United States Environmental Protection Agency Office of Water 4601 EPA811-F-95-002a-T October 1995 National Primary Drinking Water Regulations Asbestos CHEMICAL/PHYSICAL PROPERTIES CAS NUMBER: 1332-21-4 COLOR/ FORM/ODOR: White, gray, green or brown crystalline fibers; odorless , SOLUBILITIES: insoluble SOIL SORPTION COEFFICIENT: N/A BIOCONCENTRATION FACTOR: N/A; not expected to bioconcentrate COMMON ORES: Amosite, Chrysotile, Crocidiolite; Tremolite; Ascarite DRINKING WATER STANDARDS MCLG: 7 million fibers per liter (MFL) (fibers > 10 microns in length) 7 million fibers per liter (MFL) MCL: HAL(child): none HEALTH EFFECTS.SUMMARY Acute: No reliable data are available on the acute toxic effects from short-term exposures to asbestos. No Health Advisories have been established for short-term expo- sures. . Chronic: Asbestos has the potential to cause lung disease from a lifetime exposure at levels above the MCL. Cancer: Asbestos has the potential to cause cancer of the lung and other internal organs from a lifetime exposure at levels above the MCL. USAGE PATTERNS Because asbestos fibers are resistant to heat and most chemicals, they have been mined for use in a variety of products (over 3,000 different products in the United States). In 1988, asbestos was consumed in roofing products, 28%; friction products, 26%; asbestos cement pipe, 14%; packing and gaskets; 13%; paper, 6%; and other 13%. Pipe products find use in water supply, sewage dis- posal, & irrigation systems. Asbestos cement sheets are used in a wide variety of construction applications. Other uses of asbestos include fire resistant textiles, friction materials (ie, brake linings), underiayment & roofing papers, & floor tiles, Crocidolite can be spun & woven using modified cotton industry machinery; the asbestos cloth is used for fireproof clothing & curtains. Most uses of asbestos were banned in the United States by the EPA on July 12,1989 because of potential adverse health effects in exposed persons. The remain- ing, currently allowed uses of asbestos include battery separators, sealant tape, asbestos thread, packing ma- terials, and certain industrial uses of both sheet gaskets and beater-add gaskets. PATTERNS Asbestos fibers may enter the environment from natu- Toxic RELEASE INVENTORY • RELEASES TO WATER AND LAND: 1987 TO 1993 Water TOTALS (in pounds) < 32,650 Top Five States PA 0 LA 61 TX 0 AR 1,000 VA 0 Top Industrial Sources Asbestos products 3,005 Alkalis, chlorine 1,973 Industrial organic chems 0 Asphalt felts, coatings 5 Auto parts 0 Petroleum refining 0 Plastic pipes 0 Shipbuilding, repairing 0 Land 8,620,439 2,945,049 2.256,400 1,737,200 568,227 480,000 2,510,227 2,256.404 1.230,000 871,067 563,694 314.560 235,200 211,400 * State/Industry totals only include facilities with releases greater than a certain amount • usually 1000 to 10,000 Ibs. October 1995 Technical Version Printed on Recycled Paper ------- ral sources such as erosion of asbestos-containing ores, but the primary source of asbestos in the environment is through the wear or breakdown of. asbestos-containing materials. Asbestos fibers have been released into water by the dumping of mining tailings into lakes, by the runoff of process and air scrubber water into lakes and streams, and by the use of asbestos cement pipes in water supply systems. Over one million tons of asbestos is contained in friable materials in ships, buildings, power plants, chemical plants, refineries, and other locations of high temperature equipment. Other products may include insulation, auto- mobile brakes, cement pipes, and roofing materials. The maintenance, repair, and removal of this material will account for the principal releases in the future. Asbestos fibers also can be released to the environment from asbestos processing, including milling, manufacturing, and fabrication. From 1987 to 1993, according to the Toxics Release Inventory, asbestos releases to land totalled nearly 9 million Ibs., and releases to water totalled nearly 33,000 Ibs. These releases were primarily from asbestos prod- ucts industries which use asbestos in roofing materials friction materials, and cement. The largest releases oc- curred in Pennsylvania and Louisiana. ENVIRONMENTAL FATE As a naturally occurring substance, asbestos can be present in surface and ground water. Because asbestos fibers in water do not evaporate into air or break down in water, small fibers and fiber-containing particles may be carried long distances by water currents before settling to the bottom; larger fibers and particles tend to settle more quickly. Asbestos does not tend to adsorb to solids normally found in natural water systems, but some materials (trace metals and organic compounds) have an affinity for asbestos minerals. The fibers are not able to move down through soil to ground water. Asbestos is not affected by photolytic processes and is considered to be non-biodegradable by aquatic organ- isms. .Asbestos fibers are not broken down to other compounds in the environment and, therefore, can re- main in the environment for decades or longer. There are no data regarding the bioaccumulation of asbestos in aquatic organisms. OTHER REGULATORY INFORMATION MONITORING: - FOR GROUND AND SURFACE WATER SOURCES: INITIAL FREQUENCY- 1 sample once every 9 years REPEAT FREQUENCY- 1 sample once every 9 years - TRIGGERS - If detect at > 7 MFL, sample quarterly. ANALYSIS: REFERENCE SOURCE EPA 800/4-83-043 METHOD NUMBERS Transmission Electron Microscopy TREATMENT: BEST AVAILABLE TECHNOLOGIES Coagulation/Filtration; Direct and Diatomite Filtration; Corrosion Control FOR ADDITIONAL INFORMATION: 4 EPA can provide further regulatory and other general information: • EPA Safe Drinking Water Hotline - 800/426-4791 4 Other sources of lexicological and environmental fate data include: • Toxic Substance Control Act Information .Line - 202/554-1404 . • Toxics Release Inventory, National Library of Medicine - 301/496-6531 • Agency for Toxic Substances and Disease Registry - 404/639-6000 October 1995 Technical Version Page 2 ------- |