COMPLIANCE EVALUATION PROCEDURE




   FOR STATIONARY SOURCES




    0 OHIO AND  ILLINOIS  °
  fi£ ] PEDCo ENVIRONMENTAL

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                  PEDCo-ENVIRONMENTAL.
                       SUITE 13 •  ATKINSON SQUARE
                            CINCINNATI. OHIO 4-524-6
                                      513/77 1-433O
     COMPLIANCE EVALUATION PROCEDURE

        FOR STATIONARY SOURCES

         ° OHIO AND ILLINOIS °
      Contract Number 68-02-1375
         Task Order Number 11
              Prepared by

 PEDCo-Environmental Specialists, Inc.
       Suite 13, Atkinson Square
        Cincinnati, Ohio 45246
   EPA Project Officer: Lance Vinson
             Prepared for

U.S. ENVIRONMENTAL PROTECTION AGENCY
             Region V
           Enforcement Division
       Chicago, Illinois 60606

            August, 1974

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                      TABLE OF CONTENTS


                                                  Page

1.0  INTRODUCTION                                   1

2.0  PROCEDURE                                      2

     2.1  Master Source List                        2

     2.2  Check for Adequacy of Information         2

     2.3  Compliance Status Determination           3

          2.3.1  Flow Diagram                       3
          2.3.2  Determination of Actual Emission   4
                 Rate
          2.3.3  Determination of Allowable         6
                 Emission Rate
          2.3.4  Compliance - Noncompliance         7
                 Alternatives

REFERENCES AND FOOTNOTES                           10


APPENDIX A - PROJECT FORMS

APPENDIX B - OHIO AND ILLINOIS REGULATIONS

APPENDIX C - AIR ENFORCEMENT CHECKLIST

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                         1.0  INTRODUCTION








     The purpose of this report is to ensure that uniformity



is maintained in the evaluation of the compliance status



of selected Ohio and Illinois stationary sources.  The pro-




cedure for determining the compliance status for these



facilities is described in detail in the following sections.



These sections are to be followed sequentially for each



group of facility files which is processed.

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                       2.0  PROCEDURE






2.1  MASTER SOURCE LIST



     Initially, each facility to be studied is assigned a



sequential number (1,2,3...) and then entered on a master



listing (see Form No. 1, Appendix A).  Note that the columns



to the right of the name designate progressive milestones in



the compliance assessment process.  The pertinent dates of



these milestones are to be entered as they occur, to allow




for a current, individual and overall accounting of the



sources.



2.2  CHECK FOR ADEQUACY OF INFORMATION



     The available information for each source, from EPA




form 158-R75 and other pertinent references, is next



assessed for adequacy in determining the compliance status



(all source information must be checked prior to actual



compliance status determination) for each emission point



of the facility.  This preliminary information check reduces



the time necessary for the acquisition of additional



information.  The missing information is then delineated



(see Form No. 2, Appendix A) for subsequent data acquisition




if such is required from a facility.



     Although not all of the data required by EPA form




158-R75 is necessary for compliance status determination,

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all missing information should be requested in order to


establish a complete information bank on each source.  The


completed Form No. 2 for each facility examined is submitted


to EPA and can be included with a letter requesting the


required information from the source.  Once completed, Form


No. 2 is then placed in the specific facility file.



     As the requests for additional  information are made, each


facility file is categorized as either:  (1) adequate  for


partial or. complete compliance'status determination  (some


or all emission points can be accurately assessed without


additional information); or  (2) inadequate for even partial


compliance determination.  It follows that category 2 sources


become category 1 sources upon receipt of the necessary infor-


mation.


2.3  COMPLIANCE STATUS DETERMINATION


     The determination of the compliance status of an


individual facility encompasses a series of related actions.


All pertinent source-related information plus available or


calculated data must be summarized and tabulated (see Form


No. 3, Appendix A).  Additionally, all work documents


relative to a specific facility must be retained in the


facility file folder.



2.3.1  Flow Diagram


     The first step in completing the compliance status


evaluation is the preparation of a block flow diagram which
                                     o

illustrates all the processes and emission.points at  the

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facility.  Low contrast graph paper is best suited for this

flow diagram, since it allows for quick free-hand drawing.

Control devices are shown as follows:
Settling
 Chamber
             Cyclone
Fabric
Filter
           Electrostatic
Scrubber   Precipitator
                                                              Other
     All sources are identified using the source code of EPA

form 158-R75.  All emission points are identified by a number

assigned by the person conducting the compliance check so

that each source-emission point I.p. is a unique number.  An

example flow diagram is shown in Figure 1.

2.3.2  Determination of Actual Emission Rate

     The "Estimate of Pollutant Emissions" portion of Section
                                   $
VI of EPA Form 158-R75 (see Appendix A) is intended to reflect

the specific emission data for each source by pollutant type

and rate (Ibs/hr and tons/yr).  The basis for estimation of

the pollutant and emission rates in this section are to be

indicated (footnote e) by the facility; however, in some cases

the basis for estimation won't be indicated.  Regardless, the

pollutants and emission rates given should be checked for

credibility  (even if the results are from stack tests) by con-

                                         1                  2
suiting such references as EPA Pub. AP-42  or EPA Pub. AP-40 .

These references contain pollutant emission factors and typical

control efficiencies for a wide variety of sources and control

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* Note - use of low contrast graph paper,
   Figure 1.  EXAMPLE PROCESS FLOW SHEET

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 devices.   The  calculated emission  rate with  its  pertinent  emis-



 sion factor references  (e.g.,  AP-42)  and  calculations  should be



 entered in the space indicated on  Form No.  3.   If  the  calculated



 emission rate  differs significantly  from  the rate  given on the



 form,  this emission source should  be earmarked by  appropriate



 comments on Form No. 3  to insure that this difference  is



 investigated during subsequent plant contact and/or  visit.



      If the emission rate is  not given by the plant, estimate



 the emissions  by using  AP-42  ,  material balance calculations,



 or  use of similar process data.



      Both senior EPA R/0 staff and PEDCo  engineers experienced



 in  a variety of process operations should be utilized  to advise



 on  situations  where the above references .are not adequate  for



 a clear-cut decision.   In all cases,  working calculations



 must be performed neatly so that they can be checked.   All



 work sheets must be saved and included in the facility file.



 2.3.3   Determination of Allowable  Emission Rates



      Allowable emission rates are  determined by  applying the



 pertinent air  pollution control regulation of Ohio or  Illinois.



 The sections of these regulations  required for assessing



 compliance status are contained in Appendix  B.   Calculations



 and citation of the applicable regulation should be  entered



 in  the space as indicated on  Form  No. 3.  Either knowledgeable



 EPA R/0 or State personnel will be contacted to  clarify any



^interpretation of the regulation which proves necessary.   A



 consistent interpretation of  regulations  is  most important



 when the regulation is  not clear.

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     Application of the opacity regulation for compliance



determination cannot of course be accomplished without on-site



observation during plant inspection.  When it is suspected that



the opacity of a specific exhaust exceeds the applicable regu-



lation,  that emission source should be designated for further


             4
investigation  by appropriate comment on Form No. 3.




2.3.4  Compliance - Noncompliance Alternatives



     An emission source is presumed to be in compliance if



its allowable emission rate and exhaust opacity exceed its



actual emission rate and actual opacity, respectively.  Con-



versely, when the actual emission rate and opacity exceed the



allowable, the source is out of compliance.



     If a facility has all its sources in compliance (no



suspected opacity violations)  it's Compliance Status Summary



Form plus the entire facility information file are submitted



to the Project Officer (EPA)  or Project Manager (PEDCo)  for



review.  Facilities with one or more emission sources which



comply quantitatively, but are suspected of opacity vio-



lation > are to be submitted apart from totally complying



facilities so that investigation can proceed without delay.



2.3.4.1  Noncomplying Facilities - Preparation of Air



Enforcement Checklist - An Air Enforcement Checklist (see



Appendix C) is filled out for each facility with one or more



emission sources not. in compliance.   A cover sheet is



prepared for each of these companies.   The information con-



tained on this sheet includes sources in compliance,



sources out of compliance, and any additional comments.



Example information entered on the AEC is as follows:

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     Part I, Section II, A - The applicable regulations are




listed here.



     Parti, Section III - Total existing emissions from all



sources out,of compliance and total emissions from these sources



after compliance  is achieved are entered here.



     Part II, Section  I - The specific  source within the plant



is  identified.  Part II and Part III are filled out for every




source that is out of  compliance within the cited facility.



     Part II, Section  II - The requirements violated by the



source are entered here.



     Part II, Section  III, A - The annual emissions are entered



here, both without controls and with existing controls.  If



there are no controls, "No Controls" will be entered.  The



allowed emissions will be entered, based on the required control



efficiency.



     Part III, Section I, A - The type of control necessary



to  bring the source into compliance is shown here.  Selection




of this device is made by consulting AP-42,  AP-40, etc.,  and



by calculating the'additional control efficiency required  -



enter the figure in its column of Form 2.



     Part III,  Section I,  B - The control plan and schedule



necessary to bring the source into compliance is given here.



Generalized compliance schedules can be determined from EPA



Publication 340/1-74-001-a .   When a source is already under



a compliance plan, its schedule should be compared with an



appropriate schedule from this publication to ascertain its

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attainability.  Milestones of the schedule should also be

checked with required Ohio or Illinois compliance deadline.

     Part III, Section II - The estimated range of installed

cost should be included, if a basis for such an estimate is

available.  Sources which can be utilized for determination  of

capital and operating costs include:
  Grain Industry


  Sulfuric Acid

  Pulp and Paper


  Iron and Steel
  Cost Study for
  Selected Industries

  Iron Foundries
  Control Costs for
  Selected Industries

  Capital and Oper-
  ating Costs of
  Pollution Control
  Vol.  1 and 2
MRI
Chemico

Environmental
Engineering

Battelle
RTI & PEDCo
A.T. Kearney
IGCI
EPA
Contract 68-02-0213
December 1973

March 1970

Contract CPA 22-69-18
March 1970

Contract PH 22-68-65
May 1969

Contract CPA 22-69-79
February 1970

Contract CPA-22-69-106
1970

1974
EPA-R5-73-023 a & b
July 1973

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                  REFERENCES AND FOOTNOTES
1.   Compilation of Air Pollutant Emission Factors/ 2nd
     edition,U.S.Environmental Protection Agency, April
     1973..

2.   Air Pollution Engineering Manual, 2nd edition, U.S.
     Environmental Protection Agency, May 1973.

3.   For example, a granular material handling system con-
     trolled by a cyclone might comply with quantitative
     regulations, but because of the fine particles involved
     might not comply with the applicable opacity regulation.

4.   Through plant visit or contact with State or local APC
     personnel familiar with the source.
5.   Control Efficiency Required (%) =

       Actual emission rate - Allowable emission rate
                    Actual emission rate
x 100
6.   Technical Guide for Review and Evaluation of Compliance
     Schedules for Air Pollution Sources, prepared for EPA,
     Contract No. 68-02-0607, Task No. 5, by PEDCo-Environ-
     mental Specialists, July 1973.
                              10

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  APPENDIX A




PROJECT FORMS

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                                                                 ito .'I
                                                        'Cerf
to
'ort
                                                                                                                            REPORTING DATE '
2?A COIJTRACT HO.
co:rr-RAcroR
TASK 1,T0.
68-02-1375
PEDCo-Environmental Specialists,  Inc.
11      •    .    .
Source and Location ,
& NO.


State data
received
by PEDCo


Stace data
analyzed
1
-
Region V Pegion V gives
informed data! "« infor-
insufficient nation to
| PEDCo




114 forwarded
to Region V


114 reply
received by
PEDCo


Emission data
analysis in
process


Evaluation of
emission data
.completed


Checklist
completed


Plant
inspection
conducted


Notice
forwarded to
Region V


Conference
attended

•
Order tlr
Iand for-



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        Form No. 2 - Missing Information Summary
Missing Information Summary




Compliance Evaluation For
Facility Name No.
No.
Date: Request

Source Code
and Type



'
















Additional Information Needed





»














Receipt

Facility Answer To
Information Requested




















Name of Reviewer
1 tp-^^m r-r>A Tp^N-v-m 1 t:o me 	

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     Form No. 3 - Compliance Status  Summary with  Substantiating Calculations and Regulation Citations
Facility; ' Name
                                               No.
                                                           -State:
                                                                                       Date:
Source
Code
-
Process
Type

Control
device

Emission Rates and Calculations
Pol.2
Type



















Actual Emissions Calculations



^















Actual Em. Rate
Ibs/hr



















TPY3



















Allow. Em. Rate
Ibs/hr



















TPY3 .



















App.4
Reg.



















P5
c
R



















Conclusion
and
Recommendation





-













1) From Form 158-R75          3)  TPY  (tons  per yr)   4) Applicable  Regulation 5)  Percent         Contract No. 68-02-1375
2) P-Particulate; S  (SO-); HC (hydrocarbons);  N (N0x>; CO                     Control  Required  Task Order No. 11
,,,,..,,™,mC.                                                                                       Reviewer

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Date Report Submitted:_
ENVIRONMENTAL PROTECTION  AGENCY
  AIR POLLUTANT EMISSIONS  REPORT
  SECTION  I  -  GENERAL  INFORMATION
                                     FORM APPROVED
                                     OMB NUMBER 158-R75
                                                                                                                For Official Use Only:

                                                                                                                Date Sent:	:_
                                                                                                                Date Returned:.
                                                                                                                UTM Grid Coordinates:.

                                                                                                                SIC No.:	,	
                                                                                                                Source ID:_
Plant, institution, or establishment name:.
Plant, institution, or establishment address:-

Person to contact regarding this report :—=
Mailing address:
 (Street or Box Number)
(City).
(SUU)
                              (Street or Boi Number)
                        (City)
                                                                                                         (State)
            jjlar.'. Lctituti:.::, or establishment in relationship to moan con lovol :_
                                        .foot above mean coa lovcl).
Information is representative of calendar year:__	    .
Land area at plant location:	,	.acres. Enclose a sketch of layout if there is more than one building.
Plant location:  (give nearest cross streets, describe by landmarks or enclose a map, engineering drawing, or sketch)	^
                                                                            pnirm
                                      (Zip)
(Zip)
[j Air pollutants of the type indicated in the instructions for the completion of this report, i.e.,
   arp not emit.tr"1 at this plant, ins^t.ution or establishment.  Therefore, no other Sections of the report need be completed.
                                                             - — - : - : _ -(Title)
Please return all sections of this report to:
                                                      Additional forms may be obtained from Che above address.
                                                                                                                         NOTE:- Please rend reverse aide of
                                                                                                                         this page. Use additional sheets
                                                                                                                         if necessary.  Retain last copy.

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Date Report Submitted :_^^_
ENVIRONMENTAL PROTECTION  AGENCY
  AIR  POLLUTANT EMISSIONS REPORT
FORM APPROVED
OMB NUMBER I5S-R7J
                 SECTION II - FUEL  COMBUSTION  FOR GENERATION OF HEAT, STEAM,  AND POWER
Plant, institution, or establishment name:.
Dates of annually occurring shutdowns of ope
Source ".c
Code






Number of
Combust:on
Sources b.e
(Boilers)






rntinnc- J 	

Size of
Unit (Input) c,e
10«BTU/hr.

.


•

Type of Unit
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 Date Report Submitted :^^	1
ENVIRONMENTAL PROTECTION  AGENCY
  AIR POLLUTANT  EMISSIONS REPORT
FORM APPROVED
OMB NUMBER 15S-R75
          SECTION II - FUEL  COMBUSTION FOR  GENERATION OF  HEAT,  STEAM, AND POWER  (continued)
 Plant, institution, or establishment name.-j
Source
Cociea







Type
of
Fuelb
'






Annual Consumption^ •
Quantity^







Percent Distribution by Season
Spring
March/
Mav







Slimmer
June/
Aug.







Fall
Sept./
Nov.
t






Winter
Dec./
Febr.
•- —'"-:'
.





Hourly Consumption^
Maximum







Average
- - -






Percent
Used for
Space Heat







. .Heat
Content
BTU/Quan./







Percent
Sulfure.f







Percent
Ash (Solid
Fuel Only) «,f







r
Delivered-
Cost of
Fuel
$/Quantity



v



i
i
Future '
Uses j
i
i
\
\
i
. ; i
. s
i
i
i
- • j
 a.  List code numbers corresponding to each source referred to on page 2, (e.g., Il-a, Il-b, II-c. etc.), then enter required data on this page, and for the same code
    number sources in Sections V and VI.
 b.  Coke, bituminous coal, anthracite coal, lignite; Xo. 1, 2, 4, 5 and 6 fuel oil; natural gas; LPG; refinery or coke oven  gas; residual coke; wood; bark; sludge;
    etc. (Note: Indicate if two or more fuels are burned in the'same boiler and provide all data pertinent to each fuel type.)
 c.  Fuel data are to be reported on an "as burned" basis.                                                        .
 d.  Solid fuel,  tons; liquid fuel, gallons; gaseous fuel, 1000 cubic feet.                                                                 •
• Oi  If unl'.nn-irn, pionco givo riciino and  nddrocn of fuel rupplion
 f.  Sulfur and ash content for each fuel should be a weighted average.
 g.  Estimated  percent increase or decrease in fuel usage (by fuel type) per year for .the five years after the calendar year for.which this report, is completed. If in-
    crease is due to new equipment, please list this equipment separately on page 2 and the expected fuel use on this page.
                                                                                                                  NOTE: Plcaae read reverse aide of
                                                                                                                  thia page. Use additional sheet*
                                                                                                                  U neceaaary. Retain last copy.
                                                                       -3-

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Date Report Submitted :_
.   •  -•   -           ENVIRONMENTAL PROTECTION AGENCY
                     AIR POLLUTANT EMISSIONS REPORT

 SECTION III - COMBUSTIBLE  SOLID AND  LIQUID WASTES DISPOSAL
FORM APPROVED
OMB NUMBER I58-R75-
Plant, institution, or establishment name:_
CombusHble solid and liquid wastes disposed of Qj on site, ['.   off site, Qj both on and off site.  If off site, location of disposal site and/or name of hauler:	
	:	•_  -	:	.  (If disposal of solid and liquid wastes is partly or wholly on  site, complete remainder of  this page and

   •Sections IV, V and VI; otherwise, skip to Section IV.)
Normal on-site combustion operating schedule:	Hours per floy,      	Days per week	^Weeks  per year	   "Hours per year.
Seasonal and/or peak operation period: (Specify)	:	'.	'.	:	=	:	

Dates of  annually occurring shutdowns of operations:	:	;	__	
                                                           .. Additional operating information enclosed [~|.
Source
Code*





• Waste Material
Typeb





Amount
Per .
Yearc





Percent
Combust-
ible





Method of Disposal d





Installation
Date


a


Hourly Burning
-Rate; Ibs.
Average





Maximum





Auxiliary Fuel
Used.e





Percent Excess
Air Used in Com-
bustion (Design)





Future Disposal'
^\
\
\
\
\
a.  List a separate code number to represent each source (e.g., III-a, III-b, III-c, etc.), then enter required data on this page and for the same code number sources
   in Section V and VI.
b.  Rubbish, garbage, mixed garba'ge and rubbish, waste paper, wood chips or sawdust, etc.
c.  Tons, pounds, or gallons/year.
d.  Open burning dump; incinerator, single chamber; etc. (See instructions for examples and use appropriate identification numbers; other non-listed methods, specify.)
e.  Indicate whether auxiliary fuel is used in incinerators and pit burning, and the amount.
f.  Estimated increase or decrease in combustible solid an'd liquid wactes disposal rate for the five years after the calendar year for which this report is completed.
   If increase is due to new equipment, please list this equipment separately.
                                                                                                                    NOTE: Please rend reverse side ol
                                                                                                                    this page.  Use additional sheets
                                                                                                                    if necessary. Retain last copy.
                                                                        -4-

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Date Report Submitted;.
     ENVIRONMENTAL  PROTECTION AGENCY
       AIR POLLUTANT  EMISSIONS REPORT
SECTION  IV - PROCESS/OPERATIONS  EMISSIONS
                                           FORM. APPROVED
                                           OMIJ NUMBER 15S-R7
Plant, institution, or establishment name:	
Normal operating gf1m'
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Date Report Submitted:,
ENVIRONMENTAL  PROTECTION AGENCY
  AIR POLLUTANT EMISSIONS  REPORT
SECTION V - AIR CLEANING  EQUIPMENT
FORM APPROVED
OMB NUMBER \58-R75
Plant, institution, or establishment name:
Source
Code.-i




i- -•


Type of Air
Cleaning Equipment b,c
.



•--::". ~ - ''-
~ ~. •'

Installation
Datec



?~
•-


Pollutant
Removed c,d


V.




Efficiency e
Design
Percent


,_..* '




Operating
Percent







Inlet Gas
Temperature,
°F
.
o





Inlet Gas
Flow Rate,'
CFM

«. _ " i


i-.
-

Exit Gas
Pressure,
PSI
...
i. : _





a.  List code numbers corresponding to each emissions source reported in Sections II, III, and IV.
b.  Wet scrubber, electrostatic precipitator, fabric filter, etc. {£eg ir.jtriictio'aa for examples and use a
c.  Please list future equipment separately.
d.  The pollutants to be covered in this survey are specified in the accompanying instructions.
e.  Give efficiency in terms of pollutant removed.
f.  At actual flow conditions.
                                  *  Plenum  drop  box  +• secondary  cyclone
                                     typical emission  from  cooler drop  box
                                     estimated cyclone off  = 97.0
                                                                     -6-
                                     250  Ib./hr.
                                                                 NOTE: Please read reverse side of
                                                                 this page.  Vac additional sheets
                                                                 if necessary. Retain last copy.

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Date Report Submitted:,
	     HIM V1KOJN MENTAL  PROTECTION AGENCY
              AIR  POLLUTANT  EMISSIONS REPORT
 SECTION  VI - STACK AND  POLLUTANT  EMISSIONS DATA
FOU.v  VPPHOVED
.OML' NUMBER U8-R75
Plant, institution, or establishment name:.
STACK DATA
Source
Code*





%

rHeight
Above
Grade
ft.

--





Inside
Diameter
at Top,
ft.



'•

.. .

Exit Gas
Velocity,!'
ft. /sec. .







Exit Gas
Temperature, b
op

.-

;



Exit Gas Flow
Rate, CFMc
Average







Maximum







ESTIMATE OF POLLUTANT EMISSIONS
Pollutant







Quantity
Tons Per Year




.



Lbs. Per Ilour
Average

-





Maximum
1






a. List code numbers corresponding to each emissions source reported in Sections II, III, and IV.
b. Values should be representative of average flow conditions for hours of operation.         .
c. At actual flow conditions.
d. The pollutants to be covered in this survey are specified in the accompanying instructions.
e. Give stack test data if available (indicate stack sampling method used), otherwise, specif}' basis used.  If unknown, please do not complete these columns.
                                                                                                                    NOTE: Please read reverse side of
                                                                                                                    this page.  Use additional sheets
                                                                                                                    if necesjary. ReUin last copy.
                                                                       -7-

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          APPENDIX B




OHIO AND ILLINOIS REGULATIONS

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OHIO   REGULATIONS

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:ONT


               Relative  To

The  Control  of  Hydrocarbon

and  Photochemical  Oxidant,
      Carbon Monoxide   and

        Oxides   of  Nitrogen

                 Emissions
     Ohio  Department  of  Health

              Columbus,  Ohio
   AP-.3-01.  Definitions
   As  used  in regulations AP-5-01 to AP-5-08, inclu-
sive:
   (A)  "Organic   material"   means  any  chemical
compound containing  carbon, excluding carbon mon-
oxide,  carbon dioxide,  carbonic  acid,  metallic  car-
bides,  metallic carbonates, and ammonium carbonate.
   (B)  "Liquid organic material"  means any organic
material which is  a  liquid at standard conditions.
   (C)  "Photochemically  reactive  material"  means
any liquid organic  material with an aggregate  of more
than 20 percent of  its total volume composed of  the
chemical compounds  classified  below or which  ex-
ceeds  any  of  the following  individual  percentage
composition limitations, referred to the total volume
of liquid:
   ( 1)  A  combination  of  hydrocarbons,  alcohols,
aldehydes,   esters,  ethers  or  ketones  having  an
olefinic  or  cyclo-olefinic .type  of  unsaturation: 5
percent;
   (2)  A combination of  aromatic hydrocarbons with
eight  or more carbon atoms to the  molecule except
ethyl benzene: 8 percent;
   (3)  A combination of  ethylbenzene.  ketones hav-
ing branched hydrocarbon structures, trichloroethylene
or toluene:  20 percent.
   Whenever any  organic  material  or any constituent
of an  organic  material may be  classified  from  its
chemical structure  into more than one  of the above
groups  of organic compounds,  it shall be  considered
as a member of the most reactive chemical group, that
is. that group having the  least allowable percent of
the total volume of liquid.
   (D)  "Volatile  photoGhemically  reactive  material"-
means  any   photochemically reactive  material which
has a  vapor pressure of 1.5 pounds  per  square inch
absolute or  greater under actual  storage conditions.
   (E)  "Submerged, fill  pipe" means  any fill pipe  the
discharge opening  of which  is  entirely  submerged
when  the liquid  level  is six  (6) inches above  the
bottom  of the  tank; or when applied  to a tank which
is loaded from the side, shall  mean any fill pipe  the
discharge opening  of which  is  entirely  submerged
when  the liquid level is eighteen (18) inches above
the bottom of the tank.
   (F)  "Effluent  water separator" means  any  tank,
box, sump,  or other container  in  \vhich any volatile
phoiochemically   reactive1   material  floating   on  or
entrained or contained  in water entering such  tank,
box. sump,  or other container is physically  separated
and removed from  such  water  prior to  outfall, drain-
age, or recovery of such water.-
   (G)  "Architectural coating"  means  any  coating
used  for  residential  or  commercial buildings  and
their appurtenances, or industrial buildings.
(Adopted January  28, 1972;  effective February  15,
1972.)
     Al'-.O-Ofi.  Classification of regions.
     (A)  Classification of regions  shall be baser! <;
 measured  ambient  air quality  where  known or,
 not known, estimated air quality  in the area  of ;:
 mum pollutant concentration.   Each  region shuii
 classified separately with respect to carbon mono?:.
 and photochemical oxidants.   Each region  shall ;•
 be  classified into one of two categories, dcfiin-i!
 Priority 1 or Priority  111.  Classifications with rus;
 to hydrocarbons  will be  t-he same as the ciassi;
 tions with respect to  photochemical oxidants.  Aruii
 concentration limits  which define the classific:::
 system are:
    ( 1)  Carbon monoxide: Priority  I:. Equal to or uli>
 55 milligrams per cubic  meter  (-18 ppm).  1-hour n;-.i
 mum, or  1-1 milligrams per cubic meter (12 ppm), S-l-
 maximum.  Priority III: lie low such values.
    (2)  Photochemical oxidants:  Priority I:- Ec;»a!
 or above  195  micrograms  per cubic meter (0.10  p;i:
 1-hour  maximum.  Priority  III: Below  such  vu! .
    (B)  In  the absence  of measured data to the <
 trary classification with respect to carbon inonnx:
 hydrocarbons  and  photochemical   oxidants  will
 based  on the  following estimate  of the  relations'
 between  these pollutants  and  population. Any reg
 containing an area whose  1970  "urban  place"  poi,;:
'tion, as defined  in  the United. States  Bureau of C-
 sus, exceeds  200,000 will bo  classified Priorif/.
 All other regions will  be classifi*",! Priority III.
 (Adopted January  28,  1972;  effective  February   ;
 1972.)

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   AP-r>-07.  Control  of emissions  of organic mate-
rials from stationary sources.
   i.A) These regulations are applicable tu  all exist-
ing  stationary sources  located  within  a  Priority  I
region and  to all  new stationary sources regardless of
I -cation.
   ^B) Except as otherwise provide/I  in those regula-
".ons,  all new stationary emission  sources  of photo-
-henucally  reactive  materials  shall  minimize  such
• missions  by  use  of the  latest  available  control
Techniques  ami  operating  practices   in  accordance
v:ir.h best current  technology.
   •(C")  Nothing in this regulation  siuill  be  construed
' -.'  preclude  the  use  of  alternative  means to  abate
-.•missions,  if  such  alternative  is approved  by  che
Board and will not result  in emissions significantly
-.reater than would result  from  the  application of the
::'.eans specified herein.
    (D) Storage of volatile photoch'-mically  reactive
•materials.
    il) No person shall place, st-jr*-. or  hold in any
stationary  tank,  reservoir  or other container of  mort
than  65.000  gallons  capacity  a;:y  volatile photo-
-hemically reactive material  unless such tank,  reser-
voir, or other container is  a  pressure tank capable of
maintaining  working  pressures  sufficient  at al! times
to prevent  vapor  or gas loss to tl\" atmosphere  or is
designed,  and  equipped  with  one  of  the following
 vapor loss control devices:
    (a) A  floating pontoon.or double-deck' type cover
equipped  with  closure seals to  enclose  any  space
 between the cover's  edge and compartment wall. This
 control equipment shall not be permitted if the volatile
 photochemically reactive material has  a vapor  pre-
 sure  of  12.5  pounds  per  square  inch  absolute or
 greater  under  actual  storage  conditions.  All tank
 gauging or sampling  devices  shall be gas-tight except
 when tank gauging  or sampling is taking place.
    ( b)  A  vapor recovery system which  reduces the
 emission of organic 'materials into tho atmosphere by
 at  least  90 percent  by  weight.  All  tank gauging or
 sampling devices shall be gas-tight except when tank
 gauging or sampling  is taking place.
    (c)  Other  equipment  or  means  of  air  pollution
 control as may be approved by the Board.
    (2)  No  person  shall  place,  store, or hold in any
 stationary  storage  vessel  of  more  than 5 00-gallon.
 capacity any volatile photochemically reactive  mate-
 rial unless  such vessel is equipped with a permanent
 submerged fill  pipe, is  loaded  through  the  use of a
 portable loading tube  which -can be  inserted  below
 the liquid level line during loading operations, or is a
 pressure  tank  as described   in subsection (D)  (1) of
 this  regulation  or  is  fitted  with a  vapor  recovery
 system as described  in subsection (D) (1) (b) of this
 regulation.
    (E)  Volatile  photochemically  reactive  materials
 loading facilities.
    ( 1)  No person shall load  in any one day more than
 40.000  gallons  of any  .volatile  photochemically re-
 active material into any tank truck, trailer, or railroad
 tank car from any  loading facility unless the loading
 facility is equipped  with a  vapor  collection  and dis-
 posal  system  properly   installed, in good   working
 order,   in  operation,  and consisting  of  one of .the
 following:
    (a)  An  adsorber  system  or  condensation system
 which  processes and recovers- at  least 90 percent  by
 weight  of  all  vapors and gases  from the equipment
 being controlled.
    ('b)  A  vapor handling system which  directs  all
 vapors  to a fuel  gas  system.
    (c)  Other equipment or means for purposes  o.f air
 pollution control as may as acceptable to  and  approved
 by the Board.
    (2)  AH  loading from facilities subject to  the pro-
 visions of subsection i,E) (1) (al and (E) (O (b) of this
 regulation  shall  be accomplished in such  a manner
 that all displaced  vapors and gases  shall be vented
 only to the  vapor  collection system. A  means  shall
be provided  to prevent liquid drainage from the loading
device  when it is  not  in use or to accomplish com-
 plete  drainage  before the  loading  device  is
disconnected.
    (F)  Volatile  photochemically  reactive  material/
water separation.
    ( 1)  -No person  shall use  any compartment of any
 vessel or device  operated for the recovery  of volatile
 photochemically  reactive materials from  an effluent
 water separator which recovers 200 gallons a day  or
 more of any  volatile photochemically  reactive mate-
 rial  unless  such compartment is  equipped with on;.-
 of  the  following  vapor loss control  devices, properly
 installed,  in good  working  order  and  in  operation:
    (a) A  solid  cover with all openings  sealed ami
 totally enclosing  the liquid contents  of the compart-
 ment.  All  gauging  and  sampling  devices shall he
 gas-tight  except  when gauging or sampling is taking
 place.
    (b) A floating pontoon or double-deck  type cover
 equipped  with  closure  seals  to enclose   any  space
 between the cover's edge.and compartment wall. All
 gauging and sampling  devices  shall  be  gas-tight
 except when gauging  or sampling  is taking place.
    (c) A  vapor  recovery system  -which  reduces the
 emission  of  organic  materials into  the 'atmosphere by
 at  least 90  percent  by weight. All gauging  and samp-
 ling devices  shall be gas-tight except when gauging
 or  sampling  is taking place.
    (d) Other equipment .or  .means of  air pollution
 control as may be  approved by the .Board.
    (G)  Operations  using  liquid  organic   materials.
    ( I)  A  person  shall  not discharge  more  than 15
.pounds of organic  materials  into the.  atmosphere in
 any one day,  nor  more than 3 pounds in any one hour.
 from  any  article,  machine,  equipment, or   otnt-r  con-
 trivance  in   which   any  liquid organic  material or
 substance  containing liquid organic  material comes
 into  contact  with flame  or  is baker),  heat-cured, or
 heat-polymerized,  in the  presence of  oxygen,  unless
 said  discharge  has  been  reduced  by  at  least  85
 percent.
    ( 2)  A person  shall  not discharge  more than 40
 pounds of organic material into the  atmosphere in any
 one day, nor more than 8  pounds in any one  hour, from
 any article, machine, equipment, or  other contrivance
 used  under  conditions other than described in  sub-
 section  (G)  (.1)  of this regulation  tor  employing,
 applying,  evaporating or drying any photochemically
 reactive material  or substance containing such photo-
 chemically  reactive  material,  unless  said  discharge
 has been  reduced  by at  least  85 percent.
    (3)  Any  series  of articles, mac.hines,   equipment
 or other contrivances designed for  processing  a  con-
tinuously  moving  sheet,  web.  strip,  or  wire which is
subjected to any  combination of operations  described
in  subsection (G) (1) or (G) (2)  of  this   regulation
involving  any photochemically reactive material,  or
substance containing such  photochemically reactive
material,  shall  be subject  to  compliance   with  sub-
section (G)  (2)  of this regulation.   Where,  only  non-
pholochernically  .reactive  materials  or  substances
containing only nonphotochemically reactive materials

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are  employed  or  applied,  and where any  portion  or
portions of said series of  articles, machines,  equip-
ment,  or other contrivances involves operations des-
cribed  in subsection (G) (1) of this regulation, said
portions shall be collectively  subject  to  compliance
with subsection (G) (1) of this  regulation.
    (4) Emissions  of organic  materials to the^atmo-
sphere from the cleanup with' photochemically reactive
materials of any article, machine, equipment, or other
contrivance described  in subsection (G) (1), (G) (2-,
or (G)  (3)  of this  regulation,  shall he included with
the  other  emissions of  organic  materials from that
article, machine,  equipment, or other contrivance  for
determining  compliance with this regulation.
    (5) Emissions  of organic  materials to the atmo-
sphere resulting from air ur heated drying  of-  products'!
for the  first  12 hours  after their  removal  from any \
article,  machine,  equipment,  or  other  contrivance |
described in subsection (G) MI. i.C) i2;, or (G) (3)  of \
this regulation, shall be included  with other emissions !
of organic  materials from that article.'machine,  equip-
ment,  or other contrivance,  for determining  compliance
with  this regulation.
   ( 6)  Emissions of organic materials  into the atmo-
sphere required to be controlled by subsection (G) (1),
(G) (2), or  (G)  (3) of this regulation, shall  be  reduced
by:
   (a)  Incineration,  provided that 90 percent or more
of the  carbon in the  organic material being  incinerated
is oxidized to carbon dioxide, or
   ( b)  Adsorption, or
   (c)  Processing  in  a manner  determined by  the
Board  to be  not  less effective  than i'a) or (bi above.
   '. 7)  A person incinerating,  adsorbing, or otherwise
processing  liquid organic  materials  pursuant to this
rule  shall  provide,  properly install,  anil  maintain   in
calibration, in good  working order and in  operation.
devices as  specified in the authority to construct   or
the permit  to operate,  or as specified  by  the Board,
for indicating temperatures, pressures',  rat^s  of flow,
or other operating conditions necessary to determine
the degree  and effectiveness of air  pollution  control.
   (8)  Any  person  using  liquid organic materials   ur
substances  containing  liquid organic materials shall
supply the  Board, upon request  and in the manner and
form prescribed by  the  Board, written evidence  of tht.-
chemical composition, physical  properties, and amoun:
consumed for each organic solvent, used.
   (9)  The  provisions  of section (G) of this reguia--
shall not apply to:
   (a)  The use of'equipment for which other require-
ments  are specified by sections i'D), (E),  and (Fi  of
this regulation, or which are exempt  from air pollution
control requirements .by said sections.
   ( b)  The  spraying or  other  employment  of insec-
ticides, pesticides, or herbicides.
    (c) The   use  of  any  material,  in any article,
 machine,  equipment, or'other contrivance  described
 in  subsection (G) (1).  (G1  (2), (G) (3).  or  (G) (4) of
 this  regulation,  if:
    (i)  the volatile  content of such material consists
 only  of water and liquid organic material, and
    (ii)  the  liquid  organic  material  comprises  not
 more  than 20 percent  of  said volatile  content,  and
    (iii'l  the volatile  content is- not a  photochemicaiiy
 reactive  material.                             •   .
    (d)  The  use  "of  any   material,   in  any  article.
 machine,  equipment  or  other contrivance described in
 subsection (G) (1). (G) CJ). (G; (31. or (G) '.4)  of this
 regulation, if:
    (ii  the  volatile  content   of  such material does
 not exceed 20 percent-by volume of said  mate rial,, and
    (ii)  the volatile  content is not a  photochemically
 reactive material.
    (  e)  The use.  in any article,  machine,  equipment.
 or  other  contrivance  described in subsection  (G't  (-1),
 (G) (2),  i.G) ^.3),  or (G)  (.4),  of  liquid organic materials
 which exhibit a  boiling point higher than  220' F at
 0.5 millimeter mercury absolute pressure, or having an
 equivalent vapor  pressure,  unless such liquid organic
 material  is exposed  to temperatures exceeding 220' F.
    (f)  The  use  of  any  material,   in  any  article,
 machine,  equipment  or  other contrivance described in
 subsection (G) (I). (G)  (2).  (G) (3). or (G) (4), if it  can
 be demonstrated'  to  the Board's satisfaction that  the
 emissions of  organic  materials  into the atmosphere
 from  such article, machine, equipment or other  con-
 trivance-are not photochemically reactive.
    (H)  Architectural coatings.
    (  n  A person  shall not sell  or offer  tor sale  for
 use  in' containers of  greater  than 1-gallon capacity,
- any architectural coating containing a phot oc heroically
 reactive material.
    (2)  A ptfrson  shall not employ, apply,  evaporate,
 or dry  any  architectural coating, purchased  in  con-
 tainers  of greater  than  I-gaUon.capacity, containinc a
 photochemically reactive material.
    (  :>)  A person  shall not thin,  or dilute for applica-
 tion  any architectural coating  with a photoclieir.icaliy
 reactive material.
    (I )  Disposal and evaporation of solvents.
    A-person  shall not, during  any-one day, dispose of
 a  total  of more   than  1-1/2  gallons of any  volatile
 photoche-!ui:a'l.y  reactive material, or dispose ot  any
 substance containing  more than  1-1 '2 gallons of  anv
 volatile .  photochemically  reactive  material,  by  any
 means  which  will  permit the  evaporation  of such
 volatile   phoiochemic'aliy  reactive  material into   the
 atmosphere.
    (  J)  Waste gas disposal.
    (1)  No person shall emit  a waste gas stream  from
 any  • •thylene  producing plant  or  other ethylene emis-
 sion source into  the atmosphere unless the  waste gas
 stream  is properly burned  at 1.300° F for 0.3  seconds
 or  greater in a direct-flame  afterburner or an i:
 Board.
    (3)  The provisions of subsections (J) (1) and  
 of  location.
    (B)  Except as otherwise  provided  in  these regula-
 tions,  all hew stationary carbon monoxide emission
 sources shall  minimize carbon monoxide  emissions  bv
 use  of the  best- available   control  techniques am!
 operating  practices in  accordance  with  best currrii1
 technology.
    (C)  Nothing in this regulation shall  be constru>".:
 to  preclude  the  use  of  alternative means  to abat"
 emissions,  if such  alternative  is  approved  by tin
 Board and will not result in emissions  significantK
 greater than would result from the application of th
 means  specified herein.
    (D) Process equipment.
    No  person  shall emit  the carbon monoxide gusi;>
 generated during the operation of a  grey  iron  cupola,.
 blast  furnace, or basic  oxygen  steel  furnace uuli-s--
 they am burned at  1,300' F for 0.3 seconds or  greau-r
 in  a  direct-flame afterburner or equivalent  device
 equipped with  an  indicating  pyrometer -which  is  posi-
 tioned in the working area at  the  operator's eye level.
    (E) NO person shall emit carbon monoxide wast--
 gas stream from any catalyst  regeneration of  a petro-
 leum cracking  system,  petroleum  fluid  cokcr.  or'other
 petroleum  process  into  the  atmosphere.,  unless th-
 waste gas stream is burned at  1,300° F  for 0.3  second:;
 or  greater  in  a  direct-flame  afterburner  or  boiler
equipped with  an  indicating pyrometer which  is posi-
tioned   in  the   working area  at  the  operator's  cy.-
 level.
(Adopted  January  28.   1972;  effective February  15.
 1972.)

   AP-7-0.5.  Classification of regions.
   (A)  Classification  of regions shall be based upon

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are  employed  or  applied,  and  where any  portion  or
portions of said series of articles, machines,  equip-
ment,  or other contrivances involves  operations des-
cribed  in subsection  (G)  (1) of this regulation, said
portions shall be collectively  subject 'to compliance
with subsection.(G) (1) of this  regulation.
    (4) Emissions of organic  materials to the atmo-
sphere from the cleanup with photochemical!}- reactive
materials-of any article, machine, equipment, or other
contrivance described  in subsection (G) (1), (G) (2),
or (G)  (3)  of this  regulation, shall be  included with
the 'other  emissions  of  organic materials from  that
article, machine,  equipment, or other contrivance  for
determining  compliance with this regulation.
    (5) Emissions of organic  materials to the atmo-
sphere resulting from  air or heated drying of  products
for the first  12 hours  after their  removal  from any
article,  machine,  equipment,   or  other contrivance
described in subsection (G) (1), (G) (2), or (G) (3)  of
this regulation, shall be include'd with other emissions
of organic  materials from that article,  machine,  equip-
ment,  or other contrivance, for determining compliance
with  this regulation.
   ( 6)  Emissions of organic materials into the atmo-
sphere required  to be controlled by  subsection (G) (1),
(G) (2), or  (G) f3) of this regulation, shall be reduced
by:
   (a)  Incineration, provided that  90  percent or more
of the  carbon in the  organic material being incinerated
is oxidized  to carbon dioxide, or
   (b)  Adsorption, or
   (c)  Processing  in a  manner  determined  by the
Board  to be not  less  effective  than (a)  or (b) above.
'  . (7) A person incinerating, adsorbing, or otherwise
processing  liquid organic materials  pursuant to' this
rule shall  provide,  properly  install, and maintain  in
calibration, in good  working order  and  in  operation,
devices as  specified  in the authority to construct  or
the permit  to operate,  or  as specified by the Board,
for indicating temperatures, pressures, rates  of flow,
or other operating  conditions necessary to determine
the degree and  effectiveness of air pollution control.
   (S)  Any  person  using  liquid  organic materials  or
substances  containing liquid organic  materials shall
supply the  Board, upon request and  in the manner and
form prescribed  by the Board, written  evidence  of the
chemical composition, physical  properties, and.amount
consumed for each organic solvent used.
   (9) The  provisions of section  (G) of this regula-
shall not apply to:
   (a)  The use of equipment for which  other require-
ments  are  specified by sections  (D),  (E), and (F)  of
this regulation,  or which are exempt from air pollution
control requirements by said sections.
   (b) f lie  spraying  or  other  employment of insec-
ticides, pesticides, or herbicides.
    (c) The  use  of  any  material,  in  any  article,

6 '

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PART II:  EMISSION STANDARDS AND LIMITATIONS FOR STATICKAHY SOURCES
Rule 201: DEFINITIONS.             •    .               •

     ALL TERMS DEFINED IN PART 1 OF THIS CHAPTER WHICH APPEAR  IN  PART
2 OP THIS CHAPTER HAVE THE DEFINITIONS SPECIFIED BY RULE 101 of PART
1 OF THIS CHAPTER.

     Actual Keat Input :  The quantity of -heat produced by  the
combustion of fuel using the gross heating value of the fuel.

     Architectural Coating :  Any' coating used for residential  or
commercial buildings or their appurtenances, or for industrial
buildings which is site applied.

     British Thermal Unit:  The quantity of heat required  to raise
one pound of water from 60 °F to 6l°F  (abbreviated btu) .

     Complete Combustion:  A process  in which all carbon contained
in a fuel or gas stream is converted  to carbon dioxide.

     'Concentrated Nitric Acid Manufacturing Process :  Any  acid
producing facility manufacturing nitric acid with a concentration
equal to or greater than 70 percent by. weight.

     Distillate Fuel Oil:  Fuel oils of grade No. 1 or 2 as specified
in detailed requirements for fuel oil A.S.T.M. D396-S9 (1971).

     Effluent Water Separator:   Any tank, box, su-Tip, or other  apparatus
In which any organic material floating on or er.trained or  contained
in water entering such tank,  box, sump, or other apparatus is  physicall;.
separated and removed from such water prior to outfall, A?a.±-^a.*,,="--.jl-~~'
recovery of such water.                                 (
     Emission Rate:  Total quantity of any air contaminant discharged
into the atmosphere in any one-hour period.

     Excess Air:  Air supplied in addition to the theoretical
quantity necessary for complete combustion of all fuel ar.i/or com-
bustible waste material.

     Floating Roof:  A roof on a stationary tank, reservci-r or other
container which'moves vertically upon change in volume of the stored
material.
     Excessive Release;  A di-schsrge of more than 0.65 pounds of
mercaptans and/or hydrogen sulfide into the atmosphere in any five
minute period.

     Floating Roof:  A roof on a stationary tank, reservoir.or other
container which moves vertically upon change in volume of the stored
material.

  '.  FUO?L Combustion Emission Source:   Any furnace,  boiler, or sim'lar
equipment used for the primary purpose  of producing  heat or power by
Indirect  heat transfer.        '

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ILLINOIS REGULATIONS

-------
                                PEDCo - Environmental
                                        ilC'i) JAN    ,'1974
              State  of Illinois
         Air Pollution  Control
                 Regulations

            Revised, Second Printing
                  January 1973
     Note: This printing of the Illinois Pollution Control Board
     Rules and Regulations for Air Pollution includes air pollution
     regulations as published in the Pollution Control Board News-
     letter and the following opinions of  the Pollution Control
     Board:

       In the Matter of Emission Standards  -PCB R71-23 .
       In the Matter of Proposed Amendments
         to Episode Regulations        -PCB R.72-6
       In the Matter of Proposed Amendments
         to Open Burning Regulations    —PCBR72-11
       In the Matter of Asbestos Regulations -PCB R71-16

     Emission  Standards, PCB  R71-23,  were effective April 14,
     1972; Episode Regulation Amendments, PCB R72-6, were ef-
     fective August 18,1972, and Open Burning Regulation Amend-
     ments, PCB R72-11, were effective November 10, 1972.
Printed by Environmental  Protection Agency

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     Fugitive Particulate Katter:   Any partlculate matter emitted
into the atmosphere other than through a stack, provided that nothing
in this definition or in Rule 203(f) shall exempt any source from
compliance with other provisions of Rule 203 otherwise applicable
merely because of the absence of a stack.

     Gross H gat ing Value:   Amount of- heat produced when 'a unit
quantity of fuel is burned to carbon dioxide and water vapor, and
the water vapor, condensed as described in A.S.T.M. D 2015-66,
D 900-55, B 1825-61;, and D 240-61.

     Incinerator:  Combustion apparatus in which refuse is burned.

     Indirect: Heat Transfer:   Transfer of heat in such a way that
the source of heat does not come into direct contact with process
materials.
     KaJor Ketrooolitan Area (MHA):
which is defined by Table A.
                                     Any county or group of counties
     One Hundred Per Cent .Acid:
1.8205~t
             C.in the case of sulfurlc
the case of nitric acid.
Acid with a specific gravity  of
furlc acid and 1.1)952 at  30*C 1;
                                                               in
     Opacity:   A condition which renders material partially or wholly
impervious to transmittance of light and causes obstruction of an
observer's view. For the purposes of these regulations, the following
equivalence between opacity and Rlngelmann shall be employed:
          Opacity Percent

                10

                20

                30

                HO

                60

                80

               100
                                         Ringelnann

                                            0.5

                                            1.

                                            1.5

                                            2

                                           •3

                                            4

                                            5
                                                                                                                 TABLE A

                                                                                                  MAJOR METROPOLITAN AREAS IK ILLINOIS

                                                                                                                  (KKA's)
       H M A

(1)   Champaign - Urbana

(2)   Chicago


(30   Decatur

CO   Peoria

(5)   Rockford

(6)   Rock Island - Moline

(7)   Springfield

(8)   St. Louis (Illinois)

(9)   Blooraington - Normal
        COUNTIES INCLUDED
        	IK M.MA	        a

            Champaign

Cook, Lake, Will, DuPage, KcHenry,
 Kane, Grundy, Kendall, Xankakee

              Mac on

        Peoria, Tazewell

            Winnebago

           Rock Island

             Sanganicn

      St.  Clair, Madison

             McLean
                               -25-
                                                                                                                   -26-

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     Organic  Material:   Any  chemical  compound of carbon  including
diluents and  thinners which''are  liquids  at  standard  conditions  and
which are used as cissolvers,  viscosity  reducers or  cleaning  agents.
but excluding methane,  carbon  monoxide,  carbon dioxide,  carbonic
acid, metallic carbonic  acid,  metallic carbide,  metallic carbonates,
and ammonium  carbonate.

     Organic  Vapor:  Gaseous phase  of an  organic material or  a  mix-
ture of organic materials present in  the  atmosphere.

     Particulate Matter:  Any  solid or liquid material,  other than
water, which  exists in  finely  divided form.

     Photoche^lcally Reactive  Material:   Any  organic material with
an aggregate of more than 20 per cent of  -its  total volume  composed
of the chemical compounds classified  below  or the composition of
which exceeds any of the following  individual percentage  composition
limitations:

     (1)  A combination  of hydrocarbons,  alcohols, aldehydes,
          esters, either or ketones having  an olefinic or
          cyclo-olefinic type  of unsaturation:   5 per cent.
          This definition does not  apply  to perchloroethylene
          or trichloroethylene.

     (2)  A combination  of aromatic compounds With eight  or
          more carbon atoms to the  molecule except ethylben-
          zene: 8 per cent.

     (3)  A combination  of ethylber.zene,  ketones having branched
          hydrocarbon structures or toluene:  20  per cent.

     Whenever any photochemically reactive material  or  any constit-
uent of any organic material may'be classified from  its chemical
structure into more than one of the above groups of  organic mater-
ials numbered (1),  (2),  (3), it shall  be  considered  as  a member  of
the most reactive group, that is,that  group having the  least allow-
able per cent of the total organic  materials.
     Portland Cement Process:  Any   facility manufacturing portland
cer.ent by either the wet or dry process .

     PF.M CVol) - (Parts Per Million)  (Volume) :   A volume/volume ratio
which expresses the volumetric concentration  of  gaseous air contami-
nant in a million unit volumes of gas.

     Pressure Tan!;-:  A tank in which  fluids are  stored at a pressure
greater than atmospheric pressure.
                               -27-
     Process:  Any stationary emission source other than a fuel com-
bustion emission source or an Incinerator.

     Process Weight Rate:   The actual weight or engineering approxi-
mation thereof of all materials except liquid and gaseous fuels and
combustion air, introduced into any process per hour. For a cyclical
or batch operation, the process weight rate shall be determined, by
dividing such actual weight or engineering approximation "thereof by
the number of hours of operation excluding any .time during which the
equipment is idle. For continuous processes, the process weight rate
shall be determined by dividing such actual weight or engineering
approximation thereof by • the number of hour's in ons complete operatic:
excluding any tice during which the equipment is idle.

     Residual Fuel Oil:  Fuel oils of grade No. 'H-, 5 and 6 as speci-
fied in detailed requirements for fuel oils A.S.T.M. D39&-69 (1971).

     Restricted Area:  The area within the boundaries of any "munici-
pal itylr~as~de"fTned in the Illinois Municipal Code, plus a zone extend-
ing one mile beyond the boundaries of any such municipality having  s.
population of 1000 or more according to the latest federal census.

     Rlngelmann Chart:  The  chart published and described in the
Bureau of Mines,  U.S. Department of Interior, Information Circular
8333  (Revision of  IC7718) May 1, 1967, or any adaptation thereof whi_
has been approved  by the  Agency.
      Safet;
 is  deslgne
            Relief Valve_:   A valve  which  is  normally closed and which
                       order to  relieve excessive  pressures within a
            to open
vessel or pipe.

     Sandblasting:-  The  use  of a mixture  of sand and air at high
pressures for cleaning and/or polishing any type of surface.

     Set of_ Safety Relief Valves:   One or more safety relief valves
designed to open in order to relieve excessive pressures in the sa::io
vessel or pipe.  •

     Shotblasting:  The use  of a mixture  of any:metallic or non-
metallic substance and air at high pressures for cleaning and/or
polishing any type of surface.

     Smoke:  Small gas-borne particles resulting from incomplete
combustion, consisting predominantly but  not exclusively of carbon,
ash and other combustible material, that  form'a visible plu.-r.a in
the air.
                                                                                                                       -28-

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     S-.okeless Flare:   A combustion  unit and the stack to which it
is affixed in which organic material  achieves combustion by bur.ning
in the atmosphere such that the smoke or- other particulate matter
emitted to the atmosphere from such combustion does not have an appear-
ance, density, or shade darker than No. 1 of the Ringelmann Chart.

     Splash Loading:  A method of loading a tank, railroad tank
car, tank truck or trailer by use of other than a submerged load-
ing pipe.

     Stack:  A flue or conduit, free-standing or with exhaust port
above the roof of the building on which it is mounted, by which
air contaminants are emitted into the atmosphere.

     Standard Conditions:  A temperature of 70°P and a pressure
of 111. 7 pounds per square inch absolute (psia).

     Standard Cubic Foot (SCF):  The volume of one cubic foot of gas
at standard conditions.
     Startup:
any purpose .
The setting in operation of an emission source for
     Stationary Emission Source: An emission source which is not self-
propelled.

     Submerged Loading Pipe:  Any loading pipe the discharge opening
of which is entirely submerged when the liquid level is six Inches
above the bottom of the -tank. When applied to a tank which is
loaded from the side, any loading pipe the discharge of which is
entirely submerged when the liquid level is 18 inches or two times
the loading pipe diameter, whichever is greater, above the bottom
of the tank; This definition shall also apply to any loading, pipe
which is continuously submerged during loading operations.

     Sulfurlc Acid Mist: Sulfuric acid mist as measured according
to the method specified in Rule 20t(g)(2).

     Unregulated Safety Relief Valve: A safety relief valve which
cannot be actuated by a means other "than high pressure in the pipe
or vessel which it protects.

     Volatile Organic Material:  Any organic material which has a
vapor pressure of2.5 pounds per square inch absolute (psia) or
greater at 70°F.

    ' Weak Nitric Acid Manufacturing Process:  Any acid producing
facility manufacturing nitric acid with a concentration of less than
70 per cent by weight.

     Woodworking:  The shaping, sawing, grinding, smoothing, polishing
and making Into products of any form or shape of wood.
                               -29-
                                                                        Rule  202: -Visual Emlss-lon Standards ar.d Limitations.

                                                                             For purposes of this Rule 202, all visual emission opacity
                                                                        standards  and  limitations shall be considered equivalent  to  corre-
                                                                        sponding Ringelmann Chart readings, as described under the defini-
                                                                        tion  of opacity.

                                                                             (a)   Visual Emission Standards and Limitation;  for Certain
                                                                                  Hew  Emission Sources.
                                                                                  (1)
 New Fuel Combustion Emi-sslon Sources wj th Actual Heat
 Input  Greater than 250 Million 3TU CRT. Hour.  No
 person shall cause or allow the omission or sinoko
 or other particulate matter into the atmosphere
 from any new fuel combustion emission source  with
 actual heat  input greater than 250 million btu por
 hour,  having an opacity greater than 2C  per cent.
 Exception: The emissions of sn.cke or other, par-  .
 ticulate matter from any such omission source p.ay
 have an opacity greater than 20 per cent but  not
 greater than 40 per cent for a period or periods
 aggregating  3 minutes in any 60 minute period,
• providing that such more opaque emission permitted
 during any 60 minute period shall occur from  only
 one such emission source located within a 1,000
 foot radius  from the center point-of any other such
 emission source owned or operated by such person,
 and provided further that such more opaque emissions
 permitted from each such fuel combustion emission
 source shall be limited to 3 times in any 2^  hour
 period.
                                                                                  (2)
                                                                                       New  Portland Cement- Processes .
                                                                                                the emiss
                                                                                                                     No
                                   person shall cause
                    on of smoke or other particulate
                                                                                       or allow
                                                                                       matter  from  any new portland  cement process  into the
                                                                                       atmosphere having  an  opacity  greater  than  10  per cent

                                                                             (b)   Visual Emission Standards  and  Limitations  for All  Other
                                                                                  Emission Sources.

                                                                                  No  person shall cause or allow the  emission  of  smoke  or
                                                                                  other particuiate matter from  any  other  emission  source 1:
                                                                                  the  atmosphere of an opacity greater  than  JO per  cer.t.
                                                                                  Exception:   The emission of smoke  or  other particulate
                                                                                  matter from  any such emission  source  may have an  opacity
                                                                                  greater than 30 per cer.t but not greater than 60  per  cent
                                                                                  for  a period or periods aggregating 8 minutes in  any
                                                                                  60  minute period  provided  that such more opaque
                                                                                  emissions permitted during any 60  minute perlo'd shall
                                                                                  occur from only one such emission  source located within
                                                                                  a 1,000 foot radius from the center point  of any other
                                                                                  such emission source owned or  operated by  such  person,
                                                                                                                     -30-

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      ar.fi provided further that such more opaque emissions
      permitted from each such emission source shall be
      limited to 3 times in any 21 hour period.

 (c)  Exceptions to_ Rules 202(a) and 202(b) .

      (1)  Star.tup.

           Rules 202(a) and 202(b) shall apply during times
           of startup except as provided in the Operating
           Permit in Rules 103 and 105.
r
      (2)  Emissions of Water and Water
           Rules 202(a)  and 202(b)  shall not apply to
           emissions of water or water vapor from an emission
           source.

      (3)   Compliance with Rule 203  a- Defense .

           Rules 202(a) and 202(b) shall not apply  if it
           is  shown that the emission source was, at the
           time  of  such emission,  in compliance  with "the
           applicable mass emission  limitations  of  Rule
           203.

 (d)   Determination o_f_ Violations  o_f Rule 202.

      Violations  of Rule 202(a)  and  202(b)  shall be  determined:

      (1)  by  visual  observations; or

      (2)  by  the use  of a calibrated smoke  evaluation device
          approved by  the  Agency as  specified in Rule 106 of
          Parf I of  this  Chapter; or

      (3)  by the use of a  smoke monitor located in the stack
          ard approved by  the Agency as specified in Rule 106
          of Part 1 of  this Chapter.

(e)   Compliance Dates.

     (1)  Every owner or operator of a new emission source
          shall corr.ply with the emission standards  and
          limitations of this Rule 202 on the effective
          date of Part 2 of this Chapter.

     (2)  Every  owner or operator of an existing emission
          source shall comply with the emission  standards and
          limitations of this Rule 202 by December 31, 1972;
         • except that every owner or operator of an emission
          source subject to paragraph (g) of Rule  203, shall
          comply with the emission standards and limitations
          of this Rule 202 by May  30, 1975.
                         -31-
Rule 203: Particulate Emission Standards  and Limitations.

     (a)  Particulate Emission Standards  and Limitations for Uew
          Process Emission Sources.

          Except as further provided in this Rule 203, no persor.
          shall cause or allow the emission of particulate matter
          into the atmosphere in any one  hour period from any
          new process emission source which, either alone or in
          combination with the emission'of particulate matter frorn
          all other similar new process emission sources at a
          plant or premises, exceeds the  allowable emission rates
          specified in Taole 2.1 and in Figure 2.1.
                                         Table 2.1
                       Standards foj? Mew Process Emission Sources
ss Weight Rate
.nds Per Hour
100
200
100
600
800
1,000
1,500
2,000 '
1,000
6,000
8,000
10,000
20,000
30,000
10,000
50,000

Process Weight Rate
Tons Per Hour
0
0
0
0
0
0
0
1
2
3
i
5
10
15
20
25
-32-
.05
.10
.20
.30
.HO
.50
.75
.00
.00
.00
.00
.00
.00
.00
.00
.00

Allowable
Emission Hate
Pounds Per Hou:
0.
0.
1 .
1.
' 1.
1.
2.
2.
3-
14.
5.
6.
3.
10.
. 12.
11.

55
77
10
35
58
75
10
60
70
60
35
00
70
30
50 '
00


-------
                                                                                                               |ible
                                                                                               on R,
Process Weight Rate
  Pounds Per Hour
      60,000

      70,000

      80,000

      90,000

     100,000

     200,000

     300,000

     'too,ooo

  •   500,000

     600,000

     700,000

     800,000

    900,000

  1,000,000
Process Weight Rate
   Tons Per Hour
       30.00

       35.00

       'tO.00

       ^5.00

       50.00

      100.00

    '  150.00

      200.00

      250.00

      300.00

      350.00

      400.00

      450.00

     •500.00
    Allowable
 Emission Rate
Pounds Per Hour

    15.60

    17.00

    18.20

    19.20

    20.50

    29.50

    37.00

    43.00

'    48.50

    53.00

    58.00

    62.00

    66.00

    67.00
                                                                                                        o

                                                                                                  ui o* -^ pp.y

              Interpolated  and extrapolated (up to process weight
              rates of  450  tons per hour)  values of the data
              in Table  2.1  shall be determined by using the''equation:
              where:
                   and
    E = 2.54.CP) °'534

    E = allowable emission rate
        in pounds per hour;

    P = process weight rate in
        tons per hour.
              Interpolated and extrapolated  values  of the data
              of Table 2.1 for process  weight  greater or equal
              to 450 tons per hour shall be  determined using
              the equation:

                             E = 24.8  (P) °-16

                             E = allowable emission rate
                                 in pounds per  hour.  •

                   and       p = process weight rate  in
                                 tons per hour.
                             -33-
                                                                     _•_ • •   '  i  i  ; .11 \ i j	-_ __j ._^-_ i • _.:_  ; _• ;a
                                                        .: II  ::f:!:
                                                     .^i4il(.,Ll^fe^i4:iUi!
                                                     "TMi't- :ii;i;::^i":!'!l"l4'i'il
                                                                                                  • (LI^   ' J j -  - •_mi^ >	• - - >  I - . -
                                                                                                  ••n !Ti"~T S--TT Pri" r

-------
     (b)  Particulate Emission Standards and Limitations for
          Existing Process Emission Sources.'

          Except as further provided in this Rule 203, no person.
          shall cause or allow the emission of particulate matter
          into the atmosphere in any one hour period from any
          existing process emission source which, either alone
          or in combination with the emission of particulate
          matter from all other similar new or existing process
          emission sources at a plant or premises, exceeds
          the allowable emission rates, specified in Table 2.2 and
          in Figure 2.2.
                            Table 2.2

          Standards for Existing Process Emission Sources
Process Weight Rate
  Pounds Per Hour
Process Weight Rate
   Tons Per Hour
    Allowable
 Emission Rate
Pounds per Hour
100
200
100
600
800
1,000
1,5)00
2,000
1,000
6,000
8,000
10,000
20,000
30,000
1)0,000
50,000
0.05
0.10
0.20
0.30
0.10
0.50
0.75
1.00
2.00
3.00
1.00
5.00
10.00
15.00
20.00
25.00
0.55
0.87
1.10
1.83
2.22
2.58
3.38
1.10
6.52
8.56
10.10
12.00
19.20
25.20
30.50
35.10
                             -35-
                                                              Process Weight Rate
                                                                Pounds Per Hour
                                                                                                             Process Weight Rate
                                                                                                               Tons Per Hour
                                                                                          Allowable
                                                                                        Emission Rate
                                                                                       Pounds Per Hour
60,000
70,000
80,000
90,000
100,000
200,000
300,000
100,000
500,000
600,000
700,000
800,000
900,000
1,000,000
30.00
35.00
10.00
15.00 •
50.00
100.00
150.00
200.00
250.00
300.00
350.00
100.00
150.00
500.00
10.00
11.30
12.50
13.60
11.60
51.20
55-10
58.60
61.00
63.10
61.90
66.20
67.70
69-00
                                                                                                     Interpolated  and  extrapolated  values  of the data
                                                                                                     in  Table  2.2  for  process  weight  rates up to 30
                                                                                                     tons  per  hour shall  be  determined by  using the
                                                                                                     equation:
                                                                                                                        4.10 (P)
                                                                                                                                 0.67
                                                                                                     and interpolated and extrapolatea values of the
                                                                                                     data for process weight  rates  in excess of 30
                                                                                                     tons per hour shall be determined by using the
                                                                                                     equation: •
                                                                                                                    E =
                                                                                                                              (?)
                                                                                                                                        _ 40.0
                                                                              where:


                                                                                   and
                                                                                                                    E = allowable emission rate in pounds
                                                                                                                        per hour,

                                                                                                                    P =. process weight rate in tons
                                                                                                                        per hour.
                                                                                                                     36

-------
          ?e
yHMPHh'^jM-^PFpili-li-^h^-qin-jSi
=J^4 = = -^!:.VJ::T7K1"I- hH-i !' im:.\::-^-|-;;-!>'h.i
^



                          •T-
                          rf:


                                           h:t"
                                              8
                                              o
                           ~S
                           -8
                                                                              ^^^^^^^^^^^^^^^
                                                                                     P                  shall comply with paragraph
                                                            It llrtP2 of this Chapter, shall comply with
                                                            (a) of this' Rule 203,  unless both the  following condi-
                                                            tions are met:
                                                                               (1)
                                                                               (2)
                                                                 The  source is in compliance, as  of the effective
                                                                 date of Part 2 of this Chapter,  with tne ter ...s
                                                                 and  conditions of a variance granted by .he Pollu-
                                                                 tion Control Board, or, within ?ixty (60)            -Tfe-5?r5ra}r2Bpran5r2p3U,  |h
                                                                  apply to catalyst regenerators of f ^i^zec c^-iy---
                                                                  converte-s.   No person shall cause or allow .r.e em.L-
                                                                  licn rale from new and existing catalyst regenerator,
                                                                  of fluldized catalytic converters to exceed ~" *f
                                                                  one hour period the rate determined using the follow-
                                                                  ing equations :
                                                                      E=4.10 (P)
E = |_55.0 (P)
                                                                                   0.
                                                                                                        "3-
                                                                                           40
                                                                                                                       for P less than or
                                                                                                                       equal to 30 tons
                                                                                                                       per hour.


                                                                                                                       for P greater than
                                                                                                                       30 tons per hour.
                                                                  where,

                                                                       E = allowable emission rate in pounds per hour.

                                                                       P = catalyst recycle rate,  including the amount
                                                                          of fresh catalyst added,  in tons per hour.
37
                            o
                            o
                            o
                                                                                 -36-

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                        Rule  203(a),  203(b) and 203(c)
(2)   Sinter Processes
     shall
           not  apply  to any  sinter process. No person
     shall cause  or allow  the  emission  of partlculate
     matter  into  the  atmosphere  from  the breaker stack
     of any.  sinter process, to  exceed  the .allowable
     emission rate specified by  Table 2.1 of Rule 203(a).
     No person  shall  cause or  allow the emission of par-
     tlculate matter  into  the  atmosphere from the main
     windbox of any sinter process to exceed 1.2 times
     the allowable emission  rate specified by Table 2.1
     of Rule 203(a).

(3)  Portland Cement  Manufacturing Processes.  Rules 203(a)
     and 203(c) shall not  apply  to the kilns and coolers of
     Portland cement  manufacturing processes..

     (A)  The kilns and clinker  coolers of existing port-
          land  cement manufacturing processes  shall com-
          ply with the emission  standards and limitations
          of Rule 2Q3(b).'

     (B)  The kilns and clinker  coolers of new portiand
          cement manufacturing processes shall comply
          with the following emission standards  and limlt-
          tatlons:

          (1)  No person shall cause or allow  the emis-
               sion of particulate matter Into the
               atmosphere  from any such kiln to  exceed
               0.3 pounds per ton of feed to the kiln.

          (11) No person shall cause or allow  the  emis-
               sion of particulate matter into the
               atmosphere from any such  clinker  cooler
               to exceed-0.1  pounds  per  ton  of feed to
               the kiln.
(1|)   Corn Wet
                      Processes.
     Rules 203(a), 203(b) and 203(c)  shall not apply to
     feed and gluten dryers in corn wet milling processes,
     where the exit gases have a dew  point higher than the
     ambient  temperature and the specific gravity of the
     material processed is less than  2.0. No person shall
     cause or allow the emission of particulate matter In-
     to the atmosphere from any such  process:
                    -39-
     (A)  after the effective date of Part 2 of  this
        . Chapter, so  as  to  exceed 0.3 grain per stand-
         ard  cubic foot  of  effluent gas; and

     (B)  on or after  Kay 30; 1975, so as to exceed the
         emission standards and  limitations specified
         in Rule  203('o) .

(5)   Grinding, Woodworking,  Sandblasting and Shotblastir.t;.

     Rule 203(a),  203(b)  and'203(c) shall not  apply to the
     following Industries, which  shall be subject to Rule
     203(f):

     •(A)  Grinding,

     (3)  Woodworking,

     (C)  Sandblasting or Shotblasting.
                                                                                                         -HO-

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(6)   Coke Manufacturing Processes.

     Rules 203(a), 203(b) and 203(o) shall not apply to
     coke manufacturing processes.

     (A)  Beehive Coke Ovens.  No person shall cause or allow
          the use of beehive ovens  in any coke manufacturing
          process.

     (B)  By-Product Coke Plants.

          (i)  Charging.

               (aa)  Sixty (6C)  days  after the effective
                    date  of Part 2 of this Chapter and until
                    December 31, 1973,  no person  shall
                    cause or allow the  emission of smoke
                    or other particulate matter from any
                    coke  oven  charging  port into  the
                    atmosphere  after withdrawal of the
                    charging sleeve, except for a period
                    or periods  aggregating 20 seconds
                    during any  one coke oven charging
                    operation.  The charge car shall  re-
                    main  over  the charging ports  only  as
                    long  as is  needed to complete the
                    charging operation.

               (bb)  On and after December 31, 1973,  all
                    coke  oven  facilities shall be equipped
                    with  automated,  negative pressure
                    charging systems, or shall employ
                    alternative  methods  of  comparable
                    effectiveness in reducing emissions
                  .during charging;  and  after said  date,
                    no person shall  cause or allow the
                    emission of  visible  particulate
                    matter,  other than  water,  from any
                    coke  oven charging  port  into  the
                    atmosphere,  except  for  a period  or
                    periods  aggregating  15  seconds during
                    any one  coke oven charging operation.
                    During such  charging  operation the
                    emission of  smoke or  other particulate
                    matter  from  the  charging 'port or from
                    the charging' system  into the  atmos-
              1     phere  shall  have  an  opacity -of no
                    greater  than  30  per  cent.
                   -11-
(ii)  Pushing and Quenching.

     (aa)  On and after July  1,  1972,  no  person
          shall cause or allow  the  emission of
          smoke or other particulate  matter,
          other than water,  of  an opacity  greater
          than 30 per cent,  from a coke  manufac-
          turing process quench tower into the
          atmosphere.

     (bb)  On and after December 31, 1971,. all
          coke oven facilities  shall  be  equipped
          with enclosed pushing and quenching
          systems with particulate collection
          equipment, or shall employ  alternative
          methods of comparable effectiveness in
          reducing emission  during pushing and
          quenching.

(iii)Work  Rules. No person shall cause or allow
     the operation c'f a by-product coke  plant
     without operating and maintenance work rules
     approved by the Agency.^Such work rules
     shall be submitted to and  approved "by tne
     Agency no later than 60 days after the
     effective date of Part 2 of this Chapter.
     No such plan shall be approved by the Agenc;
     unless it contains, as a rr.inirnum, inforr.aticr
     sufficient to prove to the Agency that the
     emission of specified air contaminants will
     conform to the requirement of this  Rule 203-

(iv)  Coke  Oven Doors.

     (aa)  On and after July  1,  1972,  no  person
          shall cause or allow  the operation of
          a coke oven that emits any  specified
          air contaminants into t'r.e atmosphere
          during coking frorr. the coke oven door."
          for niore than ten minutes after corr.~or.c-.
          ment of the coking cycle. During such
          ten minutes the emission shall have an
          opacity no greater than 30  per cent.

     (bb)  On and after July.l,  1972,  no person
          shall cause or allow  .the operation
          of a coke oven unless

          (bb-1) there is, on the plant  premises
                 an inventory of spare coke oven
                 doors and seals at all  times,  ar.s
                                                                                                        -12-

-------
                               (bb-2) there is, on the plant
                                     premises, a repair facility
                                     capable of prompt and             
-------
     (3)  No person shall cause or allow the emission of
          partlculate matter Into the atmosphere from all
          other existing incinerators to exceed 0.2 grains
          per standard cubic foot of effluent gases corrected
          to 12 per cent carbon dioxide.'

     (4)  No person shall cause or allow the emission of
          particulate matter into the atmosphere from all other
          new incinerators to exceed 0.1 grains per .standard
          cubic foot of effluent gases corrected to 12 per
          cent carbon dioxide.

     (5)  Exception:  Subparagraphs (1), (2) and (4) of this
          Rule 2C3(e) shall not apply to incinerators which
          burn wood wastes exclusively, if all the follow-
          ing conditions are met:        -   .

          (A)  The emission of partlculate matter from such
               incinerator does not exceed 0.2 grains per
               standard cubic foot of effluent gases corrected
               to 12 per cent carbon dioxide; and,

          (B)  The location of such incinerator is not in
               a restricted area, and is more than 1000
               feet from residential or other populated areas;
               and,

          (C)  When it can be affirmatively demonstrated that
               no economically reasonable  alternative method
               of disposal is available.

(f)   Fugitive Particulate Katter.

     (1)  r;o person shall cause or allow the emission of
          fugitive particulate matter from  any process,  including
          any material handling or storage  activity, that is
          visible by an observer looking generally  toward the
          zenith at a point beyond the property  line of the
          emission source.

     (2)  ;.!o person shall cause or allow the emission of
          fugitive particulate matter from  any process,  including
          any material handling or storage  activity, in such a
          manner that  the presence of such  particulate matter
          shown  to be  larger than forty (40) microns (mean
          diameter) in size exists beyond  the property line of
          the emission source.

     (3)  Rules  203(fJ(D  and 203(f)(2)  shall not  apply  to
          emissions of fugitive particulate matter from stock-
          piles  of materials when the wind  speed is  greater
          than 25 miles per hour.  Determination  of wind speed
          for the purposes  of this rule shall be by  a one-
          hour, average at the nearest official station of the
         U.S.  Weather  Bureau, by interpretation of surface
         weather maps  by  a  meteorologist, or by wind speed.
         instruments installed  on  the  stockpile site.

    CO  No person shall cause  or  allow  the  operation  of
         a vehicle of the second division as  defined by 111.
         Rev. Stat. , Ch. 95 1/2, 51-217, as  revised, or a
         Semitrailer as defined by 111.  Rev.  Stat..  Ch.
         95 1/2, §1-187, as revised, without a covering
         sufficient to prevent the release of partlculate
         matter into the-atmosphere, provided that this
         paragraph  (f)(4) of this  Rule 203 shall not apply
         to automotive exhaust emissions.

     (5)  Except  for the stockpiling of materials, Rule 203(f)
         shall  not.apply to emissions resulting from the-
         manufacture of coke.

     (6)  Rule 203(f)' shall not apply to emissions of water-
         and water vapor from cooling towers .

(g)   Partlculate E-ission Standards  and  Limitations for Fuel
     Combustion  Emission Sources.

     (1)  Fuel Combustion Emission Sources Using Solid
         Fuel Exclusively.

         (A)  Existing  Fuel Combustion  Emission Sources  Us in,;
              Solid Fuel Exclusively  Located  in t'r.j Cr.ioaro
              Major Me t ropo111 an  Area.  Mo person shall cause
              or allow  the emission of  particulate matter
              into the  atmosphere  from  any  existing fuel com-
              bustion  source using  solid  fuel exclusively,
               located in the Chicago  major  metropolitan  area,
               to exceed 0.1  pounds  of particulate -.atter per
               million bta of actual heat  input in any one hour
               period except  as provided in  sub-paragraph (C)
               of this Rule 203 (g)(l).

          (B)  Existing Fuel  Combustion  Emission Scurces  Usl.nr-
               Solid Fuel Exclusively  Located Outs '.dc.  r.he
               Chicago Major Metropolitan Area. No person
               shall cause or allow the  emission of  particular
               matter into the  atmosphere from any existing  fu-
               combustion source using solid fuel exclusively,
               located outside the Chicago major metropolitan
               area, to exceed the limitations specifier in
               Table 2.4 and Figure 2.3 in any one hour period
               except as-provided in sub-paragraph (C) of this
               Rule 203(g)(l):
                         -45-
                                                                                                              -46-

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                            Table 2.1|
Fuel Combustion Emission Source
       Actual Heat Input
     million btu per hour

less than or equal to 10

greater than 10'but smaller than 250



greater than or equal to 250
Allowable Emlsilon Standard
   pounds per million btu

            1.0
         
            5.18
               0.715
                                                0.1
          Ss = allowable emission standard in pounds
               per million btu of actual heat Input

          Hg = actual heat Input, million btu per hour

          (C)  Existing Controllejj Fuel  Combustion Emission
               Sources 'Using Solid Fuel  Exclusively.

               Notwithstanding sub-paragraphs (A) and (B)
               of this Rule 203(g)(l), any existing fuel
               combustion source using solid fuel exclu-
               sively ir.ay emit up to, but not exceed,  0.2
               pounds per million btu, if, as of the effec-
               tive date of Part 2 of this Chapter,  either
               of the following conditions is met:

               (1)   The  emission source  has  an emission
                    rate based on original design or equip-
                    ment performance test conditions,  which-
                    ever is stricter, which  is  less  than
                    0.2  pounds per million btu  of actual
                    heat input,  and the  emission  control
                    of such source is not allowed to degrade
                    more than  0.05 pounds per million  btu
                    from such  original design or  accept-
                    ance performance test conditions;  or,

               (ii)  The  source is  in full compliance with
                    the.  terms  and  conditions  of a variance .
                    granted by  the Pollution  Control Board
                    sufficient  to  achieve an  emission  rate
                    less  than  0.2  pounds  per  million btu,
                    and  construction has  commenced on
                    equipment  or modifications  prescribed
                              -17-
                  under that program; and emission con-
                  trol of  such  source is not allowed to
                  degrade  more  than  0.05 pounds  per mil-
                  lion btu from original design  or equip-
                  ment performance test  conditions, which-
                   ever  is  stricter.

         (D)  New Fuel Combustion Emission Sources Us in?
              Solid Fuel  Exclusively.

            '  No person shall cause or allow the emission  of
              particulate  matter into'the atmosphere in any
              one hour period from any new fuel  combustion
              emission source using solid- fuel exclusively,
              to exceed 0.1 pounds of particulate matter per
              million btu  of actual heat input.

PROVISO:   Nothing in this rule  203(g)(l) shall be construed to
          apply  in any manner  inconsistent with the following
          paragraph  8(5)  of an  order  of  the Circuit Court of
          Cook County dated April 13,  1972  in  ?ase no.  72 CH

                    "The  defendants,  and  each  of  them,  their
               agents, employees, and attorneys,  are  hereby
               restrained for  a period .of ten  days from the date
               hereof from (1)  adopting or from  (2)  holding or
               conducting,  scheduling or rescheduling public
               hearings  pertaining to the adoption of proposed
               Rule 203(g)(l)(A) of the Illinois Pollution Control
               Board  and so much of proposed Rule 203( .3) (1) (C)
              . of the Illinois  Pollution Control Board as  pertains
               to proposed Rule  203(g)(1)(A), insofar as such
               rules  pertain to the use of coal  as a source of
                fuel in residential and commercial buildings in
                the  Chicago Major Metropolitan Area, or  frc:r.
                (1)  adopting or from  (2) holding  or conducting
                public hearings  to adopt  a  rule which vioulci elim-
                inate or  ban the use  of coal  as  a source  cf fuel
                in residential  and commercial  buildings in  the
                Chicago  Major  Metropolitan Area as such area is
                defined  by  the Illinois Pollution Control Board,
                unless there is a provision in said proposed rule
                for Just  compensation to owners of businesses in
                the class  represented by plaintiffs and to owners
                of  commercial and residential buildings whose
                property rights would be affected by said  rule
                wherever said rule is effective.".

            And such further orders as may be entered by the Court..
                                                                                                                       -1(8-

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                                                                                    i EalSHSSs,
                                                                                                               Ecu
                                                                                                                         He,
      Fuel Combustion  Erni_ssicn Sources Using: Llauid F,,»i'
      e£s»lonelf'  N°^^f^rauiirSf aT^tEe^

      In any one hour  periodetmatter lnt° the atmosPnere
      na-«f--i1^!i"i =•»-«.   4, *.         •  "xceeQ u. J.O pounds of*
      paniculate matter per million btu of actual heat
(3)  ^T75?^^1EjST5iSJ1 Sources'using More Than
                               e«««  of the  following
          E = allowable particulate emission
              rate in pounds per hour;

          Ss=solid fuel partulate emission   '
              standard which is applicable, pounds
              per  million btu of actual heat input;

          Hs=~actual heat Input from solid
              fuel in million btu per hour; and
                     heat  input  from liquid
              fuel in million  btu  per hour.

CO  Aggregation of Existing Fuel  Combustion Sources.'

     Rule 203(g)(3)'may be applied to the  aggregate  of
     an luej. coir.nustion emission  sources  vented to  a
     common stack provided that  after January 26,  1972:

     (A)  ductwork has not been  modified so as  to  inter-
          connect such existing  fuel  combustion emission
          sources;

     (B)  the actual heat input to  any such  existing
          fuel combustion emission  source  is  not in-
          creased;  and,

     (C)  no  new  fuel combustion emission  source is
          added  to  reduce the degree of control of
          emissions  of particulate matter  required bv
          paragraph  (g)  of this Rule 203.
                    -49-.
                                                                           I
                                                                                o
                                                                                b
                                                                                                                Ul 9 < 09W-
                                                                                   £;p.=T-


                                                                                       *?•'  I • i—M-4-J-+-
                                                                                                  £ ~:

                                                                                               :::|:;£j.-j-: 70|?pMi^£: f ;;:l";:f,Zi.!


                                                                                                                                       -niU °
~~>.
i il

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(h)  Measurement Methods.   Particulate emissions from station-
     ary emission sources  subject to Rule 203, shall be deter-
     mined by the procedures described in the ASMS Power Test
     Code 27-1957 as revised from time to time, or by any
     other equivalent procedures approved by the Agency.

(1)  Compliance Dates.

     (1)  Every owner or operator of a new emission .source
          shall comply  with the standards and limitations
          of Rule 203 of the effective date of Part 2 of this
          Chapter.

     (2)  Except as otherwise provided in paragraph (d)(1),
          (d)(6), (i)(3),  (i)(1), and (1)(5) of this Rule
          203, every owner or operator of an existing emission
          source shall  comply with the standards and limita-
          tions of Rule 203 by December 31, 1973.

     (3)  Every owner or operator of an existing emission -
          source subject to paragraph (f) of this Rule 203
          shall comply- with the standards and limitations of
          this Rule 203:

          •(A)  six months  after the effective date of Part 2
               of this  Chapter when the emissions from such
               source are  caused by the stockpiling of mate-
               rials;

          (B)  six months  after the effective date of Part 2
               of this  Chapter for emission sources subject
               to paragraph (f)(1) of this Rule 203; and

          (C)  one year after the effective date of Part 2
               o'f this  Chapter for all other emission sources
               subject  to  paragraph (f)  of this Rule 203.

     (1)  Every owner or operator of an exising emission
          source subject to paragraph (g) of this Rule 203
          shall comply  with the standards and limitations
          of Rule 203 by May 30, 1975.
a
(5)   Notwithstanding  any  other provisions of Rule 203
     of this  Part  2,  every  owner or operator of an
     existing emission  source which:

     (A)  is  required to  comply with  Rules  2-2.51,
          2-2.52,  2-2.51, 3-3.111,  3-3-2110., 3-3.2130
          and 3-3.220 of  Rules ana  Regulations Governing
          the Control of  Air Pollution  as amended Aguust
          19, '1969;  and

     (B)  which is In compliance with such  rules, as of
          the effective date of this  Chapter, or  is 'in
          compliance  with paragraphs  203(c)(l) and  (2)
          of  this  Chapter.

     shall comply  with  the  applicable emission standards
     and limitations  of this Rule 203,  by May. 30, 1975-
                         -51-
                                                                                                              -52-

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Rule 201: Sulfur Standards and Limitations.

     (a)  Sulfur Dioxide Emission Standards  and Limitations  for New
          Fuel Comb use! en Emission Sources with Actual Heat  Input
          Greater than 250 Million Btu per Hour.

          (1)   Solid Fuel Burned Exclusively.  No  person shall
               cause or allow the emission of  sulfur dioxide into
               the  atmosphere in any  one hour  period from any new
               fuel combustion emission source greater than 250
               million btu per hour,  burning solid  fuel exclusively,
               to exceed 1.2  pounds of sulfur  dioxide  per million
               btu  of actual  heat input.

          (2)   Liquid Fuel Burned Exclusively.  No  person shall
               cause or allow the emission of  sulfur dioxide into
               the  atmosphere In any  one hour  period from any new
              - fuel combustion emission source  greater than 250
               million btu per hour,  burning liquid fuel
               exclusively;

               (A)   to exceed 0:8 pounds  of  sulfur  dioxide per
                    million btu of actual heat  input when residual
                    fuel oil  is burned;  and

               (B)   to exceed 0.3 pounds  of  sulfur  dioxide per
                    million btu of actual heat  input when distillate
                    fuel oil  is burned.

    (b)  Sulfur  Dioxide Emission Standards  and Limitations, for
         tiew  Fuel  Combustion  Emission  Sources with Actual Heat
         Inout Smaller  Than,  or  Equal  to., 25_0 Million Btu per
         (1)  Solid Fuel Burned Exclusively.  No person shall
              cause or allow the emission of sulfur dioxide into
              the atmosphere in any one hour period from any new
              fuel combustion source with actual heat input
              smaller than, or equal to, 250 million btu per hour,
              burning solid fuel exclusively, to exceed 1.8 pounds
              of sulfur dioxide per million btu of actual heat
              input.

         (2)  Liquid Fuel Burned Exclusively.  No person shall
              cause or allow the emission of sulfur dioxide into
              the atmosphere in any one hour period from any new
              fuel combustion source with actual heat input small-
              er than, or equal to, 250, million btu per hour,
              burning liquid fuel exclusively;

              (A)  to exceed 1.0 pounds of sulfur dioxide per
                   million btu of actual heat input when residual
                   fuel oil is burned; and
                             -53-
          (B)   to exceed 0.3 pounds of sulfur dioxide per
               million btu of actual heat input when distillate
               fuel  oil is burned.

(c)   Sulfur Dioxide  Emission. for Existing Fuel Combustion Source::

     (.1)   Solid Fuel Burned Exclusively.

          (A)   Existing- Fuel Combustion Sources Located ln_ the
               Chicago, . S t. • Louis  (Illinois) and  Peoria i-ia.jor
               Metropolitan Areas '.  No person shall  cause or
               allow the emission  of sulfur dioxice  Into the
               atmosphere In any one hour period  from any
               existing fuel combustion source, burning solid
               fuel  exclusively, located in the Chicago. St.
               Louis (Illinois) and Peoria major  metropolitan
               areas, to exceed 1.8 pounds of sulfur dioxide
               per million btu of  actual heat Input, on or after
               May 30, 1975.

          (B)   Existing Fuel Combustion Sources Located Cut si (.:•-;
               the_ Chicago, St. Louis  (Illinois)  and Peoria
               K.a.jor Metropolitan  Areas. N'o person shall
               cause or allow the  emission of sulfur dioxide
               into  the atmosphere in  any one hour period
               from  any existing  fuel  combustion  source, burnin-:
               solid fuel  exclusively,  located outside  the Chic;.
               St. Louis  (Illinois) and Peoria major metropolit.T
               areas, to exceed the following:

               (1)   6.0 pounds of  sulfur dioxide  per million
                    btu of actual .heat input, on  and after
                    Kay 30, 1975;.and

               (ii)  1.8 pounds of  sulfur dioxide  cer million
                    btu of actual  heat input for  all such
                    fuel combustion emission sources located
                    within any MKA other than Chicago,  Peoria,
                    and St. Louis  (Illinois) which,  according
                    to any one arr.bient air monitoring station
                    operated by or under supervision and control
                    of the Agency  within such MilA, has  an  annual
                    arithmetic average sulfur dioxide level
                    greater  than;

                        60  ug/m'  (0.02 ppm) for  any year
                        ending prior  to May 3C,  1976,  or

                         15  ug/m3  (0.015 ppm) for ar.y year
                        ending en or  after May 30,  1976.

                    Compliance.with this paragraph (11) of
                    Rule  204(c)(l)(B)  shall be on and after
                    three years from the date upon which the
                    Board promulgates  an Order for Compliance.

                         -51-

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                    Before promulgation of such Order for
                    Compliance, the Board shall:

                    (aa) publish in the Board Newsletter,
                         within 21 days of receipt from the
                         Agency, a proposed Order for Compli-
                         ance along with the data used to
                         obtain said -annual arithmetic
                         average sulfur dioxide level; and,

                    (bb) serve a copy of such proposed Order
                         and supporting data, within 21 days
                         of receipt from the Agency, upon
                         the owner or operator of each such
                         emission source located within the
                         HHA; and,

                    (cc) defer promulgation of the Order for
                         Compliance for at least ^5 days
                         from the date of publication to
                         allow submission and consideration
                         of additional written comments.

     (2)  Liquid Fuel Burned Exclusively. No person shall
          cause or allow the emission of sulfur dioxide into
          the atmosphere in any one hour period from any •
          existing fuel combustion emission source, burning
          liquid fuel exclusively;

          (A)  to exceed 1.0 pounds of sulfur dioxide per
               million btu of actual heat input when residual
               fuel oil is burned; and,

          (B)  to exceed 0.3 pounds of sulfur dioxide per
               million btu of -actual heat input when distillate
               fuel oil is burned.

(d)   Combination o_f Fuels.  Mo  person shall cause or allow  the
     emission of sulfur dioxide into the atmosphere in any
     one hour period from" any fuel combustion emission source
     burning simultaneously any combination of solid, liquid
     and gaseous fuels to exceed the allowable emission rate
     determined by the following equation:
                     0.3 Kd + SRKR
     where:
          Z = allowable sulfur dioxide emission rate,  in pounds
              per hour;

          Ss= solid fuel sulfur dioxide- emission standard,  in
              pounds per million btu, which is applicable;

          SR= residual fuel oil sulfur dioxide emission standard,-
              in pounds per million btu, which is applicable;

                         -55-
                Hs=actual heat input from solid fuel,  in million
                   bta per hour;.

                HR=actual heat input from residual fuel oil, in
                   million btu per hour;

                H^actual heat input from distillate fuel oil, in
                   million btu per hour;

          and where that, portion of the actual heat input that i:;,
          derived:

     (1)  from the 'burning of gaseous fuels produced by z'ne
          gasification of solid fuels shall be Included ir. Hs;

     (2)  -from the burning of gaseous fuels produced by the
          gasification of distillate fuel oil shall be included
          in Hd;

     (3)  from the burning of gaseous fuels produced by the
          gasification of residual fuel oil shall be Included
          in HR;

     CO  from the burning of gaseous fuels produced by. the
          gasification of any other liquid fuel shall be included
          in HR; and,

     (5)  from the burning of by-product gases such as those
          produced from a blast furnace or a catalyst .rcger.enticr;
          unit in a petroleum refinery shall be included in
          H.
           'R.
(e)
Combination of Fuel Combustion Emission'Sources .
shall cause or a
                                                      No person
                                                     ur dioxl.de
                     LJ.OW the total emissions of su
     into the atmosphere in any one hour period from all fuel
     combustion emission sources owr.ed or operated by such
     person and located within a i mile radius from the center
     point of any such fuel combustion emission source to ex-
     ceed the emissions determined by the following equations:

          E = 20,000
                       300
                                Pn Hn
                                                                                                         100
                                                                                                                 (Note:
                                                                                                                                      *? =100)
wher.e:    E = total emission of sulfur dioxide,  in pounds per
              hour, into the atmosphere in any one hour period
              from all fuel combustion emission sources owned  '
              or operated by such person and located within a
              1 mile radius from the center point of any such
              emission source.
                              -56-

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Hi,l
                 ijS, .  .  .  , n = percentage of total emissions
                • E emitted from source 1;

                 1,2, .  .  .  , n = physical height in feet above
                 grade of  stack 1.
(f)   Sulfur Standards and Limitations for Process  Emission
     Sources .

     (1)   Sulfur Dioxide Standards and Limitations .

          (A)   Except as further provided by paragraphs
               (f)(l)(B), (f)(l)(C)  and (f)(l)(D)  of this  Rule
               201,  no person shall cause or allow the  emission
               of sulfur dioxide into the atmosphere from  any.
               process emission source to exceed 2000 ppm.

          (B)   Paragraph (f)(l)(A) of this Rule 201  shall
               not apply to new sulfuric acid manufacturing
               processes. Mo person shall cause or allow the
               emission of sulfur dioxide into the atmosphere
               from any new sulfuric acid manufacturing plant
               to exceed 1.0 pounds of -sulfur dioxide per  ton
               of acid produced.

          (C)   Paragraph (f)(l)(A) of this Rule 201  shall  not
               apply to processes designed to remove sulfur
               compounds from the flue gases of fuel combustion
               emission sources.

          (D)   Paragraph (f)(l)(A) of this Rule 204  shall  not
               apply to existing processes designed  to remove
               sulfur compounds from the flue gases  of
               petroleum and petrochemical processes, providing
               that  the sulfur dioxide emissions from such removal
               processes do not exceed the emissions determined
               by the equations of Rule 204(e) .

     (2)   Sulfuric Acid Mist Standards and Limitations .

          Ko person shall cause or allow the emission of sulfuric
          acid mist  into the atmosphere from any process emission
          source to  exceed 0.15 pounds of acid mist  per ton of
          acid used or manufactured.

(g)   Measurement Methods .

     (1)   Sulfur Dioxide .Measurement .

          Measurement of sulfur dioxide emissions  from stationary
          sources shall be made according to the procedure
          published in 36 Fed. Reg.  21890, Method  6, or by
                         -57-
                                                                           (h)
     measurement  procedures  specified by  the  Agency
     according  to the  provisions of Part  1 of this Chapter
     and application of  standard emission factors  as
     published  in Public Health Service  Publication  999-
     AP-12,  Compilation  of Air Pollutant  Emission  Factors,
     as revised from time to time.

(2)   Sulfuric Acid Hist  and Sulfur Trioxide  Measurement.

     Measurement  of sulfuric acid mist  and sulfur  trloxido
     shall be according  to the Barium-thcrin titration
     method as  published in 36 Fed. Reg.  21593.

(3)   Solid Fuel Averaging Measurement.

     If low sulfur solid fuel is used to  comply  with.
     subparagraphs (a),  (b), (c), and (d) of this  Rule 201,
     the applicable solid .fuel sulfur dioxide standard
     shall be met by a two month average  of  daily  samples
     with 95 per  cent  of the samples being no greater
     that 20 per  cent  above the average.  A.S.T.H.  pro
     cedures shall be  used for solid  fuel sampling,  sulfur
     and heating value determinations.

 Compliance Dates.

(1)   Every owner  or operator of a new emission source
     shall comply with the standards and  limitations of Rul-:
     201 by the effective dace of Part  2  of  this Chapter.

(2)   Every owner  or operator of an existing  fuel combust lor.
     emission source shal?. comply with  the standards and
     limitations  of Rules 20l(c)(1)(A) ,  20l(c)(2),  ?0^(d)
     ar.d 20l(e) by Kay 30, 1975.

(3)   Every owner or operator of an existing  process  emissic:
     source shall comply with the standards  and  limitations
     of Rule 20l(f) by December  31, 1973.
                                                                                                     -58-

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.Rule  205: Organic  Material  Emission Standards  and Limitations.

      (a)  Storage.   No  person  shall cause  or allow tne storage of
          any  volatile  organic material  in any stationary tank,
          reservoir  or  other container of  more than  ^0,000 gallons
          capacity unless such tank,  reservoir or other  container:

          (1)   is  a  pressure tank  capable  of withstanding the
                vapor pressure  of such materials, so  as to prevent
                vapor or gas loss to the  atmosphere at all times; or,

          (2)   is  designed  and equipped  with one of  the  following
                vapor loss control  devices:

                (A)   A floating roof which  rests on the surface of
                     the volatile organic material and is equipped
                     with a  closure seal  or seals to  close the space
                     between the roof  edge  and  the tank wall.  Such
                     floating  roof  shall  not be permitted if  the
                     volatile  organic  material  has a  vapor pressure of
                     12.5 pounds per square inch absolute or  greater at
                     70°F.   Mo  person  shall cause or  allow the emission
                     of air.  contaminants  into  the atmosphere  from any
                     gauging or sampling  devices attached to  such
                     tanks,  except  during sampling.

                (B)  A vapor recovery  system  consisting of:

                     (1)  a  vapor gathering system  capable of col-
                          lecting 85/5  or  more  of  the  uncontrolled
                          volatile  organic  material  that  would be
                          otherwise emitted to  the atmosphere; and,

                     (11) a vapor disposal  system capable of "pro-
                          cessing such volatile organic material
                          ao as to  prevent_ their emission to  the
                          atmosphere.  No  person shall cause  or
                          allow the emission  of air  contaminants
                          into the  atmosphere  from  any  gauging
                          or sampling'devices  attached  to such
                          tank, reservoir or  other  container except
                          during sampling.

                (C)  Other  equipment  or means  of equal  efficiency
                     approved by the  Agency according to  the
                     provisions of Part 1 of this  Chapter 3; or,

           (3)  is an existing cone roof tank used exclusively for the
                storage of  Illinois crude oil, if all the following
                conditions  are met:
                                -59-
         (A)  The vapor pressure of such crude oil is less
              than 5 pounds per square inch absolute (psia);
              and,

         (B)  the location of such tank is outside a major
              metropolitan area; and,

         (C)  such tank  is equipped with positive pressure
              tank vent  valves  and vacuum breakers.
(b)
     (1)   No  person shall  cause or allow  the  discharge of r.orc
          than 8 pounds  per hour of organic material into
          the atmosphere during the loading of any organic -at'-
          .rial from the  aggregate loading pipes of any loadi.-v-
          facility having a throughput, of greater than 1)0,000
          gallons per day  into any raiiroad tank car, tank
          truck or trailer, unless each such  loading pipe is
          equipped with air pollution centre! ed.uipnent capa'ole
          of reducing by 85 per cent or 'more  the uncontrolled
          organic material that would be othersviss fcrr.itted to
          the atmosphere if splash loading were employed.

     (2)  No person shall cause or allow the loading of any
          organic material into any stationary tank having a
          storage capacity of greater than 250 gallons, unleo-
          such tank is equipped with a permanent  submerged
          loading pipe or an equivalent device approved
          by the Agency according to the provisons y>?  Part
          1  of this Chapter, or unless such tank  is' a  pressure
          tank as described in Rule 205(a)(l)  or  is' fitted
          with  a recovery  system  as descrloect  in  Rule  205(a)('

      (3)  Exception:  If  no odor  nuisance exists  the  linitat I-..
          of subparagraph (b)  of  this  Rule 204 shall only up:, i.
          to volatile organic  ~,aterlal.

 (c)   Organic Material-Water Separation.

      (1)  No person shall use  any slnglelor multiple  compart-
          ment  effluent .water separator  which receives  efflu'.
          water containing 200 gallons a day or more of organ!
          material from any equipment processing, refining,
           treating, storing,  or handling organic material
           unless such effluent water separator is equipped
           with air pollution  control equipment capable of
           reducing by 85 per  cent or more the uncontrolled
           organic material emitted to the atmosphore.
           Exception:  If no odor nuisance exists the lir.itatlc
           of this Rule 205(c)(l) shall only  apply to volatile-
           organic material.
                                                                                                                        -60-

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     (2)  Rule 205(c)(l) shall not apply to'water and crude
          oil separation in the production of Illinois crude
          oil, if both the following conditions are met: •

          (A)  The vapor pressure of'such .crude oil is less
               than 5 pounds per square inch absolute (psia);
               and,

          (3)  The location of such tank is outside a major
               metropolitan area.

(d)  Pumps and Compressors.  No person shall cause or allow
     the discharge of more than two cubic inches of liquid
     volatile organic Material into the atmosphere from any
     pump or compressor in any 15 minute period at standard
     conditions.

(e)  Architectural Coatings.   No person shall cause or allow
     the sale or  use in the Chicago or St..Louis (Illinois)
     Major Metropolitan Areas of any architectural coating
     containing nore than 20 per cent  by volume of photo-
     chenically reactive material in containers having a
     capacity of  more than one gallon.

(f)  Use of Organic Material.  Ho person shall cause or allow
     the discharge of more than 8 pounds per hour of organic
     material into the atmosphere from any  emission source,
     except as provided in paragraphs  (f)(l) and (f)(2)  of this
     Rule 20S and the following:   Exception:  If no odor nuisance
     exists the limitation of this Rule 205(f) shall apply
     only to photocheniically  reactive  material.

     (1)  Alternative Standard.   Emissions  of organic  material
          in excess of those  permitted  by Rule 205(f)  are•
          allowable if such emissions are controlled by  one
          of the  following methods:

          (A)   flame,  thermal or  catalytic  incineration  so
               as either to reduce such emissions  to 10  ppm
               equivalent  methane- (molecular weight  16)
               br less,  or to convert 85 per cent  of the hy-
               drocarbons  to  carbon dioxide  and water;  or,

          (B)   a  vapor recovery system  which adsorbs and/or
               absorbs  and/or condenses at  least  35  per  cent
               of the  total uncontrolled organic  material  that
               would  otherwise be  emitted to the  atmosphere;
               or,

          (C)   any  other air  pollution  control equipment ap-
               proved  by the  Agency  capable  of reducing by  85
               per  cent  or more the  uncontrolled  organic material
               that would  be  otherwise  emitted to  the  atmosphere.
                         -61-
    (2)  Exceptions:   The.provisions of Rule 205(f) shall
         not apply to:'        •

         (A)  the spraying or use of insecticides, herbicides,
              or other pesticides;

         (B)  fuel combustion emission sources;

         (C)  the application of paving asphalt and pavement
              marking palr.t from sunrise to sunset and when   a
              air pollution watch,  alert or emergency conditions
              are not declared;

         (D)  any owner, operator,  user or manufacturer 'of
              paint, varnish, lacquer, coatings or prLr.tir.g
              ink whose Compliance  Program and Project Com-
              pletion Schedule, as  required -by Part  1 of
              this Chapter, provides  for the  reduction of
              organic material used .in such process  to 20
              per cent or  less of total volume by  May  3'J,
              1975-

(g)  Waste  Gas Disposal..

     (1)  Petroleum Refinery and  Petrochemical Manufacturing
         Process  Emissions. h'o person shall  cause  or ailcw
         the discharge of  organic materials  into  the at-oaohcro
          from:

          (A)  any  catalyst regenerator of  a petroleum crack-
               ing  system;  or,

          (B)  any  petroleum fluid coker; or,

          (C)  any  other waste  gas stream  from any  petroleum
               or petrochemical manufacturing process;

          in excess of 100  ppm equivalent methane (molecular
          weight 16.0).

     (2)  Vapor Slowdown.   No  person shall  cause or allow the
          emission of organic  material into the atmosphere frc:r.
          any vapor blowdown system or any  safety relief valve,
          except such safety relief  valves  not capable of
          causing an excessive release, unless such emission
          is controlled:

          (A)  to 10 ppm equivalent  methane (molecular weight
               16.0)  or less;  or,

          (B)  by combustion in a smokeless flare; or,

          (C)  by other air pollution control equipment approved
               by the Agency according to the provisions of Part
               1 of this  Chapter.
                                                                                                                 -62-

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      (3)
Sets c_f Unregulated Safety Relief Valves Capable of
Causing Excessive Releases,  Rule 205(g)(2) shall
not apply to any set of unregulated safety relief
valves capable of causing excessive releases,, provided
that the owner or operator thereof,.by-October 1,
1972, provides the Agency with the following.
          (A)
          (B)
          (C)
     an historical record of each such set (or, if such
     records are unavailable, of similar sets which,
     by virtue of operation under similar-circumstances,
     may reasonably be presumed to have the same or
     greater frequency of excessive releases) for a
     three-year period immediately preceding'October 1,
     1972,  indicating:

     (i) dates on which excessive releases occurred
         from each such set; and,

     (11) duration in minutes of each such excessive
         release; and;

     (lil)quar.tities (in pounds)  of mercaptans
         and/or hydrogen sulflde emitted  into  the
         atmosphere during each  such excessive
         release.

     proof,  using such three-year historical  records,
     that no excessive release is likely to occur from .
     any such  set either alone or in combination with
     such excessive  releases  from other sets  owned
     or  operated  by  the  sair.e  person  and located within
     a  ten-mile radius from the center point  of any
     such set,  more  frequently than  3 times in any
     12  month  period;  and

    accurate maintenance records pursuant to the
    requirements of paragraph  (g)(3)(A) of this Rule
    205 of  this Chapter; and
         (D)  proof, at three-year Intervals, using such
              three-year historical records, that such set
              conforms to the requirement of paragraph (g)(3)(C)
              of this Rule 205. '

(h)  Emissions During Clean-up Operations and Organic Material
    Disposal.  Emissions of organic material released during
    clean-rup operations and disposal shall be Included with
    other emissions of organic material from the related
    emission source or air pollution control equipment
    determining total emissions.
                          -63-
                                                                                       (1) "  Testing Method' for  Determination of Emissions of_
                                                                                            Organic Material.   The  total  organic material'
                                                                             o
concentrations in an effluent strean shall be measured
by a Flame lonization Detector,  or by other methods
approved by the Agency according to the provisions of
Part 1 of this Chapter.

Compliance Dates .
                                                                                            (1).  Every  owner  or  operator  of. a  new  emission  source
                                                                                                 shall  comply with  the  standards and  limitations
                                                                                                 of Rule  205  on.  the effective- date of Part  2  of
                                                                                                 this Chapter.

                                                                                            (2)   Every  owner  or  operator  of an existing  emission
                                                                                                 source shall comply with the  standards  and
                                                                                                 limitations  of  Rule 205  by December  31,  1973.
                                                                                                                  -61-

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Rule 206: Carbon Monoxide Emission Standards and Limitations.
     (a)
     Fuel Combustion Emission Sources With Actual Heat Incut     -  (
     Greater Than .10 Kllllon 3tu Per Hour.  No person shall"
     cause or allow the emission of carbon monoxide into the
     atmosphere from any fuel combustion emission source with
     actual heat Input greater than 10 million btu per hour to
     exceed 200 ppm, corrected to 50 per cent excess air.

(b)   Incinerators.   No person shall cause or allow the emission
     of carbon monoxide into the atmosphere from any incinerator
     to exceed 500 ppm, corrected to 50 per cent excess air.
     Exception:  This Rule 206(b) shall not apply to existing
     incinerators burning less than 2000 pounds of refuse per
     hour which are-in compliance with Rule 203 (e)(3).

(c)   Petroleum and Petrochemical Processes. No person shall
     cause or allow the emission of a carbon monoxide waste gas
     stream into the atmosphere from a petroleum or petrochemical
     process unless such waste gas stream is burned in a direct
     flame afterburner or carbon monoxide boiler so that the
     resulting concentration of carbon monoxide in such waste
     gas stream is less than or equal to 200 ppm corrected to
     50 per cent excess air, or such waste gas stream is controlled
     by other equivalent air pollution control equipment approved
     by the Agency according to the provisions of Part 1 of
     this Chapter.

(d)   Sintering; Plants, Blast Furnaces and Basic Oxygen Furnaces.
     No cerson shall cause o"r allow the emission of eases contain-
          No person shall cause or allow the emission o
          Ing carbon nonoxide into the atmosphere from any sintering
          plane, from any blast furnace, or from any basic oxygen
          furnace to exceed a concentration of 200 ppm, corrected
          to 50 per cent excess air.  Exception:   This Rule  ••
          2C6(d) shall not apply to blast furnaces during abnormal
          movement of the furnace burden when it is necessary, to
          relieve pressure for safety reasons.

     (e)  Cupolas.  No person shall cause or allow the emission of
          gases containing carbon monoxide into the atmosphere from
          any cupola with a manufacturer's rated melt rate in excess
          of 5 tons per hour, unless such gases are burned in a direct
          flame after burner so that the resulting concentration of
          carbon monoxide In such gases is less than or equal to 200 ppm
          corrected to 50 per cent excess air or such gas streams
          are controlled by other equivalent pollution control
          equipment approved by the Agency according to the provisions
          of Part 1 of this Chapter.
-:  O
(f)   Measurement  Methods.   Carbon monoxide  concentrations in
     an effluent  stream shall  be  measured by the  Jlon-
     dlspersive  Infrared  Method or by other methods approved
     by the Agency  according to the provisions  of Part I of
     this Chapter.

(g)   Compliance  Dates.

     (1)  Every  owner or  operator of a new  emission source
          shall  comply with the standards and limitations of
          Rule 206  by the effective date 'of Part  2 of this
          Chapter.

     (2)  Every  owner or  operator of an existing  emission
          source  shall comply  with the standards  and
          limitations of  Rule  206 by December 31, 1973.
                                -65-
                                                                                                                     -66-

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Rule 207: Nitrogen Oxides Eelssion Standards and limitations.

     (a) . N'ew Fuel Combustion Emission. Sources.  No person shall
          cause or allow the emission of nitrogen oxides into the
          atmosphere in any one hour period from any new fuel-
          combustion emission source with an actual heat Input
          equal to or greater than 250 million- btu per hour to
          exceed the following standards and limitations:

          (1)  for gaseous fossil fuel firing, 0.20 pounds per
     "•         million btu of actual heat input;

          (2)  for liquid fossil fuel firing, 0.30 pounds per
               million btu of actual heat input;

          (3)  for dual gaseous and liquid fossil fuel firing,
               0.30 pounds per million btu of actual heat input;

          CO  for solid fossil fuel firing, 0.7 pounds per
               million btu of actual heat input; and

          (5)  for fuel combustion emission sources burning
               simultaneously any combination of.solid, liquid
               ar.d gaseous fossil fuels an allowable emission
               rate shall be determined by the following
               equation:

                            /0.3 (Pg + PI)  + 0.7  (Ps)\
               where:     E = allowable nitrogen oxides emission
                             rate in pounds per hour;

                        Pg = per cent of actual heat input de-
                             rived from gaseous fossil fuel;

                        P! = per cent of actual heat Input de-
                             rived from liquid fossil fuel;

                        Ps = per cent of actual heat input de-
                             rived from solid fossil fuel;

                         Q = actual heat input derived from all
                            1 fossil fuels in million btu per hour.
               Mote:
                                     100.0
(b)   Existing Fuel-Combustion Emission Sources in the Chicago
     and St.  Louis MMA_._  No person shall cause or allow the
   •  emission of nitrogen oxides into the atmosphere in any
     one hour period from any existing fuel^combustion emission
     source with an actual heat input equal to or greater
                            -67-
                                                                                        than 250 million btu per hour, located in the Chicago and
                                                                                        St. Louis (Illinois) major metropolitan areas to exceed
                                                                                        the following limitations;
     (1)


     (2)


     (3)
                                                                                             for gaseous and/or liquid fossil fuel firing, 0.3
                                                                                             pounds per million btu of actual heat input;

                                                                                             for solid fossil fuel firing, 0.9 pounds per million
                                                                                             btu of actual heat input;

                                                                                             for fuel combustion emission sources burning
                                                                                             simultaneously any combination of -solid, liquid and
                                                                                             gaseous fuel the allowable emission rate shall be
                                                                                             determined by the following equation:
                                                                                                       E =
                              (P
                                                                                                                             Q.9
                   Pi  =


                   PS  =


                    Q  =
                                                                                                                      + Pi + PS
                                                                                                            allowable nitrogen oxides emission
                                                                                                            in pounds per hour;

                                                                                                            per cent of actual heat input de-
                                                                                                            rived from gaseous fossil fuel;

                                                                                                            per cent of actual heat input de-
                                                                                                            rived from liquid fossil fuel;

                                                                                                            per cent of actual heat input de-
                                                                                                            rived from solid fossil fuel;

                                                                                                            actual heat input derived fro-  all
                                                                                                            fossil fuels In million btu per hour.
                                                                                                  Note:
                                                                                                         P  + P
                                                                                                          1    s
                                                                                                                        100.0
(c)   Exceptions  t£ Rule  207  (b).   Paragraph  (b)  of  this  Rule
     207  shall not apply to  existing  fuel  combustion sources
     which are either  cyclone  fired boilers  burning solid or
     liquid fuel,  or horizontally  opposed  fired  boilers  burn-
     ing  solid fuel.

(d)   Nitric Acid Manufacturing Processes.

     (1)   New Weak Nitric Acid Processes.  No  person shall
          cause  or allow the emission of nitrogen oxides Into
          the atmosphere from  any  new weak nitric acid manu-
          facturing process  to exceed the  following standards
          and limitations:
          (A)
                                                                                                        3.0 pounds  of  nitrogen  oxides  (expressed  as  M02)
                                                                                                        per ton  of  acid  proauced  (100  per  cent  acid
                                                                                                        basis);
                                                                                                               -68-

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     .(B)  visible emissions in excess of 5 per cent
          opacity;

     (C)  0.1 pounds of nitrogen oxides (expressed as N02)
          psr ton of acid produced (100 per cent acid
          basis) from any acid storage tank vents.

(2)  Existing Weak Nitric Acid Processes..  No person
     shall cause or allow the emission of nitrogen oxides
     Into the atmosphere from any existing weak nitric
     acid manufacturing process to exceed the following
     standards and limitations:

     (A)  5.5 pounds of nitrogen oxides (expressed as N02)
          per ton of acid produced (100 per cent acid basis);

     (B)  visible emissions in excess of 5 per cent opacity;

     (0)  0.2 pounds of nitrogen oxides (expressed as NOj).
          per ton of acid produced (100 per cent acid
          basis) from any acid storage tank vents.

(3)  Concentrated Nitric Acid Processes.  No person shall
     cause or allow the emission of nitrogen oxides into
     the atmosphere from any concentrated nitric acid-
     manufacturing process to exceed the following standards
     and limitations:

     (A)  3.0 pounds of nitrogen oxides (expressed as NOj)
          per ton of acid produced (100 per cent acid
          basis);

     (B)  225 PP^i of nitrogen oxides (expressed as NOg)
          In any effluent gas stream emitted into the
          atmosphere;

     (C)  visible emissions in excess of 5 per cent opacity.

(1|)  Kltrlc  Ac id Concentrating Processes.   No person shall .
     cause or allow the emission of nitrogen oxides into
     the atmosphere from any nitric acid concentrating
     process to exceed the following limitations:

     (A)  3.0 pounds of nitrogen oxides (expressed as N02)
          per ton of acid produced (100 per cent acid
          basis);  ,

     (B)  visible emissions in excess of 5 per cent opacity.
(e)   Industrial  Processes:   General
         New Industrial Processes.  _No person shall cause or
         allow che emission of nitrogen oxides into the
         atmosphere from any new process producing products of
         organic nitrations and/or  oxidations using nitric acid
         to exceed the following standards and limitations:
     (1)
          (A)   5.0 pounds of nitrogen oxides  (expressed as
               per ton of nitric acid (100 per cent acid basli)
               used  in such new process.

          (B)   visible emissions in excess of 5 per cent opacity.

     (2) .  Existing; Industrial processes.  Ho person shall cause
          or allow the emission of nitrogen oxides into the
          atmosphere from any existing process producing products
          of organic nitrations and/or oxidations using nitric acid
          to exceed  10.0 pounds of nitrogen oxides (expressed as
          N0;j)  per ton of nitric acid (100 per cent acid basis)
          used  in such process.

     (3)   Exemption.  Paragraphs (e)(l) and (e) (2) of this Rule
          207 shall  not apply to any industrial process using less
          than  100 tons of nitric acid (100 per cent a.o.irL * = «•< «= V
          annually or which produces less than 1 ton pf nitrogen
          oxides (expressed as N02) per year.        v_.	

     Measurement Method.  Measurement of nitrogen oxides shall be
     according  to the Phenol Disulfonlc Acid Method as published
     in 36 Fed. Reg.  15713, Method 7.

(g)   Compliance Dates.

     (1)   Every owner or operator of "a new emission source shall
          comply with the standards and  limitations of Rule-  207
          by  the effective date of Part  2 of  this Chapter.

     (2)   Except as  otherwise provided in paragraph (5)(3) of this
          Rule  207,  every owner or operator oi".'an existing emission
          source shall comply with the standards and limitatlcr.o
          of Rule 207 by December 31, 1973.

     (3)   Every owner or operator of an  existing coal fired  fuel
          combustion emission source shall comply with the appli-
          cable standards and limitations of  Rule 207 by May  30,
          1975.
(f)
                       -69-
                                                                                                           -70-

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Rule 208: Compliance Dates.
          Notwithstanding the Issuance of an Operating Permit,
          no person shall cause or allow the operation of an
          emission source which is not in compliance with the
          standards and limitations set forth in this Part 2 after
          December '31, 1973, unless otherwise provided by a compli-
          ance date specifically set forth for a particular category
          of emission source in this Part 2.
                                                                                I
                                 -71-
                                                                            i	

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        APPENDIX C




AIR ENFORCEMENT CHECKLIST

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                                                                     PART I
                            AIR ENFORCEMENT CHECKLIST
  I.  Source Identification
      A.  Name:
      B.  Address:
      0.  Air Quality Control Region:
      D.  Pollutant(s.): •
      E.  Type of Operation:
 II.  Type of Violation:
      A.  Currently enforceable regulation
              Citation and Designation:

      B.  Increment within regulation
              Citation (attach copy) and designation:
      C.   Compliance schedule
          1.   Regulations covered (citation and.designation):

          2.   Federal  approval  status (attach copy):  .
              This schedule was approved/promulgated  by EPA on  	
              (	F.R.	)  under the provisions  of 40 C.F.R.  51.6/51.15.
III.   Total  Emissions  (each pollutant)    Present          After Compliance Achieved

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                                                               PART I



                                      . 2 -






 IV.  Previous Attempts at Compliance and Contacts with Source, if any;
  V.  Prior Local, State, or Federal Enforcement Actions:
 VI.  State/local discussion of Proposed Federal  Enforcement Action



      A.  Name and title of highest official  with whom discussed:









      B.  Attitude of person named in A.,  above toward federa-1  action
VII.   Notifications



      Source:

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                                - 3 -





State:
Local:

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                                                              PART 11

                             DATA TO SUPPORT VIOLATIONS
  I.  Source Identification
      A.   Name of Company:

      B.   Specific source within cited facility:


 II.  Requirements.)  violated by source:
MI.   Evidence supporting violation
      A.   Emission Factors
          1.   Calculated emissions
              a.   without controls;
              b.   with  controls  (known/estimated):
          2.   Allowed  emissions
          3.   Names  of  individuals who  can  testify  to  the  above  information:

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                                                               PART II

                                      - 2 -
     B.  Smokereadings

         1.  Description of smokereading evidence:
         2.  Names of individuals who can testify to the above information:
     C.  Stack sampling

         1.   Description of stack sampling evidence:
         2.   Names of individuals  who can  testify  to  the  above  information:
     D.   Evidence indicating missed  increment,  if  applicable:
IV.   Identify and explain  any factors  which  may  affect  the  persuasive  impact
     of the evidence:

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                                                            PART III
                                      - 2 -
     C.  If the source has proposed an alternative course of action  to  the
         one described in A.  above, describe and evaluate the proposed  alternative,
         (attach copy of proposal, if available):
II.   Estimated cost of remedial  action

     Estimated cost of action  described  in  I.A  and  I.C  above  if  known  (give
     bas'is for estimate and  attach  study,  if any):

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