PB85-165488
DETERMINATION OF ACTIVATED SLUDGE
BIOKINETIC CONSTANTS FOR CHEMICAL
AND PLASTIC INDUSTRIAL WASTEWATERS APPENDIX B
Oklahoma State University
Stillwater, OK
FEE 85
U.S. DEPARTMENT OF COMMERCE
National Technical Information Service
NTIS
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EPA/600/2-83/073C
February 1985
DETERMINATION OF ACTIVATED SLUDGE BI OKI NET 1C CONSTANTS
FOR CHEMICAL AND PLASTIC INDUSTRIAL WASTEWATERS
APPENDIX B
by .
Don F. Kincannon and Enos L. Stover
School of Civil Engineering
Oklahoma State University
Stillwater, Oklahoma 7^078
Cooperative Agreement
CR-810293
Project Officer
Dr. Thomas E. Short, Jr. .
Subsurface Systems Branch
Robert S. Kerr Environmental Research Laboratory
Ada, Oklahoma 7^820
ROBERT S. KERR ENVIRONMENTAL RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
ADA, OKLAHOMA 7^820
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
i. REPORT NO.
EPA-600/2-83-073C
)ECIPIENT'SACCESSLOI*Np. . --,
PB85 1 b ? £ 8 8 1J&
4. TITLE AND SUBTITLE
Determination of Activated Sludge Biokinetic Constants
for Chemical and Plastic Industrial Wastewaters
(Appendix B)
S. REPORT DATE
February 1985
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Don F. Kincannon and Enos L. Stover
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
School of Civil Engineering
Oklahoma State University
Stillwater, OK 74078
10. PROGRAM ELEMENT NO.
5ABW63LOCO (Obj. Code 2401)
li.«Jt«MKX3r!8fi««ffic!XSt Coop. Agr.
CR810293
12. SPONSORING AGENCY NAME AND ADDRESS
Robert S. Kerr Environmental Research Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
P.O. Box 1198, Ada, OK 74820
13. TYPE OF REPORT AND PERIOD COVERED
Final 09/01/82 - 01/01/85
14. SPONSORING AGENCY CODE
EPA-600/15
15. SUPPLEMENTARY NOTES
Project Officer: Thomas E. Short
16. ABSTRACT....
The most widely used method of wastewater treatment is biological treatment. The
use of kinetic models to describe the behavior of a biological wastewater treatment
process has become widely accepted practice. The most often used kinetic models
include those developed by Eckenfelder, McKinney, Lawrence and McCarty, and Gaudy..
All of these models contain kinetic 'constants, and the- usefulness of each model is a
function of the reliability of the kinetic constants. However, there has not been
enough information available to establish reliable values for these kinetic constants
for industrial wastewaters.
This continued project has determined the biokinetic constants and fate for twelve
additional toxic organic pollutants when present in a highly biodegradable wastewater.
The normal approach for determining biokinetic constants has been to plot the average
values. This approach masks the actual scatter of the data. This study has produced
a methodology for analysis of the test results from biological activated sludge systeir^
for determining the biological variability inherent in these types of systems.
This study also investigated the possibility -of predicting the fate and effluent
concentrations of the various priority pollutants. It was found that good predictions
for the priority pollutants can be made.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
Activated Sludge
Sewage Treatment
Priority pollutants
Combined industrial/
municipal
Kinetic Constants
06A
13. DISTRIBUTION STATEMENT
Release to public
19. SECURITY CLASS (ThisReport/
Unclassified
21. NO. OF PAGES
194
20. SECURITY CLASS (Thispage)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
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DISCLAIMER
The information in this document has been funded wholly or in part by
the United States Environmental Protection Agency under.assistance agreement
CR-810293 to Oklahoma State University. It has been subjected to the Agency's
peer and administrative review and has been approved for publication as an
EPA document. Mention of trade names or commercial products does not constitute
endorsement or recommendation for use.
ii
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FOREWORD
EPA is charged by Congress to protect the Nation's land, air, and water
systems. Under a mandate of national environmental laws focused on air and
water quality, solid waste management and the control of toxic substances,
pesticides, noise, and radiation, the Agency strives to formulate and imple-
ment actions which lead to a compatible balance between human activities and
the ability of natural systems to support and nurture life.
The Robert S. Kerr Environmental Research Laboratory is the Agency's
center of expertise for investigation of the soil and subsurface environment.
Personnel at the Laboratory are responsible for management of research pro-
grams to: (a) determine the fate, transport and transformation rates of
pollutants in the soil, the unsaturated zone and the saturated zones of the
subsurface environment; (b) define the processes to be used in characterizing
the soil and subsurface environment as a receptor of pollutants; (c) develop
techniques for predicting the effect of pollutants on ground water, soil and
indigenous organisms; and (d) define and demonstrate the applicability and
limitations of using natural processes,' indigenous to the soil and subsurface
environment, for the protection of this resource.
EPA, as provided for in the Clean Water Act, has the responsibility to
promulgate regulations to protect streams and publicly owned treatment works.
An important consideration is the economic impact that these regulations may
have. This appendix summarizes a study of the biokinetic constants and
environmental fate for 12 additional toxic organic pollutants. This infor-
mation will aid the Agency in its effort to determine the economic impact
that specific effluent guidelines may have on a particular industry.
Clinton W. Hall
Director
Robert S. Kerr Environmental Research Laboratory
iii
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ABSTRACT
The most widely used method of wastewater treatment Is biological treat-
ment. The use of kinetic models to describe the behavior of a biological
wastewater treatment process has become widely accepted practice. The most
often used kinetic models include those developed by Eckenfelder, McKinney,
Lawrence and McCarty, and Gaudy. Recently, Kincannon and Stover introduced
a model that shows great promise.
Cooperative Agreement CR-810293-01-0 determined the biokinetic constants
needed for the design models for twelve toxic pollutants when present in a
highly biodegradable wastewater. Biokinetic constants were also determined
for four groups of three chemicals. The biokinetic constants were determined
based upon biochemical oxygen demand (BODtj), total organic carbon (TOC), and
chemical oxygen demand (COD).
The fate of the twelve chemicals during biological treatment was also
determined. It was determined whether the chemicals were removed by biode-
gradation, sorption, stripping, or combinations of these mechanisms.
Continuous flow, internal recycle activated sludge pilot plants were
used to develop the data needed for determining the biokinetic constants and
the fate of the specific chemicals.
Cooperative Agreement CR-810293-01-0 is a continuation of the work re-
ported in "Determination of Activated Sludge Biokinetic Constants for Chemical
and Plastic Industrial Wastewater," EPA-600/2-83-0?3a.
IV
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CONTENTS
Foreword i i i
Abstract ..... iv
Figures vi
Tables ....... vii
Abbreviations and Symbols ix
1. Introduction 1
2. Conclusions and Recommendations 3
3. Materials and Methods k
General Experimental Plan k
Description and Operation of Pilot Plants k
Sample Schedule 7
Project Management ' 10
O.ual ity Assurance of Pilot Plant Operations. ... 10
Laboratory Procedures 11
Internal Qua 1ity Control Practices 13
1». Results }k
.Performance of Pilot Plants 1*»
Biokinetic Constants . . 1*»
Fate of Specific Chemicals 31*
References 37
Appendix 38
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FIGURES
Number Page
1 Bench-scale activated sludge pilot plants 5
VI
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TABLES
Number Page
1 Wastewater Concentrations . 8
2 Chemical Characteristics 9
3 Sludge Age, Hydraulic Residence Time, and Mixed Liquor
Solids for Single Systems 15
k Influent and Effluent BODj for Single Systems 16
5 Influent and Effluent TOC for Single Systems 17
6 Influent and Effluent COD for Single Systems. 18
7 Effluent Solids, Sludge Volume Index, and Oxygen Uptake
Rate for Single Systems . . 19
8 Influent, Effluent, and Sludge Concentrations of Specific
Compound for Single Systems 20
.9 Sludge Age, Hydraulic Residence Time, and Mixed Liquor
Solids for Combined Systems 21
10 Influent and Effluent BOD,- for Combined Systems 22
11 Influent and Effluent COD for Combined Systems 23
12 Influent and Effluent TOC for Combined Systems 2*4
13 Effluent Solids, Sludge Volume Index, and Oxygen Uptake
Rate for Combined Systems 25
14 Influent, Effluent, and Sludge Concentrations of Specific
Compounds for Combined Systems 26
15 BODj Biokinetic Constants for Single Chemical Systems .... 29
16 TOC Biokinetic Constants for Single Chemical Systems 30
17 COD Biokinetic Constants for Single Chemical Systems 31
18 Biokinetic Constants for Combined Systems 32
VI I
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TABLES (continued)
Number Page
19 Removal Mechanisms for Specific Chemicals in Single
Systems 33
20 Removal Mechanisms for Specific Chemicals in Combined
Systems 35
21 Effluent Achieved for Specific Chemical 36
VI I I
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LIST OF ABBREVIATIONS AND SYMBOLS
BODr biochemical oxygen demand
COD chemical oxygen demand
F flow rate
F/M feed to microorganism ratio FS./XV
F waste sludge flow rate
K Lawrence and McCarty's maximum substrate uti1ization rate
D substrate loading at which the rate of substrate utilization
is one-half the maximum rate
k maintenance energy or decay coefficient
K Eckenfelder's first order substrate removal rate constant
K ' Eckenfelder's second, order substrate removal rate constant
K. stripping rate constant
K -- Mckinny's substrate removal rate
m
K -- saturation constant
MLSS mixed liquor suspended solids
MLVSS mixed liquor volatile suspended solids
S effluent substrate concentration
S. influent .substrate concentration
SRT sludge retention time, 9
SVI sludge volume index
TC SRT (sludge retention time)
TOC total organic carbon
U S. - S /Xt, specific substrate utilization
U maximum substrate utilization rate
max
V volume
VSS volatile suspended sol i'ds
X biological solids
X effluent suspended solids
i x
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X underflow solids concentration
Y true yield
a recycle flow ratio
9 SRT (sludge retention time)
y observed growth rate
y --maximum growth rate
rmax 3
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SECTION 1
. INTRODUCTION
Provisions in the Clean Water Act clearly require the U.S. Environmental
Protection Agency to promulgate regulations to protect streams and publicly
owned treatment works and to see.to it that regulatory practices are in place
to protect the vast investment of public funds. This law can affect nearly
all industrial manufacturing plants now discharging or planning to discharge
into POTW's or a stream. An important category for which effluent guidelines
are needjed is waste components from chemical and plastic industries. For this
category, the problem.is extremely difficult because of the thousands of dif-
ferent chemicals produced at plants across the nation. The product lines of
these plants, and thus the nature of the wastes, are not fixed and change with
market needs. This industrial activity consequently produces wastewaters of
great and changing variety in the types of pollutants they contain. Further-
more, a significant number of the growing list of priority pollutants are
appearing in various waste streams from the manufacturing of chemicals and
plastics.
Because of the immensity and tremendous variety of products and process
routes from production, it is logical that a computer programming procedure
would be developed to handle the definition of wastewater composition as well
as alternate processing routes for the treatment of wastewater. Computer
programs have been developed that can combine waste load information on each
product, select various product treatabi1ity routes, combine them, design
and cost-out a plantfs treatment system, and, finally, allocate the estimated
treatment costs to the contributing product process route. However, before
plant costs can be modeled, the treatment design models must be established.
Design models are available but the biokinetic parameters for the chemical
and plastic industries are not available. Therefore, the determination of
the biokinetic parameters becomes, of vital concern to the success of the cost
model.
The current best-practical technology (BPT) for treatment of chemical
industrial and plastic manufacturing wastes usually involves activated sludge
since biological treatment "is often found to be the most cost effective in
dealing with relatively low concentrations of the types of organic materials
in such wastes.
Modern approaches for the design of activated sludge employ mathematical
process models depicting the relationships among factors affecting the kin-
etics of wastewater purification. All design models require quantitative
assessment of numerical values for biokinetic constants for the activated
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sludge in question. These values are, in general, a function of the type of
carbon source comprising the carbonaceous biochemical oxygen demand. Various
models are available for use in designing activated sludge processes.
Cooperative Agreement CR-8068^3-01 -02 determined the biokinetic constants
and fate for twenty-four toxic organic pollutants when present in a highly
biodegradable wastewater. The objective of this study was to extend this work
by studying twelve additional toxic chemicals.
Since this work is a continuation of the work reported in "Determination
of Activated Sludge Biokinetic Constants for Chemical an.d Plastic Industrial
Wastewater," EPA-600/2-83-073a, many of the basic procedures have not been
included .in this report. If the reader is interested in the basic procedures
they should- consult the above reference.
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SECTION 2
CONCLUSIONS AND RECOMMENDATIONS
High treatment efficiencies (in terms of biochemical oxygen demand, 6005;,
chemical oxygen demand, COD; and total organic carbon, TOC) can be achieved
by biological treatment of wastewaters containing toxic priority pollutants.
This study has shown that priority pollutants can be accommodated in biologi-
cal wastewater treatment processes. In addition, it was found that many of
the priority pollutants were biodegraded to very low concentrations. In
other cases, the priority pollutants were stripped or sorbed to low levels
without interfering with the biodegradation of the other organics.
The bibkinetic constants of the wastewaters containing the priority pol-
lutants are representative of a readily biodegradable wastewater. The bio-
kinetic constants for Eckenfelder, Lawrence and McCarty, and Gaudy's design
models are subject to variability. The Kincannon and Stover model provides
a method for eliminating the variability of the system. This new model pro-
vides designs comparable with the other design models without the variability
of the biokinetic constants.
Priority pollutants are removed by biodegradation, stripping, sorption,
or combinations of these mechanisms. When biodegradation is the major mechan-
ism of removal, the priority pollutants are removed to their lowest concen-
trations. Stripping and sorption mechanisms do not remove the pollutants to
effluent levels as low as those accomplished by biodegradation.
This study and cooperative agreement CR 8068^3-010-02 have shown that
wastewaters containing priority pollutants can be successfully treated by
biological processes.
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SECTION 3
MATERIALS AND METHODS
GENERAL EXPERIMENTAL PLAN
Continuous flow, internal recycle activated sludge pilot plants were
used to develop the data needed for determining biokinetic constants. Three
specific chemicals were studied each quarter. Activated sludge for starting
the pilot plants was obtained from the Souths!de wastewater treatment plant,
Tulsa, Oklahoma. The pilot plants were acclimated to the synthetic wastewater
for four weeks and then sampled for two months. Twelve pilot plants were
operated to provide three SRT's for each specific chemical and three SRT's
for the three chemicals combined in one wastewater.
The pilot plants were sealed reactors which made the measurement of the
off-gases possible. Thus, the experimental procedures allowed for the deter-
mination of the fate of the specific chemicals.
DESCRIPTION AND OPERATION OF PILOT PLANTS
A schematic of the bench-scale activated sludge pilot plants is shown in
Figure 1. These systems consisted of stainless steel internal recycle reac-
tors with 3-0 liter activated sludge reactor volumes and 3-23 liter settling
compartment volumes. The reactor and settling compartment were both fitted
with air tight stai.nless steel covers to facilitate off-gas analysis. The
wastewaters were pumped from sealed feed tanks .to the reactors, and the ef-
fluents flowed by gravity from the settling compartments to collection tanks.
All parts of the experimental system were constructed of materials to mini-
mize contamination.
The influent wastewater flow rates were regulated to provide hydraulic
retention times of 8 hours in the activated sludge reactors. The influent
air and off-gas were measured and controlled with air flow meters. The off-
gas was pulled by vacuum pumps through purge traps containing 6 inches of
Tenax and 4 inches of silica gel for gas chromatograph^analysis.
The following procedure was used for daily operation of the internal
recycle pilot plants.
1. The feed pump was set at a flow rate to prove a hydraulic
detention time of eight hours.
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OFF-QA8
4ff
AIR FLOW
METER
BAFFLE
0
VOLATILE
PURGE
TRAP
AJR FLOW
.METER
VACUUM
PUMP
REACTOR
PUMP
WA8TEWATER
FEED TANK
EFFLUENT
COLLECTION
TANK
Figure 1. Bench-scale activated sludge pilot plants.
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2. The adjustable baffle was set at a level that provided good
return flow of the return solids. This required adjusting
the baffle several times per day.
3. MLVSS were wasted once each day to provide desired SRT. This
was accomplished by the following procedure:
a. A sample was collected from the aeration chamber for MLVSS
analysis.
b. The clarified effluent collection tank was mixed and a
sample taken for VSS analysis.
c. The sludge waste flow rate was calculated by
-^L - FX
F = SRT e
w X - Xg
where:
F = waste sludge flow rate, I/day
SRT = sludge age, days
V = volume of reactor, liters
F = influent flow rate/day
X = effluent volatile suspended solids, mg/£
X = MLVSS, mg/i
d. The baffle was pulled and the aeration chamber and clarifier
were allowed to mix.
e. A volume equal to the calculated F was withdrawn from the
entire volume and wasted.
f. The baffle was reset.
The municipal activated sludge was allowed to acclimate to the "base
mix" wastewater for one week and then the organic compound was added to the
wastewater. The organic compound was first added at a low concentration.
This concentration was increased slightly each two or three days until the
desired concentration was reached. This build-up period took from two to
three weeks. Three pilot plants were operated for each compound - each at
a different SRT. The SRT's were selected so that there would be a spread
in the effluent BODc achieved by the threepilot plants.
During each quarter the pilot plants were operated as:
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Number of
Set No. Pilot Plants Feed Remarks
1 3 BM*+ compound A Three sludge ages
2 3 BM + compound B Three sludge ages
3 3 BM + compound C Three sludge ages
4 3 BM + A, B, C . Three sludge ages
»BM = base mix
A total of twelve pilot plants were operated at a time. The concentra-
tion of compounds A, B, and C in the combined units was one-third of the
concentration of those compounds in the other units.
The synthetic wastewater included selected organic chemicals combined
with a "base mix". The "base mix" was a readily biodegrladable substrate
which consisted of:
ethyleneglycol 1 volume
ethyl alcohol 1 volume
acetic acid 1 volume
glutamic acid 1 weight
glucose 1 weight-
phenol , 0.2 weight
ammonium sulfate 1.8 weight
phosphoric acid 0.14 volume .
magnesium sulfate 0.7 weight
manganese sulfate 0.07 weight
calcium chloride 0.07 weight
ferric chloride 0.004 weight
Note: use of 1 gm of weight equivalent to 1 mi of volume
The "base mix" was proportioned so that the BOD^ due to the "base mix" would
be approximately 250 mg/&. .Any BODt; attributed to the study chemical would
add to the 250 mg/£. Table 1 gives the average influent BODj, TOC, and COD
for the twelve reactors. Table 2 gives some chemical characteristics for the
twelve chemicals.
SAMPLE SCHEDULE
The following sample schedule was followed:
Parameter Frequency
Inf1uent
Flow rate Several times per day
BOD5 3 per week
TOC 3 per week
COD 1 per week
PH daily
Specific chemical 1 per week
7
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TABLE 1. WASTEWATER CONCENTRATIONS
Wastewater Concentrations, mg/Jl
Group Chemi.cal .BOD5 Toc COD
1 Anthracene
Dimethyl phthalate
Hexachlo roe thane
Combined
273
313
278
299
133
149
134
13V
449
505
485
499
II 1,2-dichloroethylene 255 119 316
4-nitrophenol 302 134 482
2,4,6-trichlorophenol 353 153 505
Combined 339 154 501
III ' Fluoranthene . 268 185 426
2-chloronaphthalene 255 201 424
Hydrazobenzene 271 201 424
Combined 265 ' 190 406
IV Nickel 214 167 318
Cadmium .229 162 276
Chromium 253 181 343
Combined 264 171 336
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TABLE 2. CHEMICAL CHARACTERISTICS
Chemical
Anthracene
Dimethyl Phthalate
Hexachlo roe thane
1 ,2-dichloroethylene
4-nitrophenol
2,4,6-trichlorophenol
Fl uoranthene
2-chloronaphthalene
Hrydazobenzene
Nickel
Cadmium
Chromium
Henry's Law
Constant
atm.m3/mole
N.A.
N.A.
9.85 x 10-3
1.5 x ID'2
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
Molecular
Weight
178.2
194.2
236.7
96.9
139.1
197.4
202.3
162.6
184.2
. 58.7
112.4
52.0
Log
POW
4.45
2.12
3.34
1.48
1.91
3.38
5.33
4.12
3.03
.N.A.
N.A.
N.A.
Sol ubi 1 i ty
mg/i
0.073
4,300
. 50
5,000
16,000
800
0.26
6.74
221
6.42 x 105
(NiCl2)
1.40 x 106
(CdCl2)
6.17 x 105
(cro,)
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Parameter Frequency
Effluent
BODj 3 per week
TOC 3 per week
COD 1 per week
Suspended solids 3 per week
VSS 3 per week
specific chemical 1 per week
Aeration Basin
MLSS 3 per week
MLVSS 3 per week
Dissolved oxygen daily
Dissolved oxygen uptake 3 per week
SVI 1 per week
pH daily
off-gas 1 per week
specific compound of mixed liquor . 1 per week
Temperature daily
PROJECT MANAGEMENT
The successful conduct of this Cooperative Agreement centered around the
proper operation of the pilot plants, proper laboratory procedures, and the
correct interpretation of the data. Therefore, a quality assurance plan was
developed to accomplish the goals of the project.
Management
The project director and co-principal investigator maintained complete
control of the project.. They inspected the pilot plants at least two times
each day. Some days the inspection visits were, as many as four or five.
These inspections ensured that the pilot plants were being operated in a
proper manner. Such items as wastewater feed rates, air flow rates, baffle
settings, and MLSS conditions were checked. Proper laboratory procedures
were also routinely checked.
The project director and the co-principal investigator routinely checked
all instruments and performed most routine maintenance of the laboratory in-
struments. They also provided unknown and spiked samples for analyses. All
data analyses were conducted by these two.
Once a week a meeting of all personnel was held. A review .of the week's
activities was conducted. All problems encountered during the week were
discussed by the group. This allowed all personnel to be aware of all prob-
lems encountered. Plans for the coming week were also outlined during this
meeting.
Quality Assurance of Pilot Plant Operation
The key factors in the proper operation of the pilot plants included
10
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1. Cleaning of wastewater feed tank and feed lines:
2. Making up synthetic wastewater feed.
3. Adjustment of baffle.
b. Pump flow rates.
5. Ai r f low rates.
To ensure that biological growth did not develop in the wastewater feed
tank or lines, a disinfection program was developed. This included acid
washing of the feed tank each time fresh synthetic wastewater was made up
and chlorination of each feed line every fourth day. After the disinfection
operation, the feed tank and lines were thoroughly rinsed with tap water
before being put back into operation.
It was important that the synthetic wastewater have the proper ingredi-
ents. To ensure this, TOC, COD, and BODj were routinely conducted on the
synthetic wastewater. Also, gas chromatography analyses were made to measure
the concentration of the specific organic compound under study.
Proper adjustment of the baffle of each pilot plant is a matter of exper-
ience. Also, either the project director or co-principal investigator checked
the flow rates daily. The flow rate was checked by the volume-time method.
Laboratory Procedures
Quality assurance in the laboratory involved reagents, glassware,
instruments, and analytical techniques. The laboratory analyses conducted
for this project included:
1. BODr .- 5 day biochemical oxygen demand
2. TOC - total organic carbon
3.. COD - chemical oxygen demand
*t. Suspended solids
5. Volatile suspended solids
6. D.O. - dissolved oxygen.
7. pH
8. Gas chromatography analyses
9. Atomic absorption analysis of metals
Sample Preservation:
Analyses were conducted immediately for most tests. However, there were
times that this was not possible. For those instances the samples were fil-
tered and stored at
Analytical Methods:
The following analytical methods were used:
Parameter Method
BODj EPA and/or Standard Methods used. Dissolved
oxygen measured by Probe method. Both total
and soluble 6005 were determined. Soluble.^
defined as that left after filtering with a
glass fiber filter.
11
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Parameter
Method
TOC
COD
Suspended Soli ds
VolatiMve Sol ids
Dissolved Oxygen
PH
Specific organic compound
Metals
Beckman 915 TOC Analyzer and Oceanography
05248 used. Only soluble TOC was determined.
EPA and/or Standard Methods used
EPA and/or Standard Methods used. Reeve angel
type 93^-AH glass fiber filter used.
EPA and/or Standard Methods used
Probe method
Instrument
Analyses followed the instructions for gas
chromatograph analysis given in the Federal
Register, Volume 44, Number 233, December 4,
1979. F & -M Model 810 GC with Tekmar LC-Purge
and Trap and HP 3380 Integrator. HP 7.626A GC
with HP 3380 Integrator. Perkin-Elmer Sigma
3B GC.
Total metals were digested according to EPA's
March/April 1977 Protocol Atomic Absorption
Newsletter 14 (5) 109' (1975), using distilled
HN03 and H202. Perkin-Elmer 5000 AA with
Graphite Furnace was used for metals analysis.
Glassware
Standard Kimax or Pyrex brand glassware was used in this study. All
glassware was chromic acid washed before use.
Instruments
An analytical laboratory depends very heavily upon instrumentation. It
was very important that these instruments be maintained in proper working
conditions. The discussion below illustrates how this project ensured that
these instruments were working properly.
1. Analytical Balance. The analytical balance was mounted on a heavy
shock-proof table and was checked and adjusted yearly by a company service-
man. Accuracy of balance was routinely checked by using known weights.
2. pH Meters. The pH meters used for this project were standardized
daily by using standard buffer solutions.
3. Beckman 915 TOC Analyzer. The Beckman TOC Analyzer required good
maintenance and operation practices to ensure continuous operation. The
following maintenance was performed once per month:
a) repack combustion tube
12
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b) clean and dry microfliter
c) clean and dry infrared cell
For improved operation, the instrument remained on continuously and was
preconditioned with repeated injections of distilled water to obtain stable
operating conditions before actual sample injection.
k. Oceanographic Total Carbon Analyzer. The main concern with this
instrument was to ensure that there were no leaks in the system and that the
drying tubes were replaced regularly with granular magnesium perchlorate.
5. Dissolved Oxygen Probe. The dissolved oxygen probe was calibrated
before each series of analyses.
Internal Quality Control Practices
Internal quality control practices varied for the various tests. These
were:
1. BODr - There are no good methods for testing the reliability of the
BOD test. Our control used duplicate samples and spiked samples
prepared by the project director.
2. TOC - Linearity of standards, duplicates, and recoveries from
spiked solutions provided the quality assurance of the TOC analysis.
3. COD - The ferrous ammonium sulfate titrant was standardized as
part of the test. Duplicates and recoveries from spiked solutions
provided ;the qua 1ity assurance for the COD test.
4. Suspended Solids - Duplicate samples provided the only quality
assurance for suspended sol ids.
5. GC Analysis for Specific Compounds - Quality assurance involved
determining linearity of the analytical range, replicate runs,
and recoveries from spiked solutions.
6. Atomic Absorption of Specific Metals - Quality assurance involved
determining 11inearity of the analytical range, replicate runs, and
recoveries from spiked solutions.
13
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SECTION k
RESULTS
PERFORMANCE OF PILOT PLANTS
Twelve chemicals have been studied in the.complete mix continuous flow
bench scale activated sludge pilot plants. Summaries of the operating con-
ditions and responses of the single chemical systems are shown in Table 3~8.
In addition, summaries of the operating conditions and responses of the com-
bined chemical systems are shown in Tables 9-1^. The chemicals associated
with each group were given in Table 1. '
Table 3 provides the mean and standard deviation (SD) values of the
sludge age (SRT), hydraulic residence time (HRT), and the mixed liquor vola-
tile suspended solids (MLVSS) for the single chemical systems. Table k gives
the influent and effluent 8005 along with the SRT and F/M ratio for the
single chemical systems. Tables 5 and 6 'provide the influent and effluent
TOC and COD along with the respective F/M ratios for the single chemical
systems. Table 7 gives the eff1uent.volatile solids, sludge volume index
and oxygen uptake rate for the single chemical systems. Table 8 gives the
influent" and effluent specific chemical values for the single chemical sys-
tems. By studying t.he data in these tables, it can be seen that the single
chemical systems performed very well during the study. High removal levels
of BODj, TOC, COD, and specific chemicals were observed. In some cases the
effluent suspended solids were high; however, in most cases they were at
acceptable levels. Oxygen uptake rates were within acceptable levels and
did not indicate any adverse effects from the wastewaters.
Table 9 provides the SRT, HRT, and MLVSS values for the various combined
systems. Tables 10, 11, and 12 give the influent and effluent BODj, TOC,
and COD, respectively, along with the corresponding F/M ratios. Table 13
provides the effluent suspended solids, sludge volume index, and oxygen up-
take rate for the combined chemical systems. Table 1^» gives the influent
and effluent concentrations of the specific compounds for the combined
chemicals. It is seen from these tables that the combined chemical systems
also performed very well. No apparent adverse effects from the chemicals
were observed.
BIOKINETIC CONSTANTS
The aim of all design models is to provide more accurate predictive
equations which are in keeping with the underlying metabolic and biological
-------
TABLE 3. SLUDGE AGE, HYDRAULIC RESIDENCE TIME, AND MIXED LIQUOR
SOLIDS FOR SINGLE SYSTEMS
Compound
Anthracene
Dimethyl phthalate
Hexach 1 oroethane
1 ,2rdichloroethy1ene
4-ni trophenol
2,46-trichlorophenol
Fluoranthene
2-chloronaphthalene
Hydrazobenzene
Nickel
Cadmi urn
Chromi urn
SRT,
mean
1.17
2.27
5.27
1.00
2.70
4.23
1 .00
2.79
5.94
0.98
2.90
5.78
0.94
2.52
6.45
1.00
2.96
5.97
1.02
3.02
9.31
1.00
3.02
9.28
1 .00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
days
S.D.
1.20
0.97
1.66
0.01
0.77
2.25
0.00
0.74
0.32
0.21
0.61
3.83
0.22
0.9**
3.92
0.00
0 . 1.6 .
3.50
0-.08
0.13
1.53
0.00
0.03
1.73
0.00
0.03
0.38
0.04
0.30
0.23
0.05
0.06 '
1.05
0.00
0.20
0.07
HRT, hours
mean S.D.
8.52
8.12
8.31
7.91
8.45
8.08
8.01
8.01
8.01
8.22
8.41
8.39
8.34
8.42
8.36
7.85
8.10
8.12
8.04 -
8.07
8.03
7.94
8.13
. 8.17
8.17
8.02
7.91
8.06
7.99
8.12
8.04
8.01
7.98
7.87
8.37
7.45
1.53
0.58
0.82
0.23
1.46
0.04,
0.01
0.00
0.00
1.49
1.48
1.47
1.47
1.49
1.48
0.09
0.10
0.15
0..10
0.09
0.06
0.24
0.15
0.27
0.37
0.34
0.36
0.15
0.18
0.10
0.06
0.03
0.04
0.25
0.69
0.94
MLVSS, mg/£
mean S.D.
478
1001
1548
491
1109
1096
594
935
1483
470
1005
1287
' 453
982
1526
625
1131
1722
344
936
'1930
517
1042
2015
445
1165
2441
351
719
2192
322
708
1288
418
1013
2369 .
235
477
463
127
379
425
329
265
202
146
246
411
146
382
749
266
163
301
93
138
174
112
136
454
85
177
257
101
254
168
76
45
314
142
383
386
15
-------
TABLE 4. INFLUENT AND EFFLUENT BODs FOR SINGLE SYSTEMS
Compound
Anthracene
Dimethyl Phthalate
Hexachlo roe thane
1 ,2-dichloroethylene
4-ni trophenol
2 , 4 , 6- 1 r 5 ch 1 oropheno 1
Fl uoranthene
2-chloronaphthalene
Hydrazobenzene
Nickel
Cadmi urn
Chromi urn
SRT,
mean
1.17
2.28
. 5.27
1 .00
2.70
4.23
1.00
2.79
5.94
0.98
2.90
5.78
0.94
2.52
6.45
1.00
2.96
5.97
1.02
3.02
9.31
1 .00
3.02
9.28
1.00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
days
S.D.
1.20
0.97
1.66
0.01
0.77
2.25
0.00
0.74
0.32
0.21
0.61
3.83
0.22
0.94
3.92
0.00
0.16
3.50
0.08
0.13
1.53
0.00
0.03
1.73
0.00 -
0.03
0.38
0.04
0.30
0.23
0.05
0.06
1.05
0.00
0.20
0.07
F/M
mean S.D,
1.88
1.04
0.60
2.03
0.82
0.99
1.77
1.00
0.58
1.64
0.73
. 0.60
2.04
1.00
0.72
1.93
0.94
0.63
2.48
0.86.
0.42
1.59
0.74
0.40
1.85
0.72
0.34
1.91
1.03
0.29
2.23
0.98
0.59
1.99
0.85
0.33
0.91
0.62
0.29
0.55
0.26
0.41
0.87>
0.54
0.14
0.54
0.22
0.25
0.76
0.52
0.50
0.60
0.14
0.15
0.71
0.14
0.05
0.54
0.12
0.12
0.37
0.14
0.04
0.55
0.44
0.06
0.59
0.16
0.24
0.50
0.39
0.05
Inf .Bod5
rng/H
mean S.D.
273
281
287
313
302
313
278
278
278
255
252
252
302
302
302
353
353
353
268
268
268
255
256
256
271
271
271
214
214
214
229
231
231
253 .
253
256
71
40
42
46
77
46
47
47
47
71
70
70
77
77
77
41
41
41
28
28
28
20
20
20
22
22
22
47
47
47
30
31
30
33
33
27
Eff.BOD5
mg/Jl
mean S.D.
2.6
1.7
2.0
6.1
2.3
3.0
5.0
2.7
1.3
4.4
2.5
3.1
6.3
3.7
2.6
12.7
4.7
5.3
5.5
2.6
1.6
4.5
1.8
1.3
5.8
2.5
1.4
.8.9
3.0
1 .0
7.0
3.7
1.7
8.8
6.8
3.1
3.1
2.6
2.7
5.0
2.9
3-0
3.6
2.8
0.8
3.3
2.7
3.1
4.5
2.9
1.3
6.7
3.7
4.6
2.8
1.3
0.8
2.6
0.9
0.8
3.6
1.1
0.8
4.7
1.7
0.4
5.0
2.1
0.7
8.3
6.5
3.7
16
-------
TABLE 5. INFLUENT AND EFFLUENT TOC FOR SINGLE SYSTEMS
Compound
SRT,
mean
days
S.D.
F/M
mean S.D.
Influent
mg/£
mean S.D.
Effluent
mg/i
mean S.D.
Anthracene
Dimethyl phthalate
Hexachloroethane
1 ,2-dichloroethylene
4-ni trophenol
2,4,6-trichlorophenol
Fl uoranthene
2-chloronophthalene
Hydrazobenzene
Nickel
Cadmium
Chromi urn
1.17
2.28
5.27
1.00
2.70
4.23
1.00
2.79
5.94
0.98
2.90
5.78
0.94
2.52
6.45
1.00
2.96
5.97
1.02
3.02
9.31
1.00
3.02
.9.28
1.00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
1.20
0.97
1.66
0.01
0'.77
2.25
0.00
0.74
0.32
0.21
'0.61
.3.83 .
0.22
0.94
3.92
0.00
0.16
3.50
0.08
0.13
1.53
0.00
0.03
1.73
0.00
0.03
0.38
0.04
0.30
0.23
0.05
0.06
1.05
0.00
0.20
0.07
0.94
0.45
0.30
0.95
0.38
0.48
0.83
0.50
0.28
0.85
0..34
0.29
0.91
0.45
0.32
0.83
0.41
0.27
1.70
0.60
0.30
1.24
0.58
0.30
1.34
0.53
0.25
1.77
1.03
0.23
1.26
0.67
0.48
1.58
0.78
0.27
0.49
0.19
0.19
0.37
0.11
0.18
0.40
0.28
0.07
0.28
0.05
0.09
0.36
0.28
0.20
0.26
0,06
0.05
0.44
0.12
0.06
0.37
0.11
0.07
0.21
0.08
0.04
0.24
0.25
0.02
0.26
0.08
0.16
0.53
0.34
0.05
133
130
129
149
149
149
134
133
134
119
119
119
134
134
135
153
153
153
185
187
185
2.01
2.02
196
201
201
201
167
167
167
162
161
160
181
181
181
22
25
24
30
30
30
26
26
26
13
13
13
37
37
37
14
14
14
30
27
30
38
39
23
23
23
23
' 11
11
11
22
.21
20
11
11
11
39
30
27
33
25
30
35
27
32
27
27
27
29
27
23
40.
36
33
29
26
16
22
17
19
34
21
18
36
27
15
21
27
17
40
25
18
10
11
13
11
14
14
12
12
11
8
9
10
13
10
8
15
12
12
7
' 8
8
4
2
8
7
7
5
21
15
9
12
12
14
33
14
9
17
-------
TABLE 6. INFLUENT AND EFFLUENT COD FOR SINGLE SYSTEMS
Compound
Anthracene
Dimethyl phthalate
Hexachloroethane
1 ,2-dichloroethylene
4-ni trophenol
2,4,6-tri chlorqphenol
F1 uoranthene
2-chloronaphthalene
Hydrazobenzene
Nickel
Cadmi urn
Chromi urn
SRT,
mean
1.17
2.28
5.27
1.00
2.70
4.23
1.00
2.79
5.94
0.98
2.90
' 5.78
0.94
2.52
6.45
1.00
2.96
5.97
1 .02
3.02
9.31
1.00
3.02
9.28
1 .00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
days
S.D.
1.20
0.97
1.66
0.01
0.77
2.25
0.00
0.74
0.32
0.21
0.61
3.83
0.22
0.94
3.92
0.00
0.16
3.50
0.08
0.13
1.53
0.00
0.03
1.73
0.00
0.03
0.38
0.04
0.30
0.23
0.05 ^
0.06
1.05
0.00
0.20
0.07
F/M
mean S.D.
3-32
1.27
0.93
3.25
1.38
1.56
2.65
1.58
1.06
2.18
0.99
0.76
3.04
1.63
1.03
2.85
1.24
0.92
4.08
1.37
0.63
2.84
1.25
0.68
2.73
1.14
0.51
2.82
1.47
0.43
2.67
1.14
0.74
2.30
1.41
0.42
1.74
0.6'7
0.31
1.03
1.32
0.68
1.35
0.17
0.29
1.23 '
0.40
0.32
1.87
1.04
0.57
0.78
0.27
0.17
1.07
0.37
0.07
1.20
0.35
0.26
0.67
0.22
0.07
0.93
0.90
0.07
0.53
0.07
0.25
0.73
1.00
0.08
Influent
mg/£
mean S.D.
449
380
441
505
453
505
485
494
485
316
348
348
482
482
482
505
505
505
426
426
426
424
424
435
424
424
424
318
- 318
318
276
276
291
343
343
343
54
165
62
133
223
133
101
106
101
154
133
133
272
272
272
91
91
91
76
76
76
58
58
54
52
52
52
52
52
52
13
13
38
18
18
18
Effluent
mg/Jl
mean S.D
42
43
35
55
24
38
46
39
31
22
20
24
44
30
24
43
26
31
27
12
7
18
13
9
24
20
10
35
42
23
47
43
25
38
30
31
' 25
30
27
23
16
23
17
30
25
15
13
14
35
17
19
39
18
24 '
24
8
4
8
7
6
12
9
7
14
15
11
14
9
7
16
10
16
18
-------
TABLE 7. EFFLUENT
SOLIDS, SLUDGE
FOR SINGLE
VOLUME 1
SYSTEMS
NDEX AND
OXYGEN UPTAKE RATE
Compound
Anthracene
Dimethyl phthalate
v
Hexachloroethane
1 ,2-di chloroethy lene
4-ni trophenol
2,4,6-tri chlorophenol
Fluoranthene
2-chloronaphthalene
-
Hydrazobenzene
Nickel
Cadmi urn
Chromi urn
SRT,
mean
1.17
2.28
5.27
1.00
2.70
I*. 23
1.00
2.79
5.94
0.98
2.90
5.78
0.3k
2.52
6.45
1 .00
2.96
5.97
1.02
3.02
9.31
1.00
3.02
9.28
1.00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
days
S.D.
1.20
0.97
1.66
0.01
0.77
2.25
0.00
0.74
0.32
0.21
0.61
3.83
0.22
0.94
3.92
0.00
0.16
3.50
0.08
0.13
1.53
0.00
0.03
1.73
0.00
0.03
0.38
0.04
0.30
0.23
0.05
0.06
1.05
0.00
0.20
0.07
Effluent
VSS, mg/.i.
mean S.D.
23
122
56
21
61
82
17
47
19
22
9
116
38
64
93
38
19
120
8
6
21
11
9
20
12
10
5
32
22
6
21
6
9
23
16
18
55
122
99
12
84
89
24 .
95
27
30
16
122
52
93
128
17
18
93
14
11
33
20
12
30
14
19
7
16
21
6
18
9
10
16
16
13
SVI
Range
102-1648
183-2041
478-797
94-1448
590-1852
556-1493
84-1721
721-1302
508-797
419-3205
704-1047
552-1149
187-2697
131-2708
326-1951
63-206
261-813
448-775
182-605
546-1029
398-515
157-2439
321-1136
355-1031
98-188
224-600
325-408
111-290
105-282
358-415
124-725
172-625
273-1020
83-342
79-570
77-143
02 Uptake
mg/gm/hr
mean
22.7
12.7
8.1
43.8
17.1
16.8
23.3
15.8
14.0
- 23,6
15.8
13.5
25.8
14.5
11.9
30.5
17.5
14.8
32,7
16.1
10.3
36.0
18.2
13.2
27.0
15.2
10.9
24.6
13.5
11.6
25.4
17.2
12.5
30.6
18.3
8.3
19
-------
TABLE 8. INFLUENT, EFFLUENT, AND SLUDGE CONCENTRATIONS OF SPECIFIC
COMPOUND FOR SINGLE SYSTEMS
Compound
Anthracene
Dimethyl phthalate
>
Hexach 1 oroethane
4-ni trophenol
2,4,6-trichlorophenol
1 ,2-di chloroethylene
Fl'uoranthene
2-chloronatphthalene
Hydrazobenzene
Nickel
Cadmi um
Chromi um
SRT
days
1.17
2.28
5.27
1.00
2.70
4.23
1 .00
2.79
5.94
0.94 .
2.52.
6.45
1.00
2.96
5.97
0.98
2.90
5.78
1.02
3.02
9.31
1.00
3.02
9.28
1.00
3.00
10.08
1.01
2.88
10.08
1.03
3.06
9.92
1.00
2.96
9.98
Inf 1 uent
yg/£
63
63
63
37,250
37,250
37,250
3,720
3,720
3,720
32,300
32,300
32,300
14,830
14,830
14,830
29,200
29,200
29,200
. . 134
134
134
2,020
2,020
2,020
4,180
4 , 1 80
4,180
3,860
3,860
3,860
3,680
3,680
3,680
3,570
3,570
3,570
Effluent
48
44
53
262
198
132
465
371
338
1820
' 2670
2160
1790
1470
590
235
320
280
26
29
24
49
30
25
2740
2330
2650
2780
3170
2950
280
170
110
120
520
600
Sludge
yg/g
61
42
21
< 10
< 10
< 10
81
64
24
.
--
8 190
'753
570
< 10
< 10-
< 10
< 10
< 10 .
" 10
< 10
< 10
" 27
< 10
"226
159
7,950
4,090
1,280
24,880
16 ,980
18,160
42,380
21,120
22,290
20
-------
TABLE 9. SLUDGE AGE, HYDRAULIC.RESIDENCE TIME, AND MIXED LIQUOR
SOLIDS FOR COMBINED SYSTEMS
Comb
1
ined System
Anthracene
Dimethyl phthalate
Hexachloroethane
SRT,
mean
1
2
I*
.01
.42
.93
days
S.
0.
0.
1.
D.
03
97
59
HRT,
mean
8
8
8
.08
.41
.00
days
S.D.
0
0
0
.05
.77
.00
MLVSS,
mean
568
1422
1316
mg/H
S.D.
198
650
373
II 1.00 0.00 7.94 0.20 471 117
1,2 dichloroethylene 3.00 0.00 8.07 0.00 1414 258
4 nitrophenol 8.01 2.69 7.98 0.03 1798 254
2,4,6 trichlorophenol
III 1.02 0.03 7.96 0.09 625
Fluoranthene 3.02 0.03 8.15 0.24 1153 95
2-chioronaphthalene 8.89 2.51 8.09 0.23 1869 436
Hydrazobenzene
IV. ' . 1.00 0.00 8.10 0.40 425 186
Nickel 3.07 0.07 7.96 0.06 663 131
Cadmium 9.87 0.22 8.03 0.18 1741 229
Chromium
21
-------
TABLE 10. INFLUENT AND EFFLUENT BODr FOR COMBINED SYSTEMS
Combined . SRT,
System
1 1
2
4
II 1
3
8
III 1
3
8
IV 1
3
9
days
.01
.42
.93
.00
.00
.01
.02
.02
.89
.00
.07
.87
1
0
0
2
0
0
1
0
0
2
1
0
F/M
.Ik
.79
.72
.27
.73
.58
.76
.68
.45
.40
.23
.45
Influent
mg/i
mean
294
299
295
339
339
339
265
266
265
264
260
260
BOD5
S.D.
46
46
45
49
49
49
28
29
28
28
30
30
Effl
mean
4
2
. 3
4
7
2
3
2
1
13
16
6
.3
.9
.3
.6
.2
.5
.6
.1
.5
.5
.6
.1
uent
mg/Jl
S
4
3
3
3
.1
. 2
1
0
9
8
7
BOD5
.D.
.3
.2
.8
.1
.2
.0 .
.1
.8
.6
.9
.0
22
-------
TABLE 11. INFLUENT AND EFFLUENT COD FOR COMBINED SYSTEMS
Combined SRT
System days
1 1.01
2.42
4.93
II 1.00
3.00
8.01
III 1.02
3.02
8.89
IV 1.00
3.07
9.87
F/M
2.93
1.08
1.04
3.56
1.10
0.86
2.76
1.07
0.70
3.49
1.64
0.55
Inf 1 uent
mg/&
mean
499
503
450
501
501
501
406
406
406
336
336
330
BOD5
S.D.
95
101
182
66
66
66
62
62
62
18
18
12
Effl
mean
40
41
18
32
19
18
18
7
7
42
47
30
uent BODr
mg/i
S.D.
12
17
14
17
12
12
11
5
4
1.4
14
9
23
-------
TABLE 12. INFLUENT AND EFFLUENT TOC FOR COMBINED SYSTEMS
Combine SRT
System days
1 1.01
2.42
4.93
II 1.00
3.00
8.01
III 1.02
3.02
8.89
IV 1.00
3.07
9.87
F/M
0.85
0.43
0.34
1.04
0.33
0.26
1.36
0.49
0.31
2.14
0.68
0.30
Influent
mg/H
mean
134
136
135
154
154
15*
190
190
186
171
171
171
BOD5
S.D.
24
23
24
28
28
28
35
30
37
14
14
14
Effluent
mg/Jl
mean
32
25
30
33
33
29
24
20
17
36
34
21
BOD5
S.D.
12
8
10
8
11
8
7
3
4
3
19
8
24
-------
TABLE 13. EFFLUENT SOLIDS, SLUDGE VOLUME INDEX, AND OXYGEN UPTAKE
RATE FOR COMBINED SYSTEMS
Combined
Systems
SRT
days
Effluent
VSS, mg/H
mean S.D.
SVI
Range
0 Uptake
mg/gm/hr
11
III
IV
01
42
4.93
1.00
3.00
8.01
1.02
3.02
8.89
00
07
11
108
57
43
7
50
8
3
37
15
11
9.87
9
169
82
41
5
61
]k
8
59
9
9.
10
128-2382
1*00-1562
489-1122
86-2152
124-1456
472-624
144-1406'
664-952
378-573
143-1737
137-1346
76-100
30.4
10.8
15.4
20.2
17,
12.
27.
15.
11.
44,
22.
8.2
25
-------
TABLE 14. INFLUENT, EFFLUENT, AND SLUDGE CONCENTRATIONS OF SPECIFIC
COMPOUNDS FOR COMBINED SYSTEMS
Comb ined
System
1 Anthracene
Dimethyl phthalate
Hexachloroethane
Anthracene
Dimethyl phthalate
Hexach 1 oroethane
Anthracene
Dimethyl phthalate
Hexachloroethane
1 1 4-ni trophenol
2,4,6 trichlorophenol
1,2 dichloroethylene
4-ni trophenol
2,4, 6 trichlorophenol
1,2 dichloroethylene
4-n i trophenol
2,4,6 trichlorophenol
1,2 dichloroethylene
III Fl uroanthene
2-chloronaphthalene
Hydrazobenzene
Fl uoranthene
2-chloronaphthalene
Hydrazobenzene
Fl uoranthene
2-chloronaphthalene
Hydrazobenzene
IV Nickel
Cadmi urn
Chromi urn
Nickel
Cadmi urn
Chromi urn
Nickel
Cadmi urn
Chromi urn
SRT
days
1.01
2.42
it. 93
1.00
3.00
8.01
1.02
3.02
8.89
1.00
3.07
9.87
Inf 1 uent
yg/S,
68 '
5960
900
68
5960.
900
68
5960
900
13500
11960
9100
13500
11960
9100
13500
11960
9100
144
840
1750
144
84 P
1750
144
840
1750 "
1.96
1.49
1.87
1.96
1.49
1.87
1.96
1.49
1.87
Effluent
yg/4
<10
540
<10
<10
370
<10
<10
410
<10
1990
330
29
600
450
26
1390
360
29
24
18
790
16
18
710
23
45
750
1.33
0.41
0.98
1.49
0.55
0.88
1.70
' 0.58
1.51
Sludge
yg/£
<10
"56
<10
<10
256
<10
<10
208
<10
2080
57
375
19
--
230
26
45
18
333
45
36
462
21
<10
. "89
6.6
8.7
18.3
5.1
7.6
14.1
5.5
8.5
7.9
26
-------
principles governing the purification process. Most models are developed by
writing material balances describing the mass rate of change in substrate and
in biomass. Substrate utilization and biomass increase are the two major
concerns in the functional design of the bioreactor. Describing mathemati-
cally these two functions is where the various models differ.
Figure \ is a diagram of an activated sludge process including the bio-
reactor and the mixed liquor separator. If a mass balance for substrate is
written around the entire process:
Rate of change
of substrate
in reactor
Rate of
substrate
inflow to
reactor
FS.
Rate of
substrate
outflow from
reactor
Rate of
substrate
uti1ization
For steady state
conditions! -r- i = 0. Therefore
\ dt /
^ SQ
The various models differ by the assumption for
Eckenfelder
x S
Lawrence and McCarty ( -7 } =
Gaudy
K x S
U S
max x e
Kincannon and Stover
ii FSI
U x '
max xv
xv
27
-------
Each model contains several biokinetic constants. These are:
K ' - Eckenfelder's 2nd order substrate removal constant
e
K - Maximum substrate utilization rate (Lawrence & McCarty)
y - Maximum specific growth rate (Gaudy)
ITlo /\
K - Saturation constant (Lawrence & McCarty, Gaudy)
Y - True cell yield (all models)
k, - Maintenance energy coefficient (all models)
L) - Kincannon and Stover's maximum substrate utilization rate
max
K. - Kincannon and Stover's saturation constant
These biokinetic constants were determined .by linear regression analysis
of the pilot plant data. The results are given in Tables 15-18. Table 15
provides the BODc biokinetic constants for the single chemical systems.
Table 16 provides the .TOC biokinetic constants for the single chemical systems
and Table 17 provides the COD biokinetic constants for the single chemical
systems. Table 18 provides the BODr, TOC, and COD biokinetic constants for
the combined systems. ATI biokinetic constants are mean constants. The
graphical procedures for determining the biokinetic constants are outlined in
the original report "Determination of Activated Sludge Biokinetic Constants
for Chemical and.Plastic Industrial Wastewaters," EPA-600/2-83-073a.
The linear regression analysis for determination of Yt, kj, Umax, and Kb
gave results with very acceptable correlation coefficients. The linear regres-
sion analysis for K, ymax, and Ks were so poor that the biokinetic constants
determined by the analysis have very little use. Eckenfelder's constant, Kg',
also showed poor correlation. However, the constants do appear to give a good
mean value. They are usable if one recognizes the high variability and uses
them accordingly.
The biokinetic constants, Kg1 and Umax, can be used to assess the effect
of the various chemicals on the biological systems. Table 15 shows that Ke'
for the control system was 71 day"1, and Umax for the control system .was 100
Ibs BOD/day/lb solids, the systems fed 2,*»,6 trichlorophenol , nickel, cadmium,
and chromium all had kinetic constants less than these. Whereas, the other
systems show constants equal to or greater than the control constants. It can
also be seen in Table k that, in general, these systems also had higher efflu-
ent BOD's. Table 18 shows that the combined system containing the metals had
a detrimental effect on the system; whereas, the other combined systems showed
no detrimental effect. It is also seen in Table 10 that combined system IV
had higher effluent BOD's than the other combined systems.
28
-------
TABLE 15. BOD5 BIOKINETIC CONSTANTS FOR SINGLE CHEMICAL SYSTEMS
Compound
Anthracene
Dimethyl Phthalate
Hexachloroe thane
1 ,2-dichloroethylene
4-ni trophenol
2,4,6 trichlorophenol
Fl uoranthene
2-ch 1 o ronaptha 1 ene
Hydrazobenzene
Nickel
Cadmi um
Chromium
Yt
0.41
0.41
0.35
0.51
0.49
0.46
0.35
0.55
0.54
0.43
0.43
0.46
day"'
0.16
0.07
0.16
0.03
0.00
0.02
0.04
0.01
0.04
0.03
0.06
0.01
I-1' max,
day
0.60
0.48
0.57
0,33
0;55
0.41
0.50
0.24
0.28
0.55
1.00
0.38
K
day
0.03
0.05
0.85 '
0.78
1.64
1.03
1.27
0.64
0.61
1.00
2.13
0.93
Ks
.mgA
0.08
0.10
2.00
2.34
4.92
3.09
3.80
1.92
1.82
3.00
5.14
1.54
Ke'
day
162
105
106
80
94
54
102
91
80
53
70
41
U K.
max D
Ibs/day/lb Ib/day/lb
100
100
100
100
100
50
100
100
100
50
50
50
101
101
100
101
101
50
101
100
100
50
50
50
Control 0.46 0.09 3.00 6.50 22.00 71 100 1;00
-------
TABLE 16. TOC BIOKINETIC.CONSTANTS FQR SINGLE CHEMICAL SYSTEMS
10
O
Compound
Anthracene
Dimethyl Phthalate
Hexachloroethane
1 ,2-dichloroethylene
4-n i trophenol
2,k,6 trichlorophenol
Fluoranthene
2-chloronaphthalene
Hydrazobenzene
Nickel
Cadmium
Chromi urn
Yt
0.85
0.89
0.91
1.39
1.26
1.45
0.61
0.79
0.74
0.67
0.96
0.67
ad"
.day
0.32
0..16
0.18
0.0k
0.03
0.01
0.03
0.02
0.01
0.05
0.20
0.01
*max
. day""1
0.87
0.65
0.54
1.13
0.41
0.34
0.65
--
O.*40
0.53
6.27
K
day"1
0.2l»
0.35
0.21
0.37
0.31
0.53
0.74
25.0
0.57
0.56
0.*»7
K
. .'.rag/A.
2.66
2.11
0.10
__.
8.67
3.90
24.80
3,96
0.49
1.31
K
e
day'1
1.81
2.55
1.85
1.67
2.52
1.60
6.02
6.93
5.97
5.33
5.59
4.54
U
max
Ibs/day/lb
14.3
14.3
14.3
12.7
10.0
10.0
9.0
21.2
16.7
7.7
5.9
6.3
Kb
Ibs/day/lb
20.1
17.9
18.4
13.7
12.7
12.7
9.8
22.8
18.2
8.2
6.1
6.7
Control 0.86 0.10 A.30 5.0 154 5.50
-------
TABLE 17. COD BIOKINET1C CONSTANTS FOR S INGLE CHEM ICALSYSTEMS . :
Compound
Anthracene
Dimethyl Phthalate
Hexachloroethane
1 ,2-dichloroethylene
4-ni trophenol
2,4,6 t richlorophenol
Fl uoranthene
2-chloronaphthalene
Hydrazobenzene
Nickel
Cadmium
Chromium
Yt
0.24
0.20
0.26
--
0.18
0.35
0.22
0.26
0.37
0.29
0.42
0.31
days
0.30
0.19
0.09
--
0.19
0.04
0.07
0.08
0.04
0.08
0.10
0.11
max,
day
0.95
0.71
0.47
2.04
0.74
0.43
0.36
0.39
0.29
1.09
--
0.49
K
day .
1.67
1.82
1.33
0.90
1.82
1.45
0.88
1.09
0.93
4.76
0.68
K
mg/.H
5.85
4.73
1.67
0.71
7.80
7.46
0.04
0.11
0.12
61
--
7.77
K
day
18
27.
21
21
33
24
58
51
33
14
9
13
U
max
Ibs/day/lb
25
100
100
71
50
100
50
100
50
25
20
100
Kb
Ibs/day/lb
26
108
108
76
52
107
50
101
51
27
22
110
Control 0.28 0.07 1.90 6.7 1^0 20
-------
TABLE 18. BIOKINET1C CONSTANTS FOR.COMBINED SYSTEMS
Combined Y
Systems
1 0.40
II 0 . 40
III 0.50
IV 0.24
1 0.91
II 0.94
III ' 0.61
IV 0.47
1 0.26
II 0.29
III 0.33
IV 0.09
daV'
0.18
0.02
0.01
0.16
0.26
0.08
0.10
0.10
0.09
0.03
0.01
0.32
^max.
day
0.61
0.38
0.31
0.74
--
0.65
2.44
0.70
0.47
0.32
0.27
1.02
K
day"1
BOD
0.80
1.03
0.72
1.81
TOC
0.31
0.65
0.73
COD
1.33
1.43
1.05
1.72
K
mg/fi,
0.03
0.71
0. 39
4.37
21.56
100
21 .80
1.67
1.45
21 .0
K ' U K.
e max b
day"1 Ibs/day/tb Ib/day/lb
92 100
85 100
106 100
27 25
2.05 12.3
2.15 20.0
6.31 27.0 '
4.61 6.3
21.4 100
38.9 50
55.7 100
14.6 20
102
101
101
25
15.6
25.0
29.2
7.0
108
51
101
22
-------
FATE OF SPECIFIC CHEMICALS
The removal mechanism for each specific chemical during biological
treatment by the activated sludge process was determined. Stripping was
determined by measuring the off-gases. Sorption was determined by 2^-hours
continuous solvent extraction or by purging sludge samples. Biological
degradation was assumed to account for the rest of the removal. The percent
treatment achieved by each mechanism for the single chemical systems is
shown in Table 19, and the percent treatment achieved by each mechanism for
the combined systems is shown in Table 20. It is seen that 1 ,2-dichloro-
ethylene was the only chemical removed by stripping. However, the" removal
was not solely by stripping. Biological removal of 1,2-dichloroethylene
also occurred. In the single chemical systems, 37 percent of the 1,2-di-
chloroethylene was stripped; however, when combined with ^-nitrophenol and
2,^,6-trichlorophenol, 62 percent was stripped.
Only four organic chemicals were removed by sorption in the single
chemical systems; these being, hydrazobenzene, 2,i»,6-trichlorophenol ,
anthracene, and hexachloroethane. The chemical ^-nitrophenol was probably
removed by sorption but problems with analysis of the sludge prevented
determining whether this was true or not. In the combined systems, these
compounds responded in a slightly different manner with different levels
of sorption being observed. This probably was due to'the problem associated
with measuring the small quantities that were sorbed. Also, sorption capa-
bilities of certain chemicals may be changed when in the presence of other
chemicals.
It is seen that the only removal mechanism for the metals was sorption.
Similar levels of removal were observed in both the single and combined
systems. .
It was also found that all of the organic chemicals were biodegraded
to some degree. Kincannon and Stover (1-5) have previously reported this
with other organic priority pollutants. . This shows that biological treat-
ment is an effective treatment process for organic priority pollutants.
The effluent concentrations for the chemicals that were achieved by
the treatment process are shown in Table 21. This data shows that, when
biological treatment is the major mechanism-of removal, the effluent con-
centrations achieved are lower than those achieved by other removal mech-
anisms. Sorption seems to be the most inefficient removal mechanism.
33
-------
TABLE 19. REMOVAL MECHANISMS FOR SPECIFIC CHEMICALS IN SINGLE SYSTEMS
Chemical
Phthalates
Dimethyl
Nitrogen Compound
Hydrazobenzene
Phenols
4-Nitro
2,4,6-Trichloro
Polynuclear Aromatics
Anthracene
Fluoranthene
2-Chloronaphthalene
Halogenated Hydrocarbons
Hexachloroethane
1,2 dichloroethylene
Metals
Nickel
Cadmium
Chromi urn
PERCENT TREATMENT ACHIEVED
Stripping
0
0
0
0
0
0
0
37.0
0
0
0
Sorption Biological Tota
0 99.5 99.5
0.3 38.1 38.4
.93.1* 93.1
-,4.2 74 ,.4 78.6
8.7 14.6 23.3
0 80.6 80.6
0 98.3 98.3
0.4 87.1 87.5
0 62.0 99.0
23.1 0 23.1
67.7 0 67.7
60.8 0 60.8
* 4-nitrophenol was removed by sorption and biological means both, but
mechanisms could not be separated.
-------
TABLE 20. REMOVAL MECHANISMS FOR SPECIFIC CHEMICALS IN COMBINED SYSTEMS
Chemical
PERCENT TREATMENT ACHIEVED
Stripping Sorption Biological Total
Phthalates
Dimethyl
Nitrogen Compounds
Hydrazobenzene
Phenols
4-nitro
2,4,6-trichloro
Polynuclear Aromatics
Anthracene
Fluoranthene
2-chloronaphthalene
Halogenated Hydrocarbons
Hexach1oroethane
1,2 dichloroethylene
Metals
Nickel
Cadmium
Chromium »
0
0
0
0
0
0
62.1
0
0
0
0.6
3.7
0
3.8
0
0
23.0
65.8
40.1
92.0
53.4
90.2
2.7 94.1
85.3
81.6
96.4
-98.8
37.6
92.6
57.1
90.2
96.8
85.3
85.4
96.8
98.8
99.7
0 23.0
0 65.8
0 40.1
'35
-------
TABLE 21. EFFLUENT ACHIEVED FOR SPECIFIC CHEMICAL
Chemical
Influent
ug/£
Effluent Achieved, ug/£
Biological Sorption Biological Biological
plus plus
Stripping Sorption
Phthalates
Dimethyl 37250
Nitrogen Compound
Hydrazobenzene 4l80
Phenols
4-nitro 32300
2,4,6 trichloro 14830
Polynuclear Aromatics
Anthracene 63
Fluoranthene 134
2-chloronaphthalene 2020
Halogenated Hydrocarbons
Hexachloroethane 3720
1,2 dichloroethylene 29200
Metals
Nickel 3860
Cadmiurn . 3680
Chromium 3570
197
26
35
2573
2217
1283
48
.278
391
3059
1187
1080
36
-------
REFERENCES
1. Kincannon, Don F. and Enos L.. Stover. Biological Treatability of
Specific Organic Compounds Found in Chemical Industry Wastewaters.
Proceedings 36th Annual Purdue Industrial Waste Conference, West
Lafayette, Indiana, 1981.
2. Kincannon, Don F. and Enos L. Stover. Fate of Organic Compounds During
Biological Treatment. Proceedings National Conference on Environmental
Engineering, ASCE, Atlanta, Georgia, 1981.
3. Kincannon, Don F., Enos L. Stover, Virgil Nichols, and David Medley'.
Removal Mechanisms for Biodegradable and Non-Biodegradable Toxic
Priority Pol 1utants in Industrial Wastewaters. .Proceedings, Industrial
Wastes Session, 5^th Annual Water Pol 1ution Control Federation
Conference, Detroit, Michigan, 1981 .
*». Kincannon, Don F. , Enos L. Stover and Yu-Ping Chung. Biological
Treatment of Organic Compounds Found in Industrial Aqueous Effluents.
Presented at American Chemical Society National Meeting, Atlanta,"
Georgia, 1981.
5. Kincannon, Don F. and Enos L. Stover. Stripping Characteristics of
Priority Pollutants During Biological Treatment. Presented at
Secondary Emissions Session of the 7*»th Annual. American Institute
of Chemical Engineers Meeting, New Orleans,.Louisiana. 1981.
37
-------
APPENDIX
This appendix provides the raw data collected during this study. It
is provided so that others interested in the treatment of wastewaters con-
taining priority pollutants may have the opportunity of conducting additional
analysis of the data if they so desire.
38
-------
COMPOUND sflNTHRRCENE
PflRflMETER =BOD
THETfl C = 1
VOLUME-REFlCTOR = 3.13
DflTE
1982
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/24
11/29
12V01
12/93
12/06
12/08
12/16
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MEflN
S.DEV
C V >;
SI
202
259
254
276
278
276
305
306
349
207
337
334
263
256
238
249
339
335
268
271
285
299
279
366
273
70.75
25.8
SE
0.8
4.5
12.5
4.6
0.9
0.7
1.3
1.7
11.0
0.0
2.1
2.0
0.8
1.7
2.8
0.5
1-3
1.5
3.0
' 5.5
1.9
1.8
0.3
1.9
2.6
3.09
120.2
F
9.50
9.36
9.36
9.65
9.07
8.93
9.36
9.50
9.36
9.65
9.65
3.93
9.65
9.22
9.50
9.50
9.36
6.48
9.22
9.22
8.93
9.36
8.93
8.93
8.82
1 . 93
21.9
FW
3.13
3.13
3.08
3.10
3.10
3.13
3.10
3.09
3.00
2.98
3.13
3.10
3.04
3.04
3.05
2.95
1.70
0.00
0.00
2. 96
0.30
3.13
2.60
3.84
2.51
1.12
44.7
X
390
590
630
400
470
730
370
343
336
623
885
1047
948
425
458
427
428
416
183
353
390
262
306
530
478
234.
49.1
XE
0
. 0
16
. 2
2
0
2
4
8
14
0
2 -
14
7
6
13
82
258
98
13
7
0
26
8
23
91 54.5
234.1
FSI
XV
1.572
1.313
1.206
2.127
1.714
1.079
2.465
2.708
3.106
1.024
1.174
0.910
0.855
1.774
1.577
1.770
2.369
1.667
4.314
2.261
2.085
3.413
2.601
1.970
1.882
.91
48.8
F
-------
COMPOUND =RHTHRfiCENE
PflRflMETER =BOD
THETfl C = 3
VULUME-RERCTOR = 3.14
DflTE
1982
11/01
11/83
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/03
12/10
12/13
12/15
12/20
12/22
12/27
HERN
S.DEV
C V '/.
SI
202
259
254
276
273
276
305
306
319
295
207
287
337
334
263
256
-233
249
. 339
355
271
285
279
281
39.65
14
SE
0.5
2.7
12.5
0.6
0.4
1.1
0.0
1.1
1.6
1.3
0.0
1.3
0.3
0.-6
0.4
1.5
4.3
0.2
0.6
0.6
'3.3 '
2.0
1.4
1.7
2.59
153.6
F
9.36
9.65
9.22
9.50
9.36
9.36
9.65
9.36
9.36
9.50
9.65
9.36
9.14
9.22
9.36
9.36
9.65
9.65
9.50
6.19
9.65
8.64
9.65
9.28
.71
7.6
FW
1.04
0.90
1.03
1.04
1.02
0.00
0.00
0.00
0.00
0.00
0.65
0.00
0.00
0.37
1.00
0.70
1 . 00
0.95
0.00
0.00
0.90
3.22
0.00
0.47
.46
99.2
X
830
940
1040
970
940
860
295
410
719
568
997
645-
865
841
1260
1864
2250
2913
1065
975
741
654
1274
1001
477.1
47.6
XE
0
20
2
0
2
114
180
150
349
555
44
262
102
80
20
80
8
24
294
247
11
64
201
122
141.73
116
FSI
XV
0.725
0.847
0.717
0.861
0.882
0.957
3.177
2.225
1.323
1.571
0.638
1 . 326
1.134
1.166
0.622
0.409
0.325
0.380
0.963
0.718
1.124
1.199
0.673
1.042
.62
60.3
F TC
3.
2.
3.
3.
3.
2.
0.
0.
0.
3.
3.
0.
2.
2.
'£..
-------
COMPOUND =flNTHRflCENE
PRRflMETER =BOD
THETfl C = 6
VQLUME-REflCTOR
3.1
DflTE
1332
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/23
12/01
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/23
ME'flN
S.DEV
C V '/.
SI
202
259
254
276
278
276
305
306
313
295
207
287
337
334
238
249
333
355
268
271
285
293
279
366
287
41.38
14.6
SE
0.7
6.4
13.0
1.5
0.7
0.7
0.0
1.3
1'.6
1.2
1.6
.0.6
1.5
0.1
1.4
1.2
3.3
0.S
1.4
1.9
3.3
1.0
1.4
1.4
2.0
2.63
132.9
F
3.65
9.73
9.07
8l93
9.50
8.93 '
8.33
3.36
9.65
9.22
9.22
3.07
3.07
8.78
8.33
9.65
9.22
5.30
9.36
3.36
8.78
9.22
5.30
9.36
8.95
.38
10.9
FU
0.52
0.52
0.50
0.50
0.00
0.34
0.52
0.52
0.52
0.43
0.40
0.37
0.00
0.33
0.00
0.05
0.33
0.42
0.07
0.32
0.50
0.54
0.24
0.00
0.34
' .2
59.9
X
1330
1660
1650
1643 .
1500
1670
1800
1778
2861
2067
1380
1886
1551
1444
33fi
1103
373
1180
1333
1283
1313
1523
1473
1150
1548
463.07
29.3
XE
0
0
4
4
168
34
0
0
0
6
21
37
392
19
115
54
14
20
64
27
3
0
72
296
56
98.62
175.3
FSI
XV.
0.326
0.493
0.450
0.485
0.568
0.476
0.488
0.520
0.347
0.424
0.311
0.445
0.636
0.655
1 . 723
0.703
1.030
0.573
0.607
0.638
0.615
0.584
0.360
0.961
0.601
.29
49.2
F TC
5.
5.
5.
5.
2.
6.
5.
5.
5.
6.
6.
5.
1.
6.
1.
. 5.
6.
6.
6.
6.
5.
5.
6.
1.
5.
1.
31
96
36
95
96
91.
02
96
96
96
02
23
73
35
20
20
96
00
04
01
03
.37
74
00
23
27
66
.6
41
-------
COMPOUND =flNTHRflCENE
PflRRMETER =COD
THETR C * 1
VOUJME-RERCTQR =3.13
DflTE
1382
SI
SE
FW
XE
FSI
XV
F
XV
TC
11/05
11/12
11/19
12/03
12/10
12/17
12/24
12/29
550
500
390
420
410
410
455
455.
23 . 0
20.0
86.0
36.0
37.0
76.0
18.0
37.0
9.36
3.33
3.36
9.65
9.50
9.22
9.36
8.93
3.08
3.13
3.00
3.04
2.95
0.00
3.13
3.04
MEflN 449
S.DEV 53.76
C V '/. 11.9
42.3
25. 16
59.5
9.29
.25
2.7
630
730
336
948
427
183
262
530
2.67
1.08
40.4
16
0
8
14
13
98
0
2.611
1.954
3.471
1.366
2.914
600
193
2.
1.
2.
1.
.478
,376
.706
.249
2.651
5.376
4.988
0.97
1.00
0.99
1.00
0.99
0.63
2.449 2.250
5@6 20 3.329 2.947
256.48 32.23 1.74 1.46
50.7 164.2 52.6 49.5'
00
00
0.95
.12
13.4
42
-------
COMPOUND =RNTHRRCENE
PRRRMETER =COD
THETfl C = 3
VOLUME-RERCTOR = 3.14
DRTE
1982
11/05
11/12
11/19
11/26
12/03
12/10
12/17
MERH
S.DEV
c. v >;
31
550
500
390
360
420
410
410
380
165.44
43.5
SE
63.0
14.0
29.0
72.0
46.0
39.0
90.0
42.6
30.24
70.9
F
9.22
9.36
9.36
9.36
9.36
9.65
9.65
3.25
3.33
40.4'
FW
1.03
0.08
0.00
0.00
1.00
0.95
0.00
0.37
.51
138.
X
1340
860
719
645
1260
2013
629
896
581.94
1 64.9
XE
2
114
349
262
23
24
381
144
161.
112.
FSI
XV
1.553
1 . 733
1.617
1 . 664
0.994
0.626
2.003
1.274
99 .67
4 53.1
FCSI-SE) TC
XV
1
1
1
1
0
0
1
1
g
.383
.685
.497
.331
.885
.583
.563
.116
.58
2.1
3.
2.
3.
0.
2.
.2.
0.
1.
1.
75
00
53
69
83
77
98
54
67
26
.8
43
-------
COMPOUND =RHTHRRCEHE THETR C = 6
PflRRMETER =COD VOLUME-RERCTOR =3.1
DflTE
1382
11/05
11/12
11/19
11/26
12/10
12/17
12/24
12/29
HERN
S.DEV
C V '/.
SI
550
500
390
360
410
410
455
455
441
61.91
14
SE
81.0
66.0
8.0
27.0
39.0
38.0
10.0
14.0
35.4
26.61
75.2
F
9.07
8.93
9.65
9.07
9.65
9.36
9.22
9.36
9.29
.26
2.8
FW
0.50
0.34
0.52
0.35
0.05
0.07
0.54
0.00
0.30
.22
76
X
1165
1670
2624
1886
1103
1333
1523
1150
1557
512.17
32.9
XE
4
34
0
37
54
64
0
296
61
98.03
160.3
FSI
XV
1.381
0.862
0.463
0.558
1.157
0.929
0.839
1.195
0.929
.31
33.7
F
-------
COMPOUND =RNTHRflCENE THETfl C = 1
PRRRMETER. =TOC VOLUME-RERCTOR = 3.13
DflTE
1382
11/08
11/10
11/12
11/15
11/17
1 1/24
11/29
12/01
12/03
12/06
12/03
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/23
MEfiN
3.DEV
C V '/.
SI .
128
116 '
122-
93
94
110
153
128
146
152
141
163
161
115
148
162
120
160
120
124
133
22.46
16.8
SE
40.0
48.0
51.0
33.0
23.0
31.0
50.0
36.0
51.0
27.0
26.3
32.0
22.0
41.0
40.0
28.0
59.0
35.0
48.0
45.0
38.6
10.32
26.7 .
F
9.65
9.07
8.93
9.36
9.50
9.65
9.65
8.93
9.65
9.22
3.50
9.50
9.36
6.48
9.22
9.22
8.93
9.36
8.93
8.93
9.15
.68
7.4
FW
3.10
3.10
3.13
3.16
3.09
2.98
3.13
3.19
3.04
3.04
3.05
2.95
1.70
0.00
0.00
2.90
3.00
3.13
2.60
3.04
2.66
.96
36.2
X
400
470
730
370
343
623
S85
1047 .
948
425
458
427
428
416
133
353
390
262 .
386
530
500
232.03
46.4
XE
2
2
0
2
4
14 -
0
2
14
7
6
13
32
258
98
13
7
0
26
8
28
60.24
215.9
FSI
XV
0.987
0.715
0.477
0.748
0.832
0.544
0.550
0.343
0.475
1 . 054
0.934
1.153
1.125
0.572
2.382
1.352
0.878
1.826
1.119
0.668
0.937
.49
52.3
FCSI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
1.
.0.
0.
0.
.
59
678
419
277
481
584
391
376
251
309
866
762
931
971
368
738
118
446
427
671
425
675
4
.4
1
1
1
1
0
1
. 1
1
1
1
1
0
0
0
0
1
1
1
1
1
0
m
9
.00
.00
.00
.00
.33
.00
. 00
.01
.00
.00
.00
.39
.99
.78
.63
.00
.01
.00
.00
.00
.97
09
.5
45
-------
COMPOUND <=RHTHRfiCENE
PflRflMETER =TOC
THETfl C = 3
VOLUME-RERCTOR =3.14
DfiTE
1982
11/03
11/10
11/12
11/15
11/17
11/22
11/24
11/29
12/01
12/03
12/96
12/08
12/10
- 12/13
12/15
'12/17
12/20
12/22
12/27
MEftN
S.DEV
c v /.
SI .
123
116
122-
' 93
34
' 85
110
158
128
146
152
141
163
161
115
148
.162
120
120
130
24.56
18.9
SE
40.0
43.0
53.0
20.0
22.0
27.0
27.0
22.0
23.0
17.0
20.0
25.0
19.0
12.0
35.0
41.0
40.0
44.0
32.0
29.8
11.13
37.3
F
9.50
9.36
9.36
9.65
9.36
9.50
9.65
9.14
9.22
9.36
9.36
9.65
9.65
9.50
6.13
9.65
9.65
8.64
9.65
9.27
.78
8.4
FW
1.04
.1.02
0.00
0.00
0.00
0.00
0.65
0.00
0.37
1.00
0.70
1.00
0.95
0.00
fl.ciR
0.00
0.30
0.22
0.00
0.41
.45
109.
X
970
940
860
295 .
410
563
977
865
841
1260
1864
2250
2013
1065
975
625
741
654
1274
1024
521.55
5 50.9
XE
0
2
114
180
150
555
44
102
80
20
30
8
24
294-
247
381
11
64
201
135
143.
110.
FSI
XV
0.393
0.368
0.423
0.964
0.683
0.453
0.346
0.532
0.447
0.345
0.243
0. 193
0.249
0.457
0.233
0.723
0.672
0.505
0.289
.0.449
17 .13
1 .44.1
F(SI-SE> TC
XV
0.
0.
e.
0.
@.
0.
0.
e.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. .
.45
274
231
233
755
523
309
261
458
343
305
211
158
220
423
162
523 .
506
320
212
339
15
.8
3.
3.
2.
0.
0.
0.
2.
2.
2.
2.
2.
3.
2.
1.
2.
3.
3.
3.
2.
. 2.
.
44
02
03
53
53
92
34
98
31
59
77
93
05
38
20
00
54
05
01
06
23 .
39
.7
46
-------
COMPOUND sflNTHRRCENE
PRRRMETER =TOC
THETfl C a 6
VOLUME-RERCTOR = 3.1
DRTE
1982
11/08
11/10
11/12
11/15
11/17
11/22
11/24
11/26
11/23
12/01
12/08
12/10
12/13
:. 12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
C V '/.
SI
128
116
122
93
94
85
110
123
158
128
141
163
161
115
148
162
120
160
120
124
129
24.13
18.7
SE
43.0
47.0
52.5
31.9
28.0
31.0
25.0
18.0
9.0
17.0
15.0
23.0
18.0
19.0
16.0
44.0
35.0
12.0
38.0
10.0
' 26.6
13.09
49.2
F
8.93
9.50
8.93
8.93
9.36
9.22
9.22
9.07
9.07
8.78
8.93
9.65
9.22
5.90
9.36
9.36
8.78
9.22
5.90
9.36
8.83
1.93
11.6
FW
0.50
0.00
0.34
0.52
0.52
0.49
0.40
0.37
0.00
0.39
0.00
0.05
0.39
0.42
8.07
0.32
0.50
0.54
0.24
0.00
0.33
.2
67.5
X
1640
1530
1670
1880
1778
2067
1988
1889
1551 .
1444
398
1103
979
1180
1335
1283
1313
1523
1473
1150
1452
387.38
26.6
XE
4
168
34
0
0
6
21
37
392
19
115
54
14
20 "
64
27
3
0
72
296
67
104.89
155.8
FSI
XV
0.225
0.237
0.210
8.148
0.160
0.122
0.165
0.191
0.298
0.251
1.021
0.460
0.489
0.185
0.335
0.381
0.259
0.312
0.155
0.326
0.297
.19
66.9
F(SI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
8.
0.
0.
0.
0.
0.
0.
. 9.
0.
0.
0.
0.
t
77
149
141
120
098
112
678
128
163
281
218
912
395
434
155
299
278
183
289
106
299
242
18
.5
5.
2.
6.
5.
5.
6.
6.
5.
1.
6.
1.
5.
6.
6.
6.
6.
5.
5.
6.
1.
5.
1
35
96
91
02
96
96
02 .
28
73
35
20
20
96
00
04
02
08 .
97
74
00
29
13
.8
47
-------
COMPOUND =DIMETHYL PHTHRLRTE
PRRRMETER =BOD
THETR C = 1
VOLUnE-REflCTOR = 3.1
DRTE
1932
11/01
11/03
11/05
11/08
11/12
11/15
11/17
11/13
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/88
12/1(3
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
C V '/.
SI
180
244
262
286
315
360
331
366
336
290
285
324
364
314
295
327
270
345
411
329
312
300
310
306
352
313
45.95
14.7
SE
5.3
11.9
7.5
6.1
5.0
3.3
3.2
1.0
4.0
2.9
3.2
2.1
6.9
3.3
6.7
9.0
7.5
18.8
19.5
11.9
. 7.2
2.1
0.0
0;e
3.7
6.1
5
81.7
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.22
9.36
9.50
9.50
9.50
9.50
9.50
9.50
8.36
9.50
9.50
9.22
9.22
9.50
9.50
9.50
9.50
9.50
9.40
.29
3.1
FU
2.96
2.30
2.97
2.99
3.08
2.89
2.91
2.97
2.95
2.95
2.95
2.64
2.76
2.72
2.43
2.84
2.39
2.57
2.61
2.66
2.47
2.59
3.10
2.70
3.02
2.30
.2
7.4
X
41.0
430
450
520
530
500
630
490
600 .
960
520
480
560
570
420
570-
400
470
430
430
409 .
350
419
408
281
491
126.77
25.8
XE
9
19
9
9
2
16
13
10
14
22
12
32
28
32
40
28
40
36
32
32
36
26
0
15
2
21
12.41
59.7
FSI
XV
1 . 345
1.739
1,784
1.685
1.821
2.206
1.610
2.222
1.691
0.926
1.680
2.069
1.992
1.688
2.152
1.492
2.069
2.249
2.843
2.039
2.390
2.627
2.267
2.298
3.839
2.029
.55
27.5
F(SI-SE)
XV
'l.
1.
1.
1.
1.
2.
1.
2.
1.
0.
1.
2.
1.
.1.
2.
1.
2.
2.
2.
1.
2.
2.
2.
2.
3.
1.
302
654
733
650
792
1S6
595
215.
671
916
661
055
954
670.
104
451
011
127
708
965
335
603
267
294
798
939
55
27.7
TC
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.80
.00
.00
.00
.00
.00
.00
.03
.00
.00
.00
.00
.00
.05
.01
.00
.01
48
-------
COMPOUND =DIMETHYL PHTHRLRTE
PflRRMETER =BOD
THETR C = 3
VOLUME-REflCTOR * 3.1
DRTE
1982
11/01
11/03
11/05
11/08
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/08
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
c v '/.
SI
180
244
262
286
315
360
331
366
336
290
285
324
364
314
295
327
345
411
329
312
300
. 310
306.
352
302
77.36
25.6
SE
1.6
7.5
12.9
5.3
1.0
2.6
1.1
0.2
0.3
.0.1
1.4
0.2
0.2
0.4
4.6
1.4
2.2
3.1
2.5
3.5
3.3
0.9
0.6
1.7
2.3
2.87
122.6-
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.93
9.97
9.22
9.22
9.22
9.22
9.22
9.22
3.35
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.80
1.84
20.9
FW
0.34
0.34
0.00
0.00
0.99
0.82
0.90
0.97
0.97
0.98
0.80
0.91
0.95
0.00
0.00
0.84
0.35
0.41
0.42
0.71
0.91
1.03
0.87
0.72
0.61
.38
62.4
X
690
830
540
720
790
1100
1280
1350
1710
1680
1470
1320
1130
1200
900
1270
1500
1470
1310.
1280
1110
986
1008
1023
1109
379.03
34.1
XE
54
63
81
110
4
28
20
10
14
19
40
20
12
224
380
32
116
104
92
43
16
0
12
26
61
83.94
137.8
FSI
XV
0.776
0.825
1.443
1.181
1.186
0.973
0.769
0.781
0.575
0.513
0.577
0.730
0.938
0.778
0.975
0.694
0.684
0.832
0.747
0.725
0.804
0; 935
0.903
1.023
0.815
.26
32.9
F
-------
COMPOUND =DIMETHYL PHTHHLRTE
PRRRMETER =BOD
THETfl C » 6
VOLUME-RERCTOR =3.3
DflTE
1932
11/01
11/03
11/05
11/08
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
.12/01
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
C V *
SI
180
244
262
286
315
360
331
366
336
290
285
324
364
314
295
327
270
345
411
329
312
300
310
306
352
313 -
45.95
14.7
SE
1.6
2.3
12.2
6.0
3.0
4.9
3.6
0.7
2.8
0.0
0.4
1.0
6.3
2.2
0.8
11.6
2.2
2.9
3.7
3.1
2.9
3.2
1.6
0.5
1.6
3.0
3.04
101.5
F
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
10.08
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.80
.05
.5
FW
0.40
0.00
0.37
0.00
0.27
0.40
0.00
0.00
0.00
0.49
0.00
0.00
0.00
0.00
0.00
0.00
0.33
0.25
0.46
0.46
'0.48
0.47
0.47
0.46
0.37
0.23
.21
94
X
1730
1000
1510
620
890
900
760
650
700
880
910
720
690
570
520
850
1030
1670
1270
1660
1680
1420
1490
1472
1S06
1096
425.44
38.8
XE
29
360
29
144
26
14
152
124
110
6
120
160
108
192
244
60
24
52
12
16
12
12
9
10
24
82
89.43
109.1
FSI
XV
0.309
0.724
0.515
1.363
1.050
1.187
1.292
1.670
1.424
0.978
0.929
1.335
1.565
1.634
1.683
1.175
0.778
0.613
0.960
0.583
0.551
0.627
0.617
0.617
0.578
0.391
.41
42.2
FCSI-SE) TC
XV
0.
0.
0.
1.
1.
1.
1.
1.
1.
0.
0.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
306
717
491
340
040
171
278
667
412
978
928
331
564
623
678
133
771
608
951 '
582
546
620
614
616
576
982
41
42.4
5.
0.
5.
1.
6.
6.
1.
1.
2.
5.
2.
1.
2.
1.
0.
4.
6.
6.
6.
6.
6.
6.
6.
6.
6.
4.
2
53
92
94
99
45
02
04
69
77
15
96
56
52
15
00
72
64
00
03
02
00
04
01
27
31
66
23
.25
.2
50
-------
COMPOUND =DIMETHYL PHTHRLRTE
PRRRMETER =COD
THETfl C = 1
VOLUME-RERCTOR =3.1
DRTE
1982
11/05
11/12
11/19
11/26
12/03
/12/10
12/17
12/24
MEfiH
S.DEV
C V '/.
SI
810
423
468
450
550
490
380
475
505
132.78
26.2
SE
33.
66.
59.
72.
94.
53.
35.
28.
55.
22.
41
0
0
0
0
0
0
0
0
0
56
F
9.50
9.50
9.22
9.50
9.50
9.50
9.22
9.50.
9.43
.12
1.3
FW
2.97
3.08
2.97
2.95
2.72
.2.39
2.66
3.10
2.86
.24
8.5
X
450
530
490
520
570
400
480
419
4S2
57.66
11.9
XE
9
2
10
12
32
40
32
0
17
15.26
89.1
FSI
XV
5.516
2.428
2.841
2.652
2.957
3.754
2.355
3.474
3.247
1.03
31.9
F
-------
COMPOUND .-DIMETHYL PHTHflLflTE THETfl C = 3
PflRRMETER =COD VOLUME-REflCTOR =3.1
DflTE
1382
SI
SE
F
FU
X
XE
FSI
XV
F(SI-SE)
XV
TC
11/05 318 37.0 9.22 0.00 540 81 4.461 4.258 2.24
11/13 468 8.0 8.93 0.97 1350 10 0.999 0.982 3.01
11/26 450 23.0 9.22 0.80 1470 40 .0.910 0.864 3.01
12/03 550 24.0 9.22 0.00 1200 224 1.363 1.304 1.80
12/10 490 31.0 9.22 1.03 1500 0 0.972 0.910 3.01
12/17 380 50.0 9.22 0.42 1310 92 0.863 0.749 2.99
12/24 475 18.0 9.22 1.03 986 0 1.433 1.379 3.01
MEflH 453 23.9 8.03 0.53 1045 56 1.375 1.306 2.38
S.DEV 223.44 15.86 3.24 ..48 524.46 77.39 1.32 1.26 1.06
C V '/. 49.3 66.4 40.4 90.5 50.2 133.5 96 96.8 44.7
52
-------
COMPOUND =DIMETHYL PHTHRLRTE
PRRRMETER =COD
THETR C » 6
VOLUME-REflCTOR =3.3
DRTE
1982
11/05
11/12
11/19
11/26
12/03
12/10
12/17
12/24
'HERN
S.DEV
c v /.
SI
810
420
468
450
550
- 490
380
475
505
132.78
26.2
SE
37.0
88.0
24.0
15.0
43.0
43.0
38.0
18.0
.38.3
22.91
59.9
F
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
0
0
FW
0.37
0.27
0.00
0.00
0.00
0.33
0.46
0.47
0.24
.2
87.1
X
1510
890
650
910
570
1030
1660
1490
1089
414.26
38
XE
29
26
124
120
192
24
16
9
68
63.26
101.1
FSI
XV
1.591
1.400
2.136
1.467
2.863
1.411
0.679
0.946
1.562
.68
43.5
F
-------
COMPOUND =DIMETHYL PHTHHLflTE
PflRflMETER =TOC
THETfl C » 1
VOLUME-REfiCTOR = 3.1
DflTE
1982
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
. 12/01
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
. 12/24
12/27
12/29
MEflN
S.DEV
c v '/.
SI
130
133
146
106
111
107
116
118
171
. 171
136
169
173
154
173
128
169
143
218
184
194
148
131
149
30.31
20.3
SE
49.5
46.0
48.5
31.0
22.0
36.0
25.0
21.0
25.5
30.0
8.0
30.0
29.0
47.0
31.0
22.0
30.0
32.0
30.0
58.0
40.0
31.0
36.0
33.0
11.21
33.9
F
9.50
9.50
9.50
9.50
9.50
9.22
9.36
9.50
9.50
9.50
9.50
9.50
9.50
8.06
9.50 .
9.50
9.22
9.22
9.50
9.50
9.50
9.50
9.50
9.39
.3
3.2
FW
2.99
3.00
3.08
2.39
2.91
2.97
2.95
2.95
2.95
2.64
2.76
2.72
2.43
2.84
2.39
2.57
2.61
2.66
2.47
2.59
3.10
2.70
3.02
2.79
.21
7.7
X
520
1060
530
500
630
490
600
960
520
480
560
570
420
570
400
470
' 430
480
400
350
419
408
281
524
174.86
33.3
XE
9
16
2
16
18
10
14
22
12
32
28
. 32
40
28 .
40
36
32
32
36
26
0
15
2
22
12.47
57.6
FSI
XV
0.766
0.385
0.844
0.650
0.540
0.649
0.584
0.351
1.008
1.092
0.744
0.909
1.262
0.702
1.325
0.835
1.169
0.886
1.670
1.611
1.419
1.112
1.429
0.954
.37
39.1
F
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
1.
0.
0.
0.
1.
1.
1.
0.
1.
0.
42
474
252
564
460
433
431
458
284
857
903
700
747
051
488
088
691
961
688
440
103
126
879
036
744 '
31
*
TC
1
1
1
1
1
1
1
1
1
1
1
' 1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00 .
.00
.00 .
.00
.00
.00
.00
.00
.05
.01
.00
.01
54
-------
COMPOUND =DIMETHYL PHTHRLRTE
PRRRMETER »TOC
THETfl C <* 3
VOLUME-REflCTOR = 3.1
DRTE
1382
11/03
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12^06
12/08
12/16
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
C V '/.
SI
130
133
146
106
111
107
116
110
171
171
. 136
169
173
154
173
12S
169
143
218
184
194
148
131
149
30.31
20.3
SE
43.
46.
50.
35.
29.
34.
24.
17.
16.
19.
15.
9.
17.
9.
12.
22.
36.
19.
38.
5.
. 43.
22.
13.
25.
13.
54.
0
0
0
0
0
0
0
0
5
0
5
0
0
0
0
0
3
0
0
0
0
0
0
4 .
33
5
F
9.22
9.22
9.22
9.22
9.22
8.93
9.07
9.22
9.22
9.22
9.22
9.22
9.22
8.35
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.16
.18
2
FW
0.00
0.83
0.99
0.82
0.90
0.97
0.97
0.93
0.30
0.91
0.95
0.00
0.00
0.84
1.03
0.35
0.41
0.42
0.71
0.91
1.03
0.87
0.72
0.71
.34
47.7
X
720
1000
790
1100 .
1280
1350
1710
1680
1470
1320
1130
1200
300
1270
1580
1580
1470
1310
1230
1110
986
1008
1023
1222
264.34
21.6
XE
110
23
4
28
20
10
14
10
40
20
12
224
380
32
0 '
116
104
32
48
16
0
12
26
58
87.87
150.7
FSI
XV .
0.537
0.396
0.550
0.287
0.253
0.228
0.193
0.195
0.346
0.385
0.358
0.419
0.572
0.327
0.343
0.254
0.342
0.325
0.507
0.493
0.585
0.437
0.381
0.379
.11
31.1
F TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
32
339
259
361
192
191
156
157
165
313
342
317
397
516
308
319
210
269
282
418
480
440
372
343
311
1
.7
2.20
3.03
3.00
3.00
3.01
3.01
2.99
3.01
3.01
2.99
2.99
1.80
0.80
3.01
3.01
2.99
3.00
2.99
3.01
3.01
3.01
3.20
3.31 '
2.34
.54
19.1
55
-------
COMPOUND =DIMETHYL PHTHRLRTE
PRRRMETER =TOG
THETfl C » 6
VOLUME-RERCTOR =3.3
DflTE
1932
11/03
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/0.1
12/03
12/06
12/08
12/19
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.DEV
C V '/.
SI
130
133
146
106
111
107
116
110
171
171
136
169
173
154
173
128
169
143
218
134
194
143
131
149
30.31
20.3
SE
43.5
61.0
47.0
32.0
20.0
33.0
60.0
19.0
41.0
25.5
29.0
15.0
33.0
11.0
22.0
27.0
28.0
36.0
23.0
27.0
3.0
23.0
28.0
30.0
14
46.7
F
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
10.03
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.80
.06
.6
FW
0.00
0.00
0.27
0.40
0.00
0.00
0.00
0.49
0.00
0.00
0.00
0.00
0.00
0.00
0.33
0.25
0.46
0.46
0.48
0.47
0.47
0.46
0.37
0.21
.21
101.
X
620
780
890
908
760
650
700
880
913
720
690
570
520
850
1030
1670 .
1270
1660
1680
1420
1490 .
1472
1806
1041
415.12
8 39.8
XE
144
69
26
14 .
152
124
110
6
120
160
108
192
244
60
24
52
12
16
12
12
9
10
24
74
69.97
94.6
FSI
XV
0.622
0.506
0.487
0.349
0.433
0.438
0.492
0.371
0.557
0.705
0.585
0.380
0.987
0.553
0.493
0.227
0.395
0.256
0.385
0.384
0.386
0.298
0.215
0.431
.18
39.4
F
-------
COMPOUND =HEXRCHLOROETHflME
PflRflMETER =BOD
THETfl C = 1
VOLUME-RERCTOR =3.17
DflTE
1982
11X01
11/03
11/05
11/SS
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/83
12/06
12/03
12/19
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
NERH
S.DEV
C V '4
SI
205
245
219
319
322
322
355
357
'362
302
270
234
251
322
239
245
218
221
' 330
307
298
240
249
266
268
261
278
47.38
17
SE
11.0
12.2
11.5
11.2
3.1
6.2
10.0
8.4
2.1
3.0
3.5
1.7
'2.7
5.8
1.2
1.6
2.6
2.2
5.2
4.6
4.5
2'. 4
6.2
2.0
1.8
2.5
5.0
3.55
71.4
3.
9.
9.
9.
9.
9.
3.
9.
9.
9.
9.
9.
9.
9.
9.
3.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
.
F
50
50
50
40
50
59
59
50
50
50
50
50
50
50
50
RPi
50
50
50
50
50
50
50
50
50
50 .
50
01
2
FW
2.83
2.50
2.94
3.10
3.00
3.18.
3. 10
3.10
3.10
3.17
3.11
2.96
3.06
3.17
3.17
3.01
3.00
2.45
2.95
2.96
3.05
1.55
0.89
3.17
2.97
3.05
2.86
.52
18.3
X
379
395
555
300
310
336
260
771
894
1285
1296
1068
633
1257
971
501
447
322
437
314
561
480
325
498
482
323
594
328.59
55.3
XE
18
36
18
0
6
4,
.3
0
0
0
12
25
11
0
0
12
12
33
15
10
10
98
86
0
15
6
17
24.36
147.3
FSI
XV
1.621
1 . 859
1.183
3.153
3.113
2.500
4.092
1 . 388
1.213
0.704
0.624
0.657
1.188
0^768
0.738
1.466
1.462
2.057
2.263 .
2.930
1.592
1.498
2.296
1.627
1.666
2.422
1.772
.87
49.5
FC
i.
1.
1.
3.
3.
2.
3.
1.
1.
0.
0.
0.
1.
0.
0.
1.
1.
2.
2.
2.
1.
1.
2.
1.
1.
2.
1,
.
49
SI-SE)
XV
534
766
120
042
083
452
977
355
206
697
616
652 .
176
754
734
456
444
036
227 .
886
568
483
239
615
655
398
737
85
.2.
TC
1.01
1.01
1.01
1.02
1.01
1.00
1.00
1.02
1.02
1.00
1 . 00
1.02
1.00
1.00
1 . 00
'1 . 00
1.00
1 . 00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0
.8 .
57
-------
COMPOUND =HEXflCHLORQETHRNE
PflRflMETER =BOD
THETfl C » 3
VOLUME-REflCTOR » 3.17
DflTE
1932
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MERN
S.OEV
C V *
SI
205
245
219
319
322
322
355
357
362
302
270
234
251
322
239
245
213
221
330
307
298
240
249
266
263
261
278
47.38
17
SE
1.1
9.7
10.7
5.1
5.6
1.4
1.0
0.7
0.7
0.1
5.0
1.7
0.6
1.0
1.0
0.9
1.5
6.9
.2.2
1.6
1.5
3.3
3.0
0.3
0.6
3.4
2.7
2.84
104.7
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.58
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
0
0
FW
0.93
0.65
0.95
1.00
0.61
0.56
0.58
1.00
1.00
1.00
0.95
0.81
1.00
1.00
1.04
0.20
0.20
0.57
0.10
0.83
1.05
0.05
1.05
1;05
0.97
0.98
0.78
.32
41.5
X
908
735
1026
1030
1170
1150
1210
1168
859
1092
1102
998
1438
995
348
835
823
760
310
437
891
542
676
810
1034
1316
935
265.28
28.3
XE
8
12
34
4
39
64
66
6
1
0
15
30
6
6
2
98
149
41
130 .
9
0
466
0
0
11
11
47
94.74
200.6
FSI
XV
0.677
0.999
0.640
0.928
0.825
0.839
0.879
0.916
1.263
0.329
0.734
0.703
0.506
0.970
0.845
0.830
0.794
0.871
3.190
2.105
1.002
1.327
1.104
0.984
8.741
0.594
1.004
.54
53.8
FCSI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
2.
0.
1.
1.
0.
0.
0.
0.
54
673
959
608
913
810
835
877
914
260
829
721
698
504
967
841
827
788
844
169
094
997
309
091
983
739
587
994
53
.1
3.
3.
2.
3.
3.
3.
2.
3.
3.
3.
2.
2.
3.
3.
2.
2.
1.
3.
0.
3.
3.
0.
3.
3:
3.
3.
2.
00
99
57
07
00
00
97
04
.14
17
97
96
06
02
99
58
63
01
78
00
02
39
02
02
00 .
02
79
74
26.5
58
-------
COMPOUND =HEXRCHLOROETHHNE
PfiRfiMETER =BOD
THETfl C = 6
VOLUME-REflCTOR =3.17
DflTE
1982
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/93
12/19
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MEflN
S.DEV
C V '/.
SI
205
245
219
319
322
322
355
357
362
302
278
234
251
322
239
245
213
221
330
307
298
240
249
266
268
261
273
47.33
17
SE
1.0
0.9
2.8
2.4
1.5
0.1
0.5
0.9
0.5
0.5
1.5
0.5
0.3
2.4
8.6
9.5
1.3
0.3
1.6
3.1
1.9
2.1
l.S
0.2
1.4
2.6
. 1.3
.83
65.2
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
. 9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
0
0
FW
0.53
0.48
8.45
0.47
0.52
0.51
0.52
0.45
0.51
0.51
0.53
0.23
0.52
0.36
0.53
0.33
9.27
0.33
0.10
0.40
0.53
0.05
0.44
0.36
0.53
0.43
0.42
.13
31.4
X
1430
1480
1300
1476
1658
1340 . .
1700
977
1336
1496
1502
1197
2016
1404
1233
1680
1400
1705
1524
1510
1531
1706
1381
150S
1613
1399
1483
201.95
13.6
XE
0
6
11
8
I
3
0
3
3
2
0
38
2
25
0
24
39
38
86
21
0
113
13
28
0
15
19
27.34
146.9
FSI
XV
0.430
0.496
0.505
0.650
0.582
0.720
0.626
1 . 095
0.783
0.695
0.539
0.586
0.373
0.687
8.581
0.437
0.467
0.388
0.649
0.609
0.583
0.422
0.540
0.529
0.498
0.559
0.575
,14
25.4
FCSI-SE
XV
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
@.
0.
0.
0.
3.
0.
0.
0.
0.
8.
0.
.
25
423
494
509
645
579
720
625
092
782
604
536
585
373
682
579
436
463
387
646
603
580
418
536
528
495
554
572
14
.5
> TC
5.
6.
6.
6.
6.
5.
6.
6.
5.
6.
5.
6.
5.
6.
5.
6.
6.
5.
5.
6.
5.
4.
6.
5.
5.
6.
5.
5.
93
14
02
11
33
98
10
fHS
99
07
98
05
99
06
98
09
01
99
03
02
98
69
03
98
98
01
94
32
4
59
-------
COMPOUND sHEXRCHLQRQETHRNE
PRRflMETER =COI>
THETfl C = 1
VOLUME-RERCTOR = 3.17
DRTE
1982
11/05
11/12
11/19
11/26
12/03
12/10
12/17
12/24
MERH
S.DEV
C V '/.
SI
640
640
430
510
420
425
395
429
485
101.31
20.8
SE
43.0
60.0
41.0
67.0
33.0
59.0 .
48.8
16.0
45.9
16.53
36
9.
9.
9.
9.
9.
9.
9.
9.
9.
0
0
F
50
50
50
50
50
50
50
50
50
i
FW
2.94
3.10
3.10
2.96
3.17
2.45
3.05
3.17
2.99
.23
7.9
X
555
386
894
1068
971
322
561
430
656
282.94
43
XE
18
4
0
25
0
33
10
0
11
12.76
113.5,
FSI
XV
3.456
4.969
1.441
1.431
1.296
3.955
2.110
2.569
2.653
1.35
50.9
F<
3.
4.
1.
1.
1.
3.
1.
2.
2.
1
50
SI-SE>
XV
224
503
304
243
194
406
854
471
400
.21
.8
TC
1.01
1.00
1.02
1.02
1.00
1.00
1.00
1.00
1.01
0
.8
60
-------
COMPOUND =HEXflCHLOROETHflNE
PfiRfiMETER =COD
THETfi C = 3 '
VOLUME-REflCTOR =.3.1?
DflTE
1982 .
11x05
11X12
11x19
11x26
12x03
"12x10
12X17
MERH
3.DEV
C V '/.
SI
640
640
430
510
420
425
335
494
105.63
21.3
SE
40.0
14.0
3.0
50.9
96.0
31.0
38.0
38.9
29.87
76.3
F
9.53
9.50
9.50
3.50
9.50
9.50
9.50
9.50
0
0
FW
0.95
0.56
1.00
0.81-
1.04
0.58
1.95
0.86
.21
24.7
X.
1026
1150
. 359
933
348
760
391
933
131.88
14.1
XE
- 34
64
1
30
2
41
0
25
24.53
99.8
FSI
XV
1.869
1.668
1.500
1.531
1.434
1.676
1 . 329
1.580
.17
11 -
F TC
XV
1.
1.
1.
1.
1.
1.
1.
1.
,
- 15
753
631
490
381
145
554
201
451
22
.3
2.
3.
3.
2.
2.
3.
3.
2.
m
6
57
00
14
96
99
00
02
95
17
61
-------
COMPOUND =HEXflCHLOROETHRNE
PRRfiMETER =COD
THETfl' C = 6
VOLUME-REflCTOR
3.17
DflTE
1982
11/05
11/12
11/19
11/22
12/03
12/10
12/17
12/24
MEflN
S.DEV
c v /.
SI
640
640
430
510
420
425
395
420
485
101.31
20.8
SE
14.0
28.0
3.0
35.0
83.0
37.0
38.0
12.0
31.3
24.63
78.8
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.58
9.50
0
0
FW
0.45
0.51
0.51
0.23
0.53
0.33
0.53
0.36
0.43
.11
26.2
X
1300
1340
1386
1197
1233
1705 .
1531
1508
1408
171.02
12.2
XE
11
3
3
38
0
38
0
28
15
16782
111.2
FSI
XV
1.475
1.431
0.930
1.277
1.021
0.747
0.773
0.835
1.061
.29
27.7
F TC
XV
1.
1.
0.
1.
0.
0.
0.
0.
0.
.
30
443
369
923
189
819
682
699
811
992
3
.3
6.
5.
5.
6.
5.
5.
5.
5.
6.
02
98
99
05
98
99
98
98
00
.02
.4
62
-------
COMPOUND =HEXRCHLOROETHHNE THETR C » 1
PfiRflMETER =TOC VOLUME-REflCTOR = 3.17
DflTE
1932
11/08
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
' 12/06
12/08
12/10
12/13
12/15
12/17
12/20
'12/22
12/24
12/27
12/29
MEflN
S.DEV
c v /.
SI
131
129
95
115
96
92
94
169
104
131
176
149
134
154
150
142
136
148
139
176
149
150'
134
25.83
19.2
SE
48.0
56.5
30.0
29.0
40.5
34.0
34.0
34.8
48.0
35.0
34.0
22.0
20.0
22.0
45.0
30.0
42.0
28.0
53.0
6.0
37.0
37.0
34.8
11.65
33.5 .
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.58
9.50
9.56
9.50
9.50
9.50
9.50
9.50
0
0
FW
3.10
3.10
3.10
3.13
3.10
3.17
3.11
3.96
3.06
3.17.
3.17 .
3.01
3.00
2.45
2.95
2.96
3.05
1.54
.0.89
3.17
2.97
3.05
2.92
.61
20.9
. X
300
386
260
771
894
1285-
1296
1668
633
1257
971
501
447
322
437
314
561
480
325
490
482
323
627
345.49
55
XE
0
4
3
0
0
0
12
25
11
0
0
12
12
33
15
10
10
98
86
0
15
6
16
26.13
163.3
FSI
XV
1.309
1.002
1.095
0.447
0.322
0.215
0.217
0.474
0.492
0.312
0.543
0.888
0.895
1 . 433
1.029
1.355
0.727
0.924
1.282
1.076
0.926
1.392
0.834
.4
48
F(SI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
8.
0.
0.
0.
0.
0.
1.
8.
1.
0.
0.
0.
1.
0.
1.
0.
m
52
829
563
749
334
186
135
139
379
265
229
438
757
761
229
726
369
502
749
793
040
696
048
619
32
.5
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0-
a
4.
02
00
00
02
02
00
00 .
78
00
08
88
00
00
00
00
00
00
00
00
00
00
00
99
04
9
63
-------
COMPOUND =HEXRCHLOROETHRNE
PRRRNETER =TOC
THETfl C = 3
VOLUME-RERCTOR
3.17
DRTE
1932
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/86
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12^29
MERN
S.DEV
C V '/.
SI
128
129
95
115
96
92
94
169
104
131
176
149
114
154
150
142
136
148
139
176
149
150
133
26.24
19.6
SE
59.0
46.0
23.0
25.0
27.0
22.0
27.0
18.0
30.9
26.0
23.0
23.0
15.0
'22.0
19.0
18.9
15.0
32.0
24.0
44.0
48.0
14.0
27.0
11.93
44.2
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
. 9.
9.
9.
9.
9.
9.
9.
9.
Si
0
0
F
50
50
50
50
50
50
50
50
50
50
50
50.
50
50
50
50
50
50
50
50
50
50
50
I
FW
0.61
0.56
0.58
1.00
.1.00
1.00
0.95
0.81
1.00
1.00
1.04
0.20
0.20
0.58
0.10
0.88
1.05
0.05
'1.05
1.05
0.97
0.93
0.76
.34
45.2
X
1170
1150
1210
1168
859
1092
1102
998
1488
995
848
385
823
760
310
437
891
542
676
810
1084 .
1316
937
284.62
30.3
XE
59
64
66
6
1
0
15
30
6
6
2
98
149
41
130
9
0
466
0
0
11
11
53
102
191.
FSI
XV
0.328
0.336
0.235
0.295
0.335
0.252
0.256
0.507
0.209
0.395
0.622
0.503
0.413
0.607
1.450
0.974
0.457
0.818
0.616
0.651
0.412
0.342
0.501
.07 .28
9 57.5
F(SI-SE)
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
64
177
216
178
231
241
192
182 .
453
149
334
541
425
359
521
266
850
407
641
510
433
279
310
407
26
.3
TC
3.00
3.00
2.97
3.04
3.14
3.17
2.97
2.96
3.06
3.02
2.99
2.53
1.68
3.00
0.78
3.00
3.02
0.39
3.02
3. 02
3.00
3.92
2.72
.75
27.7
64
-------
COMPOUND =HEXflCHLOROETHHNE
PflRflMETER =TOC
THETfl C » 6
VOLUME-RERCTOR
3.17
DflTE
. 1982
11/08
11/10
11/12
11/13
11/17
11/19
11/22
' 11/24
11/26
11/29
12/01
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MEflH
S.DEV
C V :-:
SI
131
128
129
95
115
96
92
94
169
104
tai
176
149
134
154
150
142
136
148
139
176
149
150
134
25.27
13.8
' SE
46.0
46.0
45.0
27.0
28.0
29.0
27.0
26.0
35.0
53.3
35.0
38.0
23.0
45.0
37.0
25.0
30.0
24.8
32.0
. 30.0
9.0
37.0
11.0
32.1
10.78
33.6
F
9.50
9.50
9.30
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.53
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
0
0
FW
0.47
0.52
0.51
0.52
0.45
0.51
0.51
0.53
0.23
0.52
0.36
0.53
0.39
0.27
0.33
3.10
0.40
0.53
0.05-
0.44
0.36
0.53
0.43
0.41
.13
33.5
X
1470
1628
1340
1700
977
1386
1496
1502
1197
2016
1404
1233
1680
1408
1705
1524
1510
1531
1706
1381
1508
1613
1399
1492
210.2
14
XE
8
1
3
0
8
3
2
0
38
2
25
0
24
39
38
86
21
0
113
13
28
0
15
20
28.65
141.1
FSI
XV
0.267
0.236
0.289
0.167
0.353
0.208
0.184
0.188
0.423
0.155
0.280
0.428
0*265
0.286
0.271
0.295
0.282
0.266
0.260
0.302
0.350
0.277
0.321
0.276
.87
25.4
FCSI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.
33
173
151
188
120
267
145
130
136
335
876
205
335
224
189
206
246
222
219
204.
237
332
288
298
211
36
.2
6.
6.
5.
6.
6.
5.
6.
5.
6.
5.
6.
5.
6.
6.
5.
5.
6.
5.
4.
6..
5.
5.
6.
5.
5.
11
03
98
10
05
99
07
98
05
99
06
98
09
01
99
03
02
98 ..
69
03
98
98
01
92.
34
7
65
-------
COMPOUND ^COMBINED THETfl C « 1
PfiRflMETER =BOD . VOLUME-REflCTOR = 3
DflTE
1982
11/1
11/3
11/5
11/8.
11/10
11/12
11/15
11/17
11/19
11/22
"11/24
11/26
11/29
12/01
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
MEflN
S.DEV
C V '/.
SI
191
278
273
253
309
328
382
374
343
334
293
290
294
334
249
268
283
249
362
338
285
271
278
247
256
294
45.66
15.5
SE
1.2
. 3.7
6.3
11.7
9.9
2.0
6.1
2.9
1.1
15.3
3.5
1.5
8.7
3.3
6.5
3.8
0.6.
0.6
0.7
1.0
1.2
1.0
1.3
0.5
12.5
4.3
4.27
99.9
F
8.93
8.93
3.93
8.93
8.93
8.93
8.93
8.93
8.64
8.78
8.93
8.93
8.93
8.93
8.93
8.93
3.93
8.93
.8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.91
.06
.7
FW
2.96
2.79
2.90
2.96
2.89
2.96
2.92
2.95
2.98
3.00
2.91
2.83
2.58
2.85
2.82
3.00
3.00
2.89
2.73
2.79
2.86
2.63
3.00
2.05
3.00
2.85
.2
7
X
780
530
610
810
610
540'
750
670
680
860
940
588
420
660
530
300
600
890
. 370
350
340
340
348
389
300
568
198.32
34.9
XE
5
18
19 .
6
11
4
10
6
2
0
14
16
'28
16
16
0
0
16
16
12
8
20
0
30
0
11
8.51
80.6
0.
1.
1.
0.
1
1
1
1
1
1
0
1
2
1
1
2
1
0
2
2
2
2
2
1
2
1
FSI
XV
729
561
332
930
.508
.808
.516
.662
.453
.137
.928
.488
.034
.506
.398
.659
.404
.833
.912
.875
.495
.373
.434
.890
.540
.738
.64
37.1
F(SI-SE) TC
XV
0.724
1.541
1.301
0.887
1.460
1.797
1.492
1.649
1.448
1.085
0.917
1.481
2.022
1.491
1 . 362
2.621
1.401
0.831
2.907
2.866
2.485
2.364
2.422
1.886
2.416 '
1.714
.64
37.4
1.
1.
1.
1.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
. 1
1
1
1
1
1
3
00
00
00
00
.00 .
.00 .
.00
.00
.00
.00
.00
.00.
.00
.00
.00
.00
.00
.00
.00
.00
.00
.80
.00
.16
.00
.01
03
.2
66
-------
COMPOUND "COMBINED
PRRRMETER =BOD
THETfl C-o 3
VOLUME-RERCTOR = 3.1
DRTE
1332
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/08
12/18
12/13
12/15
12/17
12/27
12/29
MERN
S.DEV
c v /.
SI
191
278
273
253
309
328
382
374
343
334
293
290
294
334
249
268
283
249
362
338
285
. 256
305
299
46.05
15.4
SE
1.6
1.0
2.9
12.0
12.2
0.5
1.5
2.1
0.8
0.7
1.3
1.4
2.0
3.9
2.6
3.5
3.0
.3.6
1.1
1.4
0.8
2.7
6.3
. 2.9 -
3.2
111.8
F
9.50
9.05
9.22
8.78
9.36
9.36
9.07 .
8.93
9.22
9.07
9.50
9.50
9.07.
8.78
5.10
9.36
9.65
9.79
9.07
8.64
8.93
8.93
5.76
8.85
1.12
12.6
FW
.1.03
1.02
1.30
1.03
1.02
1.03
1.01
0.00
1.30
1.03
1.01
0.30
0.97
0.00
0.00
3.00
0.00
0.00
0.95
0.96
0.93
0.20
0.00
0.65
.47
72.4
X
1760
1670
1818
2620
3070
1900
1780
1502
1477
1419
1735
1337
1570
769
651
245
556
1487
1132
1536
1200
866
623
1422
649.87
45.6
XE
0
2
4
8
2
0
4
230
8
0
5
34
12
407
329
105
321
600
10
14
15
82
296
108
169.
156.9
FSI
XV
0.333
0.436
0.447
0.273
0.304
0.521
0.62S
0.717
0.691
0.639
. 0.513
'0.665
0.548
1.334
0.629
3.303
1.584
0.529
0.896
0.613
0.684
0.852
0.914
0.789
18 .62
79.2
FCSI-SE) TC
XV .
0.
0.
0.
e.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
3.
1.
0.
0.
0.
0.
0.
0.
0-.
78
330
484
442
261
292
520
625
713
689
687
515
661
544
319
623
260
568
528
893
611
682
843
895
732
61
.9
3.
3.
3.
3.
3.
3.
3.
2.
2.
3.
3.
3.
3.
0.
1.
0.
0.
0.
3.
3;
3.
3.
1.
2.
01
01
04
01
02
01
02
27
97
01
00
34
00
62
20
77
56
78
04
31
01
02
13
42
.97
40.3
67
-------
COMPOUND ^COMBINED .THETfi C 6
PRRRMETER =BOD VOLUME-REflCTDR = 3.13
DflTE
1932
11/01
11/03
11/05
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/01
12/03
12/06
12/88
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MEfiH
S.DEV
C V V.
SI
191
279
273
253
309
328
332
374
343
334
293
290
294
334
249
268
283
249
362
338
285
271
278
247
256
305
295
44.77
15.1
SE
1.4
7.6
13.5
12.1
13.1
2.8
2.5
1.1
1.9.
0.7
1.0
0.5
2.0
3.0
1.0
1.6
2.1
0.4
3.4
3.9
2.6
1.3
1.6
0.1
1.9
2.7
3.3
3.82
115.2
F
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
- 0
0
FW
0.36
0.46
0.52
0.44
0.48
0.39
0.46
0.52
0.47
0.44
0.36
0.15
0.14
0.10
0.05
0.10
0.10
0.10
0.39
0.10
0.51
0.45
0.05
0.05
0.44
0.46
0.31
.18
58
X
1360
1490
1290
1153
1222
1440
1407
1587
2073
1975
1998
1335
1198
686
993
915
779
787
1081
980
1081
1389
1132
1392
1472
1510
1316
373. 18
28.3
XE
24
10
0
10
5
18
8
. 0
14
18
35
'115
82
56
66
115
204
94
25
60
1
11
375
119
13
11
57
82.02
143.2
FSI
XV
0.421
0.562
0.635
0.658
0.759
0.683
0.814
0.707
0.496
0.507
0.440
0.474
0.736
1.461
0.752
0.879
1.090
0.949
1.005
1.035
0.791
0.585
0.737
0.532
0.522
0.606
0.724
.23
32.9
FCSI-SE)
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
,
33
418
546
603
627
726
678
809
705
494
506
438
473
731
448
749
873
082
948
995 .
623
784
581
733
532
518
601
716
23
.1
TC
6.
6.
6.
6.
6.
6.
6.
6.
5.
6.
6.
4.
4.
3.
4.
2.
1.
2.
5.
4.
6.
6.
1.
3.
6.
6.
4.
1
32
03
02
02
05
06
23
13
02
90
00
04
29
05
65
67 .
47
24
59
23
68
04
01
00
69
03
01
93
.59
.4
68
-------
COMPOUND "COMBINED
PRRRMETER =COD
THETfl C = 1
VOLUME-RERCTOR = 3
DRTE
1982
11/05
11/12
11/19
11/26
12/03
12/10
12/17
12/24
12/31
MEflN
S.DEV
C V '/:
SI
730
540
495
483
420
433
420
475
500
499
95.24
19
SE
60.0
34.0
29.0
36.0
40.0
35.0
57.0
26.0
41.0
39.8
11.63
29.2
8.
8.
8.
8.
8.
8.
8.
8.
3.
8.
1
F
93
93
64
93
93
93
93
93
93
90
09
FW
2.90
2.96
2.98
2.83
2.82
2.89
2.86
2.05
2.48
2.75
.3
10.9
X
610
540
680
580
530
890
340
389
320
542
130.22
33.2
XE
10
4
2
16
16
16
8
30
16
13
8.37
63.8
FSI
XV
3.447
2.881
2.029
2.334
2.283
1.408
3.677
3.635
4.651
2.933
1
34.3
F(SI-SE)
XV
3.164
2.699
1.910
2.205
2.065
1.295
3.178
3.436
4.270
2.691
.91
33.9
T
1
1
1
1
1
1
1
1
1
1
4
C
.03
.03
.03
.03
.03
.03
.00
.16
.07
.05
.04
.4
69
-------
COMPOUND =COMBINED
PRRflMETER =COD
THETfl C = 3
VOLUME-RERCTOR = 3.1
DflTE
1982
11x05
11/12
11/19
11/26
12/03
12/10
12/17
12/29
MERN
S.DEV
c v /.
SI
730
540
495
480
420
435
420
500
503
101.34
20.1
SE
67.0
60.0
29.0
15.0
40.0
40.0
47.0
28.0
40.8
17.16
42.1
F
9.22
9.36
9.22
9.50
5.10
9.79
8.93
5.76
8.36
1.83
. 21.9
FW
1.30
1.03
1.00
0.80
0.00
0.00
0.93
0.00
0.60
.49
83.6
X
1818
1903
1477
1337
651
1487
1200 '
620
1311
476.38
36.3
XE
4
0
8
34
329
600
15
296:
161
223.
139.2
FSI
M
1.194
0.858
0.997
1 . 100
1.061
0.924
1.003
1.498
1.080
79 .19
18.3
F
XV
1.085
0.763
0.938
1.066
0.960
0.839
0.895
1.415
0.-99S
.2
20.1
TC
3.04
3.01
2.97
3.04
1.20
0.78
3.01
1,13
2.27
1.02
45.2
70
-------
COMPOUND "COMBINED
PRRRMETER =COD
THETfl C 6
VOLUME-RERCTOR «* 3.13
DflTE
1982
11/05
11/12
11/19
11/26
12/03
12/10
12/17
. 12/24
12/29
MEflN
S.DEV
C V '/.
SI
730
540
495
480
420
435
420
475
500
450
181.68
40.4
SE
47.
14.
2.
7.
28.
29.
12.
18.
18.
17.
14.
80.
0
0
0
5
0
0
0
0
0
6
15
6
F
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
8.45
2.96
35.1
FW
0.52
0.39
0.52
0.15
0.05
0.10
0.51
0.05
0.46
0.28
.22
80. 9
X
1290
1440
2073
1835
993
787 .
1081
1392
1510
1240
578.84
46.6
XE
0
18
47
115
66
94
1.
119
11
47
48.36
102.6
FSI
XV
1.698
1.125
0.716
0.785
1.269
1.658
1.166
1.024
0.993
1.043
.48
46.7
F
-------
COMPOUND ^COMBINED
PflRflMETER =TOC
THETfl C = 1
VQLUME-REflCTOR
DflTE
1982
11/03
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/24
12/27
12/29
MEflN
S.DEV
C V '/.
SI
157
134
130
122
110
104
105
100
153
169
176
142
149
. 156
111
130
130
120
118
136
177
113
134
23.71
17.7
SE
43.0
41.0
37.0
40.0
32.0
27.0
15.3
21.0
21.0
42.0
24.0
21.5
27.0
23.0
21.0
43.0
23.0
23.0-
22.0
51.0
65.0
42.0
32.0
12.48
38.9
F
8.93
8.93
8.93
8.93
8.93
8.64
8.78
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
8.93
.8.93
8.91
.06
.7
FW
2.96
2.89
2.96
2.92
2.95
2.98
3.00
2.91
2.83
2.58
2.82
3.00
3.00
2.89.
2.73
£.79
2.86
2.63
. 3.00
2.05
3.00
2.48
2.83
.22
3
X
810
610
540
750
670
680
860
940
580
420
530
300
600
890
370
350
340
340
340
389
300
320
542
210.92
38.9
XE
6
11
4
10
6
2
0
14
16
23
16
0
0
16
16
12
8
20
0
30
0
16
11
8.87
84.5
FSI
XV
0.577
0.654
0.717
0.484
0.489
0.440
0.357
8.317
0.811
1.198
0.988
1.409
0.739
0.522
0.893
1.106
1.138
1.051
1.033
1.041
1.756
1.051
0.853
.36
42.6
F(SI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
41
419
454
513
325
347
326
305
250
703
900
854
196
605
445
724
740
937
849
340
650
111
660
643
26
.8
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00 .
.00
.00
,00
.16
.00
.07
.01
.03
.6
72
-------
COMPOUND ^COMBINED
PflRRMETER =TOC
THETR C = 3
VOLUME-RERCTOR « 3.1
DRTE
1932
11/08
11/10
11/12
11/15
11/17
11/22
11/24
11/26
12/63
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/27
12/23
MERN
S.DEV
C V '/.
SI
157
134
130
122
110
105
100
158
176
142
149
156
111
130
130
120
177
133
136
22.93
16.9
SE
37.0
33.0
33.0
33.0
26.0
21.0
19.5
34.0
17.0
17.0
31.0
20.0
15.0
25.0
18.8
19.0
22.0
31.0
25.4
7.61
30
F
3.73
9.36
9.36
9.07
8.93
9.07
9.50
9.50
5.10
9.36
9.65
9.79
9.07
8.64
8.93
9.79
8.93
5.76
8.81
. 1.27
14.5
FW
1.03
1.02
1.03
1.01
0.00
1.03
1.01
0.80
0.00
0.00
0.00
0.00
0.95
0.96
0.93
0.60
0.20
0.00
0.59
.47
80.3
X
2620
3070
1900
1780
410
1419
1735
1337
651
245
556
1487
1182
1536
1200
1032
8S6 .
620
1314
742.97
56.5
XE
0
2
0
4
230
0-
5
34
329
105
321
600
10
14
15
49
82
296
116
169.7
143.7
FSI
XV
0.170
0.132
0.207
0.201
0.773
8.216
0.177
0.362
0.445
1.750
0.834
0.331
0.275
0.236
0.312
0.367
0.5.39
0.399
0.432
.38
89
F(SI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
94
130
094
154
146
590
173
142
284
402
540
661
289
238
191
269
309
516
306
357
33
.1
3.
3.
3.
3.
0.
3.
3.
3.
1.
0.
0.
0.
3.
3.
3.
. 2.
3.
1.
2.
1.
01
02
01
02
62
01
00
04
20
77 .
56
78
04
01
01
99
02
13
29
06
46.3
73
-------
COMPOUND "COMBINED
PflRRMETER =TOC
THETfl C » 6
VOLliriE-REflCTOR * 3.13
DflTE
1982
11/08
11/10
11/12
11/15
11/17
11/19
11/22
11/24
11/26
11/29
12/03
12/06
12/08
12/10
12/13
12/15
12/17
12/20
12/22
12/27
. MEfl'N
S.DEV
C V '/.
SI
157
134
130
122
110
104
105
100
158
169
176
142
149
156
111
130
130
120
118
177
133
24.43
18.1
SE
45.0
36.0
59.0
33,8
33.0
28.0
26.0
22.0
17.0
. 39.0
22.0
13.0
22.0
34.5
29.0
32.0
33.0
19.0
31.0
26.0
' 38.2
9.99
33
F
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
9.39
0
0
FU
0.44
0.48
0.39
0.46
0.52
0.47
0.44
0.36
0.15
0.14
0.05
0.10
0.10
0.10
0.39
0.10
0.51
0.45
0.05
0.44
0.31
.17
58.4
X
1153
1222
1440
1407
1587
2073
1975
1998
1835
1198
993
915
779
7.87
1081
930
1081
1389
1132.
1472
1325
397.81
30
XE
10
5
18
8
0
14
18
35
115
32
66
115
204
94
25
60
1
11
375
13
63
90.28
142.2
FSI
XV
0.409
0.329
0.271
0.260
0.208
0.151
0.159
0.150
0.258
0.423
0.532
0.466
.0.574
0.595
0.308
0.398
0.361
0.259
0.313
0.361
0.339
.13
39.2
FCSI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
@.
0.
0.
0.
0.
0.
0.
0.
0.
0.
44
291
241
148
190
146
110
120
117
231
326
465
407
489
463
228
300
269
218
231
308
265
11
.5
6.
6.
6.
6.
6.
5.
6.
6.
4.
4.
4.
2.
1.
2.
5.
4.
6.
6.
1.
6.
4.
1.
05
06
23
13
02
90
00
04
29
05
67
47
24
59
23
63
04
01
00
03
84
71
35.3
-------
COMPOUND = 1-2 DICHLOROELTYLENE THETfl C = 1
PflRRMETER =BOD VOLUME-RERCTOR =3.17
DRTE
1383
01/17
81/13
01/21
01/24
01/26
01/28
01/31
02/02
02/94
02/07
02/09
02/11
' 02/14
02/16
02/14
' 02/16
02/18
.02/21
02/23
92/25
02/28
03/02
03/04
'MERN
S.DEV
C V '/.
SI
383
275
201
239
272
214
246
265
285 .
265
306
303
281
316
281
316
277
161
323
234
' 255
146
- 238
255
71.29
27.9
SE
1.4
1.7
1.0
1.5
0.3
0.2
0.0
7.5
2.4
4.3
18.3
3.3
4.0
4.7
4.0
4.7
8.2
4.4
6.0
"8.5
5.3
10.6
9.4
4.4"
3.31
75.4
F
9.50
3.50
9.50
11.35
9.50
9.5Q
10,94
3.50
3.36
.9.50
3.50
3.50 .
3.50
3.58
3.50
9.59
3.50
9.58
3.38
9.50
3.40
9.52
9.40
9.25
2.05
22.1
FW
3.08
3.18
3.17
3.17
3.17
3.08
3.06
3.06
3.17
3.17
3.17
3.17
2.88
2.94
2.80
2.94.
2.80
2.17
2.1.1
1.24
0.57
1.7S
2.50
2.56
.88
34.4
X
610
514
642
490
454
560
452
488
502
410
. 433.
740
620
430
629
430
319
373
538
334
445
324
392
470
145.85
31 '
XE
8
6
0
0
0
8
' 4
8
0
8
6
8
24
12
24
12
42
48
68 -
68
122
68
28
22
38.06
135.6
FSI
XV
1.518
1.603
0.338
2.223
1.795
1.145
1.878
1.627
1.676
1.937
1 . 868
1.227
1.358
1.333
1.358
1 .933
2.678
1.273
1 .803
2.638
1 . 693
1.353
1.888
1.636
.54
33.3
F(SI-SE) TC
XV
1.
1.
0.
2.
1.
1.
1.
1.
1.
1.
1.
1.
. 1.
1.
1.
1.
2.
. 1.
1.
2.
1.
1.
1.
1.
33
511
593
334
212
730
144
878
581
662
382
738
211
339
304
333
304
599
238
770
562
664
255
729
605
53
.2
1.
6.
1.
1.
1.
1.
1.
1.
1.
1.
8.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
8.
00
97
00
00
88
00
81
04 .
08
00
38
98
04
02
84
02 .
05
08
08
88
06
99
86
98
.21
21
.5
75
-------
COMPOUND = 1-2 DICHLOROELTYLEME
PflRflMETER =BOD
THETfl C = 3
VOLUME-REfiCTOR =3.17
DflTE
1933
01/17
01/19
01/21
01/26
01/26
01/28
91/31
02/02
02/04
02/07
02/09
02/11
02/12
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
. 03/09
MERN
S.DEV
C V %
SI
309
275
201
289
272
214
246
265
285
265
306
303
281
316
277
161
323
294
255
. 146
238
256
263
252
69.87
27.7
SE
14.1
1.1
0.6
3.1
3.7
0.6
0.3
0.5
2.5
3.7
2.5
1.3
2.9
1.8
3. 2
2^3
2.9
1.7
2.3
2.1
2.8
2.1
1.2
2.5
2.69
109.2
F
9.50
9.50
9.50
9.50
9.50
9.50
9.36
9.50
9.22
8.93
9.50
9.40
9.50
9.36
9.40
9.50
9.50
9.50
9.48
91 50
9.46
9.52
9.48
9.05
1.93
21.3
FW
1.03
1.05
0.99
1.02
1.02
1.00
1.06
9.92
0.99
0.60
1.06
0.91
0.30
1.06
1.00
0.90
1.05
1.06
0.98
0.98
1.04
1.02
1.06
0.92
.25
28; 2
X
1202
1109
1186
998
1046
1118
1092
986
1102
944
903
890
900
1200
930
1190
1042
1382
978 .
996
976
980
974
1005
245.59
24.4
XE
4
0
10
4
0
4
0
14
8
43
0
14
72
0
6
20
0
0
6
8'
0
. 4
0
9
16.92
183
FSI
XV
0.770
0.743
0.508
0.868
0.779
0.574
0.665
0.805
0.752
0.791
1.016
1.010
0.936
0.778
0.883
0.405
0.929
0.638
0.780
0.439
0.728
0.784
0.808
0.725
.22
30.4
F(SI-SE) TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
m
30
735
740
506
859
769
572
664
804
746
780
007
005
926
773
873
400
921
634
773
433
719
778
804
718
21
.4
3.
3.
3.
3.
3.
3.
2.
3.
3.
3.
2.
3.
3.
3.
3.
3.
3.
2.
3.
3.
3.
3.
2.
2.
00
02
00
01
11
08
99
04
02
10
99
04
06
00
01
03
02
99
07
02
05
01.
99
90
.61
21
.3
76
-------
COMPOUND = 1-2 DICHLOROELTYLENE
PRRRMETER =BOD
THETR C = 10
VOLUME-RERCTOR =3.17
DRTE
1983
01/17
01/13
01/21
01/24
01/26
81/28
01/3.1
02/02
02/04
02/07
02/05
02/11
02/14
' 02/16
02/18
82/21
02/23
02/25
02/28
. 03/02
03/04
03/07
03/09
MERH
S.'DEV
C V ':
SI
. 309
275
201
289
272
214 .
246
265
235
265
306
303
281
316
277
161
323
294
255
146
238
256
263
252
69.87
27.7
SE
14.7
1.4
2.6
5.1
2.3
1.3
4.0
0.9
3.4
4.0
3.0
1.7
1.9
1.8
4.2
1.4
2.2
1 . 6
9.1
2.6
2.7
0.0
1.4
3.1
3.11
101.9
F -
9.50
9.50
9.50
9.50
9.50
9.50
9.50
3.50
9.36
9.36
9.36
9.50
9.50
9.40
9.38
9.50
9.45
9.50
9.46
9.48
9.50
9.48
9.46
9.07
1.33
21.3
FW
0.05
0.00
0.05
0.00
0.00
0.00
0.16
0.24
0.04
0.00
0.22
0.05
0.00
0.00
0.00
0.18
0.05
0.00
0.00
0.14
0.25
0.14
0.10
0.07
.08
123.
X
1678
1512
1712
1578
1038
940
1098
119.6
1278
668
730
1330
1060
1130
1178
1422
1592
1556
1530
1688
1708
1680
1486
1287
410.89
9 31.3
XE
293
206
158
138
260
129
18
10
38
288
8
65 .
493
64
90
20
62
198
130
32
12
32
34
116
122.
105.
FSI
XV
0 . 552
0.545
. 0.352
0.549
0.785
0.682
0.671
0.664
0.658
1.186
1.144
0.683
0.794
0.829
0.696
0.339
0.605
0.566
0.482
0.259
0.418
0.456
0.528
0.602
44 .25
5 42.2
F
XV
0.526
0.542
0.347
0.539
0.779
0.678
0.661
0.662
0.651
1.168
1.132
0.679
0.789 .
0.825
0.635
0.336
0.601
0.563
0.464
0.254
0.413
0.456
0.525
0.595
.25
42.3
TC
1.83
2.45
3.44
3.82
1.33
2.43
V.10. 12
"/il0.15
:10.00
0.78
5J10.14
6.19
0.72
5.95
4.42
JJ10.13
7.62
2.62
4.07
*10.16
:'.10.06
*10. 13
X10.09
5.78
3.83
66.3
77
-------
COMPOUND =1-2 DICHLOROELTYLENE
PRRRMETER =>COD
THETfl C = 1
VOLUME-REflCTOR
3.17
DflTE
1333 .
01^17
01/26
02/04
02/11
02/13
02/25
03/04
03/09
MEflH
S.DEV
C V *
si
420
370
390
430
410
104
350
363 '
316
153.98
43.7
SE
23.
10.
18.
12.
50.
39.
27;
20.
22.
15.
68.
0
0
0
0
0
0
0
0
1
19
7
F
9.50
9.50
9.36
9.50
9.50
9.50
9.40
9.42
8.41
3.15
37.5
FW
3.08
3.17
3.17
3.17
2.00
1.24
2.50
0.69
2.11
1.2
57,2
y.
610
490
502
740
310
334
392
293
408
212.27
51.9
XE
3
0
0
8
42
68
23
78
26
30.42
118
FSI
XV
2.063
2.263
2.294
1.741
3.964
0.933
2.643
3.670
2.175
1.23
56.6
FCSI-SE
XV
1.950
2.202
2. 183
1 . 693
3.480
0.583
2.443
3.470
2.001
1.15
57.8
) TC
1.
1.
1.
0.
1.
1.
1.
1'.
0.
u
37
00
00
00
93
05
08
06
07
92
34
.7-
78
-------
COMPOUND =1-2 DICHLOROELTYLENE
PRRRMETER =COD
THETfl C = 3
VOLUME-RERCTOR = 3.17
DRTE
1933
01/17
01/26
02/04
02/11
02/18
02/25
03/04
03/09
MEflN
S.DEV
C V *
SI
. 420
370
390
430
410
390
350
368
343
132.38
33.2
. SE'
33.0
10.0
10.0
37.0
31.0
28.0
9.0
18.0
19.6
13.06
66.8
F.
3.50
9.50
9.22
9.40
9.50
9.50
9.46
9.48 .
8.40
3.14
37.5
FW
1 . 03
1.02
0.99
0.91
1.00
1.06
1.04
1.06
0.90
.34
37.8
X
1202
1046
1102
890
930
1382.
976
974
945
385.67
40.8
XE
4
0
8
14
6
0
0 '
0
4
4.97
139.9
FSI
XV
1.047
1.060
1.029
1.433
1.321
0.S46
1 . 070
1.130
0.993
.4
41.2
FCSI-SE
XV
0.
1.
1.
1.
1.
0.
1.
1.
0.
.
40
965 .
031
003
309
221
785
043
075
937
33
.7
> JC
3.
3.
3.
. 3.
3.
2.
' 3.
2.
2.
. 1
37
00
11
02
05
01
99
05'
99
69
.5
79
-------
COMPOUND = 1-2 DICHLOROELTYLENE
PflRRMETER =COD
THETfl C' * 19
VOLUME-REflCTOR
3.17
DflTE
1983
01/17
01/26
02/04
02/11
02/18
02/25
03/04
03/09
MEflH
S.DEV
C V '/.
SI
420
370
390
430
410
390
350
368
' 348
132.88
33.2
SE
43.
11.
19.
27.
46.
26.
22.
26;
24.
14.
58.
0
0
0
0
0
0
0
0
4
29
4
F
9.50
9.50
9.36
9.50
9.50
9.50
9.50 .
9.46
8.42
3.15
37.5
FU
'/.S0.00
0.00
0.04
0.05
0.00
0.00
0.25
0.10
5.60
16.64
297
X
1678
1038
1278
1330
1178
1556.
1708
1486
1250
519.
41.5
XE
298
260
38
65
90
198
12
34
111
86 112.
101.4
FSI F
XV XV
0.750
1.068 1.
0.901 0.
0.969 0.
1 . 043 0.
0.751 0.
0.614 0.
0.739 0.
0.760 0.
1.7 . 32
42.6 42
0.673
036
857
90S
926
701 .
576
687
707
.3
.9
TC
1.
J£l
6.
4.
2.
*1
ms.l
4.
4.
86
0.07
33
0.00
19
37
62
0.06
0.09
97
28 .
.1
80
-------
COMPOUND = 1-2 DICHLOROELTYLEHE
PflRflMETER =TOC
THETfl C = 1 .
VQLUPE-REflCTOR = 3.17
DftTE
1983
01/17
0 1 / 1 9
01/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
'03/02
03/04
03/07
03/09
MEflH
S.DEV
C V :-;
51
118
104
104
127
124
129
104
116
110
129
118
114
122.
126
149
115
136
104
140
112
100
112
119
12.85
10.8
5E
20.0
10.0
19.0
34.0
20.0
26.0
20.0 .
43.0
27.0
40.0
34.0
27.0
30.0
30.0
37.0
39.0
25.0
27.0
27.0
23.0.
22.0
23.0
27.4
7.99
29.1
F
9.50
9.50
' 9.50
11.95
9.50
9.50
18.94
9.50
9. 36
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9. 38
9.50
9.52
9.40
9.42
9.50
9.66
.6
6.2
FW
3.08
3.18
3.17
3.17
3.17
3.08
3; 06
3.06
3.17
3.17
3. 17
3.17
2.86
2.94
2.00
2.17
2.11
1.24
1.78
2.50
0.00
0.69
2.54
.9
35.7
X
610
514
642 .
490
454
560
452
4S8
502
410
493
740
620
490
310
379
538
334
. 324
392
192
298
.465
129.3
27.8
XE
8
6
0
0
0
8
4
0
' 0
0
6
8
24
12
42
40
69
68
60
28
142
78
27
35.97
133.2
FSI
XV
0.580
0. 606
0.485
0,977
0.819
0.690
0.794
0.712
0.647-
0.943
0.717
0.462
.0.590
0.771
1 . 440
'0.909
0.759
0.933
1 . 298
0.847
1 . 548
1.126
0.848
.28
34
F TC
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
1.
1.
1.
1.
' 1.
1.
n.
. 1.
0.
1.
1.
00
97 '
00
00
00
00
01
04
00
00
98
98
04
02
05
08
08
08
99 . .
06
46
06
00
.12
12
.6
81
-------
COMPOUND =1-2 DICHLOROELTYLENE
PflRflMETER =TOC
THETfl C * 3
VOLUME-REflCTOR <= 3.17
DflTE
1983
01/17
01/19
01/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
32/11
02/14
02/16
02/18
32/21
02/23
02/25
03/02
03/04
03/07
03/09
MEAN
S.DEV
C V *
SI
118
104
104
127
124
129
104
116
110
129
113
114
122
126
149
115
136
104
140
112
100
112
119
12.85
10.3
3E
47.0
24.0
15.3
27.0
16.5
13.0
25.0
35.0
47.0
33.0
18.0
23.0
23.0
.30.0
37.0
33,8
26.0
23.0
21.0
27.0
19.0
27.0
27.3
8.62
3.1.5
F
9.53
9.50
9.53
9.50
9.50
9.50
9.36
9.50
9.22
3.93
9.50
9.43
9.50
9.36
9.40
9.53
9.50
9.50
9.50
9.46
9.52
9.48
9.44
.13
1.4
FW
1.03
1.05
0.98
1.02
1.02
1.00
1.06
0.92
0.99
0.60
1.06
0.91
0.30
1.06
1-.00
0.90
1.05
1.06
0.98
1.04
1.02
1.06
0.96
.17
18.5
X
1202
1109
1136
998
1046
1118
1092
936
1102
944
903
890
900
1203
930
1193
1042
1382
996
976
980
974
1052
124.91
11.3
XE
4
0
10
4
0
4
0
14
8
43
0
14
72
3
6
23
0
0
8
0
4
0
10
17.57
179
FSI
XV
0.294
3.281
3.263
3.331
3.355
3.346
3.231
0.353
0.290
0.385
0.392
0.330
0.406
0.310
0.475
3.290
0.391
0.226
0.421
0i.342
3.306
0.344
0.341
.35
17.5
F TC
XV
3.
3.
3.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
3.
0.
0.
3.
0.
0.
0.
0.
.
22
177
216
225
333
308
298
214
246
166
236
332
333
313
236
357
214
316
165
353
260
243
261
264
35
3
3
3
.00
.32
.31
3.31
3
3
2
3
3
3
2
3
3
3
3
3
3
2
3
3
. 3
2
3
.
i.
.11
.03
.99
.04
.02
.10
.99
.35
.36
.03.
.31
.03
.02
.99
.02
.05
.01
.99
.03.
03
1
82
-------
COMPOUND "1-2 DICHLOROELTYLENE
PflRflMETER =TOC
THETfl C « 10
VOLUME-RERCTOR =3.17
DflTE
1933
01/17
01/19
01/21
01/24
01/26
01/28
01/31
02/02
82/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
03/02
03/04
03/07
03/09
MEflM
S.DEV
C V '/.
SI
118
104
104
127
124
. 129
104
116
110
129
113
114
122
126
149
115
136
104
140
112
100
112
119
12.85
10.3.
SE -
55.0
12.0
15.0
29.0
16.0
23.0
29.0
34.0
37.0
38.0
20.0
20.0
21.0
30.0
41.0
29.0
22.0
34.0
23.0
24.0
17.0
24.0
27.0
10.04
37.2
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.36
9.36
9.36
9.50
9.50
9.40
9.38
9.50
9.45
9.50
9.48
9.50
9.48
9.46
9.47
.05
.5
FW
0.05
0.00
0.05
0.00
0.00
0.00
0.16
0.24
0.04
0.00
0.22
0.05
0.00
0.00
0.00
0.18
0.05
0.00.
0.14
0.25
0.14
0.10.
0.03
.08
115.
X
1678
1512
1712
1578
1038
940
1098
1196
1278
660
790
1330 .
1060
1130
1178
1422
1592
1556
1688
1708
1630
1486 .
1332
315.92
1 23.7
XE
298
206
158
138
260
129
18
10
38
288
8
65
493
64 .
90
20
62
198
32
12
32
34
121
125.
104
FSI
XV
0.211
0.206
0.182
0.241
0.358
0.411
0.284
0.291
0.254
0.577
0.441
0.257
0.345
0.331
0.374
0.242
0.255
0.200
0.248
0.197
0. 178
0.225
0.287
49 .09
34.4
FCSI-SE
XV
0.113
0.182
0.156
0.186
0.312
0.338
0.205
0.205
0.169
0.407
0.366 .
0.212
0.286
0.252
0.271
0.181
0.213
0.135
0.207
0.154
0.148
0.177
0.222
.07
35.2
) TC
1.83
2.45
3.44
3.82
1.33
2.43
X10.12
X10.15
X10.00 .
0.78
'/.10.14
6.19
0.72
5.95
4.42
K10.19
7.62
2.62
X10.16
*10.06
?il0. 13
Jil0.09
6.12
3.77
61.7
83
-------
COMPOUND =4 NITROPHEHOL THETR C = 1
PflRflMETER =BOD VOLUME-REflCTOR =3.13
DfiTE
1383
01X17
01/19
01/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
02/11
02/14
62/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MEflN
S.DEV
C V '/.
SI '
444
319
257
339
318
. 258
261
301
310
287
356
319
337
348
291
277
342
290
306
306
270
358
350
302
76.54
25.3
SE
12.0
19.1
2.3
3.2
3.3
2.0
1.0
1.4
4.2
5.8
10.9
6.9
9.1
9.2
3.3
1.6
5.5
7.1
12.8
9.2
6.4
4.0
6.9
6.3
4.5
71
F
9.65
9.79
9.65
9.65
9.50
9.07
9.07
9.36
S.93
9.22
9.22
9.22
8.93
9.07
9.65
9.65
9.22
9.65
9.65
9.50
9.65
9.65
9.36
9.01
1.93
21.5
FW
2.37
2.55
2.92
2.29
3.13
2.92
3.06
3.05
2.89
2.92
3.13
2.74
2.94
3.01
3.07
3.13
2.97
1.64
0.00
0.00
2.50
2.88
0.26
2.35
1.09
46.7
V.
460
350
380
440
340
540
560
470
500
490
290
430
.680
610
700
470
420
450
320
310
590
550
520
453
146.
32.3
KE
48
28
12
50
. 0
18
6
6
20
16
0
26
22
. 12
6
0
10
84
204
104
52
20
164
38
47 52
138.
F
2.
2.
2.
2.
2.
1.
1.
1.
1.
1.
3.
2.
1.
1.
1.
1.
2.
1.
2.
2.
1.
2.
2.
2.
.48
7 37
SI
XV
976
851
085
375
839
384
351
915
769
725
616
185
414
653
282
817
399
987
948
996
411
007
013
042
.76
.4
F TC
1.
1.
1.
1.
1.
1.
1.
1.
. 1.
1.
1.
1.
1.
1.
1..
1.
1.
1.
0.
0.
1.
1.
1.
0.
.2
23
00
00
00
00
00
00
00
00
00
00
00
00
00
00
'00
00
00
00
51
98
00 - .
00
00
94
2
.8 .
84
-------
COMPOUND =4 NITROPHEHQL
.PflRflMETER =BOD
THETfl C = 3
VOLUME-REflCTOR =3.14
DRTE
1983
01/17
91/19
01/21
01/24
01/26
01/28
01/31
02/02
02/84
02/07
02/03
02/11
02/14
02/16
02/13
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
HERN
S.DEV
C V '/.
SI
444
319
257
339
318
258
261
301
310
287
356
319
337
348
291
277
342
290
306
306
270
358
350
. 302
76.54
25.3
SE
13.0
6.3
1.0
2.0
3.7
2.2
1.6
2.7
3.4
4.1
1.8
1.7
2.9
2.0
4.0
2.2
1.9
1.5
3.9
. 7.3
8.6
6.8
4.2
3.7
2.9
78.3
F
9.07
9.50
9.65
9.36
8.64
9.65
9.36
9.22
9.79
9.22
9.22
9.22
9.36
9.22
9.07
9.79
9.22
9.22
9.79
9.65
9.22
. 9.22
9.07
8.95
1.92
21.5
FW
0.65
0.75
1.04
0.95
1.04
0.94
0.78
0.00
0.36
0.93
1 . 04
1.03
0.97
1.02
1.02
1.05
0.26
0.00
0.00
0.00
0.31
0.34
0.00
0.60
.43
72
X
360
880
1060
1230
830 .
1430
. 910
1020
1840
1420
1360
1390
1400
1350
1480
1200
680
670
650
348
530
1050
790
'982
381.9
38.8
XE
40
30
0
14
0
18
28
140
76
20
0
2
12
4
4
0
60
172
224
368
.44
84
196
64
92.7
.144.8,
FSI
XV
1.491
1.097
0.745
0.822
1.054
0.554
0.855
0.866
0.929
0.593
0.769
0.674
0.718
'0.757
0.568
0.720
1 .477
1.271
1.468
2.766
1.496
1.001
1.280
0.999
.52
52.3
F(SI-SE) TC
XV
1.
1.
0.
0.
1.
0.
0.
0.
0;
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
2.
1.
0.
1.
0.
m
51
448
075
742
817
042
550
850
859
919
5S5
765
670
711
753
560
714
469
264
449
700
448
982
264
985
5
.6
3.
3.
3.
3.
3.
' 2.
3.
2.
2.
3.
3.
3.
3.
3.
3.
2.
2.
1.
0.
0.
2.
2.
1.
2.
.94
37
01
00
02
00
02
99
01
48
99
00
02
01
01
01
01
99
99
33
93
30
99
99
40
52 .
.6
85
-------
COMPOUND =4 NITROPHENOL
PflRflMETER =BOD
THETfl C B 10
VOLUME-REflCTOR = 3.1
DRTE
1383
01/17
01/19
81/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/18
82/21
. 02/23
02/25
02/28
03/02
03/04
03/07
03/09
MEflN
S.DEV
c v /.
SI
444
313
257
339
318
258
261
301
310
287
356
319
337
348
231
277
342
290
306
306
270
358
350
302
76.54
25.3
SE
5.5
. 3.5
1.6
2.0
1.8
1.5
1.4
2.7
2.2
2.5
3.8
2.2
3.3
2.2
2.8
1.8
2.2
2.4
1.3
3.6
4.3
5.4
1.8
2.6
1.26
48.8
F
3.93
9.07
3.79
9.65
9.22
9.65
9.36
9.50
9.22
8.93
9.80
9.36
9.07
9.36
9.07
9.07
8.93
9.22
9.36
9.07
8.93
9.65
9.50
8.90
1.91
21.5
FW
0.19
0.28
0.27
0.26
0.31
0.24
0.29
0.00
0.00
0.00
0.00
0.90
0.15
0.00
0.00
0.00
0.25
0.24
a. 00
0.00
0.31
0/00
0.12
0.12
.13
107.!
X
2240
2280
2150
2410
2150
2310
2380
2760
2150
1130
420
720
1100
1100
1170
1050
1160
1240
1300
.920
1120
1490
1370
1526
748.84
3 49
XE
30
3
10
12-
0
18
6
270
320
376
104
74
20
76
120
146
8
10
52
440
0
108 .
28
93
128.03
137.4
FSI
XV
0.571
0.409
0.377
0.438
0.440
0.348
0.274
0.334
0.429
0.732
2.680
1.338
0.896
0.955
0.728
0.772
0.849
0.696
0.711
0.973
0.694
0.748
0.783
0.716
.5
70.6
F(SI-SE)
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
1.
0.
0.
0.
0.
0.
0.
0.
0;
0.
0.
0.
0.
m
70
564
405
375
435
437
346
272
331
426
725
651
329
888
549
721
767
844
630
707
962
683
737
779
703
5
.5
TC
>:ie.
9.37
9.86
*10.
X10.
9.89
/.10.
3.34
2.26
1.64
1.2S
3.22
9.93
4.79
3.33
2.46
5410.
9.92
8.23
0.71
V.10.
.4.43
3.95
6.45
3.92
60.7
10
11
30
04.
00
00
86
-------
COMPOUND =4 NITROPHEHOL THETfl C = 1
PflRflMETER =COD VOLUME-REflCTOR =3.13
DflTE
1983
SI
SE
F
FW
X
XE
FSI
XV
F
XV
TC
01/17 *1060 JJ113..0 9.65 2.37 -4.60 48 7.104 6.347 1.00
01/26 460 16.0 9.50 3.13 340 0 4.106 3.964 1.00
02/04 408 20.0 8.93 2.89 500 20 2.328 2.214 . 1.00
02/11 465 53.0 9.22 2.74 430 26 3.185 2.822 1.00
02/13 580 81.0 9.65 3.07 700 6 2.555 2.198 1.00
02/25 398 47.0 9.65 1.64 450 84 2.727 2.405 1.80
03/04 510 28.0 9,65 2.50 590 52 2.665 2.519 1.00
03/09 460 38.0 9.36 0.26 520 164 2.645 2.427 1.90
MEflH 482 44.0 8.40 2.07 .443 44 3.035 2.766 0.89
S.DEV 271.7 35.91 3.16 1.13 195 52.78 1.87 1.68 .33
C V '/. 56.3 79.5 37.6 57.4 43.9 118.7 61.7 61 37.5
87
-------
COMPOUND =4 NITROPHENOL THETR C = 3
PfiRflMETER =COD VOLUME-REflCTOR =3.14
DflTE
1383
si
SE
F
FW
X
XE
FSI
XV
F
XV
TC
01/17 *1060 50.0 9.07 0.65 960 40 3.560 3.392 3.01
01/26 460 18.0 8.64 1.04 830 0 1.525 1.465 . 3.02
02/04 408 17.0 9.79 0.36 1040 76 1.223 1.172 2.99
02/11 465 43.0 9.22 1.03 1330 2 0.332 0.831 3.01
02/18 .580 51.0 9.07 1.02 1480 4 1.132 1.032 3.01
02/25 398 32.0 3.22. 0.00 670 172 1.744 1.604 1.33
03/04 510 27.0 9.22 0.31 530 44 2.826 2.676 2.99
03/09 469 30.0 9.87 0.00 790 196 1.682 1.572. 1.40
MEflH 482 29.8 8.14 0.49 843 59 1.630 1.534 2.31
S.DEV 271.7 16.71 3.06 .45 445.19 75.53 1.04 .99 1.12
C V '/. 56.3 56.1 37.6 93.2 52.7 127.3 63.8 64.8 43.5
88
-------
COMPOUND =4 NITROPHEHOL . . THETR C = 10
PfiRfiriETER =COD VOLUME-REFICTClR = 3.1
DflTE
1983
SI
SE
F
FW
X
XE
FSI
XV
F
XV
TC
01/17 *1060 39.0 8.93 0.19 2248 30 1.363 1.313 X10. 10
01/26 460 16.0 9.22 0.31 2150 0 0.636 0.614 V.10.00
02/04 408 11.0 9.22 0.00 2150 320 0.564 0.549 2.26
02/11 465 50.0 9.36 0.00 720 74 . 1.950 1.740 3.22
02/18 580 52.0 9.07 0.00 1170 120 1.450 1.320 3.33
02/25 398 26.0 9.22 0.24 1240 10 0.955 0.892 9.92
93/04 510 5.0 8.93 0.31 1120 0 1.312 1.299 *10.00
93/09 460 18.6 9.50 0.12 1379 28 1.029 0.989 9.95
MERH 482 24.1 8.16 0.13 1351 65 1.029 0.969 6.53
S.DEV 271.7 19.02 3.06 .13 740.71 103.93 .57 .52 4.21
C V * 56.3 78.8 37.5 104.6 54.8 160.7 55.9 54 64.5
89
-------
COMPOUND =4 NITROPHENOL
PflRRMETER =TOC
THETfl C = 1
VOLUME-REflCTCR = 3.13
. DflTE
1983
01/17
01/13
01/21
01/24
01/26
01/28
01/31
02/02
02/84
82/87
02/03
02/11
02/14
02/16
02/13
02/21
02/23
02/25
02/23
03/02
03/04
03/07
03/09
MEflN
S.DEV
C V '/.
SI
218
126
128
144
157
143
35
120
157
125
133
146
. 145
135
143
133
151
142
137
166
. 142
124
106
134
36.63 .
27. -2
SE
67.0
42.0
24.0
39.0
17.0
21.0
25.0
56.0
34.0
32.0
30.5 .
21.5
32.0
25.0
26.0
£3.0
27.0
30.0
28.0
21.0
22.0
11.0
23.0
28.5
13.4
47
F
3.65
9.73
3.65
9.65
9.50
9.07
9.07
9.36
8.33
9.22
9.22
9.22
8.93
9.07
9.65
9.65
9.22
9.65
9.65
3.50
3.65
9.65
9.36
9.01
1.93
21.5
FW
2.37
2.55
2.92
2.92
3.13
2,92
3.06
3.05
2.83
2.92
3.13
2.74
2.34
3.01
3.07
3.13
2.97
1.64
0.03
0.00
2.50
2.88
0.26
.2.37
1.1
46.4
X
460
350
380
440
340
540
560
473
500
490 .
299
430
680
610
700
470
420
450
' 320
310
590
550
520
453
146.47
32.3
XE
48
28
12
50
0
18
6
6
20
16
0
26
22
12
6
0
10
84
204
104
52
20
164
38
52.48
138.7
FSI
XV
1.461
1.126
1 . 039
1.003
1.402
0.767
0.492
0.764
0.836
0.751
.1.412
1.000
0.608
0.641
0.630
8.305
1.053
0.373
i . 320
1.625
0.742
0.695
0.610
0.914
.36
39.9
F(SI-SE) TC
XV
1.012
0.751
0.844
0.736
1.250
0.655
0.362.
0.407
0.702
0.559
1.102
0.853
0.474
0.523
0.515
0.715
0.870
0.767
1 . 050
1.420
0.627
0.633
0.477
0.721
.3
42.5
1.00
1.00
1.00
0.85
1.00
1.00
1 . 00
1.00
1 . 00
1.00
1.00
1.00
- 1 . 00
1 . 00
1.00
1 . 00
1.00
1.00
0.51
0.98
1.00
' 1.00
1.00
0.93
.22
24
90
-------
COMPOUND =4 NITROPHENOL
FRRRMETER =TOC
THETfl C = 3
VOLUME-REfiCTOR =3.14
DOTE
1983
01/17
01/13
01/21
91/24
01/26
01/28
01/31
02/02
02/04
02/Q7
92/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MEflN
S.DEV
C V *
SI
218
126
128
144
. 157
143
95
120
157
125
139
146
145
135 .
143
13S
151
142
137
166
142
124
106
134
36.63
27.2
SE
26.0
44.0
23.0
34.0
22.0
19.0
23.0
44.0
41.0
34.0
31.5
17.0
37.0
19.5
22.9
32.0
27.0
25.0
26.Q
29.0
22.0
24.0
19.0
26.9
9.64
35.8
F
9.07
9.50
.9.65
9.36
8.64
9.65
9.36
9.22
9.79
9.22
9.22
9.22
9.36
9.22
9.07
9.79
9.22
9 ..22
9.79
9.65
9.22
9.22
9. "07
8.95
1.92
21.5
FW
0.65
0.75
1.04
0.95
1.04
0.94
0.78
0.00
0.36
0.93
1.04
1.03
0.97
1.02
1.02
1.05
0.26
0..00
0.00
0.00
0.31
0.34
0.00
0.60
.43
72
X
860
880
1060
1230
830
1430
910
1020
1040
1420
1360
1390
1400
1350
1480
1200
680
670
650
349
530
1050 '
790
982
381.9
38.8
XE
40
30
0
14
0
18
. 28
140
76
20
0
2
12
'4
4
0
60
172
224
368
44 .
34
196
64
92.7
144.8
FSI
XV
0.732
0.433
0.371
0.349
0.520
0.307
0.311
0.345
0.471
0.258
0.300
0.308
0.309
0.294
0.279
9.359
9.652
0.622
0.657
1.500
0.787
0.347
0.388
0.454
.28
62.6
F
-------
COMPOUND =4 NITROPHENOL
PRRRMETER =TOC
THETfl C = 18
VOLUME-REflCTOR * 3,1
DRTE
1983
01/17
01/19
01/21
01/24
01/26
01/28
91/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MERN
S.DEV
C V '/.
si
218
126
128
144
157
143
95
120
157
125
139
146
145
143
143
138
151
142
137
166
' 142
124
106
135
36.67
27.2
SE
23.0
. 19.0
15.0
31.0
14.0
16.0
22.0
37.0
26.0
28.5
17.0
18.0
23.0
24.0
24.0
29.0
29.0
32.0
30.0
24.0
21.0
Z1.0
13.0
22.6
7.89
34i9
F
8.93
9.07
9.79
9.65
9.22
9.65
9.36
9.50
9.22
8.93
9.80
9.36
9.07
9.07
9.07
9.07
8.93
9.22
9.36
9.07
8.93
9.65
9.50
8.39
1.91
21.5
FW
0.19
0.23
0.27
0.26
0.31
0.24
0.29
0.00
0.Q0
0.80
0.00
0.00
0*15
0.00
0.00
0.00
0.25
0.24
0.00
0.00
0.31
0.00
0.12
0.12
.13
107.
X
2240
2230
2150
2419
2150
2310
2889
2760
2150
1130
420
720
1100
1170
1176
1050
1160
1240
1300
920
1120
1490
1370
1529
747.25
3 48.8
XE
30
8
10
12
0
18
6
270
320
376
104
74
. 20
120
120
146
3
10
52
440
0
103
28
93
128.
134.
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
- 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
09
3' 6
'SI
XV
280
162
188
136
217
193'
100
133
217
319
046
612
386
358
358
385
375
341
318
523
365
259
237
315
.2
5.1
FCSI-SE)
XV
0.251
0.137
0.166
0.146
0.198
0.171
0.077
0.092
0.131
0.246
0.918
0.537
0.311
0.293
0.293
0.304
0.303
.0.264
0.249
0.452
0.311
0.215
0.203
0.264
.18
63.3
TC
V.10.
9.97
9.86
5il0.
V.10.
9.89
V;10.
3.34
2.26
1.04
1.28
3.22
9.93
3.33
3.33
2.46
V.10.
9.92
8.28
0.71
Jil0.
. 4.43
9.95
6.39
3.95
61.9
10
11
00
04
00
00
92
-------
COMPOUND'=2-4-6 TRICHLQROPHENOL
PfiRFlMETER =BOD
THETfl C = 1
VOLUME-REfiCTOR =3.1
DflTE
1983
01/17
91/13
01/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/13
. 02/21
. 02/23
02/25
02/28
03/02
03/04
03/07
- 03/09
MEflN
S,DEV
C V '4
SI
330
310
231
332
366
334
341
347
366
361
396'
375
394.
420
337
292'
396
385
360
375
312
384
379
353
41.47
11.7
. SE
1.6
1.5
11.9
22.3
24.2
11.3
5.2
5.6
5..1 '.
8.2
5.7
8.6
16.8
18.9
18.0
12.6
16.2
19.1
. 8.7
18.9
15.9
15.5
19.2
12^7
6. 66
52.5
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.PIPI
8.93
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.48
.11
1.2
FW
2.99
3.07
2.97
3.05
2.84
2.71
2.68
2.68
2.70
3.10
2.29
2.29 .
£.48
2.41
2.50
2.25
2.44
2.34
2.62
2.63
2.39
2.39
2.53
2.62
.27
10.2
X
690
740
610
480
610
770
780
849
880
1650
570
570
500.
490
560
330
430
450
520
580
440
440
440
625
266.4
. 42.6
XE
12
4
12
4
'24
44
48
52
52
24
64
64
48
48
48
42
40
48
36
40
44
44
36
38
17.1 .
44.8
FSI
XV
U466
1 . 284
1.161.
2.120
1.839
1.329
1.340
1.266
1.275
0.670
2.129
2.016
2.415
2,627
1.844
2.549
2.822
2.622
2.122
1.981
2.173
2.674
2.640
1.929
. 6
31.3
F
-------
COMPOUND =2-4-6 TRICHLOROPHEHOL
PRRflMETER =BOD
THETfl C = 3
VOLUME-REflCTOR
3.1
DRTE
1383
01/17
91/19
91/21
01/24
01/26
01/28
01/31
02/62
02/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MEflN
.S.DEV
C V '/.
SI
330
310
231
332
. 366
334
341
347
366
361
396
' 375
394
' 420'
337
292
336
385
360
375
312
384
379
353
41.47
11.7
SE
2.0
0.7
5.1
0.7
2.3
2.0
0.7
2.4
2.0
3.1
"» T
O. t
2.2
5.6
6.3
2.0
3.2
5.9
6.3
6.5
14.3
8.8
11.8
9.9 .
4.7
3.66
77.9
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.64
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.19
.12
1.3
FU
0.93
0.97
1.00
1.00
1.03
0.89
9.93
0.89
0. 93
1.03
0.98
0.96
0.98
0.98
0.96
0.97
9.86 '
0.66
0.87
0.54
0.74
0.31
0.85
0.90
- .12
13.3
X
990
960
940
903
1328
1130
1316
1350
1279
1260
1130
1330
1240
1160
1420
920
990
1300
950
980
1140
1040
1290 .
1131
163.1
14.4
XE
12
8
4
4
0
20 -
16
24
16
0
8
. 12
8
3
12
8
20
56
60 .
56
40
28
28
19
17.81
91.4
FSI
XV
0.991
0.960
0.731
1.097
1.067
0 . 879
0.774
0.764
0.857
0.852
1 . 042
0.339
0.945
1.077
0.706
0.885
1.190
0.881
1.127
1.138
0.814
1.098
0.874
0.939
.14
15.1
F
o
2
3
3
2
3
3
2
3
-i
C.
3
3
2
2
2
2
3
2
,
5
.01
.98
.00
.99
.31
.99
.01
. '39
. 08'
.01
.99
.00
.00
.99
.01
.99
.01
.01
.22
.99
.99
.99
.00
.96
16
.4
94
-------
COMPOUND =2-4-6 TRICHLOROFHENOL
PRRRMETER =BOD
THETfl C = 10
VOLUME-RERCTOR =3.3
DRTE
. 1983
01/17
61/19
01/21
91/24
01/26
01/28
. 91/31
02/62
02/04
02/07
02/09
02/11
02/14
02/16
02/1S
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
HERN
S.DEV
C V '/.
SI
330
310
231
332
366
334
341
347
366
36 1
396
375
394
420
337
292
396
385
360
375
312
384
379
353
41.47
11.7-
SE
1.
0.
0.
1.
2.
1.
1.
1.
0.
4.
5.
5.
7,
12.
2.
6.
19.
4.
4.
11.
7.
7.
9.
5.
4
7
6
3
5
7
9
8
6
4
3
2
9
3
8
2
2
9
9
7
0
5
9
3
4.59
86.
3
F
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.79
8.93
9.79
9.79
9.79
9.79
9.79
9.79
9.79
9.75
.17
1.8
FW
0.21
0.00
0.16
0.26
0.03
0.10
0.10
0.10
0.10
0.10
0.15
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.26
0.24
0.17
0.13
.06
52.2
X
1840
1820
1620
1580
1940
2030
1950
1880
1470
2580
1880
1750
1520
1510
1650
1920
1460
1190
1210
1420
1690
1750
1950
1722
300.58
17.4
XE
24 .
136
28
12
60
48
204
176
128
116
36
152
328
188
72
132
276
164
140
276
12
16
32
120
92.51
77.2
FSI
XV
0.532
0.505
0.423
0.623
0.560
0.488
0.519
0.548
0.739
0.415
0.625
0.636
0.769
0.825
0.606
0.-412
0.805
0.960
0.883
0.783
0.548
0.651
0. 577
0.627
.15
24.3 .
F(SI-SE)
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
23
530
504
422
620
556
486
516
545
737
410
617
627
754
801
601
403
766
948
371
759
535
638
562
618
14
.8
TC
9.85.
4.51
>;10.11
9.93
9.94
J:10.03
2. 96
3.28
3.50
6.16
9.86
3.50
1.51
2.53 .
6.31
4.67
1.71
2.30
2.70 ".
1.66
^10.07
':<10.08
^10.07
5.97 . '
3.5
58.8
95
-------
COMPOUND =2-4-6 TRICHLOROPHENOL THETfl C = 1
PflRflMETER -COD . VOLUME-RERCTOR =3.1
DflTE
1333
01/17
01/26
02/04
. 02/11
02/18
82/25
03/04
03/09
MERN
S.DEV
C V '/.
SI
330
630
500
600
465
482
510
520
505
30.77
17.3
SE
10.0
0.0
17.0
75.0
^118.0
40.0
50.0
32.0
42.8
38.62
30.3
F
9.50
9.50
9.50
9.50
3.50
9.50
3.50
3.50
3.50
0
0
FW
2.97
2.84
2.70
2.29
2.50
2.34
2.33
2.53
2.57
.24
3.5
X
610
610
880
570
560
450
.440 .
440
570.
145.2
25.4
XE
12
24
52
64
48
48
44
36
41
16.52
40.3
FSI
XV
1.658
3.165
1.741
3.226
F<
1.
3.
1.
2.
2.545
3.282
3.552
3.622
2.843
.78
27.3
3.
3.
3.
2.
.
28
SI-SE)
XV
608
165
6S2
823
1.833
010
204
399
533
74
.5
TC
1.
1.
1.
1.
1.
1.
1.
1.
0
0
00
00
00
00
1.00
00
00
00
00
96
-------
COMPOUND =2-4-6 TRICHLOROPHENOL
PRRRMETER =COD
THETfl C = 3
VOLUME-RERCTOR = 3.1
DRTE
1983
01/17
01/26
02/04
02/11
02/18
02/25
03/64
03/09
MERN
S.DEV
C V >:
SI
330
630
500
600
465
482
510
520
Fins
90.77
17.9
SE
10.0
0.0
13.0
46.0
33.0
42.8
44.0
, 19.0
25.9
17.64
63.1
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
0
0
FU
0.93
1.03
0.93
0.96
0.96
0.66
0.74
0.35
0.83
.12
14.1
X
990
1020
1270
1330
1420
1300
1140
1290
1220
153.62
12.5
XE
12
0
16
12
12
56
40
28
22
13.26
83
FSI
XV
0.991
1.837
1.171
1 . 342
0.974
1.103
1.331
1.199
1 . 243
.27
22.1
F(SI-SE) TC '
XV
0.
1.
1.
1.
0.
1.
1.
1.
1.
,
24
961
837
141
239
905
007
216
155
133
29
.5
3.
3.
3.
3.
3.
3.
2.
3.
3.
0
' ".2
01
01
00
00
01
01
99
00
00
97
-------
COMPOUND =2-4-6 TRICHLOROPHENOL
PRRRMETER =COD
THETfl C = 10
VOLUME-REflCTOR =3.3
DflTE
1383
01/17
01/26
02/04
02/11
02/18
02/25
93/04
03/83
MEflN
S.DEV
C V ''.
SI
330
630
500.
600
' 465
482
. 510
520
505
30.77
17.9
SE
21.0
10.0.
13.0
37.0
87.0
28.0 .
32.0
13.0
30.3
24.46
73.2
F
9.79
9.79
9.79
9.73
9.79
9.79
9.79
3.73
9.73
0
0
FW
0.16
0.03
0.10
0.10
0.10
0.10
0.26
0.17
0.13
.06
53.8
X
1620
1940
1470
1750
1650
1190
1630
1950
1658
247.89
14.3
XE
28
60
128
152
72
164
12
32'
81
59.31
73.2
FSI
XV
0.604
0.963
1.009
1.017
0.836
1.202
0.895
0.731.
0.915
.17
19.4
F TC
XV
0.
0.
0.
0.
.0.
1.
0.
0.
0.
-
21
566
948
983
954
680
132
839
762
858
18
.3
*1
9.
3.
3.
6.
2.
/A
y.\
6.
3.
49
0.11
34
50
50
31
30
0.07
0.07
93
46
.7
98
-------
COMPOUND =2-4-6 TRICHLOROPHENOL
PflRflMETER =TOC
THETfl C = 1
VO.LUME-RERCTOR
3.1
DflTE
1983
01/17
91/13
31/21
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/89
02/11
02/14
02/16
62/18
02/21
02/23
02/25
02/28
03/02
03/04
. 03/07
03/09
MERH
S.DEV
C V V.
SI
115
139
116
169
162
153
148
161
149 '
156
164
153
165
167
153
' 154.
166
159
159
162
1S1
151
152
153
14.34
9.3
SE
14.0
16.0
20.0
25.0
13.0
37.0 .
37.0
42.0
.38.0
35.0
37.0
38.0
41.0
59.0
43.0
50.0'
53.0
42.0
50.6
4S.0
56.0
73.0
53. 0
40.2
14.68
36.5
F
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
9.50
'9.50
9.50
9.50'
8.93
9.50
9.50
9.50
9.59
9.50
'9.50
9.50 .
9.48
.11
1.2
FW
2.99
3.07
£..97
3.05
2.84
2.71
2.68
2.68
2.70
3.10
2,85
2.29
2.48
2.41
2.50
2.25
2.44
2.34
2.62
2.63
2.39
2.39.
2.53
2.65
.26
3.3
X
690
740
610
486
610
770 .
780
840
880'
1650
' 750
570
500
490
560
330
430
450
520
S80
440
440
440
. '633
267.36
42.2
XE
12
4
12
4
24
44
48
52
52
24
23
64
48
48
48
42
49
48
36
40
44
44
36
37
16.26
44.4
FSI
XV
0.511
0.538
0.533
1.079
0.814
0.609
6.581
0.587
0.519
0.290
0.670
0.823
1.011
1.044
0.837
1.344
1.140
1.083
0.937
0.856
1.121
1 . 952
1.059
0.830
.26
32.4
F<
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.0.
0.
0.
0.
0.
0.
0.
01
0.
0.
28
SI-SE>
XV
449
472
482
919
723
462
436
434
387
225
519
618
760
675
602
90S
763
797
642
602
773
543
655
602
17
.9
T
1
1
1
1
1
1
1
1
1
0
1
1
0
1
1
1
1
1
1
1
1
1
1
1
0
.
C .
.00
. 00
,60
.00
.00
..00
.00
.00
. Flfi
.97
.00
.00
.98
.00.
.00
. 00
.00
.00
.00 "
.00
.00
.00 . '
.00
.00
6
99
-------
COMPOUND =2-4-6 TRICHLOROPHENOL
PflRflMETER =TOC
THETfl C = 3
VOLUME-RERCTOR = 3.1
DRTE
1983
01/17
01/19
01/21
01/24
01/26
01/28
61/31
02/02
02/04
02/67
02/09
02/11
02/14
02/16
82/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MEflN
S.DEV
C V '/.
SI
115
130
116
169
162
153
148
161
149
156
164
153
165
. 167
153
154
160
159
159
162
161
151 '
152
153
14.34
9.3
SE
19.0
23.0
23.0
32.0
19.0
26.0
25.0
39.0
42.0
44.0
43.0
37.0 .
31.0
67.0
48.0
32.0
37.0
32.0
38.0
24.0
38.0
56.0
42.0
35.5
11.78
33.1
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22.
9.22
9.22
9.22
9.22
8.64
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.19
.12
1.3
FW
0.93
0.97
1.00
1.00
1.03
0.89
0.93
0.89
0.93.
1.03
0.98.
0.96
0.98
0.98.
0.96
0.97
0.86
0.66
0.87
0.54
0.74
0.81
0.85
0.90
.12
13.3
X
990
960
940
900
1020
1130
1310
1350
1270
1260
1130
1330
1240
1160
1420
920
990
1300
950
980
1140
1040
1290
1131
163.1
14.4
XE
12
8
4
4
0
20
16
24
16
0
. 8
12
8
3
12
8
20
56
60
56
40
28
28
19
17.81
91.4
FSI
XV
0.345
0.403
0.367
0.558
0.472
0.403
0.336
0.355
0.349
0.368
0.432
0.342
0.396
0.428
0.320
0.467
0.481
0.364
0.498
0.492
0.420
0.432
0.350
0.408
.06
15.5
FC
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.
:19
SI-SE)
XV
288
331
294
453
417
334
279
269
251 '
264
318
259
321'
256
220
370
379
291
379 '
419
321
272
254
314
06
.6
TC
3.
*2
3".
2.
3.
2.
3.
2.
3.
3.
2.
3.
3.
2.
3.
2 n
3.
3.
2.
2.
2.
2.
3.
2.
.1
5.
01
98
0f1
99
01.
99
01
99
00
01
99
00
00
99 '
01
99
01
01
22
99
99
99
00
96
6
4
100
-------
COMPOUND =2-4-6TRICHLOROPHENOL
PflRfiMETER =TOC
THETfl C = 18
VQLUME-REflCTOR = 3.3
DflTE
1983
01/17
01/19
01/21
01/24
01/26
01/28
.01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/13
. 82/21
02/23
02/25
02/28
03/02
03/04
03/07
03/09
MERH
S.DEV
C V '/:
SI
115
130
116
169
162
153
148
161
149
156
164
153
165
167
153
154
160
159
159
162
161
151
152
153
14; 34
9.3
SE
40.0
21.0
13.0
60.0
23.0
34.0
32.0
37.0
40.0
36.0
41.0.
21.0'
28.0
64.0
39.0
30.0
32.0
27.0
27.0
20.0
23.0
40.0
32.0
33.0
11.92
36
F
3.73
3.73
9.79
9.79
9.79
9.73
9.79
9.79
9.79
9.79.
9.79
" 9.79
9.79
3.79
9.79
8.93'
9.79
9.79
9.79
9.79
9.79
9.79
9.79
. 9.75
.17
1.8
FU
0.21
0,00
0.16
0.26 .
0.03
0.10
0.10
0.10
0.10
0.10
0.15
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.26
0.24
0.17
0.13
.06
52.2
X
1340 .
1820
1620
1580
1940
2030
1950
1880
1470
2580
1880
1750
1520
1510
1650
1920
1466
1190
121S
1420
1690
1756
1950
1722
380.58
17.4
XE
24
136
28
12
60
48
204
176
128
116
36
152
328
188
72
132
276.
164
14Q
276
12
16
32 '
120
32.51
77.2
FSI
XV
0.185
0.212
0.212
0.317
0.248
0.224
0.225
0.254
0.301
0.179
0.253
0.259
0.322
0.328
0.275
9.217
0.325
0.396
0.390
0.338
0.283
0.256
0.231
0.271
.05
22.1
FCSI-SE>
XV .
0.
0.
0.
0.
0.
0.
0.'
0.
0.
0.
0.
0.
0.
0.
0.
0.
8.
0.
0.
0.
0.
0.
0.
0.
,
24
121
178
189
205
213
174
176
196 '
220
138
194
224
267.
202
205
175
260
329
324
297
242
188
183
213-
05
.8
TC
9.
4.
. Jil
. 9.
9.
85
51
0.11
93
94
>;10.03
2.
3.
3.
6.
9.
3.
1.
2.
6.
4.
1.
2.
2.
1.
>.l
*1
*1
5.
3.
58
96
28
50
16
86
50
51
53
31
67
71
30
70
66
0.07
0.08
0.07
37
5
.8
101
-------
COMPOUND ^COMBINED
PflRflMETER =BOD
THETfl C » 1
VOLUME-RERCTOR = 2.943
DRTE
1983
01/17
01/24
01/26
01/28
01/31
02/02
. 82/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
NEflN
S.DEV
C V '/.
SI
297
402
332
301
373
336
378
378
390
381
380-
338
330
317
. 326
353
322
184
293
357
339
48.84
14.4
SE
3.6
3.5
2.0
1.5
1.0
1.5
1.3
3.3
2.3
1.9
9.2
4.8
3.9
7.8
8.4
5.6
4.2
9.5
4.8
11.5
4.6
3.07
66.2
F
8.64
8.93
3.22
9.07
9.07
9. 22
9.07
8.64
9.07
9.22
8.78
8.64
9.07
8.64
8.64
8.78
8.78
8.78
8.93
8.93
8.91
.21
2.3
FW .
2.63
2.51
2.95
2.72
2.30
2.83
2.87
2.95
2.95
2.95
2.40
1.64
0.79
1.98
2.43
2.03
0.83
1.79
1.04
1.67
2.25
.73
32.7
X
450
410
400
600
540
530
460
590
310
540
750
590
460
590
370
410
390
230
330
410
471
117.46
24.3
XE
24
28
0
22
4
10
6
0
0
0
64
110
120
86
28
56
104
48
80
72
43
40.69
94.4
FSI
XV
1.934
2.969
2.595
1.543
2.124
1.982
2.527
1.877
3.869
2.206
1.508
1.678
2.2B6
1.574
2.581
2.600
2.458
1.889
2.689
2.637
2.272
.57
25.2,
F TC
XV
1.
2.
2.
1.
2.
1.
2.
1.
3.
2.
1.
1.
2.
1.
2.
2.
2.
1.
2.
2.
2.
910
943
579
535
119
973
515
861
841
195
472
655
180
535
515
559
426
792
645
552
240
57
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0
00
03
00
00
00
00
00
00
00
00
30
00
00
00
00
00
00
00
00
00
00
25.4 0
102
-------
COMPOUND =COMBINED
PRRflMETER =BOD
THETfl C = 3
VOLUME-RERCTOR = 3.1
DflTE
1983
01/17
01/24
01/26
01/28
01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/23
03/02
03/04
03/07
MEflN
S.DEV
' c v /.
SI
297
402
332
301
373
336
378
378
399
381
380
338
330
317
326
356
322
184
. 293
357
339
48.84
14.4
SE
2.1
1.7
6.2
1.9
91.9
2.6
3.1
4.2
2.9
2.3
3.2
4.0
1.5
1.8
3.4
1.9
3.5
2.4
0.5
2.4
7.2
19.97
278.4
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
0
0
FU
1.03
0.93
1.03
0.98
0.99
0.99
0.95
1.03
0.99
0.94
0.99
1.01
0.96
1.01
0.98
1.01
1.01
1.01
0.96
1.01
0.99
.02
3
X
930
990
1150
1180
1560
. 1390
1510
I860
1650
1460
1640
1450
1870
1350
1200
1260
1270
1410
1700
1450
1414
257.93
18.2
XE .
0
12
0
3
8
8
16
0
8
16
8
4
16
4
8
4
4
4
16
4
7
5.39
72.8
FSI
XV
0.950
1.208
0.S59
0.759
0.711
0.719
0.745
0.604
0. 703
0.776
0.689
0.693
0.525
0.698
0.808
0.845
0.754
0.388
0.513
0.732
0.734
.16
23
FOI-SE5 TC
XV
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
24
943
203
843
754
536
713
738
593
693
771
683
685
522
694
800
841
746
383.
512
727
720
17
.1 '
3.
3.
3.
2.
3.
2.
2.
3.
3.
3.
3.
3.
3.
3.
3.
2.
2.
3.
2.
3.
3.
0
.2
01
01
01
99
00
99
99
01
01
01
01
00
01
00
00
99
99
00
99
00
00
103
-------
COMPOUND ^COMBINED
PRRRMETER =BOD
THETfl C = 10
VOLUME-RERCTOR =3.13
DflTE
1983
01/17
01/24
01/26
01/28
01/31
02/02
02/04
02/07.
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
HERN
S.DEV
C V '/.
SI
237
492
332
301
373
336
378
378
390
381
380
338
330.
317
326
358
322
184
293
357
339
48.84
14.4
SE
2.1
1.4
1.3
1.0
1.7
2.2
2.3
3.4
3.7
1.9
2.5
1.6
1.1
1.0
2.3
4.0
4.6
1.6
2.7
5.6
2.5
1.24
50.8
F
3.38
9.38
9.38
9.38
9.40
9.40
9.50
9.50
9.40
9.36
9.38
9.40
9.41
9.40
9.42
9.41
9.40
9.36
9.41
9.45
3.41
.03
.4
FW
0.31
0.25
0.31
0.21
0.31
0.26
3.26
0.00
0.31
0.21
9.27
0.26
a. 00
0.00
0.05
9.20
0.05
0.05
0.05
0.30
.0. 18
.12
66.4
X
2120
1990
2000
2008
2018
2112
2002
1481.
1522
1520
1705
2300
1450
1563
1650
1893
1592
1692
1648
1686
1798
253.98
14.1
XE
0
14
0
22
0
8
12
83
0
16
8
12
122
92
248
88
94
58
62
66
50
61.01
121.4
FSI
XV
0.420
0.605
0.497
0.449
0.555
0.478
0.573
0.775
0.770
0.750
0.668
0:441
0.684
0.609
0.595
0.567
0.607
0.325
0.535
0.639
0.577
.12
23.8
F
XV
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.417
.603
.495
.448
.553
.475
.569
0.768
.762
.746
.664
.439
.682
.607
.590 .
.561
.599
.322
.530
.629
.573
.11
20.7
TC
V.10.
9.96
V.10.
V.10.
V.10.
*10.
9.92
10
10
03
10
62
5.88
V.10.
V.10.
5il0.
V.10.
3.95
5.66
2.15
4.99
5.20
8.48
7.78
4.76
8.01
2.69
33.6
10
22
01
17
104
-------
COMPOUND ^COMBINED THETft C = 1
PRRflMETER =COD VOLUME-REflCTOR = 2.949
DflTE
1383
01/17
01/26
02/04
02/11
02/18
02/25
03/04.
HERN
. .S.C'EV
C V >.
SI
430
540
440
600
560
450
485
501
66.35
13.2
SE
12.0
23.0
13.0
46.0
37.0
58.0
27.0
31.6
16.82
53.2
F
8.64
9.22
9.07
9.22
9.07
.8.78
8.93
8.99
.21
2.4
FW
2.63
2.95
2.87
2.95
0.79
2.03
1.04
2.18
.92
42.3
X
450
400
460
540
460
410
. 330
436
65.02
14.9
XE
24
0
6
0
120
56
80
41
46.3
113.3
FSI
XV
2.800
4.221
2.942
3.474
3.744
3.268
4.450
3.557
.62
17.4
F(SI-SE) TC
XV
2.
4.
2.
3.
3.
2.
4.
3.
.
17
721
002
855
208
497
847
203
333
58
.6
1.
1.
1.
1.
1.
1.
1.
1.
.0
0
00
00 '
00
00
00
00
00
00
105
-------
COMPOUND "COMBINED
PRRRMETER =COD
THETR C = 3
VOLUME-RERCTOR = 3.1
DHTE
1983
01/17
01/26
02/04
02/11
02/18
02/25
03/04
MERN
S.DEV
C V V.
SI
439
540
440
600
560
450
485
501
66.35
13.2
SE
12.0
11.0
10.0
34.0
31.0
28.0
5.0
18.7
11.82
63.2
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
0
3
FU
3.10
1.03
0.95
0.94
0.96
1.01
0.96
1.28
.8
62.
X
930
1150
1510
1460
1870
1260
1700
1411'
323.69
& 22.9
XE
0
0
16
16
16
4
16
10
7.95
81.8
F
1.
1.
0.
1.
0.
1.
0;
1.
B
21
SI
XV
375
397
867
222
891
062
849
095
23
.7
FCSI-SE
XV
1.337
1.368
0.847
1.153
0.841
0.996
0.840
1.055
.23
22
.) T
1
3
2
3
3
2
2
' 2
27
C
.00
.01
.99
.01
.01
.99
.99
.71
75
.8
106
-------
COMPOUND -=COMBINED
PflRfiMETER =COD
THETfl C = 10
VOLUME-RERCTOR '= 3.13
DflTE
1983
01/17
01/28
02/04
02/11
02/18
02/25
03/94
MEflN
S.DEV
C V '/.
SI
430
540
440
600
560
450
485
501
66.35
13.2 -
SE
0.0
15.0
7.0
30.0
33.0
26.0
12.0
17.6
12.39
-70.5
F
9.38
9.38
9.50
9.36
9.41
9.41
9.41
9.41
.04
.4'
FW
0.31
0.21
0.26
0.21
0.00
0.20
0.05
0.18
..11
63
X
2120
2008
.2002
1520
1450
1898
1648
.1807
264.5
14.6
XE
0
22
12
16
.122
88
62
46
45.72
99.3
FSI
XV
0.608
0.806
0.667
1.180
.1.161
0.713
0.885
0.860
.23
26.8
F TC
XV
0
0
0
1
1
0
.0
0
2
.608
.784
.656
.121
.093
.672
.863
.828
.2
5.2
5S10.
Jil0.
9.92
JU0.
3.95
4.99
7.78
8.15
2.66
32.7
10
08
22
107
-------
COMPOUND =COMBINED
PfiRfiMETER =TOC
THETfl C = 1
VOLUME-REflCTOR = 3.1
DflTE
1983
01/17
01/24
01/26
01/28
01/31
02/02
Q2/04
02/07
02/09
92/11
02/1-3
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
03/07
MEflN
S.DEV
C V *
SI
110
151
133
150
142
152
169
152
161
169
- 151
193
154
135
120
161
238
160
130
137
154
27.64
17.9
SE
20.0
26.0
13.0
27.0
30.0
43.0
41.0
33.5
37.5
31.0
36.5
41.0
44.0
34.0
31.0
41.0 .
35.0
39.0
27.0
38.0
33.0
7.91
24
F
8.64
8.93
9.22
9.07
9.07
9.22
9.07
8.64
9.07
9.22
8.78
8.64
9.07
8.64
8.64
8.78
8.78
8.78
8.93
8.93
8.91
.21
2.3
FW
2.63
2.51
2.95
2.72
2.90
2.83
2.87
2.95
2.95
2.95
2.40
1.64
0.79
1.93
2.48
2.03
0.83
1.79
1.04
1.67
2.25
.73
32.7
X
450
410
400
.600
540
530
460
590
310
540
750
590
460
590
370
410
390
290
330
410
471
117.46
24.9
XE
24
28
0
22
4 .
10
6
0
0
0
64
2
120 '
86
28
56
104
. 48
80
72
38
38.46
102 ,
FSI
XV
0.716
1.115
1.040
0.769
0.809
0.897
1.130
0.755
1.597
0.978
0.599
0.983
1 . 030 .
0.670
0.950
1.169
1.817
1.643
1.193
1.012
1.044
.32
31.1
F
-------
COMPOUND ^COMBINED
FflRRMETER =TQC
THETfl C = 3
VOLUME-REfiCTOR = 3.1
DflTE
1983
01/17
01/24
01/26
91/23
01/31
02/02
02/04
02/07
02/09
02/11
02/14
02/16
02/13
02/21
02/23
02/25
02/28
03/02
03/04
03/07
MERN
S.DEV
C V '/.
SI
110
151
133
150
142
152 .
169
152
161
169
151
193
154
135
120
161
233
160
130
137.
154
27.64
17.9
SE
19.0
22.0
22.0
27.0
39.0
45.0
41.0
34.0
23.0
33.0
27.0
33.0
37.0
. 71.0
26.0
40.8
26.0
30.0
34.0
39.0
33.4
11.43
34.3
F
9.22
9.22
9.22
9.22
9,22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
0
0
FW
1.03
0.93
1.03
0.9S
0.99
0.99
0.95
1.03
0.99
0.94
0.99
1.01
0.96.
1.01
0.98
1.01
1.01
1.01
0.96
1.01
0.99
.02
3
X
930
990
1150
1180
1560
1390
1510
I860
1650
1460
1640
1450
1870
1350
1200
1260
1270
1410
1700
1450
1414
257.93
18.2
XE
0
12
0
8
8
8
16
@
8
16
8
4
16
4
8
4
4
4
16
4
7
5.39
72.3
FSI
XV
0.352
0.454
0.344
0.378
0.271
. 0.325
0.333
0.243
0.290
0.344
0.274
0.406
0.245
0.297'
0.297
0.380
0.557
0.337
0.227
0.281
0.332
.07
23.6
F
-------
COMPOUND =COMBINED
PflRflMETER =TOC
THETfl C o 10
VOLUME-REflCTOR = 3.13
DflTE
1983
01/17
01/24
01/26
01/28
01/31
02/02
02/04
62/97
02/09
02/11
02/14
02/16
02/18
02/21
02/23
02/25
02/28
03/02
03/04
93/07
MERN
S.DEV
C V K
SI
110
151
133
150
142
152
169
152
161
169
151
198
154
135
120
161
238
160
130
137
154
27.64
17.9
SE
13.0
23.0
17. 0
23.0
33.0
40.0
42.0
37.0
23.0
26.0
30.0
33.0
36.0
21.0
31.0
39.0
30.0
25.0
23.0
42.0
29.4
8.39
23.6
F
9.38
9.38
9.38
9.38
9.40
9.40
9.50
9.50
9.40
9:36
9.38
9.40
9.41
9.40
9.42
9.41
9.40
9.36
9.41
.9.45
9.41
.03
.4
FU
0.31
0.25
0.31
0.21
0.31
0.26
0.26
0.00
0.31
0.21
0.27
0.26
0.00
0.00
0.05
0.20
0.05
0.05
0.05
0.30
0.18
.12
66.4
X
2120
1990
2000
2008
2018
2112
2002
1481
1522
1528
1705
2300
1450
1563
1659
1898
1592
1692
1648
1.686
1798
253.98
14.1
XE
0
14
0
22
0
8 .
12
83
0
16
8
12
122
92
248
88
. 94
58 .
62
66
50
61.01
121.4
FSI
XV
0.155
0.227
0.199
0.224
0.211
0.216
0.256
0.312
0.318
0.332
0.265
0.259
0.319
0.259
0.219
0.255
0.449
0.283
0.237
0.245
0.262
. .06
23.9
F TC
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
B
26
137
193
174
190
162
159
193 .
236
272
281
213
215
245
2i9
162
193
392
239
195
170-
212
05
.9
J<10.
9.96
. X10.
'/.10.
X10.
5il0.
9.92
5.88
*10.
V.10.
v.ie.
*10.
3.95
5.66
2.15
4.99
5.20
8.48
7.78
4.76
8.01
10
10
08
10
62
10
22
01
17
2.69
33.6
110
-------
COMPOUND = FLUORRNTHENE
PRRRMETER = BOD
THETfl C = 1
VQLUME-RERCTQR = 3.17
DRTE
1983
04/94
04/06
04/08
04/11
04/13
04/15
,04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
. 05/09
05/11
' 05/13
05/16
05/18
05/20
05/23
05/25
MERN
. S.DEV
c v /.
Si
270
278
281
271
286
259
237
267
280
260
273
307
303
282
276
269
260
279
259
289
281
210
180
268
27.52
10.2
Se
6.2
2.5
.13.4
6.8
3.2
4.6
4.0
6.0
8.9
4.1
4.9
4.9
4.2
4.2
3.4
4.0
11.6
8.3
4.8
5.5
4.4
1.6
5.8
5.5
2.76
50
F
9.22
9.50
9.50
9.22
9.50
9.50
9.52
9.50
9.51
9.50
9.22
9.55
9.50
9.65
9.22
9.50.
9.50
9.46
9.50
9.45
9.50-
9.50
9.50
9.46
..11
1.2
Fw
2.53
2.76
3.17
3.08
3.17
3.17
3.17
1.77
3.17
2.91
2.08
3.17
3.17
3.17
2.80
3.17
3.17
3.17
2.69
3.17
3.17
3.17
3.17
2.96
.'38
12.9
X
580
467
424
390
410
260
362
490
404
363
220
365
202
300
260
298
322
410
260
300
260
280
295
344
93.13
27
Xe
40
29
0
4
0
0
0
38
0
10
24
0
0
. 0
10
0
0
0
42
- 0
0
0
0
8
14.24
174.2
FSi F
XV
1.354
1.784
1.986
2.021
2.090
2.985
1.966
1.633
2.079
2.147
3.609
2.534
4.451
2.862
3.088
2.705
2.420
2.031
2.985
2.872
3.239
2.248
1.829
2.475
.71
28.9
1.
1.
1.
1.
2.
2.
1.
1.
2.
2.
3.
2.
4.
2.
3.
2.
2.
1.
2.
2.
3.
2.
1.
2.
.
XV
323
768
SSI
970
067
932
933
596
013
113
544
493
338
819
049
665
312
970
930
17
188
231
770
425
71
29.3
1.
1.
1.
1.
1.
1.
1.
1.
1.
-1.
1.
1.
1.
1.
1.
1.
1.
1.
.0.
1.
1.
1.
1.
1.
TC
06
04
00
01
00
00
00
34
00
03
li-
es
00
00 .
04
00
00
00
85
00
00
00-
00
02
.08
7.
9
111
-------
COMPOUND = FLUORflHTHENE
PRRflMETER = BOD
THETfl C = 3
VQLUME-REFlCTOR = 3.17
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
. 04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/09
05/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V '/.
Si
270
278
281
271
286
259
237
267
280
259
273
307
300
282
276
269
260
279
259
289
281
210
180
268
27.53
10.2
Se
2.2
1.3
1.8
3.1
1.2
1.6
3.6
2.9
3.1
2.2
1.9.
2.4
0.6
1.9
2.2
2.6
2.9
3.6
4.5
5.1
5.6
0.8
2.8
2.6
1.27
48.8
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
F
.07
.40
.36
.36
.50
.36
.50
.50
.48
.50
.50
.50
.36
.22
..50
.50
.55
.50
.50
.50
.22
.40
.50
.43
.11
1.2
Fw
1.07
1.06
1.06
1.00
0.62
1.06
1.00
0.75
1.06
1.06
0.79
1.06
1.06 '
0.91
0.94
1.06
1.06
1.06
1.05
1.05
1.06
1.06
1.06
1.00
.12
12.1
X .
320
845.
806
677
856
933
986
1000
868
1180
907
1280
867 .
986 .
1160
1082
1004
970
836
"893
830
860
890
936
137.76
14.7
. Xe .
16
0
0
0
40
0
0
20
0
0
26
0
0
16
14
0 .
0
0
0
0
0
0
0
6
10.92
190.3
FSi
XV
0.942
0.976
1.029
1.182
1.001
0.820
0.720
0.830
0.965
0.658
0.902
0.719
1.022
0.832
0.713
0.745
0.780
0.862
0t928
0.970
0.985
0.724
0.606
0.864
.14
16.6
F
-------
COMPOUND = FLUORRNTHENE
PfiRflMETER = BOD
THETfl C « 10
VOLUME-REftCTOR
3.17
DflTE
1983
04/04
04x06
04/68
04/11
04/13
04/15
64/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/89
05/11-
05/13
05/16
05/18
05/20
95/23
05/25
MEflN
S.DEV
C V '/.
Si
270
278
281
.271
286
259
237
267
280.
259
273
307
308
.282
'276
269
260
279
259
289
281
210
180
268
27.53
10.2
Se
1.7
1.0
0.4
2.7
1.3
1.2
1.4
1.5
i.S .
1.8
1.4
0.9
1.4
0.9
1.1
1..5
0.9
2.0
1.8 '
. 2.0
4.3
1.8
2.2
1.6
.77
48.2
F
9.50
9.36
9.40
9.50
9.50
9.58
9.40
9.48
9.46
9.50
9.50
9.50
9.50
9.50
9.50
9.40
9.50
9.52
9.50
9.59
9.22
9.50
9.46
9.47
.06
.7
Fw
0.07
0.10
0.30
0.05
0.11
0.32
0.32
0.05
0.32
0.32
0.24
0.30
6.32
0.32
0.30
0.20
0.32
0.32
8.32
0.31
0.31
0.31
0.31
0.25
..1
39.6
X .
2033
2005
2222
1804
2350
2103
1800
1910
1887
1740
1880
2000
1800
1886
1730
1610 .
1956
2058
1674
I960
1890
2080
2020
1930
173.63
8.9
Xe
52
46
60
61
52
.0
0
130
0
0
25
8
0
0
34
20
0
0
0
0
0
0
0
21
32.77
154.4
FSi
XV
0.398
0.409
0.375
0.450
0.365
0.369
0.396
0.418
0.443
0.446
0.435
0.460
0.499
0.443
0.478
0.495
0.398
0.407
8.464
0.442
0.432
0.303
0.266
0.417
.05
13.5
F
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
XV
396
408
374
446
363
367
388
416
440
443
433
459
497
447
476
493
397
404
460 .
439
426
300
263
415
05
13.5
10.
10.
5.
8.
9.
9.
9.
4.
9.
9.
8.
9.
9.
9.
6.
10.
9.
9.
9.
10.
10.
10.
10.
9.
1.
TC
19
15
81
58
98
91 .
91
58
91
91
73
41
91
91
59
09'
91
91
91
23
23
23
23
31
53
16.5
113
-------
COMPOUND s FLUORRNTHENE .. THETfl'C = 1
PRRRMETER = COD VOLUME-RERCTOR = 3.17
DRTE
1983
04/08
04/13
04/22
04/29
05/06
05/11
95/18
05/25
HERN
S.DEV
C V '/.
Si
500
568
418
440
360
400
410
320
.426
75.79
17.7
Se
78.5
21.0
20.0
44.0
10.0
20.0
12.0
10.0
26.9
23.53
87.3
F
9.50
9.50
9.50
9.55
9.22
9.50
9.45
9.50
9.47
.1
1
F.u
3.17
3.17
3.17
3.17
2.80
3.17.
3.17
3.17
3.12
.13
4.1
X
424
410
404
202
260
29.8
300
295
324
80.06
24.7
Xe
0
0
0
0
10
0
. 0 .
0
1
3.53
282.8
FSi FCSi-Se>
XV
3.534
4.093
3.101
6.562
4.027
4.023
4.074
3.251
4.083
1.07
26.3
2.
3.
2.
5.
3.
3.
3.
3.
3.
B
XV
979
940
952
906
915
321
955
149
827
94
24.7
1
1
1
1
1
1
1
1
1
1
TC
.00
.00
.00 .
.00
.04
.00
.00
.00
.01
01
.4
114
-------
COMPOUND = FLUORRHTHENE
PflRfiMETER = COD
THETR.C = 3.
VOLUME-REflCTOR « 3.17
DflTE
1983
04/08
04/13
04/22
04/29
05/06
.05/11
05/18
05/25
MEflH
3.DEV
C V '/.
Si
500
560
418
440
360
400
.410
320
426
75.79
17.7
Se
11.0
27.0
10.0
16.0
0.0
6.0
10.0
14.0
11.8
7.86
66.9
F
9.36
9.50
9.48
9.50
9.50
9.55
9.50
9.50
9.49.
.05
.5
Fw
1.06
0.62
1.06
1.06
0.94
1.06
1.05
1.06
0.99
.15
15.3
.X
806
856
868
. 1280
1160
1004
893
890
976
167.32
17.2
Xe
0
40
0
0
14
0
0 .
0
7
. 14.3
211.8
FSi
XV .
1.832
1.961
1.440
1.030
0..9S0
1.200
1.376
1.878
1.356
.37
27.7
F
1.
1.
1.
0.
0.
1.
1.
1.
1.
,
XV
791
866
406
993
930
182
342
030
318
35
27
2
3
. 2
2
3
2
TC
.99
.08
.99
.99
.04
.99
. 3. 82
2
3
,
1
.99
.01
03
115
-------
COMPOUND = FLUORRMTHEHE THETfl C = 10
PRRRMETER = COD VOLUME-RERCTOR' = 3.17
DflTE
1983
04/08
04/13
04/22
04/29
05/06
05/11
05/18
05/25
HERN
S.DEV
C V '/.
Si
500
560
418
440
360
400
410
320
426
75.79
17.7
Se
9.0
7.0
8.0
10.0
0.0
0.0
10.0
10.0
6. -3
4.3
63.7
F
9.40
9.50
9.46
9.50
9.50
9.50
9.50
9.46
9.48
.03
3
Fw
0.30
0.11
0.32
0.30
0.30
0.32
0.31
. 6.31
1.03
2.13
206.
X
2222
2350
1887
2000
1730
1956
I960
2020
2016
192.51
3 9.5
Xe
60
52
0
8
34
0
0
0
19
25
132.
_F
0.
0.
0.
0.
0.
0.
0.
0.
0.
.52
5 11
Si
XV
667
714
661
659
624
613
627
473
630
.07
.2
FCSi-Se
XV
0.655
0.705
0.648
0.644
0.624
0.613
0.612
0.458
0.620
.07
11.6
)
5.
9.
9.
. 9.
6.
9.
10.
0.
7.
3.
43
TC
81
98
91
41
59
91
23
50
79
39
:.5
116
-------
COMPOUND = FLUQRfiNTHENE
PflRflMETER = TOC
THETR C = 1
VOLJJME-REfiCTOR =3.17
DflTE
1983
64/04
04/86
04/08
04/11
04/13
84/15
. 04/18
04/20
. 04/22
94/25
04/27
04/29
05/92
05/04
05/06
CW/R9
05/11
05/13
05/16
05/13
05/20
05/23
05/25
MEflN
S.DEV
c v /.
Si
178
179
198
207
234
224
194
204
223
174
176
210
162 .
171
145
200
124.
204
187
179
180
199
114
185
29.6
15.9
Se
29.0
30.5
45.5
27.5
26.5
29.0
37.5
32.0
36.5
25.5
31.0
26.5
26. .0
24.0
24.0
26.5
58.5
22.5
24.0
27.8
23.5
23.0
24.0
29.2
7.17
24.5
F
9.22
9.50
9.50
9.22
9.58
9.50
9.52
9.50
9.50
9.50
9.22
9.55
9.5R
9.65
9.22
9.50
9.58
9.46
9.50
9.45
9.50
9.50
9.50
9.46
.11
1.2
Fu
2.53
2. 76
3.17 .
3.08
3.17
3.. 17
3.17
1.77
3.17
2.91
2.08
3.17
3.17
3..17
2.80
3.17
3.17
3.17
2.60
3.17
3.17
3.17
3.17
2.96
J-ir-t
OO
.12.9
X
580
467
424
390
410
260 .
362
490
404
363
220
365
202
300
260
298
322
419
260
300
260
280
295
344
93.13
27
Xe
40
20
0
4
3
0
0
38
3
10
24
0
0 .
0
10
0
0
0
42
0 .
0
0
0
8
14.24
174.2
FS*
XV
0.893
1 . 149
1.399
. 1 . 544
1.710
2.582.
1.609
1.248
1 . 654
1.437
2.327
1.733
2.403
1.735
1.622
2.011
1.154
1.431
2.155
1.779
2.075
2.130
. 1.158
1.695
. .44
26
F
-------
COMPOUND = FLUORFlHTHEHE
PRRRMETER = TOC
THETfl C = 3
VQLUME-R'EflCTOR = 3.17
C'flTE
1983
04/64
04/86
04/08
04/11
04/13
04/15
04/18
94/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/09
- 05/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V ':
Si
178
179
198
207
234
224
' 194
204
223
174
176
210
162
172
145
200
124
204
187
179
180
199
144
187
26.83
14.3
Se
31.5
23.0
22.0
21.5
31.0
22.5
26.5
33.0
27.5
27.0
31.0'
25.5
16.0
16.0
16.0
22.0
57.5
24.0
26.5
24.5
25.8
25.0
18.5
25.8
8.42
32.6
F
9.07
9.40
9.36
9.36
9.50
8.50
9.50
9.50
9.48
9.50
9.50
9.50
9.36
9.22
9.50
9.50
9.55
9.50
9.50
9.50
9.22
9.40
9.50
9.39
.22
2.4
Fw
1.07
1.06
1.06
1.00
0.62
1.06
1.00
0.75 '
1.06
1.06
0.79
1.06 .
1.06
0.91
0.94
1.86
1.06
1.06
1.05
.1.05
1.06
1.06
1.06
1.00
,12
12.1
X .
620
845
806
677
856
933
986
1000
868
1180
907
1280
867
936
1160
1082
1004
970 .
836
893
830
860
890
936
137.76
14.7
Xe
16
0
0
0
40
0
0
20
0
0
26
0
0
16 .
14
0
0
0
0
0
0
. 0
0
6
10.92
190.3
FSi
XV
0.621
0.628
0.725
0.903
0.819
0.644
0.598
0.611
0.768
0.442
0.582
0.492
0.552
0.507
0.375
0.554
0.372
0.630
0.670
0.601
0.631
0.686
0.485
0.604
.12
21.3
FCSi-Se)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
XV
511
547
645
809
711
579
509
512
674
373
479
432
497
460
333
493
200
556
575
518
543
600
423
521
12
24.4
2
2
2
3
3
2
3
3
2
2
3
2
2
3
3
2
2
2
3
3
2
2
2
3
4
TC
.59
.99
.99
.17
.08
.99
.17
.43
.99
.93
.05
.99
.99
.03
.04
.99
.99
.99
.02
.02
.99
.99
.99
.02
13
.5
118
-------
COMPOUND = FLUORfiNTHENE
PflRflMETER = TOC
THETR C.= 10
VOLUME-REflCTOR =3.17
DflTE
1383
04/134
84/06
64/08
84/11
04/13
.04/15
. 04/18
04/20
04/22
04/25
04/27
84/29
05/02
05/94
05/06
05/99
©5/11
55/13
05/16
05/18
05/20
05/23
05/25
NEflN
S.DEV
C V '/.
Si
178
173
198
207
234
224
194
2i34
223
174
176
. 210
162
171
145
200
i24
.294
187
179
180
199
114
185
29.62
15.9
Se
20.0
15.0
29.0
21.5
16.0
19.5
23.5
21.5
22.0
25.5
18.5
19.5
13.0
14.5
15.9
18.5
18.0
16.5
1.8
.. 2.0
. 4.3
1.8
.2.2
15.6
7.99
51.1
F
9.50
9.36
9.40
9.50
9.50
9.50
9.40
9.48
9.46
9.50
9.50
9.50
9.50
.9.50
9.50
3.40
9.50
9.52
9.50
9.50
9.22
9.50
3.46
9.47
.06
.7
Fw
0.07
0.10
8.30
0.05
0.11
0.32
0.32
0.65
0.32
0.32
0.24
0.30
0.32
0.32
0.30
9.20
0.32
0.32
0.32
0.31
0.31
8.31
9.31
0.25
.1
33.
x
2033
2005
2222
1804
2350
2103
1800
1910
1887
1740
1880
2000
1000
1886
1738
1610
. 1956
2958
1674
I960
1890
2080
2920
1896
259.72
6 13.7
Xe
52
46
60
61
52
0
0
130
0
0
25
8
0
0
34
20
3
0
0
e .
e
0
0 . .
21
32.77
154.4
FS1
XV
0.262
0.264
0.264
0.344
0.298
0.319
0.320
0.319
0.353
0.300
0.281
0.315
0.485
0.272
0.251
0.368
'0.190
6.298
0.335
0.274
0.277
0.287
0.168
0.298
.06
20.8
F
0.
0.
0.
0.
0.
0.
0.
8.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
e.
21
XV
233
242
226
308
278
291
281
286 .
318
256
251
285
447
249
225
334
162
274
332
271
270
284
165
272
05
.2
10.
10.
5.
8.
9.
' 9.
9.
4.
9.
9.
8.
9.
9.
9.
6.
.10.
9.
9.
9.
19.
10.
10.
10.
9.
1.
TC
19
15
81
58 '
98
91
91
58 .
91
91
73
41
91
91
59
99
91
91
91
23
23
23
23
31
53
16.5
119
-------
COMPOUND = 2-CHLOROHRPHTHflLENE . THETfl C = 1
PflRflMETER = BOD . VOLUME-REflCTOR = 3.1
DflTE
1983
04/04
04/06
04/08
04/11
34/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
05/02
35/04
05/36
05/89
05/11
05/13
05/16
05/18
05/2@
05/23
05/25
MERN
S.DEV
C V '/.
Si .
255
268
244
268
259
244.
. 248
244
242
274
280
250
276
241
264
276
254
246
248
259
297.
234
227
255
19.54
7.6
Se
2.2
1.2
1.1
5.0
1.6
2.6
6.5
3.2
3.6
4.5
5.7
3.2
5.2 .
2.4
3.7
4.6
3.7
4.8
6.7
12.2
9.6
4.9
' 5.2
4.5
2.53
.57.4
F
8.93
8.93
9.50
8.64
13.00
9.50
9.79
9.50'
9.53
9.22
9.50
9.22
9.22
9.50
9.22
9.50
9.22
9.50
9.50
9.50
9.50
9.50
9.22
9.37
.28
3
Fw
3.13
3.10
3.13
2.88
3.13
2.98
2.84
3.10
3.13
3.13
2.73
2.85
2. .63
3.13
3.10
1.87
2.80
3.10
3.13
3.10
3.00
3.10
3.10
2.95
.27
9.3
X
670
640
530
423
578
. 530
530
580
393
390
580
610
620
510
480
520
510
493
350
443
250
560
750
517
111.65
21.5
Xe
0 '
0
3
16
3
16
20
0
0
0
32
24
44
0
0.
84
24
0
0
0
4
0
3
11
20.29
176.8
FSi FCSi-Se)
XV
1.096
1.206
1.495
1.778
1.466
1.411
1.478
1.289
1.932
2.090
1.479
1.219
1.324
1..448
1.636
1.627
1.481
1.539
2.171
1.804
3.641
1.116
3.933
1.591
.54
34.1
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
1..
1.
1.
1.
1.
1.
2.
1.
3.
1.
3.
1.
,
33
XV
087
201
489
745 '
457
396
439
272
873
055
449
233
299
434
613
599 .
460
508
113
719
523
393
883
561
52
.3
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0
0
TC
00 .
00
00
00
00
00
33
00 '
03
30
00
00
00
00
00
00
00
33
30
00
00
00
33
30
120
-------
COMPOUND = 2-CHLORONflPHTHflLEHE
PflRfiMETER = BOD
THETfl C = 3
.VClLUME-REflCTOR = 3.1
DflTE
1983
04/04
04X06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
. 04/29
05/02
05/06
05/09
05/11
05/13
05/16
05/13
05/20
05/23
05/25
MEflN
.S.DEV
C V '/.
Si
255
268
244
268
. 259
244
248
244
.242
274
280
250
276
264
276
254
246
248
259
297
204
227
256
19.75
7.7
Se
2.1
0.9
1.0
3.5
1.9
1.5
2.9
0.9
1.7
1.8
1.9
1.5
1.9
1.7
2.0
0.9
0.2
2.4
3.1
2.7
0.0
2.8
1.8
.9
50.6
F
8.93
8.93
9.22
8.64
9.22
9.22
9.36
9.22
9.22
8.93
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.93
9.15
.16
1.8
Fu
1.01
1.01
1.00
8.97
1.00
0.90
0.85
0.63
1.03
1.01
1.03
0.86
0.88
1.01
0.98
0.80
1.03
1.01
1.03
0.82
1.03
1.03
0.95
.1
11
X
990
. 990
880
950
890
1010
950
940
1110
1250
1080
1179
1070
1030
1250
1170
1320
1030
950
790
940
1170
1042
135.5
13
Xe
0
0
0
8
0
16
20
44
0
4
0
. 24
20
4.
8
32
0
4
0
20
0
0
9
12.49
134.7
,.FSj
xv
0.742
0.780
0.825
0.786
0.866
0.719
0.788
0.772
0.648
0.631
0.771
0.636
0.767
0.762
0.657
0.646
0.554
0.716
0.811
1.118
0.645
0.559
0.736
.12
16.3
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
1.
0.
0.
0.
,
XV
736
777
621
776
859
714
779
769
644
627
766
632
762
757
652
643
554
709
801
108
645
552
731
11
16.2
3.
3.
3.
3.
3.
3.
.3.
.3;
3.
2.
3.
3.
2.
2.
3.
3.
3.
2.
3.
. 3.
3.
3.
3.
TC
07
07
10
00
10
00
01
00
01
99
01
01
99
98
00
01
01
98
01
00
01
01
02
.03
1.
1
121
-------
COMPOUND = 2-CHLORQNRPHTHfiLENE
PflRflMETER = BOD
THETfl C = 10
VOLUME-REftCTGR =3.3
DflTE
1383
04x04
04/06
04/08
04/11
04/13
. 84/15
64/18
04/20
04/22'
04/25
04/27
04/29
05/02
05/04
05/06
05/09
05/16
05/18
05/20
05/23
05/25
MEflH
S.DEV
C V '/.
Si
255
268
244
268
. 259
244
248
244
242
274
280
250
. 276
241
264
276
248
259
257 .
204
227
256
20.38
7.9
Se
2.3
1.4
0.2
3.9
1.1
1.5
1.6
0.5
1.2.
1.8
1.0
1.4
0.9
0.9
0.9
0.8
0.6
1.9
1.7
1.0
1.0
1.3
.77
59
F
9.79
9.79
9.79
8.93
9.79
9.79
10.37
9.79
9.79 .
8.93
9.79
9.50
9.50
9.79
9.50
9.79
9.79
9.79
10.01
9.79
9.50
9.69
.31
3.2
Fw
0.33.
0.33
0.29
0.33
0.33
0.22
0.31
0.33 '
0.27
0 . 00
0.11
0.25
0.33
0.33
0.33
0.31
0.33
0.33
0.33
0.00 .
0.00
0.26
.11
46.6
X
2610
2540
2560
2250
2100
2040
2100
2390
2380
1900
1940
2280
2070
2080
2130
1980
1090
1320
2040
1620
900 -
2015
.453.87
22.5
Xe
0
0
12
0
0
24
4
0
16
112
44
16
0
0 .
. 0
4
0
56
0
60
64
20
30.4
154.9
-FSJL.
XV
0.290
0.313
0.283
0.322
0.366
0.355
0.371
0.303
0.302
0.390
0.428
0.316
0.-3S4
0.344
0.357
0.414
0.675
0.582
0.442
0.374
0.726
0.397
.12
30.5
F .
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
m
30
XV
287
311
283
318
364
353
369
302
300
388 '
427
314
383
342
356
412
673
578
439
372
723
395
12
.5
10.
10.
9.
10.
10.
9.
10.
10.
9.
6.
10.
10.
10.
10.
10.
10.
10.
4.
10.
9.
4.
9.
1.
18
TC
00
00
86
00
00
92
03
90 -
88
27
01
48
00
00
00
03
00
51
00 .
10
88
28
73
.7
122
-------
COMPOUND = 2-CHLOROHRPHTHRLEHE THETfl C = 1
PRRRMETER = COD . VQLUME-RERCTQR = 3.1
DRTE
1983
04/08
04/13
04/22
04/29
05/96
05/13
05/20
05/25
MERN
S.DEV
C V V.
Si
485
500
430
450
345
350
445
390
424
57.96
13.6
Se
5.0
16.0.
22.0
30.0
14.0
26.0
10.0
21.0
18.0
8.33
46.2
F
9.50
10.00
9.50
9.22
9.22
9.50
9.50
9.22
9.46
.25
2.7
F
'3.
3.
3.
2.
3.
3.
3.
3.
3.
2
u
10
10
10
85
10
10
00
10
06
09
.9
X
500
570
390
610
480
490
. 250
750
505
148.51
29.4
Xe
0
0
0
24
0
0
4 .
0
4
.8.4
240
FSi
XV
2.973
2.830
3.379
2.194
2.138
2.189
5.455
1.547
2.838
1.2
42.4
F< Si-Si
XV . .
2.942
2. 739
3.206
2.048
2.051
2.026
5.332
1.463
2.726
1.19
43.9
??
1
1
1
1
1
1
1
1
1
0
. TC .
.00
.00
.00
.80
.00
.00
.00
.00
.00
0
123
-------
COMPOUND = 2-CHLORONRPHTHRLENE
PfiRflMETER = COD
THETfi C = 3
VOLUME-RERCTOR = 3.1
DRTE
1933
04/08
04/13
04/22
04/29
05/06
05/13
05/20
05/25
MERH
S.DEV
C V '/;
Si
485
500
430
450
345
350 .
445
390
424
57.96
13.6
Se
11.0
12.0
9.0
18.0
. 10.0
10.0
4.0
28.0
12.8
7.26
56.9
F
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.93
9.18
.1
1.1
Fw
1.00
1.00
1.03
.0.86
1.01
1.03
0.82
1.03
0.97
.08
8.5
X
880
890
1110
1170
1030
1320
790
1170
1045
180.31
17.2
Xe
0
0
0
24
4
0
20
9
6
10.02
167.1
FS,j_ F
XV
1.639
1.671
1.152
1.144
0.996
0.789
1.675
0.960
1.253
.35
28.4
1.
1.
1.
1.
0.
0.
1.
0.
1.
. .
XV
602
631
128
098
967
766
660
891
218
36
29.5
3
3
3
3
2
3
3
3
3
.
1
TC
.10
.10
.01
.01
.98
.01
.00
.01
.03
04
.5
124
-------
COMPOUND = 2-CHLORONRPHTHRLENE
PRRRMETER = COD
THETfl C = 10
VOLUME-RERCTOR =3.3
DflTE
1983
04x08
04/13
04/22
04/29
05/86
05/20
95/25
MERN
S.DEV
C V V.
Si
485
500
430
450
345
445
390
435
53.54
12.3
Se
9.0
11.0
4.0
10.0
10.0
0.0
19.0
9.0
5.94
66
F
9.79
9.79
9.79
9.50
9.50
10.01
9.50
9. '70
.2 .
2
Fw
0.29
0.33
8.27
0.25
0.33
0.33
0.00
0.26
.11
45.8
X
2560
2100
2388
2280
2130
2040
900
2056
540.55
26.2
Xe
12
0
16
16
3
0
64
15
22.67
146.9
XV
0.562
0.706
0.536
0.568
0.466
0.662
1.247
0.678
.26
38.8
F
0.
0.
0.
0.
3.
0.
1.
0.
XV
552
691
531
556
453
662
187
661
24 .
37
9.
10.
9.
10.
. 10.
. 10.
4.
9.
i.
21
TC
86
00
88
48
00
00
88
30 .
95
125
-------
COMPOUND = 2-CHLORONflPHTHRLENE THETfl C = 1
PRRRMETER = TOC . VOLUME-RERCTOR =3.1
DRTE
1983
04X04
94X136
04/98
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
94/29
05/02
05/04
05/86
05/09
05/11
05/13
05/16
05/18
05/20
05/23
05/25
HERN
S.DEV
C V '/.
Si
218
221
185
227
227
225
205
213
210
206
186
175
. 188
186
193
185
186
341
140
166
182
213
. 164
201
37.65
18.6
Se
23.0
22.0
23.0
21.0
21.0
19.0
15.0
15.0
' 13.0
25. -0
26.0
30.0
26.0
17.0
21.0
23.0
21.0
31.0
19.0
21.0
26.0
24.0
22.0
21.9
4.45
20.3
F
8.93
Si 93
9.50
8.54
10.00
9.50
9.79
9.50
9.50
9.22
9.50
9.22
9.22
9.50
9.22
9.50
9.22
9.50
9.50
9.50
9.50
9.50
9.22
9.37
.28
3.
Fw
3.10
3.10
3.10
2.88
3.10
2.90
2.84
3.10
3.10
2.78
2.73
2.85
2.63
3.10
3. 10
1.87
2.80
3.10
3.10
'3.10
3.00
3.10
3.10
2.94
.27
9.4
X
670
640
500
420
570
530
530
580
390
400
580
610
620
510
480
520
510
490
350
440
250
560
750
517
111.15
21.4
Xe
0
0
0
16
0
16
20
0
0
20
32
24
.44
0
0
84
24
0
0
0
4
0
0
12
20.21
163.7
FSi
.XV
0.903
.0.995
1.134
1.506
1 . 285
1.301
1.222
1.125
1.650
1 . 532
0.983
0.853
0.902
1.118
1.196
1 . 090
1.085
2.133
1.226
1.156
2.231
1.166
0.650
1.237
.37
30.1
F
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
1.
1.
0.
0.
1.
1.
1.
1.
1.
0.
1.
.
XV.
804
896
993
367
166
191
132
046
548
346
845
707
777
015
066
955
962
939
059
010
912
034
563
101
33
30.7
1.
1.
. 1.
1.
1.
1.
1.
1.
1.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
0
0
TC
00
00
00
00
00
00
00
©0
00
00
00
00
00
00
m
00
00 .
00
00
00
00
00
00
00
126
-------
COMPOUND = 2-CHLORONflPHTHflLENE
PRRflMETER *= TOC
THETfl C = 3
VOLUME-RERCTOR = 3.1
DftTE
1983
04/06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/06
05/09
. ' 05/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V >.
Si
221
185
227
227
225
205
213
210
206
186
175
188
193
185
186
341
140
166
182
213
164
202
39.28
19.4
Se
21.0
18.0
16.0
16.0
17.0
17.0
16.0
14.0
20.0
16.0
18.0
14.0
12.0
17..0
17. 0
17.0
14.0
11.0
17.0
19.0
19.0
16.5
2.46
14.9
F
8.93
9.22
8.64
9.22
9.22
9.36.
9.22
9.22
8.93
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
9.22
8.93
9.16
.16
1.7
1
1
0
1
0
0
0
1
1
1
0
0
1
0
0
1
1
1
0
1
1
0
Fw
.01
.00
.97
.00
.90
.85
.63
.03
.01
. 03
.86
.88
.01
.98
.80
.03
.01
.03
.82
.03
.03
.95
.1
11.2
X
999
880
950
890
1010
950
940
11-19
1250
1080
1170
1070
1030
1250 .
1170
1329
1030
950
790
940
1170
1045
138.33 .
13.2
X*
0
0
8
0
16
20
44
0
4
0
24
20
4
8
32
0
4
0
20
0
0
10
12.62
129.9
. FSi
XV
0.643
0.625
0.666
0.759
0.663
0.652
0.674
0.563
0.475
0.512
0.445
0.523
0.557
0.446 '
0.473
0.768
0.434
0.520
0.685
0.674
0.404
0.577
.11
19.5
F
-------
COMPOUND = 2-CHLORONRPHTHRLENE.
PRRflMETER = TOC
THETfl C = 18
VOLUME-RERCTQR =3.3
DRTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/23
05/02
95/04
05/06
05/09
05/16
05/18
05/20
05/23
05/25
MERN
S.DEV
C V '/.
Si
210
221
185
227
227
225
205
213
210
206
. 186
175
188
186
193
185
140
166
182
213
. 164
196
23. 18
11.8
Se
32.0
27. 0
18.0
18.0
27.0
14.0
23.0
27.0
30.0
.22.0
14.0
15.0
8.0
7.0
8.0
12.0
30.0
12.0
10.0
18.0
22.0
18.8
7.96
42.4
F
9.79
9.79
9.79
8.93
9.79
9.79
10.37
9.79
9.79
8.93
9.79
9.50
9.50
9.79
9.58
9.79
9.79
9.79
10.01
9.79
9.50
9.69
.31
3.2
Fw
0.33
0.33
0.29
0.33
0.33
0.22
0.31
.0.33 .
0.27
0.00
0.11
0.25
0.33
0.33
0.33
0.31
0.33
0.33
0.3.3
0;00
0.00
8.26
.11
46.6
X
2610
2540
2560
2250
2100
2040
2100
23^0
2380 .
1900
1940
2280
2070
2080
2130
1980
1090
1320
2040
.1620
900
2615
453.87
22.5
Xe
0
0
12
0
0
24
4
0
16
112
44
16
0 .
0 '
0
4
0
56
0
60
64
20
30.4
154.9
FSi
XV
0.239
0.258
0.214
0.273
0.321.
0.327
. 0.307
0.264.
0, 262
0.293
0.284
0.221
0.261
6.265
0.261
0.277
0.381
0.373
0.271
0.390
0.525
0.298
.07
23.6
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
XV
202
227
194
251
283
307
272
231
224
262
263
202
250
255
250
259
299
346
256
357 '
454
269
05
22.3
10.
10.
9.
10.
10.
. 9.
10,
10.
9.
6.
10.
10.
10.
10.
10.
10.
10.
4.
10.
9.
4.
. 9.
1.
TC
00
00
86
00
00
92
03
00
88
27
01
48
00
00
00
03
00
51
00
10
88
28
73
18.7
128
-------
COMPOUND » HYDRflZOBENZENE
PflRfiMETER = BOD
THETfl C =1
VOLUnE-REftCTOR = 3.13
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/86
05/09
05/11
05/13
65/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V *
Si .
285
274
269
276
276
258
243
292
263
288
290
280
273
235
274
303
249
243
268
280
294
198
263
271
22
8.1
Se
2.4
1.7
1.4
4.2
3.1
2.8
4.2
5.1
3.0
2.6
3.3
3.3
6.0
12.6
12.4
11.7
10.6
7.8
8.2
7.2
6.2
10.7
3.6
5.8
3.62
62.1
F
8.64
8.78
9.22.
8.93
9.65
9.7*9
9.07
8,64
9.65
9.22
9.36
8.93
9.79
10.08
9.65
9.07
8.93
8.93
9.22
9.07
9.07
8.64
9.36
9.20
.4
4.3
Fw
2.52
2.53
3.13
3.13
3.02
2.63
3.13
2.68
3.13
3..13
2.32
2.80
3.13
2.67
3.13
2.70
3.13
3.13
3,13
3.13
3.13
3.08
2.97
2.95
.22
7.6
X
400
420
410
580
490
470
390
430
510
470
420
450
320
390
510
360
310
. 300
480
490
680
540
490
445
84.52
19
Xe
40
40
0
a
8 .
32
0
32
0
0
20
24
0
24
0
24
0
0
0
.0
0
12
12
12
14.46
124.1
FSi
XV
1.967
1.830
1.933
1.575
1.737
1.717
1.843
1 . 874
1.620
1.805
2.065
1.775
2.668
2.353
1.656
2.439
2.292
2.311
1.645
1.656
1.253
1.012
1.605
1.854
.37
20.4
F
1.
1.
1.
1.
1.
1.
1.
i.
i.
i.
2.
1.
2.
2.
1.
2.
2.
2.
1.
1.
1.
0.
1.
1.
XV
950
319
923
551
717
698
811
842
602 '
739
041
754
610
249
531
345
194
237
594
613
226
957
583
813
36
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
20.1
TC
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00 '
.00
1
129
-------
COMPOUND = HYDRRZOBENZEME
PfiRflMETER = BOD
THETB C = 3
VOLUME-REflCTOR =3.14
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
64/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/09
05/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
3.DEV
C V *
Si
285
274
269
276
276
258
248
292
268
238
290
280
273
285
274
303
249
243
268
280
294
. 198.
263
271
22
8.1
Se.
2.0
1.6
1.0
2.7
2.0
1.8
1.9
3.2
2.9
2.8.
2.5
1.4
2.8
5.5
3.2
4.2
3.0
3.4
2.6
2.3
3.3
0.4
0.8
2.5
1.12.
45.2
F
9.50
9.50
9.79
8.93
8.64
9.79
8.93
8.78
9.79
9.65
9.65
9.36
9.07
10.37
9.97
9.64
9.22
9.36
9.22
9.50
9.79
9.22
9.36
9.40
,39
4.2
Fw
0.94
0.97
0.42
1.05
1.05
1.05
1.05
0.86
1.05
1.05
0.57
0.84
1.05
0.97
1.05
1.00
0.95
1.05
1.05
1.05
1.05
1.05
1.00
0.96
.16
16.8
X
970
1360
1070
1170
1090
1060
1290
1029
1200
860
1138
1000
1110
980
.1270
1548
920
1480
1350
1130
1140
1290
1350
1165
177.43
15.2
Xe
12
12
72 .
0
0
0
0
24
0
0
60
24
0
8
0
0
8
0
0
0
0
0
8
10
19.25
194.2
FSi
XV
0.889
0.610
0.784
0.671
0.697
0.759
0.547
0.793
0.696
1.029
0.789
0.835
0.710
0.960
0.623
0.604
0.795
0.489
0.583
0.750
0.804
0.451
0.581
0.715
.14
20.1
F
0.
0.
0.
a.
0.
0.
0.
0.
0.
i.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
,
XV
883
606
781
664
692
754
543
785
689
019
782
830
703
942
616
596
785
483
577
744
795
450.
579
709
14
20
3
3
2
2
2
2
2
3
2
2
2
3
2
3
2
3
3
2
2
2
2
2
2
3
1.
TC
.00
.00
.99
.99
.99
.99
.99
.01
.99
.99
.98
.01
.99
.00
.99
.14
.07
.99
.99
.99
.99
.99
.99
.00
03
1
130
-------
COMPOUND = HYDRRZOBEN2ENE
FRRRMETER = BOD
THETR C = 10.
VOLUME-REflCTOR = 3.1
DfiTE
1983
04/04
84/86
04/08
04/11
84/13
84/15
04/18
04/20
84/22
84/25
84/27
84/29
85/82
85/84
05/06
' 85/89
05/11
85/13
05/16
85/18
- 85/28
85/23
85/25
MEFIN
S.DEV
C V '/.
Si
285
274
269
276
276
258
248
292
268
288
298
288
.273
285
274
. 383.
249
243
268
288
294
198
. 263
271
22
8.1
Se
1.8
2.2
8.3
3.8
2.4
1.1
1.2
2.2
'1.5
1.4-
2.1
1.6
8.6
1.5
1.1
8.9
8.0
8.6
1.6
1.0
2.8
8.5
1.8
1.4
.78
55.8
F
9.79
9.36
9.58
9.22
8.64
9.94
9.36
8.64
.9.94
9.79
9.50
9.22
9.22
18.08
9.36
9.22
8.93
9.36
9.79'
9.07
9.87
9.94
9.22
9.48
.4.
4.2
F
U.
8.
.0.
8.
0.
8.
8.
8.
0.
8.
8.
8.
0.
8.
8.
0.
8.
8.
8.
0'.
8.
8.
8.
0.
9
u
24
28
31
31
31
31
31
24
31
31
28
24
31
27
31
25
31
31
31
31
31
26
29
29
02
.3
X
2218
2288
1858
2528
2588
2358
2140 .
2578
2448
2208
2418
2568
2480
2688
2698
3858
2590
2290
2490
2578
2518
2750
2818
2441
256.95
18.5
Xe-
16
8
8
8
8
0
8
28
8
8
8
20
.8 -
12
8
4
8
8
8
8
8
14
4
5
6.96
151.1
FSi
XV
0'. 487
8.363
8.446
0.326
0.298
8.352
0.358
8.317
8.352
8.413
0.369
0.325
8.327
8.356
8.308
8.295
8.277
0.320
8.340
0.319
8.343
0.231
0.389
0.340
.84
13.7
F
-------
COMPOUND = HYDRRZOBENZENE THETfl C = 1
PflRflMETER = COD VOLUME-REflCTOR =3.13
DRTE
1983
04/98
04/13
04/22
04/29
05/06
05/11
05/20
05/25
HERN
S.DEV
C V '/.
Si
536
450
445
400
390
390
420
365
424
51.73
12.2
Se
27.0
14.0
10.0
30.0
44.0
34.0
26.0
10.0
24.4
12. IS
50
F
9.22
9.65
9.. 65
8.93
9.65
8.93
9.07
9.36
9.31
.31
3.4
Fw
3.13
3.02
3.13
2.80
3.13
3.13
3.13
2.97
3.06
.12
3.9
X
410.
490
510
450
510
310
680
490
481
104.66
21.7
Xe
0
8
0
24
0
0
0
12
6
8.79
159.9
FSi .
XV
3.808
2.831
2.690
2.536
2.358
3.589
1.790
2.228
2.729
.67
24.8
. F
3.
2.
2.
2.
2.
3.
1.
2.
2.
XV
614
743
630
346
092
276
679
167
568
63
24. S
1.
1.
1.
1.
1.
1.
1.
1.
1.
0
3
TC
00
00
00
00
00
00
00
00
00
132
-------
COMPOUND. = HYDRFIZOBENZEHE THETfl C = 3 .
PflRfiMETER = COD VClLUME-REflCTOR =3.14
DflTE
1983
@4/08
. 04/13
04/22
94/29
05/06
05/11
05/20-
05/25
MEflN
S.DEV
C V '/.
Si
530
450
445
480
390
390
420
365
424
51.73
12.2
Se
33.0
16.0
10.0
28.0
20.0
24.0
7.0
18.0
19.5
8.75
44.8
F
9.79
8.64
9.79
9.36
9.07
9.22
9.79
9.36
9.38
.4
4.3
Fw
0.42
1.05
1.05
0.84
1.05
0.95
1.05
1.00
0.93
.21
23.4
X
.1070
1090
1200
1000
1270
920
1140
1350
1130
141.01
12.4
Xe .
72
0
. 0 .
24
0
8
0
8
14
24.84
177.4
M
1.544
1.136
1.156
1.192
6.887
1.245
1.149
0,806
1.139
.22
19.7
F
1.
1.
1.
1.
0.
1.
1.
0.
1.
m
19
XV
448
096
130
109
842
168
130
766
086
2
.2
2
2
2
3
2
3
2
2
3
TC
.99
.99
.99
.01
.99
.07
.99
.99
.00
.02
9
133
-------
COMPOUND = HYDRRZOBENZENE
PflRflMETER = COD
THETfl C = 10
VOLUME-RERCTOR = 3.1
DRTE
1983
04/08
84/13
04/22
04/29
05/06
05/11
05/20
05/25
MERN
S.DEV
c v /.
Si
530
450
445
400
390
390
420
365
424
51.73
12 ,2
Se
12.0
11.0
2.0
20.0
0.9
19.0
7.0
10.0
10.1
7.16
70.7
9.
8.
9.
9.
9.
8.
9.
9.
9.
4
F
50
64
94
22
36
93
07
22
24
38
.2
Fw
0.31
0.31
0.31
0.24
0.31
0.31
0.31
0.29
0.30
.02
8.2
X
2580
2580
2440
2560
2690
2590
2510
2010
2495
208.46
8.3
Xe
0
0
0
20
0
0
0
4
3
7.01
233.6
FSi.
XV
0.630
0.486
0.585
0.465
0.438
0.434
0.490
0.540
0.508
.07
13.8
F TC
0.
0.
0.
0.
0.
6.
0.
0.
0.
XV
615
474
582
441
438
413
481
525
496
07
14.5
10.00
10.00
10.00 '
9.99
10.00
10.00 .
10.00
10.07
10.01
.02
.2
134
-------
COMPOUND = HYDRflZOBENZEHE
PflRflflETER = TOC
THETfl C = 1
VOLUME-REflCTOR
3.13
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/09
05/11
05/16
05/18
05/20
05/23
05/25
MEflH
S.DEV
C V '/.
Si
219
225
232
238
219
223
199
219
215
185
208
177
155
170
186
205
164
203
197
180
212
194
201 .
22.67
11.2
Se
24.0
34.0
30.0
22.5
25.0
29.5
25.2.
39.0
26.5
26.5
30.0
28.0
24.0
39.0
30.5
31.5
33.0
29.0
28.0
38.5
49.0
44.5
30.9
6.74
21.8
F
8.64
8.78
9.22
8.93
9.65
9.79
9.07
8.64
9.65
9.22
9.36
3.93
9.79
10.08
9.65
9.07
8.93
9.22
9. .07
9.07
8.64
9.36
9.22
.4
4.4
Fu
2.52
2.53
3.13
3.13
3.32
2.63
3.13
2.68
3.13
3.13
2.82
2.80
.3.13
2.67
3.13
2.70
3.13
3.13
3.13
3.13
3.00
2.97
2.94
..22
7.7
X
400
420
410
500
490
470
390
430
510
470
420
450
320
390
510
360
318
480
490 .
680
. 540
490
451
80.25
17.7
Xe
40
40
0
0
3
32
0
32
0
0
20
24
0
24
0
£4
8
0
0
0
12
12
12
14.57
119.6
FSi
XV
1.511
1.503
1.667
1.358
1.378
1.484
1.479
1.406
1.300
1.159
1.481
1.119
1.515
1.404
1.121
1.650
1.569
1 . 246
1.165
0.767
1.084
1.184
1.340
.21
16
F
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
1'.
0.
1.
1.
1.
0.
0.
0.
0.
1.
.
17
(Si-S
XV
346
276
451
230
221
288
291
156
140
993
267
942
280
082
937
397
286
068
999
637
833
912
134
2
'.7
e>
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
.
TC'
.00
.00
.00
400
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.03
.00
.00
.00
.00
.00
.00
1
135
-------
COMPOUND = HYDRflZOBENZENE
PflRflMETER = TOC
THETR C = 3
VOLUME-REflCTOR =3.14
DflTE
1983
04/04
04/06
04/03
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
85/02
05/04
05/06
05/09
85/11
05/16
05/18
05/20
05/23
05/25
MERH
S.DEV
C V '/,
Si
219
225
232
233
219
223
199
219
215
185
208
177
155
170
186
205
164
203
197
180
212
194
201
22.67
11.2
Se
43.0
25.5
29.0
19.0
17.0
22.5
19.0
20.0
23.5
22.0
31.0
14.5
11.5
17.0
17.5
20.0
18.-0
18.5
16.0
13.0
23.5
21.5
21.0
6.81
32.4
F
9.50
9.50
9.79
8.93
8.64
9.79
8.93
8.78
9.79
9.65
9.65
9.36
9.07
10.37
3.07
9.64
9.22
9.22
9.50
9.79
9.22
9.36
9.40
.4
4.3
Fw
0.94
0.97
0.42
1.05
1.05
1.05
1.05
0.86
1.05
1.05
0.57
0.34
1.05
0.97
1.05
1.00
0.95
1.05
1.05
1.05
1.05
1.00
0.96
.16
17.1
X
970
1360
1070
1170
1090
1060
1290
1029
1260
860
1130
1000
1110
980
1270
1548
920
1350
1130
1140
1290
1350
1150
167.43
14.5
Xe
12
12
72
0
0
0
0
24
0
0
60
24
0
8
0
0
8
0
0
0
0
8
10
19.58
188.9
FSi
XV
0.633
0.501
0.676
0.579
0.553
0.656
0.439
0.595
0.559
0.661
0.566
0.526
0.403
0.573
0.422
0.409
0.523
0.442
0.527
0.492
0.483
0.428
0.532
.08
16.5
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
XV
549
444
592
532
510
590
397
541
498
582
481
483
373
516
382
369
466
401
485
457
429
331
475
07
15.1
3.
3.
2.
2.
2.
2.
2.
3.
2.
2,
2.
3.
2.
3.
2.
3.
3.
. 2.
2.
2.
2.
2.
3.
TC
00
00
99 .
99
99
99
99
01
99
99
98
01
99
00
99
14
07
99
99
99
99
99
00
.03
1.
1
136
-------
COMPOUND =|HYDRflZQBENZENE
PflRRMETER = TOC
THETR C = 10
VQLUME-RERCTOR = 3.1
DflTE
1983
04/04
04/06
04/08
84/11
04/13
04/15
94/18
04/28
04/22
. 04/25
04/27
04/29
05/02
05/04
05/06
65/69
05/11
05/16
05/18
05/20
05/23
05/25
MEfiN
S.DEV
C V *
Si
219
225
232
238
219
223
1^9
219
215
185
208
177
155
170
186
. 205
164
203
197
180
212
194
201
22.63
11.2
Se
19.5
13.6
12.0
29.0
19.0
18.0
19.6
19.5
17.0
25.0
18.5
25.0
15.0
16.5
14.0
14.5
15.0
' 11.0
10.0
19.0
27.0
17.0
17.9
5.03
28.1
F
9.79
9.36
9.50
9.22
8.64
9.94
9.36
8.64
9.94 '
9.79
9.50
9.22
9.22
10.08
9.36
9.22
8.93
9.79
.9.07
9.07
, 9.94
9.22
9.40
.41
4.3
Fw
0.24
0.23
0.31
0.31
0.31
0.31
0.31
0.24
0.31
0.31
0.28
.0.24
0.31
0.27
0.31
0.25
0.31
0.31
0.31
0.31
0.26
0.29
0.29
.02
9.4
X
2210
2280
1850
2520
2580
2350
2140
2570
2440
2200
2410
2560
2480
2600
2690
3050
2590
2490
2570
2510
2750
2010
2448
260.83
10.6
Xe ..
16
8
0
0
0
0
0
20
f\ .
0
8
20
0
12
0
4 .
0
0
0 .
0
14
4
5
7.05
146.4
FSi
XV
0.313
0.298
0.384
0.281
0.237
0.304
0.281
0.237
0.283
0.266
0.264
0.206
0.186
0.213
0.209
0.200
0.182
0.257
0.224
0.210
0.247
0.287
0.253
.04
19.4
FCSi-Se)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.
XV
285
281
364
247
216
280
254
216'
260
230
241
177
168
192
193
186
166
244
213
1'88
216
262
231
04 .
20.6
10.
9.
10.
10.
10.
10.
10.
10.
10.
10.
9.
9.
10.
9.
10.
11.
10.
10.
10.
10.
10.
10.
10.
TC
03
94
00
00
00
00
00
15
00
00
98
99
00
83
00
34
00
00
00
00
02
07
08
..39
3.
9
137
-------
COMPOUND = COMBINED THETH C = 1
PflRflMETER = BOD . VOLUME-REflCTOR = 2.945
DflTE
1983
04x@4
04x06
04/03
04/11
04/13
04/15
.94/18
04/2©
04/22
04/25
04/27
04/29
05/02
05/04
FI5/96
05/09
05/11
05/1?
05/16
05/18
05/20
05/23
05/25
ME"RN
S.DEV
C V '/.
Si
235
274
252
274
281
244
267
' 244
. 198
292
273
300
271
243
271
274
274
253
271
310
322
216
252
265
28.4
18.7
Se
1.9
1.0
1.3
3.7
2.2
2.4
3.0
3.9
3.3
2.2
3.2
2.6
8.2
4.3
4.4
4.4
5.5
7.0
3.2
3.1
7.8
0.8
2.9
3.6
1.98
55.4
F
8.96
8.93
8.93
8.93
8.93
8.90
8.60
8.93
8.93
8.96
8.93
8.64
8.93
8.93
8.80
8.90
8.86
8.90
8.90
8.63
8.93
8.93
8.90
8.88
.1
1.2
Fu
'2.23
2.00
2.72
2.76
2.55
2,95
2.95
1.76
2.95
2.95
2.61
2.92
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.77
.33
12.1
X
400
440
404
382
407
260 .
290
349
280
580
636
610
450
4330
490
540 .
490
434
518
512
. 650
420
502
625
814.72
130.3
Xe
32
46
10
8
18
0
0
40
0
0
24
4
0
0
0
0
0 . .
0
0
0
0
0
0
8
14.1
178.3
FSi
XV
1.787
1.888
1.891
2.175
2.094
2.836
2.689
2.120
2.144
1.532
1.330
1.443
1.826
0.170
1 . 653
1.533
1.682
1.762
1.581
1.768
1.502
1.559
1,517
1 . 760
.51
29
F
1.
1.
1.
2.
2.
2.
2.
2.
2.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
XV
773.
881
882
146
077
80S .
658
086
109
520
315
430
771
167
626
509
649
713
562
750
466
554
509
737
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
TC
.06
.03
.02
.02
.04
.00
.00
.14
.00
.00
.03
.00
.00
.00 '
.00
.00
. 90
.00
.00
.00
.00
.00'
.00'
.02
.5 .03
29.1
3
.5
138
-------
COMPOUND = COMBINED
PflRRMETER = BOD
THETfl C = 3
VOLUME-RERCTOR = 3.1
DflTE
1983
04x04
04/06
04/03
04/11
04/13
04/15
-04/18
84/20
04/22
94/25
04/27
04/29
05/02
05/06
05/09.
05/11
95/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V '/.
Si
235
274.
252
274
281
244
267
244
138
292
279
300-
271
271
274
274
253
270
310
322
216
252
266
28.64
10.7
Se
2.0
0.8
0.9
3.9
2.0
2.1
1.9
1.8
' 1.9
2.2
1.6
1.2
1.4
2.0
3.8
1.4
1.9
1.9
5.1
3.0
0.2.
2.9
2.1
1.1
52.9
F
9.22
9.22
9.22
9.22
8.35
9.22
9.36
9.22
9.22
8.64
9.22
8.93
8.93
9.50
9.22
9.50
9.22
9.22
9.22
8.93
9.22
8.93
9.13
.26
2.8
Fw
1.01
1.01
1.01
1.00
1.00
0.90
1.00
1.03
1.03
1.01
1.00
1.03
0.77
1.03
1.03
1.01
1.03
1.03
1.03
1.03
1.00
1.03
1.00
.05
5.8
X
1010
1190
1060
1190
1120
1280
1100
1160
1120
1200
1070
1210
1110
989
1420
1210
1190
1.180
1200
1040
1150
1170
1153
94.87
8.2
Xe
0
0
0
0
0
20
4
0
0
4
4
0
36
0
0
4
e
0
e
0
4
0
3
8.48
245.7
FSi
XV
0.692
0.685
0.707
0.685
0.676
0.567
0.733
0.626
0.526
6.678
0.776
0.714
0.703
0.847
0.574
0.694
9.632
0.68.1
0.768
0.892
0.559
0.620
0.683
-.08
13
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
13
(Si-S,
XV
636
683
705
675
671
362
728
621
521
673
771
711
700
841
566
690
628
676
756
884
558 .
613
678
08 .
3)
3.
3.
3.
3.
3.
3.
3.
3.
3.
'2.
3.
3.
3.
3.
3.
2.
3.
3.
3.
3.
3.
3.
3.
.6
1.1
TC
07
07
07
10
10
01
01
01
01
99
01
01
00
01
01
99
01
01
01
01
01
01
02
i3
139
-------
COMPOUND = COMBINED
PfiRflMETER = BOD
THETfl C = 19
VOLUME-REflCTOR = 3.13
DflTE
1983
04/04
04/06
04/03
04/11
04/13
04/15
94/18
94/20
04/22
04/25
04/27
04/29
05/92
05/84
05/06
05/09
05/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
C V *
Si
235
274
252
274
281
244
267
244
198
292
279
300
271
243
271
274
274
253
270
310
322
216
252
265
28.39
10.7
Se
1.7
1.5
0.2
2.8
2.4
2.0
2.3
1.5
1,8
2.2
1.0
0.8
0.2
1.5
2.3
0.6
1.4
0.8
0.8
2.7
2.3
0.3
1.9
1.5
.8
52.8
F
9.22
9.07
9.22
9.50
8.93
9.65
9.22
9.07
9.65
9.07
9.22
9.36
9.22
9.79
. 9.67
9.22
9.22
9.50.
9.22
3.92
9.79
9.22
9.07
9.28
.25
2.7
Fw
0.31
0.23
0.31
0.07
0.15
0.00
0.31
0.14
9.31
0.31
0.28
0.18
0.31
0.31
0.31
0.00
0.00
0.31
0.31
0.30
0.00'
0.31
0.29
0.21
.12
62.8
X
2300
2410
2320
2480
2570
2130
2269
1900
2080
2038
1920
1846
2020
1840
1570
1760
1810
1480
1460
1070
1120
1270
1300
1869
436.41
23.3
Xe
0
24
0
64
48
116
0
36
0
0
ft
28
0
0
0
64
228
' 0
0
128 ,
114 .
3
4
37
58.67
156.5
-.FSJL.
XV
0.301
0.329
0.320.
0.335
0.312
0.353
0.348
0.372
9.293
0.407
0.428
0.488
0.395
0.413
0.500
0.459
0.446
0.519
0.545
0.826
0.899
0.501
0.562
0.450
.15
34.1
f
-------
COMPOUND = COMBINED THETR C = 1
PflRRMETER = TOC VOLUME-REfiCTOR = 2.945
DflTE
1983
04/04
04/66
04/08
64/11
04/13
04/15
04/18
04/29
04/22
04/25
04/27
94/29
05/62
05/04
05/06
05/09
65/11
05/13
05/16
05/18
05/20
05/23
05/25
MEflN
S.DEV
c v /.
Si
185
187
212
216
219
223
207
212
188
119
118
216
200
119
203
178
196
251
140
192
181
202
198
190
34.9
18.4
Se
33.5
23.0
24.0
24.5
19.0
20.0
21.5
23.0
19.S
24.0
52.0
24.0
27.5
19.0 .
20.8
25.5
22.0
28.0
21.5
' 16.5
21.0
22.5
15.5
23.8
7.28
30.6
F
8.96
8.93
8.93
8.93
8.93
8.90
8.60
8.93
8.33
8.96
8.93
8.64
8.93
8.93
8.80
8.90
8.86
8.90
8.90
8.60
8.93
8.93
8.90
8.88
.1
1.2
Fw
2.23
2.00
2.72
2.76
2.55
2.95
2.95
1.76
2.93
2.95
2.61
2.92
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.95
2.77
.33
12.1
X
400
440
404
382
407
260
290
349
230
5S0
. 636
610
450
433
490
540
490
434
518
512
650
429
502
456
107.08
23.5.
Xe
32
46
10
8
18
0
8
40
0
0
24
4
&
0
9
0
0
0
0
0
&
0
0
8
14.1
178.3
-fS.i
XV
1.407
1.289
1.591
1.715
1.632
2.592
2.684
1.842
2.036
0.624
0.563
1.039
1.348
0.833
1.238
8.996
1.203
1.748
8.817
1.095
0.844
1.458
1.192
i.356
.5
37
F(Si-SeJ)
1.
1.
1.
1.
1.
2.
1.
1.
1.
0.
0.
i.
1.
0.
1.
0.
1.
1.
0.
1.
0.
. 1.
1.
1.
.
XV
152
130
411
520
490.
360
868
642
830
498
315
923
162
700
116
853
068
553
691
001
746
296
099
192
47
40
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.
3.
TC
.06
.08
.02
.02
.04
.00
.00
.14
.01
.00
.03
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.02
03
5 .
141
-------
COMPOUND = COMBINED
PflRflMETER = TOC
THETfl C = 3
VGUJrtE-REfiCTOR = 3.1
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
. 04/20
04/22
04/25
04/27
04/29
05/02
05/06
05/09
. 05/11
05/16
05/18
05/20
05/23-
05/25
MEAN
S-.DEV
C V '/.
Si
185
187
212
216
219
223
207
212
189
119
118
216
200
203
178
196
140
192
181
202
201
190
30.08
15.8
3e
29.0
21.0
17.0
23.0
20.0
20.0
21.0
19.0
20.0
23.0
19.0
23.0
14.0
14.0
19.0
19.0
17.0
17.0
21.0
. 20.0
21.0
19.9
3.27
16.4
F
9.22
9.22
9.22
9.22
8.35
9.22
9.36
9.22
9.22
8.64
9.22
8.93'
8.93
9.50
9.22
9.50
9.22
9.22
8.93
9.22
3.93
9.13
.26
2.9
Fw
1.01
1.01
1.-01
1.00
1.00
0.90
1.00
1.03
1.03
1.01
1.00
1.03
0.77
1 . 03
1.03
1.01
1.03
1.03
1.03
1.00
1.03
1.00
..05
5.8
X
1010
1190
1060
1190
1120
1280
1100
1160
1120
1200
1070
1210
1110
980
1420
1210
1180
1200
1040
1150
1170
1151
96.84
8.4
Xe
0
0
0
0
0
20'
4
0
0
4
4
0
. 36
0
0
4
0
0
a
4
0...'
4
8.66
239.3
FSi F
XV
0.545
0.467
0.595
0.540
0.527
0.518
0.568
0.544
0.562
0.276
0.328
0.514
0.519
0.635
0.373
0.496
0.353
0.476
0.501
0.522
0.495
0.490
.08
18
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.0.
0.
0.
0.
0.
0.
.
XV
459
415
547
482
479
472
511
495'
449
223
275
459
483
531
333
448
310
434
443
471
443
439
98
19.9
3
3
3
3
3
3
3
3
3
2
3
3
3
3
3
2
3
3
3
3
3
3
,
1
TC
.07
.07
.07
.10
.10
.01
.01
.01
.01
.99
.01
.01
.00
.01
.01
.99
.01
.01
.31
.01
.91
.02
03
.1 .
142
-------
COMPOUND = COMBINED
PflRflMETER = TOC
THETfl C = 10
VOUJME-REflCTOR =3.13
DflTE
1983
04/04
04/06
04/08
04/11
04/13
04/15
04/18
04/20
04/22
04/25
04/27
04/29
05/02
05/04
05/06
05/09
05/11
05/16
05/18
05/20
. 05/23
05/25
HERN
S.DEV
C V '/:
Si
35
187
212
216
219
223
207
212
189
119
.118
216
200
199
203
178
196
140
192
181
202
201
.186
37.06
19.9
Se
20.5
19.5
15.6
21.0
24.5.
22.5.
21.5
23.0
19.0
22.0
14.0
18.5
11.5
16.5
14.0
11.5
19.0
7.0
12.5
14.0
16.5
16.5
17.3
4.47
25.8
F
9.22
9.07
9.22
9.50
8.93
9.65
9.22
9.07
9.65
9.07
9.22
9.36
9.22
9.79
9.07
9.22
9.22
9.22
8.92
9.79
9.22
9.07
9.27
.25
2.7
Fw
0.31
0.23
0.31
0.07
0.15
0.00
0.31.
0.14
0.31
0.31
0.28
0.18
0.31
0.31
0.31
0.00
0.00
0.31
0.00
0.00
0.31
0..29
0.20
.13
64.8
X
2300
2410 .
2320
2480
2570
2130
2260
1900
2080
2080-
1920
1840
2020
1840
1570
1760
1810
1460
1070
1120
1270
1300
1887
438.16
23.2
Xe
0
24
0
64
48
116
0
36
0
0
8
'28
0
0
0
64
228
0
128
114
0
4
39
59.47
151.7
FSi
XV
0.109
0.225
0.269
6.264
0.243
0.323
0.270
0.323
0.280
0.166
0.181
0.351
0.292
0.338
0.375
0.298
0.319
0.282
0.511
0.505
0.469'
0.448
0.311
.1
33.4
F
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.
XV
083
201
249
239
216
290
242
288
252
135
160
321
275
310
349
279
288
268
478
466
430
411
283
1
35.3 .
10
9
10
9
9
5
10
10
10
10
9
9
10
10
10
9
2
10
2
3
10
9
8
2.
TC
.10
.84
.10
.99
.97
.96
.10
.12
.10
.10
.87
.79
.10
.10
. 10"
.34
.69
.10
.93
.14
.10
.87
.84
56
28.9
143
-------
COMPOUND = COMBINED THETfi C = 1
PflRflMETER = COD VOLUME-REflCTOR = 2.945
DflTE
1933
04/08
04/13
04/22
04/29
05/06
05/11
.05/18
05/25
MEflN
S.DEV
C V '/.
Si
515
475
330
400
360
370
382
415
406 :
61.55
15.1
Se
21.0
11.5
16.0
44.0
10.0
20.0
17,0
3.0
18.4
11.33
61.4
F
8.93
8.93
8.93
8.64
8.80
8.86
8.60
8.90
8.32
.13
1.5
Fw
2.72
2.55
2.95
2.92
2.95
2.95
2.95
2.95
2.87
.15
5.2
X
404
407
230
610
490
490
512
502
462
97.89
21.1
Xe
10
18
0
4
0
0
0
0
4
6.67
166.9
FSi F
XV
3.865
3.539
3.574
1.924
2.195
2.272.
2.179
2.498
2.756
.77
27.9
3.
3.
3.
1.
2.
2.
2.
2.
2.
m
28
XV
708
453
400
712
134
149
082
450
636
76
.9
1
1
1
1
1
1
1
1
1
|
' 1
TC
.02
.04
.00
.00
.00
.00
.00
.00
.01
01
.6
144
-------
COMPOUND = COMBINED
PRRflMETER = COD
THETfl C = 3
VGLUME-REfiCTOR = 3.1
DflTE
1983
04/08
04/13
04/22
04/29
05/86
05/13
05/20
- 05/25
MEflH
S.D'EV
C V ';
Si
515
475
330
400
360
370
382
415
406
.61.55
15.1
Se
9.0
12.0
4.0
12.0
0.0
0.0
13.0
8.0
7.3
5.31
73.2
F
9.22
8.35
9.22
S.93
9.50
9.22
3.93
8.93
9.04
.34
3.7
Fw
1.01
1.00
1.03
1.03
1.03
1.03
1.03
1.03
1.02
. .01
1.1
X
1069
1120
1120
1210
980
1190
1040
1170
1111
79.72
7.1
Xe
0
. 0
0
&
0
3
0
0
0
0
282.8
FSi
XV
1.445
1.142
0.876
0.952
1.126
0.925
1.058
1.022
1 . 068
.17
16.7
F(Si-Se)
1.
1.
0.
3.
1.
0.
1.
1.
1.
XV
420
113'
366
924
126
925
022
002
050
17
16.7
3
3
3
3
3
3
3
3
3
,
1
TC
.07
.10
.01
.01
.01
.01
.01
.0r
.03
03
.1
145
-------
COMPOUND = COMBINED
PRRRMETER = COD
THETfl C = 10
VOLUME-RERCTOR = 3.13
DflTE
1983
04/08
04/13
04/22
04/29
05/06
05/11
05/20
05/25
MEfiN
S.DEV
c v /.
Si
515
475
330
400
360
370
382
415
406
61.55
15.1
8e
9.0
9.0
3.0.
12.0
0.0
8.0
6.0
6.0
6.6
3.77
57
F
9.22
8.93
9.65
9.36
9.07
9.22
9.79
9.07
9.29
.29
3.2
Fw
0.31
0.15
0.31
0.18
0.31
0.00
0.00
0.29
0.19
.13
69.5
X
2320
2570
2080
1840
1570
1810
1120
1300
1826
493.26
27
Xe
0
48
0
28
0
228
114
4
53
80.9
153.3
FSi F
XV
0.654
0.527
0.489
0.650
0.664
0.602
1.067
0.925
0.697
.19
28.4
0.
0.
0.
0.
0.
0.
1.
0.
0.
m
XV
642
517
485
631
664
589
050
912
686
19
.28.4
10.
9.
10.
9.
10.
2.
3.
9.
8.
3.
TC
10
57
10
79
10
69
14
37
22
27
39.8
146
-------
COMPOUND = NICKEL
PRRRMETER = BOD
THETfi C = 1
VOLUME-RERCTOR * 3.1
DRTE Si. Se
1983
07/04/83
07/86/83
07/08/33
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
07/23/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83
08/10/83
08/12/83
210
197
231
204
230
193
247.
-247
192
228
220
216
280
272
267
100
114
205
MERN 214 8
S.DEV 47.
c v y. 22
21 4.
52
17.0
15.3
12.6
12.3
12.0
10.0
12.0
9.0
7.0
3.0
2.0
3.0
4.5
3.5
10.0
15.0
6.5
5.5
.9 9
71
.9
F
9.50
9.36
9.50
9.22
9.22
9.22
9.22
8.93
9.22
9.22
9.22
9.22
9.50
9.22
8.93
9.22
8.93
9.22
.23 2
.17
1.8
Fw X . Xe
2.75
2.18
2.54
2.71
2.62
2.53
1.91
2.04
2.23
2.67
2.91
2.88
2.85
2.40
2; 29
2.49
1.92
1.69
230
280
300
330 '
339
280
270
260
290
430
440
460
630
350
490
310
310
320
12
44
4
20
24
24
44
40
36
28
16
16
24
36
60
28
52
60
.42 351 32
.36 101
15 28.
.25 16
8 51
.11
__FSJL
XV
2
2
2
1
2
2.
2
' 2
1
.1
1
1
1
2
1
0
1
1
FCSi-Se)
.798
.124
.360
.839
.073
050.
.721
.737
.969
.577
.487
.397
.362
.311
.570
.959
.059
.905
1.905 1.
.55
28i9
m
28
XV
2.572
1.959
2.231
1.728
1.965
1.944
2.589
2.637
1.897
1.556
1.474
1.377
1.340
2.282
1.511
0.816
0.999
1.854
818
52
.8
TC
1
0
1
1
1
1.
1
. 1
1
1
0
1
1
1
1
1
1
1
1.01
'.04
4.5
.00
.94
.18
.00
.00
00
.00
.00
.00
.00
.99
.00
.00
.00
.00
.00
.00
.00
147
-------
COMPOUND = NICKEL
PHRflMETER = BOD
THEIR C * 3
VOLUME-RERCTOR « 3.1
DRTE Si
1983
07/04/83
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83
08/10/83
08/12/83
MEflN 214
S.DEV 47.21
C V /. 22
210
197
231
204
230
193
247
247
192
228
220
216
280
272
267
100
114
205
Se
2.0
2.6-
5.5
2.4
8.0
3.9
4.0
3.5
.3.0
1.5
0.5
3.0
2.5
1.5-
3.5
3.5
2.5
2.0
3.0 9
1.65
54.7
F
9.22
9.07
9.22
8.93
9.50
9.50
9.50
9.22
9.50
9.50
9.50
9.50
9.36
8.93
9.22
9.50
9.22
9.22
.31 0
.2
2.1
Fu X
0.00
0.65
0.00
0.00
0.07
0.91'
0.54
0.74
1.03
0.77
0.99
0.99
0.97
0.97
0.98
0.85
1.03
0.91
X*
330
443
390
420
430
530 .
660
570
960
800'
780
770
1030
950
1180
940
920
830
44
20
56
76
44
8
36
20
0
24
4
4
8
8
3
20
0
12
.69 719 22
. 39 254
56.9 35
.33 21
.3 98
.35
FSi.
XV
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
a.
0.
0.
' 1 . 026
.44
43.8
F< Si-Se >
893
310
762
399
639
075
147
289
613
873
864
860
821
825
673
326
369
735
1.
,
43
XV
1.875
1.293
1.720
1.383
1.582
1.059
1.128
1.271
0.603
0.863
0.362
0.848
0.313
0.820
0.664
0.315
0.360
0.727
011
44
.5
TC
2.
3.
2.
1.
3.
3.
3.
2.
3.
3.
3.
3.
2.
2.
2.
3.
3.
3.
2.88
.3
10.5
52
03
34
92
00
80
01
99
01
00
00
00
99
99
99
00
01
01
148
-------
COMPOUND = NICKEL
PflRflMETER » BOD
THETR C « 10
VOLUME-RERCTOR » 3.3
DflTE SI
1983
07/04/83
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
07/25/83
07/27/83.
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83
08/10/83
08/12/83
MERN 214
S.DEV 47.21
C V /. 22
Se
210
197
231
204
230
193
247
247
192
228.
220
216
280
272
267
100
114
205
1.
.43
42.
1.0
1.4
0.3
2.0
1.0
0.3
1.5
1.0
0.8
0.5
0.5
1.5
l.'S
1.0
1.0
1.0
1.0
0.5
0 9
8
F F
9.78
9.6S
9.78
9.78
9.78
9.78 .
9.73
9.58
9-. 78
9.78
9.78
9.78
9.78
10.00
9.78
9.78
9.30
9.79
.75 0.
.11
1.1 9
w X
0.31
0.33
0.33
0.33
0.33
0.29
0.27
0.23
0.30
0.31
0.31
0.27
0.30
0.30
0:28
0.33
0.33
0.31
1870
2080
2160
2260
2250
2060
2470
1920
2170
2260
2080
2070
2270
2520
2390
2190
2230
2200
30 2192
02 168
7.6
.18
Xc
4
0
0
0
0
8
16
20
0
4
4
12
8
8
12
0
0
4
6
6.15
110.8
XV
0.
0.
0.
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.239
.06
21.3
F TC
333
277
317
268
303
278
296
370
262
299
313.
309
366
327
331
135
147
276
0-
t
21
XV
0.331
0.275
0.317
0.265
0.302
0.277
8.295
0.369
0.261
0.298
0.313
0.307
0.364
0.326
0.330
0.134
0.146
0.276
288
06
.4
3.
10.
10.
10.
10.
10.
9.
10.
11.
10.
10.
10.
9.
9.
10.
10.
10.
10.
10.08
.23
2.3
33
00
00
00
00
10
95
11
00
10
05
15
90
98
07
00
00
08
149
-------
COMPOUND = NICKEL
PflRRMETER = COD
THETR C » 1
VOLUME-RERCTOR = 3.1
DflTE
1983
Si
Se
. F
Fu
X
Xe
FSi
XV
F
XV
TC
07/08/33
07/15/83
07/22/83
07/29/83
08/05/83
08/12/83
420
290
315
'310
290
280
55.0
47.0
23.0
20.3
33.0
29,0
9.50
9.22
9.22
9.22
8.93
9.22
2.54
2.53
2.23
2.88
2.29
1.69
300
280
290
460
490
320
MEAN 318
S.DEV 51.93
C V V. 16.3
34.5
13.79
39.9
9.22
.18
1.9
2.36 357
.4 93.09
16.9 26.1
4
24
36
16
0
60
33
23.14
63.4
4.290
3.080
3.231
2.004
1.705
2.602
2.319
.93
33.1
3.728
2.581
2.995
1.875
1.511
2.333
1
2.504
.79
31.7
18
1.00
1.00
1.00
1.00
1.00
1.03
.07
150
-------
COMPOUND = NICKEL THETfl C = 3
PflRRMETER = COD VOLUME-REFICTQR » 3.1
DflTE
1983
Si
Se
F
Fw
X
Xe
FSi
XV
F
-------
COMPOUND => NICKEL
PflRflMETER « COD
THETfl C « 10
VOLUKE-REflCTOR
3.3
DflTE
1983
Si
Se
F
Fw
X
Xe
FS1
XV
F_
-------
COMPOUND NICKEL . . THETfl C = 1 .
PfiRflMETER » TOC VOLUME-RERCTOR » 3.1
DflTE Si
1983
07/04/33
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
MEflN 167
S.DEV 11.27
C V '/. 6.7
Se .
158
172
164
146
166
169
165
183
181
35.
20.
57.
50.0
63.0
45.9
28.0
24.0
63.0
26.0
14.0
7.0
6 9
51
6
F
9.50
9.36
9.50
9.22
9.22
9.22
9.22
8.93
9.22
.27 2
.17
1.8
Fu
2.75
2.18
2.54
2.71
2.62
2.53
1.91
2.04
2.23
.39
.3 32
12.8
X Xe
239
290
300
330
330
280
270
260
290
286 28
.05 14.
11.2 52
FS1 F
12
44
4
20
24
24
44
40
36
34
XV
2.
1.
1.
1.
1.
1.
1.
2.
1.
1.772
.24
13.9
105
855
675
316
496
795
818
028
856
1.
t
20
XV
1.439
1.175
1.216
1.064
1.280
1.126
1.531.
1.872
1.785
387
29
.9
TC
1.
0.
1.
1.
1.
' 1.
1.
L.
1.
1.01
.06
6.4
00
94
19
00
00
00
00
00
00
153
-------
COMPOUND » NICKEL THETfl C » 3
PflRfiMETER ='lOC " VOLUME-RERCTOR <= 3.1
DflTE
1983
Si
Se
F
Fu
X
Xe
FSi
XV
F(Si-Se)
XV
TC
07/84/83 158 53.0 9.22 9.00 330 44 1.424 0.946 2.52
07/06/83 172 42.0 9.07 0.65 448 20 1.144 0.864 3.00
07/08/83 164 35.0 9.22 0.00 390 56 1.251 0.934 2.34
07/11/83 146 21.0 8.93 0.00 420 76 1.001 0.857 1.92
07/13/83 166 31.0 9.50 0.07 430 44 1.183 0.962 3.00
07/15/83 169 8.0 3.50 0.91 550 8 0.942 0.897 3.00
07/18/83 165 19.0 9.50 0.54 660 36 0.766 0.678 3.01
07/20/83 183 22.0 9.22 0.74 570 20 0.955 0.840 2.99
07/22/83 181 8.0 9.50 1.03 960 0 0.578 0.552 3.01
MEAN 167 26.6 9.30 0.44 528 34 1.027 0.842 2.75
S.DEV 11.27 15.1 .21 .42 191.55 24.17 .25 .14 .4
C V V. 6.7 56.8 2.3 96.6 36.2 71.5 25 16.7 14.5
154
-------
COMPOUND = NICKEL
PflRflMETER ' TOC
THETfl C = 10
VOLUME-RERCTOR » 3.3
DflTE
1983
Si
Se
F
Fw
X
Xe
_fJJL
XV
F
XV
TC
07/04/83
07/06/83
07/08/83
07/11/93
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
158
172
164
146
166
169
165
183
181
27.0
20.0
15.0
7.0
5.0
2.0
24.0
22.0
11.0
9.78
9.65
9.78
9.78
9.78
9.78
9.78
9.50
9.78
0.31
0.33
0.33
0.33
0.33
0.29
0.27
0.23
0.30
1970
2080
2160
2260
2250
2060
2470
1920
2170
MEflN 167
S.DEV 11.27
C V '/. 6.7
14.8
8.99
60.8
9.73
.09
1
0.30
.03
11.4
2138
183.01
8.5
4
0
0
0
0
8
16
20
0
5
7.74
145.2
0.259
0.242
0.225
0.191
0.219
0.243
0.198
0.274
0.247
0.238
0.214
0.204
0.182
0.212
0.240
0.169
0.241
0.232
9.99
10.00
10.00
10.00
10.00
10.10
9.95
10.11
11.00
0.232
.02
11.4 '
0.211
.02
11.6
10.13
.33
3.2
155
-------
COMPOUND " CflDMIUM THETfl C " 1
PflRHMETER * BOD VOLUME-REflCTOR « 3.17
DRTE Si
1983
07/04/83
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/10/83
08/12/83.
MEflN 229
S.DEV 29.67
C V '/. 12.9
Se
220
210
220
185
236
196
277
285
224
236
254
220
240
261
186
209
7.
5
71.
1.5
2.1
2.0
4.5
10.0
8.5
9.0
3.0
3.0
3.5
6.0
13.0
9.5
14.0
18.5
4.5
0 9.
B
1
F
9.50
9.36
9.50
9.50
9.30
9.50
9.50
9.50
9.50
9.50
9.52
9.40
9.40
9.22
9.50
9.50
46 2
07
8
Fu X
3.04
3.13
0.89
2.17
2.85
2.85
2.63
3.17
2.84
1.80
2.56
2.60
2.82
2.30
2.55
2.40
Xff
470
470
256
380
360
360
320
385
285
219
248 .
239
270
288
306
300
6
2
60
40
12
12
18
0
10
53
16
16
10
27
34
17
.54 322 21
.56 76.
22.4 23
3 17.
.6 84.
54
2
, FSi F
-------
COMPOUND " CflDMIUM THETfl C = 3
PHRflMETER * BOD VOLUME-RERCTOR » 3.17
DRTE Si
1983
07/04/83
07/06/83
07/11/83
07/15/83
' 07/18/83
07/20/83
07/22/33
07/25/83.
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/10/83
08/12/83
MEflN 231
S.DEV 31.48
C V X 13.6
Se
220
210
185
196
258
277
285
224
236
254
220
240
261
186
209
3
2.
58
2.4
1.2
2.5
5.0
10.0
4.5
3.9
1.5
2.5
3.0
3.5
3.5
5.0
5.0
2.5
.7 9.
13
.
F
9.65
9.50
9.43
9.50
9.50
9.50
9.50
9.43
9.50
9.50
9.50
9.50
9.50
9.50
9.50
50 0
04
5
Fw X Xe
0.85
1.00
1.00
1.00
0.58
1.05
1.05
1.05
1.05
1.01
1..05
1.05
0.84
0.79
0.98
660
750
779
720
600 .
730
782
655
686
726
730
689
749
716
726
12
6
0
0
30
9
0
9
0
3
0
0
17
20
6
. 96 708 6
.13 44.
14.1 6.
S9 9.35
3 149.
2
-ESL.
XV
i.
0.
0.
0.
1.
' 1.
1.
1.
1.
1.
0.
1.
1.
0.
0.
RSi-S«>
015
839
706
816
289
137
217
017
031
048
903
044
044
779
863
0.983 0.
.16
16.6
m
16
XV
1.004
0.834
0.697
0.795
1.239
1.119
1.204
1.011
1.020
1.036
0.889
1.029
1.024
0.758
0.852
967
15
.4
TC
3.
2.
3.
3.
3.
'3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.06
.06
1.9
14
97
17
17
09
02
02
02
02
03
02
02
06
07
02
157
-------
COMPOUND « CflDMIUM
PflRflMETER = BOD
THETfl C » 10
VOLUME-RERCTOR « 3.17
DRTE 'Si
1983
07/04/83
07/06/83
07/08/83
07/15/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/10/83
08/12/83
MEflN 231
S.DEV 29.29
C V y. 12.6
Se
220
210
220
196
277
285
224
236
254
220
240
261
186
20?
1.7
.66
39.8
F Fw X
2.5
0.8
2.0
1.5
1.5
2.8
1.0
3.0
1.5
1.5
1.0
2.5.
1.5
1.0
9.
B
9.50
9.57
9.50
9.65
9.37
9.59
9.50
9.50
9.60
9 . 55
9.50
9.50
9.50
9.50
53 0.
04 .
0.60 482
0.14 1295
0.00 380
0. 13- 800
0.32 1420
0.32 . 1528
0.32 1370
0.32 1488
0.29 1310
0.32 1386
0.32 1315
0.29 1499
0.20 1472
0.25 1500
23 1288
11 314.08
.5 51.3 24.3 1
Xe
22
24
26
18
9
0
0
0
4
0
0
4
18
10
9
10.31
14.5
FSl . j^Si-S*)
XV
1.368
0.490
0.673
0.746
0.533
8.5S2
0.490
0.478
0.587
0.478
0.475
0.522
0.379
0.418
0.589 0.
.24
41.4 41
XV
1.352
0.488
0.667
0.. 740
0.586
8.553
0.433
0.472
0.584
0.475'
0.473
0.517
0.376
0.416
585
24
.1
TC
7.31
10.07
12.58
5.21
9.91
9.91
9.91
9.91
9.96
9.91
9.91
10.08
10.10
10.17
9.92
1.05
10.6
158
-------
COMPOUND = CRDMIUM THETR C » 1
PRRRMETER = COD VOLUME-RERCTOR =3.17
DflTE
1933
Si
Se
F
Fu
X
Xe
FSi
XV
F
XV
TC
07/15/83 260 60.0 9.50 2.85 360 12 2.164 1.663 1.03
07/22/83 290 60.0 9.50 3.17 385 0 2.257 1.790 1.00
07/29/83 290 29.0 9.'50 2.56 248 16 3.504 3.154 1.05
08/05/83 270 50.0 9.20 2.30 288 27 2.721 2.217 1.08
08/12/33 270 37.0 9.50 2.40 300 17 2.697 2.328 1.13
MERN 276 47.2 9.44 2.66 316 14 2.669 2.231 . 1.06
S.DEV 13.41 13.88 .13 .35 55.53 9.76 .53 .58 .04
C V '/. 4.8 29.4 1.4 13.3 17.5 67.7 19.8 26.2 4.6
159
-------
COMPOUND = CflDMIUM THETfl C *> 3
PRRRMETER = COD VOLUME-RERCTOR =3.17
DRTE
1983
Si
Se
F
Fw
X
X«
FSi
XV
FCSi-Se)
XV
TC
07/15/83 260 50.0 9.50 1.05 720 0 1.082 0.874 3.02
07/22/83 290 54.0 9.50 1.05 702 0 1.238 1.007 3.02
07/29/83 290 38.0 9.50 1.01 728 3 1.207 1.049 ' 3.03
08/05/83 270 38.0 9.50 0.84 749 17 1.080 0.928 3.06
08/12/83 270 33.0 9.50 0.98 726 6 '1.115 0.978 3.02
MERN 276 42.6 9.50 0.99 723 5 1.144.0.967 3.03
S.DEV 13.41 8.93 0 .08 16.9 7.04 .07 .06 .01
C V '/. 4.8 20.9 0 8.8 2.3 135.5 6.4 7 .5
160
-------
COMPOUND = CflDMJUM
PflRflMETER » COD
THETfl C = 10
VQLUME-REflCTOR " 3.17
*
DflTE Si Se F
1983
Fw X Xe FSi
XV
F
-------
COMPOUND = CHDMIUM THETfl C 1
PflRRMETER « TOC VOLUME-REFlCTOR 3.17
DflTE
1983
Si
Se
F
Fu
X
Xe
FSi
XV
F
XV
TC
07/04/83 132 19.0 9.30 3.04 470 4 0.842 0.721 1.02
07/06/83 175 20.0. 9.36 3.13 470 2 1.099 0.974 1.00
07/13/83 174 2.0 9.50 2.85 360 12 1.448 1.432 1.03
07/15/83 143 36.0 9.50 2,85 360 12 1.190 0.891 1.03
07/20/83 159 30.0 9.50 2.63 320 18 1.489 1.208 1.05
07/22/83 191 17.0 9.50 3.17. 385 0 1.487 1.354 1.00
MEflN 162 20.7 9.48 2.95 394 8 1.259 1.097 1.02
S.DEV 22.01 11.72 .05 .2 62.32 7.04 .26 .27 .01
C V X 13.5 56.7 .6 6.9 15.8 88 20.8 25.4 1.8
162
-------
COMPOUND CflDMIUM THETfi C = 3
PflRflMETER = TOC VOLUME-REflCTOR = 3.17
DflTE
1983
Si
Se
F
Fw
X
Xe
FSi
XV
FCSi-Se)
XV
TC
07/04/83 132 30.0 9.65 0.85 563 12 0.609 0.470 3.14
07^06/83 175 46.0 9.50 1.00 750 6 0.699 0.515 2.97
07x11/83 164 16.0 9.43 1.00 779 0 0.626 0.565 3.17
07/15x83 143 34.0 9.50 1.00 720 0 0.595 0.454 3.17
07/20/33 159 16.0 9-50 1.05 730 0 0.653 0.587 ' 3.02
07/22/83 191 20.0 9.50 1.05 702 0 0.815 0.730 3.02
MERN 161 27.0 9.51 0.99 724 3 0.666 0.554 3.08
S.DEV 21.32 1J.91 .07 .07 40.82 5.01 .08 .1 .08
C V '/. 13.2 44.1 .7 7.4 5.6 167.3 12.2 18.1 2.8
163
-------
COMPOUND = CflDMIUM THETR C » 19
PHRRMETER = TOC VCUJME-RERCTQR =3.17
DRTE
1983 .
Si
Se
F
Fu t
< Xe
FSi
XV '
FCSi-Se)
XV
TC
07/04/83 132 33.0 9.59 0.89 .432 22 0.821 8.616 7.31
87x06/33 175 18.0 9.57 8.14 1295 24 8.488 8.385 18.07
07/88/83 133 7.0 9.50 0.00 980 26 0.468- 0.446. 12.53
07/15/83 143 1.8 9.65 8.13 808 18 0.544 0.540 9.21
07/28/83 159 11.0 9.57 0.32 1420 0 0.338 0.315 9.91
07/22/83 191 18.0 . 9.58 0.32 1520 0 0.377 0.341 9.91
07/18/83 170 37.8 9.50 0.80 1231 48 8.414 0.324 18.27
MERN 160 16.7 9.34 8.13 1184 19 8.481 8.424 9.89
S.DEV 28.83 13.52 .85 .14 369.72 14.4 .16 .11 1.55
C V * 12.4 80.9 .6 110.1 33.4 77.5 34 27.4 15.7
164
-------
COMPOUND = CHROMIUM THEIR C « 1
PRRRMETER = BOD VOUJME-REHCTQR » 3.13
DRTE Si
1983
07/04/83
07/06/33
07/08/83
07/11/83
07/13/83
97/15/33
07/18/83
07/20/33
07/22/83
. 07/25/83
07/27/83
07/29/83
08/01/83 .
08/03/83
08/05/83
08/08/83
08/10/83
08/12/83
MERN 253
S.DEV 32.59
C V '/. 12.8
Ss
227
175
221
213
248
239
271
280
285
251
235
270
300
272
289
232
283
268
8
8.
94
15.0
16.0
14.5
35.0
18.0
6.5
' 8.5
6.5
3.5
2.5
2.5
4.0
3.5
3.5
4.0
6.0
5.0
3.5
.3 9
27
.2
F FIJ
9.36
9.43
9.79
9.36
9.36
8.64
9.79
9.53
9.79
9.36
9.79
9.50
9.79
9.36
9.79
9.79
9.79
9.79
.55 2
.3
3.1
2
2
2
2
2
2
2
3
.3
3
3
3
2
2
3
2
2
2
.66
.37
13.
X
.12
.07
.77
.22
.70
.83
.40
.02
.11
.05
.09
.08
.80
.50
.03
.61
.16
.30
418
141.
9 33.
X
38Q
250 '
350
2S0
230
326
389
480
620
490
340
540
680
300
670
430
410
440
23
97 16
9 70.
42
36
18
32
14
13
38
8
2
6
2.
4
38
28
10
32
52
. 50
.47
2
XV
'2.253
2.109
1.975
2.548
3.224
1.584
2.231
1.771
1 . 438.
1.532
2.162
1.518
1.380
2.711
1.349
1.512
2.159
1.905
1 . 987 1 .
.5
25.4 23
XV
2.113
1.916
1.845
2.129
2.390
1.323
2.161
1.729
1.420
1.517
2.139
1.495
1.364
2.676
1 . 330
1.473
2.121
1.880
902
44
.6
TC
1,
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.00
0
.4
00
00
00
00
01
90
00
00
00
00
00
00
01
00
00
01
00
99
165
-------
COMPOUND = CHROMIUM
PRRRMETER » BOD
THETfl C 3
VOLUME-RERCTOR » 3.14
DRTE Si
1983
07/04/83
07/06/83
07/03/83
07/11/83
07/13/83
07/15/83
07/18/33
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/33
08/10/83
08/12/83
MERN 253
S.DEV 32.39
C V /. 12.8
Se
227
175
221
213
248
230
271
280
285
251
235
270
300
272
289
232
283
268
6
6.
94
17.0
18.5
15.5
15.5
17.0
7.0
4.5
5.0
2.0'
0.5
.2.0
3.0
2.5
2.5
3.0
2.0
3.0
2.5
.8 9.
47
.7 7
F Fw X
9.36
9.50
9.36
8.64
6.91
8.35
9.79
8.64
9.36
.8.64
8.93
8.64
9.79
9.07
8.64
9.50
9.36
9.50
00 0.
68
0.32
0.83
0.00
0.98
0.63
0.48
0.89
1.00
1.03
0.99
1.03
1.02
1.03
0.93
1.05
0.92
0.99.
0.96
Xe
650
1040
360
430
483
390
790
1340
1240
1290
1230
1180
1290
1130
1370
1430
1250
1290
FSi F
-------
COMPOUND * CHROMIUM
PRRflMETER " BOD
THETfl C « 10
VOLUME-RERCTOR « 3.1
DRTE Si
1983
07/04/83
07/08/83
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83
08/12/83
MERN 256
S.DEV 27.02
C V '/. 10.5
227
221
213
248
230
271
280
285
251
235
270
300
272
289
232
268
Se
4.0
16.0
4.0
6.0
2.0
2.5
2.5
1.0
1.5
1.0
2.0
1.0
1.0
2.5
1.5
1.5
3.1 9
3.69
118.3
F Fu X Xe
9.36
8.93
8.93
9.65
7.92
9.79
9.36
9.50
9.79
9.79
9.26
8.93
9.36
9.79
9.79
9.50
.36 0.
.49
0.19
0.17
0.31
0.31
0.28
0.23
0.29
0.27
0.30
0.29
0.18
0.18
0.23
0.23
0.21
0.21
2140
1939
2090
1590
2360
2100
2saa
2370
2240
2420
2370
2340
2530
3170
2850
2910
28
32
0
0
8
14
6
10
2
6
34
36
22
26
30
32
24 2369 18
05 385
5.2 20.7 16
.66 13
.2 74.
.33
6
XV
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
- 0.
0.
0.
0.332
.05
17.6
F
329
330
294
486
249
408
338
369
354
307
344
369
325
288
257
282
0.
t
17
XV
0.315
0.386
0.288
0.474
0.247
0.404
0.335
0.367
0.352
0.305
0.341
0.368
0.323
0.285
0.255
0.281
328
05
.5
TC
10.
9.
10.
10.
10.
9.
9.
10.
10.
9.
9.
9.
10.
10.
9.
9.
9.98
.07
.7
00
99
00
00
13
89
94
03
05
89
95
85
02
05
97
93
167
-------
COMPOUND » CHROMIUM THETfl C o 1
PfiRflMETER » COD VOLUME-.REFICTOR =3.13
DflTE
1983
Si Sc
? F
Fw
X
Xe
FSi
XV
F
XV
TC
07x08/83 330 13.0 3.73 2.77 330 18 3.123 3.012 1.00
07/13/83 365 37.0 8.64 2.80 320 18 3.149 2.829 1.00
07/22/83 350 30.0 9.50 3.11 620 2 1.713 1.567 1.00
07/29/83 320 39.0 9.50 3.08 540 4 1.799 1.579 ' 1.00
08/03/83 320 30.0 9.79 3.03 670 10 1.494 1.260 1.00
08/12/83 350 60.0 . 9.79 2.30 440' 50 2.488 2.062 0.99
MEAN 343 38.2 9.50 2.85 490 17 2.295 2.031 1.00
S.DEV 18.37 16.24 .44 .3 143.38 17.51 .73 .72 0
C V X 5.3 42.3 4.6 10.6 29.2 103 31.9 35.2 .2
168
-------
COMPOUND = CHROMIUM THETfl C =» 3
PRRRMETER = COD VOLUME-REflCTOR =3.14
DflTE Si Se
1983
07/08/83 350
07/15/83 365
07/22/83 350
07/29/83 320
08/05/83 320
08/12/83 350
MERN 343 29.
S.DEV 18.37 10.
C V * 5.3 34.
21.5
50.0
25.0
28.0
30.0
25.0
9 i
25
2
F
9.36
8.35
9.36
8.64
8.64
.9.50
5.98 0
.48
5.4
Fw
0
0
1
1
1
0
.76
.42
56.
X
.00
.48
.03
.02
.05
.96
96
457
7 47
Xe
360
390 '
1240
1180
1370
1220
0 17
.63 21.
.6 127.
56
28
2
4
0
12
67
5
FSi
XV
2.
2.
0.
0.
0.
0.
1.414
1
70.8
F
899
489
841
746
643
868
1.
70
XV
2.720
2.143
0.731
0.681
0.582
0.806
286
91
.7
TC
2.
3.
3.
3.
2.
3.
2.86
.34
12
16
00
01
00
99
01
169
-------
COMPOUND = CHROMIUM
PRRflMETER » COD
THETfl C B 10
VOLUME-RERCTOR = 3.1
DRTE
1983
Si
Se
F
Fw
X
Xe
..FfflL.
XV
F
XV
TC
07/08/83
07/15/83
07/22/83
07/29/83
08/05/83
08/12/83
350
365
350
320
320
350
14.0
57.0
20.0
40.0
. 29.0
23.0
9.36
7.92
9.79
9.36
9.79
9.50
0.17
0.28
0.27
0.13
0.23
8.21
1930
2360
2370
2370
3170
2310
MEAN 343
S.DEV 18.37
C V '/. 5.3
30.5
15.7
51.4
9.29
.69
7.5
0.22
.04
20.9
2518
445.7
17.6
32
8
10
34
26
32
24
11.69
49.3
0.548
0.395
0.466
0.408
0.319
0.369
0.417
.08
19.1
0.526
0.333
0.440
0.357
0.290
0.344
9.77
10.13
9.99
9.95
10.05
9.93
0.382
.08
22.4
9.97
.12
1.2
170
-------
COMPOUND » CHROMIUM . THETR C » 1
PRRRMETER = TOC VGLUME-RERCTOR >* 3.13
DRTE
1983
Si
Se
F'
Fw
X X
'a FSi
XV
F(Sl-Se)
XV
TC
07/11/83 172 52.8 -9.36 2.22 238 32 2.037 1.435 1.00
07/13/83 182 42.0 9.36 2.70 239 14 2.366 1.820 1.01
07/15/83 184 98.0 8.64 2.80 320 18 1.587 0.742 1.00
07/18/33 168 27.0 9.79 2.40 380 38 1.383 1.161 1.00
07/20/83 183 11.0 9.36 3.02 480 8 1.140 1.072 1.00
07/22/83 193 7.0 9.50 3.11 620 2 0.969 0.935 ' 1.00
MERN 181 39.5 9.34 2.71 330 19 1.584 1.194 1.00
S.DEV 10.51 33.49 .37 .34 148.72 13.89 .53 .38 0
C V '/. 5.8 84.7 4 12.7 39.1 74.4 34 32.1 .3
171
-------
COMPOUND = CHROMIUM THETfl C a 3
PflRfiMETER = TOC VOLUME-RERCTOR "3.14
DflTE
1983
Si
Se
F
Fu
X
Xe
FSi_
XV
.fiSi-SsLj
XV
TC
07/11/83 172 50.0 8.64 0.98 430 4 1.101 0.781 3.00
07/13/83 182 32.0 6.91 0.63 480 28 0.334 0.688 3.01
07/15/83 184 17.0 8.35 0.48 390 28 1.255 1.139 3.00
07/18/83 168 23.0 9.79 0.89 790 14 0.663 0.572 3.01
07/20/83 183 12.0 8.64 1.00 1340 10 0.376 0.351 2.98
07/22/83 198 18.0 9.36 1.03 1240 2 0.476- 0.433 3.01
MERN 181 25.3 8.62 0.84 778 14 0.784 0.661 3.00
S.DEV 10.51 13.85 .99 .21 421.87 11.41 .34 .28 .01
C V * 5.8 54.6 11.5 25.8 54.2 79.6 44.1 42.7 .3
172
-------
COMPOUND = CHROMIUM
PRRRMETER = TOC
THEIR C » 10
VOLUflE-RERCTOR » 3.1
DRTE Si Se F
1983
Fw X Xe FSi
XV
F<'Si-Se> TC
XV
07/11/33
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
172
182
184
168
183
193
23.0
25.0
23.0
23. e
1.0
13.0
8.93
9.65
7.92
9.79
9.50
9.79
0.31
0.31.
0.23
0.25
0.29
0.27
2090
1590
2360
2100
2500
2370
0
0
8
14
6
10
MEflN 181
S.DEV 10.51
C V '/. 5.3
18.0
9.35
51 ."9
9.26
.73
7.8
0.29
.02
3.2
2168 6
326.39 5.57
15 83
0.237
0.356
0.199
0.253
0.224
0.264
0.256
.05
21.2
0.205
0.307
0.174
0.218
0.223
0.247
10.00
10.00
10.13
9.89
9.93
9.99
0.229
.04
19.6
9.99
.08
.3
173
-------
COMPOUND B COMBINED
PRRflMETER » BOD
THETfl C * 1
VOLUME-RERCTOR 2.95
DRTE Si
1983
07/08/83
07/08/83 .
07/11/83
07/13/83
07/18/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83 '
08/10/83
08/12/83-
MEfiN 264
S.DEV 28.42
C V '/. 10.7
229
250
262
259
273
290
285
258
261
278
306
291
286
265
186
251
S*
14.2
15.0
35.5
36.5
7.0
8.0
5.5
6.0
21.0
9.0
9.5
8.0
11. .5
11.5
10.0
8.5
13.5
9.57
70.7
F
8.93
8.93
7.49
8.35
8.35
8.64
8.93
8.64
8.93
8.64
8.93
9.36
8.93
8.93
8.93
8.93
8.74 2
.41
4.7
Fu X
2.38
2.22
2.70
1.70
2.55
2.50
2.80
2.30
2.83
2.80
2.90
2.80
2.91
2.85
2.83
2.73
230
113
140
200
230
380
450
580
410
490
560
510
540
720
510
680
. 64 425
.31 185
12 43.
.54
6
Xa
20
12
8
36-
2@
28
10
14
8
12
4
10
4
12
10
24
15
8.86
61.1
F§1_ F
XV
3.
6.
4.
3.
2.
2.
..1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.401
1.55
64.8
014
880
752
666
6S5
235'
917
303
927
662
654
810
£03
114
104
117
2.
1
62
XV
2.827
6.467
4.108
3.149
2.596
2. 173
1.880
1.273
1.772
1.608
1.603
1.761
1.539
1.066
1.045
1.080
247
.4
.5
TC
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.00
0
.5
00
00
99
02
00
00
00
00
00
00
00
01
00
00
00
00
174
-------
COMPOUND * COMBINED THEIR C = 3
PfiRflMETER " BOD VOLUME-REFICTOR = 3.12
DflTE
1983
07/04/33
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83
07/18/83
07/20/83
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83
08/08/83
08/10/83
08/12/83
MEflN
S.DEV 29
C V '/. 11
Si Se
229
233
250
262
259
213
273
290
285
258
261
278
306
291
. 286
265
186
251
260 16
.51 8.
.3- 53
19.5
19.0
16.0
17.0
38.0
24.0
12.3
15.0
26.0
13.5
30.0.
10.0
17.0
17.5
5.0
5.0
5.0
9.0
.6 9.
86
.4
F
9.36
9.36
9.36
9.36
9.36
9.36
9.36
9.36
9.36
9.36
9.50
9.48
9.60
9.40
9.50
9.42
9.50
9.45
41 0
07
7
Fw X
1.00
0.64
1.00
1.00
1.00
0.'92
0.66
1.00
1.00
0.90
0.62
0.76
0.66
0.92
0.83
0.32
1.00
0.80
. 86 663
.14 130.
16.5 19.
Xe
570
610
652
888
320
630
626
880
714
660
411
605
500
612
542
654
686
663
11
62 9.
6 88.
0
26
0
0
0
8
28
0
0
10
18
18
20
8
12
15
10
17
35
6
FSi
XV
1.
1.
1.
0.
0.
0.
1.
0.
1.
1.
1.
' 1.
1.
1.
1.
1.
0.
1.
1.233
.31
25.7
F
-------
COMPOUND = COMBINED
PflRflMETER « BOD
THETfl C «s 10
VOLUME-REflCTOR
3.1
DRTE Si
. 1983
07/04/83
07/06/83
07/08/83
07/11/83
07/13/83
07/15/83 '
97/18/83
07/20/93
07/22/83
07/25/83
07/27/83
07/29/83
08/01/83
08/03/83
08/05/83 '
08/08/83
08/10/83
08/12/83
MEflN 260
S.DEV 29.51
C V '/. 11.3
229
235
250
262
259
218
273
290
285
258
261
278
306
291
286
265
186
251
Se
3.5
20.0
23.0
7.5
3.5
3.0
3.9
3.0
2.5
2.5
3.0
3.0
6.5
10.5
3.0
2.0
2.0
2.5
6.1 9
7.02
115.9
F F
9.50
9.22
9. -22
8.93
9.22
9.22
3.22
8.93
9.22
9.50
9.22
9.22
9.07
9.22
9.50
9.22
9.78
9.50
.27 0.
.21
2.2 2
'u X
9.27 1650
0.18 1139
0.12 1310
0.33 1540
0.27 1749
0.33 1660
0.25 1330
0.29 1750
0.33 1710
0.27 1310
0.25 1800
0.19 1780
0.14 1390
0.22 I960
0.26 2040
0.31 2010
0.31 1890
0.25 1830
25 1741
06 229.46
!4.8 13.1
Xe
8
16
28
0
8
n
12
4
0
8
12
24
36
20
12
0
0
12
11
10.49
94.4
FSt^ F
XV
0.425
0.619
0.568
.0.490
0.443
0.331
0.444
0.477
0.496
0.437
0.431
0.465
0.474
0.442
0.430
0.392
0.310
- 0.420
0.453 0.
.06
14.7 12
-------
COMPOUND = COHBINED THETfi C = 1
PflRflMETER = COD VGLUKE-RERC-TOR » 2.95
DflTE
1383
Si
Ss
F
Fu
X
Xe
FSi
XV
FfSi-SO
XV
TC
07/08/83 360 20.0 8.93 2.22 116 12 9.907 9.357 1.-00
07/22/33 320 55.0 8.93 2.80 450 10 2.153 1.783 -1.00
07/29/83 350 38.0 8.64 2.80 490 12 2.092 1.865 1.00
08/05/83 330 46.0 8.93 2.91 540 4 1.850 1.592 1.00
08/12/83 320 52.0 8.33 2.73 680 24 1.425 1.133 1.00
MEflN 336 42.2 8.87 2.69 454 12 3.485 3.158 1.00
S.DEV 18.16 14 .12 .27 211.02 7.26 3.6 3.47 0
C V X 5.4 33.1 1.4 10 46.4 58.5 103.3 110 .2
177
-------
COMPOUND = COMBINED
PflRRMETER = COD
THETR C = 3
VOLUME-RERCTOR <= 3.12
DflTE
1983
Si
'Se
F
Fw
X .
Xe
FSi
XV
F
XV
TC
97/06/83
07/22/83
07/29/83
08/05/83
08/12/83
360
320
350
330
320
43.0
70.0
45.0
33.0
40.0
9.36
9.36
9.48
9.50
9.45
0.64
1.00
0.76
0.83
0.30
S10
714
60S
542
668
26
0
18
12
17
MEflN 336
S.DEV 18.16
C V ^ 5.4
47.2
13.95
29.5
9.43
.06
.7
0.31
.13
16.1
629
65.65
10.4
15
3.53
65.6
1.770
1.345
1.758
1.854
1.451
1.636
.22
13.6
1.534
1.050
1.532
1.669
1.278
3.08
3.12
3.06
3.05
3.06
1.411
.24
17.5
3.03
.02
.9
178
-------
COMPOUND = COMBINED
PflRflMETER = COD
THETri C = 18
VOLUME-RERCTOR = 3.1
DfiTE
1983
Si
Se
F
Fw
X
Xe
FSjL
XV
F-:Si-Se>'
XV
TC
07/15/33
87/22/83
07/29/83
08/05/83
88/12/83
330
320
350
330
320
20.0
35.0
42.0
29.8
23.0
9.22
9.22
9.22
9.50
9.50
0.33
0.33
0.19
0.26
0.25
1660
1710
1788
2840
1830
0
0
24
12
12
MEflN 330
S.DEV 12.24
C V '/. 3.7
29.8
8.92
29.9
9.33
-.15
1.6
0.27
.05
21.8
1894
147.07
8.1
0.591
0.557
8.585
0.496
0.536
0.555
0.496
0.515
0.452
0.497
10 0.553
10.03 .03
104.5 7
0.503
.03
7.4
9.39
9.39
9,94
9.86
9.98
9.71
.29
179
-------
COMPOUND = COMBINED THETfl C » 1
PRRRHETER = TOC VOLUME-RERCTOR =2.95
DHTE
1983
Si Se
',3 A ' C
F
Fw
X
Xe
F3i
XV
FCSi-Se)
XV
TC
07/11/83 149 57.0 7.49 2.70 148 8 2.702 1.668 0.99
07/15/83 173 38.0 7.49 0.00 120 52 3.660 2.856 0.91
07/18/83 189 22.0 8.35 2.55 290 20 1.845 1.630 1.00
07/20/83 169 28.0 8.64 2.50 388 28 1.303 1.087 1.00
07/22/83 173 34.0 8.93 2.88 450 10 1.164 8.935 1.00
MEflN 171 35.8 8.18 2.11 276 24 2.135 1.635 0.98
S.DEV 14.31 13.31 .66 1.18 145.01 17.79 1.04 .75 .04
C V * 8.3 37.1 8 56.1 52.5 75.4 48.9 46.2 4.1
180
-------
COMPOUND = COMBINED
PflRRMETER = TOC
TKETfl C » 3
VOLUME-REflCTOR = 3.12
DOTE
1983
Si
. Se
F
Fu
X X
1 FSi
XV
FCSi-SeO
XV
TC
07/11/83
07/15/83
07/18/83
07/20/83
07/22/83
149
173
189
169
173
63.9
20.0.
26. 0
19.0
42.8
9.36
' 9.36
9.36
9.36
9.36
1.00
0.92
0.66
1.00
1.00
888
680
686
880
714
MEflN 171
S.DEV 14.31
C V /. 8.3
34.0
18.64
54.8
9.36
0
0
0.92
.14
16
770
105.25
13.6
0
8
28
0
0
0.503
0.763
0.827
0.576
0.727
7 0.679
.12.13 .13
168.5 19.8
0.291
0.673
0-.713
0.511
0.550
3.12
3.06
3.07
3.12
3.12
0.548
.16
30.3
3.10
.02
.9
131
-------
COMPOUND = COMBINED
PRRRMETER = TOC
THETR C a 10
VOLUME-RERCTOR =3.1
DRTE
1933
Si
Se
F
Fw
X >
J
XV '
TC
07/11/83
07/15/83
07/18/83
07/20/83
07/22/83
149
173'
189
169
173
8.0
29.0
24.0
21.0
23.0
8.93
9.22
9.22
8.93
9.22
0.33
0.33
0.25
0.29
0.33
1540
1660
1830
1750
1710
0 0.279 0.264 9.39
. 0 0.310 0.258 9.39
12 .0.307 0.268 "10.04
4 0.278 0.244 10.01
0 0.301 0.261 9.39
MERH 171
S.DEV 14.31
C V * 8.3
21.0
7.84
37.3
9.10
.15
1.7
0.31
.03
11.6
1698
1-08.02
6.3
3
5.21
162.9
0.293
.01
5.2
0.259
0
3.6
9.65
.34
3.5
132
------- |