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                                   TECHNICAL REPORT DATA
                            (ftettt rt*d Irutructtoni on tht rtrtrte At/err tonpltting)
1. REPORT NO.

  EPA/600/3-88/058
                              a.
               RECIPIENT'S ACCES&IOK"f^ £»!•'*
               PB89   1 ET9 8 5 6/AS
4. TITLE AND SUBTITLE
 Application Guide  for the Source PM-10 Exhaust Gas
 Recycle Sampling System
                                                            B. Mf PONT DATE
                                                                April 1989
             •. PERFORMING ORGANISATION CODE
7. AUTHOR(S)
  Randal S. Martin,  S.S.  Oawes, A.O. Williamson,
  H.E.  Farthing
                                                            I. PERFORMING ORGANIZATION REPORT NO.
B. PERFORMING ORGANIZATION NAME ANO AOORESS
 •
 Southern Research  Institute
 Birmingham, AL 35255
                                                            10. PROGRAM ELEMENT NO.
             11. CONTRACT/GRANT NO.
                                                              68-02-4442
12. SPONSORING AGENCY NAME ANO AOORESS
 Atmospheric Research and Exposure Assessment Laboratory
 Office of Research  and Development
 U.S.  Environmental  Protection Agency
 Research Triangle Park, NC 27711
              13. TYPE Of REPORT ANO PERIOD COVERED
             14. SPONSORING AGENCY CODE


                EPA/600/09
15. SUPPLEMENTARY NOTES
1C ABSTRACT
       This document describes assembly,  operation, and maintenance of the Exhaust Gas
 Recycle (EGR) sampling system.  The design of the sampling  train allows the operator
 to maintain a constant flow rate through an 1nert1a1 sampler while the gas flow rate
 into the sampling nozzle 1s adjusted  to remain isokinetic with the local duct  velocity
 This manual specifically addresses the  operation of the EGR system for determination
 of stationary source  PM-10 emissions.   Material 1n tho text includes:" construction
 details, calibration  procedures, presampling calculations,  sample retrieval, data
 reduction, and equipment maintenance.
17.
                                KEY WORDS ANO DOCUMENT ANALYSIS
                  DESCRIPTOR*
b.lOENTIPIERS/OPSN ENOEO TERMS  C.  COSATI Field/Group
1S. DISTRIBUTION STATEMENT
 Release to Public
IS. SECURITY CLASC (T*U Rrporll
 Unclassified
                                                                          21. NO. Or PAGES
                                               30. SECURITY CLASS (Thltptftj^
                                                Unclassified
                                                                          M. PRICE
If A Mm 2220.1 («•». 4-77)   »R«VIO«M S.OITIOM i* OMOLC

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                     DISCLAIMER AND  PEER REVIEW NOTICE
     The information in this document has been  funded wholly or  in  part by
the Onit»d States Environmental  Protection Agency under contract 68-02-4442
to Southern Research Institute.   It has been subjected to  the Agency's  peer
and administrative review, and it has been approved  for publication as  an
EPA document.  Mention of trade  names or commercial  products does not
constitute endorsement or recommendation for use.
                                       ii

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                                    FOREWORD
     Measurement and monitoring  research efforts  are  designed  to anticipate
environmental problems, to  support  regulatory  actions by developing  ait
in-depth understanding of the nature  and processes  that  impact  health  and  the
ecology/ to provide innovative means  of monitoring  compliance  with regula-
tions, and to evaluate the  effectiveness of health  and environmental protec-
tion efforts through the monitoring ot" long-term  trends.   The Atmospheric
Research and Exposure Assessment Laboratory, Research Triangle  Park, North
Carolina, has responsibility fort   assessment  of  environmental  monitoring
technology and systems for  air,  implementation of agency-wide quality  assur-
ance programs for air pollution measurement systems,  and  supplying technical
support to other groups in  the Agency including the Office of Air and
Radiation, the Office of Toxic Substances, and the Office of Solid Waste.

     The environmental effects of PM1(J particulate matter  are of concern to
the Agency.  Acceptable measurement methodology is critical for  proper  assess-
ment of the impact on the environment of these emissions  from stationary
sources.  Preparation of a manual which specifies measurement procedures is a
key component for assuring  reliable test data.  This  manual was  prepared to
describe the construction, maintenance, and operating procedures tor the
Exhaust Gas Recycle approach for measurement of PM1Q  emissions  from stationary
sources.
                      •
                      Gary J. Foley
                      Acting Director
                      Ataospheric Research and Exposure Assessment Laboratory
                      Research Triangle Pane,  North Carolina  27711
                                    iii

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                                    ABSTRACT
     This report describes  assembly,  operation,  and maintenance of the Exhaust
Gas Recycle  (EGR)  sampling  train.   Although the  potential  us»s of this system
are numerous, this manual specifically addresses the operation of the ZGR
train for the determination of  stationary source PM10  emissions.  The design
of the EGR system  allows the operator to maintain a preselected constant flow
rate through an inertial sampler while the gas flow rate  into the sampling
nozzle is adjusted at each  traverse point to remain isokim*tic with the local
gas velocity.  The isokinetic sample  flow rate,  Q , enters the sample nozzle
where it is mixed with a metered flow rate of recycled exhaust gas, Q .  The
combination of these two flew rates brings the total flow  rate to the
predetermined constant level, Q .   After passing through the  inertial sampler,
which collects the larger particle  size fraction (>10 urn), through an in-stack
filter which collects the smaller PMj0  size fraction,  and  through a heated
probe, the water vapor is removed from the gas stream by condensation in an
ice-cooled condenser or impinger train.   The gas stream then  enters the
control console where the total  flow  rate is eventually split into the compo-
nent flow rates, Q  and Q .  The sample flow rate is monitored in the usual
manner by using a dry g£ this  device has shown Cyclone I
produces a 10-ym size cut at a  flow rate of approximately  0.5 dscfm; the
precise flow rate depends on stack  conditions.   Calibration procedures for the
EGR sampling train are essentially  the  same as standard Method 5 or Method 17
trains with the exception of the two  L?Ea.   Calibration of the total flow rate
UTB may be performed simultaneously with the dry gas meter and orifice.
                                       iv

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Calibration of the  recycle  Clow  rate  LPE  requires  an  additional,  separate
step.  Pretest calculation  of  sampling parameters  for  operation of  the  system
involves determining  target pressure  differentials (AH, AP  ,  and  AP )  for a
range of possible velocity  pressures, AP    ,  and stack temperatures.  An
                                        vel
approximate solution  of the governing equations provides  acceptable agreement
with the exact solution and allows calculation of  these parameters  in  a few
simple steps.  Operation of the  sampling  train is  the  same  as Method 5  except
that valve settings must be adjusted  for  two  flow  rates  (Q  and Q )  rather
than one (Q ).  Sample retrieval  is dependent on the type of  sampling device
used.  For Cyclone I, a combination of brushing and rinsing with  a  suitable
solvent is required to quantitatively recover the  larger size fraction.   The
?M10 size fraction is recovered  by simply removing the filter from  the  filter
holder.  Test data analysis requires essentially the same calculations  as
outlined in Method 5 with the  addition of the cyclone  cut size, or  0$0.   Other
postsanpling activities include calibration checks and equipment  maintenance.

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                                   CONTENTS

                                                                          Page

roc ward 	   iii
Abstract 	    iv
Figures 	    x
Tables 	   xii
Symbols 	  xiii
Acknowledgement	   xvi

 M Introduction 	    1
 2. Construction 	    3
    2.1. General system description  	    3
    2.2. Component detail  	    5
         2.2.1. Control unit 	   13
         2.2.2. Condenser/Impinger train  	   IV
         2.2.3. Umbilical  	   18
         2.2.4. Sampling/Reheat probe	   18
         2.2.5. Exhaust gas recycle  nozzle	   20
         2.2.6. FM10 sampler 	   22
 3. Calibration 	   32
    3.1. Flow metering system  	   32
    3.2. Pi tot tube 	   36
    3.3. EGR nozzles 	   37
    3.4. Thermocouples 	   38
    3.5. Magnehelic gauges	   38
    3.6. Support equipment  	   38
 4. Presampling Activities	   39
    4.1. Equipment calibration and checks	   39
    4.2. Preparation of sampling  reagents	   41

                                     vii

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                             CONTENTS (Continued)
                                                                         Page

5. Sampling Parameters	  42
   5.1. Preliminary measurements	  42
   5.2. EGR flow rates  	  44
   5.3. Target pressure differentials (AH,  AP ,  AP )  	  45
   5.4. Nozzle selection	  55
6. Taking the Sample	  56
   6.1. Field assembly  	  56
   6.2. Leak test  	  57
   6.3. Pretest equipment warm-up	  58
   6.4. Flow rates 	  59
   6.5. Traversing	  	  60
   6.6. Flow rate checks	  60
   6.7. Shutdown or i en tat ion  	  60
   6.P. Datalogging  	  61
7. Sample Retrieval 	  63
   7.1. Recovery of particulate mass	  63
   7.2. Moisture determination	  64
8. Postsampling Ch-soles	  65
   8.1. Equipment calibration checks 	  65
   8.2. Sample analysis	  66
9. Data Analysis	  68
   9.1.  Average run parameters 	  68
   9.2.  Dry gas (sample)  volume  	  68
   9.3.  Sample flow rate	  69
   9.4.  Recycle and total gss flow  rates	  69
   9.5.  Volume of water vapor 	  70
   9.6.  Moisture content 	  70
   9.7.  Flow rates (actual conditions)	  71
   9.8.  Recycle ratio  	  71
   9.9.  Stack gas velocity	  71
   9.10. Concentration	  72
                                    viii

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                             CONTENTS  (Continued)
                                                                          Page

    9.11. Sampler Dj0 	  72
    9.12. Percent isokinetic 	  74
10. Maintenance 	  75
    10.1. Vacuum system	  75
    10.2. EGR pump 	  75
    10.3. Magnehelic differential pressure gauges  	  77
          10.3.1. Zero adjustment 	,	  77
          10.3.2. Calibration check  	  77
          10.3.3. Recalibration  	*..  78
    10.4. Dual nanometer  	  79
    10.5. Pi tot tube 	  80
    10.6. Hoizles 	  80
    10.7. Thermocouples  	  81
    10.8. BGR sampling probe	  81
          10.8.1. Probe cleaning	  81
          10.8.2. Probe heater check	  82
    10.9. Condensing system 	  82
11. Auditing Procedures	  84
12. Recoonended Standards f.->r Establishing Traceability  	  86

References	  87
Appendices

    A.  EGR System Coaponents L'.st  	  89
    B.  EGR System Shop Drawings	  99
    C.  Blank Data Forms	110
    0.  HP41C Setup Program	129

Glossary 	134
                                       ix

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                                    FIGURES

                                                                          Page

1.   Gas Flow  in EGR Train 	  3

2.   Schematic of the EGR Train 	  4

3.   15GR sampling system control module (front view)  	  6

4.   EGR sampling system control module (rear view)  	  7

5.   EGR sampling system control module (rear view)
       showing internal  components 	  8

6.   EGR sampling *••_-3i.&* control module (right side)	  9

7.   EGR sampling system control module (left side)
        with 4-cfm Pump  	 10

8.   EGR PM.Q cyclone sampling  device (front view)	 11

9.   EGR PMjg cyclone sampling  device (side view)  	 12

10.  EGR concept nozzle  assembly	 21

11.  Calibration system  for  heated aerosols 	 24

12.  Efficiency envelope for  PM1(J  sampler	 30

13.  Cyclone 1 Dimensions 	 31

14.  BGR Setup Calculation Worksheet  It  Orifice AH	 SO

15.  EGR Setup Calculation Worksheet  lit Total Flow  LFE AP	 51

16.  EGR Setup Calculation worksheet  III:  Recycle Plow LFE AP	 53

17.  Suggested EGR Run sheet	 62


B-l. EGR Panel (Control  Box)	 96

B-2. EGR Sampling System/  (Manometer  Leveling Accessories)  	 97

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                              FIGURES  (Continued)






                                                                         Page



B-3.  EGR Sampling System, DGM Supports 	  98




B-4.  BGR Sampling System, Back Panel:  Magnehelic Zero Valves	  99




B-5.  BGR Sampling Systea, Probe Components 	 100




B-6.  BGR Sampling Systea, Sample Orifice Assembly 	 101




B-7.  BGR Sampling System, EGR Nozzle Assembly 	 102




B-8.  BGR Sampling Systen, Pi tot Assembly 	 103




B-9.  BGR Sampling Systea, BGR Circuit Diagram 	 104




B-10. BGR Sampling Train, Condenser  	 105
                                      xi

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                                    TABLES
                                                                          Page
1.   Performance Specifications foe Source  PM1|}  Samplers 	 28

2.   Particle Sizes and Nominal Gas Velocities  for  Efficiency
     Performance Tests 	 29
                                      xii

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                                    SYMBOLS
A      Cross-sectional area of  sampling nozzle,  ft2
 n
B      Proportion by volume of  water vapor  in mixed gas, dimensionless
 mix
B      Water fraction of stack  gas  (also  f   )
 WS                                       HjO
C      Concentration of particulate, mg/dNm3
C1     Concentration of particulate matter, gr/dscf
C      Pi tot tube coefficient
 P
DL.    Cyclone cut diameter, urn
d      Diameter of nozzle n, in.
 n
D        Stack differential pressure,  in. H20
 pstack
f      Fraction C02
f      Fraction 0,
 o               *
f  _   Water fraction of stack gas  (also B   )
                                          ws
1      Percent isokinetic sampling
K      35.48 ft/s  (Ib/mole-'R)
 P
M.     Dry molecular weight of  stack gas, Ib/oole
 a
M      Mass of collected particulate  (either per stage or total), mg
 P
N      Wet molecular weight of  stack gas, Ib/mole
M      Wet molecular weight of  the mixed gas,  Ib/mole
M_     Molecular weight of water,  18 Ib/mole
 H^O
P      Ambient pressure, in. Bg
P_     Absolute pressure at LFB inlet,  in. Hg
 L
P      Absolute stack pressure, in. Bg
P      Absolute pressure at standard conditions, 29.92 in. Bg
 S7
PR     Recycle ratio at stack conditions, percent
Q.     The sampler flow rate when the total flow is composed entirely of  dry
       recycle gas (100% recycle)
Q      Flo«« rate through the sampler  (sampler  conditions) , acfm
                                      xiii

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 o     Sample  flow rate  (standard  conditions) ,  ft3/min
 ^ST
 Q     Total  (mixed)  cyclone  flow  rate  (sampler  conditions) ,  acfm
 Q     Total flowrate through the  sampler  (standard  conditions,  dry basis) ,
  fcST
       dixrfm
 Q     Recycle flow rate,  acfm
 Q     The sampler  flow  r&te  when  the total  flow is  composed  entirely of
       sample gas  with a known moisture  fraction (0% recycle)
 R     Ideal gas constant,  21.83 in. Hg-ft3/raole-*R
 S     Recycle flow LPB  calibration constant
 3     Total flow  LFE calibration  constant
 T     Absolute gas meter  temperature, *R
  H
 T     LFB temperature,  *R
  L
 T     Absolute stack gas  temperature, *R
 T     Absolute temperature at standard  conditions,  528  *R
  ST
 v     Average stack  velocity,  ft/s
  avg
 V     Total volume of liquid collected  in impingers or  condenser/silica
  ic
       gel, mL
 V     Volume of gas  sample flow through the dry gas meter
       (meter conditions),  ft3
 V     Volume of gas  sample flow through the dry gas meter  (standard
 Ho
       conditions), ft3
 V     Maximum expected  stack gas  velocity,  ft/s
 •ax
V     Stack gas velocity,  ft/s
V     Volume of water vapor  in the gas sample  (standard conditions) ,  ft3
 Vf9
W     Recycle flow LPB  calibration constant
W     Total flow LFB calibration  constant
AH     Orifice pressure drop
Al     Orifice pressure  differential for a flow  rate of  0.75 cfm  at standard
       conditions, in.
&P__  Velocity pressure drop of BGR S-type pi tot tube, in.
AP     Pressure drop across the recycle flow LP2, in. H.O
APg-   Velocity pressure drop of standard pi tot tube, in.
A?t    Pressure drp across the recycle flow LFB, in. H2O
A?  .  Velocity pressure head, in. H2O
                                      xiv

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p_ _   Density of watar, 1 g/mL
 n,u
9 ~    Total run time, min

u      Gas viscosity, up

u.     Stack gas viscosity at 0% moisture
 a
U      Gas viscosity at LFB conditions
 L
u      Viscosity of the mixed gas, up

U      Gas viscosity at standard conditions, 180.1 up
 S?
u      Stack gas viscosity for a known moisture fraction

 (/AP   )     Average square root of velocity APs, used to calculate average
    vel avg
             stack velocity.

Y      Gas meter calibration constant
                                      xv

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                                ACKNOWLEDGEMENT

     This manual builds on material presented in two previous report?  written
on the subject:  "Operations Manual for Exhaust Gas Recirculation  (EGR)
Sampling Train," prepared for the Atmospheric Research  and Exposure  Assessment
Laboratory of EPA, Contract No. 68-02-3118, August  1984,  and an  expanded
version of that manual, "Procedures Manual for The Recommended ARB Size
Specific Stationary Source Particulate Method (Emission Gas Recycle),*
prepared for the California Air Resources Board, Contract No. A3-092-32, May
1986.
                                      xv i

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                                    SECTION 1

                                  INTRODUCTION

     To ensure  a representative  sample  of  particulate  matter  is obtained from
a flowing gas stream, the  sample must be withdrawn  isokinetically;  that is,
the gas flow rate of the sample  must be adjusted  so that  the  velocity in the
sampling nozzle equals  that  in the  surrounding  gas  stream.  If  a velocity
mismatch occurs at the  nozzle, the  particulate  matter  in  the  sample gas .may  be
selectively enriched or depleted; the concentration increase  or decrease will
depend in part  on the particle size.  This bias is  avoided  in EPA Reference
Methods 5 and 17 by specifying isokinetic  sampling.  To obtain  a spatially
representative  sample,  the duct  is  divided into a number  of equal area zones.
The centroid of each zone  is then sampled  for a fixed  time  interval, and the
sample flow rate is adjusted at  each centroid to  be  isokinetic  with respect  to
the local gas stream velocity.

     The procedure outlined above is satisfactory for  total particulate mass
measurements.   However, when sampling is conducted  with inertial particle-
sizing devices  such as cascade impactors or sampling cyclones,  an additional
constraint is introduced.  These  samplers  must  be operated  at a constant flow
rate to maintain constant size cuts for each particle  size  fraction.  For  a
fixed nozzle size/ it is impossible to  satisfy  both  the requirements of con-
stant sampler flow rate and isokinetic  nozzle velocity with conventional samp-
ling trains.

     This manual describes assembly, operation, and maintenance of  a sampling
train that allows isokinetic sampling while maintaining a constant  flow rate
through an inertial particle-sizing device.  The  sampling train uses the prin-
ciple of exhaust gas recycle (EGR).  Its design allows a  preselected constant

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flow rate through the inertial sampler while the gas  flow  rate  into  the  samp-
ling nozzle ia adjusted to remain isokinetic with the local duct  velocity.
This method may bo identified in other EPA documents  as  the Omission Gas
Recycle method.  Although the potential uses of this  system are numerous,  this
manual specifically addresses the operation of the EGR system for the deter-
mination of utationery source emissions of particulate matter with diameter
<10 urn (PM10)>.  The sizing device described consists  of  a  commercially avail-
able version of Cyclone I of the Southern Research Institute  (SRI)/EPA five-
stage series cyclone sampler (Smith et al. 1979) and  an  in-stack  backup
filter.  However, most components of the EGR system are  independent  of the
type of inertial sampler used, and the material provided in this  manual
pertaining to these components is applicable to most  sampling situations.

     This manual is organized chronologically, from construction  details to
postsampling and audit checks of the system.  Section 2  describes the critical
construction details of the EGR system.  Section 3 describes the  procedures  by
which various components of the system may be calibrated.  Activities that are
required or recommended before field use of the system are outlined  in
Section 4.  Section 5 describes the calculations required  to obtain  the  system
sampling parameters before sampling, and Section 6 outlines the steps to fol-
low during op-scat ion of the sampling system.  Retrieval  of the collected
sample is described in Section 7.  Sections 8 and 9 describe postsampling
checks of the system and analysis of the field data.  Routine maintenance  of
the BGR sampling system is discussed in Section 10.   Auditing procedures and
recommended standards are described in Sections 11 and 12.  Included as
Appendix A is a list of components necessary to fabricate  an EGR  system  simi-
lar to that developed at SRI.  Appendix B contains a  complete set of fabrica-
tion drawings for the prototype BGR system.  Examples of data forms  necessary
in the course of calibrating and operating the EGR system  can be  found in
Appendix C.  Appendix D contains a listing of a program  written for  the  HP41C
that performs EGR setup calculations.

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                                    SECTION 2
                                  CONSTRUCTION
2.1.  GENERAL SYSTEM DESCRIPTION
     The principle of operation of the EGR train is  illustrated in Figure 1.
Stack gas  is  extracted i sole ine tic ally at volumetric  flow rate Q .   If the
stack moisture  fraction is f   , the sample flow consists of  Q {f    ) moisture
                             I^O                                s 82°
and   Q  (1  -  f    )  dry gas.  In the EGR nozzle a flow, Q , of dry  recycle gas
       s      HjO                                        r
is added to the sample stream to bring the total flow rate to the  predeter-
mined constant  level, Q .   In the impingers or condenser, the moisture content
Q  (f  _) is removed.   Downstream of the pump and total flow metering element,
 8  82"
the recycle flow (Q ) is diverted by means of an adjustable valve.  By mass
balance, in a leak-free system, the remaining flow that  passes through the dry
gas meter  (DGM)  and orifice will simply be Q (1 - f   ) ,  exactly as would
                                             8
occur in an isokinetic  sampling train without exhaust gas  recycle (Martin,
1971).
           MIXING
           NOZZLE
                                             CONDENSER.
                                             IMPINGER
                                                                       DRY GAS
                                                                       METER
                                                                         IMI-4II
               Figun 1. Gas flow In EGR train f Ham's and Bfddingfield, 1981).
                                     3

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             MTOT TUBE
                                      EGR PROBE ASSEMBLY
RECYCLE
LINE
                                                                                                                 EXHAUST
                                                                                                                 4III-KIC
                                 Figure 2. Schematic of the EGR train (Williamson et a/., 1984).

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      A block  diagram  of the research train of Williamson et al. (1984) is
shown in  Figure  2.  The gas sample containing participate matter enters
through the sample  inlet of the nixing nozzle.  After passing through the PM1Q
classifier, which collects  the larger  particle size fraction (>10 urn), through
a second  stage,  which collects the smaller PM10 size fraction, and through a
heated  probe,  the combined  sample  and  recycle gas passes through an ice-cooled
condenser or  impingec train,  followed  by a sealed pump controlled by valves Vj
and V2  for coarse and fine  flow adjustment,  respectively.  From this point the
gas in  a  standard isokinetic  sampling  train  would pass directly to the DGM and
sample  orifice and  finally  be exhausted.   In the train as modified for EGR,
after  the gas  exits the pump, it passes through an absolute filter and the
first o*  two  laminar  flow elements (LFEs), where the total flow is measured.
The gas stream is then split  into  the  recycle and sample lines.  The recycle
gas flow  is controlled by valves V3  and V^ and is measured by a second LFE.
The sample flow  is  monitored  in the  usual  manner by using a DGM and a calibra-
ted orifice.  Valve V$,  at  the inlet to the  DGM, was added to the system to
extend  the range of control to higher  recycle percentages by adding back-
pressure  to the  sample flow line.

     Figures 3 through 7 show the  control  module for the SRI/EPA second-gener-
ation EGR system.   As can be  seen, the module appears similar to a Method 5
sampling box, with  the exception of  the total, inlet, and recycle magnehelic
gauges, the recycle and sample (back-pressure)  control valves, and the recycle
gas outlet.  The probe head is shown in Figures 8 and 9 with a filter in line
behind  the SRI/EPA  Cyclone  X  for collecting  the PM10 size fraction.  The loca-
tion of the pitot tube relative to the cyclone body shown in the figures was
used during initial testing of the method.  The location of the pitot tube was
eventually changed  to that  described in Section .3.2.
2.2.  COMPONENT DETAIL

     This section describes essential  and specific  components of the SRI/EPA
exhaust gas recycle train.  The  included specifications  are intended as a gen-
eral outline.  Substitutions of  the designated components may be acceptable if

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Figure 3.  EGR rampling system control module (front view).

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 r
Figure 4.  EGR sampling system control module (rear view).

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                            SAMPLE
                            ORIFICE
RECYCLE LFE
SAMPLE
GAS METER
                                                                              HEPA
                                                                              FILTER
                                                                             TOTAL LFE
                                                                                 ItM-ll
   Figure 5.  EGtt sampling system control module (rear view) showing internal components.

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MAIN POWER
INPUT
                                                                       AUXILIARY
                                                                       RECEPTACLE
                                                                            Illl-ll
                       £G^ sampling system control module (right side).

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                                     JSP ARE
                           •'iiKi^Sig^'y THERMOCOUPLE'-
                             ^^^T-"? PORTS        • '
                                                   ,j 4-cfm SEALED
                                                   ' CARBON-VANE
                                                   ' PUMP
  PUMP POWER INPUT
Figure 7. £GR samp/ing system control module (left side) with 4-cfm pump.
                            10

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 y>vVV?HpfeK:^*
  ••• '•.":''";*,: ^.?^';'*: |"1SP
                          -^-,-.	
NOTE: Se text regarding pitot tube location.
                                                     IIM-II
    Figun 8.  EGR PMJO cyclone sampling device (front view).
                          11

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                                                         • »'Tv,'1*lc-r^TL-;_r"";  -'i*.' .'"'^
                                                         ^-r.^ssgrWV?> '.-•>•.?>--:.;?
63-mm Fl LTER HOLDER
       NOTE:  See text regarding pilot tube location.
                        £G/? ^Af ;^ cyclone sampling device (side view).
                                          12

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 it can be  shown  that  the  substitutions  do not  negatively affect the principles
 of exhaust gas recycle.   An  itemized  list of all  components  used foe construc-
 tion of  the BGR  sampling  system  can be  found in Appendix A.   Additionally, a
 complete set of  shop  drawings, as  used  by SRI  for fabricating the EGR system,
 can be found in  Appendix  B.

 2.2.1.  Control  Dnit

     The BGR control  unit actually consists of two units,  the control box and
 a leak-free pump.  In many source  sampling systems,  the  pump is internal to
 the control box.  However, the combined weight of the BGR control box and the
 4-cfnt pump is approximately  115  Ib.   Therefore, to distribute the system
 weight and minimize the control  box dimensions, the  EGR  pump is external to
 the system.  The pump is  connected to the control box via 1/2-in. i.d.   flex-
 ible, high-pressure rubber hose.   Full-flow, quick-connect fittings allow
 rapid assembly and disassembly.

     The gas recirculated within the  BGR  system must be  free of any foreign
particles or vapors;  therefore,  a  leak-free, carbon-vane 4-cfm pump (Andersen
 Samplers, Inc.,  1991584)  is  used with the EGR  system.  The pump operates on
 115 V ac and draws approximately 4-6  A.   The specified pump  requires no lubri-
cation, and little maintenance is  needed  to ensure long  working life.  It is
 suggested the pump be housed, at least during  transportation and storage, in a
separate and unique container (e.g.,  a tool box).  The pump  may be left in the
housing during system operation; however,  caution should be  exercised to pro-
tect the pump against overheating.  A small circulating  fan  installed in the
pump box and ventilated to the outside should  be  adequate.

     The control box contains the  required electrical circuits, internal
plumbing, flow control valves, devices to monitor  flow and pressure, and
 temperature readout and control  instrumentation.   The components are housed in
 a custom-sized, heavy-duty transit case  (Gemini,  Inc., KSH2325RPP-2).  The
electricity to the system (115 V ac at  15 A) is brought  into the control box
via a single length of 12-gauge, three-wire cable.   To prevent accidental
disconnection during  sampling runs, the electrical  input cable is attached to
                                    13

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the control box with a locking plug  and  receptacle.   The  input power is
paralleled to the various pieces of  electrical  equipment  (solenoid valves,
indicator lights, pump, temperature  readout,  and  heater  tape control)  via
standard, double-row terminal strips.

     The internal plumbing of the EGR sampling  train  can  be inferred from the
schematic drawing shown in Figure 2  and  is  shown  in some  detail in Figures 4
and 5.  Rigid! copper tubing, 1/2-in. o.d. for the total  flow and sample lines
and 3/8-in. o.d. for the recycle line, is used  for all  internal flow lines.
The lin-as are assembled into the required geometry by using a combination of
copper "sweat" fittings and a variety of brass  compression tube fittings.  The
total flow (mixed gas) enters the control box just upstream of the system
vacuum gauge, through a 1/2-in. bulkhead quick-connect-,  fitting.  As previously
mentioned, this flow is controlled through  the  pump by  valves V1 (coarse
adjust) and V, (fine adjust).  After exiting  the  pump,  the total flow is
directed through an absolute, HEPA-type, capsule  filter  (Gelraan Sciences
112127).  The filter prevents artifact particulate matter (e.g., graphite dust
from the pump vanes) from plugging the flow-monitoring  devices or entering the
recycle gas stream.  The particle-free tota."  flow is  monitored by an appropri-
ately sized LJ*B, after which the flow is split  into the recycle and sample
flows.  The nscycle flow is also monitored  with an appropriately sized LFE and
controlled with a set of coarse and  fine adjust valves  (V, and V^, respective-
ly) .  The recycle gas then exits the control  box  through  a 3/8-in. bulkhead
quick-connect fitting.  A normally open, 0.281-in. orifice, two-way solenoid
valve  (Automatic Switch Co., I8262A152)  i*  located at both the total flow
inlet and the recycle outlet.  The solenoid valves may  be switched closed
while the sampler is in-stack and is not sampling; this prevents erroneous
sample gas meter volumes and helps protect  the  sampling  filter from rupture
due to excess duct pressures.  The sample flow, after the split from the total
flow, is monitored in a manner similar to that  of a standard Method 5 train by
using a DGM and a calibrated orifice.  The  back-pressure  valve  (V5) added to
the sample line is similar to the fine adjustment valves  used in the recycle
and total flow lines.  The fine adjust valves are 1/4-in. orifice, stainless
steel, angled regulating valves  (Whitey  ISS-1RF4-A).  The coarse valves are
stainless steel ball valves with a 0.281-in.  orifice  (Whitey ISS-44P4).
                                     14

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 2.2.1.1.  Flow  Metering  Devices—
     As mentioned  above,  the  total  and  recycle flows are monitored by using
 LFEs.  These  are differential-pressure  flow measurement devices composed of a
 stainless steel capillary aatrix.   The  calibration curve of most LFEs approa-
 ches linearity  over  a wide  flow  range,  and  accuracy is  limited mainly by flow
 stability and pressure gauge  readability.   Pressure drop (AP)  across an LFE is
 a function of the  friction  between  the  flowing air  and  the  walls of the LFE's
 capillary section.   Because the  pressure differential  is not produced by a
 restriction, such  as an orifice, the  absolute  system pressure does not contri-
 bute to the AP-flow  rate  relationship of an LFE (at meter conditions).  The
 total flow LFE  should have  a  rated  capacity of at  least 1.0 cfm without exces-
 sive AP  (Meriam Instrument  I50MJ10-1/2  type 10).   The LFE used to monitor the
 recycle flow rate  should  have a  minimum capacity of 0.7 cfm (Meriam Instrument
 I50MJ10-1/2 type 11).  During construction, care should be  taken to prevent
 dust and debris from entering the LFE's capillary  section.   Any accumulation
 of foreign natter  within  the  laminar  matrix could  seriously affect the accu-
 racy and reliability of the device.   Periodically,  the  capsule filter immedi-
 ately upstream  of  the total flow LFB  should be inspected for filter integrity,
 efficiency, and pressure  differential.  If  the HBPA filter  were to rupture,
 particulate matter from the pump could  enter the LFEs,  altering the known
 calibration and potentially altering  the LFEs1  linearity.

     The sample gas  iu measured  and monitored  by using  an orifice-DGM assembly
 similar to that of a Method 5 train.  The DGM  should have a flow rate capacity
of at least 1.0 cfm  and be  readable to  0.002 ft3 (Rockwell  Series T-100).  The
geometry of the sample gas  orifice, which connects  directly to the outlet of
 the DGM, is comparable to that of the Method 5 sample orifice.   However,
 because of the  reduced total  flow rate  of the  PM10  sampler  (approximately
 0.45 scfm) and  partitioning of the  flow rate between sample and recycle flows,
 the sample orifice for the  EGR train  requires  a smaller diameter to obtain an
 adequate orifice pressure drop (AH).  Theoretical  and empirical determinations
 have shown 0.129 in. is a practical diameter for the EGR sample orifice.  How-
 ever, to ensure effective coverage of the range of  possible sample flow-rates,
 it is recommended  a  set of  sample orifices  be  fabricated with the following
 diameters:  0.180  in., 0.129  in., and 0.094 in.  A shop drawing of the EGR
 orifice set is  shown in Appendix B, Figure  B-6.
                                    15

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2.2.1.2.  Pressure Monitors—
     The differential pressure across the sample orifice  is monitored  by using
one leg of a dual-column, partially inclined, water-gauge manometer  (Dwyer
Instruments, Inc., 4422-10).  The BGR system uses  a  0-10-in. manometer,  with
an inclined range  (0.01-in. divisions) of 0-1.0 in.  Accurate  reading  with  an
inclined-vertical manometer requires that the inclined  portion of the  scale be
at the exact angle for which it was designed.  Therefore, the  specified  mano-
meter must be mounted to allow alignment as indicated by  the  integral  spirit
level.  The total and recycle LFE pressure differentials  are monitored by
using separate magnehelic pressure  that the measured flow rates, total and  recycle, can  be rela-
ted to tho flow rate at stack conditions.  To determine this pressure, a
magnehelic gauge with a 0-25-in. range  (Dwyer 42025) is used  to measure  the
pressure at tho specified location, relative to ambient pressure.  In  prac-
tice, the high-pressure tap of this differential pressure gauge is connected
in parallel with the high-pressure tap of the total  flow  LFB,  and the  low-
pressure tap isi vented to the ambient pressure.  The absolute  pressure at the
total LFB can then be determined from the sun of the local barometric  pressure
and the measured inlet relative pressure.  Finally,  as  with a  typical  Method 5
sampling system, the second leg of the dual inclined manometer is used to
measure the pitot  (stack velocity) differential pressure. All pressure  dif-
ferential measurement devices are connected to the appropriate pressure  taps
with 1/4-in. i.d. Tygon tubing  (Sargent-Welch S-73C51-KC).

     The pitot Lines enter the control box through two  1/4-in., stainless
steel bulkhead 'compression quick-connect tube fittings.  The  fittings  are
coded to distinguish between the high and low pressure  lines  (red-high,
bluelow).  This code combination is maintained on  all pitot line tube  fittings
from the control box to the probe.  A three-way solenoid  valve .(Automatic
Switch Co. 483MC21) is installed at the control box inlet to  each pitot line.
The solenoid valves can be toggled to pitot pressures or  vented to ambient  air
for a quick check of the manometer's zero reading.  The solenoid valves  are
connected directly to the appropriate leg of the dual manometer with 1/4-in.
Tygon tubing.
                                    16

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 2.2.1.3.   System  Temperature  Monitors—
     The  system temperatures  are  monitored  with type K (Chrorael-Alurael)  therm
 occupies.  A multiposition  switch (Omega IOSW3-10)  allows the operator to
 measure all system  temperatures with  a single digital meter  (Oiaega I199KF).
 As a minimum, provisions  should be made to  monitor  the following system
 temperatures:

     o     local flue gas  te&pArature,
     o     heated  recycle  gas  temperature,
     o     heated  probe  temperature,
     o     mixed gas temperature at total LP3,
     o     sample  gas temperature  at DGM,  and
     o     local ambient temperature.

     The  thermocouple connections to  the control  box are  made via a multipin,
 flanged connector  (Onega  IMTC-24-FF)  for  the  SRI/EPA prototype BGR system.
The pins  and sockets of the appropriately compensated metal  (Chromel or
Alumel) are also  used.  The power to  the probe heating system is controlled
 through a  proportional, 10-A-capacity,  temperature  controller (Omega
 I6102-K-0/500 *F).  The controller is  wired and mounted according to
manufacturer's instructions.  The controlling  thermocouple  for the probe
heater is  housed  within the probe assembly, sandwiched between the internal
tubing and the heater tape  (described  in more  detail under  Section 2.2.4.
Sampling/Reheat Probe).   A parallel extension  from  this same thermocouple line
 (within the control box)  is used  to visually monitor the  probe temperature.

 2.2.2.  Condenser/Inpinger Train

     Because the BGR system is typically operated in a Method 17 rather  than a
Method 5 configuration, the water dropout portion of the  prototype EGR system
consists of a coiled, stainless steel condenser followed  by  a drying column.
A layout drawing of a typical BGR-type  condenser  is shown in Appendix 8,
Figure B-10.  The condenser, as well as the required amount  of ice,  is housed
 in any appropriate, commercially  available  ice chest.   The drying column
should be  leak-free and capable of holding  500-600  g of an  appropriate
                                    17

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desiccant  (silica gel, calcium sulfate, etc.).  Several  commercially available
drying columns or towers  (Sargent Welch fS-28730)  are  available.   Alterna-
tively, a  standard Method 5-type impinger  train may be used  according to
traditional protocol.

2.2.3.  Umbilical

     An with a standard Method 5 train, the EGR umbilical  consists of
thermocouple, electrical, pressure, and flow  lines bound into  a single cable.
The only significant difference between a  standard Method  5  umbilical and that
of the EGR system is the addition of  another  flow  line,  the  recycle gas line.
All flow lines should be fabricated from flexible, durable (abrasive-
resistant) tubing.  The inside diameter of the total  and recycle lines should
be sufficient 'to avoid significant pressure drop through the length of the
tubing.  The EGR system umbilical uses heavy  wall, black neoprene rubber
tubing:  3/8-in. i.d. and 1/8-in, wall  (Sargent Welch  *S-73655-KF).  The pitot
pressure lines nay be fabricated from similar tubing of  the  appropriate size
(Sargent Welch IS73655-KD).  For ease of assembly  and  disassembly during
testing, it is suggested quiclc-connect-type tube fittings  be attached to both
ends of the umbilical.  Furthermore,  for stress relief,  90*  elbows are recom-
mended for use on the flow lines at the probe end  of the umbilical.

     The thermocouple and electrical  extension lines within  the umbilical are
made from  flexible and durable extension wire of the  appropriate type.
Although not required, it is strongly recommended  that a ground wire be
included in th« electrical wires to the probe.  The ground wire should be
coupled to the probe and the system ground at the  control  box  (refer to the
Sampling/Reheat: Probe section, which  follows).  The thermocouple and
electrical connections at each end of the  umbilical may  be made by using
individual connectors or a single, multipin connector.  In either case, the
properly compensated connectors should be  used.

2.2.4.  Sampling/Reheat Probe

     In most rospects, the EGR sampling/reheat probe is  similar to the
standard Method 5-type probe.  As with a Method 5  probe, the EGR probe houses
                                    18

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 the pitot  extension  lines  and  a heat-traced sample line.   A stack gas thermo-
 couple  and probe-temperature-measuring  thermocouples are  also include*  in the
 probe assembly.  Unlike  the  Method  5 probe, however, the  EGR probe also
 contains a heat-traced recycle gas  line.   The sample gas  line, referred to as
 the total  flow line  within the EGR  system, is fabricated  from a single length
 of 5/8-in.  stainless steel  tubing.   The  recycle line is  fabricated from
 1/2-in. stainless tubing,  and  the pitot lines are 1/4-in. stainless steel
 tubing.  The various tubes are held  in  place by rigid (weld or silver solder)
 attachment to an 0-ring-sealed probe cap.   The 0-ring seal between the end cap
 and the sheath prevents  particulate  material from entering the probe housing,
 which would have the potential to create  electrical and abrasive problems.  A
 second, loose-fit, end cap supports  the out-of-stack end  of the tubing.  The
 entire probe assembly is housed within  a  sheath of 2-in.  schedule 5 stainless
 steel pipe of the  appropriate length (the prototype EGR  probe sheath is
 96 in. long}.  The 8-ft  probe  weighs approximately 24 Ib.

     The heat tracing of the total  flow and recycle lines within the probe
 sheath serves a dual function.   As with the Method 5 sample line, the total
 flow line  is heated  to prevent unwanted condensation from occurring within the
 length of  the probe.  The  second function of the heated probe is to warm the
 recycle gas to stack temperatures to ensure isothermal mixing of the recycle
 and sample gases at  the \BGR  mixing nozzle.   The heated recycle gas temperature
 is monitored by a thermocouple mounted  in-line, immediately upstream of the
BGR nozzle (refer to Figure  8).  The total and recycle flow lines are heated
by using a single, proportionally controlled heater tape  (Cole-Parmer
tT-3107-80) of the appropriate length.  The 1.75-in.-wide heater tape is
cupped over both flow lines, spiralling around the tubes  several times, and is
held securely in place with  glass fiber tape.   A controlling thermocouple is
 secured to the recycle line  directly beneath the heater tape.  Unless the
 thermocouple is placed in  direct contact  with both the recycle tube and the
heater tape, the system  can  overheat, causing damage to the assembly.  A layer
of 1.0-in. x 0.06-in. ceramic  fiber  cloth tape (Sargent Welch #3-1210-100) is
wrapped completely around  the  heater  tape  and appropriate tubing to serve as
 thermal insulation for the probe assembly.   Finally, the  insulated, heat-
 traced tubing is completely  wrapped  with  glass fiber tape for security and
                                     19

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protection.  The* heated assembly, along with the  1/4-in. pitot  extension
lines, is then housed within the stainless steel  sheath.

     The external flow extension lines  (recycle,  pitot) and  th- specified  PM1Q
sampler are attached to the appropriate probe  lines by means of commercially
available tube compression fittings  (e.g., Swagelok, Parker  CPI).   It  is
suggested the in-stack fittings be assembled by using stainless steel  ferrules
for strength and reusability.  However, because it may be desirable to dis-
assemble the probe at a future date. Teflon or nylon ferrules are  recommended
for all tube fittings on the exit end of the probe.  These softer  ferrules do
not cause tubing deformation as do the metal ferrules.  This preserves the
clearance of the exit probe cap around each tube, allowing smooth  disassem-
bly.

     It is strongly recommended that the electrical  (heater)  wires extending
from the probe include a ground wire attached  to  the probe via  one of  the  end
cap fastening bolts.  Electrical shorts within the heater tape  or  stray static
charges from particulate control devices have  been known to  cause  sampling
system interferences and/or damage.

2.2.5.  Exhaust Gas Recycle Nozzle

     A conceptual design of the stainless steel EGR nozzle can  be  seen in
Figure 10.  As is shown, the recycled exhaust  gas enters the nozzle through a
1/4-in. side entry tube and fills an annular region around the  sample  inlet
tube.  A range of sizes suitable for isokinetic sampling at  varying recycle
rates should be available, for example, 0.32 to 0.64 cm  (1/8 to 1/4 in.) inlet
diameter.  Furthermore, because inertia tends  to  cause deposition  of particles
in the PMj0 size range in bends, only straight sampling nozzles should be
used.  "Gooseneck" or other nozzle extensions  designed to turn  the sample  gas
flow 90*, as in Methods 5 and 17, should not be used.
                                    20

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                                                                       MIXED
                                                                       GAS TO
                                                                      CYCLONE
                                                 RECYCLE
                                                   GAS
                          Figun 10.  EGR concept nozzle assembly.
     Figure 8 shows the recycle line of the  system contains  a "tee*  immedi-
ately upstream of the EGR nozzle.  The exhaust  recycle gas enters the tee
through a short section of 1/4-in. stainless steel tubing, bent as required,
which ia silver-soldered to  -»ie branch portion  of the  tee.   The recycle gas
exits the tee via one of the "run* end fittings, where the tee is directly
connected to the HGK nozzle with compression tube fittings.   The second "run"
end of the fitting ia .ised to introduce an open-bead,  typ«-K thermocouple to
the recycle gas stream.  By monitoring the temperature of the recycle gas
near the EGR nozzle, isothermal mixing of the recycle  and sample gases can be
more easily ensured.  It is suggested the extension  vire for the recycle
thermocouple, as well as the stack gas thermocouple, be contained in a
braided (stainless steel) sheath for abrasion resistance and durability.
                                    21

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2.2.6  PMjf, Sampler

     The exhaust gas recycle concept has been applied to a single-stage PM^.
cyclone sampler of a specific geometry.  This manual gives specific  instruc-
tion for this device but does not preclude other cyclones.  Before, any cyclone
is used as a MID sampler, its performance must be characterized  to  derive  the
relationship for the flow rate giving a 10-ym size cut and to verify that
performance, including the nozzles, satisfies minimum requirements.

2.2.6.1  Performance Determination for m. 0 Cyclones—
     To determine that a given cyclone meets the requirements for use as a
PMj. device, the performance determination procedures outlined  in the
following text must be performed.  The objectives of these procedures are
twofold:   (1) to calibrate the cyclone (i.e., establish the relationship
between collection efficiency, flow rate, gas viscosity, and gas density for
the given device) and  (2) to determine that cyclone performance satisfies the
performance specifications with the sampling nozzle geometry used in
practice.

     Particle generation—The particle generating system used for the
performance determination of the sampler must be capable of producing solid,
monodisperse dye particles with mass median aerodynamic diameters ranging from
5 to 20 iim.  The geometric standard deviation  (a ) for each particle size
                                                g
should not exceed 1.1.  Furthermore, the proportion of multiplets and
satellites should not exceed 10% by mass.

     The size of Uhe solid dye particles delivered to the test  section of the
wind tunnel should be established by using the operating parameters  of the
particle generating system.  This should be verified during the tests by
microscopic examination of samples of the particles collected on  a membrane
filter.  The precision of the particle size verification technique should be
0.5 urn or better, and the particle size determined in this manner should not
differ by more than 10% from that established by th« system operating para-
meters.
                                    22

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      The  monodispersity of  the particles should be verified for each te*t by
either microscopic  inspection of  particles collected on filters or monitoring
techniques  such  as  an  optical particle counter  followed by a multichannel
pulse height  analyzer.   It  is preferable that verification of acceptable
particle  size distribution  be performed on an integrated sample obtained
during the  sampling period  of each  test.   As an alternative, samples obtained
before and  after  each  test  may be used fo verify the size distribution.

      To determine cyclone behavior  as  a function of gas conditions, the
system must be operated at  a  range  of  temperatures.  The dye particles must
withstand temperatures  from 22 *C (70  *F)  to 200 *C (400 *F) without signifi-
cant  change in size, density,  or  spectral properties in solution (associated
with  measurement  of collected particulate c.ass).  Ammonium fluorescein
(available  from  a number of sources) has been shown to meet these require-
ments for temperatures  up to  350  *F and Pontamine Past Turquoise 8GLP (avail-
able  from B.I. DuPont de Nemours  and Company) has been shown to meet them up
to 400 *F (Smith  et al., 1979).   However,  the thermal integrity of each dye
batch should  be verified.

     The requirements of the  apparatus for  heating the monodisperse dy* aero-
sol are illustrated in  Figure 11.   A pump with  an orifice or other flow meter
is used to obtain the test  flow rate through the cyclone.  The combination of
absolute filter/bleed valve allows  excess aerosol to escape or additional air
to enter as needed.  The aerosol  stream from the generator passes through a
copper tube heated to attain  the  test  temperature.  The heat transfer rate
and uniformity of heating should  be sufficient  for the aerosol to attain the
teat  temperature but should not cause  the  temperature of any interior sur-
faces to rise  above the temperature used  for verifying the integrity of the
dye.  The inlet tube to the cyclone must  have the same inside diameter as the
inlet diameter of th« cyclone.  This tube must  be cleaned between runs and
blanks performed  to check for  possible effects  of reentrainment of particles
which accumulate on its interior.   The sample port is necessary to collect
and examine heated particles  for  correct  size,  color, and shape for «ach
measurement run.
                                     23

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 AEROSOL STREAM
 FROM VIBRATING
 ORIFICE AEROSOL
 GENERATOR
3LUTE FILTER
                                          OVEN
I                                          KEPT AT
                                          AEROSOL TEMPERATURE
                                             «
                                             u.
                                             i
                                             o
                                             £
                                             IU
                                                                           PUMP
        THERMOCOUPLE
                      SAMPLING
                      PORT
                                                           MERCURY   WATER
                                                           MANOMETER MANOMETER
                                                                           4181-92
                     Figure 11.  Calibration systim for heated aerosols.
     Wind tunnel—A portion of the collection  efficiency tests must be
performed under  isokinetic sampling conditions in a wind tunnel or similar
apparatus so  that  the effect of the sampling nozzle on the cyclone perfor-
mance may be  determined.  This apparatus must  be  capable of establishing  and
maintaining  (within 10%) velocities ranging froa  7 to 25 m/s.

     The velocity  of the wind tunnel gas stream in the vicinity of the  samp-
ling nozzle  should be raer "M by using an  appropriate technique capable  of a
precision of  5%  or better and of a spatial  resolution of 1 cm or less  (e.g.,
hot wire anemametry or miniature pitot tubes). The velocity should be  con-
stant within  10* over the inlet area of the largest sample nozzle to be used
with the PM1C|  sampler.  If the sampler obstructs  mora than 10% of the wind
tunnel cross-sectional area, the velocity uniformity must be demonstrated by
velocity measurements with the sampler in position and operating.
                                     24

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      Foe  each  efficiency test,  the  gas stream velocity should be determined
at the beginning of  each test  and maintained within 10% of the set value by
using a suitable monitoring  technique  with precision better than 5%.

      Cyclone calibration—To achieve the  first objective of the performance
determination  (establish the relationship between  collection efficiency, flow
rate, and gas  conditions) the  following procedures should be followed.

      The operator should establish  operation of the particle generator  and
verify particle size microscopically.   If monodispersity is to be verified by
measurements at the beginning  and end  of  the measurement run rather  than by
an integrated  sample, these  measurements  should be performed at this  time.
Plow  should be initiated  through the cyclone at the test value after  stable,
correct operation of the generator  is  established.   The operator should sample
long  enough to obtain ±5% precision on total collected mass as determined by
precision and  sensitivity of the measuring technique.   Immediately after
completion of  sampling,  the  size of the aerosol particles should be verified
microscopically.

      The sampled particulate mass is determined by a suitable technique
(fluorimetry or absorption spectrophotometry for ammonium fluorescein).  The
mass collected in the nozzle, PM1Q  sampler body, FM1Q  sampler exit tube, and
backup filter  (M   , M    . M  . M_.  respectively)  is determined separately.
                noz   saw   et   cii
Bach  separate  surface must be  rinsed with an adequate  amount of an appropri-
ate solvent to dissolve  the  collected  dye particles,  and care must be taken
not to contaminate the rinses with  dye from other  surfaces.  Sufficient
solvent must be added to each rinse until the rinse volume is suitable  for
measurement or calculation.  It is  suggested that  the  mass of dye in  the
rinses be determined from spectroscopic cr^ fluorescence measurement by  using
appropriate blank and standard solutions  for reference and quality control.

The total (nozzle and sampler) and  sampler-only collection efficiencies (B
                                                                           tot
and B   )  may be calculated  from the following  equations!
      sam

           B    • 100% X (M    + N   )/(M    -I- M    +  M   + M..,)       (2-1)
            tot            noz    sam     noz    sam    et    fil

                                    25

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                   Bsam - 100t x M8am/(M8am + Met + MfU)               (2-2)

At least two replicates of the above steps should be performed.

The average efficiency should be calculated and recorded  as
                             'tot'"              '-'"
                                                                        (2-3'
where B    (i) .and S    (i) represent  individual &     and E     values and n
       tot         sam                          tot      aara
equals the number of replicates.
The standard deviation  (S) for the replicate measurements  should  be calcu-
lated and recorded as

                                                   0.5
                          I  B2(i) - ( I E(i))2/n
                                                                        (2-4)
                   S •
                                   n -  1
where E(i) represents B    (i) and B    (i).
                       tot         san

For n - 2, S -  [E{1) - B(2)]//2*.  If the value of S  for B     exceeds 10% of
                                                         tot
B , the test run must be repeated.

     The size cut, t^Q, of the cyclone is established by either  of two sets
of measurements.  In one set, operating conditions are  adjusted  to obtain a
collection efficiency, B , of 50 ±5% for a  single particle  size.   Three
replicate runs uhould be performed with the actual particle size for each run
within ±5% of the average value.  In the other set,  B   is measured with at
                                                     8
least three particle sizes at the same operating conditions,  and linear
interpolation in log-probability space is used to determine the  D.  In the
latter set, the measured B  values must be between  20  and  80%  and include
values both below and above 50%.
                                    26

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           Plow rate—To  determine the empirical relationship between PM10 flow
 rate  and gas  conditions,  the  D^0  determination described above must be per-
 formed  for at least  three temperatures.   The OSQ'S must be between 5 and 15 urn
 and measured  at temperatures  within 60 *C (108 *P)  of the temperature at which
 the cyclone will be  used.   In addition,  one  of the measured D^o's must be 10 ±
 0.5 urn.

      Linear regression analysis is  used  to determine  the relationship between
 the dimensionless parameters  *50  (=  0.5  Stkso)  and Re,  where Sttc50 is the
 Stokes number giving 50% collection  and  Re is  the  Reynolds number of the gas
 entering the  cyclone.
                        *50 "  °'5 St*SO
and
where Q - gas flow rate through the cyclone  at  the  inlet conditions
      v • gas viscosity
      d » diameter of the cyclone  inlet
      p » gas density at the cyclone  inlet

With the substitution of Dgg * 10  um  into the resulting relationship,  the flow
rate for M10 measurements  is predicted  as a function of gas  conditions.

     Determination of cyclone/nozzle collection efficiency—Because the
cyclone and sampling nozzles are used as a unit in  actual sampling  situations,
it is necessary to establish that  the nozzles do not perturb  the  particle
sizing characteristics of the cyclone as determined by the  calibration proce-
dures discussed previously.  To do this, collection efficiency  tests should be
performed for the cyclone/nozzle unit by using  the  particle diameters  and gas
velocities shown in Table 1.  For  the appropriate PM1Q sampler  flow rate, the
operator should determine the nozzle  size appropriate for isokinetic sampling
in each of the three velocity ranges  shown in the table.  If  more than one
nozzle is suitable for a range, the larger nozzle may be chosen.

                                    27

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            TABLE  1.  PAR7ICLB SIZES AND NOMINAL GAS  VELOCITIES  FOR
                      EFFICIENCY PERFORMANCE TESTS OF CYCLONES

                                      Target Gas Velocity (m/s)	
           Particle Size  (urn)*      7 ±  1.0      15 ±  1.5      25 ±  2.5
                5 ± 0.5

                7 ± 0.5

               10 ± 0.5

               14 ± 1.0

               20 ± 1.0


            Mass median  aerodynamic diameter.
            Number of test points  (minimum of  two  replicates for  each
            combination  of gas velocity  and  particle size):   30.
     After the three nozzle sizes have been determined,  the first airstream
velocity to be tested in the wind tunnel  should  be established and verified
as described previously.  The particle generating  system should then be star-
ted and the particle size distribution verified.   The  particle size, as
determined by the system operating conditions, must be within the tolerances
specified in the table.  The operator should  begin sampling by establishing
the flow rate required for a 10-iin DL. in the cyclone.              .

     At the completion of the runs,  the total and  sampler-only collection
efficiencies (B. .  and E   ) should  be determined  from equations 2-3 and 2-4.
               cot      s am
For each of th* tihree gas stream velocities tested, the  average E  and B
should be plotted! as functions of particle size  (0).   Smooth curves should be
drawn through all sizes used.  The D^Q 'or Ba should be  defined as the diame-
ter at which the B  curve crosses 50% efficiency.
                                     28

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 2.2.6.2   Performance  Specifications  for  PM10  Cyclones- -
     The performance specifications  for  a  PM1Q  cyclone  are  shown in Table 2.
To be  acceptable  for use, the  E%0  for  the  sampler  (determined from the E
curve  as described previously) must  be 10  ±  1 urn.   In addition,  all data
points used  to determine the B curves for each of  the  gas  stream velocities
tested must  fall  within the banded region  shown in  Figure 12.  The portion of
the acceptance envelope corresponding  to large  particles  is bounded by a
vertical line at  12 um, a horizontal line  at 90% efficiency, and a lognormal
function (oblique line) with geometric standard deviation (o ) of 1.7 and 50%
                                                             9
efficiency at 12 um.  The boundary at  small  particle sizes  has a vertical line
at 8 um and  horizontal lines and lognormal functions which  vary  between three
ranges of gaa stream velocity.  These  horizontal lines  are  at  10, 20, and 30%
efficiency,  respectively, with increasing  gas velocity.   At the  lowest range
of velocity  the lognormal function has a   of 1.7 and 50%  efficiency at 8 um.
                                         9
For the two  higher velocity ranges,  the  lognormal functions have 55% effi-
ciency at 8  u« and values of a  of 2 and 2.9, respectively, with increasing
                              9
gas velocity.
   TABLE 2.  PERFORMANCE SPECIFICATIONS FOR SOORCE PN10 SAMPLERS—CYCLONES
          Parameter
Units
Specification
  1. Collection Efficiency
           Such that collection efficiency
          falls within envelope specified
           in Figure 12
  2. Sampler 50% cut point
           10 ± 1 um aerodynamic diameter
                                    29

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g
\
0
\
z
o
§
3T100






99
90
80
70
60
SO

40
30
20

10
5
1 1 1



—
—
—
S/)
1 1 I__



/
/ —
/ —
/ —

// /
"V / / /

9 < v < 17 m/t / /
/

v < 9 m/t /
/

1 II

,
/ 	

••«•






i r
1 2 4 8 8 10 20 40
AEROMWaC OWOER. m tm
-------
   CYCLONE I DIMENSIONS
         BOTTOM EXIT

nc


-




0*H 0 D, B
cm 127 447 1.50 1.88
h. O50 1.76 0.59 0.74


c ,:


\
B—


OIMEN2
H
6.95
174



_
i


•»

ION
1
2w
0.1





*
j
1

m
s
i
u
u



Q
•
/
^
0'.
P "^
/in. 1 0.01)
\emi0.02
z
I 471
I 1.85


t
s
i
i •
(
;
H«



S
1.5*
0.6:


'

1
1
'
MP



J
I





1




125 445 1.02 1.24
0.89 1.75 0.40 0.49
IIII-UA
Figure 13. Cyclone I dimensions.



          31

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                                   SECTION 3

                                  CALIBRATION

     As in Method 5 or Method 17, calibration of specific components of the
BGR sampling system is required.  A notebook or other record should be kept of
all calibration data pertinent to each EGR system.  This record should contain
the complete calibration history of each ievice requiring such service  (i.e.,
flow metering devices, pitot tubes, nozzles, thermocouples, and magnehelic
gauges).  A separate record may be desirable for support equipment such as
balances and field barometers, which are not directly connected with the EGR
system.

3.1.  FLOW METERING SYSTEM

     The best calibration of a flow metering device is achieved when the
calibration data are restricted to the range of expected use.  The defined
Method 5 flow ra<:e of 0.75 dscfm provides a finite range of flow  rates over
which the flow metering system should be calibrated.  However, the PMjo flow
rate depends on Uhe characteristics of the sampler used and cannot be easily
defined as a single value.  This makes defining a calibration range for the
flow metering devices difficult at best.  For the purposes of this manual, the
FMjg flow rate at typical meter box conditions is assumed to be 0.50 acfm.
For BGR sampling^ the'range of potential sample flow rates then becomes 0.1 to
0.5 acfm.  The investigator must determine the applicability of these flow
ranges to his particular system.

     The four flow metering devices of the EGR system (dry gas meter, sample
orifice, total LFE, and recycle LFE) should undergo a stringent laboratory
calibration prior to field use.  Thereafter, the calibration should be checked
after each test series.  This calibration check procedure ensures that  the
                                    32

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calibration parameters  assigned  to the flow metering devices are still valid
without requiring  the level of effort  of the initial calibration.   Should the
results of the calibration check fall  outside acceptable limits, the flow
metering device  in question should be  recalibrated by using the initial cali-
bration procedure.

     A leak check of the  flow metering system should be performed  before
calibration.  The leak  check of  the vacuum  (negative pressure)  system should
be performed according  to the following procedure:

     1) turn on  the pump, close  the recycle valves,  and completely open the
        total flow, fine-adjust  valve;
     2) plug the sample inlet of the control console, and adjust the total
        fJow, fine-adjust valve  until  a vacuum of  25 in.  Bg is  achieved;
     3) observe  the gas meter reading  for 1  min.

     If the gas meter registers  a leak rate in excess of 0.005  cfm, the leaks
must be found and corrected until the  above specifications are  met.

     The positive pressure side  of the system should also be leak  checked,
from the vacuum pump to the sample orifice  and recycle outlets, according to
the following procedure:
     1.  open the recycle valves and close  both the  total flow, coarse- and
         fine-adjust valves;
     2.  plug the vacuum pump exhaust  at the inlet  to the control  console (if
         a quick disconnect with a leak-free check  valve is used here, a plug
         will not be needed;
     3.  plug the recycle gas outlet;
     4.  place a one-hole rubber stopper with a tube through the hole in the
         outlet of the  sample orifice.
     5.  attach l«tex or  similar tubing to  the tube;
     6.  blow into the  tubing until  a  pressure of  approximately 20 in. H20 is
         registered on  the total m inlet  pressure magnehelic  gauge;
     7.  observe the gauge reading  for 1 min.
                                    33

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     If a loss in pressure occurs, a leak(s) is present  in  the  system.   All
leaks should be corrected before calibration.

     A calibrated wet test meter or any other such calibration  standard  should
be used to calibrate the EGR flow metering system.  The  outlet  of  the calibra-
tion standard ohould be connected to the sample inlet of the control console.
Before the calibration is started, the EGR vacuum pump should be run for 15
rain with the orifice meter AH set at approximately 0.5 in.  H.O  to  allow  the
pump to warm up and to wet the interior surface of the wet  test meter.

     Calibration of the EGR flow metering system must be performed in two
separate steps, the second step being the calibration of the recycle system
components.  Calibration of the dry gas meter, sample orifice and  total  flow
LPE iihould be performed as follows:

     1)  close the recycle valves and open the back-pressure valve>
     2)  perform the calibration as required in EPA Reference Method 5
         for a irange of orifice AH settings:  0.5, 1.0,  1.5, 2.0,  3.0,
         and 4.0 in. J^O  (the minimum wet test meter volume for each run
         should be 5.0 ft3, except for the two lowest flow  rates where
         a volume of 3.0 ft3 is acceptable).
     3)  record the total LPE pressure differential, inlet  pressure, and
         temperature, in addition to the data requested  in  Method  5.

     To effectively cover the range of possible sample flow rates, a set of
orifices is recommended.  Suggested orifice diameters are given in Section 2.
Calibration of the complete set should be performed before  testing. For each
orifice, the calibration procedure should be performed by using the AH set-
tings listed above, neglecting those that fall outside the  sample  flow range
described previously.
                                    34

-------
The  recycle  LFB snould  be calibrated as follows:

      1)  open both  recycle valves  and close the back -pressure valve;
      2)  perform the calibration procedure for  recycle AP values of 0.5, 1.0,
         1.5, 2.0,  3.0,  and 4.0 in.  H20 (the minimum wet test meter voluae f.o::
         each run should be 3.0 ft3);
      3)  record the recycle LPB pressure differential, inlet pressure, and
         temperature, as well  as the wet test meter  volume,  temperature and
         calibration run time.

      The calibration constants for the dry gas  meter and orifice I'Y and AH@,
respectively) should be  calculated as outlined  for Method 5.  The behavior of
the  total and recycle L?Bs may be best described  by  the equation

                                         u
                               Q • SAP (-S)  +  W                         (3-1)
vnere    u am m viscosity of standard  air  (180.1 micropoise) ,
          ST
          u  • viscosity of sample gas  (micropoise) ,  and
           it
        S,W  • linear calibration constants.
The calibration constants S and W may be obtained  by plotting the calibration
data points and determining the best-fit line.  A  linear  regression on the
data is another alternative.
                                                       i
     A calibration check should be performed on all  of the flow metering
devices after each field test series.  The post test  calibration check should
consist of three calibration runs at a single orifice setting.   This orifice
setting should be representative  of the orifice settings  used during the field
test.  The run procedure should be the same as described  for  the initial
calibration of the dry gas meter, orifice, and total flow LPB.   At the end of
each run,
     t)  record the final wet test meter and dry gas meter readings,
     2)  restart the pump without changing the total flow settings,
                                     35

-------
     3)  open both recycle valves and close the back-pressure  valve/
     4)  record the pressure differential across the recycle LFB.

     If the dry gas meter calibration factor, y, deviates by less  than 5%  from
the initial calibration factor, then the calibration constant  assigned to  the
meter is atill valid.  If the posttest calibration check yields  a  calibration
factor outside th:is limit, the gad meter should be recalibrated  by using the
initial calibration procedure.

     The average oreasure drops across the sample orifice,  total LFS,  and
recycle LFE recorded during the calibration check should be compared with
those obtained frcn the calibration equation for each device.  The AP  is cal-
culated from the calibration equation by using the wet  test meter  flow rate
corrected for temperature and pressure at each of the devices.   If the
recorded APs vary from the calculated values by more then  10%, the flow
metering device should be recalibrated.

     If either the dry gas meter or total flow LFE requires recalibration, for
the purposes of data reduction, use whichever coefficient  (initial or  recali-
brated) yields the lower gas meter volume and higher cyclone flow  rate.

3.2.  PITOT TUBE

     The construction, configuration, and calibration specificationc outlined
in EPA Reference Method 2  (U.S. EPA, 1977) should be applied to  the EGR pi tot
tube.  The pitot tube should be located at the side of  the  nozzle  furthest
from the axis of the PM10 sampler.  To check the pitot  tube for  leaks, one end
of the tube should .be plugged and a positive pressure applied  at the opposite
end.  If the tube will not maintain pressure, a soap solution  can  txs used  to
identify the location of any leaks.  The EGR pitot tube is  calibrated  by
measuring the velocity pressure, AP, at the same point  within  a  cross-section
of a straight run of ductwork with a standard pitot tube and with  the  S-type
EGR pitot tube for a desired range of gas velocities.   The  EGR pitot tube
should be calibrated as used; that is, the complete sampler assembly shO'jW be
used in pitot tube calibration determinations.  The EGR pitot  tube should  be
                                    36

-------
calibrated  twice, as recommended  in Method  2, with  the  direction  of  the  legs
reversed during the second calibratrion.  For each  velocity, determine a pitot
tube coefficient as
                                         "     '"
where     C  - EGR 3 -type calibration cc  fficient, dimensionleec;
           P
        0.99 • C  value for standard pitot tube, dimensionless;
                P
       AP _ • velocity pressure drop of  standard pitot tube,
         STD
               inches of water i and
       AP__ • velocity pressure drop of  EGR S-type pitot  tube,
         BGR
               inches of water.
The average value of C  for each direction over the  range of  velocities  used
                      P
should be calculated.
3.3.  BGR NOZZLES

     The BGR nozzles are calibrated in the following manneri

     1)  use a micrometer to measure the inside diameter of the EGR  nozzle  to
          the nearest 0.001 in.;
     2)  make four separate measurements by using different diameters  each
          time and obtain the average of the measurements.

     The largest deviation from the average should not exceed  0.004  in.   If
the variation is more than 0.004 in., the r
-------
3.4.  THERMOCOUPLES

     The thermocouples used to measure the various temperatures withi:. the EGR
sampling train (Chromel-Alumel; type K) should be checked for proper calibra-
tion before installation in the system.  A two-point calibration check with  an
ice bath and a boiling water bath should be performed  as outlined  in EPA
Reference Method 2.  If any individual thermocouple does not produce a reading
within 3* of the expected value, it should be replaced with another thermo-
couple of the same type.  If all thermocouples show a bias, the readout should
be adjusted or recalibrated according to the manufacturer's procedure,

3.5.  MAGN3HELIC GAUGES

     The calibration of the magnehelic differential pressure gauges should be
checked before field use and periodically thereafter to prevent invalidation
of test data,  liefore its calibration is checked, the magnehelic gauge should
be zeroed by using the external zero-edjust screw.  A  calibration  check is
performed by comparing AP values/ as read from the magnehelic gauge, with
those from an inclined manometer at a minimum of three points.  The 69 values
read from the magnehelic gauge should not deviate from the inclined manometer
readings by more thrn 5% at any point.

3.6.  SUPPORT EQUIT— at

     The field barometer should be adjusted initially  and before each test
series to agree with a standard (a mercury-in-glass barometer or the pressure
reported by a nearby National Weather Service station) to ±0.1  in. Hg.

     The calibration of all balances to be used during a test series should  b«
checked initially with Class-S weights.  Trip balances should be within ±0.5 g
of the standard.  Analytical balances should agree to  ±2 mg "t  the standard.
Balances that fail to meec these criteria should be adjusted or returned  to
the manufacturer,.
                                    38

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                                  SECTION 4

                             PRBSAMPLZNG ACTIVITIES

     Preparation of the BGR  sampling  system for  field use requires much the
same effort  as preparation for  Method 5 or Metliod 17 sampling.  Some type of
pretest calibration or operation  check is necrssary for most components of the
system.  This is also true of supporting equipment such as analytical bal-
ances.  Sampling reagents also  require preparation before field use.  In
several cases, the presampling  activities described below are very similar to
or the same  as those required for Method 5.

4.1.  EQUIPMENT CALIBRATION  AND CHECKS

     All EGR sampling nozzles should  be inspected for damage and repaired
where necessary.  The nozzles should  be cleaned  with tap water, deionized
water, and finally acetone.  The  dimension of  the inside diameter of each
nozzle should be determined  to  the  nearest 0.001  in. as described in Section 3
of this manual.  The knife edge of  the nozzle  should be protected during ship-
ment by serum caps or similar covers.

     The PMj0 sampler and filter  holder should be ultrasonically cleaned with
tap water and rinsed with deionized water.   After a final rinse with acetone,
the sampler  assembly should  be  allowed to air  dry.   An adequate supply of
Viton or silicon* rubber O-rings  should be available for replacement of worn
0-rings in these devices.

     The openings of the pitot  tube should be  inspected for  damage such as
dents or nicks.  A check should also  be made for  proper alignment.  The two
legs of the  pitot should be  in  a  straight line so that the opening of one leg
is directed  180* from the other.  If  damage or misalignment  is evident, the
                                    39

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pitot tube should be repaired or replaced.  If repairs  are made,  the  pitot
tube should be recalibrated/ as described in Section  3.

     All lines of the EGR probe, including the recycle  and pitot  lines,  should
be cleaned before field use.  The lines should be cleaned internally  by  rins-
ing, first with tap water, then deionized water  followed by  acetone.   The
lines should b« rinsed a final tine with acetone and  allow to  air dry.   The
probe heating siystem should be checked for proper operation.   If  problems are
encountered, the operator should refer to Section  10  of this manual  for
troubleshooting guidelines.

     The water dropout system (condenser and drying column)  should be checked
for leaks.  The condenser should be cleaned with deionized water  and  rinsed
with acetone.  The condenser should be inverted  to ensure total drainage and
allowed to air dry.

     The system flow metering devices  (dry gas meter, orifice, total  LFE, and
recycle LPE) should have appropriate calibration factors assigned to  them.  A
pretest calibration check, performed with the procedure outlined  for  posttest
calibration checks in Section 3, is recommended  to ensure the  calibrations are
still valid.  Although pretest calibration checks of  the flow  metering devices
are not required! and do not take the place of the posttest checks, they  are
useful for detecting problems before field use.  Such a pretest calibration
check is strongly recommended if the system has  not been used  for some time.

     It is recommended, but not required., that the calibration of the magnehe-
lic pressure differential gauges be checked prior to  field sampling.   As with
the flow metering system, this is strongly suggested  if the  system has not
been used for an extended period of time.

     All system temperature sensors (thermocouples, temperature gauges,  etc.)
should be checked against a mercury-in-glass thermometer at  ambient  tempera-
ture.
                                     40

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     Finally,  it  is  recommended  that a leak check of the complete system be
performed before  it  is  shipped to  the field.   The system should be assembled
from the pcobe  (it is not  necessary to include the EGR nozzle or PM10 sampler)
to the control console.  The  probe should be capped and the system leak-
checked at  15  in. Hg vacuum.  Leak check in excess of 0.02 cfm should be
corrected.  Bach  leg of  the pitot  tube,  including the umbilical lines and the
differential pressure gauge,  should be leak-checked.

4.2.  PREPARATION OF SAMPLING REAGENTS

     Used silica gel should be regenerated by drying  at 350 *F for 2 h.  New
silica gel may be used  as  received.  Several  200- to 300-g portions raay ,.be
weighed in airtight containers to  the nearest 0.5 g.   The total weight for
each container should be recorded.   As an alternative, the silica gel may be
weighed in the drying column  at  the test site.

     Filters should be desiccated  and weighed as required for EPA Reference
Method S.  To prevent the  loss of  filter cake,  it is recommended that aluminum
foil envelopes be made  to  enclose  the filter.  If used, these envelopes should
be desiccated and weighed  with the  filter.

     Aluminum foil envelopes  can also be used to collect the PM.Q cyclone
catch.  These foil envelopes  should be uniquely identified, desiccated, and
weighed in the same manner as the  filters.

     Acetone for sample  recovery should  be reagent grade with less than 0.001%
residue.  Acetone blank  deterainations to ensure residue levels are acceptable
may be male before field use  or  as  part  of  sample recovery.
                                     41

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                                   SECTION 5

                              SAMPLING PARAMETERS

     During Method 5 sampling, the operator must be able  to convert  the
velocity pressure and stack temperature at multiple traverse points  into  the
sample flow race needed to maintain isokinetic sampling.  This  flow  rate  is
then translated to a pressure differential across the sample orifice which the
operator can adjust.  There are a variety of methods  (nomographs, hand calcu-
lator prograo.3,, etc.) for doing this in a few simple  steps.

     Isokinetic sampling must also be maintained with the EGR system.  How-
ever, the EGR siystem introduces complications in the  form of additional  flow
rates that must be monitored in the same Banner as the sample flow rate.  This
section describes two methods for accomplishing this objective.  The first
method described provides an exact solution to the governing equations.   The
multiple iterations required to obtain this solution have prompted the deve-
lopment of the second method, an approximate solution to  the equations that
avoids the necessity of iterations.

5. 1.  PRELIMINARY MEASUREMENTS

     Before the appropriate sampling parameters can be calculated for the EGR
system, some type of preliminary determination of the stack gas conditions
must be made.  Stack temperature and velocity profiles of the sampling plane
may be obtained from Method 2 data.  This information is  necessary for the EGR
setup and nozzle selection calculations discussed later in this section.

     The concentration of the primary stack gas constituents  (i.e.,  oxygen,
carbon dioxide/ nitrogen, carbon monoxide, and water  vapor) may be determined
                                                        s

                                    42

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from Method  3  and Method  4 data.   With this information, the gas dry and wet
molecular weights  (M) may be determined from the following equations:

                    M   -  32(f ) + 44(f )  + 28(1 - f  - f )              (5-1)
                     doc            o    c

                            M  - M.(1  - B  )  + 18 B                      (5-2)
                             w    d      ws        ws

where B   •  the water fraction.
       ws

It may be necessary to  perform additional methods in cases where the stack gas
composition  is influenced by gases other  than those listed above.  For
example, when  sampling  gases from a high-sulfur source, Method 8 should be
performed to determine  the percentage of  H2SO4 present in the gas as vapor and
the acid dew point.

     The viscosity  (u)of  the flue gas can be determined by the equation
(Williamson  et al., 1983)
                             «• C2T  * C3T2  * C.B   * C5f                (5-3)
where u is in nicropoise, T  in  *C,  and
          Cj »  160.62
          Cj •  0.42952
          C3 -  1.0483 x  10-1*
          C,, -  74.143
          C; •  53.147

or for T in *R
          G! "  51.05
          C2 •  0.207
          C3 -  3.24 x 10-5
          G, •  74.143
          C  -  53.147
                                     43

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     This equation fits data  (with  a  standard  error  of  0.98  micropoise)  for
combustion gas of arbitrary composition  in  the range 0-350  *C,  0-70%  moisture.
this equation was generated by SRI  personnel from  large "data banks*  of visco-
sities calculated by the more rigorous algorithm of  Wilke  (1950).   Finally,
the location of the traverse points should  be  determined as  outlined  in
Method 1.

5.2.  BGR FLOW RATES

     The flow irates of interest  in  the BGR  system  are the sample flow rate
(Q ), total flow rate  (Q ), and, of secondary  interest, the  recycle flow rate
  8                     C
(Q ).  At each point of A  sample traverse,  these three  flow  rates must be
determined and then converted to pressure differentials across  the appropriate
flow metering device.

     The sample flow rate  may be determined in the same manner  as in  Method 5
from the equation
The total flow rate through  tho  PM1()  sampler  is,  in principle,  fixed by the
characteristic" of the sampler.  For  SRI/EPA  Cyclone I,  the flow rate equation
for a 10-um cut: diameter takes the  form

                                         N  p   -0.29-9
                         Qfc  • 0.002837   (-J-S)        u                  (5-5)

     Onfortunately, equation 5-5 cannot  be  solved in a  straightforward manner
because the wet: molecular weight and  viscosity terms are dependent on the
aj»unt of moisture in the total  flow.  This cannot be easily determined
because the total flow through the  cyclone  is a mix of  sample gas (with a
known moisture fraction) and recycle  gas (dry).   Solution of this equation
requires iterations of Q. until  a desired resolution is  achieved.  Once Q  has
been determined in this manner,  the recycle flow  rate may be calculated as the
difference between the total and sample  flow  rates.
                                    44

-------
     As  an  alternative to the solution described above/ an approximation may
be made  that  avoids  the necessity of iterations on Q .   Such an approximation
•ay take several  forms.   Of  primary importance is the accuracy of the approxi-
mate solution over the range of  potential sampling conditions.  The total flow
approximation discussed below agrees with tha exact solution of the equation
to ±1% for  stack  temperatures ranging from 100 to 500 *F and stack gas
moisture up to 50%.

     During a sample traverse, the total  flow through the PMj0 sampler at any
given time  is a mix  of moist sample gas and  dry recycle gas.  First, Q  is
defined  aa  the PtL.  sampler  flow rate when the total flow is composed entirely
of sample gas with a known moisture fraction (zero percent recycle).  At the
other limit,  Q is defined as the PH..  sampler flow rate when the total flow
is composed entirely of  dry  recycle gas (100% recycle).  Q  must fall some-
where between these  two  extremes.   A linear  interpolation between Q  and Q
                                                                    'H      a
provides an approximate  solution for Q ,  which takes the form
                                                                        (5-6)
5.3.  TARGET PRESSURE DIFFERENTIALS  (AS, AP ,  AP )

     When all three flow rates have  been determined,  the pressure differen-
tials across the  flow metering devices must be determined for each flow rate.
The sample orifice AH may be calculated in  the same manner as in Method 5.
The pressure drop across the total and recycle LFEs may be found by using the
calibration equation, corrected  for  local conditions, presented in Section 3.
For the total flow LFB,

                                     45

-------
Similarly, for the recycle LPE,





                    Apr - ^  C^  r  ^  (Qt - V - r 1             <5-8>
                           ST    r   L   a              r



     Although an exact solution of equations 5-7 and 5-8 could be obtained

iteratively, it is only necessary to utilize the approximate solution  for Q  .

Using the approxim solution given in equation 5-6, the term of interest  in

equation 5-7 is
                                     - V-
By using the approximation for Q  given above, this becomes





                                       VQd -Qw}
                     Q  - Q B   20  -- - — - - - -- Q B
                     Ut   U8 wa   Ud       Q         Us ws
     Prom the flow rate equation for the PM1Q sampler  (equation  5-5)  and  the


definitions given previously, we can obtain equations  for Q  and Q .
                                                            w       d


                                       M P  -0.29<»9

                        Qw - 0.002837  (-*_£)        uw                 (5-10)
                                      M p  -0.29W9

                       Qd - 0.002837  (-|-S)        ud                   (5-11)





where v  is the sample gas viscosity  and u   is the recycle gas  viscosity.
       w                                  a
                                    46

-------
Talcing the ratio of these two flow rates and simplifying



                             Q      M  -0.2949
                                               -                       (5-12,
     By solving M  and u  in terms of M. and u  and substituting into  the
                 W      w              da

above equation


     Performing a binominal expansion on the first term of this equation


yields





              t1 -•-.t1 -r)l       H 1 * °*2949 C"8*,0 -ir*]       (
                    WO     ".a                         wa     n •
                            a                                 a



After substituting into equation 5-*3 and simplifying, we have
                (B   v  (l - 0.2949(1 - — ))•»• 74.143
           y.     wo  Q                 M.
           Qw                      Ud - 74.143 B
                                                                        (5-15)
                                                ^
     Finally, to obtain the pressure differential across the total flow LPE,


which corresponds to total flow, Q., in the PM10 sampler/ we apply the equa-


tions for Q  (equation 5-4), Q  (equation 5-11), and Q./Q  (equation 5-12) to
           s                  a                       d  w

equation 5-15.  The result is the expression for AP  shown below:

                                    47

-------
where
                                „ T   p 0.7051

                                 ' M   S
            Kx - 1.5752 x 10"5  -=-£
                                 p    M 0.29i»9

                                  L    d
                  0.1539
                                °
                          - 0.2949(1 - ^)J - 74.143

                                       Md
     Taking a similar approach for the recycle LFE pressure differential,  we

see that the term of interest in equation 5-8 is
                    Qt * Qs
Applying the Q  approximation,
                                    VQ

                             3 Qd -
                             2 Qdry
Following the stops discussed previously to determine AP  ,  the equation  for

AP becomes
  r
                                    48

-------
where
                             „  T   p 0.7051
           K.  - 1.5752  X 10-5 --
                           .    PL
                0.1539 UL M "
                           PL
                  -0.2Cbl M -0.29<»9
                         "
                          d          U
-------
                                 EGR WORKSHEET I

                                   ORIFICE AH
Baronetric Pressure, ?a/  in.  Hg  •
Stack Differential Pressure,  0  Stack,  in.  B20


Average Stack Temperature, TS,  *R » __________


Meter Teaperature, TM,  *R • _________________


Gas Analysis:
          COj Fraction,  f  »  	
          Oj Fraction,  f • 	
          Watei: Fraction;
Calibration DaUa:
          Nozzle Diaaecer, d  ,  in.
          Pitoi: Coefficient,  C_ -
     44 (fc) + 32  +  18(Bws'
          0_ Stack
p  - p  +  p.^
rs   *a     13.?
A0 - 846.72
   ' Ao APvel
                    /4.  f G^ »fwp calculation worksheet I: orifice


                                    50

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                                BGR WORKSHEET II

                                TOTA'.  7LOW LFB AP


Barometric Pressure Pa/ in. Hg »	


Stack  Differential Pressure, 0  Stack,  in.  B.O -


Average  Stack Temperature, Tg, *R  • ______________


L7E Temperature,  TM, "R • __________________


Cas Analysis*
           CO_  Fraction, f  • _
           Oj Fraction, f  • __
           Water Fraction, Bw>
Calibration  Data:
           Nozzle Diameter, dR, in.
           Pitot Coefficient, C_ •
           st  " 	
     44(fc)  + 32
-------
                           BGR Worksheet  II  (Continued)
        5752
        5'«
                  ,   ULTL p 0.7051
                 -5     b fa  8        a

       0.1539
             '  - 0.2949(1  - i)  +  74.143  Bws(1 - Bwg)
     st
-
Bt
                         UL    Wt
             /5. £G/? setup calculation worksheet II: total flow LFE &P (sheet 2 of 2).


                                      52

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                                BGR WORKSHEET III

                              RECYCLE FLOW LFB AP
Barometric Pressure,  Pa,  in.  Hg » _____________

Stack Differential  Pressure,  0  Stack, in. H.,0 »
        Stack Temperature,  Ta,  *R »

LFB Temperature, T-,  *R « _________
Gas Analysis:
           C02 Fraction,  f  «
           O  Fraction,  fQ •
           Water Fraction,  Bwg »

Calibration Data:
           Nozzle
           Pitot Coefficient,
           Nozzle  Diameter,  dR, in. •
     44 
-------
                          EGR Worksheet III   (Continued)
A
                           " Ud -




                         ur  .   w.
 r     S(7)°.7051     180.1
          -Bc
             /6'.  EGR setup calculation worksheet III: recycle flow LFE &P (sheet 2 of 2).

-------
     To obtain  a  function of  this  type for  AH,  Apfc or APf,  stack temperature
is assumed  to be  constant.  Values for AH and AP  obtained  in this manner were
found to agree  with exact solutions to ±10% for tei&pet ature ranges of ±50 *F
around the  average and stack  gas moisture up to 50%.

5.4.  NOZZLE SELECTION
     Selection of the appropriate  nozzle  size  for  EGR sampling is not as
straightforward as  in Method  5.  Tor Method  5  sampling,  the only consideration
when choosing a nozzle size is that it must  provide  a flow rate of approxi-
mately 0.75 dscfm at isokinetic conditions.  When  sampling with the EGR
system, the recycle rates anticipated at  each  traverse point must also be
considered.  The chosen nozzle should not require  recycle rates less than 10%
or greater than 80% of the total flow.

     The first step in nozzle selection is to  determine  the PM1Q  flow rate for
the sampler at the  average stack temperature,  pressure and moisture fraction.
This flow rate has been defined previously as  Q and may be calculated by
using equation 5-10.

     The target nozzle diameter may then  be  calculated as shown below:


                         d (inches) • 1.74808   /•£•—                  (5-19)
                                              V   max

Because periodic fluctuations in duct velocity can occur, the velocity used in
the above calculation anould be the maximum  expected velocity increased by
10%.

     Once the target nozzle diameter has  been  determined, the next smallest
available nozzle size should be chosen for sampling.   The actual, calibrated
size of the chosen nozzle should be used  for all setup calculations.
                                     55

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                                   SECTION 6

                               TAKING THE SAMPLE

6.1.  FIELD ASSEMBLY

     After the EGR sampling system has  arrived  at  the  test  site  it should be
visually inspected for any damage incurred during  transport.   To check for
internal probe damage, a positive pressure leak check  on  each of the four
lines running through the probe  is recommended. This  check is performed by
blocking one end of each line and applying positive  pressure  at  the other.
The pressure on the line is monitored with a manometer connected in parallel.
Failure to hold pressure indicates an internal  probe leak,  which should be
found and repaired before proceeding.

     When it has been determined the EGR system is in  proper  operating condi-
tion, the operator should begin  assembling the  system. The  particle-sizing
device should bo assembled as its specific operating manual dictates.  The EGR
nozzle should then be attached to the sampler and  the  complete device mounted
on the probe by using tube unions, as necessary, to  attach  the sampler to the
sample line.  The nozzle recycle line should be attached  to the  temperature-
monitored recycle line on the probe.  With flexible  extension tubes of proper
length, the pi tot head should then be mounted on the probe.  The EGR sampling
nozzle and one leg of the pitot  tube must face  the same direction while all
the tubing unions are fully tightened.  A combined umbilical  or  individual
tubing can then be used to connect the  probe to the  control console.  If
individual tubing is used, the recycle  line should run directly  from the probe
to the control box.  The sample  line should be  attached to  the inlet of the
water dropout system (condenser  and silica gel  column), which is, in turn,
attached to the sample inlet of  the control console.  An  umbilical that
                                     56

-------
 encloses  the  recycle line,  the sample line, and the various thermocouple
 extensions  in a single  sheath is preferred if it is available.

     Because  the amount of  water collected from the condensing system must be
 known,  all  components of  this system sfould be clean and free of any foreign
 material.   If silica gel  columns are used, a preweight of the column and
 silica  gel  should be obtained before any testing.   Then the column must be
 sealed  until  testing begins to avoid any accidental uptake of moisture.  After
 sampling, the column should be weighed again to determine the amount of water
 uptake.   If a condenser is  used, it  should be placed in an ice chest and ice
 added to  the  chest until  the condenser is sufficiently covered.

     After establishing power  to the control console,  the multipin, electrical
 thermocouple  connector  should be attached at both  the  probe and the control
 box.  The readouts of the thermocouples should be  checked before proceeding to
 ensure  all  are working  properly. The manometer leads  should be check to make
 sure they are connected to  the correct port and that each port is in the open
 position.  The pump should  be connected to the BGR control box, with the hoses
 provided.  The pump's power cord should be plugged into the control box near
 the pump  flow lines.  At  this point  the BGR sampling system is fully assembled
 and ready for  a presampling leak check.

 6.2.  LEAK TEST

     The sampler,  probe,  condenser,  and sampling lines should be leak-checked
 before  final  assembly.  This can be  achieved by plugging one end of the line
 to be tested  and applying a positive pressure at the opposite end.  By placing
 a pressure gauge in parallel with the test line, the pressure within the
 system  can be monitored.  If the system fails to maintain pressure after it is
 sealed, a soap solution can be used  to locate leaks.

     When the system has  been completely assembled, the BGR control console
pump may be used to leak  check the vacuum system as in Method 5 by following
 the procedure  below.
                                     57

-------
     o  Plug the sampling nozzle
     o  Turn the recycle gas valves completely off/  and  turn on  the
        BGR pump to produce a vacuum across the desired  test section
     e  Ose the total flow fine-adjust valve to set  che  system
        vacuum to 15 in. Bg.

     If the required vacuum reading on the console-mounted  vacuum  gauge cannot
be achieved or if the gas meter indicates a leak  rate greater  than 0.02 cfra,
the system is not sealed and the leak(a) must be  located and fixed.

     The positive pressure portion of the control console can be tested for
leaks by using the procedure described in Section 3.  As an alternative, an
auxiliary pump-DGM system (or spare sampling system) may be used to draw a
vacuum in this portion of the system, as follows:

     e  Attach the recycle output of the BGR system, by  using latex
        or flim:ilar tubing, to the inlet of the auxiliary system
     e  Completely open the recycle valves and close the total flow
        and sample back-pressure valves
     o  Continue the procedure as outlined in the preceding
        paragraph

     The same leak-rate limit (<0.02 cfm) should  be  applied to the positive
side of the system as is used for the negative side.

6.3.  PRETEST EQUIPMENT MA3M-OP

     Because most flue streams to be tested are not  at ambient temperatures,
the BGR sampling train must be heated to stack conditions.  This helps ensure
isokinetic sampling, significantly reduces the chance of acid deposition with-
in the sample line, and allows isothermal introduction of recycle  gas at the
inlet of the particle-sizing device.  This is accomplished  through the use of
the heated BGR probe and in-the-flue heating of the  sampler.

     The sampler should be heated in the flue long enough to equilibrate with
the temperature of the surrounding stack gasses.  Typically, the PM10 sampler
                                    58

-------
 should  remain  in  the  flue  at  least  15-20 min.  to ensure thermal equilibrium.
 The nozzle,  if  uncapped, should  not point into the flow field during preheat-
 ing.  If possible,  the  nozzle should be capped or plugged during preheating,
 and the cap  or  plug removed immediately before sampling.

     The probe  temperature is regulated by a proportional temperature control-
 ler.  While  the sampling device  is  heating in  the gas stream, the probe heater
 controller should be  adjusted to heat  the recycle line to stack temperature.
 When condensible vapors are present,  the probe should be  heated to and main-
 tained above the dew  point.   Care should be taken to ensure  that vapor does
 not condense in the portion of the  probe extending outside the duct and flow
 back into the sampler.

 6.4.  PLOW RATES

     As stated  previously, the flow rate through the sampling nozzle is
directly dependent on the stack  gas velocity at the sample point.  In opera-
 tion, therefore, the  pressure drop  across the  sample orifice, AH, is adjusted
 according to the previously determined run calculations with shifts in the
pitot AP readings.  This ensures continued isokinetic sampling.  In turn,  the
 flow rate of the recycle gas  must also be adjusted to maintain the proper
 total flow through the  particle-sizing device.   During start-up the operator
 initially sets  the total sampler flow  rate by  using valves Vj and V2.  After
setting the  approximate total flow  rate,  the sample flow  rate is set by
 adjusting the recycle valves  V3  and V4.   if hiqh recycle  ratios are required,
the back-pressure valve, V$,  nay need  to be adjusted.   Because there is some
 interaction  between flow rates,  a few  minor repeat adjustments may be required
between the  total and sample  flow rates.   Typically,  when traversing to
 another sampling point, only  the fine  recycle  adjust (V^)  or the sample back-
pressure valve  (V5) will need adjustment.   These point-to-point adjustments
may require  slight adjustment to the total flow.  If so,  repeat the iterative
process outlined above  until  the target AP and AH sample values are achieved.
The practiced operator  can usually  obtain the  target values  within one or  two
 iterations at each new  point.
                                     59

-------
6.5.  TRAVERSING

     During traversing  (moving to a new point or new port),  all motion should
b« smooth and brief to  avoid bumping or vibrating  the  sampler.  When  removing
or inserting the sampler, care must be taken not to scrape the nozzle on che
port wall.  Also, the sampler should not be allowed to bump  against the far
inside wall of the duct.

6.6.  PU3W RATE CHECKS

     During sampling, a quality assurance check of the flow  rates through the
EGR system should be performed periodically to ensure  proper operation.  By
definition, the total flow through the EGR sampling system is the sum of the
recycle and sample gas  flows.  For example, if the total  flow LPE reading
relates to 1.0 cfa and  the sample orifice pressure relates to 0.6 cfm, the
reading on the recycle  LPE must relate to 0.4 cfm.  The EGR  setup equations
use this principle to calculate the orifice, total LPS, and  recycle LPB set-
tings for a given atack temperature and velocity AP.   Therefore,  when the
total LPB and s<«pl>) orifice pressure differentials have  been set to  the
appropriate values, the recycle LPB reading from the control box  should agree
with the value provided by the setup calculations  to ±10%.

     If the flow* are fairly constant, the EGR dry gas meter may  also be used
as a quality assurance  check.  By measuring the seconds per  revolution of the
gas meter rotation needle, the sample flow rate can be determined.  This, by
definition, is the difference between the total and recycle  gas  flow  rates.

6.7.  SHUTDOWN ORIENTATION

     Depending on the orientation of the sampler,  it may  be  advisable to
maintain an appreciable flow rate while removing the sampler from the flue.
Extreme care must be taken during removal so the sample is not contaminated by
dust from the port walls.  The flow rate should be maintained until  the samp-
ler can be placed in a  favorable orientation (usually  horizontal).  This is
particularly true when  operating a cyclone in a vertical  orientation.  Other-
                                    60

-------
wise, some dust might fall from one stage of the  sampler  to  another  and  thus
be measured where it was not collected.  After the flow has  been  terminated,
the sampler can be transported to the laboratory.  It  should be kept  in  a
horizontal position with the nozzle plugged or covered to  avoid contamination
or loss of sample.

6.0.  DATA LOGGING

     The parameters of the test should be recorded in  a clear, concise format
like that shown in Figure 17.  Parameters that are likely  to change,  such as
sample and recycle gas flow rates, should be recorded periodically.   Other
examples are port number, traverse point, gas meter  temperature,  gas  meter
volume, metering orifice and LFE pressure drops,  atmospheric pressure, stack
gas temperature, etc.
                                    61

-------
Run
Coda
10
FUtar
ID
Orlantation
Location
Msala
OlaMtav-tO (in)
Oo«eatox< *)
Data i
1
Start C
YilBat 1
Snd /
(aMpllaf 1
Duration lain) 1
OGH ' (
(initial) %
OGM a
( final)
Saapla
volvaM ( ft1 1
Dual Manoaatar Uivalad «nd Zaroad?
Maanahalica Zarmid?
Ron
ttj»a

























Port No
Tra».?t.

























1'itot

























Sa£l.

























oo«

























Total

























Itack
•aaearatora Cr)
litfacaatial Stack
raaaura (in.R.O)
Mbiane
•aaoacatura ( *T)
•biane
^r««ura (in.M)
>aa
raloeity
lyatan Laak Chack
Inlut

























Raeyela

























Stack

























Gaa Composition
%CO. »O? «CO
Hoiatora Contant
rltot Laak Chack
(real (Maa)
Kotaa
(acycla

























rroba

























Ln

























H.
























''
                                                           •tll-ll
Figure 17. Suggested EGR run sheet.
                 62

-------
                                    SECTION 7

                                SAMPLE  RETRIEVAL

     After the sampling system  has  been  allowed to cool to a point where it
can be safely handled, the collected sample may be carefully recovered.

7.1.  RECOVERY OF THE PARTICDLATE MASS

     Great care is needed during recovery  of the collected particles from the
PMj0 sampler to ensure that all of  the particulate matter  is recovered and
placed in the proper sample containers.  The sample can be effectively recov-
ered from both stages of the PM10 sampler  (cyclone and  filter)  by using a com-
bination of brushing and washing.

     The first step in recovery of  the particulate matter  from the nozzle and
cyclone is brushing the collected mass into the appropriate foil envelope.  A
clean no. 7 camel's hair brush  or small  nylon bristle brush is suggested for
this operation.  The brushed surfaces  should then be rinsed thoroughly with
acetone, or similar solvent, to recover  any particles that continue to adhere
to the sampler.  These rinses should be  collected in a  uniquely identified
sample container.  The brush used for  recovery should also be rinsed into this
container.

     The fil:er should be recovered from the filter holder and returned to the
appropriate container.  Any particulate  matter or filter fibers adhering to
the fi'.rer holder surfaces or rubber 0-ring should be brushed onto the surface
o   .ne filter.  The interior surfaces  of the filter holder should then  >e
rinsed with the solvent as described above.
                                    63

-------
     As stated previously,  assignment  of  the collected pait^culate natter to
che appropriate siampla container  is  very  important.   Particulate matter
collected from the  inner  surfaces of the  BGR nozzle,  the cyclone body, collec-
tion cup and cap are to be  considered  as  collected by the cyclone.  Further-
more, any matter brushed  or rinsed  from the  outside  of the cyclone exit tube
is also to be considered  part of  the cyclone catch.   The PM..  fraction
consists of particulate matter  collected  from the inner surface of the "turn-
around" on the cyclone cap, the inside wall  of the exit tube,  the inner walls
of the filter holder (upstream  oC the  filter), and the surface of the filter.

     Final weights  for all  particulate samples should be determined on site,
prior to shipment.  Recommended procedures are outlined in Section 8.

7.2.  MOISTURE DETERMINATION

     The condenser  should be drained of any  collected moisture and the amount
of liquid determined either volumetrically  (to ±  1 aL) or gravimetrically (to
±0.5 g).  The liquid may  be discarded  after  the weight or volume is recorded.
The spent silica <;el should be  weighed in the appropriate container  (such as
the drying column or shipment container)  to  determine the moisture uptake.
                                     64

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                                  SECTION  8

                             POSTSAMPLING  CHECKS

     Posttest  activities  for  the  EGR system  involve  equipment calibration
checks,  field  sample  analysis,  and  equipment  maintenance.   The first two
items will be  discussed in  this section.   The third  item is discussed in
Section  10 of  this manual.

8.1.  EQUIPMENT CALIBRATION CHECKS

     A posttest calibration check of the  flow metering  devices is required.
The posttest calibration  checks should  be performed  as  described in Sec-
tion 3 of this manual.  If  the gas  meter  ' .erection  factor  obtained from
the calibration check deviates  from ths initial calibration factor by more
than 5%, the meter should be  recalibrated.  The posttest data reduction
should then be performed  with whichever calibration  factor  yields the lower
gas meter volumes.  If the  calibration check  of. the  total  flow LKE deviates
from the initial calibration  by mote than 101, the L?B  should also be
recalibrated.  The calibration factor used for data  reduction should be
that which yields the higher  cyclone flow rate.

     Calibration checks should also be performed on  the stack, dry gas
meter, and L?B thermocouples.  Each of the above temperature sensors should
be compared with a mercury-in-glass thermometer at ambient  temperature.   If
the stack temperature thermocouple  reading differs from the reference by
more than 1.5% of the absolute temperature, the thermocouple should be
recalibrated as described in  Section 3.   The  old and  new calibrations
should be compared to determine the sign  and  magnitude  of  the correction to
be applied to  the average stack temperature.   If the  DO! or L?B thermo-
couple readings vary from the reference by more than  6  *C  (10.8 *F), the
                                  65

-------
thernocouples should be recalibrated.  For data  reduction  calculations,  the
calibrations that give the higher DGM or LFE  temperatures  should  be used.

     A posttest calibration check is also required  Cor  the system raagne-
helic gauges.  This calibration check should  be  performed  as described in
Section 3.

8.2.  SAMPLE ANALYSIS

     Analyuia of the EGR field samples is essentially the  same as for
Method 5.  filter and cyclone catches should  desiccate for a minimum of
24 h before the initial weighing.  Each sample shouoJ be weighed  to a
constant wight, which is achieved when the difference between consecutive
weighings Is no more than 0.5 mg or  1% of the total weight less tare
weight, whichever is greater; no less than 6  h of desiccation time should
be allowed between weighings.

     As an alternative, the samples may be oven  dried at the average stack
temperature or 220 *?, whichever is  less, for 2  to  3 h, cooled in a
desiccator„ and weighed to a constant weight. The  tester  may also opt to
oven dry the samples as described above, weigh the  sample, and use this as
the final weight.  Whichever option  is chosen/ final weights of all cyclone
and filter samples should be determined to the nearest 0.1 mg on  site,
before shipping.

     Acetone rinse and blank samples should be inspected to confirm that no
leakage hati occurred.  If a noticeable amount of sample has been  lost
through leakage, the sample must either be declared void or corrected ir.
the final results with methods approved by the sponsoring  agency.  The
liquid should be measured either volumetrically  to  ±1 mL or gravimetrically
to ±0.5 g.  Each sample should be evaporated  to  dryness at anbient tempera-
ture and pressure in a tared 250-mL beaker or smilar container.   The
evaporated samples should be desiccated for 24 h and weighed to a constant
weight.  Results should be recorded  to the nearest  0.1  rag.
                                  66

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     If the silica gel was not analyzed in the field, the spent  silica gel
samples should be weighed in the appropriate container to the neacest
0.5 g.
                                 67

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                                   S3CTION 9

                                 DATA ANALYSIS

9.1.  AVERAGE RUN PARAMETERS

     To calculate the resultant values from a test run, the  average  values  of
the recorded temperatures and pressure drops must be calculated.  The  pressure
drop across the pitot tube, however, requires special attention.  The  stack
velocity is a function of the square root of the pitot AP; therefore,  a
straight averaye of the APs over a given run would not result  in  the true
average velocity.  Because of this, the value used for calculating the average
velocity must b« the average square root of the velocity heads f (/AT?)    1.
                                                                1    vel avgj
This will result in a AP  . value that allows calculation of the  true  average
                        vel
velocity.

9.2.  DRY GAS (SAMPLE) VOLUME

     The sample volume measured by the EGR dry gas meter can be corrected  to
standard conditions (68 "P, 29.92 in. Hg) by using the following  equation:


          VMS-  (-)  f-*^)
                         TM        PST

                - 17.65  (V  v)   (?a *T?T?)                            (9-1)
                                     TM
                                    68

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9.3.  SAMPLE PLOW RATE

     The sample flow rate at standard conditions can  be  found  by using
equation 9-2
                                         —                           (9-2)
                                  ST     9
9.4.  RECYCLE AKO TOTAL GAS PLOW RATES
     The recycle and total gas flow rates are monitored by LPEs.   Therefore,
the average flow rates through these devices  (Q  and Q  , respectively)  can  be
determined by using the manufacturers calibration charts or  an  empirically
determined calibration equation in the form shown below.
                                                      ST
                        - 17.65 (S AP  (122^) + Wj(-i-)               (9-3)
                                         U           T
                                         "L           M
                                                       ST
                          - 17.65  StAPr  (l   * W      l              (9-4)
                                             L           L
                                    69

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9.5.  VOLUME OF WATER VAPOR

     The volume of the water vapor collected tram  flue gas  is  calculated as
follows:

                                      p       R T
                                       320     u ST
                           vws" vzc t~'  '~J
                                      Mu— _     f*im
                                       n« O     ST
                                  0.04707 V                             (9-5)
                                           1C
9.6.  MOISTURE CONTENT
     The moisture content of the stack  (or  sample) gas  is  calculated by the
equation
                                        Vws
                             Bws ' v - ^Tv -                       (9"6)
                              OT    MS      WS
     The addition of a known amount of dried recycle gas  to  the  measured sam-
ple gas upstrtiam of the particle-sizing device changes  the moisture content of
the 
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9.7.  FLOW  RATES  (ACTUAL CONDITIONS)

     To calculate  the particle  cut  diameter  of the inertial classifier/ it is
necessary to  know  the flow  rate through  the  sampler  at the actual sampler con-
ditions.  This can be accomplished  by using  the following equation:

                                                T      P
                      Q  .  Q     (	]	)   (	^)   (_§!)
                      Ut    Ut_, M  -  B .   '   * T  '   l P '
                              ST       mix        ST      s
                                                   T
                         -  0.056 a    h-J-g	)  fci)                   (9-8)
                                    ST   *  mix   s
     It is also necessary  to calculate  the  sample and recycle flow rates and
express them  in terns of stack conditions.   The  format shown in equation 9-8
should be used for these calculations.   However,  for  the sample flow rate the
moisture fraction becomes  the actual  stack  moisture content, B  , and for the
                                                               W8
recycle flow  rate the moisture content  equals  zero..
9.8.  RECYCLE RATIO

     The actual recycle ratio through  the cyclone  sampler  may be calculated by
the equation

                                   Qt-Q8
                             PR - (	)  x  100»                      (9-9)
9.9.  STACK GAS VELOCITY

     The average stack gas velocity or  the  gas  velocity at any one point with-
in the stack can be found by using the  following  equation:
                                     71

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                        V  - K C   (/AP  ,)
                         s    p p     vel avg
1/2
                (9-10)
        K  « 85.48 ft/s  (lb/mole-*R) when these units  are used
         P
9.10.  CONCENTRATION

     The concentration of the participate matter caught by each  stage  and  the
total particulate concentration in the stack gas can be calculated  by  the
equation below:
                                              ,    .
                           C' • 0.0154 gr/mg  (__)                     (9-11)
                            *                   MS

where    C' * concentration of particulate natter  for  a given  stage  or
              in-stack gas, grains per dry standard cubic  foot (gr/dscf ) ,
         M  » mass of collected particulate  (either per stage  or  total) , mg
          P
     The units of gr/scf can be converted to milligrams per dry  normal  cubic
meter, mg/dNn3, by using the following:
                                 C  - 2293.2 C'                         (9-12)
                                  ffl           B
9.11.  SAMPLER Djg

     The D^Q oir cut-point of each stage of the chosen particle-sizing  device
should be calculated for accurate determination of the particle  size distribu-
tion.  The cut-point is primarily a function of the actual  flow  rate through
the sampler and the viscosity and density of the gas mixture.  The  procedure
for calculating the actual flow r.ate  (rclm) was described previously.   The
                                    72

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 viscosity  of  the  mixture must be calculated.  As was shown in equation 5-3, it
 can be determined as  follows (Williamson et al., 1983):
                         ' Cl  * C2T + ^  + V.ix * C5f0
where u  is  in micropoise/  T in  *C,  and
         Cj  - 160.62
      C2 -  0.42952
      C3 -  1.0483 x  10-4
      C^ •  -74.143
      05 «  53.147

for   T  in  *R
      Cj •  51.05
      C2 •  0.207
         C3 - 3.24 x 10-5
      Q, •  -74.143
      C  -  53.147.
     The currently available data concerning  calibration of Cyclone I, used to
obtain the  10-un cut  for PM10 measurement,  show the behavior to be described
by the equation
     Because the proposed FN:g cyclone  is  actually pert of a five-stage series
cyclone system, it may at some point be desirable to operate the full cyclone
set with the EGR system.  If such  is the case,  the D50's for each of the
remaining cyclones should be calculated as described in the vendor-supplied
operator's manual.
                                    73

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9.12.  PERCENT ISOKINETIC

     To ensure nonbiased particulate sampling, the following equation should
be used to determine the percentage of isokinetic sampling:
                             .  0.00267 »lo»(Pa. -^)]
                " --          -
If 90% < Z% < 110%, the results are acceptable; otherwise, reject the results
and repeat the test.
                                    74

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                                  SECTION  10

                                  MAINTENANCE

     A notebook or other record of  all maintenance procedures  should  be  kept.
This will provide a definite  and current record of all  information  pertinent
to reliable operation of the  EGR sampling  system.  Maintenance of the system
should be performed as described previously  (Rom,  1972)  with the exceptions
noted below.

10.1.  VACUUM SYSTEM

     A preventative maintenance check of the vacuum  system  is  performed  as
follows:

     e  Insert a plugged 1/2-in. male quick-connect  into the sample
        inlet of the EGR control console.
     •  Turn the pump switch  to ON.
     o  Turn the coarse-adjust valve to the ON position.
     o  Close fully the fine-adjust valve  and the recycle valves.

     The vacuum gauge should  read about 25 in. Hg when  ambient barometric
pressure is near 30 in. Hg.   If this pressure cannot be  achieved, a leak or
sticking pump vane should be  suspected,  if the leak rate measured  by the dry
gas meter exceeds 0.02 cfm, the leak or leaks must be found and corrected.
Parts to check are the pump,  vacuum gauge, metering valves, and tubing.

10.2.  EGR PUN?

     Because the gas recirculated within the EGR system  must be free  of  any
foreign particles or vapors,  the system is equipped with a  leak-free, carbon-
                                    75

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vane pump.  The pump requires no lubrication,  and  little  maintenance is needed
to ensure long working life.  The most important factor in  ensuring  long pump
life is to allow only clean, dry gas to circulate  through the  pump.   This is
accomplished through the sampling system backup filter and  condenser.   Onlike
the oil-lubricated pumps used in most commercial Method 5 control  boxes, this
pump should never be operated with oil in the  muffler jars.

     During start-up if the motor fails to start or hums, the  operator shoulu
pull the plug and check for the correct current.   It  should be 5 to  6 A.  The
operator should .also visually inspect the plug and switch.   If the unit is
extremely crld, it may be helpful to bring the unit to ioora temperature before
starting.

     Most pump trouble can be corrected by flushing the unit according to the
manufacturer's instructions rather than disassembly.  A noisy  or inefficient
pump is frequently caused by nothing more serious  than a  vane  stuck  in a rotor
slot because of foreign material in the unit.  To  flush the unit,  follow the
procedure given below.

     e  Separate the pump from the system.
     e  Slowly add several teaspoons of solvent at the intake  while
        the unit is running (recomnK.nded commercial solvents include
        Loctite Safety Solvent, Inhibisol Safety Solvent, or Dow
        Chemical Chlorothane).
     o  Lay the unit on its side with the outlet downward so the
        solvent will work out again.

     If flushing does not eliminate the problem, take the corrective actions
belowt

     o  Remove only the end plate and the four carbon vanes.
     o  Remove any visible foreign materials,  and  clean the chamber
        with solvent.
     «  Ose the solvent to clean any buildup on inner pump  walls,
        which is caused by normal wear of the  carbon  vanes.
                                    76

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     o  Replace  any broken or  excessively  worn  vanes.
     »  Replace  the pump end plate.
     o  Check the unit  Cor leaks by plugging  the  inlet  of  the  pump
        and connecting  a gas meter to  the  outlet.

     If the pump causes the gas meter  to register  a  reading, the  pump end
plate should be  retightened and leak-checked  again.  This  should  be repeated
until the unit is leak-free.

10.3.  MAGNEHELIC DIFFERENTIAL PRESSURE GAUGES

     Magnehelic  differential pressure  gauges  are precision instruments assem-
bled and precalibrated  by the manufacturer.   If trained instrument mechanics
are not available, it is recommended that  any instruments  requiring repair  be
returned to the  factory.

     No lubrication or periodic servicing  is  required.   If the  interior is
protected from dust, dirt, and corrosive gases  and fluids, years  of trouble-
free service may be expected.

10.3.1.  Zero Adjustment

     The indicating pointer should be  set  exactly on the zero mark by using
the external zero-adjust screw on the  cover at  the bottom. The zero check  or
adjustment can be made only if the high and low pressure taps  are both open to
a.-jiosphere.

10.3.2.  Calibration Check

     For service requiring a high degree of continued accuracy, periodic cali-
bration checks are recommended.  In general,  the Magnehelic calibration should
be checked, along with the LFBs, by following the procedure below.

1.   As a comparison gauge, use a hook gauge, micromanometer, or  inclined
     gauge of kno»n accuracy.
                                    77

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2.   Connect the Magneheiic gauge and test gauge together with  two  leads  from
     a *T.'  Connect rubber tubing to the third leg of the "I"  and  impose  the
     pressure, slowly.

3.   3e certain no leaks exist in the system, and provide adequate  time for
     comparison gauges to reach equilibrium, because  fluid drainage and dif-
     ferent dynamic characteristics can affect the reading.

10.3.3.  Recallbration

1.   Remove plastic cover.

2.   Remove two screws holding scale, and slide scale out, using care not  to
     damage pointer.

3.   Loosen two set screws in range spring clamp  (Dwyer part  no. NOA-70B);
     move toward the helix to increase the range and  back to  decrease. Secure
     the clamp with the set screws, replace scale, check zero,  and  compare
     readl..j as in preceding paragraph.

4.   Replace cover.  The cover must be tight and leakproof for  accurate
     readings on high-pressure side.  Observe the following procedure.

     a.  Place the cover in position with notch engaged and with 0-ring
         properly seated.
     b.  Jockey zero-adjust screw into position so its hex end  is  inserted in
         tha socket set screw, which actuates the zero-adjusting mechanism.
     c.  Hold cover in position and screw bezel down  snug.  The Or ing must
         take sane squeeze to effect an airtight seal.
         Caution:  If bezel binds because of galling  action of  aluminum  sur
         faces/ lubricate sparingly with light oil or molybdenum suifate  com
         pound.
     d.  Troubleshooting.
         1)  Gauge sluggish.
                                    78

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             - Leads ;uay be plugged or leaking.
             - Cover may be loose or leaking.
             - Pointer may be touching scale.
             - Jewels supporting helix may be over tightened.
         2)  Gauge fails to indicate zero properly.
             - See comments above regarding sluggish readings.
             - Iron particles in a strong magnetic field  between  helix  and
               magnet.  If found, they may be removed by  touching each
               particle and withdrawing it with a small screw driver.
             - Magnet shifted and touching helix.
         3)  Apparent inaccuracy.
             - See preceding comments.
             - Improper connections to pick up desired differential.
         4)  Consult factory for unusual conditions of temperature, pressure,
             etc., and the effect on gauge operation and  accuracy.

10.4.  OCTAL MANOMETER

     A preventative maintenance check of the dual manometer is performed  as
follows:

     o  visually check the pitot and orifice manometer lines to
        ensure they are free of fluid.
     o  Check for leaks, especially around the fluid-level zeroing
        controls and drain screws.
     e  wipe the dual manometer clean.  The back can be cleaned with
        compressed air, oc the device can be removed from the control
        panel and wiped clean.
     o  if the dual manometer is unusually dirty, clean as recom-
        mended on the instruction plate.
     o  Make sure that the manometer ports are open  (1 1/2 turns
        counterclockwise from the seat) and the manometer lines are
        connected.
     o  Level the manometer and check the fluid level.
                                    79

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     e  To  till  the manometer  with  fluid,  remove the screw on the
        left side.  When  the oil meniscus  and the reflected image at
        zero are aligned,  the  fluid-level  plunger (zeroing control)
        should have about  1/4  to 1/2  in. travel  inward.

     Motet  During rough  shipment,  the manometer lines should be
     disconnected and  the  manometer ports  closed by turning clock-
     wise uiiitil  sealed.

     o  if  for any reason  the  manometer unit has been inverted, be
        sur«> the floating  check valves of  the manometer  have
        returned to their  normal position.   These floating valves
        are located under  the  manometer ports and must be in the
        normal position to use the  manometer.

10.5.  PITOT TUBE

     The pitot tube should occasionally be inspected for any defornation of
the pressure* inlets, because this may change the pitot calibration coeffi-
cient.  Any dents or nicks should be  repaired or the pitot head should be
replaced if the  damage warrants it.  Before each test run, the operator should
blow gently into each  pitot inlet to  check for obstructions.  If the pitot
tubes are clear,  the pitot tube gauge will respond.  If  no response is noted,
the operator should blow out the pitot lines with compressed air.  The pitot
can be checked for leaks by plugging  one end of  the tube and applying a posi-
tive pressure at the opposite  end.  If the tube  will not maintain pressure, a
soap solution can be used  to identify the  location of any leaks.

10.6.  N02ZI.BS

     The BGIt noxzle should be  visually inspected before  any testing.  If
repair is necessary, a plumb bob should be used  for inside damage or emery
paper for outside damage.   After any  nozzle repair, the  nozzle diameter should
be remeasured.   The knife  edge of the nozzle should be covered with serum caps
or similar  covers to avoid damage when the nozzle is not in use.
                                    80

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10.7.  THERMOCOUPLES

     The thermocouples throughout the EGR system  should  occasionally be
checked against room temperature by using a metcury-in-glass  thermometer  as
the standard.  If any thermocouples do not read within ±5  *C,  the  thermo-
couples or readout should be replaced or recalibrated.

10.8.  EGR SAMPLING PROBE

10.8.1.  Probe Cleaning

     Before each field test, all lines of the EGR heated sampling  probe should
be cleaned.  This includes the sample, recycle, and pitot  tube lines.   A
probe-cleaning procedure is outlined below.

     o  Clean the probe internally by rinsing, first with  tap  water,
        then distilled, deionized water, followed by an  acetone or
       • dichloronethane rinse.
     e  Rinse the internal tubes with the chosen  organic solvent and
        allow them to air dry.
     o  Visually inspect the probe for cleanliness, and  repeat the
        procedure if necessary.
     »  Rinse the recycle line, even if it appears clean.
     e  Rinse the pitot lines with water and blow them out with com-
        pressed air.
     e  Clean the tube fittings associated with the EGR  probe  sample
        lines by brushing, rinsing with distilled, deionized water
        and then with acetone oc dichloronethane; allow  to air dry.
     e  Cover all open ends of the probe with serum caps or Saran
        Wrap when not in use to prevent them from becoming contain2
        inated.
                                    81

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10.8.2.  Probe Heater Check

     The procedure below may be  used  to check  the probe heater.

     o  Plug the probe heater  line  and  controlling thermocouple into
        the control case,  and  turn  the  heater  controller on to
        approximately 300  *?.
     o  The indicator light on the  controller  should come on, and
        the probe should become  warm  to the  touch in a few minutes.
        After a few minutes, the indicator light should begin to
        cycle on and off.
     o  if the probe does  not  heat, check the  probe for loose
        connections.
     o  If the probe still does  net heat, it may be necessary to
        renove the probe lines from the probe  sheath for inspection
        of the heating element,  as  follows:
             Remove the tu ee  set screws  and tube fittings at the
             outlet end of the probe,
             Onscrew the front end  connector and gently slide out
             the proo* lines,
             Unwrap the insulation
             Visually inspect  the probe heating element for shorts
             or burned spots,  and
             If necessary, use an ohmmeter to  measure the resistance
             between leads (approximately 17 ohms) and also to
             ground  (infinite).   Deviations  from these values
             indicate faulty wiring.
     o  After any electrical problem  has been  solved, rewrap the
        probe lines with insulating material,  and reassemble the
        probe.

10.9.  CONDENSING SYSTEM

     Becauite it is generally preferable to operate the BGR system with a
Method 17 rather than Method 5 filter configuration, a condenser and silica
                                    82

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gel column may i«place  the built-in  impinger  train  assembly.   An impingec
system will be required if the  "back-half" catch  is to be measured.   Whichever
system is used for collection of water  vapor  from the  sampled stack  gas, it
must be clean and free of leaks before  being  used.   Glass impingera  should be
cleaned with distilled, deionized water  and then  acetone and  should  then be
allowed to air dry.  Stainless  steel condensers should also be rinsed by the
same procedure and allowed to air dry,  inverted to  ensure total drainage.  The
drying can be speeded by olowing out the condenser  with compressed air.
Silica gel columns (along with  condensers) should be leak tested,  along  with
the control box or separately,  by applying positive pressure  at the  inlet and
plugging the outlet.  Ideally,  these devices  should maintain  a pressure  of at
least 10 in. Bg above absolute.  It  is  recommended  new silica gel  be used for
each field test.
                                    83

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                                  SECTION  11

                              AUDITING PROCEDURES

     Routine quality assurance activities, such as equipment calibrations,  are
essential to obtaining good data.  An assessment of the quality  of  these  data
•ay be made through an audit.  The audit must be performed by  using equipment
or standards independent of those used in  a measurement program  to  ensure that
the tasks involved are being performed properly.

     The audits recommended for use in a program using the BGR sampling system
are similar to those described for Method  5  (U.S. Environmental  Protection
Agency* 1977).  Two types of audits, performance and system, are commonly
performed.

     Performance audits provide a quantitative evaluation of the quality  of
data produced by • measurement system.  One  type of performance  audit
recommended for Method 5 assesses the accuracy of the system's flow metering
devices using a critical flow orifice.  This is also recommended for  measure-
ment programs using the BGR system.  All four flow metering devices in the  EGR
system may be included in the audit by using the procedure for posttest
calibration checks outlined in Section 3 of  this report.

     A performance audit of data processing  is also recommended. As  for
Method 5, an audit of this type can uncover  and eliminate errors in data
transfer, calculations, etc.  The flow of  data from field data forms  and
weight sheets to data reduction programs or hand calculations  should  be traced
for at least .1 portion of the data base.   Calculation of results for  a
standard data set is another method by which data reduction procedures may ue
audited.
                                    84

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     A system audit is a qualitative  inspection  and  examination of the proced-
ures and techniques used by the field  team.  This  type of audit is strongly
recommended if the team is not familiar  with the BGR system.
                                     85

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                                  SECTION 12

              RECOMMENDED STANDARDS FOR ESTABLISHING TRACEABILITY

     Although the use of quality control checks and independent  audits  is
essential to obtaining data of the desired quality, another  important consid-
eration is the traceability of individual elements of the measurement process.
All materials, equipment* and procedures used should be traceable  to a
standard of reference.

     Workine) calibration standards should be traceable to primary  or higher
level standards.  The EGR flow metering devices should be calibrated against a
wet test meter that has been verified as required for Method  5.  The perfor-
mance of th« analytical balance should  be checked against Class-S weights
that are tr,seeable to NBS standards.
                                    86

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                              REFERENCES
 Farthing, W.  B. and A. D. Williamson.  "A Unified View of Inertial
 Znpactors and Cyclones."  Presented at 1985 Annual Meeting of American
 Association for Aerosol Research, Albuquerque, MM, 1985.

 Harris,  0. B. and L. Beddingfield.  "Isokinetic Sampling with Fixed Flow
 Rate Devices  Using Exhaust Gas Recirculation."  Presented at the third
 EPA Symposium on Advances in Particle Sampling and Measurements, Daytona
 Beach,  FL, 1981.

 Martin,  R. M.  Construction Details of Isokinetic Source-Sampling
 Equipment. APTD-0581, U.S. Environmental Protection Agency, Research
 Triangle Park, DC, April 1971.

 Ron, J.  J. Maintenance,  alibration, and Operation of Isokinetic Source
 Sampling Equipment.  APTD-0576, U.S. Environmental Protection Agency,
 Research Triangle Park, DC, March 1972.

 Smith, W. B., D. B. Harris, and R. R. Wilson, Jr.  A Five-Stage Cyclone
 System  for In Situ Sampling.  Environ. Sci. Technol.  13(11)«1387-1392,
 1979.
*
 U.S. Environmental Protection Agency.  Methods 1-5 of 40 CFR, Part 60,
 Afoendix A.

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0.3. Environmental Protection Agency.  Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume  III:  Stationary  Source Specific
Methods, Section 3.4.8.  BPA-600/2-77-026,  U.S.   Environmental Protection
Agency, Research Triangle Park, HC,  1977.

Wilke, C. R.  A Viscosity Equation  for Gas  Mixtures.   J.  Chen. Phys.
8«517, 1950.

Williamson, A. 0., O. L. losia, P.V. Bush,  W.  B.  Farthing,  J.  D.  McCain,
and W. B. Smith.  Development, Application, and  Support of  Particulate
Sampling Procedures.  3rd Annual Report  (1982).   SRX-BAS-83-348,
Southern fmsearch Institute, Birmingham, AL,  1963.

Williamson, A. 0., R. S. Martin, 0.  B. Harris,  and T.  B.  Ward.  "Design
and Characterisation of an  Isokinetic  Sampling Train  for  Particle Sise
Measurements Using Exhaust Gas Recireolation."   Paper  84-56.5.  Presented
at the 77th Annual Meeting of the Air  Pollution  Control Association, San
Francisco,, CA, 1984.
                               88

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                                  APPENDIX A

                             BGR SYSTBi CO»'PONB#K>

TUBE/PIPE FITTINGS

    1/2-in. tube bulkhead quick-connect, S.S.  (1 each)
    1/2-in. tube quick-connect sten, S.S.  (2 each)
    1/2-in. tube quick-connect body, S.S.  (1 each}
    1/2-in. tube Cull flow quick-connect sten, S.S.  (2  each)
    1/2-in. tube full flow quick-connect body, S.S.  (2  each)
    3/8-in. tube bulkhead quick-connect, S.S.  (1 each)
    3/8-in. tube quick-connect stem, S.S.  (2 each)
    3/8-in.' tube quick-connect body, S.S.  (1 each)
    1/4-in. tube bulkhead quick-connect, S.S.  (2 each)
    1/4-in. tube quick-connect ate*, S.S.  (4 each)
    1/4-in. tube quick-connect body, S.S.  (2 each)

    5/8-in. tube union, S.S. (1 each)
    1/4-in. tube union, S.S. (2 each)
    1/4-in. tube bulkhead union, brasa  (€ each)
    5/8-in. tub« x 1/2-tube reducing union,  S.S.  (1  each)
    1/2-in. tube x 3/8-tube reducing union,  S.S.  (1  each)
    1/2-in. tube elbow, S.S. (1 each)
    1/2-in. tube elbuw, brass (3 each)
    3/8-in. tube elbow, S.S. (1 each)
    3/8-in. tube elbow, braaa (1 each)
    1/4-in. tube elbow, S.S. (2 each)
    1/2-in. tube x 1/4-tube tube end reducer, braaa  (3  each)
    3/8-in. tube x 1/4-tube tube end reducer, S.S.  (1 each)
                                    89

-------
1/2-in. tube tee, brass  (1 each)
3/8-in. tube t««, brass  (1 each)
1/4-in. tulD* tee, 3.S.  (1 each)

S/8-in. tubing ferrules, Teflon  (2 each)
1/2-in. tubing ferrules, Teflon  (2 each)
3/8-in. tubing ferrules. Teflon  (2 each)
1/4-in. tubing ferrule.. Teflon  (4 each)

1/2-in. tube x 1/2-NFT aale connector, brass  (1 each)
1/2-in. tube x 3/8-NPT male connector, brass  (2 each)
1/2-in. tube x 1/4-NFT Bale connector, S.S.  (1 each)
1/2-in. tube x 1/4-NPT aale connector, brass  (2 each)
3/8-in. tube x 1/4-NFT «ale connector, brass  (1 each)
1/4-in. tub* x 1/8-NFT Bale connector, S.S.  (4 each)
1/2-in. tub* x 1/4-NPT feaale connector, be ass (2 each)
3/8-in. tub* x 1/4-MPT feaale connector, brass (3 each)
1/4-in. tub* x 1/4-NFT feaale connector, brass (1 each)
3/8-in. tub* x 1/2-NPT »«1* elbow, brass  (1 each)
1/2-in. tub* x 1/2-NFT aale elbow, brass  (2 each)
1/2-in. tub* x 1/4-NFT aale elbow, brass  (1 each)
3/8-in. tub* x 1/2-NFT *al* elbow, brass  (1 each)
3/8-in. tub* x 1/4-NFT male elbow, brass  (1 each)
1/4-in. tub* x 1/8-NFT male elbow, brass  (12 each)
1/2-in. tub* x 1/2-MPT mole branch tee, brass  (1 each)
1/2-in. tub* x 3/8-NPT Bale run  tee, brass  (1 each)

1/4-in. tub* x 1/4-hos* hose/tub* adapter, brass  (26  each)
                                90

-------
    3/8-NW x  1/4-NPT  reducing  adapter,  S.S.  (1  each)
    3/8-NPT x  1/4-NPT  bushing,  brass  (1  each)
    3/8-NPT coupling,  braas  (1  each)
    1/4-NPT adapter, brass  (1 each)
    1/4-NPT aale tee,  brass  (3  each)

    3/8-NPT x  1/2 hose barb connectors,  nylon  (1  each)
    3/8-NPT x  1/2 hose barb elbow,  nylon (1 each)
    1/4-NPT x  1/4 hose barb connector, S.S.  (4 each)
    1/8-NPT x  1/4 hose barb connector, brass  (6  each)

    1/4 hose barb tae, nylon  (10-15 each)

    1/4 flexible metal hose connector, S.S.  (1 «>ach)
        -Swagelok ISS-4HO-6-S4;   short length

    0.281-orifice ball valve, S.S.  (2 each)
        - Nbitey ISS-44P4
    0.250-orifice angled regulating valve, S.S.  (3 each)
        - Nhitey ISS-1RP4-A
    0.125-orifice 3-way ball valve, brass  (6 each)
        - Nhitey IB-42XF2

COPPER SWEAT FITTINGS

    1/2-inch elbow  (8  each)
    3/8-inch elbow  (4  each)
    1/4-inch elbow  (1  each)
    1/2-inch tee (1 each)

-------
PLOW  (or VOLUME) MEASUREMENT

    Laminar flow element, total flow  (1 each)
        - Meriam bOMJ10-10
    Laminar flow element, recycle flow  (1 each)
        • Koriam 50MJ10-1!
    Dry gas &eter, sample volume  (1 each)
        - Rockwell T-100 series  (thru Andersen  Samplers,  Inc.)

PRESSURE MEJISORBMENT

    0-4 inNS magnehelic,  (1 each)
        - D»yer 12004
    0-8 inNG magnehelic,  (1 each)
        - Dwyer 12008
    0-25 inWG magnehelic,  (1 each)
        - Dvyer 12025
    Vacuum gauge, panel mount  (1 each)
        - Onega fFGP-25 B-30V
    0-10 inWG dual inclined-vertical manometer  (1  each)
        - Dwyer 1422-10

TEMPERATURE MEASUREMENT

    Temperature controller  (1 each)
        - Omega Model 6100  (16102-K-0/500 *P)
    Thermocouple, type K, Readout (1 each)
        - Omega Model 199A  (I199K?)  (may substitute  Model  115)
    10-position thermocouple switch  (1 each)
        - Omega IOSW3-10
    Flanged female multipin connector, 24 position  (1  each)
        - Onega IMTC-24-FF
    Male multipin connector, 24 position (1 each)
        - Omega IMTC-24-MC
    Male multipin connector, 12 position (1 each)
        - Omega IMTC-12-MC
                                     92

-------
Female multipin  connector,  12  position (1  each)
    - Onega  IMTC-12-FC
Backshell cable  clamp,  foe  24  position connector  (1  each)
    - Omega  IMTC-24-SHL
Backshell cable  clamp,  foe  12  position connector  (2  each)
    - Onega  iMTC-12-SHL
Alumel sockets  (6 each)
    - Onega  fMTC-AL-S
Alumel pins  (6 each)
    - Onega  fMTC-AL-P
Chromel sockets  (6 each)
    - Onega  fMTC-CH-S
Chromel pins  (6  each)
    - Onega  IMTC-CH-P
Gold-plated  sockets  (12 each)
    - Onega  tMXC-Au-S
Gold-plated pins  (12 each)
    - Onega fHTC-Au-p
Sealing plugs  (12 each)
    - Onega fMTC-HP
Type K thermocouple, open bead,  1/4" dia x 4" L  (2 each)
    - Onega ICASS-14B-4
Type K T.C. ext wire, 20 AWG,  stranded, polyvinyl insl  (100  ft)
    - Onega tBXPP-K-20S
Type R T.C. ext wire, 24 AWG,  solid, glass insl   (15 ft)
    - Onega tGG-K-24      '
Type X T.C. ext wire, 24 AtfG,  glass insl ft SS overbeaid   (30 ft)
    - Marlin Nan. Corp.  I628S-K-24-30 ft
Hi-temp mini plugs. Type K   (2 each)
Type K T.C. ext wire, 24 ANG,  solid, glass insl   (15 ft)
    - Onega tGG-K-24
                                93

-------
    Type K T.C. ext wire, 24 AWG, qlase insl 4 SS overbeaid   (30  ft)
        - Mairlin Man. Corp.  I628S-K-24-30 ft
    Hi-temp mini plugs,  type K   (2 each)
        - Mtulin Man. Corp.  fH-1260-K
    Hi-tear «ini jacks, type K   (2 each)
        - Marlin Man. Corp.  IH-1210-K
    Mini cattle clamps   (4 each)
        - Marlin Man. Corp.  11280
    Female thermocouple connectors, type K   (4 each)
        - Omega fOST-K-K
    Panel adapters, round hole   (2 each)
        - Omega IRSACL

ELECTRICAL COMPONENTS

    Toggle 11 witch, DPDT, On-On,  rated 15 amps at  120  V*C   (2 each)
        • N«wark Electronics  Type 7565K5
    Toggle awith, DPOT, On-Off,  rated 15 amps at  120  VAC   (2 each)
        - Newark Electronics  Type 7561K4
    Green modular panel lights,  120 VAC 4 1.5 mA, w/bushing   (5 each)
        - Newark Electronics  Type 05115  (bushing  Type  100-G)
    Red modular panel lights,  120 VAC 4 1.5 mA, w/buahing   (2  each)
        - Newark Electronics  Type N5115  (bushing  Type  100-R)
    Circuit breaker, two-pole, 25 amps, Potter 4 Brumfield   (1  each)
        - Newark Electronics  IW92X11-2-25
    Male plug, 120 VAC 4 15-20 amps (2 each)
    Female recepticles, recessed, 120 VAC 4  15-20 amps   (2 each)
    Male plug, recessed,  "twist-lock", 120 VAC 4 20  amps   (1 each)
    Female recepticle,  "twist-lock",  120 VAC 4 20 amps   (1  each)
    Power cord,  3-wire, 12-14 gage   (30 ft each)
    Power cord,  2-wire, 14-16 gage   (40 ft each)
    Electrical wire, 14-16 gage, stranded, black sheath   (30 ft each)
                                    94

-------
    Electrical wire,  14-16 gage,  stranded,  white  sheath  (30 ft each)
    Electrical wire,  14-16 gage,  stranded,  green  sheath  (60 ft each)
    Terminal block,   15-20 position  w/jumpers   (1  each)
    Heat shrink tubing, black,  3/16-1/8 dia   (3  ft  each)
    Heat shrink tubing, white,  3/16-1/8 dia   (3  ft  each)
    Assortment electrical connectors, ring  and  forked
    Assortment wire nuts
    Assortment cable  tie mounts,  self-sticking
    Assortment wire ties, nylon,  3-inch length
    2-way solenoid, miniature,  120 VAC - 16.7 watts   (2 each)
        - ASCO  I8262A152
    3-way solenoid, midget,   120  VAC - 11.0 watts   (2  each)
        - ASCP  18314C21
    Heater tape,  1.75" W x 96.0" L,  120 VAC - 832  watts   (1  each)
        - Cole Farmer  I T-3107-80

TUBING  (rigid and flexible)

    2" schedule 5 pipe,  S.S.   (10 ft each)
    5/8" 0.0. x .049 wall,  S.S.  (10 ft each)
    1/2" 0.0. x .049 wall,  S.S.  (10+ ft each)
    1/2" O.B. x .049 wall,  copper   (10 ft  each)
    3/8" O.D. x .035 wall,  S.S.  (5 ft each)
    3/8" O.D. x .035 wall,  copper   (5 ft each)
    1/4" 0.0. x .035 wall,  S.S.  (2
-------
    1/4" 1.0.  SS braided Teflon hose   (6  ft  each)
        - MeMaster Carr  I5244K52
        - NOTE; requires purchase of special  S.S.  fittings
          (McMaster Carr IS244K82) which must be machined
          to desired geometry   (4 each)
    1/4" I.IX x 3/32" wall, heavy wall, black neoprene  (50 ft each)
        - Sargent Welch  #S-73655-KD
    1/4" I.D. x 3/32" wall,  Latex   (1  roll)
        - Sargent Welch  »S-73571-KD)
    1/4" I.B. x 1/16- wall,  Tygon   (30 ft each)
        - Sargent Welch  IS-73651-KC

MISCELLANEOUS

    PMjg cyclone system  (eye Z, eye IV  (if desired),  and filter holder)
        - Andersen Samplers, Inc.  ISB-280 Series
    1/4 - 21) x 3" L bolt, washer, nut assembly; S.S.  (1  each)
    Aasort»»nt 1/1 - 20 x 1/2"  L bolts, washers,  nuts,  S.S.
    Assortment 110 x J/4" L bolts, washers, nuts;   S.S.
    Assortment t 8 x 3/4" L bolts, washers, nuts;   S.S.
    Primer, line chrornate  (1 can each)
    Bnamel paint, peanut beige  (1 can  each)
    Acrylic resin clear coat,  gloss finish   (1 can)
        - i.e.  Datakoat doss
    Lettering, rub-on style  (lettering tool  desired)
        - custom fabricated
    Hand knob assembly, threaded  1/4 - 20, manometer  level  (1 each)
        - McMaster Carr  6085K12
  - Wave wanners,  1/4" dia hole
    Assorted 1/8"  AL plate (for system support)
    RTV siliicone rubber, for weather proofing  (1  tube each)
    RTV silicone rubber, high temp.  (1 tube)
    Teflon Cape  (1 roll each)     -     ...
                                    96

-------
    Liquid thread sealant,   (1  tube)
    Pin stripping, red and blue,  see  umbilical  assembly  (1  each)
    Expanding sleeve, nylon,   1.25" dia,  for  umbilical   (25  ft each)
        - Bentley Harris  f 6762001-13
        - Cole-Flex  t XS-100
    Expanding sleeve, nylon,   0.75" dia   (10  ft each)
        - available fro* above  sources
    Drying column, drierite or  silica gel,  285 mm  x 67 mm  (1 each)
        - Sargent Welch  I S-28730
    4 CFM pump, carbon vane, leak-free, w/muffler-filter   (1  each)
        - available through Andersen  Samplers,  Inc.

FABRICATED (Shop) ITEMS

    BGR noxxle assemblies, 3 individual dianeters
        - SRI Dwg. No. 6211-21-01
    Control box front panel, 1/8"  AL plate
        - SRI Owg. No. 5785-1-C-01
    Control box back panel,  1/8" AL  plate
        • SRI Dwg. No. 5785-1-C-04
    Nanometer leveling accessories, leveling guide  £ bolt  base
        - SRI Dwg. No. 5785-1-C-02
    Gas meter supports, bottom & top  supports
        - SRI Dwg. No. 5785-1-C-03
    Probe sheath, modified 2" Sen 5 SS pipe
        - SRI Dwg. No. 5785-1-C-05
    Probe caps, front ft back, with front 0-ring
        - SRI Dwg. No. 5785-1-C-05
    Sample orifice assemblies, 3 individual diameters
        -SRI Dwg. NO. 5785-1-B-06
    Pitot clamp (1 each)
        - SRI Dwg. No. 5785-1-C-08
                                    97

-------
Cyclone Z modification,  to  allow pitot attachment
    - SRI Dwg. No. 5785-1-C-08
Pitot flex-line fitting  modification   (4  each)
    - SFJ Dwg. Ho. 5785-1-C-08
Coiled condenser,  SS
    -SRI Dwg. No. 4266-D-05
                                 98

-------
                             APPENDIX B
                  LIST OF EGR SYSTEM SHOP DRAWINGS
BGR panel  (control box)
BGR sampling system, manometer leveling accessories
BGR sampling system, DGN supports
BGR sampling system, back panel!  aagnohelic  sero valves
BGR sampling system, probe components
BGR sampling system, sample orifice assembly
BGR sampling system, BGR nozzle
BGR sampling system, pitot assembly
BGR sampling system, BGR circuit diagram
BGR sampling train, condenser
                               99

-------
8


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                                                          Figure B-1.  EGR panel (control box).

-------
i
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                                                      17.1
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               EGR umpling tytttm, manometer leveling accessories.

-------
o
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                                          ^4v/» 0-J. ^Gff umpling tyttem, DGM tupportt.

-------
                                                                                          I
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                                                  £G A tampling tytUm, back panel: mognehelic zero valves.
                                                                 •lll-U

-------
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                                                                               OIl-T

-------
                                                                           1111-11
Figure B-6.  EGR umpling tyttem, ample orifice assembly.

-------
O
0\
ASSY1 O.I 25  2.«a
ASSY2 O.16O  1.OS
              EOM\ NOZZLE ASSEMBLY
                 fASSYI SHOWN)
                                                                                                           OET3 1.272 O.S2S
                                                                                                           GET4 O.S81 O.22S
                                 VIEW

                              EGR SLEEVE IPET3)
                                                                                                        DRILL O. I 10 DM
                                                                                                 + .001   T»P! f PL>CES
                        1  J>I    ••f'   \, .11_. - '
                               O.387 1.47B O.S6S  O.624
                               O.4S2 0.87B 0.104  O.234
                                                                                       FLANQE (PETTI
             EQR EXIT (DETS SHOWN>
                                                              NOTE: SILVER SOLOCR ASSY
                                                              At AREAS INDICATED THUS *.
                                                              USE MINIMUM FLUX TO
                                                              PftEVEMT RVJNNIHO TO
                                                                 AR.KCR 1-0 |S)
                                                                     0.077
                                  -f  H -O.671 0.79 —
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                                                             UNLU* oTMiwnt «Kcmu>
                                                               OMUWONt M MCHU
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            DET1 O.I29  4'  >O.B8 O.287  O.9O7 O.S93 O.2S2
            DET2 O.16O  9-  >O.B8 O.332  O.S82 O.B48 O.I49
           ECR INLET CONE
                                               Figure 8-7. EG ft sampling system, EGR nozzle.

-------
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                                  £Off umpling syttem, pilot assembly.

-------
                                                                                                           TSL
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        SWITCHES
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                                                                                 TEMP
                                                                                 TEMP.  RCAOOUT
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                                                      f/pw» fi-S. £6/7 umpling tyitam, EGR circuit diagram.
                                               nitiitaf"t'"r  "•«'""	m
                                               Cl      tim-i-t-io    I
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Figure B-10. EGR sampling train, condenser.

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                             APPENDIX C
                         LIST OP BIANK FORMS
Dry Gas Meter/Orifice Calibration Sheet
LFB Calibration Sheet
Pitot Calibration Sheet
Mozzle Calibration Porn
Temperature Sensor Calibration Form
Magnehelic Gauge Calibration Check
System Vacuum Gauge Calibration Check
Field Barometer Calibration Porn
Triple Beam Balance Calibration Form
Pyrite Analyser Calibration Form
Method 1 Data Sheet
Method 2 Data Sheet
Method 3 Data Sheet
Method 4 Data Sheet
BGR Field Data Sheet
Lab load/Onload Sheet
Field Sample Weight Sheet
Reagent Blank Evaluation Form
                               110

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                             DRY GAS METER/ORIFICE
                             (STANDARD! TEST METER)
                               CALIBRATION SHEET
       She«t Z.O.
Dry Gas Meter I.D. Standard Teat Meter I.D.
Barometric Pressure, P.
Calibrated by:
Run *
Orifice Setting, AH
Final Reading (STM)
Initial Reading (STM)
Volume VT, ft3
Temp Tj, *F
APf, in. HjO
Final Reading (DUM)
Initial Reading (DGM)
Vblume VuQ(.ft3
Temp 1D(ai, ~r
Elapsed Time 0, min.
DGM Flow Rate Q, acfm
Q ^ . AH (103,4460) .
Correction Factor, YI
% Error • tf 	 1) 100%
AHi . JO'"'^

in. Bg;
Orifice I.D.
Datei
1
















2
















3
















Leak Check!
4
















H r — T. si i Y • T
Previous Calibration!
Date;
Old Y
Orifice AH from:
___ Manometer
	 Magnehelic
Zero
Equipment Set Op:
Positive Pressure
(MS w/leakless pump)
Other
Avg


AP,
*B^ ^^^P^ * DGM^
Deviation - (T «**- T previous)  100%
Hotei Must be within ±5%.
               'previous
 fcfeei YJ criteriaJ±2»),  OMp is Dry iwlecular weight (28.97 for Standard air).
If a Laainar Flow Element is substituted for the Standard Test Meter the STM
column. >ay be used to record A^L^ (in. H.O)  and AP8W (gauge pressure at
orific. inlet, in. H.O) if different fro. XH.   For aBPositiv« Pressure equipment
arrangement AP    • AH.
                                    Ill

-------
                  LFB CALIBRATION SHEET USING MET  TEST METER
LFE 1.0.
DATS:

OPERATOR:
BAROMETRIC PRESSCRE  (In Hg)
TEMPERATURES (*F):
     Ambient *
                                      This  calibration uses the fit:
                                      where:  Q -  LFE flowrate
                                             Ap «  pressure drop
                                            K^pg •  Gas viscosity at LFE
                                            X,Y -  Calibration constants
     LFB
VISCOSITY (STD) -  180.1 micropcise

VISCOSITY (LFB) -  163.526 + 0.2552  (TLpB) +  3.2355  x 10"s
                       micropoise  (Note:  For
                                                        in *F)
RUN
1
2
3
4
5
6
7
8
WTM
VOLCMB
(Pt3)








TIME
(min)








DP LFB
(In HoO)








DP
System
(In H.,0)








Q
WTM
(AC?M)







*
g
LFB
(ACFM)








NOTBt Dp system i» the pressure differential  between the LFB inlet and
ambient;
O
QLFB
           tflPMl
lPMl 1 f
    J IP
                         AMB
                          .-
                                                 > 460)1
                                                 + "ZJJ
Calibration Results:  X •
                                     r •
                                        112

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                                                       Sheet l.D.
                    Pitot Calibration Sheet
Pitot X.D. Leak Check?
Date

Operator Manometers/Magnehelics Zeroed?
•p(STD)
Sketch or describe configuration:
(in. H.O)









APTEST
(in. HjO)









Average
Cp
-------
                                      Mosul* Calibration form
                                      (S«« Instructions Below)
Shoet 1.0.
DateAi**








Calibrated
By








ctossie
10
Ruaber








Nossle Di weter (inches)
"I








»2








D3








AD








0
•vg








where i
Oj ,2 ,3 « three different nossle dimeters at (0 degrees
              0.001 inch
         AD •• •axlaus) difference between any two diameters,
              AD < 0.004  inch
       D    •• (Dj * Dj *  Dj) »  3

Instructions
1. Inspect the nossle for nicks, dents,  and corrosion.  If
   these are found they should  be  corrected before calibration.
2. Placft a reference «ark on the nosale.  Place the nossle at
   the -seftteir of Figure 1,  aligned with  Point 1.  Measure and
   record 0..
3. Mot^t* tft'i nossle so that the reference mark is aligned
   with Point 2.  Measure and record  D2.
4. Rotate th
-------
                                                                Sheet 1.0.
                  TEMPERATURE SENSOR CALIBRATION DATA FORM
Date
                       Thermocouple I.D. No.
Asbient T*?oerature

Calibrated by 	
                       Potentiometer I.D. tto._

                       Barometric Pressure
                                         in. Hg
                                       Eefi Mercury-in-glasa
                                            Other
  Reference
  Point No.
Source
(specify)
 Reference
Thermometer
Temperature,
Thermocouple
Potentiometer
Temperature,
Temperature
Difference,*
 ar  tret, temp. *F *460) - (test thermom temp. *f *4601 i 100.
  I              (rez temp, 'f +4ouj                     J

  Motet  Temperature difference must be within ±1.51.
                                    115

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                                                        Sheet  1,0.
     Date
     Aabient Teap
 MAGNBBBLIC GAOGB CALIBRATION CHECK

__________          Gauge I.D. _____

           •?
Calibrated bys
Baroaetric Press. in. Bg


Positive
Side
negative
Sid*

Manoaeter
AP
(in. BjO)


Leak Checks
Poa. t "BjO Acceptable _____
Reg. . •_____ "BjO Acceptable ______
NAGNEHBLIC
AP
(in. 820)


Deviation
 inn«
1 Han. )10°*


   Calibcatu and leak ch«ck the differential pceaaur* gauge  using  the  following
proceduret

t. Connect Che differential pressure gauge to a
   gaugv-oi.'l •anoaeter, M shown.
2. Vent the vacuua tide to the ataosphere, and
   place pressure on each ayate* to approxiaately
   •axiaua <(«ug« reading.  Close system and observe
   gauge reading for one minute.  If no change in
   reading occurs, leak check is acceptable.
3. Compare Ap readings of the dirterential pressure
   gauge wi those of the gauge-oil nanometer at  a
   •iniaua of three points representing approxiaately
   the rango of Ap values to be encountered,  follow
   the saae procedures on the vacuua side by venting
   the presiiure side to the atmosphere and by putting
   a vacuua on the systea.
4. During a pretest calibration check if, «c each  point,
   the valuo of Ap as read by the differential pressure
   gauge and the gauge-oil aanoaeter agree within  5%,
   the difforential pressure gauge should be considered
   properly calibrated.
S. The postt-.est calibration should be perforaed  at the
   average Ap.  If the agrecaent is within ±5% the
   calibration is acceptable! if not, refer to EPA
   Reference Method 2 to deteraine acceptability.
                                      116

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                                                               Sbe«t X.D.
                     SYSTEM VftCtnW GAOGB CVLIBRATION CHBCK
   Date
             Gauge Z.O.
   Ambient Temp
             Calibrated by
   Barometric Press.
_ in.  Bg    Leak Rate (cfm)
    Mercury Nanoaeter
        (in. Bg)
      Vacuua Qauge
        (in.  Bg)
Correction
  Factor
1. Assemble system as shown. Notes Mercury nanometer
   should have at least 24" vacuum capacity.
2. System leack checks With pinch clamp closed,
   adjust system vacuum to 20 "Bg (manometer),
   observe gas meter flowrate (must be <0.02 cfm) .
3. If leak rate is accept ab'., adjust system vacuum to
   15 and 19" Bg.  Record each comparison.  The vacuum
   gauge reading should be within ±10% of the reference.
   Correction Factor, CFy -
                                       117

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                                                               Sheet X.D._


                       Field Baroneter Calibration Fora
Field B«os»etei: I.O.

Calibration Source
     The field baromter should be  adjusted  initially and before each test
series to agreo within ±2.5 ••  (0.1  in)  09 of  a Bercury-in-gl&ss barometer or
with the station pressure value reported by  a  nearby National Weather Service
station and corrected for elevation.  The correction for elevation difference
between the station and the sampling point should be applied at a rate of
-2.4 SB Hg/30 11 (-0.1 in Hg/100 ft).
     Was the pretest field baroswter calibrated? 	yes _____ no

     Operator! ______________________

     Dates	

     Reference Pressure • ___________________

                                                 Difference •
     Measured Pressure  »
                                     118

-------
                              Triple Beaa Balance
                               Calibration Form
 (S«« Instructions B«low)
      Date i
Zero*
      Operator:

1
2
3
4
S
Reference
Wt.
(9)





Measured
Wt.
(9)





Difference
(9)





  Instructionsi

      The triple bean balance shoiO.3 be calibrated by using Class-S  standard
weights and should be within ±0.5 g of the standard weight.  Adjust  or  return
the balance to the manufacturer if Units are not >et.
                                 119

-------
                        Fyrite Analyzer Calibration Form
   Octet
Op«cator>

1
2
3
Z«ro
(/)



Oxygen
Source



Average
Reading




% Brror



Carbon Dioxide
Source



Aver age
Reading




% Error




NOTBt If Oxygen Source is ambient air, the aeasured average Bust be 20.8 t 0.7%.
      If Source is a known mixture of gas*s, the average should be t 0.5% of known
      concentration for both oxygen and carbon dioxide.
                                  120

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                       METHOD 1.  DATA SHEET

Instructions:  Draw port configuration on appropriate duct geometry.


                                    Duct Diameter           _____   in.

                                    No. Diameterj to
                                    nearest upstream
                                    disturbance             	

                                    No. Diameters to
                                    nearest downstream
                                    disturbance              _____

                                    No. Required traverse
                                    points                  _____

                                    Port flange depth       	   in.
                                    Duct dimensions         ______   in.

                                    Equivalent diameter,
                                    De • 2 L*               	   in.
                                         L-Hf

                                    No. Diameters to
                                    nearest upstream
                                    disturbance             ______

                                    No. Diameters to
                                    nearest downstream
                                    disturbance             _____

                                    No. Required traverse
                                    points                  ______

                                    Poet flange depth       	

Point No
1
2
3
4
S
Position of traverse points
(Distance from inner wall in inches)

                               121

-------
                                                  Method  2 Data Sheet
         Plant:
                                                                         Datr«
         Locationt
                                Ti.se i
                                           %oo2-
                      %CO-
               (HG)l
1AP
                                            stack
         Pi tot Constant*
Point
NQ.
1
2
3
4
S
6
7
8
9
10
Avg.*
Por
A(V











1
T











Por
APy









t

2
T











Port
APy











t 3
T











Por
APy











4
T











Por
APy











S
T











Por
APy











6
T











Por
APV











7
T











Por
APy











8
T











Por
APV











9
T











KJ
          •  Averages are /ZTp, not Ap.




                AVERAGE DUCT VBLOCITY -




                AVERAGE DUCT TEMPERATURE

-------
                             METHOD 3  DATA SHEET
Test HaoMi
Swpl* Location:
                              fYRJTB GAS ANALYSIS
  Oat*
Tiac
Operator
                                    123

-------
MLTIKN)  4  -  WATKH ANALYSIS
Date











rime









. «

Run I.D.







'



vwc" <°'°«72 ftj/«l>
Vme • JI7.65 *H/ln. 1
Water
Collected, •(








r


(water Collectc
V V
, / *• r«i i
*' 1 f I
VCH Volu*
"initial











a)
"wo •
.£_«•* £i?
final











IXM -TBBP,











W£ 	 _. a A ft?1!
we BO
BaroBetrlc
Press, I'm











% 11*0











0|>erator













-------
tun
Cod.
Maplac
ID
PUtcr
10
Savplar
Orientation
SaBpllag
location
Moisi*
Oi«Mt«c-IO (in)
Ovwator(s)
«
•t*rt |
Ttnw i
lad . J
Tla€ *
ScvplUig ;
Duration (ala) 1
OGM ' (
(initial) \
OCM
(final)
Sa*pl«
VoloM ( ft1 )
Dual Manontcr L«v«l«d and I«ro«d?
Ma4n«h«lica Z«rc«d?
Ion
TiM

























fort no
Trav.pt.

























Af
Pitoe

























«8
Saopla

























OCM
VolOM

























4» ~1
Total

























leadt
>i({«r«neial Stack
^rvsaur* (in.H^O)
Mblcnt
r«ttv»r»tor« ( *f )
V^iaae
?r««*ur« (ia.Bq)
iu
r«locitr
lyataa Leak Ch^ek
p
Inlit

























AP
Recycle

























Stack

























CM Composition
Hoiatur* Contcne
Pitoc Leak OMCk
(Po«) (H«4)
•otca
t«cycl«

























Proe*

























T»
in

























&

























125

-------
LAB LOAD/UNLOAD SHEET FOR MT FILTHH. PM10. OR 5 SERIES CYCLONE
•UK COM


OMMCIB
MHO MM CM£u»raM mm MuuwmMi

r*fi**um AxraHHinT
•UT. OUTUT. OT>«*

*uMmu- • •
antMCAnm

(MVUM0MMMIM



MMOK UMMM IMMCTO* AMU OATI UVWMO

• uuu>UM*m
• HAM MOM* WIM MM COM
• UIMTUT
• «M» MIH »O1 AMD MM* MTN HIM COM
L»UA« emeu no ttcrttnuna ttnaa
CMCOI UMWI v«cuu« <-« M. M«



MtU «• OMIII VATWM
•




•on YOUII a»«u>v«no«» o» r« A>nAiumc« o» UCM
IUM. WMnun. on CTdOM UTOM OIMMUMI r
TM( fOMM MAT M U«O MM »•* 0* TUMI DVffMlir TT»M 0* tUWUM.
CMCU 1M TV*f MMKfll UOO
MTMUV) HI10 IXIMJCTCUMI

•**• nuw mnN emeu O"B
. »XU^T^. mmniut
• «J MM mnfl ttozaA WA*H 10 to.
• HIIIM.I
•M10MMMJII
CTCLOMI1
w -or

i ii mo i
Ml -CT


mtw
.v -»
IMMmCTOOMIHr
evcuMii
CT .1

CVCLOMJ
CT 4


etctaMi
CT 4

CTCUM4
CT 4
CTCU3MI
CT •»
mm
CT *
                          126

-------
                                                          Sheet 1.0.
               WBZGia SHEETS FOR USE WITH THE METTLER BAIAHCS
                        Substrata S«t Z.O.
                              PRE-TES7 WEIGHTS
Operator
Oat*
   Operator
   Data
Calibration Check?
   Calibration Check?
       Weight   Offset   Actual
Z.O.    (ga)
                                            Weight   Offset    Actual
                               Final
                                 FIHAL WEIGHTS
  Operator
  Date
Operator
Date
  Calibration Check?
Calibration Check?
           Weight   Offset   Actual
Weight Offset Actual
    Z.O.
                                                               Final
                                                                 (•g)
Wt.Cain
 Hotei A control weight should be recorded at least every tenth weight.
                                     127

-------
                                                              She*3t 1.0.
Date t
Operator:
                         REAGENT BLANK EVALUATION FORM
                                      Reagent:
                                      I.D.i:
Barometric Pressure  (in. Hg):_
Ambient Temperature  (*F)x    ~
                                            Density (mg/ml)_
     In a tared weighing pan  add  a specified amount (20-30ml) of the reagent.
Allow the solution  to  evaporate  and reweigh the pan. The net weight gain shall
be considered residue  from  the reagent.

NOTE:  For each separate bottle or container of reagent a minimum of three
blanks should be obtained to  determine an average residue mass.
Pan
I.D.





TARS
(*3)




Volume
Reagent
(ml)





Final
Weight
(mq)





Mass
Residue
(mg)





Average1*
%
Impurities*






.__..,<». i _.,
Impuritie«
                     (Residu
                              idue, n
                              /ml) (\
• x 100%
             (Density,mg/ml)(volume,ml)

  reagentti the average to impurities  should  be  <0.001%
                                     128

-------
                                  APPENDIX  0

                 HP41C SBTOP PROGRAM FOR EGR SYSTEM  (BGR SET)

     The BGR setup program is used to determine  the  sample orifice,  total flow
LFB, and recycle flow LFB pressure differentials required to maintain isokine-
tic sampling for given stack conditions.  The program  uses an  approximation of
the total flow rate, Q. to eliminate the necessity  of an iterative  solution.
This approximation agrees with the exact solution of the equation to ±1% for
stack conditions in the range of  ICO to 500  *F and 0 to 50%  moisture.  An>
additional approximation is introduced by assuming stack temperature to be
constant at the average stack temperature.   This approximation removes the
complicated temperature dependence from all  three pressure drop equations.
Pressure drops calculated in this manner agree within  ±10% with exact solu-
                               ». I
tions for temperatures in the range of ±50  *F of the average.

     Initial prompts for data input are as  follows:
       1) Barometric pressure
       2) Static pressure of stack
       3) Average stack temperature
       4) Gas meter temperature
       S) Dry molecular weight
       6) Met molecular weight
       7) Percent oxygen                 -•
       8) Percent moisture
       9) Calibration constants
            os
            o s
               r
            o w
                                     129

-------
            o Delta Ha
            o Kozzle diameter
            o Pitot C
                     P

     After the above data are entered, the program calculates the equation
constants for each of the pressure differentials, in the following form:
            AH • KAp  ,
                   *vel
             t    t    t   "vel
             r    t    t   'vel
       When the pressure differential equations have been determined, the
program enters a short loop and prompts for the velocity pressure, Ap    .
After entering this information, the sample orifice AH, total flow LFB Ap  ,
and the recycle flow LKE Ap  are determined.  The program then asks  if there
are more travenie points.  A "Yes" answer resets the program to  the  beginning
of the loop.  A "No" answer ends the program.

     Note that if the stack temperature deviates from the average temperature
entered by more than 50 *?, the equation constants should be recalculated  by
reentering the beginning of the program.
                                    130

-------
01 * LBL "BGR SET"
02  FIX 2
03  CLRG
04  "BAR PRESS?"
05  PROMPT
06  STO 01
07  .59
08  +
09  STO 06
10  "STATIC P INWG?"
11  PROMPT
12  13.6
13  /
14  RCL 01
15  +
16  STO 07
17  "STACK TEMP?"
18  PROMPT
19  STO 08
20  X*2
21  3.2355 B-5
22  *
23  .25529
24  RCL 08
25  *
26  +
27  152.418
28  +
29  STO 09
30  "METER TEMP?"
31  PROMPT
32  STO 10
33  X + 2
34  3.2355 B-5
35  *
36  .25529
37  RCL 10
38  *
39  +
40  152.418
41  +
42  STO 11
43  460
44  ST+ 08
45  ST+ 10
46  "DRY MOL WT?"
47  PROMPT
48  STO 12
49  "WET MOL WT?"
50  PROMPT
51  STO 13
52  "%02 ?"
 53  PROMPT
 54  .53147
 55  *
 56  ST+ 09
 57  ST+ 11
 58  "% MOISTURE?"
 59  PROMPT
 60  100
 61  /
 62  STO 14
 63  "CALIBRATION"
 64  AVIEW
 65  PSE
 66  "DATA"
 67  AVIEW
 68  PSE
 69  "XT ?"
 70  PROMPT
 71  STO 15
 72  "XT ?"
 73  PROMPT
 74  STO 16
 75  "XR ?"
 76  PROMPT
 77  STO 17
 78  "YR 7"
 79  PROMPT
 80  STO 18
 81  "DELTA Ha?"
 82  PROMPT
 83  RCL 01
 84  /
 85  STO 01
 86  "DIA NOZZLE?"
 87  PROMPT
 88  X+2
 89  STO 19
 90  X*2
 91  ST* 01
 92  "PITOT CP?"
 93  PROMPT
 94  ST* 19
 95  X f 2
 96  ST* 01
 97  1
 98  RCL 14
 99  -
100  Xf2
101  ST* 01
102  RCL 12
103  ST* 01
104  RCL 10
                               131

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105
106
107
108
109
110
111
112
113
114
115
116
117
118
119*
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
M7
148
149
150
151
152
153
154
155
156
ST* 1«>
ST* 01
RCL 07
ST* 01
SORT
ST* 19>
RCL 131
ST/ 01
RCL 0€l
ST/ 01
SQRT
ST/ 19i
846.72
ST* 01
LDL 01
RCL 11
ST* 1<>
RCL 06
ST/ 1SI
.1539
ST* 19
18
RCL 12
/
1
XOY
-
.2949
*
1
XOY
-
RCL Oil
*
RCL U
*
STO 03
1
RCL U
*>
RCL 14
*
74.143
*
ST+ o:\
RCL 0<»
RCL HI
74.143
*
-
ST/ 03!
RCL IS)
,57
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
            RCL 15
            /
            RCL 13
            SQKT
            /
            ST* 03
            RCL 11
            RCL 10
            *
            RCL 07
            .7051
            Y*X
            *
            RCL 09
            *
            RCL 06
            /
            RCL 12
            .2949
            RCL 08
            .7051
            1.5752  B-5
            *
            STO 20
            RCL 11
            180.1
                16
RCL
*
RCL 20
XOY

RCL 15
/
STO 02
LBL 02
RCL 17
ST/ 19
RCL 09
RCL 14
74.143
*

RCL 09
XOY
/
RCL 12
.2949
132

-------
 209  Y*X                              261  AON
 210  /                                 262  "MORE PTS? Y,N"
 211  RCL 13                            263  PROMPT
 212  .2051                              264  ASTO Y
 213  Y*X                              265  AOFF
 214  /                                 266  "Y"
 215  RCL 19                            267  ASTO X
 216  *                                 268  X-Y?
 217  STO 05                            269  GTO 03
 218  HCL 11                             270  CLX
 213  180.1                              271  END
 220  /
 221   RCL 18
 222  *
 223  RCL 20
 224 'XOY
 225  -
 226  RCL 17
 227  /
 228  STO 04
 229fLBL 03
 230   •VELOCITY DP?"
 231   PROMPT
 232   STO 00
 233   RCL 01
 234   *
 235   "DELTA H* "
 236   ARCL X
 237   AVIBW
 238   PSE
 239   RCL 00
 240   SQRT
 241   RCL 03
 242   *
 243   RCL 02
 244  XOY
 245   -
 246   "DP TOTAL • "
 247  ARCL X
 248  AVIBW
 249   PSE
 250  RCL 00
 251  SQRT
 252  RCL 05
251  *
 254  RCL  04
255  XOY
 256  -
257   "DP RECYCLE • "
258  ARCL X
259  AVIBW
260  PSE

                                133

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                                  GLOSSARY

Aerodynamic diameter:  The aerodynamic diameter of a particle ie the diameter
     of a sphere of unit density whch has the name settling velocity in  the
     gas aa the particle of interest.  For spherical particles with diameter
     Op, larger than a few aicrons and gas conditions of  interest  for  source
     PM. n» the aerodynamic diameter is essentially given  by /p~ 0  where p
       *«                                                     p  p       p
     is the particle density.

Cut-point:  Tint cut-point of a aiz« classifier is the particle diameter  for
     which all particles of equal or greater diameter are captured and all
     particles with smaller diameters ate not captured.   Mo real device
     actually has a sharp step function cut-point, but the theoretically
     defined CVi0 of a stage is often called its cut-point.

Geometric standard deviation, a t A measure of dispersion in a lognornal
     distribution.  It can be calculated as the ratio of  particle  diameter
     corresponding to a cumulative percent of SO to the diameter
     corresponding to a cutbciative percent of 15.86.
                                    134

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-------