United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-002b
February 1999
AIR
SEPA
Final Report - Volume II of
Emissions Testing of Combustion
Stack and Pushing Operations at
Coke Battery No. 5/6 at ABC Coke
in Birmingham, Alabama
-------
FINAL REPORT
EMISSIONS TESTING OF COMBUSTION STACK AND
COKE PUSHING OPERATIONS AT COKE BATTERY NO. 5/6
AT ABC COKE
IN BIRMINGHAM, ALABAMA
Volume II
Appendix D
EPA Contract No. 68-D-98-004
Work Assignment No. 2-02
Prepared for:
JohnC. Bosch, Jr. (MD-19)
Work Assignment Manager
SCGA, EMC, EMAD, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
February 1999
p:\s512.000\fmrpt.wpd
Submitted by:
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919)941-0333 FAX (919) 941-0234
-------
DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D98004, Work Assignment No. 2-02. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.
11
-------
TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 FILTERABLE PARTICULATE MATTER, METHYLENE CHLORIDE
EXTRACTABLE MATTER (MCEM), AND METALS 2-1
2.3 POLYCYCLIC AROMATIC HYDROCARBONS (PAHs) 2-27
2.4 NON-PUSHING AND NON-CHARGING COKE OVEN BATTERY
OPERATION - UNDERFIRE STACK 2-32
3.0 PROCESS AND CONTROL EQUIPMENT OPERATION 3-1
3.1 INTRODUCTION 3-1
3.2 PROCESS DESCRIPTION 3-1
3.3 PROCESS AND CONTROL DEVICE MONITORING 3-3
4.0 SAMPLING LOCATIONS 4-1
4.1 COKE OVEN BATTERYNO. 5/6 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE 5-3
5.3 DETERMINATION OF STACK GAS EMISSION RATE CORRECTION
FACTORS, DRY MOLECULAR WEIGHT, AND EXCESS AIR 5-3
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-3
5.5 DETERMINATION OF PARTICULATE MATTER/METHYLENE
CHLORIDE EXTRACTABLE MATTER/METALS 5-4
5.6 POLYCYCLIC AROMATIC HYDROCARBONS 5-6
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES AND RESULTS 6-1
6.1 CALIBRATION OF APPARATUS 6-1
111
-------
TABLE OF CONTENTS (Concluded)
P_age
6.2 ON-SITE MEASUREMENTS 6-5
6.3 LABORATORY ANALYSES 6-9
APPENDIX A PROCESS DATA
APPENDIX B RAW FIELD DATA
APPENDIX C ANALYTICAL DATA (Except CARB 429)
APPENDIX D ANALYTICAL DATA (CARB 429)
APPENDIX E CALCULATIONS
APPENDIX F QA/QC DATA
APPENDIX G PARTICIPANTS
APPENDIX H SAMPLING AND ANALYTICAL PROCEDURES
IV
-------
LIST OF TABLES
Page
Table 2.1 Emissions Test Log, ABC Coke, Birmingham, Alabama 2-2
Table 2.2 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-4
Table 2.3 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-6
Table 2.4 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Inlet, ABC Coke, Birmingham, Alabama 2-7
Table 2.5 Multiple Metals Concentrations and Emission Rates - Baghouse Inlet,
ABC Coke, Birmingham, Alabama 2-8
Table 2.6 Particulate Matter/MCEM/Metals Emission Sampling and Flue Gas
Parameters - Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-11
Table 2.7 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-12
Table 2.8 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Outlet, ABC Coke, Birmingham, Alabama 2-13
Table 2.9 Multiple Metals Concentrations and Emission Rates - Baghouse Outlet,
ABC Coke, Birmingham, Alabama 2-14
Table 2.10 Baghouse Dust Multiple Metals Concentrations, ABC Coke,
Birmingham, Alabama 2-18
Table 2.11 Filterable Particulate Matter and Methylene Chloride Extractable
Matter Removal Efficiencies, Coke Oven Battery No. 5/6 Baghouse,
ABC Coke, Birmingham, Alabama 2-19
Table 2.12 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Underfire Stack, ABC Coke, Birmingham, Alabama 2-20
Table 2.13 Filterable Particulate Matter Concentrations and Emission Rates -
Underfire Stack, ABC Coke, Birmingham, Alabama 2-21
Table 2.14 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Underfire Stack, ABC Coke, Birmingham, Alabama 2-23
Table 2.15 Multiple Metals Concentrations and Emission Rates - Underfire Stack
ABC Coke, Birmingham, Alabama 2-24
Table 2.16 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Inlet
ABC Coke, Birmingham, Alabama 2-28
Table 2.17 PAH Concentrations and Emission Rates, Baghouse Inlet,
ABC Coke, Birmingham, Alabama 2-29
-------
LIST OF TABLES (Continued)
Page
Table 2.18 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Outlet
ABC Coke, Birmingham, Alabama 2-33
Table 2.19 PAH Concentrations and Emission Rates, Baghouse Outlet,
ABC Coke, Birmingham, Alabama 2-34
Table 2.20 PAH Emissions Sampling and Flue Gas Parameters - Underfire Stack
ABC Coke, Birmingham, Alabama 2-37
Table 2.21 PAH Concentrations and Emission Rates Underfire Stack
ABC Coke, Birmingham, Alabama 2-38
Table 2.22 Particulate Matter/MCEM/Metals and PAH Emissions Sampling
and Flue Gas parameters - Underfire Stack Non-pushing and Non-charging
Operation, ABC Coke, Birmingham, Alabama 2-42
Table 2.23 Particulate Matter/MCEM Concentrations and Emission Rates -
Underfire Stack Non-pushing and Non-charging Operation, ABC Coke,
Birmingham, Alabama 2-43
Table 2.24 Multiple Metals Concentrations and Emission Rates -
Underfire Stack Non-pushing and Non-charging Operation, ABC Coke,
Birmingham, Alabama 2-44
Table 2.25 PAH Concentrations and Emission Rates - Underfire Stack Non-pushing and
Non-charging Operation, ABC Coke, Birmingham, Alabama 2-45
Table 3.1 A Pushing Control Device Parameters: Test Run No. 1,9/21/98 3-4
Table 3.IB Pushing Control Device Parameters: Test Run No. 2,9/22/98 3-5
Table 3.1C Pushing Control Device Parameters: Test Run No. 3, 9/23/98 3-6
Table 3.2A Combustion Stack Parameters: Test Run No. 1, 9/24/98 3-8
Table 3.2B Combustion Stack Parameters: Test Run No. 2, 9/24/98 3-8
Table 3.2C Combustion Stack Parameters: Test Run No. 3, 9/25/98 3-9
Table 3.2D Combustion Stack Parameters: Test Run No. 4, 9/25/98 3-9
Table 3.3 Combustion Stack Opacity Readings 3-10
Table 5.1 Summary of Sampling Locations, Test Parameters, Sampling Methods,
and Number and Duration of Tests, ABC Coke, Birmingham, Alabama 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-2
Table 6.2 Summary of Pitot Tube Dimensional Data 6-4
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-6
Table 6.4 Summary of EPA Method 315 and GARB Method 429 Field Sampling
QA/QC Data 6-8
Table 6.5 Summary of EPA Method 315 Analytical QC Data Lab Blank Analysis 6-10
Table 6.6 Summary of EPA Method 315 Analytical QC Data Field Blank Analysis ... 6-11
Table 6.7 Summaryof EPA Method 29 Analytical QC Data Lab Control Sample
(LCS) Recovery and Duplicate Analysis 6-13
Table 6.8 Summary of CARB Method 429 Analytical QC Data Field Blank
Results 6-14
VI
-------
LIST OF TABLES (Concluded)
Table 6.9 Summary of CARB Method 429 Analytical QC Data Lab Control
Sample (LCS) 6-15
Table 6.10 Summary of CARB Method 429 Analytical QC Data Surrogate
Standard Recoveries 6-17
vn
-------
LIST OF FIGURES
Page
Figure 1.1 Key Personnel and Responsibility for Testing at ABC Coke, Birmingham,
Alabama 1-2
Figure 4.1 Baghouse Inlet Sample Location, ABC Coke, Birmingham, Alabama 4-2
Figure 4.2 Method 1 Calculation Sheet, Baghouse Inlet, Method 315, ABC Coke,
Birmingham, Alabama 4-3
Figure 4.3 Method 1 Calculation Sheet, Baghouse Inlet, Method CARB 429,
ABC Coke, Birmingham, Alabama 4-4
Figure 4.4 Baghouse Outlet, Sampling Location, ABC Coke,
Birmingham, Alabama 4-5
Figure 4.5 Method 1 Calculation Sheet, Baghouse Outlet, ABC Coke,
Birmingham, Alabama 4-6
Figure 4.6 Combustion (Underfire) Stack Sampling Location, ABC Coke,
Birmingham, Alabama 4-8
Figure 4.7 Method 1 Calculation Sheet, Combustion Stack, ABC Coke,
Birmingham, Alabama „ 4-9
Figure 5.1 Sampling Train Schematic for EPA Method 315 5-5
Figure 5.2 Sampling Train Schematic for CARB Method 429 5-7
Figure 5.3 CARB Method 429 Sample Recovery Schematic 5-8
Figure 5.4 CARB Method 429 Analytical Schematic 5-9
vm
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APPENDIX D
ANALYTICAL DATA
(CARB 429)
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
7f
PURCHASE ORDER NO. 103-9S"- -
VENDOR:
/.<*./?
CONTACT: 2^u ^^^/
DATE:
INVOICE TO: Pacific Environmental Services, Inc.
560 Hemdon Parkway, Suite 200
Hemdon. Virginia 22070
(703)471-8383
SHIP TO: Pacific Environmental Services. Inc.
PHONE:
-------
Invoice
Quanterra, Incorporated
880 Riverside Parkway
West Sacramento, CA 95605
(916)373-5600
(916)372-1059
Quanterra, Incorporated
P.O. Box 2473
Carol Stream, IL 601322473
Quanterra
Number
0032027606
Quanterra Project Number
CALLAB-301802
Terms
NET 30 DAYS
Date
11 NOV 98
Customer Number
00104971
Payable
Pacific Environmental Services,
560 Herndon Parkway
Suite 200
Herndon, VA 201705240
Inc.
Ron Kolde
Pacific Environmental Services
4700 Duke Drive
Suite 150
Mason, OH 45040
Matrix
Code
Analysts Descnpnon
ANALYTICAL SERVICES
1 14 AIRTRAIN PAH in air matricies by HRGC/HRMS
2
3
14
20
Analytical Services Subtotal
ADDITIONAL SERVICES
Data Validation Package ($25.00/Sample)
XAD Trap-Prep and QC
Additional Services Subtotal
Unit Price
1000.00
14000.00
25.00
75.00
1850.00
-------
GOODS/SERVICES PURCHASE REQUISITION NO. 103-98"
Requested bv: r\6*\ n®10& Date:
Office No. /02> Charge to: S&S'. OOP
Preferred Vendor:
Address:
Phone:
Contact:
Fax:
Account No.
Special Instructions:.
(Please list alternate vendors on reverse)
Description (Detailed as possiblei
Ouannrv
Tosi/Unit
Cost
0 COMPLETE JUSTIFICATION MEMO ON REVERSE
TOTAL COST:
•oal Cot S500 pr Uts
When required by Purchase Authority Matrix
—,.
Approved:.
Dale:.
T.A. U Puma. President
-------
10/12/98 MON 14:41 FAX n03481829_6_,_
PES
O 003/00!
GOODS/SERVICES PURCHASE REQUISITION NO. 103-9S"-
Requested by:.
Office No. /*3 Charge to:.
Preferred Vendor:.
Address:
Date:
C.J
Phone: 4 tit ~
rQr>ract:
Fax:
Account No.:.
Special Instructions:.
(Please list alternate vendors on reverse)
Dcicnpaon (Deailed u possible)
Qu&nbrv
Cast/Unit
Cut
a COMPLETE JUrnFICATION MEMO ON REVEBSE
"
-------
Quanterra Incorporated
880 Riverside Parkway
West Sacramento, California 95605
916 373-5600 Telephone
916 372-1059 Fax
November 6, 1998
QUANTERRA INCORPORATED PROJECT NUMBER: 301802
PO/CONTRACT: CLC-950302
Ron Kolde
Pacific Environmental Services
4700 Duke Drive
Suite 150
Mason, OH 45040
Dear Mr. Kolde:
This report contains the analytical results for the fourteen samples which were received under
chain of custody by Quanterra Incorporated on 29 September 1998.
The case narrative is an integral part of this report.
If you have any questions, please feel free to call.
Sincerely,
Robert Weidenfeld
Project Manager
Advanced Technology
RW/tw
-------
^uanterra
TABLE OF CONTENTS
QUANTERRA INCORPORATED PROJECT NUMBER 301802
Case Narrative
Quanterra's Quality Assurance Program
Sample Description Information
Chain of Custody Documentation
Polynuclear Aromatic Hydrocarbons - Method HRGC/HRMS
Includes Sample(s): 1 through 14
Method Blank Sheets
Sample Data Sheets
Laboratory Control Sample
-------
(^uanterra
CASE NARRATIVE
QUANTERRA INCORPORATED PROJECT NUMBER 301802
Sample trains were prepared and analyzed by a modified CARB 429 procedure. All fractions of
each train were combined for a single extract which was analyzed by HRGC/HRMS.
Results above the reporting limits for Naphthalene, 2-Methylnaphthalene, and Phenanthrene
were detected in the laboratory method blank associated with your samples. These analyte levels
are common artifacts of XAD-2 resin and should be reviewed for significance. Positive
concentrations detected for these analytes in your samples are qualified with a "B" footnote on
the data sheets.
All reported results for your samples are from analysis of extracts diluted 1 OX, except where
qualified with a "D" footnote. D flagged results are from analysis of extracts diluted 100X due
to high analyte levels and/or matrix interferences.
Some internal standard recoveries are lower than the method recommended goal of 50%.
Generally, data quality is not considered affected if internal standard signal-to-noise is greater
than 10:1, which is achieved for all internal standards in all samples except as noted below. For
samples "A-U-429-1", "A-U-429-2", "A-U-429-3", and "A-U-429-4", there are very low
recoveries for Acenaphthylene-d8, Perylene-dl2, and Benzo(a)pyrene-dl2 due to severe
chemical interferences. These internal standard recoveries and the corresponding native
concentration have been determined as best as possible and should be considered estimated. The
affected analytes are qualified with an "F" footnote on the appropriate data sheets.
The Laboratory Control Sample (LCS) associated with your samples was reinjected for Flourene
on 03 NOV 98 due to poor response for this analyte in the original analysis.
-------
QUANTERRA INCORPORATED QUALITY CONTROL PROGRAM
Quanterra has implemented an extensive Quality Control (QC) program to ensure the production
of scientifically sound, legally defensible data of known documentable quality. This QC
program is based upon requirements in "Test Methods for Evaluating Solid Waste", USEPA
SW-846, Third Edition. It applies whenever SW-846 analytical methods are used. It also applies
in whole or in part whenever project requirements fail to specify some aspect of QC practices
described here. It does not apply when other well defined QC programs (e.g. CLP or CLP-like)
are specified. This is Quanterra's base QC program for environmental analysis.
Definitions:
Quality Control Batch. The quality control (QC) batch is a set of up to 20 field samples plus
associated laboratory QC samples that are similar in composition (matrix) and that are processed
within the same time period with the same reagent and standard lots.
Surrogate. A surrogate (or internal standard) is an organic compound similar in chemical
behavior to the target analyte, but not normally found in environmental samples. Surrogates (or
IS) are added to all samples in a batch to monitor the effects of both the matrix and the analytical
process on accuracy.
Method Blank. A method blank (MB) is a control sample prepared using the same reagents used
for the samples. As part of the QC batch, it accompanies the samples through all steps of the
sample extraction and cleanup procedure. The method blank is used to monitor the level of
contamination introduced to a batch of samples as a result of processing in the laboratory.
Laboratory Control Sample. A laboratory control sample (LCS) is prepared using a well
characterized matrix (e.g., reagent water or Ottawa sand) that is spiked with known amounts of
representative analytes. Alternate matrices (e.g., glass beads) may be used for soil analyses when
Ottawa sand is not appropriate. As part of a QC batch, it accompanies the samples through all
steps of the sample extraction and cleanup process. The LCS is used to monitor the accuracy of
the analytical process independent of possible interference effects due to sample matrix.
Duplicate Control Sample. A duplicate laboratory control sample (DCS) consists of a pair of
LCSs analyzed within the same QC batch to monitor precision and accuracy independent of
sample matrix effects.
-------
(Q/uanterra
SAMPLE DESCRIPTION INFORMATION
for
Pacific Environmental Services
Lab ID
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
301802-
0001-MB
0001-SA
0002-SA
0003-SA
0004-SA
0005-SA
0006-SA
0007-SA
0008-SA
0009-SA
0010-SA
0011-SA
0012-SA
0013-SA
0014-SA
Client ID
Method Blank
A-I-429-1
A-I-429-2
A-I-429-3
A-0-429-1
A-0-429-2
A-0-429-3
A-U-429-1
A-U-429-2
A-U-429-3
A-U-429-4
A-I-429-FB
A-0-429-FB
A-U-429-FB
A-429-LB
Matrix
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
Sampled
Date Time
21 SEP 98
22 SEP 98
23 SEP 98
21 SEP 98
22 SEP 98
23 SEP 98
24 SEP 98
24 SEP 98
25 SEP 98
25 SEP 98
24 SEP 98
24 SEP 98
25 SEP 98
21 SEP 98
Received
Date
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
29 SEP 98
-------
,&^rM
1 / 4fee-Duke-
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Chain of Custody Record
. /, > -
, Jjuile 1!>0
, on 4503D
(543f398-2556
FAX: (613) 308 3312
Projecl Number:
, 5
Samplers:!? *><^ /.
P. ,
PES Field Sample ID
Date
Project Name:
Purchase Order No.:
Time
Sample Description
Number
of
Containers
Analysis Requested
rr^-t
/
t>*.'>
Comments
/-T-tn-i
7
7
A. 5c
7
X
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- 1
7
7
7
X
7
7
7
X
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7
A-U-ritW-fi)
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elinquished by: (Signature)
Dale/Time
tfa/ft
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Dale/Time
Received for lab~fiy:(SJgnature)
EMARKS
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
Aflrttiu?, lk' ivw Mrfl,
s
,Udk
v/
A-I- MA-2A- Z
• Uf C.I,
y
J
(Wx w not UJJMLAJ. <\» ^
4r-
AC-
. Uttt,
fn y
v/
y
JWMi&dL
y
Page_| of
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
/
Eiltoft Mcnffi-t
v/2.
t/
/K.
Y2.
**r
fAtt. yg.
y
up
Cfjvd
Page 2. of
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
, A
fo
TII. to A
fe
(VJ-SFSH0-3
A
Ses
Utf£
MA
y
/ri^ (4^3 f
i/
Page 3 of
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
4-0-420-Z.
y
itoUfacUrAUftuulA :/
AlA
fc/dd?
dJfU
Q-23-iofl
faxd
J: ift^o Wf >oUeOU
S
s
AttLpLrtd
^4
s
Page ^ of
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
&.
jmCiy(bttL)*l^(!uuML
Tuhi
Yes
Page >5 of
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
/I ,«r^ '
VM
XAD
XA^s
i/
V/
k££k
Page of
11
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
'
y
£w> (jtut*
,
r
n to-iTf
. lluis, S*** &li.
L/
y
; /o... ,>*s*t
i. Ate ch.
j
XA'P
AL£
u/
J
A
ex-
Page
of
'"*
-------
U.S. EPA - ABC Coke - Birmingham, Alabama - S505.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
y
A
i
Cx
Page of
13
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
Method Blank
301802-0001-MB
AIRTRAIN Sampled: NA
NA Prepared: 03 OCT 98
Received: NA
Analyzed: 05 NOV 98
Parameter
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo b
Benzo k
Benzo e
Benzo a
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Result
340
25
ND
ND
ND
24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
_. _
--
10
10
10
--
10
10
10
10
10
10
10
10
10
10
10
10
10
Data
Qualifiers
NA = Not Applicable
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
Method Blank
301802-0001-MB
AIRTRAIN Sampled: NA
NA Prepared: 03 OCT 98
Received: NA
Analyzed: 05 NOV 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b
Benzofk
Benzo(a
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g', h,i )perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
42
66
64
60
80
50
54
65
85
93
87
75
84
93
94
86
% Recovery
87
m = Internal Standard recovery is outside method recovery goal.
NA = Not Applicable
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-1
301802-0001-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 02 NOV 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo km uoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
360000
76000
88000
15000
3400
160000
16000
50000
33000
15000
26000
17000
9200
6500
6300
1100
11000
2500
11000
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
D
D
D
D
BD
D
BD
D
D
D
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
uanterra
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-I-429-1
301802-0001-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 02 NOV 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzo(k)fluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
58
50
45
53
81
48
51
61
58
91
72
87
86
78
83
64
% Recovery
82
D
D
Dm
D
D
Dm
D
D
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-2
301802-0002-SA
AIRTRAIN Sampled: 22 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received:
Analyzed:
29 SEP 98
30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo b
Benzo k
Penzo ei
benzo(a
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
120000
24000
36000
4300
16000
53000
4300
18000
13000
7000
12000
5200
3700
2600
1900
330
4300
1100
3800
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
B
D
D
BD
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
uanterra
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-I-429-2
301802-0002-SA
AIRTRAIN Sampled: 22 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo b)fluoranthene-d!2
Benzo kmuoranthene-d!2
Benzo a)pyrene-d!2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
75
58
64
43
98
62
73
64
53
95
66
103
70
75
91
80
% Recovery
103
D
D
D
m
D
D
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report,
Rev 230787
-50
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-3
301802-0003-SA
AIRTRAIN Sampled: 23 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2 -Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b) fluoranthene
fluoranthene
pyrene
pyrene
Benzo
Benzo
Benzo(a
Perylene
Indeno(l , 2,3- cd) pyrene
Di benz( a, hj anthracene
Benzo(g,h, i )perylene
160000
41000
33000
6300
18000
66000
9100
25000
18000
11000
18000
6100
3600
3300
1800
280
3900
980
4000
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
BD
D
D
BD
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-I-429-3
301802-0003-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 23 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzo(k)fluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
77
58
70
50
99
49
80
75
54
90
68
99
73
68
87
68
% Recovery
94
D
D
D
D
Dm
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Pacific Environmental
A-0-429-1
301802-0004-SA
Services
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 21 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b)fluoranthene
Benzo kjfluoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
290000
55000
50000
7000
21000
66000
20000
32000
16000
290
740
200
200
130
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
--
--
100
100
100
100
100
BD
B
BD
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-0-429-1
301802-0004-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d12
Field Surrogates
13C-Fluorene
% Recovery
92
90
74
69
99
69
70
81
60
81
79
88
87
77
77
69
% Recovery
124
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-0-429-2
301802-0005-SA
AIRTRAIN Sampled: 22 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo(a)pyrene
Perylene
I ndeno(1,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
95000
24000
22000
2500
7500
45000
3300
14000
8100
240
640
180
160
ND
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
100
100
100
100
100
100
B
B
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
vuanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-0-429-2
Lab ID: 301802-0005-SA
Matrix: AIRTRAIN Sampled: 22 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
46
75
72
75
88
58
56
75
58
73
80
94
88
76
64
76
% Recovery
112
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-0-429-3
301802-0006-SA
AIRTRAIN Sampled
29 SEP 98 Prepared
23 SEP 98 Received: 29 SEP 98
03 OCT 98 Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b)fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo a pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a, hjanthracene
Benzo(g,h,i)perylene
110000
36000
17000
3500
8800
27000
5100
12000
6400
240
690
210
140
110
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
B
BD
100
100
100
100
100
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
uanterra
Cllent Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-0-429-3
301802-0006-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 23 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Field Surrogates
13C-Fluorene
% Recovery
65
85
82
75
107
69
63
80
58
80
85
88
87
73
81
66
% Recovery
117
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
4^/uanferra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-1
301802-0007-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received:
Analyzed:
29 SEP 98
31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphtha!ene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo(a)pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
100000
2900
16000
280
930
11000
310
5400
2700
160
380
270
ND
290
230
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
--
100
--
--
100
100
100
100
B
B
F
B = Compound is also detected in
F = Reported value estimated due
ND = Not Detected
Reported By: Clark Pickell
the blank.
to an interference.
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Cllent Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-1
301802-0007-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzofk fluoranthene-d!2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
46
5.0
50
81
94
70
57
52
14
70
80
79
80
18
77
58
% Recovery
119
m
m
m
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
o
-------
Q/uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-2
301802-0008-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Benzo(a)pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
130000
2300
68000
240
690
20000
460
12000
21000
100
460
420
130
1400
210
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
--
--
--
100
100
100
100
B
B
F
F
F
B = Compound is also detected in the blank.
F = Reported value estimated due to an interference.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
^uanterra
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-2
301802-0008-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-d12
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
b)fluoranthene-d!2
k)fluoranthene-d!2
a)pyrene-d!2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
42
4.0
49
78
95
65
55
61
12
52
76
74
66
17
56
40
% Recovery
99
m
m
m
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
21
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-3
301802-0009-SA
AIRTRAIN Sampled
29 SEP 98 Prepared
25 SEP 98 Received: 29 SEP 98
03 OCT 98 Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Eenzo e pyrene
Benzo(a)pyrene
Perylene
Indent) (1,2,3-cd) pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
76000
1600
13000
120
360
9900
220
4800
3300
ND
290
210
ND
350
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
100
--
100
--
100
100
100
100
100
B
B
F
B = Compound is also detected in
F = Reported value estimated due
ND = Not Detected
Reported By: Clark Pickell
the blank.
to an interference.
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-3
301802-0009-SA
AIRTRAIN Sampled: 25 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzo(kjfluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
52
9.0
59
73
88
77
64
75
20
77
95
93
90
22
79
57
% Recovery
104
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-4
301802-0010-SA
AIRTRAIN Sampled: 25 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b)fluoranthene
Benzo kjfluoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
99000
4400
NC
240
1300
18000
280
7100
4600
150
520
260
110
300
160
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
B
B
100
100
100
100
B = Compound is also detected in the blank.
F = Reported value estimated due to an interference.
NC = Not Calculated, calculation not applicable.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-4
301802-0010-SA
AIRTRAIN Sampled: 25 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
43
NC
45
79
87
80
53
53
8.0
55
79
94
75
16
61
41
% Recovery
122
m
m
m
m
m = Internal Standard recovery is outside method recovery goal.
NC = Not Calculated, calculation not applicable.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-FB
301802-0011-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo k)fluoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Result
1600
200
ND
ND
ND
210
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
..
--
100
100
100
--
100
100
100
100
100
100
100
100
100
100
100
100
100
Data
Qualifiers
B
B
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-FB
301802-0011-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Benzo
Benzo
Benzo
Di benz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
45
54
62
57
61
68
70
64
65
81
89
72
87
68
75
70
% Recovery
103
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
t^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-0-429-FB
301802-0012-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a, hjanthracene
Benzo(g,h,i)perylene
Result
1000
ND
ND
ND
ND
270
ND
190
150
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Reporting
Limit
..
100
100
100
100
--
100
--
--
100
100
100
100
100
100
100
100
100
100
Data
Qualifiers
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-0-429-FB
301802-0012-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
b)fluoranthene-d!2
kjfluoranthene-d!2
a)pyrene-d!2
Benzo
Benzo
Benzo
Dibenz( a', h) anthracene -d!4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
46
54
68
51
65
75
71
60
57
73
94
80
77
61
66
66
% Recovery
107
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-FB
301802-0013-SA
AIRTRAIN Sampled: 25 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b)fluoranthene
Benzo kjfluoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Result
980
ND
ND
ND
ND
120
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
- -
100
100
100
100
--
100
100
100
100
100
100
100
100
100
100
100
100
100
Data
Qualifiers
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-iO
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-FB
301802-0013-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 25 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d12
Field Surrogates
13C-Fluorene
% Recovery
48
63
66
64
67
83
80
61
57
73
106
81
89
65
77
73
% Recovery
98
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-429-LB
301802-0014-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo b
Benzo k
Benzo e
Benzo(a
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Result
840
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
_ _
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Data
Qualifiers
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
^uanterra
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-429-LB
301802-0014-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-d12
Field Surrogates
13C-Fluorene
% Recovery
52
51
57
69
77
84
82
56
61
64
106
76
87
65
60
64
% Recovery
101
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
LABORATORY CONTROL SAMPLE REPORT
Advanced Technology Group - High Resolution
Project: 301802
Category: PAH-HR-AIR PAH by HRGC/HRMS
Test: PAH-HR-AIR
Matrix: AIR
QC Lot: 03 OCT 98-A
Concentration Units: ng/sample
Analyte
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
QC Run: 02 NOV 98-A
Concentration
Spiked Measured
fluoranthene
fluoranthene
pyrene
Benzo b
Benzo k
Benzo e
Benzo a)pyrene
Perylene
Indeno (1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Perylene-dl2
Indeno(123 -cd)pyrene-d12
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
90
100
100
92
77
81
78
80
64
87
77
76
66
73
68
79
90
76
88
27
31
31
28
38
24
26
31
43
36
44
45
32
59
56
54
Accuracy(%)
LCS Limits
90
103
102
92
77
81
78
80
64
87
77
76
66
73
68
79
90
76
88
53
63
61
55
75
48
52
62
85
71
88
91
65
117
112
109
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
B
B
a
B
#
# = Outside of control limits.
a = See narrative.
B = Compound is also detected in the blank.
Calculations are performed before rounding to avoid round-off errors in calculated results.
-------
Method Blank
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
Method Blank
301802-0001-MB
AIRTRAIN Sampled: NA
NA Prepared: 03 OCT 98
Received: NA
Analyzed: 05 NOV 98
Parameter
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo b
Uenzo k
Benzo e
Benzo(a
Perylene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Result
340
25
ND
ND
ND
24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
_ _
--
10
10
10
--
10
10
10
10
10
10
10
10
10
10
10
10
10
Data
Qualifiers
NA = Not Applicable
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
Method Blank
301802-0001-MB
AIRTRAIN Sampled: NA
NA Prepared: 03 OCT 98
Received: NA
Analyzed: 05 NOV 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Benzo(b
Benzofk
Benzo(a
Dibenz(a',h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
42
66
64
60
80
50
54
65
85
93
87
75
84
93
94
86
% Recovery
87
m
m = Internal Standard recovery is outside method recovery goal.
NA = Not Applicable
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
47
-------
04-NOV-1998 12:40:42 PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 02N098V4
Weight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dl2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
— l3C-Fluorene
Results
301802-1MB
Total
Response
02N098V4031.RES
Date analyzed
:METHOD BLANK Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
112227400
105343000
444010000
14520000
89410200
738674
53754000
6026800
66464600
56334800
1991522
149506400
32600000
* No Peak
191478400
135260800
11031920
155985600
5781280
112804800
609918
212384000
1683386
237306000
80350200
948200
189536400
948200
149194200
481952
78083
127833600
* No Peak
98292400
59792
55083800
* No Peak
118699600
143538
56334800
39-298000-
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
1
0
1
1
1
i
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
-00.
.-00-
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
Y
Y
Y
Y
12:
10:
10:
12 :
15:
15:
16:
16:
20:
17 :
17:
20:
20:
20:
26:
24:
24:
25 :
25:
29:
29:
29:
29 :
33 :
32 :
32 :
32:
32 :
33 :
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
.17:
•17:
28
12
16
34
28
31
2
8
55
41
47
46
50
59
0
36
40
18
21
9
13
15
20
21
29
35
34
35
32
27
38
50
54
1
9
6
14
12
21
41
47
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
Y
Y
Y
Y
1.00 50.00
2.24 20.95
1.23 344.04
0.56 24.59
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
1.00
1.41
1.11
1.52
1.21
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
1.40
0.58
1.02
1.00
0.80
42 f"
32.82 66
?
,-p
-------
04-NOV-1998 12:40:39 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF '••'•'-
Rec/
MDL
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
42
66
00
64
00
60
00
80
00
50
00
54
00
65
00
87
00
75
00
84
00
93
00
00
85
00
93
00
94
00
86
00
56113700
52671500
222005000
7260000
44705100
369337
26877000
3013400
33232300
28167400
995761
74753200
16300000
0
95739200
67630400
5515960
77992800
2890640
56402400
304959
106192000
841693
118653000
40175100
474100
94768200
474100
74597100
240976
39041
63916800
0
49146200
29896
27541900
0
59349800
71769
56113700
52671500
222005000
7260000
44705100
369337
26877000
3013400
33232300
28167400
995761
74753200
16300000
0
95739200
67630400
5515960
77992800
2890640
56402400
304959
106192000
841693
118653000
40175100
474100
94768200
474100
74597100
240976
39041
63916800
0
49146200
29896
27541900
0
59349800
71769
-------
)3-NOV-1998 08:08:26 AM
429AIR Unknown RESULTS
lass Spec : VG-4
3C Column : DB-5
Data file : 02N098V4
height : 0.5
Name
dlO - 2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl 2-Benzo(e)pyrene
312-Benzo(b)fluoranthene
Benzo(b)fluoranthene
112-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
312-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
314-Dibenz(ah)anthracene
Dibenz(ah)anthracene
'J d!2-Benzo (ghi) perylene
'' Benzo (ghi)perylene
dlO-Fluorene
13C-Fluorene
Results
301802-1MB
Total
Response
02N098V4031.RES
Date analyzed
:METHOD BLANK Ex Cal
Isotope R. T. RRF
Ratio
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
112227400 1.00 Y
105343000 1.00 Y
444010000 1.00 Y
15679360 1.00 Y
89410200 1.00 Y
738674 1.00 Y
53754000 1.00 Y
6026800 1.00 Y
66464600 1.00 Y
56334800 1.00 Y
1991522 1.00 Y
149506400 1.00 Y
34755000 1.00 Y
* No Peak 0.00 N
191478400 1.00 Y
135260800 1.00 Y
11031920 1.00 Y
155985600 1.00 Y
5781280 1.00 Y
112804800 1.00 Y
609918 1.00 Y
212384000 1.00 Y
1683386 1.00 Y
237306000 1.00 Y
80350200 1.00 Y
948200 1.00 Y
189536400 1.00 Y
948200 1.00 Y
149194200 1.00 Y
481952 1.00 Y
78083 1.00 Y
127833600 1.00 Y
* No Peak 0.00 N
98292400 T -00 Y
59792 1.00 Y
55083800 1.00 Y
* No Peak .0.00 N
118699600 1.00 Y
143538 1.00 Y
56334800 1.00 Y
39298000 1.00 Y
ULUL
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
tab
28
12
16
34
28
31
2
g
55
41
47
46
50
59
0
36
40
18
21
9
13
15
20
21
29
35
34
35
32
27
38
50
54
1
9
6
14
12
21
41
47
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
Y
Y
Y
Y
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
•1
0
1
1
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
. 14
.62
.25
.40
.58
.02
.42
.00
J..TLH.
50
20
344
26
32
0
32
9
50
29
3
40
25
0
50
25
7
26
3
32
0
43
0
50
37
1
42
0
46
0
0
42
0
46
0
47
0
43
0
8
69
irv
.00
.95
.04
.55
.82
.88
.16
.00
.00
.83
.05
.06
.99
.00
.00
.04
.34
.83
.08
.73
.45
.36
.73
.00
.30
.01
.12
.43
.45
.20
.05
.74
.00
.59
.10
.21
.00
.14
.12
.35
.76
1*1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
ULt
42
000
000
66
000
64
000
60
000
80
000
000
50
000
54
000
65
000
87
000
75
000
84
000
93
000
000
85
000
93
000
94
000
86
000
17
000
-------
File:02NO98V4 #1-509 Acq: 2-NOV-1998 14:51:29 GC El+ Voltage SIR 70SE
Sampled Text:301802-lMB :METHOD BLANK Exp:PAHAIR
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-------
File:02NO98V4 #1-509 Acq: 2-NOV-1998 14:51:29 GC EH Voltage SIR 70SE
Sampled Text:301802-lMB :METHOD BLANK ExprPAHAIR
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File:02NO98V4 #1-509 Acq: 2-NOV-I998 14:51:29 GC EI+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-509 Acq: 2-NOV-1998 14:51:29 GC E1+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-641 Acq: 2-NOV-1998 14:51:29 GC E1+ Voltage SIR 70SE
Sampled) Text:301802-lMB :METHOD BLANK Exp:PAHAIR
166.0798 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Sample Data
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-I-429-1
Lab ID: 301802-0001-SA
Matrix: AIRTRAIN Sampled: 21 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 02 NOV 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo kjfluoranthene
Benzo ejpyrene
Benzo ajpyrene
Perylene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
360000
76000
88000
15000
3400
160000
16000
50000
33000
15000
26000
17000
9200
6500
6300
1100
11000
2500
11000
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
D
D
D
D
BD
D
BD
D
D
D
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Dilution Factor: 1.0
Pacific Environmental Services
A-I-429-1
301802-0001-SA
AIRTRAIN Sampled: 21 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 02 NOV 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzo(k)fluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
58
50
45
53
81
48
51
61
58
91
72
87
86
78
83
64
% Recovery
82
D
D
Dm
D
D
Dm
D
D
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
I4-NOV-1998 01:07:24 PM Dioxin Furan Unknown RESULTS
lass Spec
}C Column
>ata f:ile
/eight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
Results : 02N098V4091.RES
Date analyzed
301802-1 :100X DIL; --AIR Ex --Gal
Total Isotope R. T. RRF
Response Ratio mm-.ss
592000 1.00 Y
772000 1.00 Y
3448480000 1.00 Y
328228000 1.00 Y
357346 1.00 Y
295804000 1.00 Y
199957 1.00 Y
37493600 1.00 Y
397598 1.00 Y
299420 1.00 Y
11855640 1.00 Y
905068 1.00 Y
1267780000 1.00 Y
118200000 1.00 Y
12: 28 Y
10: 13 Y
10: 15 Y
12: 34 Y
15: 27 Y
15: 30 Y
16:
16:
1 Y
8 Y
20: 55 Y
17: 41 Y
17: 47 Y
20: 45 Y
20: 49 Y
20: 59 Y
1215336 1.00 Y 26: 1 Y
824000 1.00 Y 24: 35 Y
458920000 1.00 Y 24: 39 Y
939830 1.00 Y 25: 16 Y
368212000 1.00 Y 25: 20 Y
669672 1.00 Y 29: 8 Y
123418000 1.00 Y 29: 12 Y
1116460 1.00 Y 29: 14 Y
317112000 1.00 Y 29: 19 Y
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 29.10
1.23 3.6e+05
0.56 7.6e+04
1.21 24.87
0.94 8.86+04
0-74 22.68
1.25 l.Se+04
1.00 50.00
1.42 26.50
1.16 3411.87
50
iw
45 ^
53
2.81 40.54 81
0.89 1.66+05 B /,,
0.80 1.6e+04 ™
1.00 50.00
1.41 24.03 48
1.11 5.0e + 04 X#j
1.52 25.47 51
1.21 3 .3e+04
0.90 30.61 61
1.20 1.5e+04
1.28 35.91 72
1.08 2.6e+04
.dlO- Fluorene
-lOG-Fluorene-
299420. 1..-QO Y..J.7: 4J_ Y 1.00 50.00
197600- 1-.-00-Y: -17: 4-6- -Y 0.80 41.25
-------
04-NOV-1998 01:07:20 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF •:;:^
Rec/
MDL
296000 296000
58 386000 386000
B E 1724240000 1724240000
B E 164114000 164114000
50 178673 178673
E 147902000 147902000
45
53
81
B E
48
B E
51
61
72
99979
18746800
198799
149710
5927820
452534
633890000
59100000
607668
412000
229460000
469915
184106000
334836
61709000
558230
158556000
99979
18746800
198799
149710
5927820
452534
633890000
59100000
607668
412000
229460000
469915
184106000
334836
61709000
558230
158556000
-------
33-NOV-1998 08:29:39 AM
429AIR Unknown RESULTS
toss Spec : VG-4
3C Column : DB-5
Data file : 02N098V4
height : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
Results : 02N098V4091.RES
Date analyzed
301802-1 :100X DIL. :AIR Ex Cal
Total Isotope R. T. RRF
Response Ratio mm ss
485074 1.00 Y 12
598348 1.00 Y 10
3448480000 1.00 Y 10
328228000 1.00 Y 12
357346 1.00 Y 15
295804000 1.00 Y 15
199957 1.00 Y 16
37493600 1.00 Y 16
397598 1.00 Y 20
299420 1.00 Y 17
11855640 1.00 Y 17
905068 1.00 Y 20
1267780000 1.00 Y 20
* No Peak 0.00 N 20
1215336 1.00 Y 26
743050 1.00 Y 24
458920000 1.00 Y 24
939830 1.00 Y 25
368212000 1.00 Y 25
669672 1.00 Y 29
123418000 1.00 Y 29
1116460 1.00 Y 29
317112000 .1.00 Y 29
28 Y
13 Y
15 Y
34 Y
27 Y
30 Y
1 Y
8 Y
55 Y
41 Y
47 Y
45 Y
49 Y
59 N
1 Y
35 Y
39 Y
16 Y
20 Y
8 Y
12 Y
14 Y
19 Y
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 27.53 55
1.23 4.7e+05 0.000
0.56 9.8e+04 0.000
1.21 30.35 61
0.94 8.8e+04 0.000
0.74 27.68 55
1.25 1.5e+04 0.000
1.00 50.00
1.42 26.50 53
1.16 3411.87 0.000
2.81 40.54 81
0.89 1.6e+05 0.000
0.80 0.00 0.000
1.00 50.00
1.41 21.67 43
1.11 5.6e+04 0.000
1.52 25.47 51
1.21 3.3e+04 0.000
0.90 30.61 61
1.20 1.5e+04 0.000
1.28 35.91 72
1.08 2.6e+04 0.000
d!2-Benzo(e)pyrene
d!2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
dl2-Benzo (k) f luoranthe
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
1340970 1.00 Y
537714 1.00 Y
142542000 1.00 Y
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
314-Dibenz (ah) anthracene'
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
1040730 1.00 Y
142542000 1.00 Y
509580
507S9200
342291^00
1.00 Y
1.00 Y
1.00 Y
467150
* No Peak
50 Y
54 N
1.00 Y
1.00 Y
•511154
7223000
1.00 Y
1.00 Y
142852
8027680
12 Y
20 Y
1.00 50.00
0.45 44.18 88
1.17 2..-36 + 04 0.000
<95 40.93 82
1.16 1.2e+04 0.000
0.68 28.08 56
1.64 6068.31 0.000
1.07 6266.07 0.000
468222
62917800
299420
149561
1.00 Y
1.00 Y
1.00 Y
1.00 Y
17
17
41 Y
46 Y
0.63 27.64 55
1.71 0.00 0.000
0 44 2G.10 52
0.62 3.0e+04 0.000
0.25 21.67 43
1.40 4003.87 0.000
0 ."5-8 30.12 60
1. 02^.^.36 + 04 0.000
1.42 T,86 16
1.00 49.95 0.000
*:• o
-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
Sampled Text:301802-l :100X OIL. :AIR Exp:PAHAlR
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 19:45:31 GC E1 + Voltage SIR 70SE
Sampled Text:301802-l :100X OIL. :AIR Exp:PAHAlR
128.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
Sainple#9 Text:301802-l :100X D1L. :AIR Exp:PAHAIR
142.0782 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 19:45:31 GC E1+ Voltage SIR 70SE
Sampled Text:301802-l :100X D1L. :A1R Exp:PAHAlR
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Sample/ft) Text:301802-l :100X D1L. :A1R Exp:PAHAIR
130.9920 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FHe:02N098V4 #1-641 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR
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File:02NO98V4 #1-641 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-641 Acq: 2-NOV-1998 19:45:31 GC E1+ Voltage SIR 70SE
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File:02NO98V4 #1-641 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-939 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-939 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-939 Acq: 2-NOV-1998 19:45:31 CC E1+ Voltage SIR 70SE
Sampled Text:301802-l :100X OIL. :A1R Exp:PAHAlR
228.0939 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 j
80 J
70 j
60-
50 j
40^
30 J
20 J
10-
0-
A1.59E8
A1.35E7
26:00 27:bo 28:00
240.1692 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90
804
70
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40
30
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6.7 E6
.3.4E6
31:00 Time
1.6E5
1.4E5
1.3E5
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7.9E4
6.3E4
4.7 E4
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-------
File:02N098V4 #1-939 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
Sampled Text:301802-l :100X DIL. :AIR Exp:PAHAIR
230.9856 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
00 2
1
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L3.1E7
L2.5E7
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:5.1E6
; O.OEO
>0 Time
CO
-------
File:02N098V4 #1-878 Acq: 2-NOV-1998 19:45:31 GC £1+ Voltage SIR 70SE
Sampled Text:301802-l :100X DIL. :AIR Exp:PAHAIR
252.0939 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.13E7
:00
264.1692
100
32:1)0 ' ' ' 33:00
S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A6.70E5
00 Time
31:60
O.OEO
W Time
00
-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
Sampled Text:301802-l :100X OIL. :AIR Exp:PAHAIR
276.0939 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.15E7
288.1692 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0>0.00%,F,T)
100% A1.56E5 A2.34E5
37:00 38-1)0'
278.1096 S:9 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
)0 Time
3.5E4
-2.8E4
-2.1E4
1.4E4
L6.9E3
o.OEO
42:
)0 Time
>0 Time
37:00
292.1974 S:9 F:4 SMO(1,3)
100%
\n
)0 Time
-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 19:45:31 GC EI+ Voltage SIR 70SE
Sampled Text:301802-l :100X D1L. :AIR Exp:PAHAIR
268.9824 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,
lOQS
90-
',0
cfl
0:
31:
»-f—i . . . , r 1 1 1 1 1 r—, . . . 1 r—i 1 1 1 1 r—, r
31:00 32:00 33:00 34:00 35:00
280.9824 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
701
60-
50 J
40
i
30:
20 J
10J
36:1)0
i.89E7
:bo 38:bo 39:bfl 40:bfl
37
41
ST
A2.36E7
42:00 Time
_7.4E7
6.6E7
-5.9E7
L5.2E7
L4.4E7
3.7E7
L2.9E7
L2.2E7
1.5E7
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42:00 Time
-------
04-NOV-1998 05:02:00 -PM
Mass Spec : VG-4
iGC
Dioxin Furan Unknown RESULTS
Results : 290C98V4211.RES
.., • i_ .
Weight
Name
•" Isotope
Response Ratio tnm:ss
: PAHAIR.TRG
_: :'Rec/
SAMPLE MDL
.ICQ**
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benz o(ghi)pery1ene
35942800
14231180
2860000000
1.00 Y 33: 21 Y
1.00 Y 32: 28 Y
1.00 Y 32: 33 Y
29376000
3160000000
18968780
2022400000
1284450000
13184320
256000000
14531060
1022000000
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
32:
32:
33:
33:
33:
33:
33:
38:
38:
33
38
32
27
36
49
54
0
7
Y
Y
Y
Y
Y
Y
Y
Y
Y
7305720
258000000
13293180
1548716000
1.00 Y
1.00 Y
1.00 Y
100 Y
38
38
39
39
4 Y
13 Y
12 Y
20 Y
1.00 50.00
0.45 43.62
1.17 1.7e+04
0.95 43.10
1.16 9240.29
0.68 39.00
1.64 6497.77
1.07 6316.71
0.63 29.10
1.71 1133.11
0.44 45.47
0.62 l.le+04
0.25 41.3-4
1.40 2516.12
0.58 31.90
1.02 l.le+04
58
91
83
64
-------
04-NOV-1998 05:01:57 PM Dioxin Furan Unknown;RESULTS
.vc i a a =• = z *-»»:«:*
• MDL
rill
17971400 17971400
87 7115590 7115590
1430000000 1430000000
86 14688000 14688000
1580000000 1580000000
78 9484390 9484390
1011200000 1011200000
642225000 642225000
58 6592160 6592160
128000000 128000000
91 7265530 7265530
511000000 511000000
83 3652860 3652860
129000000 129000000
64 6646590 6646590
774358000 774358000
-- I 1 !
-------
02-NOV-1998 09:41:06 AM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 290C98V4
Weight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthatfene
d8-Acenaphthyl(
Acenaphthylei
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene,
dlO-Pyarene
?yrene
d!2 -Benzo (^anthracene
Benzo{a)anthracene
d!2-Chrysene
Chrysene
Results : 290C98V4211.RES
Date analyzed
301802-1 :10X DIL. :AIR : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
1987508 1.00 Y 12: 27 Y
7167580 1.00 Y 10: 13 Y
18269040000 1.00 Y 10: 16 Y
2594880000 1.00 Y 12: 34 Y
4874760 1.00 Y 15: 28 Y
1492652000 1.00 Y 15: 30 Y
409646 1.00 Y 16
92561800 1.00 Y 16
U533580 1.00 Y
3528760 1.00 Y
2024085000 1.00 Y/ 17
8423420s
738374000J
1803014JX30
20: 45 Y,,
20: 50 Y
20: 58 Y
ri90760 1.00 Y
'16033260 1.00 Y
6834220000 1.00 Y 24
13399300 1.00 Y 25
6081540000 1.00 Y 25
7458460 1.00 Y 29
2198000000 1.00 Y 29
10119100 1.00 Y 29
4591820000 1.00 Y 29
14 Y
19 Y
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
35942800 1.00 Y 33: 21 Y
14231180 1.00 Y 32: 28 Y
5954800000 1.00 Y 32: 33 Y
29376000 1.00 Y 32: 33 Y
5954800000 1.00 Y 32: 33 Y
: PAHAIR.TRG
: 29-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMPLE MDL
1.00 50.00
2.24 80.47 161
1.23 2.16+05 0.000
0.56 6.5^+04 0.000
101.04 202
J4 3.26+04 0.000
0.74 13.84 28
1.25 1.8e+04 0.000
1.00 50.00
1.42 23.51 47 !
1.16 5.86+04 0.000 <
2.81 33.09 66
0.89 9.86+04 0.000
0.80 2.76+04 0.000
1.00 50.00
1.41 46.61 93
1.11 3.86+04 0.000
1.52 36.20 72
1.21 3.86+04 0.000
£0 33.99 68
2.46+04 0.000
1.28 ^£2.45 65
1.08 4.2e+04 0.000
1.00 50.00
0.45 43.62 87
1.17 3.66+04 0.000
0.95 43.10 86
1.16 1.76+04 0.000
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
18968780 1.00 Y 33: 32 Y
2022400000 1.00 Y 33: 27 Y
1284450000 1.00 Y 33: 36 Y
13184320 1.00 Y 33: 49 Y
* No Peak 0.00 N 33: 54 N
14531060 1.00 Y 38: 0 Y
1397488000 1.00 Y 38: 7 Y-
7305720 1.00 Y 38: 4 Y
272420000 1.00 Y 38: 13 Y
13293180 1.00 Y 39: 12 Y
1548716000 1.00 Y 39: 20 Y
3028760 1.00 Y 17: 41 Y
3398420 1.00 Y 17: 47 Y
0.68 39.00
1.64 6497.77 0.000 •
1.07 6316.71 0.000
0.63 29.10 58
1.71 0.00 0.000
0.44 45.47-.- 31
0.62 I.Se+04 O-.OOO
0.25 41/3-4"- 83
1.40'2656.75 0.000 \
0.58 31.90 64 j
1.02 l.le+04 0.000 ||
1.42 2.97 6J'
1.00 112.20 0.0001
••": sr
-------
Flle:29OC98V4 #1-510 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sampled! Text:301802-l :10X OIL. :AIR : Exp-.PAHAIR
128.0626 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80.:
60 j
40
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0
9:(
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-1.1E9
-8.6E8
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-2.1E8
O.OEO
)0 Time
7.2E5
i.5.7E5
:4.3E5
L2.9E5
Ll.4E5
O.OEO
»0 Time
142.0782 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
80 1
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40 J
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0
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152.1410 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
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)0 Time
-------
File:29OC98V4 #1-510 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sainple#21 Text:301802-l :10X DIL. :AIR : Exp:PAHAIR
152.0626 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80 J
60 J
40_
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-4.4E7
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14:60 14:12 14:24 14:36 14:48 15:bo 15:12 15:24 15:36 15:48 16:6o 16:12 16:24 16:36 16:48 17:6fl Time
160.1128 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.82E6
14:00 14:12 14:24 14:36 14:48 15:00 15:
154.0782 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%>F>T)
100 2
801
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164.1410 S:21 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48
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(7)
-------
Flle:29OC98V4 #1-510 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 Text:301802-l :10X OIL. :AIR : Exp:PAHAIR
130.99208:21 SMO(1,3) PKD(5,3,3,0.10%)10000.0,0.00%)F,T)
00 2
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»0 Time
-------
File:29OC98V4 #1-641 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Samplelll Text:301802-l :10X DIL. :AIR : ExprPAHAIR
166.0798 S:21 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.0JE9
90 J
80 J
70 J
60 J
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20 J
10 J
0
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3.0E8
L2.6E8
2.1E8
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1.3E8
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L4.3E7
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7.3ES
6.6E5
5.9E5
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.-6.3E5
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L3.8E5
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L6.3E4
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)0 Time
17:60 17:i2 17:24 17:36 17:48 18:1)0 18:ii
172.0984 S:21 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%>F,T)
100%
90 J
80 J
70 J
60 J
SOJ
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A1.51E6
00
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-------
Flle:29OC98V4 #1-641 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 TexfJOl802-1 :IOX OIL. :AIR : Exp:PAHAIR
178.07828:21 F:2 SMO(l ,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
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O.OEO
10 Time
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:1.7E6
-1.5E6
L1.3E6
L1.1E6
L9.6ES
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L1.9ES
L O.OEO
K) Time
-------
Ffle:290C98V4 #1-641 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sarople#21 Text:301802-1 :10X OIL. :AIR : Exp:PAHAIR
204.9888 S:21 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
O.OEO
0 Time
-------
File:29OC98V4 #1-939 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
' — Text:301802-l :10X OIL. :AIR : Exp:PAHAK
202.0782 S:21 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A3.42E9 A3.Q4E9 rl.lE9
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
0
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A2.95E8
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212.1410 S:21 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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80 J
70 J
60 J
50 J
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L9.7E8
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CO
-------
Flle:29OC98V4 #1-939 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 Text:301802-l :10X OIL. :AIR : Exp:PAHAIR
00 S
90 J
80 J
70-
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50 J
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240.1692 S:21 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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-------
F11e:29OC98V4 #1-939 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SB
Saraple#21 Text:30I802-l :10X DIL. :A1R : Exp:PAHAtR
230.9856 S:21 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-879 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sampled! Text:301802-l :10X OIL. :AIR : ~ ~
cn
252.0939 S:21 F:4 SMO(1,3) PKD(5,3,3,0.10%
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-------
Text;301802-l :10X DIL, ;AIR : ExpiPAHAIR
25^.0939 S:21 F:4 SMO(1,3) PKD(5(3,3,0.10%)10000.0,0.00%,F,T)
100%
^3i:l6 32:i8 32:^0 32:^2 32:^4 32:26 32:28 32:30 32:32 32:34 32:36 32:38 32:40 32:42 32:44 32:46 32:48 32:50
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time
100%
-t ,
.,3lJ:16 32:18 32:20 32:22 32:24 32:26 32:28 32:30 32:32 32:34 32:36 32:38 32:40 32:42 32:44 32:46 32:48 32:50
O.OEO
Tune
-------
File:290C98V4 #1-879 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 Text:301802-l :10X OIL. :AIR : Exp:PAHAIR
276.0939 S:21 F:4 SMO(1,3) PKD(5,3,3,0.10%,100fljOLO,0.00%,F,T)
100% /«?) A7.74E8
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288.1692 S:21 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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278.1096 S:21 F:4 SMO(1,3) PKD(5,3,3,0.
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292.1974 S:21 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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10 Time
-------
File:290C98V4 #1-879 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 Text:301802-l :10X OIL. :AIR : Exp:PAHAIR
27
-------
File:29OC98V4 #1-879 Acq:30-OCT-1998 07:48:11 GC EI+ Voltage SIR 70SE
Sample#21 Text:301802-l :10X OIL. :AIR : Exp:PAHAIR
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)0 Time
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-I-429-2
Lab ID: 301802-0002-SA
Matrix: AIRTRAIN Sampled
Authorized: 29 SEP 98 Prepared
Dilution Factor: 1.0
22 SEP 98 Received: 29 SEP 98
03 OCT 98 Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a..
Perylene'
Indenon,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
120000
24000
36000
4300
16000
53000
4300
18000
13000
7000
12000
5200
3700
2600
1900
330
4300
1100
3800
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
B
D
D
BD
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
T 5
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-I-429-2
301802-0002-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 22 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzofb
Benzoik
Benzofa
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
75
58
64
43
98
62
73
64
53
95
66
103
70
75
91
80
% Recovery
103
D
D
D
m
D
D
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report
Rev 230787
.05
-------
04-NOV-1998 05:00:22-PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
Results : 290C98V4221.
• !f&.L2Jt-& it;g3t|SSgfet.^Sff^Sigg»a^^-s « * »a PTai'-ifn'-) *? - Vft2'™ffi*r§'*S^'S
Weight :t* 1-7 i-j':1D".:5 "ii: Total Isotbjfdv
"Name
dl 0 - 2 - Me t hy Inapht hal ene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 -Acenaphthylene
Acenaphthylene
dlO -Acenaphthene
Acenaphthene
dl 0 -Anthracene
dlO-Fluorene
Fluorene
dlO - Phenanthrene
Phenanthrene
Anthracene
d!4 -Terphenyl
dl 0 - Fluoranthene
Fluoranthene
dlO- Pyrene
Pyrene
d!2 -Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e) pyrene
d!2-Benzo (b) f luoranthene
Benzo (b) f luoranthene
d!2 -Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2-Benzo (a) pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2- Perylene
Perylene
d!2 - Indeno ( 12 3 - cd) pyrene
Indeno( 123 -cd) pyrene
d!4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2 -Benzo (ghi ) perylene
Benzo (ghi) perylene
f . • . 1 r
H4« i i; 1 1 ITl lit nnralfM Tim-r-nr- t—
'ml f ? f ffif f I *Pfpfff uoax.ne f s
Response Ratio
3711140
10509740
13241960000
1402202000
3715200
798294000
556866
59635000
8557100
5255240
991330000
18520000
6578680000
644164000
20776800
21887800
5509320000
23113800
372124COOO
12010700
1018480000
17560360
2305580000
45895600
21436600
1294000000
30286400
1290000000
23346400
996856000
485588000
15337980
87000000
19293060
514000000
10308660
158400000
21398400
818000000
W»«3AO
"iii i-Aftrnvvifii 2
f i ; f "iV^'M*!* I
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
,
I j
f"!
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
f^i
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
•Ytl
ii
'tf
RES
'" " : PAHAIR . TRG
«sS-a*i^*3Si
SEE
100X
43
1.16 1.6e+04 /^T
2 .81
0.89
0.80,
1.00
1.41
1.11
1.52
1.21
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
1.40
0.58
1.02
:£-£
38
^=^
^4345
•
50
37
_
36
r54
— x
.5)
.00
.34
ft ^^^.
SOt
.64
1.36+04
32
7040
33
.11
.05
.04
9hs!/%l. *•
ArvHS^
— AV-«>~/^-
73
E
64
X
66
1.26+04 ,B-
50
51
5171
34
3658
37
2602
1940
26
331
47
4290
45
1094
40
3762
.^
^TT?^
lllrr-S
.00
.46
.46
.80
.76
.59
.25
.27
.51
.01
.28
.44
.69
.78
.21
.46
•r Q
•H" T
103
yr
70
75
53
95
91
80
~. 3.L3-J ? f
i iPff^tf
-------
04-NOV-1998 05:00:18 PM Dioxin Furan- 'Unknown RESULTS
-^Elfc-/
MDL
126
SAT'D
B E
82
SEE
100X
20
SEE
100X
43
E
77
SAT'D
75
SAT'D
73
E
64
E
66
E
103
E
70
75
53
95
91
80
. . , ,, j.T.i
«f:i?i- 0.5
8Fr~"-- —
1855570
5254870
6620980000
701101000
1857600
399147000
278433
29817500
4278550
2627620
495665000
9260000
3289340000
322082000
10388400
10943900
2754660000
11556900
1860620000
6005350
509240000
8780180
1152790000
22947800
10718300
647000000
15143200
645000000
11673200
498428000
242794000
7668990
43500000
9646530
257000000
5154330
79200000
10699200
409000000
, *-.-
' - :- •'-'? ' - -•-' ' •' ; ; ' :
1855570
5254870
6620980000
701101000
1857600
399147000
278433
29817500
4278550
2627620
495665000
9260000
3289340000
322082000
10388400
10943900
2754660000
11556900
1860620000
6005350
509240000
8780180
1152790000
22947800
10718300
647000000
15143200
645000000
11673200
498428000
242794000
7668990
43500000
9646530
257000000
5154330
79200000
10699200
409000000
j jlt|| 1 1 itjijll jliUii '.'.',* : : " • it flSi -
t * I t :
IftiHtt
-------
03-NOV-1998 05:52:29 PM
429AIR Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 290C98V4- :---
Weight : 0.5
Name
dlO-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
• -.. . 410 r Fluoizene
-Fluorene
Results : 290C98V4221.RES :
Date analyzed :
301802-2 :10X DIL. : : : Ex Cal-i
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIR.TRG
29-OCT-98
- 'PAHAIR10-2998V4 .R
pg/ Rec/
SAMPLE MDL
3711140 1.00 Y 12: 28 Y
10509740 1.00 Y 10: 12 Y
13241960000 1.00 Y 10: 16 Y
1402202000 1.00 Y 12: 33 Y
3715200 1.00 Y 15: 27 Y
798294000 1.00 Y 15: 30 Y
556866 1.00 Y 16: 1 Y
59635000 1.00 Y 16 : 8 Y
8557100 1.00 Y 20: 55 Y
5255240 1.00 Y 17: 41 Y
991330000 1.00 Y 17: 46 Y
19292200 1.00 Y 20: 45 Y
6578680000 1.00 Y 20: 49 Y
644164000 1.00 Y 20: 58 Y
20776800 1.00 Y 26: 0 Y
21887800 1.00 Y 24: 35 Y
5509320000 1.00 Y 24: 39 Y
23113800 1.00 Y 25
3721240000 1.00 Y 25
12010700 1.00 Y 29
1018480000 1.00 Y 29
17560360 1.00 Y 29
2305580000 1.00 Y 29
45895600 1.00 Y 33
21436600 1.00 Y 32
2568140000 1.00 Y 32
30286400 1.00 Y 32:
2568140000 1.00 Y 32:
23346400 1.00 Y 33:
996856000 1.00 Y 33:
485588000 1.00 Y 33:
15337980 1.00 Y 33:
* No Peak 0.00 N 33:
19293060 1.00 Y 38:
724340000 1.00 Y 38:
10308660 1.00 Y 38:
166334400 1.00 Y 38:
21398400 1.00 Y 39:
861652000 1.00 Y 39:
._.. .5255240 1..QO.Y. 17:
*t7* 4390930 l-.OO-Y 17:
17 Y
20 Y
7 Y
12 Y
14 Y
19 Y
21 Y
28 Y
33 Y
33 Y
33 Y
31 Y
26 Y
37 Y
49 Y
54 N
0 Y
7 Y
5 Y
14 Y
12 Y
20 Y
1.00 50.00
2.24 63.19 126
1.23 l.Oe+05 0.000
0.56 2.4e+04 0.000
1.21 41.24 82
0.94 2.3e+04 0.000
0.74 10.08 20
1.25 8594.10 0.000
1.00 50.00
1.42 21.61 43
1.16 1.6e+04 0.000
2.81 40.15 80
0.89 3.8e+04 0.000
0.80 4171.63 0.000
1.00 50.00
1.41 37.34 75
1.11 2.3e+04 0.000
1.52 36.64 73
1.21 1.3e+04 0.000
0.90 32.11 64
1.20 7040.05 0.000
1.28 33.04 66
1.08 1.2e+04 0.000
1.00 50.00
0.45 51.46 103
1.17 l.Oe+04 0.000
0.95 34.80 70
1.16 7283.87 0.000
0.68 37.59 75
1.64 2602.25 0.000
1.07 1940.27 0.000
0.63 26.51 53
1.71 0.00 0.000
0.44 47.28 95
0.62 6046.18 0.000
0.25 45.69 91
1.40 1149.62 0.000
0.58 40.21 80
1.02 3963.24 0.000
.41. i ,i,..42.. .4.03 8
-46-Y- - —T T -L-.-OO * T - €-3 . 55 0 .000
c 103
-------
File:29OC98V4 #1-510 Acq:30-OCT-1998 08:37:13 GC EI+ Voltage SIR 70SE
Sample#22 Text:301802-2 :10X OIL. :: : Exp:PAHAIR
128.0626 S:22 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:29OC98V4 #1-510 Acq:30-OCT-1998 08:37:13 GC EI+ Voltage SIR 70SE
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File:290C98V4 #1-640 Acq:30-OCT-1998 08:37:13 GC Elt Voltage SIR 70SE
Sample#22 Text:301802-2 :10X DIL. : :: Exp:PAHAIR
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File:29OC98V4 #1-640 Acq:30-OCT-1998 08:37:13 GC EI+ Voltage SIR 70SE
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File:29OC98V4 #1-939 Acq:30-OCT-1998 08:37:13 GC EI+ Voltage SIR 70SE
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File:290C98V4 #1-878 Acq:30-OCT-1998 08:37:13 GC EI+ Voltage SIR 70SE
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File:290C98V4 #1-878 Acq:30-OCT-1998 08:37:13 GC EH- Voltage SIR 70SE
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-------
04-NOV-1998 03:07:13 PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC; Column : DB-5
Weight
Name
0.5
dlO-2-Methylnaphthalene
d8 -Naphthalene
Naphthalene
Results : 02N098V4101.RES
;--• = := .;. i i i *: i, Date analyzed
•||ti)|p2^S!§|lpSlt!Ji.= =r---: : Ex Ca=l=-;
Tota:l Isotope R. T. RRF
Response Ratio mm:ss
302000 1.00'"Y
508000 1.00 Y
745170000 1.00 Y
02.- 29 Y
10: 12 Y
10: 16 Y
; PAHAIR.TRG
•: 'rig/ Rec/
TRAIN MDL
1.00 50.00
2.24 37.54 l« Y
73468800 1.00 Y 15: Jl Y
143292 1.00 Y 16: 2 Y
7620000 1.00 Y 16: 7 Y
202000 1.00 Y 20: 55 Y
1.21 29.19
0.94 3.66+04
0-74 31.86
1.25 4267.58
1.00
50.00
dl0 -Phenanthrene
Phenanthrene
558000 1.00 Y
266236000 1.00 Y
20: 45 Y
20: 49 Y
2.81 49.20
0.89 5.3e+04
d!4-Terphenyl
dl0 -Fluoranthene
Fluoranthene
534000 1.00 Y
470000 1.00 Y
91496200 1.00 Y
26: 1 Y
24: 36 Y
24: 39 Y
1.00 50.00
1.41 31.19
1.11 1.88+04
Cf
/'
-------
4-NOV-1998 03:07:08 PM Dioxin Furan Unknown RESULTS
; -k :j liif-irssjijt sJi 2 2 '
151000
75 254000
B E 372585000
151000
254000
372585000
58
64
107000
36734400
71646
3810000
101000
107000
36734400
71646
3810000
101000
98 279000
B E 133118000
279000
133118000
62
267000
235000
45748100
267000
235000
45748100
T*""
-------
03-NOV-1998 08:33:30 AM
429AIR Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4101.RES
Date analyzed
301802-2 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
418344 1.00 Y 12: 29 Y
413156 1.00 Y 10: 12 Y
745170000 1.00 Y 10: 16 Y
88557800 1.00 Y 12: 34 Y
199044 1.00 Y •>." nr Y
73468800 1.00 Y 15: 31 Y
143292 1.00 Y 16: 2 Y
9442080 1.00 Y 16: 7 Y
181369 1.00 Y 20: 55 Y
150584 1.00 Y 17: 42 Y
1530162 1.00 Y 17: 47 Y
538016 1.00 Y 20: 45 Y
266236000 1.00 Y 20: 49 Y
* No Peak 0.00 N 20: 59 N
515862 1.00 Y 26: 1 Y
431102 1.00 Y 24: 36 Y
91496200 1.00 Y 24: 39 Y
487738 1.00 Y 25: 17 Y
53965600 1.00 Y 25: 21 Y
422002 1.00 Y 29: 9 Y
21731600 1.00 Y 29: 12 Y
587974 1.00 Y 29: 15 Y
66603200 1.00 Y
835210 1.00 Y 33: 23 Y
228304 1.00 Y 32: 29 Y
32515000 1.00 Y 32: 34 Y
541238 1.00 Y 32: 34 Y
32515000 1.00 Y 32: 34 Y
422678 1.00 Y 33: 32 Y
14489580 1.00 Y 33:. 27 Y
8103760 1.00 Y 33: 38 Y
91.735 1.00 Y 33: 51 Y
* No Peak ,. O.OQU 33: 36 N
.90541 1.00 Y 38: 3 Y.
10478100 l.OO Y 38: 9 Y
* No Peak 0.00 N 38: € N
2920500;;1.0Q Y 38: 16 Y
291436 1.00 Y 39: 15 Y
16019160 1.00 Y 39: 21 Y
150584 1.00 Y 17: 42 Y
* No Peak 0.00 N 17: 48 N
€
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
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TRAIN MDL
1.00 50.00
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1.25 5288.04 0.000
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1.16 875.60 0.000
2.81 52.83 106
0.89 5.5e+04 0.000
0.80 0.00 0.000
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1.41 29.62 59
1.11 1.9e+04 0.000
1.52 31.14 62
1.21 9181.68 0.000
0.90 45.45 91
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-------
Flle:02NO98V4 #1-510 Acq: 2-NOV-1998 20:34:33 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-510 Acq: 2-NOV-1998 20:34:33 GC E1+ Voltage SIR 70SE
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File:02NO98V4 #1-510 Acqt 2-NOV-1998 20:34:33 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-510 Acq: 2-NOV-1998 20:34:33 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 20:34:33 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 20:34:33 GC EI+ Voltage SIR 70SE
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-I-429-3
Lab ID: 301802-0003-SA
Matrix: AIRTRAIN Sampled
Authorized: 29 SEP 98 Prepared
Dilution Factor: 1.0
23 SEP 98 Received: 29 SEP 98
03 OCT 98 Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a ,
Perylene
Indeno (1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
160000
41000
33000
6300
18000
66000
9100
25000
18000
11000
18000
6100
3600
3300
1800
280
3900
980
4000
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BD
BD
D
D
BD
D
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-I-429-3
301802-0003-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 23 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzofb
Benzofk
Benzo(a
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
77
58
70
50
99
49
80
75
54
90
68
99
73
68
87
68
% Recovery
94
D
D
D
D
Dm
D = Compound quantitated using a secondary dilution.
m = Internal Standard recovery is outside method recovery goal,..
Reported By: Clark Pickell
Approved By::i Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-
-------
4-NOV-1998 04:56:30 PM
Dioxin Furan Unknown RESULTS
Results
290C98V4231.RES
. . Date.;
ass Spec : VG-4
r Column .:;rDB-5-;=I
ata
eight : '0" 5" -•^7" - Total Isotope
Name Response Ratio mm:ss
dlO-2-Methylnaphthalene
3132140 1.00 Y 12: 28 Y
: PAHAIR.TRG
Rec/
SAMPLE MDL
1.00 50.00
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
12-Benzo (b) f luoranthene
Benzo(b)fluoranthene
12-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
12 - Indeno (12 3 - cd) pyrene
Indeno(123 -cd)pyrene
14-Dibenz (ah) anthracene
Dibenz(ah)anthracene
dl2 -Benzo(ghi)perylene
Benzo(ghi)perylene
8497880
5992040
1233420000
18510260
7088220000
1341438000
19624660
23382400
6301600000
23884800
5274840000
13300020
1754802000
17052780
3397960000
42941600
19385000
1370000000
29788200
1236000000
19833040
1072592000
392810000
14616040
69000000
17111840
410000000
9231500
126400000
16911140
687614000
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
55
41
46
45
50
58
0
35
39
17
20
7
11
14
19
21
28
33
34
38
31
26
37
49
54
0
7
5
14
11
20
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.25
.40
.58
.02
50
24
.00
.81
l.Se+04
38
-
9054
50
42
-
40
.79
.19
.00
.23
.08
l.8e+04
37
.65
l.le+04
33
.97
1.8e+04
50
49
6054
36
3564
34
3295
1847
27
275
44
3858
43
975
33
4001
.00
.73
.65
.58
.23
.13
.96
.59
.00
.49
.82
.57
.73
.55
.97
.95
50
E
SAT^T
E
jd
SAT'D
80
E
75
E
68
E
99
E
73
68
54
90
87
68
t - * • T rt
D..Y
fiGf I
-------
04-NOV-1998 04:56:24 PM Dioxin Furan Unknown RESULTS
'M§§i *%j!gJBg i 3^^^ " g'i- i i j i i
-
-------
I2-NOV-1998 09:47:51 AM Dioxin Furan Unknown RESULTS
lass Spec : VG-4
iijC Column : DB-5
%ta file : 290C98V4
light : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
112-Benzo (b) f luoranthene
Benzo(b) fluoranthene
U2-Benzo(k) fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
112-Indeno (123 -cd) pyrene
Indeno(12 3 -cd)pyrene
114-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 290C98V4231.RES
Date analyzed
Cal
RRF
301802-3 :10
Total
Response
3132140
9950900
14849580000
1886674000
5457260
760106000
515556
86485400
8497880
5992040
1233420000
18510260
7088220000
1341438000
19624660
23382400
6301600000
23884800
5274840000
13300020
1754802000
17052780
3397960000
42941600
19385000
2624100000
29788200
2624100000
19833040
1072592000
392810000
14616040
* No Peak
17111840
574154000
9231500
188216600
16911140
687614000
5992040
4554900
X D
ISO
Rat
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
l.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
IL
tO]
io
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
. *
pe
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
•
R.
nun
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
E3
T.
ss
28
12
16
34
27
30
2
8
55
41
46
45
50
58
0
35
39
17
20
7
11
14
19
21
28
33
34
33
31
26
37
49
54
0
7
5
14
11
20
41
46
c
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
: PAHAIR.TRG
: 29-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMPLE MDL
1.00 50.00
2.24 70.89 142
1.23 1.2e+05 0.000
0.56 3.4e+04 0.000
1.21 71.77 144
0.94 1.5e+04 0.000
0.74 11.05 22
1.25 1.3e+04 0.000
1.00 50.00
1.42 24.81 50
1.16 1.8e+04 0.000
2.81 38.79 78
0.89 4.3e+04 0.000
0.80 9054.19 0.000
1.00 50.00
1.41 42.23 84
1.11 2.4e+04 0.000
1.52 40.08 80
1.21 1.8e+04 0.000
0.90 37.65 75
1.20 l.le+04 0.000
1.28 33.97 68
1.08 1.8e+04 0.000
1.00 50.00
0.45 49.73 99
1.17 1.2e+04 0.000
0.95 36.58 73
1.16 7567.06 0.000
0.68 34.13 68
1.64 3295.96 0.000
1.07 1847.59 0.000
0.63 27.00 54
1.71 0.00 0.000
C . 14 44.82 90
0..62 5403.45 0.000
0.25 43.73 87
1.40 1452.65 0.000
0.58 33.97 68
1.02 4001.95 0.000
1.42
4.91 10
76.02 0.000
-------
File:29OC98V4 #1-510 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X DIL. : : : Exp:PAHAIR
128.0626 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80
60 j
40-
20 1
0_
136.1
100?
80 1
60 j:
40.:
20 _
0
9:(
A7.4
2E9
I
/O ,
K*
\ ; •)••
0 10:1)0 11:00 12:bfl 13:00 14:6<) ' ,5.,
128 S:23 SMO(1,3) PKD(5,3,3,0 10%,10000.0,0.00%,F,T)
, A4.98E^
1
'
(V __
0 10:00 ll:bo 12:bo ' ' 13:1)0 ' 14:1)0 ^ 15:
^1.1E9
L8.6E8
6.4E8
L4.3E8
12.1E8
)0 Time
:8.8E5
^6.6E5
-4.4E5
-2.2E5
.O.OEO
10 Time
142.0782 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 j
60 1
40J
20 1
0
9:(
152.1
1002
80 J
60_
40 _
20:
0
9:0
A9.^
E8 p-t
-------
File:29OC98V4 #1-510 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X DIL. : : : Exp:PAHAIR
152.0626 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60-
40:
20 J
0-
14:
160.1
1003
80 J
60 1
40:
20 J
0
14:
A3.80E8
11 I/"
r
\
x-^ /--. J V A3.22E7
W 14:^2 14:24 14:36 14:48 15:66 15:12 15:24 15:36 15:48 16:6o 16:i2 16:24 16:36 16:48 I7:i
128 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
> A8.34E6
A
1
I \
1 \ A1.93E6 A273E6
^^^J ^-^—^/\^Y^^^ ^ A>2-^L^_
1)0 14:1(2 14:24 14:36 14:48 15:66 15:ii 15:24 15:36 15:48 16:6o 76:12 16:24 16:36 16:48 17:
-1.IE8
_8.8E7
.6.6E7
14.4E7
p.2E7
O.OEO
)0 Time
1.9E6
1.6E6
-1.2E6
-7.SES
3.9E5
O.OEO
)0 Time
154.0782 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.94E7
80 J
60:
40:
20 J
0
A4.32E7
A1.02E7
i i I i i i i r i i I i vi 'i i ii i i I r I i i i i i i i r i i—i-T-r
14:00 14:12 14:24 14:36 14:48 15:6o 15:12
164.1410 S:23 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
804
60
40
20_
0-
14:
A8.84E4
^14:ii 14:^4 14:^6 14-58 15^00 IS-E
-i—i—i—i—i—i i—i—r—i——i—i-i— r T- ,—r-r-i i i i—i i i [-i—
15:36 15:48 16:00 16:12 16:24
16
^
16:48 ^ 17:
A4.20E4
16:48 17:1
:1.7E7
:1.3E7
:8.5E6
-4.3 E6
O.OEO
)0 Time
I.1E5
8.8E4
6.6E4
4.4E4
-2.2E4
O.OEO
)0 Time
-------
Flle:29OC98V4 #1-510 Acq:30-OCT-I998 09:26:14 GC E1+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X DIL. : :: Exp:PAHAIR
130.9920 S:23 SMO(1,3) PKD(5,3,3,0.10%,IOOOO.O,0.00%,F,T)
100 % A7.9DE8
95.:
90 J
851
80:
15-
70-
65-
60
55 J
50 J
45
40
35
30
25
20
15
10
5
0
., p6Eg
'
10:6o
ll:6o
12:1)0
13:
14:1)0
15:00
16:1)0
17
4.4E8
4.2E8
4.0E8
.3.8E8
3.3E8
3.1E8
-2.9E8
:2.7E8
2.4E8
L2.2E8
2.0E8
I.8E8
L1.5E8
-1.3E8
1.1E8
-8.8E7
-6.6E7
L4.4E7
-2.2E7
lO.OEO
)0 Time
-------
FHe:29OC98V4 #1-640 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage SIR 70SE
oui»|jicn'^^ • CAI. jviov/^.-j *i.u^v ISJ.L*. . . . c/A|i;r /in./\i_K ^ -%
1 66.0798 S:23 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T) •' \
100%
90 J
80. ;
70 -.
60 J
50 J
40 J
30 J
20 1
10.;
OJ
17:
A6.17E8
ft
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ici 17:i2 17:24 17:36 17:48 18:66 18:h 18:24 18:36 18:48 19:66 19:1(2 19:24 19:36 19:48 20:1
:.2.4E8 S<
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-1.4E8
_1.2E8
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_2.4E7
O.OEO
)0 Time
172.0984 S:23 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100?
90 ;
80 J
70 j
60 J
50 J
40 J
30_
20 _
10_
0
17:
A2.28E6
rt
/
1 M
j 1
y v_ _
00 17:i2 17:24 17:36 17:48 18:66 18:ii 18:24 18:36 18:48 19:66 19:i2 19:24 19:36 19:4(8 20:
9.3E5
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L7.4E5
: 6.5E5
-5.6E5
\ 4.6E5
13.7E5
L2.8E5
L1.9E5
L9.3E4
- O.OEO
10 Time
176.1410 S:23 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100?
90_
80.
70 J
60 _
50 ;
40
30 J
20 -
10J
17:
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H '
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60 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36 18:48 19:00 19:12 19:24 19:36 19:48 20:
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L7.2E5
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• WEtV
>0 Time
-------
File:29OC98V4 #1-640 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X OIL. : : : Exp:PAHAIR
178.0782 S:23 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
90 J
80 J
70 J
60 1
50 J
40j
3Q-
20-
10 -:
0:
19:
188.1
1003
90 J
80 J
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L3.7E6
;.3.3E6
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1.3
-------
File:29OC98V4 #1-640 Acq:30-OCT-l998 09:26:14 GC EI+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X OIL. : : : Exp:PAHAlR
L-J
U**.7OO
00 S>
:
95;
90;
85;
80;
75;
70.
65;
60;
55;
50;
45;
40;
35;
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25;
20;
15;
10;
5;
o_
17 0
o j,*.j r;
-------
File:29OC98V4 #1-939 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage
Sample#23 Text:301802-3 :10X OIL.: : : Exp:PAHAIR
202.0782 S:23 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A3
90 J
801
70 J
60 J
50 J
40
30
20
10 j
0
A2.64E9
^1.1E9
9.7E8
8.6E8
7.5E8
F6.4E8
5.4E8
4.3E8
3.2E8
2.1E8
1.1E8
O.OEO
)0 Time
23:00 24:00
212.1410 S:23 F:3 SMO(1,3) PKD(5,: 3,0.10%,10000.0,0.00%,F,T)
25:00
26:00
27:
100 9
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10 J
0:
23:
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5.1E6
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L2j.O|E6
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I.OE6
L5.1E5
O.OEO
»0 Time
244.1974 S:23 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
90 J
80 J
70 J
60-
50
40
30_
20_
10-
0
23:
A9.8
E6
x
10 24:00 25:6fl 26:6o 27:
3.8E6
L.3.4E6
L3.0E6
L2.7E6
2.3E6
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- 7.6E5
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O.OEO
)0 Time
-------
File:2«
Samp)
228.0$
100 2
90 J
80 J
70-
60 -
50 J
40 J
30 J
20-
10
0
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File:29OC98V4 #1-878 Acq:30-OCT-1998 09:26:14 GC EI+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X DIL. : : : Exp:PAHAI
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FIle:29OC98V4 #1-878 Acq:30-OCT-1998 09:26:14 GC E1+ Voltage SIR 70SE
Sample#23 Text:301802-3 :10X OIL.: : : Exp:PAHAlR
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-------
04-NOV-1998 05:09:30 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4111.RES
Date analyzed
301802-3 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
289378 1.00 Y 12
498000 1.00 Y 10
961520000 1.00 Y 10
114770200 1.00 Y 12
202984 1.00 Y 1*
64111400 1.00 Y IS
150263 1.00 Y 16
11882380 1.00 Y 16
166005 1.00 Y 20
28 Y
12 Y
16 Y
34 Y
?B Y
31 Y
2 Y
7 Y
55 Y
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 38.40 77
1.23 1.66+05 B »
0.56 4.1e+04 B
1.21 28.90 58
0.94 3.36+04
0.74 34.87 70
1.25 6346.01
1.00
50.00
dlO-Phenanthrene
Phenanthrene
d!4-Terpheny1
dlO-Fluoranthene
Fluoranthene
462260 1.00 Y
272442000 1.00 Y
542000 1.00 Y
374000 1.00 Y
103869200 1.00 Y
20: 45 Y
20: 49 Y
26: 2 Y
24: 35 Y
24: 39 Y
2.81 49.59 99
0.89 6 . 6e+04 B if
1.00 50.00
1.41 24.46
1.11 2.56+04
49 I
df
-------
04-NOV-1998 05:09:26 PM Dioxin Furan Unknown RESULTS
MDL
77
B E
B
58
70
144689
249000
480760000
57385100
101492
32055700
75132
5941190
83002
.-.. i=a
:'*••-; -?t •»-*-« - •'"
144689
249000
480760000
57385100
101492
32055700
75132
5941190
83002
99 231130
B E 136221000
231130
136221000
49
271000
187000
51934600
271000
187000
51934600
TtT-r-- - ?! fttttrttf rtttiit T t fftTF'
- T II TTTtl T ! I n tftttttf tHilt t: J tftl T
-------
03-NOV-1998 08:37:07 AM
429AIR Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4111.RES
Date analyzed
301802-3 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
289378 1.00 Y 12: 28 Y
444984 1.00 Y 10: 12 Y
961520000 1.00 Y 10: 16 Y
114770200 1.00 Y 12: 34 Y
202984 1.00 y 1C• 28 Y
64111400 1.00 Y 15: 31 Y
150263 1.00 Y 16: 2 Y
11882380 1.00 Y 16: 7 Y
166005 1.00 Y 20: 55 Y
75455 1.00 Y 17: 41 Y
1165690 1.00 Y 17: 46 Y.
462260 1.00 Y 20: 45 Y
272442000 1.00 Y 20: 49 Y
* No Peak 0.00 N 20: 59 N
501878 1.00 Y 26: 2 Y
314968 1.00 Y 24: 35 Y
103869200 1.00 Y 24: 39 Y
415390 1.00 Y 25:
72381000 1.00 Y 25:
327288 1.00 Y 29:
33901000 1.00 Y 29:
469998 1.00 Y 29:
90611800 1.00 Y 29:
794292 1.00 Y. 33:
252920 1.00 Y 32:
31804200 1.00 Y" 32.:
287312 1.00 Y 32:
31804200-1.00 Y 32:
341496 l.QOv'Y 33:
13925560 l.QO Y . 33:
6532300 1.00 Y :33.:
17 Y
20 Y
8 Y
12 Y
15 Y
19 Y
21 Y
29 Y
34 Y
35 Y
34 Y
33 Y
27 Y
38 Y
*. No Peak
* No Peak
0.00 N 33-:
0.00-N 33:
121G46 1.00 Y 38:
7905860 1.00 Y 38;
* No Peak 0.00 N 38:
2401180 1.00 Y 38i
175940 1.00 Y 39
12347540 1.00 Y 39
75455 1.00 Y 17
57304 1.00 Y 17
N
.54 N
2 Y
9 Y
4 N
17 Y-.
14 Y
22 Y
41 Y
46 Y
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 34.31 69
1.23 1.86+05 0.000
0.56 4.66+04 0.000
1.21 28.90 58
0.94 3.36+04 0.000
0.74 34.87 70
1.25 6346.01 0.000
1.00 50.00 I
1.42 15.99 32 1
1.16 1331.20 0.000 |
2.81 49.59 99 i
0.89 6.66+04 0.000
0.80 0.00 0.000
r
1.00 50.00 L
1.41 22.24 44 f
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1.52 27.26 55
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0.90 36.23 721
1.20 8599.51 0.000
1.28 36.60
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1.00, 50.00 i
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1.00 7-5~94 0.000
-------
File:02NO98V4 #1-509 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
Sampled! 1 Text:301802-3 :100X OIL. : : : ExprPAHAIR
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-------
3-02NO98V4 #1-509 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
' "11 Text:301802-3 :100X OIL. : : : Exp:PAHAIR
3:11 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-509 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
Sample#ll Text:301802-3 :100X DIL. : : : Exp:PAHAlR
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1002
80 J
601
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164.1410 S:ll SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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80
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2.IE6
1.7E6
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1.9E4
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0 Time
-------
0
FiIe:02NO98V4 #1-509 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
SaHiple#ll Text:301802-3 :100X DIL. : : : Exp:PAHAIR
130.9920 S:ll SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95 J
90 J
851
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0 Time
-------
File:02NO98V4 #1-641 Acq: 2-NOV-1998 21:23:33 GC E1+ Voltage SIR
Sample#ll Text:301802-3 :100X OIL. : : : Exp:PAHAIR
166.0798 S:ll F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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172.09848:11 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
17:12 17:24
F:2 SMO(1,3)
-------
File:02NO98V4 #1-641 Acq: 2-NOV-1998 21:23:33 GC E1+ Voltage SIR 70SE
Saim)le#ll Text:301802-3 :100X OIL.: : : Exp:PAHAIR
178.0782 S:ll F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-641 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-939 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
Sampled! 1 Text:301802-3 :100X OIL. : : : ExprPAHAIR
202.0782 S:ll F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Saflirile#ll Text:301802-3 :100X OIL. : : : Exp:PAHAIR
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fe02NO98V4 #1-939 Acq: 2-NOV-1998 21:23-33 GC E1+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-939 Acq: 2-NOV-1998 21:23:33 GC E1+ Voltage SIR 70SE
Sample*!! Text:301802-3 :100X OIL. : : : Exp:PAHAIR
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-------
File:02NO98V4 #1-939 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
Samplelll Text:301802-3 :100X OIL. : : : Exp:PAHAIR
230.9856 S:ll F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 21:23:33 GC E1+ Voltage SIR 70SE
Saitiplelll Text:301802-3 :100X DIL. : : : Exp:PAHAlR
252.0939 S:ll F:4 SMO(1,3) PKD(5,3,3J0.10%,10000.0,0.00%,F,T)
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-------
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 21:23:33 GC EI+ Voltage SIR 70SE
Samplei?ll Text:301802-3 :100X OIL. : : : Exp:PAHAIR
276.0939 S:ll F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 21:23:33 GC E1+ Voltage SIR 70SE
Sampled 1 Text:30I802-3 :100X DIL. : : : Exp:PAHAIR
268.9824 S:ll F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-0-429-1
Lab ID: 301802-0004-SA
Matrix: AIRTRAIN Sampled
Authorized: 29 SEP 98 Prepared
Dilution Factor: 1.0
21 SEP 98 Received: 29 SEP 98
03 OCT 98 Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a..
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
290000
55000
50000
7000
21000
66000
20000
32000
16000
290
740
200
200
130
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
--
--
--
--
100
100
100
100
100
BD
B
BD
B = Compound is also detected in tire blank.
D = Compound quantitated using a secondary dilution.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Rettaran
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-0-429-1
Lab ID: 301802-0004-SA
Matrix: AIRTRAIN Sampled: 21 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphtha! ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
b)fluoranthene-d!2
kjfluoranthene-dl2
a)pyrene-d!2
Benzo
Benzo
Benzo
Dibenz(a',h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
92
90
74
69
99
69
70
81
60
81
79
88
87
77
77
69
% Recovery
124
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
04-NOV-1998 05:20:20 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4071.RES
Date analyzed
301802-4 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio miruss
7457740 1.00 Y
9240880 1.00 Y
16866340000 1.00 Y
2860720000 1.00 Y
8161300 1.00 Y
3825700000 1.00 Y
4122640 1.00 Y
360320000 1.00 Y
4943880 1.00 Y
4844600 1.00 Y
1184008000 1.00 Y
11013880 1.00 Y
6958000000 1.00 Y
1740686000 1.00 Y
12499040 1.00 Y
12185280 1.00 Y
4313220000 1.00 Y
13191400 1.00 Y
2604420000 1.00 Y
9067480 1.00 Y
31934600 1.00 Y
12696540 1.00 Y
102244400 1.00 Y
23610600 1.00 Y
9475040 1.00 Y
22600000 1,00 Y
19441240 .1.00 Y
45000000 1.00 Y
12272020 1.00 Y
25393.800 1.00 Y
10389580 1.00 Y
8936560 l.OD Y
* No Peak O.OOJS..33
34859€t> 1.00 Y
5621240 1.00 Y
4440720 1.00. Y,.. 38
798102 1.00 Y 38
9383680 1.00 Y
9286240 1.00 Y
4844600 1.00 Y
4864380 1.00 Y
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
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39.67
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50.00
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292.39
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742.91
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44.21
204.34
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198.83
38.41
126.11
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40.43
-------
I4-NOV-1998 05:20:16 PM Dioxin Furan Unknown RESULTS
0.5
I8V4.RRF
Rec/
MDL
3728870
55 4620440
SAT'D 8433170000
B E 1430360000
90 4080650
E 1912850000
3728870
4620440
8433170000
1430360000
4080650
1912850000
74
E
69
E
2061320
180160000
2471940
2422300
592004000
2061320
180160000
2471940
2422300
592004000
79 5506940
SAT'D 3479000000
E 870343000
6249520
69 6092640
E 2156610000
70 6595700
E 1302210000
5506940
3479000000
870343000
6249520
6092640
2156610000
6595700
1302210000
100
100
100
100
100
81
79
88
87
77
.00
60
.00
81
.00
77
.00
69
.00
4533740
15967300
6348270
51122200
11805300
4737520
11300000
9720620
22500000
6136010
12696900
5194990
4468280
0
4242980
2810620
2220360
399051
4691840
4643120
4533740
15967300
6348270
51122200
11805300
4737520
11300000
9720620
22500000
6136010
12696900
5194990
4468280
0
4242980
2810620
2220360
399051
4691840
4643120
>» '-•
-------
02-NOV-1998 08:45:21 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4071.RES
Date analyzed
301802-4 :10X DIL. : : : Ex Cal
Total Isotope _ JE. -T. RRF
Response Ratio fnihrS'S'
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2 -Indeno(12 3 -cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
7457740 1.00 Y 12
9240880 1.00 Y 10
16866340000 1.00 Y 10
2860720000 1.00 Y 12
8161300 1.00 Y
3825700000 1.00 Y
4122640 1.00 Y
360320000 1.00 Y
4943880 1.00 Y
4844600 1.00 Y
1184008000 1.00 Y
11013880 1.00 Y
6958000000 1.00 Y
1740686000 1.00 Y
12499040 1.00 Y
12185280 1.00 Y
4313220000 1.00 Y
13191400 1.00 Y
2604420000 1.00 Y
9067480 1.00 Y
31934600 1.00 Y
12696540 1.00 Y
102244400 1.00 Y
23610600 1.00 Y
9475040 1.00 Y
S7298200 1.00 Y
19441240 1,00 Y
67298200 1,00 Y
122J2020 1.00 Y
25393800 1.00 Y
10389980 r.OO Y
8936550 1^0 Y
* Nc* Peak 0.00 N
8485960 1.00 Y
5621240 1.00 Y
4440720 1.00 Y
:. ,798102 1.00 Y
9383680 1.00 Y
9286240 1.00 Y
4844600 1.00 Y
4864380 1.00 Y
27 Y
12 Y
17 Y
34 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
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-------
Flle:30OC98V4 #1-510 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
Sample#7 Text:301802-4 :10X OIL.::: Exp:PAHAIR
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File:30OC98V4 #l-5l» Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-641 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-939 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
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-------
File:30OC98V4 #1-939 Acq:30-OCT-1998 21:39:37 GC £1+ Voltage SIR 70SE
Sampled? Text:301802-4 :10X DIL.: :: Exp:PAHAIR
228.0939 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FUe:30OC98V4 #1-939 Acq;30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
Sample*? Text:301802-4 :10X OIL.::: ExprPAHAIR
230.9856 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
IOC98V4 #1-878 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
e#7 Text:301802-4 :10X OIL. :: : Exp:PAHAIR
i( 939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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j; 32:26 32:28 32:30 32:32 32:34 32:36 32:38 32:40 32:42 3&4432:46, 32:48 32:^0 ' 32:h
2641692 S:7 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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FIIe:30OC98V4 #1-878 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
Sample#7 Text:301802-4:10X OIL.::: Exp:PAHAIR
252.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,ljDOOO.O,0.00%,F,T)
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31:00 32:00 33/00 34:6fl
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FUe:30OC98V4 #1-878 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
Sampled Text:301802-4 :10X DIL.::: Exp:PAHAIR
276.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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288.1692 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 21:39:37 GC EI+ Voltage SIR 70SE
Sample*? Text:301802-4 :10X OIL.:: : Exp:PAHAIR
268.9824 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
04-NOV-1998 05:24:48 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
Results : 02N098V4121.RES
Date analyzed
301802-4 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio tnmrss
368292 1.00 Y 12: 28 Y
758000 1.00 Y 10: 12 Y
2696480000 1.00 Y 10: 16 Y
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 45.93
1.23 2.96+05 B
dl0-Anthracene
252000 1.00 Y 20: 55 Y
1.00 50.00
dlO-Phenanthrene 703560 1.00 Y 20: 45 Y
Phenanthrene 415930000 1.00 Y 20: 49 Y
2.81 49.72 9
0.89 6.6e+04 B
Cf
203
-------
04-NOV-1998 05:24:45 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
184146 184146
92 379000 379000
B E 1348240000 1348240000
126000 126000
99 351780 351780
B E 207965000 207965000
-------
03-NOV-1998 08:40:26 AM
429AIR Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4121.RES
Date analyzed
301802-4 :100X OIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
368292
567694
2696480000
*
*
*
*
*
*
*
*
*
227550000
314266
178146800
132801
23286400
208312
171793
2357760
703560
415930000
No Peak
609830
480184
74667600
534432
47295400
385960
906706
632880
6244520
811912
No Peak
602824
566782
602824
No Peak
394882
33591
139 OBO
No -Peak
No Peak
No Peak
No Peak
No Peak
No Peak
201974
171793
98612
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1
1
1
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1
1
0
1
1
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0
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0
0
0
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.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
if
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
K
Y
Y
Y
N
N
N
N
N
N
Y
Y
Y
12
10
10
-J.2
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
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18
23
25
31
39
38
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35
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40
53
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4
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18
16
27
41
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Y
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Y
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Y
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N
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Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
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N
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y f-
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N
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34.40 69
3.96+05 0.000
7.26+04 0.000
35.15 70
6.06+04 0.000
24.21 48
1.46+04 0.000
50.00
29.02 58
1182.61 0.000
60.15 120
6.6e+04 0.000
0.00 0.000
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27.91 56
1.46+04 0.000
28.86 58
7343.75 0.000
35.16 70
195.04 0.000
40.57 81
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-4 :100X OIL.::: Exp:PAHAIR
12S.0626 S:12 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
O98V4 #1-510 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
"2 Text:301802-4 :100X OIL. :: : Exp:PAHAIR
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9:24 9:36 9:48 10:
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-4 :100X OIL.::: Exp:PAHAIR
152.0626 S:12 SMO(1,3) PKD(5,3,3)0.10%,10000.0>0.00%,F,T)
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-939 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-4 :100X DIL.::: Exp:PAHAIR
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File:02N098V4 #1-878 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
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FYJe:02NO98V4 #1-878 Acq: 2-NOV-1998 22:12:35 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-4 :100X OIL.::: Exp:PAHAIR
268.9824 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Pacific Environmental
A-0-429-2
301802-0005-SA
Services
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 22 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a
Perylene'
Indeno(1,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
95000
24000
22000
2500
7500
45000
3300
14000
8100
240
640
180
160
ND
ND
ND
ND
ND
ND
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
—
--
._
--
--
„_
--
--
--
--
--
--
--
100
100
100
100
100
100
B
B
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-0-429-2
301802-0005-SA
AIRTRAIN Sampled: 22 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzolk)fluoranthene-d!2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
46
75
72
75
88
58
56
75
58
73
80
94
88
76
64
76
% Recovery
112
m
m = Internal Standard recovery is outside method;recovery goal. . ,^
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
20
-------
04-NOV-1998 05:31:10 PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 300C98V4
Weight : 0.5
Name
dlO - 2 -Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8 -Acenaphthylene
Acenaphthylene
dl 0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b) fluoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2 - Tr.deno (12 3 - cd) pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
l3C-Fluorene
Results : 300C98V4081.RES
Date analyzed
301802-5 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
7316240
7460000
8681940000
1024468000
6663040
1401130000
3898840
121433800
4982580
5320500
465870000
12360000
4940660000
324000000
16072880
13106960
2079300000
13659420
1340422000
10861060
31010600
16374560
113356000
25048600
10713240
22600000
20931000
38200000
12894700
20855800
6581120
9142680
* No Peak
8143820
4029580
3945700
889532
11051780
7159360
5320500
4818080
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
n
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1
1
1
1
1
1
1
.00
.00
.00
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.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
•\r
x
Y
Y
Y
Y
Y
Y
Y
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
27
12
16
34
27
30
1
8
54
41
46
45
49
58
0
35
39
17
20
9
12
15
20
22
30
35
35
38
34
28
39
51
55
4
11
8
18
14
23
41
46
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
V
Y
Y
Y
Y
Y
Y
Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 22.75 46
1.23 9.56+04 B E
0.56 2.46+04 B E
1.21 37.52 75
0.94 2.26+04 E
0.74 35.78 72
1.25 2499.50
1.00 50.00
1.42 37.58 75
1.16 7545.02 E
2.81 44.18 88
0.89 4.56+04 B E
0.80 3275.05
1.00 50.00
1.41 28.90
1.11 1.46+04
1.52 27.99
1.21 8143.31
E
E
0.90
1.20
1.28
1.08
37.54
237.04
39.82
638.64
1.00 50.00
0.45 47.12
1.17 180.73
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
1.40
0.58
1.02
1.00
0.8-1
C
44.07
156.77
58
i
56
I
75
80
94
88
38.04 76
-------
04-NOV-1998 05:31:06 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
3658120 3658120
46 3730000 3730000
B E 4340970000 4340970000
B E 512234000 512234000
75
E
72
75
E
88
B E
58
E
56
E
75
80
94
88
76
100.00
100.00
58
100.00
73
100.00
64
100.00
76
100.00
3331520
700565000
1949420
60716900
2491290
2660250
232935000
6180000
2470330000
162000000
8036440
6553480
1039650000
6829710
670211000
5430530
15505300
8187280
56678000
12524300
5356620
11300000
10465500
19100000
6447350
10427900
3290560
4571340
0
4071910
2014790
1972850
2014790
5525890
3579680
3331520
700565000
1949420
60716900
2491290
2660250
232935000
6180000
2470330000
162000000
8036440
6553480
1039650000
6829710
670211000
5430530
15505300
8187280
56678000
12524300
5356620
11300000
10465500
19100000
6447350
10427900
3290560
4571340
0
4071910
2014790
1972850
444766
5525890
3579680
-------
02-NOV-1998 08:48:47 AM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 30OC98V4
Weight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benz o (e)pyrene
Benz o(a)pyrene
d!2-Perylene
Perylene
dl2-Indeno(123-cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4081.RES
Date analyzed
301802-5 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio iratuss
7316240 1.00 Y 12: 27 Y
6713680 1.00 Y 10: 12 Y
8681940000 1.00 Y 10: 16 Y
1024468000 1.00 Y 12: 34 Y
6663040 1.00 Y 15: 27 Y
1401130000 1.00 Y 15: 30 Y
3898840 1.00 Y 16: 1 Y
121433800 1.00 Y 16: 8 Y
4982580 1.00 Y 20: 54 Y
5320500 1.00 Y 17: 41 Y
465870000 1.00 Y 17: 46 Y
12661800 1.00 Y 20: 45 Y
4940660000 1.00 Y 20: 49 Y
* No Peak 0.00 N 20: 58 N
16072880 1.00 Y 26: 0 Y
13106960 1.00 Y 24: 35 Y
2079300000 1.00 Y 24: 39 Y
13659420 1.00 Y 25: 17 Y
1340422000 1.00 Y 25: 20 Y
10861060 1.00 Y 29: 9 Y
31010600 1.00 Y 29: 12 Y
16374560 1.00 Y 29: 15 Y
113356000 1.00 Y 29: 20 Y
25048600 1.00 Y 33: 22 Y
10713240 1.00 Y 32: 30 Y
60963600 1.00 Y 32: 35 Y
20931000 1.00 Y 32: 35 Y
60963600 1.00 Y 32: 35 Y
12894700 1.00 Y 33: 34 Y
20855800 1.00 Y 33: 28 Y
6581120 1.00 Y 33: 39 Y
9142680 1.00 Y 33: 51 Y
* No Peak 0.00 N 33: 55 N
8143820 1.00 Y 38: 4 Y
4029580 1.00 Y 38: 11 Y
3945700 1.00 Y 38: 8 Y
889532 1.00 Y 38: 18 Y :
11051780 1.00 Y 39: 14 Y
7159360 1.00 Y 39: 23 Y
5320500 1.00 Y 17: 41 Y
4818080 1.00 Y 17: 46 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 20.48 41
1.23 l.le+05 0.000
0.56 2.7e+04 0.000
1.21 37.52 75
0.94 2.2e+04 0.000
0.74 35.78 72
1.25 2499.50 0.000
1.00 50.00
1.42 37.58 75
1.16 7545.02 0.000
2.81 45.26 91
0.89 4.4e+04 0.000
0.80 0.00 0.000
1.00 50.00
1.41 28.90 58
1.11 1.46+04 0.000
1.52 27.99 56
1.21 8143.31 0.000
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
64
07
0.63
1.71
C.44
:0,62
-0 .25
1.40
0.58
1.02
1.42
1.00
37
237
39
638
50
47
487
44
250
38
98
47
28
0
-36
79
•16
38
63
7
90
.54
.04
.82
.64
.00
.12
.51
.07
.19
.04
.57
.61
.96
.00
.57
.68
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.06
.05
.76
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.56
0
0
0
0
0
0
0
0
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0
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80
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94
.000
88
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76
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58
.000
73
.000
64
.000
76
.000
15
.000
-------
File:30OC98V4 #1-510 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sample*® Text:301802-5 :10X DIL. :: : Exp:PAHAIR
128.0626 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
142.0782 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FiIe:30OC98V4 #1-510 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
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152.0626 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
F11e:30OC98V4 #1-510 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sampled Text:301802-5 :10X OIL.::: Exp:PAHAIR
130.9920 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FUe:30OC98V4 #1-641 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sampled Text:301802-5 :10X OIL. ::: Exp:PAHAIR
166.0798 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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172.0984 S:8 F:2 SMO(1,3) PKD(5,3 3,0.10%,10000.0,0.00%,F,T)
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176.1410 S:8 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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FUe:30OC98V4 #1-641 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sampled Text:301802-5 :10XDIL.::: Exp:PAHAIR
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-------
DOC98V4 #1-641 Acq:30-OCT-1998 22:28:39 GC EH- Voltage SIR 70SE
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Flle:30OC98V4 #1-641 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sampled Text:301802-5 :10X OIL.:: : Exp:PAHAIR
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-------
FJle:30OC98V4 #1-938 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
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FUe:30OC98V4 #1-938 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
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FHe:30OC98V4 #1-878 Acq:30-OCT-1998 22:28:39 GC El-I- Voltage SIR 70SE
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File:30OC98V4 #1-878 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 22:28:39 GC EI+ Voltage SIR 70SE
Sampled Text:301802-5 :10X OIL. ::: Exp:PAHAIR
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-0-429-3
301802-0006-SA
AIRTRAIN Sampled: 23 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 30 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo a)pyrene
Perylene
Indent) (1,2,3 -cd) pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
110000
36000
17000
3500
8800
27000
5100
12000
6400
240
690
210
140
110
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/saraple
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
--
--
--
--
--
--
100
100
100
100
100
BD
B
BD
B = Compound is also detected in the blank.
D = Compound quantitated using a secondary dilution.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
;Q
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-0-429-3
Lab ID: 301802-0006-SA
Matrix: AIRTRAIN Sampled: 23 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 30 OCT 98
Internal Standards
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b|fluoranthene-dl2
Benzolkjfluoranthene-d!2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
65
85
82
75
107
69
63
80
58
80
85
88
87
73
81
66
% Recovery
117
D = Compound quantitated using a secondary dilution.
Reported By: Clark Pickell Approved By: Erie Redman
The cover letter is an integral part of this report.
Rev 230787
240
-------
04-NOV-1998 05:35:54 PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 300C98V4
Weight : 0.5
Name
dlO -2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2 - Indeno (12 3 - cd) pyrene
Indeno(123 -cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 300C98V4091.RES
Date analyzed
301802-6 :10X DIL. :
Total Isotope
Response Ratio
6247200 1.00 Y
5191140 1.00 Y
8214020000 1.00 Y
1057434000 1.00 Y
6416360 1.00 Y
1053276000 1.00 Y
3816800 1.00 Y
167765400 1.00 Y
4361140 1.00 Y
4675320 1.00 Y
478978000 1.00 Y
11780000 1.00 Y
5372860000 1.00 Y
480000000 1.00 Y
13510060 1.00 Y
13174340 1.00 Y
1730908000 1.00 Y
12865500 1.00 Y
984552000 1.00 Y
9716100 1.00 Y
28070400 1.00 Y
14713300 1.00 Y
109988000 1.00 Y
25220400 1.00 Y
10080440 1.00 Y
24200000 1.00 Y
20916200 1.00 Y
34800000 1.00 Y
12479520 1.00 Y
22107800 1.00 Y
7248280 1.00 Y
9256060 1.00 Y
* No Peak 0.00 N
9019300 1.00 Y
4096560 1.00 Y
5021960 1.00 Y
681544 1.00 Y
9675900 1.00 Y
7685780 1.00 Y
4675320 1.00 Y
4440900 1.00 Y
PAHAIR.TRG
30-OCT-98
:
R.
mm
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
Ex Cal :
T.
ss
28
12
16
34
28
30
1
7
55
41
47
45
49
59
0
35
39
17
20
8
13
15
20
22
30
34
35
38
34
28
39
51
55
4
11
9
16
14
23
41
46
RRF
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y .-..
Y '-• .
Y • :
Y
Y
Y
Y
Y
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
-0
•0
.1
0
1
1
0
PAHAIR102998V4.R
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.-25
.40
.58
.02
.00
.81
pg/ Rec/
SAMP MDL
50.00
18.54 yt-
3.6e+04 B E
42.31 85
1.7e+04 E
41.03 82
3527.38
50.00
37.72 75
8827.80 E
48.10 >6<
S^D
5090.82 E
50.00
34.56 69
1.2e+04 E
31.36 63
6350.44 E
39.95 80
239.85
42.57 85
689.63
50.00
44.03 88
205.67
43.74 87
142.92
36.56 73
107.97
« 117
-------
04-NOV-1998 05:35:50 PM Dioxin Furan Unknown RESULTS
0.5
9 8V4.RRF
Rec/
MDL
3123600 3123600
37 2595570 2595570
SAT'D 4107010000 4107010000
B E 528717000 528717000
85
E
82
75
E
96
SAT'D
E
69
E
63
E
80
85
88
87
73
100.00
58
100.00
80
100.00
81
100.00
66
100.00
3208180
526638000
1908400
83882700
2180570
2337660
239489000
5890000
2686430000
240000000
6755030
6587170
865454000
6432750
492276000
4858050
14035200
7356650
54994000
12610200
5040220
12100000
10458100
17400000
6239760
11053900
3624140
4628030
0
4509650
2048280
2510980
340772
4837950
3842890
3208180
526638000
1908400
83882700
2180570
2337660
239489000
5890000
2686430000
240000000
6755030
6587170
865454000
6432750
492276000
4858050
14035200
7356650
54994000
12610200
5040220
12100000
10458100
17400000
6239760
11053900
3624140
4628030
0
4509650
2048280
2510980
340772
4837950
3842890
243
-------
02-NOV-1998 08:52:06 AM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
GC Column : DB-5
Data file : 300C98V4
Weight : 0.5
Name
dlO - 2 -Methy Inaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) f luoranthene
Benzo(k)fluoranthene
dl 2-Benz o(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 30OC98V4091.RES
Date analyzed
301802-6 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
6247200 1.00 Y 12: 28 Y
5191140 1.00 Y 10: 12 Y
8214020000 1.00 Y 10: 16 Y
1057434000 1.00 Y 12: 34 Y
6416360 1.00 Y 15: 28 Y
1053276000 1.00 Y 15: 30 Y
3816800 1.00 Y 16: 1 Y
167765400 1.00 Y 16: 7 Y
4361140 1.00 Y 20: 55 Y
4675320 1.00 Y 17: 41 Y
478978000 1.00 Y 17: 47 Y
11988160 1.00 Y 20: 45 Y
5372860000 1.00 Y 20: 49 Y
* No Peak 0.00 N 20: 59 N
13510060 1.00 Y 26: 0 Y
13174340 1.00 Y 24: 35 Y
1730908000 1.00 Y 24: 39 Y
12865500 1.00 Y 25: 17 Y
984552000 1.00 Y 25: 20 Y
9716100 1.00 Y 29: 8 Y
28070400 1.00 Y 29: 13 Y
14713300 1.00 Y 29: 15 Y
109988000 1.00 Y 29: 20 Y
25220400 1.00 Y 33: 22 Y
10080440 1.00 Y 32: 30 Y
58691800 1.00 Y 32: 34 Y
20916200 1.00 Y 32: 35 Y
58691800 1.00 Y 32: 34 Y
12479520 1.00 Y 33: 34 Y
22107800 1.00 Y 33: 28 Y
7248280 1.00 Y 33: 39 Y
9256060 1.00 Y 33: 51 Y
* No Peak 0.00 N 33: 55 N
9019300 1.00 Y 38: 4 Y
4096560 1.00 Y 38: 11 Y1-"-;.
5021960 1.00 Y 38: 9 Y
681544 1.00 Y 38: 16 Y ':' -
9675900 1.00 Y 39: 14 Y
7685780 1.00 Y 39: 23 Y
4675320 1.00 Y 17: 41 Y
4440900 1.00 Y 17: 46 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 18.54 37
1.23 1.3e+05 0.000
0.56 3.6e+04 0.000
1.21 42.31 85
0.94 1.7e+04 0.000
0.74 41.03 82
1.25 3527.38 0.000
1.00 50.00
1.42 37.72 75
1.16 8827.80 0.000
2.81 48.^5 98
0.89 5.0e+04 0.000
0.80 0.00 0.000
1.00 50.00
1.41 34.56 69
1.11 1.2e+04 0.000
1.52 31.36 63
1.21 6350.44 0.000
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
64
07
0.63
1.71
0.44
0.62
0.25
-1.40
0.58
1.02
1.42
1.00
39.95
239.85
42.57
689.63
50.00
44.03
498.81
43.74
241.04
36.56
107.97
54.18
29.12
0.00
40.22
'73.15
40.50
9.67-
33.09
78.18
6.52
80
0.000
85
0.000
88
0.000
87
0.000
73
0.000
0.000
58
0.000
80
0.000
81
-0.000
66
0.000
13
-------
File:30OC98V4 #1-510 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sampled Text:301802-6 :10X DIL.:: : Exp:PAHAIR
128.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 2
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11:00 12:00
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5.8E5
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-7.5E5
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10 Time
-------
Files300C98V4 #1-510 Acq:30-OCT-1998 23:17:42 GC EI4- Voltage SIR 70SE
Sampled Text:301802-6 :10X OIL.:: : Exp:PAHAIR
152.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
y?
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60
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128 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
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FiIe:30OC98V4 #1-510 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sample#9 Text:301802-6 :10X OIL.::: Exp:PAHAIR
130.9920 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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-------
File:30OC98V4 #1-641 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sample#9 Text:301802-6 :10X DIL. : :: Exp:PAHAK
166.0798 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
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80 J
70 J
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-------
F11e:30OC98V4 #1-641 Acq:30-OCT-1998 23:17:42 GC El-f Voltage SIR 70SE
Sample#9 Text:301802-6 :10X DIL.::: ExprPAHAIR
178.0782 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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tt 6OC98V4 #1-641 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
m le#9 Text:301802-6 :10X OIL.::: ExprPAHAIR
178.0782 S:9 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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FOe:30OC98V4 #1-641 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sample#9 Text:301802-6 :10X OIL.::: ExprPAHAIR
204.9888 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F>T)
100%
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1700
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20:i
21 :C
22:t
23:
-------
FUe:30OC98V4 #1-939 Acq:30-OCT-1998 23:17:42 GC EH- Voltage SIR 70SE
Sampled Text:301802-6 :10X DIL.::: Exp:PAHAIR
230.9856 S:9 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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:7.3E6
0 OEO
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-------
FUe:30OC98V4 #1-878 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sampled Text:301802-6 :10X DIL. :: : £xp:PAHAIR
252.0939 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10
A2
31:00
264.1692
100%
90 J
80 J
70 j
60 j
50
40 J
30
20 J
10
0
31:
32:00 33f:00
S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.26E7
A5.04E6
N
O.OEO
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2.6E6
-2.4E6
:2.1E6
1.8E6
11.6E6
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36:
37:i
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0 Time
-------
OC98V4 #1-878 Acq:30-OCT-1998 23:17:42 GC EH- Voltage Sm 70SE
e#9 Text:301802-6 :10X DIL.::: Exp:PAHAIR
S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.21E7
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A5.04E6
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32:48 32:^4
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sample#9 Text:301802-6 :10X OIL. : : : Exp:PAHAIR
276.0939 S:9 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
37:00 38:00 39:00
288.1692 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:00 ' 38:00 39:00
278.1096 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
40:00
41:00
37:00 38-So 39:00
292.1974 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
40:1)0
41:
1002
80 J
60-
40-
20 J
37:<
A2.51E6
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O.OEO
10 Time
42:1
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42:(
38:00
41:
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)0 Time
2.4E5
Ll.9E5
Ll.4E5
-9.5E4
L4.7E4
.O.OEO
fe
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42:00 Time
-------
FUe:300C98V4 #1-878 Acq:30-OCT-1998 23:17:42 GC EI+ Voltage SIR 70SE
Sampled Text:301802-6 :10X OIL.::: Exp:PAHAIR
268.9824 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
90 :
80 j
70 J
60 j
50 J
40J
30 J
20.:
10 J
0
31:
280.9
100 S
90 J
80
70 _
60 _
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40_
30 J
20 J
10J
0
31:
A127E7 A9.50E6 A1.90E7 ^ A^HF7 A1.22E7
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^_5.6E6
L3.7E6
L1.9E6
: O.OEO
)0 Time
9.1E7
L8.2E7
L7.3E7
L6.4E7
L5.5E7
L4.6E7
L3.6E7
-2.7E7
1.1.8E7
L9.1E6
LO.OEO
10 Time
-------
04-NOV-1998 05:38:56 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4131.RES
Date analyzed
301802-6 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
348000 1.00 Y
510000 1.00 Y
688320000 1.00 Y
T.2? 29 Y.
10: 12 Y
10: 16 Y
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 32.70 65
1.23 l.le+05 B
dlO-Anthracene
208000 1.00 Y 20: 55 Y
1.00 50.00
dl 0-Phenanthrene
Phenanthrene
622354 1.00 Y 20: 45 Y
153056200 1.00 Y 20: 49 Y
2.81 53.29
0.89 2.7e+04
107
CS
259
-------
04-NOV-tL998 05:38:52 PM Dioxin Furan Unknown RESULTS
0.5
98V4. RRF
Rec/
MDL
174000 174000
65 255000 255000
B E 344160000 344160000
104000 104000
107 311177 311177
B E 76528100 76528100
-------
03-NOV-1998 08:43:44 AM
429AIR Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4131.RES
Date analyzed
301802-6 :100X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
.dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
313082 1.00'T
339338 1.00 Y
688320000 1.00 Y
84088400 1.00 Y
250974 1.00 Y
45451200 1.00 Y
163597 1.00 Y
9944880 1.00 Y
185990 1.00 Y
87891 1.00 Y
727086 1.00 Y
622354 1.00 Y
153056200 1.00 Y
* No Peak 0.00 N
516988 1.00 Y
337802 1.00 Y
24047000 1.00 Y
392988 1.00 Y
13061900 1.00 Y
275340 1.00 Y
* No Peak 0.00 N
295068 1.00 Y
6311320 1,00 Y
842284 1.00 Y
135660 1.00 Y
289624 1.00 Y
578002 1.00 Y
289624 1.00--Y
122647 1.00 Y
264256 1.00 Y
* No Peak 0. OQ H
-~ 43231 1.00^ Y
* No Peak 0.00' N
* No Peak
* No Peak
* No Peak
* No Peak
0.00 N
0.00 N
0.00 H
0.00 N
114185 1.00 Y
126093 1.00 Y
87891 1.00 Y
* No Peak 0.00 N
r 29 Y
10: 12 Y
10: 16 Y
12: 33 Y
157
15:
16:
16:
32:
32:
/8 Y
30 Y
2 Y
1 Y
20: 55 Y
17: 41 Y
17: 47 Y
20: 45 Y
20: 49 Y
20: 59 N
26: 2 Y
24: 36 Y
24: 39 Y
25: 18 Y
25: 21 Y
29: 12 Y
29: 14 N
29: 18 Y
29: 22 Y
33: 25 Y
32: 33 Y
32: 39 Y
40 Y
39 Y
33: 40 Y
33: .31 Y
33i .41 N
33:: 55 Y
33: 58 N
38: 4
38,4. 11
N
38: 8 .-W
38: 18 N
39: 17 Y
39: 26 Y
17:, 41 Y
17: 49 N
: PAHAIR.TRG
: 02-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 24.19 48
1.23 1.7e+05 0.000
0.56 4.4e+04 0.000
1.21 33.02 66
0.94 1.9e+04 0.000
0.74 35.09 70
1.25 4878.37 0.000
1.00 50.00 j
1.42 16.63 33 '
1.16 712.84 0.000
2.81 59.59 119.
0.89 2.7e+04 0.000
0.80 0.00 0.000
1.00 50.00—-
1.41 23.16 46
1.11 6403.00 0.000
1.52 25.03 50
1.21 2758.16 0.000
0.90 29.59 59
1.20 0.00 0.000
1.28 22.31 45
1.Oar 1973.25 0.000
1.00
0 .45'
1.17
0.95
1.16
0.68
1.64,
1.07
0 .63
;i.7i
0,44
50.00
17.74 35
182.90 0,000
36.19 72
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File:02N098V4 #1-510 Acq: 2-NOV-1998 23:01:38 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-510 Acq: 2-NOV-1998 23:01:38 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 23:01:38 GC EI+ Voltage SIR 70SE
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION 6C/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-1
301802-0007-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a
Perylene'
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
100000
2900
16000
280
930
11000
310
5400
2700
160
380
270
ND
290
230
ND
ND
ND
ND
ng/ sample
ng/sample
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/ sample
ng/sample
ng/sampTe
ng/sample
ng/sample
ng/sample
ng/ sample
ng/sample.
ng/ sample
--
--
--
--
--
--
--
--
--
--
--
--
100
--
--
100
100
100
100
B
B
F
F
F
B = Compound is also detected in the ilank.
F = Reported value estimated due to an interference.
ND = Not Detected
Reported By: Clark Pickell
Approved By: f^rtc ftedman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-1
301802-0007-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphtha! ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzofb
Benzofk
Benzo(a
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,n)anthracene-dl4
Benzo(g,n,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
46
5.0
50
81
94
70
57
52
14
70
80
79
80
18
77
58
% Recovery
119
m
m
m
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
f~ I
-------
04-NOV-1998 06:44:19 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4101.RES
Date analyzed
301802-7 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mtn:ss
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Ac enaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indenc(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
4546720 1.00 Y
4660000 1.00 Y
5827860000 1.00 Y
75979200 1.00 Y
302000 1.00 Y
46600000 1.00 Y
1682194 1.00 Y
5780000 1.00 Y
2875560 1.00 Y
3313300 1.00 Y
35925800 1.00 Y
7550260 1.00 Y
754314000 1.00 Y
18660000 1.00 Y
9995400 1.00 Y
9883440 1.00 Y
591552000 1.00 Y
8622380 1.00 Y
278108000 1.00 Y
4643320 1.00 Y
8743480 1.00 Y
10185540 1.00 Y
31389200 1.00 Y
17720000 1.00 Y
6376500 1.00 Y
19920000 1.00 Y
13367320 1.00 Y
13920000 l.QCKir
2160000 1.00 Y
10177060 1.0.0 Y
5220300 1.00 Y
1562000 1.00 Y
1180000 1.004Y
54800CO l.OC,Y
1662 ODD 1.00:-;Y
3340000 1.00 Y
* No Peak 0.00 N
|940:600 1.00 Y
3300000 1.00 Y
3313300 1.00 Y
3194800 1.00 Y
12:
10^
10:
12:
'£5 r
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33 .s
:33:
33 :
38:
38:
?38:
38:
39:
39:
17:
17:
28 Y
12 Y
16 Y
34 Y
T? Y
"44 Y
2 Y
8 Y
55 Y
41 Y
46 Y
45 Y
50 Y
59 Y
1 Y.
35 Y
39 Y
17 Y
20 Y
9 Y
15 Y
16^Y
20, Y
23;y
30 Y
35, Y
36 Y
38 Y
33 Y
28 Y
35 Y
.50 Y
56 N
5 Y
12 Y
9 Y
16 N/
i/Y^'i
24 Y"
41 Y
46 Y .
1.00
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
r.oo
1.41
;; 1.11
1.52
1.21
, 0.90
1.20
1.28
1 .08
0*45
1.17_
0.95-
1.16
0.68
0.63
livTT
• -0.44
0. . 62
.'' t • - ,""
-CT_25
1 \
?: 0.58
1.02
1.00
0.81
50.00
22.87 46m
l.Oe+05 B E
2908.66 B
2 . 74 5 (t
1.6e+04 E F
24.84 50
275.74
50.00
40.55 81
934.32
46.76 94
l.le+04 B E
308.77
50.00
35.05 70
5383.56 E
28.41 57
2676.57
25.81 52
156.33
39.83 80
284.30
£. so.oo
--. 39.64 79
.--'- 267 . 63 .•
39.78 80
,.,
-------
4-NOV-1998 06:44:16 PM Dioxin Furan Unknown RESULTS
0.5
8V4 . RRF
Rec/
MDL
46
B E
B
5
E
50
81
94
B E
70
E
57
52
80
79
80
do. oo
18
14
DO. 00
70
DO. 00
77
00.00
58
00.00
2273360
2330000
2913930000
37989600
151000
23300000
841097
2890000
1437780
1656650
17962900
3775130
377157000
9330000
4997700
4941720
295776000
4311190
139054000
2321660
4371740
5092770
15694600
8860000
3188250
9960000
6683660
6960000
1080000
5088530
2610150
781000
590000
2740000
831000
1670000
0
2970000
1650000
2273360
2330000
2913930000
37989600
151000
23300000
841097
2890000
1437780
1656650
17962900
3775130
377157000
9330000
4997700
4941720
295776000
4311190
139054000
2321660
4371740
5092770
15694600
8860000
3188250
9960000
6683660
6960000
1080000
5088530
2610150
781000
590000
2740000
8.31000
1670000
0
2970000
1650000
-------
02-NOV-1998 08:55:42 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4101.RES
Date analyzed
301802-7 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2 -Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
4546720 1.00 Y
4981700 1.00 Y
5827860000 1.00 Y
75979200 1.00 Y
* No Peak 0.00 N
46691600 1.00 Y
1682194 1.00 Y
* No Peak 0.00 N
2875560 1.00 Y
3313300 1.00 Y
35925800 1.00 Y
7550260 1.00 Y
754314000 1.00 Y
* No Peak 0.00 N
9995400 1.00 Y
9883440 1.00 Y
591552000 1.00 Y
8622380 1.00 Y
278108000 1.00 Y
4643320 1.00 Y
8743480 1.00 Y
10185540 1.00 Y
31389200 1.00 Y
19667360 1.00 Y
6376500 1.00 Y
34053400 1.00 Y
13367320 LOO, Y
34053400 i.tra -31.
* No Peak 0.00 K
10177060 1.00 Y
5220300 1.00 Y
* No Peak
* No Peak
0.00 N
0.00 N
3641700 1.00 Y
162374 1. 00- -Y
1901412 1.00 Y
* No Peak 0.00 N
3873040 1.00 Y
2971060 1.00 Y
3313300 1.00 Y
3194800 1.00 Y
12: 28 Y
10: 12 Y
10: 16 Y
12: 34 Y
, i--,-=,*«,.•.«» •*»
15: 31 Y
16:
16:
2 Y
8 N
20: 55 Y
17: 41 Y
17: 46 Y
20: 45 Y
20: 50 Y
20: 59 N
26: 1 Y
24: 35 Y
24: 39 Y
25:
25:
17 Y
20 Y
29: 9 Y
29: 15 Y
29: 16 Y
29: 20 Y
33: 23 Y
32: :30 Y
32 1 35 Y}
32: 36 Y
32: 35 Y
. 33 N
33: ZB Y
33i 35 Y
33-. 150 N
•33: 56 W
38: 5 Y
38: 12 Y
38 1 i^-V
38: 16 N
39: 14 Y
39: 24 Y
17: 41 Y
17: 46 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 24.45 • 49
1.23 9.5e+04 0.000
0.56 2720.83 0.000
1.21 0~QO 0
0 . 94 *NoINoIs
0.74 24.84 50
1.25 0.00 0.000
1.00 50.00
1.42 40.55 81
1.16 934.32 0.000
2.81 46.76 94
0.89 l.le+04 0.000
0.80 0.00 0.000
1.00 50.00
1.41 35.05 70
1.11 5383.56 0.000
1.52 28.41 57
1.21 2676.57 0.000
0.90 25.81 52
1.20 156.33 0.000
:1.28 39.83 80
1.08 284.30 0.000
1..00 -V 50.00
0.45 ^ 35.72
1.17:; 457.52
71-
0.95
1.16
0.68
r. 64-
0..63*
1. 71
0.44
0.62
0 T.
; 35.85 ~72
218.83 0..000
\ 'vy'?~ '-
' 0.00 . "i. 0
*NbINbXs- -
*NoINoXs
0.00 ~0
*NoIHdlB. :,
20.83 42
71.75 0-Oflfl
39
1.02 75.50 0.000
1.42 5.93 12
1.00 96.42 0.000
-------
F11e:300C98V4 #1-509 Acq:31-OCT-1998 00:06:44 GC EI+ Voltage SIR 70SE
Sample#10 Text:301802-7 :10X OIL. ::: Exp:PAHAIR
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
Pacific Environmental Services
A-U-429-2
301802-0008-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Benzo a pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
130000
2300
68000
240
690
20000
460
12000
21000
100
460
420
130
1400
210
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
- —
--
--
—
--
—
--
--
--
--
--
--
--
100
100
100
LOO
B
B
F
F
F
B = Compound is also detected in "the blank.
F = Reported value estimated due to an interference.
ND = Not Detected
Reported By: Clark Pickell
Approved By: ? BricrRedman
The cover letter is an integral part of this report.
Rev 230787
207
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-2
301802-0008-SA
AIRTRAIN Sampled: 24 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphtha! ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Benzo
Benzo
Benzo
Dibenz(a,h)anthracene-dl4
Benzo(g,h s i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
42
4.0
49
78
95
65
55
61
12
52
76
74
66
17
56
40
% Recovery
99
m
m
m
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
308
-------
04-NOV-1998 07:17:37 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4111.RES
Date analyzed
301802-8 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio tnm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
5838300 1.00 Y
5524320 1.00 T
9087580000 1.00 Y
70607600 1.00 Y
290936 1.00 Y
185853200 1.00 Y
2146320 1.00 Y
6540000 1.00 Y
3258480 1.00 Y
3628840 1.00 Y
28931200 1.00 Y
8693120 1.00 Y
1569824000 1.00 Y
31800000 1.00 Y
11645580 1.00 Y
10675940 1.00 Y
1376432000 1.00 Y
9699220 1.00 Y
2455760000 1.00 Y
6392740 1.00 Y
7919440 1.00 Y
11354900 1.00 Y
56626400 1.00 Y
25020800 1.00 Y
8447640 1,00 Y
41400000 1.00 Y
15647720 1.00 Y
23000000,1,00 Y
2920000 1.00 Y
69200000 1.00 Y
6520000 1.00'Y
1906000 1.00 Y
* No "Peak 0.00 N
5828860 1.00 Y
1235268 1.04 Y
3433960 1.00 Y
* No Peak 0.00 N
5857140 1.00 Y
3609860 1.00 Y
3628840 1.00 Y
2906200 1.00 Y
12:
10:
10:
12:
— ,.
ii"i
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
28
IZ
16
34
-2-%
31
2
8
55
42
47
45
49
59
0
36
39
17
20
9
13
15
20
22
30
34
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y ;
Y
Y
Y .
Y .V
Y ,
Y
Y
Y,
Y
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
50.00
21.11
1.36+05
2280.12
2.05
6.86+04
24.69
244.53
50.00
39.19
686.98
47.51
2.06+04
457.03
50.00
32.49
1.26+04
27.43
2.16+04
30.50
102.85
38.11
460.06
50.00
37.20
419.86
42
B E
B
4
E F
49
78
95
E
65
E
55
E
61
76
74
32:
32:
35 Y
38 Y
33; 32 Y
33:: 28 Y
33:. 38 N
33: 49 Y
33: 55 N
38; 5 Y
38:.12 Y
38^1 15:N
39: 15 Y
39: 24 Y
17: 42 Y
17: 47 Y
0.95
1.16
32.98
126.26
0.68 8.62 '•
1..64 1444.31 *•'
1,07 208.23>:
0.63.
.1>71
0.44
Q...62
6.0
52
0.58
1.02
1.00
0.81
20.19 40<
-------
l-NOV-1998 07:17:33 PM Dioxin Furan Unknown RESULTS
0.5
3V4. RRF
tec/
MDL
2919150
42 2762160
B E 4543790000
B 35303800
4 145468
E 92926600
49 1073160
3270000
1629240
78 1814420
14465600
95 4346560
E 784912000
15900000
5822790
65 5337970
E 688216000
55 4849610
E 1227880000
61
76
74
66
17
12
52
00.00
56
00.00
40
00.00
3196370
3959720
5677450
28313200
12510400
4223820
20700000
7823860
11500000
1460000
34600000
3260000
953000
0
2914430
617634
1716980
0
2928570
1804930
2919150
2762160
4543790000
35303800
145468
92926600
1073160
3270000
1629240
1814420
14465600
4346560
784912000
15900000
5822790
5337970
688216000
4849610
1227880000
3196370
3959720
5677450
28313200
12510400
4223820
20700000
7823860
11500000
1460000
34600000
3260000
953000
0
2914430
617634
1716980
0
2928570
1804930
-------
02-NOV-1998 08:58:52 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 30OC98V4111.RES
Date analyzed
301802-8 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO - 2 -Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 - Acenaphthylene
Acenaphthylene
dlO -Acenaphthene
Acenaphthene
dlO- Anthracene
dlO- Fluor ene
Fluorene
dlO - Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0 - Fluorant hene
Fluoranthene
dlO-Pyrene
Pyrene
d!2 -Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e)pyrene
d!2 -Benzo (b) f luoranthene
Benzo (b) f luoranthene
d!2 -Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2 - Benzo ( a ) pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
d!2 - Indeno (123 - cd) pyrene
Indeno( 123 -cd) pyrene
d!4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2 -Benzo (ghi) perylene
Benzo (ghi) perylene
dlO -Fluorene
13C-Fluorene
5838300 1.00 Y 12: 28 Y
5524320 1.00 T IDs 12 Y
9087580000 1.00 Y 10: 16 Y
70607600 1.00 Y 12: 34 Y
290936 1.00 Y ^ .:._;.** Y
185853200 1.00 Y 15: 31 Y
2146320 1.00 Y 16: 2 Y
* No Peak 0.00 N 16: 8 N
3258480 1.00 Y 20: 55 Y
3628840 1.00 Y 17: 42 Y
28931200 1.00 Y 17: 47 Y
8693120 1.00 Y 20: 45 Y
1569824000 1.00 Y 20: 49 Y
* No Peak 0.00 N 20: 59 N
11645580 1.00 Y 26:
10675940 1.00 Y 24:
1376432000 1.00 Y 24:
9699220 1.00 Y 25:
2455760000 1.00 Y 25;
6392740 1.00 Y 29,:
7919440 1.00 Y 29:
11354900 1.00 Y 29:
56626400 1.00 Y 29;
25020800 1.00 Y 33:
8447640 1.00 Y 32:
75738400 1.00 Y 32:
15647720 1.00 Y 32:
75738400 1.00 Y 32;
* No Peak 0.00 H 33;
77195400 1.00 Y 33;
* No Peak 0.00 N ..33:
* No Peak
* No Peak
0.00 N
0.00 1U
58288SO 1.00 Y
12352fifi 1.00 -Y
3433960 1.00. T-
* No Peak 0.00 N
5857140 1.00 Y
3609860 1.00 Y
3628840 1.00 Y
2906200 1.00 Y
33:
33:
38
38;
38:
38
39
39
17
17
0 Y
36 Y
39 Y
17 Y
20 Y
9 Y
13 Y
15 Y
20 Y
22 Y -.
30 Y
34 Y
35 Y
34 Y
32 N
28 Y
38 N
49 N
5 5 N
5 Y
12 Y
B; Y
15 N
15 Y
24 Y
42 Y
47 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 21.11 42
1.23 1.36+05 0.000
0.56 2280.12 0.000
.•*"*
1.21 2.05
0.94 6.86+04 0.00
0.74} 24.69 49
1.25 0.00 0.000
1.00 50.00
1.42 39.19 78
1.16 686.98 0.000
2.81 47.51 95
0.89 2.06+04 0.000
0.80 0.00 0.000
1.00 50.00
1.41 32.49 65
1.11 1 .,26+04 0.000
1.52 27.43 55
1.21 2.16+04 0.000
0.90 30.50 61
1.20 102.85 0.000
1.28 ^38.11 76
1.08 "460.06 0.000
1.00,. 50.00
0.45%; 37.20 74
1.17^768.10 0.000
0.95 '
1.16
0.68
1.64V
1.07-
0.63
1.71.
''. r , -•
0.44
0.62
""V'-
0.25 .-;
32.98 66;
415.77 0.000
0.00 0
*NoIHbrs
; *NoINoIS
0.00 0
; . *NoINoIS
. •
26.20 • 52
34,13 0.000,,.
'
0^58
1/02
1.42
1.00
20.19 V«3
60.66 0.000
5.10 ;i,"::-."lt)
80.09 0.000
-------
File:30OC98V4 #1-510 Acq:31-OCX-1998 00:55:45 GC EI-f Voltage SIR 70SE
Sample#ll Text:301802-8 :10X DIL.::: ExprPAHAIR
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GC EI+ Voltage SIR 70SE
Sample#ll Text:301802-8 rlOXDEL.::: Exp:PAHAIR
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-------
FUe:300C98V4 #1-510 Acq:3l-OCT-1998 00:55:45 GC EI+ Voltage SIR 70SE
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-------
File:30OC98V4 #1-640 Acq:31-OCT-1998 00:55:45 GC EI+ Voltage SIR 70SE
Sample#ll Text:301802-8 :10X OIL. : : : Exp:PAHAIR
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-------
File:300C98V4 #1-640 Acq:3l-OCT-1998 00:55:45 GC EH Voltage SIR 70SE
Sample*!! Text:301802-8 :10X OIL.::: Exp:PAHA»
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-------
File:300C98V4 #1-640 Acq:31-OCT-1998 00:55:45 GC EI+ Voltage SIR 70SE
Sample#ll Text:301802-8 :10X OIL. : :: ExprPAHAIR
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File:30OC98V4 #1-878 Acq:31-OCT-1998 00:55:45 GC EI+ Voltage SIR 70SE
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Flle;30OC98V4 #1-878 Acq:31-OCT-1998 00:55:45 GC E1+ Voltage SIR 70SE
SampledII Text:301802-8 :10X OIL.: :: Exp:PAHAIR
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-U-429-3
Lab ID: 301802-0009-SA
Matrix: AIRTRAIN Sampled: 25 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indenofl,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
76000
1600
13000
120
360
9900
220
4800
3300
ND
290
210
ND
350
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
--
--
--
--
_.
--
100
--
--
100
--
100
100
100
100
100
B
B
F
B = Compound is also detected in the blank.
F = Reported value estimated due to an interference.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Dilution Factor: 1.0
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-3
301802-0009-SA
AIRTRAIN Sampled: 25 SEP 98
29 SEP 98 Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzo(k]fluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h, i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
52
9.0
59
73
88
77
64
75
20
77
95
93
90
22
79
57
% Recovery
104
m
m
m
m = Internal Standard recovery is outside method recovery goal. ••-"••. •*..•. ,•.;
Reported By: Clark Pickell Approved By: STTCRedraan
The cover letter is an integral part of this report.
Rev 230787
-------
l-NOV-1998 07:22:17 PM Dioxin Furan Unknown RESULTS
iss Spec : VG-4
' Column : DB-5
ita file : 300C98V4
jight : 0.5
Name
ilO - 2 -Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
12 -Benzo(b)fluoranthene
Benzo(b)fluoranthene
12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
i!2-Indcno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
i!4-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4121.RES
Date analyzed
301802-9 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio inm:ss
7708300 1.00 Y
8989960 1.00 Y
8349100000 1.00 Y
79278200 1.00 Y
798254 1.00 Y
97227200 1.00 Y
3380080 1.00 Y
5080000 1.00 Y
4888660 1.00 Y
5057040 1.00 Y
20852000 1.00 Y
12122960 1.00 Y
1077356000 1.00 Y
21200000 1.00 Y
13195400 1.00 Y
14411760 1.00 Y
767880000 1.00 Y
12748280 1.00 Y
511088000 1.00 Y
8915960 1.00 Y
8564840 1.00 Y
16006240 1.00 Y
50730000 1.00 Y
30423600 1.00 Y
12877120 1.00 Y
32000000 1.00 Y
25817200 1.00 Y
25000000 1.00 Y
4540000 1.00 Y
26330600 1.00 Y
2580000 1.00 Y
3760000 1.00 Y 33: 49 Y
* No Peak 0.00 N 33: 55 N
10360060 l.OC Y 38. 4 Y
912632 1.00 Y 38: 10 Y
5934300 1.00 Y 38: 9 Y
97452 1.00 Y 38: 17 Y
9997440 1.00 Y 39: 15 Y
3370860 1.00 Y 39: 23 Y
5057040 1.00 Y 17: 41 Y
4272480 1.00 Y 17: 47 Y
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
28
12
16
34
28
30
2
8
55
41
47
45
49
59
0
36
39
17
20
9
13
15
20
22
29
34
35
34
32
28
38
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
50.00
26.02
7.66+04 B
1573.19
4.27
1.36+04 E
29.44
120.61
50.00
36.40
355.30
44.16
9934.91
218.48
50.00
38.71
4792.49
31.82
3326.87
37.54
-------
04-NOV-1998 07:22:14 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
3854150
52 4494980
B E 4174550000
B
39639100
3854150
4494980
4174550000
39639100
E
100
100
100
100
100
100
100
9
F
59
73
88
E
77
64
75
.00
95
93
90
.00
22
.00
20
.00
77
.00
79
.00
57
.00
399127
48613600
1690040
2540000
2444330
2528520
10426000
6061480
538678000
10600000
6597700
7205880
383940000
6374140
255544000
4457980
4282420
8003120
25365000
15211800
6438560
16000000
12908600
12500000
2270000
13165300
1290000
1880000
0
5180030
456316
2967150
48726
4998720
1685430
399127
48613600
1690040
2540000
2444330
2528520
10426000
6061480
538678000
10600000
6597700
7205880
383940000
6374140
255544000
4457980
4282420
8003120
25365000
15211800
6438560
16000000
12908600
12500000
2270000
13165300
1290000
1880000
0
5180030
456316
2967150
48726
4998720
1685430
-------
J2-NOV-1998 09:02:03 AM Dioxin Furan Unknown RESULTS
ijass Spec : VG-4
3C Column : DB-5
)ata file : 300C98V4
Seight : 0.5
Name
dlO- 2 -Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
dl2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
cll2 -Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
312 -Indeno (123 -cd) pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4121.RES
Date analyzed
301802-9 :10X DIL. : : Ex Cal
Total Isotope R. T. RRF
Response Ratio
7708300 1.00 Y
8989960 1.00 Y
8349100000 1.00 Y
79278200 1.00 Y
798254 1.00 Y
97227200 1.00 Y
3380080 1.00 Y
* No Peak 0.00 N
4888660 1.00 Y
5057040 1.00 Y
20852000 1.00 Y
12122960 1.00 Y
1077356000 1.00 Y
* No Peak 0.00 N
13195400 1.00 Y
14411760 1.00 Y
767880000 1.00 Y
12748280 1.00 Y
511088000 1.00 Y
8915960 1.00 Y
8564840 1.00 Y
16006240 1.00 Y
50730000 1.00 Y
30423600 1.00 Y
12877120 1.00 Y
61473800 1.00 Y
25817200 1.00 Y
61473800 1.00 Y
* No Peak 0.00 N
26330600 1.00 Y
* No Peak 0.00 N
* No Peak
* No Peak
0.00 N
0.00 N
10360060 1.00 Y
912632 1.00 Y
5934300 1.00 Y
97452 1.00 Y
9997440 1.00 Y
3370860 1.00 Y
5057040 1.00 Y
4272480 1.00 Y
*
R.
mm
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
E2
T.
ss
28
12
16
34
28
30
2
8
55
41
47
45
49
59
0
36
39
17
20
9
13
15
20
22
29
34
35
34
32
28
38
49
55
4
10
9
17
15
23
41
47
c
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
N
N
Y
Y
Y
Y
Y
Y
Y
Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 26.02 52
1.23 7.6e+04 O.OOQ
0.56 1573.19 0.000
1.21 4.27 9
0.94 1.3e+04 O.OOO
0.74 29.44 59
1.25 0.00 0.000
1.00 50.00
1.42 36.40 73
1.16 355.30 O.OOO
2.81 44.16 8S
0.89 9934.91 0.000
0.80 0.00 O.OOO
1.00 50.00
1.41 38.71 77
1.11 4792.49 0.000
1.52 31.82 64
1.21 3326.87 O.OOO
0.90 37.54 75
1.20 79.75 O.OOO
1.28 47.41 95
1.08 292.39 O.OOO
1.00 50.00
0.45 46.63 93
1.17 408.98 0.000
0.95 44.75 9U
1.16 204.54 O.OOO
0.68 0.00 O
1.64 *NoINoIS
1.07 *NoINoIS
0.63 0.00 0
1.71 *NoINoIS
C.44 38.30 77
0.62 14.19 O.OOO
0.25 39.67 79
1.40 1.-17-O.OOO
0.58 28.34 57
1.02 33.19 O.OOO
1.42 5.85 12
J-.OO 84.49 O.OQO
330
-------
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Sample#12 Text:301802-9 :10X OIL. :: : Exp:PAHAlR
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File:30OC98V4 #1-640 Acq:31-OCT-1998 01:44:49 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-9 :10X DIL.: J: Exp:PAHAIR
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File:30OC98V4 if 1-878 Acq:31-OCT-1998 01:44:49 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-878 Acq:31-OCT-1998 01:44:49 GC EI+ Voltage SIR 70SE
Sample#12 Text:30I802-9 :10X OIL. :: : Exp:PAHAlR
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-------
File:30OC98V4 #1-878 Acq:31-OCT-1998 01:44:49 GC EI+ Voltage SIR 70SE
Sample#12 Text:301802-9 :10X DIL. ::: Exp:PAHAR
268.9824 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-U-429-4
Lab ID: 301802-0010-SA
Matrix: AIRTRAIN Sampled: 25 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
99000
4400
NC
240
1300
18000
280
7100
4600
150
520
260
110
300
160
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
B
B
100
100
100
100
F
F
B = Compound is also detected in the blank.
F = Reported value estimated due to an interference.
NC = Not Calculated, calculation not applicable.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
*? -\
o-t
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-U-429-4
301802-0010-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 25 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
43
NC
45
79
87
80
53
53
8.0
55
79
94
75
16
61
41
% Recovery
122
m
m
m
m
m » Internal Standard recovery is outside method recovery goal.
NC = Not Calculated, calculation not applicable.
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
348
-------
04-NOV-1998 07:27:40 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 30OC98V4131.RES
Date analyzed
301802-10 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
*
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
i!2-Indcno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
7498280 1.00 Y 12:
7174680 l.OQ'T IT):
8741280000 1.00 Y 10:
176474000 1.00 Y 12:
* No Peak 0.00 N ..,:;
63711000 1.00 Y 15;
2518540 1.00 Y
7640000 1.00 Y
4569820 1.00 Y
5126960 1.00 Y
74847600 1.00 Y
11134240 1.00 Y
1834640000 1.00 Y
24600000 1.00 Y
14911620 1.00 Y
16826180 1.00 Y
1323714000 1.00 Y
12074540 1.00 Y
667264000 1.00 Y
7170060 1.00 Y
13040660 1.00 Y
14987060 1.00 Y
83859000 l.OQ Y
29000000 1.00 Y
12379800 1.00 Y
37600000 1.00 Y
20678000 1.00 Y
27000000 1.00 Y
3120000 1.00 Y
15172820 1.00 T
5217900 X.OO Y
1512000 1.00 Y . 33
1606000 l.OQ^Y
7C38920 1.00 Y
162523*-l.OO-'Y
4313320 1.00 T
* No Peak O.'QO.'N"
6836620 1.00 Y
3314680 1.00 Y
5126960 1.00 Y
5067840 1.00 Y
28 Y
12 Y
16 Y
33 Y
30 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 21.35 43J
1.23 9.9e-»-04 B E
0.56 4387.96 B
1.21 0.00 Q|
0.94 NC
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
:
:
.
:
•
.
:
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:
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0
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17
20
9
13
15
20
22
30
34
35
38
32
28
35
49
55
4
10
8
'".-15"
14
23
41
46
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
0
1
1
1
1
2
0
0
1
- 1
1
1
1
0
1
1
1
" 1
0
1
0
1
0
1
1
0
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28;
.os:
- v
. 00 i
.45"
.17
.95*
.16
.68
.64
.07.
. 63
22.55
243.44
50.00
39.48
1257.96
43.39
1.8e+04
276.04
50.00
39.99
7076.09
26.67
4585.84
26.71
: 151.00
-/39.29
"516.20
/"'so. oo
; 47.03
260.20
5" r
- 37.61
112.16
7.95
-296.38
156". 01
4 .14
45
79
87
B E
80
E
53
53
79
-:•: H'
\~,
75
.•...-.' •'••,
^-'161
'" -T
.;'.:'-? ,
8.
i.7i.,i-
-------
02-NOV-1998 09:05:34 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4131.RES
Date analyzed
301802-10 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mnuss
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2-Indeno(12 3 -cd)oyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
*
*
*
*
*
*
*
7498280
7174680
8741280000
176474000
No Peak
63711000
2518540
No Peak
4569820
5126960
74847600
11134240
1834640000
No Peak
14911620
16826180
1323714000
12074540
667264000
7170060
13040660
14987060
83859000
32214200
12379800
64974200
20678000
64974200
No Peak
15172820
5217900
No Peak
No Peak
7038S20
1625230
4313320
No Peak
6836620
3314680
5126960
5067840
1
1
1
1
0
1
1
0
1
1
1
1
1
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
0
0
1
1
1
0
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
B
Y
Y
N
N
Y
Y
Y
N.
Y
Y
Y
Y
i 3 •
10:
10:
12:
-A* -r.' „
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
3B:
38:
39:
39:
17:
17:
28
12
16
33
? r
30
1
8
55
41
46
45
49
59
0
35
39
17
20
9
13
15
20
22
30
34
35
34
32,
28
3'5,
49
55
4
10
B
15
14
23
41
46
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y,
Y
T
Y .
Y
Y
N ..--
Y -':: '
• Y. :"":; ;.
N/
N
Y .
Y.. x>.
Y , :, .^.
S\'-'f\
Y '';.
Y
Y
Y
1.00
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
1.00
1.41
1.11
1.52
1.21
0.90
1.20
1.28
1..OB-
l.OCH
0.45"
1.17
0.95
1.. 16 ,
0.68
1.64
1.07,
0.63
1-71
0.44
0.62
.0-251
1-403
0.58
1.02
1.42,
1.00
50
21
.00
.35
9.96+04
4387
0
.96
.00
43
0.000
0.000
0
*NoINoIs
22
0
50
39
1257
43
.55
.00
.00
.48
.96
.39
1.86+04
0
50
39
7076
26
4585
26
151
39
516
.50
-V42
449
33
269
0
, *•;
.00
.00
.99
.09
.67
.84
.71
.00
.29
.20
.00
.34
.64
.85
.91
.00
Noll
45
0.000
79
0.000
87
0.000
0.000
80
0.000
53
0.000
53
0.000
79
0.000
85?
0-000
68
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:: -*NoINoIs;
0
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24
37
127
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98
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11
O.QOO
351
-------
FUe:30OC98V4 #1-510 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL. : : : Exp:PAHAIR
128.0626 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
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128 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.59E6
1
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0 10:6o ' ll:6o 12:6o 13:00 14:6o 15:
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:3.8E5
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( ' >
-------
FUe:30OC98V4 #1-510 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X DIL.::: ExprPAHAIR
152.0626 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60:
40:
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A,
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14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:00 16:12 16:24
10.1128 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
,1.39E6
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16:48
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) 14:12 14:24 14:36 14:48 15:00 15:12
A7.02E5
A4.84E5
A3.18E5
A6.73E5
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15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:
:3.4E5
-2.5E5
1.7E5
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H) Time
1002
80:
60:
40:
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60 1
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f A1.26E6
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00 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36 15:48 16:6o 16:12 16:24 16:36 16:48 17:
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3.5E5
:2.8E5
-2.1E5
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-7.1E4
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-------
File:30OC98V4 #1-510 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL. : : : Exp:PAHAIR
152.0626 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
40
30 J
20
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0
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A6.86E6
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15:60 15:06 15:12 15:18 15:24 15:30
160.1128 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90_
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L2.5E6
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Time
15:66
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15:24
15:30
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Time
-------
File:30OC98V4 #1-510 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Samplell3 Text:301802-10 :10X DIL. : : : Exp:PAHAIR
154.0782 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A6.Q2E6
15:52 15:54 15:56 15:58 16:6o 16:62
164.1410 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
16:
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Time
-------
F1le:300C98V4 #1-510 Acq:31-OCT-1998 02:33:51 GC E1+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X DDL.::: Exp:PAHAIR
130.9920 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:30OC98V4 #1-641 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Samplei?13 Text:301802-10 :10X OIL. : : : ExprPAHAIR
166.0798 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.74E7
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90 J
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176.1410 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.
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Flle:300C98V4 #1-641 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
SampluTtt Text:301802-10 :10X D1L. ::: Exp:PAHAIR
178.0782 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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188.1410 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-641 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X DIL. : : : Exp:PAHAER
178.0782 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
20:53 20:54 20:55 20:56 20:57 20:58 20:59
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FHe:30OC98V4 #1-641 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X DEL.: :: Exp:PAHAER
204.9888 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:30OC98V4 #1-938 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10XD1L.::: Exp:PAHAIR
1009
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Flle:30OC98V4 #1-938 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL. ::: Exp:PAHAIR
228.0939 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
240.1692 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%>10000.0,0.00%,F,T)
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L1.8E5
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tO Time
-------
File:30OC98V4 #1-938 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL.::: ExprPAHAIR
228.0939 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
29:00 29:06 29:12 29:is 29:24 29:30
240.1692 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Time
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FUe:30OC98V4 #1-938 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL. ::: Exp:PAHAIR
230.9856 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A3.32E8
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31:00 Time
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File:30OC98V4 #1-878 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL.::: Exp:PAHAIR
252.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%flOOOO.O,0.00%,F,T)
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0 Time
31:00 32:60 33:6o
264.1692 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,
Al
31:00
O.OEO
0 Time
-------
File:30OC98V4 #1-878 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sampled 3 Text:301802-10 :10X OIL. : : : Exp:PAHAIR
252.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%f10000.0,0.00%,F,T)
A1.88E7
264.1692 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
O.OEO
Time
-------
File:30OC98V4 #1-878 Acq:31-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X OIL. : :: ExprPAHAIR
252.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.59E6
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90_
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701
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A1.45E7
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33:66 33:ii 33:i8 33:i4 33:30 33:36 33:42 33:48 33:54 34:66 34:66 34:ii 34:i8 34:24 34:5o 34-3T
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Flle:300C98V4 #1-878 Acq:31-OCT4998 02:33:51 GC E1+ Voltage SIR 70S1
Sampled Text:301802-10 :10X OIL.::: Exp:PAHALR
276.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%>F,T)
100%
A3.52E6
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100 3.
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A3.42E6
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3.6ES
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10 Time
37:00 ^8:0039:00
278.1096 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
40:
37:00 38:1)0 39:6o
292.1974 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
40:00
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80
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204
37:00
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42:00 Time
2.0E5
Ll.6E5
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42:00 Time
-------
FUe:30OC98V4 #1-878 Acq^l-OCT-1998 02:33:51 GC EI+ Voltage SIR 70SE
Sample#13 Text:301802-10 :10X DIL.::: ExprPAHAIR
268.9824 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 2
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1.1E7
L1.0E7
L9.2E6
:g.OE6
1&E6
-5.7E6
:4.6E6
J.4E6
:2.3E6
J.IE6
O.OEO
10 Time
r5.5E7
L5.0E7
L4.4E7
L3.9E7
L3.3E7
_2.8E7
-2.2E7
_1.7E7
_1.1E7
-5.5E6
O.OEO
0 Time
eg
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-I-429-FB
Lab ID: 301802-0011-SA
Matrix: AIRTRAIN Sampled: 24 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a ,
Perylene
Indeno (1,2,3 -cd) pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
Result
1600
200
ND
ND
ND
210
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ng/ sample
ng/ sample
ng/ sample
ng/ sample
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Reporting
Limit
«• —
--
100
100
100
--
100
100
100
100
100
100
100
100
100
100
100
100
100
Data
Qualifiers
B
B
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
370
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-I-429-FB
Lab ID: 301802-0011-SA
Matrix: AIRTRAIN Sampled: 24 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)fluoranthene-dl2
Benzolk)fluoranthene-dl2
Benzo(a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
45
54
62
57
61
68
70
64
65
81
89
72
87
68
75
70
% Recovery
103
m
m = Internal Standard recovery is outside method recovery goal. >f .. r
Reported By: Clark Pickell Approved By: ^rit Redman
The cover letter is an integral part of this report.
Rev 230787
-------
4-NOV-1998 06:34:05 PM Dioxin Furan Unknown RESULTS
ass Spec : VG-4
C Column : DB-5
ata file : 300C98V4
eight : 0.5
Name
dlO - 2 -Me thy Inaphthalene
d8-Naphthalene
Naphthalene
2 -Me thyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
12-Benzo (b) f luoranthene
Benzo(b)fluoranthene
12-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
12-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
14-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 30OC98V4141.RES
Date analyzed
301802-11 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
7751400 1.00 Y
7890140 1.00 Y
151028800 1.00 Y
8790760 1.00 Y
5068280 1.00 Y
2545600 1.00 Y
3581540 1.00 Y
1356346 1.00 Y
5198000 1.00 Y
4176380 1.00 Y
* No Peak 0.00 N
8892200 1.00 Y
16545020 1.00 Y
* No Peak 0.00 N
10706800 1.00 Y
10283040 1.00 Y
6852180 1.00 Y
11419840 1.00 Y
4832060 1.00 Y
6196900 1.00 Y
496926 1.00 Y
12217860 1.00 Y
1754734 1.00 Y
29385200 1.00 Y
9575520 1.00 Y
3097500 1.00 Y
24254600 1.00 Y
3097500 1.00 Y
13446080 1.00 Y
1355680 1.00 Y
583780 1.00 Y
12063480 1.00 Y
87404 1.00 Y
1053172C 1.00 Y
85246 1.00 Y
5405380 1.00 Y
* No Peak 0.00 N
11903780 1.00 Y
389202 1.00 Y
4176380 1.00 Y
3469460 1.00 Y
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
21:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
27
13
16
34
28
31
1
8
56
42
48
46
50
0
1
37
40
18
21
10
14
16
21
22
31
36
36
39
35
28
41
51
56
5
11
10
15
14
23
42
47
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N -
Y
Y
Y
Y
1.00
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
1.00
1.41
1.11
1.52
1.21
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
1.40
0.58
1.02
1.00
0.81
50.00
22.71
.562.43
198.76
45
B
B
26.94 54
-------
04-NOV-1998 06:34:01 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
45
B
B
54
100.00
62
100.00
57
100.00
61
B
100.00
68
100.00
70
100.00
64
100.00
89
100.00
72
100. .00
87
100.00
68
100.00
100.00
65
100.00
81
100.00
75
100.00
70
100.00
3875700
3945070
75514400
4395380
2534140
1272800
1790770
678173
2599000
2088190
0
4446100
8272510
0
5353400
5141520
3426090
5709920
2416030
3098450
248463
6108930
877367
14692600
4787760
1548750
12127300
1548750
6723040
677840
291890
6031740
43702
5265860
42623
2702690
0
5951890
194601
3875700
3945070
75514400
4395380
2534140
1272800
1790770
678173
2599000
2088190
0
4446100
8272510
0
5353400
5141520
3426090
5709920
2416030
3098450
248463
6108930
877367
14692600
4787760
1548750
12127300
1548750
6723040
677840
291890
6031740
43702
5265860
42623
2702690
0
5951890
194601
373
-------
<2-NOV-1998 09:09:00 AM Dioxin Furan Unknown RESULTS
lass Spec : VG-4
1C Column : DB-5
lata file : 300C98V4
leight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo (a) anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
12-Benzo (b) f luoranthene
Benzo(b)fluoranthene
12-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
12 - Indeno(123 -cd)pyrene
Indeno(123 -cd)pyrene
14-Dibenz(ah)anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4141.RES
Date analyzed
301802-11 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
7751400 1.00 Y 12
7890140 1.00 Y 10
151028800 1.00 Y 10
8790760 1.00 Y 12
5068280 1.00 Y
2545600 1.00 Y
3581540 1.00 Y
1356346 1.00 Y
5198000 1.00 Y
4176380 1.00 Y
* No Peak 0.00 N
8892200 1.00 Y
16545020 1.00 Y
* No Peak 0.00 N
10706800 1.00 Y
10283040 1.00 Y
6852180 1.00 Y
11419840 1.00 Y
4832060 1.00 Y
6196900 1.00 Y
496926 1.00 Y
12217860 1.00 Y
1754734 1.00 Y
29385200 1.00 Y
9575520 1.00 Y
3097500 1.00 Y
24254600 1.00 Y
3097500 1.00 Y
13446080 1.00 Y
1355680 1.00 Y
583780 1.00 Y
12063480 1.00 Y
87404 1.00 Y
10531720 1.00 Y
85246 1.00 Y
5405380 1.00 Y
* No Peak, 0.00 N
11903780 1.00 Y
389202 1.00 Y
4176380 1.00 Y
3469460 1.00 Y
27 Y
13 Y
16 Y
34 Y
: PAHAIR.TRG
: 30-OCT-98
: PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
1.00 50.00
2.24 22.71 45
1.23 1562.43 0.000
0.56 198.76 0.000
15:
15:
16:
16:
20:
17:
17:
20:
20:
21:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
28
31
1
8
56
42
48
46
50
0
1
37
40
18
21
10
14
16
21
22
31
39
36
39
35
28
41
51
56
5
11
10
15
14
23
42
47
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
1
1
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
•21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.25
.40
.58
.02
.42
.00
26
53
31
30
50
28
0
30
208
0
50
34
59
35
35
32
6
44
13
50
35
27
43
10
33
6
4
32
0
40
I
37
0
34
3
5
,,,83
.94
.20
.03
.39
.00
.27
.00
.47
.00
.00
.00
.04
.94
.13
.11
.15
.66
.60
.25
.00
.90
.71
.53
.97
.81
.14
.05
.57
.42
.31-
.30
:42
.00
.94
.22
.00
^i07
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
0
0
0
54
.000
62
.000
57
.000
€1
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68
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70
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64
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89
.000
72
.000
87
.000
68
.000
.000
65
.000
81
.000
75
.000
70
.000
10
.000
-------
File:30OC98V4 #1-510 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll :10X OIL. : :: Exp:PAHAER
128.0626 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 9
.
80 J
60
40J
20-
0
A7.55E7 :
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(J.OEO
)0 Time
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136.1128 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
152.1410 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60 J
401
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0:
9:0
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60 J
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L1.7E5
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9.6ES
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60 J
40J
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O.OEO
0 Time
10
-------
File:30OC98V4 #1-510 Acq:31-OCT-1998 03:22s54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll :10X DIL.::: Exp:PAHAIR
152.0626 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.27E6
80 J
60 J
40 J A3.23E5
20-
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L2.6E5
L1.9E5
U.3E5
6.4E4
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i—'—i—i—i—i—i—i—i—i—i—r—i—'—i—i—i—i—i—i—•—i—i—i—i—i—'—i—i—i—i—i—'—i—i—i—r*i—i—i—i—I—i—'—i—i—i—i—i—'—'—i—i—I—i—i—i—i—r—i—i—i—i—i—i—I—i—•—'—i—i—i—i—'—'—i—i—r~i—*—i—'r—ii *~~* i r~ ~
14:60 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:00 Time
160.1128 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.53E6 ,_5.5E5
90-
601
40J
20 J
A6.81E5
A1.09S5
0 r-r-^-r- , , , , ,
14:66 14:li 14:24 14:36 14:48 15:66 15:12 15:24 15736^^15:48 16:67' I6:ii 16:^ '^1656^^16^6 17:
154.0782 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60-
40-
20-
0.
A2.
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14:60 14:12 14:24 14:36
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T—i—i—i—i—•—i—i—i—i—i—i—i—i—i—i—i—i—TT—i—i—i—'—i—r—i—i—<—i—i—i—I—i—i—i—i—i—i—i—i—i—i—i—I—i—i—i—i—i—1—r~
14:48 15:60 15:12 15:24 15:36 15:48 16:60 16:12 16:24
,10000.0,0.00%SF,T)
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14.4E5
L3.3E5
L2.2E5
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O.OEO
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5.0E5
_4.0E5
-3.0E5
12.0E5
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-^-^.-O.OEO
17:00 Time
4.5E5
L3.6E5
L2.7E5
LI.SES
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14:4)0
14
34"
14:48 15
15:48 ^16
17:60 Time
-------
F11c:30OC98V4 #1-510 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll rlOXDIL.: :: Exp:PAHAIR
130.9920 S:14 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.78E8
95.
90
85:
80:
75:
70:
65:
60:
55:
50:
45:
40:
35:
30
25
20
15
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0
9:
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12:60
13:60
14:60
L».4E7
-8.8E7
:8.2E7
:7.5E7
:6.9E7
:6.3E7
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4.4E7
t3.8E7
3.1E7
2.5E7
1.9E7
1.3E7
:6.3E6
O.OEO
0 Time
0
ll
15:6o
16:6o
-------
File:30OC98V4 #1-641 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll :10X DIL. : : : Exp:PAHAIR
166.0798 S:14 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
40 J
30 4
20 J
10 J
o
A1.43E7
-6.2E6
L5.5E6
U.9E6
U.3E6
L3.7E6
L3.1E6
L2.5E6
L1.8E6
1.2E6
L6.2E5
O.OEO
)0 Time
17:00 17:12 17:24 17:36 17:48 18:66 18:i2
172.0984 S:14 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.73E6
90 J
80 J
70 J
60 J
50 J
40:
30 J
20 J
10 J
18:24 18:36 18:48 19:6o 19:^2 19:24 19:36 19:48 20:
TT-rTT
17:00 "lliii ' ^17:24 ' li^T^7:& ' ' 18:66 18:1
176.1410 S:14 F:2 SMOa,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
18-36^18:48 19:66 W:li 19:24 19:36 19:48
90 J
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-------
File:30OC98V4 #1-<541 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-11 :10X DIL. : : : Exp:PAHALR
178.0782 S:14 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:300C98V4 #1-641 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
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File:300C98V4 #1-939 Acg:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
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Flle:30OC98V4 #1-939 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
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FUe:30OC98V4 #1-939 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
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FHe:30OC98V4 #1-878 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll :10X DIL. : :: Exp:PAHAR
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-------
FUe:30OC98V4 #1-878 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
Sample#14 Text:301802-ll :10X OIL. :: : Exp:PAHAER
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Flle:30OC98V4 #1-878 Acq:31-OCT-1998 03:22:54 GC EI+ Voltage SIR 70SE
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-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: A-0-429-FB
Lab ID: 301802-0012-SA
Matrix: AIRTRAIN Sampled: 24 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b
Benzo k
Benzo e
Benzo a
Perylene'
Indeno(1,2,3-cd)pyrene
Di benz(a,hj anthracene
Benzo(g,h,i)perylene
fluoranthene
fluoranthene
pyrene
pyrene
1000 ng/sample --
ND ng/sample LQQ
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
270 ng/sample --
ND ng/sample 100
190 ng/sample --
150 ng/sample —
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample 100
ND ng/sample , LOO
ND ng/sample 100
B
B = Compound is also detected in t1« tilank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: ErfcsHednran
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-0-429-FB
Lab ID: 301802-0012-SA
Matrix: AIRTRAIN Sampled: 24 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogates
13C-Fluorene
% Recovery
46
54
68
51
65
75
71
60
57
73
94
80
77
61
66
66
% Recovery
107
m
m « Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
04-NOV-1998 06:32:52 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl 0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2 - Indc:io (123 - cd) pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4151.RES
Date analyzed
301802-12 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio tnm:ss
5288960 1.00 Y
5453300 1.00 Y
69007400 1.00 Y
2464560 1.00 Y
3478260 1.00 Y
555228 1.00 Yr~ 15
2661640 1.00 Y
1579826 1.00 Y
3746380 1.00 Y
2729320 1.00 Y
965902 1.00 Y
6811120 1.00 Y
16420000 1.00 Y
* No Peak 0.00 N
7701460 1.00 Y
8133080 1.00 Y
16742020 1.00 Y
8254040 1.00 Y
15148300 1.00 Y
4176740 1.00 Y
977006 1.00 Y
9286780 1.00 Y
4474660 1.00 Y
21132600 1.00 Y
7689560 1.00 Y
9149740 1.00 Y
15475900 1.00 Y
9149740 l.OO^Y
8657940 l.OQ Y
4443260 l.OQ Y
2517480 1.00 Y
7564260 1.00 Y .33
968200 1.00 Y
6884340 1.00 Y
793534 1.00-Y
3421880 1.00T.3B: S.~Y
* No ;peak 0.00 N 38: 15 N
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
12
10
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12
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16
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20
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1032.91 B
-------
l-NOV-1998 06:32:48 PM Dioxin Furan Unknown RESULTS
0.5
3V4.RRF
'MDL
46
B
00.00
54
00.00
68
00.00
51
DO. 00
65
B
00.00
75
71
60
00.00
94
DO. 00
80
30.00
77
30.00
61
30.00
30.00
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30.00
73
30.00
66
30.00
66
30.00
2644480
2726650
34503700
1232280
1739130
277614
1330820
789913
1873190
1364660
482951
3405560
8210000
0
3850730
4066540
8371010
4127020
7574150
2088370
488503
4643390
2237330
10566300
3844780
4574870
7737950
4574870
4328970
2221630
1258740
3782130
484100
3442170
399767
1710940
0
4032540
1180330
2644480
2726650
34503700
1232280
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277614
1330820
789913
1873190
1364660
482951
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0
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4643390
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399767
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0
4032540
1180330
o
-------
02-NOV-1998 09:12:25 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 300C98V4151.RES
Date analyzed
301802-12 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
5288960 1.00 Y
5453300 1.00 Y
69007400 1.00 Y
2464560 1.00 Y
3478260 1.00 1
555228 1.00 Y
2661640 1.00 Y
1579826 1.00 Y
3746380 1.00 Y
2729320 1.00 Y
965902 1.00 Y
6811120 1.00 Y
19592620 1.00 Y
* No Peak 0.00 N
7701460 1.00 Y
8133080 1.00 Y
16742020 1.00 Y
8254040 1.00 Y
15148300 1.00 Y
4176740 1.00 Y
977006 1.00 Y
9286780 1.00 Y
4474660 1.00 Y
21132600 1.00 Y
7689560 1.00 Y
9149740 1.00 Y
15475900 1.00 Y
9149740 1.00 -Y
8657940 1.00 Y
4443260 1.00 Y
2517480 1.00 Y
7564260 1.00 Y..:33
968200 l.OO-'Y
688434O;l.OO-Y
799534 1.0-Q'Y' 35
3421880 1.00 Y
* No :.Peak 0.00 N
8065080 1.00 Y
2360660 1.00 Y
2729320 1.00 Y
2357220 1.00 Y
PAHAIR.TRG
30-OCT-98
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File:30OC98V4 #1-640 Acq:31-OCT-1998 04:11:55 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-878 Acq:31-OCT-1998 04:11:55 GC EI+ Voltage SIR 70SE
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)0 Time
-------
Nk:300C98V411-878 Acq:31-OCT-1998 04:11:55 GC E14- Voltage SIR 70SB
Sample*! 5 Text:301802-12 :10X D1L. : t: Exp'.PAHAIR
268.9824 S:15 F:4 SMO(1,3) PKD(5,3)3,0.10%,10000.0,0.00%,F,T)
1005
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i.3.5E7
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K) Time
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name;
Client ID:
Lab ID:
Matrix:
Authorized:
Pacific Environmental Services
A-U-429-FB
301802-0013-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 25 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indenofl,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
980
ND
ND
ND
ND
120
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ng/sample —
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample --
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample r 100
ng/sample 100
ng/sample 100
ng/sample 100
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved Byt
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Client Name: Pacific Environmental Services
Client ID: A-U-429-FB
Lab ID: 301802-0013-SA
Matrix: AIRTRAIN Sampled: 25 SEP 98
Authorized: 29 SEP 98 Prepared: 03 OCT 98
Dilution Factor: 1.0
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-F.luorene
% Recovery
48
63
66
64
67
83
80
61
57
73
106
81
89
65
77
73
% Recovery
98
m
m = Internal Standard recovery is outside method recovery goal.
Reported By: Clark Pickell Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
4-CB
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Pacific Environmental Services
A-429-LB
301802-0014-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 21 SEP 98
Prepared: 03 OCT 98
Received:: 29 SEP 98
Analyzed: 31 OCT 98
Parameter
Result
Units
Reporting
Limit
Data
Qualifiers
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo a pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
840
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ng/sample --
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
ng/sample 100
B = Compound is also detected in the blank.
ND = Not Detected
Reported By: Clark Pickell
Approved By: Eric Redman -»•-
The cover letter is;an integral part of this report.
Rev 230787
407
-------
Client Name;
Client ID:
Lab ID:
Matrix:
Authorized:
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
(cont.)
Pacific Environmental Services
A-429-LB
301802-0014-SA
AIRTRAIN
29 SEP 98
Dilution Factor: 1.0
Sampled: 21 SEP 98
Prepared: 03 OCT 98
Received: 29 SEP 98
Analyzed: 31 OCT 98
Internal Standards
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Field Surrogates
13C-Fluorene
% Recovery
52
51
57
69
77
84
82
56
61
64
106
76
87
65
60
64
% Recovery
101
Reported By: Clark Pickell
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
04-NOV-1998 06:31:30 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo (e)pyrene'
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(122 -cd)pvrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4161.RES
Date analyzed
301802-13 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
6982280 1.00 Y
7543540 1.00 T
90182800 1.00 Y
3341280 1.00 Y
5337120 1.00 Y .LVT1?
776366 1.00 Y
3454280 1.00 Y
3103040 1.00 Y
4145120 1.00 Y
3760600 1.00 Y
1032322 1.00 Y
7745400 1.00 Y
8542160 1.00 Y
* No Peak 0.00 N
8371620 1.00 Y
9841480 1.00 Y
5822140 1.00 Y
10117500 1.00 Y
3920480 1.00 Y
4606660 1.00 Y
470572 1.00 Y
11376840 1.00 Y
1856788 1.00 Y
24296200 1.00 Y
8959640 1.00 Y
3841940 1.00 Y
20509600 1.00 Y
3841940 1.00 -Y
10607600 1.00 Y
2017800 1.00 Y
829178 1.00 Y
8739940 1.00 Y
152913 1. 00 -Y 33
73C7C30 1.00 Y
94214 1.00'^Y
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
12:
XD:
10:
12:
'$*'£
15:
16:
16:
20:
17:
17:
20:
20:
21:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33.
33-
38:
.38:
28 Y
12 Y
16 Y
34 Y
.-3fi -Y
"31 Y
2 Y
9 Y
56 Y
42 Y
48 Y
46 Y
51 Y
0 N
1 Y
37 Y
40 Y
18 Y
21 Y
10 Y
15 Y
16 Y
21 Y
22 Y
30 Y
36 Y
36 Y
39 Y
35 Y
28 Y
40 Y
.52 Y
56 Y
10 Y
1.00
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
1.00
1.41
1.11
1.52
1.21
0.90
1.20
1.28
1.08
1.00
0.45
1.17
0.95
1.16
0.68
1*07
0 .63
,:"•• 1-71
0 . 44
•-0.62
4576220 1.00 Y
* No Peak 0. OO; N
10277380 1.00 Y
1417142 1.00 Y
3760600 1.00 Y
2991860 1.00 Y
1.00
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
50.00
24.11 48 n1,!
975.83 B
|
30.57 61 i,
-------
4-NOV-1998 06:31:27 PM Dioxin Furan Unknown RESULTS
BV4.RRF
Rec/
MDL
48
B
00.00
63
00.00
66
30.00
64
30.00
67
B
30.00
83
30.00
80
30.00
61
30.00
106
30.00
81
JO.00
89
JO.00
0.5
3491140
3771770
45091400
1670640
2668560
388183
1727140
1551520
2072560
1880300
516161
3872700
4271080
0
4185810
4920740
2911070
5058750
1960240
2303330
235286
5688420
928394
12148100
4479820
1920970
10254800
1920970
5303800
1008900
414589
4369970
76457
3948540
47107
2288110
0
5138690
708571
3491140
3771770
45091400
1670640
2668560
388183
1727140
1551520
2072560
1880300
516161
3872700
4271080
0
4185810
4920740
2911070
5058750
1960240
2303330
235286
5688420
928394
12148100
4479820
1920970
10254800
1920970
5303800
1008900
414589
4369970
76457
3948540
47107
2288110
0
5138690
708571
-------
02-NOV-1998 09:15:56 AM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 300C98V4
: 0.5
Name
Results : 300C98V4161.RES
Date analyzed
301802-13 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
6982280 1.00 Y
7543540 1.00 Y
90182800 1.00 Y
3341280 1.00 Y
5337120 1.00 Y
776366 1.00 Y
3454280 1.00 Y
3103040 1.00 Y
4145120 1.00 Y
3760600 1.00 Y
1032322 1.00 Y
7745400 1.00 Y
8542160 1.00 Y
* No Peak 0.00 N
8371620 1.00 Y
9841480 1.00 Y
5822140 1.00 Y
10117500 1.00 Y
3920480 1.00 Y
4606660 1.00 Y
470572 1.00 Y
11376840 1.00 Y
1856788 1.00 Y
24296200 1.00 Y
8959640 1.00 Y
3841940 1.00 T
20509600 1.00 Y
3841940 1.00 Y
10607600 1.00 Y
2017800 1.00 Y
829178 1.00 Y
8739940 1.00 Y
152913 1.00 Y
7897080 1.00 -Y
.94214 1.00'Y
4576220 1.00 Y:
* NO peak O.OO;N
10277380 1.00 Y
1417142 1.00 Y
3760600 1.00 Y
2991860 1.00 Y
-12-
10
10
12
'V *} .
15
16
16
20
17
17
20
20
21
26
24
24
25
25
29
29
29
29
33
32
32
:
:
:
:
i.
:
.
:
.
:
:
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:
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;
:
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:
.
:
.
.
.
:
J
28
12
16
34
fsfc
31
2
9
56
42
48
46
51
0
1
37
40
18
21
10
15
16
21
22
30
36
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y ;
Y
YL
Y'
Y
1
2
1
0
* 1
* 0
0
1
1
1
1
2
0
0
... 1
• 1
1
1
1
0
1
!
1
!_
0,
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.281
'. 08
i, ,
*.oa •/
V45-^.
.17»,
50.00
24.11
975.83
79.02
31.49
15.41
33.22
72.09
50.00
31.93
23.65
33.28
123.29
0.00
50.00
41.67
53.21
39.80
32.16
30.57
8.48
53.12
15.06
50.00
40.63
36.74
48
0.000
0.000
63
0.000
66
0.000
64
0.000
67
0.000
0.000
83
0.000
80
0.000
61
0.000
106
0.000
81
0.000
if,: '•:"--:
32
32
33
33
33
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39
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17
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;
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.
.
:
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:
36
36
35
28
40
52
56
-.5
-10
-,B-
15-
14
21
42
47
Y
Y
Y
Y
Y
Y
Y
Y
Y.
Y
N
Y
Y
Y
Y
0
1
0
1
.95-
.16
.68 -
.64 /
; LOT"
0
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0
0
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44.52
16.09
32.26
11.591
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36.56
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36.48
13.57
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0:000,
,• 57
O-OOO
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^'^
o.ooo
11
Ip.ooo
-------
File:300C98V4 #1-510 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X OIL. :: : Exp:PAHAIR
1002
80 J
60 1
40J
20 J
0:
9:(
136.1
1002
80 J
60 J
40:
20 J
0
9:(
142.0
100 2
80 J
60-
40_
20-
0
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152.1
1002
80:
60-
40.:
20-
0.
9:
A4.51E7
IT
A1.44E7 Jf
^ IV
0 10:00 11:00 12:00 13:00 14:00 15:
128 S:16 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.77E6
/
{
IV
0 10:6o 11:1)0 12:1)0 13:1)0 14:00 15:
782 S:16 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
p A1.67E6
l\
^
\ A8.18E5
~^_ ^ : — ^ _ ^-
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0 10:6o ll:6o 12:6fl 13:00 14:6fl 15:
410 S:16 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.4S
1
E6
V
do 10:i)0 11:00 12:6o 13:6o 14:00 ' ' ' ' IS-.t
-9.1E6
-7.3E6
L5.5E6
13.6E6
Ll.8E6
1 O.OEO
)0 Time
_7.6E5
16.1E5
L4.6E5
L3.1E5
-1. 5E5
O.OEO
)0 Time
3.5E5
-2.8E5
-2.1E5
-1.4E5
-7.1E4
O.OEO
)0 Time
r7.1E5
-5.6E5
:.4.2E5
:2.8E5
:1.4ES
LO.OEO
M) Time
-------
File:30OC98V4 #1-510 Acq:3l-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X OIL.::: Exp:PAHAIR
152.0626 S:16 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
801
0
" ' ' ' i i I—i i i i—i |i" i i—i—i i i • i—i—i—r—i—•—i—i—i—i—i—i—'ill—i—r
14:60 14:12 14:24 14:36 4 14:48 15:60 15:12
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100%
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OEO
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P11c:300C98V4 #1-510 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X DIL. : : : Exp:PAHAlR
130.9920 S:16 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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10 Time
-------
File:30OC98V4 #1-640 Acqi3l-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X DIL. :: : Exp:PAHAIR
166.0'
100 S
90 J
80 J
70 J
60 J
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40J
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172.0984 S:16 F:2 SMO(1,3) PKD(5,J J,0.10%,10000.0,0.00%,F,T)
1002
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176.1410 S:16 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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10 Time
-------
FUe:30OC98V4 #1-«40 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X DIL. :: : Exp:PAHAIR
178.0782 S:16 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.2.7E6
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-------
F1le:30OC98V4 #1-640 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X OIL. : : : Exp:PAHAIR
204.9888 S:16 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
17
O.OEO
0 Time
-------
FUe:30OC98V4 #1-939 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X DDL.: : : Exp:PAHAIR
202.0782 S:16 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-939 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X OIL. : :: Exp:PAHAIR
228.0939 S:16 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
F1te:300C98V4 #1-939 Acq:31-OCT-1998 05:00:59 GC EH- Voltage SIR 70SE
Sample#l<> Text:301802-13 :10X OIL.: :: Exp:PAHAIR
230.9856 S:16 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FiIe:30OC98V4 #1-878 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X OIL.: :: Exp:PAHAIR
252.0939 S:16 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
Al.ft
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901
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70 J
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201
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A1.01E6
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264.1692 S:16 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
35:00
36:00
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-------
Flle:30OC98V4 #1-878 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sampled6 Text:301802-13 :10X OIL. : : : Exp:PAHAIR
276.0939 S:16 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FUe:30OC98V4 #1-878 Acq:31-OCT-1998 05:00:59 GC EI+ Voltage SIR 70SE
Sample#16 Text:301802-13 :10X DIL. :: : Exp:PAHAIR
CO
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-------
04-NOV-1998 06:39:37 PM Dioxin Furan Unknown RESULTS
Mass Spec : VG-4
SC Column : DB-5
Data file : 300C98V4
Height : 0.5
Name
dlO-2-Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 -Acenaphthylene
Acenaphthylene
dl 0 - Acenaphthene
Acenaphthene
dlO- Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0 - Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e)pyrene
d!2 -Benzo (b) f luoranthene
Benzo (b) f luoranthene
dl2-Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2-Benzo(a)pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
2 -Indeno(123-cd)pyrene
Indeno ( 12 3 - cd) pyrene
dl4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo(ghi)perylene
Benzo (ghi)perylene
dlO- Fluorene
13C-Fluorene
Results : 300C98V4171.RES
Date analyzed
301802-14 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
PAHAIR.TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
I
*
*
*
*
*
*
*
{.espouse t
5685740
6638940
68232000
2281260
3503460
795420
2401500
2678860
3069780
3021600
No Peak
6628280
5920000
No Peak
6833340
8104240
2461920
8492000
1667360
3454960
49906
9265380
111607
22229200
7676980
272806
18343580
272806
9845640
321448
No Peak
8587120
No Peak
6284360
No Peak
3260000
No Peak
8282640
No Peak
3021600
2471900
Cd
1
1
1
1
1
1
1
1
1
1
0
1
1
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
0
1
0
1
0
1
0
1
1
CIO
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
Y
N
Y
N
Y
Y
mm
12
10
10
12
15
15
16
16
20
17
17
20
20
21
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
sa
28
12
16
34
28
31
1
8
57
43
49
47
51
1
1
37
41
18
22
11
18
17
21
22
31
36
36
36
35
29
38
51
55
- 3
8
5
15
14
21
43
48
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
Y
N
Y
N
Y
Y
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
1
0
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.25
.40
.58
.02
.00
..81
50.00
26.06 52
838.91 B
-------
04-NOV-1998 06:39:33 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
52
B
100.00
51
100.00
57
100.00
69
100.00
77
100.00
100.00
84
100.00
82
100.00
56
100.00
106
100.00
76
100.00
87
100.00
65
100.00
100.00
61
100.00
64
100.00
60
100.00
64
100.00
2842870
3319470
34116000
1140630
1751730
397710
1200750
1339430
1534890
1510800
0
3314140
2960000
0
3416670
4052120
1230960
4246000
833680
1727480
24953
4632690
55803
11114600
3838490
136403
9171790
136403
4922820
160724
0
4293560
0
3142180
0
1630000
0
4141320
0
2842870
3319470
34116000
1140630
1751730
397710
1200750
1339430
1534890
1510800
0
3314140
2960000
0
3416670
4052120
1230960
4246000
833680
1727480
24953
4632690
55803
11114600
3838490
136403
9171790
136403
4922820
160724
0
4293560
0
3142180
0
1630000
0
4141320
0
"«&».-
425
-------
,2-NOV-1998 09:19:24 AM Dioxin Furan Unknown RESULTS
lass Spec : VG-4
1C Column : DB-5
lata file : 30OC98V4
(eight : 0.5
Name
dlO - 2 -Me thy Inapht halene
d8-Naphthalene
Naphthalene
2 -Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dl0-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
112-Benzo(b) fluoranthene
Benzo(b)fluoranthene
112-Benzo (k) fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
i!2 - Indeno (12 3 - cd) pyrene
Indeno(12 3 -cd)pyrene
114-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4171.RES
Date analyzed
301802-14 :10X DIL. : : : Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
5685740
6638940
68232000
*
*
No
2281260
3503460
795420
2401500
2678860
3069780
3021600
Peak
6628280
6636760
No Peak
6833340
8104240
2461920
8492000
1667360
3454960
49906
9265380
111607
22229200
7676980
272806
18343580
*
*
*
*
*
*
No
No
No
No
No
No
272806
9845640
321448
Peak
8587120
Peak
6284360
Peak
Peak
Peak
8282640
Peak
3021600
2471900
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
0.
0.
0.
1.
0.
1.
1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
N
N
Y
N
Y
Y
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
21:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
28
12
16
34
28
31
1
8
57
43
49
47
51
1
1
37
41
18
22
11
18
17
21
22
31
36
36
36
35
29
38
51
55
5
8
5
15
14
21
43
48
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
Y
N .:-
Y
N
Y
Y
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
. 1
0
1
1
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.25
.40
.58
.02
.42
.00
PAHAIR. TRG
30-OCT-98
PAHAIR102998V4.R
pg/ Rec/
SAMP MDL
50.00
26.06 52
838.91 0.000
61.30 0.000
25.38 51
24.05 0.000
28.36 57
89.52 0.000
50.00
34.64 69
0.00 0.000
38.45 77
111.94 0.000
0.00 0.000
50.00
42.03 84
27.32 0.000
40.93 82
16.29 0.000
28.09 56
1.20 0.000
53.00 106
1.11 0.000
50.00
38.05 76
3.04 0.000
43.52 87
1.28 0.000
32.73 65
1.99 0.000
0.00 0.000
30.65 61
0.00 0.000
31.80 - 64
0.00 0.000
*NoINoIs '
32.14 64
0.00 0.000
4.78 10
81.81 0.000
-------
Flle:30OC98V4 #1-510 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Samplell? Text:301802-14 :10X DIL. : : : Exp:PAHAIR
128.0626 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 8
80:
60:
40:
20:
0
136.1
100 S
80 J
60:
40:
20:
oi
9:C
A3.41E7
(
-'
M
IV
0 10:00 11:00 12:00 13:00 14:00 ]5:
128 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T) '
A3.32E6
_ ... . ,_ -•
i u
i-' '•
V
0 10:00 11:60 12:60 13:00 14:bO 15:
7.1E6
L5.7E6
i.4.3E6
L2.8E6
Ll.4E6
: O.OEO
10 Time
\'
_7.2E5
.5.8E5
14.3E5
-2.9E5
-1.4E5
-O.OEO
)0 Time
142.0782 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80:
60:
40:
20:
0
9:C
152.1
1003
80:
60:
40:
20:
0
9:(
Al
' *4E6
1/A6.04E5
L-
— - ^~ - ^ •, -^ . ~^_^ . -~> — -^-r s . -~ - ' ^
0 10:6o ll:6o 12:6o 13:00 14:00 15:
410 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A2. 4E6
/
L
1 1 1 1 1 1 " j 1 • • 1 r ' 1 1 1 1 r - — i 1 1 r 1 1 • 1 • r ' 1 1 1 1
0 10:bO 11:60 12:00 13:60 14:00 15:
r2.3E5
-1.8E5
-1.4E5
-9.2E4
-4.6E4
O.OEO
10 Time
5.6E5
L4.5E5
L3.3E5
12.2E5
Ll.lES
1 O.OEO
)0 Time
-------
Flle:30OC98V4 #1-510 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Sampled? Text:30l802-14 :10X DIL.: :: Exp:PAHAK
152.0626 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
80 J
60 J
40J
20 J
0
14:
160.11
1002
80 J
60 J
40J
20 J
14:
154.0
100 S
80.:
60 _:
40
20 1
0:
14:
164.1
1002
80 _:
60 j
401
20 J
0-:
14:
A3.98ES JS
I \ A g 90174
A1'53NES A9.38E4 A5.05E4 / V^'J^4 J-^/\ A1.04E5 A1.03E5
6 14:i2 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:00 16:i2 16:24 16:36 16:48 17:1
128 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.75E6
A
/ \
1 A A5.87E5
/ V_ /V
W 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:
782 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T) ^
V\ /N A8*AES/X /\A1/\'6A. A1-07E6 A9.50E5 A134E6 A1.37E6
-
7
)0 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:
410 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0>0.00%,F,T)
, A1.20E6
A
M
/ \
I ^
)0 ' 14:i2 14:24 14:36 14:48 15:6o 15:^12 15:24 15:^6 15:48 16:6b 16:i2 16:24 ' 16:3« ' ' itf:48 ' 17:
97E4:^
_7.3E4
_4.9E4
_2.4E4
O.OEO
)0 Time
-3.6E5
_2.9E5
-2.1E5
:1.4E5
L7.1E4
)0 Time
3.4E5
L2.7E5
-2.1E5
Ll.4E5
-6.8E4
O.OEO
»0 Time
r2.9E5
L2.4E5
H.8E5
-1.2E5
-5.9E4
O.OEO
10 Time
-------
FUe:30OC98V4 #1-510 Acq:31-OCT-1998 05:50:00 GC EH- Voltage SIR 70SE
Sample#17 Text:301802-14 :10X OIL. : : : Exp:PAHAIR
130.9920 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
95:
90:
85:
80:
75:
70:
65:
60:
55:
50:
45:
35:
30:
25:
20:
15
10
5
0
9:
A4.84E7
A1'E8
A9.95E7
.
A7.
7.75E7
A8 01E7
10:00
£f
3)0~
^6o~
So"
16:00
8.3E7
I.7.9E7
L7.5E7
1.7.0E7
L6.6E7
-6.2E7
:5.8E7
-5.4E7
:5.0E7
L4.6E7
:4.1E7
3.3E7
2.9E7
-2.5E7
:2.1E7
:1.7E7
1.2E7
:8.3E6
4.1E6
O.OEO
0 Time
0
11
12
13
14
-------
FUe:30OC98V4 #1-640 Acq:31-OCT-1998 05:50:00 GC B1+ Voltage SIR 70SE
Sample#17 Text:301802-14 :10X OIL. : : : Exp:PAHAIR
166.0798 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
90 J
80 J
70 J
60 J
50 J
40-
30 J
20_
10-
0-
172.0.
1002
90 J
80 J
70 J
60 J
50 J
40 J
30 J
20_
10-
0
17:
176.1
1002
90_
80_
70-
60-
50-
40J
30 J
20 J
10 _:
0:
17:
A3.16E6
f
^
I/
A2.63E5 / V
/~\__ _ J ^-^-~.
10 17:i2 17:24 17:36 17:48 18:66 18:i2 18:24 18:36 18:48 19:66 19:i2 19:24 19:36 19:48 20:1
J84 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.24E6
A
1
1
/
\
\
\
) \_^v_
— i — i — i—n — i1 i i 'i i i i i — i n TI~| i i i i i i i i i i i — i i i — i i T~j T~i^~i P*i ~i i r i i 'i 7" i i i i i — i i ' i i i*n"* r i i i*~i i ITH i T~T i — i i > — r i i — < < i — i i f i • "!^T~
10 17:12 17:24 17:36 17:48 18:6o 18:12 18:24 18:36 18:48 19:00 19:12 19:24 19:36 19:48 20:
410 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.51E6
M
1
1
/
M
I
\
I \
1 ^r^_^_
66 17:ii 17:^4 17:36 17:^8 18:66 18:i2 18:24 18:36 18:48 19:66 19:i2 19:24 19:36 19:48 20:
-1.3E6
L1.1E6 Q
L1.0E6 t^3
L8.8E5 ^
L7.6E5
L6.3E5
L5.0E5
L3.8E5
L2.5E5
L1.3E5
= O.OEO
)0 Time
-2.8ES
L2.5E5
L2.3E5
L2.0E5
-1.7E5
-1.4E5
-LIES
-8.5E4
_5.6E4
-2.8E4
: O.OEO
tO Time
3.7E5
L3.3E5
L2.9E5
L2.6E5
L2.2E5
L1.8E5
L1.5E5
I-1.1E5
L7.3E4
L3.7E4
-O.OEO
M> Time
-------
FUe:30OC98V4 #1-640 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Samplell? Text:301802-14 :10X OIL. : : : Exp:PAHAIR
178.0782 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A3.
90 J
80 J f
70 J
60 J
50 J
40 J
30 j
20 J
10 j
A1.12E6
A1.20E5
A2.S6E4
19:00 20:00
188.1410 S:17 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100 S
90 J
80 J
70 J
60 J
50 j
4Q-
30:
20:
10 J
21:t
22:
19:
A3.3JE6
00
20:00
23:i
7.4ES
L6.7E5
6.0E5
1S.2E5
:,f.-,f
14.5E5
L3.7E5
-3.0ES
L2.2ES
-1.5ES
-7.4E4
O.OEO
H) Time
21:00
23:
r8.8E5
L7.9E5
-7.1E5
L6.2ES
LS.3ES
L4.4E5
;.3.5E5
L2.6E5
Ll.SES
L8.8E4
-O.OEO
10 Time
H
«
•or
-------
Mlf III
1 I
FU£:3,POC98V4 #1-640 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
"" e#17 Text:301802-14 :10X DIL.::: Exp:PAHAIR
82 3:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A2.96E6
A5.92E4
A5.36E4
r 'i i—'—•—•—i—r~<—•—•—i—'—r"1—'—'—•—i—I—'—•—'—•—'—I—'—'—'—•—'—T"1
20:24 20:30 20:36 20:42 20:48 20:54
188.11410 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
21:00 21:06 21:12 21:is 21:24 21:30 21:36
lltllH-
6.0E5
co
-------
A1.29E7
File:30OC98V4 #1-640 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Samplell? Text:301802-14 :10X OIL. :: : Exp:PAHAIR
204.9888 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 * A8.70E6 Al 7E7
„- j • A9.44E6 f| A1.95E7
95 J I A1.17E7
A 1 AnT*1 I / I
90 J
85:
80:
75:
70:
65:
60
55:
50:
45:
40:
35:
30:
25:
20:
15
A1.52E7
A1.02E7
A1.33E7
A8.90E6
A0.10E6
3.2E6
:3.0E6
:2.9E6
:.2.7E6
L2.5E6
L2.4E6
L2.2E6
L2.1E6
L1.9E6
:1.7E6
20:00
'21:60
-1.4E6
L1.3E6
11.1E6
:9.5E5
L7.9E5
L6.3E5
4.8E5
3.2E5
L1.6E5
O.OEO
0 Time
17
00
18:
19:t
22:C
23:
-------
FUe:30OC98V4 #1-939 Acq:3l-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Sampled? Text:301802-14 :10X OIL. : : : Exp:PAHAER
202.0782 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.05E6
23:00 24:6o
212.1410 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002.
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10 J
, , , , , r 1 . r—
23:60 24:00
244.1974 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S,
90_
80_
70-
60_
50.
40-
30 J
20 J
10.
25:
A2.72E5
26:00
23:i)0
A3.42E6
24:6o
25:i
27:
1.1E6
1.0E6
L8.9E5
L7.8E5
L6.7E5
L5.6E5
L4.5E5
L3.4E5
L2.2ES
Ll.lES
LO.OEO
»0 Time
27:t
8.9E5
L8.0E5
L7.1E5
L6.3E5
L5.4E5
L4.5E5
L3.6E5
L2.7E5
L1.8E5
L8.9E4
LO.OEO
0 Time
(..J
-------
File:30OC98V4 #1-939 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
Sample#17 Text:301802-14 :10X OIL.:: : Exp:PAHAIR
228.0939 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
10
26:00 27-fio 28:1)0
240.1692 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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-------
File:30OC98V4 #1-939 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-878 Acq:31-OCT-1998 05:50:00 GC EI+ Voltage SIR 70SE
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-------
Laboratory Control Sample
-------
LABORATORY CONTROL SAMPLE REPORT
Advanced Technology Group - High Resolution
Project: 301802
Category: PAH-HR-AIR PAH by HRGC/HRMS
Test: PAH-HR-AIR
Matrix: AIR
QC Lot: 93 OCT 98-A
Concentration Units: ng/sample
Analyte
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Benzo a pyrene
Perylene
Indeno[l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzol
Benzo(k
Benzofa
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)antnracene-dl4
Benzo(g,h,i)perylene-d!2
QC Run. - 0V
Concentration
Spiked Measured
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
90
100
100
92
77
81
78
80
64
87
77
76
66
73
68
79
90
76
88
27
31
31
28
38
24
26
31
43
36
44
45
32
59
56
54
98-A
Accuracy(%)
LCS Limits
90
103
102
92
77
81
78
80
64
87
77
76
66
73
68
79
90
76
88
53
63
61
55
75
48
52
62
85
71
88
91
65
117
HZ
109
50-150 B
50-150 B
50-150
50-150
50-150 a
50-150 B
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150 #
50-150
50-150
50-150
.50-150 ,-
-50-150 v'T
-50-150 , .-:•:*'
••50-150^
,50-150, ; ^
•50-150
50-150
# = Outside of control limits. ? V
a = See narrative.
B = Compound is also detected in the blank.
441
Calculations are performed before rounding to avoid round-off errors in. calculated results.
-------
04-NOV-1998 12:45:51 PM Dioxin Furan Unknown RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
:"-02N098V4
: 0.5
Name
ResultS
02N098V4041.RES
Date analyzed
- -: = :-0 .- Ex Cal
RRF
dlO - 2 -Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 -Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dl 0 -Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4 -Terphenyl
dl 0 - Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e)pyrene
d!2 -Benzo (b) f luoranthene
Benzo (b) f luoranthene
d!2 -Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2-Benzo(a)pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
dl2 - Indeno ( 1 2 3 - cd ) pyrene
Indeno ( 123 - cd) pyrene
d!4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo (ghi) perylene
Benzo (ghi) perylene
Total Isotope
Response Ratio
89598000
107117000
118374400
61891400
68496200
65663400
40966600
46770000
58228800
41693800
14768940
122660000
89036600
76921400
153815400
104468400
92516200
122108200
94184600
85849400
89463200
167547800
139077000
196315600
63555600
56218200
163542600
126261400
120445000
144201000
87870600
80068200
109039400
102411400
57000000
53816800
57461000
123655400
110815600
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
R.
T.
mm: ss
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
.
•
:
:
.
:
.
:
.
*
:
.
:
:
.
:
:
.
:
.
:
.
:
.
*
•
.
'•
.
:
:
.
:
.
:
.
:
.
:
27
12
16
34
28
30
1
8
55
41
47
46
50
58
0
36
40
17
21
8
12
15
20
21
28
33
34
37
32
26
37
49
55
0
7
5
14
12
21
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4--.*
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 26.68
1.23 90.20
0.56 103.08
1.21
0.94
0-74
1.25
1.00
1.42
1.16
2.81
0.89
0.80
1.00
1.41
1.11
1.52
1.21
0.90
1.20
28
08
1.00
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
1.40
0.58
1.02
31.49
101.55
30.70
91.62
50.00
25.20
50.00
24.07
79.66
26.15
64.01
31.01
86.52
42.58
76.58
50.00
35.67
75.78
43.94
66.32
45.33
72.97
68.06
32.36
79.47
58.68
89.63
55.76
76.07
54.33
88.20
53
B
B
63
61
48 *"*
52
62
85
71
88
91
65
117
112
109
-------
04-NOV-1998 12:45:39 PM Dioxin Furan Unknown RESULTS
0.5
Rec/
MDL
53
B
B
63
61
50
SEE
RI
75
B
48
52
62
85
71
88
91
65
117
112
109
44799000
53558500
59187200
30945700
34248100
32831700
20483300
23385000
29114400
20846900
7384470
61330000
44518300
38460700
76907700
52234200
46258100
61054100
47092300
42924700
44731600
83773900
69538500
98157800
31777800
28109100
81771300
63130700
60222500
72100500
43935300
40034100
54519700
51205700
28500000
26908400
28730500
61827700
55407800
44799000
53558500
59187200
30945700
34248100
32831700
20483300
23385000
29114400
20846900
7384470
61330000
44518300
38460700
76907700
52234200
46258100
61054100
47092300
42924700
44731600
83773900
69538500
98157800
31777800
28109100
81771300
63130700
60222500
72100500
43935300
40034100
54519700
51205700
28500000
26908400
28730500
61827700
55407800
443
r: rj"'
t'"T Ttl~
-------
J-NOV-1998 08:11:46 AM
429AIR Unknown RESULTS
ass Spec
C Column
ata file
eight
: VG-4
: DB-5
: 02N098V4
: 0.5
Name
Results : 02N098V4041.RES
Date analyzed
301802-1LC :LCS : : : :0. Ex Cal
RRF
dlO - 2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
3l2-Benzo(b) fluoranthene
Benzo(b)fluoranthene
dl2-Benzo (k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2 - Indeno (3 2 3 - cd) pyrene
Indeno(12 3-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Total Isotope
.esponse ' Ratio
89598000
107117000
118374400
61891400
68496200
65663400
40966600
46770000
58228800
41693800
14768940
122660000
89036600
76921400
153815400
104468400
92516200
122108200
94184600
85849400
89463200
167547800
139077000
196315600
63555600
56218200
163542600
126261400
120445000
144201000
87870600
80068200
109039400
102411400
88304000
53816800
57461000
123655400
110815600
41693800
117709
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
R. T.
mm: ss
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
27
12
16
34
28
30
1
8
55
41
47
46
50
58
0
36
40
17
21
8
12
15
20
21
28
33
34
37
32
26
37
49
55
0
7
5
14
12
21
41
42
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
PAHAIR.TRG
02-NOV-98
PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1
2
1
0
1
0
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
c
6
-0
1
0
1
1
1
.00
.24
.23
.56
.21
.94
.74
.25
.00
.42
.16
.81
.89
.80
.00
.41
.11
.52
.21
.90
.20
.28
.08
.00
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
..25
.40
.58
.02
.42
.00
50
26
90
103
31
101
30
91
50
25
30
37
81
78
50
24
79
26
64
31
86
42
76
50
35
75
43
66
45
72
68
32
79
58
138
55
.76
54
88
7
.0
.00
.68
.20
.08
.49
.55
.70
.62
.00
.20
.52
.51
.15
.35
.00
.07
.66
.15
.01
.01
.52
.58
.58
.00
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Flfc:02NO98V4 #1-510 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
Sampled Text:301802-lLC :LCS : : : :0. Exp:PAHAIR
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FiIe:02NO98V4 #1-510 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
Sample#4 Text:301802-lLC jLCS ::: :0. Exp:PAHAIR
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File:02NO98V4 #1-641 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
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FHe;:p2NO98V4 #1-938 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
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-------
File:02NO98V4 #1-938 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
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Flle:02NO98V4 #1-878 Aca: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 15:40:28 GC EH- Voltage SIR 70SE
Sampled Text:301802-lLC :LCS : : : :0. ExprPAHAIR
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-------
FU4:02NO98V4 #1-878 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
Sampled Text:301802-lLC :LCS : : : :0. Exp:PAHAIR
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FTIe:02NO98V4 #1-878 Acq: 2-NOV-1998 15:40:28 GC EI+ Voltage SIR 70SE
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l-NOV-1998 12:49:26 PM
1SS Spec : VG-4
•> Column .:, DB-5
""
Dioxin Furan Unknown RESULTS
Results
jight
: 0.5
Name
dlO- Anthracene
dlO-Fluorene
Fluorene
301802-
Total
Response
03N098V4041.RES
Date analyzed
t-'-C'-r-^S-.- -fee • -Sal
Iscitope R. T. RRF
Ratio tran:ss
PAHAIR.TRG
03-NOV-98
PAHAIR1029-9#lf4%R^
ng/ Rec/
TRAIN MDL
23399000 1.00 Y
18381380 1.00 Y
16485420 1.00 Y
20: 54 Y
17: 41 Y
17: 47 Y
1.00 50.00
1.42 27.64
1.16 77.28
55
-------
04-NOV-1998 12:49:23 PM Dioxin Furan Unknown RESULTS
0.5
98V4.RRF
Rec/
MDL
11699500 11699500
55 9190690 9190690
8242710 8242710
~Jf
-------
13-NOV-1998 02:32:51 PM
429AIR Unknown RESULTS
Jass Spec : VG-4
}C Column : DB-5
)ata file : 03NO98V4
jeight : 0.5
Name
dlO - 2 -Methy Inaphthalene
d8 -Naphthalene
Naphthalene
2 -Methy Inaphthalene
d8 -Acenaphtftylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
x" — STO -Anthracene
I dlO-Fluorene
X Fluorene
dl 0 - Phenant hrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO - Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e) pyrene
!12-Benzo (b) f luoranthene
Benzo (b) f luoranthene
12-Benzo(k) f luoranthene
Benzo (k) f luoranthene
d!2-Benzo(a) pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
12-Indeno ( 12 3 -cd) pyrene
Indeno(123-cd)pyrene
14-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2 -Benzo (ghi) perylene
Benzo (ghi) perylene
dlO -Fluorene
13C-Fluorene
Results : 03NO98V4041
Date
301802-1LC :LCS : : ; :(
Total Isotope
Response Ratio
37412400 1.00 Y
45879400 1.00 Y
49271800 1.00 Y
24274600 1.00 Y
31094800 1.00 Y
27737000 1.00 Y
18919580 1.00 Y
18287420 1.00 Y
23399000 1.00 Y
18381380 1.00 Y
16485420 1.00 Y
50645000 1.00 Y
39571800 1.00 Y
31133200 1.00 Y
52179400 1.00 Y
44489600 1.00 Y
44720600 1.00 Y
46858200 1.00 Y
48076200 1.00 Y
19295560 1.00 Y
21313600 1.00 Y
46687000 1.00 Y
39673800 1.00 Y
48654800 1.00 Y
14420380 1.00 Y
13157600 1.00 Y
36534000 1.00 Y
38188200 1.00 Y
32661600 1.00 Y
41321000 1.00 Y
26617200 1.00 Y
22493800 1.00 Y
31782200 1.00 Y
16088940 1.00 Y
15325920 1.00 Y
6846840 1.00 Y
9119460 1.00 Y
19645600 1.00 Y
21834400 1.00 Y
18381380 1.00 Y
* No Peak 0.00 N
R.
mm
12
10
10
12
15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
37
38
38
38
39
39
17
17
RES
i analyzed
) Ex Cal
T. RRF
ss
27 Y
12 Y
16 Y
34 Y
27 Y
30 Y
1 Y
7 Y
54 Y
41 Y
47 Y
45 Y
49 Y
58 Y
0 Y
36 Y
39 Y
17 Y
20 Y
8 Y
12 Y
14 Y
20 Y
20 Y
28 Y
33 Y
33 Y
37 Y
31 Y
26 Y
36 Y
48 Y
54 Y
59 Y
6 Y
3 Y
13 Y
10 Y
19 Y
41 Y
46 N
: PAHAIR.TRG
: 03-NOV-98
: PAHAIR102998V4.R
ng/ Rec/
TRAIN MDL
1.00 50.00
2.24 27.36 55
1.23 87.66 0.000
0.56 94.39 0.000
1.21 34.24 68
0.94 94.49 0.000
0.74 33.96 68
1.25 77.57 0.000
1.00 50.00 ^
1.42 27.64 55
1.16 77.28 0.000
2.81 38.55 77
0.89 87.35 0.000
0.80 76.80 0.000
1.00 50.00
1.41 30.22 60
1.11 90.41 0.000
1.52 29.58 59
1.21 85.14 0.000
0.90 20.54 41
1.20 91.70 0.000
1.28 34.97 70
1.08 78.40 0.000
1.00 50.00
0.45 32.65 65
1.17 78.17 0.000
0.95 39.60 79
1.16 89.79 0.000
0.68 49.60 99
1.64 77.10 0.000
1.07 76.02 0.000
0.63 36.68 73
1.71 82.45 0.000
0.44 37.19 74
0.62 153.40 0.000
0.25 28.62 57
1.40 94.90 0.000
0.58 34.83 70
1.02 109.39 0.000
1.42 13.29 27
1.00 0.00 0.000
-------
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'•-.*•.. ;>.-;-K.,::y'sir;i-'"->'-• ;./; --'.'-:-*>;.- •"..,-j.•V'1-',?1
Initial Calibration
473
-------
ICAL
QUANTERRA INCORPORATED
West Sacramento
Initial Calibration Checklist
High Resolution
„ L ^
. ggf Method ID
Column m 3>B-g
STD ID's.
InstrumentH) \7£-ij
y Multiplier Setting.
Analyzed By_
Prepared By_
JS.vi A
Reviewed By.
OUU.'
Date Analyzed 1 o - Afl - q ft
Date Prepared \o-3o
Date Reviewed
hat-*- .*<• x*<^^A»AL«si^i)^ii^^»^l^
Curve summary present?
CS1-CS5, CPSM, solvent blank present?
Copy of logfile present?
CPSM Blow-up/Static resolution check present?
Target file RTs correct?
-ftRF s within method-specified limits?
Signal-to-noise criteria met?
Isotopic ratios within limits?
High point free of saturation?
Chromatographic.wjndows correct?
CPSM valley < 25%?-,
Manual reintearations checked and hardcopies
included?
S
^/V/A
i^
HA/ <^
L^
^
i^
Mk
^
i^
A//\
I/
y
sM&
^
^1^
^
\s
^
fsJAc
\S
S
MA
S
COMMENTS: "77"
mmr it
/. V? / / / 'x>f
f f, ^ O
J
Method S290: %RSD < 20% for natives, < 30% for labelled analytes; S/N > 10
Method 1613A: %CV< 35% (See Table 7, Method 1613A); S/N > 10
Method 23: %RSD < values specified in Table 5, Method 23; S/N > 2.5
PAH: %RSD < 30% for natives and labelled compounds; S/N > 10
PCB: %RSD < 25% for natives. < 30% for labelled compounds; S/N > 2.5
NCASI 551: %RSD < 20% for natives and labelled compounds; > 5
DBD/DBF: %RSD < 30% for natives and labelled compounds; S/N > 10
QA-384NE2/97
474
-------
02-MOV-1998 07:31:36 AM
Mass Spec : VG-4
GC Column : DB-5
265-04A,B.D,E,956-64
Mult.: 350
dB-Naphthalene
Naphthalene
Z-Methylnaphthalene
dB-Acenaphthylene
Acenaphthylene
dIO-Acenaphthene
Acenaphthene
dIO-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
dIO-Pyrene
Pyrene
DI oxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amoun':
RF
RRF
Amoun1:
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF ;
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
2
1
0
1
0
0
!•',
1
1
1
2
0
0
1
1
1
1
.24
.23
.56
.21
.94
'
'J'S,
.25
.42
.16
.81
.89
.80
.41
.11
.52
.21
S.D
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
XRSD
289
094
084
093
045
099
177
066
191
173
063
031
141
174
154
0.269
12.
7.
14.
7.
4.
13.
14.
4.
16.
6.
7.
3.
10.
15.
10.
22.
900
707
909
696
773
310
178
625
420
145
028
901
009
653
160
353
1
100.00
185.11
1.85
10.00
13.76
1.38
10.00
6.91
0.69
100.00
131.95
1.32
10.00
9.55
0.95
100.00
83.11
0.83
10.00
10.98
1.10
100.00
153.24
1.53
10.00
8.53
0.85
100.00
308.98
3.09
10.00
9.70
0.97
10.00
8.13
0.81
100.00
118.94
1.19
10.00
14.14
1.41
100.00
129.03
1.29
10.00
16.74
1.67
2
100.00
205.87
2.06
50.00
61.93
1.24
50.00
29.85
0.60
100.00
128.38
1.28
50.00
48.30
0.97
100.00
77.72
0.78
50.00
62.63
1.25
100.00
135.78
1.36
50.00
58.18
1.16
100.00
263.63
2.64
50.00
46.13
0.92
50.00
42.20
0.84
100.00
136.07
1.36
50.00
55.12
1.10
100.00
143.24
1.43
50.00
59.11
1.18
3
100.00
228.31
2.28
100.00
113.47
1.13
100.00
51.39
0.51
100.00
114.60
1,15
100.00
90.68
0.91
100.00
76.15
0.76
100.00
151.76
1.52
100.00
140.61
1.41
100.00
117.21
1.17
100.00
276.27
2.76
100.00
81.87
0.82
100.00
77.06
0.77
100.00
145.72
1.46
100.00
99.77
1.00
100.00
158.81
1.59
100.00
104.58
1.05
4
100.00
244.46
2.44
200.00
231.43
1.16
200.00
97.93
0.49
100.00
122.45
1.22
200.00
178.19
0.89
100.00
77.96
0.78
200.00
215.88
1.08
100.00
141.09
1.41
200.00
249.15
1.25
100.00
272.04
2.72
200.00
168.14
0.84
200.00
153.96
0.77
100.00
150.34
1.50
200.00
200.49
1.00
100.00
161.45
1.61
200.00
204.18
1.02
5 6
100.00
256.61
2.57
500.00
609.70
1.22
500.00
255.67
0.51
100.00
109.50
1.10
500.00
500.84
1.00
100.00
57.36
0.57
500.00
641.50
1.28
100.00
139.72
1.40
500.00
684.13
1.37
100.00
282.87
2.83
500.00
460.23
0.92
500.00
402.42
0.80
100.00
154.31
1.54
500.00
521.18
1.04
100.00
166.55
1.67
500.00
551.22
1.10
10
-------
02-NOV-1998 07:31:39 AM
Mass Spec : VG-4
GC Co limn : DB-5
265-04A,B.D,E,956-64
Mult.: 350
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
dU-Dibenz(ah)anthracene
Otoxin Furan CALIBRATION TABLE
Filename : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
r-
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.90
1.20
1.28
1.08
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
S.D.
0.238
0.124
0.139
0.051
0.029
0.125
0.021
0.111
0.017
0.140
0.112
0.037
0.142
0.008
0.052
0.023
%RSD
26.446
10.269
10.855
4.716
6.414
10.717
2.203
9.525
2.504
8.557
10.437
5.829
8.297
1.722
8.352
9.286
1
100.00
68.20
0.68
10.00
11.85
1.18
100.00
109.94
1.10
10.00
10.44
1.04
100.00
41.05
0.41
10.00
12.56
1.26
100.00
91.66
0.92
10.00
12.71
1.27
100.00
65.24
0.65
10.00
18.05
1.80
10.00
11.71
1.17
100.00
64.89
0.65
10.00
16.93
1.69
100.00
44.86
0.45
10.00
5.85
0.59
100.00
20.73
0.21
2
100.00
70.96
0.71
50.00
64.84
1.30
100.00
119.85
1.20
50.00
56.47
1.13
100.00
45.84
0.46
50.00
61.73
1.23
100.00
94.95
0.95
50.00
63.16
1.26
100.00
66.86
0.67
50.00
89.03
1.78
50.00
60.46
1.21
100.00
58.55
0.59
50.00
98.08
1.96
100.00
44.54
0.45
50.00
35.13
0.70
100.00
24.39
0.24
3
100.00
127.65
1.28
100.00
102.61
1.03
100.00
127.65
1.28
100.00
102.61
1.03
100.00
49.22
0.49
100.00
95.82
0.96
100.00
96.52
0.97
100.00
119.14
1.19
100.00
69.56
0.70
100.00
157.16
1.57
100.00
102.44
1.02
100.00
68.21
0.68
100.00
162.24
1.62
100.00
44.08
0.44
100.00
60.26
0.60
100.00
25.35
0.25
4
100.00
89.95
0.90
200.00
234.26
1.17
100.00
136.79
1.37
200.00
215.75
1.08
100.00
45.10
0.45
200.00
228.66
1.14
100.00
94.09
0.94
200.00
210.18
1.05
100.00
67.87
0.68
200.00
302.58
1.51
200.00
200.46
1.00
100.00
62.00
0.62
200.00
324.02
1.62
100.00
43.39
0.43
200.00
127.89
0.64
100.00
26.10
0.26
5
100.00
93.26
0.93
500.00
671.78
1.34
100.00
145.35
1.45
500.00
571.04
1.14
100.00
45.72
0.46
500.00
622.27
1.24
100.00
96.82
0.97
500.00
522.11
1.04
100.00
68.82
0.69
500.00
767.23
1.53
500.00
476.32
0.95
100.00
61.45
0.61
500.00
435.41
1.67
100.00
45.40
0.45
500.00
287.53
0.58
100.00
26.33
0.26
10
-------
02-HOV-1998 07:31:43 AH
Mass Spec : VG-4
GC Column : DB-5
265-04A,B,D,E,956-64
Mult.: 350
0 i benz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Dioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Mean
1.40
0.58
1.02
0
S.D.
0.077
0.022
0.091
0
XRSD
5.452
3.838
8.984
0
1
10.00
12.92
1.29
100.00
59.24
0.59
10.00
8.58
0.86
b"
2
50.00
69.25
1.38
100.00
54.17
0.54
50.00
51.44
1.03
0
3
100.00
143.15
1.43
100.00
59.73
0.60
100.00
109.18
1.09
, 0
( ' J .V
4
200.00
281 .33
1.41
100.00
58.78
0.59
200.00
211.25
1.06
j . 0
it*'-
5
500.00
751.34
1.50
100.00
57.94
0.58
500.00
522.58
1.05
0
,0:
-------
J2-NOV-1998 07:15:45 AM Dioxin Furan leal RESULTS
tass Spec : VG-4
jC Column : DB-5
)ata file : 290C98V4
teight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
dl2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-lndeno (123 -cd) pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
!3C-Fluorene
Results : 290C98V4011.RES
Date analyzed
ST1029 :CS-1 :265-04A : : Ex
Total Isotope R. T. RRF
Response Ratio tnm:ss
PAHAIRCAL1.TRG
29-OCT-98
148835400
275504000
37899400
19033020
196391000
18748260
123692800
13580000
101404200
155386800
13251380
313320000
30392400
25466000
252508000
300334000
42464400
325812000
54540800
172200000
20400000
277600000
28968600
365008000
149834000
18813720
334554000
42523000
238134000
42973400
27895800
236860000
40100200
163754400
9580000
75669400
9775940
216222000
18553180
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
28
13
17
35
28
31
2
9
56
42
48
47
51
59
1
37
41
19
22
9
14
16
22
23
31
35
36
40
34
29
40
51
57
4
11
8
18
16
24
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
pg
Rec/
MDL
•1
1
1
0
1
0
0
1
0
1
0
3
0
0
•1
1
1
1
1
0
1
1
1
0
0
1
0
1
0
1
1
0
1
0
0
0
.1
0
0
.00
.85
.38
.69
.32
.95
.83
.10
.00
.53
.85
.09
.97
.81
.00
.19
.41
.29
.67
.68
.18
.10
.04
.00
.41
.26
.92
.27
.65
.80
.17
.65
.69
.45
.59
.21
.29
.59
.86
100
100
10
10
100
10
100
10
100
100
10
100
10
10
100
100
10
100
10
100
10
100
10
100
100
10
100
10
100
10
10
100
10
100
10
100
.10
100
10
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
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0.
0.
0.
0.
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0.
0.
0.
0.
0.
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0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0.000
478
-------
02-NOV-1998 07:21:36 AM Dioxin Furan leal RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 290C98V4
: 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 29OC98V4021.RES
Date analyzed
ST1029A :CS-2 :265-04B : Ex
Total Isotope
Response Ratio
144594000 1.00 Y
297670000 1.00 Y
184351200 1.00 Y
88865000 1.00 Y
185629600 l.OQ ^'
89660600 1.00 Y
112381800 1.00 Y
70386000 1.00 Y
124663000 1.00 Y
169272600 1.00 Y
98489600 1.00 Y
328644000 1.00 Y
151615400 1.00 Y
138689600 1.00 Y
262974000 1.00 Y
357818000 1.00 Y
197230800 1.00 Y
376684000 1.00 Y
222652000 1.00 Y
186600000 1.00 Y
121000000 1.00 Y
315180000 1.00 Y
177982400 1.00 Y " 29
405140000 1.00 Y
185717200 1.00 Y
114642400,1.00 Y
384662000 1.00 Y
242954000 1.00 Y
2708600OO l.QD Y
241154000 1.00 Y
163755600 1.OD Y
237192000 1.00 Y
232648000 1.00' Y:
180449500 1.013 Y
6340OOOO 1.00 Y
98818400 1.00 Y
68429800 1.00":Y"
219460000 1.00 Y
112888400 1.00 Y
PAHAIRCAL2.TRG
29-OCT-98
R.
mm
12
10
10
12
15
16
16
20
17
17
20
20
21
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
33
38
38
39
39
T.
:SS
i 22
: 13
: 18
: 35
f *X9
\ 31
: 3
: 9
: 56
: 42
: 48
: 46
: 51
: 0
: 1
: 37
: 41
: 19
: 22
: 9
: 14
: 16
: 21
: 23
: 30
: ,35
: 35
: 39
: 34
i ,28.
: 39-
: -51
•~ 56
: 3
f .11
v 8
: 17
: 15
: 23
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
RRF
0
2
1
0
1
0
0
1
0
1
1
2
0
0
-1
1
1
1
1
0
1
1
1
0
0
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0
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~ 1
, p;?--^
'[ ^HO
*"•'•,.::. i'
0
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0
1
pg Rec/
MDL
.00
.06
.24
.60
.28
.97
.78
.25
.00
.36
.16
.64
.92
.84
.00
.36
.10
.43
.18
.71
.30
.20
.13
.00
.46
.23
.95
i26
.57 _
.78
-21-
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.45
.70
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!38
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.03
100
100
50
50
100
50
100
50
100
100
50
100
50
50
100
100
50
100
50
100
50
100
50
100
100
50
100
50
100
50
50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.00.0
.000
.000
.000
.000
.000
.000
.000
.000
IOO..OO .
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•100
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,•'.,---'•
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vfjtflij
.00^
-------
J2-NOV-1998 07:24:53 AM Dioxin Furan leal RESULTS
4ass Spec : VG-4
5C Column -. DB-5
file : 29OC98V4
Name
jfeight
Results : 290C98V4031.RES
Date analyzed
ST1029B :CS-3 :956-64 : : Ex
Total Isotope R. T. RRF
Response Ratio mmrss
PAHAIRCAL3.TRG
29-OCT-98
dlO - 2-MethyInaphthalene
d8-Naphthalene
j Naphthalene
2-MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
' Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
312-Benzo (b) f luoranthene
Benzo(b)fluoranthene
3l2-Benzo(k) f luoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benz o(a)pyrene
d!2-Perylene
Perylene
|12-Indeno(123-cd)pyrene
»'" Indeno(123-cd)pyrene
Jl4-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
l3C-Fluorene
114074600 1.00 Y 12:
260448000 1.00 Y 10:
295542000 1.00 Y 10:
133833200 1.00 Y 12:
130728800 1.00 Y 15:
118542800 1.00 Y 15:
86872800 1.00 Y 16:
131835000 1.00 Y 16:
105259600 1.00 Y 20:
148006200 1.00 Y 17
173478200 1.00 Y 17
290800000 1.00 Y 20
238078000 1.00 Y 20
224086000 1.00 Y 21
209112000 1.00 Y 26
304722000 1.00 Y 24
304036000 1.00 Y 24
332100000 1.00 Y
347310000 1.00 Y
165200000
191600000
266934000
273900000
378748000
186411000
178619200
365566000
435526000
263446000
414020000
269874000
258348000
419148000
166952200
100600000
96020800
137450400
226218000
246996000
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
25:
25:
29:
29:
29:
29:
1.00 Y 33
1.00 Y 32
1.00 Y 32
32
32
1.00 Y 33
1.00 Y 33
1.00 Y 33
33:
33:
38
38
38
38
39
39
29 Y
14 Y
18 Y
35 Y
29 Y
32 Y
2 Y
9 Y
56 Y
42 Y
48 Y
47 Y
51 Y
0 Y
2 Y
37 Y
41 Y
19 Y
22 Y
10 Y
14 Y
16 Y
21 Y
23 Y
30 Y
34 Y
35 Y
40 Y
34 Y
28 Y
39 Y
50 Y
56 Y
3 Y
10 Y
7 Y
17 Y-
15 Y
24 Y
pg
Rec/
MDL
0
2
1
0
1
0
0
1
0
1
1
2
0
0
0
1
1
1
1
0
1
1
1
1
0
0
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.28
.13
.51
.15
.91
.76
.52
.00
.41
.17
.76
.82
.77
.00
.46
.00
.59
.05
.79
.16
.28
.03
.00
.49
.96
.97
.19
.70
.57
.02
.68
.62
.44
.60
.25
.43
.60
.09
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
: 100
100
100
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
4SO
-------
02-NOV-1998 07:27:43 AM
Dioxin Furan leal RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 290C98V4
: 1
Name
dlO-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dl 0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benz o(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 290C98V4041.RES
Date analyzed
ST1029C :CS-4 :265-04D : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
110362600 1.00 Y
269792000 1.00 Y
624376000 1.00 Y
264208000 1.00 Y
135138000 1.00 Y
240808000 1.00 Y
86040200 1.00 Y
185743400 1.00 Y
115226400 1.00 Y
162568800 1.00 Y
405042000 1.00 Y
313460000 1.00 Y
527064000 1.00 Y
482604000 1.00 Y
215450000 1.00 Y
323902000 1.00 Y
649384000 1.00 Y
347844000 1.00 Y
710224000 1.00 Y
193800000 1.00 Y
454000000 1.00 Y
294720000 1.00 Y
635846000 1.00 Y
486608000 1.00 Y
219440000 1.00 Y
501770000 1.00 Y
457832000 1.00 Y
962282000 l.BQ Y
330262000 1.00 Y
999302000 1.00 Y
662030000 1.00 Y
30±T14OlDO 1.-Q0 Y 33
977600000 1.00 Y
211120000 1.00 Y
270OBQQOO UQfc Y
PAHAIRCAL4.TRG
29-OCT-98
pg
Rec/
MDL
.02
10
10
12
is"
15
16
16
20
17
17
20
20
21
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
3B
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:
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.
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.
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:
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.
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:
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:
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.
1
29-
13
17
36
iV
32
3
8
56
43
48
46
51
0
1
37
41
18
22
9
14
16
21
23
30
35
35
39
33
28
38
,50
56
3
9.
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y •«
0
2
1
0
1
0
0
1
0
1
1
2
0
0
-1
1
1
1
1
0
1
1
1
0
0
1
0
1
0
*i
"•>i
,.;--v,,.-o
•
-------
2-NOV-1998 07:30:42 AM Dioxin Furan leal RESULTS
ass Spec
C Column
ata file
eight
: VG-4
: DB-5
: 290C98V4
: 1
Name
Results : 29OC98V4051.RES
Date analyzed
ST1029D :CS-5 :265-04E : Ex
Total Isotope R. T. RRF
Response Ratio Ttim:ss
PAHAIRCAL5.TRG
29-QCT-98
dlO-2-Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 - Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Ac enaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo (a) anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo (e) pyrene
112-Benzo (b) f luoranthene
Benzo (b) f luoranthene
112-Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2-Benzo (a) pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
H2-lndeno(123-cd)pyrene
Indeno (123 -cd) pyrene
U.4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2-Benzo (ghi) perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
100692000 1.00 Y 12: 29 Y
258386000 1.00 Y 10: 13 Y
1575386000 1.00 Y 10: 17 Y
660610000 1.00 Y 12: 35 Y
110257800 1.00 Y 15: 29 Y
552216000 1.00 Y 15: 32 Y
57758000 1.00 Y 16: 3 Y
370516000 1.00 Y 16: 8 Y
108354400 1.00 Y 20: 56 Y
151395800 1.00 Y 17: 43 Y
1035738000 1.00 Y 17: 48 Y
306504000
1410624000
1233428000
209728000
323622000
1686640000
349310000
1925462000
195600000
1314000000
304846000
1740792000
502582000
229792000
1429934000
486600000
2540580000
345868000
2653600000
1647428000
308836000
2580040000
228154000
656000000
132353000
994422000
291198000
1521730000
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
1.00 Y
20: 46 Y
20: 51 Y
20: 59 Y
26: 1 Y
24: 37 Y
24: 40 Y
25: 18 Y
25: 22 Y
29: 9 Y
29: 14 Y
29: 15 Y
29: 20 Y
33: 23 Y
32: 30 Y
32: 35 Y
32:
32:
33:
33:
38:
38:
38:
38:
35 Y
39 Y
33: 33 Y
33: 28 Y
33: 38 Y
50 Y
56 Y
3 Y
9 Y
6 Y
16 Y
39: 14 Y
39: 22 Y
pg
Rec/
MDL
0
2
1
0
1
1
0
1
0
1
1
2
0
0
• 1
1
1
1
1
0
1
1
1
0
0
1
0
1
0
1
0
0
1
0
0
0
-1
0
1
.00
.57
.22
.51
.10
.00
.57
.28
.00
.40
.37
.83
.92
.80
.00
.54
.04
.67
.10
.93
.34
.45
.14
.00
.46
.24
.97
.04
.69
.53
.95
.61
.67
.45
.58
.26
.50
.58
.05
100
100
500
500
100
500
100
500
100
100
500
100
500
500
100
100
500
100
500
100
500
100
500
100
100
500
100
500
100
500
500
100
500
100
500
100
500
100
500
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.:00
.00
.00
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o"
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
482
-------
FILE
SAMP
No.
(1)
LAB.
SAMP NO
CUSTOMER
ID
CLEAN CLEAN
UP 1 UP 2
(SDS) (D2)
TYPE CONCn.
(1)
290C98V4 1
290C98V4 2
290C98V4 3
290C98V4 4
290C98V4 5
290C98V4 6
290C98V4 7
290C98V4 8
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290C98V4 42
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290C98V4 46
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290C98V4 49
290C98V4 50
ST1029
ST1029A
ST1029B
ST1029C
ST1029D
SB1029A
ST1029E
SB1029B
302050-1MB
302050-1LC
302050-1BA
302050-1LA
302050-2
302050-4
302050-6
302050-8
302050-1
302050-3
302050-5
302050-7
301802-1
301802-2
301802-3
SB1029C
ST1029F
SB1029D
301802-1MB
301802-1LC
301802-4
301802-5
301802-6
301802-7
301802-8
301802-9
301802-10
301802-11
301802-12
301802-13
301802-14
SB1029E
CS-1
CS-2
CS-3
CS-4
CS-5
Solvent Blank
CS-3
Solvent Blank
METHOD BLANK
LCS
METHOD BLANK
LCS
CLXTP
CLXTR
CLXTW
CLXVO
CLXTM
CLXTQ
CLXTV
CLXTX
10X DIL.
10X DIL.
10X DIL.
Solvent Blank
CS-3
Solvent Blank
METHOD BLANK
LCS
10X DIL.
10X DIL.
-IIQX DIL.
10X DTL.
10X DIL.
10X DIL,
•-. 10X DIL.
: 10X DIL.
:: iox DIL.
10X DIL,
::. lOX DIL,
Solvent Blank
265-04A
265-04B
956-64
265--4E
C-8
956-64
C-8
AIR PAH
AIR
C-8
956-64
C-8
AIR
PAH
PAH
C-8
1
1
1
1
1
1
1
1
VSE-25 0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
VSE-26 0.50
0.50
0.50
1
1
1
VSE-26 0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
.0,50
0.50
0,50
'X'-,
SMA, AM 10-29-98
r.
-------
Peak Locate Examination:29-OCT-1998:15:23 File:290C98V4
Experiment:PAHAIR Function:! Reference:PFK
118.98012 118.99202 119.00392
PPM
200
Volts
6.8186
130.97892 130.99202 131.00512
Volts
0.1396
142.97772 142.99202 143.00632
O)
VoltS
0.3615
Volts
0.0773
149.97542 149.99042 150.00542
154.97652 154.99202 155.00752
168.97192 168.98882 169.00571
-------
Peak Locate Examination:29-OCT-1998:15:23 File:29OC98V4
Experiment:PAHAIR Function:2 Reference:PFK • ;
154.97652 154.99202 155.00752
Volts
1.8780
168.97192 168.98882 169.00571
Volts
9.3212
180.97072 180.98882 181.00691
$
Volts
0.1808
192.96952 192.98882 193.00811
204.96832 204.98882 205.00931
-------
Peak Locate Examination:29-OCT-1998:15:24 File:290C98V4
Experiment:PAHAIR Function:3 Reference:PFK
PPM~
200
00
230.96253 230.98563 231.00872
-------
Peak Locate Examination:29-OCT-1998:15:26 File:29OC9fcV4
Experiment:PAHAIR Function:4 Reference:PFK
go
242.96133 242.98563 243.00992
PPM
200
Volts
0.3447
254.96013 254.98563 255.01112
PPM
200
Volts
0.3653
268.95555 268.98245 269.00935
Volts
2.1290
Volts
0.9836
280.95435 280.98245 281.01055
292.95315 292.98245 293.01175
-------
e:29OC98V4 #1-510 Acq:29-OCT-1998 15:27:18 GC E1+ Voltage SIR 70SE
Samplell Text:ST1029 :CS-1 :265-04A :: Exp:PAHAlR
128.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
GO
'JO
009
80 J
60.
40-
20_
0-
9:C
A1.89E7
1
1
) ^-^ A1.40E5 A6.07E5
* 1 1 ' 1 1 1 1 1 1 1 1 r 1 1 1 1 1 1 1 —i 1 1 1 1 1 1 1 1 1 1 1 — I 1 ' 1 1
0 10:00 11:00 12:00 13:00 14:00 15:
r4.0E6
L3.2E6
L2.4E6
1.6E6
8.0E5
• o.OEO
)0 Time
136.1128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
80 J
60 J
40_
20_
0
9:(
142.0
100 S
80 1
60-
40_
20_
0
9:f
152.1
1009
80 1
60-
40-
20 J
0
9:(
> A1.38E8
|
) v^
2.9E7
0 10:6o ll:6o 12:6o 13:6o 14:bo 15:
782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A9.52E6
J
\A1.43E6
v./v
* h 1 1 1 1 1 1 1 1 1 1 1 n 1 • 1 1 1 1 1 1 1 1 r 1 1 1 r~~ - — r 1 1 r—, 1 1 1
0 10:00 11:00 12:00 13:00 14:00 15:
410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.44E7
n
\\
|V
0 10:00 ll:6o 12:1)0
13:60 14:60 ' 'l5:l
_2.4E7
_1.8E7
_1.2E7
-5.9E6
O.OEO
)0 Time
.-2.0E6
H.6E6
1.2E6
L8.2E5
I.4.1E5
O.OEO
10 Time
1.7E7
Ll.4E7
Ll.OE?
16.9E6
:3.5E6
O.OEO
M> Time
-------
File:290C98V4 #1-510 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample*! Text:ST1029 :CS-1 :265-04A : : Exp:PAHAIR
1J^..U<
100 S
80:
60:
40-
20:
0
14:
•* ^A ••
t*o &ni\j\i.,ji nvt»\3,j,.
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A4.46E5
—i — i — i — r~i — i — i — i — i — i — i — i — i — r
W 14:1 2 14:24
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A2.03E5
1 l"l '1 VI I1 I i 1 i •
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% M -flA«W •* A A A A A A A
'/VffylJ • . j
A9.37E6 ' r2.6E6
l\ ' - " '-
A
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A9.07E4 A9.93E4/ V A8.96E5 J VA2.98E5
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15:00 15:12 15:24 15:36 15:48 16:6o 16:12 16:24 16:36 16:48 17:
l\frr vn fm . • ' 1 • :
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10 Time
DOS
80 J
60:
40.
20:
0
14:
. , A9.82E7
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3 1
*:?S 1 \
\ A2.09E7 • •, -.'
1 /\
10 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36 15:48 16:bo 16:12 16:24 16:36 16:48 17:i
JUE7
L2.1E7
:1.6E7
-1.0E7
L5.2E6
O.OEO
10 Time
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
14:
164.1410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100!
80 J
60
40_
20 J
0.
15:36 15:48 16:1)0
A6.18E7
-5.9E5
O.OEO
)0 Time
1.8E7
L1.4E7
-1.1E7
L7.1E6
L3.6E6
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14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:00 Time
O.OEO
-------
F!le:29OC98V4 #1-510 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample*! Text:ST1029 :CS-1:265-04A :: Exp:PAHAIR
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95 j
90 j
85 J
80 J
75.:
70 J
651
60
55 J
50 J
451
40_
35-
30_
25-
20 J
15 J
10 -
sl
0
A6.7«»E6
A3.83E6
A7.02E6
A6.28E6
A2.24E6
2.9E6
2.8E6
2.6E6
2.5E6
2.3E6
2.2E6
L2.0E6
1.9E6
1.8E6
-1.6E6
-1.5E6
-1.3E6
1.2E6
L1.0E6
8.8E5
L7.3E5
is-.ki
16:66
16
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16
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16
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4.4E5
2.9E5
t-1.5E5
O.OEO
Time
a
-------
Flle:290C98V4 #1-510 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1029 .-CS-1 :265-04A : : Exp:PAHAlR
130.9920 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
005
•
95:
90-
85:
80:
75:
70:
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-------
FUe:290C98V4 #1-641 Acq:29-OCT-1998 15:27:18 GC Et+ Voltage SIR 70SE
Sample/Pi Text:ST1029 ;CS-1 :265-04A :: Exp:PAHAIR
166.0798 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0>0.00%,F,T)
1009
90 J
80 J
70 J
60
50 J
40J
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20 J
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01
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17:
A6.63E6
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10 17:12 17:24 17:36 17:48 18:6o 18:12 18:24 18:36 18:48 19:6o 19:12 19:24 19:36 19:48 20:
172.0984 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.5JE4
90J
80 J
70 J
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17:00 17:12 17:24 17:36 17:48 18:66 18
176.1410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
:ii 18:24 18:36 18:48 19:66 19:i2 19:24 19:36 19:48
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10
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20:
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18:.
19
19:48 2O.-00 Time
-------
File:29OC98V4 #1-641 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1029 :CS-1 :265-04A :: Exp:PAHAK
CO
1009
90 J
80 J
70 J
60-
50-
40_
30-
20_
10_
0
19:
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188.1410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
UU 3
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80:
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-6.1E6
O.OEO
0 Time
-------
Flle:29OC98V4 #1-641 Acq:29-OCT-1998 15:27:18 GC E1+ Voltage SIR 70SE
Sample^l Text:ST1029 :CS-1 :265-04A : : ExprPAHAIR
204.9888 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
95:
90:
85:
80:
75:
70:
65-
60:
55:
50
45:
40:
35:
30:
25:
20:
15:
10:
5:
0
17:
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2.1E7
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1.9E7
1.8E7
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:1.0E7
:9.3E6
:8.3E6
:7.3E6
6.2E6
:5.2E6
:4.2E6
:3.1E6
-2.1E6
1.0E6
-O.OBO
-------
A2.12E7
FHc:29OC98V4 #1-938 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR
Sample*! Text:ST1029 :CS-1 :265-04A : : ExprPAHAIR
202.0782 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
40 J
30 J
20 J
10 J
0
70SE
A2. 3E7
_7,9E6
7.1E6
-6.3E6
-5.5E6
4.7E6
.3.9E6
-3.1E6
-2.4E6
-1.6E6
O.OEO
Time
23:00 \ ^24:00
212.1410 F:3 SMO(1,3) Pg0(5,3,3,0^f %,10000.0,0.00%,F,T)
25:00
26:60
100 9.
90-
80
70-
60 J
50 J
40
30 J
20-
10
0
-4
A1.63E8
A1.50E8
1 1 1 1 1 r 1 1 r-
23:00 24:00
244.1974 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
401
30 J
20 J
10 J
V— •- -' T "-" i i i ' i r • "•"•••• »•' • |-.-— i i ,i
27:00
5.5E7
[4.9E7
L4.3E7
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1.8E7
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L6.1E6
O.OEO
10 Time
25:
27:1
4.7E7
L4.2E7
L3.8E7
L3.3E7
L2.8E7
L2.4E7
L1.9E7
L1.4E7
L9.4E6
L4.7E6
LO.OEO
)0 Time
23:00
24:t
25:
27:<
-------
File:29OC98V4 #1-938 Acq:29-OCT-1998 15:27:18 GC E1+ Voltage SIR 70SE
Sample* 1 Text:ST1029 :CS-1 .-265-04A : : Exp:PAHAlR
228.0939 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
240.1692 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80
70-
60.
50.
40.
30:
20 J
10 J
, I
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1
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30:6o 31 ji
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2.8E7
L2.5E7
L2.2E7
Ll.9E7
1.6E7
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L9.4E6
-6.3E6
-3.1E6
O.OEO
-------
F1le:29OC98V4 #1-938 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sampled! Text:ST1029 :CS-1 :265-04A :: Exp:PAHAIR
230.9856 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1
1009
95:
90:
85.
80
75:
70:
65:
60:
55:
50:
45:
40-
35:
30:
25:
20:
15:
10:
5:
0
23:
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-------
Flle:290C98V4 #1-878 Acq:29-OCT-1998 15:27:18 GC E1+ Voltage SIR 70SE
Sampled! Text:ST1029 :CS-1 :265-04A : : Exp:PAHAIR
252.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.U5E7
90 J
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264.1692 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.83E8
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80 J
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Flle:29OC98V4 #1-878 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1029 :CS-1 :265-04A :: Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A9.28E6
37:00 38:1)0 39:00
288.1692 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
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278.1096 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:29OC98V4 #1-878 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029 :CS-1 :265-04A :: Exp:PAHAlR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 15:27:18 GC EI+ Voltage SIR 70SE
Sample*! Text:ST1029 :CS-1 :265-04A : : Exp:PAHAIR
268.9824 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:290C98V4 #1-510 Acq:29-OCT-1998 1(5:16:17 GC EI+ Voltage SIR 70SE
Sample^ Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
128.0626 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-510 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B: Exp:PAHAIR
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-------
File:290C98V4 #1-510 Acq:29-OCT-199816:16:17 GC EI+ Voltage SIR 70SE
Sampled Texl:ST1029A :CS-2 :265-04B : Exp:PAHAIR
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-------
File:29OC98V4 #1-640 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
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-------
F1le:29OC98V4 #1-640 Acq:29-OCT-1998 16:16:17 GC E1+ Voltage SIR 70SE
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-------
File:290C98V4 #1-640 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B : ExprPAHAIR
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-------
Fllei290C98V4 #1-938 Acq:29-OCT-199816:16:17 OC B1+ Voltage Sift 70SE
Sample^ Text:ST1029A :CS-2 .-265-04B : Exp:PAHAm
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-------
File:29OC98V4 #1-938 Acq:29-OCT-1998 16:16:17 GC EI-f Voltage SIR 70SE
Sample#2 Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
228.0939 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Hle:290C98V4 #1-938 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
230.9856 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%)10000.0,0.00%,F,T)
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File:29OC98V4 #1-878 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sample#2 Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
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FHe:29OC98V4 #1-878 Acq:29-OCT-1998 16:16:17 GC E1+ Voltage SIR 70SE
Sample*! Text:ST 1029A :CS-2 :265-04B : ExptPAHAIR
276.0939 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:29OC98V4 #1-878 Acq:29-OCT-1998 16:16:17 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
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Flle:29OC98V4 #1-878 Acq:29-OCT-1998 16:16:17 GC El-f Voltage SIR 70SE
Sampled Text:ST1029A :CS-2 :265-04B : Exp:PAHAIR
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FUe:29OC98V4 #1-510 Acq:29-OCT-1998 17:05:20 GC EI+ Voltage SIR 70SE
Sample#3 Text:ST1029B :CS-3 :956-64 :: ExprPAHAIR
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Flle:290C98V4 #1-510 Acq:29-OCT-1998 17:05:20 GC EI+ Voltage SIR 70SE
Sample/ft Text:ST1029B :CS-3 :956-64 :: Exp:PAHAIR
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File:29OC98V4 #1-510 Acq:29-OCT-1998 17:05:20 GC EI+ Voltage SIR 70SE
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File:290C98V4 #1-641 Acq:29-OCT-1998 17:05:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 :: Exp:PAHAlR
166.0798 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Sampled Text:ST1029B :CS-3 :956-64 : : Exp:PAHAIR
202.0782 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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F1le:290C98V4 #1-938 Acq:29-OCT-1998 17:05:20 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 :: Exp:PAHAlR
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-------
File:29OC98V4 #1-938 Acq:29-OCT-199817:05:20 GC EH- Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 : : Exp:PAHAIR
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-------
Flle:290C98V4 #1-878 Acq:29-OCT-1998 17:05:20 CC EI+ Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 i: Exp:PAHAIR
252.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,P,T)
A2.07E8
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31:00 32:6033:6o
264.1692 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.89E8
90 J
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-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 17:05:20 GC EH- Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 :: Exp:PAHAIR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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288.1692 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.13E8
42:00 Time
37:00 38:00 39:00
278.1096 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:00 38:00 39:6o
292.1974 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 2> A4.80E7
37:00
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-------
A5.03E7
F!le:290C98V4 #1-878 Acq:29-OCT-1998 17:05:20 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029B :CS-3 :956-64 :: Exp:PAHAIR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%, 10000.0,0.00%,F,T)
100% A1.23E8
90 j
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-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 17:05:20 GC E1+ Voltage SIR 70SE
Sample#3 Text:ST1029B :CS-3 :956-64 :: ExprPAHAIR
268.9824 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-3.0E7
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0 Time
-------
FIIe:29OC98V4 #1-510 Acfl:29-OCT-199817:54:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PA!IA)R
128.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
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142.0782 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FUe:29OC98V4 #1-510 Acq:29-OCT-1998 17:54:20 GC EI+ Voltage SIR 70SE
Sample#4 Text:ST1029C :CS-4 :265-04D i Exp:PAHAIR
152.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.20E8
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14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:6o 16:12 16:24 16:36 16:48 17:00 Time
160.1128 S:4 SMO(1,3) PKb(5,3,3,0.10%,10000.0,0.00%,F,T)
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164.1410 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:29OC98V4 #1-510 Acq:29-OCT-1998 17:54:20 GC EH- Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PAHAIR
130.9920 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FHe:290C98V4 #1-641 Acq:29-OCT-1998 17:54:20 GC E1+ Voltage SIR 70SE
Sample#4 Text:ST1029C :CS-4 :265-04D : Exp:PAHAlR
166.0798 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-641 Acq:29-OCT-1998 17:54:20 GC E1+ Voltage Sift 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PAHAIR
1009
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Flle:29OC98V4 #1-641 Acq:29-OCT-1998 17:54:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PAHALR
204.9888 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Fllct290C98V4 #1-939 Acq:29-OCM99817:54:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PAHAIR
202.0782 S:4 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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212.1410 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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90 j A1.62E8
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-------
File:290C98V4 #1-939 Acq:29-OCT-1998 17:54:20 GC EI+ Voltage SIR 70SE
Sample#4 Text:ST1029C :CS-4 :265-04D : Exp:PAHAIR
228.0939 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FUe:290C98V4 #1-939 Acq:29-OCT-1998 17:54:20 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : ExprPAHAIR
230.9856 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:29OC98V4 #1-878 Acq:29-OCT-1998 17:54:20 GC El-f Voltage SIR 70SB
Sampled Text:ST1029C :CS-4 :265-04D : ExptPAHAIR
252.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0,00%,F,T)
100 % A5.0.0E8
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264.1692 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A2.43E8
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-------
Flle:29OC98V4 #1-878 Acq:29-OCT-1998 17:54:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : ExprPAHAER
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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288.1692 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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278.1096 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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292.1974 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:00
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File:29OC98V4 #1-878 Acq:29-OCT-1998 17:54:20 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : Exp:PAHAlR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.02E8
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278.1096 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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F1le:29OC98V4 #1-878 Acq:29-OCT-J99817:54:20 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029C :CS-4 :265-04D : ExpiPAHAIR
268.9824 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
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o
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-------
File:290C98V4 #1-510 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : ExprPAHAlR
128.0626 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0,00%,F,T)
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136.1128 S:5 SMO(1,3) PtfD(5,3,3,0.10%,10000.0,0.00%,F,T)
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152.1410 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:29OC98V4 #1-510 Acq:29-OCT-1998 18:43:24 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp:PAHAlR
152.0626 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.76E8
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160.1128 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:29OC98V4 #1-510 Acq:29-OCT-I998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : ExptPAHAIR
130.9920 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:290C98V4 #1-641 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Samplers Text:ST1029D :CS-5 :26S-04E : Exp:PAHAlR
166.0798 S:S F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.18E8
90 J
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FIIe:29OC98V4 #1-641 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Samplers Text:ST1029D :CS-5 :265-04E : ExprPAHAIR
178.0782 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:29OC98V4 #1-641 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp:PAHAlR
204.9888 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-939 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : ExprPAHAIR
202.0782 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0)0.00%,F,T)
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F1le:290C98V4 #1-939 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp:PAHAlR
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-------
Flle:290C98V4 #1-939 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp:PAHAlR
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r
'•
j
bk
ft
)0 ' 24:00 25:1)0 26:i)0 27:6fl 28:00 29:1)0 30:1)0 31:
3.8E8
:
3.6E8
3.4E8
3.2E8
-3.0E8
-2.9E8
L2.7E8
:2.5E8
2.3E8
L2.1E8
L1.9E8
L1.7E8
Ll.SES
Ll.3E8
L1.1E8
L9.5E7
-7.6E7
L5.7E7
-3.8E7
H.9E7
O.OEO
10 Time
in
-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 18:43:24 GC E1+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp:PAHAlR
252.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.33E9
90 J
80 j
70 j
60 J
50 J
40
30 J
20 J
10
0
A1.29E9
31:00 32:00 33:00
264.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
"34-60
36:t
37:
o
•_o
U'3
3.0E8
12.6E8
.2.3E8
2.0E8
1.6E8
_1.3E8
9.9E7
-6.6E7
L3.3E7
O.OEO
)0 Time
100S
90 J
80:
70 J
60.
50 J
40 j
30 J
20 J
10 J
oJ
31:
A2.5
A2.43E8
i
.1
i 1
\
v_
8
1"'
«
N
4E8
v_
)0 32:6o 33:bo 34:bo 35:i>0 36:i)0 37:
-5.7E7
_5.1E7
-4.6E7
-4.0E7
L3.4E7
-2.8E7
1.2.3E7
:1.7E7
L1.1E7
L5.7E6
i O.OEO
M) Time
,n
-------
File:290C98V4 #1-878 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-S :265-04E : ExprPAHAIR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.61E8
80:
60.
40:
20:
0
37
A6.71E8 ft)
00
38:00
39:t
288.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
278.1096 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60:
40:
20
0
37:
)0
38
:00
39
:00
292.1974 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 2
80:
60
40:
20:
0
37:00
A6.62E7
38:00
39:6o
40:00
41:6o
40
:00
41
:00
40:00
41:0
42:
.-7.6E7
:6.1E7
14.6E7
13.1E7
Ll.5E7
O.OEO
)0 Time
1.4E7
L1.1E7
L8.3E6
L5.5E6
:2.8E6
42:
.O.OEO
)0 Time
4.3E7
:3.4E7
.2.6E7
.1.7E7
L8.5E6
)0 Time
42:
6.6E6
-5.3E6
-4.0E6
1.2.7E6
:1.3E6
-O.OEO
)0 Time
>i
-------
File:290C98V4 #1-878 Acq:29-OCT-1998 18:43:24 GC EI+ Voltage SIR 70SE
Sampled Text:ST1029D :CS-5 :265-04E : Exp.PAHAIR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:5038:6o 39:6fl
278.1096 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.9.7E8
JLO.OEO
)0 Time
O.OEO
42:00 Time
-------
FUe:290C98V4 #1-878 Acq:29-OCT-1998 18:43:24 GC EH- Voltage SIR 70SE
Sample#5 Text:ST1029D :CS-5 :265-04E : ExprPAHAIR
268.9824 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
90:
80:
70 j
6til
50 J
40:
30:
20:
10J
0
31
280.9!
100 2
90 J
wl
70:
60 1
50_
40_
30_
20-
10 _
0
31:
Al.05iraA6.45E7 A5.60E7 AK4jDE8^ A7.27E7 A1.23E8 A1.07E8 A1.00E8
pv -v i,y |^. v- > yv-p ^ ^^^ TTTfT"" i '
L JL
10 32:bo 33:00 34:00 35:00 36:6o 37:6o 38:00 39:00 40:6o 41:00 42:
»24 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.51E8 A1.19E8 y^g 41E7 A9.20E7 A1.77E8 A1.31E8 A9.68E7 A9.18E7 A1.07E8
)0 32:00 33:6o ' 34:6fl' 35:6o 36:00 37:6o' 38:6o 39:6o ' 40:00 41:6o 42:i
4.8E7
.4.3E7
-3.8E7
-3.4E7
-2.9E7
.2.4E7
-1.9E7
_1.4E7
.9.6E6
4.8E6
O.OEO
»0 Time
2.4E8
2.1E8
-1.9E8
L1.7E8
:1.4E8
1.2E8
L9.5E7
L7.1E7
:4.8E7
_2.4E7
O.OEO
0 Time
r?
i/3
.61
-------
Continuing Calibration
554
-------
QUANTERRA INCORPORATED
West Sacramento
Daily Standard Checklist
Dioxin/Furan High Res
STD ID STIO^°\£ Method ID ^^-^-Avf Column ID hB-^" Instr ID l/£- ^
Standard Solution Cj^-^U Prepared By ^,rr\A- Prepared Date H-O^--*}^*
Analyzed By ' < /Y\ A /A W Date Analyzed 1 O - <3- ct — ^ 9!
Reviewed By \jtf\Ji &tft<\JL> Date Reviewed 1 1 - 3 - ^ff
&" *
Standard, CPSM, and solvent blank present?
Copy of Instrument loqfile present?
CPSM blow up and peak profile present?
Curve summary present?
Summary of 1613A criteria present?
Daily standard within method specified limits*?
Daily ion abundance ratios within limits?
CPSM valley < 25%?
---^S"/****
C^SIvI window correct?
Samples analyzed within 12 hrs of daily standard?
.//AM
^
NA/^
^
A/A
•*
A/A
A/A
^
^
^^^^e^9%^flSBBfflffl8MJB^^P
S
ttfr/is
/
MA"
G>
M^
L 1 £^"
|^ *•
^f
/
COMMENTS:
«•
^•A/-7 <-.
/
n T£i y'x- r^ /"I ,• / ' "tf -*\s> 4~ \/~ n f S)J\ ~tkot 11
^Z
-,/
r.
lit A Of ^--
--- -
"*-x
ff \ h x
c/
J
^jj^uy.'g>J^6.| tj
guJ^ Pr.'s fljtj k be li-^id
For NCASI 551, Control Limit (CL) = +/- 20% from curve RRFs for all analytes.
For Method 8290, CL = +/- 20% from curve RRFs for native analytes, CL = +/- 30% from curve
labeled compounds.
For Method 1613A, see 3rd Revision to Method 1613 Performance Specifications, Table 7.
-------
•NOV-1998 08:15:11 AM Dioxin Furan ConCal RESULTS
3S Spec : VG-4
Column : DB-5
;a file : 290C98V4
Lght : 1
Name
10 - 2 -Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
12-Benzo (b) f luoranthene
• Benzo(b)fluoranthene
12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2 -Benz o(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
114-Dibenz (ah) anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 290C98V4071.RES
Date analyzed
ST1029E :CS-3 :956-64 : : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL3.TRG
29-OCT-98
pg
%
Dev
67809400
226452000
283054000
98533400
67166000
69855400
35367200
46600000
88742800
116294400
157910000
240408000
187689600
178902400
157032000
252590000
233216000
273298000
255434000
149476600
180687200
234240000
267286000
478608000
211046000
216280000
444140000
459304000
313348000
441892000
299770000
303216000
473068000
209746000
133400000
95717400
174180200
257774000
331102000
116294400
94089400
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
12:
10:
10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
21:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
29
14
17
36
29
32
3
8
56
43
48
47
51
0
1
37
41
18
22
9
13
16
21
23
30
34
35
39
34
28
38
50
56
3
10
7
17
15
23
43
48
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y -
Y
Y
Y
Y
0
3
1
0
0
1
0
1
0
1
1
2
0
0
-1
1
0
1
0
0
1
1
1
1
0
1
0
1
0
1
0
0
1
0
. 0
0
1
0
1
0
0
.00
.34
.25
.44
.99
.04
.52
.32
.00
.31
.36
.71
.78
-74
.00
.61
.92
.74
.93
.95
.21
.49
.14
.00
.44
.02
.93
.03
.65
.41
.96
.63
.56
.44
.64
.20
.82
.54
.28
.24
.81
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
ICO.
100.
100.
100".
100.
100.
100.
100.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
O'O
00
00
00
00
49
2
-22
-18
10
-30
6
-8
17
-4
-13
-7
14
-17
15
-22
6
0
17
5
-3
-12
-2
-11
-3
-14
-11
1
-9
-1
2
-19
30
-7
26
-------
$0m<:?20 J
FILE SAMP
No.
(1)
LAB.
SAMP No
CUSTOMER
ID
CLEAN
UP 1
(SDS)
CLEAN
UP 2
(D2)
TYPE CONCn.
(1)
290C98V4 1
290C98V4 2
290C98V4 3
290C98V4 4
290C98V4 5
290C98V4 6
290C98V4 7
290C98V4 8
290C98V4 9
290C98V4 10
290C98V4 11
290C98V4 12
290C98V4 13
290C98V4 14
290C98V4 15
290C98V4 16
290C98V4 17
290C98V4 18
290C98V4 19
290C98V4 20
290C98V4 21
290C98V4 22
290C98V4 23
290C98V4 24
290C98V4 25
290C98V4 26
290C98V4 27
290C98V4 28
290C98V4 29
290C98V4 30
290C98V4 31
290C98V4 32
290C98V4 33
290C98V4 34
290C98V4 35
290C98V4 36
290C98V4 37
290C98V4 38
290C98V4 39
290C98V4 40
290C98V4 41
290C98V4 42
290C98V4 43
290C98V4 44
290C98V4 45
290C98V4 46
290C98V4 47
290C98V4 48
290C98V4 49
290C98V4 50
ST1029
ST1029A
ST1029B
ST1029C
ST1029D
SB1029A
ST1029E
SB1029B
302050-1MB
302050-1LC
302050-1BA
302050-1LA
302050-2
302050-4
302050-6
302050-8
302050-1
302050-3
302050-5
302050-7
301802-1
301802-2
301802-3
SB1029C
ST1029F
SB1029D
301802-1MB
301802-1LC
301802-4
301802-5
301802-6
301802-7
301802-8
301802-9
301802-10
301802-11
301802-12
301802-13
301802-14
SB1029E
CS-1
CS-2
CS-3
CS-4
CS-5
Solvent Blank
CS-3
Solvent Blank
METHOD BLANK
LCS
METHOD BLANK
LCS
CLXTP
CLXTR
CLXTW
CLXVO
CLXTM
CLXTQ
CLXTV
CLXTX
10X DIL.
10X DIL.
10X DIL.
Solvent Blank
CS-3
Solvent Blank
METHOD BLANK
LCS
10X DIL.
10X DIL.
10X DIL.
10X DIL. ,
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
Solvent Blank
265-04A
265-04B
956-64
265-04D
265-04E
C-8
956-64
C-8
AIR PAH
AIR
C-8
956-64
C-8
AIR
PAH
PAH
C-8
1
1
1
1
1
1
1
1
VSE-25 0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
VSE-26 0.50
0.50
0.50
1
1
1
VSE-26 0.50
0.50
0.50
0.50
0.50
0.50
•0.50
0.50
0.50
0.50
0.50
0.50
0.50
1
SMA, AM 10-29-98
Y5-
-------
Peak Locate Examination:29-OCT-1998:15:23 File:290C98V4
Experiment:PAHAIR Function:! Reference:PFK
118.98012 118.99202 119.00392
Volts
6.8186
130.97892 130.99202 131.00512
Volts
0.1396
142.97772 142.99202 143.00632
Volts
0.3615
Volts
0.0773
Volts
1.3664
149.97542 149.99042 150.00542
154.97652 154.99202 155.00752
168.97192 168.98882 169.00571
-------
Peak Locate Examination:29-OCT-1998:15:23 File:29OC98V4
Experiment:PAHAIR Function:2 Reference:PFK
154.97652 154.99202 155.00752
Volts
1.8780
168.97192_168,9888 2 169,00571
Volts
9.3212
180.97072 180.98882 181.00691
LO
192.96952 192.98882 193.00811
Volts
0.1808
204.96832 204.98882 205.00931
-------
-J
o-
Peak Locate Examination:29-OCT-1998:15:24 File:290C98V4
Experiment:PAHAIR Function:3 Reference:PFK
PPM
200
Volts
0.6141
192.96952 192.98882 193.00811
Volts
3.3285
230.96253 230.98563 231.00872
Volts
0.2019
204.96832 204.98882 205.00931
218.96373 218.98563 219.00752
o
•0
l/J
242.96133 242.98563 243.009921 1254.96013 254.98563 255.01112
-------
Peak Locate Examination:29-OCT-1998:15:26 File:29OC98V4
Experiment:PAHAIR Function:4 Reference:PFK
Volts
0.3447
254.96013 254.98563 255.01112
Volts
0.3653
268.95555 268.98245 269.00935
H
Volts
2.1290
280.95435 280.98245 281.01055
Volts
0.9836
292.95315 292.98245 293.01175
-------
02-NOV-1998 08:06:49 AM
Mass Spec : VG-4
GC Colunn : DB-5
265-04A,B,D,E,956-6/«
Mult.: 350
dS-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
d10-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
Dfoxin Furan CALIBRATION TABLE
Fite name
Date analyzed
PAHAIR102998V4.RRF
29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.42
1.16
2.81
0.89
0.80
1.41
1.11
1.52
1.21
S.D.
0.289
0.094
0.084
0.093
0.045
0.099
0.177
0.066
0.191
0.173
0.063
0.031
0.141
0.174
0.154
0.269
%RSD
12.900
7.707
14.909
7.696
4.773
13.310
14.178
4.625
16.420
6.145
7.028
3.901
10.009
15.653
10.160
22.353
1
100.00
185.11
1.85
10.00
13.76
1.38
10.00
6.91
0.69
100.00
131.95
1.32
10.00
9.55
0.95
100.00
83.11
0.83
10.00
10.98
1.10
100.00
153.24
1.53
10.00
8.53
0.85
100.00
308.98
3.09
10.00
9.70
0.97
10.00
8.13
0.81
100.00
118.94
1.19
10.00
14.14
1.41
100.00
129.03
1.29
10.00
16.74
1.67
2
100.00
205.87
2.06
50.00
61.93
1.24
50.00
29.85
0.60
100.00
128.38
1.28
50.00
48.30
0.97
100.00
77.72
0.78
50.00
62.63
1.25
100.00
135.78
1.36
50.00
58.18
1.16
100.00
263.63
2.64
50.00
46.13
0.92
50.00
42.20
0.84
100.00
136.07
1.36
50.00
55.12
1.10
100.00
143.24
1.43
50.00
59.11
1.18
3
100.00
228.31
2.28
100.00
113.47
1.13
100.00
51.39
0.51
100.00
114.60
1.15
100.00
90.68
0.91
100.00
76.15
0.76
100.00
151.76
1.52
100.00
140.61
1.41
100.00
117.21
1.17
100.00
276.27
2.76
100.00
81.87
0.82
100.00
77.06
0.77
100.00
145.72
1.46
100.00
99.77
1.00
100.00
158.81
1.59
100.00
104.58
1.05
4
100.00
244.46
2.44
200.00
231.43
1.16
200.00
97.93
0.49
100.00
122.45
1.22
200.00
178.19
0.89
100.00
77.96
0.78
200.00
215.88
1.08
100.00
141.09
1.41
200.00
249.15
1.25
100.00
272.04
2.72
200.00
168.14
0.84
200.00
153.96
0.77
100.00
150.34
1.50
200.00
200.49
1.00
100.00
161.45
1.61
200.00
204.18
1.02
5
100.00
256.61
2.57
500.00
609.70
1.22
500.00
255.67
0.51
100.00
109.50
1.10
500.00
500.84
1.00
100.00
57.36
0.57
500.00
641.50
1.28
100.00
139.72
1.40
500.00
684.13
1.37
100.00
282.87
2.83
500.00
460.23
0.92
500.00
402.42
0.80
100.00
154.31
1.54
500.00
521.18
1.04
100.00
166.55
1.67
5.00.00
551.22
1.10
10
in
vJt
-------
D2-NOV-1998 08:06:52 AM
Mass Spec : VG-4
GC Column : DB-5
265-04A.B.D,E,956-64
Mult.: 350
d12-Benzo(a}anthracene
BenzoC a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d14-Dibenz(ah)anthracene
Dioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.90
1.20
1.28
1.08
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
S.D.
0.238
0.124
0.139
0.051
0.029
0.125
0.021
0.111
0.017
0.140
0.112
0.037
0.142
0.008
0.052
0.023
%RSD
26.446
10.269
10.855
4.716
6.414
10.717
2.203
9.525
2.504
8.557
10.437
5.829
8.297
1.722
8.352
9.286
1
100.00
68.20
0.68
10.00
11.85
1.18
100.00
109.94
1.10
10.00
10.44
1.04
100.00
41.05
0.41
10.00
12.56
1.26
100.00
91.66
0.92
10.00
12.71
1.27
100.00
65.24
0.65
10.00
18.05
1.80
10.00
11.71
1.17
100.00
64.89
0.65
10.00
16.93
1.69
100.00
44.86
0.45
10.00
5.85
0.59
100.00
20.73
0.21
2
100.00
70.96
0.71
50.00
64.84
1.30
100.00
119.85
1.20
50.00
56.47
1.13
100.00
45.84
0.46
50.00
61.73
1.23
100.00
94.95
0.95
50.00
63.16
1.26
100.00
66.86
0.67
50.00
89.03
1.78
50.00
60.46
1.21
100.00
58.55
0.59
50.00
98.08
1.96
100.00
44.54
0.45
50.00
35.13
0.70
100.00
24.39
0.24
3
100.00
127.65
1.28
100.00
102.61
1.03
100.00
127.65
1.28
100.00
102.61
1.03
100.00
49.22
0.49
100.00
95.82
0.96
100.00
96.52
0.97
100.00
119.14
1.19
100.00
69.56
0.70
100.00
157.16
1.57
100.00
102.44
1.02
100.00
68.21
0.68
100.00
162.24
1.62
100.00
44.08
0.44
100.00
60.26
0.60
100.00
25.35
0.25
4
100.00
89.95
0.90
200.00
234.26
1.17
100.00
136.79
1.37
200.00
215.75
1.08
100.00
45.10
0.45
200.00
228.66
1.14
100.00
94.09
0.94
200.00
210.18
1.05
100.00
67.87
0.68
200.00
302.58
1.51
200.00
200.46
1.00
100.00
62.00
0.62
200.00
324.02
1.62
100.00
43.39
0.43
200.00
127.89
0.64
100.00
26.10
0.26
5
100.00
93.26
0.93
500.00
671.78
1.34
100.00
145.35
1.45
500.00
571.04
1.14
100.00
45.72
0.46
500.00
622.27
1.24
100.00
96.82
0.97
500.00
522.11
1.04
100.00
68.82
0.69
500.00
767.23
1.53
500.00
476.32
0.95
100.00
61.45
0.61
500.00
835.41
1.67
100.00
45.40
0.45
500.00
287.53
0.58
100.00
26.33
0.26
r •
(J
L;
10
-------
02-NOV-1998 08:06:57 AM
Mass Spec : VG-4
GC Column : DB-5
265-04A.B,D,E,956-64
Mult.: 350
Dibenz(ah)anthracene
d12-Benzo(ghf>peryl°ne
Benzo(ghi)perylene
01oxin Furan CALIBRATION TABLE
File name
Date analyzed
PAHA1R102998V4.RRF
29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.40
0.58
1.02
0
S.D.
0.077
0.022
0.091
0
XRSD
5.452
3.838
8.984
0
1
10.00
12.92
1.29
100.00
59.24
0.59
10.00
8.58
0.86
0
2
50.00
69.25
1.38
100.00
54.17
0.54
50.00
51.44
1.03
0
3
100.00
143.15
1.43
100.00
59.73
0.60
100.00
109.18
1.09
0
4
200.00
281 .33
1.41
100.00
58.78
0.59
200.00
211.25
1.06
0
5
500.00
751.34
1.50
100.00
57.94
0.58
500.00
522.58
1.05
0
10
-------
FUe:29OC98V4 #1-510 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
128.0626 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
003
80:
60:
40:
20 _
0
9:
A1.42E8
l\
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1 ^
0 10:6fl ll:6o 12:6o 13:6o 14:00 15:
2.9E7
L2.3E7
L1.8E7
Ll.2E7
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)0 Time
LO
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10
136.1128 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
152.1410 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
UU J.
80:
60:
40:
20:
0
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80 1
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20:
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80:
60 J
40^
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782 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.9
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V A8.23E6
v/v
0 10:00 11:00 12:00 13:6o 14:6o 15:i
2.4E7
-1.9E7
Ll.4E7
9.5E6
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-O.OEO
10 Time
1.0E7
L8.3E6
L6.2E6
L4.1E6
L2.1E6
-O.OEO
)0 Time
13:60 14:6fl 15:
7.8E6
:6.3E6
-4.7E6
-3.1E6
.1.6E6
LO.OEO
)0 Time
-------
File:29OC98V4 #1-510 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :9S6-64 :: Exp:PAHAIR
152.0626 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80:
60:
40:
20:
0
160.1
1002
80:
60:
40J
20 J
0
14:
> A3.49E7
A
1
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128 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.36E7
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A
\ A7.12E6
/ V_ /v
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60 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36 15:48 16:6o 16:12 16:24 16:36 16:48 17:
8.7E6
_7.0E6
5.2E6
:3.5E6
:l.7E6
L O.OEO
(0 Time
8.5E6
6.8E6
L5.1E6
L3.4E6
:1.7E6
.O.OEO
)0 Time
154.0782 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80:
60:
40-
20-
0
14:
164.1
100 S
80
60:
40:
20:
0
14:
. A3.18E7
/\
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i0 14:12 14:24 14:36 14:48 15:5o 15:12 15:24 15:36 15:48 16:60 16:12 16:24 16:36 16:48 17:
410 S:7 SMOa,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
P A1.77E7
A
f\
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66 14:12 14:24 14:^6 14:48 15:66 15:i2 15:24 15:^6 15:48 16:66 1^2 16:24 16:^6 16:48 17:
-6.9E6
L5.5E6
L4.1E6
L2.8E6
•-1.4E6
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)0 Time
4.8E6
:3.8E6
:2.9E6
Ll.9E6
-9.6E5
.O.OEO
)0 Time
LJ
-------
File:29OC98V4 #1-510 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
154.0782 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
u:
15:48
15:54
16:00
16:66
-O.OEO
Time
-------
F11e:29OC98V4 #1-510 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sampled? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
130.9920 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
95 J
90 J
85 J
80
75 J
70 J
65 J
60 J
551
50
45
40
35
30
25
20
10
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12:60
13
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14
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15:1)0
17
4.5E8
4.2E8
4.0E8
3.8E8
3.6E8
3.4E8
3.1E8
2.9E8
2.7E8
2.5E8
-2.2E8
L2.0E8
1.8E8
Ll.6E8
1.3E8
L1.1E8
L8.9E7
L6.7E7
L4.5E7
L2.2E7
O.OEO
)0 Time
30
-------
File:29OC98V4 #1-641 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sampled? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
166.0798 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.90E7
90J
80 J
70 J
60 J
50 J
40 J
30 J
20-j
10 J
"—i i i i i i i i i i i i i i i i i i i i i i 'i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i I i i i i i I i i i i i I i i i i i I i i i i i i i i i i i | i
17:60 17:12 17:24 17:36 17:48 18:6o 18:12 18:24 18:36 18:48 19:6o 19:12 19:24 19:36 19:48
172.0984 S:7 F:2 S MO (1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.70E7
100 S
904
80 J
70 J
60 J
50 J
40 J
30 J
20J
10 J
0
17:
176.1410 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
00 17:12 17:24 17:36 17:48 18:66 18:i2 18:24 18:36 18:48 19:6fl 19:i2 19:24 19:36 19:48
1002
90 J
80 J
70 J
60 J
50 J
40J
30 J
20J
10 J
A5.8E7
20:
2.5E7
L2.3E7
L2.0E7
L1.8E7
L1.5E7
L1.3E7
L1.0E7
L7.6E6
L5.1E6
L2.5E6
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10 Time
20:
17:00 17:i2 17:24 17:36 17:48 18:66 18:ii 18:24 18:36 18:48 19:66 19:i2 19:24 19:36 19:48
20:
1.5E7
L1.4E7
L1.2E7
L1.1E7
L9.0E6
L7.5E6
6.0E6
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L3.0E6
L1.5E6
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1.9E7
L1.8E7
L1.6E7
.1.4E7
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LO.OEO
)0 Time
^
*J
-------
Flle:29OC98V4 #1-641 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64 :: Exp:PAHAIR
178.0782 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
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70 J
60 J
50 j
40J
30^
20 J
10 J
0
19:
188.1
1003
90 J
80 J
70 J
60 1
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40 1
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20 1
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19:
A9.38E7
A8.95E7
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410 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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12.4E7
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_7.0E6
L3.5E6
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4.6E7
L4.1E7
L3.7E7
L3.2E7
12.8E7
L2.3E7
L1.8E7
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1.9.2E6
L4.6E6
LO.OEO
to Time
-------
File:29OC98V4 #1-641 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
204.9888 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
003
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85:
80:
75:
70:
65:
60:
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45:
40:
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:5.1E6
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L3.9E6
:3.4E6
:2.8E6
L2.2E6
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L5.6E5
O.OEO
0 Time
H
r-
-------
File:29OC98V4 #1-939 Acq:29-OCT-1998 20:21:30 GC E1+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAIR
202.0782 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90j A1.17E8
80 1
60 J
50 J
40J
30 J
20 J
10 J
A1.28E8
23:00 24:00
212.1410 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 8
90 J A1.26E8
80 J
70 J
60 J
50 J
40J
30 J
20 J
10
26:00
A1.37E8
_ , _ ,_
23:00 24:00
244.1974 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
90 J
80
70 J
60 J
50 J
40 J
30 J
20 J
25:C
10 J
23:00
r4.3E7
L3.8E7
L3.4E7
L3.0E7
L2.6E7
L2.1E7
L1.7E7
L1.3E7
8.5E6
27:
24:
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26
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5.1E7
L4.6E7
L4.1E7
L3.6E7
L3.1E7
L2.5E7
L2.0E7
L1.5E7
L1.0E7
L5.1E6
LO.OEO
)0 Time
27:
2.6E7
L2.4E7
L2.1E7
L1.8E7
L1.6E7
L1.3E7
L1.1E7
L7.9E6
L5.3E6
L2.6E6
LO.OEO
27:00 Time
-------
FIIe:29OC98V4 #1-939 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sampled? Text:ST1029E :CS-3 :956-64 : : Exp:PAHAK
228.0939 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
002
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FUe:29OC98V4 #1-878 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
Sample*? Text:ST1029E :CS-3 :956-64:: Exp:PAHAIR
252.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0,10%,10000.0,0.00%,F,T)
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FUe:29OC98V4 #1-878 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
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276.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:29OC98V4 #1-878 Acq:29-OCT-1998 20:21:30 GC El-f Voltage SIR 70SE
Sampled Text:ST1029E :CS-3 :956-64 :: Exp:PAHAIR
276.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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P11e:29OC98V4 #1-878 Acq:29-OCT-1998 20:21:30 GC EI+ Voltage SIR 70SE
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FUe:29OC98V4 #1-510 Acq:29-OCT-1998 21:10:34 GC El-f Voltage SIR 70SE
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128.0626 S:8 SMO(l,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:290C98V4 #1-510 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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FUe:29OC98V4 #1-510 Acq:29-OCT-1998 21:10:34 GC E1+ Voltage SIR 70SE
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130.9920 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-641 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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166.0798 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FlIe:29OC98V4 #1-641 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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178.0782 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FUe:29OC98V4 #1-641 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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204.9888 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:290C98V4 #1-939 Acq:29-OCT-1998 21:10:34 GC E1+ Voltage SIR 70SE
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202.0782 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FUe:29OC98V4 #1-939 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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228.0939 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%>F,T)
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Flle:29OC98V4 #1-939 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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File:290C98V4 #1-878 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
Sampled Text:SB1029B :Solvent Blank :C Exp:PAHAIR
252.0939 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
Sampled Text:SB1029B '.Solvent Blank :C Exp:PAHAIR
276.0939 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:29OC98V4 #1-878 Acq:29-OCT-1998 21:10:34 GC EI+ Voltage SIR 70SE
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-------
STDID
Standard Solution
Analyzed By ' gL rc\ <
Prepared Date U - o 2.-
Date Analyzed Ift -
Date Reviewed 1 1 - 0?> -
Standard, CPSM, and solvent blank present?
Copy of Instrument logfile present?
CPSM blow up and peak profile present?
Curve summary present?
Summary of 1613A criteria present?
Daily standard within method specified limits*?
Daily ion abundance ratios within limits?
A//I
CPSM valley < 25%?
A//J
correct?
Samples analyzed within 12 hrs of daily standard?
i/
COMMENTS:
A y)
For NCASI 551, Control Limit (CD = + /- 20% from curve RRFs for all analytes.
For Method 8290, CL = +/- 20% from curve RRFs for native analytes, CL = +/- 30% from curve RRFs for
labeled compounds.
For Method 1613A, see 3rd Revision to Method 1613 Performance Specifications, Table 7.
-------
I2-NOV-1998 08:06:27 AM Dioxin Furan ConCal RESULTS
[ass Spec : VG-4
}C Column : DB-5
teta file : 300C98V4
[eight : l
; Name
dlO-2-Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Ac enaphthene
dl 0-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
112-Benzo (b) f luoranthene
Benzo(b)fluoranthene
112-Benzo (k) fluoranthene
Benzo(k) fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benz o(a)pyrene
d!2-Perylene
Perylene
I12-lndeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
114-Dibenz (ah) anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 300C98V4031.RES
Date analyzed
ST1030A :CS-3 :956-64 : : Ex
Total Isotope R. T. RRF
PAHAIRCAL3.TRG
30-OCT-98
pg *
espuxme i
78684600
139825400
153251600
70172200
103173000
87923600
65038200
59601000
49881400
73075400
60563400
155005800
123196000
112909800
127810400
143799600
153031600
159392600
180647000
107231400
109481400
172908800
147111000
229522000
110222800
115912400
222508000
276998000
163626400
284102000
187480200
153983800
303846000
120288800
59200000
69941000
83626600
163634200
144641400
73075400
59403200
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10
10
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15
15
16
16
20
17
17
20
20
20
26
24
24
25
25
29
29
29
29
33
32
32
32
32
33
33
33
33
33
38
38
38
38
39
39
17
17
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28
13
16
34
28
31
1
8
55
42
47
46
50
59
0
36
40
17
21
8
12
15
20
22
28
34
34
38
32
27
38
49
55
1
8
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15
12
21
42
47
Y
Y
Y
Y
Y
Y
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Y
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Y
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Y
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Y
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Y
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.85
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.81-
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
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8
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11
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-7
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6
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6
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2
7
5
6
7
6
15
18
-21
24
-15
23
-13
-------
<=0m<:?20 J
FILE
SAMP
No.
(1)
LAB.
SAMP No
CUSTOMER
ID
CLEAN
UP 1
(SDS)
CLEAN
UP 2
(D2)
TYPE CONCn.
(1)
300C98V4 1
300C98V4 2
300C98V4 3
300C98V4 4
300C98V4 5
300C98V4 6
300C98V4 7
300C98V4 8
300C98V4 9
300C98V4 10
300C98V4 11
300C98V4 12
300C98V4 13
300C98V4 14
300C98V4 15
300C98V4 16
300C98V4 17
300C98V4 18
300C98V4 19
300C98V4 20
300C98V4 21
300C98V4 22
300C98V4 23
30OC98V4 24
300C98V4 25
300C98V4 26
300C98V4 27
300C98V4 28
300C98V4 29
300C98V4 30
300C98V4 31
300C98V4 32
300C98V4 33
300C98V4 34
300C98V4 35
300C98V4 36
300C98V4 37
300C9SV4 38
300C98V4 39
300C98V4 40
300C98V4 41
300C98V4 42
300C98V4 43
300C98V4 44
300C98V4 45
300C98V4 46
300C98V4 47
300C98V4 48
300C98V4 49
300C98V4 50
ST1030
SB1030
ST1030A
SB1030A
301802-1MB
301802-1LC
301802-4
301802-5
301802-6
301802-7
301802-8
301802-9
301802-10
301802-11
301802-12
301802-13
301802-14
SB1029E
CS-3
Solvent Blank
CS-3
Solvent Blank
METHOD BLANK
LCS
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
10X DIL.
Solvent Blank
956-64
C-8
956-64
C-8
AIR PAH
VSE-26
C-8
SMA, AM 10-30-98
1
1
1
1
0.50
0.50
0.50
0.50
0.50
.0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
60
-------
cr-
Peak Locate Examination:30-OCT-1998:16:37 File:30OC98V4
Experiment:PAHAIR Function:1 Reference:PFK
Volts
0.0680
Volts
1.1671
VoltS
2.4819
130.97892 130.99202 131.00512
142.97772 142.99202 143.00632
118.99202
119.00392
118.98012
Volts
0.1628
Volts
0.0413
149.97542 149.99042 150.00542
154.97652 154.99202 155.00752
Volts
0.6901
168.97192 168.98882 169.00571
-------
Peak Locate Examination:30-OCT-1998:16:39 File:30OC98V4
Experiment:PAHAIR Function:2 Reference:PFK
Cfl
UJ
Volts
0.0508
154.97652 154.99202 155.00752
PPM
200
Volts
0.7613
168.97192 168.98882 169.00571
PPM
200
Volts
3.0715
180.97072 180.98882 181.00691
PPM
200
Volts
0.1946
.yW'
192.96952 192.98882 193.00811
Volts
0.0854
204.96832 204.98882 205.00931
-------
Peak Locate Examination:30-GCT-1998:16:40 File:300C98V4
Experiment:PAHAIR Function:3 Reference:PFK
CTJ
Volts
0.2604
192.96952 192.98882 193.00811
Volts
0.0978
204.96832 204.98882 205.00931
Volts
0.3718
218.96373 218.98563 219.00752
Volts
1.2103
230.96253 230.98563 231.00872
Volts
0.6202
242.96133 242.98563 243.00992
Volts
0.1497
254.96013 254.98563 255.01112
-------
Peak Locate Examination:30-OCT-1998:16:41 File:30OC98V4
Experiment:PAHAIR Function:4 Reference:PFK
Volts
0.7610
242.96133 242.98563 243.00992
Volts
0.1696
254.96013 254.98563 255.01112
Volts
0.1469
'J\
uo
268.95555 268.98245 269.00935
Volts
0.7636
280.95435 280.98245 281.01055
Volts
0.3838
292.95315 292.98245 293.01175
-------
02-NOV-1998 08:06:34 AH
Hats Spec : VQ-4
GC Column : DB-5
265-04A,B,D,E,956-64
Mult.: 350
dS-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
d10-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
Dfoxin FUran CALIBRATION TABLE
File name : PAHA1R102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount.
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
2.24
1.23
0.56
1.21
0.94
0.74
1.25
1.42
1.16
2.81
0.89
0.80
1.41
1.11
1.52
1.21
S.D.
0.289
0.094
0.084
0.093
0.045
0.099
0.177
0.066
0.191
0.173
0.063
0.031
0.141
0.174
0.154
0.269
%RSD
12.900
7.707
14.909
7.696
4.773
13.310
14.178
4.625
16.420
6.145
7.028
3.901
10.009
15.653
10.160
22.353
1
100.00
185.11
1.85
10.00
13.76
1.38
10.00
6.91
0.69
100.00
131.95
1.32
10.00
9.55
0.95
100.00
83.11
0.83
10.00
10.98
1.10
100.00
153.24
1.53
10.00
8.53
0.85
100.00
308.98
3.09
10.00
9.70
0.97
10.00
8.13
0.81
100.00
118.94
1.19
10.00
14.14
1.41
100.00
129.03
1.29
10.00
16.74
1.67
2
100.00
205.87
2.06
50.00
61.93
1.24
50.00
29.85
0.60
100.00
128.38
1.28
50.00
48.30
0.97
100.00
77.72
0.78
50.00
62.63
1.25
100.00
135.78
1.36
50.00
58.18
1.16
100.00
263.63
2.64
50.00
46.13
0.92
50.00
42.20
0.84
100.00
136.07
1.36
50.00
55.12
1.10
100.00
143.24
1.43
50.00
59.11
1.18
3
100.00
228.31
2.28
100.00
113.47
1.13
100.00
51.39
0.51
100.00
114.60
1.15
100.00
90.68
0.91
100.00
76.15
0.76
100.00
151.76
1.52
100.00
140.61
1.41
100.00
117.21
1.17
100.00
276.27
2.76
100.00
81.87
0.82
100.00
77.06
0.77
100.00
145.72
1.46
100.00
99.77
1.00
100.00
158.81
1.59
100.00
104.58
1.05
4
100.00
244.46
2.44
200.00
231.43
1.16
200.00
97.93
0.49
100.00
122.45
1.22
200.00
178.19
0.89
100.00
77.96
0.78
200.00
215.88
1.08
100.00
141.09
1.41
200.00
249.15
1.25
100.00
272.04
2.72
200.00
168.14
0.84
200.00
153.96
0.77
100.00
150.34
1.50
200.00
200.49
1.00
100.00
161.45
1.61
200.00
204.18
1.02
5
100.00
256.61
2.57
500.00
609.70
1.22
500.00
255.67
0.51
100.00
109.50
1.10
500.00
500.84
1.00
100.00
57.36
0.57
500.00
641.50
1.28
100.00
139.72
1.40
500.00
684.13
1.37
100.00
282.87
2.83
500.00
460.23
0.92
500.00
402.42
0.80
100.00
154.31
1.54
500.00
521.18
1.04
100.00
166.55
1.67
500.00
551.22
1.10
10
00
•fl
-------
02-NOV-1998 08:06:38 AM
Mass Spec : VG-4
GC Co limn : DB-5
265-04A,B,D,E,956-64
Mult.: 350
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fIuoranthene
Benzo( b) f I uoranthene
d12-Benzo(k)fIuoranthene
Benzo(k)fIuoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d14-Dibenz(ah)anthracene
Dioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.90
1.20
1.28
1.08
0.45
1.17
0.95
1.16
0.68
1.64
1.07
0.63
1.71
0.44
0.62
0.25
S.D.
0.238
0.124
0.139
0.051
0.029
0.125
0.021
0.111
0.017
0.140
0.112
0.037
0.142
0.008
0.052
0.023
XRSD
26.446
10.269
10.855
4.716
6.414
10.717
2.203
9.525
2.504
8.557
10.437
5.829
8.297
1.722
8.352
9.286
1
100.00
68.20
0.68
10.00
11.85
1.18
100.00
109.94
1.10
10.00
10.44
1.04
100.00
41.05
0.41
10.00
12.56
1.26
100.00
91.66
0.92
10.00
12.71
1.27
100.00
65.24
0.65
10.00
18.05
1.80
10.00
11.71
1.17
100.00
64.89
0.65
10.00
16.93
1.69
100.00
44.86
0.45
10.00
5.85
0.59
100.00
20.73
0.21
2
100.00
70.96
0.71
50.00
64.84
1.30
100.00
119.85
1.20
50.00
56.47
1.13
100.00
45.84
0.46
50.00
61.73
1.23
100.00
94.95
0.95
50.00
63.16
1.26
100.00
66.86
0.67
50.00
89.03
1.78
50.00
60.46
1.21
100.00
58.55
0.59
50.00
98.08
1.96
100.00
44.54
0.45
50.00
35.13
0.70
100.00
24.39
0.24
3
100.00
127.65
1.28
100.00
102.61
1.03
100.00
127.65
1.28
100.00
102.61
1.03
100.00
49.22
0.49
100.00
95.82
0.96
100.00
96.52
0.97
100.00
119.14
1.19
100.00
69.56
0.70
100.00
157.16
1.57
100.00
102.44
1.02
100.00
68.21
0.68
100.00
162.24
1.62
100.00
44.08
0.44
100.00
60.26
0.60
100.00
25.35
0.25
4
100.00
89.95
0.90
200.00
234.26
1.17
100.00
136.79
1.37
200.00
215.75
1.08
100.00
45.10
0.45
200.00
228.66
1.14
100.00
94.09
0.94
200.00
210.18
1.05
100.00
67.87
0.68
200.00
302.58
1.51
200.00
200.46
1.00
100.00
62.00
0.62
200.00
324.02
1.62
100.00
43.39
0.43
200.00
127.89
0.64
100.00
26.10
0.26
5
100.00
93.26
0.93
500.00
671.78
1.34
100.00
145.35
1.45
500.00
571.04
1.14
100.00
45.72
0.46
500.00
622.27
1.24
100.00
96.82
0.97
500.00
522.11
1.04
100.00
68.82
0.69
500.00
767.23
1.53
500.00
476.32
0.95
100.00
61.45
0.61
500.00
835.41
1.67
100.00
45.40
0.45
500.00
287.53
0.58
100.00
26.33
0.26
•JJ
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10
-------
02-NOV-1998 08:06:41 AH
Mass Spec : VG-4
GC Column : DB-5
265-04A.B.D.E,956-64
Mutt.: 350
Dibenz(ah)anthracene '
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
Ofoxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-9B
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.40
0.58
1.02
0
S.D.
0.077
0.022
0.091
0
%RSD
5.452
3.838
8.984
0
1
10.00
12.92
1.29
100.00
59.24
0.59
10.00
8.58
0.86
0
2
50.00
69.25
1.38
100.00
54.17
0.54
50.00
51.44
1.03
0
3
100.00
143.15
1.43
100.00
59.73
0.60
100.00
109.18
1.09
0
4
200.00
281 .33
1.41
100.00
58.78
0.59
200.00
211.25
1.06
0
5
500.00
751.34
1.50
100.00
57.94
0.58
500.00
522.58
1.05
0
O
10
-------
FUe:30OC98V4 #1-510 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-510 Acq:30-OCT-1998 18:23:22 GC EH- Voltage SIR 70SE
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Flle:30OC98V4 #1-641 Acq:30-OCT-199818:23:22 GC EI+ Voltage SIR 70SE
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-------
File:30OC98V4 #1-641 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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File:30OC98V4 #1-641 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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FUe:30OC98V4 #1-939 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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F1Ie:300C98V4 #1-939 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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-------
FHe:30OC98V4 #1-939 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
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§
-------
F11e:300C98V4 #1-878 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
Sampled Text:ST1030A :CS-3 :956-64 : : Exp:PAHAIR
252.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR 70SE
Sample#3 Text:ST1030A :CS-3 :956-64:: Exp:PAHAIR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File30OC98V4 #1-878 Acq:30-OCT-1998 18:23:22 GC EI+ Voltage SIR
Sampled Text:ST1030A :CS-3 :956-64 :: Exp:PAHAIR
27^.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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37il8 37:24' ' 37:30 37^6 37:42 37:48 37:54 38:00 38:06 38:12 38:18 38:24 38:30 38:36 38:42 38:48 38:54 39:00 Time
278.1096 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:300C98V4 #1-510 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sample#4 Text:SB1030A :Solvent Blank :C Exp:PAHAIR
128.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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O.OEO
15:00 Time
-------
File:30OC98V4 #1-510 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C ExprPAHAIR
152.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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160.1128 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
14:10 14:23 14:37
14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 15:48 16:00 16:i2 16:24 16:36 16:48 17:00 Time
154.0782 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
3.7E5
L2.9E5
12.2E5
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-------
FUe:30OC98V4 #1-510 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C ExprPAHAIR
130.9920 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FHe:30OC98V4 #1-641 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A .'Solvent Blank :C Exp:PAHAIR
166.0798 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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FUe:30OC98V4 #1-641 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :SoIvent Blank :C Exp:PAHAIR
178.0782 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-641 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C Exp:PAHAIR
204.9888 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:300C98V4 #1-939 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C Exp:PAHAIR
202.0782 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
FIIe:30OC98V4 #1-939 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A rSoIvent Blank :C ExprPAHAIR
228.0939 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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26:00 27:00 ' 28:00
240.1692 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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26:
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-------
F«e:30OC98V4 #1-939 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sample#4 Text:SB1030A :Solvent Blank :C Exp:PAHAIR
230.9856 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C Exp:PAHAIR
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :SoIvent Blank :C Exp:PAHAIR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:30OC98V4 #1-878 Acq:30-OCT-1998 19:12:25 GC EI+ Voltage SIR 70SE
Sampled Text:SB1030A :Solvent Blank :C Exp:PAHAIR
268.9824 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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^y
-------
STD ID £>-fUo2.
Standard Solution °\
-------
02-NOV-1998 02:17:04 PM Dioxin Furan ConCal RESULTS
Mass Spec
GC Column
Data file
Weight
: VG-4
: DB-5
: 02N098V4
: 1
Name
Results : 02N098V4011.RES
Date analyzed
ST1102 :CS-3 :956-64 : : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL3.TRG
02-NOV-98
pg
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo{ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Dev
245650000
392372000
376806000
233866000
311446000
274072000
187525800
173015800
146180800
200060000
153632400
486852000
390094000
327574000
354414000
401422000
401064000
430946000
432528000
257072000
261228000
376372000
334774000
432370000
224986000
261590000
511774000
508994000
306100000
448584000
302732000
267180000
458194000
231944000
118200000
138739800
141252600
299526000
252360000
200060000
160217000
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
12:
10:
'10:
12:
15:
15:
16:
16:
20:
17:
17:
20:
20:
20:
26:
24:
24:
25:
25:
29:
29:
29:
29:
33:
32:
32:
32:
32:
33:
33:
33:
33:
33:
38:
38:
38:
38:
39:
39:
17:
17:
27
12
15
33
27
30
1
7
55
41
47
45
50
58
0
36
39
18
21
8
12
15
20
22
29
33
33
38
32
27
37
49
55
1
8
5
14
12
21
41
46
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-2
1
0
0
1
0
0
0
-1
1
0
3
0
0
-2
1
1
1
1
0
1
1
0
0
0
1
1
0
0
1
0
0
1
0
0
0
1
0
0
0
0
.00
.60
.96
.60
.27
.88
.76
.92
.00
.37
.77
.33
.80
.67
.00
.13
.00
.22
.00
.73
.02
.06
.89
.00
.52
.16
.18
.99
.71
.47
.99
.62
.71
.54
.51
.32
.02
.69
.84
.46
.80
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
LOO.
100.
100;
-100.
100.
100.
100.
>-10Cfc
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
OC-
00:
TQ-0-
00
.00
,00
.00
:.Q»7
-29
-22
6
4
-7
3
-26
-4
•GS£
19
= 10
-16
-20
-10
-20
-17
-19
-16
-17
-18
15
0
25
-15
5
-11
-8
-2
0
21
-18
.- 31
-27
19
-17
-------
FILE SAMP LAB. CUSTOMER CLEAN CLEAN
No. SAMP No ID UP 1 UP 2
(1) (SDS) (D2)
TYPE CONCn.
(1)
02N098V4 1
02N098V4 2
02N098V4 3
02N098V4 4
02N098V4 5
02N098V4 6
02N098V4 7
02N098V4 8
02N098V4 9
02N098V4 10
02N098V4 11
02N098V4 12
02N098V4 13
02N098V4 14
02N098V4 15
02N098V4 16
02N098V4 17
02N098V4 18
02N098V4 19
02N098V4 20
02N098V4 21
02N098V4 22
02N098V4 23
02N098V4 24
02N098V4 25
02N098V4 26
02N098V4 27
02N098V4 28
02N098V4 29
02N098V4 30
02N098V4 31
02N098V4 32
02N098V4 33
02N098V4 34
02N098V4 35
02N098V4 36
02N098V4 37
02N098V4 38
02N098V4 39
02N098V4 40
02N098V4 41
02N098V4 42
02N098V4 43
02N098V4 44
02N098V4 45
02N098V4 46
02N098V4 47
02N098V4 48
02N098V4 49
02NO98V4 50
ST1102
SB1102
301802-1MB
301802-1LC
302050-1
302050-3
302050-5
302050-7
301802-1
301802-2
301802-3
301802-4
301802-6
302050-2
302050-8
ST1102A
SB1102A
302050-1MB
302050-1LA
302050-1M
302050-1LC
302050-4
302050-6
CS-3
Solvent Blank
METHOD BLANK
LCS
CLXTM 1:20 DL
CLXTQ 1:40 DL
CLXTV 1:20 DL
CLXTX 1:40 DL
100X DIL.
100X DIL.
100X DIL.
100X DIL.
100X DIL.
002CLXTP
006 CLXVO
CS-3
Solvent Blank
METHOD BLANK L
302050-1LCS L
METHOD BLANK J
302050-1LCS J
004 CLXTR
006 CLXTW
956-64
C-8
AIR PAH
SMA, 11-02-98
AIR
AIR
PAH
PAH
STRAIN PAH
956-64
C-8
STRAIN PAH
STRAIN PAH
STRAIN PAH
VSE-26
VSE-25
VSE-26
VSE-25
VSE-25
VSE-25
VSE-25
1
1
0.50
0.50
0.333
0.333
0.333
0.333
0.50
0.50
0.50
0.50
0.50
0.333
0.333
1 :
1
0.333
0.333
0.333
0.333
0.333
0.333
£23
-------
Peak Locate Examination: 2-NOV-1998:13:07 File:02NO98V4
Experiment:PAHAIR Function:! Reference:PFK
118.98012 118.99202 119.00392
Volts
7.8506
130.97892 130.99202 131.00512
Volts
0.1399
142.97772 142.99202 143.00632
168.97192 168.98882 169.00571
Volts
0.4824
Volts
0.0771
149.97542 149.99042 150.00542
154.97652 154.99202 155.00752
-------
Peak Locate Examination: 2-NOV-1998:13:10 File:02N098V4
Experiment:PAHAIR Function:2 Reference:PFK
o
Volts
0.0319
154.97652 154.99202 155.00752
Volts
1.0309
168.97192 168.98882 169.00571
Volts
3.6018
180.97072 180.98882 181.00691
Volts
0.1961
Volts
0.0719
192.96952 192.98882 193.00811
204.96832 204.98882 205.00931
-------
Peak Locate Examination: 2-NOV-1998:13:11 Pile:02NO98V4
Experiment:PAHAIR Function:3 Reference:PFK
PPM
200
Volts
0.2347
192.96952 192.98882 193.00811
Volts
0.0782
204.96832 204.98882 205.00931
218.96373 218.98563 219.00752
Volts
1.4257
Volts
0.6363
230.96253 230.98563 231.00872
242.96133 242.98563243.00992
254.96013 254.98563 255.01112
-------
Peak Locate Examination: 2-NOV-1998:13:12 File:02N098V4
Experiment:PAHAIR Function:4 Reference:PFK
242.96133 242.98563 243.00992
Volts
0.1733
254.96013 254.98563 255.01112
Volts
0.2177
268.95555 268.98245 269.00935
CO
u?
Volts
0.9680
Volts
0.4659
280.95435 280.98245 281.01055
292.95315 292.98245 293.01175
-------
02-NOV-1998 02:20:04 PM
Mass Spec : VG-4
GC Column : DB-5
265-04A.B,D,E,956-64
Hult.: 350
da-Naphthalene
Naphthalene
2-Hethylnaphthalene
d8-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
d10-Phenanthrene
Phenanthrene
Anthracene
- /•
d10-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
Dioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
CO
u?
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
2
1
0
1
0
0
1
1
1
2
0
0
1
1
1
1
.24
.23
.56
.21
.94
.74
.25
.42
.16
.81
.89
.80
.41
.11
.52
.21
S.D.
0
0
0
0
0
0
0
0
0
0
0
0
.289
.094
.084
.093
.045
.099
.177
.066
.191
.173
.063
.031
0.141
0
0
0
.174
.154
.269
XRSD
12
7
14
7
4
13
14
4
16
6
7
3
10
15
10
22
.900
.707
.909
.696
.773
.310
.178
.625
.420
.145
.028
.901
.009
.653
.160
.353
1
100.00
185.11
1.85
10.00
13.76
1.38
10.00
6.91
0.69
100.00
131.95
1.32
10.00
9.55
0.95
100.00
83.11
0.83
10.00
10.98
1.10
100.00
153.24
1.53
10.00
8.53
0.85
100.00
308.98
3.09
10.00
9.70
0.97
10.00
8.13
0.81
100.00
118.94
1.19
10.00
14.14
1.41
100.00
129.03
1.29
10.00
16.74
1.67
2
100.00
205.87
2.06
50.00
61.93
1.24
50.00
29.85
0.60
100.00
128.38
1.28
50.00
48.30
0.97
100.00
77.72
0.78
50.00
62.63
1.25
100.00
135.78
1.36
50.00
58.18
1.16
100.00
263.63
2.64
50.00
46.13
0.92
50.00
42.20
0.84
100.00
136.07
1.36
50.00
55.12
1.10
100.00
143.24
1.43
50.00
59.11
1.18
3
100.00
228.31
2.28
100.00
113.47
1.13
100.00
51.39
0.51
100.00
114.60
1.15
100.00
90.68
0.91
100.00
76.15
0.76
100.00
151.76
1.52
100.00
140.61
1.41
100.00
117.21
1.17
100.00
276.27
2.76
100.00
81.87
0.82
100.00
77.06
0.77
100.00
145.72
1.46
100.00
99.77
1.00
100.00
158.81
1.59
100.00
104.58
1.05
4
100.00
244.46
2.44
200.00
231.43
1.16
200.00
97.93
0.49
100.00
122.45
1.22
200.00
178.19
0.89
100.00
77.96
0.78
200.00
215.88
1.08
100.00
141.09
1.41
200.00
249.15
1.25
100.00
272.04
2.72
200.00
168.14
0.84
200.00
153.96
0.77
100.00
150.34
1.50
200.00
200.49
1.00
100.00
161.45
1.61
200.00
204.18
1.02
5 6
100.00
256.61
2.57
500.00
609.70
1.22
500.00
255.67
0.51
100.00
109.50
1.10
500.00
500.84
1.00
100.00
57.36
0.57
500.00
641.50
1.28
100.00
139.72
1.40
500.00
684.13
1.37
100.00
282.87
2.83
500.00
460.23
0.92
500.00
402.42
0.80
100.00
154.31
1.54
500.00
521.18
1.04
100.00
166.55
1.67
500.00
551.22
1.10
10
-------
02-MOV-1998 02:20:08 PM
Mass Spec : VG-4
GC Co I urn : DB-5
265-04A,B,D,E,956-64
Mult.: 350
Oioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)f luoranthene
Benzo( b) f I uoranthene
d12-Benzo(k)f luoranthene
Benzo( k ) f luoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
I ndeno( 1 23- cd)pyrene
d14-Dibenz(ah)anthracene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
.90
.20
.28
.08
.45
.17
.95
.16
.68
.64
.07
.63
.71
.44
.62
.25
S.D.
0.238
0.124
0.139
0.051
0.029
0.125
0.021
0.111
0.017
0.140
0.112
0.037
0.142
0.008
0.052
0.023
XRSD
26
10
10
4
6
10
2
9
2
8
10
5
8
1
8
9
.446
.269
.855
.716
.414
.717
.203
.525
.504
.557
.437
.829
.297
.722
.352
.286
1
100.00
68.20
0.68
10.00
11.85
1.18
100.00
109.94
1.10
10.00
10.44
1.04
100.00
41.05
0.41
10.00
12.56
1.26
100.00
91.66
0.92
10.00
12.71
1.27
100.00
65.24
0.65
10.00
18.05
1.80
10.00
11.71
1.17
100.00
64.89
0.65
10.00
16.93
1.69
100.00
44.86
0.45
10.00
5.85
0.59
100.00
20.73
0.21
2
100.00
70.96
0.71
50.00
64.84
1.30
100.00
119.85
1.20
50.00
56.47
1.13
100.00
45.84
0.46
50.00
61.73
1.23
100.00
94.95
0.95
50.00
63.16
1.26
100.00
66.86
0.67
50.00
89.03
1.78
50.00
60.46
1.21
100.00
58.55
0.59
50.00
98.08
1.96
100.00
44.54
0.45
50.00
35.13
0.70
100.00
24.39
0.24
3
100.00
127.65
1.28
100.00
102.61
1.03
100.00
127.65
1.28
100.00
102.61
1.03
100.00
49.22
0.49
100.00
95.82
0.96
100.00
96.52
0.97
100.00
119.14
1.19
100.00
69.56
0.70
100.00
157.16
1.57
100.00
102.44
1.02
100.00
68.21
0.68
100.00
162.24
1.62
100.00
44.08
0.44
100.00
60.26
0.60
100.00
25.35
0.25
4
100.00
89.95
0.90
200.00
234.26
1.17
100.00
136.79
1.37
200.00
215.75
1.08
100.00
45.10
0.45
200.00
228.66
1.14
100.00
94.09
0.94
200.00
210.18
1.05
100.00
67.87
0.68
200.00
302.58
1.51
200.00
200.46
1.00
100.00
62.00
0.62
200.00
324.02
1.62
100.00
43.39
0.43
200.00
127.89
0.64
100.00
26.10
0.26
5
100.00
93.26
0.93
500.00
671.78
1.34
100.00
145.35
1.45
500.00
571.04
1.14
100.00
45.72
0.46
500.00
622.27
1.24
100.00
96.82
0.97
500.00
522.11
1.04
100.00
68.82
0.69
500.00
767.23
1.53
500.00
476.32
0.95
100.00
61.45
0.61
500.00
835.41
1.67
100.00
45.40
0.45
500.00
287.53
0.58
100.00
26.33
0.26
a
10
-------
02-MOV-1998 02:20:12 PM
Mass Spec : VG-4
GC Column : DB-5
265-04A,B,D,E,956-64
Mult.: 350
D i benz(ah)anthracen«
d12-Benzo(ghi)peryl»ne
Benzo(ghi)perylene
Oioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.40
0.58
1.02
0
S.D.
0.077
0.022
0.091
0
%RSD
5.452
3.838
8.984
0
1
10.00
12.92
1.29
100.00
59.24
0.59
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8.58
0.86
0
2
50.00
69.25
1.38
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54.17
0.54
50.00
51.44
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3
100.00
143.15
1.43
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59.73
0.60
100.00
109.18
1.09
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200.00
281.33
1.41
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58.78
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211.25
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 13:13:33 GC E1+ Voltage SIR 70SE
Sample/fl Text:ST1102 :CS-3 :956-64 : : Exp:PAHAIR
128.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
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0 10:00 11:60 12:00 13:00 14:00 15:
410 SMO(1.3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-510 Acq: 2-NOV-1998 13:13:33 GC E1+ Voltage SIR 70SE
Sample*! Text:STll02 :CS-3 :956-64 : : ExprPAHAIR
152.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80:
60:
40:
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160.1128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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2.9E7
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14:00 14:12 14:24 14:36 14:48 15:6o
164.1410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02
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-------
FiIe:02N098V4 #1-641 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1102 :CS-3 .-956-64 :: Exp:PAHAIR
166.0798 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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172.0984 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:02NO98V4 #1-641 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1102 :CS-3 .-956-64 :: Exp:PAHAIR
178.0782 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-641 Acq: 2-NOV-199S 13:13:33 GC EI+ Voltage SIR 70SE
Sampled Text:ST1102 :CS-3 :956-64 :: Exp:PAHAIR
204.9888 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-938 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sampled! Text:ST1102 :CS-3 :956-64 : : Exp:PAHAIR
202.0782 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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212.1410 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-938 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Samplell Text:ST1102 :CS-3 :956-64 :: Exp:PAHAIR
228.0939 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-938 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sampled! Text:ST1102 :CS-3 :956-64 :: Exp:PAHAlR
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-------
File:02NO98V4 #1-759 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sample*! Text:ST1102 :CS-3 -.956-64 :: Exp:PAHAIR
A2.54E8
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-------
File:02NO98V4 #1-832 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1102 :CS-3 :956-64 : : Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 13:13:33 GC EH- Voltage SIR 70SE
Sample/Fl Text:ST1102 :CS-3 :956-64 : : ExptPAHAIR
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-------
File:02NO98V4 #1-878 Acq: 2-NOV-1998 13:13:33 GC EI+ Voltage SIR 70SE
Sampled! Text:ST1102 :CS-3 :956-64 :: Exp:PAHAIR
268.9824 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:02NO98V4 #1-510 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02N098V4 #1-510 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-510 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-640 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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FiIe:02N098V4 #1-640 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02N098V4 #1-640 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-938 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02N098V4 #1-938 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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FiU:02NO98V4 #1-938 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 14:02:30 GC EI+ Voltage SIR 70SE
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File:02NO98V4 #1-878 Acq: 2-NOV-1998 14:02:30 GC E1+ Voltage SIR 70SE
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QUANTERRA INCORPORATED
West Sacramento
Daily Standard Checklist
Dioxin/Furan High Res
STD ID <=~.~T \\p-3 _ Method ID 43Lft,A\V _ Column ID
Standard Solution CVS 4 — £<4 _ Prepared By _ <>(WA _
Instr ID \iC\-S
Analyzed By
Reviewed By CP irjLP- U
Date Analyzed
Date Reviewed
Standard, CPSM, and solvent blank present?
Prepared Date U-o"g.-cl
Copy of Instrument logfile present?
CPSM blow up and peak profile present?
Curve summary present?
Summary of 1613A criteria present?
Daily standard within method specified limits*?
Daily ion abundance ratios within limits?
A/A
CPSM valley < 25%?
/\/A-
CP^Twindow correct?
Samples analyzed within 12 hrs of daily standard?
COMMENTS:
f fJr S /IT.
-c, f~£
ftr
(. Lrl
9^t /\S\&
u
/f Jlr'n.1- ^ ,A
For NCASI 551, Control Limit (CL) = + /- 20% from curve RRFs for all analytes.
For Method 8290, CL = + /- 20% from curve RRFs for native analytes, CL = +/- 30% from curve RRFs for
labeled compounds.
For Method 1613A, see 3rd Revision to Method 1613 Performance Specifications, Table 7.
QA-231 gee 11
-------
D3-NOV-1998 05:27:38 PM
429AIR ConCal RESULTS
yiass Spec : VG-4
3C Column : DB-5
Data-file r-03N098V4 '
Height : 1
Name
did - 2 -Me thy Inaphthalene
d8-Naphthalene
Naphthalene
2 -MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
dl2-Benzo (a) anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
t3l2-Benzo (b) f luoranthene
Benzo(b)fluoranthene
d!2-Benzo(k) f luoranthene
Benzo(k) fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno (123 - cd) pyrene
Indeno(12 3 -cd)pyrene
-------
FILE SAMP LAB.
No. SAMP NO
(1)
CUSTOMER
CLEAN CLEAN
UP 1 UP 2
(SDS) (D2)
TYPE CONCn,
(1)
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
03N098V4
Q3N098V4
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
ST1103 CS-3 956-64
SB1103 Solvent Blank C-8
301802-1MB METHOD BLANK AIR
301802-1LC LCS
PAH VSE-26
1
1
0.50
0.50
SMA, 11-03-98
663
• T".
-------
Peak Locate Examination: 3-NOV-1998:10:36 File:03N098V4
Experiment:PAHAIR Function:! Reference:PFK
Volts
3.3291
118.98012118.99202 119.00392
Volts
4.8335
130.97892 130.99202 131.00512
142.97772 142.99202 143.00632
Volts
0.2829
149.97542 149.99042 150.00542
Volts
0.0288
154.97652 154.99202 155.00752
-------
UJ
10
Peak Locate Examination: 3-NOV-1998:10:38 File:03NO98V4
Experiment:PAHAIR Function:2 Reference:PFK
Volts
0.0397
154.97652 154.99202 155.00752
Volts
1.9342
168.97192 168.98882 169.00571
Volts
5.4631
180.97072 180.98882 181.00691
Volts
0.3011
i i*
i i*
192.96952 192.98882 193.00811
Volts
0.0840
204.96832204.98882 205.00931
-------
Peak Locate Examination: 3-NOV-1998:10:39 File:03NO98V4
Experiment:PAHAIR Function:3 Reference:PFK
PPM
200
Volts
0.4063
192.96952 192.98882 193.00811
Volts
0.1093
204.96832 204.98882 205.00931
Volts
0.7294
218.96373 218.98563 219.00752
PPM
200
Volts
2.0287
230.96253 230.98563 231.00872
254.96013 254.98563 255.01112
242.96133 242.98563 243.00992
-------
Peak Locate Examination: 3-NOV-1998:10:40 File:03NO98V4
Experiment:PAHAIR Function:4 Reference:PFK
242.96133 242.98563 243.00992
PPM
200
Volts
0.2070
254.96013 254.98563 255.01112
Volts
0.3131
268.95555 268.98245 269.00935
Volts
1.2473
280.95435 280.98245 281.01055
Volts
0.5279
292.95315 292.98245 293.01175
-------
02-NOV-199B 02:20:04 PM
Hast Spec : VG-4
QC Column : DB-5
265-04A.B.D.E,956-64
Mult.: 350
dS-Naphthalene
Naphthalene
2-Methylnaphthalene
dB-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
dIO-Fluoranthene
Ftuoranthene
dIO-Pyrene
Pyrene
Dloxln Furan CALIBRATION TABLE
filename t PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
2
1
0
1
0
0
1
1
1
2
0
0
1
1
1
1
.24
.23
.56
.21
.94
.74
.25
.42
.16
.81
.89
.80
.41
.11
.52
.21
S.D.
0.289
0.094
0.084
0.093
0.045
0.099
0.177
0.066
0.191
0.173
0.063
0.031
0.141
0.174
0.154
0.269
%RSD
12.
7.
14.
7.
4.
13.
14.
4.
16.
6.
7.
3.
10.
15.
10.
22.
900
707
909
,696
773
310
178
625
420
145
028
901
009
653
160
353
1
100.00
185.11
1.85
10.00
13.76
1.38
10.00
6.91
0.69
100.00
131.95
1.32
10.00
9.55
0.95
100.00
83.11
0.83
10.00
10.98
1.10
100.00
153.24
1.53
10.00
8.53
0.85
100.00
308.98
3.09
10.00
9.70
0.97
10.00
8.13
0.81
100.00
118.94
1.19
10.00
14.14
1.41
100.00
129.03
1.29
10.00
16.74
1.67
2
100.00
205.87
2.06
50.00
61.93
1.24
50.00
29.85
0.60
100.00
128.38
1.28
50.00
48.30
0.97
100.00
77.72
0.78
50.00
62.63
1.25
100.00
135.78
1.36
50.00
58.18
1.16
100.00
263.63
2.64
50.00
46.13
0.92
50.00
42.20
0.84
100.00
136.07
1.36
50.00
55.12
1.10
100.00
143.24
1.43
50.00
59.11
1.18
3
100.00
228.31
2.28
100.00
113.47
1.13
100.00
51.39
0.51
100.00
114.60
1.15
100.00
90.68
0.91
100.00
76.15
0.76
100.00
151.76
1.52
100.00
140.61
1.41
100.00
117.21
1.17
100.00
276.27
2.76
100.00
81.87
0.82
100.00
77.06
0.77
100.00
145.72
1.46
100.00
99.77
1.00
100.00
158.81
1.59
100.00
104.58
1.05
4
100.
244.
2.
200.
231.
1.
200.
97.
0.
100.
122.
1.
200.
178.
0.
100.
77.
0.
200.
215.
1.
100.
141.
1.
200.
249.
1.
100.
272.
2.
200.
168.
0.
200.
153.
0.
100.
150.
1.
200.
200.
1.
100.
161.
1.
200.
204.
1.
00
46
44
00
43
16
00
93
49
00
45
22
00
19
89
00
96
78
00
88
08
00
09
41
00
15
25
00
04
72
00
14
84
00
96
77
00
34
50
00
49
00
00
45
61
00
18
02
5
100.00
256.61
2.57
500.00
609.70
1.22
500.00
255.67
0.51
100.00
109.50
1.10
500.00
500.84
1.00
100.00
57.36
0.57
500.00
641.50
1.28
100.00
139.72
1.40
500.00
684.13
1.37
100.00
282.87
2.83
500.00
460.23
0.92
500.00
402.42
0.80
100.00
154.31
1.54
500.00
521.18
1.04
100.00
166.55
1.67
500.00
551.22
1.10
8
UP
10
-------
OZ-NOV-1998 02:20:08 PH
Mass Spec : VG-4
GC Column : DB-5
265-04A,B,D,E,956-64
Mult.: 350
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
dU-D i benz (ah) anth racene
Dioxin Furan CALIBRATION TABLE
File name : PAHAIR102998V4.RRF
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0
1
1
1
0
1
0
1
0
1
1
.90
.20
.28
.08
.45
.17
.95
.16
.68
.64
.07
0.63
1
0
0
0
.71
.44
.62
.25
S.D
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
XRSD
238
124
139
051
029
125
021
111
017
140
112
037
142
0.008
0.
0.
052
023
26
10
10
4
6
10
2
9
2
8
10
5
8
1
8
9
.446
.269
.855
.716
.414
.717
.203
.525
.504
.557
.437
.829
.297
.722
.352
.286
1
100.00
68.20
0.68
10.00
11.85
1.18
100.00
109.94
1.10
10.00
10.44
1.04
100.00
41.05
0.41
10.00
12.56
1.26
100.00
91.66
0.92
10.00
12.71
1.27
100.00
65.24
0.65
10.00
18.05
1.80
10.00
11.71
1.17
100.00
64.89
0.65
10.00
16.93
1.69
100.00
44.86
0.45
10.00
5.85
0.59
100.00
20.73
0.21
2
100.00
70.96
0.71
50.00
64.84
1.30
100.00
119.85
1.20
50.00
56.47
1.13
100.00
45.84
0.46
50.00
61.73
1.23
100.00
94.95
0.95
50.00
63.16
1.26
100.00
66.86
0.67
50.00
89.03
1.78
50.00
60.46
1.21
100.00
58.55
0.59
50.00
98.08
1.96
100.00
44.54
0.45
50.00
35.13
0.70
100.00
24.39
0.24
3
100.00
127.65
1.28
100.00
102.61
1.03
100.00
127.65
1.28
100.00
102.61
1.03
100.00
49.22
0.49
100.00
95.82
0.96
100.00
96.52
0.97
100.00
119.14
1.19
100.00
69.56
0.70
100.00
157.16
1.57
100.00
102.44
1.02
100.00
68.21
0.68
100.00
162.24
1.62
100.00
44.08
0.44
100.00
60.26
0.60
100.00
25.35
0.25
4
100.00
89.95
0.90
200.00
234.26
1.17
100.00
136.79
1.37
200.00
215.75
1.08
100.00
45.10
0.45
200.00
228.66
1.14
100.00
94.09
0.94
200.00
210.18
1.05
100.00
67.87
0.68
200.00
302.58
1.51
200.00
200.46
1.00
100.00
62.00
0.62
200.00
324.02
1.62
100.00
43.39
0.43
200.00
127.89
0.64
100.00
26.10
0.26
5 6
100.00
93.26
0.93
500.00
671.78
1.34
100.00
145.35
1.45
500.00
571.04
1.14
100.00
45.72
0.46
500.00
622.27
1.24
100.00
96.82
0.97
500.00
522.11
1.04
100.00
68.82
0.69
500.00
767.23
1.53
500.00
476.32
0.95
100.00
61.45
0.61
500.00
835.41
1.67
100.00
45.40
0.45
500.00
287.53
0.58
100.00
26.33
0.26
10
-------
02-NOV-1998 02:20:12 PM
Mass Spec : VG-4
GC Column : DB-5
265-04A,B,D,E,956-64
Mult.: 350
Dloxfn Furan CALIBRATION TABLE
File name : PAHA1R102998V4.RR F
Date analyzed : 29-OCT-98
INITIAL CALIBRATION CURVE
Dfbenz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.40
0.58
1.02
0
S.O.
0.077
0.022
0.091
0
XRSD
5.452
3.838
8.984
0
1
10.00
12.92
1.29
100.00
59.24
0.59
10.00
8.58
0.86
0
2
50.00
69.25
1.38
100.00
54.17
0.54
50.00
51.44
1.03
0
3
100
143
1
100
59
0
100
109
1
.00
.15
.43
.00
.73
.60
.00
.18
.09
0
4
200
281
1
100
58
0
200
211
1
.00
.33
.41
.00
.78
.59
.00
.25
.06
0
5
500.00
751.34
1.50
100.00
57.94
0.58
500.00
522.58
1.05
0
10
-------
FiIe:03NO98V4 #1-510 Acq: 3-NOV-1998 10:41:10 GC E1+ Voltage SIR 70SE
SamiHe#l Text:ST1103 :CS-3 :956-64 : : Exp:PAHAIR
128.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60:
40J
20-
I
0
9:
136.1
1002
80-
60-
40_
20-
6
9:(
AS.'
i
76E7
-
v^
0 ' ' 10:60 11:00 12:6o 13:6o 14:6o 15:1
128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
AS. E7
v^
0 10:6o 11:00 12:6o 13:6o 14:00 15:1
1.3E7
-1.0E7
-7.7E6
-5.1E6
-2.6E6
O.OEO
)0 Time
1.3E7
Ll.OE7
L7.6E6
:5.0E6
L2.5E6
O.OEO
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142.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 1
60^
4QJ
20 j
IJ
15ll
1003
80^
60^
40 J
20 1
0
?:C
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410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
> A3.5
E7
^
0 10:00 ll:6o ' 12:00 13:00 14:00 15:
7.3E6
L5.9E6
L4.4E6
12.9E6
Ll.5E6
O.OEO
)0 Time
8.2E6
:6.5E6
-4.9E6
-3.3E6
1.1.6E6
O.OEO
)0 Time
-------
FUe:03NO98V4 #1-510 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
SaihtUe/Pl Text:ST1103 :CS-3 :956-64 : : Exp:PAHAIR
152:0626 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.03E7
80 J
60 J
40:
20 J
0.
A1.63E7
14:00 14:12 14:24 14:36 14:48
16Q.U28 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
ICQ!)
801
60 J
40J
20
. i
6
I5:b6
,F,T)
15:24 15:36 15:48 16:00 16:12 16:24 16:36
A4.82E7
A1.43E7
v 1—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—r~>—i—i—i I i—i—i—i—i—I—i—'—•—i—i—i—r~
14:60 14:12 14:24 14:36 14:48 15:6o 15:12
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
10Q2.
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60J
49
201
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14:66 14:ii 14:24 14:36 14:48 15:00 IS-ii
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100 S>
80 J
60 J
40J
15:24 15:36 15:48 16:00 16:i2 16:24 16:36
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16:48 17:
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16:48
1.0E7
8.4E6
L6.3E6
:4.2E6
2.1E6
O.OEO
Time
1.3E7
L1.0E7
7.6E6
17:
_2.5E6
O.OEO
)0 Time
_6.9E6
L5.5E6
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1.4E6
16:48 17:
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7.9E6
16.4E6
4.8E6
L3.2E6
L1.6E6
14
:ii
15
:66
16:66 16-.H
16:48 17:00 Time
O.OEO
-------
FUe:03NO98V4 #1-510 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
Sampled Text:ST1103 :CS-3 :956-64 : : Exp:PAHAIR
ioos
95:
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85.;
t '
1
75 J
70 J
•4 '
65 1
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45 J
40 1
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30 J
i •
25 J
-1 J
15 J
10 1
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17.5E8
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File':03NO98V4 #1-640 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
Sample#l Text:ST1103 :CS-3 :956-64 : : Exp:PAHAIR
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File:03NO98V4 #1-640 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
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File:03NO98V4 #1-938 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
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F%Q3N098V4 #1-938 Acq: 3-NOV-1998 10:41:10 GC E1+ Voltage SIR 70SE
Sample#l Text:ST1103 :CS-3 :956-64 : : Exp:PAHAIR
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File:03NO98V4 #1-878 Acq: 3-NOV-1998 10:41:10 GC EI+ Voltage SIR 70SE
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File:63NO98V4 #1-509 Acq: 3-NOV-1998 11:30:10 GC EH- Voltage SIR 70SE
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File:03NO98V4 #1-509 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
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File:03NO98V4 #1-641 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
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File:03NO98V4 #1-641 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
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-6.2E3
1- ,
_4.2E3
L2.1E3
O.OEO
21:
0 Time
-------
FUe:03NO98V4 #1-641 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
204.9888 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95-
90 j
85 J
80 j
75 j
701
4 .
651
60-i
561
45
40
35
30
25
20
15
10
5.
9
17
A8.45E7
flt
:.75E7
\
J
A1.10E8
A1.42E8
A
A1.27E8
18:
.:60
19
:6o
20:
:6o
21:0
22
:00
O.OEO
23:00 Time
-------
File:Q3N098V4 #1-939 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
202.0782 S:2 F:3 SMO(1,3) PKD(5,3I3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 j
704
60 J
56 j
46J
20.
10 J
23:13
23:28
23:43
24:04
24:27
i24:39
24:54 25:10
25:27
25:41
26:07
26:29
26:4S
23:00 24:60
212.1410 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S,
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10J
..5.1E4
4.6E4
4.1E4
L3.6E4
L3.1E4
L2.6E4
L2.0E4
L1.5E4
L1.0E4
L5.1E3
LO.OEO
)0 Time
-1.7E4
L1.5E4
L1.4E4
L1JE4
L1.0E4
L8.5E3
L6.8E3
L5.1E3
L3.4E3
L1.7E3
LO.OEO
)0 Time
25:t
26:1)0
0
27:1
23:00 24:1)0
244.1974 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 9 p
90 J
70 J
60-
50-
40.
30_
20_
10-
0-
23:i
25:6o
A3.37E4
24:00
27:1
F5.6E4
L5.0E4
L4.5E4
L3.9E4
L3.4E4
L2.8E4
I.2.2E4
L1.7E4
L1.1E4
L5.6E3
LO.OEO
)0 Time
)0
25:i
26:
27:
-------
File:03NO98V4 #1-939 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sample#2 Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
228.0939 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
10Q%
26:00 ' 27:6o' ' 28:00
240.1692 S:2 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
2.2E4
E-2.0E4
1.8E4
1-1.5E4
H.3E4
-1.1E4
-8.8E3
-6.6E3
-4.4E3
_2.2E3
-O.OEO
H) Time
29:00
31
Time
-------
FU&Q3NO98V4 #1-939 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 -.Solvent Blank :C- Exp:PAHAIR
2301.9856 S:2 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
lop a.
JSJ , *
^IwW
^
80 J
i i
•"* 1
75-
i j
70 J
65 J
60 J
55 1
50-
45 J
46J
35 J
30.-;
25 J
20 J
lfM
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•H "i
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23 60
1.75E9
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24:60 25:6o ' 26:6o 27:00 28:6o 29:6o 30:6o ' 31:
6.7E8
6.4ES
6.0E8
L5.7E8
L5.4E8
5.0E8
L4.7E8
L4.4E8
L4.0E8
:3.7E8
L3.3E8
:3.0E8
12.7E8
1.2.3E8
2.0E8
-1.7E8
-1.3E8
Ll.OES
L6.7E7
-3.3E7
: O.OEO
>0 Time
-------
F!le:03NO98V4 #1-878 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
252.6939 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 j
1
80
70 J
60 J
5QJ
40 J
• 4
30
20 J
10 J
33:44
36:22
36:45
32:53
31:00 32:00 33:00 34:00
264.1692 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
35:C
36:4
37:
_1.7B4
1.6E4
1.4E4
1.2E4
1.0E4
L8.7E3
L7.0E3
L5.2E3
L3.5E3
-1.7E3
LO.OEO
>0 Time
M
00
03
31:00
O.OEO
!M> Time
-------
File:03NO98V4 #1-878 Acq: 3-NOV-1998 11:30:10 GC EI+ Voltage SIR 70SE
Sampled Text:SB1103 :Solvent Blank :C- Exp:PAHAIR
27&0939 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:00 38:00 39:00
288.1692 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
38:27
39:14 39:34
42:00 Time
37:00 38:00 39:6fl
278.1096 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
38:01
42:00 Time
38:30 38:55
38:45
37:00 38:00
292.1974 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.
100 2
37:00
O.OEO
)0 Time
-------
File:03NO9i
Sampled T
268.9824 S::
100 % A2.2.
70 J
1 J
Sftj
40J
3flJ
20 J
10 J
ft:
31:00'
280.9824 S:
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80 J
70 J
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60 J
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31:00
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L1.7E7
8.6E6
1 O.OEO
10 Time
r3.9E8
L3.5E8
L3.1E8
1.2.8E8
L2.4E8
L2.0E8
1.6E8
L1.2E8
L7.9E7
L3.9E7
LO.OEO
M> Time
en
-------
Sample Extraction/
Preparation Log Copies
695
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION ANALYSIS
CLIENT NAME: "foc/fc. £/w S/e,
PROJECT #:
DATE RECEIVED: JfT Q-25 DATE TO SUBBING: 10. g
LOCATION: ii.lMc^n W)7/^MATRTX:
INITIALS:
ANALYSIS: Ml^d
DATE IN PREP: IP.
PAGE
TAT:
I OF
4-
HOLD TIME UP ON:
OPS DUE DATE: |Q. |Q DUE DATE:
SAMPLE LD.'S EXTRACTION
SOXHLET ^jS/TRAINN
WW/EE DILUTION
\ _1U
1 ' \ SOLVENT QC 613
SEE BELOW
%H2O GRAMS VOLUME
%LIPIDS
QC
MB
LCS
DCS
DU
MS
SD
4
4
DILUTION
\ SPLIT ALIQUOT
ARCHIVE ALIQUOT*
,
NOCRS
OPTC V
\
FULL UPPER *
IFB IFB
]
SILICA
[GEL
D2 ACID /
AL* /
BASIC
AL*
/
Ing I RECOVERY STANDARD
2ng ?l"& I'J
2nRPCB KV.-fc»^n.UTlUW
o
k
UC-INTERNAL STD.
-k
\
1613 / 8290
TCDD/F
MET 23
MET 429
MET 428
MET 1668
DBD/F
AMT.(ng)
2.0/4.0
2.0
10.0
50.0
2.0/4.0
2.0
25.0
MATRIX SPEKE
CL4 (tetra)
CL5 - CL? (penta-hepta)
CLg(octa)
PCB
PAH
DBD/F
200 pg
1000 pg
2000 pg
2.0 ng
50.0 ng
25.0 ng
SAMPLE PRE-PREP
AS RECEIVED
DRY
GRIND
COMPOSITE
10ngM23
25ng DBD/I
SOnePAH
^^
A
^"^"^^N
X
^
^ \
1
i
/
/.
GC COLUMN
DB-5
DB-225
*
If needed
Factor
l^
Factor
)
V
;
3V
COMMENTS:
( wyyyvT^-*'^ cO~ *
o(^S ;*&,
^ \ QA-361-MF fil/97
,\v^x 7
-------
Quanterr-2 tnvironmental Services, Sacramento -
880 Riverside Parkway
West Sacramento, California 95605
(916) 373-5600
CALLAB-301802
Date Received
: 29 SEP 98 15:30
Mr. R9n Kolde
Pacific Environmental Services -
4700 Duke Drive
Suite 150
Mason, Ohio
45040
(513) 398-2556 Fax: (513) 398-3342
Project ID,
EPA Case, RMA Lot : Project 5505.000
AIR-Carb429 092998
P.O. Number : CLC-950302
Delivered By :
Storage Location : W14C,D,W17A
Logged in by : CHYTREK
Airtrain(14) samples received in good condition under Chain-of-Custody
Delivered OTC.
Sample ID Client's label info
301802-0001-MB Method Blank
301802-0001-SA A-I-429-1
301802-0002-SA A-I-429-2
301802-0003-SA A-I-429-3
301802-0004-SA A-0-429-1
301802-0005-SA A-0-429-2
301802-0006-SA A-0-429-3
301802-0007-SA A-U-429-1
301802-0008-SA A-U-429-2
301802-0009-SA A-U-429-3
301802-0010-SA A-U-429-4
301802-0011-SA A-I-429-FB
301802-0012-SA A-0-429-FB
301802-0013-SA A-U-429-FB
301802-0014-SA A-429-LB
Date/Time Samp. Containers
Method Blank
21 SEP 98 2-AGJ 500AGJ 2-250A6J PETRI XA
22 SEP 98 AGJ 2-500AGJ 2-250AGJ PETRI XA
23 SEP 98 3-500AGJ 2-250AGJ PETRI XAD
21 SEP 98 AGJ 2-500AGJ 2-250AGJ PETRI XA
22 SEP 98 AGJ 2-500AGJ 2-250AGJ PETRI XA
23 SEP 98 3-500AGJ 2-250AGJ PETRI XAD
24 SEP 98 AGJ 3-500AGJ 250AGJ PETRI XAD
24 SEP 98 AGJ 3-500AGJ 250AGJ 2-PETRI XA
25 SEP 98 AGJ 2-500AGJ 2-250AGJ PETRI XA
25 SEP 98 AGJ 2-500AGJ 2-250AGJ PETRI XA
24 SEP 98 3-500AGJ 2-250AGJ PETRI XAD
24 SEP 98 3-500AGJ 2-250AGJ PETRI XAD
25 SEP 98 500AGJ 4-250AGJ PETRI XAD
21 SEP 98 4-125AGJ PETRI XAD
Samples not destroyed in testing are retained a maximum
of thirty (30) days unless otherwise requested.
Project Manager: Robert Weidenfeld
-------
. . ** NOT LOG RELEASED! **
QUANTERRA-CALLAB LABORATORY
Chromatography Assignment Sheet
Project #: 301802 Due Date: 27 OCT 98
Analysis: P-PAH-HR-AIR Ver: 1 Receipt Date: 29 SEP 98
Client: Pacific Environmental Services Log Released:
PA: RWEIDENFELD Turnaround: NORMAL
Delivery Accepted: MGARCIA 29 SEP 98 Storage Location: W14C,D,W17A
Number of Samples: 15 Earliest Holding Time: 12 OCT 98
Program: General Airtox
Project Description:
14 airtrain samples CARB 429.
All fractions are to be combined for a single analysis per train.
For SA #14, the XAD trap was pulled from the pile of traps
that were returned.
Test Modified: N
Sample Instructions: N
Test Instructions: N
Group Instructions: N
QAS #:
Date Delivered to PA:
Comments:
_ No/Problems Occurred with Analysis
v See Anomaly Sheet
h
cje -ecn
638
-------
V<>^C^"^^'^**NTERRA'CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 301802 Date: 03 OCT 98 Page 1 of 2
Test Code: P-PAH-HR-AIR Test Description: Prep - Potynuclear Aromatic Hydrocarbons by HRHS
Turnaround Status: NORMAL Sample Matrix: AIRTRAIN Date Assigned: Prep Completion Due:
SOP-Section/Page (Revision): .
Extractions: [ ] Separatory Funnel [ ] Continuous Liquid/Liquid t ] Sonicationl 16 sfexhlet [ ] KD
[ ] Roto Vap [ ] Shaker C ] Other
Samp
ID
0001 SA
0001MB
0002SA
0003SA
0004SA
0005 SA
0006SA
0007SA
0008SA
0009SA
001 OSA
001 1SA
0012SA
0013SA
Holding
Time
12 OCT 98
20 OCT 98
13 OCT 98
14 OCT 98
12 OCT 98
13 OCT 98
14 OCT 98
15 OCT 98
15 OCT 98
16 OCT 98
16 OCT 98
15 OCT 98
15 OCT 98
16 OCT 98
Sample
Size
>-
\
Extractn
Date/
Initials
*•)•»/<«
Adj pH
Date/
Initials
MA
Hydrolysis
Date/
Initials
PA
i —
Acid Ext
Date/
Initials
PA-
^
Cone
Date/
Initials
jo ToflSji
^
CH2N2
Date/
Initials
UA
i
N2
Date/
Initials
100
S
7
1
Final
Sample
Concentn
'IsAfr}
fe«
Project Due: 27 OCT 98
Method Blank With Project:,
DCS With Project;
LCS With Project:
DCS Code;
LCS Code:
Notes/Comments:
** PLEASE PUT COMMENTS ON ANOMALY SHEET **
Extraction Includes Project(s):
MSOC with Project: MSQC Code:
Date To Instruments:
By:.
Peer Approval By:_
693
-------
QUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 301802 Date: 03 OCT 98 Page 2 of 2
Test Code: P-PAH-HR-AIR Test Description: Prep • Polynuclear Aromatic Hydrocarbons by HRMS
Turnaround Status: NORMAL Sample Matrix: AIRTRAIN Date Assigned: Prep Completion Due:
SOP-Section/Page (Revision):
Extractions: [ ] Separatory Funnel [ ] Continuous Liquid/Liquid [ ] Sonication [fV $oxhlet t 1 KD
[ ] Roto Vap [ ] Shaker [ ] other
Samp
ID
OOUSA
ffl
u& I
fff^T
Holding
Time
12 OCT 98
rtte
,/g^y
1
Sample
Size
*
\
Extractn
Date/
Initials
"'v*
Adj pH
Date/
Initials
KiAr
> r
Hydrolysis
Date/
Initials
D/V
Acid Ext
Date/
Initials
tOA
-1 f
Cone
Date/
Initials
10^
«* j
CH2N2
Date/
Initials
P*
> ^
N2
Date/
Initials
''W
1
•V
Ffnal
Sample
t^**
^
> |
JL
^
Project Due: 27 OCT 98
Method Blank With Project:.
DCS With Project; *3cM
LCS With Project:
DCS Code:
LCS Code:
Notes/Comments:
** PLEASE PUT COMMENTS ON ANOMALY SHEET **
Extraction Includes Project(s):
MSQC with Project: MSOC Code:
Date To Instruments:.
By:
Peer Approval By:.
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project I: 301802 Test: P-PAH-HR-AIR
Quality Assurance/Quality Control:
Sample ID; pfo ^>V Spiking Standard Name; V./MV $r*vfoyi.4g.
Spike Code ID;
Spiked By;
Volume: loo.J?
Witness:
Sample ID; A,i
Spike Code ID:
Spiked By.^^L
Sample ID;
Spike Code Ip
Spiked By:
Sample ID:
Spike Code ID:
Spiked By:
Spiking Standard Name:
Volume: ioovj? Cone:
Witness:
Spiking Standard Name; Vbti UftlW
Volume: ^DOs.J Cone:
Witness:
Spiking Standard Name:_
Volume: Cone:
Witness:
Final Solvent:
Other:
Solvent: Manufacturer And Lot Number:
Extracting Solvent: H^CL H
Solvent Keeper:
Transfer Solvent:
t:
agent:
i
VUCU MKttDC
mv
Was an aliquot taken?(Jt^ N
If yes, how much was aliquoted? fojS/V mL
What was the sample concentration before aliquot?
mL
/(Orr>l
Why was the aliquot taken?
701
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project f: 301802 Test: P-PAH-HR-AIR
Anomalies: Sample(s) Affected:
Sample broken during shipping.
Limited sample volume.
Matrix required a subsample to facilitate extraction.
pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
Emulsion problems.
_ Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
_ Concentration volume went lower than specified in the
SOP.
_ Concentration time longer than normal.
_ Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
_ Final concentration greater than specified in the SOP
due to ^he screening results.
_ Precipitate observed in the extract.
_L/xOther, please comment below. \-
Comments: \kL>«otf Q-% cl' <"*»*&** / \r^f^u,r O6wW,cf s
Submitted By; r\>/ckyvusug < Date; /s - fc
^_^
702
-------
QUANTERRA-CALLAB LABORATORY
Prep (Extraction) Check List
Project #: 301802 Test: P-PAH-HR-AIR
Chemist: T^\£^Yi^sC-<^>^^ Date:
Reviewer: Date:
Number of samples: ^5 Number of extracts:
x
Benchsheet;
SOP section and page number filled out properly.
Each step of extraction procedure initial'ed and dated,
Anomalies or deviations from SOP documented.
pH adjustments noted.
Solvent manufacturer and lot number completed.
Volumes and weights of samples to two sig. figs.
QA/QC;
DCS/MS forms filled out properly.
Spike information correct on bench sheet.
Spike witness?
If not spiked per SOP, were spike amounts verified?
Extraction date (complete date) correct.
QC lot number present and correct.
QC Run number present and correct.
Prep released (date extract goes to Inst.).
Extracts;
Number of extracts agree with benchsheet.
Concentrations of extract agree with benchsheet,
Testtube rack labelled with project id and test.
Initiated
Reviewed
Y N
Y N
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Comments:
703
-------
** NOT LOG RELEASED! **
QUANTERRA-CALLAB LABORATORY
Chromatography Assignment Sheet
Project #: 301802 Due Date: 27 OCT 98
Analysis: P-PAH-HR-AIR Ver: 1 Receipt Date: 29 SEP 98
Client: Pacific Environmental Services Log Released:
PA: RWEIDENFELD Turnaround: NORMAL
Delivery Accepted: MGARCIA 29 SEP 98 Storage Location: W14C,D,W17A
Number of Samples: 15 Earliest Holding Time: 12 OCT 98
Program: General Airtox
Project Description:
14 airtrain samples CARB 429.
All fractions are to be combined for a single analysis per train.
For SA #14, the XAD trap was pulled from the pile of traps
that were returned.
Test Modified: N
Sample Instructions: N
Test Instructions: N
Group Instructions: N
QAS f:
Date Delivered to PA:
Comments:
No Problems Occurred with Analysis
Anomaly Sheet
704
-------
QUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 301802 Date: 04 OCT 98 P«9« 1 of 2
Test Code: P-PAH-HR-AIR Test Description: Prep • Polynuclear Aromatic Hydrocarbons by HRHS
Turnaround Status: NORMAL Sample Matrix: AIRTRAIN Date Assigned: Prep Completion Due:
SOP-Section/Page (Revision):_ .
Extractions: Q^^bparatory Funnel [ ] Continuous Liquid/Liquid I ] Sonication [ ] Soxhlet [ 1 KD
[ 3 Roto Vap t ] Shaker [ ] Other
Samp
ID
0001 SA
0001MB
0002SA
0003SA
0004SA
0005SA
0006SA
0007SA
0008SA
0009SA
001 OSA
001 1SA
0012SA
0013SA
Holding
Time
12 OCT 98
20 OCT 98
13 OCT 98
14 OCT 98
12 OCT 98
13 OCT 98
14 OCT 98
15 OCT 98
15 OCT 98
16 OCT 98
16 OCT 98
15 OCT 98
15 OCT 98
16 OCT 98
Sample
Size
*
/
1
Extractn
Date/
Initials
WK
Adj pH
Date/
Initials
PA-
1
Hydrolysis
Date/
Initials
Wr
Acid Ext
Date/
Initials
U+r
^
Cone
Date/
Initials
|CW
CH2N2
Date/
Initials
w
N2
Date/
Initials
)*«*
506
V
Final
Sample
Concentn
ij-> » in S
Project Due: 27 OCT 98
Method Blank With Project:
DCS With Project:
LCS With Project:
DCS Code;
LCS Code:
- i/ IS
Notes/Comments:
** PLEASE PUT COMMENTS ON ANOMALY SHEET **
Extraction Includes Project(s):
*
MSQC with Project: MSQC Code:
Date To Instruments:
By:.
Peer Approval By:_
70:
-------
QUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 301802 Date: 04 OCT 98 Page 2 of 2
Test Code: P-PAH-HR-AIR Test Description: Prep • Polynuclear Aromatic Hydrocarbons by HRMS
Turnaround Status: NORMAL Sample Matrix: AIRTRA1M Date Assigned: Prep Completion Due:
SOP-Section/Page (Revision):
Extractions: Preparatory Funnel ( ] Continuous Liquid/Liquid [ ] Sonication [ ] Soxhlet [ J KD
[ ] Roto Vap t 3 Shaker [ ] Other
Samp
ID
OOUSA
JK>
Holding
Time
12 OCT 98
Sample
Size
1
J
Extractn
Date/
Initials
I00MM
J
Adj pH
Date/
Initials
pfr
\
Hydrolysis
Date/
Initials
RLV
1
Acid Ext
Date/
Initials
P/w
^
Cone
Date/
Initials
jootot;
4
CH2N2
Date/
Initials
pAr
I
N2
Date/
Initials
Ps/
^
Final
Sample
Concentn
Qfiecktr*.
,
Project Due: 27 OCT 98
Method Blank With Project:.
DCS With Project;
LCS With Project:
DCS Code; C40CTGfe- k
LCS Code:
Extraction Includes Project(s):
Notes/Comments: . ,
** PLEASE PUT COMMENTS ON ANOMALY SHEET ** MSOC with Project:
MSQC Code:
706
Date To Instruments:.
By:.
Peer Approval By:_
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project I:
Test:
Quality Assurance/Quality Control:
Sample ID: {\LL
Spike Code ID:
Spiked
Sample ID:
Spike Code ID; Qsw-
Spiked By:.
Sample ID:
Spike Code ID:.
Spiked By:
Sample ID:
Spike Code ID:
Spiked By:
Spiking Standard Name;
Volume: lono Cone:
Witness;
'?C~1
M r».»
Spiking Standard Name:
Volume: "SoojJi Cone:
W1 tness ;
424
O.
/ .t
Spiking Standard Name:
Volume: Cone:
Witness:
Sptk4nq Standard Name:
Volume: /\- Cone:
Witness:
Solvent: Manufacturer And Lot Number:
Extracting Solvent; V\.»CU H VCt"5o C*
Solvent Keeper:.
Transfer Solvent:
Derivatizing R
Final Solvent:
Other:
•
•
nt:
eager
it:
i
r
Was an aliquot taken? Y
If yes, how much was all quoted? mL
What was the sample concentration before aliquot?.
ut
-\\,
mL
Why was the aliquot taken?
707
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project I: 301802 Test: P-PAH-HR-AIR
Anomalies: Sample(s) Affected:
Sample broken during shipping.
__ Limited sample volume.
Matrix required a subsample to facilitate extraction.
_ pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
Emulsion problems.
Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
_ Concentration volume went lower than specified in the
SOP.
_ Concentration time longer than normal.
_ Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
_ Final concentration greater than specified in the SOP
due to the screening results.
_ Precipitate observed in the extract.
^ Other, please comment below.
Comments :
Submitted Bv; V M/UvUSMr — Date:
-------
1
\
2
a
lo
u
fe
B
^05
CM
115
life
127
i a
go
(28
21
105
Con
I2Z.
Keel,
709
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION PREP
Methods 23, 428, 429,1668, and T-OIX
BENCHSHEETFOR EXTRACTION OF AIR MEDIA
PROJECT*: S«\fcpT-
ANALYSIS: ^CJl
MATRTX:
DATE RECEIVED:
\
TAT:
DATE IN PREP:
GCMS LOCATION:
EXTRACTION TYPE^
SOLVENT TYPE: (*
SAMPLE ID
Iwvfc
\\J&>
iRfc
1
1
3
i|
^
6
/)
^
Sample Size
^t
^S^XHLET^-
^^^^l
TOLUENE y
-^
613
Date'Int
? (^^D5
DUE DATE: /O/W Date: 16* 25^o
Associated Pi
•oiects: A^TV-*^
j / "r
Yes (describe) .-.
Yes (describe) ^-r^n
QA-236-MF 11/97
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION PREP
Methods 23,428,429,1668, and T-O IX
BENCHSHEET FOR EXTRACTION OF AIR MEDIA
ANALYSIS:.
ff
DATERECEIV
EXTRACTION TYPE.\
SOLVENT TYPE: >
SAMPLE ID
°l
(D
i\
Vt,
.5
lt
Sample Size
,
MATRIX
rED:
GCMS LOCA'
foxHL^
^1^^^
613
Date/Int
k.\«!TaA\*j
TAT:
D ATE TN PREP:
CON:
DUE DATE: I°l5dh^
DATE TO GCMS:
(^6l5)\
DILUTION OTHER:
\^=XA5^\ DCM OTHER:
^< ,
Soxhlet
DatalnL
/
Silica Gel
Date/InL
Vts^ja
^
/
(All Samples) H i ~\
I.S. Added: Cj? 6 CS%fi^X*JLO bv:
(LCS/MS/SD)
PAR/Nat Added: 1 bv:
(MB Only) J *
Surrogate Added: v bv:
(AU Samples) «,
RS. Added: 5/
Dilution @ Extraction? No
Split of Extract? No
Dilution @ Final Volume? No
Upper IFB
Datflnt
Lower IFB
Datt'Int.
IFB
Date/Int.
Special D2
Dait'Int.
Witness: Date:
Witness: Date:
Witness: Date:
&014 Witness: lH/C* Date: 7^-23'
Associated Pi
rejects: TSOO^«^^'
Yes (describe)
Yes (describe) -«.
YS) 1:5 Cs do C= Cu
QA-236-MF 11/5
-------
Page \ o
Quanterra - Sacramento
Data Checklist
High Resolution Analyses
Services
CAL ID:
Method ID: -J>/»NJ5
Data Analyst:.
Date initiated:.
Reviewer:.
Date reviewed:
DB-225
QA/OC verification:
-Daily standard package(s) present?
-Method Blank present?
-LCS copy present?
-Internal standard recoveries
within limits?*
-Ion ratios within ± 15% of
theoretical values?
inat
DB-5
DB-5
DB-5^
DB-5
DB-5
Ininated
225
"225
225
Re viewed
-Other QC (Dup,MS,SD) within specs?** DB-5.
Sample Analysis:
-Correct sample aliquot used?
-All raw data present?
-Standard £«sei-8t.'s used? (If not
specify oelow.)^'
-DL's below ta£3si-4«tScTion limit1
-All positives reported at levels
greater than method blank DL's?
-Any analytes saturated?
-Correct RRF's used for method?
-Internal standard amounts correct
for method?
-Dilution/splitting of extract taken
into account?
-Acquisition date/time correct?
-Manual integrations checked?
.225.
225
225.
Initiated
Reviewed?
DB-5 w
DB-5 v/
f 225
' 225
DB-5
DB-5
JJB-5
DB-5^
DB-5
DB-5
DB-5_
DB-5.
DB-5
DB-5"
DB-5
225
y
225
225"
.225.
.225.
225
"225"
225
Recovery 1imits:
NCASI 551:
Method 8290
Method 1613
Method 23:
CARB 428:
CARB 429
PCBs:
non
(20-39% OK if S/N-10:1 for IS)
40-120%
40-135%
25-150%
40-130%(C14-C16), 25-130%(C17-8). 70-130%(sunv
40-120% (out of limits OK if S/N-10:1 for IS)
50-150%
25-150%
RPD limits:
50%
20%
50%
50%
50%
50%
.71^ 50%
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-002b
4. TITLE AND SUBTITLE
Final Report - Emissions Testing of Coml
Battery No. 5/6 at ABC Coke in Birmingi
Volume II of III
2.
justion Stack and Pushing Operations at Coke
lam, Alabama
7. AUTHOR(S)
Franklin Meadows
Daniel F. Scheffel
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENTS ACCESSION NO.
5. REPORT DATE
February 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98-004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating the coke making industry to characterize hazardous air pollutants (HAPs)
emitted from coke pushing operations and combustion (underfire) stacks. This test report addresses pushing emissions from a coke oven, and emissions
from the combustion (underfire) stack that serves Coke Battery No. 5/6 at ABC Coke in Birmingham, Alabama. The purpose of this test program was to
quantify emissions from the inlet and outlet of the baghouse controlling emissions from the coke pushing operation and to quantify emissions from the
combustion outlet stack. The data may be used by the EPA in the future to support a residual risk assessment for coke oven facilities.
The testing was performed to quantify uncontrolled and controlled air emissions of filterable paniculate matter (PM), methylene chloride extractable
matter (MCEM) and 19 poly cyclic aromatic hydrocarbons (PAHs) including acenaphthene, acenaphthylene, anthracene, benzo(a)anthracene,
benzo(a)pyrene, benzo(b)fluoranthene, benzo(e)pyrene, benzo(k)fluoranthene, benzo(ghi)perylene, chrysene, dibenzo(a,h)anthracene, fluoranthene,
fluorene, indeno(l,2,3-cd)pyrene, 2-methylnapthalene, napthalene, perylene, phenanthrene, and pyrene. In addition, following the PM and MCEM
analyses, the samples were analyzed to screen for the presence of 17 trace metals. Baghouse dust samples were also collected and analyzed for 16 trace
metals. Simultaneous testing was performed at the inlet and outlet of the baghouse controlling emissions from the coke pushing operation. Sampling
was also performed on the combustion outlet stack. In addition to pollutant testing, oxygen (OJ and carbon dioxide (CO2) were measured at each
location. During the sampling program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission
control system operating parameters.
This volume (Volume II) is comprised of 726 pages and consists of Appendix C (Analytical Data -CARB 429).
17.
a. DESCRIPTIONS
Baghouse
Coke Ovens
Emission Measurements
Hazardous Air Pollutants
Metals
Methylene Chloride Extractable
Matter
Particulate Matter
Polycyclic Aromatic Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
1647
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.FnD\WP 6.1
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