TECHNICAL NOTE
                            ORP/TAD-76-5
        THE UNITED STATES
ENVIRONMENTAL PROTECTION  AGENCY

  OFFICE OF RADIATION PROGRAMS
          DECEMBER, 1976

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                           EPA REVIEW NOTICE
     This report has been reviewed by the Office of Radiation Programs,
U.S. Environmental Protection Agency, and approved for publication.
Approval does not signify that the contents necessarily reflect the
views and policies of the U.S. Environmental Protection Agency, nor
does mention of trade names or commercial products constitute endorse-
ment or recommendation for use.

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                                   PREFACE



     The Office of Radiation Programs of the U.S.  Environmental Protection

Agency carries out a national program designed to  evaluate population

exposure to ionizing and non-ionizing radiation, and to promote development

of controls necessary to protect the public health and safety.   This report

was prepared in order to summarize two extensive reports which  examined the

natural radioactivity source terms associated with radium in water supplies

and the radium removal efficiencies of water treatment processes.   Readers

of this report are encouraged to inform the Office of Radiation Programs of

any omissions or errors.  Comments or requests for further information are

also invited.
                                      David S. Smith
                                         Director
                          Technology Assessment Division (AW-459)
                               Office of Radiation Programs
                                     iii

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                                  ABSTRACT

Numerous well-water supplies for public water systems contain naturally
occuring radium-226.  Methods for removing radium from drinking water must
be identified so that drinking water treatment plants may meet the limit
set in the EPA drinking water regulations for radium in drinking water,
5 pCi/liter.

Studies were performed by State agencies at 14 cities in Iowa and Illinois
to determine the radium removal efficiency of four water treatment processes.
Populations served by the water treatment plants ranged from 235 to 25,000.
The radium-226 concentration in the raw water was greater than 5 pCi/liter
at 13 of the supplies and ranged from 3 to 49 pCi/liter.

Radium removal efficiencies at plants utilizing reverse osmosis and sodium
ion-exchange processes were generally about 92%.  A much wider range of
removal efficiencies, 75% to 95%, was found at plants utilizing the lime-
soda ash softening process.  Plants utilizing iron removal processes only
were found to have radium removals ranging from 11% to 53%.

Pilot plant studies at the USEPA Cincinnati laboratory indicated that radium
removal in the lime softening process is related to the pH used in the pro-
cess.  Higher radium removal efficiency accompanies higher pH values.

It is concluded that water treatment processes are available for removing
radium from drinking water to meet the 5 pCi/liter limit.
                                      iv

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                             TABLE OF CONTENTS
EPA Review Notice	ii
Preface 	iii
Abstract	iv
Table of Contents	v
List of Figures	vi
List of Tables	vi
Conclusion	1
Introduction	2
Description of Study	3
Results	5
    Reverse Osmosis	5
    Iron and Manganese Removal	6
    Sodium Cation Exchange	6
    Lime-Soda Ash Softening	9
    Pilot Plant	12
Summary of Results	17
References	18

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                              LIST OF FIGUEES


Figure No.                                                          Page No,

   1      Radium Removal vs.  Softening pH	14
                              LIST OF TABLES


Table No.                                                           Page No,

   1      Cities Included in Radium Removal Studies 	  4

   2      Ra-226 and Hardness Removals at Greenfield,  Iowa
          Reverse Osmosis Plant 	  5

   3      Ra-226 and Iron Removals at Water Treatment  Plants
          Using Iron and Manganese Removal Processes	7

   4      Ra-226, Iron and Manganese Removals by Iron  and
          Manganese Removal Processes 	  8

   5      Ra-226 and Hardness Removals at Water Treatment Plants
          Using Ion Exchange Processes	10

   6      Ra-226 and Hardness Removals at Water Treatment Plants
          Using Lime-Soda Ash Softening	13

   7      Ra-226 Removal in EPA Lime-Softening Pilot Plant
          Using Elgin, Illinois Water	16

   8      Ra-226 Removal Efficiencies in Water Treatment Processes. .  .17
                                     VI

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                                 CONCLUSION

A study to determine the efficiency of radium removal by conventional water
treatment processes indicates that reverse osmosis, ion-exchange and lime-
soda ash softening are effective in removing the major portion of the radium
from the water.  High radium water was associated primarily with deep sand-
stone formations.  The raw water radium concentrations ranged from 3 to 49
pCi/1 at the water treatment plants studied.

Overall removal of radium at a reverse osmosis plant was 96% as compared
with a concurrent hardness removal of 95% with a product water recovery
of 69%.

Radium-226 removals in the sodium cation exchange process were generally
above 90%, with the exception of Herscher, Illinois, where an 81% removal
was noted.  At the latter plant, about 53% of the radium-226 was removed
in the aeration, settling and filtering pre-processing, before the ion ex-
change step.  The data indicate that radium removal continues for a time
after the hardness removal capacity is exhausted; thus a simple analysis
for hardness may be used as an indicator when operating the plant for radium
removal.  In all of the ion-exchange softener installations 6 to 25 percent
unsoftened water was bypassed around the softener and blended with the fin-
ished water being pumped to the distribution system to provide sufficient
calcium carbonate for deposition of a protective coating on the water mains.

Overall removal of radium-226 by softening and filtering at lime-soda ash
softening plants can reach 95%, dependent primarily on the pH of the process.
Considerable variations in radium removals were noted depending on chemical
dosage, pH range, magnesium removal, non-carbonate hardness removal and
filtration efficiency.  Most of the removal efficiencies were found to fall
within the range of 75% to 96%.

Radium-226 extraction through iron removal units varied from 11% to 53%
using aeration, detention and filtration. The manner of radium removal is
possibly adsorption or catalytic action by the oxidation products (Fe(III)
and Mn(IV)) deposited on the filter media.

Relatively high concentrations of radium in waste waters and sludges must
be considered in determining the final disposal of these wastes.  Currently,
such wastes are generally discharged to watercourses.  An exception is the
discharge of lime sludge to evaporation lagoons in most instances.  Addi-
tional research is needed to determine the most effective methods of waste
disposal.

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                                INTRODUCTION
Naturally occuring radium-226 is found in numerous well-waters.  The U.S.
Environmental Protection Agency (EPA) published interim regulations on July
9, 1976, which limit the concentration of radionuclides in public water
systems (EN 76).  Methods for removing radium had to be identified so that
drinking water treatment plants may be designed to meet the limit for com-
bined radium-226 and radium-228 of 5 pCi/liter.

Studies were performed by two State agencies, under EPA contracts, at 14
cities in Iowa and Illinois to determine the radium removal efficiency of
four water treatment processes; reverse osmosis, aeration and iron removal,
sodium cation exchange, and lime-soda ash softening (SC76 and BE76).  This
work was supplemented by a study at the water treatment pilot plant located
in the EPA's Cincinnati laboratory.

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                            DESCRIPTION OF STUDY

Water supplies were selected for the study on the basis of (1) high raw
water gross alpha or radium-226 content (13 of the 14 supplies had radium-
226 concentrations greater than 5 pCi/1 in raw water), (2) a variety of
water treatment processes, (3) availability for continous operation during
the study and (4) a range of municipal populations served.  A list of the
cities included in the study and some pertinent characteristics is shown
in Table 1.

Samples were collected from raw water supply wells and from points where
treated water enters the distribution system.  In addition, treatment systems
in Iowa and at Herscher, Illinois, were sampled at various points throughout
the treatment processes to determine changes and removals of radium and
other pertinent chemical parameters.  Flows and other data were obtained
to determine whether plants were meeting design rates and to provide data
for determining a material balance of radium-226 removals.

A significant difference between the two States' efforts was that, in Iowa,
each treatment system was sampled over the course of an operating cycle,
with numerous samples taken throughout the process whereas, in Illinois,
each system was sampled on each of three separate occasions at approximately
one-week intervals.  Thus the results from Iowa give a detailed picture
of system operation, while the results from Illinois give an indication
of the variation of operating characteristics over a period of three weeks.
Samples of well water were generally collected near the beginning of a pump-
ing period and following longer pumping times to determine any time related
variability in radium, hardness and other chemical parameters during pumping.

Radium-226 analyses were performed in Iowa at the Iowa State Hygienic Labora-
tory using coprecipitation with mixed barium and lead sulfates in accordance
with Standard Method ASTM D 2460-70.  Illinois radium-226 analyses were
performed by the Argonne National Laboratory using the radon emanation method.
Some samples were collected in duplicate for intra-laboratory collaborative
testing to check the accuracy of the radium-226 analysis.

The pilot plant in Cincinnati was used to investigate the removal of radium-
226 under ideal conditions of lime softening at two different pH levels,
9.5 and 10.6.  The raw water was brought to Cincinnati by truck from the
Slade Avenue plant in Elgin, Illinois.  Samples were collected of raw water,
treated water,  and at two points in the treatment process, and were analyzed
using the radon emanation procedure by EPA in Cincinnati.

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                                         TABLE 1

                        Cities Included in Radium Removal Studies
City
             Plant      Raw Water
Population   Capacity   Ra-226
Served       (V/day)   (pCi/1)
                      Remarks
Reverse Osmosis
Greenfield, Iowa

Iron Removal
Adair, Iowa
Stuart, Iowa
  2212
   750
  1354
570
380
530
Ion Exchange
Dwight Correctional
  Center, Illinois
Eldon, Iowa
Estherville, Iowa
Grinnell, Iowa
Herscher, Illinois
Holstein, Iowa
Lynwood, Illinois

Lime-Soda Ash Softening
Elgin, Illinois     25,000
Peru, Illinois      12,400
Webster City, Iowa    8488
West Des Moines,
  Iowa              16,441
            18,000
              6830
              5000

              9730
14
13
16
235
1319
8108
8402
1000
1445
4000
110
360
3300
3790
380
590
600
3.3
49
5.7
6.7
14.3
13
14.7
          5.6
          6.0
          7.8

          9.3
Aeration & continuously
regenerated greensand filters

Aeration & pressure iron
removal filtration

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                                   RESULTS

                               Reverse Osmosis

In the reverse osmosis demineralizing process the high hardness water is
pressurized and piped into a reverse osmosis unit where relatively pure
water diffuses through the semipermeable membrane and becomes the product
water, leaving a concentrated reject water.  The much greater rejection
of divalent ions, such as Ca, Mg, Ra and 864, than the monovalent ions,
Na and Cl, is characteristic of essentially all reverse osmosis membranes.

The usual water supply for Greenfield, Iowa, is an impoundment of surface
water.  A reserve source of water from a deep well is used during periods
of drought.  The brackish well water, with a total solids content of more
than 2200 mg/1, is treated in a reverse osmosis unit installed in 1971.
A description of the plant and discussion of operating results was published
in 1972 (MO 72).  Raw, product, and reject water samples were collected
and analyzed for radium-226 and other chemical constituents.  The results
are shown in Table 2.

                                   TABLE 2

              Ra-226 and Hardness Removals at Greenfield, Iowa
                    Reverse Osmosis Water Treatment Plant
Sampling
Point
Well Supply
RO Plant Effluent
Ra-226
Percent
pCi/1 Removal
14
0.6 96

Hardness
mg/1 Percent
as CaCO^ Removal
610
29
95
The average radium-226 concentration in the reject water was 43 pCi/1, where
31% of the influent water was rejected and 69% was converted to low hardness
product water.

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                          Iron  and Manganese  Removal

 The presence  of iron and  manganese  in  drinking water  is  objectionable  pri-
 marily because  of  taste and  the precipitation of  these metals  turns  the
 water a turbid  yellow-brown  color.   The  treatment processes  employed in
 the removal or  control of iron and  manganese include:

 1.   Precipitation  and filtration

      a.   Aeration,  detention (or sedimentation) and filtration

      b.   Oxidation by potassium permanganate, chlorine or  chlorine dioxide

 2.   Ion exchange

      a.   Continuously regenerated permanganate greensand filter

 Iron and manganese removal is  utilized in  some form of pretreatment  at five
 ion-exchange  softening plants  and as the only removal process  at  two other
 plants selected for study.   The results  are  shown on  Table 3.

 A tabulation  of radium removal, iron removal, manganese  removal and  pH (Table
 4)  suggests that radium-226  is  being removed on the manganese, just  as Mn-
 impregnated fibers  have been reported  to remove radium (MO 75).   There are
 radium-226 removals of 46-56%  when  there is  a significant manganese  removal.
 Fair (FA 68)  notes  that "Hydrous oxides  of Fe(XTT) and Mn(IV)  have high
 sorption capacities for bivalent metal ions."  Also,  "Sorption capacities
 for Mn4"1" at pH  8 are on the  order of 1.0 and 0.3  mole of Mn(II) sorbed per
 mole of  Mn02  and Fe(OH)3,  respectively."  Although this  may  explain  the
 removal  of radium  at these plants,  further studies are required to confirm
 this  theory.

 It  was noted  at several supplies that  there  was significant  reduction  in
 radium-226 content  after  aeration and  detention alone, before  the water
was  filtered.   Further studies  will be required to fully understand  this
phenomenon.

                           Sodium Cation Exchange

Water softening by  the sodium  cation exchange (zeolite)  process depends
upon  the ability of certain  substances to  exchange cations with other  cations
dissolved in water.   When  hard  water is  passed through a sodium cation ex-
changer, the  calcium and magnesium  in the  hard water  replaces  the sodium
on  the exchange  medium.  Because the reaction is  reversible, after all of
 the  readily replaceable sodium  has  been  exchanged, the cation  exchange medium
can be regenerated  with a  solution  of sodium chloride.   In the regeneration
process, the  calcium and magnesium  on the  exhausted cation exchanger are
replaced with a fresh supply of sodium from  the regenerating brine solution.
Then, after washing to free  it  from the  calcium and magnesium  cations  and
excess salt,   the regenerated exchanger is  ready to soften a new supply of

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                           TABLE 3




Ra-226 and Iron Removals at Water Treatment Plants Using Iron




               and Manganese Removal Processes
Ra-226
City
Filter
Type
Sampling
Point
Iron and Manganese Removal Only
Adair

Stuart

Iron Exchange
Eldon

Estherville

Grinnell

Herscher

Holstein

Greensand

Anthrafilt

Pretreatment
Anthrafilt

Anthrafilt

None

Anthrafilt

Anthrafilt

Well
Filter Eff.
Well
Filter Eff.

Well
Filter Eff.
Well
Filter Eff.
Well
Detention Eff.
Well
Filter Eff.
Well
Filter Eff.
pCi/1

13
8
16
12

49
43
5.7
5.1
6.7
5.7
14.4
6.7
13
7.2
Percent
Removal


38

25


12

11

15

53

45
Iron
mg/1

1.1
0.02
0.94
0.03

2.0
0.3
2.0
0.67
0.71
0.41
0.1
0.0
1.8
0.05
Percent
Removal


98

97


85

66

42



97

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00
                                                   TABLE 4




                 Ra-226,  Iron and Manganese Removals by Iron and Manganese Removal Processes
Ra-226 (pCl/1)
City
Adair

Eldon

Estherville

Grinnell

Herscher









Holstein

Stuart

Raw
6.9
pH 6.7-6.9
49
pH 7.8
5.7
pH 7.7
6.7
pH 7.6
14.9
14.5
14.9
14.3
14.0
13.9
13.9
14.1
14.3
pH 7.6-8.3
13
pH 7.4-7.6
16
pH 7.6-7.9
Treated
6.7

43

5.1

5.7

6.6
6.4
6.9
6.9
6.9
6.8
7.3
6.3
6.5

7

12

%Removal
3

12

11

15

56
56
54
52
51
51
47
55
55

46

25

Raw
0.5

2.0

2.0

0.7

0.2
0.4
0.1
0.1
0.1
0.1
0.2
0.1
0.1

1.8

0.94

Iron (mg/1)
Treated
0.01

0.3

0.67

0.41

0
0
0
0
0
0
0.1
0
0

0.09

0.03

%Removal
80

85

66

42

-
-
-
-
-
-
-
-
-

95

97

Manganese
Raw
0.01

0.01

0.24

0.01

0.47
0.41
0.48
0.39
0.45
0.63
0.44
0.53
0.50

0.15

0.01

Treated
0.01

0.01

0.27

0.01

0.02
0.01
0.01
0
0
0
0.13
0.02
0

0.01

0.01

(mg/D
%Removal
_

-

-

-

96
98
98
100
100
100
70
96
100

93

-


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hard water.  The ion-exchange media studied included both naturally occur-
ring greensand and synthetic polystyrene resins (zeolite).

Ion exchange softening removes nearly 100% of the hardness from the treated
water.  Consequently, unsoftened water is blended with the ion exchange
softener effluent to provide sufficient calcium carbonate for deposition
of a protective coating on the water mains and to reduce treatment costs.
Thus the water entering the distribution system usually has a greater radium
concentration than that leaving the softener.  The radium concentration
in raw water could be the controlling factor in the amount of blending that
would be permitted in order to meet the radium limit in drinking water.

The results of the measurements at ion exchange process water treatment
plants are shown in Table 5.

The data shown from the plants in Illinois are the averages of nine separate
data points.  Ranges in the percent reduction of radium-226 through softeners
at the three cities are:

                Dwight         70.7 - 98.3
                Herscher       68.4 - 93.9
                Lynwood        94.7 - 98.2

It was determined that the removals vary somewhat over a softener cycle,
between regenerations.  Radium-226 removal usually continues for a short
period after hardness breakthrough occurs.  However, if the cycle continues
for a longer period after hardness breakthrough, radium-226 removal drops
rapidly.

Samples of softener brine and rinse effluent during regeneration were taken
at various times during the regeneration cycle.  Regeneration normally re-
quires one to two hours.  It was found that the major portion of the radium-
226 leaves the ion-exchange media over a rather short period - 10 to 30
minutes.  Maximum radium-226 concentrations in the softener brine and rinse
effluents ranged from 320 to 3500 pCi/1.

                           Lime-Soda Ash Softening

This process of softening depends on the use of lime and soda ash to change
the soluble calcium and magnesium compounds into nearly insoluble compounds
which are flocculated, settled and filtered.  Conditions for carrying out
the precipitation of calcium and magnesium vary because different pH levels
are needed for each, about pH 9.5 for maximum precipitation of calcium car-
bonate and pH 10.5 for maximum precipitation of magnesium hydroxide.  Thus,
if the magnesium concentration is low, treatment to a pH of 9.5 will be
sufficient.  If the magnesium concentration is high, excess lime, to produce
a pH of 10.5, can be used.  A more economical treatment is to raise the
pH to 10.5 to precipitate the magnesium in a primary basin, then recarbonate
with carbon dioxide to pH 9.5 to precipitate excess calcium in a secondary
basin.

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                           TABLE 5

Ra-226 and Hardness Removals at Water Treatment Plants Using
                   Ion Exchange Processes
Softener
City Type
Dwight Correctional
Center Greensand


Eldon Zeolite



Estherville Zeolite



Grinnell Zeolite




Sampling
Point
Well
Softener Eff.
Distribution
System
Softener
Influent
Softener Eff.
Distribution
System
Softener
Influent
Softener Eff.
Distribution
System
Softener
Influent
Softener Eff.
Distribution
System
Ra-226
Percent
pCi/1 Removal
3.25
0.36 89

0.65
43
1.9 96

8.6
5.1
0.3 94

0.4
5.7
0.2 97

1.4
Hardness
mg/1
286
43

67
360
10

136
915
46

76
387
11

120
Percent
Removal

85



97



95



97



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                       TABLE 5 (cont.)

Ra-226 and Hardness Removals at Water Treatment Plants Using
                   Ion Exchange Processes
City
Herscher




Holstein




Lynwood



Softener Sampling
Type Point
Zeolite Softener
Influent
Softener Eff.
Distribution
System
Zeolite Softener
Influent
Softener Eff.
Distribution
System
Zeolite Well
Softener Eff.
Distribution
System
Ra-226
Percent
pCi/1 Removal

6.7
1.3 81

2.4

7.2
0.5 93

0.8
14.7
0.4 97

1.8
Hardness
mg/1

404
83

141

885
18

346
848
-

78
Percent
Removal


79




98







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Normally, soda ash is added as needed to precipitate non-carbonate hardness,
but due to a soda ash shortage, the West Des Moines plant was using only
a small quantity.  The Webster City plant was using lime only during the
August, 1974 measurements, but was using soda ash during the February, 1975
restudy.

Results of measurements obtained at water treatment plants using lime-soda
ash softening are shown in Table 6.  That the pH of the softening process
is a parameter that controls radium removal, at least  for water containing
both calcium and magnesium, is demonstrated in Table 6 and in Figure 1.
The least squares fit for a straight line through the  data points of Figure
1 indicates that the radium removal percentages increased as the pH of the
process increased.

The data shown from the plants in Illinois are the averages of three separate
data points, taken at approximate one-week intervals.  Ranges in the percent
reduction of radium-226 at the two cities are:

            Elgin                   86.0 - 89.9
            Peru                    70.6 - 92.4

Samples of lime sludge and filter backwash water were also collected.  The
results were:

                    Lime Sludge     Filter Backwash
                    Ra-226          Ra-226	

Elgin               6.1 pCi/g       18.3 pCi/1
Peru                9.0 pCi/g       36.9 pCi/1
Webster City        980 pCi/1       50   pCi/1
West Des Moines    2300 pCi/1        6.3 pCi/1

                     Pilot Plant (SO 75)*

The Environmental Protection Agency Municipal Environmental Research Labora-
tory,  Cincinnati, Ohio, operates a conventional coagulation water treatment
pilot  plant.  The pilot plant, designed for flexibility in operation, is
capable of treating in parallel two 7.6 1/min. streams of water.

The two treatment systems each consist of two rapid mix tanks (in series),
flocculation basin, sedimentation basin, and one or more filters (in paral-
lel).  The theoretical detention times for the mix tanks, and flocculation
and sedimentation basins are 1 minute, 60 minutes, and 6.5 hours respectively.
 *We  thank Mr. Thomas J. Sorg, Research Engineer, Municipal Environmental
 Research Laboratory, U.S. Environmental Protection Agency, Cincinnati, Ohio,
 for  providing access to, and the operation of the pilot plant.
                                      12

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                           TABLE 6

Ra-226 and Hardness Removals at Water Treatment Plants Using
                   Lime-Soda Ash Softening
Ra-226
City
Elgin

Peru

Webster City
(Aug. 1974)


Webster City
(Feb. 1975)

West Des Moines



Sampling
Point
Well
Filter Eff.
Well
Filter Eff.
Well
Clarifier #1 Eff.
Clarifier #2 Eff.
Filter Eff.
Well
Clarifier Eff.
Filter Eff.
Well
Contact Unit
Eff.
Filter Eff.
pCi/1
5.6
0.8
5.8
1.1
6.1
1.9
2.6
0.9
7.8
0.6
0.3
9.3

2.6
2.4
Percent
Removal

88

81



85


96



75
Hardness
mg/1
237
102
326
94
507
333
282
262
482
150
106
376

215
190
Percent
Removal

57

71



48


78



50
pH of
Process





10.0
10.1
9.3

11.0
9.9


10.1-10.4
9.4-9.5

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_ 100
o
>
o
E
o>
CC



I  8O
o
a:
0)
0.
   60
                            10

                    Process pH
J

 II
Figure I   Radium  Removal  vs Softening pH
                          14

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The water to be treated is pumped to  the first rapid mix tank.  Normally,
the pH control chemical is added in the first mixing tank and coagulant in-
troduced in the second tank.  From the mixing tanks, the water flows by gra-
vity through the flocculation and settling basins to the filters, which
consist of 10.8 cm diameter clear plastic cylinders providing 93 cm2 of
media surface area.  A pump on  the effluent side of each filter controls
the flow rate through the filter with the excess water wasted through an
overflow located several feet above the filter media.  For the radium re-
moval studies, two parallel filters were used.  One was a dual-media filter
containing 50.8 cm of No. 1-1/2 Anthrafilt over 30.5 cm of 0.4 mm effective
size Muscatine sand.  The other filter consisted of 76.2 cm of granular
activated carbon, Filtersorb 200.  The filtration rate was controlled at
163 1/min/m2.

The plant has instrumentation to record pH of the raw, flocculated, settled,
and filtered water;  turbidity and temperature of the raw, settled, and fil-
tered water; head loss in the filters; and volumes of raw and filtered water
pumped.

Two test runs in August, 1975, were made to determine the removal of radium-
226 from Elgin, Illinois raw water by lime softening.  The tests lasted
about 100 hours each and were run at pH 9.5 and 10.5.  The raw water was
trucked from the Elgin Slade Avenue treatment plant to Cincinnati, Ohio.

For the first test run, lime, at 220 mg/1, was fed into the second rapid
mix tank to increase the pH to 9.5.   Commercial grade lime was used and
fed as a 4 percent slurry.  The water was then flocculated, settled and
filtered.

Duplicate one liter grab samples of the raw, settled and filtered water
were collected three times during the test period.  The settled and filtered
samples were collected about 7 -hours  after the raw sample, the approximate
time required for the water to  flow through the flocculation and settling
basins.  All samples were preserved with 1.5 ml of nitric acid.

The pilot plant was operated in a slightly different manner during the sec-
ond test run.  For this test, 270 mg/1 of lime was added to increase the
pH to 10.5.  After settling, the treated water was pumped through the other
treatment system where the water was  recarbonated to lower the pH to 8.6,
settled for a second time, and  then filtered.  Grab samples were also col-
lected of the raw, settled, and filtered water.  Water samples from the
first settling basin were collected about 7 hours after the raw sample.
Water samples from the second settling basin and filters were collected
about 14 hours after the raw sample.

Results of the two tests indicated that pH affects the removal of radium-
226 (Table 7).  Lime softening at pH 9.5 resulted in removals of 79 percent
for settled water and 84 percent for  filtered water.  Excess lime softening
to a pH 10.5, achieved 92-93 percent  removals in the settled water and 93-
95 percent in the filtered water.  Little or no difference in removals were
noted between the two types of filters indicating that the carbon filter did
not achieve any additional removal by adsorption.

                                     15

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                                         TABLE 7

                    Ra-226 Removal in EPA Lime-Softening Pilot Plant
                               Using Elgin, Illinois Water
Raw
Settled
Dual-Media Filter
Activated Carbon Filter
Raw
First Settling Basin
Recarbonation Settling
  Basin
Dual-Media Filter
Activated Carbon Filter
                          Softened to pH 9.4 - 9.5

                          August 6, 1975   August 7, 1975   August 8, 1975
Average
Cone.
pCi/1
4.19
1.03
0.79
0.75
Softened

D.F

75.
81.
82.
to
August 20,
Cone.
pCi/1
4.78
0.37
0.33
0.30
0.18

D.F

92.
93.
93.
96.

. ,%*

4
1
1
pH
1975

7
. , /o

4
1
7
2
Cone.
pCi/1
3.95
0.94
0.65
0.62
Cone.
D.

76
83
84
F.,%

.1
.6
.4
P
4
0
0
0
10.6, Recarbonation
August
Cone.
pCi/1
4.86
0.39
0.36
0.30
0.28
21,
1975
Ci/1
.87
.69
.61
.65
to pH
D.F.

85.9
87.4
86.6
8.7
Cone.
,% p
4
0
0
0

Ci/1
.34+. 48
.89+. 18
.68+. 09
.67+. 07

D.F.,%

79.1+5.9
84.0+3.2
84.3+2.3

Average
Cone.
D.

92
92
93
94
F.,%
_
.0
.5
.8
.3
P
4
0
0
0
0
Ci/1
.82+.
.38+.
.35+.
.30+.
.23+.

19
02
02
00
07
D.F
_
92.
92.
93.
95.
. ,%

2+0.3
8+0.4
8+0.1
2+1.3






                          *D.F. - Decontamination Factor  (The  Removal  Efficiency)

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                            SUMMARY OF RESULTS

The radium removal efficiencies of four water treatment processes are shown
in Table 8.

                                  TABLE 8

         Ra-226 Removal Efficiencies in Water Treatment Processes
Process
City
Percent Removal
Reverse Osmosis

Iron Removal
Ion Exchange
Lime-Soda Ash
 Softening
Greenfield, Iowa

Adair, Iowa
Eldon, Iowa
Estherville, Iowa
Grinnell, Iowa
Herscher, Illinois
Holstein, Iowa
Stuart, Iowa

Dwight Correctional
 Center, Illinois
Eldon, Iowa
Estherville, Iowa
Grinnell, Iowa
Herscher, Illinois
Holstein, Iowa
Lynwood, Illinois
Elgin, Illinois
Peru, Illinois
Webster City, Iowa, pH 11.0
West Des Moines, Iowa, pH 10.1
Cincinnati Pilot
 Plant, pH 9.5
Cincinnati Pilot
 Plant, pH 10.6
      96

      38
      12
      11
      15
      53
      45
      25
                                                              89
                                                              96
                                                              94
                                                              97
                                                              81
                                                              93
                                                              97
      88
      81
      96
      75
      84

      95
                                     17

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                                REFERENCES

EN 76 Environmental Protection Agency, 1976, "40 CFR 141 Interim Primary
Drinking Water Regulations, Radionuclides," Federal Register 41, 28402.

BE 76 Bennett, D.L., Bell, C.R. and Markwood, I.M. , 1976, USEPA Rept. ORP/
TAD-76-2, "Determination of Radium Removal Efficiencies in Illinois Water
Supply Treatment Processes."

FA 68 Fair, G.M., Geyer, J.C., Okun, D.A., 1968, Water and Wastewater
Engineering, Vol. 2.

MO 72 Moore, D.H., 1972, "Greenfield, Iowa, Reverse Osmosis Desalting Plant,
"Journal American Water Works Association, 64, 781.

MO 75 Moore, W.S., Cook, L.M., 1975 "Radium Removal from Drinking Water,"
Nature, 235.

SC 76 Schliekelman, R. J., 1976, USEPA Rept. ORP/TAD-76-1, "Determination
of Radium Removal Efficiencies in Iowa Water Supply Treatment Processes."

SO 75 Sorg, T. J., 1975, Personal Communication, USEPA, Municipal
Environmental Research Laboratory, Cincinnati, Ohio.
                                      18

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
1. REPORT NO.

 ORP/TAD-76-5
                                                            3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND~SUBTITLE

 Determination  of  Radium Removal  Efficiencies in Water
 Treatment Processes
             5. REPORT DATE
                        1976
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 W.L.  Brinck, R.J.  Schliekelman, D.L.  Bennett,
 C.R.  Bell,  I.M.  Markwood
             8. PERFORMING ORGANIZATION REPORT NO.
               ORP/TAD-76-5
9. PERFORMING ORG "XNIZATION NAME AND ADDRESS

 U.S.  Environmental  Protection Agency
 Office of Radiation Programs
 Washington, D.C.   20460
                                                            10. PROGRAM ELEMENT NO.
             11. CONTRACT/GRANT NO.
 12. SPONSORING AGENCY NAME AND ADDRESS
   Same as 9
                                                            13. TYPE OF REPORT AND PERIOD COVERED
                                                            14. SPONSORING AGENCY CODE
                                                              EPA-ORP
 15. SUPPLEMENTARY NOTES
 16. ABSTRACT

  Numerous well-water supplies for  public water systems contain  naturally occuring
  radium-226.  Methods for removing  radium from drinking water are needed so that
  drinking water  treatment plants may  meet the limit set in  the  EPA drinking water
  regulations for radium in drinking water.

  Studies were performed by State agencies at 14 cities in  Iowa  and Illinois to
  determine the radium removal efficiency of four water treatment processes.  Popu-
  lations served  by  the water treatment  plants ranged from  235 to 25,000.  The
  radium-226 concentration in the raw  water was greater than  5 pCi/liter at 13 of the
  supplies and ranged from 3 to 49  pCi/liter.

  Radium removal  efficiencies at plants  utilizing reverse osmosis and sodium ion-ex-
  change processes were generally about  92%.   A much wider  range of removal
  efficiencies, 75%  to 95%, was found  at plants utilizing the lime-soda ash softening
  process with the removal  varying with  process pH.  Plants utilizing iron removal
  processes only  were found to have  radium removals ranging from 11% to 53%.
 17.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                               b.IDENTIFIERS/OPEN ENDED TERMS
                             cos AT I Field/Group
  Water,  Treatment, Removal
  Radioactivity, Radium
  Potable Water
  Natural Radioactivity
  Water Treatment
  Chemical Removal
 13. DISTRIBUTION STATEMENT
19. SECURITY CLASS (ThisReport)
                                                                          21. NO. OF PAGES
                                                 Unclassified
                                               20. SECURITY CLASS (This page)
                                                 Unclassified
                                                                          22. PRICE
EPA Form 2220-1 (9-73)


-.VU.S. GOVERNMENT PRINTING OFFICE: 1977-757-056/5640  Real on No. 5-||

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