-------
TABLE D
TOXICITY VALUE ADJUSTMENTS
(DERMAL EXPOSURES)
Adjwttd
Toxlclty tased on Absorption Toxicity
Vslue (IfD) Absorb. (AM)/ Study Efficiency Value
Cheeriest (ao/kg-day) Aotatn. (ADM) Specie* In Species (Bo/kg-day)
Chronic Exposure*
Antlaeny
Arsenic
Beryllium
Cadaiua
Chromium
•ickel
Seleniua
Thallium
Zinc
1.1-Dichloroethene
1,1-Dichloroethene
TetraeMoroether*
1,1,1-trichloroethane
Subchronic Exposures
Antieony
Arsenic
Beryllium
Caomium
Chromium
•ickel
Selenium
Thellium
Zinc
1,1-DicMoroethane
1.1-Oichloroethcne
Tetrechloroethene
1.1 , 1-tr ichloroethane
4E-04
IE-OS
SE-03
SE-04
SE-03
2E-02
SE-03
7E-OS
2E-01
1E-01
9E-03
1E-02
9E-02
4E-04
IE-OS
SE-03
SE-04
2E-02
2E-02
SE-03
7E-04
2E-01
1E*00
9E-03
1E-01
9E-01
ADM
ADM
ADM
ASS
ADM
ADM
ADM
ADM
ADM
ADM
ADM
ADM .
AM
ADM
ADM
ADM
ASS
ADM
ADM
ADM
ADM
ADM
ADM
ADM
ADM
AM
rat
kuMBn
ret
human
rat
rat
hUBan
rat
town
rat
rat
•DUS*
guinea pig
.05 2E-
.95 IE-
05
03
.01 SE-05
.03 2£-
.01 2E-
-
04
04
.90 SE-OS
.05 4E-
06
.20 4E-02
.50 5E-
02
.00 9E-03
.00 IE-
02
•
rat O.OS 2E-05
human 0.95 IE-
03
rat 0.01 SE-05
huBtn
-
rat 0.03 6E-04
rat 0.01 2E-
fcvMn 0.90 SE-
rat O.OS 4E-
kumen 0.20 4E-
rat O.SO SE-
rat 1
04
OS
05
02
01
.00 9E-OS
•ouse 1.00 1E-
•ulnea pig
01
.
-------
TABLE E
NL Industries: Carcinogenic and Noncarcinogenic Risk Summary Tables
P A T H W A
Receptor
Future
Off-site
Child
Off-site
Adult
Off-site
Worker
On-site
Child
On-site
Adult
On-site
Worker
Risk
Index
Ca
HI
Ca
HI
Ca
HI
Ca
HI
Ca
HI
Ca
HI
Soil
Ingestion
8E-7
2.4E-3
1E-6
2E-3
9E-7
2E-3
9E-6
•
1.3
2E-6
0.05
2E-6
0.05
Soil
Dermal
i
9E-8
4.1E-3
2E-7
2E-3
2E-7
4E-3
2E-6
4.7
3E-7
0.16
3E-7
0.16
Air
(Inhal.)
7E-6
5E-6
3E-6
Ground
Water
Ingestion
5E-4
15.78
2E-3
11
9E-4
3.81
IE- 3
17.32
2E-3
10.0
Ground
Water
Dermal
9E-6
0.35
8E-5
4E-1
2E-5
0.49
8E-5
0.40
Ground
Water
Inhalation
3E-4
0.09
IE- 3
1.0
6E-4
0.10
IE- 3
0.50
"Ca" indicates lifetime cancer risk."HI" indicates the Hazard Index for noncancer risk.
* A blank box indicates that this exposure pathway was not complete, and therefore, not
calculated.
** Bold-face type indicates exceedance of either EPA's acceptable Hazard Index of 1.0 or
of EPA's lower threshold for Carcinogenic Risk of 1 x 10"*.
-------
TABLE E
NL Industries: Carcinogenic and Noncarcinogenic Risk Summary Tables
T
H
W
Receptor
current
Off-site
Child
Off-site
Adult
Off-site
Worker
Risk
Index
Ca
HI
Ca
HI
Ca
HI
Soil
Ingestion
3E-8
2.4E-3
1E-6
2E-3
9E-7
1.7E-3
Soil
Dermal
3E-9
4.1E-3
2E-7
2E-3
2E-7
3 . 6E-3
Air
(Inhal.)
Ground
Water
Ingestion
Ground
Water
Dermal
Ground
Water
Inhalation
"Ca" indicates lifetime cancer risk. "HI" indicates the Hazard Index for noncancer risk.
* A blank box indicates that this exposure pathway was not complete, and therefore, not
calculated.
** Bold-face type indicates exceedance of either EPA's acceptable Hazard Index of 1.0 or
of EPA's lower threshold for carcinogenic Risk of 1 x 10"*.
-------
TABLE F
NL INDUSTRIES SITE
GROUND WATER ARARS
NJMCL1 NJGWQS2
PQL3
HAZARDOUS CONTAMINANT
MCL4
Organic (ppb)
Acetone
Bis-(2-ethylhexyl)phthalate 4
Chloroform
1,2-Dibromomethane
1,1-Dichloroethane
1,1-Dichloroethylene 2
1,2-Dichloropropane 5
Ethylbenzene 700
Naphthalene
N-Nitroso-di-n-propylantine
Tetrachloroethylene l
Toluene 1,000
1,1,1-Trichloroethane 2 6
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride 2
Xylene(s) (total) 44
o-
ro&p-
700
3
6
70
1
0.5
700
i.
0.005
0.4
1,000
30
0.08
40
NA
NA
NA
30
1
2
1
5
20
1
5
1
5
2
1
2
7
5
700
5
1,000
200
2
10,000
1New Jersey Maximum Contaminant Levels (NJMCLs) are expressed In ppb. (N.J.A.C 7:10-16.7) For any listed contaminant,
the more stringent of the NJMCL, NJGWQS, or federal MCL applies.
2New Jersey Ground Water Quality Standards (NJGWQS) (N.JAC. 7:&€) are expressed in parts per billion (ppb).
3 The Practical Quantitation Levels (PQLs) are expressed in ppb. In accordance with N.JAC. 7:9-6.9(c), where a constituent
standard (the criterion adjusted by the antidegredation policy and applicable criteria exemptions) is of a lower concentration
than the relevant PQL, the Department shall not On the context of an applicable regulatory program) consider the discharge to
be causing a contravention of that constituent standard so long as the concentration of the constituent in the affected ground
water is less than the relevant PQL
4Federal Maximum Contaminant Levels (MCLs) are expressed in ppb. For any listed contaminant, the more stringent of the
federal MCL, NJMCL, and the NJGWQS applies.
-------
TABLE F (Cont'd)
NL INDUSTRIES SITE
GROUND WATER RRARS
HAZARDOUS CONTAMINANT
NJMCL1
NJGWQS2
PQL3
MCL4
Metals fppb)
Antimony
Arsenic (total)
Beryllium
Cadmium
Chromium (total)
Copper
Cyanide
Lead (total)
Mercury (total)
Nickel (soluble salts)
Selenium (total)
Silver
Thallium
Zinc
Radiation (see footnotes 4 & 5 for units)
6
50
4
5
100
1,300*
200
15*
2
100
50
-
2
-
2
0.02
0.008
4
100
1,000,
200
5
2
100
50
NA
0.5
5,000
20
8
20
2
10
1,000
40
10
0
10
10
2
10
30
Gross Alpha
Gross Beta
155
46
6
50
4
5
100
200
2
100
50
155
15s
46
* New Jersey Action Level
5Federal MCL expressed in picocuries/Iiter (pC/l). From 40 CFR part 141.
6Federal MCL expressed in picocuries/Iiter (pC/l). From 40 CFR part 141.
-------
NL Industries Equivalent - Page 7 of 15
TABLE Gl
PERMIT EQUIVALENT SUMMARY - TABLE I
OUTFALL 001
Facility: NL Industries Superfund Site Latitude: 39° 45' 40" N Longitude: 75°
Type of Wastewater: Treated Grounduater Average Flow: 250 GPM Discharged to:
UORST
CASE
INFLUENT
PARAMETER DATA
All values are in ug/l
unless otherwise stated
WATER
QUALITY TECHNOLOGY METHOD EPA
BASED EASED DETECTION METHOD
LIMITS LIMITS LEVEL NUMBER
NON DAY NON DAY (UQ/l)
AVG MAX AVG MAX
25' 20" U
West or East stream
PERMIT
EOUIVALEMT
EFFLUENT
LIMIT
NON DAY
AVG MAX
CONVENTIONAL AND NON-CONVENTIONAL POLLUTANTS
Flow (Million Gallons/Day) 0.360
BODS (rog/t)
Chloride (mg/l) 150
(kg/day)
Dissolved Oxygen (mg/l)
pH (standard units)
Petroleum Hydrocarbons (mg/l)
Sulfate (mg/l) 24000
(kg/day)
Total Dissolved Solids (mg/l)
(kg/day)
Total Organic Carbon (mg/l)
Total Suspended Solids (mg/l)
(kg/day)
Chronic Toxieity (X effluent)
VOLATILE COMPOUNDS
Bromodichloromethane 6.3
(kg/day)
Chloroform 13
(kg/day)
1,1-Dichloroethane 74
1,2-Dichloroethane 22
(kg/day)
1,1-Dichloroethylene 210 •
(kg/day)
Tetrachloroethylene 210
(kg/day)
1,1,1-Trichloroethane 4700
Vinyl Chloride 76
(kg/day)
.
25 (1)
250
340
5.0 minimum -
6.0 min 9.0
10 15 (2)
250
340
500
680
50 (3)
40
54
NOEC > 100 (4) - -
0.27 0.54 - - 0.1 601
0.00037 0.00074
5.7 11
0.007B 0.015
5.0 10 (5)
0.3B 0.76 - • 0.03 601
0.00052 0.0010
0.57 1.1 - - 0.13 601
0.00078 0.0015
8.0 16
0.011 0.022
21 54 (6) -
2.0 4.0 - • 0.18 601
0.0027 0.0054
0.360 Report
Report 25 (1)
Report 250
340
5.0 minimum
6.0 min 9.0
10 (2) 15 (2)
Report 250
340
Report 500
680
Report 50 (3)
Report 40
54
NOEC > 100 (4)
0.27 0.54
0.00037 0.00074
5.7 11
0.0078 0.015
5.0 (5) 10 (5)
0.38 0.76
0.00052 0.0010
0.57 1.1
0.00078 0.0015
8.0 16
0.011 0.022
21 (6) 54 (6)
2.0 4.0
0.0027 0.0054
-------
NL Industries Equivalent - Page 8 of 15
Permit Equivalent Sumary Table (continued) TABLE Gl (Cont'd)
IKKST
CASE
IHFLUE1
PARAMETER DATA
All values are in ug/l
unless otherwise stated
ACID AH) BASE/NEUTRAL COMPOUNDS
bis(Z-Ethylhexyl) Phthalate 13
(kg/day)
N-Nitrosodi-n-propylamine 11
METALS
Aluminum, total recoverable 69
Antimony, total recoverable 122
(kg/day)
Arsenic, total recoverable 18200
< kg/day)
Beryl Him, total recoverable 156
Cadmium, total recoverable 1010
(kg/day)
Chromiun. total recoverable 4340
(kg/day)
Cobalt, total recoverable 38
Copper, total recoverable 4680
(kg/day)
Iron, total recoverable 429
Lead, total recoverable 6290
(kg/day)
Manganese, total recoverable 3120
Mercury, total recoverable 0.6
(kg/day)
Nickel, total recoverable 2480
(kg/day)
Selenium, total recoverable 4
(kg/day)
Silver, total recoverable 44
(kg/day)
Thallium, total recoverable 3
(kg/day)
Zinc, total recoverable 9690
< kg/day)
iADianiCLlDES
VA1
out
rr BAS
LID
KM
AVG
18
0.024
•
-
14
0.019
0.018
0.000024
-
0.66
0.00090
8.0
0.011
-
5.9
0.0080
-
1.5
0.0020
•
0.0098
0.000013
90
0.12
4.1
0.0056
0.97
0.0013
1.7
0.0023
40
0.055
•ER
ILITT TECHWXOGT METHOD
H> BASED DETECTION
UTS LIMITS LEVEL
OAT KM DAT (ug/l)
MX AVG MAX
36 5.0 10 (5)
0.048
0.5 1.0 (5) 0.46
75 150 (5)
28
0.038
0.036 - - 0.5
0.000048
0.5 1.0 (5) 0.3
1.3 - - 0.5
0.0018
16
0.022
10 20 (5)
12
0.016
100 200 (5)
3.0 - - 0.7
0.0040
100 200 (5)
0.020 - - 0.2
0.000026
180 50 100 (5)
0.24
8.2 - - 0.6
0.011
1.9 - - 0.5
0.0026
3.4 - - 0.7
0.0046
80
0.11
PERM1
EPA EQUIt
METHOD EFFU
NUMBER LINI1
KM
AVG
5.0 (5)
607 0.5 (5)
75 (5)
14
0.019
200.9 Report
-
200.8 0.5 (5)
200.8 0.66
0.00090
8.0
0.011
10 (5)
5.9
0.0080
100 (5)
200.9 1.5
0.0020
100 (5)
245.1 Report
-
50 (5)
200.9 4.1
0.0056
200.9 0.97
0.0013
200.9 1.7
0.0023
40
0.055
IT
rALEHT
EOT
r
DAT
MAX
10 (5)
1.0 (5)
150 (5)
28
0.038
0.036
-
1.0 (5)
1.3
0.0018
16
0.022
20 (5)
12
0.016
200 (5)
3.0
0.0040
200 (5)
0.020
•
100 (5)
8.2
0.011
1.9
0.0026
3.4
0.0046
80
0.11
Gross alpha
particle activity CpCi/l) 570+180
Gross beta
particle activity (pCi/l) 700+180
Conbined Radiun-226
and Radiun-228 (pCi/l)
100+10
15 (7)
50 (8)
5.0
Report 15 (7)
Report 50 (8)
Report 5.0
-------
NL Industries Equivalent - Page 9 of 15
Permit Equivalent Suiroary Table (continued)
TABLE Gl (Cont'd)
(1) Based on Minimum Treatment Requirements (N.J.A.C. 7:9-5.8} for the Delaware River Basin - FU2 waters.
(2) Based on Oil and Grease Effluent Limitations (N.J.A.C. 7:14A-14.1 et sea.): also, no visible sheen.
(3) Based on Use of Indicators of Pollution Levels (N.J.A.C. 7:9-5.5) and similar effluent limits for
discharges of treated grounduater into surface waters, which have been economically achievable.
(4) This limitation is equivalent to 1.0 TU (Chronic Toxic Units) maximum.
(5) Based on USEPA Water Engineering Research Laboratory (WERL) Treatability Database for similar discharges
and corresponding treatment technologies commonly used.
(6) Based on final USEPA Effluent Guidelines for the Organic Chemicals. Plastics and Synthetic Fibers (OCPSF)
point source category for discharges that use end-of-pipe biological treatment.
(7) Gross alpha particle activity including Radium-226, but excluding Radon and Uranium.
(5) Gross beta particle activity exceeding 50 pCi/l must be accompanied by a sample analysis identifying the
major radioactive constituents present and compliance with 40 CFR 141.16 (shall not produce an annual
dose equivalent to the total body or any internal organ greater than 4 miUirems/year).
-------
Table G2
ESTIMATED**
CHEMICAL-SPECIFIC ARARs & TBCs
FOR DISCHARGE TO THE
DELAWARE RIVER
Compound
Volatile Organic*
Acetone
Bis(2-ethylhexyl)phthalate
Chloroform
1,2-Dibromome thane
1,1-Dichloroethanc
1,1-Dichloroethylene
1,2-Dichloropropane
Ethylbenzene
Naphthalene
N-Niiroso-di-n-propylamine
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
Vinyl chloride
Xyienes (total)
Xylene (m & p)
o-Xytene
Inorganic Compounds
Antimony
Arsenic
Beryllium
Cadmium
Chloride
Chromium
Copper
Lead
Mercury
Maximum
Cone. Detected
in
Ground Water
0«g/l)
14
13
7
2
74
210
0.5
0.6
23
11
210
1.8
4,700
0.8
2.7
76
5.6
4
1.6
122
18,200
156
1,010
150,000
J4340
.14,680
6,290
0.6
Delaware River
Discharge
Zone 5
Saltwater0
(Hg/0
Criterion
Maximum
Cone.
69
43
1100
2.9
220
2.1
Criterion
Contin.
Cone.
•*
36
93
50
2.9
8.5
.025
1E-06
Human Health Risk:
Organisms
Only
5o«
470"
3^=
29,000*
8.85C
200,000*
170.000P
52SC
43001
O-M*"0
0.131P
n
n
n
.15
-------
Compound
Nickel
Silver
Sulfate
Thallium
Zinc
Maximum
Cone. Detected
in
Ground Water
(Mg/l)
2,480
37
25x10*
3
9,690
Delaware River
Discharge
ZoneS
Saltwater0
(Mg/1)
Criterion
Maximum
Cone.
75
23
95
Criterion
Contin.
Cone.
83
••*
86
1E-06
Human Health Risk:
Organisms
Only
4600
6.3a
Table G2
ESTIMATED**
CHEMICAL-SPECIFIC ARARs & TBCs
FOR DISCHARGE TO THE
DELAWARE RIVER
Note: The following conventional parameter limits must also be considered for discharge to the Delaware Riven
Parameter
BOD
COD
TDS
pH
TSS
Whole effluent toxitity
Estimated
Discharge
Limit
87% removal
No Limit
1,000 ppm or 133% of
background
concentration
6.0-8.5
45 ppm or 85% removal
Under development
Rationale
Delaware River Basin Commission (DRBC)
DRBC
DRBC
NJAC 7:9-4.
Maximum 7-day average: DRBC
NJDEPE
Treatability testing will determine the ability of a treatment system to meet these limits.
From the Federal Register/ Vol. 57, No. 246/ December 22,1992/ 60912-60922,40 CFR §13136
* Criteria revised to reflect current agency RfD, as contained in IRIS.
'The criteria refers to the inorganic form only.
'Criteria matrix based upon carcinogenaity of (10 E-06).
'Freshwater aquatic criteria expressed as a function of total hardness. Assumes hardness of 100 (mg/1) and water effects ration of 1.0.
"Criteria expressed as a function of the water effects ratio as defined in 40 CFR 13136(c).
"EPA is not promulgating human health criteria for this contaminant. Permit authorities should address this contaminant in NJPDES
permit.
"New Jersey Surface Water Quality Standards NJAC 7:9-4.1.
•"Federal Ambient Water Quality Criteria
** All final discharge values will be developed by NJDEPE through the issuance of a New Jersey Discharge Pollution Elimination
System permit.
— Value not available.
ND = Not Detected
-------
TAELEH
LISTOFAR4R3
Chemical-Specific ARARs:
RCRA. Identification of Hazardous Waste (40 CFR 261)
New Jersey Regulation for Hazardous Waste Identification (NJAC 7:26-
8)
National Arfjient Air Quality Standards (N4AQS) (contained in 40 CER
50)
New Jersey AAient Air Quality Standards (NJAC 7:27-13)
Safe Drinking Water Act, Maxinun Contaminant Levels (MXs) (40 CER
141.11-16)
New Jersey Surface Water Quality Standards (NJAC 7:9-4)
New Jersey Limitations on Discharge of Effluents to Surface Water
(as provided in NJAC 7:14 A-l et seq.)
Federal Adbient \feter Quality Criteria, as contained in the Toxic
Rule, 40 OH §131.36
New Jersey Ground Water Quality Standards (contained in NJAC 7:9-6)
New Jersey Safe Drinking \\ater Act Maximm Contaminant Levels (NJAC
7:10-16.7)
Action-Specific ARARs:
HCR4 Subtitle C Closure and Post-Closure Standards (40 CPR 264,
Subpart G)
RCRA. Standards for Generators of Hazardous ^ste (40 CER 262)
HCRA. Ground Water Manitoring and Protection Standards (40 QFR 264,
Subpart F)
HCRA. Transporter Requirements for Manifesting Waste for Off-site
Disposal (40 CFR 263)
RCR4 Transporter Requirements for Off-Site Disposal (40 CER 263)
RCRA. Subtitle DNonhazardous Waste Management Standards (40 CFR 257)
RCR4 Land Disposal Restrictions (40 CFR 268) (On- and off-site
disposal of materials)
DDT Rules for Hazardous Materials Transport (49 CFR 171-179)
-------
New Jersey RCftV Closure and Post-Closure Standards (NJAC 7:26-1 et
sefl.)
New Jersey Noise Pollution Regulations (NJAC 7:29 et seo.)
New Jersey Nonhazardous Waste Managenent Requirements (NJAC 7:26-2)
New Jersey Air Pollution Control Regulations (NJAC 7:27 et sea.)
New Jersey Soil Erosion and Sediment Control Act Requirements (NJSA
4:24-42 and NJAC 2:90-1.1 et sea.)
Location-Specific ARARs:
The Clean Water Act (Section 404)
The Coastal Zone Afenagement Act
New Jersey Freshwater Wetlands Regulations
Executive Orders 11988 (FloodplainManagement) and 11990 (Protection
of Wetlands)
Location-Specific To-Be-Considered
FPA Policy on Floodplains and Wetlands Assessments for GERCLA
Actions (08RER Directive #9280.0-02)
Chemical-Spec! fie To-Be-Considered
Clean Water Act, Water Quality Criteria (Section 304(a)) (May 1,
1987 • Gold Book);
EPA's Interim Guidance on Establishing Soil Lead Cleanup Levels at
Super fund Sites, OStVER Directive #9355.4-02
-------
TABLE 1. Lead concentrations measured in soil and earthworms from In situ bioaccumulation chambers.
Earthworms were exposed to site soils for 30 days.
National Lead Industries Site
Pedricktown, New Jersey
• :"-:':>":«••.•." . ' '•..::••.:•;';'.•>. '•'.•' '.',:•.•' '• ; . :. ." :' • :;:;':-.::!-::-
.:•••:•-•• . •- : .; .:.-• . •;••• •-•••.. : • -:•••.• • : .
Soil lead < 500 mg/kg
Soil lead 500 - 1000 mg/kg
Soil lead > 1000 mg/kg
Lead in Soil
(mg/kg dry weight)
Mean
246.0
786.7
3150.0
SD
129.3
58.6
2290.5
Mean
Percent
Moisture
24.9
29.7
48.9
Lead in Soil
(mg/kg wet weight)
Scenario 1*
184.7
. 553.1
1609.7
Scenario 2*
281.9
594.2
2780.1
Lead in Earthworms
(mg/kg wet weight)
Mean
66.3
80.0
85.7
SD
44.2
48.1
42.7
• Scenario 1 calculated using mean lead levels in sediment
* Scenario 2 calculated using mean lead levels plus one standard deviation
-------
TABLE 2. Lead concentration measured in sediment and green frogs (Rana clamltans) collected from
.the East and West stream drainages. Lead in sediments was analyzed using XRF.
National Lead Industries Site
Pedricktown, New Jersey
^
Sediment lead < 1000 mg/kg
Sediment lead 1000 - 2000 mg/kg
Sediment lead > 2000 mg/kg
Lead in Sediment
(mg/kg dry weight)
Mean
862
1024
4568*
SD
201
285
62
Percent
Moisture*
57.0
57.0
57.0
Lead in Sediment
(mg/kg wet weight)
Scenario 1*
371
440
1963
Scenario 2*
457
563
1991
Lead in Progs
(mg/kg wet weight)
Mean
5.02
5.00*
13.32
SD
3.96
5.09
6.90
• Mean percent moisture measured in 5 sediment samples collected for TOC and grain size analysis.
' Scenario 1 calculated using mean lead levels in sediment
' Scenario 2 calculated using mean lead levels plus one standard deviation
4 Based on a sample size of n « 2.
-------
TABLE 3. Mean whole body lead concentration in white-footed mice (Pervmyscus Itucopus) captured on-site.
National Lead Industries site.
Pedricktown, New Jersey
.- :.- *:V ": I:::/-''' •?S/5'.-:'!:: '''•'V.*' !-JM ""vY?*^. !*'::•!',)• :.
Area I and IA
Area II
Area III
Number of animals
11
IS
12
Mean lead
concentration
(mg/kg wet weight)
1.60
3.10
4.77
Standard deviation
1.07
3.02
3.49
Range of values
0.20 - 3.30
0.87 - 13.0
0.89 - 13.0
-------
TABLE 4. Lead concentration in surface soils in small mammal trapping grids as measured by XRF.
National Lead Industries Site
Pedricktown, New Jersey
§|||jjj-.;, ,;, ;,; §;:3ug^^
Grid I
GridIA
Area I (Grids I and IA)
Area II
Area III
Lead in Soils
(mg/kg dry weight)
Mean
1963
ISIS
1705
917
2277
SD
1062
771
914
801
1439
Percent
Moisture*
40.04
40.04
40.04
40.04
40.04
Lead in Soils
(mg/kg wet weight)
Scenario 1*
1177
908
1022
SSO
136S
Scenario 2*
1814
1371
1570
1030
2228
1
• Percent moisture is mean percent moisture measured in soils from earthworm chambers, n
' Scenario 1 calculated using mean lead levels in sediment
• Scenario 2 calculated using mean lead levels plus one standard deviation
20.
-------
TABLE 5. Lead levels measured in surface water samples.
Results are from simples collected during the Remedial Investigation in 1988 and 1989.
National Lead Industries Site
Pedricktown, New Jersey
^•^•^$?:^^J;^
Low (< 0.1 mg/kg)
Medium (0.1 - 1.0 mg/kg)
High (> 1.0 mg/kg)
Sample size
13
10
7
Mean Lead
(mg/kg)
0.049
0.257
1.847
Standard Deviation
(mg/kg)
0.033
0.129
0.696
Range of values
(mg/kg)
0.010 - 0.098
0.100-0.418
1.06 - 3.00
-------
TABLE 5-b
EXPOSURE PROFILES FOR THE ECOLOGICAL RISK ASSESSMENT
Ingestion of earthworms
Ingestion of soils
Woodcock
Ingestion of earthworms
Ingestion of soils
Great blue heron
Ingestion of aquatic biota (frogs)
Ingestion of sediment
Ingestion of water
Red-tailed hawk Ingestion of small mammals
Long-eared owl
Ingestion of small mammals
Red fox
Ingestion of small mammals
Ingestion of soil
Mink
Ingestion of small mammals
Ingestion of aquatic biota (frogs)
Ingestion of soil
Ingestion of water
-------
TABLE 6. Daily intake of lead by biota utilizing forage from the NL Industries site
Scenario 1 calculated using mean lead levels detected on-site; Scenario 2 calculated using mean lead plus one standard deviation
RECEPTOR
SPECIES
ROBIN
r
WOODCOCK
GREAT BLUE
HERON
AUF - 0.3*
LEAD IN MEDIA
(mg/kg)
Soil, < 500
Soil,
500-1000
Soil, > 1000
Soil, < 500
Soil,
500-1000
Soil, > 1000
Sediment,
< 1000
Sediment, 1000-
2000
Sediment,
> 2000
SCENARIO 1
DAILY INTAKE (mg/kg bodyweight/day)
Forage
3.16
,3.82
4.09
33.35
40.24
43.11
0,00
0.00
0.01
Soil/
Sediment
1.89
5.64
16.42
8.41
25.41
73.14
0.02
0.02
0.11
Water
nc
nc
nc
nc
nc
nc
0.00
0.00
0.00
Total
5.05
9.46
20.51
41.76
65.38
116.25
0.02
0.02 ^
-\ '•
0.12
SCENARIO 2
DAILY INTAKE (mg/kg bodyweight/day)
Forage
5.27
6.11
6.13
55.58
64.44
64.59
0.01
0.01
0.01
Soil/
Sediment
2.88
6.06
28.37
12.82
27.00
126.36
0.02
0.03
0.11
Water
nc
nc
nc
nc
nc
nc
0.00
0.00
0.00
Total,
-y&MS^
:;#I7V
134.49
? 68.40 y-
•9k44v
190.95:
0.03
0.04
0.12
nc indicates exposure pathway not considered for this species
AUF *> Area use factor
-------
TABLE 6 (continued). Daily intake of lead by biota utilizing forage from the ML Industries site
Scenario I calculated using mean lead levels measured on-site; Scenario 2 calculated using mean lead plus one standard deviation
RECEPTOR
SPECIES
i
GREAT BLUE
HERON
AUP - 50%
RED-TAILED
HAWK
LONG-EARED
OWL
LEAD IN MEDIA
(mg/kg)
Sediment,
< 1000
Sediment,
1000-2000
Sediment,
> 2000
Area II
< 1000
Arcal&IA
1000-2000
Area in
> 2000
Area II
< 1000
Areal&IA
1000-2000
Area III
> 2000
SCENARIO 1
DAILY INTAKE (mg/kg bodyweight/day)
Forage
O.SO
O.SO
1.33
0.20
0.11
0.31
0.53
0.27
0.82
Soil
3.34
3.%
17.67
nc
nc
nc
nc
nc
nc
Water
0.00
0.01
0.04
nc
nc
nc
nc
nc
nc
Total
3.84
4.47
19.04
0.20
0.11
0.31
0.53
0.27
0.82
SCENARIO 2
DAILY INTAKE (mg/kg bodyweight/day)
Forage
0.90
1.01
2.02
0.40
0.18
0.54
1.05
0.46
1.41
Soil
4.11
5.07
17.92
nc
nc
nc
nc
nc
nc
Water
0.00
0.01
0.05
nc
nc
nc
nc
nc
nc
Total
iS.01
>>H: .-..-•
::j6.ps'-^
19.99
0.40
0.18
0.54
1.05
0.46
1.41
nc indicates exposure pathway not considered for this species
AUP = Area use factor
-------
' TABLE 6 (continued). Daily intake of lead by biota utilizing forage from the NL Industries site
Scenario 1 calculated using mean lead levels detected on-site; Scenario 2 calculated using mean lead plus one standard deviation
RED FOX
MINK, MALE
MINK.
FEMALE
LEAD IN MEDIA
(mg/kg)
Area II
< 1000
Area I & IA
1000-2000
Area III
> 2000
Area II
< 1000
Areal&IA
1000-2000
Area HI
> 2000
Areal!
< 1000
Area I & IA
1000-2000
Area HI
> 2000
SCENARIO 1
DAILY INTAKE (mg/kg bodyweight/day)
Forage
0.20
, 0.10
0.31
0.55
0.45
1.22
0.61
0.50
1.36
Soil/
Sediment
0.99
1.84
2.46
2.08
3.86
5.16
2.31
4.29
5.73
Water
nc
nc
nc
0.02
0.00
OrI7
0.03
0.00
0.18
Total
1.19
1.94
2.76
2.63
4.31
6.55
r 2.94
4.82
7.27
SCENARIO 2
DAILY INTAKE (mg/kg bodyweight/day)
Forage
0.39
0.17
0.53
1.02
0.86
1.92
1.13
0.%
2.14
Soil/
Sediment
1.85
2.83
4.01
3.89
5.93
8.42
4.33
6.59
9.36
Water
nc
nc
nc
0.03
0.01
0.23
0.04
0.01
0.25
Total
2.25
3.00
4.54
4.95
6.80
10.57
S-50
7.56
ii-tt
nc indicates exposure pathway not considered for this species
-------
TABLE 7. Summary of lethal and sublethal effects of ingested lead.
SPECIES
Red-tailed Hawk*
Otter*
Otto*
Dog*
Dog-
European Starling4
Mallard*
EXPOSURE
PERIOD
30 Weeks
Lifetime
Lifetime
2 Years
180 Days
Lifetime
42 Days
DIETARY
EXPOSURE
(me/kg/day)
3
0.15
2.00
2.5'
' 3
4.1«
20*
EFFECT
Clinical symptoms of lead poisoning
No apparent population level effects
Reduced population
Inhibition of ALAD
Anorexia and convulsions
Reduced brain weight in nestlings, reduction in
ALAD in red blood cells of adults and nestlings
Elevated lead levels in bone and eggs
REFERENCE
(Reiser and Temple 1981)
(Mason and MacDonald 1986)
(Mason and MacDonald 1986)
(Azaretal. 1973)
(Clark 1979)
(Grueero/. 1986)
(Haegele«fl/. 1974)
Surrogate for long-eared owl
Surrogate for mink
Surrogate for fox
Surrogate for robin and woodcock
Surrogate for great blue heron
Dose calculated from reported dose of 100 mg/kg based on average dog bodyweight of 10 kg and ingestion rate of 250 g/day
Dose calculated from reported dose of 13.3 mg/kg (wet weight) based on average starling bodyweight of 75 g and ingestion rate of 23 g/day
Dose calculated from reported dose of 100 mg/kg based on average mallard bodyweight of 1.25 g and ingestion rate of 0.25 kg/day
-------
TABLE 8. Risk Estimates for Biota Utilizing the ML Industries site
SPECIES .
ROBIN
•
WOODCOCK
GREAT BLUB
HERON
AUP « 0.3%
LEAD IN
MEDIA
(mg/kg)
Soil, < 500
Soil, 500-1000
Soil. > 1000
Soil, < 500
Soil, 500-1000
Soil, > 1000
Sediment, .
< 1000
Sediment,
1000-2000
Sediment,
> 2000
LOAEL
(mg/kg/day)
4.1
4.1
4.1
4.1
4.1
4.1
20
20
20
DAILY INTAKE
(SCENARIO 1)
(mg/kg/day)
5.05
9.46
20.51
41.76
65.38
116.25
0.02
0.02
0.12
>!:s ' HAZARDM>
;:^QUOTIENT^|,;
i^=V:-'Jr-^te^:;
2.31"'; :>Tf!-:-%4!;
;5.ort:-:'^-^';fliii
io.19 vftlft rft"
1535-1 M? 1ft'
2«;36;:;f
••.«•;•/:.:<> •:..<;:••>: •
0.00 %; i|l gf ;
0.00 |
- * ::!;lfi;i'» :-
()roi^fJli|||||,
DAILY INTAKE
(SCENARIO 2)
(mg/kg/day)
8.15
12.17
34.49
68.40
91.44
190.95
0.03
0.04
0.12
HAZARD
QUOTIENT
1.99 ;' .tf :•:•? :: *'..•"
2.97- v-^;. '•-,:,
8.41
1«.«8
22.30
46.57
0.00
0.00
0.01
Scenario 1: Dose calculated using mean lead concentration in animals
Scenario 2: Dose calculated using mean lead level plus 1 standard deviation
LOAEL: From Table 7
(l) The hazard quotient method compares calculated exposure concentrations to levels which have been shown to cause an ecological effect (Daily intake
•*- Reference dose = Hazard quotient). A hazard quotient greater than 1 indicates that exposure to contaminants at calculated levels may cause
deleterious effects.
-------
TABLE 8 (continued). Risk Estimates for Biota Utilizing the ML Industries site
SPECIES
GREAT BLUB
HBRON
AUP - 50%
RED-TAILED
HAWK
LONG-EARED
OWL
LEAD IN
MEDIA
(mg/kg)
Sediment,
< 1000
Sediment,
1000-2000
Sediment,
>2000
AreaH
< 1000
Area I A IA
1000-2000
AieaHI
> 2000
Area II
< 1000
Area I & IA
1000-2000
Area III
> 2000
LOAEL
(mg/kg/day)
20
20
20
-3
3
3
3
3
3
DAILY INTAKE
(SCENARIO 1)
(mg/kg/day)
3.84
4.47
19.04
0.20
0.11
0.31
0.53
0.27
0.82
~-: ; -'.HAZARD;^
QUOTIENT*1?] :•
0,19;:'. '...: H£^.
0.22' ;.;';.. |i;;;:3|S;
:••"•' ':'•!•;• ' <•''•"•'•'. ": -'-v s;i!:.;: /-•
OQ«rfe ••<• n':^-:felfe:ife-
.3^ J-;*' • . ' - I---.!'/- '•••'• 1; ;: /;?•:;::•:: :>y:- > Z\
!' •'•& 1 M-:- ' • i'i iHSi-lili®
:0.0t:«fc^:j;yi;:l§ll|l!;:;i
y^if^HlillPllp
::0.(H:l"H;tW8li
mm^miim
.ojo;;;::.J:J|:|S;
P.18g:^j%|||g.
Uo|:|||:2||||
;@;|:,|||1|
DAILY INTAKE
(SCENARIO 2)
(mg/kg/day)
5.01
6.08
19.99
0.40
0.18
0.54
1.05
0.46
1.41
HAZARD
; QUOTIENT
0.25
•'0.30;-.;.; ;-!- •
•1.00* tsCji --'o ^ ;
:v.;:?,,:.;:jj i::i;ij:-; -O :r • :•.•
'0.13^ .-^ ;.;•-;• ;i.
;?.v;.f ..:..;;•:. .-^:;.^ :. -i:' -..; : :•; '.
.Ojp6j ;S ;:;.;^:;;;
o.i8;\ •:; . ;• '
0.35;;- •-.:;.:;.:;.
•xi:i5^ "t:, Mm
.y '1... :;.;.?:• ; f^; / :::; :J. '.;. g -.
.0.47;' Jg :;:-:f:;;
Scenario 1: Dose calculated using mean lead concentration in animals
Scenario 2: Dose calculated using mean lead level plus 1 standard deviation
LOAEL: From Table 7
<0 The hazard quotient,method compares calculated exposure concentrations to levels which have been shown to cause an ecological effect (Daily intake
+ Reference dose » Hazard quotient). A hazard quotient greater than 1 indicates that exposure to contaminants at calculated levels may cause
deleterious effects.
-------
TABLE 8 (continued). Risk Estimates for Biota Utilizing the ML Industries site
SPECIES
RED FOX
MINK, MALE
MINK, FEMALE
LEAD IN
MEDIA
(rag/kg)
Area II
< 1000
Area I & IA
1000-2000
Area III
>2000
Area II
< 1000
Areal&IA
1000-2000
Area III
> 2000
Area II
< 1000
Area I & IA
'1000-2000
Area in
> 2000
LOAEL
(mg/kg/day)
2.5
2.5
2.5
2
2
2
2
2
2
DAILY INTAKE
(SCENARIO 1)
(mg/kg/day)
1.19
1.94
2.77
2.63
4.31
6.55
2.94
4.82
7.27
HAZARD
QUOTIENT*1*; ;
0.48 ... ;S.L: '.•'/;,•..
o.78 . '.fc |$:
: •' .. •'. "&'..-'.'•. '-.':-.''--: •
• • • .• : :•• :• '...ff- j.
1.11 :.'-
1,32 ,--|x^:;|,-
;^^!vii81l
ZM^'\yt^M:
••i.47j::;;;!J:||;;::f;;
'2.4l?;;>;f;j]v^g;
3fM'-r '•, '.->.5 sij"isv^.'«.^-
.64:.:.:\-;::i;U:Sii;:S;i;|f;«iW^
"- 'Vsi^'^'M^1-; !P;-?;:::
DAILY INTAKE
(SCENARIO 2)
(mg/kg/day)
2.25
3.00
4.54
4.95
6.80
10.57
5.47
7.59
11.75
HAZARD
QUOTIENT
0.90
1.20
1.82
2.48
3.40
.• ':-: • •• "
5.29
2.74
3.80
5.88
Scenario 1: Dose calculated using mean lead concentration in animals
Scenario 2: Dose calculated using mean lead level plus 1 standard deviation
LOAEL: From Table 7
<*> The hazard quotient method compares calculated exposure concentrations to levels which have been shown to cause an ecological effect (Daily intake
+ Reference dose - Hazard quotient). A hazard quotient greater than 1 indicates that exposure to contaminants at calculated levels may cause
deleterious effects.
-------
APPENDIX III
ADMINISTRATIVE RECORD INDEX
-------
03/25/94 Index Docunent Nvnter Order Page: 1
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Document Number: NLI-001-0001 To 0010 Date: / /
Title: Potential Hazardous Waste Site Site Inspection Report - NL Industries Inc.
Type: PLAN
Author: Zervas, David: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Docunent Nunfcer: NLI-001 -0011 To 0108 Date: 05/01/83
Title: Hydrogeologic Study and Design of Ground Hater Abatement System at NL Industries Inc., Pedricktown
NJ Plant Site
Type: PLAN
Author: none: Geraghty & Miller
Recipient: none: none
Docunent Nunber: NLI-001-0109 To 0279 Date: 05/01/87
Title: Work Plan - Remedial Investigation/Feasibility Study - National Smelting of NJ Site, Pedricktoun
NJ
Type: PLAN
Condition: INCOMPLETE; MARGINALIA
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Docunent Number: NLI-001-0280 To 0426 Date: 05/01/87
Title: Uork Plan - Remedial Investigation/Feasibility Study - National Smelting of NJ Site, Pedricktown
NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94 Index Docunent Hunter Order Page: 2
NL IHDUSTRIES, OPERABLE UNIT 1 Documents
Oocunent Number: NLI-001-0427 To 0509 Date: 08/01/87
Title: OBG Laboratories, Inc. QA Program Manual - Remedial Investigaticn/Feasibility Study - National
Smelting of NJ Site, Pedricktoun NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Nunber: NLI-001-0510 To 0537 Parent: NLI-001-0512 Date: 04/01/88
S
Title: Field Sampling and Analysis Plan - RI/FS Oversight - NL Industries Site. Pedricktown NJ
Type: PLAN
Author: Horzempa, Lewis M: Ebasco Services
Recipient: none: US EPA
Document Number: NLI-001-0512 To 0513 Date: 05/03/88
Title: (Letter submitting Field Sampling and Analysis Plan)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Alvi, H. Shaheer: US EPA
Attached: NLI-001-0510
Document Number: NLI-001-0538 To 0889 Parent: NLI-001-0539 Date: 05/01/88
Title: Site Operations Plan - Remedial Investigation Plan/Feasibility Study - National Smelting of
NJ Site, Pedricktoun NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Docunent Hunter: NLI-001-0539 To 0540 Date: 05/10/88
Title: (Letter submitting the Final Site Operations Plan)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Holt, Stephen W.: NL Industries, Inc.
Recipient: Donato, Kernin: US EPA
Attached: NLI-001-0538
-------
03/25/94 Index Docinent Hotter Order Page: 3
NL INDUSTRIES, OPERABLE UNIT 1 Docuients
Docuoent Number: NLI-001-0890 To 1265 Date: 06/01/90
Title: Technical Memorandum - Data Validation - National Spelling of NJ Site, Pedricktoun NJ
Type: PLAN
Condition: MARGINALIA
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-1266 To 1280 Date: 12/01/90
Title: NL Industries Sediment Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Oocunent Nunber: NLI-001-1281 To 1282 Date: 11/01/90
Title: NL Industries Soil Analyses • Phase III
Type: DATA
Author: none: none
Recipient: none: none
Docunent Nunber: NLI-001-1283 To 1297 Date: 12/01/90
Title: NL Industries Grounduater Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Docunent Nunber: NLI-001-1298 To 1304 Date: 12/01/90
Title: NL Industries Surface Water Analyses • Phase III
Type: DATA
Author: none: none
Recipient: none: none
-------
03/25/9* Index Document Mutter Order Page:
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Ninber: MLI-001-1305 To 1312 Date: 12/01/90
Title: ML Industries Sediment Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Document Nuaber: NLI-001-1313 To 132 Date: 08/01/89
Title: NL Industries Oversight Grounduater Analyses - Phase II
Type: DATA
Author: none: none
Recipient: none: none
Docunent Minber: MLI-001-1323 To 1347 Date: 10/01/88
Title: (Phase I Water and Soil Analyses, Site Naps)
Type: DATA
Author: none: none
Recipient: none: none
Document Number: NLI-001-1348 To 1393 Date: 04/01/90
Title: Final RI Oversight Suimary Report - NL Industries Site, Pedricktown NJ
Type: REPORT
Condition: MARGINALIA
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Docunent Number: NLI-001-1394 To 1673 Date: 10/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volume I: Report, Tables,
Figures
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94
Index Document Nunber Order
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Page: 5
Docunent Muter: NLI-001-1674 To 2187
Date: 10/01/90
Title: Remedial Investigation • National Smelting of NJ/NL Industries Site Volute II: Appendices,
Exhibits
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Docunent Nu*er: NLI-001-2188 To 2319
Date: 12/01/90
Title: Remedial Investigation • National Smelting of NJ/NL Industries Site Volune III: Appendices
R-U
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Doonent Number: NLI-001-2320 To 2342
Title: (Letter forwarding the revised RI Oversight Summary Report)
Type: CORRESPONDENCE
Author: Rubin, David 8: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
Attached: NLI-001-2323
Date: 06/14/90
Docuoent Nunber: NLI-001-2323 To 2342 Parent: NLI-001-2320
Title: Final RI Oversight Sunmary Report - NL Industries Site, Pedricktoun NJ
Type: REPORT
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Date: 04/01/90
Docunent Nunber: NLI-001-2343 To 2354
Date: 07/19/90
Title: (Letter forwarding attached summary comparison of USEPA and NL Industries data for the Phase
II split samples)
Type: CORRESPONDENCE
Author: Rubin, David B: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
-------
03/25/94 Index Document Nunber Order Page: 6
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Oocunent Number: NLI-001-2355 To 2358 Date: 09/19/90
Title: (Letter indicating need for additional sampling at the site)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen W: NL Industries, Inc.
Document Number: NLI-001-2359 To 2361 Date: 10/05/90
•-*
Title: (Letter requesting retesting of soils and rejecting request for extension for submittal of
RI Report)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Molt, Stephen U: NL Industries, Inc.
Docunent Number: NU-001-2362 To 2365 Date: 11/15/90
Title: (Letter conveying approval of the amended Sanpling Plan and outlining methods for sample collecting
and analysis)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen W: NL Industries, Inc.
Document Number: NLI-001-2366 To 2367 Date: 11/26/90
Title: (Letter outlining analysis guidelines)
Type: CORRESPONDENCE
Author: Gilbert, Michael H: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
-------
03/25/94
Index Document Number Order
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Page: 7
Docinent Number: NLI-001-2368 To 2370 Date: 11/29/90
Title: (Letter stating EPA's intention to take and analyze samples from the site)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Docunent Number: NLI-001-2371 To 2373
Title: (Letter requesting changes in the 10/90 Remedial Investigation Report)
^
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Date: 03/06/91
Docunent Number: NLI-001-2374 To 2385
Title: (Letter forwarding attached information pertaining to wells at the site)
Type: CORRESPONDENCE
Author: Holt, Stephen U: NL Industries, Inc.
Recipient: Kothari, Dilip: Ebasco Services
Date: 04/23/91
Docunent Number: NLI-001-2386 To 2390
Title: Preliminary Health Assessment for NL Industries
Type: PLAN
Author: none: Agency for Toxic Substances & Disease Registry (ATSDR)
Recipient: none: none
Date: 04/10/89
Docunent Number: NLI-001-2391 To 2391
Date: 02/28/91
Title: (Letter stating that NL Industries will have to close the underground storage tanks at the
cite)
Type: CORRESPONDENCE
Condition: MISSING ATTACHMENT
Author: Holstrcn, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H: US EPA
-------
03/25/94 Index Docunent Number Order Page: 8
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Document Hunter: NLI-001-2392 To 2392 Date: / /
Tide: (List of EPA Guidance Publications)
Type:
Author: none: none
Recipient: none: none
Document Nwter: NLI-001-2393 To 2393 Date: 08/20/90
Title: (Letter requesting applicable or relevant requirements which pertain to the site)
*
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holstron, Christina: NJ Department of Environmental Protection (NJDEP)
Document Number: NLI-001-2394 To 2394 Date: 10/15/90
Title: (Letter regarding applicable or relevant requirements for testing at the site)
Type: CORRESPONDENCE
Author: Holstron, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Attached: NLI-001-2409
Document Number: NLI-001-2395 To 2408 Date: 11/27/90
Title: (Referral form forwarding attached surface Hater ARARs for the site)
Type: CORRESPONDENCE
Author: Holstren, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Document Number: NLI-C01-2409 To 2412 Parent: NLI-001-2394 Date: 03/01/88
Title: Regulations Implementing the New Jersey Water Pollution Control Act
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
-------
03/25/94 Index Document Muter* Order Page: 9
ML INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Number: NLI-002-0001 To 0119 Date: 09/01/90
Title: Regulations Implementing the New Jersey Underground Storage of Hazardous Substances Act
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDE?)
Recipient: none: none
Docunent Nunber: NLI-002-0120 To 0162 Date: / /
Title: NJDEP Fresh Water Permit Application
Type: OTHER
Author: none: none
Recipient: none: none
Docunent Nunber: NLI-002-0163 To 0185 Date: 12/01/86
Title: Final Community Relations Plan - NL Industries Site, Pedriektoun, NJ
Type: PLAN
Author: Diamond, Christopher R.: ICF Incorporated
Recipient: none: US EPA
Docunent Number: NLI-002-0186 To 0208 Parent: NLI-002-0188 Date: 01/01/89
Title: Final Public Information Meeting Summary for the NL Industries Site, Redricktoun, NJ
Type: PLAN
Author: Manning, Kathleen S.: ICF Incorporated
Recipient: none: US EPA
Docunent Number: NLI-002-0188 To 0189 . Date: 01/23/89
Title: (Letter submitting the Final Public Information Meeting Suiraary)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Johnson, Lillian: US EPA
Attached: NLI-002-0186
-------
03/25/94 Index Document Umber Order Page: 10
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Doeuwnt Number: NLI-002-0209 To 0219 Date: 01/01/91
Title: Oversight Sunnary Report - NL Industries Site, Pedricktotm MJ
Type: REPORT
Author: none: Ebasco Services
Recipient: none: US EPA
Document Number: NLI-002-0220 To 0261 Date: 01/01/92
Title: A Stage 1A Cultural Resources Survey of the NSNJ/NL Property, Olchians Township, Salem County
NJ
Type: PLAN
Author: Crist, Thomas A.J.: John Hilner Associates
McCarthy, John P.: John Hilner Associates
Recipient: none: O'Brien & Gere
none: NL Industries, Inc.
Document Nunber: NLI-002-0262 To 0363 Date: 03/01/91
Title: Volume IV, Appendices V-U, Remedial Investigation National Smelting of Hew Jersey, Inc./ML
Industries, Inc. Site, Pedricktoun, New Jersey
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: none
Document Number: HLI-002-0364 To 0367 Parent: NLI-002-2078 Date: 07/08/91
Title: (Letter approving the Remedial Investigation (RI) Report, Volumes I-IV for the NL Industries,
Inc., site, in conjunction with EPA's enclosed RI Addendum, and approving the Feasibility Study
Workplan with modifications specified in the letter.)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen W.: NL Industries, Inc.
-------
03/25/94 Index Document Number Order Page: 11
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Winter: NLI-002-0368 To 0375 Parent: NL I-002-2078 Date: / /
Title: Addendun to the Remedial Investigation, Volumes I-IV, NL Industries, Inc., Super-fund Site,
Pedricktown, New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Document Number: NLI-002-0376 To 0428 Date: 07/01/93
Title: Addendum to the Final Feasibility Study Report, NL Industries, Inc. Super-fund Site, Operable
Unit One, Pedricktown, New Jersey
•
Type: PLAN
Author: none: US EPA
Recipient: none: none
Document Nunber: NLI-002-0429 To 0521 Date: 02/01/93
Title: Final Report, TCLP Screening, National Lead Industries Site, Pedricktown, NJ
Type: REPORT
Author: Bovitz, Paul: Environmental Response Team (ERT)
Sprenger, Nark D.: Environmental Response Team (ERT)
Recipient: none: none
Document Number: NLI-002-0522 To 0556 Date: 02/15/93
Title: Stage IB Cultural Resources Survey, National Smelting of New Jersey Property, Oldmans Township,
Salem County, New Jersey
Type: PLAN
Author: Grubb, Richard C.: Richard Grubb & Associates, Inc.
Harmon, James M.: Richard Crubb & Associates, Inc.
Recipient: none: O'Brien & Gere
-------
03/25/94 Index Document Nunber Order Page: 12
ML INDUSTRIES, OPERABLE UNIT 1 Docunents
Oocunent Number: NLI-002-0557 To 0557 Date: 05/12/93
Title: (Letter forwarding the "Final Feasibility Study Report," which addresses EPA's comnents on
the "Draft Feasibility Study Report for the Pedricktown site.")
Type: CORRESPONDENCE
Author: Caracciolo, Angelo J. Ill: O'Brien & Gere
Recipient: Gilbert, Michael: US EPA
Attached: NLI-002-0558
Document Number: NLI-002-0558 To 1129 Parent: MLI-002-0557 Date: 05/01/93
Title: Final Feasibility Study, NL Industries, Inc. Site, Pedricktown, New Jersey
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: US EPA
Document Number: NLI-002-1130 To 1228 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ
Type: REPORT
Author: Bovitz, Paul: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Document Number: NLI-002-1229 To 1604 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ - Appendices A to E
Type: REPORT
Author: Henry, Richard: ERT -
Sprenger, Nark D.: ERT
Recipient: none: none
-------
03/25/94 Index Document Number Order Page: 13
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Nuater: NLI-002-1605 To 1699 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ • Appendices F to L
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Document Number: NLI-002-1900 To 1965 Date: 06/01/93
Title: Final Report, National Lead Industries, Pedricktoun, Neu Jersey, Ecological Risk Assessment
Type: REPORT
Author: Grossman, Scott: ERT
Kracko, Karen: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Document Nunber: NLI-002-1966 To 1972 Date: 06/01/93
Title: Final Report, Recommendations for Ecologically Based Lead Remedial Goals, National Lead Industries,
Pedricktoun, Neu Jersey
Type: REPORT
Author: Sprenger, Nark D.: ERT
Recipient: none: none
Docunent Nunber: NLI-002-1973 To 1973 Date: 06/25/93
Title: (Memo containing conments on the Hay 1993 Final Feasibility Study Report for the NL Industries
site)
Type: CORRESPONDENCE
Author: Prendergast, John: New Jersey Department of Environmental Protection and Energy
Recipient: Harvey, Paul: New Jersey Department of Environmental Protection and Energy
Attached: NLI-002-1974
-------
03/25/94 Index Oocunent Hunter Order Page: 14
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Nunber: NLI-002-1974 To 1974 Parent: NLI-002-1973 Date: 05/24/93
Title: (Nemo stating that the NL Draft Feasibility Study has satisfactorily addressed Comnents 1
and 2, which were mentioned in a February 9, 1993, nemo)
Type: CORRESPONDENCE
Condition: MISSING ATTACHMENT
Author: Kaplan, David M.: New Jersey Department of Environmental Protection and Energy
Recipient: none: Neu Jersey Department of Environmental Protection and Energy
Docunent Number: NLI-002-1975 To 1994 * Date: 07/01/93
Title: Superfund Proposed Plan, NL Industries, Inc. Operable Unit One, Pedricktoun, Salem County,
New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Document Nunber: NLI-002-1995 To 2012 Date: 07/14/93
Title: (Action Memorandum requesting a ceiling increase and a removal action restart at the National
Lead Industries Inc., Site, Pedricktoun, Salem County, New Jersey)
Type: CORRESPONDENCE
Author: Dominach, Eugene: US EPA
Recipient: Muszynski, William J.: US EPA
Docunent Nunber: NLI-002-2013 To 2013 Date: 07/16/93
Title: (Letter responding to Mr. Gilbert's request regarding the potential routing and feasibility
of the construction of a pipeline to the Delaware River)
Type: CORRESPONDENCE
Author: Holt, Stephen U.: NL Industries, Inc.
Recipient: Gilbert, Michael: US EPA
-------
03/25/94 Index Doeunent Umber Order Page: 15
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Doeunent Winter: NLI-002-2014 To 2060 Date: 12/01/90
Title: NL Industries, Sediment Analyses, Phase III Nov., Dec. 1990
Type: FINANCIAL/TECHNICAL
Author: none: Ebasco Services
none: O'Brien & Gere
Recipient: none: none
Document Number: NLI-002-2061 To 2073 Date: 01/01/91
• *
Title: Oversight Summary Report - NL Industries Site, Pedricktown, New Jersey
Type: REPORT
Condition: DRAFT; MARGINALIA
Author: Rubin, David B.: Ebasco Services
Recipient: none: US EPA
Document Hunter: NLI-002-2074 To 2077 Date: 06/20/91
Title: (Letter indicating that the inorganic analyses for groundwater have nisreported units.)
Type: CORRESPONDENCE
Author: Hale, Frank 0.: O'Brien & Gere
Recipient: Holt, Stephen W.: NL Industries, Inc.
Document Hunter: NLI-002-2078 To 2078 Date: 08/13/91
Title: (Letter forwarding the revised results of the Phase III oversight samples and indicating that
the units on the groundwater analysis have been revised.)
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holt, Stephen U.: NL Industries, Inc.
Attached: NLI-002-0364 NLI-002-0368
-------
03/25/94 Index Document Number Order Page: 16
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Document Nunber: HL1-002-2079 To 2175 . Date: 08/02/93
Title: Transcript of Proceedings - In the Matter of: Superfund Proposed Plan, NL Industries, Inc.,
Pedricktoun, N.J.
Type: LEGAL DOCUMENT
Author: Butler, Virginia E.: Accurate Court Reporting Services
Recipient: none: none
Document Number: NLI-002-2176 To 2200 Date: 02/02/94
Title: (Memo forwarding the attached project summary for the Acid Extraction Treatment System and
several sections from the final report detailing the Pedricktown soil)
Type: CORRESPONDENCE
Author: Paff, Stephen U.: Center for Hazardous Materials Research - (Univ. of Pittsburgh)
Recipient: Gilbert, Mick: US EPA
-------
03/25/94 Index Chronological Order Page: 1
NL INDUSTRIES, OPERABLE UNIT 1 Docuaents
Docunent Number: NLI-001-0001 To 0010 Date: / /
Title: Potential Hazardous Waste Site Site Inspection Report - NL Industries Inc.
Type: PLAN
Author: Zervas, David: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Docunent Nunber: NLI-001-2392 To 2392 Date: / /
Title: (List of EPA Guidance Publications) -
Type:
Author: none: none
Recipient: none: none
Docunent Hunter: NLI-002-0120 To 0162 Date: / /
Title: NJDEP Fresh Water Permit Application
Type: OTHER
Author: none: none
Recipient: none: none
Document Number: NLI-002-0368 To 0375 Parent: NLI-002-2078 Date: / /
Title: Addendum to the Remedial Investigation, Volumes I-IV, NL Industries, Inc., Superfund Site,
Pedricktoun, New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Document Number: NLI-001-0011 To 0108 Date: 05/01/83
Title: Hydrogeologic Study and Design of Ground Water Abatement System at NL Industries Inc., Pedricktown
NJ Plant Site
Type: PLAN
Author: none: Geraghty £ Miller
Recipient: none: none
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03/25/94 Index Chronological Order Page: 2
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Doctnent Nusber: NLI-002-0163 To 0185 Date: 12/01/86
Title: Final Community Relations Plan - NL Industries Site, Pedricktown, NJ
Type: PLAN .
Author: Diamond, Christopher R.: ICF Incorporated
Recipient: none: US EPA
Docunent Number: NLI-001-0109 To 0279 Date: 05/01/87
Title: Work Plan - Remedial Investigation/Feasibility Study - National Smelting of NJ Site, Pedricktown
NJ
Type: PLAN
Condition: INCOMPLETE; MARGINALIA
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-0280 To 0426 Date: 05/01/87
Title: Work Plan - Remedial Investigation/Feasibility Study - National Smelting of NJ Site, Pedricktown
NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Docunent Number: NLI-001-0427 To 0509 Date: 08/01/87
Title: OBG Laboratories, Inc. QA Program Manual - Remedial Investigation/Feasibility Study - National
Smelting of NJ Site, Pedricktown NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94 Index Chronological Order Page: 3
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Docuaent Number: NLI-001-2409 To 2412 Parent: NLI-001-2394 Date: 03/01/88
Title: Regulations Implementing the New Jersey Water Pollution Control Act
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Document Number: MLI-001-0510 To 0537 Parent: NLI-001-0512 Date: 04/01/88
Title: Field Sampling and Analysis Plan - RI/FS Oversight - NL Industries Sit*, Pedricktown NJ
Type: PLAN
Author: Horzenpa, Lewis H: Ebasco Services
Recipient: none: US EPA
Docinent Number: NLI-001-0538 To 0889 Parent: NLI-001-0539 Date: 05/01/88
Title: Site Operations Plan - Remedial Investigation Plan/Feasibility Study - National Smelting of
NJ Site, Pedricktown NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-0512 To 0513 Date: 05/03/88
Title: (Letter submitting Field Sampling and Analysis Plan)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Alvi, N. Shaheer: US EPA
Attached: HLI-001-0510
Docuaent Number: NLI-001-0539 To 0540 Date: 05/10/88
Title: (Letter submitting the Final Site Operations Plan)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Holt, Stephen U.: NL Industries, Inc.
Recipient: Donate, Kerwin: US EPA
Attached: NLI-001-0538
-------
03/25/94 Index Chronological Order Page: 4
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Hunter: NLI-001 -1323 To 1347 Date: 10/01/88
Title: (Phase I Water and Soil Analyses, Site Naps)
Type: DATA
Author: none: none
Recipient: none: none
Docunent Nunber: NLI-002-0186 To 0208 Parent: NLI-002-0188 Date: 01/01/89
Title: Final Public Information Meeting Sunmary for the NL Industries Site, Redricktown, NJ
Type: PLAN
Author: Manning, Kathleen S.: ICF Incorporated
Recipient: none: US EPA
Docunent Nunber: NLI-002-0188 To 0189 Date: 01/23/89
Title: (Letter submitting the Final Public Information Meeting Sumaary)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Johnson. Lillian: US EPA
Attached: NLI-002-0186
Docunent Nunber: NLI-001-2386 To 2390 Date: 04/10/89
Title: Preliminary Health Assessment for NL Industries
Type: PLAN
Author: none: Agency for Toxic Substances & Disease Registry (ATSOR)
Recipient: none: none
Docunent Nunber: NLI-001-1313 To 1322 Date: 08/01/89
Title: NL Industries Oversight Grounduater Analyses - Phase II
Type: DATA
Author: none: none
Recipient: none: none
-------
03/25/94
Index Chronological Order
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Page: 5
Document Number: NLI-001-1348 To 1393
Title: Final RI Oversight Sunmary Report - NL Industries Site, Pedricktown NJ
Type: REPORT
Condition: MARGINALIA
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Date: 04/01/90
Document Number: NLI-001-2323 To 2342 Parent: NLI-001-2320
Title: Final RI Oversight Sunmary Report - NL Industries Site, Pedricktown NJ
Type: REPORT
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Date: 04/01/90
Docunent Number: NLI-001-0890 To 1265 Date: 06/01/90
Title: Technical Memorandum - Data Validation • National Smelting of NJ Site, Pedricktown NJ
Type: PLAN
Condition: MARGINALIA
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-2320 To 2342
Title: (Letter forwarding the revised RI Oversight Summary Report)
Type: CORRESPONDENCE
Author: Rubin, David B: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
Attached: NLI-001-2323
Date: 06/14/90
Document Nutter: NLI-001-2343 To 2354
Date: 07/19/90
Title: (Letter forwarding attached summary comparison of USEPA and NL Industries data for the Phase
II split samples)
Type: CORRESPONDENCE
Author: Rubin, David B: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
-------
03/25/94 Index Chronological Order Page: 6
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Document Nuxber: NLI-001-2393 To 2393 Date: 08/20/90
Title: (Letter requesting applicable or relevant requirements which pertain to the site)
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holstron, Christina: NJ Departnent of Environmental Protection (NJDEP)
Docunent Number: NLI-002-0001 To 0119 Date: 09/01/90
Title: Regulations Implementing the New Jersey Underground Storage of Hazardous Substances Act
s
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Docunent Number: NLI-001-2355 To 2358 Date: 09/19/90
Title: (Letter indicating need for additional sampling at the site)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Docunent Nuifcer: NLI-001-1394 To 1673 Date: 10/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volume I: Report, Tables,
Figures
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Nutter: NLI-001-1674 To 2187 Date: 10/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volume II: Appendices,
Exhibits
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94 Index Chronological Order Page: 7
NL INDUSTRIES. OPERABLE UNIT 1 DocunentS
Document Number: NLI-001-2359 To 2361 Date: 10/05/90
Title: (Letter requesting retesting of soils and rejecting request for extension for subnittal of
RI Report)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Document Number: NLI-001-2394 To 2394 Date: 10/15/90
Title: (Letter regarding applicable or relevant requirements for testing at the site)
Type: CORRESPONDENCE
Author: HoiStrom, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Attached: NLI-001-2409
Document Number: NL]-001-1281 To 1282 Date: 11/01/90
Title: NL Industries Soil Analyses • Phase III
Type: DATA
Author: none: none
Recipient: none: none
Document Number: NLI-001-2362 To 2365 Date: 11/15/90
Title: (Letter conveying approval of the amended Sampling Plan and outlining methods for sample collecting
and analysis)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Document Number: NLI-001-2366 To 2367 Date: 11/26/90
Title: (Letter outlining analysis guidelines)
Type: CORRESPONDENCE
Author: Gilbert, Michael H: US EPA
Recipient: Holt, Stephen W: NL Industries, Inc.
-------
03/25/94 Index Chronological Order Page: 8
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Nuofaer: NLI-001-2395 To 2408 Date: 11/27/90
Title: (Referral form forwarding attached surface water ARARs for the site)
Type: CORRESPONDENCE
Author: Holstrom, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Document Number: NLI-001-2368 To 2370 Date: 11/29/90
Title: (Letter stating EPA's intention to take and analyze samples from the site)
S
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Document Winter: NLI-001-1266 To 1280 Date: 12/01/90
Title: NL Industries Sediment Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Document Nunber: NLI-001-1283 To 1297 Date: 12/01/90
Title: NL Industries Grounduater Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Document Huaber: NLI-001-1298 To 1304 Date: 12/01/90
Title: NL Industries Surface Water Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
-------
03/25/94 Index Chronological Order Page: 9
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Nunber: NLI-001-1305 To 1312 Date: 12/01/90
Title: NL Industries Sediment Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Docunent Nunber: NLI-001-2188 To 2319 Date: 12/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volume III: Appendices
R-U
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Nunber: NLI-002-2014 To 2060 Date: 12/01/90
Title: NL Industries, Sediment Analyses, Phase III Nov., Dec. 1990
Type: FINANCIAL/TECHNICAL
Author: none: Ebasco Services
none: O'Brien & Gere
Recipient: none: none
Document Nuifcer: NLI-002-0209 To 0219 Date: 01/01/91
Title: Oversight Summary Report - NL Industries Site, Pedricktowi NJ
Type: REPORT
Author: none: Ebasco Services
Recipient: none: US EPA
Document Nufcer: NLI-002-2061 To 2073 Date: 01/01/91
Title: Oversight Sinwary Report - NL Industries Site, Pedricktown, New Jersey
Type: REPORT
Condition: DRAFT; MARGINALIA
Author: Rubin, David B.: Ebasco Services
Recipient: none: US EPA
-------
03/25/94 Index Chronological Order Page: 10
ML INDUSTRIES, OPERABLE UNIT 1 Docunents
Oocunent Number: NLI -001 -2391 To 2391 Date: 02/28/91
Title: (Letter stating that NL Industries will have to close the underground storage tanks at the
site)
Type: CORRESPONDENCE
Condition: MISSING ATTACHMENT
Author: Holstrom, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H: US EPA
Document Number: NLI-002-0262 To 0363 Date: 03/01/91
A
Title: Volume IV, Appendices V-W, Remedial Investigation National Smelting of New Jersey, Inc./NL
Industries, Inc. Site, Pedricktown, New Jersey
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: none
Document Ninber: NLI-001-2371 To 2373 Date: 03/06/91
Title: (Letter requesting changes in the 10/90 Remedial Investigation Report)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Document Number: NLI-001-2374 To 2385 Date: 04/23/91
Title: (Letter forwarding attached information pertaining to wells at the site)
Type: CORRESPONDENCE
Author: Holt, Stephen U: NL Industries, Inc.
Recipient: Kothari, Dilip: Ebasco Services
-------
03/25/94 Index Chronological Order Page: 11
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Number: NLI-002-2074 To 2077 Date: 06/20/91
Title: (Letter indicating that the inorganic analyses for grounduater have nisreported units.)
Type: CORRESPONDENCE
Author: Hale, Frank D.: O'Brien & Gere
Recipient: Holt, Stephen W.: NL Industries, Inc.
Docunent Number: NLI-002-0364 To 0367 Parent: NLI-002-2078 Date: 07/08/91
Title: (Letter approving the Remedial Investigation (RI) Report, Volumes I-IV for the NL Industries,
Inc., site, in conjunction with EPA's enclosed RI Addendum, and approving the Feasibility Study
Uorkplan with modifications specified in the letter.)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U.: NL Industries, Inc.
Docunent Number: NLI-002-2078 To 2078 Date: 08/13/91
Title: (Letter forwarding the revised results of the Phase III oversight samples and indicating that
the units on the grounduater analysis have been revised.)
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holt, Stephen U.: NL Industries, Inc.
Attached: NLI-002-0364 NLI-002-0368
Docunent Number: NLI-002-0220 To 0261 Date: 01/01/92
Title: A Stage 1A Cultural Resources Survey of the NSHJ/NL Property, Oldmans Township, Salem County
NJ
Type: PLAN
Author: Crist, Thomas A.J.: John Nilner Associates
McCarthy, John P.: John MiIner Associates
Recipient: none: O'Brien & Gere
none: NL Industries, Inc.
-------
03/25/94 Index Chronological Order Page: 12
ML INDUSTRIES, OPERABLE UNIT 1 Docunents
Docuaent Niater: NLI-002-0429 To 0521 Date: 02/01/93
Title: Final Report, TCLP Screening. National Lead Industries Site, Pedricktoun, NJ
Type: REPORT
Author: Bovitz, Paul: Environmental Response Team (ERT)
Sprenger, Hark P.: Environmental Response Team (ERT)
Recipient: none: none
Docunent Hunter: NLI-002-0522 To 0556 Date: 02/15/93
Title: Stage IB Cultural Resources Survey, National Smelting of New Jersey Property, Oldnans Township,
Salem County, Mew Jersey
Type: PLAN
Author: Grubb, Richard C.: Richard Grubb & Associates, Inc.
Harmon, James M.: Richard Grubb & Associates, Inc.
Recipient: none: O'Brien & Gere
Docunent Nunber: NLI-002-0558 To 1129 Parent: NLI-002-0557 Date: 05/01/93
Title: Final Feasibility Study, NL Industries, Inc. Site, Pedricktown, New Jersey
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: US EPA
Docunent Waiter: NLI-002-0557 To 0557 Date: 05/12/93
Title: (Letter forwarding the "Final Feasibility Study Report," which addresses EPA's cements on
the "Draft Feasibility Study Report for the Pedricktoun site.")
Type: CORRESPONDENCE
Author: Caracciolo, Angelo J. Ill: O'Brien I Gere
Recipient: Gilbert, Michael: US EPA
Attached: NLI-002-0558
-------
03/25/94 Index Chronological Order Page: 13
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
DocuMnt Hatter: NLI-002-1974 To 1974 Parent: NLI-002-1973 Date: 05/24/93
Title: (Nemo stating that the NL Draft Feasibility Study has satisfactorily addressed Conaents 1
and 2, which were mentioned in a February 9, 1993, memo)
Type: CORRESPONDENCE
Condition: MISSING ATTACHMENT
Author: Kaplan, David M.: New Jersey Department of Environmental Protection and Energy
Recipient: none: New Jersey Department of Environmental Protection and Energy
Document Number: NLI-002-1130 To 1228 Date: 06/01/93
• *
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ
Type: REPORT
Author: Bovitz, Paul: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Document Hunter: NLI-002-1229 To 1604 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ - Appendices A to E
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Document Number: NLI-002-1605 To 1899 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktcwn, Salen County,
NJ - Appendices F to L
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
-------
03/25/94 Index Chronological Order Page: 14
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Nuober: NLI-002-1900 To 1965 Date: 06/01/93
Title: Final Report, National Lead Industries, Pedricktoun, New Jersey, Ecological Risk Assessment •
Type: REPORT .
Author: Grossman, Scott: ERT
ICracko, Karen: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Docunent Nunber: NLI-002-1966 To 1972 Date: 06/01/93
Title: Final Report, Recommendations for Ecologically Based Lead Remedial Goals, National Lead Industries,
Pedricktoun, New Jersey
Type: REPORT
Author: Sprenger, Nark D.: ERT
Recipient: none: none
Docunent Nmfcer: NLI-002-1973 To 1973 Date: 06/25/93
Title: (Nemo containing conraents on the Nay 1993 Final Feasibility Study Report for the NL Industries
site)
Type: CORRESPONDENCE
Author: Prendergast, John: New Jersey Department of Environmental Protection and Energy
Recipient: Harvey, Paul: New Jersey Department of Environmental Protection and Energy
Attached: NLI-002-1974
Document Muriser: NLI-002-0376 To 0428 Date: 07/01/93
Title: Addendum to the Final Feasibility Study Report, NL Industries, Inc. Superfund Site, Operable
Unit One, Pedricktown, Hew Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
-------
03/25/94 Index Chronological Order Page: 15
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Oocunent Hunter: NLI-002-1975 To 1994 Date: 07/01/93
Title: Superfund Proposed Plan, KL Industries, Inc. Operable Unit One, Pedricktoun, Sal en County,
New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Document Nunfeer: NLI-002-1995 To 2012 Date: 07/14/93
Title: (Action Memorandum requesting a ceiling increase and a removal action restart at the National
Lead Industries Inc., Site, Pedricktoun, Salem County, Neu Jersey)
Type: CORRESPONDENCE
Author: Dominach, Eugene: US EPA
Recipient: Huszynski. William J.: US EPA
Document Nunber: NLI-002-2013 To 2013 Date: 07/16/93
Title: (Letter responding to Mr. Gilbert's request regarding the potential routing and feasibility
of the construction of a pipeline to the Delaware River)
Type: CORRESPONDENCE
Author: Holt. Stephen U.: NL Industries, Inc.
Recipient: Gilbert, Michael: us EPA
Document Number: NLI-002-2079 To 2175 Date: 08/02/93
Title: Transcript of Proceedings - In the Matter of: Superfund Proposed Plan, NL Industries, Inc.,
Pedricktoun, N.J.
Type: LEGAL DOCUMENT
Author: Butler, Virginia E.: Accurate Court Reporting Services
Recipient: none: none
-------
03/2/96 Index Chronological Order Page: 16
NL INDUSTRIES, OPERABLE UNIT 1 Docuaents
Oocunent Ninber: ML I-002-2176 To 2200 Date: 02/02/94
Title: (Memo forwarding the attached project sunnary for the Acid Extraction Treatment System and
several sections from the final report detailing the Pedricktown soil)
Type: CORRESPONDENCE
Author: Paff, Stephen W.: Center for Hazardous Materials Research - (Univ. of Pittsburgh)
Recipient: Gilbert, Nick: US EPA
-------
03/25/94
Index Author Name Order
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Page: 1
Docunent Nuofcer: NLI-001-1266 To 1280
Title: NL Industries Sediment Analyses • Phase III
Type: DATA
Author: none: none
Recipient: none: none
Date: 12/01/90
Docunent Hunter: NLI-001-1281 To 1282
Title: NL Industries Soil Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Date: 11/01/90
Docunent Hunter: NLI-001-1283 To 1297
Title: NL Industries Grounduater Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Date: 12/01/90
Docunent Hunter: NLI-001-1298 To 13M
Title: NL Industries Surface Uater Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Date: 12/01/90
Docunent Hunter: NLI-001-1305 To 1312
Title: NL Industries Sediment Analyses - Phase III
Type: DATA
Author: none: none
Recipient: none: none
Date: 12/01/90
-------
03/25/94 Index Author Name Order Page: 2
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Doeuwnt Hotter: NLI-001-1313 To 1322 Date: 08/01/89
Title: ML Industries Oversight Grounduater Analyses - Phase II
Type: DATA
Author: none: none
Recipient: none: none
Doeuwnt Nuaber: NLI-001-1323 To 1347 Date: 10/01/88
Title: (Phase I Water and Soil Analyses, Site Haps)
.«
Type: DATA
Author: none: none
Recipient: none: none
Docunent Number: MLI-001-2392 To 2392 Date: / /
Title: (List of EPA Guidance Publications)
Type:
Author: none: none
Recipient: none: none
Docuaent Nurber: NLI-002-0120 To 0162 Date: / /
Title: NJDEP Fresh Water Permit Application
Type: OTHER
Author: none: none
Recipient: none: none
Document Huaber: MLI-001-0011 To 0108 Date: 05/01/83
Title: Hydrogeologic Study and Design of Ground Water Abatement System at NL Industries Inc., Pedricktown
NJ Plant Site
Type: PLAN
Author: none: Geraghty & Miller
Recipient: none: none
-------
03/25/94 Index Author Name Order Page: 3
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Document Nusber: Nil-001-0109 To 0279 Date: 05/01/87
Title: Work Plan - Remedial Investigation/Feasibility Study - National Smelting of NJ Site, Pedricktown
NJ
Type: PLAN
Condition: INCOMPLETE; MARGINALIA
Author: none: O'Brien I Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-0280 To 0426 Date: 05/01/87
• «
Title: Work Plan • Remedial Investigation/Feasibility Study • National Smelting of NJ Site, Pedricktown
NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NL1-001-0427 To 0509 Date: 08/01/87
Title: OBG Laboratories, Inc. QA Program Manual - Remedial Investigation/Feasibility Study • National
Smelting of NJ Site, Pedricktown NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Document Number: NLI-001-0538 To 0889 Parent: NLI-001-0539 Date: 05/01/88
Title: Site Operations Plan - Remedial Investigation Plan/Feasibility Study - National Smelting of
NJ Site, Pedricktoun NJ
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94 Index Author Name Order Page: 4
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Umber: NLI-001-0890 To 1265 Date: 06/01/90
Title: Technical Memorandun • Data Validation - National Smelting of NJ Site, Pedricktown NJ
Type: PLAN
Condition: MARGINALIA
Author: none: O'Brien I Gere
Recipient: none: NL Industries, Inc.
Docunent Nunfcer: NLI-001-1394 To 1673 Date: 10/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volume I: Report, Tables,
Figures
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
Docunent Number: NLI-001-1674 To 2187 Date: 10/01/90
Title: Remedial Investigation - National Smelting of NJ/NL Industries Site Volune II: Appendices,
Exhibits
Type: REPORT
Author: none: O'Brien I Gere
Recipient: none: NL Industries, Inc.
Docunent Nunber: NLI-001-2188 To 2319 Date: 12/01/90
Title: Remedial Investigation • National Smelting of NJ/NL Industries Site Volune III: Appendices
R-U
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: NL Industries, Inc.
-------
03/25/94
Index Author Name Order
ML INDUSTRIES, OPERABLE UNIT 1 Oocunents
Page: 5
Doeunent Nunber: Nil -001 -2386 To 2390
Title: Preliminary Health Assessment for NL Industries
Type: PLAN
Author: none: Agency for Toxic Substances & Disease Registry (ATSOR)
Recipient: none: none
Date: 04/10/89
Document Nunber: NLI-001-2409 To 2412 Parent: NII-001-Z394
Title: Regulations Implementing the New Jersey Water Pollution Control Act
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Date: 03/01/88
Doeunent Nmfcer: NLI-002-0001 To 0119 Date: 09/01/90
Title: Regulations Implementing the New Jersey Underground Storage of Hazardous Substances Act
Type: LEGAL DOCUMENT
Author: none: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
Document Ninber: NLI-002-0209 To 0219
Title: Oversight Sunnary Report - NL Industries Site, Pedricktown NJ
Type: REPORT
Author: none: Ebasco Services
Recipient: none: US EPA
Date: 01/01/91
Document Nunber: NLI-002-0262 To 0363
Date: 03/01/91
Title: Volume IV. Appendices V-W, Remedial Investigation National Smelting of Neu Jersey. Inc./ML
Industries, Inc. Site, Pedricktown, Hew Jersey
Type: PLAN
Author: none: O'Brien & Gere
Recipient: none: none
-------
03/2S/M
Index Author Name Order
HI INDUSTRIES, OPERABLE UNIT 1 Documents
Page: 6
Oocunent (limber: ML I-002-0368 To 0375
Parent: NLI-002-2078
Date: / /
Title: Addendun to the Remedial Investigation, Volunes I-IV, NL Industries, Inc., Superfund Site,
Pedricktown, New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Docunent Nunber: NL I-002-0376 To 0428
Date: 07/01/93
Title: Addendun to the Final Feasibility Study Report, NL Industries, Inc. Sufterfund Site, Operable
Unit One, Pedricktown, New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
Docunent Nunber: NLI-002-OSS8 To 1129 Parent: NLI-002-0557 Date: 05/01/93
Title: Final Feasibility Study, NL Industries, Inc. Site, Pedricktown, New Jersey
Type: REPORT
Author: none: O'Brien & Gere
Recipient: none: US EPA
Docunent Nuaber: NLI-002-1975 To 1994
Date: 07/01/93
Title: Superfund Proposed Plan, NL Industries, Inc. Operable Unit One, Pedricktown, Salem County,
New Jersey
Type: PLAN
Author: none: US EPA
Recipient: none: none
-------
03/25/94 Index Author Nme Order Page: 7
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Oocuaent Nunber: NL1-003-2014 To 2060 Date: 12/01/90
Title: NL Industries, Sediment Analyses, Phase III Nov., Dec. 1990
Type: FINANCIAL/TECHNICAL
Author: none: Ebasco Services
none: O'Brien & Gere
Recipient: none: none
Docunent Nunfeer: NLI-002-2014 To 2060 Date: 12/01/90
Title: NL Industries, Sediment Analyses, Phase III Nov., Dec. 1990
Type: FINANCIAL/TECHNICAL
Author: none: Ebasco Services
none: O'Brien & Gere
Recipient: none: none
Document Number: NLI-001-2355 To 2358 Date: 09/19/90
Title: (Letter indicating need for additional sanpling at the site)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Docunent Number: NLI-001-2359 To 2361 Date: 10/05/90
Title: (Letter requesting retesting of soils and rejecting request for extension for submittal of
RI Report)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
-------
03/25/94
Index Author Name Order
NL INDUSTRIES, OPERABLE UNIT 1 Oocunents
Page: 8
Docunent Nuaber: NLI -001 -2362 To 2365
Date: 11/15/90
Title: (Letter conveying approval of the amended Sampling Plan and outlining methods for sample collecting
and analysis)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen W: NL Industries, Inc.
Docunent Nunber: NLI-001-2368 To 2370 Date: 11/29/90
Title: (Letter stating EPA's intention to take and analyze sanples from the sfte)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U: NL Industries, Inc.
Docunent Nunber: NLI-001-2371 To 2373
Title: (Letter requesting changes in the 10/90 Remedial Investigation Report)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen W: NL Industries, Inc.
Date: 03/06/91
Document Nunber: NLI-002-0364 To 0367
Parent: NLI-002-2078
Date: 07/08/91
Title: (Letter approving the Remedial Investigation (RI) Report, Volumes I-IV for the NL Industries.
Inc., site, in conjunction with EPA's enclosed RI Addendum, and approving the Feasibility Study
Uorkplan with modifications specified in the letter.)
Type: CORRESPONDENCE
Author: Basso, Raymond: US EPA
Recipient: Holt, Stephen U.: NL Industries, Inc.
-------
03/25/94 Index Author Nane Order Page: 9
NL INDUSTRIES, OPERABLE UNIT 1 Oocunents
Document Hunter: NLI-002-0429 To 0521 Date: 02/01/93
Title: Final Report, TCLP Screening, National Lead Industries Site, Pedricktoun, NJ
Type: REPORT
Author: Bovitz, Paul: Environmental Response Team (ERT)
Sprenger, Mark D.: Environmental Response Team (ERT)
Recipient: none: none
Document Nunber: NLI-002-1130 To 1228 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktoun, Salem County,
NJ
Type: REPORT
Author: Bovitz, Paul: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Document Number: NLI-002-2079 To 2175 Date: 08/02/93
Title: Transcript of Proceedings - In the Matter of: Superfund Proposed Plan, NL Industries, Inc.,
Pedricktown, N.J.
Type: LEGAL DOCUMENT
Author: Butler, Virginia E.: Accurate Court Reporting Services
Recipient: none: none
Docunent Number: NLI-002-0557 To 0557 Date: 05/12/93
Title: (Letter forwarding the "Final Feasibility Study Report," which addresses EPA's cements on
the "Draft Feasibility Study Report for the Pedricktoun cite.")
Type: CORRESPONDENCE
Author: Caracciolo, Angelo J. Ill: O'Brien & Gere
Recipient: Gilbert, Michael: US EPA
Attached: NLI-002-0558
-------
03/25/94 Index Author Name Order Page: 10
HL INDUSTRIES, OPERABLE UNIT 1 Documents
Docuwnt Nuaber: NL1-002-0220 To 0261 Date: 01/01/92
Title: A Stage 1A Cultural Resources Survey of the NSNJ/NL Property. Oldmans Township. Salea County
NJ
Type: PLAN
Author: Crist. Thonas A.J.: John Hilner Associates
McCarthy. John P.: John MiIner Associates
Recipient: none: O'Brien & Gere
none: NL Industries, Inc.
Document Number: NU-002-0163 To 0185 " Date: 12/01/86
Title: Final Community Relations Plan - NL Industries Site, Pedricktoun. NJ
Type: PLAN
Author: Diamond, Christopher R.: ICF Incorporated
Recipient: none: US EPA
Docunent Nunber: NLI-002-1995 To 2012 Date: 07/14/93
Title: (Action Memorandum requesting a ceiling increase and a removal action restart at the National
Lead Industries Inc., Site, Pedricktoun, Salem County, New Jersey)
Type: CORRESPONDENCE
Author: Dominach, Eugene: US EPA
Recipient: Muszynski, William J.: US EPA
Docunent Hunter: NLI-001-2366 To 2367 Date: 11/26/90
Title: (Letter outlining analysis guidelines)
Type: CORRESPONDENCE
Author: Gilbert, Michael H: US EPA
Recipient: Holt, Stephen V: NL Industries, Inc.
-------
03/25/94 Index Author Nane Order Page: 11
HL INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Number: NLI-001-2393 To 2393 Date: 08/20/90
Title: (Letter requesting applicable or relevant requirenents which pertain to the site)
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holstron, Christina: NJ Department of Environmental Protection (NJDEP)
Docunent Umber: NLI-002-2078 To 2078 Date: 08/13/91
Title: (Letter forwarding the revised results of the Phase III oversight samples and indicating that
the units on the groundwater analysis have been revised.) "
Type: CORRESPONDENCE
Author: Gilbert, Michael H.: US EPA
Recipient: Holt, Stephen w.: NL Industries, Inc.
Attached: NLI-002-0364 NLI-002-0368
Document Number: NLI-002-1900 To 1965 Date: 06/01/93
Title: Final Report, National Lead Industries, Pedricktown, New Jersey, Ecological Risk Assessment
Type: REPORT
Author: Grossman, Scott: ERT
Kracko, Karen: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Docunent Number: NLI-002-0522 To 0556 Date: 02/15/93
Title: Stage IB Cultural Resources Survey, National Smelting of New Jersey Property, Oldmans Township,
Salem County, Hew Jersey
Type: PLAN
Author: Grubb, Richard C.: Richard Grubb & Associates, Inc.
Harmon, James M.: Richard Grubb & Associates, Inc.
Recipient: none: O'Brien I Gere
-------
03/25/94 Index Author Name Order Page: 12
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Doctnent Muster: NLI-002-2074 To 2077 Date: 06/20/91
Title: (Letter indicating that the inorganic analyses for grounduater have misreported units.)
Type: CORRESPONDENCE
Author: Hale, Frank 0.: O'Brien & Gere
Recipient: Holt, Stephen V.: NL Industries, Inc.
Docunent Hunber: NLI-002-0522 To 0556 Date: 02/15/93
Title: Stage IB Cultural Resources Survey, National Smelting of New Jersey Property, Oldmans Township,
Salem County, New Jersey s
Type: PLAN
Author: Grubb, Richard C.: Richard Grubb & Associates, Inc.
Harmon, Janes M.: Richard Grubb & Associates, Inc.
Recipient: none: O'Brien & Gere
Docunent Nunber: NLI-002-1229 To 1604 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ - Appendices A to E
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Hark D.: ERT
Recipient: none: none
Document Winter: NL I-002-1605 To 1899 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ - Appendices F to L
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
-------
03/25/94 Index Author None Order Page: 13
ML INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Nuxber: NL1-001-2391 To 2391 Date: 02/28/91
Title: (Letter stating that NL Industries Hill have to close the underground storage tanks at the
site)
Type: CORRESPONDENCE
Condition: MISSING ATTACHMENT
Author: Holstron, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H: US EPA
Docunent Ninber: NLI-001-2394 To 2394 Date: 10/15/90
*
Title: (Letter regarding applicable or relevant requirements for testing at the site)
Type: CORRESPONDENCE
Author: Nolstrom, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Attached: NLI-001-2409
Docuvnt Nuxber: NLI-001-2395 To 2408 Date: 11/27/90
Title: (Referral form forwarding attached surface water ARARs for the site)
Type: CORRESPONDENCE
Author: Holstrom, Christina: NJ Department of Environmental Protection (NJDEP)
Recipient: Gilbert, Michael H.: US EPA
Docunent Number: NLI-001-0539 To 0540 Date: 05/10/88
Title: (Letter submitting the Final Site Operations Plan)
Type: CORRESPONDENCE
Condition: MARGINALIA
Author: Holt, Stephen U.: NL Industries, Inc.
Recipient: Donate, Kerwin: US EPA
Attached: NLI-001-OS38
-------
03/25/94 Index Author None Order Page: 14
NL INDUSTRIES. OPERABLE UNIT 1 Docunents
Docuwnt Ntober: NLI-001-2374 To 2385 Date: 04/23/91
Title: (Letter forwarding attached information pertaining to wells at the site)
Type: CORRESPONDENCE
Author: Holt, Stephen U: NL Industries, Inc.
Recipient: Kothari, Dilip: Ebasco Services
Document Hotter: NLI-002-2013 To 2013 Date: 07/16/93
Title: (Letter responding to Mr. Gilbert's request regarding the potential routing and feasibility
of the construction of a pipeline to the Delaware River) *
Type: CORRESPONDENCE
Author: Holt, Stephen U.: NL Industries, Inc.
Recipient: Gilbert, Michael: US EPA
Document Nuiter: HLI-001-0510 To 0537 Parent: NLI-001-0512 Date: 04/01/88
Title: Field Sampling and Analysis Plan - RI/FS Oversight - NL Industries Site, Pedricktown NJ
Type: PLAN
Author: Horzempa, Lewis H: Ebasco Services
Recipient: none: US EPA
Document Nwber: NLI -002-1974 To 1974 Parent: NLI-002-1973 Date: 05/24/93
Title: (Mean stating that the NL Draft Feasibility Study has satisfactorily addressed Comments 1
and 2, which were mentioned in a February 9, 1993, memo)
Type: CORRESPONDENCE
Condition: HISSING ATTACHMENT
Author: Kaplan, David N.: New Jersey Department of Environmental Protection and Energy
Recipient: none: New Jersey Department of Environmental Protection and Energy
-------
03/25/94 Index Author Name Order Page: 15
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Docunent Number: NLI-002-1900 To 1965 Date: 06/01/93
Title: Final Report, National Lead Industries, Pedricktoun, New Jersey, Ecological Risk Assessment
Type: REPORT
Author: Grossman, Scott: ERT
Kracko, Karen: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Docunent Nunber: NLI-002-0186 To 0208 Parentr NL!-002-0188 Date: 01/01/89
*
Title: Final Public Information Meeting Suonary for the NL Industries Site, Redricktoun, NJ
Type: PLAN
Author: Manning, Kathleen S.: ICF Incorporated
Recipient: none: US EPA
Docunent Nunber: NLI-002-0220 To 0261 Date: 01/01/92
Title: A Stage 1A Cultural Resources Survey of the NSNJ/NL Property, Oldnans Township, Salem County
NJ
Type: PLAN
Author: Crist, Thomas A.J.: John Milner Associates
McCarthy, John P.: John Milner Associates
Recipient: none: O'Brien & Gere
none: NL Industries, Inc.
Docunent Nuofcer: NLI-002-2176 To 2200 Date: 02/02/94
Title: (Memo forwarding the attached project summary for the Acid Extraction Treatment System and
several sections fron the final report detailing the Pedricktoun soil)
Type: CORRESPONDENCE
Author: Paff, Stephen U.: Center for Hazardous Materials Research - (Univ. of Pittsburgh)
Recipient: Gilbert, Mick: US EPA
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03/25/96
Index Author Name Order
NL INDUSTRIES, OPERABLE UNIT 1 Ooonents
Page: 16
Docuwnt Niater: NLI-002-1973 To 1973
Date: 06/25/93
Title: (Memo containing coanents on the Nay 1993 Final Feasibility Study Report for the NL Industries
site)
Type: CORRESPONDENCE
Author: Prendergast, John: New Jersey Department of Environmental Protection and Energy
Recipient: Harvey, Paul: New Jersey Department of Environmental Protection and Energy
Attached: NLI-002-1974
Docunent Nunber: NLI-001-1348 To 1393 Date: 04/01/90
Title: Final RI Oversight Surmary Report - NL Industries Site, Pedricktown NJ *
Type: REPORT
Condition: MARGINALIA
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Docunent Nunber: NLI-001-2320 To 2342
Title: (Letter forwarding the revised RI Oversight Sunnary Report)
Type: CORRESPONDENCE
Author: Rubin, David B: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
Attached: NLI-001-2323
Date: 06/14/90
Docunent Nuifeer: NLI-001-2323 To 2342 Parent: NLI-001-2320
Title: Final RI Oversight Sunnary Report - NL Industries Site, Pedricktown NJ
Type: REPORT
Author: Rubin, David B: Ebasco Services
Recipient: none: US EPA
Date: 04/01/90
Docunent Nuxber: NLI-001-2343 To 2354
Date: 07/19/90
Title: (Letter forwarding attached sunmary comparison of USEPA and NL Industries data for the Phase
II split samples)
Type: CORRESPONDENCE
Author: Rubin, David B: Ebasco Services
Recipient: Gilbert, Michael H: US EPA
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03/25/94 Index Author Name Order Page: 17
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Document Hunter: NLI-002-2061 To 2073 Date: 01/01/91
Title: Oversight Sunnary Report - NL Industries Site, Pedricktown, New Jersey
Type: REPORT
Condition: DRAFT; MARGINALIA
Author: Rubin, David B.: Ebasco Services
Recipient: none: US EPA
Document Hunter: NLI-001-0512 To 0513 Date: 05/03/88
Title: (Letter submitting Field Sampling and Analysis Plan)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Alvi, M. Shaheer: US EPA
Attached: NLI-001-0510
Document Number: NLt-002-0188 To 0189 Date: 01/23/89
Title: (Letter submitting the Final Public Information Meeting Summary)
Type: CORRESPONDENCE
Author: Sachdev, Dev R.: Ebasco Services
Recipient: Johnson, Lillian: US EPA
Attached: NLI-002-0186
Document Hunter: NLI-002-0429 To 0521 Date: 02/01/93
Title: Final Report, TCLP Screening, National Lead Industries Site, Pedricktoun, NJ
Type: REPORT
Author: Bovitz, Paul: Environmental Response Team (ERT)
Sprenger, Mark D.: Environmental Response Team (ERT)
Recipient: none: none
Document Hunter: NLI-002-1130 To 1228 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ
Type: REPORT
Author: Bovitz, Paul: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
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03/25/94 Index Author Name Order Page: 18
NL INDUSTRIES, OPERABLE UNIT 1 Documents
Oocunent Number: NLI-002-1229 To 1604 Date: 06/01/93
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown. Salem County,
NJ - Appendices A to E
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Mark D.: ERT
Recipient: none: none
Docunent Nutter: NLI-002-1605 To 1899 Date: 06/01/93
•%
Title: Final Report, Field Ecological Assessment, National Lead Site, Pedricktown, Salem County,
NJ • Appendices F to L
Type: REPORT
Author: Henry, Richard: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Oocunent Umber: NLI-002-1900 To 1965 Date: 06/01/93
Title: Final Report, National Lead Industries, Pedricktown, New Jersey, Ecological Risk Assessment
Type: REPORT
Author: Grossman, Scott: ERT
Kracko, Karen: ERT
Sprenger, Nark D.: ERT
Recipient: none: none
Document Number: NLI-002-1966 To 1972 Date: 06/01/93
Title: Final Report, Recommendations for Ecologically Based Lead Remedial Goals, National Lead Industries,
Pedricktown, New Jersey
Type: REPORT
Author: Sprenger, Nark D.: ERT
Recipient: none: none
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03/25/94 Index Author Kane Order Page: 19
NL INDUSTRIES, OPERABLE UNIT 1 Docunents
Document Hatter: till -001 -0001 To 0010 Date: / /
Title: Potential Hazardous Waste Site Site Inspection Report - NL Industries Inc.
Type: PLAN
Author: Zervas, David: NJ Department of Environmental Protection (NJDEP)
Recipient: none: none
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APPENDIX IV
STATE LETTER OF NON-CONCURRENCE
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State of New Jersey
Deportment of Environment*! Protectfpnnatl Cdeigy
Robert C SWnn, jr.
Commissioner
May 18, 1994
Kathleen Callahan, Director
USEPA Region IX •
Emergency and Remedial Response Division
26 Federal Plaza
New York, NY 10278-0012
• *
Dear Ms. Callahan:
Re: NL Industries, Pedricktown, Draft ROD .
This letter concerns the draft Record of Decision (ROD) for the ML' Industries
site which was submitted to the Department of Environmental Protection and Energy
(Department) by cover letter dated February 23, 1994. The Department cannot
concur with the selected remedy because environmental use restrictions, .as
required per P.L. 1993, c. 139, (6-1070), are not included and off-site soils are
not appropriately addressed. The Department's residential soil cleanup criterion
for lead is 100 ing/kg. This is the level to which the Department would address
the off-site soils. Any remedy that does not attain this criterion must include
environmental use restrictions. Without the inclusion of use restrictions and
the incorporation of the Department's recommendations for off-site soils in the
ROD, the Department cannot concur.
Please contact me with questions at (609) 292-1250.
Sincerely, (
Lance R. Miller
Assistant.Commissioner
Newjmeylstn tqua Opportunity Employer
Retydeclnper
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APPENDIX V
RESPONSIVENESS SUMMARY
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APPENDIX V
RESPONSIVENESS SUMMARY
NL Industries, Inc. Superfund Site
INTRODUCTION
A responsiveness summary is required by Superfund policy. It provides a summary of
citizens' comments and concerns received during the public comment period, and the United
States Environmental Protection Agency's (EPA's) responses to those comments and
concerns. All comments summarized in this document have been considered in EPA's final
decision for selection of a remedial alternative for the NL Industries, Inc. site.
H
OVERVIEW
The public strongly supported EPA taking action to address the various contaminated media
at the NL site. The community supported both the ground water and sediment portions of
the preferred alterative. The community did not object to the soil and sediment treatment
process itself. However, they expressed a preference for treatment of all soil and sediment
above the remedial action objective (Soil Alternative-B), rather than the preferred
alternative presented in the Proposed Plan (Soil Alternative-D), which includes treatment
of only the hazardous portion and on-site landfilling of the non-hazardous portion of the soil
and sediment.
BACKGROUND ON COMMUNITY INVOLVEMENT
Pedricktown residents first became aware of potential environmental and public health
impacts associated with operations at the NL site in 1975, when the Salem County
Department of Health sampled 15 private drinking water wells in the vicinity of the site.
One well was found to have elevated lead levels. Several months later, private homes along
Benjamin Green Road west of the site were connected to the public water supply. Other
early investigative activities performed to assess off-site impacts included an air monitoring
program initiated by the New Jersey Department of Environmental Protection and Energy
(NJDEPE) in 1977, at which time elevated levels of several airborne contaminants, including
lead, were detected.
The NL site was included on the National Priorities List in December 1982. Since that
time, EPA has implemented a community relations program in the site area designed to
both inform the public of Superfund activities and solicit input from the community
regarding their site-related concerns and questions. These efforts have included
disseminating printed public information materials and conducting public meetings and
information sessions to coincide with technical milestones at the site.
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Through the public outreach efforts noted above, EPA has identified several concerns and
issues which have been consistently expressed by the community. These concerns and issues
are as follows:
o liability of the Potentially Responsible Parties (PRPs) for conducting and funding
site investigations and cleanup
o Plans to periodically monitor area drinking water supplies
o Impact of site activities on area property values
o Potential future uses of the site
o Anticipated schedule for completion of the site cleanup
o Loss of local tax revenue from the site property
SUMMARY OF COMMUNITY RELATIONS ACTIVITIES
The Remedial Investigation (RI) Report, Feasibility Study (FS) Report, and the Proposed
Plan for the site were released to the public for comment on July 22,1993. These documents
were made available to the public in the administrative record file at the EPA Docket
Room in Region II, New York and the information repositories at the Perms Grove Public
Library in Penns Grove, New Jersey. A copy of relevant documents and information have
also been sent to the Oldmans Municipal Building in Pedricktown, New Jersey. The notice
of availability for the above-referenced documents was published in Today's Sunbeam on
July 22,1993. The public comment period on these documents was held from July 22,1993
to September 19, 1993.
On August 2, 1993, EPA conducted a public meeting at the Oldmans Middle School, to
inform local officials and interested citizens about the Superfund process, to review current
and planned remedial activities at the site, and to respond to any questions from area
residents and other attendees.
SUMMARY OF COMMENTS AND RESPONSES
The following correspondence (see Attachment A) was received during the public comment
period:
o Letter from George Bradford, Mayor of Pedricktown.
o Letter and supporting comments from Janet D. Smith, Associate General Counsel
for NL Industries, Inc.
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o Letter and supporting comments from Dennis P. Reis, Attorney for Sidley & Austin,
submitted on behalf of Allied Signal Inc., AT&T, C&D Charter Power Systems, Inc.
Exide Corporation, and Johnson Controls, Inc.
A summary of the comments contained in the above letters and the comments provided by
the public at the August 2,1993 public meeting, along with EPA's and NJDEPE's responses
to those comments, follows.
I. Verbal Comments Received During the Public Meeting
A. TECHNICAL COMMENTS ON OPERABLE UNIT TWO
1. COMMENT: A resident asked what was used to treat the slag.
v
EPA RESPONSE: After exploring a number of treatment methods,
EPA decided upon the use of phosphoric acid. Phosphoric acid
combines with the lead in the slag to make lead phosphate. Lead
phosphate is stable and will not leach at levels which define it as a
hazardous waste. Therefore, the slag has been rendered non-
hazardous through this treatment and may be disposed of off site at a
non-hazardous landfill.
2. COMMENT: A resident asked how EPA processed the steel from the
site.
EPA RESPONSE: EPA washed the steel with high-pressure water to
remove the dust. It is then visually inspected, loaded into trucks, and
shipped to a scrap dealer for recycling.
3. COMMENT: A resident asked if the volume of water said to be
removed during remediation included water from the landfill?
EPA RESPONSE: Only landfill leachate is removed from the landfill.
This leachate is collected and disposed of at the DuPont Deepwater
facility by NL. The standing water which was removed from the site
as part of the Operable Unit Two activities consists of accumulated
rainwater and water used for decontamination purposes.
4. COMMENT: A resident asked if the dust created while structures are
being demolished at the site is dangerous.
EPA RESPONSE: Prior to demolition, dust is removed from buildings
with an industrial vacuum. Then, the structures are power-washed with
water. During this process, continuous air monitoring is performed.
No exceedences of safe air levels have been detected.
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5. COMMENT: A resident asked who pays for the cleanup.
EPA RESPONSE: To date, the responsible parties have funded the
Operable Unit Two cleanup, which is currently underway. EPA has
provided oversight of these activities.
B. TECHNICAL COMMENTS ON OPERABLE UNIT ONE
1. COMMENT: Mr. Harvey, Case Manager for NJDEPE added to the
presentation by commenting that the State of New Jersey concurs with the
selected remedy as presented by EPA, However, he added that the State may
not agree with the soil lead cleanup criteria of 500 parts per million. He said
that the State is in the process of developing criteria for cleanup of lead in
soils and therefore it is possible that when the State finalizes its criteria, it
may be less than 500 parts per million (ppm).
2. COMMENT: A resident reacted to viewing a slide showing the areas
to be excavated under soil remediation at the site by asking if all of
the areas shown are contaminated.
EPA RESPONSE: EPA indicated that all of the areas shown contain
lead above 500 ppm, thus requiring remediation.
3. COMMENT: Residents asked how much cost influences the choice of
the preferred alternative and if prohibitive cost was the reason for not
treating all soils.
EPA RESPONSE: EPA stated that nine evaluation criteria were used
to evaluate each alternative. Protectiveness of human health and the
environment and cost are two criteria considered in selecting a remedy.
Alternative-B (treating all soils and sediments above the remedial
action objective) and Altemative-D (treating only the hazardous soil
and sediments and landfilling nonhazardous soils and sediments above
the remedial action objective) are both protective of human health and
the environment. The cost is 22 million dollars for Alternative-B
versus 11.5 million dollars for Alternative-D. Based upon EPA's
evaluation of all alternatives against the nine criteria, EPA believes
that Alternative-D is cost effective relative to Alternative B.
4. COMMENT: One resident asked if the planned on-site landfill would
be constructed with a liner.
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EPA RESPONSE: A liner would underlie the landfill and the landfill
would be covered with a geomembrane cap. Soil and vegetation will
be added above the cap.
5. COMMENT: A resident informed EPA that, although several
residential wells were tested, his well had never been tested because
he was not at home during the sampling event.
EPA RESPONSE: EPA responded that it will test the well, and asked
the gentleman to give his address and phone number in order to
schedule the well sampling.
6. COMMENT: A resident asked if there are any plans to take soil samples
from residences around the site area?
EPA RESPONSE: Approximately twelve residential soil samples have been
obtained. All are below 500 ppm of lead, which is EPA's risk based cleanup
level. Additional soil sampling will take place at the site during the remedial
design phase of the project. The exact nature of any additional soil sampling
will be determined during remedial design.
C. EXISTING LANDFILL
1. COMMENT: A resident asked EPA why the existing landfill is not
included in the cleanup project.
EPA RESPONSE: The existing landfill has a cover consisting of an
impermeable membrane and clean soil, which was brought in from off-
site sources. The landfill is closed and is regulated by the State of
New Jersey. NL is maintaining, operating, securing and performing
sampling as necessary under State of New Jersey requirements. In
addition, the landfill was studied and monitored as part of the RI/FS
for Operable Unit One. At this time, EPA has no indication that the
landfill requires remediation. Note that ground water underlying the
landfill exceeding cleanup criteria will be remediated.
2. COMMENT: A resident asked if the township sees the results of tests
sampled from the monitoring wells around the landfill?
EPA RESPONSE: All data from the monitoring wells are included in
the administrative record. A copy of the administrative record is
located in the Penns-Grove Public Library, and, as requested at a
previous meeting, EPA at the Oldman's Township Municipal Building.
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3. COMMENT: A resident expressed concern that the landfill may be
responsible for contributing to the ground-water contamination of the
project site. The same resident asked what is underneath the landfill.
EPA RESPONSE: Based on results of data collected during EPA's
studies at the site, most of the wells around the landfill have yielded
results within the drinking water standard. Although there has been
some contamination detected underlying the landfill, these wells will
continue to be monitored. The preferred alternative will be designed
to address all contaminated ground water which is contaminated above
drinking water standards.
4. COMMENT: A resident asked why the whole site is not being cleaned
up.
EPA RESPONSE: The remedial investigation performed by EPA has
determined the nature and extent of contamination throughout the site.
The soil, stream sediments, and ground water that are contaminated
are the subject of EPA's preferred alternative for the site.
Furthermore, EPA has no indication that the closed, on-site landfill,
as currently maintained, is posing an unacceptable human health or
environmental risk.
5. COMMENT: A resident asked what evidence EPA had that no
leachate was leaking from the landfill.
EPA RESPONSE: As part of the RI, EPA has monitored soils, surface
water, and ground water in the vicinity of the on-site landfill. This
data indicates that elevated levels of arsenic have been detected in one
monitoring well adjacent to the landfill, and have generally been
decreasing over time. These elevated contaminant levels are believed
to have resulted when a portion of the landfill partially collapsed
during a severe storm in 1989. Structural modifications to the landfill
have been made to prevent this from occurring in the future. If any
data is collected which demonstrates that the landfill is not secured,
appropriate action will be taken.
6. COMMENT: A resident asked if the landfill will be suspected as a
source of contamination if during the five-year follow up monitoring,
the stream is found to be contaminated.
EPA RESPONSE: If surface-water contamination is detected after the
soils and stream sediments have been remediated, EPA will investigate
further to define the source of contamination and will take appropriate
action.
6
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7. COMMENT: A resident asked if a landfill is supposed to have as
many monitoring wells around it as exist at the project site.
EPA RESPONSE: The landfill is closed and regulated by the State
of New Jersey and maintained by NL. There are fourteen monitoring
wells which surround the entire landfill.
D. STEAM SEDIMENT CLEANUP
1. COMMENT: A resident asked if EPA planned to remove the
contaminated sediments from the stream.
EPA RESPONSE: Within the next few months, EPA will remove
contaminated sediments in the West Stream from just north of Penns
Grove Pedricktown Road down to Route 130.
2. COMMENT: A resident asked how many years EPA would monitor
the stream following cleanup.
EPA RESPONSE: EPA will monitor the stream and the project site
for at least five years following completion of the work.
3. COMMENT: A resident asked whether stream sediments would be removed
prior to operation of the ground-water treatment and discharge system.
EPA RESPONSE: Stream sediment will be removed first so that
contaminants will not migrate further downstream.
4. COMMENT: A resident asked whether the stream bed would be returned to
its original profile after dredging.
EPA RESPONSE: EPA is removing contaminated stream sediments and not
altering the steam's original profile. Contaminated sediments, in general, lie
within one foot of the surface. However, the Salem County Mosquito
Commission may choose to change the stream profile for better drainage after
completion of EPA's cleanup.
E. CLEANUP SCHEDULE AND REUSE OF LAND
1. COMMENT: A resident asked when EPA's work would be done at
the project site and at what point the land would be considered usable
for something else.
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EPA RESPONSE: EPA anticipates that cleanup will take
approximately three years from the time of the Record of Decision.
This time frame includes completion of the soil and sediment portion
of the remedy, and construction of the ground water treatment plant.
It is anticipated that the ground water treatment plant will operate on
the order of thirty years.
2. COMMENT: A resident asked who is responsible for giving approval
for reuse of the site property.
EPA RESPONSE: Following cleanup, the site will go through the
process of being removed from the National Priorities Superfund List
EPA may need to treat the ground water for many years. However,
once the sediment and soil are cleaned up, a business could
conceivably operate on the property while,the water treatment is
ongoing, provided that the business would not impact the site's ongoing
ground-water remediation.
3. COMMENT: A resident asked if there is a permit which must be
issued in order for the project land to be reused.
EPA RESPONSE: EPA's intention is to clean the site to a safe level.
It is not anticipated that EPA will impose any land use restrictions on
the property after the cleanup is completed.
4. COMMENT: A resident expressed concern that the state might
override the townships' wishes not to allow National Smelting to
operate again in that location.
EPA RESPONSE: EPA's responsibility is to clean up a site. It does
not have any zoning authority. EPA also added that the demolition of
the smelting facility is nearly complete, and neither the structure nor
equipment will remain at the site.
5. COMMENT: A resident expressed concern that the property would
not be returned to the tax rolls as long as the landfill was present on
the site.
EPA RESPONSE: Although the portion of the property north of the
railroad tracks would have limited use due to the existing landfill, it
should have little or no impact upon the future use of the property
south of the railroad tracks (the former industrial area).
8
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II. Written Comment Received During the Public Comment Period
Comments received by EPA during the public comment period for the NL site are compiled
in this section and are immediately followed by EPA's responses.
A. REMEDIAL ACTION OBJECTIVE FOR SOIL AND SEDIMENT
1. COMMENT: Since the 500 to 1,000 ppm cleanup range for lead in soils
established by EPA's Interim Guidance is a recommendation for residential
settings, it does not apply to the Pedricktown site, an industrial property,
where children are not found.
EPA RESPONSE: The property comprising the NL site is zoned as an
industrial property. While a cleanup range of 500 to 1,000 ppm for lead in
soils is recommended in EPA's Interim Guidance on Establishing Soil Lead
Cleanup Levels at Superfund sites for residential properties, EPA's selection
of the 500 ppm cleanup level of lead in soils and sediments was based
primarily upon an Ecological Risk Assessment performed by EPA at the NL
site.
An Ecological Risk Assessment for the site was performed to develop a
cleanup level which would provide an acceptable degree of protection to
ecological receptors. During the study, lower species in the food chain
(earthworms) were exposed to varying concentrations of lead-contaminated
soil. The earthworms bioaccumulated lead from the contaminated soil. The
amount of lead in the earthworms was then used to extrapolate (via a
mathematical model of the food chain) how much lead would accumulate in
receptor species which fed upon the earthworms. The risk was then
calculated for each receptor. The results were evaluated and used to define
a concentration of lead which would pose an acceptable level of risk to
receptor species. This concentration is 500 ppm of lead in soils and sediments
at the NL site.
The cleanup level was developed for ecologically sensitive areas of the site
where receptor species could come into contact with contaminated soils and
sediments. However, non-ecologically sensitive areas, such as the former
plant area, could contribute to the future degradation of ecologically sensitive
areas if they are not remediated to a protective level. By removing lead-
contaminated soils and sediments above 500 ppm throughout the site, the
likelihood of higher concentrations accumulating in ecologically sensitive areas
will be greatly reduced.
All contaminated areas of the site, except the plant area of the site, require
remediation to a level of 500 ppm of lead due to ecological concerns. The
plant area is approximately 244,800 square feet. An excavation to a depth of
approximately three inches would be required to meet a cleanup goal of 1,000
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ppm of lead in the plant area. An excavation to a depth of approximately six
inches would be required to meet a cleanup goal of 500 ppm of lead. The
difference between excavating three inches to meet a 1,000 ppm cleanup level
and six inches to meet a 500 ppm cleanup level is approximately 2,266 cubic
yards. This difference represents less than six percent of the total volume of
soil and sediments to be excavated under EPA's remedy. Since the plant area
would require excavation in any event, the only additional cost of excavating
this area to 500 ppm of lead versus 1,000 ppm would be the cost to treat and
dispose of the additional 2,266 cubic yards of excavated soil. Conservatively
assuming $150 to treat and dispose of this material per cubic yard via
solidification/stabilization, the total additional cost would be $340,000. This
represents less than six percent of the remedial soil and sediment treatment
and disposal costs. In addition to protecting the ecologically sensitive areas
of the site, the 500 ppm cleanup level will allow for unrestricted future use of
all areas of the site, and will be protective of both human health and the
environment.
2. COMMENT: The weight of evidence as presented in EPA's Ecological Risk
Assessment for the NL site does not support a 500 ppm cleanup level for lead
in soils and sediments.
EPA RESPONSE: During the performance of the Ecological Risk
Assessment, EPA carefully considered many factors in developing conclusions.
These factors included: the detrimental effects of the contaminants in the soils
and sediments to biota; the uncertainties associated with the evaluation of
ecological risk; and the impacts to the environment which could be anticipated
to occur as a result of the remediation. The Ecological Risk Assessment
Report is available in the information repository established for the site. The
report clearly supports all of EPA's conclusions.
B. HUMAN HEALTH RISK ASSESSMENT
1. COMMENT: EPA's model of childhood lead exposure should not be applied
to an industrial site to establish cleanup levels.
EPA RESPONSE: EPA's model of childhood lead exposure was not used
to develop cleanup levels for this site. Rather, a site-specific Ecological Risk
Assessment was performed to aid in the development of a cleanup level which
is protective of biota at the site.
2. COMMENT: The Human Health Risk Assessment shows that no potential
adverse health effects are posed by lead at the site. Furthermore, the Risk
Assessment evaluated the future use of the site as industrial, and concluded
that there would not be any potential adverse health effects from exposure to
lead in soils for a worker population.
10
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EPA RESPONSE: The EPA-approved Human Health Risk Assessment
performed at the site clearly indicates that lead levels detected in soil,
sediment and ground water pose an unacceptable risk to human health. In
a baseline human health risk assessment, a cancer potency factor and a
reference dose are numerical factors used to quantify risks posed by particular
contaminants. However, in the case of lead, there is no EPA accepted cancer
potency factor or reference dose established. Therefore, the risk or potential
adverse health effects to humans from exposure to lead can not be quantified.
A qualitative evaluation of health impacts posed by lead in soils, sediment and
ground water indicates that the concentrations of lead detected in these media
are above levels of concern to human receptors. Exposure to lead has been
associated with human noncarcinogenic effects. The major adverse effects in
humans caused by lead include alterations in red blood cell production and
the nervous system. High concentrations in the blood can cause severe
irreversible brain damage and possible death.- EPA has also classified lead
as a "B2" carcinogen, which indicates that it is considered a probable human
carcinogen.
With regard to all exposure scenarios considered in the baseline risk
assessment, where there was a quantified non-acceptable cancer or non-cancer
risk, it is plausible that the cumulative cancer risk and hazard indices would
be even higher if lead were included.
EPA agrees that the future use of the site is likely to be industrial. However,
the Risk Assessment did not conclude that there would not be any potential
adverse health effects from exposure to lead by a future worker population.
As explained above, the potential risks due to the exposure of a worker
populations (or any other human receptors) to lead can not be quantified.
EPA has determined, on a qualitative basis, that lead levels detected in soils
at the site are unacceptable to human receptors.
C. ECOLOGICAL RISK ASSESSMENT AND STUDY
1. COMMENT: EPA's failure to define the goals of its Ecological Risk
Assessment, which links the data measured to the risk management process,
calls into serious question the overall relevance of its risk assessment and the
validity of its final conclusions.
EPA RESPONSE: The objective of EPA's Ecological Risk Assessment was
to collect empirical data on target receptors and surrogate organisms and to
use these data to assess the ecological risk of lead contamination at the NL
site. The data collected were used to evaluate ecologically based cleanup
goals for soils and sediments at the site. The following specific areas of
concern were addressed in the study: bioaccumulation of lead by aquatic and
terrestrial fauna exposed to contaminated sediment and soil; laboratory
toxicity evaluation of sediment; and existing habitat evaluation.
11
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The objective of the ecological assessment, the study design, and the method
of data interpretation and evaluation are clearly defined within the Ecological
Assessment Workplan and the Final Field Ecological Assessment Report
(June 1993). The workplan and final report are available for review in the
information repository established for the site.
2. COMMENT: The analysis of the data collected during the Ecological Risk
Assessment suggests that the distribution of lead at the site is heterogenous,
not homogeneous. The study failed to acknowledge that potentially significant
portions of the 200-acre study area have lead concentrations below the
discrete values used in the Ecological Risk Assessment (1,000 ppm, 2,000
ppm, etc.). This resulted in biased overestimates of wildlife exposure.
EPA RESPONSE: EPA agrees that the distribution of lead in site soils and
sediments is heterogenous. The intent of the study was to evaluate the
potential for risk in order to make an informed risk based management
decision in selecting a cleanup level. The study's design required the use of
soils at discreet contaminant concentrations, which EPA assumed to be
present throughout the entire 200-acre study area, in order to evaluate the
related effects upon ecological receptors. This methodology provided EPA
with a conservative estimate of risk posed to wildlife by evaluating exposure
at each soil concentration evaluated.
3. COMMENT: The Ecological Risk Assessment does not establish a strong or
consistent correlation between lead levels in soils and in earthworms and
white-footed mice. The field investigation failed to demonstrate that
concentrations in earthworms decreased with decreasing exposure to lead.
The inadequacy of the field investigation, the foundation of the Ecological
Assessment, largely invalidates its use as support for the lead cleanup criterion
of 500 ppm selected in the Proposed Plan.
EPA RESPONSE: Several factors adequately account for the low correlation
between soil lead levels and the accumulation of lead by earthworms observed
during the Ecological Risk Assessment. First, it is known that many soil
characteristics alter the bioavailability of lead in soil. These include, but are
not limited to pH, organic carbon content, particle size distribution, type of
soil organic matter, cation exchange capacity, specific soil mineralogy and the
chemical form of lead present.
There are several lead forms which were observed or deemed likely to be
present at the site including elemental lead from batteries, lead from within
the battery casing material, lead released through air emissions during facility
operation, and solubilized lead from spilled solutions. The first two forms
were observed directly and have a limited but undefined distribution. The
second two may or may not have changed chemical forms since deposition.
The first two forms must be weathered to become bioavailable. All of these
factors were considered in the evaluation of lead availability, and ultimately
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the risk posed. These factors may explain the high degree of fluctuation
between soil lead levels detected and lead accumulation in earthworms.
However, a high correlation between soil lead levels and lead accumulation
by earthworms is not necessary to appropriately evaluate the availability and
threat posed by the soil lead levels.
A sub-study of the earthworm accumulation study evaluated the relationship
between the time the earthworms were stationed in the contaminated soil and
the concentration of lead in the earthworms. This study was conducted in
order to assess whether or not the accumulation study was of sufficient
duration to assume steady state tissue concentrations at the end of the 20-day
exposure. The data generated clearly show an accumulation of lead with
time. It also showed that as soil lead levels increase, the degree of
accumulation of incremental amounts of lead decreases. This observation is
consistent with the findings of other studies /ound in the literature on lead
accumulation. It is therefore evident that there is a relationship between soil
lead levels and the lead levels found within the earthworms exposed to the
contaminated soils. However, not surprisingly, this relationship is not a simple
linear relationship and has many confounding factors. It was not the intent
of the study conducted to explore the myriad of factors influencing the
bioavailability of soil lead levels at the NL site. The study's objective was
simply to collect sufficient information to conduct a reasonable and objective
Ecological Risk Assessment.
Although a simple relationship does not exist between lead soil levels and
earthworm tissue levels, it is clear that the earthworms accumulated lead from
the soil. Furthermore, this supports the finding that there is a potential risk
to species such as the woodcock (which feed on the earthworms). The data
generated suggest that at levels greater than 500 ppm of lead in soil at the NL
site, there is the potential for adverse effects. In fact, potential risks exist at
even lower concentrations. The risk management decision, therefore, was not
based upon the most conservative evaluation of the model. The uncertainties
associated with the model assumptions, along with other considerations,
support the selection of 500 ppm of lead as the remedial action objective for
soils and sediments. However, it is acknowledged that there may be some
undefined magnitude of risk posed to receptors similar to the woodcock at
levels below the remedial action objective.
With respect to the lead accumulation by mice, the study design only
incorporated three exposure levels. Therefore, the lack of a "strong
correlation" between tissue levels and soil levels is again not surprising.
However, an evaluation of data trends shows that at the highest soil
concentrations, there was the greatest bioaccumulation of lead in mice. As
with the earthworm study, this demonstrates that there is a relationship
between soil lead levels and bioaccumulation of lead at the site.
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4. COMMENT: The hazard quotient approach used by EPA inappropriately
characterizes a population's or community's risks.
EPA RESPONSE: In a human health risk assessment, the hazard quotient
is confined to an individual's risk. However, in an Ecological Risk
Assessment, the hazard quotient may be used to evaluate the risk to
individuals, populations or communities of organisms. In the Ecological Risk
Assessment performed for the NL site, the risk posed to a species was
characterized. The species was chosen to be representative of the species and
communities of ecological receptors that exist around the NL site. For
instance, mink was used to represent carnivores, owls represented raptors,
mice represented herbivores, and the red fox represented an omnivore.
5. COMMENT: The Ecological Risk Assessment states that the hazard quotient
should be interpreted based on the severity of the effect reported and the
magnitude of the calculated quotient. Therefore, the effects on the woodcock,
which have the highest hazard quotient estimates, would be further reduced
because the toxicity endpoints of reduced ALAD (an enzyme which is crucial
to the production of hemoglobin) activity, hemoglobin, hematocrit, and brain
weight of nestlings are not considered to be as severe as the toxicity endpoints
of survival, reproduction or growth.
EPA RESPONSE: The Ecological Risk Assessment used reduction in ALAD
activity, hemoglobin and hematocrit and brain weight of nestlings as toxicity
endpoints. Of these toxicity endpoints, reduced brain weight of nestlings was
the key indicator of detrimental reproductive success because reduced brain
weight may cause reduced learning ability. For example, a nestling could have
difficulty learning to fly, recognizing predators, or even recognizing food. All
of these factors severely impair reproductive success, growth and survival of
the nestling. This implies that the toxicity endpoints of reductions in ALAD
activity, hemoglobin, hematocrit, and in brain weight of nestlings are
indicative of, and as severe as, the toxicity endpoints of survival, reproduction
or growth.
6. COMMENT: Midge toxicity test data do not support EPA's claim that there
is a lead dose-response correlation.
EPA RESPONSE: EPA did not conclude from the midge toxicity testing that
there was a simple lead dose-response correlation. The objective of the
testing was to define the concentration at which toxicity effects from lead on
the midge (an insect) would be observed. As part of the study, EPA
determined the level of lead in sediment samples which would cause no
response to the exposed midge (Chironomus tentans). The midge were
exposed to varying levels of lead in sediment samples. Midge toxicity was
observed when the organisms were exposed to approximately 1,000 ppm of
lead. Therefore, 1,000 ppm of lead is considered the best estimate of the
LOAEL (Lowest Observable Adverse Effect- Level). The LOAEL is the
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lowest value at which a toxicity response was observed in the test organism.
7. COMMENT: EPA's hypothesis that survival of the test organism (the midge)
is related to increased bioavailability of lead caused by pH depression is
speculative and is not supported by the available data.
EPA RESPONSE: EPA did not conclude that survival of the test organism
was related to increased bioavailability of lead that was caused by pH
depression. The Ecological Risk Assessment included statements
acknowledging the uncertainties associated with the study results and factors
which must be considered in evaluating the ecological risks at the site.
Several of these factors related to the bioavailability of lead, and the relation
of pH to the test organisms' survival. Lead is generally more bioavailable at
lower pHs. Based upon the literature, the test organisms can not survive
under extremely acidic conditions (depressed pH). The organisms' pH
tolerance range was discussed in the Ecological Risk Assessment. In addition,
the study data showed that the test organisms had the greatest response
(mortality) at the lowest concentrations of lead, which also had the lowest pH.
The data also showed that at higher pHs, there was little mortality at
concentrations at or above 1,000 ppm of lead in the sediment.
8. COMMENT: Page 10 of the Ecological Risk Assessment states that
invertebrates comprise 43 percent of the diet of robins, with 57 percent of the
diet comprised of fruits and vegetation. Table 3 in Appendix B provides an
exposure calculation based upon worms being 100 percent of the diet. This
inconsistency results in a hazard quotient that is roughly twice what it should
be.
EPA RESPONSE: With respect to the robin exposure calculations, the
Ecological Risk Assessment did not study lead accumulation for alternate
diets for robins (including fruits and vegetation). Therefore, the conservative
assumption that earthworms would be representative of the total diet for
robins, was used in the risk model. This assumption was stated in the
exposure pathways for the model, and was appropriately and consistently
applied to the exposure calculation.
9. COMMENT: The X-Ray Fluorescence (XRF) data used to determine the soil
lead concentrations in the areas selected for assessing biological exposure to
contamination are of questionable value in a quantitative assessment of
exposures. XRF soil analysis significantly overestimates the lead
concentrations, which, in turn, results in an overestimation of the exposure
estimates for indicator species.
EPA RESPONSE: The XRF was used as a field screening tool, and the field
data analyzed by the XRF was confirmed in the laboratory through Atomic
Absorption (AA). The confirmatory analyses conducted demonstrate a clear
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relationship and good correlation between the XRF results and the
confirmatory AA results. Therefore, EPA believes that the XRF data
collected at the site provides a good representation of site soil concentrations.
10. COMMENT: EPA evaluated earthworm lead levels based on exposure of the
earthworms to soil lead concentrations in three ranges: less than 500 ppm;
500-1,000 ppm; and greater than 1,000 ppm. The use of these three ranges
is arbitrary, and the pattern of the earthworm lead levels is dependent on
these ranges. Further, uneven numbers of earthworms were observed from
each grouping. An alternate distribution of earthworm observations would
suggest that no correlation exists between lead levels in the soil and
corresponding levels in earthworms.
EPA RESPONSE: The groupings of lead concentration ranges were based
upon the need for evaluation of potential cleanup goals and are not arbitrary.
Since evaluation of the potential for ecological risk is an objective of the study
conducted, it is not critical to the evaluation that a clear statistical relationship
between total soil lead levels and earthworm accumulation exist. While it is
desirable from a mathematical standpoint to have balanced groupings for
statistical analyses, this is not critical to the interpretation of the data and the
risk assessment. The study determined that the earthworms accumulated
appreciable levels of lead from the soil which resulted in an ecological threat.
11. COMMENT: There are no statistically significant differences among the mean
lead concentrations in mice (dry weight) collected from areas of different lead
concentrations (different grid designations).
EPA RESPONSE: There are differences between the accumulation of lead
by white-footed mice in the grid areas. The lack of "statistical significance"
in lead accumulation in dry weight normalized tissue data was noted in the
text of the Ecological Risk Assessment. It was also stated that statistical
significance was found when the wet weight normalized data was evaluated.
However, as with the earthworm results, the important point is that the mice
within the contaminated areas accumulated lead, and this accumulation was
usable for the food chain threat model.
12. COMMENT: EPA has failed to consider that risks are derived from exposures
of biota to mean soil levels within their home range. The remediation of
areas which currently contain the highest soil lead levels would significantly
reduce the mean soil levels in the home range of the target species. Exposure
should be recalculated taking into account a potential post-remedial reduction
in the mean soil levels within a species' home range. This would decrease
the calculated mean exposure and risk significantly.
EPA RESPONSE: As part of the Ecological Risk Assessment, EPA selected
various areas of the site to evaluate impacts on receptor species at specific
lead concentrations. EPA considered the mean soil concentrations of lead
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within these specific areas in order to evaluate risks posed to the receptors
within these areas. The areas selected were not based on the home range of
the target species. The mean concentration for each specific area evaluated
was used to represent the entire home range of the target species. This is due
to the fact that organisms typically do not utilize their home range evenly.
There are preferred areas for nesting, resting and feeding. Many species
utilize only a small portion of their home range. Since it is not practical, or
in many instances possible, to directly evaluate wildlife utilization of a site,
this method assured a reasonable conservative evaluation of risks posed to the
target species.
The commentor suggests that EPA recalculate the ecological risks posed by
lead contamination at the site taking into account a potential post-remedial
reduction in the mean soil levels within a species' home range. This approach
is inappropriate as the purpose of the risk assessment was to evaluate the
current risks at the site. This evaluation is used by EPA to determine
whether to take a cleanup action at the site and the type of action which may
be required. The Ecological Risk Assessment performed at the site clearly
demonstrated that unacceptable risks are posed to biota by lead-contaminated
soils and sediments. EPA's selected remedy for the site will address these
risks. All risks posed by the site will be reduced to an acceptable level after
remediation.
13. COMMENT: The use of scientifically justifiable alternative values for some
of the exposure parameters (e.g., home range) and toxicity thresholds would
reduce the hazard quotient estimates developed in the Ecological Assessment.
The Ecological Assessment proportionately overestimates risks for the
woodcock, and a cleanup level derived from consideration of risks to the
woodcock would be proportionately too low.
EPA RESPONSE: The Ecological Risk Assessment utilized what EPA
considers to be the most reasonable and justifiable values for exposure
parameters and toxicity thresholds. EPA believes that these values provide
EPA a reasonable and appropriately conservative predicted risk from which
to make a risk management decision.
It is obvious that utilizing alternate exposure parameters and toxicity
thresholds would alter the hazard quotient estimates developed in the
Ecological Risk Assessment. The altered hazard quotient would, in turn, alter
the predicted risk to the target species, and thus the cleanup level.
The objective of the Ecological Risk Assessment was not to conclusively
determine the risk to the individual target species, such as the woodcock.
Rather, the Ecological Risk Assessment provided risk-related information on
a representative target species, from which ecologically based risk
management decisions can be made.
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14. COMMENT: The area use factor is incorrectly applied in the Ecological Risk
Assessment. The area use factor relates how much a particular area is
utilized by a target species relative to another particular area within a target
species' home range.
EPA RESPONSE: In order to generate a very specific data set for the area
use factor and lead levels existing within the study area, an extremely
extensive and costly study would be needed. Fortunately, this was not
necessary to evaluate the scenarios considered in this study. Area use factors
were appropriately applied in the performance of the Ecological Risk
Assessment.
This study evaluated exposure of target species to soil lead levels of 1,000
milligrams/kilograms (mg/kg) and 2300 mg/kg, even though the average
concentration of lead over the 200-acre study area is likely to be less. EPA
assumed that any use of the area by the target species, other than that
considered in the exposure scenario, would result in increased exposure of the
target species.
In the case of the NL Ecological Risk Assessment, EPA selected area use
factors that resulted in a conservative assessment of risk. However, EPA does
not agree that this approach significantly overstates the risks posed to the
target species.
15. COMMENT: Available data suggest that a hazard quotient of 8.25
mg/kg/day and a home range of 108 acres for the woodcock should have
been used in the Ecological Risk Assessment.
EPA RESPONSE: EPA agrees that the home range for woodcock is 108
acres. Unfortunately, EPA neglected to incorporate the correct home range
of 108 acres into the final Ecological Risk Assessment. However, since the
area use factor is equal to one, the numerical value of the home range for the
woodcock has little effect upon the calculation of the hazard quotient.
Therefore, the correct hazard quotient of 8.25 mg/kg/day was used, and the
use of the incorrect home range did not impact the risk calculations or
conclusions.
16. COMMENT: Available data suggest that a lead toxicity threshold of 2.5
mg/kg/day is appropriate for the red fox.
EPA RESPONSE: EPA did utilize the 2.5 mg/kg/day lead toxicity threshold
in the risk model in the final Ecological Risk Assessment.
17. COMMENT: In its Ecological Risk Assessment, EPA uses a home range size
of 57.5 hectare (ha) for the red fox, which is the smallest home range
reported in the literature. It is recommended that the average red fox home
range should be 698 ha, as this estimate was used by EPA for an Ecological
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Risk Assessment performed for the Burnt Fly Bog Superfund site. This figure
(698 ha) was deemed by EPA to be the average of available home range
values from the literature.
EPA RESPONSE: EPA's estimate of home range value is justifiable for use
at the NL site since utilization of areas for foraging by the red fox are uneven.
The site also has several different types of landscape including fields, streams,
woodlands and wetlands, which may have varying degrees of utilization. The
use of conservative home range values accounts, to a degree, for the potential
for preferential use of the more highly contaminated areas for foraging by the
receptor species.
18. COMMENT: There is strong reason to question the validity of EPA's toxicity
threshold of 2 mg/kg/day for mink. The value which EPA used was based
upon field study data for otters (Mason and MacDonald, 1986). The 1986
study showed no clear correlation between lead intake (as measured by lead
in feces) and adverse population effects could be established.
EPA RESPONSE: There is some uncertainty associated with any
lexicological data available for the development of ecological risk models.
There are instances where limited options are available for obtaining model
parameters. Parameters for otters from the Mason and MacDonald study
were applied in EPA's mink exposure model, as parameters for mink were not
available. EPA believes that the otter is an appropriate surrogate species for
mink as applied in the Ecological Risk Assessment.
Although a simple mathematical correlation was not clearly demonstrated in
the Mason and MacDonald study, the study indicated that where there was
lead in the feces above an established threshold value, there could be an
adverse effect to the target species.
19. COMMENT: In the exposure assessment for mink at the NL site, EPA
assumed that 50 percent of the mink's diet consisted of the white-footed
mouse, which is an upland mammal. If the consumption of upland mammals
is to be considered for the mink, it is improper to limit the home range of the
mink to the length of an aquatic habitat (non-upland areas) at the site. It is
suggested that EPA should have used the average mink home range expressed
in terms of area, and not length of aquatic habitat. Available data suggests
that 476 acres is an appropriate home range value for mink at the NL site.
EPA RESPONSE: In performing the Ecological Risk Assessment, EPA
assumed that the mink's home range is adjacent to the site's aquatic habitat
(the streams). This assumption is appropriate for use in evaluating ecological
risks.
As discussed in the previous comment regarding the home range of the
woodcock, since the area use factor for mink is equal to one, the home range
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has little effect upon the hazard quotient or the calculated risk. EPA selected
model parameters, such as home range, which yield conservative evaluations
of the risk such that the potential risk will not be underestimated. This
approach can be clearly seen in the mink risk evaluation.
The models presented in the Ecological Risk Assessment are meant to be
representative of important food chains and exposure pathways in the
environment at the site. The collection of field data and its use in the model
is intended to represent the potential exposure which may occur at the site
given certain assumptions. Minks are carnivores. Since EPA collected site-
specific lead concentration data for both frogs and white-footed mice, it was
assumed that each contributed 50 percent to the mink's diet. The frog
represented the aquatic forage base, while the white-footed mouse
represented the non-aquatic forage base of the mink in the model.
20. COMMENT: The dry weight of soils analyzed in the Ecological Risk
Assessment was measured by drying at 105° Celsius (C) after screening
through a 1.0 millimeter (mm) sieve. The American Society of Testing
Materials (ASTM) protocol specifies that drying should be performed at 60°
C and a 0.5 mm sieve should be used for screening.
EPA RESPONSE: EPA believes that the drying temperature and sieve size
used for soil analysis are valid values. Since the specific ASTM protocols for
measuring dry weight sieve size are not specified by the commentor, EPA is
unable to respond to the comment directly.
21. COMMENT: The relevance of using cadmium chloride as a reference toxicant
in the Ecological Risk Assessment is not apparent.
EPA RESPONSE: Cadmium chloride was used as a reference toxicant to
provide a reference for evaluating the sensitivity of the stock population of
test organisms (i.e. earthworms).
22. COMMENT: There is no evidence that the reference sediment analyzed
during the Ecological Risk Assessment was matched to the sample sediment
from the site with regard to Total Organic Carbon (TOC), particle size, and
PH.
EPA RESPONSE: The primary factor in the selection of the reference
sediment location was concentration of lead at this location. EPA desired to
obtain reference sediment from an upstream (less impacted) area, which was
as similar as possible in TOC, particle size and pH to contaminated on-site
sediment. The most appropriate reference area was selected based upon the
information available at the time of the study.
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23. COMMENT: Sediment samples obtained during the Ecological Risk
Assessment were not analyzed with regard to the presence of any chemical
contaminants with the exception of lead.
EPA RESPONSE: Extensive sampling of soil, sediment, ground water and
surface water was conducted during the Remedial Investigation performed at
the site. A number of samples collected from all media were analyzed for full
Target Compound List and Target Analyte List compounds. Based upon the
data collected during the RI, EPA determined that the presence of lead in
soils provides a good indication of the presence of other contaminants of
concern, including cadmium and zinc. The Ecological Risk Assessment
determined the risk to ecological receptors posed by lead. Other
contaminants of concern would pose additional risk. EPA believes that since
lead is the most abundant contaminant of concern at the site, efforts aimed
at remediating lead contamination would also address the other contaminants
of concern at the site.
-\
24. COMMENT: EPA did not confirm laboratory toxicity to benthic (sediment
dwelling) organisms by field testing in the streams.
EPA RESPONSE: Field benthic community evaluations were considered in
the study design and rejected because of the soft bottom and intermittent
behavior of the site streams. These characteristics are not conducive to field
testing of benthic communities. Laboratory toxicity testing was considered
adequate for the purposes of the Ecological Risk Assessment.
25. COMMENT: There are many stages of the Ecological Risk Assessment during
which EPA failed to follow ASTM procedures.
EPA RESPONSE: ASTM is not the sole source of standardized or
scientifically defensible procedures for the performance of such studies. Since
the comment does not further elaborate on deviations from ASTM
procedures, EPA can not further respond to this comment. However, it
should be noted that scientifically sound and standard methods were used
during the Ecological Risk Assessment.
26. COMMENT: There were several specific errors in the Ecological Risk
Assessment, which include: the incorrect calculation of the hazard quotient for
the red fox's daily intake at Areas I/IA and III of the site; the incorrect listing
of the hazard quotient for Area I/IA as 10.06 in Table 8, where the actual
hazard quotient is 6.06; and, the incorrect listing of the hazard quotient for
Area HI as 14.13 where the actual hazard quotient is 8.66.
EPA RESPONSE: These errors were corrected and have been incorporated
into the risk calculations in the Final Ecological Risk Assessment.
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D. SEDIMENT REMEDIATION
1. COMMENT: The water quality of the stream segments north of Route 130
should dramatically improve as a direct result of removal of the contributing
sources of the contamination. This removal includes the recently completed
cleanup of the plant area (including slag, lead-bearing debris, contaminated
buildings and contaminated standing water), and the future cleanup of
upstream contaminated site soils and stream sediments during implementation
of the Record of Decision (ROD) for Operable Unit One as well as EPA's
Phase V Removal Action.
EPA RESPONSE: Removal of upstream sources may reduce the potential for
further degradation of surface water quality. However, without removing
contaminants above ecologically-based cleanup levels throughout the stream,
improved surface water quality could not b,e ensured since contaminated
stream sediments may become resuspended and cause surface water
degradation.
2. COMMENT: The proposed excavation and dredging of sediments north of
Route 130 will be severely detrimental to the aquatic environment in the
stream. Such dredging is likely to result in downstream transport of lead-
bearing sediments and redistribution of contamination. Dredging these
stream sediments would be destructive to the existing ecosystem, increasing
turbidity and decimating the benthic flora and fauna. In addition, the ongoing
flow and deposition of new sediments from upstream to downstream, from
south to north, a process that is continual in the stream, will create a natural
cap on top of the sediments north of Route 130.
EPA RESPONSE: EPA believes that removal of contaminated sediments
above 500 ppm of lead from the stream north of Rt. 130 can be accomplished
without releasing significant amounts of lead during the operation. A number
of engineering techniques are available and will be evaluated during the
Remedial Design stage to accomplish this task. These include temporarily
damming sections of the stream at both ends, with influent water being
pumped around these sections while the sections are being excavated. Silt
screens could be used as well to control any accidental release of
contaminants during dredging. A hydraulic vacuum could be utilized to
remove the contaminated bottom layer of the stream without significantly
suspending contaminants. Collected sediments may be dewatered, and then
treated along with contaminated soils.
The ecosystem of the stream north of Route 130 has been detrimentally
impacted by site-related contamination and EPA has determined that the
ecological benefits of remediation outweigh any temporary impacts.
Contaminants remaining in the stream bed, even if covered by a sediment cap,
could become exposed due to varying water flow or enter the food chain via
bottom dwelling organisms. The reintroduction of lead into the aquatic
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environment, and the entry of lead contamination into the food chain, would
have a deleterious effect upon the downstream ecosystem.
E. SOIL REMEDIATION
COMMENT: Soil washing has been tested under a number of conditions, at
a number of lead-contaminated sites, and has not worked. The key to the
success of this technology is the makeup of the soils and sediments. Particle
size distribution, organic content and soil texture appear to be key parameters.
In the present case, soil compositions are diverse and inappropriate for soil
washing technologies which have been tested and suggested to date. It is
unlikely that a soil washing technique can be found which will work under
these site conditions or achieve the remedial action objectives.
EPA RESPONSE: In the FS and the Proposed Plan, EPA examined a
number of options for addressing the contaminated soils and sediments.
Many of the options included either solidification/stabilization or soil washing
as a treatment element.
Soil washing is a promising innovative technology which has been successfully
applied to soil remediation at a number of Superfund sites. In the Proposed
Plan for the NL site, EPA stated that a treatability study would be required
to determine the operating parameters for washing of the contaminated site
soils and sediments. The uncertainties associated with the soil washing
technology would be quantified during this study to determine if the treatment
would be successful in rendering the soils and sediments non-hazardous and
in achieving the remedial action objective for soil and sediment of 500 ppm
of lead.
Although soil washing has not been widely used on lead-contaminated soils
and sediments, there have recently been favorable applications of soil washing
involving such soils. The most recent application has been at the Twin Cities
Army Ammunition Plant in Minnesota. This process used a combination of
physical separation techniques with an acid extraction step to remove lead
from contaminated soils and sediments. At the NL site, a bench-scale study
was conducted by the Center for Hazardous Materials Research, which
applied the soil washing technology to site soils and sediments. This
application was successful in reducing lead contaminant levels from
approximately 30,000 ppm to 1,000 ppm. This study was limited in scope, but
indicated that the technology may be successful at the site.
It is possible that a process which combined physical separation and acid
extraction could be applied successfully at the NL site. Physical separation
would remove the oversize particles (greater than 0.25 inches) from the soil
media. The acid-leaching portion of the treatment would chemically remove
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lead molecules from the soil and sediment particles by solubilizing the lead
in an acidic solution.
Based upon comparable applications of the soil washing technology, EPA
believes it is likely that soil washing would render the soils and sediments
non-hazardous, and may meet the remedial action objective of 500 ppm for
lead in soils and sediments. While EPA agrees that soil textures and particle
size distribution are key factors in determining the feasibility of soil washing
at any site, there are no available data to suggest that the soils and sediments
at the NL site would not be amenable to soil washing.
The above notwithstanding, EPA has modified this portion of the remedy. As
discussed below, EPA has selected solidification/stabilization technology for
the treatment of contaminated soils and sediments.
2. COMMENT: S/S is a proven, cost-effective treatment for the soils and
sediments at the NL site, and can be more easily implemented than soil
washing.
EPA RESPONSE: EPA selected soil washing as the preferred alternative
presented in the July 1993 Proposed Plan. However, based upon comments
received during the public comment period, EPA has reevaluated all
alternatives considered in the Proposed Plan for contaminated site soils and
sediments. Many of these comments dealt with the implementability and cost
of the proposed remedy. Based upon EPA's reevaluation of the proposed
remedy and consideration of the comments received, EPA is selecting the S/S
technology, instead of soil washing technology, for the treatment of
contaminated soils and sediments.
Soil washing provides the benefit of permanently removing contaminants from
the soil matrix. Preliminary studies indicate that this technology may be
successfully applied at the NL site. However, EPA recognizes that in order
to implement a soil washing remedy, an extensive treatability study would be
required. Comprehensive sampling would be required to further define the
characteristics and distribution of contaminated soils and sediments. This
effort may be time consuming and costly. In addition, if the treatability study
indicated that soil washing would not be successful at the site, EPA would
need to select an alternative treatment technology.
S/S is a process which physically and chemically binds contaminants into an
immobile matrix. Although S/S may increase the volume of treated soils and
sediments, and thus may increase the size of the on-site landfill to be
constructed, EPA agrees that S/S is a proven treatment process for rendering
contaminated soils and sediments non-hazardous, and further, is more easily
implemented than soil washing. In fact, the S/S technology was used as part
of an earlier remedial action at this site to treat lead-contaminated slag. EPA
anticipates that solidifying/stabilizing the soils and sediments could be
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completed at least one year sooner than soil washing, while providing
protectiveness of human health and the environment and greater short-term
effectiveness than soil washing. Costs presented in the Proposed Plan also
indicate that S/S will be less expensive to implement than soil washing.
Therefore, EPA has selected S/S as the remedy for contaminated soils and
sediments. EPA believes it would be readily implementable, has a high
probability of success, and is a cost-effective method of achieving the remedial
action objectives.
3. COMMENT: The Town of Pedricktown supports the proposed treatment for
the contaminated ground water, stream sediments and surface water. The
town does not object to the proposed treatment process for soils and
sediments. However, the Town disagrees with treating only those soils and
sediments classified as hazardous waste and would like EPA to treat all the
contaminated soils and sediments, thus eliminating the proposed on-site
landfill.
EPA RESPONSE: In the Proposed Plan, EPA stated that nine evaluation
criteria were used to evaluate each alternative. Protectiveness of human
health and the environment is one of the nine evaluation criteria.
Alternative-B (treating all soils and sediments above the remedial action
objective) and Alternative-F (the selected soils and sediments treatment
alternative which treats only the hazardous soils and sediments and landfills
nonhazardous soils and sediments above the remedial action objective) are
both protective of human health and the environment. The cost is estimated
to be 22 million dollars for Alternative-B versus 6.5 million dollars for
Alternative-F. Based upon EPA's evaluation of all alternatives against the
nine criteria, EPA believes that Alternative-F provides an acceptable level of
protection to human health and the environment, is cost effective, and
represents the best balance of all alternatives evaluated. It should also be
noted that a 6.6 acre landfill already exists on a portion of the property which
is north of the railroad tracks. The additional landfill requirement to
implement the selected remedy is expected to be less than 2.5 acres. The
planned landfill is expected to be placed adjacent to the existing landfill north
of the railroad tracks.
F. GROUND WATER REMEDIATION
1. COMMENT: The RI demonstrated that the zone of ground-water
contamination is limited, has not impacted off-site areas, and generally
consists of concentrations of target compounds that marginally exceed ground-
water quality standards.
EPA RESPONSE: EPA disagrees with this comment. The site extends to
areas that have been impacted by site-related contamination. The RI data
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clearly indicates that ground-water contamination underlying the former plant
area of the ML property has been consistently measured at levels greater than
an order of magnitude higher than health-based drinking water standards.
Ground water outside the former plant area generally demonstrates lower
concentrations of contaminants, some of which are above ground-water quality
standards. Levels detected in residential wells, which are located off site at
some distance from the former plant area, currently comply with ground-water
quality standards.
2. COMMENT: The RI demonstrated that the contaminants of concern are not
mobile and that the zone of ground-water contamination is not expanding
over time. Some data indicate that contamination may be decreasing.
EPA RESPONSE: The RI clearly demonstrates that contaminants of
concern have migrated from the plant area of the site. Ground-water data
demonstrates that lead contamination has migrated beyond the source at the
NL plant and is migrating in a northwesterly direction toward the Delaware
River. The aquifer underlying the site is conducive to the migration of
contaminants. Ground-water contours indicate a ground-water gradient of
0.0038 to 0.011 ft/ft with the predominate flow in northwesterly direction.
Previous data collected at the site from a pump test (Geraghty & Miller,
1983) established the hydraulic conductivity of the unconfmed aquifer to range
from 1.87 to 45.52 ft/day. Geraghty & Miller (1983) calculated a linear flow
velocity that ranges from 0.03 to 2.02 ft/day for the unconfined aquifer with
an assumed porosity of 0.25, which indicates a fairly mobile aquifer.
3. COMMENT: The RI failed to correlate the extent and distribution of ground-
water contamination in the shallow aquifer with the distribution of soil
contamination at the site.
EPA RESPONSE: Based on the RI, soil and ground water are both
significantly impacted by contamination originating from previous plant
operations at the site. The location and distribution of contamination in
ground water and soil are not expected to directly correlate with each other
because soil contamination is relatively stationary as a result of deposition,
and ground-water contamination is generally mobile as a result of
contaminant transport through the aquifer. The transport and distribution of
contaminants in ground water are a function of several factors such as
absorption, desorption, dilution and dispersion. However, a site-wide review
of the RI data indicates that the highest ground-water contamination
underlying the plant area generally coincides with the most severe soil
contamination.
4. COMMENT: The RI failed to provide an adequate characterization of either
the shallow unconfined aquifer or the actual connection with lower aquifer
systems. It failed to explore potential mechanisms to explain the behavior of
the target compounds in ground water.
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EPA RESPONSE: The RI clearly characterized both the shallow and lower
sections of the unconfined aquifer. The RI defined the aquifer characteristics,
including its thickness, hydraulic conductivity, porosity, ground-water gradient,
direction of flow, and flow velocity. The terms "shallow" and "lower" aquifer
are used in the RI to differentiate between the shallow and lower section of
the unconfined aquifer. The RI discussed contaminant mobility with regard
to the above-mentioned aquifer characteristics, along with the mobility of lead
under conditions found in the aquifer. However, EPA believes, and the RI
stated, that updated and more detailed aquifer data would be required to
design any ground-water remediation system. This information will be
obtained during the RD stage.
5. COMMENTS: The FS did not include an assessment of the technical
feasibility of the recovery of contaminants of concern for the shallow,
unconfined aquifer.
RESPONSE: The FS described a conceptual ground-water extraction system,
along with a treatment system to remove contaminants of concern from the
extracted ground water. The RI/FS indicates that contaminants of concern
were detected at levels which greatly exceed Maximum Contaminant Levels
(MCLs) and could be recovered through a ground-water recovery system. The
FS clearly provided a conceptual scheme for the recovery of contaminants of
concern from the shallow, unconfined aquifer. During the Remedial Design
(RD) stage of the project, additional work will be performed including:
additional data collection; ground-water modeling of contaminant transport;
and treatability studies. This information will be used in the detailed
engineering design of the ground-water recovery and treatment system.
6. COMMENTS: The proposed use of the existing ground-water recovery
system is a solution of convenience which fails to address actual conditions
and the documented zone of contamination.
EPA RESPONSE: EPA did not propose to use the existing ground-water
recovery system. In EPA's Addendum to the FS, it is clearly stated that the
existing recovery system will be evaluated for its potential use in the recovery
of ground water during the RD. Based on this evaluation, the existing
recovery system will either be used, modified, or abandoned. The final
recovery system will address ground-water contamination above health-based
levels and will be designed during the RD stage.
7. COMMENT: The assessment of ground-water remediation strategies did not
consider the source(s) of ground-water contamination, or the potential effects
of source removal (industrial area sources and soils) on the long-term aquifer
quality.
EPA RESPONSE: Contributing contaminant sources from the slag piles and
contaminated debris, which were a source of contamination since at least
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1984, have been removed and remediated under the Operable Unit Two
remedy. Soil which is contaminated above EPA's remedial action objective
will be remediated as part of the selected remedy for soil, in conjunction with
the selected ground-water remedy. Therefore, all potential continuing sources
of contamination to the aquifer will be addressed as part of the remedy for
Operable Unit One.
The design of the selected ground-water extraction system will be based on
appropriate data, some of which will be collected in the Remedial Design
phase of the project. Site conditions since the removal of significant sources
of contamination emanating from the plant area will be reflected in the design
as appropriate. It will also incorporate the effect of remediating soils
contaminated with lead above the remedial action objective. Even after the
surface sources of contamination have been eliminated, ground water which
is already contaminated will require remediation to meet health-based levels
established for the aquifer.
8. COMMENT: The proposed extraction rate for the ground-water extraction
system is unrealistic and does not consider aquifer capacity.
RESPONSE: EPA has not proposed a rate of pumping for the ground-water
extraction system. The estimated pumping rate of 250 gallons per minute was
intended only to be used for the comparison of remedial alternatives and the
relative cost associated with each alternative. As stated in EPA's Addendum
to the FS, pumping rates, configuration of the ground-water extraction system,
and location of extraction wells as described in FS Report were not intended
as a final design. The ground-water extraction system will be designed during
the RD stage, and will consider aquifer capacity as a design parameter.
9. COMMENT: The remedial strategy for ground water is based on the premise
that there is a substantial and imminent threat to public health. This premise
is contrary to the findings documented in the RI and re-stated in the Proposed
Plan.
EPA RESPONSE: Concentrations detected within the ground water
underlying the site exceeded the remedial action objectives for both lead and
cadmium by over an order of magnitude. These remedial action objectives
are based upon water quality standards established to protect public health.
The RI showed that lead in ground water in the vicinity of the former plant
area ranged from 3,130 parts per billion (ppb) to 4,400 ppb, and cadmium
concentrations ranged from 6 ppb to 997 ppb. The remedial action objective
for lead in ground water is the New Jersey Ground-Water Standard of 5 ppb
with a Practical Quantitation Limit (PQL) of 10 ppb. The PQL is the lowest
concentration that can be reliably detected by a laboratory during routine
laboratory operating conditions, as established by the NJDEPE, as part of the
New Jersey Ground-Water Standards. The remedial action objective for
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cadmium is the New Jersey Ground-Water Standard of 4 ppb. Other metals
detected on the site at elevated levels include arsenic, beryllium, chromium,
copper, nickel and zinc. Volatile organic compounds exceeding Federal
MCLs were found in two wells, and include 1,1,1 trichloroethane at levels up
to 4,700 ppb, 1,1-dichloroethane at 74 ppb, 1,1 dichloroethylene and
tetrachloroethene at 210 ppb, and vinyl chloride at 76 ppb.
The Human Health Risk Assessment concluded that there was an
unacceptable risk posed by exposure to ground water for future exposures
(under current and future land uses) via ingestion, dermal adsorption, and
inhalation. It should be noted that the risk posed by lead could not be
quantified, however, it is deemed to be present in unacceptable levels based
on a qualitative risk evaluation. A quantitative risk assessment was performed
for contaminants other than lead which were detected at the site. This risk
assessment resulted in the calculation of risk levels which exceeded EPA's
acceptable risk range. Since ground-water contamination exceeds established
remedial action objectives for the protection of human health, and poses
unacceptable risks, it represents a substantial and imminent threat to public
health and the environment, necessitating remediation of the aquifer.
10. COMMENT: The conceptual ground-water remediation strategy includes
restoration of a non-use aquifer to ground-water quality standards (for
primary drinking water sources) as a means to protect a public which, as
agreed by EPA'in the Proposed Plan, is not now being exposed.
EPA RESPONSE: The ground water underlying the site is classified as Class
2A, a potable drinking water source, by the State of New Jersey. Future
exposure pathways under current and future land-use scenarios indicate that
this ground water would pose unacceptable risks to human health as a result
of ingestion, dermal adsorption, and inhalation at current contaminant levels.
Because of the aquifer's classification as a potable drinking water source, it
will be remediated to established health-based drinking water standards.
11. COMMENT: Both Alternative G-2 (discharge of treated ground water to the
Delaware River), as well as Alternative G-l (discharge of treated ground
water to the East or West Streams) should be retained, and the selection of
the final discharge point should be made during the Remedial Design phase
of the project. Alternative G-2 may be more implementable and cost
effective than Alternative G-l, and both alternatives are feasible in terms of
time, permitting and access.
EPA RESPONSE: EPA believes that adequate information is available at this
time to determine the most appropriate ground-water treatment and discharge
alternative.
Both Alternative G-2 (discharge of treated ground water to the Delaware
River), and Alternative G-l (discharge of treated ground water to the East or
29
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West Streams) include similar ground-water treatment systems. However,
discharge to the on-site streams would likely require a reverse osmosis unit.
The reverse osmosis unit would be designed to remove total dissolved solids
(TDS) from the treatment plant effluent to meet applicable discharge
standards.
As discussed in the Proposed Plan, EPA agrees that Alternatives G-l and G-2
would be equally protective of human health and the environment. Both
alternatives would require similar and available treatment technology and can
be constructed on site. However, it is likely that Alternative G-2 would not
require a reverse osmosis unit, which would make the system easier to
operate. Reverse osmosis units often require a significant amount of
maintenance to operate reliably and are expensive to run.
The system for surface discharge associated .with Alternative G-l would be
easier to construct and maintain than the discharge system for Alternative G-
2, which would require a pipeline to be constructed from the site
approximately one and one-half miles to the Delaware River to transport and
discharge treated ground water. The pipeline could be constructed using
standard construction techniques and would traverse off-site properties
between the site and the Delaware River.
In the Proposed Plan, EPA stated that there was uncertainty with respect to
procuring the appropriate access agreements prior to construction. The
planned discharge pipe would cross underneath rail road tracks (between the
plant area and the landfill) and Route 130, which may require additional
access agreements and permits from state and local government, as well as
private parties. Construction of such a pipeline in marshy areas and wetlands
may be difficult to implement.
Written comments submitted to EPA included letters from private property
owners whose right-of-way would be required to build the pipeline to the
Delaware River under Alternative G-2. EPA has reviewed these letters which
indicate that the necessary land-owning parties have no objection to entering
into negotiations for the granting of an easement to construct the pipeline.
In addition, B.F. Goodrich, a neighboring facility, recently constructed its own
discharge pipeline under Route 130 and through the U.S. Army Corp of
Engineers Dredge Spoils to the Delaware River.
Therefore, currently available information indicates that discharge of treated
ground water to the Delaware River described in the Proposed Plan
(Alternative G-2) may be more easily implementable than previously
envisioned relative to discharge to the on-site streams (Alternative G-l).
Since the treatment plant required for Alternative G-2 would be more reliable
and economical to operate than that required for Alternative G-l (because
discharge to the Delaware River is not likely to require a reverse osmosis unit
to reduce TDS in the effluent), EPA has chosen Alternative G-2, discharge
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of treated ground water to the Delaware River, as the selected remedy for
ground water.
12. COMMENT: The Proposed Plan does not consider the RFs recommendation
for additional investigations, nor the FS's recommendation for further
evaluation of ground-water reinjection options. The final selection is made
despite this lack of information.
EPA RESPONSE: The RI included a comprehensive study to determine the
nature and extent of contamination in site soils, sediments, surface water and
ground water. The RI Report contains an extensive analysis and discussion
of aquifer characteristics, as well as the findings of the ground-water, soil,
sediment and surface-water analyses at the NL site. The RI Report contained
all relevant data necessary to develop and evaluate ground-water remediation
alternatives. During the RD phase, supplemental information will be
obtained as necessary to perform the detailed engineering design of the
selected ground-water remediation system.
The FS Report contains extensive discussion regarding the many ground-water
reinjection options evaluated during the FS. EPA evaluated a total of seven
different options for addressing contaminated ground water at the site. Five
of these included various means of reinjecting treated ground water into the
aquifer underlying the site.
In addition to the two surface-water discharge options evaluated, the Proposed
Plan and the FS thoroughly evaluated two alternatives which include the
reinjection of treated ground-water into the aquifer. These were Alternative
Ground Water-E, reinjection into the unconfined aquifer, and Alternative
Ground Water-F, reinjection into the confined aquifer. Sufficient information
was available during the writing of the FS and the Proposed Plan to evaluate
each alternative and to select a ground-water remedy. Ground-water
reinjection options were thoroughly evaluated and took into consideration a
number of factors including the aquifer characteristics. Based on EPA's
detailed evaluation of all ground-water discharge options, it was determined
that the reinjection options were not as implementable as the options which
included surface water discharge of the treated ground water. The evaluation
of all ground-water discharge options, based on the nine criteria established
under CERCLA, is presented in the FS Report and summarized in the
Proposed Plan.
G. PHASE V REMOVAL ACTION
1. COMMENT: EPA's Phase V removal action, which includes the removal of
contaminated sediments from the West Stream, is inconsistent with the
National Contingency Plan (NCP).
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EPA RESPONSE: EPA's Action Memorandum authorizing a removal action
at the ML site in Pedricktown, New Jersey, was issued on July 15, 1993. The
NL site meets the criteria for a removal action under the Comprehensive
Environmental Response, Compensation and Liability Act, as amended
(CERCLA), and as described in Section 300.415 of the NCR
The following criteria from Section 300.415(b)(2) of the NCP are directly
applicable to the threats that exist at the NL site:
(i) Actual or potential exposure to nearby human populations, animals, or
the food chain from hazardous substances, or pollutants, or
contaminants;
(ii) Actual or potential contamination of drinking water supplies or
sensitive ecosystems;
(iv) High levels of hazardous substances, or pollutants, or contaminants in
soils and sediments largely at or near the surface that may migrate;
(v) Weather conditions that may cause hazardous substances, or pollutants,
or contaminants to migrate or be released; and
(vii) The lack of availability of other appropriate federal or state response
mechanisms to respond to a release.
In addition, EPA determined that this removal action is a time-critical action,
as there is a period of less than six months available before cleanup activities
should begin. Due to the time-critical nature of this removal action, EPA
initiated the Phase V Removal Action in July 1993.
2. COMMENT: The removal action is not consistent with the long-term remedy
at the NL site as required by the NCP. In addition, all upgradient sources
have not yet been removed, possibly allowing the stream to become
recontaminated.
EPA RESPONSE: The on-going removal action is consistent with, and will
contribute to, the efficient performance of any anticipated long-term remedial
action at the site. All of the contaminated sediments addressed under this
removal action would have been addressed during future remedial activities.
The removal action provides immediate protection of public health, welfare
and the environment. Without taking immediate action, overflow of stream
banks could deposit lead-contaminated sediments on adjacent downstream
properties. Flooding of the stream could transport contaminated sediments
further downstream, affecting the water quality of the Delaware River.
During dry periods, highly contaminated dried sediment could become
airborne and expose humans and environmental receptors to lead bearing
dust.
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EPA is concerned about protecting the West Stream from recontamination.
Upgradient contaminant sources, such as lead bearing debris and slag piles,
have been removed during the Operable Unit Two remedial action. Although
contaminated soils remain between the West Stream and the plant area of the
site, measures will be taken during the removal action to prevent
recontamination of the West Stream from contaminated soils.
3. COMMENT: There will be an inherent waste of mobilization costs for the
removal action, since remediation of the West Stream could be carried out at
the same time as remediation of the East Stream and site soils.
EPA RESPONSE: This removal action, and the entire cost of this removal
action including mobilization costs, are justified based upon the removal
action criteria listed in §300.415(b)(2) of the NCP. In addition, EPA has
determined that this removal action is time critical, and, as stated in EPA's
July 1993 Removal Action Memorandum, a prompt removal activity is
necessary to protect public health and the environment.
4. COMMENT: More than 12 months have elapsed since removal activities
began on site. Thus, the Phase V removal actions contravenes CERCLA and
the NCP §300.415(b)(5).
EPA RESPONSE: The NCP §415(b)(5) provides that, for fund-financed
removal actions, more than 12 month may elapse from the initiation of
removal activities on site if the lead agency determines that; (i) there is an
immediate risk to public health or welfare of the environment; or (ii)
continued response action is otherwise appropriate and consistent with the
remedial action to be taken. In the case of this removal action, EPA has
determined that both conditions have been met
5. COMMENT: EPA was required to conduct an engineering evaluation/cost
analysis (EE/CA), which should have been made available for public
comment. No EE/CA was ever performed or distributed for public comment.
EPA RESPONSE: In accordance with Section IV.A.4 of EPA's Action
Memorandum, issued on July 15, 1993, the proposed removal action was
determined by EPA to be of a time-critical nature; therefore, an EE/CA is
not required.
6. COMMENT: EPA has known the identity and location of numerous
Potentially Responsible Parties (PRPs) prior to the onset of this removal
action. EPA did not notify any of the PRPs regarding any phase of the
removal action, nor had EPA made any effort to determine whether the PRPs
could or would perform the necessary removal action promptly and properly.
EPA RESPONSE: EPA indicated in Section VII of the Action Memorandum,
issued on July 15,1993, the time-critical nature of this removal action in order
33
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to protect the public and the environment. EPA has identified a number of
PRPs for the site. However, EPA believes that notification of the PRPs and
negotiation of an administrative order to provide for the performance of the
Phase V Removal Action by the PRPs would be a lengthy process. This
would likely have prevented a timely initiation of the removal action as
required by the circumstances at the site pursuant to the NCP.
7. COMMENT: The Phase V removal action is a thinly disguised public works
project.
EPA RESPONSE: As stated previously, the Phase V removal action is
justified by, and consistent with the NCP based on threats to human health
and the environment.
8. COMMENT: While EPA will be excavating the first foot of sediment from
the stream, EPA is voluntarily donating resources to the Salem County
Mosquito Control Commission (SCMCC) stream enhancement program by
excavating the stream to 14 feet wide, while it is currently only up to six feet
wide. EPA is spending federal (Superfund) funds to remove specific areas
based upon local flooding concerns dictated by the SCMCC, rather than any
environmental criteria described in §300.415 of the NCP.
EPA RESPONSE: EPA's coordination with the SCMCC represents efficient
planning and coordination between federal and local governments. The
removal of contaminated sediment and soil was dictated strictly by
environmental concerns, and not by drainage concerns. All material
excavated under this removal action is above EPA's established cleanup
criteria of 500 ppm of lead in soil and sediment (which is consistent with
EPA's cleanup criteria determined in this ROD). Furthermore, the removal
action being performed meets all of EPA's removal action criteria and is
consistent with the long-term remediation of the site.
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APPENDIX V
RESPONSIVENESS SUMMARY
ATTACHMENT A
LETTERS SUBMITTED DURING THE PUBLIC COMMENT PERIOD
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George W. Bradford
Township Mayoiv
Phone i 299-5358
Township Clerk
Mildred A. Hyatt
Phone: 299'2949
_.
OlDMANS TOWNSHIP
SALEM COUNTY NEW JERSEY
299-0?80
/?93
p Q Box P
Pedricklown- NJ- °8067
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OLDMANS TOWNSHIP
SALEM COUNTY NEW JERSEY
6
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8c AUSTIN
INCLUDING MOmSIONAl. OOBPOIIAnOHC
ONE FIBST KATIOKAI. PLAZA.
CHIG*OO.IIXINOXS 60603
TELEPHONE ais: B53-7OOO
KEWTOHZ TZIJEX 85-4364 SPTOAPOHE
VASKTNGTOK, D.C. FACSThDXE 312: 853-7036 TOKYO
FOTJIOJED 1866
WHXnzre DQZZCT 1*UM&^B
Sqrtember 17, 1993
Michael Gilbert, Project Manager
U. S. Environmental Protection Agency
Emergency and Remedial Response Division
26 Federal Plaza, Room 720
New York, New York 10278
Re: N. L. Industries. Inc. Superfund Proposed Plan
Dear Mr. Gilbert
Pursuant to Section 300.430(f)(3)(C) of the National Contingency Plan, the
companies listed below1 submit these comments to the United States Environmental
Protection Agency ("U.S. EPA') on the proposed plan for Operable Unit 1 at the N. L.
Industries, Inc. Superfund Site in Pedricktown, New Jersey ("Proposed Plan"). Our
comments mainly address two anas of concern:
* The soil clean-up standard and soil-washing technology proposed by the U.S.
EPA and our suggested alternatives to the proposed technology.
* Groundwater data and die extraction plan chosen in the Proposed Plan.
The discussion below is intended to summarize the more expansive discussions
contained in Attachments A through C.
1 The parties to mis correspondence are: Allied Signal Inc., AT&T, C&D Charter Power
Systems, Inc., Exide Corporation, and Johnson Controls, Inc. Please note that of these
companies, Sidley & Austin represents only Johnson Controls in this matter.
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SIDLEY & AUSTIN CHICAGO
Michael Gilbert
September 17, 1993
Page 2
1. SoD Clean-up.
As noted, our concerns regarding soil clean-up center on the 500 ppm
standard chosen as the soil remediation level and the technology U.S. EPA has chosen to
address contaminated soils. Irrespective of what clean-up limit may be appropriate, we offer
alternatives to the suggested technology which are both implementable and more cost
effective.
a. Critique of Proposed Flan.
Regarding the 500 ppm remedial action objective, the Proposed Plan first
establishes that, according to a guidance entitled "Interim Guidance on Establishing Soil
Lead Clean-up Levels at Superfund Sites," the recommended soil clean-up range is 500 -
1000 ppm. The Proposed Plan then implies that the principal basis for choosing a 500 ppm
standard was the site ecological study. Attachment A evaluates the ecological assessment,
noting three important inadequacies: (1) U.S. EPA felled to follow its own guidance
regarding defining assessment endpoints (i.t., specific designations of the ecological
grouping to be protected) prior to conducting the assessment; (2) the assessment is based on
a simplistic model that does not meet U.S. EPA's stated goals; and (3) the assessment is
based on data collected in such a manner as to preclude meaningful assessment of site-
specific risks. The evaluation concludes that the ecological risk assessment is flawed and
does not provide a sound basis for the 500 ppm lead clean-up standard.
Reliance on the interim guidance as a basis for justifying the 500 ppm
standard is equally problematic. First, on its face the guidance applies to clean-up in
residential areas. However, the site is currently in an industrial area, and given that a
hazardous waste landfill will remain on-site, the site is unlikely to be used in the future as a
residential area. Consequently, the use of a residential clean-up criteria designed to protect
young children is inappropriate. The clean-up standard should instead be specific to the
potential health threats to adults who might be present at the site during the work day.
Furthermore, we understand that the U.S. EPA intends to revise its guidance for the clean-
up of lead at Superfund sites. Recent efforts under the Housing and Community
Development Act indicate that even for residential areas the current U.S. EPA-preferred
strategy for remediation may be to require excavation of soil containing lead at levels of
2,000 ppm and above, but to allow the undertaking of other activities for clean-up of soils
with lead levels under 2,000 ppm. A major reason for this current position is the
government-sponsored studies in urban areas over recent years which indicate little
correlation between blood lead levels in children and soil lead levels in the surrounding
areas. In particular, soil removals in Baltimore and Boston had little or no effect on
subsequent blood levels in children, and blood studies in other areas, like Granite City,
Illinois and Aspen, Colorado also indicate little correlation.
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SIDLEY & AUSTIN CHICAGO
Michael Gilbert
September 17, 1993
Page 3
Finally, reliance on a guidance without both independently supporting the
premises set forth in the guidance and taking into account case-specific factors is tantamount
to illegal rulemaking. See McLouth Steel Products Corp. v. Thomas. 838 F.2d 1317 (D.C.
Cir. 1988). Other than the flawed ecological site assessment, there is no evidence that the
U.S. EPA gave serious consideration to any site-specific factors in its selection of a soil
clean-up level. In the absence of useful site-specific information, relying on the guidance as
if it were a binding rule is illegal since the document has not been subjected to proper
rulemaking procedures. For all these reasons, U.S. EPA's decision to set the soil lead
action level at 500 ppm is untenable scientifically and is entirely unsubstantiated in the
record.
Regarding son clean-up technology, Attachment B discusses EPA's proposal
to use soil washing. In short, soil washing has been tested under a number of conditions, at
a number of sites, and has not worked. The key to the success of this technology is the
make-up of soil - particle size distribution and soil texture appear to be key parameters. In
the present case, soil textures are diverse and inappropriate for technologies which have
been tested and suggested to date, and it is unlikely that a soil-washing technique can be
found which will work as necessary under these site conditions or achieve the remedial
action objective.
b. Alternative Proposal.
The parties to this correspondence propose the following alternatives, which
we believe provides a greater environmental benefit than the remedy in the Proposed Plan at
reduced cost. As our first alternative, we propose that soils which exhibit a hazardous
characteristic be stabilized and consolidated on-site with other soils exceeding the action
level. As our second alternative, we propose that soils which exhibit a hazardous
characteristic when tested according to the Toxic Characteristic Leaching Procedure be taken
off-site and stabilized before land-filling. Soils which exhibit the same hazardous
characteristic, but fall within the exemption to U.S. EPA's land disposal restrictions because
they do not fail the Extraction Procedure Toxicity test, would be disposed of off-site in a
hazardous waste landfill without treatment Soils that do not exhibit a hazardous
characteristic, under our second proposal, would be consolidated on site or transported for
use as daily cover at a local landfill, where the soils would serve a useful function and yet
be removed from the site.
In addition to the environmental benefits conferred by total removal from the
site, we think it worth emphasizing that the soil-washing technology cannot be implemented
without great expense, relative to the other alternatives. As noted in Attachment B, while
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SIDLEY & AUSTIN CHICAGO
Michael Gilbert
September 17, 1993
Page 4
soil-washing would cost in excess of at least $10 million without any assurance of success,
our first alternative would cost about $5.6 million, and our second alternative would cost
between $7 million and $8.4 million.
2. Groundwater Rglpfdffltjop Under the Proposed Plan.
a. Critique of Proposed Plan.
The comments set forth in Attachment C regarding groundwater question both
the current relevance of the groundwater data and also the interpretation of that data, in the
Remedial Investigation, in the choice of alternatives set forth in the feasibility study, and in
the Proposed Plan.
The data used to develop the groundwater response action is now four years
old. Groundwater measurements were taken at the site over an extended period of time
preceding 1989, and throughout the monitoring period there was a general downward trend
in contaminated concentration. Given the propensity of metals to adsorb to soil particles, it
is likely that the trend has continued and that the groundwater problems raised in four-year
old data may be greatly attenuated. The fact that lead is quickly immobilized in soil also
leads to questions about the interpretation of the alleged groundwater problem. Commonly,
if lead does migrate downward through soil, its continued migration depends on there being
an acidic environment. While battery acid may have been present at the site during
operation, it has not been present over the last decade. Rather than being viewed as a
plume, the presence of lead is probably residual and contained.
Regarding the source of any lead which may have migrated to groundwater at
the Pedricktown site, it would likely be traced to former sources of acid on-site, such as the
batteries which were received at the facility and lay about it over an extended area during
times in which the smelter furnace was not operating; the battery breaker itself, from which
acid may have leaked; or perhaps the site acid holding tank which, according to facility
records, may have leaked during the facility's operation. Another possibility is the landfill,
which may have spiked the groundwater with some lead when its leachate collection system
clogged.
Even if actionable levels of lead remain in the groundwater after soil
remediation, the use of the current wells to extract groundwater in accordance with the
Proposed Plan will result in the extraction of a large amount of clean water because of their
placement outside of the area of concern. In turn, that clean water will be mixed with
contaminated water, and a large volume of slightly contaminated water will have to be
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SIDLEY & AUSTIN CHICAGO
Michael Gilbert
September 17, 1993
Page 5
discharged. Rather than rely on an exterior ring of wells to extract the groundwater, if
necessary at all, wells should be located in the areas showing the most severe contamination
and pumped in a manner which n>foimiyf$ mixing with clean water.
b. Groundwater Recommendations.
Given the downward trend of the data and the possible sources for lead
migration to groundwater, the parties to this correspondence recommend that U.S. EPA
draft a Record of Decision that allows sufficient latitude for an appropriate groundwater
remedy design to be determined based on information gathered as and after soil remediation
occurs. We propose that U.S. EPA proceed with the soil remediation and take groundwater
samples during mat period. At the end of the soil remediation period, given the results of
the sampling and analysis, U.S. EPA should then consider which groundwater design is
most appropriate and proceed accordingly. If groundwater is no longer a problem,
U.S. EPA should reconsider the no-action alternative.
If recovery wells are shown to be necessary after further sampling, the Record
of Decision should also allow sufficient latitude to permit reinjection of treated groundwater,
as the groundwater flow rate is likely to be much less than predicted in the Feasibility
Study. This option requires allowing latitude for the creation of a Classification Exception
Area, as provided for by State regulations, which permits discharge of treated water back to
the aquifer at higher concentrations than the standard as long as groundwater is restored to
the applicable standard at the completion of the groundwater treatment process. The small
amount of lead contained in the groundwater will be immobilized and the perceived problem
will cease without contaminating thousands of gallons of clean groundwater unnecessarily or
moving trace amounts of lead into a local stream.
We thank you for this opportunity to comment on the Proposed Plan and
request that the Record of Decision appropriately address the parties' comments.
very truly,
Dennis P. Reis
PRrlcd
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ATTACHMENT A
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COMMENTS ON USEPA'S PROPOSED CLEAN-UP LEVEL FOR LEAD
AT THE NL INDUSTRIES, INC SITE, PEDRICKTOWN, NEW JERSEY
Prepared by:
WEINBERG CONSULTING GROUP Inc.
1220 19th Street, NW
Washington, D.C 20036
August 30,1993
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COMMENTS ON USEPA'S PROPOSED CLEAN-UP LEVEL FOR LEAD
AT THE NL INDUSTRIES, INC SITE, PEDRICKTOWN, NEW JERSEY
Weinberg Consulting Group Inc.
1220 Nineteenth Street, KW. Suite 300
Washington, D.C 20036-2400
(202) 8334077 • Fax (202) 833-7057
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TABLE OF CONTENTS
INTRODUCTION
REVIEW OF SEDIMENT TOXICITY TESTS 1
Interpretation of die Results 1
Methodological Problems with the Toxicity Tests 3
REVIEW OF ECOLOGICAL RISK ASSESSMENT 4
Assessment Endpoints 4
Risk Assessment Model 5
Exposure Assessment 6
Availability of Other Data 7
CONCLUSIONS C 7
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COMMENTS ON USEPA'S PROPOSED CLEAN-UP LEVEL FOR LEAD
AT THE NL INDUSTRIES, INC SITE, PEDRICKTOWN, NEW JERSEY
INTRODUCTION
USEPA (1993a) has proposed a remedial objective for lead of 500 ppm in wetland soils and
stream sediments of the NL Industries Inc. site in Pedricktown, New Jersey (NL site). This
remedial action objective was derived based on USEPA's interpretation of the results of a
field ecological assessment and an ecological risk assessment conducted for the site.
Specifically, USEPA (1993b) derived this objective based on the results of sediment toxicity
tests conducted at the site and men used the results of an ecological risk analysis conducted
for potential terrestrial wildlife inhabitants of the site to substantiate mis lead level. We
believe that the proposed remedial action objective for lead is not supported by the analyses
presented by USEPA. In fact, we do not believe that USEPA has yet demonstrated that the
site poses any risks to aquatic or terrestrial wildlife populations.,and that remediation for the
protection of wildlife might not be warranted. This document provides support for our
position.
REVIEW OF SEDIMENT TOXICITY TESTS
USEPA conducted site-specific toxicity tests on the midge, Chironomus tertians, using
sediment samples collected from two streams that drain the site to the east and west (East and
West streams). Samples were collected from areas of the streams that were identified by the
use of field screening analyses as having sediment lead concentrations within specified target
levels ranging from less than 100 ppm to greater than 2,000 ppm. Based on the results of the
C. tentans assays, USEPA concluded that there was demonstrable toxicity associated with site
sediments at sediment lead concentrations of 1,100 ppm. To derive the remedial objective of
500 ppm, USEPA applied an arbitrary safety factor of 2 to mis number and rounded off to the
lowest 100.
We believe that the remedial objective proposed by USEPA is not supported by the results of
the sediment toxicity tests. Further, we believe that the toxicity tests relied on by USEPA
were seriously flawed and should not be used as the basis for regulatory decision making at
the NL site.
Interpretation of the Results
USEPA (1993c, p. 33) notes that "mortality of midge larvae exposed to site sediment was not
directly related with (sic) sediment Pb concentrations." In fact, based on the data presented in
the reports, there is no relationship at all between midge mortality or other test endpoints and
sediment lead concentrations. In addition, the data suggest that other factors are the possible
cause of the observed responses.
1
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Toxicity test data do not support USEPA's claim that there is a lead dose-
response relationship. It is an accepted principle of environmental toxicology that
the response of an organism to a toxicant is a function of the dose of the toxicant.
Thus, if lead in sediments from the NL site was toxic to C. tentans, we would expect
a correlation to exist between lead concentrations and toxicity endpoints. Using the
data presented in the USEPA (1993c) report, we calculate a coefficient of
determination (r2) for the hypothesized relationship between sediment lead levels and
survival of 0.22, clearly indicating that no significant relationship between dose and
response exists. Further supporting the lack of a dose-response relationship is the fact
that C. tentans exposure to the highest sediment lead concentration (4,400 ppm) was
associated with precisely the same percent survival as the laboratory control sample.
Similar results are found for C. tentans length1 (an indication of growth). There was
no dose-response relationship (mean organism length was greater at 4,400 ppm than at
1,100 ppm), and there was no significant difference in mean length between organisms
exposed to 4,400 ppm lead (17.51 ± 0.96) and the controls (18.80 ± 1.03).
X
There also was no dose-response relationship for growth expressed as either wet-
weight or dry-weight. Further, the statistical significance associated with these tests
contradicts the basic dose-response relationship that USEPA purports to exist: growth
was statistically elevated for organisms exposed to 4,400 ppm lead compared to 1,100
ppm lead. It is difficult to hypothesize a mechanism of lead toxicity that implies a
negative relationship between dose and response.
USEPA's hypothesis that survival is related to increased bioavailability of lead
caused by pH depression is speculative and is not supported by the available data.
USEPA (1993c) notes that there were problems associated with pH and alkalinity
control during the assay and hypothesizes that reduced pH resulted in an increased
bioavailability of lead from the sediment The available data, however, do not support
USEPA's hypothesis. In fact, the quality and type of data available cannot even be
used to advance this speculation.
The pH measurement exhibited an extremely wide range in the various tests. Four of
the five samples had pH values outside of those associated with C. tentans in the
natural environment By the end of the experiment all of the samples had pH values
significantly different from the control sample. Based on our calculations, there is no
correlation (r2) between final pH and survival. Although alkalinity and pH are
chemically related, the problems with alkalinity control were even more striking than
with pH control Alkalinity was never detected in one sample and was found at the
detection limit in two others; thus, there is no analytical certainty concerning the
alkalinity measured. The alkalinity measurements changed markedly throughout the
'It should be noted that ASTM (1993) iBcrnmnrnds using weight inner than length as a measure of
C tentans growth.
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course of the experiment; in some cases increasing and in others decreasing. This is
likely a consequence of the low buffering capacity of the dilution water and the
tendency to achieve equilibrium with atmospheric carbon dioxide. Regardless of the
hypothesized mechanism, the differences in final alkalinity are sufficient to account for
73% of the variability in survival based on our analysis of the data. We also find
parallels between alkalinity and other toxicity endpoints measured in these bioassays.
Given these limitations, the only data that could be used to support USEPA's
speculation regarding increased lead bioavailability are measurements of lead in the
test water. However, no measurements were made of the amount of lead released into
the water, and therefore, the effect of pH can never be known. The failure to match
samples and the control with regard to pH, alkalinity, or conductivity further
complicates the interpretation. The aqueous chemistry of lead is extremely complex;
conclusions cannot be drawn without performing water quality analyses and, as
necessary, a speciation model The fact mat no significant correlation existed between
pH and survival suggests that USEPA's speculation is inaccurate.
Methodological Problems with the Toxicitv Tests
There are numerous concerns about the conduct of the toxicity test and its documentation that
further argue against USEPA's assessment of risk. These include the following:
• Dry weight was measured by drying at 105° C after screening through a
1.0-ram screen. ASTM (1993) protocol specifies 60° C and a 0.5-mm screen.
• The relevance of using cadmium chloride as a reference toxicant is not
apparent Not only was this irrelevant to the site, but the laboratory did not
have an adequate database for its interpretation. A more useful reference
toxicant would have been lead nitrate. Use of a soluble and bioavailable lead
salt would have helped to explain some of the anomalies observed with the
sediment samples. ASTM (1993) further recommends a sediment sample
spiked with the chemical of concern as a positive control.
-• There is no evidence that the control sediment was matched to the sample
sediment from the site. ASTM (1993) methods call for matching with respect
to TOG particle size, and pH. Lead does not appear to have been measured in
the control sediment
• Sediment samples were not analyzed with regard to the presence of any
chemical with the exception of lead. Factors known to potentially impact
benthic organisms such as grain size (except for a gross silt-sand-clay
classification) and sulfide content were not analyzed. Moisture content was
only measured on oven-dried sediment
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USEPA did not confirm laboratory toxicity testing by field testing. Since the
results from the laboratory were highly equivocal, field measurements of
diversity, enumeration, and lead in sediments would have been the necessary to
demonstrate toxicity to the benthos. As noted in USEPA guidance (USEPA
1989a), correlation of the abundance and distribution of animals and plants
with measurements of concentrations is useful to demonstrate sensitivity and to
contribute to the weight of the evidence for ecological risk.
There are many other stages of the test during which USEPA failed to follow
ASTM procedures, failed to document its following of procedures, or failed to
demonstrate mat modification to the procedure would have no effect on the
outcome.
REVIEW OF ECOLOGICAL RISK ASSESSMENT
-X
The risk assessment conducted by USEPA (1993d) does not adequately evaluate potential
ecological risks. First, the Agency fails to follow its own guidance with respect to defining
assessment endpoints prior to conducting the ecological risk assessment Second, the
ecological risk assessment is based on a conservative and overly simplistic risk assessment
model that does not meet the Agency's stated goals for ecological risk assessment Third, the
exposure assessment is based on data that were collected in such a manner as to preclude any
true evaluation of ecological exposures and risks. Finally, the overall risk assessment ignores
a large body of site-specific data that should be used to support an overall assessment of
potential site ecological risks.
Given these limitations, we believe mat the ecological risk assessment conducted by the
Agency cannot be used to support the remedial objective proposed for lead. Further, we
believe that a more complete ecological assessment would show that the ML site does not
pose a threat to terrestrial wildlife populations or other receptor populations or communities
and that remediation for the protection of wildlife is not be warranted.
Assessment Endpoints
USEPA guidance for ecological risk assessment (USEPA 1989b, 1992) states that an
important initial step in ecological risk assessment process is the definition of assessment
endpoints2 that can be used to guide the design, conduct, and interpretation of the ecological
risk assessment According to USEPA (1992), assessment endpoints are the ultimate focus in
risk characterization and link the measurement endpoints (the data) to the risk management
process. Without an a priori definition of the assessment endpoint, there is no context in
which to draw conclusions on the significance of the data collected during the ecological
* Assessment endpoints are explicit expressions of the actual environmental variable that is to be protected
(e.g., a sport fish population, an endangered species).
-------
study. In these instances, the measurement endpoints become the assessment endpoints upon
which the Agency bases its decision. This is in direct contrast to the Agency's own guidance.
USEPA's failure to define its assessment goals calls into serious question the overall
relevance of its risk assessment and the validity of its final conclusions.
Risk Assessment Model
According to USEPA ecological risk assessment guidance (USEPA 1989a,b), the goal of
Superfund ecological risk assessments is to determine the degree to which wastes associated
with a particular site have altered the structure, function, or interactions of biological
populations and communities or the systems of which they are a part This goal is consistent
with the generally accepted premise of ecological risk assessment (and ecology in general)
that effects on individual organisms are not significant unless they result in effects at higher
levels of biological organization3. USEPA, however, ignores this basic premise in
conducting the ecological risk assessment for the NL site, and instead, adopts a risk
assessment approach that is designed to evaluate potential effects on individual organisms
rather than populations or communities.
The hazard quotient approach used by USEPA does not characterize population
or community risks. USEPA uses the hazard quotient approach to characterize
potential ecological risks. This approach is based on estimating potential exposures in
individual organisms and comparing these to a toxicity criterion. Although valid when
used as a screening-level assessment to identify the need for additional study, the
hazard quotient approach in and of itself does not constitute a population- or
community-level risk assessment Generally, some type of model (quantitative or
qualitative) that links measured responses in individual organisms to population-level
or higher responses is needed. USEPA's failure to extrapolate, even qualitatively, the
predicted individual organism effects to the population or community level renders the
risk assessment meaningless.
Moreover, we believe that had these extrapolations been made, the conclusion of the
risk assessment would be that potential lead exposures associated with the NL site will
not result in any impacts on wildlife populations or communities. Given the size of
the available habitat area (which is considerably less than the 200 acres assumed by
the Agency), we believe that it is highly unlikely that the NL study area supports a
significant portion of the wildlife populations of the region.
The lexicological endpoints selected by the Agency are not relevant to assessment
of population-level effects. Consistent with the overall goal of ecological assessment
to evaluate population-level or higher effects, toxicological endpoints that are or can
be directly related to population growth, maintenance, or reproduction should be
*Tbc exception to this is endangered and threatened species for which the loss of a single individual is
regarded as significant. No endangered or threatened species exist at the NL site.
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selected for use in the ecological risk assessment. The toxicity endpoints selected by
the Agency as the basis for the toxicity values for non-raptor birds, however, are
sensitive organism-level endpoints that overestimate the no-observed-adverse-
effect-level (NOAEL) or lowest-observed-adverse-effect-level (LOAEL) based on
reproduction or other population-relevant parameters. Indeed, according to the
Agency, the LOAEL selected for robin and woodcock based on altered blood and
brain characteristics in starlings is in fact the NOAEL for reproductive effects. Use of
sensitive, organism-level lexicological endpoints in the ecological assessment results in
overestimates of potential population-level effects.
Exposure Assessment
The exposure assessment conducted by USEPA does not realistically characterize potential
wildlife exposures for the following reasons.
The data collected by USEPA provide a biased estimate of potential exposure.
According to USEPA (1992), wildlife exposures should be estimated by combining
information on the spatial and temporal distribution of chemicals with that of the
ecological receptors being evaluated. USEPA, however, did not define the spatial
extent of lead distribution at the NL site. Instead, the Agency used a biased sampling
scheme to define categories of lead concentrations at the site rendering the actual
distribution of lead at the site unknown. This approach results in a biased
overestimate of potential wildlife exposures because only "contaminated" habitat areas
at the site are factored into the exposure equation even though other equally habitable
areas are likely to have lower lead concentrations.
The analysis of the data collected by USEPA does suggest that the distribution of lead
at the site is heterogenous not homogeneous. For example, the data show mat high
lead levels are localized in West Stream, just south of the railroad tracks and north of
Pedricktown Road; lead concentrations in downgradient portions of West Creek and in
East Creek are substantially lower. Also, the data show that concentrations vary
considerably across very small areas (e.g., within 2 feet). Consequently, exposures
could be considerably less than those predicted using data obtained from the biased
sampling strategy.
Other approaches adopted by USEPA in the exposure assessment also result in
overestimates of exposure. For example, in estimating exposures for each receptor
species, USEPA alternately assumes that the entire 200-acre study area contains lead at
either less than 1,000 ppm, 1,000 to 2,000 ppm, or greater man 2,000 ppm. Clearly,
none of these conditions exist at the NL site. The failure to acknowledge that
potentially significant portions of the 200-acre study area have concentrations that fall
below these levels results in biased overestimates of wildlife exposures.
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The conduct of the earthworm study also results in overestimates of exposure. The
exposure regime for the earthworm study was artificially manipulated to increase
exposure concentrations by using surficial soils (0-1 inch depth) that were shown to
contain the highest lead concentrations. Concentrations in worms present at the site
and available as forage would be substantially lower than that observed in the
artificially manipulated worm study because worms in the natural environment would
also inhabit deeper soils and would be exposed to much lower concentrations overall
than were observed within the first inch of soil
Availability of Other Data
USEPA (1989a) guidance states that ecological assessment is usually based on the
weight-of-evidence approach. However, USEPA failed to take into account other data
obtained from the field ecological assessment when conducting the ecological risk assessment.
Consideration of these other data would support the contention that no ecological risks exist
at the NL site. For example, the study with earthworms demonstrated that no correlation
exists between mortality and exposure to lead in site soils4. Greater survival was observed in
worms exposed to 6,800 ppm lead compared to 120 ppm lead, and only a weak correlation
between worm weight and lead exposure was noted. Total body and organ (thymus, spleen,
testes, uterus, adrenal gland) weights from Peromyscus leucopus trapped at various areas on
the site did not show any relationship to lead concentrations in soil. These data along with
the observations in the C. tenians assay do not reveal significant toxicity or impact at lead
levels in the thousands of parts-per-million range. We believe mat the weight of evidence at
the NL site does not support a remediation goal of 500 ppm when the ecological field studies
are evaluated.
CONCLUSIONS
We believe mat tile proposed remedial action objective for lead is not supported by the
analyses presented by USEPA. Overall, the results from the toxicity testing are so anomalous
and equivocal that they are virtually useless from either an research or regulatory context
USEPA has not adequately demonstrated that lead was the source of toxicity to C. tentans,
nor has USEPA identified a level of safety for protection of the local benthic community.
Further, the ecological risk assessment conducted by USEPA does not evaluate nor
demonstrate the potential for impacts on wildlife populations or communities and is based on
a biased data set that results in overestimates of potential wildlife exposures. Finally, the
Agency ignores a body of evidence that collectively indicates that the proposed 500 ppm
remedial objective for lead for the protection of wildlife is not warranted.
4It should be stressed, however, that die earthworm studies also suffered from quality assurance problems
and annmaiiet and, therefore, may be of limited utility io assessing lead toxicity in rite soils.
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REFERENCES
American Society for Testing and Materials (ASTM). 1993. Annual Book of Standards
Volume 11.04. Philadelphia, PA.
United States Environmental Protection Agency (USEPA). 1989a. Risk Assessment
Guidance for Superfund - Environmental Evaluation Manual. Office of Emergency and
Remedial Response. Washington, D.C. EPA/540/1 -089/001 A.
United States Environmental Protection Agency (USEPA). I989b. Ecological Assessment of
Hazardous Waste Sites: A Field and Laboratory Reference. Environmental Research
Laboratory. Corvallis, OR. EPA/600/3-89/013.
United States Environmental Protection Agency (USEPA). 1992. Framework for Ecological
Risk Assessment Risk Assessment Forum. Washington, D.C. EPA/630/R-92/001.
United States Environmental Protection Agency (USEPA). 1993a. Superfund Proposed Plan.
NL Industries, Inc. Operable Unit One. Pedricktown, Salem County, New Jersey. July 1993.
United States Environmental Protection Agency (USEPA). 1993b. Recommendations for
Ecologically Based Lead Remedial Goals. National Lead Industries. Pedricktown, New
Jersey. ERB/ERD/OEER. June 1993.
United States Environmental Protection Agency (USEPA). 1993c. Field Ecological
Assessment National Lead Site. Pedricktown, Salem County, NJ. ERB/ERD/OEER. June
1993.
United States Environmental Protection Agency (USEPA). 1993d. National Lead Industries.
Pedricktown, New Jersey. Ecological Risk Assessment ERB/ERD/OEER. June 1993.
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ATTACHMENT B
COMMENTS ON PROPOSED
SOIL WASHING REMEDY
AND
ALTERNATIVE PLANS
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TABLE OF COKTEKTS
Page
1. INTRODUCTION 1
2. COMMENTS ON SOIL WASHING TECHNOLOGY . 1
A. Introduction 1
B. Review of EPA Literature 1
C. Soil Particle Size Considerations 3
D. King of Prussia Site 6
E. CHMR Study 6
3. ALTERNATIVE SOILS REMEDIES ^ 9
A. Introduction 9
B. Proposed Alternative Remedy 1 -
Stabilization/On-Site Consolidation 9
C. Proposed Alternative Remedy 2 -
Off-Site Disposal of Hazardous Soils/
On-Site Consolidation or Beneficial Use
Of Nonhazardous Soils 9
D. Comparison of Proposed Alternative Remedy 1
- Stabilization/On-Site Consolidation 10
E. Comparison of Proposed Alternative Remedy 2
- Off-Site Disposal of Hazardous Soils/
On-Site Consolidation or Beneficial Reuse
of Nonhazardous Soils 10
F. Summary 14
List of Figures
Figure 1 - Soil Hashing Applicable
Particle Size Range 5
Liat ef Tables
Table 1 - Soil Remediation - Comparison of
Alternatives 15
Table 2 - Soil Remediation - Comparison of Costs ... 17
-i-
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COMMENTS ON PROPOSED SOIL WASHING
AND ALTERNATIVE PLANS
1. INTRODUCTION
During the remedial investigation conducted by NL
Industries, total lead concentrations of up to 12,700 ppm
were detected in on-site soils and concentrations of up to
1,770 ppm were detected in off-site soils. EPA selected a
remedial action objective for soil of 500 ppm total lead and
a remedy which includes soil excavation, soil washing of
hazardous soils, on-site landfilling of nonhazardous soils,
and the backfilling of washed soils that meet the remedial
action objective into the excavated areas. The 500 ppm
remedial action objective will be addressed elsewhere; these
comments focus on the proposed remedy and suggest
alternatives to that remedy.
2. COMMENTS ON SOIL WASHING TECHNOLOGY
A. INTRODUCTION
In the proposed plan, EPA has selected a remedy which
provides for the excavation of all soils above the
remedial action objective and subsequent soil washing
of all hazardous soils. According to EPA, the
preferred alternative satisfies all statutory
requirements, including EPA's preference for treatment.
EPA also acknowledges that soil washing is an
innovative treatment technology and that a treatability
study will be performed during remedial design to
determine optimum design parameters. EPA's addendum to
the final feasibility study report comments that NL is
unjustly critical of soil washing, that concerns
regarding the applicability of soil washing to the site
would be addressed during laboratory, bench, and pilot
scale tests, and that information which has been
developed by EPA since 1990 suggests significant new
developments related to soil washing technologies.
B. REVIEW OF EPA LITERATURE
The NL Pedricktown Site Group has reviewed several EPA
publications which have been issued since 1990 related
to soil washing.
According to EPA's July 1991 Selection of Control
Technologies For Remediation of Lead Battery Recvclinci
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Sites.1 two sites have unsuccessfully attempted soil
washing of lead-contaminated soil. Lee's Farm in
Woodville, Wisconsin attempted soil washing with EDTA
after brief laboratory and bench-scale testing. This
attempt, however, was discontinued when material
handling problems became excessive. Basu et al. also
reported that EPA's Mobile Soils Washing System (MSWS)
was used at the ILCO site in Leeds, Alabama, and was
successful in reducing the level of lead in the ILCO
soil from 47,000 ppm to 1,300 ppm (e.g., a concentra-
tion which exceeds the remedial action objective at the
KL Pedricktown site). At the ILCO site, however,
severe material handling problems such as fine
particles clogging the filter and excessive suspended
solids loading to the EDTA/lead recovery system
prevented the MSWS from cleaning up the entire site.
Basu et al. also noted that EPA h.as recently completed
a series of laboratory tests on soil and battery casing
samples from metal recycling sites to determine, among
other things, the feasibility of reducing lead concen-
trations by soil washing. During these studies, soil
samples were subjected to bench-scale washing cycles
using water, EDTA, or a surfactant (Tide detergent),
respectively. The results of the study indicated that
soil washing did not remove significant amounts of lead
from any of the soil fractions, causing Basu et al. to
comment that the "results did not augur success for
battery breaker applications'*. The Bureau of Mines
researchers involved in the project believed that there
were a number of problems associated with the field
application of EDTA, including the cost of the reagent,
the extreme difficulty in filtering sands and silts,
the complexity of recycling EDTA, and the variety of
EDTA forms required (depending on the prevalence of
various lead species).
The U.S. Bureau of Mines has also performed soil
washing bench scale treatability studies at three lead
battery recycling sites (C&R Battery, VA and United
Scrap Lead and Arcanum, OH) using nitric acid.
Basu et al. also reported that Barth and others of EPA
have conducted other bench-scale studies of con-
taminated soils from several battery breaking sites
throughout the United States. As part of these studies
(which evaluated soil washing as a pretreatment before
solidification/ stabilization, EPA investigated
1 Basu, T.K., A. Selvakumar, R. Gaire. Selection of Control
Technologies for Remediation of Lead Battery Recycling Sites.
EPA/540/2-91/014. 1991.
-2-
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different washes of tap water (pH 7), anionic
surfactant (0.5%), and Na4EDTA (3:1 molar ratio),
respectively, at a 10:1 (solution to soil) ratio for a
30-minute contact time. Although the chelating wash
solution removed store lead from the raw soil than the
tap water or surfactant, the authors concluded that the
amount of lead which was removed was insignificant
compared to the total lead content and that weathering
time impacts the efficiency of separating contaminants
from soil.
Basu etxal. has summarized some of the disadvantages of
soil washing as follows:
• Soil washing and acid leaching are still in the
bench-scale developmental stage,
• Soils which are high in clay, silt, and/or humic
material have proven difficult to treat,
• Mineralogical characteristics of soil...can have
detrimental effects on process reactions and use
of reagents,
• Effluents from soil washing systems require
further treatment before discharge. If reagents
are expensive and are not recyclable, treatment
costs will increase, and
• Residuals or sludges generated from the process
may require further treatment before disposal or
reclamation.
In general, Basu et al. concludes that soil washing
technology requires significant development prior to
use in large scale application.
C. SOIL PARTICLE SIZE CONSIDERATIONS
According to EPA's Engineering Bulletin-Soil Washing
Treatment,2 particle size distribution is the key
physical parameter for determining the feasibility of
using a soil washing process to remove contaminants
from soils. Although the NL Pedricktown Site Group
does not believe that particle size distribution should
be the sole reason for choosing or eliminating soil
washing as a candidate technology for remediation, it
is believed that particle size distribution can provide
2 U.S. Environmental Protection Agency. Engineering Bulletii
Soil Washing Treatment. EPA/540/2-90/017. September 1990.
-3-
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an initial means of screening for the potential
likelihood of success using soil washing.
EPA's Engineering Bulletin notes that soil washing is
effective on course sand and gravel. Soils containing
a large amount of clay and silt typically do not
respond well to soil washing, particularly if soil
washing is applied as a stand-along technology. Figure
1, excerpted from EPA's Engineering Bulletin, presents
a simplistic particle size distribution range of curves
that illustrate a general screening definition for soil
washing technology. In regime 1 of Figure 1, where
course soils are found, the matrix is very amenable to
soil washing using simple particle size separation. In
regime 3 of Figure 1, however, soils consisting largely
of finer sand, silt, and clay fractions, and those with
high humic content, tend to contain strongly adsorbed
organics that generally do not respond favorably to
systems that work by only dissolving or suspending
contaminants in the wash solution. Thus, contaminants
in soils containing a high percentage of silt and clay-
sized particles typically are strongly adsorbed and are
difficult to remove.
The NL Remedial Investigation Report suggests that
soils at the site are highly variable. For example,
on-site soils are characterized by a thin (1-2 inch)
layer of top soil containing little plant material over
a tannish-brown, sandy soil. In wooded areas, however,
a thick (6-8 inch) humus layer is overlaying the soil.
The soil under the humus was a tannish to reddish
brown, sandy soil. Soils on adjacent agricultural
lands have 12 to 14 inches of rich, blackish brown
topsoil with an underlying tannish brown, sandy soil.
Sediments from the stream may contain lead which is
tightly adsorbed to organic materials. The variability
of the soils which are planned to be remediated by
washing thus adds another element of uncertainty to the
proposed remedial technique.
-4-
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Figure 1
Soil Washing Applicable Particle Size Rang*
Sand
Average • Large
Gravel
Average • Large
Silt
Average
Soil Washing
(Regime III)
Soil Wash with
Specific Washing Fluid
(Regime II)
Economic Wash
with Simple Particle
Size Separation
Regime I)
0.001 0.002 0.008 0.01 0.02
0.063 0.1 0.2 0.6 1 2
Diameter of Particle In Millimeters
10 20
60 100
-5-
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D. KING OF PRUSSIA SITE
The NL Pedricktown site Group is aware that EPA has
selected a soil washing technology for remediation of
the King of Prussia (KOP) Technical Corporation Site in
Winslow Township, New Jersey. According to informa-
tion3 published by Geraghty and Miller, Inc., the
process to be utilized at the KOP Site involves removal
of bulk over-size material by mechanical screenings,
with subsequent screening and separation of coarse- and
fine-grained fractions. Hydrocyclones are planned to
be used to sep-arate the sands (coarse-grained
materials) and the fines (silts and clays). The sands
are subsequently planned to be treated by flotation
techniques, while the fines are concentrated and
dewatered in a dense sludge cake.
Based upon information available,.to the NL Pedricktown
Site Group, it is believed that the process to be
utilized at the KOP site involves only the physical
separation and processing of on-site materials.
Because the EPA has not demonstrated that physical
processing will be adequate for the separation and
processing of lead contaminated soils at the NL
Pedricktown cite, the NL Pedricktown Site Group
believes that chemical processing will also need to be
incorporated into the soil washing process. The
chemical treatment process is unproven and the
likelihood of successful implementation for Pedricktown
soils at a reasonable cost cannot be guaranteed.
E. CHMR STUDY
The EPA addendum to the final Feasibility study Report
places particular significance on a test conducted by
the Center for Hazardous Materials Research (CHMR)
performed under EPA's Emerging Technology Program with
the soils obtained from the NL site, upon U.S. Bureau
of Mines studies, and other private evaluations of
treatment processes .for the extraction of lead from
soils. EPA, however, has not demonstrated that soil
washing will work. In fact, CHMR was only successful
in reducing the lead concentrations in Pedricktown
soils to about 1,000 ppm, in excess of EPA's remedial
action objective for soils at the site.
The NL Pedricktown Site Group examined a copy of CHMR's
3 Geraghty & Miller, Inc. Environmental Services. News and
Communications. Geraohty & Miller Joint Venture Project
introduces Nev Soil Washing Technology in the United States.
Issued July 1993.
-6-
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draft final report4 for the Acid Extraction System
(AETS) Technology, developed jointly by CHMR and
Interbeton bv, under a grant from the U.S. Environ-
mental Protection Agency. AETS uses hydrochloric acid
to remove heavy metals from soils and a proprietary
system to regenerate the spent extractant.
The NL Pedricktown Site Group comments related to the
CHMR research are summarized as follows:
• The soil used during the CHMR study contained an
average initial TCLP concentration of 510 mg Pb/1
. and an average initial total lead concentration of
26,200 mg/kg. Compared to the samples which were
collected and analyzed by NL Industries during the
remedial investigation, the soil which was
evaluated in the studies performed by CHMR is not
representative of "average11- site conditions.
• CHMR has confirmed the variability of on-site
soils. The soil is sandy, with some clays and a
few large particles (greater than 1/8" diameter).
The raw soil is reddish in color with some visible
clays. (In addition, stream sediments are likely
to contain significant amounts of organic
materials).
• CHMR screen analysis data, summarized as follows,
shows the distribution of lead throughout the
different soil fractions:
Mesh
+ 5
+ 9
+ 20
+ 40
+ 60
+ 100
- 100
Micron
4000
2190
841
420
250
149
N/A
Weight (g)
124 on
160 on
342 on
550 on
458 on
216 on
160 thru
% on
6.2
8.0
17.1
27.5
22.9
10.8
8.0
Pb (mg/kg)
12,000
12,000
34,500
34,500
34,500
34,500
132,500
Overall:33,000
These results indicate that the lead content of
4 Paff, S.W., B. Bosilovich, and N.J. Kardos. Acid Extraction
Treatment System for Treatment of Metal Contaminated Soils.
Contract No. CR-815792-01-0. Draft Final Report Issued by CHMR
to Exide Corporation, September 1993.
-7-
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the fines (-100 mesh) was extremely high (over
13%) and that even the coarse fractions of the
soil contained appreciable quantities of lead.
Thus, soil washing techniques which involve simple
physical separation will not be effective. More
complex, yet-to-be proven chemical separation
techniques would need to be developed in order for
soil washing to be demonstrated as an effective
remedy for the Pedricktovn site.
CHMR conclusions regarding lead removal from soil
are based upon two experiments, the results of
which are summarized as follows:
First Experiment;
TCLP (mg/1)
Total lead (mg/kg)
Untreated
520.0
29,200.
Extraction 1
"• ^*
1,430.
Extraction 2
5.1
1,310.
Second Experiment;
TCLP (mg/1)
Total Lead (mg/kg)
Initial
503.0
23,200.
Final
23.1
1,040.
The results from the experiments do not convince
the NL Pedricktown Site Group that attainment of
EPA's remedial action objectives for the
Pedricktown Site are feasible using this
technology.
CHMR attributed the high TCLP values in the soil
to problems with rinsing. A confirming test,
however, could not be conducted because CHMR had
an insuf-ficient volume of soil remaining at the
conclusion of the test.
Based upon CHMR's initial results, CHMR
anticipated that improved results could be
obtained if a longer soil washing period (e.g.,
increased residence time) was used. The results
of CHMR's residence time studies are summarized as
follows:
I Residence Tim* | Total Lead (mg/kg) |
-8-
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5 minute
10 minute
20 minute
30 minute
40 minute
1,790
1,930
2,210
954
1,080
Again, the results of CHMR's experiments do not
convince the NL Pedricktovn Site Group that
attainment of EPA's remedial action objectives is
possible.
3. ALTERNATIVE SOILS REMEDIES
A. INTRODUCTION
The NL Pedricktovn Site Group has reviewed the remedial
options presented in the RI/FS and EPA's proposed plan.
For reasons which are detailed in the following
sections, the NL Pedricktown Site Group believes that
it has developed two remedial strategies which are
consistently superior to the soil washing remedy
selected by EPA.
B. PROPOSED ALTERNATIVE REMEDY 1 - STABILIZATION/ON-SITE
CONSOLIDATION
Proposed alternative remedy 1 consists of on-site
stabilization of 12,500 cubic yards of hazardous soil
followed by placement of treated material in an on-site
consolidation pile. In addition, approximately 14,300
cubic yards of soil which do not exhibit a hazardous
characteristic but exceed EPA's remedial action
objective would be excavated and placed directly into
the on-site consolidation pile.
C. PROPOSED ALTERNATIVE REMEDY 2 - OFF-SITE DISPOSAL OF
HAZARDOUS SOILS/ON-SITE CONSOLIDATION OR BENEFICIAL
REUSE OF HONHAZARDOUS SOILS
Proposed alternative remedy 2 includes the following
activities for the soil types which are expected to be
generated during remediation:
• Hazardous soils (estimated volume of 3,750 cubic
yards) which fail the TCLP test and the EP
toxicity test will be excavated and stabilized to
render the soils nonhazardous. The soil will
either be stabilized on-site or off-site, based
-9-
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upon a cost effectiveness evaluation to be
performed during the remedial design. Stabilized
soils will be disposed in an off-site landfill.
• Soils (estimated volume of 8,750 cubic yards)
which fail the TCLP test but pass the EP toxicity
test will be excavated and transported to an off-
site hazardous waste landfill for disposal. EPA
land disposal restrictions provide an exemption
from treatment (and allow for direct placement)
for soils which exhibit a hazardous characteristic
based upon the TCLP but which do not exhibit a
hazardous characteristic based upon the EP
toxicity test.
• Soils (estimated volume of 14,300 cubic yards)
which exceed EPA's remedial action objective for
the site but do not exhibit a hazardous character-
istic based upon either the"* TCLP or the EP
toxicity test will be excavated and either
consolidated in an on-site disposal area or
transported to the Salem County Landfill or to an
alternate municipal waste landfill for use as
daily cover.
The NL Pedricktown Site Group's proposed alternatives
for soils are compared to EPA's preferred remedy, soil
washing, in the following sections.
D. COMPARISON OF PROPOSED ALTERNATIVE REMEDY 1
- STABILIZATION/ON-SITE CONSOLIDATION
The NL Pedricktown Site Group has evaluated its
alternative proposed remedies in terms of environ-
mental/public health protectiveness, compliance with
required cleanup standards, technical performance, and
cost. In addition, the remedies have been assessed in
terms of their permanence and their use of treatment to
the maximum extent possible.
Proposed alternative remedy l satisfies EPA's statutory
preference for treatment and is equivalent or superior
in performance criteria (see Table 1) to soil washing.
Alternative remedy 1 employs proven technology .
(utilized previously by the NL Pedricktown Site Group
for treatment of slag during remediation of operable
unit 2 at the site) and avoids the lengthy design
period and inherent risks associated with soil washing.
The NL Pedricktown Site Group is convinced that
alternative remedy 1 can be completed at significantly
less cost (estimated in Table 2 to be $5,628,000) than
soil washing.
-10-
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E. COMPARISON OF PROPOSED ALTERNATIVE REMEDY 2 - OFF-SITE
DISPOSAL OF HAZARDOUS SOILS/ON-SITE CONSOLIDATION OR
^ENEFICIAL REUSE OF NONHAZARDOUS SOILS
The NL Pedriektovn Site Group's alternative remedy 2 is
compared in further detail to EPA's proposed soil
washing remedy in summary form in Table 1 and in
additional detail in the following discussion.
• Overall Protection of Human Health and the
Environment
Alternative remedy 2 results in the removal of all
hazardous soils from the Pedricktown site. Soils
which exceed EPA's remedial action objective and
are nonhazardous would be excavated and disposed
on-site. Alternatively, the nonhazardous soils
would be used as daily cover at a local municipal
landfill. If the nonhazardbus soil can be
beneficially reused as daily cover at a local
landfill, the remedy avoids on-site habitat
destruction for construction of the landfill, long
term monitoring and maintenance is not necessary,
and the possibility of future reuse of the
property for a productive purpose is maximized.
• Compliance with Applicable or Relevant and
Appropriate Requirements fARARs)
EPA has specified that the primary ARARs of
concern are those which apply to wetland areas
(New Jersey Freshwater Wetlands Regulations) and
RCRA regulations dealing with the identification,
handling, transport, treatment and disposal of
hazardous waste. The NL Pedricktown Site Group's
alternative remedy 2 will comply with all ARARs
and, if all nonhazardous soils can be beneficially
reused off-site, further destruction of wetlands
(which is required by EPA's proposed remedy) is
not required for construction of an on-site
consolidation pile.
• Long Term Effectiveness and Permanence
Since alternative remedy 2 includes plans for the
excavation and off-site disposal of all hazardous
soils and includes plans for the on-site
consolidation or off-site reuse of nonhazardous
soils which exceed EPA's remedial action
objectives, alternative remedy 2 is superior to
all other remedial plans in terms of long-term
effectiveness and permanence. If nonhazardous
soils can be beneficially reused, future
-11-
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monitoring and maintenance of a new on-site
disposal area would not be required. Assuming
that contaminated soils may have impacted
groundwater, alternative remedy 2 represents a
solution which includes removal of source areas
and provides for long term protection of
groundwater.
Reduction of Toxieitv. Mobility, or Volume Through
Treatment
Although EPA's preferred option is expected to
reduce the toxicity, nobility, and volume of
contaminants through soil washing, the soil
washing process is expected to generate some
secondary waste requiring off-site disposal.
Assuming the lead from the soil washing is
concentrated in a soil /residual volume which is
30% of the original volume "of soil which is
washed, the soil washing process is estimated to
produce approximately 3,750 cubic yards (12,500 •
cubic yards estimated soil volume to be washed x
30%) requiring stabilization to render the soil
nonhazardous for disposal.
Implementation of alternative remedy 2 would also
necessitate the stabilization of approximately
3,750 cubic yards of soil (e.g., soil which fails
both the TCLP and EP toxicity test) prior to
disposal. In addition, all other nonhazardous
soil which exceeds the remedial action objective
would be excavated and either consolidated on-site
or transported for off -site beneficial use. In
this respect, the alternate remedy is superior to
EPA's proposed soil washing remedy.
Term Effectiveness
Alternative remedy 2 may create some short-term
impacts to the community in that it will require
the off-site transport of soil for disposal and/or
beneficial use. EPA's proposed remedy also
includes the use of roadways for off -site
transport of soil washing residuals for treatment
and disposal. Because alternative remedy 2 is
expected to be implementable in one work season,
the alternative remedy offers an immediate benefit
for the protection of human health and the
environment at the Pedricktown site.
Imp 1 ement ab i 1 itv
Soil washing is an unproven technology and
-12-
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requires treatability studies to determine
feasibility and effectiveness. Since the
likelihood of successful implementation of the
soil washing remedy is not known at the present
time, completion in three years, as EPA has
projected, cannot be guaranteed.
In contrast, alternative remedy 2 is the easiest
alternative to implement using standard excavation
and transportation techniques. Alternative remedy
2 could be implemented without the complex
treatability studies required by EPA's preferred
remedy and would likely be completed during one
work season.
Cost
The NL Pedricktown Site Group has estimated costs
of approximately $10,146,000 for implementation of
the soil washing remedy (see Table 2). Since soil
washing is an unproven technology, can not be
guaranteed to work, could require additional costs
for treatment or regeneration of soil washing
chemicals, and requires developmental work to
determine its feasibility and likelihood of
success, EPA's costs can only be considered
estimates at this time.
Alternative remedy 2 has been estimated to cost
$8,397,000 for off-site disposal of hazardous
soils with on-site consolidation of nonhazardous
soils. If off-site beneficial reuse of non-
hazardous soils is feasible, the cost for
alternative remedy 2 is approximately $7,659,000
(see continuation sheet of Table 2). Because
alternative remedy 2 employs standard excavation,
transport, and disposal techniques, actual
completion of the project for the estimated cost
is believed to be highly probable.
State Acceptance
Although it is not known by the NL Pedricktown
Site Group whether the State of New Jersey will
approve EPA's proposed soil washing plan, the NL
Pedricktown Site Group anticipates that the State
will approve alternative remedy 2 since the remedy
involves off-site management of all hazardous
soils. In addition, if beneficial reuse of
nonhazardous soils is feasible, alternative remedy
2 avoids the destruction of on-site wetlands for
the creation of a new disposal area, as
contemplated by EPA's soil washing remedy.
-13-
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Community Acceptance
During the public meeting held in Pedricktovn on
August 2, 1993, the mayor of Pedricktovn expressed
the community's objection to the construction of
another on-site disposal area. If beneficial
reuse of nonhazardous soils is feasible,
alternative remedy 2 would address the community's
concerns since all soils in excess of the remedial
action objective would be excavated and
transported off-site for either disposal or
beneficial reuse.
F. SUMMARY
For the reasons detailed above, the NL Pedricktown Site
Group believes that alternative remedy 1 (soil
stabilization/on-site consolidation) and alternative
remedy 2 (off-site disposal of hazardous soils/on-site
consolidation or off-site beneficial reuse of
nonhazardous soils) are superior to the unproven soil
washing remedy proposed by EPA.
Off-site disposal of hazardous coils with either
on-site consolidation or off-site beneficial reuse of
nonhazard-ous soils provides a lower cost remedy and
utilizes proven excavation and handling methods which
allow for completion in one work season.
Soil stabilization provides the lowest cost remedy
which has already been demonstrated at the site for
slag treatment.
-14-
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TABLE
SOIL REMEDIATION - COMPARISON OFALTERNATIVES
BPH CRITERIA
EPA PROPOSED REMEDY
(SOIL WASHING)
ALTERNATIVE REMEDY 1
(SOIL STABILIZATION)
ALTERNATE REMEDY 7
(OFF-SITE DISPOSAL/OH-SITB
CONTAINMENT OR OFF-SITE REUSE)
1. Overall Protec-
tion of Human
Health and
Environment
Yes
(Uses treatment and
containment)
Tee
(Uses proven treatment
and containment
techniques)
(Uses treatment,
beneficial use)
Yea
containment, and
2. Compliance with
ARARfl
Yea
YOB
(Uses treatment,
beneficial uae)
Yea
containment, and
3. Long Term
Effectiveness
and Performance
Yea
(Technology removea lead from
aoil. Residual levels of lead
in eoll will remain, assuming
treatment ia effective,
subjecting site to future
inspection, maintenance and
monitoring).
Yea
(Technology results in
nonleachable nonhazardous
material in on-elte
consolidation area).
Yea
(Plan will reeult in removal of
soil above action level from the
site and eliminate need to monitor
a new on-aite disposal area. An
estimated volume of 2O,000 tone of
aoil will be beneficially reuaed).
Reduction of
Toxlcity,
Mobility or
Volume Through
Treatment
Yea
(The aoil washing process ia
likely to generate some
eecondary waste requiring off-
site treatment and disposal).
Yes
(Technology utilizes
proven treatment
technology and results in
the generation of
nonhazardous waste).
Yes
(All soils exceeding the remedial
action objective will be excavated
and removed from the facility for
off-site treatment, disposal, or
beneficial use).
5. Short-Term
Effectiveness
Not Known
(Since soil washing is an
unproven technology, a start-
ing date for remediation is
not known. Additional time
would be required for con-
struction of on-site equip-
ment. EPA has estimated 3
years for implementation).
Yes
(Since all soil is
managed on-site and there
ia no use of local roads,
there is no short-term
impact to the community).
Yes
(Of all the remedies which have
been evaluated, this remedy pro-
vides the opportunity for immediate
start-up and prompt completion.
Because the alternative remedy
could be implemented in one work
season, the remedy offers immediate
benefit for the protection of human
health and the environment. Short-
term impacts to the community would
involve use of local roads for off-
site transport of soil).
-15-
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SOIL REMEDIATION - COMPARISON OP;ALTERNATIVES
BPA CRITERIA
EPA PROPOSED REMEDY
(SOIL HASHING)
ALTERNATIVE REMEDY i
(SOIL STABILIZATION)
ALTERNATE REMEDY 2
(OFF-SITE DISPOSAL/ON-SITB
CONTAINMENT OR OFF-SITE REUSE)
6. Implementa-
bility
Not Known
(Soil washing is not a proven
technology and requires
treatability studies to
determine Implementabillty).
Yen
(Soil stabilization tech-
nology has already been
demonstrated at the site.
Remedy provides for Imme-
diate implementation).
Yea
(The element* of the remedy are
easy to implement and do not
require significant developmental
activities or feasibility
evaluations).
7. Cost
$10,146,000
(EPA costs can only be con-
sidered as estimates, since
soil washing is an unproven
technology and requires
developmental work to evaluate
feasibility).
$5,628,000
(Implementation, for slag
treatment, has already
been demonstrated to be
feasible).
$6,397,000
(Off-site disposal of hazardous
soils; on-site consolidation of
nonhazardous soil).
$7,659,000
(Off-site disposal of hazardous
soils; off-site beneficial reuse of
nonhaeardous soils).
8. State Accept-
ance
Not Known
Not Known
Likely
9. Community
Acceptance
Not Likely
(During the EPA public
meeting, the mayor of
Pedricktown expressed serious
concerns about the creation of
a new on-site disposal area.
The community is not likely to
accept a proposed plan which
allows for creation of a new
disposal area).
Not Likely
(During the EPA public
meeting, the mayor of
Pedricktown expressed
serious concerns about
the creation of a new >
on-site disposal area. '
The community is not
likely to accept a pro-
posed plan which allows
for creation of a new
disposal area).
. Likely
(The alternative remedy is likely
to receive community support since
all soils above the remedial action
objective would be removed from the
aite for off-site management and
for beneficial reuse.
NOTES: '" 11.500 cubic yirdi 9 MOO/cublc yard
°» 30% of 12,500 cubic yarda 9 1.4 tons/cubic yard 9 SZOOAon
«» 70% of 12.500 cubic yarda 9 $5Aon
m 70% of 12,500 cubic yarda 9 1.4 torn/cubic yard 9 SI50Aon
'* Then mnmpHen wen Wilized uniformly. Engineering *nd administration costa would be coraMerably greater for
•oil wishing aa fhli remedy would require 3 yeara for completion compared to 6-9 monthi for off-site disposal.
* 12,500 cubic ytrdi 9 1.4 torn/cubic yifd Q $50/lon
m 12,500 cubic yirdi * 1.25 9 IA lorn/cubic yard 9 $5/ton
• See continuilion pige for noterditl cost saving i ainciited wllh olT-sMe beneficial rente of nonhtxardous will
-16-
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TABLE
SOIL REMEDIATION - COMPARISON OF COSTS
COMMON COSTS 1
Sit* Work
On-Site restoration
Off-Bit* restoration
On-aite consolidation pile
COMMON COSTS (SITE PREP) 1
Road relocation
HASP
Hooded area access
Erosion control
VARIABLE COSTS I
Treatability
Mobilization
Soil Washing
Solidification/disposal
On-aite disposal
Direct placed soils
Treated and placed soils
SUBTOTAL
COHTIHOENCT (25%)
ENOINEERINO <15%)n
ADMINISTRATION (5%)M
TOTAL
EPA PROPOSED REMEDY
(SOIL WASHING/
ON-SITE CONSOLIDATION)
$ 660,300
$ 807,500
$ 109,000
$ 951,500
$ 35,000
$ 20,000
$ 120,000
$ 50,000
$ 150,000
$ 500,000
$ 2,500,000"*
$ 1, 050,000™
$ 43,750 m
$ 6,997,050
$ 1,749,263
$ 1,049,550
$ 349,853
$10,145,724
ALTERNATIVE REMEDY 1
(ON-SITE STABILIZATION/
ON-SITE CONSOLIDATION)
$ 660,300
$ 807,500
$ 109,000
$ 951,500
$ 35,000
$ 20,000
$ 120,000
$ 50,000
$ 25,000
$ 150,000
$ 875,000 *
$ 78,125 m
$3,881,425
$ 970,356
$ 582,214
$ 194,071
$5,628,066
ALTERNATE REMEDY 2
(OFF-SITE DISPOSAL/
ON-SITE CONSOLIDATION)
$ 660,300
$ 807,500
$ 109,000
$ 951,500*
$ 35,000
$ 20,000
$ 120,000
$ 50,000
$ 150,000
$1,837, 500 w
$1,050, 000 m
$5,790,800
$1,447,700
$ 868,620
$ 289,540
$8,396,660*
NOTES: m 12.500 cubic yanh$$200/eublc yard
* 30* of 12,500 cable yard* 0 1.4 torn/cubic yard O S200/ton
w 70% of 12,500 cubic yards 9 $5/ion
M 70* of 12,500 cubk yirdi Q 1.4 loni/cabk yard 9 J150Aon
" Theie muhiplkri wen utilized uniformly. Engineering ind •dmintantlon cotti would be considerably greater for
•oil wishing n (hit remedy would require 3 yein for completion compared to 6-9 monthi for ofT-sile dispoul.
M 12,500 cubic yirdi« 1.4 Ion/cubic y«fd 0 $50/ton
m 12,500 cubic yirdi x 1.25 9 1.4 torn/cubic yard 0 $5Aon
• See contimution pige for potential co«t uvingi asiociited whh olT-site benericiil reuse of nonhtzardous soils
-17-
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TABLE
(continued)
...... .. SOIL REMXDIATION - COMPLETION OF COSTS ", ..
Surface preparation
Disposal
40 ml liner
Drainage layer
Root cone soil
Top soil
Seed, fertilizer, etc.
Liner system
SUBTOTAL
CONTINGENCY (25%)
ENGINEERING (5%)
ADMINISTRATION (5%)
TOTAL
ALTERNATIVE REMEDY 2
(OFF-SITE DISPOSAL WITH
ON-SITE CONSOLIDATION)
$ 37,000
$147,500
$ 79,000
$ 14,000
$ 87,000
$ 28,000
$ 9,000
$550,000
$951,500
$237,875
$142,725 .
$ 47,575
$1,379,675
ALTERNATIVE REMEDY 2
(OFF-SITE DISPOSAL WITH
OFF-SITE BENEFICIAL REUSE)
$147,500
...
...
$147,500
$ 36,875
$ 22,125
$ 7,375
$213,875
NOTEi The information presented above summarizes the two options associated with alternative remedy 2.
If nonhazardous soils which pass the TCLP but exceed the EPA remedial action objective are able to
be beneficially reused at a local municipal landfill, this option would result in removal of all
contaminated soils from the site, would result in additional cost savings, would preclude the con-
struction of a landfill in two acres of wetlands, and could save the county approximately $500,000
in purchase costs for daily cover.
-18-
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ATTACHMENT C
-------
REVIEW AND COMMENTS ON
GROUNDWATER INVESTIGATION AND
REMEDIATION STRATEGIES
NL INDUSTRIES SUPERFUND SITE
OPERABLE UNIT ONE
PEDRICKTOWN, NEW JERSEY
15 September 1993
3520701
Langan
Engineering and Environmental Services. Inc.
-------
REVIEW AND COMMENTS ON GROUNDWATER
INVESTIGATION AND REMEDIATION STRATEGIES
NL INDUSTRIES SUPERFUND SITE
OPERABLE UNIT ONE
PEDRICKTOWN, NEW JERSEY
Prepared by:
• •
Langan Engineering and Environmental Services. Inc.
350 South Main Street Suite 103
Doylestown. Pennsylvania 18901
15 September 1993
3520701
8«a S-.-te—rt~:t- Services. IPC
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TABLE OF CONTENTS
Pace No.
1.0 INTRODUCTION 1
2.0 COMMENTS ON REMEDIAL INVESTIGATION 2
3.0 COMMENTS ON FEASIBILITY STUDY 5
4.0 COMMENTS ON U.S. EPA PROPOSED PLAN 10
5.0 CONCLUSIONS AND RECOMMENDATIONS 14
LIST OF FIGURES
Figure 1 Estimated Extent of Groundwater Contamination
Figure 2 Distribution of Lead in Soil
Figure 3 Schematic of Relationship Between Contaminated Zone and Proposed Recovery
System
LIST OF APPENDICES
Appendix A Documents Reviewed
Appendix B Evaluation of the Efficiency of Using Interceptor Well Network as a Groundwater
Recovery System
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1.0 INTRODUCTION
This repon summarizes the review of technical and administrative documents which pertain
to the groundwater investigation and proposed groundwater remediation at the N.L industries
Superiund Site. Operation Unit One. Pedricttown. New Jersey. The objective of the review was
to understand site groundwater conditions, as defined in the Remedial Investigation (O'Brien
& Gere. 1991), to develop a conceptual technical approach which would best address the
remediation of groundwater. to review the Feasibility Study (O'Brien & Gere. 1993) and
Proposed Plan (U.S. EPA. 1993). and to evaluate the EPA-setected remediation strategy. This
technical assessment included a review of those documents from the Superfund Document
Record which were made available to Langan. and which constitute the basis for the selection
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of the preferred remediation strategy. These documents are listed in Appendix A..
The organization of this report is similar to that in the U.S.EPA Proposed Plan (July 1993). This
organization is intended to facilitate preparation of responses to the Proposed Plan, and to
provide a logical progression through the technical discussions.
Overall, we conclude that the groundwater remediation preferred by EPA in its Proposed Plan
is inappropriate. The data and assumptions that were used to formulate the preferred
remediation strategy likely do not represent actual conditions in the shallow aquifer, and the
proposed groundwater recovery system is not appropriate to address the potential problem.
The proposed plan fails to demonstrate whether the recovery of inorganic compounds from
the shallow aquifer matrix is possible, using a groundwater extraction technique, even though
such an evaluation could nave been conducted using simple rapid field tests (typically less
than ten days of field time). We further conclude that the Proposed Plan is invalid because
it fails to consider whether the proposed soil remediation would also remedy any problems
associated with groundwater quality.
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2.0 COMMENTS ON REMEDIAL INVESTIGATION
Our review of the Remedial Investigation (Rl) focussed on the interpretations of aquifer
conditions and groundwater quality, and on now these interpretations were used in. and
affected the decisions in. the Feasibility Study and Proposed Plan, as related to groundwater.
Our technical assessment concluded that the Remedial Investigation:
• Demonstrated that the zone of contamination is limited, consists generally of
concentrations of target compounds which marginally exceed groundwater quality
standards and has not impacted off-site areas.
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• Failed to correlate the extent and distribution of contamination in the shallow aquifer
with soil remedial investigation findings and failed to consider potential continuing
residual sources in soil.
• Demonstrated that the compounds of concern are not mobile, and that the zone of
contamination is not expanding over time. Some data indicate it might be
decreasing.
• Failed to provide an adequate characterization of either the shallow unconfmea
aquifer or the actual connection with tower aquifer systems, and failed to explore
potential mechanisms to explain the behavior of the target compounds in
groundwater.
The Rl demonstrated that the zone of contamination in the shaflow. unconfined aquifer is bitted
and restricted to the vicinity of former process/operations areas. Despite this demonstration the
Rl concluded that these compounds are present in a mobile plume which flows approximately
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parallel to me grounowater flow direction. This conclusion ooes not agree with grounawater
monitoring results which did not detect target compounds in downgradient or off-site weds.
The authors of the Rl attrfeute the groundwater contamination to recharge from areas where
slag piles were staged. This explanation can not account for either the distribution or extent
of compounds in the impacted zone, which are present at low concentrations over a large
area, or for higher concentrations at two specific, and limited locations. These locations do
not correspond to the locations of the former slag piles. Furthermore, this explanation does
not account for the distribution of residual compounds in soil, which is similar to that in
groundwater. and which does not indicate contamination from localized sources. Rather, the
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distribution m unsaturated soil (Figure 8 of the Rl) and in groundwater (Figure 33 of the FS)
can be correlated very well, demonstrate a non-point source distribution, and indicate a
continuing discharge to the shallow aquifer from residual soil contamination over a large and
diffuse area. This issue is discussed in greater detail in our comments on the Feasibility Study
• Section 3.0 of this report.
The Rl demonstrated thai the target compounds are not mobile within the shallow aquifer, but
still concluded that the contaminated zone represents a "plume.' The term 'Plume' implies a
region of contamination which originates at one or more source areas and migrates, through
various mechanisms, within the aquifer. This designation is difficult to reconcile with the
groundwater data, and with the interpretations in the Rl which conclude that *...[t]he current
limited extent of contamination relative to predicted groundwater flow (emphasis added)
demonstrates that the migration of chemicals within the ground water is being impeded...' (Rl -
pg. 57). in other words, the compounds within the contaminated zone are not actually
moving. The Rl also concluded that the contamination in the shallow, unconfined aquifer has
not measurably impacted either the first or second confined aquifer, and there has been no
impact to potential off-site receptors.
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The Rl did not include tests or analyses to determine aquifer charactenstics. or to explain the
behavior of target compounds in the shallow aquifer. Although the Rl recognizes me limitations
of the existing groundwater database, and recommends additional investigation, which
includes installation of additional monitoring wells, replacement of some existing monitoring
wells and resampling of all wells, these recommendations have not been implemented. This
is of particular importance because the data upon which the ultimate remediation strategy will
be decided was generated in 1989 (four years ago), in the intervening time, groundwater
conditions and quality might have changed significantly. We note this as a concern because
there were significant decreases in the concentrations of sulfates and filterable lead reported
tor monitoring welts on the northern section of the site during the period 1983 -1988. Further
aecreases occurred between the 1988 and 1989 monitoring episodes.
The Rl includes no discussion or explanation for these decreases, and does not attempt to
explain the presence of the particular suite of compounds which characterize the contaminated
zone. The authors of the .Rl intimate that sulfates are an indicator parameter of the
contamination, but an explanation of its presence is not provided. Neither is an attempt to
correlate the sutfates with other indicators such as pH. TDS. TSS. turbidity, or target inorganic
compounds. We speculate that the presence of sutfates could be related to battery acid
(HjSO. - Sulfuric Acid) which has been partially neutralized in the soil environment, where
sulfuric acid combines with water, oxygen and humic acid (H2CO,) to produce water, carbon
dioxide and the soluble sutfate anion (S04).
The important issue, however, is that similar decreases in these parameters could have
occurred in the ensuing four years, and current groundwater conditions and quality could be
very different than presented and predicted in the Rl.
Another issue which might be resolved with current groundwater quality data is whether the
presence of lead in groundwater around the RCRA landfill might be related to a former
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leacnate back-up and overiill. and whether the subseauent maintenance of the collection
system has resulted in an improvement to groundwater quality in this area.
3.0 COMMENTS ON FEASIBILITY STUDY
Our comments on the Feasibility Study (FS) focus on the relevance of the assumptions used
in the evaluation of potential remediation strategies, and consider both technical and regulatory
issues which will affect the ultimate strategy selection. We reviewed the FS prior to the U.S.
EPA Proposed Plan to avoid preconceived bias from the EPA recommendations and
remediation strategy selection.
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Our review and assessment of the Feasibility Study concluded that:
• The study did not include an assessment of the recovery potential of the compounds
of concern from the.shallow aquifer.
• The conceptual remediation design did not include a groundwater extraction-
recovery system designed to address the documented zone of contamination.
• The assessments of remediation strategies were conducted without understanding
the source(s) of the contamination, and did not consider the potential effects on
groundwater quality of the remediation of the overlying, contaminated soil.
• The effects on groundwater quality of source (soil) remediation were not evaluated.
even though such an evaluation could have been completed in less than ten days
using simple field tests.
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The proposed Dumping rates for the recovery-treatment system are unrealistic ana
do not consider aquifer capacity.
The FS does not evaluate the technical feastoOfty of the remediation of the shallow, unconfined
aquifer, in that it does not assess whether the physical extraction/recovery of the compounds
of concern from the aquifer is possWe. Tests to evaluate the recoverability of the inorganic
compounds are not included in the study. Rather, it is limited to an evaluation of potential
treatment and discharge options for (theoretical) groundwater intercepted at the perimeter of
the site, which is likely not similar in composition to actual groundwater in the contaminated
zone.
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Throughout the FS it is assumed that the compounds are distributed homogeneously in the
aquifer, and that they are in a dissolved state and completely recoverable. This assumption
has no basis in technical fact and is difficult to reconcile with the conclusion in the Rl that lead
(and possibly other compounds) is not a mobile species as a result of some natural
process(es) which arrests possible transport mechanisms. Neither O'Brien and Gere nor the
EPA offered an explanation of the mechanism through which pumping groundwater would
mobilize non-mobile compounds. In the absence of these evaluations, and the resultant
conclusions, none of the potential remediation strategies can be considered feasible.
The proposed use of the existing interceptor weib as a recovery system, rather than for their
intended purpose as in interceptor network, is a solution of convenience which fate to address
actual conditions. This proposed recovery system would result in an aggregate treatment and
discharge capacity of 360.000 gallons per day. Because the extraction points are located
around the outer perimeter of the site, we note that approximately 55% of that water (193.000
gpd) would be from off-site or from areas outside the contaminated zone, as defined in the Rl.
(Our calculations and rationale for this estimate are included in Appendix B.) The FS did not
include a design for a groundwater extraction system to recover groundwater specifically from
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^econtam.natedzone.nord.dncon^^
require tower pumpmg rates to control groundwater flow.
The FS does not consider the source(s) * the groundwater contamination, or the potential
effects of source removal on br^ermaefafero^ity.The distribution of inorganic compounds
in shallow groundwater and the interpretation of migration potential in a pfcme (FS. Figures
33 through 36) is the key issue upon which the conclusion that aquifer restoration is possible
is based. The FS postulates that the immobile inorganic compounds are migrating parallel to
groundwater Mow in the shallow, unconfined aquifer in a southeast to northwest direction
(Rgure 33). We question whether this distribution represents a plume, or rather me
Moduen. into the aquifer of a vadose solute from soil.contamination throughout the area.
such as lead-bearing battery acid. Companson of Figure 6 of the R. and Figure 33 tf the FS
(revised and attached as Rgures 1 and 2) shows a strong correlation between the distribution
of lead in soil and the location of the lead*earing zone in the upper, unconfined aquifer, in
specu.ation. this toner scenario coutd account for the decrease in filterable lead between 1983
and 1988 (four years after cessation of facility operations), and also for the absence of
migration (acid precipitation neutralized in a pH-normal aquifer).
The FS tails to discuss the possiWe effects of the remova. of the sources) on groundwater
quality, and a proposal to evaluate such effects. Such an evaluation can be accomplished in
•ess than ten days using a simple, rapid field test which would demonstrate whether there is
a continuing discharge from a soil source. This testing would define the leachate production
and inflation rates, would demonstrate the fate of the leachate and expfcin the behavior of
compounds within the shariow aquifer, and would determine whether the proposed recovery
of inorganic compounds is possible.
The evaluation would begin by conducting the groundwater Investigation tasks proposed in
me R. to supplement the existing data base. At the same time. Suction Lysimeiers would be
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installed in the unsaturated zone at select locations to collect vadose water from suspecteo
source areas. Samples from the saturated and unsaturated zones would then oe analyzed for
total metals, filteraole metals. IDS. TSS. pH. and suifates. Data from the two media would be
compared to determine whether there is potential contaminant communication between soil
and groundwater.
Based on these initial data, the monitoring network would be refined, as necessary, and both
media would be monitored after a rainfall, to establish the (suspected) causative link between
the systems. Monitoring episodes would be conducted before and following precipitation
events to estimate the leachate loading rate to the aquifer and to determine the fate of the
leachate in the aaurfer. *
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in addition to these observations and analyses, a field extraction (pumping) test, would be
conducted to determine the recovery potential of the compounds from the shallow aquifer over
time. This would consist of groundwater extraction from a well at the location of highest lead
concentration. The well would be pumped at a rate determined during a preliminary well
performance test and would be set to ensure equilibrium flow over a three-day period.
Samples would be analyzed from the discharge stream at regular time intervals to determine
whether dissolved compounds continue to be released into the aquifer under pumped
conditions over time. The test would also be used as an opportunity to collect hydraulic data
about the aquifer, if necessary, these data would then be used for the design of a proper
groundwater recovery system after soil sources are removed. An additional simitar
demonstration of the recovery potential of the existing interceptor system could also be
performed at this time.
The treatment system discharge options considered in the FS are evaluated using an assumed
flow rate which is unrealistic, and which has no technical basis. For each option, a total
(aggregate) flow/discharge rate of 250 gallons per minute (gpm) is assumed. This volume was
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selected aroitrariiy by assuming that the grounawater recovery system would consist of the 49
existing site-perimeter interceptor well points, which would be pumped at 5 gpm each. Apart
from assuming that each of the wells could sustain this discharge rate under long term
pumping, there is no justification for using all of the interceptor points, some of which are
greater than 600 feet from the edge of the 'plume.' and are not down gradient. The locations
of the well points in relation to the estimated edge of the contaminated zone are depicted on
Figure 3. More importantly, as specified in Secton 12.3.2. of the FS (page 17). the well point
system *... was designed to prevent off-site migration of contaminated groundwater.' Later in
the FS (Section 3.3.2. page 57) this same system is proposed to '...recover groundwater and
limit off-site migration...' which. as documented in the Rl and in the Proposed Plan, is not now
occurring.
By considering only the recovery/treatment system described above, the remediation strategies
which would involve the re-introduction of treated groundwater back into the shallow aquifer
were eliminated from the list of viable alternatives. We contend that aO of those groundwater
discharge options are not only feasible, but preferable if a lower flow/discharge rate is applied.
This modified remediation strategy would include an extraction or interceptor system designed
and located to recover contaminated groundwater from a well defined zone within the aquifer.
We reiterate, however, that even this modified system should not be considered unless the
recovery potential of the target compounds is documented, and should be proposed only as
a contingency if the removal of the (suspected) source(s) of the continuing discharges (soil)
does not result in an improvement in groundwater quality.
4.0 COMMENTS ON U.S.EPA PROPOSED PLAN
Our comments in the previous sections of this report respond to those sections of the
Proposed Plan which summarize the documents prepared for the selection by U.S.EPA of
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remeoiai strategies. This section presents our observations and comments on the Er A
selection criteria, and the technical basis tor selection of the preferred option. Our review of
the Proposed Plan was completed only after we had reviewed the Rl and F5 reports and had
formed our own interpretations and conclusions, independently of the EPA selection.
The Proposed Plan relies on data and interpretations from the Rl and FS which are either
flawed or incomplete, and which do not present an adequate assessment of site conditions
upon which to base long-term remediation decisions. The bases for this conclusion include:
• The remedial strategy selection is based on the premise that there is a '...substantial
and imminent threat to public health...* which is •contrary to the findings documented
in the Rl ano re-stated in the Proposed Plan.
• The Proposed Plan does not consider the potential positive effects on aquifer quality
of the remediation of overlying. contaminated soil.
• The Proposed Plan proposes to restore site groundwater quality by using an
interceptor system that was designed only to prevent off-site migration.
• The conceptual groundwater remediation strategy includes restoration of a non-use
aquifer to groundwater quality standards (for primary drinking water sources) as a
means to protect a public which, as agreed to by EPA in the Proposed Plan, is not
now being exposed.
• The Proposed Plan does not consider the recommendations in the Rl for additional
investigation, or those in the FS. that remediation options which include re-
introduction of the treated groundwater to the aquifer should be evaluated further.
The final selection is made despite this lack of information.
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The requirement to remediate groundwater is based on the conclusion that there is a risk to
public health and the environment In particular. EPA has assessed this potential risk assuming
that future uses of the site could include residential development, despite its industrial zoning.
and despite the deed noticing mechanism used frequently by NJOEPE to minimize or eliminate
exposure by restricting future land use options. We note in particular the Summary of Risks
paragraph on page 9 of the Proposed Plan, which states that '...groundwater...pose(s) an
imminent and substantial threat to public health....' presumably through ingestion of
groundwater. We question this conclusion considering there has been no off-site impact to
groundwater. and no measurable impact to other aquifers by the contamination at the site.
An evaluation of the potential effects of soil remediation should be considered. Therefore, we
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recommend that future Discussions and/or references to potential long-term active aquifer
restoration efforts should be in terms of a contingency plan. Considering the existing aquifer
conditions, and the demonstrated minimal exposure potential, and considering that
groundwater contamination is likely the result of ongoing releases into the shallow aquifer from
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residual soil contamination throughout the impacted area, there is no justification to require
aquifer restoration using a groundwater extraction strategy, without first evaluating the effects
of soil (source) remediation on groundwater quality. An appropriate groundwater remediation
strategy would be designed and implemented only if source remediation does not result in a
decrease in dissolved compound concentrations in the impacted saturated zone, and that
compounds in the aquifer become demonstrably mobile, and threaten an exposure to a
potential receptor.
The plan proposes to restore site groundwater quality by using in interceptor system that was
designed only to prevent off-site migration. This proposed misapplication of the interceptor
system would result in pumping groundwater from outside the zone of contamination on-site.
Consequently, the feasibility study on which the Proposed Plan is based is significantly, if not
fatally, flawed in it's evaluation of groundwater recovery and treatment system options.
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Much 01 the decision at remediation technology feasibility and selection should be predicated
on the definition of the extent of the contamination which must be remediated to comply with
ground water quality standards, in other words, the decision of whether to address ail locations
where iead concentrations in groundwater exceed 10 ppb (New Jersey Groundwater Quality
Criterion), or whether some other concentration is appropriate, must be made before the
tecnnical feasibility of any option can be assessed, in the Proposed Plan, the remediation
objective is a complete restoration of aquifer quality, using the practical quantitation limit for
lead (5 ppb) as the numeric objective. The NJOEPE has a mechanism which will allow intenm
exceedence of this standard, however, by establishing a Classification Exception Area
(N.JAC. 7:9-6.6). This would allow discharge of treated water back to the aquifer at higher
concentrations than the standard. The Classification Exception Area is granted only through
the Duration of the remediation period, after which the existing standard will again be
applicable. The ultimate goal would be the restoration of the aquifer to the applicable
standard(s). if technologically feasible.
By obtaining a Classification Area Exception a groundwater recovery system could be
designed to address only those portions of the aquifer with significant contamination, and the
re-mtroduction of the treated water could be a viable option, based on the lower flow/discharge
rates, and/or by establishing an exemption zone. In this way. a treatment system which is
capable of reducing concentrations to the MCL(s) could be installed, but operated under a
New Jersey Aquifer Classification Exemption to treat and discharge back to groundwater, at
significantly higher concentrations. The aquifer would be monitored over time to demonstrate
remediation performance, and to evaluate and/or reconsider the ultimate remediation
objectives.
The Proposed Plan presents the U.S.EPA selection of a remediation strategy despite the lack
of the additional data and analyses recommended in the Rl and FS. The Rl recommended
additional groundwater investigation to batter characterize aquifer conditions and the nature
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ana extent of the contaminated zone. The FS recommended further evaluation of the
remediation alternatives which include the re-introduction of treated groundwater back into the
aquifer, because they are viable options. Neither of these sets of recommendations were
implemented, but the Proposed Plan culminates in a recommendation for a single preferred
strategy.
5.0 CONCLUSIONS AND RECOMMENDATIONS
We conclude that the groundwater portion U.S.EPA Proposed Ran is flawed in that the data
used to formulate the remediation strategy likely do not represent actual conditions in the
aquifer.
We conclude that the Proposed Plan is invalid because the selection of the treatment and
discharge methods was predicated on unrealistic assumptions regarding the capacity of both
the groundwater recovery and treatment systems.
We conclude that the FS is incomplete in that it does not evaluate, or even address, the
recovery potential of site specific target compounds, and has not proposed a groundwater
extraction/recovery system designed to address the zone of contamination , as defined in
theRl.
We agree with the conclusions in the Rl that the target compounds present in the shallow
aquifer are not mobte, but we disagree thai their presence represents a •plume* of
contamination which is migrating parallel to the general groundwater flow direction. We
conclude that the presence of these compounds is more likely the result of non-point source
discharges from residual soil contamination. We also agree with the recommendations in the
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Ri mat additional investigation of groundwater conditions and duality are required, and note
tnat me Proposed Plan was prepared without the benefit of such additional data.
We conclude that removal of source area(s) in the overtying unsaturated soil would Ikery result
in an improvement in groundwater quality over time, without active remediation of the aquifer.
We recommend a field testing program to demonstrate whether there is a continuing soil source
of groundwater contamination.
We recommend a re-evaluation of the quality of groundwater in the shallow aquifer to confirm
the results of the previous monitoring episodes, and to refine the estimate of the extent of the
contaminated zone and the distribution of contaminants within the aquifer.
We recommend determination of the recovery potential of inorganic compounds from the aquifer
by using an extraction test, as discussed in this report
Considering this summary and conclusions, we do not agree that long-term groundwater
remediation is necessary a priori, and recommend that first the effects of the remediation of
contaminated soil on the aquifer quality should be demonstrated. This would involve a
redefinition of the impacted area by a baseline groundwater quality monitoring episode.
monitoring water quality throughout the contaminated zone (current definition) after the
contaminated soil is excavated. Monitoring would permit evaluation of the effects of source
removal, and would confirm that contamination is not migrating from the site. During the
monitoring period, changes in aquifer quality would be evaluated at regular intervals and the
ultimate remediation objectives would be reviewed, reconsidered, and revised, as necessary.
We recommend that a monitoring period of two years following soil (source) removal, with
quarterly sampling episodes, would provide the necessary data. If groundwater quality does
not improve during the monitoring period, or if the compounds begin to migrate toward an off-
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•its receptor, the neea for grounawtw remediation would be re-asaened, and wouia
coneider ma findings of the aadfflonai invemio&tions recommended m vie Ri. the FS, and in
thi reooa
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FIGURES
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»M l-~
GROUND WATER QUALITY 1989* FOR LEAD
" NL INDUSTRIES. INC. SITE
PEDRICKTQWK
MN
IPGEND
PLANT AREA
— STREAM
PROPERTY LINE (APPROX.)
PLUME DELINEATION BASED
ON USEPA ACTION LEVEL OF
10P06 FOR LEAD
EXISTING CULVERT
UPDATED TO
REFLECT 1990 DATA
2* WEL. (NFSTCD PAIR) AND DESIGNATION
•* 4" WELL ANC CESttNATlON
•••••ESTIMATED PLUME DELINEATION
GROUND WATER FLOW DIRECTION
'00
800
—- Langan
Englnt«rtn9 and Environmental S«rrte*t. Inc.
ESTIMATED EXTENT OF
GROUNDWATER CONTAMINATION
35207011,0^ NTS
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NSNJ INC/NL SITE
SURFACE SOIL ANALYSESm
O 0
fROKHTY UNt
Approximate Limit ct
Residual Soil • Lead Contamma
Not included in
No GW data in area which
West Stream discharge
LEGEND
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• >lOOOm«/M
ID 0*3*
SOU.C IN FEET
800 100 0
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DISTRIB JTION OF
LEAD IN SOIL
3S20701
—
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PEDRICKTQWNI
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SE SOUTHEAST SUB-SYSTEM
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. WELL POINT LOCATION AND
DESIGNATION
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SCHEMATIC RELATIONSHIP BETWEEN
CONTAMINATED ZONE AND
PROPOSED RECOVERY SYSTEM
352D7Q1
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APPENDIX A
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APPENDIX A
DOCUMENTS REVIEWED
Langan E-?-«-«Q »'?£-•••'=—*":s Service£
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PEDRICKTOWN OU-1 SUPERFUND PROJECT
GROUNDWATER INVESTIGATION - REMEDIATION
DOCUMENT REVIEW UST
Document Title
Remedial Investigation. National Smelting of New Jersey. inc./NL Industries. Inc. Site
March 1991 • O'Brien and Gere
Vois: I. Repoa Tables. Figures
II. Appendices. Exhibits
III Appendices R-U
IV Appendices v-w
Final Feasibility Study - ML Industries. Inc. Site
1993 • O'Brien and Gere
Addendum to the Final Feasibility Study Report
NL Industries. Inc. Supertund
Operaoie Unit One
(Undated - No preparer Listed)
Superfund Proposed Plan
NL industries, inc.
Operable Unit One
U.S. EPA-July 1993
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APPENDIX B
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APPENDIX B
EVALUATION OF THE EFFICIENCY OF USING INTERCEPTOR WELL
NETWORK AS A GROUNDWATER RECOVERY SYSTEM
-,"•: =
•: — **•» S*-.-:«s
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APPENDIX B
EVALUATION OF THE EFFICIENCY OF USING INTERCEPTOR WELL
NETWORK AS A GROUNDWATER RECOVERY SYSTEM
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r... CVICTINP. WFIl POINT IOCATIONS
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POINT LOCATIONS
NL INDUSTRIES. -NC. Si
^PEDRICKTQWN
LEGEND
— PLANT AREA
STREAM
PROPERTY UNE (APPROX.)\ «...•«. ESTIMATED PLUME DELINEATION
NE NORTHEAST SUB-SYSTEM
s£ SOUTHEAST SUB-SYSTEM
sw SOUTHWEST SUB-SYSTEM
it* \ORTHWEST SUB-SYSTEM
. WELL POINT IOCATON AND
DESIGNATION
A IXBTINC CULVERT
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Janet D. Smith
Associate General Counsel
September 17, 1993
BY HAND
•*
Mr. Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
Emergency & Remedial Response Division
26 Federal Plaza, Room 720
New York, New York 10278
Re: Comments on U.S. Environmental Protection Agency
Proposed Plan for Operable Unit One, National
Smelting of New Jersey/NL Industries, Inc. Site,
Pedricktown. Salem County. New Jersey
Dear Mr. Gilbert:
This letter sets forth the comments of NL Industries, Inc.
on the U.S. Environmental Protection Agency's July 1993 Proposed
Plan for Operable Unit One of the National Smelting of New
Jersey/NL Industries, Inc. Superfund Site, Pedricktown, Salem
County, New Jersey (hereinafter, the "Pedricktown Site.") In
summary, the comments address the following topics: (1) the
inappropriate selectioh of 500 parts per million as the cleanup
level for lead-in-soil at the site; (2) the premature and unwise
decision to dredge stream sediments north of U.S. Route 130; (3)
the erroneous choice of soil washing, an unproven technology, as
the remedial alternative for soil; and (4) the exclusive
selection of the on-site streams as the discharge point for
treated groundwater, rather than considering both the streams and
the Delaware River viable discharge options. For these reasons,
the Proposed Plan is inconsistent with the National Contingency
Plan ("NCP"), 40 C.F.R. Part 300, arbitrary, capricious and not
in accordance with law, including the Comprehensive Environmental
Response, Compensation and Liability Act ("CERCLA"), 42 U.S.C.
§9601 et sea. We also submit comments on the Phase V removal
action approved by the U.S. Environmental Protection Agency in
conjunction with the Proposed Plan.
NL Industries, Inc.
Office of General Counsel
445 Park Avenue, New York, New York 10022 Tel. (212) 421-7204
Telecopier (212) 421-7207
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -2-
Z. There is No Basis for the Selection of 500 Parts
Per Million As the Cleanup Criterion for Lead-in-Soil
The Proposed Plan states that the cleanup criterion for
lead-in-soil is based on the U.S. EPA's "Interim Guidance on
Establishing Soil Lead Cleanup Levels at Superfund Sites"1
("Interim Guidance"), a U.S. EPA model that is used to evaluate
potential lead exposure of children, and the Ecological
Assessment performed for the Pedricktown Site. None of these
supports the selection of the cleanup level set forth in the
Proposed Plan. Further, a site-specific evaluation of lead
exposures conducted as part of the baseline Risk Assessment
performed for the Pedricktown Site indicates no adverse health
effects from exposure to lead.
A. The Interim Guidance for Lead Cleanup
Does Not Apply to the Pedricktown Site
The Interim Guidance recommends using a cleanup level for
lead-in-soil in residential areas within the range of 500 to 1000
parts per million ("ppm"). This guidance is intended to protect
human health in residential settings, but it focuses particularly
on children, the most lead-sensitive portion of the population.
Since the 500 to 1000 ppm cleanup range of the Interim Guidance
is a recommendation for residential settings, it does not apply
to the Pedricktown Site, an industrial property, where children
are not found.
The Interim Guidance clearly specifies that a lead-in-soil
cleanup range of 500 to 1000 ppm only applies "when the current
or predicted land use is residential." The Pedricktown Site
property is part of an area zoned for development as an
industrial park. This area includes present and past operations
of B.F. Goodrich, Airco, Browning-Ferris Industries, Exxon a
cogeneration plant, and others. Given the industrial nature of
the site and the zoning restrictions on its future use as
anything other than industrial, it is inappropriate to conclude
that the site will be either used for residential development or
frequented by children. Therefore, the Interim Guidance cannot
form the basis for a cleanup criterion for lead at the site,
except to suggest that because of its industrial nature the site
cleanup criterion for lead-in-soil should be above 1000 ppm.
1 The Interim Guidance is set forth in the U.S.
Environmental Protection Agency's OSWER (Office of Solid Waste
and Emergency Response) Directive #9355.4-02, September 7, 1989.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -3-
The implicit assumption of future residential use of the
Pedricktown Site contained in EPA's application of the Interim
Guidance to the site is inconsistent with recent testimony
provided by EPA Deputy Administrator Robert Sussman at
Congressional oversight hearings relating to the selection of
remedies for Superfund sites. At the June 23, 1993 hearings, Mr.
Sussman stated that EPA is now moving in the direction of
assuming that the present land use will be the future land use
unless there is persuasive information which is presented that
shows current land use is likely to change.2 since the
Pedricktown Site is zoned for industrial Use and is surrounded by
parcels similarly zoned and currently used for industrial
purposes, continued industrial use should be assumed in carrying
out a risk assessment. Consequently, site-specific
considerations warrant the use of lead-in-soil cleanup levels
above the higher end of the residential cleanup range of 1000
ppm.
B. EPA's Model of Childhood Lead Exposure Should Not Be
to an Industrial Site
In recent years, EPA has been developing and calibrating a
model that predicts blood lead levels in children based on
exposure to lead-contaminated media in lieu of its older,
conventional risk assessment procedures for other pollutants.
Since the model is intended to be applied to children in typical
residential settings, it should not be applied to the Pedricktown
Site. Moreover, the model is still under development and is
being refined.
v
Nonetheless, available information on the model actually
reinforces the conclusion that a lead-in-soil cleanup criterion
for the Pedricktown Site based on risk considerations would be
significantly higher than the 500 ppm selected in the Proposed
Plan. EPA has circulated a memorandum3 that states that if
default assumptions are used with respect to lead exposures, a
lead-in-soil cleanup criterion of 500 ppm would always be
predicted by the model. These default assumptions represent
exposure from regular contact and ingestion of lead, which is
2 See also Superfund Administrative Improvements, Final
Report, June 23, 1993, at pp. 24-5.
3 OSWER memorandum "Update on OSWER Soil Lead Cleanup
Guidance" (Don Clay, U.S. Environmental Protection Agency, August
28, 1991).
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -4-
substantially higher than the intermittent, low level exposure
that might occur from occasional trespassing onto the
Pedricktown Site by children. Therefore, lead cleanup criteria
for the site would be significantly higher than 500 ppm, and
should be above the Interim Guidance range of 500 to 1000 ppm
recommended for in residential areas.
C. The Ecological Risk Assessment Does Not Support a 500
Ppm Lead Cleanup Criterion
The Proposed Plan provides that "EPA*s site-specific
Ecological Assessment concluded that 500 ppm of lead is the
appropriate remedial action objective for site soils located in
wetland areas, as well as stream sediments.1* However, a review
of the Ecological Assessment indicates that several overly-
conservative assumptions were used in the estimation of exposures
for the target species, and, as acknowledged in the assessment,
considerable uncertainty was associated with the literature-
derived toxicological data applied in the assessment. As a
consequence, by compounding inappropriate assumptions and
uncertainties, the Ecological Assessment predicts that an
unacceptable risk from exposure to lead exists at virtually any
lead concentration in soil. This failure of a "reality check"
significantly limits the use of the Ecological Assessment for
developing a soil cleanup criterion. Thus, the 500 ppm lead
cleanup criterion is arbitrarily selected and is not supported by
the results of the Ecological Assessment.
During the development of the work plan for the Ecological
Assessment and thereafter as it was carried out, NL Industries
and its consultant ENVIRON provided extensive comments on the
Ecological Assessment. A copy of the comments is attached hereto
as Attachment 1. The following highlights the key criticisms of
EPA's reliance upon the Ecological Assessment in risk management
decisions at the Pedricktown Site:
• The Ecological Assessment does not establish a strong or
consistent correlation between lead levels in soils and in
earthworms and white-footed mice. Significantly, the field
investigation failed to demonstrate that concentrations in
earthworms decreased with decreasing exposure to lead. This
failure severely limits the use of the dietary exposure-
based risk assessment results to establish a lead-in-soil
cleanup criterion at the site. Target species such as the
woodcock whose risk supposedly derives from ingestion of
earthworms may not be at risk at all if the level of lead in
earthworms is not directly proportional to the level of
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -5-
lead-in-soil. This inadequacy of the field investigation,
the foundation of the Ecological Assessment, largely
invalidates its use as support for the lead-in-soil cleanup
criterion selected in the Proposed Plan.
In developing cleanup criteria that are proposed as maximum
limit values, EPA has failed to consider that risks are
derived from exposures of biota to mean soil levels within
their home range. For example, if 500 ppm is established as
a cleanup level for lead-in-soil (based on exposures of
biota to soils that average 500 ppm) ,< then once the site is
remediated to a 500 ppm maximum residual level, then the
actual exposures will be to soils in the species' home range
that average less than 500 ppm. Thus, exposure should be
recalculated taking into account the post-remedial reduction
in the mean soil levels within a species' home range. This
correction would make a major difference at the Pedricktown
site, where the elevated concentrations requiring
remediation constitute approximately 30 percent of the home
range of the woodcock, one of the species to be protected by
the proposed cleanup. Remediation of this area with the
highest soil levels would significantly reduce the mean soil
levels in the home range of the target species and therefore
the mean exposure and risk would decrease significantly.
If the hazard quotient "should be interpreted based on the
severity of the effect reported and the magnitude of the
calculated quotient," as the Ecological Assessment states,
then even the effects on the woodcock, which have the
highest hazard quotient estimates, would be further reduced
because the toxicity endpoints (e.g., reductions in ALAD
activity, hemoglobin and hematocrit, and in brain weight of
nestlings) are not generally considered as severe as the
ecological endpoints of survival, reproduction or growth.
The use of scientifically justifiable alternative values for
some of the exposure parameters (e.g., home range) and
toxicity thresholds would reduce the hazard quotient
estimates developed in the Ecological Assessment. For
example, the available toxicity data indicate that a
toxicity threshold of 8.25 mg/kg/day or higher is justified
for the woodcock rather than the 4.1 mg/kg/day value that
was applied. Thus, the Ecological Assessment
proportionately overpredicts risks for the woodcock, and a
cleanup criterion derived from consideration of risks to the
woodcock would be proportionately too low.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -6-
D. The Risk Assessment for Lead Shows
No Potential for Adverse Health Effects
A baseline Risk Assessment was conducted for the Pedricktown
Site to evaluate the health effects associated with exposure to
soils and ground water affected by the site. This Risk
Assessment evaluated the future use of the site as industrial,
and concluded that there would be no potential adverse health
effects from exposure to lead in soils for a worker population.
Therefore, EPA's proposed selection of the 500 ppm cleanup
criterion is contrary to the results of the risk assessment, and
has not been substantiated by any other quantitative
characterization of risks at the site.
II. The EPA Proposal to Clean up Sediments North of U.S. Route
130 Is Premature/ Unwarranted and Could Have Severe Adverse
ntal Impacts _
The Proposed Plan calls for remediation of stream segments
located north of U.S. Route 130 ("Route 130"). However,
commencement of this work is unwarranted by the present record,
and ignores several important factors concerning these streams/
We recommend the adoption of Stream Alternative A for the
sediments situated north of Route 130.
First, the water quality of the stream segments north of
Route 130 should dramatically improve as a direct result of
removal of the sources of the contamination. In particular, the
Pedricktown Site Operable Unit Two surface cleanup of substantial
sources of runoff from, the Site, including the removal of lead-
bearing slag, waste piles and pooled surface water, is now
complete. This work has eliminated sources that contributed to
the presence of lead in the waterways north of Route 130.
Further, the anticipated removal of sediments south of Route 130,
where significantly higher levels of lead are found in the
sediments than are present to the north, should have an
ameliorating effect on stream and river beds sediments north of
Route 130. In addition, the ongoing flow and deposition of new
sediments from upstream to downstream, from south to north, a
process that is continual in the stream, will create a natural
cap on top of the sediments north of Route 130.
* The comments summarized in this Section II. were submitted
on NL's behalf by O'Brien & Gere to the U.S. EPA in July, 1992.
See Attachment 2.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -7-
Second, the Proposed Plan fails to take into account the
negative impacts of remedial action in the stream segments north
of Route 130. These stream segments are too large to be diverted
or dewatered, the techniques that can be used in the stream south
of Route 130. The proposed excavation and dredging will be
severely detrimental to the aquatic environment. Such dredging
is likely to result in downstream transport of entrained, lead-
bearing sediments and redistribution of contamination. Sediment
resuspension and slump during the dredging might serve only to
increase the concentration of lead in the water column. Dredging
these stream sediments would be destructive to the existing
ecosystem, increasing turbidity and decimating the benthic flora
and fauna. This was made abundantly clear by the high mortality
reflected in the results of the bioassay studies upon sediments
from the stream conducted by Dr. Sprenger of the U.S. EPA as part
of the field investigation of the Ecological Assessment. Such
remediation should not be undertaken without first awaiting the
outcome of the sediment cleanup south of Route 130, and allowing
for the passage of time so that the newly cleaned sediments may
form a cap. Thereafter, if monitoring demonstrates that stream
sediments north of Route 130 contain levels of lead that are too
high the decision to cleanup those sediments could be revisited.
Finally, while weighing the pros and cons of these invasive
cleanup measures in the stream north of Route 130, the Agency
should also consider that the sediments are affected by sources
of lead not related to the Site. Elevated lead levels are found
in two tributaries which discharge into the area north of Route
130 but do not receive runoff from the Site. These two
tributaries were sampled by EPA (Samples EPA-1 and EPA-6.) Most
likely, an upstream source affects these tributaries and is also
contributing to water quality north of Route 130. In addition to
the tributaries, runoff from the Army Corps of Engineers' dredge
spoils piles will continue to enter the channels north of Route
130. The contribution of the tributaries and the dredge spoil
disposal by the Army Corps may result in recontamination of
sediments north of Route 130. Thus, any cleanup of sediments by
dredging north of Route 130 could be physically destructive of
habitat, and may be futile due to contribution by other sources.
For all these reasons, we believe that the correct remedial
alternative for the stream sediments north of Route 130 is
Sediment Alternative A. This alternative, which includes
monitoring of stream water quality, would be most protective of
the aquatic environment as it would allow time for the related
cleanup activities to proceed, positively affecting the stream
sediments north of Route 130. Further, this Alternative would
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -8-
not prematurely disturb the benthic ecosystem with destructive
techniques that could be unnecessary, and in the long run,
furnish no net environmental benefit.
III. Solidification/Stabilization Technology is A Superior Choice
Because Soil Washing Technology is Unproven At Sites
Comparable to Pedricktown, and Available Data Suggests That
It Is Expensive and Will Fail at the Pedricktovn Site
The Proposed Plan recommends modified Alternative Soil D
as the remedial technology for contaminated soil at the
Pedricktown Site. However, soil washing has not been fully
implemented to date for remediation at lead battery or smelting
sites, and available data suggests that it will fail at sites
with soils that contain large portions of fine clays and high
levels of humic material. In contrast, the soil treatment
technology we recommend, solidification/stabilization, is a
proven and widely used remedial technology for lead. It is also
more cost-effective than soil washing, and does not result in the
potential introduction of additional pollutants. Soil washing
may even increase the volume of contaminants at the Pedricktown
Site.
A. Overview of Soil Washing
Soil washing is a hybrid of remedial technologies. It may
include the use of a washing solution, such as water,
surfactants, chelating agents, or acidic solutions to achieve
necessary particle size and separation and to extract
contaminants from the soil. The washing solution and
contaminated soil are mixed together, mechanically agitated and
separated again. After this treatment, the soil is either
returned to the site, treated further or disposed of offsite.
The critical factor that determines the success of soil washing
is whether it can extract sufficient lead to render the soil
nonhazardous and reduce lead concentrations below applicable
response objectives.
Under specific circumstances, soil washing has shown promise
in the treatment of heavy metals, although not for lead. The
technology works best on coarse-grained sandy soils, but is only
marginally effective for remediating silty soils (more effective
for treating a mix of sandy/silty soils then for a mix of
silty/clay soils), and ineffective for fine clay soils.
Since soil washing is not a proven technology, its
performance history at lead battery sites comparable to the
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -9-
Pedricktown Site must be taken into account in determining its
implementability for the Pedricktown Site. This performance
history is reviewed in the next section.
B. Review of Soil Washing Experience and Literature
Suggests That the Technology is Ill-Suited for
Pedricktown
1. Selection of Control Technologies for Remediation
of Lead Battery Recycling Sites, EPA/540/2-91/014,
July 1991 _r
This U.S. Environmental Protection Agency work reviews
remedial options for lead contaminated soils including
solidification/stabilization and soil washing/acid extraction.
The document states that solidification/stabilization has been
proven effective at full scale in remediating lead contaminated
soils. The document further states that, while soil washing has
been shown to be effective on a bench scale, it has not been
successfully demonstrated at full scale. The Agency cites two
full scale demonstrations, Lee's Farm in Woodville, Wisconsin and
the Arcanum site in Troy, Ohio, where soil washing of lead
contamination was attempted. In both cases, EDTA, a chelating
agent, was used to promote the removal of lead from solution.
Neither site was sufficiently cleaned up by the soil washing so
soils at both sites required subsequent treatment by
solidification/stabilization to complete the remediation.
According to the paper, the majority of the problems with soil
washing at these sites were related to materials handling.
Clogging of filters by fine silty particles and excessive loading
of suspended solids into the EDTA recovery system were nagging
problems. These problems foreshadow what could be expected at
sites with fine sandy soils or silty/clay soils, such as
Pedricktown.
The paper also refers to the U.S. Bureau of Mines acid
leaching process which used nitric acid and pretreatment to
remove lead from soil. The Bureau of Mines has not yet completed
their work or evaluated their process on a full scale. The paper
concludes that soils which are high in clay, silt, and/or humic
material are difficult to treat by soil washing, and that soil
washing has not been effectively demonstrated on a full scale.
Review of this paper suggests that soil washing makes a poor
choice for Pedricktown, in light of the soil composition, and
leads to the conclusion that solidification/stabilization is a
better, more reliable option.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -10-
2. Control Technologies for Remediation of
Contaminated Soil and Waste Deposits at Superfund
Lead Acid Battery Recycling Sites, Michael Boyer,
et al.. U.S. EPA. Edison. N.J. Julv 1992.
This U.S. Environmental Protection Agency paper states that
full scale remediation using soil washing has not been
successfully demonstrated even though bench scale studies have
been favorable. The paper concludes that one of the chief
limiting factors for soil washing performance is the physical
nature of the soils, and that soils high in clay, silt or fines
have proven difficult to treat. The paper also refers to the
full scale soil washing failures at Lee's Farm in Woodville,
Wisconsin, the ILCO site in Leeds, Alabama, and the U.S. Bureau
of Mines bench scale studies.
The Bureau of Mines studies did indicate that high levels of
lead removal can be achieved with acid washing. However, it is
highly undesirable to introduce acid into the environment at a
former lead smelter site such as Pedricktown. Moreover, the
Bureau of Mines results have not been duplicated at full scale.
The Bureau of Mines studies also indicated that soil washing with
water and EDTA did not remove significant amounts of lead from
any of the soil fractions.
Written a year after the July 1991 U.S. Environmental
Protection Agency paper on soil washing, this later work does not
hold out promise that soil washing has been improved into a
remedial technology that will work well on lead-contaminated
soils such as those at the Pedricktown Site.
3. Soils Washing, Bergmann USA/Applied Environmental
Technologies Inc., Michael Mann and Jill Besch,
August 1993
The organization performing this work is Applied
Environmental Technologies Inc. (AET), an Dutch-American joint
venture. We view the results reported as less reliable than
those reported by the U.S. Environmental Protection Agency, since
a company in the remedial technology business may be inclined to
present a rosy picture of their abilities for marketing purposes.
We include the results reported here for completeness.
The article reports that soil washing technology has been
successfully employed by AET at five sites in the Netherlands.
All of these projects were performed on coarse, sandy soils with
initial soil concentrations in the range of 1,000 ppm lead.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -11-
According to AET, treatment efficiencies in the range of 80-90%
have been demonstrated on these projects.5
AET has designed a soil washing remediation project in
Winslow Township, New Jersey that is underway. This is the first
full scale remediation of soils contaminated by heavy metals
using soil washing in the United States. Soils at this site are
primarily coarse sands. Contaminants of concern are chromium,
copper, and nickel at concentrations of up to 500 ppm, 8,000 ppm,
and 3,500 ppm respectively, but not lead. Initial data suggests
treatment efficiencies are in the 80-85% range. AET claims that
its process is effective in soils with less than 10% by weight of
humic material and 400 mesh or larger soil particles, but warns
that soils not meeting these criteria may not be amenable to soil
washing.
Soils at the Pedricktown Site sharply contrast with the
soils reported to be suitable for treatment by AET. Pedricktown
soils contain fine sand, silt, clay and a large fraction of humic
material, the type of material reported to clog treatment filters
in the U.S. EPA reports. Moreover, Pedricktown Site soils have
initial lead concentrations ranging up to 12,700 ppm, as opposed
to the average of 1000 ppm reportedly treated by AET in the
Netherlands. Thus, treatment by soil washing, even if it could
be performed, is unlikely to produce treated soil meeting the 500
ppm lead remedial objective.
Treatment costs using the AET process are typically in the
$150 to $250 per ton range depending on soil quantity and
characteristics.
4. Soil Washing Test Performed on Pedricktown Site
Soils by the Center for Hazardous Materials
Research
The Center for Hazardous Materials Research reportedly
subjected a sample of soils from the Pedricktown Site to soil
washing and achieved lead concentration reduction from 30,000 ppm
to "about" 1,000 ppm. The test conducted under laboratory
conditions was unable to reduce levels of lead-in-soil below 1000
5 We report upon what AET has presented, although we are
unable to corroborate their work. On a cautionary note, it is
difficult to extrapolate the results obtained in the Netherlands
to what might occur in the U.S. due to differences in the
regulatory environment.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -12-
ppm and therefore does not demonstrate that the designated
treatment objective for the Pedricktovn Site of 500 ppm lead can
be achieved at full scale. Although we were not afforded the
opportunity to observe this sampling or duplicate the results,
we believe that it is likely that only soils from the coarse
sandy fraction at the Pedricktown Site were subjected to the
test, since otherwise the results would be inconsistent with the
larger official studies reported above by the U.S. EPA.
C. Conclusions Derived From Review of U.S. EPA Reports
Suggest That Soil Washing Will Fail at the Pedricktown
Site
A review of available literature on soil washing shows that
there have been numerous failures in applying soil washing at
Superfund sites, and in laboratory efforts to develop the
process. The literature does suggest that the technology may
succeed when the soil to be treated possesses certain
characteristics that make it more susceptible to washing, such as
being coarse and sandy. Soil washing has not been demonstrated
as effective at full scale in remediating lead contaminated soils
in the United States.
While soil washing can be an effective remedial technology
under ideal soil conditions, the feasibility of soil washing for
the Pedricktown Site is highly questionable. Soils at
Pedricktown contain fine sand, silt, clay and a considerable
fraction of humic material. Such soils have been repeatedly
shown to be difficult to treat with soil washing. Past attempts
to treat such silts by soil washing have resulted in the
occurrence of materials handling problems which resulted in the
abandonment of soil washing as a remedial technology at full
scale. Further, soils at the Pedricktown Site contain levels of
lead as high as 12,700 ppm, lending a high degree of difficulty
to the treatment process. It would be highly undesirable to
complicate the environment at Pedricktown by the introduction of
acids to promote better soil washing.
D. Soil Washing is Inferior to
Solidification/Stabilization When the Statutory
Criteria for the Selection of Remedies at Superfund
Sites Are Applied
Application of the Superfund criteria for remedy selection
to soil washing and solidification/stabilization results in
inferior marks for soil washing when judged on implementability,
cost, long and short term effectiveness and reduction in
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -13-
toxicity, mobility and volume. Soil washing has not been
successfully implemented at full scale for remediation of lead
contaminated soils at sites similar to the Pedricktown Site. To
the contrary, sites that are comparable, such as Leed's Farm,
Arcanum and ILCO resulted in large-scale.remedial failures.
Portions of these cleanups had to be completed using
solidification/stabilization. Reports by the U.S. EPA in the
literature strongly suggest that soil washing would fail at
Pedricktown.
Since soil washing has not been successfully implemented at
full scale for remediation of lead contaminated soils at lead
battery sites, extensive treatability studies would be required
to design a workable remedy. Parameters to be examined would be
expected efficiency, type of washing solution, optimum contact
time, and secondary waste generation quantities and
characteristics. The particular characteristics and contaminant
concentrations of the wastes, soil types and contaminant
concentrations at the Pedricktown Site would have to be examined
during these studies. Given the heterogenous nature of the
Pedricktown soils and the relatively high concentrations of
contaminants, extensive treatability studies would be required in
the remedial design phase. As acknowledged by the U.S. EPA6,
there must be economies of scale involved in application of the
soil washing technology in order to make it cost-effective. But
since the quantity of soil that could be washed at Pedricktown is
a relatively small amount, approximately 10,000 cubic yards, no
economy of scale would exist, thereby rendering soil washing a
remedy that scores low marks for both implementability and cost-
effectiveness .
Even if soil washing were feasible, it would still be
expensive. Unit costs for soil washing of heavy metals are
typically $150 to $250 per ton for full scale remediations. Unit
costs for solidification/stabilization are typically in the range
of $100 per ton. A unit cost ratio of soil washing
solidification/stabilization of 1.5/1 is typical for remediation.
This ratio is actually somewhat higher for the Pedricktown Site
according to the EPA figures in the Proposed Plan: the costs of
Soil Alternatives D and F, as modified by the U.S. EPA, are
projected as $10,712,000 and $6,450,000 respectively (a cost
ratio of 1.65/1). Thus, soil washing, even if it were readily
6 "Guide to Conducting Treatability Studies Under CERCLA:
Soil Washing", EPA/540/2-91/020A, September 1991.
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -14-
implementable, would be far more expensive than
solidification/stabilization at the Pedricktovn Site.
If soil washing is unable to extract the lead to levels that
meet response objectives, soil washing will be ineffective in
reducing toxicity, and would in fact increase volume. And if the
residual lead concentrations are not low enough for the soil to
be used as replacement fill material, washed soil would be
replaced in the on-site consolidation pile. Thus, the soil
washing would have exacerbated conditions at the Pedricktown Site
by increasing volume.7 Moreover, the sludge and chemicals
created in the soil washing process would also require disposal,
thereby further increasing the total amount of material requiring
treatment and disposal.
As to long-term and short-term effectiveness, soil washing
trials at Lee's Farm and Arcanum site showed that soil washing
technology is ineffective at lead battery sites. Past experience
further demonstrates that soil washing has limited effectiveness
at sites with fine silty or clay soils, or soils with appreciable
quantities of organic matter. The ultimate success of soil
washing does not lie in its ability to extract lead, but in
removing enough lead to meet remedial objectives. Aqueous washes
have been largely unsuccessful in this regard, with limited
success experienced at the bench scale level using acid leaches.
However, acid leaches have associated problems including proper
worker training to handle acids, necessity for specialized acid-
resistant equipment for the acid leaching process and the further
treatment of lead sulfate sludge that is produced. In general,
the historical lack of demonstrated effectiveness of soil washing
at lead sites casts grave doubt upon its ability to meet remedial
objectives at the Pedricktown Site.
IV. The Agency Should Retain Two Options for Groundwater
Discharge Rather than Selecting Only the Stream Discharge
Point
NL Industries has studied the September 15, 1993 "Review and
Comments on Groundwater Investigation and Remediation Strategies"
7 While there may be some small benefit from the reduction
in mobility of the washed soil disposed in the consolidation
pile, given that the pile must be lined and capped anyway and the
material has inherently low solubility, the mobility of the lead
is low even without treatment. Thus, the incremental benefit
from soil washing is marginal at best.
-------
Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -15-
prepared by Langan Engineering and Environmental Services, Inc.,
submitted to the U.S. EPA as commentary on the Proposed Plan. NL
joins in the comments to the extent that they endorse further
groundvater monitoring and the re-examination of the need for
groundvater remediation.
If and when the EPA determines to proceed with groundwater
remediation as set forth in the Proposed Plan, NL believes that
the Agency should preserve two options for the discharge of
treated groundwater. The Proposed Plan recommends the discharge
of treated groundwater to the East or West* Streams rather than to
the Delaware River. This selection is premised on the assumption
that a Delaware River discharge might be delayed or blocked by
the need for the construction of a pipeline crossing the railroad
tracks, Route 130 and several private properties, and would
require a NJPDES permit. We believe that these logistical issues
could be readily resolved, and would not delay the groundwater
cleanup. NL recommends that the Proposed Plan be modified to
preserve Groundwater Alternatives G-l and G-2 inasmuch as
Alternative G-2 may be more implementable and cost effective, but
the alternatives are otherwise comparable. We recommend that the
final choice of discharge point be made during the remedial
design phase.
A. Logistics and Access
There is sufficient space on the Pedricktown Site north of
the railroad right-of-way and south of the existing landfill to
accommodate a treatment plant of the type and size anticipated
for treating groundwater at the site. In fact, the existing well
point system piping network extends under the railbed to this
location. Thus, a treatment plant could be sited north of the
railroad right-of-way, close to the Delaware. The outfall could
be constructed under Route 130, since the jacking of water
pipelines under major highways is routine construction practice.
The requisite permit from the New Jersey Department of
Transportation should be readily obtained.
NL has commenced the process of exploring whether access
agreements may be obtained to construct a pipeline across the
private properties situated between the north side of the
Pedricktown Site and the Delaware River. Both B.F. Goodrich8 and
8 B.F. Goodrich has already demonstrated the feasibility of
such a pipeline in that it currently runs a discharge pipeline
from its facility to the Delaware River.
-------
Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -16-
Corrosion Control have favorably responded to NL's overtures. A
copy of correspondence to these companies is attached as
Attachment 3. Based on discussions with these companies, we
believe that access for a pipeline easement could be obtained in
a timely fashion and would not delay construction of the outfall.
B. Water Discharge Permit Requirements
Constructing a treatment plant and outfall as proposed in
Groundwater Alternative G-2 would require water discharge
permits, a New Jersey Pollutant Discharge Elimination System
(NJPDES) Discharge to Surface Water permit and a Treatment Works
Approval. The NJPDES permit is required prior to discharging
treated groundwater to the Delaware River. The permit would
specify flow and effluent limitations for contaminants. Our
review of Recommended Water Quality Criteria for Toxic Pollutants
for the Delaware River Estuary (January 1992), confirmed by
representatives of the Delaware River Basin Commission, indicates
that lead discharge levels for the proposed treatment plant could
be up to 63 parts per billion and be protective of the aquatic
environment for the Delaware River Basin's Region V.e This
remedial objective should be more implementable and cost
effective than a discharge to the East or West Stream, where lead
would have to be treated to 10 parts per billion or less. We do
not anticipate any delay in obtaining a NJPDES permit, since it
must be issued six months after the receipt of a complete
application.
Several other permits may be required for the Delaware
discharge option, and they should be readily obtained. A
Treatment Works Approval ("TWA") would be required for the
construction of the groundwater treatment plant and outfall. The
State of New Jersey is required by law to review and approve a
TWA application within 90 days. Additional permits which may be
needed (depending on the exact placement of the discharge
outfall) include a wetlands permit, a Coastal Area Facility
Review Act permit and a stream encroachment permit. All of these
permits must be issued within ninety days after receipt of a
complete application.
9 Upstream of any discharge from the Pedricktown site, the
Delaware River receives effluent of 500 mgd from the City of
Philadelphia wastewater treatment plant as well as several other
significant municipal and industrial discharges. The volume of
flow in the River is sufficient to accept these discharges with
no degradation.
-------
Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -17-
The total time for obtaining permits is approximately twelve
months, allowing adequate time for completion of the permit
applications. Since design of the groundwater treatment system,
including treatability studies, should take twelve months, and
construction should take twelve to eighteen months, the time
needed to secure the necessary permits would not delay the
commencement of treatment, since it can occur at the same time as
design and construction of the treatment works. Accordingly, the
discharge of treated groundwater to the Delaware River is as
feasible as a discharge to the East or West Streams in terms of
time, permitting and access.
C. Because Alternative G-2 Might Provide a Substantial
Cost Savings Over G-l, It Would Be Preferable to Retain
Both Discharge Options
Anticipated costs for Groundwater Alternative G-l are
approximately $1.5 million more than Alternative G-2. These
additional costs are primarily attributable to the costs
associated with the reverse osmosis required to meet water
quality standards in the streams. Thus, G-2 may be both more
implementable and less expensive. Since Alternatives G-l and G-2
are otherwise roughly comparable in meeting environmental
objectives, NL recommends retaining both discharge options, and
making the final decision during the remedial design phase.
v. The Phase V Removal Action is a Public Works Project
Not an Environmental Response Action
The U.S. EPA approved the Phase V removal action for the
Pedricktown Site on July 15, 1993, in conjunction with the
Proposed Plan for Operable Unit One. The Removal Action
Memorandum requested a ceiling increase of $1,237,700. The Phase
V Removal Action is: (1) inconsistent with the NCP, (2)
inconsistent with the proposed long term remedial action, and
(3) predicated upon a Salem County flood control project rather
than an imminent and substantial endangerment to human health,
welfare, or the environment.
A. The Phase V Removal Is Inconsistent With The NCP
CERCLA establishes criteria for responding to a release into
the environment of any pollutant or contaminant that may present
an imminent and substantial danger to the public health and
welfare. The criteria include the following:
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Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -18-
1. "Removal actions shall, to the extent practical,
contribute to the efficient performance of any
anticipated long term remedial action with respect to
the release concerned." NCP §300. 4 15 (c).
At the Pedricktown Site, all upgradient sources of the
contaminant of concern (lead) have not been removed. Surface
soils, immediately upgradient of the West Stream, contain lead in
excess of 9,000 ppm. These soils are scheduled for remedial
action pursuant to the proposed plan for Operable Unit One l.
The excavation of the stream to a depth of ^ four feet may enhance
erosion of the upgradient surface soils, resulting in the
recontamination of the stream sediments. Accordingly, this
removal action is inconsistent with the proposed remedial action.
Moreover, the environmental remediation of the East Stream should
be carried out at the same time as the West Stream to avoid the
inherent waste in remobilization.
2. "Fund financed removal actions, other then those
authorized under section 104 (b) of CERCLA, shall be
terminated after $2 million has been obligated for the
action or 12 months have elapsed from the date that
removal activities begin onsite .... " NCP §300.415
Funding for Phase I of the Removal Action was approved in
1988. The Phase I Removal Action was completed on May 31, 1989,
and the Phase IV Removal Action was completed on June 26, 1992.
Accordingly, more than four years have elapsed from the date that
removal activities began on site, and more than twelve months
since Phase IV was completed. Thus, the Phase V removal
contravenes CERCLA and the NCP.
3. "Whenever a planning period of at least six months
exists before on-site activities must be instituted . . .
[t]he lead agency shall conduct an engineering
evaluation/cost analysis ("EE/CA") or its equivalent"
NCP §300.415 (b)(4), and shall M[p]ublish a notice of
availability and brief description of the EE/CA in a
major local newspaper of general circulation . . . [and]
[p]rovide a reasonable opportunity, not less than 30
calendar days for submission of written and oral
comments ---- " NCP §300.415(m) (4) .
The Agency has had full knowledge of the contaminants of
concern in the West Stream sediments prior to the approval of the
Remedial Investigation Report on July 8, 1991, providing more
-------
Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -19-
then ample time for completion of the EE/CA. There has been no
notice of availability or brief description of the EE/CA
published to date, or opportunity provided for submission of
comments pursuant to the above.
4. "Where the responsible parties are known, an effort
initially shall be made, to the extent practicable, to
determine whether they can and will perform the
necessary removal action promptly and properly." NCP
§300.415(3)(2).
«•»
The Agency has known the identity and location of numerous
potentially responsible parties prior to the Phase I Removal
Action of 1989, and has not notified any of these parties
regarding any phase of the removal actions.
B. The Phase V Removal Action Is A Thinly Disguised Public
Works Project
In January 1992, the Salem County Mosquito Control
Commission ("SCMCC") commenced excavation of sediments from the
West Stream, immediately south of Route 130, depositing those
sediments along the northeast bank of the stream. This action
was performed to alleviate flooding in upstream farm lands. Due
to the distribution of contaminated sediments along the banks of
the stream, subjecting the area soils to potential contamination,
the EPA required the SCMCC to cease disturbing the contaminated
stream sediments. Forced to change course, the SCMCC installed
drainage ditches along the north sides of Pennsville-Pedricktown
Road and New Road as an alternative measure to reduce the flood
potential.
The risk of flooding and sediment redistribution has been
greatly diminished by these SCMCC flood control measures.
Meanwhile, the EPA performed removal action at the site, and a
Focused Feasibility Study which culminated in the performance of
Operable Unit Two at the site. Throughout the past year,
additional upgradient sources of lead have been removed from the
site under Operable Unit Two, further reducing the potential
spread of contaminants. Accordingly, the potential risk or
threat to health and the environment has been controlled by
focusing on both the risks of flooding and of runoff from surface
contaminants. Nonetheless, the EPA has chosen to proceed with
another phase of its four-year old removal action.
While the U.S. EPA will be removing only the first foot of
sediment from the stream, the Agency is voluntarily donating
-------
Michael Gilbert, Project Manager
U.S. Environmental Protection Agency
September 17, 1993
Page -20-
resources to the SCMCC "stream enhancement" program by excavating
to a fourteen foot width in a stream having a present maximum
width of approximately five to six feet. The stream widening is
dictated only by the SCMCC program, not by any stated
environmental concerns. After the U.S. EPA work, the SCMCC will
deepen the stream by an additional three feet. The SCMCC, and
not the EPA, will be determining stream sediment removal areas by
"staking the new route of the widened stream." This demonstrates
that the EPA is not determining the specific removal areas based
upon any environmental criteria, but is responding to the local
flooding fears using federal funds earmarked for Superfund
cleanups .
VI. Conclusion
In conclusion, NL believes that there is no basis for the
choice of 500 parts per million as the cleanup level for lead-in-
soil at the site. Considering the industrial land use of the
site, the cleanup level for soils should be greater than 1000
ppm. In addition, the experience of the EPA and other companies
with soil washing, an unproven technology with respect to lead
cleanups, clearly demonstrates that it is the wrong choice for
the remedial alternative for soil at the Pedricktown site.
Solidification/stabilization is more cost effective and has
proven to be a more reliable and feasible technology at lead
sites and should be selected as the preferred alternative.
Taking into account the potential adverse impacts of dredging in
a water column, NL recommends proceeding with a conservative
monitoring program before invading the streambed north of Route
130 with dredging equipment. Similarly, NL joins in the comments
of Langan Engineering and Environmental Services, Inc. as to the
uncertainty of the need for groundwater remediation at this time,
and recommends that when and if groundwater remediation is
conducted, the Agency should consider both the streams and the
Delaware River viable discharge options. Finally, we believe
that the Phase V removal action is unwarranted and motivated by
local desires for flood control assistance rather than
environmental protection.
Respectfully submitted,
fanet D. Smith
cc: Susan H.S. Monks, Esq.
-------
€ N V I R O N
•
JUL
July 6, 1993
' D'^irT
Chief, Site Investigations and
Compliance Branch
Emergency and Remedial Response
Division - Room 720
U.S. Environmental Protection Agency ^ C.K. p/J
26 Federal Plaza ~" "" ••• -""•••• . •'
New York, NY 10278
Attention: Michael Gilbert, Project Officer
Re: NSNJ Pedricktown. New Jersey Facility RI/FS
Dear Mr. Gilbert:
We were pleased to receive draft copies of the January Final Report: Field Ecological
Assessment and the Ecological Risk Assessment for the Pedricktown, New Jersey Superfund
Site, and to have the opportunity to discuss, on behalf of NL Industries, our initial comments
on the drafts with you, Dr. Mark Sprenger and Ms. Kim O'Connell at your offices on
March 9, 1993. At the request of NL Industries, ENVIRON prepared the attached report
summarizing the comments made at the meeting as well as a few additional comments that
were developed following a more thorough review of the documents.
We trust that the comments will be of assistance to you in preparing the final reports. If you
have any questions, please contact me at (703) 516-2300.
Very truly yours,
Dan Weltering, Ph.D.
Principal
cc: Paul Harvey, NJDEPE (Three copies)
Dr. Mark Sprenger, U.S. EPA
Evans Stamataky, U.S. EPA
Steve Holt, NL Industries, Inc.
KJM\n\atemr.let
CNVIRON Corporation • Counsel in Health and Environmental Science
4350 North Fairfax Drive. Arlington. Virginia 22203 • (703) 516-2300 • (800) ENVIRON . FAX (703) 516-2345
-------
COMMENTS ON THE USEPA ECOLOGICAL RISK ASSESSMENT
FOR THE NL PEDRICKTOWN SITE
In January, 1993 U.S. Environmental Protection Agency (USEPA), Region n
(Environmental Response Branch, Emergency Response Division, Office of Emergency and
Remedial Response) released two draft documents concerning the assessment of ecological
risk associated with lead contamination at the NL Industries, Inc. (NL) Site, Pedricktown,
New Jersey. The first document, Final Report: Field Ecological Assessment, describes a
series of field investigations to collect empirical data on target receptors and surrogate
organisms to be used in a subsequent ecological risk assessment of lead contamination in the
vicinity of the NL Site. The report presents data on sediment toxicity, aquatic vertebrate
lead levels, earthworm in-situ bioaccumulation of lead, small mammal lead contaminating
and a terrestrial and wetland habitat assessment. The second document, Ecological Risk
Assessment, uses the data presented in the Field Ecological Assessment to assess the risk of
lead contamination at the NL Site to the following species of concern: woodcock, robin,
great blue heron, red-tailed hawk, long-eared owl, red fox, and minlc Of the seven indicator
species considered by the USEPA, four species, woodcock, robin, red fox, and minlc were
concluded to be at risk from lead at all areas assessed.
The purpose of this document is to provide technical comments on the USEPA Field
Ecological Assessment and Ecological Risk Assessment reports. Four areas are covered:
• Field investigation results: soil lead levels;
• Use of field results in the assessment of ecological risk: earthworm and white-
footed mouse lead levels;
• Toxicity thresholds and exposure parameters used in assessing the risk of lead
contamination; and
• Computational errors in the Ecological Risk Assessment.
I. Field Investigation Results: Soil Lead Levels
The XRF data used to determine the soil lead concentrations in the areas selected
for assessing biota lead contamination are of questionable value in a quantitative
assessment of exposures. XRF soil analysis significantly overestimates the lead
concentrations, which, in turn, results in an overestimation of the exposure
estimates for indicator species.
The Ecological Risk Assessment uses XRF analysis data for surface soil lead as an input
into the overall oral exposure level for indicator species. This surface soil lead data is
directly incorporated into the oral dose calculation through the use of an incidental soil
-1- ENVIRON
-------
ingestion rate. The use of the XRF data grossly overestimates the oral exposure via this
route. Figure 1 illustrates the relationship between XRF-determined lead concentrations
and lead concentrations measured by atomic absorption spectroscopy (AA) for the same
soil samples. It is evident that the XRF results overestimate the lead concentration in
soil by a factor as high as 8X. Figure 2 groups XRF data into discrete lead
concentration ranges and shows that the ratio of XRF to AA ratio is at least 2. It
therefore follows that indicator species' oral exposure levels from incidental soil
ingestion should be reduced by a factor of at least 2.
H. The Use of the Field Results in the Assessment of Ecological Risk: Earthworm and
White-Footed Mouse Lead Levels
A. Earthworm Lead Levels
1. There is no apparent relationship between the lead concentrations in the
test chamber soils and those in earthworms.
The Final Repon: Field Ecological Assessment describes an in situ earthworm
bioaccumulation study. Eisenia foetida were used to test for bioaccumulation
of lead over a 28-day period at twenty locations that were selected to
represent a range of target soil concentrations of lead. A sample of worms
from the stock culture served as a time zero lead concentration. However,
no background (i.e., off-site local soil) worm bioaccumulation control was
included in the test. Alter 28 days of exposure, the earthworms were
removed from the test chambers, depurated of gut contents, and analyzed for
lead.
Earthworms exposed to lead contaminated soil for 28 days accumulated lead
to levels ranging from 29 mg/kg to 170 mg/kg. Lead concentrations of
earthworms (dry weight) were not correlated with soil lead levels in the in
situ test chambers (r=0.18, n=20). Similarly, lead concentrations in
earthworms were not correlated with other soil parameters measured: TOC,
grain size, pH, and percent organic matter.
A plot of earthworm lead concentrations expressed as wet weight versus soil
lead concentrations (Figure 3) also supports the conclusion that there is no
discernable relationship. The figure illustrates that earthworm lead
concentrations do not appear to increase with soil lead concentration.
Furthermore, the concentrations of lead in worms associated with the
-2- ENVIRON
-------
10
8
< 6
IL
QC
X
t •
1000 2000 3000
XRF (mg/kg)
4000
Figure 1. Relationship Between XRF and AA Measurements in Soils Less Than 4,000 ppm
-3- ENVIRON
-------
cc
X
0-500 500-1000 1000-2000 2000-4000
XRF Range (mg/kg)
Figure 2. Ratio of XRF to AA in Soils
ENVIRON
-------
.g
a
og
0 *
100
Eo>
|^ 50
a
UJ
1000 2000 3000 4000 5000 6000 7000
Soil Lead Concentration (mg/kg)
Figure 3. Earthworm Lead Concentrations Versus Soil Lead Concentrations
-5-
ENVIRON
-------
contaminated areas cannot be evaluated against background worm lead
concentrations due to the lack of a background control in this experiment.
2. USEPA's division of the observations into groups as <500, 500-1,000,
and > 1,000 mg/kg soil is arbitrary, and the pattern of the group mean
earthworm concentrations is dependent on this division.
The Ecological Risk Assessment arbitrarily groups the results of the
earthworm accumulation study into three ranges of soil lead levels, <500
mg/kg, 500-1,000 mg/kg, and > 1,000 mg/kg with associated mean
earthworm lead levels of 66.3, 80.0, and 85.7 mg/kg (wet weight),
respectively. This suggests some correlation between lead in soil and lead in
earthworms, although the Ecological Assessment states that no statistical
correlation exists between lead in earthworms and lead in soil. In addition,
this grouping results in an uneven distribution of observations (only four are
<500, three between 500 and 1,000, and nine are > 1,000).
An alternative grouping of earthworm data by soil lead levels to maintain
more equal group distribution would be < 1,000 (seven observations), 1,000-
2,000 (four observations), and > 2,000 (five observations). Figure 4 shows
that placing the earthworm observations into a different grouping of lead
concentrations results suggests that no correlation exists between earthworm
lead and soil lead.
B. White-Footed Mouse Lead Levels
1. There are no significant differences among the mean lead concentrations
in mice (dry weight) collected from the various grid areas.
The Final Report: Field Ecological Assessment describes a small mammal
tissue lead study. Small mammal trapping was conducted in three discrete
wooded areas of the site identified during a preliminary site visit. A target
sample size for each wooded area consisted of 10 white-footed mice
(Peromyscus leucopus). The contents of the gastrointestinal tract of each
animal was removed and the whole body was analyzed for lead. XRF
screening for soil lead concentrations was conducted for each area sampled
for small mammals.
Page 29 of the Final Report: Field Ecological Assessment states that there are
no significant differences among the mean lead concentrations in mice form
the different sampling grids, when expressed on a dry weight basis.
2. The pattern of differences in the mean wet weight lead concentration hi
mice is not consistent with the apparent pattern of differences in mean
-6- ENVIRON
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200
160
O O)
0| 120
of
(0
0)
a
LU
80
40
I
<500 500-1000 >1000 <1000 1000-2000 >2000
Soil Concentration (mg/kg)
Figure 4. Influence of Selection of Soil Concentration Intervals on Calculated Mean
Earthworm Concentration
-7-
ENVIRON
-------
soil lead concentration among the areas. Figure 5 presents a side-by-side
comparison of a plot of mean lead concentration in mice (wet weight) vs.
mean soil lead concentration to a plot of the means and standard deviation
bars for soil lead concentration data in each sampling area. Soil lead levels
are lowest in Area n and highest in Area ffi. The mean concentration in
mice on a wet weight basis is lowest in Areas I and IA. This inconsistency
suggests that the lead concentrations of the mice are not strongly related to
the lead concentrations in the soil.
Toxicological and Biological Assumptions Used in the Ecological Risk Assessment
The area use factor is incorrectly applied in the ecological risk assessment. As
described in the assessment (Page 6), "The area use factor is defined as one if the study
area is greater than the home range of a species. If the study area is less than the home
range, a ratio of home range size to the size of the study area will be used." The study
area for the assessment is 200 acres. This application of the area use factor fails to
consider the levels of lead existing within the "study area", so that the entire 200 acres
is assumed to be contaminated at average lead levels between 1000 mg/kg and
2300 mg/kg depending on the exposure scenario being evaluated. This approach applies
elevated lead concentrations to uncontaminated areas and areas of low concentration
within the 200 acre "study area", thereby significantly overstating the ecological risk to
the receptor/indicator species.
A. Woodcock Assumptions
x- available data suggest a toxidty threshold of 8.25 mg/kg/day and a home
^ range of 108 acres for the woodcock.
1 . The USEPA toxlcity threshold is based upon a field study of lead levels in
European starlings (Grue et al. 1986) which showed reductions in hematocrit,
red blood cell ALAD activity, and brain weight of nestlings in a population
estimated by USEPA to be exposed to dietary lead at approximately 4.1
mg/kg/day. Since these data were not included in the work plan commented
on by ENVIRON (Comments on Proposed Toxidty Thresholds and Exposure
Parameters for the NL Pedricktawn Site Ecological Risk Assessment,
submitted by NL Industries, Inc. on November 19, 1992) a review of the
study and USEPA's interpretation was conducted.
Grue et al. (1986) is a field study of lead contamination of soil, invertebrates,
and tissues of European starlings nesting in areas of high vehicular traffic.
The study includes measures of blood ALAD activity, hemoglobin
concentrations, hematocrits, body weights, brain weights, clutch size,
hatching success, and fledgling success for the starling populations. Adult
birds from areas where ingesta contained lead at 84 mg/kg dry weight
-8- ENVIRON
-------
0>
o
.
CO 0)
= *
« »
*
(0
o
10
8
AflM ///
500
1000
1500
2000
2500
Mean Lead Concentration in Soil
(mg/kg)
Figure 5. Plots of Mouse Lead Versus Mean Soil Lead and Mean Soil Lead by Area
-9- ENVIRON
-------
exhibited ALAD activity depressions of 43 to 60 percent when compared to
control populations. However, these adults showed no weight loss, paralysis,
or loss of vision, nor were any reproductive effects noted. Nestlings from
areas where ingesta contained lead at 94 mg/kg dry weight exhibited a 16
percent reduction in hemoglobin concentration, a 10 percent reduction in
hematocrit, and significantly lower brain weights when compared to controls.
It is not clear that any of these reductions would produce ecologically
significant effects. Reduced brain weight in nestlings appears to be the most
sensitive/serious endpoint. USEPA interprets this study as showing adverse
effects in starlings at a concentration of lead in ingesta (wet weight) of 13.3
mg/kg. Because the ingesta lead concentrations in the study are reported on a
dry weight basis, and no water content data for the ingesta samples are
reported, it is unclear how the 13.3 mg/kg wet weight value was obtained.
Further, USEPA derives its dietary effects-threshold using adult food
consumption and adult body weight data even though adverse effects were
reported not for adults but for nestlings. In order to accurately reflect the
fact that the more ecologically significant adverse effects were observed in
nestlings, a daily dietary effect threshold should be based upon food
consumption and body weights for nestling starlings. Grue et al. report a
starling nestling weight of 66.9 g as compared to the USEPA adult weight of
75 g. The ingestion rate for adult starlings reported by USEPA is 31 percent
of body weight per day. A relationship between juvenile and adult bird
consumption rates can be assumed to be such that juveniles consume twice
the food per unit body weight as adults (e.g. juvenile chickens consume food
at a rate of 13 percent of body weight/day, while adult chickens consume 6
percent of body weight/day [Fraser and Mayes 1986]). On the basis of this
relationship, the juvenile starling food consumption rate would be 62 percent
of the body weight per day, or 41.5 g/day. Allowing for the validity of the
13.3 mg/kg wet weight ingesta threshold for adverse effects in nestling
starlings, the daily dietary threshold for nestling starlings would be 8.25
mg/kg/day (13.3 mg/kg X 0.0415 kg/day X 1/0.0669 kg bw = 8.25
mg/kg/day) instead of the 4.1 mg/kg/day assumed by USEPA.
2. Hie Ecological Risk Assessment lists the home range of a woodcock as being
45 acres, citing the work of Wilson (1982). This home range size does not
accurately reflect the data in Wilson (1982) which lists the average home
range to be 44 ha (not 45 acres) or equivalent to 108 acres.
B. Robin Assumptions
The alternative toricity threshold value of 8.25 mg/kg/day discussed above also
applies to the robin.
-10- ENVIRON
-------
C. Red Fox Assumptions
The available data suggest a toxicity threshold of 2.5 mg/kg/day, and a
territory size of 698 ha. for the red fox.
1. In the Ecological Risk Assessment, USEPA cites Demayo et al. (1982) as the
source for the toxicity threshold for dogs (surrogate for the red fox) of 0.32
mg/kg/day. Demayo et al. (1982) is a secondary source that cites Hatch
(1977) as the source of the 0.32 mg/kg/day. Hatch (1977) is also a
secondary source that cites Zook (1973) as the source of the 0.32 mg/kg/day.
Zook (1973) is also a secondary source that cites the original source of the
0.32 mg/kg/day (Firmer and Calvery 1939). The Firmer and Calvery study
involved the feeding of lead to only 29 dogs. Of the 29 dogs used in the
study, only data for five dogs are reported. Data for the other 24 animals is
not available. Of the subjects reported, three received an estimated dietary
dose of lead (as lead acetate) of 1.5 mg/kg/day. One of these dogs died at
day 43 of exposure,a second died following 121 days of exposure (interrupted
by an interim period for treatment for convulsions), and the third dog
suffered paralysis by day 14 yet survived until sacrifice (time of sacrifice
unreported, but over 228 days after initial exposure). The two other dogs
reported were exposed to an estimated 0.33 mg/kg/day lead in the diet.
These two dogs died after 140 and 167 days of exposure, with no interim
signs of intoxication. No data on food consumption for the five reported
subjects is available, thus the dietary dose estimates cannot be confirmed. In
addition, the absence of data on the other 24 dogs in this study prevents
validation of the authors' statement that the five cases reported were typical
of results for all dogs. This study is not well designed nor are the results
documented sufficiently to form the basis of a toxicity threshold.
The 0.32 mg/kg/day toxicity endpoint adopted by USEPA is almost an order
of magnitude below the endpoints reported for the 1973 multi-dose, multi-
subject, controlled dog study deemed acceptable for inclusion in the ATSDR
lexicological Profile for Lead (ATSDR 1990). The most sensitive endpoints
listed in the ATSDR document for lead effects in dogs were a no observed
adverse effect level (NOAEL) of 1.25 mg/kg/day for heme synthesis and a
lowest observed adverse effect level (LOAEL) of 2.5 mg/kg/day for
inhibition of ALAD activity. The citation for the ATSDR endpoints was
Azar et al. (1973) which was a two-year chronic study of lead acetate
administered in the diet. For comparison with the mortality/paralysis results
reported in Firmer and Calvery (1939), the two-year dietary study (Azar et al.
1973), showed no significant effects on appearance, behavior, weight gain,
mortality, or neurology even at doses as high as 12.5 mg/kg/day over the
two-year study period. The toxicity endpoints presented in ATSDR (1990)
agree with a study contemporary to Firmer and Calvery (1939) and also cited
-11- ENVIRON
-------
in Zook (1973). This study showed no signs of toxicity in dogs dosed with
lead at 1.0 mg/kg/day for six months (Horwitt and Cowgill 1939). Since a
contemporary study (Horwitt and Cowgill 1939) and a multiple subject,
controlled study of considerably longer duration (Azar et al. 1973) both
disagree with the findings of Finner and Calvery's reported study results, the
weight of evidence suggests that the 0.32 mg/kg/day endpoint is not a valid
lower limit of effects for dogs. A more appropriate toxicity threshold would
be the LOAEL of 2.5 mg/kg/day cited in the peer-reviewed ATSDR (1990)
discussion of Azar et al. (1973).
2. In the Ecological Risk Assessment, USEPA uses a home range size of
57.5 ha, which is the smallest home range reported in the literature.
ENVIRON recommended in the report submitted on November, 1992 to the
Agency that the average red-fox home range should be 698 ha on the basis of
procedures used by the Agency for an ecological risk assessment for Burnt
Fly Bog, in which USEPA used the average of available home range values.
D. Mink Assumptions
There is strong reason to question the validity of the USEPA toxicity threshold
for mink. In addition, an alternative value for the territory size of the species
is suggested.
1. USEPA bases its toxicity threshold of 2 mg/kg/day on field study data for
otters (Mason and MacDonald 1986). In the November, 1992 ENVIRON
discussion of alternative toxicity values, the Mason and MacDonald study was
reviewed and no clear correlation between lead intake (as measured by lead in
feces) and adverse population effects could be established. USEPA maintains
in its Ecological Risk Assessment (page 16) that the Mason and MacDonald
study shows otter populations were reduced in areas where estimated lead
intake exceeded 2 mg/kg/day.
A Revaluation of the Mason and MacDonald study has been performed. It
must be noted that the study was not designed to establish a statistical
relationship between fecal lead levels and otter population success. There
was no effort made to control for any site-related parameters that may
contribute to poor performance of otter populations. Decreases in
populations can not be reliably attributed to the effects of any one
contaminant. It must further be noted that other potentially toxic metals were
found in the otter feces, further confounding any attempt to attribute
causation to lead exposure. Because there are no quantitative measures
presented for defining population health, no dose response relationship can be
made and no quantitative ranking of population health can be made. At best,
the only possible comparison could be a qualitative correlation.
-12- ENVIRON
-------
In a search for such a correlation the population status ("healthy" or
"declining") was compared to a ranking of the mean fecal lead levels. Three
populations of otters were identified in the study as being in a state of
decline, Brue, Frome, and Teme. These populations ranked 1 (Bnie), 10
(Frome) and 11 (Teme), out of 13 populations studied, on the basis of mean
fecal lead level. There are 8 healthy, non-declining otter populations with
fecal lead concentrations higher than the mean for the Frome and Teme
populations. Further, the fecal lead concentration in the declining Brue
population is not statistically different from the next three highest fecal lead
concentrations for healthy populations. Therefore, no correlation can be
demonstrated between fecal lead and otter population performance. The
study authors support such a conclusion with the statement that "at the
majority of localities from where faecal samples were taken, otter populations
are thriving, while at three areas where otters have declined steeply and
populations may be endangered (Brue, Frome, and Teme), metal
concentrations in the faeces are not exceptionally high.*
Because USEPA used the fecal data to calculate dietary intake of lead for the
otter populations in the Mason and MacDonald study, and it is assumed that
the dietary intake-to fecal lead relationship was constant for all populations,
the lack of a correlation between fecal lead and population effects makes the
calculation of a dietary LOAEL for this study unrealistic. The Mason and
MacDonald study should not be used to establish a toxicity threshold for
fninlc
2. USEPA's exposure assessment for mink at the NL Site includes the
consumption (50% of the diet) of an upland small mammal, the white-footed
mouse. If the consumption of upland organisms is to be considered for the
mink, it appears inappropriate to limit the home range estimation to the
length of an aquatic habitat. ENVIRON, in the November, 1992 report
submitted to the Agency, presented a list of home range data for the mink
that included area determinations in addition to the stream length data used by
USEPA. ENVIRON suggests the use of an average female home range
expressed in terms of acres (not linear feet). This average home range value,
476 acres based on the available data, is a more reasonable estimate of home
range for the NL Site.
Additionally, no comparison has been made of the quality of the aquatic
habitat available to mink in the East and West Streams versus the quality of
the habitat in the Sweden surface waters on which the literature estimates of
stream length territory were made. Differences in the habitat quality for
mink would affect the validity of using the literature estimate. This further
supports the recommendation to use an average reported territory size.
-13- ENVIRON
-------
IV. Computational Errors In the Ecological Risk Assessment
The Ecological Risk Assessment incorrectly calculates the hazard quotient for red fox
for daily intake scenario 1 for Areas I/IA and ffi. The hazard quotient for Area I/IA is
listed as 10.06 in Table 8, where the actual ratio of daily intake to LOAEL is 6.06.
The hazard quotient for Area m is listed as 14.13, where the actual ratio of daily intake
to LOAEL is 8.66.
Page 10 of the Ecological Risk Assessment states that invertebrates comprise 43 percent
of the diet of robins, with 57 percent comprised of fruits and vegetation. Table 3 in
Appendix B provides an exposure calculation based upon worms being 100 percent of
the diet. This inconsistency results in a hazard quotient that is roughly twice what it
should be.
Agency for Toxic Substances Disease Registry (ATSDR). 1990. Toxicological Profile for
Lead. Agency for Toxic Substances Disease Registry, U.S. Public Health Service,
ATSDR/TP-88/17, NTIS# PB90-267378.
Azar, A., HJ. Trochimowicz, M.E. Maxfield. 1973. Review of lead studies in animals
carried out at Haskell Laboratory - Two-year feeding study and response to hemorrhage
study. In: Earth, D., A. Berlin, R Engel, P. Recht, J. Smeets (eds.). Environmental
health Aspects of Lead: Proceedings, International Symposium, October 1972,
Amsterdam, The Netherlands. Commission of the European Communities,
Luxembourg, pp. 199-210.
Demayo, A., M.C. Taylor, K.W. Taylor, P.V. Hodson. 1982. Toxic effects of lead and
lead compounds on human health, aquatic life, wildlife, plants, and livestock. CRC
Crit. Rev. Environ. Control 12:257-305.
Finner, L.L. and H.O. Calvery. 1939. Pathologic changes in rats and in dogs fed diets
containing lead and arsenic compounds. Arch. Pathol 27:433-446.
Fraser, C.M. and A. Mays (eds.). 1986. The Merck Veterinary Manual, sixth edition.
Merck and Company, Inc., Rahway, NJ, p. 1194.
Grue, C.E., D.J. Hoffman, W.N. Beyer, L.P. Franson. 1986. Lead concentrations and
reproductive success in European starlings Sturnus vulgaris nesting within highway
roadside verges. Environ. Pottut. (Series A) 42:157-182.
Hatch, R.C. 1977. Poisons causing nervous stimulation or depression. In: Jones, L.M.,
N.H. Booth, L.E McDonald (eds.). Veterinary Pharmacology and Therapeutics, 4th
edition, Iowa State University Press, Ames, pp. 1185-1242.
-14- ENVIRON
-------
Horwitt, M.K. and G.R. Cowgill. 1939. J. Pharmacol Expil. Therap. 66:289, as cited in
Zook 1973.
Mason, C.F. and S.M. MacDonald. 1986. Levels of cadmium, mercury and lead in otter
and mink faeces from the United Kingdom. The Science of the Total Environment 53:
139-146.
Wilson, H.J. 1982. movements, home ranges, and habitat use of wintering woodcock in
Ireland. In: Dwyer, TJ. and G.L. Storm (technical coordinators). Woodcock Ecology
and Management; papers from the Seventh Woodcock Symposium held at the
Pennsylvania State University, University Park, Pennsylvania, 28-30 October, 1980.
U.S. Fish and Wildlife Service, Wildlife Research Report 14, Washington, DC.
Zook, B.C. 1973. Lead intoxication in urban dogs. Clin. Toxicol. 6:377.
-15- ENVIRON
-------
r
CJEREEMBGERE
1 July 1992
Mr. Michael Gilbert
U.S. Environmental Protection Agency
Emergency and Remedial Response Division
26 Federal Plaza, Room 720
New York, New York 10278
File: 2844.014
Re: Pedricktown, New Jersey
Superfund Site
Dear Mr. Gilbert:
This letter is submitted in response to your request that NL
Industries, Inc. expound upon the rationale for selecting a
remedial response alternative for surface water and sediments based
upon ambient water quality criteria for lead at the National
Smelting of New Jersey/NL Industries, Inc. Superfund site (the
"Site") as set forth in the February 1992 Interim Feasibility Study
(FS) for the Site. We are grateful that you afforded us this
opportunity.
1. The Feasibility Study Recommends a Remedial Response for
Stream Sediments That Will Achieve Ambient Water Quality
Criteria With Minimal Adverse Environmental Impacts
To recap, the FS sets forth as remedial objectives for surface
water the ambient water quality criteria for lead. We selected
ambient water quality criteria as remedial response objectives
because they are established benchmarks for protection of the
aquatic environment, promulgated by the USEPA and also are readily
measurable. The FS depicts areas where surface water quality is
most adversely affected by the Site: in the West Stream south of
U.S. Route 130, and in the East Stream south /of the railroad
tracks. Attachment 1 compares surface water, quality to acute
ambient water quality criteria for lead; examination of Attachment
1 shows where the acute ambient water quality criteria are
exceeded. As is apparent from Attachment 1, lead concentrations in
downstream segments of the West and East Streams are significantly
below acute ambient water quality criteria and thus, these segments
were not targeted for remediation.
O'Brien & Gere Enoineers. Inc.. an O'Brien & Gere Limited Company
440 Vikinc Dr. / Suite 250 / Virginia Beach. VA 23452 / (804) 431-2956 FAX (804) 431-9006
... and offices in rmjor U.S. cities.
-------
Mr. Michael Gilbert
1 July 1992
Page Two
Surface Water Remedial Alternative B proposes remediation of
sediments in all of the stream segments where acute ambient water
quality criteria for lead are exceeded. These stream segments are
illustrated on Attachment 2. Surface Water Remedial Alternative B
would result in the cleanup of fifty-one hundred linear feet of
stream sediments with a proposed depth of excavation of two feet,
as illustrated on Attachment 3. These proposed portions of the
East and West Streams are readily amenable to dewatering or re-
direction. This makes it possible to excavate with precision in
three dimensions, and to minimize the possibility of redistribution
and resuspension of lead-bearing sediments. We believe that
Surface Water Remedial Alternative B will achieve the dual goals of
cleaning up the most lead-bearing stream sediments and minimizing
the adverse impacts to the downstream aquatic biota.
We recognize that the current draft FS does not present a
monitoring approach for assuring the achievement of acute and
chronic ambient water quality criteria for lead. However, Surface
Water Alternative B could easily be modified to include a surface
water monitoring program. This program could include quarterly
sampling of the East and West Streams and analysis for lead,
hardness and any other necessary parameters. If the Agency
recommends the addition of a surface water monitoring program to
insure the continued protection of the fresh water aquatic
environment, we are prepared to develop such a program for
inclusion in the FS.
2. Dredging North of U.S. Route 130 Is Unwarranted
and Could Have Adverse Environmental Impacts
There are stream segments downstream from the areas we have
proposed for remediation that, at the present time, exceed chronic
ambient water quality criteria for lead. We predict that the water
quality of these downstream segments will improve as remedial work
at the Site progresses for several reasons. First, removal of the
upstream sediments where higher levels of lead are currently found
will remove some of the source of the downstream exceedances of
chronic ambient water quality criteria. Moreover, as work
progresses on the Operable Unit 2 surface cleanup of the Site, such
as the removal of lead-bearing slag and waste piles and pooled
surface water, other sources now contributing to the presence of
lead downstream will be eliminated. These remedial efforts should
contribute to the improvement of downstream surface water quality,
with the objective of meeting AWQC acute and chronic in these
stream segments and with minimal impact on downstream biota during
remediation.
Q'BRIEIM S GERE
-------
Mr. Michael Gilbert
1 July 1992
Page Three
We believe that the excavation of the stream segments north of
U.S. Route 130 is unwarranted and would be detrimental to the
aquatic environment. These stream segments are too large to be
diverted or dewatered and thus, remediation would have to consist
of dredging in a water column. Sediment resuspension and
redistribution during the dredging is likely to result in
downstream transport of entrained sediments. Further, dredging
these stream sediments could be destructive to the existing
ecosystem, increasing turbidity and adversely impacting the
existing benthic flora and fauna.
3. The Single Sediment Cleanup Standard Suggested By DSEPA,
Reportedly Derived from a NOAA Document, Is Inappropriate
for Use as a Cleanup Standard According to NOAA
We have previously discussed with you whether it is
appropriate to establish a single numerical concentration standard
to govern the cleanup of stream sediments at the Site. You have
referred to a report published by the National Oceanographic and
Atmospheric Agency entitled "The Potential for Biological Effects
of Sediment-Sorbed Contaminants Tested in the National Status and
Trends Program", Long & Morgan, 1990 (hereinafter, the "NOAA
report") as a possible source for the establishment of such a
standard. The NOAA report refers to two levels of concentrations,
the Effects Range Low (ERL) and Effects Range Medium (ERM)
concentrations. We continue to believe that establishing a cleanup
standard for stream sediments with reliance on either of these
numbers is inadvisable, and without scientific basis, for several
reasons.
The FS states that no toxicity-based criteria or standards are
available for cleaning up lead in stream sediments. We reached
this conclusion after careful evaluation of the scientific
literature and, in particular, an examination of the NOAA report to
which you referred. In fact, the NOAA report plainly states:
"[t]hese guidelines were not intended for use in regulatory
decisions or any other similar applications." NOAA report at p.l.
Because we understood this issue to be one of interest to you,
we consulted directly with one of the authors of the NOAA report.
Edward R. Long, co-author of the document, confirmed in a telephone
conversation, that the ERLs and ERMs presented in the NOAA report
were not intended to be used as standards or criteria for the
cleanup of sediments. Mr. Long stated that the caveats against
such use set forth in the NOAA report continue to apply.
Because we knew that you wanted to encourage further
discussion on this issue, we asked Dr. James Rhea of O'Brien &
Gere, who has expertise in the area of sediment chemistry, to
O'BRIEN S GERE
-------
Mr. Michael Gilbert
1 July 1992
Page Four
comment on the extrapolation of cleanup standards from the NOAA
report. Dr. Rhea concludes that such use of the ERL and ERM values
presented in the NOAA report is inappropriate for several reasons:
i. the ERM and ERL values fail to take into
account the differences in bioavailability of
contaminants in different sediments with
widely divergent chemical and physical
characteristics;
ii. the ERM and ERL values do not identify any
cause and effect relationships between
chemical and biological effect, (i.e.. the
values assume that chemicals quantified in
studies are responsible for observed
biological effects); and
iii. the article relies heavily on data that lacks
independent validation.
Dr. Rhea has written a critique regarding the employment of ERL and
ERM values as cleanup criteria for lead at this Site, attached
hereto as Attachment 4.
Some of Dr. Rhea's comments are echoed by Mr. Long in a recent
publication entitled "Ranges in Chemical Concentrations in
Sediments Associated with Adverse Biological Effects", Marine
Pollution Bulletin. Vol. 24, No. 1, 1992. Therein, he summarizes
the deviations in the NOAA ERLs and ERMs stating:
The ranges in concentrations may represent fortuitous
flukes, since the variables that control bioavailability
of sediment toxicants were not accounted for and
differences in analytical methods, biological tests,
sediment regimes, etc., occurred among the studies. . .
In addition, data derived in fresh water, estuarine, and
marine studies were treated equally, despite, the
possibility that bioavailability may differ remarkably
between the two regimes.
Marine Pollution Bulletin. Vol. 24 at p. 43.
Mr. Long concluded that the evaluation of a hodgepodge of data
in the NOAA report, collected from different approaches,
laboratories and techniques, was analogous to comparing "grapes and
watermelons". He viewed this type of comparison as "symptomatic of
the current status of knowledge regarding the degree of sediment
contamination that is associated with measures of biological
effects" and advocated the development of techniques beyond those
that are currently available.
O'BRIEN & GERE
-------
Mr. Michael Gilbert
1 July 1992
Page Five
4. If the Agency Still Has Reservations About Surface
Water Remedial Alternative B, We Recommend the Performance
of a Benthic Study and the Consideration of Factors
Affecting Bioavailabilitv
Because of the drawbacks of dredging stream segments, any
decision to expand the proposed remediation of stream sediments
should be based upon consideration of whether the benthic community
has been adversely affected by the Site. A suitable study would
compare community parameters such as species diversity, taxa
dominance, species abundance, and spatial distribution in a control
area unaffected by the Site to similar parameters in the
potentially impacted stream sediments. Remedial decisions could
then be based on statistically supported Qifferences, if any, in
the benthic community parameters. The benefit of such a study is
that the adverse impacts of dredging would not be risked without
prior demonstration of an adverse impact of the discharges from the
Site upon the receptor ecosystem.
We also recommend the collection and analysis of data to allow
the evaluation of bioavailability of lead in the stream sediments.
Such data to be collected would include sediment type and
properties, including organic matter content and acid volatile
sulfide concentration, pH, salinity, and oxidation-reduction
potential.
5. Conclusion
As you discussed with Stephen Holt, we look forward to meeting
with the Agency personnel to discuss this matter further. We
envision a technical discussion with input from NL's
ecotoxicologist, as well as other engineers and scientists. Please
call Mr. Holt at (609) 443-2405 at your earliest convenience to
discuss dates for this meeting.
Very Truly Yours,
OABRIEN & GERE ENGINEERS, INC.
ames M. O'Loughlin, Pr
Senior Project Engineer
JMO:SWH:bg
Attachment
Mr. Michael Gilbert, USEPA, Original + 5 copies
Mr. Paul Harvey, NJDEPE, 6 copies
Mr. Stephen W. Holt, 1 copy
03R1EN £ GERE
-------
bcc: R. Machado
R. Oslan
J. Rhea
J. Schlesinger
J. Smith, Esq.
C. Pal, Esq.
O'SRIEN £ GERE
-------
DELAWARE RIVER
NSNJ INC/NL SITE
1990 SURFACE WATER SAMPLES
LEAD CONCENTRATION/AWQC-ACUTE
•DEPEND:
o EPA 1990 SAMPLE LOCATIONS
OT~) LEAD CONCENTRATION/AWqC-ACUTE-1990 DATA
; 6X LEAD CONCENTRATION/AWQC-ACUTB 1989 DATA
(1090 DATA NOT AVAILADLE)
a..
re J
.1
30
-------
ATTACHMENT 2
(derived from draft FS Figure 32)
N5NJ INC/NL SITE
SEDIMENT CLEANUP PLAN
LSGEKD:
PROPOSED STREAM DIVERSION
_^. 7— CURRENT STREAM LOCATION
-------
NSNJ INC/NL SITE
VERTICAL EXTENT OF LEAD IN STREAM SEDIMENT
(EAST STREAM)
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-------
OBRIEN E GERE Memorandum
Attachment 4
Jim O'Loughlin . 1 July 1992
From:Jim RhM File: 2844'°14
Site Copies: K- Farmer
E-Michalcnko
NL INDUSTRIES INC.
PEDRICKTOWN, NEW JERSEY
CRmCAL REVIEW OF THE APPLICATION OF NOAA EFFECTS RANGE VALUES TO
ESTABLISH LEAD CLEAN-UP LEVELS IN AQUATIC SEDIMENTS
BACKGROUND
The National Oceanic and Atmospheric Administration (NOAA) annually samples and chemically
analyzes marine and estuarine sediments from approximately 200 sites throughout the United
States. This sampling and analysis effort is conducted as part of the National Status and Trends
(NS&T) program and includes the analysis of sediments for trace metals, petroleum hydrocarbons,
and synthetic organic compounds. The principal objective of the NS&T program is to characterize
the chemical conditions at the sites and to establish temporal trends in pollutant levels1'2. The
effects of chemical concentrations on the native biological community has not been measured at the
majority of the sites in the NS&T program.
In an attempt to prioritize the sites within the NS&T program for intensive regional surveys, NOAA
developed guidelines for evaluating the potential for chemically induced biological effects of
contaminated sediments3. The overall approach consisted of:
• assembling and reviewing the technical literature for information in which adverse
biological effects of sediment contaminants were calculated, measured, or could be derived,
1 National Oceanic and Atmospheric Administration. 1987. National Status &. Trends Program
for marine environmental minlitv. Progress report and preliminary assessment of findings of the
henthic!surveillance proiect-19R4. Rockville, MD. Office of Oceanography and Marine Assessment.
2 National Oceanic and Atmospheric Administration. 1988. Progress Report. A summary of
selected data on chemical contamination in sediments collected during 1984. 1985. 19R6. and 19S7.
NOAH Technical Memorandum NOS OMA 44. Rockville, MD
s National Oceanic and Atmospheric Administration. 1990. The notenti:il for biological effects
of sediment-sorbed contaminants tested in the National Status and Trends Program. Technical
Memorandum NOS OMA 52. Office of Ocean and Marine Assessment. Rockville, MD.
-------
Attachment 4
Memo
1 July 1992
P.ige Two
• determine ranges of concentrations in which biological effects were likely to occur, and
• evaluate chemical data from the NS&T program sites with respect to established
concentrations ranges estimated to produce biological effects.
The technical literature reviewed included reports which documented controlled laboratory studies
of biological effects of sediments containing individual compounds, calculations of sediment quality
criteria based upon equilibrium partitioning concepts, and Held studies in which simultaneous
measurements of chemical concentration and biological effects were measured.
Specific chemical concentrations observed or predicted to posse an adverse biological effect were
sorted and an apparent effects threshold, lower 10 percentile concentration, and median
concentrations were identified for a number of chemicals. The lower 10 percentile concentrations
were identified as the Effects Range-Low (ER-L) values and the median concentration in the sorted
list were identified as the Effects Range-Median (ER-M) values.
NOAA explicitly states that the ER-L and ER-M were not intended to be used as NOAA standards
or criteria, but were simply developed as a means of assessing the NS&T data.
A number of different approaches for establishing effects based sediment quality values were
employed for the analytes in the NS&T program. These different approaches included:
•background approach (BA),
• sediment/water equilibrium partitioning approach (EP),
• spiked sediment bioassay approach (SSB),
•screening level concentration approach (SLC),
• apparent effects threshold approach (AET), and
•biocffects/contaminnnt co-occurrence analyses approach (COA).
The approach employed by NOAA in establishing ER-L and ER-M values assumes that data from
several sediment quality criteria approaches would establish patterns between chemical
concentrations and biological effects and would, therefore, be a more robust measurement of
biological effects than numbers derived from a single approach.
HR-T. AND F.R-M FOR TP.AD
An ER-L and ER-M for lead were established from 47 observed or calculated biological effects
values from a number of sites. These values were established from the following approaches:
O'BRIEN & GERE
-------
Attachment 4
Memo
1 July 1992
Page Three
\ APPROACH '
.W'^f -»,;<;*
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7
2
38
47
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14
5
81
100
*
The technical merit of the NOAA technique for establishing the ER-L and ER-M values lies in the
integration of multiple approaches to establish biological effects-based sediment chemical
concentration values. However, the technical literature for Jead is limited to three approaches:
AET, EP, and COA. Of these, the COA approach accounts for 81 percent of the database.
Therefore, the ER-L and ER-M values derived for lead are biased toward values predicted from
the COA approach. The COA approach includes a number of inherent assumptions regarding co-
measurement of biological effects and chemical concentrations which limits its application in
chemically complex environmental settings. Finally, the database for lead does not contain a single
reference for an SSB derived biological effects level. An SSB value could be used to verify values
obtained by other approaches.
COA APPROACH-
The bioeffects/contaminant
field collected data for both
includes the calculation of
associated biological effects
significant to note that, the
establish ER-L and ER-M
thresholds. . •
co-occurrence analysis or COA approach involves the application of
chemical concentration and observed biological effects. The approach
the centrality of the chemical data (e.g. means, medians, etc.) with
observations (high, intermediate, and low indications of effects). It is
data used to calculate the COA effects values ultimately employed to
values were collected for purposes other than determining effects
The principal concerns with the COA approach of establishing sediment quality criteria are:
•its inability to describe cause and effect relationships,
•its lack of independent validation, and
•its inability to describe differences in bioavailability of chemicals in different sediments.
O'BRIEN a GERE
-------
Attachment 4
Memo
1 July 1992
Page Four
The first concern regarding the COA approach originates from the inherent assumption that the
chemicals quantified in the studies include those responsible for the observed biological effects.
Chemicals not included in the analytical program for a given site may have been acting singly or
synergistically with other chemicals to induce the observed effect.
The second concern is important because the COA approach assumes that the effects of the
chemical compounds in question have an adverse effect in excess of that caused by the natural
ecological stress inducing factors at the site. An independent validation of the COA observations
such as an SSB conducted with suitable controls is desirable to filter out the effects of natural
physicochemical stresses at the site.
•»
The third concern is important because of the heterogeneity of aquatic sediment systems and the
variability in factors controlling bioavailability and consequently biological effects. The
bioavailability of chemicals in sediments are controlled by a number of factors including: sediment
organic matter content, redox potential, pH, and in the case of trace metals, the presence of
precipitant such as carbonate and sulfides. Sulfide concentrations are particularly important in
controlling the bioavailability of trace metals in anoxic environments.4
SUMMARY
The ER-L and ER-M values were developed by NOAA solely for the purpose of assessing the
NS&T data. NOAA explicitly states that these values should not be applied as sediment clennup
or quality criteria. Furthermore, the ER-L and ER-M values derived for lead are based primarily
on the COA approach for establishing biological induced effects of chemicals. This approach has
a number of technical limitations with regards to establishing cleanup level for sediments.
The ER-L and ER-M values derived from the NOAA database should not used as a basis for
establishing sediment cleanup goals at the Pedricktown, New Jersey site.
* DiToro, D.M., and others. 1990. Toxicitv of cadmium sediments: the role of Acid Volatile
sulfide environmental toxicology and chemistry 9:1487-1502.
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THOMPSON ASSOCIATES
U.S.Rootel30,Borl56A
Pedriclctown, N.J. 08067
September 16,1993
Mr. Stephen W. Holt
CORPORATE ENVIRONMENTAL SERVICES
NL INDUSTRIES, INC
P.O. Box 1090
Wykofl&MiORoad
Hjghtttown, N.J. 088520
Re: Access for NL Pipeline to Dehrowe River
DearMr.HoIl:
This letter wiD confirm our discussion regarding your request for authorization for a pipeline
easement on our property. We understand that the Fedricktown Site Group ("HSG"X * group of
companies identified by the U.S-E-P.A. as potentially responsible parties for Che Pedrickiown She,
is seeking to acquire the necessary easements to allow PSG to construct and operate a water
discharge pipette between the former NL Industries, Inc. Site in Pedricklown, N.J. and the
Delaware Rrver. The pipeline is planned to be constructed as part of the remediation activities
directed by the U.S.E J*. A. at the NL Industries Supcrfund Site. We understand that an easement
for this pipeline requires the consent and cooperation of Thompson Associates, since our piupeny
fics between the former NL Site and the Delaware River.
We acknowledge that you have discussed the proposed pipeline casement with us and have
given us preliminary information including a site sketch showing the proposed path. Based upon
thia preliminary information, we have no objection to entering into negotiation for the granting of
such an easement
Sincerely youn,
THOMPSON ASSOCIATES
pA,SJulton
Partner
HAS Ape
cc:Mike Testa, BASILE, TESTA A TESTA
file
SEP 17 '93 14:48 > ^09 299 52BS PAGE.002
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08/17/93 1B.23 tS-BOS 299 8431
SFG PEDRICKTOTN
Q 001/001
P.O. Box 400
Rte. 130 & Porcupine Rd.
Pedricktown, New Jersey 08067
609-299-5400
Mr. Stephen V. Holt ; I
Corporate Environmental Services
NI Industries, Inc. ! !
P.O. Box 1090 i
Wykoffs Hill Road ;
Hightstown, New Jersey 08520 • •
Re: Easement for Treated Effluent Pipeline To the Delaware River
Dear Mr. Holt:
This letter is to confirm the discussions. you haVi with our Mr. 'Jim Kiel,
Manager of Environmental Affairs, for The Geon Company Pedricktown
Facility on September 9, 1993 regarding your request for an easement for a
treated effluent pipeline on property owned by The Geon Company. As per
the Superfund Proposed Plan for NL Industries, Inc. Operable Unit One
Pedricktown, Salem County, New Jersey dated July 1993, it is anticipated
that the Pedricktown Site Group (PSG), a group of companies identified by*
the U.S. EPA as potentially responsible parties for the NL Industries Inc.
Pedricktown site, will seek to acquire the necessary easements to Allow
the PSG to construct and operate a treated effluent discharge pipeline
from the former ML Industries, Inc. Site, Pedricktown, New Jersey to the
Delaware River. This pipeline would be constructed as part of the
remediation activities directed by the U.S. EPA at the NL Industries
Superfund Site. The Geon Company recognize that such a pipeline would
require the consent and cooperation of any property owner between the NL
Site and the Delaware River plus all the appropriate environmental and
construction permits.
The proposed pipeline easement path is tentatively adjacent to The Geon
Company property Block #39 Lot #19 and through Block 39 Lot 116 as per the
attached NSNJ INC/NL SITE drawing. Based on this preliminary information
and subject to a mutually acceptable agreement between the involved
parties, The Geon Company hereby expresses its intent to actively discuss
with the intent to grant such an easement to PSG.
Please contact Mr. Jim Kiel to initiate formal discussions regarding the
proposed pipeline easement.
Sincerely,
William Fultz
Pedricktown Plant Manager
The Geon Company
cc. Jim Kiel
Jim Lewis
KL
SEP 17 '93 16:25
BBS S99 8431 PflGE.001
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