Pollution Abatement
                 in the Fruit and
            Vegetable Industry
                    Basics of Pollution Control/
                          Case Histories
EPAlechndogy Transfer Seminar Publication

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EPA—625/3-77-0007
                  POLLUTION ABATEMENT IN THE
               FRUIT AND VEGETABLE INDUSTRY

                              Basics of Pollution Control/
                                         Case Histories
ENVIRONMENTAL PROTECTION AGENCY
Environmental Research Information Center* Technology Transfer

                       July 1977

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                 ACKNOWLEDGMENT
   This  seminar  publication contains  materials prepared for the
United  States Environmental Protection Agency Technology Trans-
fer Program and presented  at industrial pollution-control seminars
for the fruit and vegetable processing industry.
   The Technology Transfer  Program extends its appreciation to the
Food Processors Institute  and  the National  Canners Association
for their work in preparing the publication.
                              NOTICE
  The mention of trade names or commercial products in this publication is for
illustration purposes, and does not constitute endorsement or recommendation for use
by the U.S. Environmental Protection Agency.

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                                      CONTENTS


                                                                                      Page

 Chapter I.  Introduction	    1
    Water  	    1

 Chapter II. Water Pollution Parameters  	    5
    Major Aspects	    5

 Chapter HI. Sampling	   14
    Grab Samples 	   14
    Composite Samples	   14
    Sample Storage	   15

 Chapter IV. Case Histories	   16
    Environmental Motivation	   16
    Case History I. Wastewater Treatment at Artichoke Industries 1955-1975	   18
    Case History II.  In-Plant Control of Wastes at Red Wing  	   21
    Case History III. Water Pollution Control — Frito-Lay, Inc	   26
    Case History IV. In-Plant Control Technology for a Carrot Processor	   34
    Case History V.  In-Plant Water and Waste Control	   39
    Case History VI. Heat Recovery and Water Recycle  	   41
    Case History VII. Snokist Growers Cannery  	   44
    Case History VIII.  Case History of Tomato Processing Wastewater Management
      at Hickmott Foods, Inc	   57
    Case History IX. Permit Requirements for Starting a New Food Processing Plant	   77
    Case History X.  Land Spreading and Discing of Food Residuals  	   81
    References   	   86

 Chapter V. Glossary	   87
                                    LIST OF FIGURES
 1-1    Distribution of water on Earth  	    1
 1-2    A hypothetical oxygen-sag curve  	    3

 II-l    Dissolved oxygen meter with recorder  	    6
 II-2    First and second-stage BOD curve  	    7
 II-3    Steps in the determination of total and fixed solids  	   10
 II-4    The pH scale, with values of some materials 	   11

III-l    Temporal fluctuations in a food plant waste load	   15

IV-1    Treatment scheme for potato preparation water with recycle	   30
IV-2    Treatment scheme for potato chip slice wash water with recycle  	   31
                                             m

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                              LIST OF FIGURES (Continued)

                                                                                      Page

IV-3   Treatment scheme for corn wash water with recycle  	   32
IV-4   Original flow, carrot processor "A"  	   35
IV-5   Modified flow, carrot processor "A"	   36
IV-6   Schematic for heat recovery and water recycle	   42
IV-7   Schematic flow diagram 1967-1968 processing season 	   47
IV-8   Schematic Flow diagram 1968 processing season  	   48
IV-9   BOD removal rate vs concentration at 20°C 	   49
IV-10  COD removal coefficient vs temperature   	   50
IV-11  Endogenous respiration rate vs temperature 	   52
IV-12  Schematic flow diagram — solids dewatering  	   54
IV-13  Digestibility of rations by biological solids content  	   54
IV-14  Metabolizability of rations by biological solids content  	   55
IV-15  Weight gain by ration biological solids content	   55
IV-16  Carcass yield grade and marbling score by ration   	   56
IV-17  Flowsheet for wastewater treatment process (put into operation in 1974)	   66
IV-18  Aeration basin with surface aerators in operation	   66
IV-19  Flowsheet for waste sludge thickening facilities 	   72
                                     LIST OF TABLES


                                                                                     Page

 II-l   Water pollution parameters in fruit and vegetable processing  	    5

IV-1   Characterization of wastewater   	   28
IV-2   Pilot test results  	   29
IV-3   Results from full scale installation  	   33
IV-4   Carrot process "A" parameter differences  	   37
IV-5   Unit waste contribution  	   44
IV-6   Treatment system performance 1967-1968 processing season	   45
IV-7   Treatment system performance 1968-1969 processing season	   46
IV-8   Sludge yield coefficients	   46
IV-9   Summary of activated sludge process — 1974  	   51
IV-10  Tomato processing production data for the 1973,1974, and 1975 canning seasons ...   57
IV-11  Waste generation during 1974 tomato canning season	   58
IV-12  Wastewater characteristics during 1973,1974, and 1975 canning seasons	   59
IV-13  Effect of peeling sludge on wastewater characteristics  	   59
IV-14  Tomato processing waste discharge requirements 	   60
IV-15  Daily water usage during 1974 canning season and percent reduction data over 1973
         canning season  	   62
IV-16  Summary data on caustic tomato peeling operation and acid usage at Hickmott Foods,
         Inc	   63
IV-17  Influent and effluent wastewater characteristics during the 1974 and 1975 tomato
         canning season  	   64
IV-18  Nutrient requirements of activated sludge process and quantities available in
         wastewater from tomato canning operations	   67
                                            IV

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                              LIST OF TABLES (Continued)


                                                                                     Page

IV-19  Physical characteristics and operational parameters for the activated sludge process
         measured during 1974 tomato canning season   	   68
IV-20  Sedimentation basin characteristics, loadings and performance data  	   70
IV-21  Summary of capital costs of wastewater treatment facilities	   73
IV-22  Summary of daily operating costs for wastewater treatment facilities during
         1974 canning season	   74
IV-23  Summary of daily solids and sludge disposal costs during 1974 canning season 	   74
IV-24  Summary of total daily cost for wastewater treatment during 1974
         tomato canning season  	   75
IV-25  Requirements for starting a new food processing plant  	   80

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                                        Chapter I
                                    INTRODUCTION
                                           WATER

     Examination of the distribution of water on this planet (figure 1-1) reveals that the greatest
quantity (97.13%) exists in the oceans of the world. The second major quantity (2.24%) exists
as ice and snow in the polar regions. These sources are, of course, unavailable for domestic use
without extensive treatment and/or transportation. Of the remainder of Earth's water, the largest
supply that is used for human consumption exists as ground or subsurface waters (0.612%). The
widespread dependence on wells for fresh water attests to its distribution and availability. Only
a relatively small portion, then, exists as surface water in the lakes (0.009%) and the streams
(0.0001%)  of the world.

     Water in its pure state is a simple molecule consisting of two hydrogen atoms attached to a
single atom of oxygen. However,  water molecules have the unique property of being able to
dissolve an extremely wide variety of substances. Therefore, in its natural state, water contains
varying concentrations of dissolved minerals, organic matter and atmospheric gases.
                        Ice caps 2.24%
                             Figure 1-1.   Distribution of water on  Earth.

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     Materials are continually added to water in a natural setting. Rocks and soil are eroded by
the passage of the stream, adding suspended solids to the water; trees and plants shed their leaves,
or die and fall to rot, adding organic matter; animals, birds and fish, all functioning naturally and
living their normal life cycles, further add to the organic load imposed upon the stream. These
normal and continual contributions of water contaminants have been termed natural pollution.

     Each stream, however, also has the capability to purify itself of various materials. In the slow-
flowing stretches, suspended solids settle to the stream bed, thereby forming sandy bottoms. As a
stream tumbles and falls over rocks and other obstacles in its path,  oxygen is entrained in and dis-
solved by the water. Even as a stream slowly flows through forest or meadow, oxygen is absorbed
from the air at the water's surface. The  dissolved oxygen not only sustains fish, plants and other
large aquatic life, but also sustains a large group of microorganisms which are especially responsible
for the stream's self-purification.

     Aerobic bacteria (microorganisms which require oxygen) rely on organic matter in the water
for food. These microorganisms, in utilizing the pollutants in the stream, convert the organic
matter into cellular material during growth, or degrade  the organics to nonputrescible compounds
through  their metabolic process. During the process, dissolved oxygen is consumed. In a free-
flowing stream, the rate  at which bacteria consume dissolved oxygen to stabilize natural pollu-
tants only infrequently exceeds the rate at which the stream is physically oxygenated.  Thus,
sufficient dissolved oxygen is normally present to sustain the needs of a variety of aquatic life.


ASSIMILATIVE CAPACITY

     The rate at which dissolved oxygen is consumed is directly related to the concentration of
pollutants present in water.  That is, the higher the concentration, the more active are the
bacteria, and hence the higher the rate at which oxygen is used; the lower the concentration, the
lower the consumptive or deoxygenation rate. When the consumptive rate exceeds the oxygena-
tion rate of a stream, the level of dissolved oxygen in the water begins to decrease. Since mini-
mum levels of  dissolved  oxygen are required by fish and other aquatic life,  excessive oxygen
depletion will result in biological stress and, ultimately, fatality.  The quantity of pollutants which
may be added  to a stream without deleterious effects on aquatic organisms is called the assimi-
lative capacity  of the stream.


EFFECT OF WASTE DISCHARGES

     Waste discharges, whether domestic sewage or industrial wastewaters, impose demands upon
the assimilative capacity  of the receiving water. When a heavy load exceeding the assimilative
capacity is discharged, the dissolved oxygen content of the stream will be greatly depressed.
However, provided no further waste discharges occur downstream, the dissolved oxygen content
of the stream will eventually be re-established.  A graph depicting the profile of the dissolved
oxygen content in  such a situation is called an oxygen-sag curve (figure 1-2). Reoxygenation
rates depend upon  the number of factors, including the initial dissolved  oxygen content of the
stream, the pollutional strength of the waste discharge, the relative volumes of the two, and
the characteristics of the downstream flow (fast or slow, smooth or turbulent).

     Unfortunately, waste discharges occur at numerous points along most streams, thereby
often precluding sufficient reoxygenation. Thus, the self-purification capabilities of such streams
are seriously hampered.  When excessive waste loads are discharged under these conditions, the
consequences become evident by  large fish kiljs and nuisance conditions with serious public
health significances.

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      I
      z
      LU
      C3
      X
      o
      Q
      LU
      OT
      Q
                     Waste discharge
Oxygen depletion
                                                          Reoxygenation
                                         TIME OF FLOW, days

                           Figure 1-2. A hypothetical oxygen-sag curve.
ENVIRONMENTAL LEGISLATION

     During the late 1950's and through the 1960's, several important Congressional acts were
passed. Although some of these were not individually significant, they served as precursors to the
most important piece of environmental legislation enacted to date. On October 18, 1972, Congress
established Public Law 92-500, the Federal Water Pollution Control Act Amendments of 1972.
This act essentially rewrote and consolidated several preceding laws in an effort to create a me-
chanism by which to attack and resolve the nation's water pollution plight.

     The law establishes as  a national goal the elimination of pollutant discharges into navigable
waters by 1985. This is popularly called the "zero discharge" concept.  In an effort to meet this
goal, the Administrator of the EPA is directed to establish for each major industry group a set
of effluent limitations—that is, specific  restrictions on the quantity of pollutants that an industrial
plant will be permitted to discharge. These limitations are to be based on reductions considered
to be achievable through in-plant process changes, as well as end-of-pipe wastewater treatment.

     PL 92-500 requires that  by July 1, 1977, effluent limitations reflect the application of the
"best practicable control technology currently available"; by July 1, 1983, the limitations are to
be based on application of  the "best available  technology economically achievable"; and per-
formance standards for all new sources must be based on the "best available demonstrated
technology." Factors to be considered in the establishment of effluent limitations include the age
of equipment and facilities, the processes employed, and costs to achieve the specified reductions.

     PL 92-500 also establishes  a permit program known as the National Pollutant Discharge
Elimination System (NPDES). To  assure that  effluent limitations are being met and that desig-
nated water quality standards are maintained,  all wastewater dischargers are required to obtain
a permit.  Although the permit program was initially administered by EPA, a mechanism is pro-
vided to  shift administrative responsibilities to individual states. (Many states now have or will
soon be granted administrative authority.)

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     When NPDES discharge permits are issued, conditions are prescribed to assure compliance
with all appropriate regulations, including (but not limited to) protection of designated bene-
ficial uses of the receiving water, specification of effluent limitations, and a construction schedule
of adequate wastewater treatment facilities to meet the limitations. The permits also prescribe
self-monitoring procedures required of all  direct dischargers. The self-monitoring program gen-
erally consists of data collection and record keeping; reports must be periodically submitted  to
the appropriate  regulatory agency.

     Those provisions of PL 92-500 described in the preceding paragraphs relate primarily to
direct dischargers, i.e., those industrial plants which discharge wastewater directly to receiving
streams. The Act, however, also contains provisions which affect industrial users of publicly-
owned treatment works.  Industrial users can be significantly affected by performance standards
and effluent limitations which are imposed upon publicly-owned facilities.  Since industrial waste
loads may constitute a significant portion  of the total load being treated at a municipal plant, the
type and size of that facility may be greatly affected by the industrial load, thereby influencing
the total cost of new or expanded  facilities to meet imposed regulations. For municipalities to
take advantage of federal construction grants, the Act requires each municipality to establish a
revenue recovery program which insures that industrial users will contribute their proportionate
share of total capital costs. Additionally,  each municipality is required to establish a schedule
of user charges,  based on flow rate and strength, which will assure that each recipient of waste-
water treatment services, both industrial and non-industrial, will pay its proportionate share of
total operating and maintenance costs. Therefore, industrial users of publicly-owned treatment
works may incur significant costs for the privilege of utilizing such facilities.

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                                       Chapter II


                       WATER  POLLUTION PARAMETERS


                                      MAJOR ASPECTS

     The potential effect of wastewater discharges, either upon a receiving stream or a treatment
system, is evaluated by accumulating specific information with which to determine the pollutant
concentration, or waste load, associated with the discharges.  Waste loads are used:

     •    By engineers to design appropriate wastewater treatment facilities.

     •    By regulatory authorities to specify effluent limitations.

     •    By municipalities to levy surcharges for sewer services.

     There are two aspects  of industrial waste loads which are of primary concern. The first is the
volume or quantity of wastewater which must be treated and/or disposed. This is referred to as the
hydraulic load.  The second consideration is the pollutant concentration of the wastewater. For
most fruit and vegetable processing wastes, the pollutant concentration can be measured through
the use of biochemical oxygen demand (BOD) and suspended solids (SS).  These are collectively
referred to as the organic load. The hydraulic and organic loads comprise what is referred to as the
raw waste load (RWL).

     Other water pollution  parameters which may be of concern to fruit and vegetable processors
are listed in table II-l and are also briefly described in the remainder of this chapter.

                 Table 11-1.  -Water pollution parameters in fruit and vegetable processing

                             Major                              Other3

                   Flow                                    Temperature

                   Biochemical oxygen demand                 Total solids

                   Total suspended  solids                      Dissolved solids

                   Settleable  solids                            Chlorides

                   Chemical oxygen demand                    Nitrogen

                   pH                                      Phosphorus

                   Dissolved oxygen
                    May be major depending upon concentrations and/or circumstance.

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 FLOW

     Flow measurements are a basic requirement for monitoring all discharges. Hydraulic loads can
 only be determined by accurate flow records, preferably kept on a continuous basis. Since the
 hydraulic load largely dictates the required size of a treatment facility, each processing plant should
 provide some means for obtaining and recording this information.

     Various equipment is commercially available for measuring flow, including meters, weirs,
 flumes, and special devices. This equipment, as well as simple flow measuring techniques, is de-
 scribed  in detail in volume 2.  (Flow measurement is also covered in the Handbook for Monitoring
 Industrial Wastewater1 published by the EPA.)
DISSOLVED OXYGEN

     Dissolved oxygen is defined as oxygen which is dissolved in water or other liquid. This should
not be confused with the presence of visible air bubbles since such bubbles are still in a gaseous
state. Although dissolved oxygen is not generally a significant parameter when dealing exclusively
with waste streams, it is of major importance in receiving waters and in certain waste treatment sys-
tems. Aerobic conditions must be maintained in the latter to preclude development of odors asso-
ciated with stagnation.

     Dissolved oxygen (DO) may be measured either by wet chemical analysis or by instrument
(figure II-l); the procedures are discussed in volume 2. Dissolved oxygen concentrations are ex-
pressed as milligrams per liter (mg/1 DO), which is approximately equivalent to parts per million
(ppm).

     The quantity of dissolved oxygen which can be maintained in water is directly related to
atmospheric pressure and inversely related to water temperature. Thus, the lower the temperature
and the higher the pressure, the greater the maximum maintainable DO level. Although it is pos-
sible to obtain relatively high concentrations of dissolved  oxygen, 9 mg/1 DO is generally regarded
as the saturation level under ambient conditions. A minimum of 5 mg/1  is considered to be de-
sirable for sustaining game fish (trout, salmon, etc.).
                         Figure 11-1. Dissolved oxygen meter with recorder.

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BIOCHEMICAL OXYGEN DEMAND

     For many years, investigators have attempted to measure the strength of wastewater contain-
ing decomposable organic compounds in terms of their effect upon streams or other bodies of water
into which the wastes are discharged. The standard method for measuring this effect is the bio-
chemical oxygen demand (BOD) test.  The test was developed by determining the amount of oxygen
required to microbially stabilize known quantities of decomposable organic matter.

     The BOD test is based on an apparent direct relationship between the pollutional strength of
organic wastes and the amount of oxygen that will be required (oxygen demand) in biochemical
reactions to convert the materials to carbon dioxide, water and inorganic nitrogen compounds.
The oxygen demand is related to the rate of increase in microbial activity which is, in turn, pro-
portional to the concentration of nutrients in the organic wastes. These relationships also represent
the mechanism responsible for the self-purification of streams.

     In the standard laboratory BOD test, samples of wastewater are seeded with an inoculum,
diluted with previously aerated water (if necessary), and incubated at 20°C. The initial DO is mea-
sured and after a specified period, the dissolved oxygen content  is again determined; the BOD is
based on the depletion of oxygen from the sample during the incubation period.  Since complete
stabilization of organic wastes requires prolonged periods (figure II-2), laboratory analysis is limited
to two periods. The 5-day BOD, which is used most widely, represents most of the oxygen neces-
sary to stabilize the carbonaceous and readily oxidized materials. Since fruits and vegetables are
largely composed of carbohydrates, the 5-day BOD value is  of greatest significance to this industry.
The 20-day, or second stage, BOD  value is used to estimate the ultimate BOD; this value represents
oxygen required to stabilize nitrogenous and other slowly oxidized materials.
                        1st stage
                        (carbonaceous)
              O)
              E
              Q"
              O
              00
                                                             JL
                                      INCUBATION TIME, days

                           Figure II-2. First and second-stage BOD curve.

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      Laboratory results are reported as milligrams per liter (mg/1). However, effluent limitations
 and sewer service charges are based on pounds of BOD.  To determine the latter quantity, accurate
 flow measurements must be available.  Pounds of BOD may then be calculated as follows:

               , nrkr.   BOD (mg/1) X total flow (gallons) X 8.34
          pounds BOD =	1,000,000	'

      For any waste, the concentration of pollutants can be readily reduced by simply using more
 water, but the increase in volume will result in the same  number of total pounds of pollutants.
 Therefore it is apparent that "dilution is no solution to pollution." Instead, the BOD load can be
 effectively reduced only by simultaneously reducing water usage and  BOD generation.


 CHEMICAL OXYGEN DEMAND

      Chemical oxygen demand (COD)  is an alternative to biochemical oxygen demand (BOD) for
 measuring the pollutional strength of wastewaters. Simply described, the COD test measures the
 amount of oxygen consumed during chemical oxidation  of waste constituents. The test is relatively
 quick and highly reproducible, thereby eliminating the two primary disadvantages of the BOD test.

      When considering the use of COD for measuring the pollutional strength of wastewater, one
 must bear in mind that the BOD and COD tests involve separate and distinct reactions.  Chemical
 oxidation measures carbon and hydrogen but not amino  nitrogen in organic materials. Furthermore,
 the COD test does not differentiate between biologically stable and unstable compounds.  For example,
 cellulose is measured by chemical oxidation but is not measured biochemically under aerobic con-
 ditions. Despite these differences, a number of investigators have found a reliable and useful rela-
 tionship between BOD and COD  for certain types of wastes. The COD is especially useful for
 routinely monitoring wastewater discharges.

      The primary disadvantage of the COD test is its susceptibility to  interference by chloride. Thus,
 wastewaters containing high salt concentrations, such as sauerkraut and pickle brines, cannot be
 readily analyzed without modification.  However, the standard method for COD is  designed to re-
 move interferences at low chloride concentrations and can be used for analysis of processing waste-
 waters.
SOLIDS IN WASTEWATERS

     Solids, or particulates, present in screened wastewaters are of concern for several reasons.
When discharged into receiving streams, the particulates may remain in suspension to create turbid
conditions. They may float and agglomerate to form unsightly scum blankets, or they may settle
on stream beds to form anaerobic sludges. In wastewater treatment systems, settleable and float-
able solids must be removed so that they will not interfere with the efficiency of treatment.


Settleable Solids

     Information on the amount of settleable solids in wastewaters provides a basis for predicting
the sludge load in settling basins, clarifiers, stream beds, or sewer lines.  The laboratory method is
semi-quantitative and is useful only for estimating the volume of sludge which can be anticipated.

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Total Solids

     Total solids determinations (figure II-3) measure all matter contained in a water or wastewater
sample. Included in the determination are suspended materials, which contribute to the turbidity
of water, as well as dissolved components, such as sugars and salts. Although some volatile organic
compounds may be excluded in this analysis, which is conducted at the boiling point of water, total
solids is a useful tool for the qualitative determination of the pollutants contained in wastewater
samples.

     Total solids is the residue remaining after evaporation of water from a sample.  Solids can be
further subdivided into fixed and volatile solids.  The fixed solids, determined by weighing the
residue remaining after combustion, are regarded as representing the inorganic matter contained in
the sample. The volatile solids, which is that portion of the total solids lost upon combustion,
represents the organic matter.


Suspended Solids

     Suspended solids  (SS) in wastewater is the solid  matter parameter of greatest interest. This
parameter is used by regulatory agencies as an index of potential formation of sludge deposits and
turbid conditions in receiving waters; effluent limitations are therefore placed on allowable SS dis-
charges. Engineers and treatment plant operators utilize SS information to determine the quantity
of solids which will require removal in activated sludge treatment systems (described under Treat-
ment Methods). Suspended solids determinations reflect the operating efficiency of the system.

     Suspended solids is defined simply as that matter which will not pass through a filter. For
fruit and vegetable processing wastewaters, SS  is considered to be all materials which pass through
a 20-mesh screen but are retained on a filter. The laboratory determination is made by first filtering
a wastewater sample, and then drying and weighing the residue retained on the filter. As with total
solids, the total suspended solids (TSS) thus obtained may be further subdivided into fixed (FSS)
and volatile (VSS) components by combustion.

     Laboratory results are expressed as milligrams SS per liter (mg/1). However, as in the case of
BOD, SS limitations are expressed in pounds. The conversion of units, which requires accurate flow
data, is identical to BOD:

          , 00   SS (mg/1) X total flow (gallons) X 8.34
     pounds OD = •	
     v                      1,000,000

     Again, dilution will effect no change in the total pounds. Rather, the organic load, consisting
of both BOD and TSS, can only be effectively reduced by simultaneous reductions in water usage
and pollutant generation at in-plant sources.


Dissolved Solids

     Since as much as 85% of the BOD of fruit and vegetable processing wastewaters may be
attributable to dissolved organic matter, the total dissolved solids (TDS) determination  is often of
interest.  TDS measurements are made by filtering samples, and drying and weighing the residues in
the filtrates. Fixed (inorganic) and volatile (organic) fractions may be determined by combustion.
When brines (such as used for storing olives, pickles and sauerkraut) are discharged,  the TDS test is
often used to estimate the quantity of salt contained in the wastewater.

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                                                           2. Evaporating dish placed
                                                              in drying oven for one
                                                              hour at 103° C.
1.  Evaporate sample to
   dry ness on steam
   table.
                                        7. Total fixed
                                           solids deter-
                                           mined by
                                           weighing re-
                                           sidue after
                                           combustion.
                      6. Cool combusted
                         sample.


                                                                                             3. Evaporating
                                                                                                dishes trans-
                                                                                                ferred to
                                                                                                desiccator foi
                                                                                                45 minutes
                                                                                                to cool.
                                                                              4. Total solids
                                                                                 determined by
                                                                                 weighing dried
                                                                                 sample.
                 5.  Sample heated in muffle
                    furnace for 20 minutes
                    at 600°C to burn the
                    organic material.
                               Total volatile solids = Total solids - Total fixed solids
                   Figure 11-3. Steps in the determination of total and fixed solids.
                                                  10

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PH

     pH is a measure of the hydrogen ion concentration in water and indicates the acidic or alkaline
character of the water. A pH measurement does not, however, indicate a liquid solution's buffering
capacity, which is its capacity to accept acid or alkali without corresponding changes in the hydro-
gen ion concentration. The pH values are expressed by a numerical scale from 0 to 14, the mid-
point, 7.0, being neutrality (figure II-4). The 0 to 7 range is the acid scale and the 7 to 14 range is
the alkaline scale. Measurements are most suitably made potentiometrically with an appropriate
pH meter.

     The pH of fruit and vegetable processing  wastewaters may vary from 3.5 to 11.5, depending
upon the product being packed and the type of operations conducted within the plant. Natural
waters generally have pH values between 5.5 and 8.5. Accurate pH measurement and control of
plant effluents are often essential for successful treatment and disposal.
                                         14
                                         11
                             Basic
                                          9  ' '
                            Neutral
                                          5  — ™
                             Acidic
                                         3  - -
                                                        Caustic (lye) solution
                                                        Weak or dilute
                                                         alkaline solutions
       .)..... Most effluent limits

~f\  I   )"" Most ground waters in U.S.

       I	Pure water = pH 7
                                                )	  Most vegetables
     \...... Most tree fruit, tomato

    ^  /••* Berries

     >«...« Citrus juices



            Weak or dilute acids
                                                      •• Mineral acids, concentrated
                         Figure II-4. The pH scale, with values of some materials.
                                               11

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  OTHER PARAMETERS

      The tests discussed in the previous paragraphs constitute the parameters of major concern to
 fruit and vegetable processors.  In specific situations, the tests described in the remainder of this
 chapter may also be of importance to this industry.


 Temperature

      Since the dissolved oxygen concentration in water is inversely related to temperature, effluent
 limitations based on water quality standards generally include temperature limits. The temperature
 of plant effluents may be of little or no consequence to some processors but may be of significant
 concern to others.  The degree to which temperature may be a problem is determined by the types
 of operations which contribute heat to the waste discharge and the relative flows between the plant
 effluent and the receiving stream.

      Container and compressor cooling waters and evaporator condenser effluents are the major
 sources of heated wastewaters in fruit and vegetable processing plants.  These effluents may be dis-
 charged in several fashions. When they are mixed with processing wastewaters prior to treatment,
 temperatures in the final discharge will have minimal effects on receiving streams. When mixed with
 treated wastewaters prior to discharge, the final temperature will depend upon the degree to which
 the heated effluent is diluted by the treated waste.  The severest impact on a receiving stream will
 occur when heated wastewaters are  discharged directly. In this case the effect will be determined
 by the flow and temperature of the  discharge versus the flow and temperature of the receiving
 stream. Cooling ponds or towers may be required in extreme situations.

      Temperature measurements can be manually taken by periodically checking the discharge with
 a mercury-filled glass thermometer or any number of commercially available temperature measuring
 devices. Where continuous readings are desirable, suitable temperature sensors and recorders are also
 available.
 Nutrients

      Aside from carbonaceous organic matter (which is measured largely as BOD), the nutrients of
 primary concern are organic nitrogen and phosphorus-containing compounds.  Both compounds
 are required for reproduction of microorganisms. Nitrogen (N) and phosphorus (P)  are largely
 responsible for algal "blooms" which result from eutrophication of lakes and streams. To optimize
 efficiencies of biological wastewater treatment systems, nitrogen and phosphorus concentrations
 are adjusted according to the BOD concentration in the wastewater.  The generally  recommended
 ratio of BOD to total N to total P is 100:5:1.  Fruit and vegetable processing wastewaters are
 normally nutrient deficient.

     The laboratory nitrogen determination of greatest interest to this industry is the total
 kjeldahl nitrogen (TKN) analysis.  Most of the organic nitrogen compounds are converted to ammonia
 which can then be measured colorimetrically or by titration.  Results are reported as mg/1 TKN.

     Phosphorus occurs nearly always in the form of various types of phosphates (PO4>. Detergents
 used for product washing and plant cleanup are the primary sources of water soluble phosphates in
 fruit and vegetable processing effluents.  Insoluble forms of phosphates  may be found in sediments
 and in waste sludges. In the laboratory procedure, wastewater samples may be  analyzed solely for
soluble forms of phosphate or may be treated to solubilize all phosphates.  All of the various avail-
able laboratory methods for measuring phosphate are colorimetric, with  results being reported as
mg/1 P.
                                             12

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Chlorides (Salt)

     Chlorides, or more generally salt (NaCl), in fruit and vegetable processing effluents are asso-
ciated with brining operations. Saline waters cause metal corrosion and are toxic to fresh water
aquatic organisms. Salt in high concentrations will also exert deleterious effects on agricultural
crops.

     Brines from quality graders and fillers are generally diluted by sufficient volumes of processing
wastewaters such that the final concentration is adequately low.  However, the disposition of large
volumes of brines (like those associated with olive, sauerkraut, and pickle processing) is frequently
problematic. Such waste discharges will often be regulated by effluent limits for chloride.

     Chlorides may be determined either colorimetrically with special reagents, or by potentiometric
titration; results are reported as mg/1 Cl.  These results may then be used to calculate the salt con-
centration (as NaCl).  For high salinity brines, an estimate of the salt concentration may be obtained
from total solids or total fixed solids determinations.
Analytical Procedures

     EPA-approved procedures should be used to develop all analytical data, especially those re-
quired for compliance monitoring. These are contained in Methods for Chemical Analysis of Water
and Wastes2 and Standard Methods for the Examination of Water and Wastewater^. It is strongly
recommended that companies performing their own laboratory analyses obtain both of these
references.
                                             13

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                                      Chapter III


                                      SAMPLING


     The most vital part of an effluent monitoring program is the procedure used to collect
 wastewater samples.  Only with  appropriate sampling procedures can laboratory analyses yield
 accurate information relative to  a plant's discharge.  Optimally, the best information can be
 developed  by continuous in-line sampling with instantaneous analysis and recording. For some
 parameters, such as temperature and pH, this is very practical.  However, the cost or the unavail-
 ability of suitable instrumentation renders continuous monitoring infeasible for most parameters.
 As a compromise, laboratory analyses are performed on samples which  are collected and pre-
 served in a manner that  will yield representative or typical data.


                                       GRAB  SAMPLES

     A sample which is collected on a one-time basis is called a  grab or discrete sample. A grab
 sample, as implied by its name,  may be collected by manually dipping a container into a waste-
 water stream.  However, laboratory results  obtained from such a sample will provide but a single
 data point, reflecting only those conditions which exist at the time the sample is drawn.  Since
 wastewater characteristics from fruit and vegetable processing operations vary widely throughout
 the production day,  a single grab sample is of little value.  If, on the other hand, numerous grab
 samples are collected and separately analyzed, temporal fluctuations in  the waste load  will be
 revealed (figure III-l). This type of information is extremely useful, not only for determining (or
 which periods of the day the loads tend to peak, but also for calculating meaningful daily  (or
 other period) averages.  Automatic  sampling equipments capable of collecting a series of discrete
 samples are commercially available.
                                 COMPOSITE SAMPLES

     As previously indicated, laboratory results from numerous grab samples taken within a
period of time can be used to calculate meaningful averages for that time interval.  However,
this procedure for obtaining daily (or other) averages places a heavy burden on laboratory per-
sonnel. To minimize laboratory efforts while  obtaining meaningful data, a single sample may be
used by combining numerous discrete subsamples or aliquots. Such samples are referred to as
composites.  Composite samples will yield excellent average values, but cannot reveal peak and
low data points within a specified temporal interval (figure III-l).

     Composite samples can be readily obtained by merely collecting a containerful of waste-
water at regular intervals. For example, a half-liter sample can be obtained each hour over a
24-hour period, thereby resulting in a composite sample  of approximately 3 gallons.  Laboratory
results obtained by analyzing a single sample collected by this procedure, which can be referred
to as fixed time-fixed volume (TpVp), will closely approximate the average obtained by individual
analysis of each aliquot. Relatively inexpensive devices are available to automatically collect
TpVp composite samples.  This procedure is quite satisfactory for nonfluctuating flows.
                                             14

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       2000
       1500
    a"
    CD   1000
        500
                                                                                TFVF
            6A
                            12N
                                             6P

                                        TIME OF DAY
                                                            12M
                                                                             6A
                     Figure 111-1. Temporal fluctuations in a food plant waste load.

     When discharge flows fluctuate widely, a single aliquot in a TpVp composite may lead to
a misinterpretation of the composite sample analysis.  To minimize the effect of an individual
aliquot, flow-proportioned aliquots are taken.  For example, when aliquots are collected once per
hour, the volume should be adjusted according to the flow rate at that time (1 liter at 1000
gpm, 250 ml at 250 gpm, etc.).  This may be referred to as the fixed time-variable volume (TpVy)
procedure. This procedure (for which a few automatic sampling devices are available) will yield
laboratory results in close agreement with those obtained by the method explained in the next
paragraph.

     Best results short of continuous on-line analysis are obtained by analyzing samples com-
posited on a "per unit flow" basis, which is a composite consisting of aliquots, each of which
represents a unit volume of discharge  (e.g., per 1000 gallons).  Automatic  sampling equipment
operated in conjunction with various accurate flow-measuring devices are available for this pur-
pose. These samplers obtain  an aliquot of fixed volume for every 1000 gallons (or other unit)
of wastewater discharged (TyVp). Thus, representative samples are obtained regardless of wide
fluctuations in the discharge rate.


                                   SAMPLE STORAGE

     Since organic matter in wastewaters can degrade rapidly, it is important to analyze samples
as quickly  as possible to assure sample integrity and valid results. Analysis of composite samples,
by the nature of collection procedures,  must inevitably be delayed.  Therefore, these samples
must be iced or held under refrigeration during compositing and up to the time laboratory
analyses can be performed.  When unavoidable prolonged delays are anticipated, other preser-
vation techniques should be followed. These are discussed in greater detail in volume 2 of this
series, in the Handbook for Monitoring Industrial Wastewater1, and in Methods for Chemical Anal-
ysis of Water and Wastes3.
                                            15

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                                      Chapter IV


                                CASE HISTORIES


     This chapter contains several case histories which illustrate what can and has been done both
 inside and outside the processing plant.  In many instances, these case histories are examples of
 what was discussed in the first three chapters.

     Some of the measures taken by the processors may, at first, not seem to be economical in
 themselves. However, when compared with the cost of constructing a waste treatment system, the
 steps taken inside the plant may be a most attractive alternative.

     The case histories involve a variety of products and techniques. Examples are cited which
 reduce pollution, reclaim and recycle water, effect in-plant process modifications, reclaim valuable
 by-products, segregate and separate treatment of individual waste streams, and safely dispose of
 solid residuals.


                           ENVIRONMENTAL MOTIVATION*

     Top management alone makes the decision, "It is important. Let's do it."  Top management
 must let everyone down below know exactly what is to be done and see that it gets done.  It's the
 only thing that makes good safety and environmental programs.  It does not start from the bottom
 and work its way up, but rather  starts from the top and works all the way down or it does not work
 at all.  What exactly happens in top management to get one of these shows on the road? First, you
 or somebody gets top management's attention. Sometimes with a club or something slightly
 more subtle, like a trip to the D.A.'s office, or a fine and a threat from some regulatory agency
 to close the plant. Something subtle like that.

     When the preceding occurs, what is the thought process that causes top management to get
 with it? It is money. It is the fear of losing money.  If this fear is great enough, money will be
 spent to overcome the potential  loss, providing top management thinks the books will still balance
 after it is all over with. Otherwise, you close the plant and look for something else.

     Are the environmental accomplishments in industry in direct proportion to the degree that
 top management fears financial loss, due to regulatory actions? I think so.

     Look at environmental noise. About three years ago, most of us, at least in top management,
 knew very little about noise.  That was someone else's problem in the engineering department.  Then
 came OSHA.  Did we learn in a hurry! See what  I mean?

     We had a big problem with  acoustical surfaces being compatible as sanitary surfaces. We knew
of no answers, but we were highly motivated and we found them. Most of us know that the 90
decibel level is just a place to catch our breath. We better darn well be forging toward an 85 decibel
level because that's next. And we will do it for the same reason most of us are down to 90 now.
*Mr. Granville Perkins-Artichoke Industries, Inc., Castroville, California
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     It is amazing as we glance back for a moment how practical and innovative we have been. We
just started working really hard on environmental noise in the industry a little while ago, and we
started from a dead stop.

     Our accomplishments are not due to the relative amount of knowledge and expertise in an
environmental area. For example, we've known a lot about wastewater management and treat-
ment for a long time. The fruit and vegetable processing industry has made some worthwhile
accomplishments, but when measured against what kind of knowledge is available and what has
to be done, many of us have not measured up very well.

     Our in-plant environmental programs would be as good as most of our safety programs, if
we had been motivated as we were by our Workmen's Compensation Insurance premiums.  We
all recognize the futile waste and the pain of a serious accident. But believe me, a high experience
modification rating gets a lot of attention.

     My message to you is very simple. It requires the involvement of top management to make
these programs  work.  What is your company's environmental motivation?

     Over at Artichoke Industries, we have been just as typical as anyone. We think we have a
good record in safety. It was not always so.  We think we have a good record in many of our
environmental efforts. It was not that way in the beginning. We started just about at the bottom.
It has been a long, hard, expensive way up. But it has been worth it, because halfway up we
discovered that we were saving money, saving more money that we were spending. That really
gets to top management.

     We have proven this, time and again, and have preached about wastewater management and
in-plant modification. We now believe it is true in some other areas. Perhaps safety engineers should
concentrate on noise as a contributing cause of industrial accidents as much as they are preoccupying
themselves with the critical day concept of the biorhythm theory.

     Let's look at some profit for environmental programs. We need an experience modification
to promote our environmental task, and saving money might just as well be it.  I am not suggesting
that we forget over-taxation and over-regulation, but while we  are attempting to survive these
burdens, there are some positive economic advantages in upgrading our work place environment.

     None of us will deny that we have all contributed to various forms of environmental pollution.
We agree that we have a moral obligation  to clean it up.  But it does cost money. If it is accepted
that we must do it, we say it can be done profitably. How?  Because you cannot afford to do what
you're doing now. You cannot afford to  treat it or quiet it; you have got to reduce it.

     Our cost of energy is going up, up and up.  It costs a great deal less to treat one fourth as much
water at the same level of pollution.  The same is true of noise  and air pollution recovery systems.
Don't put it up there and you won't have to get it back down.

     The cheapest control measures available and the most effective usually attack the environmental
problem right at its source, be it water, air or noise.

     Now, I have just shared with you something you already knew, haven't I?  The point is, I think
it would be well for you to think about environmental motivation as it affects what you do and
how you do it.
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                                    CASE HISTORY I


          WASTEWATER TREATMENT AT ARTICHOKE INDUSTRIES 1955 - 1975*


     Artichoke Industries is located in Castroville, a town of 4000 people near Salinas. The town's
 major industries are two food processing plants and several fresh produce shippers.  Wastewaters re-
 sulting from these plants are discharged to the Castroville treatment facility which has a capacity of
 800,000 gallons per day.

     Artichoke Industries supports fresh artichoke shippers by converting small unmarketable
 artichokes into marinated and frozen artichoke hearts. The processing season covers twelve months
 of the year with peaks in the spring and fall.

     In 1955, Artichoke Industries contributed approximately 100,000 gallons per day (gpd) of
 wastewater to the treatment plant. In the following 3 years, while artichoke tonnage increased five
 times, wastewater discharge rose to over 400,000 gpd.  Concern over this large amount of water was
 secondary to production problems.  Meanwhile, the Castroville treatment facility increased its capac-
 ity from 800,000 gallons to over 1,000,000 gallons. During these years the frequency of visits and
 telephone calls by the Sanitation District increased logarithmically.  Sanitation officials were con-
 cerned that one morning they would find their plant in the ocean. Eventually, they managed to get
 Artichoke Industries' attention by threatening to fill the sewer line with concrete, unless action was
 taken to reduce the amount of water.  Zero discharge way back in 1958! Impressive, isn't it? From
 then on, wastewater management  became a part of doing business.  At that point, water driven
 hydroughts were used to trim artichokes which were then flumed with fresh water. This was thought
 to be the only way to slow enzymatic browning.  Much of the solid waste (approximately 60% in
 trimming an artichoke) was conveyed by water in gutters.

     An inventory of water usage  was conducted  and a program of water reuse and recycling was
 instituted. Water was reused as much as nine times prior to discharge. Over a period of 1 year,
 water usage was cut from 400,000 to 300,000 gpd.  However, due to the increased contact time
 of water and solids, the BOD concentration increased dramatically from 1500 mg/1 to 4000 mg/1.
 Further reductions in water use had to be made.  In 1961, the water-driven hydroughts were re-
 placed with mechanical trimming machines, designed to incorporate pneumatic separation of prod-
 uct and solid waste.  Additionally, screw conveyors were installed to carry  the solid waste to a
 hopper from where it is trucked to two dairies and used as cattle feed. Fog sprays now wet the
 product to slow down the browning. This modification resulted in a 100,000 gpd water reduction.
 Blanched artichoke hearts in the freezer production line, which up to now  had been cooled in a
 flume system, were now conveyed on a wire mesh belt through an ice water cooling tank, where
 the water is screened and recirculated. Instead of using fresh water in the blancher to compensate
 for what is lost by  steam and carried out with the product, excess cooling water resulting from the
 melted ice is pumped into the blancher.

     In 1965, a wastewater  ordinance was put into effect by the Castroville Public Works Advisory
 Committee limiting BOD, suspended solids, ether soluble materials and total flow. A base  flow of
60,000 gpd was established for Artichoke Industries. For a fee, additional capacity could be pur-
chased, if available. Total wastewater discharge at that time was still 120,000 gpd. In an effort

*Mr. Peter Luthi - Artichoke Industries,  Inc., Castroville, California
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to comply with these regulations, Artichoke Industries hired a consulting engineer who recom-
mended chemical precipitation. The facilities built included a 6000 gallon precipitation tank, a
60,000 gallon holding tank and a centrifuge to concentrate the sludge. After a year of operation,
performance of this precipitation unit was still far below desired levels. It was concluded that
such large quantities of water could not be handled satisfactorily by this method.  In addition,
the high pH of between 10 and 11 (which resulted from the addition of precipitation chemicals)
caused solids settling problems in the Castroville treatment facilities clarification process. There-
fore, precipitation was abandoned in 1969.  Based on an analysis of the specific gravity of the
suspended solids, it was concluded that floatation would be a more effective process.  In 1970, the
precipitator was modified into an air floatation tank. Realizing the large amount of water used
for the sanitation clean-up, efforts were channeled in that direction.

     With the system of screw conveyors available, it was possible to handle all solid waste dry.
The broom and squeegee became the two most important tools. All solid waste is pushed into the
screws before any water is used.  Then a gate is opened on a screw conveyor and water and solids
resulting from the clean-up operation pass over a vibratory separating screen which removes any
solids from the water. Steam mixing units with quick shut-off valves were installed to prevent the
waste of any water from unmanned hoses. This procedure, together with the installation of the
new clean-up stations, saved an amazing 20,000 gpd.

     Water usage in 1970 was between 45,000 and 60,000 gpd.  Of course you realize that I have
not mentioned all changes that were involved in reducing water use to this level.  There have been
many minor changes forgotten over the years.

     In 1971, with the help of another consulting engineering firm, a systematic survey of the plant
was conducted.

     •    First, a diagram of the wastewater system was drafted.

     •    This was followed up with a complete laboratory study of all wastewater streams.

     •    Discharge requirements were given consideration before deciding on a plan.

     A new wastewater ordinance passed in 1974 now limits BOD and suspended solids  discharge
to 500 mg/1. A  record of daily water discharge is required, and not more than 50 gpm may be
discharged for 90% of the time with maximum peaks of 100 gpm for the remaining 10%. Con-
tinuous composite sampling is required and fees are calculated on a per Ib. BOD, SS and per 1000
gallon basis.

     As a result of the plant survey, it was decided to segregate wastewater into three separate
streams.

     •    Low BOD waters resulting from container  coolers are now discharged directly. With a
          BOD of between 50 and  80/mg/l, this water could not be improved by treatment.  At
          the same time, the fan sprays that were used to cool the containers were replaced with
          fog sprays and large blowers to make use of the latent heat of evaporation.  Approxi-
         mately 14,000 gpd were saved with this step, and small glass containers can even be
         cooled without any additional water, using only the steam condensate on the  jars and
         air.

     •   The second category is medium strength wastewater between 1000 and 1500  mg/1 BOD
         resulting from clean-up. This water is passed over a 40 mesh screen and is then treated
         in the air flotation unit. A maximum of 40% BOD and SS reduction can be achieved
         with this system.

                                            19

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     •    High strength BOD water is the third category resulting almost exclusively from the
          blanching operation, in which vinegar or citric acid is used. Here, BOD is between
          20,000 and 30,000 mg/1.  In order to cut back on the volume, the blancher water in
          the marinated heart operation is wasted only every 5 days. Fresh water leaches solids
          out of the product being blanched. This mass transfer slows down as solids build up
          in the water. Also, weight loss of the product slows  down. This system uses five times
          less water than the old practice of using fresh water in the blancher every day.

     Secondary treatment was definitely needed to reduce BOD to an acceptable level. An exten-
 sive pilot study was conducted in 1972 comparing an anaerobic digestion and an activated sludge
 system.  The activated sludge system with extended aeration achieving 90 to 97% BOD reduction
 was ultimately  chosen as a permanent system. Medium strength water is used to dilute the high
 strength water approximately 5:1. Nitrogen and phosphorus have to be added to achieve the cor-
 rect BOD : N :  P ratio. The addition of storage tanks enables us to virtually treat 100% of the plant
 effluent during the low production season. Total discharge from our plant is now about 20,000
 GPD.

     In summary, I would like to review the guidelines that we have used for improving our waste-
 water system.

     •    Always keep water usage in mind when adding or changing process procedures.

     •    When possible, keep product and solid waste out of the water or minimize contact time
          as much as possible.

     •    Keep different wastewater streams segregated.

     •    Secondary biological treatment is  time consuming and expensive. The smaller the volume,
          the cheaper the price. The cost of our treatment amortized over a 10-year period at 10%
          interest on the  capital investment. Operating and maintenance cost is approximately 50tf
          per 1000 gallons.  Thus, the cost works out to be only about 25
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                                     CASE HISTORY II


                     IN-PLANT CONTROL OF WASTES AT RED WING*


     When thinking or talking about pollution, I'm reminded of a story about two kids from a
village out our way who are lying in the tall grass, beneath a tree, on a hill which overlooks a local
factory. It's autumn and the sky is blue.  Farmers are in the vineyards harvesting the crop and the
factory is issuing forth clouds of white vapor. Grapes are becoming wine. The aroma of the grape
is in the air. One kid turns to the other and says, "Isn't it great to live  in a town so small that even
the pollution smells good!"

     With the PSC, FPC, FDA, EPA and DEC, we can no longer use small or smell  as the criteria
for pollution.

     Pollution has many characteristics as follows:

     •    Oxygen depletion                    •   Toxicity

     •    Sediments                           •   Heat

     •    Color                               •   Nuisance factor and aesthetic factors

     •    Taste and odors                      •   Chemical exotics

     •    pH                                  •   Radioactivity

     It is true that " definitions " change with time, increased knowledge, and changes in adminis-
tration.  So stay abreast of rules and regulations set forth by DEC, EPA, etc. A few years ago the
village discovered abruptly that it had an overloaded waste treatment plant.  They had a problem
as did we because we are a substantial contributor to their system.  The village retained engineers
to design a new plant, that contained adequate allowances for our plant based on continued growth
over the years. Outfall sampling compared to present production was extended to allow for future
production. The estimated cost was astronomical! At this time, we asked to become involved in
selecting the design criteria for that part of the new plant affected by our operations.  We were
hoping for some other less costly alternatives.

     Four major courses were clear:

     1.   We could isolate our sewers from  the village and construct our own waste treatment
          system,  or

     2.   Construct a partial pre-treatment  plant and discharge wastes to the village, or

     3.   Curtail or eliminate some departments, or

     4.   Remain with the village and use part of the new system.
*Mr. Ralph W. Wilson The Red Wing Company, Inc., Fredonia, New York


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      We formed an "Industrial Waste Study Committee", which included people from the village,
 our factory, village engineers and our consulting engineers.  Our goal was the economical and effi-
 cient elimination of stream and lake pollution in accordance with present and proposed EPA and
 DEC trends.

      We used a two-fold approach as follows:

      •   We would work with local village officials, county and state health officers, and consult-
          ing engineers to obtain optimum waste treatment systems.

      •   We would involve ourselves with definitions and control of the variables involved, a con-
          sideration of alternatives and future plant operations.

      The action steps taken included:

      1.   Meeting with local administrators.

      2.   Initiating "Industrial Waste Study Committee".

      3.   Setting up sampling programs.

      4.   Deciding how to coordinate the program.

      5.   Paying for sampling.

      6.   Setting up sampling procedure, including such things as:

          a.   Establishing flow rates.

          b.   Waste characteristics.

          c.   Techniques of sampling.

          d.   Establishing industrial to domestic ratios - BOD's, etc.

          e.   Establishing industrial waste cycles.

          f.    Establishing peaks and lows for treatment plant.

     Next we had to:

     7.   Determine methods to handle waste.

     8.   Work to establish meaningful ordinances.

     9.   Negotiate a workable contract.

     Early on, we rediscovered that resource conservation is a source of company profit, although
it is not as well recognized as other principal sources of profits such as raw materials, human pro-
ductivity, facilities and market resources.  As previously mentioned, considerable sampling had
been conducted on the plant outfalls during the survey by the village's engineer.  However, little
of the sampling data had been analyzed in relation to the company's production. Furthermore,
those sampling results had been extrapolated according to water use trends and production in order
                                            22

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to estimate loads for 25 years into the future. Sampling was again conducted around the clock and
flow samples were composited proportional to flow, with analyses performed on individual
samples generally covering 4 to 8-hour shifts (although single days were periodically broken down
into hourly composites).  The significance of this sampling, when related to plant production, is
that it confirmed the need for in-plant sampling.  Wastewater sampling data must be related to
plant operation.  With this relationship in mind, it is possible to estimate the effect of increased
production on future  wastewater discharges.

     The wastewater analysis program at the Red Wing Company was divided into two parts:

     •    First, an extensive in-plant analysis was undertaken of individual process lines and
          the unit operation in each line. Sampling conducted under this part of the program
          was of many types—grab samples with measured flows, grab samples with  estimated
          flows, samples composited by flow, and samples composited with  time.

     •    Second, to confirm the reliability of this in-plant analysis, the total wastewater loads
          calculated from production records were compared against the results of a second
          sampling program on the control plant effluent.

     Results of our wastewater analysis program have been dramatic and very encouraging.
The following are some examples of cost reduction projects that were generated by  our in-plant
sampling program:

     1.   Purchase and install chiller on catsup pasteurizer for recycling of cooling water.

     2.   Purchase and install screening system for tomato wastes.

     3.   Purchase and install water chiller for starch cooking-cooling system.

     4.   Purchase and install conveyors for pulping wastes (tomato and grape).

     5.   Provide for collection and re-processing of tomato products washup.

     6.   Provide for collection and disposal of  preserve and jelly cleanup.

     7.   Programming of production schedules  to reduce washups.

     8.   Pre-treatment and filtering of wash water from tank cleanups.

     9.   Provide a recycle system for compressor seal water to cold room defrost and back
          to seal water (recycled BTU's as well).

    10.   Pressurize recycle systems to compete with city water pressure.

    11.   Application  and approval for permit to discharge.

    12.   Install solenoid valves, as a standard practice, on makeup, seal water, cooling water,
          and other systems which operate intermittently.

    13.   Pick up and shovel up—don't hose down!

    14.   Use cleaners that tend to neutralize your process. For tomato process, use caustic,
          not chlorides!
                                           23

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    15.   Provide separate recycle system for #4 refrigeration compressor and for cold rooms
          1, 2, and 3.

    16.   Provide separate recycle system for #4 tank room defrost operation and for cold rooms
          1, 2, and 3.

    17.   Provide recycle system for cookroom vacuum pump seal water.

    18.   Recycle cooling water from Cochrane Becker pumps.

    19.   Pipe spent cooling water from Joy compressor as makeup for defrost.

    20.   Install cooling tower for grape juice heat exchangers.

    21.   Send distilled water from essence unit to defrost, then to no-name creek.

    22.   Better control of  overflow on #1 and #2 J&J pasteurizers.

    23.   Rapid repears on  hoses, valves and  fittings.

    24.   Standardize on pistol grip nozzles.

    25.   Eliminate slug loads.

     The results have been encouraging, for it is now possible to accurately  predict industrial
 wastewater discharge loading for a particular  day.  In  addition, it is now known which produc-
 tion operations will result in large waste loadings and  which operations do not. By knowing the
 individual flows that do  attend each process,  it is possible to recognize when processing personnel
 become careless and discharge more than is necessary  for a given unit operation.

     The plant engineering department has also worked very closely with the sales and production
 departments of the company to develop a production schedule that eliminates the peaks in waste-
 water  discharge, while at the same time reducing the absolute quantity of waste discharge.  This
 is possible because many of the wastewater discharges result from individual process lines and
 equipment washups. When  equipment washups are eliminated, wastewater load goes down.
 The improved production scheduling system,  called the "Rajat Plan" (after the business admin-
 istration student who developed it), breaks down the plant operations in the jams and jelly
 department into a 32-day cycle of product manufacturing sequences.  This incorporates four
 8-day  subcycles.  Following this system, it has been possible to cut weekly discharges by
 hundreds of thousands of gallons in flow and by tons of BOD and suspended solids.  As a
 result, production efficiency has increased, while saving thousands of  dollars.  Before  the plan,
 there were 25 departmental washups per week as opposed to 10 per week now.  This has
 produced $75 of product saved per washup and $200 in labor cost per washup.

     Another in-house procedure that has resulted in great reductions of waste loading is in the
 catsup process lines.  Prior to the waste analysis program, lines and tanks were flushed to the city
 sewer at the end of the production run.  Analysis has shown that even after hundreds of gallons
 of wash water have passed through the system, the "wash water" still contains a much higher
solids content than that of the original raw material. This is due to the concentration that occurs
in evaporating tomatoes.  By diverting the initial wash water to refrigerated storage vessels and
recycling it into the next production run, the Red Wing Company has increased product yield.
The savings amounts to $100 per day, while keeping 500 Ibs of BOD out of the sewers.
                                            24

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     In addition to the range savings accomplished because of in-house cleanup, as well as reduction
in wastewater discharge through production scheduling, the company has been able to substan-
tially revise the design loads for the new municipal wastewater treatment plant.  The major
strength in this program of "resource conservation through waste analysis" is that the responsi-
bility for improvement is spread over hundreds of employees.  Each departmental manager, fore-
man, and machine operator has the opportunity and responsibility for improving operating
practices, upgrading equipment, improving maintenance, and taking other measures necessary to
minimize the amount of waste  discharged into the sewers.  Many of the techniques have initial
capital costs, but these costs are often repaid several fold over a very short period of time. This
was the case  in our "Rajat Plan".  The development of resource conservation is indeed helping
us to increase profits  at the Red Wing Company.
                                            25

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                                    CASE HISTORY III


                     WATER POLLUTION CONTROL - FRITO-LAY. INC/
 INTRODUCTION
      During the last three years, Frito-Lay, Inc. has been engaged in a study to develop the tech-
 nology required to pretreat its wastewater. That portion of the study concerned with suspended
 solids removal is presented below.
 BACKGROUND INFORMATION

      Frito-Lay, Inc. markets approximately 90 different snack foods.  Most of these are manu-
 factured by Frito-Lay, Inc. in nearly 40 manufacturing locations.  Of the snack foods produced,
 only three utilize water in their manufacture:  Lay's® brand potato chips, Fritos® brand corn
 chips, and Doritos® brand tortilla chips.


 Potato Chips

      In production of potato chips,  the potatoes (either clean or covered with farm soil) are de-
 livered by truck or rail car and placed into raw material storage. They are then taken from storage
 and conveyed to a degritter/destoner. The destoner removes the majority of dirt, sand, and bits of
 rock which come in with unwashed potatoes.  After the potatoes have been initially washed, they
 go to a peeler which abrasively removes the outer skin. From the peelers, the potatoes move along
 the production line where they are inspected for quality, raised in a vertical lift, and conveyed to
 the slicer.  The potato slices then drop into a washer which removes the starch and sugar clinging to
 the surface. From there, the potato slices are rinsed, fried, and packaged.


 Corn Chips

     In the corn chip production process,  a special mixture of corn is cooked, steeped, and washed.
 The corn is then milled for frying. The chip is fried, salted, and packaged.


 Tortilla Chips

     In tortilla chip process, the corn is cooked, steeped, washed, and milled as in corn chips.
Dough from the mill is pressed  into a triangular shape and fried. Salt and necessary flavorings
are added prior to packaging.
*Mr. William F. Priebe - Frito-Lay, Inc., Irving, Texas
                                            26

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HISTORY

     Until recently, the company's basic philosophy of disposal of water-borne waste was to pur-
chase these services from municipalities, since they could handle the effluent more efficiently than
Frito-Lay, Inc. In light of this approach, the company located plants in or near municipalities
which had adequate treatment facilities.

     Several events occurred which caused a basic change in this philosophy. One was the passage
of the 1972 water pollution act which included provisions opening the door for substantial in-
creases in sewage rates. Another was the fact that some of the municipal treatment plants had become
inadequate to handle the demands placed upon them by the city's growth.

     In many of the smaller communities where the problem  was most acute, we were significant
contributors. In these communities, we were faced with both moral and economic incentives to
ease the burden on local treatment plants. A good example was Irving, Texas, where one of the
company's plants is located. The lagoon system, operated by the Trinity River Authority (TRA),
had become overloaded due to rapid growth of the city of Irving.  Frito-Lay was requested to aid
in solving the problem. After exploring various alternatives, it became evident that the best solution
was to provide pretreatment at our Irving facility easing the waste burden to the TRA plant.  At
this time, the company had basically no technology which would make pretreatment possible. In
order to allow time to develop the needed technology, liquid  cyclones and screens were temporarily
installed on processing lines.  A program was immediately initiated within Frito-Lay to develop more
satisfactory wastewater treatment systems.


DETERMINATION OF A BASIC APPROACH

     There were two basic approaches as follows:

     •   One, develop a system which combined all effluent into a single stream, treat and dump
         it into the city sewer.

     •   Two, to separate the various waste streams allowing recovery of valuable by-products
         and reuse of some of the wastewater.

     Even though the latter solution required a larger capital expenditure, the potential return on
investment of the divided flow system influenced the company to orient its research  in this direction.

     In dividing flows, it became a matter of choosing which flows carried the greatest possibility
of by-product recovery. It was decided to split the stream from the plant into three wastewater
flows—potato preparation water, the potato chip slice wash water, and the corn wash from both
tortilla chips and corn chips.  The potato preparation water contained potato peels which had value
as animal feed.  The potato chip slice wash contained potato starch, and the corn wash contained
corn fibers, protein, and corn starch which had use as animal feed.


CHARACTERIZATION OF WASTE

     The first step in developing pretreatment was to characterize the wastewaters. It became
immediately evident that the high concentration  of suspended solids in  each waste stream was par-
tially responsible for the high BOD. If the suspended solids could be removed, it would remove large
quantities of BOD.
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      The first stream to be characterized was the potato preparation water. The potato preparation
  area consisted of washing, peeling, and rinsing operations. The operations generated about 90 gal-
  lons per minute of wastewater. The wastewater had moderate-to-high suspended solids, but some-
  what lower BOD since most of the suspended solids were sand and soil (see table IV-1).
                                 Table IV-1.-Characterization of wastewater
Process
Potato preparation wastewater
Potato chip slice wash
Tortilla /corn chip wash water
Flow
gpm
90
100
200
SS
mg/l
2000
2900
2800
BOD
mg/l
1100
2200
3600
      The potato chip slice wash was the second stream to be characterized.  This was starchy water
 with high BOD and suspended solids. The material in the water was made primarily of the potato
 starch granuals released during the slicing process. The BOD, suspended solids, and flow values are
 given in table IV-1.

      The third waste stream to be characterized was the corn water generated by the corn chip and
 tortilla chip process. This water had a fairly high pH and consisted primarily of products of corn
 degenerating during the cooking process (gelatinized starch, the germ and cellulose). This waste was
 characterized by extremely high BOD and suspended solids.  The BOD was also different in nature
 from the potato streams in that the starch was typically gelatinized which made it much more
 soluble and the suspended solids had a gelatin-like consistency. The  BOD, suspended solids, and
 flow values are also shown in table IV-1.
 PILOT TREATMENT STUDIES

      From waste characterization data, the decision was made to concentrate initial efforts on sus-
 pended solids removal.  Based on laboratory tests, two pieces of equipment were leased for testing
 at the Irving plant.  The equipment consisted of a settling basin for the potato processing streams
 and a flotation unit for the corn processing stream.


 Potato Preparation Water

     Laboratory studies indicated that with the addition of alum and an anionic polymer, the sus-
 pended solids could be reduced 90% by settling.  A lamella type settling basin was used to pilot test
 the lab results because of space limitations. The results, shown in table  IV-2, indicated greater than
 90% removal of suspended solids and greater than 50% removal of BOD.


 Potato Chip Slice Wash

     The laboratory studies indicated that the slice wash suspended solids would settle although no
suitable flocculents were found. The lamella type clarifier, when used, reduced suspended solids
over 90% (table IV-2), and the BOD by over 75%. The starch removed by the clarifier was found
to be marketable.
                                            28

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                             Table \V-2.-Pilot test results
Process
Potato preparation
water clarifier
Potato si ice
wash clarifier
Corn wash
flotation unit
Parameter
Flow
SS
BOD
Flow
SS
BOD
Flow
SS
BOD
Influent
90gpm
2000 mg/l
1100mg/l
100gpm
2900 mg/l
2200 mg/l
200 gpm
2800 mg/l
3600 mg/l
Effluent
1 50 mg/l
520 mg/l
200 mg/l
500 mg/l
400 mg/l
2200 mg/l
% Removal
92
53
93
77
86
39
Corn Wash

     Also based on lab studies, a pilot scale flotation unit was leased for testing on the corn wash.
The flotation unit was equipped with lamella plates to decrease the Reynold's Number. Over 85%
of the suspended solids were removed (table IV-2) and almost 40% of the BOD.


FINAL INSTALLATION

     The treatment schemes shown in figures IV-1, IV-2, and IV-3 were the ones used in the final de-
sign. Because of the company's intention to conserve water by means of recycle after pretreatment
and to sell the by-products, all chemicals used had to be potable water or food grade and all equip-
ment had  to be made of either plastic or stainless steel.
Potato Preparation Water

     The water from the potato preparation area was taken to the wastewater treatment room where
it was screened to remove the peels.  Chemicals were added for flocculation and the solids were
settled in a lamella clarifier. Some of the overflow was recycled back to the peelers. The remaining
water was discharged. The sludge from the clarifier was dewatered, mixed with other sludge from
the treatment plant and sold.  The final installation failed to give the anticipated^effluent quality
(table IV-3). A surging problem caused by an oversized pump caused some of the lighter particles
to remain suspended. A replacement pump is scheduled to rectify the problem.
Potato Chip Slice Wash

     The water from the slice washers was taken to the waste treatment room where the slices and
slivers were screened.  The water was then settled in a lamella type clarifier.  Part of the overflow
was returned to the vertical lifts; the rest was discharged.  The underflow was collected and sold as
potato starch.
                                           29

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                                                                                      From slice wash clarifier
W
o
                                                      Pump
                                                                                                                                                         Pump
                                                                                                                                           Discharge
                                                   Figure IV-1. Treatment scheme for potato preparation water with recycle.

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                                                                                                                                            To vertical lift
00
                                                                                                                                                         Pump
                                                    Figure IV-2. Treatment scheme for potato chip slice wash water with recycle.

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                                                                   Recycle to com washer
Co
to
                                                                                                                                                   Pump
                                                                                                                         Discharge •
                                                        Figure IV-3. Treatment scheme for corn wash water with recycle.

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                          Table \V-3.-Results from full scale installation
Process
Potato preparation
water clarifier
Potato slice wash
clarifier
Corn wash flotation
unit
Test
SS
BOD
Flow
SS
BOD
Flow
SS
BOD
Flow
Anticipated
effluent
1 50 mg/l
520 mg/l
90 gpm
200 mg/l
500 mg/l
100 gpm
400 mg/l
21 00 mg/l
200 gpm
Actual
effluent
370 mg/l
400 mg/l
90 gpm
281 mg/l
640 mg/l
170 gpm
420 mg/l
1 200 mg/l
200 gpm
     The BOD and suspended solids in the overflow from the clarifier were ^lightly higher than ex-
pected (table IV-3). Since the pilot testing, installation of a new slice washer caused the flow to in-
crease by 70%, overloading the clarifier.


Corn Wash Water

     The corn wash water was screened in the wastewater treatment room.  After chemical addition,
it entered the flotation unit.  Part of the underflow from the flotation unit was recycled back to the
corn washers and the rest was discharged.  The sludge was combined with the potato preparation
sludge, dewatered and sold as animal feed.  The flotation unit performed as expected in suspended
solids removal, but did substantially better in BOD removal (table IV-3).


INSTALLATION ANALYSIS

     The final installation accomplishes the objectives of the Frito-Lay pretreatment study.  Sus-
pended solids have been reduced to levels slightly above predicted values.  BOD has been reduced
to less than anticipated concentrations. Fifty percent recycle has been achieved thus far. Investi-
gation is  still in progress to determine where recycle can be increased. The sludge from the potato
preparation clarifier and flotation unit is being sold as animal feed and the slice wash clarifier under-
flow has  been processed into  edible potato starch. Data from the installation indicates that the
effluent from plants processing potato chips, corn chips, or tortilla chips can be successfully pre-
treated with the systems described.
                                             33

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                                   CASE HISTORY IV
                          IN-PLAIMT CONTROL TECHNOLOGY
                             FOR A CARROT PROCESSOR*
     Plant "A" processes frozen carrots. The plant operates on a typical schedule of 5 days per
week, 10 to 11 months each year.  Normal production is set for two shifts per day with addi-
tional cleanup time as needed. Average throughput is approximately 8 raw tons per hour.

     Figure IV-4 is a flow diagram of this plant's operation prior to 1974.  As shown, the manu-
facturing processes were quite typical. Carrots were delivered in bins either directly from the
field or from a fresh sorting shed.  They were washed, trimmed, conventionally lye peeled and
diced or sliced. Blanching was accomplished by means of a water blancher; post blanch cooling
was by  water.  Water usage was high with a daily average approaching 1.5 mgd:  BOD levels were
similarly high averaging about 2400 mg/1.

     This plant, landlocked by city growth, was already paying a surcharge for its effluent dis-
posal, but the city, recognizing that expansion was needed for industrial users, initiated discus-
sions for a revised surcharge system.  The tentative proposed surcharge formulae indicated that
if this system was adopted, monthly  discharge rates would approach $4,000.

     At this point, corporate management decided to institute changes in the form of capital
investments.  The engineers, when designing modifications, considered each waste-contributing
point within the processing sequence. Figure IV-5 shows the results of these efforts, while
table IV-4 shows the benefits.
CARROT WASHING

     Water used to wash the incoming carrots had previously been combined with the main plant
effluent stream. However, observation and testing of this stream indicated that its chief com-
ponents were sand and dirt, some field debris, and occasional carrot particles.  Because  of the
plant's location, they decided to isolate this stream from the higher concentration waste streams
and discharge it separately under NPDES permit. A double screening system was installed  to
effectively remove the various solid particles from the waste stream. This not only lowered the
suspended and settleable solids but also,  in part, contributed to reduced BOD discharge. Freezer
defrost water was also diverted to merge with this stream.

     The effect of this separation should not be underestimated.  These two components are
responsible for approximately 60% of the total plant flow or about 350,000 gallons per day.
The alternative  discharge of this large volume of water to a city sewer system would have been
extremely expensive.
*Mr. Kenneth V. LaConde and Mr. Curtis J. Schmidt — SCS Engineers, Long Beach, California
                                           34

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   Bins
       Liquid
       waste
   Wash
  Lye peel
   Trim
 Dice/slice
Water blanch
Water cool
  Freeze
                           Dirt, solids
                           Solids, lye
                             Solids
                             Juices
                          Organics, solids
-- 1
 H
                            Organ ics
                                                    I
        City
        sewer
      Figure IV-4. Original flow, carrot processor "A".
                         35

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Solid
waste
                 Lye-peel
                 Slurry
Solids
disposal
 Bins
                                           Wash
Dry
caustic
peel
                                           Trim
                                            Dice/
                                            slice
                                           Steam
                                           blanch
                                            Air
                                            cool
Freeze
                                                  Liquid
                                                  waste
                                                                Dirt, solids
                                                                               Separate
                                                                               discharge
                                                                      Juices
                                                                    Condensate
City
sewer
                        Figure IV-5.  Modified flow, carrot processor "A"
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                          Table IV-4. - Carrot process "A", parameter differences
Parameter
Flow (mgd)
Flow ratio (gal/ton)
BOD (mg/l)
Sliced recovery (%)
Diced recovery (%)
Monthly surcharge ($)
Before
1.5
9375
2400
50
65
4000*
After
0.6a
3750
1600
62
72
500
                'Estimated
                0.35 mgd discharged under NPDES permit, 0.25 mgd to city.
PEELING

     The peeling process was identified as the main source of BOD and SS generation. The water
required for peel removal was a substantial percentage of the plant's total effluent. A new lye
peeler (ferris wheel type) was purchased and installed. The conventional, high-pressure water,
lye peel removal system  was replaced with a Magnuscrubber. The resultant peel waste slurry was
pumped directly to a holding tank.  Ultimate disposal of this waste fraction is to a sanitary land-
fill.  Note in table IV-4 that in addition to the expected water usage and BOD reductions, finished
product recoveries increased for both sliced and diced. These increased yields are a direct result
of the new peel removal system. Although numbers were not available, the plant personnel
were also aware of a reduction in lye consumption.
DRY SOLIDS HANDLING

     The plant engineers recognized that every attempt should be made to stop the introduction
of solid wastes into the  effluent stream.  The  original plant flow allowed for trimmings and
solid waste to be flushed into gutters with final screening before discharge to the city sewer
system. This allowed for additional leaching of soluble solids and was, in part, responsible for
the plant's high BOD. To overcome this problem, a separate series of dry  solids conveyors were
installed to transport trimming table and other wastes directly to outside  waste bins. Further,
a concerted effort was made by management to instruct  plant employees  on proper methods of
solid waste handling.


BLANCHING

     As shown in figure IV-4, a hot water blancher had been used over the years. Enzyme deac-
tivation and product quality met the  necessary criteria for continued use.  Water blanchers,
however, have been shown to be a major  source of water pollution.  The action of solids leach-
ing, continuous spillage and overflow contribute heavily to a plant's  BOD and SS loads. The waste
stream is not only concentrated,  but  is of substantial volume. The old water blancher was re-
moved and a steam blancher was installed. The only effluent from this unit process is a highly
                                             37

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concentrated 1-2 gpm condensate.  The effect on total BOD and SS load has been considerably
lessened, while maintaining desirable product quality characteristics.


COOLING

     Similarly, post blanch hydrocooling, which is necessary to prepare carrots for freezing and
to optimize  freezer efficiencies, was determined to be a contributor to the plant's effluent load.
Total elimination of the flow was the objective. The conventional hydrocooling system was re-
placed with  an ambient air cooler. Working on a fluidized bed principle, the product exits the
blancher and is blown and vibrated over perforated screens by the action of air jets blowing through
and upward  to contact the product. The action of the air and the  mechanical vibrations of the
screen move the  product across the screen during which the required cooling  gradient is achieved.
The use of air eliminates almost all water contact after blanching, with the exception of one or
two fine water sprays between the blancher and cooler.  Water usage at this stage was estimated
at no more than 2  gallons per minute.


CAPITAL INVESTMENT

     The plant estimates their total expenditure for all the improvements and  modifications to be
approximately $90,000. Although no attempt was made  to calculate paybacks on investment
capital, it can be seen in table IV-4 that savings due to reduced discharged volume and pounds
of pollutants to the city, amount to approximately $42,000 per year.  If one  were to add a
monetary value to the increased yields, the investment looks even more attractive.


WASTE MANAGEMENT

     We have briefly reviewed the components of a revised, modified and updated carrot processor.
We have alluded to  an active management role and corporate confidence in terms of capital in-
vested.  One personal observation should be added at this point. All of the employees seemed to
be cognizant of management's attempt to reduce both solid and liquid wastes. The plant was a
model of cleanliness. They all appeared involved, concerned and willing to do  their share to help
management achieve its goals.
                                             38

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                                    CASE HISTORY V


                       IN-PLANT WATER AND WASTE CONTROL*


     To me there are two basic methods of in-plant water control:

     1.   Training of personnel.

     2.   Plant and equipment design technology.

     The water used in each of these two methods can be categorized as cleanup water and
process water.

     Consider process water first since  its method of conservation lies primarily in the plant and
equipment design fields. Equipment manufacturers have made great strides in the construction and
design of food processing machinery to facilitate minimum use of process water. This is being
accomplished through cooperation and testing by the food processor.

     At Stayton, we are continuously striving to design, construct, and purchase equipment
which lends itself to pollution abatement.  One such piece of equipment is the air cooler  which
has taken the place of water spray cooling and flume cooling in many areas. Stayton was  one of
the pioneers in this field and experimented with its first air cooler in 1969. Since then  air coolers
have become a commercially manufactured item and Stayton operates seven units at three of its
plants. Water savings is estimated at about 87% in terms of volume. Another process currently
being used at the Stayton plant is the dry lye  peeling of carrots. This process results in less
water being used but poses a problem of pH neutralization and utilization of the sludge being
generated. We are now working with several organizations to find an effective means of develop-
ing this sludge into a useable by-product.

     Isolation of receiving areas can also play an important part in water conservation. In many
cases, large receiving areas are necessary to keep enough product on hand for optimum plant
production. It is often economically feasible to divert runoff from these receiving areas to
storm drains during winter months. It is not uncommon to find roof gutters and downspouts
which discharge to process gutters in the plant. These should be relocated and/or rerouted to
appropriate storm drain areas to eliminate treatment.

     Cleanup and sanitation is of primary importance and concern to all food processors.  Strict
regulations imposed by FDA and USD A make it imperative that plants be clean and sanitary.
How do we accomplish this?  We use water. No  matter how many conveyors are eliminated, no
matter how many water saving devices are manufactured, they all have to be cleaned at regular
intervals.

     Many things can be implemented to reduce water consumption, such as trigger nozzles on
cleanup hoses, dry collection of solids where possible, and the elimination of water as  a conveying
medium.   In addition, high pressure, low volume cleanup systems are commercially  available but
these may be detrimental to bearings and paint on conveyors and equipment.
*Mr. Joseph E. Cogar — Stayton Canning Company Cooperative, Stayton, Oregon
                                             39

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     One of the most important methods of water reduction is a complete and comprehensive
training program of everyone involved in production and sanitation. Nearly all plumbing and
piping systems are over designed, i.e., pipes are usually selected at the next larger size to assure
adequate volume to a piece of equipment. I don't know about other plants but I can seldom go
into one of our plants and find a globe or gate valve 1/2 or 3/4 open. They're either open or closed.
In most cases, this is unnecessary. One way to get an employee's attention is to point out that the
water being used is being paid for twice:  once to obtain it and once to get rid of it.  Last year at
our Salem plant, for instance, incoming water cost in excess of $8,000 with a proposed rate increase
upcoming.  Proposed sewer charges for the same plant are to be more  than $120,000.  The Stayton
plant pays more than $35,000 per year for its water and about $160,000 for expansion of the
spray irrigation disposal facilities.

     In conclusion, it is hard to imagine a drastic overall reduction in water usage if food processors
intend to keep pace with the growing population. The cost of treatment can come only from the
consumer. However, the industry must make every effort possible to  keep these costs at a minimum.
                                          40

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                                   CASE HISTORY VI


                       HEAT RECOVERY AND WATER RECYCLE*
     The Aunt Nellies company was faced with the problem of discharging hot, relatively clean
can cooling and "cushion" water. The permit for its discharge called for the water not to exceed
89  F. The permit also had a BOD limitation which could not be exceeded, with few exceptions.
Rather than simply install a cooling tower to  remove the heat and then discharge the water,
consideration was given to methods of using the heat and water to the company's advantage.

     The first step was to take an inventory of in-plant operations which used hot water and to
develop the necessary mass balances.  Next was to develop the available sources of hot water
and potential reuse sites, providing heat  was removed and the water was re-chlorinated.

     After several months of planning and gathering of the  data, a system was designed  to incor-
porate heat  recovery and reuse of water from the retorts and cooler systems.  A schematic of
the system is indicated in figure  IV-6. Temperature, volume and source of water are also given
Values which indicate temperature changes, and to some extent the volume of water, are
engineering estimates.  The system is nearing completion and will soon be tested.  From this
test, some adjustments may  be made in  the temperatures or in the volumes of water.  An
8000-gallon cooling canal was constructed to  cool cans from the still retorts. Two 8000-gallon
holding tanks were also constructed adjacent to the cooling canal. Some 1400 feet of 2-inch
pipe was installed in the two holding tanks.  Water from holding tank 1  overflows into tank 2.
Excess cooling canal water also overflows into tank 2.

     The sequence of operations, as depicted  in figure  IV-6, is as follows:

     •   The retort cooling water is collected and discharged into the first holding tank.
         This water comes from continuous cooker-coolers and is estimated to be 150° F at a
         rate of 400 gpm.  Provisions have been made to divert from the system water less
         than 150°F.

     •   Water is withdrawn from the entrance of tank 1  and is pumped to the still retorts.
         This water is used to cushion  the cans as the retorts are being filled.  The tempera-
         ture of this water is approximately  160°F.  Once the retorts are filled, the water is
         returned to holding tank 1.  The volume of this water is not recorded because equal
         quantities are removed and then returned to tank 1 for each cycle of operation.  One
         purpose in returning the hot water back to tank  1 is to increase the temperature of
         water  being pumped through the 2-inch coiled pipe.

     •   Water exiting from tank 2 will be approximately  120°F.  This water will pass over
         a cooling tower at 500 gpm.  It is expected that there will be  a 40-degree drop in
         temperature, resulting in water being cooled to 80° F.   The 500 gpm rate is a
         composite of the 400 gpm from the retorts and the 100 gpm from the cooling canal.
*Mr. David D. Albright and Edwin F. Pleus - Aunt Nellies Foods, Clyman, Wisconsin
                                            41

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                         300gpm 80°F
                                                                                    100gpm 53°F
                                                                                    well water
Brine
Boiler feed
Topping
120 gpm
53° F well water
                                    150gpm 80°F
                                    For vegetable wash, gutter flush, etc.
                 Figure IV-6.  Schematic for heat recovery and water recycle.
                                             42

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     •    The 80° F water from the cooling tower will be collected in a surge tank and used in
          three ways. After filtration and chlorination, some 300 gpm will be recycled back as
          retort cooling water.  While there, some 100 gpm of well water will also be used in the
          coolers. Some 50 gpm of this cooling tower water and 50 gpm of well water will be
          introduced into the cooling canal. The remaining 150 gpm, which is excess water from
          the system, will be used for initial raw product washing, flushing of gutters and other
          plant uses which do not require potable water. This excess 150 gpm is the result of
          using 100 gpm of well water for the coolers and 50 gpm for the cooling canal. Rather
          than simply being discharged to the gutters directly, secondary uses have been found
          for it.

     •    Well water, at 53°F and at 120 gpm, will be pumped through the 2-inch pipe that is
          placed in holding tanks 1 and 2. It is expected that the water will exit from tank 1 with
          a temperature of 140°F.  This water will then be used principally for brine make-up
          with smaller quantities used for boiler feed make-up, as topping water, and possibly
          other  areas in which hot, potable water is required.  The well water as it passes through
          the pipe takes up heat and cools the retort and cushion water.  The advantages of this
          approach are to obtain heated water without putting energy into the system and to
          reduce the temperature of water to be treated by the cooling tower.

     The projected  cost for the entire system is $50,000.  It is estimated that there will be a water
savings of at least 375 gpm or 54,000,000 gallons per year. This will amount to a savings of
$10,800 per year, using a cost of 2 cents per 1000 gallons of water. Savings in water costs would
be greater in  areas which have fresh water costs greater than 2 cents  per 1000 gallons. The esti-
mated fuel savings for the system is  $33,000.  This is a result of the 53° F water being increased
to 140°F.  The cost estimate is based on using $2.50 per million BTU's.  With fuel costs rising,
and given the ever increasing need to conserve energy, this part of the  system appears to  be very
attractive.  The total savings  are projected to be $43,800 per year for a $50,000 investment.
                                            43

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                                  CASE HISTORY VII
                           SNOKIST GROWERS CANNERY*
INTRODUCTION

     Snokist Growers, a cooperative, operates a pear, apple, peach, plum, cherry and apricot
cannery in Yakima, Washington. The principal products are pears and apples.  The pear process-
ing occurs in Hie fall  when the cannery capacity is upwards of 250 tons per day.  Apple process-
ing occurs later in the fall and through the winter at from 50 to 150 tons per day in a variety
of products including apple rings, apple slices and apple sauce.  Unit wastewater flows and
waste loads from the  cannery are shown on table IV-5. Total discharge from the cannery
amounts to from 1.5  to 2.0 million gallons per day of flow during peach and pear processing
and from .5 to  1 mgd during apple processing.
                            Table \V-5.-Unit waste contribution

Product

Pears
Peaches
Apples
Flow
(gal /ton
Material
processed)
5,800
7,500
8,200
COD
(Ib/ton
Material
processed)
105
98
71
BOD
(Ib/ton
Material
processed)
78
66
53
     During 1966, the state of Washington's Water Pollution Control Commission  (WPCC) di-
rected Snokist Growers to upgrade their effluent to a BOD reduction of 90% by the 1968
processing season. The WPCC also wanted 70% BOD reduction by the 1967 processing season.
Snokist Growers embarked on a research,  development and demonstration project which was
partially funded by a grant from the Federal Water Quality Administration.  The project was
to provide biological treatment for the company's  wastewaters. Aerated lagoon treatment
systems and activated sludge pilot studies  were to be accomplished during the 1967 processing
season, and a full scale  activated sludge plant was to be in operation during 1968  for demon-
stration of biological treatment technology.
*Dr. Larry A. Esvelt — Bovay Engineers, Spokane, Washington
                                          44

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BIOLOGICAL TREATMENT OF FRUIT PROCESSING WASTES

    During the 1967 processing season, parallel systems of an aerated lagoon for about 85% of
the wastewater and activated sludge for 10-15% of the wastewater were used to treat Snokist
Growers effluent (see figure IV-7). The results of this testing are shown on table IV-6. The
aerated lagoon was constructed with surface aerators and was provided with a PVC lining.  The
lining failed during that operating season and was replaced during the following season with
the same material containing a rock cover to prevent flotation and  to prevent hydraulic stresses
from separating the seams.
               Table IV-G.-Treatment system performance 1967-1968processing season


Pear processing
Peach processing
Apple processing
(Nov., Dec.)
Apple processing
(Jan., Feb.)

Pear processing
Peach processing
Apple processing
(Mar., Apr., May)
Screened waste
Flow
(mgd)
1.03
1.36
0.60
0.52
BOD
(mg/l)
2,040
1,810
1,230
950
COD
(mg/l)
3,050
2,150
1,520
1,400
Screened waste
0.21
0.30
0.40
2,040
1,810
1,390
3,050
2,150
1,830
Aerated lagoon effluent
BOD
(mg/l)
370
340
190
110
COD
(mg/l)
1,040

760
620
SS
(mg/l)
770
830
540
470
Activated sludge effluent
250
360
130
490

570
375
370
470
     A full scale, activated sludge system was used during the 1968 processing season.  It had
the capability for sludge reaeration by upgrading the aerated lagoon to an aeration basin with
additional aerator capacity, clarification and sludge return pumping capabilities and a sludge
thickener (see figure IV-8). Results from the 1968 treatment experience are shown on
table IV-7.

     Snokist  Growers' studies during the 1967 and 1968 processing seasons resulted in the
collection of considerable data which was analyzed for use by other fruit processors in the de-
velopment of biological wastewater treatment systems.  The rate of pollutant uptake by  the
biological organisms was developed and presented.  This is shown on figure IV-9. The tempera-
ture relationship of the substrate removal rate for the biological organisms is shown on figure
IV-10. Table IV-8 shows the summary of the sludge yield coefficients for various fruits processed.
Figure IV-11  shows the endogeneous respiration rate of the organisms according to temperature.
                                           45

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Table IV-7. -Treatment system performance 1968-1969 processing season



Pear processing
aerated lagoon
Peach processing
aerated lagoon
Peach processing
activated sludge
Pear processing
activated sludge
Pear processing
activated sludge
w/sludge reaeration
Apple processing
activated sludge
Screened waste
Flow
(mgd)
1.48

2.02

2.02

1.87

1.58


0.43

BOD
(mg/l)
2,080

860

860

1,600

2,150


1,190

COD
(mg/l)
2,870

1,510

1,510

2,290

2,910


1,500

Effluent
BOD
(mg/l)
460

115

20

9

4


5

COD
(mg/l)
1,050

710

120

55

23


28

SS
(mg/l)
640

520

66

15

6


11

                Table \\J-Q.-Sludge yield coefficients
Product being processed
Pears
Peaches
Apples
Sludge growth
constant
mg VSS/mg COD removed
0.49
0.46
0.57
Sludge growth
constant
mg VSS/mg BOD removed
0.66
0.69
0.76
                                46

-------
                                        Screened
                                        waste
                     Metering and flow
                     distribution box
                                         I
To river
Activated
sludge

Aeration
basin
                                       Clarifier
                                              Aerated
                                              lagoon
      Waste flow
      Return sludge flow - activated sludge
      Figure IV-7.  Schematic flow diagram 1967-1968 processing season.
                                         47

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                      Metering and flow
                      distribution box
To river
Sludge
reaeration
basin
                                             I
                                             I
                                             I —
                                    Clarifier
                                                Aeration
                                                basin
         Waste flow
         Return sludge flow - activated sludge

         Return sludge flow - activated sludge -with sludge reaeration
         Figure IV-8.  Schematic flow diagram 1968 processing season.
                                           48

-------
*>.
co
                   i CO
                   • CO
                  o
                  g
                  O
                  CN
 Q
 O
 m
ct
                            1.0  -
                           0.5  -
                                                                                               >Rnn_ = 0.068x1.16 (r-20)
                                                                                                rBOD
                                                                                                       = 0.068
                                                                                                               mg BOD rem
                                                                                                               mg MLVSS — day — mg/l
~Y~ Pears — Aerated lagoon
 ©  Pears — Activated sludge
 0  Pears — Activated sludge with sludge reaeration
-E)- Peaches — Aerated lagoon  & activated sludge
 ^  Apples — Activated sludge
                                                                    10
                                                                                      I

                                                                                     20
                                                                               SUBSTRATE BOD, mg/l
                                                              Figure IV-9.  BOD removal rate vs concentration at 20  C.

-------
         0.02   -
D
O
O

 D)
CO
CO
                                 fr = 0.017 x 1.16
                                                 7-20
         0.01   -
         0.008 -
                                                                                0.017
 01

Q

8
 O)
UJ

o

u_
LL
LU
O
O
         0.006  -
         0.005  —
         0.004  -
         0.003  -
                                                                 Log"1 0.064
                                                                               1.16
 DC
 Q
 O
         0.002  -
                                                                     O  Pear processing

                                                                     El  Peach processing


                                                                     /\  Apple processing


                                                                     ©  Pear processing —

                                                                         Activated sludge with

                                                                         sludge reaeration
          0.001
                                                     10
                                                                       15
                                                                                         20
                                               TEMPERATURE, °C
                            Figure IV-10.  COD removal coefficient vs temperature.
                                                      50

-------
     The following are significant conclusions and recommendations resulting from the 1967-1968
studies of fruit processing waste treatment at Snokist:

     •    The fruit processing wastewaters were treatable by biological treatment.

     •    Nutrients were deficient. Both phosphorous and nitrogen additions were necessary
          for successful biological treatment.

     «    Kinetic constants derived (figures IV-9, IV-10, IV-11), including their temperature
          dependency, were suitable for design of biological systems for fruit processing wastes.

     •    In a biological treatment system, sludge settling was extremely critical to the overall
          process and clarification rates at less than 400 gal/ft^/day were necessary in order
          to get proper operation.

     •    Sludge recirculation rates, because  of the low compacting characteristics of the sludge,
          were necessarily high, and sludge recirculation rates equal to or greater than the raw
          influent waste flow were necessary.

     •    Sludge wasting was difficult with this system because the sludges developed were
          very  difficult to thicken and dewater.

     Operating experience since 1968 has indicated that the biological treatment system can
capably meet the effluent standards defined  as Best Practicable Treatment  by the  EPA. Results
from the  1974 operating season shown  on table IV-9 illustrate this capability.
                     Table IV-9.--Summary ofactivatedsludge process— 1974
                                    [Mean/standard deviation]

Influent COD, mg/l
COD loading on MLVSS, day"1
Effluent COD, mg/l
Effluent SS, mg/l
Flow, 103m3/day
Ave. processing rate, kkg/day
Pear
processing
(59 days)
2740/440
0.14/0.04
52/43
19/17
5/9/0.6
260
Peach
processing
(4 days)
1 670/220
0.07/0.01
24/6
7/1
6.9/1.3
200
Apple
processing
(23 days)
550/100
0.024/0.009
52/39
20/12
3.8/1.4
100
                                             51

-------
        0.20  H
GO
00

01
E


I
O)
E
 I
LU

S
tr
z
O
D-
oo
LU
cc
GO
o
Q
                                                                          0.115
0.10

0.09

0.08


0.07


0.06



0.05  -




0.04  —





0.03  -
                       Ay = 0.115 x 1.14T~20
                                                               Log 1 0.057   1.14
        0.02   H
                                                 10
                                                                 15
                                                                                   20
                                         TEMPERATURE, °C
                        Figure IV-11. Endogenous respiration rate vs temperature.
                                                   52

-------
     One problem encountered from time to time is the use of chlorine in the cannery which
has escaped into the wastewater treatment system. These leaks have been responsible for
selectively killing off portions of the biological population that have normally promoted high
clarity in the effluent.   The in-plant chlorination is prompted by requirements from the FDA
for a lack of machinery  mold on all components of the cannery and subsequent advice by USDA
to chlorinate to prevent machinery mold development. Severe problems were encountered
during one of the operating seasons  which led to a marked deterioration of wastewater efflu-
ent.  During the 1975  processing season a lesser deterioration (allowing the effluent to still
meet the 1977 guidelines) was experienced.  This deterioration did affect other  objectives for
the wastewater system and impact the operation.


SLUDGE UTILIZATION AS CATTLE FEED

     The Snokist Growers biological treatment system for fruit processing waste has resulted
in the production of biological solids which must be disposed of.  During the 1974 processing
season Snokist Growers, with the assistance of a grant from the EPA, investigated  utilization
of the waste biological solids as a cattle feeding supplement. Waste sludges were dewatered on
basket centrifuges from the approximate 1/2 to 1 percent clarifier underflow concentration
and the approximate 2 to 2-1/2 percent sludge thickener solids concentration up to about
8 percent solids. The sludges were fairly high in crude protein with approximately 40 percent
on the dry solids basis. The solids dewatering was conducted as shown in figure IV-12 and
resulted in a fairly consistent product at about 8 percent total solids.

     The cattle feeding portion of the investigation was conducted by Washington State  Uni-
versity's Irrigation,  Agricultural, Research and Extension Center in Posser,  Washington, under
contract to  Snokist Growers.  The first part of the feeding investigation was a metabolizability
and digestibility trial utilizing eight head of cattle in a latin square distribution with a control
feed and rations containing 2-1/2, 5 and 10 percent dry solids from the waste sludges. The
digestibility (defined as the intake minus the fecal matter) and the metabolizability (defined as
the intake minus the fecal, urine and respiration  matter) were determined  utilizing the eight
steers in a confined area where all intake and excrement was monitored.  The digestibility and
metabolizability of the rations containing the sludges were equal to  that of the  control ration up
through the 5 percent level and nearly equal at the 10 percent level as shown on figure IV-13 and
figure IV-14.

     To determine  the value of the sludge as a feed for cattle being finished for slaughter,
24 head of cattle were divided into  four groups of six each and fed to a finished state (approxi-
mately 265  days) on control rations and rations containing 2.3, 4.6 and 8.9 percent total solids
from the biological treatment system. The weight gain rate of steers fed the ration containing
2.3 percent  biological solids seemed to be enhanced by the presence of the solids, and the weight
gain for the steer groups receiving 4.6 and 8.9  percent solids was at least equal  to that of the
control group as shown by figure IV-15. Following slaughter, the carcass quality of the steer
groups was determined.  The carcass quality  of the groups containing sludge actually appear
to be slightly higher than that of the control group, especially at the 2.3 percent biological
solids level as shown by  figure IV-16.

     No harmful constituents were found in  the biological solids fed to  the animals, and FDA
approval for slaughter  and marketing of the carcasses was obtained.  Prior to full scale inclusion
of the biological solids into a cattle  feeding ration, it would  be necessary to obtain a permit
from FDA.  One of the principal criteria in obtaining such a permit is the assurance that no
human wastes entered  the treatment system where the biological solids were produced.
                                           53

-------
                               Air
        Clarifier effluent
                                 Pressurization
                                 system
         Biological solids from
        clarifier underflow
                             Clarifier
                             solids
V , ,.^5-,

Flotation
thickener







ri I
1 I
Sub
natant
                                                          Thickened
                                                          solids
                                                            Alternate centrifuge
                                                            feed sources
                      Figure IV-12. Schematic flow diagram — solids dewatering.
                                                                                              Basket
                                                                                              centrifuge
Q

Q

IT
ai
         75 -
                           DE
DMD
                                                                        I
        50 -
>- a

LU

Q
        25  -
                                                                                 Standard deviation
                                    2.3
                              I
                             4.5
                                                                                                     I
                                                                                                    9.2
                                   PERCENT BIOLOGICAL SOLIDS IN  RATION
                       Figure IV-13.  Digestibility of rations by biological solids content.
                                                       54

-------
DC
LU
         75  —
                                                                ME
i         -—    =
                                                              DMM
 I >      50  -

£ c
!! in
-" Z
N
o
00
£ 25-
s
0 2.3 4.5

i



= Standard deviation

1
9.2
o
i-
LU

g
                               PERCENT BIOLOGICAL SOLIDS IN RATION
                 Figure IV-14. Metabolizability of rations by biological solids content.
      1.5 -
       1.0 —
      0.5 —
                             2.3
                                              4.6
                                                                                I

                                                                               8.9
                               PERCENT BIOLOGICAL SOLIDS IN RATION
                      Figure IV-15.  Weight gain by ration biological solids content.
                                              55

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  TREATED EFFLUENT REUSE

      Snokist Growers is currently investigating, with EPA assistance, reuse of the biologically
  treated process effluent from their cannery.  Additional treatment facilities for effluent polish-
  ing, including mixed media filtration and chlorination, have been added.  The effluent was
  reused principally for gutter wash and floor wash purposes and experimental uses for other
  areas such as can cooling, equipment washdown, and belt washdown, during the 1975 process-
  ing season. An overall  30% reduction in discharge to the river was accomplished during the
  1975 season due to the wastewater recycling and reuse in the cannery.  During the 1976 season
  additional objectives included demonstration of use of the water for boiler feed to produce steam
  for cooking and line cleanup. Additional can  cooling demonstrations will be performed as well
  as raw fruit conveying to the process lines on a trial basis.

      As mentioned previously, chlorination in the plant during the 1975 season resulted in a
  change in biological solids characteristic  of the treatment system, which in turn resulted in some
  solids carry over in the effluent and a subsequent deterioration  in the quality of the effluent
  treated by the mixed media filtration system.  Additional problems in the wastewater reuse
  system were encountered in the mechanical equipment during its startup and break-in period.
  It is anticipated that during the 1976 season, better in-plant chlorination control and better
  reliability of equipment will result in even higher percentages of wastewater reuse.  With the
  present capability of the system, it may  be feasible for up to 50 percent reuse of wastewater
  during pear processing and an even greater percentage during apple processing.
HI
x
O
CD
cc
     Abundant  —
      Moderate  —
       Modest  —
       Small   -
       Slight
                                                                                   — 4
                                                                                T ~ 3
                                                                                         LLJ
                                                                                         Q
                                         Q

                                         —
                                         >
                                •*•  - 2
                                                                                   - 1
                               —T~
                                2.3
T-
 4.6
—I

 8.9
                                  PERCENT BIOLOGICAL SOLIDS IN RATION
                   Figure IV-16.  Carcass yield grade and marbling score by ration.
                                            56

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                                   CASE HISTORY  VIII


                       CASE HISTORY OF TOMATO PROCESSING

              WASTEWATER MANAGEMENT AT HICKMOTT FOODS, INC.*
INTRODUCTION

     Hickmott Foods, Inc. is a small independent cannery located in Antioch, California.  In
the past, the  principal items processed were tomatoes, asparagus, and sweet potatoes.  The sweet
potato and asparagus operations were abandoned after the  1973 and 1974 seasons respectively,
leaving tomatoes as the  only commodity to be canned in 1975.  Tomatoes are canned in an
80-day operating season during the months of July through October.   With the exception of
a week or two at the beginning and end of the season, the canning operation is continuous
around the clock.  In 1971, to meet waste discharge requirements established by the Central
Valley Water Quality Control Board, Hickmott Foods undertook a program of wastewater
management to clean up its wastewater discharge to the  San Joaquin River.  Because no
municipal system was available  to  handle the cannery wastes, Hickmott Foods was forced to
develop its own waste treatment system or cease to operate.


WASTE QUANTITIES

     Approximately 1,200 tons  of mechanically and hand harvested tomatoes are processed
daily at Hickmott Foods.  Production data for the 1973, 1974 and 1975 seasons are summarized
in table IV-10. Of the daily total, 55 to 65 percent of the raw fruit was  peeled.


      Table IV-10. -Tomato processing production data for the 1973, 1974, and 1975 canning seasons
Item
Raw product delivered
Daily average3, tons/day
Season total, tons
Percentage increase
Peeled product
Percentage of season tonnage
Season
1973

870
54,500
-

55
1974

1,050
66,000
21

57
1975

1,200
85,000
29

65
     aAverage for full 24-hour operating day.
*Mr. Ed Fernbach - Trotter-Yoder and Associates, Lafayette, California
Dr. George Tchobanoglous - University of California at Davis, Davis, California
Mr. Bill Ostertag - Food Industry Consultant, Pittsburg, California
                                            57

-------
     Wastes from the tomato canning operation at Hickmott Foods are in three forms:

     1.    Solid wastes such as whole tomatoes and tomato skins, seeds, and stems.

     2.    Sludge from the caustic peeling of raw tomatoes.

     3.    Wastewaters which contain suspended and  soluble tomato components, sand, and
          silt.

     The quantities of these wastes are shown in table IV-11 for the 1974 canning season. Of the
170  tons of tomato components that went to waste  each day,  39 tons are hauled away as solids
for cattle feed, 120 tons of  caustic tomato sludge are generated per day from the dry peeling
operation, and approximately 11  tons  per day of raw product  is lost in the wastewater flow
stream. The characteristics of the wastewater that would have to be treated  if the peeling sludge
were to be dumped into the  plant sewer (as  was the  practice before the 1974 canning season) is
shown in  tables IV-12 and IV-13.  As shown in table IV-12, a significant reduction in wastewater
generation occurred between 1974  and 1975.  This reduction was a result of the following:

     •    The rearrangement of the production area, reducing spray requirements.

     •    The running of the cannery at full production  capacity which reduced the per ton
          water usage.
                 Table IV-11.— Waste generation during 1974 tomato canning season
Item
Solid wastes, tons/day
Peeling sludge at 7% solids, tons/dayd
Loss of tomato in wastewater, tons/day6' f
Total loss of raw product as waste, tons/day9
Percentage of total
Value
With
peel
recovery*3
39
120
11
170
16
Without
peel
recovery0
37
0
133
170
16
Unit value3
With
peel
recovery6
74
228
21
323
-
Without
peel
recovery0
70
0
253
323
-
    aUnit production values are on a gal/ton or Ib/ton of raw tomato basis (whichever is applicable).

    Current method of operation

    cPredicted quantities based on measured values for peeling sludge COD, suspended solids, and flow rate.

    d32,400gal/day.

    eBased on waste characteristics given in table IV-12.

    M.O pound of whole tomato yields 1.3 pounds of COD (COD of whole tomato = 73,000 mg/l, TSS of whole tomato =
    55,000 mg/l).

    ^Checked with pack reports using standard case per ton conversion factors and estimated loss in evaporation and waste.
                                               58

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         Table IV-12. — Wastewater characteristics during 1973, 1974, and 1975 canning seasons
Item
Wastewater flow rate, mgd
unit value, gallons/ton3
reduction, percent
Biochemical oxygen demand (6005), mg/l
unit value, pounds/ton8
reduction, percent
Chemical oxygen demand (COD)1-1, mg/l
unit value, pounds/ton3
reduction, percent
Total organic carbon (TOC), mg/l
unit value, pounds/ton3
reduction, percent
Total suspended solids (TSS), mg/l
unit value, pounds/ton8
reduction, percent
Season
1973b
1.7
1,950
-
2,400
39
-
5,500
90
—
2,000
32
-
1,800
29
—
1974C
1.14
1,090
44
1,300
12
69
3,000
27
69
1,100
10
69
1,000
9
69
1975C
1.0
850
24
1,200
8
33
2,800
19
30
1,000
7
30
1,000
7
22
aUnit production values are reported on a per ton of raw tomato basis.
"Includes peeling sludge.
cPeeling sludge isolated from waste stream.
d1.0 pound of peeling sludge yields 1,3 pound of COD (see table IV-11).


                   Table \M-"\3.-Effect of peeling sludge on wastewater characteristics
Item
Wastewater flow rate, mgd
Biochemical oxygen demand (BODg), mg/l
Chemical oxygen demand (COD)C- mg/l
Total organic carbon (TOG), mg/l
Total suspended solids (TSS), mg/l
1974
Witha
peel
recovery
1.14
1,300
3,000
1,100
1,000
Without0
peel
recovery
1.17
2,400
5,500C
2,000
1,200
1975
Witha
peel
recovery
1.0
1,200
2,800
1,000
1,000
Withoutb
peel
recovery
1.04
2,880
6,600C
2,400
1,500
  aCurrent method of operation.
  ^Predicted quantities based on measured values for peeling sludge COD, suspended solids and  flow rate.
  C1.0 pound of peeling sludge yields 1.3 pound of COD (See table  IV-11).
                                                     59

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Discharge Requirements

     Hickmott Foods was given its first set of discharge requirements in 1971 and was issued a
NPDES permit on January 1, 1975.  These requirements are shown in table IV-14. Based on the
requirements set forth in table IV-14, Hickmott Foods must remove 94 percent of the BODg and
91 percent of the total suspended solids from its wastewaters before discharge.
                     Table IV-14.-Tomato processing waste discharge requirements3

Constituent
Process wastewater
Daily flow, mgd
BOD5 Ibs/day
Total suspended solids, mg/l
Ibs/day
Settleable matter, mg/l
Oil & Grease, mg/l
pH
96-hour Bioassay, % survival
Minimum, any one bioassay
Median, three or more consecutive
Cooling water
COD, mg/l
Temperature, "F

Value3
30-daya
Average


800
75 (50)
820
0.2 (0.5)
10


70(100)
90






Daily
maximum

1.3
1,890
125(75)
1,360
0.5 (1.0)
15(10)
6.5-9.5b




5Qc
20° above
backgroundd
          aEffective January 1, 1975; previous requirements shown in parenthesis.
          bRange.

          cAverage value above background.

          dCombined process and cooling water discharge shall not exceed 20° F above the temperature
           of the San Joaquin River or 85°—90° F.
WASTE MANAGEMENT IN CANNERY

     Significant reductions in the wastewater flow rate and strength have been accomplished by
modifying various operations within the cannery production area.  These changes and their impact
are discussed in this section.
                                              60

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Wastewater Flow Reduction

     The two principal components of the wastewater produced during the 1973 and 1974 tomato
canning seasons are the process water and the water from the evaporators and retorts (see table
IV-15). Water used in the production process is derived primarily from the domestic water supply
of the City of Antioch, whereas the water used to cool the evaporators and retorts is filtered from
the San Joaquin River.

     Several steps were taken between 1973,1974 and 1975 to reduce the quantity of water used
by the cannery and to reduce the wastewater flow rates. The cooling water was analyzed and found
to be suitable for direct discharge to the river after cooling (COD less than 50 mg/1). Eliminating
the cooling water from the waste stream reduced the flow requiring treatment from 3.1 mgd to 1.14
mgd, while cannery production increased 20 percent between 1973 and 1974.

     The installation of four dry peel removal machines in 1974 reduced the total water needed for
peeling from 306 to 124 gpm. The quantity of peel sludge produced dropped from 150 to 24 gpm
while cannery  production increased 20 percent. This reduced amount of peeling sludge now made
it possible to isolate this material and process it separately.

     All low pressure-high volume washdown hoses were removed and a high pressure hose system
with nozzles that shut off upon release was installed. This change resulted in a washdown flow re-
duction of at least 80 gpm (see table IV-15). As low pressure hoses are usually left to run on the
floor, the reduction was probably somewhat larger. Some employees objected to the use of the
high pressure spray, as it is harder to control, but eventually became accustomed to using these
nozzles.  No degradation in the quality of the product or plant sanitation was observed. Cooling
water discharge was reduced by 200 gpm by reusing the retort cooling water for can washing. Be-
sides reducing the amount of water to be cooled before discharge to the river, the amount of river
water that must be filtered and chlorinated for use in the can washing system was also reduced.


Dry Peeling

     The installation of four dry peel removal machines and modifications in the operation of
caustic peelers has resulted in a reduction in chemical usage and the quantity of waste that must be
treated. This has been accomplished with no deterioration in product quality.  Dry caustic peeling,
using rotating rubber discs to mechanically rub peel from tomatoes dipped in sodium hydroxide,
replaced the conventional water rinse peeling operation.  Effective peeling was  obtained with this
method while reducing the concentration of caustic in the peelers. Operational data for the peelers
are summarized in table IV-16 for the 1973 and 1974 seasons.  Data were not collected during  the
1975 canning season.  Through a combination of reducing the peeler speed (resulting in more
tomatoes per bucket but a longer contact time with the caustic per tomato) and using mechanical
peeling, it was possible to use a caustic solution of 7 to 10 percent in 1974 as opposed to an 18 to
20 percent solution in 1973. This mode of operation resulted in a reduction in caustic usage (6.9
Ibs/ton in 1974 as opposed to 11.7 Ibs/ton previously) and reduced chemical requirements for
neutralization  of the resulting wastewater.

     Dry caustic mechanical peeling requires about 80 gallons of potable water per ton of tomatoes
as opposed to 720 gallons per ton using conventional methods.  The 80 gallons per  ton, which
amounted to 24 gal/min of caustic sludge in the Hickmott Foods operation, is  small enough to  be
disposed of in  a land spreading operation. The exclusion of this sludge from the waste stream to
the water pollution control plant reduced the BODs load on the treatment facility  by 46 percent.
As shown in table IV-13, if the peeling sludge had not been handled separately, the BODg of the
wastewater in  1974 and 1975 would have been 2,400 to 2,880 mg/1 as opposed to the 1,200 to
1,300  mg/1 actually measured.


                                            61

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                    Table IV-15. -Daily water usage during 1974 canning season and percent
                                    reduction data over 1973 canning season3

Item
no.

Description of source

1974
Flow rate,
gpm
Percent
reduction
over 1973
Process wastewaterb
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

Seals on sump pump (1/2" line, 2 @ 8.8 gpm)
Bin washing system (2 @ 17.5 gpm)
Incoming product sprays (2 @ 10 gpm)
Small tomato dropout fluming to product tables
Make-up water to lye peelers (2 @ 10 gpm)
Rinse tanks after peeling (2 @ 50 gpm in 1 973)
Dry scrubbers (4 @ 6 gpm)(1 @ 50 gpm in 1973)
Rinse water on roller washers (4 @ 20 gpm) (4 @ 35 gpm in 1973)
Belt lubrication and cleaning
Can washers, 7 peeling, 3 product (10 @ 18 gpm)
Kettles (1" line, 1 @ 30 gpm)
Washdown lines, low pressure (4 @ 35 gpm in 1973)
Washdown lines, high pressure (6 @ 10 gpm)
Can cooling, outside coolers (7 @ 35 gpm)
Cooling water, vacuum pumps (3 @ 8.8 gpm)
Total wastewater generated, gpm (1126 gpm in 1973)
18
35
20
35
20
Oc
24b
80d
50e
180h
30
Oc
60f
245
27
800
—
-
—
—
-
100
52
43
-
-
-
100
-
-
—
29
Evaporators & retorts9
16
17
18

Evaporator no. 1
Evaporator no. 2
Retorts

550
350
100h
1,000
	
—
69
17
Pluming water'
19
Tomato fluming
600

aBased on individual flow rate measurements during 1973 and 1974 peak production periods.
 All process wastewater must be treated by the wastewater treatment facilities except item 7. See following section on dry peeling.
cEliminated from 1973 operation.
"Reduced by lowering spray pressure.
^To be reduced in 1975  by shortening belt runs.
 Nozzles shut off When not in hand of operator.
9Water from evaporators and retorts is discharged directly to river after passing through cooling tower.
 Retort water is recovered and used for can washing.
'Fluming water is recycled internally.  Make-up water is obtained from items 3 & 4.
                                                         62

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   Table IV-16. - Summary data on caustic tomato pee/ing operation and acid usage at Hickmott Foods, Inc.
Parameter
No. caustic peelers
Peeler speed, buckets/min, each
Loading rate, tons/min, each
Caustic solution in peeler, percent
Total season throughput, tons

Caustic usage, tons
Unit caustic usage, Ibs/ton

Acid usage, tons
Unit acid usage, Ibs/ton
Season
1973
4
40-44
0.33
18-208
29,000
h
198
11.7
c d
71'
4.9
1974
4
24-28
0.33
7-10a
35,000
b
121
6.9
c e
53
3.0
Reduction
1974 over 1973,
percent







41


39e
       aEstimated average from operator titrations.
       ^50 percent sodium hydroxide used.
       C93 percent sulfuric acid used for neutralization of wastewater at treatment facilities.

       '•'All caustic peeling sludge entered treatment system.
       eOnly a small portion of the caustic sludge entered the waste treatment system. Tighter restraints
        imposed on neutralization system offset expected acid usage reductions.
Floor Waste Management

     Because tomatoes are, for the most part, a water soluble fruit, the longer they remain on the
cannery floor or in a wastewater conveyance facility, the more the tomato solids and juices con-
tribute to the soluble COD and BOD5 of the wastewater.  If processing wastes are picked up in
solid form, they can be fed to livestock or at least trucked to disposal sites as solid wastes.  Manual
collection of large solid tomato parts was stressed during the 1974 and 1975 seasons. Gratings on
all floor drains were also bolted down.  Reliable solid waste per ton data were not available for the
1973 season, but it is estimated that considerably more solid waste was trucked to cattle for feed
during the 1974 season.  This is waste that does not reach the treatment facility as fine suspended
matter or soluble organics.
Wastewater Characteristics

     Eight and 24-hour composite samples of the wastewater were taken weekly during the 1974
and 1975 operating seasons.  Constituent concentrations determined for both the raw wastewater
and treatment process effluent are reported in table IV-17.  As shown, the COD of the raw waste-
water is about 2.3 times the BOD5 as compared to 2.5 for most domestic wastes.  The BOD5
values shown in table IV-17 are those obtained from the BOD5 test as delineated in Standard
Methods2. The BOD5 values were found to increase by about 20 to 25 percent when the bacterial
seed for the test was acclimated to tomato peeling sludge.  It was also found that the BOD5 value
was approximately 55 to 65 percent of the ultimate BOD value when using acclimated seed. If it is
assumed that a reported BOD5 value of 1,300 mg/1 is about 80 percent of the acclimated value and
that the acclimated value is 60 percent  of the ultimate BOD value, the ultimate value would be
                                               63

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                  Table IV-17.-Influent and effluent wastewater characteristics during the
                                 1974 and 1975 tomato canning season
Constituent
Total flow, gpm
mgd
Suspended solids,
total, mg/l
volatile, mg/l
fixed, mg/l
BOD5, total, mg/l
soluble, mg/l
TOC, total, mg/l
soluble, mg/l
COD, total, mg/l
soluble, mg/l
Normal operation without
peeling sludge
Influent6
—
1,000
400
600
1,200-1.300
1,100
1,000-1,100
900
2,800-3,000
2,700
Effluent0
800
1.14
60
20
40
30
20
50
30
120
90
With peeling sludge
in waste stream"
lnfluentb
—
1,200
-
-
1,800-2,800
1,600-2,400
-
5,500-6,600
-
Effluent0
825
1.18
60
20
40
30
20
60
—
200
150
	 J
     aValues based on limited operational data obtained during periods when peeling sludge was discharged to waste stream.
      After screening with a 20 mesh vibrating screen.
     cAfter biological treatment.

 computed to be 2,710 mg/l.  This compares reasonably well with the COD value of 3,000 mg/l.  The
 total organic carbon values are slightly less than the conventionally determined BOD5 values.  For
 this particular tomato waste, the TOC can be used as a quick indication of the BOD5.

      Over 50 percent of the  influent suspended solids are fixed solids such as clay, silt and sand.
 Because separate dirt removal facilities are not used, all of the dirt (except what is settled out in the
 dump tank or a very small settling bin) is pumped to the treatment process. The impact of this
 inert material is discussed in  the sections dealing with nutrient requirements and sedimentation
 basin performance.


 Treatment Process Flowsheet

     Hickmott Foods initiated the design and construction of wastewater treatment facilities in 1972.
 In the original design, large solids were removed with vibrating screens before the wastewater was sent
 through a series of centrifugal screen separators.  From there, the  waste was neutralized and dis-
 charged into a two-stage aerated lagoon system which was mixed and aerated by circulating the
 lagoon contents through pressurized tanks.  Sedimentation facilities were not included in the
 original design.  It was soon realized that this system could not meet discharge requirements. Un-
 fortunately, the wastewater had not been characterized adequately before the plant was constructed.
 Because the centrifugal screens were overloaded hydraulically, it was not possible to produce a
tomato sludge thick  enough to make  hauling feasible. Although the treatment process did reduce
the soluble organic.content of the waste, liquid-solids separation facilities were not provided and
                                              64

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the suspended solids concentration in the effluent was as high or higher than the original waste flow.
In addition, the cooling water discharge was part of the waste flow.  This put an additional hydraulic
loading on the treatment plant and reduced the detention time in the treatment system.

     A new consultant was retained by Hickmott Foods, the treatment flowsheet was modified, and
the necessary construction was completed in time for the 1974 operating season4. The modified
process flowsheet currently in use is shown in figure IV-17.  The vibrating screens, neutralization
facilities and the effluent disposal portion from the original flowsheet were retained. The two
lagoons have been converted to aeration and sedimentation basins.  Sludge is recycled from the sedi-
mentation basins back to the aeration basin.  Cooling water is treated separately but is discharged
through a common outfall. A pictorial view is presented in figure IV-18.
UNIT OPERATIONS AND PROCESSES

     The individual unit operations and processes that comprise the treatment system of Hickmott
Foods are considered in this section.  They include:

     •    Raw solids separation

     •    Neutralization and nutrient addition

     •    Activated sludge process

     •    Sedimentation

     •    Activated sludge waste solids thickening

     •    Sludge disposal

     •    Cooling water treatment


 Raw Solids Separations

     The raw solids separation facilities consist of two 60-inch diameter two-stage vibrating screens.
 The screens are cleaned by the vibratory motion of the screens and the rotating spray headers.
 Approximately 5 tons per day of raw tomato solids, twigs and cans are removed from the waste
 stream using 20-mesh stainless steel screens.  About 50 percent of the total suspended matter that
 reaches the treatment facility is removed with the screens.  This material is discharged directly into
 a storage hopper.  Screened solids are trucked to nearby ranches for cattle feed or for land disposal.


 Neutralization and Nutrient Addition

     Before further treatment, the wastewater pH is adjusted to between 6.5 and 8.5.  Neutralization
 is accomplished in a two-compartment tank. The detention time in each compartment at average
 flow is about 20 minutes.  Sulfuric acid addition to each compartment is controlled with a pH probe
 and individual controllers  are used for rough and fine pH adjustment. Sulfuric acid usage during the
 1973 and 1974 canning seasons is shown in table IV-16.  During the 1975 canning season, the acid
 usage was reduced further through more efficient handling of the caustic peeling sludge. Mishaps
 with the neutralization system during the 1975 season are discussed in a later section of this case
 history.
                                              65

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Peeling sludge
      Raw
      waste
      sump
                   ./
                                     Sludge
                                     storage
                                     tank
                                                          Sludge
                                                          thickeners
                Coarse
                tomato solids
Solids
separation
facilities
pH adjustment
tank
                                                           Aeration
                                                           basin
                                                         Sedimentation
                                                         basins
                                                                                             Cooling water
                                                                            1
                                                                                   Cooling
                                                                                   tower





T
e
1

reated
ffluen
                                                                           sump
           Figure IV-17.  Flowsheet for wastewater treatment process (put into operation in 1974).
                      Figure IV-18.  Aeration basin with surface aerators in operation.


                                                     66

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     Nitrogen and phosphorus as well as many trace elements are essential to the growth of micro-
organisms in the aeration basin5. The estimated nitrogen and phosphorus requirements, as well as
the range in concentrations of these nutrients measured in the tomato wastewater, are reported in
table IV-18.  During most of the canning season, the nitrogen and phosphorus levels in the waste-
water are near the upper end of the ranges shown in table IV-18. However, during the early part of the
canning season when tomatoes are harvested from the southern portion of California's Central Valley,
nutrients must be added because the sandy soils in this area contain few, if any, adsorbed nutrients.
As Hickmott Foods has no prior removal of sand, silt and clay, the NH4+ and PO4 '3 associated with
the inorganic solids serve as a major nutrient source.  The clay and silt content of the soil increases
as harvesting moves up the Central Valley and nutrient addition is not required. The reduced nitro-
gen and phosphorus levels also occur at the time of process start-up. The presence of filamentous
organisms  (associated with sludge bulking) and the absence of the protein foam (usually present on
top of the aeration basin) were observed until supplemental nutrients were added. When nitrogen
and phosphorus are added in the form of aqueous ammonia and phosphate fertilizer, bulking is
eliminated and the surface foam reappears (nitrogen and phosphorus are added until traces of ammonia,
nitrate or phosphate are observed in the effluent).
               Table IV-18. —Nutrient requirements of activated sludge process and quantities
                         available in wastewater from tomato canning operations


Constituent


Total kjeldahl nitrogen as N
Total phosphorus as P

Amount
required,
Ib/day

41 7b
85C
Amount available
in wastewater


Cone.,
mg/l
20-90
4-12

Total,3
Ib/day
190-856
38-114
       aAverage daily flow of 1.14 mgd.
       b
        12.4 percent of the total daily volatile solids production in activated sludge process during normal operation.

       C2.5 percent of the total daily volatile solids production by activated sludge process during normal operation.
Activated Sludge Process

     After neutralization, the wastewater flows into the aeration basin where waste tomato organics
are converted to bacterial cell material.  Six 60 hp, floating, high-speed aerators are used to provide
oxygen and completely mix the contents of the basin. Normally all six aerators are operated con-
tinuously.  However, to save power costs, the units could be turned on and off with the demand.
A Hypalon liner is used to prevent erosion by the aerator turbulence.  Biological solids are separated
from the flow stream in sedimentation basins and are then returned to the aeration basin.  The net
biological solids produced are removed daily from the treatment system.

     The physical characteristics of the aeration basin and the operational parameters of the activated
sludge processes are reported in table IV-19. As shown, the process can be classified as extended
aeration of activated sludge (mean cell residence time typically greater than 12 days). With the
existing aeration and mixing capacity, it was possible  to maintain mixed liquor SS concentrations
ranging from 9,000 to  15,000 mg/l, while holding a dissolved oxygen concentration of 4 to 5 mg/l.
High solids concentrations, however, may result in problems in the design and operation of sedimen-
tation facilities. This subject is discussed further in the following section.
                                              67

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               Table IV-19. -Physical characteristics and operational parameters for the activated
                          sludge process measured during 1974 tomato canning season
                       Item
   Range
Average
        Aeration basin characteristics

          Volume, million gallons
          Aeration time, hrs.
          Aerators,
             number
             horsepower  (6 @ 60 hp/aerator)
          Oxygen transfer rate3, Ib 02/hp-hr
          Mixing, hp/1,000 gallons
          Dissolved oxygen concentration, mg/l
  2.0-4.5

  2.0-6.0
  1.10
    24

     6
   360
   3.0
  0.33
   4.5
        Process operational parameters

          MLSSb under aeration,
             mg/l
             percent volatile
          F/M (food to microorganism ratio),
             Ib BOD5/lb MLVSSC
             lbCOD/lbMLVSSc
          Mean cell residence timed, days
          Yield coefficient,
             lbcells/lbBOD5
             Ibcells/lbCOD
          Sludge production6, Ib VSS/day
8,000-15,000
   40-75
    8-20

 0.30-0.60
 0.13-0.26
3,700-7,400
10,000
    55

  0.28
  0.49
    12

  0.58
  0.24
       Calculated on the basis of COD satisfied (see table IV-16).
        Mixed liquor suspended solids.

       cMixed liquor volatile suspended solids.
        Calculated on basis of cells in aeration basin only.
       eSludge production varies with mean cell residence time.
     The observed advantages of this process in terms of process performance and reliability are
as follows:

     •    Because of the low food-microorganism ratio, the process is less susceptible to upsets
          caused by high organic shock loadings.

     •    Because high levels of dissolved oxygen can be maintained, higher forms of microorganisms
          are present and a very clear effluent is produced (3 to 4 ft. on a standard secchi disc).

     •    Because the process can be operated in the extended aeration mode, a sludge is produced
          that settles well and carries down colloidal silt and clay particles.

     •    Because the process can be operated in the extended aeration mode, nutrient require-
          ments are reduced.
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     Daily observations of the bacterial population were made because it was found that process
changes and stress conditions could be observed before they would affect overall treatment effi-
ciency.  Under normal operations, the bacterial population is composed primarily of small bacteria
with large numbers of stalked ciliates (Vorticella) and many free swimming ciliates and rotifers
(Philondina).  The presence of these higher forms was used as an indication that the process was
operating properly. The following conditions would cause the disappearance of the higher forms:

     1.    Dissolved oxygen levels below 3.0 to 4.0 mg/1.  It is possible that with high mixed liquor
          solids, the oxygen transfer efficiency is impaired at lower concentrations.

     2.    High organic loadings.  When the process was in the dispersed growth phase, it was ob-
          served that the higher forms did not compete as well as the simpler bacterial forms.

     3.    Toxic substances or nutrient deficiencies. These problems were also found to affect the
          higher forms.

     4.    pH control. If the pH control system was turned off or acid spillage occurred (1975), it
          was observed that the ciliates and rotifers could not adapt to  pH fluctuations and would
          soon disappear.

      Filamentous bacteria were not present under normal operation unless the following conditions
 prevailed:

      1.   Nutrient deficiencies. When the supply of nitrogen and phosphorus was below that re-
          quired by the process for extended periods of time, filaments would begin to predominate
          and cause sludge bulking.

      2.   Low DO levels. When  dissolved oxygen concentrations remained below 2.0 mg/1 for
          extended periods, the population of filamentous organisms would rise.


 Sedimentation Facilities

      The sedimentation facility was constructed in a pond which  was once used as an aerated lagoon.
 Modifications to the old lagoon included the addition of concrete and walls, the fabrication of an
 inlet manifold, center rail support structure and effluent weir troughs, scum collectors, and the in-
 stallation of two electric motor-driven, traveling bridge mechanisms for removing sludge.  The dirt
 basin is lined with Hypalon. Neoprene rubber skirts are used to push sludge to the pick-up points
 on each bridge.

      Sedimentation basin loadings and performance characteristics are summarized in table IV-20.
 The high mixed liquor SS levels and the settling characteristics of this sludge result in a solid-liquid
 separation process that is solids limited.  The activated sludge process could not be operated in the
 extended aeration mode or with the high mixed liquor SS levels with a smaller sedimentation basin.

      The traveling sludge-return  mechanism allows for flexible operation of the sedimentation
 facility.  The sludge-return rate can be varied by adjusting the self-priming sludge pumps on each
 bridge. Under normal operation, the bridge travel rate is 5 feet/min. Return sludge is discharged
 into an overhead trough and flows by  gravity  back to the aeration basin or is pumped to the sludge-
 wasting facilities.
                                               69

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              Table \\J-2Q.-Sedimentation basin characteristics, loadings and performance data
                                   Item
                                                                              Value
           Basin characteristics

              Number
              Average surface area, sq ft, each
              Liquid depth, ft
              Volume, million gallons, each
              Detention time at 2.28 mgd, hr, total
     2
 4,080
   6.5
  0.20
   4.2
            Design loadings

              Hydraulic loading rate including 100 percent recycle flow,
                 gal/sq ft/day
              Solids loading rate including 100 percent recycle flow,
                 Ib/sq ft/day
              Weir loading gal/day/lineal ft
              Return sludge,
                 flow rate, gpm
                 percent of average flow
  280

    23

11,400

  800
  100
            Effluent quality

              Suspended solids,
                 range, mg/l
                 average, mg/l
                 volatile fraction
              Secchi disc readings, ft
  9-75
    60
    33
   1-4
     Because the sedimentation facility was solids limited, hydraulic surges caused the transfer of
solids from the aeration basin into the sedimentation basin at a rate much faster than they could be
settled and pumped back to the aeration basin. If the surges were of short duration, the sludge-
return facilities would catch up with the rising sludge blanket.  However, if the duration of the flow
surge was too large, a deterioration in effluent quality would ultimately result. As noted previously,
Hickmott Foods has no sand, silt, and clay separation from its wastewaters. During periods of stable
process operation, it was observed that the small colloidal clay particles present in the wastewater
are carried down with the bacterial flow. But during periods when the sludge is not settling well,
when the bacterial process is in the log growth phase (such as when the cannery is starting up after
being down), some of the clay particles  escape into the effluent.  This resulted in a decrease in  the
ratio of volatile to total SS  in the final effluent.  This ratio was as low as 0.25 when the corresponding
total effluent SS was 75 mg/l (normal value of volatile to total SS ratio in mixed liquor was ap-
proximately  0.55).


Activated Sludge Waste Solids Thickening

     To maintain process control, the bacterial cells grown each day must be wasted.  Wasting  is
accomplished by pumping return sludge through a three-stage, centrifugal-screen thickening operation.
In the centrifugal screen, the sludge is pumped through a distributor against a rotating polyester
screen with 43-micron openings. Water and some solids pass out through the rotating screen (ro-
tating at 200 to 400 rpm), with the thickened sludge being discharged out the bottom. The capture
                                               70

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efficiency of each of these waits is approximately 50 percent. After a single pass through the sludge,
it is thickened by approximately 25 percent. A schematic with the various flow rates, sludge con-
centrations and total pounds wasted daily is shown in figure IV-19. Because the clay and silt particles
in the waste sludge blind the screens, a thicker final sludge could be obtained if this material were
eliminated.
Sludge Disposal

     Raw tomato solids are trucked away to nearby ranches for cattle feed. Sludge from the peeling
operation is combined with the waste-activated sludge and approximately 20 loads per day (3,000
gal/load) are hauled away by tanker for land spreading at the disposal site. The waste-activated
sludge neutralizes the caustic peeling sludge. After spreading, the sludge is allowed to dewater for
24 hours before being disced into the soil.


Cooling Water Treatment

     Cannery cooling water is treated in a single cooling tower and discharged with the wastewater
effluent into the San Joaquin River through a common outfall. The Central Valley Regional Water
Quality Control Board tentatively set 50 mg/1 as the maximum COD increment concentration to be
allowed in cooling water discharge. This value is subject to change after more data are gathered
during the 1975 operating season.  Data gathered during 1975 showed the average COD of the  cooling
water discharge to be 45 mg/1 or less.
TREATMENT COSTS

     The purpose of this section is to

     1.    Briefly summarize the capital expenditures involved in the construction of the Hickmott
          waste treatment facility.

     2.    Identify the daily operation costs.

     3.    Put these costs into perspective with respect to production costs.


Capital Costs

     Capital expenditures for the Hickmott Foods wastewater treatment facility are reported in
table IV-21.  As shown, the total cost of the plant at $885,000 (ENRCC Index = 2,240) is about
one-half that of a comparable conventional secondary treatment plant design. The use of earthen
basins for both aeration and sedimentation is most significant in terms of cost savings.  Use of
traveling sludge-pick-up mechanisms in a lined earthen basin makes possible an efficient and flexible
sedimentation operation at a considerable cost savings over conventional designs employing concrete
or steel tanks. Hickmott Foods was also able to reduce construction costs  by doing the majority of
the general contracting and labor with cannery personnel.
                                             71

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                                   Centrifugal
                                   screen
                                   concentrator
                                                             Pumps
To aeration basin
To aeration basin
To aeration basin
    77 gal/min


 1.8 percent solids
                        Centrifugal
                        screen
                        thickener
    31  gal/min

2.2 percent solids




            Bypass




    12.5 gal/min
                                            52 gal/min
                                            2.6 percent solids
                      2.7 percent solids
                                           21 gal/min
                                           3.2 percent solids
                                          -M	
                                                                            Bypass
                                                          8.5 gal/min
                                                                                  Centrifugal
                                                                                  screen
                                                                                  thickener
                                                       4.0 percent solids
                                            Pumps
To aeration basin
                                                                                                     Return
                                                                                                     sludge
                                          12,000 gal/day
                                            4,000 Ibs. solids/day
                                                                                            Sludge
                                                                                            storage
                                                                                            hopper
                     Figure IV-19.  Flowsheet for waste sludge thickening facilities.
                                                     72

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                 Table IV-21. -Summary ofcapital costs ofwastewater treatment facilities3
Item
Major equipment
Aerators
Clarifier mechanisms
Sludge thickeners
Other equipment
Soil excavation, filling, grading, paving, etc.
Concrete work
Structural steel & supports
Pond liners
Piping, fittings & installation
Crane & rigging
Fencing & landscaping
Electrical sub-station, hook-ups, equipment & installation
Permits, impact report & other governmental fees
Sub total
Plant labor
Design, civil, soil, marine engineering & general contracting expenses, etc.
Total
Cost, dollars
$ 36,000
76,000
45,000
101,000
70,000
200,000
47,000
21,000
95,000
5,000
7,000
74,000
1,500
$778,500
58,000
49,000
$885,500
         Engineering news record construction cost (ENRCC) index for San francisco Bay region = 2240 (January, 1974).

Operational Costs

     Operational costs for wastewater treatment are associated with the following:

     •    The operation and maintenance of the wastewater treatment facilities.

     •    The hauling and disposal of sludge.

     Daily costs for the 1974 tomato canning season are summarized in tables IV-22 and IV-23.  From
these tables, it can be seen that one-half of the daily operating expenses are associated with the dis-
posal of waste solids and sludge.
                                               73

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Table \V-22.-Summary of daily operating costs for wastewater treatment
                 facilities during 1974 canning season
Item
Power
(520 hp x 24 hr x 0.746 kw/hp x 0.02 kwh)
Chemicals
(acid, ammonia and phosphate)
Supplies
Testing & monitoring operations
(24hr/day x$5.50/hr)
Mechanic-operator
(10hr/dayx$8.00/hr)
Total
Cost, dollars/day
$186
130
50
132
80
$628
    Table IV-23.-Summary of daily solids and sludge disposal costs
                     during 1974 canning season
Item
Truck driver
(1 x 24 hr/day x $7.50/hr)
Truck operation (solids)
(4 trips/day x 14 miles/trip x $0.30/mile)
Truck operation (sludge)
(20 trips/day x 20 miles/trip x $0.35/mile)
Solids disposal fees
(4 loads/day x $3.60/load)
Sludge disposal fees
Discing tractor & operator
(1 x 16 hr/day x$13/hr)
Total
Cost, dollars/day
$180
17
140
14
67
208
$626
                               74

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Annual Cost

     An estimate of the total daily cost to Hickmott Foods including the construction and opera-
tional costs is given in table IV-24. For the 1974 tomato canning season, the cost of treatment
amounted to 13.0 cents per case of tomato product. On a per can basis, the cost of wastewater
treatment at Hickmott Foods is approximately 0.5 cents.
                   Table \V-24.-Summary of total daily cost for wastewater treatment
                                 during 1974 tomato canning season3
Item
Capital cost, dollars/day
($885,500b x 1627C/90 day/yr)
Treatment plant operationd, dollars/day
Solids and sludge disposal6, dollars/day
Total, dollars/canning day
Cost/casef , cents/case
Cost/can, cents/can
Cost/ton of raw tomatoes, dollars/ton9
Cost
$1,601
628
626
$2,855
13.0
0.5
$4.28
           aBased on a 90-day canning season.
           bCapital cost from table IV-21.
           °Capital recovery factor = 0.1625 (10 yrs  10 percent).
           dCost data from table IV-22.
           eCost data from table IV-23.
           fBased on two million cases of number 2-1/2 cans.
           9Based on 60,000 tons.


PROBLEMS, FUTURE IMPROVEMENTS AND WASTE REDUCTIONS

     With the measures Hickmott Foods has instituted to reduce and treat the wastes generated from
canning operations, the company is now in compliance with state and federal discharge requirements.
Nevertheless, additional steps are being taken or considered to increase process reliability, to reduce
waste loads and treatment and/or disposal costs.  These developments are outlined in the following
paragraphs.


Acid Spills

     Twice during the 1975 canning season, several hundred gallons of sulfuric acid were accidentally
dumped into the aeration basin. These spills were caused by (1) the delivery truck driver's failure
to pay attention to what he was doing, and (2) failure of an air operated valve which allowed the
storage tank to drain. Both these spills caused a major failure in biological process efficiency (pH
in the aeration basin dropped to 3.0 for a short period of time). Within 4 days, the process had
fully recovered from both these incidents. Audio alarms were installed on the pH controller to
assure that incidents like these will not occur again without the operator's knowledge.
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Reduction in Water Usage

     Because Hickmott Foods has abandoned its sweet potato and asparagus operations, daily water
usage was reduced further by shortening the lengths of belts on which peeled tomato products must
travel. This change eliminated about 50 gpm of water now used for belt lubrication. In turn, this
reduced the peak water usage in the cannery to about 750-800 gpm.  This quantity is considered to
be the minimum water usage possible to maintain sanitary conditions.  Heightened concern by
USDA and FDA over the issue of machine mold may ultimately result in  increased water usage
per ton.
Flow Equalization

     In activated sludge systems such as the one employed at Hickmott Foods, hydraulic surges
cause large amounts of mixed liquor solids to be transferred from the aeration basin to sedimentation
basin in a short amount of time. If these surges are sustained and are of large enough magnitude, a
deterioration in effluent quality can result as the sludge blanket builds up. With the high concentra-
tion mixed liquor solids employed at Hickmott Foods, increasing the sludge return rate does not
effectively draw down the sludge blanket because of the very low settling velocity of the mixed
liquor at  a concentration of 10,000 mg/1 TSS. To reduce the impact of the flow surges, the top 18
to 24 inches of the aeration basin is to be used for flow equalization. A floating weir will be used to
maintain a constant flow to the sedimentation basin regardless of the water level in the aeration
basin.
Solids Disposal

     Currently, all solid and sludge wastes must be hauled away for disposal. As long as nearby
disposal sites are available, this method is cost effective. If, however, the present system proves to
be unworkable, then further sludge dewatering must be considered. Because a large amount of con-
centrated carbonaceous waste is produced, the use of a pyrolysis process to produce activated carbon
is now being evaluated by personnel from the Jet Propulsion Laboratory of the California Institute
of Technology.  The production of a useful and marketable by-product would reduce an otherwise
prohibitively high operating cost for this method of sludge processing.


Raw Product Transportation

     Hickmott Foods has also contemplated the installation of bulk tub dumping facilities (bins are
now used). However, based on preliminary studies, it was found that when ripe tomatoes are stacked
30 to 36 inches high, the bottom one quarter by weight are broken or cracked. In a plant such as
Hickmott where over 50 percent of all tomatoes are peeled, this amount of damaged product and
extra waste cannot be tolerated.
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                                     CASE HISTORY IX


                         PERMIT REQUIREMENTS  FOR  STARTING

                            A NEW FOOD PROCESSING  PLANT*


     My remarks will be confined to starting a new plant in the Central Valley of California.
The requirements may be, and probably are, different  in other states and even in other sections
of California.

     In any new or existing plant, it is Tri/Valley's philosophy to reduce waste to a minimum
consistent with acceptable operating procedures.  This philosophy includes both liquid and solid
waste.

     It is another Tri/Valley philosophy that waste or  residual material is generally best handled
through land application on Tri/Valley property.  Four of our five  plants totally or partially
handle all of their residual material.  Tri/Valley and the food  processing industry have a residual
material that is generally compatible with land disposal. We at Tri/Valley Growers believe that
the disposal costs associated with land disposal will be the most reasonable in the long run. In
addition, the regulations probably will be less stringent.  Through land disposal we gain the added
benefit of controlling what happens to the residual material and are generally cognizant of it.
Through land disposal we are investing in land and not concrete and  steel as with conventional
treatment plants.  If and when a plant is closed, land is an asset while a more conventional treat-
ment plant may be a liability.  Thus, in  the disposal of residuals, it is Tri/Valley's policy to
utilize land disposal.

     When Tri/Valley decided to build a new processing facility,  several criteria were established
for the plant. The plant would not be municipally sewered.  It would be totally self-contained
in its ability to dispose of all liquid and solid residuals.  The plant  would be located in an agri-
cultural area but would not be located on prime agricultural land.  The location would have to
be near major highways and have access to  a railroad.  Since this would be a tomato processing
plant, it had to  be located near  the tomato  growing area. Thus,  the  guidelines for locating the
plant were set.

     The plant was actually located near Los Banos in western Merced County. It was located
on 840 acres of marginal land with alkalinity problems (pH 8-9), salinity  problems and high
ground water.  Eight hundred and forty acres give Tri/Valley  the ability to adequately handle
liquid and solid residual loads. The plant is near 1-5 and State 152.  Also, the Southern Pacific
tracks are along one side of the property.  By being located in western Merced County, the plant
is located  in the  center of three major tomato growing areas.

     The plant,  which first operated during the 1975 season,  processes tomatoes into tomato
paste and  packages the paste into 55 gallon drums.  The plant has  a  nominal throughput of 200
tons per hour.  There are three  Rossi-Catelli T-120 evaporators producing tomato paste and six
Fran Rica drum fillers packaging the paste.  The plant is located on approximately 20 acres.
*Mr. Robert Parodi — Tri/Valley Growers, San Francisco, California
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The liquid residuals are disposed of by sprinkler irrigation of a cover crop.  The solid waste is
disposed of by spread and disc.  Spreading is accomplished with a spreader truck.  Thus, the plant
did operate during 1975 and accomplished the objectives set by management.

     Now I will describe how we manuevered through the maze of requirements and permits to
build the plant and operate it during 1975. It was approximately 18 months from the time we
decided to build the plant until we actually began operation.  This is the minimum time required.
If you want to be on the safe side, allow two years from conception to operation.  Any shorter
period of time would be pressing the issue, as I will show.

     The first order of business in building our plant  was a county use permit. This was required
since the plant site property was zoned agricultural and was in an exclusive  agricultural area. We
were required to prepare an Environmental Impact Report as the first step to obtain the use
permit.  Merced County requires that the applicant prepare the EIR.  Other counties write the
EIR for the applicant, either directly or  through a consultant.  Even though we were responsible
for preparation, we still hired a consultant from Merced  who was familiar with the area and had
worked closely with the County Planning Department.

     Coincidentally,  we purchased the plant site with two contingencies:  (1) that we obtain the
use permit, and (2) that we could obtain well water of adequate quality and quantity. We worked
closely with the consultant in preparing  the EIR.  The consultant worked closely with County
Planning (the lead agency), County Health, Public Works and Agriculture Extension.

     The County  Planning Commission met in a public hearing to review the EIR and rule on our
use permit application. It took three Planning Commission hearings and several months to re-
solve the issue. Most of the local communities and the agricultural interests in the area were in
favor of the plant and we helped foster the favorable opinion when we  could.  A major point was
the reclaim of the marginal land.  The county agencies felt that the plans associated with the
plant were environmentally sound and they had the means to control the plant if problems de-
veloped. Some of the local environmental groups were opposed to the plant. The State Depart-
ment of Fish and  Game (DFG) was opposed to the plant site since it was next to the Volta
Wildlife Refuge.  We had several meetings with the various groups to try to  resolve differences.
Some were productive while others were not, but they were all worthwhile from the standpoint
that we attempted to resolve any and all questions or areas of contention. Also, in the midst of
the EIR proceedings, we engaged a local attorney.  This  we felt was necessary in order to ensure
that we met our legal obligations and that the county met their legal obligations. We did not
want to be challenged in court for failing to meet some legal stipulation.  The EIR  was approved
as adequate by the Planning Commission and the permit was issued. Both actions were taken
unanimously.

     There was a waiting period between the commission's action and deliberation by the Board
of Supervisors.  The  use permit has to be approved by the Board prior to being granted.  We
again tried to present our position to local communities  and groups. We also had another meet-
ing with Department of Fish and Game trying to resolve our differences.  When the Supervisors
met, we had broad local support. We were still opposed by some local  interests and DFG.  The
Board weighed the issue and granted  the use permit unanimously. We wanted a decision and not
a postponement.  Thus, about six months after starting on the EIR, we had a use permit to begin
construction. Yet we had  to wait another thirty  days until the judicial review period expired.
After 30 days, a suit could still be filed but it would  not halt construction.   Thus, about 12 months
prior to processing tomatoes, we broke ground and began preparing the site.
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     The next order of business was a building permit.  Again we used the firm that prepared the
EIR.  With their local insights, they were able to expedite processing of the building permit.  We
obtained only one building permit for the entire installation. This meant that a complete design
was submitted with the application. In the long run, it saved considerable time. One item of
concern that we had not anticipated in the building permit was the disposal of domestic waste.
The size, type, and extent of septic tanks and leach lines had to be reviewed.  This aspect of the
building permit came under the jurisdiction of the County Health Department. Again we met with
this group and finally resolved the problems caused in our case by very tight clay soil and high
water table.  Other than some minor problems and some delays in receiving equipment, the
building of the plant proceeded on schedule.  It is important to note that because of long lead
times and delays in the EIR process, certain pieces of equipment had to be ordered  before the
building permit or use permit was issued.

     Next we applied for Waste Discharge Requirements from the Central Valley Regional
Quality Control Board. The discharge of both the solid and liquid residual is controlled by
regional boards in  California.  The solid waste had to be disposed of in a manner similar to the
Santa Clara and  San Joaquin experience. The operating parameters used at these sites were im-
posed upon us.  The only difference was that we transported and spread with the same piece of
equipment, our spreader truck.  The liquid residual requirements were, primarily, written to
prevent avian botulism since the wildlife refuge is a neighbor.  In many areas the Board staff
deferred to the Department of  Fish and Game.  In essence, if we obtained DFG approval on
certain approaches and methods, the Water Quality Control  Board staff would concur.  Thus, we
started another round of meetings with  Department of Fish  and Game and  Board staffs. In the
end we were able to petition the Central Valley Regional Water Quality Control Board with a
plan and set  of requirements that were acceptable to Tri/Valley Growers, DFG, and Water Quality
Control.  Under the requirements, we have certain operating conditions such as no standing water
over 60 hours.  We also have monitoring requirements for our wastewater, ground water and rain
water. Thus, we did obtain reasonable requirements through our work with DFG and the Board
staff.

     I cannot emphasize enough the need for a well-conceived, documented plan to  present to
the Board staff.  This will certainly aid in the entire permit  application. It is also helpful when
you have a good track record with the Board staff.

     In regard to air pollution requirements,  we had to  work with the County Health Department.
In the area of the  State that I am familiar with, the  health agency is the enforcement group.  At
about the time we obtained the building permit, we  obtained a permit to construct  our boilers.
At that time we provided the Health Department with the required data regarding our two 125,000
pound boilers.  After the boilers were installed and before the plant operated, we applied for a
permit to operate.  At that time the staff inspected the installation of the boiler and the control
equipment.  There was a question regarding the burning of oil but this was resolved administratively.
The entire permitting procedure was handled administratively by the Health Department.  I am not
sure how long this will continue, especially with the new source review rules on the horizon.

     There were several unique requirements  that were imposed upon us before and during con-
struction of the  plant. Some could have been disastrous if they went against us.  First, a natural
gas line had to be  brought 6 miles from the main Pacific Gas & Electric (PG&E) line. In order
to do this, we had to gain permission from the California Highway  Department to go under 1-5,
and from the Central California Irrigation District to go under and along their main canal.  Re-
garding the gas line, PG&E had to obtain approval from the California PUC to serve our plant.
This certainly caused apprehension on our part.  As I understand it, this type of approval for our
industry could be  a thing of the past. Tri/Valley Growers had to purchase the gas line and also
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had to pay for the maintenance of the line for the first five years. We also had to have rail
access because we have to cross the tracks to get into our plant site.  We had to obtain permis-
sion from the railroad to cross the track with vehicles. Tri/Valley Growers had to install a safety
crossing and has to pay for the maintenance of the crossing.  Thus, be cognizant of what other
requirements could be imposed and deal with them as early as possible.

     In conclusion, the best advice that I can give you when building a new food  processing plant
is to allow enough time. At a minimum, two years are required to build a plant in agriculturally
zoned land. We were extremely fortunate to build the plant and operate in 18 months.  Secondly,
do your homework. Know  what permits and operating requirements are needed and what  needs
to be done to obtain them (the requirements and agencies are summarized in table IV-25). Employ
a local firm or group to assist you if you do not have extensive  knowledge and insight of the
area.  This can help from a technical as well as a public relations aspect. Tell your  story in a
positive manner.  Also, tie down the property and make the purchase contingent upon obtaining
a use permit and any other particular requirement. After you have covered the bases, be pre-
pared to  go through the agonizingly slow process of obtaining the proper permits and approvals.
Again, allow enough time!
                   Table \V-2b.-Requirements for starting a new food processing plant
                               Use permit

                                  A.  Environmental Impact Report
                                  B.  Planning Commission
                                  C.  Board of Supervisors
                               Building permit

                                 A.  Building Department
                                 B.  Health Department
                             I. Waste discharge requirements

                                 A.  Regional Water Quality Control Board
                                 B.  Department of Fish and Game
                           IV. Air pollution requirements

                                 A.  Permit to construct
                                 B.  Permit to operate
                           V.  Other requirements

                                 A.  Highway Department
                                 B.  Irrigation District
                                 C.  Public Utility Commission
                                 D.  Railroad
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                                    CASE HISTORY X


                 LAND SPREADING AND DISCING OF FOOD RESIDUALS*


INTRODUCTION

     The Cooperative for Environmental Improvement (CEI), Inc., was established in late 1969
by a group of California canners in Santa Clara County.  Its sole purpose was to manage fruit and
vegetable processing residuals from canning and freezing operations in an improved and environ-
mentally-sound manner.  The CEI operation was initiated in 1970  and has since proven highly
successful.

     The spread-and-disc operation for returning agricultural residuals to soils is now a widely
accepted practice and readily adaptable to most areas.  However, the nature and quantity of
materials handled at a site used exclusively for food processing residuals requires special attention
and equipment to preclude creation of nuisance conditions.
THE LAND

     The CEI land, located in Santa Clara and San Benito Counties, is relatively flat and is
located in a sparsely populated farming and grazing area which is subject to frequent winter flood-
ing.  The spread-and-disc sequences and the equipment items described are  those required  for the
operation of this site.  Suggestions for modifications to suit other conditions are offered.

     A site could undoubtedly be successfully operated in much closer proximity to developed
and settled areas.  The operation can be conducted on all soil types and in all but extremely wet
areas.  With modifications of the handling equipment, the spread-and-disc operation can also be
conducted on hilly land. The solid residuals handled on the CEI site are primarily from the
processing of cherries, apricots, peaches, pears, and tomatoes.  During the past four years, the
disposal operation has returned these residual materials to the soil in a nuisance-free manner,
resulting in improved soil tilth and crop productivity.  The loading rates are dictated by soil
characteristics, climatic conditions, the nature of residual materials handled, and the method
and diligence of spreading and working.


EQUIPMENT

     The tractor used in the CEI operation is a four-wheel drive unit (John Deere, International
Harvester, or equivalent), equipped  with 26.00 X 28 single tires.  A similar tractor, equipped
with 18.4 X' 38 dual wheels, has been successfully used in another operation.  However, caution
should be exercised to avoid excessively wet clay soil when using dual wheels.  "Track layers"
are not recommended since this type of equipment will tend to excessively mix the soil and
residual materials, thus hampering drying.
* Mr. Allen M. Katsuyama — National Canners Association, Berkeley, California
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     The weight of the tandem drag is important.  Too heavy a drag will tend to move soil as
well as the residuals, while too light a drag will simply ride over all materials.  The drags used
at the CEI site were fabricated from 10-inch heavy wall (3/8-inch) steel pipe, 18 feet in length.
When operations are conducted on slopes, the length of the drags should be shortened  as neces-
sary to obtain even spreading.

     Railroad iron (90 pounds per foot) was welded to the entire length of each tubing. Addi-
tionally, a  5- to 6-foot length of rail (116 pounds total weight) was  welded to the back center of
the rear drag. This piece (the actual length of which must be determined by trial-and-error) im-
parts a wobbling action to the rear drag; the motion facilitates spreading and crushing of large fruit
pieces.  All ends of the tubings were capped with steel plates. The two sections are  connected by
46-inch lengths of 1-inch chain.  The connecting length is critical for proper spreading.  The
entire unit is connected to the tractor with 20 feet of  1-inch cable and an appropriate  coupling.
The cable length is also critical in providing proper maneuverability to the tractor, especially  when
large piles are encountered.

     The recommended discs are off-set, not tandem, and equipped with notched blades.  The
unit is also equipped with four hydraulically-adjustable rubber tires to control the depth of cut.
This is an essential feature to avoid excessive  depths in wet soil.  When operating on clay soils,
the unit must be provided with additional weight.  When maneuvering at the ends of a field,
care must be exercised to avoid creating "dead furrows."  Materials deposited in such furrows
will anerobically decompose, thereby creating odors and attracting flies.

     Where soil  characteristics dictate  the need for breaking clods of soil, a Schmeizer or equiva-
lent should be provided.  This apparatus not only evens out the soil texture but also helps to
settle the  soil, thereby enabling trucks to operate in the field without becoming bogged. Use
of a clod breaker also facilitates spreading of residuals.  A variety of trucks are used  to  deliver
food processing residuals to the CEI site.  These range  from bottom-dump rigs to tank  trucks
containing a  slurry of ground material.

     The ideal equipment is a rear-dumping bed with hydraulically-operated gates. Hydraulic
cylinders with two-way valves should be protected within the bed walls and connected  to the gate
at mid-height.  By locating the control within the truck cab, close regulations of discharge  rates
may be obtained.  Dump trucks without hydraulically-operated gates must be carefully unloaded to
avoid piles of moist materials.  Chains used to limit the opening of the gates have not worked well
as a means to regulate discharge rates  because residual  characteristics vary widely.

     Long-bed trailers with up to  36-cubic yards capacity have posed problems with  uniform dis-
charging of loads and must be carefully operated. These have a tendency to tip or shift while un-
loading, thereby delaying site operations, increasing their costs, and increasing  nuisance liabilities
by creating "wet" piles.  Bottom-dumping rigs are quite satisfactory since these are generally
equipped with hydraulically-operated gates. Positive control provided by the hydraulic  system
enables these units to discharge materials in a narrow and uniform ribbon.  However, most
existing canneries cannot accommodate the double rigs.

     When slurries of ground residuals are delivered in  tank trucks, proper spreading  (light  and
even distribution) is especially critical.  A truck with a multi-valved discharge manifold should be
used. If ground materials are discharged through a single valve, splash plates to spread the dis-
charge should be provided.
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LAND PREPARATION

     To maximize the receptive capacity of the soil and to minimize problems, the land must be
prepared annually prior to disposition of any residuals. The soil should be worked to a depth of
8 to 10 inches with the discs.  Compacted soils may require initial plowing.  When large clods
occur, a suitable clod breaker should be employed.

     Although land  planning is unnecessary, the soil surface must be leveled to the extent that
no pocket holes exist.  The tandem drag used for residuals spreading may also be used for this
purpose.  It is vitally important that all holes and furrows be filled before residuals are applied,
thereby eliminating  the possibility of excessive accumulations of residuals and providing a uni-
form and moderately compacted surface for truck travel.

     Timing of the land preparation step is important.  Unlike  normal farming practices where
soils are worked to retain moisture, the land must be prepared  to obtain maximum dryness. (Dry
soils will have greater capacities for assimilating high moisture residuals.)  Therefore, land prepara-
tion should be delayed as late as possible.


OPERATION

     Undue delays in deliveries must be avoided, especially with  fruit residuals. When these
materials are allowed to sit either at the processing plant or in  an open truck, flies will inevitably
be attracted and begin  to breed.  In such a situation, fly problems at the disposal site will be un-
avoidable and difficult  to control. Past experiences indicate that pear residuals quickly develop
fruit fly populations and must be handled quickly.

     Non-processing residuals (cans, wood and metal scraps, paper) must be absolutely precluded
from the loads. The materials will interfere with the field operations and equipment and will
hamper subsequent agricultural uses of the land.  In the CEI operation, the site manager is given
full authority and responsibility to control unloaded materials.

     When residuals from numerous canneries are being delivered by several contract haulers, it
is virtually impossible to  schedule  deliveries to the site. Therefore, a full-time field supervisor
is required, especially during the peak of the season.  The supervisor must be responsible for
directing each truck to the appropriate spot in the field and assure that each load is properly
discharged and spread.

     A fluorescent triangular sign is used at the CEI site to direct and align arriving trucks.
Night deliveries are further assisted by lights.  The sign is positioned at the end of a discharge
lane so that each load will be discharged in line with the  preceding load.  The discharge lanes
should be located on not less than 20-foot centers.

     The discharge of each load should  be started  sufficiently beyond the end of the  previously
deposited load to avoid overlapping of spread materials. The residuals must be discharged from
the trucks as thinly  and evenly as  equipment and the driver's skill allow.   Hydraulically-operated
tailgates will greatly facilitate obtaining desirable distributions.   Trucks without this feature must
be carefully operated, i.e., the rate of discharge and the forward speed of the truck must be well
coordinated to avoid piles.  Ideally, the residuals should be distributed in a 4- to 8-inch layer.

     Residuals should  never  be deposited in  piles.   Free moisture will seep from such piles
making it extremely difficult to dry the soil at that spot.  These wet spots, popularly referred to
as "hot spots," generate odors and provide ideal conditions for fly breeding.  Piles delay field
operations: they necessitate additional costly work and additional time for drying.


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     The residuals must be spread and crushed with tandem drag soon after discharge.  It is vitally
important to immediately spread any materials which  have been deposited in  piles.  Residuals
which have been distributed in thick layers may require several passes with the drags to obtain
a spread that is  as thin as practicable.

     The residuals should be allowed to dry for a period of up to 48 hours.  This initial drying is
important to reduce the moisture content within the materials, thus accelerating subsequent aerobic
decomposition of the residuals by soil microorganisms. Using the drag for initial spreading aids
the drying process by crushing the larger residual fragments.

     Between the initial and later dragging steps, the residual materials are incorporated into and
mixed with the  surface soil by repeated passes with the discs. The soil should be worked to a
depth of 6 to 8 inches. Dual  rubber tires mounted on the discs are used to control the maximum
depth; the tires  are especially  required when wet soil conditions are encountered.

     As with initial land preparation, the discings are designed to maximize drying.  The fre-
quency and the  number of passes will  be determined by those local conditions which affect the
drying rate.


END-OF-SEASON PROCEDURES

Final Site Preparation

     To preclude the occurrence  of problems during the first rains following an operating  season,
the residuals must be adequately  stabilized. The operation must be continued until it is evident
after discing that the residuals are sufficiently degraded or dried.  Leveling the soil will aid surface
drainage and minimize rainwater  ponding which may contribute to later  problems.

     Special attention must be given to preventing soil erosion of hilly sites during the  off-season.
It is recommended that such areas be dry planted with barley, wheat, or other similar crops imme-
diately after the seasonal operation.


Equipment Maintenance

     In addition to the normal maintenance program, the tractor must be thoroughly washed,
steam cleaned, and  painted at  the conclusion of each season. The underside of the pickup truck
should also be steam cleaned and undercoated.  Without  diligent care, metal corrosion due to fruit
acids will be extremely severe  and costly.


CONCLUSION

     The spread-and-disc operation can be conducted in virtually any geographic area.  The
operation is basically one of good applied farming practices.  It is actually "farming" of food
residues. It consists of preparing the soil, working the disposal "crop" and the  land relative to
the material concentration, moisture content, and absorption, and doing this in a prompt and
thorough manner.  Good control  of hauling truck performance is also mandatory.
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     CEI considers its program to be one of soil enrichment.  With careful and constant attention,
most food processing residuals will be readily assimilated into the soil without creating environ-
mental problems.  As a result of this operation, definite improvements in soil tilth and crop
productivity will be achieved.

     The procedure which is followed must be tailored to each site, with consideration given to
climatic conditions, soil characteristics, topography, and the nature of residuals.  The key to a
successful operation lies with a diligent and knowledgeable site  manager.  His efforts will assure
the achievement of a  viable program for recycling agricultural organic materials back to the soil.

     A manual which illustrates the equipment at this site and complete details of the opera-
tional sequences involved can be obtained by writing to:

                      Cooperative for Environmental Improvement, Inc.
                              c/o Canners League of California
                                       1007 L Street
                                  Sacramento, CA  95814
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                                      REFERENCES
     1 Handbook for Monitoring Industrial Wastewater, U. S. Environmental Protection Agency,
Cincinnati, Ohio, 1973.

     2"Methods for Chemical Analysis of Water and Wastes," U.S. Environmental Protection
Agency, EPA-625-/6-74-003, Cincinnati, Ohio, 1974.

     ^Standard Methods for the Examination of Water and Wastewater,  (14th ed.), American
Public Health Association, New York, N.Y., 1976.

     4Tchobanoglous, G., "Investigation and Modification of Wastewater Management Facilities."
A report prepared for Hickmott Foods, Inc., Davis, California, June 1974.

     5Wood, D. K. and Tchobanoglous, G., "Trace Elements in Biological Waste Treatment with
Specific Reference to the Activated Sludge." Presented at the 29th Annual Industrial Waste
Conference, Purdue University, May 1974.
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                                      Chapter V

                                    GLOSSARY
Acidity — The quantitative capacity of aqueous solutions to neutralize bases caused by carbon
     dioxide, mineral acids, and the salts of strong acids and weak bases.

Activated carbon — An amorphorus form of carbon obtained by carbonization of cellulosic material
     possessing a high adsorptive capacity.

Activated sludge — Sludge floe produced by the growth of zoogleal bacteria and other organisms
     in the presence of oxygen and accumulated in sufficient concentration by returning floe
     previously formed.

 Activated sludge process — A biological wastewater treatment process in which a mixture of waste-
     water and activated sludge is agitated and aerated.  The activated sludge is subsequently
     separated from the treated wastewater (mixed liquor) by sedimentation and is wasted or
     returned to the process as needed.

 Adsorption— A taking up of gases or liquids by the surfaces of solids or liquids with which they
     are in contact.

 Advanced waste treatment — A term including any treatment process applied for renovation of
     wastewater that goes beyond the usual 90- to 99-percent oxygen demand and organic solids
     removal of secondary treatment.  May include nitrogen, phosphorus, other minerals, taste,
     odor, color, and turbidity removal by a variety of conventional and special processes as re-
     quired to renovate wastewater for intended reuse.

 Aerobic — Living or taking place only in the presence of oxygen.

Alkalinity — The capacity of water to neutralize acids, imparted by the content of carbonates,
     bicarbonates, hydroxides, borates, silicates, and phosphates, expressed in milligrams per liter
     or equivalent calcium carbonate.

 Alum — A trade name for the chemicals aluminum ammonium sulfate or aluminum sulfate, used  as
     a flocculentor sludge thickening agent.

 Anaerobic — Living or taking place in the absence of oxygen.

 Anaerobic digestion — The degradation of organic matter by the action of microorganisms in the
     absence of oxygen.

 Assimilative capacity — The maximum capacity of a natural body of water to receive wastewaters
     or toxic materials without deleterious effects.

 Available chlorine — A measure of the total oxidizing power of chlorinated compounds used for
     chlorination.


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                                             B

Biochemical oxygen demand (BOD) - A measure of the potential of a wastewater to utilize oxygen
     while experiencing microbial degradation; a semiquantitative measure of the organic content of
     a waste. BOD5 is the standard test conducted over a 5-day period.

Biological oxidation - The process whereby living organisms in the presence of oxygen convert the
     organic matter contained in wastewater into a more stable or a mineral form.

BOD load — The BOD content, usually expressed in pounds per unit of time,  of wastewater passing
     into a waste treatment system or to a body of water.

BOD:N:P ratio - A ratio calculated from analysis of the BOD to total nitrogen and total phosphorus
     contained in the waste stream. (To  assure  a nutrient balance within a biological treatment
     system, a ratio of 100:5:1 is generally recommended.)

Brackish water - Water having excessive chloride content ( > 10,000 mg/1) in the general range be-
     tween fresh water and seawater.

Breakpoint chlorination — The process of applying chlorine to the wastewater containing free
     ammonia in order to provide free residual chlorine.

Buffer action — The capacity exhibited by dissolved minerals that resists a large change in the pH
     of a solution.  In surface water, the primary buffer action is related to carbon dioxide, bicar-
     bonate and carbonate equilibria.

Bulking sludge — A sludge that settles poorly because of a floe with excessive volume and low den-
     sity.
Chemical oxygen demand (COD) — A measure of the potential of a wastewater to utilize oxygen
     while experiencing chemical oxidation; a semiquantitative measure of the organic content of
     a waste. It does not necessarily correlate with the BOD.

Chloramines — Compounds of organic or bounded nitrogen and chlorine.

Chlorine demand — The difference between applied chlorine and  residual chlorine remaining at the
     end of a specific contact time. Chlorine demand varies with dosage, time, temperature and
     nature of the water impurities.

Clarification — Any process or combination of processes which reduces the concentration of sus-
     pended matter.

C/N ratio _ The calculated weight ratio of carbon to nitrogen, from analytical determinations.

Coagulation _ The process of reducing the repelling forces between colloidal particles in order that
     they may combine into larger particles that are more easily settled.

Coliform group _ A group of bacteria made up of several genera of which Escherichia coli (E. coli)
     and Aerobacter aerogenes are dominant. The E. coli predominantly inhabit the intestines of
     man and animals and have therefore been used as evidence of sanitary contamination.

Colloidal particles - Finely divided solids which will not settle due to gravity alone but which may
     be  removed from a wastewater by coagulation, filtration, or biological action.

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Composite wastewater sample »- A sample made up of a series of individual grab samples or con-
     tinuous portions of wastewater with respect to some measure of flow or time.

Contact stabilization process — A modification of the activated sludge process in which raw waste-
     water is aerated with a high concentration of activated sludge for a short period, usually less
     than " 0 minutes, to obtain suspended removal by absorption. The solids are subsequently
     removed by sedimentation and transferred to a stabilization tank where aeration is continued
     further to oxidize and condition them before their reintroduction to the raw wastewater flow.

                                             D

Denitrification — 1. The removal of nitrogen from the water by conversion of oxidized nitrogen
     (nitrate and nitrite-N) to nitrogen gas.  2. A reduction process by chemical or biological reduc-
     tion.

Detritus — The coarse debris, such as sand and grit, carried by wastewater.

Diatomactuus earth —  A fine, siliceous earth consisting mainly of the skeletal remains of diatoms
     (unicellular organisms).  Also called diatomite.

Diffuser — A porous plate, tube, or other device through which air is forced and divided into min-
     ute bubbles for diffusion in liquids.

Digested sludge — The solids from either aerobic or anaerobic processes in which the volatile content
     has been reduced.

Dissolved  oxygen (DO) — Uncombined oxygen in solution in a liquid.  A minimum of 4 or 5 parts
     per million (ppm) DO is necessary for the survival of fish in streams, and a minimum of 1 or
     2 ppiix is necessary to avoid odors in wastewater.
Dissolved oxygen-sag curve — A curve that represents the profile of dissolved oxygen content along
     the course of a receiving water from deoxygenation associated with biochemical oxidation of
     organic matter and reoxygenation through the absorption of atmospheric oxygen and bio-
     logical photosynthesis. Also called oxygen-sag curve.

dissolved solids — The total amount of soluble material, organic and inorganic, contained in water
     or wastes (TDS).

Drinking water standards — 1. Standards prescribed by the US Public Health Service for the quality
     of dr'  king water supplied to interstate carriers. 2. Standards prescribed by state or local
     jurisdictions for the quality of drinking water supplied from surface water,  groundwater or
     bottled-water sources.

                                            E

Effluent - The liquid which flows out of a unit process or point.

Estuary — The mouth of a river, where  tidal effects are evident and where fresh water and sea water
     mix.

Eutrophication — The photosynthetic overproduction of biological material due to enrichment of
     the budy of water with an abundance of nutrients, such as nitrogen and phosphorus.
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Evapotranspiration — Water withdrawn from soil by evaporation and/or plant transpiration.

Extended aeration — A modification of the activated sludge process which provides for aerobic
     sludge digestion within the aeration system.
Facultative bacteria - Bacteria that can adapt themselves to growth and metabolism to either aerobic
     or anaerobic conditions.  Many organisms of interest in wastewater stabilization are among this
     group.

Fats — Any of a number of triglyceride esters of fatty acids.

Filter — A device or structure for removing solid or colloidal material that cannot be removed by
     sedimentation.

Filtrate — The liquid which has passed through a filter.

Filtration - The process of passing a liquid through a porous medium for the removal of suspended
     or colloidal material contained in the liquid by a physical straining action.

Fixed solids — The residue remaining after ignition of suspended or dissolved matter.

Floe — Solids formed by chemical, biological, or physical agglomeration of fine materials into
     larger masses that are more readily separated from the liquid. The process is called floccu-
     lation.

Flotation — The raising of suspended matter to the surface of the liquid and the subsequent re-
     moval by skimming.

F/M ratio — Food to microorganism ratio:  the weight ratio of BOD (food) in wastewater to sus-
     pended solids (microorganisms) within an activated sludge treatment system.

Fouling — A  gelatinous, slimy accumulation on the waterway of a conduit, resulting from the
     activity of organisms in the waters.  Fouling is more easily removable than tuberculation.
     Fouling may be found on concrete, masonry, and metal surfaces, but tuberculation is found
     only on metal surfaces.

Free residual chlorination — The application of chlorine or chlorine compounds to water or waste-
     water to produce a chlorine residual.

                                            G

Grease - A group of substances including fats, waxes, free fatty acids, calcium and magnesium
     soaps, mineral oils, and certain other nonfatty materials. The type of solvent and method
     used for extraction should be stated for quantitation.

Grit — The heavy suspended mineral matter present in water or wastewater, such as sand, gravel,
     and cinders.

                                            H

Hardness - The sum of the polyvalent cations of calcium, magnesium, and iron such as bicarbonates,
     carbonates, sulfates, chlorides and nitrates, expressed as the equivalent quantity of calcium
     carbonate.

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Hydrolysis — A change in the chemical composition produced by a reaction with water to form one
     or more new substances.

                                              I

Infiltration — 1. The penetration of water through the soil from surface precipitation, stream or
     impoundment boundaries. 2. The entrance of groundwater into a sewer through breaks, defec-
     tive joints or porous walls.

Influent — Water, wastewater, or other liquid flowing into a reservoir, basin, or treatment plant, or
     any unit thereof.

Integrator — A device for indicating the total quantity of flow through a measuring device, such as
     a Parshall flume or weir.

Intermediate treatment — Wastewater treatment such as aeration or chemical treatment, supple-
     mentary to primary treatment.  Such treatment removes substantial percentages of very finely
     divided particulate matter, in addition to the suspended solids removed by primary treatment.
     Supplementary processing improves the efficiency of treatment so that about 60 percent of
     both BOD and suspended solids are removed.

lodophor — A germicide consisting of a mixture of iodine and a carrier. The carrier is a surfactant
     which stabilizes the iodine. Reaction of iodophors is similar to chlorine.

Ion-exchange — 1. A chemical process involving reversible interchange of ions between a liquid  and
     a solid but no radical change in structure of the solid. 2. A chemical process in which ions from
     two different molecules are exchanged. 3. Ion-exchange treatment of water or wastewater in-
     volves the use of ion-exchange materials such as resin or zeolites to remove undesirable ions
     from a liquid and substitute acceptable ions.

                                             K

Kraus process — A modification of the activated sludge process in which aerobically conditioned
     supernatant liquor from anaerobic digesters is added to activated sludge aeration tanks to im-
     prove the settling characteristics of the sludge and to add an oxygen resource in  the form of
     nitrates.
Land disposal _ 1. Disposal of wastewater onto land by spray or surface irrigation. 2. Disposal of
     solid waste materials by incorporating the solid waste into the soil by cut-and-fill techniques
     or by sanitary landfill operations.

Leaching — 1. The removal of soluble constituents from soils or other material by percolating
     water.  2. The removal of salts and alkali from soils by abundant irrigation combined with
     drainage. 3. The disposal of a liquid through a non-watertight artificial structure, conduit, or
     porous material by downward or lateral drainage or both, into the surrounding permeable
     soil.  4. The loss of soluble constituents from fruits, vegetables, or other material into water
     or other liquid in which the material is immersed. 5. The escaping of free moisture from a
     solid waste land disposal site into the surrounding environment, frequently causing odors and
     other nuisance conditions of public health  significance.
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Loading - The quantity of waste, expressed in gallons (hydraulic load) or in pounds of BOD, COD,
     suspended or volatile solids (organic load), which is discharged to a wastewater treatment
     facility.

                    ,_.   ,.    ,     ,  ,   mg/1 (X) x Q (gallons) x 8.34
                    (X) loading (pounds) = -&	1>0oo,000	

     where X  = BOD, COD, SS, P, N, etc.

                                            M

Membrane filtration - A method of quantitative or qualitative analysis of bacterial or particulate
     matter  in a water sample by  filtration through a membrane capable of retaining bacteria.

Mesh _ One of the openings or spaces in a screen.  The value of the mesh is usually given as the
     number of openings per linear inch.  This gives no recognition to the diameter of the wire,
     and thus the mesh number does not always have a definite relation to the size of the hole.

Mesophilic range —  Operationally, that temperature  range most conducive to the maintenance of
     optimum digestion by mesophilic bacteria, generally accepted as between 27° and 32 ° C (80°
     and 90 °  F).

mg/1 — Abbreviation for milligrams per liter. A unit of the concentration of water or wastewater
     constituent.  It is 0.001 g of the  constituent in 1,000 ml of water. It has replaced the unit
     formerly used, parts per million, to which it is approximately equivalent, in reporting the
     results  of water and wastewater analysis.

Mixed liquor — A mixture of activated sludge and organic matter undergoing activated sludge treat-
     ment in the aeration tank.

MLVSS — Abbreviation for mixed liquor volatile suspended solids contained in the mixed liquor of
     an activated  sludge treatment system which is lost on ignition of the dry  solids at 600 ° C.

Modified aeration — A modification of the activated sludge process in which a shortened period of
     aeration is used with a reduced quantity of suspended solids in the mixed liquor.

Most probable number (MPN) — That number or organisms per unit volume that, in accordance
     with statistical theory, would be more likely than any other number to yield the observed test
     result or that would yield the observed test result with the greatest frequency. Expressed as
     density of organisms per 100 ml. Results are computed from  the number of positive findings
     of coliform-group organisms resulting from multiple-portion decimal-dilution plantings.

                                            N

Natural purification — Natural processes occurring in a stream or other body of water that result
     in the reduction of bacteria, satisfaction of the BOD, stabilization of organic constituents,
     replacement of depleted'dissolved oxygen, and the return of the stream biota to normal.
     Also called self-purification.

Navigable water — Any stream, lake, arm of the sea, or other natural body of water that is actually
     navigable and that, by itself  or by its connections with other waters, is of sufficient capacity
     to float watercraft for the purposes of commerce, trade, transportation or even pleasure for a
     period long enough to be of commercial value;  or any waters that have been declared navi-
     gable by the Congress of the United States.
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Nitrification — 1. The conversion of nitrogenous matter into nitrates by bacteria. 2. The treatment
     of a material with nitric acid.

Nitrogen cycle — A graphical presentation of the conservation of matter in nature,  from living ani-
     mal matter through dead organic matter, various stages of decomposition, plant life, and the
     return of living animal matter, showing changes which occur in course of the cycle.  It is used
     to illustrate biological action and also aerobic and anaerobic acceleration of the transformation
     of this element by wastewater and sludge traetment.

Nitrogenous wastes - Wastes of animal or plant origin that contain a significant concentration of
     nitrogen.

Nutrient — A substance that promotes cellular growth in organisms. Compounds of nitrogen and
     phosphorus are of concern in  wastewaters due to their encouragement of overenrichment of
     water bodies.

                                             O

Oils — 1. Liquid fats of animal or vegetable origin. 2. Oily or waxy mineral oils.

Outfall — \. The point, location, or structure where wastewater or drainage discharges from a
     sewer, drain, or other conduit. 2. The conduit leading to the ultimate disposal area.

Oxidation process (treatment) — Any method of wastewater treatment for the oxidation of the
     putrescible organic matter. The usual methods are biological filtration and the activated
     sludge process. Living organisms in the presence of air are utilized to convert the organic
     matter into more stable or mineral form.

Oxygenation capacity — In treatment processes, a measure of the ability of an aerator to supply
     oxygen to a liquid.

Oxygen demand — The quantity of oxygen utilized in the biochemical oxidation of organic matter
     in a specified time, at a specified  temperature, and under specified conditions.   See  BOD.

Ozone — Oxygen in molecular form with three atoms of oxygen forming each molecule (03).

                                            P

ParshaU flume  — A calibrated device developed by Parshall for measuring the flow of liquid in an
     open conduit. It consists essentially of a contracting length, a throat, and an expanding length.
     Flows through the device are determined by measuring the head of water at a  specific distance
     from a sill over which water passes.

Particulate matter — Refers to detectable solid materials dispersed in a gas or liquid. Small sized
     particulates may produce a smoky or hazy appearance in a gas or a milky or turbid appearance
     in a liquid. Larger particulates are more readily detected and  separated by sedimentation or
     filtration.

Parts per million (ppm) — The number of weight or volume of units of a minor constituent present
     with each one million units of the major constituent of a solution or mixture.   Formerly used
     to express the results of most water and wastewater analyses,  but more recently replaced by
     the ratio  milligrams per liter.  See mg/l.
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Percolation — 1. The flow or trickling of a liquid downward through a contact or filtering medium.
     The liquid may or may not fill the pores of the medium. Also called filtration. 2. The move-
     ment or flow of water through the interstices or the pores of a soil or other porous medium.
     3.  The water lost from an unlined conduit through its sides and bed.

Permeability -  1. The property of a material that permits appreciable movement of water through
     it when it is saturated and the movement is actuated by hydrostatic pressure of the magnitude
     normally encountered in natural subsurface water.  Perviousness is sometimes used in the same
     sense as permeability.  2. The capability of a rock or rock material to transmit a fluid.

pH — The negative logarithm of the hydrogen ion concentration. The concentration is the weight
     of hydrogen ions, in grams, per liter of solution. pH values reflect the balance between
     acids and alkalies. The extreme readings are 0 and 14. The pH of most natural waters falls
     within the range 4 to 9. Neutral water, for example, has a pH value of  7.0 and a hydrogen ion
     concentration of 10"7 Slight decrease in pH may greatly increase the toxicity of substances
     such as cyanides, sulfides, and most metals. Slight increase may greatly increase the toxicity
     of pollutants such as ammonia.  Alkaline water will tend to form a scale; acid water is corro-
     sive.

Pollutional load — 1. The quantity of material in a waste stream that requires treatment or exerts
     an adverse effect on the receiving system. 2. The quantity of material  carried in a body of
     water that exerts a detrimental effect on some subsequent use of that water.

Polymer — Any one of several commercially available high molecular weight, water-soluble polymeric
     flocculation agents.  When added to water, these substances form a flocculent precipitate
     which will agglomerate or coagulate suspended matter and expedite sedimentation.

Population equivalent — 1.  The calculated population which would normally contribute the same
     amount of biochemical oxygen demand (BOD) per day. A common base is 0.167 Ib. of 5-day
     BOD  per capita per day. 2. For an industrial waste, the estimated number of people contri-
     buting sewage equal in strength to a unit volume of the waste or to some other unit involved
     in  producing or manufacturing a particular commodity.

Potable water — Water that does not contain objectionable pollution, contamination, minerals, or
     infective agents and is considered satisfactory for domestic consumption.

Precipitate — The formation of solid particles in a solution, or the solids that settle as a result of
     chemical or physical action that caused solids separation.

Preliminary treatment — 1. The conditioning of a waste at its source before discharge,  to remove
     or to neutralize substances injurious to sewers and treatment processes  or to effect a partial
     reduction in load on the treatment process.  2.  In the treatment process, unit operations
     (such as screening and comminution) that prepare the liquor for subsequent major operations.

Primary settling tank — The first settling tank for the removal of settleable solids through which
     wastewater is passed in a treatment works.

Primary treatment — The first major treatment designed to remove from wastewater organic and
     inorganic solids by the physical process of sedimentation.

Process  water - Water (liquid or vapor) that comes in contact with an end product or with ma-
     terials incorporated in an end product.
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                                             R

Rapid sand filter _ A filter for the purification of water, in which water that has been previously
     treated, usually by coagulation and sedimentation, is passed downward through a filtering
     medium. The medium consists of a layer of sand, prepared anthracite, coal, or other suitable
     material, usually 24 to 30 inches thick, resting on a supporting bed of gravel or a porous
     medium such as carborundum. The filtrate is removed by an underdrainage system which
      also distributes the wash water.  The filter is cleaned periodically by reversing the flow of the
     water upward through the filtering medium, sometimes supplemented by mechanical or air
     agitation during washing, to remove mud and other impurities which have lodged in the sand.
     It is characterized by a rapid rate of filtration, commonly from 2 to 3 gallons per minute  per
     square foot of filter area.

Receiving waters _ A natural watercourse, lake, or ocean into which treated or untreated waste-
     water is discharged.

Residual chlorine — Chlorine remaining in water or wastewater at the end of a specified  contact
     period as combined or free chlorine.

Reverse osmosis — A process in which, if pressure is put on  the concentrated side of a liquid system
     in which liquids with different concentrations of mineral salts are separated by a semipermeable
     membrane, molecules of pure water pass out of the concentrated solution to the weak or
     fresh water side (contrary to the case of normal osmosis).

Riprap — Broken stone or boulders placed compactly or irregularly on dams,  levees, dikes, or sim-
     ilar embankments for protection of earth surfaces against the action of waves or  currents.

Roughing filter — In wastewater treatment, a trickling filter containing coarse material or plastic
     medium operated at a high rate to afford partial treatment preliminary to a secondary treat-
     ment operation. By using a roughing filter, the organic loading imposed on the subsequent
     biological system is significantly  reduced.

Runoff — 1. That portion of rainfall or melted snow which runs off the surface of a drainage area
     and reaches a stream or other body of water or a drain or sewer.  Runoff is faster and greater
     during heavy rain than during protracted drizzle, on clay soils than on sandy soils, on frozen
     soils than on frostless  soils, in treeless areas than in forests. The ratio between runoff and
     rainfall varies considerably  with climatic conditions. 2. Total quantity of runoff water dur-
     ing a specified time. 3. In  the general sense, that portion of the precipitation which is not
     absorbed by the deep  strata, but finds its way into the streams after meeting the persistent
     demands of evapotranspiration, including interception and other losses.  4. The discharge of
     water in surface streams, usually expressed in inches depth on the drainage area,  or as volume
     in such terms as cubic feet or acre-feet.
Saline water — Water containing dissolved salts, usually from 10,000 to 33,000 mg/1.

Sand filter — A filter in which sand is used as a filtering medium. Also see rapid sand filter, slow
     sand filter.

Scum baffle — A verticle baffle dipping below the surface of wastewater in a tank to prevent the
     passage of floating matter.  Also called scum board.
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Secondary wastewater treatment — The treatment of wastewater by biological methods after pri-
     mary treatment by sedimentation. Common methods of treatment include trickling filtration,
     activated sludge processes, and oxidation.

Sedimentation - The process of subsidence and deposition of suspended matter carried by water,
     wastewater, or other liquids, by gravity. It is usually accomplished by reducing the velocity of
     the liquid below the point at which it can transport the suspended material.  Also called
     settling.

Self-cleansing velocity — The minimum velocity in sewers necessary to keep solids in suspension,
     thus preventing their deposition and subsequent nuisance from stoppages and odors of decom-
     position.

Self-purification — The natural processes occurring in a stream or other body of water that result in
     the reduction of bacteria, satisfaction of the BOD, stabilization of organic constituents, re-
     placement of depleted dissolved oxygen, and the return of the stream biota to normal. Also
     called natural purification.

Settleable solids — 1. That matter in wastewater which will not stay in suspension during a pre-
     selected settling period (such as one hour) but settles  to the bottom.  2.  In the Imhoff cone
     test, the volume of matter that settles to the bottom of the cone in one hour.

Skimming tank — A tank so designed that floating matter will rise and remain on the surface of the
     wastewater until removed, while the liquid discharges continuously under curtain walls or
     scum boards.

Slimes — Substances of viscous organic nature, usually formed from microbiological growth.

Sloughing — A phenomenon  associated with trickling filters and contact aeration units where slimes
     or biological growth build up on the media and then slip  off into the discharged flow.

Slow sand filter — A filter for the purification of water in which water without previous treatment
     is passed downward through a filtering medium consisting of a layer of sand or other suitable
     material, usually finer than for a rapid sand filter and  from 24 to 40 inches thick. The filtrate
     is removed by an underdrainage system and the filter  is cleaned by scraping off and replacing
     the clogged layer. It is characterized by a slow rate of filtration, commonly 3 to  6 mgd/acre
     of filter area.

Sludge _ 1.  The accumulated solids separated from liquids (such as water or wastewater) during
     processing, or deposits on bottoms of streams or other bodies of water.  2. The precipitate
     resulting from chemical treatment, coagulation,  or sedimentation of water or wastewater.

Sludge conditioning— Treatment of liquid sludge before dewatering to facilitate dewatering and
     enhance filtering, usually by the addition of chemicals.

Sludge density index (SDI) - The reciprocal of the sludge volume index multiplied by 100.

Sludge digestion - The process by which organic or volatile matter in sludge is gasified, liquified,
     mineralized, or converted into more stable organic matter through the activities of either
     anaerobic or aerobic organisms.

Sludge treatment— The processing of wastewater sludges to render them innocuous. This may be
     done by aerobic or anaerobic digestion followed by drying on sand beds, filtering, and incin-
     eration, filtering and drying, or wet air oxidation.


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Sludge volume index (SVI) — The ratio of the volume in milliliters of sludge settled from a 1000-ml
     sample in 30 minutes to the concentration of suspended solids in milligrams per liter multi-
     plied by  1,000.

Solids-contact clarifier — A unit in which liquid passes upward through a solids blanket and dis-
     charges at or near the surface.

Solute — The  substance dissolved in a solution.  A solution is made up of the solvent and the solute.

Solvent — Liquid used to dissolve a substance.

Sparger — An  air diffuser designed to give large bubbles, used singly or in combination with mech-
     anical aeration devices.

Specific conductance — A measure of a water's capacity to convey an electric current.  This prop-
     erty is related to the total concentration of the dissolved ionized substances in the water and
     the temperature at which the conductance is measured.

Spaerotilus — A filamentous, sheath-forming bacterium, often considered the  organism responsible
     for bulking sludge.  In polluted streams, the  presence of this bacterium is evidenced by fibrous
     growths adhering to rocks and plants along the stream bed.

Stabilization —  1.  Maintenance at a relatively nonfluctuating level, quantity, flow, or condition.
     2.  In lime-soda water softening, any process that will minimize or eliminate scale-forming
     tendencies. 3. In waste treatment, a process used to equalize wastewater  flow composition
     prior to regulated discharge. 4. In erosion control, treatment of dikes or shorelines with
     riprap, sod, penetrations, or similar protective devices.  5. In corrosion control, pH adjustment
     of water to maintain carbonate equilibrium at the saturation point.

Stage aeration — Division of activated sludge treatment into stages with intermediate settling tanks
     and return of sludge in each stage.

Standard methods — Unless otherwise specified, it refers to the latest edition of Methods for the
     Examination of Water and Wastewater published jointly by the American  Public Health Asso-
     ciation, the American Water Works Association, and the Water Pollution Control Federation.

Step aeration —  A procedure for adding increments of settled wastewater along the line of flow in
     the aeration tanks of an activated sludge plant.

Substrate — 1. The substances used by organisms in liquid suspension.  2. The liquor in which
     activated sludge or other matter is kept in suspension.

Supernatant liquor _ 1. The liquor overlying deposited solids. 2. The liquid in a sludge-digestion
     tank that lies between sludge at the bottom and floating scum at the top.

Suspended solids (SS) — Those inorganic and organic particles which exist in suspension in a liquid
     and which may be partially removed by gravity settling and completely removed by filtration.
Tapered aeration — The method of supplying varying amounts of air into the different parts of an
     aeration tank.
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Tertiary treatment — Treatment beyond normal or conventional secondary methods for the pur-
     pose of increasing water reuse potential.

Thermal pollution - Impairment of water through temperature change due to geothermal, industrial,
     or other causes.

Thermophilic range— That temperature range most conducive to maintenance of optimum digestion
     by thermophilic bacteria, generally accepted as between 120° and 135  F.

Totalizer - A device for indicating the total quantity of flow through a measuring device.  Also called
     integrator.

Total organic carbon (TOC) — A test expressing wastewater contaminant concentration in terms of
     the organic carbon content.

Total solids — A measure of both suspended and dissolved solids.

Toxic substance — A substance that either directly poisons living things or alters their environment
     so that they  die.

Transpiration — The process by which water vapor is lost to the atmosphere from living plants.

Trickling filter —  A structure containing an artificial bed of coarse material, such as broken stone,
     clinkers, slate, slats, or plastic materials, over which wastewater is distributed, giving oppor-
     tunity for the formation of zoogleal slimes which clarify and oxidize the wastewater through
     biological  oxidation.

Turbidity - The presence of suspended matter, resulting in the scattering and absorption of light
     rays.

Turnover — A phenomenon usually occurring in spring and fall because of the increase in density
     of water above and below the temperature of maximum density. In the spring, as the surface
     of the water warms above the freezing point, the water increases in density, becomes heavier,
     and tends  to sink, producing vertical currents, while in the fall, as the surface water becomes
     cooler and therefore heavier, it also tends to sink.  Also called overturning.  It is of particular
     importance to the operation of ponds  and lagoons.

                                            U

Ultimate biochemical oxygen demand — 1.  Commonly, the total quantity of oxygen required to
     satisfy completely the first-stage biochemical oxygen demand.  2. More strictly, the quantity
     of oxygen required to satisfy completely  both the first-stage and the second-stage biochemical
     oxygen demands.

Undigested sludge - Settled sludge promptly removed from sedimentation tanks before decompo-
     sition has much advanced.  Also  called raw sludge.

Unloading — The  periodic or continuous sloughing of the biological film from the medium on which
     it has been growing.

Upflow contact clarifier — A unit in which  water enters the bottom and is discharged at or near the
     surface. See solids contact clarifier.
                                            98

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Vacuum filter _ A filter consisting of a cylindrical drum mounted on a horizontal axis, covered with
      filtering material made of wool, felt, cotton, saran, nylon, dacron, polyethylene or similar sub-
      stance, by stainless steel coil springs or metal screen, revolving with a partial submergence in
      the liquid. A vacuum is maintained under the filter medium for the larger part of a revolution
      to extract moisture. The cake is scraped off continuously.

Venturi meter - A differential meter for measuring flow of water or other fluid through closed
     conduits or pipes, consisting of a venturi tube and one of several proprietary forms of flow-
     registering devices.  The difference in velocity heads between the entrance and the contracted
     throat is an indication of the rate of flow.

Volatile acids — Fatty acids containing six or less carbon atoms, which are soluble in water and
     which can be steam-distilled at atmospheric pressure.  Volatile acids are commonly reported
     as equivalent to acetic acid.

Volatile solids — Organic solids which are combustible at 600° C.

                                             W

Watercourse — A channel in which the flow of water occurs, with some degree of regularity, in a
     definite direction.

Water cycle — The circuit of water movement from the atmosphere to the earth and return to the
     atmosphere through various stages or processes such as precipitation, interception, runoff,
     infiltration, percolation, storage, evaporation, and transpiration. Also called hydrologic cycle.

Water quality standards — Limits set by authority on the basis of water quality criteria required for
     beneficial uses. Limits are imposed on the physical and chemical characteristics required for
     specific beneficial use.

Water softening  — The process of removing from water, in whole  or in part,  those cations which
     produce hardness.

Weir — A diversion dam with an edge or notch sometimes arranged to measure flow.

Wet oxidation process — A method of sludge disposal that involves the oxidation of sludge solids
     in water suspension and under increased pressure and temperature.
 Zeolite — A group of hydrated aluminum complex silicates, either natural or synthetic, with cation-
     exchange properties.

 Zeolite process _ The process of softening water by passing it through a natural ion exchange
     substance known as zeolite.

 Zooglea — A jelly-like matrix developed by bacteria.  A major part of activated sludge floe and of
     trickling filter slimes.
                                             99

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                                            METRIC CONVERSION TABLES
Recommended Units
Description
Length






Area







Volume



Mass




Force





Moment or
torque



Flow (volumetric)


Unit
meter

kilometer
millimeter
micrometer or
micron

square meter
square kilometer
square millimeter
hectare




cubic meter

litre

kilogram
gram
milligram
tonne

newton





newton meter




cubic meter
per second
liter per second
Symbol
m

km
mm
/jm at n


m2
km2
mm2
ha




m3

1

kg
9
mg
t

N





N-m




m3/s

l/s
Comments
Basic SI unit









The hectare (10,000
m2) is a recognized
multiple unit and will
remain in interna-
tional use.




Basic SI unit


1 tonne = 1,000 kg

The newton is that
force that produces
an acceleration of
, , 2 •
1 m/s^ in a mass
of 1 kg.

The meter is mea-
sured perpendicular
to the line of action
of the force N.
Not a joule.



Customary
Equivalents*
39.37m = 3.281ft =
1.094yd
0.6214 mi
0.03937 in
3.937 X lQ-5in= 1 X 104 A


10.76 sq ft = 1.196sqyd
0.3861 sq mi -247.1 acres
0.001550 sq in
2.471 acres




35.31 cuft= 1.308 cu yd

1.057 qt = 0.2642 gal =
0.8107 X 10^ acre ft
2.205 Ib
0.03527 oz- 15.43 gr
0.01543 gr
0,9842 ton (long) =
1.102 ton (short)
0.2248 Ib
= 7.233 poundals




0.7375 Ib-ft
23.73 poundal-ft



15.850 gpm =
2,119cfm
15.85gpm
Description
Velocity
linear






angular


Viscosity



Pressure or
stress







Temperature


Work, energy,
quantity of heat







Power


Recommended Units
Unit

meter per
second
millimeter
per second
kilometers
per second

radians per
second

pascal second

centipoise

newton per
square meter
or pascal

kilonewton per
square meter
or kilopascal

bar

Celsius (centigra
Kelvin (abs.)

joule






kilojoule

watt
kilowatt
joule per second

Application of Units
Description
Precipitation,
run-off,
evaporation





Flow



Discharges or
abstractions.

yie



Usage of water



Unit
millimeter







cubic meter
per second

liter per second
cubic meter
per day


cubic meter
per year

liter per person
per day


Symbol
mm







m3/s


l/s
m3/d


m3/year


1 /person/
day


Comments
For meteorological
purposes, it may be
convenient to meas-
sure precipitation in
terms of mass/unit
area (kg/m2}.
1 mm of rain =
1 kg/m2




1 l/s = 86.4 m3/d









Customary
Equivalents*








35.31 cfs


15.85gpm
0.1835gpm


264. 2 gal/year


0.2642 gcpd



Description
Density





Concentration

BOD loading


Hydraulic load
per unit area,
e.g., filtration
rates


Air supply



Optical units

Unit
kilogram per
cubic meter




milligram per
liter (water)
kilogram per
cubic meter
per day
cubic meter
Symbol

m/s

mm/s

km/s


rad/s


Pa-s

Z

N/m2
or
Pa

kN/m2
or
kPa

bar

ide) °C
°K

J






kJ

W
kW
J/s

Comments


























1 joule = 1 N-m
where meters are
measured along
the line of action
of force N.




1 watt = 1 J/s


Customary
Equivalents"

3.281 fps

0.003281 fps

2,237 mph


9.549 rpm


0.6722 poundal(s)/sq ft

1.450 X 10'7 Reyn (M)

0.0001450 Ib/sq in


0.14507 Ib/sq in


14. 50 Ib/sq in

(°F-32)/1.8
°C + 273.2

2.778 X 10'7
kw-hr =
3.725 X 10'7
hp-hr = 0.7376
ft-lb = 9.478 X
1Q-4 Btu

2.778 X ID"4 kw-hr

44.25 ft-lbs/min
1.341 hp
3.412 Btu/hr

Application of Units
Symbol
kg/m3





mg/l

kg/m3/d


m3/m2/d
per square meter
per day



cubic meter or
liter of free air
per second

lumen per
square meter



m3/s

l/s

lumen/m2

Comments
The density of water
under standard
conditions is 1,000
kg/m3or!,000g/l
or 1 g/ml.






If this is converted
to a velocity, it
should be expressed
in mm/s (1mm/s =•
86.4 m3/m2/day).







Customary
Equivalents*
0.06242 Ib/cu ft





1 ppm

0.06242 Ib/cu ft/day


3.281 cu ft/sq ft/day








0.09294 ft candle/sq ft

'Miles are U.S. statute, qt and gal are U.S. liquid, and oz and tb are avoirdupois.
& U. S. GOVERNMENT PRINTING OFFICE  1977-757-056/6^7 Region No. 5-11

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