United States Environmental Protection Agency Office of Water 4601 EPA 811-F-95-003J-T October 1995 &EFA National Primary Drinking Water Regulations Dalapon CHEMICAL/ PHYSICAL PROPERTIES DENSITY/SPEC. GRAV.: 1.4 at 15° C CAS NUMBER: 75-99-0 SOLUBILITY: 800 g/L of water at 25° C; Very soluble in water COLOR/ FORM/ODOR: Colorless liquid with an acrid odor; sold SOIL SORPTION COEFFICIENT: as sodium or magnesium salt K°c N/A; very high mobility in soil ODOR/TASTE THRESHOLDS: N/A M.P.: 20° C B.P.: 190°C VAPOR PRESSURE: N/A OCTANOL/WATER PARTITION (Kow): Log Kow = 0.778 BlOCONCENTRATION FACTOR: BCF =1 to 3; not expected to biocon- centrate in aquatic organisms. HENRY'S LAW COEFFICIENT: 6.3x10-8 atm-cu m/mole TRADE NAMES/SYNONYMS: 2,2-dichloro- proprionic acid; 2,2-DPA; Revenge; Alatex; Basfapon; Basinex; Crisapon; Dawpon-RAE; Ded-Weed; Dowpon; Gramevin; Kenapon; Liropon; Propon; Radapon; Unipon; S-1315; S-95 of the sodium and magnesium salts. Domestic production of dalapon in 1982 ranged be- tween 7 and 9 million Ibs. active ingredient. In 1984, its use in California was reported as follows: Non-food use, 92.9% (89.9% use on rights of way); main food crop treated was sugarbeet (6.7% of total). DRINKING WATER STANDARDS MCLG: 0.2 mg/L Met: 0.2 mg/L HAL(child): 1- to 10-day: 3 mg/L longer-term: 0.3 mg/L HEALTH EFFECTS SUMMARY RELEASE PATTERNS Acyte/EPAhasfounddalapontopotentiallycausethe Da|apon is released directly to the environment in its following health effects from acute exposures at levels use as a herbicide for the control of annual and perennial above the MCL: no effects, but readily absorbed into and grasses widely distributed throughout the body. . . . . Since dalapon is not a listed chemical in the Toxics Drinking water levels which are considered "safe" for Re|ease Inventory, data on releases during its manufac- short-term exposures: For a 10-kg (22 Ib.) child consum- ture and hand|ing are not available. ing 1 liter of water per day, up to a ten-day exposure to 3 mg/L or up to a 7-year exposure to 0.3 mg/L. ENVIRONMENTAL FATE Chronic: Dalapon has the potential to cause the .,-,_.,.,'_,. .,, u- following health effects from long-term exposures at If reteased.to soil, microbial degradation and leaching levels above the MCL: increased kidney-to-body weight ??Pear to be tne important environmental fate processes. Dalapon leaches readily in soil; however, under condi- Cancer: There is inadequate evidence to state whether tjons favorab|e for microbial growth, microbial degrada- or not dalapon has the potential to cause cancer from tjon wj|| proDab|y proceed at a faster rate than leaching. lifetime exposure in drinking water. in the absence of mjCrobial action, dalapon degradation in soil is slow. The resultant average persistence of USAGE PATTERNS dalapon at recommended rates of application has been Dalapon is a herbicide used to control grasses in a reported to be two to four weeks in most agricultural soils ride variety of crops, including fruit trees, beans, coffee, durin9the 9rowin9 season- althou9h a Persistence of six corn, cotton and peas. It is also registered for use in a months has been observed in soils of various forests and numberof non-crop applications such as lawns, drainagetree nurseries. ditches, along railroad tracks, and in industrial areas. If released to water, microbial degradation, hydrolysis, Dalapon is marketed as the sodium salt or as a mixture and photolysis are potentially important in the removal of October 1995 Technical Version Printed on Recycled Paper ------- dalapon. The hydrolysis half-life of dalapon and its salts in water is on the order of several months at temperatures less than 25 deg C, with the hydrolysis forming pyruvic acid. Under conditions favorable for microbial growth, dalapon decomposition via microorganisms will probably be complete within one month which will diminish the importance of chemical hydrolysis. Direct photolysis in water may be possible, although photolytic rates have not been investigated under environmental conditions. Aquatic volatilization and adsorption to sediments are not expected to be significant. If released to the atmosphere, dalapon will react in the vapor-phase with photochemically produced hydroxyl radicals at an estimated half-life rate of 72.3 days. Atmo- spheric removal via washout may be possible since dalapon is extremely water soluble: Bioconcentration is not expected to be significant. The BCF measured for dalapon (sodium salt) during a 3-day exposure in an aquarium was 3 for fish and less than one for snails. BCF's of less than one have been measured for poultry, rodents, dogs, and cows. Occupational exposure to dalapon may occur through dermal and inhalation routes associated with the formu- lation and application of dalapon herbicide. OTHER REGULATORY INFORMATION ^^i^Mi^HI^^^^^ MONITORING: FOR GROUND/SURFACE WATER SOURCES: INITIAL FREQUENCY- 4 quarterly samples every 3 years REPEAT FREQUENCY- If no detections during initial round: 2 quarterly per year if serving >3300 persons; 1 sample per 3 years for smaller systems TRIGGERS - Return to Initial Freq. if detect at > 0.001 mg/L ANALYSIS: REFERENCE SOURCE METHOD NUMBERS EPA 600/4-88-039 515.1; 552.1 TREATMENT: BEST AVAILABLE TECHNOLOGIES Granular Activated Charcoal FOR ADDITIONAL INFORMATION: 4 EPA can provide further regulatory and other general information: EPA Safe Drinking Water Hotline - 800/426-4791 * Other sources of lexicological and environmental fate data include: Toxic Substance Control Act Information Line - 202/554-1404 Toxics Release Inventory, National Library of Medicine - 301/496-6531 Agency for Toxic Substances and Disease Registry - 404/639-6000 National Pesticide Hotline - 800/858-7378 October 1995 Technical Version Page 2 ------- |