United States
Environmental Protection
Agency
Municipal Environmental Research
Laboratory
Cincinnati OH 45268
EPA-600/2-79-156
November 1979
Research and Development
Dissolved  Oxygen
Impact from  Urban
Storm  Runoff

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.  Environmental Health  Effects Research
      2.  Environmental Protection Technology
      3.  Ecological Research
      4.  Environmental Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency Energy-Environment Research and Development
      8.  "Special" Reports
      9.  Miscellaneous Reports

This report has been assigned  to the ENVIRONMENTAL PROTECTION TECH-
NOLOGY series. This series describes research performed to develop and dem-
onstrate instrumentation, equipment,  and methodology to repair or prevent en-
vironmental degradation from point and non-point sources of pollution. This work
provides the new or improved technology required for the control and treatment
of pollution sources to meet environmental quality standards.
This document is available to the public through the National Technical Informa-
tion Service. Springfield, Virginia 22161.

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                                   EPA-600/2-79-156
                                   November  1979
          DISSOLVED OXYGEN IMPACT
          FROM URBAN STORM RUNOFF
                    by

  Thomas N. Keefer, Robert K. Simons, and
             Raul S. McQuivey
          The Sutron Corporation
        Arlington, Virginia  22209
          Contract No. 68-03-2630
              Project Officer

               John English
       Wastewater Research Division
Municipal Environmental Research Laboratory
          Cincinnati, Ohio  45268
MUNICIPAL ENVIRONMENTAL RESEARCH LABORATORY
    OFFICE OF RESEARCH AND DEVELOPMENT
   U.S. ENVIRONMENTAL PROTECTION AGENCY
          CINCINNATI, OHIO  45268

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                          DISCLAIMER
     This report has been reviewed by the Municipal Environmen-
tal Research Laboratory, U.S. Environmental Protection Agency,
and approved for publication.  Approval does not signify that
the contents necessarily reflect the views and policies of the
U.S. Environmental Protection Agency, nor does mention of
trade names or commercial products constitute endorsement or
recommendation for use.

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                           FOREWORD
     The Environmental Protection Agency was created because of
increasing public and government concern about the dangers of
pollution to the health and welfare of the American people.
Noxious air, foul water, and spoiled land are tragic testimony
to the deterioration of our natural environment.  The complexity
of that environment and the interplay between its components re-
quire a concentrated and integrated attack on the problem.

     Research and development is that necessary first step in
problem solution and it involves defining the problem, measuring
its impact, and searching for solutions.  The Municipal Environ-
mental Research Laboratory develops new and improved technology
and systems for the prevention, treatment, and management of
wastewater and solid and hazardous waste pollutant discharges
from municipal and community sources, for the preservation and
treatment of public drinking water supplies, and to minimize the
adverse economic, social, health, and aesthetic effects of pol-
lution.  This publication is one of the products of that re-
search, a most vital communications link between the researcher
and the user community.

     This report investigates the correlation between storm run-
off and dissolved oxygen deficits downstream of urban areas.
Several hundred station years of water quality monitor flow and
rainfall data obtained by the U.S. Geological Survey, the U.S.
Environmental Protection Agency, the National Weather Service
and other government agencies are used in the study.
                               Francis T. Mayo
                               Director
                               Municipal Environmental
                               Research Laboratory
                              111

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                           ABSTRACT
     The primary objective of the research reported here was to
determine if on a national basis a correlation exists between
strength of dissolved oxygen (DO) deficits and the presence of
rainfall and/or storm runoff downstream of urban areas.   A
secondary objective was to estimate the magnitude and extent of-
the problem.

     One hundred and four water quality monitoring sites in and
downstream of urban areas throughout the country were considered
for inclusion in the study.  These were screened from over 1000
monitors maintained by federal and state agencies such as the U.S.
Geological Survey, Environmental Protection Agency (EPA), Ohio
River Valley Sanitation Commission and Wisconsin Department of
Natural,Resources.  Daily data were obtained and processed for
83 of the 104 candidate sites.   Of the ,83 monitors considered,
42 percent or roughly one monitor in two had data which demon-
strated a 60 percent or greater probability of a higher than
average DO deficit occurring at times of higher-than-average
stream flow or on days with rainfall.  This result was obtained
by considering daily data for entire water years.  Not all years
at any given station exhibited a 60 percent probability.  One to
three years out of five is typical.  DO levels fell to less than
75 percent saturation at most of the sites where 60 percent or
greater probability existed.  Levels of 5 mg/1 or less were not
uncommon.

     Detailed hourly data analysis was made .at 22 of the sites
with high correlation between flow and DO deficit.  Typically,
at times of steady low flow the DO fluctuates widely on a daily
cycle.  These cyclic changes range from 1 to 7 mg/1.  When a
storm event occurs and the flow increases, the diurnal cycle
disappears.  The minimum DO drops from 1 to 1.5 mg/1 below the
minimum values observed during steady flows and remains constant
there for periods ranging from one to five days.  As the flow
event subsides, the DO level resumes its cyclic behavior.  Of
the 22 monitors examined on an hourly basis, 11 would not meet
a 5.0-mg/l DO standard.  Six of the 11 would not meet the EPA-
suggested 2.0-mg/l-for-four-hour standard.  Streeter-Phelps
analysis indicated that two additional monitor sites at which
hourly data were examined would not have met the EPA standard
had they been properly located.  An additional two sites at which
hourly data could not be obtained would also not have met the
EPA standard.

                               iv

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     In general, the data examined here indicate that 19 percent
of the 104 cnadidate monitors might not meet a 5.0-mg/l standard
and 15 percent might not meet a 2.0-mg/l standard.  Frequency of
violations was not tabulated exactly but appears to be zero to
five times per year at sites with correlations.

     The data base from which this study was drawn is not geo-
graphically homogeneous.  By far, the largest number of monitors
is in the midwest and northeast.  Less than one-half of the
states are represented.  No conclusions can thus be drawn on the
national scope of either correlations or standards violations.
Further study of monitor sites with both strong correlations and
standards violations is recommended to specifically identify
causes.  The frequency of standards violation appears to be low,
but the causes should be identified to prevent the frequency
from increasing.

     This report was submitted in partial fulfillment of
Contract No. 68-03-2630 by the Sutron Corporation under the
sponsorship of the U.S. Environmental Protection Agency.  This
report covers a period from November 18, 1977 to May 1, 1979
and work was completed as of May 1, 1979.
                               v

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                           CONTENTS
Foreword	.	   iii
Abstract	    iv
Figures	viii
Exhibits	viii
Tables	    ix
English to Metric Conversion Units 	    xi
Acknowledgments  	   xii

   1.  Introduction  	     1
   2.  Summary of Findings 	     6
   3.  Conclusions 	     9
   4.  Recommendations	    11
   5.  Site Location and Screening	    13
   6.  Daily Correlation Analysis  	    26
   7.  Detailed Site Analysis	    57
   8.  Assessment of Extent and Causes of Problem  ....    76

References	    94
Appendices

   A.  Water quality data collection agencies  	    96
   B.  Monitor sites considered for analysis 	   119
   C.  Results of daily correlation analysis 	   128
   D.  Results of detailed site analyses	   152
                              Vll

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                            FIGURES
No.                                                        Page

1.   Card format used by National Climatic Center for
     weather data	   33

2.   Typical daily flow and DO records illustrating
     high degree of correlation between high flow
     and low DO	   41

3.   Box or compartment method used to analyze daily
     data for correlation between high flow and low DO. .   43

4.   Streeter-Phelps analysis results for Scioto River
     at Chillicothe, OH	   69

5.   One month of hourly data for the Scioto River
     at Chillicothe, OH	   74

6.   Hourly data for one-month period, Scioto River
     at Chillicothe, OH	   75

7.   DO/flow correlation on the Little Miami River
     near Spring Valley, OH	   79

8.   Probability of low DO at high flow versus per-
     centage of urban area	   87
                           EXHIBITS

No.                                                        Page

1.   Tape File Structure Description, ORSANCO Data  ...    39

2.   Site Analysis Form - Streeter-Phelps ........    59

3.   Site Analysis Form ..........••••••.    60
                             Vlll

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                            TABLES
No.                                                         Paqe
1.   OWDC Regions and Number of Agencies Collecting
     Water Quality Data	15

2.   List of All Sites Considered for Daily or Hourly
     Analysis	23

3.   Study Code Classifications	   24

4.   USGS, 1,656-Byte, Magnetic-Tape Output Format  ....   28

5.   Record Arrangement on Disk File for STORET
     MORE = 4*	32

6.   Card Image Content for National Climatic Center
     Weather Data	34

7.   Data Block Structure, ORSANCO Data	38

8.   Eligible Sites not Analyzed and Reasons	47

9.   Monitor Sites Exhibiting a 60 Percent or Greater
     Probability of Low DO During High Flow or Periods
     of Rainfall	49

10.  Monitor Sites with 60 Percent or Greater Proba-
     bility of Low DO at Times of High Flow .	50

11.  USGS Monitor Sites with 60 Percent or Greater
     Probability of Low DO on Days with Rainfall	53

12.  Streeter-Phelps Analysis Sites 	   68

13.  Sites at Which Hourly Data Were Processed  .  	   70

14.  Monitor Sites at Which DO Levels Below 5.0 mg/1
     Were Observed  	 ...........   81

15.  Monitor Sites at Which EPA DO Standards Were  Not
     Met During Runoff Events ........  	   81
                              IX

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                      TABLES (CONTINUED)
No.                                                         Page

16.  Monitor Sites with Potential for EPA Standard
     Violations If Properly Located 	   82

17.  Problem Sites Per State Versus Number of Monitors
     Per State	85

18.  Sites Recommended for Further Study  	   90

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ENGLISH TO METRIC CONVERSION UNITS








       cfs  x   0.02832   =  m 3/g




       ft  x   0.3048    =  m




       in.  x   2.54      =  cm




     mile  x   1.609     =  km




 sq. miles  x   2.590     =
               XI

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                        ACKN OWLEDGMENT S
     Sutron gratefully acknowledges the cooperation of the U.S.
Geological Survey in obtaining data for this study.  Mr. Robert
Wall of the Automatic Data Processing Unit at the national head-
quarters in Reston, Virginia, was particularly helpful in obtain-
ing and using the daily data.  Mr. I. D. Yost of the Texas
District Office in Austin,  Mr.  R. 0. Hawkinson of the Ohio
District Office in Columbus, and Mr. T. G. Ross of the Pennsyl-
vania District Office in Philadelphia were very cooperative in
obtaining hourly data.
                              XII

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                           SECTION 1

                         INTRODUCTION
BACKGROUND

     Dissolved oxygen (DO) levels have long been taken as indi-
cators of the health of a water body.  The aquatic plant and
animal life depend on the presence of minimum DO levels.  A
stream's ability to assimilate waste is largely a-function of
available DO.                        .

    - In the initial efforts to clean up the nation's waters and
meet DO standards, attention was  focused  on point source waste
discharges.  It was generally believed that upgrading sewage
treatment plants and industrial outfalls to a high treatment
level would restore water quality.  There is little question
that these efforts were beneficial.  However, as more and .more
point sources have come under control,  it has become evident
that nonpoint waste sources are also significant.

     The exact effect of urban nonpoint runoff on DO levels is
difficult to quantify for several reasons.  The phenomenon is
highly transient in nature.  How and what enters a receiving
water is a function of the type of urban activity, land use,
time between storms, distribution of rainfall, collection
methods, and numerous other factors.  Urban runoff may enter a
receiving water directly through storm sewers or through com-
bined storm/sanitary sewers.

     The combined sewers represent a particularly complex prob-
lem.  These route both storm runoff and sanitary waste to a
central treatment facility.  At times of peak flow, the sewer
is designed to overflow directly into a receiving water.  These
overflows may occur at the treatment plant or at a variety of
places in the urban drainage system.

     Studies in Durham, North Carolina (1), indicate that direct
urban runoff is no more desirable than sanitary sewage.  Urban
surface waters receive substantial amounts of organics, solids,
nutrients, heavy metals, and microorganisms.  It is not surpris-
ing then that stream quality may be adversely affected downstream
of urban' areas after a storm event even in the presence of ad-
vanced wastewater treatment.

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     The research presented here is,designed to determine,  as
far as possible, the behavior of DO levels downstream of urban
areas after storms.

SCOPE AND OBJECTIVES

     The original scope of work divided the study into six in-
terrelated areas.  The first and major area was to examine
available, continuously recorded water quality information in
data banks such as U.S. Geological Survey (USGS)  and the U.S.
Environmental Protection Agency's (EPA)  STORET system.  Data
from other state and local agencies such as the Ohio River
Valley Sanitation Commission (ORSANCO),  Wisconsin Department of
Natural Resources  (WDNR), Greater Metropolitan Chicago Sanita-
tion District and others were to be considered when possible.
The data bases were to be reviewed to obtain a five-year his-
torical picture of DO, temperature, and flow in the receiving
waters of the United States at the location of all reliable
continuous water quality monitoring stations.  Concurrent with
this review, five years of hourly rainfall data for the areas
in which the monitoring stations are located were to be obtained
from the National Climatic Center in Asheville, North Carolina,
or other sources.  The DO and temperature records were to be
examined to find all locations downstream of urban areas in
which the DO during the warm weather portion of the year fell
to less than 75 percent of saturation.  At these locations, an
analysis was to be made to determine whether a correlation
exists between wet weather discharge and DO sag and how sig-
nificant the wet weather impact is.

     The second area of study recognized the fact that existing
monitors are not necessarily located to study urban runoff.  The
location of the monitoring stations and rain gages relative to
the urbanized areas and the relative sizes of urban and nonurban
drainage areas contributing to the receiving water were to be
considered in making judgments about urban rainfall/runoff and
DO deficits.

     The third study area was to determine:the accuracy and re-
liability of the monitors used in the research.  Inoperative
periods and frequency of maintenance were variables to be con-
sidered.

     The fourth component of the Scope of Work was a reemphasis
of the need for studying hourly variations in the variables of
interest.  Study, of daily averages to determine whether a moni-
tor was to-be included in the study,was permissible ,but hourly
values were to be used in the final analysis.

     The fifth study area was to.perform an in-depth analysis of
sites with a strong high flow, low DO correlation.  The tradi-
tional Streeter-Phelps  (Thomann  (2) p. 110) technique was to be

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used to determine if severe oxygen sags could be caused by the
particular urban area and how many stream miles (Kilometers —
see conversion factors page 238)are affected.

     The-final study area was to analyze the study results on a
national basis and attempt to estimate the overall impact of
urban storm runoff.  The analysis was to be stated in terms of
stream miles affected, if possible.

     For the most part, the Scope of Work was carried out as
originally intended.  Modifications were made primarily to rec-
ognize the very large number oi: monitors available with less
than the five years of continuous data1and those without hourly
rainfall data.  The need for this modification became apparent
early in the study.  For instance, the USGS maintains over 100
water quality monitors.  Only 12 had five years'of record, were
in close-proximity to a stream gage, and were within reasonable
distance of a primary weather station where hourly rainfall data
were available.  By modifying Area 1 of,the Scope of Work to in-
clude monitors with five years or less of data,'the number to be
considered increased significantly.  This required a greater
emphasis on daily analysis to keep the total amount of data
values manageable.  As stated in the fourth area of the Scope,
of Work, each station was examined on a daily average basis for
inclusion in the study.  Periods of hourly data ranging in
length from 240 to 720 hours at sites with strong correlation
between flow or rainfall and low DO were then examined.

     The major objective of the study was to determine on a
national basis the impact of urban runoff on DO levels in re-
ceiving waters.  Data from points-specific studies such as the
Triangle J Joint Council of Governments "208" waste management
plan (3) have indicated a strong correlation between periods of
low DO and high stream flow.  Similar, results have been obtained
in other locations  (Texas (4) ,> Missouri (5)) .  It was hoped that
by examining existing water quality monitor records that a broad
national picture of the problem-could be obtained if, indeed,
one existed.

DEFINITION OF PROBLEM DO LEVELS

     Tne exact definition of a low DO level is subject to some
debate.  The definition is largely a function of the intended
use.  Thomann  (2) summarizes several representative standards.
The Ohio River Sanitation Commission requires that the dissolved
oxygen should not be less than 5 milligrams per liter  (mg/1)
during at- least 16'hours of any 24 nor less than 3 mg/1 at any
time in the upper basin areas.  In the industrialized lower
basin' and estuary region, a level of 3.5 mg/1 must be maintained
on a daily average basis.  The National Academy of Sciences Com-
mittee on' Water Quality Criteria  (6) recommends a minimum level
                               3

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of 4 mg/1 at all times and-other higher criteria based on the
"natural seasonal oxygen minimum."

     The U.S. Environmental Protection Agency has supported con-
siderable research on DO levels "and their effect on aquatic life.
The DO criteria proposed by EPA for freshwater aquatic life are
given as follows:

     "Freshwater aquatic life:  A minimum concentration
     of dissolved oxygen to maintain good fish popula-
     tions is 5.0 mg/li  The criterion for salmonid
     spawning beds is a minimum of 5.0 mg/1 in the in-
     terstitial water of the gravel." (7)

     Research has established that DO:concentrations as low as .
2 to 3 mg/1 can be tolerated for short duration.  Thus, minimum
DO levels and allowable frequency of exceedance have been estab-
lished.  The DO level-duration relationship is based on measured
survival times of juvenile brook trout when subjected to lethal
DO levels.  Juvenile brook trout are a very sensitive indicator
species.

     The EPA DO criteria based on the survivability of brook
trout are as follows:

     "The minimum receiving water dissolved oxygen
     concentration shall not average less than 2.0
     mg/1 for more than 4 consecutive hours; nor
     shall the minimum receiving water dissolved
     oxygen concentration average less than 3.0
     mg/1 for more than 72 consecutive hours (3
     days) .  In addition, the annual 'average re-
     ceiving water dissolved oxygen concentration
     shall be greater than 5.0 mg/1 for all waters
     which will support warm water species and
     shall be greater than 6.0 mg/1 for all waters
     which will support cold water (salmonid)  spe-
     cies."  (7)

Simulation studies indicate that if the criterion of 2.0 mg/1
for 4 consecutive hours is met, then, in general, all other
criteria will be met. - An allowable frequency of exceedance of
the 2.0 mg/1 criteria of one four-hour period per year is the
basis for biological oxygen demand (BOD)  removal requirements.

     For the purposes of the this study,  DO levels of less than
5.0 mg/1 will be referred to as low DO or poor water quality.
Sites at which the standard of 2.0 mg/1 for more than four consecu-
tive hours is violated will be referred to as problem sites.

     The question of what constitutes a problem is important in
an economic sense.  Since the existence of a problem implies  the

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necessity of a cure, in this case treatment of urban runoff,
considerable dollars are involved.  It was an important part  of
the study, if not a secondary objective, to carefully examine
"problems" before concluding the cause to be urban runoff.

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                           SECTION 2

                      SUMMARY OF BINDINGS


CORRELATION OF LOW DO WITH FLOW AND RAINFALL

     Daily correlation analyses using either flow or rainfall
or both were attempted at 104 stations.  These included USGS,
STORET, and WDNR data.  Of these, 83 had sufficient data to
produce results.  These included 55 USGS monitors, 17 STORET
monitors, and 11 WDNR monitors.


     Of the USGS monitors, 19 exhibited a 60 ^percent or greater
probability of low dissolved oxygen at times of high flow.
Eighteen exhibited a 60 percent or greater probability of low DO
on days with rainfall.  Eight of the stations correlated with
both flow and rainfall.  The total number of stations exhibiting
either type correlation was 30.

     Of the 17 STORET monitors, three exhibited a 60 percent or
greater probability of low DO at times of high flow.  Of the 11
WDNR monitors, three exhibited the 60 percent or greater proba-
bility.

     Out of 104 candidates for analysis, 36 gave positive re-
sults in the correlation analysis.  Twenty-one of the monitors
could not be correlated because of data problems.  Thus, 42
percent of the monitors successfully examined or 36 percent of
the likely candidates gave positive correlation results.  For
discussion purposes, it is thus concluded that four monitors
in ten placed near an urban area might indicate lower than aver-
age DO at times of storm runoff.

MAGNITUDE OF DO DEFICITS

     Because of the coarse time resolution of the daily data, no
direct conclusions could be drawn concerning the severity of the
DO deficits which sometimes accompany high flow or rainfall.
Examination of hourly data at sites with strong daily correla-
tion indicated that water quality violations can occur.  Of the
30 USGS sites, 11 clearly indicate a severe DO deficit at times
of high flow.  Eleven additional sites clearly indicate an
effect from storm runoff but could not be classified as severe.

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Several of these were judged to be too close to the urban area
to detect the maximum deficit in the Streeter-Phelps sense.
Six of the sites did not have water quality problems, at least
concerning DO.  Some depression during storm events would
usually be seen.


CHARACTERISTICS OF DO VARIATIONS

     Although the eleven sites with severe problems varied
widely in size and physical setting, all demonstrated remarkably
similar hourly data records.  The period prior to a storm event
is characterized by fairly large diurnal cycles in the DO level;
fluctuations of 4 to 5 mg/1 are not unusual.  Periods of
supersaturation are often indicated.  As the flow increases,
the diurnal cycles in the DO record disappear.  This may be due
to increased turbidity and depth cutting off the sunlight to
the aquatic plant life at times of high flow.    '

     At the time of peak flow, deficit levels at least equal to
and. occasionally  10 to 15 percent higher than the peak diurnal
cycle value are reached.

     The effect of the storm flow on the DO level lasts quite a
long time.  This long-term effect gives added validity to the
daily analysis procedure.  Sites at which a single hydrograph
peak was examined usually recovered in three to five days.

COMPARISON OF STORM FLOW DEFICITS AND QUALITY STANDARDS

     When measured against existing stream quality standards,
the DO deficits accompanying storm flow may cause water quality
violations.  Hourly data at monitor sites with strong correla-
tion consistently show deficits below 5.0 mg/1 extending over
several days.  The Streeter-Phelps analysis of 10 sites, in-
cluding several with strong correlations, consistently indi-
cated that monitors are not ideally placed to sense maximum
effects.  In many cases, deficits 30 to 50 percent stronger
could theoretically be found.

     Storm-flow-related deficits at some sites consistently vio-
late 2.0 mg/1 - 4 hour standards.  In fairness, it must be
pointed out that at these sites the water quality is marginal
at all times.  Storm events merely push the level down further.
General improvements in water quality at all the critical sites
would help alleviate the problem.

NATIONAL DISTRIBUTION OF SITES

     The question of whether dissolved oxygen deficits caused
by urban runoff is a national problem is difficult to answer.
One item to consider is the geographic coverage of this study.

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     The USGS data base maintained at the Reston, Virginia,
Headquarters contains records for 150 water quality monitors.
These monitors are located in 30 of the 48 conterminous states
or 63 percent coverage.  The distribution of states containing
monitors is highly nonuniform.  Thirteen states are east of the
Mississippi River and 17 are west.  Only 47 of the 150 monitors
are in western states.  If the dividing line between east and
west is considered to be along the western boundaries of Louisi-
ana, Arkansas, Iowa, and Minnesota, the distribution becomes
even more unbalanced.  Only 19 monitors are then located in the
west.

     The distribution of monitors by state is highly nonuniform
also.  Ohio alone has 32 monitors, followed by New Jersey with
13 and Louisiana with 11.

     It was ultimately concluded that the existing monitor net-
work is probably inadequate to define a national problem.  The
probability is approximately one in three of detecting a corre-
lation between flow and DO deficit.  Many states with signifi-
cant urban areas on streams have no monitor records at all in
the major data banks.

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                           SECTION 3

                          CONCLUSIONS
     Several hundred station-years of DO, stream-flow, and temp-
erature data from locations around the United States have been
analyzed to determine if a correlation exists between DO deficit
and either flow and/or rainfall downstream of urban areas.  In
the first portion of the study, daily average data were used to
select stations where a high probability existed of the simul-
taneous occurrence of higher than average flow and/or a rainfall
event and DO deficit.  In the final portions of the study,
hourly flow, rainfall, and DO data were examined at those sites
exhibiting a high probability.  The hourly data examination was
used to more clearly identify the nature of the correlation.  In
addition, a Streeter-Phelps analysis was made at selected sites
to determine if a particular water quality monitor was in the
best location to detect DO deficits from an urban area.  The
following conclusions were drawn from the study:

     •  The probability is approximately one in three
        that analysis of data from a currently existing
        water quality monitor in or near an urban area
        will show a correlation between high flow and/
        or rainfall events and high DO deficit.

     •  In close examination of sites that exhibited
        daily correlation between flow and low DO or
        both rainfall and flow and low DO, strong
        visual evidence was usually found of the cor-
        relation in hourly data records.  Sites that
        exhibited daily correlation with rainfall
        seldom showed any visible evidence of correla-
        tion in hourly data records.  Flow was judged
        the better correlation parameter because it is
        a direct rather than a secondary indicator of
        stream conditions.

     •  At stations where correlation exists, maximum
        deficits observed during periods of high flow
        are equal to or 10 to 15 percent greater than
        the maximum deficits observed during diurnal
        cycles at times of steady low flow.

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©  At locations where water quality is already
   marginal (e.g., 5-7 mg/1 DO),  a storm event
   can result in DO levels less than 4-5 mg/1
   for periods of several days or longer.  Occa-
   sional violations of 2  mg/1 - 4 hour standards occur,

a  Most water quality monitors are located too
   close to the urban areas to detect the maximum
   possible DO deficit in a Streeter-Phelps sense.

•  Flow and DO deficit are correlated in a wide
   variety of urban situations ranging from
   towns of 20,000 population to urban mega-
   lopolises of greater than 1 million population.

•  The absence of a correlation between flow and
   DO deficit does not correlate well with
   the percentage of contributing urban areas in
   the drainage basin.  There are exceptions in
   extreme cases where 50 percent or more of the
   contributing area is urban.

•  There is no reliable way to extend the results
   of this study to an estimate of total affected
   stream miles nationally.  No government agency
   currently publishes data on the distribution
   of population along major rivers.

•  The probability of a high DO deficit occurring
   at times of high flow  is not demonstratably
   greater during the summer months.

•  In most instances, the exact cause of the in-
   crease in DO deficit is not obvious.  In some
   cases, there are heavy concentrations of in-
   dustry along the stream channel.  In other
   cases, a sewage treatment plant is close
   upstream.  Reintrainment of benthic material
   is a likely cause in such locations.  In other
   instances, there is no industry or sewage
   treatment shown on the site maps.  Here, the
   problem may be strictly due to BOD of urban
   runoff, a chemical oxygen demand, or other
   problems.
                         10

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                           SECTION 4

                        RECOMMENDATIONS
     The resources of this study were directed primarily at de-
termining if a correlation exists between increased flow and/or
rainfall events and increased DO deficit below urban areas.
This fact was reasonably well established at a number of loca-
tions.  At several of these locations the dissolved oxygen levels
were low enough to violate water quality standards.  The follow-
ing recommendations are made in an effort to determine why such
a relationship exists:
        More-detailed investigations should be undertaken
        at three to five of the sites with strongest cor-
        relation.  These investigations should include:
        (1) a field study of the river reach through the
        urban area to the monitor; (2)  studies of the
        industrial waste and sewage treatment practices
        along the reach; (3) details on the drainage
        systems from the urban areas; (4)  population
        density, climate, and other pertinent data.

        Sites specifically identified as worthy of study
        include the Cuyahoga River between Akron and
        Cleveland, Ohio; the Scioto River between Colum-
        bus and Chillicothe, Ohio; the Mahoning River
        below Youngstown, Ohio; the Sandusky River below
        Upper Sandusky, Ohio; and six other sites with
        hydraulically complex conditions.

        The data base created as part of this study has
        considerable value.  Consideration should be
        given to publishing a short report on the data
        base and making it available along with digital
        magnetic tapes of the data.

        A project should be undertaken at one site with
        a strong correlation to develop an adequate data
        set to support an unsteady flow water quality
        model.  Streeter-Phelps analysis is not an accu-
        rate representation of water quality behavior
        under storm conditions.  "Adequate" data set
        does not mean historical data collected by random

                              11

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agencies at random times and places.   It means
a concerted effort to obtain synoptic or near-
synoptic values of pertinent water quality
variables in a way designed for use with a
model.  Such a data set would allow meaningful
investigation into the exact behavior of the
DO deficit and the oxygen-demanding material
during storm flow.

Even in the absence of a modeling effort,
further cause-effect type data would be valu-
able at sites with strong flow-DO correlation.
It would be particularly valuable to determine
if the cause is nonpoint runoff,  treatment
plant bypass, reintrainment of settled indus-
trial waste, combined sewer overflow (CSO),  or
other causes.
                     12

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                           SECTION 5

                  SITE LOCATION AND SCREENING
     Locating agencies that maintain data bases of water quality
information and screening for relevant material required a
significant amount of effort.  This section identifies those
sources that were contacted, describes the type of data avail-
able, and outlines the procedure for selecting sites for inclu-
sion in this study.

     The following paragraph from the Scope of Work clearly
describes the required tasks:

     ''Available, continuously recorded water quality
     information in data banks such as EPA's STORET
     system and USGS's NAWDEX system and from other
     sources and agencies such as the Ohio River
     Sanitation Commission  (ORSANCO) that operate
     monitoring stations shall be reviewed to obtain
     a five (5) year historical picture of dissolved
     oxygen, temperature, and flow in receiving waters
     of the United States at the locations of all re-
     liable continuous water quality monitoring
     stations.  Concurrent with this review five  (5)
     year hourly rainfall data for the areas in which
     the monitoring stations are located shall be
     obtained from the National Climatic Center in
     North Carolina and the National Weather Service
     in Maryland, or from other available sources."

The requirement for five years of data was subsequently relaxed,
but initially the project proceeded as directed above.

     In order to comply with this segment of the Scope of Work,
a search of the listed agencies was begun.  During the course
of the search, other sources were discovered and in turn searched
for pertinent data.  The quantity of information available is
quite large and cannot practically be presented here, even as
an appendix.  Instead, each agency that provided useful input
to the study will be discussed individually.  Relevant names and
addresses are provided so that the interested reader can obtain
more-detailed information if desired .  Idiosyncrasies of the
system, if any, are mentioned.  After describing the various
information banks, the screening procedure will be described.

                              13

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AVAILABLE DATA BASES

Office of Water Data Coordination (OWDC)

     The Office of Water Data Coordination is under the Depart-
ment of the Interior.  It is part of the Water Resources Divi-
sion of the USGS.  Its nominal mission  is to "coordinate
federal activities in the acquisition of certain water data."
The OWDC is located in the USGS National .Headquarters at Reston,
Virginia.  Inquiries may be mailed to the USGS Headquarters,
Mail Stop 417.  At the time of this writing, Russell H. Langford
was in charge of the operation.

     The OWDC compiles a catalog of water data collection sta-
tions throughout the United States.  Water quality and quantity
monitors for streams, lakes, reservoirs, estuaries, and ground
water are included.  It publishes a 21-volurae set of "Catalog of
Information on Water Data," the most recent dated 1974.  Another
set was under review but was not available for this study.
These 21 volumes correspond to 21 regions of the country.  These
21 regions, along with the number of federal, nonfederal, and
Canadian agencies contained in each, are listed in TABLE 1.

     The OWDC catalogs draw information from many sources in-
cluding federal agencies, state and local agencies, and Canadian
agencies.  The following statement appears on page 2 of each
catalog:

     "Although not all non-federal agencies acquiring
     water data were contacted, the district offices
     attempted to include those agencies most active
     in water-data acquisition in each state, thereby,
     deriving extensive, though not necessarily com-
     plete, coverage."

All of the agencies in each region are listed in Appendix A.

     A quick glance at Appendix A should convince even the most
casual reader that an, enormous number cf agencies collect water
quality data.  It also should explain why the OWDC catalog was a
primary source of information for this study.  Over 350 non-
federal  (state and local) agencies are listed, plus all the
relevant federal agencies.  The writers are confident that no
more complete list of.such information exists.

     The reader should be aware that OWDC^does not collect or
disperse data.  It merely keeps track of who does.  The OWDC
will supply upon request names and addresses of all the agencies
listed,as well-as-a'personal contact ,and telephone number, if
known^  This was invaluable for the present study.
                              14

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  TABLE 1. OWDC REGIONS AND NUMBER OF
AGENCIES COLLECTING WATER QUALITY DATA
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Region
New England
Mid-Atlantic
South Atlantic-Gulf
Great Lakes
Ohio
Tennessee
Upper Mississippi
Lower Mississippi
Souris-Red-Rainy
Missouri Basin
Arkansas-White-Red
Texas-Gulf
Rio Grande
Upper Colorado
Lower Colorado
Great Basin
Pacific Northwest
California
Alaska
Hawaii and other Pacific islands
Caribbean
Federal
agencies
8
10
10
10
9
6
7
7
5
9
8
7
7
6
9
10
14
13
9
6
4
Non-federal
agencies
5
14
32
15
19
13
31
21
9
36
17
2
2
6
9
14
28
61
4
10
1
Canadian
agencies
2
2
0
2
0
0
0
0
2
2
0
0
0
0
0
0
2
0
1
0
0
                 15

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     One unfortunate idiosyncrasy of the OWDC catalogs is that
the information is not stored in computer data banks.  In order
to locate the continuous monitors, it was necessary to go
through all 21 volumes one page at a time and decipher the codes.

National Water Data Exchange (NAWDEX)

     The National Water Data Exchange is also a program of the
Department of the Interior.  It is administered through the
Water Resources Division of the USGS.  While OWDC is a catalog-
ing agency, NAWDEX actually deals in data.  When fully opera-
tional, NAWDEX will'be capable of searching the complete USGS
water data records as well as the EPA STORET data base.  Contact
with NAWDEX is established through the Office of the Assistant
Chief Hydrologist for Scientific Publications and Data Manage-
ment at the USGS National Headquarters in Reston, Virginia,
Mail Stop 440.  At the time.of this writing, Mr. George W. Whet-
stone was in charge of the office.  The writers dealt with Mr.
Melvin D. Edwards.

     At the time the present study was undertaken, the NAWDEX
program was only capable of scanning the USGS records.  A list
of 45 continuous water quality monitors at which flow data were
available was obtained.  It was subsequently determined that
these could have been found in the OWDC catalogs.  The advantage
of NAWDEX, if there is one, is more current information on the
USGS files.  Better results,  however, can be obtained from the
USGS Automatic Data Processing (ADP) Unit, which is described next.
The cost of a NAWDEX search is roughly $50 to $100.

USGS Automatic Data Processing Unit

     The USGS ADP Unit is located in the National Headquarters
in Reston, Virginia.  Its purpose is to provide standardized
processing programs and procedures for the water resources data
collected by USGS.  The ADP Unit may be contacted ,by writing
the.National Headquarters, Mail Stop 485.  Mr.,Robert B.  Wall
is in charge.

     This unit is the most up-to-date source of information on
the contents of the USGS water quality and flow data base.  It
is also"the place to contact to obtain data in digital format
such as cards or magnetic tape.  For very reasonable prices ($35
to $70) any of the daily parameter values stored by the ADP
Unit can be obtained along with excellent instructions on how
to read and translate the cards or tape.  The personnel of USGS
ADP Unit are some of the most friendly and cooperative of any
encountered in the course of this study.  The work would have
been very difficult without them.
                              16

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EPA's STORET System

     STORET is a computerized water quality data base.  It was
conceived and initiated in the early 1960s by the U.S. Public
Health Service.  Its sole purpose is to allow storage and re-
trieval of water quality information by government users.  Con-
tact with STORET is initiated by calling the User Assistance
Center in Washington, D.C., at (202) 426-7792.  Mr. Phil Lindens-
truth was very helpful to this study.

     The potential STORET user is in for a difficult time if he
does not have connections with a government agency.  While any-
one can walk into the USGS and receive data for a fee, this is
not true of STORET.  Some kind of government account number is
required.  For the purpose of this study it was necessary to
obtain a user identification number through the project officer.


     Finding continuous monitor records in STORET was not easy.
A number of the people at EPA Headquarters were convinced that
no more than half a dozen continuous moni'c ji records were in
STORET.  Over 1100 were eventually located.  Approximately 200
of these monitors were located on lakes, over 100 in pipes, al-
most 100 beside the ocean, and about 50 in intakes and estuaries.
This left about 500 monitors located along rivers.  Data from all
the river sites below urban areas were transferred to a digital
tape for use in this study.

     The water quality data in STORET is in an unusual format.
Daily and hourly observations are mixed together in a continuous
string.  This complicates processing to some degree.  The poten-
tial user should be aware that STORET contains no flow informa-
tion.

U.S. Army Corps of Engineers (COE)

     The U.S. Corps of Engineers maintains on its own or
through USGS a great many water quality monitors.  These are
listed for the most part in the OWDC catalog described earlier.
Virtually all are located at the inlet or outlet of reservoirs
and were of no interest to this study.   No direct data input
from COE is included here.

State and Local Agencies

     Little actual contact was made with state and local agen-
cies during the course of this study.  There are two reasons for
this.  First, the OWDC catalogs are a definitive source of which
state and local agencies collect water quality data.  The very
great percentage of those that do,  did not have continuous data
bases.   They concentrate on random observation. Very few data on
flow are available from such sources.  Second, those rare

                              17

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state agencies that  actually collect continuous data report the
data to the Environmental Protection Agency' s STORET data base..
Thus, it was not necessary to spend a great deal of time coiv-
tacting many places.   Two agencies  that  do maintain their own
data bases are the Wisconsin Department of Natural Resources and
the Metropolitan Sanitation District of Greater Chicago.  They.
are described below.   .

Wisconsin'Department of Natural Resources

     The Wisconsin Department of Natural Resources maintains a
network of 11 water quality monitors.  It also records flow
continuously.  The WDNR may be contacted at Box 7921, Madison,
Wisconsin.  Mr. Mitchell S. Nussbaum of the Water Quality Eval-
uation Section was quite helpful.

     For a very reasonable amount, the WDNR will copy all 11
stations of daily data onto a magnetic tape.   Hourly data are
also available.  The WDNR  is  as helpful and courteous to deal
with as the USGS ADP Unit.

Metropolitan Sanitary District of Greater Chicago

     The Chicago Sanitation District maintains a number of flow-
water quality monitor stations in and around Chicago.  Many are
located in canals.  Hourly data are available, but in digital
forms.  Hand-copying of the numbers in person at its offices
in Chicago is the only way to obtain information.  Even this can
only be arranged with difficulty.  A letter from a government
project officer explaining the need for the data is required.
Because of the manpower and travel requirements, no data were
used from this source in this study.

     At the time of this writing, the point of contact is Dr.
Cecil Lue King, Director of Research and Development, Metropoli-
tan Sanitation District of Greater Chicago, 100 E. Erie Street,
Chicago, Illinois, 60611.

Ohio River Valley Water Sanitation Commission

     The ORSANCO is an interstate compact agency.  It was cre-
ated in 1948 by the states bordering the Ohio River.  Its pri-
mary purpose is to monitor and prevent pollution along the river.
To achieve this, ORSANCO maintains a network of water quality
monitors.  This network reports continuously to the headquarters
in Cincinnati, Ohio, where a complete picture of the quality of
the river at any time is available.  The address of the commis-
sion is 414 Walnut Street, Cincinnati, Ohio, 45202.

     At various times, 56 monitor sites have been placed on the
river.  Half of these have been in continuous operation since
1961;  the DO and temperature data from these stations are

                              18

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available on an hourly basis.  However, no flow data are avail-
able.  For less than $100, ORSANCO will copy all the data onto
a digital tape.

     While the data are readily available, there are serious
drawbacks.  Most important is the data format.  Because of
ORSANCO1s interest in an "overall" look at the basin, the num-
bers are not grouped by station.  Instead, each tape record
contains data for one day for all stations reporting that day-
The records are random length and structured in such a way that
hundreds of tape reads are required to sort the data by station.
A second drawback is the age of the ORSANCO tape drives.  ORSAN-
CO' s system is an IBM 11/30.  The tapes it provides produce
numerous read errors on later-model IBM equipment.  Processing
cost was so high for the ORSANCO data that none is included in
this report.  For example, it cost $45 to transfer three months
of a single station to a disk pack and plot the results.

National Climatic Center

     Precipitation data  for  the present study were obtained
from the National Climatic Center in Asheville, North Carolina.
Its address is Federal Building, Asheville, North Carolina 28801.
Telephone inquiries can be made to (704)  258-2850, ext. 683.

     The Climatic Center is a data bank for the parent agency,
the National Oceanic and Atmospheric Administration (NOAA),
which is part of the Department of Commerce.  A very large
quantity of atmospheric data is available there.  Literally
thousands of rain gages are scattered at small airports and
other locations throughout the United States.  Most of these
report daily.  In addition, it maintains nearly 300 primary
weather stations that record rainfall, temperature, wind, and
relative humidity on an hourly basis.  This voluminous infor-
mation is available in monthly and annual reports and on digital
tapes or cards.

     For this study, only two forms of data were used.  In the
initial phases a digital tape containing daily precipitation and
other variables was obtained.  This type of data is very costly.
For reasons  that  were never clear to the writers, the Climatic
Center charges $33 to mount a tape.  An additional charge of
roughly $50 per single station is encountered as each station
requires a separate tape mount.  These charges are very high
compared to other government agencies on a per-number basis.
They are also much higher than private computer centers.  How-
ever, the Climatic Center is the only available source.  Digital
data have a large lead time of six to eight weeks.

     The large money requirement ruled out obtaining the hourly
data for the later phases of the study in digital form.  Instead,
free copies of "Local Climatologic Data," a monthly publication,


                              19

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were obtained from the National Weather Service (NWS)  in.' Silver
Spring,  Maryland.   These contain the hourly .precipitation for
the month of issue.  The normal single copy price of the local
climatologic data is $0.20.  These may be ordered from the
National Climatic Center in Asheville.

SITE SELECTION PROCESS


     The process of selecting monitors for inclusion in the
study was quite time consuming.  It consisted of four steps.
First, the data bases discussed above were scanned to discover
which of the water quality stations were actually continuous <
monitors.  Next, the continuous monitor sites were located.
Following location, each monitor was classified as to its use-
fulness to this study.  Finally, those with the best classifi-
cation ratings were selected and data obtained.  Each of these
steps will now be described in detail.


Monitor Discovery

     The process of discovering monitor data for use in this
study was complicated by the number of agencies involved and the
variety of cataloging systems.  Many of the possible sources of
information (exclusive of the large federal groups such as USGS
or EPA) were not known to the writers at the outset.  It became
a matter of detective work to go from known specific monitor
listings to more general information.

     The first government agency contacted was the Water Re-
sources Division of the USGS.  The NAWDEX provided a list that
supposedly contained all the continuous USGS water quality
monitors where flow was also recorded.  There were only 45.
Two of the writers had worked for USGS for over 10 years and
were aware of monitors that did not appear on the list.  Further
inquiries led to the Office of Water Data Coordination and in-
dividual USGS district offices in the various states.

     The Office of Water Data Coordination was the best source
of monitor sites discovered in the entire study.  Its 21-volume
catalog contains thousands of locations where sampling activi-
ties occur.  There was only one serious drawback.  Continuous
monitors are not separated out except by letter codes.  Each of
the several thousand pages could contain from zero to 10 moni-
tors useful to the study.  These had to be located by going
through the 21-volume one page at a time, reading the codes, and
writing down potentially useful sites and the governing agency.
This process produced a very comprehensive list of likely sites.

     The USGS maintains a district office in almost every state
in the union.  These offices conduct water quality monitoring

                              20

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through cooperative agreements with many state, local, and other
federal agencies.  Most monitors are designed to specifications
set by the USGS.   The writers initially set out to call all 50
district offices one by one to determine if monitors were avail-
able that did not appear on the NAWDEX list.  Inquiries were
also made concerning activities in the cooperative program.
During this slow process, several districts suggested contacting
the USGS ADP Unit and obtaining a list of the monitors on the
backfile records.  This provided a list of all water quality
monitors maintained by USGS as well as flow stations.  The list
was far more comprehensive and up to date than the one obtained
from NAWDEX.   No further searches were conducted for USGS moni-
tors .

     No difficulty was encountered in determining how many moni-
tors were available from ORSANCO or EPA.  ORSANCO merely pro-
vided a comprehensive list.  Cross-checks verified that the same
information was available through the OWDC catalogs.  At first,
it was difficult to gain access to the STORET system.  Once a
user number was obtained, very little time was required to
obtain lists of the monitors contained in the data base.  A
great many of these were state and local agency monitors that
were also listed in the OWDC catalogs.

     In all, over 1500 monitors that recorded continuous DO and
temperature plus other parameters were located.  The next steps
were to locate, classify, and sort them to determine which were
near urban areas and had flow and rainfall data available.

     The location, classification, and sorting processes are
described in the following sections.  Each of the 1500 monitors
was processed in the same way unless it became obvious for some
reason that it did not apply to the study (for instance, a moni-
tor 50 miles from the nearest town in the middle of a swamp).

Monitor Site Location

     Most monitors were located by means of latitude and longi-
tude coordinates.  All the station lists with the exception of
ORSANCO reported an accurate latitude and longitude for each
site.   ORSANCO locates its stations by COE river mile markers.

     In the early parts of the study, USGS 7.5-minute topo-
graphic sheets were purchased and used to locate monitors and
flow gages.  This proved unwieldy  and expensive.  To avoid
buying so many maps, most locating was done at the National
Headquarters Library of the USGS.  Topographic maps covering 7.5
minutes, 15 minutes, and at a scale of 1:250,000 for the entire
country are available there.  Each monitor was found and its
proximity to an urban area noted.  As mentioned in the previous
section, a number of monitors were rejected from consideraton at
this point if no urban area was in a position to affect the stream.

                              21

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     Locating the monitors on 7.5-minute quadrangles required
one intermediate step.  The appropriate quad sheet name had to
be determined.  This was done by obtaining index sheets for all
50 states from the USGS Cartographic Information Center at the
National Headquarters in Reston,  Virginia.  These were free.
Where possible, the town after which the monitor was named was
located and the quad sheet identified.  If the town could not be
found, rough latitude-longitude was used and several quad sheets
picked.  The quad sheet names and other pertinent information
were entered on a classification form, which will be discussed
shortly.  The format is presented in TABLE 2.

Monitor Site Classification

     Classification of the monitor sites for suitability was an
important step.  Several factors had to be considered.  These
were

     •  proximity to urban drainage area,

     •  presence of continuous record,

     •  length of record,

     •  proximity of flow gage,

     •  proximity of rain gage, and

     •  length of time monitor was in operation.

There were  several hundred monitors to consider, which made it
impossible  to remember even a small portion.  The previously
mentioned standard classification sheet was developed and filled
out at the  time the monitors were being located.  An example of
the completed form is shown in TABLE 2.  Although the form indi-
cates that  it'was used only for monitors in the OWDC catalog, it
was actually used for all monitors in the study.  A complete
list of slightly over 100 monitors considered for analysis is
contained in Appendix B.

     The state column was used to identify both the state in
which" the monitor was located and the 7.5-minute quad sheet
required to locate it precisely.  The station name, agency,
latitude, and longitude columns are self-explanatory.  The site
column identified the type of monitor location.  These were
based on the OWDC catalog description or the writer's observation
of the topographic map. ' The date established is self-explana-
tory.  This information came from either the OWDC catalog or
the agency  that operated the station.  The column'labeled water
discharge indicates whether or not a stream gage was located
near the monitor.  Information obtained in this regard was occa-
sionally misleading.  The USGS, for example, assigns different

                               22

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      TABLE 2. LIST OF ALL SITES CONSIDERED  FOR  DAILY OR HOURLY ANALYSIS
State
Alabama

Colorado





Georgia





Illinois




Louisiana





Station name
Coosa R. at Verbena
Coosa R. at Gadsen
S. Platte R., 60 ave.
S. Platte R., 88 ave.
Burlington Ditch at
York St.
Sand Cr. at
Burlington Ditch
Chattahoochee R. at
Atlanta
Peachtree Cr. near
Atlanta?
Ocmulgee R. near
Warner-Robins?
Calumet R. STWt
Chicago R. Bridge?
Chicago Sanitation
and Ship Canal
at Lockport?
Bayou Tech at
Olivier
Houma Nav. Canal
near Dulac?
Ouachita R.at
Monroe
Agency*
GS
EPA
EPA
EPA
EPA

EPA

EPA

GS

GS

GDI
G01
GDI


GS

GS

GS

Lat.
324756
340057
394826
395115
394802

394837

335132

335133

324017

413946
415333
413408


295718

292306

323019

Long.
862602
855843
1045730
1045615
1045730

1045659

842716

842716

833611

873940
873832
880441


914254

904347

920732

Site
Stream
Stream
Stream
Stream
Canal

Stream

Stream

Stream

Stream

Canal
Stream
Canal


Stream

Stream

Stream

Established
1974
1971
1968
1968
1967

1967

1960

_

1970

1969
1969
1969


1972

1973

1954

Water discharge
available?
Yes
Yes
Yes
Yes
Yes

Yes

Yes

No

No

No
Yes
Yes


Yes

No

Yes

Primary
rain
gage
Montgomery
Gadsen
Denver
Denver
Denver

Denver

Atlanta

Atlanta

Macon

Chicago
Chicago
Chicago


-

-

Shreveport

Applicability
Distance to
, , to study
rain gage (mi)
code
4
4
<10 1
<10 1
<10 1

<10

10 1

10 1

20 4

20 2
5 1
35 2


- -

-

90 4

The agency codes, taken from OWDC, identify the agency that was in charge of the data ; specifically, GS = Geological Survey, EPA = Environmental Protection
Agency, and GO1 = Metropolitan Sanitation District of Greater Chicago.
   was later dropped.

-------
names and  station numbers to monitors  and  gages that are not
exactly in the  same place, even if only a few hundred yards
separates  them.   Thus, the monitor Lonely  River at Outback,
Montana, may be listed by OWDC or the  USGS as having no flow.
A stream gage named Lonely River near  or below Outback, Montana,
may be quite nearby.  This problem was minimized by checking
USGS state reports to determine if what OWDC indicated was true.
The rain column gives the location of  and  distance to the near-
est weather bureau primary weather station (those with, hourly
rainfall data) .   The .distances are in  miles.  The last column,
applicability to study codes, was used to  rate each site as to
its usefulness  to this research.  These ratings tended to be
subjective and  based heavily on how  the monitor's location on
the map appeared in relation to an urban area.

     The classification codes are listed in TABLE 3.  The amount
of urban area was judged by eye.  In general, towns were judged
in relation to  the size of the river.   A town of 1/4 square mile
on the Mississippi was ignored.  The same  town on a small river
was included.   Thus, the terms "significant urban area" and
"small town" were relative rather than absolute measures.  The
criterion  of  15 miles to a weather station was based on judgment
and experience  with other studies.


       	TABLE 3. STUDY CODE CLASSIFICATIONS	

        Code                     Definition

         1          Significant urban area, NWS primary station within 15 miles

         2          Significant urban area, NWS primary station farther than 15 mites

         3          Some urban area, NWS primary station within 15 miles

         4          Some urban area, NWS primary station farther than 15 miles

         5          Small town(s)

         6          No urban area

         7(1-6)       Reservoir or lake
Site Selection

     By the  time the study had progressed to site selection,  it
became apparent that there were very  few places that met the
criteria  in  the Scope of Work. • These criteria were the existence
of five years  of research including hourly flow, DO, and temper-
ature plus 15-mile proximity to a rain gage with hourly data.
                               24

-------
There were 12 in the USGS,  none in ORSANCO, none in EPA'sSTORET,
and only a few with other agencies.

     A decision was subsequently reached through discussion with
the project officer to broaden the Scope of Work.  It was decided
to accept sites with five years or less of data, to examine
sites that had only daily data, and to consider sites that were
not near hourly rain gages.  At the same time, it was decided to
concentrate initially on daily correlations and use the hourly
data for a detailed look at sites with strong daily flow-DO
deficit correlations.

Summary

     A review of the process of site selection is now in order.
Initially, slightly more than 40 USGS monitors were found in the
NAWDEX system.  A search of the OWDC catalog series added 250
more.  Several additional USGS monitors were located through the
ADP Unit.  ORSANCO added 56.  A search of the STORET files pro-
duced 1100.  Thus, there have been nearly 1500 monitor sites
established along the nation's streams, lakes, and estuaries.
Each monitor was located on USGS maps and evaluated for proximity
to urban areas.  They were further rated on proximity to rainfall
and flow gages and for length of record.  Those in proximity to
an urban area of significant size and which were near a flow
gage or primary weather station were selected for daily correla-
tion analysis.  The number of such sites was slightly greater
than 100.  The process of examining these on a daily basis is
the subject of the following section.

     Some explanation is in order on why out of 1500 monitors
less than 10 percent were considered.  The most common reason
was that the monitor was not in or near any urban area.   The
vast majority of EPA's monitors (at least those in the STORET
files)  are at industrial outfalls or in canals or lakes.  This
is also true of the USGS and ORSANCO networks.  A small minority
of monitors were rejected because no flow records were available.
Some were rejected because an examination of the daily monitor
records indicated no quality problems at any time.  Some sites
were incorrectly listed as continuous monitors when in fact they
were just grab-sample locations.

     The list of all monitors considered is too large to conven-
iently publish here, even as an appendix.  Appendix B expands
TABLE 2, presenting 104 sites that were seriously considered for
analysis.  The following section describes how the 104 sites
were analyzed.  Note that the ORSANCO sites considered for anal-
ysis are included even though they were not analyzed because of
the awkward data storage format.
                              25

-------
                           SECTION 6

                  DAILY CORRELATION ANALYSIS
GENERAL CONSIDERATIONS

     The necessity for basing initial correlation efforts on
daily data stemmed from broadening the Scope of Work to accept
monitors with less than five years of data or located more than
15 miles from an hourly rain gage.  Hourly data are difficult to
obtain and process.  For example, hourly data from the USGS are
not stored on permanent files in a computer or on magnetic tape.
They are available only on listings called primary computation
sheets.  In order to analyze a year of this type of data, one
must read 8760 numbers from the sheets and either punch the
values on cards or have them put on tape.  Performing hourly
correlation analysis on 100 sites with an average of 2.5 years
record and four parameters (DO, rainfall, temperature, and stage)
would require 8,760,000 numbers.

     Another important factor restrict:", the use of hourly data.
Hourly precipitation data are only available at about 300 sites
throughout the United States.  Therefore, many dissolved oxygen
monitors are located at such a distance from these primary
weather stations to make an hourly correlation between DO and
rainfall meaningless.

     The necessity of using daily data to supplement the hourly
values was anticipated in the Scope of Work:

     "Some of the available data banks have been sum-
     marized and contain only daily average values.
     These can be utilized to determine whether the
     particular stream segment should be included in
     the analysis, but it will be necessary to obtain
     the hourly parameter variations from the organi-
     zation responsible for the water quality monitor-
     ing or rainfall station in carrying out the
     analysis."

The method of examining daily data first saved a great deal of
computation by allowing use of readily available computer tapes.
The USGS,  STORET, and WDNR data bases were all able to provide
daily values in this form.
                              26

-------
     There were three distinct phases to the daily correlation
analysis.  First, the daily data had to be acquired and converted
to a standard format.  These values were stored on a computer
direct-access file.  Second, the stored values had to be re-
trieved and processed with suitable correlation programs.  Final-
ly, sites for hourly and detailed analysis were selected.  Each
phase will be discussed in turn.  The computer processing and
results of the analysis will be presented first.  The process
used for selecting sites for hourly analysis completes the sec-
tion .

PRELIMINARY DATA ACQUISITION PROCESSING

     Four major computer programming efforts were required to
accomplish the first phase of data processing.  Each type of
taped data (USGS, NWS, STORET, and WDNR) required different
recovery and processing methods.  A short discussion o± the data
formats and the processing problems encountered with each will
now be presented.

USGS Data

     The importance of USGS data to this study cannot be over-
emphasized.  When the site selection process was complete, 62
of its monitors were of interest.  USGS flow data were often
required to supplement DO data from other sources.  For these
reasons, the USGS data were obtained and processed first.

     The USGS ADP Unit is highly cooperative and accustomed to
dealing with the public.  To request data, all that is required
is a letter or memorandum stating what stations and years of
record are of interest.  In from three days to a week the re-
quested data arrives along with a detailed set of instructions
on how to decode it.  The price for 100 station-years of record
including a magnetic tape is around $65.  The appendix of the
instruction book contains a program for reading and listing
either a data tape or cards.  Anyone familiar with programming
can have the program operational in less than a day.

     The data are stored on tape such that data covering a year
are easily accessible at a particular site.  The USGS uses water
years, which begin October 1 and end on September 30 the follow-
ing year.  The data values are stored in a two-dimensional,
12 x 31 array.  This is preceded by header information such as
the state code, latitude and longitude, year of record, and other
information.  Days that do not exist (such as February 31) or
missing data are marked by a 999999 no-value indicator.  TABLE 4
presents the 9-track 1600 bpi tape format used by the USGS.

     The program provided by USGS to read and list the tape was
modified slightly to write the 12 x 31 arrays, the station name,
the year of record, and the latitude-longitude onto a direct

                              27

-------
                                   TABLE 4. USGS. 1.656-BYTE, MAGNETIC-TAPE OUTPUT FORMAT
K)
00
                        Byte
                       position
                         1-2
                         3-4
                         5-9
                        10-24
                        25-28
                        29-32
                       33-36
                       37-38
                       39-40
                       41-44
                       45-1532


                     1533-1535
                     1536-1537

                     1538-1540
                     1541-1588
                     1589-1592

                     1593-1596

                     1597-1600
  Data
  type
               Description
CHAR (2)
CHAR (2)
CHAR (5)
CHAR (15)
FLOAT (6)
FLOAT (6)
FIXED BIN (31)
FIXED BIN (31)
FIXED BIN (15)
FLOAT (6)
FLO AT (6)


CHAR (3)
CHAR (2)

CHAR (3)
CHAR (48)
FLOAT (6)

FLOAT (6)

FLOAT (6)
Blank.
Code for the state in which the station is located.
Code for the agency collecting the data.
Station identification number (right justified).
Cross-section locator. Location of sampling point in the
cross-section. A  value  of '999999'  indicates no value
stored.
Sampling depth. Depth at which sample was collected. A
value of '999999' indicates no value stored. A value of
'111111'  indicates a top sample and '888888' indicates a
bottom sample.
Parameter code.
Calendar year date.
Statistic code.
No  value indicator - value that  is stored in place of a
missing daily value. A value of '999999' is stored as the
no value indicator for most data. The no value indicator
is also stored for  non-existent days in the array, such as
February 30.
Two-dimensional  array (12, 31) containing all of the daily
values for a 12-month period. For additional information,
see page 12.
Blank.
Code for the state in which the Geological Survey office
that operates the  station is located.
Code for county in which the station  is located.
Station name.
Drainage area of the site in square miles. A zero indicates
no value stored.
Contributing drainage area of the site in square miles. A
zero indicates no  value stored.
Depth of well. The greatest depth at which water can
enter the well. Applicable only to sites coded as 'GW. A
value of '-99999'  indicates no value stored.
                                      (continued)

-------
                                                         TABLE 4 (continued).
fO
                        Byte
                      position
                      1601-1604
                      1605-1608
                      1609-1610

                      1611-1612

                      1613-1614
1615-1620

1621-1627

1628-1629
                      1630-1637
                      1638
                      1639
                               Data
                               type
                                           Description
                          FIXED DEC (7, 2)
                          FIXED BIN (31)
                          FIXED BIN (15)

                          FIXED BIN (15)

                          CHAR (2)
CHAR (6)

CHAR (7)

CHAR (2)
                          CHAR (8)
                          CHAR(l)
                          CHAR(l)
                          Datum of gage to nearest hundredth of a foot.
                          Hydrologic unit code.
                          Retrieval  sequence number for data control of batched
                          retrievals.
                          Month number that  contains the beginning date of the
                          12-month period. For additional information, see page 12.
                          Site code. The codes are:
                                                                               SW = Stream
                                                                               SP  = Spring
                                                                               ES  = Estuary
                                                                            GW = Well
                                                                            LK  = Lake or reservoir
                                                                            ME  = Meteorological
                      1640-1656
                          CHAR (9)
Latitude  of the site  location in  degrees,  minutes and
seconds.
Longitude of the site location in degrees, minutes and
seconds.
Sequence number—used differentiate between stations
having the  same latitude and longitude and to identify
the site  location  in  relation  to  the Earth's spherical
quadrants.
Geologic unit code.
Reserved.
Aquifer type. The codes are:
      U = Unconfined single aquifer.
      N = Unconfined multiple aquifer.
      C = Confined single aquifer.
      M = Confined multiple aquifer.
      X = Mixed (confined and unconfined) multiple
          aquifers.
Blank.
                    Source: "Data Formats for U.S. Geological Survey Computer Files Containing Daily Values for Water Parameters," by Charles R. Showen, 1976.

-------
access disk file.  This allowed any year at any station to be
called into the computer without reading any others.   Because of
the relatively large number of USGS monitors that were to be
analyzed and because of the convenience of the 12 x 31 array
data format, daily data from other agencies was converted to
this form.  By building the disk files in a single format, only
one set of plotting and analysis programs will be discussed
following the presentation of the data formats of the other
agencies.

     Data are stored in the Daily Values File as a data array
that comprises a water year of data (October 1 through September
30).  The water-year date is designated by the calendar year in
which the 12-month period ends.  The daily values data array is
always represented as a two-dimensional array (12,31), with the
month as the first dimension and the day as the second dimension.
The data are physically stored in the array such that the first
data value  (01,01) is for January 1, the second data value  (01,
02.) is for January 2, etc., on through December 31 (12,31).

     The data within each daily values array may be chronologi-
cally ordered for output to comprise any type of year.  How-
ever, the physical order will always begin with the values  for
January and end with those for December even though two calendar
years are spanned.  The type of year stored within a daily
values record is defined by a beginning month number stored in
the record.  Unless specifically requested, the daily values
output records will be comprised of water years  (beginning
month = 10).  For example, data for the 1974 water year are
physically  stored in the data array such that the first data
value'(01,01) would be for January 1, 1974, the 180th data
value (10,01) would be the data value for October 1, 1973,  and
the data value in the array (12,31) would be for December 31,
1973.

     In terms of number of monitors the STORET data base was
second to USGS.  The monitor records were from a variety of
federal, state, and local agencies.  The STORET data were some
of the last to be processed because of the difficulty in gaining
access to the system for private organizations.  Once in, how-
ever, the system works well..

     The personnel of the STORET user assistance facility at EPA
Headquarters in Washington, D.C., created a number of useful
products for this study.  First, a. scan was done on the data
base to produce a list of all the continuous water quality  moni-
tors.  This was mentioned previously, in the site location
section.  After this listing had been evaluated and the monitors
of interest selected, all the daily and hourly data available
at each monitor were transferred to a magnetic tape.
                              30

-------
     STORET intermixes daily, hourly, and random observations.
This makes processing more difficult.  STORET, as with USGS,
provides the user with a sample reading and translation program.
The only difficulty with it was sorting out what variable went
with what variable name.  This was necessary to know so that
useless data could be discarded.  Roughly one week of effort
was required to get a working program.


     The data came in a format somewhat similar to the USGS but
not in 12 x 31 yearly arrays  (TABLE 5).   The sequence of records
(Delimiter-station-data) shown in TABLE 5 is repeated until all
stations retrieved have been exhausted.   An IBM "end-of-file"
is encountered following the last data record.  FORTRAN program-
mers must code an "END-" control transfer in the read statement
for the data records to avoid a program interrupt at end-of-file.
     The data were read from the tape, sorted, restructured, and
then written on the disk file in 12 x 31 water-year arrays.  The
initial cost of the data is unknown since it was supplied by EPA.
Processing costs were moderate, that is, $200-300.

National Climatic Center (U.S. Weather Bureau) Data

     Daily precipitation data used in the study came from the
National Climatic Center.  Daily precipitation data are avail-
able for many locations in the United States and almost all DO
monitors were located within a few miles of these stations.
However, only about 300 hourly precipitation stations are avail-
able and many water quality monitors are too far away from pre-
cipitation stations to make hourly analysis meaningful.

     The daily precipitation data are readily obtained from the
National Climatic Center, but as mentioned earlier, they are
very expensive.  The numbers are stored on the tape as computer
card images.  A standard computer card has 80 columns in which
numbers and symbols can be punched.  The same format is used on
tape and is given in a publication from the U.S. Weather Bureau
(1009 Daily Observations 486).  The card image and column-by-
column description are presented in Figure 1 and TABLE 6 , respec-
tively.  Only the first 33 columns are shown in Figure 1 since
these are the ones used in this study.

WDNR Data

     The WDNR is one of the few state agencies that collects and
stores  its  own DO data instead of reporting them to STORET.
This data source was found in the OWDC catalogs.  Daily data
from 11 stations were ordered for the years 1972-1977.  The data
were similar in format to the U.S. Weather Bureau data.  Station
identification, date, DO level, water temperature, and flow were

                              31

-------
      TABLE 5. RECORD ARRANGEMENT ON DISK FILE FOR STORET JV1ORE=4*
Group                                      Description
  1          Parameter heading records. Each record is 145 characters long. The first 25 characters of each
            record may be ignored. The remaining 120 characters are a printable alphanumeric line. These
            lines, in groups of four, would comprise the columns printed by the standard retrieval. With
            MORE=4, there will be five groups of four lines each, a total of 20 parameter heading records.

  2         Dummy data record. This is a delimiter record in Group 4 format, containing the print charac-
            ters '99' in columns 26 and 27.

  3         Station heading records. Each record is 145 characters long. The agency code is in column 1-8,
            the station code is in  column 9-23. Column 24 is blank. Column 25 contains a line number (1
            through 9, in order). The remaining 120 columns of each record are a printable alphanumeric
            line. There are nine such records in this group. These nine lines are normally printed at the top
            of each page of retrieval output. The content is affected by use of the "SHIFT" and "HEAD"
            parameters in the retrieval deck.

  4         Data records. Each record covers one  sample, either grab or composite, and its remarks codes.
            Each record is 305 characters long. Agency code is in columns 1-8, station code is in columns
            9-23, columns 24 and 25 contain '99', columns 26-31 contain the date as YYMMDD, columns
            32-35 contain the time (0000-2400, with blank time stored as 2500). The next 200 columns
            (36-235) contain the values of the water quality parameters retrieved, in IBM four-byte words.
            The FORTRAN programmer must read this field as 50 A4, into an array whose type is REAL-
            *4. Missing entries in this field, which occur either when fewer than 50 parameters are re-
            trieved or when no data were stored for a particular parameter within the sample, are key-coded
            with a binary number approximately equal to 1.E-20. The next 50 columns (236-285) contain
            the STORET alphabetic remarks codes to go with  the parameters retrieved. Column 286 will
            be blank if this represents a grab sample, and the next four columns may be ignored. If this is
            a composite sample, column  286 will  contain "S",  "T", or "B" for space, time, or both. Col-
            umn 287 will be coded "A" for average, "L" for minimum, "H" for maximum. Columns 288-
            293 contain a date in the form YYMMDO. This will be an  initial date for comprehensive com-
            posite samples, and a final date for a regular composite. Columns 294-297 are time for the same
            point  (0000-2400). Columns 298-299 are the number  of samples comprising the composite.
            Columns 300-340 are sample depth, and column 305 is coded "B" to indicate bottom sample,
            and is otherwise blank.

  5         Delimiter data record with year coded  '99' in date area (columns 26-27).

  6         Station heading records for next station, formatted as in  Group 3.

  7         Data records - See Group 4.
  *This is the broadest type of retrieval possible, allowing for as many as 50 parameters and more than one
   station.

  Source: STORET Handbook Supplementary Manual, Volume 2, "Advanced Retrieval."


                                              32

-------
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                                 Figure 1. Card format used by National Climatic Center for weather data.

-------
TABLE 6. CARD IMAGE CONTENT FOR NATIONAL CLIMATIC CENTER WEATHER DATA
Column Item or element
1-33 Missing data
35-76

1-2 State index
number
3-6 Station index
number


7-8 Year
9-10 Month
w 11-12 Day
** 13 Intrastate-
division and
time of
observation

14-16 Maximum
temperature





17-19 Minimum
temperature

Symbolic
. .. Card code
letter
B
x/

1-99

0001-
9999


00-99
01-12
01-31
0-9

X/


TXTXTX 000-199

X01-X99

X/


TnTnTn 000-099
X01-X99

Card code definition
Blank
X overpunch

State index number

Station index number
within state


Last 2 digits of year
January to December

Climate Division within
state 0= 10
X overpunch for a.m.
observations

Whole degrees F

X punch in column 14
indicates minus ( - )
X overpunch in column
16 indicates estimated
maximum temperature
Whole degrees F
X punch in column 17
indicates minus ( - )
Remarks
Columns blank if data missing or not
reported. See supplemental card content
for 1949 and prior years, page 5.
Assigned alphabetically. See list on page
6, maps pages 2 and 3.
Number assigned in proportion to its
relative position in "Index of Cities and
Towns" in Rand McNally Atlas, 65th
edition.
80-99 for 1880-1 899.


Indicates division number with p.m.
observation.
Indicates division number with a.m.
observations. X overpunch for a.m.
observations discontinued 1 July 1967.
For 24 hours ending at time of
observations.
Note: When temperature was rounded
to whole degrees (-0.4 F rounded =
0° F punched 000) (-0.5 = -1° F
punched X01).

For 24 hours ending at time of
observations.
See note columns 14-16.
                                                                       (continued)

-------
                                                           TABLE 6 (continued).
         Column
  Item or element
  Symbolic
   letter
                                                              Card code
                   Card code definition
                                          Remarks
        17-19
        (continued)

        20-22
        23-26
Temperature at
observation time
Precipitation
TTT
RRRR
OJ
        27-29
Snowfall
includes
sleet
                                            sss
X/


000-199

X01-X99

0001-
9999
OOOX
XBBB

OOXB

X/
                 001-999
                                                             XBB
X overpunch in column
19 indicates estimated
minimum temperature
Whole degrees F 0 in
column 20 = + value
X punch in column  20
indicates minus ( -)
00.01-99.99 inches to
hundredths
Trace
None, X in column 23

Amount included in
subsequent measurement
X overpunch in column 24
indicates accumulated value
                00.1-99.9 inches to
                tenths
                X in column 27 no
                snowfall
See note columns 14-16.
For 24 hours ending at time of
observation.
Less than 0.005 inches.
Blank in columns 24-26. Some
stations use 0000 for none.
Blank in column 26.
                              Note: Beginning Dec. 56 estimates of
                              daily precipitation were derived from
                              snowfall by the 10 to 1 ratio method
                              and identified by "X over 9" punch in
                              column 33. However, state climatologists
                              have been authorized to use  X/9 punches
                              in column 33 to indicate estimates of
                              daily precipitation derived by other
                              methods.
                              Amount for 24 hours ending at
                              observation time.
                              Note: Hail included  with snowfall from
                              July 1948 - December 1955. Hail
                                                                                                                            (continued)

-------
                                                     TABLE 6 (continued).
U)
CTl
Column Item or element
27-29
(continued)


30-32 Snow depth
on ground
includes
sleet and
ice
33 Estimated
precipitation
Symbolic
. Card code
letter
OXB
OOX
X/
sss 001-999
OOX
XXB
X/9
Card code definition
0 in column 27, X in
column 28 amount
included in subsequent
measurement
Trace
X overpunch in column
28 for 100.0-199.9
1-999 inches (whole
inches)
Trace
X in column 30 = none
When precipitation
amount in columns 23-26
estimated from snowfall by
Remarks
occurring alone was not included with
snowfall and snow on ground before
and after that period.
Less than .05 inch.

Depth of snow at time of observation .
See Note Columns 27-29.
Depth of less than 0.5 punched as
trace.
Blank in columns 31-32.
Columns 33 and 34 not punched for
"day with," effective 1 January 1949.
See note columns 23-26 above.
                                                                     the 10 to 1 ratio

-------
in specified locations on the tape.  The data were written in
ASCII characters, which were converted to integers and then to
floating point numbers as was the Weather Bureau data.  These
were again stored on the permanent file in 12 x 31 water-year
arrays.

     The tapes of data from WDNR were obtained at a reasonable
cost of about $60.  Processing was similar to that of the Weather
Bureau.

ORSANCO Data

     Data from ORSANCO were not used in this study primarily
because of difficulties related to the way it is stored for
computer processing and secondarily because the Ohio is a large
river and few of the urban areas along it have drainage areas
significant to that of the river itself.  This section is in-
cluded because other investigators may wish to examine ORSANCO
data.  The data format and the difficulties it causes are de-
scribed here.

     Two magnetic tapes of data were obtained from ORSANCO.  The
first tape contained the ORSANCO robot monitor data for 1961
through 1974.  The second tape covered 1975 to July 31, 1977.
This includes hourly data from 28 of the 56 sites it had oper-
ated since beginning operation.  The data were stored on tape
such that all stations reporting data on a particular day were
stored in one block.  The next block would then contain all
hourly data at all stations for the next day.  This is a con-
venient and efficient method of storing data if one wished to
see the water quality of the Ohio River basin on a day-by-day
basis.  However, it is very cumbersome to obtain data on a
particular site for a year.  A typical data block is presented
in TABLE 7.  The structure of the data tapes is described in
Exhibit 1.

     In TABLE 7, words 1 through 10 constitute the block header
and the last word of the block is its word count.  These are
always present and in some cases represent the entire block.
This happens when no stations transmitted data for a day.  There-
fore, block sizes of 11 words should be ignored.

     This example illustrates a day (block) when only two sta-
tions transmitted data.   Each station requires 240 contiguous
words (station segment),  which are subdivided into 24 groups of
10 words reflecting 24 hours of data each day.  Each word in a
group has a fixed definition only its value may change.  This
example shows the first station segment occupying words 11
through 250 with the second station segment at words 251 through
490.
                              37

-------
TABLE 7. DATA BLOCK STRUCTURE, ORSAISICO DATA

   Word                 Meaning - one word integers 1 & 2

     1          Block number (day of year)
     2          Type of block (always equals three)
     3          Year of record
     4          Month
     5          Day of month
     6          Storage date - day of year
     7          Storage date - year
     8          Number of words in this block
     9          Zero
    10          Zero
    11          Station number (first station segment)
    12          Hour
    13          Test signals
    14          Oxidation reduction  potential
    15          Temperature
    16          Conductivity
    17          pH
    18          Solar radiation intensity
    19          Dissolved oxygen
    20          Chloride
    21          Station number (same value as at word 11)
   250          Chloride
   251          Station number (second station segment)
   252          Hour
   253          Test signal
   254          Oxidation reduction  potential
   255          Temperature
   256          Conductivity
   257          pH
   258          Solar radiation intensity
   259          Dissolved oxygen
   260          Chloride
   261          Station number (same value as at word 251)
   490          Chloride
   491          Number of words in this block
                            38

-------
                    Exhibit 1. Tape file structure description,
                             ORSANCO data.
     Each block within a tape file constitutes one day of data for all stations having transmitted
     data on this day. Each file contains as many blocks as there are days in the year (either 365
     or 366).

     Blocks are variable length ranging from 11 words (no stations transmitted just block header)
     to a maximum of 6731 words (28 stations max.).

     Block size is determined as follows:

         SIZE  = Header + (Numst * Segment) + Word Count,

     where

              Header

              Numst
= first 10 words of the block and are always present,

= the number of stations that transmitted data on this day.
              Segment    = 240 contiguous words required to house a station-day (24
                          hours at 10 words per hour), and

              Word Count  = the last word of a block, containing the value of 'SIZE'. This
                          word is always present.
      ORSANCO IBM  1130 magnetic  tape routines write data by  cal-
culating  the lowest physical core address of the block to be
transmitted.  Data are written  into tape as a  single  block.   The
contents  of the lowest physical location are written  first, with
bits 0-7  becoming the first byte on the tape and bits 8-15  be-
coming the  second byte.   Succeeding 16-bit words are  transferred
in  a similar fashion.

      IBM  1130 arrays are  arranged in core storage in  descending
storage addresses.   Element 1 of a five-element array will  be at
storage address 508 and element 5 at byte 500.   This  is the re-
verse of  360 and  370 allocation and results in element 5 being
the  first element transmitted to tape.   Reading these data  to an
IBM  360 or  370 array requires that the  array be reversed in
storage.

      Thus,  unusual structure of the tape required the following
manipulation to recover data at a single station:

      •  initiate  a read,  which  picked up the number of
         words in  a tape block;
         backspace  the tape
                                  39

-------
     •  read the entire data block;

     •  search the input data buffer from the highest
        element down (remember they are stored back-
        wards)  to discover the station of interest;

     •  transfer 24 values (one day per block) to a
        storage array;

     •  translate the 24 values from ASCII to floating
        point;  and

     •  read the next block.

Backspacing is very inefficient, as are the formatted reads that
were required to recover the binary data.  The ORSANCO tape
drives are old and did not produce a "clean" copy.  Many tape
read errors were encountered.  The cost of transferring three
months of hourly data to the disk pack for a single station was
$45.  Simply figuring out how to read the tape cost over $600.
No one at ORSANCO could provide much guidance.  Apparently, the
people who work the tape software have gone on to other jobs.
The people currently on board just use it and did not fully
understand it.

     The quality of the data on the tape appeared very poor.  No
flow information was available.  For these reasons, the ORSANCO
data were abandoned.

     This completes the  discussion of the computer processing
necessary to transfer data from the various agencies to the disk
pack for use in the correlation analysis.  The following section
describes the actual correlation programs and their development.

Data Retrieval and Correlation

     The first step in the daily correlation analysis after the
required data were stored was to develop a suitable correlation
technique.  This is not as straight forward as it might seem.

     The objective of the correlation program development was to
build a program that was a sensitive indicator of the problem in
question.  That is, it should give a strong numerical indication
whenever a site was found where the DO level dropped with in-
creasing flow.   At the same time, it should not be costly to run
or difficult to implement.  These goals were never entirely
achieved, but workable methods were obtained with experimenta-
tion.

     Before undertaking program development, several test data
bases were created for Sutron's desktop calculator system.


                              40

-------
These test data  consisted of a year's daily rainfall,  tempera-
ture, and DO data  from Wilson Creek near Springfield,  Missouri.
Wilson Creek was selected as a standard because a very well
documented problem existed there.  Over 80 percent  of  the  Wilson
Creek drainage is  from Springfield, Missouri.  If a correlation
program could not  clearly identify the problem there,  it could
not be expected  to work elsewhere.

     The type of data typical of daily analysis is  illustrated
in Figure 2.  Illustrated are the flow and DO signals.  They
have been plotted  to illustrate the rather obvious  correlation
of high flow and low DO at Wilson Creek.  The problem  was  to
detect this mathematically.
       O)
       E
         10-
       X
       o
       o
       LU
       >
       -J
       O
       00
       00
                                                    r600
                      WILSON'S CREEK NEAR
                      SPRINGFIELD, MO.
                      WATER YEAR 1975
PERIODS OF LOW
DO AND HIGH
    FLOW
 Uoo
                       DISSOLVED OXYGEN
                    210        240

                           DAY OF YEAR
270
300
             Figure 2. Typical daily flow and DO records illustrating
            high degree of correlation between high flow and low DO
     The first  and  most obvious correlation method attempted was
standard statistical  cross-correlation analysis.  This  is  de-
scribed in several  textbooks such as Bendat and Piersol (8).
Initially developed in the communications industry, cross-corre-
lation is a means of  determining how two such signals  "look
alike" at different time offsets.  A cross-correlation  of  1.0
(for properly prepared signals) at zero time lag indicates per-
fect correlation or identical values at all times.  A correlation
                               41

-------
of zero would mean no relationship.  A correlation of 1.0 at an
offset of five hours would mean identical signals displaced in
time.

     Cross-correlation proved unworkable for daily data.   The DO
signal is more or less random in time with some long-term (low
frequency) components.  The flow is an intermittent highly
skewed signal.  Low correlations (0.6 or less)  were obtained at
all reasonable time lags for the Wilson Creek data.  This indi-
cated that other methods must be developed.

     The next correlation method used was based on a comparison
of the DO levels on "wet" and "dry" days.  Various definitions
of "wet" and "dry" were tried with both rainfall and flow data.
The different definitions of "wet" and "dry" are described as
follows.  When correlating the DO sag with rainfall, a dry day
was when the daily precipitation was zero and a wet day was a
day with rainfall greater than zero.  When correlating the DO
sag with flow, a dry day was when the discharge was less than a
given percentage of mean annual discharge and a wet day was when
the discharge was greater than the same percentage of mean annual
discharge.  The percentage was varied from 50 percent to 400 per-
cent by 50 percent increments in order to determine the effect
of the wet/dry cutoff.  A wet/dry cutoff equal to the mean
annual discharge was found to be a reasonable value.

     The method was implemented on one year of data at a time.
First, all the DO deficits were summed for wet days and for dry
days.  DO deficit is the difference between the actual DO level
and the saturation DO level for a given water temperature.  The
number of wet and dry days was also computed.  The average dry
DO sag was then calculated.by dividing the sum of all dry DO
sags by the number of dry days, and vice versa.  The average
annual wet DO sag was then divided by the average annual dry DO
sag.  If this ratio was greater than one, the DO sag was worse
during wet weather.  This method proved sufficiently sensitive
to indicate a problem at Wilsons Creek and was retained for use
in the analysis.  It was not considered the best method, however.

     The final, and most sensitive correlation measure was de-
veloped by  viewing the occurrence of a correlation in a proba-
bilistic sense.  The "following questions were asked:   (1) "Is it
more likely for the DO deficit to increase or decrease when the
flow changes or a rainfall event occurs?"  (2) "How does this
likelihood compare during periods of low and high flow?"  The
answers to these questions were found by developing a computer
counting scheme.  Figure 3 illustrates what may be thought of as
a four-compartment box.  The compartments are labeled A through
D.  Numbers are assigned to the four compartments by graphing
DO deficit divided by a moving average deficit versus discharge
divided by average discharge.  The averaging period was initially
not specified and various values were tried in order to find one

                              42

-------
                   "DRY"
       -».  "WET"
     o
     U.
     ill
     Q
     ui
     cc
     LU
         1.0
      u.
      LU
      Q
      CC
      CC

      O
         0.0
                    0
                             © -
               0 @.GL - ©
                           ©
                    0
    TENDENCY FOR DO DEFICIT
    TO INCREASE AS FLOW
    INCREASES
                                                      "WORSE"
                                                      'BETTER'
           0.0                   1.0

                       CURRENT DAY'S DISCHARGE/
                       MOVING AVERAGE DISCHARGE
             Figure 3. Box or compartment method used to analyze daily
                data for correlation between high flow and low DO.
most  suited to this study.
mately  chosen as the best.
The value of  seven days was ulti-
     The  reasoning behind  the  graph is as follows.   First, some
means was necessary to determine whether the DO deficit on any
given day was "better" or  "worse" than on previous  days.   The
method  selected compares the value observed "today"  with the
average of the values which occurred for the previous seven days
Thus, a value of (deficit/moving average deficit) greater than
1.0 indicates "worse" and  a value less than 1.0 indicates
"better."  Points on Figure 3  that lie in the upper  half  (com-
partments A&B)  represent days  when the water quality was worse
than it had been for the previous seven days.  Points that lie
below the line (compartments C&D)  represent days  on  which the
water quality improved.
                                43

-------
     Next, some means was required to determine if the water
quality consistently decreased on days with rainfall or increased
flow.  Identifying days with rainfall was easy.  Identifying
days with increased flow was again done by moving average.  The
average daily flow "today" was compared with the average for the
previous seven days.  A value of (flow/moving average flow)
greater than 1.0 indicates "increased" flow or "wet" and a value
less than 1.0 indicates "decreased" flow or "dry-"  Points on
Figure 3 that lie to the left of center (compartments A&C) rep-
resent days on which the flow decreased.  Points that lie to the
right of center (compartments B&D)  represent days with increases.

     The logic of Figure 3 can now be discussed.  For any year
of DO and flow or rainfall data up to 358 points  (365 - 7 used
for moving average) could be plotted on a graph.  By counting
the number of points which fell in each of the four compartments
it was possible to compare the number of days when DO levels
decreased and flow increased (or rain fell) (compartment B) with
the number of days when DO levels increased and flow increased
(compartment D).  If the contents of compartment B were signifi-
cantly greater than the contents of compartment D, then a corre-
lation was considered to be established between flow  (or rainfall)
and decreased DO.  A number of other comparisons can also be
made.  These will be discussed later.

     The implementation of the probability method was as follows.
First, a year of data was retrieved from the disk file.   Next,
the seven-day moving average was computed beginning with the
first days data.  The eighth day was then examined to see if the
flow had increased or decreased compared to the average of the
last seven days and whether the DO deficit increased or decreased
compared to the average for the last seven days.  The answer
gave a point on the graph in Figure 3.  The procedure was then
repeated with a new moving average beginning at the second day.
The number of points that fell in each quadrant of the graph
(that is, the compartments of the box) were counted as the
process was repeated.  At the same time, the strength of the DO
deficit in each quadrant (compartment) was computed and summed.
This was used to determine how strong the deficits were under
high- and low-flow conditions.   This was important because even
if a correlation between flow/rainfall and low DO existed, a
problem did not exist if the DO level did not fall significantly
below saturation.   At the end of a year's data the number of days
in each of the following categories could be obtained by count-
ing the contents  of the four compartments:

     •  wet days with worse than average deficit,
        compartment B;

     •  wet days with better than average deficit,
        compartment D;
                              44

-------
     •  dry days with worse than average deficit,
        compartment C;

     •  dry days with better than average deficit,
        compartment A;

     •  wet days with worse than average DO,
        compartment B, using DO values in moving
        average instead of DO deficit values;

     •  wet days with better than average DO,
        compartment D, using DO values in moving
        average instead of DO deficit values;

     •  dry days with worse than average DO,
        compartment C, using DO values in moving
        average instead of DO deficit values;  and

     •  dry days with better than average DO,
        compartment A, using DO values in moving
        average instead of DO deficit values.
The probability of a worse-than-average deficit during wet
weather was determined by dividing the number of days of worse-
than-average deficit during wet weather by the total number of
wet days.  Similarly, the probability of a worse-than-average
deficit during dry weather was determined by dividing the number
of days of worse-than-average deficit during dry weather by the
total number of dry days.  In these calculations, wet weather
is increased flow or day with rain and dry weather is decreased
flow or day with no rain.

     These two probabilities were compared to see if a worse-
than-average DO sag is more likely during wet (day with rain or
higher average flow)  or dry weather.  Similar probabilities were
also computed for the DO level itself.  The average deficit and
percentage of saturation DO level was computed for each of the
possible situations.   From this, the relative strength of the
sag during wet (day with rain or higher than average flow)  and
dry weather and the relative percentage saturation level of DO
could be determined.

     The probability method was tested on data from Wilsons
Creek near Springfield, Missouri.  The method was sensitive
enough to indicate the known correlation at that site.  A
greater than 70 percent probability of low DO at times of
higher than average (seven-day moving) flow and on days with
rainfall was found for several years of data.
                              45

-------
     After determining that the probability method would identify
a site with a known correlation between flow or rainfall events
and DO deficit, it was necessary to set criteria for selecting
sites for more-detailed examination.  Many sites exhibited cor-
relation between low flow and DO deficit as well as high flow
and DO deficit.  Only those sites at which low DO could clearly
be identified with high flow were desired.

     A cutoff level of 60 percent was finally selected. That is,
only sites at which the probability of a greater than seven-day
moving average DO deficit at times of greater than seven-day
moving average flow were chosen for further study.  In an inde-
pendent review of this report, Meta Systems of Cambridge,  Massa-
chusetts, verified the 60 percent cutoff level as being statis-
tically valid.  A Chi-squared test was used to demonstrate that
a probability of greater than 60 percent or less than 40 percent
is required in order for nonrandom distributions to exist be-
tween two categories at the 95 percent confidence level.  Thus,
for a given station year if a 60 percent probability of low DO
exists at times of high flow or on days with rainfall, then low
DO is significantly associated with these events.

     Consideration was also given to the absolute DO level in
selecting sites.  Even though a correlation existed between low
DO and flow or rainfall, a"problem" did not necessarily exist.
In general, sites were selected where DO levels less than 75
percent of saturation were present at times of high flow.

Results of Daily Correlation Analysis

     'Presentation of the results of the daily analysis is com-
plicated by the volume of numbers involved.  As mentioned in the
previous section on Site Selection, the potential locations to
be analyzed was 104.  Three primary factors reduced the number
to 83.  First, data could not be obtained for some sites. Second,
information in the OWDC catalog was not always accurate.  Final-
ly, the list of 104 sites included a number of ORSANCO monitors
that were not analyzed because of the difficulty with the data.
The final list includes 55 USGS monitors, 17 STORET monitors
(recall that STORET contains data from numerous state and local
agencies), and 11 WDNR monitors.  Periods of record range from
one to- five years.  TABLE 8 lists those sites contained in the
original group of 104 that were not analyzed.  The reason or
reasons for their rejection are also listed.  Appendix B con-
tains the list of all monitors considered for analysis.

     Daily rainfall correlations were completed at most of the
USGS monitor sites.  The prohibitive expense of the National
Climatic Center data discouraged the completion of the rainfall
correlation at the STORET and WDNR sites.
                              46

-------
                                             TABLE 8. ELLIG1BLE SITES NOT ANALYZED AND REASONS
     State
                                        Name of site
                                                     Data
                                                     base*
                                                                                                                     Reason(s) not included
 Georgia

 Illinois


 Louisiana
 Massachusetts

 New Jersey
 Ohio


 Oregon


 Pennsylvania



 West Virginia
Peachtree Cr. near Atlanta
Ocmulgee R. near Warner-Robins
Calumet R.STW
Chicago R. Bridge
Chicago Sanitation & Ship Canal at Lockport
Houma iMav. Canal near Oulac
Connecticut R. at Agawam
Merrimac R. above Concord R. at Lowell
Passaic R. at Little Falls
Cuyahogu R. at Superior St. Bridge
Ohio R. at West End (Cincinnati)
Ohio R.at Andersons Ferry
Willamette R. at Portland
Willamette R. at Oregon City
Willamette R. above Oregon City
Allegheny R. at Oakmont
Beaver R. at Beaver Falls
Kiskiminetas R.at Vandergrift
Monongahela R. at S. Pittsburgh
Ohio R. at Huntington
GS
GS
G01
G01
G01
GS
GS
GS
GS
GS
R02
R02
EPA
EPA
EPA
R02
R02
R02
R02
R02
Unable to locate records in archive files
Unable to locate records in archive files
Chicago Sanitation District would not provide data at reasonable cost
Chicago Sanitation District would not provide data at reasonable cost
Chicago Sanitation District would not provide data at reasonable cost
Unable to obtain rain or flow data  - marginal site
Unable to obtain flow or rainfall for correlation
Unable to obtain flow or rainfall for correlation
Unable to locate records in archive files
Unable to locate records in archive files
ORSANCO site - data processing cost too high
ORSANCO site - data processing cost too high
Data not found in STORET files
Data not found in STORET files
Data not found in STORET files
ORSANCO site - data processing cost too high
ORSANCO site - data processing cost too high
ORSANCO site - data processing cost too high
ORSANCO site - data processing cost too high
ORSANCO site - data processing cost too high
"GS = U.S. Geological Survey, G01 = Metropolitan Sanitation District of Greater Chicago, R02 = ORSANCO, and EPA = STORET.

-------
     The results of the daily correlation study for all the
sites examined are presented in Appendix C.  TABLE 9 lists those
USGS, STORET, and WDNR monitors that were considered for hourly
examination.  As mentioned previously, these are sites for which
the probability of lower than average dissolved oxygen reached
60 percent on days with higher than average flow or rainfall.

     For convenience in identifying the sites with strong cor-
relations, TABLE 9 lists the names with no accompanying data.
Listed first in TABLE  9  are those USGS sites that exhibited a
strong correlation (60 percent or greater) between higher than
average flow and low DO.  Listed second are those STORET moni-
tors that exhibited a strong correlation with flow.  The WDNR
monitors with strong flow correlation are listed next.  The
final group of stations in TABLE 9 are those USGS sites that
exhibited a strong correlation (60 percent or greater) between
days with rainfall and periods of lower than average DO.

     In TABLE 9 some stations, such as the Mad River at Dayton,
exhibited strong correlations between both flow and rainfall and
low DO.  Such stations appear tv/ice in the listing.

     TABLES 10 and 11 provide daily correlation analysis data
for the stations listed in TABLE 9.  The information in TABLES
10 and 11 is taken from Appendix C.  Data are presented only for
those years that exhibited a 60 percent probability of low DO at
times of higher than average flow  (TABLE 10)  or days with rain-
fall (TABLE 11).  These data are included here for the conveni-
ence of the reader in determining why the sites were chosen for
possible hourly analysis.  Three types of statistics are in-
cluded in each table:  the probability of a worse-than-average
DO deficit, the strength of the deficit, and the average per-
centage saturation occurring when the DO deficit is worse than
average.  The three types of statistics answer the following
six questions about a given monitor site:

     •  What is the probability at this station that a
        worse-than-average (seven-day moving)  DO deficit
        will occur on a wetter-than-average (seven-day
        moving) day?

     •  What is the probability at this station that a
        worse-than-average (seven-day moving)  DO deficit
        will occur on a dryer-than-average (seven-day
        moving) day?

     •  If the DO deficit on a particular wetter-than-
        average day is worse than average, how much
        worse is it?
                              48

-------
              TABLE 9. MONITOR SITES EXHIBITING A 60 PERCENT OR
              GREATER PROBABILITY OF LOW DO DURING HIGH FLOW
                               OR PERIODS OF RAINFALL
 Agency
Correlation
                     Monitor sites
USGS
Flow
EPA
(STORED
WDNR
USGS
Flow
Flow
Rainfall
North Nashua R. near Lancaster (Leominster), MA.
Westfield R. at Westfield, MA.
Wilsons Cr. near Springfield, MO.
Delaware R. at Trenton, I\IJ.
Manasquan R. near Squankum, NJ. (later rejected for lack
 of urban area)
Raritan R. near South Bound Brook, NJ.
Ashtabula R. at Ashtabula, OH.
Hocking R. below Athens, OH.
Little Miami R. at Miamiville (Milford), OH.
Little Miami R. near Spring Valley, OH.
Mad R. near Dayton, OH.
Maumee R. at Defiance, OH.
Portage R. at Woodville, OH.
Sandusky R. near Upper Sandusky, OH.
Scioto  R. at Chillicothe, OH.
S. Umpqua R. near Brockway, OR
Delaware R. at Bristol, PA.
Delaware R. at Chester, PA.
Trinity R. below Dallas, TX.
S. Platte R. at Denver, CO.,
 Burlington Ditch at York St., MDSDD #1
S. Platte R. at Denver, CO.,
 S. Platte R. at 60th ave., MDSDD #1
Wisconsin R. at Biron, Wl.
Wisconsin R. at Dubay Dam, Wl.
Wisconsin R. at Petenwell, Wl.
Connecticut R. at W. Springfield, MA.
Westfield R. at Westfield, MA.
Center  Cr. near Carterville, MO.
James R. near Boaz, MO.
Wilsons Cr.  near Battlefield, MO.
Wilsons Cf.  near Springfield, MO.
Delaware R. at Trenton, NJ.
Ashtabula R. at Ashtabula, OH.
Blanchard R. near Findlay, OH.
Cuyahoga R. at Independence, OH.
Cuyahoga R. at Old Portage, OH.
Grand R. at Painesville, OH.
Little Miami R. near Spring Valley, OH.
Mad R. near Dayton, OH.
Mahoning R. at OH.-PA. State Line, OH.
Sandusky R. near Upper Sandusky, OH.
Scioto  R. at Chillicothe, OH.
Lehigh  R. at Easton. PA.	
                                             49

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                         TABLE 10. MONITOR SITES WITH 60 PERCENT OR GREATER PROBABILITY
                                             OF LOW DO AT TIMES OF HIGH FLOW
Strength of DO deficit

Monitor site
by state and agency*

OHIO (USGS)
Ashtabula R. at Ashtabula
Hocking R. below Athens
Little Miami R. at Miami-
ville (Milford)
Little Miami R. near Spring
Valley
Mad R. near Dayton
tn
0 Maurnee R. at Defiance

Portage R. at Woodville

Sandusky R. near Upper
Sandusky

Water
Year
(19-)

75
76
73
74
74
75
72

73
75
73
75
73
76
Probability
than average
Wetter than
avg. days

.63
.67
.66
.67
.65
.67
.63

.66
.60
.60
.68
.60
.64
of greater
DO deficit
Dryer than
avg. days

.49
.45
.40
.37
.43
.45
.47

.41
.38
.44
.40
.46
.46
when deficit
is greater
than average
Wetter than
avg. days

1.23
1.44
1.61
1.56
1.33
1.18
1.25

1.37
7.64
1.43
1.76
1.58
1.34
Dryer than
avg. days

1.21
1.40
2.01
1.42
1.18
1.14
1.13

1.29
1.77
1.75
1.72
1.86
1.27
Average
percentage of
saturation when deficit-
is worse
Wetter than
avg. days

.64
.84
.83
.84
.73
.72
.71

.72
.77
.56
.77
.83
.71
than average
Dryer than
avg. days

.72
.86
.85
.86
.74
.76
.71

.67
.76
.62
.83
.76
.74
 Scioto R. at Chillicothe        72

MASSACHUSETTS (USGS)
 North Nashau R. near         70
  Lancaster (Leominster)

 Westfield R. at Westfield       75
                                          .64
                                          .63
                                          .62
.48
.50
.48
1.21
1.17
1.69
1.15
1.17
2.65
.41
                                                                                                           .53
                                                                                                           .78
                                                                                                                           .51
                                                                 .62
                                                                 .88
*Stations are grouped by state, states are in alphabetical order, stations are alphabetized within groups.
                                                                                                                         (continued)

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                                                           TABLE 10 (continued).
Ln
Strength of DO deficit

Monitor site
by state and agency

MISSOURI (USGS)
Wilsons Cr. near
Springfield

NEW JERSEY (USGS)
Delaware R. at Trenton

Manasquan R. at Squankum
(This station later aban-

Water
Year
(19--)

73
75
76

73
75
71
72
Probability
than average
Wetter than
avg. days

.70
.81
.77

.64
.61
.61
.66
of greater
DO deficit
Dryer than
avg. days

.42
.39
.44

.45
.40
.58
.52
when deficit
is greater
than average
Wetter than
avg. days

1.27
1.27
1.28

1.83
2.79
1.12
1.22
Dryer than
avg. days

1.20
1.16
1.14

6.66
3.73
1.13
1.11
Average
percentage of
saturation when deficit
is worse
Wetter than
avg. days

.60
.56
.58

.85
.91
.51
.50
than average
Dryer than
avg. days

.64
.69
.65

.93
.96
.55
.56
       doned for lack of urban
       area; it is near a swamp.)
      Raritan R. near South          75
       Bound Brook (below
       Callo Dam at Boundbrook)

     OREGON (USGS)
      Umpqua R.  near              76
       Brockway

     PENNSYLVANIA (USGS)
      Delaware R. at Bristol          75
      Delaware R. at Chester         73

     TEXAS (USGS)
      Trinity R. below Dallas         77
.60
.63


.71
.67

.60
.37
1.60
.55


.43
.65

.52
3.82


1.33
1.13

1.13
1.65
2.30


1.24
1.61

1.14
.71
.82


.84
.36

.28
.80
.83


.84
.42

.26
                                                                                                                             (continued)

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                                                       TABLE 10 (continued).
Monitor site
by state and agency
Water
Year
(19-)
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days
Strength of DO deficit
when deficit is greater
than average
Wetter than Dryer than
avg. days avg. days
Average percentage of
saturation when deficit
is worse than average
Wetter than Dryer than
avg. days avg. days
COLORADO (EPA)
 S. Platte R. at Denver,         71
   Burl. Ditch at York St.
   MDSDD #1
 S. Platte at Denver, S.         76
   Platte at #60 Ave,
   MDSDD #1

WISCONSIN (WDNR)
 Wisconsin  R. at Biron         74
 Wisconsin  R. at Dubay         74
 i  Dam                      76
 Wisconsin  R. at Petenwell      73
.60
.66
.64
.60
.64
.60
.44
.44
1.35
1.21
.46
.52
.50
.40
1.48
1.08
1.08
1.20
1.30
1.28
1.13
1.11
1.13
1.16
.72
.61
.60
.36
.36
.56
.72
.70
.62
.44
.44
.62

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                    TABLE 11. USGS MONITOR SITES WITH 60 PERCENT OR GREATER PROBABILITY
                                          OF LOW DO ON DAYS WITH RAINFALL
Monitor site
MASSACHUSETTS
Connecticut R. at W.
Springfield
(Thompsonvillo)
Westfiekl R. at Westfield
MISSOURI
Center Cr. near Carterville

James R. near Boa?



Wilsons Cr. near
Battlefield

Wilsons Cr. near
Springfield
NEW JERSEY
Delaware R. at Trenton
OHIO
Ash tabula R. at Ashtabula

Water
Year
(19--)

73
74
75
75

74
75
73
74
75
76
74
75
76
75
76

72

75
76
Probability of greater
than average DO deficit
Wetter than
avg. days

.60
.66
.63
.63

.64
.65
.64
.64
.65
.63
.63
.62
.63
.67
.77

.62

.63
.67
Dryer than
avg. days

.52
.47
.47
.45

.49
.50
.47
.54
.53
.52
.56
.53
.52
.38
.43

.46

.45
.42
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.67
1.32
1.26
2.13

1.14
1.14
1.14
1.13
1.14
1.11
1.08
1.12
1.06
1.26
1.24

1.79

1,24
1.22
Dryer than
avg. days

2.98
1.21
1.23
2.46

1.10
1.15
1.12
1.13
1.09
1.11
1.10
1.08
1.05
1.15
1.16

5.35

1.18
1.24
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.80
.78
.81
.81

.59
.54
.57
.49
.44
.30
.09
.14
.03
.61
.61

.86

.70
.69
Dryer than
avg. days

.76
.81
.83
.87

.62
.54
.58
.48
.45
.28
.10
.14
.04
.68
.64

.87

.68
.68
"Stations are grouped by state, states are in alphabetical order, stations are alphabetized within groups.
                                                                                                                    (continued)

-------
                                                        TABLE 11 (continued).
    Monitor site
                             Water
                             Year
                             (19--)
                Probability of greater
               than average DO deficit
                                   Strength of DO deficit
                                   when deficit is greater
                                        than average
                                                     Average percentage of
                                                    saturation when deficit
                                                     is worse than average
           Wetter than
            avg. days
              Dryer than
               avg. days
              Wetter than
               avg. days
               Dryer than
                avg. days
               Wetter than
                avg. days
              Dryer than
               avg. days
OHIO (continued)
Blanchard R. near Findlay
Cuyahoga R. at
 Independence
Cuyahoga P.. at Old
 Portage
Grand R. near
 Painesviiie
Little Miami R. near
 Spring Valley
Mad R. near Dayton
Mahoning R. at OH.-PA.
 State Line below
 Loweliville
Sandusky R. near Upper
 Sandusky

Scioto R. at Chillicothe
73
75
76
73

76

75

74
75
72
73
74
75
76
76
74
75
76
76
.65
.62
.64
.60
.66

.60

.60
.61
.66
.64
.60
.63
.65
.60
.62
.62
.69
.60
.48
.44
.49
.41
.44

.59

.43
.43
.43
.34
.45
.41
.45
.44
.45
.41
.42
.39
1.29
1.17
1.22
1.25
1.27

1.19

1.27
1.17
1.20
1.26
1.17
1.20
1.21
1.18
1.77
1.38
1.40
2.15
1.20
1.16
1.19
1.22
1.19

1.16

1.21
1.14
1.14
1.14
1.13
1.20
1.15
1.14
2.62
1.21
1.31
.65
.50
.57
.72
.67

.72

.73
.74
.72
.78
.73
.74
.68
.54
.71
.70
.71
.54
.58
.55
.59
.70
.75

.66

.74
.75
.70
.78
.72
.75
.70
,52
.70
.74
.75
.58
                                                                                                                               (continued)

-------
                                                     TABLE 11  (continued).
Strength of DO deficit

Monitor site


PENNSYLVANIA
Lehigh R, at Easton
(Glendon)

Water
Year
(19-)

72
73
Probability
than average
Wetter than
avg. days

.67
.62
of greater
DO deficit
Dryer than
avg. days

.51
.45
when deficit
is greater
than average
Wetter than
avg. days

1.35
1.50
Dryer than
avg. days

1.56
1.60
Average
percentage of
saturation when deficit
is worse
Wetter than
avg. days

.77
.83
than average
Dryer than
avg. days

.76
.82
L71
Ln

-------
     •  If the DO deficit on a particular dryer-than-
        average day is worse than average, how much
        worse is it?

     •  On wetter-than-average days when the DO deficit
        is worse than average, what percentage of satu-
        ration is present?

     •  On dryer-than-average days when the DO deficit
        is worse than average, what percentage of satur-
        ation is present?

     The first and third questions were of primary concern to
this study.  If the answer to the first was "yes" and the answer
to the third was "less than 75 percent saturation," then the
site in question was felt to be worth closer examination.

     The results of the analysis to examine the DO  deficit levels
for days on which the flow equaled various percentages of the
mean annual value are not presented here.  In general, they were
used to augment or confirm judgments made from information in
Appendix C.

     The following section describes the more-detailed analyses
that were performed at the sites that exhibited strong correla-
tions.  The detailed analysis was designed to determine which
of the sites with strong correlations also had water quality
standard violations.
                              56

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                           SECTION 7

                    DETAILED SITE ANALYSIS
GENERAL CONSIDERATIONS

     Water quality monitor sites where correlations existed be-
tween rainfall and/or flow and low DO were identified in Sec-
tion 6.  The daily data used to identify these sites did not
allow a determination of specific water quality standard viola-
tions.  Hourly data analysis was required at sites that showed
strong deficits  (DO levels less than 75 percent saturation).
For these reasons and because of other contract requirements,
it was necessary to examine those sites with correlations in
greater detail.

     The contract requirement that required the most additional
information was the Streeter-Phelps analysis.  This is a pro-
cedure used to calculate the location of the maximum DO deficit
downstream of point or distributed sources of oxygen-demanding
material.  The purposes of such analysis were to determine if a
given water quality monitor was in a position to sense the maxi-
mum deficit from urban runoff and if observed deficits appeared
reasonable based on the best estimates of input loads.  Urban
population, drainage area, streamflow, temperature, BOD loads,
and other data were required.

     In addition to selecting sites for hourly and Streeter-
Phelps analysis, it was desired to form some opinion on why a
correlation might exist between flow/rainfall and low DO at a
given site.  Information was needed on travel time from the
urban area to the monitor, distance from the rain gage to the
urban area, and other factors that might influence the DO that
a monitor "sees."

     The overall process of the detailed site analysis studies
will now be described.  Specific aspects of the analysis, such
as Streeter-Phelps, will be singled out and discussed in detail.
These detailed discussions occupy the remainder of the section.

     The first step in the detailed site analysis was the gath-
ering of available maps.  The monitor and flow gage and the
weather station, if any, were then located precisely.  An in-
formation sheet that summarized what could be learned from USGS
                              57

-------
records, the map, or other sources was next filled out.  Infor-
mation sheet data were used to select sites with the simplest
hydraulic conditions for analysis by the Streeter-Phelps tech-
nique.  Finally, the plots of daily average flow, DO, and rain-
fall values were examined and periods for hourly analysis were
selected. From 10 to 30 days or more of hourly data were
examined at each site where the hourly data could be obtained.
The total of all this information was then studied carefully to
see what could be concluded.  The results form the substance of
Section 8, which follows.

GENERALIZED INFORMATION ANALYSES

     The gathering of. information; at each site was systematized
by developing a standard form.  The two-page form, filled out
for,the- Scioto River at Chillicothe, Ohio, monitor is illustrated
in-Exhibits 2 and 3.

     It was originally intended that completed forms for each
of the sites in TABLES 9, 10, and 11 would be included as an
appendix to this report..  However, experience indicated that
much of the information was unavailable.  For this reason, each
site will be discussed individually in the appendix and as much
general information as possible tabulated there.

     In order to keep the main body of the text to a reasonable
size, the remainder of the discussion^on the completion and use
of the site .analysis forms will be structured around the Scioto
River at Chillicothe.  This will serve as an example of the
method used. 'The reader is referred to Appendix D, where the
remaining sites, as well as the Scioto, are presented.

     The first step in filling out the analysis forms was usually
to assemble USGS 7.5-minute topographic sheets to form a complete
picture of the particular urban area in question.  These ranged
in size from a single sheet to as many as nine sheets for the
Philadelphia-Trenton area.  Next, the water quality monitor, the
stream gage, and the precipitation station were located.  This
was done by plotting the reported latitude and longitude of the
facilities.  This had been done in the early phases of the study
to select monitors for inclusion in the daily analysis.  Many of
the maps used, however, were in the USGS library.  More maps
were purchased and brought to Sutron for the detailed analysis
work.

     The assembled maps were large and cumbersome.  Therefore, a
sketch of relevant features was transferred to the site form.
This aided in remembering each one later.  Any outstanding fea-
tures such as industry or sewage treatment plants were noted.
Other information gathered from the maps included the urban
drainage area, stream width, the distance from monitor to stream
gage, and distances from the monitor to sewage outfalls.  The

                               58

-------
                             Exhibit 2. Site analysis form - Streeter-Phelps.
MONITOR NAME: Scioto R.at Chillicoths, OH.
AGENCY:  US6S
MONITOR LOCATION:  Lat.: 392029  Long.: 825816
AGENCY ID NO.: 03231500
SKETCH OF SITE:
 POP. OF COLUMBUS
   566,600 11,069,400]
PHYSICAL DESCRIPTION:   43 milas south of Columbus, OH.
                                          HILLICOTHE FED.
                                          REFORMATORY
OUTSTANDING FEATURES:  Sewage disposal downstream of monitor, no obvious problems
STREAM GAGE NAME: Scioto R.at Chitlicothe, OH.
                                                                 AGENCY:  USGS
STREAM GAGE LOCATION: Lat.: 392029   Long.:  S25S16
AGENCY ID NO.:  03231500
PRECIPITATION GAGE NAME:  Chillicoths - Mound City
                                                                 NWS ID NO.: 1528
DISTANCE-MONITOR TO STREAM GAGE: 0
                                                 DISTANCE - RAIN GAGE TO MONITOR: ~2 mi
QUALITY OF RECORDS:  Looks good most of the time
DESCRIPTION OF STREAM:
        APROX. WIDTH: 250ft    AVG. DISCHG.:  ^3400 cfs
RANGE  OF DISCHG.: 500-50,000 cfs
        APROX. DEPTH AT AVG. Q.:
                                                 APROX. MEAN VEL. AT AVG. Q.:
        OTHER INFORMATION:
                                                59

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                                  Exhibit 3. Site analysis form.




MONITOR NAME: Scioto R. at Chillicothe, OH.
TOTAL DRAINAGE AREA AT MONITOR:  3850	 TOTAL URBAN DRAINAGE: 3-4 mi2
% URBAN CONTRIBUTING AT MONITOR: 50%	  % CONT. URB./TOTAL:  <1%





APROX. POPULATION OF URBAN AREA: ___^_	





RESULTS OF CORRELATION ANALYSIS:





        DAILY FLOW -   COMMENT ON PROBABILITY OF OCCURRENCE:  .64-1972	
                        COMMENT ON STRENGTH OF SAG: 1.21 wet, 1.15 dry -1972 / .41% wet, .51 dry -1972






        DAILY RAIN -   COMMENT ON PROBABILITY OF OCCURRENCE:  .6-1976	






                        COMMENT ON STRENGTH OF SAG: 2.15 wet, 1.31 dry -1976 / 54% wet, 58% dry - 1976






STREETER-PHELPS ANALYSIS PARAMETERS






        STREAM Q, cfs:	WASTE DISCHG., cfs:	STM. VEL., ft/sec.:	






        DEPTH,ft.:  	 INITIAL DEFICIT, mg/l:	
        DEFICIT INFLOW,, no./day:	 BOD INFLOW,no^day:
        DIST. BOD SOURCE, mg/l/day:	UPSTRM. BOD IN RIVER, mg/l: _





        DIST. BENTHAL DMND., g/m2/day:	 REAERATiON COEF., Ka, I/day:
        BOD DECOY COEF., Kr, I/day:	DEOXYGENATION COEF., Kd, I/day:






STREETER-PHELPS RESULTS






        COMMENT ON MONITOR LOCATION:	
        COMMENT ON STREAM MILES AFFECTED:
        CONFIDENCE IN RESULTS:
ANALYSIS OF PROBLEM AT THIS SITE:






        Chillicothe is 44 mi downstream of Columbus. This could be near the Columbus sag point - bad water quality






probably originates at Columbus.
                                              60

-------
urban area was estimated as accurately as possible from the rose-
tinted areas on the maps.  Distances were measured by map  scale
and dividers.

     After tabulating the physical features of the site, the
stream flow was examined.  The flow and DO records were gath-
ered and the range of values entered.  The plots of DO and dis-
charge were examined to determine the percentage of missing
records.  This examination was combined with the quality esti-
mates in the agency reports to rate the record.  Records were
"excellent" if only one or two weeks a year were missing.  A
"good" rating went to stations with one or two months missing.
A "poor" rating went to all others.

     While examining the flow records, typical July-August low
flow values were selected.  These were for later use in the
Streeter-Phelps analysis  (if performed).  If rating curves were
available, they were used to determine the depth and velocity,
which were also required for Streeter-Phelps.

     The results of the daily correlation analysis were entered
on the form in a summarized fashion.  This was done to give at
a glance the magnitude of the "problem" at each site.  This was
omitted in cases where there was too much information to fit.
A note was entered referring to a separate summary table.

     The population figures were obtained from a World Almanac
from the 1970 census.  No attempt was made to account for growth
increases.  The maps were often more out of date than the census.
For consistancy,  no  adjustments were made to "urban" areas
either.

     The Streeter-Phelps portion of the site forms was completed
only if the analysis was actually performed.  Development of
complex water quality models was not within the Scope of Work.
For this reason, sites with fairly simple hydraulic conditions
were selected for analysis.  Meaningful analysis using the
Streeter-Phelps method required streams with few tributaries
and not too many waste sources.  Five sites were required by the
contract. Thirteen were done because the writers felt that it
contributed a worthwhile insight into the location of monitors.
The actual Streeter-Phelps procedure is complex enough to warrant
separate discussions.  It is the subject of the following sec-
tion.

Streeter-Phelps Analysis

     The bulk of the "Streeter-Phelps" theory used in this study
was derived from Thomann's (2)  excellent book on water quality
management.  Virtually, all of Section 5 of the book is directed
toward one-dimens.ional modeling of stream quality., Streeter-
Phelps is a subset of the methods covered,


                              61

-------
LQ
     The term "Streeter-Phelps" is somewhat misleading.  The
original work of Streeter and Phelps in 1925 was directed specif-
ically at determining the DO deficit versus distance caused by a
point source of carbonaceous BOD (CBOD) , LO , and some initial DO
deficit, D0.  In the intervening years, other researchers have
added additional capabilities to the original model.  These in-
clude nitrogenous BOD (NBOD) , photosynthesis , respiration, ben-
thai oxygen demand, and distributed sources of CBOD and NBOD.

     The "Streeter-Phelps" equations used in this study were
selected primarily on the basis of data available to set the
various parameters.  In all cases, the data were very limited.
It was necessary to work from good estimates of the urban area,
the population, and the data obtained for the study, that is,
flow, temperature and DO levels.  No CBOD, NBOD, photosynthesis,
respiration, or rate constant information was available.  In the
absence of these key numbers, it was decided to be consistent
with the technique, even though accuracy was out of the question.

     The equation chosen for use is as follows:

     D =  [(wd/Q) + DQ] exp  [-Ka(X/V>]

            V(Kd - Kr)  |eXP  [-VX/V>]  - exp [-Ka(X/V)]})

           (Kd/(KaKr)  j1 - exP  [-Ka(X/V)]})Lrel

               (Ka - Kr)  HP  -VX/V)  -exp  -K& (X/V)

                                   Ka
where     D = DO deficit  (milligrams per liter) ,

       Wd/Q = weight of initial DO deficit divided by river
              discharge (Wd is expressed in pounds, Q in
              cubic feet per second, and the quotient con-
              verted to milligrams per liter) ,
        exp = exponential function,
                                             ,_ •]
         Ka = reaeration rate constant (days   ) ,

          X = distance from initial source (miles) ,
          V = mean stream velocity  (miles per day) ,

         K^ = CBOD oxidation rate coefficient  (days " ) ,

         Kr = CBOD settling plus oxidation rate coefficient
               (days -1) ,

         L0 = initial point source CBOD (milligrams per liter) ,

        Lrd = distributed CBOD source  (milligrams per liter
              per day) ,  and

         Sb = oxygen uptake of benthic deposits (milligrams
              per liter per day) .

                              62

-------
     The initial value of CBOD, LQ, is found by a mass balance
at X = 0 as

                     L0 =  (W + LUQ)/Q + Qw

where   W = weight of CBOD input  (pounds),

       Lu = upstream CBOD  (pounds), and

       Qw = waste discharge rate  (cubic ft per sec).

The quotient is converted to milligrams per liter.

     Benthal demand, S]-,, is normally reported as grams oxygen per
meter squared per day.  It is converted to milligrams per liter
per day by dividing by the hydraulic radius  of the channel.

     Photosynthesis/respiration effects were not considered.
Likewise NBOD, both point source  and distributed, were not con-
sidered .

     Before discussing the means  used to  evaluate the many co-
efficients and parameters in the  equations, it is worth discus-
sing the method in general.  There  are a  number of  reasons to be
skeptical of the outcome from the start.  First, the equation is
one-dimensional in nature.  All waste sources and other param-
eter values are assumed to be uniformly distributed across the
length and breadth of the stream.   Experience has shown this to
be a fairly reasonable assumption for the case in which lateral
mixing is rapid or in which waste sources are deliberately in-
troduced through diffusers placed across  the channel.  Second,
the equations were designed for steady state conditions.  That
is, the waste discharges, the stream flow, and all  the rate
controls are time invariant.  Assuming such condition to exist
under the influence of storm runoff is highly suspect. Dis-
charge increases of factors of ten  are common in small streams
under summer storm runoff conditions.  Peak flows seldom last
an entire day-  Often storm hydrographs last less than one day.
Finally, as mentioned earlier, virtually  no data are available
on the various rate constants.  Empirical formulas are available,
but seldom specific measurements.

     The writers would have preferred to  see the "Streeter-
Phelps" analysis replaced with a  coupled  unsteady-flow/water-
quality model.  This would have been much more realistic and is
still strongly recommended.  However, this would require a con-
centrated data collection effort  at one site.  Recommendations
on suitable places will be made later.

     Since application  of the Streeter-Phelps methodology was  a
requirement in the Scope of Work,  every effort was  made to
implement it in a consistent and  reasonable way.  Although it
was not within the Scope of Work  to develop water quality models,
the first step was to develop a flexible  Streeter-Phelps solu-
tion algorithm.  Direct solution  of the equation confined the

                              63

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answer to a single point source of CBOD as well as single iden-
tifiable point sources.  In order to handle these situations, a
model was developed capable of superimposing solutions at vari-
ous distances.  A starting position, X=0, was specified for each
point source desired, and the program kept track of each and
added them all together to form an overall DO deficit profile
for the reach in question. Take for example a situation in which
three sewage treatment plants are present in a city seven miles
long and a reach length of 70 miles was desired. The procedure
is as follows:  First, assign X = 0 to the upstream edge of the
city and solve the equation for a distributed demand over the
seven miles of city. Store this result. Next, solve the equation
for a point source of CBOD at the location of the first treat-
ment plant. Add this to the first solution with the origin off-
set appropriately to reflect the plant location. Finally, do the
same for the other two plants.
     In practice, the scheme was implemented on. a large desktop
calculator with a plotter.  The "Streeter-Phelps" equation was
solved at one-quarter-mile intervals for whatever total reach
length was specified.  A large one-dimensional matrix saved the
solutions and accumulated them for plotting.  The calculator
handled all the offset calculations automatically.  Examples of
the results will be shown after discussing parameter estimation.

     The following is a list of the parameters that had to be
estimated for the Streeter-Phelps technique:

     ®  Flow parameters:  stream distance
                          discharge
                          depth
                          flow velocity

     ®  Rate constants:   Ka, Kr, Kd

     •  Demand and loading constants:  D.L.Q.L,, S,,W.
                                        o   o   w   rd   b
     As mentioned previously, the hope for accuracy of the tech-
nique was not great.   Consistency was sought, however, so that
relative results could be compared.  Thus, each site considered
for "Streeter-Phelps" analysis was treated in exactly the same
way.

     The flow parameters were the easiest to estimate.  Even
here,  however, detail was lacking.  Stream distances were meas-
ured by picking a starting point for X = 0.  This was usually
the upstream edge of  the urban area as indicated by the rose-
colored area on the 7.5-minute quad sheets.  In some instances,
it was taken as the outfall of the farthest upstream treatment
plant.   Stationing in miles was then established by using

                              64

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dividers set at one-quarter-mile spacing proceeding down the
channel centerline.

     When very large distances  (10 miles or more) were involved,
atlases or 1:25,000 scale maps were used.  In the absence of
suitable maps, channel length was estimated using a standard
geomorphology formula (Leopold et al.  (9)).  This states that
channel length, L, is proportional to drainage area to the 1.4
power.  The USGS publishes drainage areas  at all gages and the
distance between each could be found as

                            1.4      1.4
                    AL = A,     -A,
                          dl       d2
Values obtained by this method were always checked for reason-
ableness by measuring the straight-line distance and assuring
that AL was neither shorter nor greater than a factor of five
longer.

     The magnitude of discharge to use was an important consid-
eration.  The final decision was to use two separate values for
each site.  First, a typical July-August low flow was picked by
eye from a year when a correlation existed between discharge or
rainfall and low DO.  This was done by looking at the plots of
mean daily discharge and selecting the low point.  Next, a
typical July-August storm flow was selected.  This was also
chosen of the mean daily value plots.

      The reasoning behind using two flows was based on the
Streeter-Phelps limitation of steady flow. It seemed unwarrant-
ed to merely change the loading into the low flow conditions to
simulate storm events when it was known that storm flows were
often 10 times or more greater than low flow.  By using realis-
tic low flow loadings in a low flow and realistic storm loadings
in a storm flow, it was hoped that reasonable results would be
obtained.

     After selecting the two discharges, it was necessary to
estimate the depth and flow velocity.  Readers familiar with
river mechanics can appreciate the difficulty of assigning a
single depth and velocity to reaches as long as 60 miles.  As
stated earlier, the objective was not to reinvent the water
quality model, so reach-by-reach depths were not entered.  If a
rating curve was available, the depth and  area were taken from
that.  If no rating curve was available, the widely used Manning's
equation for discharge,
                  Q = (1.486/n)  AR2/3S01/2 ,

was used to estimate depth.  Here, n = channel roughness param-
eter, taken to be 0.035 (typical of many open channels); A =
cross-sectional area, in square feet; R =  hydraulic radius
(approximately equal to depth for wide channels); and So = the

                              65

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energy slope (bed slope for steady flow in a uniform rectangular
channel).   By assuming a rectangular channel, R = depth, and
taking So = bed slope,

                  Q = (1.486/n)  WY(Y2/3)Sb1/2


                    = (1.486/n)  WY5/3Sb1/2 .

By estimating the width, W, and the slope, Sb, from maps, the
depth was easily computed.  Once the depth was known, the veloc-
ity was also easily computed.

     The rate coefficients were all computed from standard for-
mulas or typical values reported in the literature.  The reaera-
tion rate coefficient, Ka, was extensively studied by Rathbun
and Bennett of the USGS (10).  They recommend the formula

                  K  = 2.59  (V0
                   cl

where Y is mean stream depth.  This was based on a very large
data base in a variety of rivers collected by many other re-
searchers .

     The CBOD oxidation and settling rate constants, Kr and Kd,
are normally determined in the laboratory from stream samples.
In the absence of such samples, rate constants typical of streams
in urban areas were used.  Thomann (2)  gives a table of values
of typical rate constant, Kr  (values at 20°C):

     Kr = 1.0+3.0 in shallow streams, high oxidation,
                  rapid settling
        = 0.6+0.8 some settling

        = 0.1+0.6 "normal"
     Kd * 0.5 Kr "normal."

For this study, both K^ and Kr were considered to be 0.3.  This
was approximately the middle of the "normal" range.  Rate con-
stants were adjusted for temperature by the formula:

                K(T) =K  (20°C) (1.024(T~20)) .

     It was particularly difficult to make good estimates of the
CBOD loads and the upstream DO levels.  Again, the goal was
one of consistency rather than accuracy. The first loading con-
sidered was usually the initial point source of CBOD.  Two cal-
culations were performed.  The first was for "normal" sewage
flow.  The second was for "storm" flow.  If more than one treat-
ment plant was involved, more calculations were made and the
multiple solution capability used.
                              66

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     The "normal" sewage flow was readily computed from the pop-
ulation of the urban area.  The population figures were obtained
from a World Almanac, if possible.  If not possible, a population
density of 7000 per square mile was assumed.  This figure was
obtained by averaging 25 cities ranging in population from
50,000 to 5,000,000.  Raw-sewage flow is characteristically
taken to be 125 gallons per capita per day.  This gave Qw.  The
raw weight per day, W, of the CBOD load was computed by multi-
plying the population by 0.5 pounds per capita per day (typical
according to Thomann  (2)).  This was multiplied by 0.15 to give
an estimate of the treated load (i.e., we assumed 85 percent
treatment efficiency).  The "Streeter-Phelps" calculator program
used the information to compute Lo.

     The "storm" loadings were a somewhat more difficult matter.
Two steps were necessary.  First, an assumption was required
regarding the quantity of rainfall and the percentage of runoff.
Second, the CBOD load associated with this runoff was required.

     Thomann  (2) again provided an answer.  A study of combined
sewer overflows in North Philadelphia, Pennsylvania, produced a
graph of CBOD load in pounds per day per acre versus storm
duration in hours at various intensities.  Arbitrarily a rain-
fall rate of 0.15 inch per hour and a storm duration of 10 hours
was selected.  This gave 1.5 inches total rainfall, which seemed
somewhat reasonable.  The graph indicated a 10 pounds per acre
per day load for these conditions.  Twenty percent of the water
that fell was assumed to run off.  This again was based on the
Philadelphia study as reported by Thomann.  The procedure then
was:   (a)  multiply the urban area by 10 pounds per acre per day
to get W,  (b) multiply the urban area by 1.5 inches and convert
to cubic feet,  (c)  divide the cubic feet by 10 hours and convert
to cubic feet per second, (d)  multiply cubic feet per second by
the 20 percent runoff factor to get Qw.  If the urban area had a
single treatment plant, this "storm" load was entered as a point
source there.  If more than one plant was present, the load was
entered at the midpoint of the urban area.  Typical "storm"
loadings computed by this method roughly equaled the estimated
raw sewage yield.  This seemed reasonable as the Durham, North
Carolina,  studies  (1,3) and a study of San Francisco CSO's in-
dicate that such discharges are roughly equal to raw sewage in
quality.

     Three parameters remain.   These are Do, Lrcj, and Sb.  The
value  of D0, the initial deficit, was assumed to be zero.  That
is, the stream was assumed saturated at X = 0.  This was done
simply for lack of a way to make an intelligent guess.  Similar-
ly, the distributed CBOD source was set to zero.  The solution
was extremely sensitive to this value and again no good way was
available to estimate it.  The distributed benthal demand, Sj-,,
was taken as 1.5 grams per meter squared per day.  According to
Thomann, this is typical of aged municipal sewage.  The S^ term

                               67

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was needed  only when a concentration of industry or treatment
plants were present.

     TABLE  12 identifies  the 13 sites where  the Streeter-Phelps
analysis  was applied.  As mentioned previously, these are sites
on rivers with few tributaries and fairly well-defined waste
loads.  These were felt to  be sites where analysis would be most
meaningful.  The results  for the Scioto River at Chillicothe,
Ohio, are illustrated in  Figure 4.  Figure  4 is fairly typical
                TABLE 12. STREETER-PHELPS ANALYSIS SITES
                No.                     Monitor name

                1           Lehigh R. at Easton, PA.
                2           Scioto R. at Chillicothe, OH.
                3           Sandusky R. near Upper Sandusky, OH.
                4           Portage R. at Railroad Bridge at Woodville, OH.
                5           Maumee R. at Defiance, OH.
                6           Mahoning R. at OH.-PA. State Line below
                             Lowellville, OH.
                7           Mad R. near Dayton, OH.
                8           Hocking R. below Athens, OH.
                9           Cuyahoga R. at Old Portage, OH.
                10           Cuyahoga R. at Independence, OH.
                11           Blanchard R. near Findlay, OH.
                12           Raritan R. near South Bound Brook, NJ.
                13           Connecticut R. at West Springfield, MA.
of  all the Streeter-Phelps analysis  results.  Plotted  on the
graph are DO deficit  versus distance below Columbus, Ohio.
Columbus is the only  significant urban area upstream of  Chilli-
cothe.  Two DO deficit curves are illustrated.  The  lower curve
represents the theoretical DO deficit for August low-flow con-
ditions.  The upper curve represents the theoretical deficit for
an  August "storm flow  with urban runoff contributing oxygen-de-
manding material  at Columbus.  The  location of the  Chillicothe
monitors is shown at  80  miles downstream of Columbus.  The DO
sag point, or maximum deficit would  theoretically occur  26 miles
below Columbus.   The  monitor is, thus, poorly located.  Water
quality violations could occur near  the sag point and  not be
observed at Chillicothe.  The analysis indicates that  a  deficit
of  slightly over  4 mg/1  could be observed at Chillicothe during
storm flow conditions at Columbus.   A deficit of 7  mg/1  could
theoretically be  observed at the sag point.  Also illustrated in
the figure are the saturation DO levels for 20°C and  27°C.  The


                                68

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  15.0
      1
      I
  10.0 --
           SATURATION AT 20 C = 9.07 mg/J
                                                      SCIOTO R. AT CHILLICOTHE, OH.
O)
E

N
O
U,
UJ
Q
O
Q
SATURATION AT 27°C = 8.07 mg/l
   5.0 --
                                       STORM FLOW
•COLUMBUS
                                                                              t
                                                                           90

                                                                     CHILLICOTHE
                                                                      MONITOR
                                                                                               100
                                          DISTANCE, mi
             Figure 4. Streeter-Phelps analysis results for Scioto River at Chillicothe, OH.

-------
difference between these lines and the deficit curves is the
absolute DO  level.   In the worst case (27°C),  absolute DO  levels
at Chillicothe could theoretically fall below  4.0 mg/1 (8.07  -
4.1)  under storm conditions.   At the  sag point, DO  levels  of  1.0
mg/1  (8.07 -  7.0) could theoretically be observed.   These  obser-
vations are  typical  of the information available from the
Streeter-Phelps analysis.  Discussion of the Streeter-Phelps
analysis for  all 13  sites is  included in Appendix D.   Reference
will  be made  to the  results in Section 8.

Hourly Data  Analysis
      The last and most important of the detailed site analysis
techniques was the hourly data analysis.  This was  ultimately
completed at 22 of the 30 USGS sites  that indicated a strong
correlation  between  flow and/or rainfall and periods  of low DO.
These sites  are listed in TABLE 13.   No decision process was  in-
volved in reducing the number of sites for hourly analysis from
30 to 22.  Those sites that are included had hourly data avail-
able.  The eight missing sites did not.
                 TABLE 13. SITES AT WHICH HOURLY DATA
                           WERE PROCESSED
               No.                    Monitor name
                1            Connecticut R. at West Springfield, MA.
                2            North Nashua R. near Lancaster, MA.
                3            Wilsons Cr. near Springfield, MO.
                4            Ashtabula R. at Astabula, OH.
                5            Blanchard R. near Findlay, OH.
                6            Cuyahoga R. at Independence, OH.
                7            Cuyahoga R. at Old Portage, OH.
                8            Grand R. at Painesville, OH.
                9            Hocking R. below Athens, OH.
               10            Little Miami R. at Miamiville, OH.
               11            Little Miami R. near Spring Valley, OH.
               12            Mad R. near Dayton, OH.
               13            Portage R. at Railroad Bridge at Woodville, OH.
               14            Sandusky R. near Upper Sandusky, OH.
               15            Scioto R. at Chillicothe, OH.
               16            South Umpqua R. near Roseburg, OR.
               17            Delaware R. at Bristol, PA.
               18            Delaware R. at Chester, PA.
               19            Lehigh R. at Easton, PA.
               20            Schuylkill R. at Philadelphia, PA.
               21            Trinity R. below Dallas, TX.
               22            Trinity R. near Rosser, TX.
                                  70

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     Looking at every piece of hourly data available was out of
the question.  Five years of hourly data for flow, DO, and tem-
perature plus the computation of an hourly DO deficit would be
5.25 million numbers.  This would not be infeasible if the
numbers were available in digital form.  Unfortunately, they are
not.  All hourly data had to be transcribed by hand from computer
listings provided by USGS.   Further discussion of this follows
later.

     Instead of examining all available hourly data for each
site, a "windowing" technique was used with daily data.  For a
given station the plots of mean daily discharge, DO and DO defi-
cit were located for years with a 60 percent or greater proba-
bility of a low DO event coinciding with a flow or rainfall
event.  These were searched to find typical periods ("windows")
when such events occurred.   Hourly data were then processed for
these periods and plotted.

Advantages of USGS Data—
     Some explanation of why only USGS sites were used in the
hourly analysis and how hourly data are obtained is in order.
Several federal and state agencies gather and file hourly data.
Most notable of these are USGS, ORSANCO, EPA (through the STORET
system), the Metropolitan Sanitation District of Greater Chicago,
and WDNR.

     Recall from earlier discussions that ORSANCO stores hourly
values at some 20 places along and tributary to the Ohio
River.  There are two major drawbacks to its data.  First, no
flow data are collected.  The COE collects those. Second, the
data are given to outside users in a very awkward format for a
project such as this.  Each file on an ORSANCO digital tape con-
tains data from all the stations reporting on a given hour.
Thus, it is necessary to execute 8760 tape reads to recover a
single year of data at one station.  The computational expense
is prohibitive. (This is not an indictment of the method used
but simply a warning to other potential users.)

     EPA's STORET data base contains several types of data mixed
together.  There is a good deal of usable daily average data,
as mentioned in the section on site screening.   The writers were
unable to locate hourly data in significant amounts at any sites
of interest.  The Chattahoochee River near Atlanta, Georgia,
monitor is typical.  Well over five years of daily data were
included in the STORET records.  Scattered through this were
random days when one or two diurnal oxygen cycles had been
sampled on an hourly basis.  There were not enough data to con-
tribute to this study.

     The Metropolitan Sanitation District of Greater Chicago
keeps track of hourly data on a number of sites.  However, it is
not sufficiently staffed to copy these data onto a digital tape

                              71

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for outside users.   It will, however, allow access to its data
for hands-on copying of numbers.   This represents a sizable man-
power cost for useful amounts of  data.

     The WDNR stores both hourly  and daily data on 14 stream
sites.  It was highly cooperative at providing a tape of the
daily average values.  No attempt was made to obtain the hourly
data because only three of the 11 showed any degree of correla-
tion between rainfall/flow and low DO.  Neither of the correla-
tions was exceptionally strong.   There is no reason to believe
that hourly data could not be readily obtained from WDNR.

Hourly Rainfall Data--
     For reasons of economy the hourly rainfall data for the
detailed analysis was obtained from a National Climatic Center
publication called "Local Climatologic Data."  This is a monthly
publication that summarizes various data at primary weather
stations throughout the country.   Each state contains three to
five such stations.  Each monthly summary contains the hourly
rainfall.  These data were obtained free from NOAA at no charge.
The cost of obtaining hourly data on one year from the National
Climatic Center in Asheville, North Carolina, on digital tape is
$50.

     The rainfall data were entered by hand into files on digi-
tal magnetic-tape cartridges. The program for creating the
files and plotting the data will  be discussed in the next sec-
tion on USGS hourly data.

Obtaining and Processing USGS Data—
     Most USGS data are recorded  at monitor or stream gage sites
on digital punched tape.   In rare instances, the stream gages
still record stage on strip chart recorders.  The digital tape
punches used by USGS are capable  of punching at intervals from
five minutes to one hour.  The tapes are collected once a month
or more.  The monitors are serviced and brought to working order
if necessary when the tapes are changed.  Any clock descrepan-
cies or monitor malfunctions are  noted on the tape.

     The next step in recovering  data from the digital punched
paper tape is to copy it to magnetic tape.  This is done by
reading the paper tape via phone  connection to the USGS central
computer system in Reston, Virginia.  There, the digital magnetic
tape is created.  Some state offices have facilities for making
their own magnetic tapes.

     The next step in the data recovery process is to examine
and edit the numbers on the magnetic tape.  It is at this stage
that hourly data become  available.  Standard processor programs
are run to produce hourly or bihourly listings of the data on
the digital magnetic tape.  These listings are called primary
computation sheets or "primaries" by the USGS.  They are the

                              72

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only record of hourly or bihourly data available.  The digital
tapes from which the primaries are made are reused, thus destroy-
ing the only digital form of the data.  Each primary sheet is
carefully examined by a hydrologist and periods of erroneous,
missing, or shifted data are identified.  A second series of
programs is then run to create a file of corrected data.  The
corrected files are then daily averaged and the results stored
in the USGS's backfile library of daily values.  The daily
values are published each year on a state-by-state basis.

     Obtaining hourly data from USGS thus is a matter of obtain-
ing copies of the primary computation sheets.  No software is
maintained by USGS to provide the information in magnetic-tape
form.  Again, this is because the digital tapes on which the
information from the paper tapes is copied are not saved.  In
general, it is not too difficult to obtain copies of the sheets.
A district office is maintained in almost every state.   The
district chief will usually direct an interested user to the
correct person to talk to.  Occasionally reluctance is shown
because the data are in raw form and must be interpreted with
caution.

     For this study, the primary sheets were obtained for 22 of
the 30 USGS sites that showed positive correlation with rain or
flow.  For various reasons hourly data could not be obtained at
the remaining eight sites.  In most cases, the problem was in-
ability to obtain the primary sheets.  A number of older sta-
tions still record data on strip charts.  These are not converted
to digital form.   In a very small number of instances the
District Chief of a particular state would not release the pri-
maries because of  alleged deficiencies in the data.  Emphasis
was placed on obtaining periods of hourly data during June,
July, August, and September.  In addition to the primary sheets,
appropriate rating curves were obtained for use in converting
the stage data to discharge.  Primary sheets report hourly stage
instead of hourly flow.

     Recovering useful data from the primary sheets requires a
great deal of hand work.   This was minimized for this study by
developing a flexible plotting and analysis sequence for a desk-
top calculator.  First, a program was developed which created
digital magnetic-tape cartridge files.  Each day of data of a
particular kind (stage, DO, rainfall, or temperature)  was
entered as a separate tape file.  Files were created only for
periods when all four types of data were available simultan-
eously.  Next, a processor and plotting program was developed.
This program reads the files of data, applies the rating curve
to the stage data to obtain flow, calculates the saturation DO
level, and plots the results, including rainfall.  The program
contains shift table capability so that the stage datum can be
corrected just as is done by USGS.  The program allows periods
from a single day up to one month to be studied.

                              73

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       A one-month period of  hourly data for the  Scioto River at
 Chillicothe, Ohio, is illustrated in Figure 5. A portion of the
 plot of 1972 daily data which contains the month is  illustrated
 in  Figure 6. These two plots are fairly typical  of  the hourly
 analysis procedure. The correspondence between descreasing DO
     O)
     E
     O
     Q
       20
       10
SCIOTO R. AT CHILLICOTHE, OH.
8/1772 TO 8/30/72
SATURATION DO LEVEL
DO LEVEL—
       3.0 T
I
0
t/5
Q
d
> 0
< 3^
-- H-

tt E
< ^
X
0 O
W Q
O


2.5 :


2.0 •


1.5 \


1.0 ;



0.5 ;
0.0 3


DIS
U I O

: r— DO
: PRE






^y\f\
LOffi
              DISCHARGE / AVG. DISCHARGE

              DO DEFICIT/10, mg/l
              PRECIPITATION, inches
                         8   10   12  14  16   18  20  22  24

                           TIME FROM START OF PERIOD, days
                                           26   28  30
        Figure 5. One month of hourly data for the Scioto River at Chillicothe, OH.


and increased  flow is fairly evident  in  Figure 6. The upper  line
in the  figure  is  the observed daily minimum DO level, the  lower
line is the mean  daily discharge. A decrease in the DO level
can be  seen in almost all instances when the flow increases.
The period from day 215 to day 245 was selected as typical.
Figure  5 provides  a highly detailed hourly look at this  same
time period. The  upper graph in Figure 5 illustrates the behavior
of the  absolute DO level. Daily fluctuations of approximately
4.0 mg/l were  common before the rainfall and subsequent  runoff
event. The upper  line in  the DO graph is the saturation  level
based on the hourly water temperature. Note periods of super-
                                74

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          60 -,
          40 -
                       SCIOTO RIVER AT CHILLICOTHE, OH.
                                   I PERIOD OF HOURLY
                                       ANALYSIS
                                                 DO
- 15
                                                       - 10
    en

    o"
    Q
                                                       „ 5
             180
                                                      300
                        I	

                            TIME, day of year, 1972
                    Figure 6. Hourly data for one-month period,
                        Scioto River at Chillicothe, OH.

 saturation  occurring on days 3 and  11. Also note  that the DO
 level  falls below 2.0 mg/1 and remains there  for  three days
 beginning at day 18. This precisely coincides with  the peak of
 the  flow hydrograph in the lower graph. The lower graph in Figure
 5 illustrates the behavior of the flow, rainfall, and DO deficit.
 The  flow has been plotted as discharge divided  by averge dis-
 cahrge  for  the period. This was simply a  convenience  to avoid
 rescaling every graph. The shape of the hydrograph  is preserved
 and  no  useful information is lost. The DO deficit level is the
 difference  between the upper and lower lines  in the upper graph
 of Figure 5.  This was included in the lower graph to  aid in see-
 ing  the coincidence between a change in the behavior  of the DO
 level and the change in flow. Rainfall amounts  are  plotted as
 histograms.  The period of greater than average  DO deficit that
 occurs  during the time of higher-than-average flow  can clearly
 be seen extending from day 18 to day 30. There  is a clear cor-
 respondence between the rainfall events and the increases in
 flow.
      Further  discussion of the hourly data plots  is  included in
Section 8. Additionally daily and hourly plots  are included in
Appendix D.
                                75

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                           SECTION 8

          ASSESSMENT OF EXTENT AND CAUSES OF PROBLEM


GENERAL CONSIDERATIONS

     This section of the report presents an analysis of the
findings.  A very large number of data have been examined in
various ways.  The purpose of this final section is to determine
what has been learned.

     This section is divided into five subsections.  Each sub-
section is designed to answer a question or several related
questions concerning the correlation between DO deficit and
urban runoff.  These questions are as follows:

     •  Is there a correlation between the presence of
        urban runoff and DO deficits?  If so, what is
        the nature of the correlation and are water
        quality standards violated when the correlation
        is present?

     •  Is the problem national in scope?

     •  What are the causes of the problem?

     •  Where is the problem worth studying further?

     •  What should be studied and how?

THE EXISTENCE OF A CORRELATION, ITS NATURE AND SEVERITY

Daily Correlation Analysis

     The answer to the first part of the first question (Is
there a correlation between periods of higher-than-average DO
deficit and storm runoff?) is an unqualified "yes."  Some general
statistics and results will now be presented to support this
conclusion.

     Attempts were made to run daily correlation analysis using
either flow or rainfall or both on 104 stations.  These included
USGS, STORET, and WDNR data.  Of these, 83 had sufficient data
or data that could be economically analyzed to produce results.


                              76

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These included 55 USGS monitors, 17 STORET monitors, and 11 WDNR
monitors.

     Of the USGS monitors, 19 exhibited a 60 percent or greater
probability of low DO at times of high flow.  Eighteen exhibited
a 60 percent or greater probability of low DO on days with rain-
fall.  Eight of the stations correlated with both flow and rain-
fall.  The total number of stations exhibiting either type cor-
relation was 30.  Of the 17 STORET monitors, three exhibited a
60 percent or greater probability of low DO at times of high
flow.  Of the 11 WDNR monitors, three exhibited the 60 percent
or greater probability-

     Out of 104 candidates for daily analysis, 35 (19 USGS flow
+18 USGS rain -8 USGS overlap +3 STORET +3 WDNR)  gave positive
results in the correlation analysis.  Twenty-one of the monitors
could not be correlated because of problems in obtaining or using
data.  Thus, 42 percent of the monitors successfully examined,
34 percent of the likely candidates, gave positive correlation
results.  For discussion purposes, it will be assumed that four
monitors in 10 placed near an urban area might indicate low DO
at times of storm runoff.  That is, a correspondence between
lower-than-average DO and higher than average flow or rainfall
can be identified.  This does not mean that water quality stan-
dards are always violated.

     An interesting question can be raised concerning the pres-
ence of a correlation at a given station:  What is the implica-
tion of finding a correlation in only one or two of the years
examined?  Only general comments can be offered in answer.  One
problem comes from the statistical problem of defining a corre-
lation in the first place.  Recall that this was defined as a
60 percent probability of DO lower than the seven-day average on
a day with flow or rainfall higher than the seven-day average. One
can easily question the 60 percent cutoff level even though this
has statistical significance.  For instance, the Little Miami
River near Spring Valley, Ohio, monitor showed strong correlation
(65 and 67 percent) with flow in two of the five years examined.
Two additional years had 58 and 59 percent probabilities. Should
these years be counted as "correlated"?  Examination of the daily
DO and flow plots indicate that there are certainly times when
the DO decreases on days with increased flow.  A second problem
in determining the presence or absence of a correlation comes
from physical reality.  Since the cause of the DO depressions is
not known, it is not possible to say why a correlation is present
one year and not the next.  If the cause was sewage treatment
plant overflow, perhaps a new plant was added.  If the cause
depends on time between storms for pollutant accumulation, then
perhaps one year was wetter than the next.   The answer to these
questions will have to come from further research.
                               77

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Nature of the Correlation

     The second part of the first question concerned the nature
of the correlation.  When hourly data from sites with strong
correlations were examined, similar DO records were found at
sites with widely different physical settings.  Data from the
Scioto River at Chillicothe, Ohio, were presented earlier.  Data
from the Little Miami River near Spring Valley, Ohio, are repro-
duced from Appendix A in Figure 7.

     The three-day period prior to the storm event  (Figure 7) is
characterized by fairly large diurnal cycles in the DO level,
4 to 5 mg/1 is not unusual.  Periods of supersaturation are often
indicated.  These are clearly visible at the Little Miami sta-
tion.  There is some question, of course, whether these periods
are real or a monitor malfunction.  Conversations with the USGS
office in Columbus, Ohio, indicate that periods of supersatura-
tion, due to algal growth, are common.  The precipitation re-
sponsible for the rise in flow is visible just prior to the
hydrograph along the bottom axis.  Approximately six hours elapsed
from the time of the rainfall to the beginning of the flow change.
Approximately two inches of rainfall fell at Dayton for the
several small events shown.  As the flow increases, the diurnal
cycles in the DO record disappear.  This may be due to increased
turbidity and depth cutting off the sunlight to the aquatic
plant life at times of high flow.  At the time of peak flow a
deficit level 40 percent higher than the maximum achieved during
a nonhigh-flow diurnal cycle is reached.  This percentage in-
crease at other sites with correlations varied from zero to 50
percent.  In the case of the Little Miami, the peak deficit
during diurnal cycles was 2.5 to 2.6 mg/1.  At peak flow, the
deficit reached 3.5 mg/1 and the absolute DO level reached 5 mg/1.

     The correlation between the DO deficit and the flow is very
obvious in the lower graph.  Beginning at the seventh day, seven
small events follow in which the deficit curve mimics the flow
hydrograph almost exactly.  There is roughly a six-hour lag be-
tween the time the flow begins to increase and the time the
deficit begins to increase.

     The effect of the storm flow on the DO level is quite long
lasting.  Note, that on the Little Miami the DO has not returned
to the diurnal cyclic behavior in 17 days.  The DO depression
caused by the large flow hydrograph that began on day 3 would
probably have only lasted four to six days if it had not been
followed by the smaller events on days 7, 10, and 13.  This be-
havior is typical of all the sites with pronounced correlation.
Sites at which a single hydrograph peak was examined usually re-
covered in three to five days.

     This long-term effect gives added validity to the daily
analysis procedure.  If the DO depressions only lasted a few


                              78

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o>
£
   20
   "
                                     R.
                             7/1/75 TO 7/20/75
SATURATION DO LEVEL
DO LEVEL
                       VALLEY, OH.
    3.0 T
    2.5
                           •"-DISCHARGE / AVT. DISCHARGE
                             DO DEFICIT / 10, mg/l —
                            -PRECIPITATION, inches
                                           10      12     14
                             TfME FROM START OF PERIOD, days
                                    16
18
20
    Figure 7. DO/fiow correlation on the Little Miami River near Spring Va!!ey, OH.

-------
hours after storm events, it would not be possible to detect
them using daily average data.

Severity of Problem

     The final part of the first question concerned the severity
of the DO deficits associated with urban runoff.  The fact that
the DO decreases at times of storm runoff is scientifically of
interest.  However, if the level does not consistently decrease
below prescribed standards, no "problem" exists.

     Water quality standards were mentioned in the introduction.
There is no uniform standard for the entire country.  Generally,
for a warm-water system containing fish, other aquatic life, and
wildlife, a level of 5 mg/1 is recommended  (Thomann (2)).  The
ORSANCO recommends that DO levels not drop below 5 mg/1 for more
than eight hours a day or below 3.0 mg/1 at any time.   The EPA
standards recommend that DO not drop below 2.0 mg/1 for more
than four hours or below 3.0 mg/1 for three days.  The hourly
DO data in Appendix D were examined carefully and compared to
these standards.

     The first standard used to examine the hourly data was sim-
ply 5.0 mg/1.  This standard appears so frequently in the liter-
ature that the writers felt it was worthwhile to identify those
sites that would not meet it.  While 5.0 mg/1 is not a severe
water quality problem, it is certainly poor water quality.
Eleven monitor sites on nine rivers had hourly DO levels that
fell to 5.0 mg/1 or below.  These 11 monitor sites are identi-
fied in TABLE 14.  Also listed in the table are the minimum
observed DO level and the time (hours)  that the DO remained be-
low 5.0 mg/1 because of the change in flow.

     The next standard used to examine the hourly data was the
EPA recommended standard.  Six monitor sites on five rivers had
hourly DO levels that violated the EPA standard.  These six
sites are listed in TABLE 15.  Also listed in the table are the
minimum observed DO level, the approximate DO level before the
runoff event, and the time the DO remained below 2.0 mg/1.

     The final examination of the data with respect to standards
was to determine how many additional monitor sites would show
EPA standard violations if the monitor were more appropriately
located.  Minimum observed values were reduced by the  difference
between the Streeter-Phelps predicted minimum value and the
Streeter-Phelps predicted value at the monitor site.  Four addi-
tional monitor sites would probably show EPA standard  violations
if properly located.  These are listed in TABLE 16.   Also listed
for each site are the minimum observed DO level, the Streeter-
Phelps correction, and the predicted minimum for a properly
located monitor.  Hourly data were not available at two of the
four sites listed.  The observed values were taken from plots of

                              80

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              TABLE 14. MONITOR SITES AT WHICH DO LEVELS
                    BELOW 5.0 mg/l WERE OBSERVED


No.


1
2
3
4
5
6
7
8
g
10
11


Monitor name


N. Nashua R. near Lancaster, MA.
Wilsons Cr. near Springfield, MO.
Cuyahoga R. at Independence, OH.
Cuyahoga R. at Old Portage, OH.
Little Miami R. at Spring Valley, OH.
Mad R. near Dayton, OH.
Sandusky R. near Upper Sandusky, OH.
Scioto R. at Chillicothe, OH.
Schuylkill R. at Philadelphia, PA.
Trinity R. below Dallas, TX.
Trinity R. near Rosser, TX.
Minimum
observed
DO level.

mg/l
1.8
0.0
4.9
1.9
5.0
4.9
1.5
0.9
3.0
0.9
0.0

Length of time
below 5.0 mg/l.
hours

8
84
3
4
1 or less
1 or less
240+
168
72
All the time
All the time
          TABLE 15. MONITOR SITES AT WHICH EPA DO STANDARDS
                WERE NOT MET DURING RUNOFF EVENTS


No.

1
2
3
4
5

6



Monitor name

IM. Nashua R. near Lancaster, MA.
Wilsons Cr. near Springfield, MO.
Sandusky R. near Upper Sandusky, OH.
Scioto R. at Chillicothe, OH.
Trinity R. below Dallas, TX.

Trinity R. below Rosser, TX.

Minimum DO

level
mg/l

1.8
0.0
1.5
0.9
0.0

0.0

DO level
before
runoff.
mg/l
5-6
6-10
5-9
4-10
2-3

1-2

Time DO

remained below
2.0 mg/l, hours

4
9
18
16
Much of the time
(6-8 hr/event)
Much of the time
(6-8 hr/event)
the daily minimum for years with positive correlation.  One
additional monitor site, the Little Miami River near Spring
Valley, Ohio, monitor, would probably be included with  those  in
TABLE 16 if the Streeter-Phelps analysis had been used  there.
The monitor is near the outskirts of Dayton.  Experience with
other sites indicates that if the monitor had been  30 to 40
miles further downstream, it might have sensed a greater deficit,
Absolute DO levels of 5.0 mg/l were observed at the monitor's
present location.
                               81

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       TABLE 16. MONITOR SITES WITH POTENTIAL FOR EPA STANDARD
                  VIOLATIONS IF PROPERLY LOCATED
No. Monitor name
1 Cuyahoga R. at Independence,
OH.
2 Cuyahoga R. at Old Portage,
OH.
3 Mahoning R. at OH.-PA.
State Line below
Lowellville, OH.
4 Maumee R. at Defiance, OH.

Problem with
location
Too close to
urban area
Too close to
urban area
Too close to
urban area

Too far from
urban area
Minimum
observed DO
level, mg/l
4.9

1.9

0-1.5
(daily)

2.5-4.0
(daily)
Streeter/Phelps
correction,
mg/l
4.9

1.9

1.5


4.0

Possible
minimum DO
level, rng/l
0.0

0.0

0.0


0.0

     Several other general observations were made from the hourly
data concerning the severity of the problem.  Three of the USGS
sites examined were unusual.  All showed strong correlation be-
tween flow and low DO but none were truly urban in character.
Center Creek near Carterville, Missouri, for instance, is near
a relatively small town in an isolated area.  There is a good
deal of strip mining near the monitor.  The site on the Manasquan
River near Squankum, New Jersey, was near a large federal muni-
tions reservation and a few suburbs, but nothing truly urban.
Much of the drainage appeared swampy.  The site on the Little
Miami River at Miamiville, Ohio, is in the far outskirts of
Cincinnati and has no direct drainage from the city.  Five of
the sites examined on an hourly basis did not have water quality
problems associated with urban runoff, at least  concerning DO.
However, some depression during storm events could usually be
seen.  These five sites are on the

     &  Ashtabula R, at Ashtabula, OH;

     @  Grand R. at Painsville, OH;

     •  Hocking R. at Athens, OH;

     ©  Delaware R. at Chester, PA; and

     o  Lehigh R. at Easton, PA.

     In summary, the question "Do severe  (EPA standard) DO defi-
cits occur downstream of urban areas due to urban runoff?"   can-
not be answered conclusively.  There is definite evidence that

                               82

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decreases in DO levels occur downstream of a number of urban
areas after rainfall or flow events.  However, only six of the
monitor sites examined for this study showed clear evidence of
EPA water quality standard violations.  For purposes of discus-
sion, the following facts might be considered.  A population of
104 monitor sites were considered for analysis.  Data could only
be obtained for 83 of these.  Out of the 83, only some of the 55
USGS sites could be examined on an hourly basis.  Of the 55 USGS
sites, 29 showed positive correlation between either rainfall or
flow events and low DO.  Of these 29, only 22 could be examined
on an hourly basis.  Eleven of the 22 could not meet a 5.0 mg/1
DO standard and six could not meet the lesser EPA standard of
2.0 mg/1 for four hours.  When poor monitor location is accounted
for using the Streeter-Phelps technique, a total of 10 sites
might not meet the EPA standard.  If it is assumed that the
group of monitors actually examined closely (22) contains the
same percentage of monitors with water quality violations as the
candidate group (104), the following is obtained.  Including
Streeter-Phelps sites, (13/29) of the 42 percent ((29 + 3+3)/83)
of all monitors that might be correlated, or 19 percent of the
candidate monitors, might not meet a 5.0-mg/1 standard.  (Eight/
22) of the 42 percent, or 15 percent, might not meet the EPA
standard of 2.0 mg/1 for four hours.  The frequency of these
violations would appear to be fairly low.  No exact figures can
be given because programs were not developed to address this
question.  Three to five violations per year at a site with a
strong correlation might be a reasonable guess.  This question
of frequency should probably be the subject of further investi-
gation.

     In fairness, it must be pointed out that the water quality
at sites with EPA standard violations is marginal at all times.
Storm events merely push the level down further.  General im-
provements in water quality at all the critical  (EPA standard)
sites would help alleviate the problem.  For example, the main-
stream of the Delaware River below Trenton, New Jersey, consis-
tently shows a correlation between DO deficit and flow events.
The DO levels are high enough and the river big enough to absorb
the effect without standard violations.  Note that it is not
possible from this study to define how the water quality might
be improved at critical sites.  Further investigation would be
required to determine why quality is poor.

SCOPE OF THE PROBLEM

     The question of whether urban runoff caused DO deficits is
a national problem is difficult to answer.  One item to consider
is the geographic coverage of this study.

     The USGS data base maintained at the USGS National Head-
quarters contains records for 150 water quality monitors.  These
monitors are located in 30 of the 48 conterminous states, i.e.,

                              83

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63 percent coverage.  The distribution of states containing moni-
tors is highly nonuniform.  Thirteen states are east of the
Mississippi River and 17 are west.  Only 47 of the 150 monitors
are in western states.  If the dividing line between east and
west is considered as the western boundaries of Louisiana,
Arkansas, Iowa, and Minnesota, the distribution becomes even
more unbalanced.  Only 19 monitors are then located in the west.

     The distribution of monitor by state is highly nonuniform
also.  The top five monitoring states and the numbers of moni-
tors for USGS are:

     •  Ohio, 32;

     •  New Jersey, 14;

     •  Pennsylvania, 13;

     •  Louisiana, 11; and

     •  South Carolina, 10.

These five states contain over half of all USGS monitors.  Ohio
alone contains over 20 percent.

     The STORET data base contains over 1000 monitor records.
It added, however, only three additional states to the geographic
coverage.  Most of the STORET monitors applicable to this study
are located in North Carolina along the Neuse River.

     The major monitoring networks that contributed to this
study are not designed to provide uniform geographic coverage.
They are heavily biased toward the northeast, with a fair amount
of coverage in the south.  Some investigation of whether the
networks are adequate to detect a national problem is in order.

     It is reasonable to assume that the more water quality
monitors are present in a state, the more likely any existing
DO problems would be found.  The data used in this study were
examined by state  to determine the number of sites with water
quality standards violations versus the number of monitors pres-
ent.  The number of correlations found versus the number of
monitors was also considered.  The results are given in TABLE 17.
Listed are states with violations, the rank of the state in
terms of number of monitors, and the type of violation  (5.0 mg/1
or EPA, 2.0 mg/1 for four hours).  Streeter-Phelps sites are in-
cluded in the totals.  The sites counted in the visible correla-
tion column are those where DO depressions of any size could be
seen at the time of storm events.  No consideration was given  to
standards.

-------
              TABLE 17. PROBLEM SITES PER STATE VERSUS
                  NUMBER OF MONITORS PER STATE
State
Ohio
Massachusetts
Missouri
Texas
New Jersey
Pennsylvania
Oregon
No. of USGS
monitors in
state
32
9
10
3
14
13
1
Rank in
terms of
monitors
1
6
5
10
2
3
Tie for 12
No. of sites
with visible
correlations
10
3
3
2
2
1
1
No. of sites
with 5.0 mg/l
standard violations
8
1
1
2
0
1
0
No. of sites
with EPA
standard violations
6
1
1
2
0
0
0
     The probability of finding visible evidence of a correlation
between low DO and runoff events appears to be one in three (num-
ber of correlations divided by number of monitors in state).
The probability of finding a site where the 5.0-mg/l standard
is violated appears to be between one in 10 and one in four.
The probability of finding an EPA standard violation is between
one in 10 and one in five.

     The writers feel that the geographic distribution of the
nation's water quality monitoring network is not adequate to
conclude anything on national scope of urban runoff related DO
problems.  The odds seem to indicate that if monitors were
located in a Streeter-Phelps correct way, then one in three would
show some evidence of a correlation between urban runoff and DO
depression.  Of those, one in 10 to one in four might indicate
standards violations.

     There is little other information on which to base an esti-
mate of the national impact of urban runoff.  Considerable time
was spent trying to determine if any government agency kept
statistics on the distribution of the nation's population along
rivers.  The U.S. Water Resources Council is considering such an
effort but to date has not implemented a project.  If results
from such a project were available, it might be possible to
estimate the number of potential stream miles affected using the
Streeter-Phelps technique.  Even this would not be conclusive
because there is no well-defined relationship between size of
the urban area and the presence of correlations or standards
violations.  This is discussed in the following subsection.  The
monitoring network is also not adequate to extrapolate the prob-
lem from one area of the country to another.

-------
POSSIBLE CAUSES OF PROBLEM

     The Scope of Work did not call for a determination of the
cause of specific problems.  It did call for considerations of
the percentage of contributing area when selecting monitors for
inclusion in the study.  The percentage of urban area was also
to be considered when stating that a low-DO condition was re-
lated to the presence of urban area.  This will be discussed
along with some other possible contributing factors.

     It is intuitively inviting to assume that the larger the
percentage of a drainage basin that is urban, the more likely it
should be that a low-DO runoff correlation would exist.  This
did not prove to be the case for the data examined here.  Fig-
ure 8 illustrates the nonrelation between the probability of a
greater-than-average DO deficit during higher-than-average flow
and the percentage of urban drainage.  Data for this figure were
taken from Appendix D for most of the 29 USGS sites that showed
positive correlation between flow or rainfall and low DO.  The
percentage of urban drainage ranges from less than one to more
than 80.

     Several other relationships were investigated in an effort
to determine what effect the percentage of urban area has on the
presence of a correlation.  Equally discouraging results were
obtained.  For instance, a regression was run using the mean
probability of low DO at times of high flow as one parameter and
the estimate of urban storm flow from the Streeter-Phelps analy-
sis divided by the mean low flow at the station as the second
variable.  The idea was that if the volume of urban storm runoff
was high compared to the normal stream flow, then the influence
of the runoff would be greater and, hence, the correlation would
be greater.  Many streams are regulated and the percentage of
drainage is no longer a measure of the percentage of flow that
may be contributed.  The results looked encouraging but statis-
tically the correlation coefficient was 0.002.  Regressions were
also run using estimated urban flow divided by average flow as
one parameter and both maximum and mean probability of low DO
at times of high flow as the second parameter.  These were also
unsuccessful. The problem is too complex to study using simple
relations.

     As stated earlier, it was not part of the Scope of Work to
precisely identify the cause of each problem.  However, it is
worthwhile to examine some other possible causes since the ob-
vious urban area percentage proved discouraging.  These are the
types of things that should be studied in order to better under-
stand the problem.

     The urban areas with strong correlations are of many sizes,
covering a fairly large range.  The population of Leominster,
Massachusetts, is approximately 33,000, while the population of

                               86

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CO
         o
         Q


         O
         O

         >
CD
O
oc
Q-
                                                                                                             Y = 50.33 + .4006 log X


                                                                                                             Correlation Coefficient = .0018
             10
                                                                                                                                    100
                                                    RATIO OF URBAN FLOW TO AVERAGE OR LOW FLOW
                                     Figure 8. Probability of low DO at high flow versus percentage of urban area.

-------
Akron, Ohio (Cuyahoga River at Independence monitor), is nearly
three quarters of a million.  Several of the monitor sites with
poor monitor location in a Streeter-Phelps sense were near urban
areas of 20,000.

     Close study of the sites with strong correlations did not
reveal any notable common characteristics.  For instance, the
Mahoning River at the Ohio-Pennsylvania state line, below Lowe11-
ville monitor is just downstream of Young's town, Ohio.  Youngs town
is in a very hilly country.  A large concentration of steel mills
and several sewage treatment plants are located along the river.
The monitor is located on the fringe of the urban development.
The monitor on the Sandusky River near Upper Sandusky, Ohio, is
in a fairly rural setting some 30 miles downstream of Bucyrus,
Ohio.  Bucyrus is a city of 30,000.

     Proximity to sewage treatment facilities is a matter of some
interest.  In most cases, at least one treatment plant was
located upstream of the monitor site.  Distances varied from
less than one mile to 8 to 10 miles.  The monitor on the Raritan
River near South Bound Brook, New Jersey, had six treatment
plants within five miles upstream.  Reintrainment of oxygen-
demanding materials in solids deposits downstream of outfalls
could certainly be a factor at some locations.  Combined sewer
overflows could also be a factor.  Quality and capacity of treat-
ment facilities should also be considered.  If significant quan-
tities of sewage are bypassed during times of high flow, the
impact on a receiving water could be significant.  A high per-
centage of BOD removal still leaves significant quantities of
BOD for high-volume facilities.  The remainder must be oxidized
by the stream in some way.

     The hourly records examined did not show any "first flush"
effect.  The DO deficit increased in a smooth way and remained
high for lengthy periods.  This might indicate that for the
cases examined the problem is not related to a buildup of mate-
rial that is flushed rapidly away.  The length of the deficit
period points to sources of oxygen-demanding material that would
continue throughout a storm event.

     The type of activity carried out along the stream in the
urban environment should certainly be investigated as a cause of
wet weather DO deficits.  Sewage treatment has already been
mentioned.  Certain types of industry continue to discharge
treated waste.   Gravel dredging and concrete mixing activities
often concentrate along rivers.  Each site has its own peculiar-
ities .

SPECIFIC STUDY SITES

     The data examined here indicate that water-quality viola-
tions associated with flow events can occur downstream of urban

-------
areas.  The 5.0 mg/1 and EPA  (2.0 mg/1 for four hours) standards
are both violated.  The frequency of such violations was not
determined exactly, but no need for panic  treatment appears to
exist.  There is, however, a need to understand the causes of
the DO deficits observed here .  An exact understanding of the
causes can be used to prevent the frequency of occurrences from
increasing.  The purpose of this subsection is to identify and
discuss those monitor sites that the writers feel are worthy of
further investigation.

     TABLE 18 identifies those monitor sites that are most likely
to yield useful results from further study.  Listed along with
each site are the minimum observed DO level, the standard that
was violated, and a short description of why the site was chosen.
The sites are listed in the order of preference for study.   Two
monitor groups are identified.  The first group is hydraulically
simple sites; single streams with major urban areas present.
The second group is complex sites with branched streams, several
towns, and other factors--sites where more sophisticated analy-
sis techniques and data collection will be required.

     The first group contains five monitor sites.  These are the
Scioto River, near Chillicothe, Ohio; the Cuyahoga River at Old
Portage and Independence, Ohio; the Mahoning River at the Ohio-
Pennsylvania state line near Lowellville, Ohio; the Sandusky
River near Upper Sandusky, Ohio; and the Little Miami River near
Spring Valley, Ohio.

     The Scioto River site is highly attractive.  It has one of
the most distinct correlations of any station examined on an
hourly basis.  The monitor is located fairly well in a Streeter-
Phelps sense to detect the sag from Columbus, Ohio.  The USGS is
establishing a monitor at Circleville, which is halfway between
Chillicothe and Columbus.  An additional monitor called Scioto
River at Shadeville  is situated in Columbus.  The Ohio USGS
personnel are extremely cooperative and would probably be in-
terested in collecting sediment or other supplementary data to
examine this site.  This is also an excellent choice for further
study.

     The Cuyahoga River flows southwestward, generally parallel-
ing the southern shore of Lake Erie.  It turns north at Akron,
Ohio, joining the Little Cuyahoga, and flows through Cleveland
into the lake.  All of the flow from Akron is sensed by both
monitor sites.  The monitor at Independence is below the mouth
of Tinkers Creek, which drains part of Cleveland and its suburbs.
The Akron sewage treatment facilities lie between the two moni-
tors.  They are separated by roughly 13 miles.  Sediment records
are available at both sites.   The Cuyahoga is famous for having
caught fire in the early 1960.  This, however, was in the in-
dustrial part of Cleveland, which is below both monitors.   There
should be considerable other data available here.

                               39

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TABLE 18. SITES RECOMMENDED FOR FURTHER STUDY
Site Monitor Min. DO
classification normal level, mg/l
Simple -^





Complex -^m


Scioto R. near 0.9
Chillicothe, OH.
Icuyahoga R. at 1.9,4.9
Independence and
Old Portage, OH.
Mahoning R. at 0-1.5
OH.-PA. State
Line below
Lowellville, OH.
Sandusky R. 1.5
near Upper
Sandusky, OH.
Little Miami R. 5.0
near Spring
Valley, OH.
r North Nashua R. 1.8
near Lancaster,
MA.
Schuylkill R. at 3.0
Philadelphia,
PA.
Trinity R. below 0.0
Dallas, TX.
Wilsons Cr. near 0.0
Springfield, MO.
Wilsons Cr. near —
Battlefield, MO.
James R. near —
Boaz, MO.
Standard
violated
EPA
5.0 mg/l,
potential
EPA
Potential
EPA based
on daily
EPA
5.0 mg/l,
potential
EPA
EPA
5.0 mg/l
EPA
EPA


Reason for recommendation
Clear correlation in hourly data; clearly
defined urban area and hydraulics;
potential for cooperation with USGS
Sediment data available; clearly defined
urban area; national reputation for
poor quality.
Large, clearly defined urban area draining
to single stream; good example of heavily
industralized flood plain.
Well located to sense runoff from Bucyrus;
straightforward hydraulics;.
Close to outskirts of Dayton; simple hydraulics;
clear DO depression with storm events .
Significant problem; two distinct
urban areas.
Major urban area; empties into Delaware R.
Biggest urban area of any site; worst
water quality.
Clear correlation; second worst water quality
of any monitor site.


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     The remaining three sites in the first group are all equally
attractive.  The Mahoning River site is just below Youngstown,
Ohio, an industrial city of half a million.  The Sandusky River
monitor is in a excellent position to study runoff from Bucyrus,
Ohio, a city of 20,000.  The Little Miami River site receives
the runoff from Dayton and Xenia, Ohio.  All three are single
streams draining well-defined urban areas with no other signi-
ficant urban area upstream.

     The second group of sites contains six monitor sites and
four stream systems.  These are given in roughly the order of
preference for study.  All are interesting, but they would re-
quire extensive investment in complex models and supportive data
collection.  They are the North Nashua River near Lancaster,
Massachusetts; the Schuylkill River at Philadelphia, Pennsylvania;
the Trinity River below Dallas, Texas; Wilsons Creek near Spring-
field and Battlefield, Missouri; and the James River near Boaz,
Missouri.

     The North Nashua River site is complicated by two distinct
urban areas, Fitchburg and Leominster.  Each are cities of
roughly 35,000.  The monitor and flow gages are separated by
several miles and a lake  dilutes  the stream below the monitor.

     The Schuylkill River site is in the heart of industrial
Philadelphia, just upstream from the junction with the Delaware
River. It may be partially tidally affected. There is no
question of it being an urban site, but only a small reach of
river is available for study before reaching the Delaware.

     The Trinity River below Dallas, Texas, has the worst water
quality observed anywhere during the study.  Six lakes regulate
the flow and in the summer the stream is mostly  treated  sewage
effluent.  The DO falls to zero at a monitor 40 miles downstream
of Dallas during storm events.  The site is discouraging just
from the physical size of the contributing urban area, over 700
square miles.

     The Wilsons Creek and James River sites in Missouri also
have very bad water quality.  These sites have the highest per-
centage urban contributing area in the study, 85 percent.   The
two Wilsons Creek monitors would be interesting to study,  but
the flow in the James is regulated by a lake that catches some
of the runoff from Springfield.  A number of small creeks feed
the runoff from Springfield into Wilsons Creek.


RECOMMENDATIONS FOR STUDY PROCEDURES

     Two types of further study would be worthwhile.   The first
is a general site survey.  The second is a specific study of
detailed site(s).

                               91

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     The general survey study would not require a great deal of
resources.  The study procedure would be to visit each of the
monitor sites where a strong correlation has been identified.
Characteristics of the stream and the land use along it would
be identified.  Local agencies would be visited to determine
sewage treatment practices, industrial practices, and other
activities impacting water quality.  The study objective would
be to develop a general picture of the places where the problem
has been observed.  A study of this type could more accurately
locate sewage outfalls, combined sewer overflow locations, in-
dustrial waste deposits and other things not part of the present
study.

     The detailed site-specific study (studies)  should be di^-
rected toward understanding exactly what happens at one err several
locations where strong correlations have been observed.   This
will require considerably more effort.  Ideally, a well-designed
data collection program should be undertaken to support a mathe-
matical model.  The study should be undertaken in three parts.
First, the necessary information to build an accurate model of
the receiving water flow should be obtained.   This will include
stage records, cross-sections, and tributary and mainstream dis-
charge data.  The second step contains two substeps.  First, an
accurate unsteady flow model should be set up and calibrated.
Steady-flow modeling should not even be considered.  The problem
is associated with unsteady flow and should be studied with the
appropriate models.  The technology is available and not overly
expensive.  Second, the unsteady flow model should be coupled to
a conservative mass transport model.  If at all possible,  this
should be verified by conducting a dye study during a storm
event.  This procedure positively guarantees  a model that will
produce meaningful transport predictions.

     The final step is to model the transport of nonconservative
constituents such as BOD and DO.  No data should be collected
until the conservative transport model has been verified.   It
should then be modified to handle the appropriate constituents
and used to simulate expected conditions during several storm
events.  Best guesses are used for all unknown coefficients.
All data sampling should be geared to define  those receiving
water reaches and at those times the model indicates as  critical
or of most interest.  This minimizes sample cost and maximizes
model accuracy when calibration is undertaken.  Transport in
transient flow is not easy to second guess.  This has been amply
demonstrated by Jobson and Reefer (11)  on the Chattanoochee River.
Only an accurate process model can tell the investigator when
and where to look.

     After the necessary data are collected for the constituents
of most interest, the model can be calibrated for these.  If
this proves impossible, further data collection and model modi-
fication can be undertaken.  Since it will be known that the


                              92

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model accurately predicts conservative transport, any errors in
the nonconservative transport have to be due to inadequately
defined coefficients or processes that were not considered.  By
carefully proceeding to add capability to the model  (e.g., ben-
thic sediment, chemical oxygen demand, and others), the exact
cause of the DO-deficit/high-flow correlation can be identified.

     It is highly unlikely that adequate data for a modeling
effort of the type exists.  Attempting such a study with exist-
ing monitor records and randomly collected water quality samples
is probably a waste of time.

     The writers would strongly recommend the Scioto River be-
tween Columbus and Chillicothe, Ohio, for a study of this type.
This would provide an excellent site and the maximum opportunity
for cooperation with USGS.  As a second choice, the Cuyahoga
River between Akron and Cleveland, Ohio, would be good.  There
are some sediment records that may be helpful  and the hydraulic
conditions are simple to model.  This is also true of the Scioto
River.
                               93

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                          REFERENCES


1.   Rimer,  Alan E.,  and James  A.  Nissen.   Characterization and
     Impact  of Stormwater Runoff  from Various Land Cover Types.
     J.  Water Pollution Control Federation,  Feb.  1978.   pp. 252-
     264.

2.   Thomann, Robert  V.  Systems  Analysis  and Water Quality
     Management.  Environmental Research Applications,  Inc.,
     New York, New York, 1972.  p.  13.

3.   Triangle J Council of Governments.  Areawide Water Quality
     Management Plan.  208 Pollution  Source Analysis.   Research
     Triangle Park, North Carolina, Feb.  1976.   Section V.E.

4.   City of Dallas,  Texas.   Urban Storm Runoff Sampling Program.
     Storm of February 11, 1977.   DWV Operations  Division,  Nov.
     1977.

5.   Unpublished data.  U.S.  Geological Survey , Missouri District,
     Water Resources  Division,  Rolla, Missouri.

6.   Committee on Water Quality Criteria.  Water Quality Criteria,
     1972.  Environmental Protection  Agency, Report R3-73-033,
     March 1973.  p.  134.

7.   Office  of Water  Programs Operations,  U.S. Environmental
     Protection Agency.  1978 Needs Survey.   Report to Congress
     on Cost Estimates for Control of Combined Sewer Overflow
     and Stormwater Discharge.

8.   Bendat, Julius S., and Allan G.  Piersol.  Measurement and
     Analysis of Random Data.  John Wiley  & Sons, New York,
     New York, 1958.

9.   Leopold, Luna B., Gordon M. Wolman,  and John P. Miller.
     Fluvial Processes in Geomorphology.   W. H. Freeman and Co.,
     San Francisco, California, 1964.  p.  251.

10.  Bennett, James P., and R.  E. Rathbun.  Reaeration in Open-
     Channel Flow. U.S. Geological Survey, open file report,
     Fort Collins, Colorado,  April 1971.
                               94

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11.    Jobson,  H.  E.,  and T.  N. Keefer.  Thermal Modeling of Highly
      Transient Flows in the Chattahoochee River Near Atlanta,
      Georgia. Proceedings,  American Water Resources Association
      Symposium on River Quality Assessments, Tucson, Arizona,
      Nov. 2-3, 1977.
                                95

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                           APPENDIX A

             WATER QUALITY DATA COLLECTION AGENCIES
      This appendix contains a complete listing of all the agen-
cies that collect water quality data as reported by the USGS
Office of Water Data Coordination (OWDC).  The agencies and their
identification codes are listed according to the regions de-
scribed in Section 5 of the report.
                               96

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                   REGION 1


               FEDERAL AGENCIES

CE    Corps of Engineers (Army)
EPA  Environmental Protection Agency
ERD  Energy Research and Development Administration
FS    Forest Service (Agriculture)
GS    Geological Survey (Interior)
NFE  Naval Facilities Engineering Command (Navy)
NOS  National Ocean Survey (Commerce)
NWS  National Weather Service (Commerce)
                     CANADA

WQB  Environment Canada, Water Quality Branch
WSC  Environment Canada, Water Resources Branch
             NON-FEDERAL AGENCIES

      Connecticut
DOO  Environmental Health Service Division,
        State Department of Health
D01  The Water Bureau of the Metropolitan District,
        Hartford
D02  Bridgeport Hydraulic Company
DOS  Connecticut Department of Environmental Protection

      New York
P50  New York State Department of Environmental
        Conservation
                      97

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                    REGION 2
                 FEDERAL AGENCIES

AHS  Army Health Services Command (Army)
CE    Corps of Engineers (Army)
ERD  Energy  Research and Development Administration
EPA  Environmental Protection  Agency
GS    Geological Survey (Interior)
MC   Marine  Corps (Navy)
MFS  National Marine Fisheries Service (Commerce)
NpE  Naval Facilities Engineering Command (Navy)
NOS  National Ocean Survey (Commerce)
NWS  National Weather Service (Commerce)
                       CANADA

WQB  Environment Canada, Water Quality Branch
WSC  Environment Canada, Water Resources Branch
              NON-FEDERAL AGENCIES

      Delaware
050   Delaware Geological Survey

      Maryland
D51   Baltimore County Health Department
D52   City of Baltimore, Water Supply Treatment and
         Pumping Division

      District of Columbia
D53   Department of Sanitary Engineering
D54   Department of Environmental Health Administration

      New Jersey
050   Passaic Valley Water Commission
051   New Jersey State Department of Environmental
          Protection
052   North Jersey District Water Supply Commission
054   Delaware River Joint Toll Bridge Commission

      New York
P50   New York State Department  of Environmental
          Conservation

      Pennsylvania
S50   Pennsylvania Department of Environmental Resources
                       98

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       Virginia
 WOO   State Water Control Board

       West Virginia
 X50   West Virginia Department of Natural Resources
 X51   West Virginia Department of Health


                     REGIONS


                  FEDERAL AGENCIES

 AHS   Army Health Services Command (Army)
 CE    Corps of Engineers (Army)
 ERD   Energy Research and Development Administration
 El'A   Environmental Protection Agency
 FS    Forest Service (Agriculture)
 GS    Geological Survey (Interior)
 MC    Marine Corps (Navy)
 NFE   Naval Facilities Engineering Command (Navy)
 NOS   National Ocean Survey (Commerce)
 NWS   National Weather Service (Commerce)
               NON-FEDERAL AGENCIES

      Alabama
A04  Alabama Water Improvement Commission

      Florida
EDO  Hollywood Reclamation District
EO1   Hillsborough County Health Department
E02  Manatee County Health Department
£03  Central and Southern Florida Flood Control District
E17  State of Florida Department of Pollution Control
E21   Hillsborough County Environmental Protection
         Commission

      Georgia
E50  Savannah Department of Water and Sewage
E51   Thomasville Water and Light Department
E52   Valdosta Water and Sewer Department
E5 3   Water Works, City of Gainesville
E54   Rome City Manager
E5 5   Water Works, City of Griffin
E56   Board of Water Commissioners, City of Macon
E57  Atlanta Water Works
E58  Columbus Water Works
E60  Georgia  Department of Natural Resources
                        99

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       Louisiana
151    Louisiana State Department of Health
159    Louisiana Wildlife and Fisheries Commission

       Mississippi
L51    City of Jackson Water Works
L52    Pearl River Valley Water Supply District
L53    City of Meridian Water and Sewer Dept.
L54    City of Columbus Light and Water Dept.
L55    Mississippi State Board of Health

       North Carolina
QOO    North Carolina Department of Human Resources
Q01    North Carolina Department of Natural and Economic
         Resources

       South Carolina
T50    Agricultural Engineering Department, Clemson University
T51    Greenville Water System
T52    Spartanburg Water Works
T53    South Carolina Department of Health and Environmental
         Control

       Tennessee
U52    Cleveland Water System

       Virginia
WOO    State Water Control Board
                   REGION 4


                 FEDERAL AGENCIES

CE    Corps of Engineers (Army)
EPA   Environmental Protection Agency
ERD  Energy Research and Development Administration
FS    Forest Service (Agriculture)
FWS   Fish and Wildlife Service (Interior)
GLB   Great Lakes Basin Commission
GS    Geological Survey (Interior)
NFE   Naval Facilities Engineering Command (Navy)
NOS   National Ocean Survey (Commerce)
NWS   National Weather Service (Commerce)
                       CANADA

WQB  Environment Canada, Water Quality Branch
WSC  Environment Canada, Water Resources Branch
                        100

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               NON-FEDERAL  AGENCIES

       Illinois
GOO   Illinois Department of Public Health
G01    Metropolitan Sanitary District of Greater Chicago
G03   Illinois Department of Public Works and Buildings

       Indiana
G50   Indiana State Board of Health

       Michigan
K50   Michigan Department of Natural Resources

       Minnesota
L02   Minnesota Department of Natural Resources
L06   Water, Gas and Sewage Treatment Department,
          City of Duluth
L07   Minnesota Ore Operations,  USS Corp.
L09   Minnesota Power and Light Company
LI 1    Minnesota Pollution Control Agency

       New York
P50    New York State Department of Environmental
          Conservation

       Ohio
R03   Ohio Environmental Protection Agency

       Pennsylvania
S50    Pennsylvania Department of Environmental Resources

       Wisconsin
YOO   Wisconsin Department of Natural Resources
Y05   Wisconsin Michigan Power Company
                    REGIONS
                  FEDERAL AGENCIES

AHS   Army Health Services Command (Army)
CE    Corps of Engineers (Army)
EPA   Environmental Protection  Agency
ERD   Energy Research and Development Administration
FS     Forest Service (Agriculture)
FWS   Fish and Wildlife Service (Interior)
GS    Geological Survey  (Interior)
NWS   National Weather Service (Commerce)
TVA   Tennessee Valley Authority
                       101

-------
               NON^FEDERAL AGENCIES

      Illinois
GOO   Illinois Department of Public Health
GO 2   Illinois Department of Registration and Education
G03   Illinois Department of Public Works and Buildings

      Indiana
G50   Indiana State Board of Health

      Kentucky
100    Kentucky Department for Human Resources
101    Kentucky Department for Natural Resources and
         Environmental Protection

      New York
P50   New York State Department of Environmental
         Conservation

      North Carolina
Q01   North Carolina Department of Natural and Economic
         Resources

      Ohio
ROO   Ohio Department of Natural Resources
RO1   The Miami Conservancy District
R02   Ohio River Valley Water Sanitation Commission
R03   Ohio Environmental Protection Agency

      Pennsylvania
S50   Pennsylvania Department of Environmental Resources

      South Carolina
T53   South Carolina Department of Health and Environmental
         Control

      Tennessee
U50   Tennessee Wildlife Resources Agency
U51   Tennessee Department of Public Health

      Virginia
WOO   State Water Control Board

      West Virginia
X50   West Virginia Department of Natural Resources
X51   West Virginia Department of Health
                       102

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                   REGION 6


                 FEDERAL AGENCIES

EPA  Environmental Protection Agency
ERD  Energy Research and Development Administration
FS    Forest Service (Agriculture)
GS    Geological Survey (Interior)
NWS  National Weather Service (Commerce)
TVA  Tennessee Valley Authority
               NON-FEDERAL AGENCIES

      Alabama
A01   Geological Survey of Alabama

      Georgia
E60   Georgia Department of Natural Resources

      Kentucky
100   Kentucky Department for Human Resources
101   Kentucky Department for Natural Resources and
         Environmental Protection

      Mississippi
L55   Mississippi State Board of Health

      North Carolina
QOO   North Carolina Department of Human Resources
QO1   North Carolina Department of Natural and Economic
         Resources

      Tennessee
U50   Tennessee Wildlife Resources Agency
US 1   Tennessee Department of Public Health
U52   Cleveland Water System
U54   Bristol Water Plant
U55   University of Tennessee Experiment Station
U57   Water Resources Research Center, University of
         Tennessee
                   REGION?


                 FEDERAL AGENCIES

CE    Corps of Engineers (Army)


                        103

-------
EPA   Environmental Protection Agency
ERD  Hnergy Research and Development Administration
FS    Forest Service (Agriculture)
FWS  Fish and Wildlife Service (Interior)
GS    Geological Survey (Interior)
NWS  National Weather Service (Commerce)
               NON-FEDERAL  AGENCIES

      Illinois
GOO   Illinois Department of Public Health
G01   Metropolitan Sanitary District of Greater Chicago
G02   Illinois Department of Registration and Education
G03   Illinois Department of Public Works and Buildings

      Indiana
C50   Indiana State Board of Health

      Iowa
HOO   Iowa State Hygenic Laboratory
H02   Des Moines Water Works
H03   Ottumwa Water Works
H05   Iowa Department of Preventive Medicine and
         Environmental Health
H06   Agricultural Engineering Department, Iowa State
         University
H07    Fort Dodge Department of Municipal Utilities
H09    Des Moines County Drainage District No. 7
H10    Green Bay Levee and Drainage District No. 2

      Minnesota
LOO    Hennepin County Highway Department
L02    Minnesota Department of Natural Resources
LOS    Otter Tail Power Company
L04    Ramsey County  Engineer's Department
LOS    Northern State Power Company
LOS    Blandin Paper Company
L09    Minnesota Power and Light Company
L10    Metropolitan Sewer Board
LI 1   Minnesota Pollution Control Agency
LI 2   Washington County Highway Department

      Missouri
MOO   Division of Health of Missouri
M02   University  of Missouri at Rolla
M03   Metropolitan St. Louis Sewer District
M04    Little River Drainage District
M06   Missouri Clean Water Commission
                         104

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        Wisconsin
 YOO    Wisconsin Department of Natural Resources
 Y02    Dairyland Power Cooperative
 Y04    Northern States Power Company
                    REGION 8

                  FEDERAL AGENCIES

CE    Corps of Engineers (Army)
EPA   Environmental Protection Agency
GS    Geological Survey (Interior)
MFS   National Marine Fisheries Service (Commerce)
NFE   Naval Facilities Engineering Command
NWS   National Weather Service (Commerce)
TVA   Tennessee Valley Authority


               NON-FEDERAL AGENCIES

       Arkansas
B50   Bureau of Environmental Engineering, Arkansas State
          Department of Health
B5 1    Arkansas Game and Fish Commission
B52   Arkansas Pollution Control and Ecology

       Kentucky
100    Kentucky Department for Human Resources
101    Kentucky Department for Natural Resources and
          Environmental Protection

       Louisiana
151    Louisiana State Department of Health
152    Houma Light and  Water Plant
153    Jefferson Water Works District No. 2
154    Lafourche Water Works District No. 1
155    East Jefferson Water Works District No. 1
156    New Orleans Sewerage and Water Board
158    Utilities Commission Water Treatment Plant, City of
          Monroe
159    Louisiana Wildlife  and Fisheries Commission, Division of
          Water Pollution Control

       Mississippi
L50    City of Vicksburg Water Treatment Plant
L55    Mississippi State Board of Health

                        105

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       Missouri
MOO   Division of Health of Missouri
M04   Little River Drainage District
M06   Missouri Clean Water Commission

       Tennessee
U50   Tennessee Wildlife Resources Agency
US 1   Tennessee Department of Public Health
U55   University of Tennessee Experiment Station
                   REGION 9

                 FEDERAL AGENCIES

CE    Corps of Engineers (Army)
EPA  Environmental Protection Agency
FS    Forest Service (Agriculture)
GS    Geological Survey (Interior)
NWS  National Weather Service (Commerce)


                       CANADA

WQB  Environment Canada, Water Quality Branch
WSC  Environment Canada, Water Resources Branch


               NON-FEDERAL AGENCIES

      Minnesota
L02   Minnesota Department of Natural Resources
L03   Otter Tail Power Company
L07   Minnesota Ore Operations, USS Corp.
L09   Minnesota Power and Light Company
LI 1   Minnesota Pollution Control Agency

      North Dakota
Q50  North Dakota Game and Fish Department
Q51   North Dakota State Department of Health
Q52  Minot City Water Treatment Plant
Q55  Grand Forks Water Treatment Plant
                       106

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                   REGION 10


                 FEDERAL AGENCIES

BR    Bureau of Reclamation (Interior)
CE    Corps of Engineers (Army)
F.PA   Environmental Protection Agency
FS    Forest Service (Agriculture)
FWS   Fish and Wildlife Service (Interior)
GS    Geological Survey (Interior)
NFE   Naval Facilities Engineering Command (Navy)
NWS   National Weather Service (Commerce)
SCS    Soil Conservation Service (Agriculture)
                        CANADA

WQB   Environment Canada, Water Quality Branch
WSC   Environment Canada, Water Resources Branch
               NON-FEDERAL AGENCIES

       Colorado
C50    Board of Water Commissioners, City and County of
         Denver
C51    Division of Water Resources, Office of Colorado State
         Engineer
C53    Boulder City County Health Department

       Iowa
HOO    Iowa State Hygenic Laboratory
HOI    Director of Lakeside Laboratory, University of Iowa
H06    Agricultural Engineering Department, Iowa State
         University
H08    Council Bluffs Water Works

       Kansas
H50    Kansas State Department of Health
H51    Board of Public Utilities, Kansas City
H52    Kansas State Board of Agriculture
H53    Topeka Water Department
HS4    Kansas Forestry, Fish, and Game Commission

       Minnesota
L02    Minnesota Department of Natural Resources
LI 1    Minnesota Pollution Control Agency
                        107

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       Missouri
MOO   Division of Health of Missouri
M06   Missouri Clean Water Commission
MOV   Union Electric Company, Bagnell Dam

       Montana
M50   Montana Fish and Game Department
M51   Montana University Joint Water Resources Research
          Center
M52   Montana State Department of Health and Environmental
          Sciences
M53   Montana Department of Natural Resources and
          Conservation

       Nebraska
NOO   Nebraska Game and Parks Commission
N01    State of Nebraska Department of Environmental Control
N02   Metropolitan Utilities District, City of Omaha
N03   Soil and Water Testing Laboratory,  University of
          Nebraska

       North Dakota
Q50   North Dakota Game and Fish Department
Q51    North Dakota State Department of Health
Q52   Minot City Water Treatment Plant
Q53   City of Bismarck Water Department
Q54   City of Dickinson Water Treatment

       South Dakota
UOO   Water Resources Research Institute, South Dakota State
          University
U01    East Dakota Conservancy Sub-District

       Wyoming
Y50   City of Casper Board of Public Utilities
Y51    Sheridan Water Department
Y52   Wyoming State Engineer
Y53   Water Resources Research Institute, University of
          Wyoming
                   REGION 11
                 FEDERAL AGENCIES

BR    Bureau of Reclamation (Interior)
CE    Corps of Engineers (Army)
EPA   Environmental Protection Agency

                      108

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FS     Forest Service (Agriculture)
FWS   Fish and Wildlife Service (Interior)
CiS     Geological Survey (Interior)
NFE   Naval Facilities Engineering Command
NW'S   National Weather Service (Commerce)
               NON-FEDERAL AGENCIES

       Arkansas
B-50    Arkansas State Department of Health
QS]    Arkansas Game and Fish Commission
B5Z    Arkansas Pollution Control and Ecology

       Colorado
C51    Division of Water Resources, Office of State Engineer
CS2.    City of Colorado Springs, Water Division
C54    Pueblo Board of Water Works

       Kansas
H50    Kansas State Department of Health
H52    Kansas State Board of Agriculture
H54    Kansas Forestry, Fish and Game Commission

       Louisiana
151    Louisiana State Department of Health
157    Bossier City Water Plant
159    Louisiana Wildlife and Fisheries Commission
160    City of Shreveport Department of Water Utilities

       Missouri
MOO   Division of Health of Missouri
M06   Missouri Clean Water Commission

       Oklahoma
R50    Oklahoma State Department of Health

       Texas
VOO    Texas Water Development Board
                    REGION 12

                  FEDERAL AGENCIES

CE     Corps of Engineers (Army)
EPA   Environmental Protection Agency
GS     Geological Survey (Interior)
                        109

-------
IBW   International Boundary and Water Commission
NFE  Naval Facilities Engineering Command (Navy)
NOS  National Ocean Survey (Commerce)
NWS  National Weather Service (Commerce)
               NON-FEDERAL AGENCIES

      Louisiana
159   Louisiana Wildlife and Fisheries Commission

      Texas
VOO   Texas Water Development Board
                  REGION 13

                 FEDERAL AGENCIES

BR    Bureau of Reclamation (Interior)
CE    Corps of Engineers (Army)
EPA  Environmental Protection Agency
FS    Forest Service (Agriculture)
GS    Geological Survey (Interior)
IBW  International Boundary and Water Commission
NWS  National Weather Service (Commerce)


               NON-FEDERAL AGENCIES

      Colorado
C51   Division of Water Resources, Office of Colorado State
         Engineer

      New Mexico
POO   New Mexico State Engineer's Office
                  REGION 14

                 FEDERAL AGENCIES

BR    Bureau of Reclamation (Interior)
EPA   Environmental Protection Agency
FS     Forest Service (Agriculture)
FWS   Fish and Wildlife Service (Interior)

                       110

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GS     Geological Survey (Interior)
NWS   National Weather Service (Commerce)
               NON-FEDERAL  AGENCIES

       Colorado
C50    Board of Water Commissioners, City and County of
         Denver
C51    Division of Water Resources, Office of Colorado State
         Engineer
C52    City of Colorado Springs, Water Division

       Utah
V50   Utah State Health Department
V52   Utah Department of Natural Resources

       Wyoming
Y52   Wyoming State Engineer
                   REGION 15

                  FEDERAL AGENCIES

BLM   Bureau of Land Management (Interior)
BR    Bureau of Reclamation (Interior)
CE    Corps of Engineers (Army)
EPA   Environmental Protection Agency
FS    Forest Service (Agriculture)
GS    Geological Survey (Interior)
IBW   International Boundary and Water Commission
NWS   National Weather Service (Commerce)
SCS   Soil Conservation Service (Agriculture)
               NON-FEDERAL AGENCIES

       Arizona
BOO    Salt River Project
B01    Water Resources Research Center, University of Arizona
B02    Roosevelt Irrigation District
BOS    Arizona Game and Fish Department
B04    Maricopa County Municipal Water Conservation
BOS    Gila Water Commissioner
                        111

-------
       California
COO    California Department of Water Resources

       Nevada
N50    Nevada State Health Division

       Utah
V50    Utah State Health Department


                   REGION 16


                  FEDERAL AGENCIES

BLM   Bureau of Land Management (Interior)
BR    Bureau of Reclamation (Interior)
CE    Corps of Engineers (Army)
EPA    Environmental Protection Agency
ERD   Energy Research and Development Administration
FS     Forest Sendee (Agriculture)
GS    Geological Survey (Interior)
NFE   Naval Facilities Engineering Command (Navy)
NWS   National Weather Service (Commerce)
SCS    Soil Conservation Service (Agriculture)
               NON-FEDERAL AGENCIES

       California
COO    California Department of Water Resources

       Idaho
F50    Idaho State Fish Hatchery
F52    Idaho Department of Environmental and Community
          Services

       Nevada
N50    Nevada State Health Division
N51    Walker River Irrigation District

       Utah
V50    Utah State Health Department
V51    Metropolitan Water District of Salt Lake City
V53    Salt Lake County Water Conservancy District
V54    Salt Lake City Water Supply and Waterworks
V55    Ogden Bay Waterfowl Management Area
V56    Clear Lake Waterfowl Management Area
V58    Utah Geological and Mineralogical Survey
V59    Ogden River Water Users
V60    Weber Distribution System
                        112

-------
                    REGION 17
                  FEDERAL AGENCIES

HPA   Bonnevillc Power Administration (Interior)
BR    Bureau of Reclamation (Interior)
CF    Corps of Engineers (Army)
HPA   Environmental Protection Agency
I- KD   Energy Research and Development Administration
I;S     Forest Service (Agriculture)
I-'WS   Fish and Wildlife Service (Interior)
CiS    Geological Survey (Interior)
NIC    Marine Corps (Navy)
MFS   National Marine Fisheries Service (Navy)
N'FH   Naval Facilities Engineering Command (Navy)
NOS   National Ocean Survey (Commerce)
NWS   National Weather Service (Commerce)
SCS    Soil Conservation Service (Agriculture)
                       CANADA

WQB  Environment Canada, Water Quality Branch
WSC  Environment Canada, Water Resources Branch
               NON-FEDERAL AGENCIES

      Idaho
F5l   Water Resources Research Institute, University of Idaho
F52   Idaho Department of Environmental and Community
         Services

      Montana
M50   Montana Fish and Game Department
M53   Montana Department of Natural Resources and
         Conservation

       Nevada
N50   Nevada State Health Division

       Oregon
SOO    Department of Forest Engineering, Oregon State
          University
SOI    Oregon Wildlife Commission
S02    Douglas County Water Resource Survey
SOS    Oregon State Engineer
S04    Fish Commission of Oregon
S13    Portland General Electric
                        113

-------
       Washington
XOO   State of Washington, Department of Ecology, Water
         Resources Division
X01   Public Utility District No. 1, Skagit County
X02   Chelan County PUD No. 1
X03   College of Fisheries, University of Washington
X04   College of Engineering Research, Washington State
         University
X05   Department of Zoology, University of Washington
X06   City of Bremerton Water Department
X07   City of Everett Department of Water
X08   Seattle Water Department
X09   City of Tacoma, Department of Public Utilities
XI2   Municipality of Metropolitan Seattle
XI6   King County, Washington, Department  of Public Works
X19   The Washington Water Power Company
X20   Douglas County Public Utility District
X21   Public Utility District of Grant County
X24   Puget Sound Power and Light Company
X25   City of Seattle
                   REGION 18


                 FEDERAL AGENCIES

BLM  Bureau of Land Management (Interior)
BR   Bureau of Reclamation (Interior)
CE   Corps of Engineers (Army)
EPA  Environmental Protection Agency
FS   Forest Service (Agriculture)
GS   Geological Survey (Interior)
IBW  International Boundary and Water Commission
MC   Marine Corps (Navy)
MFS  National Marine Fisheries Service (Commerce)
NFE  Naval Facilities Engineering Command (Navy)
NOS  National Ocean Survey (Commerce)
NWS  National Weather Service (Commerce)
SCS   Soil Conservation Service (Agriculture)
               NON-FEDERAL AGENCIES

      California
COO   California Department of Water Resources
CO I   Los Angeles County Flood Control District
C03   Alameda County Water District
C04   County of Sacramento, Water Resources Division
COS   Whitewater Mutual Water Company

                        114

-------
 C06   California Water Quality Control Board
 C09   Ventura County Flood Control District
 CIO   San Diego Department of Sanitation and Flood Control
 Cl 1    Orange County Flood Control District
 Cl 2   Merced Irrigation District
 C13   Turlock Irrigation District
 C.14   Tridam Irrigation District
 C15   Pacific Gas and Electric
C16   Oroville-Wyandotte Irrigation District
C17   Mosquito Irrigation District
CIS   Contracting Entities
Cl9   East Bay Municipal Utility District
C20   Modesto Irrigation District
C21    El Nido Irrigation District
C22   Madera Irrigation District
C23   Hetch Hetchy Water Supply, City and County of
          San Francisco
C24   Southern California Edison Company
C25   Pacific Power and Light
C26   Kings River Water Association
C27   Fresno Irrigation District
C28   Kaweah and St. Johns Water Association
C29   Tulare Irrigation District
C30   Delano-Earlimart Irrigation District
C31    Kern County Land Company
C32   Buena Vista Water Storage District
C33   Terra Bella Irrigation District
C34   Sausalito Irrigation District
C35   Monterey County Flood Control and Water Conservation
          District
C36   San Luis Obispo County Flood Control and Water
          Conservation District
C37   Montecito County Water District
C38   Santa Barbara County Flood Control and Water
          Conservation District
C39   Metropolitan Water District of Southern California
C40   Marin Municipal Water District
C41    Marin, North, County Water District
C42   Sonoma County Flood Control and Water  Conservation
          District
C43    Alameda County Flood Control and Water  Conservation
          District
C44    Santa Clara Valley Water District
C45    Tule Irrigation District
C46    Montague Water Conservation District
C47    City of Los Angeles,  Dept. of Water and Power
C48    Palm Springs Water Company
C49    Escondido Mutual Water Company
                        115

-------
ZOO    San Bernardino County Flood Control District
Z01    San Antonio Water Company
Z02    Temescal Water Company
Z03    Riverside County Flood Control and Water Conservation
          District
Z04    Ventura River Municipal Water District
Z05    Ventura County Water Resources Division
Z06    United Water Conservation District
Z07    Kings River Water Conservation Board
Z08    La Canada Irrigation District
Z09    San Gabriel Electric Company

       Nevada
N50    Nevada  State Health Division
N54    Nevada  Irrigation District

       Oregon
SO 1    Oregon  Wildlife Commission
SOS    Oregon  State Engineer
                   REGION 19

                 FEDERAL AGENCIES

EPA   Environmental Protection Agency
FS     Forest Service (Agriculture)
GS     Geological Survey (Interior)
MC    Marine Corps  (Navy)
MFS   National Marine Fisheries Service (Commerce)
NFE   Naval Facilities Engineering Command (Navy)
NOS   National Ocean Survey (Commerce)
NWS   National Weather Service (Commerce)
SCS    Soil Conservation Service (Agriculture)
                        CANADA

WSC   Environment Canada, Water Resources Branch


               NON-FEDERAL AGENCIES

       Alaska
A50   Chugach Electrc Association
A51   Alaska Department of Highways
ASS   Alaska Department of Environmental Conservation


                        116

-------
       Washington
X03   College of Fisheries, University of Washington
                  REGION 20

                 FEDERAL AGENCIES

CE    Corps of Engineers (Army)
EPA   Environmental Protection Agency
GS    Geological Survey (Interior)
MC    Marine Corps (Navy)
NFE   Naval Facilities Engineering Command (Navy)
NOS   National Ocean Survey (Interior)


               NON-FEDERAL AGENCIES

       Hawaii (and other Pacific Islands)
FOO    Board of Water Supply, City and County of Honolulu
F01    Department of Water, County of Kauai
F02    Board of Water Supply, County of Maui
F03    Board of Water Supply, County of Hawaii
F04    Department of Hawaiian Home Lands, State of Hawaii
F05    Department of Land and Natural Resources, State of
         Hawaii, Division of Fish and Game
F06    Department of Land and Natural Resources, State of
         Hawaii, Division of Water and Land Development
F07    Public Utility Agency Water Division, Government
         of Guam
F08    Ryukyu Industrial Research Institute, Government of
         Ryukyu Islands
F09    Ryukyu Meteorological Agency, Government of
         Ryukyu Islands
                  REGION 21

                 FEDERAL  AGENCIES

GS    Geological Survey (Interior)
NFE  Naval Facilities Engineering Command (Navy)
NOS  National Ocean Survey (Commerce)
NWS  National Weather Service (Commerce)
                       117

-------
              NON-FEDERAL AGENCIES

      Puerto Rico
TO-1   Puerto Rico Water Resources Authority
                     118

-------
                          APPENDIX B

            MONITOR SITES CONSIDERED FOR ANALYSIS
      This appendix contains a listing of the 104 monitor sites
that were considered for analysis in this study- All the sites
listed were considered to be sufficiently close to some populat-
ed area to warrant analysis. Further investigation sometimes
revealed that data were not available or some other factor was
present and prevented analysis. Those sites that could not be
used and the reasons why are identified in Table B-l.
                               119

-------
      TABLE  B-1. LIST OF ALL SITES CONSIDERED FOR DAILY OR HOURLY ANALYSIS
State
Alabama

Colorado





Georgia




Illinois


Louisiana



Station name
Coosa R. at Verbena
Coosa R. at Gadsen
S. Platte R., 60 ave.
S. Platte R., 88 ave.
Burlington Ditch at
York St.
Sand Cr. at
Burlington Ditch
Chattahoochee R. at
Atlanta
Peachtree Cr. near
Atlanta1'
Ocmulgee R. near
Warner-Robins1
Calumet R. STW1
Chicago R. Bridge*
Chicago Sanitation
and Ship Canal
at Lockport*
Bayou Teche at
Olivier
Houma Nav. Canal
near Dulac*
Agency* Lat.
GS
EPA
EPA
EPA
EPA

EPA

EPA

GS

GS
G01
G01
G01

GS

GS

324756
340057
394826
395115
394802

394837

335132

335133

324017
413946
415333
413408

295718

292306

Long.
862602
855843
1045730
1045615
1045730

1045659

842716

842716

833611
873940
873832
880441

914254

904347

	 Water discharge . Distance to
Site Established , ram . . ..
available? ram gage (mt)
gage
Stream
Stream
Stream
Stream
Canal

Stream

Stream

Stream

Stream
Canal
Stream
Canal

Stream

Stream

1974
1971
1968
1968
1967

1967

1960

_

1970
1969
1969
1969

1972

1973

Yes
Yes
Yes
Yes
Yes

Yes

Yes

No

No
No
Yes
Yes

Yes

No

Montgomery —
Gadsen —
Denver <10
Denver <10
Denver <10

Denver <10

Atlanta 10

Atlanta 10

Macon 20
Chicago 20
Chicago 5
Chicago 35

_ _

_ _

Applicability
to study
code
4
4
1
1
1

1

1

1

4
2
1
2

_

_

•The agency codes, taken from OWDC, identify the agency that was in charge of the data; specifically, GS * Geological Survey, EPA = Environmental Protection Agency, GDI = Metn
 politan Sanitation District of Greater Chicago, R02 = ORSANCO, WDNR <= Wisconsin Department of Natural Resources.
tShe was later dropped.
                                                                                                  (continued)

-------
TABLE B-1 (continued).
State
Louisiana
(continued)
Massachusetts




















Mississippi

Maine

Station name
Ouachita R. at
Monroe
Blackstone R. at
Millville
Connecticut R. at
W. Springfield
Connecticut R. at
Agawamt
Hoosic R. below
Williamston
Merrimack R. at W.
Newbury
Merrimac R. above
Concord R. at
Lowell*
N. Nashua R. near
Leominster
Quinebaug R. near
Dudley
Westfield R. at
Westfield
Chicopee R. at
Chicopee Falls
Yellow Cr. near
Doskie
Vermillion R. near
Empire City
Agency
GS

GS

GS

GS

GS

GS

GS


GS

GS

GS

GS

GS

GS

Lat.
323019

420116

420546

420257

424428

424838

423857


423006

420140

420559

420937

345402

444000

Long.
920732

713404

723543

723635

731247

710002

711950


714323

715722

723828

723452

881735

930317

Primary „
.. . Water discharge Distance to
Site Established .. . . , raln i -\
available? ram gage (mi)
gage
Stream

Stream

Stream

Stream

Stream

Stream

Stream


Stream

Stream

Stream

Stream

Stream

Stream

1954

1969

1972

1968

1968

1969

1967


1968

1968

1972

1973

1973

1974

Yes Shreveport 90

Yes

Yes Hartford 25

Yes Hartford 25

Yes

Yes

No Boston 25


Yes

Yes

Yes Hartford 25

Yes Hartford 30

Yes

Yes

Applicability
to study
code
4

4

2

2

4

4

4


4

4

2

4

4

4

                                             (continued)

-------
TABLE B-1 (continued).
State
Missouri







New Jersey









North
Carolina







Station name Agency
Center Cr. near
Carterville
James R. near
Boaz
Wilsons Cr. near
Battlefield
Wilsons Cr. near
Springfield
Delaware R. at
Trenton
Manasquan R. at
Squankum
Pompton R. at
Two Bridges
Passaic R, at
Little Falls*
Raritan R. at S.
Bound Brook
Cape Fear R. at
Channel Marker 50
Muddy Cr. 500' below
effluent
N. Fork Muddy Cr.
Muddy Cr. atS.R.
1485
Muddy Cr. at S.R.
2991
GS

GS

GS

GS

GS

GS

GS

GS

GS

EPA

EPA

EPA
EPA

EPA

Lat.
370826

370025

370702

370706

401318

400947

405352

405305

403305

341533

360312

360220
355690

360030

Long.
942257

932150

932414

932414

744642

740921

741622

741335

743254

775624

794424

801810
802100

802000

Primary r.
Water discharge Distance to
Site Established ...... rain . . ..
available? ram gage (mi)
gage
Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream
Stream

Stream

1962

1972

1972

1967

1923

1970

1969

1963

-

1974

1974

1974
1974

1974

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes
Yes

Yes

Springfield 70

Springfield 25

Springfield 20

Springfield 20

Trenton 10

-

Trenton 10

Newark 15

- -

Wilmington <10

Greensboro —

Winston-Salem —
Winston-Salem —

Winston-Salem —

Applicability
to study
code
4

4

2

2

1

4

1

1

4

1

2

2
2

2

                                             (continued)

-------
                                               TABLE B-1 (continued).
[\J
State Station name Agency
Roanoke, R. 1 mi.
upstream of Welch
Cr.
Neuse R. at U.S. 70
Neuse R. at U.S. 42
Neuse R. at U.S. 98
Neuse R. at U.S. 50
Ohio Ashtabula R. at
Ashtabula
Black R. at Elyria
Black Fork at
Loudonville
Blanchard R. near
Findlay
Cuyahoga R. at
Independence
Cuyahoga R. at Old
Portage
Cuyahoga R. at
Superior St. Bridget
Cuyahoga R. at W.
3rd St. Bridge
Grand R. near
Painsville
Hocking R. below
Athens
Huron R. below
Milan
EPA


EPA
EPA
EPA
EPA
GS

GS
GS

GS

GS

GS

GS
GS

GS

GS

GS

Lat.
355200


353041
353815
355840
360052
415400

412442
403809

410321

412343

410808

412939
412917

414409

391939

412006

Long.
764700


782100
782347
78380"
789130
804744

820545
821422

834117

813748

813250

814212
814107

811559

820018

823438

Water discharge Distance to
Site Established .. . . , rain . . ..
available? ram gage (mi)
gage
Stream


Stream
Stream
Stream
Stream
Stream

Stream
Stream

Stream

Stream

Stream

Stream
Stream

Stream

Stream

Stream

1974


1975
1975
1975
1975
1968

1966
1968

1965

1948

1965

1950
1966

1950

1966

1970

Yes


Yes
Yes
Yes
Yes
Yes

Yes
Yej

Yes

Yes

Yes

Yes
Yes

Yes

Yes

Yes




-
_
_
-
Cleveland

Cleveland
Mansfield

Toledo

Cleveland

Cleveland

Cleveland
Cleveland

Cleveland

Parkersburg,
WV.
_




-
—
—
-
60

20
20

50

10

25

10
10

25

30

_

Applicability
to study
code
4


4
4
4
4
2

4
4

4

1

1

1
1

4

4

3

                                                                                         (continued)

-------
TABLE B-1 (continued).
State Station name
Ohio Little Miami R. at
(continued) Miamiville
Little Miami R.
near Spring Valley
Mad R. near Dayton
Mahoning R.atOH.-
PA. State Line
below Lowellville
Maumee R. at
Defiance
Maumee R. at
Mouth at Toledo
Maumee R. at
Waterville
Muskingham R. at
McConnelsville
Ohio R. at West End
(Cincinnati)^
Ohio R. at
Andersons Ferryt
Portage R. at
Woodville
Sandusky R. near
Freerrtont
Sandusky R. near
Upper Sandusky
Scioto R. at
Chillicothe
Scioto R. below
Shadeville
Agency
GS

GS

GS
GS


GS

GS

GS

GS

R02

R02

GS

GS

GS

GS

GS

Lat.
391238

393500

394750
410153


411643

414136

413000

393842

Long.
841733

840149

840519
803110


842307

832820

834246

815100

None Published


None Published

412658

412212

405102

392029

394737


832129

830610

831523

82581,6

830040

. , Primary
_. _ „ ... . . Water discharge . Distance to
Site Established ., ., , raln . / ,
available? ram gage (mi)
gage
Stream

Stream

Stream
Stream


Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

Stream

1970

1968

1961
1967


1966

1967

1950

1950

1961

1961

1971

1970

1965

1950

1965

Yes

Yes

Yes
Yes


Yes

Yes

Yes

Yes

No

No

Yes

Yes

Yes

Yes

Yes

Cincinnati

Dayton

Dayton
Youngstown


Toledo

Toledo

Toledo

Parkersburg,
WV
Cincinnati

Cincinnati

— .

—

Mansfield

Columbus

Columbus

15

15

10
10


50

5

25

35

10

10

_

_

40

40

5

Applicability
to study
code
3

3

3
1


4

1

3

4

1

1

3

3

4

1

1

                                          (continued)

-------
                                             TABLE B-1 (continued).
N>
Ul
State
Ohio
(continued)
Oregon







Pennsylvania
















Station name
Tuscarawas R. at
Navarre
S. Umpqua R. near
Brockway
Willamette R. at
Portland*
Willamette R, at
Oregon City*
Willamette R. above
Oregon City*
Allegheny R. at
Oakmont*
Beaver R. at
Beaver Falls*
Delaware R. at
Bristol
Delaware R. at
Chester
Delaware R. at
Easton
Delaware R. at
Torresdale Ints1--
Kiskiminetas R. at
Vandergrift*
Monongahela R. at
S. Pittsburgh*
Lehigh R. at Easton
Agency
GS

GS

EPA

EPA

EPA

R02

R02

GS

GS

GS

GS

R02

R02

GS
Lat.
404336

431320

453349

452154

452030

Long.
813147

1232445

1224317

1223603

1223733

None Published

4048

400455

395012

404243

400157

403620

402436

404112

8019

745158

752200

751148

745946

793315

795715

751232
Site Established
Stream

Stream

Stream

Stream

Stream

Stream

Stream

Estuary

Esutary

Stream

Stream

Stream

Stream

Stream
1970

1970

1962

1968

1968

1962

1961

1949

1961

1947

1949

_

-

1961
Primary
Water discharge . Distance to
available? rain gage (mi)
gage
Yes

Yes

Yes

Yes

Yes

Yes

No

Yes

Yes

Yes

Yes

No

Yes

Yes
_

Eugene

Portland

Portland

Portland

Pittsburgh

Pittsburgh

Trenton

Philadelphia

Allentown

Philadelphia

Pittsburgh

Pittsburgh

Allentown
_

60

5

20

20

15

40

10

20

15

10

30

10

15
Applicability
to study
code
3

4

1

4

4

3

4

3

2

3

2

4

1

3
                                                                                         (continued)

-------
TABLE B-1 (continued).
State Station name
Pennsylvania Schuylkill R. at
(Continued) Philadelphia
W. Br. Brandywine
Cr. at Modena
Tennessee W. Fork Stones R.
at Manson Park
Texas Trinity R. below
Dallas
Virginia N. Fork Holston R.
near Gate Cityt
[ 	 i Washington Green-Duwamish R.
I\J Station 307
O1
West Ohio R. at
Virginia Huntington^
Wisconsin Fox R. at Menasha
Fox R. at Appleton
Fox R. at Rapide
Croche
Fox R. at DePere
Fox R. at Green
Bay
Wisconsin R. at
Wasau
Agency
GS

GS

GS

GS

EPA

EPA


R02

WDNR
WDNR
WDNR

WDNR
WDNR

WDNR

Lat.
395800

395742

355125

324227

363631

Long.
751120

754806

862443

964408

823405

None Published


3825

441151
441517


442653
443129

445725



8225

882653
882443


880402
880026

893808

Site
Stream

Stream

Stream

Stream

Stream

Stream


Stream

Stream
Stream
Stream

Stream
Stream

Stream

Established
1945

1974

1973

1967

1969

1969


1961

1971
1971
1971

1971
1971

1971

Water discharge
available?
Yes

Yes

Yes

Yes

Yes

Yes


Yes

Yes
Yes
Yes

Yes
Yes

Yes

Primary
rain
gage
Philadelphia

_

Nashville

Dallas

Bristol, TN.

_


Huntington

Green Bay
Green Bay
-

Green Bay
Green Bay

Green' Bay

Distance to
rain gage (mi)
10

_

25

20

25

	


5

30
25
-

5
5

90

Applicability
to study
code
1

4

4

1

4

_


1

4
4
4

3
1

4

                                               (continued)

-------
TABLE B-1 (continued).
State

Wisconsin
(continued)








Station name

Wisconsin at
Moisinee
Wisconsin at
Dubay Dam
Wisconsin at
Biron
Wisconsin at Port
Edwards
Wisconsin at
Petenwell
Agency Lat.

WDNR

WDNR 442450

WDNR

WDNR 442552

WDNR

Long. Site

— Stream

895121 Stream

— Stream

894647 Stream

— Stream

Established

1971

1971

1971

1971

1971

Water discharge
available?

Yes

Yes

Yes

Yes

Yes

Primary _.
Distance to
ram . , ..
ram gogc (mi)
gage
£treen Bay —

Green Bay 90

Green Bay —

Green Bay 90

Green Bay —

Applicability
to study
code
	

4

-

4

_


-------
                           APE-ENDIX C

             RESULTS OF DAILY CORRELATION ANALYSIS
      This appendix contains the results of all the daily corre-
lation analyses for both flow and rainfall. Table C-l contains
the results of flow correlation analysis at USGS monitor sites.
Table C-2 contains the results of flow correlation analyses for
STORET data base monitors.  Table C-3 contains the results of the
flow correlation analyses for the WDNR monitor sites. Table C-4
contains the results of daily rainfall correlation analysis at
the USGS monitor sites.

      In the following tables the stations are grouped by state.
The states are in alphabetical order and the stations in a group
are alphabetized. Three types of statistics are included in each
table.  These are the probability of a worse than average dissolv-
ed oxygen deficit,  the strength of the deficit, and the average
percent saturation which occurs when the dissolved oxygen def-
icit is worse than average.  The three types of statistics answer
the following six questions  about a given monitor site:

      •  What is the probability at this station that a worse-
         than-average (seven-day moving)  DO deficit will occur
         on a wetter-than-average (seven-day moving)  day?

      •  What is the probability at this station that a worse-
         than-average (seven-day moving)  DO deficit will occur
         on a dryer-than-average (seven-day moving)  day?

      »  If the DO deficit on a particular wetter-than-average
         day is worse than average,  how much worse is it?

      *  If the DO deficit on a particular dryer-than-average
         day is worse than average,  how much worse it it?

      •  On wetter-than-average days when the DO deficit is
         worse than average, what percentage of saturation is
         present?

      •  On dryer-than-average days when the DO deficit is worse
         than average, what  percentage of saturation is present?
                               128

-------
                TABLE C-1. USGS MONITOR SITE SUMMARY OF DAILY FLOW CORRELATION ANALYSIS RESULTS
to
Monitor site*
ALABAMA
Coosa R. near Verbena
(at Jordan Dam near
Wetumbwa)
LOUISIANA
Bayou Teche at Olivier
(at Keystone Lock near
St. Martinsville)
Houma Nav. Canal at
Dulac
Quachita R. at Monroe



MASSACHUSETTS
Blackstone R. at MUlville



Water
Year
(19-)

74
75


72-
74
75
74<
75
69
70
71
72

69
70
71
72
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

- ABORTED
.44


- ABORTED

.52
- ABORTED

.45
.50
.51
.38

- ABORTED
.43
.48
.48

—
.60


—

.53
—

.60
.53
.46
.46

—
.65
.65
.63
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

—
1.16


—

1.15
—

1.39
1.19
1.28
1.28

—
1.09
1.06
1.15
Dryer than
avg. days

—
1.46


—

1.18
—

1.35
1.21
1.33
1.36

_
1.11
1.11
1.09
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

—
.62


—

.24
—

.29
.42
.35
.33

_
.45
.44
.62
Dryer than
avg. days

—
.72


-

.31
—

.47
.33
.38
.43

—
.49
.45
.55
      "Stations are grouped by state, states are in aiphadettcal order, stations are alphabetized within group; ABORTED indicates that less than 180 days of data were available that
      year.
                                                                                                                          (continued)

-------
                                                  TABLE C-1 (CONTINUED).
h-
OJ
O
Monitor site
MASSACHUSETTS (continued)
Connecticut R. at W.
Springfield (Thompsonville)


Hoosic R. below
Williamstown

Merrimack R. at W.
IMewbury



North Nashau R. near
Lancaster (Leominster)



Quinebaug R. near Dudley
(at Quinebaug CN.)


Westfield R. at Westfield


Water
Year
(19-)

72
73
74
75
73
74
75
72
73
74
75
76
68
69
70
71
72
69
70
71
72
72
73
74
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

- ABORTED
.46
.43
.41
- ABORTED
.46
- ABORTED
.46
- ABORTED
.44
.46
.47
ABORTED
.55
.63
.47
.32
.38
.33
.47
.39
- ABORTED
.46
.52

—
.60
.60
.61
—
.58
-
.57
—
.65
.52
.45
—
.58
.50
.52
.69
.61
.52
.67
.66
—
.51
.47
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

—
1.76
1.27
1.21
—
1.37
-
1.63
-
1.52
1.50
1.09
—
1.14
1.17
1.14
1.20
1.38
2.14
1.68
1.28
—
1.42
1.30
Dryer than
avg. days

—
2.86
1.25
1.25
—
1.26
-
1.54
—
1.49
2.48
1.13
—
1.13
1.17
1.12
1.13
1.48
1.79
1.50
1.24
—
2.46
1.26
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

—
.72
.81
.81
_
.64
-
.74
—
.55
.63
.63
_
.48
.53
.48
.66
.83
.88
.74
.70
—
.76
.79
Dryer than
avg. days

—
.80
.79
.82
_
.60
-
.74
—
.67
.72
.61
—
.53
.62
.57
.59
.74
.83
.67
.71
—
.75
.80
                                                                                                               (continued)

-------
TABLE C-1 (CONTINUED).
Monitor site
Water
Year
(19-)
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
Dryer than
avg. days
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
Dryer than
avg. days
MASSACHUSETTS (continued)
Westfield R. at Westfield

MISSISSIPPI
Yellow Cr. near Doskie


MAINE
Vermillion R. near Empire

MISSOURI
Center Cr. near Carterville




James R. near Boaz




Wilsons Cr. near
Battlefield
75
76

73
74
75

74
75

72
73
74
75
76
72
73
74
75
76
73
74
.62
.30

- ABORTED
.58
- ABORTED

- ABORTED
- ABORTED

.53
- ABORTED
.49
.43
- ABORTED
- ABORTED
.44
.40
.43
.44
.36
.51
.48
.48

—
.50
-

-
—

.52
—
.56
.58
-
—
.58
.64
.62
.57
.63
.61
1.69
1.68

-
2.16
—

-
—

1.68
—
1.12
1.10
-
—
1.14
1.11
1.11
1.09
1.06
1.06
2.65
1.79

—
2.80
—

-
—

1.71
—
1.11
1.16
-
_
1.13
1.14
1.11
1.11
1.10
1.10
.78
.89

-
.74
—

-
—

.59
—
.58
.46
-
—
.53
.42
.32
.18
.09
.06
.88
.82

—
.76
—

-
—

.57
—
.61
.56
-
—
.59
.50
.48
.31
.13
.10
                                                           (continued)

-------
                                                TABLE C-1 (CONTINUED).
CO
N>
Monitor site
MISSOURI (CONTINUED)
Wilsons Cr. near
Battlefield (continued)
Wilsons Cr. near
Springfield



NEW JERSEY
Delaware R. at
Trenton



Manasquan R. at Squankum
(This station later abandoned
for lack of urban area. It
is near a swamp.)

Passaic R. at Two Bridges


Raritan R. near South Bound
Brook (below Callo Dam at
Water
Year
(19-)

75
76
72
73
74
75
76

72
73
74
75
76
70
71
72
73
74
72
73
74
74
75
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.53
.57
- ABORTED
.70
.54
.81
.77

.58
.64
.44
.61
.51
.52
.61
.66
.55
.48
.48
.34
- ABORTED
- ABORTED
.60

.57
.54
_
.42
.48
.39
.44

.49
.45
.47
.40
.51
.48
.58
.52
.44
.52
.69
.66
-
—
.37
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.10
1.04
_
1.27
1.30
1.27
1.28

2.12
1.83
2.75
2.79
4.71
1.20
1.12
1.22
1.16
1.26
1.07
1.12
-
—
1.60
Dryer than
avg. days

1.09
1.05
	
1.20
1.18
1.16
1.14

4.60
6.66
2.74
3.73
3.66
1.16
1.13
1.11
1.13
1.22
1.09
1.21
-
	
1.65
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.10
.02
	
.60
.58
.56
.58

.85
.85
.89
.91
.91
.52
.51
.50
.68
.67
.52
.48
-
	
.72
Dryer than
avg. days

.16
.04
	
.64
.64
.69
.65

.87
.93
.91
.96
.97
.56
.55
.56
.71
.70
.42
.50
—
_
.80
      Boundbrook)
                                                                                                          (continued)

-------
                                              TABLE C-1 (CONTINUED).
OL)
LO
Monitor site
OHIO
Ashtabula R. at Ashtabula




Black R. at Elyria




Black Fork at
Loudonville



Blanchard R. near Findlay




Cuyahoga R. at
Independence



Water
Year
(19--)

72
73
74
75
76
70
71
72
73
74
72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.44
.52
.42
.63
.58
- ABORTED
- ABORTED
- ABORTED
.54
.49
.57
.48
.52
.47
.56
.55
.53
.47
.49
.41
.39
.54
.52
.42
.56

.54
.47
.57
.49
.50
—
—
—
.52
.53
.45
.51
.46
.50
.45
.39
.55
.59
.52
.60
.58
.48
.56
.53
.47
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.29
1.40
1.50
1.23
1.25
—
—
—
1.81
1.43
2.59
?
1.24
1.21
1.22
2.96
1.19
1.14
1.18
1.23
1.23
1.24
1.15
1.22
1.24
Dryer than
avg. days

1.35
2.02
1.32
1.21
1.21
—
=-
—
1.47
1.61
1.27
1.49
1.12
1.12
1.12
.67
.26
.11
.16
.19
1.16
1.24
1.15
1.21
1.14
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.72
.76
.76
.64
.68
—
—
—
.57
.57
.60
.71
.67
.67
.67
.61
.63
.42
.47
.50
.69
.70
.62
.69
.71
Dryer than
avg. days

.67
.78
.72
.72
.69
—
—
—
.63
.54
.65
.73
.68
.74
.72
.69
.60
.44
.55
.61
.62
.72
.65
.74
.75
                                                                                                      (continued)

-------
TABLE C-1 (CONTINUED).
Monitor site
OHIO (continued)
Cuyahoga R. at Old Portage




Cuyahoga R. at W. 3rd St.
Bridge



Grand R. near Painesville

Hocking R. below Athens




Huron R. below Milan





Water
Year
(19-)

72
73
74
75
76
72
73
74
75
76
75
76
72
73
74
75
76
70
71
72
73
74
75
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.45
.37
.39
.47
.41
.47
.44
.43
.41
.45
.45
.34
.46
.50
.42
.57
.67
- ABORTED
.49
.43
.41
.57
.50

.51
.63
.58
.49
.61
.54
.54
.59
.51
.52
.67
.63
.55
.46
.55
.60
.45
—
.52
.37
.54
.45
.49
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

2.27
1.47
1.24
1.36
1.25
1.14
1.10
1.09
1.13
1.17
1.16
1.26
2.02
1.74
1.39
1.33
1.44
—
1.54
3.33
2.21
1.49
1.76
Dryer than
avg. days

1.18
3.33
1.35
1.28
1.22
1.21
1.11
1.09
1.12
1.13
1.18
1.56
1.33
1.60
1.34
1.31
1.40
—
1.51
3.14
5.60
1.50
2.24
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.63
.72
.75
.58
.63
.41
.45
.38
.43
.38
.72
.63
.65
.82
.84
.79
.84
__
.70
.81
.87
.77
.67
Dryer than
avg. days

.67
.76
.75
.74
.74
.35
.37
.37
.41
.39
.68
.67
.64
.82
.84
.82
.86
	
.78
.83
.80
.79
.72
                                                      (continued)

-------
TABLE C-1 (CONTINUED).
Monitor site
OHIO (continued)
Little Miami R. at
Miamiville (Milford)


Little Miami R. near
Spring Valley



Mad R. near Dayton




Mahoning R. at OH.-PA.
State Line (Lowellville)


Maumee R. at Defiance




Water
Year
(19-)

71
72
73
74
72
73
74
75
76
72
73
74
75
76
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than
avg. days

.59
.57
.66
.67
.58
.49
.65
.67
.59
.63
.50
.49
.56
.50
.50
.38
.48
.39
.51
.66
.56
.60
.55
Dryer than
avg. days

.47
.37
.40
.37
.42
.40
.43
.45
.39
.47
.45
.52
.48
.54
.54
.58
.54
.56
.42
.41
.44
.38
.42
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.51
1.85
1.61
1.56
1.17
1.49
1.33
1.18
1.23
1.25
1.31
1.19
1.23
1.16
1.16
1.15
1.10
1.22
1.94
1.37
2.38
7.64
4.92
Dryer than
avg. days

2.07
2.37
2.01
1.42
.15
.30
.18
.14
.13
.13
.19
1.13
1.19
1.19
1.29
1.13
1.09
1.14
1.44
1.29
3.22
1.77
11.23
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.68
.84
.83
.84
.62
.68
.73
.72
.63
.71
.76
.73
.73
.65
.53
.54
.51
.47
.74
.72
.63
.77
.78
Dryer than
avg. days

.71
.81
.85
.86
.64
.71
.74
.76
.67
.71
.79
.72
.75
.71
.53
.52
.57
.54
.77
.67
.71
.76
.83
                                                              (continued)

-------
TABLE C-1 (CONTINUED).
Monitor site
OHIO (continued)
Maume R. at Mouth
at Toledo


Maumee R. at
Waterville


Muskingum R. at
McConnelsville


Portage R. at
Woodville



Sandusky R. near
Fremont




Water
Year
(19-)
69-
70
71
72
69
70
71
72
73
74
75
76
71
72
73
74
75
70
71
72
73
74
75
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days
- ABORTED

.53
.49
.42
- ABORTED
- ABORTED
.58
- ABORTED
.57
.54
.45
- ABORTED

.60
.54
.68
.52
.52
.53
.45
.42
.47


.52
.52
.61
—
—
.49
—
.43
.43
.44
-

.44
.46
.40
.64
.54
.47
.68
.53
.48
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days


6.65
1.34
11.76
—
—
1.45
—
1.56
1.69
1.87
-

1.43
1.32
1.76
1.33
1.19
5.14
1.45
1.65
1.34
Dryer than
avg. days


1.41
1.65
3.25
—
—
1.63
—
1.62
2.57
3.50
—

1.75
2.25
1.72
1.28
1.22
2.48
9.71
2.61
1.26
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days


.38
.46
.79
—
—
.55
—
.80
.85
.81
—

.56
.64
.77
.52
.44
.65
.68
.63
.59
Dryer than
avg. days


.44
.59
.70
—
—
.64
—
.77
.85
.81
—

.62
.63
.83
.53
.60
.67
.65
.60
.75
                                                            (continued)

-------
                                                 TABLE C-1 (CONTINUED).
U)
-j
Monitor site
OHIO (continued)
Sandusky R. near
Upper Sandusky



Scioto R. at
Chill icothe



Scioto R. below
Shadeville



Tuscarawas R. at
Navarre (Massillion)




Water
Year
(19-)

72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
70
71
72
73
74
75
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.52
.60
.57
.54
.64
.64
.52
.52
.54
.58
.39
.31
.40
.56
.49
- ABORTED
.54
.50
.43
.40
.40

.47
.46
.49
.46
.46
.48
.59
.50
.48
.40
.60
.67
.63
.60
.55
—
.55
.54
.61
.64
.56
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

2.03
1.58
—
2.67
1.34
1.21
1.19
1.19
1.21
2.19
1.23
1.16
1.12
1.16
1.14
_
1.09
1.12
1.12
1.06
1.08
Dryer than
avg. days

4.47
1.87
1.81
1.57
1.27
1.15
1.15
1.11
1.16
1.23
1.25
1.20
1.13
1.12
1.16
	
1.08
1.10
1.11
1.09
1.11
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.78
.83
.71
.69
.71
.41
.59
.47
.43
.51
.42
.58
.48
.43
.51
	
.17
.29
.41
.40
.45
Dryer than
avg. days

.80
.76
.70
.75
.74
.51
.65
.52
.60
.61
.54
.58
.46
.48
.59
_
.28
.26
.41
.32
.39
                                                                                                           (continued)

-------
                                                 TABLE C-1 (CONTINUED).
UJ
CO
Monitor site
OREGON
South Umpqua near
Brockway



PENNSYLVANIA
Delaware R. at
Bristol



Delaware R. at
Chester



Delaware R. at
Easton



Water
Year
(19--)

72
73
74
75
76

72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.57
.56
.33
.49
.63

.51
.56
.50
.71
- ABORTED
.49
.67
.52
.35
.57
- ABORTED
- ABORTED
- ABORTED
.50
.44

.42
.47
.48
.49
.55

.53
.45
.61
.43
-
.62
.65
.73
.77
.54
—
—
—
.60
.49
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

3.25
1.79
3.57
2.98
3.82

1.21
1.95
1.69
1.33
-
.05
.13
.04
.07
.07
—
—
—
1.53
2.33
Dryer than
avg. days

1.91
12.68
1.94
1.69
2.30

1.22
1.67
2.00
1.24
-
1.07
1.61
1.06
1.07
1.07
_
—
—
2.62
1.83
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.84
.83
.96
.87
.82

.72
.77
.69
.84
-
.31
.36
.31
.37
.36
—
—
—
.85
.86
Dryer than
avg. days

.88
.87
.82
.81
.83

.68
.79
.65
.84
-
.28
.42
.33
.42
.42
	
—
—
.86
.92
                                                                                                            (continued)

-------
                                                TABLE C-1 (CONTINUED).
U)
Monitor site
PENNSYLVANIA
(continued)
Delaware R. at Torresdale
Intake, Philadelphia

Lehigh R. at Easton
(Glendon)



Schuylkill R. at
Philadelphia


West Br. Brandywine
Cr. at Modena


TENNESSEE
W.F. Stones R. at Manson
Pk., at Murpheesboro


TEXAS
Trinity R. below Dallas
Water
Year
(19-)
72
73
74
75
76
72
73
74
75
76
69
70
71
72
71
72
73
74

73
74
75
76

77
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days
.46
.49
.50
.44
.41
.53
.46
.39
.37
.50
.43
.48
.39
.61
- ABORTED
.44
.58
.53

- ABORTED
- ABORTED
.52
- ABORTED

.60
.52
.53
.49
.55
.62
.58
.55
.63
.60
.55
.54
.55
.58
.55
—
.49
.53
.49

—
-
.53
—

.52
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
1.24
1.63
1.17
1.25
1.19
1.28
1.71
1.44
1.50
2.85
1.25
1.42
1.45
1.24
—
1.58
1.32
1.40

—
—
1.71
-

1.13
Dryer than
avg. days
1.30
1.30
1.18
1.37
1.58
1.55
1.48
4.43
1.30
1.24
1.47
2.26
1.60
1.53
—
2.41
1.76
1.46

—
—
2.29
-

1.14
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
.72
.58
.54
.59
.67
.71
.83
.77
.80
.79
.66
.66
.68
.76
—
.83
.84
.69

—
—
.85
-

.28
Dryer than
avg. days
.70
.58
.52
.67
.74
.78
.82
.75
.77
.83
.72
.68
.71
.79
—
.83
.81
.62

_
—
.86
-

.26

-------
                                         TABLE C-2. STORE! DATA BASE MONITOR SITES
                                  SUMMARY OF DAILY FLOW CORRELATION ANALYSIS RESULTS
>£>
O
Monitor site*
ALABAMA
Coosa R. at Gadson
Coosa R. Left Side





COLORADO
S. Platte R. at Denver
Sand C. Birlington
Ditch MDSDD # 1






S. Platte R. at Denver
S. Platte R. at 88th Ave.
MDSDD # 1




Water
Year
(19-)

71
72
73
74
75
76
77

67
70
71
72
73
74
75
76
77
69
70
71
72
73
74
75
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.58
.49
.47
.46
.56
.41
- ABORTED

- ABORTED
.53
.55
.52
.51
.47
.50
.50
.41
- ABORTED
.46
.51
.57
.51
.35
.52

.51
.41
.51
.52
.40
.43
—

—
.48
.45
.50
.47
.53
.42
.56
.40
—
.51
.47
.55
.52
.65
.54
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.82
1.72
1.63
1.34
1.27
1.40
—

—
1.17
1.25
1.63
1.51
1.22
1.52
1.61
1.93
—
.09
.19
.17
.20
.09
.15
Dryer than
avg. days

1.56
2.00
1.70
1.31
1.34
1.49
—

—
1.13
1.21
1.41
1.40
1.26
1.30
1.79
1.85
—
1.11
1.16
1.14
1.14
1.12
1.18
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.88
.86
.82
.77
.73
.78
-

—
.64
.68
.77
.79
.70
.84
.78
.89
_
.57
.68
.68
.70
.69
.67
Dryer than
avg. days

.83
.88
.85
.78
.74
.79
-

—
.66
.70
.79
.76
.72
.81
.84
.84
	
.57
.68
.67
.69
.79
.68
     •StBtlora are grouped by state, states are in alphabetical order, stations are alphabetized within group; ABORTED indicates that less than 180 days of data were available that
     year.
                                                                                                                     (continued)

-------
TABLE C-2 (CONTINUED).
Monitor site
COLORADO (continued)
S. Platte, 88 Ave. (cont.)
S. Platte R. at Denver
Burlington Ditch at York
St. MDSDD #1






Flow-S. Plane at Denver
S. Platte #60 Ave.
MDSDD #1







GEORGIA
Chattahoochee R. at
Atlanta
Water
Year
(19--)
76
77
67
68
69
70
71
72
73
74
75
68
69
70
71
72
73
74
75
76
77

67-
68
Probability of greater
than average DO deficit
Wetter than
avg. days
.51
.50
.48
.51
.48
.49
.60
.52
.53
.37
.40
.56
Dryer than
avg. days
.40
.52
.46
.46
.57
.44
.44
.55
.56
.60
.46
.58
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
1.29
1.26
1.17
1.47
1.09
1.14
1.35
1.28
1.14
1.09
1.13
1.29
Dryer than
avg. days
1.21
1.24
1.21
1.11
1.08
1.13
1.30
1.20
1.15
1.10
1.10
1.09
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
.63
.62
.35
.65
.56
.67
.72
.67
.66
.68
.66
.60
Dryer than
avg. days
.67
.61
.44
.64
.55
.69
.72
.66
.67
.63
.68
.65
ABORTED -----
.49
.57
.51
.47
.38
.42
.66
.53

- ABORTED

.48
.47
.54
.53
.56
.52
.44
.51

— highly

1.15
1.30
1.26
.17
.14
.28
.21
.31

intermittent data

1.14
1.28
1.23
1.20
1.19
1.14
1.28
1.28

-

.65
.75
.72
.73
.74
.76
.61
.60

—

.68
.74
.69
.73
.71
.77
.70
.60

—

                                                             (continued)

-------
TABLE C-2 (CONTINUED).
Monitor site
NORTH CAROLINA
Cape Fear R. at Lock #1
near Kelly, Cape Fear R. at
Channel Marker #50
Muddy Cr. near Muddy Cr.
500 below efficient discharge
Muddy Cr. near Muddy Cr.
Muddy Cr. at SR 1485
i_, Muddy Cr. near Muddy Cr.
*• Muddy Cr. at SR 2991
NJ
Muddy Cr. near Muddy Cr.
NFK, Muddy Cr,
Roanoke R. at Roanoke Rapid
Roanoke R. 1 mi. upstream
of Welch Cr.
Neuse R. near Northside
Neuse R. at U.S. Hwy. 42
Neuse R. near Northside
Neuse R. at U.S. Hwy. 50
Neuse R. near Northside
Neuse R. at U.S. Hwy. 70
Neuse R. near Northside
Neuse R. at U.S. Hwy. 98
Water
Year
(19-)

74
75

74
75
74
75
74
75
74
75
74
75

75
76
75
76
75
76
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

—
.52

.69
.64
—
.49
.50
.53
—
.51
.55
.49

—
-
—
-
—
-
—
—

ABORTED




ABORTED



ABORTED




ABORTED
ABORTED
ABORTED
ABORTED
ABORTED
ABORTED
ABORTED
ABORTED

—
.55

.45
.44
—
.45
.52
.54
—
.36
.74
.55

_
-
—
-
—
-
—
—
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

-
1.20

1.24
1.46
—
1.64
1.13
1.20
—
2.01
1.27
1.27

_
-
—
-
—
-
—
—
Dryer than
avg. days

—
1.20

1.38
1.38
—
1.75
1.24
1.14
—
1.86
1.26
1.19

—
-
—
-
—
-
—
—
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

—
.44

.73
.71
_
.75
.75
.73
—
.81
.68
.75

	
-
—
-
—
-
_
_
Dryer than
avg. days

—
.40

.68
.74
_
.79
.75
.64
—
.86
.68
.65

__
_
__ .
-
_
-
_
_
                                                       (continued)

-------
                                                     TABLE C-2 (CONTINUED).
                                                                                Strength of DO deficit               Average percentage of
                                              Probability of greater                when deficit is greater              saturation when deficit
     Monitor site               Water          than average DO deficit                   than average    	is worse than average
                               Year      Wetter than         Dryer than      Wetter than       Dryer than       Wetter than        Dryer than
                              (19--)       avg. days          avg. days        avg. days         avg. days         avg. days         avg. days

WASHINGTON
 Green R. at Tuckwilla           69-            -   ABORTED    -              -                -                -                -
 Green Duwamish R.             73
 Sta. 307

-------
TABLE C-3. WDNR MONITOR SITES SUMMARY OF DAILY FLOW CORRELATION ANALYSIS RESULTS
Monitor site
Fox R. at Menasha




Fox R. at Appleton




Fox R. at Rapide Croche




Fox R. at Depere




Fox R. at Green Bay

Water
Year
(19~)
73
74
75
76
77
73
74
75
76
77
73
74
75
76
77
73
74
75
76
77
73
74
Probability of greater
than average DO deficit
Wetter than
avg. days
.57
.47
.50
.46
.58
.54
.48
.42
.43
.52
.40
.41
.45
.46
.48
.53
.39
.47
.47
.46
.48
.41
Dryer than
avg. days
.39
.50
.48
.62
.47
.56
.45
.50
.50
.57
.60
.59
.59
.63
.59
.54
.56
.54
.59
.52
.58
.55
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
3.15
2.12
1.75
1.29
1.58
1.34
1.92
1.34
1.39
1.55
.69
.38
.28
.31
.29
1.80
1.51
2.51
1.28
1.39
1.26
1.34
Dryer than
avg. days
2.31
2.68
1.73
1.50
2.32
1.42
1.37
1.33
1.52
1.25
1.65
1.58
2.74
.14
.20
.45
.59
.67
.29
.48
1.59
1.31
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
.84
.87
.85
.82
.83
.73
.80
.81
.77
.78
.70
.71
.65
.62
.60
.75
.82
.75
.76
.69
.66
.74
Dryer than
avg. days
.87
.88
.87
.80
.86
.69
.74
.74
.77
.78
.61
.54
.60
.56
.60
.81
.78
.73
.72
.71
.56
.61
                                                                                   (continued)

-------
TABLE C-3 (CONTINUED).
Monitor site
Fox R. at Green Bay
(continued)

Wisconsin R. at Wausau




Wisconsin R. at Mosinee




Wisconsin R. at Dubay Dam




Wisconsin R. at Biron




Water
Year
(19-)
75
76
77
73
74
75
76
77
73
74
75
76
77
72
73
74
75
76
72
73
74
75
76
Probability
than average
Wetter than
avg. days
.44
.44
.56
.40
.56
.57
.45
.49
.40
.38
.47
.53
.44
.55
.52
.60
.58
.64
.48
.42
.64
.49
.50
of greater
DO deficit
Dryer than
avg. days
.59
.43
.49
.58
.63
.55
.57
.54
.66
.57
.58
.62
.61
.59
.60
.52
.55
.50
.68
.59
.46
.52
.54
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
1.29
1.14
1.17
1.12
1.18
1.14
1.15
1.19
1.20
1.06
1.12
1.06
1.09
1.10
1.11
1.08
1.13
1.08
1.13
1.24
1.48
1.18
1.14
Dryer than
avg. days
1.40
1.24
1.16
1.13
1.32
1.14
1.16
1.10
1.16
1.14
1.25
1.12
1.13
1.13
1.15
1.11
1.18
1.13
1.47
1.38
1.13
2.04
1.20
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
.66
.72
.57
.70
.71
.62
.54
.56
.51
.46
.40
.33
.40
.27
.52
.36
.47
.36
.46
.72
.60
.61
.50
Dryer than
avg. days
.56
.58
.60
.76
.71
.59
.55
.60
.54
.44
.38
.36
.52
.36
.56
.44
.49
.44
.56
.79
.62
.71
.64
                                                          (continued)

-------
                                     TABLE C-3 (CONTINUED).
Strength of DO deficit

Monitor site


Wisconsin R. at Port
Edwards


Wisconsin R. at Petenwell




Water
Year
(19-)
73
74
75
76
73
74
75
76
Probability
than average
Wetter than
avg. days
.42
.54
.44
.50
.60
.53
.54
.56
of greater
DO deficit
Dryer than
avg. days
.59
.59
.70
.54
.40
.45
.56
.61
when deficit is greater
than
Wetter than
avg. days
1.24
1.14
1.11
1.14
1.20
1.10
1.11
1.13
average
Dryer than
avg. days
1.38
1.42
1.24
1.20
1.16
1.21
1.12
1.14
Average percentage of
saturation when deficit
is worse than
Wetter than
avg. days
.72
.56
.49
.50
.56
.53
.34
.56
average
Dryer than
avg. days
.79
.61
.58
.64
.62
.43
.47
.60
en

-------
       TABLE C-4.  USGS MONITOR SITES SUMMARY OF DAILY RAINFALL CORRELATION ANALYSIS RESULTS
Monitor site*
MASSACHUSETTS
Connecticut R.at W.
Springfield (Thompsonville)


Chicopee R. at Chicopee
Falls

Westfield R. at Westfield




MISSOURI
Center Cr. near Carterville




James R. near Boaz




Water
Year
(19--)

72
73
74
75
73
74
75
72
73
74
75
76

72
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

- ABORTED
.60
.66
.63
- ABORTED
.59
.56
- ABORTED
.56
.59
.63
.38

.58
- ABORTED
.64
.65
- ABORTED
- ABORTED
.64
.64
.65
.63

—
.52
.47
.47
_
.60
.58
—
.46
.45
.45
.45

.50
—
.49
.50
-
_
.47
.54
.53
.52
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

—
1.67
1.32
1.26
—
1.30
1.36
—
1.41
1.27
2.13
1.64

1.67
—
1.14
1.14
-
—
1.14
1.13
1.14
1.11
Dryer than
avg. days

—
2.98
1.21
1.23
—
1.16
1.23
—
2.49
1.28
2.46
1.84

1.71
—
1.10
1.15
-
	
1.12
1.13
1.09
1.11
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

—
.80
.78
.81
—
.56
.41
	
.74
.78
.81
.86

.62
_
.59
.54
-
	
.57
.49
.44
.30
Dryer than
avg. days

—
.76
.81
.83
—
.45
.39
	
.76
.80
.87
.82

.55
—
.62
.54
—
__
.58
.48
.45
.28
'Stations are grouped by state, states are in alphabetical order, stations are alphabetized within group; ABORTED indicates that
 year.
; than 180 days of data were available that

                  (continued)

-------
TABLE C-4 (CONTINUED).
Monitor site
MISSOURI
(continued)
Wilsons Cr. near Battlefield



Wilsons Cr. near
Springfield



NEW JERSEY
Delaware R. at Trenton




OHIO
Ashtabula R. at Ashtabula




Water
Year
(19-)


73
74
75
76
72
73
74
75
76

72
73
74
75
76

72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days


.55
.63
.62
.63
- ABORTED
.58
.56
.67
.77

.62
.57
.47
.52
.51

.51
.58
.56
.63
.67


.55
.56
.53
.52
—
.45
.46
.38
.43

.46
.50
.46
.44
.51

.51
.41
.47
.45
-42
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days


1.11
1.08
1.12
1.06
—
1,21
1.24
1.26
1.24

1.79
2.14
2.05
4.66
2.91

1.29
1.51
1.41
1.24
1.22
Dryer than
avg. days


1.09
1.10
1.08
1.05
—
1.23
1.18
1.15
1.16

5.35
5.76
3.07
2.53
4.58

1.35
2.13
1.34
1.18
1.24
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days


.12
.09
.14
.03
—
.61
.59
•§1
.61

,86
.87
.90
.92
.96

.71
.77
.75
.70
.69
Dryer than
avg. days


.13
.10
.14
.04
—
.64
.64
.68
.64

.87
.90
.90
.95
.95

.67
•77
.72
.68
-68
                                                       (continued)

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TABLE C-4 (CONTINUED).
Monitor site
OHIO (continued)
Black R. at Elyria



Blanchard R. near Findlay




Cuyahoga R. at
Independence



Cuyahoga R. at Old
Portage



Cuyahoga R. at W. 3rd St.
Bridge



Water
Year
(19-)
70
71
72
73
74
72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than
avg. days
Dryer than
avg. days
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days
Dryer than
avg. days
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days
Dryer than
avg. days
- ABORTED _____
- ABORTED -
- ABORTED _____
.55
.52
.58
.65
.59
.62
.64
.50
.60
.52
.57
.56
.55
.57
.56
.58
.66
.59
.57
.55
.51
.53
.50
.52
.57
.48
.52
.44
.49
.54
.41
.49
.43
.39
.42
.48
.43
.38
.44
.45
.46
.52
.45
.47
1.55
1.51
1.79
1.29
1.14
1.17
1.22
1.20
1.25
1.15
1.24
1.20
1.71
1.63
1.30
1.31
1.27
1.20
1.12
1.10
1.14
1.15
1.64
1.58
2.65
1.20
1.10
1.16
1.19
1.16
1.22
1.15
1.17
1.14
1.40
4.14
1.34
1.31
1.19
1.17
1.09
1.09
1.12
1.14
.68
.59
.65
.65
.44
.50
.57
.66
.72
.67
.74
.74
.66
.74
.75
.68
.67
.41
.42
.43
.48
.42
.53
.51
.67
.58
.43
.55
.59
.61
.70
.62
.70
.74
.66
.76
.76
.68
.75
.31
.35
.31
.34
.36
                                                       (continued)

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TABLE C-4 (CONTINUED).
Monitor site
OHIO (continued)
Grand R. near Painesville

Grand R. at Painesville


Little Miami R. at
Miamiville (Milford)


Little Miami R. near
Spring Valley



Mad R. near Dayton




Mahoning R. at OH.-PA.
State Line below
Lowellville


Water
Year
(19-)

75
76
72
73
74
71
72
73
74
72
73
74
75
76
72
73
74
75
76
72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.60
.54
.46
.54
.46
- ABORTED
.41
.56
.53
.59
.53
.60
.61
.58
.66
.64
.60
.63
.65
.49
.56
.51
.59
.60

.59
.49
.51
.49
.48
—
.44
.42
.43
.37
.36
.43
.43
.38
.43
.34
.45
.41
.45
.50
.50
.49
.45
.44
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.19
1.70
1.45
1.45
1.23
—
2.32
1.50
1.47
1.17
1.31
1.27
1.17
1.19
1.20
1.26
1.17
1.20
1.21
1.15
1.17
1.16
1.09
1.18
Dryer than
avg. days

1.16
1.31
2.10
1.37
1.23
	
2.08
2.22
1.49
1.13
1.43
1.21
1.14
1.16
1.14
1.14
1.13
1.20
1.15
1.16
1.32
1.12
1.10
1.14
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.72
.69
.79
.81
.71
	
.85
.85
.83
.65
.70
.73
.74
.65
.72
.78
.73
.74
.68
.42
.53
.56
.57
.54
Dryer than
avg. days

.66
.64
.74
.68
.57
	
.81
.84
.86
.61
.70
.74
.75
.66
.70
.78
.72
.75
.70
.37
.52
.49
.52
.52
                                                         (continued)

-------
                                             TABLE C-4 (CONTINUED).
Ln
Monitor site
OHIO (continued)
Sandusky R. near Upper
Sandusky



Scioto R. at Chillicothe




OREGON
South Umpqua near
Brockway



PENNSYLVANIA
Lehigh R. at Easton
(Glendon)



Water
Year
(19-)

72
73
74
75
76
72
73
74
75
76

72
73
74
75
76

72
73
74
75
76
Probability of greater
than average DO deficit
Wetter than Dryer than
avg. days avg. days

.58
.56
.62
.62
.69
- ABORTED
- ABORTED
.53
.56
.60

.49
.51
.40
- ABORTED
- ABORTED

.67
.62
.57
.61
.65

.43
.47
.45
.41
.42
—
—
.49
.47
.39

.46
.42
.47
—
-

.51
.45
.54
.47
.47
Strength of DO deficit
when deficit is greater
than average
Wetter than
avg. days

1.89
1.84
1.77
1.38
1.40
—
—
1.14
1.20
2.15

1.85
15.62
3.07
—
-

1.35
1.50
1.52
1.37
1.42
Dryer than
avg. days

5.08
1.68
—
2.62
1.21
—
—
1.13
1.17
1.31

2.88
5.49
1.86
—
-

1.56
1.60
4.98
1.34
1.96
Average percentage of
saturation when deficit
is worse than average
Wetter than
avg. days

.74
.79
.71
.70
.71
—
—
.51
.48
.54

.90
.93
.95
—
-

.77
.83
.77
.77
.81
Dryer than
avg. days

.83
.78
.70
.74
.75
—
—
.52
.57
.58

.84
.84
.80
—
-

.76
.82
.75
.77
.83

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                          APPENDIX D

               RESULTS OF DETAILED SITE ANALYSES


     This appendix contains the results of the detailed site
analyses.  These analyses were performed at 30 sites where a 60
percent or greater probability existed of a high flow or rain-
fall event occurring at the same time as a low dissolved oxygen
event.  The sites are grouped by state.  The states are in alpha-
betical order within each state group.

     Each site analysis contains some or all of the following:

     9  water quality monitor site name;

     •  monitor location, latitude and longitude, agency
        I.D.  number;

     •  flow gage site name;

     •  flow location, latitude and longitude, agency
        I.D.  number;

     •  rain gage location, I.D. number;

     •  short summary of daily correlation results;

     •  assessment of record quality;

     •  discharge, drainage area and population description;

     •  Streeter-Phelps analysis results;

     «  conclusions and comments; and

     9  daily or hourly plots of data from years with
        positive correlation.

     Three types of illustrations are included in this appendix.
Streeter-Phelps analysis results are presented as plots of DO
deficit  (mg/1)  versus distance  (miles) downstream of the urban
area.  Two lines generally appear on each illustration.  The
lower line depicts the deficit due to "normal" flows and the
second line depicts the deficit due to "storm" flows.  The
                             152

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saturation DO level for typical conditions is also illustrated.
Important features such as the stream gage and DO monitor loca-
tion as well as sewage treatment facilities are identified.  The
second type of illustration is the hourly data analysis.  Two
separate graphs are included in each illustration.  The upper
graph illustrates absolute DO level and saturation DO level
(both in mg/1) versus time in days.  The lower graph presents
the stream flow, DO deficit, and rainfall. The flow line has
been normalized by dividing the actual flow values by the average
value for the entire period illustrated.  This preserves the
hydrograph shape and avoids rescaling the graph for every new
station.  The rainfall is shown as hourly histograms (vertical
rectangular bars).  The format of the illustrations allows fairly
easy visualization of the relationship between the several vari-
ables.  The final illustration type is the daily average value
plots.  These generally illustrate either flow in cubic feet per
second versus time in days or DO and DO deficit in mg/1 versus
time in days.
                               153

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STATE:  MASSACHUSETTS

Monitor Name;  Connecticut River at West Springfield
USGS I.D.:01 177 200  Latitude: 42 05 46  Longitude: 72 35 43

Stream Gage Name;  Connecticut River at Thompsonville, Conn.
USGS I.DTI01 184 OOP  Latitude: 41 59 14  Longitude 72 36 21

Rain Gage Name;  Springfield
Weather Bureau I.P.:  8046

Daily Data Analysis Results:  Water years 72-75 were examined.
   The probability of low dissolved oxygen with high flow
   averaged 40 percent.   The probability of low dissolved
   oxygen on days with rainfall was greater than 60 percent
   in 1973, 1974, and 1975.  Dissolved oxygen levels remained
   around the 75-80 percent of saturation level on days with
   rain.

Quality of Records;  The monitor is visited once a month or
   more.  Record is reliable except for two to three weeks
   each summer.

Discharge Characteristics:  Average flow 16,250 cfs, approx.
   range 1,000 to 100,000 cfs

Drainage Area at Monitor:  9,623 square miles

Urban Area(s) Contributing at Monitor:  Turners Falls,
   Northampton, Holyoke, Chicopee
   approximate population  (Almanac) 87,500

Approximate Urban Area Contributing at Monitor:  60 sq mi or
   less than 1 percent of total

Results of Streeter-Phelps Analysis:  Monitor is located
   satisfactorily for normal flows.  At high flows a location
   20 to 30 miles downstream would be better.  Storm flow
   could produce D.O. deficits of 4.5 mg/1 resulting in D.O.
   levels below 5 mg/1 during storm events.  There is some
   evidence of this on daily plots.  Simulation results
   follow in Figure D-l.

Hourly Data Analysis Results:  The period examined illustrates
   a mild tendency for the deficit to decrease slowly during
   the flow event.  Water quality is never very bad at this
   site.  The period of hourly data is illustrated in Figure
   D-2.
                               154

-------
Ln
01
                              15.0 _
                              10.0 .
                           O
                           u.
                           LU
                           Q

                           O
                           Q
                               5.0
                                0.0
                                       SAJURATK3NjAT^O c =_9.17jn&n_
                                       SATURATION AT_27^C_=_8.07_mg/l_
                                                                                             STORM
                                                                                              NORMAL
-T"
i
I
t
-*—
0
I
w
VIC
-1 — 1 — 1 1 1 • 1 — 1 — 1 — t — 1 — 1 — 1 — 1 — 1 — » — 1 — 1 — 1 — 1 — t — 1 — 1— — t — 1— 1 — 1
' | T20 30 40 50 6(
| DISTANCE, mi
1 FLOW GAGE
LONG MEADOW AND SUBURBS
WESTFIELD R.
.SPRINGFIELD
)NITOR
                                          SPRINGFIELD N. CHICOPEE R.
                                      HOLEYOKE
                                    SOUTH HADLEY
                             Figure D-1. Streeter-Phelps analysis results for Connecticut R. at West Springfield, MA.

-------
                               20 _
                          O"
                          o
                               10 ..
                                                  SATURATION DO LEVEL
U1
                          o
                          Q
                          HI

                          i
                          z

                          5
                               3.0 -
                               2.5 :,
                               2.0 ::
                                                                                   DISCHARGE / AVG. DISCHARGE
                                                                 4               6


                                                       TIME FROM START OF PERIOD, days
10
                                       Flgurt D-2. Hourly data for Connecticut R. at W. Springfield, MA.

                                                             (4/1774 to 4/10/74).

-------
Conclusions and Comments:  During June 1974, there appears
   to have been a period when the D.O. dropped drastically
   during a flow event.  The monitor quit during the most
   interesting time.  This site does not appear to have a
   water quality problem attributable to urban runoff.   It
   would be interesting, however, to put a monitor at the
   theoretical D.O. sag point and see what was observed
   then.
                             157

-------
STATE:   MASSACHUSETTS

Monitor Name:   North Nashua River near Lancaster
USGS I.P.; 01 094 700  Latitude:  42 28  47  Longitude: 71 41 04

Stream Gage Name:  North Nashua River near Leominster
USGS I.P.; 01 094 500  Latitude:  42 30  06  Longitude: 71 43 23

Rain Gage:  Fitchburg 4 SE
Weather Bureau I.P..:

Daily Data Analysis Results;  Water years 1968-72 were  examined.
   The probability of low dissolved oxygen with high flow
   exceeded 60 percent in 1970 and the summer of 1971.  Paily
   rainfall correlation was not run at this station.  Hourly
   rainfall data were used in the detailed analysis, however.
   Dissolved oxygen levels are definitely low, averaging
   less than 60 percent of saturation most of the time and
   falling to 40-50 percent during wet weather.

Quality of Records;  Monitor is visited once a month or more.
   Record is highly reliable for flow and good for the monitor
   except for short periods scattered throughout the year.

Discharge Characteristics:  Average flow approximately 175
   cfs, approx. range 50-1,000 cfs

Drainage Area at Monitor:  128 square miles

Urban Area(s) Contributing at Monitor:  Fitchburg, Leominster,
   approximate population:  43,300 and 33 ,000, respectively
                                                      . 2
Approximate Urban Area Contributing at Monitor:  11 mi
    (based on 7100/mi^)or 9 percent of total

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  The period examined had a
   definite tendency for the D.O. deficit to increase  at
   the beginning of a storm event.  The D.O. level dropped
   from an average of over 6 mg/1 to less than 5 and re-
   mained there  for one day.  The average D.O. level was
   definitely worse during the flow events examined.   The
   period of hourly data is illustrated in Figure D^3.
   The EPA suggested standard of 2.0 mg/1 for 4.0 hours
   was violated on the third and fourth days of the period
   examined.
                               158

-------
     20
o"
Q
     10 .
                            SATURATION DO LEVEL
                       DO LEVEL
•o
O
Q

C3
I


Q


>


UJ

c

I
O
                               DISCHARGE /AVG. DISCHARGE
                    PRECIPITATION, inches

                               DO DEFICIT/ 10, mg/l
                           6      8     10    12     14     16


                              TIME FROM START OF PERIOD, days
                                                                18
                                                                      20
                                                                             22     24
              Figure D-3. Hourly data for N. Nashua R. near Leominster, MA.
                                   (6/1770 to 6/25/70).

-------
Conclusions and Comments;   A definite  problem exists  here.
   The monitor is 5  miles  downstream of  the  Leominster
   Sewage Treatment  Plant.   It is  10 miles below the  town.
   This probably puts  it in an excellent position to  sense
   a D.O. sag.   It is  not  possible without detailed exami-
   nation of the site  to tell whether  the problem is  urban
   runoff, combined  sewer  overflows, sediment entrainment,
   or some other problem.
                           160

-------
STATE:   MASSACHUSETTS

Monitor Name:   Westfield River at West Springfield
USGS I.D.;   01 183 600  Latitude: 42 05 59  Longitude: 72 38 28

Stream Gage Name:  Westfield River near Westfield
USGS I.D.;   01 183 500  Latitude: 42 06 24  Longitude: 72 41 58

Rain Gage:   Springfield
Weather Bureau I.P.;  8046

Daily Data Analysis Results:  Water years 1972-76 were examined.
   The probability of low dissolved oxygen with high flow
   reached 62  percent in 1975.  The same year the probability
   of low D.O. on days with rainfall was 63 percent.  Dis-
   solved oxygen levels are not bad, running approximately
   75 percent saturation most of the time.

Quality of Records:  The monitor is visited once a month or
   more.  Flow records are excellent.  Monitor records are
   poor in the summer with entire months missing.

Discharge Characteristics:  Average flow approx. 940 cfs,
   approx.  range 100-13,000 cfs

Drainage Area at Monitor:  497 square miles

Urban Area(s)  Contributing to Monitor:  Pittsfield, Westfield,
   West Springfield
   approximate populations:  estimate 35-50,000

Approximate Urban Area Contributing at Monitor;  5 to 7  square
   miles or approximately 1 percent of total

Results of Streeter-Phelps Analysis:  Not performed at this
   site*

Hourly Data Analysis Results;  Hourly data could not be  ob-
   tained for this site.

Conclusions and Comments;  Examination of the daily record
   indicates a number of periods where the D.O. level appears
   to drop at the time of flow events.  The monitor is poorly
   located.  The "problem" may originate at Pittsfield which
   is 40 miles upstream.  A monitor closer to there might
   have detected more.  The water quality is generally good
   at this site.
                              161

-------
STATE:  MISSOURI

Monitor Name:  Center Creek near Carterville
USGS I.D.;   07 186 400  Latitude: 37 08 26  Longitude: 94 22 57

Stream Gage Name:  Same
USGS I.D.:   Same 	  Latitude: Same      Longitude: Same
Rain Gage:   Springfield
Weather Bureau I.P.;   8046

Daily Data Analysis Results:  Water years 1972-76 were  examined.
   The probability of low dissolved oxygen with high flow
   never exceeded 53 percent.  The probability of low dis-
   solved oxygen on days with rainfall reached 64 percent in
   1974 and 65 percent in 1975.  Pissolved oxygen levels in
   general are low ranging from 45 to 60 percent of satura-
   tion.

Quality of Records:  The monitor was visited once a month or
   more.  Monitor records are excellent with only a few short
   periods per year missing.

Discharge Characteristics:  Average flow 200 cfs, a.pprox.
   range 10 to 37,000 cfs.

Drainage Area at Monitor:  232 square miles

Urban Area(s)  Contributing at Monitor:  Perhaps a little of
   Carthage and the fringes of Joplin, approx. population -
   no t de te rmi ned .

Approximate Urban Area Contributing at Monitor;  2 or 3 square
   miles at most or less than 1 percent of total.

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  No hourly data were obtained
   at this site.

Conclusions and Comments:  Very little urban area seems to
   contribute at monitor.  Correlation is with rain gage
   60 miles away.  Examination of daily record seems to
   indicate isolated events where D.O. decreases with flow.
   This does not seem to be related to urban runoff.  There
   is a great deal of strip mining between the monitor and
   Joplin.
                              162

-------
STATE:  MISSOURI

Monitor Name;  James River near Boaz, Missouri
USGS I.D.;   07 052 250  Latitude: 37 00 25  Longitude: 93 21 50

Stream Gage Name:   Same
USGG I.^.:      Same     Latitude:  Same     Longitude:   Same

Rain Gage:   Springfield
Weather Bureau I.P.:  7976

Daily Data Analysis Results:  Water years 1972-76 were examined.
   The probability of low dissolved oxygen with high flow never
   exceeded 44 percent.  The probability of low dissolved
   oxygen on days with rainfall exceeded 60 percent in 1973, 74,
   75, and 76.  The  correlation could be clearly seen by eye.
   Dissolved oxygen levels were extremely low, ranging from
   23 to 60 percent saturation.

Quality of Records:  Rated fair by USGS, monitor is visited
   once a month.  Flow record is continuous, monitor looses
   from 1 to 2 months a year, usually at summer low flow.

Discharge Characteristics:  Average flow approx. 300 cfs,
   approx.  range 55 to 31,500 cfs,

Drainage Area at Monitor:  462 square miles

Urban Area(s) Contributing at Monitor:  Springfield, approx.
   population 180,000.

Approximate Urban Area Contributing at Monitor:  25 square
   miles or 5 percent of the total

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  Hourly data were not available
   for this site.

Conclusions and Comments:  The James River receives treated
   sewage from the Springfield Southwest sewage treatment
   plant.  It also receives the flow from Wilsons Creek
   which is very low in D.O.  There is a definite D.O.
   problem here, but whether it is direct urban runoff or
   something else is hard to say.  The dissolved oxygen
   level is typically below 5 mg/1 4 months of every year.
                              163

-------
STATE:   MISSOURI

Monitor Name:  Wilsons Creek near Battlefield
USGS I.D.1  07 052 160  Latitude: 37 07 02  Longitude: 93 24 14

Stream Gage Name:   Same
USGS I.D.:    Same      Latitude:   Same _  Longitude:  Same

Rain Gage:  Springfield
Weather Bureau I.P.:  7976

Daily Data Analysis Results:  Water years 1973-76 were examined,
   The probability of low dissolved oxygen at the time of a
   flow event never exceeded 60 percent but did reach 57 per-
   cent in 1976.  The probability of low D.O. on days with
   rainfall exceeded 60 percent in 1974, 75, and 76.  Pissolved
   oxygen levels are very low, ranging from 2 to 16 percent
   of saturation.

Quality of Records:  Monitor is visited once a month or more.
   Flow record is  generally continuous.  Monitor record is
   intermittent during the summer months.

Discharge Characteristics;  Average flow approx. 100 cfs,
   approx. range 25-4,000 cfs,

Drainage Area at Monitor:  55 square miles.-

Urban Area(s)  Contributing at Monitor:  Springfield, approx.
   population 180,000-

Approximate Urban  Area Contributing at Monitor;  25 square
   miles or 45 percent of total.

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  Hourly data could not be
   obtained for this site.

Conclusions and Comments;  The problem at this site is con-
   nected to the problem at Wilsons Creek near Springfield,
   Missouri.  Hourly data were examined there and may be
   seen by referring to that station.  The problem is no
   doubt related to the fact that Springfield is nearly
   1/2  of the drainage basin.
                              164

-------
STATE:  MISSOURI

Monitor Name:  Wilsons Creek near Springfield
USGS I.D.:   07 052 100  Latitude: 37 10 06  Longitude: 93 22 14

Stream Gage Name:  Same
USGS I.D.;     Same      Latitude:  Same     Longitude:  Same

Rain Gage;   Springfield
Weather Bureau I.P.:  7976

Daily Data Analysis Results:  Water years 1972-76 were examined,
   The probability of low dissolved oxygen with high flow ex-
   ceeded 70 percent in 1973, 75, and 76.  It hit a peak of
   81 percent in 1975.  This is the highest probability en-
   countered at any site examined.  The probability of low
   D.O. on days with rainfall exceeded 60 percent in 1975 and
   1976.  D.O. levels are characteristically low, averaging
   50 to 60 percent saturation.

Quality of Records:  The monitor is visited once a month or
   more.  Flow records are virtually continuous.  The monitor
   quits from one to two months a year, usually at times of
   low flow.

Discharge Characteristics:  Average flow approximately 20 cfs,
   range from 0 to 2800 cfs.

Drainage Area at Monitor:  31.4 square miles-

Urban Area(s) Contributing at Monitor:  Springfield, approx.
   population 180,000.

Approximate Urban Area Contributing at Monitor:  25 square
   miles or 80 percent of total.

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  The hourly data periods ex-
   amined are shown in Figures D*-4,   D-5 , and  D-6.  Water
   quality is very poor at all times, but definitely decreases
   more at times of high flow.  The EPA suggested standard
   of 2.0 mg/1 for 4.0 hours is violated several times in the
   periods examined.

Conclusions and Comments:  This site had the highest percent-
   age of urban drainage of any in the entire study.  There
   can be no doubt that the large percentage of urban area
   contributes to the bad quality.  It is not possible, how-
   ever, to tell the exact cause of the low D.O. - high flow
   without physically examining the site.


                              165

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                                20 T
                           cr
                           a
                                10 . r
                                                                    SATURATION DO LEVEL
                               3.0  ,.
CTi
                               0.0
                                                                             DISCHARGE / AVG. DISCHARGE
                                                        4         6          8         10


                                                         TIME FROM START OF PERIOD, days
12
           14
                                           Figure D-4. Hourly data for Wilsons Cr. near Springfield, MO.

                                                              (4/15/73 to 4/29/73).

-------
                            cr
                            o
                                 20
                                 10
                          SATURATION DO LEVEL
CTi
•o
O
Q
 .-
O
I
O
C/J
Q

CD
                            UJ
                            C3
                            CC
                            <

                            O
                            VI
                                3.0
                                2-5
                                2.0
                                1.5
                                1.0
    0.5   •
                                0.0
                                              DISCHARGE / AVG. DISCHARGE
                                                                                       n PRECIPITATION, inches
                                                                     4                6

                                                           TIME FROM START OF PERIOD, days
                                                                                                                      10
                                            Figure D-5. Hourly data for Wilsons Cr. near Springfield, MO.
                                                                (8/10/75 to 8/19/75).

-------
                           O"
                           a
                                20  T
      10  ..
                                                                                        SATURATION DO LEVEL
                                                                                  DO LEVEL
CTl
03
                           •o
                           O
                               3.0  ,.
                               2.5  ::
J  2.0  X


Q   1.5  ±


•«.   1.0  ::
UJ
o
tr        ••.
<   0.5  ::
                               0.0
                                                             DISCHARGE / AVG. DISCHARGE
                                                                                  DO DEFICIT / 10, mg/l
                                                          TIME FROM START OF PERIOD, days
                                                                                                                     10
                                             Figure D-6. Hourly data for Wilsons Cr. near Springfield, MO.
                                                                (2/15/76 to 2/24/76).

-------
STATE:  NEW JERSEY

Monitor Name:  Delaware River at Trenton
USGS I.D.:   01 463 500  Latitude: 40 13 18  Longitude: 74 46 42


                                    Same    Longitude:   Same


                      8883
Stream Gage Name:   Same
USGS I.D.:     Same     Latitude:
Rain Gage:  Trenton
Weather Bureau I.D.:
Daily Data Analysis Results:  Water years 1972-76 were examined,
   The probability of low D.O. with high flow exceeded 60 per-
   cent in 1973 and 1975.  It reached 58 percent in 1972.
   The probability of low D.O. on days with rainfall exceeded
   60 percent in 1972.  It reached 57 percent in 1973 and
   1976.  Water quality here is generally good with D.O.
   levels from 85 to 97 percent saturation.  The correlation
   between flow and low D.O. is so obvious that it can easily
   be seen by eye.  This is illustrated in Figure D-7.
Quality of Records:  The monitor is visited once a month or
   more.  The flow record is virtually continuous.  The moni-
   tor record is good overall but from two weeks to a month
   are missing each year.

Discharge Characteristics:  Average flow 12,000 cfs, approx.
   range 1,200 to 325,000 cfs.

Drainage Area at Monitor:  6,780 square miles

Urban Area(s)  Contributing at Monitor:  Trenton and suburbs,
   population estimated at greater than 1/2 million.

Approximate Urban Area Contributing at Monitor:  60 to 70
   square miles or 1 percent of total.

Results of Streeter-Phelps Analysis:  Not performed at this
   site.
Hourly Data Analysis Results:
   tained at this site.
                               Hourly data could not be  ob-
Conclusions and Comments;  Trenton, New Jersey marks  the up-
   stream edge of an urban megalopolis.  The water quality
   in the Delaware deteriorates rapidly downstream.   See
   for example Delaware at Chester and Bristol, Pennslyvania.
   While the water quality is good at Trenton, it is  defi-
   nitely not good as one proceeds downstream.  The fact that
   such a strong correlation exists at Trenton makes  one
   wonder what would have been measured on a smaller  stream.

                             169

-------
                                               WATER YEAR = 1972
    20.00n
                                                                 i- 80.00
   15.00-
   10.00-
z
LU
a

x
o
Q
HI
5.00-
    0.00

      1SOOO
    -5.00 -I
                                                                   0.00
        Figure D-7. Daily DO and flow for Delaware R. at Trenton, NJ.

-------
The monitor is downstream of Trenton on the New Jersey
shore.  It is in a good place to sense urban runoff
before it mixes laterally across the stream.  It is
much too close to Trenton to sense a fully developed
D.O. sag.  No water quality standards violations were
seen here.
                          171

-------
STATE:  NEW JERSEY

Monitor Name:  Manasquan River at Squankum
USGS I.D.:01 408 OOP  Latitude: 40 09 47  Longitude: 74 09 21
Stream Gage Name:   Same
USGS I.D.:    Same      Latitude:
        Same    Longitude:   Same
Rain Gage:
Weather Bureau I.D.:

Daily Data Analysis  Results:   Water years 1970-74 were examined.
   The probability of low D.O. at high flow exceeded 60 percent
   in 1971 and 1972.   No daily rainfall correlation was per-
   formed at this site.   D.O.  levels are generally low ranging
   from 50 to 70 percent saturation.  The daily record for
   1972 is illustrated in Figure D-8.
Quality of Records:   USGS rates the flow record as excellent.
   The monitor is visited at least once a month.  Monitor
   data is fairly typical with from two to four weeks missing
   each year.
Discharge Characteristics:
   13 to 3,000 cfs.
Average flow 75 cfs, approx. range
Drainage Area at Monitor;   43.4 square miles

Urban Areas Contributing at Monitor:   Farmingdale, Naval
   Reserve Ammunition Dump, several unnamed suburbs, popu-
   lation unknown.

Approximate Urban Area Contributing at Monitor:  1-2 square
   miles or 2-4 percent of total.

Results of Streeter-Phelps Analysis:   Not performed at this
   site.

Hourly Data Analysis Results:   Not performed at this site.

Conclusions and Comments;   Very little urban area could be
   found here.  There is a good deal of swamp upstream of the
   monitor.  This may lend some additional evidence to the
   swamp flushing theory advanced by the Triangle J208 Study
   (3) .  The water quality is definitely bad and there is an
   obvious correlation with flow events.  The problem, how-
   ever, does not appear to be related to the objectives of
   this study.
                              172

-------
                                                                           WATER YEAR = 1972
U)
                                  10.00 -I
                                  -10.00 -"
                                                                   210.00
                                                                 TIME, days
                                                           DO DEFICIT
                                                                                                    60.00
                                                                                                     0.00
                                                                                 240.00          270.00
                                        Figure D-8. Daily DO and flow for Manasquan R. at Squankum, NJ.

-------
STATE:  NEW JERSEY

Monitor Name:  Raritan River near South Bound Brook
USGS I.D.:   01 404 100  Latitude: 40 30 47  Longitude: 74 32 24

Stream Gage Name;  Raritan River Below Calco Dam at Bound Brook
USGS I.D.:   01 403 060  Latitude: 40 33 05  Longitude: 74 32 54

Rain Gage:   Bound Brook
Weather Bureau I.P.:   0927

Daily Data Analysis Results:  Water years 1974 and 1975 were
   examined.  The probability of low D.O. at high flow reached
   60 percent in 1975.  D.O. levels were generally high,
   ranging from 75 to 80 percent saturation.  The daily data
   for 1975 is illustrated in Figure  D-9.  Several obvious
   instances where the D.O. decreased with flow events were
   found.  Just as many times can be found when the opposite
   is true.

Quality of Records:  Much of the 1974 D.O. record was missing.
~~  The flow record is excellent.  The 1975 monitor record is
   good except for the winter months.  The monitor is visited
   once a month or more.

Discharge Characteristics:  Average flow 1250 cfs, approx.
"range 1,000 to 17,000 cfs.

Drainage Area at Monitor:  862 square miles

Urban Area(s) Contributing at Monitor:  Somerville, Bound
   Brook, Middlesex,  Manville, South Bound Brook, approximate
   population 47,000.

Approximate Urban Area Contributing at Monitor:  6.63 square
   miles or 1 percent of total.

Results of Streeter-Phelps Analysis;  The results of the
   analysis are illustrated in Figure D-10. The monitor
   location is too close to the urban area to sense
   maximum, sag. A location 10 miles or more downstream
   would be better.

Hourly Data Analysis Results:  Hourly data could not be
   obtained for this site.

Conclusions and Comments:  Water quality is not good here.
   There are 6 sewage treatment plants along the reach
   immediately above the monitor.  The entire area is neavily
   industrialized.  The monitor is too close to the urban
   area to sense the maximum sag in a Streeter-Phelps sense.
                              174

-------
                                                    WATER YEAR = 1975
    15.00 -i
    10.00 -
Z
LU
C3

X
o

Q
in
o

5
     5.00-
     0.00
        150.00
     -5.00 -
    -10.00 -1
                       180.00           210.00

                             TIME, days  /*"
                                                                         r eo.oo
                                                                           4O.OO
                                                                                   O
                                                                                   cc
                                                                         - 20.00    0
270.00
                                             DO DEFICIT
       Figure D-9. Daily DO and flow for Raritan R. near South Bound Brook, NJ.

-------
01
                               15.0 T
                               10.0 1
                                   |	SATURATION ATJ00C_=_7.63_rng/l_
                            LU
                            a
                            o
                            a
                                5.01
                                       SATURATION AT20°<^=J3.17jTig/l
0
A
                                              1
10
                                              MONITOR
                                             MIDDLESEX
                                           BOUND BROOK
                                           LOW GAGE
                                        MANMILLE
                                      FINDERINE
                                   SOMERVILLE
                                                                                     STORM
                20              30
                    DISTANCE, mi
                             Figure D-10. Streeter-Phelps analyses results for Raritan R. near South Bound Brook, NJ.

-------
STATE:   OHIO

Monitor Name:  Ashtubula River at Ashtabula
USGS I.D.;   04 212 700  Latitude: 41 54 00  Longitude: 80 47 44

Stream Gage Name:  Ashtabula River near Ashtabula
USGS I.D.:   04 212 500  Latitude: 41 51 20  Longitude: 80 45 44

Rain Gage:   Ashtabula
Weather Bureau I.P.:  0264

Daily Data Analysis Results:  Water years 1972-76 were examined,
   The probability of low D.O. with high flow reached 60 per-
   cent in 1975.  The probability of low D.O. on days with
   rainfall exceeded 60 percent in 1975 and 1976.  Dissolved
   oxygen levels are in the 65 to 70 percent saturation range.

Quality of Records:  The monitor is visited once a month or
   more.  Both the flow and monitor records are excellent
   with little missing data.

Discharge Characteristics:  Average flow 150 cfs, approx.
   range 0-10,000 cf s.

Drainage Area of Monitor:  136 square miles

Urban Area(s) Contributing at Monitor:  Ashtabula, Harbor,
   East Ashtabula, approximate population 64,000

Approximate Urban Area Contributing at Monitor:  9 square
   miles or 7 percent of total

Results of Streeter-Phelps Analysis:  Not performed at this
   site - river empties into Lake Erie less than one mile
   downstream.

Hourly Data Analysis Results:  The period examined shows a
   definite tendency for the D.O. to improve with increased
   flow.  Water quality is poor here with D.O. less than
   5 mg/1 during much of the summer.  The hourly data are
   illustrated in Figure D-ll.

Conclusions and Comments:  The lower reaches of the Ashtabula
   are probably more like an estuary than a river.  There is
   a heavy industrial concentration near the monitor.  Poor
   water quality does not appear directly related to urban
   surface runoff.
                              177

-------
                        o
                        Q
                                                          SATURATION DO LEVEL
00
                        T3

                        O
C3
I
                        CD
                        111

                        CD
                        CJ
                        in
                             3.0 r
                             2.5 ..
                             2.0 ::
                                                           DISCHARGE / AVG. DISCHARGE
                                                         CIPITATIQN. inches  -i  i  I
                                                                                                         DO DEFICIT/10, mg/l
                                                        6       8       10      12


                                                      TIME FROM START OF PERIOD, days
                                     Figure D-11. Hourly data for Ashtabula R. near Ashtabula, OH.

                                                          (6/1/75 to 6/20/75).

-------
STATE:  OHIO

Monitor Name;  Blanchard River near Findlay
USGS I.P.;  04 189 OOP  Latitude: 41 03 21  Longitude: 83 41 17

Stream Gage Name:  Same
USGS I .D. ;    Same	  Latitude:  Same     Longitude:  Same

Rain Gage;  Findlay STP
Weather Bureau I.P.;  2791

Daily Data Analysis Results:  Water years 1972-1976 were examined.
   The probability of low P.O. with high flow never exceeded
   55 percent.  The probability of low P.O. on days with rain-
   fall exceeded 60 percent in 1973, 1975, and 1976.  Water
   quality levels are generally poor, ranging from 40 to 70
   percent P.O. saturation.

Quality of Records:  Both the monitor and flow records are
   excellent.  Virtually, no data are missing from either.
   The monitor is visited once a month or more.

Pischarge  Characteristics;  Average flow 250 cfs, approx.
   range 10 to 15,000 cfs

Drainage Area at Monitor:  346 square miles

Urban Area(s) Contributing at Monitor:  Findlay, approximate
~  population 38,200

Approximate Urban Area Contributing at Monitor;  7 square
   miles oar 2 percent of total

Results of Streeter-Phelps Analysis:  Results of the analysis
   indicates that the monitor is too close to Findlay to
   sense the maximum deficit.  A location 8 to 10 miles down-
   stream would be better.  The results of the analysis are
   illustrated in Figure P-12.

Hourly Pata Analysis Results:  The period examined seemed to
   indicate a correlation between the presence of rainfall
   and higher than average P.O. deficit.  High flow appears
   to decrease the deficit.  Water quality is poor with many
   days below 5 mg/1 P.O.  Given the monitor location this
   may actually be a case of urban runoff caused P.O. defi-
   cit.  The hourly data are illustrated in Figure p-13.
                               179

-------
co
o
                             15.0 _
                             10.0 ..
                          O
                          il
                          ui
                          O

                          8
5.0 ..
                                                    STORM
                                   ft
               10
                            20
                                      MONITOR, FLOW
                                    FINDLAY STP
                                          30

                                     DISTANCE, mi
                                                       40
                                                                    50
60
                              Figure D-12. Streeter-Phelps analysis results for Blanchard R. near Findlay, OH.

-------
                           o
                           D
                                20 ,
                                10 .
                                                           SATURATION DO LEVEL
                                                               JDO LEVEL
00
                           •o
                           O
                           O
                           X
                           $
                           o

                           o
                           in
                                3.0 ,.
2.5 :
                                2.0 :
                                                                    DISCHARGE / AVG. DISHCARGE
                                                                                             ^ PRECIPITATION, inches i
                           6       8       10       12      14

                         TIME FROM START OF PERIOD, days
                                                                                                 16
                                                                                                        18
                                                                                                                20
                                      Figure D-13. Hourly data for Blanchard R. near Findlay, OH.
                                                         (7/1776 to 7/20/76).

-------
Conclusions and Comments:   This would be an interesting site
   to study in detail.   It is hydraulically simple.   Findlay
   is the only urban area.   The monitor is 1.5  miles down-
   stream of the sewage treatment plant.  Sediment records
   are available.   There is some strip mining and consider-
   able Oil activity in the area.   Ohio State University
   examined this site in an independent effort and concluded
   that poor treatment facilities were part of the problem.
   They concluded that it would be difficult to separate the
   CSO effects from just plain bad treatment effluent.
                            182

-------
STATE:   OHIO

Monitor Name:  Cuyahoga River at Independence
USGS I.D.:   04 208 OOP  Latitude: 41 23 43  Longitude: 81 37 48

Stream Gage Name:   Same
USGS I.P. :     Same	  Latitude:  Same     Longitude:   Same
Rain Gage:  Cleveland WB APT
Weather Bureau I.P.;  1657

Daily Data Analysis Results:  Water year 1972-1976 were ex-
   amined.  The probability of low P.O. with high flow never
   exceeded 60 percent.  The probability of low P.O. on
   days with rainfall exceeded 60 percent in 1973 and 1976.
   Water quality levels are in the range 60 to 70 percent
   of saturation.

Quality of Records:  The monitor is visited once a month or
   more.  Both the flow and monitor records are virtually
   continuous with little or no missing values.

Discharge Characteristics:  Average flow approx. 800 cf s ,
   range 55 to 25,000 cfs

Prainage Area at Monitor:  707 square miles

Urban Area(s)  Contributing at Monitor:  Cleveland suburbs,
   Akron, approximate population 2,500,000+

Approximate Urban Area Contributing at Monitor:  60 square
   miles counting Akron or 8 percent of total, 110 square
   miles counting Cleveland suburbs or 16 percent of total.

Results of Streeter-Phelps Analysis:  The analysis indicates
   that the monitor is in a good place to sense a sag due
   to influences at Akron.  The analysis indicates that storm
   flow at Akron could drive the P.O. at Independence to
   zero.  The results are shown in Figure D-14.


Hourly Pata Analysis Results:  The period examined showed a
   definite tendency for the P.O. deficit to increase at
   high flow and on days with rain.  The problem was not
   overly severe for the period investigated with P.O.  levels
   averaging 6 mg/1. This is shown in Figure D-15.

Conclusions and Comments:  This would be a reasonably good
   site to study in detail.  The lower reaches of the Cuyahoga
   are famous in water quality annuals for catching fire in
   the early 1960s. Sediment records are available here.  The
   urban percentage is large and the monitor is well located.

                              183

-------
    15.0 _
    10.0 ..
li.
O
Q
    5.0 ..
    0.0
            SATURATION AT 26°C = 8.22 mg/l
* j
J



, i


, 	 f. f . y i y i • T ' 	 f- 	 If 	 f 	 f 	 —91 	
'10 20 i
| DISTANCE, mi
AKRON STP
CUYAHOGA AT OLD PORTAGE MONITOR
STORM FLOW AKRON
SiPPROX. EDGE OF AKRON
•r — r 	 "
30 '
i



i


1— 	 -1 —
k '


— —r 	 r r * • 	 r 	 "t-"""
40
t
CENTER OF CLEVELAND
CLEVELAND STP
CUYAHOGA AT INDEPENDENCE MONITOR
TINKERS CREEK
SMALL STP
Figure D-14. Streeter-Phelps analysis results for Cuyahoga R. from Akron to Cleveland, OH.

-------
                                20 ^
                           o-
                           Q
                                10 ..
                                                SATURATION DO LEVEL
                                                DO LEVEL
I—

00

U1
                           O



                           '3
O
Q


(3


O
UJ
CD
ec

I



5
                                3.0 „
                                2.5 ::
2.0
                           Q    1.5

                           6
                           >
                                1.0
                                0.5
                                0.0
                                  DISCHARGE / AVG. DISCHARGE

                                                               O DEFICIT / 10, mg/l


                                                                  PRECIPITATION, inches
                                              46     8    10   12    14    16   18    20


                                                         TIME FROM START OF PERiOD, days
                                                             22    24    26   28   30
                                         Figure D-15. Hourly data for Cuyahoga R. at independence, OH.

                                                             (6/19/76 to 7/18/76).

-------
The hydraulics of the Akron sewer system are quite com-
plex, but the reach from the Cuyahoga at Old Portage
gage to the Independence gage would be good because the
input and output D.O.  levels are monitored.  The Akron
treatment plant lies between the two gages.
                         186

-------
STATE:  OHIO

Monitor Name:  Cuyahoga River at Old Portage
USGS I.D.:   04 206 OOP  Latitude: 41 08 08  Longitude: 81 32 50

Stream Gage Name:  Same
USGS I .D. :     Same	  Latitude:   Same    Longitude:   Same

Rain Gage:   Cleveland WB APT
Weather Bureau I.P.:  1657

Daily Data Analysis Results:  Water years 1972-1976 were ex-
   amined.   The probability of low D.O. with high flow never
   exceeded 47 percent.  The probability of low D.O. or days
   with rain exceeded 60 percent in 1976 and averaged 57
   percent for the period examined.  Water quality is mar-
   ginal at 60 to 75 percent of saturation.

Quality of Records:  Monitor is visited once a month or more.
   Both flow and monitor records are very good with little
   missing data.

Discharge Characteristics:  Average flow40Qcfs, range 25-
   8,000 cfs

Drainage Area at Monitor:  404 square miles

Urban Area(s) Contributing at Monitor:  Akron, approx. popu-
   lation 690,000, including suburbs

Approximate Urban Area Contributing at Monitor:  50 square
   miles or 12 percent of total

Results of Streeter-Phelps Analysis:  The analysis indicates
   that.the monitor is too close to Akron to sense the maxi-
   mum sag in a Streeter-Phelps sense.  The Cuyahoga at
   Independence monitor is better situated.  The analysis
   is illustrated in Figure D-14 .

Hourly Data Analysis Results:  The period examined is illus-
   trated in Figure D-16.  This is the same time period
   examined for the Cuyahoga at Independence monitor.  A
   slight increase in the D.O. deficit and a definite damp-
   ening of the diurnal D.O. cycles can be seen for the
   first two flow events.  The effect is not as pronounced
   as at Independence.  Water quality is marginal, averaging
   6 mg/1.   It is difficult to conclude much from this hourly
   data.  Examination of 1976 daily data indicates several
   places where D.O. levels well below 5 mg/1 occur with
   increased flow.
                               187

-------
                            o
                            Q
                                 20 ,
                                 10 ..
                                                  SATURATION DO LEVEL
oo
oo
                           x
                            u
Q


(5
                           LU

                           <5
                           1
     3.0




     2.5 ::
o    2.0 ::
x
                                1.5 ::
                                                                  DISCHARGE / AVG. DISCHARGE
                                                         8    10    12    14    16   18    20


                                                         TIME FROM START OF PERIOD, days
                                                                  DO DEFICIT/ 10, mg/l


                                                                      PRECIPITATION, inches
                                                                 22    24    26   28    30
                                           Figure D-16. Hourly data for Cuyahoga R. at Old Portage, OH.

                                                              (6/19/76 to 7/18/76).

-------
Conclusions and Comments:  A problem can be identified here,
   but not as well as at Independence.   It would be an inter-
   esting place to study in detail because sufficient evidence
   exists to show a correlation between both rain and flow
   and low D.O.  The availability of monitor records here and
   at Independence would be very good for model calibration.
                              189

-------
STATE:  OHIO

Monitor Name:   Grand River at Painsville
USGS I.D.:   04 212 200  Latitude:  41 44 09  Longitude: 81 15 59

Stream Gage Name;   Grand River near Painsville
USGS I.D.;   04 212 100  Latitude:  41 43 08  Longitude 81 13 41

Rain Gage:   Cleveland
Weather Bureau I.P.:  1657

Daily Data Analysis Results:  Water years 1975 and 1976 were
   examined.  The maximum probability of low D.O. with high
   flow was 45 percent.  The probability of low D.O. on days
   with rain was 60 percent in 1975.  D.O. levels fall in
   the 60 to 70 percent saturation range.

Quality of Records:  The monitor is visited once a month or
   more.Flow records are good but the monitor record is
   very poor with nearly 1/3 of the year missing.

Discharge Characteristics;  Average flow 1,000 cfs, range
   50-13,000 cfs

Drainage Area at Monitor;  701 square miles

Urban Area(s)  Contributing at Monitor:  Painsville, approx.
   population 30,000

Approximate Urban Area Contributing at Monitor:  4 square
   miles or less than 1 percent of total

Results of Streeter-Phelps Analysis:  This was not considered
   here.  River empties into Lake  Erie several miles down-
   stream.

Hourly Data Analysis Results:  The hourly data are illustrated
   in Figure D-17.  There is some indication of increased
   deficit for the small flow event but the D.O. improves with
   the larger event.  The evidence is inconclusive.

Conclusions and Comments:  This site has occasional water
   quality problems with the D.O.  dropping to less than
   5 mg/1.   There is no real evidence to connect this to
   direct urban runoff.  There is no obvious correlation
   with flow and the rainfall correlation is suspect because
   of the distance  (60 miles) to the rain gage from the
   monitor.
                              190

-------
o
o
      20  ,.
      10  ..
                                   SATURATION DO LEVEL
                                        DC LEVEL
•o
O
Q

6
I

 HI
 O
 K
 <

 O
     3.0  ^
2.5 ::
2.0 ::
      1.5 ::
      1.0
o.5  ::
      o.o
                                             DISCHARGE / AVG. DISCHARGE
                                 6       8       10      12

                               TIME FROM START OF PERIOD, days;
                                                           14
                                                                   16
                                                                           18
                                                                                   20
                 Figure D-17. Hourly data for Grand R. at Painesville, OH.

                                   (8/25/75 to 9/13/75).

-------
STATE:  OHIO

Monitor Name:   Hocking River Below Athens
USGS I.D.:   03 159 510  Latitude:  39 19 39  Longitude: 82 00 18

Stream Gage Name:   Hocking River at Athens
USGS. I.P.; 03 159 500  Latitude:  39 19 44  Longitude: 82 05 16
Rain Gage:   Athens
Weather Bureau I.P. ;
0279
Paily Pata Analysis Results;   Water years 1972-1976 were ex-
~  amined.  The probability of low D.O.  and high flow reached
   67 percent in 1976.   The dissolved oxygen levels are
   generally high,  averaging 65 to 86 percent of saturation.

Quality of Records:  The monitor is visited once a month or
~~  more.  Both flow and monitor records  are good with little
   missing data.
Discharge Characteristics;
   range 25-30,000 cfs
      Average flow approx.  1,000 cfs,
Drainage Area at Monitor:   943 square miles

Urban Area(s)  Contributing at Monitor:   Athens,  approx.  popu-
   lation 15,000

Approximate Urban Area Contributing at Monitor;   2 square
   miles or less than 1 percent of total

Results of Streeter-Phelps Analysis;   Analysis indicates
   that the monitor is too close to town.  A location 15  to
   20 miles downstream would have been better.  Even storm
   flow seems incapable of doing much harm to water quality
   here.  The analysis results are illustrated in Figure D-18.

Hourly Data Analysis Results:  The period examined is illus-
   trated in Figure D-19.It is highly inconclusive evidence
   of anything.  The D.O.  level decreases slightly as the
   flow events continue to occur, but that is all.  P.O.
   levels are high, running quite near saturation.  Some
   evidence of supersaturation is apparent for the first
   three days of the period examined.

Conclusions and Comments:   Examination of the daily record
   indicates that the P.O. does drop  below 5 mg/1 in the
   summer, but no evidence is present in the hourly to say
   that it is an urban runoff problem.   Possibly the level
   of sewage treatment is  inadequate.  There is little else
   shown on the map to suspect.
                              192

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U)
                             15.0 T
                             10.0 .
                          H
                          LU
                          Q
                              5.0
                                     SATURATION AT 20°C = 9.17 mg/l
                                                 AT 28°C =
                                                                    DISTANCE, mi
                                  ATHENS STP   MONITOR
                                                                                                       STORM
                                                                                                                30
                               Figure D-18. Streeter-Phelps analysis results for Hocking R. below Athens, OH.

-------
      20  ,.
O
Q
      10 .
                                SATURATION DO LEVEL
                                        DO LEVEL
u

'i
•O

O
Q


C3
O
UJ
O
oc
<
I

8

O
     3.0 ,,
2.5 ::
DISCHARGE / AVG. DISCHARGE
                                                                  PRECIPITATION, inches




                                                                             DO DEFICIT/10, mg/l
                             8    10    12   14   16    18    20


                              TIME FROM START OF PERIOD, days
                                                            22
                                                                 24    26    28
                                                                                 30
                  Figure D-19. Hourly data for Hocking R. at Athens, OH.

                                   (6/19/76 to 7/18/76).

-------
STATE:  OHIO

Monitor Name:  Little Miami River at Miamiville
USGS I.D.;  03 245 300  Latitude: 39 12 38  Longitude: 84 17 33

Stream Gage Name:  Little Miami River at Milford
USGS I.D.;  03 245 500  Latitude: 39 10 17  Longitude: 84 17 53

Rain Gage:  Cincinnati ABBE OBS
Weather Bureau I.P.:  1561

Daily Analysis Results:  Water years 1971 to 1974 were ex-
   amined.  The probability of low D.O. and high flow reached
   67 percent in 1974 and 66 percent in 1973.  The probability
   of low D.O. on days with rain never exceeded 60 percent.
   Water quality is generally good at the site with D.O.
   levels averaging 80-85 percent saturation.

Quality of Records;  The monitor is visited once a month or
   more.  Both flow and D.O. records are generally continuous.

Discharge Characteristics:  Average flow 1,200 cfs, range
   100-60,000 cfs

Drainage Area at Monitor:  1200 square miles

Urban Area(s) Contributing at Monitor:  Suburbs of Cincinnati,
   population difficult to estimate

Approximate Urban Area Contributing at Monitor:  unknown -
   probably less than 1 percent

Results of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Data Analysis Results:  The period of hourly data
   examined is illustrated in Figure D-20.  There is clear
   evidence of an increased D.O. deficit at the time of
   the  flow events shown.  The dissolved oxygen level fell
   near the 5 mg/1 level during the events.

Conclusions and Comments:  There is clearly a correlation here,
   but the cause is not clear.  The writers visited the
   site and it is not obviously urban.  The monitor is near
   several small towns in the fringe suburbs of Cincinnati.
   There is a good deal of gravel mining and cement pro-
   cessing upstream.  Deficit levels are not severe enough
   to warrant further study here.
                              195

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      20 T
O
Q
SATURATION DO LEVEL
•a
O
Q

CJ
X
o
I


5
                      DISCHARGE / AVG. DISCHARGE
                               6       8      10      12

                             TIME FROM START OF PERIOD, days
                                                            14
                                                                    16
                                                          20
               Figure D-20. Hourly data for L. Miami R. at Miamiville, OH.
                                 (8/1/73 to 8/30/73).

-------
STATE:  OHIO

Monitor Name:  Little Miami River near Spring Valley
USGS I.D.:   03 242 050  Latitude: 39 35 00  Longitude: 84 01 49

Stream Gage Name:  Same
USGS I.D.:      Same     Latitude:   Same    Longitude:   Same

Rain Gage:   Dayton WB APT
Weather Bureau I.P.;  2075

Daily Data Analysis Results:  Water years 1972-1976 were ex-
   amined.   The probability of low P.O. with high flow reached
   58 percent in 1972, 59 percent in 1976, and exceeded 60
   percent in 1974 and 1975.  The probability of low P.O. on
   days with rainfall exceeded 60 percent in 1974 and 1975.
   Pissolved oxygen levels ranged from 60 to 75 percent satu-
   ration.

Quality of Records:  The monitor is visited once a month or
   more.  The flow record is continuous.  The monitor record
   is generally continuous with an occasional two to three
   weeks missing.

Pischarge Characteristics:  Average flow 386 cfs, range 23-
   18,400 cfs

Prainage Area at Monitor:  366 square miles

Urban Area(s) Contributing at Monitor:   Payton, Payton sub-
   urbs, Xenia, approximate populations 60-70,000 and 25,000
   respectively

Approximate Urban Area Contributing at Monitor:  11 to 13
   square miles or 3 percent of total

Results  of Streeter-Phelps Analysis:  Not performed at this
   site.

Hourly Pata Analysis Results:  A clear correlation exists
   between  the presence of storm event flow and a lowering
   of the dissolved oxygen level for the period examined.
   This  is  illustrated in Figure P-21. There is a fairly
   clear relationship between the rainfall events and
   small increases in the P.O, deficit,, The P.O. level
   is driven close to the 5 mg/1 level by the  flow event.

Conclusions  and Comments:   Sutron contacted the  cities of
   Payton and Xenia concerning  the  correlation observed
   here.  The Assistant  City Manager at Xenia  indicates
   that the  discharge of  raw sewage at  times of  high  flow
   from the  city of Spring  Valley is probably  the  reason


                              197

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                              20
                         o
                         Q
                              10
                                                  SATURATION DO LEVEL
                                                      DO LEVEL
                             3.0 ,
00
                                                    DISCHARGE / AVG. DISCHARGE
                                                       6      8       10      12     14


                                                     TIME FROM START OF PERIOD, days
16
        18
               20
                                     Figure D-21. Hourly data for L. Miami R. near Spring Valley, OH.

                                                          (7/1/75 to 7/20/65).

-------
for poor water quality here.  The correlation is unmis
takeable here and a limited further investigation may
be warranted.
                          199

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STATE:   OHIO

Monitor Name:   Mad River near Dayton
USGS I.D.:   03 270 OOP  Latitude:  84 05 19  Longitude:  84 05 19

Stream Gage Name:   Same
USGS I.D.:     Same      Latitude:    Same    Longitude:    Same

Rain Gage;   Dayton WB APT
Weather Bureau I.D.:  2075

Daily Data Analysis Results:   Water years 1972-1976 were ex-
   amined.   The probability of low D.O. at times of high flow
   reached 56  percent in 1975 and  exceeded 60 percent in 1972.
   The probability of low D.O. days with rainfall exceeded
   60 percent  all  5 years.  Dissolved oxygen levels are gen-
   erally in the 60 to 75 percent  of saturation range.

Quality of Records;  The monitor is visited once a month or
   more.Records  are generally continuous for both flow and
   the monitor.   Occasional  periods of one to two weeks are
   missing.

Discharge Characteristics:  Average flow 620 cfs, range 100-
   20,000 cfs

Drainage Area  at Monitor:  635 square miles

Urban Area(s)  Contributing at Monitor;  Springfield, small
   portion of  Dayton suburbs, Wright Patterson Air Force
   Base,  approximate population 90-100,000

Approximate Urban  Area Contributing at Monitor:  11-12  square
   miles or 2  percent of total

Results of Streeter-Phelps Analysis:  Streeter-Phelps analysis
   indicates that  a storm flow at  Springfield could produce
   a deficit of 4-5 mg/1 at the monitor.  The monitor is prob-
   ably 10  to  12 miles too far downstream to best sense
   effects  from Springfield.   The  results are illustrated
   in Figure D-22.

Hourly 'Data Analysis Results;  The hourly data examined are
   illustrated in  Figure D-23.  There is a fairly clear cor-
   relation between periods of high flow and periods when the
   D.O. deficit remains high.  The minimum value at times of
   high flow is no worse than on normal days but no recovery
   to "better" conditions takes place.  The correlation be-
   tween the rainfall and flow events is fairly clear.   D.O.
   levels fall to  roughly 5-6 mg/1.  While the correlation
   is clear, no real problem seems to exist here as far as
   standards go.


                              200

-------
   15.0 ,.
   10.0
            SATUftATJON AT_17_°C_=_9.74_ma/l_
            SATURATION AT_27^C_=_8.07jng/l_
m
O
O
Q
    5.0
                                                                       STORM
        SPRINGFIELD
      MONITOR
HUBER HEIGHTS
          Figure D-22. Streeter-Phelps analysis results for Mad R. near Dayton, OH.

-------
                                20 „
                          O
                          D
                                              SATURATION DO LEVEL
                               3.0 T
K)
O
NJ
                          .e
                          u
                          •o
                          8
I
i
                          I
                          Q
                    DISCHARGE / AVG. DISCHARGE
                                                      8   10    12    14   16    18    20    22   24    26    28   30

                                                       TIME FROM START OF PERIOD, days
                                           Figure D-23. Hourly data for Mad R. near Dayton, OH.
                                                           (6/26/72 to 7/25/72).

-------
Conclusions and Comments;  This is a fairly good example
   of a correlation.  It would require further study to
   determine if the monitor is actually located in a poor
   place and if the problem is worse upstream as indicated
   by Streeter-Phelps.  The Streeter-Phelps results indi-
   cate that D.O. levels as low as 3.0 mg/1 might be found,
                           203

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STATE:  OHIO

Monitor Name:   Mahoning River at Ohio-Pennsylvania State Line
               below Lowellville
USGS I.D.:  03 099 510  Latitude: 41 01 53  Longitude: 80 31 10

Stream Gage Name:   Mahoning River at Lowellville
USGS I.D.:  03 099 500  Latitude: 41 02 12  Longitude: 80 32 11

Rain Gage:  Youngstown
Weather Bureau I.D.:  9406


Daily Data Analysis Results:  Water years 1973-1976 were
   examined.  The probability of low D.O. at times of high
   flow days with rainfall reached 60 percent in  1976.
   Water quality is fairly poor with D.O. levels  averaging
   from 45 to 55 percent saturation.  The 1976 daily data
   are illustrated in Figure D-24.  There are clearly
   identifiable periods when flow events coincide with
   periods of near zero dissolved oxygen.  The rainfall
   correlation is also clear.

Quality of Records:   The monitor is visited once a month or
   more.Both flow and monitor records are excellent with
   only isolated periods of 3-5 days missing.

Discharge Characteristics:  Average flow 1400  cfs, range
   700-7,000 cfs

Drainage Area at Monitor:  1073 square miles

Urban Area(s)  Contributing at Monitor;  Niles,  Girard,
   Youngstown, approx. population 550,000,  including
   metropolitan area.

Approximate Urban Area Contributing at Monitor:   25 square
   miles or 2 percent of total

Results of Streeter-Phelps Analysis;  The results of the
   analysis are shown in Figure D-25. Storm flow  from Youngs-
   town is theoretically capable of driving the D.O. to  zero.
   The monitor should ideally be 10 to 15 miles further  down-
   stream to sense this. It seems to be getting the full
   effect where it's at now, however.

Hourly Data Analysis Results;  Hourly data could not be
   obtained at this site.  The daily analysis  clearly in-
   dicates the correlation between both rainfall, flow and
   low D.O.
                              204

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                                10.00-1
to
O
en
                                                                                                r40.00
                                                                                                       o
                                                                                                       ^
                                                                                                       1
                                                                                                -20.00
                                                                                                  0.00

                                                                                              270.00
                                -10.00 -I
                                            Figure D-24. Daily DO and flow for Mahoning R. at
                                                 OH.-PA. state line below Lowellville, OH.

-------
                             15.0 „.
o
CTi
                             10.0 ..
                          h-
                          O
                          iZ
                          HI
                          Q
                          O
                          Q
SAJURAT1QN AT_31°C ^_6.5 mg/j
                              5.0 ..
                                                                                                         NORMAI
                                                              30        40        50

                                                                    DISTANCE, mi
                                                      60
                                                                70        80
                                                    MONITOR
                                                    FLOW
                                                YOUNGSTOWN BELOW R. STP
                                            YOUNGSTOWN ABOVE R. STP
                                       GIRARDSTP
                                    NILESSTP
                                  NILES
                                         Figure D-25. Streeter-Phelps analysis results for Mahoning R. at
                                                     OH.-PA. state line near Lowellville, OH.

-------
Conclusions and Comments:  Youngstown is very heavily in-
   dustrialized.  The entire river valley is a mess of
   rail yards  and steel plants.   The entire urban area
   drains into the river.  Sutron contacted the Youngs-
   town treatment facility and learned that no facilities
   above primary level exist in the Mahoning Valley.  A
   secondary treatment facility for Youngstown has
   reached final design stages.
                            207

-------
STATE:  OHIO

Monitor Name:  Maumee River at Defiance
USGS I.P.:  04 184 100  Latitude: 41 16 43  Longitude: 84 23 07

Stream Gage Name:  Maumee River at Antwerp
USGS I.D.:  04 183 500  Latitude: 41 11 56  Longitude: 84 44 40

Rain Gage:  Defiance
Weather Bureau I.P.:  2098

Paily Pata Analysis Results:   Water years 1972-1976 were ex-
   amined.The probability of low P.O. at times of high flow
   exceeded 60 percent in 1973 and 1975.   The P.O.  levels are
   generally in the 60 to 70  percent of saturation range.

Quality of Records;   The monitor is visited once a month or
   more.The record quality, however,  is poor.   One to two
   months of record are missing each year.  Much of the record
   missing is in the summer when it would have been of most
   interest.

Pischarge Characteristics: Average flow 2680 cfs,  range 26-
   26,200 cfs

Drainage Area at Monitor:  2300 square  miles

Urban Area(s)  Contributing at Monitor:   Fort Wayne, Indiana
   (none of Defiance), population 182,000

Approximate Urban Area Contributing at  Monitor:   25 square
   miles or 1 percent of total

Results of Streeter-Phelps Analysis:  The Streeter-Phelps tech-
   nique was used to determine if the problem observed could
   originate at Fort Wayne, Indiana.  This was done because
   the monitor is upstream of all of Defiance.  The results,
   illustrated in Figure D-26, indicate that storm flow from
   Fort Wayne could cause a 4-5 mg/1 deficit  (2-3 mg/1 absolute
   DO level) at Defiance.  The monitor would have been better
   located at Antwerp, Indiana, to sense the maximum deficit.

Hourly Data Analysis Results;  Hourly data were not examined
   at this site  because of the large distance between the
   monitor and flow gages  (20+ miles).

Conclusions and Comments;  It seems quite probable that 5.0
   mg/1 standard violations would be detected by a properly
   placed monitor.  EPA standards violations might also be
   found.  The daily data are of poor quality, however, and
   the monitor is not in the best location.  The reach from
   Fort Wayne to Antwerp would definitely be worth investi-
   gating.

                              208

-------
t-o
o
                         15.0 ,.
                         10.0 ..
                       Q
                           5.0 ..


                              '•
                                  JLAJU_RATJC3W AT_20.5?C_=_9.g7 jpg/l
                           0.0
^--"~ ~ 7~Z~TZT~7~~^:T:::ri — i — ; — ; — ; — ; — ; — : — :
10 20 30 4 40 50 '
!
:ORT WAYNE, IN. FLOW
i i
'60
JEF
                                                                  DISTANCE, mi
                                                                                                                DEFIANCE, OH.
                                                                                                              MONITOR
                             Fioure D-26. Streeter-Phelps analysis results for Maumee R. at Defiance, OH.

-------
STATE:  OHIO

Monitor Name:  Portage River at Railroad Bridge at Woodvilie
USGS I.D7;04 195 600  Latitude: 41 26 58  Longitude: 83 21 29

Stream Gage Name;  Portage River at Woodville
USGS I.D.;  04 195 500  Latitude: 41 26 58  Longitude: 83 21 41

Rain Gage:  Freemont
Weather Bureau I.P.;  2974

Daily Data Analysis Results:  Water years 1971-75 were ex-
   amined.  The probability of low D.O. with high flow
   exceeded 60 percent in 1973 and reached 68 percent in
   1975.  Dissolved oxygen levels generally fall in the
   50 to  70 percent saturation range.

Quality of Records:  The monitor is visited once a month or
   more.The flow record is continuous.  The monitor record
   usually  contains periods of from two weeks to a month or
   more missing each year.

Discharge Characteristics:  Average flow 300 cfs, range 0-
   17,000 cfs

Drainage  Area at Monitor:  428 square miles

Urban Area(s) Contributing at Monitor-:  Bowling Green, Portage,
   approximate population 22,000 and less than 5,000 respec-
   tively

Approximate Urban Area Contributing at Monitor:  3 square
   miles  or 1 percent of total


Results of Streeter-Phelps Analysis:  Results of the analysis
   are shown in Figure p-27.  They indicate that storm flow at
   Bowling Green might create a D.O. deficit of 3.5 to 4 mg/1
   at Woodville.  The monitor location is too far downstream
   for ideal study  of a problem at Bowling Green.

Hourly Data Analysis Results:  The period examined is illus-
   trated in Figure D-28. There is a clear tendency for the
   D.O. deficit to increase and hold steady at times of
   high flow. The correlation of the flow events with rain-
   fall is also clear. D.O. levels fall to roughly 6 mg/1
   at times of high flow.

Conclusions and Comments:  There is clear evidence of a corre-
   lation here.  Water quality in the river may be worse than
   indicated because of poor monitor location.  The urban area
   involved is relatively small, but would probably be worth
   investigating.

                              210

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   15.0
   10.0 L - SAJURATJON AT_15.5fC_=JOjp5_mg/l_
y
LL
UJ
D

O
a
    5.0
            SATURATION AT 30°C = 7.63 mg/l
                     10
        BOWLING GRtEN
                                                                            50
                                                                                          60
                                               WOODVILLE


                                            DISTANCE, mi
               Figure D-27. Streeter-Phelps analysis results for Portage R. at
                            Railroad Bridge at Woodville, OH.

-------
     20 „
r
o
Q
SATURATION DO LEVEL
     3.0 „
                                DISCHARGE / AVG. DISCHARGE
                              6       8       10     12      14

                             TIME FROM START OF PERIOD, days
              Figure D-28. Hourly data for Portage R. at Woodviile, OH.
                                (8/14/75 to 9/2/75).

-------
 STATE:   OHIO

 Monitor  Name:  Sandusky River near Upper  Sandusky
 USGS I.D. ;  04 196 500  Latitude: 40  51 02  Longitude:  83  15  23

 Stream Gage Name:  Same
 USGS I.D. :  Same	  Latitude: Same      Longitude:  Same

 Rain Gage:  Upper Sandusky
 Weather Bureau I.P.:  8534

 Daily Data Analysis Results:  Water Years 1972-76 were  examined.
   The probability of low D.O. with high  flow reached 60 per-
   cent in 1973 and exceeded 60 percent in 1976.  The proba-
   bility of low D.O. on days with rainfall exceeded 60 percent
   in 1974, 75 and 76.  D.O. levels were  generally in the  70-
   75 percent of saturation range.  Periods when low D.O.
   occurs at times of both flow and rainfall can be clearly
   identified on the daily plots.

 Quality of Records:  The monitor is visited once a month or
   more.  The flow record is continuous.  The monitor record
   has minor interruptions occasionally but these are in-
   frequent and of short duration.

 Discharge Characteristics:  Average flow  250 cfs, range 10-
   10,000 cfs

 Drainage Area at Monitor:  298 square miles

 Urban Area(s)  Contributing at Monitor:  Bucyrus, Upper San-
   dusky, approximate population 13,000 and 7500 respectively

 Approximate Urban Area Contributing at Monitor:   3 square
   miles or 1 percent of total

 Results of Streeter-Phelps Analysis;  The results of the analy-
   sis are shown in Figure D-29.  The storm flow from Bucyrus
   could conceivably cause a 3-4 mg/1 deficit at Upper  Sandusky.
   The monitor is not in a good position  to sense the effect of
   either town.

Hourly Data Analysis Results;  The period analyzed is illus-
   trated in Figure D-30. There is clear evidence that a
   rainfall event followed by a flow increase is accompanied
   by an increase in D.O. deficit. The period examined
   contained one severe deficit where the D.O.  level fell
   to less than 1 mg/1.

 Conclusions and Comments:  There is clear evidence of a problem
   here"The exact cause is not obvious, although it probably
   originates at Bucyrus.  The monitor is rather poorly located


                              213

-------
   15.0
   10.0 ..
H
ui
Q

O
a
    5.0 ..
                             =L9X>7_mg/l_
           SATURATJON
       BUCYRUS
            30

      FLOW, MON.
   STP

UPPER SANDUSKY
                                                                STORn/|
                                        DISTANCE, mi
   Figure D-29. Streeter-Phelps analysis for Sandusky R. near Upper Sandusky, OH.

-------
                       o
                       a
                            20 ,.
                             10
                                                                    SATURATION DO LEVEL
Ul
                                                                          DISCHARGE / AVG. DISCHARGE
                                                      6      8      10     12      14



                                                     TIME FROM START OF PERIOD, days
16
                                                                                                 18
               20
                                  Figure D-30. Hourly data for Sandusky R. near Upper Sandusky, OH.

                                                        (8/6/73 to 8/25/73).

-------
in a Streeter-Phelps sense but still picks  up  the problem.
This site would also be worth examining more  closely.   In
an independent study, Ohio State University indicated  that
poor treatment facilities at Bucyrus may cause problems in
the Sandusky.
                          216

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STATE:  OHIO

Monitor Name:  Scioto River at Chillicothe
USGS I.D.;   03 '231 500  Latitude: 39 20 29  Longitude:  82 58 16

Stream Gage Name:   Same
USGS I.D.:     Same	  Latitude:   Same    Longitude:    Same

Rain Gage:   Chillicothe-Mound City
Weather Bureau I.P.;  1528

Daily Data Analysis Results:  Water years 1972-1976 were ex-
   amined.   The probability of low D.O. with high flow ex-
   ceeded 50 percent all five years and exceeded 60 percent
   in 1972.  The probability of low D.O. or days with rainfall
   exceeded 60 percent in 1976.  D.O. levels are generally
   in the 40 to 60 percent of saturation range.  Periods of
   low D.O. which coincide with flow and rainfall events can
   be clearly identified on the daily data plots.

Quality of Records;  The monitor is visited once a month or
   more.  The flow record is continuous and the monitor
   record is very good.  Only isolated periods of a few
   days are missing.

Discharge Characteristics:  Average flow 35,000 cfs, range
   500-50,000 cfs

Drainage Area at Monitor:  3850 square miles

Urban Area(s) Contributing at Monitor;  Columbus, approximate
   population 1,069,000

Approximate Urban Area Contributing at Monitor;  22 square
   miles or 1 percent of total


Results  of Streeter-Phelps Analysis;   The  results  of the  analy-
    sis  are  shown  in FigureD^Sl.ft is theoretically  possible
    for  storm  flow from Columbus  to create  a  3-4  mg/1 deficit
    at' Chillicothe.  'The  monitor  is  poorly  located.  It would
    probably see nearly twice  the deficit if  it were at Circle-
    ville,  halfway between Columbus  and Chillicothe.

Hourly Data Analysis Results;  The period examined is illus-
   trated in Figure D-32.There is clear evidence of a corre-
   lation between both rainfall and flow and increased D.O.
   deficit.  In one storm event, the D.O. drops very near zero.
   This violates the EPA suggested 2.0 mg/1 for 4.0 hours
   standard.
                             217

-------
                              15.0 T
to
M
00
                              10.0 ..
                           LU
                           Q
                           O
                           Q
                                      SATURATION AT 27°C = 8.07 mg/l
                                                 20      30      40      50      60      70      8(
                                   COLUMBUS
CHILLICOTHE

MONITOR
                                     Figure D-31. Streeter-Phelps analysis for Scioto R. at Chillicothe, OH.

-------
o
Q
     20 ,.
      10 ..
                                                           SATURATION DO LEVEL
     3.0 ,
                                                        DISCHARGE / AVG. DISCHARGE
8    10    12    14   16   18   20


 TIME FROM START OF PERIOD, days
                                                                 22    24   26   28   30
               Figure D-32. Hourly data for Scioto R. at Chillicothe, OH.

                                 (8/1772 to 8/30/72).

-------
Conclusions and Comments:   This is a good example of a site
   with a definite storm runoff related problem.   It would
   definitely merit further study.  One Sutron engineer
   worked with USGS in Columbus and is familiar with the
   Chillicothe monitor.  He states that the diurnal oxygen
   variations are due to heavy algal growth in the channel.
   He also indicates that Columbus often flushes  the
   trickling filters at the treatment plant during storm
   flows.  Conversations with Columbus treatment facility
   operators indicate that storm flow bypassing does occur.
                           220

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STATE:   OREGON

Monitor Name:  South Umpqua River near Roseburg
USGS I.D.:   14 312 260  Latitude: 43 13 20  Longitude: 123 24 45

Stream Gage Name:  South Umpqua River near Brockway
USGS I.P.;   14 312 OOP  Latitude: 43 08 00  Longitude: 123 23 50

Rain Gage:   Roseburg KQEN
Weather Bureau I.P.:  7331

Daily Pata Analysis Results;  Water years 1972-1976 were ex--
   amined.   The probability of low P.O. with high flow reached
   63 percent in 1976 and reached 57 and 56 percent in 1972
   and 1973 respectively.  The probability of low P.O. on
   days with rainfall never exceeded 50 percent.  P.O. levels
   are generally high, averaging 80 to 87 percent saturation.

Quality of Records:  The monitor is visited once a month or
   more.  The flow and monitor records are both intermittent
   in the winter but are generally good.

Pischarge Characteristics;  Average flow 3,000 cfs, range 50
   to 40,000 cfs

Prainage Area at Monitor:  1800 square miles

Urban Area(s)  Contributing at Monitor:  Winston, Roseburg,
   approximate combined population of 65,000 or more

Approximate Urban Area Contributing at Monitor:  9 square
   miles or 1 percent of total

Results of Streeter-Phelps Analysis;  Not performed at this
   site.

Hourly Pata Analysis Results;  The period examined is illus-
   trated in Figure P-33.  There is clear evidence of an
   increased P.O. deficit accompanying an increase in flow.
   There is no real problem in a quality sense, as the P.O.
   remains above 8 mg/1 at all times.

Conclusions and Comments:  There is no doubt that something
   happens here.  Periods of low P.O. at times of high flow
   can be clearly identified on the daily data plots.   Based
   on other sites, the monitor would probably see a greater
   deficit were it located 20 miles further downstream.   The
   low magnitude of the deficits do not appear to merit fur-
   ther study.
                              221

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      20  ,.
O
Q
      10 .«
                                   SATURATION DO LEVEL
                                  _—•	-

                                  -fT—	~_

                                   DO LEVEL
O
t—

5
O

i
•O

O
Q


13
<
cc
<
x
     3.0 T
     2.5 ::
     2.0 ::
     1.5 ::
     1.0 ::
     0.5 ::
     0.0
                                       DISCHARGE / AVG. DISCHARGE
                                       DO DEFICIT/10, mg/l
                               6       8      10      12


                             TIME FROM START OF PERIOD, days
                                                             14
                                                                     16
                                                                             18
                                                                                    20
          Figure D-33. Hourly data for South Umpqua R. near Brockway, OR.

                                  (3/1776 to 4/6/76)

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STATE:   PENNS YLVANIA-

Monitor Name;  Delaware River at Bristol
USGS I.D.:   01 464 &00  Latitude: 40 05 55  Longitude:  74 51 58

Stream Gage Name;   Delaware River at Trenton,  New Jersey
USGS I.D.:   01 463 500  Latitude: 40 13 18  Longitude:  74 46 42

Rain Gage;   Trenton
Weather Bureau I.P.:   8883

Daily Data Analysis Results;  Water years 1972-1976 were ex-
   amined.   The probability of low D.O. at times of high flow
   exceeded 50 percent all years.  It reached  71 percent in
   1975.  Average  D.O. levels ranged from 65 to 85 percent
   of saturation.

Quality of Records;  The monitor is visited once a month or
   more.  Records  in the summer for the monitor are very bad
   with as much as two months missing.  The flow record is
   continuous.

Discharge  Characteristics:  Average flow 12,000 cfs,  range
   200-32,500 cfs

Drainage Area at Monitor:  7163 square miles

Urban Area(s) Contributing at Monitor:  Trenton, Levitown,
   Bristol, Bordentown, PA, and suburbs, population greater
   than 1/2 million

Approximate Urban Area Contributing at Monitor:  65 square
   miles or 1 percent of total

Results of Streeter-Phelps Analysis;  Not performed at  this
   site.

Hourly Data Analysis Results:  Hourly  flow data were not
   available.  The Trenton daily flows are plotted with the
   hourly D.O. and D.O. saturation data in Figure D-34.
   There is clearly an increase in D.O. deficit with in-
   creased flow.  There is no real water quality problem,
   however, as the D.O. never falls below 8 mg/1.

Conclusions and Comments;  The Trenton area forms the up-
   stream end of a large urban megalopolis. Water quality
   deteriorates steadily from here to Philadelphia and
   below.   The problem here is not bad enough to warrant
   further study.
                               223

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                           O
                           D
                                20 -r
                                                                SATURATION DO LEVEL
                                                                DO LEVEL
to
tsJ
                           a

                           i
                           Q
                           CJ
                          UJ
                          O
                          tt
                          <
                          I
                          CJ
3.0


2.5  ::


2.0  ::


1.5  ::


1.0  ::


o.s  ::


0.0
                                                                     DISCHARGE / AVG. DISCHARGE
                                                                     DO DEFICIT / 10, mg/l
                                                           6       8      10      12      14

                                                          TIME FROM START OF PERIOD, days
                                                                   16
                                                                                                          18
                                                                                   20
                                               F/aure D-34. Hourly data for Delaware R, at Bristol, PA.
                                                                 (4/20/75 to 5/9/75)

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STATE:  PENNSYLVANIA

Monitor Name:  Delaware River at Chester
USGS I.p.:  01 464 600  Latitude: 40 05 55  Longitude: 74 51 58

Stream Gage Name:  Delaware River at Trenton, New Jersey
USGS I.D. .-  01 463 500  Latitude: 40 13 18  Longitude: 74 46 42

Rain Gage:  Philadelphia WB APT
Weather Bureau I.P.;  6889

Daily Data Analysis Results:  Water years 1972-1976 were ex-
   amined.  The probability of low D.O. with high flow ex-
   ceeded 50 percent in 1973, 1974, and 1976, reaching a
   peak of 67 percent in 1973.  D.O. levels average 65 to
   75 percent of saturation.

Quality of Records:  The monitor is visited once a month or
   more.  Flow records are continuous.  Monitor records are
   highly intermittent with roughly 1/3 of each month missing.

Discharge Characteristics:  Average flow 12,000 cfs, range
   1200-32,500 cfs

Drainage Area at Monitor:  10,300 square miles

Urban Area(s) Contributing at Monitor:  Trenton, New Jersey,
   Philadelphia metropolitan area

Approximate Urban Area Contributing at Monitor:  Greater than
   100 square miles but less than 2 percent of total

Results of Streeter-Phelps Analysis:  Not performed at this
   site

Hourly Data Analysis Results:  Hourly flow data were not
   available here.The hourly D.O. and D.O. saturation
   values are plotted with the Trenton, New Jersey, daily
   flows in Figure D-35.  The D.O. level drops to less than
   5 mg/1 as the flow increases for the period examined.
   The relationship is not as pronounced as at other sites.

Conclusions and Comments:  There is evidence of a correla-
   tion here.The fact that the D.O. can be driven down
   4 mg/1 by a drainage area which represents less than
   2 percent of the total speaks for the potency of the
   runoff here.   This is a very large river and the changes
   are much slower in a time sense than at other locations.
   This is probably too large and complex a site to study
   effectively at reasonable cost.
                              225

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                               20 ,.
                          O
                          Q
                               10 ..
                                                  SATURATION DO LEVEL
                                                  DO LEVEL
CTi
                          •s
                          T3
                          O
                          Q

                          a
                          O
                          LU
                          C3
                          cc
                               3.0 ^
2.5 ::
2.0 ::
                                           DISCHARGE / AVG. DISCHARGE
                                                          6       8      10      12      14

                                                       TIME FROM START OF PERIOD, days
                                                                 16
                                                                                                                20
                                            Figure D-35. Hourly data for Delaware R. at Chester, PA.
                                                             (2/26/73 to 3/17/73).

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STATE:  PENNSYLVANIA

Monitor Name;  Lehigh River at Easton
USGS I.D.;  01 454 720  Latitude: 40 41 12  Longitude: 75 12 32

Stream Gage Name:  Lehigh River at Glendon
USGS I.P.;  01 454 700  Latitude: 40 40 09  Longitude: 75 14 12

Rain Gage:  Allentown WB APT
Weather Bureau I.P.;  0106

Paily Data Analysis Results:  Water years 1972-1976 were ex-
   amined.  The probability of low D.O. with high flow reached
   53 percent in 1972 but averaged 35 to 40 percent.  The
   probability of low D.O. on days with rainfall exceeded
   60 percent every year but 1974.  That year it was 57 per-
   cent.  D.O. levels in general are good, averaging 75 to
   85 percent saturation.  Periods of low D.O. at times of
   rianfall are discernable on the daily data plots.

Quality of Records:  The monitor is visited once a month or
   more.  Flow records are continuous.  The monitor record
   exhibits intermittent missing periods of a week or less.

Discharge Characteristics:  Average flow 3,000 cfs, range
   1500-16,000 cfs

Drainage Area at Monitor:  1360 square miles

Urban Area(s) Contributing at Monitor:  Allentown, Bethlehem,
   population approximately 610,000 and 71,500 respectively.

Approximate Urban Area Contributing at Monitor:  25 square
   miles or 2 percent of total

Results of Streeter-Phelps Analysis:  The results of the
   analysis are shown in Figure  D-36.  Theoretically, storm
   flow from Allentown-Bethlehem could produce a deficit of
   3-4 mg/1 at Easton.  The monitor could not be located at
   the sag point under any circumstances because the Lehigh
   joins the Delaware at Easton.

Hourly Data Analysis Records:  The period examined is illus-
   trated in Figure  D-37.  The results do not clearly show
   anything.  The D.O. deficit appears to reach a maximum
   between the first and second rainfall events.  As the
   flow increases, the D.O. level improves, nearly reaching
   saturation at one point.  This type of behavior can also
   be seen on the daily plots.  The deficit nears the 5 mg/1
   level at its worst.
                              227

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M
                              15.0 ,.
                              10.0 ..
                           I
                           O
                           H
                           Ul
                           Q
                           O
                           Q
                               5.0 ..
                                     _ SAJURATION AT_27°C =^8.07jng/l
                                       "          ~   ^CsZJiamlS/r
                                   EDGE
                                   OF
                                   ALLENTOWN
2.0       4.0

 ALLENTOWN
                                                                      8.0      10.0
                                                                       DISTANCE, mi
                                                                     BETHLEHEM
                                                                                        12.0
                                                                                                 14.0
                                                                                                           16.0
                                                                   EDGE
                                                                   OF
                                                                   EASTON
T 18.0

 MONITOR
                                       Figure D-36. Streeter-Phelps analysis for Lehigh R. at Easton, PA.

-------
                           o
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                                 20  „
                                 10
                                                     SATURATION DO LEVEL
NO
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                            LLJ
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                            o
                            CO
                                 3.0 T
                                 2.5 ::
                                 2.0 ::
                                                                                 DISCHARGE / AVG. DISCHARGE
                                            2       4        6       8       10      12      14      16

                                                         TIME FROM START OF PERIOD, days
                                                                              18      20
                                             Figure D-37. Hourly data for Lehigh R. at Easton, PA.
                                                             (8/1776 to 8/20/76).

-------
Conclusions and Comments;   There does not appear to be a
   real problem at this site, even though Streeter-Phelps
   indicates one could theoretically exist.   Water quality
   is generally good.  The D.O.  generally increases with
   increased flow.  It would be interesting  to see why the
   D.O. seems to consistently be low at times of rainfall.
   The cause is not obvious.
                           230

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STATE:  PENNSYLVANIA

Monitor Name:  Schuylkill River at Philadelphia
USGS I.P.;  01 474 500  Latitude: 39 58 00  Longitude:  75 11 20

Stream Gage Name:  Same
USGS I.P.:    Same      Latitude:   Same    Longitude:    Same

Rain Gage;  Western Philadelphia, Drexel Institude of Technology
Weather Bureau I.P.;  6879

Daily Data Analysis Results:  Water years 1969-1972 were ex-
   amined.  The probability of low D.O. with high flow  reached
   61 percent in 1972.  D.O. levels averaged 60 to 70 percent
   of saturation.

Quality of Records:  The monitor is visited once a month or
   more.  The flow record is continuous.  The monitor record
   is fair with periods of up to one month missing, generally
   in the summer.

Discharge Characteristics:  Average flow 1900 cfs, range 0-
   100,000 cfs

Drainage Area at Monitor:  1893 square miles

Urban Area(s) Contributing at Monitor:  Philadelphia and
   suburbs

Approximate Urban Area Contributing at Monitor;  40  square
   miles or 2 percent of total

Results of Streeter-Phelps Analysis:  Not performed at  this
   site

Hourly Data Analysis Results;  The period examined is illus-
   trated in Figure D-38.There is clear evidence of a D.O.
   deficit increase at the time of the flow event.  The
   correlation between the rainfall and increase in flow is
   also clear.  The D.O. drops below 5 mg/1 during the  event
   shown.

Conclusions and Comments:  There is clear evidence of a cor-
   relation here.  The monitor is probably not in the best
   location based on similar sites elsewhere.  Unfortunately,
   it could only be moved 4 or 5 miles downstream, as the
   Schuylkill joins the Delaware there.  The junction is
   just above the Delaware at Chester monitor which is  dis-
   cussed elsewhere.  There is no question of urban area
   here, but other sites would be simpler hydraulically for
   detailed studies.
                              231

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                               20 T
NJ
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                         O
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                         .S
                          u
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O
                         ui
                         O
                         K
                         <
                         U
                         CO
                                   SATURATION DO LEVEL
                                          DISCHARGE / AVG. DISCHARGE
                                                        6       8      10      12

                                                      TIME FROM START OF PERIOD, days
                                       Figure D-38. Hourly data for Schuylkil! R. at Philadelphia, PA.
                                                           (8/19/72 to 9/7/72).

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STATE:  TEXAS

Monitor Name:  Trinity River below Dallas
USGS I.D.:  08 057 410  Latitude: 32 42 27  Longitude: 96 44 Qi
                                    Same
                Longitude:   Same
Stream Gage Name:  Same
USGS I.P.;    Same      Latitude:

Rain Gage:  Dallas FAA APT
Weather Bureau I.P.:  2244
Daily Data Analysis Results:  Only water year 1977 was avail-
   able, as the stream has not been monitored long.  A 60
   percent probability of low D.O. at high flow was computed.
   The dissolved oxygen level averaged an extremely low 26
   percent of saturation.

Quality of Records:  The monitor was serviced once a month or
   more.  The flow record is continuous for the entire year.
   The monitor record was highly intermittent in the summer.
Pischarge Characteristics:
   1,000-8,000 cfs
Average flow 2,000 cfs,  range
Drainage Area at Monitor:  6278 square miles

Urban Area(s) Contributing at Monitor:  Dallas-Fort Worth
   Metropolitan Area

Approximate Urban Area Contributing at Monitor;   724 square
   miles or 12 percent of total

Results of Streeter-Phelps Analysis;  Not performed at this
   site

Hourly Data Analysis Results:  Two sets of hourly data were
   examined for the Dallas gage as well as one for the
   Trinity River at Rosser, Texas.  Rosser is some 40 miles
   south of Dallas and seemed to be in a better  position to
   sense a deficit in the Streeter-Phelps sense.  All three
   data sets are illustrated in Figures D-39, D-40, and D-41.
   There is no doubt that a problem exists here.  The flow
   of the Trinity is almost all treated sewage under low
   flow conditions.  The D.O. is often zero during flow
   events.  Note that even at Rosser the D.O. goes to zero
   with a flow event.

Conclusions and Comments:  The Trinity River below Dallas
   has some of the worst water quality encountered anywhere
   in this study.  During summer low flow periods, the river
   is primarily treated sewage effluent.  It would be par-
                              233

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                              20 T
                        O
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                              10 ..
SATURATION DO LEVEL
                                                 DO LEVEL
                              3.0 T
to
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                         I
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                         (D


                         O
                         (S
                         til
                         O
                         oc
                         <

                         8
                         a
                                                        DISCHARGE / AVG. DISCHARGE
    8    10    12    14   16   18    20


    TIME FROM START OF PERIOD, days
                                                                                         22    24   26   28
                                                                                                             30
                                          Fiaure D-39. Hourly data for Trinity R. below Dallas, TX.

                                                           (5/21/77 to 6/19/77).

-------
                               20 ,.
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                              10 ..
                        SATURATION DO LEVEL
to
CO
                         O
                         Q
i
                         <
                         CD
                         CC
                         <

                         O
                         CO
                                                                               DISCHARGE / AVG. DISCHARGE
                                                                4               6


                                                      TIME FROM START OF PERIOD, days
                                         Figure D-40. Hourly data for Trinity R. near Rosser, TX.

                                                           (9/4/77 to 9/13/77).

-------
                           20 „
                       o
                       a
                           10 .
                     SATURATION DO LEVEL
                                           ?t'%>*^^
CO
CTl
o

£
•o
O
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C3

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la
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CD
                      m
                      O
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                      GO
                                                 DISCHARGE / AVG. DISCHARGE
                                               8   10   12   14   16   18   20

                                                TIME FROM START OF PERIOD, days
                                                        22   24   26    28   30
                                    Figure D-41. Hourly data for Trinity R. below Dallas, TX.
                                                    (9/1777 to 9/30/77).

-------
ticularly interesting to see exactly what causes the
D.O. to go to zero when flow increases.  This is perhaps
a reintrainment of oxygen demanding material.  The urban
area involved is very large and a rather expensive samp-
ling program might be required to adequately define the
problem.
                           237

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
  REPORT NO.
     EPA-600/2-79-156
                                                           3. RECIPIENT'S ACCESSION-NO.
 4. TITLE AND SUBTITLE
                                    5. REPORT DATE
                                     November  1979
                                                                           (Issuing Date)
     DISSOLVED OXYGEN IMPACT FROM URBAN  STORM RUNOFF
                                                           6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
     Thomas  N.  Keefer,  Robert K. Simons, and Raul  S,
     McQuivey
                                                           8. PERFORMING ORGANIZATION REPORT NO.
 9. PERFORMING ORGANIZATION NAME AND ADDRESS
     The Sutron Corporation
     1925 North Lynn Street  Suite 700
     Arlington, Virginia   22209
                                    10. PROGRAM ELEMENT NO.
                                         1BC822
                                    11. CONTRACT/GRANT NO.
                                       No.  68-03-2630
 12. SPONSORING AGENCY NAME AND ADDRESS
     Municipal Environmental Research Laboratory—Gin.,OH
     Office of Research and Development
     U.S.  Environmental Protection Agency
     Cincinnati, Ohio    45268
                                    13. TYPE OF REPORT AND PERIOD COVERED
                                    Final 11-18-77 thru  5-1-79
                                    14. SPONSORING AGENCY CODE
                                       EPA/600/14
 15. SUPPLEMENTARY NOTES
     Project Officer:
John N. English  513/684-7613
 16. ABSTRACT  The primary objective of the research reported nere is to determine if
     on a national basis a correlation  exists  between strength of dissolved  oxygen
     (DO) deficits and the presence of  rainfall  and/or storm runoff downstream of
     urban areas.  A secondary objective is  to estimate the magnitude  and extent of
     the problem.

     One hundred and four water quality monitoring sites in and downstream of urban
     areas throughout the country were  considered for inclusion in the study.   These
     were screened from over 1000 monitors maintained by federal and state agencies
     such as the U.S. Geological Survey, Environmental Protection Agency  (EPA), Ohio
     River Valley Sanitation Commission and  Wisconsin Department of Natural  Resources.
     Daily data were obtained and processed  for  83 of the 104 candidate sites.   Of the
     83 monitors considered, 42 percent or roughly four monitors in ten of the 104
     candidates demonstrated a 60 percent or greater probability of a higher than
     average DO deficit occurring at times of  higher-than-average stream  flow or on
     days with rainfall.  In general, the data examined here indicate that 19 percent
     of the 104 candidate monitors might not meet a 5.0-mg/l standard and 15 percent
     might not meet a 2.0-mg/l standard.  Frequency of violations was not tabulated
     exactly but appears to be zero to  five  times per year at sites with
 	correlations.	
                               KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                             b.IDENTIFIERS/OPEN ENDED TERMS
                                                                          COSATI Field/Group
      Rainfall
     •-Surface Water Run off
      Combined Sewers
      Water Pollution
     *Water Quality
                          ^Dissolved Oxygen
                           Urban Runoff
                          "Streeter-Phelps"
      13B
                EMENT
     RELEASE TO PUBLIC
                                             19. SECURITY CLASS (ThisReport)
                                                 Unclassified
                                                 21. NO. OF PAGES
                                                       250
                      2O. SECURITY CLASS (Thispage)
                          Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
                                           238
                                                                      SUSGPO: 1980-657-146//5513

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