PB85-197820
.Literature Review and  Survey of
Emissions from Residential Wood
Combustion and Their  Impact
Radian Corp.,  Research Triangle Park, NC
Prepared for

Environmental Protection Agency
Research Triangle  Park, NC
Aor 85
                    U.S. DEPARTMENT OF COMMERCE
                  National Technical Information Service
                                 NTTS

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                                     EPA/600/2-85/047
                                     April  1985
    LITERATURE REVIEW AND SURVEY OF

        EMISSIONS FROM RESIDENTIAL
    WOOD COMBUSTION AND  THEIR IMPACT
        M. W. Hartman and G. D. Rives
              Radian Corporation
               P. O. Box 13000
      Research Triangle Park, NC  27709
     EPA Contract:  68-02-3174, Task 139
   EPA Project  Officer: Robert C. McCrillis
Air and Energy Engineering Research Laboratory
       Research Triangle Park. NC 27711
                Prepared for:
    U.S.  Environmental Protection Agency
      Office of Research and Development
            Washington, DC  20460

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                                 TECHNICAL REPORT DATA
                          (Please read lutinictiuns on the reverse before completing)
1. REPORT NO.
  EPA/600/2-85/047
4. TITLE AND SUBTITLE
 Literature Review and Survey of Emissions from
   Residential Wood Combustion and their Impact
            3. RECIPIENT'S ACCESSION NO.
               PBS 5  197820 /AS
            5. REPORT DATE
             April 1985
            6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 M. W.  Hartman and G. D. Rives
                                                       8. PERFORMING ORGANIZATION REPORT NO
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Radian Corporation
 P. O. Box 13000
 Research Triangle Park,  North Carolina  27709
                                                       10. PROGRAM ELEMENT NO.
             11. CONTRACT/GRANT NO.
             68-02-3174, Task 139
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA. Office of Research and Development
 Air and Energy  Engineering Research Laboratory
 Research Triangle Park, NC  27711
                                                       13. TYPE OF REPORT AND PERIOD COVERED
                                                        Task Final; 9/83 -  3/84
             14. SPONSORING AGENCY CODE
              EPA/600/13
15. SUPPLEMENTARY NOTES AEERL project officer is Robert C. McCrillis, Mail Drop 54,
 919/541-2733.
 s. ABSTRACT Tne report gives results of a literature search 01 53 reports covering
 woodstove design,  operating conditions, emissions,  testing methods,  and ambient
 air impacts. The woodstoves studied, both controlled (catalytic) and uncontrolled,
 varied in design from simple to complex.  The primary considerations in operating
 conditions were  that the stoves burned primarily cord wood. Test results were seg-
 regated by the type of wood utilized,  the percent moisture in the tested wood,  the
 burn rate of the  wood,  the stage of burning that was  tested,  and the length of the
 test. In addition to the operating conditions, the emissions were qualified by the
 test method that was performed, the firebox temperature, and the stack tempera-
 ture. Emission parameters studied included particulate matter (PM), carbon mon-
 oxide, nitrogen oxides, hydrocarbons (HC), and polycyclic organic  material,  espec-
 ially benzo-a-pyrene.  This report includes ambient  air impact  surveys at various
 locations in the U.S. Most ambient studies were concerned with the PM and HC
 impacts,  but a few looked at relating these impacts back to their sources.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
  Pollution
  Combustion
  Wood
  Reviews
  Stoves
                                           b.IDENTIFIERS/OPEN ENDED TERMS
Pollution Control
Stationary Sources
Residential Wood Com-
  bustion
Woodstoves
                                                                      COSATI I k-U'lln>u|i
13B
2 IB
11L
05B
13A
13. DISTRIBUTION STATEMENT
 Release to Public
                                           19. SECURITY CLASS (Tliis Ki-ptirt)
                                           Unclassified
                                                                    21. NO. OF PAGES
                             108
20. SECURITY CLASS (This pane)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)

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              NOTICE

THIS DOCUMENT HAS BEEN REPRODUCED
FROM THE BEST COPY FURNISHED US  BY
THE SPONSORING AGENCY.  ALTHOUGH  IT
IS RECOGNIZED THAT CERTAIN PORTIONS
ARE ILLEGIBLE, IT IS BEING RELEASED
IN THE  INTE'REST OF MAKING AVAILABLE
AS MUCH INFORMATION AS  POSSIBLE.

-------
                      NOTICE

This document has been reviewed in accordance with
U.S. Environmental Protection Agency policy and
approved for publication.  Mention of trade names
or commercial products does not constitute endorse-
ment or recommendation for use.
                       11

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                                ABSTRACT

     This report resulted from a literature search of 53 reports covering
woodstove design, operating conditions, emissions, testing methods, and
ambient air impacts.  The woodstoves studied varied in design from
simple to complex and included controlled (catalytic) and uncontrolled
woodstoves.   The primary considerations in operating conditions were
that the stoves studied burned primarily cord wood.   The results of the
tests were segregated according to the type of wood utilized, the percent
moisture in the wood as tested, the burn rate of the wood in kg/hr, the
stage of burning which was tested, and the length of the test.   In
addition to the operating conditions, the emissions were qualified by
the test method which was performed, the firebox temperature, and the
stack temperature.   Emission parameters studied included particulate
matter (PM), carbon monoxide (CO), nitrogen oxides (NO ), hydro-
carbons (HC),  and polycyclic organic material (POM), especially
benzo-a-pyrene (BAP).  This report includes ambient air impact surveys
at various locations in the United States.   Most ambient studies were
concerned with the particulate matter and hydrocarbon impacts but a few
looked at relating these impacts back to the sources.

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                            TABLE OF CONTENTS

Section                                                             Page
   1     INTRODUCTION  	   1-1
         1.1  Background	1-2
   2     SUMMARY	2-1
   3     CHARACTERIZATION OF EMISSIONS  FROM RESIDENTIAL
         WOOD COMBUSTION	3-1
         3.1  Data Bank Compilation Analysis	3-1
         3.2  Individual Study Analysis  	   3-19
         3.3  Variables Affecting Emissions  	   3-22
   4     AIR SHED STUDIES AND IMPACT ASSESSMENT  METHODS   	   4-1
   5     SAMPLING AND ANALYTICAL METHODS  	   5-1
         5.1  Sampling, Source 	   5-1
         5.2  Sampling, Ambient  	   5-9
         5.3  Lab	5-12
   6     ADVANCED DESIGN APPROACHES TO  RESIDENTIAL
         WOOD BURNING APPLIANCES	   6-1
         6.1  Cord Wood Designs	6-1
         6.2  Noncord Wood Designs	6-2
  7.0    REFERENCES	7-1
  8.0    APPENDIX	8-1
          Preceding page blank

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                             LIST OF FIGURES


Figure                                                              Page

 3-1     CO vs.  burn rate	3-15

 3-2     CO (g/hr) vs.  burn rate (kg/hr)	3-16

 3-3     Comparison of emissions from several wood heaters ....   3-25

 3-4     Summary of total particulate emission factors
         versus  wood burn rate	2-27

 3-5     Summary of condensible organic emissions factor
         versus  wood burn rate	3-28

 3-6     Variation of carbon monoxide with firing rate,
         conventional stoves 	   3-29

 3-7     HC emissions for several stoves as a function
         of burn rate	3-30

 3-8     Summary of total organic emission factors (g/kg) as a
         function of burn rate (kg/hr) from combustion of 0.12M
         and 0.06M diameter oak logs	3-31

 3-9     Variation in POM emissions with firing rate,
         conventional stoves 	   3-32

 3-10    Concentration of CO in flue gas as a function of time .  .   3-33

 3-11    Particulate emissions (normalized to burn rate) as
         a function of fuel moisture	3-37

 3-12    Effect  of wood size on CO emission factors	3-39

 3-13    (The effect of varying operating conditions on
         condensible particulate emissions of the thin-walled
         convective heater.)  Compare standard runs (small dots)
         with emission factors (large dots) produced by varying
         wood size and moisture.  Note extreme effects caused by
         burning 1 inch logs.   Dots represent sample means and
         vertical bars represent 97 percent confidence limits  .  .   3-40

                               (continued)

                                   vi

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                       LIST OF FIGURES (Concluded)



Figure                                                              Page


 5-1     Semi-VOST train schematic diagram 	   5-2


 5-2     State of Oregon Source Sampling Method 7  	   5-4

          2
 5-3     S  dilution sampling system 	   5-5


 5-4     Condar Company sampling system  	   5-7


 5-5     SASS schematic diagram	5-8


 5-6     Schematic of NuTech thermal desorption device 	   5-10


 5-7     Assembled Hi-Vol sampler with shelter housing 	   5-11

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LIST OF TABLES
Table
3-1
3-2

3-3
3-4
3-5
3-6

3-7

3-8

3-9

3-10

3-11
4-1

Woodstove Data (Airtight Stoves) 	
Listing of Woodstove/Emission Studies Used as the
Basis for Trend Analysis 	
Woodstove Data (Burn Rate Ranking) 	
Woodstove Data (Catalytic Stoves) 	
Particulate Emission Factors 	
Carbon Monoxide Emissions from Residential
Wood Combustion 	
Total Hydrocarbon Emissions from Residential
Wood Combustion . '. 	
Polycyclic Organic Matter Emissions from
Residential Wood Combustion 	
Summary of Emission Results for Criteria Pollutants and
POMs from Wood Fired Residential Combustion Equipment . .
Effects of Size of Charge on Emissions,
Side Draft Burning of Oak 4x4s 	
Particulate Emission Rates from Wood Burning (g/kg) . . .
Air Shed Studies and Impact Assessment Methods 	
Page
3-2

3-7
3-10
3-18
3-20

3-20

3-21

3-21

3-24

3-35
3-36
4-2
     vm

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                            1.  INTRODUCTION

     Radian Corporation has concluded a literature search of available
data on woodstove emissions.  In the computer search of various libraries
of information, 239 citations were identified through the use of a key
word listing which was primarily for residential wood combustion emissions
and their impact.  Approximately half of these were unique citations and
of that number, 53 were chosen as applicable to this study.   A compu-
terized abstract of the 53 citations are contained in the appendix.  The
key word listing is located in the Appendix.  The citations and literature
studies came from all sectors of industry and government.   To date,
there has been no one agency or association, which has coordinated all
of the work which has preceded this study.   The result was that the
information was mostly piecemeal as to its content, purpose and methods
utilized.
     The report discusses the various aspects of Residential Wood
Combustion (RWC).  Section 2.0 presents the summary and conclusions of
this literature review.   Section 3.0 summarizes the various emission
ranges for the pollutants.   Since the methods, stoves, wood burned, and
conditions vary from citation to citation,  this section is only concerned
with overall trends.   Section 4.0 is a review of some of the literature
derived from ambient air studies of various air sheds and also discusses
the tracer compounds or methods that have been utilized to link ambient
samples to woodstove emissions.   Sampling and analytical methods employed
in the testing of stoves and ambient studies are discussed in Section 5.0.
Section 6.0 is titled Alternative Design Approaches to Residential  Wood
Burning Appliances.
                               1-1

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1.1  BACKGROUND
     The use of wood for residential heating, while aesthetically pleasing
and economically attractive, may carry a potential for adverse health
effects to large segments of the population.  The impact of RWC on
ambient particulate emissions is especially noticeable because the plume
impacts the ground very near the source.  In addition, the areas of
highest RWC emission density often coincide with the areas of maximum
population density and the majority of the RWC particulate emissions are
within the size range deposited within the lungs.  RWC emissions are
relatively rich in carcinogenic organics, toxic pollutants and respiratory
irritants.   For all of these reasons, wood smoke represents a problem
that is of growing public concern.
     The chemical  products formed during wood combustion have recently
been shown to contain 17 priority pollutants, 14 carcinogenic compounds
and 6 toxic or mucus coagulating agents which, when considered in addition
to toxic gaseous emissions and respiratory irritants, collectively
represent a potential health risk.
     RWC emissions are becoming increasingly important as a major
contributor to violations of current particulate air quality standards
and are implicated in issues related to visibility reduction, odors and
public health.  New attention being focused on the adoption of an
Inhalable Particulate National Ambient Air Quality Standard has also
caused concern about the RWC impact on 24-hour particulate standard
attainment.  The continuing economic pressures to expand the use of wood
and coal for residential heating, and the limited regulatory pressures
restricting the use of wood, may cause additional concern about the
impact of RWC emissions on public health, aesthetics and the future
"livability" of many communities.
                                 1-2

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                               2.  SUMMARY

     This report resulted from a literature search of 53 reports covering
woodstove design, operating conditions, emissions, testing methods, and
ambient air impacts.  The woodstoves studied varied in design from
simple to complex and included both controlled (catalytic) and uncon-
trolled woodstoves.   The stoves studied burned primarily cord wood.  The
results of the tests were segregated according to the type of wood
utilized, the percent moisture in the wood as tested, the burn rate of
the wood in kg/hr, the stage of burning which was tested, and the length
of the test.   In addition to the operating conditions, the emissions
were qualified by the test method which was performed, the firebox
temperature,  and the stack temperature.  Emission parameters studied
included particulate matter (PM), carbon monoxide (CO), nitrogen
oxides (NO ), hydrocarbons (HC), and polycyclic organic material (POM),
          /\
especially benzo-a-pyrene (BAP).  This report includes ambient air
impact surveys at various locations in the United States.  Most ambient
studies were concerned with the particulate matter and hydrocarbon
impacts but a few looked at relating these impacts back to the sources.
     The test methodologies used for both the source testing of wood-
stoves and for the ambient impact varied from study to study.   As a
result, few conclusions or trends could be drawn from the combined
studies. Conclusions and trends are seen within each study although the
reader must exercise caution as to the test method and the test conditions
utilized to achieve these conclusions.  An overview of the testing
methods and analytical techniques is presented in this report with no
conclusions or recommendations made.   The individual studies selected a
test method which best suited their needs for the data.  There is no
standard method of sampling and analysis for woodstove emissions.   ASTM
                                 2-1

-------
is working on a standard for sampling and analysis.  Also, there is no
standard set of conditions for the operation of the woodstoves, although
guidelines are available.
     Since the widespread use of woodstoves is a recent reoccurrence,
the use of controls on them is still somewhat rare.  The studies that
evaluated control devices (i.e., catalytic, secondary combustion, or
modified combustion) all reported variable decreases in emissions relative
to standard stoves.  No control devices appeared to dramatically reduce
emissions under all conditions.
                                 2-2

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                    3.  CHARACTERIZATION OF EMISSIONS
                    FROM RESIDENTIAL WOOD COMBUSTION
     Numerous studies have been conducted which characterize emissions
from residential wood combustion appliances.  The goals and objectives
of these investigations vary considerably and consequently the resulting
emission characterizations also show considerable variation.  For example,
different emission test methods have been used to develop emission
factors for a number of stove types using wide ranges of operating
conditions and a diversity of fuel types.  Test conditions have not been
well defined and consequently, reproducible and comparable data have not
been produced.
3.1  DATA BANK COMPILATION ANALYSIS
     Emission measurements and test conditions reported in 13 studies
were compiled into a data bank and used as the basis for the data analyses
performed (see Table 3-1).  The 13 studies selected were those that
reported detailed information about test conditions, emission measurements,
and stove operating parameters.  From each of the chosen studies,
measurements conducted during individual test runs were included in the
data bank rather than overall summaries or averages (for the purpose of
identifying overall emission trends.)  A listing of each data source
along with an assigned study code is presented in Table 3-2.  The assigned
study code provides a quick reference back to the original source of the
data and identifies the test run.
     The data retrieved from each of the studies may be categorized as
either "Emission Measurement data" or "Test Condition data."  All of the
data is presented on a wet basis.   Emission measurement data include
particulate matter (PM), carbon monoxide (CO), nitrogen oxides (NO ),
hydrocarbons (HC), and polycyclic organic matter (POM).  Except for POM,
all emission parameter values are expressed as grams of pollutant per
kilogram of wood burned.  In the case of POM, the emission value is

                                3-1

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Table 3-1.  WOODSTOVE DATA (AIRTIGHT STOVES)





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                     3-2

-------
Table 3-1.   Continued

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9.60
74.30
23.30
14.20
15.50
8.00
6.00
17.10
24.40
22.00
1 .40
4.50
12.60
3.90
13.30
21 .90
14.40
0.50
0.90
10.40
22.40
28.20
29.40
7.20
37.00
32.40
44. 40
3.20
5.00
7.50
6. 10
3.50
3.60
4.20
,— *. Cn
Cn -^
-* ^v.
^ en
en >—
X
0 0
o z
59
61



220
280
170
400
200
25
30

















1.57
153
174
21
40
130
194
157
153
174
21
40
130
216
298
281
1 18
216
298
281
1 18
134
59
101
43
134
. 59
en
•— > -*
en ^
-^ en
cr* ~— ~
*~" s:
<-> o
a: a.
5.0
7.0 0.05



34.0
32.0 0.01
34.0
42.0
33.0
5.0 0.01
2.0

















35.2
20.2
52.3
61 .3
59.5
84.8
45.9
35.2
20.2
52.3
61.3
59.5
84.8
63.4
85. 1
72.2
62.6
63.4
85. 1
72.2
62.6
55.3
77.7
73.0
44.6
55.3
77.7

-------
Table 3-1.   Continued

3 TJ
•(-> 0
CO <_)
OM2-84-28
OM2-84-29
OM2-84-30
OM2-84-31
OM2-84-32
OM2-84-33
OM2-84-34
OM2-84-35
OM2-84-36
OM2-84-37
OM2-84-38
OM2-84-39
OM2-84-40
OM2-84-41
OM2-04-42
OM2-84-43
OM2-84-44
OM2-84-45
OM2-84-46
OM2-84-47
OM2-84-48
OM2-84-49
BE-81-1
BE-81-2
BE-81-3
BE-81-4
BE-81-5
BE-81-6
BE-81-7
3E-81-8
3E-81-8
3E-81-8
TVA-83-1
TVA-83-2
TVA-83-3
TVA-83-4
TVA-83-5
TVA-83-6
TVA-83-7
TVA-83-8
TVA-83-9
TVA-83-10
TVA-83-1 1
TVA-83-12
TVA-83-13
TVA-83-14
TVA-83-15
B2-81-1A
B2-81-2A
B2-81-3A
B2-81-4A
B2-81-5A
BS-81-1
BS-81-2
BS-81-3
BS-81-4
 E
+-» rc^— . (U
 CC J- I—
O C ^» <\}*~*
T£. S- cn i- c_>
3 -* -i-O
3*3 CD ^— " LL ~ -^
17 1.6
19 0.6
18 1.2
18 1 .0
18 0.8
19 1 .5
19 1.6
19 0.9
18 1 .0
19 4.3
19 1 .6
19 0.9
18 1 .0
19 4.3
19 1.1
19 0.7
19 1.5
19 1.7
19 1.1
19 0.7
19 1.5
19 1 .7
18 3.0
18 1 .7
18 2.0
18 2.2
16 2.9
16 1 .7
16 2.2
13 2.3
16 3.4
16 3.1
10 2.2
10 2.2
10 5.8
10 5.8
10 8.5
10 8.5
10 1 .3
10 1.3
10 2.0
10 2.0
10 2.9
10 2.9
10
10
10
12
42
12
12
21
23 2.0 158
23 1.7 154
23 2.0 160
23 1.7 148
a. 
CO
a>
>*-» c
o o s_
•MD 3
co>— -co
111 A
54 A
74 A
61 A
58 A
98 A
1 19 A
76 A
86 A
303 A
119 A
76 A
86 A
303 A
85 A
81 A
166 A
226 A
85 A
81 A
166 A
226 A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
370 A
310 A
510 A
380 A
170 A
137 0
149 0
132 0
133 0

-------
Table 3-1.  Continued
-o  0
>

oo
NB
NB
NB
NB
N8
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
B
B
B
NB
NB
CER
NB
NB
1
0
D
0
D
0
D
0
D
0
0
0
0
0
0
0
0
0
0
D
0
0
0
0
0
D
0
D
0
0
0
0
D
D
D
D
D
0
0
D
D
0
0
0
0
D
0
D
D
T3
o
•M
>
-a
o
o
3
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
% Moisture
23
23
23
23
23
23
23
19
3
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23 .
23
23
23
23
23
23
23
23
23
23
23
23
23
• 

3 -*
CQ^—
1 .3
1 .9
1 .4
3.2
2.3
1.8
1 .6
1 .5
2.3
1.9
1 .4
1 .8
1 .8
1 .0
2.8
1 .6
1 .9
1 .7
1 .1
2.3
3.4
1 .5
2. 1
2.8
2.3
2.3
3.2
1.8
2.6
3.2
1 .6
2.7
2.3
2.4
2.0
2.9
2.4
1 .7
1.3
2.8
2.3
1 .9
2.4
1 .5
1 .4
1 .7
3.2
2.9 •
a.

h-
q}*-*
1. 0
•r-0
|J_. -^^
96
97
123
21 1
163
154
156
145
163
154
144
154
152
99
203
156
165
172
92
146
194
97
143
174
133
153
203
1 19
158
202
96
150
208
147
94
196
153
150
161
139
147
148
153
158
96
143
196
144
a.
at
f-
OJ
>^-
0 
oo
. c
i S_
3
-co
0
0
0
0
0
D
0
D
0
0
D
0
D
0
D
D
D
D
0
0
D
D
0
D
0
D
D
0
0
0
D
0
0
D
0
0
D
D
0
0
0
D
0
D
0
0
0
0
^
^t ^. ~~^ -* en
•^. ^ o> -^. e
a> en — cr —
""""* """"' X 2!
z o o o o
a- <-> z ^ a-
10.10
14.00
11.10
3.20
10.30
10.70
6.10
14.50
15.00
25.20
5.80
9.90
5.30
12.30
2.10
12.20
7.60
9.20
11 .80
10.60
2.20
10. 10
7.30
3. 10
5. 10
5.80
1.90
10. 10
3.70
2.40
7.70
3.70
2.50
4.00
8.50
2.10
3.40
3.20
8.00
4.00
4.30
4.70
3.90
3.20
3.60
2.40
1.10
3.60
       3-5

-------
                          Table 3-1.  Concluded
Stove Type
  B - Baffled
CAT - Catalytic
C-R - Catalytic Retrofit
CER - Ceramic
 NB - Nonbaffled
  0 - Other (includes modified combustion stoves and/or stoves that
      could not be classified into one of the other categories due to
      insufficient description)
  J - Jotul 201

Test Method
MM5 - Modified Method 5
 M7 - Oregon Method 7
OIL - Dilution Method

Wood Type
  0 - Oak
  P - Pine
 OF - Douglas Fir
 SM - Sugar Maple

Burn Stage
  A - Testing took place over an entire burn cycle with the fire being
      started from hot coals
  B - Testing took place over an entire burn cycle beginning with a cold
      start
  C - Testing only took place during the constant burn (steady-state)
      stage of the burn cycle
  D - Testing took place over several burn cycles (additional fuel
      charges) with the fire being started from hot coals
                                 3-6

-------
               Table 3-2.  LISTING OF WOODSTOVE/EMISSION STUDIES
                     USED AS THE BASIS FOR TREND ANALYSIS
Study Code                                   Reference

MI-80               "Preliminary Characterization of Emissions from Wood-Fired
                    Residential Combustion Equipment," March 1980, Monsanto
                    Corporation, DeAngelis, Ruffin, and Reznik.

RTI-83              "Characterization of Emissions from the Combustion of Wood
                    and Alternative Fuels in a Residential Woodstove," March
                    1983, Research Triangle Institute, Truesdale, Mack, White,
                    Leese, and Cleland.

DG-82               "Residential Wood Combustion Study; Task 5, .Emissions
                    Testing of Wood Stoves - Volumes 1&2," November 1982, Del
                    Green Associates, Grotheer.

CCRL-81             "Performance of Domestic Wood-Fired Appliances," 1981
                    Canadian-Combustion Research Laboratory, Hayden and
                    Braaten.

M2-81               "Wood Combustion Emissions at Elevated Altitudes,"
                    Monsanto Corporation, Peters, Hughes, and DeAngelis.

Bl-81               "Control  of Emissions from Residential Wood Burning-by
                    Combustion Modification," 1981, Battelle and Allen.

0-81                "Particulate Emissions from New Low Emission Woodstove
                    Designs Measured by EPA Method V," 1981, Oregon Depart-
                    ment of Environmental Quality, Kowalczyk, Bosserman,  and
                    Tombleson.

OM1-83              "Test Report prepared for Catalytic Damper Corporation,"
                    May 1983, Omni.

OM2-84              "Test Report Woodstove Emissions and Efficiency," February
                    1984, Omni.1

BE-81               "Particulate Emission Factors for SmalKWood and Coal
                    Stoves,"  1981, Butcher and Ellenbecker.

TVA-83              "Efficiency and Emission Performance of Residential Wood
                    Heaters9With Advanced Designs," 1983, TVA, Knight and
                    Knight.

B2-81               "Characterization of Emissions from Residential Wood
                    Combustion Sources," 1981, Battelle, Cooke, Allen, and
                    Hall.

BS-81               "Effects  of Woodstove Design and Operation on Copdensible
                    Particulate Emissions," 1981, Barnett and Shea.
                                    3-7

-------
expressed as milligrams of pollutant per kilogram of wood burned.  Test
condition information collected from each of the studies includes:  the
type of stove tested, method used for measuring particulate, moisture
content of the fuel (expressed as wet basis), type of fuel, burn rate,
firebox and stack temperatures, stage of the burn cycle during sample
collection, and the length of the sampling period.  Abbreviations or
qualifiers were used to describe parameters such as stove type, test
method, wood type, and burn stage and are defined at the end of Table 3-1.
     In several studies, test conditions were not reported in detail.
In such cases, the data incorporated into the data bank were somewhat
subjective based solely on inferences or indirect evidence presented in
the original study.  For example, if a study did pot document the burn
rate, but did provide the initial charge loading and the total sampling
time, burn rate was calculated based on the assumption that all of the
fuel was burned during the reported sampling period.   Other cases in
which approximate values were included in the data set include instances
when the value of a parameter was reported as a range (e.g., fuel
moisture = 20-25 percent).  In such cases, the average of the reported
range was used.  If sufficient information was not provided in the text
to allow these values to be determined or approximated, the entry was
left blank.  When approximations were used, every attempt was made to
represent the conditions of the study as accurately as possible.
3.1.1  Data Analysis
     As mentioned before, the number of variables and the uncertainty of
the validity of each variable has made this study one of general  trends.
These trends can be best pointed out by comparing a dependent and
independent variable graphically.  Burn rate was selected as the
independent variable.   When this is done and certa.in outlying points are
discarded, some trends become noticeable.  The largest problem encountered
with this type of analysis was the uncertainty which results from
analyzing a data set consisting of measurements collected by different
test methods and using different stove types and operating parameters.
An example of this can be seen when evaluating the effect of burn rate
on particulate emissions.  Individual studies demonstrate that particulate
emissions decrease with increasing burn rate.  However, when particulate
measurements from all  studies are reviewed and analyzed against burn
                                 3-8

-------
rate, the trend is much weaker.  The reason for this is that each testing
group defined particulate with a different set of parameters.  Some
investigators defined particulate as front filter catch at 250°F, whereas
others included various combinations of filter catch and condensed
organics.
     In addition to the problems of definition are the problems of
plotting the graphs by overall studies.  One study included 61 test
runs, while others had as few as two test runs.  This problem is
accentuated if the author did not report measurements for the parameters
of interest.  The NO  results are a good example of this.  Only
25 individual tests from two studies measured NO .   The results were
                                                /\
similar.   However, it is difficult to indicate a trend for 16 studies
and 217 tests with this limited data.  The same is true for POM
measurements.
     As noted previously, burn rate was selected as the independent
variable.  The data in the data bank were arranged so that the tests
were ranked in order of increasing burn rate (see Table 3-3).
3.1.2  CO Analysis
     The results of the CO analysis for the tests provided unexpected
results.   Except for the catalytic type, it appears to make no difference
which stove is used.   When presented on an emission factor (g/kg wood
burned) basis, the CO emissions remain fairly constant as the burn rate
increases (see Figure 3-1).  However, when these results are plotted on
an emission rate basis vs.  burn rate, the CO emissions appear to increase
as the amount of wood burned per hour is increased (see Figure 3-2).
This latter result would tend to indicate that fireplaces yield a much
higher CO emission rate than do woodstoves which generally are run at
lower burn rates.   The highest CO emissions rate noted in the literature
was 5,000 grams/hour.     The observed CO trends run counter to some
                23
studies  results   which showed a decrease as the burn rate was increased.
The methods by which the results were obtained were unclear in some
cases; and the level  of quality control exercised was in most cases, not
addressed.  Thus,  the trends noted here must be interpreted with caution.
                                 3-9

-------
Table 3-3.  WOODSTOVE DATA (BURN RATE RANKING)






>>
-a  O
(S> O
Bl-81-1
B1-81-2
81-81-3
B1-81-4
B1-81-5
B1-81-6
B1-81-7
B1-81-8
B1-81-9
82-81-1A
B2-81-2A
B2-81-4A
TVA-83-13
TVA-83-14
81-81-10
81-81-11
81-81-12
B2-81-3A
B2-81-5A
TVA-83-15
OM2-84-25
OM2-84-29
OM2-84-3
OM2-84-7
OM2-84-43
OM2-84-47
OM2-84-10
OM2-84-22
OM2-84-26
OM2-84-32
OM2-84-15
OM2-84-19
OM2-84-35
OM2-84-39
OM2-84-31
OM2-84-2
BS-81-27
OM2-84-36
OM2-84-40
OM2-84-9
BS-81-32
OM2-84-16
OM2-84-20
OM2-84-42
OM2-84-46
CCRL-81-1
i
I—

at
>
o
+j
oo
B
B
B
B
8
B
B
B
B
B
B
B
CAT-RET
CAT/B
NB
NB
NB
NB
0
0
CAT
CAT
J
J
NB
NB
0
CAT
CAT
CAT
NB
NB
NB
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CAT
J
NB
NB
NB
0
NB
NB
NB
NB
NB
B
•o
o
-C
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s

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ai
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MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM 5
MM5
MM5
MM5
MM5
M7
OIL
M7
M7
M7
OIL
OIL
M7
OIL
M7
M7
OIL
M7
OIL
M7
M7
OIL
M7
OIL
OIL
OIL
M7
OIL
M7
OIL


>
I—

•o
o
o
2
0
0
0
0
p
0
0
0
0
0
p
0
0
0
0
0
0
0
0
0
OF
OF
OF
OF
OF
DF
OF
OF
OF
OF
DF
OF
DF
OF
DF
DF
0/SM
OF
DF
OF
0/SM
OF
DF
DF
DF
SM
ai
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1/1
ai
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OO 	 CQ
A
A
360 A
A
A
A
A
A
A
370 A
310 A
380 A
A
A
A
A
A
510 A
170 A
A
54 A
54 A
68 A
88 A
81 A
81 A
68 A
73 A
73 A
58 A
68 A
68 A
76 A
76 A
61 A
90 A
86 0
86 A
86 A
90 A
1 17 D
81 A
81 A
85 A
85 A
44 B
a>

z 3:
112
12.0
15.0
28.0
9.0
56.0
56.0
5.0
7.0
28.0
9.0
5.0
1 .01
0.82 0.2



32.0
5.0
1.14 0.1
44.6
44.6
52.3
45.9
17.8
17.8
52.3
55.3
55.3
54.9
85. 1
85. 1
54.2
54.2
56.9
20.2

80.3
80.3
20.2

72.2
72.2
30.2
30.2
39.0
CD
_ii

CD

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^
o
a.



0.03
0.04



0.05
0.04
0.05
0.05
0. 19
0.16



0.02
0.01
0.08


























                  3-10

-------
Table 3-3.  Continued
•o 
3 -0
•M O
1/1 O
OM2-84-30
OM2-84-1
OM2-84-8
TVA-83-7
TVA-83-8
BS-81-14
BS-81-52
OM2-84-23
OM2-84-27
OM2-84-6
BS-81-16
BS-81-24
BS-81-58
OM2-84-13
CCRL-81-6
OM2-84-33
OM2-84-5
BS-81-21
BS-81-35
BS-81-57
BS-81-6
OM2-84-44
OM2-84-48
0-81-12
OM2-84-12
OM2-84-24
OM2-84-28
BS-81-12
BS-81-20
BS-81-29
BS-81-44
BS-81-7
OM2-84-34
OM2-84-38
0-81-10
BS-81-59
BE-81-2
BE-81-6
BS-81-11
8S-81-2
BS-81-37
BS-81-4
BS-81-51
OM2-84-14
OM2-84-18
OM2-84-45
OM2-84-49
CCRL-81-2
0-81-6
0)
a.
>,
0)
>
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4->
GO
CAT
J
0
CAT
CAT
NB
NB
CAT
CAT
J
NB
NB
NB
0
B
CAT
J
NB
NB
NB
NB
NB
NB
NB/0
0
CAT
CAT
NB
NB
NB.
NB
NB
NB
NB
NB/0
CER
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
B
CAT
TO
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j=
+j


>
h- .
•a
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0
OF
OF
OF
0
0
0/SM
0/SM
OF
OF -
OF
0/SM
0/SM
0/SM
OF
SM
OF
OF
0/SM
0/SM
0/SM
0/SM
OF
OF
OF
OF
OF
OF
0/SM
0/SM
0/SM
0/SM
0/SM
OF
OF
OF
0/SM
0
0
0/SM
0/SM
0/SM
0/SM
0/SM
OF
OF
OF
OF
SM
OF
% Moisture
18
16
16
10
10
23
23
19
19
18
23
23
23
18
16
19
20
19
23
23
23
19
19
14
20
17
17
23
23
23
23
23
19
19
14
23
18
16
23
23
23
23
23
17
17
19
19
16
18
L)
3 ^*™>i
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3 -*
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.2
.2
.3
.3
.3
.3
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.4
.4
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.4
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.4
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.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.6
.6
.6
.6
.6
.6
.6
.6
.6
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.7
.7
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GO —
74
11 1
11 1


104
192
104
104
132
102
136
116
132
122
98
182
1 18
126
163
142
166
166
104
182
1 1 1
111
161
137
138
134
137
119
1 19
124
160


183
149
136
133
179
1 18
1 18
226
226
67
125
ai
cn
ITS
+->

_*:
cn
Si
a.
1.50
17.10
13.30
16.80
5.10
10. 10
8.00
7.50
4.20
12.60
11.10
5.80
3.60
10.40

1 .50
4.50
14.50
10.10
3.20
9.90
9.70
6.90
74.30
0.90
6.10
4.10
8.70
6. 10
12.20
7.70
9.10
18.30
20.60
50.60
2.40
4.30
3.80
12.90
7.80
9.20
1 1 .00
3.20
22.40
37.00
3.40
0.60

29.30
--^ ai
cn -*
it ^
•-^ ai
cn ^-*
X
O 0
o z
25
157
157
28 0.03
26 0.85


59
59
130



130
87
48
40




88
88

40
101
101





175
175


63






216
216
66
66
140

'cn
cn ^
j* cn
en - —
"~^ S
O O
:c a.
53.8
35.2
35.2




77.7
77.7
84.8



84.8
20.0
65.7
59.5




40.4
40.4

59.5
73.0
73.0





71 .6
71 .6









63.4
63.4
43.9
43.9
33.0


-------
Table 3-3.  Continued
T3 <1>
3 -O
•M 0
,

o
-(->
oo
NB
NB
NB
NB
NB
NB
NB
NB
B
NB
NB
NB
CAT
CAT
NB
NB
NB
NB
CAT
NB
NB
NB
NB
NB
B
NB
NB
NB
NB
NB
NB
NB
B
NB
NB
NB
NB
NB
J
NB
0
CAT
CAT-RET
NB
•a
o
4->
g
-M
01
O)
1—
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL •
OIL
OIL
OIL
MM5
MM 5
OIL
OIL
OIL
OIL
M7
OIL
OIL
OIL
MM5
MM5
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL
OIL

• M7
M7

OIL
M7
M7
OIL
o>
CL
>»
-o
0
o
3
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0
0
0
0/SM
0/SM
0/SM
OF
0/SM
0
0
0
0
0/SM
0
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
0/SM
SM
OF
OF
SM
OF
OF
OF
0/SM
% Moisture ||
23
23
23
23
23
23
23
23
23
23
23
23
10
10
18
23
23
23
17
23
18
16
10
10
23
13
23
3
23
23
23
23
23
23
23
23
16
21
19
16
19
16
19
23

HJx-»
OH i-
-C
s. en
3-*
CQ- —
.8
.8
.8
.8
.8
.8
.8
.8
.9
.9
.9
.9
2.0
2.0
2.0
2.0
2.0
2.0
2.1
2.1
2.2
2.2
2.2
2.2
2.3
2.3
2.3
2.3
2.3
2.3
2.3
2.3
2.4
2.4
2.4
2.4
2.4
2.4
2.5
2.5
2.5
2.6
2.6
2.6
Q.
O)
1—

-*
-^
cn
a.
7.60
10.70
9.90
5.30
10.10
10.70
10.50
7.90
4.70
14.00
25.20
7.60
2.20
6.40
6.40
8.50
9.80
8.50
38.00
7.30
3.20
1 .60
80.80
97.30
4.30
4.20
10.30
15.00
10.60
5. 10
5.80
2.50
3.90
2.90
4.00
3.40

22.00
1 .40

0.50
21 .40
22.00
3.70
•~^ CO
^^ ai s-~- .*
cn -* cn --s.
.*: ^ j£ cn
•^ cn -^ E
cn — • cr —
*~* X *"* S
O O 0 O
0 2 OC Q.












6 2.00 0. 1
50 0.88 0.2
106



120 10.7

158

102 0. 13 1 .9
98 0.10 1 .6












184 43.0
190 13.8
21 61.3
129 30.0
21 61 .3

110 8.0


-------
Table 3-3.  Continued
>,
•o cu
3 -a
-M 0
CO CJ
DG-82-17
BS-81-45
DG-82-2
DG-82-13
DG-82-15
BS-81-28
BS-81-37
BS-81-53
OM2-84-17
OM2-84-21
TVA-83-1 1
TVA-83-12
BE-81-5
BS-81-49
BS-81-61
BE-81-1
DG-82-5
DG-82-12
BE-81-8
DG-82-11
BS-81-17
BS-81-40
BS-81-43
BS-81-60
OM1-83-1
OM1-83-3
OM1-83-4
BE-81-8
BS-81-34
OM1-83-2
DG-82-7
0-81-13
CCRL-81-3
DG-82-16
DG-82-9
0-81-9
CCRL-81-7
RTI-83-2
CCRL-81-8
0-81-1 1
OM2-84-41
OM2-84-37
CCRL-81-9
0-81-7
0-81-8
DG-82-8
RTI-83-1
0-81-3
DG-82-3
OG-82-19
0-81-4
CU
Q.
>>
cu
>
o
•M
CO
0
NB
NB
0
CAT
NB
NB
NB
NB
NB
CAT
CAT
NB
NB
NB
NB
NB
0
NB
CAT-RET
NB
NB
NB
NB
NB
CAT-RET
CAT-RET
NB
NB
NB
NB
NB/0
B
0
NB
NB/0
NB
NB
NB
NB/0
NB
NB
B
B
B
NB
NB
B
NB
CER
B
•o
o
.c
4->
CU
4->
in
cu
I—
M7
OIL
M7
M7
M7
OIL
OIL
OIL
M7
OIL
MM5
MM5
OIL
OIL
OIL
DIL
M7
M7
DIL
M7
DIL
DIL
DIL
DIL
M7
M7
M7
DIL
DIL
M7
M7
M7

M7
M7
M7

MM 5

M7
DIL
M7

M7
M7
M7
MM5
M7
M7
M7
M7
cu
Q.
>>
•o
0
o
•3
DF
0/SM
DF
DF
DF
0/SM
0/SM
0/SM
DF
DF
0
0
0
0/SM
0/SM
0
DF
DF
H
DF
0/SM
0/SM
0/SM
0/SM
DF
DF
DF
H
0/SM
DF
DF
DF
SM
DF
DF
DF
SM
0
SM
DF
DF
DF
SM
DF
DF
DF
0
OF
DF
DF
DF
cu
s_
3
•(->
in
O

••-o
|j^ x,^.
255
150
283
289
435
203
174
139





196
144

298
301

315
21 1
203
202
196




194

322
404

331
315
379

537

159





243
515

346
646

Q.
cu
CU
oo"
•MD
CO*—
1 10
205
158
122
162
198
238

221
221



256
224

148
129

178
209
297
258
210
123
135
134

267
128
189
232
150
191
183
254
223
248
139
257
303
303
1 17
177
157
146
286
129
172
318
127
cu
CD
10
4->
CO
C
i.
3 '
co
A
D
A
A
A
D
0
D
A
A
A
A
A
D
D
A
A
A
A
A
D
D
D
D
A
A
A
A
D
A
A
A
B
A
A
A
B
C
B
A
A
A
8
A
A
B
C
A
A
A
A
cu
I—
cu
Q.
ITS
CO
175
300
250
270
150
300
300
300
165
165


60
300
300
61
208
255
56
223
300
300
300
300



45
300

198


120
189





85
85



155


181
99

CD
_i^
^.
CD
Q-
30.00
3.70
54.00
35.00
23.00
2.10
3.10
4.00
7.2.0
3.20
2.60
1 .40
2.60
2.10
3.60
3.90
62.00
38.00
2.10
17.00
3.20
1 .90
2.40
1 .10
14.20
8.00
6.00
2.40
2.20
15.50
19.00
23.30

14.00
22.00
23.90

0.80

9.60
13.20
10.20

31 .00
20.00
24.00
0.50
18.80
34.00
2.00
10.00
-— •* CD
01 -*
-*: ^
•^ CD
CD — •
X
O 0
cj z
150

189
160
50



1 18
118
23 0.81
6 0.76
67


106
220
200

90







98


160

108
80
1 10

1 16
44 0.82
153

1 15
1 15
169


190
29 0.69

160
50

CD
^.
O->
O
32
5.8

16.9
9.3
7.3



62.6
62.6
0. 1





12. 1
1 1 .8

6.2










8.8

25.0
3.9
6.6

27.0
6.5
36.0

71 .3
71 .3
40.0


11.1
,4.9

10.5
0.6

CD
-i£
O>
E.
S.
O
0.







































/












-------
Table 3-3.   Concluded

T3 il)
3 -a
+-> O
GO O
TVA-83-3
TVA-83-4
M1-80-5
81-81-13
M1-80-1
M1-80-6
M2-81-1
M1-80-3
DG-82-6
M1-80-7
M2-81-2
81-81-14
DG-82-18
M1-80-4
M1-80-8
M1-80-1
TVA-83-5
TVA-83-6
DG-82-4
81-81-15
81-81-19
0-81-2
81-81-18
81-81-16
81-81-17
0-81-1
Hi
CL
1—
OJ
o
•M
GO
NB
NB
NB
NB
B
NB
NB
B
NB
NB
NB
NB
CER
B
NB
B
NB
NB
NB
NB
0
0
0
NB
NB
0
o
+->
z
O)
(—
MM5
MM5
MM5
MM5
MM5
MM5
MM5
MM5
M7
MM5
MM5
MM5
M7
MM5
MM5
MM5
MM5
MM5
M7
MM5
MM5
M7
MM5
MM5
MM5
M7
o>
Q.
I—
T3
0
O
3
0
0
0
0
0
0
0
p
OF
P
0
0
OF
P
P
0
0
0
OF
0
0
DF
0
0
0
OF
Moisture

a*
10
10
5

28
28
5
28
19
5
5

16
5
28
5
10
10
12


33



32
OJ CL
(O -*~ *» QJ
oe s_ H-
C *•*•*. Q) *— -
s. en i. o
3 -^ -i-O
CO *— •* ' ' *~ -"
5^8
5.8
6.0
6.5
6.6
6.6
6.8
7.2
7.2 314
7.2
7.4
7.5
7.7 826
7.8
7.8
8.4
8.5
8.5
9.2 357
9.5
9.9
10.5
10.9
12.3
14.4
16.4
Q.
0)

O
:r
0.8
0.2

34.0




9.2


32.0
0.4



0. 1
0. 1
11.9
34.0
2.0

5.0
42.0
33.0

en
en
2;
o
Q.


0. 19








0.01


0.32
0.21






0.01



      3-14

-------
              400  J
          OT
               300
CO

 I
tn
          CD
          o
          o
               200
               100  -4
                           •
                         ..
1     \     I     T

 1234
T

 6
T

 7
                                                             8
T^


 9
10
                                                   Burn Rate (kg/hr)
11
12
13
14
15
16
                                             Figure 3-1.   CO vs. burn rate.

-------
CO
                  5 -
                  4 -
                  3 _
           i~  -O

           CD  (/)
           0  JZ
           0  -!->
                  1 -
                                3    4    5     6
7    8    9    10    11    12   13    14    15   16    17
  Burn Rate  (kg/hr)
                                        Figure  3-2.   CO (g/hr)  vs.  burn rate  (.kg/hr).

-------
     A possible explanation for the CO results could be the size of the
wood being burned.  Since wood is loaded into fireplaces and woodstoves
by the log, it is intuitive that, regardless of burn rate, CO would be
produced in the inner portion of the log, while combustion occurred at
the outer portion.  This should hold somewhat true for HC emissions
also.  Almost all tests studied showed a fairly high CO value (1 to
4 percent), indicative of poor air mixing during the combustion process.
Stoves equipped with oxidation catalysts did reduce the CO emissions
approximately 40 percent on the average.  Ceramic stoves were tested and
ranked by burn rate and had the lowest CO emissions.
3.1.3  Catalytic Analysis
     The results obtained on catalytic stoves were extracted from the
data bank ranked by burn rate (Table 3-4).   The only general conclusions
which can be drawn are that the CO and particulate emissions averaged
the same or lower than the noncatalytic average, while HC emissions
average about the same.  The high HC average comes primarily from
one series of OMNI runs,  which may have been a result of differences in
measurement methods.   The OMNI results were measured on a NDIR instrument
whereas TVA used a GC/FID which measures only the low molecular weight
(Ci-C?) hydrocarbons.   Another possibility is that, in the OMNI tests,
temperature of the gases was too low to achieve catalytic action.  It is
unclear from the test reports if this condition was achieved since the
majority of investigators failed to report the operating temperature of
the catalyst.   Light-off temperature is about 400°F (205°C).  In general,
the removal efficiency of CO, HC, and particulate increases with an
increase in temperature of the gases entering the catalyst.
3.1.4  Particulate and HC Results
     The emissions from a woodstove contain flyash, condensed organics
either adsorbed on the flyash or as liquid droplets,  semi-volatile
(boiling point >100°C) organics, and volatile (boiling point <100°C)
organics.   The method of testing and the care taken during the test can
have a strong effect on whether a species is reported as a particulate
or hydrocarbon.   In viewing the data it was noted that very few tests
had both high particulate and high hydrocarbon values.   In most cases
those tests which had high particulate values had low HC results and
                                 3-17

-------
Table 3-4.  WOODSTOVE DATA (CATALYTIC STOVES)

"O Ol
3 T3
+-> o
00 O
TVA-83-13
TVA-83-14
OM2-84-25
OM2-84-29
OM2-84-22
OM2-84-26
OM2-84-32
OM2-84-31
OM2-84-30
TVA-83-7
TVA-83-8
OM2-84-23
OM2-84-27
OM2-84-33
OM2-84-24
OM2-84-28
0-81-6
TVA-83-10
TVA-83-9
DG-82-14
0-81-5
DG-82-10
DG-82-15
TVA-83-11
TVA-83-12
OG-82-11
OM1-83-3
OM1-83-4

01
SL
t—
01
o
CAT-RET
CAT/B
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT
CAT-RET
CAT
CAT
CAT
CAT-RET
CAT-RET
CAT-RET

T3
O
-C
Ol
01
1—
MM5
MM5
M7
OIL
M7
OIL
M7
M7
M7
MM5
MM5
M7
OIL
M7
M7
OIL
M7
MM5
Mf-15
M7
117
M7
M7
MM5
MM5
M7
M7
M7

O)
Q.
•o
O
0
3
0
0
OF
OF
OF
OF
OF
OF
OF
0
0
OF
OF
OF
OF
OF
OF
0
0
OF
OF
OF
OF
0
0
OF
OF
OF

% Moisture
1
10
10
19
19
19
19
18
18
18
to
10
19
19
19
17
17
18
10
10
17
16
19
20
10
10
19
16
16

s-
^^ ^™^
en o
Ol Q-
4J E
ra 01
C Ol
S- S-
3 -r-
CQ U_


0.6
0.6
0.8
0.8
0.8
.0
.2
.3
.3
.4
1.4
1.5
1.6
1.6
1.8
2.0
2.0
2.1 320
2.6
2.6 317
2.8 435
2.9
2.9
3.2 315
3.4
3.4

o
o
Q.
Ol
1—
Ol
o
00


54
54
73
73
58
61
74


104
104
98
111
111
125


118
155
143
162


178
135
134

01
en
(O
oo
c
3
CO
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A

Ol
•r"
t—
Ol
Q.

-------
vice versa.  As noted previously, the tests with high HC results used an
NDIR which includes all species in the absorbtive range.  This would
include methane which could account for as much as 50 percent of the
total HC value.  The particulate value is also uncertain since this
measurement is dependent upon filter temperature, particle size, and
pre-conditioning; variables which were not documented in the references.
With all these undefined variables, it is difficult to draw conclusions
from the testing done on an overall basis.  Conclusions are probably
more valid within each test as some of these variables are controlled.
3.1.5  NO  Analysis
       ^^^x\
     Only 25 of the 217 tests reported NO  values which ranged from
.03 to 2.0 gr/kg of wood fired, with an average value of .75 gr/kg.  The
higher values were all associated with tests done on catalytic stoves,
while the lower values were associated mainly with non-catalytic stoves.
While this is a significant trend, the level of NO  emissions from
woodstoves is lower than for other residential heating equipment.
3.2  INDIVIDUAL STUDY ANALYSIS
     As noted above, looking for trends in the whole data bank is clouded
by the wide, often undocumented, variations in the test procedures.
Analyzing the trends in a single study might prove to be more fruitful
since many of these variables were controlled within individual studies
by the investigator.
     The reported particulate emission factors for RWC range from 0.5 g/kg
to as high as 62 g/kg of wood.   Several studies have reported typical
factors ranging from 0.5-25.0 g/kg.  Table 3-5 illustrates particulate
emission ranges reported in four different studies.
     Carbon monoxide emission factors measured from RWC range from 4 to
400 g/kg of wood.  In general,  emission factors for stoves and other
air-tight appliances have been in the 100 to 200 g/kg range.   Fireplaces
have demonstrated lower CO emissions (15 to 30 g/kg range).     Table 3-6
illustrates carbon monoxide emission ranges reported in four different
studies.
     The reported HC emission factors range from 2 to 113 g/kg.  In the
majority of the tests, HC emission factors have been in the 20-60 g/kg
range.   Table 3-7 illustrates HC emission factor ranges reported in
three different studies.
                                 3-19

-------
 Table 3-5.  PARTICULATE EMISSION FACTORS

Study
Butcher and Buckley
Butcher and Sorenson
Monsanto
Argonne
Emission factor
range (g/kg)
0.7 -
1.3 -
5.1 -
0.8 -
25
24
19
22
Reference
9
10
11
12
Table 3-6.   CARBON MONOXIDE EMISSIONS FROM
        RESIDENTIAL WOOD COMBUSTION

Study
Argonne Lab
Monsanto
Battell e
California Air
Emission factor
range (g/kg)
92 - 196
15 - 370
33 - 400
4 - 147
Reference
12
11
13
14
                  3-20

-------
   Table 3-7.  TOTAL HYDROCARBON EMISSIONS FROM
            RESIDENTIAL WOOD COMBUSTION

Study
Battell e
Canadian Combustion
Research Laboratory
Acurex
Emission factor
range (g/kg)
2.0 - 113
20.4 - 43.4
2.0 - 110
Reference
13
15
16
Table 3-8.  POLYCYCLIC ORGANIC MATTER EMISSIONS FROM
            RESIDENTIAL WOOD COMBUSTION

Study
Argonne
Monsanto
Battell e
Emission factor
range (g/Kg)
.004 - .040
.025 - .370
.011 - .050
Reference
12
11
16
                      3-21

-------
     When airtight combustion units are operated under oxygen starved
conditions low combustion efficiencies result.  Incomplete combustion
results in the formation of a complex mixture of products.  These
combustion products, a mixture of hydrocarbons, olefinic and polycyclic
organic matter, condense as the stack emissions cool.  In general, the
term POM is used to describe all multi-ring organic compounds.  ROMs are
of special concern in wood smoke since several of these compounds have
been identified as potential carcinogens.   A well studied example is
Benzo(a) pyrene (BaP).
     Because of their high melting points the bulk of POM is believed to
be linked with particulate matter.    It is uncertain whether POM
condenses out as discrete particles after cooling or condenses on surfaces
of existing particles after formation during combustion.   It is clear,
however, that POM tends to concentrate on the particle surfaces.  It has
been demonstrated that most of the mass of POM is associated with
particles of aerodynamic diameters in the respirable size range.    It
is estimated that RWC accounts for as much as 80 percent of the national
                                      18
POM emissions from stationary sources.
     Similar to other emission factors developed for RWC, factors reported
for POM range over several orders of magnitude.  Examples of POM emission
factors developed in three studies are shown in Table 3-8.  An overall
range of 0.004-0.37 g/kg of wood is reported.
3.3  VARIABLES AFFECTING EMISSIONS
     Several factors can significantly affect the emissions from wood
burning appliances.  In general, these factors can be grouped into one
of three categories.  These are:  1) equipment type, 2) operating
conditions, and 3) fuel characteristics.   Each of these categories and
their role in affecting emissions will be discussed briefly.
3.3.1  Equipment Type
     Several studies have demonstrated different emission rates for
different combustion appliances.  Initially, these studies compared
emissions measured from fireplaces to those measured from stoves.
One of the first such studies was conducted by Monsanto.     The Monsanto
study compared emissions from a fireplace, a baffled stove and a
                                 3-22

-------
nonbaffled stove.  The results of this study have been included in
Table 3-9.  In summary, Monsanto demonstrated that the air-tight stoves
have significantly higher emission rates for CO and POM, while NO
                                                                 A
emissions were greater from fireplaces.
     More recently, studies have been conducted which compare emission
performance of conventional air tight wood heaters with performance of
                        19 20
advanced design heaters.   '    TVA has conducted such studies using
carbon monoxide, particulate, and polycyclic aromatic hydrocarbon (PAH)
measurements from various stove types to assess emission performance.
                                                          20
Figure 3-3 summarizes the results of one comparison study.    In general,
TVA found that the advanced design sytems tested generated much lower
emission factors.  The catalytic wood heater (#2) gave the lowest CO and
PAH emission factors.  The retrofit catalytic system (#3) tested on the
conventional wood heater and the catalytic wood heater with a metal
combustor (#4) had lower PAHs, total particulates, and volatile hydro-
carbons than the conventional wood heater.  Although emissions for the
prototype secondary combustion wood heater (#5) were far reduced in
comparison to the conventional wood heater, TVA noted that this system
required frequent operator attention to sustain such reduced emissions.
Referring back to the TVA-83 test series in Table 3-1, it can be seen
that the conventional wood heater (tests 1-6) had emissions that increased
dramatically with decreased burn rate.  Generally, emissions from the
catalytic wood heater (tests 7-12) showed less dependence upon wood load
size than the conventional wood heater.
3.3.2  Operating Conditions that Affect Emissions
     Several stove operating conditions have been identified as affecting
emission rates.   Three of these variables will be briefly discussed.
These are:  1) burn rate, 2) stage of the burn cycle, and 3) charge
loading.
     3.3.2.1  Burn Rate.   Several investigators have looked at the
effect of burn rate on emission performance.   In general, these studies
have demonstrated that an increased burn rate will result in various
emission reductions.   These reductions include:
                                 3-23

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   Table 3-9.  SUMMARY OF EMISSION RESULTS FOR CRITERIA POLLUTANTS AND ROMs
               FROM WOOD FIRED RESIDENTIAL COMBUSTION EQUIPMENT3

Wood
burning
device
Fireplace
Baffled
stove
Nonbaffled
stove
Burn
rate
kg/hr
10.8
8.4
7.8
Parti cul ate
matter
g/kg
2.3
3.0
2.5
Condensible
organics
g/kg
6.3
4.0
6.0
N0xd CO6 POMf
2.4 30 0.025
0.4 110 0.21
0.4 370 0.19
Source:   DeAngelis, et al.
^ood type - seasoned oak.
 Front half of EPA Method 5 and POM train.  Averaged when two values
 are available.
 Back half of EPA Method 5.  Averaged when two values are available.
 EPA Method 7.   Average of six grab samples.
eEPA Method 3 (Orsat) for stoves; average of 10 samples.  Drager tube for
 fireplace; 15-30 minute composite.
fPOM train (EPA Method 5 modified with XAD resin trap).
                                    3-24

-------
                                                      SL

                                       Hood Heater tl - Airtight circulator
                                       Hood Heater 42 - Ceramic honeycomb catalytic
                                       Hood Heater #3 - Hetro ceramic honeycomb catalytic-
                                       Hood Heater *4 - Metal catalytic
                                       Hood Heater 15 - Secondary combustion
                    2343

                     (Hood  Heater)

                   TOTAL PARTICULATES
                                            S
                 12343                      12345
                   (Hood Heater)                            (Wood Heater)

                  CARBON HONOXIBE                           PAH EMISSIONS

Footnotes:   a.  Fuel sample was red oak, split cordwood,  10.41 moisture (wet).
            b.  Hood heater *1 data was taken from 8 samples at low, medium, and high
                burn rates.
            c.  Wood heater 12 and 03 data was taken from 6 samples at low, medium, and
                high burn rates.
            d.  Wood heater 14 data was taken from 2 samples at a medium burn.rate.
            e.  Wood heater 05 data was taken from 2 samples at medium and high burn rates.
    Figure 3-3.    Comparison of emissions  from  several  wood heaters.
                     (Reproduced with permission of  APCA.)
                                                                                   20

-------
     1)   participate,21'22
                               22
     2)   condensible organics,
                          19 23
     3)   carbon monoxide,  '
     4)   total hydrocarbons,19'23
                              12
     5)   aliphatic compounds,   and
                         12
     6)   total organics.
These burn rate emission reduction relationships are illustrated in
Figures 3-4 through 3-8.
     The effect that burn rate has on POM emissions is less certain.
       23
Studies   conducted at the Canadian Combustion Research Laboratory
indicate a decrease in POM emissions with increasing burn rates
                                         12
(Figure 3-9).   On the other hand, studies   conducted at the Argonne
National Laboratory (ANL) strongly suggest that POM emissions increase
with increasing burn rates.   ANL's suggestions are supported by the
apparent shift to higher molecular weight organics observed when the
burn rate is increased.
     Peters   suggests that high temperature combustion favors POM
formation from the alkyl benzene fragments pyrolyzed during wood
combustion.  He makes the following statement concerning burn rate and
POM emission rate:  "The very  limited data on POM emissions from
residential wood-fired equipment and deductive reasoning suggest that,
within the operating temperature range of residential equipment, the
burning rate - POM emission rate relationship is exactly opposite that
of other pollutants.  Because  temperatures of 500-800°C are needed for
POM formation, a very cool fire similar to overnight use conditions
should, at some point, result  in zero POM emissions, although large
amounts of other unburned organics and CO will be emitted."
     3.3.2.2  Stage of the Burn Cycle.   Several investigators have
determined that emission rates for various pollutants are dependent upon
the stage of the burn cycle.   DeAngelis, et al. observed this dependency
when monitoring CO over an entire burn cycle.    Figure 3-10 illustrates
the carbon monoxide concentration in the flue gas as a function of time.
It has also been reported that particulate emission rates are dependent
upon the stage of the burn.   '    These studies have shown that
approximately one-half of the  mass of particulates are emitted in the
first 17 percent of the burn.

                                 3-26

-------
   100

    90

    to

    70

    "
40
    20

    io 4
     o
I
I
                                A  Oak Brand* 2" * *", 11.71
                                •  Sad 
-------
    100


I  w


1  M ^


8  TO
•

I  60
a   *« «


    30


    20 .


    10


     0
A Oak Brand* V x 4", 11.72 Bolatara

• Sad Oak Cardvood, 122 Mia Cera
                            10        15

                                ttb/br)
                                 6
                                
-------
    400,
    300
 jt
 ~^.
 CO

  -  200
 bl
 Q
    100
                2         4         6


                FIRING RATE, kg/hr
10
Figure 3-6.   Variation of carbon monoxide with  firing  rate,

                                 23
             conventional stoves.

             (Reproduced with permission of APCA.)
                          3-29

-------
  100
u
a
•
•


1
   80
   60
   40.
2

"2.  20 J
                   10     13     20     25

                       Burning Sate, Ib/hr
30
35
  Figure 3-7.   HC emissions for several  stoves  as  a

                                     19
               function of burn rate.

               (Reproduced with permission of the

               Oregon Graduate Center.)
                        3-30

-------
              *
              e
                    O Pkrtteutete * Cbndmfbto . Urtt Wood

                    X PvttcutaU * Candnalbl* . Small Wood


                    £ PmrHcutol* + Candralbh * CrwawU . Urf* Wood


                    V PwllciiJato * CoodMHifal* » Crmote . Small Wood
                          246

                           Burn  Rate, kg/hr
Figure 3-8.   Summary of  total organic  emission factors (g/kg)

              as a function of burn  rate (kg/hr) from combustion

                                                      12
              of 0.12M  and 0.06M diameter oak logs.

              (Reproduced with permission of the Oregon

              Graduate Center.)
                             3-31

-------
  10
  c
  o
 O
 Q.
  Nl
 •^«


  10
    1 +
                2         4          6


                    Firing Rate,  kg/hr
10
Figure 3-9.   Variation  in  POM  emissions with firing rate,
                                 23
             conventional  stoves.

             (Reproduced with permission of APCA.)
                         3-32

-------
      0   5   10  15  20  25  30  35  40  45  50  55  60  65  70  75
                     TIME INTO BURNING CYCLE, min
Figure  3-10.  Concentration of CO in flue  gas as a function  of time.
                                                                11
                              3-33

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                                            19
     3.3.2.3  Charge Loading.  Cooke, et al.   concluded from their
emission studies that the amount of wood loaded into the stove will have
a large influence on the amount of pyrolysis products leaving the stove.
The emissions increase with the increase in wood inventory due to the
increased quantity of wood exposed to the heat and thereby subject to
preburning pyrolysis.  As seen from these data (Table 3-10), both the HC
and CO emissions increased when the charge mass increased.
3.3.3  Fuel Characteristics
     The combustion properties of wood are influenced by several fuel
characteristics.  As a result the types and magnitudes of emissions
generated by wood combustion are also governed by these characteristics.
It has been reported that wood type, moisture content, size and shape of
the fuel may all affect emissions.   Each of these factors and their
influence on emission performance will be briefly discussed.
     3.3.3.1  Wood Type.  To date,  one of the most comprehensive studies
that specifically investigates the relationship between emissions and
wood type was conducted by Muhlbaier.   This study reported particulate
emission rates from a free standing fireplace for seven different wood
types.  In addition to particulate emissions, gaseous emissions were
measured during combustion of select woods.   No significant trends are
available in the data.   A summary of these results is presented in
Table 3-11.
     3.3.3.2  Moisture Content.   Considering the error factors involved
with emission testing,  many investigators have concluded that fuel
moisture has little or no significant effect on emissions.   Some have
added that dry wood (less than 25 percent moisture) may produce slightly
higher emissions than wood with more typical moisture contents of
              24
30-40 percent.    In contrast, Del  Green Associates concluded that fuel
                                             05
moisture does significantly affect emissions.    Figure 3-11 illustrates
measured particulate emission rates for various fuel moisture contents.
This figure illustrates that the low moisture fuel resulted in signifi-
cantly higher emission levels than the medium moisture fuel.  The high
moisture fuel also resulted in higher particulate emissions, but the
increase was not as great as with the dry fuel.
                                 3-34

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         Table 3-10.   EFFECTS OF SIZE OF CHARGE  ON  EMISSIONS,
                   SIDE DRAFT BURNING OF OAK 4x4s19

Test run number
Mass of charge, 1b
Burning rate, Ib/hr
Excess air, percent
Stack temperature, °F
(°C)
Gas composition, as measured
CO, percent
HC , ppm
Emissions, lb/1,000 Ib wood
CO
HC
34
12.9
17.4
62.9
680
(360)

1.2
2800

100
15
35
41.9
19.2
58.1
660
(350)

2.5
5300

220
26
(Reproduced with permission of the Oregon Graduate Center.)
                              3-35

-------
    Table 3-11.   PARTICULATE EMISSION RATES FROM WOOD BURNING (g/kg)c

Teat
Softwood
25
26
27
32
33
31
34
36
40
Hardwood
23
24
35
42
43
20
21
19
22
28
29
30
37
38
39
Synthetic
41
44

Wood

Eastern Sprue*




Jack lae




Soft Maple
•
*
Birch
N
Hard Maple
•
White Aah
•
Red Oak





Logs
Sternolog
Northland II

Front Catch

6.0 (47)*
2.9 (30)
1.8 (12)
-
-
—
1.7 (17)
4.0 (28)
4.2 (40)

2.6 (11)
1.9 (21)
2.2 (23)
5.9 (40)
2.2 (23)
1.2 (12)
4.2 (38)
1.5 (11)
1.1 (12)
3.4 (43)
2.5 (30)
2.8 (24)
2.6 (29)
2.2 (20)
3.3 (11)

1-5 (8)
2.3 (11)

Filter Catch

2.1 (17)
1.2 (13)
1.9 (13)
1.4
1.6
3.7
1.7 (17)
7.6 (53)
2.9 (28)

3.9 (17)
1.4 (16)
1.6 (17)
4.2 (29)
1.7 (18)
1.2 (12)
1.9 (17)
1.0 (7.4)
1.5 (16)
2.0 (25)
3.4 (41)
6.2 (53)
1.2 (13)
1.8 (17)
3.6 (12)

8.4 (45)
14 (71)

lapioger Catch

4.6 (36)
5.5 (57)
11 (75)
-
-
•
6.7 (66)
2.6 (18)
3.3 (32)

17 (72)
5.7 (63)
5.8 (60)
4.5 (31)
5.7 (59)
7.9 (77)
5.1 (46)
11 (81)
6.5 (71)
2.6 (33)
2.3 (28)
2.8 (24)
5.1 (57)
6.9 (63)
22 (76)

8.8 (47)
3.6 (18)

Total

13
9.6
15



10
14
10

24
9.0
9.6
15
9.6
10
11
14
9.1
8.0
8.2
12
8.9
11
29

19
20
*Numbers in  the  (  ) are the percent of the total.
 (Reproduced with permission of the Oregon Graduate Center.)
                                3-36

-------
o
^
Ol
   70
   60
   SO
   40
«  30
   20-
   10
                            •  gAg
                            •  gAg, average
                            a  g/104 Btu
                            •  g/104 Btu, average
      (wet)    10
      (Dry)    11
20        30         40         SO         60
25        43         67        100        150
    Fuel Moisture,  X
   Figure 3-11.   Participate emissions (normalized  to burn  rate) as
                                                  25
                   a function of fuel  moisture.
                                  3^37

-------
     3.3.3.3  Fuel Size.  The log size/emission relationship has been
studied by several investigators.  The size of the pieces of wood has a
large effect on the rate of pyrolysis.  The smaller pieces result in a
shorter distance for the pyrolysis products to diffuse, a larger surface
area to mass ratio, and a reduction in the time required to heat the
entire piece of wood.
     Investigators have shown that as the ratio of surface area to mass
increased (i.e., smaller log sizes) the emission factors are markedly
                         19
increased.  Cooke, et al.   demonstrated this with CO emissions
                           24
(Figure 3-12) while Barnett   demonstrated the same relationship with
                                   12
particulates (Figure 3-13).  Hubble   concluded that total organics do
not exhibit a log-size effect but the forms of the organics (particulate
matter, creosotes, and condensibles) do exhibit such an effect
(Figure 3-8).

-------
    140.
    120 ,
   100 ,
Ji  80 4
5
 •

 •  60

s
8  40 .


    20
                LEGEKD
          O • Oak, Round
             2- Oak. Split
             • Oak, 4x4
          O ~ Oak Kindling
             • Fir Brands
            10  20    30    40    50   60    70   80
              Surface Area Wood/Volume Wood,  ft2/ft3
                                      90  100
Figure 3-12.
Effect of wood  size  on CO emission factors.
(Reproduced with permission of the Oregon
Graduate Center.)
                                                           19
                           3-39

-------
                 ^\  INCH LOGS
                 VARYING OPERATING
                 ON CONDENSABLE
                E EMISSIONS OF THE
                DCONVECTIVE  HEATER
             10  •
            a
            o
            ta.
            O
            O
            Z
            O
            5:
            C/J
en

5
6
i—i
H
OS
              8  •
                   DRY WOOD
                         M)
   6 -
              2  '
                  EFFECT
                  CONDITION!
                  PARTICULAR
                  THIN-WALLI
                               XTRA LARGE
                               WOOD LOAD
                                 STANDARD RUNS
                                                20
                                       tu
                                       O
13 §
   *

   z
                                                10
                                                   u
                                                   l-t
                                                   H

                                                5  I
               200
              300°F     400C
          STOVE TEMPERATURE
Figure 3-13.
  (The effect of varying operating conditions, on
  condensible participate emissions of the thin-
  walled convective heater.)  Compare standard runs
  (small dots) with emission factors (large dots)
  produced by varying wood size and moisture.   Note
  extreme effects caused by burning 1 inch logs.
  Dots represent sample means and vertical bars
                                         24
  represent 97 percent confidence limits.
  (Reproduced with permission of the Oregon
  Graduate Center.)
                3-40

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           4.  AIR SHED STUDIES AND IMPACT ASSESSMENT METHODS

     Several air shed studies have indicated that RWC is a major air
pollution source in regard to the current total suspended particulate (TSP)
          234
standards. ' '   Additional concern is warranted due to the respirable
nature of the particulate.  Muhlbaier has reported RWC particulate to
have a mass median diameter of 0.17 pm.    Other studies have measured
similar sizes and have generally concluded that the majority of partic-
                                           7 8
ulate emitted from RWC is less than 2.5 |jm.  '    Based on these studies,
if an inhalable particulate standard was implemented, RWC would be a
much greater contributor to nonattainment than under the current TSP
regulations.
     During studies conducted in 1978 on the Denver "Brown Cloud," it
was noted that wood burning sources contributed 12 percent of the fine
particulate mass (<2.5um) and 18 percent of the visual range reduction
                          pc
(0.1-1.0 urn) in that city.    These estimates  were based on the high
potassium to iron ratio noted for wood smoke that did not appear for
other sources.   Other studies have shown up to 84 percent of the fine
particulate fraction to be attributed to RWC.    All studies predict an
increase in this percentage as other sources are controlled and wood use
increases.  Table 4-1 displays six ambient air surveys, their measurement
techniques, and the constituents measured.
     The assessment of these reports was based upon:
     (1)  Size of the community and the ability to obtain a good
          indication of wood usage from home surveys.  Example, the home
          survey was not obtained for Denver "Brown Cloud."  However, a
          detailed survey was obtained for Waterbury, Vermont along with
          actual testing of 14 woodstoves.
     (2)  The placement of ambient air monitors.   Good upwind and downwind
          monitors are needed to account for ambient background concen-
          trations.   These are easy to obtain  for wood smoke as very few
          sources are greater than 15 meters high at the point of emission.
          The sampling and/or monitoring intervals are critical.

                                   4-1

-------
          Table 4-1.  AIR SHED STUDIES AND IMPACT ASSESSMENT METHODS
                                     Glass  Backup                                            TSP
                   Upwind/  Teflon   fiber   trap  Other                            Stove    average
TSP  <2.5|jin  POM  downwind  filter  filter  XAD-2  filter  C14  CMB  K: Fe  Survey   test      ug/m3
oc
Colorado,
Denver "Brown
Cloud"
Colorado,
Telluride
29
New Hampshire,
Lyme Center
2
Alabama,
Petersville
Mi'ssouU4
3
Oregon,
Medford


XX X

X XX

X XX
X X X X
X X
XXX


XX X 89.6

X 61

X X 52
XX XX N/A
XX XX X 81
X X X X X X 100

-------
     (3)  The type of ambient monitor utilized.   Generally wood smoke is
          found in the 0.1-1.0 urn size range.   Analytical methodology
          can be improved by the use of a sampler which fractionates the
          size to less than 2.5 urn or "respirable" particulate matter.
                                                                     ff*
     (4)  The filtration method or collection substrate.   Both Teflon
          and glass fiber filters are utilized for these studies, but
          new data shows that some of the hydrocarbons are passing
          through the filter material.  This material, in the semi
          -volatile range, must be collected on an organic adsorbant
          such as XAD-2.

     The key to obtaining a credible ambient air survey of RWC emissions

appears to be the method utilized to correlate the ambient sample to the
source emission.  There are currently three main methods to separate the
total particulate catch to a fraction which is wood smoke.   They are
listed below with their comments.

     •    Particulate sizing on the Hi-Vol  Sampler.  Wood smoke is known
          to be 80 percent in the 0.1-1 urn size range, so fractionating
          this size eliminates other interferences but does not neces«7
          sarily preclude other condensibles or other fine particles.

     •    Chemical Mass Balance (CMB).  This method utilizes a detailed
          analysis of the filter samples to identify compounds or elements
          which are predominantly attributed to wood smoke emissions.
          Examples of these chemicals are the potassium to iron ratio,
          Levo glucosan and retene.

     •    Carbon14 identification.   This method utilizes the fact that
          all vegetative and vegetatively derived material  contains C14.
          A known fraction of atmospheric C02 contains the C14 isotope
          formed in the upper atmosphere by cosmic ray bombardment
          of C12.   Plants incorporate the C14 isotope through photo-
          syntheses.   When the plant dies,  incorporation of new C14
          stops; the existing C14 in the plant starts to decrease decaying
          to C12.   C14 half life is ^5,730 years.   Over the hundreds of
          millions of years since the vegetation died, which now appears
          as coal, oil, or natural  gas, virtually all of the C14 has
          decayed to C12.  The C12/C14 ratio in ambient particulate
          matter is a measure of the fraction contributed by wood
          combustion.   For best results, the analysis is performed on
          the <2.5 urn particulate fraction to separate the smaller
          combustion derived particles from the larger vegetative
          particles such as soil and bits of leaves entrained in wind
          blown dust.
                                 4-3

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                  5.  SAMPLING AND ANALYTICAL METHODS

     There has been considerable controversey surrounding the use of
sampling methods both for source evaluation and ambient monitoring of
woodstove emissions.  As noted earlier in the discussion of emissions,
very few people use the same method and little work has been done to
evaluate the accuracy and precision of each method.   A brief description
of each method is provided below.
5.1  SAMPLING, SOURCE
5.1.1  Semi-VOST (Modified Method 5) Sampling and Analysis Procedures for
       the Determination of Semi-Volatile Compounds from Combustion Sources
     Gaseous and particulate pollutants are withdrawn from an emission
source at an isokinetic sampling rate and are collected in a multicomponent
sampling train.  Principle components of the train include a high effi-
ciency glass or quartz fiber filter and a packed bed of porous polymeric
adsorbent resin.  The filter is used to collect organic laden particulate
materials, and the porous polymeric resin to adsorb semi-volatile organic
species.   Semi-volatile species are defined as compounds with boiling
points greater than 100°C.
     This method is currently being studied in an EPA/IERL project.   The
purpose of the project is to validate the semi-VOST procedures and
determine the Method Detection Limit, Method Accuracy and Precision, and
Interferences.
     A schematic of the sampling train used in this method is shown in
Figure 5-1.   This sampling train configuration is adapted from EPA
Method 5 procedures and as such, the majority of the equipment required
is identical to that used in EPA Method 5 determinations.   The new
components required are a condenser coil  and a sorbent module, which is
used to collect semi-volatile organic materials that pass through the
glass or quartz fiber filter in the gas phase.

                                 5-1

-------
                                             Filter Holder
                 "I*!  Stack Wall
     Thermocoupl* [J       p,^
-S-Type
  Pitot
                                                                                             Thermometer
                                              Check Valve
en
I
       < o-
       2.g
       0°
       o 3
      •o
                         Redrcutatlon Pump
Dry Gas Meter  Air-Tight

                Pump
                                                                                                                     Vacuum Line
                                      Figure  5-1.   Semi-VOST train  schematic diagram.

-------
5.1.2  Oregon Source Sampling Method 7
     Particulate matter including condensible vapors are withdrawn
isokinetically from a flowing gas stream.   The particulate matter is
determined gravimetrically after extraction with organic solvents and
evaporation.
     This method is applicable to stationary sources whose primary
emissions are condensible gases.   It should be considered a modification
of Source Sampling Method 5 as shown in Figure 5-2.
     The probe, sampling train, and metering system are the same as
outlined in Source Sampling Method 5 with the following exceptions:
     •    The heated filter and cyclone are optional, but should be used
          if significant quantities of solid particulate are present.
     •    An unheated glass fiber filter is placed between the third and
          fourth impingers.
                              2
5.1.3  The Source Signature (S ) Sampler (Dilution Sampler)
                                                                 2
     Figure 5-3 is a diagram of the principal components of the S
               2
sampler.  The S  sample train is made up of an isokinetic sampling
probe, a dilution system, the two parallel  filter trains, and the
necessary flow control  systems.  The raw wood smoke is sampled from the
stack at approximately 20 1pm and diluted to approximately 200 1pm with
clean air.   This dilution takes place in a dilution tube, 25 cm long and
2 cm in diameter.
     Equal  portions of the diluted aerosols are pumped through the two
filter trains.   The particles larger than 2.5 urn in aerodynamic diameter
are cut from the stream in cyclones.   The remaining fine particles are
                                    ®
collected simultaneously on a Teflon  and a quartz filter.   Both filters
                                                            ®
have a 1-um pore size and are 37 mm in diameter.   The Teflon  filter is
used in the X-ray analysis procedure.   The quartz filter is used in the
                                                 2
carbon analysis procedures.  In addition to the S  sampler, this method
requires measurement of the chimney or stack flow rate.  Measuring this
flow rate can be difficult, given the low velocity in natural draft
chimneys, but a standard "J" type Pi tot tube with an electronic manometer
sensitive to 0.001 mmHg provided suitable flow measurements in the
laboratory.
                                 5-3

-------
en
i
          CT30
          (D (D

           "
         *:s.
         ™"-
         "i
         o 3
                                                         (Optional)

                                                          filter
                                                                                filler  thesaomater
                           nozzle
                                                                                                 heck valve
                                   Figure 5-2.   State of Oregon Source Sampling Method  7.

-------
en

CJl
             20 Ipm
Pitot tube/-
-------
5.1.4  Dilution Sampler (Condar)
     Particulate emissions can be sampled by pumping a portion of the
flue gases through a filter.   Two versions are detailed in Figure 5-4.
The unit consists of a sampling pipe that is inserted into the stack
about two feet above the stove.  The sampling pipe has numerous small
holes that allow room air to dilute and condense the flue gases.   This
mixture then passes into the filter housing where the particulates are
collected on filter paper.  A vacuum motor is used to pump the flue
gases through the system.   This procedure samples 10 to 17 percent of
the total stack exhaust flow.
5.1.5  Source Assessment Sampling System (SASS)
     Particulate and semi-volatile organic materials are withdrawn from
a source at constant rate near isokinetic conditions and are collected
in a multi-component sampling train.
     Three heated cyclones and a heated high-efficiency glass or quartz
fiber filter remove and collect the particulate material from the sample,
and a packed bed of porous polymeric resin adsorbs the semi volatile
organic species.
     Chemical analyses of the sample are conducted to determine the
concentration and identity of the semi-volatile organic species and
gravimetric determinations are performed to approximate particulate
emissions.
     A schematic of the sampling train used in this method is given in
Figure 5-5.   This sampling train configuration is that of the Source
Assessment Sampling System (SASS) as supplied by Anderson Samplers,
Inc., Atlanta, Georgia.
5.1.6  EPA Method 5--Determination of Particulate Emissions from Stationary
       Sources with Condensate Collection Analysis for Gaseous Emissions
     Particulate matter and gaseous emissions are withdrawn isokinetically
from the source and collected on a glass fiber filter maintained at a
temperature in the range of 120 ± 14°C (248 ± 25°F) and in water collection
impingers.  The particulate mass, which includes any material that
condenses at or above the filtration temperature, is determined gravi-
metrically after removal of uncombined water.   The collected gaseous
emissions are analyzed by ether chloroform extracts of the impinger
solutions.
                                 5-6

-------
en
                                                                     6 in Dilution
                                                                     Chamber
                Dilution
                Air Inlet
                                                         i****5
                                                   <. <*** *
                Calibrated
                Manometer
                                          Figure 5-4. Condar Company sampling system.

-------
tn
I
oo
                                                CONVCaiON
                                                OVEN
 ISOLATION
BALL VALVE

   /   FILTER
                                                SORBENT
                                                CARTRIDGE
                                                                                         , GAS COOLER
                                                                                  GAS
                                                                                  TEMPERATURE
                                                                                  T.C.
                                                                  CONDENSATE
                                                                  COLLECTOR
                   DRY GAS METER/ORIFICE METER
                     CENTRALIZED TEMPERATURE
                      AND PRESSURE READOUT
                         CONTROL MODULE
               IMP/COOLER
               TRACE ELEMENT
               COLLECTOR
                                                             TWO iah3Anin VACUUM PUMPS
                                           Figure 5-5.   SASS schematic  diagram.

-------
     This method is applicable for the determination of particulate
emissions from stationary sources.  Chemical analyses of the condensate
sample are conducted to determine the concentration and identity of
hydrocarbon emissions.
     A schematic of the sampling train used in this method is shown in
Figure 5-6.  Complete construction details are given in APTD-0581
(Citation 2 in Section 7).
5.1.7  Cryogenic Trapping
     Cryogenic trapping is routinely used to concentrate organics in air
samples for injection into gas chromatographs.  This preconcentration
affords detection limits in the sub-parts-per-billion range with adequate
reproducibility.  Cryogenic traps are usually constructed of capillary-
bore chromatographic grade stainless steel tubing formed into a loop.
The loop is immersed in a cryogenic bath for trapping.   Liquid nitrogen
is most often used as the cryogenic fluid (boiling point - 195°C).
Typically, an evacuated reservoir of precisely known volume is used to
pull sample gas through the cryogenic trap.  The volume of the gas
sample is calculated from the pressure change in this reservoir.  The
concentrated organic sample is released into the GC by removal of the
capillary tube from the cryogenic bath followed by heating.  Figure 5-7
presents an example of a typical thermal desorption device with cryogenic
trapping.
5.2  SAMPLING, AMBIENT
5.2.1  Ambient Sampling With Hi-VOL Sampler
     Air is drawn into a covered housing and through a filter by a
high-flow-rate blower at 1.13 to 1.70 mVmin (40 to 60 ftVmin) that
allows total suspended particulates (TSP) with diameters of <100 |jm
(Stokes equivalent diameter) to collect on the filter surface.  Particles
with diameters of 0.1 to 100 (jm are ordinarily collected on glass fiber
filters.  When a sampler is operated at an average flow rate of
1.70 mVmin (60 ftVmin) for 24 h, an adequate sample can be obtained
even in an atmosphere having TSP concentrations as low as 2 ug/m3.
                                 5-9

-------
      Thermal  Desorption Device
Sample
cartridge
Capillary
cryogenic
trap
             Direct connection to
             capillary column of
             chromatograph
Purge
 gas
                                  Vent
2 position
6- port
valve

Carrier
  gas
                            XBL808-I728
Figure 5-6.  Schematic of NuTech thermal desorption device.
                  5-19

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Figure 5-7.   Assembled Hi-Vol  sampler with shelter housing.
                          5-11

-------
     The mass concentration (ug/m3) in ambient air is computed by
measuring the mass of TSP collected and the volume of air sampled.
Thus, this method is applicable to measurement of the mass concentration
of TSP in ambient air.   The size of the sample collected is usually
adequate for other analyses.
5.2.2  Dichotomous Hi-Vol Sampler
     Air is drawn through a mechanical separator enclosed in a covered
housing and through a filter by a high-flow-rate blower.  Particles with
diameters greater than 2.5 urn are deposited in the mechanical separation
chamber while particles less than 2.5 urn are captured on the glass fiber
filter.   The smaller size fraction can be separated for analysis either
by gravimetric means or by specific compound or element identification.
5.2.3  Hi-Vol Sampler With Adsorbent
     A high volume sample can be operated in either of the above modes
of operation with an adsorbent placed after the glass fiber filter.   The
purpose of the adsorbent is to trap (adsorb) any condensible organic
material which can be extracted or disorbed later.  Recent studies have
shown this to be a measurable fraction (>10 percent of the total catch).
5.3  LAB
5.3.1  Gas Chromatograph/Mass Spectrometer (GC/MS)
     The Gas Chromatograph/Mass Spectrometer (GC/MS) is an ultra high
sensitive analytical instrument.  The instrument produces mass spectra
of volatile and semi-volatile samples separated by the gas chromatograph
or of samples introduced via a solid probe inlet.
     The sample introduced via the GC is separated by the column and
introduced into the source of the MS.   The sample is ionized in the
source and sent through a mass filter where a range of masses is scanned
over a period of seconds.  The output is a chromatogram which is charac-
terized by the masses present and the elution time.
     The sample introduced by solid probe is volatilized directly in the
source and is characterized by the mass spectrum.
     Data collection and manipulation are controlled by a dedicated
computer system which minimizes operator time and report writing.
                                 5-12

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5.3.2  Ion Chromatography (1C)
     Ion Chromatography is used to identify and quantitate organic and
inorganic ions in solution.   1C combines the separation capabilities of
ion exchange resins with conductivity detection.   Small sample amounts
are loaded onto ion exchange columns which separate the ions by their
charge and size.   The separated ions are detected by an increase in
conductivity as they elute off the columns.  The order of elution and
the increase in conductivity determine the identity and quantity of the
ion.   To prevent background conductivity interference, a second exchange
column converts the background ions to a common ionic form.   Minimum
detectable limits are often as low as 10 parts per billion or less.
5.3.3  HPLC/UV - Fluorescence
     HPLC is a high pressure, highly efficient, high speed chromatographic
technique.  Variations of the experimental conditions and use of different
detectors provides an immense work scope, and separations that are
difficult or impossible by other means such as gas Chromatography.
Particular advantages of HPLC over gas Chromatography are its ability to
cope with polar, high molecular weight, thermally labile or relatively
non-volatile compounds, and the ease with which fractions can be collected
for further analyses.
     The combination of a UV and a dedicated fluorescence detector
allows the analyst to be specific and very sensitive (sub-nanogram) in
the quantisation of fluorescent compounds such as polynuclear aromatic
hydrocarbons (PNA).
5.3.4  Gas Chromatograph (GC)
     The Gas Chromatograph is a sensitive analytical instrument which
may identify any volatile or semi-volatile sample by means of separation,
temperature and retention time.  The unknown sample is introduced into a
heated injector where it is volatilized and passed through a column by
an inert carrier gas.  The column is selected based on either the physical
characteristics of the unknown or of the expected compounds.
     The detector is selected based on the expected compounds.
     The Electron Capture (EC) Detector is a radioactive source and is
extremely sensitive to chlorinated hydrocarbons.   This makes it especially
suitable for analysis of volatile pesticides and most chlorinated
compounds.
                                 5-13

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     The Flame lonization (FI) Detector is based on an oxidative hydrogen
flame that ionizes molecular fragments which are collected at an electrode.
The FID is less sensitive than the EC but is nearly uniform to all
organics containing only carbon and hydrogen.   Certain gases give little
or no signal, i.e., H2S, CS2, CO, which makes them excellent solvents or
media for analysis.
5.3.5  Metals
     5.3.5.1  Inductively Coupled Plasma (ICAP).  ICAP identifies and
quantitates metals in solution.  Atomic and ionic emission are measured
at variable wavelengths of light.  The sample is aspirated into an argon
plasma flame.  The energy of the flame excites either the atomic or
ionic electrons.   As the electrons fall back to their unexcited states,
light is emitted.   The intensity of this emission is measured by a
photomultiplier tube.  A double monochromator is used to observe many
different wavelengths of light per analysis.  The wavelength of emission
and the intensity identify and quantitate the metal.
     Determination of most metals is possible with minimum detectable
limits as low as  5 parts per billion.   Each analysis run can usually
check for 30 to 40 elements.   Generally, the amount of spectral overlap
and interference  is the main limiting factor on the number of elements
checked for per analysis.
     5.3.5.2  Atomic Absorption (AA).   Atomic absorption identifies and
quantitates metals in solution.  A sample is aspirated into a flame and
atomized.   A light beam is directed through the flame into a monochromator,
and onto a detector.   The detector then measures the amount of light
absorbed.   The amount absorbed in the flame is proportional to the
concentration of  the element in the sample.
     Absorption depends on the amount of free unexcited atoms.  Usually,
the ratio of unexcited to excited atoms is very high, which increases
the sensitivity.   Since each metal has its own absorption wavelength, a
source lamp made  up of that element is used.  This makes the method
relatively free of spectral interferences.  However, each lamp can check
for only one metal per analysis.   The detection limits are often as low
as 5 parts per billion.
                                 5-14

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                    6.  ALTERNATIVE DESIGN APPROACHES
                 TO RESIDENTIAL WOOD BURNING APPLIANCES
     Several alternative residential woodstove designs have been or are
being developed with the goals of improved overall efficiency and lower
emission generation.  Some of these designs are new, while others are
old ideas which are being re-evaluated.  These old ideas were initially
designed for better fuel efficiency but are now being re-evaluated from
an emission standpoint.   Most of these alternative approaches fall into
two main categories:  those which utilize cord wood and those which use
wood in other forms such as pellets or chips.
6.1  CORD WOOD DESIGNS
     Most of the alternative cord wood burning stoves are designed to
increase both the combustion efficiency and the subsequent transfer of
the energy released into the room.   These designs have been developed
primarily to increase the overall thermal efficiency.  Usually, increasing
thermal and combustion efficiency results in lowered emissions.
     The combustion of cord wood is inherently inefficient.  In the
localized combustion areas within the individual pieces of wood, there
is insufficient oxygen present to fully combust the volatile organic
compounds and CO driven out of the unburnt wood adjacent to the burning
wood.   In ordinary air tight stoves (and even in open fireplaces with
high excess air), these combustible compounds are subject to rapid
cooling once they are driven out of the wood and start to flow toward
the flue.  As soon as the temperature drops below the ignition point, no
further burning will occur, no matter whether oxygen is present or not.
Most secondary combustion stoves attempt to maintain these unburnt fuel
components produced in the primary combustion zone (grate area) at a
sufficiently high temperature and to provide sufficient oxygen so they
will burn more completely.   The two principal  secondary combustion
variants are defined by the absence or presence of a catalyst.

                                6-1

-------
     Noncatalyst secondary combustion stoves must maintain gas
temperatures above 1,100°F to achieve ignition of the CO while providing
sufficient oxygen.   This appears to work well at high burn rates but is
difficult to maintain at low burn rates.  This trend can be seen by
comparing tests OM2-84-1 through 7, Table 3-1.  Note the low PM values
at the higher burn rates.  Several sources reported high operator
attention was needed to maintain secondary combustion at low burn rates.
     Placing a catalyst in the flue gas stream lowers the ignition
temperature to about 400°F, thus greatly improving the changes for
successful secondary combustion.   Evidence for this can be seen by
looking at tests OM2-84-30 through 33, Table 3-1.  Note the low PM
factor (1.1 g/kg) at a burn rate of 0.8 kg/hr.  Catalysts, however, are
not panaceas.  Excessive temperature will cause melting and agglomeration
of the precious metal greatly reducing the available contact area.
Sulfur in coal and heavy metals in colored inks may poison the catalyst
reducing its effectiveness.  Even under normal homeowner use, effective-
ness will decline,  requiring periodic replacement of the catalyst
cartridge to maintain good emission control.
6.2  NONCORD WOOD DESIGNS
     Most noncord wood stoves utilize wood in the form of chips or
compressed pellets.   This form of wood fuel has commonly been burned in
industrial wood boilers, but has seen very limited application to
residential heating either in central systems or parlor stoves.  The
principal advantage of burrning wood in this form lies in the fact that
each piece of fuel  can be burned quickly in a nearly ideal temperature-
oxygen environment which ensures virtually complete combustion.
Three residential-use stoves now entering the marketplace all employ a
hopper to store 1 or 2 days fuel  in pellet form.   The fuel is automati-
cally fed by an auger or similar device into the combustion zone at a
variable rate dependent on home heating demand.   Obviously there is a
minimum rate required to maintain a continuous fire.   Two drawbacks to
widespread use of pellet- or chip-fueled residential  stoves are
(1) limited availability of fuel, and (2) loss of asthetics associated
with gathering wood and tending the fire.  Currently, pellets and chips
are generally available only in those areas of the country where logging
for construction and pulpwood are common.  Certainly, if demand arose in
                                 6-2

-------
other parts of the country, suppliers would move into the market.  The
problem may be that homeowners will not buy a stove unless the fuel is
readily available.
     The fluidized bed optimizes the three "Ts" of combustion (Time,
Temperature, and Turbulence).   There was only one test citation available
for this search, but it appeared to have promising results - lower
emissions with increased efficiency.
     The tunnel burner mentioned in one citation claimed to have a
99.999 percent reduction in POM emissions.  Both of these burner
modifications were used with wood chips or pellets to provide continuous
feed to the systems.
     Loss of the alsthetic appeal would be more difficult to counter.
Convenience is certainly a positive selling point.  At least a segment
of the public would also react positively to the greatly reduced
environmental impact of a clean burning stove.
                                 6-3

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                             7.  REFERENCES
 1.   Core, J. E. , et al.  Residential Wood Combustion Study, U.S.
     Environmental Protection Agency, EPA 910/9-82-089a.  Seattle,
     Washington.  February 1984.

 2.   Imhoff, R.  and J.  Manning.  "Preliminary Report on a Study of the
     Ambient Impact of-Residential Wood Combustion in Petersville,
     Alabama."  Proceedings, 1981 International Conference on Residential
     Solid Fuels,   p. 520.  June 1981.

 3.   Ibid, Carlson, J.   "Residential Wood Combustion in Missoula, Montana:
     An Overview of Its Air Pollution Contributions, Health Effects, and
     Proposed Regulatory Solutions."  p. 539.

 4.   Ibid, DeCesar, R.  and J. Cooper.  "The Quantitative Impact of
     Residential Wood Combustion and Other Vegetative Burning Sources on
     the Air Quality in Medford, Oregon."  p. 551.

 5.   Cooper, J.   "Environmental Impact of Residential Wood Combustion
     Emissions and Its Implications."  Journal of Air Pollution Control
     Association, Vol.  30, pp.  855-861.   1980.

 6.   Op. cit. (2), Muhlbaier, J.  "A Characterization of Emissions From
     Wood-Burning Fireplaces."  p. 164.

 7.   Ibid, Cooper, J.  "Chemical and Physical Methods of Apportioning
     the Contributions of Emissions from Residential Solid Fuels to
     Reductions in Air Quality."  p. 349.

 8.   Kamens, R., G. Rives, J. Perry, B.  Goodman, D. Bell, and D. Saucy.
     "Mutagenic and Chemical Changes in Dilute Wood Smoke as it Ages and
     Reacts in the Atmosphere."  76th Annual APCA Meeting.   June 19-24,
     1983.  83-54.12.

 9.   Butcher, S. and D.  Buckley.  "A Preliminary Study of Particulate
     Emissions from Small Woodstoves."  JAPCA, Vol. 27, pp.  346-348.
     1977.

10.   Butcher, S. and E.  Sorenson.   "A Study of Woodstove Particulate
     Emissions." JAPCA,  Vol. 29, pp. 724-728.  1979.
                                 7-1

-------
11.  DeAngelis, D. , D. Ruffin, and R. Reznik.  "Preliminary
     Characterization of Emissions from Wood-Fired Residential Combustion
     Equipment," EPA-600/7-80-040.  March 1980.

12.  Op. cit. (2), Hubble, B., et al.  "Experimental Measurements of
     Emissions from Residential Wood-Burning Stove."  p. 79.

13.  Allen, J.  "Control of Emissions from Residential Wood Burning by
     Combustion Modification."  Proceedings of the EPA Conference on
     Wood Combustion Environment Assessment, New Orleans, Louisiana.
     February 21-24, 1981.

14.  Ibid, Kosel, P.  "Pollution and Fireplaces in California."

15.  Ibid, Hayden, A. and R. Braaten.  "Performance of Domestic
     Wood-Fired Appliances."

16.  Lim, K.  and H.  Lipps.  "Overview of Emissions from Wood Combustion."
     From Wood:  An Alternate Energy Source for Appalachian Industry and
     Institutions.  Conference Proceedings and Manual for Wood Energy
     Conference, Winston-Sal em, North Carolina.  April 7, 1981.  Publ.
     N.C. State University, Raleigh, North Carolina.  1981.

17.  Op. cit. (2), Peters, J..  "POM Emissions From Residential
     Woodburning:  An Environmental Assessment."  p. 267.

18.  DeAngelis, D., D. Ruffin, J.  Peters, and R. Reznik.  "Source
     Assessment: Residential Combustion of Wood," U.S. Environmental
    . Protection Agency, EPA-600/2-80-042b.  March 1980.

19.  Op. cit. (2), Cooke, W. and J. Allen.  "Characterization of Emissions
     From Residential Wood Combustion Sources."  p. 139.

20.  Knight,  D. and C. Knight.  "Efficiency and Emission Performance of
     Residential Wood Heaters with Advanced Designs."  APCA 76th Annual
     Meeting.  June 1983.  paper 83-54.1.

21.  Op. cit. (2), Kowalczyk, J.,  P. Bosserman, and B. Tombleson.
     "Particulate Emissions from New Low Emission Wood Stove Designs
     Measured by EPA Method V."  p. 54.

22.  Knight,  C.  "Emission and Thermal Performance Mapping for an
     Unbaffled, Air-Tight Wood Appliance and a Box-Type Catalytic
     Appliance."  Proceedings No.  SP-45:  APCA Specialty Conference,
     Residential Wood and Coal Combustion.  APCA Specialty Conference.
     March 1982.  p. 25.

23.  Ibid, Hayden, A.  "Effects of Firing Rate and Design on Domestic
     Wood Stove Performance."  p.  56.

24.  Op. cit. (2), Barnett, S. and D. Shea  "Effects of Woodstove Design
     and Operation on Condensable Particulate Emissions."  p.  227.
                                 7-2

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25.  Op. cit. (1), Vol. Del Green Associates.  "Residential Wood
     Combustion Study."  Task 5, EPA-910/9-82-089g.

26.  Wolff, G.  T., et al.   "Visibility-Reducing Species in the Denver
     'Brown Cloud' - II. Sources and Temporal Patterns."  Atmospheric
     Environment.   July 13, 1981.

27.  Op. cit. (2), Kowalczyk, J. and W. Green.  "New Techniques for
     Identifying Ambient Air Impacts from Residential Wood Heating."
     p.  469.

28.  Ibid, Murphy, D. and R.  Buchan.  "Ambient Particulate and Benzo (a)
     Pyrene Concentrations From Residential Wood Combustion in a Mountain
     Resort Community."  p. 495.

29.  Ibid, Hornig, J., et al.  "Ambient Air Assessment in Rural Village
     and Small  Town Locations in New Hampshire Where Wood is an Important
     Fuel."  p.  506.

30.  Truesdale,  R. S., K.  L.  Mack, J. B. White, K. E. Leese, and
     J.  G. Cleland.  "Characterization of Emissions from the Combustion
     of Wood and Alternative Fuels in a Residential Woodstove."  Final
     Report.   EPA Contract No.  68-02-3170, Work Assignment No. 39.  U.S.
     Environmental Protection Agency, Research Triangle Park, NC 27711.
     March 1984.

31.  "Test Report Prepared for Catalytic Damper Corporation."  Omni.
     May 1983.

32.  Butcher, S. and M. J. Ellenbecker.  "Particulate Emission Factors
     for Small  Wood and Coal  Stoves."  Bowdoin College, Brunswick,
     Maine 04011.   JAPCA,  Vol.  32, pp. 380-384.  April 1982.
                                 7-3

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                             8.0     APPENDIX
18/5/6
81-00135
  Air  Pollution  emissions  anrl  rnnt.rn!   t.pchni n
-------
20/5/3
1013766  PB83-250720
  Compilation of Air Pollutant Emission Factors? Third Edition?  Supplement
No. 14 (Including Supplements 1-7)
  Environmental Protection Agency?  Research Triangle Park?  NC.  Office of
Air Quality Planning and Standards.
  Corp. Source Codes: 034680059
  Report No.: AP-42-SUPPL-14
  Ma* 83   172p
  See also PB83-126557.
  Languages' English
  NTIS Prices: PC A08/MF A01    Journal Announcement: GRAI8326
  Country of Publication: United States
  In this Supplement for AP-42? new or revised emissions data are presented
for   Anthracite  Coal  Combustion!   Wood  Waste  Combustion  in  Boilers?
Residential Fireplaces? Wood Stoves} Open Burning?  Large Appliance Surface
Coating? Metal Furniture Surface Coating?  Adipic Acid?  Synthetic Ammonia?
Carbon Black? Charcoal? Explosives? Paint and Varnish?  Phthalic Anhydride?
Printing  Ink?  Soap and Detergents?  Terephthalic Acid?  Maleic Anhudride!
Primary  Aluminum  Production?   Iron   and   Steel   Production?    Gapsum
Manufacturing?    Construction   Aggregate  Processing?   Sand  and  Gravel
Processing? Taconite Ore Processing? Western Surface Coal Mining?  Fugitive
Dust Sources? Unpaved Roads?  Agricultural Tilling?  Aggregate Handling and
Storage Piles? and Industrial Paved Roads.
  Descriptors:   *Air  pollution?   Anthracite!   Wood  wastes?   Coatings?
Appliances? Furniture!  Carbon black? Explosives? Detergents? Soaps? Paints!
Maleic anhdride? Phthalic anhydride?  Gypsum!  Aluminum industry!  Iron and
steel  industry? Pavement? Roads?  Surface mining
  Identifiers: ^Emission factors? ^Stationary sources? Wood stoves!  Refuse
derived fuels? Fugitive emissions? Unpaved roads? NTISEPAAQP
  Section  Headings:   13B  (Mechanical?   Industrial?   Civil?  and Marine
Engineering—Civil  Engineering)?    68A   (Environmental   Pollution   and
Control—Air Pollution and Control)
 0147919   EIM8304027919
   CHARACTERIZATION OF EMISSIONS FROM RESIDENTIAL COAL STOVES.
   Sanborn? Cedric R.
   Vt Hep of Water Resour I Environ Eng?  Montpelier?  USA
   Proceedings  -  Residential Wood S  Coal Combustion Specialty Conference.
 Louisville. Ku»  USA   Mar 1-2 1982
 — Sponsor: AP'CA» Resid Fuel Combust Comm?  Pittsburgh? Pa?  USA?  APCA?  Indoor
 Air dual Coitrm. Pittsburgh? Pa? USA
   Source:  Publ  by APCA (Spec Conf Proc  SP-45)?   Pittsburgh?    Ps?   USA  p
 151-160   1982
   Languages! English    Conf. No.! 01854
   Descriptors! STOVES-Environmetal Impact
   Identifiers!   RESIDENTIAL  COAL  EMISSION  TESTING  STUDY!    PARTICULATE
 EMISSIONS!  SULFUR DIOXIDE EMISSIONS!  THREE COAL STOVE  TYPES!   RANGE  OF
 BURNING  RATES!    TESTING WITH ANTHRACITE AND BITUMINOUS COAL!   PRELIMINARY
 TEST PROGRAM RESULTS!  SIGNIFICANTLY HIGHER PARTICULATE  EMSSION  RATE  FOR
 BITUMINOUS COAL! EFFECT OF BURN RATE ON SULFUR DIOXIDE EMISSIONS! EFFECT OF
 FIREBOX TEMPERATURE ON SULFUR DIOXIDE EMISSIONS
   Classification Codes! 643? 524? 451

 ? T 23/5/6-^7
                                     8-2

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   j/10

 1157591   ERA-OS!042212» INS-83J017234*  NTS-83J018231 ,  EDB-83:152419
/ Computing transient exposure to indoor pollutants
  Owczarski* P.C.?  Parker* G.B,
  Pacific Northwest Lab.* Richland*  UA (USA)
  13 P.   Mar 1983
  TIC Accession No.! DE83014500
  76.   annual  meeting of the Air Pollution Control Association   Atlanta*
GAf USA   19 Jun 1983
  Country of Publication: United States
  Journal Announcement: EDB8307
  Availabilita: NTIS* PC A02/MF AOli 1.
  Report No.1. PNL-SA-10838? CONF-830617-12
  Note: Portions are illegible in microfiche products
  Document Tape*. Report? Conference literature? Numerical data
  Languages: English
  Subfile!  NTS .(NTIS)?  INS .(US Atomindex input)?  ERA .(Energy Research
Abstracts)
  Uork Location! United States
  Contract No.! AC06-76RL01830
  A computer code* CORRAL* is used to compute the transient levels of gases
and  respirable  particulates  in a residence.  Predictions of time-varying
exposure to radon (from  the  outside  air*   soil  and  well  water)   and
respirable  particulates  (from  outside  air*   wood  stove  operation and
cigarette smoke)  for a mother and child over 24 hours ere  made.   Average
24-hour radon exposures are 13 times background (0.75 pCi/1)  for the child
and 4.5 times  background  for  the  mother.   Average  24-hour  respirable
particulate  exposures are 5.6 times background (100  ..mu..2/m/sup 3/>  for
the mother and  4.2  times  background  for  the  child.   The  controlling
parameters  examined  are  source location*  flow rates between roomsi  air
infiltration rate and lifestale. The first three are  shown to influence the
formation of local pockets of hiah concentration of radon and particulates*
and the last parameter shows  that  lifestyle  patterns  ultimately  govern
individual  exposure  to these pockets of high concentrations.  The code  is
useful for examination  of  mitigation  measures  to  reduce  exr-osure  and
examination of the effects thct the controlling parameters hove on exposure
to indoor pollutants.
  Descriptors!     *INDOOR    AIR    POLLUTION	COMPUTER    CALCULATIONS?
*PARTICULATES	ECOLOGICAL    CONCENTRATION;     KRADON	RADIOECOLOGICAL
CONCENTRATION;  #RESIDENTIAL BUILDINGS	INDOOR AIR  POLLUTION ?  CHILDREN?
COMPUTER CODES? EXPERIMENTAL DATA? TOBACCO SMOKES; VARIATIONS* WOMEN!  WOOD
BURNING APPLIANCES
  Special Terms! AEROSOLS; AGE GROUPS? AIR POLLUTION? ANIMALS?  APPLIANCES?
BUILDINGS? COLLOIDS? DATA? DISPERSIONS; ECOLOGICAL CONCENTRATION? ELEMENTS*
FEMALES; FLUIDS; GASES; INFORMATION;  MAMMALS;  MAN;  NONMETALS;  NUMERICAL
DATA; PARTICLES; POLLUTION? PRIMATES? RARE GASES? RESIDUES?  SMOKES?  SOLS?
VERTEBRATES
  Class Codes! 500300*; 500200 ) B33*? C52
                                    8-3

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20/5/15
856614  PB81-217655
  Control   of  Emissions  from  Residential  Wood  Burning  bu  Combustion
Modification
  (Final rept. Jun 79-Nov 80)
  Allen? John M. ? Cooke? W. Marcus
  Battelle Columbus Labs.? OH.
  Corp. Source Codes! 038006000
  Sponsor! Industrial Environmental Research Lab.?  Research Triangle Park?
NC.
  Report No.! EPA-600/7-81-091
  Maa 81   lOOp
  Languages! English
  NTIS Prices! PC A05/MF A01    Journal Announcement! GRAI8121
  Country of Publication! United States
  Contract No.! EPA-68-02-2686
  The  report  describes  an  exploratory  study of factors contributing to
atmospheric emissions from  residential  wood-fired  combustion  eauipment.
Three  commercial  appliances  were  operated with both normal and modified
desiansf providing different burnina modes!  updrsft with a state?  updraft
with a hearth? crossdraft? downdraft?  and a high-turbulence mode utilising
a forced-draft blower.  Fuels were naturally dried commercial oak corduood?
commercial green pine cordwood? oven-dried fir brands?  and naturally dried
oak cut into reproducible triangles. Continuous measurements of stack aases
included 02?  C02?  CO?  NO*  S02?  and total  hydrocarbons  (FID)   as  an
indication  of  the  total  organic species in the stack gases during batch
type operation.  Several combustion modification techniaues were identified
which have an appreciable effect on emission factors and? therefore*  can be
developed  and  applied  to  reduce  emissions  in  consumer use.  The more
promising design modifications include! prevention of heating the inventory
of wood within the stove but not yet actively burning?   focusing  the  air
supply  into the primary burning area with high turbulence?  and increasing
the temperatures in the secondary burning regions of the appliances.
  Descriptors! *Air pollution control?  (Wood? Stores?  Combustion products?
Revisions? Residential buildings? Eauipment? Oxygen? Carbon dioxide?  Carbon
monoxide? Nitrogen oxide(NO)? Sulfur dioxide? Hydrocarbons? Design criteria
? Performance evaluation
  Identifiers: NTISEPAORD? NTISEPAORD
  Section  Headings!   13B  (Mechanical?   Industrial?   Civil?  and  Marine
Engineering—Civil  Engineering)t    68A   (Environmental   Pollution   and
Control—Air Pollution and Control)
                                      8-4

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20/5/18
780215  COO-4559-1
  Design?   Construction  and  Performance  of Stick-Wood Fired Furnace for
Residential and Small Commercial Application* September li  1977-Auaust 31?
1979
  Hill? R. C.
  Maine Univ.  at Orono.
  Corp. Source Codes: 050804000? 3877000
  Sponsor! Department of Eneray? Washington? DC.
  Oct 79   28p
  Languages! English
  NTIS Prices! PC A03/MF A01    Journal Announcement: GRAI8019? NSA0500
  Country of Publication! United States
  Contract No.! EC-77-S-02-4559
  An experimental program uas conducted at the Universitu of Maine at Orono
to  develop  a  combustion  sastem for residential furnaces that solves the
traditional problem of wood burnina! inefficienca? air pollution?  and fire
hazard.   The  program   led to the designs that are now covered ba a patent
application and are being manufactured ba Dumont Industries? Madauaska Wood
Furnace Compana?  and Hampton Technoloaies Corporation Ltd.    The  histora?
desianr performance? and the construction of prototape production units are
presented.  (ERA citation 05:013993)
  Descriptors: tCommercisl buildings! ^Residential buildings?  *Uood?  *Uood
burnina furnaces?  Air pollution?  Calorific value?  Chemical  composition?
Combustion products? Concretes?  Construction?  Desian?  Experimental data?
Fire hazards? Graphs? Maine? Manufacturing? Performance? Tables
  Identifiers? ERDA/320101? ERDA/320104? NTISDE
  Section Headinas!  13A   (Mechanical?   Industrial?   Civil?   and  Marine
Enaineerina—Air Conditioning?  Heating?  Liahtina?  and Ventilating) J  97J
(Eneraa—Heating and Coolina Systems)
                                                                 Combustion
 18/5/2
 82-04512
  Control   of  Emissions  From  Residential  Wood  Burnina
 Modification
  Allen? J.M.? Cooke? W.M.
  Battelle Columbus Lab.? OH
  Publ.YrJ 1981
  NTIS? SPRINGFIELD? YA
  SUMMARY LANGUAGE -  ENGLISH?  PB81-217655
  Languages! ENGLISH
  The report describes an exploratory  studa  of  factors  contributing  to
Three commer ei"JSSlOnS  from  residential  wood-fired combustion eouipment.
design?  providing rtiff~~~r.t  ^	?^fr?.^__"lth  .bo^h  nor'"3l  and  modified
with a hearth?
a forced-draft

oTcut1--''!!^!^^^' r-":?i?«"*"1*"''""1  and naturalla dried
           of  the  total
t.wpp nvprat.inn.
  uesi. rip tu rs i  toinous Lion ?  wuou? tmissionsi
turbulence? furnaces? air pollution control
                                        in the  stack  aases  durina  batch
                                             naurocd coonvi ?
                                      8-5

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 /1196909   EDB-83!191742
   Development  and  testing  of  an  automated  wood-burning  heating  system.
 Final  report
   Martin  (Uerner). Chapel Hill. NC  (USA)
   48 P.   Maa  1981
   TIC  Accession No.! DE84000383
   Country of Publication! United States
   Journal Announcement!  ERA8311
   Availabilita! NTIS. PC A03/MF A01? 1.
   Report  No.!  DOE/R4/10156-T1
   Note! Portions  are illegible in microfiche  products
   Document Tape!  Report
   Languages! English
   Subfile! ERA .(Energw  Research Abstracts)?  NTS  .(NTIS)
   Uork Location!  United  States
   Contract No.! FG44-80R410156
   An improved  wood  continuous.    automated   combustion   system  has  been
 developed  using  a  tunnel  burner.   The  tunnel  burner  implemented into a
 boiler heating system has proven to  be vera efficient.  The   prototype  was
 tested and  evaluated.  A second generation  tunnel  system was designed and
 fabricated. Uork  performed between  April  1980 and  April 1981 is summarized.
 The most  important results of the project are!  the  finalized tunnel burner
 design?   hiah  combustion efficiency?   and low air  pollution emissions.   3
 tables. (DMC)
   Descriptors!    *BURNERS	DESIGN?   *FUEL    FEEDING    SYSTEMS	DESIGN?
 *UOOD	COMBUSTION?   *UOOD  BURNING APPLIANCES	DESIGN ?  AIR POLLUTION
 ABATEMENT? AUTOMATION? EFFICIENCY?  EMISSION?  ENERGY  SYSTEMS
   Special Terms!  APPLIANCES? CHEMICAL REACTIONS?   FUEL  SYSTEMS?  OXIDATION?
 POLLUTION ABATEMENT? THERMOCHEMICAL  PROCESSES
   Class Codes! 090400*?  140504?  421000


23/5/20                                                                    ^
0039963   EIM8210039963
  EFFECT   OF   CATAI YTTT  rnMRIIRTTflN  OF  rSFOfiOTF  P^niirTTON.
              HNU r-ULLUIiUN HtlH I tntM I  TUK Kt&iUtNllrtL WUUU Mt
    Ziman  Frank. VanDeuoestine.  Robert W.{  Allaire.  Rosier A.
    Corning Glass Works. NY. USA
    Proceedings -  1981  International  Conference on Residential Solid  Fuels.
  Environmental Impacts  and Solutions.   Portland. Ored, USA   Jun 1-4 1981
    Sponsor!  Dreg Grad Cent, Beaverton,  USA?  Northwest Environ Res Cent.  USA?
  Omark Ind.  Oreg Saw Chain Div.  USA
    Source!  Publ  by  Oreg Grsd Cent.  Beaverton,  USA i>  924-940   1982
    Languages!  English   Conf.  No.!  00722
    Descriptors!  UOOD-Heating
    Identifiers!   CATALYTIC  COMBUSTION?  CREOSOTE REDUCTION?   AIR POLLUTION
                                                                      ORGAN??
    Classification  Codes!  811?  643?  521?  451?  532

. 1196909    EDB-83!191742
   Development   and  testing   of   an  automated  wood-burning heating system.
 Final  report
   Descriptors!    *BURNERS ---- DESIGN?    *FUEL    FEEDING   SYSTEMS ---- DESIGN?
 *UOOD ---- COMBUSTION?    *WOOD   BURNING APPLIANCES ---- DESIGN )   AIR POLLUTION
 ABATEMENT?  AUTOMATION?  EFFICIENCY?  EMISSION?  ENERGY SYSTEMS
   Special  Terms!  APPLIANCES?  CHEMICAL REACTIONS?   FUEL SYSTEMS?   OXIDATION?
 POLLUTION  ABATEMENT?  THERMOCHEMICAL PROCESSES
   Class  Codes!  090400*;  140504?  421000
                                        8-6

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.1173232   EDB-83: 170062
  The  effects  of stove desian and control mode on condensable ^articulate
emissions! flue pipe creosote accumulation and the efficiency of woodstoves
in homes
  Symposium papers? energy from biomass and wastes VI
  BarnettF S.G.! Feinaold. B.U.!  Courtney. L.  (eds.)
  Condar Co.f NY
  283-322 P.   Jun 1982
  6.  annual conference on energy from biomass wastes VI   Lake Buena Vista.
FL. USA   25 Jan 1982
  Countra of Publication! United States
  Publ! Institute of Gas Technology. Chicago. IL.
  Journal Announcement: EDB8306
  Report No.! CONF-820127-
  Document Tape! Analytic of a Book! Conference literature
  Languages: English
  Uork Location: United States
  Four uears of woodstove research utilizing a mixture  of  laboratory  and
in-home investigations has lead to both the development at Condsr Co.  of a
new extremely clean burning and efficient!  commercially viable*  catalytic
uoodstove as well as a new stove control system.   Results .arc presented in
four  research areas:  characterization of home burning ratesi   psrticulate
emissions*   in-home  creosote  accumulation rates;  and in-home efficiency
evaluations .
  Descriptors:    *CREOSOTE ---- BUILDUP.    *STOVES ---- COMBUSTION   PRODUCTS.
*STOVES ---- DESIGN;  *UOOD BURNING APPLIANCES ---- COMBUSTION PRODUCTS?  *UOOD
BURNING APPLIANCES ---- ENERGY EFFICIENCY ! AIR QUALITY,' CATALYTIC COMBUSTORS
i  COMBUSTION CONTROLS COMPARATIVE EVALUATIONS!  CONTROL SYSTEMS*  FLUE GAS!
INDOOR AIR POLLUTION! PARTICULATES
  Class Codes:  421000*! 320101! 090400! 500200
23/5/9
0147914   EIM8304027914
  EFFECTS OF FIRING RATE AND DESIGN ON DOMESTIC WOOD STOVE PERFORMANCE.
  Haaden. A. C. S.! Braaten. R. U.
  DeP of Energy. Mines & Resour, Ottawa. Ont. Can
  Proceedings  -  Residential Wood S  Coal Combustion Specialty Conference.
Louisville. Ka» USA   Mar 1-2 1982
 'Sponsor! APCA. Resid Fuel Combust Comm. Pittsburgh? Pa» USA! APCA. Indoor
Air dual Comm. Pittsburgh. Pa. USA
  Source! Publ ba APCA (Spec Conf Proc SP-45)» Pittsburgh. Pa.  USA p  56-69
1982
  Languages: Enalish   Conf. No.! 01854
  Descriptors: STOVES-Performance
  Identifiers:   CONTROLLED COMBUSTION WOOD STOVES!  INCOMPLETE COMBUSTION!
               HTRH FMTSSTOMSJ  ri nqr PFI ATTON OF  PMT-scinN i FIICI 
-------
X/1110395   EDB-83!105268
   Effects of woodburnina on indoor pollutant concentrations
   74.   annual meeting of the Air Pollution Control Association.     Session
 22.  Energy conservation effects on  indoor air  pollution  ?    Pelton?
 D.J.f  Bera» D.R.
   14 Pt Paper 2 P.    1981
   74.    annual   meeting   of   the   Air  Pollution  Control   Association
 Philadelphia, PA» USA  21  Jun  1981
   Country of Publication: United States
   PublS Air Pollution Control Association*Pittsburgh?  PAr
   Journal Announcement! EDB8306
   Report No.: CONF-810631-
   Docunent Type! Analytic of a Book;  Conference  literature
   Languages! English

    Elevations  in  the concentrations  of  carbon   monoxide*    total  suspended
  particulates?    and  benzo-a-purene   are   associated   with   fugitive indoor
  emissions  from  indoor woodburnina  activity  in   fireplaces  snd   woodstoves .
  While   indoor  woodburnina  activity  can  not  be  statistically associated with
  elevated  indoor  concentrations  of  total  aldehydes   snd  formaldehyde?    the
  existence   of   indoor  sources   of   these  pollutants   hss  emersied from the
  collected  data  base.  The operation  of fireplaces letidc to a marked increase
  of  the  infiltration rate of the  room with the   fireplace.    This  loads  to
  waste   rather   than  saving of   energy.    This  is  a  pilot  study snd its
  conclusions must not  be generalized  to  the  American housing stock.   It  is
  apparent? however?   that woodburnina is  an  indoor  activity  that  leads  to an
  increase of human exposures to  TSP   and   BaP?    and  it   may  contribute  a
  significant  portion  of an individual's  total  exposure  to  those pollutants
  and their associated  health effects.
   Descriptors!      *BENZOPYRENE	ECOLOGICAL    CONCENTRATION?      *CARBON
  MONOXIDE	ECOLOGICAL CONCENTRATION?  *FORMALDEHYDE	ECOLOGICAL CONCENTR-
  ATION?   *HUMAN POPULATIONS	HEALTH HAZARDS?   *PARTICULATES	ECOLOGICAL
  CONCENTRATION?  #UOOD  FUELS	COMBUSTION  PRODUCTS?  *UOOD  FUELS	ENVIRONM-
  ENTAL EFFECTS  ?  CARCINOGENS?  ENERGY CONSERVATION?    FIREPLACES?   HOUSES?
  INDOOR AIR  POLLUTION; SPACE HEATING
   Special Terms! AIR  POLLUTION?  ALDEHYDES?  AROMATICS?   BUILDINGS?  CARBON
 COMPOUNDS?  CARBON  OXIDES?  CHALCOGENIDES?   CONDENSED  AROMATICS?  ENERGY
  SOURCES?' FUELS? HAZARDS? HEATING? HYDROCARBONS?  ORGANIC  COMPOUNDS?  OXIDES?
 OXYGEN COMPOUNDS? PARTICLES? POLLUTION? POPULATIONS? RESIDENTIAL BUILDINGS
   Class Codes!  500200*
  23/5/27
  0039925   EIM8210039925
    EFFECTS  OF  UOODSTOVE  DESIGN  AND  OPERATION ON CONDENSABLE PARTICULATE
  EMISSIONS.
    Barnett? Stockton G.J Shea? Domian
    State Univ of NY? Plattsburgh? USA
    Proceedings -  1981 International Conference on Residential Solid  Fuels?
  Environmental Impacts and Solutions.   Portland? Ored? USA   Jun 1-4 1981
    Sponsor: Orea Grad Cent? Beaverton? USA? Northwest Environ Res Cent? USA?
  Omark Ind? Ores Saw Chain Div? USA
    Source: Publ by Orea Grad Cent? Beaverton? USA P 227-266   1982
    Languages: English   Conf. No.! 00722
    Descriptors! UOOD-Combustion
    Identifiers!   FLUE  GASES?   WOOD  STOVE  DESIGN?  FILTERS?  FLOUMETERS?
  THERMOSTATS? AIR POLLUTION? CRITICAL STACK TEMPERATURE? CONVECTIVE HEATER
    Classification Codes! 811? 521? 802? 451? 643? 732
                                  8-8

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impact  of  residential  wood combustion emissions and its
                of Environmental Science?   19600 NU Uslker
                             30(8) >
                                       855-861:
Coden:
18/5/5
81-00172
  Environmental
implications.
  Cooper?  J. A.
  Oreaon Graduate Center?  Dept.
Rd.f Beavertonr OR 97005
  Air Pollution Control Association.  Journal
JPCAAC   Publ.Yr: Aua 1980
  illus.   55  refs.
  No abs.
  Landuaaes: ENGLISH
  Doc Type? JOURNAL PAPER
  A direct measurement of the impact of residential wood  combustion  (RUC)
sources  on  ambient  sir particles showed that on a moderately cold dau in
Jan.   1978?  51%  of the respirable particulates in a  Portland»   Oreaon?
residential area were from RUC sources.   The results of a Vail?  Colorado?
survey showed   that  emissions  from  RUC  could  contribute  <=0.64  T  of
particulates/d  to  the  valley's  air  pollution levels.   Health concerns
relate to  particulates and chemicals formed due to  incomplete  combustion.
Two recent studies measured MOO chemicals and compound groups in emissions
from  burning   wood and wood-burnina stoves (UBS).   The results are shown.
Emissions  from RUC sources must be considered s potential major  threat  to
public  health.    There  are  currently  7  national  ambient  air duality
standards  and  others are being considered.   The major emissions and  their
emission  factors  for  UBS  and  fireplaces  are listed.   These emissions
normalized  to  a  hypothetical   UBS  particulate  level  in  the   ambient
environment  are  compared with ambient standards for sn acute impact where
UBS emissions  are postulated to account for  260  mu3/ro3  of  particulates.
Emissions   from  RUC sources appear more significant when compared to other
fuels for  residential space heating and transportation sources.  (FT)
  Descriptors: Environmental impact?  Combustion?'  Emissions?  Particulates?
Uoods? Air pollution
  Identifiers: residential wood combustion
                     8-9

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  J212998    EDB-84S005496
*•*  Environmental   impact   of   residential   wood  combustion omissions and its
 implications
   Cooper*  J.A.
   J.  Air Pollut.  Control  Assoc.  (United  States)    30!8    855-861  P.    1980
 Coden:  JPCAA
   Journal  Announcement: EOB8308
   Document Type!  Journal  Article
   Lanauases!  English
   Work  Location:  United States
   Currently  available  information   suaaests   a   substantial  environmental
 impact  from residential wood  combustion  emissions.   Air pollution from this
 source   is  widespread  and   increasing.     Current   ambient  measurements*
 surveys*   and model predictions  indicate  winter  respiroble «2 micrometers)
 emissions  from  residential wood  combustion  can   easily  exceed  all  other
 sources.     Both   the  chemical  potency  and  deliverability of  the emissions
 from  this  source  are of concern.  The emissions  are almost entirely in the
 inhalable    size    ranae   and    contain   toxic   and  priority  pollutants*
 carcinogens *   co-carcino3ens»  cilia  toxic*  mucus coaaulatina adcnts*  and
 other respirators irritants such as phenols* aldehydes*  etc.    This source
 is contributing substantially to the  nonattainment of current   rorticulate*
 carbon   monoxide*  and   hydrocarbon  ambient air  duality  standards and will
 almost  certainly  have a sianificant  impact on   potential   future  standards
 such  as inhalable particulatest   visibility*  and other chemically specific
 standards.    Emission  from   this arowind  source   is   likely  to  reouire
 additional  expenditures  by industry  for  air pollution  control eauipment in
 nonattainment areas.
   Descriptors:      *WOOD	COMBUSTION      PRODUCTS?      #UOOD     BURNING
 APPLIANCES	ENVIRONMENTAL   IMPACTS  ?    AIR   POLLUTION!  AIR  POLLUTION
 ABATEMENT?    ALDEHYDES}   CARBON  MONOXIDE?     CARCINOGENS?    COMBUSTION?
 ENVIRONMENTAL  EFFECTS?   HOUSES?    PARTICULATES?    PHENOLS?    POLLUTANTS?
 RESIDENTIAL SECTOR? RISK  ASSESSMENT  •
   Special  Terms:  APPLIANCES?  AROMATICS?  BUILDINGS? CARBON COMPOUNDS? CARBON
 OXIDES? CHALCOGENIDES?   CHEMICAL REACTIONS?  HYDROXY  COMPOUNDS?   ORGANIC
 COMPOUNDS?    OXIDATION?   OXIDES? OXYGEN  COMPOUNDS?   PARTICLES?  POLLUTION?
 POLLUTION  ABATEMENT? RESIDENTIAL BUILDINGS?  THERMOCHEMICAL PROCESSES
 23/5/10
 0147913   EIM8304027913
   EMISSIONS AND THERMAL PERFORMANCE MAPPING FOR AN UNBAFFLED,  AIRTIGHT WOOD
 APPLIANCE AND A BOX TYPE CATALYTIC APPLIANCE.
   Kniaht* C,  V.?  Graham* M.  S.
   TVA»  Chattanooaa* Tenn* USA
   Proceedings  -   Residential Wood t  Coal Combustion Specialty Conference.
 Louisville* Ku. USA   Mar 1-2 1982
	SpoTis"o>:~"APCA»  Res'id Fuel  Combust Comm*  Pittsburah* Po*  USA? APCA» Indoor
 Air dual Comm. Pittsburgh* Pa*  USA
   Source: Publ by APCA (Spec Conf Proc SP-45)» Pittsburah* Pa*  USA p 25-55
 1982
   Landuaaes:  Enalish   Conf. No.! 01854
   Descriptors: STOVES
   Identifiers:   TENNESSEE  VALLEY  AUTHORITY  TESTING  OF RESIDENTIAL MOOD
 HEATING?  ENERGY USE TEST FACILITY?  EMISSION FACTORS?  EFFICIENCIES?   GAS
 CONCENTRATION   MONITORING?     TEMPERATURE   AND  WEIGHT  DATA  MONITORING?
 THERMODYNAMIC COMPUTER MODEL FOR CALCULATING EMISSION FACTORS AND? INDIRECT
 STACK LOSS METHOD?  COMPARISON OF RESULTS WITH OTHER TEST DATA?   DATA  FOR
 LOWER BURN RATES? OPTIMUM OPERATING CONDITIONS
   Classification Codes: 643? 811? 521? 451
                                        8-1Q

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20/5/4
1011629  PB83-247395
  Evaluation of an S2 Sampler for Receptor Modeling of Uoodsmoke Emissions

  Northrop Services* Inc.i  Research Triandle Park*  NC.
  Corp. Source Codes: 058582000
  Sponsor!   Environmental  Sciences Research Lab.*   Research Triangle Pork»
NC.
  Report No.! EPA-600/D-83-099
  Aug 83   20p
  Languages! English
  NTIS Prices! PC A02/MF A01    Journal Announcement! 6RAI8325
  Country of Publication! United States
  The Source Signature (sauared S)  sampler was developed  to  characterize
the carbon (C)  and elemental components in fine particulate emissions from
a residential wood burner.   The hot exhaust is  sampled  and  diluted  with
filtered air to simulate normal diffusion.  The resulting aerosol it. passed
through a 2.5-mu m cyclone  and the remaining  particles  collected  on  two
parallel 1-mu m filers* one Quarts and one Teflon.  The Quarts filter allows
analysis  of carbon content and the Teflon filter allows elemental analysis
bu x-ray fluorescence.  Both filters are  also  weighed  to  determine  the
mass-emission rate. The test program's main objectives were (1)  to test and
improve  the  performance  of  the  method*   and (2)  to make a laboratory
measurement of the elemental composition including  the carbon component  to
establish a source signature for use in receptor modeling.
  Descriptors!   *Mass»   *Fines»   *Air  pollution*    XX-rsu fluorescence*
^Samplers*  ^Chemical analysis*  Mathematical models*   Particles*   Design
criteria* Performance evaluation* Comparison
  Identifiers: ftUood stoves* *Air Quality* *Source  signature samplers* *Air
pollution sampling* Air pollution detection* NTISEPAORD
  Section   Headings!   14B  (Methods  and  £auipment--Labor3tories*   Test
Facilities*  and Test Eauipment>*  7D (Chemistry—Physical  Chemistry)*  68A
(Environmental  Pollution  and  Control--Air  Pollution  and Control)*  99A
(Chemistry—Analytical Chemistry)
                                    8-11

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 23/5/32

 0039919   EIM8210039919

 o-rnnr!RIMENTAL  MEASURE«ENTS  OF  EMISSIONS  FROM  RESIDENTIAL  WOOD-BURNING
 aTQVES•

   Hubble. B. R.f Stetter. J. R.i Gebert. E.! Harkness.  J.  B.  L.?   Flotard.
 R» D.

   Araonne Natl Lab. 111. USA

   Proceedings  -  1981 International Conference on Residential  Solid  Fuels,
.Environmental Impacts and Solution*.   Pnrtlanrl. flrprt.  USA   .Inn  1-4  19fll

    a^onsor;  Urea  urao  Lent,  oaavtti- ton,  uan.  nurtures, L environ <\es> uent, UOH.
  Omark  Ind,  Orea  Saw Chain Div,  USA

    Source: Publ  ba  Orea  Grad Cent. Beaverton.  USA  p  79-138   1982
    Lanauaaes:  Enalish    Conf.  No.! 00722
    Descriptors:  WOOD-Combustion

    Identifiers!   ORGANIC  EMISSIONS?   STACK   GAS   TEMPERATURES!     HEATING
  REQUIREMENTS?   LOGS?   CREOSOTE!   ENVIRONMENTAL ASSESSMENT?  CHROMATOGRAPHY?
  DATA SYSTEM?  ASH HANDLING

    Classification Codes!  811?  521? 643! 901?  723?  802
 21/5/7
   146303   *80-006112
   ERA'S  RESEARCH  PROGRAM  FOR  CONTROLLING  RESIDENTIAL  WOOD  COMBUSTION
 EMISSIONS.
V  HALL ROBERT E. »  DEANGELIS DARYL G.
   (EPA) AND? (MONSANTO RESEARCH CORP. OHIO)
   APCA J. AUG 80. V30. N8. P862 (6)
   RESEARCH REPORT!  AN EPA-FUNDED STUDY BY THE MONSANTO CORP.  OF OHIO.  WAS
 CONDUCTED  TO  QUANTIFY  CRITERIA  POLLUTANTS  AND  TO  CHARACTERIZE  OTHER
 ATMOSPHERIC EMISSIONS FROM  WOOD-FIRED  RESIDENTIAL  COMBUSTION  EQUIPMENT,
 MAJOR  FINDINGS  OF  THE  MONSANTO  CHARACTERIZATION  STUDY  ARE DISCUSSED.
 EQUIPMENT TESTED INCLUDED A ZERO CLEARANCE FIREPLACE AND TUO AIR TIGHT  CAST
 IRON STOVES.  WOOD TESTED INCLUDED SEASONED AND GREEN RED  OAK  AND  YELLOW


 SULFUR OXIDES.   ORGANIC  SPECIES.   CONDENSABLE  ORGANICS.   PARTICULATES.   AND
 TRACE   ELEMENTS.    BIOASSAY   ANALYSES  OF  THE STACK  EMISSIONS  AND BOTTOM  ASH
 WERE PERFORMED.  (2  GRAPHS.  10 REFERENCES,  6 TABLES)
   DESCRIPTORS:  *EMISSION CONTROL PROGRAMS  ?  *EPA. FEDERAL  ?  *SPACE  HEATING.
 DOMESTIC !   *WOOD ENERGY !   *PARTICULATES  ?  *AIR SAMPLING   ?   BIOASSAY  ?
 CHROMATOGRAPHY,  GAS ?  NITROGEN OXIDES  ?  SULFUR OXIDES
   REVIEW CLASSIFICATION:  01
23/5/14
0056062   EIM8211056062
  FACTORS AFFECTING WOOD HEATER EMISSIONS AND THERMAL PERFORMANCE.
  Harper. J. P.? KniSht. C. V.
  TV A, USA
  Environmental   and   Economic   Considerations  in  Enerau
Proceedinas of the 7th National Conference on Energy and   the
Phoenix, Ariz. USA   Nov 30-Dec 3 1980
  Sponsor! DOF, Wa<5hi n^ton , Df. . USA! FPAt Uachi ndt.nn •
  Source; Kuoi ua HHII Hroor aci ruDi inc. men, UOH r
  ISBN: 0-250-40468-0
  Languages: English   Conf. No.: 00534
  Descriptors: STOVES-Wood
  Identifiers!    RESIDENTIAL   HEATING!
                                                                 Utilization,
                                                                 Environment.
                                                        nr
                                                            lisa
                                                           ™ JOM
                                              TENNESSEE   VALLEY
  ENVIRONMENTAL  IMPACTS!   CARBON  MONOXIDE!
                                                 HYDROCARBONS!
 AUTHORITY!

COMPARATIVE
  EVALUATIONS!  EMISSIONS DATA?
  HEAT TRANSFER EFFICIENCY
    Classification Codes: 811? 643? 902? 451! 641? 521
                                 EFFECTIVE FUEL SIZE?  COMBUSTION EFFICIENCY?
                                       £-12

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20/5/16
828563  DOE/EV-0114
  Health  Effects  of Residential Wood Combustion!  Survey of Knowledge and
Research
  Department  of  Energy,    Washington.    DC.    Office   of   Environmental
Assessments.
  Corp. Source Codes: 052661219. 9511689
  So» an   74o
  Languages:  English
  NTIS Prices: PC A03/MF A01    Journal  Announcement:  6RAI8111J  NSA0600
  Country of Publication:  United States
  Health  and  safety  issues  related  to  residential  wood  burning  are
examined.  Current research and findings are also described*  and  research
status is assessed in terms of future health and safety reouirements.  (ERA
citation 06:002170)
  Descriptors:  tCombustion,  *Uood.  Air pollution?   Efficiency;   Health
hazards* Residential sector; Safety! Stoves
  Identifiers: ER0A/140504; NTISDE
  Section  Headings:   6F   (Biological  and Medical Sciences—Environmental
Biology);  6SG (Environmental Pollution  and  Contrul--Environraenta 1  Health
and  Safety);   68A (Environmental Pollution and Control — Air Pollution and
ControDr 97J (Enerau — Heating and Coolina Systems)
18/5/3
82-03065
  Factors Affecting Wood Hester Emissions and Thermal Performance
  Harperr J.P.; Knight. C.V.
  TVA
  Seventh Nat. Conf. Energy S Environ.   Phoenix. AZ   30 Nov.-3 Dec. 1980
  IN  'ENVIRON.  g  ECON.  CONSIDERATIONS IN ENERGY UTILIZ.   pr-.  556-564,
Publ.Yr: 1981
  ANN ARBOR SCI. PUBL. INC.. 230 COLLINGUOOD> P.O. BOX 1425. ANN AKBOR.  HI
48106
  SUMHARY LANGUAGE -  ENGLISH
  Languages: ENGLISH
  The  primary  conclusion of this report from the environmental viewpoint.
is by reducing emissions from wood heaters it is also possible  to  improve
the  efficiency  of  these devices.  Therefore.  the need exists to do both
simultaneous emissions and efficiency testing. Secondly, fuel wood size maa
be a major operating variable governing  the  efficiency  and  emission  of
residential  wood heaters.Thirdlu,  design considerations,  primarily those
affecting air flow into the combustion zone and flue gas resonance time  in
the wood heater, tend to be present in the more efficient stoves.Fourth.  a
comparative basis for evaluating different  wood  heaters.   a  performance
index.   was  proposed.   This  performance index eoualled the ratio of the
efficiency to the source severity.  This performance index could provide  a
basis  for  rank  ordering  those  wood  hectors  which are the most highly
efficient and least polluting devices.
  Descriptors: heating systems; emissions, thermodynamics; wood processing;
combustion; environmental impact
                                    S-13

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20/3/14
864227  PB81-226151
  High Altitude Testing of Residential Uood-Fired Combustion Eouipment
  (Final rept.)
  Peters* J. A. ? DeAngelis? 0. G.
  Monsanto Research Corp.? Dayton? OH. Dayton Lab.
  Corp. Source Codes: 018509001
  Sponsor: Industrial Environmental Research Lab.? Cincinnati? OH.
  Report No.J EPA-600/2-81-127
  Jan 81   48P
  See also rept. dated Mar 80> PB80-182066.
  Languages! English
  NTIS Prices: PC A03/MF A01    Journal Announcement: GRAI8124
  Country of Publication: United States
  Contract No.! EPA-68-03-2550
  To  determine  whether  emissions  from  operating  a  wood stove  at hiah
altitude differ from those at  low  altitude?   a  hiah  altitude  sampling
proaram  was  conducted  which  was  compared  to  previously collected  low
altitude data.  Emission tests were conducted in the identical model  stove
using the same type of wood with the same moisture content?  amount  of wood
charged* burning rater air flow rate?  and identical sampling intervals  and
port  locations.   Particulate emissions?  carbon monoxide?  and polycyclic
oraanic matter were analyzed.
  Descriptors: KStoves? *Air pollution? *0ak wood? Combustion?  Flue gases?
Oraanic  compounds?   Carbon monoxide?  Residential buildings?  Performance
tests
  Identifiers! *Uood burnina appliances! Particulates? NTISEPAORD
  Section Headings!  13B  (Mechanical?   Industrial?   Civil?   and  Marine
Engineering—Civil   Engineering)?    68A   (Environmental   Pollution   and
Control—Air Pollution and Control)? 97R (Fnergy— Fnvi rnnmpnt.al St.nrlipc)


 23/5/2
 0147927   EIM8304027927
   INDOOR  EXPOSURE  TO  CARBON  CONTAINING PARTICULATES AND VAPORS  IN HOMES
 UHICH USE UOOD FOR HEATING.
   McGill? K. C.? Miller? D. P.
   Uashburn Univ? Topeka? Kans? USA
   Proceedings -  Residential Wood g  Coal Combustion Specialty  Conference.
 Louisville.?_.Ky?JJSA	ilar.... 1-2. .1.982
   Spons'or": APCA? Resid Fuel Combust Comm? Pittsburgh? Pa? USA? APCA? Indoor
 Air Qua! Comm? Pittsburgh?  Pa? USA
   Source!   Publ  bs  APCA  (Spec Conf Proc SP-45)?  Pittsburgh?  Pa?  USA p
 281-295   1982
   Languages! English   Conf. No.! 01854
   Descriptors! HOUSES-Fuels
   Identifiers! PRELIMINARY  RESULTS OF TESTING METHOD?  THERMOGRPHIC METHOD?
 AMflHNT OF rAPPOW-rnuTATMTUO CIIOCTAIK-CC TU ATO- oireui TC cno rrnur unur-c-  IITTU
 DiFFERENT  UOOD  BURNING  DEVICES?   DIFFERENT  DEVICES GIVING RECOGNIZABLE
 THERMOGRAMS?  COLD METAL STOVES GIVING DETECTABLE  EMISSIONS?   FIREPLACES?
 CENTRAL FURNACE? METAL STOVES? EXPOSURE LEVELS
   Classification Codes! 402? 811? 451
                                        8-14

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 25/5/5
  1162685    EI810862685
   IMPACT  OF RESIDENTIAL  MOOD  COMBUSTION  ON  URBAN  AIR  QUALITY:  FIRST  AMBIENT
 MEASUREMENTS «
   Cooper?  John  A.?  Currie.  Lloud  A.;  Klouda.  Georae A.
   Ores  Grad Cent.  Beaverton
   Proe  Annu Meet Air  Pollut Control Assoe 73rd.   v 1,   Montreal.   due.   Jun
 22-27 1980.  Publ  bu  APCA.  Pittsburah. Pa.  1980 PBP n 80-7.  1,  13  P   CODEN!
 PRAPAP   ISSN: 0099-4081
   The impact of wood  burnina  stoves and  fireplaces on urban  air oualita  has
 been measured and  determined  to be a  significant  source of   respirsble   air
 particulates.   One half  of  the  respirable air ^articulates  in  3 residential
 area of Portland.  Oregon were found to have originated  from  wood combustion
 sources.   The impact  was determined using new low-level  counting methods to
 measure   bioaenic   carbon-14  and recently   improved chemical  mass  balance
 methods.    The  methods and  results of this studu  are discussed  as  well   as
 their implications.   34  refs.
                                                                COMBUSTION.-

  Classification Codes: 451. 811? 521? 643
23/5/28
0039924   EIM8210039924
  MEASUREMENT OF WOOD HEATER THERMAL AND EMISSIONS PERFORMANCE.
  Harper. Jerome P.. Harper. Jerome P.? Kniaht. C. V.
  TVA.  Chattanooaa.  USA
  Proceedings  -  1981 International Conference on Residential Solid Fuels.
Environmental Impacts and Solutions.   Portland. Orea. USA   Jun 1-4 1981
  Sponsor: Ores Grad Cent.  Beaverton. USA.  Northwest Environ Res Cent.  USA!
Omark Ind. Ores Saw Chain Div. USA
  Source! Publ ba Orea Grad Cent. Beaverton. USA p 210-226   1982
  Languages: English   Conf. No.! 00722
  Descriptors: UOOD-Heat Transfer
  Identifiers:  COMBUSTIONS  EMISSIONS PERFORMANCE;  WOOD  HEATER  TESTING.
HYDROCARBONS? CARBON MONOXIDE? ELECTRONIC SCALE? ELECTROCHEMISTRY
  Classification Codes: 811? 641? 804? 803? 521? 801
 23/5/6
 0147918   EIM8304027918
  MEASUREMENT TECHNIQUES AND EMISSION FACTORS FOR HAND-FIRED COALSTOVES.
  Jaasma. Dennis R.?  Macumber.  Dale  U.
  va Polatech Inst  X  State Univ. Blacksbura. USA
  Proceedings  -  Residential Wood 8  Coal Combustion Specialty Conference.
J.aujsville. Ka, USA 	Mar. .1-2.. 1982 ...
  Sponsor! APCA7 Resid Fuel Combust  Comm. Pittsburah. Pa. USA? APCA.  Indoor
 Air Qual Coma. Pittsburah. Pa.  USA
  Source:  Publ ba  APCA  (Spec Conf Proc SP-45).  Pittsburgh.   Pa.    USA   P
 129-150   1982
  Languages: Enalish   Conf. No.: 01854
  Descriptors! STOVES
  Identifiers:   RADIANT  AND CONNECTIVE COAL STOVES?   STUDY USING  DILUTION
 TUNNEL TECHNIQUES?  REAL-TIME MEASUREMENTS OF GAS-PHASE SPECIES   EMISSIONS?
 TIME-AVERAGED TOTAL PARTICULATE AND  CONDENSABLE ORGANICS EMISSIONS?  AVERAGE
 HEAT  RELEASE RATE?   AVERAGE EFFICIENCIES FOR TWO STOVES STUDIED!   SENSIBLE
 ENERGY LOSS MAJOR FACTOR IN DECREASING EFFICIENCY?   MEASUREMENT   TECHNIQUES
 FOR  SMOKE EMISSIONS? ESTIMATE OF SAMPLING  INTERVAL FOR ACCURATE EMISSIONS
 AND EFFICIENCY
  Classification Codes:  643? 524. 451
                                      8-15

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 1204489   NOR-83:05093»  EDB-83!199324
  Meeting on solid fuel  room heaters.    Testing for efficiency and scfety
  SoenJUr O.K.;  Klausen* T.
  SINTEF. Trondheim (Norway)
  186 P.   Jun 1981
  TIC Accession No.:  DE83751460
  Country of Publication! Norway
  Journal Announcement:  ERA8309
  Availability! NTIS  (US  Sales Only)*  PC A09/MF A01! 1.
  Report No.: STF-15A81020
  Note! Portions are  illegible in microfiche products
  Document Tape! Report!  Numerical data
  Languages! English
  Subfile! ERA .(Energy Research  Abstracts). NTS .(NTIS)
  Uork Location: Norway
  The  main  goal  of  the  meeting  was  to  discuss  testing  procedures*
standards?  and trends of the future for  solid  fuel  room  heaters.   The
production  and  use   of   solid fuel room heaters are incressind at a rapid
rate on a world wide  sealer   and  it  was  felt  that  it  would  be  very
beneficial  for  experts  on this  subject from various countries to meet and
exchange information  and  experience.  A further goal of the meeting was  to
start some cooperative work on an international basis in this area.  Senior
staff  members  from   research  testing   laboratories   and   governmental
institutions in U.S.r  U.K.*  West-Germany»   Denmark)  Sweden*  Finland and
Norway perticipated.  The  report includes!  A list of attendees*  minutes of
the  meeting*   notes  taken  during   the  meeting*   correspondence*  and
papers/notes presented at the meeting.  The technics! papers/notes  include
the  following  topics!   testing  of  solid  fuel  room heaters*  measuring
techniaues and testing methods* safety testing* use of biomsss* cooperative
programs*  and a paper on energy  conservation in U.K.  in relation to solid
fuel room heaters. 37 drawings* 11 tables.
  Descriptors!    *SPACE    HEATERS	THERMAL  EFFICIENCY!   *UOOD  BURNING
APPLIANCES	MEETINGS*   *UOOD BURNING  APPLIANCES	PERFORMANCE  TESTING*
*UOOD  BURNING APPLIANCES	SAFETY !   AIR POLLUTION*  CERTIFICATION!  FIRE
HAZARDS* FIREPLACES*  SOLID FUELS* STANDARDS* STOVES* WOOD BURNING FURNACES
  Special Terms: APPLIANCES* DOCUMENT TYPES* EFFICIENCY!  FUELS!  FURNACES!
HAZARDS* HEATERS* POLLUTIONS TESTING*  UOOD BURNING APPLIANCES
  Class Codes: 090400*.  140504* 299003 ! Z99X
                                      8-16

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20/5/9
945006  DE82005501
  National Estimates of Residential Firewood and Air Pollution Emissions
  Lipfert* F. U.  i Dungan* J. L.
  Brookhaven National Lab.* Upton* NY.
  Corp. Source Codes: 004545000* 0936000
  Sponsor: Department of Energa* Washington* DC.
  Report No.: BNL-30367* CONF-811212-9
  1981   lOp
  International conference on alternative energa sources* Miami Beach*  FL»
USA. 14 Dec 1981.
  Languages: English   Document Tape: Conference proceeding
  NTIS Prices: PC A02/MF A01    Journal Announcement: GRAI8304! NSA0700
  Countra of Publication: United States
  Contract No.: AC02-76CH00016
  Estimates are presented for  the  distribution  and  ouantitvi  of   recent
(1978-1979)   use of residential firewood in the United States*  based on a
correlation of survey data from 64 New  Endland  counties.   The  available
survea  data  from  other  states  are  in  agreement with the relationship
derived from New England*  no constraints due to wood suppla are  apparent.
This  relationship indicates that the highest densita of wood usage (Kg/hs)
occurs in urban areas* thus exacerbation of urban air Quality problems is a
matter of some concern.   The data presentation used  here  dives  an  upper
limit  to  this  densita  of  firewood  usage  which  will  allow realistic
estimates of air oualita impact to be made.  (ERA citation 07:044632)
  Descriptors: *Uood*  *Uood burning furnaces*  *Fireplaces *  Distribution*
Fuels*  Usa* Correlations* North atlantic region* Resources* Combustion* Air
pollution* Environmental impacts
  Identifiers: ERDA/500200*  NTISDE
  Section  Headings:    13B  (Mechanical*   Industrial*    Civil*  and Marine
Engineering—Civil  Engineering) i     68A   (Environmental   Pollution   and
Control—Air Pollution and Control)
                                      8-17

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 X1083656   EDB-83S078526
'  Factors affectina wood heater emissions and thermal performance
   Environment and economical considerations in eneraa utilities
   Harper* J.P.!  Kniaht. C.V.
   TVA* USA
   556-564 P.   1980
   7. national conference on eneraa and the environment   Phoenix*  AZ*  USA
 30 Nov 1980
   Countra of Publications United States
   Publ! Ann Arbor Sci Publ Inc..Ann Arbor* MI*
   Journal Announcement: EDB8302
   Report No.: CONF-801171-
   Document Tape! Analytic of a Book* Conference literature* Numerical data
   Languages: English
   Work Location: United States
   The objective is to identifa those factors  related to stove operation and
 design which maa significantly affect the emissions and the  efficiency  of
 some  residential  wood  heaters commonly used in TVA Region.  The analysis
 presented shows that emissions  and  efficiency  are  interrelated  factors
 governing the overall performance of wood heaters!  such that reductions in
 emissions*  for example carbon monoxide and total hydrocarbons*   typically
 result  in an increase  in the  efficiency of eight wood heaters tested.  The
 paper not only presents the data  obtained  from  the  testing*   but   also
 proposes  a  performance index for the comparison of different wood heaters
 on  the basis of both efficiency and emissions considerations. 7  refs.


 .1070992   ERA-08-.019958,  EDB-83:065861
'  Overview   of  R  and  D  programs being  coordinated  by  the  inter-governmental
 wood combustion  research group.    Paper  81.8.3
   Osborne, M.C.
   US EPA,  Research  Triangle  Park*  NC»  USA
   Proc..  Annu.  Meet.* Air  Pollut.  Control  Assoc.   (United  Ststes)     VP P.
 1981   Coden: PRAPA
   74.     annual   meeting    of   the   Air   Pollution   Control   Association
 Philadelphia. PA, USA   21  Jun  1981
   Journal  Announcement:  EDB8302
   Report  No.: CONF-810631-
   Document Tape:  Journal  Article?  Conference  literature
   Languages!  English
   Uork Location:  United States
   A  studa  on the  emissions  from residential  wood  combustion was   conducted.
 It  was   found   that  hiah  concentrations  of  carbon  monoxide arid  particulatt?
 are  found  in wood smoke but  also concluded  that  socallcd  polacuclic  organic
 matter (POM)   is  a  more hazardous  pollutant  which  is  released  from  airtight
 wood  stoves.    A   survey   of programs for  research  of  the  hazards  from  air
 pollutants is given.  6  refs.
   Descriptors:  *COMBUSTION	RESEARCH PROGRAMS?  *UOOD	COMBUSTION?  *WOOD
 BURNING APPLIANCES	AIR  POLLUTION  ?  AIR  QUALITY!   CATALYTIC   CONVERTERS?
 POLYCYCLIC AROMATIC HYDROCARBONS!  RESIDENTIAL  SECTOR
   Special  Terms!  APPLIANCES!  AROMATICS?   CHEMICAL  REACTIONS?   ENVIRONMENTAL
 QUALITY?  EQUIPMENT? HYDROCARBONS!  ORGANIC  COMPOUNDS!  OXIDATION!   POLLUTION?
 POLLUTION  CONTROL EQUIPMENT?  THERMOCHEMICAL  PROCESSES
   Class Codes:  090400*!  500200!  140504
                                       8-18

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29/5/30

 1020244   EDB-83.'015107
  Overview of emissions from wood combustion
  Wood!    an  alternate  energy  resource  for  application  industry  and
institutions.   Conference proceedings and manual
  Lira. K.J.?  Lips. H.I.; Kohl» J.?  Pulaeki. E.?  Rao. D.P.?  TriPlett. B.
(eds. )
  Acurex Corp.F Mountain View? CA
  61-74 P.   1981
  industry  and  institutions    Uinston-Salem.  NC.  USA    7  Apr  1981
  /^Country of  Publication.*  United  States
    Publ! North Carolina  State University.Raleigh.  North  Carolina.
    Journal Announcement! EDB8301
    Report  No.! CONF-8104173-
    Document Type!  Analytic  of a  Book?  Conference literature
    Languages:  Endlish
    Uork  Location!  United States
    Increasing  combustion of wood  for residential and industrial  purposes has
  raised  many   environmental   concerns.    This   paper attempts to  assess and
  correlate scattered research results  on  the emissions from  wood combustion.
  The major emissions are particulate matter. CO.  and hydrocarbons>   some of
  which  are  potentially  carcinogenic.    Research  results   show  negligible
  amounts of SO/sub 2/   and  low amounts of NO/sub :•:/   emissions.    Parameters
  affeetina emissions appear to be  combustion design, firind  rate,  and excess
  air   level.    In  general  industrial   users   have  lower   emissions  than
  residential users because  of better combustion  conditions.   The problems of
  the  residential   emissions   are   aggravated  bu the localized  and  seasonal
  concentration of  emissions.   Significant data  d3PS   exist.    but   the  most
  urgent   area   needind  investigation  is  the amount  and kinds of potentially
  carcinogenic  matter being  emitted.  (CKK)
    Descriptors! *UOOD  FUELS	COMBUSTION?   *WOOD FUELS	POLLUTANTS ?   AIR
  POLLUTION? CARBON MONOXIDE?  CARCINOGENS?  HYDROCARBONS?  INDUSTRIAL PLANTS?
  PARTICLES? RESIDENTIAL BUILDINGS? WOOD BURNING  FURNACES
    Special Terms!  APPLIANCES?  BUILDINGS?  CARBON COMPOUNDS?  CARBON OXIDES?
  CHALCOGENIDES? CHEMICAL REACTIONS?  ENERGY  SOURCES?  FUELS?  FURNACES? ORGANIC
  COMPOUNDS? OXIDATION? OXIDES? OXYGEN  COMPOUNDS?  POLLUTION?  THERMOCHEMICAL
  PROCESSES? WOOD BURNING APPLIANCES
    Class Codes! 140504*? 090400?  S00100
                                         8-19

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   20/5/19

     Preliminara  Characterization  of  Emissions  from blood-fired Residential
   Combustion Eauipment
     DeAnSelis,  D.  G.  ! Ruffin*  D. S.  !  Reznik*  R. B.
     Honsanto Research Corp.* Dauton*  OH.
     Corp. Source Codes! 018509000
     Sponsor: Industrial Environmental Research Lab.*  Research Tnansle Park,
   NC.
     Report No.: EPA-600/7-80-040
     Mar 80   159p
     Languages:  English
     NTTS Pl-i r»«»«i ? OP AAO/MCA/M      I	'  »           •'	•	• -
     country or  Publication:  United States
     Contract No.:  EPA-68-02-1874i  EPA-ROAP-21AXM-071
     This  report  describes  a study conducted to Quantify criteria pollutants
   and characterize other atmospheric  emissions   from  wood-fired  residential
   combustion  eauipment.   Flue  Sases   were  sampled  from   a zero clearance
   fireplace and two  air-tiaht   cast   iron   stoves  (baffled   and  nonbaffled
   design).   Four   wood  tapes   were   tested*   oak-seasoned   and areen-  and
   pine-seasoned  and   areen.    Samples   were   snalaaed   for   F-orticulatest
   condensable  oraanics*   nitroaen oxides*   carbon monoxide*  sulfur oxides*
   organic species*  and individual  elements.
     Descriptors!  *Fireplaces * SStoves!  *nir  pollution*  *0ak  wood! *Pine wood*
   Combustion* Nitrogen oxides!   Carbon  monoxide*  Sulfur oxides*  Flue asses!
   Ordanic compounds*  Performance tests* Residential buildings
     Identifiers!  *Uood burning  appliances? Particulates* NTISEPAORD
     Section  Headings!   13B  (Mechanical*    Industrial*   Civil*  and Marine
   Enaineerina--Civil   Enaineerina) »    68A    (Environmental    Pollution   and
   Control--Air  Pollution and Control)*  97R  (Enor3y—Environmental Studies)
 23/5/13
 0147910    EIM8304027910
   PROCEEDINGS  -  RESIDENTIAL  WOOD  I  COAL  COMBUSTION SPECIALTY CONFERENCE.
   Frederick* Edward  R.   (Ed.  )
   APCA,  Pittsburgh*  Pa,  USA
   Proceedings  -  Residential  Mood  S   Coal  Combustion Specialty Conference.
J^ou^sj/ille*  Ka,  USA    Mar 1-2  1982
  "Sponsor!  APCA* Resid  Fuel  Combust Comm*  Pittsburgh* Pa*  USA*  APCA*  Indoor
 Air dual Comm* Pittsburgh*  Pa*  USA
   Source!   Publ  ba APCA  (Spec  Conf  Proc  SP-45)*   Pittsburgh*  Pa*   USA 300P
 1982
   Lanauaaes! English   Conf.  No.!  01854
   Descriptors! HOUSES-Fuels
   Identifiers!   WOOD BURNING  STOVES!   COAL BURNING STOVES*   DOMESTIC STOVE
 PERFORMANCE FACTORS  AND   ANALYSES*    OUTDOOR  AIR  POLLUTION*   INDOOR  AIR
 POLLUTIONS   EUROPEAN ACTIVITES  IN  SOLID  FUEL FIRED HEATING!   EMISSIONS FROM
 RESIDENTIAL COAL STOVES!  PREDICTION  OF  PULMONARY  TOXICITY   OF  RESPIRABLE
 COMBUSTION PRODUCTS! SPACE  HEATING
   Classification Codes!  402!  811!  524* 521! 451!  461
                                      8-20

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25/5/2
 1366960   EI8304026960
  PROCEEDINGS  -  RESIDENTIAL WOOD g  COAL COMBUSTION SPECIALTY CONFERENCEi
1982.
  Frederick* Edward R.  (Ed. )
  APCAf Pittsburgh, Pa, USA
  Proc - Resid Wood X Coal Combust Spec Conf* Louisville* Ka» USA*  Mar 1-2
1982 Publ ba APCA  (Spec Conf Proe SP-45)* Pittsburgh. Par USA* 1982 300p
  Languages! ENGLISH
  The  volume  contains  18 papers and one abstract of a paper presented at
the meeting.   Subjects  covered  include  techniaues  for  achieving  more
complete  combustion  in  wood   stoves*   emission  and thermal performance
napping*  effects  of  firinS  rate  and  design  on  domestic  wood  stove
performance*  European activities in solid fuel fired heating*  measurement
techniaues,   characterization of emissions from  residential  coal  stoves*
anbient  impact of residential  wood combustion*  national assessment of air
Quality impacts* impact of residential wood combustion appliances on indoor
air oualitu*  prediction of pulmonary  toxicitu  of  respirable  combustion
products from residential  wood  and coal stoves* and others.    Technical and
professional papers from this conference are indexed  with  the  conference
code  no.   01854 in the Ei Enaineerina Meetinds (TM)  database produced ba
Engineering  Information* Inc.
  Descriptors! *HOUSES-*FuelsS   UOOD-FuelsS  COAL*   AIR POLLUTION-Analusis»
STOVES* HEATING
  Identifiers?   WOOD  BURNING   STOVES*   COAL  BURNING STOVES?  INDOOR AIR
POLLUTIONS HEALTH EFFECTS* EIREV
  Classification Codes: 402* 811* 524; 521S 451* 461
23/5/33

°°PARTICULATE  EMISSIONS  FROM NEW LOW EMISSION WOOD STOVE DESIGNS MEASURED
BY EPA METHOD V.
  KowalC2*k» John F.S Bosserman. Peter B.S Tombleson* Barbara J.
  Orea Dep of Environ Qual* USA
  Proceedings -  1981 International Conference on Residential Solid  Fuels*
Environmental Impacts and Solutions.   Portland. Orea* USA   Jun  1-4 1981
  Sponsor! Ores Grsd Cent, Beaverton, USAS Northwest Environ Res  Cent. USA,
Omark  Ind, Ores Saw Chain Div, USA
  Source! Publ b* Orea Grad Cent* Beaverton, USA p 54    1982
  Languages! English   Conf.  No.: 00722
  Descriptors! WOOD-Combustion
  Identifiers! WOOD STOVE DESIGNS PARTICULATE EMISSIONS?  STACK  FILTERS   AIR
POLLUTIONS   FOSSIL  FUELSS   THERMOSTATSS    DAMPER   CONTROLS    MOISTURE
DETERMINATION* CREOSOTE
  Classification Codes!  811S  521S 451* 532S  9445 732
                                     8-21

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20/5/13
867297  PB81-248155
  Proceedings of the Conference on Uood Combustion Environmental  Assessment
Held at New Orleans in February 1981
  (Rept. for Oct 80-Jun 81)
  Auer« Franklin A.
  Research Triangle Inst.t Research Triangle Park* NC>
  Corp. Source Codes! 045968000
  Sponsor! Industrial Environmental Research Lab.»  Research Triangle  Park*
NC.
  Report No.5 EPA-600/9-81/029» IERL-RTP-1235
  1981   330p
  Languages: English   Document Tape! Conference proceeding
  NTIS Prices! PC A15/MF A01    Journal Announcement! GRAI8125
  Country of Publication! United States
  Contract No.! EPA-68-02-3170
  These proceedings document presentations at the conference. The objective
of the conference  uas  to  disseminate   recent   research   and   development
findings  on  the  subject  of residential wood combustion.  The  conference
sessions  dealt  with!   (1)   and  overviw  of  environmental    assessment
activities* (2) specific emissions and heating efficiency  assessments*  (3)
PH14ainn.!«•.  ^Meetings*   Rcsidental
buildings* Combustion products* Stoves* Assessments* Catalysts*   Standards*
Polycyclic compounds
  Identifiers!  NTISEPAORD
  Section  Headings!   13S  (Mechanical*   Industrial*   Civil*   and Marine
Engineering—Civil   Engineering)*   68A*    (Environmental    Pollution   and
Control—Air Pollution and Control)
 23/5/26
 0039926   EIM8210039926
   POM  EMISSIONS  FROM  RESIDENTIAL UOODBURNING!  AN ENVIRONMENTAL ASSESSMENT.
   Peters*  James  A.
   Monsanto Rpq Corp,  Han+.nn.  flhin.  IIRA
   r roceeoinas  -  iyai  iril.el-ri3tlOii.ji  uomeltiict un rveiiueu i,i>;i aonu rueis.
 Environmental Impacts and Solutions.    Portland* Oreg*  USA   Jun 1-4 1981
   Sponsor! Oreg  Grad  Cent*  Beaverton*  USA*  Northwest Environ Res Cent*  USA*
 Omark  Ind* Oreg  Saw Chain Div*  USA
   Source!  Publ by  Oreg Grad Cent*  Beaverton*  USA i» 267-288   1982
   Languages!  English   Conf.  No.!  00722
   Descriptors! UOOD-Combustiori
   Identifiers! HOME HEATINGS  ORGANIC  SPECIES*  EMISSION  INVENTORY* FIREPLACE
 )  COAL SMOKE? CARCINOGENS?  PARTICULATE MATTER
   Classification Codes!  811*  521*  643*  804*  461
                                     8-22

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20/5/8
0983614  DE83007784
  Results of Laboratory Tests on Wood-Stove Emissions and Efficiencs
  Hubble7 B. R. ) Harkness* J. B. L.
  Argonne National Lab.* IL.
  Corp. Source Codes: 001960000$ 0448000
  Sponsor! Department of Energy* Washington! DC.
  Report No.! CONF-810295-1
  1981   19p
  International • trade show and wood heating seminar* New Orleans* LA*  USA*
21 Feb 1981* Portions are illegible in microfiche products.
  Languages: English   Document Type I  Conference proceeding
  NTIS Prices! PC A02/MF A01    Journal Announcement: GRAI8316! NSA0800
  Country of Publication: United States
  Contract No..* U-31-109-EN6-38
  Air-tight*  wood-burning stoves were operated in s manner consistent with
typical  residential heating reauirements in order to determine psrticulate
and carbon  monoxide  emissions  and  creosote  build-up.   Test  data  are
presented as functions of burn-rates and stove efficiencies.  The principal
conclusions are that emissions from  the  stove  used  in  this  studu  are
related  to  log-size  and  wood  burn-rate  and  that  CO  and ^articulate
emissions and creosote build-up increased  uith  increasing  efficienca  of
operation.  Therefore*  future environmental testing should be conducted at
typical stove operating conditions*  low burn-rates with  large  logs.   In
addition*   heat-loss  calculations  show a trade-off between sensible heat
loss and CO-fuel  heat loss over the  range  of  burn-rates  studied.   This
indicates that*  if further improvements in stove efficiencies are desired*
improvements in stove combustion efficiency are needed.  This also decreases
stove emissions.  (ERA citation 08:020895)
  Descriptors!  *Uood burning furnaces*   Particulates!    Carbon  monoxide*
Creosote* Flue gas* Efficiency*  Heat  losses*  Combustion*  Carbon dioxide*
Temperature distribution* Experimental data
  Identifiers: ERDA/320101! ERDA/299003! ERDA/140504! NTISDE
  Section Headings: 21D (Propulsion and Fuels—Fuels)* 97K (Energy—Fuels)*
68A (Environmental Pollution and Control--Air Pollution and Control)
23/5/16
0039978   EIM8210039978
  REGULATORY  OPTIONS  FOR CONTROLLING EMISSIONS FROM COMBUSTION OF MOOD IN
RESIDENTIAL APPLICATIONS.
  Mors* Terra A.! Blair* Terrence T.i  Cole* Robert H.
  Dalton Dal ton Newport* Cleveland* Ohio* USA
  Proceedings -  1981 International Conference on Residential Solid  Fuels*
Environmental Impacts and Solutions.   Portland* Ored* USA   Jun 1-4 1981
  Sponsor! Ores Grad Cent* Beaverton*  USA*  Northwest Environ Res Cent*  USA*
Omark  Ind* Ores Saw Chain Div* USA
  Source: Publ bu Dreg Grad Cent* Beaverton* USA p 1253-1271   1982
  Languages: English   Conf. No.! 00722
  Descriptors! UOOD-Combustion
  Identifiers:  PARTICULATE EMISSIONS!  SPACE HEATING.  AIR QUALITY*  STOVE
WASTE!  CHIMNEY CLEANER!   POLLUTION  CONTROL!   REGULATIONS!   COMMON  LAW
DOCTRINES
.  Classification Codes: 811! 321! 451! 902
                                    8-23

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 / 167471   83-006131
V RESIDENTIAL UOOD S COAL COMBUSTION  .
  APCA RESIDENTIAL UOOD i COAL COMBUSTION SYM PROCEEDINGS* LOUISVILLE*   KY»
 MAR  1-2. 82.  (308)
  CONFERENCE  PROCEEDINGS  ON  METHODS  OF  UOOD  AND  COAL  COMBUSTION   IN
 HOUSEHOLDS  AND  EMISSION  MONITORING  ARE  PRESENTED.    TOPICS   DISCUSSED
 INCLUDE:   IMPROVED  COMBUSTION   IN   UOOD  STOVES*   EMISSION   AND  THERMAL
 PERFORMANCE  MAPPING  FOR  AN  UNBAFFLED*   AIRTIGHT  UOOD  APPLIANCE AND A
 BOX-TYPE CATALYTIC APPLIANCE? EFFECTS OF FIRING RATE AND  DESIGN ON DOMESTIC
 UOOD STOVE  PERFORMANCE*   SOLID  FUEL-FIRED  HEATING*    RESIDENTIAL  STOVE
 EMISSIONS  FROM  COAL  AND  OTHER ALTERNATIVE FUEL COMBUSTION*  MEASUREMENT
 TECHNIQUES AND EMISSION FACTORS FOR HAND-FIRED STOVES?  AN OUTDOOR EXPOSURE
 CHAMBER TO STUDY UOOD COMBUSTION  EMISSIONS UNDER  NATURAL  CONDITIONS}  IMPACT
 OF RESIDENTIAL UOOD COMBUSTION APPLIANCES ON  INDOOR AIR QUALITY*  AND  INDOOR
 EXPOSURE  TO  CARBON-CONTAINING   PARTICULATES AND VAPORS  IN HOMES THAT BURN
 UOOD FOR HEATING.  (NUMEROUS DIAGRAMS* GRAPHS, REFERENCES* TABLES)
  DESCRIPTORS: *CONF PROCEEDINGS  * *UOOD ENERGY »  *COAL  USAGE*   DOMESTIC »
 *MONITORING* ENV-AIR » *AIR POLLUTION* INDOOR } *HEATING  SYSTEMS.  DOMESTIC
 »  *MATHEMATIC MODELS-AIR  *  *SPACE   HEATING*   DOMESTIC   »    COMBUSTION  }
 PARTICULATES  * FIREUOOD  *  PATHOLOGY*  HUMAN  *  AMBIENT AIR  » KEROSENE
  REVIEU CLASSIFICATION: 01

 21/5/2
  165475   *83-004207
  INDOOR AIR  POLLUTION AND SOME SOLUTIONS*
  MORRILL ELIZABETH
  UOOD N ENERGY* DEC 82* V2> N12. P30 <4)


 yiNSULATING THEIR HOUSES,   RESEARCHERs"HAVE'DISCOVERED THAT"suCH"*ACTIVITIES
  SERVE  TO  SEAL  IN  POTENTIALLY  DANGEROUS POLLUTANTS THAT NORMALLY ESCAPE
  THROUGH WINDOU AND DOOR CRACKS.  ONE FREQUENT SOURCE OF INDOOR AIR POLLUTION
  IS THE FIREPLACE*  ALONG WITH UOOD AND COAL-BURNING HEATERS.    PARTICULATES
  AND  CARBON  MONOXIDE ARE EMITTED BY THESE SYSTEMS.  KEROSENE HEATERS,   GAS
  APPLIANCES,   AND INSULATING MATERIALS  ARE  ALSO  CULPRITS  OF   INDOOR  AIR
  POLLUTION.  AIR CLEANING APPLIANCES,   INCREASED VENTILATION,  AND THE USE OF
  AIR-TO-AIR HEAT EXCHANGERS CAN HELP PURIFY INDOOR  AIR.    (2  DIAGRAMS*   1
  TABLE)
    DESCRIPTORS:    *AIR  POLLUTION*    INDOOR ;  *HEATING SYSTEMS.   DOMESTIC ;
  *INSULATION»  COLD  »   *RADON  *    XRESPIRABLE  DUST  i   *FORMALDEHYDE  *
  *VENTILATION  »   *HEAT  EXCHANGERS >   UEATHERSTRIPPING »  GAS APPLIANCES *
  KEROSENE
    REVIEU CLASSIFICATION:  01
                                      8-24

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 1130258   EDB-83:i25133
  Results of 3 forty-home indoor-sir-pollutant monitoring study
  Hawthorne* A.R.!  Gammase* R.B.!  Dudneti* C.S.!  Uomack*  D.R.!   Morris*
S.A.!  Uestley* R.R.!  White* D.A.!   Gupta, K.C.
  Oak Ridae National Lab.* TN (USA)
  14 P.   1983
  TIC Accession No.! DE83014138
  76.  annual meeting of the Air Pollution Control  Association    Atlanta?
GA,  USA   19 Jun 1983
  Country of Publication! United States
  Journal Announcement: ERA8307
  Availabilitu: NTIS» PC A02/MF A01! 1.
  Report No.! CONF-830617-8
  Note! Portions are illegible in microfiche products
  Document Tape! Report? Conference literature
  Languages! English
  Subfile: ERA .(Energy Research Abstracts)! NTS .(NTIS)
  Work Location: United States
  Contract No.! U-7405-ENG-26
  A   study  was  conducted  in  40 homes in the areas of Oak Ridae and west
Knoxville* Tennessee. Concentrations of CO/sub x/> NO/sub ::/» particulates*
formaldehyde*  and radon*  as well as selected volatile organic  compounds*
were  Quantified.   In addition*  information was collected on air exchange
rates*  meteorological conditions*  and structural and  consumer  products.
This paper summarises some of the results and provides specific examples of
increased  indoor  concentrations  of  pollutants due to the operation of a
kerosene space heater* a sas ranse*   and a wood/coal stove.  Results showed
formaldehyde  levels  freouently  exceeded  0.1 ppM!  wore highest in newer
homes*  and fluctuate diurnalla and seasonally.   Radon  levels  freauentlu
exceeded  3  pCi/L  and  correlated  strondly with house location.  Organic
pollutant levels were at least an order of magnitude  higher  indoors  than
outdoors. Combustion sources (especially unvented)  significantly increased
levels of CO/sub x/» NO/sub x/»  and particulates.  Air exchange rates were
increased  nearly two-fold by operation of the HVAC central air circulation
fan.
  Descriptors! *CARBON MONOXIDE	ECOLOGICAL CONCENTRATION* *FORMALDEHYDE-
	ECOLOGICAL   CONCENTRATION*    tHOUSES	AIR    QUALITY*     *NITROGEN
OXIDES	ECOLOGICAL   CONCENTRATION?    *ORGANIC   COMPOUNDS	ECOLOGICAL
CONCENTRATION! *PARTICULATES	ECOLOGICAL CONCENTRATION! *RADON	ECOLOG-
ICAL CONCENTRATION ! COAL! CONSUMER PRODUCTS!  ELECTRIC APPLIANCES!  ENERGY
CONSERVATION* GAS APPLIANCES! INDOOR AIR POLLUTION! KEROSENE)  METEOROLOGY!
NATURAL GAS! SPACE HEATERS! TENNESSEE! VENTILATION! VOLATILE MATTER!  WOOD!
WOOD BURNING APPLIANCES
  Special Terms! AIR POLLUTION! ALDEHYDES!  APPLIANCES!  BUILDINGS!  CARBON
COMPOUNDS? CARBON OXIDES! CARBONACEOUS MATERIALS! CHALCOGENIDES)  ELEMENTS!
ENERGY SOURCES! ENVIRONMENTAL QUALITY!  FEDERAL REGION IV!  FLUIDS*  FOSSIL
FUELS! FUEL GAS* FUELS! GAS FUELS! GASES! HEATERS! LIQUID FUELS! MATERIALS!
MATTER! NITROGEN COMPOUNDS!  NONMETALS!  NORTH AMERICA!  ORGANIC COMPOUNDS!
OXIDES! OXYGEN COMPOUNDS! PARTICLES!  PETROLEUM PRODUCTS!  POLLUTION!  RARE
GASES! RESIDENTIAL BUILDINGS! USA
                                      8- 25

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 /1137429   EDB-83!132305
    A simple and effective technique for testins wood stove performance
    Barnett. S.
    Wood Energa (United States)    II!12   54-57 P.   Dec 1982   Coden! WOEND
    Journal Announcement:  EDB8307
    Document Type! Journal Article
    Languages:  English
    Work Location: United  States
    Simple  and  effective  technioues  for  testing  the performance of wood
  stoves is discussed.   The two major sampling  technioues  are  psrticulate
  emissions measurement and gas measurements.
    Descriptors!      *STOVES	PERFORMANCE    TESTING!     XUOOD    BURNING
  APPLIANCES	PERFORMANCE TESTING i  EFFICIENCY! GAS ANALYSIS? HEAT TRANSFER
  ?  MEASURING METHODS! PARTICULATES
    Special Terms! APPLIANCES!  ENERGY  TRANSFER! PARTICLES?  TESTING
    Class Codes! 320100*
  1020317    EDB-83!015180
/ Retrospective  search  on wood  and  wood waste burning eouipment
   144 P.    1980
   Countra of  Publication: Ireland
   Pubi:  Biomass  Conversion Technical  Information  Service.Dublin.  Ireland.
   Journal Announcement: EDB8301
   Document Tape!  Book?  Bibliographa/review article
   Languages:  English
   Work Location:  Ireland
   This   literature  survea  covers  the  period   1963  to  date  including
 residential and  commercial wood stoves.   fuels.    mixed  fuel  combustion.
 emissions, wood  waste combustion, general eauipment. and miscollaneous.
   Descriptors:  *STOVES	BIBLIOGRAPHIES? *UOOD BURNING APPLIANCES	BIBL-
 IOGRAPHIES?      *UOOD      BURNING     FURNACES	BIBLIOGRAPHIES!     *UOOD
 FUELS	BIBLIOGRAPHIES  !   COMBUSTION!   COMMERCIAL  SECTOR!   EQUIPMENTS
 RESIDENTIAL SECTOR. WOOD  WASTES
   Special Terms:   APPLIANCES.  CHEMICAL REACTIONS!  DOCUMENT TYPES!  ENERGY
 SOURCES!  FUELS?  FURNACES? OXIDATIONS.  SOLID WASTES? THERMOCHEMICAL PROCESSES
 ? WASTES? WOOD BURNING APPLIANCES
   Class Codes:  140504*? 090400! 299003



 23/5/37
 0013534   EIM8207013534
   RESIDENTIAL WOOD FIRED FURNACES!  RESULTS FROM A DEMONSTRATION OF ADVANCED
 SYSTEMS»
   Brandon. R, J.
   Inst of Man S Resour. Charlottetown. Prince Edward Isl. Can
   Samposium Papers - Energy  from Biomass and Wastes 5.    Lake Buena Vista.
 Fla. USA   Jan 26-30 1981
   Sponsor: Inst of Gas Technol. Chicago. 111. USA
   Source!  Samposium Papers -  Energa from Biomass and Wastes 5.   Publ   ba
 Inst of Gas Technol. Chicago. 111.  USA P 175-202   1981
   CODEN:  EBWADU
   Languages!  English   Conf. No.! 00130
   Descriptors! FURNACES. SPACE HEATING-Fuels
   Identifiers:   THERMAL PERFORMANCE?   COMBUSTION SYSTEMS?  EMISSIONS?  WOOD
 WASTE UTILIZATION? BIOMASS COMBUSTION! ENERGY DENSITY! CREOSOTE FORMATION
   Classification Codes: 643! 811? 524? 521? 901
                                       8-26

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18/5/3
  99125287    CA:  99(16)1252872    CONFERENCE  PROCEEDING
  Thermal performance testina of residential solid fuel heaters
  AUTHOR(S):  Sheltonr Jaa U.
  LOCATION:  Shelton Energy Res.r Santa Fe»  NM.  87502.  USA
  Solutions  EDITOR:  Cooper.  John A.  (Ed)"  Malek.  Dorothu  (Ed)"    DATE!   1982
  PAGES:    1117-59  CODEN:   SOEHAA  LANGUAGE:   Enaush  HEETING  DATE:   sioooo
  PUBLISHER:  Orea. Brad.  Cent..  Beaverton.  Orea
    SECTION:
  CA151018 Fossil Fuels.  Derivatives,  and Related  Products
  CA152XXX Electrochemical. Radiational. and Thermal Enera'j Technology
    IDENTIFIERS:   standardization evaluation residential heater.   solid  fuel
  residential  heater  evaluation.   wood coal residential heator evaluation.
  combustion  residential  wood coal evaluation
    DESCRIPTORS:
  Mood...
      combustion  of.  evaluation of residential heaters for
  Air pollution.•.
      emissions.   from residential wood or cool heaters.  evaluation criteria
      including
  Creosote••.
      emissions  of.    from  wood  or  coel  residential heaters.  evaluation
      criteria includina
  Heat transfer...
      in  residual wood or coal heaters, evaluation criteria includina
  Combustion. . .
      of  coal  and wood, evaluation of residential  heaters for
  Standardization...
      of  residential wood or coal heaters, criteria for
  Heatina  systems and Heaters...
      residential, for wood and  coal, evaluation of
   23/5/11
   0147912    EIM8304027912
     TECHNIQUES  FOR  ACHIEVING  MORE  COMPLETE  COMBUSTION  IN  UOOD  STOVES.
     Allen.  John M.i  Piispanen.  William  H.
     Battelle. Columbus  Lab. Ohio.  USA
     Proceedings  -   Residential  Wood  X   Coal  Combustion Specialty  Conference.
   Louisville. Ky. USA    Mar  1-2  1982
     Spo'nsorT-ftPCA.  Resid Fuel  Combust Comm. Pittsburgh. Pa.  USA. APCA.  Indoor
   Air  dual  Comm.  Pittsburah.  Pa. USA
     Source:  Publ  ba  APCA (Spec  Conf Proc SP-45).  Pittsburah.   Pa.   USA  p  2-21
   1982
     Lanauaaes:  Enalish   Conf.  No.! 01854
     Descriptors:  STOVES
     Identifiers!  SECONDARY COMBUSTION!   REDUCTION OF AIR  POLLUTION  EMISSIONS*
   HIGH BURNING  RATES?   SMALL  AIR-TIGHT  BOX  STOVE   OPERATING  AT  LOU  BURNING
   RATES; EXPERIMENTAL STUDY?  DESIGN OF  SECONARY AIR  INLET  SYSTEM;   DUALITY  OF
   SECONDARY   AIR  ADMITTED;    THERMAL   INSULATION OF  STOVE;    SIMULTANEOUS
   MONITORING  OF CARBON  MONOXIDE  AND TOTAL HYDROCARBON; AIR IN-LEAKAGE THROUGH
   JOINTS
     Classification Codes: 6438 Silt 521
                                    8-27

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23/3/8

01JoSDSTOv"HD";4GS2AND5CONTROL MODE AS DETERMINANTS OF EFFICIENCY, CREOSOTE
ACCUMULATION, AND CONDENSABLE PARTICIPATE EMISSIONS.
  Barnett, Stockton 6.

                              Uood ,  Coal Co.bu.tion SPecialta Conference.

                                    Comm, Pittsburgh, Pa, USA? APCA,  Indoor

                                       SP-45>, Pittsburah, P.,  USA P  70-88
1982
  Languages: English   Conf. No.: 01854
              TKIPRFASES; EFFECT  OF  WOOD  PIECE  SIZE,   BURN  RATE,
               S1!S?E ACCUMULATION  IN FLUEPIPES;   TEST  HOUSES  IN NEW YORK
 AND  OHI08  EXPERIMENTAL STUDY  OF WOOD  STOVE  EFFICIENCY
   Classification  Codes: 643$  811?  5218  451


 23/5/29
 0039923   EIM8210039923
   WOOD COMBUSTION EMISSIONS AT  ELEVATED  ALTITUDES.
   Peters, J.  A.)  Huahes, T. U.»  DeAnaelis,  D.  G.
   Monsanto Res Corp, Dayton, Ohio, USA
   Proceedings  -  1981 International  Conference on Residential Solid  Fuels,
 Fnvi rnnmont.al Tmeaote *r.rt «!n 1 ii» i n-^r .    o~~ti-.r.A.  n--.-.  IICA    i..~  i_«  1001

   Sponsor: Ores Grad Cent,  Beaverton, USA!  Northwest Environ  Res  Cent,  USA!
 Omark  Ind, Orea Ssu  Chain  Div,  USA
   Source:  Publ ba Ores Grad Cent,  Beaverton,  USA  p 199-209    1982
   Lanauaaes:  Enalish   Conf.  No.:  00722
   Descriptors: UOOD-Combustion
   Identifiers: ELEVATED ALTITUDES?  HOME HEATING;  POLLUTANT  EMISSIONS;   DATA
 COLLECTION;  AIRTIGHT STOVE; BOILER PLATE;   FILTERS;   SEASONED OAK;  SOLVENT
 EXTRACTION
   Classification  Codes: 811; 521;  641;  723; 614;  451
 23/5/21
 0039960   EIM8210039960
  WOOD HEATING SYSTEM  DESIGN  CONFLICTS  AND  POSSIBLE  RESOLUTIONS.
  She Iton,  Jay
  Shelton Enerds Res,  Santa Fe,  NM,  USA
  Proceedings  -   1981  International  Conference  on Residential  Solid  Fuels,
 Environmental Impacts  and Solutions.    Portland, Ores,  USA    Jun  1-4  1981
  Sponsor:  Orea Grad Cent, Beaverton, USA;  Northwest Environ  Res  Cent,  USA;
 Omark Ind,  Orea Saw Chain Div, USA
  Source: Publ ba  Orea Grad Cent, Beaverton, USA P 873-891    1982
  Lanauaaes: Enalish   Conf.  No.: 00722
  Descriptors! UOOD-Combustion
  Identifiers:  HEATING SYSTEM;  SOLID  FUELS?  WOOD  STOVES?   HEAT TRANSFER
 EFFICIENCY; CHIMNEYS;  CREOSOTE;  AIR  POLLUTION
  Classification Codes: 811;  521? 643;  641; 451
                                    8-28

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29/5/18

' 1090446   EDB-83:085317
  Uoodburning stove    (Patent)
  Jarboei  J.E.
  Patent No.: US 4f335»702   Filed date 22 Aug  1979
  v  P.   22  Jun  1982
  Country  of Publication! United States

  Note! PAT-APPL-068422
  Document Tape! Patent
  Languages: English
  Uork Location: United States
  An  efficient?   clean  burnina»  woodburnina stove in which super heated
fresh air  and exhaust asses from the primary combustion of  the  wood  fire
are  introduced into a secondary combustion chamber wherein these sioses are
mixed to recombust remaining fuel psrticles.  Exhaust  from  the  secondary
combustion  chamber enters a heat exchange chamber wherein the heat content
of the exhaust 3as is transferred to the cooking surface of the stove.  The
burning    rate  of  both  the  primary  and  secondor-j  combustion  con   be
independently controlled by individually selecting the air supplies to  the
combustion areas.  An  inclined grate*  in combination with the direction  of
the  exhaust gases* provides a self feeding feature in which an even burning
rate of the fire is insured.
  Descriptors: KSTOVES	DESIGN? #UOOD BURNING APPLIANCES	AIR POLLUTION
CONTROL?   *UOOD BURNING APPLIANCES	FUEL ECONOMY 5  AIR FLOW!  COMBUSTION
CHAMBERS;   COMBUSTION  CONTROL}   EXHAUST  GASES*   FOOD PROCESSING?  HEAT
EXCHANGERS? HEAT TRANSFER
  Special  Terms! APPLIANCES? CONTROL? ENERGY TRANSFER? FLUID FLOW?  FLUIDS?
GAS  FLOU?  GASEOUS WASTES! GASES? POLLUTION CONTROL? PROCESSING? WASTES
  Class Codes!  320100*
                                    8-29

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                                KEY WORDS
Sources
     Wood Stoves
     Wood Combustion
     Wood Heating
     Wood Furnaces
     Wood Heaters
     Wood Pyrolysis
     Wood Stokers
     Wood Pellets
     Wood Burning
     Woodstove Efficiency
     Residential Heating
     Residential Combustion
     Home Heating
     Fireplaces
     Residential Solid Fuels
     Biomass Combustion
     Biomass Energy
                              8-30

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                          KEY WORDS (Continued)

Emissions
     Wood Smoke
     Wood Volatiles
     POM Emissions
     PAH Emissions
     PNA Emissions
     BAP Emissions
     Pyrene Emissions
     Polar Fraction
     Acid Fraction
     Organic Fraction
     Inorganic Fraction
     Particle Bound Organics
     Condensible Organics
     Condensible Particulates
     Organic Emissions
     Inorganic Emissions
     Air Emissions
     Emission Factors
     Particulate Emissions
     Gaseous Emissions
     Chemical Emissions
     Carbonaceous Pollutants
     Toxic Air"Emissions
     Hazardous Air Pollutants
     Genotoxic Pollutants
     Emission Characteristics
     Air Pollutants
     Indoor Air Pollution
                                8-31

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                          KEY WORDS (Concluded)

Effects
     Carcinogenicity
     Mutagenicity
     Carcinogens
     Mutagens
     Cancer
     Health Effects
     Biological Effects
     Ecological Effects
     Bioassay
     Ames Test
     Salmonella Bioassay
     Tradescantia Bioassay
Miscellaneous
     Atmospheric Transforms
     Source Apportionment
     Source-Receptor Models
     Receptor Models
     Personal Monitoring
     Occupant Exposure
     Human Exposure
     Risk Assessment
     Particulate Sampling
     High Volume Sampling
     Organic Analysis
     Organic Fractionation
                                  8-32

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