INTERNATIONAL SYMPOSIUM

ON SUBSURFACE INJECTION

      OF OILFIELD BRINES


           Proceedings


           Sponsored By
          UNDERGROUND INJECTION
          PRACTICES COUNCIL, INC.
      LU
      o
          RESEARCH FOUNDATION
      Royal Sonesta Hotel

    New Orleans, Louisiana
         May 4 through 6t 1987

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       Proceedings o£ a International symposium

                          on

        SUBSURFACE INJECTION OF OILFIELD BRINES

                 May 4 through 6, 1987



                   Sponsored by the

         U.S. Environmental Protection Agency


                        and the
        Underground Injection Practices Council
                  Research Foundation
President UIPCRF - Paul Roberts, Director, Nebraska Oil &
                   Gas Conservation Commission

Executive Secretary UIPCRF - Michel J. Pague, Director,
                    UIPC

Chairman UIPCRF - Science Advisory Committee, Dr. Wayne
           Pettyjohn, Sun Professsor, Oklahoma State Univ.

Symposium Coordinator - Rosemary A.  Marmen

Symposium Registrar   - Betty J. Robins           i
                   Published by the

        Underground Injection Practices Council
           525 Central Park Drive, Suite 304
               Oklahoma City, OK  73105
                    (405) 525-6146
          Additional copies available at $75

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             UNDERGROUND INJECTION PRACTICES COUNCIL
                       RESEARCH FOUNDATION
     Approximately two years ago, five state members  of  the  UIPC
took an action authorizing the formation of the Underground
Injection Practices Council Research Foundation.  The UIPC
Research Foundation exists with an independent Board  of  Directors
and functions as a separate entity.  The purpose of the  Research
Foundation is strictly to promote research in underground
injection which it feels are necessary and to provide a  means  for
the funding of those projects.  It takes recommendations for its
research program from the UIPC Board of Directors and its own
members as well.  To date, the Research Foundation has conducted
the following projects:

     1) Hydrogeological and Hydrochernical Assessment  of  the  Basal
Sandstone and Overlying Paleozoic Age Units for Wastewater
Injection and Confinement in the North Central Region.

     £) A Pilot Survey of State Mechanical Integrity  Testing
(MIT) - New Mexico.

     3) Conducted a major national symposium on Subsurface
Injection of Oilfield Brines.

     4) Conducted a Well Construction Seminar in Washington, DC.

     5) Conducted two Mechanical Integrity Seminars ana  will
conduct a third in Long Beach, California, July 14-16th.

     6) Will conduct an International Symposium Class V  injection
Well Technology on September 2£-£4 in Washington, DC.

     The Foundation has also established the UIPC Library, funded
the first UIC Bibliography, and has as one of its ongoing
committments the further development of what will hopefully  be
the largest collection of UIC texts and articles in the  country.

The officers of the UIPC Research Foundation are:

          1)  Paul Roberts - President
          £)  Jim Watkins - Treasurer
          3)  Jarnes Welsh
          4)  Al Rarick
          5)  Jim Collins
          6)  Manual Sirgo
          7)  Michel Paque - Secretary

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                      TABLB OF CONTENTS


                                                       PAGE I

                   OPERATIONAL EXPERIENCE

1.    Brine Disposal at Sour Lake Field, Texas:  The
     Interplay of Area of Review, Mechnical Integrity
     and Geology in Evaluating Returns to the Surface       1

2.    Application of the Temperature Survey in
     Demonstrating the Mechanical Integrity of Injection
     Wells                                                 22

3.    Injection Monitoring and Control;  Dollarhide
     Clearkfork "AB" Unit                                  63

4.    Subsurface Injection of Fluids for the Recovery
     of Petroleum                                          79

5.    Oilfield Brine Disposal into the Wilcox Aquifers
     in S.E. Mississippi  -  A Case History               132

6.    Mechanical Considerations of the Disposal of
     Fluids into Poorly Consolidated Sandstone Reservoirs 134

7.    Leaking Abandoned Wells Caused by Class II
     Injection Operations - Case Histories from the
     Texas Railroad Commission files                      166

8.    Sources of Ground-Water Salinization in Parts of
     West Texas, USA                                      224

9.    Field Results of Tracer Tests Conducted in Oil
     Field Steam and Non-condensible Gas Injection
     Projects                                             254

10.  Environmental Protection Agency's Pennsylvania
     Compliance Initiative for Blow Box Operations        256

11.  Mathematical Evaluation of Operating Parameters
     Identified in a Class II Brine Disposal Well Permit
     Application                                          262

12.  The Use of Controlled Source Audio Magnetotellurics
     (CSAMT) to Delineate Zones of Ground Water
     Contamination - A Case History                       286

13.  Convective Circulation During Subsurface Injection
     of Liquid Waste                                      318

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                                                       PAQI ft


14.   Monitoring, Troubleshooting and Repairing Wellbore
     Communication o£ Waterflood Injection Wells in
     the Ville Platte Field - A Case History              342

15.   Some Aspects of Monitoring a Waterflood, Ventura
     Avenue Field Waterfloods                             368

16.   Status of Mechanical Integrity Testing  in
     Mississippi                                          423
                       WELL TECHNOLOGY

17.  Well Integrity Maintenance Using Pumpable Sealants   438

18.  Measuring Behind Casing Water Flow                   468

19.  A Pilot Survey of State Mechanical Integrity
     Testing Programs in New Mexico                       485

20.  Planning Successful Temperature Surveys              512

21.  Mobil's Attempt to Obtain a Waiver from the Surface
     Cementing Requirements for Rule Authorized Class II
     Enhanced Recovery Wells in the Springfield North
     Unit                                                 535

22.  A Method to Convert Multiple-Shop Section Openhole
     Completions into Cased-Hole Completions with Zonal
     Isolation                                            556

23.  How to Locate Abandoned Wells                        578

24.  "Ada" Pressure Test                                  598

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                     BRINE DISPOSAL AT SOUR LAKE FIELD, TEXAS:
       THE INTERPLAY OF AREA OF REVIEW, MECHANICAL INTEGRITY AND GEOLOGY IN
                         EVALUATING RETURNS TO THE SURFACE

                                        BY
                               T. LAWRENCE HINELINE

                              KEN E. DAVIS ASSOCIATES
                            3121 SAN JACINTO, SUITE 102
                               HOUSTON, TEXAS  77004
ABSTRACT

     Sour  Lake Field  in  Hardin  County Texas,  approximately  20  miles  west  of

Beaumont, Texas is one of  the  oldest  producing fields  in  the  country,  having been

discovered a commercially productive field in 1903.  The field continues to produce

about one million barrels of oil a year with approximately seven million gallons of

water being  produced  which must be disposed  of.   Throughout  the  recent operating

history  of  the field,  the produced  brines  have been  returned  to  the  subsurface

through  the  use of injection  wells.   The  injection  of produced  brine  was  either

purely  disposal  or  in  some  cases,   into  producing  zones,  for   the   purpose  of

secondary recovery.

     A unique  feature  at  Sour  Lake is a twelve acre  lake, commonly referred  to in

the  area as  the "sink hole".   This  lake formed in the  late 1920s  as  a result of

subsidence due  to the oil  and water withdrawal.

     In  1980,  the Texas Railroad  Commission,  which  has  regulatory authority over

oil  and  gas  operations  in  the  state,  held a hearing to  review all  of the existing

disposal permits for possible  cancellation  which  would  have  the ultimate effect of

virtually  shutting  in the  field.    Investigations and  incidents   relevant  to the

hearing  included  a  wellbore  flowing saltwater  to  the  surface,   injection   wells

without  tubing or  with  mechanical   integrity infractions,   a  reported  two foot

increase in  water level  in  the sink  hole coincident  with  the  injection of 288,000

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barrels of brine  into  a  disposal  well and  an  increase  in  chlorides concentrations
in  the sink  hole  from  2000  ppm to  over  25,000  ppm.   These  events  and  their
subsequent resolutions are discussed.

INTRODUCTION
     Sour  Lake Field  in  Hardin County,  Texas,  approximately 20  miles  west  of
Beaumont,  Texas  is one  of  the oldest  producing oil  fields  in the  country.   The
field has  produced  over  90  million  barrels of oil  and continues to produce in the
vicinity of  a million barrels  of  oil  per year.   In  the  early days of  production
produced brines  were discharged  to the  surface  and were carried  off  in  drainage
ditches.   Later in  the history of the  field, produced brines were  disposed of down
wells.   For  the  most part,  brine disposal  in   an  old  salt dome  field  is fairly
routine  procedure.   In  the early 1980s however,  there was a series of events that
could have virtually  shut down the  field.

SITE GEOHYDROLOGY
     As  mentioned  above, Sour  Lake Oil  Field is located  on  the north  side of the
town of  Sour Lake about 20 miles  west of Beaumont.   This places the field in the
Gulf Coast Salt  Dome Basin  Province.   Other than  around salt domes,  oil  and gas
production is  from  Frio  and Yegua sands along this trend.  The  Sour  Lake Salt Dome
is  a piercement  feature,  cutting  through the  Yegua, Jackson  and Frio  sections.
Miocene  sands thin  considerably over  the dome,  having  a thickness  of  over 4500
feet less  than two miles off  of the flanks  of the  dome and  less than 1000 feet  at
the  crest.    A  schematic  cross  section of the  west  flank   of  the  feature   is
illustrated  in Figure 1.  Oil  and  gas  production in the immediate vicinity of the
dome  is  from  a  series  of Miocene  sands.  On the  flanks of the  dome,  the  deeper
                                        -2-

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Yegua  sands  are  productive.    Oddly,  despite  ideal  structural  and  stratigraphic
trapping, there is virtually no Frio production from the flanks of the dome.
     Salt  dome   areas   are   prolific   oil   and  gas   producers   because  of  the
stratigraphic  and  structural  traps  formed  in the  surrounding  lithology.    The
upwarping of sediments  and extremely complex  faulting  in  the sand-shale sequences
results  in  a multitude  of individual   reservoirs.   Unfortunately  this  complexity
also makes precise geohydrological analysis nearly impossible.
     Aquifers in the Sour Lake Area include the Miocene Oakville Sand, the Pliocene
Willis  Sand  and  Goliad  Sand,  the  Pleistocene  Lissie Sand  and  recent alluvium.
Because  of  the   similar  character  of   all  of  these  formations,   because   it  is
difficult to distinguish them in the subsurface with drillers logs or electric logs
and because  it  is assumed  they all  are  hydrologically connected,  these formations
are generally referred to collectively as the  Gulf Coast Aquifer.
     On  the  flanks  of  the  dome,  the depth to  the base  of  fresh water reaches 2000
feet.  At the crest of the dome fresh water is  found to an approximate depth of 100
feet.  This configuration  is illustrated  in Figure 2.   The transition from fresh to
salt water is easily detected by resistivity logs as shown in that same  figure.
     There  are  numerous water  wells  in the Sour  Lake area  (Figure  3)  from which
water  quality  information  can  be  obtained.   The nearest shallow  well  to the crest
of the  dome  that  there  is  water quality information for is  about  7000  feet to the
southeast.   It  is drilled  to  a depth of 60 feet and  in 1962  had  a total dissolved
solids  (TDS) concentration  of 1,025  ppm.    The City  of  Sour Lake  operated  two
municipal  supply  wells  about one mile  south  of the  crest of  the  dome  which drew
water  from 177 feet.  In the years from  1941 to  1949 the TDS  concentration in these
wells  rose  from  520 ppm to over  1500  ppm.   These  wells  were  replaced  by two new
wells  another two miles  to the south.   These  wells were drilled  to  a depth of 812
feet and  224 feet.   The deeper  well  initially had a  TDS  concentration  of 548 ppm
                                        -3-

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and a  chlorides  concentration of  188  ppm.   After  ten  years of operation  the IDS
concentration rose to  1460  ppm and chlorides to 645 ppm.  The  quality  of water in
the shallower well remained  fairly constant over the same period  of  time with 500
to 600 ppm IDS  and  approximately 200 ppm chlorides.  This  change  in water  quality
is typical around a  salt dome, especially in wells  on the down  gradient  side of the
dome.   As  the  wells  are  pumped  over time,  salt  water   encroachment  is  to be
expected.

HISTORICAL REVIEW
Production History
     The  poor  quality of water in the  Sour  Lake  area can  not be  attributed  to oil
and gas operations.   This can be assumed  from the  name  given  to  the town  of  Sour
Lake which was founded  in  1835.   In fact,  there is  a legend  that  the original  Sour
Lake,  now gone,  caught  fire, inciting the rather superstitious  Indians  in  the  area
never  to return.    Seeps  of  oil  and  sulfur  to  the  surface  first  brought  those
seeking   medicinal   treatment  to  the  area  and  as  early  as  1893   brought  oil
prospectors  into the area.  In the  later years  of  the  1890s there was  minimal oil
activity.   On  January 6, 1903 the  first significant well  was drilled by the Texas
Co.,  coming  in as a  15,000  barrel a day gusher.   Well  over a  thousand  wells  have
since  been  drilled  at Sour Lake.   Texaco,  alone has drilled  in  excess  of 800 wells
on  the major 815 acre  lease of  the  field  as  well  as  on some  smaller  surrounding
leases,  and  to  date  over ninety  million barrels of  oil  have  been produced.

Sink  Hole Development
      A relatively unique feature at Sour Lake Field is  a depression  that developed
in  the ground  in  1929.   The  twelve acre  by  40 to  50  foot  deep feature  did  not
evolve over time,  but  in two brief  incidents on  October  9 and  12  of  that year.
                                         -4-

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Several oil wells  up  to 2000 and 3000  feet  from the sink  went  entirely to water.



All of the  affected  wells were apparently producing  from the caprock  of  the dome



rather than the overlying sands.



     The formation of the sink is attributed to the dissolution of the  salt and cap



rock,  the  production  of over 73  million barrels of  oil  and the  production  of an



undetermined  quantity of  saltwater,  sand  and  dissolved  solids.    The  volume of



displaced earth at the surface was estimated to be 98,000 cubic yards.



     In  the  years from  the  early  1930s  until   the  late  seventies,  drilling,



production,  brine disposal  and  the  sink  hole apparently coexisted  with  little



adverse consequence.





EVENTS LEADING TO THE SOUR LAKE ORDER



     The  interplay of  area  of   review,  mechanical   integrity  and  geology  became



apparent at Sour Lake when the Texas Railroad Commission  took action to  investigate



brine  disposal at that field.  The investigation was  triggered by  one incident, and



in  the several months  that followed  new circumstances  either  developed  or  were



uncovered.



     In January 1980, Texaco reported to  the Texas Railroad Commission  that an  oily



accumulation  was  collecting  on the surface  of  the  sink  hole.   The  material  which



was collecting at  an  estimated rate of  ten to fifteen gallons per  day was described



as  a  "fibrous, oily,  muddy looking  material."  At  the  time  of  the  report,  the



material  covered   about  two acres  of  the  twelve  acre  lake.   Texaco  offered to



make every  effort  to  contain the  material but  felt that  they were not  responsible



and  would  seek   assistance  from  other  operators  in  the  field.   The   Railroad



Commission  made periodic  inspections  of the sink hole  and  surrounding  area  in the



following months.  One  such  inspection followed a  report of contaminated water in



Clemmons Gully into which the sink occasionally drains.   The  inspection revealed no





                                        -5-

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problems, although  later  testimony alleged  that  some cattle  died  as  a  result of
drinking this water.   In  May, Texaco  received  permission to  skim  3000 barrels of
fluid off of the sinkhole for transport through a pipeline.
     In May and June  a  new commercial  brine disposal  well  was permitted, drilled,
and completed 1,500 feet north of the sink hole.  The well was drilled  to  1912  feet
and reached total  depth in the caprock.   The  well  was completed  with  10 3/4-inch
surface pipe to 113 feet, 7-inch casing to 1740 feet,  a  4 1/2-inch liner  from  1700
feet to 1904 feet and 3 1/2-inch tubing set on a packer at 1638 feet.
     Texaco maintains storage caverns that were dissolved in the  salt  dome for the
storage of hydrocarbon  products.   To  control  the  movement of  product  in  or out of
the caverns,  Texaco  had  two lined  pits  at  the  surface  to  hold   brine  which was
pumped  into or  out  of the caverns.   Around  the time that  Luther  Hendon  completed
his disposal well, one of the Texaco pits developed a leak and needed to be drained
of the  several hundred thousand barrels of brine it contained  so that repairs  could
be made.    Luther  Hendon  was given  permission  to  dispose of  this brine  by the
Railroad Commission and had  disposed  of  approximately 250,000 barrels  of  the  brine
before  he suspended injection in late June.
     In the middle  of June,  an  operator  in the field reported  a  rise  in  the  fluid
level  in the  sink hole  and at the  end of  June a program was  begun to monitor the
water level in  sink hole.   Precipitation  and  evaporation were taken into  account.
The area of  the water surface was  surveyed  to be 12.24  acres and the calculation
made that a one inch  rise represented 7,854 barrels.
     In  consideration of  these  occurrences,  the Railroad  Commission District   3
office requested that a hearing be  held in Austin to  show cause why
     1.   All disposal wells   into  charged  zones should not  have  permits  cancelled
         and be plugged in accordance with Railroad Commission Regulations.
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     2.   All  disposal wells  should  not  require tubing to  be  set on  a  packer  with
         annual  pressure tests.
     3.   Any present or future disposal wells  should  not  have permits cancelled if
         testing reveals that the injection zone is charged or under pressure.

     In  July there  was  an official  call  for  this  hearing which was  to  be held on
September 25, 1980.   In the mean time,  the  Railroad  Commission requested that  Dome
Holding   Company  and  Luther  Hendon  shut  in  their  disposal  wells.   These  two
operators were  singled out because  they were injecting water  not  produced at  Sour
Lake.
     At  the  same  time  all of  this  was  transpiring,  the  Luther  Hendon   application
was pending,  despite there having been emergency authority to dispose of the Texaco
brine.  Apparently other  small operators  in  the  field  felt that the occurrences at
the sink hole which jeopardized  their operations could  be attributed to the Hendon
operation.  They therefore joined together  and  called  for a hearing to  protest the
Hendon  permit.   This  hearing  was  called  by the  Railroad Commission  and  held on
August 21, 1980.
     In  the course of the two  hearings  a  great  deal  of  information as well as some
speculation  was brought  forth on  the  events  surrounding brine  disposal  in  the
field.
     The opposition to the Hendon application provided testimony which they believe
connected the rise in the sink hole water level  to the Hendon operation.  Although
at the time records had not been kept, photographs indicated  a two foot  rise in the
water level  between June  18  and June  28  during  which  time Hendon had  injected
approximately 250,000  barrels of brine.   The  two foot  increase  represents about
190,000  barrels of additional  water in  the  sink  hole.   The opposition  alleged that
injection of the  heavy brine  from  the  Texaco  pits (10.5  pound  per  gallon)  at 825
                                        -7-

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psi  would  fracture  the receiving  formations.   Records  of  level  began  being kept
after this incident but also  after the  time Hendon shut in his well  and were kept
from July 10 to  August 18.    In this  period,  minus the  effects of  rain, the  level
increased  approximately three inches.   During  August,  excluding  effects of  rain,
there was a net loss in the level.  A note was made that during that period,  Texaco
disposal wells were  shut  in for testing  or  repairs.   A great  deal  of  speculation
arose as to  how  injected  brine could end  up  it the sink hole.   The complexity of
the  geology on  the  crest  of the  dome  makes  any  specific  analysis virtually
impossible  despite  the  dense  well  control.    Whether  or  not  the sands  at
approximately  1700  feet  at  the  Hendon  well   actually  contact  the  sink  hole  or
whether  or  not  fractures,   faults   or  abandoned  wellbores  may  have   allowed
communication was only theorized.
     The point was also made  that  any effects on the sink hole were most likely the
cumulative effects of  the 20  or so disposal wells operating in the vicinity.
     In  consideration  of  the facts presented at the  Hendon  hearing which  included
that the well  was  properly completed  and that  the  operation  was  given  approval by
the Texas Water Commission  and  based  apparently on  the fact  that the opponents had
not  proven  connection between  that  operation  and detriment  to  the  field, the
hearing  examiner made  his  recommendation.   This included injection  be  allowed at
1675 feet  to 1730  feet,  injection pressure  be limited  to  400  psi,  injection be
through tubing and packer,  only brines  produced in  Sour Lake Field be  injected  and
that annual mechanical integrity tests be  performed.
     In view of the fact that  the  September 25,  1980 hearing  required  all operators
of  disposal  wells  in the  field   to  defend  their  operations,   a  great  deal  of
information  was  produced.   Photographs  were  presented  which  pictured  flow  to  the
surface of the  sink  as indicated by an  area  of disturbed  water and some bubbling.
In  April  and into May,  operators made  an effort  to  stop  the flow  into the  sink
                                         -8-

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hole.  Reportedly, divers were able to locate a submerged wellhead.  A pipe was run



into this wellbore  to  a depth of  310 feet  and  1,377  sacks of  cement  were pumped



into the well.  The bubbling to the surface reportedly stopped.



     The  most  significant  rise  in  water  level  however,  was  reported   to  have



occurred in June.   This  would  indicate that if  brine  disposal  was responsible for



the  level rise, there were other avenues than the abandoned wellbore.  Dome Holding



and  the  Hendon well were  shut in  upon  Railroad Commission request yet  the water



level  continued  to rise.   Between the  time  of  the call  for  the  hearing  and the



hearing, ten of the twenty or  so disposal  wells  at  the field were tested and found



to be  injecting  into  overpressured zones.   Additional  testing  also indicated that



some of the active disposal wells failed mechanical integrity tests.



     Texaco, the major operator  in  the field,  operated two disposal wells  into the



caprock  near  the  crest of the dome.   Texaco produced  approximately 61  percent of



the  field's million  barrel  a year  production  and  disposed of  approximately 11,000



barrels  a day  of  salt  water  of  the field's  21,000  barrels  disposed  of daily.



Approximately  seven million barrels of water are injected  annually.  Neither of the



Texaco wells  met  the  standards set forth for the hearing,  so  prior to the hearing



Texaco repaired both of  the wells.  The  number  one  well  was fitted with tubing and



packer in servicing that also  found a leak  in the casing.   Because  of a restriction



in  the casing of  the  number two  well,  a packer could  not be set, so  tubing was



cemented  into the  entire  length  of  the  casing.    Both  wells  passed  subsequent



radioactive tracer  tests.   Sun Oil Company  is  another major company that  operates



in  the field,  though of  considerably  less consequence  than  Texaco.    Sun  only



injected  about  200 barrels per  day into  two  wells,  both of which were about two



miles  from  the  sink  hole.    Also,  both  Sun  wells  met the  mechanical   standards



required.
                                        -9-

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     Considerable testimony was provided  by a group of  small  operators called the
Sour Lake Operators Group.  The group's testimony  had  two fundamental  themes.  The
first was that  any difficulties with the  sink  hole could be  attributed  to  one or
two  disposal  operations  that  were  injecting  brine  not   associated  with  oil
production in Sour Lake Field.  The second was a verification  that all  of the wells
utilized by  the  group  were  completed  with tubing and  packer  and  therefore met the
standards set forth by the Railroad Commission or else they were shut-in.
     There were other conditions or incidents that  led to the  conclusion that there
was  brine migration at the  field.   There  was  a report,  although  not documented,
that there had  been  a  drilling rig  active in the vicinity of  the  sink hole run by
an  unknown operator.   Following this  operation,  an abandoned  pipe  was found to be
flowing  salt water to  the  surface at  that location.   A second  similar incident
which is  documented,  occurred after the  1980  hearings.   This  incident involved  a
well drilled to 902 feet that  reached total  depth  in  the caprock.   When an  attempt
was made to  log the well, it  began  flowing  salt  water  in an  eight inch stream that
rose four feet  into the air and continued to do so  for 24 hours.
     Another  factor indicating flow  into  the  sink  hole was  the quality  of the
water.   Testimony was  given  that  the sink  hole  water  had  always  been relatively
fresh,  derived  primarily from  runoff.   Reportedly, as  late  as  January  1980, the
chlorides content  of  the water was around  2000 ppm.   The water  from the sink or
from Clemmons Gully into  which it  drains had been  reportedly used for irrigation,
cattle  watering  and mixing  drilling mud.   In September  of  1980,  water quality was
analyzed at  different depths.  The  chlorides content was  reported  as follows:
                       Depth  (ft.)           Chlorides  (ppm)
                            7                   28,700
                           10                   28,910
                           19                   28,595
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                       Depth (ft.)          Chlorides (ppm)
                           20                   28,830
                           30                   28,520
                           40                   25,995
THE SOUR LAKE ORDER
     Following the consideration of  all data  and  testimony,  on October 5, 1980 the
Railroad Commission issued the following order:
          All  existing  disposal  or  injection permits  currently in  effect  in the
     Sour Lake Field will terminate 90 days after the effective date  of this order.
     However,  an  existing  permit  may be renewed  by  the   refiling of  Railroad
     Commission Forms W-14 or H-l and other Commission required supporting data.  A
     renewed  permit  or  any future disposal or  injection permit for  the  Sour Lake
     Field  will   be  subject  to  the  following  conditions   as  well  as   any  other
     limitation that may be required by the Commission.
          1.   Injection must  be  through tubing  set  on a packer located immediately
               above the disposal zone.
          2.   The  injection  fluid  will   be  limited   to   saltwater  produced   in
               association with oil and gas production in the  Sour Lake Fields.
          3.   Prior  to   injection,  and annually thereafter,  a  surface  monitored
               downhole  survey must  be  conducted  under  the  supervision   of the
               District  Director  to  insure that the  injected material can enter  no
               other  strata  than  that approved in the  permit; and provided  further
               that  should  it be determined  by  the Commission  that  such injected
               material  is  not confined to the approved  strata,  the  authorization
               given  hereby  shall be  suspended and  the  injection stopped until all
               migration from  such strata is eliminated.

                                       -11-

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     In April  1981,  the Railroad Commission investigated operators'  compliance with



the order.  There were 38  injection  or  disposal  wells in existence  at  the  time of



the order.  Nineteen  disposal  wells  and  two injection  wells  were  found to  be in



compliance and were reissued  permits.  Thirteen  disposal  or  injection  wells were



not in compliance and  issued letters cancelling permits.  Three of those wells were



rejected  because they had  been  recompleted  into  zones   too  shallow  by  Water



Commission standards.   Other reasons for  rejection  included  no tubing,  holes in



tubing, a wellhead  leak  or other  incidents  of mechanical   integrity test failure.



Other  rejections  were  due to the  fact  that  operators  failed  to perform  tests or



submit the results of the tests.





SUMMARY AND CONCLUSIONS



     In 1980 and  1981 the  water  filled  sinkhole  at  Sour Lake experienced increases



in  levels that   were  not  attributed to  rainfall   or   run  off.    The   fact  that



overpressurization  of   saltwater  disposal   zones  was  leading  to   flow  into  the



sinkhole  was   substantiated  by  disposal   wells   with  shut-in   pressure,  observed



indication of  submerged  flow into  the  sink  hole,  wellbores flowing brine  and an



increased  chlorides  concentration   in  the  sink   hole.     Although  there  were



approximately  20  disposal  wells in  the  field, Texaco  and  Luther Hendon  were the



most  significant  operators.   Luther  Hendon  had  been injecting 15,000  barrels of



brine  a  day  when the  most significant  level  increase  occurred.  Texaco had been



injecting 11,000 to 14,000 barrels a day into wells with no  tubing.  Putting tubing



in these wells restricted their volume to  the point of  having  to shut in producing



wells.



     Although   it  was   implied  that  flow   to  the  surface  was   the   result  of



overpressured   disposal  zones,  losses of mechanical  integrity,  complex  geology and
                                       -12-

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old  abandoned  wellbores,   none  of  this  could  really  be   verified   due  to  the
complexity of the area.
     Luther Hendon never operated  his  well  again despite  being  issued a permit to
do  so.   Texaco converted  three  wells on  the  west flank  of the  dome to disposal
wells.  Disposal would be  into non-productive  Frio  sands which pinch out at a  safe
distance  from  the  sink  hole  and  caprock  so  that  there  should  never  be  any
complications.  All other  smaller operators in the field  either  shut in their wells
or verified that they met  the standards of the order.
                                       -13-

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                                    REFERENCES










Baker,  E. T.,  (1964),  Geology and Groundwater  Resources  of Hardin  County,  Texas,



  Texas Water Commission Bulletin  6406.



Sellards, E.  H., (1930), Subsidence  in  Gulf Coastal Plains Salt  Domes,  University



  of Texas Bulletin,  3001,  pp. 9-36.
                                       -14-

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FIGURES
 -15-

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           FIGURE 1
SCHEMATIC CROSS SECTION OF WEST
    FLANK OF SOUR LAKE DOME
             -16-

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                                                                                              SINK HOLE
1000
2000
4000
5000
                                UNDIFFERENTIATED MIOCENE
                                    AND YOUNGER SANDS
                                                                                       1000'
                         FIGURE 1  SCHEMATIC CROSS-SECTION OF WEST FLANK OF SQUR LAKE DOME

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           FIGURE 2
CROSS SECTION SHOWING DEPTH OF
FRESH WATER OVER SOUR LAKE DOME
             -18-

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                                                                                        DV
              Approximate
                                                 surface
FIGURE  2   CROSS-SECTION SHOWING DEPTH OF FRESH WATER OVER SOUR LAKE DOME
                             (FROM BAKER, 1964)

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      FIGURE 3





MAP OF SOUR LAKE AREA
         -20-

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TEXACO FLANK WELLS
                 TEXACO CAPROCK WELLS
                          CREST OF  DOM
                       FIGURE 3   MAP OF SOUR LAKE AREA
                                   -21-

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       APPLICATION  OF  THE  TEMPERATURE  SURVEY IN DEMONSTRATING THE  MECHANICAL
                           INTEGRITY OF INJECTION WELLS

                        MALCOLM D.  JARRELL AND RICHARD LYLE

                     KEN E.  DAVIS ASSOCIATES,  300 N.  MICHIGAN
                       SUITE 409, SOUTH BEND,  INDIANA  46601
ABSTRACT

     The temperature  log  has  an  important role  in demonstrating  the  absence  of

fluid migration  behind casing  in  injection  wells.   At  the  present  time,  many

regulatory agencies  require  temperature logs to  satisfy the mechanical  integrity

test  requirements  of the  Underground  Injection Control  (UIC)  program.   However,

these agencies have not established guidelines for conducting a temperature survey.

Two methods have been  successfully applied and approved by  regulatory agencies  in

specific cases.    The  first method  involves  an  injecting  temperature log  and  a

series  of  shut-in  logs  run immediately  after normal  injection  is  ceased.   The

second  method requires  a  stabilized  static  base  log  followed  by  a period  of

injection and a subsequent suite of post injection temperature logs.  As these logs

have  become more  prevalent in  mechanical  integrity evaluations,  experience shows

that the three (3)  critical survey parameters  are  the  shut-in time prior to static

base  log, the volume of water  injected,  and the  temperature differential  between

the injected  water  and  the formation water  in  the zone of  interest.   Recommended

procedures for running and presenting temperature logs have been developed based on

case  histories  of  both Class  I and Class  II  injection wells  in  the Midwest  and

Nevada.  These cases  include logs  conducted  in wells  with  and  without tubing,  and

utilize  both  traditional  differential  temperature  tools  and  the   newer  radial

differential  temperature tool.
                                        -22-

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INTRODUCTION
     Ascertaining the mechanical integrity of injection wells  is  a  major  objective
of the  Underground  Injection Control  (UIC)  program.    Under  the program,  various
state  agencies   and  the  United  States   Environmental  Protection  Agency  require
injection well  operators  to demonstrate  that  the fluids  they inject  are  staying
within the  permitted disposal  intervals  and not contaminating  underground  sources
of drinking water.  Also,  the UIC program is concerned about any other flow between
zones  penetrated  by  a  well   through  channels  behind  the  casing.    The  high
sensitivity of temperature logging tools to minute thermal  disturbances has made it
a valuable tool  in evaluating flow anomalies in  injection  wells.  Properly run, the
temperature log can detect where injected fluids are being  stored; whether injected
fluids are remaining in the receiving zone or channeling;  and  whether or  not there
is  other interzonal  flow  which  may  affect  the  quality   of  potentially  useable
water.

PRINCIPALS OF THE TEMPERATURE SURVEY
     An  injection well  is part  of a  complex heat  transfer  system  where heat energy
is exchanged with formations surrounding the well.  This heat transfer is  dependent
on whether  the  well  is  acting  as  a  heat  source  or sink.   By  analyzing the system,
information  on  the  disposition of  fluids  into  the  well,  and more  importantly,
outside  the wellbore  in  the  formations  can be  obtained.   The  effect  of  fluid
movement will have a measurable influence on the heat flow.
     Temperature  logs   enable   the  heat   transfer  that  exists  in   a  well  to  be
recorded.  Also,  by  using various logging  techniques,  the  heat transfer system can
be  altered  to investigate  fluid  migration  problems.   Using proper  techniques,  a
temperature  log  can  provide  information  on the flow  distribution  taking  place
                                       -23-

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inside or near  the wellbore.   On most  injection wells,  the temperature  log  can
show:
     1) where fluids are being stored within a disposal zone,
     2) the point of entry or exit at the wellbore,
     3) the source and path of flow behind casing, and
     4) locations  of   interzonal  flow   not  necessarily   related   to  injection
        activity.

     To understand  the  temperature  log  application  to injection wells requires  a
consideration of heat transfer mechanisms within the earth.

GEOTHERMAL TEMPERATURE GRADIENT
     The temperature within the earth  increases with  depth.   A constant heat flow,
with  its source  at  the  molten core,  is carried through the  rock  up  to the surface
by  conduction.    The temperature  decreases  toward  the  surface which acts  as  a
radi ator.
     Geothermal  temperature  gradient  is  a measurement of  heat  dissipation  as it
rises  through the earth to the surface.   Generally,  it is defined as the change in
temperature per  100 feet of depth.   Geothermal  gradients  vary widely in the United
States and are dependent on the geology of  a particular area  and  the  ability of the
specific  rock sequence  to conduct  heat.   In  the  Midwestern   United  States  the
geothermal gradient could be  as low  as 0.6  °F/100 feet, whereas  in the  Gulf Coastal
area  it  is  about  2.3  "F/100  feet.    In central  Nevada  where  a case history is
presented, the geothermal  gradient is  1.3 "F/100.  Figure  I shows  the variance in
the temperature  gradient in different  regions  across  the  United  States.
     Figure 2 illustrates how the temperature  gradient  response  varies  with type of
formation.  These  changes  are due to the differences  in  the thermal heat  transfer
                                        -24-

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coefficient of the  individual  formations.   These lithological differences must  be
taken into account when investigating fluid  channeling  in a well.   A lithological
log  should be  evaluated during both  the  planning and  interpretation stages of  a
temperature survey.
     The effect that injected fluids have on the  natural  temperature gradient of a
well is best  shown by case history presentations.  First,  however  a description  of
the logging tools is necessary.

LOGGING SYSTEMS
     Two  logging  systems used  to  investigate the  mechanical  integrity of injection
wells include  the conventional  temperature  system and the  new  radial differential
temperature system.
     The basic configuration of the conventional system is described in Figure 3.
     Three sections are common to this system.   These are:
     1) A  tool  which  consists of  a  single  temperature sensing  element.  This  is
        usually  a high  resolution platinum  thermistor  sensitive   to  temperature
        changes of 0.1 °F.
     2) A  temperature  section, which  processes  the  line  signal  into  a  gradient
        curve.  This is the absolute temperature recorded  by the tool.
     3) A  differential  section  which provides  a calculated  curve.    This  curve
        responds  to differences in the rate of temperature change.

     The   differential   temperature   curve  increases  the  sensitivity  of   the
temperature gradient data.   Although  it does  not  furnish any new  information  not
included on the gradient curve, it  presents  the data in  terms  of  relatively small
temperature changes which  may not appear significant on  the gradient curve.   The
sensitivity of the differential curve can be varied  by  the logging  engineer  over  a
                                       -25-

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wide range.   Figure  4 is  an  idealized presentation  illustrating  the differential



temperature response of a conventional single element temperature tool.



     The  second  type of  logging  system  used  to evaluate  injection wells  is the



radial differential temperature (RDT)  logging system.   The  ROT is a specialty tool



used to detect flowing channels behind casing.   It  is  normally run in conjunction



with other  investigative  logs  to  confirm  channeling where channeling is suspected.



Its  primary function is  to pinpoint  the orientation  of  flowing channels  once  a



temperature  anomaly  is  detected  utilizing a conventional  differential  temperature



logging system.   The use  of  the  RDT  tool  as  the  primary  source of demonstrating



mechanical  integrity is not recommended.



     A typical RDT tool is  shown in Figure 5.   The  tool has two arms equipped with



temperature  sensors  positioned 180°  apart that  extend to contact the casing walls.



The  contact  diameter of the arms are  adjusted to exert  optimal  pressure to maintain



contact between  the  temperature  sensors  and the  interior  of the casing.   A motor



rotates the  tool  at  a speed which is  recorded on the  left hand  margin of the log.



     The  RDT tool  is typically  run  into  the  injection  well  after  the  well  is



shut-in.   The tool  is positioned  adjacent to a point where channeling outside the



casing is  suspected.  The  logging operator then extends the mechanical arms  against



the  casing and  activates  tool  rotation.    Where there  is  no  flowing  channel the



temperature  sensors  should measure a  uniform temperature at  all  contact surfaces as



shown in  Figure  6.   If a  flowing  channel  exists however, a sinusoidal wave will be



recorded  as  shown  in  Figure 7,  indicating  unequal  heating  or  cooling  of the



casing.






PLANNING AND  EXECUTING A TEMPERATURE  SURVEY



     The  planning  and  preparation  of a production  logging  survey  requires the



definition  of the type of  flow condition  that may be  encountered.  This will enable





                                       -26-

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the prediction of the expected temperature responses.  The expected well  conditions
will  influence   the  log  scale,   injection  procedures,  intervals  over  which  the
temperature logs will  be  run and  whether or not  the  tubing and  packer  should  be
removed.
     The first step in temperature  log  planning  and  interpretation is to determine
whether the bore is  acting  as  a  heat  sink or source.  This  will  depend  on whether
the fluids  injected  into the well  are greater  or less  than the  normal  gradient.
For proper  interpretation  their  must  be a  sufficient  temperature  change  taking
place at the zone of interest.
     The most  important objective  is to determine  which portions  of a  zone  are
accepting  fluids and  whether any  migration out  of  that   zone  is  taking  place.
Shut-in temperature logs are the most effective means to detect whether an injected
fluid is remaining in the zone or channeling behind casing.
     The path  and  storage  of  injection fluids  are  associated  with  the  heat  sink
effect  of  the   earth.    Generally,  injected  fluids  are   close  to  the  surface
temperature which  is  usually less than the  natural  bottom   hole  temperature.   The
following examples  illustrate  temperature surveys conducted in  the  Midwest  and  in
Nevada  to  demonstrate mechanical  integrity.    The first two  case  histories  show
containment  of  injected   fluids  within  the  receiving   interval   with  no  upward
migration behind casing.   The third  example  shows suspected channeling  above  the
fluid  entry point  into  the formation.    The   channeling  could  be  confirmed  by
specialty temperature logging techniques.

Case History - 1
     The first example is a  temperature  log  performed  to show  the absence of fluid
channeling behind the  long  string casing  of a Class I industrial  disposal well  in
Illinois.  Non-hazardous wastewater had been  injected  into  this  well for the past
                                        -27-

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17 years.  The wastewater is injected  at  ambient  temperatures.   Since this logging
was conducted during the winter, the  cold fluids injected had  a  cooling  effect on
the well.   The  total  depth of  this  well  is  5524  feet  with  a  disposal  interval
consisting of 565 feet of porous dolomite.
     The well was  undisturbed  for  a period  of  48 hours prior  to  running  the base
temperature  log.   The base  log showed  the static  geothermal  gradient to  be 0.6
°F/100 feet.  The  fluid  level  in this  well  was discernable  from  the base log and
recorded at  a depth of  170  feet.   Changes  in  the  recorded  conductivity  are also
noted  on the base  log.   The most  significant  occurs at  a  depth of 4060  feet  as
shown  in Figure 8.   At 4060  feet  there  is a  transition from  the St.  Peter,  a
predominantly sandstone formation to the Prairie du  Chien, a  predominantly dolomite
formation.
     These  temperature  shifts  occur  naturally  due  to  the  different  thermal
conductivity  of  the changing rock matrix.
     The heat transfer  between the  Eminence-Potosi  injection  zone and  the Prairie
du  Chien upper  confining zone is evident  by the cooling  effect  noted  on  the base
log below  4850  feet.   This  response above the disposal zone  is resulting  from the
vertical conductive cooling due to the  injection of  cool fluids below 4968 feet.
     After the  base  log  was  completed  approximately 163,800  gallons of cool  (46°F)
fresh  water  was injected into  the  well down the  7" diameter  casing.   Three post
injection  temperature logs were performed  sequentially at  15 minutes, 2 hours  and 4
hours  following  cessation of injection.
     The post injection  logs  show  that the majority of  the  injected fluid entered
the  zone from 4970  feet  to 5110 feet  where the  largest  cooling  effect  is  seen.
Each sequential  post injection log pass  shows  the  heat flow recovery to gradient
taking  place.   The recovery in various sections of the wellbore  will  be directly
proportional  to  the  amount of  cooling  that  has occurred under  injection.
                                        -28-

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     The first  post  injection  log shows  the entire  well  remaining  at  a  fairly
constant temperature.   The second  and  third post injection  logs show  a definite
warming effect  above  4970 feet.   The logs  are  approaching  the  base  log gradient
with similar  slope which  is  characteristic  of  natural warming.   This  signifies
little or no fluid migration  above  4970  feet.  This depth corresponds  to the base
of the confinement system indicating proper fluid isolation.
     At the disposal  zone, the  rate of  thermal  recovery is reduced where the cold
water is stored.  The post injection  logs  are showing  this as  a cooling effect due
to the mass of cold water in the disposal zone absorbing the  heat flow.

Case History - 2
     The next example  is  a case where produced  brine was injected  into a disposal
well for two years prior to conducting a temperature log.  This well was  a Class II
injection well located in Nevada.   A  section  of  the  composite  log showing the base
temperature log  and three  post  injection runs is presented  in  Figure  9.   This log
demonstrates that  a good temperature  log can be recorded with the tubing  and packer
installed  if  the  temperature  differences  between  the  injected  fluids and  the
formation are sufficient.
     The base temperature  log was  run  92 hours  after  the well was shut-in.   The
amount of shut-in  time was due  to  an  obstruction  in  the injection tubing which had
to be removed to allow the logging  tool  to go below the packer.
     The cooling effect apparent on the  base  log between 8105 feet and 8155 feet is
the  result  of  a temperature  sink between  the extremely cool  formation  below 8155
feet and the normal gradient  at about 8105 feet.  From 8155 feet  to  8325 feet the
extreme cooling  on the base  log  is due  to the large volume of cooler water which
had  been  injected  into the  formation for approximately two  years.   Although the
geothermal  injection  water at  the  surface  is  210 °F,  the  cooling effect  of the
                                       -29-

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formation temperature, (being less than 210 °F to  a  depth  of  6100  feet),  cools the
water to less than 190 °F from the surface to the injection point because the water
traveled 6100 feet being affected by cooler formations.  Between 6100 feet and 8114
feet  the temperature  of the  formation  tries  to   raise  the  temperature  of  the
injected fluid,  but  due to  the rate  of  pumping  and the fluid  traveling  only 2014
feet  at  this increased temperature,  the  heating effect does not bring  the water
back  to  any temperature above  190  °F before  going  into  the disposal zone.   The
temperature  differential at  the disposal  zone then  is 50  °F  resulting  in extreme
cooling  of  the  formation.    The  base  log  shows   that  the  largest quantity  of
injection fluid  is going into the formation between 8155 feet to 8300 feet.
      The post injection temperature logs were run after pumping 375 barrels  (15,750
gallons) of  52 °F surface water at a  rate  of  three  barrels per minute (126 gallons
per minute).  The  passes were made  at approximately 30 minute  intervals from 7100
feet  to  total depth  at  8400 feet.
      In  post injection  pass  number   one  the  fluid  in the  tubing just  above the
packer  is  about  55  °F cooler than the base  log.  From 8137  feet  to  8277 feet the
formation  is being  cooled  by  the  52  °F surface  water   being injected  into the
formation.   From 8277 feet to 8400 feet  there is a heating  back  to  a bottom hole
temperature  of  235  °F.   Injection  occurred  between  8137  feet  and  8277  feet with
very  little water being injected  between 8277  feet  and  8382  feet.   No  injection
occurred below 8382  feet.
      Post  injection  log pass number  two  shows  the fluid   in  the  tubing  just  above
the   packer  to   be   about  45  °F  cooler  than  the  base   log.    This  increase   in
temperature  means that  the  wellbore  fluid is trying  to  reheat to normal  gradient.
Between  8137 feet  and 8277  feet the  formation cooling  is  still evident  due  to  the
375 barrels  of cooler fluid  injected  into the formation.   The  heating effect still
evident  from 8277  feet  to  8400 feet  further  confirms  that the largest quantity  of
                                       -30-

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fluid was injected  between  8137  feet and 8277  feet,  with  very little  water  being



injected below that point and none below 8382 feet.



     Post injection  pass number  three  demonstrates  the  same  effects  as  the  two



previous  runs  except  for  the  gradient  heating   another  five degrees  above  the



packer.   All  three of the  post  injection logs come  back  to  the  same  temperature



below the perforated intervals indicating good log quality control.



     There is no channeling evident in this well.





Case History - 3



     The  previous examples  showed  temperature  logging techniques  applied  using  the



suggested procedures included in this paper.   The  results  are exactly as  expected.



In the next example, shown  in Figure  10,  a  channel is suspected using conventional



gradient  temperature  and differential temperature logging  techniques.    Since  the



injection well had  previously been shut-in,  a base temperature log  was run before



injecting the  cold test  fluid.   Two post  injection  logs were  run to verify  the



fluid entry point and demonstrate  external mechanical  integrity.



     The  majority of the  injected  fluid appears to be entering the upper perforated



interval  from  5040  feet  to  5060  feet as indicated by the cooling  effect.   There



also appears to  be  some  injection into  the  upper   ten feet of the  lower perforated



interval  from 5140 feet to  5160 feet.  A  rapid return to normal gradient  indicates



that there is little or no  injection below 5150 feet.



     The  gradient log shows possible inadequate cementing of the long string casing



above the perforation  and possible channeling.  The  static base pass  and the post



injection passes have opposing gradients between 4670 feet and 4990 feet  indicating



a cooling effect from fluid moving outside  the casing.   The  cooling effect extends



upwards to approximately  4750 feet before returning to normal  gradient.  This depth



correlates to a  lithological change in the open hole  logs and  represents  the top of




                                       -31-

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the injection formation.  There is no evidence  of  migration  of fluid above the top
of the disposal zone.
     Another  log  was  run,  using  the  ROT  tool  and  a flowing  channel  was  again
detected as previously depicted in Figure 7.  The sinusoidal presentation confirmed
the presence  of  the  channel  at 4800 feet  along with  its  orientation  and vertical
extent.  The  tool was  run  above and  below the  suspected  channeling  interval.   The
wave presentation above  and below the  zone of  interest  indicated  no channeling as
previously  illustrated  in  Figure  6.   This example  highlights the  use  of  the  RDT
tool as a secondary source of flowing channel identification.

TEMPERATURE LOGGING PROCEDURES
     The following recommended  procedures for running  temperature  logs on injection
wells  is  a  compilation  of  recommended  practices  from  various   logging  service
companies  and the  authors personal  experiences.    Injection  wells  and injection
practices  are extremely varied and  there  are  certain to  be  exceptions  to  these
rules.
     The  general  approach will   depend  on  the  normal   differential   temperature
between the injected fluids and the receiving formation and the chemical properties
of  the  injected  fluids.  Obviously if  the injected  fluids  are highly corrosive or
toxic  it  is  recommended to  run  the  logs after  flushing the wellbore  with  fresh
water  or brine.    If  the  temperature  of  the  injected   fluid  is  near  the   same
temperature  as the  receiving  zone special  injection  procedures  may  be required.
The two general cases  are described as follows  and shown  graphically on  Figure  11.

Case I
     For wells in which  the injected fluid  temperatures  are at least 35 °F greater
than or less  than the  temperature of the receiving zone  the general approach is to
                                        -32-

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run a log with the well  in its stabilized normal condition prior  to  shut-in.   Then



run  a  series of  logs  after the  well  is shut-in.   This  would  mean  a  stabilized



injecting log and a series of post injection shut-in logs.





Case II



     If the temperature of the injected fluids  are  similar to  that  of the disposal



zone or if the well has already been shut-in for a  period  of  time the procedure is



more complex.  In this case an artificially high or  low temperature  fluid may have



to  be  injected  to impart  a  thermal  change  as  was  done  in  the   Case  Histories



presented.   The well  is  generally  shut-in  for a  time and  allowed  to  stabilize



before the  heated  or cooled fluid is  injected.   Three  critical  survey  parameters



must be determined.  These are:



     1) The time period that the well is shut-in prior to running a base log,



     2) The temperature of the test fluid, and



     3) The volume of the test fluid.





     The  logic diagram presented  in Figure  12 may help determine  whether  Case I or



Case II above may  be employed.





Shut-In Time



     It is  not  necessary  for  the  well  to be shut-in  until the temperature reaches



static conditions.   This could take  days or weeks  in some  cases.   The  pertinent



information  is how the temperature is changing  with  time at  all  depths in the well



after  the well's  condition  has  changed.   The tools  available  today  are  capable of



detecting small temperature changes  accurately  without having  to  wait a long time.



Also  the longer  the well  is  shut-in the  longer  it  is  unavailable for  normal
                                        -33-

-------
injection activities.  A  shut-in  period  of 24 hours  is  generally satisfactory for
mechanical integrity demonstration.

Temperature of Test Fluid
     Although  todays  temperature  tools  are  capable  of  extreme  sensitivity,  the
recorded  logs  are  much easier  to  interpret when the  changes in  the  wellbore  are
relatively  large.    This  is  especially  true  if  the  survey is  conducted  without
removing  the injection tubing.   The  best results are obtained  when  the difference
between the injected fluid temperature and  the well bore  temperature  at the zone of
interest  is at least 35 °F.  The maximum heat flow occurs  in the early part of the
post injection period.  The maximum temperature difference between the borehole and
the surrounding formation exists at this time.  This horizontal heat flow decreases
rapidly with shut-in time.  Also the effects  of  vertical  heat flow are less during
the early part of  the shut-in  period.   For this reason  it  is  recommended  that  a
post injection log be run immediately after the cessation of  injection and one hour
after the cessation of injection.  The timing of any subsequent post injection logs
can be determined based on the  response of the initial post  injection  logs.

Volume of Test Fluids
     The  amount of temperature  change induced  in the  wellbore is a function of the
volume of the  injected  fluid  and rate  of displacement as  well  as its temperature.
Heat  transfer  starts  immediately  as the  injected  fluid  enters  the  well  and  the
thermal   exchange  takes   place  across  the entire  depth  of  the well   above  the
receiving interval.   A sufficient  volume must be injected  so that there is enough
differential left  to  uniformly  heat  or  cool the receiving  zone.   Injection should
also  take place long  enough to  build  up  an  injection  pressure  near to  that of
normal  injection operations.   As  a general  rule  of thumb the  injection volume
                                       -34-

-------
should be the greater of either three well volumes or one  barrel  of fluid per each
foot of disposal interval.  For  example  if a 7" well is considered  with  1500 feet
of disposal  zone and a total depth of 4500 feet,  a volume  of  at least 1500 barrels
or 63,000 gallons  of  fluid would be desirable.   If  a 7"  well  (2 gallons/ft) with
100 feet  of disposal  zone  and  a total  depth  of 4500 feet  is considered,  then a
volume of 4500 x 2 x 3 = 27,000 gallons would be desired.  The higher the injection
rate  the greater  will  be  the  differential  temperature  imparted  at the  zone  of
interest.   In  general,  the  rate should  be near that  of  the  maximum  permitted
injection rates or should be limited by the maximum permitted injection pressure.

Logging Speed and Direction
     Most temperature  logs are  designed to give  the best results  when run  at a
logging  speed  of  25-35  feet per  minute.   Running at  a  faster speed  will  tend  to
spread out  temperature anomalies  or entirely miss small changes.
      It  is  important to  keep the  logging  speed  constant throughout  the  survey.
Stopping  the tool during a  log run should  be avoided.  The logging speed should be
kept constant for  all sequential  passes.
     The  direction  in  which  the well  is  logged   is  also  an  important  factor.
Ideally,  temperature  surveys  should  be run  only  through  undisturbed fluid.  Since
the  logging tool   and  electric   line will  disturb the fluid  in  the wellbore,   the
temperature log should always be  run while going  into the  hole.

Interval  of Investigation
     The  temperature  log  should  be  started  at  least 300 feet  above  the  area of
interest.    In  most  injection  wells  which  are   undergoing  routine   mechanical
integrity testing,  the  objective is  to  determine if  there is any channeling above
                                       -35-

-------
the permitted  disposal  interval.   Therefore  in  these cases  the temperature  log
should be started a minimum of 300 feet above the top of the receiving zone.

Calibration Scales
     The  calibration  scale selected  will  depend on  the  differential  between  the
post injection logs and the base or injecting log.  Frequent shifts in the log will
be required if the scales selected are too small.  This makes  the log difficult to
interpret.   A  scale range  of  4 °F/inch  to  10  °F/inch  is   generally best  for
injection well logs conducted according to the preceding guidelines.
     The  actual scale determination may have to be made at the  time that the log is
conducted.

Data To Include With Log
     A temperature survey  is meaningless  when it cannot be correlated  to  the well
construction or  conditions  under which it was  run.   Data that should  be  included
on, or accompanied with, the log include:
     1) Well pressure,
     2) Time log was run,
     3) Well conditions, shut-in or injecting,
     4) Scales,
     5) Injection rates if injection is taking place,
     6) Construction features, and
     7) Logging Speed.

     To  correlate  the  log  back  to other  well  logs,  it  is desirable  to  run  the
temperature  log  in tandem  with  a casing  collar locator  and/or  a  gamma-ray  log.
This  is  especially important  if the   log  is being  conducted  with the  tubing  and
packer installed or if there are lithological changes at the zone of  interest.
                                       -36-

-------
                                    REFERENCES









Cooke, Claude E., 1973, Radial differential temperature  (RDT)  logging  -  a new tool



  for detecting  and  treating  flow behind casing;  Paper  SPE 7558 presented  at  the



  53rd Annual Fall Technical Conference of SPE-AIME, October 1978, 8 pp.



Dresser  Atlas,   Dresser  Ind.   Inc.,  Home  Office,  1982,  Interpretive  methods  for



  production well logs.



N. L. Ind. Inc., N.  L. McCullough,  1984,  Systems  approach  to  production  logging, a



  training manual for logging engineers.



Wei lex, no date,  Temperature  log interpretation,  Document  No.  CL-2002,  a training



  document for logging personnel, Wei lex, a Halliburton Company.
                                       -37-

-------
FIGURES
 -38-

-------
                     FIGURE 1





TEMPERATURE GRADIENT VARIANCE IN THE UNITED STATES
                       -39-

-------
S31V1S
   (2861 'd3SS3UCJ WOHd
3Hi NI aoNviavA iN3iavaD
  tn       to        f-

   DEPTHS IN THOUSANDS

-------
                      FIGURE 2





TEMPERATURE GRADIENT VARIANCES WITH TYPE OF FORMATION
                        -41-

-------
                                     TEMPERATURE INCREASES
                                                       GYPSUM
                                                              ANHYDRITE
                 Thermal Conductivity in 10"^ Calories/Sec./Cm./°C
 Shale    2.8 - 5.6
 Sand    3.5 - 7.7
 Por. Lm.    4-7
 Dense Lm.  6-8
 Dolomite   9—13
 Quartzite  13
Gypsum   3.1
Anhydrite  13
Salt      12.75
Sulphur    .6
Steel     110
Cement    .7
Water 1.2-1.4
Air    .06
Gas    .065
Oil    .35
                                FIGURE 2

TEMPERATURE GRADIENT VARIANCES WITH TYPE OF  FORMATION
                            (MODIFIED FROM WELLEX)
                                  -42-

-------
         FIGURE 3
CONVENTIONAL SINGLE ELEMENT
TEMPERATURE LOGGING SYSTEM
           -43-

-------
 WIRELINE
TEMPERATURE
   TOOL
   TEMPERATURE
      PROBE
                   GRADIENT
                  TEMPERATURE
                     PANEL
                  DIFFERENTIAL
                  TEMPERATURE
                     PANEL
                 FIGURE 3

    CONVENTIONAL SINGLE  ELEMENT
    TEMPERATURE LOGGING SYSTEM
              (FROM N-L-McCULLOUGH)
                   -44-

-------
            FIGURE 4






DIFFERENTIAL TEMPERATURE RESPONSE
              -45-

-------
             TEMPERATURE
              GRADIENT
NATURAL GRADIENT
        x	\
                   \
                     \
                                           Q.
                                           UJ
                                           Q
                              DIFFERENTIAL
               FIGURE 4

DIFFERENTIAL TEMPERATURE RESPONSE
             (FROM N-L-McCULLOUGH)
                   -46-

-------
              FIGURE 5






RADIAL DIFFERENTIAL TEMPERATURE TOOL
                -47-

-------
                     (
-ANCHOR SPRING
                               •ROTATION MOTOR
                                ELECTRONICS
                               -CONVENTIONAL
                                TEMP. SENSOR
                                RDT ARM WITH
                                SENSOR PROBE
                                -CENTRALIZER
                    FIGURE 5

RADIAL DIFFERENTIAL TEMPERATURE TOOL
                (MODIFIED FROM COOKE, 1973)
                        -48-

-------
                 FIGURE 6





RDT RESPONSE SHOWING ABSENCE OF CHANNELING
                   -49-

-------


















































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CCL A
-20 MV 20
4600
DEPTH








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RAD. DIFFERENTIAL
4 DES F 6
                  FIGURE 6
RDT RESPONSE SHOWING ABSENCE OF CHANNELING
                   -50-

-------
              FIGURE 7






RDT RESPONSE SHOWING FLOWING CHANNEL
                -51-

-------

































TIME DATE ROT SERIAL # PROGRAM MODE JOB # FILE
STAT
CCL A
-20 MV 20















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4800
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              FIGURE 7



RDT RESPONSE SHOWING FLOWING CHANNEL
               -52-

-------
              FIGURE 8
        CASE HISTORY NO. 1 -
BASE AND POST INJECTION GRADIENT LOGS
                -53-

-------
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S
                   4900
                    RUN
                            RUM 3
                    LOGS
                    5000
                    5100
s
BASE LOG
                                NH
 EST
                                              CASING
                                              COLLAR:
                                              DV TOOL
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                              -54-

-------
              FIGURE 9
        CASE HISTORY NO. 2 -
BASE AND POST INJECTION GRADIENT LOGS
                -55-

-------





                    "' iiRUN 3
PERFORATIONS^


                --DEGREES FAHRENHEIT

                                                          u.
                                                             O
                               -56-

-------
                    FIGURE 10
              CASE HISTORY NO. 3 -
BASE AND POST INJECTION GRADIENT AND DIFFERENTIAL
        LOGS SHOWING SUSPECTED CHANNELING
                      -57-

-------
                 TEMRDEG. F)
            90.00           110.00
DIFFERENTIAL TEMP
i:.
     X
                          FIGURE 10

                   CASE HISTORY NO. 3 - ,
                 BASE AND POST INJECTION
                GRADIENT AND DIFFERENTIAL
                 LOGS SHOWING SUSPECTED
                        CHANNELING
                           -58-

-------
              FIGURE 11






GENERAL TEMPERATURE LOGGING PROGRAMS
                -59-

-------
CASE - 1
                NORMAL INJECTION     ^-SHUT WELL IN      ^--RETURN TO NORMAL OPERATION
            INJECTING TEMP. LOG^            VPOST INJECTION LOGS
o
i
CASE - 2


           NORMAL INJECTION      SHUT-IN          /BASE TEMP. LOG      x POST INJECTION LOGS
          /                 ^-           /

         {                                      I     L    I
                                   t

                                   ^SHUT-IN PERIOD      MNJECT TEST FLUID     ^RETURN TO NORMAL
                                                                           OPERATION
                                     TIME
                                        FIGURE 11



             GENERAL  TEMPERATURE LOGGING PROGRAMS

-------
                       FIGURE 12
         LOGIC DIAGRAM FOR TEMPERATURE LOGGING
TO DEMONSTRATE MECHANICAL INTEGRITY OF INJECTION WELLS
                         -61-

-------
M TO MOHMAt OPtHATIOH [    ! (JO TO HOT. HOMf OH RAT LOO
                        FIGURE 12
       LOGIC DIAGRAM FOR TEMPERATURE LOGGING
        TO DEMONSTRATE  MECHAN5CAL  INTEGRITY
                  OF INJECTION WELLS
                           -62-

-------
               INJECTION MONITORING AND CONTROL




                DOLLARHIDE CLEARFORK "AB" UNIT









                        T. S. Collier




                            Unocal




                       Midland,  Texas
ABSTRACT




The Dollarhide Clearfork "AB" Unit, a West Texas waterflood,




currently produces 1600 BOPD and is expected to recover 37




percent of original oil in place.  Of this 37 percent, more




than half is attributable to effective waterflood operations.




In order to effectively waterflood this field, control of




injection water plays a critical role.









This paper describes the benefits of injection monitoring and




control both from a standpoint of protection of ground water




and increased oil recovery. It describes how injection




performance, production performance, radio-active tracer




surveys, and temperature surveys were used to quantify and




identify injection that was not entering the target interval




in the Dollarhide Clearfork "AB" Unit.  Discussions are




presented on the various causes of "out-of-zone" injection as




well as several remedies for this problem.  Finally,



                             -63-

-------
additional oil recovery is shown to be directly related to




the monitoring and control of injection water-









Background Information




The Dollarhide Clearfork "AB" Unit is located in Andrews




County, Texas near the Texas-New Mexico border (Fig. 1).  Oil




production averages 1600 barrels per day from 60 producing




wells.  Average daily water injection is 7000 barrels per day




into 30 water injection wells.









The Clearfork "AB" Unit has three productive zones.  They are




the Upper "A", the "A", arid the "B" zone.  The Clearfork




formation is encountered at an average depth of 6500 ft.




(1980 m).  As shown in Figure 2, the Clearfork formation is a




North-South trending anticline, and although it is not shown




on the figure, there is closure to the south.  The lithology




is predominantly limestone.









On June 1, 1959, the various  leases in the Dollarhide Field,




excepting one operator, were  unitized for the purpose of




establishing a waterflood.  A small scale pilot waterflood




comprising two water injection wells  was initiated.  This




pilot waterflood was expanded in November, 1961 to  include




six injectors.  Increased water production in offsetting




wells was detected indicating a possible problem with
                             -64-

-------
injection control.  This problem was corrected and the




waterflood was expanded to full scale in May, 1964.








In 1959, prior to unitization and waterflood operations, the




life of the Dollarhide Clearfork Field was estimated to be




twelve years, based on production decline data.  By the




implementation of a well designed, closely monitored




waterflood, the life of this field has been extended  into




the next century and will, in all probability, allow it to be




produced using CO2 for enhanced oil recovery.









Benefits of Controlled Injection




Ultimate Recovery.




The chief benefit of controlled injection to the operating




company is reduced operating costs. This is accomplished




through several mechanisms, allowing the operating company to




recover more oil economically from any given project.









The cost reduction takes many forms.  The most obvious of




these is associated with injecting less water to achieve the




desired waterflood performance.  The procurement and




pressurization of water in a waterflood is often a costly




process.  Since the cost of injection is the same for water




that enters the target interval and enhances oil production




as for water which does not, it is important that injection
                              -65-

-------
water is confined to the target interval.









Sometimes, injection water will exit the wellbore, into to a




high permeability lens (or "thief" zone), and then proceed to




an offset producing well.  For example, if the well was




completed "open hole" (the casing is set just above the




target interval leaving the target interval uncased)




injection water may preferentially exit the open hole into a




few fairly thin intervals. Another example involves wells




which are completed with casing cemented through the




producing zone.  Occasionally, the bond between the formation




and the cement used to secure the casing has insufficient




strength to isolate these "thief" zones.  Water entering thin




intervals having high permeability  contributes little, if




any, to additional oil production, but requires additional




expense to produce.  The costs associated with producing a




barrel of water are the same as producing a barrel of oil.









Since oil recovery is predicated on continuing favorable




economics, each increase in operating costs is associated




with a decrease in ultimate oil recovery-









Leak detection.




Injection monitoring and control can assure that injected




water does not enter the ground water aquifer-  This aspect
                              -66-

-------
of injection control is especially important in the




Dollar-hide Clearfork "AB" Unit as the climate is semi-arid




and water wells are the sole source of water for livestock.




Fortunately, the signals that a leak has occurred into the




annulus which could further escape into the ground water




aquifer is readily detected.









Figure 3 shows a schematic cross section of a typical water




injection well including (1) surface casing which is solidly




cemented from the base of the aquifer to surface, (2)




production casing which penetrates the production - injection




zone and is cemented in place, and (3) tubing string with a




packer set immediately above the zone into which water is




injected.  Deviations  from the type of completion shown in




Figure 3 are often necessary, or desirable.  For example,




unusual drilling problems which are encountered at Dollarhide




make it necessary to run an additional or "intermediate"




casing string at 3100 ft. (940 m), which is placed between




the surface and production casing string.  In contrast, other




shallow oil reservoirs require only a production string, thus




eliminating the need for surface casing.









Water to be injected is introduced into the tubing at the




surface and enters the oil zone through perforations in the




casing.  The packer prevents water from contacting the
                             -67-

-------
production casing opposite the aquifer.  Surface pressure of




the annular space between tubing casing is monitored and if




communication occurs, a pressure increase will be observed at




the surface.  Corrective action can then be taken to repair




or replace the tubing or packer, as necessary, which is the




first line of defense.  In this schematic, second and third




lines of defense are provided by the production and surface




casing strings, respectively.









Monitoring Methods




Tubing-Casing Annulus Pressure.




As noted above, the most effective way to verify that fresh




water aquifers are not being impacted is by the diligent




monitoring of tubing-casing annulus pressures.  If no




pressure exists, then communication with the ground water




aquifer is not taking place.









Well Performance.




A valuable tool available to the petroleum engineer in




evaluating the effectiveness of underground injection is the




analysis of the production performance of the wells which




offset an injection well.  Early water breakthrough into the




producing well indicates that injected water is most likely




exiting the injection wellbore into a high permeability lens




of limited size.  Further corrective action may be warranted,
                             -68-

-------
as it was in the Dollar-hide Clearfork "AB" Unit.








Radio-Active Tracer Surveys.




One very useful tool for tracking and quantifying water exit




from an injecting well is the use of radio-active tracers.




By injecting a small amount of radio-active material and




measuring the length of time it takes to travel a certain




distance within the wellbore, it is possible to determine the




amount of injection water exiting the wellbore over a given




interval.  This information is very useful in designing any




corrective action which may be required.









Temperature Surveys.




Another useful tool in determining injection water exit from




the wellbore is the temperature survey.  By recording the




wellbore temperature vs. depth, an analysis may be made of




intervals where injection water is leaving the wellbore.  The




temperature survey  yields interpretations which are more




qualitative than the radio-active tracer, but offer a




slightly better idea of what happens to the injectant




after it leaves the wellbore.
                              -69-

-------
Mechanisms of Out-of-Zone In.lection.




Mechanical Integrity.



One cause of injection outside of the target zone may be a




lack of mechanical integrity.  This is evidenced by an




increase in pressure on the tubing-casing annulus.  Prompt




attention to the situation and timely repair should ensure




that injection water does not enter the tubing-casing




annulus.








Primary Cementing Procedures.




Occasionally, the primary cementing procedures used in older




wells did not achieve sufficient bonding to the pipe or the




formation to prevent the flow of injection water behind




casing.  This situation can be corrected by squeezing cement




into the formation and behind the primary cement.









Dollarhide Clearfork "AB" Pilot Flood Performance




Description of Pilot Flood.




As shown in Figure 4, six producing wells were converted to




water injection service in November, 1961.  Of the six, five




were completed open hole.  The remaining well was a dual




completion and was perforated in the Lower "A".  Water was




injected into the six wells and production performance was
                             -70-

-------
monitored in the offsetting producing wells.









Early Injection-Water Breakthrough.




After only six weeks of water injection, water production was




observed in well number 15-72-C.  By July, 1962, just eight




months after injection was initiated, water breakthrough had




been observed in  eight offset producing wells.  Water




production steadily increased while oil production




diminished.  Finally, in October, 1962, injection was




discontinued.








In the case of the Dollarhide Clearfork "AB" Unit, the key




indicator had been early water breakthrough. Further




investigation using tracer surveys indicated that a thin,




highly permeable zone at the top of the Upper "A" interval




was acting as a "thief" zone within the oil reservoir.  Water




injected into the wells was not reaching the target interval,




but instead was virtually all exiting from the top 150 feet




of open hole.








During the period while injection was discontinued  between




October, 1962, and March, 1963, oil production from two




offsetting wells decreased by a total of 20-30 barrels per




day.  This indicated that some oil response had been achieved




and that a solution of the breakthrough problem would result
                             -71-

-------
in a significant increase in oil production.









The Solution.




Several alternatives were considered, such as re-cementing




and recompleting,  attempting to cement off selected




intervals, and cementing inner liners which are placed




opposite the injection interval. The latter alternative was




selected as the most effective solution for several reasons.




A steel liner has  the best mechanical integrity of the three




methods considered.  In addition, liners offer the best




wellbore stability and are superior to cement repairs for




isolation of the injection intervals.  The drawback of this




alternative was the reduction in internal diameter which




would make future  workover operations more difficult.  Also,




it was the most expensive of the three solutions considered.









In designing the liner installations, care was taken to




properly balance all considerations.  In this type of design




there is a trade-off between the size of the pipe (the larger




the pipe the fewer the problems during future injection and




workover operations), and the likelihood of obtaining a good




primary cement bond.  After considering the size and




condition of the open hole section, liner sizes were were




determined on a well-by-basis.  During the five month period




from October, 1962, to March, 1963, five liners were
                             -72-

-------
installed and cemented, after which time water injection was




resumed.









Results.




Following the installation of liners in the Dollarhide




Clearfork "AB" Unit Pilot Waterflood, water production was




stabilized and oil production was increased, (Fig. 5).




Water production was virtually eliminated in three of the




offsetting production wells .  Based on the results of the




pilot waterflood, full scale water injection was initiated in




the Dollarhide Clearfork "AB" Unit in May, 1964.  The




techniques used to monitor and control the water injection in




the pilot water flood have been extended throughout the field




and have enabled Unocal to double total oil recovery over




primary depletion.









Conclusion




Close control and monitoring of injected fluids in a




secondary recovery project can improve economics and




reserves.  This objective may be achieved by close




surveillance of tubing-casing annulus pressures, by carefully




monitoring the production performance of offsetting producing




wells, and by using various wellbore surveys.
                             -73-

-------
FIGURE
                                  't
         INDEX MAP
           SHOWING

   DOLLARHIDE   FIELD
      ANDREWS COUNTY,TEXAS
  -74-

-------
                           FIGURE 2
                                        ""
    ~K.lt' UNIT
CLEAR FOHK WELLS ONLY
              DOLLARHIDE CLEAR FORK AB  UNIT
                  STRUCTURE - TOP OF B ZONE
                              1 MILE
                           -75-

-------
                           FIGURE  3
///^V/A^
\
X
                     CASING
                   PERFORATIONS
///sy/A\y7/
                                                         AQUIFER
                                        -SURFACE CASING
                                        -INJECTION TUBING
                                        -PRODUCTION CASING
                                         INJECTION PACKER
                                        TARGET INTERVAL
                 TYPICAL WELLBORE SCHEMATIC
                                -76-

-------
FIGURE 4
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   -77-

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                                             -78-

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                                            NIPER  Paper  No.  EPR/OP-87/10

SUBSURFACE  INJECTION  OF  FLUIDS FOR THE  RECOVERY  OF  PETROLEUM
         By A. Gene  Collins  and  Herbert B. Carroll, Jr.
                          IIT Research  Institute
     National Institute for Petroleum and Energy  Research
                              P.  0. Box  2128
                         Bartlesville,  OK   74005

                         To be presented at the
              UNDERGROUND  INJECTION  PRACTICES COUNCIL
                INTERNATIONAL  SYMPOSIUM ON  SUBSURFACE
                      INJECTION  OF OILFIELD BRINES
                New  Orleans,   Louisiana,  May 4-7,  1987
                             COPYRIGHT WAIVER

      By  acceptance of  this  article for  publication,  the  publisher recognizes  the
      Government's (license) rights in any copyright and the government and Its authorized
      representatives  have unrestricted rights to reproduce In whole or  in part said
      article under any copyright secured by the publisher.
                                 DISCLAIMER

     This  report was  prepared as an account of work sponsored by an agency of the United
     States Government.  Neither the United States Government nor any agency thereof, nor
     any of their employees,  makes any warranty, express or Implied, or assumes any legal
     liability or  responsibility for the accuracy, completeness, or usefulness of any
     Information, apparatus,  product, or process  disclosed, or represents that its use
     would  not  infringe privately  owned rights.   Reference  herein to any  specific
     commercial  product, process, or service by trade name, trademark, manufacturer, or
     otherwise, does not necessarily constitute or imply its endorsement, recommendation,
     or favoring by the United States Government  or  any agency thereof.   The views and
     opinions  of authors expressed herein do  not necessarily state or reflect those of
     the United States Government or any agency thereof.
                                    -79-

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                               TABLE OF CONTENTS
                                                                           Page
Acknowl edgments	    v
Abstract	   vi
Introduction	    1
011 Recovery Mechanisms	    3
          Primary Recovery	    4
          Secondary Recovery	    4
          Tertiary Recovery	    6
EOR Selection Methodology.	    7
          Laboratory Tests	    7
Water and Rock in Secondary and Tertiary Recovery Operations	    8
     Injection Water	    8
          Water Sources	    8
          Formation Water	„	    9
          Fresh Water	   10
          Seawater	   11
          Water Compatibility	   12
          Core Flow Tests	   12
          Corrosion	   13
          Bacteria	   14
     Formation Rock Minerals	   14
     Fluid Injection Treatment Systems	   16
                                     -80-

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                         TABLE OF CONTENTS (Continued)
                                                                          Page
Types of EOR Operations	  16
     Micellar-Polymer EOR Operation	  16
     Polymer	  18
     Alkaline	  19
     Carbon Dioxide	  20
     Steam	  21
     In Situ Combustion	  21
     Miscible Hydrocarbon	  22
     Inert Gas Injection	  22
     Microbial Flooding	  23
     Cyclic Microbial Flooding	  23
     Quantity of Chemicals Used in EOR	  24
          Mobility Control Agents (Polymers)	  24
          Cosurf actants	  25
          Alkaline Flooding Agents, Preflush Agents, Thermal  Enhancers...  25
          Surfactants	  25
          Biocides, Chelating Agents, Oxygen Scavengers	  26
Transport and Fate	  26
Conclusions	  26
References	  28

                                    TABLES
  1.   Geochemical  Water Analyses	  31
  2.   Tertiary System	  32
  3.   Toxicological  Data	  33
                                      -81-

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                       TABLE OF  CONTENTS (Continued)



                                                                          Page



                               ILLUSTRATIONS



 1.   Oil  Production	   35



 2.   Crude Oil and Water Produced (Including Alaska)	   36



 3.   Crude Oil and Water Produced (Excluding Alaska)	   37



 4.   Chemical Flooding (Micellar-Polymer)	   38



 5.   Chemical Flooding (Polymer)	   39



 6.   Chemical Flooding (Alkaline)	   40



 7.   Carbon Dioxide Flooding	   41



 8.   Steam Flooding	   42



 9.   In-Situ Combustion	   43



10.   Nitrogen — C02 Flooding...	   44



11.   Microbial Flooding	   45



12.   Cyclic Microbial Flooding	   46
                                    -82-

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                                ACKNOWLEDGMENTS
    The authors appreciate the support of this work by the U. S. Environmental
Protection Agency (EPA) through Contract/IAG DW89931947-01-0 and the U. S.
Department of Energy (DOE) through an interagency agreement with the EPA. The
authors also thank Bill Linville for his encouragement and for editing the
manuscript and Joe R. Lindley who prepared the drawings of enhanced oil
recovery processes.
                                    -83-

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         SUBSURFACE INJECTION OF FLUIDS FOR THE RECOVERY OF PETROLEUM
                By A. Gene Collins and Herbert B. Carroll, Jr.
             National Institute for Petroleum and Energy Research
                            Bartlesville,  OK   74005

                                   ABSTRACT
    This report addresses the major methods used to recover petroleum which
are classified as (1) primary, (2) secondary, and (3) tertiary or enhanced oil
recovery (EOR).  Further, EOR methods which include miscible, thermal, and
chemical are described.  Subsurface injection of fluids is used in secondary
and tertiary petroleum recovery operations.
    The report notes that one of the most important criteria relevant to an
injection operation is adequate geologic and engineering characterization of
the subsurface reservoir.  Reservoir screenings and detailed characterizations
of reservoirs are made by use of appropriate computer models.
    Laboratory studies are conducted using core samples taken from the target
injection zone in conjunction with appropriate dynamic flowthrough core
apparatus, whereby porosity, permeability, ion exchange, clay sensitivities,
rock wettability, miscibility, etc. are determined.   The laboratory data and
the characterization data are used in an appropriate computer model to predict
the probable hydrologic transport and flow of the injected fluids and the
targeted petroleum.   If these studies indicate a high probability of success
for economic petroleum recovery, the next step is a pilot field test.  If the
pilot test indicates that an economic amount of petroleum can be recovered,
then a full-scale field operation is designed and properly sited, wells are
drilled, injection and production equipment is installed, and the petroleum
recovery operation begins.
    Important operations may include reservoir preflush for the removal of the
connate brine; injection fluid treatment to mitigate clay sensitivities or to
                                    -84-

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prevent corrosion and incompatible reactions.  The waters used in injection
operations consist of formation water, fresh water, or seawater, and
consideration must be given to fluid-fluid interactions and fluid-rock
interactions.
    Micellar-polymer, polymer, alkaline, carbon dioxide, steam, in situ
combustion, miscible hydrocarbon, inert gas, and microbial EOR processes are
briefly described.  The types and amounts of some of the injected chemicals
also are addressed.
                                    -85-

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                                 INTRODUCTION
    Subsurface petroleum reservoirs possess natural pressure, and when a
producing well is drilled into the reservoir, the pressure is reduced,
creating a pressure differential which moves the oil and gas from the
reservoir into the well and to the surface.  This pressure is caused by water
pressing upward from beneath the petroleum (water drive); a gas pressing
downward (gas cap drive); by gas in solution (solution gas drive); or by all
of these working together.  In most reservoirs, initial pressure is strong
enough to lift the oil to the surface of producing wells; however, as
reservoir pressure declines with cumulative oil withdrawals, "artificial lift"
is required to raise petroleum to the surface.  This is accomplished with
downhole pumps lifting the oil to the surface or by injecting gas deep into
the fluid column to lighten the weight of the fluid (gas lift).
    Even when reservoir pressure is depleted and no longer lifts oil to the
surface, the reservoir pressure may be adequate to move petroleum through the
formation into the well bore.  Primary recovery, or production relying
entirely on natural forces, often recovers a substantial portion of a field's
total petroleum reserve.
    Natural forces are wastefully dissipated when inefficient production
procedures are used.  In the oil booms of yesterday, when "boomers" rushed to
drill as many wells as possible and produce oil as fast as they could, total
recovery was far less than that of today's methods.  Oil reservoirs must be
carefully managed to conserve pressure and optimize recovery.
    Today, the number, location, and producing rates of oil wells are planned
to maximize recovery and to maintain production as long as possible.  Natural
forces are augmented by injecting replacement fluids like water and/or gas,
and these efforts are known as secondary recovery operations.
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    The methods described as "primary" or "secondary" operations move only
part of the oil, often leaving as much as 40 to 80 percent unrecovered.  Even
a we11-engineered waterflood leaves more than one-third of the original oil as
unrecovered residual oil.  The national average for oil recovery by both
primary and secondary methods is only about 34 percent.
    Enhanced or "tertiary" methods recover residual oil by increasing the
volume of the reservoir contacted and by reducing interfacial tension.  These
enhanced methods are classified as follows:
    •    Thermal recovery.  Heated oil flows more easily through the reservoir
         rock.  It may be heated by injecting high-pressure steam into the
         reservoir or by actually burning some of the crude oil in the
         reservoir rock (fireflooding).
    •    Miscible recovery.  Miscibility is the ability of fluids to mix with
         each other to form a single phase.  Normally, oil and water separate
         into layers and are not miscible.  Some fluids that mix with oil are
         effective in displacing oil from reservoirs; for example, light
         liquid hydrocarbons, such as propane and ethane, which are extracted
         from natural gas.  Carbon dioxide is also miscible with oil.
    •    Chemical  recovery.  Chemicals with large molecules,  such as polymers
         which "thicken" water when added in low concentrations to water, are
         used to enhance recovery by improving the ability of water to "wash"
         or "sweep" oil from the rock pores.  Surfactant flooding calls for a
         combination of surfactants (special detergents) and  polymers  used to
         recover residual  oil that remains trapped after secondary recovery.
         A "bank"  or "slug" of fluid (mostly water)  containing surfactant is
         injected  to reduce the interfacial  forces trapping the residual oil
         allowing  it to flow to the producing wells.   The surfactant bank is
                                     -87-

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         followed by water usually thickened with polymer to maximize  the
         volume of reservoir contacted.
                            OIL RECOVERY MECHANISMS
    There are three major types (or mechanisms) of recovery of oil from
subsurface reservoirs: primary, secondary, and enhanced.  Each type of
recovery is associated with the original-oil-in-place, the remaining oil-in-
place  (subsequent to recovery or production operations), and the pressures
within the reservoir.  For example, when a well is drilled into a subsurface
reservoir containing oil, tests are conducted to determine the amounts of oil,
water, and gas that are present.  This  information plus knowledge of the
depth, reservoir thickness, reservoir pressure, reservoir lithology, and
results from specific production tests  permits accurate calculations of the
amount of oil in the reservoir.  Further, calculations can indicate how much
oil should be produced by primary recovery when primary recovery is defined as
oil produced from a well as a result of oil flowing and finally pumping the
reservoir until it is depleted or no longer economical to operate.  Secondary
recovery usually involves repressuring  by gas injection or water injection,
i.e., simple waterflcoding.  The third  or tertiary phase employs more
sophisticated technology such as altering one or more properties of the crude
oil to reduce surface tension.  This technology is known as enhanced oil
recovery.  Tertiary recovery often is accomplished by injecting water mixed
with specific chemicals that "free" the oil adhering to the porous rock so
that it is taken into the solution and  pumped out of the well.
    Figure 1 illustrates the three major oil recovery operations where, during
primary recovery, 12 to 15 percent of the original oil-in-place is produced.
Secondary recovery can produce an additional 15 to 20 percent of the oil
reserve, and enhanced oil recovery (EOR), another 20 percent.
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    Primary Recovery
    As noted in figure 1, primary recovery refers to oil that can be recovered
from the subsurface reservoir through the natural energy of the reservoir.
Artificial lift such as pumping may be used, but injection of water is not
used in primary recovery.
    Secondary Recovery
    The widespread application of waterflooding  (Craig, 1971) to boost
production after initial decline in primary production  led to this process
being called secondary recovery.  For regulatory and pricing purposes
waterflooding has been set apart from other forms of EOR.  In a typical
waterflood, the "watercut" in the produced fluid continually increases, and
the expenses of pumping, separation, and disposal of the floodwater eventually
exceed the income from the oil recovered.  Then  secondary recovery efforts are
halted even though oil may remain in the reservoir.
    The effectiveness of secondary recovery is dependent on the volume of the
reservoir contacted by the injected fluid, which is dependent on the
horizontal and vertical  sweep efficiency of the  process.  Factors which
control the sweep efficiency are  (1) pattern of injector wells, (2) off-
pattern wells, (3) unconfined patterns, (4) fractures,  (5) reservoir
heterogeneity, (6) continued injection after breakthrough, (7) mobility ratio,
and (8) position of gas-oil and oil-water contacts.   (Langnes et al.,  1985)
    Selection of an injection pattern is one of  the first steps  in the design
of a  secondary recovery  project.  In making the  choice, it is necessary to
consider  all available  information about the reservoir. The adverse effects
of the factors listed above can be offset if they  are  considered during the
pattern selection.  Other factors to consider  in pattern selection are
(1) flood  life, (2) well spacing, (3) injectivity,  (4)  response  time,  and
                                      -89-

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(5) productivity.
    Waterflood life depends on the availability of injection water, the rate
at which it can be injected, well spacing, and proration policies.  The
performance and economics for various well spacings and pattern sizes should
be analyzed in order to pick the economically optimum choice.  These analyses,
however, cannot be made without considering injectivity, which is best
determined using pilot operations, and a well designed and applied pilot
operation is essential to understanding all the pattern selection factors.
    An ordinary waterflood, operated at practical rates with ordinary water or
brine, is physically incapable of displacing all of the oil from reservoir
rock.  Capillary forces acting during the waterflood may cause part of the oil
to be retained in water-wet rock as disconnected structures which do not flow
under the pressure gradient from the flow of water.  The detail of these
structures is directly related to the microscopic mechanism of oil
entrapment.  Thus, even in those regions of the reservoir which are relatively
well-swept, i.e., regions through which relatively large quantities of water
flowed, a residual oil saturation can range from 15 to 40% of pore space.  The
residual oil saturation in well-swept regions of proven accessibility with
respect to injected fluids is an important target, though a difficult one, for
EOR.
    Ordinary waterflooding is a less expensive process than most EOR
operations.   However, the economics of waterflooding becomes uneconomical when
the revenue produced by the amount of oil recovered is less than the cost of
waterflood injection, which may occur when the residual oil saturation is as
high as 40% of pore space to as low as 15% of pore space.
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    Tertiary Recovery
    The target oil for recovery is the residual oil in the reservoir that is
left after primary and secondary recovery operations.  Tertiary recovery by
EOR methods usually is a more expensive operation and is not usually applied
unless the price of oil is sufficient to pay the costs of producing the oil
from the subsurface reservoir.  In this report, we shall refer to tertiary
recovery as enhanced oil recovery or EOR.
    Petroleum production from reservoirs under primary, secondary, or EOR
processes involves the simultaneous flow of two or more fluids.  Multiphase
flow, particularly three-phase flow, is not well understood or adequately
described analytically, even for pipeline flow.  With natural porous media
with complex geometry, a microscopic description of the multiphase fluid flow
process is not possible.  Empirical macroscopic descriptions based on Darcy's
work, relating fluid velocity to pressure gradient and viscosity through a
constant called permeability, permits the needed fluid-flow calculations.
Multiphase flow of fluids through porous media is related to a relative
permeability of each phase, fluid viscosities, pressure drop, capillary
pressure, and permeability; however, the relative permeabilities are the least
understood and the most difficult quantities to measure.
    The effectiveness of EOR is dependent upon the same variables as secondary
recovery with regard to sweep efficiency, injection patterns, etc.  Since EOR
usually is more expensive to implement per barrel of oil recovered, the
preliminary work before implementation often is more detailed and exacting
than for primary and secondary recovery operations.  The studies often involve
geological reservoir characterization, laboratory studies, computer simulation
studies, and field pilot studies.
                                     -91-

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                           EOR SELECTION METHODOLOGY
    Since the oil targeted for EOR is difficult and expensive to obtain, the
oil producer wishes to apply only the most cost-effective technology to
extract the oil.  Selection of the most cost-effective technology requires
several studies, as noted by Goodlett, et al. (1986).  Detailed information
concerning geological, chemical, physical, and engineering characteristics of
the target reservoir rocks and fluids (oil/gas/water) is used along with
screening parameters to make a preliminary EOR selection.  Subsequent to
selection of a candidate method, basic laboratory tests are performed
including dynamic fluid flowthrough core experiments using simulated
subsurface pressures and temperatures.
    Information gathered from these tests, plus other relevant knowledge, is
used as input variables for numeric computer models which helps decide the
viability of the selected EOR process.  Other relevant knowledge includes
reservoir characterization in as much detail as possible.  The presence of
certain minerals and/or reservoir heterogeneities adversely affect EOR.
Knowledge of micro-scale reservoir heterogeneities such as dead-end pores,
pore throat size, and tortuosity also is important.
    Laboratory Tests
    Goodlett, et al. (1986) described some of the numerous experiments and/or
tests that should be conducted before implementation of even a pilot EOR
operation.  For example, scaling should be determined by application of linear
scaling principles to better reproduce the basic operative physical and
chemical mechanisms which will occur in the reservoir.  Scaling experiments
are accomplished through the use of laboratory core floods.  Cores used in
laboratory core floods range from sandpacks to native-state reservoir samples
which are obtained and retained at subsurface conditions of temperature,
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pressure, and fluid saturations.  Native-state cores are the most expensive
and most useful porous-media system for EOR evaluation.
    Core wettability is a critical factor in evaluation, and alteration of the
wettability can occur during the operations of obtaining a core.  Other
important tests include injectivity, plugging, mobility control, relative
permeability, oil saturation, rock-fluid and fluid-fluid interaction, etc.
         WATER AND ROCK IN SECONDARY AND TERTIARY RECOVERY OPERATIONS
INJECTION WATER
    Items that should be considered before implementation of a fluid injection
project involving any type of injection water include the following:
(1) formation type; (2) formation quality such as clay content; (3) formation
porosity and permeability; (4) depth of formation; (5) fracture-opening
pressure of formation; (6) fracture-breakdown pressure of overlying and
underlying formations and; (7) compatibility of injection solutions with
fluids already in the formation and with the formation rock material.
    Petroleum reservoir rock formations are filters and are susceptible to
plugging by any type of solid material which may be suspended in or
precipitated from an injection fluid.  Even materials such as oil  and grease
from the pumps, corrosion inhibitors, and bactericides can cause plugging
problems.
    Table 1 lists the items typically requested in analyses of a produced
oilfield water; water used in injection for pressure maintenance for secondary
recovery for EOR; water used to generate steam for steam injection; and water
injected into a disposal  well.
    Water Sources
    Three major types of  water are used for injection:  formation  water,
seawater, and fresh water.
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    Formation Hater
    Formation water is subsurface brackish or brine water usually produced
from a petroleum producing formation.  Table 2 illustrates the composition of
some formation waters taken from some Tertiary Age formations.  The table
gives the highest value found in milligrams per liter for a given constituent,
the average values, and the number of samples used to estimate the average
value, Collins (1975).
    An estimate of the amounts of water that are in various reservoirs was
made for the State of Oklahoma.  The estimate indicated that Oklahoma has
about 3.4 trillion gallons of surface water possessing a quality of 100 to
1,000 ppm dissolved solids (OS); about 5.0 trillion gallons of ground water
with a quality of 280 to 4,000 ppm OS; about 23.6 trillion gallons of
formation water down to 5,500 feet deep with a quality of 15,000 to 110,000
ppm DS; and 35.8 trillion gallons of formation water down from 5,500 to 8,500
feet deep with a quality of 15,000 to 110,000 DS.   Further, it was> determined
that the State of Oklahoma has no exact information on the quantity or quality
of water injected or produced in petroleum operations involving primary,
secondary, and EOR.  Related information for other states was not determined
(Collins and Wright, 1982).
    An analysis was made of the approximate amount of water produced with
crude oil in 14 states.  The states and their percent of total U.S. crude oil
production are:  Alabama, 0.3%; Alaska, 19.9%; California, 11.7%; Colorado,
1.0%; Florida, 1.4%; Louisiana, 13.4%; Montana, 1.0%; Mississippi, 1.2%;
Nebraska, 0.2%' New Mexico, 2.3%; North Dakota, 1.4%; Texas, 31.2%; Utah, 0.8;
and Wyoming, 4.2%.
    Figure 2 indicates the crude oil and water production from wells in the 14
states.   The figure indicates that about 4.3 barrels of water is produced per
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barrel of oil.  Figure 3 is a similar graph for 13 states excluding Alaska.
This figure indicates that about 5.2 barrels of water is produced per barrel
of oil.  Further it can be shown that oil wells produce more water as
cumulative oil production increases.  In other words, the older the well, the
higher the water-to-oil ratio.
    Fresh Water
    Fresh water primarily is water that can be made potable by flocculation,
filtration, and/or chlorination; contains less than 2,000 ppm dissolved solids
(DS); and can come from surface sources such as lakes, rivers, or underground
sources.  In any EOR project, a first consideration must be given to the water
source.  In some projects where a fresh water preflush is necessary, it is
obvious what the water source must be.  Usually some sodium chloride is added
to the fresh water to inhibit clay swelling.  Some EOR chemicals can tolerate
a more salty water.  In such cases formation water, a mixture of formation
waters, a mixture of formation water and fresh water, or even seawater might
be feasible.  When surfactants, polymers, and caustics are used with these
waters, precipitates caused by reactions with multivalent cations pose major
problems.  The two most problematic cations are calcium and magnesium,
primarily because they are so highly concentrated in some waters.
    The first step in determining the suitability of any water is to analyze
the water for physical properties and for chemical and biological
constituents.  Next, the composition of the formation into which it is to be
injected should be determined.  Clays such as smectites, kaolinites,
chlorites,  and illites are sensitive to fresh water.  Permeability reduction
may occur because of clay dispersion and clay swelling, Mangan (1965).
Increasing  the salinity of the water usually minimizes the effect.
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    Smectites and illites are the more common clays sensitive to fresh
water.  They can absorb water on their edges and surfaces.  Fresh water can
penetrate between the layers of a smectite to cause the plates to separate and
disperse.  Therefore, formation damage caused by fresh water usually  is most
severe in a formation that contains smectite.
    Seawater
    Several companies use seawater for water injection as a pressure
maintenance technique or for secondary recovery in some giant oil reservoirs,
Davis (1974); Mitchell (1978); and Carlberg (1979).  It is injected into both
sandstone and carbonate reservoirs.  Some of the negative aspects of  seawater
injection are described by Ogletree and Overly (1978).
    Eventually seawater will be used as an injection fluid in EOR technology,
Jerque (1984).  The use of seawater presents the same problems associated with
any open system; that is, where air-water contact exists.  Seawater presents
some additional problems; one of the most notable is the biomass; for example,
organisms such as copepods, diatoms, and dinoflagellates.
    Mitchell and Finch (1978) outlined some of the necessary water quality
tests including:  membrane filter test, examination of the filtered
particulates with light and scanning electron microscopy, on-site core
injectivity tests, particle size distribution in the injection water with
respect to the pore size distribution in the reservoir, amount and type of
biomass (other than bacteria) in the raw seawater, and bacterial levels
(aerobic and anaerobic).   They found that cores are superficially plugged by
lipids derived from copepods plus inorganic debris.  They also emphasized the
plugging of cores by bacterial debris, which was documented by Fekete (1959).
                                     -96-

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    Water Compatibility
    Waters that can be mixed without the formation of precipitates are
considered to be compatible.  Henkel (1953,1955) reported testing brine and
wastewater compatibility by allowing a mixture of the two liquids to stand
from 8 to 24 hours at the approximate aquifer temperature.  The mixture is
considered compatible if it remains free of precipitates.  Others have
suggested that this criterion may not always be entirely satisfactory, since
reactions may require considerable time for completion and because gaseous
reaction products may also cause reduction in permeability (White and Delany,
1982).
    If the planned project is EOR using chemicals such as surfactants,
polymers, or caustics, the compatibility tests become even more complex.  For
example, various studies indicate that sulfonates and polymers react with the
multivalent cations in formation water, Meister, et al. (1980).  The tolerance
of petroleum sulfonates to the multivalent cations depends upon the average
equivalent weight (AEW) of the sulfonate.  In general, the amount of cation
tolerated increases as the AEW of the sulfonate decreases.
    Ostroff (1979) presents two methods of determining water compatibilities
and information on how to predict scale formation.  Collins (1975) presents
some information on brine stabilization and methods for calculating over and
under saturation of some relatively insoluble compounds.  A method approved by
the American Society for Testing and Materials (ASTM) Subcommittee D-19.09
appears in section 11.02 of the ASTM 1985 Annual Book of Standards.
    Core Flow Tests
    Core flow testing is the only good method of determining the effects of
the proposed injection fluid upon the permeability of the formation
reservoir.  McCune (1977) describes some core test equipment for a flow
                                     -97-

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test.  An ASTM standard practice using core flow testing is in press and will
appear in the 1987 ASTM Annual Book of Standards on Water, Section 11, Volume
11.02.
    Near-well filtration is the filtration of small particles on the face of
the formation from injected solutions which causes injection rates to lower.
Eventually, the permeability of the interior of the formation will decrease.
For example, it is not unusual for water injection rates to decline by 50% in
12 months.  The only way to circumvent this is to inject water that contains
no suspended solids and is compatible with the formation water and formation
rocks, especially the clays.  Workovers can improve the injection rates after
a decline but are expensive and time-consuming.
    Corrosion
    Ostroff (1979) lucidly defines corrosion and the forms of corrosion found
in oilfield operations.  As he points out, electro-chemical corrosion of steel
is the usual type found in the oilfield.  He further notes that "it is
necessary to have an (1) anode; (2) cathode; (3) electrolyte, and (4) external
connection.  Remove any one of these and corrosion will cease."  Obviously the
electrolyte is the water, and it is impossible to remove it in an oilfield
water system.  Also it usually is impossible to remove the anode, cathode or
the external connection in most oilfield systems.  Complete coating of the
steel lines and vessels or use of non-conducting lines and vessels (cathodic
protection) would solve the problem, but this is not yet feasible for all
systems.
    The gases in some EOR injection waters, which are deleterious because of
potential corrosion problems, are 02, H2S, and C02.  The presence of these
gases in salt water presents severe corrosion problems because salt water is
                                     -98-

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an electrical conductor and is corrosive, and the corrosivity increases as the
water becomes saltier and as the concentration of 62, ^S, or CC^ increases.
    These dissolved gases drastically increase the corrosiveness of salt
water.  Fewer corrosion problems exist if they are removed and if the
injection water is maintained at a neutral or slightly higher pH; however,
because of the effect of high pH on clay swelling, a pH above 7 may be
undesirable.
    Bacteria
    Injection waters must be free of bacteria because they can cause corrosion
as well as plugging of the equipment and the face of the injection well.
Bacteria can reproduce rapidly, and they populate in extremely diverse
conditions such as low and high pH, temperature, pressure, and even in the
absence of oxygen.  Patton (1975) and Collins and Wright (1982) describe tests
and problems bacteria cause in oilfield water injection operations.
FORMATION ROCK MINERALS
    As noted by Collins and Kayser (1985), a small number of minerals comprise
the mass of most sandstone aquifers, and the average sandstone consists of
66.8% Si02 (mostly quartz), 11.5% feldspars, 11.1% carbonate minerals, 6.6
percent micas and clays, 1.8% iron oxides, and 2.2% other minerals.  Limestone
and dolomite aquifers are primarily CaC03 and CaMg(C03)2, respectively, but
some contain 50% noncarbonate constituents such as Si02 and clay minerals.
    Quartz, the main constituent of sandstones, is the least reactive of the
common minerals and generally can be considered nonreactive except in highly
alkaline solutions.  Clays can react with highly basic or highly acidic
solutions; however, an injected fluid need not be highly acidic to attack
                                     -99-

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certain clay minerals.  The degree of reaction of feldspars and micas with
injected solutions is uncertain, but some reaction is likely to occur.
    Sandstone aquifers often are cemented with carbonate minerals, which react
with acid solutions.  Reaction of acid wastes with the carbonate cement in
sandstone causes an evolution of C02 that increases the pressure and reduces
the permeability.  In the special case of acid aluminum nitrate wastes, it was
determined that the reaction of the waste with CaC03 creates a gelatinous
precipitate that plugs sandstone pores.  Many sandstones are composed of
gypsum and limonite cementing material.  These two minerals can dissolve,
reprecipitate, and block pores.  Deep limestone, dolomite, or calcareous
sandstone aquifers usually contain brines which are in chemical equilibrium
with the aquifer, and dissolution and/or reprecipitation are not as likely to
occur.
    If injected EOR fluids are at a lower pH than formation waters, solution
of the carbonate reservoir material can occur.  This reaction is beneficial if
gelatinous precipitation does not occur.  If alkaline injected fluids mix with
formation water and raise its pH, dissolved salts can precipitate and plug
pores.
    Clay minerals are present in sedimentary rocks, and sandstones containing
less than 0.1% clay minerals probably do not exist anywhere except in small
deposits of almost pure glass sand.  Clay minerals reduce the permeability of
sandstone to water versus its permeability to air, and the degree of
permeability reduction to water versus air is the water sensitivity of a
sandstone.   Collins and Kayser (1985) address phenomena associated with
injection of oilfield waters into formation rocks; for example, anhydrite
versus gypsum, clay sensitivities, ion exchange, and adsorption.
                                    -100-

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FLUID  INJECTION TREATMENT SYSTEMS
    Water and/or EOR fluid  injection systems are divided  into two categories;
(1) closed systems and  (2)  open systems.  A closed system  is designed to
exclude air or oxygen, whereas an open system makes no attempt to exclude
oxygen.  Ostroff (1979) and Patton  (1981) present detailed  information
concerning injection water  chemistry; chemicals used  in scale and corrosion
prevention; chemicals used  to control microorganisms; and methods used  in
coagulation, sedimentation, filtration, degasification, etc.  Modifications
and/or extensions of these  methods  are used in EOR injection fluid
pretreatment.
                            TYPES OF EOR OPERATIONS
MICELLAR-POLYMER
    Figure 4 shows a single 5-spot  injection-production pattern for a
micellar-polymer EOR operation.  In this particular operation, a reservoir
preflush was first used to  condition the reservoir followed by the micellar
fluid for releasing oil, polymer solution for mobility control, a fresh water
buffer to protect the polymer, and  the final drive injection water.
    Surfactant-polymer floods are chemical EOR processes.  Surfactants are
micellar or surface-active  agents including soaps and soap-like substances.
To be useful in enhanced oil recovery, they must reduce the interfacial
tension between water and oil.  They have an amphiphilic molecule that is
attracted, at one end, to water (the hydrophilic or water-loving end), and the
other end is attracted to oil (the oleophilic or oil-loving end).
    Alcohol  improves the quality of some micellar solutions and, when used, is
a cosurfactant.  The cosurfactant also aids the micelle in solubilizing oil or
water, stabilizes the solution, and reduces adsorption.
                                   -101-

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    The water-soluble polymers used in EOR consist of chain-like molecules
with molecular weights up to or exceeding 20 million.  Polymers such as
polyacrylamides and polysaccharides often are used as mobility-control buffers
for permeability reduction and/or increased viscosity.  Polysaccharides
sometimes are called biopolymers.  Polymers increase the viscosity of the
waterflood and prevent it from running ahead of the oil.  Increased resistance
to flow, particularly in high permeability zones, improves the volumetric
reservoir sweep efficiency resulting in increased oil recovery.
    Water-soluble synthetic polyacrylamides consist of high-molecular-weight,
chain-like molecules with CONH2, COOH, and COONa groups attached to every
other carbon atom on a carbon chain.  Naturally occurring polysaccharides
consist of cyclic carbohydrate monomers alternating in the polymer
structure.  These additives aid oil recovery by decreasing the floodwater's
mobility.  The polyacrylamides, for example, are most susceptible to breakdown
because of mechanical shear degradation and are more likely to adsorb on clay
or silicate surfaces than the polysaccharides.  However, the fact that the
polysaccharides react with low concentrations of polyvalent cations, react
with bacteria, and in general plug filters or well sand faces because of
numerous reactions gives polyacrylamides a wider acceptance in oil recovery
operations.
    In many of the surfactant-polymer EOR operations, a preflush is used.
This preflush often consists of fresh water to which sodium chloride is
added.  More specifically, it probably will consist of fresh water, plus
sodium chloride, plus a bactericide, plus a corrosion inhibitor.  A preflush
may continue for a year or until 80% of the rock pore volume (PV) is
flushed.  The purpose of the preflush is to remove the connate brine from the
area of the reservoir where the operator wants to form an oil bank.  After
                                     -102-

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completion of the preflush, the sulfonate solution is injected.  The preflush
theoretically removes most of the divalent ion cations (calcium and magnesium)
that were in the connate brine.  These divalent cations react with many
sulfonates causing them to precipitate or become inactive or useless in the
entrainment or entrapment of the oil phase.
    Other constituents in this surfactant or micelle phase may be sodium
hydroxide, sodium chloride, polymer, crude oil, and, of course, fresh water.
The polymer is added to increase the viscosity of the solution.  Sodium
hydroxide, if used, may aid in forming a multiphase microemulsion system.  The
microemulsion has at least three components: oil, water, and surfactant,
Collins and Kayser (1985).
    Much of the preliminary work on an EOR operation is conducted to determine
possible interactions and compatibilities of injected fluids with the
indigenous reservoir fluids and rocks.  This work is performed to minimize
losses of the injected solutions because of incompatible reactions with the
reservoir fluids and rocks and to ensure maximum oil recovery per dollar value
of injected chemical.
POLYMER
    Figure 5 illustrates a single 5-spot injection-production pattern for a
polymer EOR operation.  As shown, a preflush was performed to condition the
reservoir.  This was followed by an injection of polymer solution primarily
for improved mobility control and an improved volumetric sweeping of oil
through the reservoir.  Next, a fresh water buffer was injected to protect the
polymer followed by injected drive water.
    A polymer operation is similar to a surfactant-polymer operation.  The
notable exception is that the surfactant phase is not injected.  The polymer
phase only is used; therefore, it might be called a thickened or polymer-
                                    -103-

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augmented waterflood.  The polymer increases the mobility ratio of the flood
and tends to move more oil without allowing the flood to finger through the
oil.
    A preflush usually is used.  Fresh water is used in many of the preflushes
—  in the polymer phase and in the first drive water phase.  Brine-tolerant
polymers will decrease the necessity of using fresh water.  Many polymers
react with divalent cations such as calcium and magnesium.
ALKALINE
    Figure 6 illustrates a single 5-spot injection-production pattern for an
alkaline EOR operation.  As shown, a preflush of the reservoir is used to
condition the reservoir followed by an injection of an alkaline or
alkaline/polymer solution to form surfactants in situ to release oil from the
reservoir rock.  Next, a solution of polymer is injected for mobility
control.  Then injection of fresh water buffer to protect the polymer is
followed by injection of the driving fluid (water).
    In general, an alkaline (caustic) flood is performed only in a sandstone
reservoir because of the abundance of calcium in a carbonate reservoir
brine.  The most common chemical used in caustic flooding is sodium
hydroxide.  Sodium orthosilicate and sodium carbonate are also used.  Other
chemicals that have been used include ammonium hydroxide, potassium hydroxide,
sodium silicate, trisodium phosphate, and polyethylenimine.  Since cost is
important, sodium hydroxide is more likely to be used than potassium
hydroxide.
    Divalent cations such as calcium and magnesium in the connate water can
deplete a caustic slug by precipitation of hydroxides.  Also, if anhydrite or
gypsum are in the rock, calcium will  react with the slug to precipitate
calcium hydroxide.   High ion-exchange-capacity clays will exchange hydrogen
                                    -104-

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for sodium rendering the caustic slug ineffective by producing water and tying
up the sodium.  Caustic usually reacts with the silica in sandstone too slowly
to cause problems.  Most dolomites and limestones will not react with the
caustic to cause deleterious effects.
    Krumrine, et al. (1982) reported on the effects that alkaline additives
have on dilute surfactant systems for low-tension waterflooding and how
interfacial tension, hardness removal, and surfactant retention affect oil
recovery in high-hardness core systems.  They also examined the effects of
alkaline additives on dilute surfactant systems for improved oil recovery.
CARBON DIOXIDE
    Figure 7 illustrates the carbon dioxide oil flooding process, a miscible
displacement process applicable to many reservoirs.  A slug or a prescribed
amount of carbon dioxide is injected into the reservoir followed by an
injection of water and a subsequent injection of carbon dioxide.
    Most C02 floods uses a water-injection phase as a preflush and as a water-
alternating-gas injection (WAG).  For example, the preflush may be a fresh
water to which salt is added or it may be a softened salt water.  In some
areas softened seawater is used.
    At least four methods of carbon dioxide and water injection have been
studied or used:  (1) continuous injection of carbon dioxide for the life of
the flood, (2) injection of carbon dioxide followed by water, (3) injection of
alternate slugs of carbon dioxide and water, and (4) simultaneous injection of
carbon dioxide and water.  The water in some field applications consists of
polymer-thickened water.  Carbon dioxide floods are useful  in both carbonate
and sandstone reservoirs.
    The depth of the reservoir should be 2,500 ft or more.   If it is not, the
overlying rock may be fractured.  If the pressure in the reservoir containing
                                    -105-

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an oil of 30° API gravity or greater has been depleted to  less than  1,200  psi,
the pressure must be built up by injection of water before the C02 injection
begins.  Of course, C02 could be injected to build up the pressure—  but this
would be very expensive at the current prices for C02«
STEAM
    Figure 8 illustrates a steamflcoding operation.  Heat from steam  injected
into a heavy-oil reservoir thins the oil making it easier to push through  the
formation toward production wells.  Steam and hot water flooding account for
most of the oil recovered by all EOR operations.  There are two steam recovery
processes:  (1) steam stimulation, sometimes called cyclic steam injection,
steam soak, or huff and puff and  (2) steamflooding which is a process similar
to waterflcoding.  Water used in a steamflood usually is a high quality water
and usually is softened before it goes into the steam generator to prevent
scale problems in the boiler.  Steamflooding accounts for the most oil
recovered by any EOR technology.
IN SITU COMBUSTION
    Figure 9 illustrates an in situ combustion operation where heat is used to
thin the oil and thereby permit it to flow to the production well.  In this
operation, the oil in the formation is ignited, and by continued injection of
air the fireflood front advances through the reservoir.
    There are two fundamental processes of in situ combustion -- forward
combustion and reverse combustion.  Water is used in variations of the forward
combustion process.  When water is injected with air, it forms superheated
steam near the injection well.  At the combustion front, it mixes with
nitrogen,  carbon monoxide, carbon dioxide, and other gases.  This hot gas
mixture displaces the oil.  Heat reduces the viscosity of the oil allowing the
                                    -106-

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oil to flow toward the production well.  The benefit of the wet method is that
it allows a threefold reduction in air to produce a barrel of oil.
MISCIBLE HYDROCARBON
    As the name of the flood implies, the injected gas or liquid hydrocarbon
becomes miscible with the hydrocarbons in the reservoir.  This miscibility
usually is accomplished at elevated temperatures and pressures; therefore,
depth of the reservoir is important because of the need to maintain a high
pressure.
    Three different techniques are commonly used:  (1) miscible slug process,
whereby a slug of liquid hydrocarbon about 0.05 PV is injected followed by gas
and water as the drivers; (2) enriched gas process, whereby a slug of enriched
gas is injected followed by lean gas and water as the driver; and (3) high-
pressure, lean-gas process, whereby lean gas is injected at high pressure to
cause evaporation of the crude oil and formation of a miscible phase.
INERT GAS INJECTION
    Increased costs of natural gas and carbon dioxide have prompted operators
to look at other methods to maintain the pressure in petroleum reservoirs.
With natural gas, miscibility could be achieved in some reservoirs.  The
miscibility state allows almost 100% displacement efficiency in the swept
zone; however, this is not always the goal.   Often pressure maintenance is the
goal.
    Figure 10 illustrates the use of nitrogen in a carbon dioxide flood
operation where the nitrogen is used for economic reasons.  Inert gases such
as nitrogen are not miscible with many oils at low pressures.  Also, the API
gravity of the oil should be 35° or higher for application of this process.
                                    -107-

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MICROBIAL FLOODING
    Microbial flooding is performed by injecting a solution of microorganisms
and a nutrient such as industrial molasses down injection wells drilled  into
an oil-bearing reservoir.  As the microorganisms feed on the nutrient, they
metabolically produce products ranging from acids and surfactants to certain
gases such as hydrogen and carbon dixoide.  These products act upon the  oil in
place in a variety of ways, making it easier to move the oil through the
reservoir to production wells.
    The microbial and nutrient solution and the resulting bank of oil and
products are moved through the reservoir by means of drive water injected
behind them, as  illustrated in Figure 11.

CYCLIC MICROBIAL RECOVERY
    This well-stimulation method is one of the newest EOR methods and requires
the injection of a solution of microorganisms and nutrients down a well  into
an oil reservoir.  This injection can usually be performed in a matter of
hours, depending on the depth and permeability of the oil-bearing formation.
Once injection is accomplished, the injection well is shut in for days to
weeks.  During this time, known as an incubation or soak period, the
microorganisms feed on the nutrients provided and multiply in number.  These
microorganisms produce products metabolically that affect the oil in place in
ways that make it easier to produce.  Depending on the microorganisms used,
these products may be acids, surfactants, and certain gases, most notably
hydrogen and carbon dioxide.
    At the end of this period, the well is opened, and the oil and products
resulting from this process are produced.
    This method eliminates the need for continual injection, but after the
                                     -108-

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production phase is completed a new supply of microorganisms and nutrients
must be injected if the process is to be repeated.  Figure 12 illustrates the
process.

QUANTITY OF CHEMICALS USED  IN EOR
    In general, a micellar  injection is in the range of 5-20% pore volume
(PV), with 5-20% of the injection slug containing sulfonate and 1-20% of the
injection containing alcohol.  Polymer injections vary greatly, ranging in the
area of 25-75% PV, depending on polymer concentration, and tapered to lower
concentrations as injection progresses.  For better economics, efforts are
being made to lower the amounts of chemicals used, and, in fact, no new
micellar-polymer field operations were started in the past 2 years.
    Alkaline operations inject 15-40% PV caustic slugs composed of less than
2% caustic compounds, such as NaOH and sodium orthosilicate.  Biocides are
added to the surfactant slug if it is biochemically unstable; however, they
normally are injected with the polymer injection.  Concentrations used are in
the order of 10-150 ppm, and the volume injected is less than 1% of the
injection.
    Silvestro and Desmarais (1980) divided EOR chemicals into five functional
groups as shown in table 3 and below:
    1.  Mobility Control Agents (Polymers)
    In general, these are considered to be low in toxicity; many of them are
used in small amounts as food and drug additives or constituents of food
packaging.  The main hazards from polymers are associated with on-site
handling and dispensing.
    Degradation products of polyacrylamide and polysaccharide polymers are
generally smaller fragments of the respective polymer.  In the cases of
                                    -109-

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polysaccharides, the degradation products are ultimately the monomers often
used in synthesizing the polymer.  Polysaccharides are hydrolyzed at the ring-
ester linkages to form simpler sugars, while polyacrylamides tend to be
hydrolyzed at the amide linkage and form a low-viscosity polymer with reduced
mobility control properties.  The alkylcellulose ethers degrade to simpler
starches, sometimes hydrolyzing at available linkages under higher-pH
conditions.  It is unlikely that toxic hazards should be expected from any of
these degradation products.
    2.  Cosurfactants
    Cosurfactants are generally used in relatively small amounts.  They are
composed primarily of longer chain aliphatic alcohols whose hazards have been
well documented through industrial usage and are not expected to cause
environmental problems in EOR projects.
    3.  Alkaline Flooding Agents, Preflush Agents, Thermal Enhancers
    Some of the compounds in this group are quite caustic and require
conscientious handling (sodium hydroxide, sodium orthosilicate); others are
organics with relatively high toxicity levels or carcinogenic potential
(hydrazine, quinoline).  The sodium compounds are generally considered safe in
the diluted amounts used in EOR; little is known about the safety of on-site
disposition of the organic compounds used.
    4.  Surfactants
    Recent standards established within the United States consider up to 0.5
mg surfactant per liter of water as being safe for human purposes.  Although
alkylaryl  and petroleum sulfonates are minor irritants to eyes and skin,
systemic chronic effects and toxicological data are not generally known.   The
high toxicity of sulfonates to aquatic life may be an indicator of toxic
potential.   Incomplete degradation of alkylbenzene sulfonates does occur in
                                    -HO-

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the environment, possibly introducing free benzene rings into the formation or
a surface disposal site.
    5.  Biocldes, Chelatlng Agents, Oxygen Scavengers
    The biocides are moderate to severe irritants, particularly to eyes, skin,
and upon inhalation.  Certain ones, such as acrolein, glutaraldehyde,
formaldehyde, pentachlorophenol (PCP), and 2,4,5-trichlorophenol, are
extremely toxic over short exposure periods.  Bioaccumulation is high, and all
five are implicated as carcinogens.  Pentachlorophenol and 2,4,5-
trichlorophenol contain contaminants (dioxin, chloroquinone,
tetrachlorobenzene) which may be more toxic than the pure compound.
                              TRANSPORT AND FATE
    Physical, chemical, and microbiological processes affect the transport and
fate of fluids injected into subsurface reservoirs.  Geohydrology provides a
quantitative understanding of the flow of fluids through the subsurface, and
as a discipline it includes the mathematical, chemical, geological, and
physical sciences.  Although many methods are available to aid in solving
mathematical problems associated with flow, transport, and fate of injectants
into subsurface reservoirs, many of the problems require further study, and
new methods need to be developed and tested.
                                 CONCLUSIONS
    Water is important in petroleum recovery operations.  Adequate
considerations should be given to the type, quality, and quantity of water
available.   Necessary tests should be made to ensure that the water used is
compatible  with the recovery technology planned and the reservoir rock and
associated  indigenous fluids.   After the recovery operation is begun,
necessary tests should be conducted on a routine basis to ensure that the
system is maintained at optimum conditions.
                                    -ill-

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    Knowledge of abiotic and biodegradation transformations and mobility
pathways in soils, surface waters, and groundwaters for many chemicals used in
petroleum recovery is nonexistent.  Better information concerning abiotic and
biodegradation transformations, transport, and ultimate fate of EOR chemicals
and their by-products in soils and waters should be obtained for (1) mobility
control agents, (2) cosurfactants, (3) surfactants, (4) alkaline flooding
agents, (5) preflush agents, (6) thermal enhancers, (7) biocides, (8) chelat-
ing agents, (9) oxygen scavengers, (10) solid wastes from steamfloods, and
(11) potentially dangerous chemicals used in any EOR operation.
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                                  REFERENCES
    American Society for Testing and Materials  (ASTM), 1985, Philadelphia, PA.
Standard Practice for Calculation of Supersaturation of Barium Sulfate,
Strontium Sulfate.  Dihydrate  (Gypsum)  in Brackish Water, Sea Water, and
Brines, Section 11, volume 11.02, pp. 551-556.
    Carl berg, B. L.  1979, How to Treat Seawater for Injection Projects.
World Oil, v. 189, No. 1, pp. 78-81.
    Collins, A. 6.  1975, Geochemistry of Oilfield Waters.  Elsevier
Scientific Publishing Co.  New York, 496 pp..
    Collins, A. G. and M. B. Kayser.  1985, Interaction, Compatibilities, and
Long-Term Environmental Fate of Deep-Well-Injected EOR Fluids and/or Waste
Fluids with Reservoir Fluids and Rocks - State-of-the-Art, Oept. of Energy
Report No. NIPER-70, NTIS Order No. DE85000146, 103 p.
    Collins, A. G. and C. C. Wright.  1982, Enhanced Oil Recovery Injection
Waters.  Dept. of Energy Report. No. DOE/BETC/RI-82/5, Apr., 82 pp.
    Craig, F. F., Jr.  1971, The Reservoir Engineering Aspects of
Waterflcoding, Society of Petroleum Engineers, Morgraphy Series 3: 134 pp.
    Davis, J.  1974, Big Waterflood Begins Off Abu Dhabi.  Oil and Gas
Journal, v. 73, No. 33, pp. 49-51.
    Fekete, T.  1959, The Plugging Effect of Bacteria in Sandstone Systems.
M.S. Thesis, University of Alberta Canada, 1959.
    Goodlett, G. 0., M. M. Honarpour, H. B. Carroll, P. S. Sarathi.  1986,
Screening for EOR - 4 Parts, Oil and Gas Journal, June 23, 1986 ending July
28, 1986.
    Henkel, H. 0.   1953, Surface and Underground Disposal of Chemical  Wastes
at Victoria, Texas.  Sewage and Industrial Wastes.  Chemical Engineering
Progress, v. 25, No. 9., pp. 1044-1049.
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    Henkel, H. 0.  1955, Deep-Well Disposal of Chemical Wastes.   Chemical
Engineering Progress, v. 51, No. 12, pp. 551-554.
    Jorque, M. A.  1984, How to Treat Seawater for Water  Injection,  Petroleum
Engineer, Nov. 28-34.
    Krumrine, P. H., J. Falcone, and T. Campbell.  1982,  Surfactant  Flooding
2: The  Effect of Alkaline Additives on Permeability and Sweep  Efficiency.
Society of Petroleum Engineers Journal, v. 22, No. 6, pp. 983-992.
    Langnes, G. L. Robertson, J. 0. Jr., Mehdizadeh, A.,  Torabzadeh, J., Yen,
T. F.,  Donaldson, E. C., and Chilingarian, G. V.  1985, Waterflcoding, Ch. 8
in Enhanced Oil Recovery, 1. Fundamentals and Analysis, Elsevier, p. 251-334.
    McCune, C. C.  1977, On-Site Technology to Define Injection Water Quality
Requirements.  Journal of Petroleum Technology, v. 1, pp. 17-24.
    Meister, M. J., C. A. Wilson, and A. G. Collins  1980, Tolerance of
Petroleum Sulfonates to the Presence of Calcium Ions, Chapter  in  Solution
Chemistry of Surfactants, Plenum Press, pp 927-940.
    Mitchell, R. W. 1978,  The Forties Field Sea-Water Injection  System.
Journal of Petroleum Technology, v. 30, pp. 877-884.
    Mitchell, R. W. and T. M. Finch  1978, Water Quality  Aspects  of North Sea
Injection Water, Society of Petroleum Engineers, (UK) LTD Europe  Offshore
Petroleum Conference, Proceedings, v. 1, pp. 263-276.
    Mungan, N.  1965, Permeability Reduction Through Changes in pH and
Salinity.  Journal of Petroleum Technology, v. 12, pp. 1449.
    Ogletree, J. 0. and R. J. Overly  1973, Sea-Water and Subsurface Water
Injection in West Block 73 Waterflood Operation.  Journal of Petroleum
Technology, v. 25, pp. 623-628.
    Ostroff,  A.  G.  1979, Introduction to Oilfield Water  Technology, National
Association of Corrosion Engineers, 394 p.
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    Patton, C. C.  1975, Oilfield Water Systems.  Campbell  Petroleum Series,
Norman, OK, 65 p.
    White, A. F. and J. M. Delany  1982, Investigation of Surface Interactions
Between Silicate Rocks, Minerals, and Groundwater.  Annual  Report, Earth
Sciences Division, Lawrence Berkeley Laboratory, LBL-15500, pp. 112-115.
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                     TABLE  1.  -  Geochemical  water analyses
Property
or
Constituent
PH
Eh
Specific resistivity
Specific gravity
Bacteria
Barium
Bicarbonate
Boron
Bromide
Calcium
Carbonate
Carbon dioxide
Chloride
Hydrogen sulfide
Iodide
Iron
Magnesium
Manganese
Oxygen
Potassium
Residual hydrocarbons
Sodium
Silica
Strontium
Sulfate
Suspended solids
Total dissolved solids
Produced
Water
X
0
X
X
0
X
X
0
0
X
X
0
X
0
0
X
X
0
0
0

X
0
0
X

X
Injection
Water
X
X

X
X
X
X


X
X
X
X
X

X
X
0
X

X
0
X
X
X
X
X
Steam
Generation
Water
X


X


X


X
X
X
X


X
X
0
0


0
X
0
X

X
Disposal
Water
X
0

X
0
X
X


X
X
0
X
0

0
X
0
0

0
0
0
0
X
X
X
X usually requested
o sometimes requested
                                    -116-

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TABLE 2. - Tertiary system - highest concentration of a
           constituent found, average concentration, and
           number of samples analyzed - Collins (1975)
Constituent
Lithium
Sodium
Potassium
Rubidium
Cesium
Calcium
Magnesium
Strontium
Barium
Boron
Copper
Chloride
Bromide
Iodide
Bicarbonate
Carbonate
Sulfate
Organic Acid as acetic
Ammonium
Concentration
highest
27
103,000
1,200
0.6
0.4
38,800
5,800
420
240
450
1
201,300
1,300
35
3,600
300
8,400
1,900
2,700
(mg/1)
average
4
39,000
220
0.24
0.20
2,530
530
130
60
36
0.63
64,600
85
28
560
75
320
140
230
Number of samples
169
379
176
11
9
376
368
142
140
170
3
380
323
322
364
8
139
53
64
                            -117-

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                         TABLE  3.  -  Toxicological  Data



                Survey Chemicals  Arranged by General  Use In EOR



                   (Reference Silvestro and Desmarais, 1980)
Group I       Mobility Control Agents
              Polyacrylamides
              Xanthan gums
              Carboxymethylcellulose
              Hydroxyethy1 eel 1ulose
              Polyethylene glycol monobutyl ether
              Polyethylene oxide

Group II      Cosurfactants
              1-hexanol           2-hexanol
              1-octanol
              2-octanol
              n-butanol (and tert-, sec-, iso-isomers)
              Cyclohexanol
              Polyethoxyalkylphenol

Group III     Blocides, Chelating AGents, Oxygen Scavengers
              Quaternary ammonium chloride
              2,4,5-trichorophenol
              Pentachlorophenol
              Phenol
              2,2-dibromo-3-nitrilopropionamide
              Copper sulfate
              Glutaraldehyde
              Formaldehyde
              Sodium hypochlorite
              Acrolein
              EDTA
              1,6-hexanediamine

Group IV      Surfactants
              Alky aryl sulfonates
                   e.g.,  Alkyl benzene sulfonate
                          Octadecyltoluene sulfonate
                          Tridecyl benzyl sulfonate
                          Decyl benzyl sulfonate
                          Alkyl naphthenic sulfonates
              Petroleum sulfonates (toxicity as groups)
                                   -118-

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Group V       Alkaline Flooding Agents. Preflush Agents. Thermal  Enhancers
              Sodium nitrate
              Sodium hydroxide
              Sodium orthosilicate
              Sodium carbonate
              Sodium borate
              Sodium hydrosulflte
              Sodium bisulfite
              Sodium sulfate
              Hydrazlne
              Qu1nol1ne
              Toluene
              Xyl1d1ne
              Aniline*            2,2-d1bromo-3-nitr1loprop1onam1de
              Copper sulfate
              Glutaraldehyde
              Formaldehyde
              Sodium hypochlorite
              Acrolein
              EDTA
              1,6-hexanedlamine
                                   -119-

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                                                                    FIGURE  1
K!
O
 I
                                                            OIL  PRODUCTION
                                                     Improved technology through research is
                                                              enhancing oil recovery.
                 PRIMARY RECOVERY
                  Produces  12-15% of the
                    original  oil-in-place*
                                     SECONDARY RECOVERY
                                        Another 15-20% of the
                                      original oil-in-place* may be
                                       produced by waterflooding
     ENHANCED OIL RECOVERY (EOR)
An additional 4-11% of the original oil-in-place* may be
  produced using current and advanced technology
                                                                                                                      ADVANCED PROCESSES
                                                                                                                       • Improved Mobility
                                                                                                                         Control
                                                                                                                       • Deep Steam
                                                                                                                       • Microbial
                                                                                                                            y Mining
                              y^&ZKvmK*!

                                                        Approximately 65% (300 billion bbls)
                                                         of original oil in place* still locked
                                                          in earth after secondary recovery
Approximately 460 billion bbl of
 oil estimated to be in place
   before any production


-------
       31,000
       30,000 -
       7,000 r
       6,000
            1975    76    77    78     79     80
                            YEAR
FIGURE  2. - Crude oil and water produced (x 1,000 barrels

           per day) from wells in 14 states including

           Alaska (Collins and Wright, 1982).
                       -121-

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    3 1,000
    30,000
    29,000 -
Q   28,000 -
CD
CD
 ;  27,000 -
Q
O
OC.
    26,000 -
    25,000 -
     7,000 -
     6,000 -
     5,000
-   (EXCLUDING ALASKA)
 FIGURE 3. - Crude oil and water produced (X 1,000 barrels

           per day) from wells in 13  states excluding

           Alaska  (Collins and Wright, 1982).
                        -122-

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                                                           FIGURE 4

                                                  CHEMICAL FLOODING
                                                      (Micellar-Polymer)
                       The method shown requires a preflush to condition the reservoir, the injection of a micellar
                     fluid for releasing oil, followed by a polymer solution for mobility control to minimize channeling,
                       and a driving fluid  (water) to move the chemicals and resulting oil bank to production wells.

                                                                            (Single 5-Spot Pattern Shown)
ro
t_o
I
                                                                      Additional
                                                                         Oil
                                                                      Recovery
                                                                      (Oil Bank)
 Preflush
to Condition
 Reservoir

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                                        FIGURE 5
                               CHEMICAL FLOODING
                                        (Polymer)
The method shown requires a preflush to condition the reservoir, the injection of a polymer
   solution for mobility control to minimize channeling, and a driving fluid (water) to move
              the polymer solution and resulting oil bank to production wells.
   Mobility ratio is improved and flow through more permeable
   channels is reduced, resulting in increased volumetric sweep.
                                        (Single 5-Spot Pattern Shown)
                                  Production Well
                                  Polymer
                                  Solution
                                    For
                                  Mobility
                                  Control
 Fresh
 Water
 Buffer
to Protect
 Polymer
Additional
  Oil
Recovery
(Oil Bank)
 Preflush
to Condition
 Reservoir
Driving
 Fluid
(Water)

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                                          FIGURE  6
                                CHEMICAL FLOODING
                                          (Alkaline)
The method shown requires a preflush to condition the reservoir and injection of an alkaline
  or alkaline/polymer solution that forms surfactants in situ for releasing oil. This is followed
 by a polymer solution for mobility control and a driving fluid (water) to move the chemicals
                           and resulting oil bank to production wells.
  Mobility ratio is improved, and the flow of iiquids through
   more permeable channels is reduced by the polymer
     solution resulting in increased volumetric sweeo.
         (Single 5-Spot Pattern Shown)
                                   Production Well
                                           Alkaline
                                           Solution
                                            Forms
                                          Surfactants
                                          In Situ For
                                          Releasing
                                             Oil
Additional
  Oil
Recovery
(Oil Bank)
 Preflush
to Condition
 Reservior

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                                                  FIGURE 7
                                   CARBON DIOXIDE FLOODING
           This method is a miscible displacement process applicable to many reservoirs. A CO2 slug followed
                   by alternate water and CO2 injections (WAG) is usually the most feasible method.
                             Viscosity of oil is reduced providing more efficient miscible displacement.
I
I—»
hO

I
                                         Produced Fluids (Oil. Gas and Water)
                                          Separation and Storage Facilities

-------
I
t—»
N5

I
                                                      FIGURE 8
                                              STEAM FLOODING
                     Heat, from steam injected into a heavy-oil reservoir, thins the oil making it easier
                       for the steam to push the oil through the formation toward production wells.
                                       Heat reduces viscosity of oil and increases its mobility.
                                          Production Fluids (Oil, Gas and Water)
                                            Separation and Storage Facilities
^W&^W^-^c®
•^MMc^'^P^^^df
aaaiafcQ^y-»y-csfa»;Yvffq-B?-^


                                                                              Oil and
                                                                            Water Zone
                                                                            Near Original
                                                                             Reservoir
                                                                            Temperature
                                  Steam and
                                Condensed Water

-------
OO
I
                                                  FIGURE 9
                                        IN-SITU COMBUSTION
            Heat is used to thin the oil and permit it to flow more easily toward production wells. In a fireflood,
         the formation is ignited, and by continued injection of air, a fire front is advanced through the reservoir.
                    Mobility of oil is increased by reduced viscosity caused by heat and solution of combustion gases.

J-^J
-r-1-
^
^F
L-r-L .-'I , 1 |
1 ' 1 '"I
T - 1
L-rr-^r^
1 	 ^~1 — 	 '
E^3
r-^-T-i-
i 	 '
1
i — '
1
r-1-
r-J-r-J
| 	 ' 	 1 	 ' 	 1 	 ' 	 1 	 1 	 ' 	 1 	 ' 	 T^1 	 1 	 ' 	 1
. 1. Injected Air and Water Zone (Burned Out)
2. Air and Vaporized Water Zone
3. Burning Front and Combustion Zone (600
^— 4. Steam or Vaporizing Zone (Approx. 400CF
I
i 	
1
,° .
:)
[ — — c~
i — i — i-
1200°F)

-i — '
5,
6
7
i ' i '", •' i H
r^-r-
L-i
L 	 1 	 1 	 , 	 1 	 1 	 1 	 1 	 1 	 1 	 ' 	 1 	 •
. Condensing or Hot Water Zone
(50° - 200°F Above Initial Temperat
. Oil Bank (Near Initial Temperature
. Cold Combustion Gases
1 l ' I i-T-^
i
ure) J
) -
~r — i — ' — j — "~
L-r-1 ! ' 1 ' '
L^~l l ' ! '
H^ . ' . '
[ • -r 1 , 1 ,1-

-------
                                 FIGURE  10
                     NITROGEN — CO2 FLOODING
  In a CO2 flood, the use of nitrogen to displace the C02 slug and its miscible oil bank
               might be desirable due to the lower cost of the nitrogen.
Viscosity of oil is reduced providing more
efficient miscible displacement.
                                                            Produced Fluids (Oil, Gas and Water)
                                                             Separation and Storage Facilities
                '	\	1	1	1	1	*	1	^

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u>
o
I
                                                       FIGURE 11

                                            MICROBIAL FLOODING
              Recovery by this method utilizes the effect of microbial solutions on a reservoir. The reservoir is usually
               conditioned by a water preflush, then a solution of microorganisms and nutrients is injected. As this
               solution is pushed through the reservoir by drive water, it forms gases and surfactants that help to
               mobilize the oil. The resulting oil and product solution is then pumped out through production wells.
                                                                       (Single 5-Spot Pattern Shown)
                Microorganisms
                 and Nutrients

-------
                                                      FIGURE 12

                                     CYCLIC MICROBIAL RECOVERY
                  A solution of microorganisms and nutrients is introduced into an oil reservoir during injection.
                 The injection well is then shut in for an incubation period allowing the microorganisms to produce
                  carbon dioxide gas and surfactants that help to mobilize the oil. The well is then opened and oil
                    and products resulting from the treatment are produced. This process may be repeated.
                                       Schematic portrays one well during the 3 phases of this
                                            process. Flow pattern is stylized for clarity.
                                                  INCUBATION (Shut-in Phase)                    PRODUCTION
                                                       Days to Weeks                        Weeks to Months
INJECTION
  Hours
LO
i—'
I
                            Microorganisms
                             and Nutrients
                                                                                                           K
                                                                                                  Produced Oil\
                                                                                                  and Products/
   ^  I   I    I
                                                                                                      Depleted
                                                                                                      Oil Sand
           Injected Microorganisms
               and Nutrients
                                 Metabolic Activity Produces
                                    CO2 and Surfactants

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           PAPER UNAVAILABLE.  WILL BE PRINTED IN UIPC JOURNAL.
                          ABSTRACT

      Oilfield Brine Disposal into the Wilcox Aquifers
            in S.E. Mississippi - A Case History

                           Author

                         Lee Thomas
            U.S. EPA Region IV, Atlanta, Georgia
Since the 1940's oilfield brines have been disposed  of  by
injection into the Wilcox Aquifers  in Clarke,  Jones,  Jasper,
Wayne and Smith counties in Mississippi.  When the
regulations for the Safe Drinking Water Act were  promulgated
it was required that any aquifer with less than 10,000  m/g
per litre total dissolved solids be protected.  Regional
studies for these counties subsequent to  the  promulgation  of
the UIC regulations indicated that  the Wilcox  Aquifers  in
these counties contained less than  10,000 m/g  per  litre total
dissolved solids.  In order to  insure that injection did not
endanger any protected aquifer, the Environmental  Protection
Agency requested that all owners of Wilcox disposal  wells  in
this area submit permit applications.  To evaluate  these
permit applications it was necessary to give  careful
consideration to the hydrogeology in this area.   Each permit;
application was evaluated with  respect to the  injection
aquifer using geophysical logs  since water samples  showing
ambiant conditions were generally not available.   In many
permit applications the actual  injection  sand  was  shown to  be
less than 10,000 m/g per litre  total dissolved solids.   In
other permit applications a Wilcox  aquifer contained
protected waters in its upper section and injection  was into
a lower sand with greater than  10,000 m/g per  litre  total
dissolved solids water.  The issue  in these permit
applications became whether adequate confining layers existed
within a specific Wilcox aquifer.   In order to provide
confinement a zone must extend  continuously ton enough  in  all
directions so that it is beyond the zone  of endangering
influence, it must be between the injection zone  and the
lowest protected water, it must have sufficiently low
hydraulic conductivity to preclude  migration  of injection
fluid or formation fluid into protected sands. Determining
whether Wilcox injection might  cause endangerment  of
protected water required an understanding of  the  complex
ge;ology and hydrogeology of the Wilcox aquifers in this area.

                            -132-

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                     BIOGRAPHICAL SKETCH


Lee Thomas
Lee Thomas has 7 years professional experience as  a
Geologist.  He is presently with  the Underground  Injection
Control Section, Ground Water Protection  Branch,  U.S.  EPA
tiegion IV in Atlanta, Georgia.  He has a  Bachelor  of  Arts in
Geology from the University of  Tennessee  at  Chattanooga.   A
Master of Science in Geology  from Memphis State University.
He is presently attending  Georgia State University doing
graduate study in Hydrogeology-
                            -133-

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MECHANICAL CONSIDERATIONS OF THE DISPOSAL OF  FLUIDS  INTO  POORLY
CONSOLIDATED SANDSTONE RESERVOIRS

by J.G. Roberts and R.F. Stiles, Completion Services,  Inc
ABSTRACT
This paper discusses the mechanical aspects of disposing fluids into a
poorly consolidated sandstone formation. In certain areas of the U.S.
unconsolidated or poorly consolidated formations are prevalent and the
injection of  fluids into these strata require specific mechanical
considerations in the injection well design. Among the most of
important of  these considerations are the perforating program, gravel
pack design and maintenance of the wellbore environment. Each of these
items are discussed in detail and a recommended procedure is
presented.

In order to see the impact of these items on the pressure/rate
relationship, a theoretical model is used to calculate the effect of
changing these design considerations. This work shows the importance
of proper well design in minimizing the pressure drop across the final
wellbore completion.

INTRODUCTION
The disposal of fluids into an underground strata has been used
extensively in the waste industry for several years. The technology
for these applications originally came from the oil and gas industry
however have been modified to meet the specific requirements of
disposal projects. The systems and procedures necessary to implement
these projects are complex and can involve a variety of different
disciplines.
                                -134-

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In certain areas  of  the  country  the"construction of these injection
systems are  further  complicated  by  the type of strata underlying the
region, in these  areas,  the  formations that are available for waste
injection consist of unconsolidated or poorly consolidated sandstone
reservoirs.  Injecting fluids into these  formations theoretically does
not present  a problem because  of the direction of flow. In practice
however the  actual operation of  the entire injection system creates
situations in which  the  unconsolidated formation sand may fall into
the wellbore area. A pressure  surge caused by an emergency shut-down
system, fluctuation  of injection rates and pressures, operator error
and so forth all  may allow the introduction of formation sand into the
wellbore. This  formation sand  can lead to an increase in injection
pressures and ultimately total failure of the injection well.
                l
As a method  of  controlling this  problem  a variety of different sand
control techniques have  been tried. The  sand control system that has
produced the best results in both injection well technology as well as
in producing wells is gravel packing. Gravel packing involves the
placement of a  wire-wrapped  screen  or slotted liner across from the
injection interval and packing the  screen-casing annulus with high
quality gravel  pack  sand. This technique, while developed for use in
the oil and  gas industry to  prevent the  production of formation sand,
provides many of  the  same benefits  for injection well applications.
The basic difference  between an  injection well gravel pack and a
producing well  gravel pack is  the final  "direction" of production. The
desired results for  both are the same:
                   1. High volumes of production or injection
                   2. Low pressure drop across the completion
Gravel packing has been proven to be a viable method of controlling
the movement of formation sand from the reservoir into the wellbore
while minimizing the pressure drop across the completion. This process
has steadily improved over the past 50 years to the point that in
certain areas, (Gulf Coast, Florida, California) a majority of the
wells are completed initially using gravel packing as a sand control
measure.
                                 -135-

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The initial success and overall life of the gravel pack is greatly
effected by several factors. These factors include wellbore
maintenance, perforating, and completion design. This paper will
address the design considerations in relation to these factors.
THEORY
Sand problems are most common in younger Tertiary sediments,
particulary of the Miocene epoch. Notable examples are the extensive,
troublesome sand production areas in such sediments in the U.S. Gulf
Coast, the Los Angeles basin of California, and the Florida panhandle.
In other areas, however sand or rock failure can occur in other
formations when local earth stress states and rock strength are
affected by certain completion practices and production operations
that create an unstable condition.

Gravel pack technology has evolved over the past 40-50 years and
developed into a highly specialized service. A gravel pack completion
consists of packing high quality gravel pack sand around a screen or
slotted liner. In addition to packing this screen-casing annulus,
gravel pack sand is also pumped into the perforation tunnels. The
function of the gravel pack sand is to prevent the formation sand from
flowing into the wellbore while at the same time allowing the produced
fluids into the production screen.

The gravel pack sand in the annulus requires the produced or injected
fluid to flow through this sand pack and therefore will increase the
pressure drop across the completion. For this reason high quality sand
is used in gravel packing because its permeability is significantly
higher than the formation sand's permeability. For example, smaller
gravels such as 40-60 U.S. mesh have about 69 darcies of permeability
while others sands such as 20-40 have about 170 darcies. In
comparison, a good Gulf Coast formation sand will have only 500
milli-darcies or 1/2 darcy permeability.

The amount of pressure drop created by the produced or injected fluids
                                -136-

-------
flowing  across  the  gravel  pack  sand  can  be  calculated using Darcy's
law  for  fluid  flow  through a  porous  media.

                               kh  (Pe - Pw)
                    Q -  7.082   	
                               (u  ln(re/rw))
As can be  seen  in the above equation,  the permeability of  the  porous
media has  a  large effect  on the calculated  pressure drop.  In order to
keep the pressure drop  at  a minimum  over the  gravel packed section,
the  permeability of the gravel  pack  sand must be kept at a maximum.
Any  reduction of pack sand permeability  will  cause the pressure  drop
at any specific  flow rate  to  increase.

The  gravel pack  sand must  therefore  be sized  in order to restrain or
bridge the formation sand  while maintaining the highest permeability
possible. When  the  gravel  pack  sand  has  been  correctly sized,  the
formation  sand will bridge exactly at  the gravel pack sand, formation
sand interface.   Since  there  is no migration  of formation  sand into
the  gravel pack,  maximum permeability will  be retained. If any mixing
of the pack  sand and formation  sand  occurs  then the permeability of
the  resultant mix is less  than  either the formation sand or the  gravel
pack sand alone.  This in turn will increase the pressure drop across
the  completion because  of  the  reasons described above.

To further investigate  the pressure  drop across a gravel packed
completion a model  of the  flow  environment must be used. To describe
this flow, three  separate  regions are assumed: Flow through the  sand
packed screen-casing annulus,  flow through the sand packed perforation
tunnels and  flow through the surrounding reservoir. Each of these
areas can be modeled using various flow  equations. In general flow
through the  screen-casing  annulus and flow through the surrounding
formation is described  by  the  radial form of  Darcy's law.  The flow
through the  perforation tunnels, however is described by the linear
form of Darcy's  law.  This  modification of Darcy's general  equation
predicts the pressure drops through  a porous  media where flow is
confined to  a uniform cross-sectional area.

When these equations  are applied to  the  gravel pack model  it can
                                -137-

-------
readily be seen that by far the largest pressure drop occurs in the
perforation tunnel. This indicates that the permeability of the sand
in the perforation tunnel is probably the most important aspect of the
gravel pack. This is why it is so important that gravel pack sand be
packed into both the screen-casing annulus as well as the perforation
tunnels themselves.

The importance of placing high quality gravel pack sand into the
perforations can be illustrated by calculating pressure drops due to
one darcy formation sand filling the perforations. One darcy of
permeability is about twice as much as normally occurs in Gulf Coast
formation sand.  Assuming a flow rate of 1 BPD/perf, the pressure drop
across a 3/8" diameter perf would be 450 psi.  Across a 1/2" diameter
perf the pressure drop would be 190 psi and across the larger 3/4"
perf the pressure drop would be 64 psi.

If the flow rate is increased, the pressure drop in the perforations
will become quite large. Increasing the rate to 10 BPD/perf, the
pressure drop across a 3/8" diameter perforation will be 27,760 psi.
There are no wells in the Gulf of Mexico which are capable of flowing
at this pressure drop.  Even in a 1/2" diameter perforation the
pressure drop will be over 9000 psi.

If these same perforations are filled with a medium permeability 20-40
U.S. mesh gravel, the pressure drops are significantly less. Flowing
at 1 BPD/perf the pressure drop in a 3/8" diameter perf is 2 psi; in a
1/2" diameter perf the pressure drop is 1 psi; and in a 3/4" diameter
perf the pressure drop is 0.4 psi. Increasing the rate to 10 BPD/perf
produces only a 6 psi pressure drop in a 3/4" diameter perforation. As
can be seen, placing high quality sand into the perforation tunnel is
very important in limiting the pressure drop across the completion. A
well that is gravel packed with a high quality gravel can easily flow
at a rate between 50-100 BPD/perf with a relatively small pressure
drop.

The selection of the gravel size needed to restrain sand production
but maximize the permeability of the pack has been an area of debate
for some time. Prior to 1966 up to 30% of the gravel packs performed
                                -138-

-------
resulted  in  failure.   Early  gravel  pack  design was  based  on  the works
of Coberly,  Wagner  and Hill     and  suggested  using  a  gravel  pack  grain
size with  a  diameter  equal  to  10  times  the  formations 10% coarse  point
on a cumulative  sieve analysis.  Formation  sand is made up of several
different  particle  sizes  and some method must be used to  describe the
overall characteristics of  the sample.  A cumulative sieve analysis is
a standard method of  describing these various particle sizes that make
up the formation sand.

In additional work  done by Winterburn   it  was suggested that the
gravel size  determination be based  on the  fines end of the cumulative
sieve analysis.  A finer gravel will naturally impede  the  movement of
formation  sand into the wellbore, however,  lower productivity may
occur as a result of  the  decreased  permeability of  the pack  sand.

In 1974 Saucier  performed a  series  of experiments to  simulate a
perforation  tunnel  .  Part of the  simulated  tunnel was packed with
gravel pack  sand and  the  other part was  packed with formation sand.
By flowing liquid through this model and measuring  the flow  rate,
cross sectional  area  and  pressure drop,  the permeability  of  the sand
in the tunnel could be  calculated using  Darcy's linear flow  equation.

Saucier's  work used the median gravel pack  sand size  to the  median
formation  sand size as  the design criteria.   The median sand size  was
defined as the 50%  point  on  a  cumulative sieve analysis plot.  When
this ratio between  the  formation  sand size  and the  pack sand size  was
6 and the  flow rate was 8.2  BPD/perforation the pressure  drop was  16
psi.  When the flow rate  was increased  to  14  BPD/perforation the
pressure drop increased to 30  psi.   Since both the  flow rate and  the
pressure drop were  increasing  proportionately, the  permeability
remained constant.  The flow rate was then  lowered  back to the
original 8.2 BPD/perforation and  the pressure drop  came back to the
original 16 psi. This  indicated that the permeability remained
constant throughout the experiment  and no damage was  incurred at  the
higher flow  rate.

When the gravel  size was  increased  to 8.5 times the formation sand
size, a higher pressure drop of 54  psi was  obtained with  a lower  flow
                                -139-

-------
rate of 7.7 BPD/perforation. This demonstrates that the permeability
was already being damaged due to formation  sand migration into  the
gravel pack sand. When the  flow rate was doubled to 13.0
BPD/perforation the pressure drop went up by more  than double
indicating that the permeability had been further  damaged.  Finally
when the flow rate was lowered back to the  original 7.7
BPD/perforation the pressure drop was now 94 psi indicating that  the
permeability of the gravel  pack had been permanently damaged.

The results of Saucier's experiments show that as  long as the diameter
ratio between the median pack sand and the  median  formation sand  is
less than 6, none of the formation sand will migrate into the gravel
pack section. This will maintain the permeability  at a maximum  and
provide the minimum pressure drop. Whenever this diameter ratio is
exceeded, the permeability  will begin to drop as formation sand
migrates into the gravel pack.  It will finally reach a point at  about
14 times the diameter where there will be unrestrained formation  sand
production through the gravel pack.

One of the major problems of gravel packing technology prior to the
early 70's was that the permeability of the final  pack was extremely
low. This would create a large pressure drop across the completion and
only highly prolific wells  could produce in this manner. The reasons
for this low pack sand permeability have been identified in the last
several years and can be summarized into three major areas:

         1) Poor quality gravel pack sand
         2) Fluid systems during placement
         3) Placement technique itself

Each of these areas will be covered in the  following sections with
steps and recommendations to minimize any of the above problems.  The
importance of quality gravel packing techniques cannot be over
emphasized. In many cases the results of the gravel packing operation
will determine the success  or failure of the well. While it is
understood that the gravel  packing of a well may represent a major
portion of the total project cost, the incremental costs associated
with performing quality gravel packs are minimal when compared  to the
                                -140-

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cost of well  failure  and  re-completions
Wellbore  Preparation And  Maintenance
Preparation  and  maintenance  of  the wellbore environment is one of the
most critical  steps  in  the implementation of a sand control
completion.  This step begins  with the  choice of completion or workover
fluid. The majority  of  wells  today are  completed using clear water
brines. These  brines are  used because  of their non-formation damaging
characteristics  and  low solids  content. The use of a low solid fluid
is extremely important  in a  gravel packed completion because of the
reduction in permeability that  would result in mixing solids from the
completion fluid with the gravel pack  sand itself.

Clear water  brines are  available in a weights of 8.4 to 19.2 Ibs/gal
For those well not requiring  high density fluids for hydrostatic
control, brines  made of 2% potassium chloride or 3% ammonium chloride
are frequently used.

Frequently the fluids left in the casing prior to the completion
process are  of a different weight and viscosity than the fluids to be
used for the completion or workover. For this reason the casing fluid
must be displaced with  the completion fluid prior to operations
commencing.  It is important  that this operation be carried out
efficiently  in order to insure  that no  fluid or debris will
contaminate  the  clear brine  completion  fluid.

The procedure  to changeover  from drilling mud to completion fluids
depends on mud type, storage  facilities, logistics, and environmental
conditions.  Before displacement of the  drilling fluids begins,  all
surface equipment should  be  thoroughly  cleaned. All circulation during
this procedure should be  in  the reverse circulation mode where fluid
is pumped into the annulus and  returns  taken up the workstring or
drillpipe. This  technique insures maximum turbulence during fluid
circulation  and  more efficient  transport of debris to the surface.
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The following is a general procedure for changeover from drilling
fluids to completion fluids. This process, used by several operators
&11, achieves a clean, closed system in an efficient, and economical
manner:

         1. Run bit and scraper on DP to TVD.
         2. Reverse circulate drilling fluids through surface
            cleaning equipment to remove solids while diverting
            cleaned mud to storage.
         3. Clean all surface lines and tanks with high pressure
            hose.
         4. Make up and store in portable tanks required volume of
            completion fluid.
         5. Prepare and pump the following pills*:
                   a. Spacer containing 2% surfactant
                   b. Caustic wash with 3-5 Ibs caustic per barrel
                   c. Scavenger slurry containing 1 Ib/barrel HEC and
                      25-50 Ibs per barrel sand blast sand
                   d. High viscosity pill containing 3-5 Ibs/bbl HEC
         6. Follow pills with completion fluids
         7. After pills have been reverse circulated to surface
            change to closed system

         *  Pills should be designed for a 10 min. contact time and
            turbulent flow. Do not stop pumping during changeover as
            the different weights and viscosities of the fluids will
            cause contamination of the pill stages and they will have
            to be discarded. The workstring should be reciprocated
            and/or rotated to enhance the displacement process.

Once the changeover has been completed, the use of pipe dope should be
held to a minimum. It has been found that pipe dope is a major cause
of plugging not only in the formation but also on the gravel packing
screens. This plugging of the screens may cause poor gravel packs due
to the inability to effectively dehydrate the slurry through the
screen. In recent field tests pipe dope was applied to only the pin
end of the workstring using a 1 in. (2.54 cm) paint brush and then
only when required. It was found that as many as 5 round trips were
                                -142-

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made without  galling  or  leaks  developing
                                         10
By using  the  changeover  procedure  outlined above, acceptable  clarity
levels may  be  obtained  in  as  little  as  1-1/2 circulations.  In the  case
of severe hole contamination,  this process may need  to be  repeated  2
or 3  times, in general  time and  money spent on the proper  execution of
the changeover procedure will  be less than that of additional
filtering and  loss  of production if  improper displacement  methods  are
used.

Once  the  system has  been closed  it is imperative that all  completion
fluids be filtered  before  being  pumped  into the well. There are two
methods generally used  to  filter completion fluids;  cartridge filter
systems and Diatomeacous Earth (DE)  systems.

Cartridge systems utilize  filter elements for the removal  of  solids
from  the  completion  fluids. These  elements are constructed  by wrapping
a perforated  tube with  a woven material made of cotton or
polypropylene  fibers. The  tightness  of  the weave determines the size
particle  the  elements are  capable  of filtering. Cartridge  elements are
rated by  the  nominal size  in microns of the smallest particle to be
filtered  out.  A 10  micron  element  is constructed to  filter  those
solids with a  diameter  10  microns  or larger. However, differential
pressure  across the  filter element may  distort the weave allowing
larger particles to  pass through.  For this reason it is necessary for
the filter system to be  monitored  closely and the filter elements
changed often.  Absolute  cartridges are  available that will correct
this problem but are in  most cases cost prohibitive. Due to the
frequency of element changes required to maintain the fluid clarity,
it is recommended that  systems having volumes greater than 100 barrels
use DE filtering systems.

DE filter systems are proven to  be an effective and economical method
of cleaning completion  fluid systems  .  The DE system, however must be
sized properly  in order  to achieve optimum filtering capabilities. An
acceptable rate of filtering is  .25-.50 gallons per minute per square
foot10. When fluids of higher weights are used, care must be  taken
when sizing DE  systems as the  increase  in weight and viscosity of the
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fluid greatly reduces the efficiency of the filter system in terms  of
rate and solids removal.

Additional problems that may be encountered with improperly sized DE
systems are solids blow-by and DE bleed through. These two problems
are caused by operating the system at a higher pressures than
recommended in order to maintain an acceptable rate. These problems
were addressed by Glaze and Echols   and found increasing the square
footage and reducing the flowrate increased filter efficiency. Due  to
the plugging ability and the fact that DE is virtually insoluble in
acid, it is recommended that a cartridge filter unit be placed down
stream of the DE unit as a guard against contamination of the
completion fluid with DE material.

In order to prevent excessive fluid loss to the formation, completion
fluids should be of the lowest density possible while maintaining a
safe hydrostatic over-pressure (100-150 psi overbalance). In many
cases however fluid loss materials will be required in order to
maintain hole stability. These materials may be used for the control
of fluid loss to the formation and/or as a method of preventing
formation sands from "sloughing" into the wellbore. In either case
these materials must be non damaging and 100% removable. The size and
use of wellbore stabilizing slurries should be held to a minimum, that
is use only what is required to continue with normal completion
procedures.

There are three major fluid loss systems in use today; calcium
carbonate, saturated salt systems, and HEC gel slurries. Calcium
carbonate (CaCO.,) is often used as a well stabilizer because of it's
ease of handling and 100% solubility in hydrochloric acid. Calcium
carbonate is normally mixed in a HEC pill at a load of 50 Ibs/barrel
and spotted across the perforations. If calcium carbonate is used
during the completion or workover process it is necessary that all of
the material be removed with hydrochloric acid prior the start of the
gravel packing operation. If not the calcium carbonate forms a thick
filter cake that will not allow for good injectivity into the
perforations.
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Another  form of wellbore  stabilizer  is the super-saturated salt
systems. This  involves  the building  a viscosified salt pill to a point
that exceeds the saturation  limits of the fluid. Additional granulated
salt in  then added  to the pill,  however will not dissolve because of
the fully saturated state of  the  fluid. The pill is then spotted
across the formation and  the  salt crystals act as a plugging agent.
The salt is removed by  circulating or injecting a fluid with a low
salt concentration  and  therefore  dissolving the granulated material.
As in the case of calcium carbonate, the salt pill must be removed
prior to the actual gravel packing operation.

Finally HEC (hydroxyethyl cellulose) is the most widely used method of
lost circulation control. HEC  can be used to viscosify both treated
fresh water and brines. Through  many test and field applications it
has proven to  be the least damaging  gelling agent. HEC pills will
degenerate as  a function  of  time  and temperature without additional
treatment. Pills are normally  mixed with a loading of 3.5-4 Ibs of HEC
per barrel of  brine and then  spotted across the formation. The
viscosity of the gel will then impede the loss of fluid to the
formation.
PERFORATING
Perforating is that part of the completion procedure that allows for
communication between the wellbore and the formation. The main
objective of a perforating program is to achieve channels which allow
for efficient flow of fluids from the reservoir into the wellbore.

Early perforating systems involved the use of mechanical, hydraulic or
bullet perforators. These systems often were a source of high
formation damage and excessive rig time and have been largely replaced
by explosive shaped charges. Shaped charges were developed originally
for use in anti-tank guns by the military in the late 1930's. The
typical shaped charge consists of a steel case, charge and a liner.
Upon detonation of the charge, the force generated by the rapidly
burning material is focused by the construction of the case and
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creates a high speed jet of metal which penetrates the casing walls.

Explosive shaped charges are available in many forms and
configurations. The two basic groups however are classified as
expendable guns and hollow carrier guns.

Expendable guns are shaped charges run in the hole on an explosive
train to the proper depth. The charges are then detonated and as the
name implies, all firing mechanisms and charge housings are destroyed
and left in the hole. The advantage of expendable guns is that a
larger charge may be used for any given gun diameter. The
disadvantages are a.) debris left in the hole may interfere with
further completion operations, and b.) potential casing and cement
damage caused by improperly positioning the guns.

Hollow carrier guns consist of a shaped charge confined in a pressure
housing and may be run on wireline or tubing. When detonated, this
hollow carrier retains the debris from the charge housings and firing
mechanisms. The additional strength and protection of firing
mechanisms make hollow carrier guns the more reliable choice of
perforating guns.

In order to design an effective perforating program many factors
should be considered:

    1. Perforating Fluids - This is the fluid that will be across
       from the perforations when the guns are actually fired.

    2. Perforating Debris -Debris consisting of copper, lead, and
       copper are injected into the formation every time a
       perforating gun is fired.

    3. Perforation Compacted or Crushed Zone -In test performed by
       Saucier and Lands   on Berea cores showed that an area of
       severe damage consisting of crushed or compacted zone extended
       radially from the perforation to a distance of up to .7
       in.(1.7 cm.)
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    4. Perforation  Cleaning  -  The perforating process has inherent
       damaging  characteristics  that  cannot be completely eliminated.
       In order  to  correct  these problems an effective method of
       cleaning  the perforations needs  to be considered.

    5. Depth  of  Penetration  vs.  Perforation Diameter - In general, as
       shot penetration  increases the shot diameter diameter
       decreases. The  depth  of penetration should always be
       sufficient to extend  past the  damaged area caused by drilling
       and cementing.

    6. Shot Density -The  number  of  shots per foot to achieve maximum
       production.

The perforating  program  required in a gravel pack completion is
significantly different  than perforating in harder formations. One of
the decisions that  must  be made  in  this area is the type of
perforation cleaning system. Two general methods exist; 1) the well is
perforated with  wireline  casing  guns  and the perforations washed with
a mechanical wash tool assembly  and 2)  the well is perforated
underbalanced with  tubing conveyed peforating equipment and the
underbalanced condition  allowed  to clean the perforation tunnels.

Perforating underbalanced (the formation having a higher pressure than
the wellbore at  the moment of  perforation) will help overcome much of
the damage caused by perforating, drilling, and cementing operations.
In soft sand formations  a 500  to 1000 psi underbalance is used to
perforate the formation.  While underbalanced perforating is an
excellent method of removing damage from the perforations it is
doubtful and should not  be expected that all perforations will be
affected the same.

Formation damage may also be removed by washing the perforations. For
this method a mechanical  wash  tool is lowered to the perforated
interval on tubing  and fluids  forced  into the formation at 6"-!'
increments. After being  injected into the formation the fluid washes
the areas directly  adjacent  to the casing with returns being taken
through the perforation  immediately above the section being washed.
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In test performed by Penberthy   perforations were tested under
several different conditions and the following conclusions were made
in regards to washing:

       a. Voids can be washed between perforations and then filled
          with gravel pack sand.
       b. The amount of formation sand removed by washing increases
          with increasing pump rates.
       c. Low viscosity rather than high viscosity fluids are more
          effective in washing perforations
       d. Perforation wash volume geometry is dependent on the
          permeability of the formation sand. High permeability sand
          is more easily removed than low permeability sands
       e. Perforation washing can precipitate pressure parting if the
          pressure gradient is exceeded

It must be noted that washing perforations runs the risk of
intermixing formation clays and shales with productive sand causing
possible formation damage. Either perforating systems may be used
successfully in the completion process as long as a viable cleaning
process is utilized.

The next major item in the design of the perforating program is the
selection of shot size, shot diameter and shot density. With the
perforating equipment available today shot diameter and shot
penetration are mutually exclusive, as shot diameter increases, shot
penetration decreases. In sand control applications this trade off is
decided in favor of shot diameter for the following reasons.

As detailed in the Theory section of this paper,  the pressure drop in
the perforation tunnels for a gravel packed completion is quite large.
For this reason it is important to have as many open perforations as
possible to pack gravel pack sand into.

Furthermore in soft formations requiring sand control, penetration is
not generally a problem. The damage caused by the shaped charge in the
compacted or crushed zone is also not as severe due to the formation's
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ability to absorb  the  force of the perforating charge. For these
reasons it is much more productive to increase shot diameter in
relation to  shot penetration. A normal perforating program for a
gravel packed completion will consist of a shot diameter of the
largest size capable,  usually greater than .75", and a shot density  of
12-16 shots/foot.
GRAVEL PACK DESIGN
The purpose of a gravel pack is to place a high quality sand in the
perforation tunnels and around a screen which has been positioned
across from the productive interval. The sand acts as a filter and
keeps the formation sand from being produced with the well fluids. As
with any phase of the completion operation, there are several design
parameters which need to be addressed to assure a quality gravel pack.

Most gravel packed completions are performed under cased hole
conditions and this discussion of gravel pack design will be aimed
more towards these types of completions. Open hole gravel packs differ
primarily in the perforating program, however many of the items
covered in this paper will also apply to these types of completions.

Gravel Pack Sand Sizing
The first step in designing a gravel packed completion is to obtain a
sample of the formation material in order to be able to size the
required gravel pack sand. Rubber sleeve and conventional cores are
excellent methods of accomplishing this because they obtain a large
volume of sample which is representative of the true formation sand
size-  The difference between these two coring techniques is that the
rubber sleeve core has a rubber sleeve which lines the core barrel.
This sleeve contracts to hold the formation material in place while it
is being tripped out of the hole. The conventional core barrel does
not have this feature therefore allowing unconsolidated formation sand
to fall out of the core barrel while being tripped to the surface-
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The most common and readily available formation sample is  the  side
wall core. Side wall cores are easily obtained prior to setting  casing
by the use of a core gun. The gun is run into the hole and  shot  at  the
intervals of interest. The samples can then be individually  tested  and
studied. Many companies go to the additional expense of obtaining two
sets of side wall cores. One set is given to the geologist  and the
other set used to design the sand control completion.

Bailed and produced samples are the worst method of collecting
material, although they are sometimes the only sampling technique
available. Bailed samples are poor because of the inability  to
determine where the bailer caught the material. Finer particles  will
settle out of the fluid first, resulting in coarser material resting
on bottom and the finer material on top. Because we cannot determine
where the sample is being taken in this gradated sand column, a  true
representation of the formation is not known.

The next step in the design process is to analyze the formation  sand
sample to determine the median sand grain size. The sample is sieved
on a series of sieves to obtain the weight percentage retained on each
screen. The cummulative percentage on each consecutively smaller
screen is plotted against the sand grain size. When plotted  this graph
looks like an S-curve. The sand size which is the most representative
of this particular formation sample is chosen to be the 50 percentile
point on the S-curve. This design point determines the median sand
grain size of the formation. As discussed in the Theory section  of
this paper the size of the gravel pack sand can now be determined.

The selection of the size and quality of the gravel pack sand is of
utmost importance. The size of the gravel pack sand will determine
whether the formation sand is restrained while the use of poor quality
gravel pack sand may cause a reduction in the permeability of the
final pack.  Fines can be generated by erosion of the sand grains
during transportation or during the placement process. These problems
are almost always associated with angular type gravel. When  forces  are
applied to angular gravels by handling, trucking, shipping,  or pumping
operations,  the gravel tends to be eroded to a more spherical shape.
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The particles that are broken off will plug the pores therefore
causing a reduction in permeability.
i
Fines can also be present in the gravel source due to improper quality
control by the gravel supplier. Poor quality control can be seen in a
gravel that has a large percentage of fines or oversize particles. A
good quality gravel pack sand should be within 96% of specifications
and should not have any grain size varying by more than 2%.

The perfect sand grain will have a sphericity and a roundness factor
higher than 0.6, with 1.0 being a perfect circle.  It will also have a
very rough crater-like surface which gives the gravel enough
frictional resistance to form a stabilized pack that will not be
fluidized by the production or injection process. Glass beads have a
slick surface and a very low friction factor and if used in a gravel
pack can be very easily fluidized.
                                                         •

Attention must be given to avoid using inferior gravel pack sand. The
use of a gravel with a guaranteed low quantity of fines and oversized
grains will result in a better gravel pack. For the 20 mesh cuts (i.e.
20-40, 40-60, 50-70) there should be no more than 2% by weight of
oversized or undersized particles.  For the 10 mesh cuts (i.e. 20-30,
30-40, 40-50) 1% oversized and undersized can be tolerated.

Rounded gravel will greatly reduce erosion during the placement
operation and limit the amount of fines generated. The use of a gravel
with a high percentage of quartz is also beneficial because the high
quartz content increases the strength of the sand grain. This results
in the sand being very resistant to crushing and erosion as well as
being very resistant to acid exposure.
Gravel Pack Fluids
The next step in designing a gravel pack is determining the type of
gravel packing fluid to be used. There are a variety of gravel pack
fluids available to the industry today and the correct system for a
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specific well depends on various parameters that must be examined
before a final design can be determined. The two most widely used
systems are the slurry pack and the water pack.

The water pack systems was the original method  for the placement of
sand in which the un-viscosified workover fluid is used to carry the
gravel pack sand to bottom. Because of the poor carrying capabilities
of water, the concentration of sand must be kept low. This operation
is carried out by the placement of a sand injector in line with the
gravel pack pump. The gravel pack sand is then  injected into the well
with completion fluid at a rate of approximately 50-100 Ibs/barrel.

Gravel packing with a sand injector tends to co-mingle gravel and
formation sand in the perforation tunnels therefore causing a severe
reduction in permeability. In addition water packs require large
amounts of fluids and time to execute. Due to the disadvantages
encountered with this system, water pack are discouraged.

A slurry pack is performed by loading a viscosified fluid with gravel
pack sand and pumping this sand ladened fluid into the screen-casing
annulus. The viscosity of the carrier fluid is such that the
concentration of gravel pack sand can be greatly increased, normally
around 300 Ibs/bbl. This highly concentrated slurry moves into the
perforation tunnel as one mass and allows for little inter-mixing of
formation sand and gravel pack sand. This maintains the permeability
in the perforation tunnels at a maximum and therefore minimizes the
                                    18
pressure drop across the completion.

The base fluid used for the slurry is usually fresh water treated with
3% Ammonium Chloride or 2% Potassium Chloride. The completion brine
may also be used with an HEC loading at a ratio of 2.5-3.0 Ibs
HEC/barrel. With this high sand/fluid ratio, much less fluid is
required to perform the gravel pack therefore reducing the required
placement time. The slurry pack method is by far the most popular
fluid method in gravel packing and is highly recommended for the
completion design.
                                  151a

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Gravel Pack Techniques
The next major  decision  concerns  the  method of placing the slurry
across  the  perforated  interval. Although  it will not be covered in
this paper  it  is  recommended  that a matrix acid treatment be performed
prior to gravel packing  regardless of the technique used. This
procedure assures  that the  perforations are open and taking fluid and
therefore can  be  packed  with  the  gravel pack sand. The actual method
of placement will  depend on factors such  as well deviation, length of
interval, and  tool  spacing. There are three techniques available for
slurry  placement.  These  are:

                    1.  Squeeze  pack
                    2.  Conventional circulating pack
                    3.  Bottom-up circulating pack

Due to  limited  service tool manipulation, squeeze packs are generally
less complicated  to perform than  circulating packs. When a slurry is
squeezed into  place, the slurry is circulated to the gravel pack
packer  and  then forced into the formation. Because there is no way to
insure  the  slurry  has  been  introduced to  the entire interval and
cannot  be squeezed  through  the production screen there is a
possibility that voids will exist in  the  gravel pack. These void may
result  in movement  of  formation sand  into the perforations and
wellbore, greatly  reducing  productivity.  For this reason it is
recommended that  a  squeeze  pack be performed on those intervals no
greater than 20 feet.

A circulating  pack, as the  name implies, utilizes a circulation path
to position the slurry across  the production interval. This process is
accomplished with  the use of washpipe  in a four position service tool.
A lower screen  section (Tattle-Tale)  is placed below the production
interval and separated from the production screen with a seal bore
assembly. Wash  pipe is then placed in  the seal bore to direct the
circulation path  through the tattle-tale  (lower circulation)

Once the tattle-tale is  covered the circulation path is blocked and
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the slurry  squeezed  into  the  formation. After sand-out the wash  pipe
is pulled from  the seal bore  and circulation is  re-established with
the washpipe  through  the  production screen  (upper circulation).  This
circulation path allows the slurry to be de-hydrated through  the
screen.  This  placement method is much more  successful at placing  sand
both  in  the perforations  and  around the screen.

The technique described above has worked well in straight holes  and
produces satisfactory results.  In a deviated well however, the gravel
fails  to pack uniformly and voids are developed  in the packed annulus.
In recent years, several  studies  '  '   have been performed  to
investigate this problem.

All of these  studies  indicate that as the degree of deviation
increases,  the  percent pack in  the annulus  decreases. The main reason
for this correlation  is that  gravitational  forces tend to cause  the
gravel to prematurely settle  out near the upper part of the zone  to be
gravel packed.  As a  result, a small dune begins to form at the upper
end of the  zone. As  the dune  enlarges and desends down the annulus,
more  and more of the  carrier  fluid is diverted through the screen by
the fluid flowing over the dune. This causes the velocity of  the
slurry to decline therefore resulting in additional sand settling.
This  process  continues until  the dune completely blocks flow  to  the
lower  portion of the  annulus. When this shut off occurs, the  slurry
fluid  is diverted through the top section of the screen and no further
slurry can  be paced  in the annulus. This will adequately pack the
upper  section but leave a void  in the lower section.

                                                   19
In field and  laboratory studies conducted by Stiles   a new technique
for placement of sand slurry  was developed. This technique has been
named bottom-up after the manner in which the sand is placed  in  the
screen annulus. In conventional gravel packs, the sand is pumped  from
the top  of  the  interval to the  bottom. The  bottom-up method reverses
this  flow and the sand is circulated from the bottom of the interval
to the top. This concept  is similar to the  method used in cementing
casing strings  in a well.

As identified in the  gravel packing studies referenced above, the
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settling  rate of  the gravel pack sand is what causes the "duning"
phenomena to occur. The bottom-up system reduces this settling rate
and therefore reduces or eliminates the formation of these dunes.
Another way of describing this effect is that the sand is being
constantly "bumped" up the hole by the force of the fluid and
therefore not allowed to settle out. This will keep the sand in the
fluid instead of  settling out and being deposited on the low side of
the casing. The sand will then move completely to the top of the
screen in plug flow and not accumulate at the bottom of the zone.
Downhole Equipment
The final step in the design of a gravel pack completion is the
selection of the downhole equipment. Selection of packers and screens
will depend on the type of fluid to be injected, the type of gravel
pack to be performed and the production requirements.

In many injection wells the fluid being disposed of is corrosive to
the standard metal and rubber products used in conventional downhole
equipment. For this reason premium metals, such as stainless steel or
other exotic metals are used in the construction of the tubulars,
packers, screens and other downhole accessories. Information
concerning the application of such materials is available from the
equipment suppliers.

In conventional oilfield equipment, seals and packer elements are
normally made of butal-nitrile.  Under corrosive conditions however
premium rubbers such as vyton, ryton, and teflon must be used. These
premium rubber products are resistant to many corrosive fluids but
require certain design modifications to the wellbore hokk-up. For
example these materials are often quite brittle, and therefore once
located in a seal bore they should not be allowed to move.  This
requires certain modifications to the downhole equipment and must be
designed for in the completion setup.

In gravel pack completions, there are two basic types of production
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packers: Permanent-retrievable packers and mechanical hook-wall
packers. The type of packer used is dependent upon depth, system
pressures, production or injection rates, access to well, and
regulatory guidelines. Hook-wall packers are run on tubing and
normally set with a combination of torque and set down weight. Upward
pull of the tubing unsets these packers at which time they can be
reset without  redressing the tool.

Permanent retrievable packers are set with a "setting tool" that
imparts a force to the packer that sets the slips and expands the
packing elements. The setting tool is then pulled from the hole
leaving the packer in a set position. A seal assembly is then run into
the hole and sealed into the polished bore on the packer.

In general the hook-wall packers are less expensive than the permanent
type packers and are used in shallow to medium depth land
applications.  The major disadvantage to this type of packer is the
possibility of it becoming unset during production or injection
operations. As stated above these packers will unset with upward pull
of the tubing. This same upward pull however can be generated by
tubing shrinkage caused by normal well operations. From tubing
movement analysis it can be seen that this problems becomes more acute
when the depth of the well increases, the system pressure increases,
high volumes of fluid are being produced or injected, and bottom hole
temperature increases. For these cases a more permanent installation
is required and a permanent type packer should be used.

Another problem encountered with hook-wall packers is the difficulty
in the setting process. It is sometimes difficult to determine when
enough torque  has been applied to correctly position the setting
mechanism on the packer. This can result in over-torquing the
workstring. Furthermore when the tubing is lowered to apply set down
weight on the  packer, the tubing buckles in the form of a helix and a
significant amount of the applied weight is supported by the friction
between the tubing and casing. These problems are amplified by well
deviation and  depth and can cause difficulty in setting the packer.

A permanent-retrievable packer is more costly than a hook-wall packer
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but has the advantage of being both extremely stable and tubing
retrievable. This type packer cannot be unset by tubing movements and
normally has working pressures which greatly exceed other production
packers. The permanent-retrievable packer was developed for offshore
use, however, because of the ability to support a variety of gravel
pack configurations it is frequently used in land operations. These
types of system also require that a seal assembly be run on the end of
the tubing in order to seal into the bore of the already set packer.
This seal assembly isolates the injection fluid from the production
tubing annulus.

The seal assembly may be used in a floating seal or fixed seal       «
configuration. A floating seal assembly allows the seal to move within
the seal bore during production. A tubing movement analysis should be
performed to insure that sufficient seals are run to prevent
communication between the production tubing and the tubing annulus.
Furthermore in some high volume injection wells, forces encountered
during injection may cause sufficient stress in the form of a bending
moment that permanently distorts the tubing. In these cases the seals
are not allowed to float or move in the packer bore but are held in
place with some type of anchoring system. The forces generated by
tubing movement in the well can be substantial and should always be
analyzed and incorporated into the final well design.
Gravel Pack Systems
The selection of the production packer is not only dependent upon well
conditions but also dependent upon the gravel packing method to be
used. In order to select the type of production packer to be used an
understanding of the different gravel pack systems is first required.
The gravel pack process itself requires a packer to be set during the
pumping operation. The packer is needed in order to be able to squeeze
the sand slurry into the perforations without applying the squeeze
pressure to the entire casing string. After completion of the pack, a
production packer must also be set on top of the production screen in
order to control the flow of fluids into the tubulars. In general the
                                 -156-

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following two systems are available to the operator to achieve these
results:

         1) Two trip system
         2) One trip system

The two trip system was the original method for completing gravel
packed wells and utilizes a mechanical hook-wall packer as the gravel
pack packer. The hook-wall packer is used during the gravel packing
operation and then pulled from the well after completion. A production
packer and an overshot is then run to bottom and sealed over a hook-up
nipple that is on top of the screen and liner assembly. The production
tubing is connected directly to the packer and therefore no seal
assembly is required. Almost any type of production packer can be used
with this system although most often another hook-wall packer is
selected. As the name implies this method requires two trips of the
pipe in order to finish the gravel pack.

Due to the design of the hook-wall packer used in the two trip method,
this technique is primarily used to perform squeeze packs. Although
some modifications may be employed to allow a circulating pack, it is
not capable of providing an upper and lower circulating position. Due
to the lack of a true lower circulating position the slurry may not be
"forced" to the bottom of the interval resulting in a premature sand
out. For these reasons it is not recommended that this type of gravel
pack be used for zones greater than 20' in length.

The one trip system was developed in the mid 70's for offshore
completions. This system utilizes the same packer for both the gravel
packing operation as well as the production operation. A permanent-
retrievable packer is set prior to the gravel pack and then left
behind to serve as the production packer. This concept requires one
less trip and is used exclusively in offshore completions.

The one trip system allows for the most flexibility of all of the
gravel pack systems. Both a squeeze pack and a circulating pack can be
performed with the system depending upon how the screen assembly is
configured. Many service companies offer a four position one trip
                                 -157-

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system and these should be used when possible. This is especially true
for gravel packing zones in excess of 20' or on wells deviated greater
than 45 degrees.

In general these one trip systems are run as follows: The packer,
crossover and setting tool, and screen assembly are run in the hole
and positioned across the production interval. The packer is then set
and the crossover tool released with mechanical and/or hydraulic
force. Once the packer has been set and the gravel pack has been
performed the crossover and setting tool are pulled out of the hole.
The seal assembly can then be run into the well and the remainder of
the completion process continued. Appendix A contains a sample
completion procedure using a one-trip type gravel pack system.

The actual type of gravel pack system to be used is dependent upon the
well conditions. In general the one-trip type systems produce superior
packs because of the four positions which are available during the
packing operation. In addition these systems utilize a stronger more
stable packer for the final production packer. The two trip systems
however can be used successfully on short zones, shallow depth, low
pressure and other field applications.
CONCLUSIONS
1)  Gravel packing injection wells is a viable technique that can
    control unconsolidated formations while maintaining high
    injectivity.

2)  The placement of high quality gravel pack sand in the perforation
    tunnels is the most important aspect of the gravel pack procedure.

3)  The use of clean low solids fluids is a requirement for high
    quality gravel packs.

4)  The perforating program for gravel packed completions should allow
    for some type of perforation cleaning, high shot density and large
                                -158-

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    shot diameter.

5)  The gravel pack system to be used should be matched with the
    wellbore conditions and the equipment requirements.
REFERENCES
1.  Liebach, R.E. and J. Cirigliano: Gravel packing in Venezuela,
    Seventh World Petroleum Cong. Proceedings,  Mexico City (1967),
    Sec. Ill,       p. 407-418

 2. Williams, B.B., L.S. Elliott, and R. H. Weaver: Productivity of
    inside casing gravel pack completions,  J. Petroleum Technology
    (April 1972), p. 419-425

 3. Saucier, R.J.: Conciderations in gravel pack design,  J. Petroleum
    Technology (Feb 1972) p. 205-212

 4. Holman, G.B.: Evaluation of control techniques for unconsolidated
    silty sands, J. Petroleum Technology (Sept  1976)  p. 979-984

 5. Monroe, S.A. and W.L. Penberthy, Jr.:  Gravel packing  high volume
    water supply wells, J. Petroleum Technology (Dec  1980), p.
    2097-2102

 6. Manthooth, M.A.: "Statistical Analysis  of Recent  Sand Control
    Work", API Committee on Sand Control,  API Paper 926-13-G (1968)

 7. Coberly, C.J. and Wagner, E.M.:  "Some  Considerations  in Selection
    and Installation of Gravel Pack  Oil Wells", Pet.  Tech. (Aug.
    1938) TP 960.

 8. Hill K.E.: "Factors Affecting the Use  of Gravel in Oil Wells,"
    Oil Weekly,  (may 26, 1941 p. 13-20

 9. Winterburn,  Read: "Control of Unconsolidated Sands in Wilmington
                                  -159-

-------
    Oil Field," Drill, and Prod. Prac.,  API (1947) p. 63-79

10. Ledlow, L.B. and Sauer, C.W.: "Recent Design, Placement, and
    Evaluation Techniques Lead to Improved Gravel Pack Preformance,"
    SPE 14162, 1985

11. Sollee, S.S., Elson, T.D. and Lerma, M.K.: "Field Applications of
   v Clean Completion Fluids," SPE 14318, 1985

12. Barren, C.W., J.A. Young, and R.E. Munson: "New Concept-High
    Density Brine Filtration Utilizaing Diatomaceous a Earth
    Filtration System," SPE 10648, 1982

13. Glaze, O.K. and J. B. Echols: "Filtering oil field brines is not
    that simple," World Oil, (Oct. 1984), p. 85-90

14. Penberthy, W.L.: "Gravel Placement and Perforation Cleaning for
    Gravel Packing", SPE 14161 1985

15. Maly, G.P., Robinson, J.P- and Laurie, A.M.: "New Gravel Pack
    Tool for Improving Pack Placement,"  J. Pet. Tech. (January, 1974)
    19-24

16. Gruesbeck, C., Salathiel, W.M. and Echols, E.E.: "Design of
    Gravel Packs in Deviated Wells," paper SPE 6805 presented at SPE
    52nd annual Fall Technical Conference, Denver, Oct.  9-12, 1977.

17. Shryock, S.G.: Gravel Packing Studies in a Full-Scale, Deviated
    Model Wellbore," paper SPE 9421 presented at SPE 55th Annual Fall
    Technical Conference, Dallas, Sept.21-24,  1980.

18. Sparlin, Derry D., "Pressure Packing with Concentrated Gravel
    Slurry," paper SPE 4033 presented at the 47th Annual Fall
    Meeting, San Antonio, Oct. 8-11 1972.

19. Stiles, R.F,  Colomb,  G.T., and Farley, D.L.:"Development of a
    Gravity-Assisted Gravel Pack System, " SPE 15409 presented at
    61rst Annual  Technical Conference, New Orleans, LA,  October 1986.
                                 -160-

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20. Saucier, R.H. and Lands, J.F.: "A laboratory Study of
    Perforations in Stressed Formation Rocks," JPT, February 1978
                                 -161-

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                          Appendix A
                     Operating Procedure
Perform any necessary squeeze work.  Make a bit and scraper run
to 4;50' below the desired interval to clean the casing wall of
any debris (such as mud cake or scale) which might obstruct the
running of any tools.

After the casing has been scraped, reverse circulate 2 hole
volumes with clean, filtered workover fluid to wash out any
debris which has been scraped from the casing and POOH.

RU the wireline unit and make a gauge ring and junk basket run to
assure a constant casing ID from surface to the desired plugback
and POOH.

GIH with wireline set sump packer and set it to 10-12 feet below
the lowest perforation of the desired interval and POOH

GIH with the perforating equipment and perforate the desired
interval.  The recommended perforating shot density is 12-16 spf
with the largest hole diameter allowable.  POOH

GIH with the centralized screen and liner assembly. Caliper and
check all tool connections,  screen gauges, and record all
lengths. Lubricate all connections with available lube oil. DO
NOT USE PIPE DOPE. For a single zone circulating gravel pack the
screen and liner assembly will consist of:

    a.  1/2 muleshoe, collet latch, 2' of seals and locator sub
    b.  Crossover to tattle  tale screen
    c.  Tattle tale screen
    d.  "0" ring seal sub
    e.  All-weld production  screen wrapped from bottom up and
                             -162-

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        centralized every 15' for casing size used
    f.  Blank tubing
    g.  Safety shear out sub

Hang off the screen and liner assembly with clamps. Pick up the
sized washpipe and GIH. Sting into "0" ring seal sub and space
out to the rotary with the proper sized pup joints.

Make up Gravel Pack assembly consisting of:
    a.  Crossover and setting tool
    b.  Gravel Pack Packer
    c.  Slotted extension
    d.  Lower seal bore
    e.  Lower seal bore extension
    f.  Interference collar
    g.  Interference collar extension

Connect the washpipe to the washpipe adapter on crossover tool.
Next connect the gravel pack assembly with the screen and liner
assembly. Finally connect the workstring to the gravel pack
assembly and GIH with the entire assembly.

Immediately prior to tagging the sump packer, PU on the
workstring and note actual pick up weight.

Gently sting into the sump packer with collet latch and seals.
In order to verify the position of the assembly, pull 30001 over
the pipe pick up weight.  Once a positive indication of the latch
in is observed, slack off to neutral weight and close the hydril.
Slowly reverse circulate to fill the tubing.

With the gravel pack assembly properly positioned and the tubing
full,  drop the ball and wait for it to gravitate to the ball
seat.   Pressure up on the tubing slowly in 500 psi increments to
3000 psi.  Three shears will be observed during the packer
setting procedure.  The first shear (at +1000 psi) indicates that
the packer has been set.  The second (at +2000 psi) shear
indicates that the setting sleeve on the setting tool has been
                              -163-

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sheared which deactivated the setting tool.  The final shear (at
+3000 psi) indicates that the releasing sleeve has shifted to the
lower position allowing the threaded lugs to disengage, releasing
the setting tool and crossover assembly from packer assembly and
indicates that the ball seat has been blown to below the
crossover ports.

One the three shears have been observed place 10,000#'s on the
packer and mark the tubing to indicate the squeeze position.  PU
8" and mark the pipe to indicate the lower circulating position.
Establish a circulating rate and note the pressure required to
break circulation.  PU 2' while bumping against the interference
collar and mark the pipe to indicate the upper circulating
position.  Slack off to the squeeze position and set 10,000#'s on
the packer.  Establish an injection rate with filtered workover
fluid at less than the calculated fracture pressure.

After the packer has been set and the tool positions established,
a mutual solvent acid job should be performed prior to the
introduction of the sand slurry to the perforation tunnels.  A
mutual solvent dcid job will enhance the injection profile,
alleviate damage near the wellbore and provide for rapid clean up
of the well.  Position the crossover tool in the reverse
circulating position and spot the acid 2-3 barrels above the
tool.  Slack off to the squeeze position and set 10,000t's on the
packer and squeeze the acid into the formation at matrix rates.

Directly behind the afterflush for the acid treatment, pump a
viscous spacer of gelled fluid to prevent any sand from entering
the neat fluid while being pumped downhole.  Next, pump a sand
slurry consisting of a gelled fluid containing quality controlled
sands whose sizes are determined by a sieve analysis of
representative samples obtained from the zone of interest.

The use of a high density slurry allows gravel placement into the
formation and perforations tunnels with minimum fluid loss and
prevents the mixing of the pack sand and formation sand.  When
two sizes of sand are mixed, the resulting permeability is less
                             -164-

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than either.

When the afterflush has been displaced to the formation, position
the crossover in the lower circulating position and continue
pumping until a sand out of the lower telltale screen is
obtained.  The sand out is indicated by an increase in pressure
and a decrease of the returns at the surface.

At this sand out the pressure should be allowed to increase
1000-1200 psi over the circulating pressure.   Slack off to the
squeeze position and set 10,000#'s on the packer.  Squeeze the
slurry into the formation until a pre-determined squeeze pressure
is attained.  Allow the pressure to bleed off into the formation.
PU to the upper circulating position and circulate through the
production screen.  Continue circulating until a sand out on the
production screen is obtained.  Again,  an increase in pressure
and diminishing returns at the surface  serve  as indicators that a
sand out on the production screen has been obtained.   Allow the
pressure to increase o 1000-1200 psi over the circulation
pressure.

Bleed off the pressure and pull the collet through the
interference collar.  Pick up 3-4' to get into the reversing
position.  Reverse out the excess slurry plus a minimum of 2
tubing volumes.  POOH with the crossover tool.

Go in the hole with the production seals with a locator sub,
landing nipples and other required equipment.  Continue the
procedure to place the well on production.
                             -165-

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           FACTORS THAT CAN CAUSE ABANDONED WELLS TO LEAK




       AS VERIFIED BY CASE HISTORIES FROM CLASS II INJECTION,




                  TEXAS RAILROAD COMMISSION FILES









              J. E. CLARK, M. R. HOWARD, D. K. SPARKS









                E. I.  DU PONT DE NEMOURS & CO., INC.




                           P. O. BOX 3269




                       BEAUMONT, TEXAS  77704
                              ABSTRACT







An  abandoned  well  is  a  well  where  use  has  been  permanently



discontinued or is in disrepair such that it  cannot be used for its



intended purpose nor  for observation purposes.  A properly plugged



well is a well where upward migration  of fluids  does not occur  as a



result of increased reservoir pressures.








Abandoned wells are possible  sources of pollution  to water supplies



if fluids are allowed to migrate  into  Underground  Sources of Drink-



ing Water  (USDW)  from the  over-pressured  injection zone.   Federal



Underground Injection Control (UIC) regulations require the critical



identification and evaluation of  all abandoned wells in  the Area of



Review (AOR) during the permitting process.
                                  -166-

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Case histories  from the Texas Railroad Commission  files  on leaking



abandoned wells reportedly caused by  Class  II  injection wells (salt



water and enhanced  recovery)  were studied.   Important  factors have



been identified from these case histories that  can  cause an improp-



erly  plugged  abandoned well  to  leak due to  overpressuring  the



injection zone.   The  factors  include:  1)  depth of the injection



zone,  2) casing left in the borehole which is open to the injection



zone, providing a direct path for upward fluid migration,  3) reser-



voir properties and flow rates,   4) drilling method, and  5) bore-



holes  in "hard"  rock  which  tend  to  remain  open  indefinitely,  as



opposed  to  boreholes   in  "soft"  rock where  expandable clays  or



sloughing shales close  the borehole.







An  important  finding   of  this  study  was  that  wells  drilled  in



unconsolidated  (soft)   rock,   such  as  the Texas  Gulf Coastal Plain



experience  natural  borehole  closure,  which drastically  reduces  the



potential for leakage from these abandoned wells.   This study showed



that  the most likely  pathway for  leakage  is  a  production  well



improperly  abandoned with the  production casing left  open  to  the



injection zone.







All abandoned wells in  the AOR must be identified to satisfy Federal



UIC  regulations.   Abandoned  wells  that are satisfactorily plugged



are dismissed  from  further review,  and remaining wells  are consid-



ered for plugging or modeling to determine the maximum permissible



injection  pressure.    The  maximum  injection  pressure  is   set  to



prevent the hydraulic lift of the injected fluid or other non-native
                                  -16-7-

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fluids  into an  overlying USDW  from  improperly  plugged  abandoned



wells.  During modeling it is important to consider  the  entire well



field of surrounding injection or production wells which may affect



the injection zone.  From case studies of several  Class II injection



wells suspected of causing leakage through abandoned wells in Texas,



we believe that operators can achieve responsible  compliance through



the use of historical records and available modeling techniques.







                            INTRODUCTION








Since 1859, when the first petroleum well was drilled  in the United



States,  approximately  three  million  oil  and  gas wells have  been



drilled  and over  two million  have  been abandoned (Anzzolin  and



Graham,  1984).    According  to  40  CFR 146,  a well is  considered



abandoned if its use has  been permanently discountinued or  is in a



state  of disrepair such  that it cannot  be used  for  its  intended



purpose nor for observation  purposes.  Of  particular concern to the



Class II UIC program are improperly plugged wells  that  penetrate the



injection zone  or within  300 feet of  the injection zone,  because



they have the potential for  conveying  fluid from  the injection zone



to an overlying Underground Source of Drinking Water (USDW).








Of  the  approximately 150,000  Class  II  (brine  injection)  wells



operating in the United States (Fryberger and Tinlin, 1984), approx-



imately  54,000  are in Texas  (Roth, 1987).   The State of  Texas has



recognized  the  need for  proper  plugging  of  abandoned  wells  since



1899 when  the  first  regulations  were  passed.    In  1919  the  Texas
                                 -168-

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Railroad Commission  (TRC) was  given regulatory  responsibility  for



proper well plugging.  The TRC  is also  responsible  for  a program to



remedy improperly  abandoned  wells where the operator is  unknown or



financially  insolvent.    Through this  program  approximately  1400



wells have been plugged since 1965 with state funds (Ross and Steed,



1984).







                        AREA OF REVIEW CONCEPT








The  AOR is  the main  UIC requirement  to protect  an USDW  against



potential  upward migration of  fluid from boreholes  that penetrate



protective confining layers.  Abandoned wells come under the current



review process  for a UIC  permit.  In Texas,  the AOR encompasses  the



area within a  1/4-mile  radius of the injection well.   If unplugged



wells  are  known  to exist  nearby,   but  outside  the  AOR, they  may



require  reservoir  simulations  to  determine  the adequacy  of  the



1/4-mile radius  (Engineering Enterprises, 1985).








This  State UIC program  requires  that  records   of  all  artificial



penetrations (boreholes that penetrate the confining/injection zone)



be examined during the AOR to locate wells that are improperly aban-



doned.  A  properly completed or abandoned well is one  where inter-



formational movement  of  fluids  will not  occur  as  a result of  an



increased  reservoir pressure.
                                  -169-

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We  developed  a  protocol   to   identify  and  evaluate  artificial



penetrations in the AOR (Figure 1).  All wells  identified as being



inadequately  plugged  must   be  modeled  to  verify that  no  upward



migration will occur.   If upward migration  is possible, then one of



the  following steps  must be  taken  before the  injection well  is



allowed to operate:








1)  Reenter and properly plug the potential problem well.







2)  Lower the proposed injection rate to reduce the  pressure (head)



    driving force.








3)  Complete  the  injection  well in a lower zone so that  the aban-



    doned  well   can   tolerate   a   higher  pressure  without  fluid



    migration.







4)  Complete the  injection well  in  a  lower  zone which  the abandoned



    well does not penetrate.








5)  Increase  the  density of the injection fluid to prevent upward



    migration.








6)  Drill  a monitor  well next  to the  potential problem well  to



    monitor possible upward  fluid movement.
                                  -170-

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                 FACTORS RELATED TO LEAKAGE THROUGH



                   IMPROPERLY ABANDONED BOREHOLES







Class  II  wells  are  generally  constructed  with  surface  casing



cemented below freshwater aquifers,  long-string casing  perforated



through the injection zone, and injection tubing to deliver brine to



the  subsurface.    Figure 2  shows the  construction of  a Class  II



injection  well and  three  improperly abandoned  wells that  provide



potential  fluid  migration pathways.  A leaking abandoned well  can



mean a leak at the  surface or  interformational  flow of  fluids which



does not  reach the surface  (Figure  2).   Injected fluids will  move



laterally  through the injection  zone and  can migrate into an impro-



perly plugged  well.   A discussion of important  factors  that relate



to leaking abandoned wells follows.







For  the  purposes  of the  study,  two  rock  types  were  identified:



consolidated ("hard") rock and unconsolidated  ("soft")  rock.   These



two  types  are  geologically  distinct  and  their  characteristics



greatly influence the behavior of abandoned wells.







ROCK TYPES








Unconsolidated formations such  as  the  geologically young  Tertiary



shales in  the Texas  Gulf Coastal  Plain  have hydration  (expanding



clays-smectities) and plastic properties which result in the natural



closure  of man-made  boreholes   (Johnston and  Greene, 1979;  Davis,



1986).   Smectite exhibits a high amount  of  swelling when hydrated.
                                  -171-

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Non-expanding clays or  illite  swell much less on being wetted  than
expanding clays.  Collins  (1986)  reported that  shales  penetrated by
drilling fluids  experience a significant water  exchange  due to an
osmotic process  which is dependent upon  ionic  activity of  the  mud
and  the brine  in  the  shale.    This  water  exchange  can  lead  to
swelling of the shale and sloughing into the borehole.

A  change  in  mineralogy   from   smectite   to  illite  occurs  with
increasing depth and temperature and  is associated with  squeezing
water  out  of the  clay lattice  (Grim,  1968).   This alteration is
called  clay  diagenesis (See Figure 3).  Powers (1967)  found  that
when  montmorillonite  (smectite)   is  buried  to  a depth of  approxi-
mately  3000 feet, most  of  the water  is  expelled from it, except for
the  last  few bound layers  that  are along the basal layers  between
the unit layers  of clay.   At this depth,  the  effective porosity and
permeability are essentially zero because all space is occupied by
the  solid  layers of  clay  and  the rigid water  layers  bound  to  the
clay.   In a laboratory  experiment by Darley (1969) most of  the  free
water  in clays was  squeezed out  of the expanding clay members  at a
pressure  of  2500  psi,  approximately  equivalent  to  5000  feet  of
overburden.

Borehole closure by hydration occurs at depths less than 10,000  feet
in the  Gulf  Coast.    Alteration  of  smectite  to  illite  (mixed-layer
clay) begins at a depth of  6000  feet (Figure  3)  and  continues until
a  near  total   transition  has   occurred   by  a  burial   depth  of
approximately 10,000  feet  in the Gulf Coastal Plain  (Powers, 1967).
                                    -172-

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Below 14,000 feet in the Gulf  Coast,  there  is no swelling component



remaining in the illite (Burst, 1959).







Borehole  closure by  plastic  flow  is  associated with  high  pore



pressure shales being relieved of  the overburden stress by penetra-



tion of the drill bit.  This geopressured zone (plastic flow) occurs



at approximately 10,000  feet in the Gulf Coastal  Plain (Figure 3).



Because the  pore pressure and shale  plasticity is abnormally  high



relative to  the overburden  strata, the  shale is extruded  into the



borehole by plastic flow if  the drilling fluid pressure (mud column



weight) is  less than the  fluid pressure   in the rock pores  being



drilled.







Drilling muds are generally conditioned to prevent borehole closure.



If the mud breaks down or settles out, the borehole will seal itself



by  natural  closure  (Ammons,  1987).     Johnston and  Knape  (1986)



reported after  interviewing several experienced drilling engineers



that the geologically young and unconsolidated sediments of the Gulf



Coast tend  to slough and swell, and  an uncased borehole will  com-



monly  squeeze  shut within  hours, resulting  in  natural  borehole



closure.  According to Cheatham (1984), shale hydration has been one



of  the  more  significant causes of borehole  instabilities in the



past; however,  improved drilling fluids  in the last 20  years  have



provided  better  control  of   swelling   shales.    Therefore,   old



abandoned wells which  typically  did  not  have  good  drilling  muds



would have exhibited natural closure even more rapidly.
                                 -173-

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Reentering  and plugging  abandoned  wells near  Du  Pont  injection



facilities  in  the  Texas Gulf Coastal  Plain  has confirmed  that  the



boreholes are  closed by natural  processes (Klotzman, 1986;  Meers,



1987).  Old abandoned boreholes have healed across shale sections to



the extent that the reentering is like drilling a new hole.   Natural



borehole closure is also verified by day-to-day  experience  of field



engineers who  encounter difficulty  in keeping boreholes  open while



drilling, running casing, and logging.  Our experience  in this area



indicates that borehole closure while running casing can result in



being stuck ("wall stuck") in the well and not able  to  bring circu-



lation of fluids ("break circulation") to the surface.   Generally a



wiper trip is made (drill bit is run in the hole and the borehole is



conditioned with mud)  to keep  the  borehole  open for logging  if it



needs to be left open for more than 24 hours.








Typically,  dry holes drilled  in the Gulf Coastal  Plain have  been



abandoned with surface  casing set  and  plugged, but without  long



string casing, thus providing  ready opportunity  for  natural closure



below surface casing.








Consolidated formations, such as  in west  Texas,  are  generally rigid



("hard rock") and lack  the shale  mineralogical properties that help



the  borehole  to  close by  caving  or sloughing  (see  Figure  4).



Abandoned  wells may  remain open  here  indefinitely  because  the



factors for natural closer are  limited.   Lost circulation zones are



more  common in consolidated rock areas  where  drilling  fluids  and



cement may  have been  displaced  from  the borehole.   Johnston  and
                                   -174-

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Knape (1986) stated  that  abandoned wells in this  region may remain



open for many  years,  and  reentering the boreholes for  plugging may



be done by merely washing down with a  drill  bit.  Most reports of



leaking  abandoned wells  or  groundwater  contamination  have  been



reported as occurring in consolidated  rocks  (Johnston and  Greene,



1979).







A  major  exception  to the  normal  stability  of  the West  Texas



boreholes  is  exhibited  in uncased  sections  of  wells penetrating



shale formations of the Triassic  "red beds".  These beds consist of



water-sensitive  clays  which  swell  and  slough  in  the   borehole,



causing well construction problems and total hole  closure during and



after well abandonment.   This  is typically below the  base of the



surface casing in  a  well  where the long-string casing  is  absent or



has  been  pulled  for  salvage  prior  to abandonment  (Johnston  and



Knape, 1986).







DRILLING METHODS








The  method used to  drill a well can  influence  the  potential  for



leakage  after  it  is abandoned.   Three dominant drilling  methods



examined were  rotary mud,  rotary air, and cable tool.







Rotary  drilling  with  mud  as  the  drilling  fluid  has   been  the



preferred  method,  especially in  the Gulf  Coastal Plain,   since its



invention  in 1901.   It  is  almost impossible to drill shale  with
                                   -175-

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other techniques  in  coastal  plain areas and keep the borehole  open



to advance the bit and casing.







The  rotary mud  rig uses  a  water-based  drilling  fluid (mainly  a



suspension of bentonite,  a swelling clay), weighting material,  and



chemical  additives  as  a  medium  to  carry  drill   cuttings  to  the



surface,  control  pressures  encountered in underground  formations,



and lubricate the bit.







In most wells drilled prior to the 1930's, rotary drilling fluid was



a mixture of water and the drill  cuttings.   This was  called  "native



mud", derived from the clay  formations  penetrated by  the drill  bit.



Water was continually added  to  thin native muds,  and  the  minimum



weight  for  these drilling  fluids was probably not less  than  9



Ibs/gal (Johnston and Knape,  1986).







When a  well  reaches logging  depth,  the mud is conditioned  to  keep



the  borehole open  prior to  running geophysical logs   (a practice



since the  1930's).   The  density of mud left in the borehole can be



determined from plugging records or from the geophysical log header.








Rotary  drilled dry holes can be  assumed  to have been left  full of



mud as  a  minimum condition  because  there is no economic  reason to



recover the  drilling mud prior to abandonment  (Johnston and Knape,



1986).  However,  if  the  mud  were  recovered for another  project, the



borehole  would  be  filled  with  a  bentonite   type mud.    Totally



removing  the mud system  from the borehole  with  the drill  pipe on
                                    -176-

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bottom of  the well  is taking  an unnecessary  risk  of getting  the



drill pipe (salvagable material) stuck in the hole, because removing



the mud can cause hole instability and caving.







Mud  density,  primarily used  for well  control  while drilling,  can



also be used  to prevent interformational fluid flow.   Permeability



of the mud left in the borehole is less than the surrounding produc-



tive formations and the pressure maintained by the mud column in the



hole  is  high  enough to prevent the displacement of the  plugging



material.    Drilling  fluid  that  is  suitably  conditioned  after



drilling can satisfy these requirements (Polk and Gray, 1984).







In plugging  mineral exploration holes, Polk and Gray  (1984)  found



that by  increasing mud viscosity  to 20 sec/quart,  the  exploration



holes  that were drilled were  sealed with permeabilities  less  than



10"8  cm/sec.    The  sealing effectiveness  of  the mud  conditioner



treatment was  confirmed by observations of  surface  hole  intercepts



made during the  mining operations.  This fact minimizes  the chance



of encountering a  truly open conduit in an  abandoned dry well which



was rotary drilled using mud.








Cable  tool drilling is sometimes  used  in consolidated  rock forma-



tions, but  it has  not been used  very  much in unconsolidated  rock



regions for  the past  50  years  because  caving sands and sloughing



shales caused  operating problems.   If a well were drilled by cable



tool or rotary air drilling methods, then the fluid  in  the hole is



probably native  water or  brine.  Generally,  cable  tool  holes  are
                                  -177-

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hard to locate because the surface casing was never cemented and was



removed after drilling.








HUD HEIGHT








The  mud column  provides a  downward force,  or higher  hydrostatic



head, than the fluids  in formations  encountered by the  drill bit to



maintain well control  (keep the well from "blowing out").  This same



mud column can keep the  abandoned well  bore  from  "breaking out" due



to  injection in other  wells,  if  the  formation  pressure  is  not



increased above the hydrostatic head of the mud column.   Figure 5 is



an example of pressure resistance of a  static mud column exerted at



different depths  and  mud weights.   Figure 6  represents  normal for-



mation  pressure   at  depth  for two  pressure  gradients.   Figure  7



represents pressure resistance differential based on the hydrostatic



pressure resistance of the  mud column minus  the formation pressure,



for  several  different cases.   Formation  pressure must  be  greater



than the pressure resistance of the  mud column to cause movement of



fluids  in the  improperly plugged borehole.   This  is  a  conservative



calculation because  it assumes no credit  for  borehole  closure, gel



strength, or  pressure required to break  the mud  cake  gel at the



borehole face.








High-density  muds  undergo density changes  due  to   gravitional



settling.   In a  field experiment,  Cooke, et al   (1983,  1984)  made



direct determinations  of change in the density of bentonite mud left



standing in the  annular  space  where  pressure  transducers at various
                                    -178-

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levels  along the  outer casing  were located.  The water-based  mud



weighted with barite  to 11.0 Ibs/gal was reduced  to  9.1  Ibs/gal in



eleven months.   The weight of natural  and  modern muds left  in  the



borehole have a reported low range of 9 to 9.5 Ibs/gal (Price, 1971;



Johnston and Knape, 1986; Collins,  1986;  Davis, 1986; and  Alford,



1987).   A 9  Ibs/gal  mud would  be a conservative  value  to  use in



modeling  calculations  to predict upward  migration  in  abandoned



wells.   This value of  9  Ibs/gal would  be valid  for rotary  mud-



drilled dry holes and for cased holes with long string or  production



casing  only  if records  indicate  mud/cement left in  the  boreholes.



Of  course,  if the  records  indicate lost  circulation zones, or if



casing is pulled from the borehole, the mud column cannot  be assumed



to  fill the borehole.







GEL STRENGTH







A  second mud  parameter, gel  strength (Gs),  helps prevent  upward



fluid movement in a mud-filled borehole.  Gel  strength is the prop-



erty  which  acts to suspend the  drill  cuttings  in the  static  mud



column  when  circulation stops.    Drilling  mud  gels under  static



conditions as a function of  the amount and  type of clays  in  sus-



pension, time, temperature, pressure, pH,  and chemical agents in the



mud system.  The pressure required to displace the gelled mud can be



significantly large.








Gel  strength may   be   the  main  factor  in preventing  brine  from



migrating up abandoned wells from a fluid flow injection well driven
                                   -179-

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by  pressure build-up  (Collins,   1986;  Johnston  and Knape,  1986).



Collins (1986), in simple  laboratory  experiments  (pipe  with collars



or  shoulders  to  simulate  different  hole  sizes and  filled  with



bentonite mud)  to test gel strength,  demonstrated that mud gel and



hole irregularities interacted to yield  a  large contribution (five-



fold or more increase  in gel  strength) to  sealing pressure and help



prevent upward migration.








Gel  strength  is  increased  by   flocculation  which  enhances  clay



particle contact.  Several  studies were  conducted which showed that



gel strength increases with time  (Garrison,  1939;  and Gray, et al.,



1980) at  borehole  conditions.  An  increase in pH  (Garrison,  1939)



increases gel strength.  High pressures in thousands of psi (Killer,



1963) pressures generally  much  greater than  those  encountered  in



Class II injection wells, decrease gel strength.  The gelling nature



of mud has  been observed and  reported in replugging abandoned wells



(Johnston and Knape, 1986).







Minimum gel strength for drilling muds has been reported as 20 to 25



lbs/100 ft2  (Barker,  1981; Johnston  and Knape, 1986;  Davis,  1986;



Collins,  1986;  and Gurke,  1987)  and  would provide  a  considerable



safety factor  in  modeling most situations.   Figure 8 is  a plot  of



gel  strength  and  pressure  resistance to prevent upward  migration.



The added pressure  resistance for a well 5000  feet  deep  with a gel



strength of 20  lbs/100 ft2  and a  6-inch borehole would equal 50 psi.
                                    -180-

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DEPTH OF INJECTION ZONE







Injection zone depth is important because a  shallower  borehole will



have a  lower hydrostatic head  (downward  force)  due to  the  shorter



fluid column weight in the abandoned well.  A longer column of fluid



(deeper injection zone) can counterbalance more formational pressure



buildup in  the injection zone.  Table  1  shows the hydrostatic mud



pressure for 9.0 Ibs/gal mud at depths  from  1000  to 5000 feet.  The



mud column has a pressure differential resistance to initiate upward



flow (hydrostatic mud  pressure minus formation pressure)  of  18 psi



at 1000 feet, and 90 psi at 5000 feet.







CASING LEFT  IN BOREHOLE







Special attention  should be  placed on abandoned wells with  long-



string or production casing remaining in  the borehole  and left open



to the production/injection zone.    Generally,  if production casing



is intact,  then  a  mud-filled hole cannot be  safely assumed,  unless



records indicate the presence  of  mud or  cement at abandonment  to



counterbalance higher injection pressures.







If an operator abandons  a depleted well or  dry  hole without proper



plugging,  then injected  fluid  from a Class  II well (Figure  2, Well



A) could  enter  the  improperly abandoned well  from  the  same pro-



duction zone (Figure 2, Well D). Another potential avenue for upward



migration exists if the well  is cemented across only part  of the



well bore, and drilling  mud was displaced ahead  of the  cement from
                                  -181-

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the annular  space between the casing  and the open hole  (Figure 2,



Well B).   If cement was not circulated to  the  surface,  the annular



space above  the  cemented  portion would be filled with drilling mud.



If  driving  pressures  are  high   enough,   fluids  can  enter  the



uncemented or mud annulus and migrate upward if  not  cemented above



the injection/production  zone.







The  annular mud space provides   resistance  as  in the  mud-filled



borehole  to  upward migration  because  of the increased hydrostatic



head of the mud  column and gel stength of the mud (Davis, 1986).  In



addition,  in the  Gulf  Coastal Plain,  shale can close  around the



casing and seal  off the borehole.








RESERVOIR PROPERTIES







Transmissivity  and  injection rates  are  the  main variables  that



control  formation pressure buildup in an  injection  zone.   Trans-



missivity is equal  to permeability of  the injection zone multiplied



by  the  pay thickness (injection zone  height).    Figure 9 shows the



relationship between  pressure  buildup and distance from  the injec-



tion well for various transmissivities and injection  rates.  Higher



disposal  injection pressure buildups  are  related  to zones  of low



transmissivity  and  higher flow   rates.    Because flow   rates  are



important to  formation  pressure  buildup,  it  is  imperative  to



consider  other  nearby disposal and production  operations utilizing



the same  injection zone when determining the potential for leakage



through abandoned wells.
                                    -182-

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                     MODELING UPWARD MIGRATION







Well-established, conservative, engineering models are available for



computing  the  pressure at which upward  migration will begin.   The



formation pressure necessary to initiate upward flow (Pf)  through an



abandoned  well  is  determined  first  by calculating  the  pressure



exerted by the well's mud column  and then adding the pressure for



gel  strength  (note  that no additional credit is  taken  for borehole



closure  resulting from  shale hydration  or the  plastic  nature  of



abnormal pressured shales).  Second, the formation pressure prior to



injection  (Po)  is  subtracted  from  Pf.    This  difference  (Pf-Po)



represents the injection formation pressure buildup which  must occur



at an  abandoned well to initiate  upward flow.   This difference  is



the  key for limiting the maximum permissible pressure increase in an



injection  formation  at  the  location  of  an  improperly  plugged



abandoned well.  An equation developed by Barker (1981)  to calculate



the  pressure  resistance  in  an  improperly abandoned  well  is  as



follows:







          Pf = Pt + 0.052*p*H + (0.00333*Gs*H/ Dw)              (1)







where  :  Pf  =  pressure required in the formation to initiate



                upward flow in an abandoned borehole (psi)







         Pt  =  surface well pressure (psi)








          p  =  density of mud (Ibs/gal)
                                   -183-

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          H  =  height of mud column (feet)
                                               2
         Gs  =  Gel strength of mud (lbs/100 ft







         Dw  =  maximum diameter of well bore (inches)








Davis  (1986)  reported  an equation to calculate the  opposing forces



(mud hydrostatic  head  and gel  strength)  that  act in  resistance  to



upward fluid migration along a  uncemented/mud casing annulus if not



cemented above an injection or production zone:








         Pf = Pt + 0.052*p*H +  (0.00333*Gs*H/ Dw-Dc)             (2)








where  : Pf, Pt, p, H, Gs, and Dw are defined as in equation 1 and



        DC = outside diameter of casing (inches)







The AOR for an injection well is dependent upon the following



variables:








1.  unit weight of mud plug, gel strength, and borehole diameter,








2.  reservoir properties: permeability  (k)  and pay  zone  (effective



    injection zone) thickness(H),








3.  injection rates (Q),
                                   -184-

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4.  injection or production operations utilizing the  same  injection



    zone,







5.  initial reservoir pressure and surface pressure,








6.  depth of injection zone,







7.  injection and formation fluid properties.
When  pressure modeling  calculations  indicate  that injection  well



operations are  sufficient  to cause fluid migration in  an  abandoned



well, one of the alternatives previously discussed under AOR must be



pursued.







Figure 10 shows cross-section modeling  calculations for a  reservoir



and  indicates  that with a 9 Ibs/gal mud at 5000 feet,  the  area of



review  for  abandoned rotary drilled  dry wells  would  be  less  than



1000  feet from the injection well.  Figure 11 is a plan view for the



above modeling calculations.







             CASE HISTORIES FOR LEAKING ABANDONED WELLS



                              IN TEXAS







Agency  Information Consultants,  Inc.   (AIC)  of  Austin,  Texas  has



examined  records  on file with  the Texas Railroad  Commission (TRC)



for  pollution  problems  associated with  abandoned  wells  in  the
                                  -185-

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following cases:  1) significant problem  leaking  abandoned wells in



Texas  cited  by EPA  (1975),  (AIC,   1987a),    2)  proper  plugging



hearings from  selected  counties  along the Texas Gulf  Coast (uncon-



solidated rock areas) to determine pollution problems  in connection



with the upward migration of  fluids  in improperly abandoned  wells



(AIC, 1987b),  and  3)  proper plugging hearings for fluid  migration



from improperly plugged wells in unconsolidated (TRC Districts  2, 3,



and  4)  and  consolidated rock areas  (TRC  Districts 7-B, 7-C and 9)



(AIC, 1987c).







CASE 1








The  TRC gained  authority and  funds  in  1967  to  plug those  wells



causing a problem or  presenting a potential pollution  threat.   EPA



(1975) found approximately 830 wells  that were plugged from 1967 to



1974  and  identified approximately  twenty-eight  leaking,  abandoned



wells that were  significant problems  and  reportedly caused by  Class



II  injection wells  (Figure  12,  location  map).    These wells  were



found  in a  review of  the  TRC files  on unplugged  or  improperly



plugged  wells  that  have  been plugged by  State  authority.    AIC



(1987a) studied these 28 problem wells.








The  AIC study  identified  the  following  as  important  factors  that



contribute to  the  potential for upward migration due  to  injection



operations in  the unconsolidated rock areas:   1)  long-string casing



left in  the  borehole and left open  to the production  or  injection
                                   -186-

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zone, and 2) significantly overpressured injection  zones because  of



the low reservoir transmissivity.







Out of  28  problem wells, only  4  leaking  abandoned wells were  from



the  unconsolidated  rock  area   (Figure  12).    Three   improperly



abandoned wells  in the  unconsolidated rock  region had  production



casing set  and left open to the injection zone, providing  a  direct



pathway  to  the  surface  and eliminating  possibilites for  borehole



closure.  In one of these wells, a cause-and-effect  relationship was



shown when  a  suspect  injection well reduced its flow by  two-thirds



and  another suspect  well was  shut in,  the problem well  stopped



leaking.







The fourth well cited in the unconsolidated rock area was  drilled  to



a total  depth of 1395 feet,  abandoned with 21 feet of surface  pipe



in the  borehole  and filled with  heavy mud.   The well suspected  of



causing  the problem injected between 1810 to 1900 feet, or  400  feet



below the depth of the leaking well.  Thus,  this suspect well is not



likely to have been the  cause of  the leaking well.   The most likely



source of salt water  for the abandoned well is the  fact  that fresh



groundwater at this location is very shallow (less than  100  feet).



When  the leaking  well  was  entered to stop  the  leak,  "A partial



obstruction was  encountered at approximately 20  to 25 feet  and  it



was found that a solid obstruction of clay and shale was encountered



at approximately 50 feet.   It  is  obvious  that this  obstruction will



have to  be  drilled out  rather than washed out in order to  properly



plug  the well"  (Eikel,  1969).    This  record  on  the  attempt  at
                                   -187-

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reentering  the  abandoned well  confirms that  borehole closure  can



occur in unconsolidated formations.








In  summary,  improperly  plugged abandoned  wells in  unconsolidated



formations  with  long-string  casing left  open  to  the  injection



interval may have  only mud  and mud gel strength or  formation brine



to withstand pressure buildup.  Thus, depth of injection is critical



in  these cases.   It  is important  to review the  records of  all



production wells within the AOR because they  are commonly abandoned



with casing intact and they have the greatest potential  for  upward



migration.







In 21 of 24  cases in the consolidated rock area,  leaking abandoned



wells were  again  due  primarily to  injection  by the  suspect  wells



into the same  interval to  which the leaking  wells  had  been  open;



but, it was through the production casing or the open borehole.







In the  other  three cases, AIC  (1987a)  could  not find  an injection



well after  searching a  radius of 1.5 miles  for well  No.  25.   In



addition, the  abandoned  well was not  leaking  salt  water but  was



identified  as  a  well  that was not properly  plugged.    A  second



leaking  well was  drilled to  a depth of  4156 feet  in consolidated



formations and abandoned with 112 feet of surface casing in the hole



with  75  sacks  of  cement  and  heavy  mud.     An  injection  well



approximately 3/4 mile away  (injection  zone   518  to 535  feet)  was



suspected of causing the  leak;  however, when  the injection well was



shut down for  a week,  there was no  change   in the  leaking  well.
                                    -188-

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Thus, the  suspect well was probably  not  the cause of  the  leakage.



Additionally,  the  sand  used  for  injection  pinches  out  in  the



direction  of the  leaking well (Krusekopy,  1970).     Lack of  sand



continuity  prohibits  lateral  fluid  migration.   Thus,  the  suspect



well was probably not  the cause of this leakage.   The third leaking



well that did not fit  the same zone as the  suspect well was drilled



to  a total depth  of  4,050   feet  in consolidated formations  and



abandoned  with  101 feet  of  surface  casing  in the hole  and  filled



with mud.   An injection well  approximately  1700  feet away  was sus-



pected of causing the problem.  This injection well was disposing of



salt water  through the  annulus between 354  and 2302 feet.  Modeling



the suspect well  based on the  following limited reservoir  parameters



and sensitivity analysis:







where,  Q  (flow rate) = 110 bpd



        H  (pay zone) =  35 feet



        p  (injection pressure  wellhead) = 175 psi



        r  (radius from well) = 1700 feet








indicated  that  pressure buildup due to injection was approximately



50 psi at the 530  foot depth injection zone.  Assuming 9 Ibs/gal mud



in  the  abandoned borehole,  the  borehole  can only support  10  psi



buildup before fluid migrates  upward (Figure 13, Case No.  3).








In all cases where there was  sufficent reservoir  data  available to



model pressure buildup  at the  leaking abandoned well,  the reservoir
                                    -189-

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pressure buildup  exceeded  the calculated pressure resistance  for  9



and 10 Ibs/gal mud systems (Figure 13).








In nearly all  28  cases cited by EPA (1975), AIC  (1987a)  found that
                                                           •*


records pertaining to  cement and/or mud plugs in  the  leaking  wells



were inadequate, incomplete, or non-existent.  Plugging with mud was



more common  than  plugging  with cement, but  in either  case,  details



on  the mud  weight  ("heavy")  and  cement  (amount and location  of



plugs) are usually not given.  If this  information  is unavailable,



then conservative values should be used in modeling (9 Ibs/gal mud



and no cement).







Two  other  important  mechanisms  that  are  related  to   reservoir



modeling  include well depth and  distance  from leaking  well  to



suspect injection well.  Figure  14  shows that the average depth for



a leaking well in this case study is less than 2500 feet.   Figure 15



shows  that  the maximum reported distance  from a leaking well  to  a



suspect  Class II  injection well  is  less  than 6000  feet and the



average is less  than 2000  feet.  This is  consistent with reservoir



modeling  where greater  formation  pressure  buildup   is  associated



closer to the  injection well.








CASE 2








A  second   study   also  conducted  by  AIC   (1987b)   involved  the



examination  of proper  plug  hearing  files  in  selected  Gulf  Coast



counties.  Proper plug hearings are called by the TRC  "when it comes
                                   -190-

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to their attention  that a well has been  abandoned or is not  being



operated and is  causing or likely to cause pollution  to  freshwater



above or below the below  the  ground  or if gas  or oil is  escaping



from the well,  the commission shall  determine  at a hearing,  after



due notice, whether or not the well  was  properly plugged."   These



hearings are called under Statewide Rule 14  (b)  (2) of  the  "Texas



Statewide Rules For Oil, Gas, and Geothermal Operations."







This study was undertaken  to determine  the  magnitude and  mechanisms



of pollution problems  associated with improperly  abandoned  wells in



unconsolidated sediments.  From six selected counties along  the Gulf



Coastal Plain  (Figure  16), 2531 oil  and  gas fields were examined.



From these  fields,  171 proper plug hearing orders were identified,



only three involved actual leakage incidents of which  only  two were



directly  related to an injection well  (Figure   17).   These  three



pollution incidents were examined to verify the  factors that  caused



the abandoned wells to leak.








Pollution incident  No.  1 consisted of three wells on one  lease that



were in  violation of  proper  plugging.  Subsequent field  investiga-



tions by the TRC revealed that surface pollution existed but was not



the result of upward migrating fluids.  Oil found in a pit  near one



well was  leaking from a  250-barrel tank.   Operator negligence was



cited.








Pollution incidents Nos. 2 and 3 were  the  result of upward migration



of  fluids  due  to  subsurface  injection of  Class II  wells in San
                                   -191-

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Patricio County.   Incident No.  2  involved an  improperly abandoned
production well  leaking oil  to the  surface.   This  well had  been
drilled to 2590 feet.  The well was abandoned with 885 feet of 8-5/8
inch surface casing,  2444  feet of 5-1/2 inch casing,  and 2316  feet
of 2-inch production  tubing in  the hole.   The  5-1/2 inch casing was
plugged back to  2345  feet  and perforations were noted from  2446 to
2590  feet.    The  2-inch tubing  was cemented  to  the surface  and
mud-laden fluid was pumped into the well along with a 25 sack-cement
plug (set at an unknown depth).

A  suspect  injection well was  located approximately 2550  feet  from
the leaking well.  This suspect well was probably not a likely cause
of the pollution because its  injection  interval (5128  to 5132 feet)
is far below the producing interval (2446 to 2590  feet).   In addi-
tion, the leaking well never penetrated the injection interval.   Oil
migration has  probably been  the  result of natural fluid migration
from the production zone through the improperly abandoned production
well.

Pollution  incident  No.  3 involved another  improperly  abandoned
production well, cited for leaking oil and water to the surface from
the thread of  a  "home-made" cap on  the  5-1/2  inch  casing.  The  well
was abandoned  with 210 feet of 8-5/8 inch surface  casing, 1358  feet
of 5-1/2 inch  production casing, and 1355 feet of  2-inch tubing in
the hole.  No  records of cement were found on  this well indicating
that it was ever plugged.  The well  was completed  from 1331 to 1337
feet.  A suspect injection well was located  approximately 1300 feet
                                    -192-

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away and  the injection interval was  from 1110  to  1155 feet.   The



suspect well was permitted  to operate at an average of 300  bbl/day



with maximum surface pressure of 30 psi.







Both  pollution  incidents  Nos.  2  and  3  involved  actual   upward



migration of fluids and  had  protection/production  strings  left  in



the hole, eliminating any possibility of borehole closure.







It is important to note that out of 2531 fields examined (the number



of abandoned wells  may exceed the number  of  fields by a  factor  of



ten) along  the Gulf Coast, only  two  leakage incidents were found.



This case study confirmed that the number of pollution problems  in



the unconsolidated  rock areas is  small  and indicates  that  natural



borehole  closure is an important mechanism  in eliminating upward



fluid migration.







CASE 3








To  enhance   our understanding  and defend  the  conclusions  of  the



second  study,  a third  study  was  conducted of proper plug hearings



for pollution  incidents in  "hard"  and "soft"  regions  in Texas (AIC,



1987c).   TRC Districts 7-B,  7-C,  and 9  were selected  as  the "hard



rock" area and  Districts  2, 3, and 4  comprised  the  "soft rock" area



(Figure  18).    Districts  were  chosen  primarily  for  their  rock



environment and large number of oil and gas fields (i.e., production



wells).
                                    -193-

-------
According to Anzzolin and Graham (1984, citing A. D.  Little), 95% of



all production  wells and 78% of  all abandoned wells  (Anzzolin  and



Graham, 1984) fall within the AOR of Class  II  injection operations.



Accordingly, because each district  contains  a  substantial  number of



oil and gas fields, we can assume that a significant number of Class



II wells  exist in each  region studied.   The study concluded that



pollution incidents  resulting from  Class  II  injection  operations in



"hard  rock"  areas outnumber those  cited  in "soft rock" areas by a



factor  of  10.    Our  conclusions  are  explained  in  the  following



paragraphs.







Proper  plug hearing  files  for  12,461 oil  and gas  fields in  the



"consolidated rock"  area were studied for pollution  incidents  (AIC,



1987c).  Seven  hundred and  ninety  (790) hearing files  were located,



and further examination of  these  files found that 112  hearings were



called  as  the  result  of  fluid  migration from  improperly  abandoned



wells  (Figure 19).







On the  other hand, hearing files for 34,512 oil and gas  fields in



the unconsolidated area were  studied for  leakage incidents.    Six



hundred,  seventy-four  (674)  hearings   were   found   and   only  16



indicated fluid migration.   Nearly three times  as many fields were



examined  in unconsolidated rock  areas as compared to  consolidated



rock areas,  but only 13%  (16)  of the  128 proper plug  hearings from



both areas  resulted from upward  fluid migration  in  unconsolidated



rock.
                                    -194-

-------
The  16 unconsolidated  rock  pollution  incidents  were  studied  to
determine  the factors  which caused  the abandoned  wells  to  leak.
Fourteen of  the pollution  incidents  involved wells abandoned  with
production  casing left  in the  hole;  two  pollution incidents  had
incomplete or nonexistent records.

It  is  important  to note   that  all  sixteen  unconsolidated  rock
incidents  (leaking wells)  were  once production wells, and most,  if
not all, were completed or  abandoned with production casing  intact.
In turn, by improper cementing across production intervals,  improper
abandonment, or both, these wells were left  open to upward migrating
fluids.  Thus, natural  borehole  closure, common  in the Gulf  Coastal
Plain  or  unconsolidated  rock   areas,  was  restricted  because  of
production casing left open to the injection zone.

Regarding  the  112 pollution incidents  in  "hard rock" regions,  AIC
(1987c) noted that the  producing zones were much  shallower  than in
"soft  rock" areas.  Abandoned wells in  "hard  rock" areas would tend
to  have smaller  hydrostatic heads due  to  the  shorter  static  mud
column.     Thus,  pressure  differentials   between  injection   or
production  intervals and  static  mud  columns  are  small  and  more
likely  to  allow  upward fluid  migration than  deeper  injection  or
production zones  in  "soft rock".   "Hard rock" areas accounted  for
87% of  the  total  128 leakage incidents  resulting  from upward fluid
migration.
                                   -195-

-------
CONCLUSIONS







Case studies of Class II injection wells from the Texas Railroad



Commission files showed that only a small number of pollution



problems from leaking abandoned wells are associated with the



Texas Gulf Coastal Plain.  These studies also documented natural



borehole closure as an important mechanism in preventing upward



fluid migration in the unconsolidated rock of the Texas Gulf Coastal



Plain.








The most important factors providing potential for upward



fluid migration due to injection operations in the unconsolidated



rock regions are:  1) production wells which  had protection or pro-



duction casings  left  in the hole  left  open to  the  injection  zone,



eliminating  any possibility of  borehole  closure;  and  2)  signi-



ficantly overpressurized injection zones  because of  low  reservoir



t ransmi ss ivi ty.







The case studies for west Texas (consolidated rock) indicate



a higher percentage of pollution incidents resulting from improperly



abandoned wells.  The important factors relating to upward migration



are: 1)  boreholes abandoned with or without casing remaining open



to  the  injection  zone,  2)  significantly  overpressurized  injection



zones because of low  transmissivity,  and 3)  shallower production or



injection zones  resulting in shorter  static mud columns to counter-



balance increased formation pressure.
                                   -196-

-------
This study of case histories has shown that all of the leaking



abandoned wells could have been identified as potential problem



wells.  Preventive measures could have been taken prior to injection



operation.  We believe operators can  achieve  responsible  compliance



through  the  use  of  historical  records  and  reservoir modeling  to



conduct  injection  operations   in   a  manner  that   protects   the



environment.
                                  -197-

-------
                              TABLE 1








                   MUD WEIGHT PRESSURE RESISTANCE








Assuming  9.0  Ibs/gal mud  and formation  pressure  gradient of  0.45



psi/ft:
Depth
(ft)
1000
2000
3000
4000
5000
Hydrostatic
mud pressure
(psi)
468
936
1404
1872
2340
Formation
pressure
(psi)
450
900
1350
1800
2250
Pr
di
(P
18
36
54
72
90
                                                   differential
                                    -198-

-------
               PROTOCOL FOR  IDENTIFYING
       RBflNDONED WELLS  IN  FM flRER OF  REVIEW
                           SERRCH DHTfl

                            SOURCES
STRTEX
FEDERRL
RECORDS

IWtRNFL
OOCUKMT5

corn.
LOG.
CO. 'S

OIL
COMPPNY
RECORDS
                  IDENTIFY WELLS IN RRER OF REVIEW
                               _L
                PENETRRTE CONFINING -' INJECTION ZONE
                         FORMflTION TYPE
                     UNCONSOLIDHTEDXINDURRTED
                          DRILLING METHOD
                          ROTRRY/CRBLE
                         PLUGGING RECOfiDS
                            RVRILHBLE
                          SERRCH CE^E^^•,
                          INJECTION RNIM3R
                         PRODUCTION RECORDS
  SEflRCH CEJCNT.
 INJECTION HND^OR
PRODUCTION RECORDS
      _L
    PLUGGED

rwjttKLT


Y
OK


MR»ET<*ETER






POTENTIRL UPWRRD MIGRHTION


LOCRTE HBRNDONED
1

MFP WELL LOG
COORDINHTES COORDINHTES

WELL
1



NO UPWRRD MIGRHTION


METHL
DETECTOR

1

OK

SURVEYOR





OTHER
                       WELL  LOCRTED
                                       N N
                                             LOWER INJECTION
                                                 ZONE
                                 LOWER INJECTION
                                     RHTE
                            Figure 1
                            -199-

-------
          POTENTIRL PRTHS OF  FLUID MIGRRTION
              FROM CLRSS  II INJECTION  WELLS
B
                                                           EXPLRNRTION
                                                   fl - CLRSS II  INJECTION WELL

                                                   B - PRODUCTION WELL - COMPLETED IN
                                                      DEEPER ZONE, RNNULUS PRRTIRLLY
                                                      UNCEMENTED TO SURFRCE, FORMRTION
                                                      PRESSURE  » STRTIC RNNULRR MUD
                                                      COLUMN
                                                   C - IMPROPERLY PLUGGED RND RBRNDONED
                                                      DRY HOLE  - PENETRRTING THE
                                                      INJECTION / PRODUCTION ZONE
                                                      FORMRTION PRESSURE » STRTIC
                                                      FLUID COLUMN
                                                   D - IMPROPERLY RBRNDONED PRODUCTION
                                                      WELL - DEPLETED WELL WITH
                                                      PRODUCTION STRING LEFT OPEN TO
                                                      INJECTION ZONE, NO CEMENT OR
                                                      MUD PLUGS
 i
o
o
CN
                                                                  SURFRCE COSING
                                                                  CEMENT
                                                                        ION
                                                                  PERFORATIONS
                                                                  CEMENT
                                                                  DIRECTION OF
                                                                  FLUID MOVEMENT
                              Figure 2

-------
                  Stepwise Dehydration of Clay
             Gulf Coast Well, Chambers County, Texas

                          in Mixed Layer Components
                         From Burst, 1969)
                 w  «.v  -,0  60   80  100
o
I—'
I
           10,000
           15,000
                      ©
i
• Zone « .
^*
                                              Closure
Top Anahuac

* Top Frlo
• Top
 Geopressure
                            10,000
Restricted
Dehydration
Zone
                                              Plastic
                                              Borehole
                                              Closure
                        ±
               15,000
                             Figure 3

-------
                   CONSOLIDATED AND UNCONSOLIDATED
                             BOCK TYPES IN TEXAS
P*.5"S;!«fl5?*^;.T
•&#^^#:£;;#3$
• SA!
:«!?£:-ff7J
•&::':$&£:V'
£$££$•$!
^•Syv-Stt*
M
                                      ;•?(?:%
                                      ^fe^iiwffiwiih.^v

*!
             8
   1
                   IT
      'sa^

  LEGEND

Railroad Commission
District Numbers

Consolidated Sediments
("Hard Rock")

Unconsolldated Sediments
("Soft Rock")
                                    Figure  4
                                    -202-

-------
  5000T-
  4500--
  4000--
                   MUD COLUMN PRESSURE  VS.  DEPTH
  3500--
P
r
e 3000-
s
s
u
r
e
2500--
  2000--
  1500--
  1000--
   500--
           500  1000 1500  2000 2500  3000  3500  4000  4500  5000

                             Depth,  feet
                        	  9  Ibs/gal mud
                        	   10  Ibs/gal mud
                        	 11  Ibs/gal mud
                               Figure  5
                                -203-

-------
                   FORMATION  PRESSURE VS. DEPTH
  5000T
  4500--
  4000--
  3500-
P
r
e 3000-
s
s
u
r
e
2500--
  2000--
  1500-
  1000-
   500--
           500   1000  1500 2000  2500 3000  3500  4000  4500  5000

                            Depth,  feet
                                0.45 psi/ft
                                0.47 psi/ft
                              Figure  6
                               -204-

-------
           PRESSURE  DIFFERENTIAL  BASED ON MUD WEIGHT
                     AND  FORMATION GRADIENT
  400-r
D
i
f
f
e
r
e
n
t
i
a
1

P
r
e
s
s
u
r
e

P
s
i
300--
200--
100--
     0    500   1000  1500 2000  2500 3000  3500  4000  4500  5000

                           Depth,  feet

                     10 Ibs/gal mud & 0.45  gradient
               	 10 Ibs/gal mud &  0.46  gradient
               	  9 Ibs/gal mud &  0.45  gradient
               	  9 Ibs/gal mud &  0.46  gradient
                               Figure 7
                              -205-

-------
                     GEL  STRENGTH  VS.  PRESSURE RESISTANCE
Pressure
resistance (psi)
per 500 ft depth
                 35T-
                 30-
                 25-
                 20--
                 15--
                 10--
                         20     40     60     80     100    120

                       Gel  Strength  (Gs),  lbs/100 sq.  ft.

                           	  6  inch hole diameter
                           	  8  inch hole diameter
                           	 10  inch hole diameter
                           	• 13  inch hole diameter
                             Figure 8
                              -206-

-------
             700-r
           P

           S 600--


           D 500-
           I
           F 4QO--
           F

           I 300--
           E
           N 200--
           T
           I
           A
           L
               0-
               100
               1000

DISTANCE  IN  FEET FROM INJECTION WELL
                                         10000
                                 Q »  10 gpm, T
                                 Q - 100 gpm, T
                        100 gpd/ft
                        100 gpd/ft
             250-r
                                         1000

                         DISTANCE IN FEET FROM INJECTION WELL
                                         10000
                                Q =.  600  gpm, T
                                Q = 1200  gpm, T
                        3700 gpd/ft
                        3700 gpd/ft
            Injection  Zone Pressure  Buildup After  30 Years vs.  Distance
and Relationship Between Transmissivity and Injection Rates.
                                  Figure 9
                                  -207-

-------
                                       AREA  OF  REVIEW  CALCULATION
o
00
        p
        R 400-p
        E
        S
        S
        U
        R
        E
I
F
F
E
R

N
T
I
A
L

P
S
350- =
300--
          250+
200-
          150 +
100--
           50 +
                                     Pressure Buildup From Injection
            100
                                                   1000
                                                                                          10000
                                  DISTANCE  IN  FEET  FROM  INJECTION WELL

                         	 Mud pressure  resistance,  10  Ibs/gal mud @ 5000 ft
                         	 Mud pressure  resistance,  10  Ibs/gal mud @ 2000 ft
                         	 Mud pressure  resistance,   °  IK,-/~,I  -..^ a inAn **-
                         	 Mud pressure  resistance,
                                                9  Ibs/gal  mud @  2000 ft
                                                9  Ibs/gal  mud @  2000 ft
        Area of Review Calculation  Based on Formation Gradient = 0.45 psi/ft,
        9 Ibs/gal Mud at 5000  ft  Depth,  and an Injection Zone where Q = 600 gpm
        and T = 3700 gpd/ft.   Other Weight Muds at Various Depths Shown.
                                                  Figure  10

-------
                               CRLCULRTED PRESSURE INCRERSE DISTRIBUTION
                                        RRER  OF REVIEW CRLCULRTION
O
^>
I
           EXPLRNHTIQN

                 CRLCULRTED RRER OF REVIEW
                                                    •60 PSI
                                                  Figure 11
Q - 600 gpm
T • 3700 gpd/-ft
(30 yr.  Injection)

9 Ibs/gal  MUD ® 5000 FT

-------
                       Cast  1


          CASE HISTORIES RESEARCHED

    FROM TEXAS RAILROAD COMMISSION FILES
                 r
                 •
                                                 YOUNQ

                                                       COOKE
                                                 JACK  /       STEPHENS
                      COLEMAN


                        COMANCHE
HARRIS
                                 DUVAL
        LEGEND


1 •  C«»» Hlitorl** R«**>rch*d
                                 Figure 12
                                  -210-

-------
                                              CASE  1

                      RESERVOIR  PRESSURE  BUILDUP VS. MUD PRESSURE RESISTANCE
I
ho
P
R 800
E
S
g 700-
u
600-
E
D 500
I
F
F 400
E
R
£ 300-
N

200-
A
L 100-
P
Sn
















0_j — ,
I

















170


















15
A^jP
1

















70
^





































50

















250

37



16
s\s*
3* 7

















63
%









500


























50
$
8

















19C
I


800




































600









224
I
60 V>
\Q< //






















13
15 16








500








50

















42
cv
vv
I'Si^
17

















165
/y












400















250

140
/; 90
36 // ,2 /V
^
-------
                                                       CASE  1
                               TOTAL DEPTH OF LEAKING WELLS  VS.  NUMBER  OF  OCCURRENCES
I

I—'
N3
                                                     Occurrences

                                                      Figure  14

-------
                                                      CASE 1

                               DISTANCE FROM LEAKING WELLS TO SUSPECT CLASS  II WELLS
 i
NJ
00

I
              4501-5000


              5001-5500 >5
                        £•£

              5501-6000 $
                                                      10
12
14
16
18
20
22
                                                    Occurrences


                                                      Figure 15

-------
            Case 2
PROPER PLUGGING HEARING SURVEY



 SELECTED GULF COAST COUNTIES
                   Flgure  16
                  -214-

-------
                                           CASE  2
                  NUMBER OF FIELDS  EXAMINED, PROPER PLUG HEARINGS,  AND
               POLLUTION INCIDENTS  REPORTEDLY  CAUSED BY CLASS  II  INJECTION
           1000-r
            800--
           600 —
t_n
I
           400--
           200--
                                     887
                          260
                222
                   47
                              19
                                                554
                                                           405
40
                  Harris      Jefferson
                                        Nueces
                                                San Patricio   Victoria
                                            County
                                                     Figure 17
                                         fields
                                         examined
                                         (2,531)

                                         Proper  Plug
                                         Hearings
                                         (171)

                                         leakage
                                         incidents
                                         (2)

-------
                  CaM  3


    PROPER PLUGGING HEARING SURVEY

SELECTED RAILROAD COMMISSION DISTRICTS
     LEGEND

 Railroad Commission
 District Numbers
 Consolidated Sediments
 ("Hard Rock")
 Unconsolldated Sediments
 ("Soft Rock")


                Figure 18
                   -216-

-------
                                   CASE  3
                 CONSOLIDATED  VS.  UNCONSOLIDATED FORMATIONS
i
to
          35000-
          30000-
   25000-
0
c
c
u  20000-
r
r       '.
e
n  15000-
c       !
e
s
   10000-
                                34.512
                 12,461
           5000-
                                 112
                                                16
                     Consolidated         Unconsolidated

                                 formations
Oil & gas fields

Proper Plug Hearings
(PPH)

PPH's with
well bore leaks
                                                Figure 19

-------
                             REFERENCES



AIC  (Agency  Information Consultants,  Inc.), 1987a, Survey  of Cited



      EPA Problem Leaking Wells in Texas:  Prepared for E. I.



      Du Pont.



AIC   (Agency  Information  Consultants,   Inc.),   1987b,   Survey  of



      Pollution Abatement  Hearings  for Selected  Counties Along the



      Texas Gulf Coast:  Prepared for E. I. Du Pont.



AIC  (Agency  Information Consultants,  Inc.),  1987c,  Survey of Proper



      Plugging  Hearings  for  Fluid  Migration  from  Unplugged  or



      Improperly   Plugged   Wells   in  Texas  Railroad   Commission



      Districts 02, 03,  04, 07B, 07C, and 09:  Prepared for E. I.



      Du Pont.



Alford, S. E., 1987,  Conoco,  Senior Drilling Engineer (drilling mud



      specialist), Houston, TX; personal communication.



Ammons,  C.  T.,  1987,  Conoco,  Drilling Engineer,  Lafayette,  LA;



      personal communication.



Anzzolin,  A.  R.,   and  Graham,  L.   L.,  1984,  Abandoned  Wells—A



      Regulatory Perspective,  in D. M. Fairchild,  ed.,  Proceedings



      of the First National Conference on Abandoned Wells:  Problems



      and  Solutions:     Environmental  and  Ground Water  Institute,



      University of Oklahoma, Norman, OK, p. 17-36.



Barker, S. E.,  1981,  Determining the Area  of  Review  for  Industrial



      Waste  Disposal  Wells:   Master's  Thesis,  The  University  of



      Texas at Austin, Austin, TX, 146 p.



Burst,  J.  F.,  1959,  Postdiagenetic  Clay  Mineral   Environmental



      Relationships in  the Gulf  Coast Eocene,  in A. Swineford, ed.,
                                  -218-

-------
      Clays and Clay  Minerals:  6th National Clays and  Clay  Mineral
      Conference Proceedings, Pergamon Press, 411 p.
Burst, J.  F.,  1969,  Diagenesis of  Gulf  Coast Clayey Sediments  and
      Its  Possible  Relation  to  Petroleum  Migration:   American
      Association of Petroleum Geologists Bulletin, v. 53, p. 73-93.
Cheatham, Jr., J.  B.,  1984, Wellbore Stability:  Journal  of Petroleum
      Technology,  V.  36, p. 889-896.
Collins, R. E., 1986, Technical Basis for Area  of  Review:  Prepared
      for Chemical Manufacturers Association, 112 p.
Cooke,  Jr.,  C.  E.,   Kluck,  M.  P.,  and  Medrano,  R.,  1983,  Field
      Measurement of Annular Pressure and Temperature During  Primary
      Cementing:  Journal  of Petroleum Technology, V.  35, p.  1429-
      1438.
Cooke,  Jr.,  C. E.,  Kluck, M.  P.,  and Medrano,  R., 1984,  Annular
      Pressure  and  Temperature  Measurements   Diagnose   Cementing
      Operations:     Journal  of Petroleum  Technology,   v.  36,   p.
      2181-2186.
Darley,  H. C.  H.,  1969,  A  Laboratory  Investigation  of Borehole
      Stability:    Journal  of  Petroleum  Technology,   v.  21,   p.
      883-892.
Davis,  K.   E.,  1986,  Factors  Effecting the Area  of  Review  for
      Hazardous   Waste   Disposal   Wells:    Proceedings  of   the
      International  Symposium  on  Subsurface  Injection  of   Liquid
      Wastes, National Water  Well  Association,  Dublin,  OH,  p.  148-
      194.
Eikel, B. C., 1969, Assistant District Director, Railroad Commission
      of Texas, letter of August, 20, 1969  to R. D.  Payne, Director
                                   -219-

-------
      of Field  Operations,  Railroad Commission  of Texas:  Railroad



      Commission of Texas file 00000101834.



Engineering Enterprises, Inc., 1985, Guidance Document  for  the Area



      of Review Requirement:  Norman, OK, prepared for EPA.



EPA, 1975,  Proposed Injection Well  Regulations  for Brine  Produced



      with Oil or Gas:   US  EPA Document from J. T. Thornhill  to E.



      Hockman,  24 p.



Fryberger, J. S., and Tinlin, R. M., 1984,  Pollution  Potential from



      Injection Wells via Abandoned Wells,  in D. M. Fairchild, ed.,



      Proceedings  of the  First National   Conference  on Abandoned



      Wells:   Problems  and  Solutions:    Environmental  and  Ground



      Water  Institute,   University  of  Oklahoma,   Norman,   OK,  p.



      84-117.



Garrison,  A. D.,   1939,  Surface  Chemistry of  Clays  and  Shales:



      Petroleum Transactions of AIME, v. 132, p.  191-203.



Gray, G. D., Darley, H.  C.,  and Rogers, W.  F.,  1980, Composition and



      Properties  of  Oil  Well  Drilling  Fluids:     Houston,   Gulf



      Publishing.



Grim, R. E., 1968, Clay Mineralogy (2nd ed.): New York,  McGraw-Hill,



      596 p.



Gurke, R.,  1987,   Halliburton Service Training Course,  Duncan, OK,



      personal communication.



Hiller,  K.  H.,  1963, Rheological  Measurements  on Clay  Suspensions



      and  Drilling  Fluids  at  High  Temperatures and  Pressures:



      Journal of Petroleum Technology,  v. 15, p.  779-789.



Johnston, 0., and Green, C.  J.,  1979, Investigation of Artificial



      Penetrations  in  the  Vicinity of  Subsurface Disposal  Wells:



      Texas Department of Water Resources.
                                  -220-

-------
Johnston, 0.  C.,  and Knape,  B.  K., 1986,  Pressure Effects of  the
      Static Mud Column in Abandoned Wells:   Texas  Water Commission
      LP86-06, 99 p.
Klotzman, 1986, Consulting Geologist;  Concerning  Plugging Abandoned
      Wells Near Victoria, TX; personal communication.
Krusekopy, Jr., H. H., 1970,  Geologist, Railroad Commission of Texas
      letter of January 22,  1970 to R. D. Payne, Director  of  Field
      Operations,  Railroad  Commission  of  Texas:   Texas  Railroad
      Commission file 00000300113.
Meers,  R.  J.,  1987,  Petroleum  Consultant;  Concerning  Plugging
      Abandoned Wells Near Orange, TX; personal communication.
Polk, G., and  Gray, G. R., 1984,  Plugging Mineral Exploration Holes
      with  a  Drilling Fluid  Conditioner,  in D. M.   Fairchild,  ed.,
      Proceedings  of the  First  National Conference  on  Abandoned
      Wells: Problems and Solutions:  Environmental  and Ground Water
      Institute, University of Oklahoma, Norman, OK, p. 295-302.
Powers, M.  C., 1967,  Fluid-release Mechanisms  in Compacting Marine
      Mudrocks  and Their  Importance in  Oil Exploration:   American
      Association  of  Petroleum  Geologists  Bulletin,  v.  51,   p.
      1240-1254.
Price, W. H.,  1971, The Determination  of Maximum Injection Pressure
      for Effluent Disposal  Wells, Houston,  Texas  area:   Master's
      Thesis, The University  of Texas at Austin, Austin, TX, 84 p.
Ross, C. C., and Steed, W. C., 1984, Well Plugging in Texas, in
      D.  M.  Fairchild,   ed., Proceedings  of  the  First  National
      Conference  on  Abandoned  Wells:    Problems   and  Solutions:
                                    -221-

-------
      Environmental  and  Ground  Water  Institute,  University   of
      Oklahoma, Norman, OK, p. 251-270.
Roth, T.,  1987,  Head of UIC  Program  (Class  I)  for State of  Texas;
      Concerning  Number of  Class  II  Injection  Wells;    personal
      communication.
                                   -222-

-------
Biographical Sketches



    James E.  Clark holds a B.S.  in  geology (1972) from Auburn  University and



an M.S.  in  geophysical sciences  (1977)  from Georgia Institute  of Technology.



As a geohydrologist with Law Engineering Testing Co., he worked  on suitability



studies of  salt  domes as repositories for  nuclear waste.   He is  a consultant



with Du Font's  (E.  I.  du Pont de Nemours & Co., Inc.,  Engineering Department,



P. 0.  Box  3269,  Beaumont,  TX  77704)  solid waste and geological  engineering



group and is active in permitting and evaluation of disposal wells.



    Milton  R. Howard received  his B.S.  degree  in geology from Texas  A&M



University  (1985).  He served as a petroleum geologist for SOHIO  and Albaine,



active in on-shore database evaluation and oil and gas exploration.   In 1985



he joined the waste and geological engineering group of Du Pont as a contract



consulting  environmental  geologist  responsible for permitting  and evaluation



of the Federal UIC Class I disposal wells.



    Diane K.  Sparks received her  B.S.  degree (1977) in geology and  her M.S.



degree  (1978)  in  geology  from  Bowling Green  State University.    She  was  a



petroleum geologist with Amoco Production  Company and Helmerich and  Payne,



Inc.   Sparks  is  now a consulting  geologist and  currently  works as a contract



geologist for  the Engineering Service  Division  of Du  Pont,  in evaluation of



Class I disposal wells and fluid migration studies.
                                  -223-

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        Sources of Ground-Water Sal1n1zat1on in Parts of West Texas, U.S.

                     Bernd C. Richter and Charles W.  Kreitler

          Bureau of Economic Geology, The University of Texas at Austin,
             University Station,  Box X, Austin, Texas,  USA 78713-7508
Acknowledgments
    Funding for this project was provided by the Railroad Commission of Texas under
contract no. IAC(84-85)-2122. Appreciation is expressed to Railroad Commission of
Texas personnel at District 7-C in San Angelo, Texas, and to many individuals in
Tom Green, Runnels, and Concho Counties for assistance during data collection.
Tonia J. Clement assisted in data preparation. The manuscript was reviewed by
Jules R. DuBar and Alan R. Dutton, Bureau of Economic Geology, The University of
Texas at Austin. Figures were drafted under the supervision of Richard L. Dillon,
Bureau of Economic Geology.

Abstract
    Determination of chemical constituent ratios allows distinction between two
salinization mechanisms responsible for shallow saline ground water and vegetative-
kill areas in parts of West Texas. Mixing of deep-basin salt water and shallow
fresh ground water results in saline waters with relatively low Ca/Cl,
*Publication authorized by the director, Bureau of Economic Geology,  The University
of Texas at Austin.
                                       -224-

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Mg/Cl, S04/C1, Br/CI, and N03/C1  ratios.  In scattergrams of major chemical
constituents versus chloride, plots of these waters indicate trends having brine
values as high-Cl end members.  Evaporation of ground water from a shallow water
table, in contrast, results in saline water that has relatively high Ca/Cl, Mg/Cl,
S04/C1, and Br/CI ratios. Trends indicated by plots of this water type do not
coincide with trends indicated by plots of sampled brines. Leaching of cultivation
nitrate in areas with a shallow water table accounts for high N03 concentrations in
shallow ground water.

Introduction
    Salinization of soil and shallow ground water and the appearance of vegetative-
kill areas are major concerns of farmers in parts of Texas and in other
agriculturally important areas in the United States. In many parts of the country
natural and agricultural factors are responsible for salinization. In Texas,
pollution hazards associated with the exploration and production of oil are
additional possible sources of salt water. These hazards complicate the problem of
determining the sources of soil and ground-water contamination.
    Residents of Tom Green, Runnels, and Concho Counties in West Texas (Figure 1)
blame oil-field-related activities for widespread contamination. They point out
that (1) water was of better quality before drilling for oil began and (2) locally,
formerly productive land has become so salty that plant growth is limited or has
ceased. Many cases of oil-field-related water and soil pollution, caused by brine
flow from abandoned holes and leaky injection wells, are known in the area.
Unknown, however, is the areal extent of contamination that has occurred or is
occurring from thousands of oil wells, core holes, shot holes, and injection wells
and from the use of open pits for brine disposal, a practice which was abandoned in
the late 1960's. The area is underlain by an artesian brine aquifer (Coleman
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Junction aquifer, Table 1) that flows to land surface where pathways are provided
and that stratigraphically overlies most of the major oil-producing horizons in the
area. Therefore, most holes drilled for oil penetrate this aquifer and thus create
a potential, artificial pathway for brine movement into shallow fresh ground water
or to land surface.
    Researchers (for example, Reed [1962] and Marshall [1976]) claim that a
combination of natural conditions and inappropriate agricultural and water-well
drilling techniques is responsible for salinization of soils and ground water in
the area. During severe droughts in the 1950's many water wells that had run dry
were deepened until saline water was encountered (Marshall, 1976). Many of these
wells have not been plugged (Marshall, 1976) and therefore constitute a possible
source of ground-water pollution. At about the same time, extensive closed-contour
terracing of land and destruction of former drainage networks began in the area in
an attempt to reduce surface runoff. Unusual heavy rainfalls in the early 1960's
following the droughts of the 1950's and the practice of land terracing have had
the combined effect of gradually raising the water table closer to land surface
during the last 30 years. Today, ground water stands at or within a few feet of
land surface in many topographically low localities in the eastern part of the
area, causing waterlogging and subsequent salinization of vadose and ground waters
owing to evaporation. Salts that precipitate in the soil during this process
inhibit growth of non-salt-resistant plants and are dissolved and flushed into
ground water after rainfall, thus spreading the pollution hazards to other areas.
These processes occur in the absence of any oil field activity or artesian brine
aquifers, as evidenced by hundreds of thousands of acres affected throughout the
Great Plains from Texas to Montana (Miller et al., 1981).
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Purpose
    This study was designed to discover whether certain hydrochemical methods, such
as determination of Na/Cl, Br/Cl, and I/Cl ratios, could differentiate surface
salinization caused by evaporation from a shallow water table from surface
salinization caused by discharge (natural or man-made) of deep-subsurface brine
aquifers. The study was conducted from January 1 through April 30, 1985. Water
samples were collected from water-supply, oil, and injection wells for chemical and
isotopic analyses designed to establish the chemical characteristics of ground
water in the area.

Geologic Setting
    The study area is underlain by Permian to Quaternary sediments (Figure 1).
Cretaceous rocks, which consist of argillaceous limestone, form topographic highs
that border the study area in southern, western, and northern Tom Green County.
southern Concho County, and northeastern Runnels County. Pleistocene and Recent
alluvial deposits of variable thickness directly overlie Permian strata in central
and eastern Tom Green County and parts of Runnels and Concho Counties. Permian
strata crop out in north-south-trending belts in central Tom Green and northern
Concho Counties and are scattered throughout Runnels County. Permian strata dip to
the west and northwest at approximately 50 ft/mi (10 m/km) and include sandstone,
limestone, shale, gypsum, and dolomite beds (Willis, 1954).
    Thousands of oil wells have been drilled in the area since oil exploration
started at the end of the last century. Most oil production is from Pennsylvania*!
strata at depths greater than 3,000 ft (915 m) in the western part of the area and
greater than 2,000 ft (610 m) in the eastern part of the area. Some production is
from shallow depths from the San Angelo Formation (Table 1), approximately 1,000 ft
(305 m) below land surface, in southwestern Tom Green County. Oil has been
                                       -227-

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encountered in wells within 50 to 300 ft (15 to 90 m)  of land surface in the San



Angelo area in western Tom Green County (Udden and Phillips, 1911).







Hydrogeologlc Setting



    Cretaceous limestones and Quaternary alluvial  deposits form principal aquifer



units bordering the area (Table 1). In the remainder of the three counties, no



extensive, major fresh-water aquifers are present at shallow depths. Local  supplies



of potable water are found in outcrops of Permian limestone and gypsum. However,



the quality and quantity of ground water is very erratic in these units. Many dry



holes have been drilled in the immediate vicinity of high-capacity wells. At one



location in northern Concho County a 100-ft (30-m) deep dry hole was drilled just



20 inches (50 cm) from a flowing well of the same depth, which indicates that



ground water flows through solution channels or fractures in that area.



    Saline water is encountered downdip of potable water supplies in outcrops of



Permian strata. Highly mineralized water occurs under artesian pressure and at



shallow depths in the Permian San Angelo and Blaine Formations (Table 1) of west-



central Tom Green County (Udden and Phillips, 1911; Willis, 1954). The brine



aquifer in the Permian Coleman Junction underlies the area at depths between



3,000 ft (915 m) in the southwest and 800 ft (245 m) in the east. Brine has the



potential to flow to land surface from this aquifer via natural and artificial



pathways, with surface-casing pressures exceeding 100 psi in individual wells in



Runnels County (Raschke and Seaman, 1976).



    Water levels in eastern Tom Green County have generally increased during the



last 30 years but remain 50 ft (15 m) or more below land surface. In contrast, in



southern Runnels County water levels approach land surface in many wells, causing



seepage of ground water at topographically low areas.
                                      -228-

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    Marshall  (1976) reported that probably hundreds of water wells were drilled
down to depths of 500 ft (150 m) west of the city of San Angelo during the drought
in the 1950's, and, although these wells encountered highly mineralized water, many
of them were not plugged. These water wells create a pollution hazard by allowing
saline water to mix with potable water resources (Marshall, 1976).

Geochemical Approach
    In a study of salt-water sources in north-central  Texas, Richter and Kreitler
(1986) showed that differences in ratios of Na/Cl, Br/Cl, I/C1, Mg/Cl, K/C1,  and
(Ca+Mg)/S04 indicate two salt-water types. (1) Salt water derived from dissolution
of halite by fresh water relatively close to land surface is characterized by Na/Cl
and (Ca+Mg)/S04 molar ratios of approximately 1, and by low Mg/Cl, K/C1, Br/Cl, and
I/C1 ratios. (2) Salt-water derived from deep-basin brines is characterized by
Na/Cl ratios of less than 1, (Ca+Mg)/S04 molar ratios  of greater than 1, and high
Mg/Cl, K/C1, Br/Cl, and I/C1 ratios. This differentiation worked especially well at
concentrations of greater than 10,000 mg/L of total dissolved solids. In addition,
stable isotopes of oxygen and hydrogen characterized halite-dissolution brine as
local, meteoric ground water. Deep-basin brine proved  to be of nonlocal origin.
    Two principal sources of saline water exist in Tom Green, Runnels, and Concho
Counties: deep-basin brines and agricultural salinization. Goals of the present
study were to obtain clear definitions of deep-basin brine characteristics and of
seep-water characteristics using the parameters previously mentioned. However, in
contrast to the study by Richter and Kreitler (1986),  most of the polluted ground
waters in the area are of relatively low salinity (less than 5,000 mg/L) and
halite-dissolution brine is not present.  Therefore, it was unknown how well  these
ratios could be applied in this case.
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    In the present study, nitrate was chosen as an additional possible tracer of
pollution sources. Shallow ground water in the Runnels County area typically
exhibits high concentrations of nitrate owing to dissolution of cultivation nitrate
by water recharging through the vadose zone {Kreitler, 1975). High nitrate
concentrations in shallow ground water are caused by changes in agricultural
practices in the area. Dryland farming prior to the 1950's had caused oxidation of
organic nitrogen to nitrate in the soil zone. Nitrate was leached below the root
zone by percolating ground water but was out of contact with the water table until
the late 1950's and early 1960's, when extensive terracing raised the water table
to within a few feet to land surface. The latter caused leaching of nitrate into
shallow ground water (Kreitler, 1975).   Ground water at or slightly below land
surface in seep areas, therefore, could contain elevated nitrate concentrations.
Deep-basin brines, in contrast, normally do not contain appreciable amounts of
nitrate.
    Brines in the area were expected to be isotopically enriched in oxygen and
deuterium with respect to fresh ground water. Evaporation of ground water from a
shallow water table also may result in an isotopic shift toward higher values.
Therefore, seep waters too were expected to be isotopically heavier than local
precipitation. The magnitude of the shift and the difference between brines and
seep water, however, were not known.
    In addition to water sample data obtained from published and unpublished
sources, 46 samples were collected during this study: 39 from shallow water wells
and 7 from oil field wells and holes (Figure 1, Table 2). Five of the 39 samples
were obtained from shallow wells drilled in seep areas. Three of these were from
water wells and two from shallow holes drilled for this investigation.
    To establish the characteristics of water types, sampling included (1) oil
wells, (2) a Coleman Junction well (3) allegedly polluted wells, (4) stock wells,
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(5) house wells, and (6)  seep wells.  Samples for chemical  analyses were stored in
500 ml polyethylene bottles,  and samples for isotope analyses were stored in 250 ml
glass bottles. During collection, samples were filtered using 0.45-micron membrane
filters and nitrogen gas  to remove particulate matter.  The filter bottle was
cleaned thoroughly between samples and checked for residual  ion content, using
distilled water and silver nitrate, to prevent cross-contamination of water
samples.

Results
    Data from previous investigations, when plotted on  Piper diagrams, show that
ground water in Tom Green County is characterized by four  chemical  facies.  At
chloride concentrations of less than  250 mg/L, Ca-Mg-HC03  water is the major facies
type (Figure 2). This type occurs predominantly in Cretaceous (limestone)
formations. Another facies type is Ca-Mg-S04 water, the result of dissolution of
gypsum or anhydrite in Permian strata. At chloride concentrations of greater than
250 mg/L, an increase in  sodium and especially chloride percentages results in Ca-
Mg-Cl and Na-Cl waters (Figure 2). In Runnels County, cation percentages in ground
water are evenly distributed without  a shift toward sodium dominance at chloride
concentrations of greater than 250 mg/L (Figure 2). Anions too are distributed
relatively evenly at chloride concentrations of less than  250 mg/L, but show a
shift toward the chloride apex at chloride concentrations  of greater than 250 mg/L.
Therefore, at chloride concentrations of greater than 250  mg/L, Piper diagrams of
ground water in Tom Green and Runnels Counties indicate that different mechanisms
control the distribution  of cations in ground water in  the two counties.
    Only 6 of 39 water samples collected during this study contain chloride
concentrations of less than 250 mg/L  because emphasis was  put on collection of
allegedly contaminated ground water.  The configuration  of  data points from these
                                      -231-

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samples within a Piper plot (Figure 3)  is similar to the distribution of data
points in the plot of ground water in Tom Green County for chloride concentrations
of greater than 250 mg/L (Figure 2). Most of the samples collected during this
study are of the Ca-Mg-Cl  or Na-Cl types. Within the cation triangle, a linear
trend between Ca-Mg-dominated ground water and Na-dominated brine is indicated.
    On bivariate plots of Ca, Mg, $04,  and Br/Cl versus Cl, evolution or mixing
trends are indicated that contain fresh water and brine as end members (Figure 4).
At high chloride concentrations, the plots of Mg and $04 versus Cl suggest that
possibly two trends exist, where one trend points toward brine values and is
relatively low in Mg and $04 and the other points away from brine values and is
relatively high in Mg and $04. Bromine  and nitrate were the only minor chemical
constituents that were above detection  limits both in the brine and in the ground-
water samples and that showed some differences between water samples. Ratios of
Br/Cl in brines underlying the area are lower than ratios in, for example, shallow
subsurface brines in the southern Rolling Plains of North-Central Texas and in oil
field brines of Kansas (Figure 4). In contrast, Br/Cl ratios in fresh water are
typical of this water type. With increasing chlorinity, Br/Cl ratios in ground
water in the area decrease to values similar to Br/Cl ratios in brines underlying
the area, possibly indicating a mixing  trend between fresh ground water having high
Br/Cl ratios and brines having low Br/Cl ratios.
    Nitrate concentrations range from less than 1 mg/L to more than 200 mg/L
(Table 2). Lowest concentrations were measured in ground water in western Tom Green
County and in central Runnels County, as well as in brines underlying the area.
Concentrations in excess of 100 mg/L prevail in northeastern Tom Green County,
southern Runnels County, and northern Concho County (Figure 5). Four of five seep
samples have nitrate concentrations of  between 121 mg/L and 158 mg/L.
                                       -232-

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    A differentiation of salinization sources by use of stable isotopes of oxygen
and hydrogen was not possible from analyses obtained during this study. All
samples, regardless of chlorinity and geographic or stratigraphic origin, plot
within one cluster and indicate no apparent trends (Richter and Kreitler, 1985).
Mixing and dilution of waters from different sources may account for this
relationship between water types and isotopic composition.

Discussion
    Water-table elevation is close to land surface in many topographically low
areas in Runnels, Concho, and eastern Tom Green Counties,  whereas it is well  below
land surface throughout western Tom Green County.  Associated with a high water
table, saline seeps and vegetative-kill  areas are  widespread phenomena in the
eastern part of the area but are less frequent in  the western part. Therefore,
salinization by evaporation should be more prevalent in the eastern part of the
area than in western Tom Green County.
    Mixing between brine and fresh water seems to  be indicated in 16 of the 39
water samples, as suggested by ratios of major chemical constituents in ground-
water samples when compared with ratios  typical of sampled brines in the area
(Table 2). Of these 16 samples only 4 were obtained from Runnels County, Concho
County, and eastern Tom Green County, whereas 12 were obtained from western Tom
Green County. The remaining 23 water samples, which include only 3 from western Tom
Green County, do not indicate any similarity with  brines underlying the area.
    Grouping of the data according to sample location (east versus west) breaks up
the cluster and the tentatively suggested trends of Figure 4 into two, fairly well-
defined trends (Figure 6). Trend 1, characterized  by high Ca, Mg, and $04
concentrations, is made up mainly of samples from  Runnels, Concho, and eastern Tom
Green Counties. This trend does not include values typical of brines in the area,
                                       -233-

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which indicates that a salinization mechanism other than mixing of fresh ground
water and deep-basin brine is responsible for increases in salinity in ground water
of the area. Possible mechanisms are (1) evolution of ground water through mineral
dissolution, (2) mixing of different ground-water types, and (3) evaporation from a
shallow water table. Trend 1 approaches a slope of one in the bivariate plots of
molar concentrations, which eliminates the possibility of mineral dissolution as
the most dominant salinization mechanism. During evaporation, the molar ratios of
chemical constituents stay constant in absence of precipitation or dissolution
reactions. Also, the relative position of cation percentages in a Piper diagram
does not change during evaporation, which is suggested for water samples from the
east (Figure 7). In contrast, two water types would be expected to plot within two
discrete clusters in a Piper plot, where mixing would be indicated by a trend that
connects the two clusters. Although the possibility cannot be dismissed that two
nonrelated waters fall within the same cluster, it seems most likely that
evaporation is the mechanism that accounts for the trends observed in the Piper
plot and in the bivariate plots for waters from the eastern part of the area.
Trend 2 is made up of samples low in Ca, Mg, and $04 and is represented by samples
obtained mainly from the western part of Tom Green County. This trend includes
values of Coleman Junction and oil field brines as high-chloride end members,
suggesting mixing of fresh ground water and brine rather than evolution of fresh
ground water to a brine through water-mineral reactions. At low concentrations of
dissolved chemical constituents, the two trends overlap and do not allow
differentiation of salinity sources. As chloride increases, the trends increasingly
deviate from each other, making it possible to determine salt-water sources.
    Seep samples, although not indicating mixing of fresh ground water and brine in
any of their chemical constituents (Table 2), do not plot clearly within Trend 1
but within the zone of overlap between Trend 1 and Trend 2. Because sample
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collection was during early February, when the effects of evaporation are at their
lowest, seep samples are similar to other samples from the area. It can be expected
that seep samples collected during summer months will plot as high-chloride end
members of Trend 1. Four of the five seep samples (6, 7, 8, and 10) were obtained
from wells in topographically low areas where the water table was within a few feet
of land surface, indicating stagnant water- These samples have nitrate
concentrations in excess of 100 mg/L owing to dissolution of nitrate in the shallow
soil zone. Seep sample 11 was obtained from a flowing well that is used to drain
the seep area in an attempt by the owner to reclaim waterlogged land. According to
the owner, this well stops flowing whenever irrigation from nearby wells is
activated. Therefore, the sample from this well is part of an active ground-water
flow system (activated by the well), in contrast to a sluggish or stagnant ground-
water system at the other seeps. Continuous flushing of this particular flow path
may explain the low nitrate concentration of sample 11 when compared with other
seep samples.
    Samples 2 and 4 are high-chloride waters that were obtained from wells in
central Runnels County. These samples consistently fall within Trend 2, which is
the trend of samples from western Tom Green County. This suggests that two sources
of salinity exist in the eastern part of the area. Most samples follow Trend 1, and
therefore evaporation seems to be the most dominant salinization mechanism. The
distribution of cations from samples in the east form one big cluster in a Piper
plot (Figure 7), similar to the cluster typical of Runnels County at chloride
concentrations of greater than 250 mg/L (Figure 3). This indicates that the samples
obtained during this study are representative of the area and that salinization
through evaporation is of widespread nature. In contrast, few samples from the east
follow Trend 2, suggesting that mixing between fresh ground water and brine is a
local  phenomenon in the area. Samples 2 and 4 were obtained from abandoned water
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wells close to producing oil wells. Ratios of Br/Cl  and concentrations of N03 in
both samples are very low and similar to brine values, which is atypical of ground
water in the Runnels County area. Therefore, the location and the atypical chemical
composition of the two samples indicate that mixing of fresh water and brine
accounts for the salinity of the samples. In western Tom Green County, mixing of
fresh ground water and brine seems to be an area! phenomenon. All but three samples
indicate mixing in at least one of the major chemical constituents, Ca, Mg, and $04
(Table 2), and more than half of the samples indicate mixing in two or all of these
constituents. Mixing is also indicated by the cation percentages of ground water in
western Tom Green County, as shown by a linear trend from Ca-Mg-dominated water to
Na-dominated water (Figure 7). This trend could also be interpreted as an evolution
trend. However, considering the position of brine and ground-water values of
Trend 2 in the bivariate plots (Figure 4), mixing rather than evolution through
mineral reactions appears to be the most likely explanation for this cation trend.
    Some Br/Cl ratios seem to be additional tracers of salinization sources, with
ratios of less than 30 X 10~4 being indicative of possible mixing of brine and
fresh ground water. However, absolute bromide concentrations, the range of bromide
concentrations, and the range of Br/Cl ratios in all samples are relatively small
in this study, which makes Br a less favorable tracer. Ratios in seep samples fall
within the range of ratios in fresh ground water and are only twice as much as
ratios of Br/Cl ratios in brines underlying the area. In comparison, differences in
Br/Cl ratios of approximately 1:10 were used by Whittemore and Pollock (1979) and
by Richter and Kreitler (1986) to distinguish brine sources. Even more important,
at concentrations of approximately a few mg/L of Br, analytical errors will greatly
affect Br/Cl ratios. For example, a bromide concentration of 1.5 mg/L places
sample 24 within the field of possible mixing of brine and fresh water (Figure 6,
Table 2). In contrast, a concentration of 2 mg/L would place this sample within the
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range of fresh water and seep water in the area. Similarly, nitrate concentrations
may or may not serve as additional tracers of salinization sources. In Runnels
County, where extremely high nitrate concentrations in shallow ground water have
been measured for the past 15 years, low nitrate concentrations in combination with
high chloride concentrations may indicate mixing of fresh ground water and brine,
the latter being high in Cl and low in N03. In contrast, high chloride
concentrations combined with high nitrate concentrations may suggest a common
source of Cl and N03, such as animal waste. However, mixing of Cl-rich brine and
N03~rich ground water would result in a similar relationship between chloride and
nitrate. In western Tom Green Counties, where nitrate concentrations in shallow
ground water are much lower than in Runnels and eastern Tom Green Counties, nitrate
is a less favorable tracer of salinization sources. In general, N03/C1 and
especially Br/Cl ratios are not good tracers of salinization sources in this study
because of their relatively narrow ranges and overlapping trends. At best, these
ratios can be used as supportive arguments for salinization sources, but within a
suite of diagnostic ratios and plots rather than by themselves.
    There are four possible mechanisms for the mixing of fresh water and deep-basin
brine in the area. (1) Western Tom Green County includes an outcrop of the Permian
San Angelo and Blaine Formations. These formations contain salt water under
artesian conditions downdip, which indicates the potential for natural discharge of
saline water at formation outcrops and by movement across confining layers. (2)
Discharge of salt water from the San Angelo and Blaine Formations is possible
through unplugged, exploratory water wells that were drilled into saline parts of
these aquifers. The locations of these numerous wells are poorly known. (3) Tom
Green County and Runnels County have been sites of extensive exploration for and
production of oil. Most oil reservoirs in the area underlie artesian brine
aquifers, such as in the Coleman Junction, and thus pathways for upward flow of
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brine from the artesian aquifer or from oil reservoirs along poorly cemented wells
may have been created by exploration and production of oil. Also, shallow seismic
holes may connect saline parts of the San Angelo and Blaine Formations with
overlying fresh ground water. (4) Open-surface pits for brine disposal were used in
the area until the late 1960's. This practice of brine disposal was abandoned in
Texas after numerous cases of ground-water contamination by brine had been
documented. However, brine may still be migrating from below these former disposal
areas into shallow ground water. The amount of salt still present in the subsurface
at those sites and the rate of migration are unknown. There are indications that
all of these potential mechanisms of brine pollution were or are active in the
area. At this time we do not have enough data to chemically characterize these
contamination sources and to explain particular mechanisms for mixing between deep-
basin brine and fresh ground water in this part of West Texas.

Conclusion
    In this study, determination of Ca/Cl, Mg/Cl, and SO/j/Cl ratios, and to a
smaller degree Br/Cl and N03/C1 ratios, allowed differentiation between salt-water
pollution derived from evaporation of shallow ground water and pollution derived
from mixing with Na-Cl brine. All these ratios should be considered, rather than
only chloride concentrations or the sole ratio of one constituent over chloride,
because chemical characteristics of these two sources of contamination overlap.
Overlaps are most pronounced at low ionic concentrations because dilution by fresh
water masks chemical characteristics of salt-water sources. Therefore,
differentiation of contamination sources is most successful where concentrations of
dissolved solids are high.
    In western Tom Green County, the chemical composition of ground water appears
to result from mixing of fresh ground water and Na-Cl deep-basin brine. This is
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indicated (1) in Piper plots by a mixing trend between Ca-Mg-dominated ground water
and Na-dominated ground water and (2) in bivariate plots by low Ca/Cl, Mg/Cl, and
S04/C1 ratios that indicate trends with deep-basin brine values as high-chloride
end members. Mixing of fresh ground water and deep-basin brine appears to be an
areal phenomenon, but the mechanism of mixing and the source of salt water are
unknown.
    In Runnels, Concho, and eastern Tom Green Counties, there appear to be two
causes of deterioration of water quality. Most poor-quality waters result from the
evaporation of shallow ground water. These waters typically have Ca/Cl, Mg/Cl,
S04/C1, and Br/Cl ratios that are higher than those observed in sampled deep-basin
brines. On bivariate plots, these waters suggest trends indicative of evaporation,
that is, ratios are constant with increases in salinity. The potential  for ground-
water evaporation and subsequent salinization increases as the water table becomes
shallower. Therefore, salinization by evaporation should be more prevalent in
Runnels County and eastern Tom Green County, where the water table is generally
shallower than in western Tom Green County. In combination with a shallow water
table, nitrate concentrations in most samples from the east are very high owing to
leaching of nitrate in the shallow subsurface. Other poor-quality waters collected
in the area during this study result from mixing between Na-Cl brine and fresh
ground water, which occurs on a local basis. These waters, which were obtained from
shallow water wells close to producing oil wells, have low Ca/Cl, Mg/Cl, SO/j/Cl,
N03/C1, and Br/Cl ratios. The latter water type is similar to brines underlying the
area and to ground water in western Tom Green County, suggesting mixing of fresh
water and brine.
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References
Barnes,  V. E.,  1975,  San Angelo Sheet:  The University of Texas at Austin,  Bureau of
    Economic Geology, Geologic  Atlas of Texas,  Scale 1:250,000.
Barnes,  V. E.,  1976,  Brownwood Sheet:  The University of Texas at Austin,  Bureau of
    Economic Geology, Geologic  Atlas of Texas,  Scale 1:250,000.
Kreitler, C. W., 1975, Determining the Source of Nitrate in Ground Water  by
    Nitrogen Isotope  Studies:  The University of Texas at Austin, Bureau of Economic
    Geology Report of Investigations No. 83, 57 pp.
Marshall, M. W., 1976, City of San Angelo Pollution  Abatement Program,  Water
    Department: Memorandum to  T. L. Koederitz,  P.  E., Water Pollution  Control  and
    Abatement Program Director.
Miller,  M. R.,  Donovan, J. J.,  Bergatino, R. N., Sonderegger, J. L., Schmidt,
    F. A., and  Brown, P. L., 1981, Saline Seep  Development and Control  in  the  North
    American Great Plains—Hydrogeological Aspects,  ^n Holmes, J. W.,  and  Talsma,
    T.,  (eds.), Land  and Stream Salinity: Elsevier Development in Agricultural
    Engineering, v. 2, 391 pp.
Raschke, A. J., and Seaman, W.  H., 1976, Leaking Core Hole Problem Review, Hatchel
    Area, Runnels County, Texas: Railroad Commission of Texas, Oil  and Gas Division
    District 7-C, San Angelo,  Texas, 14 pp.
Reed, E. L., 1962, Letter to Mr. James K. Anderson:  Midland, Texas, April  2.
Richter, B. C., and Kreitler,  C. W., 1985, Sources of Shallow Saline Ground Water
    in Concho,  Runnels, and Tom Green Counties: The  University of Texas at Austin,
    Bureau of Economic Geology, Report prepared for  Railroad Commission of Texas
    under Contract No. IAC(84-85)-2122, 31 pp.
Richter, B. C., and Kreitler,  C. W., 1986, Geochemistry of Salt Water  Beneath  the
    Rolling Plains, North-Central Texas: Ground Water, v. 24, no. 6, pp.  735-742.
                                       -240-

-------
Udden, J. A., and Phillips, W.  B.,  1911,  Report on Oil,  Gas,  Coal  and  Water
    Prospects near San Angelo,  Tom Green  County,  Texas:  Report to  the  Chamber  of
    Commerce, San Angelo, Texas,  36 pp.
Whittemore, D. 0., and Pollock, L.  M.,  1979,  Determination of Salinity Sources in
    Water Resources of Kansas by  Minor  Alkali  Metal  and  Halide Chemistry:
    Manhattan, Kansas, Kansas Water Resources  Research  Institute Contribution
    No. 208, 28 pp.
Willis, G. W., 1954, Ground-water Resources of Tom Green County, Texas: Texas  Board
    of Water Engineers Bulletin 5411, 60  pp.
Work Projects Administration, 1941, Tom Green  County—Records of Wells and  Springs,
    Drillers' Logs, Water Analyses, and Map Showing Locations of Wells and  Springs:
    Texas Board of Water Engineers  Work Projects  Administration, Project  17279,
    80 pp.
                                      -241-

-------
                               List of Figures

Figure 1   Area location map showing outcrop areas of major geologic units
           (from Barnes, 1975,  1976) and location of sample sites.
Figure 2   Piper diagrams of ground-water chemistry in Tom Green and Runnels
           Counties (data from  Work Projects Administration [1941],  Willis
           [1954],  and Texas Natural Resources Information System).
Figure 3   Piper diagram of ground-water chemistry in Tom Green, Runnels,  and
           Concho Counties (data from this study).
Figure 4   Bivariate plots of ground water and deep-basin brine chemistry  in
           Tom Green, Runnels,  and Concho Counties (data from this  study).
Figure 5   Nitrate  concentrations in ground water from Tom Green, Runnels, and
           Concho Counties (data from this study).
Figure 6   Bivariate plots of ground water and deep-basin brine chemistry  in
           Tom Green, Runnels,  and Concho Counties, with data sorted according
           to sample location (data from this study).
Figure 7   Cation diagrams of ground-water chemistry in (a) Runnels, Concho,
           and eastern Tom Green Counties and (b) western Tom Green  County
           (data from this study).
                                       -242-

-------
                                List of Tables

Table 1    Generalized relationship between strati graphic and hydrogeologic
           units found in study area; see text for  discussion (modified after
           Willis, 1954).
Table 2    Chemical  analyses of ground water and brines in Tom Green,  Runnels,
           and Concho Counties.
                                     -243-

-------
 I
ho
STRATIGRAPHIC UNIT
System Formation
Quaternary Alluvium
Cretaceous
Blaine Gypsum
San Angelo
Sandstone

Coleman Junction
HYDROGEOLOGIC UNIT
Yields small quantities of
potable water
Yields potable water from
two aquifer units that are
separated by confining beds
of massive limestone
Yields small amounts of
highly mineralized water
Yields small amounts of
moderately to highly
mineralized water

Highly overpressured brine
aquifer
                                                       Pennsylvanian

-------
Table 2. Chemical  analyses (in mg/L)  of ground water and brines
          in Tom Green,  Runnels,  and  Concho  Counties.
ID Ca
No.
Mg
Na
Coleman
B1+ 2310
B2@ 1940
B30 2500
B4+ 4530
B5$ 1605
B6$ 2400
B7& 931
1120
1059
1122
5
1110
881
696
Ground Water:
1 113
2 255
3 335
4 1172
5 731
6** 350
7** 319
8** 299
9 414
10** 202
11** 585
12 129
13 369
14 273
15 525
16 252
17 359
18 229
19 189
20 185
21 188
22 212
23 157
24 669
35
216
138
524
198
115
154
137
339
82
192
108
50
764
123
82
128
96
62
118
115
111
64
242
25700
22500
22900
31600
7440
26100
15600
S04
Cl
Br
N03
Junction and Oil Field
4080
2310
4170
3750
3390
3930
9
41900
38000
38300
51600
15500
41200
27200
Runnels, Concho,
173
1140
269
1790
249
295
305
289
512
245
633
218
271
952
178
169
334
143
114
91
192
233
156
369
108
378
940
1092
1815
591
567
501
1485
249
2115
251
223
2415
1008
270
174
167
156
474
465
258
261
2040
166
2330
452
5130
595
699
723
685
983
454
735
343
720
1460
516
461
980
454
236
205
367
482
184
639
70.8
70.2
70.9
93.5
37.2
83.4
56.7
and
0.9
5.5
1.8
3.8
2.4
2.5
2.5
2.4
3.2
1.6
3.1
1.6
2.5
8.5
0.2
1.9
3.3
2.0
1.0
0.8
1.4
2.0
0.8
1.5
< 1
< 1
< 1
< 1
< 1
< 1
< 1
Eastern
155
< 1
5
1
32
149
128
158
57
169
< 1
121
165
30
147
115
229
115
98
35
28
131
20
< 1
Ca*
TTT
Mg*
rr
S04*
CT
IT3
(BrxlO4)
Cl
Brines
0.05
0.04
0.06
0.08
0.09
0.05
0.05
Tom
0.60
0.09
0.66
0.20
1.09
0.50
0.39
0.39
0.37
0.40
0.71
0.34
0.46
0.16
0.90
0.49
0.33
0.50
0.71
0.80
0.46
0.39
0.76
0.93
.04
.04
.04
.00
.11
.03
.03
Green
.31
.14
.45
.15
.49
.24
.31
.29
.51
.27
.38
.46
.10
.77
.35
.26
.19
.31
.39
.84
.46
.34
.51
.55
0.03
0.02
0.04
0.03
0.08
0.04
0.00
.00
.00
.00
.00
.00
.00
.00
16.9
18.5
18.5
18.1
24.0
20.2
20.2
Counties
0.24
0.06
0.76
0.08
1.11
0.31
0.28
0.27
0.55
0.20
1.05
0.27
0.10
0.61
0.71
0.21
0.07
0.14
0.24
0.84
0.46
0.20
0.52
1.16
.93
.00
.01
.00
.05
.21
.18
.23
.06
.37
.00
.35
.23
.02
.28
.25
.25
.25
.41
.17
.07
.27
.11
.00
48.2
23.6
39.8
7.2
38.7
34.3
34.6
35.0
31.5
33.0
42.2
46.6
33.3
57.5
3.9
39.0
33.7
41.8
42.4
39.0
38.1
39.4
43.5
23.5
                                -245-

-------
                          Table 2  (continued)
     ID   Ca   Mg   Na    S04   Cl    Br  N03    Ca*   Mg*  $04* N03 (BrxlO4)
     NO.                                        FT    n~   rr   TTT   ~n
    25
    26
    27
    28
    29
    30
    31
    32
    33
    34
    35
    36
    37
    38
    39
                 Ground Water:  Western Tom Green County
268
452
181
448
536
385
188
73
90
212
498
560
519
280
921

97
152
50
139
177
124
69
30
41
89
185
263
223
192
491

243
363
391
731
744
386
232
259
113
422
1770
978
220
284
7185

161
192
284
402
386
131
113
180
128
318
432
462
753
225
2070

735
1310
573
1622
1970
1230
479
211
161
712
3380
2650
1060
976
11630

2.7
4.4
1.9
4.7
5.6
4.3
1.3
0.7
0.6
2.2
6.9
6.2
4.5
3.2
9.9

125
87
29
173
43
63
8
2
2
29
43
41
46
13
13

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

.32
.31
.28
.25
.24
.28
.35
.31
.50
.27
.13
.18
.44
.26
.07

.19
.17
.13
.13
.13
.15
.21
.21
.37
.18
.08
.15
.31
.29
.06

0.08
0.06
0.18
0.09
0.07
0.04
0.09
0.31
0.29
0.17
0.05
0.07
0.26
0.09
0.07

.17
.07
.05
.11
.02
.05
.02
.01
.01
.04
.01
.01
.04
.01
.00

                                                              36.7
                                                              33.6
                                                              33.2
                                                              28.4
                                                              28.4
                                                              35.0
                                                              27.1
                                                              33.2
                                                              37.3
                                                              30.9
                                                              20.1
                                                              23.4
                                                              42.4
                                                              32.8
                                                               8.4
EXPLANATION
$
&
**
0.09
Mol ratios
Leaky injection well  with flow from bradenhead
Flowing well completed and abandoned in the Coleman Junction
aquifer; sample B2 was obtained after 10 minutes of flow,  sample
B3 was obtained after 90 minutes of flow
Flowing core hole, approximately 100 ft deep
Producing oil  well, possibly affected by waterflooding
Seep sample
Ratio similar to ratios of Coleman Junction and oil field  brines
                                     -246-

-------
                                                                                                         ion"
 I
K>
-p-
^J
 I
                                                           EXPLANATION

                                                  o Water well      •  Brine well

                                                                 Cretaceous
                                                                                                                          ;;:; ;j ;; CONCHQ i
                                                                                                                                    QA5896

-------
00
I
                                              CK250 mg/L
                                                      TOM GREEN COUNTY
Cl>250 mg/L
                                                       RUNNELS COUNTY

-------
            EXPLANATION
o  Ground water sample     A  Brine sample
                                QA 5900

-------
                     4000 H
                   0
                   o
                      400 H
Ln
O
 I
                     2400H
                      240H
                                        Log Cl (mmol/L)
                                       I            2
                                      J	i
                                     350
                                                 3500
                                           Cl  (mg/L)
                        35,000
   Log Cl (mmol/L)
 l            2
J	i
                                    350
             I
           3500
      Cl  (mg/L)
                                                            35,000
                                                                         o'

                                                                         E
                                                                                 9600H
                                         O
                                         C/5
                                                                                  960H
                                                                                   60 H
                                                                                   40H
                                                                                   20H
                                                               Log  Cl (mmol/L)
                                                              I            2
                                                            350
                                                                        3500
                                                                  Cl (mg/L)
35,000
                                                                              , Southern
                                                                              I Roljing
                                                                              . Plains of
                                                                              | North-
                                                                              . Central
                                                                              | Texas
                                                                                     100           1000         10,000
                                                                                                       Cl (mg/L)
 100,000
                                                                                                                                QA 5901

-------
                                                EXPLANATION
                                   20  Nitrate  concentration as  N03 (mg/L)
                                   •  Good-quality ground water (Cl < 250 mg/L)
                                   x  Mixing between fresh water and deep-basin brine
 I
N}
Ol
                                                                                                                                     -32°
I    N
                                                                                                         ]28go!58_j2l	RUNNELS |
                                                                                                                                  _    CONCHQ |
                                                                                                                                       QA 5902

-------
                   4000-
                    400-
                                     Log Cl (mmol/L)
                                    I           2
                                   350         3500
                                        Cl (mg/L)
                                                           I
                                                         35,000
                                                                  -2'
                                                                             9600-
                                                                              960-
                                      Log Cl (mmol/L)
                                     I           2
                                     I	I	
                                     I
                                   350
                                               3500
                                         Cl (mg/L)
                                                                                                                   35,000
                                                                                                                           -2
 I
M
Ul
ro
 I
                   2400-
                    240-
                                     Log  Cl (mmol/L)
                                               2
                                     	I	
                                   350
                                              3500
                                        Cl (mg/L)
35,000
                                                                  -I  CT
                                                                     O
-

60-



40-

-
20-


/"^\
. Southern
[ Rolling
Plains of
1 North -
u 0 Central
O o Q, D • 1 Texas /
• aSfffa i~^~~ ^/
« • (Kansas /
Brines^
4° *











1 1 1
                                                                                 100
                                    1000         10,000

                                        Cl  (mg/L)
                                                - EXPLANATION
                         4 Sample  numbers  (see table 2)
                         O Water sample from Runnels, Concho,  and eastern Tom Green Counties
                         n Water sample from seep area
                         • Water sample from western Tom Green County
100,000
                                                                                                                          OA 5903

-------
-253-

-------
                          ABSTRACT

                    COFRC-GREG PIETRUSZKA
                CHEVRON U.S.A. - T. R. BEVINS

    Fie 1 ct Results of Tracer Teats Conducted  i _n_ 0i 1  Field

      Steam and Non-Condensible Gas Inject ion Projects
chevron has more than twenty years of experience  in  using

rhemi r:.\ I and radioactive tracers to determine  flow patterns

of injected steam and non-condensible gases  in  oil field

reservoirs.  Chemical tracers used include sodium salt  ions

(btumide, chloride and nitrate), sulfur  hexaflouride  (SF6),

and £1 ourocarbons (Freons 11 and 113).   Radioactive  tracers

1.1 ;o".:d include krypton 05, tritiated water  and  tritiated

methane,  Tracer test design considerations  wj 11  be  discussed

including reservoir characteristics, amounts  of  tracers,

Irriect. ion and monitoring techniques and  impact  on

env ironment.



Results of  tracer testing of several different  Injection

fluids will bp presented.  The  Kern River Ten-Pattern Steam

Flood tracer program demonstrated the use of  tracery  in steam

nnoil Lug;   the SACROC tracer test program applied tracer

t.eM.ing to  C02 flooding;  and the current Painter Reservoir

Unit tracer test program applies tracer  testing to a  nitrogen

infection project.  Uses of  tracer testing results will be

ii iscussetj including as an aid in:  geologic  modeling,

:<:.'Hjuct i on/reservoir engineering, and reservoir modeling for

 • . ruir ] a t i on .
                            -254-

-------
                     BIOGRAPHICAL SKETCH


Greg Petruszka graduated from the University  of  Tulsa  in  l':)80

with a Bachelor of Schience Degree in Petroleum  Engineering.

He worked for Chevron USA> Denver between June 198d  dud  July

1984 on assignment in drilling production and reservoir

engineering.  He hds worked for Chevron Oil Research Company

since July 1984 and his current assignment as Research

Engineer is in the Production Research Department.   He

implements new research technology in oilfield app 1. {<"* t \ on.i:;
NB  -  A FULL TEXT IS NOT AVAILABLE FOR  INCLUSION  IN  THESE
       PROCEEDINGS
                           -255-

-------
          Identification and Closure
      of Shallow Brine Disposal Wells in
                 Pennsylvania
       By Jon M. Capacasa, P.E., Chief
Drinking Water/Ground Water Protection Branch
            U.S. EPA, Region III
  Presented at UIPC International Symposium
               New Orleans, LA
                 May 5, 1987
                    -256-

-------
                  Identification and Closure of Shallow
                   Brine Disposal Wells (Blow Boxes) in
                               Pennsylvania
                            By Jon M. Capacasa
                   US EPA Region III, Philadelphia, PA
     The shallow gas producing fields in the Commonwealth of Pennsylvania
are "wet gas" formations which produce hrine in association with the
natural gas.  The brine is a highly saline formation fluid which contains
a variety of chemical elements. The EPA has established Primary or Second-
ary Drinking Water Standards under Parts 141 and 142 of the Code of
Federal Regulations for a number of these elements, including:  arsenic,
barium, cadmium, chromium, chlorides, iron, sodium, sulfate and strontium.
Produced brines consistently exceed established MCL's and secondary
standards and can be a threat to public and individual water supplies if
not disposed of in an environmentally prudent manner.

     Gas producers use a variety of methods to dispose of their waste
brines including injection wells, annular disposal, pretreatraent to a
municipal system, stream discharges, road spreading, etc.  A number of
these are approvable methods for disposal of brines and drilling fluids.

     However, it has been the common practice of producers in the
Southwestern PA area to dispose of produced brines on site into a dry
well known as a blow box.  Blow box is a generic terra used to describe a
bottomless wooden or concrete structure of varying construction type;
most common types seen within the study area were rectangular concrete,
circular concrete, and square wooden cribs extending, in depth, approx-
imately 1.8 - 3.6 meters (6 to!2 feet).  Many were of similar construction
to septic system tanks.

     At gas well sites employing blow boxes, the brine is typically directed
from the well head, sometimes via a brine storage tank, to the blox box, from
which it percolates into the subsurface potentially contaminating under-
ground sources of drinking water.  After a period of time, the blow boxes
tend to fill with silt, resulting in reduced fluid capacity.  As a result
of this reduced fluid capacity and seasonally high water tables, surface
releases of brine may occur, causing extensive vegetation damage and
discharges of contaminants into local streams. Sand or gravel is often
placed in a portion of the box to promote percolation.

     Blow boxes are in essence, shallow brine disposal wells, discharging
brine directly into the zone of aeration and surficial aquifers.  Such
injection is prohibited under EPA's Underground Injection Control
(UIC) Program,  specifically in such sections as: the definition of a
Class II well §144.6(b); §144.12 prohibits movement of fluids into under-
ground sources of drinking water; §144.21 requires authorization by rule
or permit to inject; §144.27 requires inventory submittals by owners or
operators authorized to inject; and §144.28 specifies casing and cementing
requirements to prevent fluid movement.  Discharges to ground water are
also prohibited under the Pennsylvania's Clean Streams Law (P.L. 1987
No. 394) and Section 207 of the Oil and Gas Regulations (P.L. 223).

                                      -257-

-------
     The environmental risk associated with the blow box practice
was generally assessed based upon interviews of state field inspectors,
by EPA review of drinking water quality data in the area, analytical
results of brine samples and ancedotal information from news reports of
individual water well contaminantion.  Although contributing on average
small volumes of brine to the ground water (ranging from .25 to 1
barrel per day), the widespread use of the practice in a 13 county area
of Southwestern PA brought EPA's original estimate of 3000 or more gas
well sites using boxes.  Data on total volumes of brine are as yet, incomplete,
however one large company provides an illulstrative example in documenting
that their yearly brine production of 98,000 barrels is now directed to
a treatment plant.  An early drinking water survey of sodium levels of
public supplies in the State of PA left the overall observation that the
highest levels of sodium could be found in the SW PA Region.  In fact
the levels ranged as high as 250 ppm in Indiana County.  Coupled with
this observation were several documented barium MCL violations in the
area under the SDWA. On-site visits to blow box locations also provided
frequent ancedotal accounts about individual water wells or agricultural
use wells fouled by high sodium or barium levels.

    Given the regulatory mandate for protection of USDW's, the chemical
composition of the brines, the estimate of in excess of 3000 active blow
boxes in this small region of PA, and the other conerns for localized
drinking water quality impacts based on data reviews, EPA Region III
developed in April, 1985 a strategy for the identication, notification
and enforced closure of blow boxes in PA under the UIC Program.

    The Blow Box Compliance Strategy was developed with a full appreciation
of the 40 or more year history of blow box use with little previous
interference by regulators, the marginal economics of the gas industry
In this area characterized by many independent owners and operators and a
depressed gas price, and the large number (3000) of small sites which
were involved.  The decision was made to set up a strategy which sought
the cooperation of the industry through early and frequent notification
of the problem and requirements, provided sufficient lead time for
conscientious operators to close the wells without undue economic burden, and
establish a series of progressively more severe enforcement actions for those
owners who denied operations or resisted closure efforts.  A reasonable
goal of a 2 year closure project was developed.  The strategy was divided
into 3 phases some of which proceeded on concurrent paths:

     I -   EPA Identification of Blow Boxes Owners and Locations.

    II -   Outreach and Notification to Owners of Record and Verfication.

   Ill -   Closure Plans/Methods.
                                     -258-

-------
     The first phase of the project was critical to its success.  The
public outreach and notification sought to advise all potentially
impacted owners of the problem, seek their feedback and cooperation
in the strategy, and provide them an opportunity to comply with DIG
inventory deadline of June 25, 1985.  Initial briefings/meetings were
held with PA Natural Gas Association (PNGA) and PA Oil and Gas Associa-
tion (POGAM) before the strategy was finalized or other outreach occurred.
The Associations responded in a positive way to the upfront communication
of EPA's goals and the reasonable compliance deadlines.  An aggressive
series of press releases, paid news ads, trade journal articles, and
direct mail notices followed to all gas well owners of state record to
promote inventory identification by the June 25, 1985 deadline.  As a
result of these efforts, over 1200 well sites were inventoried in a 2-3
month period.  For these individuals and companies EPA negotiated up to
18-month closure schedules based on the number of boxes owned.  Five
bilateral compliance agreements were executed to confirm the closure
schedules and methods for closure.  There were no penalty assessments
for operation during this period.

     To maintain the enforcement aspect of the project and as an incentive
to self-identification, EPA moved on a separate track to independently
identify blow box locations and then ownership using several innovative
techniques.  The techniques used were gas well ownership records of the
state, interviews of state field inspectors, field inspections by EPA,
and aerial surveillance.  No official inventory of blow box locations
existed at the outset of this project.

     A pilot study was conducted to assess the feasibiity of identifying
wells using blow boxes in a cost efficient manner using aerial photography.
Three types of  film and three different imagery scales were considered
in determining the best combination for identification accuracy and
cost effectiveness.  The best combination of film type and scale
was found to be 9" color infrared film at a scale of 1:12,000.  Ground
truthing by EPA personnel was done to establish features and signatures
associated with blow boxes.  Based on the pilot study findings, the
entire study area was flown, in early 1985.

     The coverage area was approximately 10,748 square kilometers (4150
square miles).  The EPA Environmental Photographic Interpretation Center
performed this sutdy at the request of EPA Region III.

     Stereoscopic viewing of the backlit transparencies provided a three-
dimensional effect which, when viewed at various magnifications,
enabled the identification of signatures or features associated
with gas wells using blow boxes.  The "signature" refers to a combination
of visible characteristics (such as color, tone, shadow, texture, size,
shape, pattern and association) which permit a specific object or condition
to be recognized.
                                      -259-

-------
     It is not prudent for EPA to provide the specific features
associated with the presence of blow boxes here.  Suffice it to say
that no one feature provided conclusive identifications, only through a
combination of well construction and surrounding environmental features
could they be identified as "possible," "probable" or "definite" blow
boxes from the imagery.

     From this work, over 1526 sites were identified for followup of
which only 118 or 7.7% were determined to be invalid identifications
through field inspections.

     The followup to this information could have been extremely resource
intensive with field visits to each.  However, Phase II of the strategy
targetted notices to owners/operators of these well sites to solicit
voluntary compliance.  EPIC "calls" were crosschecked versus state records
to obtain well ownership.  Due to the potential ramifications of improperly
accusing persons of blow box operation, initial letters were sent out
educating the addressees about EPA's program and the probable blow box
ownership. Persons in this group fell into two categories: those denying
ownership and those cooperating to close the boxes.  Field inspections
were used only to supplement ownership identification where state permit
files were not complete.

     Owners were asked to voluntarily provide:

     - inventory forms for all blow boxes operated; specific site location
       on maps; total numbers of facilities owned.

     Following receipt of the data, the owners were placed on a compliance
schedule for closure of each identified blow box.  Those denying ownership
received priority attention for field inspection and followup in terms
of potential enforcement and penalties.

     Phase III or Closure Phase of the project involved followup on the
compliance schedules and field verification of closures.  As of April, 1987,
voluntary compliance efforts have identified roughly 2154 blow boxes.  Of
these, only 20 remain active and the rest are temporarily or permanently
abandoned, subject to field verification.  The 2154 closures were achieved
without one legally enforceable order being issued or civil action taken.
EPA is just now in process of issuing administrative orders to the very
small number of blox box owners which came to our attention at this
stage of the project.  All of the EPIC leads have been addressed.

     As blow boxes were closed, EPA personnel verified a representative
number of closures relative to accepted methods and assessed whether or
not alternate means of equally illegal disposal of produced brines were
replacing the blow boxes.  A listing of state accepted alternate brine
disposal methods was provided to each blow box opeator identified by
this project.
                                      -260-

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Summary and Results

     The blow box compliance project was a highly successful,
efficiently managed project for EPA Region III.  The practice of illegal
brine disposal into surficial aquifers via blow box injection wells
has for all intents and purposes been brought to a close by this effort.
The elimination of many minor surface discharges to streams has also been
avoided from these sites.  The project has seen the placement of many
above ground storage tanks for brine hauling to approved disposal sites
and facilities.  In this regard, over the period from 1985 to the present,
three new permitted brine treatment or pretreatment facilities have
opened in PA for commercial use.  In addition, three new brine injection
wells were permitted for private use or commercial use.  This compliance
effort, in redirecting brine to such alternate facilities, has helped to
make proper brine disposal practices more economically viable.

     More importantly, this initiative by EPA's UIC program helped establish
a momentum for proper brine disposal practices in PA and EPA/State
enforcement of the same.

    The key to the success of this project was the early public outreach
and notifications by EPA to the gas industry to seek their voluntary efforts
to comply in lieu of enforced efforts by EPA.  This single factor resulted
in 2154 closures of illegal wells in less than two years.
Acknowledgements

     The author wishes to acknowledge the innovative efforts and dedication
of the following who were critical to this project's success and of
assistance in this paper:  Karen DeWald, Gary Naumick, George Hoessel,
Anthony Spano, Alfred Sturniolo and EPA's Environmental Photographic
Interpretation Center (EPIC).
                                      -261-

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                MATHEMATICAL EVALUATION OF OPERATING PARAMETERS
        IDENTIFIED IN A CLASS II BRINE DISPOSAL WELL PERMIT APPLICATION
                              MARC EDWARD HERMAN
                      U.S.  ENVIRONMENTAL  PROTECTION AGENCY
                               REGION 8  (8WM-DW)
                           999 18TH STREET,  SUITE  500
                            DENVER, COLORADO  80202
                                ACKNOWLEDGEMENTS
     The  author  gratefully  acknowledges  Victoria  Parker Christensen,  Lester
Sprenger, Gustav  Stolz,  Jr.,  Eric  Koglin,  Joseph  J.  D'Lugosz,  and Debra  G.
Ehlert, for their  invaluable  comments  and thorough reviews of  the  manuscript.
As chairman of  the internal  EPA  review  committee, Mr.  Sprenger ensured  that
peer review  proceeded  smoothly and  efficiently.   Daily  technical  discussions
between the author, Mr. Stolz, Ms. Ehlert, and Ms.  Parker Christensen  serve  to
continually improve  EPA  Region  8's  UIC program  implementation.    Thanks are
also extended to Ms.  Kay Stortz for her careful  proofreading of  the  paper.

                                    ABSTRACT
     The  purpose  of the Underground  Injection Control  (UIC)   program  is  to
prevent contamination,  caused  by  improper injection operations,  of  underground
sources of drinking  water  (USDW's).   In  Montana,  there  are  approximately 150
Class  II  brine  disposal  wells that must be  regulated  under the UIC  program,
which  is  administered  by U.S. Environmental  Protection  Agency   (EPA)  Region  8
offices.
     Any person who  proposes  to  operate a new Class  II  brine disposal well  is
required to submit a  permit application  to  the EPA.   Permit applications  for
rule-authorized   (existing)  brine  disposal  wells  must  be  submitted within  4
years of the  program promulgation date (June  25, 1988 for Montana).
                                      -262-

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     The following operating  data are reviewed  in the course  of  evaluating a
permit  application:   (a)  specific  gravity  and  viscosity  of the  injection
fluid;  (b)   injection   zone   rock  type,  thickness,  porosity,   depth,   and
permeability;  (c)  depth  to  top  of  perforations  and  extent of  perforated
interval; (d) fracture  pressure  data and pore pressure of  the  injection zone;
(e)  proposed average/maximum injection  rate  and  pressure;  and  (f)  expected
operating life of the well.
     Some potential  injection operation  impacts  are:   (1)  the fracturing  of
either  the  injection or  confining zones;   (2)  the  amount  of  injection  zone
pore  space  available for fill-up; (3) the  extent  of the fluid plume;  (4) the
length  of time the well  should  operate,  based on  volume  fill-up calculations;
and  (5) the  feasibility  of  disposing  of  proposed  fluid  volumes  at  proposed
injection pressures.
     Numerical  approximations  are  obtained   through the  use of  analytical
equations  that  take  into  account  injection  pressure,   volume,  and  rate.
Estimation  of  formation  fracture  pressure   values  may  be   accomplished  by
evaluating the results of a step-rate test.
     Comparisons  are made  between:    fracture pressure  and  proposed  maximum
injection  pressure;   projected   total  volume of  fluid  to  be   injected  and
available  formation   pore  volume;  theoretical  injection  rate   and  proposed
injection pressure;  and  formation  pressure  build-up and  proposed  injection
pressure.

                                   INTRODUCTION
     The  purpose of  the Underground  Injection  Control  (UIC) program  is  to
protect  underground   sources  of  drinking  water  (USDW's)   from  the  improper
operation of  injection  facilities.  The  UIC  program for the State of Montana
                                     -263-

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is administered  by the  U.S.  Environmental  Protection  Agency  (EPA)  Region  8
offices, and became effective  on  June  25,  1984, under the  authority  of Part C
of the Safe Drinking Water Act (SDWA).
     Many  of the  underground injection  facilities  in  Montana  are  Class  II
injection wells.   These  are wells  in  which brine  and  salt water,  brought  to
the  surface  in  association  with  oil  production,  are  injected  into  the
subsurface.  The Class II well category can  be  further divided  by defining the
purpose of a given injection operation.
     Two  basic  reasons   for  salt  water  disposal   are:   (a)  injection  into
water-bearing formations  to  dispose of the  salt water;  and (b)  injection into
oil-bearing  formations  to  enhance  the recovery  of hydrocarbons.   The former
are termed "salt water disposal" wells, and  are the subject of this report.
     According  to  the UIC  regulations for  EPA administered programs  (40 CFR
Subpart D Section  144.31(c)(l)),  Class II  brine disposal wells  operating prior
to a  program promulgation date are authorized  by rule  until  5  years after the
date  of  promulgation.    However,   a   permit  application  for  each   and  every
existing brine  disposal  well must be  submitted  no  later than  4 years from the
promulgation  date  of  the UIC  program.  At  the  end of the  5-year  period, all
existiny  brine  disposal   wells   shall have been   issued   permits   or  permit
denials,  thereby  replacing  any  rule-authorized  status.    The 4-year deadline
for   applications  is   designed   to  provide  a  transition  period   from
rule-authorized  to permitted injection status.
     Except  for  rule-authorized  wells,  all other brine  disposal   wells are
prohibited unless  authorized by  permit.  Generally  speaking then,  any company
that proposes or performs a Class  II  brine  disposal  operation  is,  or will be,
required  to  submit a permit application  to the  EPA.   All   applicants  for UIC
permits must provide  the  EPA with a completed application  form (40 CFR Subpart
                                     -264-

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D  Section  144.31 (e))  and  supplemental  information  unique  to the  specific
facility.

                                    OBJECTIVE
     Proper  implementation of the  permit  review  process  is  based  on  the
establishment of  consistent guidelines  for  evaluating criteria associated with
proposed  operating  parameters.   The purpose of  this  paper  is  to elaborate on
several  techniques  for   analyzing  permit  application  operating data.   This
paper does not discuss all aspects of the UIC  program,  nor does it discuss all
Class  II  injection well  technical  issues.   Rather,  an  attempt  is made  to
present  quantitative  methods   for evaluating certain injection  well  operating
parameters.
     These  methods   are   used as   a   means  for  gaining  a  more  objective
understanding of  the impacts  due  to  injection operations.   The equations and
results  serve as  tools  to supplement  additional information  obtained  during
the  course  of an application  evaluation.   Figure 1   highlights  the  topics and
parameters to be  addressed.

                                DATA REQUIREMENTS
     Prior  to issuance of a   permit or  permit denial  for  the construction or
conversion of a new Class  II  brine  disposal  well, the  following  information is
considered by the EPA:
     (a)  information required on EPA form 4;
     (b)  a  map  locating  the  disposal  well   and  other wells  within  the
          applicable area of review;
     (c)  a  tabulation  of  data  on all  wells within  the  area  of  review  that
          penetrate the injection zone;
                                      -265-

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     (d)   proposed  average  and maximum rate/volume of  fluid  to be  injected;
     (e)   proposed  average  and maximum injection  pressure;
     (f)   source  and  analysis of  the  injection  fluid;
     (g)   hydrogeologic  data  on the  injection  and confining  zones;
     (h)   hydrogeologic  data  on all  USDW's present;
     (i)   construction schematic  of  the  disposal  well;
     (j)   a demonstration of  financial responsibility;
     (k)   available logging and formation  testing data;
     (1)   a demonstration of  mechanical  integrity;
     (m)   injection procedures; and
     (n)   status  of defective wells  within the  area  of review.
     Except for  items  (b),  (c),  and   (n),  the  information  above  must  also
accompany  any  application  for  an  existing   Class   II  brine  disposal  well.
Applicants for both  existing and new brine  disposal wells  may  be required  to
submit additional numerical data  identifying facility operating parameters  not
previously mentioned.
     Numerical  data  that  are  used  to  analyze  the operational  aspects  of  a
Class II  brine disposal  well  include, but  are  not limited  to:
     (a)   specific gravity  of injection  fluid;
     (b)   viscosity of injection  fluid;
     (c)   fracture pressure data  for the injection zone;
     (d)   injection zone pore pressure;
     (e)   proposed maximum  injection pressure;
     (f)   porosity of injection zone;
     (9)   permeability of injection  zone;
     (h)   injection zone thickness;
     (i)   depth to top of perforations;
                                     -266-

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     (j)   description of injection  zone rock type;
     (k)   number of years the well  has  operated and is expected to operate;
     (1)   proposed maximum injection  rate  and cumulative injected volume; and
     (m)   theoretical radial  limitation of the  injection fluid  plume,  measured
          from the injection  well.
     This  information  will  serve  as  input  for  mathematical  equations that
approximate the  relationships between  injection pressure,  injection rate,  and
ground-water flow.   Environmental  effects  that are of  particular  concern are:
(1) the  potential extent of  the  fluid  plume; (2) the  potential  for  fracturing
either the  injection or  confining  zones;  and (3)  the  feasibility  of disposing
of proposed fluid volumes at  proposed injection pressures.

                              GOVERNING EQUATIONS
     Analytical  ground-water  models  have  proven  to  be  useful  tools   for
evaluating  many  ground-water  problems.    By  combining  the  results of  these
models with a  qualitative  analysis of accompanying  hydrogeologic  information,
the EPA  permit writer can  conduct  a  comprehensive  review of any brine  disposal
well permit application.
     Five  analytical  equations  are  employed  to  evaluate  the  impact of  the
operating parameters on  the  injection  formation, and the  reasonability  of  the
brine disposal  operations:

pressure due to hydrostatic head:

                                   Pd = 12Sh                          (1)
                                      -267-

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injection/fracture pressure equivalent at specific  depth:
                               Pi=Pw
injection zone pore volume:

                               V = Crrr2bn)/5.6                     (3)

length of time to fill  pore volume:

                                   T = V/365q                       (4)

steady flow from a well in a confined aquifer:

                    Q = (7.07kb[Pi -  Pf])/m(ln  re/rw)                (5)

     The following  assumptions  are made  so that  the  above  analytical  equations
may be used with some degree of confidence (Bear, 1979):
     (a)  ground-water flow obeys Darcy's law;
     (b)  ambient ground-water flow is negligible;
     (c)  ground-water flow is radially symmetric, steady-,  and horizontal;
     (d)  the injection zone is a homogeneous,  isotropic, confined aquifer;
     (e)  injection zone hydraulic conductivity and thickness are constant;
     (f)  the base of the injection zone is horizontal ;
     (g)  the injection zone has an infinite areal extent;
     (h)  the injection rate is constant; and
     (i)  the injection zone is fully penetrated by the well.
                                      -268-

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     For  many  brine  disposal  wells,  this  last  assumption  is  not  valid.
However,  for  a well that  partially penetrates  an  aquifer,  at a  distance  of
"2b" from  the well, the effects  of partial  penetration  become negligible and
ground-water flow is essentially horizontal (Bear, 1979).

                               PROBLEM FORMULATION
     The  hypothetical  example  discussed in this  paper is  based on  an  actual
permit  application,  and  although the numerical  values for the parameters are
not  identical  to  the original  problem,  they represent realistic  estimates for
operating and hydrogeologic conditions in  Montana.
     The  brine disposal  operation  to  be  reviewed  is a  rule-authorized  well
that  has  been  operating  for  5  years.    Figure  2  is a  well  schematic  that
illustrates several  important  parameters.   Much  of  the technical  data  needed
to  perform an  analytical  evaluation  of a given  permit application  are basic
operating  parameters  that are  easily  obtainable   (i.e.   injection  pressure,
rate, formation thickness,  depth to perforations,  etc.).
     Values  for the specific  gravity  and dynamic  viscosity  of  the  injection
fluid can be  found  or derived from the  chemical analysis submitted  with the
permit  application.   The  applicant  is  also often  able to provide acceptable
estimates  for  the  porosity, permeability,  and  bottom hole  pore  pressure of the
injection  zone.   Table   1  is  a  compilation  of  parameters  and  equivalent
numerical values to be used for this sample problem.
     In  the  event that  certain  hydrogeologic   data  are  not   available,  the
permit  writer  has  several options.   First,  textbooks by  Davis  and   DeWiest
(1966),   Freeze and  Cherry (1979),  and Mott  (1979)  can  be  used to   provide
approximations for fluid and formation characteristics.
                                      -269-

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     Perhaps of  more  value  is  the  practical   experience  the  permit  writer
accumulates from each  application  that  is  processed.   As each  application  is
reviewed,  the  permit  writer  gains  a  better  understanding  of the  geologic
characteristics  that  are  unique  to  the   individual  oil-producinq  areas  of
Montana.    By  cross-referencing  the  data,  the   permit  writer  can  assess  the
validity of submitted information.

                          FRACTURE  PRESSURE ESTIMATION
     According  to  UIC  regulations   (40   CFR   Part   146  Subpart   C  Section
146.23(a)(l)),
               "Injection  pressure  at  the wellhead  shall  not
               exceed a  maximum  which  shall be  calculated  so  as
               to assure that  the  pressure during  injection does
               not  initiate  new  fractures  or propagate  existing
               fractures in  the confining  zone adjacent to  the
               USDW's."
     Essentially, each  permit must  establish a maximum  injection  pressure  to
ensure that fractures are not  initiated  in a confining zone and that injected
fluids do  not  migrate  into  USDW's.  Realistically, fracture pressure  data for
a  confining zone  is rarely  available.   On  the  other  hand,  the  injection  zone
is almost always tested.
     It  has been  observed  that  injection formations  usually possess  lower
fracture  pressure  values than the  confining  zones  overlying   and  underlying
them.   Therefore,  it has been concluded  that  fracture  data obtained  for the
injection   formation  will   represent   conservative  estimates  that   can  be
confidently applied to the requirements set by the regulations.
     For existing  or converted disposal wells,  the applicant  usually submits
the  results of a fracture  treatment that  was conducted  shortly after the well
was  constructed.   Experience  indicates  that the   average  value for  fracture
                                      -270-

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pressure can  be expected  to  increase during  the  operational  life of  a well.
This implies that an old fracture test will most likely  be an underestimate of
current  formation  conditions.  With  this  in  mind, it  is in  the applicant's
best  interest to  perform  an  up-to-date  step-rate  test  to  determine  a  more
appropriate fracture pressure value.
     For the  purposes  of this paper,  fracture  (or  breakdown)  pressure  will  be
defined  as the  instantaneous  shut-in  pressure   (ISIP)   plus  the  additional
pressure  needed to  overcome  fractional   losses   in  the  well.    JSIP   is  the
pressure  needed to  maintain  an  open  fracture.    In  a  step-rate  test,  the
formation  is  intentionally  fractured   in  order   to  obtain  values  for  the
breakdown, ISIP, and frictional loss pressures.
     The results of a  step-rate test  can  be graphed (Figure 3) to determine an
approximate value  for  fracture pressure.    The  break  in  slope between  the  two
lines  is  taken  as  the  point  at  which  a  fracture  is  initiated.   For  this
example,  the  fracture pressure  appears  to be approximately  875 psig.   This
value  will  be  compared  to the  proposed maximum  injection pressure.   A  more
conservative  estimate  of fracture pressure  will be provided if the  ISIP value
is used.
     If  an  applicant is  unable to  supply the  EPA with  current results  from a
step-rate test, the  following  equation  is applied   (40 CFR  Part 147  Subpart BB
Section 147-1353(a)):
                           Pw  =  (0.733  -  0.433Sjh                 (6)
                           w                  g
where S   is  the specific  gravity  of the injection or  fracturing  fluid.  This
equation assumes that  the  fracture gradient  for  any  given  formation  is 0.733
psig/ft.  Fortunately, a sufficient  number  of permit  applications  has provided
                                      -271-

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the  EPA   Region  8   staff  with   a  clearer   picture   regarding   fracture
characteristics for many of the  formations in Montana.  This  knowledge  allows
permit writers to assess the appropriateness of equation 6.

                         INJECTION PRESSURE  CALCULATIONS
     To  determine  an   acceptable   value  for  maximum   allowable   injection
pressure,   the permit  writer can  compare  proposed operating  pressures  with
fracture pressure  data  derived  from field-determined  step-rate  tests.   Values
for  fracture  and  proposed  maximum  injection  pressures  at  specific  depths
(usually  the  top  of  the  perforated  interval)  can  be  calculated  in  the
following manner.
     Pressure  at  the  top  of the perforations,  induced by applying  a  surface
pressure equivalent  to the  fracture  pressure,  can  be calculated as  follows.
First, the pressure due to hydrostatic head is determined with equation 1.

                                  Pd  =  12Sh                     (1)

     NOTE:   the fluid used  in the step-rate test is the same  as  the injection
     fluid; the specific gravity of the fluid is 1.107.

                     S = [(1.107M62.4 Ib/ft3)]/(12 in/ft)3
                             = 0.03997 = 0.040 pel.

     Substituting 0.040 pci for "S"  and 1400 feet for "h",

                       Pd = (12)(0.040)(1400) = 672 psig.

                                     -272-

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     Equation 2,
                               pi = pw + Pd
combines fracture  pressure measured  at the  surface  (Pwfrac  =  875 psig) with


the pressure due to the hydrostatic column within the tubing  (Pd =  672 psig).







                    Pifrac = 875 psig + 672 psig = 1547 psi9





P.f     is  the  total   pressure,   at  the   perforations,   associated  with  the


fracture pressure applied at the surface.


     Pressure  at the  perforations,  induced  by  applying  the maximum proposed


surface  injection  pressure  (P^,.,.,  =  700 psig)  is calculated in  a  similar
                               WIHoA
manner.
                        Pd = (12)(0.040){1400) = 672 psig
and with P     = 700 psig = maximum proposed injection pressure,
          WlMClA
                    Pimax = 70° ps1g + 672 psig = 1372 psl'9'





     Pimax  rePresents  pressure,   at  the  perforations,  caused  by  a  surface


 injection pressure  of 700 psig and  is the  maximum proposed  injection  pressure


 at  the  same  depth as  the calculated fracture pressure.   Comparing  the  proposed


 injection  pressure  (P.jmax  =  1372  psig)  to  the  fracture  pressure  (Pifrac =



 1547  psig),   it can  be  seen  that  the  company  will be operating  below  the


 pressure necessary  to fracture the injection formation.

                                       -273-

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                           INJECTION VOLUME LIMITATION
     The proposed maximum  injection  rate  is  2000 BWPD,  and  the well  has  been
in operation  for approximately  5  years.   Results from  equations  3,  4, and  5
will  quantitatively indicate:
     (a)  the injection zone pore volume available for fill-up;
     (b)  the  amount  of  time it  will  theoretically  take  for the plume  to
          extend to the designated limit;  and
     (c)  whether the proposed injection  rate  is consistent with  the  proposed
          injection pressure.
     Equation  3  is  used  to estimate the volume  of fluid that is theoretically
necessary to fill up a subsurface  cylinder,  centered  around  the disposal  well,
with a  radius of 1/4  mile and height  equal  to  the injection  zone  thickness.
This equation  is similar  to  the  equation used  to calculate  the  volume  of  a
cylinder  (volume = TTr h,  where  h = height  of  cylinder).   The porosity  term
represents the pore space of the  cylinder.
     Before equation 3
                               V = (TTr2bn)/5.6                     (3)
can be  used,  however,  several  intermediate calculations must  be  performed, in
order  to  take into  account the  fact  that the well  has been operating  for 5
years.  If the disposal well was a newly constructed or converted well,  these
calculations would  not  be necessary.  According to the  applicant, the average
injection rate over the 5-year period was 1300 BWPD.
     Equation 4,

                                   T = V/365q                       (4)
                                      -274-

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which describes  the  length of time it will  take to fill the  pore  volume, can
be rearranged to solve for pore volume filled during a known time period.
     q, = average injection rate during specified time period = 1300 BWPD
      a
     V  = subsurface volume filled during time period (barrels)
      a
     T  = specified time period = 5 years
               V   =  365qaTa  =  (365)(1300)(5) =  2.3725x1 O6  barrels.
               a        a  a
     Naturally,  if  records  for total  volume  of injected fluid  are available,
they should be used for V,.
                         a
     As  a rule-authorized  well,  the  facility was  originally  limited  to  an
injection plume  extent of 1/4  mile  from the wellbore.   However,  the equations
used in this  analysis neglect  the effects  of  salt-water dispersion and ambient
ground-water  flow  within  the  formation.   Therefore,  a  safety  factor  is
incorporated  into the  analysis,  in  an attempt  to  acknowledge  the phenomena of
molecular diffusion, mechanical dispersion, and regional flow.
                   5% of 1/4 mile is 66 feet or 0.0125 miles,
                (0.25 - 0.0125) miles  = 0.2375  miles  =  1254  feet.
     A value  of  1254 feet will be used as  the radial  distance (r), instead of
the  1/4-mile  value  (1320  feet).  Although for this   situation  a  10% safety
margin  is  considered  adequate,  it  should  not  be  viewed  as  necessarily
acceptable for all disposal  operations.
     Total  subsurface volume  available   (Vt)  is determined  by  substituting
the following values into equation 3:  1254 feet for "r",  50 feet for  "b", and
0.30 for "n".

            Vt = [(Tr)(1254)2(50)(0.30)]/5.6  = 1.323269xl07 barrels
                                      -275-

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     The subsurface  volume,  currently available  (Vb)  for fill-up,  takes  into
consideration  the   reduction  of  available  pore  volume  caused  by  previous
injection.
         Vt - Va = Vb = 1.323269x1O7 - 2.3725x1O6 = 1.08602x1O7 barrels
     The  proposed  maximum  injection   rate   (q.)  is  2000  BWPD.   Using  the
calculated  value   for   Vb,   the  length  of  time   remaining   for  injection
operations (Tb) is calculated through the use of equation 4,

          Tb = V365% = H. 08602x107)/(365) (2000) = 14.8 = 14 years.

     Tb  is  rounded down  to  incorporate  an  additional  margin of  safety.   The
value of  14 years is the theoretical length  of  time the company  may  continue
to operate the disposal  well.   In  the  permit application,  the company  proposed
an  operating   life  of  approximately 20  years;  beginning  from   the  date  of
application.   Unless   additional   technical  data   is  submitted  to   prove
otherwise, the permit would be written  such that  it  would  expire  no later than
14 years after issuance.

                          PRESSURE  &  RATE  COMPATIBILITY
     Equation 5 is  used  to assess  the  feasibility of injecting at the  proposed
maximum  rate   and  pressure,  and  is derived from  a  standard  equation  that
describes the  drawdown  curve for steady  flow to  a well  in  a  confined aquifer
(Bear, 1979).

                    Q =  (7.07kb[Pi  -  Pf])/m(ln re/rw)                (5)
                                     -276-

-------
This  equation can  be  used  to  estimate  the  theoretical,  maximum  allowable
injection  rate  that  would  be  operationally  consistent  with  the  proposed
injection pressures, and is an objective  method for comparing theoretical rate
with  proposed  rate.    In   addition,  equation  5  makes   a  comparison  between
proposed injection pressure and the formation pressure.
     If  an  applicant is unable to provide estimates  of  aquifer permeability,
the  permit writer  has  several  options.    Referring  to  inhouse  hydrogeologic
records,  maintained for  the  same or  similar  formations,  has  proven   to  be
helpful.  EPA  UIC staff  discussions  further serve  to guarantee that there will
be an ongoing  exchange of new or pertinent information.
     An  operator will  often  submit  a  bottom  hole pressure  measured  shortly
after the well was  drilled.   If the  well  has been  in  operation  for some time,
this  value  will be   an  underestimate  of  current formation pressure.   One
approach for  estimating  pore  pressure is to assume that  formation  pressure is
equivalent  to a hydrostatic  column  measured  from the top  of the perforations
and  extending just  to  the  land   surface.   For  disposal  zones  that are  not
highly  pressured,  this approach  may  overestimate  pore  pressure,  but will
actually  reduce  the  value  of  "Q" and provide a  conservative  limit for  the
maximum  allowable injection rate.
     From the  previous pressure calculations,

                     Pj  = 1547 psig,  and  Pf =  Pd =  672  psig.

     Substituting 0.05  darcys for  "k",  50  feet for "b",  0.4  cp  for  "m", 1254
feet for the adjusted "r ", and 0.333 feet for  "r ",
                        C                        W

    Q  = ((7.07)(0.05)(50)[1547 - 672])/((0.4)[ln (1254/0.333)])  = 4695 BWPD.
                                      -277-

-------
     The proposed maximum injection rate  (q  =  2000  BWPD)  is much less than the
calculated, theoretical  maximum  allowable  injection  rate  (Q  =  4695  BWPD).
However, this  does  not mean that  the company would necessarily be  allowed io
arbitrarily increase the proposed rate.

                                    SUWIARY
     This paper presents a mathematical  approach  for evaluating Class II brine
disposal permit applications.   Certain physical  processes associated with well
hydraulics  and  ground-water flow  can  be  approximated   through  the  use  of
analytical  models.    Once   numerical  estimates   are  assigned  to  specific
variables, operating  conditions can  be  evaluated  in terms  of compliance with
the  UIC program.   It  should  be  remembered that  mathematical equations  are
tools  to  be used  in  conjunction with a  qualitative  review of all  available
hydrogeologic  information pertinent to the injection operation.

                                   FUTURE WORK
     Technical  reviews  of  permit   applications  would  be  greatly  enhanced
through the use  of appropriate ground-water computer models.   However,  access
to documentable hydrogeologic data  is often  limited.   In  many cases, numerical
values   for   specific   parameters   must   be   approximated.    Under   these
circumstances,  it  is  not  appropriate  to make  use of data-intensive  models,
particularly  when  the  data  base itself  is  based  on  generalized  assumptions.
Time constraints and  computer  hardware capabilities limit programming choices,
further complicating the matter.
     Fortunately,  valid computer  codes  have  been developed  for  almost  any
hardware setup.  It is  hoped that in  the  forseeable future, a FORTRAN program
written  by Hsieh  (1986)  will   be  incorporated  into  the  permit  application
                                      -278-

-------
review procedures.   Hsieh's program evaluates  the analytical  solution  of the
radial dispersion  problem  by  analyzing  dispersive transport  in  radial  flow
from  a recharge/injection  well.   Most  of  the  input  items  required for the
model  are  data  that are  regularly  reviewed during an  application evaluation.
In addition,  the  analytical solution  is  predicted to  be  computationally more
efficient than previous solutions.
                                      -279-

-------
                           SCIENTIFIC  TERMS
                                          2
psig = pounds per square inch gauge (Ib/in )
                                   3
pci  = pounds per cubic inch (Ib/in )
BWPD = barrels of water per day
Pd   = hydrostatic pressure at a specific depth (psig)
S    = specific weight of injection or fracturing fluid (pci)
     = (specific gravity of fluid)(specific weight of fresh water)
h    = height of fluid column (feet)
12   = conversion factor for feet to inches (1  foot = 12 inches)
PW   = fracture or injection pressure  at the  surface, or wellhead (psig)
PI-   = pressure, due to injection/fracturing, at a specific depth (psig)
V    = subsurface injection zone pore  volume  (barrels)
r    = radial distance of injection plume limitation (feet)
b    = thickness of injection zone (feet)
n    = porosity of injection formation (dimensionless)
                               3                   3
5.6  = conversion factor for ft  to barrels (5.6 ft  =1  barrel)
q    = injection rate (BWPD)
T    = time period to fill  the injection zone pore volume (years)
365  = conversion factor for days to years (365 days = 1  year)
Q    = theoretical injection rate (BWPD)
k    = injection zone permeability (darcys)
Pf   = injection zone pore pressure (psig)
m    = viscosity of water (centipoise)
r    = distance of theoretical plume limitation (feet)
r    = well bore radius (feet)
7.07 = conversion factor
                                 -280-

-------
                               METRIC  CONVERSIONS
     (Ib/in3)*(2.767990x104)  = kg/m3
     (psi)*(6.894757x103)  = Pa
     (centipoise)*(1.000000xlO~3)  = Pa-second
     (barrel )*( 1.58987 3x10"1)  = m3
     (ft3)*(2.831685xlO~2) = m3
     (feet)*(0.3048)  = meter
     (darcy)*(9.870x10"13) = m2
     (jiffy)*(3.3602x10"12) = sec/m
                                   REFERENCES
Bear, Jacob.  1979.   Hydraulics of Groundwater.   McGraw-Hill  Inc., New York,
     569 pp.
Davis, Stanley N. and Roger J.M.  DeWiest.   1966.   Hydrogeology.   John Wiley
     & Sons,  Inc.,  New York, 463 pp.
Freeze, R. Allan and John A. Cherry.   1979.   Groundwater.   Prentice-Hall, Inc.,
     Englewood Cliffs, 604 pp.
Hsieh, Paul A.  1986.  A New Formula for the Analytical  Solution of the Radial
     Dispersion Problem.  Water Resources Research, volume 22, number 11,
     October, pp. 1597-1605.
Mott, Robert  L.  1979.  Applied Fluid Mechanics.  Charles E.  Merrill Publishing
     Co., Columbus, 2nd Edition, 405 pp.
Nielsen, David M. and Linda Aller.  1984.   Methods for Determining the
     Mechanical Integrity of Class II Injection Wells.  National Water Well
     Association, Worthington, OH, July, Report No. EPA-600/2-84-121, 263 pp.
                                       -281-

-------
                Table 1.   Hydrogeologic & Operational  Parameters
          parameter
injection zone permeability
viscosity of fluid
maximum proposed surface injection pressure
fracture pressure measured at the surface
maximum proposed injection rate
arbitrary radial plume limitation (1/4 mile)
specific gravity of fluid
previous average injection rate
injection zone thickness
porosity of injection zone
depth of perforations
well bore radius
proposed operating life of the well
numerical  value
  0.05 darcys
  0.4 centipoise
  700 psig
  875 psig
  2000 BWPD
  1320 feet
  1.107
  1300 BWPD
  50 feet
  0.30
  1400 feet
  0.333 feet
  20 years
                                      -282-

-------
                                            UIC PROGRAM
                                                 I
Class I
            CLASS II
              Class III
       Class IV
Class V
           BRINE DISPOSAL
                I	
                       enhanced recovery
                     PERMIT APPLICATION INFORMATION
   well
construction
 details
p&a
plan
OPERATIONAL DATA
  financial
demonstration
                                EXISTING
                                                  new
  area
of review
                                                        corrective
                                                          action
    INJECTION RATE-

 INJECTION PRESSURE-

    OPERATING TIME •
RICAL
NG DATA



                           OPERATING'PARAMETERS   HYDROGEOLOGY
MAXIMUM  INJECTION PRESSURE

    MAXIMUM INJECTION RATE.

            OPERATING TIME •

       RADIUS OF INFLUENCE
            POROSITY'

        PERMEABILITY'

           THICKNESS•

               DEPTH-

GEOLOGIC DESCRIPTION-

   FRACTURE PRESSURE -

       PORE PRESSURE-
                                                        FLUID DATA

                                                       	I
                                                  INJECTION
                                                    FLUID
                                                    injection
                                                      zone
                                             SPECIFIC
                                             GRAVITY
                                             I
                                          VISCOSITY
              INJECTION ZONE
                         confining  zones-
                                                                     total
                                                                   dissolved
                                                                     solids
                                                                     (tds)
                                                                    content
                         - geologic
                            description

                         • fracture
                             pressure

                       — depth

                       — thickness
Figure 1.   Generalized Flow Chart of Information Requirements (capitalized items are

           discussed in paper).
                                             -283-

-------
                                    '////S
                                       INJECTION ZONE
Figure 2.   Injection well schematic (after Nielsen and Aller,  1984, p.  18)
                                 -284-

-------
          1200-

  i
           800-
           600-

       I
          400-
          200-
             0
8 75 PSIG
                           INJECTIOH RATE, IH
                         BARRELS PER MINUTE fSPMJ
                                                  8PM
                     0.59
                     1.80
                     3.35
                     4.02
                     4.76
                     5.10
                          PSIG
240
560
930
1015
1160
1187
in
oo
oj
\
                                          \    \
               0      1
Figure 3. Step-rate test results.
                      \
                      5

-------
               THE USE  OF  CONTROLLED  SOURCE AUDIO
           MAGNETOTELLURICS  (CSAMT) TO  DELINEATE ZONES
         OF GROUND WATER CONTAMINATION  -  A CASE HISTORY

       By Richard M.  Tinlina,  Talib Syedb, Steve Figginsc,
                     and A.  Roger Anzzolin*1

                        aVice President
                     Geraghty  & Miller, Inc.
        3322 E.  Fort  Lowell  Road, Tucson,  Arizona   85716

                          °Geophy s i c i s t
           Zonge Engineering and  Research Organization
        3322 E.  Fort  Lowell  Road, Tucson,  ARizona   85716

                        Project  Officer
                   Office of  Drinking  Water
              U.S. Environmental  Protection Agency
                        Washington, D.C.


                            ABSTRACT

     A significant potential  for the  pollution of fresh water

aquifers  exists  due  to oil-field  water-flood operations.   The

sources  of  potential pollution are surface spills, a  lack of

mechanical integrity  of injection wells,  and improperly plugged

wells  which  are in  communication with the injection  zone.

Surface spills are relatively  easy to  detect  and  control.   Pro-

cedures   for checking  the  mechanical integrity  of a  properly

constructed injection well are available.  Making a determination

in the  absence  of good records  as to  whether or  not a  well is

improperly plugged,  providing  a  conduit  for  the vertical migra-

tion of  formation brines  from the production  zone to shallower

fresh water aquifers, is very  difficult.


     Electrical   surface geophysical  methods  offer considerable

promise  in detecting   the  movement of   formation brines  into
                                     -286-

-------
fresh  water  aquifers,  through improperly  abandoned or  plugged




wells.






     An  electrical  surface geophysical  technique.  Controlled




Source Audio-Frequency  Magnetotellurics (CSAMT) has  been  applied



to  locate  the presence  of  anomalies resulting  from the  upward



movement of  formation brines  through  improperly plugged  wells.




The primary  objective in a CSAMT  Survey  is to provide  apparent



resistivity and the phase angle between the electric  and magnetic




fields over  a prospect area.    CSAMT has  the advantages  of




excellent lateral resolution,  good depth penetration  (a  kilometer




or  more) and  is  relatively  inexpensive.   The frequency  and



resistivity of the  subsurface  controls  the  depth  of  penetration.



The lower the frequency, the deeper the penetration.






     A CSAMT  Survey was  run  in an oil producing field in  east



central  Oklahoma  which  is  currently on waterflood  and has  many



abandoned and apparently improperly plugged wells.   The water in




the Vamoosa aquifer underlying the study area has a high  chloride



content.  The objective of running the  CSAMT Survey was  to  locate



suspected low  resistivity anomalies due  to formation brines  in



the vicinity  of  improperly  plugged wells  and  to attempt  to  map



their  extent.






                          Introduction




     The study area  includes approximately  324 hectares  (800




acres) in the Sac  and Fox Reservation located  in  Lincoln  County,




east central Oklahoma (Figure  1) .   The area is underlain  by  the




Vamoosa Formation, which consists  of alternating  thin  to  massive
                                  -287-

-------
OO
00
I
                       SAC & FOX
                       RESERVATION
                    R6E
   SAC & FOX UNIT
STUDY AREA LOCATION

Lincoln County,  Oklahoma

        Figure  1

-------
sandstones and sandy-silty shales.   The  sandstone layers are fine



to coarse-grained and provide a  reservoir source for  one  of the




major fresh water aquifers in Oklahoma.






     Oil production in the study area began  in  the  1930's.   The




unit's cumulative production  through August 1982 is approximately



28 million barrels,  with an estimated current monthly production



of 4500 barrels.  Water  injection  for secondary recovery  and/or




salt water  disposal  purposes began  in the  1950's and  the



cumulative water injected through August 1982 is approximately 75



million barrels, with an estimated current monthly  injection of



48,000 barrels.






     The major objectives of  the ground water contamination study



included  the determination  of the  cause  of the high chloride



concentrations in the Vamoosa  aquifer underlying  the  study area



and  whether  this resulted directly  from oilfield  activities  on



and  around  the  study  area.   A large number of  well logs  and



plugging and abandonment  records were evaluated and several tests



conducted to determine the source of the high chloride waters in



the  Vamoosa  aquifer underlying  the  study area.   Test  holes were



drilled and logged  to  obtain ground water  samples  and  to



determine the ground water quality  profile at the test sites.  In



addition,  an   electrical surface geophysical survey  (Controlled



Source Audio Magnetotellurics -  CSAMT) was run in order to locate




the  presence of anomalies  that might  result  from  the  upward



movement of formation  brines high in salt content through
                                  -289-

-------
improperly plugged wells into  the  overlying  Vamoosa  fresh water




aquifer.






                      Background Studies



Hydrogeology




     The surface geology of  the  area  is part of  the  Ada  Group.



Underlying the Ada Group is  the Vamoosa  Formation.   The Vamoosa




aquifer  includes  the  Vamoosa  Formation  and  underlying  and




overlying Pennsylvanian formations   that   are  1ithologically




similar and hydrologically interconnected.   The  Vamoosa aquifer




consists  of a  complex sequence of fine   to  very  fine grained



sandstone, siltstone,  shale,  and  conglomerate,  with interbedded



very  thin limestones.    The  water-yielding   capabilities  of  the



aquifer  are largely  controlled  by  the  lateral  and  vertical



distribution  of  the   sandstone  beds  and  their  physical




characteristics (D'Lugosz et  al, 1978).  Figure 2 illustrates the



hydrogeology underlying  the area  and was prepared from driller's




logs  and  plugging  records of  five  abandoned wells.   The



orientation of the  geologic  cross-section  is   approximately



southwest to northeast (Tinlin  et al,  1984).






     Earlier investigations   (Hart,  1966) reported that  the  base




of the fresh water beneath the  area could range from 50 meters to



more  than 150 meters below ground  level.   An evaluation  of



electrical resistivity logs   run on  oil  wells in  and  around the




area shows the base of the fresh water  to be in  the  range of 40




to 90 meters below ground level.   A base  of  fresh water contour



map (Figure 3)  was drawn utilizing data  from  resistivity logs and
                                  -290-

-------
                                  SAC & FOX GROUNDWATER CONTAMINATION STUDY
                                                                                             • Approx. 3000'
I
NJ
0-
500-
1000-
1500-
2000-
2500-
3000-
3500-
Sac. 10 Sae. 16 Sac. 16 Sac. 10 Sac. 18 Sao. 19
No. 9 No. 4 No. 3 No. 2 No. 1 No. 18
a>
8
CO
3
0
c5
a
to
3
'-' '"i •-'~~~^.



^-Ttj~Li7j^j^rurij^_r^rir;

Sao.
L No.

-

HI-vvir^HHHjiHH
^ l ^ ', l ' ' • ^
19
5



V Prua Sandatona
lonzonlal Scale: 1' - 500'
/ertical Scale 1' - 500'
HOT6: Qaologlc Formatlona ara Pannaylvanlan In Aga. «.UM., „=« «Brt, ««,^ ™«oo o=^,.«..
                                                                            GENERALIZED GEOLOGIC CROSS SECTION

                                                                               Lincoln County, Oklahoma TUN - R6E
                                                                                                                  -500
                                                                                                                  -1000
                                                                                                                  -1500
                                                                                                                  -2000
                                                                                                                  -2500
                                                                                                                  -3000
                                                                                                                 L3500
                                                                                        Figure 2

-------
                                            SAC  &  FOX  GROUNDWATER  CONTAMINATION  STUDY
                                                                                        R6E
         UEQEND

  A^»A' Crou Section Location
 —250—Contour truetvrt
 • ••••• Boundary at A<*a
     •  Ten Well Drilled In 1M3
        EEI Tett Well OrlDwl In 1970
     ©
     O
 I
f-O
Ni
I
S»c 1 Fox T««t WWK
Drlltod In 1879
EEI T*M Vttol 1963
Othar W»ll Control
        4
         N
  Seal* I  - 1/4 ml*
  Conlout Inlirvat -SO'
  Contour* and Control Polnli
  a/« in Fe»l Below Ground Level
  10 It. - Ground Uvel Datum)
                                                                                                           BASE OF FRESH WATER CONTOUR  MAP
                                                                                                                   Lincoln County. Oklahoma
                                                                                                                           Figure 3

-------
from test wells drilled earlier  in  the  study area  (Tinlin et al,



1984).   The contour map  shows the base  of  fresh water  to be



relatively shallow  over a  large portion of  the  area.






Ground Water Quality



     A study (Bingham and  Moore, 1975)  showed  that  the  quality of



the ground water adjacent  to the area  to be generally  good with a



IDS of 500 mg/L or  less.





     In  the  spring of 1979,  four test holes   were  drilled  by



Engineering  Enterprises,  Inc.   in  order  to determine  the



ground water quality.    The  test well  data  showed an anomalous



occurrence of  salt water in a  portion of the Vamoosa  aquifer



that  was  expected to  contain  only fresh  water.   Three



possibilities  as  to the  cause of the high  chlorides  in  the



Vamoosa were  postulated;   (1) natural  occurrences  of  salt



(halite)  in the Vamoosa,  (2)  upconing  of  the  fresh water - salt



water  interface due to overpumping of  the Vamoosa aquifer,  and



(3) accidental  introduction  of salt water into  the  aquifer due to



various phases of oil field  activities.    The Vamoosa  and



associated rock units do not contain salt  beds nor does  the



sedimentary environment in which the Vamoosa was deposited allow



for the development of  bedded salt.  Overpumping of the Vamoosa



aquifer was also ruled  out as  the recharge  rate of  the  Vamoosa is



much higher than the pumping rates  of the existing  supply wells.
                                  -293-

-------
Determination of Salt Water  Contamination  Source  in the Vamoosa
by Water Sampling

     Water  samples from  a test well  (located  in Section 22}

drilled under the supervision of  Engineering  Enterprises, Inc. in

July 1983 were analyzed  by Dr.  Donald 0. Whittamore  of  the Kansas

Geological  Survey.   Whittamore's  (1983)  procedure is  very

effective in  distinguishing  oilfield  brines from  halite   (rock

salt)  solution  brines and thus  can  determine which may  be the

source of ground water contamination.


     Bromide concentrations were  determined by Dr. Whittamore and

the  chloride concentrations were determined by Environmental

Control Laboratory in Norman,  Oklahoma.  The  results of  the water

analyses are presented in  Table 1.


     The bromide/chloride ratio is  the  key in determining the

brine  contamination source.  The  ratios in the saline waters are

what could be expected if oilfield brine pollution had  occurred.

Bromide/chloride ratios  for most Oklahoma  oilfield  brines range

from  0.003  to 0.01.  The bromide/chloride  ratio  expected for

waters with chloride concentrations of  10,000 mg/L for a halite-

solution  source   of   salinity   is  0.0002  +   0.0002.    The

bromide/chloride values  are much  higher than the expected values

for a  halite-solution source and  fall  within the values for most

Oklahoma oilfield brines.   Since  this  situation fits the special

case where the injected  fluid is  the same  or very similar to the

Prue  formation  fluid,  the source of  salinity  in the Vamoosa

ground waters beneath the  area was  concluded  to be Prue  formation

brine.
                                  -294-

-------
TABLE 1:  CONSTITUENT  CONCENTRATIONS  AND RATIOS




           FOR VAMOOSA WATER  SAMPLES
Sample No.
1
2
3
Depth, meters
42
61
79
Cl, mg/1
200
7,520
10,800
Br, mg/1
0.78
33
50
Br/Cl
0.0039
0.0044
0.0050
                          -295-

-------
     In December  of  1983,  two  samples  of  Prue  formation brine



were obtained from a surface separator on site, and the bromide/



chloride ratios  determined  by Dr. Whittamore.   The  purpose  of



this  testing  was to  obtain a  comparison of  the Prue  brine



bromide/chloride  ratios with  the previous  Vamoosa  ground water



bromide/chloride ratios of  July,  1983.  The bromide and chloride



concentration and bromide/chloride ratios are listed in Table 2.



The bromide/chloride  ratios  from the Vamoosa aquifer  closely



match   the bromide/chloride ratios  of  the brine in  the Prue



Formation.   Due  to this close match  of  geochemical ratios,  the



Prue oilfield brine is considered to be the most probable  source



of brine polluting the Vamoosa aquifer.





Location and Evaluation of  Improperly  Plugged Wells



     An evaluation of all plugged and  abandoned  wells  in  the



study and  surrounding  areas  was made  from Oklahoma Corporation



Commission  records.   A location  map  of   these  wells,  including



identification of  the  properly  and  improperly  plugged wells,  is



shown in Figure 4.





     A number of  the  wells were  determined  to be  improperly



plugged.   For  a  proper plugging operation  in  an area  where



protection of  the fresh water  aquifer  is  important,  at least four



downhole cement plugs  should be  installed  in every  well  that is



to be plugged and abandoned.   These four plugs are  a bottom plug



opposite the injection interval,  an isolation plug across the top



of cut casing,  a  surface  casing protection plug,  and  a surface



plug.
                                  -296-

-------
         TABLE 2:  CONSTITUENT CONCENTRATIONS AND RATIOS




                    FOR PRUE OILFIELD BRINES






Sample No.       	Cl,  mg/1	 Br, mg/1	Br/Cl




 Prue 1                74,200            377              0.0051




 Prue 2                74,600            372              0.0050
                                   -297-

-------
©   Producing Oil  Well
0   Oil  Well - Properly Plugged
0^   Oil  Well - Improperly Plugged
A   Infection  Well
{&   Injection  Well  - Properly Plugged
     Surface Rights Only

-298-
                 SAC & FOX  UNIT
             Lincoln  County, Oklahoma
                                                             Figure 4

-------
     Many of  the older wells  were plugged  by  loading the  hole



with mud.  With  time  mud  can settle out and  allow  channeling  of




salt water through the borehole. The cement  plugs in most  of  the




older wells were determined to be  inadequate.  Many of  the wells




had only  the  top surface  cement  plug and no  additional downhole




cement  plugs.    In  addition,  in most  of the  plugged  wells  the



surface casing was set too shallow.  Surface casing  should  be  set



below  the base of fresh  water  and cemented  all  the  way  to  the



surface  to  effectively seal  fresh  water  zones from  deeper



injection fluids.  Although these  plugging methods  satisfied




regulations  at the  time,    they  are inadequate  as  they provide



potential  flow paths  for upward  migration  of  reservoir  and/or



injection fluids to shallower fresh water zones.






    Controlled Source Audio-Frequency Magnetotelluric Survey



     Controlled  source audio-frequency magnetotellurics  (CSAMT)



is  a  relatively new technique  first  used on  a consistent



commercial basis in 1978 by Zonge Engineering of Tucson, Arizona.



The CSAMT technique is  similar to  the conventional  audio-



frequency magnetotelluric  (AMT)  method,  with the exception  that  a



fixed current  source  is substituted for  a  natural earth-telluric



source resulting in a fixed,  dependable signal.






     The  primary objective  in  a  CSAMT Survey  is to provide



apparent  resistivity  and  phase angle  soundings  over a prospect




area.   The  technique is  particularly  effective  at  identifying




buried, conductive features.   It  has been successfully  applied in



hydrocarbon exploration, mineral exploration, and  geothermal
                                   -299-

-------
exploration,  and mapping  of  EOR fronts  (steam  front).   In this




particular case the application of interest was to use the CSAMT




to locate suspected low resistivity anomalies in the vicinity of




wells thought to be improperly plugged and abandoned.






     CSAMT has  several advantages over the other  geophysical



methods.   It has good lateral resolution,  good  depth  penetration,




is fast  and relatively inexpensive, $1000  to $2000 per line




kilometer (or approximately  $200  per  station),  depending on the




receiver dipole spacing used.  It is  also relatively  insensitive



to "cultural"  features  such as pipelines,  power  lines,  fences,



well  casings, etc.   Disadvantages associated with CSAMT include



difficulty in data  interpretation due to near-field effects and




difficulty  in estimating depths to anomalous two  and three-



dimensional  features without extensive computer  modeling  and some




geologic  input.    It  is   important  to   consider  the  specific



requirements of a field project before deciding  whether or not to



use CSAMT.






CSAMT Layout in Study Area




     A typical  layout  for a CSAMT Survey  is shown  in Figure 5.



The large transmitter  dipole is located as far away from the



receiver dipole as  is  practical  - usually  three  skin depths at




the lowest frequency being used.  Skin  depth (6)  is related to the




signal  penetration into the ground,  and is defined as:
                                  -300-

-------
        Controlled source AMI
                                     400 Cycle Engine
co
o
            NOTE: Not to Scale


            Current Electrodes

            Potential Electrodes
                                                                                 AMTCoi
                                                                             LAYOUT FOR
                                                                 CONTROLLED SOURCE AMT SURVEY
                                                                               Figure  5

-------
     Skin depth ( 
-------
        EXPLANATION
   f>    Water Injecnan Well

   •    Oil Well

-T	T- Powerlme

        Pipeline

        Fence

        Sac 8 Fo« Boundary
NOTE  a =200 ,  Deormg N60E
BASE MAP Bl A/Tenneco niap supplied uy
Engineering Enterprises
                                                                                                 T.UW.II  o   Line 783
                                            Figure  6 - Layout  of Lines for  CSAMT  Survey.

-------
          5  W W
18.0        17.0       16.0        15.0       1M.0
                                                                          13.0
11.0        ie.0
                                                                                                    9.0
                                                                                                               B.0
                                                                                                                7.0
                                                                                                               —I	N 6« E
COQNIRRD RESISTIVITY
 values in
                  13.8
     1C2U Hz
      512 Hz 4
      250 Hz 4
      12* Hz 4



       I
      OJ
      o
      *-
       i
       W Hz J-
                                                                                                                                                            24U8 Hz
                                                                                                                                                            1«2U Hz
                                                                                                                                                             512 Hz
                                                                                                                                                             256 Hz
                                                                                                                                                       4    ize HZ
                  5.S
                                                                                                                                                              6U Hz
                                                                                                                                                              22 Hz
CQ
 C

 CD
                 UW»ITM1IC CONTOURS   (  Intcrvah   «.!«)
i:?'
2.51
3.16
3.96
S.fl
6.31
T.SK
It.t
12.6
                                                                                                                                                                    2ong* « 347
                                                                                                                                                                    Plot bu CPLOT 3F
                                                                                                                                                                    Plotted BPR 16 IB

-------
resistivity  of the ground underlying line  3  (in ohm meters)


plotted against the frequency (in Hz)  at each station on line 3.


The same data is also shown in Figure 8 except that the apparent

resistivity is plotted against depth.    A pseudo-section such as

Figure 8  can be  viewed  as showing  relative  depths  in  an


approximation to a  vertical  slice  through the  ground.



     The depth  of  penetration in  a  layered  environment can  be


estimated from the  following MT equation:


    Depth of  penetration  =  356 /_£_  meters
                              V f
                      p  =  ground  resistivity  in ohm meters


                      f  =  frequency in Hz

     Figure  7  shows  the  vertical  low resistivity  anomaly

extending  laterally between  stations  10  to 16 and  extending  to


depth below.   The low resistivity anomalies are more significant


at approximate depths  of  14, 40,  and 80 meters at station 13  and


at an  approximate  depth  of  13  meters at  station  11.   The  low


resistivity (high conductivity)  anomalies  can be  identified  more

clearly in Figure 8.   The  low anomaly extends to a  depth of  at

least  82 meters below  station  13.   These significant  low

resistivity  anomalies are  most  likely  caused  by improperly

abandoned  and plugged wells.  However,  this will  need to  be

verified and  confirmed in  future  studies  through  detailed  test

drilling and  water  quality  sampling.



     Figure 9 is a  horizontal  view at  a depth  corresponding to 64


Hz.  At  station 13  this frequency  corresponds  to a  depth of

approximately 63 meters.
                                  -305-

-------
        17.0  16.6
                               iz.t  11.1  t«.a
                                                          6.*
S £• H I
                  !.»   >-i~ ...&.,
 • ^r*l"5^  '•*^*^** X LI  \ •   « «       ».•

J'*  \ J.V^Tt? /J \'»*f X"'  /'!   !»'•'  !\	M  UOMIIIH
^i  i»:r ••?,«(•»;« )vi s  »••   /   i'/  7    v^   ,«

"'•  /.;-,w v-  ,y..    .-   cf  -^   s
                  •:        V   ,   l,s,    ....

                  > al   ' _..   . I .  . .
                                                  DESISTtVITY

                                                  in
                                                              uewirwic canouu  i

                                                                .H
 •;»

                                            t.l
                                                                  1.3*

                                                                  I.H
                                                 v  A
                                            M       4.3
                                                             r	1 i-s
                                                             I——I J.I
                                                          t.t
                                                              luat » M>
                                                              f loTow CfUJI 3H
                                                              riciiM MC M it
   Figure 8  - Vertical  Pseudo-Section  Line  3 Resistivity versus  Depth.
                                       -306-

-------
        CflGNIflRD RESISTIVITY at 64  Hz ior lines  1  to 5
o
1
                                                              7.8
  in
       FEET
< = = = =  increcTs'ing station  numbers
                                                           .8.2
                                                                     o. u

-------
In Area of  Current Injection Activity




     In the  area  of  current  injection  activity,  line  8  was




selected for presentation.  Figure  10 is  a vertical  pseudo-




section  showing  apparent  resistivity versus  frequency  while



Figure 11 plots apparent resistivity versus depth.  Note the low




resistivity anomaly extending to depth  below  station -4.0,  Figure




10,  and a depth of 114 meters below station -4.0, Figure 11.   It




is particularly  interesting because  it  spreads out  near  the



surface and  the  apparent resistivity has  the lowest  value near



the surface, indicating  possible  surface  or  near surface  spills



or leaks.






     Figure 12 is  a horizontal  view at a  depth corresponding to




a frequency of 64  Hz.   This corresponds  to a depth of 63  meters



at station  -4.0.






Test Drilling of  CSAMT Anomalies



     Two test well sites in line 8 were selected on the basis of



the CSAMT  results.   Test well  #1  was  located  at station -2.0,



line 8 because of the contrasting resistivites encountered with



depth.   Test well #2  was located at station  -4.0,  line 8 where




the surface  resistivity  is  the lowest and the conductive plume




appears to  be deep seated.






     The stratigraphic sequence of rock penetrated in both wells




drilled in  July,   1984 is shown  in  Table  3.   Rock cuttings were




logged continuously during the drilling of each well.   The first




good water bearing zone  encountered  was  in  the Vamoosa,  in the




interval  120-150  feet in test well #1, and in the interval 113-
                                  -308-

-------
                                        Ml 63
1.0
     U)
     o
(Q
 c
 —»
 CD
                             S 60 N
                                                0.0       -i.e
                                -2.0
                                —i—
-3.0
                        i2« HZ
 -1.0
—t—
 -5.0
	1  N S0 E
                                                                                                              -r   utas HI
                                                                                                                   812 Hi
                                                                                                                   25fl Hi
                                                                                                                   129 Hi
                                                                                                                    eu HI
                                                                                                                   32 Ui
                                                    COCNIflRD RESISTIVITY
                                                     values  In ohn-nelers
                                                                                                                                    LOCflRITHMIC CONTOURS   I  Interval,   «.!« I
                                                                                                   2.M
                                                                                                   2.51
                                                                                                   3. IE
                                                                                                   3.08
                                                                                                   S.tl
                                                                                                   6 31
                                                                                                   7.8M
                                                                                                                                   Zonoe » 347
                                                                                                                                   Plot by CPLOT 3F
                                                                                                                                   Plotted APR 16 li

-------
          U«ll S3
       L.9    9.9    -1.8   -Z.9    -3.8   -4.9   -5.9
3 69 H  I	1	1	1	1	1	1  N 69 E
CflGNIfKD RESISTIVITY
 values in ohm-meters
                                                                               UWWITHMIC CONTOURS  ( Interval,   0.14)

                                                                                   2.W
                                                                                   2.51
                                                                                   3.16
                                                                                   3.08
                                                                                   5.41
                                                                                   S.31
                                                                                   r.w
                                                                                   19.9
                                                                                   12.6
                                                                               SWING LEGEND

                                                                                ^^     I SO
                                                                                       2-51


                                                                                       3.16
                                                                                       3.98
               9.5
                r

               5.1
                                                                               Zonge » W7
                                                                               Plot by CaOT 3H
                                                                               Plotted DEC 31  I98H
                                                     -310-
                                                                                                    Figure  11

-------
     ZONGE ENGINEERING & RESEflRCH ORGflNIZflTIGN
     COGNIflRD RESISTIVITY qt SU- Hz for Linas 7.8. and 9
SAC 8. FOX PROJECT

-------
Table 3   Stratigraphic Sequence of Rock Penetrated in July, 1984 Test Wells






                       Alluvium	Ma Group	Vamoosa Formation



   Test Well  #1          0-9 m.           9-23 m.           23-91 m.



   Test Well  #2          0-10 m.         10-20 m.           20-91 m.
                                      -312-

-------
137 feet  in  test  well  #2.   Water  samples  were collected from a



shallow,  intermediate,  and  deep zone in  each well   and  the




composition and bromide/chloride ratios determined.   Results of




the analyses are shown  in Table  4.






     The bromide/chloride ratios are  similar  to the ones  obtained



earlier and  are within  the  range  of  typical  Oklahoma   oilfield



brine which is  0.003 to  0.01.   This  indicates  that  the  probable



source  of  polluted  Vamoosa  ground water is  Prue oilfield brine



regardless  if  it  came  from  surface   spills,  improperly plugged



wells, or mechanical integrity failure  of injection wells.  After



logging and testing operations, both  wells were completed as



monitoring wells to provide  future monitoring data of the ground




water.






Conclusions



     The  CSAMT technique has been successful in locating  low



resistivity anomalies which appear  to  result  from  oilfield brines



in  the  vicinity  of improperly  plugged wells and near active



injection wells.    Two  deep  conductive plumes and one shallow



conductive feature were detected and  traced in  the area  of active



injection wells in Section 15, while  on  the grid  in Section 16 in




the area of improperly plugged wells,  one localized deep feature



and two deep plumes  were detected  and  traced.   Several  of these



plumes  ran out  of  the  edge of  the survey  grids and their extent



is not known.






     Test  drilling  confirmed  the  low resistivity  anomalies



detected by the CSAMT Survey.  Future  studies of  this  type should
                                  -313-

-------
Table 4  Constituent Concentrations and Ratios  for Vamoos Water Samples
                         (July. 1984 Test Wells)
Well
No.
I


2


Sample
No.
1
2
3
1
2
3
Depth,
m.
40
61
87
38
56
90
Cl,
mg/L
950
1,180
1,200
650
664
643
Br,
mg/L
4.9
5.9
6.1
3.5
3.6
3.4
Br/Cl
0.0052
0.0050
0.0051
0.0053
0.0054
0.0053
                              -314-

-------
include sufficient  test drilling and  logging  to gather data  to

permit  comparison  and  correlation  of  known salinity  contrasts

with  resistivity  contrasts.   Once  the baseline contrasts  for  a

given area or oilfield  are established, detecting and  tracing  of

conductive plumes  might be  combined  with estimates of  water

salinity to give even more useful results.


                        ACKNOWLEDGEMENTS

     Partial funding  for  the Vamoosa ground water  contamination

study  (including  the CSAMT Surveys) was  obtained from  the U.S.

Environmental Protection Agency as part of  Project  68-01-6389  of

the  Underground  Injection  Control Program and is  gratefully

acknowledged.  The cooperation of the  Sac and Fox  officials

including Mr. Truman Carter is also acknowledged with  thanks.


                           REFERENCES

Bingham, R.H. and Moore, R.L., 1975.  Reconnaissance of the Water
     Resources of the Oklahoma City Quadrangle,  Central Oklahoma:
     Oklahoma Geological Survey,  HA-4.

D-Lugosz, J. , and McClaflin,  1978.   Geohydrology of the Vamoosa
     Aquifer,  East-Central  Oklahoma:   U.S. Geological  Survey
     Open-File Report 78-781.

Fryberger,  J.S.,  and  Tinlin,  R.M., 1984.   Pollution  Potential
     from Injection Wells via Abandoned Wells,  presented at First
     National  Conference on Abandoned  Wells:    Problems and
     Solutions,  Norman, Oklahoma, May 1984.

Hart, D.L., 1966.   Base of Fresh Water in Southern Oklahoma, U.S.
     Geological  Survey, Hydrologic Investigations Atlas HA-223.

Whittamore, D.O., 1983.   Geochemical  Identification of  Salinity
     Sources in Proceedings of International Symposium on  State-
     of-the-Art Control of Salinity;  Ann Arbor, Michigan.
                                  -315-

-------
                      BIOGRAPHICAL SKETCHES






     Dr. Richard Tinlin  is a Vice President with  Geraghty  &




Miller,  Inc. located  in  Tucson,  Arizona.   He  has over 20  years




experience in hydrogeology and geophysics.   He  holds  a Ph.D.  from



the University of Arizona in Watershed Hydrology  with  a minor  in



mineral  exploration,  and  a B.S.  in Geology  from Arizona  State




University.






     Talib Syed  graduated with a degree in  Chemical  Engineering




from the University of Madras,  India in 1971 and earned a  Masters



or Petroleum Engineering  from  the University of Oklahoma,  Norman,



in 1983.   He previously  worked as  a  petroleum engineer  for  the



Arabian-American Oil  Company  in Saudi Arabia  from 1974  to  1979



primarily  in production,  reservoir,  completions and  workovers,



both onshore and offshore.   He currently is Program Manager  - UIC



Projects for a nationwide  contract providing technical  assistance




to the  EPA in  the  implementation of the UIC Program  in the  non-



primacy states.






     Steve Figgins  is  a  geophysicist  with Zonge Engineering  in



Tucson,  Arizona.   He obtained  a B.S.  in geophysics from  the



University of Arizona in 1982 and has  experience  in  CSAMT and  CR



methods in  Australia and  the United States.   He  is  present



working as General  Manager of  Zonge Engineering while pursuing an




MBA degree at the University of Arizona.






     Roger Anzzolin  graduated with  a degree in geology  from




Wichita State University,  Kansas  (1970) and a  Master's degree  in
                                  -316-

-------
Environmental  Engineering from  Florida  Institute  of  Technology,



Melbourne,  Florida (1979).   He worked with the U.S. Army for four



years on pollution  abatement and  installation  restoration  (IR)



projects.   Since  joining  the Environmental  Protection  Agency  in



1979.  Roger has  held numerous varied  assignments.   He  also



manages the  UIC Implementation Contract for  regional program



support in  Direct  Implementation states,   and chairs the



mechanical  integrity  workgroup in the branch for the UIC program.



Mr. Anzzolin is a member  of  the Groundwater Technology Division



of NWWA.
                                  -317-

-------
     CONVECTIVE CIRCULATION DURING  SUBSURFACE INJECTION OF LIQUID WASTE
                               John J. Rickey
                U.S. Geological Survey, Tampa, Florida 33634
                                  ABSTRACT
     Injection of liquid waste into a highly transmissive,  saltwater-bearing,




fractured dolomite provided an opportunity to study density-dependent  flow




associated with two miscible and density-different liquids.   Mean chloride




concentration  of the injectant during two tests of 91 and 366 days  duration




was 180  and  170 milligrams per liter, respectively; whereas  chloride concen-




tration  of native saltwater ranged from 19,000 to 20,000 milligrams per  liter.




During the 366-day  test, chloride concentration  in water from  a well open to




the upper part of the  injection zone  223 meters from the  injection well




approximately stabilized at about 3,900  milligrams per liter.   Approximate




constancy of  chloride concentration in water from this observation well  at  a




level significantly greater than the  injectant  concentration suggested the




hypothesis that convective circulation with saltwater flow added chloride  ions




to the injection-zone flow sampled at the observation well.




     In  order  to assess  the acceptability  of the convective circulation




hypothesis,  information was required about  the velocity field during injec-




tion.  Mass-transport model simulations were used to provide this information
                                    -318-

-------
after determining that the fractured injection  zone could be  treated as an




equivalent porous medium with a single  porosity.  The mass-transport model was




calibrated using the 91-day test data from  the  observation well  223 meters




from the  injection well.  The model was  then run without parameter changes to




simulate the  366-day test.  Mass fractions of injectant computed for observa-




tion wells during the  366-day test compared  favorably with  observed mass




fractions.  Observed mass fractions were  calculated as a function of chloride




concentration and density.  Comparisons between model-computed mass fraction




and velocity  fields in a radial section  showed  convective circulation with




saltwater flowing toward the injection  well  in the lower part of the injection




zone, then mixing with the injectant, and the mixture flowing  away from the




injection well in the upper part of the  injection zone.  Based upon the model




results and the assumed reasonableness  of treating  the injection  zone as an




equivalent porous medium with a single porosity, the hypothesis of convective




circulation during subsurface injection of liquid waste into a  highly trans-




missive, saltwater-bearing, fractured dolomite was judged acceptable.
                                INTRODUCTION









     Subsurface  injection of  liquid waste  into a highly  transmissive,




saltwater-bearing, fractured dolomite provided an opportunity  to  study




density-dependent flow  associated with  two miscible and density-different




liquids.   Two injection tests  were  run at a  site  in  the  city of




St.  Petersburg, Florida (Figure 1).   The first  test was run for 91 days and
                                    -319-

-------
                     86°
                      i
      84°
      i
ST. PETERSBURG



 TEST SITE
                   0    10   20 MILES
82°
 i
80°
 i
                                                                -30°
                                                                -28C
                                    -26°
                   0
32 KILOMETERS
                     Fig. 1.  Location of test site.
                                   -320-

-------
the second test  for  366  days.   During  the second  injection test,  chloride




concentration in water  from an observation well  open to the  top of the




injection zone at  223 m  from the injection well changed slowly after passage




of the  injectant front and, toward the end of the test,  became  approximately




stable at concentrations (3,900 mg/L) significantly above  the concentration of




the liquid-waste injectant  (170 mg/L).  The liquid waste was  treated  municipal




sewage similar in  composition and density to freshwater.   Native  saltwater in




the  injection zone was similar in composition and density  to seawater.  The




observed chloride-concentration data  raised questions about the transport




processes that occurred  in the injection zone during injection.   Approximate




constancy of chloride concentration in water from  the observation well at a




level significantly above  the injectant concentration suggested the hypothesis




that convective circulation with saltwater flow, related to a convection cell,




added chloride ions to  the  injection-zone flow sampled at  the observation well




(Hickey and Ehrlich,  1984).




     Convective circulation  in variable-salinity ground-water  flow has been




discussed as a possibility  by several  other authors.   Flow of  saline water




opposite to the flow of  overlying and less dense fresher water in an  isotherm-




al, variable-salinity ground-water environment was discussed  by Cooper (1959)




and Cooper et al.  (1964).   Cooper theorized that saltwater would  flow landward




in a coastal aquifer in  response to dispersion of saltwater into  seaward flow-




ing  freshwater.  A similar idea was  proposed by Carrier  (1958).   Hubbert




(1957) and de Josselin  de Jong  (1969) concluded that circulation would occur




in a  variable-density  ground-water environment as a result  of density gradi




ents that were related  to  salinity variations.
                                     -321-

-------
     Even  though the mechanisms and resulting  flow patterns postulated by some



of the  above mentioned authors differ, they all are in  agreement that  some



form of convective circulation, related to a convection cell, may occur during



variable-salinity ground-water flow.  This article evaluates the hypothesis of



convective  circulation  as  an explanation for the approximate constancy of



chloride concentration at a level significantly above the  injectant concentra-



tion in water from an observation well during subsurface  injection.   To



achieve this purpose, the 91-day and 366-day injection tests  are described.



Then, the  hydrogeologic characteristics of the test  site  are described with an



emphasis on  treating the  fractured injection zone as an equivalent  porous



medium with a single porosity.  This  is followed by a  discussion wherein a



numerical, mass-transport model is calibrated  with data from the 91-day  test



and  run without parameter  changes to  simulate the 366-day test.  Finally,



model-computed mass fraction and velocity fields are compared and interpreted



with regard  to the acceptability of the convective-circulation hypothesis.
                              INJECTION TESTS







     Injection  of treated sewage into a saltwater-bearing aquifer was tested



for 91 days in 1977  and for 366 days in 1979 and 1980  at  a  test site  in the



city  of  St.  Petersburg,  Florida  (Rickey,  1982; 1984b; Rickey and Ehrlich,



1984).  During the 91-day  test, the injection well became  partially plugged by



algae  in the liquid waste  (Rickey, 1982).  Mean injection rate for the 91-day


                43                                        33
test was 1.54x10  m /d with a standard deviation of  1.28x10  m /d,  and the


                                                       4  3
mean  injection  rate during the 366-day test was 1.33x10  m /d with a standard



deviation of 2.31x10  m /d.  The mean injection rate  for the  366-day  test was



about 14% less than the 91-day test.
                                    -322-

-------
                         473 m-
                                        223 m
 O
Cl
  O
B2, B3
B6  O'
                                .INJECTION WELL
                                                 M.
                                                          OJ

                                                          3
                               100 METERS
                                                       O-
                                                      C3
 Fig. 2.  Areal configuration of wells open to  the  injection  zone.
                               -323-

-------
     Chemical composition of injected sewage was similar  during both  tests.



The mean  concentration of dissolved solids during  the 91-day test was 508 mg/L



and during  the  366-day test was 466 mg/L.   The mean density  of the treated


                               3
sewage injectant was 999  kg/m  for both tests,  and mean chloride concentra-



tions were  180  mg/L and 170 mg/L during the 91-day and  366-day tests, respec-



tively.   Chloride concentration of native water from the injection zone before



injection occurred was similar to seawater and ranged from 19,000 mg/L  in the



upper part of  the zone  to 20,000 mg/L in the lower part.   Density of the


                                      3             3
native saltwater  ranged from 1,025 kg/m  to 1,026  kg/m  .



     Areal configuration of wells open to the injection zone at the test site



is shown in Figure 2.  The  injection-zone interval and  water-producing  inter-



val  open to each observation well are shown in  Figure 3.  Wells B3, B6, Cl,



and C3 are  open to the upper part of  the injection zone, and the  injection



well and well B2  are  open to the lower part of the zone.   Wells Cl and C3 were



constructed after the 91-day test to monitor the 366-day test for evidence of



anisotropy  in the plane of  the injection zone.



     One month  before the start of the 366-day test,  chloride concentration in



water from well  B3 was  14,000 mg/L; from wells B6,  Cl,  and C3,  it was



18,000 mg/L; and from well  B2, it was 20,000 mg/L.  These data suggest that



chloride concentrations are stratified in the injection  zone at the start of



the  366-day test.



     Chloride  concentrations in water from well B3 during the 91-day and 366-



day  injection tests  are  shown in Figure 4.  For  the  period common  to both



tests,  chloride concentrations are similar and show little or no influence



from plugging of the  injection well.  Similar concentrations during both  tests



would be expected because the mean chloride concentration of injectant for



each test was very similar  and the mean  injection rate  for each test  differed
                                     -324-

-------
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by  only 14%.     During  the 366-day  test,  chloride  concentration  slowly


decreased after passage of the injectant front and became approximately stable


at  about 3,900 mg/L  after 190 days from the  start  of the test.  Because this


concentration was  significantly larger than the injectant concentration  (170


mg/L) ,   it  appeared that  chloride ions were somehow being added  to  the


injection-zone  flow sampled at well B3.   This  consideration played an import-


ant role in developing the hypothesis of convective  circulation with saltwater


flow  (Hickey and Ehrlich,  1984).  Convective  circulation  was thought to be


related to a convection cell similar to the type proposed  either by Cooper


(1959) or by de Josselin de Jong  (1969).  Well B3 is emphasized in mass-


transport model  calibration, discussed below,  because it showed no apparent


influence from injection-well plugging,  as did well  B6.


      Chloride  concentrations  in water  from well B2  during  the 91-day and 366-


day injection tests are  also  shown  in Figure 4.  During  both   tests, chloride


concentrations did not  change and remained at the  native  chloride concentra-


tion  of  20,000 mg/L.
             HYDROGEOLOGIC CHARACTERISTICS OF THE INJECTION  ZONE





     The injection zone at the test site is composed of a dolomite  that is in


 the middle Eocene series.   The injection zone is in the Upper Floridan  aquifer


 and is overlain and underlain by semiconfining beds  (Figure 5) .    The  top of


 the  injection zone  is at 234 m below sea level.   Thickness of  the  zone is


 about 98 m.  Darcian flow  occurs in the injection zone,  at least beyond 11 m


 from  the injection  well  (Hickey, 1984a).   Transmissivity  of  the  zone at the

                           2
 test site is about 75,000  m /d,  whereas  transmissivity of the zone  beyond
                                     -327-

-------
DEPTH BELOW LAND SURFACE, IN METERS
J) Ul A OJ PO —
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D O 0 O O O O
-
HYDROGEOLOGIC
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system
Intermediate
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Upper
Floridan
aquifer
Middle
confining unit
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Floridan
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semiconfining
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INJECTION
ZONE
semiconfining
bed

Fig.  5.   Hydrogeologic section of the injection site.
                        -328-

-------
24 km and east of the  site may be less (Hickey, 1981).   The vertical component




of hydraulic conductivity of the overlying and underlying semiconf ining beds




is estimated to lie between about 0.03 m/d and 0.3 m/d (Hickey.  1982).




     Regional saltwater  flow toward the southeast likely occurs  in the injec-




tion zone (Hickey, 1982) .   However, the apparent stratification of chloride




concentrations prior to  the 366-day test suggests  that flow of  native salt-




water  in the neighborhood of the site  was of  little importance before  and




during injection.




     A total  porosity of 14% for the rocks comprising the injection zone  was




estimated in one borehole  at the test  site from  geophysical  logs (Hickey,




1982).   Transport-model simulation of the arrival time of the  injectant  front




at well B3,  223 m from the injection well, discussed later, required an effec-




tive porosity of 10%.   Both estimates are remarkably consistent considering




that the borehole geophysics estimate is based upon measurement  of rock prop-




erties in the immediate vicinity of the borehole.  Even though  this comparison




of porosities may be  fortuitous, it does suggest that porosity  may be distrib-




uted more or less uniformly  throughout the injection zone.




     The injection zone generally can be characterized as a fractured crypto-




crystalline to microcrystalline dolomite with minor solution enlargement  along




some of the fractures.  The  fracture pattern in the dolomite is  very complex




and  cannot be described by  a  simple repeating pattern of similarly spaced  and




oriented fractures.  A borehole television survey and a caliper log of a test




hole drilled  into the injection zone showed the wall of the  hole to be very




blocky with fractures  between  the blocks generally occurring about every  0.3




to 1.0 m.  Cores taken from holes  within 24  km of the site showed oblique




fractures oriented between  30  to 60 degrees from the axis of the cores.  Some




of the cores also showed horizontal fractures.  Added to this fracture pattern
                                    -329-

-------
are shattered  intervals that collapsed during  drilling.  A shattered interval

was cored  at  another site  in the area  (Hickey,  1977) and  showed fracture
                           .3
spacing on  the order of 5x10   m and less.   Shattered intervals appeared  at

different  depths in holes  drilled into  the  injection zone, not only at this

site but at other sites in west-central Florida.  When encountered in a bore-

hole,  shattered  intervals were always water-producing intervals, although not
all water-producing intervals identified in boreholes were shattered (Hickey,
1982).   Conceptually, the varying positions  of  shattered intervals and other
water-producing intervals, along with the  blocky  character  of the injection
zone,  suggest a branching  network of numerous intersecting fractures.   As
noted by Long  et  al. (1982), when fracture density is increased, when fracture
orientation is distributed (as would be the case with numerous intersecting
fractures), and when larger sample sizes of fractures are tested (as would  be
the case with 6-m  to 33-m thick water-producing  intervals), fractured systems
behave like a  porous medium.
     Supporting the perception of a high fracture density are the observations
                                                                       2
that the injection  zone has a very high transmissivity  (about 75,000 m  /d) ,
yet the injection well became plugged during the first injection test at the
site (Hickey,  1982).  In order to explain both of these  occurrences, the
injection  zone at the well would have  to be composed of numerous fractures
with relatively small aperture rather  than a few fractures with relatively
large  aperture.   Other  injection wells within 24 km of this site also became
plugged during injection  of secondarily treated sewage indicating that the

zone has similar  physical characteristics throughout the area.
     The injection  zone also can be  described as a collection of variably
sized crystalline dolomite blocks with bounding fractures.  Visual examination
of  the  crystalline dolomite indicates  that it generally has no  visible
                                    -330-

-------
porosity  and thus  should have very small,  if measurable, hydraulic conductiv-




ity and effective porosity.   Five representative cores  of the crystalline




dolomite blocks  taken  from test holes within 24 km of  the site have laboratory




measurements of  hydraulic conductivity that did not exceed  2.0x10   m/d with




four  of the five  cores  at  or below the  detection  limit  of the permeameter




(Hickey, 1977; Mickey  and Barr, 1979).   An additional  10 representative cores




of the  crystalline dolomite blocks,  also taken from holes within 24 km of  the




site, have laboratory  measurements of  effective porosity  that have a mean




value of 0.9%  (Hickey.  1977; Rickey,  1979;  Hickey and Barr, 1979).   The




branching network of numerous intersecting fractures  and the very small




hydraulic conductivity  and effective  porosity of  the crystalline dolomite




blocks strongly  suggest that the injection zone can be treated as an equiva-




lent porous medium  with a single porosity.
              CALIBRATION OF THE SWIP MASS-TRANSPORT MODEL USING




                          THE FIRST INJECTION TEST









     The SWIP finite-difference mass-transport model  (Intercomp, 1976; Intera,




 1979) was calibrated using data from the 91-day injection test.  The model,  as




 used in this article,  solves for two dependent variables --pressure  and mass




 fraction of injectant--in two dimensional, cylindrical  (r-z) coordinates under




 isothermal conditions.   Central-in-space and central-in-time finite-difference




 equations were used in the numerical model. The  reduced band-width direct-




 solution procedure was  used  to solve the equations.




     In addition to equivalent porous medium and single porosity assumptions,




 other  major assumptions  in the mass - transport model application  are:
                                     -331-

-------
hydrostatic  conditions prevail in  the  injection zone at  the  start of




injection; the injection zone  is confined;  hydraulic characteristics of the




injection zone are  radially  extensive; and flow during  injection is




isothermal.  The first assumption  ignores background flow of  the  resident




saltwater and  restricts model computations  to effects caused solely by




injection.  The second and third assumptions  restrict model computations to




effects caused  by injection within  a  confined, radially symmetric cylinder




that has uniform characteristics.  The fourth assumption restricts model




computations  to effects caused by constant temperature ground-water  flow.




Because the injection zone,  as discussed in  the hydrogeology section,  only




approximately satisfies these assumptions, it  was hoped that  the  hydraulic




characteristics assumed for the model, although likely nonunique,  would be




close enough to the actual characteristics of the  injection zone  such that the




major  flow processes during subsurface  injection would be approximately




simulated.




     The original plan for calibrating the mass - transport model  envisioned




using mass - fraction data  observed  in wells  B2 and B3 and holding all




injection-zone hydraulic characteristics constant except for dispersivity,




which  was to  be varied.  During  the trial and  error calibration process, a




minor alteration to the plan was necessary.  In  addition to varying dispersiv-




ity, porosity was changed,  as mentioned above, from 0.14 to 0.1 to improve




comparisons between the observed and computed arrival time of  the injectant




front at well  B3.  During the  91-day injection test, the front arrived at well




B3 sometime between 9 and 15 days from start  of  injection.  Model runs using  a




porosity  of 0.14 consistently computed the front  arriving between 15 and 20




days.  After changing porosity to 0.10,  the arrival  time computed by  the  model




was consistent with the observed data.
                                   -332-

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     Mass  fractions  of  injectant computed by the calibrated model  and observed




mass fractions of  injectant at wells  B2 and B3 are shown in  Figure 6.  The




model calibration, in addition to what has already been mentioned,  mainly en-




tailed varying the longitudinal and transverse dispersivities  in a trial and




error fashion until  what was  considered an acceptable fit between  computed and




observed mass fractions occurred.  Mass fractions computed at well B3 differed




from observed mass fractions  by no more than 0.06 and were generally much less




than  this,  as can be seen in Figure 6.  Also, mass fractions computed at well




B2 showed no changes and,  as  such, agreed with the observed data.   Longitudi




nal and transverse dispersivities of the calibrated model were 2.85 m and 0.85




m, respectively.  These values compare reasonably well with  the longitudinal




(6  66  m)  and transverse  (0.66 m)  dispersivities  found by Segol and  Finder




(1976) in their model analysis of saltwater intrusion into a highly transmis-




sive aquifer in southeast  Florida.
                   SIMULATION  OF  THE SECOND INJECTION TEST









     After  calibration,  the  model was run without changing any of the  param-




 eters for the purpose of simulating  the 366-day  injection test.   Figure  7




 shows  the distribution in a radial  section of  observed and computed mass




 fractions of injectant at the  end of the 366-day test.   The leading edge of




 the  injectant front in the upper part of the injection zone is approximately




 at the position of the 0.30 mass-fraction contour as it was  for the 91-day




 test.   In general,  the observed  mass  fractions of injectant shown in Figure  7




 compare very favorably with the computed mass fractions.   This  is true even in




 the  immediate vicinity of the injection well where observed and computed mass
                                      -334-

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                                                                             FRACTION OF INJECTANT
0\  100  200   300   400   500   600   700   800  900  1000  1100  1200  1300  1400  1500  1600
  \               DISTflNCE PROM INJECTION  WELL,IN METERS

 INJECTION WELL
                Fig. 7.  Observed and computed mass fractions of injectant in a  radial  section of the injection
                                              zone at the end of the 366-day  test.

-------
fractions  for well B6 were, respectively, 0.91 and 0.98.  Also shown in Figure




7 is the  initial mass-fraction distribution that was used in the model at  the




beginning  of the injection-test simulation.




     Because the observed and computed mass fractions of injectant compare




favorably  with each other during the 366-day test,  particularly at wells Cl




and C3 , this not only strongly supports  treatment of the injection zone as an




equivalent porous medium with a single porosity, but also, that  the model is




likely simulating the major flow processes  that occur during subsurface injec-




tion.   Thus, it appears that model computed velocity fields may be interpreted




with some  degree of confidence.
                       MODEL-COMPUTED VELOCITY FIELD









     Figure 8 shows  the model-computed velocity field at the end of the  366-




day injection  test.  The velocity field shows  convective  circulation  in a




radial  section of the  injection zone  related to a convection cell.   Flow




within  the  region of convective circulation  is  generally away  from the




injection well in  the upper part of the zone, whereas flow is generally toward




the injection  well in the lower part of the zone.   Separating these outward




and inward flows is a shear zone wherein velocity vectors are about oppositely




directed.




     Figure 8  shows that buoyant or free convection occurs at radial distances




of less than 100 m from  the  injection  well.   This is  consistent with the




interpretation of buoyant convection  based  upon the mass-fraction distri




butions shown  in Figure  7.   Beyond  the region of convective circulation,




Figure  8 shows flow directed away  from  the  injection well throughout the




injection zone.
                                    -336-

-------
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                   EXPLANATION

PORE VELOCITY VECTOR. MAGNITUDE OF VECTOR IS PROPORTIONAL TO SHAFT
LENGTH. FOR LOW VELOCITIES, VECTORS HAVE NO MEASUREABLE SHAFT. IN
THESE CASES, TIP OF ARROWHEAD IS LOCATED AT THE NODE POINT. THE FIRST
COLUMN OF VECTORS IS SHOWN AT 6 METERS FROM THE INJECTION WELL.
THEREAFTER, EVERY FIFTH COLUMN OF COMPUTED VECTORS IS SHOWN
- •=* •=>- •>•
->:=- ;=-==-=-

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     Comparison of Figure  7  with Figure 8  shows that downward flow in  the


outermost band  of convective circulation is  in the vicinity but beyond the


leading edge  of the injectant front.   For the test,  the  leading edge of  the


front  is approximated by the intersection of the 0.3 mass-fraction contour


with the top  of the injection zone.   Comparison  of these figures, in addition,


shows  that  counter flow  directed toward the injection well in the lower part


of the zone  is mostly saltwater.


     Between  100  and 800 m from the injection well, model results for the 366-


day test also show that some of the counter flow of saltwater mixed with  flow


away from the well at a rate of about 4,100 m /d.  Also, saltwater with a rate

               3
of about 5,600 m  /d flowed past 100 m to subsequently mix  with flow in the


neighborhood of the injection well.  Because mostly saltwater was added to


flow occurring away from the injection well in the upper part of the zone, the


magnitude  of mass fraction of injectant and the temporal rate of change in


mass fraction of  injectant at points within the upper part  of the injection


zone should be markedly influenced.
                                CONCLUSIONS





     This article represents  an  effort to test the hypothesis of convective


circulation used to  explain the magnitude and approximate  constancy of  chlo-


ride concentration  in water from an observation well during subsurface injec-


tion of liquid waste into a saltwater-bearing,  fractured dolomite.  A numeri


cal model  was constructed as a simplified representation of the very complex


fractured injection  zone by assuming that it could be treated as an equivalent


porous medium with  a single  porosity.   Observed mass  fractions from  two
                                     -338-

-------
observation wells  during a 91-day injection test were  used to calibrate the




mass-transport model.  After calibration, the model was run to  simulate a 366-




day injection test.   Comparisons between observed and computed  mass  fractions




for the  366-day  test at five observation wells suggest that the model is not




only conceptually  appropriate, but also does likely  simulate the major  flow




processes  during subsurface injection.  Convective circulation with counter




flow of saltwater  in the injection zone was portrayed by the model as  a major




process  related to  a convection cell that influenced the distribution of mass




fraction and,  thus,  chloride concentration in space  and time.  Because  of




these  model results and the assumed reasonableness of treating the injection




zone as an equivalent porous medium with a single porosity,  the hypothesis  of




convective circulation is judged acceptable for explaining the magnitude and




approximate constancy of chloride concentration in water from an observation




well during subsurface injection.
                                 REFERENCES









Carrier,  G. F. ,  The  mixing  of ground water and  sea water  in  permeable




     subsoils,  Jour,  of Fluid Mechanics, 4, 479-488,  1958.




Cooper, H.  H. ,  Jr.,  A hypothesis concerning the dynamic balance  of  freshwater




     and saltwater in a coastal aquifer, Jour.  Geophys.  Res.,  64(4),  461-467,




     1959.




Cooper, H. H. ,  Jr.,  F.  A.  Kohout, H. R. Henry,  and R.  E. Glover,  Seawater in




     coastal aquifers, U.S.  Geol.  Surv.  Water-Supply Pap.  1613-C,  84 pp.,




     1964.
                                     -339-

-------
de Josselin de Jong,  G. ,  Generating functions in the  theory  of  flow through




     porous  media,  Flow  Through Porous Media,  edited by R. J. M.  De  Weist,




     pp.  377-400, Academic Press, New York, 1969.




Hickey,  J. J., Hydrogeologic  data for the McKay Creek  subsurface waste-




     injection test site, Pinellas County,  Florida,  U.S.  Geol.  Surv. Open-File




     Rep.  77-802, 94 pp., Tallahassee, Fla. 1977.




Hickey,  J. J. , Hydrogeologic data for the South Cross Bayou subsurface waste-




     injection test site, Pinellas County,  Florida,  U.S.  Geol.  Surv. Open-File




     Rep.  78-575, 87 pp., Tallahassee, Fla.,  1978.




Hickey,  J. J.,  Hydrogeology.  estimated  impact, and regional monitoring of




     effects of subsurface wastewater injection, Tampa Bay  area, Florida, U.S.




     Geol. Surv. Water-Resour. Inv. 80-118, 40  pp.,  Tallahassee, Fla., 1981.




Hickey.  J. J. , Hydrogeology and results of injection tests at  waste-injection




     test sites in  Pinellas County, Florida,  U.S.  Geol. Surv. Water-Supply




     Pap.  2183, 42  pp.,  Reston, Va., 1982.




Hickey,  J. J.,  Field testing the hypothesis of Darcian flow through  a  carbon-




     ate aquifer, Ground Water, 22(5), 544-547, 1984a.




Hickey,  J. J.,  Subsurface  injection  of  treated sewage into  a saline-water




     aquifer  at  St. Petersburg,  Florida-- aquifer pressure  buildup, Ground




     Water,  22(1),  48-55, 1984b.




Hickey,  J.  J. , and G.  L. Barr, Hydrogeologic data for  the Bear Creek  subsur-




     face waste-injection test  site, St. Petersburg, Florida, U.S. Geol.  Surv.




     Open-File Rep. 78-853, 53  pp., Tallahassee, Fla.,  1979.




Hickey,  J. J.,  and  G.  G. Ehrlich,  Subsurface injection of treated  sewage into




     a saline-water aquifer  at St. Petersburg, Florida--water-quality  changes




     and potential  for recovery of injected sewage, Ground Water,  22(4),  397-




     405,  1984.
                                     -340-

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Rickey,  J.  J.,  and R. M. Spechler, Hydrologic data for  the  Southwest  subsur-




     face injection  test site, St. Petersburg,  Florida, U.S. Geol. Surv. Open-




     File Rep.  78-852,  104pp., Tallahassee,  Fla.,  1979.




Hubbert, M. K.,  Darcy's law and the field equations of  the  flow of underground




     fluids, Bulletin  de Association Internationale  d'   Hydrologic




     Scientifique, 5, 24-59, 1957.




Intercomp Resource Development and Engineering,  Inc., Development of model for




     calculating effects of  liquid waste  disposal in  deep saline aquifers,




     parts I and II, Rep. USGS/WRI-76-61, PB 256 903,  236  pp.,  Reston,  Va.,




     1976.




Intera Environmental Consultants, Inc., Revision of the  documentation for  a




     model  for calculating effects of liquid waste  disposal in deep saline




     aquifers,  U.S.  Geol. Surv. Water-Resour. Inv.  79-96, 72 pp., Reston, Va.,




     1979.




Long, J. D. S.,  J. S. Remer, C. R. Wilson,  and P.  A. Witherspoon, Porous media




     equivalents for networks  of discontinuous fractures, Water Resources




     Res.,  18(3), 645-658, 1982.




Segol, G.  and  G. F. Pinder,  Transient simulation of saltwater intrusion in




     southeastern Florida, Water Resources Res., 12(1), 65-70, 1976.
                                     -341-

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            Monitoring, Troubleshooting and Repairing Wellbore
            Communication of Waterflood Injection Wells in the
                    Ville Platte Field - A Case History

                     Steven K. Whiteside, Conoco Inc.

SUMMARY
Three waterflood  projects  are currently  in  operation in  the  Ville Platte

Field, Evangeline Parish, Louisiana.  In mid-1986, casing pressure began to

develop on  each  of the three  injection  wells that  serve  these waterflood

projects.   This  paper  outlines the  history  of these  injection wells,  the

troubleshooting techniques employed in an attempt to identify the source of

casing pressure,  and  the workover  procedures which led to  the successful

elimination of wellbore communication.



INTRODUCTION



The three waterflood projects  that  are presently  in operation in the Ville

Platte Field  include  the Cook Mountain  "B"   Sand  (VP  CM B RA  SU  WF),  the

Basal Cockfield Sand (VP BSL CF RD SU WF) and the Middle Cockfield Sand (VP

MDL CF RA SU WF)  waterfloods.



The Cook Mountain  "B"  Sand  is a channel  sand  of  Middle  Eocene age located

at a  subsea depth  of  8,050'.  Initially, the  Cook  Mountain  "B" Sand was a

normally pressured reservoir  of  approximately  3,770 psig  (9.0  ppg  pore

pressure).   However,  by the time  the  waterflood  was initiated  in March

1985, the reservoir  pressure had declined  to approximately  870  psig (2.1

ppg).  Average reservoir  porosity  and  sidewall core  permeability are  30%

and 900  md.,  respectively.   The  approximate  reservoir  area is  180 acres

with  an average net effective pay of 12 feet.
                                   -342-


SKW1/011

-------
At the outset  of the waterflood project,  there  were three producing wells




which had a combined production  rate  of 120 BOPD.  Waterflood response has




been quite favorable in the Cook Mountain "B" Sand with the peak production




rate reaching 862 BOPD in September 1986.









The  Basal Cockfield Sand  is a  Middle Eocene age  sandstone  located  at  a




subsea  depth  of 7,900'.   The  initial reservoir  pressure  in the  Basal




Cockfield Sand was 3,720 psig (9.0 ppg).  Upon initiation of the waterflood




in April  1986,  the  reservoir pressure  had  declined  to approximately 2,900




psig (7.1 ppg).  The average reservoir porosity of the Basal Cockfield Sand




is  25.5% with  a  sidewall  core permeability  of  66  md.   The  estimated




drainage  area  of the reservoir is 210  acres with an average net effective




pay  of  five  feet.   There  are  currently  three  producing  wells   in  this




waterflood unit  with a combined  average production rate of  120  BOPD.   To




date, waterflood response has not yet been detected  in the Basal Cockfield




Sand.









The  Middle  Cockfield Sand  is  a  Middle  Eocene  age sandstone  located  at  a




subsea  depth of 7,730'.   The waterflood  encompasses  a  drainage  area  of




approximately 260 acres with an average net effective pay of six feet.  The




Middle   Cockfield   Sand  has  an  average  porosity   and   sidewall  core




permeability  of 25%  and  33 md.,  respectively.   The original  reservoir




pressure  was  approximately  3,620 psig  (9.0 ppg).  At  the beginning of the




waterflood project in April 1986,  the reservoir pressure was  approximately




2,520  psig  (6.3 ppg),  with  a  combined  production  rate  from   the  two




producing wells  of  72  BOPD.  In  recent weeks,  the  first  indications  of




waterflood  response  have  been  seen   in  the nearest offset producer, as








                                   -343-



SKW1/011

-------
evidenced by a significant increase in the producing fluid level as well as

a 20 BOPD increase in production.


There are  presently three  injection wells  that  serve  the  aforementioned

waterfloods.   The  Ludeau-Haas  No.   14  Well  is  completed  as  a  single

injection well in  the  Cook Mountain "B" Sand waterflood from perforations

at 8,147'-82' (see Figure 1).  This is the sole injection well for the Cook

Mountain "B" waterflood.  Since initiation of the waterflood in March 1985,

cumulative injection into the Cook Mountain "B" Sand has been approximately

985,000 barrels of water.


The August Attales No.  3 and the Opelousas St.  Landry Securities Co. No. 11

Wells are dually  completed  injection wells serving both the  Basal and the

Middle Cockfield Sand Waterfloods  (see Figures 2  and  3).  Since initiating

these floods in April  1986,  cumulative injection  into the Basal and Middle

Cockfield Sands has been approximately 65,000 and 102,000 barrels of water,

respectively.


In mid-1986,  casing pressure  began  to  develop on  each of  the waterflood

injection wells.   This  paper outlines the history of  the  injection wells,

describes the troubleshooting techniques  employed to identify the source of

the  casing  pressure,  and details  the  quality  control measures  utilized

during  workover  operations  which  led  to  the  successful elimination  of

casing pressure.
                                   -344-
SKW1/011

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LUDEAU-HAAS NO. 14 WELL



The Ludeau-Haas No. 14 Well was completed as a single injection well in the

Cook Mountain  "B"  Sand in March 1985 (see Figure  1).   During the first 15

months of the waterflood, injection rates averaged approximately  1,100 BWPD

with a  corresponding  average surface injection  pressure of  less than 500

psig (see Figure  4).   However,  in June 1986,  injection pressures began to

increase  significantly as a  result  of the  increases  in  injection rates.

During this time, injection reached a peak rate of 2050 BWPD with injection

pressures  in  excess  of  2,100  psig.    These  injection  increases  were

necessary in order to match withdrawal rates from the reservoir.



Corresponding  to the  sudden increase  in injection  rates  and pressures,

pressure  began to develop on  the  casing.  Initially,  the  casing pressure

built-up rather slowly, approximately 50-100 psig per day.  However, within

a matter of weeks, the casing pressure began to build up by more  than 1,000

psig per day.  During  this time, the casing pressure was being very closely

monitored and  bled off daily.   Conoco  immediately informed the Underground

Injection  Control Division  of  the  State Office of  Conservation  of  the

development  of  casing  pressure  and  requested  permission   to  continue

injection  while  attempting  to  identify   the  source  of  casing  pressure.

After review by the State to ensure that  there was no risk of contamination

to  fresh  water sands,  permission was granted  to  continue operation.  This

permission was granted provided that the  subject well was closely monitored

and efforts were made  to identify and repair the wellbore communication.
                                   -345-
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The  initial  investigation into  a possible  cause of  the  casing  pressure

indicated that the bypass valve on the existing compression-set retrievable

packer may  be opening,  as a result  of  the  increased injection  rates  and

pressures.  The bypass valve is  located  on  the  top  of  the packer  and  is

designed  to provide  a means of  circulating  fluid in  the  wellbore without

having to release  the  packer.   The packer is set by  rotating  and slacking

off weight on the tubing string.  Set down weight of approximately 8,000 to

10,000  Ibs.  is required to close the bypass  valve  and  set  the packer.

A  tubing  stress   analysis   indicated  that  under the existing  injection

conditions the tensile forces acting on the tubing string were great enough

to cause the bypass valve on the retrievable packer to open, thus providing

communication between the tubing and  the  casing  annulus.   In an attempt to

offset the tensile forces acting  on  the  tubing  string, an additional 6,000

Ibs. of  set  down  weight was applied  to  the packer.   Also,  in conjunction

with  this work the  tubing  hanger was pressure tested to  2,250 psig  to

ensure that no leaks were present  in  the  hanger.   Two days after restoring

injection into the Ludeau-Haas No.  14 Well,  casing pressure had built back

up to 1,025 psig.




At this  point,  it  was still suspected that  casing  pressure was associated

with the  bypass valve on the  retrievable packer.  On September  24, 1986,

workover  operations  were begun  to  pull  tubing  and  replace  the  existing

packer with a retrievable  packer more suitably  designed  for the injection

conditions.  Unlike its  predecessor,  the  new packer  did  not have to be set

in compression and was not  equipped with a  bypass valve.   Upon retrieving

the packer, a close  inspection of the bypass valve did not  show any signs

of wear or erosional effects to support our theory that  the  bypass  valve
                                   -346-
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had been prematurely opening downhole.   While  rerunning the tubing and the

new packer,  each  joint  of tubing was  internally  hydrotested to 3,000 psig

for  approximately 10  seconds.   No  tubing was  discarded  during  pressure

testing.  After setting the packer,  the  casing annulus was pressure tested

to  1,000 psig  for  10  minutes  with  no bleed  off.   Injection was  then

restored at  1,700 BWPD and 1,600 psig injection pressure.  Within two days,

1,140 psig of pressure had developed on the casing annulus.


During  the  first week  of October  1986,  the  Ludeau-Haas  No.   14 Well  was

shut-in  in  order to  conduct  extensive  pressure  testing to establish  the

source  of  the casing pressure.  This  work  involved setting a  plug  in  the

landing  nipple  located  immediately  above  the  retrievable  packer  and

pressuring up on the tubing to  approximately  3,000 psig  while monitoring

the  casing  pressure.  Testing  also included  pressuring  up on  the  casing

annulus while monitoring the tubing.


There  were   two  primary  reasons for conducting  this  testing.  First,  in

order  to  comply  with applicable State regulations,  every  effort was being

made  to identify the  source  of casing  pressure  so that  the  appropriate

steps  could  be  taken  to  effectively  eliminate  communication.   Secondly,

since   the   first   workover   proved   unsuccessful   in    repairing   the

communication, it was  critical that every attempt  be  made to  identify  the

source of casing pressure before initiating further costly wellwork.


However, after four  days  of testing no conclusive evidence was obtained to

substantiate the source of the casing pressure.  Thus, another workover was

necessary in order to identify and repair the wellbore communication.
                               -347-
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Workover


On  October  27,  1986  the  second  workover  operation  was  begun  on  the
Ludeau-Haas  No.  14 Well.   During  this  workover, the  following work  was
performed:


     1.   The  tubing  and  retrievable  packer  were pulled  from the  well.
          Each joint of tubing was laid down on pipe  racks.


     2.   While the tubing  was on the pipe  racks, the threads  on  the  pin
          and  box  ends were  cleaned  and visually inspected for signs  of
          wear or  galling.   Thread  protectors were then placed  on  the  pin
          ends.   Each  joint  of  tubing  was  inspected  for  any  obvious
          corrosion or defects.


     3.   The  retrievable packer  was  inspected and redressed  before  being
          rerun in the well.


     4.   The tubing was rerun into well in the following manner:


          a.   Each joint  of  tubing  was made  up to  the API  recommended
               optimum make-up  torque  for 2-3/8", 4.7#/ft., J-55,  EUE  8rd
               tubing of 1,290 ft.-lbs.


          b.   Each connection was internally pressure tested with helium
               gas to 5,000 psig for 30 seconds.
                                  -348-
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          c.   Each joint  of tubing  was  internally  hydrotested  to  5,000




               psig for 15 seconds.









     5.   The wellhead and  Christmas  tree were gas tested  with helium and




          hydrotested to 5,000 psig.









In  performing this  work,   every  effort  was  made  to implement  effective




quality control measures in order to ensure that the wellbore communication




was identified and  repaired.   The following quality  control measures were




taken while rerunning the tubing.









Tubing Make-Up









In  making  up each  joint  of tubing,  a  torque  gauge  was installed on the




hydraulic  power  tongs to  ensure that  the tubing was made-up to  the API




recommended  optimum make-up torque  for  2-3/8",  4.7#/ft.,  J-55  tubing  of




1,290  ft.-lbs.   Special  attention was given to orienting  the load cell at




right angles  to  the lever arm on  the  power tongs  and  horizontal to the rig




floor.  Otherwise, significant error in the torque gauge reading can result




from  improper orientation of the load  cell.   Each connection was made-up




with  the power  tongs  operated in low gear.   Experience  has indicated that




it  is physically   impossible   to   maintain   control  of  the  tongs and




achieve the  optimum make-up torque of  the tubing while operating in high




gear.  While the  tubing was  being  made-up,  the  pin  and  coupling were




visually inspected to make sure that the  last round of threads  on the pin
                                   -349-



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shouldered up to the coupling.  If several rounds of threads remain exposed




after optimum make-up torque is achieved, this indicates the possibility of




crossthreading.  Conversely,  if the  optimum  make-up torque is not achieved




by the time  that  the  threads are  completely buried, this  is  an indication




of a pin or coupling that is out of tolerance or the threads are stripped.









Gas Testing









The fundamental operation of a helium gas test involves placing an internal




test tool  across  from the coupling  area of  the tubing  connection.   After




packing off  above  and  below the coupling with  the  test  tool, the coupling




area  is   filled with  a  helium  test-gas mixture   to  a  prescribed  test




pressure.  Once the test  pressure  has  stabilized,  a gas containment sleeve




is placed around the exterior  of  the coupling where helium will accumulate




if a leak exists  in the  coupling.   After a designated accumulation time, a




probe is inserted into a  sampling  port  on the containment  sleeve to detect




the  presence  of  helium.   The  helium  concentration  is  determined  by




utilizing a portable thermal conductivity meter, which compares the thermal




conductive properties  of  the atmosphere with those  of  the sleeve gas (see




Figure 5).









Several quality control  measures  were  taken  to  ensure accurate  gas test




results.   Before  testing began, the helium  concentration of  the  test gas




was  checked  to  confirm  that  sufficient  levels   existed that  could  be




detected by the thermal  conductivity meter.   During testing,  the meter was




recalibrated  regularly in order  to  make sure  that the meter  was reading




accurately.   This  calibration  simply   involved  "sniffing"  a  helium test




bottle with the meter probe to check the response of the meter.  After each



                                   -350-





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joint of  tubing  was  made up, excess pipe  dope  would accumulate around the

coupling.  Since this pipe dope could mask a  small leak,  each coupling was

wiped clean  with a  rag  before placing  the containment  sleeve  around the

coupling.


Hydrotesting


Internal   hydrotesting   involved   simultaneously   pressure   testing   the

connection, which had previously been tested with gas, and the tubing body.

This  testing  was  performed  above  the  rotary  table so  that  a  visual

inspection of the joint of tubing could be made during testing to check for

any signs of leakage.


In addition  to the quality  control  measures described above,  several other

steps were taken to  ensure accurate test  results.   Company personnel were

located  on  the  rig  floor  and the  pump  truck to  make  sure  that  strict

quality  control  measures  were constantly adhered  to  during testing.   All

pressure  testing was conducted with the  tubing  string  hung   in   tension

above the  rotary table,  in order to simulate the  downhole  tensile  loading

conditions that  would exist  on  the  tubing.  Finally, the  gas coupling test

was conducted  before the hydrotest.  If the  hydrotest is performed first,

water can  enter  into a potential helical  leak  path in the  tubing threads,

resulting in masking a leak which would otherwise be detectable with gas.
                                   -351-
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Workover Results


When the tubing was pulled from the Ludeau-Haas No. 14 Well, it was obvious

that  some  of  the  tubing had  not previously  been made-up  adequately,  as

evidenced by  the  fact that several  rounds  of threads were  exposed  on the

pin ends.  While  cleaning and inspecting the tubing on the pipe  racks,  a

total  of nine joints  were  discarded  due  to  obviously   galled  or  worn

threads.  In  two instances, a  majority  of  the threads were worn completely

smooth, indicating that severe crossthreading had occurred during make-up.


While rerunning the  tubing  into  the subject  well,  seven  couplings and one

landing nipple  failed either  the gas test  or the hydrotest and had  to  be

replaced.  Also, one  collar became distorted as a  result  of making  up the

connection and consequently was discarded.


After running  the tubing  into  the well  and  setting the retrievable packer,

the casing annulus was  pressure  tested  to  1,000 psig  for  one  hour with  no

bleed-off occurring.   On October 31, 1986,  injection was  restored  to the

Ludeau-Haas  No.  14  Well  at  a  rate  of approximately 2,000 BWPD with a

corresponding  injection  pressure  of   2,100   psig.    To   date,  no  casing

pressure has developed on the subject well.


Overall,  the  workover   operations  went   as  planned  and  the  wellbore

communication was successfully eliminated.   One drawback to this testing is

the considerable running  time  associated with performing  a combination gas

and water pressure test.  The average running time was approximately 10 to
                                   -352-
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11  joints  per  hour;  which  includes  the  downtime  associated  with  tool

failures and mechanical problems.  Generally speaking, this author does not

advocate gas  testing for  this  type of  application,  considering  that  the

subject well  is a waterflood injection well  operating at  relatively  low

pressures.   However,  due  to  the  importance  of minimizing the downtime  of

this well  and the previous workover  attempt which proved unsuccessful  in

identifying the  wellbore   communication,  the additional precautions  taken

were  economically justifiable.   Nonetheless,  if  more  stringent  quality

control measures  had been implemented during  the initial workover on  the

Ludeau-Haas No 14 Well, a second costly workover would most likely not have

been required.


AUGUST ATTALES NO. 3 WELL


The August Attales No.  3  Well was completed  as a dual waterflood injection

well in the Basal and Middle  Cockfield Sands  in  April 1986  (see  Figure  2).

Due to the low permeability and the high reservoir pressure of these sands,

the  initial  injection  rates  were relatively  low  (100  to  200  BWPD)  with

correspondingly high injection pressures (in excess of 2,000  psig).


Immediately following the  completion  of  the  August Attales  No.  3  Well,

pressure began  to develop on the casing.   Initially, the casing pressure

built  up  very  gradually  (approximately  100-300  psig  per  day)  which

suggested  that  any  leak(s)  were  small.   However, within  two  months  the

casing pressure was  building  up by as much  as 1,200 psig in  one day.   In

an   attempt   to   identify   the   source  of   casing   pressure,   several

trouble-shooting techniques were employed.
                                   -353-
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Troubleshooting


The first method utilized in an attempt to identify the cause of the casing

communication simply involved  shutting  in one side of  the  dual completion

while maintaining injection into the other.   Prior  to  doing so, the casing

annulus pressure was bled off to 0  psig.   During injection  into  only one

string  of  tubing,  the  casing  pressure  was closely  monitored  for  any

build-up.  This method proved unsuccessful in conclusively establishing the

source of casing pressure.  Regardless  of  which  string  of tubing was being

injected into, casing pressure would develop.


There  were  two primary  factors  which  contributed  to  the  inconclusive

results.  First, thermodynamic effects were  present due to  the injectivity

of a relatively cool fluid  into  the  wellbore.   Significant  fluctuations in

the casing pressure were apparent when changes in the  injection rates would

occur. By injecting the cool  saltwater  down  the  tubing, the temperature of

the wellbore would begin  to decrease resulting  in a corresponding decrease

in the casing pressure.  Conversely, as the injection  rates were reduced or

the well was shut-in, the wellbore would begin to warm up, causing pressure

to  increase.    Due  to  the  thermodynamic  effects,  it  was  impossible  to

establish how much of  the  casing  pressure was  actually  attributable  to

wellbore communication.


A second factor which contributed to the  inconclusive  test  results was the

slow bleed-off  of  the  tubing pressure  after one  of  the  completions was

shut-in.  Due  to  the  low reservoir permeability,  it  took  a considerable

length of time for  the pressure to dissipate in the reservoir and the
                                   -354-
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tubing pressure to bleed to zero.  Therefore, until the tubing pressure had




bled  off  entirely,  it  was  impossible  to  determine  which  completion




accounted for  the  increase in casing pressure.   Since  the duration of the




tests were  relatively  short, the wellbore never  had time  to  stabilize in




order to establish the source of casing pressure.









The  second  method employed  to  identify the  cause  of  the  casing pressure




involved setting  plugs in the  landing  nipples in the  shortstring and the




longstring at approximately 7,712' and 7,944' respectively.  Once the plugs




were  set, the  entire wellbore was bled off  to zero.   Then, each string of




tubing and  the casing  was  individually  pressure  tested while the remainder




of  the wellbore  was  closely monitored  for any  pressure  build-up.   The




primary advantage  of this  method  over  the  previously described alternative




was  the ability to isolate the  wellbore from the reservoir pressure.  This




provided more  flexibility  in testing in addition to  having the  ability to




quickly reach a stabilized wellbore condition.  The results of this testing




clearly established that  the longstring was  the  source of casing pressure




(see  Figure 6).









After  identifying  the  longstring  as  the  source  of  casing  pressure,




additional testing was conducted in order to determine  if the tubing hanger




was  leaking.   If  the  hanger was the  cause of  the casing pressure,  the




communication could be repaired without requiring a costly workover.









A tubing bridge plug was set  on a collar  stop one joint below the surface.




Once  the  plug  was set,   red  dye was  poured into   the  longstring before




pressure testing began.  Only subtle changes  in the casing  pressure were







                                  -355-




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apparent during  the  previous testing,  indicating  that a  relatively small




leak existed. Therefore,  it  was decided that the  only way to conclusively




establish if the  tubing  hanger  was leaking was to  actually detect colored




dye returns on the casing during testing.









Initially,  the  longstring was  pressured  up  to 3,000 psig.  Within  four




minutes, the longstring had bled down to approximately 1,000 psig while the




casing pressure  remained  unchanged.   At this point,  it was suspected  that




the bridge plug was not holding.  Testing then began on the shortstring.




After  pressuring up  to  approximately  3,000  psig,  the   pressure  on  the




shortstring  held  steady  while  pressure   on  the  casing  increased  only




slightly.  The increase in casing pressure was caused by ballooning effects




of the tubing.   After the  wellbore remained stable for several minutes the




casing and  tubing pressure was bled  off.   While  bleeding  off  the casing,




red  dye  was recovered  from  the  annulus,  indicating that  a leak  in  the




hanger did exist.  Further testing confirmed that  a leak was present in the




tubing  hanger.   The most  likely  explanation  for  not detecting  the  leak




initially with  the  pressure gauges  is that  the   casing  annulus was  not




completely full of fluid when testing began.









Subsequently, a  workover  rig was  brought in to  repair  the leak  in  the




tubing hanger.   After nippling  down the Christmas  tree and picking up the




longstring tubing and the  dual  split  hanger,  the  tubing threads that screw




into the  bottom  of  the  tubing  hanger  were hydrotested again in  order to




visually witness the leakage  (see  Figure 7).  It was  obvious that the  leak




in the  hanger was  caused by inadequate  make-up  of  the  tubing  into  the




bottom of the hanger, thus creating a helical leak path in the threads.








                                   -356-



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The leak  was  then repaired  by  taping the  tubing threads with  teflon and

completely  making up  the  tubing into  the  hanger.   Additional  pressure

testing confirmed that the tubing hanger leak had been eliminated.



Three days after restoring injection into both completions, casing pressure

again developed.  At this point,  the  longstring  was  shut-in and the casing

pressure  ceased.  For nearly three months,  injection  was maintained in the

shortstring, with no sign of casing pressure developing.



Working over the subject well had intentionally been delayed until wellbore

communication was eliminated on the  Ludeau-Haas No.  14  single completion.

By  delaying   this   work,  valuable   experience  could   be   gained  from

successfully repairing communication  in  the No.   14 Well before initiating

workover  efforts on the dual completion.



Workover



In November  1986, workover  operations began on  the  August Attales  No.  3

Well  in  order  to  repair  the   longstring-to-casing  communication.   The

workover  procedure that was  carried out  on  the  longstring was identical to

the procedure previously  implemented  on  the Ludeau-Haas  No.  14.  However,

cleaning  and  visually inspecting  the threads as  well as gas  testing was

excluded  for  the shortstring  since  it  was  not the  cause  of  the casing

pressure.
                                   -357-
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After cleaning  and  visually inspecting the  longstring on the  pipe  racks,

two  joints  of  tubing  were  discarded;  one  due to  a slight  scar on  the

threads  and   the  other  because the  tubing  body was partially  crimped.

Although these joints were thrown out as a precautionary measure, they were

not suspected to be the cause of the communication.



It was  obvious  when the  longstring  was pulled out  of the well,  that  the

entire  tubing  string  had  been inadequately  made-up  during   the  initial

completion.   Three  or  four  rounds  of  threads  were  exposed  on  each

connection.  It was  immediately  suspected  that  a  helical  leak  path existed

in  the  8  round  connections,  thus  causing  communication  between  the

longstring and the casing.



While  rerunning the  longstring,  effective  quality  control measures  were

taken  to  ensure  that  the  optimum make-up torque  was   applied  to  each

connection  and  that  proper  testing  procedures  were  followed.    During

pressure  testing,  not  a single  joint  of  tubing failed  to  test.   Since

performing  this workover,  the  August  Attales No.  3 Well has  been  on

injection for nearly five months at  injection  pressures  in excess  of 2,000

psig, with no sign of casing pressure.
                                   -358-
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OPELOUSAS ST. LANDRY SECURITIES CO. NO. 11 WELL


The  Opelousas  St.  Landry  Securities  Co.  No.  11  Well,  like  the  August
Attales No.  3,  is  completed  as a  dual waterflood  injection well  in the
Basal and Middle Cockfield  Sands  (see  Figure  3).   Shortly after completing
the subject well in April 1986, pressure began to develop on the casing.


Of the three  injection  wells  discussed within this  paper,  the development
of  casing  pressure was  least  pronounced  in  the  Opelousas   St.  Landry
Securities  Co.  No.  11.   Despite  realizing surface  injection  pressures in
excess of 2,000 psig into both completions, the casing pressure never built
up by more  than  200 psig per  day,  indicating  that  only  a very  minute
leak(s) existed in this wellbore.  Extensive pressure testing utilizing the
various troubleshooting  techniques  described previously, was  conducted on
the No. 11 Well.


While preparing to  pressure test the  tubing head, water was discovered in
the test port indicating that a leak existed  in  the  wellhead or the tubing
hanger (see Figure  7).  To  seal  off the leak,  plastic packing was injected
into  the  tubing  head test  port.  Afterward,  the tubing  head  was pressure
tested to 5,000 psig for one hour with no bleed off.   Since performing this
work,  casing  communication  has  been eliminated.   Presently,  injection
pressures  into  both  completions are  greater  than  2,200  psig, with the
casing pressure remaining constant at approximately 200 psig.
                                   -359-
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CONCLUSIONS


Several  valuable  lessons  have  been  learned  as  a  result  of  the  work

performed  on these  injection wells.   First,  by  closely  monitoring  and

troubleshooting  a   problem  well,  in   many  instances   the  source  of

communication  can   be   identified  without  requiring   costly   workover

operations.   Secondly,  implementing  effective   quality   control  measures
during  remedial  work  can  ensure  that  tubing  leaks  are  successfully
identified and repaired.  Thirdly, exercising rigorous completion practices
initially  will  help  ensure  the  mechanical  integrity  of  the  completion
configuration and minimize costly workover operations.


Also,  timely  and   thorough  communication  with  the   State  Office  of

Conservation provided  them  with an  understanding  of the testing objectives
and  an assurance  that fresh water  sands  were not  being  endangered during
this lengthy program.


ACKNOWLEDGEMENTS


I  thank  Conoco  Inc.  for  permission to publish  the material  presented in
this paper.  Thanks are also due Mark McClelland and Chuck Spisak for their
critical review of the manuscript and  Ty  Maxey for his field assistance in

making this work a success.
                                   -360-
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              Figure 1: Ludeau Haas No. 14 Wellbore Schematic
                 LUDEAU HAAS #14 WELL
16* DRIVE PIPE SET__v-J
AT 93'
10 3/4* CASING SET 	 ^
AT 1818'
8.7 PPG FSW IN ANNULUS

RETRIEVABLE PACKER /
AT 8,072'
5 1/2" CASING SET AT 	 v-
//

X^





-— -J


X
X


$&£:0:£&i£CJj'ti$fi

II
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-------
                Figure 2: August Attales No. 3 Wellbore Schematic
                  AUGUST ATTALES  ^3 WELL
16"  DRIVE PIPE AT
10-3/4" CASING SET AT
1822'
8.8 PPG IN ANNULUS
2-3/8", 4.7*/FT.,N-80,
EUE, 8RD. TUBING
W/BEVELED COLLARS.
7-5/8" DUAL PACKER SET
AT 7,744'
LANDING NIPPLE AT 7,944'
7-5/8" PERMANENT —
PACKER SET AT 7,977'
7-5"/8" CASING SET AT
8494'
X
      I
       ~>
                                X
X
                                           I
                     VILLE PLATTE FIELD
                     EVANGELINE PARISH, LA.
                                             LANDING NIPPLE AT 7,712'
                                             LANDING NIPPLE AT 7,759'
                                              MIDDLE COCKFIELD SD.
                                          :    PERFS. AT 7,868'-950'
                                              BASAL COCKFIELD SAND

                                              PERFS. AT 8,036'-64'

                                              FLOAT COLLAR AT 8,405'
  T.D. = 8,500'
       -362-

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        Figure 3: Opelousas St. Landry Securities Co., No. 11 Wellbore Schematic
OPELOUSAS  ST. LANDRY SEC. CO.
                                                     WELL
 16' DRIVE PIPE AT
 130'
10-3/4* CASING SET
AT 1804*
 8.7 PPG FSW IN ANNULUS
7-5/8" DUAL PACKER AT
7708'
LANDING NIPPLE AT 7,9271

7-5/8" PERMANENT -
PACKER AT 7960'
FLOAT COLLAR AT 8403'
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LVILLE PLATTE FIELD
EVANGELINE PARISH, L
	 2-3/8", 4.7*/FT, N-80,
EUE, 8RD TUBING
W/BEVELED COLLARS.
LANDINft NIPDI P AT 7 R7*



LANDING NIPPLE AT 7 72%

x MIDDLE COCKFIELD SO.
== PERFS. AT 7,840'-928'



BASAL COCKFIELD SD.
'==^ PERFS AT 8 O18'-50*




                    T.D. = 8,500'
                       -363-

-------
        i'lgure 4:  Ludeau-Haas No. 14 Water Injection History
           LUDERU  HflflS  «   14  NELL
                INJECTION RflTE  VS. TIME
  10'
CD
d.
CO
  10' l-f
                                            WflTER INJ
                  L.
      JFMflMJJflSONDJFMRMJJFlSONpJFMRMJ
              1985                 1986            1987
  3500





  3000





 • 2500



CS


JC 2000


LJ



f, '50Q
LJ
Qi
Q_


 ; 1000





  500
               LUDERU  HRRS
             INJ.  TUBING PRESSURE VS.  TIME
                                            WflTER INJ
                                        n
               r
               J  i
                                _J
      JFnflMJJflSONDJFMnMJJnSONDJFnflMJ
              1985                1986            1987
                          -364-

-------
                       Figure 5:
   INTERNAL  GAS TESTING CONFIGURATION
 WIRELINE
PACKER
PACKER
                PRESSURE SUPPLY LINE
                  ANNULAR
                  PRESSURE
                                            N2/He SUPPLY
              PRESSURE
              GAUGE
                       TEST PROBE
                    COUPLING
                    TEST AREAS
GAS
CONTAINMENT
SLEEVE
                  INTERNAL
                  TEST TOOL
             THERMAL CONDUCTIVITY
                    METER
                         -365-

-------
                                           FIGURE 6:
                              AUGUST  ATTALES NO.  3
                        WELLBORE PRESSURE  TESTING RESULTS
                    L.S.
                    CSG.
20
40   60   80   100
TIME, MINUTES
    a)
                     3000

                     2500

                     2000--
                           100--
                             0
                                                       S-S-   1000--
                                                       CSG.
                                                       L.S.
20   40   60   80  100
     TIME, MINUTES
                                               b)
                                                              950-
                                                         300-
                                                              200-
                                                              100
20   40   60   80   100  120
     TIME, MINUTES
            C)
            a)  PRESSURE TESTING THE LONGSTRING
            b)  PRESSURE TESTING THE SHORTSTRING
            c)  PRESSURE TESTING  THE CASING

-------
                       Figure 7:
              DUAL SPLIT TUBING HANGER
TUBING HEAD
TEST PORT
                                      TUBING HANGER
                                        THREADS
                        -367-

-------
                   SOME ASPECTS OF MONITORING A WATERFLOOD
                       VENTURA AVENUE FIELD WATERFLOODS
                              R. A. Deans and E. Jean Hill


                  Texaco USA, P.O. Box 811, Ventura, California 93002
                                ACKNOWLEDGMENTS

     The authors wish to thank the management of Texaco USA for permission to publish this

paper.  Special thanks are also extended to Ms. M. O. Sorensen and the local drafting personnel

for their assistance in the preparation of  this manuscript.  The authors are indebted to  those

many engineers who have spent countless hours analyzing the  information and formulating the

recommendation which have led to the current  operating strategy for Texaco's Ventura Avenue

Field Waterfloods.
                                       -368-

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                                 TABLE OF CONTENTS


                                                                        Page No.

      List of Tables 	.	    iii
      List of Figures	    iv

I.     INTRODUCTION	     1

II.    WATERFLOOD REVIEW	     2

      A.   Reservoir Description 	     2
      B.   Historical Background	     3
III.    INJECTION WATER QUALITY
      A.   Mechanical Treatment	     5
      B.   Chemical Treatment	     7
IV.    MONITORING TECHNIQUES
      A.   Injection Well Surveys	    9
      B.   Spinne r Surveys	    9
      C.   Temperature Surveys	    10
      D.   Waterflood Tracer Surveys	    10

V.    CONTROLLING INJECTION WATER	    12

      A.   Mechanical Methods	    12
      B.   Chemical Methods  	    14

VI.    SUMMARY	    16

VII.   APPENDIX	    18

VIII.  REFERENCES	    19
                                        -369-

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                              LIST OF TABLES



Table No.                                     Title
    1          Fluid and Rock Properties (C-Block Average), Ventura Avenue Field




    2          Optimum Requirements - Injection Water, C-Block Unit Waterflood




    3          Staged Acid Program




    <4          Gross Pore Volume Injection, Phases 1-10, C-Block Unit Waterflood




    5          Water Entry Surveys, Producing Wells, C-Block Unit Waterflood
                                   -370-

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                                   LIST OF FIGURES




FiRure No.     	Title
     1           Areal Conformance




     2           Vertical Performance Saturation Fronts




     3           Field Location Map




     4           Ventura Avenue Field North-South Cross Section




     5           Type Electric Log  Ventura Avenue Field (Lloyd No. 244)




     6           Ventura Avenue Field - C-Block and D-Block Unit Boundaries




     7           C-Block Unit Waterflood




     8           Project Production History; Phases 1-1 n, C-Block Unit Waterflood (1961-1984)




     9           Ventura Avenue Field, VL&W East D-6, 7U Waterflood, D-Block Unit




     10          Ventura Avenue Field; D-Block Unit Waterflood Status




     11          Ventura Avenue Field; Performance of D-Block Waterfloods




     12          Ventura Avenue Water Cleaning System




     13          Typical Radioactive  Tracer Detector Tool Configuration




     14          Lloyd //234 Injection Profile Surveys




     15          Spinner Survey Tool  Configuration




     16          Typical Temperature Survey Response, C-Block Unit Waterflood, Well Lloyd




     17          External Casing Packer Schematic




     18          Injection Well Flow Regulation Assembly




     19          Conceptualized  Polymer Treatment




     20          C-Block Unit Polymer Treatment Results - Treated Sands




     21          C-Block Unit Polymer Treatment Results - Untreated Sands




     22          Gross Pore Volume Injection, C-Block Unit Waterflood, Phases 1-10




     23          Water Entry  Surveys, Producing Wells, C-Block Unit Waterflood




     24          Injection Profile Status C-Block Unit Waterflood




     25          C-Block Unit Oil Production
                                        -371-

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                   SOME ASPECTS OF MONITORING A WATERFLOOD




                       VENTURA AVENUE FIELD WATERFLOODS
                              R. A. Deans and E. Jean Hill








                   Texaco USA, P.O. Box 811, Ventura, California 93002








                                      ABSTRACT




     Effective  waterflooding relies, in part,  on the efficient use of the injected water to



displace movable  oil toward  a  producing well.  Because  of  this requirement, steps  must be



taken to direct water to the  zones containing the oil reserves and data must be  obtained to



reflect the  true path of the water.  Every barrel of water that does not go where it is  intended



reduces the recovery and, consequently, negatively impacts the economics of the operation



     Texaco operates two waterflood units in the Ventura Avenue Field. This field is massive



and, to waterflood it properly,  careful attention to the quality and placement of the  injected




water is required.  Many techniques are used to help direct the water to the desired location.



They include mechanical means (external casing packers, cement, mechanical flow regulation,




selective  perforations)  and chemical  means (acid  treatments and crosslinked polymer).  In



addition,  downhole  data are  collected  (from  temperature,  injection  profile  surveys and




chemical waterflood  tracers) to identify the water path.



     Through these efforts, the integrity  of  the waterflood is maintained, the  condition  of the




injection  wells is understood and the injected water is used effectively.
                                        -372-

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                                    I. INTRODUCTION



     As administered by the Division of Oil and Gas, the State of California laws governing the




conservation of oil and gas deposits include two fundamental goals:




           (1)   the protection of fresh water supplies, and



           (2)   the conservation of oil and natural gas resources.



     Texaco USA and the Division of Oil and  Gas have a mutual interest in accomplishing these



goals.  Texaco (and its predecessor companies), by implementing specific engineering concepts,



has increased waterflood reserves in  the Ventura Avenue Field and has simultaneously  reduced



operating costs  without impugning the integrity of the environment.   This  presentation will



discuss Texaco's experience  in monitoring Ventura Avenue  Field waterflood  projects utilizing



operations designed specifically  to  not only  comply  with  state  regulations,  but to do  so



consistent with good oil field practice.



     Waterflooding  operations  have been "without  question  responsible for  the current  high



level of producing  rate  and reserves with the  U.S. (sic) and  Canada." 1  Using  the concepts



forwarded by individuals like F. F. Craig, Jr.l, proper engineering of any waterflood requires an



ever increasing understanding of the  nature of  the reservoir involved and how it reacts to the



injection of water.  Improper placement of  the  water, known or unknown, results in, at  best, an



inefficient flood and, at worst, unwanted damage.



     Unbalanced areal coverage will  not provide the displacement of available oil toward a



producing well.   As depicted in  Figure 1 the circles on the right and  their size represent  an




idealized, proportional volume of injected water.  To the left, the oil between the ineffective



injection  wells and the producers  will eventually  be  moved away by the  disproportionate



injection.   The  injection  of  uniform volumes in each  well would  prohibit such  adverse




consequences.  An equally important but less frequently considered view of inequitable water



injection  is depicted in  Figure  2.   The oil that,  in fact,  should be produced can actually  be



moved away  resulting in a corresponding loss of reserves, if equal injection into each zone is not
                                          -373-

-------
present.



     Efforts in the C-Block and  D-Block Unit Waterfloods of the Ventura Avenue  Field  have




been designed to address these important issues through thoughtful study and careful operation.




The success is verified by the results.



                                II.  WATERFLOOD REVIEW




A.   Reservoir Description



     The  Ventura Avenue Field is on the Ventura Anticline in the northwestern onshore area of




the  Ventura Basin,  about two  miles  north of  the  city  of San Buenaventura  ("Ventura")




California (Figure 3).  In this field, the  Pliocene Age Sands of the Pico Formation are composed




of the  Upper Pico and Lower Repetto  members and consist of a  sequence  of  sands, silts and



shales  more  than  10,000 feet thick.  The Ventura Anticline, a major structural feature of the



Ventura Basin, is  tightly folded and oriented in a generally east-west direction. It is  broken into



major  areas  by two  large longitudinal  thrust faults known as the "Taylor"  and the "Barnard".



These  faults divide the Ventura  Avenue Field into  two major oil producing sections,  the "C-




Block" and the  "D-Block".  The C-Block section is that portion of the field which lies  between



these two faults and  the D-Block  section is located below the Barnard Fault (Figure 4).



     Typically, these major producing blocks have been divided into many sand sequences which



are interrupted by shale laminations. The C-Block,  for example, consists of twelve  major sand



bodies, some of which are two hundred  feet thick (Figure 5).  The producing Blocks, then,  are a



very complex series of reservoirs to which  general waterflood  principles must be  judiciously



applied.   Monitoring  procedures  which  are useful for less  complex operations are  not always



applicable  for the Ventura  Avenue  Field because of  its large gross sand interval, the  large




number of sands and the permeability  variations.  Table  1  is compendium of fluid and rock



properties  for  the  Ventura Avenue Field,  representative  of  the  C-Block.   The  general



orientation of the "C"- and "D-Block" waterflood units  is shown on Figure 6.
                                         -374-

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B.   Historical Background




     The first commercial oil production in the Ventura Avenue Field was established in 1916




by the State Consolidated Oil Company with the completion of  their well,  Lloyd #2, which




produced  100 barrels per day of 50° gravity  oil from a light oil zone at a depth  of approximately




2,500 feet.  By 1921, Associated  Oil Company had acquired  State  Consolidated and in January




(1921) completed the first C-Block producer (129 barrels of oil per day, 3,778  feet total depth).




The following year, Lloyd //5 was completed at 1900 barrels of oil per day from a depth of 4,051




feet.  C-Block total production peaked in 1929 at 30,000 barrels of oil per day.




     By 1956,  the C-Block producing  rate  had declined to  4,900 barrels of oil per day and a




waterflood feasibility  study  was begun.  Completed in 1958, this study  defined a waterflood




development plan and  recommended  a waterflood pilot to test injectivity and waterflood




response of the C-Block  sands.  The first  water  injectivity  test was initiated in August 1961




with the "Lloyd Lease (C-Block) Pilot Waterflood", consisting of one producer-conversion to salt




water injection, one producer-redrill completed as an injection well and five observation wells.




Two years later, neither injection well had attained planned injection rates (965 and 770 barrels




of water  per day) nor had waterflood response been noted in any observation well.  A second




pilot waterflood  (East VL&W) was commenced in  1964 and the Lloyd  Waterflood Pilot was




subsequently discontinued (September 1964).




     Although performance of the second pilot was poor, the  final waterflood development plan




was designed in 1967 and unitization agreements were  signed in 1968 (final unitization July 1,




1970).   The C-Block Unit Waterflood was divided from east to west into ten "Phases" denoting




individual sections of a staggered line-drive flood  pattern  (Figure 7) which included the C-2, 3




and 4 Sands from the "S"  Sand marker to the "AT"  Sand marker (shown earlier on Figure 5).  By




January 1972, Phases 1 through 8 had been developed.  [Development of  Phases  9 and 10 was




hampered by the lack of  an operator's agreement with   Shell Oil Company, the offset operator




to the  west of  the  C-Block Unit.   Although negotiations were  vigorously  pursued,  final
                                          -375-

-------
agreements  were not signed until  August 1979  which finally enabled  Phases 9 and  10  to be



expanded to full-scale injection and the C-Block Unit to become fully developed.




     Figure 8 is a composite graph of waterflood production histories for all  ten C-Block Unit




Waterflood  Phases.   To date, Phase  8 has provided the  highest  waterflood response  while



reflecting a relatively shallow decline.  Phases 9 and 10 have been slow to respond because of




injection delays in that particular area, but  are  currently responding well.  Phases 1, 2 and  3




responded only slightly to the C-Block Unit Waterflood  because of  water influx and reservoir



heterogeneity prevalent in those areas. These phases also recorded particularly severe declines



following peak response.  Phase 5 responded well initially,  but production declined rapidly as  a




result of early water breakthrough.  Ultimate waterflood recoveries, when adjusted to an  acre-



foot basis,  also  indicate  superior  Phase 8 performance.   Phases  4,  5,  6,  and 7  ultimate




waterflood recoveries are substantially less and recoveries from Phases 1, 2 and 3 are  very



poor.




     Tidewater Oil Company began development of the Ventura Avenue Field "D-Block" Zones




in April 1931 with the completion of Lloyd #57.  At  that time, this well's total depth of  8,823



feet made it the world's deepest producing oil well.  There  were many technological limitations



associated  with drilling at  these  depths and development of the D-Block was, by necessity,



rather slow.  However, by 1938, technology had  advanced sufficiently to support additional




drilling and, while oil production peaked in  1949 at 23,600 barrels/day, active development of




the D-Block Sands actually continued through the early 1960's.



     A D-Block waterflood plan was designed in 1970 and unitization was finalized in October



1978.  Following a successful water injectivity  test in 1979, the first D-Block Unit Waterflood



was  initiated  in January 1980 ("VL&W East D-6,7 Upper").   Figure 9  indicates  the original



pattern and location  of  this waterflood relative to the  D-Block Unit.  Fourteen months  later,



this  waterflood  was expanded.   (Initially, an inferred fault  was expected to form the  west



boundary.   By  February 1981, it  was  apparent  that  the inferred fault either did not exhibit
                                          -376-

-------
enough  displacement to seal against injection or that the injection water traveled around the




fault.) Because of the numerous fault blocks and the massive zone thickness associated with the



D-Block, many floods will be required to properly develop this unit's  waterflood  potential.  A




total of fourteen waterfloods have been d signed for initiation by the year 2008 (Figure 10).



      Oil production in the waterflood area was averaging approximately 300 barrels/day when



full-scale water injection was initiated and,  as  shown  on Figure  11,  performance  of this




waterflood has been excellent.



                            HI. INJECTION WATER QUALITY



      Waterflooding porous media requires excellent water quality to aid in effective secondary



recovery.   In the  C-Block Unit  Waterflood  alone,  poor  water  quality  could  account  for




reductions in  the proved reserves approaching 9.6  million barrels of oil.  Because the sands in



the  D-Block  waterfloods generally  have lower permeability,  the  impact on  them could be



equally  dramatic.   Potential  losses of reserves of this  magnitude  provide  the basis  for  the



extensive water  treating efforts in both waterfiooding projects and economically substantiate



the capital  expenditures and assigned manpower required to maintain and improve the water



quality.



      "Excellent" water quality is often a relative  term which  may constitute a wide  range of



water standards. Frequently, a level of five to  fifteen ppm total suspended solids  is considered



as "excellent" quality.  However,  experts in oilfield  water systems have  established certain



criteria as listed in Table 2  which quantify more restrictive  standards for high quality injection



water.  Mechanical and chemical means, the effects of each on the  other cannot be separated,



are used to achieve the desired quality.



A.    Mechanical Treatment



      Because the surface locations of the C-Block and the D-Block Unit Waterfloods physically



overlap, processing the water for  injection  is performed  as  one  major "facility" and  then




apportioned to each waterflood.   A simplified schematic representation of the  processing is
                                          -377-

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shown in Figure 12.  Approximately 95,000 barrels of water are  processed  in the facilities for



injection each day.   Water produced with and  then  separated from the oil amounts  to  about




70,000 barrels,  10,000  barrels come  from saltwater source  wells, and the remaining 15,000




barrels come from a nearby freshwater lake.




     The water produced along with the oil is  first separated  and then  transferred to four



vessels  ("WEMCOS")  for  removal of  solids  and  oil  remaining in the  water after the initial



separation.  Unfortunately, the efficiency of the "WEMCOS" does not meet our rigid standards



and further processing is necessary.  Water  from several source  wells is added  to the freshly




treated water stream and then it is all routed to  two storage tanks. This water is then blended




with fresh water and transferred to tanks that supply water to five downflow multimedia "sand"



filters.




      After being  filtered,  the water  is held in more tankage that supplies both diatomaceous



earth (DE) filters and centrifugal pumps.  This second filtration is to "polish"  the water for



injection into the  D-Block.  About 30,000 barrels of water are injected into the  D-Block  daily.




The remaining 65,000 barrels processed on a daily basis are distributed to the C-Block  injection



wells.  Because of the remote location of many of the injection wells in the waterfloods, several



other "plant sites" are  located throughout the  field.  Primarily, however,  these are  basically




stations containing limited tankage and pumps to boost the injection pressure.



      Mechanically, with  the help of some of the changes in the water imposed by chemical



treatment, the total suspended solids (TSS) levels of the water consistently and continuously are




reduced as a given body of water moves through the facilities.  (Tankage  is not sufficient to



hold the entire daily  volume required by the  flooding operations.) Figure 12 also indicates the




TSS  levels at various points in the system.   Overall,  the facilities  lower the TSS  from  an




average inlet level of 90 ppm to an average outlet level of less than 1 ppm.




     The testing that provides this  information uses filters which will collect particles larger



than 0.45 microns. Thus, not only is the TSS  level down, the size of the material is quite small.
                                          -378-

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These data verify  that the technology being used in the water treatment facilities is capable of




approaching the desired levels for "excellent" water quality.




B.   Chemical Treatment




     Major problems affecting Ventura Avenue Field water quality attacked by chemicals are




primarily related  to scale and  bacteria.  Although a  corrosion inhibitor program  is in place,




corrosion problems in the field are not considered significant; however, corrosion does affect




the scaling tendencies.




     1.    Scale;  Scale   deposition  in  the  Ventura  Avenue  Field is  a  continual problem.




Calcium carbonate, barium sulfate, calcium sulfate and iron sulfide precipitation is frequently




observed.  Because  all of  the  water in the C-Block and D-Block have high bicarbonate and




sulfate levels, chemically treating the water is necessary. Although many of the injection wells




are treated with acid periodically, appropriate treatment for scale has decreased the frequency




of the remedial work.




     Carbonate  and  sulfate   scale  is  generally  controlled  by  organic   phosphonates and




polyelectrolytes.  Both types of chemicals  aid in the removal of the  precipitate  rather than




allow deposition or continued crystal growth.  Because of the complex  nature of oilfield brines,




the myriad of chemical equilibria and the chemical kinetics, the  precipitation mechanisms are




not well understood; scale inhibition is still closer to an art than a  science.




     Control of iron sulfide precipitation and the subsequent fouling of equipment is attempted




by reducing or removing  the reagents used to form iron sulfide.  Restricting the  corrosion rate




reduces the soluble iron.   Eliminating  the presence  of hydrogen  sulfide removes a significant




source of sulfide ion.  Corrosion is controlled by a combination of the following:




     ...using alloy steels and plastics in construction,




     ...removing the dissolved gases,




     ...using plastic, epoxy or cement coatings on steels,




     ...organic film forming chemicals, and
                                          -379-

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     ...cathodic protection.




     2.    Bacteria;  Bacteria  have  associated  with them the attendant  problems affecting



corrosion and scale.  The three strains commonly attacked in oil field operations are sulfate




reducing bacteria, iron bacteria and  slime forming bacteria. In each case,  detrimental effects



on the  faciliites and, in turn, the solids content of the water, can be very deleterious.




     The first  rule for the successful  application of any  bactericide is to generate and then




maintain a  "sterile"  system.   This  means  that all surface  facilities  should  be  purged  of




biomasses in the tanks, along the walls of the pipes and in  the filters.  Because bacteria usually




prefer  to grow  in the nonturbulent  zones  of water systems and even under  scale or  debris, the



effectiveness of a  biological control scheme will depend on the manner in which the scheme



overcomes the  obstacles.  Bacteria will remain very  difficult to kill when they are shielded by



scale, debris or even their own  secretions (biopolymers and iron hydroxide, for example).



     In the Ventura Avenue Field,  these  obstacles are  tackled by  "pigging" the injection lines.



This means physically  removing scale, debris  and  even biomass  from  the tubular goods  by



forcing a scraping device, a "pig", through the lines.  Additionally, the filters and the tanks are




emptied and cleaned when evidence suggests that a problem exists.



     A new biocide  program  using  chlorine dioxide  has been implemented  in the Ventura



Avenue Field.  Many  months of optimization (which included  the monitoring of  biocide  levels,




introduction of  hydrogen sulfide scavenging and ferrous iron oxidation chemicals,  changes  in the



frequency, duration and location  of  the  chemical addition and cleaning of the surface lines,




tanks and filter vessels) have yielded the values indicated on Figure 12.




     When compared  to the requirements for  excellent water quality listed in Table  2, the



water treatment efforts for the C-Block and D-Block injection fluid approach ideal.  In general,




suspended solids are   "om  or  less, oxygen levels are less  than  10  ppb,  hydrogen sulfide  levels



are less than 0.1  ppm, corrosion rates exceed the guidelines and the soluble iron is essentially




zero.
                                          -380-

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                              IV.  MONITORING TECHNIQUES




A.    Injection Well Surveys




      Injection profile surveys are the primary means by which the entry of the injected water




is monitored.  The method commonly used is fluid velocity profiling which involves timing the




movement of an injected  slug of radioactive material in the flowing stream.  This procedure is




effective for determining the zones receiving fluid injection.   In addition, it is diagnostic for




fluid movement behind  casing, leaking packers and evaluation of well stimulation procedures




such as acidization.




      Shown  in Figure 13  is the  typical configuration of a radioactive tracer tool.  The casing




collar locator (CCL) is  a sensor that responds to the  increased metal density  at the casing




coupling.  This  information  is used to correlate the tracer survey data with the correct depth.




The ejector port is the point from  which the radioactive chemical (usually either  Iodine-131 or




lridium-192)  is  injected.  Finally,  two gamma ray detectors with known  spacing  lie below the



ejector.




      An example  of  injection profile  survey results can be  seen in Figure 14.  These  data




reflect the sensitivity of profile  on the rate within the  C-Block but also show the  resolution of




the  information available.   To explain  further, at an injection  pressure  of 1100  psi, five




identifiable zones  are  receiving water  injection and,   with the  exception  of the uppermost




interval, the  distribution is more or less equitable for each interval.  With an injection pressure




of 1800 psi, additional zones are taking water, although  the water is more  confined.  Finally, at




higher pressures,  still a different distribution is observed.   These types of data provide the




reservoir engineer and  operations personnel with  the basis  upon which  to  make  informed




decisions on the proper operations for the  waterflood.




B.    Spinner Surveys




      Another type of device used to follow the water as it leaves the  wellbore is  the "spinner"




tool.  This  tool, conceptually shown in Figure  15 is nothing more than a flow meter located on
                                          -381-

-------
the  bottom of a cable.  The "spinner" is simply a propeller that spins in response to the water



flowing past.  The rate  of spinning is detected by a receiving coil which surrounds a magnet




attached  to the propeller.




     The simplicity of the tool makes its operation easy to understand, but, it is also limited by



flow rate and orientation in the hole.  However, these limitations are well known  and can be




overcome for  many  situations.   The spinner surveys are  often  conducted  along  with the




radioactive injection profile survey to verify results.




C.   Temperature Surveys



     Reservoir temperatures  in the  C-Block and D-Block are  higher than the temperature of




the injection water and this difference in temperature allows identification  of the zones that




have received significant amounts of  injection water.  As the cooler water is injected, the rock



and fluid temperatures  are lowered.   By  recording the downhole temperature  with respect to




depth, any cooling observed can be distinctly attributed to the action of the injection water.



     Figure  16 shows the results of a  temperature survey that was conducted in a C-Block well



(Lloyd  //246). Several areas of cooling can be observed. Substantial cooling has occurred in the




"AC", the "AE" and the "AK" Sands  with some  cooling also seen in  the "AA" Sand.   Had no



influence by  the injected water occurred, the  temperature survey would have  shown the normal,




gradual,  steady increase in temperature as the depth increased.




D.   Water flood Tracer Surveys



     Various chemicals have  been used to follow the movement of the injected water through



the reservoir.  Although the information  from injection profile  surveys and  spinner surveys is



extremely useful, these data only indicate  the depths at which the water is exiting the wellbore.



They do  not  provide insight on the movement beyond the  wellbore.  By adding a  "tag"  to the



water  that  can  be  analyzed in  the  subsequently  produced  fluid,  communication  between




injection wells and producing wells can  be  defined.   To accomplish  this task,  however, the




chemical "tags" must (1) not react in the  formation chemically, (2) must move with the injected
                                          -382-

-------
fluids and not suffer adsorption, and  (3) must be  detectable  in the produced fluids.  To date,



fluorescent dyes, ions and radioisotopes have been used in the C-Block Unit Waterflood with



good success.



     For tests in which very rapid communication between injection wells and producing wells




is  suspected, flourescent dyes are recommended.  Their large losses  through  adsorption and



reactivity with reservoir constituents prevent a prolonged life.  Analytically, the presence  of




the dyes can be detected colorimetrically and even visually.



     Specific ions (especially thiocyanate) are recommended for situations anticipated to be  of



longer  duration.  Although  nitrate and sulfate may be  used as tracers, thiocyanate  has been



proved more  successful. Thiocyanate  can be detected colorimetrically after complexation with



ferric iron; however, ion chromatographic  techniques provide  more reliable information  with



much less sample preparation.




     Other  ionic chemical  tracers should not be used in  the C-Block Reservoir.   Chloride,



bromide, iodide and phosphate are all present with inconsistent levels  in the produced  water.



Lithium is expected to exhibit a significant exchange problem with the cations weakly bonded in



the reservoir clay material and has a relatively high cost.  Finally, fluoride has a very limited



solubility in the C-Block water (30 ppm maximum).



     Radioisotopes are the  best tracers for the long term, complex, flow-studies.  Although the



major disadvantages are the costs and inconvenience  of  the analytical  services, they have



better characteristics than either of the other types of tracers for the following reasons:



     ...They have few compatibility problems.



     ...Naturally occurring background levels of the radioisotopes are usually zero.



     ...Introduction of radioisotopes into the injection stream is very fast.



     Recent chemical  tracer work has produced very  good  results.   In an extensive test  to



define the nature of the interaction of a C-Block injection  well, Hartman #58, and a producing




well, Hartman //9, a combination of fluorescent dye, tritiated water and thiocyanate was used.
                                          -383-

-------
Because either the "AK" Sand or the "AH" Sand was suspected of contributing excessive water




to Hartman #9, several tracers were needed for primary and confirming information.  The final




analysis identified the "AK" Sand as  the offending zone when the injection pressure was above




1000 psi. Subsequent  reduction in the injection pressure at the "AK" Sand has resulted in lower




water production with no loss of oil production; a more effective use of the water.




     Sulfur-35,  introduced  as a sulfate, was tested with  inconclusive results.  Although  it




should  have been detected, it  was not.  This observation  has fostered speculation that the




sulfate moiety may have been consumed by the activity of the resident bacteria.




                         V.  CONTROLLING INJECTION WATER




     Because  the Ventura Avenue Field waterfloods are in structurally thick  reservoirs with




multiple layers of sandstone and shale, the equitable vertical distribution of the injected water




across  the waterflood interval has been a severe, vexing, continual problem for our engineers.




Since waterflood inception, many procedures have  been tried, and, unfortunately, many have




failed  to materially  improve  injectivity profiles.   The  C-Block injection interval  includes as




much as 1,000 feet of net oil sand and several hundred noncommunicating individual sand layers.




The designed injection rate  is 5 BW/day/foot of sand; however, some sands  will take no water




while some  "thief" zones take  over  100 BW/day/foot of sand.  The majority of the injection




wells have 7-inch cemented casing, perforated at intervals with two  1/2-inch holes per foot.




Many  older producing  wells  have been  converted  to  injection  wells  and  their  slotted-liner




completions make injection profile improvement very difficult.  Left uncontrolled,  water will




preferentially  enter  the zone which yields the least amount of resistance.  For these reasons,




care is exercised to specifically  direct the injected  water, again,  by both mechanical and




chemical means.




A.   Mechanical Methods




     1.    External Casing  Packers;  The primary cementing of the casing within the wellbore




is very important to  the integrity of the waterflood. External casing packers have been added
                                          -384-

-------
to the methods of segregating vertical sections of a given wellbore in an effort to improve the




primary cement effectiveness and to provide a reasonable guarantee for success



      In brief, the external casing packer  is an elastomeric sleeve surrounding a mandrel on




which an inflation valve system is mounted.   This design,  illustrated in Figure 17, allows the



sleeve to expand upward  from the  bottom  as it is  being filled with cement only after the




primary cementing operation has been completed.  Placement of this type of packer in the new



wells being drilled (or redrilled  because of  failure) eliminates fluid migration behind the casing




between the sands.



      2.    Mechanical  Flow Regulation; Generally, a single wellbore  is used to inject water



into more than one of the sands in the C-Block and, as has  been mentioned, the variety of  rock



characteristics will not allow the desired distribution of injection water over a large interval.



Therefore, regulation of the  flow between sand bodies having diverse  qualities is required to




improve the effectiveness of water.



      Figure 18 illustrates the type of flow regulation currently being used  in the C-Block and,



to a much more  limited extent, in the D-Block.  The assemblies consist of packers to isolate



zones intended for injection and a side-pocket mandrel containing a flow regulating orifice to



limit the flow rate by generating a backpressure.  Usually,  no more than five packers with four



mandrels have been  successful because of the difficulties with  their operation.  Once installed,



the  flow rates can be adjusted  by changing the size of the orifice within each mandrel.  This



operation can be performed remotely (by "wireline" recovery) so that the entire assembly does



not require removal.



      This  method of  controlling the injected  water  has proved to  be   the  most effective



technique when several zones of significantly different permeabilities are open to injection in  a




given well  at the same  time.



      3.    Cemented Isolations;  As  a general practice, isolations between one or more zones



may be needed in existing wells. External casing packers have not been used on many wells and
                                          -385-

-------
were not used on any wells prior to 1985.  Routine procedures for these situations require the




operator to establish a segregation, most often in an identifiable shale zone.




     Usually, the casing is perforated with six holes, sixty degrees apart along a  1.5 foot casing



section.  This orientation and low-angle phasing of the perforating holes provide  a very  good




chance of intersecting existing channels in the primary cement sheath.  Following a "spearhead"



of hydroflouric acid to dissolve the drilling mud filter cake, large volumes of cement slurries



are generally beneficial to permit casing wellbore annulus  fill up with cement.




     After an attempt is believed successful, the casing  is reperforated above  and below the



segregation to pressure test the zones, ensuring the integrity of the procedure.




     *.    Selective  Perforations: Because  a great wealth of information is available to the




Reservoir and Operations Engineers and Development Geologists, the maintanence and plans for



the waterflood are carefully thought through.  Each new project  (involving new wellbores and




the maintenance to replace failed wells) is  designed  to  selectively perforate  specific major




sands within the C-Block.



     For  example,  flooding  selective  sands is a  viable  option (assuming  the  recoverable



reserves assigned to the project can make the project economic).  This  technique certainly will



mechanically  restrict the water  only to those  zones thought  to contain  moveable oil and



improve the effectiveness of the injected water. However, not many areas are available in the




C-Block in which to define this type of project.



     The  nature of the deep waterflooding operations in  the D-Block are essentially selective




sand floods.  The difference in reservoir pressures requires special measures and the difficulty




of achieving good mechanical isolation at depths greater than 10,000 feet make the flooding of




multiple sands less attractive.  The history of the C-Block waterflood  suggests  that initial



selective flooding of the C-Block may have resulted in a much more manageable project today.




B.   Chemical Methods



     1.    Acidization;  Regardless of attempts to maintain exceptionally high quality injected



fluids, injectivity unfortunately decreases in the water injection wells.   This loss of injectivity
                                          -386-

-------
is  usually  caused  by  damage  from  scale  deposition  and particulate matter.   The  loss is

monitored  by a gradual but continual increase in the injection pressure and, eventually, when

the maximum available pressure is reached,  a decrease in the  injection rate occurs. To  rectify

this damage, wells  are usually treated with acid  in an attempt to restore  the  well closer to its

former condition.  Unfortunately, the original conditions can never be attained again.

      Although the  details of the entire procedure are quite involved, the usual procedure for an
                                                                                       i
acid treatment consists of three  "stages" of injection using 20 gallons of an acid  mixture per

foot of open interval.  The entire  perforated interval is "washed" in two-foot increments using

one stage at a time. The composition of typical acid stages in  a program is given in  Table 3.

      The acid  provides significant improvements to the  injectivity.   As the  quality  of the

injected  water continues  to improve,  less frequent acidization programs will  be required.

Because  of the reduced frequency of acidization, water  will be entering the zones preferred by

the engineering  staff  for  a much  longer  time  and the  adverse consequences  of reduced

injectivity  will not  be as severe.

      2.    Crosslinked Polymer; A program using crosslinked  water-soluble polymers to aid the

mechanical methods in the redistribution of injected water was implemented in the C-Block

Unit Waterflood.  This project was certified as a qualified tertiary recovery method under the

Windfall Profit Tax Act of 1980 and consisted of a series of injection well treatments designed

to curtail  the ability  of certain zones to accept the injected  water while not impairing the

injectivity  of other sands.  The goal of each  treatment was to provide  a means to more  evenly

distribute  the injection water when no other method would be available.  Again, the result of

the treatments would  be a more effective placement of the injected water and would yield a

more  efficient recovery of incremental oil.  The results of a  well treatment are shown in the

conceptualized drawing of  Figure  19.  As shown, the polymer  enters a zone previously open to

water  injection and effectively  restricts further  flow.  The water is then  forced into areas less

affected, or even previously unaffected, by the waterflood.
                                         -387-

-------
     Each well selected as a  treatment candidate was extensively reviewed to determine how




better  to redistribute  the  injected water.   Usually, a sequential injection of a polymer  and




crosslinking agent followed by injection of polymer fluid containing a crosslinking agent formed




the basis for the treatment. Each treatment was specifically tailored to the conditions of the




individual well.  As the complex nature of the process became better understood by the project



engineers, the ability  of the  process  to  intentionally  reduce the water injection  in  selected



zones improved  and, as a  consequence, the redistribution of the injected water occurred as



planned.




     Data from  the injection  profile surveys taken following  the treatments conducted in 1985



indicate  consistent improvements.   As  shown  diagramatically  in Figure  20, the  average




reduction in daily water injection into the sands  receiving the polymer treatment was about 36



percent (from  876 to  562 barrels of water per  day).  For the individual treatments, the best




reduction of injectivity was 76 percent while the lowest was actually an increase of about 12




percent.



     However, each well treatment resulted in an increase in injection into the  sands targeted



for an increase, as depicted in  Figure 21.  On the  average, the eight treatments resulted in a 38




percent increase of injection.   As a result of these treatments, in total, about 2,371 barrels of



injected water have been redirected to zones having more potential.



     Although the project was planned to continue for several years, the dramatic drop  in the




price of oil made these expensive, individual well  treatments uneconomic.  Consequently, the




program has been discontinued; the manpower has been reassigned.




                                     VI. SUMMARY



     Historically,  water entry surveys performed in the C-Block  Unit  wells  indicated that,



generally, the highest  water  production  occurred in those zones of greatest water injection,




confirming zone  isolation with no apparent crossflow (Figures 22 and 23, Tables 4 and 5).  Static




temperature surveys, conducted at very regular intervals, substantiate that  none  of the injected
                                          -388-

-------
water is moving out of the targeted waterflood zones. Figure 24 clearly reflects that the "AH"




and "AK" Sands have been successfully  flooded  while  the "AM" through  the  "AQ" intervals




remain  basically unflooded.  Utilizing procedures discussed in this paper, the art of "selective



waterflooding" is now being applied to these less permeable sands with promising results.



      Much  has been said here  about  "technology" and the  "proper  application"  of  that



technology.  However, we must also address the assimilation and the  interpretation of  these



data.  As with any  new project, hindsight has  fostered the creation of invaluable information



systems for the C-Block Waterflood which can (if properly used) immediately denote  specific



problem areas.  Conversely, these same  data banks can often affirm the successful pursuit of



increased  reserves recovery by waterflooding.   (These monitoring systems are already in  place




as a monitoring device of the newer D-Block  Waterfloods).



      Records  must be  accurately  and  diligently maintained.    Engineers  must  periodically



review  fluid levels, production and injection rates,  as well as injectivity  profiles. Complex



waterflood projects are best reviewed on an individual well basis; composite data per flood have



a tendency to hide or distort problematic  areas resulting in counterproductive effects.



      Having arrested the waterflood base decline  rate (as shown on Figure 25) the C-Block Unit



Waterflood  is considered extremely successful.  However,  this pinnacle will not be sustained



without future extensive  waterflood  maintenance.    Well replacements  (new  or redrilled



wellbores), improved injection well profiles  and the continuing stimulation of producing wells



will be  favorably reflected in reserves recovery.  Our waterflood achievement  in the  Ventura



Avenue Field is also a direct and positive manifestation of the skillful application of proper



oilfield  technology blended with the vital synergism of the reservoir engineer and operating or



field personnel. Through this  fundamental collaboration, we have learned to emphasize  correct



operating  strategy,  rather than merely relying on  proper procedures.   As a result, Texaco's



success is  twofold:   ...increased reserves recovery with its associated economic rewards and



...the secure knowledge that the integrity of the surface and subsurface ecological systems has



been preserved.
                                          -389-

-------
       English Unit
          Acre
          °AP1
           bbl
           cp
           ft
           oF
           gal
           mil
           psi
         scf/STB
           in
          VIL APPENDIX
English to Metric Conversion Factors

x 4.04687 x 10+3
x 1.58987 x 10"1
x 1 x 10-3*
x 3.048x10-1*
(OF - 32)/1.8
x 3.78411
x 2.54 x ID'3*
x 6.89476
x 1.80118 X 10-1
x 2.54*
     Metric Unit

       g/cm3
         m3
       P2 • s
         m
         °C

         cm
        kPa
std m3/stock-tank
         cm
*Conversion factor is exact.
                                        -390-

-------
                                  Vffl. REFERENCES



1.    "The Reservoir Engineering Aspects of Waterflooding", Craig, F. F.:  Monograph Volume



     3, Society of Petroleum  Engineers of American Institute  of  Mechanical Engineers, Ne-




     "ork, 1971, p. 9.



Much of the  information  in  this paper has  been summarized from  the following  internal



reservoir engineering reports and papers:



2.    "Reservoir Engineering Analysis. C-Block  Unit Waterflood (1970-198ft)".  Goble, P.G.:



     Texaco USA, October 1984.



3.    "Ventura District 1987 Capital Budget", Texaco USA, June 24, 1986.



4.    "Water Injection  Well Monitoring Ventura  Avenue  Field", Goble,  P.O.,  Reis, T.A., and



     Davis, A.K.:  Getty Oil Co., September 1983.



5.    "Here's How Getty Controls Inactivity Profiles in Ventura", Froning, S. P., Birdwell, R.F.:



     Oil and Gas Journal, February 1975.



6.    Hartman  58  Tracer  Tests Results and  Recommendations;  C-Block Unit Waterflood",



     McHenry, J.: Texaco, USA, July  9, 1986.
                                        -391-

-------
                                        TABLE 1

                 FLUID AND ROCK PROPERTIES (C-BLOCK AVERAGE)
                               VENTURA AVENUE FIELD
PRESSURE (datum 5500 feet subsea)

Initial psia
Bubble point psia
Reservoir pressure psia (1956)

TEMPERATURE (datum 5500 feet subsea)

Reservoir °F

ROCK

Anticline plunge
Formation dip degrees (South Flank)
 (North Flank)
Average formaton depth (subsea) ft.
Porosity (range %)
 (with overburden)
Permeability
 (air-absolute) md (range %)
 (effective brine) md
Permeability  variation

Authigenic clay content, thin section analysis, Lloyd #235
 (total)
 (expandables, fraction of total)
Authigenic clay content, pipette analysis, Lloyd
 (total)
 (expandables, fraction of total)

SATURATION

Soi (fraction)
Swi (fraction)
Sgi (fraction)

OIL

Gravity (range o API)
Viscosity (initial, cp)
Bo (initial)
 (1956)
2800
2800 (Assumed)
550
160
3°-8° Eastward
up to 60°
5500
22.0 (18.8-24.8)
20.0

160 (70-350)
70
0.7
1-17% avg. 5%
6-79% avg.

avg. 3%
avg. 50%
.70
.30
0
30.50 (29°-32°)
1.3
1.315
1.141
                                          -392-

-------
                                  TABLE 1 (concluded)

PRODUCED WATER (C-3 SANDS)*

Na (ppm)
Ca (ppm)
Mg (ppm)
Cl (ppm)
HCO3 (ppm)
SO^ (ppm)
B (ppm)
ph

* Average of eight analyses - primarily Phases 1 and 2

GAS

Original gas formation volume factor = Bgi (RB/scf)
 (1956)                            = Bg

Original gas compressibility factor    = Zi
 (1956)                            = Z
Initial solution GOR scf/STB
 (1956)

Original gas viscosity (Cp)

Gas specific gravity 7g
                                   = Rsi
                                   = Rs
                                                                       10,467
                                                                      205
                                                                      17,097
                                                                      750
                                                                      7.5
                                                                      56
                                                                      7.7
0.00517
0.02941

0.835
0.911

570
135

0.0186

0.8
                                         -392-

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                                      TABLE 2

                    OPTIMUM REQUIREMENTS - INJECTION WATER
                            C-BLOCK UNIT WATERFLOOD
Our experience indicates the following general requirements are necessary for excellent  water
quality:
     Item

     Suspended solids

     Scale


     Iron (total)

     Corrosion  rate

     Pit depth (30 days)

     Pit frequency (30 days)

     Oxygen

     Bacteria count

     H2S
Level at Inj. Wellhead

Less than 0.5 ppm

No decrease in calcium, sulfate or bicarbonate
levels through the system

Less than 1 ppm

Less than 0.1 mils/year

1 mil

1 pit/sq.in.

Less than 10 ppb

Less than 100 colonies/ml

Zero
                                        -394-

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                                   TABLE 3

                           STAGED ACID PROGRAM
                             ACID COMPOSITION
STAGE         DESCRIPTION

 I              A solution  of  15 percent  hydrochloric  acid containing  0.5  percent

                corrosion inhibitor, 0.3 percent  water wetting surfactant, 15 pounds per

                1000 gallons of  iron chelating agent, 1.0 percent acetic acid for buffer,

                20 pounds per 1000 gallons of a reducing agent and 3 percent of a mutual

                solvent.



 II              A solution of  13.5 percent hydrochloric acid and 1.5 percent hydrofluoric

                acid containing  0.5   percent  corrosion  inhibitor,  0.3  percent water

                wetting surfactant, 15 pounds per 1000 gallons of iron chelating agent,

                1.0 percent  acetic acid  for  buffer,  5 pounds per  1000  gallons of a

                reducing agent.



 Ill             A solution  of  7.5 percent hydrochloric acid containing  0.5  percent

                corrosion inhibitor, 0.3 percent  water wetting surfactant, 15 pounds per

                1000 gallons of iron chelating agent, 1.0 percent acetic acid for buffer, 5

                pounds per 1000 gallons of a reducing agent and  3 percent of a mutual

                solvent.
                                     -395-

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              TABLE 4

    GROSS PORE VOLUME INJECTION
PHASES 1-10. C-BLOCK UNIT WATERFLOOD
Za
AA
AC
AE
AGa
AH
AK
AM
AO
AP
AQi
AS
Floodable
Sand Vol.
(AC.FT.)
24,940
19,361
39,295
64,474
57,569
42,075
90,508
46,083
16,675
16,760
21,787
22,932
0
.20
.20
.20
.20
.18
.20
.20
.20
.18
.18
.18
.16
Gross PV
(MBbls.)
38,697
30,041
60,970
100,038
80,392
65,284
140,432
71,502
23,286
23,404
30,424
28,465
Inj. To 3/1/8*
(MBbls.)
26,505
16,457
27,462
30,057
36,179
58,634
84,397
17,237
4,305
987
841
7,393
%
PV
68
55
45
30
45
90
60
24
18
4
3
26
                -396-

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                 TABLE 5

          WATER ENTRY SURVEYS
PRODUCING WELLS. C-BLOCK UNIT WATERFLOOD
BWPD
Lloyd #56 Lloyd #99 Lloyd #10* Lloyd #1*2
Markers 8/7/78 10/21/7* 12/30/82 */28/78
Za MINOR 280
AA
AC
AE 200
AGa
AH 175
AK MAJOR 515 60
g AM 120
^ AN
AO 25 50
AP
AQi
AR
AS 20
Lloyd #226 VL&W #2 VL&W #160 McGonigle #*3 Marker
12/16/77 9/5/78 12/26/79 5/20/76 Totals
300 580
220 220
100 170 270
200
0
130 290 595
80 210 865
120
320 320
75
0
0
0
20

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                                              Figure 1

                                       AREAL CONFORMANCE
                    POOR OIL RESPONSE
VD
00
           POOR INJECTION BALANCE AND COVERAGE
       GOOD OIL RESPONSE
GOOD INJECTION BALANCE AND COVERAGE

-------
        Figure 2

 VERTICAL PERFORMANCE
   SATURATION FRONTS
    POOR OIL RESPONSE
POOR VERTICAL CONFORMANT
   GOOD OIL RESPONSE
   BALANCED INJECTION
           -399-

-------
                               Figure  3

                        FIELD  LOCATION MAP
R 24 W
           R 23W
                      R 22 W
R 21 W
R 20 W
R 19 W
R 18 W
                                             R 17 W
          HOPPER .
          CANYON^
                                         MARILLO

                                             CONEJO (Abd)
                                                                      PIRU CREEK
                                                                              AMONA
                                                                                         T

                                                                                         5
                                                                                         N
                                                       T

                                                       4
                                                       N
                                                                   EUREKA CANYON
                                                       CANYON GAS  *  _ _—NORTH TAPO
                                                            (Abd)-~^5~v»^*. ^-TAPO  RIDGE
                                                          , TORREY ^f  VBANTA SUSANA

                                            SOUTH   |H;N^CTKOR%GE^  %™™>     ]
                                            MOUNTAIN^0AANKYOpNARKN I  -BIG MTN J CANYOXN
                                                                                  \
1
1
1
1
1
°SIMI









                                                                           SANTA SUSANA
                                                             THOUSAND OAKS \
                                                                                         T
                                                                                         2
                                                                                         N
                                                                                         T
                                                                                         I

                                                                                         N
                                                                                         I

                                                                                         S

-------
                        Figure 4

                  VENTURA AVENUE FIELD
               NORTH-SOUTH CROSS SECTION
      C-BLOCK
         UNIT
BARNARD FAULT
                                             TAYLOR FAULT
                                             D-BLOCKUNir
                             -401-

-------
               Figure 5
TYPE ELECTRIC LOG - VENTURA AVENUE  FIELD
           (LLOYD NO. 244)
                       C-5
                  -402-

-------
                                          Figure 6



                                   VENTURA AVENUE FIELD

                          C-BLOCK AND D-BLOCK UNIT BOUNDARIES
o
CO
I
                                                   LEGEND




                                                 — — — — C-BLOCK UNIT




                                                 —^— D-BLOCK UNIT

-------
                                     Figure 7


                              C-BLOCK UNIT WATERFLOOD
i
-O
o
                                     UNIT  BOUNDARY     ^

-------
                                           Figure 8


                                   PROJECT PRODUCTION HISTORY

                                    1-10, C-BLOCK UNIT WATERFLOOD

                                         (1961  -  1984)
i
-p-
o
Ijl
I
q

£
                 1961
                      1966
1971
1976
1981

-------
                          Figure 9

                   VENTURA AVENUE FIELD

              V.L.&W. EAST D-6, 7U WATERFLOOD



                       D-BLOCK UNIT
                  D-Block
                  Unit Boundary
                        Waterftood
                        Area
                                                        N
LEGEND


 WATER NJECTOR

 PRODUCER
WATERFLOOD  AREA
                        -406-

-------
I
->
o
~J
I
                                           Figure 10


                                     VENTURA AVENUE FIELD

                          D-BLOCK UNIT WATERFLOOD STATUS
                D-5 ZONE
                                                                            WATERFLOOD

                                                                               AREA



                                                                            Lloyd  CD
                                                                            Hartman


                                                                            V.L.4W.
                                                                            Weat


                                                                            V.L.4W.
                                                                            Central

                                                                            V.L.4W.
                                                                            East

-------
                     Figure 11
               VENTURA AVENUE FIELD
      PERFORMANCE OF D-BLOCK WATERFLOODS
                                                     I- 100M
                   WATER INJECTION
                                                      - 10M
                                                      - 1M
                      PRIMARY OIL
I 1078  I 1979 I 1980 | 1961  I 1982  I 1983 I 1984 I 1985 I 1986
                                                        100
                          -408-

-------
                                                Figure 12
                              VENTURA AVENUE WATER CLEANING SYSTEM
o
VO
I
                           BIOCIDE
 INJECTION TO  -	
   D-BLOCK             0.4 ppm TSS
(30 MBBLS/DAY)  100 COLONIES/ML SRB
           OXIDIZER/BIOCIDE
             ^   1
         PRODUCED WATER
          (70 MBBLS/DAY)
                SOURCE WELLS
               (10 MBBLS/DAY)'
            SOURCE TANKS
                                  WEMCOS
 1.0 ppm TSS
 100 COLONIES/ML SRB
-^	1—&—oooo
                                 D.E. FILTERS
                                                MULTIMEDIA
                                               SAND FILTERS
                                                                                 >. INJECTION TO
                                                                                    C-BLOCK
                                                                                  (65 MBBLS/DAY)
                                                                         POST-FILTER TANKS
                                                            10 ppm TSS
                                                            106 COLONIES/ML SRB
                                                                         PRE-FILTER TANKS
r^ ^-r^ » l
/ FRESH
^ 1 \A/ATi-r>
\ TANK
                                                                                        LAKE CASITAS
                                                                                           WATER
                                                                                       (15 MBBLS/DAY)

-------
              Figure 13


TYPICAL RADIOACTIVE TRACER DETECTOR
        TOOL CONFIGURATION
                     CCL
                     EJECTOR PORT
                        TOP OF
                     GAMMA DECTOR
                        TOP OF
                     GAMMA DECTOR
            -410-

-------
                             Figure 14
7100
    8EQ.i .!
7160
7200
7250
7300
      17
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     73
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         37
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         as
         21
7360
7400
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                           LLOYD  234
                 INJECTION  PROFILE  SURVEYS
                       6/29/83
                      460 BWPD
                       1100 P8i
                                 lilJ
                                            B
 6/30/83
760 BWPD
1800 psi
                                       2222223
 7/1/83
860 BWPD
 2200 psi
            V.VWiYMWYM
                 0  10   20   30  40  60 0   10   20  80  0   10   20   30

                                 INJECTION RATE
                                     B/D/FT
                              -411-

-------
                         Figure 15
           SPINNER SURVEY TOOL CONFIGURATION
PIPE
 WIRELINE

   CABLE
INSTRUMENT
 IMPELLER
                 —I °

                   £
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                       CASING CABLE-






                             MAGNET





                         PICKUP COIL






                             SPINNER
                          WELL CASING
                                        •H
                                              5pj)
                                                 t
                                              N\
                          -412-

-------
                   Figure 16

   TYPICAL TEMPERATURE SURVEY RESPONSE
C-BLOCK UNIT WATERFLOOD, WELL LLOYD #246
        TEMPERATURE »F
 4000'-s
 5000'-
 6000'-  —
                                         STATIC
                                     TEMPERATURE
                                           °F
                  -413-

-------
              Figure 17
EXTERNAL CASING PACKER SCHEMATIC
                                    MUD DISPLACED
                                    FROM ANNULUS
                                 HIGH SEAL LOAD AT
                                  ROCK INTERFACE
                             FILTER CAKE COMPRESSED
                                  AND DEHYDRATED
               -414-

-------
INJECTION WELL FLOW REGULATION ASSEMBLY
                 X
                      \
                  -415-

-------
                                   Figure  19
                   CONCEPTUALIZED POLYMER TREATMENT
   .".'•••.'•'•••. '• '•:'.'.•%'••'TV "••e.'.•»*.*>• •*•" ••- '.c '•.:.< '.•;.•:,•«'''• •'
   •?•';?• ..";•..*.••,.'•;"•• i••'« ••*'••• .••••,•"."•••••
                               FLUID FLOW

1.  FLUID ENTERS STREAM TUBE - A
2.  INJECT POLYMER
*.  FLUID DIVERTED TO STREAM TUBE - B
         LEGEND
            WATER

            OIL
            WATER,
            SOME OIL
[POLYMER [    POLYMER
                                                                          FORMATION
                                    -416-

-------
                           Figure 20
                        C-BLOCK UNIT
                POLYMER TREATMENT RESULTS
                       TREATED SANDS
      INJECTION RATE. BWPD
2000
1500-1
1000-
 500-
                                          BEFORE TREATMENT
                                          AFTER TREATMENT
         AVG.  L-49  H-64 L-270 L-216 V-14  L-67  H-12a  L-62

-------
               2000'
                                         Figure 21
                                      C-BLOCK UNIT
                             POLYMER TREATMENT RESULTS
                                    UNTREATED SANDS

                       INJECTION RATE, BWPD
                                                           BEFORE TREATMENT
                                                           AFTER TREATMENT
                1600'-
00
                1000'-
                 500'-
                         AVG. L-49  H-64 L-270 L-216 V-14  L-67 H-12a L-62

-------
                             Figure 22
                     GROSS PORE VOLUME INJECTION

               C-BLOCK UNIT WATERFLOOD, PHASES 1
                                              - 10
   1.00
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-------
                                               Figure 23

                                        WATER ENTRY SURVEYS
                              PRODUCING WELLS, C-BLOCK UNIT WATERFLOOD
                900
NJ
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 •
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to
                800-
                700
                600-
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-------
                                   Figure 24


                          INJECTION PROFILE STATUS

                         C-BLOCK UNIT WATERFLOOD
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                                  SANDS
             uugiiigiiiiiiig
                                  LEGEND



                             FLOOOABLE AC. FT. - % UN8T TOTAL



                             CUM. INJECTION - % UNIT TOTAL



                             12/1 sea INJ. RATE - % UNIT TOTAL



                             8/1984 INJ. RATE -  % UNIT TOTAL

-------
                              Figure 25


                    C-BLOCK UNIT OIL PRODUCTION
     8000-
     7500-
                                       5% DECLINE RATE
o
Q.

O
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111
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           1979  '1980  '  1981
     5500-
     5000
1982'  1983

    YEAR
1  1984  I  1985  '  1986  '

-------
                STATUS OF MECHANICAL INTEGRITY TESTING
                            IN MISSISSIPPI

                                  by
               Lynnette A. Gandl  and Desiree  A.  Landry
                    KEN E. DAVIS ASSOCIATES,  INC.
                         11805 Sun  Belt Court
                     Baton Rouge,  Louisiana 70809
                             (504)293-2561
I. ABSTRACT


     Pressure testing of Class II wells  in  Mississippi  for mechanical

integrity has been  witnessed for the  last  two  years by Ken  E.  Davis

Associates (KEDA) personnel  under contract  to Engineering  Enterprises

Incorporated and  the  Region IV United States  EPA office  in  Atlanta,

Georgia. Initially, only those wells used for secondary recovery were

tested;  however,  all  Class  II  disposal  wells  are currently  being

tested. The  testing conducted  from September 1985 through March 1987

resulted in  a  failure rate  of approximately 20*  for all  first time

tests. However,  some of these  failures were due  to pressure .increases

caused  by  insufficient  temperature stabilization  prior  to  testing,

rather than pressure increases or decreases due  to  leaks.  Evidence of

well failures has been  observed  at  some sites,   and  some unusual well

completions  have  resulted in  variable testing  procedures.  Suspected

groundwater  contamination  due to  oilfield  operations  has also been

reported and preliminarily investigated  in  some  areas of the  state.
                                -423-

-------
II.  INTRODUCTION-DEFINITIONS






     The primary function  of KEDA personnel  in  Mississippi has  been




to act as witness to a variety of procedures  required by the U.S.  EPA




of the Class  II  operators  in the state.  The  procedures are intended




to assure  that  all Class  II wells  in  operation are  operating in  a




manner which  assures  that  all Underground  Sources  of Drinking  Water




(USDW's) are  protected  from  contamination by the injected  saltwater.




The principle  concern  has been  to  determine  if  the operating  wells




are properly constructed and have mechanical integrity.




     The procedure which is  being used to assure internal  mechanical




integrity  is  a  pressure  test   of  the  annular  space between  the




injection tubing and the protection casing. A file review of all  well




completion records  is   also  conducted to  determine  if  each  well  is




properly  constructed   to  protect   the  USDW.  Proper  construction




includes surface or production casing set below the base of the  USDW,




and sufficient  cement  behind  the  casing to  prevent  migration  from




saltwater bearing zones into USDW's or freshwater bearing zones.




     Other functions  carried out by KEDA for the  EPA have included




witnessing plugging  and abandonment procedures  to  assure that  the




plans approved by EPA  are  followed.  Wells scheduled for plugging  and




abandonment have included  formerly  operating  Class II wells which do




not  meet  construction  or  MIT   requirements,   and  unplugged   or




improperly plugged abandoned oil  and gas  exploration wells  within  the




area of review of the permitted Class II wells.
                                -424-

-------
     Unannounced inspections  have  also been performed  on  wells which

have  been  ordered  shut   down  due  to  failure  to  meet  permitting

requirements. The operational status and condition  of  these wells  are

noted  when   inspected,   and   each  is  photographed   by   the  field

inspector.

     Other tasks requested specifically by  EPA which  have  also  been

performed are described in the following sections.


III. EESDLTS OF MECHANICAL INTEGRITY TESTS

     A. Pressure Test Requirements to Prove  Internal Mechanical
        Integrity

     The  requirements  for mechanical  integrity which  have  been  used

in Mississippi  were  designated  by  the U.S.  EPA  Region IV  office  in

Atlanta,  Georgia.  The  pressure  test  to  confirm  mechanical  integrity

of  the well  casing  requires  that  the  annulus  be pressured  to  a

minimum of 300 psig  and that  this pressure must hold for a minimum of

30 minutes with  no more  than  a  3%  change in pressure.  However,  most

tests  have been  run at  a minimum of  500  psig  in  order  to meet  the

requirements  of the state  of  Mississippi. Tests  which exceed  30

minutes may be allowed  one additional percentage point  of change  for

each ten minutes, to a maximum of 6%.  Failure  is  considered as either

an  increase  or  decrease  in  pressure  in   excess  of  the  allowed

percentage.


     1. Pressure Decreases

          A decrease in annulus  pressure during testing can be caused

     by leaks at a variety of  locations in the  system as follows:

     	The downhole packer on the tubing can leak,
                                 -425-

-------
	The casing can leak through a corroded spot  or  a  parted  joint



of casing,




	The  injection tubing  can  leak  from the  annulus  into  the



tubing during a test, or




	The seals and valves at the surface can leak.




     Additionally,  leaks  in  the   surface  pipes  leading  to  the




injection tubing  can also cause  surface and shallow  subsurface



contamination.




     A  decrease  in   annulus  pressure can also  be the result  of



injecting cold fluid down a well that is geothermally  stable.  As




the cold fluid is injected, the temperature of  the annulus  fluid



drops due  to  contact  with the  cold injection  tubing,  and  the



corresponding  pressure in  the  annulus  drops.  The  temperature



will  eventually  stabilize   if    injection  of  cold  fluid   is



continued over a sufficient period for the well  to reach  thermal




equilibrium.  At  that time  the well can  be successfully  tested




with meaningful results.






2. Pressure Increases



     Pressure  increases  due  to  lack  of  internal  mechanical




integrity  can  occur  if  the  injection  pressure  exceeds  the



annulus  pressure  and a  leak in the injection  tubing or  packer



allows  injection fluid to bleed into the annulus  during  testing.



However,  a  common  reason  for failure  due  to  an  increase  in




pressure has  been temperature increases  caused when  cold  fluid




is  placed into  the annulus  on the day  of  the  test,  and  the




temperature  is  not   allowed  to stabilize before  the  annulus  is
                            -426-

-------
pressured up.  When cold  fluid  is  placed in a deep borehole,  the




increasing temperature  of  the earth  with depth  will  heat  the




annular  fluid  and cause the  pressure in  a sealed  annulus  to




rise.  This  rise in  pressure  as  a result  of thermal  expansion




could mask  a  small  leak and  therefore such a test  can  not  be




considered valid.






3. Results of Pressure Tests



     The  MIT's   conducted   during  the  period  from  startup  in




August  1985  through  March  1987   have included  both  secondary




recovery wells and saltwater disposal wells. Most  of  those  wells




which  failed  their  first  MIT have  been  retested   or  will  be




retested. The figures below reflect the results of MIT's  through




the end of March, 1987.




     Large Operators




          Five  oil  companies  operating  in the  state have  each




     had 19 or  more  of  their  wells tested. The total tested  for




     each company  ranged from 19 to  47,  and  the failure  rate




     ranged from 5*  for one operator  to  32% for  two operators.




     Interestingly,  the  operator  with the  most   wells  had  the




     highest success  rate.  For the group  as  a  whole, 22%  or  37




     of  the  total  171  wells  tested failed  their first MIT.  Of




     the failed wells which have been  retested  almost all  passed




     the second  MIT,  although not all  of the failed wells  have




     been retested. Some companies have chosen  to temporarily or




     permanently abandon the wells which failed.
                           -427-

-------
     Svall  Operators



          Fourteen  companies  have  each  had fewer  than  10  of



     their  wells  tested;  ten of  these companies  have  had only




     one to three wells tested. A  total  of 37 wells were  tested




     for these fourteen  companies  with an  overall failure rate




     of 30*  resulting from  11  failures.   These  small  operators



     are not  necessarily  independent  oil  companies,   some  are



     majors with  few  wells  in the state  and/or  few wells which



     have been selected to be tested.



     Well Locations




          Of  the  208  wells  tested  through  March  1987  the



     majority were  located in Wayne  and Yazoo counties, with 67



     and 47  tests,  respectively (Figure  1).  Jasper and Lincoln




     Counties had  28  each tested,  and Pike  county  had 19.  The



     following counties  had  fewer  than ten  wells each tested:



     Jefferson,  Adams, Wilkinson,  Lamar,  and Amite.






     As mentioned  previously,  wells  were  selected by  EPA first



on the basis of use as secondary recovery wells, and then on the



basis of  concentration of wells  in an  area and  potential  for




USDW contamination.






4. Unusual Well Completions and Tests






     One type of  completion  for which  an annular pressure test




is inappropriate  is those wells  in which  the  injection  tubing




has been  cemented  into  the  hole.  Because a minimal  amount  of
                           -428-

-------
annular space is present  above  the  top of the cement  a  pressure




test of  the  annulus can  not  be  used  to test  the  mechanical




integrity of such a  well.  For wells  such as these  a  radioactive




tracer  survey is a more appropriate test.




     Several wells  are  injecting  into  more   than  one  disposal




zone,  and due to this unique construction have been difficult  to




test.   Failures  due  to  pressure  drops  occurred  frequently  and



successful  tests  were  accomplished  only  after   the  packer  was




reset   or replaced.  Three  different  methods of  accomplishing




injection  into  multiple  zones  have  been   observed  and   are




described below.






          a. Two tubings  are  run side by  side to  two  different




     depths  (Figure  2B).  A dual packer  is  in place which  seals




     off both tubings above an upper disposal zone, and  a  single




     packer  is  set  on  the lower tubing,  sealing off the  lower




     disposal   zone.  Two   sets   of  perforations  are   usually




     present:  one at the base of the  upper tubing, between  the




     upper  and  lower packers,  and  one  below the  lower  packer




     into which  the  lowest tubing injects. In one  case,  a  zone




     above the upper packer is also perforated, and injection  in




     the past has been down the annulus of the well.






          b. Two tubing strings are run,  one inside  the  other,




     with the smaller,  inner  tubing  at a greater depth  than  the




     outer  tubing  (Figure 2C).   Packers  are set  at the base  of




     each tubing string and injection  is into  perforations below
                           -429-

-------
          each  packer.   In   one  case   a  third   set   of  plugged




          perforations  is   present   above  the   upper   packer   and




          injection was previously into this zone.






               c.   A  tubing  string  is  run with  one or  two sliding




          sleeves  set across one  or  two different disposal  intervals




          (Figure   2D).   Packers  separate  the   sleeve  openings  to




          provide  for controlled injection into either of the zones.






          In  some  of these  completions,  the  wells  were   originally




     used to  simultaneously  produce   oil  from  one  tubing  and  inject




     saltwater down the other tubing or down the  annulus. However, we




     are not aware of any wells currently being used in this manner-






     B.  Factors to Demonstrate External Mechanical Integrity






     Casing  and  cementing  records  for  each  well  tested  are  also




reviewed to determine the  location of  each string of casing, and  the




calculated  or  measured height  of the  cement  behind  the  production




casing.   The  location and  thickness   of  the injection  and  confining




intervals are also reviewed, if known,  in order  to  determine whether




the USDW's are being protected by sufficient confinement. The results




of the  reviews  are  forwarded  to EPA  for followup  as  required.   The




significance  of  USDW  protection  is  discussed  in  the   following




section.






IV. INJECTION ZONES AND USDW PROTECTION






     In   Wayne  County in  the  eastern  part  of the  state,  the Lower




Wilcox  Aquifer  is  the  deepest  USDW  in  most of  the  county.  This
                                -430-

-------
aquifer consists of  the  lower portion  of  the Lower Wilcox  Group and

the  upper portion  of  the  Naheola Formation.  Under  present  laws,

injection of  oilfield brines  or drilling  fluids  into  a USDW  via  a

Class II well  is prohibited;  however,  numerous wells  in  Wayne County

in some  adjacent counties  have  been  injecting into the  Lower Wilcox

for  30   to   40  years  under   previous  authorization.   The  permit

applications for these Lower Wilcox wells  in Wayne County  have been
denied when application is made, and the wells  have  been  ordered shut

down within a  specific period of time.  Some  operators  have  requested

that an aquifer exemption  be granted,  on the basis  of  the historical

injection into the  zone,  and  the water   quality degradation  which has

already occurred.

     Insufficient  confinement of  the   Lower  Wilcox  is  suspected  in

some of the areas near and within Wayne  County.  Therefore, EPA is now

requiring that supporting information such  as  geophysical logs,  cross

sections  and  hydraulic  conductivity  values  from  core  analyses  be

submitted with each application  to operate.
   *
V. INSPECTIONS AND  OTHER TASKS

     KEDA has  also been  asked to perform additional tasks related to

the operation  of Class II  wells, which do  not  deal  specifically with

Mechanical Integrity  Testing.  These tasks  generally are  performed in

order to  verify  whether or  not  wells  which  have  not  been  permitted

have ceased  operation and/or been  properly  plugged   and  abandoned.

Some additional  tasks specifically  requested by  EPA  have  also been
performed.
                                -431-

-------
1.  Unannounced Inspections






     Since August 1986, wells which have been denied permits  and



ordered  shut  down  by  a  certain  date  have  been   inspected




following the  ordered shut  down  date to  determine  if they  are



operating. Additional  wells  for  which  permit applications have



been requested by EPA  but  have  not  been received have  also been



inspected following a specific deadline. In some cases  the wells



are operating when inspected; in many cases they appear operable



but are  not operating  when inspected.  In some  cases they  are



obviously  inoperable  due  to disconnected injection  lines.   In




other cases  the  well has  apparently  been  plugged and  abandoned




because no evidence of a wellhead is present at a site.






     A total of  138  wells have been inspected unannounced since



August 1986.  Of  those  wells,  41  (30*),   were  operating at  the



time of the inspection.   Four wells could  not be located,  either



due  to  plugging  and  abandonment  or  to   incorrect   location



coordinates.  The  majority  of  the  93 wells   which   were   not



operating appeared to be  operable  as  indicated by fresh  paint,




connected injection  lines, and new gauges and  valves, but were




reported to EPA as not operating. The presence  at some  wells  of



automatic timers  in  an "off" cycle when checked, indicates that



these wells  may  be use,  although they were  reported  to EPA  as




not operating.



     Several of  the  wells which were  inspected were  operating




gas  wells  rather than  disposal  wells,   due  to  apparent mis-




identification or filing errors.
                            -432-

-------
2. Witness Plugging and Abandonment Procedures






     KEDA personnel  have  witnessed  P  & A  procedures for  fewer




than one  dozen different  wells,  after  approval by  EPA of  the




proposed procedure.  Former  Class  II wells  and  former  producing




wells and dry holes  are both  required  to be plugged  if  they  are



in the  area  of review of  an  operating  Class  II well,   and have




not been properly plugged.  The approved  plugging and  abandonment




procedure has  generally consisted  of  the  placement  of  3  or 4




cement plugs as follows:




     1) One opposite the perforated zone,




     2) One at the base of the USDW (10,000 mg/1 TDS), to a




        height of at least 100 feet above the USDW,




     3) One at the base of the freshwater zone  (1,000 mg/1  TDS),




        to a height of at least 100 feet above the freshwater



        limit, and




     4) A 50 foot plug at the surface.




The casing has been pulled when possible, and has generally been




perforated at the plugging interval when it could not be pulled.




     In some  cases  the base  of  freshwater and  the  base of  the




USDW are essentially the same,  and one continuous plug  has been




set from 100  feet  below the USDW to  100 feet above  the base  of




freshwater. In some cases additional plugs have  been  required  at




the base of  casing  left in the hole due to insufficient cement




behind  the  casing.  In  other  instances  wells with   multiple
                           -433-

-------
perforated zones  or  badly  deteriorated casing have been  plugged



from  the  base   of  the  perforations   to  the  surface.   The



requirements for  plugging  are currently undergoing modification



by the EPA.






3. Suspected Surface Water and Groundwater Contamination






     Chloride contamination  of  surface water and domestic  water



supply  wells  has  been  reported  in  certain   areas  of  south



Mississippi.  The Water Resources Division of  the  U.S.  Geological



Survey has conducted several studies of the  situation  in recent



years,  (see  the  list of  references), however,  no  conclusions



have been  drawn  in  these  reports  regarding  the  specific  source



of  the  chlorides:  they  could  have originated  from  the  former




storage of  drilling mud and  brine  in unlined pits,  from  direct



discharge  of brine  into  surface water, from disposal of  brine



into Class II  wells lacking mechanical integrity, or  from  leaks



through the  unplugged well bores of abandoned oil and  gas  wells




and exploratory holes.



     At  EPA's  request,  KEDA  field  inspectors  have  collected




conductivity  data from water  supply wells  in  Pike and  Lincoln



Counties;  and  have noted any reports  of water  quality problems,



such  as  cloudy  water in  drinking water  wells  coinciding  with




injection  into nearby  Class  II wells.  The data  collected  is




currently being evaluated  by  EPA's  Region IV  office.
                           -434-

-------
V.  SUMMARY

     Through March  1987,  a total  of  23 %  of the Class  II  injection

wells  in  Mississippi  which  were  pressure  tested  for  mechanical

integrity  had  failed  their  first  test.   However,  the  successful

retesting  of  the majority  of the wells  which failed  indicates  that

many operators  have  a  desire to  operate  their  wells correctly.  By

contrast,  30  *  of  the  unpermitted  Class  II wells  which have  been

inspected  after  being  ordered   shut  down   were   still  operating,

indicating a reluctance on the part of  these  operators  to comply  with

the permitting requirements.

     Pressure  testing  is  expected   to continue  until  all  of  the

authorized  or  permitted  wells  in  the state  have  been  tested,   and

those that fail  are  repaired  or  plugged.  This testing  is expected  to

require  several  more  years  but is necessary  in  order  to protect  the

drinking water resources in the state of Mississippi.

VI. REFERENCES

Gandl,  L.A., 1981, Characterization of  Aquifers Designated as
     Potential Drinking Water Sources in Mississippi; U.S. Geological
     Survey Open-File Report 81-550, 90 p.

Hem, John D., 1970,  Study and Interpretation of the  Chemical
     Characteristics of Natural Water;  U.S. Geological  Survey,
     Water Supply Paper 1473, 383 p.

Kalkhoff, S.J.,  1982, Specific Conductance  and Dissolved  Chloride
     Concentrations of Freshwater Aquifers  and Streams  in Petroleum
     Producing Areas in Mississippi; U.S. Geological  Survey Open-File
     Report 82-353,  33 p.

Kalkhoff, S.J.,  1985, Brine Contamination of Freshwater Aquifers  and
     Streams in  Petroleum Producing Areas in Mississippi;  U.S.
     Geological  Survey Water Resources  Investigation  85-4117,  116 p.

Kalkhoff, S.J.,  1986, Brine Contamination of Shallow Groundwater  and
     Streams in  the Brookhaven Oilfield, Lincoln County,  Mississippi;
     U.S. Geological Survey Water Resources Investigation 86-4087,
     57 p.
                                 -435-

-------
FIGURE 1.MAJOR AREAS OF OIL AND/OR GAS PRODUCTION
     AND NUMBER OF WELLS TESTED IN  MISSISSIPPI
                THROUGH MARCH 1987.
                       -436-

-------
A. TYPICAL CLASS ff WELL; ONE TUBING,
  ONE PACKER.
=
s

MM?
m
s s
"*
^^>-^^
\
{riST'

B. TWO TUBINGS; SIDE BY SIDE,
  TWO PACKERS,  	
C. TWO TUBINGS; ONE INSIDE
  THE OTHER. TWO PACKERS.
D. ONE TUBING WITH TWO SLIDING
  SLEEVES, TWO PACKERS
FIGURE 2. TYPICAL AND UNUSUAL CLASS H WELL COMPLETIONS.
                             -437-

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               WELL INTEGRITY MAINTENANCE USING PUMPABLE SEALANTS




                         R. Clay Cole and Kurt Lindstrom




                              Halliburton Services









ABSTRACT




     Integrity of  Class  II  disposal wells  can be  restored and  maintained  by




applications of a variety of pumpable sealants.




     In this paper many of the diverse causes  for  failure  of  Class II disposal




wells  to  pass state  and  federal  integrity  tests  are  discussed,  as well  as




methods for identifying these causes.   Experience with many well  histories has




shown that, because of  their diverse nature,  not  all of these  problems  can  be




remedied  with a  single  product  or  technique.    Therefore,  thorough  problem




diagnosis  is  emphasized  in  addition  to  a  description  of  the application  of




several sealant systems to overcome the problems.




     Considerations are given  to  overall well conditions, age of the  casing




string, magnitude  of  the failure,  associated well  temperature  and  hydraulic




pressures, and the nature of the fluids against which a seal is required.   Port-




land cement slurries  (used alone,  or  in conjunction with  secondary sealants),




true solution  type sealants  capable  of entering  the formation matrix,  micro-




annuli, or pinholes in pipe are discussed.









INTRODUCTION




     In the oil  and  gas production industry,  wells used to reinject  brine,  to




aid in enhanced oil recovery, and for storage of hydrocarbons are referred to  as




Class II wells.1  2  Environmental considerations require that  these wells meet




certain standards to prevent  leakage  into  ground water aquifer  zones  and/or  to




other adjacent zones.   Complete isolation of the wellbore is required,  and





                                     -438-

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mechanical integrity tests (MIT) are performed to establish the  condition of  the




wells.




     Failure of  MIT may be  caused by a  variety of mechanical  failures in  the




hardware installed to provide protection required.




1.   Corrosion from extended exposure of casing to  fresh water  or  brines.   A




     continuous and competent cement  sheath around  the casing helps prevent  the




     exposure, however if the sheath was not proper when installed or has failed




     from subsequent damage, casing may corrode.  Early completion practices  did




     not provide  cement  all the way  to  the  surface,  so  casing  was  exposed  to




     corrosive fluids for long intervals.




2.   Tubing leaks inside the casing can  cause corrosion from inside out.  Where




     this occurs, the corroded interval may be extensive.




3.   Fractured confining  zones may  allow  fluid migration  even when  the  well




     itself is completed properly.




     Restoration  of well  integrity  is  most commonly  accomplished by squeeze




cementing, a technique  that  is  also used to  stop fluid migration through frac-




tured confining zones behind sound pipe strings.  Externally catalyzed  silicates




(ECSS) were developed specifically to control subsurface brine flow in  producing




or injection wells.  Also,  an  epoxy  based system has been successfully used  to




make a high strength bond between pipe and cement, thus plugging microannuli  and




collar leaks.




     This paper  discusses  the above  methods briefly and  provides an  extensive




bibliography of  references  that  give complete details.   A complete description




and  detailed operating  procedure  is  presented  on a  more  recently   developed




family  of  sealants known  as  internally  catalyzed  silicate  sealants (SS-I.




SS-II).  Since there is little information on this method  to be  found in current




literature, more detail is offered.  Sections on sealant selection and





                                      -439-

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diagnostic methods apply to all sealing methods discussed.









DIAGNOSTIC METHODS




     Forming a good definition  of  the problem is a vital early step in treating




a  damaged disposal well.   The  original  cement  bond  log  might  establish  the




condition  of  the  cement  sheath  and locate  top  of  cement  (TOC).   If  squeeze




cementing has been done, logs conducted after the squeeze are needed.




     Temperature logs may help  locate TOC.  These logs are recordings of incre-




mental temperature changes occurring  while the  logging tool  is lowered into the




well.   From these  records  a  temperature curve  can  be made;  the  curve  may




indicate perforations, casing leaks and fluid channelling.




     Direction and rate of  travel taken by leaked  fluids may  be established by




injecting short half-life radioactive isotopes into fluids being pumped into the




well and  monitoring  their route with a gamma ray  logging tool.   The route and




rate  of  fluid  travel  relative to  the  physical  geometry  of  the  system  may




indicate casing leaks, channels, packer and bridge plug leaks, etc.3




     A  spinner  survey may be used to  determine  the  location of  casing leaks.




Fluid movement turns  a  propeller in  the  tool which directly  measures the fluid




rate flowing past the instrument.1*




     By isolating the hole with packers, the magnitude of the casing leak may be




determined  from  the  injection rate.   A straddle  packer  used   in  precision




perforation breakdown as described by Hushbeck  can be used to isolate intervals




as short as 3 in.5




     Although  the foregoing  tests  may be  expensive  and  time  consuming,  the




information they  provide  is  critical to  selection of the correct sealant and




execution of the treatment on the first try.
                                      -440-

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PORTLAND CEMENTS




     The method most commonly used to repair  casing leaks has been, and is now,




to squeeze portland cement slurries into the spaces and voids around the casing.




When performed  successfully,  a squeeze cement  job  can plug  leaks  by  forming a




permanent,  high-compressive  strength  seal at  a reasonable  cost.  Fluid loss




control, thickening time, and  cement  density are designed  for  each squeeze job




according to downhole conditions .




     Best  results  are usually  achieved by  preceding the  squeeze with  a thin




fluid such as water to open  and clean the zone of interest.  The squeeze  slurry




itself  should have  a sufficient  thickening  time   and  proper  low fluid loss




characteristics to  allow it to  be  pumped all  the  way to  the  repair  area.  If




these properties are  not correctly selected,  (1)  the cement may  dehydrate too




soon and leave  the  pipe  plugged, or  (2) a squeeze  may enter  in the wrong loca-




tion which would prevent slurry from penetrating the intended zone.




     Displacement pressure should be limited to the minimum needed to accomplish




the squeeze  as  excess pressure  can break down a weak formation.   Foam cements




have provided significantly higher success ratios in controlling water zones and




in sealing corroded casings where low fracture gradients exist.7









EXTERNALLY CATALYZED SILICATES




     An externally catalyzed silicate system  (ECSS)  has been developed specifi-




cally to control brine flow in producing or injecting wells.  Generally. ECSS is




applied  to the most  severe  channels behind  pipe  where  brine flow  is   severe




enough  to  dilute conventional  squeeze  cement  slurries.   This system  has been




used extensively in flood operations  to  improve oil/water ratio,  and for  repair




of casing leaks.® ^




     ECSS may consist of two or three fluids, applied  in either two or three





                                      -441-

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stages.   The  process  is designed  so that chemicals  in the  second  stage react




instantly with chemicals  in the first  stage  to yield a plugging  material.   If




this plug is sufficient to  complete  the job,  then the process is two fluid, two




stage.  In the three  stage  process,  portland cement  is pumped  behind the plug.




The following paragraphs describe each stage.




     Stage 1 consists of pumping a special brine  preflush  into  the formation to




cause a  gelling  reaction in  the second  stage.   Although  the  material  used in




Stage 2  will  react with most  formation brines,  use  of the  preflush (Stage 2)




helps achieve the  rapid formation of a plugging  gel when chemicals  of  the two




stages meet.




     In Stage 2,  solids-free,  non-Newtonian,  inorganic silicate fluid intermixes




with the brine after  being  displaced from the tubing to form a gel  which inhi-




bits  flow through  previously  open channels.   This chemical  has a viscosity of




200 cp,  and  can carry  up  to  10  Ib  (4.5 kg)  of   inert  filler  per  gallon.   To




obtain bridging in severe cases, silica sand  and  other special  materials may be




added.




     The  third  stage,  which  is  normally used,  is  a low-water-loss  portland




cement  slurry.   Since  the first  two  stages  drastically  reduce  flow  within




channels, the leading edge  of  the  Stage 3 slurry  is able to  combine with  the




silicate of  Stage 2.   Both stages thicken at  the point of interface.




     Stages  1 and  2  should be  pumped at pressure lower than the  fracture gra-




dient.  By the time Stage  3 enters the  flow channel, a pressure buildup should




occur but the fracture  gradient should  not  be exceeded.   If pressure  does  not




build up, sequential injection of Stage  2 and  3 components are  repeated  until a




five-minute  standing pressure  can be maintained on the perforated interval.9
                                     -442-

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EPOXY-BASED SEALANT




     Persistent collar  leaks and/or  microannuli that  do not  respond to  lower




strength treatments  may occasionally be  repaired  with  epoxy  sealants.   These




high-strength, true solution  sealants bond tenaciously to both pipe and  cement,




and success ratios in treating small  leaks are high.  If  the  leak  to be repaired




is more than  5 bbl  (0.79 m3)/day, inert fillers  such as  silica should be  added




to fill voids and reduce fluid loss.10




     The epoxy  resin is strengthened by  the  addition of a  chemical hardener.




Hardening  of  the mixture  is  accelerated by  high  temperature and  a chemical




accelerator speeds the reaction by (1) reacting along with the hardener compound




to accelerate  its reaction with  resin and (2) reacting  independently with the




epoxy  resin,   which   further  hardens  the  resin.10   Although  this   system  is




successful, it is expensive and usually considered for unique or severe problems.









INTERNALLY CATALYZED SILICATES




                                     General




     A  family  of  internally  catalyzed silicate  sealants (ICSS)  was developed




specifically  to  offer  an  alternative  to portland  cement  for the  purpose  of




squeezing  off  casing  leaks and  re-establishing zone  isolation.   ICSS sealants




offer flexibility of  job design,  competent sealing,  casing protection, and ease




of removal.




     Depending on the level of  silicate content,  these sealants are referred to




as SS-I  (low  level of  silicate content), and  SS-II (high  level  of  silicate).




SS-I is used  to provide a moderate  seal  that  can be  removed  later.  SS-II is




formulated to  enter  the matrix  and  form  a  permanent seal  against moderate to




high pressures.
                                      -443-

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                                  SS-I Sealants




Properties




     SS-I sealants are composed of water  and inorganic silicates routinely used




as soil  stabilization/solidification agents.11   Ungelled SS-I  without fillers




(neat SS-I)  has a viscosity  of  1.2 cp,  enabling it to  penetrate  tight forma-




tions.   The  co-reactant  gel  initiators,  dissolved  in  fresh water,  react  with




silicates, become  part  of  the gel  network, and do not  leach out  with  time.




Resultant gel  is pH  10  to  11 and  resists fluid  penetration  until  broken  up




physically.12




     With a  pH  11  gel surrounding a pipe or inside the  pipe,  corrosion due  to




brines or fresh water  is resisted.   Figure 1 shows results of a 90-day study in




which the corrosion  rate of J-55 grade tubing  surrounded by SS-I  gel was  com-




pared to that of J-55 tubing immersed in tap water.12









Inert fillers




     SS-I properties  are enhanced by addition  of a composite  of  inert fillers




such  as  diatomaceous  earth,  which  is  the  optimum filler  for SS-I,  yielding




slurry density  of  9.2 Ib/gal  (1.1  kg/L).  The  nature  of this  inert  filler  is




such that it allows  some slow fluid loss through the structure of the diatoms




(Fig. 2  shows  structure).   When  establishing   a fluid  seal  against  a porous




formation loss of some fluid  into the  formation  is  desirable,  since that  fluid




also has some gelling qualities.  Conversely, fluid loss must be limited so the




slurry will  not dehydrate.   Qualities of diatomaceous earth inert filler provide




both of these desirable characteristics.




     Another filler  in the  composite  slurry helps keep  the other  fillers  in




suspension so  that  pipe  removal  is  easier.  Settled and  compacted fillers can




prevent  pipe removal.





                                     -444-

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     A  third filler  in the  composite slurry  is a  bridging  agent  that  helps





correct severe  lost  circulation.  In  situations  where there  is  a brine  column




behind  the  pipe and a  9.2  Ib/gal (1.1 kg/L)  slurry  inside  the  pipe,  too much




fluid  loss  could cause  a  continuing  "U-tube  effect", using a  high  volume of




sealant.  The bridging agent allows complete pipe fill-up if  desired.




     All the inert fillers in the composite slurry provide added  strength  to the




gelled product.









Gel Strength and Sealing




     The texture of SS-I gel  is  best  described as friable (easily crumbled) yet




rigid.  When gelled in  a container,  the gel retains  the  shape of the container




when  removed,  thus  the  term  "rigid  gel" is used.   The unsupported  gel  can be




broken up by very light physical disturbances,  after  which it does not congeal.




Broken pieces of the gel can act as check valves across pin holes and split pipe




openings.




     SS~I gel  strength  is  measured by using a  penetrometer  to gauge resistance




to penetration  by a  sharply pointed cone weighing  200 gm (Fig.  3).   Neat SS-I




gel  allowed 23.5 mm  penetration; an  SS-I slurry  containing  inert  fillers as




described above allowed 17.4 mm penetration, or 25% improvement in strength.




     Two tests  were  conducted to  determine the level  of  hydraulic  pressure at




which SS-I gels could provide an adequate seal.12




1.   Two 10 in. (254.0 mm)  x 2  in.  (50.8  mm) stainless  steel reservoirs were




     plumbed together to allow  series  flow in  the vertical  direction (Fig. 4).




     The bottom portion of the lower reservoir  contained approximately 200 grams




     of No.  70-170  U.S. sieve  sand  to provide a porous matrix  media  having a




     permeability of  around  4  darcies.   This  reservoir  was  filled  with  fresh




     water containing fluoricein dye.




                                     -445-

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     Once  the SS-I had  gelled,  a pressure  test  was performed on the  system by




     applying pressure  on the  fluorescein dye water in 50 psi (344.7 kPa)  incre-




     ments  up to 300 psi  (2068.4  kPa),  with flow rates measured at  each  incre-




     ment.   The  pressure test  data are  shown in Table 1.   Fluid flow was checked




     every  1/2  hour.   No dye flow was detected  and no  damage  to  the gel  was




     observed during  the test  period.









2.    A section of  2  3/8 in.  (60.325 mm)  tubing was placed inside  a  4^ in.  (114.3




     mm)  casing  to simulate placement of  SS-I sealant in the annulus  (Fig.  5).




     Twelve 3/4  in.  (19.05 mm) holes were drilled on a 3 in.  (76.2  mm)  spacing




     in a  12 in.









     (304.8 mm)  section of the  casing  to simulate casing damage. Three sets  of




     four holes  were  oriented  90°  apart  around the casing. The  holes  were  packed




     with  resin  consolidated  40-60 mesh  Ottawa sand  to provide  a  permeable




     medium to simulate  the leakage of fluid  from  the  hole  into the  formation




     matrix.   The average  permeability of  the  consolidated  40-60  mesh  Ottawa




     sand was about  40  darcies.   Enough SS-I solution was placed in  the annular




     space  to cover the  entire 12  in.  (304.8 mm)  section.  The  annulus  space  was




     then  filled with  dyed water.  After the SS-I  was squeezed with 100  psi




     (689.5  kPa) for an hour, the  test was  shut-in to allow the  SS-I gel  to




     form.   After 48 hours  of  shut-in,  the pressure  test  was  performed  by  slowly




     increasing  the  pressure from  0 to  500 psi  (0-3447.4 kPa) with  nitrogen on




     top  of water.   The  leakoff  rate  was measured  at each pressure  increment.




     Results  are shown  in Data Table  2.  This test presented an extreme  condi-




     tion,  wherein  only enough  SS-II was used to  just  cover the target  leaks.




     It was  concluded that  even with 12  high permeability holes present in a  12






                                    -446-

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     in.  long  (304.8  mm)  section  of pipe  that they  can be  sealed  off  to a




     sufficient degree to  pass an  MIT.   Only 1.0 psi  (6.9 kPa)  was lost in 30




     minutes at  500 psi (3447.4  kPa) test pressure.   Usually, several  hundred




     feet of SS-I  is  run above the shallowest known point of leakage to  be sure




     complete coverage is attained.









Allowance for Pipe Retrieval




     The  friable  consistency  of SS-I  allows  partial or  complete  filling of an




annular  space  with sealant, leaving  it  there, and  subsequent  retrieval of the




workstring.  If  cement is used,  it is necessary  to either  reverse out liquid




cement  after a squeeze pressure was  attained, or allow  the  cement to attain a




soft  set and drill out  what   remains  in  the  casing.   Drilling out cement can




cause severe damage to casing strings and liners.




     From  laboratory  tests,  it was soon  recognized  that SS-I type gels might




have  the properties  to allow a permanent annulus  application that would permit




easy inexpensive removal.  It has been determined that tubing, with  or without a




packer,  can be pulled through SS-I gel.  Eight  full-scale tests were conducted




using a  test rig (Fig. 6) to determine the pull required  to lift 180 ft  (54.9 m)




of tubing  string  through  a casing filled with SS-I  gels, both neat and  slurry.




In four of the  eight tests  an unseated  retrievable type packer  of  the  size




corresponding to the  casing  size  used was attached  to  the bottom of the tubing




string.   The various  pipe specifications used are  given  in  Table 3 along with




the pull data from all eight tests.




     Tests were conducted by preparing SS-I formulations  under  field conditions,




then pumping the liquid sealant into  the annulus between  the  pipes being  used in




each test.  The SS-I was allowed  to gel and  age  overnight.  Samples of the SS-I




material were saved to verify that a  gel had  formed  in each case,  and that its





                                      -447-

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strength was normal.   Then,  the tubing was pulled  without rotation, reciproca-




tion, or fluid circulation to break the initial bond.









Job Design and Performance




     SS-I Jobs  are designed  to place sealant  over the entire  corroded casing




zone (Fig 7).  Although placing sealant just to cover the leak has been shown to




seal sufficiently  to  withstand  500  psi  (3447.4  kPa),  it is  advisable  for two




reasons to place  at  least 300  to  500 ft (91.4 m - 152.4 m)  of  SS-I above the




shallowest known point of corroded casing.




1.   Inaccuracies  in  determining the location  of the leak  may  lead  to  use of




     insufficient  volume.   If  an  interval  of  several  hundred feet  of  leaking




     exists,  some  small  section may  be  overlooked.   Some sections  of the leak




     may be  temporarily  plugged at the  time  of  testing,  also resulting in the




     use of insufficient sealant.




2.   If the  leaks  are fairly large,  or  the temporarily  plugged  sections of the




     leak become open, more  SS-I is  lost to  the voids  outside the  casing than




     anticipated.  This  could  result in  some of  the  upper  holes  being left




     untreated.




     If the precise location  of the leaks is not known,  it  is best  to run SS-I




up to where the bottom of the surface casing is located, or to surface.




     Two typical placement procedures are used.  One is to  preflush with fresh




water or light  sodium or potassium chloride brines, then  pump the sealant into




the annulus with the production packer seated.  In effect this can be considered




a "bullhead  squeeze"  technique.  Although many good results  have been achieved




with this procedure,  it  can  allow sealant  contamination.  With  this procedure,




pump rates are  restricted by the  leak  size,  not the annulus  size.   Therefore,




with very low placement rates SS-I could fall through the brine in the annulus





                                      -448-

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and become contaminated, resulting in no gel and no  seal.




     A better  approach is to unseat  the packer, pump  a preflush and then  spot




(pump rapidly with circulation to get  the  SS-I in the proper position)  the  SS-I




down  to  the packer.   The packer is  then  set.   The required  pressure  is  then




applied to the annulus to accomplish a squeeze.  When a  squeeze  is achieved, the




well  is  shut-in  for a minimum of  24 hours after which the treated wellbore is




ready  to be  pressure tested.   It  is recommended  that  any  pressure  test be




carried  on  in a  step-wise fashion  so that if  a premature  failure occurs, at




least the extent of improvement will be known.









Example  Treatment  1:   The  Oklahoma  Corporation Commission  (OCC)  required  a




customer  in  northeastern Oklahoma to  pressure test  the annulus of a  disposal




well.  The  annulus between 7  5/8  in.  (193.7  mm)  casing and  5% in. (139.7 mm)




casing would take fluid at 3 bbl/min  (0.48 bbl/min)  at  150 psi  (1034.2  kPa).  A




retrievable  packer  was  set  inside the  5^ in.  (139.7  mm) casing  and  pressure




applied to the 2  7/8  in.  (73.0 mm)  - 5^ in. (139.7  mm)  annulus.  It held pres-




sure with no leakage.  At  the  same  time  fluid  was flowing to surface from the 7




5/8 in.  (193.7 mm)  - 5% in.  (139.7  mm)  annulus.  This  indicated a leak inside




the 7  5/8 in.  (193.7 mm) casing.  A  3000 gallon batch  of  SS-I was prepared to




repair this leak.









Time  (Minutes)  	__	Operation	




     0000       SS-I Solution mixed




     0020       Solid fillers added to the neat SS-I




     0065       Began to pump the 71.5 bbl  (11.4 m3) of  composite SS-I down




                the 7 5/8 in. (193.7 mm) -  5^  in. (139.7 mm) annulus at  2




                bbl/min  (0.32 m3/min) at 0.0 psi





                                      -449-

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     0085       Pump rate slowed to 1 bbl/min (0.16 m3/min) [52 bbl (8.3 m3)




                pumped]




     0095       Stopped pumping (annulus dead)




     0097       Resumed pumping SS-I at less than 1 bbl/min (0.16 m3/min) [61




                bbl (9.7 m3)] pumped)




     0115       Stopped to reprime pump




     0120       Rate slowed to 1/4 bbl/min (.04 m3/min) as pressure began to




                build




     0125       All 71.5 bbl (11.4 m3) of SS-I in place in the annulus; Pressure




                reached 300 psi (2068.4 kPa)




     0130       Well shut in









Results:   at 68 hours after the well was shut in, it  held 1200 psi (8273.7  kPa)




for  10 minutes.   In the  final  pressure test the  annulus held 800 psi  (5515.8




kPa) for  30  minutes,  and passed  the OCC test.   Estimated savings in terms  of




manpower, rig time, down  time  on  the well,  and the cost  difference between the




SS-I job  and other means of repairing the leak was about $25,000.









Example Treatment  2:   In Kansas,  a disposal well  completed  into the Arbuckle




formation had developed  a casing  leak.   Initially, when  300 psi (2068.4  kPa)




pressure  was applied to the annulus, bleedoff to  75 psi (517.1 kPa) occurred  in




10 minutes.









Step No.        	Operation	




     1           Packer  bypass opened




     2           70 bbl  (11.1  m3)  of fresh water  pumped down the annulus




     3           17 1/2  bbl (2.8 m3) of a SS-I type treatment pumped down  the
                                     -450-

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                annulus and displaced to packer




     4          Packer bypass closed




     5          Tubing volume of light sodium chloride brine pumped down the




                tubing to displace any SS-I below the packer




     6          Squeeze pressure applied to the annulus




     7          Well shut in for 48 hours









Results:  the  well  was pressure tested  in three steps.   In  the final pressure




buildup  the annulus  held  285  psi  (1965.0  kPa)   for  30  minutes.    The  state




accepted the test and, one year later, the well is being used for disposal.









     Table  4 lists  results  of  mechanical integrity tests  performed  on 12 wells




that have received  SS-I  treatments to repair casing  leaks.   All of these wells




were given  approval by the OCC and were  put  into service as  injector or brine




disposal wells shortly thereafter.









                                 SS-II Sealants




Properties




     SS-II  is  placed as  a low viscosity  (1.7 cp)  solution which  contains  no




undissolved  solids, although fillers  may be  added  if  desired.   The internal




catalyst allows a controllable pump time before  the system sets to a stiff gel.




The material does not  have  significant  strength in its neat form [15 psi  (103.4




kPa)].  Its virtue  lies in the matrix sealing quality of the system.8  13




     In laboratory  extrusion tests, SS-II  gel  was placed in matrices of various




types of unconsolidated sand packs.  In  40-60 U.S.  Mesh  sand (40 to 50 Darcys),




gelled SS-II withstood 1500 psi (10342.1 kPa) before the seal failed.  In  70-170




U.S. Mesh sand (9 Darcys) 2000 psi (13789.6 kPa) broke the seal.  Sand packs
                                      -451-

-------
were inside  1  in.  (25.4 mm)  ID by 3 in.  (76.2 mm)  long pipes,  at room tempera-




ture. 11




     Penetrometer tests,  as  described earlier, showed  16.6  mm  average penetra-




tion for neat SS-II gels, showing a tougher structure than SS-I gels.









Applications




     SS-II gel sealant provides higher strength and longer pump times  (up to 600




minutes)  than SS-I  gels.8  n  13   SS-II is  especially  suited  for  repair  of




pinhole leaks  and the  long  placement times  help achieve  entry  of  SS-II  into




formation pore throats  and microannuli.   The  key  to casing repair appears to be




in the ability of  the operator to place  sealant  outside  the casing, regardless




of the volume of sealant inside the casing.




     SS-II may be used  alone or as part  of a  combination of ICSS sealant/cement




squeeze.  Primary use of SS-II material  has  been to help prevent  bottom water




coning and help to seal  selected  zones.   Qualities  of SS-II  allow radial injec-




tion deep into the formation.  A cement tail-in provides the following synergis-




tic benefits on the treatment.8 ^ 13




1.   Cement provides high compressive strength near the wellbore where differen-




     tial pressure is greatest.




2.   Cement give a positive indication that proper displacement has occurred.




3.   SS-II reacts  with  cement  to flash  set  near the  wellbore and  the  cement




     begins hydration almost immediately.




     After setting, SS-II  forms a firm,  permanent gel  inert to most chemicals.




It may be used  to  help  form a  barrier  to lower brine  zones or to  help prevent




acid from subsequent treatments from contacting water zones below the treatment.




     Application steps  for  SS-II  may be  the  same as for  SS-I,  or  the optional




procedure presented below may be used.







                                     -452-

-------
  Step No.      	 Procedure	




     1          Locate damaged area




     2          Pull tubing and packer




     3          Perforate if needed to gain access to channel or leak area




     4          Set a bridge plug below damage




     5          Set a retrievable packer above zone of repair




     6          Pump a fresh water preflush, followed by SS-II, spacer, and




                cement (optional)




     7          Squeeze to  displace SS-II  into  formation or  annulus;  maintain




                slight pressure  on SS-II as  it  sets; avoid rapid  injection  of




                SS-II at this point




     8          Shut well in to allow strength to build




     9          Wash out SS-II left inside casing




    10          Retrieve packer and bridge plug




    11          Test seal









SEALANT SELECTION




     Selection of the proper sealant  for  the  application requires consideration




of  several factors.   Shown below in  tabular  form are  descriptions of  some




commonly  found  conditions  and  a recommended sealing  method  for that condition.




These recommendations can not be  considered "ironclad"  since there may be other




variables that influence the selection.
                                     -453-

-------
                                    CEMENT BOND LOG INDICATIONS
Magnitude of Leak
Flow rate 5 bbl/
min at low pres-
sure. Most likely
well will not
stand full
above packer.
Medium flow
behind pipe.
(1 to 3 bbl/min)
Leak less than
1.0 bbl/min
  Competent cement
 with good bond to
 pipe and formation
Evidence of frac-
tured formation be-
hind cement. Per-
forate to intersect
channel. Use ECSS
with low water loss
cement slurry as
tail-in. Repeat
Stages 2 and 3 un-
til well holds
pressure.

     Method 1	
If not accessible,
perforate to inter-
sect, try ECSS
squeeze with re-
peated steps of
brine and ECSS.

	Method 2	
If interval is less
than 50 ft, inject
neat SS-II formula-
ted to gel as it is
injected.  If in-
terval is over 50
ft, tail-in SS-II
slurry.

	Method 1	
Squeeze with neat
SS-II followed by
SS-II slurry.  Re-
move excess from
casing.

	Method 2	
Squeeze neat SS-I
followed by SS-I
slurry.  Leave in
casing.

     Method 3	
If well has high
pressure, or if
well is Class I,
consider using
epoxy based sealant.
Some cement present
 but poor bond to
pipe and formation
Try ECSS squeeze
first. Perforate if
necessary to inter-
sect channel. Re-
peat Stages 2 and 3
until well holds
pressure.
      Method  1
Perforate to inter-
sect flow. Squeeze
with ECSS and
cement slurry.

     Method 2	
Treat with SS-I or
SS-II slurry.

Method 3	
Use low pressure
cement squeeze if
drillout is no
problem.
	Method 1	
Squeeze with neat
SS-II followed by
SS-II slurry.  Re-
move excess from
casing.

     Method 2
Squeeze neat SS-I
followed by SS-I
slurry.  Leave in
casing.
 Very poor or no
 cement present
   behind pipe	
Apply combination
of ECSS and ce-
ment. May require
repeated applica-
tions of both.
Consider adding
bridging agents
to ECSS and cement
slurry.
	Method 1
Perforate to
intersect flow.
Apply ECSS squeeze,
repeating Stages 2
and 3.
     Method 2	
Apply Hesitation
squeeze using Port-
land cement alone.
     Method 1
Apply ECSS squeeze
with one or more
cement stages.

	Method 2	
Apply large volume
squeeze with SS-I
or SS-II slurry.
Consider preflush-
ing with calcium
brine.
                                     -454-

-------
Pinhole leak,            Method  1	  Consider perfor-           Method 1	
well stands         Use neat SS-I or     ation  to open  ac-    Perforate  to inter-
full but will       neat SS-II.          cess to fractures    sect  void  area.  Run
not hold                                 an
-------
     and Gas Conservation Division," 1986 Edition.




3.    Murphey, Bill,  "Squeeze Cementing  Requires Careful  Execution  for  Proper




     Remedial Work" Presented to  SPE Squeeze Cementing  Symposium,  Dallas,  Tx.,




     1985.




4.    University  of Texas  at Austin, "A  Dictionary  of Petroleum  Terms",  Second




     Edition, 1979.




5.    Hushbeck, D.F.,  "Precision  Perforation Breakdown for More Effective Simula-




     tion   Jobs,"   Presented  to   the   International   Meeting  on   Petroleum




     Engineering,  March 17-20, Beijing, China.




6.    Smith,  Dwight,  "Cementing"  SPE Monograph Series, Volume 4.




7.    Bour,   D.B.,  Creel,  P.G.,  "Foam Cement  for Low-Pressure  Squeeze  Applica-




     tions," presented at the 1987 Southwestern Petroleum Short Course,  Lubbock,




     Tx, April  22-23,  1987.




8.    Cole,  R. Clay,  Mody,  Bharat,  Pace,  James,  OE81 SPE10396.1  "Water Control




     For Enhanced  Oil Recovery",  Presented to  the  Offshore  Europe  Technology




     Conference,  Aberdeen,  Scotland, 1981.




9.    Smith,   C.W.;   Pugh,   T.D.;   Mody.  B.:  "A  Special  Sealant  Process  for




     Subsurface  Water",  Presented  at  the  Southwest  Petroleum  Short  Course,




     Lubbock, Tx.,  Aug.,  1978.




10.   Cole,  Robert C. ,  SPE  71874,  "Epoxy Sealant  for Combatting Well  Corrosion"




     Presented to  the International Symposium on Oilfield and Geothermal Chemis-




     try, Houston,  Tx., January,  1979.




11.   Dalrymple,  Dwyann; Sutton,  David;  Creel,  Prentice:  "Conformance  Control in




     Oil Recovery",  Presented at the Southwest  Petroleum Short Course,  Lubbock,




     Tx., April,  1985.




12.   Cole,  R. Clay,  Dalrymple, D.,  McDuff,  C.H.,  Jones,  Mark, "Chemical Process




     Seals  Leaks  in  Injection Wells", Presented at the Southwest Petroleum Short
                                         -456-

-------
     Course,  Lubbock, Tx, April, 1987-
13.   Koch,  R.R.,  Mclaughlin,  H.C.,  "Field  Performance of  New  Technique for
     Control  of Water Production or  Injection in Oil Recovery," paper SPE  2847,
     presented at  SPE  Improved Recovery  Techniques  meeting,  Fort  Worth, Tx,
     March 1970.
        Before Treatment
        During Treatment
        After Treatment
                                       Table 1
                                 SS-I Pressure Test
Fluid Loss
in 30 min
(cc)

107.0
1.2
4.0
16.0
19.0
20.5
21.0
21.0
Flow Rate
Through Sand
(cc/min)
960.0
3.56
0.04
0.1333
0.5333
0.6333
0.6833
0.7000
0.7000
Pressure
 (psi)

    10
    10
    50
   100
   150
   200
   250
   300
                                          -457-

-------
                                       Table 2
                                  SS-I Sealing Test
Holes per foot = 12
Pack sand = Consolidated Ottawa 40-60 mesh sand
SS-I Volume = 3 liters (13 in. - 14 in. from bottom)
Temperature = 75°F

Before Treatment

Flow Pressure
(psi)
2.5
2.5
4.5
4.5

Flow During Treatment

Squeeze Pressure
(psi)
10
20
30
40
50
60
70
80
90
100

Flow Rate
(cc/min)
4500
4420
5240
5220



Flow Rate
(cc/min)
0
0
0
0
0
0
0.02
0.02
0.02
0.0366
Leak Off
Rate
(cc/min/psi)
1800
1768
1164
1160
Avg. = 1473

Leak Off
Rate
(cc/min/psi)
0
0
0
0
0
0
0.0003
0.0003
0.0002
0.0004
                                          -458-

-------
After Treatment
            Test
          Pressure
            (psi)
             100
             200
             300
             400
             500
                                   Table 2 (Con't)
                                  SS-I Sealing Test
  Flow
  Rate
(cc/min)
  0.56
  1.10
  2.10
   2.9
  1.42
  Leak Off
    Rate
(cc/min/psi)
   0.0056
   0.0055
   0.0070
   0.0073
   0.0028
 Leak Off
 Pressure
Per 30 Min
   (psi)
   1 psi
                                       Table 3
     Pull test data obtained from full scale testing using  180 feet of tubing inside
casing.
                 Pull Test Data for SS-I Neat Formulations  (No Filler)
Test
No.
1
3
5
7

Test
No.
2
4
6
8
Casing Size
(in.)
7.0
7.0
7.0
4.5
Pull Test Data
Casing Size
(in.)
7.0
7.0
7.0
4.5
Tubing
(in.)
4.50
2.875
2.875
2.875
for SS-I Slurry
Tubing
(in.)
4.50
2.875
2.875
2.875

Packer
no
no
yes
yes
Formulations

Packer
no
no
yes
yes
Final Pull
lb/ft2
19.47
21.7
34.37
43.72

Final Pull
lb/ft2
28.42
40.40
57.00
56.63
                                         -459-

-------
             Table 4
Mechanical Integrity Test Results


Location
Kansas
Oklahoma
Oklahoma
Oklahoma
Oklahoma
Oklahoma
Kansas
Kansas
Oklahoma
Oklahoma
Oklahoma
Oklahoma

Depth
(ft)
1,539
1,290
712
2,205
2,200
2,800
2,370
2,717
1,270
2,600
3,375
4,000
Treatment
Volume
(gal)
1,000
600
500
2,000
1,500
3,000
500
1,000
800
250
1,000
1,000
Required
Test Pressure
(psi)
300
200
200
200
200
800
300
300
1,000
250
300
300
Achieved
Test Pressure
(psi)
300
200
100
300
200
880
300
300
1,000
350
300
300
               -460-

-------
    0.1


g*  0.04

ff
   0.01
  0.001
 0.0001
                          Fig. 1

          CORROSION OF J-55 CASING SAMPLES


          LIQUIDS IN WHICH THE J-55 CASING WAS TESTED
            m TAP WATER       • SS-I SLURRY
                         DATA FOR 75 DEGREE F EXPOSURE
              20
40       60

 TIME (days)
80
100
 The maximum acceptable corrosion rate is 0.04 Ib/sq ft.
 This occurred with water after 60 days exposure.
                            -461-

-------
                                      FIGURE 2

1000X Photomicrograph showing the SS-I filler structure through which some very
limited fluid loss into adjacent formations is achieved.
                                          -462-

-------
                                      FIGURE  3

                         A Precision  Scientific Penetrometer

This instrument is used  to determine  the relative strength of SS-I gels by
measuring the distance of penetration attained by the cone point into the gel
structure.   ASTM (D-217)  test  procedures and  specifications were used in these
determinations.
                                    Y./
                                         -463-

-------
                        Fig. 4
Sealing test 1 apparatus used to evaluate SS-I gels
                          Gauge
                                   N, Inlet
                       Water Reservoir
                       SS-I Gel Inside
                       a 10" x 2" Reservoir
                       70-170 U.S. Mesh Sand
                       200 gpm
                          -464-

-------
                          .5
                    Process To Seal Leak
                    injection Well
                         IP
N, Inlet
             Water
             Tank
  Reservoir
                                  Pressure Bleed Off
                                  Valve
                                  4Vz" Casing

                                  23/a" Tubing
Dyed Water
   SS-I Gel
                                 3/4" Pipe Nipples
                                 Packed with Consolidated
                                 40-60 Mesh Sand
                                        To Drain
                         -465-

-------
            Fig. 6
        SS-I Service
Pull Test Well Configuration


/si




V\V\V\>yS




fch
•^

Casing
QQ_I in 1Qn' nt anniilne

rioai uoiiar on ena OT luoing
or Retrievable Type Packer
— - Cap on end of casing
            •Cemented Wellbore in Test Well
                 -466-

-------
                        .7
         SS-S Job Placeman! Schematic
    Tubing
Holes in Casing
    Packer
                                Casing Damage Area
                      -467-

-------
                MEASURING BEHIND CASING WATER FLOW




                                 by



                          T. M. Williams



              Texaco,  Inc., E & P Technology Division



        Box 425, 5901 S. Rice Avenue, Bellaire, Texas 77401




ABSTRACT



     A common problem encountered in water injection operations is



locating and stopping undesired water channeling.  The Texaco



E & P Technology Division has developed a Behind Casing Water Flow



(BCWF)  measurement system to measure vertical water flow in or



behind multiple casings.  This nuclear logging system can measure:



          •  the direction of flow



          •  the linear flow velocity



          •  the volume flow rate



          •  the radial distance of the flow from the sonde.



     The system uses a neutron generator tube to provide a source



of high energy neutrons to activate oxygen in the flowing water.



The resulting high energy gamma rays are detected with two crystal



detectors.  By using the counts in different energy ranges in the



two detectors, the system computer can calculate the water flow



velocity, volume flow rate, and radial distance from the flow to



the sonde.  Velocities of between 0.75 and 10 in/sec (19 and 254



mm/sec) can be measured.  This 3-5/8 inch (92 mm) diameter logging



sonde is reversible so either upward or downward flowing water can



be detected.  This logging system has been used in several Texaco



fields and has proved its value in detecting undesired water flow.




                               -468-

-------
INTRODUCTION
     A common problem encountered in production and water  injection
operations is locating and stopping undesired water channeling.
The Texaco E & P Technology Division has developed a Behind Casing
Water Flow (BCWF) measurement system to measure vertical water flow
in or behind multiple casings.  This nuclear logging technique can
measure:
         •  the direction of flow
         «  the linear flow velocity
         •  the volume flow rate
         •  the radial distance of the flow from the sonde.
PRINCIPT.K OF BCWF LOG
     The BCWF log is based on a nuclear activation technique in
which flowing water is irradiated with high energy (14 MeV)
neutrons emitted by a neutron generator within the logging sonde.
These neutrons interact with the oxygen nuclei in the water to
produce the radioactive isotope nitrogen-16 through the
016(n,p)N16 reaction.  Nitrogen-16 decays  exponentially in  time
with a halflife of 7.13 seconds, emitting 6.13 and 7.12 MeV gamma
radiation.  An oxygen activation gamma ray spectrum is shown in
Figure 1.
     The characteristic activation gamma rays are identified in
this plot of gamma ray intensity per energy versus gamma ray
energy.  The 2.615 MeV thorium peak, which is used for energy
calibration, is also marked.  The water flow parameters of interest
are computed from the energy and intensity response of two gamma
ray detectors mounted within the logging  sonde.
                               -469-

-------
     Figure 2 shows schematically a two-detector BCWF sonde in a
well bore where water channeling occurs within the cement annulus
behind the well casing.  The channeling water is activated as it
flows past the neutron source.  The gamma rays from the activated
flowing water are first measured when the water passes the first
detector and then again when it passes the second detector.  During
its travel from detector 1 to detector 2, the gamma intensity
decays by an amount determined solely by the travel time; that is,
by the distance between detectors and the linear velocity of the
water.  Consequently, the ratio of the detector 1 to detector 2
count rates is an exponential function of the water velocity only.
The linear water velocity is determined from this function
regardless of the radial position of the water channel from the
BCWF sonde.  The direction of the water flow to be measured is
determined by the relative position of the neutron generator and
detectors.  That is, so that flow can be measured in both
directions, the sonde has been made reversible.
    Figure 3 graphically shows the laboratory apparatus used to
calibrate a BCWF sonde.  Water of various metered rates can be
pumped through different PVC pipes simulating flow channels.  The
PVC pipes are positioned at various radial distances from the sonde
and one or several casings can be inserted between the pipes and
sonde.
    Figure 4 shows the linear velocity calibration results for a
BCWF sonde containing two 2-inch (51mm) diameter x 6-inch (152mm)
long Nal(Tl) detectors spaced 18 inches (457mm) apart.  As
predicted, the logarithm of the ratio of the detector count rates
                                -470-

-------
is a linear function of I/velocity, and velocity is given by:
      velocity = A^/ClnfcJ/cJ) - AQ]                          (1)
where
     AO and A^ are calibration constants,
     C? = net counts in detector 1 from 3.7 to 7.2 MeV, and
     G£ = net counts in detector 2 from 3.7 to 7.2 MeV.
For this detector spacing, linear velocities of 0.75 to 10 in/sec
(19 to 254 mm/sec) can be measured with reasonable accuracy.
    The material between the water channel and the detectors
degrades the primary gamma ray energy; that is, the number of
primary (6.13 and 7-12 MeV) gamma rays is reduced and the number of
low energy gamma rays is increased.  This effect is used to
determine the radial distance from the sonde to the flow.  The
                                                 H
ratio of:  (1) the counts in the energy window (C?) from 4.9 to 7.2
MeV, to (2) the counts in the energy window (C,) from 3.25 to 4.0
MeV, is related to the total number of electrons per unit area
between the water channel and detector 1.  The relation for a
detector spaced about 40 inches  (1 m) from the source is given by
where aQ, a^, and a2 are calibration constants and pem is the
total number of electrons per unit area between the  sonde and  flow
channel .
     The electron density for different materials is known.  Thus
with the borehole fluid, casing, and cement information, the radius
from the sonde to the water flow can be calculated from /9em.
     Theory suggests and experiments have shown that the gamma
ray activity divided by the volume flow rate is a function  of:
                               -471-

-------
(1)  water velocity, (2)  the radial distance of flow channel to the
sonde,  (3)  the type and amount of material between the flow and
sonde,  and (4) the output of the neutron tube.
     Data analysis reveals that the logarithm of gamma count rate
per unit volume flow rate can be expressed by a second order
polynomial in ln(v) as given in equation 3.
where
      ln[Cn/qw] = b0(R,pem)  + b1ln(v) + b2[ln(v)]2           (3)
      c" = the net detector 1 count rate from 3.25 to 7.2 MeV,
      gw = the water volume flow rate,
      v  = the linear water velocity,
      bO = C0 + C1R + C2R2 + C3'em'  and
      b,, b-/ CQ, c,, c-, and c- are calibration constants.
     This relationship is demonstrated graphically in Figure 5,
where the detector 1 net count rate/water volume flow rate is
plotted versus linear velocity for various radii of the flow
channel to the sonde and for various casing sizes and combinations.
     The volume flow rate can be determined from this plot
regardless of the flow channel cross-sectional area, which is not
accessible to measurement.  Velocity and gamma ray count rate are
measured by the BCWF sonde; then, knowing radial distance and type
of intervening material, the volume rate can be obtained as shown
in Figure 5.
     In short, the water velocity and volume flow rates can be
determined from the gamma ray spectra measured by the BCWF sonde
without knowledge of the location and cross-sectional area of the
flow channel and the intervening material.
                               -472-

-------
     Additional information on the theory of operation of this
logging system may be found on page 121 of the January 1979 issue
of the Journal of Petroleum Technology.
FIELD TESTS
     Field tests with the BCWF system have been successfully
performed in several wells, including the four in Texas chosen as
examples for this presentation.
     Two (No. 123 and 124) were logged in June 1985 to determine
the source of the salt water channeling behind casing to the
surface.  These wells had been recently drilled to about 2000 ft
(610 m).  5-1/2 inch, 17 Ib. (140 mm, 25.3 kg/m) production casings
were set to TD and 13-3/8 inch, 72 Ib. (340 mm, 107 kg/m) surface
casings were set to 40 ft  (12 m).  Both surface and production
casings were cemented with cement circulated to the surface.
     Prior to the BCWF water flow measurements, a long spaced
neutron-gamma ray log or a natural gamma log was run in each well
to select the depths for the BCWF measurements and to correlate
BCWF depths with those of available commercial logs.
Well No. 123
     A  cement-bond/gamma ray/CCL log and a temperature log were
available on Well No. 123.  The temperature log indicated a
potential source of the salt water channeling at about 750 feet
(229 m).  The BCWF log was run to confirm the temperature log
results and to locate any additional sources of salt water
channeling.  Stationary flow measurements, each of 15 minute
duration, were made opposite shales at 12 locations.  These 12 were
between 13 and 900 feet (4 and 275 m) and were above formations
                                -473-

-------
which could contribute and/or be the source of the salt water
breaking out at the surface.  The results are given in Table I.
     Based on a preliminary wellsite interpretation, the casing was
perforated below 470 feet  (143 m) and the well was squeezed with
100 sacks of cement, which stopped the breakout of salt water at
the surface.
     The BCWF log also revealed what appeared to be flow from a
zone near 700 feet  (213 m) to a zone near 600 feet (183 m).  This
was reported to the field for corrective action.
Well No. 124
     Well No. 124 was logged with the BCWF log about 24 hours after
casing was set.  The well was about 600 feet (183 m) east  of No.
123 and it was suspected that the source of the channeling salt
water was at about the same depth interval as in well 123.
Consequently, stationary flow measurements of 15 minute duration
each were made at 12 locations opposite shales and above formations
which could contribute to the salt water breaking out at the
surface.  The results of the log is given in Table II.
     Based on a wellsite interpretation, the casing was perforated
and a cement squeeze made.  These measures stopped the water
breakout at the surface.
Well Nos. 3521 and  5334
     Tests were also performed in two other Texas wells in
September 1985.  This field had a history of casing problems
between 3200 and 4200 feet  (973 and 1281 m).  These two wells were
logged primarily to determine if behind casing water flow  was a
cause of casing erosion/corrosion in this field.  A second reason
                               -474-

-------
for running the BCWF log in these wells was to determine if
cementing of the casing in the problem zone had stopped the
suspected water flow.
     Well No. 5334 produced 20 BOPD and 22 BWPD before the pump and
tubing were pulled for logging operations.  This well had 7-5/8
inch (194 mm) casing set to 3166 feet  (965 m) and cemented to the
surface.  The 5-1/2 inch, 15-1/2 Ib.  (140 mm, 23 kg/m) production
casing was set to 7949 feet (2423 m) and cemented.  A temperature
survey indicated the top of the cement was at 5390  feet  (1643 m).
Stationary measurements were made at nine locations between  4485
and 3250 feet  (1367 and 990 m).  The measurements at 4485 and 4040
feet (1367 and 1231 m) indicated no water flow.  Each station
between 3726 and 3250 feet  (1136 and 990 m) indicated an upward
water flow behind the casing of approximately 4 BWPD.
     Well No. 3521 was shut in because it produced  only water.  The
well had 8-5/8 inch  (219 mm) intermediate casing set to 3287 feet
(1002 m) and cement circulated to the surface.  The 5-1/2 inch,
15-1/2 Ib. (140 mm, 23 kg/m) production casing was  set to 7300 feet
(2225 m) and cemented.  A temperature log indicated the top  of the
cement was at 2650 feet  (808 m).  Logging runs to measure both up
and down flow were made at ten locations between 3020 and 4675 feet
(920 and 1425 m).  No water movement was detected.  This indicates
that cementing the problem interval did stop the water flow  behind
the casing.
PLANNED DEVELOPMENT
     This logging technique has been effective in locating behind
casing water flow in many locations.  We are currently improving
                                -475-

-------
the electronics to double the data acquisition rate.  This will
reduce the time needed at each station to measure the water flow.
     We are currently studying the feasibility of constructing a
1-11/16 inch (43 mm) diameter model of the BCWF sonde.  This small
diameter would increase the number of wells in which the BCWF
logging system could be effectively used.  To use the standard
3-5/8 inch (92 mm) diameter sonde, the tubing must be pulled in
most wells.  In many wells, water flows behind the casing only when
the well is being produced or during water injection.  Thus, with
the tubing pulled, no flow is observed with the BCWF logging system
unless the casing can be pressurized to induce flow.
SUMMARY
    The system uses 14 MeV neutrons to create radioactive nitrogen
from the oxygen in the water.  The decay of this radioactive
nitrogen can be measured to locate water flow.
    The capabilities of the BCWF system are:
          •  the direction of water flow (up or down)
          •  the linear flow velocity from
                  0.75 to 10 in/sec (19 to 254 mm/sec)
          •  volume flow rates > 10 BWPD
          •  flow radially displaced up to
                  10 inches  (254 mm) from sonde
          •  flow behind up to 3 casings
     This logging technique has been licensed to Dresser-Atlas.
They are developing a field system and plan to offer this system as
part of their regular service.
                                -476-

-------
                        FIGURE CAPTIONS
Fig. 1  A typical BCWF gamma ray spectrum when water is flowing.

Fig. 2  A BCWF sonde in a well bore with water channeling within
the cement annulus behind the well casing.

Fig. 3  BCWF calibration facility.  Different pipe sizes can be
placed at selected radial distances from the sonde.  Different
casing combinations can be used during calibration.

Fig. 4  This is the velocity calibration results for a typical BCWF
sonde.  V is the velocity and C^ and C^ are respectively, the
counts in detectors 1 and 2 between 3.7 and 7.2 MeV.

Fig. 5  This plot shows the volume flow rate can be determined
without knowing the flow channel cross-sectional area.
                               -477-

-------
CD
I
     ID
     O
     O
        1400
        1200
        1000
         800
         600
         400
         200
           0
            0
                                         BEHIND  CASING WATER FLOW

                                              TEST  PIT  DATA
                                                 ENERGY (MeV)
6          7


  Figure  1

-------
DUAL DETECTOR BCWF SONDE
               14 MeV
               SOURCE
     -479-
                          Figure 2

-------
 CALIBRATION FACILITY
 CONTROL
 VALVE METER
3-5/81
nfciznr^
                               PUMP
        -480-
                       Figure 3

-------
0.7
                     CN/CN  VS
                      I   2
                     L - L = 18 INCHES
                      52   5i
_|	L

 0.2
                              I	L    I     I
                                  0.6
                             '/v
0.8
                          -481-
                                               Figure A

-------
                     DETECTOR I TO  SOURCE = 39.4 INCHES
     50

     30

     20


      10
O
o
  3  2
  ZD
  _J
  O
     .07
 R       CASING

2.60     NONE

3.00     NONE
                                                  4.30
5.65
                             5       10   15  20

                               VELOCITY (In/sec)
         NONE
         71
         7'+4'/21
NONE
9%'
9 % '+7'
9 s/8'+7i+4l/2>
                                   -482-
                                                         Figure 5

-------
     TABLE I



BCWF LOG RESULTS
     WELL No. 123
RECORD
NUMBER
1
2
3
4
5
6
7
8
9
10
11
12
DEPTH
feet meters
822.7
801.7
771.4
751.4
721.4
690.7
613.7
562.8
233.2
79.8
29.2
13.3
250.8
244.4
235.1
229.0
219.9
210.5
187.1
171.5
71.1
24.3
8.9
4.1
VOLUME
BWPD
0
0
0
2.8
2.8
50
38
9
286
86


        -483-

-------
     TABLE II
BCWF LOG RESULTS
    WELL No. 124
RECORD
NUMBER
1
2
3
4
5
6
7
8
9
10
11
12
DEPTH
feet meters
782.6
766.4
740.6
694.0
635.7
594.7
511.7
482.0
442.1
82.0
35.1
24.1
238.5
233.6
225.7
211.5
193.8
181.3
156.0
146.9
134.8
25.0
10.7
7.3
VOLUME
BWPD
0
0
79
107
83
13
15
3.2
>107
3.1


        -484-

-------
                A PILOT SURVEY OF STATE MECHANICAL
          INTEGRITY TESTING (MIT) PROGRAMS IN NEW MEXICO

         Kelly Nash, ERT, 12655 North Central Expressway,
                       Dallas, Texas  75243
            Raleigh Kreuz, ERT, 3000 Richmond Avenue,
                      Houston, Texas  77098
              Jack Marr, ERT,  3000 Richmond Avenue,
                      Houston, Texas  77098
ACKNOWLEDGEMENTS;

     The  authors  gratefully  acknowledge the assistance and the
patience of the New Mexico Oil Conservation  Division  staff,  in
particular,  Prentiss  Childs, Jerry Sexton, Frank Chavez, Evelyn
Downs, Bonnie Prichard,  and  Charles  Gholson.   Special  thanks
also  to  Judith  Anderson  of  ERT for compiling the bulk of the
data used in this study*  Finally, the UIPC  Research  Foundation
provided critical review and funding for the project.

ABSTRACT;

     A  pilot  survey  of  State  MIT Programs for Class II wells
under  the  EPA  UIC  Program,  was  conducted  in  New   Mexico.
Records  of  217  annulus  pressure test failures (of 1309 MITs) ,
witnessed  and  recorded  by  the  New  Mexico  Oil  Conservation
Division in 1984 and 1985,, were  reviewed.   File  data  on  test
conditions,  well  construction,  and  subsequent  workovers were
listed  on  an  automated  database.   The  database  allows   an
evaluation  of  the  diagnostic  abilities  of  positive pressure
testing  of  the  tubing  -  casing  annulus   as   compared   to
monitoring   annulus   pressure,   for  which  records  are  also
available.  Information listed in the database includes:
                                   -485-

-------
     1.)   Pressure conditions in the tubing  and  casing  strings
          prior to and at the beginning and ending of testing.
     2.)   Well  construction  data - including initial completion
          dates,  casing and  packer  set  depths,  and  injection
          intervals.
     3.)   Failure  type  indicated - primarily casing, packer and
          tubing failures were indicated by the survey.
     4.)   Well repair data - the survey included  information  on
          the  type  of repair,  estimated cost of the repair, and
          details  such  as  the  casing  hole  interval   (where
          identified).
     The   spreadsheet   feature   of  the  database  allows  the
calculation  of  frequency  distributions  of  such  features  as
casing hole interval, age of well, and repair  types.   Reviewing
the  information  in  the  database  allows  an evaluation of the
various factors which may lead to pressure test failures.
     The study indicates that  the  annulus  pressure  test  will
detect   holes   in  casing.   64%  of  the  test  failures  were
associated with casing holes.   Most  holes  were  in  uncemented
sections  adjacent  to  saline zones below underground sources of
drinking water.
     The age distribution of the  injection  wells  which  failed
the  annulus  pressure  test was a function of general historical
drilling activity if they  were  completed  prior  to  the  early
1970's.     Wells   completed   later   were   not   significantly
represented in the database.
     The  average  cost  of  repairs  necessitated  by conditions
leading to an annulus pressure test failure was estimated  to  be
$11,000.
     The  New  Mexico MIT program was reviewed and evaluated with
the test data.  The New Mexico program  is  more  stringent  than
the   EPA   program  in  that  annulus  monitoring  is  conducted
annually on all wells.  Annulus monitoring in  positive  pressure
                                   -486-

-------
injection  wells  identifies  leaks  of  injection  fluid through
tubing or packer and casing  leaks  opposite  pressurized  zones.
The  first  level of USDW protection in the New Mexico program is
centered around monitoring of  the  tubing  and  casing  annulus.
The  pressure  test looks at the second level of protection - the
production casing string.  There is a third level  of  protection
-  surface  casing.   Usually,  this third level would have to be
breached before a USDW would be endangered by a  failure  of  the
second level.
     The  annulus  pressure  tests  did not identify any evidence
of injection wells which caused groundwater contamination.
                                   -487-

-------
      INTRODUCTION;

      ERT, A Resource Engineering Company, was  retained  by  the
Underground   Injection   Practices   Council   (UIPC)   Research
Foundation,   to   conduct  a  Pilot  Survey  of  the  Mechanical
Integrity Testing  (MIT) program for Class II injection  wells  in
the State of New Mexico.
      The  survey  focused  on  Mechanical Integrity Tests of the
casing, tubing or  packer.   Potential  fluid  movement  into  an
Underground  Source  of  Drinking Water through vertical channels
adjacent to the injection well bore was not  considered  as  part
of the survey.
      The  survey  included  a  review  of  the  New  Mexico  MIT
program   and  comparison  with  EPA  MIT  requirements  and  the
compilation of  MIT  and  well  workover  data  to  indicate  the
diagnostic abilities of annulus pressure tests.

      ENVIRONMENTAL    PROTECTION    AGENCY     (EPA)   MECHANICAL
INTEGRITY TESTING  (MIT) REQUIREMENTS;

      EPA    Mechanical    Integrity    Testing     requirements,
promulgated  in  40CFR146.08,  defined  Mechanical  Integrity  as
having  two  parts:   1) the absence of a significant leak in the
casing, tubing or packer;  and  2)  the  absence  of  significant
fluid  movement  into  an  Underground  Source  of Drinking Water
(USDW) through vertical channels adjacent to the  injection  well
bore.   The  regulations  specified  that  one  of  the following
tests must be used to evaluate the absence of  significant  leaks
as  defined  in  146.08: 1) monitoring of annulus pressure; or 2)
pressure  test  of  the  annulus  with  liquid   or   gas.    The
regulations  also  provided  an  avenue  for the use of alternate
Mechanical  Integrity   Tests,   when   approved   by   the   EPA
Administrator.   These  testing  requirements  were  prepared for
                                   -488-

-------
use by EPA in direct implementation programs,  and  EPA  expected
states  to  use these tests in the State UIC programs implemented
under the authority of the Safe Drinking Water Act.
      On December 5,  1980,  the  Safe  Drinking  Water  Act  was
amended  and,  among  other  changes,  the amendments added a new
Section  1425  to  the  Act.    Section   1425   established   an
alternative  method  for  a  state  to obtain primary enforcement
responsibility for those portions of its UIC program  related  to
the  recovery  and  production  of  oil  and  gas  (i.e., Class II
Injection Wells).  The  Amendments  specified  that  if  a  State
program  meets  the requirements of Sub-paragraphs a-d of Section
1421(b)(1) of the Safe Drinking  Water  Act,  and  represents  an
effective   program   to   prevent  underground  injection  which
endangers  drinking  water  sources,  EPA   shall   approve   the
program.   On  May  19,  1981,  EPA  published  guidance  on  the
implementation  of  the alternative demonstration provided for in
the new Section 1425.  The guidance  included  the  criteria  EPA
would   use  in  approving  or  disapproving  applications  under
Section 1425.  The guidance established the  following  tests  as
adequate  to  demonstrate the absence of significant leaks:  1) a
pressure  test  of  the  annulus  with  liquid  or  gas;  2)  the
monitoring of annulus pressure in  those  wells  injecting  at  a
positive  pressure,  following  an  initial  pressure test; or 3)
all other tests or combinations  of  tests  considered  effective
by the State Director.

      NEW MEXICO MIT REQUIREMENTS;

      The  UIC  program  for Class II (enchanced recovery or salt
water disposal) injection wells in  New  Mexico  is  administered
by  the  Oil Conservation Division (OCD) of the New Mexico Energy
and  Minerals  Department.    The   OCD   was   granted   primary
enforcement  authority  for  the  UIC  program  under the federal
Safe Drinking Water Act on February 5, 1982.
                                   -489-

-------
      The MIT requirements for Class II wells are found  in  Rule
704,  pursuant to the Oil and Gas Act, as follows:

      1.    Prior    to   commencement   of   injection,   initial
           integrity testing of the casing,  tubing,  and  packer
           (if   used)   including   pressure   testing   of  the
           casing-tubing annulus.

      2.    At least  every  five  years  thereafter,  testing  to
           assure continued mechanical integrity, including:

                a.)   measurement  of  annular pressures in wells
                injecting at positive pressures  under  a  packer
                or balanced-fluid seal;

                b.)    pressure   testing  of  the  casing-tubing
                annulus  for   wells   injecting   under   vacuum
                conditions; and

                c.)    other   tests   which   are   demonstrably
                effective and approved by the OCD.

      3.    The  OCD  can  require  additional testing when deemed
           advisable,  including  the  use  of  tracer   surveys,
           noise   logs,   temperature   logs,   or   other  test
           procedures or devices.

      4.    The OCD may order tests to be conducted prior  to  the
           expiration of five years if conditions warrant.

      5.    The  operator  must  notify  the OCD of the scheduling
           of  MITs  so  that  a  Division   representative   may
           witness the test.
                                   -490-

-------
      6.   Rule  704  was  amended  in  1986  to  require  casing
           pressure  tests  whenever  the tubing is pulled or the
           packer is unseated.

      In addition to MIT requirements, Rule  704  also  specifies
monitoring    requirements    which   serve   as   a   continuous
demonstration of mechanical integrity:

      1.   Injection wells must be equipped such  that  injection
           pressure  and  all  casing  annular pressures could be
           measured at the well  head  and  the  injected  volume
           may be determined at least monthly.

      2.   Injection  wells  used  for  storage  must be equipped
           such that both injected and produced  volumes  may  be
           determined at any time.

      When   tests   indicate   that  wells  are  defective,  the
operators are required  to  take  corrective  action.   Operators
must  submit  for  approval  a description of proposed repairs on
Division Form C-103,  "Sundry  Notices  and  Reports  on  Wells",
which  is  also  used  to  report  on  completed  work.  District
inspectors schedule and witness follow-up pressure tests.
      Rule 116 requires operators to report  mechanical  failures
or  downhole  problems  which might endanger fresh water, such as
"spills, leaks  or  blowouts".   The  Rule  requires  appropriate
corrective action for injection well failures.
      Rule   705   requires   notification  to  the  Division  of
commencement,  discontinuance  and   abandonment   of   injection
operations (e.g., plugging and abandonment).
      Rule   706   requires   monthly   or  annual  reporting  of
injection  volumes  or  pressures  on   Form   C-115    (enchanced
recovery  and  pressure  maintenance)  or  Form 120-A  (salt water
disposal).

                                   -491-

-------
      In addition  to  the  testing,  monitoring,  and  reporting
requirements  specified  in  the OCD rules, when easily corrected
problems such as  small  surface  leaks  or  excessive  injection
pressures  are  noted  by  Field  Inspectors,  the  problems  are
brought   to   the   attention  of  the  operator  for  immediate
corrective action, under the  general  authority  of  Rule  1303,
"Duties and Authority of Field Personnel".

      NEW MEXICO TESTING PROGRAMS;

      At   least   twenty-five  percent  of  the  pressure  tests
carried out on wells injecting  on  a  vacuum  are  witnessed  by
District  Field  Inspectors  (NMOCD,  1981).    When tests are not
witnessed, the operators are required to file  the  test  results
with the District offices.
      The   District   offices   place   a   strong  reliance  on
observations and records of pressures and  other  pertinent  data
for  each  string  of  casing  and  tubing during injection.  The
procedure for field observations of annulus  pressure  conditions
(referred  to  in  New  Mexico  as  a  "bradenhead  test")  is as
follows:

      1.   The operator closes in the valves  on  the  bradenhead
           24 hours prior to testing.

      2.   The  operator  opens  each  valve  during the test and
           the  NMOCD  inspector  records  pressures  and   other
           pertinent  information.   Often,  a  short puff of air
           or  a  short  flow  of  water  will  result  from  the
           expansion  of   the   tubing   caused   by   injection
           pressures    and    temperature    differentials.    A
           continuous pressure  or  fluid  flow  at  the  surface
           indicates  either  a  tubing or packer leak  (for wells
           injecting at a  positive  pressure)  or  casing  leaks
           adjacent to pressurized water-bearing formations.
                                   -492-

-------
      NMOCD  observations  of  annulus pressure have been carried
out  in  District  1  since  1974,  District  2  since  1979  and
District  3  since  1981  (NMOCD,  1981).   The  testing  program
includes producing wells in addition to injection wells.
      In some injection wells, the weight  of  the  fluid  column
in  the  well is sufficient to push water into the injection zone
without applying pressure  at  the  surface.   If  a  well  takes
water  at  a  particular rate faster than it can be filled to the
surface, the surface injection pressure will be  less  than  zero
and  the  well  is  said to operate under vacuum conditions.  For
these wells, bradenhead tests  may  not  indicate  if  tubing  or
packer  leaks  are  occurring.   Therefore,  the  State  requires
periodic  annulus  pressure  tests,  under  Rule  704,  for wells
injecting under a vacuum.
      Aside  from  the  annulus  monitoring   program   and   the
periodic  pressure  tests, bond logs, radioactive tracer surveys,
temperature logs and other  special  tests  are  carried  out  in
areas where problems are suspected (NMOCD, 1986).
      Most  of  the New Mexico pressure test and well records are
located  in  three  District  offices  in  Hobbs  (District   1) ,
Artesia  (District  2)  and  Aztec   (District  3) which serve the
eight oil and gas producing counties in New  Mexico.   There  are
presently  approximately  4400  active  Class  II injection wells
which are distributed roughly as follows;

           District 1 (Hobbs) -   2,600
           District 2 (Artesia) - 1,300
           District 3 (Aztec) -     500

      Since 1983, New Mexico has reported to EPA  on  the  number
of MITs conducted and the number of MIT failures, as follows:
                                   -493-

-------
      Year                  MITs     # Failures      % Failing
      1983                  3502          75       2.1%
      1984                  3713         148       4.0%
      1985                  3199         430      13.4%
      1986 (Jan-Sept.)       2519          98       3.9%
           TOTAL          12,933         751       5.8%

      Higher  reported  failure  rates  in 1985 are partially due
to  a  special  study  for  which   approximately   2,000   wells
injecting  at  positive  pressures  were  pressure-tested between
March, 1985 and March,  1986 (NMOCD, 1986).

      SPECIAL STUDIES OF MIT IN NEW MEXICO;

      The New Mexico OCD conducted a  study  for  EPA  (completed
in  June,  1986),   which  discusses  the  results  of  comparison
testing  between  annulus monitoring (referred to in the study as
"bradenhead testing") and pressure tests of 416  injection  wells
in  1984,  and  summary  data  on mechanical integrity testing of
2,091 injection wells in 1985 and 1986 (NMOCD,  1986).   The  OCD
study   and   the    accompanying  background  data  provided  the
foundation for the design and implementation of this survey.
      The conclusions from the Phase 1 testing of  416  wells  in
1984 included the  following (NMOCD, 1986):

     "1.    The  bradenhead  test  is  adequate to find tubing and
           packer  leaks or casing  leaks  with  pressure  on  the
           zone where the leak is located.
      2.    The  problems  found  during  this  study represent no
           significant threat to fresh water since  most  of  the
           casing   leaks  were  found below the surface casing in
           the salt sections where pump-in pressure is  known  to
           be  betweern  400  psi  and  1000 psi.  Such pressures
           resulting  from  tubing  or  packer  leaks  would   be
           detected by the regular bradenhead testing.
                                   -494-

-------
      3.    The   data  collected  supports  the  conclusion  that
           without  a  significant  tubing  or  packer  leak  the
           majority of casing leaks  cannot  be  found  with  the
           bradenhead  test.    However,  it should be pointed out
           that where the bradenhead test  did  not  show  casing
           leaks,  the  tubing and packer were mechanically sound
           so no movement of fluid was occurring  in  the  casing
           annulus.
      4.    The  bradenhead  test  is  not  adequate  for  finding
           tubing or packer leaks on vacuum injection wells."

      The   Phase   2  testing  in  1985  and  1986  resulted  in
additional conclusions;

      "Problem Areas - Wells in Districts I and  II  have  fairly
comparable  geologic  conditions and, as would be expected, found
fairly  comparable  problem  situations;  viz.,   in   the   salt
sections  or  at  the  base of the red beds (tertiary).  The salt
section,   approximately  1000  feet  in  thickness,  provides   a
corrosive  environment  to  external  surfaces of intermediate or
production  casing  strings  when  left  uncemented  through  the
salt.  However, cemented surface casing above the  salt  protects
fresh  water.   The  red  beds  tend  to swell in the presence of
fresh water to the  extent  of  closing  off  the  annular  space
between  pipe  and  formation,  setting  up  a  zone  of  intense
corrosivity.   Caliche  beds  near  the  surface  are also highly
corrosive.
      In District III, the most  corrosive  zone  appears  to  be
the   Menefee   which  is  the  middle  productive  zone  of  the
Mesaverde formation.  This is  an  electrolysis  problem  in  the
entire   area  for  all  types  of  wells.   It  is  not  related
specifically to injection."
      The final recommendations of the OCD study were:

      1.    Continue  annual  observations  of  annulus   pressure
           during well operation bradenhead tests.

                                   -495-

-------
      2.    As  resources  permit,  supplement  annulus monitoring
           with positive pressure tests.
      3.    Require casing pressure tests during workovers.
      4.    Require reports  of  tubing  repairs  and  changes  in
           packer  set  depths,  and  require  that the packer be
           set not more than 100 feet above the perforations.

      STUDY AREAS;

      A  subset  of  records  from  the  NMOCD   special   study,
consisting  of  wells  which  failed  the positive pressure tests
during the special study discussed in  Section  4  were  reviewed
for  this  project.   Specifically,  records  for  pressure  test
failures  in  1984  and  1985  from  the  District  1 (Hobbs) and
District 3 (Aztec)  offices  were  reviewed.   This  consists  of
approximately  220  test  and  well  construction records.  These
are the most complete records available  on  well  integrity  and
provide  representative  comparisons  of  annulus  pressure tests
and bradenhead tests in New Mexico.  District  1  wells,  in  the
southeast  part  of New Mexico, are completed in formations which
are  primarily  structurally  controlled  by  the  Delaware   and
Permian  Basins.   District 3 wells, in the northeast part of the
State,  are  completed  in  formations  which  are   structurally
controlled  by  the  San Juan Basin.  These are the major oil and
gas producing regions in New Mexico.

           DISTRICT 1 GEOLOGY;

      District  1,  in  southeast  New  Mexico,  lies   generally
within  the  Great Plains Physiographic Province.  The plains are
a remnant of an  alluvial  plain  built  up  by  eastward-flowing
streams  from  the  Rocky  Mountains.   There  are essentially no
surface  streams  in  District  1  and  the  Tertiary  sands  and
gravels of the Ogallala  formation  provide  the  only  extensive
source   of   fresh  water  for  the  area  (Boyer,  1986).   The
                                   -496-

-------
saturated thickness of the Ogallala  formation  is  approximately
200  feet  in the eastern part of District 1 and the  formation is
removed by erosion to the south and  west  (USGS,  1984).   Minor
local   sources   of   fresh  groundwater  are  also  present  in
sandstone layers in the  Triassic  "Red  Beds"  and   the  Permian
Rustler  formation  (Nicholson  and  Clebsch,  1981).   All known
USDWs lie above the Permian salt section (NMOCD, 1981).
      Subsurface structure in District 1  is  controlled  by  the
Permian  and  Delaware  basins  and  the  associated  shelf-reefs
which   formed   during   the  Paleozoic  era.   The  hydrocarbon
reservoir rocks are entirely  Paleozoic  and  the  production  is
from  the  fields on the Central Basin Platform and the Northwest
shelf.  Ninety percent of the state's  oil  production  has  come
from  southeast  New  Mexico,  with  commercial  production since
1924  (NMBMER,  1981).    The  reservoir  rocks  are  predominantly
limestone,   largely   Permian   in   age.   Over  half  the  oil
production is  from  the  Grayburg  and  San  Andres  formations.
Other  important  hydrocarbon reservoirs include the  Yates, Seven
Rivers, Queen and Abo Reef formations.  Most of the oil  and  gas
produced  in  southeast  New  Mexico  is  structurally trapped in
anticlines (Landes, 1970).
      Standard casing practice in District 1  is  to  set  casing
to  the  top  of  the Permian salt section (Salado formation) and
cement to the  surface.   The  salt  section  itself  acts  as  a
confining  layer  to  prevent  out-of-zone water from hydrocarbon
reservoirs from entering shallower USDWs (NMOCD, 1981).

      DISTRICT 3 GEOLOGY;

      District 3,  in  northwest  New  Mexico,  lies  within  the
Colorado  Plateau  Physiographic  Province.   The  topography  is
much  more  rugged  than  in  the  southeast.   The San Juan, Rio
Puerco  and  Chaco  Rivers  provide   important   surface   water
supplies  and  the  associated  alluvium  is  a  source  of fresh
groundwater.
                                   -497-

-------
      The  subsurface  geology  of  northwest   New   Mexico   is
structurally  dominated  by  the San Juan Basin.  The major fresh
groundwater  sources  in  the  San  Juan  Basin  are   Cretaceous
sandstones,  most  importantly  the  Ojo  Alamo  sandstone (which
immediately  overlies  the  Kirtland  shale   (Brimhall,   1973).
Freshwater  also  occurs  in the Menefee member of the Mesa Verde
Formation and locally in the  Morrison  formation.   Fresh  water
may  be  found at depths to 3000 feet in District 3.  Since these
aquifers are often artesian, cemented production casing  is  used
to  isolate  these aquifers.  Artesian conditions also contribute
to the effectiveness of annulus monitoring in  indicating  casing
leaks (pers. comm., E. Busch, OCD).
      In   northwest   New   Mexico,   most  of  the  hydrocarbon
production has been from Cretaceous  rocks,  mostly  sandbar-type
stratigraphic  traps,  and  also  from  fractures  in  the Mancos
shale (NMBMER, 1981).  Gas  has  been  commercially  produced  in
District 3 since 1921 and oil since 1922.

      DATA ELEMENTS;

      After  reviewing  the  file  material  available at the New
Mexico Oil Conservation  Division   (NMOCD),  a  survey  form  was
developed,  an  example  of  which  is  shown in Figure 5-4.   The
main sources of information available in the OCD files  were  the
inspector  worksheet  for  the pressure tests, the workover forms
filed after the pressure tests, and the initial  well  completion
report,  which contained construction details of the wells.
      After  the  records  were reviewed, the key data to conduct
the evaluation  was  determined  and  set  up  on  a  spreadsheet
program.  The data elements included:

      1)   Record Number - unique for each well test.

      2)   Pressure  drop-rate  in  psi/minute.   In general, the
           tubing-production  casing  annulus  was  pressured  to
                                    -498-

-------
     approximately 300 psi.  In  many  cases,  it  was  not
     possible  to  reach  the  initial pressure of 300 psi,
     or even to fill the annulus with packer fluid.

3)    Completion  date  -  the  year  that  the   well   was
     initially completed.

4)    Bradenhead  Tests  Pass/Fail  -  whether  the well was
     considered  to  have  passed  or  failed  an   initial
     observation of annulus pressures.

5)    Test  Data  -  the initial, start test and end of test
     pressures  inside  the  surface,   intermediate,   and
     production casing and the injection tubing.

6)    Type  of  Failure  -  a review of the test records and
     workover forms indicated, in many cases, the  type  of
     failure  which  was  indicated  by  the  pressure test
     failure.

7)    Squeeze/Leak Interval  -  when  the  interval  of  the
     casing  hole  was  identified by subsequent workovers,
     including  plugging   and   abandonment,   the   depth
     interval was recorded.

8)    Approximate  Cost  - cost estimates were made for each
     repair.

9)    Surface  Casing  Depth   -   as   indicated   by   the
     construction records.

10)  Surface Casing Cement Circulated - Yes or No.

11)  Packer Set Depth,

12)  Injection Interval.
                           -499-

-------
      13)   Type of Packer - (if known).

      14)   Injection Pressure.

      15)   Additional Remarks.

      COST ESTIMATES OF REPAIRS;

      Costs  were  derived  by reviewing each record, summarizing
each job,  estimating the total time  required  to  complete,  and
then  totaling  the  cost  based  upon  the  work performed.  For
example, if a packer was re-set only and the well  re-tested  and
passed, this would require one day, as follows:

                Rig - 1 day              $1,250
                Pump Truck - 4 hours        600
                     Estimated Cost      $1,850

      The  cost  applied to each phase of a job from quoted daily
costs  obtained  from  various  oilfield  service  companies  and
operators,  including  workover  contractors,  cement  companies,
tool rental companies, logging companies, etc.

      The  total  cost  of  the  repairs  for  which   sufficient
information   was   available   (143)   and   for   which   wells
subsequently  passed  the  annulus pressure test is $1,564,000 or
an average of $11,000 per job.

      DATA ANALYSIS;

           Summary Statistics.

      A total of 217 records of annulus  pressure  test  failures
were  reviewed.   These  represented  all the records which could
be located for the  District  1  and  3  annulus  pressure  tests
                                   -50CK

-------
conducted   in   1984  and  1985  for  the   (NMOCD,  1986)  study
previously  discussed.   A  test  failure  in   the   study   was
generally  defined  as  the  decrease of more than 10% in annulus
pressure over 15 minutes.   The  annulus  pressure  test  failure
records  identified  in  this  study  are  from  a  total of 1301
mechanical integrity tests, of which 263 failed.   The  procedure
for  testing  was  that pressure tests followed bradenhead tests.
Not all wells which failed bradenhead  tests  were  subjected  to
annulus  pressure  tests.  District 3 did not conduct any annulus
pressure  tests  for  wells  which  failed  the  bradenhead  test
(pers. comm.( E. Busch, OCD).
      The average depth of the top of the injection zone  in  the
database is 3,866 feet.
      The  age  distribution  of  the  wells  in  the database is
shown in Figure 1.  In general, the age distribution  shows  good
correlation  with  historical  drilling, activity until the early
1970gs.  Figure 2 shows  a  comparison  of  the  distribution  of
ages  (initial  well  completions)  of wells in District 1, which
failed  the  annulus  pressure   test   with   the   total   well
completions  for  each  year in eastern New Mexico as reported by
the   International    Oil    Scouts    Association    (I.O.S.A.,
1930-1983).   The  figure  suggests  that  improvements in casing
materials and  cementing  technologies  in  the  1970's  will  be
evaluated  by  future  pressure  tests.   In  the  1990's,  wells
completed  during  the "boom" years of the late 1970's will reach
the age of those which showed casing problems in this survey.
      In general, the  findings  of  this  survey  supported  the
conclusions   discussed  in  OCD,  1986  regarding  the  problems
indentified by the annulus pressure test.   The  primary  problem
type   identified  was  holes  in  the  production  casing.   The
distribution of  problem  and  repair  types  is  illustrated  in
Figures 3 and 4.
      Casing  problems  were  identified  in  88  wells in one of
three ways:
      1.   Holes found during subsequent workovers,
                                   -501-

-------
      2.    Problems reported by operators,  or
      3.    Flow  of  fluid  or  pressure  increase  in  the  pipe
           string outside the string being tested.

      The  locations  of  casing  leaks  were  determined  in  79
wells.  The distribution of the top of  the  leaks  is  shown  in
Figure  5.   The  average  depth  of  the top of the casing holes
found was 1,595 feet.  Most  of  the  holes  were  in  uncemented
sections  of  the  production casing below the surface casing, as
discussed in (NMOCD, 1986).
      Records of ten wells with  old  casing  perforations  above
the  packer  were  found.   In  one  case,   the  Bureau  of  Land
Management  was  requiring  the operator to monitor annulus fluid
levels.    Twenty-two   wells   with   packer    problems    were
identified.   Five  of  these  showed  evidence  of  packer leaks
during the bradenhead tests,  four  were  shut-in  and  two  were
injecting  on  a  vacuum.   Tension-set  packers  may  have  been
unseated  by  the  pressure test in some instances.  For example,
the packer in one well was unseated by the  operator  during  the
well  workover  by  applying 500 psi annulus pressure.  OCD, 1986
also discusses packer failures, and  states  that  some  reported
packer  failures  were  repaired  by  moving  the packer slightly
up-hole to  cover  a  casing  leak,  but  remaining  set  in  the
injection zone.
      Tubing  leaks  were  identified  in nine instances.  Two of
these failures were in wells that passed the bradenhead test.
      The remaining test failure types  were  nine  miscellaneous
valve,  line  and  wellhead  packing  leaks which were identified
after  the  initial  testing  and  do  not  indicate   mechanical
integrity problems.
      The  type  of  repair  was  determined  for 175 wells.  The
most common repair was a cement squeeze for casing leaks  (61  of
175   wells  or  35%).   Twenty-eight  wells  (16%)  were  simply
plugged and  abandoned.   Forty  wells  (23%)  were  reported  as
shut-in,   with  seven  of  these  having  a cast iron bridge plug
                                   -502-

-------
set.  The packer was reset on 15 wells  (9%).  In some  cases,  it
was  not  necessary  to  pull  the tubing to accomplish this.  On
nine wells (5%), it  was  necessary  to  repair  or  replace  the
packer.   Twelve  wells  (7%)  were  tested  again and passed the
annulus pressure test the second time.

      GROUNDWATER IMPACTS;

      An  actual  determination  of  groundwater  impacts   would
require  a  site-specific investigation at each suspected problem
well.  While the  actual  determination  of  groundwater  impacts
from  injection  wells  which failed the annulus pressure test is
beyond  the  scope  of  this  survey,  a  general  assessment  of
contamination potential can be made.
      OCD, 1986, which formed the basis  for  this  study,  noted
that  no  evidence of contamination of a USDW was found at any of
the 2,507 well locations where tests were  conducted.   Likewise,
this  survey  did not identify any evidence of contamination of a
USDW.
      From OCD, 1986 and the previous discussion, it  is  obvious
that  annulus  monitoring can detect tubing or packer problems in
wells injecting at a  positive  pressure.   It  can  also  detect
casing   problems   opposite   pressurized   zones.   Where  such
conditions exist, the potential for  contamination  is  greatest.
These  conditions  are  readily  detectable  by  annulus pressure
observations.
      Injection under a vacuum  poses  minimal  threat  to  USDWs
since   it   is   unlikely,  under  these  conditions,  that  the
hydraulics exist that could cause injected fluids  to  enter  and
contaminate  a  USDW.   Before  injection  fluids could enter the
formation, fluid levels would rise to  a  level  above  the  USDW
sufficient  to  overcome  the  natural  pressure  gradient of the
USDW formation.
      The increase in pressure down-hole  in  an  injection  well
is  due  to  the  weight  of fluid in the hole (approximately 0.5
psi/ft.).  If the pressure at  the  surface  is  negative  (i.e.,

                                   -503-

-------
vacuum  conditions),  positive  pressure conditions will exist at
some point down-hole.  It can be  intuitively  reasoned  that  if
this  point  is  below  a USDW, no contamination of the USDW from
injection fluid can occur.  Even though  the  annulus  monitoring
is  less  definitive  for  vacuum  wells,  these  wells  are less
likely to contaminate groundwater.

      SUMMARY;

      o    ERT  reviewed  the   New   Mexico   Oil   Conservation
           Division's   program  of  mechanical  integrity  tests
           (MITs) for Class II injection wells.

      o    Records  of  217  pressure  test  (PT)  failures  were
           reviewed.   Records  represented  1309  MITs  in   New
           Mexico during 1984 - 1985.

      o    A database was developed listing test and well data.

      o    Failure   types,   repairs   and   repair  costs  were
           analyzed.

      o    The PT failures  were  mostly  due  to  casing  holes.
           Most holes were in uncemented saline zones.

      o    The   age   distribution   of   well  failures  tracks
           historical drilling trends up to the 1970«s.

      o    The  average  cost  per  well  associated  with  a  PT
           failure was estimated at $11,000.

      CONCLUSIONS;

      o    The pressure test will detect holes in casing.
                                   -504-

-------
The  analysis  of  pressure  test  failures  did   not
identify evidence of USDW contamination.

The  New  Mexico  annulus  monitoring  program is more
stringent than the EPA UIC requirements  and  provides
a high level of USDW protection.

The   first   level   of  protection  for  underground
sources of drinking water in the New Mexico  Class  II
UIC  program  is  centered  around  monitoring  of the
tubing and casing annulus.  The  pressure  test  looks
at  the  second  level  of  protection, the production
casing string.  There is a third level  of  protection
   surface  casing.   Usually,  the  third level would
have  to  be  breached  before   a   USDW   would   be
endangered  by  a  failure  of  the second level.  The
$1,564,000 spent  to  repair  wells  failing  pressure
tests   was   necessary   to   meet  New  Mexico  well
construction  requirements,  but  was   not   required
because of an imminent threat to a USDW.
                        -505-

-------
      REFERENCES:

Boyer,   David   G.,    1986,   Differences   in   Produced  Water
Contaminants  from  Oil  and  Gas  Operations  in  New  Mexico
Implications for Regulatory Action, Presented at  National  Water
Well  Association  Conference on Southwestern Groundwater Issues,
Tempe, Arizona, October 20-23, 1986.

Brimhall, Ronald M.,  1973, Ground  Water  Hydrology  of  Tertiary
Rocks  of  the  San  Juan Basin, New Mexico, in:  "Cretaceous and
Tertiary rocks of the Southern  Colorado  Plateau,  A  Memoir  of
the Four Corners Geological Society, p. 197-207.

Gutentag,  E.,  et.  al.,  1984,  Geohydrology of the High Plains
Aquifer in Parts  of  Colorado,  Kansas,  Nebraska,  New  Mexico,
Oklahoma,  South  Dakota, Texas and Wyoming, U.S.G.S. Prof. Paper
1400-B.

International Oil Scouts Association   (1939-1980),  International
Oil and Gas Development Yearbooks, I.O.S.A., Austin, Texas.

Landes,   Kenneth   (1970),   Petroleum   Geology  of  the  U.S.,
Wiley-Interscience, New York, NY.

New Mexico Bureau of Mines and Energy Resources  (NMBMER),  1981,
New Mexico's Energy Resources  '80', Circular 181, Santa Fe, NM.

Oil  Conservation  Division   (OCD), 1981, Primacy Application for
Class II Injection Wells, EPA Region 6, Dallas, Texas.

Oil Conservation Division  (OCD), 1986,  Comparison  Test  Between
a  Bradenhead  Test  and  Pressure  Test, Final Report, EPA Grant
No.  X811232-01-3,  OCD,   New   Mexico   Energy   and   Minerals
Department, Santa Fe, New Mexico.
                                   -506-

-------
              AGE DISTRIBUTION OF ALL RECORDS
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           193O   1935   1940  1945  195O  1955  196O  1965   1970  1975  1980  1985
                            DATE OF iNmAL WELL COMPLETION
                              # WELLS COMPLETED

-------
           AGE DISTRIBUTION  -  DISTRICT ONE
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1945  1950  1955  1960  1965



  DATE OF INITIAL WELL COMPLETION
                                                     1975
1980  1985

-------
                                        Type  of Failure
                                  Other (6.5%)
                      Tubing (6.5%)
        Casing" Perf. (7.2%)
i
£>
I
         Packer (15.9%)
                                                                                               H

                                                                                               O
                                                                                               a
                                                                                   Casing (63.8%)

-------
                                         Type  of Repair
                 Shut In (22.9%)
f         Other (1.1%)

    Rep. Casing (1.7%)



   Repair Tubing (2.9%)
     Repair Packer (5.1%)
             Re-test OK (6.9%)
                                                                               Cement Squeeze (34.9%
                                                                                                  H
                                                                                                  a
                                                                                                  a
                        Reset Packer (8.6%)
                                                                 Rug and Abandon (16.0%)

-------
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           DISTRIBUTION  OF  CASING HOLE TOPS
24


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20 -


18 -


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14 -


12 -


10 -


 8 -


 6 -
       4 -


       2 -
                            AS IDENTIFIED DURING REPAIRS
                  z
                                                                         8
              500  1000 1500 2000 25OO 3000 3500 4000 4500 5OOO 55OO 6OOO 6500 7000

                        TOP OF HOLE INTERVAL (DEPTH IN FEET)
                                 No. OF WELLS

-------
           PLANNING SUCCESSFUL TEMPERATURE SURVEYS




         John G. Berner, Conoco Inc., Houston, Texas
ACKNOWLEDGEMENT








The author appreciates the critical review  of  this paper




provided by fellow employees, Rob  Bedard, Ed Dew, and  Paul




Pilkington.  Permission to present this paper  was provided




by Conoco  Inc.






ABSTRACT








Temperature surveys are often run  in injection wells as soon




as a problem is suspected.  Very little thought goes into




analyzing the possible problems and thinking about how they




will affect the temperature  survey, if  at all.  Often  the




survey is simply run and  then an attempt is made to analyze




the results.








Some pre-testing, data gathering and considerable thought




should precede  the  temperature survey.   Pressure communica-




tion does not necessarily mean fluid flow is  occurring.




Temperature anomalies do  not exist if fluid flow is confined




to its normal injection path.
                            -512-

-------
Injection should be maintained at its normal  state  unless  it




is known that contamination of the USDW is occurring  and can




be stopped by shutting in the well.  A survey should  be




planned, and if it does not  show anomalies, then some can  be




created according to the  test procedure.








A differential temperature survey will accentuate an anomaly




from the continuous temperature survey.  The most definitive




survey, however, may be several successive surveys  known as




a temperature decay log.  A decay log is normally successful




at distinguishing zones of fluid entry into the  formation.








TEMPERATURE SURVEYS FOR PROBLEM INJECTION WELLS






Temperature surveys are run for a variety  of  reasons.  They




are run in some areas  on  a schedule, perhaps annually, to




monitor injection profiles.  They are also run as the first




choice when a problem  is  discovered.  The temperature survey




is quick and relatively cheap.  The problem is that the




planning stage is also  "quick".   Very little thought  has




been given concerning what the temperature log should or




might show.  The result is that the log is ultimately sent




to the company "expert", with inadequate accompanying data,




for interpretation.
                            -513-

-------
A problem in an injection well  could  be discovered by a




sudden  change in the injection  rate-pressure  relationship.




The well could suddenly develop  pressure  on  the tubing-




casing annulus or a surface seepage could be spotted.  A




surface seepage would require closing  in  injection because




the ground waters are being contaminated.  In  the other




cases it would be preferable to  not disturb  the injection




until after the first temperature  survey  is  run.








Fast action is required.  Shutting in the injection will not




stop pollution of the ground waters if it is occurring,




because the injection zone will  probably  back  flow for a




long period of time.  Shutting off injection and doing




nothing creates a worse day of  reckoning  later.  The problem




needs to be reported and a remedial program  planned.









WELLBORE DIAGRAMS








Temperature surveys should be planned  for success.  One of




the first tasks is to  draw a  diagram of the downhole equip-




ment.  The well file should be scanned thoroughly in order




to determine the equipment currently  installed in the well.




The minimum  I.D. of all of the pieces should be determined




along with any obstruction that might exist  in the injection




string.   Circulating valves should be noted  and all perfora-
                             -514-

-------
tions,  open or squeezed, below the packer or  above, should




be included.








Figure No. 1 shows a simple injection well with  casing,




tubing, packer and one set of perforations in the  injection



zone.   This is the simplest situation that is possible and




should lead to a simple analysis of a temperature  log.




Hopefully, several feet of rathole will exist below the




bottom perforation.  This will allow the temperature survey




to read the normal temperature at that depth.  Complications




occur when multiple  injection zones, uphole  perforations,




circulating valves, liners and twin well injection are




added, as  in  Figure  No.  2.








Another item  of interest would be the type and density of




fluid in the annulus.  In a lot  of old wells, this value is




probably not known with  any degree of accuracy.  A sudden




indication of pressure on the casing-tubing  annulus could




mean a lot of things.  An analysis of the situation could




point out possibilities to plan for.   The injection pressure




(Pi)  can  be compared to  the annulus  pressure (Pa).  If the




leak is at the bottom of the  injection string, Pa  = Pi minus




tubing friction pressure losses minus difference in densi-




ties of fluid in annulus and  tubing.
                             -515-

-------
          WELL DIVGNOSIS
In order to remove the unknown  value  of friction  pressure,




it may be desirable to shut off injection  for a few  minutes.




A comparison between  stabilized Pi  and  Pa  can then be made




to see if they are directly related.  If the annulus  fluid




is considerably heavier than the injection  fluid, then  a




large difference in Pa and Pi would be  expected.  On  the




other hand, there could also be a hole  in  the casing.   If




Pa = Pi, a shallow tubing leak could be expected with no




leak in  the casing.








If a well has multiple injection strings,  it would be normal




to suspect the upper  injection string.  By comparing  Pa to




the Pi's with various strings shut in,  or  injecting,  it




should be possible to determine which  string  has  a  leak.  If




the pressures observed during injection indicate  a shallow




tubing leak,  the shutin pressures should indicate which




tubing string is at fault.  If Pi reduces  considerably when




injection ceases and  Pa mirrors that pressure drop,  then the




shut-in tubing string is at fault.  A multi-pen chart re-




corder could  give a good record of  these  test  pressures.




Figure No.  3  indicates some pressure relationships in a




simple injection well.
                             -516-

-------
In order to think of all the possibilities for the particu-




lar well design, it may be desirable to construct a decision




tree for the wellhead test.  The decision tree would force




more thought into the situation, provide a logical sequence




to the testing, and allow written results at  each test




point.   See Figure No. 4 for an example.








Another factor to be considered is a casing leak due to




outside sources of injection.  In a new injection project




this could be likely if twin injection  wells  exist.  In




older injection projects it could come from any pressured




zone uphole of the problem well's injection zone.  This  is




one instance where failure of uphole perforations could  be a




strong possibility, even  if  they  have  been  squeezed.








NORMAL EARTH TEMPERATURE








It is important to know what the normal temperature-depth




profile is for the area.  The well files, log files, and




lease files, by now have  hopefully been searched for tem-




perature information.  Continuous temperature surveys are




not usually run during normal primary  operations and none




may be available.   In planning an injection  project, the




additional cost to run two or three con-tinuous temperature




profiles in the field would be very small.  If temperature




                             -517-

-------
profiles are available, make  sure  they  were  run  under  static




conditions with all  temperatures  stablized.








The alternative to a continuous temperature  log  is a multi-




point curve created from maximum recording thermometer




readings at various  open hole log  depths.  Open  hole logs




are often run at surface pipe depths and at  total depth.   In




some areas, other  logs  may  be run  if an intermediate casing




string and/or liner  are set.  More than one  log  run is




generally used at  each  logging depth.   Each  succeeding  tool




run will usually have a higher temperature than  the pre-




ceding tool run.   The temperature  from  the last  tool run in




the hole is still probably low but can  be considered as




representative at  that  depth.






The resulting temperature graph will usually be  a straight




line as shown in Figure No. 5.  The temperature  gradient




will probably be about  1° F. per 100 feet but can be much




higher or quite a  bit lower.  Extrapolation  of the downhole




temperatures to the  surface can safely  be made.  Surface




temperatures will  vary  with area considerably but will  range




from 80° F. offshore Gulf of Mexico to  50° F. at the




Canadian border.   Surface  temperature is a constant tempera-




ture just below the  earth's surface which is unaffected by




atmospheric temperature changes.
                            -518-

-------
The accuracy of the plotted log points can be improved by




creating a temperature buildup plot at each depth.  This




plot,  see Figure 6, is similar to a "Homer Plot" for pres-




sure buildup.








In deep wells and in areas having over pressures, abrupt




gradient changes can occur.  See  Figure No. 7-  This knowl-




edge can greatly improve interpretation accuracy.  Data from




several wells will offset possible bad data from a single




well.








INJECTION TEMPERATURE PROFILE








Water injection at surface temperatures will  change the con-




tinuous temperature profile considerably.  The cool water




temperatures absorb heat from the tubing,  annular fluids,




casing,  cement and formation until the gradient in the well




becomes very low.  The amount of cooling varies with rate




and volume injected.  The temperature decrease does not




occur  very far out into the formation from the wellbore.




Injection into the reservoirs  will have a much greater




effect,  however, because the "cool"  water  actually pene-




trates  the formation.  Figure No.  8  shows  the cooling




effects.
                             -519-

-------
Actual continuous temperature surveys run during normal
injection are rare.   Very few companies run them on a regu-
lar basis for monitoring purposes.  Each subsequent run
would be a little different if they were available, but the
difference should only be in the slope of the line and the
ultimate injection zone temperature.  Any anomaly in the
curve is probably due to equipment  changes or a rare forma-
tion change.   Papers  have been written on temperature
profile modeling.  A  lot of data on thermal conductivity of
wellbore equipment and fluids and all formations from
surface to TD would be necessary to obtain a good  model.
This could provide a  good base model if it is built
properly.


SEARCHING FOR ANOMALIES


Now that we know  what  to expect from the data collected at
this point,  it is time to run a continuous temperature
survey and see what anomalous  indications  occur.


Very high rates of injection may prevent the temperature
tool from "seeing" anything but the temperature of the water
in the injection string.  Small leaks in the tubing or
channels behind the pipe or up past the packer may go un-
noticed or provide only small anomalies.  Most service
companies can run a differential temperature curve which
                             -520-

-------
accentuates the anomaly.  It may be either a one or two




detector tool,  but it measures the  difference in temperature




between two  depth points (2'  to  10' apart) in  the  tubing.




It is not  a different temperature survey but merely a dif-




ferent presentation  displayed on an exagerated  scale.




Figure No. 9  is a  combination continuous temperature log and




a differential temperature  survey.








If anomalies occur, it is time for interpretation.  Many




papers have been written on this subject and it will not be




discussed  here.  If anomalies are not present,  then why not?




just because we have pressure on the annulus,  it  doesn't




mean we have flow outside the injection string.  Fluid flow




outside the intended fluid flow path is required to create




an anomalous temperature change.








CHEATING AN ANOMALY








Now is the time to create an anomaly or increase what looks




like an insignificant one.   A significant increase in injec-




tion rate  may create a prominent anomaly on the next temper^




ature survey.  Another  method of attack would be to open the




annulus and flow it  to a tank for a while and run  the




temperature survey again.  A leak in the injection tubing, a




packer not set, communication behind the casing back into




the annulus,  a faulty circulating valve; all of these will




                             -521-

-------
now show a temperature anomaly.  The amount of temperature




change will depend on the amount of flow coming out of the




annulus.   A large flow volume will require a shorter flow




period to obtain a significant temperature change.  A small




flow volume may  require  several hours of flow period to




obtain the same  amount of  change.








Very shallow wells with  low  injection rates will  have little




temperature change from  surface to TD.  The temperature




profile may change more  from night to day with injection




water temperatures changes than it does from top  to bottom




of the well.  The best solution here may be to get a hot




oiler on .pa location and heat  a tank of injection water to




120° F.   A significant difference will now occur  from top to




bottom of the well.








The biggest change of all after running the first tempera-




ture log during  injection may be to  shut the well in.  A




series of temperature surveys can now be run on some




schedule such as 1,  3, 5 - - - hours after shutin.  This is




called a temperature  decay log.  See Figure No.  10.  It




illustrates the  earth's  return  to temperature equilibrium.




The areas with the shallowest cooling (all areas  where water




did not enter the rock)  will return  to the earth's normal




temperature gradient  first.  This is the best type of tem-




perature log to  find  leaks in the  casing.




                            -522-

-------
A lot of papers have been written on mathematical  interpre-




tation of temperature surveys, but most people consider




their interpretation a work of art.  The radioactive tracer




survey can be run with the temperature survey and  is a good




tool for finding small leaks.  It is also a good tool to




confirm confinement of injection fluid to the injection




zone.  The  temperature survey may solve the problem, but it




would be advisable to have radioactivity tracer logging




equipment on  location.








Development of a good data base and proper planning of the




temperature survey will go a long way in assuring  successful




interpretation of the well's problem.








REFERENCES








1.   Cocanower,  R. D., Morris, B. P.,  and Dillingham,  M.:




     "Computerized Temperature Decay - An Asset to Tempera-




     ture Logging," J^ Pet^  Tech^  (Aug.  1969)  933-9^1.




2.   Loeb,  J.,  and Poupon, A.,: "Temperature  Logs  in Produc-




     tion and Injection Wells."  Twenty-Seventh Meeting of




     the European Association of Exploration Geophysicists



     in Madrid - May  5-6-7,  1965.
                             -523-

-------
3-    Fagley, John, Folger, H. Scott,  Davenport,  C.  Brent,



     and Millhone, Ralph  S.:  "An Improved Simulation  for




     Interpreting Temperature Logs  in Injection Wells."




     Paper SPE-AIME  10081, 56th Annual  Fall  Meeting,  San




     Antonio, Texas,  Oct.  5-7,  1981.




4.    Western Company Technical Leaflet.   No  date.



5.    Joslyn, C. D.,  and Chilton,  L.  F.: "Analysis of  Well



     Problems Through the Use of Differential Temperature



     Logs."   API Preprint Paper No. 875-24-H, for presenta-



     tion at Spring Meeting, Rocky Mountain  District  Divi-




     sion of Production,  Denver,  Colorado,  April 27-29,



     1970.
                             -524-

-------
                               WELLBORE DIAGRAM
                           ZERO
                         GRD. ELEV.
               7" CASING
            2 3/8" TUBING
to
Ul
I
 15' ALF
  936'
    TENSION PACKER @ 6357-59' _E
           TOP/MILO SAND
          BASE/MILO SAND
                    PBTD
          7" CASING SHOE
                     T.D.

                                   E-6250'
                                   ^6350'
 PRESENT WELL CONDITION:
INJECTING  430 BWPD
         1250 PSI
CONDUCTOR PIPE 70'
SURFACE CASING 10 3/4" H-40 @ 2900'
CEMENT CIRCULATED
CASING 7" J-55 23#/FT.  #/FT.
TOP OF CEMENT 3600'
ANNULAR FLUID - 80,000 PPM NaCI
MINIMUM ID - PACKER 1.9"
VBOTTOM OF TUBING
 L_OPEN ENDED @ 6369'
i?-PERFS

 l~6400'
 ^6423'
 ~^_6429'
 - 6433'
                                                                           FIGURE NO. 1

-------
ZERO
GRD. ELEV.
15' ALF
936'
ON
I
        TOP/CATOOSA SAND —
       BASE/CATOOSA SAND-
               SLIDING SLEEVE
       DUAL HYDRAULIC PACKER

                TOP/JONES —
    BASE/JONES—

PERMANENT PACKER

 TOP/MILO SAND —
                       PERFS

           BASE/MILO SAND	
                     PBTD
           7" CASING SHOE
              TOTAL DEPTH
                                    ^-6300'
                         ^6400'
                                                   WELL BORE DIAGRAM
  PRESENT WELL CONDITION:

INJECTION
 MILO      430 BWPD
          1250 PSI
 JONES     300
          1200 PSI
 CATOOSA TWIN WELL INJECTION
           200 BWPD
          1400 PSI
          PERFS SQUEEZED
 NORRIS FORMATION
          5310-31  IS BEING
          FLOODED  IN THIS
          PART OF THE FIELD.
 CASING 7" J-55 23#/FT.
 TOP OF CEMENT 3600'
 ANNULAR FLUID - 80,000 PPM NaCI
 MINIMUM ID
    MILO TUBING 1.94 IN.
    JONES TUBING 1.875 IN.
                                                                         FIGURE NO. 2

-------
                     PRESSURE BALANCE
INJECTION






PW = Pi -





x

Pf -







h p




>
x

H


a
FLUID LEVEL
Y* Prr —
r ' I u


PR = Pj - 1

                                        Pi  =
                                        Pa  =
                                        PTC =

                                        PW =
                                        Pf  =
                                        PH  -
                                        PR  =
                                        Pn  =
INJECTION PRESSURE
ANNULUS PRESSURE
TUBING CASING
BOTTOM HOLE PRESSURE
BOTTOM HOLE PRESSURE
FRICTION PRESSURE
HYDROSTATIC PRESSURE
RESERVOIR PRESSURE
PRESSURE LOSS
ACROSS PERFORATIONS
                                      Pa + PH
                                                             FIGURE NO. 3

-------
               DECISION TREE                           CLOSE ANNU.
                                             TAKE WTR.         ENDTEST
                                             SAMPLES    NO CHANGE IN
                                            CK. INJ. RATE   INJ. RATE & PRESS.
                                            RECORD TIME./                   CLOSE-IN ANNU.
                                             & PRESS. ^                 P    END TEST
                                      CONT.       RATE INCR. AND/OR    ANNU.
                             RECORD   L°W          PRESS. DECR.     FLOW DIES

                              PRESS
                              FLOW   X                        \NJ.
S                     EXISTS  ""•"•"•    \                          ANNU. FLOW
t°          m  MONITOR  ^/               \                           CONT.
           °ANNU PRESS.X                 N,0 ,                            V CLOSE ANNU.
                        NO              FLOW                 n END      D  RESUME INJ.
                       PRESS.               \                r TEST         END TEST
                          V. RECORD &       \          NO PRESS.
                             END TEST        \          BUILD-UP
                                                  SHUT-IN y              ^END TEST
                                                  ANNU.
                                                        PRESS       TUBING PRESS. DROP &
                                                        RETURNS       ANNU. PRESS. DROP
                                                                      TBG. PRESS DROP
                                                                    & ANNU. PRESS. DROP

                                                                          END TEST
                                                                                    FIGURE NO. 4

-------
i
Ul
VD
I
       ESTIMATION OF FORMATION TEMPERATURE GRADIENT

                       FROM BHT DATA
                                                   240
   18,000
                                                    FIGURE WO. 5

-------
   220
   210
o
t 200
   190
   180
      0.4
                         TEMPERATURE BUILDUP
0.5
0.6
0.7
0.8
                                     At
                                   t  + At
0.9
1.0
                                                                      FIGURE NO. 6

-------
01
Co
                   BHT DATA FROM RESISTIVITY LOGS
                           CUSTER CO., OKLAHOMA
    o
    o
    a.
    g
 6


 8 -


10


12
      16 •
      18 •
      20
                           SNIDER NO. 1-A
           X
     TOP
OVERPRESSURE
                                                     WOLFCAMPIAN
                                                                   BROWN DOLOMITE
                                                       U. TONKAWA-
                                                                 •

                                                   COTTAGE GROVE •
                                                 CHECKER BOARD LS.'
                                                       U. RED FORK
COUNTY LINE LS.

L. TONKAWA

HOGSHOOTER
DEESE



L. RED FORK
     FORMATION TOPS AND
     OVERPRESSURE DATA
     TAKEN FROM SNIDER NO. 1-A
                                                       "A"
                                                        A __
                                                  ni-> i • • r><*\O c ^^^
                                                  PRIMROSE —
                                                            v
                                                             V
                                                                   CUNN|NGHAM
        100° 120° 140° 160°  180° 200° 220° 240°  260°  280° 300° 320°
                              TEMPERATURE °F
                                                                                FIGURE WO. 7

-------
          INJECTION PROFILES

        ARE RATE AND VOLUME

              DEPENDENT
(M

CO
                                U.

                                o
                                o
                                o
                                0.
                                UJ
                                Q
                                             90 100  120

                                             TEMPERATURE
140
160
                                                            FIGURE NO. 8

-------
                               CONTINUOUS AND DIFFERENTIAL
                                   TEMPERATURE CURVES

                                           TUBING LEAK
I
Ul
             COLLAR LOG
               TUBING
                        10,000
10,050
                       10,100
                       10,150
                       10,200
                              GRADIENT ONE DEG.
                                  PER INCH
                        DIFFERENTIAL
       TUBING PRESSURE
          7200 PSI

        FLUID LEVEL
        IN ANNULUS
                                ABSOLUTE TEMP.
                                                 DIFFERENTIAL CURVE
                              TUBING LEAK (10,118')
                                            T.D. @ 21,700'
                                                                      FIGURE NO. 9

-------
                                         90°  91°  92°  93°
U)
        TEMPERATURE DECAY LOG


         DETERMINES FLUID MOVEMENT
              IN THE FORMATION
        R-1   2:00 P.M. -IN J. RATE -400 BPD
        JV2 __ 4jO_0_P_J\/L. ~ 30 MINUTE SHUT IN

        R3   6:00 P.M/
        R-52:00 A.M
        R-7
 94°  95°  96° 97° 98° 99°
4200-
                                                                          FIGURE 10

-------
Mobil's  Experience  in  Applying  for  a  Waiver   from  the  Surface  Cementing
Requirements  for  Rule  Authorized  Class   II  Enhanced  Recovery  Wells   in  the
Springfield North Unit.
N. H. Ginest, Sr. Regulatory Engineer
Mobil Oil Corporation
J. V. lerubino, Operations Engineer
Mobil Oil Corporation
                                      ABSTRACT
On July  20,  1986 the Region V office of  the  EPA  issued a casing and cementing
policy for all  Class II injection wells  to  provide  guidance to its UIC permit
writers.   Mobil's  rule authorized  Class  II  enhanced  recovery wells  in  the
Springfield  North  Unit  (SNU)  do not meet  the surface  cementing requirements
set  out  in  the subsequently promulgated  40 CFR §  146.22 (b) and § 147.754 (b)
and, under the aforementioned Region V casing and cementing  policy, Mobil would
be  required  to  squeeze  cement to  isolate  USDW's.   The high  costs  and risks
associated with  squeeze  cementing  the 35  to 40 year old  injection wells in the
SNU  would  force Mobil  to  abandon  this  waterflood  project.    In  order  to
demonstrate that USDW's are being adequately protected under existing operating
conditions, evidence was collected which  included cement  bond logs, radioactive
tracer surveys,  cyclic  activation  logs  and pressure  tests.   This evidence was
submitted in a waiver  request  to satisfy  the burden of  proof for protection of
USDW's which  is  placed on the operator.  It  should  be noted that the costs of
gathering  evidence   to  illustrate  protection  of  USDW's can  easily  reach  an
amount which  could  make a mature waterflood  uneconomic.  Should the economics
of compliance  dictate  that  Mobil  abandon  its SNU, approximately 32,000  barrels
                                      -535-

-------
of recoverable  oil  will  be  left  in  place.   Not only  will  foregone production
in cases  such  as  this  be detrimental,  but  rising compliance  costs  will  make
many secondary  recovery  projects much  less  economically attractive  and fewer
operators  will   be  willing  to  make  the increased   investment  necessary  to
recover secondary reserves.
                                      -536-

-------
                                    INTRODUCTION

Examination of a typical injection wellbore  configuration  for existing or rule
authorized Class  II  wells, as shown  in  Figure No. 1,  reveals  two areas where
the cement and/or  casing may  not meet the EPA's  construction requirements for
Class II injection wells.   The areas  in question are:

     1.   the  area through and  above  the  injection  zone;  there may  not  be
          sufficient cement to fill the  casing/wellbore annulus to a point 250
          feet above the injection zone, and

     2.   the area from the surface  to the  base  of the USDW's; surface casing
          and cementation  may  not be  sufficient to isolate all USDW's.

In  existing  fields  which were  developed  prior  to  enactment  of the  Safe
Drinking  Water  Act,  these  conditions  will  generally exist  on  a field  or
area-wide  basis  since,  during development,  drilling and  completion practices
would have remained relatively uniform.

By  monitoring  and  utilizing  available  technology,  operators   can  show  on  a
case-by-case  basis  that  the  USDW's  are  being  adequately   protected  from
contamination  in  a specific  area  under existing  operating  conditions.   This
paper  summarizes  Mobil's   attempt  to  provide  the  EPA  with the data  and
information required to  illustrate that USDW's are  being  adequately protected
in the Springfield North Unit  (SNU).
                                      -537-

-------
                                    FIELD HISTORY

The Springfield  North  Unit (SNU) is  located  in  Posey County, Indiana, and the
field was  discovered with  the drilling of  the  Highman Heirs No. 1 (renamed as
the SNU  No.  30) on June  4, 1946.   The unit contains  approximately 970 acres
upon  which  there  are  currently   47  wellbores  capable  of  production  or
injection.  The producing reservoir is the Palestine Sandstone.

SNU waterflooding operations began  in February  of 1963 and there are currently
13  wells  permitted by rule for injection.  A  field  map  is shown  in  Figure
No. 2.
                     INJECTION WELLBORE CONFIGURATION IN THE SNU

Figure No. 3 illustrates  the  typical  configuration  of an injection well in the
SNU.     The   stratigraphic  succession  of  geologic   formations   with  their
approximate thicknesses  is set  out  on  the left  side  of  the wellbore.   The
dashed line  represents surface  casing which was run  to various  depths  up  to
125' on the injection  wells in the  SNU.   In all cases where surface casing was
run,  it   was   cemented to the  surface.    Although  there  is  little  or  no
information available  as   to  how deep sands which  could be  defined  as USDW's
occur, it is generally accepted  that  the  USDW's run to at least the top of the
West Franklin limestone.   The injection wells  in the SNU do not meet the EPA's
surface cementing  requirements  because surface casing setting depths  are not
sufficient to  cover  all  the  sands  classified   as USDW's.   It is  important  to
note that when  these wells were  permitted by   rule  and  converted  to injection
                                      -538-

-------
service the  definition  of  a  USDW was quite  different from  that  contained in
the SDWA.

During  initial  completion  of  the  injection  wells,  cement was circulated up
from the  base  of the long  string  casing  into the annulus  between  the wall of
the  hole  and  the outside  of  the  casing.   Cement  tops  in  this  casing/hole
annulus range  from approximately 366  feet to 1271  feet  above the  top  of the
injection  interval.    Cement  tops were  calculated  using  80%  of  the  volume
circulated in the casing/hole annulus.

               UIC REGULATIONS PERTAINING TO THE SITUATION IN THE SNU

Pursuant  to  §144.22(b),  existing Class  II  enhanced recovery  wells  in Indiana
must comply  with casing  and  cementing requirements  by June 25, 1987.   These
casing  and  cementing requirements  are set out  specifically for the  State of
Indiana in §147.754(b).   Mobil  is requesting a waiver for the 13 existing Class
II enhanced recovery wells  in  the  Springfield North Unit from the requirements
in §147.754(b)(l)(i)  and (ii) which state that the USDW's must be protected by:
"Cementing surface  casing  by  recirculating the  cement to the  surface  from a
point  50  feet below the lowermost  USDW;  or  isolating all  USDW's  by placing
cement between the outermost casing and the wellbore."

Under  provisions  in §144.16(a),  the Director  may  authorize  less  stringent
requirements for  construction  than those  required  in  the  previously  mentioned
sections.     In  Mobil's  SNU cementing waiver  request  to the  EPA,  data and
evidence  were  compiled  and  submitted   to  justify  variances  from  required
surface cementing standards.
                                      -539-

-------
EVIDENCE GATHERED TO ILLUSTRATE THAT USDW'S ARE BEING ADEQUATELY PROTECTED



                              FROM INJECTED FLUIDS







   A.   Adequate cementation above the injection interval  in the casing/



        hole annulus.  All  thirteen (13)  injection  wells  have  approximately



        366  feet to  1271  feet  of cement  coverage  above  the  top  of  the



        injection interval.  All  injection wells have more  than  250  feet of



        cement  coverage  which  is  considered  sufficient  as   required  in



        §147.754(b)(2).







        Cement bond logs were run on SNU Wells No. 2 and 14 and  confirmed the



        calculated values for cement tops.







   B.   Radioactive tracer surveys.   Radioactive tracer  surveys provide  an



        effective means  for  locating and  evaluating  leaks  in  the  casing,



        tubing and/or packer and  channeling behind the casing.   The  primary



        advantage of  a  radioactive  tracer survey  is  that it  is run  during



        injection operations  and  can  therefore  provide  a clear picture  of



        what is  taking  place  in the well  under  actual  operating conditions.



        Radioactive tracer surveys were run in Wells No. 2 and 14.  Both logs



        indicated injected  water  to be  entering  the Palestine zone with  no



        evidence of upward channeling behind the casing.
                                    -540-

-------
     Noise  and  temperature  logs  can  also  be  run  separately  or  in
     combination  to  detect  tubing  and/or  casing  leaks  and  also  fluid
     channeling in the cement sheath  behind  the  casing.   Neither of these
     logs were run  in  the SNU  injection  wells  because  they were  all
     cemented adequately above the injection interval.

C.   Mechanical integrity pressure testing.    Pressure tests,  which  were
     witnessed  by  EPA  field  inspectors,  were  conducted  on  all   the
     injection wells in  the SNU.   This  testing demonstrated  the  tubing,
     casing, and  packer in the  injection  wells were  mechanically  sound.

D.   Wellhead injection pressures below the formation fracture pressure.
     All  injection wells are operated  with wellhead  injection pressures
     below the calculated fracturing  pressure.   These calculated fractur-
     ing  pressures  are  based  on a  frac  gradient  of 0.8  psi/ft and  an
     injection fluid  specific  gravity of 1.015.

     It should be noted  that  the formation  fracture  gradient  is actually
     approximately 0.98  psi/ft   as   is  evidenced  by  the  instantaneous
     shut-in pressure (ISIP) data from a stimulation  treatment on  the No.
     14  well.   Mobil   has   recently   submitted   a  request  for  increased
     allowable  injection  pressure  in this  field  supported by  copies  of
     actual  treatment reports which  show treating  pressure  and ISIP data.
                                 -541-

-------
E.   Overlying formations prevent upward migration of injected water.
     The Palestine  Sandstone is  overlain  by several limestone  and  shale
     beds which consist of several impermeable layers and serve to prevent
     upward  migration of  the  water  injected  into  the Palestine  zone.
     These  beds  are  illustrated  in  the  stratigraphic  section  on  Figure
     No. 3.
      EVIDENCE GATHERED TO ILLUSTRATE THAT INTERMINGLING OF FLUIDS
                        IN USDW'S IS NOT OCCURRING

A.   Monitoring of long string casing/surface casing annulus shows no
     pressure changes or fluid movement.   Mobil  currently  monitors  the
     aforementioned casing/casing annulus on a  weekly  basis and  has  found
     no indication of a pressure change or fluid flow.   This is a critical
     monitoring point  which allows  an operator to  sense any changes  or
     disturbances  in  the  freshwater zones not  covered  by surface casing.

     There are two likely  situations which could  exist in the long string
     casing/hole annulus which are as follows:
                                 -542-

-------
          1.    Since  the casing was  run in the  open  hole while  it was  filled
               with  drilling mud, the  casing/hole  annulus will be filled  with
               the fresh water,  solid-based  drilling  fluid.   The drilling fluid
               is  more  dense  than  fresh  water  and  will  exert  a  hydrostatic
               pressure  due to the column of  drilling fluid that will  tend  to
               keep   formation   fluids   out  of  the   casing/hole   annulus   and
               discourage  intermingling of formation  fluids.

          2.    If  after standing  in  the casing/hole  annulus for  several years
               the  drilling fluids  were to dehydrate,  it  is  unlikely  that  a
               void   would   exist  adjacent  to  the  production   casing.    The
               overburden  stresses present in the geologic column will  tend  to
               force  the formation to compact  around  the pipe.   This  would  also
               tend  to  prevent  any  fluid movement  from occurring adjacent  to
               the  long  string  casing.

     B.    Pulsed Neutron Logs  show no evidence of fluid  movement behind the
          casing.  Arnold  and  Paap   described a  water-flow monitoring  system
          (referred  to  as  the  Cyclic Activation  or CA  log)  based on  a nuclear
          activation  technique  in which water  is  irradiated with neutrons emitted
          by  a source  in   the  logging sonde.   These  neutrons  interact  with
       Arnold,  D.  M.  and  Paap,  H. J.,  Quantitative Monitoring of  Water Flow
Behind and in Wellbore Casing, JPT, January 1979.
                                     -543-

-------
               oxygen nuclei  in the water  to produce  the  radioactive  isotope
               nitrogen-16.     N  decays with  a  half-life of 7.13  seconds  and
               emits gamma radiation during  decay.   If water flow is occurring
               outside the casing,  its  velocity can then be  computed  from  the
               energy and  intensity response of  the  two gamma  ray detectors
               mounted  in  the  logging   sonde.    Basically,  the  difference  in
               gamma  ray  count  rates   (above  the  normal  background  gamma
               emission) of  the two detectors is  used to  calculate a  linear
               fluid velocity.

               This water  flow detection system  is similar  to  various  radio-
               active tracer  techniques, but  is  unique in  the  sense that  the
               tracer,   N is "manufactured" in the water.  This eliminates  the
               need to perforate the casing  and  to inject tracer material  from
               an external  source.

               The  CA  log  was  run  on   SNU  Well  Nos.  14  and 17.   The CA  log
               analysis  obtained from these  two  logging runs  indicated  that  no
               fluid flow was occurring  outside the casing.
                     ECONOMIC IMPACT OF COMPLIANCE COSTS

There are  several  different cases  or  scenarios which could be  used  to attain
compliance for the injection wells  in  the  SNU.   For the following cases, costs
and the  resulting  unit  economics  are  listed  which illustrate  the  associated
                                      -544-

-------
economic  repercussions.   The  economic  indicator referred  to  in each  of the
following cases  is  payout.   Payout  is  defined as the  time  required to recoup
all investment costs.  Economic assumptions  include  an initial  unit production
rate of 35 BOPD and an annual decline rate of 11%.
CASE I
Case  I  is an example  of the work  completed  to date  in  the SNU.   It entails
running two (2) cyclic activation  (CA)  logs  on a representative sampling basis
at  a  cost of $7,000  ($3,500/well).   Economic  runs  indicate a  payout on this
$7,000 investment would  occur in approximately 0.4  years.   The SNU can support
the compliance-related investment associated with Case I.
CASE II
Case II  assumes  that  the EPA would not accept  Ipgs  run  in sample wells for an
area-wide  waiver  and  would  require  Mobil  to  run  CA  logs  in  all  existing
injection wells  to obtain a  waiver  for the entire  unit.    Running  CA logs on
all thirteen  (13)  injection wells  would  require a total  investment of $45,500.
Economic runs  indicate  a payout on this  investment  never  occurs.  Mobil could
not afford  to run CA  logs  on all  SNU  injection wells  and still  maintain a
profitable operation.
                                      -545-

-------
CASE III

Case III  is the  scenario most  likely to  occur should  Mobil  be  required  to
squeeze cement  to  isolate the  USDW's.   In order  to realistically  estimate
costs  involved  in  squeeze  cementing  the  mature injection  wells in  the  SNU,
costs were gathered to perform the following work:

     1)   Four  (4)  of the  thirteen  (13)  squeeze jobs would proceed with  no
          problems and cement  returns to the  surface  would  be obtained  after
          the first squeeze attempt,

     2)   Five (5) of the injection wells  would require a  cement bond log  after
          the initial cement squeeze and have to be  reperforated and resqueezed
          two (2) more times  before isolation of USDW's  could  be obtained and

     3)   Four (4) of the injectors would  require not only the work and expense
          incurred in  1)  and  2)  above, but also would require new production
          casing  strings  (liners)  due  to  casing   failures  during  workover/
          squeezing  operations.    The  new   liners  would  have  to  be  run  and
          cemented if the  original  long string casing collapsed.   The risk  of
          casing collapse  is  very high when  exerting  the high pump  pressures
          required to break circulation to the surface.
                                      -546-

-------
The investment required to complete the work described in the Case III scenario
is $286,000.   Economic  runs  indicate that  a  payout of  this  investment never
occurs.

The three economic  cases  are  summarized in  Table  1.   Table 1  illustrates that
the only case  under which Mobil can  economically  justify the  costs associated
with  compliance  is  Case  I.    A  waiver,  based  on  a  showing  of  adequate
protection  of  USDW's  under  current  operating  conditions,  would  have  to
include  running  CA logs  on   a representative  sampling basis  to  illustrate
unit-wide  compliance.     It  should  also  be  npted   that  Mobil  or any  other
company, for that matter, will not operate  a  project at  a  loss  with income to
be made  up  in  another producing area.  Each project  must stand  on its own and
be economical or  it will be abandoned.
                                      -547-

-------
                                   SUMMARY







Commercial   oil   production  in  the  SNU  is  dependent  entirely  upon  water



injection.   Should  the  economics of compliance dictate  that  Mobil  abandon the



waterflood  in the SNU, approximately 32,000  barrels  of recoverable  oil will be



left in place.   Not only would foregone production in cases like Mobil's SNU be



detrimental, but  the  rising costs  of  compliance  could have  a  major  effect on



oil  production   nationwide.    As  compliance  costs   rise,  secondary  recovery



projects will   become  significantly  less  economically  attractive.    Fewer



operators will  be willing to make the increased investment necessary to recover



the  additional   reserves  left  in  place  after  primary  recovery  has  been



completed.
                                      -548-

-------
                                 CONCLUSIONS

1.   It is  important that  the  EPA and  state regulatory  agencies  approve the
     use  of available  technology  to gather data  which  can  show  injection
     operations  are  not  contaminating   USDW's.     This   available  technology
     includes logging techniques.

2.   It is equally  important that  the EPA respond to Mobil's waiver request in
     a timely manner.  All  enhanced recovery wells in Indiana must comply with
     Class  II  casing and  cementing  requirements  by  June  25, 1987.   Not only
     would a timely  response allow Mobil  sufficient time  to make plans for the
     future operation of  the  SNU,  but it would  also provide guidance to other
     operators  that will  be  required to  attain  compliance  with construction
     requirements.

3.   As is  the  case in  the SNU,  squeeze cementing  to  isolate USDW's  will not
     be economically viable in  many  of the  existing  mature waterfloods in the
     United States.
                                      -549-

-------
                                    TABLE 1
                       SUMMARY OF THREE COMPLIANCE CASES
COMPLIANCE
RELATED
WORK
INVESTMENT
REQUIRED
PAYOUT
(YRS.)
CASE I
2 CA LOGS RAN ON
REPRESENTATIVE
BASIS
$  7,000
   0.4
CASE II
CA LOGS RAN ON
ALL INJECTORS
IN UNIT
$ 45,500
DOES NOT
PAYOUT
CASE III
SQUEEZE USDW'S
IN ALL INJECTORS
IN UNIT
$286,000
DOES NOT
PAYOUT
                                      -550-

-------
Noel  Ginest  is  a Senior  Regulatory  Engineer  with  Mobil  Oil  Corporation  in
Denver, Colorado.   He  received a  BS degree  (1981) in  Petroleum Engineering
from  the  Colorado School  of Mines.   Mr.  Ginest was  employed  by Mobil  in Lake
Charles,  Louisiana,  in  1981  as  an Operations  Engineer and worked  in  Mobil's
Gulf  Coast  Operations  until  being  transferred  into   the Environmental  and
Regulatory Affairs  Department  in   1985.    He  is  a  member  of the  Society  of
Petroleum Engineers.

James  lerubino  is   an  Operations  Engineer  with   Mobil  Oil  Corporation  in
Crossville,  Illinois.   He  received a BS degree  (1982) in  Geology  from Rider
College,  where  he   was  published  by the  GSA  and  various  other  journals
following  his  research  on sedimentation  patterns  on  the  continental  shelf.
Mr. lerubino also holds an MS degree   (1985) in  Petroleum  Engineering from the
Colorado  School   of  Mines.    He  is   a  member  of  the Society of  Petroleum
Engineers.
                                      -551-

-------
             INJECTION
          PRESSURE GAUGE
        ANNULUS
    PRESSURE GAUGE
SURFACE  CASING/
INJECTION CASING
    ANNULUS
PRESSURE GAUGE
         POTABLE
          WATER
       NON-POTABLE
          WATER
     UNDIFFERENT1ATED
           ROCKS
       CONFINING BED
       INJECTION ZONE
   INJECTED
    LIQUID
             >WELLHEAD
1^ ANNULAR
                                          ACCESS
      SURFACE  CASING
                                            CEMENT
   INJECTION TUBING


   LONG STRING CASING




   ANNULAR FLUID


   CEMENT

   PACKER
    PERFORATIONS
      FI0URE 1.  TYPICAL INJECTION WELLBORE CONFIGURATION FOR

                RULE AUTHORIZED CLASS II  WELLS

                              -552-

                                                     «L-P«D-«7-«l4.23.a

-------
              Rl 4W
                            13
       6
                          A
                          5
                  20
       f§   e    « »|§     *
       7   16   15  14    13
                                           X
                                                                RI3W

18
             19
                   20    21
                           24
                              22    23
     | 35    34    33    32
            36     37
                                   30
                                   38

                                   X
                                   5
                24
25
                                         29
                                                 28
                *39   40
                <§>     «
                42     41


                49     48
                                                      26
                                                       27
                                                     46    47
                                                     43
                                                     44
                                                        Jj
LEGEND:

  • PRODUCING OIL WELL

 ^ ABANDONED OIL

 -6- DRY HOLE
® INJECTION WELL

j§f ABANDONED INJECTION WELL
FIGURE  2.  SPRIK«FIII.B NORTH UNiT FIELD
                                                     Mobil Oil Corporation
                                                     DENVER AFFILIATE
                                                               DATA MAP
                                                      SPRINGFIELD NORTH  UNIT
                                                         POSEY CO.,  INDIANA
                                                    DRAWN  C . ARCHER
                                                    CHECKED CHECKED
                                                               SCALE  NONE
                                                               DATE  03/02/37
                                                                        DWG NO.
                                                                           IN-PRG-DM-
                                      -553-

-------
  APPtOX.
THICKNESS

   aoo-
4V-TO'

            SURFACE
           •AND, (HALES *
           INTEHSEDDCD
           (AMD * *HAUS


 100- 10V   CLOH  « NCOIIIA (MAUI
 •-12'
e-tas*  or  SUMACI
CASINO  (CIBINT
CUICULATU TO
SUWAd V SUWAd
CASINO  MISMT)
                                                           TVSINO- CASINO
                                                           ANNUtVS FILLED WITH
                                                           COOMSION INNISITID
                                                           a- 1/i  CIMNT. LINED
                                                           MMCTIOII TVMNO
                                                               CEMENT TOPS SOS-taTl'
                                                               ASOVE THE INJECTION
                                                               INTIBVAL
            •mi niie w * rrrnu.
            m >rtan« •IIIJIM acufci,
  PACHEB SET AT AN
  AVEBAOE DEPTH OF I MO1

  PDODUCTION CASINO SET
  AT AN AVEBAOE DEPTH
  OF isso* 
          FIOURE X.   TYPICAL INJECTION  WCtLIORI  CONFIQURATION IN
                       THE SPRINQFIELD  NORTH UNIT
                                                                                           •C-U-A-Gft-Ul i 3( .2
                                       -554-

-------
                                    TABLE  1
                       SUMMARY OF THREE COMPLIANCE CASES
                       COMPLIANCE
                        RELATED                 INVESTMENT               PAYOUT
                         WORK                   REQUIRED                 (YRS.)
CASE I                2 CA LOGS RAN ON          $  7,000               0.4
                      REPRESENTATIVE
                      BASIS
CASE II               CA LOGS RAN ON            $ 45,500            DOES NOT
                      ALL INJECTORS                                 PAYOUT
                      IN UNIT
CASE III              SQUEEZE USDW'S            $286,000            DOES NOT
                      IN ALL INJECTORS                              PAYOUT
                      IN UNIT
                                     -555-

-------
     A METHOD TO CONVERT  MULTIPLE-SHOT SECTION OPENHOLE
COMPLETIONS INTO CASED-HOLE  COMPLETIONS WITH ZONAL ISOLATION

                           Authors

                 C.D.K. Darr and  E.K.  Brown
      Conoco, Inc. & J.R.  Murphey,  Halliburton Services
                           Presented

                              at



       THE UNDERGROUND  INJECTION PRACTICES COUNCIL\EPA
       INTERNATIONAL  SYMPOSIUM ON SUBSURFACE INJECTION
                      OF  OILFIELD BRINES
       THE ROYAL SONESTA  HOTEL,  NEW ORLEANS, LOUISIANA
                         MAY  4-6,  1987
                                 -556-

-------
                                Introduction




     The "Puddle-Pack" completion process  was  developed  to convert old




wellbores, not originally designed  for  fluid  injection,  into usable




wellbores for fluid injection.  This  process  was  applied to Conoco's MCA




Unit to prevent  fluid  loss  and  provide  zonal  isolation in injection




wells.  Furthermore, this process has been used on producing wells to




increase productivity  by selective  stimulation.   The MCA Unit,  located in




southeastern New Mexico, is currently under waterflood and has  tertiary




oil recovery potential (see Figure  3).




     Production  within the  unit is  from the Grayburg Sixth sandstone and




the San Andres Upper Seventh, Upper Ninth  and Lower Ninth Massive dolomite




formations.  Formation depths range from 3650 to  4050 feet (see sample log




Figure 2).  Most of the 366 active  wells are  over 30 years old  and were




open hole completed over a  300  foot interval.  Most wells have  at least




two and often three shot sections which generally exceed 20" in diameter




(Figure 1).  These  factors  have combined to make  remedial attempts very




difficult.




     The feasibility of implementing  a  carbon dioxide miscible  flood




within the unit  is  presently being  evaluated.  A  major operational,




environmental, and  economic concern was whether old well problems could be




repaired to maximize C02 efficiency during C02 and post-flush




injection.  Wells drilled four  decades  ago without any thought  of use for




injection could  not be expected to  prevent injection fluid loss and




provide zonal isolation.  These conditions are not tolerable during CC>2




injection because only a small  loss of  CC>2 would  significantly reduce




the profitability of the project;  thus  zonal  isolation would be required.




A liner with a simple  cement  job  would  not satisfy this requirement since




it would be impossible to perforate through  the  thick cement sheaths  in






                                  -557-

-------
Page No .  2









the shot hole sections.  Therefore,  a  different method  has  to  be  developed




to convert the shot hole wells  to cased hole  completions  with  zonal




isolation.  Otherwise  replacement wells for  all the  existing  open hole




injection wells would  have  to be drilled  and  the  old  wells  plugged and




abandoned.  An estimated 14 million  dollars  could be  saved  if  the current




injectors would not have to be  replaced with  new  wells.




                                Discussion









     The problem of injection fluid  loss  and  zonal communication  in  old




wells (40 years old or greater) has  been  recognized  for many  years.




Injection fluid control has been attempted by running and cementing  liners




across the shot open hole  section.   These attempts failed because




conductivity with  the  formation could  not be  re-established after




perforating the liner  and  acidizing  in the shot open  hole section.  This




is due to the fact that the cement,  after completely  filling  the  shot  hole




could not be totally penetrated.  Other attempts  at  casing  the shot  open




holes failed because zonal  isolation was  not  achieved.  The "Puddle-Pack"




was designed to solve  these problems.









                            Criteria  for Success of the




                            "Puddle-Pack"  Completion









     The four requirements  listed below had  to be met for the




"Puddle-Pack" process  to be considered successful.
                                   -558-

-------
Page No. 2









the shot hole sections.  Therefore,  a different  method has to be developed




to convert the shot hole wells to cased hole  completions  with zonal




isolation.  Otherwise replacement wells for all  the  existing open hole




injection wells would have to be drilled  and  the old wells plugged and




abandoned.  An estimated 14 million  dollars could be saved if the current




injectors would not have to be replaced with  new wells.




                                Discussion









     The problem of injection fluid  loss  and  zonal communication in old




wells (40 years old or greater) has  been  recognized  for many years.




Injection fluid control has been attempted by running and cementing liners




across  the shot open hole section.   These attempts failed because




conductivity with the formation could not be  re-established after




perforating the liner and acidizing  in  the shot  open hole section.  This




is due  to the fact that the cement,  after completely filling the shot hole




could not be totally penetrated.  Other attempts at  casing the shot open




holes failed because zonal isolation was  not  achieved. The "Puddle-Pack"




was designed to solve these problems.









                           Criteria  for Success  of the




                           "Puddle-Pack"  Completion









     The four requirements listed below had  to be met for the




"Puddle-Pack" process to be considered  successful.
                                  -559-

-------
Page No.  3









1)  Zonal isolation.  Zonal  isolation  aids  in  the  stimulation  of




    individual zones and the profile control of  injection  fluids.




2)  No fluid loss to non-pay intervals.   Injection  fluid  loss  to  non-pay




    intervals can cause collapsed casing  and in  extreme  cases  surface




    waterflows.




3)  No loss in injectivity.  Based  upon a bbl/psi/NEP  criterion,




    injectivity after the "Puddle-Pack" process  should be  greater  than  or




    equal to (within 15%) the  injectivity before the "Puddle-Pack".




4)  Capability of running an injection profile log.  To  properly manage a




    waterflood or tertiary recovery project the  injection  profile  must  be




    regularly monitored.  Therefore, it is  important that  an interpretable




    injection profile log can  be run.









              Requirements of  the Resin Coated Fill Material









     Resin coated fill material used in the "Puddle-Pack"  process  must




have the properties of (1) permeability,  (2) strength, (3)  chemical




inertness to formation fluid and injected fluid, and (4)  feasible  cost.




Additional desirable features  are (1)  inertness  to  projected treating




chemicals and (2) ease of handling.




     PERMEABILITY.  A reasonably wide  range of permeability is acceptable




provided (1) communication to  the formation is not  lost  or  restricted and




(2) fluid loss during cementing does not  result  in  excessive cement




dehydration.  Vugs and mud channels in the  fill  material  are unacceptable,




therefore, systems requiring long reaction  or  settling times and  materials




of widely varied densities were not considered.






                                 -560-

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Page No. 4




     STRENGTH.  An upper strength  limit  of  5000-6000 psi is suggested for




maximum penetration rates based on  experience  with drilling cements (see




Table 1).  Although the compressive strength  of the native formation is




approximately 9700 psi, fill material  need  only be strong enough to hold




its form while being drilled out.




     CHEMICAL INERTNESS.  Resin coated fill material must be chemically




inert to formation crude oil and  formation  brine as well as the




combination of injected C02 and brine.  This  combination forms carbonic




acid under downhole temperature and pressure.   Inertness to common




workover fluids is also desirable.   Fluids  used on the MCA Unit project




include hydrochloric acid, mutual  solvent  flushes, and aromatic solvent




flushes.




     EASE OF APPLICATION.   Ideally, synthetic  formation slurries can be




placed  with conventional bulk  mixing equipment and should require no




unusual steps in  either preparation or cleanout.  Rapid cure time and easy




drillout are desirable qualities.









               Selection and Optimization  of  Fill Material









     Two resin systems were evaluated  to determine the optimum fill




material for the  project.   The first system has been widely used in resin




cementing of disposal wells where  highly corrosive fluids could attack a




conventional cement-^.  The  second  system has  been widely used  for




consolidated pack sand control jobs on the Gulf Coast and West Coast.




     Both systems proved  to have  good chemical resistance, but the Gulf




Coast system was  chosen  for its better retained permeability.
                                   -561-

-------
Page No. 5




     With the system selected, optimization  of  permeability was approached




in a manner similar to  that used  in  gravel packing;  i.e.,  intermixing of




fine sand with the pack  sand  to  achieve  the  desired  porosity and




permeability1.  Table 2  demonstrates this  effect  when 70-170 mesh sand




is mixed with 10-20 rounded pack  sand  and  20-40 mesh angular sand.




     Eventually, the method selected was to  mix small matrix sand (70-170




mesh) and graded silica  flour.   This mixture yielded the  desired




permeability, a more uniform  graduation, and minimal separation by




sedimentation.




     Since any wellbore  is  an excellent  sedimentation column, a mixture




with a wide range in particle size would have the tendency to settle out.




Introduction of a gelled carrier  fluid moderately reduced  this tendency




but did not eliminate it.   Experimentation with laboratory samples showed




that the addition of the selected resin  greatly reduced  the tendency to




form sediment.  Microscopic examination  showed  that  the  fine grained




silica flour clustered  about  on  the  larger grains of resin coated sand.




Further experimentation  proved  that  the  order of  addition  of ingredients




influenced the character of the  mix.




     The sequence used  is as  follows:




     1.  Add the large  sand to  the gelled  carrier fluid.




     2.  Then add the resin,  which coats the large sand  grains and leaves




         little resin in the  carrier fluid phase.




     3.  Then add the silica  flour.   The silica flour particles are not




         initially coated,  but  rather attach themselves  to the larger




         grains, and are then coated with  resin.
                                   -562-

-------
Page No.  6




     Contrary to the initial assumption  that  the  fine silica flour would




substantially increase the requirement for  resin  due to increased surface




area of the flour over the 10-20 mesh  sand  used  in control  experiments,




the increase was only on the order of  20%.  Final strength  and




permeability of the resin coated gravel  pack  depend upon optimization of




the resin volume.




     A minimal resin level is desirable  to  force  the silica flour to




cluster on the sand grains and since resin  is the single most  expensive




ingredient of the fill, keeping the minimum level is even more desirable.




     Gelling agent level was the final variable  in the fill formula.  The




proper gelling agent in a fill of  this type must  be sufficient to suspend




the material, but provide no additional  restriction to injection.




Functions of the gelling agent are (1) to  suspend the sand  and silica




flour in bulk equipment before pumping,  and (2)  suspend the slurry




downhole while the slurry is being pressure packed.




     The final product showed uniform  permeability from 1.8 to 8 darcies




with most falling around 6 darcies (see  Table 3).









                            Bulk Mixing  Tests









     Large scale mixing tests were performed  to  determine pumping




characteristics of the 14 Ib/gal optimized  slurry as developed in the




laboratory.  The procedure was as  follows:




     1.  A clean 12 bbl conventional  stirring blender was loaded with 3




         bbls water and gel.  Ambient  temperature was 35° F.
                                   -563-

-------
Page No. 7




     2.  An addition of 1 cu  ft 70-170 mesh  sand  was made.




     3.  The resin (less  than 1 gal/cu  ft  sand) was  then  added.




     4.  Then 1 sk of  silica  flour  (1 cu  ft)  was  added.




     5.  The slurry was then  circulated  for  1 hour with  a standard




         centrifugal pump and triplex pump.   The  slurry  properties




         resembled a cement slurry.




     6.  The sample was withdrawn and breaker was added  to  the sample.




         Break time was slow  due to  cold  temperature.




     7.  To stimulate  bottom  hole temperatures, samples  similar  to No.  6




         were cured in an 80° F water bath which  resulted in a 1200 psi




         compressive strength within 24 hours.









                          The Remedial  Procedure









     MCA Unit No. 61 was  identified  as  a  problem  well  for injection fluid




loss control in the MCA Unit. Past  injection profile  logs  indicated




abnormal injection fluid  distribution and  possible  fluid  loss to




stratigraphically higher horizons.   After  reviewing  several wellbores  in




the MCA Unit, MCA Unit No. 61 was identified  as a worst  case condition due




to the three large shot holes, hole  sloughing,  and  the large volume of




resin coated gravel required  (see Figure  1).   Thus,  it was  felt  that if




MCA Unit No. 61 could  be  successfully repaired using  the  "Puddle-Pack"




process, it would be applicable to  the  other shot open hole completions in




the MCA Unit.




     The following steps were taken  to  convert MCA Unit  No. 61 to a cased




hole completion with zonal isolation:
                                  -564-

-------
Page No. 8




1)  To prepare the wellbore  for  squeeze  cementing the production casing




    shoe, all injection equipment was  pulled  from the well and the shot




    open hole was plugged back to within 20'  (35701)  of the production




    casing shoe with crushed  oyster  shells.   The volume of crushed oyster




    shells required to fill  the  open hole was recorded to verify the




    volume of resin coated gravel required.   Crushed  oyster shells were




    used because they were tested to be  96%  acid soluable.  Therefore,




    when the shells were drilled out,  the oyster shells remaining in the




    open hole section could  be removed with  acid.  A 100 Ib quick setting




    cement plug was then placed  on  top of the crushed oyster shells @




    3570' .




2)  The production casing shoe at 3550"  was  cement squeezed with 20 sacks




    of  Class "C" cement with 2%  CaCl2  and 30 sacks Class "H" thixotropic




    cement.




3)  After WOC time, the cement and  oyster shells were drilled out to a TD




    of  4024'.  The shot open hole sections were then jet washed.  Jet




    washing  uses a sub above the bit that has an orifice which directs




    hydraulic impact force towards  the open  hole walls.  The hydraulic




    impact force removes scale and  loose formation rock from the shot open




    hole sections.




4)  The wellbore was then prepared  for the resin coated gravel placement




    by:




    a)  Rattling and pickling the tubing by spotting 32 bbls of a mutual




        solvent and scale converting chemical solution in the open hole




        section for 13 hrs.   Every  two hours after the chemical solution




        was  in place,  the downhole  assembly was worked up and down 60'.
                                   -565-

-------
Page No. 9




        This would agitate  the  chemical  solution  in  the  open hole  section.




        The scale converter chemical was  used  because  samples from




        drilling scale bridges  in  the  well  had indicated the bridges  to be




        calcium sulphate  (CaSO^ scale,  which  is  only  moderately




        soluable in acid  without conversion.




    b)  The chemical  solution was  reversed  out and 37  bbls  of 15%  HC1




        treated with  scale  inhibitor was  then  spotted  in the open  hole




        section.  The workstring and bottom hole  assembly was stroked 60'




        after 30 minutes  of shut-in  time  to agitate  the  acid solution in




        the open hole.  The acid was then allowed to soak an additional 30




        minutes.  After the 1 hour soak  period, the  acid was reversed out




        of the hole with  233 bbls  of 8.4 Ib/gal KC1  water filtered to two




        microns.




        The pH of the circulating  fluid  was adjusted with clay stabilizers




        to 6.8.  It was important  that the  pH  of  the fluid  in the  wellbore




        be in a range of  6-8.   If  the  pH was  too  low,  the resin would




        prematurely harden, and if the pH was  too high,  the resin  would




        not harden.




        The mixing procedure was:   1)  50 bbl  of gelled brine (2% KC1, 40




        Ibs hydroxyethylalcohol/1000 gals)  was prepared; 2) 33.125 bbls of




        this gelled brine was actually used for mixing the slurry; 3)




        23,875 Ibs of sand, 209 gallons  of  resin, and  1375 Ibs of  silica




        flour were added  to the gel  in succession.   The mixing process




        took approximately  2 hours.




    c)  After circulating the 8.4  Ib/gal  KC1  water,  total depth was tagged




        at 4024' and  the  workstring was  picked up 10'  off bottom.
                                   -566-

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Page No. 10









5)  The resin coated gravel mix was  placed  in the open hole by:




    a)  Pumping 52 bbls of resin coated  gravel  slurry and displacing the




        slurry with 18 bbls of 8.4 Ib/gal KC1 water.   The calculated open




        hole volume was 37 bbls.  30%  additional  volume was calculated for




        slurry shrinkage  and  11% was calculated for excess open hole




        volume.  Laboratory work had indicated  that when the gel broke in




        the resin slurry,  a 30% volume reduction  occurred.  The 11^ excess




        volume was used due to jet washing  the  open hole after drilling




        out the oyster shells.  This jet washing  increased the shot open




        hole size by removing scale  and  loose formation.




        By displacing the resin coated gravel with only 18 bbls of 8.4




        Ib/gal brine, the tubing was left with  a  calculated overbalance of




        344 psi.  This overbalance allowed  the tubing to be pulled dry




        immediately after shutting down  the displacing pumps.  Initial




        pumping was at 2  bbl/min at  600  psi.




    b)  Immediately after displacing the resin coated gravel, the tubing




        was pulled 900",  150  psi was applied  at the surface, and the well




        was shut-in.




6)  After waiting on resin for 30 hours, the  resin coated gravel was




    drilled out to a total depth of  4024'  with 6-1/4" milled tooth bit.




    The weight on bit was 4000 Ibs  and the  penetration rate was 150'/hour.




    At  this point, the shot open holes were filled with the permeable




    resin coated gravel  and  a 0.375" sheath of permeable  resin coated




    gravel existed between the shot  sections in the wellbore.




    The intervals  from 3560'-3575'  and 3670'-3850' were underreamed to 7"
                                   -567-

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Page No. 11




    to remove the permeable  resin  fill  sheath  from above and between the




    shot sections.




7)  A 4-1/2", 10.5  Ib/ft,  K-55,  ST&C  liner  was run and cemented in place




    with 120 sxs of  a  50/50  Pozmix Class  "C"  cement mixture treated with




    fluid  loss additive.   The  density of  the  slurry was 15.5 Ib/gal.




    Centralizers were  used and  during cement  displacement,  no pipe




    movement was used.   The  minimum displacement rate was 6 BPM and the




    maximum displacement  rate  was  7 BPM.




8)  After  WOC time,  the  cement  and cement plugs were drilled out and the




    liner  top was tested  to  1200 psi.




9)  The well was then  logged with  a CBL,  CCL-GR and perforated from




    4005'-3890' and  3636'-3595'  with  a 3-1/2"  hollow steel  carrier gun




    loaded with 1 JSPF (see  Figure 4).   A total of 158 shots was fired.









                                 Testing









     The perforations  where  the shot  open holes existed were straddled




individually with bridge  plugs  and packers.  Injection rates and pressures




were recorded and the  intervals were  tested for communication.  The




testing revealed that  no  communication existed between shot sections and




injectivity had increased from 0.00403 bbls/psi/NEP to 0.00857




bbls/psi/NEP.




     After seven days  of  continuous injection, an injection profile and




temperature log were run. These logs revealed that 15%-28% of the




injected fluid was  entering  the Grayburg 6th,  10% was entering the
                                    -568-

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Page No. 12




San Andres Upper 9th and 72% to 75% was entering  the  San  Andres  Lower  9th




Massive.  The injection profile had changed dramatically  in  comparison to




the profile run before the "Puddle-Pack"  (see  Figures  5 and  6).   The




profile of MCA Unit No. 61 run after the  "Puddle-Pack" closely resembled




the injection profile of MCA Unit No. 257, a cased hole injector 3




locations to the east (see Figures 6 and  7).   An  injection profile  survey




run 7 months after the "Puddle-Pack", revealed that  the injection profile




had not changed significantly as compared to the  original injection




profile log run 7 days after the "Puddle-Pack" (see  Figure 8).




     After two weeks of injection, injectivity declined to  .0052




bbls/psi/NEP, still higher than the injectivity before the "Puddle-Pack".




After five weeks of continuous injection, the  injectivity stabilized  at




0.0052 bbls/psi/NEP.  The injectivity has been monitored  once  a  month




since that time.  Table 4 lists the injectivity for  MCA Unit No. 61.




     The cost to "Puddle-Pack" MCA Unit No. 61 was  approximately $141,000.




This represented a savings to Conoco of approximately $275,000 vs.  new




well drilling costs to achieve the same goals.




      Also, it is believed that potential exists  to  "Puddle-Pack" shot




open hole producing wells.  The economic  advantages  would be:




1.  Reduction of clean out frequency and  costs caused by  open  hole




    sloughing.




2.  Improved stimulation of producing wells by allowing mechanical




    isolation of pay horizons during stimulation.




3.  Reduction of chemical volumes required  to  stimulate  the  wells compared




    to  the volumes required to treat the  shot  open  holes.
                                   -569-

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Page No. 13




4.  Allowing more efficient beam  lifting  techniques by  placing  the  seating




    nipple below the producing horizon  instead  of  above the  producing




    horizon as in shot open hole  wells.









                               Conclusions
1.  A method has been developed  and  tested  to  convert  multiple shot




    section open hole completions  into  cased hole  completions.




2.  The "Puddle-Pack" method  has  provided  zonal  isolation  between shot




    sections in MCA Unit  No.  61.




3.  The "Puddle-Pack" method  has  controlled injection  fluid  loss  to  non-




    pay horizons in MCA Unit  No.  61.




4.  The "Puddle-Pack" process is  mechanically  and  economically feasible.




5.  Interpretable  injection profile  logs  can be  obtained  after an




    injection  well has been successfully  repaired  using  the  "Puddle-Pack"




    process.
                                   -570-

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Page No. 14









                             Acknowledgements









     The authors wish to thank Conoco  Inc. and Halliburton  Services  for




allowing the publication of this paper.  They would  also  like  to  thank  the




management and Engineering staff of  the Conoco, Hobbs,  New  Mexico,




Division office, for without their support and assistance the  work would




not have been done.




                        SI METRIC CONVERSION FACTORS




                        bbl x 1.589  873 E-01 = ra3




                        ft x 3.048 E-01 = m




                        gal x 3.785  412 E-03 = m3




                        Ibm x 4.535  924 E-01 = kg




                        Ibm/gal x 1.198 264 E+02 = kg/ra3




                        psi x 6.894  757 E-03 = MPa




REFERENCES









1.   Saucier, R.  J.:  "Gravel Pack Design Considerations", SPE  4030,




     presented at the 47th Annual Meeting of the  Society of  Petroleum




     Engineers,  San  Antonio, Tex., Oct.  1972.




2.   VanPoollen,  H.  K.;  Tinsley, J. M.;  and Saunders, C. D.:  "Hydraulic




     Fracturing:  Fracture Flow  Capacity vs. Well Productivity:, paper




     number 890-G presented at the 32nd Annual Meeting of the Society of




     Petroleum Engineers, Dallas,  1957.




3.   Cole, R. C.:  "Epoxy Sealant  for Combatting  Well Corrosion",  SPE 7874




     presented at the  SPE International Symposium on Oilfield and




     Geothermal  chemistry, Houston,  TX.,  Jan.  1979.






                                  -571-

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Page No. 15

                                 Table  1

    Compressive Strength of Resin Consolidated Formation  Exposed  to  a
                     Saturated CC^-Water  at  120°  F

                                                  Compressive
                Test                              Strength,  psi
              First Day                               1675
               8 days                                 1675
              16 days                                 1835
              34 days                                 1910

                                 Table  2

        Permeability of Mixtures of  70-170 Mesh  Sand  in  10-20 and
                              20-40 Mesh Sands

                                      	Permeability  in  Darcies
                                        10-20  Mesh           20-40  Mesh
                                       Rounded Sand         Angular Sand
       0% Fine Sand Added                  310                 121
      10% Fine Sand Added                   90                  70
      20% Fine Sand Added                   60                  25

*From Ref (a) VanPoollen,  Tinsley  and  Saunders
                                 Table  3

        Compressive  Strengths  and  Permeabilities  of  Various  Tests

                                       Compressive       Permeability
                                       Strength, psi        Darcies
Laboratory,  5%  Silica Flour;               44755
  80 lb/1000 gal gel carrier

Laboratory,  5%  Silica Flour;
  40 lb/1000 gal carrier                   4760                2.1

Resin Cement System                        8000                .01

Mixing Test                                1890                12*

MCA No. 61                                 1960                N.R.
                                                             est. 6*

*These were  permeabilities  of  samples  settled  from  the slurry,  not
 pressure compacted.  The  samples  were taken from the blenders  after the
 test.
                                  -572-

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Page No. 16
                                 Table 4
                      Injectivity of MCA Unit No. 61
     Date

     7/84
     8/84
     9/84
    10/84
    11/84
    12/84
     1/85
     4/85

     5/85
     6/85
     7/85
     8/85
     9/85
    10/85
Injectivity
bbl/psi/NEP
    Comments
  0.0031
  0.0029
  0.00366
  0.00403
  0.00401
  0.00398
  0.00403
  0.00857
  0.0052
  0.0083
  0.0051
  0.0052
  0.0052
  0.0051
MCA Unit No. 61
"Puddle-Packed"
                                -573-

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                              Table 1

Compre3slve Strength of Resin Consolidated Formation Exposed to a
                   Saturated CO -Water at 120°F

                                          Compressive
                Test                    • Strength, psi
              First Day        .              1675
               8 days                        1675
              16 days                        1835
              34 days                        1910
                              Table 2

     Permeability of Mixtures of 70/170 Mesh Sand in 10/20 and
                         20/40 Mesh Sands

                                    Permeability in Darcies
                                 10/20 Mesh20/40 Mesh ^
                                Rounded Sand        Angular Sand
     0% Fine Sand Added              310                 121
    10% Fine Sand Added]               90                  70
    20% Fine Sand Added               60                  25

From Ref (4) VanPoollen, Tlnsley and Saunders

                              Table 3

     Compressive Strengths and Permeabilities of Various Tests

                                      Compressive      Permeability
                                     Strength, psi       Darcies
 Laboratory, Test 1                      4475               6

 Laboratory, Test 2                      4760               2.1
                    2
 Resin Cement System                     8000                .01

 Bulk Mixing Test                        1890              12

 MCA Ib 61                               I960              N.R. ^
                                                          est. 6

These were permeabilities of samples settled from the slurry, not
pressure compacted.  The samples were taken from the blenders after the
test.

                             Table 4

Date
7/84
8/84
9/84
10/84
11/84
12/84
1/85
4/85

5/85
6/85
7/85
8/85
9/85
10/85
Injectivity of MCA Unit No. 61
Injectivity
bbl/psi/NEP Comments
0.0031
0.0029
0.00366
0.00403
0.00401
0.00398
0.00403
0.00857 MCA Unit No. 61
"Puddle-Packed"
0.0052
0.0083
0.0051
0.0052
0.0052
0.0051
                            -574-

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  T.D.  4024' P.B.T.D. 4020'
          10 3/4' AT  721
                                                               GAMMA RAY    NEUTRON
         T AT 3558'
          SHOT W/80 QTS.  NITRO
          AVG. HOLE DIA. 19'

          SHOT W/70 QTS.  NITRO.
          AVG. HOLE DIA. 20"

          SHOT W/170  QTS. NITRO
          AVG. HOLE DIA. 17"
                                                 GRAYBURG-6th  ZONE-
                                           TOP SAN ANDHES-7th ZONE -
Sth ZONE

9th ZONE-


9-M ZONE —
Fig. 1—MCA Unit 61, a typical Injection well.
                                                     Fig. 2—Typical tog aectlon.


  XXXXXXXXXXXXXXX/       XXXXXXXXXX
     MCA  UNIT
                                                                   SCALE
                                                                   1 MILE
                               r_.

                                   *
                             PILOT AREA
                                          XXXXXXXXXXXXXXXX,

            PROPOSED 1st  STAGE EXPANSION

                          /
                           \xxx\xxx\\xxxx
                                     Fig. 3— MCA unit.
                                    -575-

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   T.D. 4024' P.B.T.D. 4020'
            10 3/4- AT 72'
             AT 3558'


           SHOT W/80 QTS. NITRO
           AVG. HOLE  DIA.  19'

           SHOT W/70 QTS. NITRO.
           AVG. HOLE  DIA.  20'

           SHOT W/170 QTS.  NITRO
           AVG. HOLE  DIA.  17'
        4 1/2' LINER

        RESIN COATED  GRAVEL
  Fig. 4—MCA Unit 61 after puddle pick.
                 CASING
                 SHOE
 GAMMA
' RAY
                      58%
                      I
                1
                      ^VELOCITY
                      I PROFILE
                      I SURVEY
                      I
                    38%

                    TEMPERATUR
                           SURVE
Fig. 5— Injection profile survey before puddle pick.
                                                             TRACER  VELOCITY
                                                                        15%
        16%
                   VELOCITY-
                        TRACER
Fig. 6—Injection profile survey after puddle pack.
                                               -576-

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TRACER
                          VELOCITY
                          TEMPERATURE
                                      VELOCITY
                                                                                 % OF LOSS
                                                                                   TRACER
                                                                                0  20 40 60 80
                                                                                1   '  J   '
 % OF LOSS
 VELOCITY
0  20 40
                                                                                                          11%
                                                                                                          10%
                                                                                                          7%
                                                                                                         3%
                                                                                                         INJECTING
                                                                                                         TEMPERATURE
                                                                                                       |-30 MIN. SHUT IN
                                                                                                         1  HOUR SHUT IN
              Fig. 7—Injection profile cased hole MCA unit.
                                                                               Fig. 0— Injection profile lurvey 7 monthi after puddle
                                                                                     pack.
                                                              -577-

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                         HOW TO LOCATE ABANDONED WELLS

                                       by

                      J. Jeffrey van Ee and Eric N. Koglin


                  Environmental Monitoring Systems Laboratory
                       Office of Research and Development
                      U.S.  Environmental  Protection Agency
                            Las Vegas, Nevada 89114


                                    ABSTRACT

     Record searches are typically used to locate abandoned oil  and gas wells
within the area of review for injection wells; however, the accuracy and success
in locating all of the abandoned wells often is questionable.  In some cases,
the records may be incomplete, or inaccurate; in other cases, a  thorough search
of the records may be quite time consuming, particularly when large areas and
multiple record bases must  be searched.  Other methods for locating abandoned
wells are frequently sought when the risk in missing an abandoned well  from a
record search appears to be significant.

     The U.S. Environmental Protection Agency (EPA) has conducted several
studies to determine if other means exist to locate abandoned wells.  The R.  S.
Kerr Laboratory conducted a literature search of alternate methods for locating
abandoned wells.  Field, geophysical, and aircraft-based remote  sensing surveys
were some of the methods that were highlighted in the final report.  The
Environmental Monitoring Systems Laboratory in Las Vegas evaluated two of the
most promising methods in a survey of central Oklahoma for abandoned oil and
gas wells.  The evaluation  of geophysical methods began with the development  of
a mathematical model for the magnetic anomaly produced by steel  casing.  The
United States Geological Survey determined from the mathematical modeling that
airborne magnetometry offered the greatest potential of success  in surveying
large areas for abandoned wells.  The EPA's Environmental Photographic Inter-
pretation Center evaluated historical aerial photographs as the  second means
for locating abandoned wells.  Photographs dating back to the 1930's were
examined.  The data from the aerial magnetometer survey were compared against
the historical photographs, and the results from these two methods were then
compared against a search of the records.  The record search was conducted by  .
the University of Oklahoma's Environmental and Ground Water Institute.

     All three methods were successful in locating abandoned wells.  Each has
its own advantages and disadvantages.  Used alone, each method was useful in
                                     -578-

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locating abandoned wells.  Used together, the methods were able to locate a
higher percentage of wells than any one of the methods used alone.

INTRODUCTION

     It has been estimated that over two million abandoned wells exist in the
United States (Aller, 1984).  Numerous problems are created by these wells, and
documented cases of pollution from abandoned wells are widespread.  Improperly
plugged and abandoned wells may allow fluids to migrate between aquifers
especially when those wells are located within the zone of influence of under-
ground injection wells.  When the piezometric surface is greater than the land
surface, brine may contaminate the land and surface waters.  Abandoned oil  and
gas wells may also allow gases to migrate toward the surface and into structures
where explosive levels may lead to fire and explosion.  Abandoned agricultural
wells in Silicon Valley are a problem in conveying contaminated water from
shallow aquifers to deeper, drinking water aquifers.  Knowing the location of
abandoned wells is an important first step in characterizing the potential  for
pollution of underground sources of drinking water.  Once the well has been
located, an assessment is usually made of the condition of the well to determine
whether it was properly plugged and abandoned.

     Federal regulations developed in response to the Safe Drinking Water Act
and the Resource Conservation and Recovery Act require a search for abandoned
wells within an "area of review" of underground injection wells (see 40 CFR
Part 146).  Typically, these searches are of records.  Other data bases and
methods may be used when the risk in not locating all the wells within the area
of  review is high, and when the location of a well in the field is complicated
by either a lack of surface features, or poor, incomplete, or nonexistent
records.  In those instances where large areas must be surveyed (such as
counties where reservoirs or injection wells may be located) a search of the
records by itself may not be sufficient.  Other methods must be examined.

     The Environmental Protection Agency's R. S. Kerr Laboratory reviewed the
literature to determine what methods have been, or may be used to search for
abandoned wells (Aller, 1984).  A variety of methods were identified with some
being routine and straight forward, such as a search of records or consulting
long-time property owners, and others, such as thermal mapping, being less
feasible.  The EPA's Environmental Monitoring Systems Laboratory in Las Vegas
(EMSL-LV) chose to evaluate three of the most promising techniques:  record
searches, historical aerial photographic analysis, and magnetometry.  Much of
the research centered on four test areas outside of Oklahoma City where the
three methods were compared.  The purpose of this paper is to summarize the
results of the research and to outline a strategy for locating abandoned wells.
A bibliography of EPA-funded research publications is provided for further
references.

RECORD SEARCHES

     Written records for oil and gas, mineral exploration, water, and injection
wells reside in numerous locations throughout the country.  Searches of those
records are a starting point in the search  for abandoned wells.  Where  records
are easily accessible, such as computer data bases or maps, little effort  is
                                    -579-

-------
required.  Where records are scattered or incomplete, more effort is required
and the pay back is reduced.  When records do not exist, such as for wells  that
were drilled many years ago, a search of the records will not locate all  of the
wells within the search area.  In many cases, particularly with the older
wells, descriptions are poor of where the wells are located, and how they were
drilled and plugged.  A well may have been described as being two hundred feet
from the big oak tree; however, the tree may no longer be present.  Even  with
more modern day records, the accuracy in which the location of a well  may be
pinpointed can be poor.  A well may simply be located in 1/64 of a section, and
the area where the well may be located can be on the order of hundreds of feet.
When no surface features are left to identify the location of the well bore,
locating an abandoned well can be quite difficult from a search of the records.

     One reason why it is important to first search the records is that infor-
mation presumably exists on how the well was drilled and whether the well was
properly plugged and abandoned by modern day standards.  A search of historical
photographs and the use of magnetometers cannot provide this information
(Fairchild and others, 1983).

HISTORICAL AERIAL PHOTOGRAPHIC ANALYSIS

     EMSL-LV began a research program in 1982 to devise a method of locating
abandoned wells cost effectively and quickly.  This research program, conducted
by the Environmental Photographic Interpretation Center (EPIC) of EMSL-LV
located at Vint Hill Farms Station, Warrenton, Virgina, tested a method of
locating abandoned wells using historical aerial photography to locate old
wells during or close to their period of production, when well site features
are most recognizable.  Photographic analyses are particularly useful  in  areas
where commercial or residential development in agricultural or oil-producing
areas have virtually obliterated the old wells.

     Abandoned wells are located from aerial photographs through the development
of "signatures."  A signature is a combination of characteristics or features
by which an object or activity can be identified on an aerial photograph.
Depending upon the land use and history of the area being analyzed (agricul-
tural, oil  or gas production), these signatures may include pump houses,  storage
tanks, derricks, impoundments, or depressions in the earth left by storage
tanks (Figure 1).  Sites in which these signatures are very clear in successive
years of imagery are classified as "active/abandoned" wells.  Signatures  whose
origin is less certain are classified as "probable abandoned" or "possible
abandoned" wells, depending upon the degree of certainty.

     As an example, the first application of this method was at sites located
around the Oklahoma City, Oklahoma, area (U.S. EPA, 1983).  Signatures for the
well  sites were developed through researching early petroleum publications,
personal communications with individuals familiar with old drilling techniques,
and preliminary field work.  Signatures for producing wells were found to
include various combinations of the following features:  maintained roads,
brine pits, derricks, power houses, ground stains, ground scars, walking  beams
and scars from pipelines. The actual well locations were determined by knowing
the general spatial relationship between the wells and these recognizable
features.  In addition, associated oil extraction activities such as storage
                                    -580-

-------
oo
                    Figure  1.  Active oil wells  in 1951 located in the Arcadia, Oklahoma, study area.

-------
tanks, water/oil separation ponds and well spacing patterns aided in well  site
identification.  The analysts found that signatures varied from one Oklahoma
area to another, depending on the time the oil field was developed and the
technology used (Stout and Sitton, 1984).

     Signatures for agricultural and water supply wells have features different
from those for oil  and gas wells.  The principal  features include pump houses,
power poles, water tanks, shade trees, access roads and irrigation water flow
patterns.  Usually, the features associated with  agricultural  or water supply
wells are not as prominent on aerial photographs  because of their size and the
minimum ground resolving capability of the historical photography (U.S. EPA,
1987).

     Once a signature is identified in a photograph, its location can be manu-
ally transferred from the historical photograph to a recent photograph or with
the aid of a computerized interactive graphics system.  With the aid of this
current photograph and overlay, a field crew can  inspect a site and identify
likely well locations within a relatively short period.  In cases where the
well is not visible from the surface, the crew can use a magnetometer to locate
the metal well casing.

     This historical photographic analysis method of locating abandoned wells
has advantages over the traditional method of record searches.   First, it  is
relatively quick.  In about one month, a photointerpreter can analyze an area
of several square miles and provide maps and overlays to field  crews.  Gen-
erally, if the wells are in a nonurbanized area with moderate vegetation,  the
field crews can locate the wells easily.

     A second advantage of the aerial photographic analysis method is that it
provides confirmation of the location and number  of wells in an area with  one
common method used to identify past well drilling activity.  Though it may not
be possible to locate all wells identified on the photos, it is still  advan-
tageous for the purpose of risk assessment to know where and how many wells
exist.

     Finally, there appears to be significant cost savings in using photographic
analysis.  In a Santa Clara County, California, study area where the landscape
has changed drastically due to rapid growth and urbanization,  costs to local
agencies for personnel to identify a single abandoned well  have been as much as
$4,000.  In the same area, the photo analysis cost as little as $40 per well.
As this technique can narrow the field of search  to within a 50-foot diameter,
time spent in the field is greatly reduced, resulting in further cost savings.
This difference is especially dramatic in urban areas where literally thousands
of abandoned wells may exist.

     No method for locating abandoned wells is perfect.  A disadvantage of the
photographic method is that some abandoned wells  will not be found, particularly
when photo coverage of the area has been poor, and rapid changes have occurred
on the surface.  When combined with other methods, such as record searches, the
use of historical aerial photographs can increase the level of success in
finding all  the abandoned wells that may exist in an area.
                                     -582-

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SOURCES FOR HISTORICAL PHOTOGRAPHS

     Historical aerial photography is available through a number of different
sources, some of which are listed in Table 1.


                TABLE 1.  SOURCES FOR HISTORICAL AERIAL IMAGERY
     ° Limited air photo library maintained by EPIC and the Remote and Air
       Monitoring Branch at EMSL-LV

     ° National Cartographic Information Center, Reston, Virginia, (will
       research availability of aerial photo coverage).  Telephone number:
       (703) 860-6045

     ° EROS Data Center, U.S. Geological Survey, Sioux Falls, South Dakota,
       (maintains photography for the following agencies:  USGS, USAF, USA,
       USN, BLM, COE, and NASA).  Telephone number: (605) 594-6511, ext. 151

     ° National Archives and Records Service, Alexandria, Virginia, (photog-
       raphy from the 1930's and early 1940's).  Telephone number:  (703)
       756-6700

     ° Agriculture Stabilization Conservation Service, U.S. Department of
       Agriculture, Salt Lake City, Utah.  Telephone number:  (801) 524-5856

     ° National Oceanic and Atmospheric Administration, National Ocean
       Survey, Rockville, Maryland.  Telephone number: (301) 443-8661

     ° State Department of Transportation Offices

     ° County Tax Assessors

     0 Private companies which specialize in taking aerial  photographs

MAGNETOMETER SURVEYS

     Abandoned wells with few visually evident surface features can be located
with magnetometers.  Ferrous metal scrap and trash located on the surface near
the well bore and steel casing in the hole can be used to locate the well in
areas where cultural features, such as metal tanks, fences, and houses are few
and far between.  The earth's magnetic field averages approximately 53,000
gammas in the U.S. and a proton precession magnetometer is able to measure
changes in the field intensity of a few gammas.  By mapping the magnetic field
in an area, it is possible to locate the well bore of a steel-cased well to
within a few feet.
                                    -583-

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     The United States Geologic Survey (USGS) performed several  studies for the
EMSL-LV to determine whether airborne magnetometry could be used to locate
abandoned wells.  It was first necessary to develop a mathematical model of the
magnetic anomaly to determine the optimal altitude and spacing of the aircraft
flight paths.   Ground-based magnetometer measurements were made in the vicinity
of steel-cased oil wells to verify the model.  Good agreement was obtained
between the calculated and observed magnetic anomaly on the ground (Figures 2a
and 2b).  This provided some assurance that the extrapolation of the model to
the airborne case would be valid (Frischknecht and Raab, 1984).

     The model indicated that abandoned wells with a minimum of several hundred
feet of casing could be located from an aircraft at 200-foot altitudes (Figure
3).  The spacing between the flight paths would have to be approximately 300-400
feet to adequately map the magnetic anomaly with a proton precession magnetom-
eter.

     The USGS possessed a small private plane that was instrumented and used
for magnetometer surveys.  The magnetic field has been extensively mapped by
the USGS across most of the U.S.  Small features such as wells were not observed
because they were not of interest, and they would contribute "noise" to the
magnetic field of the underlying geologic material of interest.  Ferrous metal
materials in the plane had been removed, and the much of the remaining magnetic
field had been compensated by the use of coils and an electrical current to
produce an opposing magnetic field.  A radar altimeter was used to record the
altitude above  the ground and to ensure that the plane kept a constant above
the ground.  A ground-based radio navigation system was deployed on the perime-
ter of each test area in Oklahoma to allow the pilot to maintain precise flight
paths and to allow the magnetic data to be referenced to an accurate location.
The orientation of the aircraft was also recorded to permit compensation of the
magnetic data after the flight.  Figure 4 graphically depicts this airborne
profile data from one of the Oklahoma study areas.  While the use of airborne
magnetometry by the USGS would seem to be an involved, complicated process, the
general process and most of the equipment could be readily acquired and used by
commercial airborne magnetometer firms.

     Measurements of the magnetic field with a ground-based magnetometer can be
complicated by nearby, small pieces of metal.  Figures 2a and 2b illustrate the
magnetic profile generated by a ground-based magnetometer.  The response drops
off rapidly within a short distance from the well location, therefore, metal
debris in the subsurface can mask a location or confuse an interpretation.  An
airborne magnetometer is not as sensitive to ground clutter in the mapping of
the magnetic anomaly from larger objects.  The magnetic anomaly from a well
will be reduced in intensity with altitude (Figure 5); however, the anomaly
will broaden in size and fewer survey lines will be required to detect the well
casing.  Ground-based magnetometers are able to pinpoint the location of a
buried well casing to within a few feet.

     The airborne magnetic surveys in Oklahoma found a significant number of
abandoned wells (Figure 6).  Some of the anomalies could easily be associated
with a visible  feature such as the well head or concrete pad; other anomalies
could not.  Ground-based magnetometer measurements were made where an abandoned
well could not  be observed from the surface.  In many instances, the anomaly
                                    -584-

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                N-S MAGNETIC TRAVERSE
           54000.

           54720.
           54060.
        I  64400.


        an

        "  54240.
        a


        «  04080.
        —  53920.
               N
           53760.
           53600.
           53440.
           53280.

           63200.
T
    I  '   I
                        o   o   o    o   o
                        o   o   o        o
                        MM—        —
                        1    I     I




                              DISTANCE (Fe»t)
Figure  2a.  Observed and  calculated north-south magnetic  profiles

      over well  No. 17, Horseshoe  Lake test  area,  Oklahoma.
           54*0™


           54720.




           54560.




           54400.




           54240.
        «  54080.
        U.

        CJ
        «  53920.


        2
        "  53760.



        ^  53600.



        *~  53440.



           53280.

           63200.
                E-W  MAGNETIC TRAVERSE
                                8    °   S   S    S   8
                                y        -   S    »   •»



                              DISTANCE (F*«t)
                                       8
 Figure 2b.   Observed  and calculated east-west magnetic  profiles

       over well  No.  17,  Horseshoe Lake test area,  Oklahoma.
                                  -585-

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0)
(U
o
c
CO
**
CO
     -400
     -300
      -200
     -100
100
       200
      300
       400
                                                                      N "
         -400 -300  -200  -100    0     100   200   300   400
                                Distance  (feet)
       Figure 3.  Calculated center  map of total intensity at a  height of
     200 feet above a well  (the  lines show 200 foot spacings  on  north-south
  or east-west flight (has  to measure a two gamma anomaly in  the worst case),
                                         -586-

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MANEUV. NOISE
COR.-GAMMAS

 DIFFERENTIAL
   ROLL-DEG.
  DIFFERENTIAL
   PITCH-DEG.

 DIFFERENTIAL
 HEADING-DEG.
 BARO. ALTMTR
    METERS


RADAR ALTMTR
    METERS
                 0.76
-0.76
                  376
 300
                   26
   COR. MAG
FIELD-GAMMAS
                           4620
                           	1	
                        4480
                                                       4440
                                                                        -3
                                                      '100
                                                                        26
                                             26
                           4620
                                         4480
                                                       4440
                                                                    1
                                                                   H MILE
    Figure  4.  Airborne profile data from Arcadia area (the numbers at the top
   and bottom are identification numbers associated with each reading, and the
             numbered anomalies correspond with those on Figure 6).
                                    -587-

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                                                                          N
 o>
 
SB'

•o

 0)
(0
*»
o
      200-n
100-
        0  J
                    Height  of  Plane
                       250  feet
                 200
                 150
                 100
                                            5000
                                                      10000 feet

                                                     	I
        Figure 5.  Aeromagnetic  profiles for different aircraft heights
                over Well  No.  4,  Piney Creek test area,  Colorado.
                                     -588-

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Figure 6.   Total  intensity  contour  map  for  part  of
        the Arcadia,  Oklahoma, test  area.
                     -589-

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measured on the ground could be associated with an abandoned well.  Sometimes,
the well may have been a water well.  In other instances, the anomaly which
appeared to be from a well was from a pipeline that traversed a hill.  The bend
in the pipeline produced the magnetic anomaly that appeared to be from an
abandoned well (Frischknecht and others, 1984).

     Ground-based magnetic surveys for abandoned agricultural wells have been
conducted by the USGS in Silicon Valley.  A mathematical model was developed
and verified with field data to determine the minimum size of casing that could
be observed in an urban area.  The mathematical model indicated that most
agricultural wells could be located in theory, but the difficulties in making
measurements in an urban area remained to be investigated.

     Where historical photographs were able to locate a probable abandoned well
in a vacant lot or in a backyard, ground-based magnetometer measurements were
usually successful in locating abandoned agricultural wells in the urbanized
areas of Silicon Valley.  When a well was thought to exist in a parking lot,
ground-based magnetometer measurements were complicated by the presence of
buried utilities, reinforcing steel, and nearby automobiles and buildings.
When abandoned wells were thought to exist under buildings, no magnetometer
measurements were made, nor is it believed that they could have been made with
the interfering utilities and nearby metal objects.  Without the use of his-
torical photographs to identify search areas for magnetometer measurements,
magnetometer measurements for abandoned wells in urbanized areas are likely to
be less effective and more costly than searches for abandoned wells in less
developed areas (Jachens and others, 1986).  Further details may be obtained
from the USGS and the publications listed in the bibliography.

COST COMPARISON

     Costs for locating abandoned wells vary with the area and the elapsed time
since the well was drilled.  It has been estimated that a search of records to
"locate" an abandoned well costs approximately $50 (Arthur D. Little, Inc.,
1979 in van Ee, 1984).  To actually locate the well may require the use of other
methods and data sources.  The cost of using historical photographs has been
estimated at approximately $600 per square mile (Stout and Sitton, 1984).  As
noted previously, "probable" or "possible" abandoned wells will require field
verification.  The cost for conducting magnetometer surveys is more difficult
to estimate.  The size of the search area is an important factor because the
deployment costs for an airborne magnetometer survey can be significant no
matter what size an area is to be surveyed; thus, the cost on a "square mile"
basis will be lowered as the number and size of areas increases.  A cost-figure
obtained for airborne magnetometer surveys from the Oklahoma studies was between
$1,000 to $2,000 per square mile.  For ground-based magnetometer surveys,
estimates of the cost are relatively fixed.  On a lineal basis, the costs range
from $50 to $121 per line-mile, or approximately $3,100 to $12,100 per square
mile.  While the equipment required to perform an airborne survey is more
sophisticated and expensive than required for ground-based measurements, the
increased time required to perform a ground-based survey of a large area leads
to higher costs (Frischknecht and Raab, 1984).
                                    -590-

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IMPLEMENTATION STRATEGY

     Airborne magnetometer studies proved to be cost effective in areas where
low-level  flights could be made and where little development of the land occur-
red.  Federal Aviation Administration (FAA) regulations limit the type of
aircraft and flight patterns that can be flown at low altitudes.  Tall, man-made
objects such as radio towers, electrical transmission towers, water towers,
buildings, and silos need to be located before an assessment can be made on  the
practicality of airborne measurements.  Low-level overflights of farms and
dwellings  are permissible with certain restrictions; however, as the number  of
proposed flights over these features increase, the difficulties in complying
with the FAA regulations and the likelihood of complaints also increase.
Aircraft magnetometer measurements can only be considered after other factors
have also  been considered.

     Typically, the first approach is to consult the records.  The next approach
would be to use historical photographs, and the third approach would be to
consider magnetometry with airborne measurements being a consideration for
surveying  large areas.  Ground-based magnetometer measurements should always be
considered in locating those wells that have little, if any, visible surface
features.

Study Areas - Lessons Learned

     Table 2 lists all the abandoned wells projects which have been conducted
by EMSL-LV.  These eight projects provided great insight into the application
and limitations of the above-mentioned methods.  The following sections discuss
some to the lessons learned from selected projects.

OKLAHOMA AND CLEVELAND COUNTIES, OKLAHOMA

     The objective for the studies conducted in Oklahoma and Cleveland Counties,
Oklahoma,  was to test, evaluate, and compare the three previously discussed
methods for locating abandoned wells.  Four areas were selected within these
counties because of the presence of underground injection wells in each area.

     These study areas represented ideal locales in which each method worked
very well.  The Oklahoma Corporation Commission records were adequate; the
aerial photographic method was very successful because signatures were well
defined and not obscured by urban growth or revegetation; and, the ground and
airborne magnetic surveys did not suffer from interference effects due to
cultural features (U.S. EPA, 1983).

     As an example, in the Arcadia, Oklahoma, study area 36 wells were identi-
fied from photos, 41 were wells identified from the record search and 37 were
wells identified with magnetic methods.  Frischknecht and Raab (1984) concluded
that 95 to 98 percent of the magnetic anomalies identified in the four study
areas were associated with abandoned wells.  Stout and Sitton (1984) concluded
that 91 percent of the abandoned wells in the four study areas were identified
with the aerial photographic method, using the results of the record search  as
a measuring stick.  They believe that some additional wells may not have been
                                     -591-

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             TABLE 2.  SUMMARY OF EMSL-LV ABANDONED  WELLS  PROJECTS


         State                        EPA Region                Year  Completed


Oklahoma                                   6

   Cleveland and
    Oklahoma Counties                                          1983

   Kay County                                                  1985

   Washington County

Pennsylvania                               3

   Elk, McKean, and
    Warren Counties                                            1985

   Allegheny Reservoir                                         1987

New York                                   2

   Chautauqua County                                           1985
    (Levant)

California

   Farmers Market                          9                   1985

   Santa Clara County                      9                   1985  (Phase  I)
                                                               1987  (Phase  II)
identified, but these represent a very small minority and would not signifi-
cantly change the accuracy rate of the photo analysis.

PENNSYLVANIA STUDY AREAS

     Only the photographic analysis method was applied in the study areas in
Pennsylvania (Elk, McKean, and Warren Counties and the Allegheny Reservoir).
Because of the rapid revegetation, and much of the oil exploration predated the
earliest aerial  imagery, the photo analysis method was not as successful  com-
pared to the Oklahoma experience.  The signature developed for these areas had
some similarities to the Oklahoma areas; however, unique oil field attributes
were identified in Pennsylvania (U.S. EPA, 1985 and U.S. EPA, in progress).
                                    -592-

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SANTA CLARA COUNTY, CALIFORNIA

     In this study area, aerial photographic analysis and hand-held magnetometer
surveys were used to locate abandoned agricultural  and domestic water supply
wells.  The signature developed for this study area included site features
which are different from those used in oil  and gas  production areas.  Using
these signatures, 805 wells were identified in the 26-square mile study area.
This number may not account for all abandoned wells since some may not have
exhibited any surface features visible on historical photography, or the wells
may have been obscured by vegetation.

     Field work failed to reveal the degree of accuracy of the historical photo
analysis method because of the small sample of wells visited and the difficul-
ties encountered in verifying their locations in an urban environment.  Many of
the photo-identified wells are now located under buildings, parking lots, and
highways.  Geophysical methods proved less successful  in Santa Clara County
because of the abundance of metal  objects and structures present in the study
area.  It is also conceivable that some well casings may have been removed
during the construction of highways and buildings (U.S. EPA, 1987).

SUMMARY AND CONCLUSIONS

     Three methods were used to locate abandoned oil,  gas, agricultural, and
water supply wells in various areas around the U.S.  As each method was applied
in the Oklahoma study areas, the level of confidence that all abandoned wells
had been located increased, but each method also raised the total cost of the
investigation.  The records search provided information on well construction
which the other techniques cannot  supply; therefore, it is likely that records
search will always be required to  assess the pollution potential from abandoned
wells.  Unfortunately, the information contained in the records on both well
location and construction may not  be complete or accurate.  Additional location
techniques are desirable to supplement the data.

     Historical aerial photographs are particularly valuable for those periods
when records are not complete or accurate.   This particularly true for the
period from the 1930's through 1950's during which  improved, wide-spread photo-
graphic coverage became available  and accurate records were not often required.
In areas where rapid land use changes have occurred, it can be difficult to
locate abandoned wells when the length of drilling  time at a site was short in
relation to the period of time between photos.  Even wells drilled in the
recent past, when frequent photographs are likely to exist, can escape detection
because the length of time that modern-day rigs spend on a site can be less
than in the past when the drilling derrick had to be constructed at the site.
Fortunately, the increased emphasis on developing good records has made the
problem of locating recently abandoned wells much easier.

     The aeromagnetic method, like the photographic method, can be readily used
to locate abandoned wells for many areas where there has been no surface evi-
dence of the well.  Large areas can be surveyed rapidly from the air without
need for access to the property.  While the method  allows a well casing to be
located to within 3 to 6 feet with the aid of a ground-magnetometer, the method
is costly.  An aeromagnetic survey requires more sophisticated equipment and
                                     -593-

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technical expertise than the other two methods.   However, more wells were
detected by the aeromagnetic surveys than by the initial  photointerpretation.

     For any survey method, or methods, selected will  depend on the available
resources and the potential threat posed by unknown locations of abandoned
wells in an area.

                                ACKNOWLEDGEMENTS

     The authors would like to recognize all the individuals who have con-
tributed to the EMSL-LV abandoned wells studies.  Chief among them are Kristen
Stout of the Bionetics Corporation and Frank Frischknecht of the United States
Geological Survey.  Their efforts and resulting publications have provided
important contributions to the 4-year abandoned wells research program.

                                     NOTICE

     Although the research described in this article has been funded wholly or
in part by the United States Environmental Protection Agency, it does not
necessarily reflect the views of the Agency and no official  endorsement should
be inferred.

                                 ERRATUM NOTICE

     The authors found a few omissions and oversights in the reference and
bibliography sections after the final copy was submitted to the UIPC.

     Citations highlighted with asterisks {*) are the replacements for the pre-
ceeding citation.  The body of the paper does not cite the replacements.

     The citation highlighted with the pound symbol {#) was inadvertantly
omitted from the bibliography.

                                   REFERENCES

Aller, L.  1984.  Methods for Determining the Location of Abandoned Wells.
     EPA-600/2-83-123.  Available through NTIS, Publication No. PB84-141530 and
     through NWWA.

Fairchild, D. M., C. M. Hull, and L. W. Canter.  1983.  Selection of Flight
     Paths for Magnetometer Survey of Wells.  Environmental  and Ground Water
     Institute.  The University of Oklahoma, Norman, Oklahoma.  EPA Unpublished
     Report.

Frischknecht, F. C. and P. V. Raab.  1984.  Location of Abandoned Wells with
     Geophysical Methods.  EPA-600/4-84-085.  Available through NTIS, Publica-
     tion No. PB85-122638.  Frischknecht, F. C., L. Muth, R. Grette, T. Buckley,
     and B. Kornegay.  1984.  Geophysical Methods for Locating Abandoned Wells.
     EPA-600/4-84-065.  Available through NTIS, Publication No. PB84-212711.
                                      -594-

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 Frischknecht,  F-  C.,  P-  V.  Raab,  R.  Grette,  and J.  Meredith.   1984.   Aeromag-
      netic  Surveys  for Locating Abandoned  Wells.   USGS unpublished report.

 Jachens,  R. C., M.  W.  Webring, and F.  C. Frischknecht.  1986.   Abandoned-Well
      Study  in  the Santa Clara Valley,  California.   USGS Open-file Report 86-350.

 Stout, K.  K.  and M. D. Sitton.   1984.   Locating Abandoned Oil  and Gas Wells
      with  Historical  Aerial  Photos.   Proceedings of the First  National  Confer-
      ence  on Abandoned Wells:  Problems and  Solutions, held May 30 to 31, 1984.
      Environmental  and Ground Water Institute,  University of Oklahoma,  Norman,
      Oklahoma.

 U.S. EPA.   1983.   Abandoned Wells Study:   Oklahoma and Cleveland Counties,
      Oklahoma.  TS-PIC-83051.

*Stout, K.  K.  and M. D. Sitton.   1983.   Abandoned Wells Study:   Oklahoma and
      Cleveland Counties, Oklahoma.  The Bionetics Corporation  for the U.S. EPA.
      Report Number TS-PIC-83051.

 U.S. EPA.   1985.   Abandoned Wells Study:   Elk,  McKean, and Warren Counties,
      Pennsylvania.   Technical Support  to Region III.   Two Volumes.   TS-PIC-
      85008.

*Sitton, M.  D.   1985.   Abandoned Wells  Study:   Elk,  McKean, and Warren Counties,
       Pennsylvania.  The Bionetics Corporation  for the U.S.  EPA.   Technical
       Support to Region III.   Two Volumes.   Report Number TS-PIC-85008.

 U.S. EPA.   In  progress.   Abandoned Wells Study:   Allegheny Reservoir,
      Pennsylvania.   Technical Support  to Region III.   Two Volumes.

*Stouts K.  K.  and L. M. Fauss.  In progress.   Abandoned Wells Study:   Allegheny
      Reservoir, Pennsylvania.  The Bionetics Corporation for the U.S. EPA.
      Technical Support to Region  III.   Two Volumes.

 U.S. EPA.   1987.   Abandoned Agricultural Wells:   Santa Clara County, California.
      Technical Support to Region  IX.   Two  Volumes TS-PIC-86046.

*Stout, K.  K.  and L. M. Fauss.  1987.    Abandoned Agricultural  Wells:  Santa
      Clara County,  California.   The Bionetics Corporation for  the U.S.  EPA.
      Technical Support to Region  IX.   Two  Volumes.   Report Number TS-PIC-86046.

 van Ee, J.  J., L. Aller, K.  K.  Stout,  F- Frischknecht, and D.  Fairchild.   1984.
      Summary and Comparisons of  Three  Technologies for Locating Abandoned Wells
      in Central Oklahoma.  Proceedings from  the Seventh National  Ground Water
      Symposium, September 26 to  28,  1984,  Las Vegas,  Nevada.   Available through
      the NWWA.

                                   BIBLIOGRAPHY

 Aller, L.   1984.   Abandoned Wells:  How to Find Them.   Proceedings from the
      Seventh National  Ground Water Symposium, September 26 to  28, 1984,
      Las Vegas, Nevada.   Available through the NWWA.
                                      -595-

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 Environmental  and Ground Water Institute.   1984.   Proceedings of the First
      National  Conference on Abandoned Wells:   Problems and  Solutions, held May
      30 to 31, 1984.  Environmental  and Ground Water Institute, University of
      Oklahoma, Norman, Oklahoma.

 Frischknecht,  F. C. et al.   1983.   Geophysical  Methods for  Locating Abandoned
      Wells.   USGS Open-File Report 83-702.

#Frischknecht,  F- C., L. Muth, R.  Grette, T.  Buckley, and B.  Kornegay.   1984.
      Geophysical Methods for Locating Abandoned Wells.   EPA-600/4-84-065.
      Available through NTIS, Publication No.  PB84-212711.

 Frischknecht,  F. C., D. P-  O'Brien,  R. Grette,  and P. V. Raab.  1985a.   Location
      of Abandoned Wells by  Magnetic  Surveys:   Acquisition and  Interpretation of
      Aeromagnetic Data for  Five Test Areas.   USGS Open-File Report 85-614A.

 Frischknecht,  F. C., D. P.  O'Brien,  R. Grette,  and P. V. Raab.  1985b.   Location
      of Abandoned Wells by  Magnetic Surveys:   Location Maps and Aeromagnetic
      Contour Maps. USGS Open-File Report 85-614B.

 U.S. EPA.  1985a.  Abandoned Wells Study:   Kay County, Oklahoma.  Technical
      Support to Region VI.  Two Volumes. TS-PIC-85008D.

*Stout, K. K. and L. M. Fauss.  1985a.  Abandoned Wells Study:  Kay County,
      Oklahoma.  The Bionetics Corporation for the U.S. EPA.   Technical  Support
      to Region VI.  Two Volumes.   Report Number TS-PIC-85008D.

 U.S. EPA.  1985b.  Abandoned Wells Study:   Washington County,  Oklahoma.   Tech-
      hnical  Support to Region VI.   Two Volumes.  TS-PIC-85008F-

*Stout, K. K. and L. M. Fauss.  1985b.  Abandoned Wells Study:  Washington
      County, Oklahoma.  The Bionetics Corporation for the U.S. EPA.   Technical
      Support to Region VI.   Two Volumes.  Report Number  TS-PIC-85008F.

 U.S. EPA.  1985c.  Abandoned Wells Study:   Chautauqua County,  Levant, New York.
      Technical Support to Region  II.   Two Volumes.   TS-PIC-85008D.

*Stout, K. K.,  L. M. Fauss,  and M.  D.  Sitton.   1985c. Abandoned Wells Study:
      Chautauqua County, Levant, New  York.   The Bionetics Corporation  for the
      U.S. EPA.  Technical Support to Region II.  Two Volumes.  Report Number
      TS-PIC-85008D.

 U.S. EPA.  1985d.  Abandoned Wells Study:   Farmers Market Area-Los Angles,
      California.  Letter Report to Region IX.

*Stout, K. K.  1985d.  Abandoned Wells Study:   Farmers Market Area-Los Angles,
      California.  The Bionetics Corporation for the U.S. EPA.  Letter Report to
      Region IX.
                                      -596-

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                             BIOGRAPHICAL SKETCHES

     J. Jeffrey van Ee is an electronics engineer with the Aquatic and Subsur-
face Monitoring Branch at the EPA Environmental  Monitoring Systems Laboratory
in Las Vegas, Nevada.   Mr. van Ee is an EPA Project Officer who has been
involved in several major EPA Programs during his 15 years with the Agency.  He
was involved with the  measurement of air pollution in the 1970's,  and he  became
involved in the development of quality assurance procedures for the calibration
of air pollution instruments.  His work with the National  Eutrophication  Survey
involved the assessment of the water quality of  lakes and reservoirs.   His
recent duties include  the assessment of monitoring systems for the detection of
leaks from underground storage tanks, the development of monitoring strategies
for hazardous waste site assessments, and the development of quality assurance
guidelines for ground-water studies.

     Eric N. Koglin is a hydrogeologist with the Aquatic and Subsurface Monitor-
ing Branch at the EPA  Environmental  Monitoring Systems Laboratory  in Las  Vegas,
Nevada.  He holds a B.S. in geology from Indiana State University  and an  M.S.
in hydrology from the  University of Arizona*  Prior to joining EMSL-LV,
Mr. Koglin was an environmental  scientist working for U.S. EPA Region 9 in the
Superfund Programs Branch.  From 1979 to 1982 he worked for the South Dakota
Geological Survey as a mud rotary drill rig operator and geologist.  Since
joining EMSL-LV, he has been involved with a variety of research projects
including the placement of ground-water monitoring wells, ground-water flow and
contaminant transport  in fractured rocks, and the application of geographic
information systems to ground-water resource management and contamination
issues.
                                     -597-

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                            "ADA" PRESSURE TEST

                            Richard C. Peckham
               Environmental Protection Agency - Region VI
                              Dallas, Texas

                                   and

                              Everett M. Wilson
               Environmental Protection Agency - Region VI
                            Pawhuska, Oklahoma
ABSTRACT
     Since December 30, 1984, the Environmental Protection Agency's

Region VI has been implementing the Underground Injection Control  (UIC)

program in Osage County, Oklahoma.  There are approximately 3500 injec-

tion wells in the county which must demonstrate mechanical integrity

before January 1, 1990 or be plugged.  There are a number of wells with

open perforations above the packer which cannot be tested by the standard

annulus pressure test.

     A special pressure test was developed to test these wells and the EPA

Robert S. Kerr Laboratory's (RSKERL) "leak test" well  was used to test the

principle of the method before using it in the field.   The method was

designed on the same principle used to measure water levels by an air line

in water wells.  After measuring the fluid level in a  well to determine

the height of the water column above the perforations, the pressure

required to depress this column of water to the top of the perforations

is calculated.  Nitrogen is added to the annulus until the pressure no

longer increases.  If the pressure reached is approximately the same as

that calculated and it remains constant for 30 minutes, after closing the

valve to the nitrogen source, there are no leaks in the casing above the

perforations.

                                    -598-

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The same test may be used inside the tubing to demonstrate the integrity
of the tubing and packer.
     The method was used to test 13 wells in Osage County in 1986.  All
were witnessed by EPA inspectors and the results were conclusive.  Five
of the wells passed and eight failed.
     Three case histories covering the basic spectrum of conditions that
will be encountered on wells with this type of test are presented as
operational examples of the Ada Pressure Test.
     From these examples, it can be demonstrated that the Ada Pressure
Test is a simple inexpensive, reliable and viable test for establishing
the mechanical integrity of a well.  In addition, the conditions for
application of the test assures the protection of the USDW.
                                   -599-

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INTRODUCTION

     In EPA's Region VI, primacy for the UIC program has been

delegated to all five of the states in the Region (Arkansas,  Louisiana,

New Mexico, Oklahoma, and Texas).

     The Osage Nation consists of the entire county of Osage  in Oklahoma

(Figure 1) and as required by the Safe Drinking Water Act of  1974 (PL93-523),

Region VI has direct implementation of the UIC Program on Indian Lands.

Accordingly, the Osage UIC regulations (40 CFR Part 147, Subpart GGG)

were established and became effective December 30, 1984.  These regulations

require that all injection wells demonstrate mechanical integrity by

December 30, 1989 and at least once every five years thereafter.

Osage County Oklahoma has approximately 3500 injection wells  ranging in

depth from 500 to 3000 feet.  In order for these wells to have mechanical

integrity it must be demonstrated that:

     (1) There is no significant fluid movement into an underground source

of drinking water (USDW) through vertical channels adjacent to the

well bore, and

     (2) there is no significant leak in the casing, tubing or packer.


The demonstration of (1) above can be through any of the following:

          (a) Cementing records (need not be reviewed every five years);

          (b) Tracer survey (in appropriate hydrogeologic settings; must
              be used in conjection with at least one of the other
              alternatives);

          (c) Temperature log:

          (d) Noise log; or

          (e) Other tests deemed acceptable by the Regional Administrator.
                                   -600-

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     This demonstration is usually accomplished through a file review of
Bureau of Indian Affairs (BIA)  records.   The BIA has regulated the oil
and gas production in Osage County almost since the first discovery of
oil in the County and maintain  a comprehensive file on all  well  compl-
etions dating back to the early 1900's.

The demonstration of (2) above  can be through any of the following:
          (a)  Performance of a pressure test of the casing/tubing
               annulus to at least 200 psi,  or the pressure specified by
               the Regional Administrator,  to be repeated thereafter, at
               five year intervals, for the life of the well  (pressure
               tests conducted  during well  operation shall  maintain an
               injection/ annulus pressure  differential of at least 100
               psi through the  tubing length); or
          (b)  Maintaining a positive gauge pressure on the casing/tubing
               annulus (filled  with liquid) and monitoring the pressure
               monthly and reporting of the pressure information annually;  or
          (c)  Radioactive tracer survey; or
          (d)  for enhanced recovery wells,  records of monitoring showing the
               absence of significant changes in the relationship between
               injection pressure and injection flow rate at the well
               head, following  an initial pressure test as described by
               (a) above; or
          (e)  Testing or monitoring programs approved by the Regional
               Administrator on a case-by-case basis.
     Over 90 percent of the injection wells in Osage County demonstrate
the presence or absence of a significant leak in the casing, tubing, or
packer through the standard pressure test (2a. above).
                                    -601-

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     However, early into the mechanical integrity test (MIT)  program,  it
was discovered there were some wells which had open perforations  above
the packer.  The operators and the BIA were reluctant to squeeze  off
these perforations, both because of the economics of the remedial  work
and the possibility that these zones might once again become  commercially
productive or could be used for an injection well in an enhanced  recovery
project.  Thus, the problem of being able to demonstrate the  mechanical
integrity of such wells.
     Region VI was not the only region or State to face this  problem.
Kansas has similar types of completions in S.E. Kansas, which is  adjacent
to Osage County.  Their program, having been in operation several
years ahead of the Osage UIC program, had already discovered  they had  no
practical means of testing these wells.  A memorandum, written in February
1984 by Harold Owens of EPA Region VII, suggested the possibility of
pressuring the annulus with air (or gas) and forcing the fluid level
down to the perforations.
     In search of a practical  and reliable method of testing  these wells,
Owens' suggestion was evaluated and it was determined that the principal and
procedure was very similar to the air line method used to measure fluid  levels
in some municipal wells with deep water levels.  The following method  is quoted
from the Missouri Water Well Handbook (Reference 1) and Figure 2  illustrates
the application of this method.
                                    -602-

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          Air Line:   One of  the best  methods  is  the  air  line which
          can be installed easily and permanently.   The  air line  is
          usually 1/8 or 1/4-inch copper  tubing  or galvanized  pipe,
          long enough to extend below the lowest water level to be
          measured.   The air line may be  fastened to the pump  bowls
          or cylinder and installed with  the  pump.   The  pipe must
          be airtight and care should be  taken in making up all
          joints. The vertical  length of the air line (A) from the
          pressure gauge to  the bottom of the line should be measured
          carefully  at the time of installation.

          A pressure gauge is attached to the air line at the  surface
          with an ordinary tire valve to  permit  attaching a tire  pump
          or air compressor  hose.

          To measure the depth to water at any time, pump air  into the
          air line until the maximum  reading  on  the  gauge is obtained.
          This reading is equal  to the pressure  exerted  by the column
          of water (B) standing outside of the air line. It is custo-
          mary to use an altitude pressure gauge reading directly in
          feet of water.  If the gauge reads  in  pounds per square inch,
          multiply by 2.31 to convert to  feet (or use the conversion
          table in Chapter I).

          The gauge  reading  in feet  (which equals the height B) is then
          subtracted from the total vertical  length  of air line (A) to
          obtain the depth to water  (C) in feet  below the center  of the
          gauge.

     The procedure was presented to a number  of  engineers, geologists, and

hydrologists for their opinions.  The opinions were  equally divided as to

whether it would or  would not work in the situation  for  which  it  was being

proposed.

     Early in 1985,  EPA's RSKERL in Ada,  Oklahoma had constructed a "leak

test" well for the purpose of providing a facility to develop  methods for

testing the integrity of the tubing,  casing and  packer of injection wells, as

required in EPA's UIC regulations.
                                   -603-

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     The "leak test" well was designed to represent and to operate like  a
typical injection well, with a few exceptions that were added to permit
the simulation of numerous different test conditions.  In addition to the
standard surface casing, longstring casing, tubing and packer, the well
is equipped with a second packer and a sliding sleeve on the injection
tubing and a 2 3/8" tubing attached to the outside of the long string
(Figure 3).  This rather unorthodoxed configuration permits the control
and monitoring of the desired conditions from the surface.
     A more detailed description of this well may be found in a paper by
Thornhill and Benefield (Reference 2) presented at the International
Symposium on Subsurface Injection of Liquid Wastes in New Orleans, March
1986.

Development of the Ada Pressure Test
     A test was designed to demonstrate the principle in the RSKERL test well
in December 1985.  With the well perforated from 1120 to 1130 feet and
the hole in the longstring casing, leading to the outside tubing, at
1070', the packers were set straddling the hole with the upper packer at
1057' and the lower packer at 1084'.
     The test was performed on the tubing in two parts: the first (test
A) with the sliding sleeve open, to represent a leak in the tubing at a
depth of 1070 feet; and the second (test B) with the sliding sleeve
closed, to represent a no leak situation.  The fluid level was measured  at
360 feet below the land surface with an acoustic fluid level instrument.
This gave us 710 feet of hyrostatic head above the open hole at 1070
feet and 760 feet of head above the top of the perforations at 1120

                                   -604-

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feet.  Using 2.31 feet* of water per psi, it was calculated that it
would require 307 psi to depress the water level to a depth of 1070 feet
and 329 psi (the formation pressure of the perforated zone) to depress
it to a depth of 1120 feet:
              710                             760
              "273"! =  307 psi                 "Ol  = 329 psi
*Note:  1 psi = 2.31 feet of fresh water was used because the casing had been
filled with fresh water before perforating and the same water was still in the
well.
     The following table represents what is theoretically taking place in
the well during the tests as air is added to the tubing.
(1)
Tubing
Gauge
Reading
(psi)
0
100
200
300
307
329
(2)
Depth to
Fluid
Level
(feet)
360
591
822
1053
1070 (Hoi
(3)
Hydrostatic
Head Above
the Perforations
(feet)
760
529
298
67
e) 50
1120(Perforations)0
(4)
psi
P
Fluid
Level
0
100
200
300
307
329
(5)
psi
§
hole
(1070')
307
307
307
307
307
329
(6)
psi
P
perf.
(1120')
329
329
329
329
329
329
With a static fluid level of 360 feet (column 2) below the land surface, the
hydrostatic head above the perforations would be 760 feet (column 3).  The
tubing gauge pressure (column 1) and the psi at the fluid level (column 4)
would both be zero.  This hydrostatic head would exert 307 psi  (column 5) at
the hole (1070 feet of depth) and 329 psi (column 6) at the perforations (1120
feet of depth).  As air is added from cylinders of compressed air, the gauge
pressure (column 1) increases and depresses the fluid level (column  2)
                                   -605-

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2.31 feet for every psi added, thus reducing the hydrostatic head (col. 3) by a
corresponding amount.  The amount of pressure at the gauge (column 1) and
pressure at the  fluid level  (column 4) remain equal to each other throughout
the procedure.   The pressure at the 1070-foot hole (during test A), 307 psi
(column 5), and  at the 1120-foot perforations, 329 psi (column 6), remain
constant throughout even though air pressure is being added.  The added air
pressure simply  replaces the lost hydrostatic pressure caused by depressing
the fluid level.
     In test  (A), with the sliding sleeve open, when 307 psig of air
has been reached, the fluid  level should be at a depth of 1070 feet and you
would not be able to add any more pressure because any addition of air will  be
lost through the hole.  If the source of air (cylinders) is shut off, and
there are no leaks in the system above the 1070-foot hole, the pressure should
remain 307 psi.
     In test  (B), with the sliding sleeve closed, you should be able to reach
329 psig before you could not increase pressure by adding more air.  At this
point the fluid  level  should be at the top of the perforations and any additional
air added would  be lost into the formation.  Again with the air source closed,
the pressure gauge will  continue to read 329 psig as long as there are no
leaks in the system.
     During test (A),  using cylinders of compressed air, air was added to the
tubing until the pressure would no longer increase.  This occurred at 300 psig,
a  little less than calculated, but considering the accuracy of the acoustic
fluid level  instrument we were close to getting the results we were looking for
and once the air source valve was closed, the pressure gauge remained at 300 psig.
     Test (B) was a different story.  After closing the sliding sleeve, compressed
air was again added to the tubing.  An excessive pressure (380 psig) was achieved
                                    -606-

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without reaching a maximum.  The cylinder valve was closed and the pressure
dropped to a point less than 329 psig.  The procedure was repeated several
times and each time the excessive pressure was added, the ensuing pressure
drop became less, but it never did stablize at 329 psig before we ran out of air
cylinders and aborted the test.  This indicated that the permeability of the
injection zone was probably extremely low and that even though the added pressure
was more than enough to depress the fluid level to the 1120-foot level, the
formation would not accept the water fast enough and the fluid level  was not
as deep as the pressure indicated it should be.  Since the well had been filled
with fresh water at the time the well was perforated, creating a pressure
inside the well higher than that of the formation, it was hoped that debri
clogging the perforations rather than a formation with extremely low permeability,
was responsible for the situation.
     Even though the tests did not go perfectly as planned, the results showed
that the principle was sound and that a practical, economical, and reliable
test could be developed.
     Several months later, the well was acidized and injectivity tests showed a
permeability of 125 md.  Test (B) was then successfully run without the problems
encountered on the original test.  Nitrogen was substituted for the compressed
air because when used on a formation which contains hydrocarbons, the compressed
air will cause a combustible mixture.  Also, it took less cylinders of nitrogen
to achieve the desired pressure and the cost was comparable to that of compressed
ai r.
Development of Procedures
     Based on the results of the tests conducted on the RSKERL "leak test" well
and the operational considerations learned through trial and error while performing
these tests, we developed procedures for an annulus pressure test on wells
with open perforations above the packer  (the "Ada" Pressure Test).  Those
procedures are as follows:
                                    -607-

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                               Test Requirements

1.  Must have at least 100 feet of cement immediately above the uppermost
    perforations.
2.  Must have at least 200 feet of water above the uppermost perforations  in
    the annul us  (must have an accurate static fluid level  measurement  and  know the
    depth to uppermost perforations).
3.  Must know the specific gravity or total  dissolved solids (IDS)  of  the  water
    in the annulus.
4.  There can be pressure on the tubing, but injection must be shut-in and the
    pressure stabilized.  The well should be shut-in long enough before the
    test for temperatures to stabilize.
5.  Must have at least a 500-foot interval  between base of USDW and the uppermost
    perforations, or a total of at least 100 feet of good shale (not silty or
    sandy shale), as determined from an electric log.
6.  Annulus water level  may not be above the base of USDW unless the casing is
    cemented from the land surface through  the base of the USDW.
7.  With the tubing and packer set at their normal injection depth, (a) tracer
    survey must be run through tubing, while injecting, to demonstrate no  leaks
    in the tubing or packer below the uppermost perforations, or (b) this  same
    type pressure test can be run in the tubing if:  distance between  injection
    perforations and bottom of tubing is at least 50 feet; water level in  tubing
    is at least 200 feet above perforations; fluid level  is measured;  and  the
    specific gravity or TDS of fluid and depth to perforations are  known.

       To make sure the  test is reliable in demonstrating  the protection of the
USDW's, we feel  the above requirements are  necessary.  The rational for each are:
1.  The cement above the uppermost perforations is required to prevent
    injected fluid from moving out the perforations and up the well bore in the
    event of a tubing or packer failure.
                                   -608-

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2.  The 200 feet of water above  the perforations  is  needed  to  require
    enough added pressure to adequately test the  casing.  An accurate static
    fluid level  and known depth  to perforations is needed to determine the
    hydrostatic head.
3.  The specific gravity or dissolved solids of the  water is needed  to
    accurately calculate the pressure needed to depress  the fluid  level.
4.  Shut-in during the test is needed to stabilize the effects of  temperature.
5.  The depth requirement below  the base of  USDW  is  to assure  an adequate
    confining layer above the upper perforations  in  the  event  there  is a tubing
    or packer leak and injected  fluid is injected into the  shallower zone with
    the upper perforations.
6.  If the water level in the annulus is above  the base  of  the USDW, the
    casing or surface  casing must be cemented from the land surface  through the
    base of fresh water to protect the USDW  in  the event of a  corrosion hole
    developing in the  casing.
7.  The tubing and packer must be tested independently from the annulus
    test because the annulus test does not tell you  if you  have any  leaks in the
    tubing, packer, or casing below the uppermost perforations. The reason for
    the 50 foot distance between the end of  the tubing and  injection perforations
    is so the pressure differential between  the two  points  is  sufficient that
    you will be able to recognize (interpret) a packer leak.

                                Test Procedures

1.  Calculate the pressure required to depress  the fluid level to  top of per-
    forations: Sp. Gr. X .433 = Gradient (psi/ft  of  head)  X water  column  =  psig
2.  Pressure the annulus (the tubing, if testing  the tubing and packer) using
    compressed nitrogen cylinders.  Be sure  the hoses and  gauges  are rated  to
    handle the high pressures of the cylinder.   The number  of  cylinders required
                                   -609-

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    will depend on the volume of the space above the perforations.
3.  When pressure at the wellhead will  not increase any  more  (be  sure there is
    still gas flowing from the cylinder into the well),  shut  off  the valve to the
   ..cylinder.
4.  Record the time and pressure.  Monitor the pressure  for  30  minutes.  Record
    pressures after 5, 10, 20 and 30 minutes.

                              Test Interpretation

1.  If you cannot pressure up - indicates a hole in the  casing  or tubing above
    the fluid level.
2.  If you cannot obtain the calculated pressure (step  1 of  the procedures) -
    indicates hole in tubing or casing  between the static fluid level and
    perforations and a lower pressure in the tubing or  formation.
3.  If the pressure calculated to force the fluid level  down  to the open
    perforations is obtained and can be held for 30 minutes  (no increase or
    decrease) - indicates integrity of  the tubing and casing  above the
    perforations.
4.  If you reach desired pressure or greater, and the pressure  decreases below
    the calculated value during the 30-minute hold period -  indicates a small
    leak above the perforations and a lower pressure in  the  tubing or formation.
    Note:  It may take more pressure than calculated before you reach the point
    where you cannot increase the pressure any more and, when shut-in, the
    pressure will  decrease to the calculated value, but  this  should be within 5
    minutes of shut-in and it should stabilize at or near the calculated value.
                                   -610-

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     In addition to testing wells  with perforations  above  the packer,  the
"Ada" pressure test can be used:
     1.  To test the casing in wells  without packers.
     2.  To test the tubing in wells  in which the tubing has  been  cemented in
         the casing.
     3.  To test the tubing and packer as  described  under  "Test  Requirements"
         7.(b) above.
     It has been suggested by some that we should take  into account  the weight
of the gas and temperature changes in the  gas.  To do so,  would  require a lot
of assumptions and calculations which would complicate  the interpretation and
thus reduce its usability in the field.  It may  be you  cannot use  the  test on
deep wells, but for the shallow wells of Osage County and  S.E. Kansas, it
works, it's simple, it's easy to interpret, it's relatively inexpensive,  and
it is reliable.  If there are errors  in this simplicity, we feel that  it  is on
the conservative side.   That is,  if the well passes  this test, we  feel that it
has demonstrated that the casing has  no holes above  the uppermost  perforations
and no leaks in the tubing or packer.
Case Histories or Field Application
     Using the above procedures,  we began  using  the  "Ada"  Pressure Test in the
Osage UIC program in January 1986. During 1986, we  tested 13 wells using
this method; 8 failed and 5 passed.  The following 3 case  histories  are examples
of the Ada Test as applied in the field.
                                  -611-

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      Case  history  #1  (illustrated in  Figure 4) represents a well that has
 been  re-entered, has  no  pressure on the tubing and has minimum casing around
 the tubing through which  the  salt water is injected.  Since there is 1560 feet
 of open  hole  surrounding  the  injection string, it would be impossible to apply
 pressure on the annul us  between the 2 3/8" tubing and 8" casing and be sure
 that  the entire length of tubing was being adequately tested for integrity.
 The Ada  Pressure test allows  the tubing to the tested internally throughout
 it's  length and the depth of  a leak (if any) to be determined by simple math-
 ematical calculations.
      The pressure  required to push the fluid level from 180 feet to 1836 feet
 was calculated to  be:
           (18361 - 180')  x 1.13 S.G. x .433 psi/ft = 810 psig.
      The operator  reached pressure of 432 psig before running out of Nitrogen.
 This  amount proved to the sufficient as the pressure began dropping immediately
 upon  the well being shut-in.  Figure 5 illustrates the corresponding relationship
 between  the pressure, shut-in time and fluid depth in the tubing during the test.
 Eighty minutes into the test  the pressure reached 370 psig and held steady for
 the next 30 minutes indicating through calculations that the fluid level and
 corresponding leak was at:
           370 psig 7 1.13 S.G. f .433 psi/ft + 180' = 936 feet
           It is significant that the operator found the leak at 938 feet
 during preparation for remedial work to bring the well into compliance, there-
 fore  demonstrating the reliability of the test in determining the depth of the
 leak.   It  should further  be noted that this test can only determine the existence
 and location of the uppermost leak should there be more than one present in the
we! 1.
                                    -612-

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     Case history #2 (represented in Figure 6) is a well  with pressure on  the
tubing and known perforations  in the casing. The mechanical  integrity of the
casing was previously demonstrated by setting the packer  above the uppermost
perforations and performing the standard pressure test.   The following calcula-
tions were made to determine the pressure requirements  to force the fluid
level from surface to the injection zone and demonstrate  mechanical  integrity
of the tubing and packer:

       1024.0 feet x 1.10 S.G. x .433 + 100 psig (tubing  pressure) = 588 psig

     The tubing was pressured to a maximum of 625 psig  with  Nitrogen.  Upon
shut-in, the tubing pressure decreased immediately to 600 psig and held for
30 minutes.  At this point, a  fluid level  was acquired  by an acoustic fluid
level instrument which confirmed that the liquid had been depressed to the top
of the injection interval at 1024 feet.  After the test was  run it was determined
that the actual specific gravity of the injection fluid was  1.13 instead of the
1.10 value used in the initial calculations.  Using a specific gravity of  1.13*
the calculated pressure for the test to push the fluid  level down to 1024  feet
is 601 psig.  This is a difference of 1 psig as opposed to 12 psig under the
original calculations.
     It is desirable that it be standard procedure to shoot  a fluid level  when
applying this test in the field since there are inherent  variables both in the
well construction and fluid properities in the wellbore that can affect the
relationship between the calculated pressure and the actual  final test pressure.
However, when specific gravity of 1.10 is used for salt water in the initial
calculation, it can be assumed that any pressure that exceeds the calculated
value and holds steady for 30 minutes is sufficient to demonstrate mechanical
integrity.
                                    -613-

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     Case history #3 represents one of the first wells  to have  this  test
applied to it and is an excellent example as to the reliability and  simplicity
of the test.
     Figure 7 details the construction of the well  and  defines  the conditions
in the well at the time the Ada Pressure test was run.   Figure  8 illustrates
the pressure-time-fluid level relationship as it evolved during the  course  of
the test.  From this data the following test analysis can be  made:
         Tubing Test
     1.  The pressure required to push the fluid level  from 150 feet
         to 1614 feet was calculated to be:

         (1614' - 150') x 1.13 S.6. x .433 psi/ft = 716 psig

     2.  The maximum pressure achieved was 705 psig. Upon shut-in,
         the tubing pressure steadily decreased, as shown on  Figure  8,
         until the pressure stabilized at 670 psig.  The test was repeated
         with the same results.
     3.  The leak in the tubing was calculated to be at:

         670 psig i 1.13 S.G.j .433 psi/ft + 150 feet = 1519  feet

         Although we know at this stage that the tubing has a leak,
         we do not know if the packer is also leaking since the fluid level
         is above the packer depth.
         Casing Test
     1.  This is a dual  completion well with 35 psig of gas pressure on the
         casing annulus.  The pressure required to  push the fluid level from
         562 feet to 748 feet was calculated to be:

         (7481- 562') x 1.08 S.G. x .433 psi/ft + 35 psig = 122 psig
                                   -614-

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     2.  The maximum pressure  achieved  for  the  test was  180  psig.   Five minutes
         after shut-in the pressure  had dropped to  120 psig  and  continued  to
         decrease for the next 30 minutes to 104 psig, at which  time  the test
         was terminated.   This indicated a  leak in  the casing  at or above:

         (104 psig - 35 psig)  7 1.08 S.G. f .433 psi/ft  +  562  feet  =  710 feet

     3.  The operator contended that the annul us contained oil instead of
         salt water.  If  a 39  API gravity of 0.830  S.G.  was  assumed to be
         present in the casing/tubing annulus,  the  calculated  test  pressure
         would have been:

         (748'- 562') x .830 S.G. x  .433 psi/ft + 35  psig  =  102  psig

         At the point where the test was terminated,  the inspector
         could have attempted  to add more pressure  to the  annulus.
         If the operator's contention was correct,  he would  not  have  been
         able to increase the  pressure  and  when shut-in, the pressure should
         remain stabilized at  about  102 psig for 30 minutes  if there  were  no
         leaks in the casing above the  upper perforations.   In this case,
         however, a fluid level was  obtained with an  acoustic  measuring instru-
         ment which showed the fluid level  to be above the perforations.   When
         the specific gravity  of the fluid  (or  fluids) is  not  known,  it is
         essential that an acoustic  fluid level instrument be  used  to confirm
         the validity of the calculations to the actual  test results.

CONCLUSIONS
     It is a viable test for demonstrating  whether  a  well  has  mechanical
integrity.  This relatively simple test will not only assure the protection  of
the underground sources of drinking  water,  but  will  provide  the  oil industry
with a relatively inexpensive means  of  demonstrating integrity of  their wells.
                                    -615-

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A demonstration which, because of their construction (i.e. perforations  above  the
packer), could not be made through the conventional standard pressure test.
     In many respects the "Ada" Pressure Test gives you more than the standard
annulus pressure test.  If the well fails the test, it not only tells you  that
you have a leak, but it will tell you at what depth the leak is occurring  and
whether it is relatively small or large.

     The test will not tell you if you have casing leaks below the upper
perforations, but if the well later (after testing) develops a leak in the
tubing or packer, the leaking fluids will go out those casing leaks or the
upper perforations.  By requiring the well bore to be cemented above the upper
perforations, this fluid is prevented from moving up the well bore.
     The test may not include everything or be as sensitive as some regulators
would like, but:
     1.  It does meet the requirements of the regulations;
     2.  It is simple to run and interpret;
     3.  It is reliable;
     4.  It is relatively inexpensive; and
     5.  It does provide a practical test for demonstrating mechanical integrity
         for a well which could not otherwise be tested.

                                   REFERENCES

1.  Missouri  Water Well  Drilling Association, "Water Well Handbook", 1959, 199
    pages (Edited by Anderson, Keith E.).
2.  Thornhill, Jerry T.  and Benefield, Bobby G., "Mechanical Integrity Research"
    Proceedings of the International Symposium Subsurface Injection of Liquid
    Wastes, pp. 241-278, March 3-5, 1986.
                                    -616-

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                                 ILLUSTRATIONS
Figures:
     1.  Map of Region VI Showing Location of Osage  County
     2.  Air Line Method of Measuring Water Levels
     3.  Sketch of the RSKERL "Leak Test" Well
     4.  Case History #1:  Well bore Schematic
     5.  Case History #1:  Pressure - Time - Fluid Depth  Plot
     6.  Case History #2:  Wellbore Schematic
     7.  Case History #3:  Wellbore Schematic
     8.  Case History #3:  Pressure - Time - Fluid Level  Relationships
                                    -617-

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                             MAP OF EPA REGION VI
                                  Osage County,  Oklahoma
FIGURE 1

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SCHEMATIC OF AIRLINE METHOD FOR MEASURING FLUID  LEVELS
Pressure Gauge
Compressor \ ^






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                                          Perforations
                       FIGURE 2
                          -619-

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RSKERL  "Leak Test" Well
                   680*
    .•,,.,.,,..,,.....,..,.... 905'
 Bifiji liiiii:
vx:w:m:? Saffiffiffi g35,
   1057' Deptn of
    upper packer
      Cement
       1070'
   1084' Deptft of
    lower packer
1. Baker nodel *C-1" landen Tmsion Pecker
2.  2 J/a" luolng
3. Wur nodel V Sliding Slew
4. Mur Hod«l *R' Profile Hippie
5. Mur Hodel 'Ad-l* Tension Packer
6. 2 VT tubing
7. Befctr flodti f Profile Hippie
I. leker Hodel f Profile Hippie
9. » 1/2" Long suing

                  INJECTION  ZONE
       FIGURE  3

              -620-

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CASE HISTORY II
Wellbore Schematic

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FIGURE 4
-621-

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^•^ — ^ 140' TD of 8" casing
—.180' Static Fluid Level in Tubing
* ,£—,140' - 1600' Open Hole
— 2 3/8" Tubing
•*"~X— 1631' Top of Cement
"Z 	 1800' Packer
**TL_»1836' to 1600' 5h" Casing
"2L-. 1872' TD

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(psig)
PRESSURE











434§
432
430
428
426
424
422
420
418
416
414
412
410
408
406
404
402
400
398
396
394
392
390
388
386
384
382
380
378
376
374
372
370
368
366
364
362
360
0 CASE HISTORY #1
o
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Pressure-Time-Fluid Depth Plot


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0
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916
5   15    25    35    45   55   65    75   85    95   105
  10   20   30   40   50   60   70   80   90   100  110
                   TIME (minutes)
                       Figure

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PASE HISTORY  12
Wellbore Schematic

                               #


                                r-
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Fu
                                            , Fluid Level  at Surface
                                              23/8"  Tubing
   1
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                                                  480'  Top of Perforations
                                                  610'  Top of Perforations
                                      %%-*-
          958' Packer
                                                  1024'  Top of Perforations
                                                 7" Casing
                                                   15391  TD
                                FIGURE  6
                                    -623-

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CASE HISTORY  #3

Wellbore Schematic
                                 C'"
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                                                -•» 35 psig Casing Pressure
                                           \::i
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                                                150'  Static Fluid Level
                                                     in Tubing

                                           -5
        562'  Static Fluid Level in
             Casing
                                                     748'  Top of Perforations

                                               2 3/8"  Tubing
                                                      Casing
                                                Sliding  Sleeve
                                                  1562' Packer


                                                1580' Bottom of Tubing



                                                    1614' Top of  Perforations



                                                     1648' TD
                                 FIGURE 7
                                     -624-

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Tubing Test
            Case History #3



PRESSURE-TIME-FLUID  LEVEL  RELATIONSHIP









                   Calculated
                                                                Calculated
Time
(minutes )
0
5
10
20
25
30
Test Pressure
(PSIG)
705
695
686
674
670
670
Fluid Level
Above Perforations
( Feet )
23
44
62
86
95
95
Fluid Level
Below Land Surface
(Feet)
1591
1570
1552
1528
1519
1519
Casing Test
                                       Calculated
Time
(minutes )
0
5
10
15
17
23
25
35
Test Pressure
(PSIG)
180
120
117.
114
112
108
108
104
Fluid Level
Above Perforations
(Feet)
(maximum pressure
4
11
17
21
30
30
38
V«-*-l- T_l_» -1_CA |_^U
Fluid Level
Below Land Surface
( Feet )
achieved for test)
744
737
731
727
718
718
710
                                   Figure 8



                                       -625-

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