CV
SD 0.0484 CV
4*1
0.7951 mg/L
526
0.8431 mg/L
578
AV 539.3 EM
AV 0.8964 mg/L
499
506
i C^TE: 4*3
1.0508 mg/L
SD
SD
34.O CV
0.1359 CV
E: 4*1
0.7352 mg/L
i C^TE: 4*2
0.7632 mg/L
RSETF>L_ I
0.8391 mg/L
525
AV 510.0 EM
AV 0.7792 mg/L
914
918
SD 13.5 CV
SD 0.0538 CV
I CftTEI 4*1
2.3932 mg/L
RE;F>L_ i
2.4092 mg/L
2.3
5.64
1451 10/22/98
6.3
15.16
1453 10/22/98
2.6
6.90
1455 10/22/98
F>E:F>I_ i
4*3
-------
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
332 0 . 0680
AV 332.3 EM
AV O.0693 mg/L
438 0.4915
404 0 . 3557
401 0.3437
AV 414.3 EM
AV O.3970 mg/L
432 0 . 4675
435 0 . 4795
413 0.3916
AV 426.7 EM
AV O.4462 mg/L
423 0.4316
REIF>I_
433 0.4715
REF=-l_
409 0 . 3756
AV 421.7 EM
AV O.4263 mg/L
mg/L peak-noisy
SD 1.5 CV O.5
SD O.O061 CV 8.80
I GATE 4* ± 1437 10/22/98
mg/L peak-noisy
ICrtTE 4*2:
mg/L
mg/L peak-noisy
SD 20.6 CV 5.0
SD 0.0821 CV 20.68
i C^TE: 4* ± 1439 10/22/93
mg/L
i C<=*TE: 4*2
mg/L
Irf™ w .^^^, ^^^™ i^^~ ^Ufc ^^»l
^ i f ^"^ • T_ ^f^T I_ I
-0.0758 mg/L
1443 10/22/98
1.0
1.58
4* 1 1445 1O/22/98
window-edge
I CPfcTE 4*2
-0.0718 mg/L peak-noisy
-------
P214
P214
EM 312
P214 AV 315.7 SD
P214 CC 1.0000 SLOPE
EM 787
EM 851
6.4 CV
250.2997 INT
ICftTE 4*1
1 .8858 mq/L
2.O CONC O.OOOO
314.9751
1337 10/22/98
REZF^IL-I
2.1415 mg/L
4*2
RE:F>I_ i C^TE: 4*3
P214
B
P214
B
P214
B
P214
OO2
P214
OO2
P214
OO2
P214
1
P214
1
P214
1
P214
1
P214
1
P214
EM
P214
P214
EM
EM
EM
P214
P214
- B— 1
EM
- B — 1
EM
- B— 1
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
816 2.0017 mg/L
AV 818.0 EM SD 32.0 CV 3.9
AV 2.O097 mg/L SD O.1280 CV 6.37
RE:F>L_ i C^TE: 4*1 1339
318 0.0121 mg/L peak-noisy
RE:F=-L_ i C^TE: 4*2
316 0.0041 mg/L peak-noisy
RE:F>I_ i C*=*TE: 4*3
327 0.0480 mg/L peak-noisy
AV 320.3 EM SD 5.9 CV 1.8
AV O.O214 mg/L SD 0.0234 CV 1O9.35
REF*!- i c<=kTE: 4*1 1341
478 0.6513 mg/L
RE:F>L_ i C^TE: 4*3
498 0.7312 mg/L
F?E:F=-I_ i C^TTE: 4*3
494 0.7152 mg/L
AV 490. O EM SD 10.6 CV 2.2
AV 0.6993 mg/L SD O.O423 CV 6.05
REIF^LI c*=kTE: 4*1 1343
5019 18.7936 mg/L
REF^LIC^TE: 4*s
5017 18.7856 mg/L
• ' •>• f™ f " h j TT rf ' w ^^. * B fl_— • _fr^ *"^>
• ^^ F^^- • •. — - J» • _-
-------
400 Analysis Ver. 4.10 Thu 10/22/98 - 13:23:27
Dd File Name: P
rks :
t file is 10236
P214
P214
P214
P214
ftf«4r>£=*RlI> 4*2
P214
d Ivl T^ £2* 1^? T""^ At ^w^
1 • • ^V J^,f m^^9 • ^^« JLf^ ^ f WB«W
P214
ftNI>*=kRII> 4*2
P214
P214
ftMDl^RD 4*3
P214
P214
P214
P214
P214
P214
P214
P214
PhNK
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
Repl icates :3
368
369
RETR-L. I CftTE:
370
369 . 0 SD 1.0
550
563
RE:F>I_ i C^TE:
562
558.3 SD 7.2
RETF-L. I CftTE
798
RE:I=-L_ i C^TE:
816
838
817.3 SD 2O. 0
1550
1570
1581
1567.0 SD 15.7
RER-L I C^TE
Read Delay: 65
Data File:
4*1 1327 10/22/98
peak -noisy
peak-noisy
peak -noisy
CV O.3 CONC 0.2000
4* 1 1329 10/22/98
4*2
4*3
CV 1.3 CONC 1.0000
4* 1 1331 10/22/98
4*2
4*3
CV 2.5 CONC 2.0000
4*1 1333 10/22/98
<*^
4*3
CV l.O CONC 5.0000
4*1 1335 10/22/98
P214
EM
RER-L I C^TE 4*2
P214 EM 312
-------
!on cent rat ion (ua/L ): 59.5
lean Cone .(uo/L ): 58.2
;orrected Cone (ua/L ): 291.
Corrected Cone (ug/L ): 297.
SD: 1.85 RSD C/.): 3.18
H
TD: CC'-
Jeolicate 1
;oncentration (ua/L
88.6
?=>ol icate 2
Concentration (ua/L ): 88.2
Sea. No.: OOO42 A/S Pos.
Time: 14:45
Time: 14:48
lean Cone (ua/L ):
88.4
SD: 0.29
3C samole is within ranae 79-5 - 120.49
Date: 10/19/98
RSD ('/.}: 0.32
Ji
ID: CCB
Concentration (ua/L ): -4.3
•lean Cone < ua /L ) :
Sea. Mo.: 00043 A/S Pos.
Time: 14:52
Time: 14:55
Concentration (ua/L ): -4.
-4.2
SD: 0.06
Date: 1O/19/98
RSD C/.): 1.35
c samole is within ranae -15.49 - 15.49
-------
Jamole abs. is oreater than that of the largest standard.
lean Cone (ua/L ): 384.3 SD: 9.79
RSD C/.): 2.55
h" ID: AS Position 000 Sea. No.: O0037 A/S Pos. : 0 Date: 10/19
5eolicate 1 Time: 14:13
-oncentration (ua/L ): 5.6
;=>olic?t= 2 Time: 14:16
Concentration (ua/L ): -2.9
lean Cone (ua/L ) : 1.4 SD: 6.01 RSD(7.): 439.'
-H TP; 81006.1x5 Sea. No.: O0038 A/S Pos.: 28 Date: 10/19
?eolicate 1 Time: 14:20
Toncentration (ua/L ): 85.5 Corrected Cone (ug/L ): 427.
?<=o!ic?t= 2 Time: 14:23
Concentration (ua/L ): 79.0 Corrected Cone (ug/L ): 395.
lean Cone (ua/L ): 82.2 SD: 4.61 RSDC/.): 5.61
Corrected Cone (ua/L ): 411.
•Ji
TD: 81006.1x5
Sea. Mo.
Reolicate 1
Concentration (ua/L
): 165.4
'=nli rate 2
Concentration (ua/L ): 166.8
lean Cone (ua/L ):
Corrected Cone (ua/L
Recovery is 83.9V.
166.1
): 830.
O0039
A/S Pos.: 28
Time: 14:26
Corrected Cone (ug/L
Times 14:29
Corrected Cone (ua/L
SD: 0.96
Date: 10/19
): 827.
): 834.
RSDC/.): 0.58
Mi
TD: 81006.2x5
icate 1
Concentration (ua/L
Sea. No.
: 58.6
7 = o i i cat? 2
Concentration (ua/L ): 53.5
•lean Cone (ua/L ): 56.0
Corrected Cone (ua/L ): 280.
00040
A/S Pos.: 29
Date: 10/19
Time: 14:32
Corrected Cone (ug/L ): 293.
Time: 14:36
Corrected Cone (ua/L ): 267.
SD: 3.61
RSDC/.) : 6.45
'H TD: 81006.3x5
^eolicate 1
Concentration (ug/L ): 56.9
Sea. Mo,
00041
A/S Pos.: 3O
Date: 10/19
Time: 14:39
Corrected Cone (ug/L ): 284,
^policate 2
Time: 14:42
-------
i TD: 81OO3.T2
eolicate 1
oncentration (ua/L
Sea. Mo.
): 178.5
onrentration (ua/L ): 167.4
ean Cone (ua/L ): 172-9
00031 A/S Pos
Time: 13:41
Time: 13:44
SD: 7.88
26 Date: 10/19/98
RSD ('/.): 4. 56
li
ID: 81003.13
Sea. Mo,
eoli cate 1
oncentration (ua/L ): 122.9
loncent.r at ion (ua/L H : 122.4
lean Cone (ua/L }: 122.7
00032 A/S Pos,
Time: 13:47
Time: 13:50
SD: 0.36
27 Date: 10/19/98
RSD (*/.): 0.30
li
TD:
icate 1
:oncentration (ua/L ): 89.2
Sea. No.: OO033 A/S Pos.
Time: 13:53
Time: 13:57
: 3
Concentration (ua/L ): 90.1
lean Cone (ua/L
89.7
SD: 0.70
)C samole is within ranae 79.5 - 120.49
Date: 1O/19/98
RSD (V.): 0.78
Ji
TD: CCB
11icate 1
Concentration (ua/L ): -2.8
'PD! i ca te 2
Concentration (ua/L ): -3.8
Sea. No.: 00034 A/S Pos.
Time: 14:OO
Time: 14:03
0
•lean Cone (ua/L ): -3.3 SD: 0.74
3C samole is within ranae -15.49 - 15.49
Date: 1O/19/9E
RSD (7.): 22.59
TD: 81006.1
Sea. No.: 00035 A/S Pos.: 28 Date: 10/19/96
Bamole abs. is oreater than that oi the laraest standard.
^eolicate 1 Time: 14:06
-oncentration (ua/L ): 377.4
-.ample abs. is areater than that oi the laraest standard.
^eolicate 2 Time: 14:09
Concentration (ua/L ): 391.2
-------
"jDisqiay Calibration - C:\Afi US
0.*4-,
1 "
a
c.
J&3*
^&£
——?*' L 1 n e a r
PTtf i Corf. Coct1. : U.SSS72
r--^~^ ri^pe: 3.301?
(3 ConcenTracian ei!HJ.O
*
1,
Date: 10/19
Mi
ID: ICV
^eolicate i
loncentration (ua/L ): 106.1
Sea. No.: OOO07 A/S Pos
Time: 10:51
Time: 10:54
Zoncentration (ua/L ): 109.8
"lean Cone (ua/L )
10S.O
SD: 2.62
3C sample is within ranae 79.5 - 120.49
RSD(7.): 2.42
Mi ID: TCB
i ca te 1
Concentration (ua/L ): 3.6
Sea. No.: 00008 A/S Pos.
Time: 10s58
Times 11:01
Concentration iua/L ): 2.6
Mean Cone (ua/L ): 3.1 SD: 0.69
QC samnle is within ranae -15.49 - 15.49
Date: 10/19
RSD(7.) : 22.1
Mi
ID: 810O3.RB-AP
Sea. Mo.
RPD! i cate 1
Concentration (ua/L )
Concentration (ua/L
Mean Cone i uo/L ) :
Hi IT: 3)003.RB-F
Peolicate 1
Concentration (uo/L ):
-0.8
-6.1
-3.5
00009 A/S Pos,
Time: 11:04
Time: 11:07
SD: 3.71
14 Date: 10/19
Sea. No.: O0010 A/S Pos.: 15
Time: 11:10
RSD ('/.): 107.
Date
-0.
-------
TD: 5O PpB MI
Sea. No
00004
A/S Pos.: 2
Date: 10/19/9G
!eol i cate I
>eak Area (A-sJ: O.103
3ackaround Pk Area (A-s): 0.093
Hank Corrected Pk Area (A-s): O.O85
;oncen trat ion (uo/L ): 56.3
Time: 10:28
Peak Heioht (A): 0.056
Background Pk Heiqht (A): 0.037
3eak Area (A-s): 0.097
Background Pk Area (A-s): 0.102
31ank Corrected Pk Area (A-s): 0.079
:oncentration (ua/L ): 52.6
Time: 10:32
Peak Heioht (A): 0.054
Backaround Pk Heiaht (A): 0.041
'lean Cone ( ua/L )
54.4
Standard number 2 applied. F50.0"]
Correlation coefficient: 0.99739
SD: 2.62
Slope: 0.0016
RSD C/.): 4.82
TD: 1OO PPB MI
Sea. No,
00005
A/S Pos.: 3
Date: 1O/19/9E
Replicate 1
3eak. Area ( A-s ) : 0.190
Backaround Pk. Area (A-s): 0.125
Blank Corrected Pk Area (A-s): O.172
Concentration (ua/L ): 106.0
Time: 10:35
Peak Heiqht (A): 0.097
Backaround Pk Heiaht (A): 0.046
'(=nl irate 2
°<=>ak Area (A-s): 0.191
Backaround Pk Area (A-s): 0.133
Blank Corrected Pk Area (A-s): O.173
Concentration (ua/L ): 106.5
Mean Cone (ua/L ):
106.3
Time: 10:38
Peak. Heiaht (A) : 0.100
Backaround Pk Heiaht (A): 0.048
SD: 0.37
RSD C/.): O.35
Standard number 3 applied. [100.01.
Correlation coefficient: 0.99841
Slope: 0.0017
Mi TD: 200 PPB MI Sea. No
Replicate 1
Peak Area (A-s): 0.350
Backaround Pk Area (A-s): O.171
Blank Corrected Pk Area (A-s): 0.332
Concentration (ua/L ): 195.0
"poli cate 2
Peak Area (A-s): 0.366
Backaround Pk Area (A-s): O.133
Blank Corrected Pk Area (A-s): 0.348
Concentration (uq/L ): 204.6
00006
A/S Pos.: 4
Date: 10/19/9!
Time: 10:41
Peak Heiaht (A): 0.171
Background Pk Height (A): 0.066
Time: 10:44
Peak Heiqht (A): 0.176
Background Pk Height (A): 0.054
lean Cone (uq/L )
199.8
Standard number 4 applied. T200.0]
Correlation coefficient: 0.99972
SD: 6.78
Slope: 0.0017
RSD(7.): 3.39
-------
Element File: NI.GEL
Date: 10/19/98
Data File:
rechniaue: HGA
Element: Ni
Time: 1O:09
ID/Wt File: 81002.IDW
Calib. Tvoe: Linear
Wavelength: 232
Slit: 0.20 L
Lamp Current: 21
Energy: 47
ID: BLANK
1
Sea. No.: 00001
=eak Area ( A-s ) i 0.041
Backaround Pk Area (A-s): 0.096
Blank Corrected Pk Area (A-s): 0.041
3e
-------
M I 1 00
98/10/2O
PAGE
v ' 'P ». 1
¥ i >L> £^_3
MAIN: -0,06
HG Ul
MAIN: 0. 19
HG t/(T__
MAIN; 0..00
HG . "\
MAIN: 0. 19
HG $ (
MAIN;, 0.22
/MA I Me 0..27
MAIN;. 4.76^
«c£
& HG ,
MAIN;: 1 0. 03
HG ^
MAJNr 0.01
HG £
MAIN: 0.09
[ HG £-T,&
^- MA IK" i -0. 04
> ^^,
^MAIN; 3.01
HG U-7^^
MAINt 7.39
r iL) l*i™"~
MAIN? 2,, 19
f
HG «-^
MAIM: 4.42
UG/L
UG/L
UG/L.
UG/L
UG/L.
UG/L.
X
UG/L.
•^
V_
UG/L.
UG/L
UG/L.
x*
UC/L
UG/L...
U6/L
UG/L
UG/L
AA-BG
PA-O.OOB
PH-0. 002
PA
PH
PA
PH
PA
PI -I
PA
PH
PA
PH
PA
PH
x'
PA
PH
PA
PH
PA
PH
AA-BG
0 . 023
0. 005
AA-BG
0. 005
0. 000
AA-BG
0, 1O1
0. 005
AA-BG
0 . OB9
0. 006.
AA-BG
O, 124
O. 007
AA-BG
2,, 145
O. 129
AA-BG
ov no 3
0 „ 00 1
AA-BG
0, 024
0. 000
AA-BG
0 ., 039
O, OO2
AA-BG
PA-0, 019
PH-0. 001
PA
PH
PA
PH
PA
PH
PA
PH
AA-BG
1 , 295
0. OB2
AA-BG
3 , 307
0. 200
AA-BG
0,935
0. 059
AA-BG
2, 141
0. 120
BG
-0,029
-0. 000
BG
-0.012
-0. 000
BG
-0.010
0 . 00 1
BG
— 0. OO4
0.. OO2
BG
-0 . 0.1 3
-0.001
BG
0,. 0.20
O.. 002
BG
0 . 0 1 2
O. 001
EG
-o. no?
-0,. 001
BG
-0. 003
0. 001
BG
-0. 012
-•0. 000
BG
0 ., 0 1 8
0. OOO
BG
O., 049
O. 003
BG
0. 008
0. 001
BG
0. 021
0. 002
BG
0. 007
0. 002
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIM:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MA I N :
HG
MAIN:
-0.06 UG/L
0. 12 UG/L
-0.01 UG/L
0. 15 UG/L
0.24 UG/L
0.32 UG/L
-0.06 UG/L
0.09 UG/L
0. 12 UG/L
-0.01 UG/L.
0.07 UG/L
3. 13 UG/L
7,34 LJG/L
2.29 UG/L
-0.09 UG/L
AA-BG
PA-0. 022
PH-0. 002
AA-BG
PA 0.043
PH 0.003
AA-BG
PA-0., 006
PH-0. OOO
AA-BG
PA 0.080
PH 0. 004
AA-BG
PA 0. 121
PH 0.006
AA-BG
PA 0. 12.8
PH 0 . 009
AA-BG
PA-0, 052
PH-0. 002
AA-BG
PA O.O26
PH 0.002
AA-BG
PA 0,026
PH 0.003
AA-BG
PA-O.. 004
PH-0, 000
AA-BG
PA-0.. 016
PH 0.002
AA-BG
PA 1.365
PH 0.085
AA-BG
PA 3 . 355
PH 0. 199
AA-BG
PA 0.951
PH 0.062
AA-BG
PA-0. 066
PH-0. 002
EG
-0.003
0. 001
BG
0 . 000
0 . OOO
BG
-0.010
-0. 001
BG
0.006
0. OOO
BG
--0.-007
0 . OOO
BG
-0.002
-0 . 00 1
BG
-0,008
0. 00.1
EG
0.005
-0. OOO
BG
-0.016
-0. 000
BG
0.010
o.ooo
BG
O.O04
— 0. 000
BG
-0 . 006
-O.OOO
BG
0 . 05O
0. 002
BG
0.011
0.002
BG
-0 . 009
-0.001
-------
!vi 1100
98/10/20 PAGE 3
HGA DISPLAY CALIBRATION MODE
ELEMENT: H6 - PEAK HEIGHT
a.278~l
flBS.
^^•"""
^--<
--K"*" S3
Si S2
PRINTER:
BS CORR:
UNITS :
CH.MABS:
_i^"""
w-"-^f-
S4
0 CONCENTRATION (UG/L
HG <£CV
MA I N : 4 ,
'> HG 1L<1 ,
^ MAIN: -0.
•*J-
1 !G flJl
MAIN: 0.,
AA-EB
79 UG/L. PA 2.038
PH 0. 130
Af AA-BG
07 UB/L PA-0 .033
PH--0. 002
*~€ AA-BB
OO UG/L PA--O.OG5
PH 0. OOO
HG £<£ AA-BB
MAIN;. -Ou
HG ^ -
MAIM; -0.
HG £g,
MAIN: 0.
HG 6 1
MAIN- 0.
HB 013
MAIN: 4.
HB &**-
MAINr 4,
-••*
HG 0 1
W MAINr • 0..
04 UG/L PA-0. 026
PH--0. 001
k AA-BG
03 UB/L PA-0. 014
PH-0.001
AA-BG
04 UG/L PA 0., 014
PH O.OO1
AA-PG
01 UB/L PA 0,017
PH 0.000
AA-BG
43 UG/L PA 1,. 985
PH 0. 120
#>/»X AA-BG
53 UG/L. PA 2. .022
' PH 0. 123
AA-BG
">3 UG/L PA-0.. 031
PH- 0, 00.1.
BB
0 . 0 .1. 1
0. 001
BG
-0.021
-0. 002
BG
-0. 041
-0. OO2
BG
-0. 044
-0. 002
BB
-0.011
0,. 000
BG
-0.007
-0. 001
BG
-0.017
0. 000
EG
-0. 0.1.1
-0. OOO
BG
-0.010
0. 000
BG
-0,. 020
— 0. 001
ON
ON
UG/L
^--
^^
)
HG ££S
MAIN:: -0.
HB
MAIN: -0.
HG
MAIN: 0.
HG
MAIN: 0.
HG
MAIN: 0.
HG
MAINr -0.
HG
MAIN; 0.
HG
MAIN: 5.
HB tc. {.
MAIN: -0.
HG
MAIN: -0.
10.25
, READ
^^ PEAK AREA (A-S)
35 AA-BG: 4.198
BS: 0.021
PEAK HEIGHT (A)
AA-BG: 0.278
EG: 0.303
1
13.25
AA-BG BB
13 UG/L PA-0 ,098 -0.000
PH-0.004 -0.000
AA-BG BB
01 UG/L PA-0., 004 -0.024
PH-0.000 -0.001
AA-BG BB
03 UG/L PA-0. 01 9 -0.040
PH 0.001 -0.001
AA-BG BG
03 UG/L PA-0. 019 -0.018
PH 0.001 -0.001
AA-BG BB
01 UG/L PA-0. 029 -0.015
PH 0.000 -0.002
AA-BG BB
04 UB/L PA-0. Oil -0.029
PH-0.001 -0.002
AA-BG BB
03 UG/L PA 0.007 -0.016
PH 0.001 -0.000
AA-BG BG
04 UG/L PA 2.323 O.OOB
PH 0. 13& 0.000
^ AA-BB BS
IB UG/L PA-0. 104 -0.012
PH-0.005 -0.001
AA-BG BB
01 UG/L PA-0. 032 -0.020
PH-0. OOO 0.000
-------
M 1100 ' 98/10/20 PAGE 2
HG AA-BG EG
MAIN; 0.001 PA 0.030 0.005
PH 0.00:1 O.OOO
AUTDZERD
HG AA--BG EG
MA IN E 0,. 0 i 0 PA 0 .,141 0 „ 0 i 8
PH 0-010 0.000
1,STANDARD
HG AA-BG BG
MAIN: 1.21 LIG/L PA 0., 428 -0.040
PH 0.025 -O.001
E6:i Sample? concentrat i on greater than highest standard
1.03 2.STANDARD
HG AA-BG BG
MA1N: 1„70 UG/L PA 0.657 -O.025
PH 0.042 -O.O01
E61 Eanipl G; concentration grc-?at.c?r than highest standard
1.91 3.STANDARD
HG AA-BG BG
MAIN: 5.73 UG/L PA 2,. 020 0-024
PH 0.125 0.002
E61 Samp i e c. on c c?r11 r a t i Dn g r eat er t han high a«; t ot iind ar d
5. 10 4.STANDARD
HG AA-BG BG
MAIN: 11.31 UG/L PA -1.198 O.O21
PH 0.278 0.003
EM Samples concontrati on greater than highest standard
10.25 5.STANDARD
-------
PERKIN--ELMER M 1100 98/10/15 PABE 9
AA AA
MA IN: 0.451 MG/L HO 0.O57 MAIN: 0.465 MG/L HO 0. 059
MN /£"2_ MEAN: 0.458 MG/L ED: 0.010 RED: 2.2
AA AA
MAIN: 0.446 MG/L HO 0,056 MAIN: 0.442 MG/L HO 0.056
MN /£3> MEAN: 0.444 MG/L SD: 0.003 RSD: 0.6
AA AA
MAIM: 0.494 MG/L HO 0.062 MAIN: 0.516 MG/L HO 0.065
MEAN;: 0.505 MG/L SD: 0.016 RSD: 3.1
AA AA
MAIN: 0,879 MG/L HO 0,. Ill MAIN: 0.885 MG/L HO 0.111
MM I <> MEAN: 0.8B2 MG/L BD: 0.004 RGD: 0.5
AA AA
MAIN: 0.345 MG/L HO O.043 MAIN: 0.322 MG/L HO 0.041
MN 2_ MEAN: 0.334 MG/L BD: 0.017 RSD: 5.0
AA AA
MAIN: 0.333 MG/L HO 0.042 MAIN: 0.336 MG/L HO 0.042
MN 2-J> MEAN: 0.334 MG/L SD: 0.002 RSD: 0.6
AA AA
MAIN: 0.359 MG/L HO O.045 MAIN: 0.356 MG/L HO 0.045
MN 3 MEAN: 0.358 MG/L BD: 0.003 RSD: 0.7
AA AA
MAIN: 0.473 MG/L HO 0,060 MAIN: 0.475 MG/L. HO 0.060
MN O-U MEAN: 0.474 MG/L 5D: 0.001 RSD: 0.2
AA AA
MAIN: -0.016 MG/L HO-0.002 MAIN: -0.020 MG/L HO-0.003
MN C(_Q MEAN: 0.01B MG/L. ED: 0.003 RSD: 17.7
-------
PERKIN-ELMER M iiQO 98/10/15 PAGE B
AA AA
MAINs 0.064 MG/L HO 0.008 MAIN: O.067 MG/L HO 0.008
MM & "£— MEAN: 0.065 MG/L BD: O.003 RSD: 3.9
AA AA
MAIN: 0.062 MB/L HO 0.008 MAIN: 0.067 MG/L HO O.008
MN 07, MEAN: 0.065 MG/L SD: 0.004 RSD: 6.2
AA AA
MAIN: 0.033 MB/L. HO 0.004 MAIN: 0.034 MB/L HO 0.004
MN A,-7 MEAN: 0.034 MB/L BD: 0.000 RSD: 1.4
AA AA
MAIN: 0.027 MB/L HO 0.003 MAIN: 0.031 MG/L HO 0.004
MM Ul MEANj 0.029 MB/L BD: O.OO3 RSD: 10.8
AA AA
MAJNr 0.03.2 MG/L HO 0.004 MAIN: 0.029 MG/L HO O.004
MN M ^- MEAN; 0,031 MB/L' SD: 0.002 RSD: 5.6
AA AA
MAINs O.O14 MG/L HO 0.002 MAIN: 0.013 MG/L HO O.002
MN (A "* MEAN: 0.014 MG/L SDr 0.001 RSD: 6.5
AA AA
MAIN: 0.4B9 MG/L. HO 0.062 MAIN: 0.480 MB/L HO 0.060
MN CfJ MEAN: 0,484 MB/L BD: 0.007 RSD: 1.4
AA AA
MAIN: -0.007 MG/L HQ--0»001 MAIN: -O.O08 MG/L HO-O.001
MN ' MEANs-0. O08 MB/L SD: 0.000 RSD: 5.1
AA AA
MAIN: 0.416 MG/L HO 0,052 MAIN: 0.427 MG/L HO O.054
MN ,r\ MEAN: 0.421 MB/L SD? O.OOB RSD: 1.9
AA AA
MAIN: 0.000 MB/L HO 0.101 MAIN: 0.799 MB/L HO 0.101
MN £.13 ME AN: 0.800 MG/L SD: 0.001 RSD: 0.1
-------
PERKIN-EL.MER M 1100 98/1O/15 PASES
AA AA
MAIN: 0.005 MS/'L HO-0.000 HAIM: 0.004 MG/L HQ-O.OOO
MN MEANs 0.005 MB/L SD: 0.001 RSD: 18.9 AUTOZERO 0.000
AA AA
MAlMr 0.494 MG/L. HO O.O62 MAIN: 0.499 MB/L HO O.O63
MN/£V MEAN; 0.496 MG/L 3D: 0.004 RSD: 0.7
AA AA
MAIN: 0.001 MG/L HO 0.000 MAIN: -0.001 MB/L HO-0.000
MEAN s--0. 000 MG/L SD: 0.002 RSD: 99.9
AA AA
MAIM: 0.050 MG/L HO 0.006 MAIN: 0.057 MG/L HO 0.007
L-MN/?_l MEAN: 0.053 MG/L SD: O.OO5 RSD: 9.9
AA
MAIMs 4.074 MG/L HO 0.513
E61 Sample concentration greater than highest standard
AA
MAIN; 4.113 MG/L HO 0.518
E61 Saiftpl i-:>te<5riceritrati on greater than highest standard
MM C-^l MEAN; ,.4<094 MG/L SD: 0.027 RSD; 0.7
AA , AA
MAIN: 0,004 MG/L HO 0-001 MAIN: 0.005 MG/L HO 0.000
MN SMf ME\::. 0,005 MG/L SD: 0.001 RSD: 19. B AUTOZERO 0.000
AA AA
MAIN; 0.352 MG/L HO 0.044 MAINs 0.360 MG/L HO 0.045
|VW c~UlC> MEAN: 0.356 MG/L SD: O.OO6 RSD: 1.6
AA AA
MAIN: 0.848 MG/L HO 0.107 MAIN: 0.845 MB/L HO 0.106
MEAN: 0.847 MG/L SP: 0.002 RSDr 0.3
AA AA
MAIN: 0.680 MG/L HO 0.086 MAIN: 0.687 MB/L HO O.OB7
MM ?-U £"~ MEAN: 0.6B4MB/L SD: 0.005 RSDt 0,8
-------
PERKIM-ELMER
M 1 1 CO
98/10/15 PAGE 4
MAIML -O.OOO
MN MEAN:-0.000
A A
HO-O.OOO
AA
HO 0.000
MAIN: -0.000
BD: 0.000 RSD: 52.8 AUTOZERO 0.000
MAIN: 0.006
MM MEAN;: 0.006
AA
HO 0.006
AA
HO 0.006
MAIN: 0.006
GD: 0.000 RSD: 1.1 1.STANDARD 0.050 MG/L
AA
AA
MAINt 0.101 MG/L HO 0,013 MAIN: 0.102 MG/L HO 0.013
MM MEAN: 0.101 MG/L SD: O.OOO R3D: 0.3 2.STANDARD 0.100 MG/L
AA
AA
M AIN: 0.194 M6/L H0 0.0 25 MAIN: 0.200 MG/L HO 0.0 2 6
MN MEAN: 0,197 MG/L SDr 0.005 RSD: 2.3 3.STANDARD 0.199 MG/L
A A
MAINs 0.516 MG/L HO 0,,065
A A
MAIN: 0.514 MG/L HO 0.065
MN
MEAN: 0.515 MG/L SD: 0.002 RSD: 0.3 4.STANDARD 0.503 MG/L
AA
AA
MAIN: 0.943 MG/L HO 0.122 MAIN: 0.950 MG/L HO 0.123
MN MEAN:: 0.947 MG./L SD: 0.005 R5D: O.6 5. STANDARD 0.987 MG/L
A A
A A
MAIN; 1,015 MG/L. HO 0.126 MAIN: 0.988 MG/L HO 0.123
MN MEAN: 1,002 MG/L SI): 0.019 RED: 1-9 5« STANDARD 0.990 MG/L
FLAME DISPLAY CALIBRATION MODE
ELEMENT: MM
REPL. 0 OF 2
0.125
AES.
PRINTER: ON
EG COPR: OFF
UNITS : MG/L
SI
0.990
FIBS. READING
S5 AA : 0.123
STATISTICS
MEAN: 1.002
SD: 0.019
RSD
-------
PERKIN--EL.MER M 1100 98/10/15 PAGES
AA AA
MAIN: 2,41 MB./L. HO 0.035 MAIN; 2.36 MG/L HO 0.034
PB /.<, MEAN: 2,30 MG/L BD: 0.034 RSD: 1.4
AA AA
MAIN: 0.33 MB/L HO 0,005 MAINE 0.36 MG/L HO O.O05
P3 ^- MEAN;; 0.34 MG/L SD: 0.021 RGD: 6.1
AA AA
MAINs 0.35 MG/L HO 0.005 MAIN: 0.30 MG/L HO 0.004
PB 2~£> MEAN:' 0.32 MB/L SD: 0.037 R5D: 11.4
AA AA
MAIN: 0,. 33 MG/L HO 0.005 MA I Ms 0.38 MG/L HO O.005
PB ? MEAN: 0.35 MG/L SDs 0.036 RSD: 10.1
AA AA
MAIM: 1.94 MG/L HO 0.02S MAIN: 1.94 MG/L HO 0.028
PB ffj MEAN: 1.94 MG/L SD: 0.005 RSD: 0.3
A A A A
MAIN: -0.02 MG/L HO-0.000 MAIN: --0.05 MG/L HO-O.001
MEAN: --0.03 MG/L SD: 0.023 RSD: 69.5
-------
i-'L-RKJ.!\i--GLMFR
M HOC
98/10/15 PAGE 2
AA AA
MAIN: 1.98 MG/L HO 0.029 MAIN: 1.92 MG/L HO O.028
PB frv MEAN: 1.95 MG/L SD: 0.039 RSD: 2.0
AA AA
M A J N t, 0.01 T'i G / L !-! 0 0. 0 0 0 MAI N: 0.0 O MG/L H 0 O., 0 0 O
PB -^R, MEAN; 0.01 MG/L SD: 0.007 RBD: 99.9
A A A A
MAIN: 1,. 02 MG/L HO O..015 MAIN: 1.04 MG/L HO O.015
PB £ J MEAN: 1,03 MG/L SD: 0.018 RGB: 1.7
A A A A
MAIN: 3,, 00 MG/L. HO 0.044 MAIN: 2.95 MG/L HO 0.043
MEAN: 2.98 MG/L SD: 0.036 RSD: 1.2
AA AA
MAINs 1.54 MG/L HO 0,022 MAIN: 1.53 MG/L HO O.022
PB <£ "l^ MEANs 1.53 MG/L SD: 0.010 RSD: 0.6
AA AA
MAIN: 1.55 MG/L HO 0.022 MAINs 1.60 MG/L HO O.023
PB ^Tj) MEAN: 1.57 MG/L GD: 0.038 RBD: 2.4
A A A A
MAIN: 1.2B MG/L HO 0.019 MAIN: l.^f. I'C'L I in 0.019
PB ,£3> MEAN; 1 . 2f 'C-'!. '""I- "• 00:'. HrD:. C „ 1
AA
N.Vi •"'.' - .. :;r •":• ':";2~ MAIK:: 1 93 MG/L. HO O.O23
!'''"•' ff \J ''T'-iV 1-9';- MP- 'I- V3D: 0.039 RSD;- 2=0
A A A A
!1A •'!•!: --0.0? MC5/L !-:C-0,;"'00 MAIN: -0.01 MG/L HO-O.OOO
Clc: _.o MEAN-. -0.02 MG/L ED: 0.009 RBD: 55.4
AA AA
MAIN: 0,. 46 MG/L HO 0,007 MAIN: 0.41 MG/L HO O.O06
PB / MEAN: 0,43 MG/L SD: 0.036 RSD: 8.2
-------
F'ERKIM-ELMER
M 1100
96/10/15 PAGE 1
=:=: = =:i=~=;r_' = =: = K:=:=!=s=5—=:s:s: —BK
AA
HO-0., 000
MAIN: -0.000
AA
HO 0.000
PB
MEAN;-0. 000
SD: 0.000 RSD: 99.9 AUTOZERO 0.000
MAI ML 0.003
AA
HO 0.00"
MAINE O.O03
AA
HO 0.003
ME™ AN: 0. 003
SDs 0.000 RBD: 2,. 2 1. STANDARD 0.20 M6/L
A A
AA
MAIN: 0.4Q MG/L HO 0,007 MAIN: 0.4B MG/L HO 0.007
PB MEAN: 0.48 MB/L BD: 0.001 RSD: 0.3 2.STANDARD 0.50 MG/L
AA
AA
MAIM: 0,,9G MG/L HO O.. 014 MAIN: 1. OO MG/L HO 0,0:15
PB MEAN: 0.99 MG/L SD: 0.017 RSD: 1., 7 3. STANDARD 1.00 MG/L
A A
AA
MAIM: 1.97 ME/L HO 0., 029 MAIN: 1.95 MG/L HO 0.029
PB MEAN: 1.96 MG/L SD: 0.015 RSD: O.B 4.STANDARD 1.99 MG/L
Art
MAIN; 5,00 MG/L HO O., 072
MAIN:
AA
5.01 MG/L HO 0.073
MEAN: 5.00 MG/L SD; 0.007 RSD: 0.1 5.STANDARD 5.00 MG/L
FLAME DISPLAY CALIBRATION MODE
ELEMENT: PB
REPL. 0 OF 2
0.072"|
AES.
PRINTER: ON
BS CORR: OFF
UNITS : MG/L
5,00
ASS. READING
S5 AA : 0.07;
S2
CONCENTRATION (MG/L )
5.00
STATISTICS
MEAN: 5.00
SD: 0.007
RSD(JO: 0.1
C2H2: 2.5 L/MIN OXIDANT: 8.0 L/MIN FLAME: C2H2-AIR
AA
M AI N: -- 0.01 MG/L H 0 •- 0 . 0 0 0
O 01 Mr;/!
AA
MAIN: O.O.? MB/L HO 0.000
n OVA pqr>; <-;o p AUTO?FRO o. oo
-------
CU324
CU324 EM
CU324 EM
'V
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
:B
CU324 EM
CU324
CU324
IMF»I_E:
CU324 EM
AV
EM
1.8806 mg/L
5849
37568
i GATE:
1.9682 mg/L
RE:F^L_ i GATE:
2.0657 mg/L
RE:F>I_ i GATE:
2.0165 mg/L
SD 1O17.2 CV
SD 0.0577 CV
4*±
3.0
3.07
10/15/98
*t=3
SD
SD
0.0173 mg/L
36700
AV 367O5.7 EM
AV 2.0168 mg/L
1441
1263
I
1276 0.0079 mg/L
AV 1326.7 EM SD
AV O.0108 mg/L SD
859.5 CV
O.0487 CV
2.3
2.42
0.0072 mg/L
CU324 EM
1369
1337
REIF"!- I
0.0132 mg/L
99.2 CV
0.OO56 CV
I 4* ±
± 1616 10/15/98
peak-noisy
peak-noisy
7.5
52.22
1618 10/15/98
i GATE:
0.0114 mg/L
-------
CU324 AV
CU324 AV
OO& . 1
CU324 EM 5058
OO& _ 1
CU324 EM 4994
OO& _ 1
CU324 EM 5053
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324
CLJ324
EM
EM
U . l-' 1 y .•£ I II 9 i l_
1363.7 EM SD
O.0129 mg/L SD
68.4 CV
O.O039 CV
I C#=lTE 4*1
0.2223 mg/L
FSEF>L_ I CftTE 4*2
0.2187 mg/L
REF^L. I
0.2221 mg/L
4*3
CU324
CU324
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
AV
AV
4587
4592
4651
AV
AV
5035. O EM
0.2210 mg/L
0. 1956
REF>I_
0. 1959
REF=-L_
0.1993
4610. O EM
O.I 969 mg/L
SD
SD 0.
mg/L
X C*=*TE
mg/L
mg/L
SD
SD 0.
35.6
0020
4* 1
4*2
4*3
35.6
O020 i
4*1
4625
4659
4633
AV
AV
4718
4626
4785
AV
AV
34111
35403
0.1978 mg/L
REF»I_I
0.1997 mg/L
F£EF>L_ I C^TE 4*3
0.1982 mg/L
4639.0 EM
O.1986 mg/L
0.2031 mg/L
SD 17.8 CV
SD O.O010 CV
4*1
4*2
r c<=»-ri
0.1978 mg/L
REF>I_ I GATE 4*3
0.2069 mg/L
47O9.7 EM SD
O.2026 mg/L SD
REF-L.I
1.8697 mg/L
79.8 CV
O.O045 CV
I 4*1
1.9429 mg/L
RE
5.0
30.12
1606 10/15/98
0.7
0.91
1608 1O/15/98
0.8
1.02
1609 10/15/98
0.4
0.51
1611 1O/15/98
1.7
2.23
1613 10/15/98
4*3
-------
CU324
CU324
CU324 EM
CU324 EM
CU324
CU324
CU324
CU324
CU324
CU324
CU324
-V
CU324
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
CU324 EM
CU324 EM
CU324
CU324
B
CU324 EM
B
CU324 EM
0.1442 mg/L
1470 0.0189 mg/L
AV 1510.0 EM SD
AV O.O212 mg/L SD
3679
3654 0.1427 mg/L
FSEF>I_I
3624 0.1410 mg/L
AV 3652.3 EM SD
AV 0.1426 mg/L SD
34.7 CV
0.0020 CV
E 4*±
4*2
4*3
27.5 CV
O.0016 CV
4844
4875
4907
RE:F>-I_ i GATE 4*1
O.2102 mq/L
RE:F>L_ i
O.2120 mg/L
0.2138 mg/L
AV 4875.3 EM
AV 0.2120 mg/L
4641
4695
SD
SD
E 4*3
31.5 CV
O.O018 CV
4789
AV 47O8.3 EM
AV 0.2025 mg/L
37874
38366
0.2018 mg/L
REF>l_I
0.2071 mg/L
SD
SD
38573
AV 38271.0 EM
AV 2.1055 mg/L
1442
1333
I CftTE 4*±
0.1987 mg/L
4*2
4*3
74.9 CV
0.0042 CV
E 4*±
4*2
4*3
359.1 CV
0.0204 CV
I CftTE 4*1
0.0173 mg/L
2.0830 mg/L
2. 1109 mg/L
2.1227 mg/L
SD
SD
2.3
9.28
1557 10/15/98
0.8
1.O9
1559 1O/15/98
0.6
O.84
16O1 1O/15/98
1.6
2.10
16O2 1O/15/98
0.9
0.97
1604 1O/15/98
I CftTEI 4*2
0.0111 mg/L
-------
I—11 "•« I '-s.
CU324 EM 1164
CU324 AV 1285.O SD 11O.6 CV 8.6 CONC
CU324 CC 1.0000 SLOPE 17636.554 INT 1136.6479
0.0000
CU324 EM
V
CU324 EM
V
CU324 EM
CU324
CU324
36059
36151
I CftTE # 1
1.9801 mg/L
1504 10/15/98
36900
AV 36370.0 EM
AV 1.9977 mg/L
1.9853 mg/L
REF>I_ I
2.0278 mg/L
•Zf*'
L
^<=*'
L
SD
SD
T~E 4*2
TE 4*3
461.3 CV
0.0262 CV
1.3
1.31
CU324 EM
CU324 EM
1289
1294
0.0086 mg/L
REF>l_I
O.OO89 mg/L
CU324
OO2
CU324
OO2
CU324
OO2
CU324
1
CU324
1
CU324
1
CU324
1
CU324
EM
CU324
CU324
. B— 1
EM
EM
. B— 1
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
1229
AV
AV
1792
1852
1842
AV
AV
3593
3780
3746
AV
AV
3459
0
1270.7
O.0076
0
. 0052
EM
mg/L
. 0372
REF>L
0 . 0406
REF>I_
0 . 0400
1828.7
0.0392
0
R
0
EM
mg/L
.1393
ER-I—
. 1499
mg/L
SD
SD 0.
IC^HTE
mg/L
mg/L
I C*=fcTE
mg/L
SD
SD 0.
mg/L
ICftTE
mg/L
REF>I_ I CftTE
0.1480 mg/L
3706.3
0.1457
R
0
EM
mg/L
EF>I_
. 1317
SD
SD 0.
peal
36.2 CV
0021 CV
4*1
»=>
4*3
32 . 1 CV
0018 CV
4*1
4*2
4*3
99.6 CV
0056 CV
ICATE 4*1
mq/L
4*1 15O6 10/15/98
peak—noisy
4*2
peak-noisy
4*3
2.8
26.99
15OB 1O/15/98
1.8
4.65
1509 10/15/98
2.7
3.88
1511 10/15/98
-------
3MA 400 Analysis Ver. 4.10 Thu 10/15/98 - 14:52:14
od File Name: CD
rks: CU ONLY
t file is 10236
CU324
CU324
CU324
CU324
AIMDARD 4*2
CU324
^g^ Ixl T^ £2k f^ T~fr 4*^2
CU324
AIMDARD 4*2
CU324
CU324
AIME>ARE> 4*3
CU324
ANDARD 4*3
CU324
CU324
CU324
ANDARD 4*^4-
CU324
AIMDARD 4*-4-
CU324
ANDARD 4*-=*
CU324
CU324
=IIMK
CU324
^MK
CU324
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
Repl icates:3
Rr~r~n T t~~*£^—w-tz^ •**• ••
i • i JL 4_^f"^ I w^ 1 1 .A.
2893
2922
3032
2949. O SD 73.3 CV
18716
F5EF>L_ I CATE 4*2
18102
18600
18472.7 SD 326.2 CV
36619
^^^ Bw^ i^^^ I ^r rf " w ^^^. ^^^* ^^~* ^K^ —"^^
•^S, L^_ • B^^ Jv "i . i i<~ F^l 1 E^— ^«* ^K->
36754
t^> t " • "'^ i "r rf11 "w ^y^ "T™ ft^T" **" -l-Hi
r^. •- — • ^_ ^L ^•.i^* •"' Tl •• » i"~in • • ••mTv
36O7B
36483.7 SD 357.7 CV
87901
89983
R:EF=-I_ i GATE 4*3
90163
89349. O SD 1257.2 CV
RER-L I GATE 4*1
1381
RER-L. I GATE 4*2
1310
Read Delay: 60
Data File:
1455 10/15/98
2.5 CONC O.10OO
1457 10/15/98
1.8 CONC l.OOOO
1459 10/15/98
1.0 CONC 2.0OOO
1501 10/15/98
1.4 CONC 5.00OO
1502 10/15/98
-------
fSl*«t ft^/19/98
cr267
cr267
cr267
EM
EM
EM
cr267 EM
cr267
cr267
B
cr267
EM
cr267 EM
B
cr267 EM
5695
5877
6603
1 .9773 mg/L
RE:F>I_ i
2.0472 mg/L
=1*2:
5959
AV 6O33.5 EM
AV 2.1072 mg/L
512
487
508
2.3258 mg/L
F3!EF>L_ I
2.0786 mg/L
SD
SD
4*-*
395.4 CV
0.1517 CV
6.6
7.2O
-0.0118 mg/L
1 1525 1O/19/98
peak-noisy
-0.0214 mg/L
-0.0133 mg/L
peak-noisy
4*3
peak-noisy
4*4
window-edge
14.7 CV
0.0057 CV
0.0017 mg/L
peak -noisy
0.0032 mg/L
window-edge
O.OO20 mg/L
cr267 EM
cr267 EM
MF>l_E
cr267 E
-0.0033 mg/L
REF>I_
0.0124 mg/L
cr267 EM 541 -0.OOOG/rfig/L
cr267 AV 548.3 E*T SD 18.2 CV
cr267 AV O.Op^l mg/L SD O.O070 CV
MF>I_E 4*2-* / RE:F»l_ T Cf^~rf=: 4*1
1529 10/19/98
w iodbw—edge
peak-noisy
4*3
peak-noisy
4*4
peak-noisy
3.:
15.31 in/19/98
-------
or267 EM
cr267 EM
cr267 EM
cr267 EM
cr267
mg/i
REIF=-L_
!=>L>
41= ±
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM J
/\f
EM
EM
cr267
cr267
EM
EM
EM 3
EM
cr267
cr267
1135
1076
1095
1081
AV
AV
1044
/ 1080
1108
1105
AV
AV
1098
1 1 04
1147
1062
AV
AV
0.2273 mg/L
RER-I— I Crf=fcTE 41=2
0.2047 mg/L
RER-L- i GATE:
0.2120 mg/L
0.2066 mg/L
1096.8 EM SD
0.2126 mg/L SD 0.
0.1924 mg/L
RER-I— i GATE
0.2062 mg/L
0.2170 mg/L
RER-L I GATE
0.2158 mg/L
1O84.3 EM SD
0.2O78 mg/L SD 0.
0.2131 mg/L
RER-L. I GATE
0.2154 mg/L
0.2319 mg/L
0.1993 mg/L
1102.8 EM SD
0.2149 mg/L SD 0.
41=3
41= -4-
26.7 CV
0103 CV
4f=±
41=2
41=3
41= -*
29.6 CV
0114 CV
4*1
41=3
4*= -4-
34.8 CV
0134 CV
4*±
1.7248 mg/L
41=3
5037
4910
S089
5151 1.7685 mg/L
AV 5046.8 EM SD 102.4 CV
AV 1=7285 ma/L SD 0.0393 CV
1 .6760 mg/L
ER-L-IC
1 .7447 mg/L
1516 10/19/98
2.4
4.83
1518 10/19/98
2.7
5.47
152O 10/19/98
3.2
6.22
1522 10/19/98
2.0
2.27
-------
HV
mg/i_
cr267 EM
cr2&7
EM
cr267 EM
cr267 EM
cr267
cr267
V
cr267 EM
cr267 EM
V
cr267 EM
V
cr267 EM
cr267
cr267
B
cr267 EM
•:r267 EM
B
cr267 EM
cr267 EM
cr267
cr267
692
724
687
780
AV
AV
6026
6188
6083
6012
AV
AV
546
516
516
REF=-L_ i
0.0573 mg/L
1508 1O/19/9B
REF=>L_ I
0.0696 mg/L
44=12
0.0554 mg/L
ICATI
0.0911 mg/L
720.8 EM SD
0.0683 mg/L SD
REF=>L_I
2.1043 mg/L
44=-4
42.8 CV
O.O164 CV
44=1
5.9
24. Ol
1510 1O/19/98
2.1665 mg/L
ICATI
2.1262 mg/L
REF*I_ I Crf=fcTI
2.0990 mg/L
6077.3 EM SD
2.124O mg/L SD
: 44=3
: 44=4
80.0 CV
0.0307 CV
REF>l_ICftTE 44=1
0.0013 mg/L
REF=>1_ I GATE 44=S
-0.0102 mg/L
1.3
1.44
1512 10/19/98
495
I GATE 44=3
-0.0102 mg/L peak-noisy
44=-4
peak-noisy
I GAT
-0.0183 mg/L
AV
AV
518.3 EM SD
-O.O094 mg/L SD
21.O CV
0.0081 CV
4.0
85.93
OO& . 1
cr267 EM
OO& . ±
cr267 EM
OO& . 1
cr267 EM
00& . ±
cr267 EM
cr267
1414
1402
1396
1508
AV 1430.0 EM
I GATE
0.3344 mg/L
REF>1_ I GATE
0.3298 mg/L
REF^L:
0.3275 mg/L
REF=>I_I
0.3705 mg/L
44= JL
1514 1O/19/98
SD
44=3
: **=-*
52.5 CV
-------
=HMK
cr267
cr267
cr267
cr267
3
cr267
3
cr267
3
cr267
3
cr267
cr267
cr267
cr267
cr267
cr267
EM
AV
EM
EM
EM
13968
13549.8 SD
REF>L_ I CftTE
587
R-EF>I_ I GATE
694
4*-1-
312.4 CV
4* ±
2.3 CONC 5.OOOO
1445 10/19/98
4*12
580
FSEF^L. I CftTI
=:«
=t*=-4-
O.OOOO
cr267 EM 552
cr267 AV 603.3 SD 62.4 CV 10.3 CONC
cr267 CC 0.9999 SLOPE 26O5.7290 INT 542.6687
4* ± 1447 1O/19/98
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
227
REF>1_ I GAT
1 .7977 mg/L
1 .8123 mg/L
-0.0191 mg/L
5353 1.8461 mg/L
5384 1 .8580 mg/L
AV 53O7.3 EM SD
AV 1.8285 mg/L SD
493
493
482 -0.0233 mg/L
REF>I_I
560 0.0067 mg/L
AV 507.0 EM SD
AV -O.O137 mg/L SD
-0.0191 mg/L
41=2:
E 4*-*
73.5 CV
0.0282 CV
1.4
1.54
4*=± 1449 1O/19/98
peak-noisy
4*2
peak-noisy
4*3
peak-noisy
4**4
peak-noisy
35.7 CV 7.O
0.0137 CV 100.12
OO3-Ol
cr267 EM
DOS-Ol
cr267 EM
DOS.01
cr267 EM
479
497
521
-0.0244 mg/L
REF>I_ I GATE
-0.0175 mg/L
FSEF>1_ I
-0.0083 mq/L
41= ± 1451 1O/19/98
peak-noisy
41=2
peak-noisy
4*3
-------
1A 400 Analysis Ver. 4.10 Mon 10/19/98 - 14:34:28
d File Name: CR
ks: CR ONLY
file is 1036
=HME>rf=*RD 4*1
cr267 EM
=HME>*=*RE> 4* 1
cr267 EM
^NDARD 4*1
cr267 EM
2fclMr>ARD 4* 1
cr267 EM
cr267 AV
2tlME>AR£> 4*2
cr267 EM
2IIMI3ARD 4*2
cr267 EM
=*IMD<=kRE> 4*2
cr267 EM
3fclMDARr> 4*2
cr267 EM
cr267 AV
=fclMD(ftRD 4*3
cr267 EM
2fcNDARE> 4*3
cr267 EM
=hMDARD 4*3
cr267 EM
^IMDARD 4*3
cr267 EM
cr267 AV
^NDARD 4*4
cr267 EM
*NZ>ARr> 4*4
cr267 EM
*ND*=kRr> 4*4
Repl icates:4
REF^L. I C*=»TE
819
733
738
g^fr >*""" B" '^ 1 TT rf""w ^N. "'B'" KI— 1!'
• ~^w • .. • *•• ^L. ^— r B^™1 • K^n L
742
758.0 SD 4O.8
3063
3043
REF=>I_ I Cl=kTE
2965
3123
3O4B.5 SD 65.2
6422
5739
5782
5498
5860.3 SD 394.8
REF>1_ I GATE
13437
REF*L_ I GATE
13568
REF^L. I CftTE
Read Delay: 65
Data File:
4*1 1437 10/19/98
4*2
4*3
peak-noisy
CV 5.4 CONC 0.10OO
4* 1 1439 10/19/98
4*2
*3
*-*
CV 2.1 CONC 1.0000
4*1 1441 10/19/98
4*2
4*3
4*4
CV 6.7 CONC 2.0000
4* 1 1443 10/19/98
4*2
4*3
-------
PERK1N-ELMER M 1100 98/10/15 PARE 15
AA AA
MAIN: 0.020 MG/L HO O.006 MAIN: 0.020 MG/L HO 0.006
CD "Z- MEArk 0,020 MG/L 3D: 0.000 RSD: 0.1
A A A A
MAIN: 0.018 M3/L HO O..005 MAIN: 0.018 MG/L HO 0.005
CD T~5} MEAN;: 0.018 MG/L BD: 0.000 RSD: 0,,8
AA AA
MAIN: 0.025 h'G/L HO 0.007 MAIN: 0.025 MG/L HO 0.007
MEAN: 0,. 025 MG/L SD: 0.000 RSD: 0.1
AA AA
MAIN: 0.511 MG/L HO 0.152 MAIN: 0.514 MG/L HO 0.153
CD « ^ MEAN: 0.513 MG/L SDs 0.002 RSD: 0.5
AA AA
MAIN: 0.005 MG/L. HO 0.. 002 MAIN: 0.005 MG/L HO 0.001
CD <"t>£ MEAN: 0.005 MG/L SD: 0.000 RSD: 7-0
-------
PERK IN" ELMER M 1100 98/10/15 PAGE 14
AA AA
MAIN; 0.016 MB/L. HO 0.005 MAIN: 0.017 MG/L HO 0.005
MEAN :•. 0 . 0 1 6 ME / L SD : 0 . 00 1 RSD : 7 . 0
AA AA
MAIN; 0.011. MG/L. HO 0.003 MA I is): 0.012 MB/L. HO O.003
CD MEAN.-, 0.011 MG/L SD: 0.001 RSD: 5.9
AA AA
M AIN:, 0 „ 4 9 9 M B / L H 0 0.148 MAIN: 0.5 0 0 MB/L HO 0.149
CD f("J MEAN: 0.500 MG/L BD: 0.001 RSD: 0.2
AA AA
MAIN; 0.001 MG/L HO 0.000 MAIN: 0.002 MG/L HO 0.001
CD xv (2 MEAN:; 0.002 MG/L SD: O.O01 RSD: 35.5
A A A A
MAIN: 0.030 MS/L HO 0.009 MAIN: 0.030 MB/L. HO 0.009
CD MEAN: 0,409 MG/L SD: 0.005 RSDr 1.1
-------
PLRKIN-LLMER M 11OO 9B/10/15 PAGE 11
AA AA
MAIN: 0.520 M6/L HO 0.155 MAIN: 0.524 MG/L HO 0.156
MEAN: O.522 MG/L. BD: 0.002 RSD: 0.5
AA AA
MAIN: 0.003 MG/L HO O.001 MAIN: 0.003 MG/L HO 0.001
CD /£ MEAN: 0,003 MG/L ED: 0.001 RSD: 22.1
AA AA
MAINs 0.004 MG/L HO O.001 MAIN: 0.003 MG/L HO 0.001
CD ~\ MEAN;; 0.021 MG/L BD: 0.000 RSD: 2.3
A A A A
MAIM:: 0.024 MG/L HO 0., 007 MAIN: 0.026 MG/L HO O.O08
CD 5-1--* MEANr O, 025 MG/L SD: 0.001 RSD: 3.9
-------
per::::::1: -ELMER
M 1100
MAIN: 0,001
AA
HO 0.001
98/10/15 PAGE
MAIN: 0.000
- AA
HQ-0.000
CD
MEAN:; 0.000
MAIN; 0.017
A A
HO 0.017
ED: 0.000 RSD: 80.4 AUTOZERO 0.000
MAIN! 0.016
AA
HO 0.016
CD MEAMt 0.016 BD: 0.000 RSD: 2.6 1.STANDARD 0.050 MG/L
AA
AA
MAIN: 0.097 MG/L HO 0.032 MAIN: O.098 MG/L HO 0.032
CD MEANs 0.098 MB/L BDs 0.001 RSDr 1.0 2.STANDARD 0.100 MG/L
AA
AA
MAIN: 0.197 MG/L HO 0., 063 MAIN: 0.199 MG/L HO 0.064
CD MEAN: 0.193 MG/L BD: 0.002 RSD: O.B 3.STANDARD 0.200 MG/L
A A
MAIN;: 0.477 MB/L HO 0.152.
AA
MAIN: 0.471 MG/L HO 0.150
CD MEAN; 0.474 MG/L BD: 0.005 RED; 1.0 4. STANDARD 0.495 MG/LJ
AA
AA
MAIN: 0.953 MG/L HO 0.291 MAIM: 0.974 MG/L HO 0.298 :
CD MEAN: 0.963 MG/L SDs 0.014 RSDr. 1.5 5. STANDARD 0.991 MG/L
FLAME DISPLAY CALIBRATION MODE
ELEMENT: CD
0.295
nBS.
PRINTER; ON
BS CORR: OFF
UNITS : MQ/L
0,991
fiBS. READING
S5 AA
0.298
Si
CONCENTRATION n •-•n/l_, (:;)> O.OOO RGJ"" 1,5 AU'rn7FRn O 000
-------
lean Cone luq/L
7.40
SD: 0.355
RSD(7.): 4.79
Je ID: B1006.3
teolicate 1
loncentrat ion (uq/'L
Sea. No,
): 7.51
-------
3e
ID: CCV
Jeolicate i
Concentration (ug/L ): 5.36
ieoiicate 2
Concentration (ug/'L ): 4.95
Sea, No.: OOO74 A/S Pos.
Times 19:04
Times 19s07
lean Cone (uq/L )
5.15
SD: 0.297
JC sample is within range 3.5 - 6.49
3e IDs CCB
teolicate 1
Concentration (uq/L ): 0.06
-------
e ID: ICV
BDlicate 1
oncentration iuo/L
Sea. No
i: 5.12
eolicate 2
oncemiratiDn IUQ/L J : b.Ol
ean Cone (ua/L )
5.O7
00055 A/S Pos.: 5
Time: 17:05
Time: 17:05
SD: 0.077
C sample is within range 3.5 - 6.49
e ID: ICB
eolicate i
oncentration vug/L ): 0.16
eoiicate 2
oncentration iua/L >: O.lt>
Sea. No.: 00056 A/S Pos.
Time: 17:11
Time: I/:14
ean Cone lua/L
0.16
SD: O.O02
C sample is within ranae -1.49 - 1.49
uco—zero oerTormea.
'V "v 'V 'V -i» '-v 'V "V 'V "^ '\» 'V ' v ' W '\f *V *V "W '
e ID: 8IO03.RB-AP
eolicate i
oncentration vug/L )
Dates 10/22/98
RSD (*/.): 1.51
Date: 10/22/98
RSD(X): 1.25
Sea. No.
. acate JL.
oncentration tug/L
iean Lone i ug/L )i
fe ID: 8LO03.RB-F
.'eolicate i
-O.O1
-0.02
-0.02
00057 A/S Pos,
Time: 17:17
Time: ±7:20
SD: O.OOS
14 Date: 1O/22/96
RSD C/.): 44 . 56
Sea. No.: 00058 A/S Pos.: 15 Date: 10/22/96
Time: 17:24
-------
Cone t ua/L ):
1.81
SD: O.O82
RSDC/.) : 4.f
tandard number 2 applied. C2.00]
urrelation coefficient: O.99891
Slope: O.0216
ID: 5 PPB
Sea. No.: OO053
solicate 1
eak Area (A-s): 0.100
ackqround Pk Area (A-s): 0.305
lank Corrected Pk Area (A-s): 0.103
Dncentration (ug/L )s 4.76
soiicate 2
eak Area (A-sj: 0.1O3
ackqround Pk Area (A-s)i 0.297
lank Corrected Pk Area (A-s): O.1O6
Dncentration iug/L ): 4.88
ean Cone (ua/L
4.82
tandard number 3 applied. C5.0O1
orrelation coefficient: O.99966
A/S Pos.: 3
Date: 10/2
Time: 16:49
Peak Height (A): O.255
Background Pk Height (A): 0.632
Time: 16:52
Peak Height (A): 0.250
Background Pk Height (A): O.630
SD: 0.085
Slope: 0.0210
RSDC/.): 1.;
' '\f 'V "\t -V 'W'V '
ID: 10 PPB
Sea. No.: OO054 A/S Pos.: 4
Date: 10/:
eolicate 1
eak Area (A-s)s O.173
ackqround Pk Area (A-s): 0.505
lank Corrected Pk Area (A-s): 0.176
Dncentration (ug/L ): 8.39
eolicate 2
eak Area (H-S): O.170
ackqround Pk Area (A-'s) : O.500
lank Corrected Pk Area (A-s): 0.173
oncentration (ua/L ): 8.23
ean Cone (ua/L );
8.31
tandard number 4 applied. [10.00]
orrelation coefficient: 0.99183
Time: 16:55
Peak Height (A)s 0.286
Background Pk Height (A): 1.139
Time: 16:58
Peak Height (A): O.268
Background Pk Height (A): 1.194
SDs 0.113
Slope: 0.0184
RSDC/.): 1,
-------
lement File: BE.GEL
ate: 10/22/98
ata File:
=chniaue: HGA
Element: Be
Time: 16:3O
ID/Wt File: 81013.IDW
Calib. Type: Linear
Wavelength: 234.9
Slit: 0.7 L
Lamp Current: 3O
Energy: 65
s ID: BLANK
=plicate L
=ak Area (A-s): —o.003
ackqround Pk Area (A-s)
lank Corrected Pk Area
Sea. No.: 00050
A/S Pos.: 0
Date: 10/22/98
Time: 16:30
Peak Height (A): 0.003
s O.550 Background Pk Height (A):
(A-s): -0.006
0.195
Dncentration (ug/L ): -0.37
sak Area i A-s i : -O.OO3
ackqround Pk Area (A-s): O.288
lank Corrected Pk Area (A-s): -O.OO6
ancentration (uq/L ): -0.36
Time : 16 : 33
Peak Height (A): O.OO2
Background Pk Height (A)
0.1O1
san Cone (ua/L ):
-O.37
5D: O.O05
RSD (*/.): 1. 39
jto-zero performed,
ID: O.5 PPB
Sea. No,
00051
A/S Pos.: 1
Date: 10/22/98
eolicate 1
eak Area (A-s): 0.008
ackground Pk Area (A-s): 0.180
lank Corrected Pk Area (A-s): 0.011
oncentration (ug/L ): 0.68
eoiicate 2
eaK Hrea (A-s): O.O10
ackground Pk Area (A-s): 0.149
lank Corrected Pk Area (A-s): 0.013
oncentration (ua/L ): O.79
Time: 16:36
Peak Height (A): 0.023
Background Pk Height (A): 0.122
Time: 16:4O
Peak Height (A): 0.029
Background Pk Height (A): O.121
ean Cone (ua/L
0.73
tandaro number 1 applied. [0.501
orrelation coefficient: l.OOOOO
SD: 0.079
Slope: 0.0237
RSDC/.): 10.74
ID: 2 PPB
Sea. No,
00052
A/S Pos.: 2
Date: 1O/22/96
eolicate 1
eak Area ii A-s): 0.039
ackaround Pk Area (A-s): 0.186
lank Corrected Pk Area (A-s): 0.042
oncentration (ug/L ): 1.76
epi j. care 2
eak Area iH-S>: 0.041
ackgrouno Pk Area (A-sj : 0.182
lank Corrected Pk Area (A-s): 0.044
oncentration (ug/L ): 1.87
Time: 16:43
Peak Height (A): 0.096
Background Pk Height (A): 0.245
Time: 16:46
Peak Height (A): 0.118
Background Pk Heignt (A): 0.276
-------
V
BA455
\S
BA455
V
BA455
BA455
BA455
EM
EM
EM
BA455
BA455
AV
AV
1508
1531
1501
AV
AV
847.3 EM
0.5955 mg/L
REF*!-
1.0810
SD
SD O.
mg/L
REF>t_ I CPkTE
1 .0979 mg/L
REF>I_
1 . 0759
1513.3 EM
1.0850 mg/L
. I Crf=fcTE
mg/L
SD
SD 0.
9.8 CV
OO72 CV
4* 1
4*2
4*3
15.7 CV
0115 CV
1.2
1.21
1242
l.O
1.O6
BA455
Ef
BA455
:JB
BA455
EM
EM
EM
BA455
BA455
4*±
1244 10/15/98
39
41
35
0.0014 mg/L
peak-noisy
0.0028 mg/L
AV
AV
-0.0016 mg/L
38.3 EM SD
O.OO09 mg/L SD
peak -noisy
4f=3
peak-noisy
3.1 CV
O.OO22 CV
8.O
255.78
-------
. DM 14- mg/ i
00&
BA455
00&
BA455
OO&
BA455
>
BA455
5
BA455
3
BA455
BA455
BA455
BA455
)
BA455
:>
BA455
y
BA455
BA455
Raa15;!^
BA455
BA455
_ 1
EM
. 1
EM
. 1
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
AV
AV
813
835
824
AV
AV
1841
1996
1899
AV
AV
1079
1024
1160
AV
AV
1 034
1058
1038
AV
AV
836
853
40.7 EM SD 1.5 CV
O.O026 mg/L SD 0.0011 CV
0.5702 mg/L
0.5864 mg/L
0.5783 mg/L
824.0 EM SD 11. 0 CV
0.5783 mg/L SD 0.0081 CV
1 .3258 mg/L
RE:F>L_ i c ATE: 4*2
1 .4397 mg/L
RE:F>I_ i GATE: 4*3
1.3684 mg/L
1912. O EM SD 78.3 CV
1.378O mg/L SD 0.0576 CV
REF>I_ i c ATE: 4*1
0.7657 mg/L
RE:I=-L_ i c ATE: 4*2
0.7253 mg/L
RER-L i GATE: 4*3
0.8253 mg/L
1O87.7 EM SD 68.4 CV
0.7721 mg/L SD 0.0503 CV
0.7327 mg/L
REIR-L- i GATE: 4*s
0.7503 mg/L
RER-L. i c ATE: 4*3
0.7356 mg/L
1043.3 EM SD 12.9 CV
0.7395 mg/L SD 0.0095 CV
REF^I — i CATE: 4* i
0.5871 mg/L
RE:F>L. i c ATE: 4*2
0.5996 mq/L
•::-noisy
3.8
43.30
1232 10/15/98
1.3
1.40
1234 10/15/98
4.1
4.18
1236 10/15/98
6.3
6.51
1238 10/15/98
1.2
1.28
1240 10/15/98
'f=-t=>t T t—£±-
-------
BA455 EM
BA455
BA455
54
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
BA455
EM
EM
BA455 EM
V
BA455 EM
BA455 EM
BA455
BA455
B
BA455 EM
B
BA455 EM
AV
AV
0.0124 mg/L
55.O EM SD
0.0131 mg/L SD
402
431
0.2682 mg/L
0.2895 mq/L
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
398 0 . 2652
AV 41O.3 EM
AV 0.2743 mg/L
523 0.3571
RER-L
536 0 . 3666
REF>1_
510 0.3475
AV 523.0 EM
AV 0.3571 mg/L
408 0 . 2726
455 0.3071
406 0.2711 •
AV 423.0 EM
AV 0.2836 mg/L
mg/L
SD
SD
ICf
mg/L
1C*:
mg/L
IC*=
mg/L
SD
SD
ICf
mg/L
IC*=
mg/L
ICrf=
mg/L
SD
SD
1515
1611
1 .0862 mg/L
1.1567 mg/L
RER-LI
1.0737 mg/L
1498
AV 1541.3 EM SD
AV 1.1055 mg/L SD
42
41
RSEF"L_ I
0.0036 mg/L
peak-noisy
l.O CV 1.8
O.OO07 CV 5.60
4*1 1221 1O/15/98
I 4*3
18.0 CV
O.O132 CV
•E 4*1
•E 4*2
13.0 CV
0.0096 CV
'E 4* 1
27.7 CV
0.02O4 CV
60.9 CV
0.0448 CV
=: 4*1
4.4
4.83
1223 1O/15/98
2.5
2.68
1225 10/15/98
6.6
7.19
1227 10/15/98
4.O
4.05
1230 10/15/98
I Crf=fcTE
0.0028 mg/L
peak-noisy
4*2
peak-noisy
-------
BPi455
BA455
BA455 CC
EM
AV
34
32.0 SD
5.3 CV
0.9999 SLOPE 1360.5981 INT
REF=-|_ I CftTE 4*±
16.5 CONC 0.0000
37.1389
1119 10/15/98
BA455
BA455
BA455
B
BA455
B
BA455
B
BA455
OO2
BA455
O02
BA455
002
BA455
1 X2
BA455
1 X2
BA455
1 X2
BA455
1 X2!
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
_ B— ±
EM
- B— 1
EM
• ^> •«
EM
BA455
BA455
EM
EM
EM
BA455
BA455
5
EM
1358 0.97OS mg/L
REF>1_ I CftTE 4*2
1360 0.9723 mg/L
REF=-|_ I GATE 4*3
1342 0.9590 mg/L
AV 1353.3 EM SD 9.9 CV 0.7
AV 0.9674 mg/L SD O.OO73 CV O.75
39 0.0014 mg/L peak-noisy
F>EF>I_ I CftTE 4*2
37 -0.0001 mg/L peak -noisy
34 -0.0023 mg/L peak-noisy
AV 36.7 EM SD 2.5 CV 6.9
AV -O.OO03 mg/L SD 0.0018 CV 532.91
RER-L- I C*=kTE 4* ± 1123
999 0.7069 mg/L
1O09 0.7143 mg/L
REF*!— I CftTE 4*3
1039 0.7363 mg/L
AV 1015.7 EM SD 2O.8 CV 2.O
AV 0.7192 mg/L SD 0.0153 CV 2.13
REF»l_ I CftTE 4*1 1125
572 0.3931 mg/L
REF>I_ I C*=*-TE 4*2
596 0.4107 mg/L
RER-L. I CftTE 4*3
584 0.4019 mg/L
AV 584.0 EM SD 12.0 CV 2.1
AV 0.4019 mg/L SD 0.0088 CV 2.19
REF>L_ I C^TE 4*± 1127
1330 0.9502 mg/L
1O/15/98
1O/15/98
1O/15/98
10/15/98
-------
A 400 Analysis Ver. 4.10 Thu 10/15/98 - 11:06:51
d File Name: BA
ks: BA ONLY
file is 10236
=hNr>ARD 4*1
BA455
=fclMDARr> 4* 1
BA455
=hlMDARD 4* ±
BA455
BA455
=kNDARI> 4*2
BA455
2klNlD*=tRD 4*2
BA455
2*MDARr> 4*2
BA455
BA455
21NDARD 4*3
BA455
:*NDARD 4*3
BA455
=fcMDARD 4*3
BA455
BA455
=*NDARE> 4*4
BA455
:»NDARD 4*4
BA455
=*|NlDARD 4*4
BA455
BA455
*NK
BA455
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
Repl icates:3 Read Delay: 65
Data File:
REF=-L_ X C ATE 4* A 11O8 1O/15/98
49
REF>L_ICATE 4*2
53
F5EF*1_ I C ATE 4*3
60 peak -noisy
54. 0 SD 5.6 CV 10.3 CONC 0.0200
REF*I_ICATE 4*1 1111 10/15/98
788
REF^L. I GATE 4*2
709
REF^U. I CATE 4*3
719
738.7 SD 43.0 CV 5.8 CONC 0.5000
REF>L_XCATE 4*1 1113 10/15/98
1410
REF^L I GATE 4*2
1360
REF=-L.ICATE 4*3
1420
1396.7 SD 32.1 CV 2.3 CONC 1.0000
REF>L_ I GATE 4*1 1115 10/15/98
2707
REF>L_ICATE 4*2
2803
REF31!— I GATE 4*3
2751
2753.7 SD 48.1 CV 1.7 CONC 2.0000
REF>I_ICATE 4*1 1117 10/15/98
36
BA4
EM
4*2
26
-------
3C sample is withan ranoe 79.50 - 120.49
'45 ID: CCB Sea. Mo.: 00141 A/S Pos. : 0 Date: 10/20/96
•ieoiicate i Time: 13:46
Concentration (ua/L ): 4.86
"eDi-icic= I Time: 13:50
joncentrataon IUQ/L ): 0.86
lean Cone iua./L ): 2. B4 SD: 2.824 RSD(7.): 98.81
QC sample is within ranae -5.49 - 5.49
-------
3C sample is within ranae -5.49 - 5.49
Vs ID: 81006.1x5
^eolicate i
Concentration (ua/L ): 56.87
;' e i' i i c a t e 2
Concentration iua/L ): 54.95
Sea. No.: 00136 A/S Pos.
Time: 13:14
Time: 13:17
28 Date: 10/20
lean Cone iua/L ):
55.91
SD: 1.355
RSD ('/.): 2.42
ID: 81006.1x5
'eolicate 1
Concentration iua/L J: 157.80
Concentration iua/L ): 157.70
'lean Cone (ua/L ): 157.75
Recovery is 1O1 ,8'/'.
Sea. Mo.: 00137 A/S Pos.
Time: 13:20
28 Date: 10/20
Times 13:24
SD : 0 . 074
RSDC/.) : 0.05
^•= ID: 81006.2x5 Sea. Mo,
-: 114.56
00140 A/S Pos.: 3
Time: 13:40
Time: 13:43
Date: 10/20
Cone i ua/L > :
111.2:
3D: 4.696
RSD (*/.): 4.22
-------
ID: 81003. 12 XC"
icate 1
Doncentrstion (ua/L ): 138.93
Sea. No.: 00131 A/S Pos.: 26
Time: 12:35
Date: 10/20/9E
tration (ua/L ): 188.76
'lean Cone (ua/L ): 163.63
Time: 12:39
SD: 35.236
RSD C/.): 21.51
;= ID: 31003.13*5
Concentration (ua/L ):
3-D 1 i ea te 2
Concentration tua/L
Cone (ua/L
Sea. No.: 00132 A/S Pos.: 27
Time: 12:42
12:45
Date: 10/20/95
/Time:
SD: 42.660
RSD C/.): 27-91
.. PL.. ••..«.., -\. f\. -\ . .-<.. •*..<%. n.t t\f r
Sea. No.: 00133 A/S Pos.: 27
Time: 12:49
Replicate 1
Concentration (ua/L ): 186.O6
"he •iianai is too iarae for the ranae OT the electronics.
Replicate 2 Time: 12:52
Concentration itio/L ):
Mean Cone iua.L ):
SD:
Date: 10/20/9!
RSD (7.):
ID: CCV
Sea. No.: 00134 A/S Pos.
Time: 13:01
Concentration (ua/L ): 103.60
1 fi O i i C 5 t =• —
Concentration iua/L ): 110.83
"ime: 13:04
Mean Cone iua/L ): 107.21 SD: 5.11o
OC samole is within ranae 79.50 - 120.49
-5 ID: CCB
Keolicate i
Concentration iua/L ): 7.84
"• c D I i C = t =• -
Concentration luo.'L j: 1.49
Sea. No.: 00135 A/S Pos.
Time: 13:07
Time: 13:11
0
Date: 10/20/9
RSDC/.): 4.77
Date: 1O/20/9
Mean Cone iua/L >:
4 .63
SD: 4.488
RSDC/.) : 96.19
-------
As ID: ICE
Reolicate 1
Concentration (ua/L ): 0.98
~ <= c- J i >- a t = 2
Concentration vua/L ): 3.21
5ea. No.: 00\\\
Time: 10:26
Time: 10:29
Mean Cone (ua/L ): 2.09 SD : 1.576
QC sample is within range -5.49 - 5.49
As ID-, 81003.RB-AP
Replicate 1
Concentration' (ua/L ): 3.39
s» 11 \ i '_:a te 2.
Concentration (ua/L ): O.24
Sea. No.: 00112 A/S Pos
Time: 1O:32
T lme: 1O:35
RSD(7.)i 75.
14 Date: 10/2
Mean Cone (ua/L
1 .31
3D: 2.234
R5D (V.): 123
As ID: SIO03.RB-P
Reeli cate 1
Concentration (ua/L ): -0.48
" = D i i cate 2
Concentration (ua/L ') : -3.37
Sea. Mo.: 00113 A/S Pos
Time: 10:39
Time: 1O:42
15 Date: 10/A
Mean Cone tua/L );
-i .9:
SD: 2.04B
As ID: B1O03.0B
Reolicate 1
Concentration (ua/L )s O.75
s e o J i c a t e 2
Concentration \ua/L ): 3.06
Sea. Mo.: O0114 A/S Pos
Time: 1O:45
Time: 10:48
Mean Cone (ua/L ):
1.90
SD: 1.635
R5D <•/.): 106
16 Date: 10/1
RSDC/l): 85
As ID: 81O03.UB
Reolicate 1
Concentration (ua/L
Sea. No.
): 3.46
Concentration (ua/L )s 0.78
00115 A/S Pos,
Time: 10:51
Time: 10:5^
17 Date: 10/1
Mean Cone (ua/L ):
2.11
SD: 1.B94
RSD ( V.) •. 89
-------
Mean Cone ( ua./L ) :
51 -95
3D: 6.724
RSD (*/.): 12.94
Standard number 2 applied. T5O.OO]
Correlation coefficient: 0.99999 Slooe: 0.0029
i^MDispiay Calibration - C;\HH ilSl!
10. 4J-,
1
l
1
1
! r •
1 a
1
1
^E«
„.*••"
.^*" "~"
.^'-^
t! C-^ricsritK'Trion eOC.Cfi
!
*
i
Display Data - C;\ftft USERXftA FILES\ELB1ENT\
J-J < yy ug/L Mean
QC sanple is within range 79,50 - 120,49
Nd
St
3 F
t
F
Atonic Signal
Background Signai
Repi. 2
Kean:
of 2
183,06
Area: 0,239 A-s
Area: 8,103 A-s
Cone, 101.19 ug/L
SO: 2,646
Heis
Heig
-------
Mean Cone f ua/L ):
.32
SD: 7.451
RSD ('/.): 19.
Standard number 2 applied. r5O.OO1
Correlation coefficient: 0.99324
Slooe: O.OO21
ID; 100 PPB AS
Sea, No.: 00107
Replicate 1
Peak Area (A-s): 0.232
Background Pk Area tA-s)5 0.120
Blank Corrected Pk Area (A-s): 0.234
Concentration (ua/L ): 109-75
•_ e* T- 4? j.
Peak Area (A-s): 0.23?
Backaround Pk Area (A-s): 0.114
Blank Corrected Pk Area (A-s): O.241
Concentration (ua/L ): 113.04
Mean Cone !ua/L ):
111.40
Standard number 3 applied. [10O.OO]
Correlation coefficient: O.99591
A/5 Pos. : 3
Date: 10/2
Time: 09:49
Peak Heiaht (A): 0.362
Backaround Pk Heiaht (A): 0.085
Time: 09:53
Peak Heiaht (A): 0.428
Background Pk Height (A): 0.084
3D: 2.326
Slope: 0.0023
RSD ('/.): 2.0'
ID: 20O PPB AS
Sea. Mo -
Replicate 1
Peak Area (A-s): 0.429
Backaround Pk Area (A-s): 0.121
Blank Corrected Pk Area (A-s): 0.431
Concentration (ug/L ): 185.23
Area (A-s): O.449
Backaround Pk Area (A-s): 0.121
Blank Corrected Pk Area (A-s): O.451
Concentration (ua/L ): 194.04
Mean Cone (ua/L ):
189.64
Standard number 4 applied. T20O.OO]
Correlation coefficient: 0.99849
00108
A/S Pos.: 4
Date: 10/2
Time: 09:56
Peak Height (A): 0.723
Backaround Pk Height (A): 0.070
Time: O9:59
Peak Heiaht (A): O.73B
Background Pk Height (A): O.O79
SD: 6.233
Slope: 0.0022
RSD ('/.): 3.2
ID: ,50 PPB AS
Sea. Mo.: OO109
Replicate 1
Peak Area (A-s): 0.138
Backaround Pk Area (A-s): 0.100
Blank. Corrected Pk Area (A-s): 0.139
Concentration (ug/L ): 56.73
Peak Area (A-s): 0.115
Eackaround Pk Area (A-s): O.O94
Blank Corrected Pk Area (A-s): 0.117
Concentration (ua/L ): 47.22
A/S Pos. : 2
Date: 10/2
Time: 10:09
Peak Height (A): O.222
Backaround Pk Heiaht (A): 0.068
Time: 10:12
Peak Height (A): 0.199
Backaround Pk Heiaht (A): 0.064
-------
Element File: AS.GEL
Date: 10/20/78
Data File:
Technioue: HGA
Element: As
Time: 09:30
ID/Wt File: 81002.IDW
Calib. TYDE: Linear
Wavelength: 1^3.7
Slit: 0.70 L
Lamp Current: 0
Enerov: 33
A 5
ID: BLANK
Replicate 1
Peak Area (A-5): O.OO7
Backaround Pk Area (A-s)
Blank Corrected Pk Area
Concentration (uq/L ):
Sea. Mo
: 0.135
(A-s): O.OO6
2.60
Ren lies te 2
Peak Area (A-s): -0.010
Backaround Pk Area (A-s): 0.130
Blank Corrected Pk Area (A-s): -0.010
Concentration (ua/L ): -4.07
00104
A/S Pos.: 0
Date: 10/20/9
Time: 09:30
Peak. Height (A): 0.040
Background Pk Height (A): 0.149
Time: 09:33
Peak Height (A): 0.039
Backaround Pk. Height (A):
0.119
Mean Cone (ua/L ):
Auto-zero oerformed.
-O. 74
SD: 4.715
RSD(7.): 639.OZ
ID: 10 PPB AS
Sea- Mo,
00105
A/S Pos.: 1
Date: 10/2Q/C
Replicate 1
Peak Area (A-s): O.O26
Backaround Pk. Area (A-s): 0.129
Blank. Corrected Pk Area (A-s): 0.02S
Concentration (ua/L ): 11.24
Time: 09:36
Peak Height (A): 0.057
Backaround Pk Heiaht (A): 0.10O
Peak Area (A-s): 0.026
Backaround Pk Area (A-s): 0.114
Blank Corrected Pk Area (A-s): 0.028
Concentration (ua/L ): 11.26
Mean Cone (ua/L
11.25
Time: 09:40
Peak Height (A): 0.047
Backaround Pk Heiaht (A): O.O96
SD: 0.012
RSD<7.): O.ll
Standard number 1 applied. [10.O01
Correlation coefficient: 1.OOOOO
Slope: O.002B
ID:
AS
Sea. Mo,
Reali cate 1
Peak. Area (A-s): 0.118
Backaround Pk Area (A-s): O.105
Blank Corrected Pk Area (A-s): 0.119
Concentration (ua/L ): 42.59
00106
A/S Pos.: 2
Date: 10/20/
Time: 09:43
Peak Height (A): 0.208
Backaround Pk. Heiaht (A): O.O94
Peal, Area (A-s): 0.088
Backaround Pk Area (A-s): 0.119
Blank Corrected Pk Area (A-s): 0.090
Concentration (ug/L ): 32.05
rime: 09:46
Peak Height (A): 0.175
Backaround Pk. Heiaht (A): 0.112
-------
>, TD: CCB Sea. No.: 00193 A/S Pas.: 0 Date: 10/1!
!eolicate 1 Time: 14:59
Concentration (ua/L ): -6.7
:=>n1 i.-ats 2 Time: 15:02
Concentration (ua/L, ): -5.1
lean Cone
-------
ib ID: 81006.1 Sea. No.: 00188 A/S Pos.: 28 Date: 10/15/9E
tedicate 1 Time: 14:26
Toncentration (ua/L ): 0.4
3«=dicate ~ Time: 14:30
Concentration (ua/L ): 6.0
lean Cone (ua/L ): 3.2 SD: 3.97 RSD (7.): 122.53
~b ID: 81006.1 Sea. Mo.: 001B9 A/S Pos.: 28 Date: 10/15/9!
Dedicate 1 Time: 14:33
Concentration (uo/L ): 100.3
if?1icste 2 Time: 14:36
ronrentration iua/L ): 102.8
Mean Cone (ua/L ): 101.5 SD: 1.82 RSD (7.) : 1.79
Recovery is 98.37.
- --
!_» =>
r> - j. _ i ,-\ ' < c: -
U d t e ; i '.' - L .'.•
"-...- . ; -",.'_ SD: 0.63 RSD (7.) : 19.58
";h ID: 81006.3 Sea. Mo.: 00191 A/S Pos.: 30 Date: 10/15/9
Redicate 1 Time: 14:46
Concentration (ua/L ): 0.7
^oniicate 2 Time: 14:49
Concentration (ua/'L ): 0.6
Mean Cone (ua/L ^: 0.6 SD: 0.08 RSD (7.): 13.33
"V *V *\* *V *V 'V *V *V ""W 'v *\< *^* *V *V* 'V *%* 'V ^* *V 'V '^ *\* '\* *V *V *V *V ^/ *\J *V 'V ^* *\* *V *W *i/ *V *^« *V *^ *^» *^ *V* ^* *^ *V *V 'V 'X* *\f ^« *V *\* ^* *\* *\* *\* *V *V *\» ^* *\* ^* ^* ^* ^* ^/ *\* A* *\* *N< *V ^* *\* *\» ^» ^*
^b ID: CCV Sea. No.: 00192 A/S Pos.: 3 Date: 10/15/9
Reolicate 1 Time: 14:52
Concentration (uq/L ): 98.8
= = nl irate 2 Time': 14:56
Concentration (ua/L ): 103.1
Mean Cone (ua/L >: 101.0 SD: 3.07 RSD(7.): 3.04
QC samole is within ranae 79.5 - 120.49
-------
25 Date: 10/15/
?b ID: 81.003.11
?eolicate 1
Concentration (uq/L ); 46.4
?"=>Dl i cate 2
Concentration (ua/L ): 38.8
Sea. No.
lean Cone (ua/L ):
42.6
00183 A/S Pos,
Time: 13:54
Time: 13:57
SD: 5.39
RSDC7.): 12.6!
ID: 81003,I 2
Sea. No
Concentration (uq/L ): 36.0
Concentration fuo/L ): 38.3
vlean Cone (ua/L ): 37.2
OO184 A/S Pos,
Time: 14s01
Time: 14:04
SD: 1.65
26 Date: 10/15,
RSD (•/.): 4.44
27 Date: 10/15
TD: 81003.13
icate 1
Concentration (ua/L
Concentration (ua/L
Cone (ua/L )
Sea. No,
)s 38.1
): 29.2
33.7
OO1B5 A/S Pos,
Time: 14;07
Time: 14:10
SD: 6,29
RSD(7.) : IB.6
^b TD: CCV
Reolicate 1
Concentration (ua/L ): 106.3
Sea. No.: 00186 A/S Pos.
Time: 14;14
Time: 14:17
Concentration I'ua/L ): 115.8
Mean Cone (ua/L ): 111.0
SD: 6.72
QC sample is within ranae 79.5 - 120.49
Date: 10/15
RSDC/.): 6.05
Reeli cate 1
Concentration (ua/L ): 0.2
Sea. Mo.: 00187 A/S Pos.
Time: 14:20
T ime: 14:23
Concentration (uo/L ): -11.5
-lean Cone ILIQ/L i: -5.7 SD: B.29
QC sample is within ranqe -15.49 - 15.49
Date: 10/15
RSDC/.): 146.
-------
Sb ID: IC^V Sea. No.: 00153 A/S Pos . : 5 Date: 10/15/9;
ReDlicate i Time: 10:38
Concentration (uo/L ): 100.5
Replicate 2 Time: 10:41
Concentration (ua/'L ): 94.1
Mean Cone (ua/L ): 97.3 SD : 4.54 RSD (*/.): 4.67
QC sample is within range 79.5 - 120.49
I
Rh TD: ICE Sea. No.: 00154 A/S Pos.: O Date: 10/15/9
ReDlicate 1 Time: 10:45
Concentration (ua/L ) : 4.6
2 Time: 10:4B
Concentration (ua/L ): 1.8
Mean Cone (ua/L ): 3.2 SD: 1.95 RSD (7.): 61. OO
QC samole is within ranqe -15.49 - 15.49
Rb ID: 81002. B-l Sea. No.: 00155 A/S Pos.: 6 Date: 10/15/9'
Reolicate 1 Time: 10:51
Concentration (ua/L ): 2.1
Peolicate 2 Time: 10:54
Concentration (ua/L ): -4.1
Mean Cone (ua/L ): -1.0 SD : 4.36 RSD(7.): 430.91
Rb TD: 81.0O2.8-1 Sea. No.: 00156 A/S Pos.: 7 Date: 10/15/9
Replicate 1 Time: 10:58
Concentration (ua/L ): -0.3
9e>c3H rats I Time: 11:01
Concentration (ua/L ): 4.8
Mean Cone (ua/L ): 2.3 SD : 3.63 RSD(7.)s 159.04
Sb TD: S10O2.8-1 Sea. No.: 00157 A/S Pos.: 7 Date: 10/15/9
ReDlicate 1 Time: 11:04
Concentration (ua/L ): 94.9
Rpolicate 2 Time: 11:08
Concentration »ua/L ): 104.6
Mean Cone (ua/L ): *?9 .7 SD : 6.85 RSD(7.)t 6. 86
-------
Calibration - C:\ftfl USER
iricantr otlori
SEC.D
-------
lean Con c ( LIQ/L
50.7
SD: 0.73
RSD C/.): 1.44
Standard number 2 applied. [50.0]
lorrelation coefficient: O.99999
Slooe: 0.0016
ID: 100 PPB
Sea. Mo.: 00151 A/S Pos.: 3
Dedicate 1
= eak Area (A-s): 0.153
Backaround Pk Area (A-s): 0.143
Blank Corrected Pk Area (A-s): 0.150
Concentration (ug/L ): 93.2
'eolicate 2
=eak Area (A-s ) : 0.159
3ack.qroi.ind Pk Area (A-s): 0.136
Blank Corrected Pk Area (A-s): 0.155
Concentration (uo/L ): 96.4
lean Cone ( ua/L
94 .8
Date: 10/15/9E
Time: 10:22
Peak Height (A): 0.220
Background Pk Height (A): 0.087
T ime: 10:25
Peak Height (A): 0.241
Backaround Pk Height (A): O.O72
SD: 2.26
RSD (7.) : 2.38
Standard number 3 applied. T1OO.O]
Correlation coefficient: O.99925
Slope: O.0015
ID: 200 PPB
Sen. No,
Replicate 1
Peak Area (A-s) : 0.291
Backaround Pk Area (A-s): 0.151
Blank Corrected Pk Area (A-s): 0.288
Concentration (ug/L ): 186.4
icate 2
Peak Area (A-s): 0.285
Backaround Pk Area (A-s): 0.152
Blank Corrected Pk Area (A-s): 0.281
Concentration (ua/L ): 182.0
Mean Cone ( ua/L
184.2
00152
A/S Pos.: 4
Date: 10/15/9
Time: 1O:28
Peak Height (A): 0.396
Backaround Pk Height (A): 0.078
Time: 1O:32
Peak Height (A): 0.396
Backaround Pk Heiaht (A): O.081
SD: 3.07
RSD C/.): 1.67
Standard number 4 applied. [200.01
Correlation coefficient: 0.99817
Slope: 0.0015
-------
ri 1. e : 1 O .-' i 5 •-' 98
ata File:
echniaue: HGA
Element: Sb
Time: 10:00
ID/Wt File: S1002.IDW
Calib. Type: Linear
Wavelength: 217,
Slit: 0.7 L
Lamp Current: 0
Energy: 38
ID: BLANK
Sea. No.: OO14B
A/S Pos.
O
Date: 10/15,
eo1icate i
'eak Area (A-s): 0.010
lackoround Pk Area (A-s): 0.127
Hank Corrected Pk Area (A-s): -0.000
,'oncentration (ua/L ): -0.1
Time: 10:02
Peak Height (A): 0.020
Background Pk Height (A)
O.OB2
!eol icate 2
!eak Area (A-s): -0.004
lackoround Pk Area (A-s): 0.138
Hank Corrected Pk. Area (A-s): -0.014
.'oncentration (ua/L ): -9.1
lean Cone (ua/L )
-4.6
Time: 10:06
Peak Height (A): 0.018
Backoround Pk Heiaht (A): O.088
SD: 6.35
RSDr/.): 139.
*uto-zero performed.
5b
TD: !'"' PPB
Sea. No.: 00149
A/S Pos.s 1
Date: 10/15
!eo1i cate 1
:eak Area (A-s): 0.024
Jackaround Pk Area (A-s): 0.123
31ank Corrected Pk Area (A-s): 0.021
Concentration (ua/L ): 12.9
Time: 10:09
Peak Height (A): 0.040
Background Pk Height (A): 0.083
5 f? D 1 i c a t e 2
3eak Area (A-=): 0.014
3ackoround Pk Area (A-s): 0.134
Blank Corrected Pk Area (A-s): 0.011
Concentration (ua/L ): 7.0
Time: 10:12
Peak Height (A): 0.035
Background Pk Heiaht (A)
O.073
'lean Cone i ua/L )
9-9
SD: 4.20
RSDC/.): 42.3
Standard number 1 applied. [10.0]
Correlation coefficient: l.OOOOO
Slope: 0.0016
ID: 50 PPB
Sea. No,
00150
A/S Pos.: 2
Date: 10/15'
?eolicate i
3eak Area (A-s): 0.083
Backaround Pk Area (A-s): 0.129
Blank Corrected Pk Area (A-s): 0.080
Concentration (ua/L ): 50.2
Time: 10:15
Peak Height (A): 0.127
Background Pk Height (A): 0.078
= <=nlicate 2
3eak Area (A-s): 0.085
BackoroLind Pk Area (A-s): 0.136
Blank Corrected Pk Area (A-s): 0.081
loncentration (ug/L ): 51.2
Time: 10:19
Peak Height (A): 0.130
Background Pk Height (A): 0.075
-------
Element File: AS.GEL
Date: 1O/20/98
Data File:
Technioue: HGA
Element: As
Time: 09:30
ID/Wt File: 81002.IDW
Calib. Tyoe: Linear
Wavelength: 193.7
Slit: O.~70 L
Larno Current: O
Enerav: 33
A=
ID: BLANK
Reali cate 1
Peak Area (A-s): O.OO7
Backaround PR Area (A-s)
Blank Corrected Pk Area
Concentration (ua/L ):
Sea. Mo.: 00104
: 0.135
(A-s): O.006
2.60
A/S Pos.: 0
Date: 10/20/9
Time: 09:30
Peak Heiqht (A): 0.040
Background Pk. Height (A): 0.149
R=DlicstB 2
Peak. Area (A-s): -0.010
Backaround Pk Area (A-s): O.130
Blank Corrected Pk Area (A-s): -0.010
Concentration (ua/L ): -4.07
Time: 09:33
Peak Height (A): 0.039
Backaround Pk. Heiaht (A): 0.119
Mean Cone (ua/L ):
Auto-zero performed.
-0.74
SD: 4.715
RSD ('/.): 639.0;
a 5
ID: 10 PPB AS
Sea. Mo,
00105
A/S POB.: 1
Date: 10/20/S
Reolicate 1
Peak Area (A-s): O.O26
Backaround Pk Area (A-s): 0.129
Blank. Corrected Pk Area (A-s): 0.028
Concentration (ug/L ): 11.24
"SD1i cate 2
Peak Area (A-s): 0.026
Backaround Pk Area (A-s): O.114
Blank Corrected Pk Area (A-s): 0.028
Concentration (ua/L ): 11.26
lean Cone (ua/L
11
Standard number 1 aoolied. f.lO.00]
Correlation coefficient: 1.OOOOO
Time: 09:36
Peak Height (A): O.057
Backaround Pk Heiaht (A): 0.10O
Time: 09:40
Peak Height (A): O.047
Backaround Pk Heiaht (A): 0.096
SD: 0.012
Slooe: O.OO2B
RSD (7.): 0.11
ID: 50 PPB AS
Sea. No,
Reolicate 1
Peak Area (A-s): 0.118
Backaround Pk Area (A-s): O.1O5
Blank Corrected Pk Area (A-s): 0.119
Concentration (ua/L ): 42.59
HSDiicats 2
Peat' Area CA-e): 0.088
Backaround Pk Area (A-s): O.119
Blank Corrected Pk Area (A-s): O.090
Concentration (ug/L ): 32.05
00106
A/S Pos.:
Date: 10/20/c
Time: 09:43
Peak Height (A): 0.208
Background Pk Height (A): 0.094
rime: 09:46
Peak. Height (A) : 0.175
Background Pk Height (A): 0.112
-------
t- TD: CCB Sea. Mo.: 00193 A/S Pos. : 0 Date: 10/15,
eolicate 1 Time: 14:59
oncentration (ua/L ): -6.7
= n1 ic-ats 2 Time: 15:02
oncentration (uo/L ): -5.1
iean Cone fuo/L ): -5.9 SD: 1.12 RSDC/.): 18.£
1C samole is within ranoe -15.49 - 15.49
-------
b ID: 81O06.1 Sea. No.: 00188 A/S Pos.: 28 Date: 10/15/98
:eolicate 1 Time: 14:26
ioncentration iua/L ): 0.4
j=o]icr
-------
Sea. No.: 00183 A/S Pos.: 25 Date: 10/15,
Time: 13:54
Time: 13:57
b ID: 81.003.11
eoli cate 1
oncentration (uq/L ): 46.4
<=>ol i cate 2
oncentration (uq/L ): 38.8
-------
=b TD: ICV Sea. No.: 00153 A/S Pos.: 5 Date: 10/15/9
Replicate 1 Time: 10:38
Concentration (ua/L ): 100.5
isolicate 2 Time: 10:41
Concentration i'ua/L ): 94.1
lean Cone (ua/L ): 97.3 SD: 4.54 RSD(7.): 4.67
QC sample is within range 79.5 - 120.49
t
V *W *V 'V ''v *V *V ^/ 'V *\* ^ *\* 'V "v 'v *V ^< *V *V 'x, *v *V 'V* *V 'V *V *V *V *V *V *\* *^ *V 'V *\/ *V 'w *\^ *\/ ^ **t f\f *w ^» 'V *V *V *V *V *\/ *\* *V ^V *V *V *V *V *V ^ *V *V *V *V *V *\* *\» 'V *V *V *V *V *V *V *V *V* *^<
^h TD: ICE Sea. No.: 00154 A/S Pos.: 0 Date: 10/15/9
^eolicate 1 Time: 10:45
Concentration (ua/L '): 4.6
~.p=olic3te 2 Time: 10:46
Concentration (ua/L ): 1.8
Mean Cone (ug/L ): 3.2 SD: 1.95 RSD(7.): 61.00
QC sample is within range -15.49 - 15.49
Rb ID: 81002.B-l Sea. No.: 00155 A/S Pos.: 6 Date: 10/15/9
Reolicate 1 Time: 10:51
Concentration (ua/L ): 2.1
Peolicate 2 Time: 10:54
Concentration (ua/L ): -4.1
Mean Cone (ua/L ): -1.0 SD: 4..36 RSD(7.): 430.91
cb TD: eioo^.a-l Sea. No.: 00156 A/S Pos.: 7 Date: 1O/15/9
Replicate 1 Time: 10:58
Concentration (ua/L ): -0.3
9=o1irate ~ Time: 11:01
Concentration (ua/L ): 4.8
Mean Cone (ua/L ): 2.3 SD: 3.63 RSD(7.): 159.04
Rb TD: 81002.8-1 Sea. No.: 00157 A/S Pos.: 7 Date: 10/15/9
Reolicate 1 Time: I1:O4
Concentration (ua/L ): 94.9
Rpolicate 2 Time: 11:08
Concentration (ua/L ): 104.6
Mean Cone (ua/L ) :
99.7 SD: 6.85 RSD(7.): 6.96
-------
* Display Calibration - C%.\flft
.EU4
I
(X
IS I
3.3
2CC.D
-------
•lean Cone (ug/L ) :
50.7
SD: 0.73
RSDC/.): 1.44
Standard number 2 applied. [50.0]
lorrelation coefiicient: 0.99999
Slope: 0.0016
ID: LOO PPB
Sea. Mo
=eak Area ( A-s ) : 0.153
3ackaround Pk Area (A-s): 0.143
Blank Corrected Pk Area (A-s): 0.150
Concentration (ug/L ): 93.2
^SD 1 i cate 2
Peak Area (A-s): O . 1 59
Background Pk Area (A-s): 0.136
Blank Corrected Pk Area (A-s): 0.155
Concentration (uo/L ): 96.4
00151
A/S Pos.: 3
Date: 10/15/9E
Time: 10:22
Peak Heiaht (A): 0.220
Background Pk Height (A): 0.087
Time: 10:25
Peak Height (A): 0.241
Background Pk Heiaht (A): 0.072
Mean Cone (ua/L ):
94.8
Standard number 3 applied. [100.0]
Correlation coefficient: 0.99925
SD: 2.26
Slope: 0.0015
RSD C/.): 2. 38
Sb
TD: 200 PPB
Sea. No.
Reolicate 1
Peak Area (A-s): O.291
•Backaround Pk Area (A-s): 0.151
Blank Corrected Pk Area (A-s): 0.288
Concentration (ug/L ) : 186.4
icate 2
Peak Area (A-s): 0.285
Background Pk Area (A-s): 0.152
Blank Corrected Pk Area (A-s): 0.281
Concentration (ua/L ): 182.0
Mean Cone (ug/L ):
184.2
Standard number 4 applied. [200.0]
Correlation coefficient: 0.99817
00152
A/S Pos.: 4
Date: 10/15/9
Time: 10:28
Peak Height (A): 0.396
Background Pk Height (A): 0.078
Time: 10:32
Peak Height (A): 0.396
Background Pk Height (A): O.OS1
SD: 3.07
Slope: 0.0015
RSDC/.): 1.67
-------
H !. e: lO/iL'i/^Q
ata File:
echniaue: HGA
Element: Sb
Time: 10:00
ID/Wt File: 81OO2.IDW
Calib. Type: Linear
Wavelength: 217,
Slit: 0.7 L
Lamo Current: 0
Energy: 38
b
eD 1
TD: BLANK
icate 1
5ea. No. : 00148
Time :
A/S Pos. : O
10: 02
Date: 10/15
:eak Area (A-s): 0.010
lackground Pk Area (A-s): 0.127
Hank Corrected Pk Area (A-s): -0.000
Concentration (ug/L ): -0.1
;eo 1 icate 2
!eak Area (A-s): -O.O04
Jackaround Pk Area (A-s): 0.138
Jlank Corrected Pk. Area (A-s): -O.014
Concentration (ua/L )s -9.1
Peak. Height (A): O.O20
Background Pk Height (A): 0.082
Time: 1O:06
Peak Height (A): 0.018
Backaround Pk Heiaht (A): O.O88
lean Cone (ua/L )
-4,6
SD: 6.35
RSD(%): 139
^uto-zero performed.
TD: K> PPB
Sea. No.: 00149
A/S Pos.
Date: 10/1
i cate 1
= eak Area (A-s): 0.024
3ackaround Pk Area (A-s): 0.123
31ank Corrected Pk Area (A-s): 0.021
loncentration (ua/L ): 12.9
~eolicats 2
~eak Area (A-s): 0.014
Backaround Pk Area (A-s): O.134
Blank Corrected Pk Area (A-s): 0.011
Concentration (ua/L ): 7.0
Mean Cone (ua/L
9.9
Standard number 1 applied. f.10.0]
Correlation coefficient: 1.00000
Time: 1O-.O9
Peak Height (A): 0.040
Background Pk Height (A)
0.083
Time: 10:12
Peak Height (A): 0.035
Background Pk Height (A): 0.073
SD: 4.20
Slope: 0.0016
RSD C/.): 42.
ID: 50 PPB
Sea. No.: 00150
Realicate 1
Peak Area (A-s): 0.083
Backaround Pk Area (A-s): 0.129
Blank. Corrected Pk Area (A-s): 0.080
Concentration (ua/L ): 50.2
A/S Pos.: 2
Date: 10/1
Time: 10:15
Peak Height (A): 0.127
Background Pk Height (A): 0.078
"enlicate 2
Peak Area (A-s): 0.085
Backaround Pk Area (A-s): 0.136
Blank Corrected Pk Area (A-s): 0.081
Concentration (ua/L ): 51.2
Time: 10:19
Peak Height (A): 0.130
Backaround Pk Heiaht (A)
0.075
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-002a
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Final Report - Emissions Testing of Combustion Stack and Pushing Operations at Coke
Battery No. 5/6 at ABC Coke in Birmingham, Alabama
Volume I of III
5. REPORT DATE
February 1999
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Franklin Meadows
Daniel F. Scheffel
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98-004
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating the coke making industry to characterize hazardous air pollutants (HAPs)
emitted from coke pushing operations and combustion (underfire) stacks. This test report addresses pushing emissions from a coke oven, and emissions
from the combustion (underfire) stack that serves Coke Battery No. 5/6 at ABC Coke in Birmingham, Alabama. The purpose of this test program was to
quantify emissions from the inlet and outlet of the baghouse controlling emissions from the coke pushing operation and to quantify emissions from the
combustion outlet stack. The data may be used by the EPA in the future to support a residual risk
assessment for coke oven facilities.
The testing was performed to quantify uncontrolled and controlled air emissions of filterable paniculate matter (PM), methylene chloride extractable
matter (MCEM) and 19 polycyclic aromatic hydrocarbons (PAHs) including acenaphthene, acenaphthylene, anthracene, benzo(a)anthracene,
benzo(a)pyrene, benzo(b)fluoranthene, benzo(e)pyrene, benzo(k)fluoranthene, benzo(ghi)perylene, chrysene, dibenzo(a,h)anthracene, fluoranthene,
fluorene, indeno(l,2,3-cd)pyrene, 2-methylnapthalene, napthalene, perylene, phenanthrene, and pyrene. In addition, following the PM and MCEM
analyses, the samples were analyzed to screen for the presence of 17 trace metals. Baghouse dust samples were also collected and analyzed for 16 trace
metals. Simultaneous testing was performed at the inlet and outlet of the baghouse controlling emissions from the coke pushing operation. Sampling
was also performed on the combustion outlet stack. In addition to pollutant testing, oxygen (O2) and carbon dioxide (CO2) were measured at each
location. During the sampling program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission
control system operating parameters.
This volume (Volume I) is comprised of 542 pages and consists of the report text, and Appendices: A (Process Data), B (Raw field Data), and C
(Analytical Data except CARS 429).
17.
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
b. IDENTIFIERS/OPEN ENDED TERMS
c. COASTI Field/Group
Baghouse
Coke Ovens
Emission Measurements
Hazardous Air Pollutants
Metals
Methylene Chloride Extractable
Matter
Paniculate Matter
Polycyclic Aromatic Hydrocarbons
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (This Report)
Unclassified
Unlimited
21. NO. OF PAGES
1647
20. SECURITY CLASS (This page)
Unclassified
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6.1
------- |