PB83-259853
The Fate of Organic Pollutants in a Wastewater Land Treatment System
Using Lagoon Impoundment and Spray Irrigation
Y. A. Demirjian, et al
Muskegon County Wastewater Management System
Muskegon, MI
September 1983
U.S. DEPARTMENT OF COMMERCE
National Technical Information Service
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EPA-600/2-83-077
September 1983
THE FATE OF ORGANIC POLLUTANTS IN A WASTEWATER LAND TREATMENT SYSTEM
USING LAGOON IMPOUNDMENT AND SPRAY IRRIGATION
by
Y.A. Demirjian
R.R. Rediske
T.R. Westman
Muskegon County Wastewater Management System
and
Department of Public Works
8301 White Road
Muskegon, MI 49442
CR806873
Project Officer
Bert E. Bledsoe
Wastewater Management Branch
Robert S. Kerr Environmental Research Laboratory
Ada, Oklahoma 74820
ROBERT S. KERR ENVIRONMENTAL RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
ADA, OKLAHOMA 74820
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TECHNICAL REPORT DATA
//'lease read Inunctions on tin' reverse before completing)
\. PEPonr NO.
EPA-600/2-83-077
4. TITLE AND SUBTITLE
The Fate of Organic Pollutants in a Wastewater Land
Treatment System Using Lagoon Impoundment and Spray
Irrigation
6. PERFORMING ORGANIZATION CODE
3. RECIPIENT'S ACCESSION-NO.
PS8
-.
259853
5. REPORT DATE
September 1983
7. AUTHOR'S)
Y.A. Demirjian, T.R. Westman, and R.R. Rediske
8. PERFORMING ORGANIZATION REPORT NO
and Department of Public Works
8301 White Road
Muskegon, MI 49442
System
10. PROGRAM ELEMENT NO.
CAZB1B
11. CONTRACT/GRANT NO.
CR806873
12. SPONSORING AGENCY NAME AND ADDRESS
Robert S. Kerr Environmental Research Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Ada, OK 74820
13. TYPE OF REPORT AND PERIOD COVERED
Final Mav 1979 - Nov. 1981
14. SPONSORING AGENCY CODE
EPA-600/015
15. SUPPLEMENTARY NOTES
16. ABSTRACT ^skegon County Wastewater Management System (MCWMS)
facilities of its kind treating on the average of 125 thousand
is one of the largest
cubic meters of waste-
water by extended aeration, lagoon impoundment and spray irrigation. Over 70% of the
influent originates from industrial sources including several organic chemical manufac-
turers. This study was undertaken to determine the fate of the organic compounds with-
in the treatment system. The influent, which is comprised of about 150 organic chemi-
cals at low ug/1 to low mg/1 concentrations, enter the system and is treated, initially
in the biological cells. Over 90% of the total organic compounds are removed from the
water at this stage by volatilization, sedimentation into sludge and biological break-
down. Certain compounds preferentially settle in the sludge and are resistant to bio-
degradation. A few biodegradable compounds are also found in the sludge at less than
1 mg/kg. The water treated in this manner enters two storage lagoons (344 hectare
each)'. Impoundment for approximately five months helps to further remove organics by
further volatilization, sedimentation, biological breakdown and photodecomposition.
The organic compounds surviving after this treatment are in most cases less than 1% of
their influent concentrations. Spray irrigation of the lagoon impounded water, however
virtually removes all remaining organic matter.' The draintiles which collect the soil
percolated water show only sporadic low concentrations. In addition, after eight years
of irrigation, the soils are almost free of organic compounds. The analysis of corn
samples did not detect any, uptake of man-made organics.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
Sewage treatment
Waste disposal
Water quality
Organic wastes
Land application
Underdrain systems
Muskegon, Michigan
Irrigation
68D
13. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
10. SECURITY CLASS (Tliis Report)
UNCLASSIFIED
21. NO. OF PAGES
20. SECURITY CLASS (Tliis page I
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
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NOTICE
THIS DOCUMENT HAS BEEN REPRODUCED
FROM THE BEST COPY FURNISHED US BY
THE SPONSORING AGENCY. ALTHOUGH IT
IS RECOGNIZED THAT CERTAIN PORTIONS
ARE ILLEGIBLE, IT IS BEING RELEASED'
IN THE INTEREST OF MAKING AVAILABLE
AS MUCH INFORMATION AS POSSIBLE.
(-0,
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DISCLAIMER
Although the research described in this article has been funded wholly
or in part by the United States Environmental Protection Agency through
cooperative agreement number R806873 to the Muskegon County Wastewater Manage-
ment System and Department of Public Works, it has not been subjected to the
Agency's required peer and policy review and therefore does not necessarily
reflect the views of the Agency and no official endorsement should be inferred.
Mention of trade names or commercial products does not constitute endorsement
or recommendation for use.
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FOREWORD
EPA is charged by Congress to protect the Nation's land, air, and water
systems. Under a mandate of national environmental laws focused on air and
water quality, solid waste management and the control of toxic substances,
pesticides, noise, and radiation, the Agency strives to formulate and imple-
ment actions which lead to a compatible balance between human activities and
the ability of natural systems to support and nurture life. In partial re-
sponse to these mandates, the Robert S. Kerr Environmental Research Laboratory,
Ada, Oklahoma, is charged with the mission to manage research programs: to
investigate the nature, transport, fate, and management of pollutants in ground
water; to develop and demonstrate technologies for treating wastewater with
soils and other natural systems; to control pollution from irrigated crop and
animal production agricultural activities; and to develop and demonstrate
cost-effective land treatment systems for the environmentally safe disposal of
solid and hazardous wastes.
The purpose of this project was to determine the fate of toxic organics in
a slow rate land treatment system. The slow rate system was preceeded by both
extended aeration and lagoon impoundment. Due to the pretreatment steps prior
to land application a majority of the compounds were reduced to nondetectable
levels in the liquid. The irrigated water after percolation through the soil
profile was found to contain sporatic low concentration of organics. There
was no significant accumulation of organic compounds in the soils after seven
years of application nor contamination of the corn crop grown. The results of
this project have further encouraged the use of natural systems for wastewater
treatment.
jlinton W. Hall, Director
Robert S. Kerr Environmental Research
Laboratory
1H
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ABSTRACT
Muskegon County Wastewater Management System (MCWMS) is one of the largest
facilities of its kind treating on the average of 125 thousand cubic meters
of wastewater by extended aeration, lagoon impoundment and spray irrigation.
Over 70% of the influent originates from industrial sources including
several organic chemical manufacturers. This study was undertaken to de-
termine the fate of the organic compounds within the treatment system.
The influent, which comprises of about 150 organic chemicals at low ug/1
to low mg/1 concentrations, enter the system and is treated, initially,in
the biological cells. Over 90% of the total organic compounds are removed
from the water at this stage by volatilization, sedimentation into sludge
and biological breakdown. Compounds preferentially settling in the sludge
are 3,3'-dichlorobenzidine, 2-chloroaniline, alky! benzenes and 2,4'-diamino-
3,3'-dichlorobiphenyl at average concentrations ranging from 26 to 44 mg/kg.
These compounds are resistant to biodegradation. A few biodegradable com-
pounds like phenanthrene and naphthalene are also found in the sludge at less
than 1 mg/kg, possibly due to their affinity to the oils and greases commonly
found in the sludge. The water treated in this manner enters two storage
lagoons (344 hectare each). Impoundment for approximately five months helps
to further remove organics by volatilization, sedimentation, biological
breakdown and photodecomposition. The organic compounds surviving after
this treatment are in most cases less than 1% of their influent concentra-
IV
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tions. The compounds 2,2'-dichloroazobenzene and diethoxychlorobenzene, how-
ever, do not readily volatilize, are not biodegradable and do not accumulate
in the sludge and thus appear to elude treatment during the initial two steps.
Spray irrigation of the lagoon impounded water, however, virtually removes
all remaining organic, matter. The draintiles which collect the soil perco-
lated water show only sporadic low concentrations (1 yg/1) of chloroform,
1,2-dichloroethane and phthalate esters.
In addition, after eight years of irrigation, the soils are almost free of
organic compounds except for 2,2'-dichloroazobenzene and phthalates detected
in some fields. The analysis of corn samples did not detect any uptake of
nan-made organics.
The discharges, except for occasional (yig/1) levels of some organics, have
been clean. Isolated incidences are apparently due to lagoon seepage, which
also contributes to the discharge. Minimization at the industrial source
has kept the levels of contamination in the lagoon seepage under control.
This report was submitted in fulfillment of Cooperative Agreement CR806873
by Muskegon County Wastewater Management System and Department of Public Works
under the sponsorship of the U.S. Environmental Protection Agency. This report
cover the period May 1, 1979 to November 30, 1981, and work was completed as
of September 1982.
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CONTENTS
Disclaimer ii
Foreword iii
Abstract iv
Figures vii
Tables viii
Acknowledgements x
1. Introduction 1
2. Summary and Conclusions 4
3. Recommendations 6
4. Design Features of the Wastewater 8
5. Sampling 13
6. Results and Discussions 22
References 60
Appendices
A. Results 62
Water Samples 63
Well Samples 184
Lagoon Seepage Well Samples 190
Soil Samples 213
Sludge Samples 242
Corn Samples 253
B. Quality Control 255
C. Sludge Distribution 285
D. Analytical Procedures 288
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FIGURES
Number Page
1 Sampling locations 18
2 New organic monitoring wells 19
3 Lagoon seepage wells 20
vii
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TABLES
Number Page
1 Treatment Performance 1980 12
2 December 1979 - November 1980 Sampling Program- 14
3 December 1980 - November 1981 Sampling Program 16
4 Industrial Sources of Chemicals 24
5 Priority Pollutants Found in Influent Samples During 1980
and 1981 25
6 Additional Organic Chemicals Found in Influent Samples
During 1980 and 1981 27
7 Influent Chemicals Detected at Levels Over 50 yg/1 on
the Average 30
8 Influent Chemicals Detected at Levels Between 500 yg/1 and
10,000 yg/1 on the Average 30
9 March 1981 Influent Data 31
10 Priority Pollutants Found in the Spillway Effluent and
Their Removal Efficiencies During 1980 and 1981 33
11 Additional Organic Chemicals Found in Spillway Effluent and
Their Removal Efficiencies During 1980 and 1981 34
12 Results of Air Sampling for Volatile Solvents Over Aeration
Cell II, October 1981 37
13 Removal Efficiencies by Metabolic Routes in Extended
Aeration 38
14 Average Concentration of Organic Chemicals in Cell II Sludge
(pg/kg) for 1980 and 1981 39
15 Selected Sludge Concentration Factors for Chemicals in Cell
II Sludge 40
vi ii
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TABLES (continued)
Number Page
16 Seasonal Variation in the Storage Lagoons During 1980. ... 43
17 Seasonal Variation in the Storage Lagoons During 1981. ... 43
18 Average Storage Lagoon Concentrations of Organic Chemicals
and Removal Efficiencies for 1980 and 1981 . 46
19 Concentration of Organic Chemicals in East and West Lagoon
Sludge (pg/kg) 1980 48
20 Organic Chemical Levels in Irrigation Water for 1980 and
1981 49
21 Chemical Changes in Well 1B2 53
22 Chemical Changes in Well 2B2 53
23 Chemical Changes in Well LS31B2 53
ix
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ACKNOWLEDGEMENTS
The authors would like to express their sincere gratitude by acknowledging
the contributions of the following people whose collective efforts have
guided this project to a successful end.
To the laboratory staff, especially Dr. William Clark and Mr. Michael
Barry for their analytical persistence, Mr. Ray Buhl for not only his fine
analytical contributions but also his editorial assistance and to Dr.
Avinash Joshi who stepped in as the Laboratory Supervisor during preparation
of the final draft and spent numerous hours verifying data, editing and
proofreading final copies with the help of his capable assistant Mrs. Donna
Rop.
To the Environmental Protection Agency and specifically to the Robert S.
Kerr Environmental Research Lab of Ada, Oklahoma for their financial support
and to Mr. Bert Bledsoe for his exceptional patience, administrative skills
and moral support during this research effort.
To the Muskegon County Board of Public Works for their continued dedication
to the goals of a cleaner environment as demonstrated by their committment
to the land treatment concept and their financial support for further
research.
And to our secretaries, Bertha and Diane, for their efforts in producing the
numerous drafts which have lead to this final product.
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SECTION 1
INTRODUCTION
The Muskegon County Wastewater Management System began operation in 1973 as
a regional land treatment system for Muskegon County, Michigan. The system
is currently the largest land treatment works in the United States and
consists of a regional collection network, treatment facility, and farm opera-
tion designed for reclamation of the nutrient value of the wastewater for
agricultural irrigation and ultimate renovation of polluted waters to produce
a high quality effluent. Decades of industrial and municipal pollution of
the lakes in Muskegon County by the discharge of wastewater have created an
adverse situation in terms of resource management, economic development, and
overall quality of life in the County. Faced with these problems, the County
evaluated numerous alternatives for wastewater treatment and finally chose an
innovative, regional, land treatment system as the solution for its water
quality problems. The treatment system first operates by collection of re-
gional municipal, industrial wastewater and its transportation to an inland,
treatment works. All wastewater was previously discharged directly or in-
directly to river and lake systems within the County. After collection, the
wastewater is treated by aeration and impoundment before being used as water
for agricultural irrigation. The soil acts as a "living filter" for purifi-
ing the treated water, while the nutrient value is reclaimed by crops in the
largest farming operation in the County. With this system, a very high
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quality effluent is produced. In addition, the sale of crops from farming
operations provides a significant revenue source for the system to offset
operational costs, thereby reducing the ultimate cost for treatment to the
users.
Numerous research efforts by the United States Environmental Protection
Agency, the University of Michigan, Michigan State University, the Michigan
Department of Natural Resources, and the County of Muskegon have examined
the effects of the land treatment system on the site and also the impact on
the entire region. These studies have been limited in scope to classical
parameters such as nutrients and trace metals in the study of lake and
stream water quality, water-soil-crop interactions, and treatment efficiency.
All studies to date have shown the treatment system is providing high
quality, cost effective wastewater treatment to the area*, while at the same
time, creating an acceptable environment for recreational usage and indus-
trial development of the natural resources in the County.
Within the last decade, considerable emphasis on a national level concerning
toxic wastes and their effect on the environment has created renewed in-
terest in the Muskegon System. Over 60% of the influent to the treatment
work originates from sources typically industrial from pulp and paper,
chemical, and general manufacturing operations in the County. The Robert S.
Kerr Environmental Research Laboratory in 1977 conducted a preliminary
survey of toxic pollutants in the System and identified 56 chemicals,
including priority pollutants in the influent to the treatment works (1).
This information promoted this present investigation to study the fate of
* The 1982 User's fee for operation and maintenance is 25.4 cents/1,000
gallons and the debt retirement was an additional 4.5 cents/1,000 gallons.
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these and other organic chemicals in the Muskegon System. The objectives of
this study are as follows:
1) The qualitative and quantitative identification of the organic chemicals
that enter the system.
2) Defining the variability of organic chemicals in the treatment works
over a two year period with emphasis on seasonal cycles and treatment
unit processes.
3) Determine the ultimate fate of organic chemicals in the System and de-
fining any potential environmental impact.
4) Suggest improvements in wastewater pretreatment, design criteria and
operational modes in land application sites which are effective in
treating various organic chemicals.
The information from the study will be used to not only document the effici-
ency of land treatment for hazardous waste management, but also for local
industrial regulatory programs and the ultimate management of the treatment
system. The results of this study can also have a dramatic impact on local
industries by saving major capital investments and continued O&M costs for
maintaining elaborate pretreatment systems if the land application system
is effective in removing organic pollutants.
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SECTION 2
SUMMARY AND CONCLUSIONS
The results of the study show that the Muskegon County Wastewater Management
System is very effective in treating a variety of chemicals and industrial
wastes by utilizing extended aeration, lagoon impoundment, and spray irriga-
tion. Almost 150 chemicals have been identified in the plant influent
and traced through the various treatment processes. Volatile solvent con-
centrations in the influent range from low mg/1 levels to trace (1-50 i*g/l)
amounts of phenols, amines, and aromatic hydrocarbons.
Extended aeration removes over 90% of most of these chemicals by volatiliza-
tion, sedimentation into the sludge and biological breakdown. The concen-
trations increase from low yg/1 influent levels to mid range mg/1 levels in
the sludge for 3,3'-dichlorobenzidine, 2-chloroaniline, alkyl benzenes, and
2,4'-diamino-3,3'-dichlorobiphenyl. Lagoon impoundment of aeration cell
effluent further removes the organic chemicals by additional volatilization,
metabolism, sedimentation, and photo oxidation. Due to the pretreatment
steps prior to irrigation, a majority of the influent chemicals have been
reduced to non-detectable levels in the liquid, with 99%+ removal of the
remaining residuals.
The irrigated water, when percolated through the soil profile and collected
as drain tile effluent is found to contain sporatic low concentration (1
yg/1) levels of chloroform, 1,2-dichloroethane, and phthalate esters. These
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chemicals are not detected in the actual discharge waters (NPDES #001 and
#002). In addition, the soils do not exhibit any significant accumulation
of organic chemicals after seven years of irrigation activities nor has any
contamination been detected in the corn crop.
Two chemicals, 2-chloroaniline and 1,2-dichloroethane have been detected in
the lagoon seepage waters. The levels have significantly declined during
the study period and average 2 ttg/1 in recent samples. Because these chem-
icals are related to past and present storage lagoon concentrations, it be-
comes imperative to manage the levels in the lagoons and influent concentra-
tions to minimize survival of chemicals in the seepage waters. Since both
chemicals are removed by more than 98% by extended aeration and impoundment,
then by minimizing at the industrial source, the discharge in the seepage
waters can be eliminated. Since this research has commenced, and with the
help of its findings, the County has passed an amendment to its sewer use
ordinance minimizing certain toxic compound discharges into the system. The
impact of this minimization requirement or "pretreatment" on local industry
has been very slight with only two industries affected. Of these two indus-
tries one had to reduce the loading of a single compound while the second
required more extensive pretreatment due to a State DNR litigation agree-
ment.
The feasibility of sludge application is also investigated as part of this
study. This phase is currently under investigation with results expected in
a later report. In order to minimize any long-term effects from continued
application of sludges containing organic chemicals, compound accumulating
in the sludge also need to be controlled at the industrial sources.
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SECTION 3
RECOMMENDATIONS
The County has identified two areas from the study that require management
changes to maintain the integrity of the treatment works and decrease the
possibility of environmental discharge of chemicals. These areas are lagoon
seepage and sludge concentration. The lagoon seepage question is two-fold,
first, as it relates to the interception ditches, and second, the northwest
corner of the storage lagoons.
In February 1981, the County issued management guidelines, limiting the dis-
charge of organic chemicals by industrial users to the system. Utilizing the
extensive data base of industrial loadings and treatment performance data
collected by the County laboratory during the study period, limits were
established for chemicals that persist by concentrating in the sludge or that
survive treatment and thus have a potential for discharge to the environment.
The limits will be effective January 31, 1982 and should insure future oper-
ation without lagoon seepage or sludge disposal questions being raised. In
addition, if monitoring indicates any significant trends which suggest that
present limits need to be revised or new compounds need to be controlled,
the necessary action will be taken by the County through the powers outlined
in the Amendments to Exhibit D (County Wastewater Ordinance).
Lagoon seepage in the northwest corner of the storage lagoon system will be
examined in the 201 Facilities Expansion Plan hydrogeological study. When
the groundwater dynamics of this area are defined, management strategies will
6
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be developed to control or contain any migration from the storage lagoons.
In examination of the sludge accumulation question, results of lysimeter
sludge application studies indicate that the organic chemicals in the sludge
will not leach through the soil column and that they will undergo some bio-
degradation. A small field pilot study is being proposed for spring of 1982.
If results are favorable, the sludge may be land applied on a larger scale.
\
In order to prevent any future questions from arising concerning sludge
management, chemicals accumulating in the sludge will be limited as part of
the industrial effluent guidelines. These limits are again subject to the
results of future monitoring programs by the County.
The studies that were undertaken at Muskegon will help understand the
behavior of many of the man-made organics at treatment facilities employing
extended aeration, lagoon impoundment and spray irrigation. Other than
volatilization, the two major removal mechanisms include detoxification by
bacteria and photo-oxidation by solar radiation. The mechanism of bacterial
action should be investigated further with a goal of isolating the working
bacteria.
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SECTION 4
DESIGN FEATURES OF THE WASTEWATER SYSTEM
The Muskegon County Wastewater Management System employs extended aeration,
lagoon impoundment, and spray irrigation to treat an average of 33 million
gallons per day (MGD), 125 thousand cubic meters per day (TCMD) of municipal
and industrial wastewater. The System, operates as a regional treatment
facility, serving 13 municipalities and over 23 major industries (including
six chemical-related industries). Over 70% of the incoming wastewater can
be attributed to industrial discharge.
The System is located on 11,000 acres (4,455 hectares) of sandy, unproductive
land in the northeast corner of Muskegon County. Wastewater is collected by
six pumping stations and delivered to a central pumping station with a maxi-
mum capacity of 56,000 gallons per minute (212 cubic meters/minute). The
combined wastewater is pumped through approximately 11 miles (17.2 kilometers)
of reinforced concrete pipe (a 66-inch diameter force main) to the Wastewater
System.
Initial treatment of the wastewater is first provided by three extended aera-
tion cells. Each cell has a surface area of eight acres (3.24 hectares) and
a holding capacity of 42 MG (159 thousand cubic meters}. The cells are
lined with soil-cement and contain 12 mechanical floating aerators and six
stationary platform mixers, with a total combined horsepower of 1020. Opera-
tion of the extended aeration cells typically involves utilizing two cells
in series with a holding time of 2.5 days. The remaining cell is left
8
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empty to accomodate future flows or, as an emergency treatment basin, to iso-
late wastewater if an industrial spill of hazardous waste materials occurs.
In the cells, biological oxidation takes place, along with some sedimentation
of suspended solids and anaerobic digestion of the bottom material. BOD5
removals for 1980 averaged 68% while suspended solids removed averaged 48%.
After aeration, the treated wastewater passes down a concrete spillway to
the storage lagoon system. The Wastewater System utilizes two, 850-acre
(344 Hectares) lagoons with a total combined storage capacity of 5.1 billion
gallons (19.3 million cubic meters). The lagoons are encircled by 15 feet
(4.6 meters) high dikes with 200 feet (61 meters) as their base width. A
400 ft (122 meters) wide border strip of the lagoon is lined with 8 inches
(20 centimeters) of compacted clay, with the remaining bottom area left as
native soil. The dike, together with clay border strips, provides 600 ft
of filtration for the seepage water. This water is then collected by an
interception ditch system surrounding the lagoons. Interception ditch water
may then be pumped back into the storage lagoons, or if NPDES water quality
criteria are met, it may be discharged to receiving streams. The lagoon
system provides further treatment of the wastewater by sedimentation of
solids, and biological treatment by aerobic oxidation in the warmer months,
and anaerobic metabolism under ice cover. In addition, photochemical reac-
tions can take place to degrade organic chemicals and to cause die-off of
bacterial agents. Examination of overall treatment efficiency at this point
reveals about 95% of the 6005 and 93% of the suspended solids are removed by
lagoon impoundment and extended aeration.
The storage lagoons are operated by alternately filling each lagoon in the
winter months. During irrigation season, the lagoon with the highest water
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quality (the one currently not being filled) is discharged into an outlet
lagoon with about 14 acres surface area (.5.67 hectares). The outlet struc-
ture is constructed similar to the aeration cells, with a depth of 12 feet
(3.66 meters). This water is then discharged into two ditches which feed
the irrigation pumping stations. The lagoons may be operated in series, in
parallel, or alternately filled during irrigation season. The lagoons have
a winter storage capacity to impound five months influent flow at 42 MGD (159
TCMD). The spray irrigation part of the treatment system is carried out on
5,500 acres (2,327 hectares) of specially-drained farm land. Irrigation vol-
ume is related to the capacity of the soil to act as a filter for the water.
About 85% of the soil types on the project fall into the categories of Rubi-
con, Roscommon, and Au Gres sand, all of which are well drained. The remain-
ing soils are clays (Granby and Nester-Tonkey) which are poorly drained.
Water is applied to the land by 54 center-pivot irrigation rigs at a rate of
2.5-4 inches (6.4-10.2 cm) per week. The rigs move in a circular path with a
radii of 730 to 1,350 feet (223-411 meters) and make one revolution in one to
seven days. End spray guns are used in many of the rigs to expand the irriga-
tion area. Water is supplied to the irrigation system by two large pumping
stations. The north station has ten 250 horsepower (188 KW). pumps wbile the
south station has four 100 horsepower (75 KW) and seven 250 horsepower (188
KW) pumps. The irrigation fields are drained by an elaborate network of per-
forated nylon-socked tiles and a series of collection ditches. The drainage
network consists of 70 miles (114 kilometers) of drain tile, 19 miles (31
kilometers) of drain pipe, and 10 miles (16 kilometers) of ditches. This
system acts to control the groundwater table, direct water flow, and to re-
collect the renovated Water and thus preventing water logging of the land.
10
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Because all irrigated water is intercepted by the drain tiles, the Wastewater
System does not operate as a discharge to groundwater, thus protecting usable
aquifiers from potential contamination. Over 300 monitoring wells have been
installed to ensure the protection of groundwater quality and to study the
efficiency of irrigation operations.
Corn is grown in the irrigation fields as both a cash crop and a source for
removal of nutrients. The crop, along with the adsorption capacity of the
soil, acts to remove nutrients as fertilizer. In addition, the soil acts as
a media for bacterial degradation of organic chemicals, which results in a
reduction in BOD5- Tnis phase of the treatment cycle acts as a final polish
to renovate the quality of the wastewater and to reclaim the nutrients as a
usable fertilizer. Considering the sandy soils discussed earlier, the land,
in its original state, would be highly unproductive for farming operations.
With irrigation, however, the System continues to yield 50+ bushels per acre,
43.5 hectoliters per hectare (near the County average for productive farm land)
of corn. This amounts to about one million dollars of revenue from the sale
of the crop, which can be applied to reduce operational costs.
The collected water from the drain tiles and lagoon seepage is then discharg-
ed to the north via an outfall to Mosquito Creek. Water from the fields on
the southern part of the project is discharged to Black Creek. These streams
flow eventually to Lake Michigan through inland lakes. The project has oper-
ated since May, 1973, and has continuously produced a high quality effluent.
Average water quality parameters for 1980 are given in Table 1.
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TABLE 1. TREATMENT PERFORMANCE 1980
BOD5
Suspended Solids
Total Phosphorus (P)
Ammonia (N)
Influent (mg/1 )
242
245
2.14
7.68
North Outfall 001
Effluent (mg/1)
2.6
6.5
0.11
0.96
The high level of 8005 and total phosphorus removal was provided at a cost
to the users of $254 per million gallons. A more detailed discussion of the
treatment facility and its operation was presented in several earlier progress
reports (2 & 3).
12
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SECTION 5
SAMPLING
Locations and Frequency
Two separate sampling regimes were employed during the study. The first year
of the study, December 1, 1979-November 30, 1980, was designed to provide in-
tensive data concerning treatment performance and to identify any potential
problem areas. The second year program, December 1, 1980-November 30, 1981,
was designed to continue treatment performance monitoring, and also to study
soil accumulation and lagoon seepage in a detailed manner.
Sampling stations, sample type, and frequency for the first year are given
in Table 2. Similar information for the second year is given in Table 3.
Figure 1 shows the location of the various sampling stations monitored
during the study. Figure 2 gives the location of the additional lagoon
seepage monitoring wells on the dike walls. These wells were added for the
special lagoon seepage study.
Collection and Preservation
All water samples collected as two-week composites were taken as daily, 300
ml grab samples in a solvent-rinsed BOD bottle, dried at 100°C for six hours
prior to use. The sample was then split into two portions: Ij 40 ml aliquot
stored in a teflon-faced, screw-capped glass vial for volatile analysis, and
2) 260 ml aliquot stored in a one-gallon amber glass bottle for semi-volatile
analysis. All volatile analysis samples were stored in separate glass vials
13
-------
TABLE 2
DECEMBER 1979 - NOVEMBER 1980
SAMPLING PROGRAM
Station
Sample Type
Frequency
Influent
Spillway (biological
treatment effluent)
South Interception Ditch
(NPDES #000)
Drain Tile Discharge ill
Drain Tile Discharge #19
Drain Tile Discharge #48
North Outfall, SW-05
(NPDES #001)
South Outfall, SW-34
(NPDES #002)
Outlet Lagoon
East Storage Lagoon
West Storage Lagoon
Aeration Cell #2 Sludge
East Storage Lagoon Sludge
2-Week Composite Monthly, 12-79 through 4-80; then biweekly 5-80^ 11-80
2-Week Composite Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
2-Week Composite Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
Monthly, 12-79 through 4-80; then biweekly 5-80-.11-80
Monthly, 12-79 through 4-80; then biweekly 5-80- Jl-80
Monthly, 12-79 through 4-80; then biweekly 5-80 - 11-80
Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
2-Week Composite Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
2-Week Composite Bimonthly during irrigation
4-Point Composite Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
4-Point Composite Monthly, 12-79 through 4-80; then biweekly 5-80- 11-80
Grab Bimonthly 6-80 through 11-80
Grab Bimonthly 6-80 through 11-80
-------
TABLE 2
DECEMBER 1979 - NOVEMBER 1980
SAMPLING PROGRAM
(CONTINUED)
Station
Sample Type
Frequency
West Storage Lagoon Sludge Grab
Wells: USGS2-6, LS-34C2, Grab
LS-34C3, LS-33B2,
LS-31B2, 17A, LS-1B2,
LS-2B2, LS-3B2,
LS-4B2, LS-5B2,
LS-6B2
Soils: Circle 11, 19, and 48 Composite as 0' -
I1, l'-2', &
2'-3' intervals
Corn: 6 Circles on project
plus 3 controls off
project
Composite
Biweekly 6-80 to 11-80
2 Wells per month on a rotating schedule
Annual
Annual
-------
TABLE 3
DECEMBER 1980 - NOVEMBER 1981
SAMPLING PROGRAM
Station
Sample Type
Frequency
Influent
Spillway
South Interception Ditch
North Interception Ditch
Drain Tile #11
Drain Tile #19
Drain Tile #48
North Outfall
South Outfall
East Storage Lagoon
West Storage Lagoon
Outlet Lagoon
Aeration Cell #2 Sludge
East Storage Lagoon
Sludge
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
2-Week Composite
4-Point Composite
4-Point Composite
2-Week Composite
Grab
Grab
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly during irrigation
Quarterly
Quarterly
-------
Table 3
DECEMBER 1980 - NOVEMBER 1981
SAMPLING PROGRAM
(CONTINUED)
Station
Sample Type
Frequency
West Storage Lagoon
Sludge
Wells: (See Table 1)
Grab
Grab
Soils: Circle 11, 19, 48 Composite at O'-l1, I1-2', &
2'-3' intervals
Corn: 3 Circles on
project plus 3
controls off
project Composite
Special Lagoon Seepage
Wells:
Al-3, Bl-3, Cl-3, Dl-3,
1-6B2, 34C2 Grab
Air Samples: Cell II Composite
Quarterly
1 well/month on a rotating schedule
Irrigation
Annual
Monthly 6-81 to 11-81
Daily for 2 Weeks
-------
COUNTY LINE
IRRIGATION
AREAS
AERATED
TREATMENT
CELLS
MAPLE
ISLAND
RD
MOOR-
LAND
RD
APPLE AVE
-- DRAINAGE DITCHES
-* MAIN DRAIN PIPES
INTERCEPTION DITCHES
A PUMPING STATIONS
HUM INFLUENT PIPE
FIGURE I
SAMPLING LOCATIONS
SWANSON
RD
1&
-------
NEW ORGANIC MONITERING WELLS
GROUP "A"
N
SULLIVAN
RD
IENSLEY
RD
SWANSON
RD
FIGURE 2
-------
1 - -
^ ~»~«
9
I2AC
MAPLE
ISLAND/*
RD
-»
-^
-»
*
13)
o '
o
o
0
o
o
0
o
o i
o
-o-
«*>;
*n
31 32 33
1 I*
o o o
tA
1 1^-1
34C *-i
STORAGE
^*>v^
1 r o o *T^«
tW£U
1 t
14 18 2
WHITE RD->
-v AtTDATCn PCI 1 O
LAGOONS \.
2SSS2SSSS
t t f
.2 26 30
'A' WELL
J
>
N
X
I
J
MOORLAND
RD
*S
/
APPLE AVE
o 'B' WELL CLUSTER
'C' WELL CLUSTER
FIGURE 3 - LAGOON SEEPAGE WELLS
-------
for each day. Semi-valatrle'ahaTysi's samples ''were" composited -da-fly into 'the :
same bottle by station. Storage lagoon samples were collected by compositing
four 500 ml samples, taken at the middle of each dike wall in a gallon amber
glass bottle. A volatile sample was taken at each station also. Well
samples were collected by either bailing the well with a galvanized bailer,
or by pumping with Aquamaster 3 HP model 5306 centrifugal pumps. Upon col-
lection, the samples were transferred to a one-gallon amber glass bottle and
a 40-ml teflon-faced, screw-capped vial for each station. All water samples
were stored at 4°C prior to analysis.
Sludge samples were collected using a ponar dredge and stored in glass jars
with teflon liners. Study samples were stored at 4°C prior to analysis.
Soil samples were collected using a metal coring device. Ten locations in
each circle were cored and composited into one sample. The soil was trans-
ferred to a glass jar with a teflon liner and stored at 4 C prior to analysis.
Corn samples were collected as dried grain (^15% moisture) and stored in
glass jars with teflon caps. The corn was stored at 4°C prior to analysis.
21
-------
SECTION 6
RESULTS AND DISCUSSION
Results for the sampling period December 1, 1979 to November 30, 1981 are
presented in Appendix A. Results are grouped according to month. Compounds
not reported are non-detectable at the detection limits listed in the Methods
section. Quality control data is given in Appendix B. All the analytical
procedures were adapted from EPA protocol. A complete description of these
is in Appendix D.
The results presented detail the systems performance during an 18-month
period. The following cycles are studied:
Storage 12-79 to 4-80
Irrigation 5-80 to 11-80
Storage 12-80 to 4-81
Irrigation 4-81 to 11-81
Each phase of the system (influent composition, extended aeration treatment,
long term impoundment, sludge application irrigation, discharges and wells)
will be discussed in terms of chemical composition, treatment efficiency,
and general environmental impact. Lagoon seepage is also discussed in detail
as this area is subject to intensive study during the second year. The data
not only shows the effects of present loadings, but also historical contri-
butions. This is especially true for soil, sludge, and lagoon seepage data.
Because the historical component cannot be quantified, interpretations and
conclusions drawn from present data may be changed if future observation
results in new information.
22
-------
A section concerning quality control data is also included.' The first five
months of the study contain a large portion of quality control analyses to
establish the validity of the data and to aid in the interpretation of the
results. Utilizing a series of spiked and duplicate samples, the recovery
and precision of the results are defined according to the various sample
matrices.
23
-------
Influent Composition
The influent data collected over the study period shows a complex mixture
of chemicals entering the wastewater system. Chemical types include
chlorinated and aromatic solvents, aromatic amines, chlorinated benzenes,
polynuclear aromatic hydrocarbons, sulfides and phenols. The wide varia-
tion in loadings and compound types can be attributed to the diversity of
industry utilizing the metro system (6 chemical, 1 pulp and paper, 20+
manufacturing) and their production campaigns. A review of industrial
monitoring data collected to date indicates the grouping of chemicals and
industrial sources shown in Table 4.
TABLE 4. INDUSTRIAL SOURCES OF CHEMICALS
Industrial Category Chemical
Pulp and Paper Sulfides, Halomethanes,
Chlorinated Phenols (di & tri-
chloro), Substituted Phenols
(Vanillin, etc.), Substituted
Naphthalenes and Benzenes
Chemical Aromatic Amines, Solvents,
Substituted Phenols,
Chlorinated Benzenes, Naphtha-
lenes, Substituted Benzenes
Manufacturing Solvents, Polynuclear
Aromatic Hydrocarbons
Loading of compounds from the pulp and paper industry are relatively
consistent, as their process discharge does not vary greatly on a daily
basis. In contrast, loadings of compounds from the chemical industries
may vary over several orders of magnitude.
A total of 50 priority pollutants have been identified as entering the
24
-------
wastewater system,- along with about 97 other organic chemicals. Tables .5
and 6 list the chemicals in these two groups and also give the average
influent concentrations during the two-year study period.
TABLE 5. PRIORITY POLLUTANTS FOUND IN INFLUENT
SAMPLES DURING 1980 AND 1981
Average
Priority Pollutants Concentration (yg/1)
Acenaphthene <1
Acenaphthylene <1
Anthracene <1
Benzene 153
Benzo (a) anthracene <1
Benzo (a) pyrene <1
Bis(2-ethylhexyl)phthalate 23
Bromodichloromethane 2
Butyl benzyl phthalate 1
Chlorobenzene 23
2-Chlorophenol 2
Chlorophenyl ether <1
Chloroethane <1
Chloroform 747
4-Chloro-3-methylphenol 3
2-Chloronaphthalene <1
Chrysene <1
1 ,2-Dichlorobenzene 4
1,4-Dichlorobenzene 1
3,3'-Dichlorobenzidine 23
1,1-Dichloroethane 3
1,1-Dichloroethene <1
V,2-Dichloroethane 730
2,4-Dichlorophenol 2
Diethyl phthalate <1
2,4-Dimethylphenol 1
Dimethyl phthalate 4
Di-n-butyl phthalate <1
Ethyl benzene 14
Fluoranthene 18
Fluorene <1
Methyl chloride <1
Methylene chloride 43
Naphthalene 4
Pentachlorophenol <1
Phenahthrene 1 . ,.
(continued)
25
-------
TABLE 5. (Continued)
Average
Priority Pollutants Concentration (ug/1)
Phenol 5
Pyrene < 1
Tetrachloroethylene 361
Toluene 1,964
Trans-l,2-dichloroethene 6
Trichlorobenzene < 1
1,1,1-Trichloroethane 93
Trichloroethylene 36
2,4,6-Trichlorophenol 2
Vinyl chloride 1
26
-------
TABLE 6. ADDITIONAL'ORGANIC CHEMICALS FOUND IN INFLUENT
SAMPLES DURING 1980 AND 1981
Average
Compound Concentration (yg/1)
Acetanilide 5
Acetone 2664
Alkyl substituted benzenes 53
Aniline 24
Benzaldehyde <1
Benzyl alcohol <1
Butyl benzene <1
Carbon disulfide <1
2-Chloroaniline 567
2-Chlorohydroquinone <1
Chioromethylbenzene <1
Cresol 10
2,4'-Diamino-3,3'-dichlorobiphenyl 118
2,2'-Dichloroazobenzene 38
1,4-Diethoxybenzene <1
Diethoxychlorobenzene 21
Dihydroxyphenylethanone <1
Dimethoxybenzene 1
3,4-Dimethoxyphenol 6
Dimethyl benzaldehyde 2
Dimethyl phenol <1
Dimethyl disulfide 180
Dimethyl naphthalenes 14
Dimethyl oxetane <1
1,4-Dioxane <1
2-Ethoxypropane 3
Ethyl aniline 2
Ethyl phenol <1
Acetovanillone 16
Isopropylidene dioxyphenol 8
Methanethiol <1
2-Methoxyaniline <1
2-Methoxyphenol 40
Methyl aniline 37
Methyl naphthalenes 8
Naphthol 1
N,N-Dimethylaniline 5
N-Phenylaniline <1
Phenylethanone *=!
Phthalic acid <1
2-Propanol 842
Substituted benzoic acids 1
(Continued)
27
-------
' 'TABLE 6.' (Continued) '
Average
Compound Concentration (vg/1)
Substituted benzaldehyde 2
Substituted vanillin <1
Thiobismethane 171
Tributyl phosphate 30
Diisopropoxychlorobenzene 4
Trimethyl naphthalenes 11
Trimethyl phenanthrenes <1
Vanillin 6
Xylene <1
28
-------
Of the priority pollutants the volatile compounds-benzene (153 yg/1), chloro-^
form (747 yg/1), 1,2-dichloroethane (730 yg/1), tetrachloroethylene (361
yg/1), toluene (1,964 yg/1), 1,1,1-trichloroethane (93 yg/1) comprise the
largest loadings to the treatment works. These materials all originate
from industrial usage (parts washing, paint, etc.) or chemical manufacturing.
The only semi-volatile priority pollutants comprising significant average
loadings are bis(2-ethylhexyl)phthalate (23 yg/1), 3,3'-dichlorobenzidine
(23 yg/1) and fluoranthene (18 yg/1). The remaing semi-volatile compounds
average less than 10 yg/1.
Of the additional organic chemicals received, acetone (2,264 yg/1), 2-chloro-
aniline (567 yg/1), 2,4'-diamino-3,3'-dichlorobiphenyl (118 yg/1), dimethyl
disulfide (180 yg/1), 2-propanol (842 yg/1), and thiobismethane (171 yg/1)
are received in high quantitites. The sulfides originate from the pulp and
paper industry while the remaing compounds are discharged from chemical
manufacturers. The compound, 2,4'-diamino-3,3'-dichlorobiphenyl could not
be identified by mass spectral interpretation alone, as its spectrum is
similar to 3,3'-dichlorobenzidine. NMR analysis, however, defined the
structure as a diphenylene derivative formed by the benzidine rearrangement
in the industrial synthesis of dichlorobenzidine.
Overall, about 80% of the chemicals detected are at levels of less than 50
yg/1. The highest concentrations detected for any of the chemicals are 18
mg/1 of acetone in the June, 1981 composite and 11 mg/1 in the August, 1981
composite. No other levels in excess of 10 mg/1 are encountered during the
two-year study period. Numerous other compounds including aliphatic hydro-
carbons, esters, alcohols, and terpene-related derivatives are frequently
29
-------
detected; however,.for the purposes of the study and because the low environ-
mental significance of the previous materials, only the compounds listed in
Tables 5 and 6 were followed in the treatment system.
Considerable differences in concentration ranges are evident in the data.
Compounds .detected over 50 yg/1 are given in Table 7. These materials
amount to about 10% of the chemicals studied.
TABLE 7. INFLUENT CHEMICALS DETECTED AT LEVELS
OVER 50 ug/1 ON THE AVERAGE
Chloroform* Thiobismethane
1,2-Dichloroethane* Dimethyl disulfide
Benzene 2-Chloroaniline
Tetrachloroethylene* Acetone
Toluene 2-Propanol
1,1,1-Trichloroethane* Alkyl substituted
Methylene chloride* benzenes
2,4-Diamino-3,3'-dichloro-
* EPA Priority Pollutant biphenyl
Table 8 gives the chemicals detected at levels between 500 yg/J and 10,000
yg/1. This group corresponds to about 5% of the total number of influent
chemicals examined.
TABLE 8. INFLUENT CHEMICALS DETECTED AT LEVELS
BETWEEN 500 ug/1 AND 10,000 yg/1 ON THE AVERAGE
1,2-Dichloroethane* Toluene*
Chloroform* Acetone
2-Chloroaniline 2-Propanol
* EPA Priority Pollutant
While Tables 7 and 8 classify the compounds on the basis of their averages,
any individual sample may contain fewer or larger number of compounds in
each category. Using the March, 1981 composite as an example, the following
30
-------
groupings can be developed:
59 total chemicals
14 chemicals between 50 yg/1 and 1,000 yg/1
45 chemicals less than 50 yg/1
Table 9 presents the March data in total form.
TABLE 9 . MARCH, 1981, INFLUENT DATA
Priority Pollutants Concentration (yg/1)
Methylene Chloride 70
1,1-Dichloroethane 3
Trans-l,2-dichloroethene 9
Chloroform 541
1,2-Dichloroethane 391
1,1,1-Trichloroethane 62
Bromodichloromethane 4
Trichloroethene 13
Benzene 181
Tetrachloroethene 500
Chlorobenzene 5
Toluene 562
2-Chlorophenol 1
Phenol 4
2,4-Dich.lorophenol 1
2,4,6-Trichlorophenol 2
4-Chloro-m-cresol 1
1,4-Dichlorobenzene 2
1,2-Dichlorobenzene 7
Trichlorobenzene 2
Naphthalene 6
2-Chloronaphthalene 1
Dimethyl phthalate 2
Acenaphthylene 1
Acenaphthene 1
Diethyl phthalate 1
Fluorene 1
Chiorophenylether 2
Anthracene 2
Phenanthrene 3
Di-n-butyl phthalate 3
Pyrene 2
Fluoranthene 3
Butyl benzyl phthalate 13
Benzo(a)anthracene 2
Benzo(a)crysene 2
(Continued)
31
-------
TABLE 9 (Continued)
Priority Pollutants Concentration (yg/1)
Di(ethylhexyl)phthalate 351
Acetone 181
Thiobismethane 141
2-Propanol 721
Dimethyl disulfide 78
2-Methoxyphenol 55
Cresol 7
3,4-Dimethoxyphenol 41
Dihydroxyphenylethanone 3
Ethyl phenol 1
Isopropylidene dioxyphenol 2
Vanillin 2
Acetovanillone 90
Aniline 120
2-Chloroaniline 770
Methyl naphthalene 12
Di-methylnaphthalene 17
Trimethylnaphthalene 18
Tributyl phosphate 15
Substituted benzene 38
Dichloroazobenzene 24
Dichlorobenzidene isomer > 291
Diethoxychlorobenzene 3
The overall variability illustrated here again relates back to the industrial
usage breakdown discussed earlier. It is a combination of batch-to-batch
process variation and the change in production campaigns that contribute to
the influent concentration levels. In addition, the overall dilution of
chemical industry effluent in the system acts to prevent adverse impacts
from spot concentration variations over several orders of magnitude. Indi-
vidual flows for the six industries range from 0.3 MGD to 1.2 MGD. Given
the total flow of 33 MGD to the wastewater system, a 30-fold dilution will
take place before an effluent reaches the treatment works.
32
-------
In summary, the influent of the Muskegon County Wastewater Management System
contains a large number of potentially toxic chemicals. Concentrations are
low, however, as over 80% of the chemicals are less than 50 yg/1. It should
also be noted that highly resistant chemicals such as PCB's and certain
pesticides are absent from the influent.
Extended Aeration Treatment
The incoming wastewater is first subjected to an extended-aeration (approxi-
mately three days) treatment, as discussed earlier. This consists of two
8-acre (42 MG) aeration cells operated in series. Comparison of the spill-
way values as the water leaves the aeration cell illustrates the effects
of this treatment.
Average concentrations for priority pollutants and the additional organic
chemicals are given in Tables 10 and 11. Overall present removal data are
also included.
TABLE 10. PRIORITY POLLUTANTS FOUND IN THE SPILLWAY EFFLUENT
AND THEIR REMOVAL EFFICIENCIES DURING 1980 AND 1981
Average %
Priority Pollutants Concentration (yg/1) Removal
Acenaphthene
Acenaphthylene
Anthracene
Benzene 11
Benzo(a)anthracene
Benzo(a)pyrene
Bis(2-ethylhexyl) phthal ate 9
Bromodichloromethane
Butyl benzyl phthal ate
Chlorobenzene <1
2-Chlorophenol <1
Chi orophenyl ether
Chloroethane
Chloroform 86
4-Chloro-3-methyl phenol
100
100
100
93
100
100
61
100
100
99+
99+
100
100
89
100
(Continued)
33
-------
TABLE 10 (Continued)
Average Average 5
Priority Pollutants Concentration (yg/1) Removal
2-Chloronaphthalene
Chrysene
1,2-Dichloro benzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2,4-Dichlorophenol
Di ethyl phthalate
2, 4-Dimethyl phenol
Dimethyl phthalate
Di-n-butyl phthalate
Ethyl benzene
Fluoranthene
Fluorene
Methyl chloride
Methylene chloride
Naphthalene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Tetrachl oroethyl ene
Toluene
Trans-l,2-dichl oroethyl ene
Trichlorobenzene
1,1, 1-Trichl oroethane
Tri chl oroethyl ene
2,4,6-Trichlorophenol
Vinyl chloride
TABLE 11. ADDITIONAL ORGANIC CHEMICALS
AND THEIR REMOVAL EFFICIENCIES
_
< 1
< 1
_
6
<1
-
164
<1
-
-
-
<1
<1
<1
-
-
31
<1
-
<1
5
-
31
34
<1
-
9
2
1
FOUND IN
100
99+
99+
100
74
99+
100
78
99+
100
100
100
99+
99+
99+
100
100
28
99+
100
99+
0
100
91
98
99+
100
90
94
50
100
SPILLWAY EFFLUENT
DURING 1980 AND 1981
Compound Concentration
Acetanilide
Acetone
< 1
1258
Average %
(yg/1) Removal
99+
53
(Continued)
34
-------
TABLE 11. (Continued)
Average %
Compound Concentration (vg/1) Removal
Alkyl substituted benzenes
Aniline
Benzaldehyde
Benzyl alcohol
Butyl benzene
Carbon disulfide
2-Chloroaniline
Chi oromethyl benzene
Cresol
2,4'-Diamino-3,3'-dichlorobipheny1
2,2-Dichloroazobenzene
1,4-Diethoxybenzene
Diethoxychlorobenzene
Di hydroxyphenyl ethanone
Dimethoxybenzene
3,4-Dimethoxyphenol
3, 4-Dimethyl phenol
Dimethyl benzaldehyde
Dimethoxy phenol
Dimethyl disulfide
Dimethyl naphthalenes
Dimethyl oxetane
1,4-Dioxane
N-Ethylaniline
2-Ethoxypropane
Ethyl aniline
Ethyl phenol
Acetovanillone
Isopropylidene dioxyphenol
2-Methoxyaniline
2-Methoxyphenol
Methyl aniline
Methyl naphthalenes
N ,N-Dimethyl ani 1 i ne
N-Phenyl aniline
Phenyl ethanone
Phthalic acid
2-Propanol
Substituted benzaldehyde
Substituted vanillin
Thiobismethane
Tri butyl phosphate
Di i sopropoxychl orobenzene
19
1
< 1
< 1
-
-
92
-
1
52
18
< 1
10
< 1
< 1
2
< 1
< 1
-
50
4
-
-
-
< 1
< 1
-
1
4
< 1
3
13
2
1
-
< 1
-
589
< 1
< 1
30
12
1
64
96
99+
99+
100
100
84
100
90
56
53
99+
52
99+
99+
67
99+
99+
100
72
71
100
100
100
99+
99+
100
94
50
99+
93
65
75
80
100
99+
100
30
99+
99+
82
60
75
(Continued)
35
-------
TABLE 11 (Continued)
Average %
Compound Concentration (yg/1) Removal
Trimethyl naphthalenes 5 55
Trimethyl phenanthrenes - 100
Vanillin < 1 99+
Xylene - 100
The data show a majority of the chemicals in the influent are removed by
extended aeration treatment. Four processes may take place in this treat-
ment: loss to atmosphere by aeration of volatile materials, loss by bac-
terial metabolism of labile materials, sedimentation, and concentration
of recalcitrant materials through the system. Atmospheric loss via aeration
can be attributed to be the mechanism for removal of almost half of the
priority pollutants present as they are classed as volatile materials. On
a weekly basis, as the February, 1980 sample shows, chloroform drops from
1100 to 91 yg/l, 1,2-dichloroethane from 1900 to 500 yg/1, and benzene from
160 to 3 yg/1 from influent to spillway. Chloroform removal reported here is
consistent with levels found by the University of Cincinnati (11) as they
noted a reduction of 80 yg/1. The same study found chloroform levels over
the aeration cells to range from 100 to 200 yg/M^, which i.s far below the
OSHA threshold limit value (TLV) of 50,000 yg/M3 for an 8-hour, 5-day week.
Air samples, collected as part of the study gave similar results. The data
are given in Table 12.
36
-------
TABLE 12. RESULTS OF AIR'SAMPLING FOR VOLATILE SOLVENTS
OVER AERATION CELL II, OCTOBER, 1981
Date
10/14
10/15
10/20
10/21
10/22
Chloroform
98
85
110
65
130
Solvent (yg/M3)
1,2-Dichloroethane
72
51
63
42
81
Toluene
100
92
130
85
70
Using the average influent concentrations for these three solvents, the
pounds per day lost to the atmosphere amount to 156 for chloroform, 133 for
1,2-dichloroethane, and 467 for toluene. The loss, spread over two 8-acre
aeration cells, however, is diluted sufficiently to prevent any potential
public health problem from occurring.
Atmospheric loss via aeration probably is also the major mechanism for re-
moval of other compounds including methylene chloride, 1,1-dichloroethane,
trans-l,2-dichloroethylene, 1,1,1-trichloroethane, trichloroethylene, tetra-
chloroethylene, bromodichloromethane, chlorobenzene, and ethyl benzene as
metabolic breakdown would be very slow.* ' Thiobismethane, dimethyl
disulfide, acetone, and isopropanol could be removed by combinations of
volatilization, chemical oxidation (sulfides only), and metabolism. These
compounds may be produced in situ by metabolic routes as sulfides are
products of anaerobic digestion while alcohols and ketones are oxidative
(13)
metabolites. . These compounds also have considerable water solubility
which probably acts to reduce volatilization. This is noted by the lower
removal efficiency of each chemical (thiobismethane 82%, dimethyl disulfide
72%, acetone 53%, 2-propanol 30%). The efficient treatment of volatile
37
-------
organics is very important as 10 of the 12 compounds listed in Table 7, as
present in the influent at levels greater than 500 ug/1, are volatile. The
data shows between 89 and 100% removal of most priority pollutant influent
volatile organics by the aeration process. Such efficiency is not to be
achieved by most conventional, short-term aeration, activated-sludge type
(14)
systems. The only volatile compound not consistently averaging high
removal levels is 1,2-dichloroethane. The removal of this compound averages
78%. This material also has a water solubility of approximately 1%, which
would act to keep the chemical in solution and inhibit volatilization.
Loss via microbial metabolism can be postulated for many of the phenolic
and aniline compounds entering the system. Table 13 summarizes some of the
weekly removals observed after an extended aeration treatment.
TABLE 13'. REMOVAL EFFICIENCIES BY METABOLIC ROUTES
IN EXTENDED AERATION
Sample 2-Year Avg.
Compound Levels (ug/1) % Removal Date Removal
2-Methoxy phenol
Methyl aniline
Aniline
Acetovanillone
Isopropylidene
dioxy phenol
78 to <1
320 to 48
5 to <1
61 to <1
30 to 8
100
85
100
100
74
3/80
6/80
2/81
1/81
1/81
93
65
96
94
50
These chemicals show no accumulation in the sludge from aeration Cell II,
and are not volatile. Any loss should, therefore, be by metabolic breakdown.
38
-------
Sludge accumulation does occur for many types of influent chemicals as shown
by the average concentration data for Cell II in Table 14. These chemicals
include the alkyl substituted benzenes (present as a homologous series cen-
tering around dodecylbenzene), naphthalenes, chlorinated aromatic amines,
and polynuclear aromatic hydrocarbons. Concentration factors for selected
compounds are given in Table 15. These values are based on averages of
influent data and sludge data..
TABLE 14. AVERAGE CONCENTRATION OF ORGANIC CHEMICALS
IN CELL II SLUDGE (ug/Kg) FOR 1980 and 1981
Priority Pollutants Average
Butyl benzyl phthalate 280
Benzo(a)anthracene 60
Bis(ethylhexyl)phthalate 4,200
1,4-Dichlorobenzene 200
1,2-Dichlorobenzene 320
Di-n-butyl phthalate 340
3,3'-Dichlorobenzidine 44,000
Fluoranthene 230
Fluorene 140
Naphthalene ' 580
Phenanthrene 810
Phenol 240
Pyrene 200
Toluene 730
Additional Organic Compounds
2-Chloroam'line 26,600
Cresol 1,100
2,2'-Dichloroazobenzene 1,400
Diethoxychlorobenzene 4,000
Dimethyl naphthalenes 9,400
2,4'-Diami no-3,3'-di chlorobi phenyl 35,000
Methyl naphthalenes 2,600
Substituted alkyl benzenes 40,000
Trimethyl naphthalenes 7,300
Tributyl phosphate 800
39
-------
TABLE 15. SELECTED SLUDGE CONCENTRATION FACTORS
FOR CHEMICALS IN CELL II SLUDGE
Avg. Sludge
Compound Cone, (yg/1)
Phenanthrene
Bis( ethyl hexyl )phthalate
3,3'-Dichlorobenzidine
2-Chloroaniline
Cresol
2,2'-Dichloroazobenzene
Diethoxychlorobenzene
2,4'-Diamino-3,3'-
dichlorobiphenyl
Alkyl substituted
benzenes
Methyl naphthalene
Dimethyl naphthalene
Trimethyl naphthalene
Naphthalene
810
4,200
44,000
26,600
1,100
1,400
4,000
35,000
40,000
2,600
9,400
7,300
580
Avg. Influent
Cone, (vig/1)
1
23
23
567
10
38
21
118
53
8
14
11
4
Cone.
Factor
810
183
1,910
47
110
37
190
300
755
325
670
663
145
Compounds with high concentration factors such as phenanthrene and naphtha-
(19}
lenes have been shown to biodegrade in an aerobic aqueous environment.
The accumulation of these compounds in the sludge can be partially attribut-
ed to their affinity to the oils and greases common to sludge.
The concentration of alkyl substituted homologues of naphthalene far exceeds
that of the parent compound, and this is consistent with a study recently
completed at the University of California. '
Other compounds such as 2-chloroaniline, 3,3'-dichlorobenzidine, and 2,4'-
dianrino-3,3'-dichlorobiphenyl due to their resistance to biodegradation, and
tend to either appear in the sludge or remain in the aqueous phase.
Alkyl substituted benzenes (C^g - ^4) originate from linear alkyl benzene
sulfonate (LAS) detergents which are used domestically as well as once
manufactured locally. The accumulation of these compounds in the sludge is
40
-------
probably due to their low biodegradability and Tow water solubility.
Aeration cell sludge appears to be at equilibrium as over two years of data
collection has shown no trend of increasing or decreasing chemical accumu-
lation. Variations in concentration are partially resultant from sampling
and experimental differences, but primarily due to non-homogeneity within
the sludge itself.
Examining the overall performance of extended aeration, only 15 of the 135
influent chemicals have been detected at levels greater than 50 yg/1 after
treatment. These include toluene, chloroform, 1,2-dichloroethane, dimethyl
disulfide, phenol, 2-chloroaniline, 2-propanol, 2-methoxyphenol, methylene
chloride, acetone, benzene, tetrachloroethylene, methyl aniline, alky!
substituted benzenes, and 2,4'-diamino-3,3'-dichlorobiphenyl. Of these
compounds, only 4 are consistently above or near 50 l^g/l. They are chloro-
form (86 yg/1), 1,2-dichloroethane (164 yg/1), dimethyl disulfide (50 yg/1),
\
and 2-chloroaniline (92 yg/1). Differences such as these can be attributed
again to variations in industrial loadings. Generally, removals for most
compounds are better during summer months than winter, probably due to
higher temperatures increasing volatilization and metabolism. This is
evident when comparing February, 1980, and September 8-19, 1980, in terms of
the removal of 1,2-dichloroethane (1900 - 580 yg/1 vs 780 - 42 yg/1), and
2-chloroaniline (410 - 80 yg/1 vs 330 - 10 yg/1). Even sporadic high levels
such as 1250 yg/1 benzene entering the system during the second July, 1980,
composite and the 120 yg/1 3,3'-dichlorobenzidine entering during the May,
1980, composite did not result in higher levels leaving the spillway.
41
-------
In summary, the large volume, extended aeration treatment employed appears
to be highly effective in handling daily loadings and even sporadic shock
levels as efficient removal is achieved by volatilization, metabolism,
sludge concentration, or combinations of these mechanisms for most compounds.
A majority of the overall removal of organic chemicals occurs in this unit
of the treatment process. Even though the concentration of certain chemicals
in the sludge does represent a removal from the liquid phase, continued
accumulation may prohibit future land application of aeration cell sludges.
Long-Term Impoundment
The storage lagoon system acts to further treat the wastewater by facilitat-
ing additional volatilization, metabolic utilization, photo-oxidations, and
settling processes. The tremendous volume of the lagoon system also provides
a large "buffer"^capacity to adsorb any short-term shock load that may pass
through the extended aeration treatment. Both composition and concentration
exhibit seasonal patterns with the highest levels and number of compounds
being found when the lagoons are under ice cover. Lack of volatilization
and the slow nature of anaerobic metabolism prevent efficient chemical
removal during this period. This is illustrated in Tables 16 and 17 for
1980 and 1981 data respectively.
42
-------
TABLE 16. SEASONAL
VARIATION IN THE
1980
STORAGE LAGOONS .DURING
Compound E.
Chloroform
Bis (ethyl hexyl )phthalate
2-Chloroaniline
Dichloroazobenzene
Alkyl substituted benzenes
Tri butyl phosphate
Benzene
1 ,1 ,1-Trichloroethane
Phenol
Methyl ene chloride
1 ,2-Dichlorethane
Toluene
Dimethyl disulfide
2-Ethoxy propane
Methyl aniline
3,4-Dirnethoxyphenol
2,4l-Dianiino-3,3'-dichloro-
bi phenyl
March,
Lagoon
13
-
4
2
-
10
3
2
1
4
68
-
1
35
1
4
2
Concentration
1980
W. Lagoon E
1
-
1
3
-
19
2
2
-
3
51
1
2
2
-
-
-
(ug/D
August,
. Lagoon
6
2
8
4
2
-
-
-
-
-
9
-
-
-
-
-
-
1980
W. Lagoon
1
2
2
2
-
-
-
-
-
-
-
_
-
-
-
-
-
Total
16
TADLE 17. SEASONAL
VARIATION
IN THE STORAGE
LAGOONS
DURING
1981
Compound
Chloroform
1 ,2-Dichloroethane
Tetrachl oroethene
Toluene
Acetone
2-Chloroaniline
Cresol
1 ,1 ,1-Trichloroethane
2 , 4 ' -Di ami no- 3 , 3 ' -Di chl oro-
bi phenyl
2, 2 '-Dichloroazobenzene
Diethoxychlorobenzene
3,4-Dimethyl phenol
March,
E. Lacjoon
25
10
12
2
53
48
1
-
22
16
7
-
Concentration (
1981
W. Lagoon E
18
12
14
1
_
7
_
-
-
1
1
1
yq/i)
August,
. Lagoon
1
-
1
_
_
6
_
_
-
2
-
-
1981
W. Lagoon
15
13
9
_
_
37
_
3
-
28
-
-
(continued)
43
-------
TABLE 17. (Continued)
Compound
Dimethyl disulfide
Dimethyl naphthalenes
IH-Indole
Isopropylidine dioxyphenol
Methyl aniline
Phenyl ethanone
Trichloroethylene
Alkyl substituted benzenes
Thiobisme thane
Tributyl phosphate
Trimethyl naphthalenes
Methyl naphthalenes
March,
E. Lagoon
1
7
6
1
12
2
-
11
8
1
8
2.
Concentration
1981
W. Lagoon
_
-
5
-
-
-
-
-
-
-
(yg/1)
August,
E. Lagoon
.
-
.
1
-
-
-
-
_
-
-
1981
W. Lagoon
-
-
3
5
-
1
-
_
_
-
-
Total 22
Differences in concentration between the two storage lagoons is from
different flow patterns employed in the filling of each lagoon. Higher
concentrations and numbers of compounds are found in the lagoon that is being
filled. Both Tables 16 and 17 show about 20 compounds present during winter
months, with only chloroform and 1,2-dichloroethane near 50 Ug/1 in 1980 and
acetone and 2-chloroaniline at that level in 1981. The other chemicals
average 10 ug/1, which is a very low level and at the recommended detection
limit for EPA priority pollutants (4&5). Water that is used for irrigation
is drawn from the lagoon with the longest residence time (east lagoon in
1981). Using the August, 1981, data, as an example, the 100+ compounds
entering the system are reduced to only 5 (chloroform, trichloroethylene,
2-chloroaniline, isopropylidene dioxyphenol, and 2,2'-dichloroazobenzene) at
levels less than 10 ng/1 by the extended-aeration, lagoon-impoundment treat-
ment prior to irrigation.
Dichloroazobenzene does not show a seasonal variation with higher lagoon con-
44
-------
centrations during the winter. This compound could also be dichlorodiphenyl
hydrazine. A distinction has never been made, as they both chromatograph
as the azo compound. This chemical exhibits a trend of increasing concen-
trations during summer months. A recent study^ ' has demonstrated the
conversion of certain chlorinated anilines to chlorinated azobenzenes by
photochemical oxidation. Such a condensation reaction may be occurring in
the storage lagoon to convert the 2-chloroaniline to 2,2'-dichloroazo-
benzene, thus increasing the concentration of the latter chemical during
periods without ice cover.
Table 18 gives the average storage lagoon concentrations and pollutant
removal efficiencies during the two-year study. Out of the original list of
125 chemicals, 35 have survived the impoundment phase of treatment. Of this
group, only 18 are detected sufficient times or in great enough quantities
to average 1 ug/1 or more. One of the key functions of long term storage
is to further degrade the low quantities of chemicals left after extended
aeration. The large surface area, coupled with wind action, provides an
excellent mechanism for volatilization of solvent chemicals. Only one
solvent, 1,2-dichloroethane persists at greater than 10 yg/1 (average 14
yg/1). This concentration represents, however, 98% removal of the influent
loading.
Metabolic and sedimentation routes remove heavier chemicals with 2-chloro-
aniline being the only non-volatile to persist at> 10 yg/1 (actual average
11 vg/1). Most of the chemicals in Table 20 are loaded into the system at
50 ug/1 or greater. With a few exceptions, such as isopropylidene dioxy-
phenol, alkyl benzenes, tributyl phosphate, and diethoxychlorobenzene, treat-
ability could probably be enhanced by limiting the influent concentrations.
45
-------
The latter'.group.of chemicals, however, show definite resistance to treat-
ment by either extended aeration or impoundment.
TABLE 13. AVERAGE STORAGE LAGOON CONCENTRATIONS OF ORGANIC
CHEMICALS AND REMOVAL EFFICIENCIES FOR 1980 AND 1981
Average
Concentration
Priority Pollutants (^g/1)
Benzene
Bis(2-ethylhexyl)phthalate
2-Chlorophenol
Chloroform
3 , 3 ' -Di chl orobenzi di ne
1,2-Dichloroethane
Methyl ene chloride
Phenol
Pyrene
Tetrachl oroethyl ene
Toluene
1,1,1-Trichloro ethane
Trichloroethylene
2 ,4 ,6-Tri chl orophenol
Additional Organic Compounds
Acetone
Acetovanillone
Alkyl substituted benzenes
Carbon disulfide
2-Chloroaniline
2-Chlorohydroquinone
<1
3
<1
9
<1
14
< 1
2
<1
3
1
< 1
< 1
< 1
1
< 1
3
< I
11
< 1
2,4'-Dianrino-3,3'-dichlorobiphenyl 3
Cresol
2,2'-Dichloroazobenzene
Diethoxychlorobenzene
Diethoxybenzene
3 ,4-Dimethoxyphenol
Dimethyl disulfide
Dimethyl naphthalenes
Isopropylidine dioxyphenol
Methyl aniline
Methyl naphthal enes
N ,N-Dimethyl am' 1 ine
2-Propanol
Thiobismethane
Tributyl phosphate
< 1
7
2
< 1
<1
1
<1
2
2
<1
< 1
1
1
3
Average Removal (%) Average
From Extended Removal (%}
Aeration Total
93
61
99+
89
74
78
28
0
99+
91
98
90
94
50
53
94
64
99+
84
99+
56
90
53
52
99+
67
72
71
50
65
75
80
30
82
60
99+
87
99+
99
99+
98
99+
60
99+
99
99+
99+
99+
99+
99+
99+
94
99+
98
99+
97
99+
82
90
99+
99+
99+
99+
75
95
99+
99+
99+
99+
90
46
-------
Sedimentation of compounds associated with solids does contribute a
significant part to the overall treatment in the storage lagoons as sludge
blankets are located at the inlets of each lagoon. A sounding study
conducted in 1980 revealed a thin sludge blanket averaging a 250-yard
radius, .75 inches deep in the west lagoon and a 550-yard radius, 4 inches
deep in the east lagoon (Appendix C).
Representative sludge quality data for the east and west lagoon sludges
are given in Table,21. The chemical makeup is essentially the same as Cell
II sludge with, however, a general reduction in concentration of an order
of magnitude. The alkyl benzenes, 2-chloroaniline, 3,3'-dichlorobenzidine
and 2,4'-diamino-3,3'-dichlorobiphenyl are in greatest concentrations in the
sludge. From this information, it is evident that the chemicals associated
with the suspended solids in the spillway effluent settle out quickly in
the storage lagoons. A small, dissolved fraction of these chemicals also
exists which results in the water levels observed.
In summary, the lagoon impoundment of the wastewater provides an efficient
means to treat residual chemicals after extended aeration. Through sedi-
mentation, volatilization, and metabolic mechanisms, a large portion of
the spillway chemicals are removed. Because of seasonal cycles in the stor-
age lagoon system, concentrations are higher in the winter than in the
summer.
47
-------
TABLE 19. CONCENTRATION OF ORGANIC CHEMICALS
IN EAST AND WEST LAGOON SLUDGE (yg/Kg) 1980
Priority Pollutants 10/31, East 11/18, West
Bi s( ethyl hexyl )phthal ate
Chrysene
3,3'-Dichlorobenzidine
Di-n-butyl phthalate
Ethyl benzene
Fluoranthene
Naphthalene
Phenanthrene
To! uene
4,400
310
4,000
600
4
220
60
-
3
11,700
-
11,200
-
-
1,260
50
200
_
Additional Organic Compounds
2-Chloroaniline 5,700 2,500
2,2-Dichloroazobenzene 940 440
2,4'-Diamino-3,3l-diohlorobiphenyl 13,100 52,000
Diethoxychlorobenzene 460 90
Dimethyl naphthalenes 820 1,400
Methyl naphthalenes 560 420
Substituted benzenes 17,600 17,000
Trimethyl naphthalenes 1,200 2,200
48
-------
Irrigation . ..-.''
After impoundment, water is pumped into the outlet lagoon and then to crop
irrigation. Examining the composition of the outlet lagoon reveals only
6 compounds are present. With the exception of sporadic occurrences of
bis(ethylhexyl )phthalate being present (possible laboratory contamination),
concentrations of organics are well below 10 vg/1 prior to irrigation.
Selected examples of organic chemical levels in irrigation water for 1980
and 1981 are given in Table 20.
TABLE 20. ORGANIC CHEMICAL LEVELS IN IRRIGATION WATER
FOR 1980 AND 1981
Compound
1 ,2-Dichloroethane
Chloroform
Bis (ethyl hexyl )phthlate
2-Chloroanil ine
2,2'-Dichloroazobenzene
1 ,1 ,1-Trichloroethane
June
1
1
7
4
4
<1
Concentration
1980
August
1
1
-
2
2
<1
(W/l)
1981
June
<1
1
-
1
7
<1
August
1
<1
-
1
2
1
These reductions, with the exception of 2,2'-dichloroazobenzene, correspond
to 99+% removal prior to irrigation. Again, the 2,2'-dichloroazobenzene
level may partially be from photochemical, condensation of 2-chloroaniline as
discussed earlier.'^'
Results of the drain tile analyses illustrate the treatment of the irrigated
outlet lagoon water after passing through the soil. Trace levels of phthalate
esters and herbicides (1 vg/1) appear in the drain from May to November in
1980 and 1981. This corresponds to crop treatment with simazine and atrazine,
and irrigated water leaching herbicides and possibly phthalates from drain tiles.
49
-------
Levels of 1 yg/1 chloroform and 1,2-dichloroethane did occur in the August
and November sample series for 1980 and 1981. Chloroform and 1,2-dichloro-
ethane breakthrough is limited to the north fields as DT 48 contained no
measurable levels of these materials. Fields south of Apple Avenue (drained
by DT 48) receive lower hydraulic loadings which could account for the absence
of these chemicals at this station. The levels are, however, extremely low.
In examining 1981 results for drain tiles, breakthrough of chloroform and
1,2-dichloroethane at 1 ug/1 levels is noted in the April through August
samples on a sporadic basis for DT 11 and DT 19. The sporadic nature of these
results probably reflects the difficulty of obtaining precise analytical data
at the detection limit of the test. Overall, the drain tile effluent shows
high quality treatment is taking place in the soil matrix.
The fate of chemicals applied to the soil is examined in the second year of
research by an initial sampling in November, 1980, and subsequent monthly
samples taken from April to August of 1981. The results show phthalate esters
and xylene distributed in the soil column at 1,2, and 3 foot intervals. One
\
chemical 2,2'-dichloroazobenzene, is located only in the surface sample.
Levels range from 0.05 to 9.0 mg/Kg for phthalates, <0.05 mg/Kg to 1.0. mg/Kg
for xylene, and <0.05 to 0.20 mg/Kg for 2,2'-dichloroazobenzene. The vari-
ability of phthalate data indicates possible laboratory contamination problems.
For example, 8.3 mg/Kg of bis(ethylhexyl)phthalate is reported for Circle 48,
0-1 foot on Way, 1981. Samples from April to June, 1981 are <0.05 mg/Kg for
both dates. No rationale for such data can be given, except for laboratory
contamination. Consequently, phthalate data for soil samples is of limited
value. Xylene is an ingredient in the dispersing agent (crop oil) used to
50
-------
apply herbicides to the-farm land. -It is not detected in any significant
quantities in wastewater samples, so its distribution is resultant from
herbicide application.
The residuals of 2,2'-dichloroazobenzene are from irrigation water loadings.
Because of the possible photochemical condensation of 2-chloroaniline and
loadings applied in past years of operation, the dynamics of this material
cannot be determined. The levels are low and confined to the first foot of
soil, suggesting minimal environmental impact from potential leaching or
future accumulations. Given the analytical variability of the numbers (0.15
mg/Kg to <0.05 mg/Kg), it is difficult to speculate if the levels are
increasing, decreasing,.or at equilibrium. Only additional monitoring can
answer these questions. The most important information gained from the soil
samples is the fact that no significant accumulation for .any of the influent
chemicals is noted. The possibility exists for levels of chemicals, below
the water detection limit, to concentrate in the soil matrix to high levels.
After 7 years of operation, this has not occurred in the wastewater system.
Samples of corn collected at harvest in 1980 and 1981 revealed no trans-
location of wastewater organic chemicals. Numerous aldehydes, esters, sub-
stituted phenols, fatty acids, and hydrocarbons are noticed, but similar
compounds are found in control samples taken from corn fields in other counties,
None of the 125 organic chemicals identified in the influent are detected in
the corn samples.
Lagoon Seepage
The system is designed to prevent lagoon seepage from migrating off the
project by two interception ditches surrounding the north, east, and south
5.1
-------
boundaries, and purge'wells .along the west. Monitoring of the lagoon seepage..
wells (Figure 3) on the western side (2B2 and 3B2) are found to contain 5 ug/1
of 1,2-dichloroethane while 1B2, 4B2, and 5B2 contain no detectable organics.
Chloride data for 2B2 and 3B3 are 132 and 155 mg/1 respectively while 4B2 and
5B2 are 5 and 1 mg/1. This suggests a localized groundwater migration in the
northwest direction towards 2B and 3B wells. Chloride levels of 2 and 1 mg/1
in 2C2 and 3C2, however, show no migration approximately 500 ft beyond the
B well cluster. It seems that this migration is localized to 2B and 3B areas.
Monitoring of the wells in 1981, however, reveal 1,2-dichloroethane (1 i*g/l)
and several aniline homologs present at 1B2. Chemical changes in wells 1B2
and 2B2 during the study period are given in Tables 21 and 22. The results
do show a definite localized deterioration in water quality. Table 23
illustrates changes in well 31B2 from 1980 to 1981. Again, there appears
to be a migration of storage lagoon water in the northwest direction.
Continued operation of the purge wells should restrict the localized migration
to the B clusters. The hydrogeology of this area is currently under investiga-
tion as part of the 201 facilities plan for the site. Depending on the re-
sults of this study, additional groundwater control measures may be instituted.
One possible alternative is the construction of an interception ditch in this
area.
Analysis of the middle dike seepage well LS34C2 in 1980 revealed elevated
levels of 2-chloroaniline (210 vg/1) and 1,2-dichloroethane (53 vg/1), indi-
cating groundwater contamination localized below the storage lagoons at 38 ft.
The contamination does not persist to 68 ft as LS34C3 contains no detectable
organics. These levels may be resultant from previous high water concentra-
tion levels, adsorption phenomena concentrating present low organic levels,
52
-------
TABLE 21... CHEMICAL CHANGES IN WELL 1B2
Compound
Concentration (yg/1)
7-28-80 8-28-80 2-19-81 3-11-81 8-13-81
Chloroethane <1
1 ,2-Dichloroethane <1
Di-n-butyl phthalate <1
Cresol <1
Methyl aniline <1
Ethyl aniline <1
Trichloroethylene <1
Trans-1 ,2-dichloroethylene <1
<1 1
<1 1
<1 2
<1 1
<1 1
<1 3
<1 <1
<1 <1
<1
<1
3
<1
1
1
<1
<1
8
<1
<1
<1
<1
<1
1
1
TABLE 22. CHEMICAL CHANGES IN WELL 2B2
Compound
Concentration (yg/1)
6-13-80 7-81
1,2-Dichloroethane
Chloroethane
Tetrachloroethene
Toluene
3
8
26
9
TABLE 23. CHEMICAL CHANGES IN WELL LS31B2
Compound
Chloroform
1 ,2-Dichloroethane
Di-n-butyl phthalate
Bis (ethyl hexyl )phthalate
Dichloroazobenzene
2-Chloroaniline
Aniline
Naphthalene
Concentration
10-20-80
6
10
1
2
1
-------
or leaching organics from the sludge blankets on the lagoon bottom. With
the sandy soils present under the lagoons, adsorption reactions may be
minimal as this type of matrix does not tend to concentrate organics (17).
Similarly, the small extent of the sludge blankets in the storage lagoons,
as discussed earlier, would tend to limit the effects of leaching. Levels
of these chemicals are found in the interception ditches as both contain
mixtures of lagoon seepage and groundwater. The north interception ditch
(ND) is mixed with groundwater and drain tile effluent to form the north
discharge (05 or NPDES #001) to Mosquito Creek. Its influence on water
quality will be discussed in the section on "discharges." South inter-
ception ditch (SD, or the discharge to HH&G Drain) represents a direct
discharge of groundwater and lagoon seepage to Black Creek.
A consistent 4 to 6 yg/1 of 1,2-dichloroethane was found at SD, along with
concentrations of 2-chloroaniline that varied from 86 yg/1 to 1 yg/1 in 1980.
The 86 yg/1 level was found in December and then the level dropped to
20 yg/1 for 3 months. Beginning with warmer temperatures, the level dropped
to 5 yg/1 and then to non-detectable levels.
Beginning in 1981, north ditch was sampled and a peak level of 180 yg/1 of
2-chloroaniline was present in March. Levels fell to 28 yg/1 in April and
then to
-------
D group wells. .The greatest concentrations .are localized at 30 ft in
A (.113 mg/1), 50 foot in B (.25 mg/1) and 30 foot in D (.160 mg/1). Deeper
wells of the A and D cluster (50 ft and 70 ft) contain very low levels
of 2-chloroaniline. The C group cluster contained 29 yg/1 at 30 feet and
less than detectable levels for other remaining depths.
The lower levels of 2-chloroaniline present in the C group cluster supports
the data observed for south ditch during this period. Higher levels
present in north ditch are also supported by the elevated levels in A and B
groups. Reasons for the concentration distribution are, however, not as
clear. The presence of 2-chloroaniline and isopropylidene dioxyphenol in the
seepage water reflect lagoon water concentrations. The A group of wells is
the only group in the close proximity to the sludge blankets in the lagoons.
TherB group of wells are located in the path of regional groundwater flow and
this could account for higher levels of 2-chloroaniline in this group. There-
fore, elevated 2-chloroaniline levels are probably only slightly influenced by
the leaching action of seepage water through the sludge.
The distribution of 1,2-dichloroethane is of interest as it is only present
in well group D. As documented in this report and previous ones, 1,2-dichloro-
ethane also occurs in lagoon seepage wells 1B2, 2B2, and 3B2. This distribu-
tion pattern suggests a problem with 1,2-dichloroethane localized in west
lagoon. A previously high load of 1,2-dichloroethane may have entered west
lagoon in the past and, because of mixing problems which would occur under
ice cover, a localized area of the lagoon may have become contaminated. The
lagoon area around D group is especially prone to mixing problems.
55
-------
The A, B, and D well clusters are all in proximity of the lagoon inlets
and the higher levels of chemicals observed could be resultant from
such a mixing problem. This problem could be eliminated by extending the
outfall pipe further into the lagoon to facilitate better dispersion.
Continued monitoring of these wells by gas chromatography and HPLC has
revealed no significant trend of increasing or decreasing levels. Given the
complexity of the data patterns, accurate conclusions regarding lagoon
seepage cannot be drawn with present data. Hydraulic loadings may also
influence lagoon seepage concentrations. Levels of 2-chloroaniline are
greatest during winter months, which corresponds to the highest water levels
in the storage lagoon system. Only future monitoring and correlation of
storage lagoon, dike wells, and interception ditch data can answer the
questions surrounding lagoon seepage.
Analysis of well 17A in 1980 revealed no detectable organics present,
illustrating the absence of lagoon seepage movement beyond the interception
ditch. This plus the lack of chloride contamination in C group well
clusters, shows the effectiveness of the design features in preventing
lagoon seepage migration off the project. The presence of organic chemicals
in the seepage water, however, indicates inadequate treatment with respect
to possible previous high loadings, soil adsorption and concentration
mechanisms, or sludge leaching causing the survival of certain chemicals
in the wastewater system. There is no adverse environmental impact from la-
goon seepage of the two chemicals, considering that the currently proposed EPA
water quality criteria for 1,2-dichloroethane is 7 yg/1 at the 10 risk level.
This is based on the consumption of 2 liters of water plus 18.7 grams of
contaminated fish per day (16). Using this as a criteria, the 4-6 ug/1 are
56
-------
probably not harmful to the environment. No present standard is available . .
for 2-chloroaniline; however, bioassay information will be developed as
part of the system's new NPDES permit. Father investigation is needed,
however, to define the dynamics of lagoon seepage in order to insure that
levels are controlled and do not increase beyond any standards.
With the potential for discharge of chemicals to the environment in lagoon
seepage waters, it is important to manage the concentration of these chemicals
in the storage lagoon water. While the historical influences to the lagoon
seepage waters cannot be changed, the future influences can, by limiting the
initial concentration of chemicals entering the system to levels which will
reduce survival in the lagoon system. The County has instituted management
guidelines for effluent chemicals from industrial chemicals. The levels
are set to introduce influent levels that can be effectively treated and
thus, eliminate potential adverse environmental effects from the pass through
of chemicals in the lagoon seepage water.
Discharges
The two discharges are unique in terms of composition and, therefore,
warrant separate discussions. South discharge(34) on NPDES #002 is made
up of groundwater and drain tile effluent. The effluent chemical composi-
tion is very similar to the drain tiles discussed earlier as only trace
levels of phthalate and herbicides are present in 1980-1981 samples. The
herbicide levels (1 yg/1) are probably no greater than those experienced
at any farming operation in terms of agricultural runoff. The absence of
organics from this station illustrates the efficiency of the treatment
system in producing high quality effluent by spray irrigation.
57
-------
The north discharge (05 of'NPDES #001) .is made up of drain.tile effluent,
groundwater, and lagoon seepage collected in the north interception ditch.
Low levels of 1,2-dichloroethane (1 yg/1) and 2-chloroanil ine (15 to< 1 yg/1)
are encountered at this station from January, 1980, to April, 1980. With
the drain tiles showing no contamination present, the introduction of these
compounds must be from lagoon seepage entering north ditch and being mixed
in the discharge. Concentrations of 2-chloroaniline follow seasonal patterns
with highest values in the winter and a reduction to nondetectable levels
in the summer.
The chemicals were not present in 1981 samples which is consistent with the
change in lagoon seepage concentrations discussed earlier. Several sporadic
concentrations (1-18 yg/1) of chlorinated solvents such as methylene chloride
and tetrachloroethene are found in the discharge water, however, concentra-
tions in drain tiles or irrigation water are not observed. These numbers
are probably laboratory contamination as no consistent trend is documented.
The effective nature of the Muskegon System is evident by the absence of the
influent industrial chemicals in the discharges. Of the 125 chemicals
identified in the study, only low levels of 2-chloroam'line and 1,2-dichloro-
ethane pass through the system. These chemicals could be easily eliminated
from the discharge by management of influent levels as both compounds have
a treatment efficiency of 98%. Lower influent levels would reduce these
chemicals to below analytical detection limits.
Wells
In addition to the lagoon seepage wells discussed earlier, six metal cased
USGS wells and other selected lagoon seepage were monitored during the study
58
-------
period. The USGS wells are metal cased, and not subject to phthalate inter-
ferences. No detectable compounds are found in USGS 1-6 during the sampling
program. These results show that ground water aquifiers are being protected
in the land application of the treated water. The draintiles collect the
irrigated water adequately, preventing possible contamination of the ground-
water table. Small quantities of the organic compounds in the lagoon im-
pounded water are further eliminated by land application.
59
-------
REFERENCES
1. Preliminary Survey of Toxic Pollutants at the Muskegon Wastewater
Management System. Robert S. Kerr Environmental Research Laboratory.
May, 1977.
2. Progress Report, 1968 through 1975. Muskegon County Wastewater
Management System. EPA 905/2-80-004.
3. Progress Report, 1976-1979. Muskegon County Wastewater Management
System. 1980.
4. Method 624, Purgeables. (1979) U.S. EPA, Cincinnati, OH.
5. Method 625. (1979) Semivolatiles, ibid.
6. Reference Compound to Calibrate Ion Abundance Measurements in Gas
Chromatography-Mass Spectrometry Systems. Eichelberger, J. W. and
L. E. Harris, W. L. Budde, Anal. Chem. 47_ 995. 1975.
7. Methods for the Analysis of Priority Pollutants in Solids and Bottom
Sediments (1978). ibid.
8. Method 601. (1979) Purgeables. US EPA, Cincinnati, OH.
9. Method 605. (1979) Benzidines. ibid.
10. NIOSH Manual of Analytical Methods. HEW Publication No. (NIOSH) 75-121.
GPO 1733-0041.
11. Draft Report of Analytical Data (1979). C. S. Clark, University of
Cincinnati, Medical Center. Institute of Environmental Health,
Cincinnati, OH.
12. Handbook of Environmental Data on Organic Chemicals. (1977).
K. Verschueren. Van Nostrand Reinhold Co., N.Y.
13. Biochemistry (1972) Lehninger. Worth Publishing Co., Ft. Worth, Texas.
14. Fate of Priority Pollutants in Publicly Owned Treatment Works.
EPA 440/1-80-302. 1980.
15. Photolysis of 3,4-Dichloroaniline in Natural Waters (1980). G. C. Miller,
R. Zisook, and R. Zepp. J. Agriculture Food Chemistry. 28:6:1053-56.
16. Federal Register Vol. 44, No. 191. Oct. 1, 1979, pp 56642-56646.
17. Environmental Chemistry (1971). V. Stumm and G. Morgan. Wiley
Interscience Co., N. Y.
18. Quality Assurance and Quality Control Procedures for Organic Priority
Pollutants (1979). U.S. EPA, Cincinnati, OH.
60-
-------
19. The Chemical Society Annual Reports on the Progress of Chemistry,
Biological Chemistry (1965), D. W. Ribbons, Volume 63, pp 445-468.
20. Environmental Science and Technology, (1982), R. P. Eganhouse and
I. R. Kaplan, Volume 16, No. 9, p 541.
61
-------
APPENDIX A
Results
62
-------
WATER SAMPLES
63
-------
Priority Pollutants
-Acenaphthene
-Acenaphthylene
-Anthracene
Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2- ethyl hexyl ) phthal ate
-B romodi chl oromethane
-Butyl benzyl phthal ate
Chlorobenzene
-2-Chlorophenol
-Chl orobhenyl ether
-Chloroethane
Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
Chrysene
1,2-Di Chlorobenzene
-1,4-Di chlorobenzene
3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1,1-Dichloroethene
-1,2-Di chloroethane
-2,4-Dichlorophenol
-Diethyl phthal ate
2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
60
13
4
1,300
2
2
2
14
560
8
3
Spillway
2
140
1
1
11
91
32
2
East
Lagoon
2
West
Lagoon
14
15
Outlet
Lagoon
5
SD
3
ND
05
1
34
1
DT 11
3
DT 19
1
2
. !
DT 48
-
-
. -
. -
-
1. -
-
-
-
-
.-
-
-
-
-
-
-
. -
-
-
-
-
.-
-
1 -
-
-
-
TABLE A-l. DECEMBER, 1979 - JANUARY, 1980 COMPOSITE SAMPLES (uG/L)
-------
cr>
tn
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1 , 1 , 1-Tri chloroethane
-Trichloroethylene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
24
4
13
10
89
28
38
1,200
Spillway
3
4
90
2
5
2
3
88
East
Lagoon
5
3
West
Lagoon
7
2
4
Outlet
Lagoon
SD
2
86
ND
05
3
15
34
2
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
'-
-
-
-
fc
-
-
4-
-
-
-
-
-
-
-
-
-
DECEMBER, 1979 - JANUARY, 1980 COMPOSITE SAMPLES (uG/L) (CONTINUED)
-------
en
cr>
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethyl aniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
17
90
41
83
320
Spillway
18
3
45
East
Lagoon
West
Lagoon
5
Outlet
Lagoon
SD
ND
05
34
DT 11
^
DT 19
DT 48
..
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
DECEMBER, 1979 - JANUARY, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 11 i n
-Xyl ene
Influent
40
320
15
32
Spillway
14
i
120
48
39
East
Lagoon
6
West
Lagoon
4
12
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
_
_
.
_
_
. _
_
'_
_
_
_
^
_
_
_
_
. _
'._
_
_
^
_
-
DECEMBER, 1979 - JANUARY, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
Priority Pollutants
-Acenaphthene
-Acenaphthylene
-Anthracene
Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chlorobhenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1,2-Di Chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1- Di chloroethane
-1 , 1-Oi chl oroethene
-1,2-Di chloroethane
-2 ,4-Di chl orophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
Di-n-butyl phthal ate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
160
1
12
4
15
1,100
2
1,900
Spil Iway
3
2
4
92
1
580
East
Lagoon
1
13
43
West
Lagoon
1
20
Outlet
Lagoon
SD
5
NJ3
05
2
34
DT 11
1
DT J9
1
. |
DT 48
.
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
. -
-
-
FEBRUARY, 1980 COMPOSITE SAMPLES (yG/L)
-------
10
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chloromethylbenzene
Infl uent
3
32
100
160
62
16
410
Spillway
32
3
3
5
1
80
East
Lagoon
5
3
4
West
Lagoon
3
3
Outlet
Lagoon
SD
2
22
ND
05
3
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
. -
.-
-
_
-
-
-
-
-
-
. -
-
-
FEBRUARY, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-Z^'-Diamino-S.S'-dichloro-
biphenyl
-2, 2-Dichl oroazobenzene
-1,4-Diethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyanil ine
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
14
5
260
3
37
30
Spil Iway
10
5
9
3
16
10
East
Lagoon
2
2
West
Lagoon
3
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
T
-
-
-
-
-
-
-
. -
-
--
-
-
-
-
-
-
-
-
-
-
-
-
-
FEBRUARY, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4- Methyl dibenzothiophene
Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethylanil ine
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Tri methyl naphthalenes
-Trimethyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
2
16
160
8
3
Spillway
2
10
72
11
2
East
Lagoon
6
West
Lagoon
1
Outlet
Lagoon
SD
2
NTJ
05
34
DT 11
DT 19
DT 48
. _
_
_
- _
J.
_
_
_
^
'_
_
'
_
'
" _
-
_
_
_
__
_
_
FEBRUARY, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
ro
Priority Pollutants
Acenaphthene
-Acenaphthylene
Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl )phthal ate
-Bromodichloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
Chi orophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
Chrysene
-1,2-Di chlorobenzene
-1, 4- Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1- Di chloroethane
1 , 1-Di chl oroethene
-1,2-Di chloroethane
-2 ,4-Di chlorophenol
-Di ethyl phthalate
-2,4-Dimethyl phenol
Dimethyl phthalate
-Di-n-butyl phthalate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
81
2
1
2
6
740
9
Spillway
17
250
East
Lagoon
3
68
West
Lagoon
2
51
32
Outlet
Lagoon
SD
6
ND
05
2
34
DT 11
DT 19
!
i
DT 48.
.* _
-
r
.
; '-
" -
'.' -
'.. i
''
'
-' -
-
'" -i
-:
-
.'..'-
." -
.-
".'-
: -
-' T
-
.'-
-
-
MARCH, 1980 COMPOSITE SAMPLES (yG/L)
-------
CO
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl.oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chi oromethyl benzene
Influent
37
2
8
130
370
12
130
110
20
200
Spillway
24
1
4
64
7
25
18
East
Lagoon
4
1
7
17
2
4
West
Lagoon
3
1
2
1
Outlet
Lagoon
SD
25
ND
05
2
34
DT 11
DT 19
DT 48
..' .
.-
-
-
'-
;
. :
:
:' -
-
;
-
-
T
'-.
-
-
' -
' -
"' '-
-: -
'-
.-
-
'' T
MARCH, 1980 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
19
110
5
11
790
2
11
78
11
Spillway
7
4
290
7
East
Lagoon
2
2
4
35
1
West
Lagoon
3
2
Outlet
Lagoon
"
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
.-
-
.-
-
>
-
-
-
-
-
-
;-
-
-
-
-
-
-
-
-
-
-
-
MARCH, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
1
in
Additional Org. Chem. (Cont'd)
4- Methyl dibenzothiophene
-Methyl naphthal enes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N.N- Dimethyl aniline
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Tri methyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
1
3
250
40
2
Spillway
1,200
49
39
East
Lagoon
1
10
West
Lagoon
2
19
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
_
_
*
_
_
._
_
'.
_
_
,
^
^
_
^
_
-
MARCH, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
CT>
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bis( 2- ethyl hexyl )phthal ate
Bromodichloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
Chlorophenyl ether
-Chloroethane
Chloroform
-4-Chl oro- 3- methyl phenol
2-Chloronaphthalene
Chrysene
-1,2-Di chlorobenzene
1,4-Di chlorobenzene
-3,3 '-Dichlorobenzi dine
-1,1- Di Chloroethane
-1,1-Dichloroethene
1,2-Di Chloroethane
-2 ,4-Di chl orophenol
-Di ethyl phthalate
-2, 4-Dimethyl phenol
Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
62
97
4
670
14
53
1
Spillway
35
7
170
2
130
East
Lagoon
16
96
West
Lagoon
29
110
Outlet
Lagoon
SD
5
ND
05
1
34
DT 11
DT 19
. i
DT 48-
.
-
. .-
.
-
-
-
-
r
-
-
-
-
-
-
-
-
-
-
-
-
-
-
;-
-
-
-
-
APRIL, 1980 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
6
4
150
580
30
30
5,800
8
180
Spil Iway
2
19
26
36
5
1
44
East
Lagoon
3
2
1
17
West
Lagoon
3
1
6
3
Outlet
Lagoon
SD
32
ND
05
12
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
. -
-
-
APRIL, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
-J
00
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
16
20
770
12
6
4
Spillway
8
5
6
33
360
8
88
East
Lagoon
3
West
Lagoon
3
3
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
'.
-
-
_-
-
.-
-
-
-
-
-
-
-
-
-
'-
'-
-
'.
-
-
.-
-
-
-
APRIL, 1980 COMPOSITE SAMPLES (yjG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
6
2,400
1,700
16
10
Spillway
4
170
20
8
East
Lagoon
13
West
Lagoon
15
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
-.
_.
_.
_
_
. _
_
_
_
^
_
^_
_
_
_
.
-
-
APRIL, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
-Acenaphthylene
Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
Bi s( 2- ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
Chlorobenzene
2-Chlorophenol
-Chi orobhenyl ether
-Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di chlorobenzene
-1,4-Di chlorobenzene
3,3'-Dichlorobenzidine
-1,1-Di Chloroethane
-1,1-Dichloroethene
-1,2-Di Chloroethane
-2 ,4-Di chl orophenol
-Di ethyl phthal ate
2, 4-Dimethyl phenol
Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
26
16
5
7
2
610
20
19
120
510
7
11
5
Spillway
10
1
70
1
7
270
4
East
Lagoon
6
10
19
1
West
Lagoon
6
3
Outlet
Lagoon
2
4
SD
8
5
ND
05
8
2
34
4
DT 11
3
2
DT 19
3
DT 48
.
-
-
4 -
-
.
'-
.
-
-
-
.-
.
-
-
-
-
-
-
-
-
-
-
' :
-
-
-
-
'-
-
May 1-15, 1980 COMPOSITE SAMPLES (yG/L)
-------
00
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1,2-dichloroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chloromethylbenzene
Infl uent
120
16
5
12
160
550
60
9
11
110
1,800
91
51
1,100
Spil Iway
770
1
8
10
11
8
6
300
19
5
43
East
Lagoon
4
2
3
11
8
West
Lagoon
2
8
4
Outlet
Lagoon
3
3
5
SD
5
ND
05
2
34
DT 11
DT 19
DT 48
'.
-
-
-
-
-
'-
-
-
-
-
. -
-.
-
' -
'-
-
--
'-
-
-
-
-
-
-
MAY 1-15, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
ro
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
14
400
89
82
10
270
40
130
Spillway
79
18
44
5
48
7
East
Lagoon
10
8
8
3
West
Lagoon
2
7
3
2
Outlet
Lagoon
4
2
1
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
.-
-
.-
-
-
-
-
-
-
.
-
.-
-
-
-
MAY 1-15, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thi ol )benzothi azol e
-Naphthol
-N.N-Dimethyl aniline
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
28
11
1,100
250
86
32
Spillway
2
22
90
26
39
6
East
Lagoon
2
West
Lagoon
7
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
_
.
'_
_
_
_
~
.
_
_
_
_
_
_
_
_
_
_
-
MAY 1-15, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
-pi
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chi orophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di chlorobenzene
1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
1,1-Di chloroethane
1,1-Dichloroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Diethyl phthal ate
-2, 4-Di methyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
34
7
6
3
4
810
6
81
680
10
6
1
Spillway
2
95
2
300
5
East
Lagoon
4
12
21
2
West
Lagoon
4
4
4
Outlet
Lagoon
3
5
SD
5
ND
05
10
1
34
3
DT 11
5
DT 19
4
DT 48
_
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
. -
-
-
-
-
-
-
-
MAY 19-30, 1980 COMPOSITE SAMPLES (yG/L)
-------
CO
en
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethyl ene
-Tol uene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethyl ene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Infl uent
12
2
6
200
920
71
18
11
900
99
910
Spillway
4
2
25
57
3
10
100
31
57
East
Lagoon
4
4
4
17
10
West
Lagoon
3
6
5
Outlet
Lagoon
3
5
SD
ND
1
05
34
DT 11
1
DT 19
DT 48
.
-
. -
-
-
'-
-
-
-
-
-
'/
-
-
-
-
-
.-
-
-
-
'-
-
-
MAY 19-30, 1980 COMPOSITE SAMPLES (wG/L) (CONTINUED)
-------
00
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Dianrino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
16
600
91
97
12
290
46
34
180
29
Spillway
81
21
39
4
57
6
6
7
East
Lagoon
12
9
6
4
West
Lagoon
4
9
3
3
Outlet
Lagoon
3
2
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
_-
-
-
-
-
,-
-
-
-
MAY 19-30, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2-(methyl thiol )benzothiazol e
-Naphthol
fl,N-Dimethyl aniline
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thi obi smethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
31
300
310
41
30
Spillway
5
41
41
47
7
East
Lagoon
4
West
Lagoon
10
Outlet
Lagoon
SD
3
3
ND
05
34
DT 11
DT 19
DT 48
_
_
_
_
_
-
. _
_
_
_
_
_
._
__
_ ,
_
_
_
_
_
-
MAY 19-30, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
00
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl )phthal ate
-Bromodichloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
-Chi orophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
-3,3 '-Dichlorobenzi dine
1,1-Dichloroethane
-1,1-Di chloroethene
-1,2-Dichloroethane
2,4-Dichlorophenol
-Di ethyl phthalate
-2, 4-Dimethyl phenol
-Dimethyl phthalate
Di-n-butyl phthalate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
43
4
4
2
2
1
540
4
3
2
1,800
1
5
6
Spillway
1
1
39
2
220
1
East
Lagoon
20
7
24
West
Lagoon
31
1
Outlet
Lagoon
7
1
1
SD
2
6
ND
05
2
34
2
DT 11
2
DT 19
i
DT 48
-
-
.
-
-
5 .
.
-
-
-
-
-
.'-
.'-
-
-
.
-
-
-
-
-
-
'-
-
-
-
-
-
-
JUNE 2-13, 1980 COMPOSITE SAMPLES (pG/L)
-------
00
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
21
4
1
2
190
520
6
44
9
1
2,100
10
540
Spillway
3
1
12
5
3
1
1
400
13
210
East
Lagoon
1
51
West
Lagoon
4
Outlet
Lagoon
4
SD
1
ND
05
1
1
34
1
DT 11
1
DT 19
1
DT 48
.
-
-
'-
-
-
-
-
.-
"-
-
.-
-
-
_
-
.-
-
-
.-
-
-
-
-
-
JUNE 2-13, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Dianrino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
4
12
13
25
2
13
22
12
15
34
320
Spillway
15
13
26
2
3
4
2
,48
East
Lagoon
4
4
3
1
1
30
West
Lagoon
4
2
Outlet
Lagoon
4
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
.-
-
-
-
-
-
-
-
-
-
.
-
' .
-
-
-
.-
JUNE 2-13, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobi smethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
5
1,100
190
14
9
Spillway
1
130
21
11
5
East
Lagoon
1
1
West
Lagoon
Outlet
Lagoon
SD
NO
£5
34
DT 11
1
DT 19
DT 48
._
'
_
_
j.
__
_
^
_
_
. _
-
_
'._
__
1
._
*.
_
^
_
-
JUNE 2-13, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
IO
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
Benzene
Benzo (a) anthracene
-Benzo (a) pyrene
Bi s( 2- ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chl orobhenyl ether
-Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di Chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
1,1-Dichloroethane
1 , 1- Di chl oroethene
-1, 2- Di chloroethane
-2 ,4-Di chl orophenol
-Diethyl phthal ate
-2, 4-Di methyl phenol
-Dimethyl phthalate
-Di-n-butyl phthalate
Ethyl benzene
Fluoranthene
-Methyl chloride
Influent
240
7
3
6
1
750
2
6
1,500
2
2
11
Spil Iway
2
37
^
3
64
2
East
Lagoon
3
5
25
West
Lagoon
11
1
2
Outlet
Lagoon
26
1
1
SD
2
1
5
ND
05
1
34
4
DT 11
DT 19
DT 48-
.
.
.
-
.
3 -
-
-
-
. -
: -
-
V-
. -
-
-
-
-
-
-
'.
.
-
-
-
-
-
-
.-
-
JUNE 16-27, 1980 COMPOSITE SAMPLES (yG/L)
-------
IO
CO
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1,2-dichloroethyl ene
-Trichlorobenzene
-1,1, 1-Tri chloroethane
-Trichloroethylene
-2,4,6-Trichlorophenol
-Vinyl chloride
i
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chloromethylbenzene
Influent
26
1
3
390
1,200
12
58
9
2
1,500
23
460
Spillway
3
8
2
1
2
55
10
46
East
Lagoon
1
2
West
Lagoon
2
Outlet
Lagoon
4
SD
1
ND
05
2
34
1
DT 11
1
DT 19
1
DT 48
.
' -
-
. "-
-
.-
-
-
-
-
'-
' .
-
'.-
-
".-
_ :
-
. -
: -
-
JUNE 16-27, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
10
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dich1oro-
biphenyl
-2,2-Dichloroazobenzene
- 1 ,4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxy phenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
4
28
42
8
5
8
300
2
32
11
Spillway
27
10
7
*
2
35
3
East
Lagoon
2
2
14
West
Lagoon
1
Outlet
Lagoon
1
SD
ND
05
34
DT 11
DT 19
DT 48
:-
-
-
-
. -
.-
-
"'-
-
-
-
.-
-
-
-
-
-
' -
-
-
. -
.
-
-
-
-
JUNE 16-27, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
1
850
-
110
140
2
Spillway
17
4
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
1
34
1
DT 11
1
DT 19
1
DT 48
_
_
_
. _
_ _
- _
'
.
"_
_
_
'
_
_
. ' _
_
_
' _
_
-
JUNE 16-27, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
VQ
CT>
Priority Pollutants
-Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
Benzo (a) anthracene
-Benzo (a) pyrene
-Bis(2-ethylhexyl )phthalate
-Bromodichloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthal ene
-Chrysene
-1,2-Di chlorobenzene
-1 ,4-Di chl orobenzene
-3,3'-Dichlorobenzidine
-1,1-Di chloroethane
-1,1-Dichloroethene
-1,2-Dichloroethane
-2 ,4-Di chl orophenol
-Diethyl phthalate
-2, 4-Dimethyl phenol
-Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
380
10
2
19
520
6
2
4
72
4
1
15
Spi 1 Iway
10
7
25
1
8
East
Lagoon
1
8
3
4
4
West
Lagoon
3
1
1
4
Outlet
Lagoon
2
1
1
1
SD
6
ND
05
4
1
34
12
1
DT 11
2
1
1
DT 19
2
DT 48
' ;
-
-
:
, -
-
4:
-
-
-
-
-
: -
. -
. -
. -
-
' -
-
-
. ;-
-
-
, -
; -
- -
-
' -
JULY 7-18, 1980 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
35
2
1
4
170
310
2
16
7
3
940
22
930
Spillway
9
5
2
3
94
12
97
East
Lagoon
1
2
4
West
Lagoon
2
Outlet
Lagoon
w
SD
ND
05
1
34
1
DT 11
1
DT 19
1
DT 48
-
-
-
-
. -
-
-
.-
. -
... -
-
.
-
-
-
-
1 -
-
. -
-
-
. -
' . -
-
JULY 7-18, 1980 COMPOSITE SAMPLES (jiG/L) (CONTINUED)
-------
10
03
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 ,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
4
22
31
2
2
4
79
6
v
10
1
Spillway
8
15
1
1
4
70
East
Lagoon
2
7
1
6
West
Lagoon
4
Outlet
Lagoon
4
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
'-
-
-
-
-
-
''-
-
;-
-
-
' -
-
-
-
JULY 7-18, 1980 COMPOSITE SAMPLES (vQ/l) (CONTINUED)
-------
10
Additional Org. Chem. (Cont'd)
4-Methyldibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thi ol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobi smethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
1
340
71
44
8
Spillway
110
10
2
East
Lagoon
1
West
Lagoon
Outlet
Lagoon
1
STJ
NTJ
05
1
34
1
DT 11
1
DT 19
1
DT 48
..
_
_
^
_
^
_
_
1 .
_
_
_^
mf
J
^
._
__
^_
fc
,^
^
_
^_
-
JULY 7-18, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
o
o
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
2-Chloronaphthalene
-Chrysene
-1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di chloroethane
1,1-Dichloroethene
-1,2-Di chloroethane
-2 ,4-Di chl orophenol
-Di ethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
1,250
12
2
1
620
5
1
2
1,200
2
9
Spillway
50
8
35
1
31
East
Lagoon
11
5
7
West
Lagoon
17
1
Outlet
Lagoon
3
1
1
SD
5
ND
05
-
7
1
34
13
DT 11
12
2
1
DT 19
i
DT 48
_
.-
-
-
-
-
8 -
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
JULY 21-31, 1980 COMPOSITE SAMPLES (uG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
- 1 , 1 , 1-Tri chl oroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-C hi oromethyl benzene
Influent
80
3
1
2
87
490
6
69
13
3
3,400
16
890
Spillway
6
3
10
4
3
530
11
150
East
Lagoon
2
5
West
Lagoon
1
Outlet
Lagoon
1
SD
1
ND
05
34
1
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
JULY 21-31, 1980 COMPOSITE SAMPLES (nG/L) (CONTINUED)
-------
o
ro
Additional Org. Chem. (Cont'd)
-Cresol
-Z^'-Diamino-S.S'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3 ,4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylanil ine
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
10
17
41
15
8
4
400
8
6
Spillway
10
7
3
4
1
East
Lagoon
3
6
West
Lagoon
4
Outlet
Lagoon
3
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
j
-
-
-
-
-
-
-
-
-
-
JULY 21-31, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
o
to
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- ( methyl thiol )benzothiazole
-Naphthol
-N,N- Dimethyl aniline
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
1
38
38
27
7
Spillway
140
8
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
1
DT 11
DT 19
DT 48
_
_
_
_
_
' _
_
_
_
..
.
_
_
_
_
__ .
_
.
._
-
JULY 21-31, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1 , 1-Di chl oroethane
1, 1-Di chl oroethene
1, 2- Di chl oroethane
-2 ,4-Di chl orophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
190
10
4
2
21
3
790
10
2
15
1,100
3
2
1
12
Spi 1 Iway
10
9
2
12
3
29
1
East
Lagoon
7
6
10
West
Lagoon
9
1
1
Outlet
Lagoon
6
1
1
SD
7
5
ND
05
6
1
34
9
DT 11
8
DT 19
2
DT 48
-
.
.
-
2-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
AUGUST 11-18, 1980 COMPOSITE SAMPLES (PG/L)
-------
o
tn
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-T rich! oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
41
3
1
5
200
1,600
2
18
2
270
21
740
Spillway
5
1
8
41
1
95
9
110
East
Lagoon
8
West
Lagoon
2
Outlet
Lagoon
1
SD
ND
05
1
34
1
DT 11
1
DT 19
1
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
_
-
-
-
-
1-
-
-
-
-
-
-
AUGUST 11-18, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxy benzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
6
19
64
8
8
2
97
10
35
6
Spillway
3
11
2
2
6
3
East
Lagoon
2
9
1
West
Lagoon
6
Outlet
Lagoon
5
SD
ND
05
34
DT 11
DT 19
DT 48
-
'-
-
-
-
.-
-
-
-
-
.-
-
-
. -
-
-
-
-
-
.
-
-
-
-
-
-
-
AUGUST 11-18, 1980 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4- Methyl dibenzothiophene
-Methyl naphthalenes
Methyl phenanthrenes
-2- ( methyl thiol )benzothiazole
-Naphthol
-N ,N-Dimethyl ani 1 i ne
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
7
91
120
19
10
Spillway
2
40
5
3
3
East
Lagoon
3
West
Lagoon
1
Outlet
Lagoon
1
SD
NCI
05
1
34
1
DT 11
1
DT 19
1
DT 48
_
_
. _
_
/_
_
_
'_
_
1-
_
_
_
_
.__
_
fc-
_
_
^,
_ :
-
AUGUST 11-18, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
o
00
Priority Pollutants
-Acenaphthene
Acenaphthylene
Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chl oronaphthal ene
-Chrysene
1, 2- Di Chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
1,1-Di chloroethane
-1,1-Dichloroethene
-1,2-Di chloroethane
-2 ,4-Di chl orophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
Dimethyl phthal ate
Di-n-butyl phthal ate
Ethyl benzene
Fluoranthene
-Methyl chloride
Influent
70
3
3
2
33
990
3
1
9
690
4
3
2
11
Spillway
1
5
4
36
2
51
East
Lagoon
2
6
9
West
Lagoon
2
1
Outlet
Lagoon
1
1
SD
3
ND
05
2
5
1
34
2
DT 11
26
1
2
DT 19
12
DT 48
_
-
.
-
310*
-
'
.
-
-
-
-
-
-
-
AUGUST 25 - September 5, 1980 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
36
3
1
401
1,100
1
49
8
4
21
15
970
Spillway
12
1
4
1
1
10
210
East
Lagoon
2
8
West
Lagoon
2
Outlet
Lagoon
2
SD
ND
05
1
34
2
DT 11
1
DT 19
1
DT 48
. .
-
-
-
-
-
-
-
-
-
_-
-
-
_
-
-
-
-
1-
.. -
' -
-
-
-
-
-
AUGUST 25 - SEPTEMBER 5, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
4
21
51
21
5
71
6
2
21
4
3
Spillway
4
12
14
4
1
11
East
Lagoon
2
4
3
1
7
West
Lagoon
2
2
Outlet
Lagoon
2
2
SD
ND
05
34
DT 11
DT 19
j
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
AUGUST 25 - SEPTEMBER 5, 1980 COMPOSITE SAMPLES (jiG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2- Pro pa no!
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted. naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
280
22
9
8
Spillway
1
3
1
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
1
34
DT 11
1
DT 19
1
DT 48
_
_
. _
_
_
' _
1 _
' _
_
_
_
_
_
_
_
* High concentration due to possible laboratory contamination.
AUGUST 25 - SEPTEMBER 5, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED
-------
Priority Pollutants
Acenaphthene
Acenaphthylene
Anthracene
Benzene
Benzo (a) anthracene
-Benzo (a) pyrene
Bi s( 2-ethyl hexyl )phthal ate
-B romodi chl oromethane
Butyl benzyl phthalate
Chlorobenzene
-2-Chlorophenol
Chlorophenyl ether
Chloroethane
-Chloroform
-4-Chl oro- 3- methyl phenol
-2-Chl oronaphthal ene
-Chrysene
-1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di Chloroethane
-1,1-Dichloroethene
1, 2- Di Chloroethane
2 ,4-Di chl orophenol
-Diethyl phthalate
2 ,4-Dimethyl phenol
Dimethyl phthalate
Di-n-butyl phthalate
Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
95
9
2
2
920
4
3
780
1
5
Spillway
2
70
42
East
Lagoon
4
8
3
West
Lagoon
2
2
1
Outlet
Lagoon
2
1
1
SD
2
ND
05
2
34
1
DT 11
5
DT 19
3
DT 48
_
-
-
-
-
-
r
-
-
-
-
-
-
-
-
-
-
-
-
-
-
r
-
-
-
-
SEPTEMBER 8-19, 1980 COMPOSITE SAMPLES (vG/L)
-------
CO
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
9
4
6
310
670
49
3
290
26
5
26
330
Spillway
1
8
38
71
1
10
East
Lagoon
7
West
Lagoon
1
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
1
DT 48
.
-
. -
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER 8-19, 1980 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
6
9
5
8
3
2
270
6
51
5
83
Spil Iway
2
18
1
36
East
Lagoon
1
3
5
3
West
Lagoon
2
1
2
Outlet
Lagoon
1
2
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER 8-19, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Tri methyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
2
730
71
9
5
18
Spillway
1
10
1
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
1
DT 48
_
_
_
_
_
_
_
_
_
_
_
..
_
_
_
_
_
_
_
_
-
SEPTEMBER 8-19, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
-Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
2-Chlorophenol
Chi orobhenyl ether
Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
3,3'-Dichlorobenzidine
-1,1-Di Chloroethane
-1,1-Di chloroethene
1,2-Di Chloroethane
-2 ,4-Di chl orophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
70
11
4
33
4
670
2
4
22
690
2
3
11
Spillway
9
2
1
42
8
85
East
Lagoon
3
2
4
West
Lagoon
2
1
1
Outlet
Lagoon
1
1
1
SD
1
4
ND
05
1
34
5
DT 11
2
DT 19
4
DT 48
.
-
-
.
-
-
2-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER 27 - OCTOBER 3, 1980 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
p- Aniline
|-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
190
3
4
400
1,200
31
8
3
1,200
51
18
15
870
Spillway
26
1
1
21
26
5
30
3
6
180
East
Lagoon
1
1
2
3
West
Lagoon
1
1
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
1
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER 27 - OCTOBER 3, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
3
19
13
12
5
100
5
3
32
18
110
Spillway
3
3
2
1
12
1
2
8
East
Lagoon
1
2
1
West
Lagoon
2
Outlet
Lagoon
1
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
'-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER 27 - OCTOBER 3, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thi ol )benzothi azol e
-Naphthol
-N ,N-Dimethylanil ine
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
1
270
.
32
14
7
47
Spi 11 way
1
*
6
1
East
Lagoon
West
Lagoon
Outlet
Lagoon
S_D
ND
£5
34
DT 11
1
DT 19
1
DT 48
_
_
_
_
_
_
_
_
..
..
.,
_
_
_
_
_
_
_
^
_
-
SEPTEMBER 27 - OCTOBER 3, 1980 COMPOSITE SAMPLES (UG/L) (CONTINUED)
-------
t\>
o
Priority Pollutants
-Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chi oronhenyl ether
Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di chloroethane
-1,1-Dichloroethene
-1, 2- Di chloroethane
-2 ,4-Di chl orophenol
-Di ethyl phthal ate
-2, 4-Di methyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
-Fl uoranthene
-Methyl chloride
Influent
42
6
6
1
510
2
4
11
760
1
4
20
Spillway
67
37
140
East
Lagoon
8
3
5
West
Lagoon
3
2
2
Outlet
Lagoon
5
1
1
SD
2
3
ND
05
1
34
3
DT 11
3
DT 19
2
DT 48
.
-
-
-
-
-
^
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
,
-
OCTOBER 6-17, 1980 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Tri chl orobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Al kyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Infl uent
84
1
2
7
500
490
81
4
2
580
46
66
20
1,300
Spil Iway
7
8
^
7
4
13
70
East
Lagoon
2
1
1
2
West
Lagoon
1
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
. -
-
-
_
-
-
.-
-
-
-
-
-
-
-
-
-
OCTOBER 6-17, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
ro
po
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
- 3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
2
97
64
32
18
1
130
6
9
18
96
Spillway
21
17
3
240
1
6
18
East
Lagoon
1
3
1
West
Lagoon
1
1
Outlet
Lagoon
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
r
-
-
-
-
-
-
-
-
-
-
V
-
-
-
-
r
.
-
-
-
-
-
r
-
OCTOBER 6-17, 1980 COMPOSITE SAMPLES (uG/L) (CONTINUED)
-------
ro
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- ( methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethylaniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
1
480
48
18
7
33
SpilTway
1
1
4
East
Lagoon
1
Hest
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
DT 48
_
_
_
i
_
_
_
_1
'_
. -!
^
_
_
_
_
^
OCTOBER 6-17, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
ro
Priority Pollutants
Acenaphthene
Acenaphthylene
Anthracene
-Benzene
Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl )phthal ate
-B romodi chl oromethane
Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
-Chl orophenyl ether
-Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1 , 1-Di chl oroethane
-1,1-Dichloroethene
-1,2-Di chl oroethane
-2,4-Dichlorophenol
-Diethyl phthalate
-2, 4-Di methyl phenol
Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
-Fl uoranthene
-Methyl chloride
Influent
34
6
270
3
690
1
3
34
990
2
4
Spillway
8
90
10
45
East
Lagoon
3
5
1
8
West
Lagoon
2
2
3
Outlet
Lagoon
2
1
2
SD
7
;
ND
05
8
34
2
DT 11
2
DT 19
2
DT 48
.
-
-
.
-
-
1-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
OCTOBER 20-31, 1980 COMPOSITE SAMPLES (pG/L)
-------
ro
en
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans-l,2-dichloroethylene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chi oromethyl benzene
Influent
100
2
2
140
390
3
27
30
6
4,600
15
210
93
190
Spillway
10
1
3
8
15
1
8
15
East
Lagoon
1
3
West
Lagoon
1
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
DT 48
-
7
;
'-
-
-
-
:-
-
-
-
.-
-
'.
'-
-
:
-
'-
-
-
'-
-
'-
-
OCTOBER 21-31, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
4
53
24
16
7
1
160
7
16
6
13
Spil Iway
8
7
8
1
1
6
East
Lagoon
2
5
2
3
West
Lagoon
2
1
1
Outlet
Lagoon
1
1
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
.-
-
.
.
-
-
-
.
-
.
-
-
-
-
-
OCTOBER 20-31, 1980 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
ro
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
N ,N-Dimethyl ani 1 i ne
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
19
3
6
11
Spillway
1
1
2
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
DT 48
'_
_
_
_
_
_
_
_
_^
_
.
_
_
_
_
_
_
_
i_
_
_
-
OCTOBER 20-31, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
ro
00
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
Bis(2-ethylhexyl)phthalate
-Bromodi chloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
Chi orobhenyl ether
-Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
Chrysene
1, 2- Di Chlorobenzene
-1,4-Di Chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1,1-Di chloroethene
1,2-Dichloroethane
-2,4-Dichlorophenol
-Di ethyl phthalate
-2, 4-Dimethyl phenol
-Dimethyl phthalate
-Di-n-butyl phthalate
Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
2
2
2
11
2
730
5
3
27
870
1
2
10
Spi 1 Iway
2
32
4
68
East
Lagoon
4
3
2
5
West
Lagoon
2
3
2
Outlet
Lagoon
1
2
1
SD
1
4
ND
05
1
34
1
DT 11
4
1
1
DT 19
2
1
1
DT 48
.
-
-
-
-
-
1 '
. -
- -
-
-
-
-
.-
-
-
-
-
-
-
-
-
-
-
NOVEMBER 3-14, 1980 COMPOSITE SAMPLES (yG/L)
-------
ro
UD
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans-l,2-dichloroethylene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
|-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chi oromethyl benzene
Influent
31
2
3
460
710
10
11
2
380
46
41
510
Spillway
2
1
2
8
1
15
6
42
East
Lagoon
1
1
8
West
Lagoon
2
Outl e't
Lagoon
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
_
-
-
-
-
-
. -
-
-
-
-
-
-
NOVEMBER 3-14, 1980 COMPOSITE SAMPLES (nG/L) (CONTINUED)
-------
CO
o
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
_biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
2
26
42
27
9
91
2
31
9
10
Spillway
3
9
8
3
8
2
8
East
Lagoon
1
6
2
1
3
West
Lagoon
3
1
2
Outlet
Lagoon
2
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
NOVEMBER 3-14, 1980 COMPOSITE SAMPLES (U3/L) (CONTINUED)
-------
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N ,N-Dimethylanil ine
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobi smethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
3
4
610
37
31
7
39
Spi llway
1
1
2
2
East
Lagoon
1
West
Lagoon
Outlet
Lagoon
SD
WD
05
34
DT 11
DT 19
DT 48
_
_
_
_
_
_
_
_
_
__
_
.
..
_\
-
_
_
_
_
_
_
_
_
_
-
NOVEMBER 3-14, 1980 COMPOSITE SAMPLES (wG/L) (CONTINUED)
-------
to
ro
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2- ethyl hexyl ) phthal ate
-B romodi chl oromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
-Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
2-Chloronaphthalene
-Chrysene
-1,2-Di Chlorobenzene
-1 ,4-Di chl orobenzene
-3,3'-Dichlorobenzidine
-1,1-Di chloroethane
-1 , 1-Di chl oroethene
-1,2-Di chloroethane
-2 ,4-Di chl orophenol
-Di ethyl phthal ate
2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
63
5
1
8
2
810
5
2
11
730
4
13
Spillway
3
96
3
270
East
Lagoon
2
3
8
West
Lagoon
4
3
2
Outlet
Lagoon
2
2
2
SD
1
4
ND
05
2
34
2
DT 11
5
1
1
DT 19
3
1
1
DT 48
_
-
-
-
-
-
1-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
'-
-
-
-
-
-
-
NOVEMBER 17-28, 1980 COMPOSITE SAMPLES (nS/L)
-------
CO
co
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
[-Aniline
[-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chloromethylbenzene
Influent
63
1
4
4
590
820
33
11
1
570
38
22
61
340
Spil Iway
6
1
1
2
4
1
3
1
3
4
21
East
Lagoon
1
2
3
West
Lagoon
2
Outlet
Lagoon
1
SD
ND
05
34
DT 11
1
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
NOVEMBER 17-28, 1980 COMPOSITE SAMPLES (wG/L) (CONTINUED)
-------
CO
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4- Di ethoxy benzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Me.thoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
3
11
9
19
7
2
87
4
5
27
11
25
Spillway
2
6
3
5
1
-
7
2
East
Lagoon
3
2
3
West
Lagoon
3
2
Outlet
Lagoon
2,
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
NOVEMBER 17-28, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
GO
en
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethylanil ine
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
1,300
41
9
5
22
Spillway
1
12
3
1
1
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
1
DT 19
DT 48
_
_
_
_
_
_
..
_
_
_
..
J
'_
_
_
_
__
_
__
,
-
NOVEMBER 17-28, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
CO
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chi orophenyl ether
-Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1 , 1-Di chl oroethane
-1 , 1-Di chl oroethene
-1,2-Di chl oroethane
2,4-Dichlorophenol
-Diethyl phthal ate
-2, 4-Di methyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
-Fluoranthene
Methyl chloride
Influent
1
9
7
2
510
1
4
24
6
1,300
1
1
17
1
Spillway
14
35
18
48
1
1
East
Lagoon
10
18
27
West
Lagoon
1
1
Outlet
Lagoon
SD
3
ND
4
3
05
1
34
DT 11
3
1
1
DT 19
1
1
DT 48
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
DECEMBER, 1980 COMPOSITE SAMPLES (nG/L)
-------
to
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethyl ene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
21
4
4
1
200
920
19
12
310
3
38
2,000
4
12
6
370
Spillway
2
2
21
1
1
4
2
2
72
1
10
1
13
East
Lagoon
37
1
1
1
1
1
8
1
20
West
Lagoon
2
3
Outlet
Lagoon
SD
1
ND
42
05
34
2
DT 11
1
DT 19
DT 48
.
-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
-
DECEMBER, 1980 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
GO
CO
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
9
53
29
3
1
49
200
3
1
23
Spillway
49
29
2
2
7
3
99
4
East
Lagoon
15
38
16
3
1
22
17
1
8
West
Lagoon
4
Outlet
Lagoon
SD
ND
1
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
.
-
-
-
.
'
DECEMBER, 1980 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
2
1
1,600
50
2
2
1
Spillway
2
99
13
13
4
4
East
Lagoon
1
1
9
5
2
1
West
Lagoon
1
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
_
._
* _
_
_
_
_;
_
_
_
v
«
' 1.
_
' '_
^
i
_
-_
_.
1_
_w
-
DECEMBER, 1980 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chi orophenyl ether
Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di Chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Dichloroethane
1,1-Dichloroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Di ethyl phthal ate
-2 ,4-Di methyl phenol
Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
96
6
93
1
2,000
55
270
1
11
76
Spi 1 Iway
9
1
150
15
150
1
East
Lagoon
60
49
West
Lagoon
1
3
Outlet
Lagoon
SD
1
5
1
ND
3
6
7
2
05
1
1
4
34
2
2
DT 11
2
1
1
1
DT 19
1
1
DT 48
_
-
-
-
-
'-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
JANUARY, 1981 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2,4 ,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
24
1
7
770
8,000
26
100
23
3
1,300
61
300
Spillway
2
49
22
2
10
2
1
43
16
10
East
Lagoon
13
5
2
1
1
9
8
West
Lagoon
10
Outlet
Lagoon
SD
1
1
ND
2
1
72
05
1
34
1
DT 11
1
DT 19
1
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
.-
-
-
-
-
-
-
-
JANUARY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
PO
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
12
140
84
3
32
350
5
2
30
51
7
Spil Iwa^y
38
37
1
17
79
2
8
East
Lagoon
21
10
2
3
8
4
West
Lagoon
3
4
Outlet
Lagoon
SD
ND
1
05
34
DT 11
DT 19
DT 48
-
'-
"-
-
-
-
-
-
'--
-
'-
-
-
-
-
-
-
-
-
.
-
-
'-
-
-
-
-
JANUARY, 1981 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
OJ
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothi ophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-NjN-Dimethylanil ine
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2- Pro pa no!
-Simazine
Substituted arizidine
-Substituted benzaldeh.yde
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
2
5
640
70
74
20
4
8
Spillway
1
56
7
29
5
1
3
East
Lagoon
8
14
6
West
Lagoon
1
Outlet
Lagoon
SD
ND
05
34
DT 11
'
DT 19
DT 48
_
. _
_
_
_
,_
_
. _
_.
'.'.
_
_
'_
_ .
_
_
_
rm
r
JANUARY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
-Acenaphthene
-Acenaphthylene
Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl )phthal ate
Bro modi chl oromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
Chi orophenyl ether
Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di chlorobenzene
-1 ,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1- Di chloroethane
-1 , 1-Di chl oroethene
1,2-Di chloroethane
-2 ,4-Di chl orophenol
-Diethyl phthalate
-2, 4-Di methyl phenol
Dimethyl phthalate
Di-n-butyl phthalate
-Ethylbenzene
Fluoranthene
Methyl chloride
Influent
54
1
4
370
7
2
2
14
26
2
Spillway
4
65
5
1
4
1
1
East
Lagoon
1
33
16
1
West
Lagoon
2
24
12
1
2
Outlet
Lagoon
SjD
2
ND
2
3
05
34
DT 11
DT 19
DT 48
__
-
-
:
-
-
.-
-
'
;
:-
-
.
-
r
.-
-
-
-
'
-
.-
:
'
FEBRUARY, 1981 COMPOSITE SAMPLES (yG/L)
-------
45.
en
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans-l,2-di chloroethyl ene
-Trichlorobenzene
-1,1, 1-Tri chl oroethane
-Trichloroethylene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
20
3
2
250
3,900
5
36
4
2,000
46
5
3
6
730
Spillway
7
1
48
7
1
6
14
24
13
54
East
Lagoon
4
10
2
2
2
15
51
West
Lagoon
1
1
1
19
Outlet
Lagoon
SD
8
ND
1
05
3
34
DT 11
DT 19
1
DT 48
-
.-
/-
-
'-
'.-
-
>
.-
. -
--
-
'-
- _
>
-
-
-
-
.:-
;-
.-
..-
-
.-..
-
FEBRUARY, 1981 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-Z^'-Diamino-S.S'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
6
8
42
12
11
9
38
Spillway
26
36
99
5
9
East
Lagoon
1
11
8
3
22
4
7
10
West
Lagoon
3
3
11
9
5
15
1
10
Outlet
Lagoon
SD
2
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
'-
-
-
-
'-
-
.-
-
-
-
-
',
-
-
-
FEBRUARY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4- Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
9
1,700
30
35
18
4
Spillway
2
25
17
7
East
Lagoon
2
1
4
9
18
6
1
West
Lagoon
13
1
Outlet
Lagoon
SD
NTJ
3
05
34
DT 11
DT 19
DT 48
_
_
_.
_
_
_
_
_
_
_
_
.
«
_
_
_
_
_
_
_
_
_
_
-
FEBRUARY, 1981 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
00
Priority Pollutants
Acenaphthene
-Acenaphthylene
-Anthracene
-Benzene
Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
-Chlorophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1,1-Dichloroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
1
1
2
181
2
2
351
4
13
5
1
2
541
1
1
7
2
3
391
1
1
2
3
3
Spill way
12
7
1
1
88
251
1
East
Lagoon
25
10
West
Lagoon
18
12
Outlet
Lagoon
SD
3
1
ND
2
2
05
34
DT 11
1
1
DT 19
DT 48
.
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
MARCH, 1981 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans-l,2-di chloroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichloroethylene
-2, 4, 6-Trichl orophenol
^-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chi oromethyl benzene
Influent
70
6
3
4
2
500
562
9
2
62
13
2
181
90
38
120
770
Spillway
1
1
65
13
1
4
3
1
151
381
East
Lagoon
12
2
1
1
53
11
48
West
Lagoon
14
1
7
Outlet
Lagoon
SD
1
ND
1
18C
05
34
DT 11
2
DT 19
10
.-
DT 48
._
.-
-
'.-
, -
.-
' ';.-
'. '
'. '
;
.-
.
'.
;'-
-
-
-.-
-
.-
.-
-
';-
-
.-
-
MARCH, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
cn
O
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
291
24
3
3
41
1
2
55
Spillway
7
22
*
35
1
5
2
East
Lagoon
1
22
16
7
6
1
12
West
Lagoon
1
1
1
1
5
Outlet
Lagoon
SD
1
1
ND
1
05
34
DT 11
DT 19
DT 48.
-
-
-
-
*
-
.-
-
r
'-
-
-
.:
-
-
-
'-
-
.;
' -.
-
.
'-
-
-
''-
MARCH, 1981 COMPOSITE SAMPLES (uG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyldibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thi ol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobi smethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
12
721
141
15
18
2
Spillway
4
9
43
4
8
5
East
Lagoon
2
2
8
1
8
West
Lagoon
Outlet
Lagoon
SD
1
1
ND
3
2
£5
34
DT 11
DT 19
DT 48
_
_
_
_
-
_
_
_
j
^.
_
_
_
_
_
_
_
_
_
-
MARCH, 1981 COMPOSITE SAMPLES (pG/L) (CONTINUED)
-------
en
ro
Priority Pollutants
-Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
-B romodi chl oromethane
-Butyl benzyl phthal ate
-Chlorobenzene
2-Chlorophenol
-Chl orobhenyl ether
-Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di Chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di Chloroethane
-1 , 1-Di chl oroethene
-1,2-Dichloroethane
2,4-Dichlorophenol
-Diethyl phthal ate
-2, 4-Di methyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
Fluoranthene
-Methyl chloride
Influent
62
5
66
2
3
561
3
1
3
2,610
1
140
Spillway
2
5
38
160
East
Lagoon
West
Lagoon
3
7
Outlet
Lagoon
SD
3
ND
3
05
1
3
34
DT 11
1
1
DT 19
DT 48
-_
.--
.;
\.
.-'.-
.-
-
'.'
'
>
'
;
'-
;-
V
.-
.'-
';-
.-
!.-
"'-
;.'-
\-
_"
\-
-
-.'.-
;-
_-
APRIL, 1981 COMPOSITE SAMPLES (yG/L)
-------
CO
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
171
3
1
851
9,300
88
94
5,600
5
56
28
9
180
Spillway
4
1
20
9
3
1
130
28
10
East
Lagoon
2
4
11
West
Lagoon
2
2
2
6
4
Outlet
Lagoon
SD
1
ND
28
05
18
34
DT 11
DT 19
DT 48
-
.
-
':
'-
-
'-
-
-
"
'.
'-
-
-
-
-
-
-
'-
-
-
.-
-
APRIL, 1981 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
61
37
40
2
47
1
5
331
8
26
10
43
Spillway
32
35
5
1
1
15
1
East
Lagoon
15
West
Lagoon
10
.
Outlet
Lagoon
26
5
SD
ND
1
1
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
'-
-
'-
-
-
-
-
'-
-
-
.
-
-
-
-
-
-
. -
APRIL, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
en
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N ,N-Dimethyl ani 1 i ne
-N-Phenylaniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
4
1,400
42
3
11
3
240
38
15
Spillway
160
8
9
9
7
9
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
1
1
ND
1
£5
34
DT 11
DT 19
DT 48
_
_
_.
_
'_
_
_
_
..
^
_
_
_
_
_
_
_,
_
-
APRIL, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
cr>
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2- ethyl hexyl ) phthal ate
-Bromodichloromethane
-Butyl benzyl phthal ate
Chlorobenzene
2-Chlorophenol
-Chi orophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di chloroethane
-1,1-Dichloroethene
-1,2-Di chloroethane
-2 ,4- Di chl orophenol
-Diethyl phthal ate
-2, 4-Dimethyl phenol
Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
53
3
840
1
1
8
420
1
1
1
Spillway
3
61
260
East
Lagoon
2
2
West
Lagoon
5
3
Outlet
Lagoon
2
2
SO
3
ND
3
05
34
DT 11
1
1
DT 19
. 1
1
DT 48
_
-
-
.-
-
-
.-
-
-
.
-
1-
-
-
-
-
-
-
-
MAY, 1981 COMPOSITE SAMPLES (pG/L)
-------
en
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2 ,4 ,6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chloromethylbenzene
Influent
2
1
4
400
2,600
10
330
44
1
5,900
6
51
7
180
Spillway
8
14
2
1
6
3
130
1
3
2
East
Lagoon
2
2
1
1
West
Lagoon
1
4
5
3
1
3
Outlet
Lagoon
2
1
1
SD
1
ND
2
2
£5
34
DT 11
2
DT 19
17
1
'
..':
DT 48
.
' -
-
-
-
3 '
-
-
-
'-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
-
MAY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
00
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 ,4-Di ethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3 ,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
6
2
57
42
1
1
240
10
13
1
11
1
Spillway
7
29
1
East
Lagoon
9
2
West
Lagoon
12
3
Outlet
Lagoon
8
1
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
MAY, 1981 COMPOSITE SAMPLES (PG/L) (CONTINUED)
-------
en
vo
Additional Org. Chem. (Cont'd)
-4-Methyldibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thi ol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sul fonyl bi smethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobi smethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
8
7
1
1,900
1
290
11
3
Spillway
93
25
East
Lagoon
2
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48-
_
_
_
_
'_
_.
_
_
_
_
~\
_
_
_
1
-1
1
i
__
_
_
_
1
MAY, 1981 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
Acenaphthylene
Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
Bi s( 2- ethyl hexyl ) phthal ate
Bromodi chloromethane
-Butyl benzyl phthal ate
Chlorobenzene
-2-Chlorophenol
Chlorophenyl ether
-Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
Chrysene
-1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Di Chloroethane
-1 , 1-Di chl oroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Di ethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
Ethyl benzene
-Fluoranthene
Methyl chloride
Influent
74
39
2
9
940
2
6
1
11
17
5
470
1
2
1
1
1
23
530
Spillway
3
15
52
1
60
23
East
Lagoon
1
1
1
West
Lagoon
23
50
12
Outlet
Lagoon
1
SD
2
ND
2
1
05
34
DT 11
DT 19
7
1
2
DT 48
. ^
-
-
:
.
-
-
-
-
-
-
-
JUNE, 1981 COMPOSITE SAMPLES (MG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
64
4
2
1
2,500
25
510
200
18,000
19
150
6
300
Spillway
8
41
1
27
1
78
7
86
East
Lagoon
2
2
West
Lagoon
3
39
Outlet
Lagoon
1
2
1
SD
2
ND
1
8
05
1
34
1
DT 11
DT 19
1
DT 48
-
-
._ -
-
-
-
-
'-
-
v. -
-
.
-
. -
'-
3.-
-
.' -
'.-
. -
' -
-
JUNE, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
ro
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Diisopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
11
17
36
15
1
32
21
2
Spil Iway
5
9
4
East
Lagoon
2
7
7
Rest
Lagoon
16
1
1
Outlet
Lagoon
7
SD
W)
05
34
DT 11
^
DT 19
DT 48
:-
'-
-
;-
-
.'.-
-
-
-
-
-
r
f
-
-
.-
.
-
-
-
' T
.-
-
-
JUNE, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N,N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tri butyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
3
28
10
1,600
210
20
25
5
Spillway
57
2
9
East
Lagoon
West
Lagoon
1
1
3
Outlet
Lagoon
SD
ND
05
34
1
DT 11
1
DT 19
DT 48
-
^
-
_
_
_
_
'_
_
1-
_
_
*.
_
__
1
H
i
1
_
-
_
_
1
JUNE, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
Bi s( 2-ethyl hexyl )phthal ate
Bro modi chl oromethane
-Butyl benzyl phthalate
-Chlorobenzene
2-Chlorophenol
Chlorobhenyl ether
Chloroethane
-Chloroform
4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
1,2-Di Chlorobenzene
-1 ,4-Di chl orobenzene
3,3'-Dichlorobenzidine
-1,1-Di chloroethane
1 , 1-Di chl oroethene
-1,2-Dichloroethane
2,4-Dichlorophenol
-Di ethyl phthalate
2, 4-Di methyl phenol
-Dimethyl phthalate
Di-n-butyl phthalate
-Ethylbenzene
-Fluqranthene
-Methyl chloride
Influent
76
29
1
2
1,100
3
1
16
8
56
2
6
Spillway
4
130
2
190
1
East
Lagoon
4
^
4
West
Lagoon
13
20
Outlet
Lagoon
1
SD
2
ND
2
05
34
DT 11
1
DT 19
1
DT 48
_
-
-
-
-
-
-
-
-
-
-
-
-
.-
-
-.-
-
-
-
-
-
-
-
-
-
-
JULY, 1981 COMPOSITE SAMPLES (yG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
i
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Infl uent
26
590
450
13
170
11
4
580
22
610
3
Spillway
7
57
23
2
31
2
830
5
81
East
Lagoon
2
1
1
West
Lagoon
9
1
3
23
Outlet
Lagoon
1
SD
ND
05
34
1
DT 11
1
DT 19
DT 48
.
-
-
-
-
-
-
1 -
-
'-
. -
-
-
.
-
-
-
-
-
-
-
-
-
-
. -
JULY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
cn
Additional Org. Chem. (Cont'd)
-Cresol
-Z^'-Diamino-a.a'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychl orobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3,4-Dimethylphenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepi n-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
95
19
7
1
2
Spillway
18
14
3
East
Lagoon
2
West
Lagoon
25
3
2
Outlet
Lagoon
2
SD
ND
05
34
DT 11
DT 19
DT 48
,-
.-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
.
-
-
.-
.
-
JULY, 1981 COMPOSITE SAMPLES (PG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothi ophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethylaniline
-N-Phenylam'line
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
4
160
1
6Q
2
1
Spillway
230
12
East
Lagoon
West
Lagoon
1
Outlet
Lagoon
SD
NTJ
05
34
DT 11
1
DT 19
DT 48
_
_
_
_
_
_
_
_
_
_
«
_
__
-
.
_
_
_;
J
"
JULY, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
cr>
oo
Priority Pollutants
Acenaphthene
Acenaphthylene
Anthracene
Benzene
:Benzo (a) anthracene
-Benzo (a) pyrene
Bi s( 2-ethyl hexyl )phthal ate
Bromodichloromethane
Butyl benzyl phthalate
-Chlorobenzene
2-Chlorophenol
-Chlorophenyl ether
Chloroethane
Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaph.thalene
-Chrysene
-1,2-Di chlorobenzene
-1,4-Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1- Di chloroethane
1,1-Dichloroethene
-1,2-Di chloroethane
2,4-Dichlorophenol
-Diethyl phthalate
2, 4-Di methyl phenol
-Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
110
9
3
530
5
6
98
1
1
14
Spillway
16
4
31
East
Lagoon
1
West
Lagoon
15
13
Outlet
Lagoon
1
SD
2
*"
ND
2
05
34
DT 11
DT 19
DT 48
_
-
-
-
-
-
-
-
-
-
*
-
-
-
-
-
-
-
-
-
-
-
-
-
AUGUST, 1981 COMPOSITE SAMPLES (yG/L)
-------
CT>
IO
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachlorophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans-l,2-dichloroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2,4,6-Trichlorophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chi oromethyl benzene
Influent
1
1,600
11,000
6
96
15
4,800
27
9
700
Spillway
1
8
33
2
14
19
300
East
Lagoon
1
6
West
Lagoon
9
3
1
37
Outlet
Lagoon
1
1
SD
ND
1
05
34
DT 11
DT 19
1
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
-
AUGUST, 1981 COMPOSITE SAMPLES (vG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dich1oro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl etna none
-Diisopropoxychlorobenzene .
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4- Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
3
43
28
24
25
10
280
Spillway
3
9
16
22
10
2
3
190
East
Lagoon
2
1
West
Lagoon
28
3
5
Outlet
Lagoon
2
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
.
-
-
-
-
-
AUGUST, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothi ophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothiazole
-Naphthol
-N,N-Dimethylaniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 1 1 i n
-Xyl ene
Influent
3
39
3,100
48
20
11
3
Spillway
10
1
18
4
2
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
34
DT 11
DT 19
DT 48
-
_
^
_
_
-.
_
_
_
_
..
_.
..
.
__
^
_;
__
__
_
^
_
-
AUGUST, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
-Bi s( 2-ethyl hexyl ) phthal ate
Bromodichloromethane
-Butyl benzyl phthal ate
-Chlorobenzene
-2-Chlorophenol
Chlorophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
Chrysene
1, 2- Di chlorobenzene
-1, 4- Di chlorobenzene
-3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1 , 1-Di chl oroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Di ethyl phthal ate
-2, 4-Dimethyl phenol
-Dimethyl phthal ate
-Di-n-butyl phthal ate
-Ethylbenzene
-Fluoranthene
-Methyl chloride
Influent
440
97
930
7
190
6
470
3
9
2
Spi 1 Iway
130
74
56C
77
4
l.OOC
East
Lagoon
1
West
Lagoon
8
10
Outlet
Lagoon
7
3
SD
2
NO
2
05
34
DT 11
DT 19
DT 48
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER, 1981 COMPOSITE SAMPLES (pG/L)
-------
CO
Priority Pollutants (Cont'd)
-Methyl ene chloride
7Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Infl uent
4
1
4
500
5,200
13
4
99
16
9
13,000
1
180
29
510
Spillway
1
340
450
8
58
19
28,000
8
62
170
East
Lagoon
4
2
19
West
Lagoon
5
1
4
Outlet
Lagoon
7
1
3
2
SD
ND
2
1
05
3
34
DT 11
DT 19
1
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
-
SEPTEMBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 ,4-Di ethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
12
1,300
75
51
19
39
4
Spillway
2
1,000
53
35
9
7
11
18
East
Lagoon
2
1
West
Lagoon
13
5
4
Outlet
Lagoon
5
1
3
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
.
-
-
-
-
-
SEPTEMBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
en
Additional Org. Chem. (Cont'd)
-4- Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N.N-Dimethyl aniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
--Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
12
54
1,500
87
8
21
6
Spillway
5
6
14,000
-
100
24
10
East
Lagoon
West
Lagoon
Outlet
Lagoon
SD
ND
05
2
34
DT 11
DT 19
2
DT 48
_
_
_
_
_
_
_
_
_
_
..
~\
M
_
_
_
__
_
_
_
-
SEPTEMBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
cr>
Priority Pollutants
Acenaphthene
Acenaphthylene
-Anthracene
-Benzene
-Benzo (a) anthracene
-Benzo (a) pyrene
-Bi s( 2-ethyl hexyl )phthal ate
-Bromodichloromethane
-Butyl benzyl phthalate
Chlorobenzene
-2-Chlorophenol
Chi orophenyl ether
-Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1, 2- Di chlorobenzene
-1, 4- Di chlorobenzene
3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1 , 1-Di chl oroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Diethyl phthalate
-2, 4-Dimethyl phenol
Dimethyl phthalate
-Di-n-butyl phthalate
-Ethylbenzene
Fluoranthene
-Methyl chloride
Infl uent
440
28
1
1
1
1,000
59
6
11
120
2
1
2
1
8
Spillway
28
13
150
13
1
51
1
1
5
East
Lagoon
1
3
West
Lagoon
27
5
2
2
Outlet
Lagoon
14
5
1
SD
2
ND
1
05
34
DT 11
1
DT 19
DT 48
_
-
-
.
-
-
_-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
OCTOBER, 1981 COMPOSITE SAMPLES (vG/L)
-------
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Tol uene
-Trans- 1 ,2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Tri chl oroethyl ene
-2, 4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetaniline
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Influent
15
3
1
3
390
1,400
13
250
29
4
32
51
130
27
1
4
55
Spillway
1
2
94
19
3
16
8
2
5,700
13
62
1
93
East
Lagoon
2
7
West
Lagoon
4
57
3
2
3
1
1
59
Outlet
Lagoon
8
1
3
2
1
1
SD
1
ND
2
05
5
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
~
.
-
-
-
-
-
-
-
-
-
-
-
-
OCTOBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
Additional Org. Chem. (Cont'd)
-Cresol
-Z^'-Diamino-S.S'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
- 1 , 4-Di ethoxybenzene
-Di ethoxychl orobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylanil ine
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
24
25
30
35
5
10
25
10
14
51
15
Spillway
3
45
39
15
44
5
4
17
11
86
East
Lagoon
5
4
2
West
Lagoon
1
15
14
4
15
22
Outlet
Lagoon
12
5
SD
ND
05
34
DT 11
DT 19
DT 48
-
-
-
-
-
-
-
-
-
.-
-
-
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
OCTOBER, 1981 COMPOSITE SAMPLES (nG/L) (CONTINUED)
-------
IO
Additional Org. Chem. (Cont'd)
4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- ( methyl thiol )benzothiazole
-Naphthol
-N ,N- Dimethyl anil ine
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzaldehyde
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Van i 11 i n
-Xyl ene
Influent
13
39
1,000
17
95
28
24
Spillway
3
13
96
1
9
33
10
4
East
Lagoon
1
West
Lagoon
2
40
4
18
1
Outlet
Lagoon
1
7
1
SD
NT)
05
34
DT 11
DT 19
1
DT 48
-
_
_
_
_
_
'
_
'
1
'.
.
J
J
_
-1
_
_
* _
_
_
OCTOBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
Priority Pollutants
Acenaphthene
Acenaphthylene
Anthracene
Benzene
Benzo (a) anthracene
Benzo (a) pyrene
Bis(2-ethylhexyl ) phthalate
-Bromodichloromethane
-Butyl benzyl phthalate
-Chlorobenzene
-2-Chlorophenol
-Chl orophenyl ether
Chloroethane
-Chloroform
-4-Chl oro- 3-methyl phenol
-2-Chloronaphthalene
-Chrysene
-1,2-Di chlorobenzene
-1 ,4-Di chl orobenzene
3,3'-Dichlorobenzidine
-1,1-Dichloroethane
-1 , 1-Di chl oroethene
-1,2-Dichloroethane
-2,4-Dichlorophenol
-Diethyl phthalate
-2, 4-Di methyl phenol
-Dimethyl phthalate
-Di-n-butyl phthalate
Ethylbenzene
-Fluoranthene
-Methyl chloride
i
Influent
96
2
5
1
590
2
1
18
5
61
1
4
1
18
2
7
Spi 1 Iway
9
1
140
4
1
26
1
1
3
1
East
Lagoon
3
West
Lagoon
6
49
10
Outlet
Lagoon
13
2
SD
2
NO
2
05
2
34
DT 11
3
DT 19
3
DT 48
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
NOVEMBER, 1981 COMPOSITE SAMPLES (yG/L)
-------
00
Priority Pollutants (Cont'd)
-Methyl ene chloride
-Naphthalene
-Pentachl orophenol
-Phenanthrene
-Phenol
-Pyrene
-Tetrachloroethylene
-Toluene
-Trans- 1 , 2-di chl oroethyl ene
-Trichlorobenzene
-1,1,1-Trichloroethane
-Trichl oroethyl ene
-2 ,4, 6-Tri chl orophenol
-Vinyl chloride
Additional Organic Chemicals
-Acetanil ine
-Acetone
-Acetovanillone
-Alkyl substituted benzenes
-Aniline
-Atrazine
-Azobenzene
-Benzaldehyde
-Benzyl alcohol
-Butyl benzene
-Carbon disulfide
-2-Chloroaniline
-Chl oromethyl benzene
Infl uent
6
2
3
1
190
910
6
1
150
13
45
2,200
15
140
210
11
230
Spillway
10
1
44
46
2
68
6
1,100
25
63
East
Lagoon
1
1
7
3
West
Lagoon
16
5
36
88
Outlet
Lagoon
2
16
3
SD
1
ND
1
1
05
34
DT 11
DT 19
DT 48
.
-
-
-
'
-
-
-
-
-
-
-
.
-
-
-
. -
-
-
-
-
-
-
-
NOVEMBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
00
ro
Additional Org. Chem. (Cont'd)
-Cresol
-2,4'-Diamino-3,3'-dichloro-
biphenyl
-2,2-Dichloroazobenzene
-1,4-Diethoxybenzene
-Diethoxychlorobenzene
-Di hydroxyphenyl ethanone
-Di i sopropoxychlorobenzene
-Dimethoxybenzene
-3,4-Dimethoxyphenol
-3, 4-Dimethyl phenol
-Dimethyl benzaldehyde
-Dimethyl disulfide
-Dimethyl naphthalenes
-Dimethyl oxetane
-1,4-Dioxane
-N-Ethylaniline
-2-Ethoxypropane
-Ethyl aniline
-Ethyl phenol
-Hexahydroazepin-2-one
-IH-Indole
-Isopropylidene dioxyphenol
-Methanethiol
-2-Methoxyaniline
-Methoxyethoxyethene
-2-Methoxyphenol
-Methyl aniline
-3-Methyldibenzothiophene
Influent
10
71
88
29
1
23
1
4
17
23
Spillway
1
30
53
22
11
4
17
9
3
East
Lagoon
8
8
West
Lagoon
1
25
49
24
2
37
Outlet
Lagoon
8
1
1
SD
ND
05
34
DT 11
DT 19
DT 48
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
.
-
.
-
-
-
.
-
NOVEMBER, 1981 COMPOSITE SAMPLES (uG/L) (CONTINUED)
-------
CO
CO
Additional Org. Chem. (Cont'd)
-4-Methyl dibenzothiophene
-Methyl naphthalenes
-Methyl phenanthrenes
-2- (methyl thiol )benzothi azol e
-Naphthol
-N.N-Dimethylaniline
-N-Phenyl aniline
-Phenylethanone
-Phthalic acid
-2-Propanol
-Simazine
-Substituted arizidine
-Substituted benzoic acids
-Substituted indene
-Substituted naphthalenes
-Substituted naphthothiophenes
-Substituted phenanthrenes
-Substituted triazine
-Substituted vanillin
-Sulfonylbismethane
-Tetrahydrofuranmethanol acetate
-Tetramethyl butyl phenol
-Thiobismethane
-Tributyl phosphate
-Trimethyl naphthalenes
-Trimethyl phenanthrenes
-Vanillin
-Xyl ene
Influent
17
10
35
1
11
160
33
2
5
Spillway
4
4
9
1,100
38
38
11
6
East
Lagoon
10
West
Lagoon
6
39
12
22
Outlet
Lagoon
1
2
9
SD
ND
1
05
1
34
DT 11
DT 19
DT 48
_
_
_
_
_
_
_
_
._
_
_
_
_
_
_
_
_
-
NOVEMBER, 1981 COMPOSITE SAMPLES (yG/L) (CONTINUED)
-------
WELL SAMPLES
184
-------
Well Samples
USGS Wells
Date
2-02-80
5-31-80
9-05-80
9-20-80
11-06-80
11-25-80
4-17-81
1-21-81
2-04-81
7-09-81
Well Number
USGS
USGS
USGS
USGS
USGS
USGS
USGS
USGS
USGS
USGS 1
Concentration
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
No Detectable Compounds
4-06-80
5-01-80
7-08-80
7-28-80
8-08-80
8-20-80
10-24-80
10-07-80
Lagoon Seepage Wells
LS34-C3
17A
5B2
1B2
1B2
4B2
6B2
LS33-B2
No Detectable
No
No
No
No
Detectable
Detectable
Detectable
Detectable
No Detectable
No Detectable
No Detectable
Compounds
Compounds
Compounds
Compounds
Compounds
Compounds
Compounds
Compounds
2B2
6-13-80
Priority Pollutants
1,2-Dichloroethane
No other compounds detected
3B2
6-27-80
Priority Pollutants
1,2-Dichloroethane
No other compounds detected
LS34-C2
3-10-80
Priority Pollutants
Benzene
1,2-Dichloroethane
Concentration (pg/1)
5
11
53
185
-------
LS34-C2 (Cont'd) 3-10-80
Additional Organic Compounds
2-Chloroaniline
Tributyl phosphate
N,N-Dimethyl aniline
No other compounds detected
Concentration (yg/1)
210
8
8
WELLS
LS33-82
12-09-80
Additional Organic Compounds
Di chloroazobenzene
No other compounds detected
LS31-B2
10-20-80
Priority Pollutants
Chloroform
1,2-Dichloroethane
Di-n-butyl phthalate
Bis(ethylhexyl)phthalate
Additional Organic Compounds
Di chloroazobenzene
No other compounds detected
LS34-C2
1-06-81
Priority Pollutants
1,2-Dichloroethane
Bis(ethylhexyl)phthalate
Benzene
Additional Organic Compounds
2-Chloroaniline
LS1-B2 2-19-81
Priority Pollutants
Chloroethane
1,2-Dichloroethane
Di-n-butyl phthalate
6
10
1
2
83
4,400
8
2,400
1
1
2
186
-------
LS1-B2 (Cont'd) 2-19-81
Additional Organic Compounds Concentration (yg/1)
Cresol 1
Methyl aniline 2
Ethyl aniline 3
No other compounds detected
3B2 5-19-81
Priority Pollutants
1,2-Dichloroethane 17
1,1,1-Trichloroethane 2
Tetrachloroethylene 1
Chloroethane 2
Additional Organic Compounds
Carbon disulfide 1
Tetrahydrofuran* 11
* Plastic well, compound found in PVC Cement
34-C2 5-29-81
Priority Pollutants
Chloroform / 4
1,2-Dichloroethane 10
1,1,1-Trichloroethane 1
Benzene 1
Tetrachloroethylene 1
Additional Organic Compounds
2-Chloroaniline 600
LS31-B2 3-24-81
Priority Pollutants
Chloroform 2
Naphthalene 1
Di-n-butyl phthalate 2
Additional Organic Compounds
Acetone* 34
Tetrahydrofuran* 38
187
-------
LS31-B2 (Cont'd) 3-24-81
Additional Organic Compounds (Cont'd)
Carbon disul fide
Ani 1 i ne
2-Chloroaniline
* Plastic well, compounds found in PVC Cement
LS1-B2 3-11-81
Priority Pollutants
Toluene
Naphthalene
Di-n-butyl phthalate
Additional Organic Compounds
Methyl aniline
Ethyl aniline
Concentration (u9/1)
2
1
2
6
1
3
Well Group
USGS 2
2B2
IB 2
Monitoring Wells
Date
7/81
7/81
8/81
Compound and Concentration (yg/1)
No detectable compounds
Chloroethane
1,2-Dichloroethane
Tetrachloroethylene
Toluene
8
3
3
9
Chloroethane 8
Trans-1,2-dichloroethylene 1
Trichloroethylene 1
WELLS
2B2
7-81
Priority Pollutants
Chloroethane
1,2-Dichloroethane
Tetrachloroethylene
Toluene
Concentration (yg/1)
8
3
26
9
188
-------
2B2 (Cont'd) 7-81
Additional Organic Compounds Concentration (ug/1).
No other compounds detected
1B2 8-81
Priority Pollutants
Chloroethane 8
Trans-l,2-dich1oroethylene 1
Trichloroethylene . 1
Additional Organic Compounds
No other compounds detected
4B2 9-81
Priority Pollutants
Not detected, 1 pg/1
Additional Organic Compounds
Not detected
5B2 10-81
Priority Pollutants
Not detected, 1 yg/1
Additional Organic Compounds
Not detected
6B2 11-81
Priority Pollutants
Not detected, 1 yg/1
Additional Organic Compounds
Not detected
189
-------
LAGOON SEEPAGE NELL SAMPLES
190
-------
New Lagoon Seepage Wells
5/81
A-l
70 ft
Priority Pollutant^ yg/1
Not detected at 1 g/1
Additional Organic Compounds
2-Chloroaniline 1
Substituted Benzene 1
Isopropylidenedioxyphenol 3
Vanillin 1
A-2
50 ft
Priority Pollutants
Not detected at 1 g/1
Additional Organic Compounds
Not detected
A-3
30 ft
Priority Pollutants
Not detected at 1 g/1
Additional Organic Compounds
Isopropylidenedioxyphenol 2
2-Chloroaniline 113
B-l
50 ft
Priority Pollutants
Trans-l,2-dichloroethane 1
Bis(ethylhexyl)phthalate 6
191
-------
New Lagoon Seepage Wells
5/81
Continued
Additional Organic Compounds ug/1
M-Phenylacetamide 3
Ethyl aniline 7
2-Chloroaniline 250
N,N-Dimethylaniline 6
B-2
40 ft
Priority Pollutants
1,1-Dichloroethane 1
Diethyl phthalate 1
Additional Organic Compounds
Isopropylidene dioxyphenol 1
Methyl aniline 2
Ethyl aniline 8
2-Chloroaniline 22
Trimethyltriazene-trione 7
Atrazine 2
Priority Pollutants
Diethyl phthalate 1
Bis(ethylhexyl)phthalate 20
Additional Organic Compound^
Isopropylidene dioxy phenol 2
Methyl aniline 10
2rChloroaniline 80
Trimethyl triazene-trione 2
Atrazene 1
.192
-------
New Lagoon Seepage Wells
5/81
C-l
70 ft
Priority Pollutants yg/1
Di-n-butyl phthalate 1
Additional Organic Compounds
Not detected
C-2
50 ft
Priority Pollutants
Tetrachloroethylene
Additional Organic Compounds
Not detected
C-3
30 ft
Priority Pollutants
None
Additional Organic Compounds
Isopropylidene dioxyphenol 6
Methyl aniline 1
2-Chloroaniline 29
D-l
70 ft
Priority Pollutants
Tetrachloroethylene 18
Di-n-butyl phthalate 3
Bis(ethylhexyl)phthalate 430
193
-------
New Lagoon Seepage Wells
5/81
D-l
70 ft
Continued
Additional Organic Compounds yg/1
Not detected
D-2
50 ft
Priority Pollutants
Not detected at 1 g/1
Additional Organic Compounds
Not detected
D-3
30~Tt
Priority Pollutants
1,2-Dichloroethane x 9
Tetrachloroethylene 92
Toluene 2
Additional Organic Compounds
Isopropylidene dioxyphenol 1
2-Chloroaniline 160
Methyl aniline 2
Tributyl phosphate 1
N,N-Dimethyl aniline 4
Trimethyltriazene-trione 1
194
-------
New Lagoon Seepage Wells
9-81
A-2
50 ft
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
Tributyl phosphate 1
Di-n-butyl phthalate 18
A-3
30~7t
Priority Pollutants
Not detected
Additional Organic Compounds
Methyl aniline 11
2-Chloroaniline 170
Tributyl phosphate 8
Di-n-butyl phthalate 2
B-l
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
2-Chloroaniline 28
B-2
40 ft
Priority Pollutants
Not detected
195
-------
New Lagoon Seepage Wells
9/81 (Cont'd)
B-2 (Cont'd)
Additional Organic Compounds yg/1
Methyl aniline 4
2-Chloroaniline 45
Tributyl phosphate 2
Substituted triazine 2
B-3
30 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Methyl aniline 2
2-Chloroaniline 25
C-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
C-2
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
196
-------
New Lagoon Seepage Wells
9/81 (Cont'd)
C-3
30~7t
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
2-Chloroaniline 47
Tributyl phosphate 9
D-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
D-2
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
197
-------
New Lagoon Seepage Wells
9/81 (Cont'd)
D-3
30 ft
Priority Pollutants yg/1
1,2-Dichloroethane 7
Additional Organic Compounds
2-Chloroaniline 83
Tributyl phosphate 2
N,N-Dimethyl aniline ' . 3
198
-------
' -New"Lagoon "Seepage-Wells
10/81
A-2
50 ft
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
2-Chloroaniline 2
A-3
30 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Methyl aniline 7
2-Chloroaniline 29
Isopropylidine dioxy phenol 1
B-l
Priority Pollutants
Not detected
Additional Organic Compounds
2-Chloroaniline 39
N,N-Dimethyl aniline 4
B-2
40 ft
Priority Pollutants
Not detected
199
-------
New. Lagoon Seepage -'Wells.7
10/81 (Cont'd)
B-2 (Cont'd)
Additional Organic Compounds yg/1
Methyl aniline 4
2-Chloroaniline 19
Substituted triazine 5
B-3
30 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Methyl aniline 2
2-Chloroaniline 77
Substituted triazine 3
C-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
C-2
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
200
-------
Mew Lagoon- Seepage WelTs
10/81 (Cont'd)
C-3
30-ft
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
Methyl aniline 2
2-Chloroaniline 44
Isopropylidine dioxy phenol 1
D-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
D-2
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
D-3
30 ft
Priority Pollutants
1,2-Dichloroethane 8
Additional Organic Compounds
2-Chloroaniline 74
201
-------
. New Lagoon. Seepage Wel.ls
11/81
A-2
50 ft
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
Not detected
A-3
30 ft
Priority Pollutants
Not detected
Additional Organic Compounds
2-Chloroaniline 260
Isopropylidine dioxy phenol 2
B-l
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
2-ChloroamTine 360
N,N-Dimethyl aniline 3
B-2
40 ft
Priority Pollutants
Not detected
202
-------
New Lagoon Seepage Wells
11/81 (Cont'd)
B-2 (Cont'd)
Additional Organic Compounds yg/1
2-Chloroaniline 19
Substituted triazine 6
B-3
30 ft
Priority Pollutants
Not detected
Additional Organic Compounds
2-Chloroaniline 6
Isopropylidine dioxy phenol 1
C-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
C-2
WTt
Priority Pollutants
Not detected
Additional Organic Compounds
Phthalate 16
203
-------
New Lagoon Seepage- Wells
11/81 (Cont'd)
C-3
30 ft
Priority Pollutants yg/1
Not detected
Additional Organic Compounds
2-Chloroaniline 37
Isopropylidine dioxy phenol 1
D-l
70 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
D-2
50 ft
Priority Pollutants
Not detected
Additional Organic Compounds
Not detected
D-3
30 ft
Priority Pollutants
1,2-Dichloroethane 5
Additional Organic Compounds
2-Chloroaniline 140
N,N-Dimethyl aniline 2
204
-------
Lagoon Seepage Study
Chlorinated Aromatic Amines
(6/81)
Concentration (yg/1 )
Well
A-l
A- 2
A- 3
B-l
B-2
B-3
C-l'
C-2
C-3
D-l
D-2
D-3
34-C2
2-Chloro-
anil ine
Dry
9
300
190
190
70
< 1
< 1
63
< 1
< 1
160
190
3,3'-
benzi
<
<
<
<
<
<
<
<
<
<
<
<
<
Dichloro-
dine
1
1
1
1
1
1
1
1
1
1
1
1
1
2,4'-Diamino-
3,3'-dich1oro-
biphenyl
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
205
-------
Lagoon Seepage Study
Chlorinated Aromatic Amines
Well
A-l
A- 2
A- 3
B-l
B-2
B-3
C-l
C-2
C-3
D-l
D-2
D-3
34-C2
2-Chloro-
ani 1 ine
Dry
7
420
195
180
90
1
1
59
1
< 1
180
240
(7/81)
Concentration (
!yg/i)
2,4'-Diamino-
3,3'-Dichloro- 3,3'-dichloro-
benzidine biphenyl
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< i
< i
< i
< i
< i
< i
< i
< i
< i
< i
< i
< i
< i
206
-------
Lagoon Seepage Study
Chlorinated Aromatic Amines
Well
A-l
A- 2
A- 3
B-l
B-2
B-3
C-l
C.-2
C-3
D-l
D-2
D-3
34-C2
2-Chloro-
aniline
Dry
4
510
230
210
100
1
1
69
< 1
< 1
170
210
(8/81)
Concentration (yg/1 )
3,3'-Dichloro-
benzidi ne
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
2,4'-Diamino-
3,3'-dichloro-
biphenyl
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
207
-------
Lagoon Seepage Study
Well
A-l
A- 2
A- 3
B-l
B-2
B-3
C-l
C-2
C-3
D-l
D-2
D-3
34C2
2-Chloro-
aniline
Dry
3
140
29
55
25
< 1
< 1
49
< 1
<1
85
120
Chlorinated Aromatic Amines
Concentration (9/31)
3,3'-Dichloro-
benzidine
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
<1
<1
<1
<1
(pq/D
2,4'-Diamino-
3,3'-dichloro-
biphenyl
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
<1
<1
208
-------
Lagoon Seepage Study
Well
A-l
A-2
A-3
B-l
B-2
B-3
C-l
C-2
C-3
D-l
D-2
D-3
34-C2
2-Chloro
aniline
Dry
3
29
45
20
77
< 1
< 1
5
< 1
< 1
100
100
Chlorinated Aromatic Amines
Concentration (10/81)
3,3'-Dichloro-
benzidine
<1
< 1
< 1
< 1
<1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
(yg/D
2,4'-Diamino-
3,3'-dichloro-
biphenyl
<1
<1
< 1
< 1
<1
< 1
<1
< 1
< 1
< 1
< 1
< 1
209
-------
Lagoon Seepage Study
Wells
A-l
A- 2
A- 3
B-l
B-2
B-3
C-l
C-2
C-3
D-l
D-2
D-3
34- C2
Chi
2-Chloro-
anil ine
Dry
< 1
380
398
50
23
< 1
< 1
45
< 1
< 1
135
85
orinated Aromatic Amines
Concentration (11/81)
3,3'-Dichloro-
benzidine
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
(vg/i)
2,4'-Diamino-
3,3'-dichloro-
biphenyl
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
210
-------
Lagoon Seepage Study
1,2-Dichloroethane
Concentration (vig/1)
Wells 6/81 7/81 8/81 9/81 10/81 11/81
1-B2 <1 <1 <1 <1 <1 <1
2-B2 7.1 6.2 6.8 3.9 2.4 <1
3-B2 3.3 4.1 4.5 1.9 3.2 2.7
4-B2 <1 <1 <1 <1 <1 <1
5-B2 <1 <1 <1 <1 <1 <1
6-B2 <1 <1 <1 <1 <1 <1
34-C2 10 12 8 6 3 4
A-l < 1 < 1 < 1 < 1 <1 <1
A-2 <1 <1 <1 <1 <1 <1
A-3 < 1 < 1 < 1 < 1 <1 <1
B-l <1 <1 <1 <1 <1 <1
B-2 <1 <1<1<1 <1 <1
B-3 <1 <1 <1 <1 <1 <1
C-l <1 <1<1<1 <1 <1
C-2 <1 <1 <1 <1 <1 <1
D-l <1 <1<1<1 <1 <1
D-2 <1 <1 <1 <1 <1 <1
D-3 15 9 12 12 8 6
211
-------
Dike Wells
Compound
Methyl aniline
2-Chloroaniline
Date: 6/81
Well:
A2
Concentration (yg/1)
A3
Cl
C2
4
290
C3
4
58
Date: 7/81
Methyl aniline
2-Chloroaniline
1
6
6
390
1
54
Date: 8/81
Methyl aniline
2-Chloroaniline
1
4
3
450
2
62
212
-------
SOIL SAMPLES
213
-------
Soils, Circle 11, 'l foot, 11/80
Priority Pollutants ug/g
Di-n-butyl phthalate 0.18
6is(ethylhexyl)phthalate 0.25
Additional Organic Compounds
2,2'-l)ichloroazobenzene 0.10
Soils. Circle 11, 2 feet. 11/80
Priority Pollutants
Diethyl phthalate 0.12
Di-n-butyl phthalate 2.2
Bis(ethylhexyl)phthalate 1.7
Additional Organic Compounds
Xylene 1.0
Soils. Circle 11, 3 feet, 11/80
Priority Pollutants
Diethyl phthalate 0.07
Di-n-butyl phthalate .1.7
Additional Organic Compounds
Xylene 1.1
214
-------
Soil', Circle 11. 1 foot, 4/81
Priority Pollutants yg/'g
Diethylphthalate 0.029
Butyl benzyl phthalate 1.5
Additional Organic Compounds
Xylene 0.27
Dichloroazobenzene 0.055
Benzyl alcohol 0.040
Rhenyl ethanone 0.029
Butyl-methylpropyl phthalate 0.21
Soil, Circle 11. 2 feet, 4/81
Priority Pol 1utants
Diethylphthalate 0.037
Additional Organic Compounds
Xylone 0.39
Soil, Circle 11, 3 feet, 4/81
Priority Pollutants
Diethylphthalate 0.062
Di-n-butyl phthalate 0.20
Additional Organic Compounds
Xylene 0.28
Benzyl alcohol 0.091
215
-------
Soil Circle 11. 1 foot, 5/81
Priority Pollutants pn/g
Diethylphthalate 0.072
Di-n-butyl phthalate . 0.087
Bis(ethylhexyl )phtha1ate 0-.093
Additional Organic Compounds
Dichloroazobenzene 0.047
Soil Circle 11, 2 feet, 5/81
Priority Pollutants
>
Diethylphthalate 0.10
Di-n-butyl phthalate 0.19
Butyl benzyl phthalate ' 0.14
Bis(ethylhexyl)phthalate 0.12
Additional Organic Compounds
N-phenylanil ine 0.023
Soil Circle 11, 3 feet. 5/81
Priority Pollutants
Diethylphthalate 0.064
D.i-n-buty1 phthalate 0.10
Butyl benzyl phthalate 0.025
Bis(ethylhexyl)phthalate 1.2
Additional Organic Compounds
Xylene 0.24
Ethenyl benzene 0.061
216
-------
Soils. Circle 19. 1 foot. 11/80
Priority Pollutants y.g/g
Diethyl phthalate 0.06
Di-n-butyl phthalate 0.97
Bis(ethylhexyl)phthal ate 8.9
Aroclor 1016 0.09
Additional Organic Compounds
2,2'-Dichloroazobenzene 0.11
Soils, Circle 19, 2 feet. 11/80
Priority Pollutants
Diethyl phthalate 0.05
Di-n-butyl phthalate 1.2
Bis(ethylhexyl)phthalate 1.3
Aroclor 1016 0.026
Additional Organic Compounds
Xylene . 0.23
2,2'-Dichloroazobenzene 0.04
Soils, Circle 19, 3 feet. 11/80
Priority Pollutants
Di-n-butyl phthalate 0.68
Bis(ethylhexyl)phthalate 0.21
Aroclor 1016 0.016
Additional Organic Compounds
Not detected
217
-------
Soil. Circle 19, 1 foot, 4/81
Priority Pollutants yg/g
Diethyl phthalate 0.074
Di-n-butyl phthalate 0.64
Additional Organic Compounds
Xylene 0.32
Ethenyl benzene 0.098
Dichloroazobenzene . 0.038
Benzyl alcohol 0.061
phenyl ethanone 0.079
Butyl-methylpropyl phthalate 3.9
Soil , Circle 19, 2 feet, 4/81
Priority Pollutants
Diethylphthalate 0.034
Di-n-butyl phthalate 0.12
Additional Onjanic Compounds
Xylene 0.25
Ethenyl benzene 0.080
Benzyl alcohol 0.062
Phenylethanone 0.055
Soil, Circle 19, 3 feet, 4/81
Priority Pollutants
Diethylphthalate 0.038
Di-n-butyl phthalate 0.17
Additional Organic Compounds
Xylene 0.25
Ethenyl benzene 0.088
Benzyl alcohol 0.048
Phenyl ethanone 0.057
Butyl-methylpropyl phthalate 0.27
218
-------
.Soil-., Circ-le 19, 1 foot,' 5/81
Priority Pollutants. jig/g
Not detected
Additional Organic Compounds
Xylene 0.15
Soil , Circle 19. 2 feet, 5/81
Priority Pollutants
Diethylphthalate 0.007
Di-n-butyl phthalate 0.042
Additional Organic Compounds
Xylene 0.14
Ethenyl benzene 0.15
Rhenyl ethanone 0.056
Soil, Circle 19, 3 feet, 5/81
Priority Pollutants
Bis(ethylhexyl)phthalate 0.97
Additional Organic Compounds
Xylene 0.29
Ethenyl benzene 0.36
Phenyl ethanone 0.12
219
-------
Soils. Circle 48, 1 foot, 11/80
Priority Pollutants yg/g_
Di-n-butyl phthalate 0.81
Bis(ethylhexyl)phthalate 1.4
Additional Organic Compounds
Xylene 0.21
Soils. Circle 48, 2 feet, 11/80
Priority Pollutants
Diethyl phthalate 0.052
Di-n-butyl phthalate 0.12
Bis(ethylhexyl)phthalate 0.25
Additional Organic Compounds
Not detected
Soils, Circle 48, 3 feet, 11/80 .
Priority Pollutants
Diethyl phthalate 0.048
Dibutyl phthalate 0.38
Bis(ethylhexyl)phthalate 0.38
Additional Organic Compounds
Not detected
220
-------
Soil, Circle 48, 1 foot, 4/81
Priority Pollutants yg/g
Diethylphthalate 0.092
Di-n-butyl phthalate 0.84
Butyl benzyl phthalate 0.11
Additional Organic Compounds
Xylene 0.24
Ethenyl benzene 0.079
Dichloroazobenzene 0.068
Benzyl alcohol 0.068
Phenyl ethanone 0.034
Butyl-niethylpropyl phthalate 0.25
Soil , Circle 48, 2 feet, 4/81
Priority Pollutants
Diethylphthalate 0.061
Di-n-butyl phthalate 0.14
Butyl benzyl phthalate 0.78
Bis(ethyl hexyl)phthalate 0.28
Additional Organic Compounds
Xylene 0.21
Ethenyl benzene 0.072
Benzyl alcohol 0.12
Rhenyl ethanone 0.059
Butyl-methylpropyl phthalate 0.055
Soil, Circle 48, 3 feet, 4/81
Priority Pollutants
Diethyl phthalate 0.038
Di-n-butyl phthalate 0.081
Butyl benzyl phthalate 0.39
Additional Organic Compounds
Xylene 0.41
Benzyl alcohol 0.22
221
-------
Soil , Circle 48/1 foot, 5/81
Priority Pollutants yg/g'
Diethylphthalate 0.008
Di-n-butyl phthalate 0.062
Bis(ethylhexyl)phthalate 8.3
Additional Organic Compounds
Dichloroazobenzene 0.012
Ethenyl benzene 0.099
Benzaldehyde 0.056
Bhenyl ethanone 0.061
(methylpropyl) butyl phthalate 0.11
Soil , Circle 48, 2 feet, 5/81
Priority Pol 1utants
Di-n-butyl phthalate 0.074
Bis(ethylhexyl)phthalate 4.4
Additional Organic Compounds
Xylene 0.030
Benzyl alcohol 0.051
Soil , Circle 48, 3 feet. 5/81
Priority Pollutants
Di-n-butyl phthalate 0.034
Bis(ethylhexyl)phthalate 4.9
Additional Organic Compounds
Benzyl alcohol 0.044
222
-------
Soil . Circle 11, 1 foot, 6/81
Priority Pollutants yg/g
Diethyl phthalate 0.022
Di-n-butyl phthalate 0.13
Butyl benzyl phthalate 0.15
Additional Organic Compounds
Xylene 0.32
2,2'-Dichloroazobenzene 0.14
Benzyl alcohol 0.045
Phenyl ethanone 0.038
Soil , Circle 11, 2 feet, 6/81
Priority Pollutants
Diethyl phthalate 0.030
Di-n-butyl phthalate 0.095
Phenol 0.061
Additional Organic Compounds
Xylene ' 0.25
Benzyl alcohol 0.058
Soil. Circle 11. 3 feet, 6/81
Priority Pollutants
Di-n-butyl phthalate 0.12
Bis(ethylhexyl )phthalate 2.8
Phenol 0.087
Additional Organic Compounds
Not detected
223
-------
Soil, Circle 11. 1 foot, 7/81
Priority Pollutants yg/g
Di-n-butyl phthalate 0.094
Phenol 0.040
Trichloroethylene 0.006
Additional Organic Compounds
Not detected
Soil . Circle 11, 2 feet, 7/81
Priority Pollutants
Phenol 0.047
Additional Organic Compounds
Mot detected
Soil, Circle 11, 3 feet, 7/81
Priority Pollutants
Diethyl phthalate 0.049
Di-n-butyl phthalate 0.71
Phenol 0.054
Additional Organic Compounds
Benzyl alcohol 0.089
Butyl (2-methylpropyl)phthalate 2.6
224
-------
Soil , Circle 11, 1 foot, 8/81
Priority Pollutants yg/g
Diethyl phthalate 0.40
Di-n-butyl phthalate 0.38
Butyl benzyl phthalate 0.16
Tetrachloroethylene 0.046
Toluene 0.067
Additional Organic Compounds
2,2'-Dichloroazobenzene 0.056
Soil , Circle 11. 2 feet. 8/81
Priority Pollutants
Diethyl phthalate 0.065
Di-n-butyl phthalate 0.17
Bis(ethylhexyl)phthalate 0.49
Additional Organic Compounds
Not detected
Soil. Circle 11. 3 feet, 8/81
Priority Pollutants
Diethyl phthalate 0.97
Di-n-butyl phthalate 0.19
Additional Organic Compounds
Not detected , .. ...
225
-------
Soil , Circle 19, 1 foot, 6/81
Priority Pollutants yg/g
Bis(ethylhexyl)Phthalate 38
Phenol ' 0.062
Additional Organic Compounds
Not detected
Soil , Circle 19, 2 feet, 6/81
Priority Pollutants
Bis(ethylhexyl)phthalate 0.49
1,1,1-Trichloroethane . 0.001
Additional Organic Compounds
Xylene 0.044
Soil. Circle 19, 3 feet, 6/81
Priority Pollutants
Not detected at 0.005 yg/g
Additional Organic Compounds
Not detected
226
-------
Soil. Circle 19, 1 foot, 7/81
Priority Pollutants uQ/g
Di-n-butyl phthalate 0.068
Phenol 0.087
Additional Organic Compounds
Benzaldehyde 0.22
Soil, Circle 19, 2 feet, 7/81
Priority Pollutants
Di-n-butyl phthalate 0.15
Bis(ethylhexyl)phthalate 0.14
Phenol 0.058
Additional Organic Compounds
Not detected
Soil, Circle 19, 3 feet, 7/81
Priority Pollutants
Di-n-butyl phthalate 0.30
Phenol 0.053
Additional Organic Compounds
Not detected
227
-------
Soi1, Circle 19. 1 foot. 8/81
Priority Pollutants yg/g
Diethyl phthalate 0.12
Di-n-butyl phthalate 0.083
Bis(ethylhexyl)phthalate 1.0
Additional Organic Compounds
2,2'-Dichloroazobenzene 0.18
Benzaldehyde 2.3
Phenyl ethanone 0.32
Phenylacetic acid 1.2
Simazine 0.17
Atrazine 0.13
Vanillin 0.022
Soil , Circle 19, 2 feet, 8/81
Priority Pollutants
Diethyl phthalate 0.071
Di-n-butyl phthalate 0.089
Bis(ethylhexyl)phthalate . 1.8
Additional Organic Compounds
Benzaldehyde 0.25
Soil. Circle 19, 3 feet. 8/81
Priority Pollutants
Diethyl phthalate 0.10
Di-n-butyl phthalate 0.17
Additional Organic Compounds
Butyl(2-methylpropyl)phthalate 1.5
228
-------
Soil, Circle 48, 1 foot, 6/81
Priority Pollutants pg/g
Di-n-butyl phthalate 0.052
Phenol 0.086
Additional Organic Compounds
Not detected - .
Soil . Circle 48, 2 feet, 6/81
Priority Pollutants
Di-n-butyl phthalate 0.085
Phenol 0.032
Additional Organic Compounds
Xylene 0.046
Soil , Circle 48, 3 feet, 6/81
Priority Pollutants
Diethyl phthalate 0.099
Di-n-butyl phthalate 0.47
Phenol 0.034
Additional Organic Compounds
Not detected
229
-------
Soil , Circle 48. 1 foot, 7/81
Priority Pollutants pg/g
Di-n-butyl phthalate 0.23
Additional Organic Compounds
Not detected
v Soil . Circle 48, 2 feet. 7/81
Priority Pollutants
Diethyl phthalate 0.12
Additional Organic Compounds
Not detected
Soil , Circle 48, 3 feet, 7/81
Priority Pollutants
Diethyl phthalate 0.17
Di-n-butyl phthalate 0.11
Additional Organic Compounds
Not detected
230
-------
Soil , Circle 48. 1 foot. 8/81
Priority Pollutants yg/g
Diethyl phthalate 0.099
Phenol 0.045
Additional Organic Compounds
Not detected
Soil . Circle 48. 2 feet. 8/81
Priority Pollutants
Diethyl phthalate 0.047
Di-n-butyl phthalate 0.14
Phenol 0.049
Additional Organic Compounds
B-utyl(2-methylpropyl )phthalate 0.98
Soil . Circle 48, 3 feet, 8/81
Priority Pollutants
Diethyl phthalate 0.74
Di-n-butyl phthalate 0.35
Phenol 0.044
Additional Organic Compounds
Not detected .
231
-------
Soils, Circle 11, 1 foot, 9/81
Priority Pollutants ug/g
Diethyl phthalate 0.18
Additional Organic Compounds
Xylene 2.4
Dichloroazobenzene 0.043
Soils. Circle 11. 2 feet, 9/81
Priority Pollutants
Diethy] phthalate 0.091
Additional Organic Compounds
Xylene 0.39
Ethenyl benzene 0.16
Phenyl ethanone 0.070
Soils. Circle 11, 3 feet, 9/81
Uiethyl phthalate 0.33
Di-n-butyl phthalate 0.092
Tetrachloroethylene 0.005
Toluene 0.004
Additional Organic Compounds
Xylene 0.41
Phenyl ethanone 0.081
232
-------
Soils, Circle 19, 1 foot, 9/81
Priority Pollutants vg/g
Diethyl phthalate 0.043
Di-n-butyl phthalate 0.039
Additional Organic Compounds
Xylene 0.39
Dichloroazobenzene 0.029
Ethenyl benzene 0.19
Phenyl ethanone 0.077
Soils. Circle 19, 2 feet, 9/81
Priority Pollutants
Diethyl phthalate 0.019
Additional Organic Compounds *
Xylene 2.4
Ethenyl benzene 0.14
Phenyl ethanone 0.046
Soils. Circle 19, 3 feet. 9/81
Priority Pollutants
Diethyl phthalate 0.17
Di-n-butyl phthalate 0.064
Additional Organic Compounds
Xylene 0.46
Ethenyl benzene 0.20
Phenyl ethanone 0.087
233
-------
Soils. Circle 48, 1 foot, 9/81
Priority Pollutants yg/g
Diethyl phthai ate 2.1
Di-n-butyl phthalate 0.26
Additional Organic Compounds
Not detected
Soils, Circle 48, 2 feet. 9/81
Priority Pollutants
Diethyl phthalate 0.19
Additional Organic Compounds
Not detected
Soils, Circle 48, 3 feet, 9/81
Priority Pollutants
Diethyl phthalate 0.91
Di-n-butyl phthalate 0.30
Additional Organic Compounds
Xylene 0.55
Vanillin 0.11
234
-------
Soils, Circle 11. 1 foot. 11/81
Priority Pollutants ug/g
Di-n-butyl phthalate 0.061
1,1,1-Trichloroethane 0.020
1,2-Dichloroethane 0.002
Additional Organic Compounds
Xylene 0.62
Vanillin 0.14
Soils. Circle 11, 2 feet, 11/81
Priority Pollutants
Di-n-butyl phthalate 0.067
Additional Organic Compounds
>
Xylene 0.54
Vanillin 0.072
Soils. Circle 11, 3 feet, 11/81
Priority Pollutants
Diethyl phthalate 0.027
Di-n-butyl phthalate 0.066
Additional Organic Compounds
Not detected
235
-------
Soils, Circle 19,'i foot, 10/81"""
Priority Pollutants pg/g
Not detected
Additional Organic Compounds
Benzeneacetic acid 0.18
Vanillin 0.063
Soils, Circle 19. 2 feet, 10/81
Priority Pollutants
1,1,1-Trichloroethane 0.031
Additional Organic Compounds
Xylene 1.2
Alkyl substituted benzene (4) 0.64
Soils, Circle 19, 3 feet, 10/81
Priority Pollutants
Phenol 0.045
Additional Organic Compounds
Xylene 0.69
Alkyl substituted benzene (4) 0.30
Vanillin 0.023
236
-------
Soils. Circle 48, 1 foot, 10/81
P r i o ri ty Po11utant s yg/g
Phenol 0.049
Additional Organic Compounds
Xylene 0.60
Alkyl substituted benzenes (4) 0.41
Vanillin " 0.15
Soils. Circle 48, 2 feet, 10/81
Priority Pollutants
Not detected
Additional Organic Compounds
Xylene * 0.41
Alkyl substituted benzenes (5) 0.29
Phenylacetic acid 0.22
Vanillin 0.075
Soils. Circle 48. 3 feet. 10/81
Priority Pollutants
Di-n-butyl phthalate 0.037
Additional Organic Compounds
Xylene 0.46
237
-------
Soils, Circle 11, 1 foot, 11/81
Priority Pollutants yg/g
Toluene 0.025
Additional Organic Compounds
Xylene 0.53
Alkyl substituted benzenes (4) 0.29
Phenylacetic acid 0.073
Vanillin 0.065
Soils. Circle 11. 2 feet, 11/81
Priority Pollutants
Di-n-butyl phthalate 0.062
Toluene 0.020
Additional Organic Compounds
Xylene 1.1
Vanillin 0.061
Soils. Circle 11, 3 feet. 11/81
Priority Pollutants
Diethyl phthalate 0.041
Di-n-butyl phthalate 0.074
Toluene 0.013
Additional Organic Compounds
Xylene 0.26
238
-------
Soils, Circle 17, 1 foot, 11/81
Priority Pollutants y.g/9
Di-n-butyl phthalate 0.094
Toluene 0.022
Additional Organic Compounds
Xylene 0.31
Alkyl substituted benzenes (5) 0.31
Phenylacetic acid 0.21
Vanillin 0.068
Soils, Circle 17, 2 feet, 11/81
Priority Pollutants
Di-n-butyl phthalate 0.076
Toluene 0.014
Additional Organic Compounds
Xylene 0.55
Soils, Circle 17, 3 feet. 11/81
Priority Pollutants
Diethyl phthalate 0.049
Toluene 0.010
Additional Organic Compounds
Xylene 1.1
Alkyl substituted benzene (5) 0.69
239
-------
Soils, Circle 48, 1 foot, 11/81
Priority Pollutants
Soils, Circle 48, 3 feet, 11/81
Priority Pollutants
Di-n-butyl phthalate 0.17
Toluene 0.028
Additional Organic Compounds
Xylene 0.41
Soils. Circle 48. 2 feet. 11/81
Priority Pollutants
Toluene 0.015
Additional Organic Compounds
Xylene 0.27
Di-n-butyl phthalate 0.30
Toluene 0.014
Additional Organic Compounds
Xylene 0.31
Vanillin 0.072
240
-------
Hells 10/81
USGS 3 yg/1
No detectable compounds
USGS 4
No detectable compounds
9/81
USGS 1
No detectable compounds
USGS 2
No detectable compounds
11/81
3B2
1,2-Dichloroethane 6
31B2
1,2-Dichloroethane 8
241
-------
SLUDGE SAMPLES
242
-------
Concentration;of. Organic Chemicals ,
In Cell II Sludge (yg/Kg) 1980
Priority Pollutants
Acenaphthalene
Anthracene
Butyl benzyl phthalate
Benzo(a)anthracene
Bis(ethylhexyl)phthalate
Chrysene
Chlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Dimethyl phthalate
Di-n-butyl phthalate
3,3'-dichlorobenzidine
Diethyl phthalate
Ethyl benzene
Fluoranthene
Fluorene
Naphthalene
Phenol
Pyrene
Phenanthrene
Tetrachloroethylene
Toluene
Additional Organic Compounds
6/11
te
_
late 4,400
170
11
160
340
650
ne 20,600
170
680
900
640
980
1,180
4
460
6/25
450
170
3,300
-
36
120
350
760
15,400
550
520
280
600
220
-
990
5
1,900
7/18
200
68
1,340
-
44
150
220
340
12,600
390
160
210
440
330
-
540
-
1,870
8/21
260
200
7,800
-
35
110
190
400
14,100
390
400
200
400
300
-
' 740
42
1,900
9/05
-
-
3,500
-
-
440
470
490
78,800
71
-
210
820
-
-
1,200
-
180
9/19
-
-
2,500
1,000
-
560
530
60
66,800
120
-
180
870
210
-
1,100
-
120
Alky! substituted
benzene
Alkyl substituted
phenol
Biphenyl
Benzothiazole
2-Chloroaniline
Cresol
2,2'-Dichloroazobenzene
Dimethyl phenanthrene
Di ethoxychlorobenzene
Dimethyl naphthalene
2,4'-Diamino-3,3'-di-
chlorobiphenyl
Benzaldehyde
Dimethyl disulfide
Ethyl phenol
Methyl naphthalene
2-Methoxy-1,1'-bi phenyl
31,300 49,600 27,900 41,700 57,300 62,300
46,
2,
4
6
22
,500
,500
550
,350
,700
,000
28,000 11,300
970 1,140
850 390
6,600 62,800
1,480 820
410 1,700
6,900 5,140 4,600 5,000
8,000 5,400 4,000 18,700
31,700 22,500 21,300 51,300
50,500
880
1,700
4,300
17,300
42,200
1,700 1,850 1,300 1,400 4,400 5,200
243
-------
'Concentration of Organic-Chemicals
In Cell II Sludge (yg/Kg) 1980 (Cont'd)
Additional Organic
Compounds (Cont'd) 6/11 6/25 7/18 8/21 9/05 9/19
Methyl dibenzothiophene ______
Methyl phenanthrene ______
N,N-Dimethylaniline - - - . -
Substituted indene ______
Substituted phenanthrene- ______
carboxaldehyde
Trimethyl naphthalene 6,600 6,000 5,000 4,200 11,900 13,600
Tributyl phosphate 630 1,180 850 900 1,200 1,200
Tetramethylbutyl phenol ------
Trimethyl phenanthrene ______
Tetramethyl phenanthrene ------
Vanillin _____ 120
244
-------
Concentration of Organic- Chemicals In
- Ce1T.il Sludge -(vg/Kg.) 1981 -
Priority Pollutants 3/81 7/81 9/81
Acenaphthalene 76 -
Butyl benzyl phthalate 1,300 - 280
Benzo (a) anthracene 85 -
Bis(ethylhexyl)phthalate 11,000 310 3,300
Chrysene 270 80 81
Chloroform - 1 -
1,4-Dichlorobenzene 98 95 72
1,2-Dichlorobenzene 180 420 200
Dimethyl phthalate 630 150
Di-n-butyl phthalate 200 320 110
3,3'-Dichlorobenzidine 171,000 12,000 5,500
Diethyl phthalate - 710
Ethyl benzene - 10 -
Fluoranthene 200 130
Fluorene 120 120 110
Naphthalene 760 280 160
Phenol 95 320 53
Pyrene 480 260
Phenanthrene 500 610 430
Toluene 85 23 4
Additional^ Organic Compounds
Alkyl substituted benzene 28,000 25,000 33,000
Alkyl substituted phenols - 20,000
Biphenyl 430
Benzothiazole - 400 260
2-Chloroaniline 21,000 6,600 6,500
Cresol 900 530 590
2,2'-Dichloroazobenzene 6,600 300 190
Dimethyl phenanthrene 4,600 9,300 9,300
Diethoxychlorobenzene 2,400 2,800 920
Diethoxydichlorobenzene - - 610
Dimethyl naphthalenes 6,700 8,300 9,600
2,4'-diamino-3,3'-
dichlorobiphenyl 88,000 26,000 6,100
Benzaldehyde . - - 160
Dimethyl disulfide 160
Ethyl phenol 90
Methyl naphthalenes 3,000 1,800 2,700
2-Methoxy-l.r-biphenyl - 740
Methyl dibenzothiophene - 2,300
Methyl phenanthrene 3,300 3,500
245
-------
Concentration of 0*rgY:iic Chemical sin
Cell II Sludge (yg/Kg) 1981
Continued
Additional Organic Compounds 3/81 7/81 9/81
N,N-Dimethylaniline - 280 450
Substituted indene 480
Substituted phenanthrene-
carboxaldehyde 2,450 4,500 5,100
Trimethyl naphthalenes 7,100 10,200 7,900
Tributyl phosphate - 470 930
4-(2,2,3,3-tetramethylbutyl)phenol - 2,700
Trimethyl phenanthrene - 3,300
Tetramethyl phenanthrene - 350
Xylene - 120
246
-------
Concentration of Organic Chemicals
In East Lagoon Sludge (yg/Kg) 1980
Priority Pollutants
Anthracene
Bis( ethyl hexyl )phthalate
Butyl benzyl phthalate
Benzo(a)anthracene
Chlorobenzene
Chrysene
1,2-Di chlorobenzene
3,3'-Dichlorobenzidine
Di-n-butyl phthalate
Dimethyl phthalate
Ethyl benzene
Fluoranthene
Fluorene
Naphthalene
Phenol
Pyrene
Phenanthrene
Toluene
Tetrachloroethylene
Additional' Organic Compounds
Alkyl substituted benzenes
Benzyl alcohol
Benzaldehyde
Cre'sol
2-Chloroaniline
2,2'-Dichloroazobenzene
2,4'-Diamino-3,3'-dichloro-
biphenyl
Di ethoxychl orobenzene
Dimethyl naphthalene
Dimethyl trisulfide
Methyl naphthalene
N,N-Dimethylaniline
Substituted phenanthrenes
Substituted thiophenes
Trimethyl naphthalene
Vanillin
Xyl ene
6/11
1,900
-
38
15
-
100
1,850
-
-
65
-
_
160
170
-
270
440
6
16,200
-
-
1,400
7,500
180
2,100
790
1,700
~
570
-
-
-
1,800
-
-
7/18
600
180
21
-
-
-
230
190
-
-
64
-
35
-
-
100
19
-
3,200
-
-
180
2,160
270
6,000
640
680
-
130
-
-
-
700
-
-
8/13
1,370
52
-
-
-
-
-
130
-
-
-
-
26
-
-
58
-
-
10,500
-
-
110
1,280
67
560
150
3,700
-
90
-
-
-
350
_
-
8/29
-
-
-
-
2,500
90
7,300
-
490
15
1,200
-
110
-
-
-
15
-
38,500
-
-
170
19,800
3,300
80,700
1,400
3,000
^
740
-
-
-
3,900
150
-
9/19
5,000
-
-
-
630
-
5,900
-
-
40
280
-
50
-
-
-
-
-
16,800
-
260
120
7,540
740
16,000
300
1,000
-
290
160
-
-
1,600
130
-
247
-------
'CcJhcent'ratioh'' of Orga-riic"-Cheitn"ca-Ts'
In East Lagoon Sludge (ug/Kg) 1980
Priority Pollutants 10/09 10/31 11/18
Anthracene -
Bis(ethylhexyl)phthalate 1,100 4,400 2,200
Butyl benzyl phthalate -
Benzo(a)anthracene -
Chrysene - 310 270
1,2-Dichlorobenzene 130
3,3'-Dichlorobenzidine - 4,000 1,200
Di-n-butyl phthalate - 600
Ethyl benzene 18 4 -
Dimethyl phthalate - 80 80
Fluoranthene 320 220 160
Fluorene
Naphthalene 40 60 30
Phenol 120
Pyrene -
Phenanthrene -
Toluene 4 3 -
Tetrachlorobenzene -
Additional Organic Compounds
Alkyl substituted benzenes 25,200 17,600 12,900
Benzyl alcohol -
Benzaldehyde - 300 200
Cresol 610
2-Chloroaniline 6,100 5,700 4,800
2,2'-Dichloroazobenzene 530 940 620
2,4'-Diamino-3,3l-dichloro- 6,500 13,100 7,300
biphenyl
Diethoxychlorobenzene 570 460 370
Dimethyl naphthalene 2,'400 820 500
Dimethyl trisulfide
Methyl naphthalene 740 560 420
N,N-Dimethylaniline 420 140 70
Substituted phenanthrenes -
Substituted thiophenes -
Trimethyl naphthalene 5,200 1,200 1,000
Vanillin - 170
Xylene -
248
-------
.Cppcen.trat.ibn .of .Organic Chemicals
In"East 'Lagoon 'S fudge' (yg/Kg)'1981
Priority Pollutants 3/81 7/81 9/81
Bis(ethylhexyl)phthalate 1,000 220 7,000
Butyl benzyl phthalate 2,500 100
Benzo (a) anthracene - 98 -
Chrysene 180 120 210
1,2-Dichlorobenzene 51
3,3-Dichlorobenzidine 1,500 - 1,400
Di-n-butyl phthalate 160 260
Diethyl phthalate - 460
Fluoranthene 66 78
Fluorene 25
Naphthalene 46 - 110
Phenol 64
Pyrene 140 IQO
Phsnanthrene 65 , 490
Toluene 7 4
Trichlorobenzene 170
Additional Organic Compounds
Alkyl substituted benzenes 25,000 2,300 71,000
Benzyl alcohol 100
Benzaldehyde 470 - 350
Biphenyl 78
Cresol 57 - 560
Benzothiazole - 290 390
2-Chloroaniline 4,800 110 9,500
2,2-Dichloroazobenzene 350 - 880
2,4'-Diamino-3,3'-
dichlorobiphenyl 23,000
Diethoxychlorobenzene 120 49
Dimethyl naphthalenes 1,000 - 3,500
Dimethyl trisulfide 410
Methyl naphthalenes 510 170 2,800
N,N-Dimethylaniline 140 - 490
Substituted phenanthrenes 1,600
Substituted thiophenes 360
Trimethyl naphthalenes 1,200 230 7,500
Xylene -. - 140
249
-------
Concentration of' Organic Chemicals
In West Lagoon Sludge (ug/Kg) 1980
Priority Pollutants 6/11 6/25 7/18 8/13 8/29
Anthracene -
Bis(ethylhexyl)phthalate 1,700 - 400 1,940 13,400
Butyl benzyl phthalate - 620 290 40
Benzo(a)anthracene - 79 40 70 280
Chrysene 105 -
1,4-Dichlorobenzene 16 -
1,2-Dichlorofaenzene 45 -
3,3'-Dichlorobenzidine 2,000 630 260
Di-n-butyl phthalate - - 210 -
Diethyl phthalate _ _ 30
Ethyl benzene 18 5 22 - 15
Fluoranthene 300 130 60 140 660
Fluorene - 63 350 30
Naphthalene 140 60 40 30 20
Phenol 160 850 760
Pyrene -
Phenanthrene - 160 80 90
Toluene 15 5 3 10
Tetrachloroethylene 10 13 -
Additional Organic Compounds
Alkyl substituted benzenes 22,700 25,400 3,100 33,800 11,700
Benzyl alcohol -
Benzaldehyde 220 - - - 210
Cresol 600 - - 150 70
2-Chloroaniline 5,700 1,400 860 2,500 1,100
2,2'-Dichloroazobenzene 410 630 160 630 350
2,4'-Diamino-3,3'-dichloro- 3,400 7,120 3,100 3,800 6,700
biphenyl
Diethoxychlorobenzene 390 590 220 110 60
Dimethyl naphthalene 2,640 1,180 490 500 550
Dimethyl trisulfide -
Methyl naphthalene 490 280 130 90 630
N,N-Dimethylaniline 72 140
Substituted phenanthrenes -
Substituted thiophenes _____
Trimethyl naphthalene 2,560 1,720 460 550 840
Xylene ... 660
250
-------
Concentration of Organic Chemicals
In West Lagoon Sludge (yg/Kg) 1980
Priority Pollutants
Anthracene
Bis(ethylhexyl)phthalate
Butyl benzyl phthalate
Benzo(a)anthracene
Chrysene
1,2-Dichlorobenzene
3,3'-Dichlorobenzidine
Di-n-butyl phthalate
Diethyl phthalate
Ethyl benzene
Fluoroanthene
Fluorene
Naphthalene
Phenol
Pyrene
Phenanthrene
Toluene
Tetrachl orobenzene
Additional Organic Compounds
Alkyl substituted benzenes
Benzyl alcohol
Benzaldehyde
Cresol
2-Chloroaniline
2,2'-Dichloroazobenzene
2,4'-Diamino-3,3'-dichloro-
biphenyl
Diethoxychl orobenzene
Dimethyl naphthalene
Dimethyl trisulfide
Methyl naphthalene
N.N-Dimethylaniline
Substituted phenanthrenes
Substituted thiophenes
Trimethyl naphthalene
Vanillin
Xyl ene
9/17
13,600
-
-
-
50
-
-
-
-
1,150
_
50
-
-
-
-
-
37,000
-
440
380
5,100
1,240
27,800
100
1,130
100
780
450
-
-
1,650
180
-
10/09
10,800
-
-
590
30
21,400
-
-
5
1,120
_
50
-
-
320
-
-
50,200
-
210
300
5,700
1,100
34,900
90
2,000
90
730
220
-
-
3,600
220
-
10/22
*
-
-
1,170
-
17,200
-
-
-
1,200
_
90
-
-
350
-
-
49,000
-
290
_
5,050
2,400
93,500
300
3,200
180
660
-
2,000
-
3,700
_
-
11/18
11,700
-
-
700
-
11,200
-
-
-
1,260
-
50
-
-
200
-
-
17,000
-
200
_
2,500
440
52,000
90
1,400
90
420
140
800
-
2,200
-
-
* Contaminated
251
-------
. .,Concentra'ti.on..of Organic.Chemicals. In
'West Lagoon Sludge (y'g/Kg) 1981
Priority Pollutants 3/81 7/81 9/81
3is(ethylhexyl)phthalate 1,300 13,000 6,800
1,2-Dichlorobenzene 41 - 64
3,3-Dichlorobenzidine 6,500 6,100 2,100
1,2-Dichloroethane - 12 -
Chrysene - 420 500
Di-n-butyl phthalate - - 280
1,4-Dichlorobenzene - - 59
Diethyl phthalate 30 -
Dimethyl phthalate 33 -
Ethyl benzene - 3 -
Fluoranthene 190
Fluorene 23
Naphthalene 34 81 120
Phenol - 230 45
Phenanthrene ' 92 1,500 210
Trichlorobenzene 87 -
Toluene 6 21 13
Additional Organic Compounds
Alkyl substituted benzenes 12,700 91,000 34,000
Benzaldehyde - 120 290
Benzothiazole - 1,600 720
2-Chloroaniline 3,500 3,900 6,200
Cresol 89 1,300 420
2,4'-Diamino-3,3'-
dichlorobiphenyl 22,000 21,000
Diethoxychlorobenzene 90 850
Dimethyl naphthalenes - 8,400 3,400
2,2-Dichloroazobenzene - - 590
Dimethyl trisulfide 240
Dimethyl phenanthrene - 6,600
Methyl naphthalenes - 1,400 1,400
Methyl dibenzothiophene - 3,100
Methyl phenanthrene - 4,100
Substituted benzoic acid 250 -
Substituted thiophene 340
Tetramethylphenanthrene - 1,500
Trimethyl naphthalene - 11»4QO 5,300
Trimethyl phenanthrene - 3,700 2,300
N,N-Dimethyl aniline - - 240
Xylene - 410 130
252
-------
CORN SAMPLES
253
-------
CORN: 10/80
Circle 15
Circle 4
Circle 29
Circle 39
Circle 50
Circle 54
No priority pollutants detected <0.01 mg/Kg
CORN: 11/81
Circle 11
Circle 18
Circle 48
Circle 50
No priority pollutants detected at <0.01 mg/Kg
254
-------
APPENDIX B
Quality Control
255
-------
QUALITY CONTROL
A rigorous quality control program was undertaken to produce data of known
precision and accuracy levels. The goal of the program was to assure validity
of the monitoring data and to control the daily analytical process. Because
of the variety of sample types studied in this project, it was necessary to
verify the methodology for each category. Samples verified and corresponding
categories are given in Table B-l.
TABLE B-l
Verification Categories
Sample Category
West Lagoon Sludge Sludge: East and West Lagoons,
Cell II
Influent Raw and partially treated sewage:
Influent, Spillway
West Lagoon Treated Sewage: East and West
Lagoons, Outlet Lagoon
South Ditch Discharge: 05, Drain Tiles, 34
Wells, South'Ditch
Samples were spiked with priority pollutants to determine the precision and
accuracy within a given matrix. In addition, surrogate standards were used
to act as a measure of daily analytical quality control.
The quality control program employed was similar to that described by the
EPA (14). For water samples, two-liter aliquots were used. Three replicates
were spiked and analyzed at two concentration levels. In addition, background
levels were determined as the average of three replicate analyses. Extraction
and analytical procedures were identical to those described earlier. Standard
precision and accuracy calculations were made for each level and sample type.
256
-------
Results of the quality control samples are given in Appendix B according to
category. Also included are check samples received from the Kerr Environ-
mental Research Laboratory.
257
-------
,1980
'South Ditch'Volatile Fraction Quality'Contro-T (yg/1):
Compound Initial
Ethylbenzene <1
Chlorobenzene <1
Toluene <1
Perchloroethylene
-------
'.. 1980
.South Ditch Volatile Fractian'-Qual ity.'Gontro.T. {-yg/1):
LoW Level Spike
Compound
Ethylbenzene
Chlorobenzene
Toluene
Perchloroethylene
Tetrachloroethane
Bromoform
Trichloroethylene
1,1,2-Trichloroethane
Benzene
Cis-1,3-Dichloropropene
1,1,1-Tn'chloroethane
Trans-l,3-Dichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Methylene chloride
Chloroform
Bromochloromethane
2-Bromo-l-chloropropane
1,4-Dichlorobutane
Initial Spiked Amount
1.3
1.8
1.0
3.1
3.3
8.2
0.90
2.8
1.8
6
<1
5
2
3.2
2.4
2.4
2.2
2.4
3.3
2.2
2.4
2.8
39
30
23
Recovered
X
1.2
1.7
.82
2.5
2.6
5.1
.48
2.2
1.7
1.9
2.4
1.9
2.1
7.0
2.3
2.8
1.9
2.4
2.4
37
30
22
S
. .1
.1
.2
.3
.2
.4
.3
.2
.1
.2
.2
.1
.3
.3
.7
.1
.1
.2
.2
2
1
1
%R
92
92
82
82
80
62
53
80
93
72
74
78
86
96
97
84
81
100
85
95
100
96
259
-------
1980 .
' SOUTH' DITCH-BASE-NEUTRAL FRACTION-QUALITY CONTROL (u.g/1).
HIGH LEVEL SPIKE
Compound
Bis(2-chloroethyl)ether
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Diriitrotoluene
Diethyl phthlate
Fluorene
1,2-Diphenylhydrazine
4-Bromophenyl phenyl ether
Hsxschl ^robpp.zs^is
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo(a)pyrene
Initial
<1
<1
<1
< 1
< 1
< 1
< 1
< 1
22
< 1
^ 1
< 1
< 1
< 1
< 1
^ 1
<1
<1
< 1
<1
<1
<1
<1
< 1
<1
<1
< 1
<1
< 1
<1
<1
Spiked Amount
35
39
28
13
51
42
46
40
86
50
46
40
37
42
42
40
42
40
42
36
40
42
36
38
38
44
40
40
46
63
40
Recovered
X
33
29
27
9
44
34
46
32
96
32
34
38
26
31
36
26
34
34
34
28
31
31
29
25
25
37
25
26
28
33
28
5
3
5
2
5
3
3
2
5
2
2
3
3
2
1
2
1
2
1
1
2
3
3
2
2
3
1
1
3
3
3
94
74
96
70
86
81
100
80
86
64
74
95
70
74
86
65
81
85
81
78
78
74
81
67
67
84
63
66
61
52
70
260
-------
. .. 1.980 .
SOUTH DITCH BASE-TO.TRAL FRACTION QUALITY ' CONTROL '< ug/.l)
LOW LEVEL SPIKE
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Ni trosodi -n-propy 1 ami ne
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroanil ine
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlate
Fluorene
1 ,2-Diphenylhydrazine
4-Broinophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo(a)pyrene
Initial Spiked Amount
<1 3.5
<1 3.9
<1 2.8
<1 1.3
<1 5.1
<1 4.6
-------
Sou-th DTtch Acid
1980 .
Fraction".Quality Control (frg/1
Compound
2-Chlorophenol
Phenol
2, 4-Dimethyl phenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloro-3-methyl phenol
Pentachlorophenol
DIQ Phenol
-.':...- High
Initial Spiked Amount
<1 74
<1 274
<1 119
<1 113
<1 106
<1 101
<1 48
<1 100
Level Spike
Recovered
X
53
134
96
89
87
81
38
50
S
4
8
8
7
8
6
6
6
"R
72
49
81
79
82
80
79
50
Low Level Spike
2-Chlorophenol
Phenol
2,4-Dimethylphenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloro-3-methylphenol
Pentachlorophenol
D,Q Phenol
7.4
27
12
11
11
10
4.8
100
5.1
13
9.1
8.3
8.8
7.9
3.3
. 51
2
4
2
2
1
2
1
6
69
48
76
75
80
79
69
51
262
-------
1980 . ;
West Lagoon Volatile Fraction Quality'Control (yg/1)
High Level- Spike
Recovered
Compound Initial Spiked Amount.. X
Ethylbenzene <1 13 9.4 .6 72
Chlorobenzene <1 18 15 2 86
Toluene <1 10 9.8 .5 98
Perchloroethylene <1 31 30 .8 98
Tetrachloroethane <1 33 32 .'3 97
Bromoform <1 82 68 2 83
Trichloroethylene <1 9.1 9.1 .3 1QO
1,1,2-Trichloroethane <1 28 28 .2 100
Benzene <1 18 19 '.2 106
Cis-l,3-Dichloropropene <1 26 25 .2 97
1,1,1-Trichloroethane <1 32 28 .9 89
Trans-l,3-Dichloropropene <1 24 22 .5 93
1,2-Dichloropropane <1 24. 23 .3 98
1,2-Dichloroethane 25 22 46 '.4 95
1,1-Dichloroethane <1 24 24 .3 100
Acetone <1 10 6 2' 60
Acrolein <1 12 81 67
Acrylonitrile <1 13 82 63
Isopropanol <1 13 83 63
Trichlorofluoromethane
-------
1980.
west Lagoon Volatile Fraction Quality Control (yg/1)
Compound Initial
Ethylbenzene <1
Chlorobenzene <1
Toluene <1
Perchloroethylene <1
Tetrachloroethane <1
Bromoform <1
Trichloroethylene <1
1,1,2-Trichloroethane <1
Benzene <1
Cis-l,3-Dichloropropene <1
1,1,1-Trichloroethane <1
Trans-l,3-Dichloropropene <1
1,2-Dichloropropane
-------
1980
WEST'LAGOON''BASE-NEUTRAL. QUALITY CONTROL
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethans
Nitrobenzene
Isophorone
2-Chloroanil ine
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlate
Fluorene
1 ,2-Diphenylhydrazine
4-Bromophenyl phenyl ether
Hsxcicn i GrGusnzsris
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Gutyl benzyl phthalate
Dichlorobenzidine
8enzo(a)pyrene
Chrysene
HIGH LEVEL SPIKE
Initial Spi
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
i
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
<= 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
<= 1
(ug/1)
ked Amount
35
39
28
13
51
46
42
40
86
50
46
40
37
42
42
40
42
40
42
36
40
42
38
38
38
44
40
40
46
63
40
40
Recovered
X
31
26
21
8
43
31
33
36
84
46
32
38
30
36
33
31
34
34
32
28
30
25
31
30
29
32
29
28
36
32
28
30
4
3
3
3
5
5
2
7
6
6
3
6
5
4
7
4
3
2
4
3
A
t
3
3
4
2
3
3
3
4
7
3
3
%R
88
67
75
62
86
68
79
91
93
92
70
95
82
85
80
78
81
84
77
78
7C
/ *J
60
81
79
75
73
72
70
78
51
71
76
265
-------
1980
.' -WEST LASOON BASE-NEUTRAL QUALITY .CONTROL .(pg/1)
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Ni trosodi -n-p ropy! ami ne
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlata
Fluorene
1 ,2-Di phenylhydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Ptiena threne
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidirie
3enzo(a)pyrene
Ghrysene
LOW LEVEL
Initial
<]
<1
<=1
<1
*=!
< 1
< 1
-------
1980
West L'agdotr Actd'fractTon QuaTtty .'Control'" (ijg'/T)'
High-level Spike
Compound
2-Chlorophenol
Phenol
2,4-Dimethylphenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloro-3-methylphenol
Pentachlorophenol
DIQ Phenol
Initial Spiked Amount
< 1
3
< 1
< 1
74
274
119
113
106
101
48
100
Recovered
X
61
135
71
84
80
73
42
50
S
3
9
9
8
7
8
8
7
%R
83
48
60
74
75
72
88
50
Low Level Spi ke
2-Chlorophenol
Phenol
2,4-Dimethylphenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloro-3-methyl phenol
Pentachlorophenol
DIQ Phenol
7.4
27
12
11
11
10
4.8
100
4.8
17
6
7.8
8.7
6.5
2.1
. 51
2
3
3
4
3
4
2
65
52
48
71
79
65
43
51
267
-------
1980.
influent VciTat'ile'f-r'actTon 'Quality -'Control'' ("M/T
Compound
Ethyl benzene
Chlorobenzene
Toluene
Perchloroethylene
Tetrachloroethane
Bromoform
Trichloroethylene
1,1,2-Trichloroethane
Benzene
Ci s - 1, 3- Dichloro propane
1,1,1-Trichloroethane
Trans- 1, 3-D ichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Acetone
Acrolein
Acrylonitrile
Isopropanol
Trichlorofl uoromethane
1,1-Dichloroethene
Methyl ene chloride
Chloroform
Bromochloromethane
2-Bromo-l-chloropropane
1,4-Dichlorobutane
V
Initial
-------
, .1980 .
Influent. Vo.1-a.tH-e Fraction Qual-i-ty. Control '(.ug/1-)
Low Level. Spike
Recovered
Compound Initial Spiked Amount X S %R_
Ethylbenzene <1 1.3 1.0 .2 79
Chlorobenzene 2 1.8 3.5 .3 81
Toluene 550 1.0 Spike too low
Perchloroethylene 160 3.1 Spike too low
Tetrachloroethane <1 3.3 2.6 .5 80
Bromoform <1 8.2 5.3 I 65
Trichloroethylene 9 .91 Spike too low
1,1,2-Trichloroethane <1 2.8 2.3 .3 83
Benzene 26 1.8 Spike too low.
1,1,1-Trichloroethane 60 3.2 Spike too low
Trans-l,3-Dichloropropene <1 2.4 1.9 .4 80
1,2-Dichloropropane <1 2.4 2.0 .2 83
1,2-Dichloroethane 510 2.2 Spike too low
1,1-Dichloroethane <1 2.4 2.2 .3 90
Trichlorofluoromethane <1 3.3 2.7 .5 81
1,1-Dichloroethene <1 2.2 1.9 .2 86
Hethylene chloride <1 2.4 1.9 .2 79
Chloroform 610 2.8 Spike too low
Bromochloromethane <1 39 38 3 98
2-Bromo-l-chloropropane <1 30 29 2 97
1,4-Dichlorobutane <1 23 22 2 97
Cis-l,3-Dichloropropene <1 2.6 . 2.2 .5 86
269
-------
1-980..
'' INFLUENT'-BASE'-NEUTRAL 'FRACTION QUALITY CONTRO'L'-'Cyg/l )
HIGH LEVEL SPIKE
Compound
Bis(2-chloroethyl)ether
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
iN-Ni trosodi -n-propylami ne
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthalene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlate
Fluorene
1,2-Diphenylhydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo(a)pyrene
Chrysene
Initial Spiked Amount
<1 35
<1 39
<1 28
2 13
<1 51
< 1 46
<1 42
<1 40
121 86
<1 50
<1 46
2 40
<1 ' 37
<1 42
<1 42
<1 40
<1 42
<1 40
<1 42
<1 36
<1 40
<1 42
<1 36
<1 38
<1 38
<1 44
<1 40
<1 40
<1 46
<1 63
<1 40
<1 40
Recovered
X
21
12
9
6
22
10
12
20
163
25
18
18
18
29
18
25
29
24
21
17
1.9
25
. 17
23
23
26
27
28
25
12
17
16
3
2
2
2
2
2
2
2
8
3
3
2
2
4
2
2
8
4
2
2
2
5
3
2
2
3
3
3
3
4
4
3
%R_
60
32
33
31
44
23
28
50
49
50
39
40
48
68
42
63
68
60
50
47
48
59
46
60
61
59
67
71
55
20
43
40
270
-------
1980
'INFLUENT'BASE-NEUTRAL" F RAPT I ON QUALITY- CONTROL (yq/1:)
LOW LEVEL SPIKE
Recovered
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroanil ine
Bis (2- chlo roe thoxy) methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenapnthalene
Acenaphthene
2,4-Dini tro toluene
Di ethyl phthlate
Fluorene
1 ,2-Diphenylhydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenathrene
Oi-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
fjenzo(a)pyrene
Chrysene
Initial
< 1
< 1
< 1
2
< }
< 1
< 1
< 1
121
< 1
< 1
2
<= 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
Spiked Amount
3.5
3.9 '
2.8
1.3
5.1
4.6
4.2
4.0
8.6
5.0
4.6
4.0
3.7
4.2
4.2
4.0
4.2
4.0
4.2
3.6
4.0
4.2
3.8
3.8
3.8
4.4
4.0
4.0
4.0
12.6
4.0
4.0
X
2.4
1..1
.8
2.3
2.7
.7
1.4
2.0
124.0
3.2
1.4
3.9
1.8
1.5
.7
2.0
2.1
2.4
1.9
1.6
1.8
2.0
1.5
2.2
1.9
2.4
2.4
2.5
2.5
1.2
1.4
1.6
S
.8
.2
.2
.1
.8
.3
.6
.7
.7
1.3
.6
1.2
.7
.6
.3
.9
1.3
1.2
.8
.2
.9
.8
.8
1.1
.9
.7
.8
1.4
1.4
.9
1.3
1.1
69
28
30
20
52
16
34
50
35
65
31
47
50
35
17
50
51
59
46
45
45
47
40
57
49
54
60
62
62
10
36
41
271
-------
1980
Influent Acid Fraction Quality Control jug/I)
Compound
2-Chlorophenol
Phenol
2, 4-Dimethyl phenol
2,4-Dichlorophenol
2 ,4 ,6-Tri chlorophenol
4-Chloro-3-methyl phenol
Pentachlorophenol
DIQ Phenol
Initial
8
17
< 1
1
2
< 1
< I
< 1
Spiked Amount
74
274
119
113
106
101
48
100
High Level Spike
Recovered
X
56
157
69
88 :
95
71
33
53
3
8
8
10
9
8
8
7
%R
65
51
58
77
88
70
68
53
Low Level Spike
2-Chlorophenol 8
Phenol 17
2,4-Dimethylphenol < 1
2,4-Dichlorophenol 1
2,4,6-Trichlorophenol 2
4-Chloro-3-methylphenol < 1
Pentachlorophenol < 1
D, Phenol < 1
7.4
27
12
11
11
10
4.8
100
12
30
6.5
9.0
11
5.8
2.8
52
2
5
2
2
3
2
1
7
60
48
54
73
81
68
59
52
272
-------
1980
VI e'st'Lagoon -Sludge 'Volatile Fraction Quality Control
High Level Spike
Compound
Ethyl benzene
Chlorobenzene
Toluene
Perch!oroethylene
Tetrachloroethane
Bromoform
Trichloroethyl ene
1,1,2-Trichloroethane
Benzene
Cis-l,3-Dichloropropene
1,1,1-Trichloroethane
Trans-1,3-Oichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Acetone
Acrolein
Acrylonitrile
Isopropanol
Trichlorofluoromethane
1,1-Dichloroethene
Methylene chloride
Chloroform
Bromochloromethane
2-Bromo-l-chloropropane
1,4-Dichlorobutane
Initial Spiked Amount
11
2
40
3
< 1
2
< 1
2
< 1
< 1
< 1
< 1
8
< 1
< 1
< 1
13
18
10
31
33
82
9.
28
18
26
32
24
24
22
24
10
12
13
13
33
22
24
28
39
30
23
Recovered
X
20
16
45
29
29
9.8
9.9
26
19
15
31
11
21
26
20
6
8.2
9.0
11
27
18
. 22
20
36
26
20
S
3
4
15
3
3
6
1
2
2
3
6
2
2
3
4
4
5
4
6
10
5
2
6
3
4
3
%R
69
81
51
84
88
12
88
94
95
59
98
47
88
80
85
60
68
69
83
81
82
85
71
92
87
87
273
-------
1980
West LagQon-Sludge- Volatile'Fraction Quality Control (yg/kqj
Low -Level Spike
Compound
Ethylbenzene
Chlorobenzene
Toluene
Perch! oroethylene
Tetrachloroethane
Bromoform
Trichloroethylene
1,1,2-Trichloroethane
Benzene
Cis-l,3-Dichloropropene
1,1,1-Trichloroethane
Trans-l,3-Dichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Trichlorofluorornethane
1,1-Dichloroethene
Methylene chloride
Chloroform
Bromochloromethane
2-Bromo-l-chloropropane
1,4-Dichlorobutane
Initial
11
2
40
3
< l
< 1
2
< 1
2
< 1
< 1
< 1
< i
8
< 1
< 1
< 1
2
< 1
< 1
< 1
< i
Spiked Amount
1.3
1.8
1.0
3.1
3.3
8.2
.90
2.8
1.8
2.6
3.2
2.4
2.4
2.2
2.4
2.8
1.9
2.4
2.4
39
30
23
Recovered
X
Spike too
3.1
Spike too
4.3
1.2
.49
2.5
1.8
3.3
.85
1.8
.74
1.6
9.3
1.5
.39
1.0
3.3
1.8
36
25
20
S
low
.3
low
.5
.3
.2
.5
.5
.8
.3
.2
.3
.3
.4
.6
.2
.5
.6
.5
4
3
3
%R
62
43
40
6
55
65
74
34
56
31
65
60
64
14
53
55
74
92
86
87
274
-------
' 1980
' WEST LAGOON 'SLUDGE BAS'E-NEuTRALTMCTTON''QUALITY CONTROL'-(mg/kg)'-
HIGH LEVEL SPIKE - SOXHLET METHOD
Recovered
X
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroanil ine
B i s ( 2-chl oroethoxy )methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlate
Fluorene
1 ,2-Diphenylhydrazine
4-Bromophenyl plvenyl ether
Hsxflchl orobep.zens
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo(a)pyrene
Chrysene
Initial
<.05
<.05
<.05
.05
<.05
<=.05
<=.05
<.05
3.6
<.05
<.05
.71
-------
1980
WEST LAGOON- SLUDGE BASE-NEUTRAL FRACTION QUALITY CONTROL (mg,
LOW LEVEL SPIKE -
Compound
Bis(2-chloroethyl)ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis( 2-chl oroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthylene
Acenaphthene
2,4-Dinitrotoluene
Diethyl phthlate
Fluorene
1 ,2-Di phenyl hydrazine
4-Bromophenyl phenyl ether
Hexschlcrcbsnzene
Anthracene
Phena threne
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
3enzo(a)pyrene
Chrysene
Initial
< .05
< .05
< .05
< .05
< .05
< .05
< .05
< .05
3.6
< .05
< .05
.71
< .05
< .05 '
< .05
< .05
< .05
< .05
< .05
< .05
< .05
< .05
.34
< .05
.13
< .05
< .05
< .05
3.4
< .05
< .05
SOXHLET METHOD
Spiked Amount
.70
. .78
.56
.26
1.0
.92
.84
.80
1.7
1.0
.92
.80
.74
.84
.84
.80
.84
.84
.72
.80
.84
.72
.76
.76
.88
.80
.80
.92
.13
.80
.80
Recovered
X
.45
.29
.27
.17
.62
.20
.48
.56
kq) -
s
.40
.13
.09
.09
.26
.13
.24
.31
4.6 2.8
'.71 .38
.52 .20
1.2 .46
.42 .25
.43 .28
.52 .16
.47 .20
.58 .12
.39 .17
.47 .21
.24 .14
.39 .28
.19 .09
.86 .09
.56 .17
.67 .27
.42 .11
.54 .11
.32 .30
Spike too low
.58 .18
.37 .12
%R
64
37
48
46
62
22
58
70
61
71
57
62
57
51
62
59
69
47
65
30
47
26
68
74
61
52
68
35
72
46
276
-------
1980
13pU
West Lagoon Sludge. Quality Control (mg/kg)'
High Level Spike
Compound
2-Chlorophenol <.05
Phenol <.05
2,4-Dimethylphenol <.05
2,4-Dichlorophenol <.05
2,4,6-Trichlorophenol <.05
4-Chloro-3-methyl phenol <.05
Pentachlorophenol <.05
DIQ Phenol <.05
Initial Spiked Amount
15
55
24
23
21
20
9.6
10-
Recovered
X
13
38
20
21
18
17
7.8
7.1
S
3
6
4
3
5
5
4
3
%R
84
69
84
90
85
86
80
71
Low Level Spike
2-Chlorophenol <.05
Phenol <.05
2,4-Dimethylphenol <.05
2,4-Dichlorophenol <.05
2,4,6-Trichlorophenol <.05
4-Ch1oro-3-methylphenol <.05
Pentachlorophenol <.05
D Phenol <.05
1.5
5.5
2.4
2.3
2.1
2.0
1.0
10
1.2
3.4
1.9
1.9
1.7
1.6
.75
7:0
.8 80
1.0 65
1.1 78
1.1 81
1.4 82
1.1 80
.35 75
3 70
277
-------
INFLUENT QUALITY CONTROL CASE-NEUTRAL FRACTION (yg/1) 1981
Compound
Bis(2-chloroethyl )ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene '
Isophorone
2-Chloroam'line
Bi s (2-chl oroethoxy )methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2, 6-Dinitro toluene
Dimethyl phthalate
Acenaphthalene
Acenaphthene
2,4-Dinitrotoluene
Di ethyl phthlate
Fl uorene
1 ,2-Diphenyl hydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo(a)pyrene
Chrysene
Initial
1
1
1
1
1
1
1
130
1
1
5.6
1
1
3.6
1
1
1
1.6
1
1
1
1
1
0.7
1.2
1
1
1
6.8
1
1
Spiked
Amount
43,7
49.4
34.5
62.9
57.5
51.7
53.4
54.7
61.7
57.9
49.2
46.0
52.0
53.2
50.1
51.2
49.6
51.6
44.0
47.8
52.0
46.8
48.5
48.6
55.9
50.2
48.0
57.0
52.6
49.7
48.5
Recovered
X
42.0
42.0
29.0
54.1
48.9
43.9
45.4
180
56.1
50.4
48.4
45.1
40.0
49.4
45.6
44.0
45.1
47.0
37.0
42.1
44.2
37.9
42.7
46.9
52.6
43.7
41 .3
48.5
65.2
42.7
40.3
S
2.7
2.7
1.4
2.5
2.0
2.3
2.1
7.2
6.8
3,3
3.3
2.8
1.2
1.1
3.1
3.6
2.3
2.7
2.0
2.4
0.6
2.1
3,4
0.7
1.7
1.0
110
1.0
6.4
3.1
1.0
%R
96
85
84
86
85
85
85
91
91
87
87
98
77
86
91
86
91
88
84
88
85
81
88
95
92
87
86
85
111
86
83
278
-------
INFLUENT VOLATILE FRACTION QUALITY CONTROL (yg/1)
Compound
Ethylbenzene
Chlorobenzene
Toluene
Perch! oroethylene
Tetrachloroethane
Bromoform
Trichl oroethylene
1 ,1 ,2-Trichloroethane
Benzene
Cis-1 ,3-Dichloropropene
1 ,1 ,1-Trichloroethane
Trans-1 ,3-Dichloropropene
1 ,2-Dichloropropane
1 ,2-Dichloroethane
1 ,1-Dichloroethane
Trichlorofluoromethane
1 ,1-Dichloroethene
Chloroform
Trans 1 ,2-dichloroethylene
Initial
1
1
1,150
250
1
1
25
1
150
1
100
1
1
100
1
1
1
1,000
20
Spiked
Amount
17.3
22.1
17.3
32.5
31.9
57.8
29.3
27.9
17.6
23.6
26.8
24.1
23.1
24.7
23.5
26.2
24.4
29.7
25.1
Recovered
X
15.9
21.0
1,165
280
30.0
51 ,4
54.0
27.6
164,6
22.9
125.5
22.6
22.6
21 ,5
22.3
24.6
24.2
1,028
45.3
S
.7
.9
o9
1.6
.6
2.4
.8
2.7
.2
1.3
.2
.4
.5
1.2
.4
o4
.4
.6
.7
o/n
Am
92
95
85
92
94
89
99
99
83
97
95
94
98
87
95
94
99
94
101
INFLUENT QUALITY CONTROL ACID FRACTION (yg/1) 1981
. Compound
2-Chlorophenol
Phenol
2, 4-Dimethyl phenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloro-3-methyl phenol
Pentachlorophenol
2-Fluorophenol
Initial
1
8
1
1
1
1
1
1
Spiked
Amount
37
137
59.3
56.6
53.1
50.7
24.7
25
Recovered
X
" 33.7
112
36.8
51.5
51.0
43.6
24.2
16.8
S
1.9
2.7
2.9
2.1
0.8
3.6
0.7
0.4
^
91
76
62
91
96
86
98
67
279
-------
SOUTH DITCH QUALITY CONTROL BASE-NEUTRAL FRACTION (yg/1) 1981
Compound.
Bis(2-chloroethyl )ether
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
N-fli trosodi-n-propyl ami ne
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthalene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthalene
Acenaphthene
2, 4-Dinitro toluene
Di ethyl phthalate
Fl uorene
1,2-Diphenyl hydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenathrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo (a) pyrene
Chrysene
Initial
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
5
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
Spiked
Amount .
43.7
49.4
34.5
12.2
62.9
57.5
51.7
53.4
54.7
61.7
57.9
49.2
46.0
52.0
53.2
50.1
51.2
49.6
51.6
44.0
47.8
42.0
46.8
48.5
48.6
55.9
50.2
48.0
57.0
52.6
49.7
48.5
Recovered
X .
39.8
36.6
33.1
9.4
54.1
47.7
50.7
42.7
60.0
41.9
45.2
45.8
34.9
39.5
45.8
40.1
46.1
42.2
41.8
34.3
40.6
41.1
37.9
35.9
33.0
48.1
32.6
31.7
34.8
42.1
34.8
36.4
S
4.2
3.7
5.6
3.1
4.7
4.2 '
3.7
3.6
5.2
3.1
2.7
4.4
4.3
3.1
2.0
2.2
3.6
2.1
2.5
2.7
3.1
4.6
3.8
3.7
2.3
3.4
3.6
2.2
3.4
4.9
3.6
3.4
%R
91
74
96
77
86
82
98
80
95
68
78
93
76
76
86
80
90
85
81
78
85
79
81
74
68
86
65
66
61
80
70
'75
280
-------
SOUTH DITCH VOLATILE FRACTION QUALITY CONTROL (ug/-1) 1981
Compound
Ethyl benzene
Chlorobenzene
Toluene
Perchloroethylene
Tetrachloroethane
Bromoform
Trichloroethylene
1,1,2-Trichloroethane
Benzene
Cis-l,3-Dich1oropropene
1,1,1-Trichlo roe thane
Trans-l,3-Dichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Trichlorofl uoromethane
1,1-Dichloroethene
Methyl ene chloride
Chloroform
Trans-l,2-Dichloroeth.ylene
Initial
< 1
< 1 .
11
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
5
< 1
< 1
< 1
< 1
< 1
< 1
Spiked
Amount
17.3
22.1
17.3
32.5
31.9
57.8
29.3
27.9
17.6
23.6
26.8
24.1
23.1
24.7
23.5
26.2
24.4
26.5
29.7
25.1
Recovered
"x
17.1
20.8
17.1
29.3
28.1
57.2
25.2
25.9
19.6
22.7
27.6
23.1
22.4
24.7
22.8
19.9
16.6
24.4
27.9
23.1
S
.9
.8
.5
1
2
2
.9
.8
.4
.4
.3
.3
.3
.4
.2
.6
1.4
.3
.4
.8
c/p
/or\
93
94
99
90
88
99
86
93
100
96
103
96
97
100
97
76
68
92
94
92
SOUTH DITCH QUALITY CONTROL ACID FRACTION (ug/1) 1981
Compound
2-Chlorophenol
Phenol
2, 4- Dimethyl phenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chl oro-3-methyl phenol
Pentachlorophenol
2-Fluorophenol
Initial
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
Spiked
Amount
37
137
59.3
56.6
53.1
50.7
24.7
25
Recovered
X
33.3
106.9
37.9
50.1
50.4
44.6
23.5
17.5
S
2.2
3.1
3.4
2.0
1.0
3.3
1.0
0.6
%R
90
78
64
90
95
88
95
70
281
-------
WEST. LAGOON QUALITY CONTROL BASE-NEUTRAL FRACTION (ug/l)"1981
Compound
Bis(2-chloroethyl )ether
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
N-Nitrosodi-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Chloroaniline
Bis(2-chloroethoxy)methane
Trichlorobenzene
Naphthalene
2-Chloronaphthal ene
2,6-Dinitrotoluene
Dimethyl phthalate
Acenaphthalene
Acenaphthene
2, 4-Dinitro toluene
Diethyl phthalate
Fluorene
1 , 2-Di phenyl hydrazi ne
4-Bromophenyl phenyl ether
Hexachlorobenzene
Anthracene
Phenanthrene
Di-n-butyl phthalate
Pyrene
Fluoranthene
Butyl benzyl phthalate
Dichlorobenzidine
Benzo (a) pyrene
Chrysene
Initial
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
120
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1 .
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
Spiked
Amount
43.7
49.4'
34.5
12.2
62.9
57.5
51.7
53.4
54.7
61.7
57.9
49.2
46.0
52.0
53.2
50.1
51.2
49.6
51.6
44.0
47.8
52.0
46.8
48.5
48.6
55.9
50.2
48.0
57.0
52.6
49.7
48.5
Recovered
X
42.0
43.5
30.7
10.6
62.9
48.9
53.3
41.1
173
60.5
61.0
46.7
42.3
42.1
48.4
46.1
44.5
43.6
49.5
38.3
42.5
44.7
42.1
45.6
44.7
50.3
43.7
39.4
45.0
41.6
43.2
39.8
S
3.1
4.2
2.0
1.0
4.5
3.5
2.4
2.8
8.0
3.6
4.7
3.7
4.7
3.9
0.8
0.9
2.3
3.2
1.7
1.6
0.8
2.3
0.5
3.0
1.3
2.9
3.5
2.4
4.6
8.9
5.8
4.6
%R
96
88
89
87
100
85
103
77
97
98
88
95
92
81
91
92
87
88
96
87
89
86
90
94
92
90
87
82
79
79
87
82
282
-------
WEST'lAGOON 'VOLATILE-FRACTION- QUALITY -CONTROL (tig/1) 1981
Compound
Ethyl benzene
Chlorobenzene
Toluene
Perch! oroethyl ene
Tetrachloroethane
Bromoform
Trichl oroethyl ene
1,1,2-Trichloroethane
Benzene
Cis-l,3-Dichloropropene
1,1,1-Trichloroethane
Trans-l,3-Dichloropropene
1,2-Dichloropropane
1,2-Dichloroethane
1,1-Dichloroethane
Trlchlorofl uoromethane
1,1-Dichloroethene
Methyl ene chloride
Chloroform
Trans- 1, 2- Dichl oroethyl ene
Initial
< 1
< 1
11
10
< 1
< 1
3
< 1
2
< 1
5
< 1
< 1
46
< 1
< 1
< 1
< 1
55
< i
Spiked
Amount
17.3
22.1
17.3
32.5
31.9
57.8
29.3
27.9
17.6
23.6
26.8
24.1
23.1
24.7
23.5
26.2
24.4
26.5
29.7
25.1
Recovered
X
15.2
18.8
26.9
35.0
33.5
59.5
28.8
27.3
17.5
23.6
26.7
23.4
22.9
71.7
26.3
25.9
24.6
21.5
77.3
26.6
S
.9
.7
.5
2.9
.7
3.5
1.8
1.6
.3
.4
.8
.6
.7
1.0
.3
2.1
1.2
.4
.9
1.5
%R
88.
85
92
77
105
103
88
98
88
98
81
97
99
104
112
99
101
81
75
102
WEST LAGOON QUALITY CONTROL ACID FRACTION (yg/1) 1981
Compound
2-Chlorophenol
Phenol
2, 4- Dime thy! phenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chl oro-3-methyl phenol
Pentachlorophenol
2-Fluoro phenol
Initial
< 1
4
< 1
< 1
< 1
< 1
< 1
< 1
Spiked
Amount
37
137
59.3
56.6
53.1
50.7
24.7
25
Recovered
X
34.8
78.0
40.3
54.9
54.2
47.7
23.5
17.5
S
1.5
5.2
.6
1.1
2.7
3.4
1.9
1.2
%R
94
54
68
97
102
94
95
70
283
-------
PC3 Ident. .
Results of Kerr Laboratory Check Samples
PCB Concentration, ug/1
Sample No. . , Reported Value
True Value.
1254 1
1016 2
1254 3
1016 3
Volati
Parameter
Chloroform »1
n
1 ,2 Dichloroethane -rl
;f2
Di bromochl oromethane :?'!
?2
Bromodichl oromethane ,vl
?2
Bromoform ^1
7 2
Carbon Tetrachloride £1
7 2
1,1,1 Trichloroethane ?1
'0
,7 6
Trichloroethylene #1
«o
rrd
Perchloroethylene #1
#2
0.86
0.62
0.66
0.30
le Organi cs , ijg./l
Reported Value
9.1
61
1 .9
27
2.3
15
1.6
15
3.5
11
2.9
11
<1
13
<1
21
<1
13
True
9
68
1
27
2
17
1
11
L.
14
1
12
-
11
-
18
-
8
0.
0.
0.
0.
Val
.13
.46
.39
.21
.74
.15
.19
.90
.85
.24
.68
.57
-
.19
-
.97
-
.76
96
65
58
26
ue
284
-------
APPENDIX C
Sludge Distribution Map for 1980
285
-------
EAST LAGOON
Sample
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
*Extra Samples
*1
*2
Angle of Degrees
"F" Structure
155
135
115
105
125
135
145
165
155
135
115
105
125
135
145
165
135
150
Distance
in Yards
200
200
200
300
300
300
300
300
400
400
400
500
500
500
500
500
550
450
Depth of
Sludge
4 "
4 "
6 "
3 "
5 "
8 "
6 "
3 "
3 "
7 "
3 "
No Sample
2 "
5 "
3 "
4 "
3 "
lh-2 "
286
-------
WEST LAGOON
Sample
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Angle of Degrees
"F" Structure
245
225
205
195
215
225
235
255
245
225
205
195
215
225
235
255
Distance
in Yards
200
200
200
300
300
300
300
300
400
400
400
500
500
500
500
500
Depth of
Sludge
3 "
2%"
y
y
y
i "
0 "
3 "
i "
0 "
0 "
0 "
*0 "
*0 "
*0 "
*0 "
* No Sludge - No Sample Taken
287
-------
APPENDIX D
ANALYTICAL PROCEDURES
Gas Chromatography-Mass Spectrometry
Water samples were analyzed according to EPA protocol (4&5) using combined
gas chromatography-mass spectrometry and gas chromatography.
s ~
Table D-l represents the volatile fraction as described in the EPA list of
priority pollutants. Additional compounds have been added to this list
along with the detection limits of this laboratory. Volatile fraction
compounds were analyzed by the purge-trap technique using a Tekmar LSC-2
Liquid Sample Concentrator coupled to a Finnigan 4021 GC/MS system. A
5-rnl sample was purged for 11 minutes with a helium flow of 30 ml/min.
The effluent was trapped on a Tenax-Silica gel column which was held at
ambient temperature. After the purge cycle was completed, the trap was
flash-heated to 180°C with the GC carrier gas routed through it to the
analytical column. Instrumental conditions were as follows:
Column: 8 ft stainless steel, 1% SP-1000
on Carbopack B (60/80 mesh)
Carrier: Helium, 20 ml/min.
Injector: 200°C
Program: 3 min. hold at ambient, then rapidly
heated to 50 C for 3 min. and pro-
grammed to 200 C at 8 /min.
Separator: Glass-jet, 250°C
Transfer Line: 250°C
Filament: .3 ma
Electron Energy: 70 ev
289
-------
VOLATILE FRACTION
Water Detection Limit Sludge, Soil, & Corn
Compound (mg/1) Detection Limit (mg/1)
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methyl ene chloride
Tri fl uorochloromethane
1 , 1-Di chl oroethyl ene
1,1-Dichloroethane
Trans-l,2-dichloroethylene
Chloroform
1,2-Dichloroethane
1,1,1-Tri chloroethane
Carbon tetrachloride
Bro modi chloromethane
1 , 3-Di chl oropropane
Tri chl oroethyl ene
Bis-1 ,2- di chl oropropane
Trans- 1, 2- di chl oropropane
1,1,2-Tri chloroethane
Benzene
2-Chloroethyl vinyl ether
Bromoform
1,1,2,2-Tetrachloroethane
Perch! oroethyl ene
Toluene
Chlorobenzene
Ethyl benzene
Acrolein
Acrylom'trile
Styrene*
Chloroprene*
Dibromochloromethane
.01
.01
.01
.01
.001
.001
.001
.001
.001
.001
.001
.001
.005
.001
.001
.001
.001
.001
.001
.001
.01
.01
.001
.001
.001
.001
.001
.01
.01
.01
.001
.001
.05
.05
.05
.05
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.05
.05
.01
.01
.01
.01
.01
.1
.1
.1
.01
.01
Not present on EPA's list of priority pollutants
290
-------
Scan :'"' 33-2-5Cr;amu:-' T.9& sec/'i^j:; ;'.t)5-:see'. down"
Quantitation was based on internal standards, using bromochloromethane,
2-bromo-l-chloropropane, and 1 ,4-dichlorobutane as representative of early,
middle, and late eluting compounds. A mixed volatile priority pollutant
standard was analyzed daily to determine response factors and overall system
performance.
Semi-volatile compounds as given on the EPA priority pollutant list are
detailed in Tables D-2 - D-4. Additional compounds have again been added to this
list along with the detection limits of this laboratory. Semi-volatile
compounds were extracted from water samples using a two-step procedure. A
2-liter sample was adjusted to pH 12 with 6N NaOH and serially extracted
with 150-, 50-, and 50-ml portions of dichloromethane. The solvent layer
was dried with sodium sulfate and concentrated in a Kuderna-Danish evaporator.
This was used for the analysis of the base-neutral fraction as listed in
Table 5. The aqueous phase was then made acidic (ph
-------
TABLE D-2
BASE-NEUTRAL FRACTION
Compound
Water Detection Limit
(mg/1)
Sludge, Soil, & Corn
Detection Limit (mg/1)
Dichlorobenzene (3 isomers)
Hexachloroethane
Pentachloroethane
Hexachlorobutadiene
1,2,4-Trichlorobenzene
Naphthalene
Hexachl orocycl opentadi ene
Nitrobenzene
2-Chloronaphthalene
Acenaphthene
Isophorone
Fl uorene
2, 4-Dinitro toluene
1 ,2-Di phenyl hydrazi ne
2,6-Dinitrotoluene
N-Ni trosodi phenyl ami ne
Hexachlorobenzene
4- Bromo phenyl phenyl ether
4-Chlorophenyl phenyl ether
Anthracene
Phenanthrene
Dimethyl phthalate
Bis(2-chloroethyl )ether
Di-n-butyl phthalate
Diethyl phthalate
Butyl benzyl phthalate
Benzidine
Pyrene
Fluoranthene
Chrysene
Bi s ( ethyl hexyl )phthal ate
Benzo(a)anthracene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenzo( a, h) anthracene
Benzo(g,h,i)perylene
3,3'-Dichlorobenzidine
Tetrachlorodibenzo-p-dioxin
N-Ni trosopropyl ami ne
Pentachloronitrobenzene*
i
.001
.001
.001
.001
.001
.001
.001
.001
.001
.001
.001
.001
.01
.001
.01
.005
.001
.001
.001
.001
.001
.001
.001
.001
.001
.001
.01
.001
.001
.001
.001
.001
.001
.005
.01
.01
.01
.001
.01
.001
.001
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.08
.08
.05
.05
.05
.05
.05
.05
.05
.05
.05
.05
.10
.05
.05
.05
.05
.05
.05
.08
.10
.10
.10
.05
.10
.05
.05
(Continued)
292
-------
' TABLE' D-2
(Continued)
Water Detection Limit Sludge, Soil, & Corn
Compound (mg/1) Detection Limit (mg/1)
Aniline* .001 .05
Chioroanilines* .001 .05
Acenaphthalene .001 .05
Bis(2-chloroisopropyl)ether .001 .05
Bis(2-chloroethoxy)methane .001 .05
* Not present on EPA's list of priority pollutants
TABLE D-3
ACID FRACTION
Water Detection Limit Sludge, Soil, & Corn
Compound (mg/1) Detection Limit (mg/1)
2-Chlorophenol
Phenol
2,4-Dichlorophenol
2-Nitrophenol
4-Chloro-3-methyl phenol
2,4,6-Trichlorophenol
2, 4-Dimethyl phenol
2,4-Dinitrophenol
2-Methy 1 -4 , 6-Di ni t rophenol
4-Nitrophenol
Pentachlorophenol
Methyl phenols*
.001
.001
.001
.01
.001
.001
.001
.01
.01
.01
.01
.001
.05
.05
.05
' .1
.05
.05
.05
.5
.5
.1
.1
.05
* Not present on EPA's list of priority pollutants
293
-------
TABLE" 0-4
PESTICIDES AND PCB FRACTION
Compound
Mi rex
Met ho xyc hi or
Endosulfan
* BHC
3^ BHC
^3 BHC
Aldrin
Heptachlor
Heptachlor epoxide
Endosulfan sulfate
Endrin
Chlordane
Toxaphene
Dieldrin
DDT and Analogs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Water Detection Limit
(yg/D
0.1
0.5
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
1.0
1.0
0.1
0.1
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sludge, Soil , & Corn
Detection Limit (ug/1)
1
5
1
1
1
1
1
1
1
1
1
10
10
1
1
10
10
10
10
10
10
10
294
-------
Column: 30m Fused Silica, SE-30
Carrier: Helium, 1 ml/min.
Program: 50 for 5 min., then to
270° @ 8°/min.
Injection: Splitless
Injector: 250°C
Transfer Line: 270°C
Filament: .3 ma
Electron Energy: 70 ev
Scan: 33-505 amu: .95 sec. up;
.05 sec. down
Quantisation was based on internal standardization with deuterated anthra-
cene (D-|nA). A mixed priority pollutant standard was analyzed daily to
determine response factors and overall system performance. The standard
also contained 20 ng of decafluorotriphenylphosphine (DFTPP) and 40 ng of
benzidine. The GC/MS system had to meet required calibration and performance
criteria (6) before samples were processed. Acid compounds were analyzed
under the following conditions:
Column: 1% SP-1240DA, 6 ft glass
Carrier: Helium, 20 ml/min.
Program: 80° for 2 min., then to 200°
@ 120/min.
Injector: 200°C
Transfer Lines: 270°C
Filament: .3 ma
Electron Energy: 70 ev»
295
-------
Scan:
33-300 amu: 1.95 sec. up;
.05 sec. down
Quantisation was based on internal standardization with D,~A. A mixed
standard was analyzed daily to determine response factors. Performance
criteria for DFTPP and pentachlorophenol were checked daily before samples
were analyzed. Pesticides were analyzed by gas chromatography using
electron capture (ECD) and Hall Electrolytic Conductivity (HECD) Detectors.
Pesticides were confirmed on polar and nonpolar columns using the two-
detector system. Instrumental conditions were as follows:
Column:
System 1
3% OV-1, glass
Temperature: 150-250° @ 8°/min.
Final Hold:
Injector:
Detector:
Carrier:
Reactor:
Solvent:
15 min.
200°
HECD
He, 20 ml/min.
910°C
N-propanol, .5 ml/min.
System 2
3% SP2250, glass
220°C Isothermal
200°
Ni63, 350°C
N , 25 ml/min.
Reaction Gas: H,,, 20 ml/min.
All samples for GC/MS analysis were searched for three selected ions maxi-
mizing at a given retention time as described in the protocol (4&5).
Peaks not corresponding to priority pollutant standard were subjected to
library searches for identification. If the search revealed a good spectral
match (>90% fit), the peak was quantitated using the response of a similar
compound or a 1:1 ratio with the internal standard. Surrogate standard
296
-------
recovery was monitored for each sample as a measure of quality control.
A Soxhlet extraction was used for sludge and soil analysis. A 50-gram
sample of wet solid was allowed to air dry for 24 hours (7). The material
was then extracted in a Soxhlet extractor with a 50/50 mixture of acetone-
hexane for 18 hours. The extract was then concentrated in Kuderna-Danish
evaporator and the concentrate extracted three times with 1.0 N NaOH. The
hexane layer was saved as the base-neutral extract. The NaOH layer was then
made acidic to pH 3 with 1.0 N HCL and extracted three times with dichloro-
methane. Both solvent layers were concentrated as before and analyzed under
the same instrumental conditions as water samples. Volatile analysis of
sludge samples was performed by slurrying 8 grams of material in 32 ml of
blank water and adding 5 ml of slurry to the purge and trap apparatus.
Analytical conditions were identical to water samples.
Corn samples were ground in a high-speed blender and the resulting material
was Soxhlet-extracted under the same conditions as the sludge and soil samples,
Base-neutral and acid separations were also identical. No volatile analysis
was performed on the corn samples.
Additional Testing Methods
Analysis of 1,2-dichlorethane for the lagoon seepage study was performed
using Method 601 (8). Analysis was conducted using a Tekmar LSC-3-sample
concentrator coupled to a Tracor 560 gas chromatograph with a Hall 700A
detector. A 5-ml sample was purged for 11 minutes with a helium flow of
30 ml/min. The effluent was trapped on a Tenax-Silica gel column which was
held at ambient temperature. After the purge cycle was complete, the trap was
297
-------
flash-heated to 180° with the GC carrier gas routed through it to the
analytical column. Instrumental conditions were as follows:
Column: 8 ft stainless steel, 1%
SP-1000 on Carbopack B
(60/00 mesh)
Carrier: Helium, 20 ml/min.
Program: 3 min. hold at ambient, then
rapidly heated to 50 C for
3 min. and programmed to
200°C at 8°/min.
Reaction gas: H^, 20 ml/min.
Solvent: 1-propanol, 0.5 ml/min.
Reactor 850°C
Quantitation was based on internal standardization with bromochloromethane.
Three standards were analyzed daily to determine linearity.
Analysis of 2-chloroaniline, 3,3'-dichlorobenzidine, and 2,4'-diamino-3,3'-
dichlorobiphenyl in the lagoon seepage wells was performed using Method
605 (9). The technique was modified by operating the electrode potential
at 0.9 volts to facilitate detection of 2-chloroaniline. This compound is
not oxidized at the recommended 0.8 volts.
A 2-ml aliquot of the methylene chloride base-neutral extract was exchanged
for methanol by adding it to 200 ml MeOH and concentrating the solvent in a
Kuderna-Danish evaporator. The concentrate was reduced to 3 ml and then
diluted to 6 ml with HPLC grade water. The sample was then stored at 4 C
for analysis.
Analysis was performed by high pressure liquid chromatography (HPLC) using
298
-------
a Spectra Physics SP8700 solvent delivery system connected to a BAS LC-3
electrochemical detector. Instrumental conditions were as follows:
Mobile Phase: 50% acetonitrile, 50% 0.1 N
acetate buffer at pH 4.7
Column: Lichrosorb RP-2, 5 micron
Injection: 100 ul, loop
Electrode: Glassy carbon
Potential: 0.9 volts
Flow: 1.7 ml/min.
The instrument was calibrated daily by duplicate standard injections at
three concentration levels. Samples that contained peaks with matching
retention times were quantitated in the linear range of the standard.
Air Samples
Air samples were collected and analyzed according to standard NIOSH procedures
(10). Samples were collected at the down wind wall of Aeration Cell I, approx-
imately 5 feet from water level, A three hour sample was taken, using a large
size (200/400 mg) charcoal tube hooked to a Bendix Personal Sampling Pump
calibrated at 100 ml/min. At the end of the sampling interval, the tubes were
capped and stored at 4°C prior to desorption and analysis.
Samples were desorbed by breaking the glass tube and transferring the two
charcoal sections into separate, 5 ml, teflon-capped vials. Three mis of
carbon disulfide was added to each vial. The sealed container was placed in
an ultrasonic water bath for 30 minutes. After desorption, the samples were
analyzed by gas chromatography under the following conditions:
Instrument: Varian 2100
Injector: 200°C
299
-------
Column: 20 ft;. Stainless Steel, 10% .
SP-1000 on 80/100 mesh Supelcoport
Program: 100°C for 6 min., then to 140°C @
10°/min.
Detector: FID, 300°C
Carrier: Helium, 30 ml/min.
Sample concentration was calculated by the analysis of desorbed standards.
300
------- |