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DISCLAIMER
This material has been funded wholly or in part by the United States
Environmental Protection Agency under contract 68-03-3389 to PEI Associates,
Inc. It has been subject to the Agency's review and it has been approved for
publication as an EPA document. Mention of trade names or commercial products
does not constitute endorsement or recommendation for use.
11
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ABSTRACT
Rotary Kiln incineration tests were performed on two wastewater
treatment sludges generated by wood preserving processes, RCRA Waste Code
K001. This summarizes the information on waste characteristics, presents an
evaluation of the treatment technology (incineration), discusses sampling and
analytical problems/corrective actions, and presents the results of emission
tests and the analysis of wastewater discharges. This report supplements
earlier reports entitled "Onsite Engineering Report of Treatment Technology
Performance and Operation for Incineration of KOOl-Pentachlorophenol (PCP)
Waste at the U.S. Environmental Protection Agency Combustion Research
Facility" and "Onsite Engineering Report of Treatment Technology Performance
and Operation for Incineration of KOOl-Creosote Waste at the John Zink Co.
Test Facility."
The work described in this report was submitted by PEI Associates as
partial fulfillment of Contract 68-03-3389. These reports were prepared in
support of OSW's development of best demonstrated available technology (BOAT)
for complying with the restriction rules on land disposal. This report
covers a period from March 1987 to September 1989 and work was completed as
of September 1989.
iv
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CONTENTS
Foreword iii
Abstract iv
Figures vii
Tables viii
1. Introduction 1
Project background 1
Purpose 1
Scope and objectives 2
Report organization 2
2. Summary of Findings 3
Generation of K001 3
Waste characteristics 3
Current treatment 3
Results of test burns 6
Effectiveness of treatment 8
3. Waste Characterization 9
Waste generation 9
Analysis for major constituent 11
Significant parameters 14
4. Treatment Technology Evaluated 15
Description of incineration systems 15
Test data 21
Effectiveness of treatment 89
5. Sampling and Analytical Problems and Corrective Actions 91
General quality assurance concerns 91
Specific sampling problems 91
Results of quality assurance analyses 94
Atmospheric emission tests 96
6. Other Results 98
Atmospheric emission tests 98
Summary of results 98
Statistical Evaluation of Test Burn Data 109
Non-BDAT parameters 113
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CONTENTS (continued)
Page
References 119
Appendices (copies may be obtained from the EPA project monitor)
A. Correspondence A-l
B. Pilot-Scale Incineration Tests of Wastewater Treatment
Sludge From Pentachlorophenol Wood-Preserving Process
(K001) B-l
C. Incineration Test Burn of K001 Creosote Waste for PEI
Associates on October 5, 6, and 7, 1987 C-l
D. Analytical Results, Combustion Research Facility Test
Burn of K001 PCP Wastes D-l
E. Analytical Results, Combustion Research Facility Test
Burn K001 Creosote Wastes E-l
F. Emission Test Report, Incineration Tests of K001 (Creosote)
at the John Zink Facility F-l
VI
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FIGURES
Number Page
1 Number of U.S. Wood-Preserving Facilities by State and
EPA Region 4
2 Schematic of Wood-Preserving Process 10
3 CRF Rotary-Kiln Incineration System and Sampling Points 18
4 John Zink Rotary-Kiln Incineration System and Sampling
Points 20
vn
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TABLES
Number Page
1 Major Constituents of Untreated K001 Waste 5
2 Untreated K001 Waste Total Composition 12
3 Design Characteristics of the CRF Rotary-Kiln System 16
4 Analyte Decision Matrix for Waste Code K001-PCP 23
5 Analyte Decision Matrix for Waste Code KOOl-Creosote 24
6 K001-PCP Sample Information 25
7 K001-PCP Feed and Ash Composition—Analysis of Volatile
Organics by Using Tetraglyme Extract 26
8 K001-PCP Feed and Ash Composition—Analysis of Volatile
Organics by Using Methanol Extract 28
9 Semivolatile Organics Results for K001-PCP Feed Samples 31
10 Metals Analysis for K001-PCP Feed Samples 33
11 Total Organic Carbon Data for K001-PCP Feed Samples 34
12 K001-PCP Feed Dioxin/Furan Results 34
13 Semivolatile Organic Results for K001-PCP Ash Extract 35
14 Metals Analysis for K001-PCP Ash Samples 37
15 Total Organic Carbon Data for K001-PCP Ash Samples 38
16 K001-PCP Ash Dioxin/Furan Results 38
17 Volatile Organic Results for K001-PCP Ash Subject to TCLP 39
18 TCLP Semivolatiles Organic Results for K001-PCP Ash 41
19 Metals Analysis for K001-PCP TCLP Extracts of Ash Samples 43
20 Volatile Organic Results for K001-PCP Scrubber Water 44
viii
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TABLES (continued)
Number Page
21 Semi volatile Organic Results for K001-PCP Scrubber Water 46
22 Metals Analysis for K001-PCP Scrubber Water Samples 48
23 Purgeable/Nonpurgeable Organic Carbon Data for K001-PCP
Scrubber Water Samples 49
24 K001-PCP Scrubber Dioxin/Furan Results 49
25 KOOl-Creosote Sample Information 51
26 GC/MS Volatile Organic Results for KOOl-Creosote Feed 52
27 Semivolatile Organic Results for KOOl-Creosote Waste
Feed Samples 54
28 Metals Analysis Results for KOOl-Creosote Feed Samples 57
29 KOOl-Creosote Feed Total Organic Carbon Results 58
30 KOOl-Creosote Feed Sample ZK01C-1-A1 Ultimate and
Proximate Analyses Results 58
31 KOOl-Creosote Feed Sample Organophosphorous Pesticide
Results 59
32 KOOl-Creosote Waste Feed Organochlorine Pesticide Results 60
33 KOOl-Creosote Waste Feed Samples Chlorinated Herbicides
Results 61
34 KOOl-Creosote Feed Samples Dioxin/Furan Results 61
35 GC/MS Volatile Organic Results for KOOl-Creosote Ash 62
36 Semi volatile Organic Results for KOOl-Creosote Ash Samples 64
37 Metals Analysis Results for KOOl-Creosote Ash Samples 67
38 KOOl-Creosote Ash Samples Total Organic Carbon Results 68
39 KOOl-Creosote Ash Samples Organophosphorous Pesticide
Results 69
40 KOOl-Creosote Ash Sample Organochlorine Pesticide Results 70
ix
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TABLES (continued)
Number Page
41 KOOl-Creosote Ash Samples Chlorinated Herbicides Results 71
42 KOOl-Creosote Ash Samples Dioxin/Furan Results 72
43 Volatile Organic Results for KOOl-Creosote Ash Subjected
to TCLP 73
44 TCLP Semivolatile Organic Results for KOOl-Creosote
Ash Samples 75
45 Metals Results for KOOl-Creosote Ash TCLP Extraction
Samples 78
46 GC/MS Volatile Organic Results for KOOl-Creosote Water
Samples 79
47 Semivolatile Organic Results for KOOl-Creosote Scrubber
Water 81
48 Metals Analysis Results for KOOl-Creosote Scrubber Water 84
49 KOOl-Creosote Aqueous Samples Waste Quality Parameter
Results 85
50 KOOl-Creosote Water Samples Organophosphorous Pesticide
Results 86
51 KOOl-Creosote Water Sample Organochlorine Pesticide
Results 87
52 KOOl-Creosote Water Samples Chlorinated Herbicides Results 88
53 KOOl-Creosote Water Samples Dioxin/Furan Results 88
54 Deviations from the Site Test Plan/Quality Assurance
Project Plan 92
55 Volatile Organic Constituents in the Scrubber Discharge
Flue Gas 99
56 Semivolatile Organic Hazardous Constituents in Flue Gas
Samples 100
57 K001-PCP Test Operating Conditions: Air-Pollution-
Control System 101
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TABLES (continued)
Number Page
58 Volatile Organic Compounds Sought in the K001-PCP Test
Sample Analyses 101
59 Semivolatile Organic Compounds Sought in the K001-PCP
Test Sample Analyses 103
60 ' POHC DRE's for the K001-PCP Test Burn 105
61 Results for Critical Emission Parameters for the K001-
Creosote Test Burn 106
62 Summary of Sample and Analytical Procedures for the
KOOl-Creosote Test Burn 107
63 Summary of Particulate Emission Data From KOOl-Creosote
Test Burn 108
64 Summary of HC1 Emission Data From KOOl-Creosote Test Burn 108
65 Summary of Semivolatile Organic Feed Rate Data From KOOl-
Creosote Test Burn 110
66 Summary of Data on Semivolatile Organic Concentrations
and Mass Emission Rates 111
67 Summary of Semivolatile Organic ORE Data 111
68 Summary of BDAT-List Metals Emission Data From KOOl-
Creosote Test Burn 112
69 Concentration and 99 Percent Upper Confidence Limits
For Compounds Detected in K001-PCP Samples 114
70 Concentrations and 99 Percent Upper Confidence Limits
For Compounds Detected in KOOl-Creosote Samples 116
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SECTION 1
INTRODUCTION
PROJECT BACKGROUND
The Risk Reduction Engineering Laboratory (RREL) of the U.S. Environ-
mental Protection Agency (EPA) collected data for the Office of Solid Waste
(OSW) in support of OSW's development of the land disposal restriction regu-
lations. It is OSW's responsibility to set treatment standards and perform-
ance levels based on best demonstrated available technology (BOAT).
The information collected by RREL was to be used to identify the current
generators of K001, to select generators for obtaining a waste sample of K001
from a wood-preserving process that uses pentachlorophenol (K001-PCP) and one
that uses creosote (KOOl-creosote), to select a treatment technology for
evaluation, and to develop Quality Assurance Project Plans (QAPP's).1'2 The
selected treatment technology, incineration, was then tested for each K001-
PCP and KOOl-creosote, and facility- and waste-specific onsite engineering
reports were prepared.3'4
In addition to the OSW-required documentation of waste- and •Facility-
specific treatment technology performance and operation, RREL was responsible
for supplemental evaluations and sampling and analysis activities. These
supplemental evaluations and activities, which are covered in this report,
were not addressed in either the K001-PCP or KOOl-creosote Onsite Engineering
Reports (OER's).3'1* They were conducted as part of RREL's ongoing evaluation
of the treatment of hazardous wastes.
Additional information pertaining to this study is available in the
previously mentioned K001 OER's and in the "Site Test Plan/Quality Assurance
Project Plan (Parts A and B): Incineration Tests of K001 and K015 at the
John Zink Co. Test Facility" (revised July 10, 1987) and the "Site Test
Plan/Quality Assurance Project Plan for the Combustion Research Facility Test
Burn of K001."
PURPOSE
The purpose of this document is to present the data gathered on the
generation and treatment of K001 (bottom sediment sludge from the treatment
of wastewaters from wood-preserving processes that use pentachlorophenol or
creosote) and on the incineration tests that were conducted. The combination
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of this report and the OER's and QAPP's for the test burns provide all the
data that were collected by PEI Associates, Inc., and U.S. EPA RREL on
K001-PCP and KOOl-creosote during the course of producing the OER's for OSW.
SCOPE AND OBJECTIVES
The scope of this report covers a discussion of the process that gener-
ates K001, estimates of the quantities generated and their current disposi-
tion, a review of available waste characterization data, and test burns of
K001. It also includes an assessment of the applicability and effectiveness
of incineration as a treatment option.
Some analytical data collected during the test burn, but not presented
in the K001 OER's, are also included in this report—specifically, the re-
sults of emission testing. Supplemental analytical data on the characteris-
tics of untreated waste and the residues of incineration (i.e., scrubber
water) are also presented. The K001 OER presented analytical data in terms
of Practical Quantitation Limits (PQL's), which were defined as being the
lowest level that can be reliably achieved within specified limits of
precision and accuracy during routine laboratory operating conditions (i.e.,
five times the detection limit). This report includes all analytical results
that were above the detection limits. Analytical results that were above the
detection limit, but were less than the PQL, were not reported in the K001
OER's.
REPORT ORGANIZATION
Section 2 summarizes the findings and conclusions. Section 3 presents
waste characteristics. Section 4 contains an evaluation of incineration as a
treatment technology. Section 5 discusses sampling problems and corrective
actions, and Section 6 presents and discusses the results of the emission
tests and the analysis of wastewater discharges.
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SECTION 2
SUMMARY OF FINDINGS
GENERATION OF K001
The bottom sediment sludge from the treatment of wastewaters from wood-
preserving processes that use pentachlorophenol (PCP) or creosote is called
K001 waste. The four-digit Standard Industrial Classification (SIC) code
most often reported for the wood-preserving industry is 2491. The EPA esti-
mates that at least 400 facilities have wood-preserving processes that could
generate K001 waste.5 Figure 1 shows, by State EPA Region, the number of
wood-preserving processes tjjat could generate K001.
WASTE CHARACTERISTICS
Table 1 presents an estimate of the major constituents in the waste and
their approximate concentrations. Engineering judgment was used to determine
the concentration percentage of each major constituent in the waste, based on
chemical analyses of K001 wastes from wood-preserving processes using creo-
sote and from pentachlorophenol-based, treatment chemicals. Samples of K001
from two generators (one K001-PCP and one KOOl-creosote) were characterized
during this project; results of these characterizations are described later
under Waste Feed Characteristics.
CURRENT TREATMENT
Applicable treatment technologies were identified based on available
waste composition data, contacts with industry, and technical publications.
The technologies considered to be applicable to the untreated waste are those
that treat hazardous organic compounds by reducing their concentrations.
The chemical composition of K001 waste has the greatest direct effect on
the applicability of the technologies to the waste. The waste primarily con-
sists of high concentrations of BDAT-list organic constituents, high concen-
trations of filterable solids, a moderate amount of water, and less than
1 percent concentrations of BDAT-list metals. Treatment technologies are
needed for both BDAT-list organics and BDAT-list metals.
Incineration and fuel substitution were the treatment technologies
identified as being applicable to BDAT-list organic constituents in K001.
Incineration destroys the organic constituents in wastes. Like incineration,
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MA
Figure 1. Number of U.S. wood-preserving facilities by State and EPA Region.
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TABLE 1. MAJOR CONSTITUENTS OF UNTREATED K001 WASTE15
Major constituents Concentration, %a
Soil 35
BDAT-list organic constituents
Naphthalene 4.0
Phenanthrene 3.5
Fluoranthene 2.0
Acenaphthene 2.0
Pyrene 1.5
Fluorene 1.5
Anthracene 1.0
Pentachlorophenol <1.0
Others 8.5
Water 20
Other organic compounds 14
Wood chips 5
BDAT-list metals <1
100
a Percent concentrations presented here were determined
from engineering judgment based on chemical analyses.
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fuel substitution destroys the organic constituents of a waste while deriving
a fuel value from the waste.
The goal of incineration is the thermal destruction (oxidation) of the
organic constituents of a waste. The types of incineration systems normally
demonstrated on wastes are fluidized-bed, rotary-kiln, fixed-hearth, and
liquid-injection systems. The EPA selected the performance of rotary-kiln
incineration as adequately representing the performance achievable by other
well-designed, well-operated thermal destruction technologies (including fuel
substitution) capable of handling sludges of this type.5
Incineration technologies generally result in the formation of two
treatment residuals: ash and scrubber water. For the BDAT-list metals pres-
ent in the wastewater residual (i.e., scrubber water), chemical precipitation
and filtration were identified as applicable treatment technologies. Chemi-
cal precipitation removes dissolved metals from solution, and filtration
removes suspended solids that result from the use of an underdesigned clari-
fier or from the generation of precipitates that do not settle easily. The
filter cake generated from filtration contains BDAT-list metals and requires
stabilization before land disposal.
For the BDAT-list metals present in the nonwastewater residuals (waste-
water treatment filter cake and ash), high-temperature metals recovery and
stabilization were identified as applicable treatment technologies. The
high-temperature metals recovery process recovers metals from wastes primari-
ly through volatilization and subsequent condensation and collection steps.
The process yields a metal product for reuse and reduces the amount of waste
requiring land disposal. Stabilization chemically and physically binds metal
constituents of the waste into the microstructure of a cementitious matrix,
which reduces their leaching potential. Various reagents (including portland
cement, cement kiln dust, hydrated limes, quick lime, fly ash, and other
pozzalanic materials) have been demonstrated to act as binding reagents for
various types of wastes containing metals.
RESULTS OF TEST BURNS
Nine data sets (untreated and treated waste) were collected during the
test burns to characterize the treatment performance of rotary kiln incinera-
tion on K001. Three of these data sets represent K001 wastes from wood-
preserving processes using PCP-based preservative chemicals, and six are from
K001 wastes containing creosote. The K001-PCP used for the test burn at the
U.S. EPA Combustion Research Facility (CRF) in Jefferson, Arkansas, came from
Allied Chemicals in Fairfield, Alabama. Allied obtained the K001-PCP from
the American Wood Division of Power Timber Company, Richton, Mississippi.
The KOOl-creosote data sets were collected during test burns at the John link
Co. Incineration Test Facility in Tulsa, Oklahoma. Both John Zink and the
CRF used a rotary-kiln incineration system to treat the K001. The KOOl-
creosote used for the burns at John Zink also came from Allied Chemicals.
Allied obtained this particular KOOl-creosote from Pearl River Wood Preserv-
ing Corporation, Picayune, Mississippi. Each of the sources of K001 periodi-
cally removes the K001 from their water-treatment ponds and sends it to
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Allied Chemicals for treatment in Allied's pyrolytic incinerator. Corre-
spondence with Allied Chemicals and the trip report for the initial Allied
site visit are presented in Appendix A.
Both K001 wastes proved to be incinerable; the waste streams generated
by both were ash and scrubber water effluent. Four samples of K001-PCP feed
taken from the CRF K001-PCP test burn were analyzed, but only three of them
were representative of the incinerator feed. Because all of the waste was
not incinerated, three samples each of scrubber effluent and incinerator ash
were also taken from the CRF test burn and analyzed. Six samples of K001-
creosote feed and six samples each of scrubber water and ash were taken from
the John Zink KOOl-creosote test burn and analyzed. The original analytical
data tables, as received from the laboratory, are included in Appendix B.
Waste Feed Characteristics
The K001-PCP waste used for the CRF test burn contained the expected
levels of various analytes typically found in bottom sediment sludges of
wastewaters from wood-preserving processes that use PCP. The PCP concentra-
tions in the feed samples ranged from 920 to 3000 yg/g. The feed samples
also contained fairly high levels of polynuclear aromatic hydrocarbons
(PNA's) ranging up to 50,000 yg/g.
The KOOl-creosote (K001-C) waste used for the John Zink test burn con-
tained the expected levels of various analytes typically found in bottom
sediment sludges of wastewaters from wood-preserving processes that use creo-
sote. The BDAT-list volatiles detected in the K001-C feed above the PQL's
were benzene (up to 83 yg/g) and toluene (up to 170 yg/g). Analyses for the
BDAT-list semivolatiles in the feed samples showed several polynuclear aro-
matic hydrocarbons and phenols that are typical of creosote waste. Naphtha-
lene, for example, was present in concentrations up to 43,000 yg/g, and
anthracene, fluoranthene, fluorene, phenanthrene, and pyrene were all present
in concentrations exceeding 10,000 yg/g.
Characteristics of Incinerator Residuals
K001-PCP--
No BOAT volatiles or semivolatiles were detected above the PQL in the
K001-PCP ash, ash TCLP, and scrubber water samples. The BDAT-list metals
found in the ash that were above the PQL were arsenic (up to 0.8 ppm), barium
(up to 74 ppm), chromium (up to 8.2 ppm), copper (up to 6.8 ppm), lead (up to
5.2 ppm), and zinc (up to 11 ppm). Only lead (0.021 yg/ml in one sample) and
zinc (0.03 yg/ml in one sample) were detected above the PQL in the TCLP
extracts of the ash. Arsenic, barium, copper, lead, and zinc were detected
above the PQL in the scrubber water samples.
No BDAT-list dioxins or furans were detected above the method detection
limit in any of the K001-PCP samples.
KOOl-Creosote—
With one exception, no BDAT-list volatiles or semivolatiles were de-
tected in the K001-C ash, ash TCLP, or scrubber water samples above the
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PQL. One ash sample contained 0.93 yg/g of di-n-butylphthalate.
Barium (up to 150 ppm), copper (up to 39 ppm), lead (up to 190 ppm), and
zinc (up to 200 ppm) were the major BDAT-list metals found in the feed sam-
ples. The ash contained arsenic, barium, chromium, copper, selenium, vanadi-
um, and zinc above the PQL, but the TCLP extracts contained only barium and
zinc above the PQL (both were less than 1 mg/liter). Lead (up to 5.4 mg/li-
ter), thallium (up to 4.0 mg/liter), and zinc (up to 11 mg/liter) were the
major metals present in the scrubber water samples.
No BDAT-list organophosphorous pesticides, organochlorine pesticides,
polychlorinated biphenyls (PCB's), organochlorine herbicides, dioxins, or
furans were detected above the PQL in any of the K001-C samples.
Atmospheric Emissions
K001-PCP--
Atmospheric emission test results during the K001-PCP test burn suggest
that this waste can be incinerated in compliance with the incinerator regula-
tions governing principal organic hazardous constituent (POHC) destruction
and removal efficiency (ORE).6 Eleven POHC's were designated for the waste:
pentachlorophenol and 10 polynuclear aromatic hydrocarbon (PNA) compounds.
For both tests, DRE's were greater than 99.99 percent for 10 of the 11
POHC's. The DRE's for the eleventh POHC (naphthalene for one test and
acenaphthylene for the other) were 99.984 percent.6
KOOl-Creosote—
Atmospheric emission test results during the K001-C test burn suggest
that this waste can be incinerated in compliance with the incinerator regula-
tions governing POHC ORE. Anthracene, acenaphthene, naphthalene, phenan-
threne, and fluroanthene were designated as POHCs during the test. For all
three emission tests, DRE's were greater than 99.99 percent for the five
POHC's.
EFFECTIVENESS OF TREATMENT
As demonstrated by these tests, incineration appears to be an effective
method for treating K001-PCP and K001-C. The CRF rotary-kiln incineration
system appeared to operate normally during the K001-PCP test and the John
Zink rotary kiln incineration system appeared to operate normally during the
K001-C test.
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SECTION 3
WASTE CHARACTERIZATION
By definition, K001 is the bottom sediment sludge from the treatment of
wastewaters from wood-preserving processes that use creosote or pentachloro-
phenol. This waste contains toxic organic substances, carcinogens, and
suspected carcinogens (including PCP, toluene, phenanthrene, fluoranthene,
and naphthalene). An estimated 400 facilities in the United States have
wood-preserving processes that could generate K001 waste.5 This waste is
currently landfilled or incinerated.
This waste characterization includes 1) a description of how the waste
is generated, 2) results of laboratory analyses to determine the major con-
stituents present in the waste, and 3) the significant parameters of the
waste. [Analytical data on constituents detected in the waste samples taken
during the test burns EPA conducted at the CRF (K001-PCP) and the John Zink
Test Facility (K001-C) are reported in Section 4.]
WASTE GENERATION
As shown in Figure 2, wood preservation in which pentachlorophenol or
creosote is used generates wastewaters containing the hazardous constituents
present in the preservatives. Creosote is a derivative of coal containing a
wide range of constituents, including creosols, phenol, 2,4-dimethylphenol,
naphthalene, benz(a)anthracene, benzo(a)pyrene, fluoranthene, benzo(b)fluor-
anthene, chrysene, benzo(a,h)anthracene, indeno(l,2,3-cd)pyrene, and ace-
naphthalene. Treatment of these wastewaters by any means (including simple
settling) generates the listed waste K001.
The wood-preserving process consists of two steps: 1) pretreatment of
the wood to reduce its natural moisture content, and 2) impregnation of the
wood with preservatives, including pentachlorophenol and/or creosote. These
agents are added to the wood to increase its resistance to natural decay,
attack by insects, and microorganisms. Drippings and condensed vapors gen-
erated during the preservation treatment are sent to an oil-water separator.
In the oil-water separator, wood treatment chemicals are recovered and recy-
cled back to the preserving process. The wastewater, which is contaminated
with components of pentachlorophenol, creosote, and/or other related com-
pounds, is pumped to a wastewater treatment plant. The treatment residual
generated is the listed waste K001.5
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o
WOOD
TREATMENT CHEMICALS
(CREOSOTE AND/OR
PENTACHLOROPHENOL)
I
TREATMENT
VESSEL
VAPOR
DRIPPINGS AND
CONDENSATE
RECYCLE
PRESERVATIVES
PRESERVATIVE
WORK TANK
WASTEWATER
TREATMENT
WATER
TREATMENT
SLUDGES
->• K001
Figure 2. Schematic of wood-preserving process.
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ANALYSIS FOR MAJOR CONSTITUENT
Both the K001-PCP burned at the CRF and the K001-C burned at John Zink
were black "sloshy sludges." Laboratory analyses were used to determine the
concentrations of the major constituents of the untreated K001 waste samples
obtained for the test burns. These concentrations, which are documented in
Section 4, are summarized as follows:
K001-PCP
Constituent
Soil
Water
Wood chips
BOAT constituents
Other organic compounds
KOOl-Creosote
Constituent
Soil
Water
Wood chips
Naphthalene
Phenanthrene
Fluoranthene
Other BDAT-list constituents
Other organic compounds
Concentration,
percent
40
30
10
15
5
100
Concentration,
percent
30
20
10
4.0
3.5
2.5
14
20
100
The preceding compositions were determined by engineering judgment based on
chemical analyses.
The EPA has obtained compositional data from this testing program and
from numerous literature sources.5 Table 2 summarizes the ranges of BDAT-
list constituents present in the K001 wastes, including the data collected
from the CRF and John Zink burns.
The data in Table 2 show the wide ranges of concentrations of hazardous
organics that may be present in the wastes. Such variations may be
attributed to the type of preservative chemicals used and the type of waste-
water treatment systems used. Generally, these K001 wastes contain numerous
polynuclear aromatic compounds and chlorinated phenolics present in the wood
preservatives. No characterization data identified in the literature for
K001 had values for BDAT-list metals. The K001 wastes from two generators
(one K001-PCP and one KOOl-creosote) were characterized during this project.
11
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TABLE 2. UNTREATED K001 WASTE TOTAL COMPOSITION
(ppm)
BOAT- list constituent
Acenaphthene
Anthracene
Chrysene
Fluoranthene
Naphthalene
Pyrene
Phenanthrene
Pentachl orophenol
2,4-Dlchlorophenol
p-Chloro-m-cresol
2,4-D1methyl phenol
Benzo(g,h,1)perylene
Fluorene
01bez(a,h)anthracene
Benz(a)anthracene
Benzo(a)pyrene
Phenol
2-Chlorophenol
2, 4 ,6-trichl orophenol
Benzo(b and/or k) fluoranthrene
Source of data*
(a) (b) (c) (d) (e) (f)
-+ 3,000 - 15,000-21,000
8,410 .... 7,300-15,000
45 9.29 4.5 2.1 4,100-4,800
5,090 1,400 ... BQL**
43,640 1,200 ... 29,000-43,000
604 52 - - 12,000-17,000
8,410 3,200 - - ' - 28,000-42,000
1.84 - 4.8 302 58 BQL
1,650 - BQL
1,690 . ... BQL
8.2 - 4.4 3.4 BQL
84 - - - BQL
1,400 ... 12,000-18,000
0.052 - - BQL
1.25 3.7 0.149 BQL
5.98 - - BQL
4.5 9.0 16 2,400-3,900
0.30 39 1.2 BQL
25 BQL
BQL
(9)
13,000-18.000
8,500-13,000
<2, 500-3, 400
13,000-21,000
26,000-43,000
9,200-15,000
28,000-43,000
920-3,000
BQL
BQL
BQL
BQL
8,200-12,000
BQL
<2, 500-3, 400
<250-340
BQL
BQL
BQL
940-2,300
- = No data.
(a) Reference 7.
(b) Reference 7.
(c) Reference 8.
d) Reference 8.
e) Reference 8.
f) Reference 9.
(g) Reference 10.
BQL = Below quantitation limit.
-------
TABLE 2 (continued)
Source of data*
BDAT-list constituent (h) (i) (j) (k) (1) (m) (n) (o)
Acenaphthene _ _ _ _ . ._.
Anthracene _ _ _ _ . _ _ .
Chrysene ... 1-170 -
^luoranthene ___- .. _ _ _
Naphthalene 20,000 - 1.7-150 -
Pyrene - 0.17-440 -
Phenanthrene - 3.5-900 t
Pentachlorophenol 50,000-200,000 10,000 0.034 - - 55-1,500 0.18-30 20,000-50,000
2,4-Dlchlorophenol - - 165 - -
p-Chloro-m-cresol - - - - - 0.17 -
2,4-D1methyl phenol ..._ . ...
Benzo(g,h,1)perylene __._ . ...
Fluorene - 0.93-560 -
D1bez(a,h)anthracene .__. . ...
Benz(a)anthracene - 0.014-0.37 1-260 ...
Benzo(a)pyrene _ _ _ _ . ...
Phenol - 10,000 5.043 - - <5.0 0.45-1.6
2-Chlorophenol .... . . 0.12-39.6
2,4,6-trichlorophenol - - 2.5
2,4-Dinitrophenol - - 0.024 - - - 0.3-0.8
"Creosote" --10 - - ...
+ - = No data.
(h) Reference 7.
(i) Reference 11.
(j) Reference 8.
(k) Reference 12.
(1) Reference 13.
(m) Reference 13.
(n) Reference 14.
(o) Reference 15.
-------
The results of these characterizations were presented earlier under Waste
Characteristics in Section 2.
SIGNIFICANT PARAMETERS
Selected parameters of the waste sampled that would affect treatment
performance were characterized. These selected parameters of the sampled
K001 waste from Allied were as follows:
K001-PCPS
Parameter
Ash content
Heating value
Water
PCP
KOOl-Creosote
Parameter
Ash content
Heating value
Water
Volatile matter
Range of determined values
12 to 51%
3800 to 8300 Btu/lb
8 to 41%
970 to 3000 ppm
Range of determined values
10 to 35%
10,000 to 11,000 Btu/lb
5 to 20%
45 to 85%
14
-------
SECTION 4
TREATMENT TECHNOLOGY EVALUATED
Currently, K001 generators dispose of the waste in one of two ways:
1) by incineration at permitted incinerators (several generators send their
waste to Allied Chemicals), or 2) by landfilling.
Because of the high organic content of K001 waste and the current use of
incineration as a treatment technique, rotary kiln incineration was evaluated
for possible treatment of this waste. Two rotary kiln incineration systems
were tested: 1) one at the U.S. EPA Combustion Research Facility (CRF) near
Jefferson, Arkansas (for KOOj-PCP), and 2) the other at the John Zink Company
in Tulsa, Oklahoma (KOOl-creosote). The tests are described in detail in the
QAPP and OER.1'1*
DESCRIPTION OF INCINERATION SYSTEMS
U.S. EPA Combustion Research Facility
The unit selected for the incineration of the K001-PCP samples was a
pilot-scale rotary kiln incinerator managed by the U.S. EPA at its Combustion
Research Facility in Jefferson, Arkansas. Table 3 presents the design charac-
teristics of this system. Although the kiln is designed to operate at tempera-
tures up to 1000°C (1832°F), it has reached temperatures of 1150°C (2100°F)
when incinerating feed material with a high heating value. Figure 3 presents
a schematic diagram of the overall system.
The combustion gases from the kiln pass through an afterburner for
further incineration. The design temperature of the afterburner is 1200°C
(2200°F). Both the kiln and the afterburner use propane as startup fuel and
as supplementary fuel during a waste burn.
During the test burn of K001-PCP, a ram feeder was used to inject 1.5-
gallon, cylindrical, fiber packs containing the feed material. One or two
fiber packs were manually placed in the ram feeder, the access door was
closed, and the ram was activated to inject the fiber packs directly into the
rotary kiln. The ram feeder operator (stationed at the equipment) controlled
the feed rate.
The hot combustion gases leaving the afterburner entered a venturi
scrubber and then a packed tower, a carbon bed, and a high efficiency partic-
ulate air (HEPA) filter in series (Figure 3). An induced-draft (I.D.) fan
followed the HEPA filter in line. Typical rotary kiln gas-handling systems
15
-------
TABLE 3. DESIGN CHARACTERISTICS .OF THE CRF ROTARY-KILN SYSTEM
Characteristics of the main chamber
Length (inside)
Diameter (inside)
Chamber volume
Rotation
Construction
Refractory
Solids retention
time
Burner
Primary fuel
Feed system
Temperature
2.13 m (7 ft)
0.95 m (3.12 ft)
1.74 m3 (61.4 ft3)
Clockwise or counterclockwise 0.1 to 1.5 ppm
0.63-cm (0.25-in.) thick cold rolled steel
12.7-cm (5-in.) thick high-alumina castable refractory
with variable depth to produce a frustroconical effect
for moving inerts
1 h (at 0.2 rpm)
American Combustion
Propane
Liquids:
Semi liquids:
Solids:
1000°C (1832°F)
Front-face, water-cooled lance with
positive-displacement pump
Front-face, water-cooled lance with
double-diaphragm pump
Ram feeder or metered twin-auger screw
feeder
Characteristics of the afterburner chamber
Length (inside)
Diameter (inside)
Chamber volume
(continued)
2.74 m (9 ft)
0.91 m (3 ft)
1.80 m3 (63.6 ft3)
16
-------
TABLE 3 (continued)
Construction 0.63-cm (0.25-in.) thick cold rolled steel
Refractory 15.24-cm (6-in.) thick high-alumina castable refractory
Retention time Depends on temperature and excess air (1.2 to 2.5
seconds)
Burner Iron Fireman, Model C-120-G-SMG, rated at 530 kW
(1.8 x 106 Btu/h or 31.6 MJ/s)
Primary fuel Propane
Temperature 1200°C (2200°F)
Characteristics of the air pollution control system
System capacity Inlet gas flow of 106.8 m3/min (3773 acfm) at 1200°C
(2200°F) and 101 kPa (14.7 psia)
Pressure drop Venturi, 7.5 kPa (30 in. WC)
Packed tower, 1.0 kPa (4 in. WC)
Liquid flow Venturi, 77.2 liters/min (20.4 gal/min) at 69 kPa
(10 psig)
Tower, 115 liters/min (30 gal/min) at 69 kPa
(10 psig)
Slowdown, 7.6 to 9.5 liters/min (2 to 2.5 gpm)
pH control Feedback control by NaOH solution addition
Packing Saddles
a Operating temperatures in excess of 1000°C-(1837°F) have been generated.
Waste treatment effectiveness under these conditions should not be
affected.
17
-------
SAMPLE
D
A
B
C
D
SITE
DESCRPTON
Dnm
AthBh
Vmtufl Sautter
RfdrcuMonT**
SAMPLE
DESCRIPTION
Wvto Feed Before Packing
KDOI-PCPAsh
Scrubber IWieup
Scfubbor Btowdown
SCRUBBER
MAKEUP
FROM
RECIRCULATON
TANK
BLOWDOWN
^ TO
STORAGE
TANKS
Figure 3. CRF rotary-kiln incineration system and sampling points,
-------
consist of a venturi scrubber for participate control and a packed column
for gaseous pollutant control (i.e., hydrogen chloride). The carbon bed and
HEPA filter were added to the CRF system because of operating permit require-
ments.
Sodium hydroxide was added to the scrubbing system (venturi and packed
tower) to maintain a pH greater than 7. Makeup water was added at a rate of
5 to 10 gallons per minute, and the water system was blown down continuously
at a rate of 2.0 to 2.5 gallons per minute.
The exits of the afterburner and the packed-bed scrubber were equipped
with continuous monitoring and recording equipment for oxygen (0?), carbon
monoxide (CO), and carbon dioxide (C02). A computer recorded otner operating
parameters every 20 seconds (e.g., propane flows, combustion air, tempera-
ture). Every 15 minutes, an operator manually recorded critical parameters,
which included 02, CO, CO^t temperature, scrubber pressure drop, feed rate,
and makeup and bfowdown water flows.
The temperature in the kiln was controlled by adjusting the waste feed
rate, combustion air, and/or supplementary fuel. Waste feed rate was manual-
ly controlled by changing the rate of waste-filled fiber packs fed to the
incinerator. Combustion air and supplementary fuel were also manually con-
trolled by valve adjustments.
Detailed data collected during the test (manually by operators and on
computer printouts) are presented in the K001-PCP OER3 and in the Acurex
report of the K001-PCP CRF Test.6 The Acurex test report is presented as
Appendix B.
John Zink Co. Incineration Test Facility
The John Zink incineration test facility was selected for the incinera-
tion of the KOOl-creosote samples. Figure 4 presents a schematic of the test
facility used. The test system consisted of a rotary kiln and afterburner
for combustion, a ram feeder for feeding waste-filled fiber packs into the
kiln, a water quench for kiln ash, and a venturi scrubbing system for flue
gas treatment. In addition to this equipment, the Oklahoma State Department
of Health (OSDH) requires that an additional afterburner (a fume incinerator)
be used during all tests involving hazardous waste. This unit provides
further thermal treatment of the flue gas from the primary combustion system.
All process monitoring and sampling for the BOAT program were conducted
upstream of this unit.
The minimum input to rotary kiln incineration systems (including waste
and natural gas supplementary fuel) is 2 million Btu/h; the maximum is 3
million Btu/h. The waste feed rate was controlled by ramming the fiber packs
containing KOOl-creosote into the kiln at specified time intervals. Supple-
mentary fuel input was manually controlled through a valve. The kiln pro-
vided a 1-hour solids residence time at 0.25 rpm (adjustable, 0.25 to 2 rpm).
The kiln afterburner provided a flue gas residence time of 2.2 seconds at
2000°F (design residence time is 2.4 seconds at 22008F).
19
-------
SAMPLE
10
A
B
C
D
E
SITE
DESCRIPTION
Drums
Ash Bin
Solids Separator
Water Separator
Water Separator
SAMPLE
DESCRIPTION
Waste Feed During Packing
Bottom Ash
Cly Ach
1 Ij rWI
Scrubber Water Before Waste Feed
Scrubber Water During Waste Feed
NATURAL
GAS AND
COMBUSTION
AIR
TO
ATMOSPHERE
SCRUBBER
MAKEUP
SOLIDS
SEPARATOR
EFFLUENT
RECYCLED
TO SCRUBBER
SLOWDOWN
BOTTOM
ASH
Figure 4. John Zink rotary-kiln incineration system and sampling points.
-------
The hot combustion gases leaving the kiln afterburner entered a solids
separator (cyclonic), which elevated the flue gas (i.e., the duct exiting the
separator is higher than the duct entering the separator) and removed any
large pieces of fly ash that might damage downstream equipment. The gases
then entered an adjustable-throat venturi scrubber, which was followed by a
droplet separator consisting of a cyclonic-flow knockout chamber and a vent
stack.
No chemicals were added to the scrubber water during the K001-C tests,
and the scrubber did not require blowdown because the waste contained no
halogens, sulfur, or other compounds that would significantly affect the
recycled scrubber water. Makeup water, however, was continuously added to
the scrubbing system because of evaporation losses.
The rotary kiln incineration system was equipped with multiple tempera-
ture- and pressure-measuring devices that were monitored by plant operators
and engineers. At 30-minute intervals, the operator recorded temperatures in
the incinerator (kiln and afterburner). PEI monitored these parameters at
15-minute intervals during the KOOl-creosote tests. The following data also
were recorded manually from^ pressure gauges, rotometers, manometers, and
other instruments located on the incinerator and associated equipment:
% 02 in stack gas
Fiber pack feed rate
Natural gas rotometer (%/psi)
Venturi rotometer (% of full scale)
Combustion air (AP)
pH of scrubber and quench water (litmus)
Scrubber recycle tank water level (inches)
Makeup water rotometer (% of full scale)
Effluent rotometer (% of full scale)
Venturi AP (in. H20)
Temperatures were controlled by manually changing the supplementary fuel
feed rate, the waste feed rate, and/or the combustion air flow rate. Supple-
mentary fuel and combustion air are controlled by manually operated valves.
Continuous monitoring and recording of C02, CO, 02, and temperature took
place at the exit of the kiln afterburner, at a point prior to the solids
separator. Other system performance monitoring conducted by John Zink Co.
consisted of continuous monitoring of temperature, CO, 02, and NO in stack
gases exiting the OSDH-required afterburner on the test system.
Detailed data collected during the KOOl-creosote test are presented in
the KOOl-creosote OER1* and the John Zink test report. The John Zink test
report is included as Appendix C.
TEST DATA
Detailed analyses of the K001 incinerator feed and of the residues of
incineration (ash and scrubber water) were made to determine the presence of
21
-------
BDAT-list compounds and selected non-BDAT compounds. The types of compounds
analyzed in each sample are listed in Table 4 (K001-PCP) and Table 5 (K001-
creosote). One sample each of the untreated KOOl-creosote and the resulting
bottom ash and scrubber water was analyzed for all BDAT-list compounds.
Separate tables giving results for each parameter class (e.g., volatile
organics, semivolatile organics) are presented for each sample type. These
tables also present the quantitation limits for each analyzed constituent,
which is five times the detection limit achieved on a given analysis. The
multiple used to derive a quantitation limit from the detection limit is
laboratory-specific. As the concentration of an analyte approaches the
detection limit, the accuracy and precision of the determination diminish.
The quantitation limit is used to flag results where greater variation is
expected. Compounds that were detected, but are below the quantitation
limit, are noted in the tabulations.
K001-PCP
The time and dates of samples collected for the K001-PCP test burns at
the CRF are presented in Ta^ble 6. The following is a listing of the tables
that show the samples types*and the results for each parameter class:
Sample type Analytical results table
K001-PCP composition
Volatile organics (tetraglyme extract) 7
Volatile organics (methanol extract) 8
Semivolatile organics 9
Metals 10
Total organic carbon 11
Dioxins/furans 12
Ash composition
Volatile organics (tetraglyme extract) 7
Volatile organics (methanol extract) 8
Semivolatile organics 13
Metals 14
Total organic carbon 15
Dioxins/furans 16
TCLP volatile 17
TCLP semivolatiles 18
TCLP metals 19
Scrubber water composition (makeup and
effluent)
Volatile organics 20
Semivolatile organics 21
Metals 22
Purgeable/nonpurgeable organic carbon 23
Dioxins/furans 24
22
-------
TABLE 4. ANALYTE DECISION MATRIX FOR WASTE CODE K001-PCP
Parameter class
BOAT list3
Volatiles
Semivolatiles
Metals
Inorganics
Organochlorine pesticides
Phenoxyacetic acid herbicides
Organophosphorous insecti-^
cides
PCB's
Dioxins and furans
OAQPS
Inorganics
Volatiles
Semivolatiles
Alcohols
POC
NPOC
TCLP
Metals
Volatiles
Semivolatiles
Proximate and ultimate
analyses
pH, dissolved solids, dissolved
metals, COD, TOX, and chloride
Scrubbing liquid
K001-PCP Makeup Effluent
X X X
X XX
X XX
X X
X
X
X XX
X XX
X
X X
Ash
X
X
X
X
X
X
X
X
X
Represent major peaks beyond BOAT.
23
-------
TABLE 5. ANALYTE DECISION MATRIX FOR WASTE CODE K001-CREOSOTE
Parameter class
BDAT listb
Volatiles
Semivolatiles
Metals
Inorganics
Organochlorine pesti-
cides
Phenoxyacetic acid
herbicides
Organophosphorous
insecticides
PCB's
Dioxins and furans
OAQPS
Inorganics
Volatiles
Semivolatiles
Alcohols
POC
NPOC
TCLP
Metals
Volatiles
Semi volatiles
Proximate and ultimate
analyses
pH, dissolved solids,
COD, TOX, and chloride
Scrubbing liquid
Untreated
KOOl-creosote Makeup Effluent
XXX
XXX
XXX
X
X
X
XXX
XXX
X
X X
Flya
X
X
X
X
X
X
X
X
Ash
Bottom
X
X
X
X
X
X
X
X
Sufficient fly ash was collected for only one sample.
Represent major peaks beyond BDAT.
24
-------
TABLE 6. K001-PCP SAMPLE INFORMATION
Test
No.
Sample No.
Date
collected
Time (24-h)
collected
1
2
3
b
K001-PCP feed samples
CK01P-1-AX
CK01P-2-AX
CK01P-3-AX
CK01P-4-AX
Ash samples
6/25/87
6/25/87
6/26/87
6/26/87
a
a
a
a
1
2
3
1
1
2
3
CK01P-1-B1
CK01P-2-B1
CK01P-3-B1
Makeup water sample
CK01P-1-1C
Scrubber blowdown samples
CK01P-1-D1
CK01P-2-D1
CK01P-3-D1
6/30/87
7/1/87
7/1/87
6/26/87
6/26/87
7/1/87
7/1/87
c
c
c
1530
1915
1230
1745
a The feed samples were collected while the fiber packs were being packed.
b
The drum of K001-PCP from which sample CK01-4-AX was collected was not
used for the test burn.
c The ash samples were collected from the ash bin after the ash had cooled.
25
-------
TABLE 7. K001-PCP FEED AND ASH COMPOSITION—ANALYSIS OF VOLATILE ORGANICS
BY USING TETRAGLYME EXTRACT
(ug/g)
Analyte
Acetonitrile
Acrolein
Acrylonitrlle
Benzene
Bromodichloromethane
Bromomethane
Carbon tetrachlorlde
Carbon disulfide
Chlorobenzene
2-ch1oro-l,3-butad1ene
Chi orodi bromomethane
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
3-Chloropropene
l,2-Dibromo-3-chloropropane
1.2-D1 bromoethane
01 bromomethane
Trans-l,4-d1chloro-2-butene
D1 chl orodlf 1 uoromethane
l,l-D1chloroethane
l,2-D1ch1oroethane
l,l-D1chloroethylene
Trans-1 ,2-d1chloroethene
l,2-D1chloropropane
Trans- 1,3-dl chl oropropene
C1s-l,3-d1chloropropene
l,4-D1oxane
Ethyl cyanide
Ethyl methacrylate
lodomethane
Isobutyl alcohol
Methyl ethyl ketone
Methyl methacrylate
Methyl methane sulfonate
MethylacrylonHrlle
Methylene chloride
Pyridine
1,1,1,2-Tetrachloroethane
1,1,2 ,2-Tetrachl oroethane
Tetrachloroethene
Toluene
Trlbromomethane
1 , 1 , l-Tr1 chl oroethane
1,1.2-Trlchloroethane
Trlchloroethene
Tr1 chl orof 1 uoromethane
1 ,2 ,3-Tr1ch1 oropropane
Vinyl chloride
Quanti-
tatlon
limits
250
250
50
10
10
10
10
10
10
0.25
10
10
1
10
10
10
10
10
10
0.25
10
10
10
10
10
25
25
25
250
0.5
10
10
1
50
10
25
1
50
25
10
10
10
10
10
10
10
10
10
250
10
Feed
CK01P-
1-AX
NDa
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
16
ND
ND
ND
ND
ND
NO
NO
Feed
CK01P-
2-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HO
ND
ND
ND
10
ND
NO
ND
ND
ND
ND
ND
Ash
CK01P-
1-B1
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
NO
NO
Feed
CK01P-
3-AX
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
39
ND
ND
ND
ND
ND
ND
ND
Feed
CK01P-
4-AX
ND
ND
NO
NDK
8.5b
ND
ND,
5.3b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
41
ND
NO
NO
ND
ND
ND
ND
Ash
CK.01P-
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P-
3-B1
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
(continued)
26
-------
TABLE 7 (continued)
Analyte
Quanti-
tatlon
limits
Feed
CK01P-
1-AX
Feed
CK01P-
2-AX
Ash
CK01P-
1-81
Feed
CK01P-
3-AX
Feed
CK01P-
4-AX
Ash
CK01P-
2-B1
Ash
CK01P-
3-B1
Non-BDAT Parameters
2-Chloroethyl vinyl ether
Ethylene oxide
Acetoni trlle
Acrolein
Ethyl benzene
Xylenes
Styrene
Ethyl ether
Ethyl acetate
Eplchlorohydrin
Acetone
Methyl isobutyl ketone
50
250
250
250
10
10
10
250
10
10
250
50
NO
NO
NO
ND
NO
21
31
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
12
18
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
38
110
64
ND
ND
ND
ND
ND
ND
ND
ND
ND
41
130
68
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4 ND « The compound was not detected above the detection limit.
b Less than quantltation limit (5 times the detection limit).
27
-------
TABLE 8. K001-PCP FEED AND ASH COMPOSITION—ANALYSIS OF VOLATILE ORGANICS BY USING METHANOL EXTRACT
(vg/g)
ro
oo
Feed
BOAT No.
1
2
3
4
5
6
7
8
9
10
, 11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
Analyte
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodichlorome thane
Bromomethane
Carbon tetrachloride
Carbon disulfide
Chlorobenzene
2 Chloro-l,3-butadiene
Chlorodibromomethane
Chi oroe thane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
3-Chloropropene
1 , 2-D1 bromo-3-chl oropropane
1,2-Dibromoethane
Dibromome thane
Trans-l,4-dichloro-2-butene
Di chl orodi f 1 uoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
Trans-l,2-dichloroethene
1 ,2-Dichloropropane
Trans-1 ,3-di chl oropropene
Cis-l,3-dichloropropene
Quantita-
tion limit
250
250
50
10
10
10
10
10
10
0.25
10
10
50
10
10
10
10
10
10
0.25
10
10
10
10
10
25
25
25
CK01P
1-AX
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CX01P
2-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P
3 -AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P
4-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P
1-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P
3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 8 (continued)
ro
10
Feed
BOAT No.
29
30
31
32
34
35
36
37
38
39
40
, 41
42
43
44
45
46
47
48
49
50
Analyte
1,4-dioxane
Ethyl cyanide
Ethyl methacrylate
lodomethane
Methyl ethyl ketone
Methyl methacrylate
Methyl methanesulfonate
Methyl acrylonitrile
Methylene chloride
Pyridine
1,1, 1 ,2-Tetrachloroethane
1 , 1 ,2 ,2-Tetrachl oroethane
Tetrachl oroethene
Toluene
Tribromomethane
1,1, 1-Tri chl oroethane
1,1,2-Trichl oroethane
Tri chl oroethene
Trichlorofluoromethane
1 ,2 ,3-Tri chl oropropane
Vinyl chloride
Non-BDAT Parameters
Ethyl ene oxide
Ethyl benzene
Xylene
Styrene
Ethyl ether
Quantita-
tion limit
NAb
0.5
10
10
50
10
25b
NAD
50
25
10
10
10
10
10
10
10
10
10
250
10
250
10
10
10
250
CK01P
1-AX
ND
ND
ND
ND
650
ND
ND
ND
ND
ND
ND
ND
ND
14
ND
ND
ND
ND
ND
ND
ND
ND
20
73
18
ND
CX01P
2-AX
ND
ND
ND
ND
720
ND
ND
ND
ND
ND
ND
ND
ND
23
ND
ND
ND
ND
ND
ND
ND
ND
31
98
29
ND
CK01P
3-AX
ND
ND
ND
ND
720
ND
ND
ND
ND
ND
ND
ND
ND
32
ND
ND
ND
ND
ND
ND
ND
ND
33
110
42
ND
CK01P
4-AX
ND
ND
ND
ND
770
ND
ND
ND
ND
ND
ND
ND
ND
25
ND
ND
ND
ND
ND
ND
ND
ND
26
89
36
ND
CK01P
1-B1
ND
ND
ND
ND
770
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P
2-B1
ND
ND
ND
ND
540
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P
3-B1
ND
ND
ND
ND
590
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 8 (continued)
Feed
BOAT No. Analyte
Non-BDAT Parameters (cont'd)
Ethyl acetate
Epichlorohydrin
Acetone
Methyl isobutyl ketone
Quantita-
tion limit
250
10
10
250
CK01P
1-AX
ND
ND
ND
ND
CX01P
2-AX
ND
ND
ND
ND
CK01P
3-AX
ND
ND
ND
ND
CK01P
4-AX
ND
ND
ND
ND
CK01P
1-B1
ND
ND
ND
ND
Ash
CK01P
2-B1
ND
ND
ND
ND
CK01P
3-B1
ND
ND
ND
ND
a ND = The compound was not detected in concentrations above the detection limit.
NA = The standard 1s not available; the compound was searched by using an NBS data base of 42,000
compounds.
to
o
-------
TABLE 9. SEMIVOLATILE ORGANICS RESULTS FOR K001-PCP FEED SAMPLES
(.yg/g).
Analyte
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetylamincfluorene
4-Am1 nobiphenyl
Aniline
Anthracene
Aramite
Benz(a)anthracene
BenzenetMol
Benzidine
Benzo(a)pyrene
Benzofb &/or kjfluoranthrene
Benzo(g,h.i Jperylene
Benzofkjfluoranthrene
p-Benzoquinone
Bis(2-ch1oroethoxy)methane
Bis(2-chloroethyl )ether
CAS Number
208-96-8
83-32-9
96-86-2
53-96-3
92-67-1
62-53-3
120-12-7
140-57-8
56-55-3
108-98-6
92-87-5
50-32-8
205-99-2
191-24-2
207-08-9
106-51-4
111-91-1
111-44-4
Bis(2-chloroisopropyl )ether 39638-32-9
Bis(2-ethylhexyl )phthalate
4-Bromophenyl phenyl ether
Butylbenzylphthalate
2-sec-Butyl-4,6-dinitrophenol
p-Chloroanil ine
Chlorobenzilate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropioni tri le
Chrysene
Ortho-cresol
Para-cresol
D i benz ( a, h) anthracene
Dibenzo(a,e)Pyrene
D1benzo(a,1)pyrene
m-Dichlorobenzene
o-Dichlorobenzene
p-D1chlorobenzene
3,3'-D1ch1orobenz1dine
2,4-D1chlorophenol
2,6-Olchlorophenol
Diethyl phthalate
3,3'-D1methoxybenzidine
p-Dimetnylaminoazobenzene
3, 3' -Dimethyl benzldlne
2, 4-Oimethyl phenol
Dimethyl phthalate
D1-n-butylphthalate
l,4-D1n1trobenzene
4,6-D1n1tro-o-cresot
2,4-D1n1tropheno1
2,4-D1nitroto1u«n«
2,6-01nitrotoluene
Di-n-octylphthaltte
Di-n-propyln1trosam1ne
Diphenylamine/diphenylnitrosamlne
l,2-D1phenylhydraz1ne
Fluoranthene
Fluorene
117-81-7
101-55-3
85-68-7
88-85-7
106-47-8
510-15-6
59-50-7
91-58-7
95-57-8
54-27-67
218-01-9
95-48-7
106-44-5
53-70-3
192-65-4
189-55-9
541-73-1
95-50-1
106-46-7
91-94-1
120-83-2
87-65-0
84-66-2
119-90-4
60-11-7
119-93-7
105-67-9
131-11-3
84-74-2
100-25-4
534-52-1
51-28-5
121-14-2
606-20-2
117-84-0
122-39-4/
86-30-6
122-66-7
206-44-0
86-73-7
Quanti-
tatlon
limits
2.500
2,500
2,500
5,000
5,000
5,000
2,500
b
2,500
b
5,000
2,500
2,500
2,500
2,500
5,000
2,500
2,500
2,500
2.500
2,500
2,500
b
12,500
b
5,000
2,500
2.500
b
2,500
2.500
2,500
2,500
2,500
2,500
2,500
2,500
2.500
5,000
5.000
5,000
2.500
5,000
5,000
5,000
2.500
2.500
2,500
5,000
5.000
5,000
5,000
5,000
2,500
d
5,000
5,000
2,500
2,500
Reagent
blank
N0a
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
CK01P-1-AX
ND
13,000
ND
ND
ND
NO
9,300
ND
ND
ND
ND
ND
940C
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
1,900C
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
13,000
8,200
CK01P-2-AX
ND
18,000
ND
ND
ND
NO
13,000
ND
3.400
ND
NO
940^
2,300C
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
3,600
ND
ND
NP
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
21,000
12,000
CK01P-3-AX
ND
14,000
ND
NR
ND
ND
8,500
ND
2,500
NO
ND
620^
1,600C
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND C
2,400
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
15,000
9.000
CK01P-4-AX
ND
18,000
ND
ND
NO
ND
11,000
ND
2,900
ND
NO
800C
2,000C
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
NC
3,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
550C
ND
ND
ND
ND
ND
ND
ND
ND
II D
ND
ND
20,000
9,500
(continued)
31
-------
TA3LE 9 (continued)
Analyte
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroe thane
Hexachlorophene
Hexachloropropene 1
Ideno(l,2,3-cd)pyrene
Isosafrole
Malononitrile
Methapyrilene
3-Methylcholanthrene
4,4'-Methylenebis(2-chloro-
aniline)
Naphthalene
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
p-N1troaniline
Nitrobenzene
4-N1trophenol
N-N1trosodi-n-butylamine
N-Ni trosodi ethyl ami ne
N-Nitrosod1methylamine
N-Nitrosomethylethylamine 10
N-N1trosomorphol1ne
N-Nitrosopiperidine
N-Nitrosopyrrol idine
5-Nitro-o-tolu1dine
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
2-Picoline
Pronamide 23
Pyrene
Resorcinol
Safrole
1.2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trlchlorophenol
Tris(2,3-dibromopropyl ) phosphate
CAS Number
118-74-1
87-68-3
77-47-4
67-72-1
70-30-4
.888-71-7
193-39-5
120-58-1
169-77-3
91-80-5
56-49-5
101-14-4
91-20-3
130-15-4
134-32-7
91-59-8
100-01-6
98-95-3
100-02-7
924-16-3
55-18-5
62-75-9
,595-95-6
59-89-2
100-75-4
930-55-2
99-55-8
608-93-5
76-01-7
82-68-8
87-86-5
62-44-2
85-01-8
108-95-2
109-06-8
,950-58-5
129-00-0
108-46-3
94-59-7
95-94-3
58-90-2
120-82-1
95-95-4
88-06-2
126-72-7
Quantl-
tation
limits
5,000
5,000
5,000
5,000
b
5,000
2,500
5,000
12,500
2,500
5,000
2,500
5,000
5,000
5,000
12,500
2,500
5,000
5,000
5,000
5,000
5,000
5,000
5,000
5,000
5,000
5,000
5,000
5.000
25
5.000
2,500
2,500
5,000
5,000
2,500
5,000
5,000
2,500
5,000
2,500
2,500
2,500
b
Reagent
blank
ND
NO
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
CK01P-1-AX
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
26,000
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
970
ND
28,000
ND
ND
ND
9,200
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-2-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
43,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
3,000
ND
42,000
NO
ND
ND
15,000
ND
ND
ND
ND
ND
ND
ND
NO
CK01P-3-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
37,000
ND
ND
ND
ND
ND
NO
Nf>
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
920
ND
32,000
ND
ND
ND
11,000
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-4-AX
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
50,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
1,200
ND
42,000
ND
ND
NO
13,000
ND
ND
ND
ND
ND
ND
ND
NO
3 NO • The compound was not detected above the detection Hm1t.
Detection Hm1t not given, standard unavailable.
c Less than the quantltatlon Hm1t (5 times the detection Unit).
d Not detected by reverse search. PQL not determined.
32
-------
TABLE 10. METALS ANALYSIS FOR K001-PCP FEED SAMPLES
(yg/g)
Analyte
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis
type
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
Quantitation
limit
4.5
0.01
0.045
0.5
0.015
0.045
0.05
0.001
10
0.01
30
2.5
1.5
10
0.03
CK01P-
1-AX
NDa
2.9
30
ND
0.5
1.5
6.7
0.11
4b
7.8
ND
ND
0.4b
ND
64
CK01P-
2-AX
ND
2.3
19
ND
0.6
2.7
11
0.16
3b
11
ND
ND
ND
ND
58
CK01P-
3-AX
ND
1.1
17
ND
0.4
2.1
10
0.064
3b
6.3
ND
ND
ND
ND
30
CK01P-
4-AX
ND
1.3
21
ND
o.e
1.3
10
ND
ND
5.3
ND
ND
ND
ND
40
a ND = Not detected above the detection limit.
b Less than the quantitation limit (5 times the detection limit).
33
-------
TABLE 11. TOTAL ORGANIC CARBON DATA FOR K001-PCP FEED SAMPLES
(percent)
CK01P-1-AX CK01P-2-AX CK01P-3-AX CK01P-4-AX
TOC 30 47 34 47
TABLE 12. K001-PCP FEED DIOXIN/FURAN RESULTS
(ng/g)
Analyte Reagent blank, CK01P-1-AX CK01P-2-AX, CK01P-3-AX, CK01-4-AX,
Total
Total
Total
Total
Total
Total
TCDD <15
TCDF <8.6
PCDD <14
PCDF <12
HxCDD <19
HxCDF <15
NDa
ND
ND
ND
ND
ND
<3
<2
<3
<2
<5
<3
.5
.4
.4
.4
.0
.7
<6
<4
<6
<5
<9
<6
.3
.2
.2
.0
.6
.8
<3
<2
<3
<3
<4
<4
.6
.5
.4
.0
.9
.0
ND = Not detected; surrogates could not be recovered and detection limits
could not be calculated.
34
-------
TABLE 13. SEMIVOLATILE ORGANIC RESULTS FOR K001-PCP ASH EXTRACT
(yg/g)
Aralyte
Acenaphthalene
Acenaphthene
Acetophenone
2-Acety 1 ami nof 1 uorene
4-Aminobi phenyl
Anil ine
Anthracene
Aramite
Benz(a)anthracene
Benzenethiol
Benzidine
Benzo(a)pyrene
Benzo(b)fluoranthrene
Benzo(g,h,i)perylene
Benzojkjfluoranthrene
p-Benzoquinone
8is(2-Chloroethoxy)ethane
Bis(2-Chloroethyl )ether
CAS Number
208-96-8
83-32-9
96-86-2
53-96-3
92-67-1
62-53-3
120-12-7
140-57-8
56-55-3
108-98-6
92-87-5
50-32-8
205-99-2
191-24-2
207-08-9
106-51-4
111-91-1
111-44-4
8is(2-Chloroisopropyl Jether 39638-32-9
8is(2-ethylhexyl )phthalate
4-Bromophenyl phenyl ether
Butyl benzyl ph thai ate
2-sec-Butyl-4,6-
-------
TABLE 13 (continued)
Analyte
Hexachlorobenzene
Hexachlorobutadiene
Hezachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
IdenoU ,2,3-cd)pyrene
Isosafrole
Malononltrile
Methapyri lene
3-Methylcholanthrene
4,4 '-Methyl eneb1s(2-chl oro-
aniline)
Naphthalene
1 ,4-Naphthoquinone
1-Naphthylamfne
2-Naphthylamine
p-Nitroaniline
Nitrobenzene
4-Ni trophenol
N-Nitrosodi-n-butylamine
N-N i t rosodi ethyl ami ne
N-N itrosodi methyl ami ne
N-Ni t rosodi -n-propyl ami ne
N-Ni trosomethy 1 ethyl ami ne
N-Ni trosomorphol i ne
N-Nitrosopiperidine
N-Nitrosopyrrol1dine
5-Nitro-o-toluidine
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenaeetin
Phenanthrene
Phenol
2-Picoline
Pronamide
Pyrene
Resorcinol
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Tris(2 ,3-dibromopropyl Jphosphate
CAS Number
118-74-1
87-68-3
77-47-4
67-72-1
70-30-4
1888-71-7
193-39-5
120-58-1
169-77-3
91-80-5
56-49-5
101-14-4
91-20-3
130-15-4
134-32-7
91-59-8
100-01-6
98-95-3
100-02-7
924-16-3
55-18-5
62-75-9
621-64-7
10595-95-6
59-89-2
100-75-4
930-55-2
99-55-8
608-93-5
76-01-7
82-68-8
87-86-5
62-44-2
85-01-8
108-95-2
109-06-8
23950-58-5
129-00-0
108-46-3
94-59-7
95-94-3
58-90-2
120-82-1
95-95-4
88-06-2
126-72-7
Quanti-
tation
limits
2.5
2.5
2.5
2.5
a
2.5
2.5
25
2500
a
25
50
2.5
2.5
25
25
12.5
2.5
12.5
25
25
25
25
25
50
50
50
50
2.5
2.5
25
12.5
25
2.5
2.5
25
25
2.5
2.5
25
25
25
2.5
12.5
2.5
a
Reagent
blank
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
CK01P-1-B1
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
NO
NO
ND
ND
NO
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
CK01P-2-81
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
ND
ND
ND
NO
ND
ND
NO
NO
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
NO
CKC1P-3-81
NO
ND
fit1
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
NP
MO
NP
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND • The compound was not detected above the detection limit.
Detection limit not given, standard unavailable.
Not detected by reverse search. PQL not determined.
36
-------
TABLE 14. METALS ANALYSIS FOR K001-PCP ASH SAMPLES
(yg/g)
Analyte
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis
type
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
Quantisation
limit
4.5
0.01
0.045
0.5
1.5
0.045
0.05
0.001
10
0.01
30
2.5
1.5
10
0.03
CK01P-
1-B1
1.3a
0.8
74
0.7a
ND
8.2
6.8
ND
7a
5.2
ND
ND
ND
7a
11
CK01P-
2-B1
NDb
0.6
21
ND
ND
1.1
3.0
ND
ND
1.2
ND
ND
ND
ND
2.1
CK01P-
3-B1
ND
0.4
21
ND
ND
1.2
2
ND
ND
0.96
ND
ND
ND
ND
2.1
a Less than quantitation limit (5 times the detection limit).
b ND = Not detected above the detection limit.
37
-------
TABLE 15. TOTAL ORGANIC CARBON DATA FOR K001-PCP ASH SAMPLES
(percent)
CK01P-1-B1
CK01P-2-B1
CK01P-3-B1
TOC
0.2'
0.5
o.;
a Less than the quantitation limit of 0.5 percent (5 times the detection
limit of 0.1 percent)
TABLE 16. K001-PCP ASH DIOXIN/FURAN RESULTS
(ng/g)
Analyte
Reagent blank, CK01P-1-B1, CK01P-2-B1, CK01P-3-B1
Total
Total
Total
Total
Total
Total
TCDD
TCDF
PCDD
PCDF
HxCDD
HxCDF
<0
<0
<0
<0
<0
<1
.089
.075
.25
.20
.60
.2
<0
<0
<0
<0
<0
<0
.093
.057
.097
.085
.19
.34
<0
<0
<0
<0
<0
<0
.073
.050
.090
.075
.21
.27
<0
<0
<0
<0
<0
<0
.077
.051
.086
.072
.18
.21
38
-------
TABLE 17. VOLATILE ORGANIC RESULTS FOR K001-PCP ASH SUBJECTED TO TCLP
(yg/liter)
Analyte
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromomethane
Carbon tetrachloride
Carbon disulfide
Chlorobenzene
2-Chloro-l,3-butadiene
Chlorodibromomethane
Chi oroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
3-Chloropropene
1 ,2-Di bromo-3-chl oropropane
1,2-Dibromoethane
Dibromomethane
Trans-l,4-dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
Trans-l,2-dichloroethene
1,2-Dichloropropane
Trans-l,3-dichloropropene
Ci s-1 ,3-di chl oropropene
1,4 Dioxane
Ethyl cyanide
Ethyl methacrylate
lodomethane
Isobutyl alcohol
Methyl ethyl ketone
Methyl methacrylate
Methyl methane sulfonate
Methylacrylonitrile
Methyl ene chloride
Pyridine
1,1, 1 ,2-Tetrachl oroethane
1 , 1 ,2 ,2-Tetrachl oroethane
Quanti-
tation
limits
250
250
50
10
10
10
10
10
10
0.25
10
10
1
10
10
10
10
10
10
0.25
10
10
10
10
10
25
25
25
250
0.5
10
10
1
50
10
25
1
50
25
10
10
Ash
CK01P-
1-61
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P-
3-D1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P-
3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
39
-------
TABLE 17 (continued)
Analyte
Tetrachloroethene
Toluene
Tribromomethane
1 , 1 , 1-Trichl oroethane
1,1,2-Trichloroethane
Trichloroethene
Tri chl orof 1 uoromethane
1,2,3-Trichloropropane
Vinyl chloride
Quanti-
tation
limits
10
10
10
10
10
10
10
250
10
Ash
CK01P-
1-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ash
CKC1P-
3-D1
ND.
3.0b
ND
ND
ND
ND
ND
ND
ND
Ash
CK01P-
3-61
ND.
2.9b
ND
ND
ND
ND
ND
ND
ND
Non-BDAT Parameters
2-Chloroethyl vinyl ether
Ethylene oxide
Acetonitrile
Acrolein
Ethyl benzene
Xylenes
Styrene
Ethyl ether
Ethyl acetate
Epichlorohydrin
Acetone
Methyl isobutyl ketone
50
250
250
250
10
10
10
250
10
10
250
50
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
a ND = The compound was not detected above the detection limit.
Less than quantitation limit (5 times the detection limit).
40
-------
TABLE 18. TCLP SEMIVOLATILES ORGANIC RESULTS FOR K001-PCP ASH
(ing/liter)
Analyte
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetyl ami nof 1 uorene
4-Aminobiphenyl
Anil ine
Anthracene
Arami te
Ber.z(a)anthracene
Benzenethiol
Benzidine
Benzo(a)pyrene
8enzo(b 4/or k)f luoranthrene
Benzo(b)fluorantnrene
Benzo(g,h,i)perylene
Benzo(k)fluoranthrene
p-Benzoquinone
Bis(2-Chloroethoxy)ethane
Bis(2-Chloroethyl)ether
8is(2-Chloroisopropyl )ether
B1s(2-ethylhexyl Jphthalate
4-Bromophenyl phenyl ether
Butylbenzylph thai ate
2-sec-Butyl-4,6-dinitrophenol
p-Chloroanil ine
Chlorobenzilate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-CMoroprop1on1tme
Chrysene
Ortho-Cresol
Para-Cresol
Dibenz(a , h)anthracene
Dibenzo(a,e)pyrene
Dibenzo(a,i)pyrene
m-Dichlorobenzene
o-Dichlorobenzene
p-D1chlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
2,6-Dichlorophenol
Oiethylphthalate
3,3' -Dimethoxybenzidi ne
p-Dimethylaminoazobenzene
3,3'-Dimethylbenzidine
2, 4-Dimethyl phenol
Dimethylphthalate
Di-n-butylph thai ate
l,4-01nitro benzene
4 ,6-[)1ni tro-o-cresol
2,4-Dinitrophenol
2,4-01n1trotoluene
2,6-Olnitrotoluere
Di-n-octylph thai ate
Di-n-propylnitrosamlne
Di phenyl ami ne/d1 phenyl nltro-
samine
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Practical
quanti-
tation
limits
10
10
10
1,000
200
20
10
b
10
b
1,000
10
10
10
10
10
1,000
10
10
10
10
10
10
b
100
b
10
10
10
b
10
10
10
10
10
10
10
10
10
20
10
10
10
10,000
200
10,000
10
10
10
100
50
50
10
10
10
d
10
10
10
10
Leachate
blank
NDa
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
NO
NP
NO
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
CK01P-
1-B1
ND
ND
ND
ND
NO
ND
MO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
CK01P-
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
4.4C
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
NO
NO
ND
NO
ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
CK01P-
3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
(continued)
41
-------
TABLE 18 (continued)
Analyte
Hexachlorobenzene
Hexachlorobutadiene
Heza chlorocycl open tad iene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Ideno(l,2,3-cd)pyrene
Isosafrole
Kalononitrile
Methapyrilene
3-Methylcholanthrene
4,4'-Methylenebis(2-chloro-
aniline)
Naphthalene
1,4-Naphthoqulnone
1-Naphthylamine
2-Naphthylamine
p-Ni troaril ine
Nitrobenzene
4-Nitrophenol
N-Nitrosodi-n-butylamine
N-N i t rosodi ethyl ami ne
N-N1 trosodimethyl ami ne
N-Nitrosod1-n-propylamine
N-N itrosomethyl ethyl am ine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrol idine
5-Nitro-o-toluidine
Pentachlorobenzene
Pentachloroethane
Pertachloronitrobenzene
Pertachlorophenol
Phenacetin
Phenanthrene
Phenol
2-Picoline
Pronamide
Pyrene
Pyridine
Resorcinol
Safrole
1 ,2 ,4 ,5-Tetrachl orobenzene
2 ,3 ,4 ,6-Tetrachl orophenol
1, 2, 4-Trichl orobenzene
2, 4, 5-Tr1chl orophenol
2, 4, 6-THchl orophenol
Tris(2,3-d1bromopropy1)pnosphate
Practical
quanti-
tation
limits
10
10
10
10
10
10
10
100
10,000
a
100
200
10
100
100
100
50
10
50
100
100
100
100
100
200
200
200
200
10
10
100
50
100
10
10
100
100
10
100
10
100
100
100
10
50
10
a
Leachate
blank
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-
1-81
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
CK01P-
2-81
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
CK01P-
3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND • The compound was not detected above the detection limit.
Detection limit not given, standard unavailable.
c Less thin quantitation limit (5 times the detection limit).
Not detected by reverse search. PQL not determined.
42
-------
TABLE 19. METALS ANALYSIS FOR K001-PCP TCLP EXTRACTS OF ASH SAMPLES
(yg/ml)
Analyte
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis
type
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
Quantita-
tion
limit
0.045
0.015
0.045
0.005
0.015
0.045
0.05
0.001
0.1
0.01
0.3
0.025
0.05
0.1
0.03
Extraction
blank
NDa
0.004b
0.013b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.019b
CK01P-
1-B1
ND
0.007b
0.32
ND
ND
ND
ND
ND
ND
0.021
ND
ND
ND
ND
0.009b
CK01P-
2-B1
ND
0.01b
0.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.019b
CK01P-
3-B1
ND
0.008b
0.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.03
a ND = Not detected above the detection limit.
Less than quantitation limit (5 times the detection limit).
43
-------
TABLE 20. VOLATILE ORGANIC RESULTS FOR K001-PCP SCRUBBER WATER
(yg/liter)
Quanti-
tation
Analyte limits
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodi chl oromethane
Bromomethane
Carbon tetrachloride
Carbon disulfide
Chlorobenzene
2-Chloro-l,3-butadiene
Chl orodi bromomethane
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chl oromethane
3-Chloropropene
1 ,2-Di bromo-3-chl oropropane
1,2-Dibromoethane
Di bromomethane
Trans- l,4-dichloro-2-butene
Di chl orodi f 1 uoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
Trans-l,2-dichloroethene
1,2-Dichloropropane
Trans-1 ,3-di chl oropropene
Cis-l,3-dichloropropene
1,4 Dioxane
Ethyl cyanide
Ethyl methacrylate
lodomethane
Isobutyl alcohol
Methyl ethyl ketone
Methyl methacrylate
Methyl methane sulfonate
Methyl aery 1 oni tri 1 e
Methyl ene chloride
Pyridine
1,1,1 ,2-Tetrachl oroethane
1,1,2,2-Tetrachloroethane
50
10
10
10
10
10
10
10
10
0.25
10
10
1
10
10
10
10
10
10
0.25
10
10
10
10
10
25
25
25
250
0.5
10
10
1
50
10
25
1
50
25
10
10
Makeup
CK01P-
1-C1
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND.
43b
ND
ND
ND
ND
ND
ND
ND
Effluent
CK01P-
1-D1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NDb
22
ND
ND
ND
ND
ND
ND
ND
Effluent
CK01P-
2-D1
5.3b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Effluent
CK01P-
3-D1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
19b
ND
ND
ND
ND
ND
ND
ND
(continued)
44
-------
TABLE 20 (continued)
Analyte
Quanti-
tation
limits
Ma-keup
CK01P-
1-C1
Effluent
CK01P-
1-D1
Effluent
CK01P-
2-D1
Effluent
CK01P-
3-D1
Tetrachloroethene 10
Toluene 10
Tribromomethane 10
1,1,1-Trichloroethane 10
1,1,2-Trichloroethane 10
Trichloroethene 10
Trichlorofluoromethane 10
1,2,3-Trichloropropane 250
Vinyl chloride 10
1,4-Dioxane NA
Non-BDAT Parameters
2-Chloroethyl vinyl ether 50
Ethylene oxide 250
Acetonitrile 250
Acrolein 250
Ethyl benzene 1C
Xylenes 10
Styrene 10
Ethyl ether 250
Ethyl acetate 10
Epichlorohydrin 10
Acetone 250
Methyl isobutyl ketone 50
Methylacrylonitrile NA
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO = The compound was not detected above the detection limit.
Less than the quantitation limit.
c NA = The standard is not available; the compound was searched by using a
NBS data base of 42,000 compounds.
45
-------
TASLE 21. SEMIVOLATILE ORGANIC RESULTS FOR K001-PCP SCRUBBER WATER
(ug/liter)
Analyte
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anil ine
Anthracene
Aramite
8enz(a)anthracene
Benzenethiol
Benzidine
Benzo(a)pyrene
Benzofbjfluoranthrene
Benzo(g,h,i )perylene
Benzo(k)fluoranthrene
p-Benzoquinone
Bis(2-Chloroethoxy)ethane
Bis(2-Chloroethyl)ether
Bis(2-Chloroisopropyl Jether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Butylbenzylphthalate
2-sec-Buty1-4,6-dinitrophenol
p-Chloroaniline
Chlorobenzilate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloroprop1onitrile
Chrysene
Ortho-Crespl
Para-Cresol
Dibenzfa.h) anthracene
Dibenzo(a,e)pyrene
Dibenzo(a,i jpyrene
m-D1chlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
3,3 '-Dichlorobenzi dine
2,4-Dichlorophenol
2,6-Dichlorophenol
Diethylphthalate
3,3'-Dimethoxybenzidine
p-Dimethylaminoazobenzene
3,3 ' -Dimethylbenzidine
2, 4-Di methyl phenol
Oimethylphthalate
Di-n-butylphthalate
1,4-Oi nitrobenzene
4,6-Dini tro-o-cresol
2,4-Dinitrophenol
2,4-Oinltrotoluene
2,6-D1nitrotoluene
Di-n-octylphthalate
Di-n-propy1n1trosam1ne
Di phenyl ami ne/d1phenylnitrosamine
1, 2-01 phenyl hydraz Ine
Fluoranthene
Fluorene
Quanti-
tation
limits
50
50
50
5,000
1,000
100
50
b
10
b
5,000
50
50
50
50
5,000
50
50
50
50
50
50
b
500
b
50
50
50
b
50
50
50
50
50
50
50
50
50
100
50
50
50
50.000
1,000
50,000
50
50
50
500
250
250
50
50
50
NO
50
50
50
50
Blank
NDa
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
CK01P-
1-C1
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
140
NO
NO
ND
ND
ND
CK01P-
1-01
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
ND
Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
NO
ND
CK01P-
2-01
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-
3-D1
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
NO
ND
NR
ND
ND
(continued)
46
-------
TABLE 21 (continued)
Analyte
Hexachlorobenzene
Hexachlorobutadiene
Hezachlorocyclopentadiene
hexachloroethane
Hexachlorophene
Hexachloropropene
Idenc(l,2,3-cd)pyrene
Isosafrole
Malononitrile
Hethapyrilene
3-Methylcholanthrene
4,4' -Methylenebis(2-chloro-
anil Ine)
Naphthalene
1 ,4-Naphthoquincne
1-Naphthylamine
2-Naphthylamine
p-Ni troani 1 ine
Nitrobenzene
4-Nitrophenol
N-Ni trosodi-n -butyl ami ne
N-N Hros odi ethyl ami ne
N-Ni trosoditnethylamine
N-Ni trosodi-n-propy lam ine
N-Ni trosome thy 1 ami ne
N-Ni trosomorphol ine
N-Ni tros op i peri dine
N-Ni trosopyrrol idine
5-Nitro-o-toluidine
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
2-Picoline
Pronamide
Pyrene
Resorcinol
Safrole
1 ,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Tris(2,3-dibromopropyl } phosphate
Quanti-
tation
1 imits
50
50
50
50
b
50
50
500
50,000
b
500
1,000
50
500
500
500
250
50
250
500
500
500
500
500
1,000
1,000
1,000
1,000
50
50
500
250
500
50
50
500
500
50
50
500
500
500
50
250
50
b
Blank
ND
NO
NO
ND
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-
1-C1
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
CK01P-
1-01
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Blank
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
no
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
CK01P-
2-01
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
- ND
ND
ND
ND
CK01P-
3-D1
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND « Not detected above detection limit.
b Detection limit not given, standard not available.
47
-------
TABLE 22. METALS ANALYSIS FOR K001-PCP SCRUBBER WATER SAMPLES
(yg/ml)
Analyte
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis Quantitation CK01P-
type limit 1-C1
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
0.045
0.01
0.045
0.005
0.015
0.045
0.05
0.001
0.1
0.01
0.3
0.025
0.015
0.1
0.03
NDa
ND
0.12
ND
ND
ND
0.15
ND
ND
0.021
ND
ND
ND
ND .
1.1
CK01P-
1-D1
ND
0.12
0.24
ND
0.008b
0.019b
0.09
ND
0.03b
0.18
ND
0.007b
0.01b
ND
0.61
CK01P-
2-D1
ND
0.11
0.39
ND
0.009b
0.023b
0.07
0.003
0.03b
0.20
ND
0.007b
0.006b
0.04b
0.88
CK01P-
3-D1
ND
0.16
0.31
ND
0.008b
0.020b
0.08
ND
ND
0.18
ND
0.017b
0.008b
ND
0.94
ND = Not detected above the detection limit.
Less than quantitation limit (5 times the detection limit).
48
-------
TABLE 23. PURGEABLE/NONPURGEABLE ORGANIC CARBON DATA FOR
K001-PCP SCRUBBER WATER SAMPLES
(mg/liter)
NPOC
POC
CK01P-1-C1
6
ND
CK01P-1-D1
la
3a
CK01P-2-D1
NDb
ND
CK01P-3-D1
ND
ND
Less than the quantitation limit (5 times the detection limit).
ND = Not detected above the detection limit of 1 mg/liter.
TABLE 24. K001-PCP SCRUBBER DIOXIN/FURAN RESULTS
(ng/liter)
Analyte Reagent blank, CK01P-1-C1
Total TCDD
Total TCDF
Total PCDD
Total PCDF
Total HxCDD
Total HxCDF
<1.8
<1.2
<1.8
<1.6
<3.4
<2.6
<1.8
<1.3
<2.1
<1.9
<4.4
<3.7
, CK01P-1-D1, CK01P-2-D1, CK01P-3-D1
<2.0
<1.3
<2.0
<1.7
<4.0
<3.7
<1.9
<1.3
<1.9
<1.3
<3.6
<3.4
<2.2
<1.5
<2.1
<1.9
<4.7
<5.0
49
-------
The original data tables as received from the laboratory are presented
in Appendix D.
KOOl-Creosote
The time and dates of sample collection for the KOOl-creosote test burns
at John Zink are presented in Table 25. The following is a listing of tables
that show the sample types and the results for each parameter class:
Sample type Analytical results table
KOOl-creosote feed composition
Volatile organics 26
Semivolatile organics 27
Metals 28
Total organic carbon 29
Proximate and ultimate 30
Organophosphorous pesticide 31
Organochlorine pesticide 32
Chlorinated herbicides 33
Dioxins/furans 34
Ash composition
Volatile organics 35
Semi volatile organics 36
Metals 37
Total organic carbon 38
Organophosphorous pesticide 39
Organochlorine pesticide 40
Chlorinated herbicides 41
Dioxins/furans 42
TCLP volatiles 43
TCLP semivolatiles 44
TCLP metals 45
Scrubber water composition (pretest and
during test)
Volatile organics 46
Semi volatile organics 47
Metals 48
Water quality parameters 49
Organophosphorous pesticide 50
Organochlorine pesticide 51
Chlorinated herbicides 52
Dioxins/furans 53
The original data tables as received from the laboratory are presented
in Appendix E.
50
-------
TABLE 25. K001-CREOSOTE SAMPLE INFORMATION
Test
No.
1
1
2
2
3
3
1
1
2
2
3
3
All
1
1
1
2
2
3
3
Sample No.
KOOl-Creosote Feed Samples
ZK01C-1-A1
ZK01C-1-A2
ZK01C-2-A1
ZK01C-2-A2
ZK01C-3-A1
ZK01C-3-A2
Ash Samples
ZK01C-1-B1
ZK01C-1-B2
ZK01C-2-B1
ZK01C-2-B2
ZK01C-3-B1
ZK01C-3-B2
Fly ash
Pretest Scrubber Water Sample
ZK01C-1-D1
Scrubber Water Samples
ZK01C-1-E1
ZK01C-1-E2
ZK01C-2-E1
ZK01C-2-E2
ZK01C-3-E1
ZK01C-3-E2
Date
collected
10/2/87
10/2/87
10/5/87
10/5/87
10/6/87
10/6/87
10/6/87
10/6/87
10/6/87
10/6/87
10/7/87
10/7/87
10/8/87
10/5/87
10/6/87
10/6/87
10/6/87
10/6/87
10/7/87
10/7/87
Time (24-h)
collected
a
a
a
a
a
a
1340
1525
1840
2015
1230
1445
b
1400
1340
1525
1840
2000
1230
1445
a The feed samples were collected while the fiber packs were being packed.
The fly ash sample was collected from the solids separator after the tests
were complete.
51
-------
TABLE 26. GC/MS VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE FEED
(mg/g)
Compound
Quantltatlon
limit
ZK01C-1-A1
ZK01C-1-A2
ZK01C-2-A1
ZK01C-2-A2
ZK01C-3-A1
ZK01C-3-A2 Reagent Blank
en
ro
Volatlles (Method 8240)
Acetonitrile 1000
Acroleln 2500
AcrylonltHle 50
Benzene 50
Bromodlchloromethane 50
Bromomethane 50
Carbon dlsulfide 50
Carbon tetrachlorlde 50
Chlorobenzene 50
Chlorodlbromonethane 50
Chloroethane 50
Chloroform 50
Chi orone thane 50.
2-Chloro-l,3-butad1ene NA°
2-Chloroethyl vinyl ether 500
3-Chloropropene 50
l,2-D1bra»o-3-chloropropane 50
1,2-Dlbronomethane 50
Dlbromwethane 50
Dlchlorodlfluoromethane 50
1,1-Oichloroethane 50
l.2-01chloroethane 50
1,1-Olchloroethylene 50
trans-l,2-D1chloroethene 50
trans-l,4-D1chloro-2-butene 50
1.2-01chloropropane 50
trans-l.3-D1chloropropene 50
c1s-1.3-01chloropropene 50
1,4-Dloxane NA
Ethyl cyanide NA
Ethyl methacrylate 250
lodomethane 100
Isobutyl Alcohol NA
Methyl ethyl ketone 250
Methyl methacrylate 250
Methyl methanesulfonate NA
MethylacrylonltMle NA
Methylene chloride 250
1,1.1,2-Tetrachloroethane 50
1,1,2.2-Tetrachloroethane 50
ND"
NO
ND
56
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
60
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
61
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
58
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
83
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 26 (continued)
en
u>
Quantttation
Compound limit
Tetrachl oroethene
Toluene
Tribromomethane
1.1,1-Trlchloroethane
1,1,2-Trlchloroethane
Trichloroethene
Trlchlorofluoromethane
1.2,3-Trichloropropane
Vinyl chloride
Ethyl benzene
Xylenes
Styrene
Ethyl Ether
Ethyl Acetate
Eplchlorohydrln
Acetone
Methyl Isobutyl ketone
01 -n-propy 1 nl trosoanl ne
Chi orodl f 1 uorone thane
1.3-Butadlene
Hexachl oropentadl ene
Cumene
Benzyl Chloride
Acetaldehyde
Cyclohexanone
Dimethyl Nltrosoamlne
Methyl Acetate
Propylene Oxide
Phthalic Anhydride
50
50
50
50
50
50
50
50
50
50
50
50
NA
50
NA
250
500
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
ZK01C-1-A1
NO
110
NO
ND
NO
ND
ND
ND
ND
57
120
69
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-A2
ND
120
ND
ND
ND
ND
ND
ND
ND
56
130
71
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-A1
ND
100
ND
ND
ND
ND
ND
ND
ND
55
120
64
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-A2
ND
110
ND
ND
ND
ND
ND
ND
ND
72
130
66
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-A1
ND
110
ND
ND
ND
ND
ND
ND
ND
71
130
71
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-A2
ND
170
ND
ND
ND
ND
ND
ND
ND
87
170
98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND « not detected above the detection limit.
NA * standard not available. Compound searched by using an NBS data base of 42,000 compounds.
-------
TABLE 27. SEMI VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE WASTE FEED SAMPLES
(pg/g)
Compound
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetylaminofluorene
4-Aminob1phenyl
Aniline
Anthracene
Aramlte
Benz(a)anthracene
Benzene thlol
Benzidlne
Benzo(a)pyrene
Benzol b and/or K)fluoranthrene
Benzo(g.h,1)peryiene
p-Benzoqulnone
Bis 2-Chloroethoxy)methane
Bis 2-Chloroethyl)ether
Bis 2-Chloro1sopropyl)ether
Bis 2-ethylhexyl)phthalate
4-Bronophenyl phenyl ether
Butyl benzyl phthal ate
2-sec-Butyl-4,6-d1n1trophenol
p-Chloroanlllne
Chlorobenzllate
p-Chloro-n-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropionitrile
Chrysene
ortho-Cresol
para-Cresol
D1 benz ( a ,h )anthracene
D1benzo(a.e)pyrene
D1benzo(a,1)pyrene
n-DI chl orobenzene
o-DI chl orobenzene
p-01 ch 1 orobenzene
3,3'-D1chlorobenz1d1ne
2,4-D1chlorophenol
2,6-Dichlorophenol
Diethylphthalate
3.3'-D1wethoxybenzidine
p-Dimethylamlnoazobenzene
3,3'-Dimethylbenzid1ne
2, 4-Dime thy 1 phenol
Quantitation
limit
4.600
2,500
3.700
8,500
3.950
13,000
2.500
NAC
10.500
NA
10.000
3.300
6,500
5,500
NA
7,000
7,500
7,500
3,300
2,500
3,300
NA
13.000
5,500
NA
2.500
4.350
NA
3,300
13,000
13.000
3.300
NA
NA
2.500
2.500
6,000
22 .000
3.550
900
2,500
NA
4.500
4,000
3.500
ZKOlC-1-Al
¥~ 1
NDb
21,000
ND
ND
ND
ND
15.000
ND .
4.500°
ND
ND .
1.70Q-S
4,900°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.800
ND
ND'
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
870
ZK01C-1-A2
x=0.94
1000
15 ,000
ND
ND
ND
ND
7.300
ND ,
4,000
ND
ND .
1.800°
4.700d
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
4,200
ND .
3.400°
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
1.200
ZK01C-2-A1
x=l
ND
19,000
ND
ND
ND
ND
12.000
ND .
4.600°
ND
ND
1.900°
3,900°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4,800
ND .
3.300°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
1.100°
ZK01C-2-A2
x=0.98
ND
16.000
ND
ND
ND
ND
8,500
ND .
4,000°
ND
NO
1,700°
4,100
ND
ND
ND
ND
ND
92°
ND
ND
ND
ND
ND
ND
NO
ND
ND
4,100
ND
3.600
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.200°
ZK01C-3-A1
x=0.97
NO
19.000
ND
ND
ND
ND
7,400
ND
4,200
ND
ND
1 .600°
3,000°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4,200
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
910d
ZK01C-3-A2
ND
17,000
ND
ND
ND
ND
9.100
ND
4,000
ND
ND
1,700°
3.100°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4,300
ND
3,100°
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
1,200°
Reagent blank
x=0.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 27 (continued)
Quantitation
Compound limit
Dimethyl phtha late
D1-n-butylph thai ate
1,3-Dinitrobenzene
4 ,6-D1nitro-o-creosol
2,4-Dlnitrophenol
2.4-D1n1trotoluene
2,6-Dlnltrotoluene
Dl-n-octylphthalate
DIphenylaBilne/dlphenylnitrosamine
l,2-D1phenlhydraz1ne
Fluoranthene
Fluorene
Hexachl orobenzene
Hexachl orobutad 1 ene
Hexachl orocycl opentadl ene
Hexachloroethane
Hexachl orophene
Hexachl oropropene
lndeno(l,2,3-c,d)pyrene
Isosafrole
££ Methapyrllene
3-Methylcholanthrene
4.4'-Methyleneb1s(2-chloroan1l1ne)
Naphthalene
1 ,4-Naphthoqulnone
1-Naphthylamine
2-Naphthylamlne
p-Nitroanil 1ne
Nitrobenzene
4-Nitrophenol
N-N1trosodi-n-butylam1ne
N-N1 trosodlethyl ami ne
N-Nltrosodlnethylamine
N-N 1 trosodl -n-propy 1 ami ne
N-Nltrosonethyl ethyl ami ne
N-Nitrosomorphol Ine
N-Nitrosoplperldlne
H-N1 trosopyrrol Idlne
5-Nltro-o-toluldlne
Pentachl orobenzene
Pentachloroethane
Pentachl oronitrobenzene
Pentachl orophenol
Phenacetln
Phenanthrene
Phenol
2.100
33.000
3.450
31.500
55,000
7,500
2.500
3.300
2.650
NA
29.000
2.500
2.500
1.200
8.000
2.100
NA
7.500
4.900
2.000
16.000
4.600
NA
2,100
1,600
7,500
17 ,000
65.000
2.500
3,150
4,100
3,550
13.000
16.000
4,600
4.500
3.850
55,000
3,450
2,000
2.500
3.450
4,750
NA
7,000
2,000
ZKOlC-1-Al
id
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND H
26.000
18.000
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
42,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
41,000
2,400
ZK01C-1-A2
x=0.94
NO
riC
ND
ND
ND
ND
ND
ND
ND
ND .
22,000°
12,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
40,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
32,000
3,700
ZK01C-2-A1
x=l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
25,000
16.000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
40,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
37.000
3,600
ZK01C-2-A2
x=0.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND A
21.000°
14,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
32.000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
29,000
3.900
ZK01C-3-A1
x=0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
23 .000°
16.000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
29.000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
32,000
2,400
ZK01C-3-A2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
23 .000°
14,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
43,000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
36,000
3,300
Reagent blank
x=0.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 27 (continued)
Compound
2-P1col1ne
Pronamide
Pyrene
Resorcinol
Safrole
1 ,2 ,4 ,5-Tetrachlorobenzene
2,3,4.6-Tetrachlorophenol
1.2,4,-Trlchlorobenzene
2 ,4 ,5-Tri chlorophenol
2,4.6-Trichlorophenol
Quantitation
limit
3.150
2.400
2.500
NA
3.300
2.000
9,000
2.500
13.000
3.650
Tr1s(2,3-d1bromopropyl)phosphate NA
* Variable dilutions perforated
limit) for that sample.
b NO - not detected above the
c NA * standard not available.
d Less than quantltatlon limit
en
cri
ZKOlC-1-Al
x=la
ND
NO
17.000
ND
ND
ND
ND
ND
ND
ND
ND
for each sample. Quantltatlon
detection limit.
Compound searched
(5 times detection
by using NBS
limit).
ZK01C-1-A2
x-0.94
ND
ND
13.000
ND
ND
ND
ND
ND
ND
ND
NU
limit times x
data base of
ZK01C-2-A1 ZK01C-2-A2
x=l
ND
ND
16,000
ND
ND
ND
ND
ND
ND
ND
ND
(listed under sample
42,000 compounds.
x=0.98
ND
ND
12.000
ND
ND
ND
ND
ND
ND
ND
ND
number) is
ZK01C-3-A1
x=0.97
ND
ND
15.000
ND
ND
ND
ND
ND
ND
ND
ND
the quantitation
ZK01C-3-A2
x=l.ll
ND
ND
13,000
ND
ND
ND
ND
ND
ND
ND
ND
limit (5 times
Reagent blank
x=0.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
the detection
-------
TABLE 28. METALS ANALYSIS RESULTS FOR K001-CREOSOTE FEED SAMPLES
Ug/g)
Parameter
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Hercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis Quantttation
type 1 Imi t
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
3.5
2.0
1.0
0.5
2.0
3.5
3.0
1.25
7.5
21
17
2.0
2.5
4.0
1.0
ZK01C-1-A1
NDa
2.6
63
ND
3.4
5.0
35 h
0.35°
2.1B
170
ND b
1.5b
7.7
ND
170
ZK01C-1-A2 ZK01C-2-A1
ND
ND
58
ND
3.4
4.8
32 b
0.35b
ND
160
ND fa
1.4b
8.0
ND
170
ND
2.1
70
ND
3.1
6.4
39
ND h
2.1b
150
NO b
1.2b
6.8
ND
160
ZK01C-2-A2 ZK01C-3-A1 Reagent blank
NO
2.5
59
ND
2.4
7.0
39 b
°-4B
2.8D
110
ND b
i.r
5.3
0.82b
120
ND .
0.7b
12
ND
0.79b
1.6°
12 b
l.B
37
ND b
0.3b
2.2
ND
40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-A2 Reagent blank
ND
2.6
150
ND
3.5
8.6
38
0.64b
4.5B
190
ND h
l.l"
3.3K
1.9b
200
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
• NO • not detected above the detection limit.
b Less than quantltatlon Unit (5 times detection limit).
-------
TABLE 29. K001-CREOSOTE FEED TOTAL ORGANIC CARBON RESULTS
(ug/g)
Parameter
TOC
Quantitation
limit
0.5
ZK01C-3-A2
61
TABLE 30. K001-CREOSOTE FEED SAMPLE ZK01C-1-A1
ULTIMATE AND PROXIMATE ANALYSES RESULTS
Parameter
Drying loss
Carbon
Hydrogen
Oxygen
Nitrogen
Sulfur
Ash
Volatile matter
Fixed carbon
ZK01G-1-A1, %
9.19
66.2
5.26
14.0
0.09
0.51
12.7
58.0
20.1
58
-------
TABLE 31. K001-CREOSOTE FEED SAMPLE ORGANOPHOSPHOROUS
PESTICIDE RESULTS
Ug/g)
Compound
Phorate
Sulfatepp
Disulfoton
Methyl parathion
Ethyl parathion
Famphur
Quantitation
limit
0.10
0.10
0.20
0.20
0.15
0.50
Reagent
blank
NDa
ND
ND
ND
ND
ND
ZK01C-1
ND
ND
ND
ND
ND
ND
Not detected above the detection limit.
59
-------
TABLE 32. K001-CREOSOTE WASTE FEED ORGANOCHLORINE
PESTICIDE RESULTS (yg/g)
Quantitation Reagent
Compound limit blank ZK01C-1-A1
Aldrin
(Alpha)-BHC
(Beta)-BHC
(Delta)BHC
(Gamma)-BHC
Chlordane
p,p'-DDD
p.p'-DDE
p.p'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
7.5
4.0
7.5
7.5
5.0
100
15
7.5
15
7.5
7.5
7.5
7.5
15
5.0
7.5
7.5
40
25
1000
1000
1000
1000
1000
1000
300
400
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.1b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
a Not detected above the detection limit.
Less than quantitation limit (5 times detection limit).
60
-------
TABLE 33. K001-CREOSOTE WASTE FEED SAMPLES CHLORINATED
HERBICIDES RESULTS
(ug/g)
Compound
2,4-D
Si 1 vex
2,4,5-T
Dinoseb
Quantitation
1 imit
1.25
0.375
0.375
0.375
ZK01C-1-A
NDa
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
3 Not detected above the detection limit.
TABLE 34. K001-CREOSOTE FEED SAMPLES DIOXIN/FURAN RESULTS
(ng/g)
Compound
Total TCDD
Total TCDF
Total PCDD
Total PCDF
Total HxCDD
Total HxCDF
Reagent blank
<0.2
<0.2
<0.2
<0.2
<0.5
<0.4
ZK01C-1-A13
<52
<39
<48
<41
<129
<87
a The complex matrix required a 1000:1 dilution to obtain
suitable chromatography. The detection limits have been
affected by this dilution.
61
-------
TABLE 35. GC/MS VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE ASH
(yg/g)
Compound
Quantltatlon
limit (PQL)
ZK01C-1-B1
ZK01C-1-B2
ZK01C-2-B2
ZK01C-2-B1
ZK01C-3-B1
Fly Ash
ZK01C-3-B2 Reagent Blank
Volatlles (Method 8240)
Acetonitrlle 1000
Acrolein 2500
Acrylonltrlle 50
Benzene 50
Bromodichloromethane 50
Bromomethane 50
Carbon dlsulfide 50
Carbon tetrachlorlde 50
Chlorobeiuene 50
Chlorodlbronomethane 50
Chloroethane 50
Chloroform 50
Chloromethane 50.
2-Chloro-l.3-butad1ene NAD
2-Chloroethyl vinyl ether 500
O-, 3-Chloropropene 50
ro 1.2-D1brono-3-chloropropane 50
1.2-D1bro»omethane 50
Dlbromonethane 50
Dlchlorodlfluoronethane 50
1.1-Dichloroethane 50
l,2-D1chloroethane 50
1.1-Dlchloroethylene 50
Trans-1,2-dlchloroethene 50
Trans-1,4-d1chloro-2-butene 50
l.2-D1chloropropane 50
Trans-1.3-d1ch1oropropene 50
C1s-l,3-d1chloropropene 50
1.4-Dioxane NA
Ethyl cyanide NA
Ethyl nethacrylate 250
lodonethane 100
Isobutyl Alcohol NA
Methyl ethyl ketone 250
Methyl methacrylate 250
Methyl nethanesulfonate NA
Methylacrylonltrlle NA
Methylene chloride 250
1,1,1,2-Tetrachloroethane 100
1.1.2.2-Tetrachloroethane 100
ND"
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 35 (continued)
CO
Quantltatton
Compound limit (PQL)
Tetrachloroethene
Toluene
Tribromomethane
1 ,1 ,1-Trichloroethane
1 ,1 ,2-Trichloroethane
Trlchloroethene
Trlchlorofluorome thane
1 ,2,3-Trlchloropropane
Vinyl chloride
Ethyl benzene
Xylenes
Styrene
Ethyl Ether
Ethyl Acetate
Eplchlorohydrln
Acetone
Hethyl Isobutyl ketone
01 -n-propyl nl trosoaml ne
Chlorodlfluorofflethane
1.3-Butadlene
Hexachloropentadlene
Cumene
Benzyl Chloride
Acetaldehyde
Cyclohexanone
Dimethyl N1 trosoaml ne
Methyl Acetate
Propylene Oxide
Phthallc Anhydride
50
50
50
50
50
50
50
50
50
50
50
50
NA
50
NA
250
500
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
ZK01C-1-B1
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ZK01C-1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly Ash
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-R2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent Blank
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
a ND = Not detected above the detection limit.
NA = Standard not available. Compound searched by using an NBS data base of 42,000 compounds.
-------
TABLE 36. SEMI VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE ASH SAMPLES
(yg/g)
Quant Itatlon
Compound Unit (PQL)
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetylamlnofluorene
4-AiRlnoblphenyl
Aniline
Anthracene
Aramlte
Benz(a)anthracene
Benzenethlol
Benzldlne
Benzo(a)pyrene
Benzolb t/or K)fluoranthrene
Benzo(g,h,1)perylene
p-Benzoquinone
81 s ( 2-chl oroethoxy )ne thane
Bis 2-chloroethyl)ether
Bis 2-chloro1sopropyl)ether
B1s 2-e thy lhexyl)ph thai ate
4-Bromophenyl phenyl ether
Butyl benzylph thai ate
2-Sec-butyl -4 ,6-d1 n1 trophenol
p-Chloroaniline
Chlorobenzllate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropionitrile
Chrysene
Ortho-cresol
Para-cresol
Di benz( a ,h)anthracene
Dibenzo(a,e)pyrene
D1benzo(a.1)pyrene
p-Dlchlorobenzene
o*D1 chl orobenzene
p-Dlchlorobenzene
3.3'-D1chlorobenz1dine
2,4-D1chlorophenol
2,6-Dlchlorophenol
Diethylphthalate
3,3'-Dimethoxybenz1dine
p-Dimethylaminoazobenzene
3,3'-Dimethylbenzidine
2,4-Dimethylphenol
1.15
0.65
0.95
2.15
100
3.35
0.65
NAD
2.60
NA
14.5
0.85
1.60
1.35
NA
1.80
1.90
1.90
0.85
0.65
0.85
NA
3.35
1.35
1.0
0.65
1.10
NA
0.85
3.35
3.35
0.85
NA
NA
0.65
0.65
1.45
5.5
0.90
2.30
0.65
NA
1.15
2.75
0.90
ZK01C-1-B1
NDa
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.18C
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ZK01C-3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
NO
0.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
Fly ash
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 36 (continued)
en
Quantltatlon
Compound limit (PQL)
Dlmethylphthalate
Dl-n-butylphthalate
1,3-DI nitrobenzene
4,6-01n1tro-o-creosol
2,4-Dlnitrophenol
2,4-Dlnitrotoluene
2,6-Dlnitrotoluene
Dl-n-octylphthalate
01 phenyl ami ne/d1 phenyl ni trosaml ne
1.2-D1phenlhydrazine
Fluoranthene
Fluorene
Hexachl oro benzene
Hexachl orobutadl ene
Hexachl orocyclopentadl ere
Hexachl oroethane
Hexachl orophene
Hexachl oropropene
Indeno(l,2,3-c,d)pyrene
Isosafrole
Methapyrilene
3-Methy 1 chol anthrene
4,4'-Hethylenebis(2-chloroan11ine)
Naphthalene
1 ,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
p-N1troan111ne
Nitrobenzene
4-N1trophenol
N-N1trosodi-n-butylam1ne
N-Nltrosodl ethyl ami ne
N-Nltrosodimethylamlne
N-Nitrosodl-n-propylamine
N-NUrosomethylethylamlne
N-Nltrosomorphol ine
N-N1 trosopiperldi ne
N-Nitrosopyrrolid1ne
5-Nitro-o-toluldine
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
0.55
0.85
0.85
8.0
14.0
1.90
0.65
0.85
0.65
NA
0.75
0.65
0.65
0.30
2.0
0.55
NA
1.90
1.25
0.50
4.0
1.15
NA
0.55
0.40
1.90
4.35
17.0
0.65
0.80
1.05
0.90
3.35
4.0
1.15
1.15
0.95
1.40
0.85
0.50
0.65
0.85
1.20
NA
1.80
0.50
ZK01C-1-B1
ND
0.83C
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-B2
ND
0.70C
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
0.93
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ZK01C-2-B1
ND c
0.53
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NP
ND
ND
ND
ZK01C-3-B1
ND
0.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND c
0.77C
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
(continued)
-------
TABLE 36 (continued)
Compound
2-P1col1ne
Pronamide
Pyrene
Resorclnol
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
1 ,2 ,4 ,-Trlchlorobenzene
2,4,5-Trlchlorophenol
2.4,6-THchlorophenol
Quantltatlon
limit (PQL)
0.80
0.60
0.65
NA
0.85
0.50
2.30
0.65
3.35
0.90
Tr1s(2,3-d1bromopropyl)phosphate NA
ZK01C-1-B1
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-B2
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ZK01C-2-B1
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ZK01C-3-B1
ND
NP
ND
ND
ND
ND
ND
ND
ND
ND
NO
ZK01C-3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
ND
NH
ND
ND
ND
NO
ND
ND
ND
ND
Reagent
blank
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
cn
en
* NO = Not detected above the detection limit.
6 NA « Standard not available; quantltatlon limit not determined.
0 Less than quantltatlon limit (5 times detection limit).
-------
TABLE 37. METALS ANALYSIS RESULTS FOR K001-CREOSOTE ASH SAMPLES
(ug/g)
Parameter
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Lead
Antimony
Selenium
Thai Hum
Vanadium
Zinc
Analysis
type
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
Quantitation
limit (POL)
3.5
2.0
1.0
0.5
Z.O
3.5
3.0
1.25
7.5
21
17
2.0
2.5
4.0
1.0
ZK01G-1-B1
NDa
5.3
81
NO
ND
6.1
86
ND .
3.6b
ND
ND
2.3
ND
4.4
1.9
ZK01G-1-B2
ND
5.3
74
NO
ND
5.3
100
ND .
4.6b
NO
NO .
1.9b
ND
4.1
1.8
Reagent
blank
nn
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01G-2-B1
NO
9.0
61
NO
ND
5.8
98
ND .
5.0b
NO
NO .
1.8b
ND
4.1
3.2
ZK01G-2-B2
NO
10
48
ND
ND
8.7
110
ND .
5.2b
ND
ND
2.5
NO
4.2
2.8
ZK01G-3-B1
ND
13
56
ND
ND
10
130
NO .
6.8b
ND
NO
2.6
ND
5.2
3.0
Reagent
blank
Nn
Nn
NO
Nn
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ZK01C-3-B2
ND
11
72
NO
NO
7.7
86
ND .
3.9b
ND
NO
2.8
NO
4.8
2.5
Reagent
blank
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
17
90
0.35
54
120
77
ND
26
110
NO
NO
ND
21
290
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
CTi
ND « not detected above the detection limit.
Less than quantitation limit (5 times detection limit).
-------
CT>
CO
TABLE 38. K001-CREOSOTE ASH SAMPLES TOTAL ORGANIC CARBON RESULTS
Parameter
TOC
Quanti-
tatlon
limit
0.5
ZK01C-1-B1
27
ZK01C-1-B2
41
ZK01C-2-B1
58
ZK01C-2-B2
29
ZK01C-3-B1
32
ZK01C-3-2
38
-------
TABLE 39. K001-CREOSOTE ASH SAMPLES ORGANOPHOSPHOROUS
PESTICIDE RESULTS
(yg/g)
Compound
Phorate
Sulfotepp
Disulfoton
Methyl parathion
Ethyl parathion
Famphur
Quantitation
limit
0.05
0.05
0.10
0.10
0.65
0.25
Reagent
blank
NDa
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
ND
ND
ND
ND
a Not detected above detection limit.
69
-------
TABLE 40. K001-CREOSOTE ASH SAMPLE ORGANOCHLORINE
PESTICIDE RESULTS
(vg/kg)
Compound
Aldrin
(Alpha)-BHC
(Beta)-BHC
(Delta)BHC
(Gamma)-BHC
Chlordane
p,p'-DDD
p.p'-DDE
p.p'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Quantitation
limit
5.0
2.5
5.0
5.0
5.0
65
10
5.0
10
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
30
15
500
500
500
500
500
500
250
250
Reagent
blank
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Not detected above the detection limit.
70
-------
TABLE 41. K001-CREOSOTE ASH SAMPLES CHLORINATED
HERBICIDES RESULTS
(yg/g)
Compound
2,4-D
Si 1 vex
2,4,5-T
Dinoseb
Quantitation
limit
2.5
0.10
0.10
0.10
ZK01C-3-B2
NDa
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
3 Not detected above the detection limit.
71
-------
TABLE 42. K001-CREOSOTE ASH SAMPLES DIOXIN/FURAN RESULTS
(ng/g)
Compound Reagent blank ZK01C-3-B2 ZK01C-3-B2
Total TCDD <0.2 <0.3 <0.4
Total TCDF <0.2 <0.2 <0.3
Total PCDD <0.2 <0.3 <0.3
Total PCDF <0.2 <0.2 <0.3
Total HxCDD <0.5 <0.5 <0.7
Total HxCDF <0.4 <0.5 <0.6
72
-------
TABLE 43. VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE ASH SUBJECTED TO TCLP
(yg/g)
Compound
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodl chl orome thane
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chl orodl bronomethane
Chl oroe thane
Chloroform
Chloromethane
2-Chloro-l,3-butadiene
2-Chloroethyl vinyl ether
3-Chloropropene
1 ,2-D1brorao-3-chloropropane
1 ,2-01 bronomethane
01 bronomethane
Olchlorodlfluoromethane
1 ,l-D1chloroethane
1,2-Dlchloroethane
1,1-Dlchloroethylene
Trans-1, 2-dichloroethene
Trans-1 ,4-d1chloro-2-butene
1,2-Dlchloropropane
Trans-1 ,3-dichloropropene
C1s-l,3-d1chloropropene
1,4-Dloxane
Ethyl cyanide
Ethyl methacrylate
lodome thane
Isobutyl Alcohol
Methyl ethyl ketone
Methyl nethacrylate
Methyl methanesulfonate
Methylacrylonltrlle
Methyl ene chloride
1,1, 1-2-Tetrachl oroethane
1,1, 2, 2-Tetrachl oroe thane
Tetrachloroethene
Toluene
Tribromomethane
1,1,1-Trl chl oroe thane
1 ,1 ,2-Trichloroethane
Quant1tat1on
limit (PQL)
1000
2500
50
50
50
50
50
50
50
50
50
50
50.
NAb
500
50
50
SO
50
50
50
50
50
50
50
50
50
50
NA
NA
250
100
NA
250
250
NA
NA
250
50
50
50
50
50
50
50
ZK01C-1-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 43 (continued)
Compound
Trlchloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl chloride
Ethyl benzene
Xylenes
Styrene
Ethyl ether
Ethyl acetate
EpichlorohydHn
Acetone
He thy 1 Isobutyl ketone
01 -n-propy 1 ni trosoaml ne
Chlorodl f luoronethane
l.3-Butad1ene
Hexach 1 oropentadi ene
Cumene
Benzyl chloride
Acetaldehyde
Cyclohexanone
Dimethyl nltrosoamine
Methyl acetate
Propylene oxide
Phthallc anhydride
Quantitation
limit (PQL)
50
50
50
50
50
10
10
NA
50
NA
250
500
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
ZK01C-1-B1
NDa
ND
NO
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ZK01C-1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ZK01C-3-B1
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP Blank
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP Blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND - not detected above the detection limit.
b NA = standard not available. Compound searched by using NBS data base of 42,000 compounds.
-------
TABLE 44. TCLP SEMI VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE ASH SAMPLES
(yg/liter)
Quantitation ZK01C-
Compound limit (PQL) 1-61
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetyl ami nof 1 uorene
4-Aninobiphenyl
Aniline
Anthracene
Aranite
Benz ( a ) anthracene
Benzenethiol
Benz 1 dine
Benzo(a)pyrene
Benzol b i/or K)fluoranthrene
Benzo(g,h,1)perylene
p-Benzoqulnone
Bis 2-chloroethoxy)nethane
B1s 2-chloroethyl)ether
Bis 2-chloroisopropyl)ether
Bis 2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Butyl benzyl phthal ate
2-Sec-butyl-4,6-dinitrophenol
p-Chloroaniline
Chlorobenzllate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropionitrile
Chrysene
Ortho-cresol
Para-cresol
01benz(a.h)anthracene
D1benzo(a,e)pyrene
01 benzo ( a , 1 ) py rene
•-Dlchloro benzene
o-D1chlorobenzene
p-D i ch 1 orobenzene
3,3'-Dichlorobenzidine
2 ,4-Dichlorophenol
2,6-Dlchlorophenol
Diethylphthalate
3,3'-Dimethoxybenz1dine
p-Dimethylaminoazobenzene
3,3'-Dimethylbenzidine
2. 4-Dimethyl phenol
20
10
15
30
15
55
10.
NAb
40
NA
250
15
25
20
NA
30
30
30
15
10
15
NA
55
20
NA
10
20
NA
15
55
55
15
NA
NA
10
10
25
85
15
35
10
40
15
NA
15
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
'ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
1-B2
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
3-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
NU
ND
NU
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP
blanka
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 44 (continued)
Quantitation ZK01C-
Compound limit (PQL) 1-B1
Dimethylphthalate
01-n-butylphthalate
1,3-Di nitrobenzene
4,6-D1n1tro-o-creosol
2,4-Dinitrophenol
2.4-Dinltrotoluene
2,6-Dlnitrotoluene
01 -n-octylphthalate
01 pheny 1 ami ne/di pheny Inl trosamlne
1,2-Diphenlhydrazlne
Fluoranthene
Fluorene
Hexachl oro benzene
Hexachlorobutadiene
Hexachl orocycl open tad i ene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno( 1 ,2 ,3-c ,d)pyrene
Jjosafrole
Nethapyrllene
3-Methy 1 chol anthrene
4.4l-Methylenebis(2-ch)oroan1l1ne)
Naphthalene
1,4-Naphthoo.ulnone
1-Naphthylamlne
2-Naphthylam1ne
p-Nltroaniline
Nitrobenzene
4-Nitrophenol
N-Nitrosodl-n-butylamine
N-N1trosodiethylamine
N-Ni trosod Imethy 1 ami ne
N-Nitrosodi-n-propylamlne
N-Nitrosonethylethylanlne
N-Nitrosomorphol ine
N-N1trosop1peridine
N-N1 trosopyrrol idine
5-N1tro-o-tolu1dine
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachl orophenol
Phenacetin
Phenanthrene
Phenol
10
15
15
125
220
30
10
15
10
NA
10
10
10
5
30
10
NA
30
20
10
60
20
NA
10
5
30
65
260
10
15
15
15
55
65
20
15
15
20
15
10
10
15
20
NA
30
10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND'
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ZK01C-
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
2-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
3-B1
ND
ND
ND
ND
ND
NO
NO
ND
NO
ND
NO
NO
NO
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ZK01C-
3-B2
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
tIP
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
Fly ash
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NP
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TCLP
blank3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
Nn
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 44 (continued)
Quantitation ZK01C-
Compound limit (PQL) 1-B1
2-Picoline
Pronamide
Pyrene
Resorcinol
Safrole
1 ,2,4,5-Tetrachlorobenzene
2,3,4 ,6-Tetrachl orophenol
1.2,4,-Trichlorobenzene
2,4,5-Trlchlorophenol
2 ,4 ,6-Trlchl orophenol
Tr1s(2,3-dibromopropyl)phosphate
10
10
10
NA
15
10
35
10
55
NA
15
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ZK01C-
1-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
2-B1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-
2-B2
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ZK01C-
3-B1
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ZK01C-
3-B2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Fly ash
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
TCLP
blank3
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
Reagent
blank
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
Reagent
blank
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
* ND « not detected above detection limit.
NA = standard not available. Detection limit not determined.
-------
TABLE 45. METALS RESULTS FOR K001-CREOSOTE ASH TCLP EXTRACTION SAMPLES
(mg/liter)
Parameter
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Hercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis Quantitatlon
type limit (PQL)
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
0.035
0.020
0.010
0.005
0.020
0.035
0.030
0.0025
0.075
0.210
0.170
0.020
0.025
0.040
0.010
ZK01G-1-B1
NDa
NP
0.38
NO
ND
ND
0.020
NO
ND
NO
0.035
ND
ND
ND
0.020
ZK01G-1-B2
ND
ND
0.57
ND
ND
ND
0.030
ND
ND
ND
ND
NO
ND
ND
0.050
ZK01G-2-B1
ND
ND
0.53
ND
ND
ND
0.030
ND
0.020
ND
0.040
ND
ND
ND
0.080
ZK01C,-2-B2
ND
ND
0.31
ND
ND
ND
ND
ND
ND
ND
0.040
ND
ND
ND
0.010
ZKOlf.-3-Bl
NO
0.025
0.22
ND
ND
ND
0.008
ND
ND
ND
0.040
0.004
ND
0.020
0.030
TCLP blank
ND
ND
0.020
ND
ND
ND
0.030
ND
ND
ND
ND
ND
ND
ND
0.003
Reagent
blank
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-B2
ND
ND
0.41
ND
ND
ND
0.070
ND
0.020
ND
0.040
ND
ND
ND
0.002
Fly ash TCLP blank
ND
0.12
0.080
ND
0.006
2.8
0.009
ND
0.030
ND
0.060
0.004
ND
0.12
0.11
NO
ND
0.008
ND
ND
ND
0.15
ND
ND
ND
ND
ND
ND
ND
0.010
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Not detected above detection limit.
Co
-------
TABLE 46. GC/MS VOLATILE ORGANIC RESULTS FOR K001-CREOSOTE WATER SAMPLES
dig/liter)
Compound
Quantitation
limit (PQL)
ZK01C-1-D1 ZK01C-1-E1 ZK01C-1-E2 ZK01C-2-E1 ZK01C-2-E2 ZK01C-03-E1 ZK01C-03-E2
Volatile* (Method 8240)
Acetonitrlle 1000
Acrolein 2500
Acrylonitrlle 50
Benzene 50
BroModichloromethane 50
Bromonethane 50
Carbon dlsulflde 50
Carbon tetrachlorlde 50
Chlorobenzene 50
Chlorodlbromonethane 50
Chloroethane 50
Chloroform 50
Chiorone thane 50.
2-Chloro-l,3-butadiene NA
2-Chloroethyl vinyl ether 500
3-Chloropropene 50
l,2-D1bro«o-3-chloropropane 50
1.2-Dlbrononethane 50
Dlbrononethane 50
Dlchlorodlfluoromethane 50
1,1-Dichloroethane 50
1.2-D1chloroethane 50
1,1-Dlchloroethylene 50
Trans-l,2-d1chloroethene 50
Trans-l,4-d1chloro-2-butene 50
1.2-D1chloropropane 50
Trans-l,3-d1chloropropene 50
C1s-l.3-d1chloropropene 50
1.4-D1oxane NA
Ethyl cyanide NA
Ethyl methacrylate 250
lodomethane 100
Isobutyl Alcohol NA
Methyl ethyl ketone 250
Methyl methacrylate 250
Methyl methanesulfonate NA
Methylacrylonitrlle NA
Methylene chloride 250
1,1,1,2-Tetrachloroethane 50
1,1,2.2-Tetrachloroethane 50
NO"
ND
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 46 (continued)
00
o
Compound
Tetrachloroethene
Toluene
Trlbromonethane
1,1.1-Trichloroe thane
1.1,2-Trlchloroe thane
Trlchloroethene
Trlchlorofluorome thane
1,2,3-Trichl oropropane
Vinyl chloride
Ethylbenzene
Xylenes
Styrene
Ethyl ether
Ethyl acetate
Eplchlorohydrln
Acetone
Nethyl Isobutyl ketone
01 -n-propy 1 nl trosoanl ne
Chlorodlfluoromethane
1,3-Butadlene
Hexachl oropentad 1 ene
Cunene
Benzyl chloride
Acetaldehyde
Cyclohexanone
Dimethyl nitrosoamine
Methyl acetate
Propylene oxide
Phthalic anhydride
Quantltatlon
limit (PQL)
50
50
50
50
50
50
50
50
50
50
50
50
NA
50
NA
250
500
NA
NA
NA
NA
NA
NA
«A
NA
NA
NA
NA
NA
ZK01C-1-D1
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-E1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-E2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-E1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ZK01C-2-E2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-03-E1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-03-E2
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND = not detected above detection limit.
NA - standard not available. Compound searched using an NBS data base of 42,000 compounds.
-------
TABLE 47. SEMIVOLATILE ORGANIC RESULTS FOR K001-CREOSOTE SCRUBBER WATER
(pg/liter)
CO
Quantitation
Compound limit
Acenaphthalene
Acenaphthene
Acetophenone
2-Acetylaminofluorene
4-Amlnoblphenyl
Aniline
Anthracene
Aramite
Benz(a)anthracene
Benzene t hi ol
Benzidine
Benzo(a)pyrene
Benzol b and/or K)fluoranthrene
Benzo(g,h,1)perylene
p-Benzoquinone
B1s(2-chloroethoxy)me thane
B1s(2-chloroethyl )ether
Bis(2-chloro1sopropyl)ether
Bfs(2-ethylhexy1)phthalate
4-Bromophenyl phenyl ether
Butyl benzyl ph thai ate
2-Sec-butyl-4,6-d1n1trophenol
p-Chloroaniline
Chlorobenzllate
p-Chloro-m-cresol
2-Chloronaphthalene
2-Chlorophenol
3-Chloroproplonitrlle
Chrysene
Ortho-cresol
Para-cresol
Dibenz(a,h)anthracene
Dibenzo(a.e)pyrene
Dibenzo(a,1)pyrene
•-Dichloro benzene
o-D1chlorobenzene
p-Dlchlorobenzene
3,3'-Dichlorobenzidine
2,4-Dkhlorophenol
2 ,6-Di chl orophenol
Diethylphthalate
3.3'-Dimethoxybenzidine
p-Dimethylaminoazobenzene
3,3'-Dimethylbenzidine
2, 4-Dimethyl phenol
20
10
15
30
15
55
10_
NAC
40
NA
250
15
25
20
NA
30
30
30
15
10
15
NA
55
20
NA
10
20
NA
15
55
55
15
NA
NA
10
10
25
85
15
35
10
40
15
NA
15
ZK01C-1-D1
x-13
NDC
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-E1
x=l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-E2
x=3.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-E1
x=l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-E2
x=l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-E1
x=1.5C
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-E2
x=l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
TABLE 47 (continued)
Quantltation
Compound limit
Diraethylphthalate
Di-n-butylph thai ate
1,3-DI nitrobenzene
4,6-Din1tro-o-creosol
2,4-01n1trophenol
2, 4-D1n1tro toluene
2.6-Dinitrotoluene
Di-n-octylphthalate
Diphenylamine/diphenylnitrosamlne
1,2-Dlphenlhydrazlne
Fluoranthene
Fluorene
Hexachl orobenzene
Hexachlorobutadlene
Hexachlorocyclopentadlene
Hexach 1 oroe thane
Hexachl orophene
Hexachl oropropene
lndeno(1.2,3-c,d)pyrene
Isosafrole
Nethapyrllene
3-Hethylcholanthrene
4.4'-Hethylenebis(2-chloroaniline)
Naphthalene
l,4-Naphthoqu1none
l-Naphthylam1ne
2-Naphthylam1ne
p-Nitroaniline
Nitrobenzene
4-Nitrophenol
N-NUrosodi-n-butylamine
N-N 1 trosodl ethyl anl ne
N-N1trosod1methylam1ne
N-Nltrosodl-n-propylawlne
N-Nitrosome thy 1 ethyl ami ne
N-N 1 trosomorphol 1 ne
N-Nltrosoplperldlne
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
Pentachl orobenzene
Pentachl oroethane
PentachloronHrobenzene
Pentachl orophenol
Phenacetin
Phenanthrene
Phenol
10
15
15
125
220
30
10
15
10
NA
10
10
10
5
30
10
NA
30
20
10
60
20
NA
10
5
30
65
260
10
15
15
15
55
65
20
15
15
20
15
10
10
15
20
NA
30
10
ZK01C-J-D1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
.ND
ND
ND.
2d
ZK01C-1-E1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-1-E2
x-3.5
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-E1
ND
NU
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-2-E2
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-E1
x=1.5c
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-E2
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND.
5.5d
Reagent
blank
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
(continued)
-------
TABLE 47 (continued)
Quantitation ZK01C-J-01
Compound limit x=l
2-P1coline
Pronamide
Pyrene
Resordnol
Safrole
1,2, 4, 5-Tetrachloro benzene
2,3,4 ,6-Tetrachlorophenol
1 ,2,4,-Trlchlorobenzene
2,4,5-Trlchlorophenol
2,4,6-Trlchlorophenol
Tr1s(2,3-d1bromopropyl )phosphate
Variable dilutions performed for
10
10
10
NA
15
10
35
10
55
15
NA
each sample.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reported
ZK01C-1-E1 ZK01C-1-E2 ZK01C-2-E1 ZK01C-2-E2 ZK01C-3-E1 ZK01C-3-E2
x=l x=3.5 x=l x=l x=1.5 x=l
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
times x
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(listed under sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
number)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
is the PQL
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
for that sample.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reagent
blank
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
b ND - not detected above detection limit.
c NA - standard not available, PQL
d Less than quantltatlon limit (5
not determined
times detection
.
limit).
00
to
-------
TABLE 48. METALS ANALYSIS RESULTS FOR K001-CREOSOTE SCRUBBER WATER
(mg/1iter)
Parameter
Silver
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Hercury
Nickel
Lead
Antimony
Selenium
Thallium
Vanadium
Zinc
Analysis Quantitation
type limit
ICPES
AA
ICPES
ICPES
ICPES
ICPES
ICPES
C. Vapor
ICPES
AA
ICPES
AA
AA
ICPES
ICPES
0.035
0.020
0.010
0.005
0.020
0.035
0.030
0.0025
0.075
0.210
0.170
0.020
0.025
0.040
0.010
7.K01C-1-D1
NDd b
0.010
0.12
ND
0.64
0.09
0.18
ND
0.12
0.47
NO
ND
ND .
0.010°
0.14
ZK01C-1-E1
ND
0.041
0.76 .
0.002
0.87
0.35
0.42
0.016
0.48
2.5
ND
0.057
0.028
0.040
5.0
Reagent
blank
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ZK01C-1-E2
0.010b
0.15
0.80
ND
0.99
0.74
0.50
0.060
0.51
4.5
ND
0.11
2.4
0.060
7.1
ZK01C-2-E1
o.oiofc
0.16
0.56 .
0.001
0.95
0.60
0.43
0.008
0.56
3.5
ND
0.090
2.8
0.040
9.1
ZK01C-2-E2
0.020fc
0.28
1.0
0.001
1.2
1.0
0.51
0.29
0.60
5.4 b
0.040
0.12
3.4
0.080
11
Reagent
blank
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZKOK-03-E1
o.oioh
0.25
0.90
0.002
0.45
0.65
0.45
0.19
0.70
3.3
ND
0.038
3.8
0.050
8.2
ZK01C-3-E?
0.0202°
1.6
1.1 h
0.001
0.46
0.89
0.35
0.54
0.54
3.9 b
0.040°
0.021
4.0
0.060
8.2
Reagent
blank
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND * not detected above detection limit.
D Less than quantitation limit (5 times detection limit).
CD
-------
TABLE 49. K001-CREOSOTE AQUEOUS SAMPLES WATER QUALITY PARAMETER RESULTS
(mg/liter)
en
en
Parameter
Chloride
Total cyanide
Chemical oxygen
demand
Fluoride, SIE
Hydrogen sulfide
Nonpurgeable
organic carbon
Purgeable organic
carbon
Total dissolved
solids
Total organic
hal ides
pH (pH units)
Quanti-
tation
limit
5
0.25
25
0.05
5
5
5
5
0.05
NAC
ZK01C-1-D1 ZK01C-1-E1 ZK01C-1-E2 ZK01C-2-E1
260
NDSa
10
NDS
NDS
3
1
860
0.15
6.8
590
NDb
25
36
1
6
2
2400
0.24
3.3
560
NDS
80
NDS
NDS
6
2
2200
0.25
3.3
770
NDS
40
NDS
NDS
8
NO
3000
0.5
3.2
ZK01C-2-E2 ZK01C-3-E1 ZK01C-3-E2
920
NDS
120
NDS
NDS
9
2
3600
0.19
3.1
920
NDS
75
NDS
NDS
11
2
3700
0.44
3.4
830
NDS
80
NDS
NDS
11
3
3400
0.23
3.2
Not determined in this sample.
b Not detected above detection limit.
c Not applicable.
-------
TABLE 50. K001-CREOSOTE WATER SAMPLES ORGANOPHOSPHOROUS
PESTICIDE RESULTS
(ug/liter)
Compound
Phorate
Sulfotepp
Disulfoton
Methyl parathion
Ethyl parathion
Famphur
Quantitation
limit
0.50
0.50
1.0
1.0
0.75
2.5
Reagent
blank
NDa
NO
ND
ND
ND
ND
ZK01C-3-E2
ND
ND
ND
ND
ND
ND
Not detected above detection limit.
86
-------
TABLE 51. K001-CREOSOTE WATER SAMPLE ORGANOCHLORINE
PESTICIDE RESULTS
(yg/liter)
Compound
Aldrin
(Alpha)-BHC
(Beta)-BHC
(Delta)BHC
(Gamma)-BHC
Cnlordane
p,p'-DDD
p.p'-DDE
p.p'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Quantitation
limit
0.15
0.10
0.15
0.15
0.10
1.0
0.30
0.15
0.30
0.15
0.15
0.15
0.15
0.30
0.10
0.15
0.15
0.80
0.50
10
10
10
10
10
10
3.0
4.0
Reagent
blank
NDa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ZK01C-3-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
a Not detected above detection limit.
87
-------
TABLE 52. K001-CREOSOTE WATER SAMPLES CHLORINATED
HERBICIDES RESULTS
(yg/liter)
Compound
2,4-D
Silvex
2,4,5-T
Dinoseb
Quantitation
limit
0.25
0.75
0.75
0.75
ZK01C-3-E2
NDa
NO
ND
ND
Reagent
blank
ND
ND
ND
ND
a Not detected above detection limit.
TABLE 53. K001-CREOSOTE WATER SAMPLES DIOXIN/FURAN RESULTS
(ng/liter)
Compound
Total TCDD
Total TCDF
Total PCDD
Total PCDF
Total HxCDD
Total HxCDF
Reagent blank
<2
<1
<2
<1
<3
<3
ZK01C-3-E2
<2
<2
<2
<2
<5
<5
-------
EFFECTIVENESS OF TREATMENT
K001-PCP
The CRF rotary kiln incinerator appeared to operate normally during the
K001-PCP test. The K001-PCP waste used for the CRF test contained the expect-
ed levels of various analytes typically found in bottom sediment sludges of
wastewaters from wood-preserving processes in which PCP is used. The PCP
concentrations in the feed samples ranged from 920 to 3000 ppm. The feed
samples also contained fairly high levels (ranging up to 50,000 ppm) of
PNA's. No BDAT-list volatiles or semivolatiles were detected above the
quantitation limit in the ash, ash TCLP, and scrubber water samples. Also,
no BDAT-list dioxins or furans were detected above the method detection limit
in any of the K001-PCP samples.
Arsenic (up to 0.8 ppm), barium (up to 74 ppm), chromium (up to 8.2
ppm), copper (up to 6.8 ppm), lead (up to 5.2 ppm), and zinc (up to 11 ppm)
were the BDAT-list metals found above the quantitation limit in the ash.
Only lead (0.021 yg/ml in one sample) and zinc (0.03 yg/ml in one sample)
were detected above the quantitation limit in the TCLP extracts. In the
scrubber water samples, arsenic, barium, copper, lead, and zinc were detected
above the quantitation limit.
The methods and results of the atmospheric emission tests are presented
in Section 6. A brief summary is presented here to add perspective to the
preceding analytical results. Atmospheric emission test results during the
K001-PCP test burn suggest that this waste can be incinerated in compliance
with the incinerator regulations governing the destruction and removal effi-
ciency (DRE) of POHC's.g Eleven POHC's were designated for the waste--PCP
and 10 PNA compounds. For both tests DRE's were greater than 99.99 percent
for 10 of the 11 POHC's. DRE's for the eleventh POHC (naphthalene for one
test and acenaphthylene for the other) were 99.984 percent.6
KOOl-Creosote
The John Zink rotary kiln incineration system appeared to operate nor-
mally during the KOOl-creosote test. The KOOl-creosote (K001-C) waste used
for the test contained the expected levels of various analytes typically
found in bottom sediment sludges of wastewaters from wood-preserving
processes in which creosote is used. BDAT-list volatiles detected in the
K001-C feed above the quantitation limits were benzene (up to 83 yg/g) and
toluene (up to 170 yg/g). The BDAT-list semivolatiles analyses for the feed
samples showed several polynuclear aromatic hydrocarbons and phenols typical
of creosote waste. Naphthalene, for example, was present in concentrations
up to 43,000 yg/g, and anthracene, fluoranthene, fluorene, phenanthrene, and
pyrene were all present in concentrations exceeding 10,000 yg/g. With one
exception, no BDAT-list volatiles or semivolatiles were detected above 5
times the quantitation limit in the ash, ash TCLP, or scrubber water samples.
One ash sample contained 0.93 yg/g of di-n-butylphthalate.
89
-------
Barium (up to 150 ppm), copper (up to 39 ppm), lead (up to 190 ppm), and
zinc (up to 200 ppm) were the major BDAT-list metals found in the feed sam-
ples. The ash contained arsenic, barium, chromium, copper, selenium, vanadi-
um, and zinc above the quantisation limit, but the TCLP extracts contained
only barium and zinc above the quantisation limit (both were less than 1 mg/
liter). In the scrubber water samples, lead (up to 5.4 mg/liter), thallium
(up to 4.0 mg/liter), and zinc (up to 11 mg/liter) were the major metals
present.
No BDAT-list organophosphorous pesticides, organochlorine pesticides,
PCB's, organochlorine herbicides, dioxins, or furans were detected above the
method detection limit in any of the K001-C samples.
Atmospheric emission test results during the K001-C test burn suggest
that this waste can be incinerated in compliance with the incinerator regula-
tions governing POHC ORE. Anthracene, acenaphthene, naphthalene, phenan-
threne, and fluroanthene were designated as POHCs during the test. For all
three emission tests, DRE's were greater than 99.99 percent for the five
POHC's.
90
-------
SECTION 5
SAMPLING AND ANALYTICAL PROBLEMS AND CORRECTIVE ACTIONS
GENERAL QUALITY ASSURANCE CONCERNS
Site-specific QAPP's were developed for the K001-PCP test burn at the
U.S. EPA CRF and the KOOl-creosote test burn at the John Zink facility. The
QAPP for the K001-PCP burn was entitled "Site Test Plan and Quality Assurance
Project Plan for the Combustion Research Facility Test Burn of K001." A two-
part QAPP was prepared prior to the KOOl-creosote test burns. This QAPP was
entitled "Site Test Plan and Quality Assurance Project Plan - Part A: Incin-
eration Tests of K001 and K015 at the John Zink Company Test Facility" and
"Part B: Emission Testing." These QAPP's were approved by the HWERL Quality
Assurance Officer before the tests. Each Site Test Plan (STP) was prepared
in accordance with HWERL QAPP requirements and OSW protocols as documented in
the "Generic Quality Assurance Project Plan for Land Disposal Restrictions
Program" (EPA/530-SW-87-011). Except for the deviations summarized in Ta-
ble 54, the test burns were conducted as defined in the STPks. None of the
deviations materially affect the validity of the test results. The specific
results of the analytical quality assurance procedures are provided in the
K001-PCP and KOOl-creosote OER's.
SPECIFIC SAMPLING PROBLEMS
No significant problems were encountered in the sampling of untreated
K001-PCP, KOOl-creosote, ash, or scrubber water. Differences did occur,
however, between both the number of samples taken and the analyses conducted
during the K001-PCP test burns and the KOOl-creosote and other subsequent
HUERL BOAT tests involving treatment of other RCRA wastes. These differences
are summarized in the following paragraphs.
A total of four samples of untreated K001-PCP were taken, one for each
of the three tests plus one sample from a drum of K001-PCP that was not
incinerated during the test burn. Three samples of ash were taken, one
during each test. Three samples of scrubber water also were taken, again one
during each test. One sample of scrubber makeup water also was taken.
Subsequent to the K001-PCP test burns, OSW required that a minimum of six
samples of each residue be collected. These six samples of treatment resi-
dues must be temporally related with samples of untreated waste fed to the
treatment unit. This procedure was followed for the KOOl-creosote test burn.
91
-------
TABLE 54. DEVIATIONS FROM THE SITE TEST PLAN/QUALITY ASSURANCE PROJECT PLAN
Activity
STP specifications
Deviations from the STP
K001-PCP
Collection
of samples
for metals
analysis
Sample
analysis
KOOl-creosote
Scrubber
water sam-
ples
K001-C
feed rate
The STP/QAPP did not
specify collection of
aliquots for metals
analysis.
The STP/QAPP specified
that SW-846, 3rd edi-
tion, would be followed
and methanol would be
used to extract vola-
tile organics.
The STP/QAPP specified
that a length of Tef-
lon tubing would be
used for the sample
cooling coil.
The STP/QAPP specified
500 Ib/h as a feed
rate.
After the test burn, it was decided
that metals in K001-PCP feed, ash,
and scrubber water would be analyzed.
These analyses were conducted on
sample aliquots that had not been
preserved (acidified) in the field.
The volatile organic determinations
were made using both tetraglyme
and methanol.
Stainless steel tubing was used in
place of Teflon. This material
provided better heat transfer and
was easier to work with.
A feed rate of 180 Ib/h K001-C feed
was used during the test periods to
comply with John link's 3 million
Btu/h permit limitation. The K001-C
feed used had a significantly higher
heat content (10,000 to 11,000 Btu/lb
instead of 2000 to 4000 Btu/lb) than
was anticipated when the STP/QAPP
was written.
"Site Test Plan and Quality Assurance Project Plan for the Combustion
Research Facility Test Burn on K001" and "Site Test Plan/Quality Assur-
ance Project Plan for Incineration of K001-C at the John Zink Test
Facility."
92
-------
K001-PCP
The untreated K001-PCP, ash, and scrubber water were analyzed for the
constituents indicated in Table 4 and as specified in the STP/QAPP. Subse-
quent to the K001-PCP test burns, OSW required that at least one sample of
each untreated waste and treatment residue(s) be analyzed for each compound
on the BOAT list. The analysis of the remaining five samples of each mate-
rial could be limited to those classes of compounds reasonably expected to.be
present.
Flue gas emissions were measured during two of the three CRF incinera-
tion tests. Elevated levels of several phthalate compounds were found in the
scrubber discharge flue gas during both tests. The most common phthalate
found was bis(2-ethylhexyl)phthalate, which was measured in the scrubber
discharge flue gas at levels up to 540 yg/dscm. Butyl benzyl phthalate was
also measured in the scrubber discharge flue gas for both tests at levels up
to 14 yg/dscm. Dimethyl phthalate was present in the scrubber discharge flue
gas at levels up to 18 yg/dscm, and di-n-octylphthalate was measured in the
Test 2 scrubber discharge flue gas at 19 yg/dscm. Because these compounds
were not present in any of the feed samples at the detection limit of
.100 yg/g, their presence as an undestroyed feed organic is not likely.
The most logical explanation for the high concentrations of phthalates
found in the flue gas samples is that the packed-tower scrubber and much of
the ductwork between the scrubber and the scrubber-discharge flue gas samp-
ling location were replaced before the K001-PCP tests. The-new scrubber and
ductwork are made of fiber-reinforced plastic, which contains phthalate
plasticizers in the binder resin. The'levels measured in flue gas samples
for these tests were likely the result of the new scrubber and ductwork
installed.
No particulate data were obtained for the second emission test. Upon
recovery of the individual sample fractions, rupture of the filter support
was noted, which allowed particulate matter to get into the back half of the
sampling train, particularly the resin trap. Because an undeterminable
amount of particulate was Tost, no attempt was made to analyze this sample;
however, semivolatile organic and HC1 emissions data were collected during
this run.
KOOl-Creosote
No unusual sampling problems were encountered during the KOOl-creosote
tests at the John Zink test facility.
RESULTS OF QUALITY ASSURANCE ANALYSES
K001-PCP
Volatile Organic Analyses-
All volatile organic compounds in the untreated K001-PCP, ash, and
scrubber water samples were analyzed in accordance with the procedures speci-
fied in'Method 8240 of SW-846, 3rd edition, with one exception—tetraglyme
93
-------
was used instead of methanol.19 When this discrepancy became known, methanol
extracts of K001-PCP feed samples were conducted, and the results compared
favorably. The results of these two tests are presented in the data in
Tables 7 and 8 in Section 4.
Recoveries of surrogate compounds were within acceptable QA/QC limits
with the exception of toluene-d8 in Sample CK01P-3-B1 (118% vs. 117%), and
1,2-dischloroethane-d^ in Sample CK01P-3-D1 (118% vs. 114%). The results of
the matrix spike/matrix spike duplicate (MS/MSD) were within QA/QC limits and
the analysis of laboratory blanks showed no significant contamination.
Semivolatile Extracts--
All semivolatiles extracts were analyzed in accordance with the QA/QC
procedures outlined in Method 8270 SW-846, 3rd edition, without significant
modification. Recoveries of surrogates and the results of the MS/MSD analy-
sis were within acceptable QA/QC limits. The analysis of the laboratory
blanks showed no significant contamination.
Metals and Water Quality Parameters
All samples were analyzed in accordance with the procedures outlined in
the QA/QC plan. The relative percent difference between the matrix spike and
the matrix spike duplicate was less than 20 percent for all elements except
arsenic and zinc. The recoveries for arsenic were 73 and 42 percent, respec-
tively; whereas the respective zinc recoveries were 46 and 9 percent. Other
parameters (instrument checks, calibration check samples) were within range
for these analyses, which indicates a matrix effect to be the cause of these
low anomalies. No contamination was observed in the laboratory blanks.
Dioxin/Furan Samples
The dioxin/furan samples were analyzed in accordance with the QA/QC pro-
cedures outlined in SW-846 Method 8280, 3rd edition. Extraction efficiencies
of surrogates were within acceptable limits, and no contamination was ob-
served in the reagent blanks.
KOOl-Creosote
Volatile Organic Analyses--
The volatile samples were analyzed in accordance with the QA/QC pro-
cedures outlined in Method 8240 SW-846, 3rd edition. Recoveries of the
surrogate compounds were all within acceptable limits with the exception of
toluene-d? in three out of six of the feed samples. All MS/MSD compounds
were within Method 8240 recovery limits, and no significant contamination was
observed in system blanks.
Semivolatile Extracts--
All semivolatile extracts were analyzed in accordance with the QA/QC
procedures outlined in Method 8270 SW-846, 3rd edition, without significant
modification. All surrogate recovery values for KOOl-creosote waste feed
samples were within acceptable limits. The surrogate recovery values for
several ash and scrubber water samples were outside acceptable limits (see QA
Section of the original analysis results in Appendix E, Radian KOOl-creosote
94
-------
analytical report). For those samples that had recovery values outside these
limits, the reported concentrations for the analytes should be considered
estimates. The MS/MSD's were performed for one ash (ZK01C-3-B2) and one
scrubber water (ZK01C-3-E2) sample. Several matrix-spike relative percent
differences (RPD's) and recoveries were not within acceptance limits (Appen-
dix E). For those samples that had recovery values outside these limits, the
reported concentrations for the analytes should be considered estimates. At
least one extraction blank was generated for each sample set. A leachate and
reagent blank were generated for TCLP samples. Phthalates and phenol were
the only target analytes observed in the blanks.
All samples were analyzed in accordance with the QA/QC procedures (Ap-
pendix E). Duplicate matrix spike analyses data on ash and scrubber water
samples showed many of the analytes were outside of the recovery acceptance
criteria, which could be indicative of matrix interferences. In some in-
stances, the recoveries were not determined because of a low-level spike into
a sample containing much greater amounts of that analyte. The small amount
spiked was within the variability of the analysis and could not be reproduc-
ibly determined. Distilled water blanks and reagent blanks showed no levels
detected at a concentration greater than 5 times the instrument detection
limits.
Instrument Calibration and Tuning
The extracted samples were analyzed in accordance with the QA/QC proce-
dures outlined in Method 8140 SW-846, 3rd edition. All surrogate recoveries
were within acceptable QA/QC limits, with the exception of the feed samples.
A low surrogate recovery for the water sample was due to a loss during sample
concentration. Duplicate matrix spike analyses for feed, ash, and scrubber
water samples showed several compound recoveries outside the limits in the
QAPP.
The extracted samples were analyzed in accordance with the QA/QC proce-
dures outlined in Method 8080 SW-846, 3rd edition. Even though some varia-
tion was noted in the surrogate recoveries, all were above 50 percent and
most were within acceptable limits. A feed surrogate recovery of 121 percent
indicates a matrix interference. Matrix spike recoveries were within accept-
able limits, and no significant contamination was observed in the reagent and
extraction blanks.
The extracted samples were analyzed in accordance with the QA/QC proce-
dures outlined in Method 8150 SW-846, 3rd edition. The surrogate recovery
was outside acceptable limits on the ash sample, but within the QAPP limits
on the feed and water samples. Duplicate matrix spike analysis was performed
on a sample from the water and the ash matrix. Low recoveries and large
RPD's were observed in the ash samples because of the polarity of the matrix.
No significant contamination was noted in the analysis of the reagent and
extraction blanks.
The dioxin/furan samples were analyzed in accordance with the QA/QC pro-
cedures outlined in SW-846 Method 8280, 3rd edition. Extraction efficiencies
95
-------
were monitored by spiking each sample with 13C-labeled surrogates prior to
extraction. Surrogate compounds were not recovered from the feed samples
because of the large dilution necessary to obtain adequate peak shape and
resolution.
ATMOSPHERIC EMISSION TESTS
K001-PCP (U.S. Combustion Research Facility)
Sampling--
All of the sampling quality assurance objectives were met with one
exception—the desired total number of samples was not achieved because of
time constraints. Only two particulate and POHC determination tests were run
(instead of three). No HC1 tests were performed. Historically, the CRF has
been in compliance with the HC1 emission requirements for incinerators.
Quality assurance procedures were followed to assess the data quality of
the volatile and semivolatile hazardous constituents in the flue gas samples.
The data quality objectives (DQO's) for volatiles matrix spike recoveries
were met. In addition to matrix spike sample analyses, all volatile organic
sampling train (VOST) Tenax traps were spiked with the surrogates isooctane
and octane prior to analysis, and the surrogate recovery was measured. The
recovery DQO of 50 to 200 percent was met for 10 of 14 measurements for
isooctane (or 71 percent) and for all octane measurements (or 100 percent).
The completeness DQO was 90 percent; therefore, this DQO was met for octane
recovery for this data set, but not for isooctane recovery.
For semivolatiles QA, all modified Method 5 (MM5) train samples subject-
ed to extraction were spiked with 20 vg of each of the surrogate compounds
octaflurobiphenyl and 9-phenylanthracene. Surrogate recoveries were measured
in all extract analyses. The recovery DQO for this measurement is 50 to 200
percent recovery. All octafluorobiphenyl recoveries were within this range;
no 9-phenylanthracene recovery was within this range. Measurement complete-
ness was, thus, 50 percent compared to a completeness DQO of 90 percent.
A more complete QA discussion of the K001-PCP is included as Section 7
of Reference 6 (Appendix D of this report).
KOOl-Creosote (John Zink Test Facility)
Sampling—
All of the sampling quality assurance objectives were met with one
exception—no particulate data were obtained for the second emission test
because a ruptured filter support allowed particulate matter into the back
half of the sampling train, which caused an undeterminable amount of partic-
ulate to be lost.
Analysis--
Emission tests were run for particulate, HC1, semivolatile organics
(POHC's), and metals. For particulate and HC1, all QA objectives were met
96
-------
except for a low matrix spike recovery (45 percent) for HC1. This low recov-
ery indicates a possible matrix effect on the samples. The replicate analy-
sis and standard reference sample (SRS) data were within expected ranges.
The surrogate recovery data for semivolatiles were within the acceptable re-
covery limits specified by the method. One set of independent reference
standards data was generated in duplicate to verify the calibration for
analyzing these samples. These values were all within ± 20 percent, which is
acceptable according to Method 8270. The blank train data showed that no
sample contamination problems were encountered. Quality assurance for metals
included matrix spike recoveries, duplicate analyses, and filter/reagent
blank data.
A more complete QA discussion of the KOOl-creosote test burn is included
as Section 3 of Reference 16 (Appendix E of this report).
97
-------
SECTION 6
OTHER RESULTS
ATMOSPHERIC EMISSION TESTS
As part of the waste-destruction-technology evaluation, selected atmos-
pheric emissions were measured. These measurements would typically be made
as part of a trial burn test under the Resource Conservation and Recovery Act
(RCRA) requirements. During the K001-PCP test burn at the CRF, emission
tests were performed for total particulate and selected volatile and semi vol-
atile organic hazardous constituents. During the KOOl-creosote test burn at
John Zink, emission tests were performed for total particulate, HC1, and
selected semivolatile hazardous constituents (POHC's).
The complete atmospheric emission test results for K001-PCP are pre-
sented in the Acurex Corporation report entitled "Pilot-Scale Incineration
Tests of Wastewater Treatment Sludge From Pentachlorophenol Wood Preserving
Processes (K001)." This report is presented in Appendix B. "
The complete atmospheric emission test results for KOOl-creosote are
presented in the PEI Associates, Inc., report entitled "Emission Test Report
- Incineration Tests of K001 (Creosote) at the John Zink Company Test
Facility." This report is presented in Appendix F.
SUMMARY OF RESULTS
K001-PCP
Tables 55 and 56 present the results of the two atmospheric emissions
tests for volatile organic constituents and semivolatile organic hazardous
constituents, respectively. Table 57 summarizes the operating conditions of
the scrubber air-pollution-control system. Particulate emissions were not
measured at the scrubber discharge; instead, they were measured in the stack
downstream of the carbon bed and HEPA filter for compliance with State permit
requirements.
The VOST sampling was performed to determine the concentrations of
volatile organic compounds in the scrubber discharge flue gas. The samples
were analyzed by GC/FID for the 23 compounds listed in Table 58. As shown in
Table 55, chloroform, 1,2-dichloroethane, and benzene were present in one or
98
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TABLE 55. VOLATILE ORGANIC CONSTITUENTS IN THE SCRUBBER
DISCHARGE FLUE GAS
Concentration, pg/dscm
Test 1 (6-26-87)
Compound
Methylene chloride
Chloroform
1,2-Dichloroethane
Benzene
All others
1st
trap
pair
480
<9.4
<6.7
17
<3.9
to
<21
2nd
trap
pair
1,100
22
22
40
<4.8
to
<23
Average
790
16
14
29
<23
Test 2
1st
trap
pair
220
<9.4
48
12
<4.1
to
<22
2nd
trap
pair
330
<8.9
34
31
<3.7
to
<20
(7-1-87)
3rd
trap
pair
770
17
37
37
<4.0
to
<22
Average
440
12
40
27
<22
Average assumes "<" values present at the corresponding detection limit.
99
-------
TABLE 56. SEMI VOLATILE ORGANIC HAZARDOUS CONSTITUENTS IN FLUE GAS SAMPLES
Concentration, pg/dscm
Scrubber discharge
flue gas Stack gas
Test 1 Test 2 Test 1 Test 2
Compound (6-26-87) (7-1-87) (6-26-87) (7-1-87)
POHCs
Acenaphthene <1.0 <1.0 <1.0 <1.0
Acenaphthylene <1.0 <4.0 <1.0 <1.0
Anthracene <1.0 1.9 <1.0 <1.0
Benzo(a)anthracene <1.0 4.0 <1.0 <1.0
Chrysene <1.0 4.8 <1.0 <1.0
Fluoranthene 3.4 10 <1.0 <1.0
Fluorene <1.0 <1.0 <1.0 <1.0
Naphthalene 74 5.9 16 16
Phenanthrene 31 <1.0 0.74 <1.0
Pyrene 14 8.1 <1.0 <1.0
Pentachlorophenol <1.0 <1.0 <1,0 <1.0
Other semivolatile organic
hazardous constituents
2,4-Dimethylphenol 15 <1.0 <1.0 <1.0
Phthalates:
Bis(2-ethylhexyl)phthalate 300 540 110 59
Butyl benzyl phthalate 14 4.4 2.2 3.8
Dimethyl phthalate 18 9.4 <1.0 <1.0
Di-n-octylphthalate <1.0 19 <1.0 <1.0
All other 8270 constituents <1.0 <1.0 <1.0 <1.0
100
-------
TABLE 57. K001-PCP TEST OPERATING CONDITIONS: AIR-POLLUTION-CONTROL SYSTEM
Parameter
Test start time
Test stop time
Test duration, h
Venturi scrubber liquor flow rate, liters/min
(gal/min)
Venturi scrubber pressure drop, kPa (in.WC)
Packed tower scrubber liquor flow rate,
liters/min (gal/min)
Average makeup rate, liters/min (gal/min)
Average blowdown rate, liters/min (gal/min)
Stack gas 02, %
Range
Average
Stack gas C02, %
Range
Average
Test 1
(6-26-87)
1620
2020
4.0
64
(17)
_ _
114
(30)
17
(4.4)
5.7
(1.5)
8.0-11.0
9.0
5.0-7.2
6.0
Test 2
(7-1-87)
0930
1430
5.0
64
(17)
6.2
(25)
114
(30)
16
(4.3)
5.7
(1.5)
10.5-14.5
12.0
5.4-8.0
6.2
TABLE 58. VOLATILE ORGANIC COMPOUNDS SOUGHT IN THE K001-PCP
TEST SAMPLE ANALYSES
Compound Compound
Methylene chloride Benzene
1,1-Dichloroethene 1,1,2-Trichloroethane
1,1-Dichloroethane Hexane
t-l,2-Dichloroethane Bromoform
Chloroform Tetrachloroethene + tetrachloroethane
1,2-Dichloroethane Toluene
1,1,1-Trlchloroethane Chlorobenzene
Carbon tetrachloride Ethylbenzene
Bromodichloromethane 1,3-Dichlorobenzene
1,2-Dichloropropane 1,2-Dichlorobenzene
t-l,3-Dichloropropane 1,4-Dichlorobenzene
Trichloroethylene
101
-------
more scrubber-discharge flue gas samples at levels generally in the 10- to
40-yg/dscm range. These compounds are measured products of incomplete com-
bustion (PIC's) routinely detected in combustion source flue gas in a range
of 1 to several tens of ug/dscm, as found in these tests.
The MM5 sampling was performed to determine the concentrations of semi-
volatile organic hazardous constituents in the scrubber discharge flue gas.
The samples were analyzed for the semivolatile organic hazardous constituents
listed in Table 59 by GC/MS, in accordance with EPA Method 8270.
As shown in Table 56, several of the PNA POHC's were present in the
scrubber-discharge flue gas during both tests, at levels up to several tens
of ug/dscm. The POHC concentrations in the scrubber discharge flue gas were
roughly comparable during both tests. Naphthalene and phenanthrene levels
were somewhat higher during Test 1. In contrast, acenaphthylene, anthracene,
benzo(a)anthracene, chrysene, and fluoranthene levels were higher during
Test 2.
In addition to the PNA POHC's, several phthalate compounds were present
in the scrubber-discharge flue gas. The most commonly found phthalate was
bis(2-ethylhexyl)phthalate, which was measured in the scrubber discharge flue
gas at levels up to 540 yg/dscm. Butyl benzyl phthalate was also measured in
the scrubber-discharge flue gas during both tests, at levels up to 14 ug/dscm.
Dimethyl phthalate was present in the scrubber-discharge flue gas at levels
up to 18 ug/dscm, and di-n-octylphthalate was measured in the Test 2 scrubber
discharge flue gas at 19 ug/dscm.
Phthalates are universal laboratory contaminants routinely found in
Method 8270 sample extracts; however, the levels shown in Table 56 are higher
than those usually ascribed to laboratory contamination. This indicates that
these compounds were probably present in the flue gas at the elevated levels
measured in these tests. Because the compounds were not present in any of
the feed samples at a detection limit of 100 yg/g, their presence as an unde-
stroyed feed organic is not likely. The most logical explanation for the
high concentrations of phthalates found in the flue gas samples is that the
packed-tower scrubber and much of the ductwork between the scrubber and the
scrubber-discharge flue gas sampling location were replaced before the
K001-PCP tests. The new scrubber and ductwork are made of fiber-reinforced
plastic, which contains phthalate plasticizers in the binder resin. The
levels measured in flue gas samples for these tests might well have resulted
from the new scrubber and ductwork.
KOOl-Creosote
Table 61 summarizes the critical emission parameters for the KOOl-creo-
sote test burns at the John Zink facility. Briefly, these data show the
following:
Particulate concentrations corrected to 7 percent 02 were below the
RCRA allowable limit of 0.08 grain per dry standard cubic foot
(gr/dscf).
102
-------
TABLE 59. SEMIVOLATILE ORGANIC COMPOUNDS SOUGHT IN THE
K001-PCP TEST SAMPLE ANALYSES
Compound
Compound
N-Nitrosodimethylamine
Phenol
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Bis(2-chloroisopropyl)ethyl
N-Nitroso-di-n-propylamine
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Hexachlorobutadiene
4-Chloro-3-methyl phenol
1,4,6-Trichlorophenol
2-Chloronapththalene
Dimethyl phthalate
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
Fluorene
4,5-Dinitro-2-methylphenol
Diphenylamine
N-Nitrosodiphenylamine
Azobenzene
1,2-Diphenyl hydrazine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Disulfoton
Di-n-butyl phthalate
Fluoranthene
Benzidine
Pyrene
Butyl benzyl phthalate
Bis(2-ethylhexyl)phthalate
Di-n-octyl phthalate
Benzo(b)fluoranthene
Benzo(k)f1uoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Benzo(g,h,i)perylene
103
-------
0 Measured HC1 emission rates in pounds per hour were considerably
less than the RCRA allowable of 4.0 Ib/h.
0 The average secondary combustion chamber concentration of CO was
less than 30 ppm during each test.
0 The ORE performance standard of 99.99 percent was achieved for the
designated semivolatile analytes.
Table 62 summarizes the sampling and analytical methods used in this
test program. Samples were collected after the venturi scrubbing system to
determine the concentrations and mass emission rates of the pollutants listed
in Table 61. Stack samples for determining semivolatile organics were col-
lected on XAD-2 sorbent. The XAD-2, filter, and probe rinse residues were
solvent-extracted, and the concentrated extracts were analyzed by gas GC/MS
(M8270-SW-846).
104
-------
TABLE 60. POHC DRE's FOR THE K001-PCP TEST BURN
DRE, percent
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
Pentachlorophenol
Scrubber discharge
flue gas
Stack gas
Compound
Test 1
(6-26-87)
Test 2
(7-1-87)
Test 1
(6-26-87)
Test 2
(7-1-87)
>99.99967
>99.9935
>99.99969
>99.9986
>99.9972
99.9989
>99.99961
99.984
99.9958
99.9915
>99.99989
>99.99979
99.9844
99.99945
99.9931
99.9955
99.9973
>99.99974
99.9981
>99.99991
99.9965
>99.99994
>99.9S958
>99.9918
>99.99961
>99.9982
>99.9964
>99.99958
>99.99951
99.9957
99.99987
>99.99923
>99.99986
>99.99975
>99.9954
>99.99966
>99.9980
>99.9989
>99.99968
>99.99970
99.9937
>99.99989
>99.99949
>99.99994
105
-------
TABLE 61. RESULTS FOR CRITICAL EMISSION PARAMETERS FOR THE
K001-CREOSOTE TEST BURN
Parameter
Test date (1987)
Test time (24-h)
Feed rate, Ib/h
Analyte feed rate, Ib/h
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
Exhaust data data
Volumetric flow, dscfm
02. %a
C02, %a
CO, ppm (dry)b
Particulate concentration,
gr/dscf at 7% 02
Emission rate, Ib/h
Particulate
HC1
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
ORE, %c
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
a Values determined from Orsat
1
10/6
1210-1526
180
2.0
3.2
7.4
6.6
4.3
1596
8.95
8.10
31
0.027
0.32
0.11
<3.7 x 10"5
<3.7 x 10"5
<3.7 x 10"5
<3.7 x 10"5
<3.7 x 10"5
>99.99
>99.99
>99.99
>99.99
>99.99
analysis of
CO values determined from CEM located at
chamber.
c nnr _ Ib/h (in) - Ib/h (out)
v inn
Test No.
2
10/6
1713-2024
180
1.8
3.2
6.5
5.9
4.1
1637
8.95
8.10
38
_
-
0.12
<3.7 x 10"5 <3
<3.7 x 10"5 <3
<3.7 x 10"5 <3
<3.7 x 10"5 <3
<3.7 x 10"5 <3
>99.99
>99.99
>99.99
>99.99
>99.99
integrated bag
3
10/7
1155-1458
180
1.4
3.2
6.5
6.1
4.1
1555
8.35
8.95
18
0.029
0.34
0.05
.7 x 10"5
.7 x 10"5
.7 x 10"5
.7 x 10"5
.7 x 10"5
>99.99
>99.99
>99.99
>99.99
>99.99
samples.
Average
180
1.7
3.2
6.8
6.2
4.2
1596
8.75
8.38
29
0.028
0.33
0.09
_
_
_
_
*,
„
_
.
_
-
outlet of secondary combustion
Ib/Min)
106
-------
TABLE 62. SUMMARY OF SAMPLE AND ANALYTICAL PROCEDURES
FOR K001-CREOSOTE TEST BURN
Sample
identification
Stack gas (after
venturi scrubber
system)
Parameter
POHC's
(phenanthrene,
anthracene,
naphthalene,
acenaphthene,
fluoranthene)
Sample
method
MM5a
Analytical
method
SW 846-8270b
(GC/MS)
Number
of samples
3
Particulate EPA 5
HC1 EPA 5
BDAT-list metals EPA 12
Volumetric gas EPA 1-4
flow, temperature,
moisture content,
composition (02,
C02)
EPA 5 (gravi-
metric)
EPA 300.Oc
(ion chroma-
tography)
SW 846b
(ICP/AA)
2
3
Secondary com-
bustion chamber
(outlet)
CO
02
C02
Gas temperature
EPA 10
EPA 3A
EPA 3A
Thermo-
couple/
digital
readout
NDIR
Zirconium
cell
NDIR
-
Continuous
Continuous
Continuous
Continuous
a Sampling and Analysis Methods for Hazardous Waste Combustion, Method S008,
EPA-600/8-84-02, February 1984; and Laboratory and Field Evaluation of the
Semi-VOST Method, EPA-600/4-85-075.
b Test Methods for Evaluating Solid Wastes. Physical/Chemical Methods, EPA
SW 846, 3rd Edition. November 1986.
c Methods for Chemical Analysis of Water and Wastes. EPA-600/4-79-020, 1979.
107
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Tables 63 and 64 summarize the particulate and HC1 emissions data from
this test program. Concentrations are expressed in grains per dry standard
cubic foot and mass emission rate data,-in pounds per hour. Test times for
these runs were 180 minutes.
TABLE 63. SUMMARY OF PARTICULATE EMISSION DATA
FROM K001-CREOSOTE TEST BURN
Concentration
Run No.
KO-SV-1
KO-SV-2*
KO-SV-3
gr/dscf
0.023
-
0.026
gr/dscf at 7% 02
0.027
-
0.029
Mass emission
rate, Ib/h
0.32
-
0.34
a Particulate not determined.
TABLE 64. SUMMARY OF HC1 EMISSION DATA FROM K001-CREOSOTE TEST BURN
Run No. Concentration, gr/dscf
KO-SV-1
KO-SV-2
KO-SV-3
0.008
0.008
0.004
Mass emission rate, Ib/h
0.11
0.12
0.05
As noted in Table 63, no particulate data were obtained for Run KO-SV-2.
Upon recovery of the individual sample fractions, it was found that the
filter frit support had ruptured and allowed particulate matter to enter the
back half of the sample train. Because an undeterminable amount of particu-
late was lost, no attempt was made to analyze this sample. Data on semivola-
tile organics and HC1 emissions were collected during this run, however.
Particulate concentration corrected to 7 percent 02 averaged 0.028 gr/dscf
for the two available sample runs, and corresponding mass emission rates
averaged 0.33 Ib/h. The HC1 concentrations averaged 0.007 gr/dscf, with a
corresponding mass emission rate of 0.09 Ib/h.
Prior to the organics analysis, probe rinse and filter samples were
analyzed gravimetrically for particulate determination in accordance with EPA
Method 5 procedures. An aliquot from the IN sodium hydroxide (NaOH) impinger
of each MM5 sampling train was also analyzed for chloride content (as HC1) by
ion chromatography in accordance with EPA Method 300.
108
-------
Samples for metals analyses were collected by an EPA Method 12 sampling
train. This train is identical to an EPA Method 5 (participate) sampling
train except that 0.1N nitric acid (HN03) is added to the impingers and used
as the sample nozzle and probe rinse reagent.
During each test, the flow rate, temperature, moisture content, and com-
position (02 and C02) of the flue gas were measured by EPA Methods 1 through
4 procedures. Also, continuous emission monitors were used for monitoring
and continuous recording of 02, C02, and CO concentrations at the outlet of
the secondary combustion chamber during each test period. Procedures out-
lined in EPA Method 3A (02 and C02) and Method 10 (CO) were followed.
Tables 65 through 67 summarize the semivolatile organic feed, mass emis-
sion data, and the DRE's for each compound, respectively. Also included are
the method detection limits (MDL's) for the feed and stack samples. As shown
in Table 66, nondetectable levels of each analyte were observed in all stack
emission samples. A minimum detection limit of 20 micrograms per sample was
established for this set of samples. This value was used in calculating the
sample concentrations and mass emission rates for generating ORE data. Cal-
culations produced DRE's of greater than 99.99 percent for each compound,
which indicates that these compounds were effectively destroyed by the incin-
eration process. Method 8270 (GC/MS) quality control measures were applied
with acceptable results. Because all sample surrogate recoveries were within
accepted criteria of the method, no corrections were made to the sample re-
sults. Analysis of the Modified Method 5 stack samples also included analy-
sis for dibenzo furan and 2-methylnaphthalene, and both were below the method
detection limit (20 ug/sample). The feed composition analysis does not indi-
cate positive identification of these compounds; therefore, no ORE data were
developed.
Table 68 summarizes the concentration and mass emission rate data for
the BDAT-list metals. Concentrations are expressed in micrograms per dry
normal cubic meter (yg/dNm3) and mass emission rates in pounds per hour.
Cadmium, lead, and zinc were present in these samples at higher concentra-
tions (700 to 995 yg/dNm3) than were the other listed metals. Because of
probe-heat electrical problems, the three tests were run for 103, 60, and 80
minutes, respectively, to minimize condensation of water vapor on the filter
media. In two of the three tests, the filter media was observed to be wet
upon recovery. This should have a minimal effect on sample analysis because
the fractions are combined and digested prior to analysis.
STATISTICAL EVALUATION OF TEST BURN DATA
The statistical methods for establishing BOAT outlined in the Federal
Register (Vol. 51, No. 172, September 5, 1986) were used to determine data
outliers and 99 percent confidence limits. Data outside the range of a
Z-score of ±2.00, are rated as outliers.
Based on this criterion, the Z-score test outlined in the Federal Regis-
ter indicated that none of the data values can be rated as outliers.Tfie
109
-------
TABLE 65. SUMMARY OF SEMI VOLATILE ORGANIC FEED RATE DATA FROM
K001-CREOSOTE TEST BURN
Test Nos. and total feed rates
Analyte3
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
1
180 1
Concentra-
tion, %
by weight
1.1
1.8
4.1
3.6
2.4
b/h
Feed .
rate,b
Ib/h
2.0
3.2
7.4
6.6
4.3
2
180 Ib/h
Concentra-
tion, %
by weight
1.0
1.0
3.6
3.3
2.3
Feed
rate,
Ib/h
1.8
3.2
6.5
5.9
4.1
3
180 1
Concentra-
tion, %
by weight
0.8
1.8
3.6
3.4
2.3
b/h
Feed
rate,
Ib/h
1.4
3.2
6.5
6.1
4.1
Minimum detection limit, ppm
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
500
500
420
1400
5800
Analyte feed rate (Ib/h) = concentration (%) x feed rate (Ib/h).
110
-------
TABLE 66. SUMMARY OF DATA ON SEMIVOLATILE ORGANIC CONCENTRATIONS AND MASS EMISSION RATES
Test Nos. and sample volumes
1
3.19 dNm3
Analyte3
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
2
3.31 dNm3
Concentra- Mass emission Concentra- Mass
tion, pg/m3 rate, 10"5 Ib/h tion, pg/m3 rate,
a Analyte detection 1
Analyte3
Anthracene
Acenaphthene
Naphthalene
Phenanthrene
Fluoranthene
a a npF _ lb/
la LM'.C -
Feed
rate,
Ib/h
2.0
3.2
7.4
6.6
4.3
h (In) -
Ib/h
<6.3
<6.3
<6.3
<6.3
<6.3
<3.7
<3.7
<3.7
<3.7
<3.7
imit: 20-pg/sample.
TABLE 67.
1
Mass
emission
rate, 10"5 Ib/h
<3.7
<3.7
<3.7
<3.7
<3.7
Ib/h (out) _ ,,
(in) x 1(
ORE
>99
>99
>99
>99
>99
30
<6.0
<6.0
<6.0
<6.0
<6.0
3
3.14 dNm3
emission Concentra- Mass emission
10"5 Ib/h tion, pg/m3 rate, 10"5 Ib/h
<3.7 <6.4
<3.7 <6.4
<3.7 <6.4
<3.7 <6.4
<3.7 <6.4
All analytical values were less than the analyte
SUMMARY OF SEMIVOLATILE ORGANIC ORE DATA
Feed
rate
,a % Ib/h
.998 1.85
.999 3.15
.999 6.5
.999 5.9
.999 4.1
Test Nos.
2
Mass
, emission
rate, 10"5 Ib/h
<3.7
<3.7
<3.7
<3.7
<3.7
<3.7
<3.7
<3.7
<3.7
<3.7
detection limit.
3
Feed Mass
rate, emission
ORE, % Ib/h rate, 10"5 Ib/h ORE
>99.998 1.4
>99.999 3.2
>99.999 6.5
>99.999 6.1
>99.999 4.1
<3.7 >99
<3.7 >99
<3.7 >99
<3.7 >99
<3.7 >99
a „
, *
.997
.999
.999
.999
.999
-------
TABLE 68. SUMMARY OF BOAT-LIST METALS EMISSION DATA
FROM K001-CREOSOTE TEST BURN
Metals
Arsenic
Antimony
Barium
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thai! ium
Vanadium
Zinc
yg/dNm3
25.2
14.2
36.2
0.1
769.3
73.5
74.6
992.5
0.006
29.0
1.1
3.8
14.8
36.7
836.2
1
Ib/h
0.00015
0.00009
0.00022 7
4.9 x 10"'
0.005
0.0004
0.004
0.006 B
3.3 x 10"b
0.0002 f.
6.6 x 10"°
0.00002
0.00009
0.002
0.005
Run
Nos.
2
yg/dNm3
34.0
25.1
58.7
0.2
481.2
146.5
179.6
1208.3
0.009
90.5
1.8
2.6
11.5
80.4
1058.9
Ib/h
0.0002
0.00015
0.00035 ,
9.7 x 10"'
0.003
0.0009
0.001
0.007 fi
5.7 x 10"G
0.0005
0.00001
0.00002
0.00007
0.005
0.006
yg/dNm3
23.6
18.6
41.3
0.1
91.4
42.2
104.1
672.9
0.02
25.8
1.4
1.1
135.7
8.1
1073.7
3
Ib/h
0.00014
0.00011
0.00025-,
6.4 x 10"'
0.0006
0.0003
0.0006
0.004 7
1.1 x 10"'
0.0002 ,
8.3 x 10"°
6.9 x 10"°
0.0008
0.00005
0.007
112
-------
compounds detected in the K001-PCP and KOOl-creosote samples are summarized
in Tables 69 and 70; the 99 percent upper confidence limits are also speci-
fied.
NON-BDAT PARAMETERS
In addition to determining the compounds included on the BOAT list,
EPA's Hazardous Waste Engineering Research Laboratory completed analysis of
several other compounds in samples of both K001-PCP and KOOl-creosote feed,
ash, and scrubber water. These additional data were collected for EPA's
Office of Air Quality Planning and Standards (OAQPS) to assist them in their
development of air emissions regulations for TSDF's (treatment, storage, and
disposal facilities), including waste-treatment processes. Specifically,
OAQPS needed data on waste characteristics and waste handling prior to incin-
eration. Most of the OAQPS compounds are included on the BOAT list of com-
pounds; those that are not are identified separately as non-BDAT parameters
on the data tables in Section 4.
113
-------
TABLE 69. CONCENTRATION AND 99 PERCENT UPPER CONFIDENCE LIMITS
FOR COMPOUNDS DETECTED IN K001-PCP SAMPLES
Compounds
Samples
1 2 3
99% Upper
limit
K001-PCP Untreated Waste
Volatiles, ppb
Toluene
Semivolatiles, ppm
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b and/or k)fluor-
anthene
Chrysene
Fluorene
Fluoranthene
Naphthalene
Pentachlorophenol
Phenanthrene
Pyrene
Metals, ppm
Arsenic
Barium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Zinc
(continued)
16
2.9
30.0
0.
1,
6.
.5
.5
.7
10
7.8
0.11
64.0
39
13,000
9,300
940
8,200
13,000
26,000
970
28,000
9,200
18,000
13,000
3,400
940
2,300
3,600
12,000
21,000
43,000
3,000
42,000
15,000
14,000
8,500
2,500
620
1,600
9,000
15,000
37,000
920
32,000
11,000
2.3
19.0
0.6
2.7
11.0
11.0
0.16
58.0
1.1
17.0
0.4
2.1
10.0
6.3
0.064
30.0
92
22,092
17,003
a
a
4,316
15,250
28,393
63,127
6,579
54,235
20,451
6.32
42.99
0.79
4.06
16.67
15.69
0.30
125.64
114
-------
TABLE 69 (continued)
Samples
Compounds
K001-PCP Incinerator Ash
Metals, ppm
Arsenic
Barium
Chromium (total)
Copper
Lead
Zinc
K001-PCP Ash TCLP
Metals, mg/ liter
Barium
Lead
K001-PCP Scrubber Water
Metals, mg/liter
Arsenic
Barium
Chromium (total)
Copper
Lead
Mercury
Zinc
1
0.8
74
8.2
6.8
5.2
11
0.32
0.021
0.12
0.15
0.021
1.1
2
0.6
21
1.1
3
1.2
2.1
0.19
0.12
0.24
0.09
0.18
0.61
3
0.4
21
1.2
2
0.96
2.1
0.25
0.11
0.39
0.045
0.07
0.2
0.003
0.88
99% Upper
confidence
1 imit
1.30
174
31
15
15
34
0.45
a
0.89
0.24
1.76
1.68
a It is not appropriate to calculate 99 percent confidence limits for
residuals when less than three data points are available.
115
-------
TABLE 70. CONCENTRATIONS AND 99 PERCENT UPPER CONFIDENCE LIMITS FOR
COMPOUNDS DETECTED IN K001-CREOSOTE SAMPLES
Samples
Compounds 123 45
99% upper
6 limit
KOOl-Creosote Untreated Waste
Volatiles, ppb
Benzene
Toluene
Ethyl benzene
Xylenes
Semivolatiles, ppm
Acenaphthalene
Acenaphthene
Anthracene
Chrysene
Fluorene
Naphthalene
Phenanthrene
Phenol
Pyrene
Metals, ppm
Arsenic
Barium
Cadmium
Chromium (total)
Copper
Lead
21,000
15,000
4,800
18,000
42,000
41,000
2,400
17,000
1,000
15,000
7,300
4,200
12,000
40,000
32,000
3,700
13,000
19,000
12,000
4,800
16,000
40,000
37,000
3,600
16,000
16,000
8,500
4,100
14,000
32,000
29,000
3,900
12,000
19,000
7,400
4,200
16,000
29,000
32,000
2,400
15,000
17,000
9,100
4,300
14,000
43,000
36,000
3,300
13,000
23,723
18,571
5,176
20,698
54,342
45,831
5,254
19,560
2.6
63.0
3.4
5.0
35.0
170.0
58.0
3.4
4.8
32.0
160.0
2.1
70.0
3,
6,
39.0
150.0
,1
.4
2.5
59.0
2.4
7.0
39.0
110.0
0.7
12.0
0.8
1.6
12.0
37.0
,10
(continued)
-------
TABLE 70 (continued)
Compounds
Samples 99% upper
cum i ticiiCc
123 45 6 limit
Metals, ppm (cont'd)
Mercury
Nickel
Selenium
Thallium
Vanadium
Zinc
KOOl-Creosote Ash
^ Metals, ppm
--4
Arsenic
Barium
Chromium (total)
Copper
Nickel
Selenium
Vanadium
Zinc
KOOl-Creosote Ash TCLP
Metals, mg/liter
Arsenic
Barium
0.4
2.1
1.5
7.7
0.4
1.4
8.0
2.1
1.2
6.8
0.4
2.8
1.1
5.3
0.8
1.8
37.0
2.2
170.0
2.3
4.4
1.9
0.38
170.0
1.9
4.1
1.8
160.0
120.0
40.0
0.57
1.8
4.1
3.2
2.5
4.2
2.8
2.6
5.2
0.6
4.5
1.1
3.3
1.9
200.0
2.8
4.8
2.5
0.53
0.31
0.025
0.22
1.14
5.85
56
17
512
5.3
81
6.1
86
3.6
5.3
74
5.3
100
4.6
9
61
5.8
98
5
10
48
8.7
110
5.2
13
56
10
130
6.8
11
72
7.7
86
3.9
20
102
13
145
8.04
3.46
5.57
4.34
0.41
0.87
(continued)
-------
TABLE 70 (continued)
Compounds
Metals, mg/ liter (cont'd)
Cadmium
Copper
Nickel
Selenium
Vanadium
Zinc
K001 -Creosote Scrubber Water
^ Metals, mg/ liter
00
Arsenic
Barium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Nickel
Selenium
Thallium
Vanadium
Zinc
1
0.02
0.02
0.02
0.041
0.76
0.87
0.35
0.42
2.5
0.016
0.48
0.057
0.04
5
2
0.03
0.05
0.15
0.8
0.74
0.5
4.5
0.06
0.51
0.11
2.4
0.06
7.1
Samples
3
0.03
0.02
0.08
0.16
0.56
0.95
0.6
0.43
3.5
0.008
0.56
0.09
2.8
0.04
9.1
4
0.01
0.28
1
1.2
1
0.51
5.4
0.29
0.6
0.12
3.4
0.08
11
5
0.008
0.004
0.02
0.03
0.25
0.9
0.45
0.65
0.45
3.3
0.19
0.7
0.038
3.8
0.05
8.2
9'
l«U
6
0.07
0.02
0.002
1.6
1.1
0.46
0.89
0.35
3.9
0.54
0.54
0.021
4
0.06
8.2
9% upper
nfidence
limit
0.16
0.41
3.50
1.45
2.06
1.59
0.61
6.95
3.87
0.76
0.30
5.31
0.10
14.63
a It is not appropriate to calculate 99 percent confidence limits for residuals when less than three
data points are available.
-------
REFERENCES
1. PEI Associates, Inc. Site Test Plan and Quality Assurance Project Plan
on the Combustion Research Facility Test Burn of K001-. Prepared for
U.S. Environmental Protection Agency, Hazardous Waste Engineering Re-
search Laboratory, under Contract No. 68-03-3389. March 1987.
2. PEI Associates, Inc. Site Test Plan and Quality Assurance Project Plan,
Part A: Incineration Tests of K001 (Creosote) and K015 at the John link
Co. Test Facility (Revised July 10, 1987) and Part B: Atmospheric
Emission Testing (Revised July 2, 1987). Prepared for U.S. Environ-
mental Protection Agency, Hazardous Waste Engineering Research Labora-
tory, under Contract No. 68-03-3389.
3. PEI Associates, Inc. Onsite Engineering Report of Treatment Technology
Performance and Operation for Incineration of KOOl-Pentachlorophenol
(PCP) Waste at the U.S. Environmental Protection Agency Combustion
Research Facility. Prepared for U.S. Environmental Protection Agency,
Hazardous Waste Engineering Research Laboratory, under Contract No.
68-03-3389. November 12, 1987.
4. PEI Associates, Inc. Onsite Engineering Report of Treatment Technology
Performance and Operation for Incineration of KOOl-Creosote Waste at the
John link Co. Test Facility. Prepared for U.S. Environmental Protection
Agency, Hazardous Waste Engineering Research Laboratory, under Contract
No. 68-03-3389. March 1988.
5. U.S. Environmental Protection Agency. Best Demonstrated Available
Technology (BOAT) Background Document for K001. Office of Solid Waste.
EPA/530-SW-0009-0. May 1988.
6. Acurex Corporation. Pilot-Scale Incineration Tests of Wastewater Treat-
ment Sludge from Pentachlorophenol Wood Preserving Processes (K001).
Prepared for U.S. Environmental Protection Agency, Risk Reduction
Engineering Laboratory, under Contract No. 68-03-3267. October 1988.
7. U.S. Environmental Protection Agency. RCRA Listing Background Document,
Waste Code K001. 1980.
8. Myers, L. H., et al. Indicatory Fate Study. EPA OGC 2-78-179. 1978.
9. U.S. Environmental Protection Agency. Onsite Engineering Report for
KOOl-Creosote. Office of Solid Waste. November 23, 1987.
119
-------
REFERENCES (continued)
10. U.S. Environmental Protection Agency. Onsite Engineering Report for
K001-PCP. Office of Solid Waste. November 12, 1987.
11. DPRA. Data from U.S. Environmental Protection Agency, Office of Solid
Waste, Mail Survey: Generator Questionnaire, Incinerator, Land Disposal
Questionnaire. 1984.
12. Brown, K. W., and Associates. Hazardous Waste Land Treatment. 1981.
13. Acurex Corporation. Emissions and Residue Values From Waste Disposal
During Wood Preserving. 1982.
14. Mitre Corporation. Composition of Hazardous Waste Streams. 1981.
15. Illinois Environmental Protection Agency. Special Waste Authorization
File. 1983.
16. PEI Associates, Inc. Emission Test Report - Incineration Tests of K001
(Creosote) at the John Zink Company Test Facility. Prepared for U.S.
Environmental Protection Agency, Hazardous Waste Environmental Research
Laboratory, under Contract No. 68-03-3381. December 1987.
17. John Zink Company. Incineration Test Burn of K001 Creosote Waste.
Prepared for PEI Associates, Inc., under PEI Purchase Order No. PEI-87-
1399-3724-1-A. February 25, 1988.
18. Acurex Corporation. Pilot-Scale Incineration Tests of Stillbottoms From
Phthalic Anhydride Production (K024). Prepared for U.S. Environmental
Protection Agency, under Contract 68-03-3267. November 1987.
19. U.S. Environmental Protection Agency. Test Methods for Evaluating Solid
Waste. EPA/SW-846, November 1986.
120
-------
TECHNICAL HEIGHT DATA
read /ititrucnont on thr rtvtnt btfoet ccm/tlrtutfl
3. RECIPIENT'S ACCESSION MO.
I TITLE AND SUBTITLE
INCINERATION OF CREOSOTE AND PENTACHLOROPHENOL
WOOD-PRESERVING WASTE WATER TREATMENT SLUDGES
ft REPORT DATE
1989
I PERFORMING ORGANIZATION CODE
AUTNOR(S)
I PERFORMING ORGANIZATION REPORT NO
PEI ASSOCIATES, INC.
) PERFORMING ORGANIZATION MAME AND ADDRESS
11499 Chester Road
Cincinnati, Ohio 45246
10. PROGRAM ELEMENT NO.
D109
11. CONTRACT/GRANT NO
68-03-3389
12 SPONSORING AGENCY NAME AND ADDRESS
Risk Reduction Engineering Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Cincinnati, Ohio 45268
13. TYPE OF REPORT AND PERIOD COVERED
10/86 - 9/89
14. SPONSORING AGENCY CODE
EPA
IS. SUPPLEMENTARY NOTES
Project Monitor, Ronald J. Turner (513) 569-7775
16. A1STRACT
This report describes the treatment of creosote and pentachlorophenol wood
preserving wastewater treatment sludges by rotary kiln incineration (RCRA
Code K001.)
IT.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field'Cioup
Incineration
Wood-Preserving Wastes
11. DISTRIBUTION STATEMENT
EPA Fw* 2230-1 («•»• 4-77) PREVIOUS COITION it OMOLCTC
It. SECURITY CLASS
nHCLASSIFIED
21. NO. Of PACES
JO. SECURITY CLASS (THUf»ltl
22. PRICE
------- |