Ecological Research Series
CHRONIC TOXICITY  OF  METHOXYCHLOR,
     MALATHION, AND  CARBOFURAN TO
                 SHEEPSHEAD  MINNOWS
                 (Cyprinodon variegatus)
                        Environmental Research Laboratory
                       Office of Research and Development
                       U.S. Environmental Protection Agency
                            Gulf Breeze, Florida 32561

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination  of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.  Environmental  Health Effects Research
      2.  Environmental  Protection Technology
      3.  Ecological Research
      4.  Environmental  Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency  Energy-Environment Research and Development
      8.  "Special" Reports
      9.  Miscellaneous Reports

This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on  the effects of pollution on humans, plant and animal spe-
cies, and materials. Problems are assessed  for their long- and short-term influ-
ences. Investigations include formation, transport, and pathway studies to deter-
mine the fate of pollutants and their effects. This work provides the technical basis
for setting standards to minimize undesirable changes in living organisms in the
aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia  22161.

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    CHRONIC TOXICITY OF METHOXYCHLOR, MALATHION, AND
CARBOFURAN TO SHEEPSHEAD MINNOWS  (Cyprinodon variegatus)
                          by
Patrick R. Parrish, Elizabeth E. Dyar, Mark A. Lindberg,
          Chiara M. Shanika, and Joanna M. Enos
                    EG&G, Bionomics
               Marine Research Laboratory
                Pensacola, Florida  32507
                Contract No. 68-03-0264
                    Project Officer

                    David J. Hansen
           Environmental Research Laboratory
              Gulf Breeze, Florida  32561
           ENVIRONMENTAL RESEARCH LABORATORY
          OFFICE OF RESEARCH AND DEVELOPMENT
         U. S. ENVIRONMENTAL PROTECTION AGENCY
              GULF BREEZE, FLORIDA  32561

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                          DISCLAIMER
     This report has been reviewed by the Gulf Breeze Environmen-
tal Research Laboratory,  U.  S.  Environmental Protection Agency,
and approved for publication.   Approval does not signify that the
contents necessarily reflect the views and policies of the U. S.
Environmental Protection  Agency, nor does mention of trade names
or commercial products constitute endorsement or recommendation
for use.

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                                  FOREWAKD

     The protection of our estuarine and coastal areas from damage caused
by toxic organic pollutants requires that regulations restricting the
introduction of these compounds into the environment be formulated on a
sound scientific basis.  Accurate information describing dose-response
relationships for organisms and ecosystems under varying conditions is
required.  The Environmental Research Laboratory, Gulf Breeze, contributes
to this information through research programs aimed at determining:

     the effects of toxic organic pollutants on individual species and
     communities or organisms;

     the effects of toxic organics on ecosystem processes and components;

     the significance of chemical carcinogens in the estuarine and marine
     environments.

     This report describes effects of three insecticides in partial life-
cycle tests with an estuarine fish, the sheepshead minnow.  The data will
be useful in establishing estuarine water quality criteria, and limiting
effluents containing carbofuran, malathion, or methoxychlor.
                                 Thomas W. Duke
                                 Director
                                 Environmental Research Laboratory
                                     iii

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                            ABSTRACT
     Sheepshead minnows (Cyprinodon variegatus) were exposed to
each of three pesticides—methoxychlor, malathion, and carbofu-
ran—in flowing seawater to determine the acute and chronic  (par-
tial life-cycle) effects.   The calculated 96-hour LCSO's and 95%
confidence limits, based on measured concentrations, were:
methoxychlor, 49 micrograms per liter  (yg/£), 37-65 yg/£; mala-
thion, 51 yg/£, 41-63 yg/£; and carbofuran, 386 yg/fc, 311-480
ygA.

     Mortality of adult sheepshead minnows exposed to mean mea-
sured concentrations of methoxychlor >23 yg/£ was significantly
(P<0.05)  greater than mortality of control fish during the 140-
day study-  Further, hatching success of fry from eggs spawned
by fish exposed to 23 yg/£ was significantly less than hatching
success of control fry-  The maximum acceptable toxicant concen-
tration (MATC) was estimated to be >12<23 yg/£ and the applica-
tion factor limits were 0.24-0.47.

     Mortality of adult sheepshead minnows exposed to mean mea-
sured concentrations of malathion >18 yg/£ was significantly
greater than mortality of control fish during the 140-day study-
Mortality of fry hatched from eggs spawned by fish exposed to 9
and 18 yg/£ was significantly greater than mortality of control
fry.  The MATC was estimated to be >4<9 yg/& and the application
factor limits were 0.08-0.18.

     Mortality of adult sheepshead minnows exposed to mean mea-
sured concentrations of carbofuran >49 yg/£ was significantly
greater than mortality of control fish during the 131-day study.
Hatching success of fry from eggs spawned by fish exposed to 49
yg/£ was significantly less than hatching success of control fry.
Also, mortality of fry hatched from eggs spawned by fish exposed
to ?3 and 49 yg/£ was significantly greater than control fry
mortality.  The MATC was estimated to >15<23 yg/£ and the appli-
cation factor limits were 0.04-0.06.

     This report was submitted in fulfillment of Contract Number
68-03-0264 by EG&G, Bionomics Marine Research Laboratory, under
the sponsorship of the U.S. Environmental Protection Agency.
This report covers the period 23 May 1973 to 23 May 1975; work
was completed on 1 November 1976.
                               IV

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                           CONTENTS
Foreword	iii
Abstract	iv
Tables	vi
Acknowledgment 	   ix

   1.  Introduction	    1
   2.  Conclusions 	    3
   3.  Recommendations 	    4
   4.  Materials and Methods
            Test materials	    5
            Test water	    5
            Test animals	    6
            Test methods	    7
            Chemical analyses	    9
            Statistical analyses 	   13
   5.  Results and Discussion
            Chemical analyses	14
            Acute toxic ity	18
            Chronic toxicity 	   19
            Application factors	30
            Summary	31

References	33

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                             TABLES
Number                                                       Page

  1   Nominal and Measured Concentrations of Methoxychlor
        during Acute and Chronic Exposures of Sheepshead
        Minnows (Cyprinodon variegatus)  in Flowing Sea-
        water	14

  2   Nominal and Measured Concentrations of Malathion
        during Acute and Chronic Exposures of Sheeps-
        head Minnows (Cyprinodon variegatus)  in Flowing
        Seawater	15

  3   Nominal and Measured Concentrations of Carbofuran
        during Acute and Chronic Exposures of Sheepshead
        Minnows (Cyprinodon variegatus)  in Flowing Sea-
        water	16

  4   Analysis of Parent and Hydrolyzed Carbofuran in Sea-
        water Samples Collected from the Nominal Concen-
        tration of 500 yg/& during a 131-Day Exposure of
        Sheepshead Minnows (Cyprinodon variegatus)  	   16

  5   Acute Toxicity of Three Pesticides to Sheepshead
        Minnows (Cyprinodon variegatus)  Exposed in Flow-
        ing Seawater	18

  6   Percentage Mortality of Parental Sheepshead Minnows
        (Cyprinodon variegatus)  Exposed to Methoxychlor
        in Flowing Seawater	19

  7   Growth of Sheepshead Minnows (Cyprinodon variegatus)
        Exposed for 140 Days to Methoxychlor in Flowing,
        Natural Seawater ..... 	   20
                                                           *

  8   Number of Eggs Spawned by Sheepshead Minnows
        (Cyprinodon variegatus)  Exposed to Methoxychlor
        in Flowing, Natural Seawater during Three 10-Day
        Spawning Periods 	   21

  9   Number of Eggs Spawned per Day per Female Sheeps-
        head Minnow (Cyprinodon variegatus) Exposed to
        Methoxychlor in Flowing, Natural Seawater during
        Three 10-Day Spawning Periods	22

                                vi

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Number                                                       Page

 10   Hatching Success of Fry from Eggs Spawned by Sheeps-
        head Minnows  (Cyprinodon variegatus) Exposed to
        Methoxychlor in Flowing, Natural Seawater	23

 11   Percentage Mortality, Average Standard Length, and
        Weight (Determined In Water) of 28-Day Old Sheeps-
        head Minnow  (Cyprinodon variegatus) Fry Hatched
        from Eggs Spawned by Fish Exposed to Methoxychlor
        for 54-63 Days	  23

 12   Concentrations of Methoxychlor in Surviving Adult
        Sheepshead Minnows (Cyprinodon variegatus)  Ex-
        posed for 140 Days	24

 13   Accumulation of Organochlorine Pesticides by Marine
        Fishes	24

 14   Percentage Mortality of Sheepshead Minnows (Cyprinodon
        variegatus) Exposed to Malathion in Flowing, Natural
        Seawater for 140 Days	25

 15   Growth of Sheepshead Minnows  (Cyprinodon variegatus)
        Exposed for 140 Days to Malathion in Flowing, Nat-
        ural Seawater	25

 16   Number of Eggs Spawned by Sheepshead Minnows
        (Cyprinodon variegatus) Exposed to Malathion in
        Flowing, Natural Seawater during Two 10-Day Spawn-
        ing Periods	26

 17   Number of Eggs Spawned per Day per Female Sheeps-
        head Minnow  (Cyprinodon variegatus) Exposed to
        Malathion in Flowing, Natural Seawater during
        Two 10-Day Spawning Periods	26

 18   Hatching Success of Fry from the Eggs Spawned by
        Sheepshead Minnows (Cyprinodon variegatus)  Ex-
        posed to Malathion in Flowing, Natural Seawater.  .  .  27

 19   Percentage Mortality, Average Standard Length, and
        Weight (Determined In Water) of 28-Day Old Sheeps-
        head Minnow  (Cyprinodon variegatus) Fry Hatched
        from Eggs Produced by Fish Exposed to Malathion
        for 87-96 Days	27

 20   Percentage Mortality of Sheepshead Minnows (Cyprinodon
        variegatus) Exposed to Carbofuran in Flowing, Syn-
        thetic Seawater	28
                               VI1

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N umber                                                       Pagt

 21   Growth of Sheepshead Minnows (Cyprinodon variegatus)
        Exposed for 131 Days to Carbofuran in Flowing,
        Synthetic Seawater . ••	28

 22   Number of Eggs Spawned by Sheepshead Minnows
        (Cyprinodon variegatus)  Exposed to Carbofuran in
        Flowing, Synthetic Seawater	29

 23   Hatching Success of Fry from Eggs Spawned by Sheeps-
        head Minnows (Cyprinodon variegatus)  Exposed to
        Carbofuran in Flowing,  Synthetic Seawater	29

 24   Percentage Mortality and Average Standard Length of
        30-Day Old Sheepshead Minnow (Cyprinodon variegatus)
        Fry which were Hatched from Eggs Spawned by Fish
        Exposed to Carbofuran for 42-95 Days in Flowing,
        Synthetic Seawater	, .  30

 25   Concentrations (yg/£)  of Three Pesticides Toxic to
        Sheepshead Minnows (Cyprinodon variegatus)  in Acute
        and Chronic Tests, and the Relationship of Acute
        Toxicity to Chronic Toxicity 	  30

 26   Comparison of Acute and Chronic Malathion Toxicity
        to Two Freshwater Fishes and a Saltwater Fish. ...  31

 27   Summary of Significant Effects of Methoxychlor,
        Malathion, and Carbofuran on Sheepshead Minnows
        (Cyprinodon variegatus)  during Chronic Exposures
        in Flowing Seawater. ,	32
                               Vlll

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                        ACKNOWLEDGMENTS


     We thank the Project Officer, Mr. David J. Hansen, for his
guidance and patience during these studies.  Thanks to Mr. Terry
A. Hollister, EG&G, Bionomics Marine Research Laboratory, for
his help with statistical analyses, and thanks to Ms. Susan
Walker for typing the manuscript.  The assistance of Mr. Kenneth
S. Buxton, EG&G, Bionomics Analytical Chemistry Laboratory, -is
appreciated, as is the review of the manuscript by Kenneth J.
Macek, Ph.D., and Sam R. Petrocelli, Ph.D., EG&G, Bionomics
Aquatic Toxicology Laboratory.
                                IX

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                           SECTION I

                          INTRODUCTION


     These studies were undertaken to gain information about the
effects of three pesticides—methoxychlor, malathion, and carbo-
furan—on sheepshead minnows  (Cyprinodon variegatus), a saltwater
fish.  Data from these studies can be used to derive application
factors, first described by Mount and Stephan (1967).  An appli-
cation factor is obtained by dividing the concentration consid-
ered to be "safe" over a long period by a short-term toxicity
value.  The application factor may then be used to establish wa-
ter quality criteria for each pesticide.  The use of sheepshead
minnows for long-term, life-cycle tests was proposed by Schimmel
and Hansen (1975) and a tentative method was described by Hansen
and Schimmel  (1975).  In our short term studies, data on 96-hour
LCSO's (the concentration of each pesticide estimated to be lethal
to 50% of the test animals after 96 hours of exposure) were ob-
tained.  In our long-term studies, parental sheepshead minnows
were exposed for 28 days or more and then effects on spawning
and progeny were determined.  "Safe" concentrations were esti-
mated after evaluation of data on number of eggs spawned by pa-
rental fish, hatching success of embryos, mortality of fry,  and
growth of fry.

     Methoxychlor is a stable, chlorinated hydrocarbon compound
used to control a wide variety of insects which attack fruits,
vegetables, field and forage crops, and livestock.  It is also
used to control certain household and industrial insects.  Me-
thoxychlor is a replacement for DDT in many applications (Anon-
ymous, 1972).  Methoxychlor is ostensibly insoluble in water but
soluble in lipids (Gardner and Bailey, 1975) and thus might be
expected to accumulate in fish and to be cumulatively toxic dur-
ing long-term exposure.

     A recent publication (Gardner and Bailey, op. cit.) provides
an excellent overview of the effects of methoxychlor on environ-
mental quality and states that although there are variances in
estimates of the acute toxicity of methoxychlor to fishes, all
reported LCSO's ranged from 5-80 micrograms per liter  (pg/fc), ex-
cepting three.

     We know of only one chronic (partial life-cycle) toxicity
study that has been conducted with methoxychlor and fish (Merna
and Eisele, 1973).  Data from that study were insufficient for

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deriving an application factor.

     Malathion is an organophosphate pesticide used throughout
the U. S. to control a variety of pests.  A major use of mala-
thion is for mosquito control in both freshwater and estuarine
areas.  Several studies (Parkhurst and Johnson, 1955; Westman
and Compton, 1960; Weiss,  1961; Lewallen and Wilder, 1962;
Holland and Lowe, 1966; Wellborn, 1971; and Post and Schroeder,
1971) have shown that malathion is acutely lethal to a variety
of freshwater and saltwater fishes under both field and labora-
tory test conditions.  Sublethal effects (avoidance and inhibi-
tion of brain acetylcholinesterase)  have also been observed in
fashes exposed to malathion (Hansen e,t al., 1972; Coppage, 1972;
and Coppage and Matthews,  1972).

     Chronic studies have been conducted with malathion and two
freshwater fishes, fathead minnows (Pimephales promelas)  (Mount
and Stephan, 1967), and bluegill (Lepomis macrochirus)   (Eaton,
1970).  The studies showed the application factor limits for the
two fishes to be very similar, ranging from 0.02-0.06.

     Carbofuran is a carbamate pesticide utilized both as a con-
tact poison or as a soil-applied systemic poison.  It is regis-
tered for soil-applied use on a variety of crops, including rice,
and for direct use on several insects, including mosquitoes
(Anonymous, 1971).  Little research has been performed on the
effects of carbofuran on aquatic organisms.

     Carbofuran was the first compound tested.  Tests were con-
ducted from March-July 1974 in the EG&G, Bionomics Aquatic Toxi-
cology Laboratory, Wareham, Massachusetts.   Our new laboratory
was opened in January 1975, and tests with methoxychlor and mala-
thion were conducted from June-October 1975, at EG&G, Bionomics
Marine Research Laboratory, Pensacola, Florida.

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                            SECTION 2

                          CONCLUSIONS


     Sheepshead minnows  (Cyprinodon variegatus) are suitable test
animals for toxicity tests which include the reproductive portion
of the life cycle and the critical life stages  (embryos and fry)
of the successive generation.

     Tests with these saltwater fish are practical means of de-
termining maximum acceptable toxicant concentrations and appli-
cation factors because of (a) the amenability of sheepshead
minnows to laboratory culture and (b) the relatively short peri-
od of time required to reach sexual maturity and complete the
reproductive phase of the life cycle.

     The application factor limits derived for sheepshead minnows
exposed to malathion are very similar to the application factor
limits derived for two freshwater fishes, indicating that this
saltwater fish may be used effectively to obtain data on which
to base water quality criteria.

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                            SECTION 3

                         RECOMMENDATIONS
     Spawning groups comprising five sheepshead minnows in the
ratio of 3 female fish:2 male fish are satisfactory to determine
spawning success.

     A 10-day spawning period for a spawning group is sufficient
to monitor spawning success.

     Studies should be conducted with sheepshead minnows and
other toxicants in chronic  (full life-cycle) tests because tests
with this saltwater fish appear to provide accurate estimates of
MATC's in a shorter time and with less effort than do tests with
most freshwater fishes.

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                            SECTION 4

                      MATERIALS  AND METHODS
TEST MATERIALS
     Methoxychlor  used in this  study  was  obtained  from E.  I. du
Pont de Nemours  &  Company,  Biochemicals Department, Wilmington,
Delaware.   It was  contained in  a plastic  jar  labeled  "Methoxy-
chlor Technical, 1 Kg."   Although active  ingredient was not
listed on  the label,  a technical data sheet dated  April 1972
which accompanied  the chemical  stated that "...methoxychlor tech-
nical. . .contains 88%  (minimum)  2,2-bis-(p-methoxyphenyl)-1, 1,
1-trichloroethane  and 12% (maximum) other isomers  and reaction
products.

     Malathion was obtained from the  American  Cyanamid Company,
Agricultural Division,  Princeton,  New Jersey.   It  was contained
in a metal bottle,  apparently aluminum, with a transluscent cap.
The bottle was refrigerated at  all times.  The material was la-
beled "MALATHION Technical,  Active Ingredient:  Malathion* 95%;
Inert Ingredients  5%.   *0,0-dimethyl  phosphorodithioate of di-
ethyl mercaptosuccinate;  (1 Gallon contains 9.7 Ib of malathion)."

     Carbofuran was obtained from FMC Corporation, Agricultural
Chemical Division, Middleport,  New York.  It was contained in a
plastic bag labeled "Carbofuran Technical  (99%), FURADAN® In-
secticide,  Mr L514, 2Kg.  C4717-54-A,  9/14/73."

     Concentrations of each pesticide are reported here as micro-
grams (yg)  of the  technical material  described above per liter
(£) of seawater.

     Stock  solutions  of all three  pesticides were  prepared on a
weight:volume basis by dissolving them in reagent  grade acetone.
These I-I  stock solutions were  placed in  amber glass bottles and
stored in  the laboratory.   New  stock  solutions were prepared as
required.

TEST WATER

Methoxychlor and Malathion

     All water used for holding,  acclimation,  and  testing was
natural seawater which was  pumped  from Big Lagoon  into the

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 laboratory-  The pump  intake was  85 meters  (m) offshore  at  a
 depth of approximately 3 m.  Water was pumped by a  #316  stain-
 less steel pump through hard polyvinylchloride  (PVC) pipes  into
 an elevated  fiberglass reservoir.  En route, the water passed
 through a fiberglass,  sand  filter and a 10-micrometer  (ym)  poly-
 propylene bag filter.   From the reservoir,  in which the  water was
 continuously and vigorously aerated, water  flowed by gravity
 through PVC pipes to the diluters.

     No attempt was made to alter the salinity of the water, but
 temperature was maintained  at 30±1 degrees  Celsius  (°C)  by  heat-
 ing the incoming seawater in small fiberglass-coated plywood
 boxes above the diluters with electric quartz heaters and by
 placing test aquaria in constant-temperature water  baths.

 Carbofuran

     All water used for holding, acclimation, and testing was
 synthetic seawater, formulated according to the methods  of
 LaRoche et al. (1970).  Freshwater was pumped from  a 120-m  deep
 bed-rock well at the Wareham, Massachusetts, laboratory  into two
 l,500-& fiberglass tanks.   Ingredients were added,  mixed with
 freshwater, and aerated.  Water was drained from one tank at the
 rate of approximately  1,200 a per day until it was  empty.   Then,
 water was drained from the  second tank while fresh  synthetic sea-
 water was being prepared in the first tank.

     All water flowed  by gravity through PVC pipes  to the diluter.
 Temperature was maintained  at 30±1°C by placing the test aquaria
 in constant-temperature water baths.

 TEST ANIMALS

 Methoxychlor and Malathion

     All sheepshead minnows used in these studies were collected
 from Big Lagoon,  near  Bionomics Marine Research Laboratory.  They-
 were held in sand-banked ponds on the laboratory grounds and in
 fiberglass tanks in the laboratory.  All fish were  acclimated to
 test conditions for 14  days before testing according to  the con-
 ditions of U. S.  Environmental Protection Agency (1975).  Mor-
 tality was <3% during  acclimation.  During holding  and acclilfta-
 tion, fish were fed frozen or live Artemia  salina (San Francisco
Bay Brand)  which contained  <0.1 yg/g of chlorinated hydrocarbon
pesticides or polychlorinated biphenyls as  determined by our
electron-capture gas chromatograph analyses.

     Size of fish was:   methoxychlor—acute test, 1.7-3.8 centi-
meters (cm)  standard length (SL) and chronic test,  1.0-1.9  cm SL
and 0.15 g mean weight  (determined in water); malathion—acute
test, 0.8-1.8 cm SL and chronic test, 1.0-1.8 cm SL and  0.11 g
mean weight (determined in water).

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Carbofuran

      Fish were  obtained from the U.  S.  Environmental  Protection
Agency's Gulf Breeze  Laboratory,  Sabine Island,  Gulf  Breeze,
Florida, where  they had spawned naturally  in  outside  earthern
ponds.  Fish for the  acute  and chronic  tests  were  1.8-4.0  cm SL.

TEST  METHODS

Acute Tests

      All procedures followed methods of APHA  et  al.  (1976)  and
U. S. Environmental Protection Agency (1975) ,  except  as  stated.
The 96-hour  tests were  conducted in  an  intermittent-flow system
by-using a proportional diluter (Mount  and Brungs,  1967) con-
structed to  deliver 1 Jl/cycle at a dilution ratio  of  75%.   The
average number  of cycles was approximately 5/hour,  providing 99%
replacement  in  24 hours (Sprague, 1969) .   A mechanical injector
 (manufactured by George Frasier,  Duluth, MN),  equipped with a
50-milliliter  (m£) glass syringe and stainless steel  needle,
pumped methoxychlor,  malathion,  or carbofuran stock solution
through polyethylene  tubing to the mixing  cell.  Test containers
were  30 X 30 X  61-cm  glass  aquaria.   Each  contained 20 fish and
approximately 28 a of water.

Chronic Tests
     The tests were  conducted  as  described  above except that the
proportional diluter was  constructed  for  50%  dilution.  It de-
livered 1  Jl/cycle  at a  rate  of approximately  5  cycles/hour.  For
the methoxychlor and malathion tests,  the diluter was modified
'to include a solvent control wherein  the  same volume of solvent/
carrier (acetone)  was added  to methoxychlor-  or malathion-free
seawater as was added to  the highest  pesticide  concentration.
One injector, equipped  with  a  30-m£ glass syringe and a stainless
steel needle, metered the respective  stock  solutions through
polyethylene tubing  into  the mixing chamber.  A second injector,
equipped with a 50-m.e, glass  syringe with  stainless  steel needle,
metered acetone to each solvent control.  Maximum solvent concen-
tration was 29 y£/£  (parts per million, ppm) .
     To begin each test,  20  acclimated  fish were  impartially se-
lected and placed in the  test  aquaria  (a  total of 40  fish per
treatment) after the toxicant  delivery  system had been opera-
tional for several days.  Fish were  daily fed flaked  commercial
fish food  (BiOrell® and Tetramin®) ad libitum.  Salinity and dis-
solved oxygen were measured  daily throughout the  tests.  Light
for all tests was provided by  two 3.7-m fluorscent bulbs sus-
pended 46 cm above the test  containers, providing approximately
1,100 lux incident to the water  surface.   Photoperiod was 16
hours light, 8 hours dark.   Survival was  monitored daily by vi-
sually inspecting each test  container.  Growth was monitored bi-
weekly according to the photographic method of McKim  and Benoit

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 (1971) and  average weight was determined monthly by weighing
 each  group  in water.

      Effects of each pesticide on.-spawning were determined after
 fish  began  to exhibit signs of sexual maturity.

 Methoxychlor and Malathion—
      Monitoring of spawning activity was begun on day 54 of the
 methoxychlor test and on day 87 of the malathion test.  Spawning
 chambers were constructed by lacing pieces of 6.5-millimeter  (mm)
 square mesh #316 stainless steel screen together with #316 stain-
 less  steel  wire.  The chambers were 30.5-cm square X 25.5-cm
 high, and were supported by 5-cm high extensions of the screen
 ends.  Beneath each spawning chamber, a 29.5-cm square X 4.7-cm
 high  egg collection tray was placed to retain the demersal eggs
 that  sank through the bottom of the spawning chamber.  The tray
 was constructed of plate glass and silicone sealant, with a 4-cm
 wide  strip  of 480-ym square mesh nylon screen along one side of
 the bottom  to facilitate consolidation of eggs.  Spawning groups,
 which consisted of two male and three female fish, were placed in
 the spawning chambers for a 10-day period.  All possible 2:3
 ratios in each aquarium were spawned once and extra, unspawned
 fish  from each replicate aquarium were combined whenever possible
 to form a 2:3 spawning group.  Each day, one end of each spawning
 chamber was lifted slightly and the egg collection tray was re-
 moved from  the aquarium.  The eggs spawned during the previous
 24 hours were washed with seawater, transferred by large-bore
 glass pipette into glass Petri dishes, counted, and separated
 into  groups of 50 eggs.  Each 50-egg group was placed in an egg
 incubator cup (a 100-m£ glass jar with the bottom cut off and
 480-ym square mesh nylon screen attached with silicone sealant).
 Each  egg cup was then placed in the same aquarium as the spawn-
 ing group which produced it.  The egg incubator cups were sus-
 pended from a rocker-arm apparatus (Mount, 1968)  which gently
 oscillated  them in the test aquaria.   Eggs were removed from each
 egg incubator by pipette daily, counted, and the cups washed with
 bursts of freshwater to clean the screens.  This procedure was
 repeated until all living embryos hatched.  Then, 40 fry were
 placed in glass chambers (14-cm wide X 20.5-cm high X 26-cm long
 with  381-ym square mesh #316 stainless steel screen over one end).
 Survival was monitored daily and growth (standard length anS av-
 erage weight)  was measured after 28 days.   At least two groups
 of fry per duplicate from each test concentration and controls
were monitored,  except in the higher concentrations where toxi-
 cant-induced mortality made it impossible to obtain spawning
 groups and subsequent eggs and fry.

Carbofuran—
     Effects on spawning were determined by monitoring spawning
activity of individual pairs of fish, beginning on day 28.  Each
pair was placed in a 14 X 25 X 25-cm glass and #316 stainless
steel mesh spawning chamber similar to the fry chambers described

-------
 above.   Spawning was  monitored  for  a  62-day period, during which
 all  possible  pairs  of unspawned fish  in all duplicate  aquaria
 were spawned.   Eggs that  sank through a false bottom of  7-mm
 square mesh #316 stainless  steel screen were collected daily and
 treated  as described  above.

 CHEMICAL ANALYSES

 Seawater

      For each of the  three  acute tests, water was collected from
 each aquarium at the  beginning  and  end of the 96-hour  exposure.
 Water was collected from  alternate  duplicate aquaria weekly dur-
 ing  the  chronic tests.  Water samples were prepared and  analyzed
 as follows:

 Methoxychlor—
      Unfiltered seawater  was extracted twice with two  50-m& por-
 tions of Nanograde® (Mallinckrodt)  dichloromethane.  Volumes ex-
 tracted  were:

                       Nominal
                    concentration   Volumes
                        (yg/ft)          (ma)

                          6            500
                          11            300
                          22            300
                          45            100
                          90            100

 The  combined extracts were dried by elution through anhydrous
 sodium sulfate  (heated at 100°C  for 24 hours), concentrated to
 approximately 1 m£  in a Kuderna-Danish evaporator, and solvent-
 exchanged with  Nanograde  petroleum ether.  The extract volumes
were  adjusted to obtain a sensitivity of 0.05 ppm (nanograms
 [ng]   per y£)  by using a Perkin-Elmer  Model 2100 gas chromatograph
 equipped with a Ni63 electron-capture detector.

      Operating  conditions were:

      Column (glass)—2 m  X 4 mm  ID  3%  OV-101 on 80/100 mesh
                     Gas  Chrom Q

      Oven temp.—210°C           Detector temp.—275°C

      Injector temp.—250°C       Carrier gas—Nitrogen

Malathion—
      Unfiltered seawater  samples of 500 m£ were extracted twice
with  two 50-m£ portions of Nanograde  dichloromethane.  The ex-
tracts were dried by eluting through  anhydrous sodium  sulfate

-------
 (heated at 100°C for 24 hours) and concentrated in a Kuderna-
 Danish evaporator.  The extract volumes were adjusted to obtain
 a sensitivity of 1.0 ppm by using a Perkin Elmer Model 2100 gas
 chromatograph equipped with a flame photometric detector oper-
 ating in the phosphorus mode.

     Operating conditions were:

     Column  (glass)—2 m X 4 mm ID 3% OV-101 on 80/100 mesh
                     Gas Chrom Q

     Oven temp.—210°C          Bead setting—500

     Injector temp.—250°C      Carrier gas—10% argon/methane

 Carbofuran—
     Unfiltered water samples (approximately 500 nu) were mea-
 sured volumetrically in a graduated cylinder and placed in a l-£
 separatory funnel equipped with a Teflon® stopcock.  The water
 was extracted three times with separate 30-m& portions of Nano-
 grade dichloromethane and the combined extract was passed through
 an anhydrous sodium sulfate column to remove moisture from the
 solvent.  The sodium sulfate was rinsed with a portion of di-
 chloromethane and the extract and rinse were placed in a Kuderna-
 Danish evaporator equipped with a three-ball Synder column.  The
 solvent was evaporated to approximately 3 nU over an 80°C water
 bath, the extract was transferred to a 15-m& centrifuge tube with
 a Teflon-lined cap, and evaporated to dryness at room temperature
 by using a gentle stream of clean dry air.  The extract was then
 dissolved in an accurately known volume of Nanograde benzene and
 stored in a freezer at 15°C prior to analysis by gas/liquid chro-
 matography under the following conditions:

 Instrument—Perkin-Elmer Model 3920 gas chromatograph

 Detector—Nitrogen/phosphorus thermionic detection

 Column—0.6 m X 2 mm ID glass packed with 20% SE-30 coated on 60/
        80 Chromasorb W.  The column was conditioned at 235°C for
        two weeks prior to use.   Several injections (3 X 50 y&)
        of Silyl-8, a column-silanizing agent, were made ovSr the
        two-week conditioning period.

Gas flows—38 cubic centimeters (cc)  N2/minute (min.)  carrier,
           7 cc H2/min.  and 100 cc air/min. to the N/P detector.

Temperatures—Injection port:  225°C
              Column:   155°C
              Transfer line:  245°C

Recorder—Leeds & Northrup dual pen,  0-1 mV range, 5 mm/min.
          chart speed


                               10

-------
Response—30 ng of carbofuran and  80 ng of 3-hydroxycarbofuran
          gave half-scale response with retention times of  3.4
          and 6.4 min., respectively

     Extraction efficiency and mean recovery for the analytical
methods were 89.9±9.8% for methoxychlor,  84.5±11.7% for mala-
thion, and 79.0±7.3%  for carbofuran.  Data in this report are
corrected for recovery.

Fish Tissue

     Fish were collected for residue analyses as follows:

a.  adults alive at the end of the respective exposure;

b.  fry alive at the  end of the 28-day growth period; and

c.  eggs randomly collected during the spawning periods.

Methoxychlor—
     Tissues were analyzed by an adaptation of the methods of
U. S. Environmental Protection Agency (1971 and 1974).  Fish
tissue was weighed to the nearest 0.01 g  in a beaker.  The tis-
sue was transferred to a 100-m2, graduated cylinder, which had
been cut at the 80-mJi mark to reduce the  height of the cylinder;
the beaker was rinsed with dichloromethane, which was then added
to the cylinder.  The tissue was homogenized with approximately
30 m£ of dichloromethane for 20 seconds by using a Brinkman
Polytron Homogenizer, Model PT 10/20.

     The homogenate was filtered through No. 3 Whatman paper in-
to a clean beaker, approximately 30 m£ of dichloromethane was
added to the graduated cylinder, and the  Polytron probe was
rinsed for approximately 10 seconds in the solvent while the
homogenizer was operating at low speed.  The probe rinse was
added to the filter and finally the filter was washed with di-
chloromethane .

     The solvent was evaporated to approximately 5 m£ over a
steam bath, cooled, and evaporated to dryness at room tempera-
ture by using a gentle stream of clean air.  At this point the
extract was cleaned by florisil column chromatography according
to U. S. Environmental Protection Agency  (1974).  Methoxychlor
eluted quantitatively from the 6% ether-in-petroleum ether frac-
tion and was sufficiently free of interfering substances to
permit analysis by electron capture detection.  The 6% ethyl-
petroleum ether fraction containing methoxychlor was evaporated
to approximately 3 m£ in a Kuderna-Danish evaporator equipped
with a three-ball Snyder column, and the  unit was cooled to room
temperature.  The receiver was disconnected, the remainder of
the solvent was evaporated to dryness at  room temperature by using
a gentle air flow, and a known volume of  hexane was added to the

                                11

-------
receiver to dissolve the residue.

     An aliquot of the extract was analyzed by gas chromatography
under the following operating conditions:

Instrument—Tracer Model MT-550 gas chromatograph

Detector—Electron capture with 15 millicuries of Ni63

Column—2 m X 2 mm ID glass packed with 3% OV-101 on 100/120
        mesh HMDS-treated Supelcoport

Cashflows—30 cc N2/min. carrier, 60 cc N2/min. scavenger

Temperatures—Column:  200°C      Inlet:  230°C
              Transfer:  270°C    Detector:  302°C

Recorder—Corning Model 841, 0-1 mV, 0.5 cm/min. chart speed

Response—2.5 ng of methoxychlor gave half-scale pen deflection
          at an attenuation of 1.6 X 10~9 amperes

     Three fish, weighing approximately 1 g each, were spiked
with 100 ng of methoxychlor and were analyzed by the above
method.  The average precentage recovery of methoxychlor was
100±4.6%.  The analytical results were not corrected for re-
covery which was considered quantitative.

Malathion—
     Tissues were analyzed in the manner described for methoxy-
chlor except that malathion eluted from the florisil column
quantitatively in the 1:1 ethyl ether-in-petroleum ether frac-
tion.  An aliquot of the extract was analyzed by gas chromatog-
raphy under the following operating conditions:

Instrument—Perkin-Elmer Model 3920 gas chromatograph

Detectors—Electron capture with 15 millicuries of Ni63 and
           nitrogen/phosphorus thermionic detection

Effluent Splitter—10 parts to N/P and 3 parts to BCD

Column—2 m X 2 mm ID glass packed with 3% Dexsil 300 GC on 80/
        100 mesh DMHS-treated Supelcoport

Gas flows—36 cc N2/min. carrier, 7 cc N2/min. and 100 cc air/
           min. to the N/P detector

Temperatures—Injection port:  250°C
              Column:  220°C
              Transfer line and splitter:  265°C
                               12

-------
Recorder—Leeds & Northrup dual pen, 0-1 mV range, 1.0 cm/min.
          chart speed

Response—0.30 ng of malathion gave half-scale recorder pen
          deflection using the N/P detector at an attenuation
          of 16 X 1.  Retention time was 2.0 min.

     Three whole fish, weighing approximately 1  g each, were
spiked with 100 ng of malathion and were analyzed by the above
method.  The average percentage recovery of malathion was 103±
6.8%.  The analytical results were not corrected for recovery
which was considered quantitative.

Carbofuran—
     Results of previous research in which fish were continu-
ously exposed to radiolabeled C14 carbofuran for 28 days indi-
cated that the maximum tissue concentrations were reached within
3-10 days, after which an equilibrium concentration was observed.
A concentration factor of 5-20X was calculated (FMC, 1976).  In
view of the rapid equilibrium, the low concentration factor, and
the absence of a routine gas-chromatographic analytical method
for fish tissues, fish from the carbofuran chronic test were not
analyzed for residues.

STATISTICAL ANALYSES

     In the acute tests, the LCSO's and 95% confidence limits
were calculated by linear regression analysis after probit trans-
formation (Finney, 1971) .

     In the chronic tests, differences between treatments were
determined by chi-square (X2) and analysis of variance (Sokol
and Rohlf, 1973).  Differences were considered significant at
the 95% (P<0.05) confidence level.  Post-hoc tests were con-
ducted on treatment means by using the Student-Newman-Keuls
range test (Keuls, 1952).
                               13

-------
                            SECTION 5

                    RESULTS AND DISCUSSION
CHEMICAL ANALYSES

     Mean measured concentrations of methoxychlor  in  seawater
were from 57-109% of nominal during the 96-hour test  and  from
45-55% of nominal during the chronic test  (TABLE 1).  Because
this chlorinated hydrocarbon pesticide is  "essentially  insoluble
in water (0.10 mg/A @ 25°C)" (Anonymous, 1972) and because  ex-
posure to light and the addition of particulate matter  and  micro-
organisms hastens its degradation (Gardner and Bailey.-  1975),,
these mean measured concentrations were within an  expected  and
acceptable range.


TABLE 1.  NOMINAL AND MEASURED CONCENTRATIONS OF METHOXYCHLOR
          DURING ACUTE AND CHRONIC EXPOSURES OF SHEEPSHEAD  MIN-
          NOWS (CYPRINODON VARIEGATUS) IN FLOWING  SEAWATER.
 Test
                         Concentration (yg/l.)
Nominal
Measured
0
Acute Control
22
30
40
53
70
93
125

Chronic Control
Sol. control
6
11
22
45
90
hour
<0.01
13
11
25
33
26
67
62
Mean
0.2
_a
3
5
12
23
48
96 hour
<0.01
21
29
26
35
54
86
209
S.D.
±0.5
—
±2
±4
±7
±19
±10
Mean
_
17
20
26
34
40
78
136
Range
0-2
-
1-7
2-18
4-30
9-85
34-53
% of nom.
_
77
67
65
64
57
84
109
% of nom.
_
-
50
45
55
51
53









t samples
18
-
15
15
15
15
4
JNot analyzed.
                               14

-------
      Malathion is readily soluble in water and mean measured
 concentrations during both the acute and chronic tests reflected
 this characteristic; concentrations were 72-143% of nominal
 (TABLE 2).
 TABLE 2.  NOMINAL AND MEASURED CONCENTRATIONS OF MALATHION DUR-
           ING ACUTE AND CHRONIC EXPOSURES OF SHEEPSHEAD MINNOWS
           (CYPRINODON VARIEGATUS) IN FLOWING SEAWATER.
Concentration (yg/£)
Test Nominal

Acute Control
22
30
40
53
70
94
125

Chronic Control
Sol. control
4
8
15
30
60
Measured
0 hour
<0.1
16
26
25
43
62
78
108
Mean
<0.1
_a
4
9
18
37
86
96 hour
<0.1
16
27
37
50
67
99
111
S.D.
_
—
±2
±4
±6
±12
±15
Mean -
_
16
26
31
46
64
88
109
Range '
_
-
1-6
4-17
8-28
20-57
70-101
1 of nom.
_
72
87
78
89
91
95
87
'5 of nom.
_
—
100
112
120
123
143









# samples
19
-
20
20
20
10
3
 aNot analyzed.

     Mean measured concentrations of parent carbofuran were from
44-62% of nominal during the acute test and from 18-24% of nomi-
nal during the chronic test  (TABLE 3).  Evaluation of the analy-
ses of water samples collected during days 1-30 of the chronic
test shows that concentrations of parent carbofuran were approxi-
mately 40% of nominal.  Thereafter, despite the use of a flowing-
water exposure system, measured concentrations of parent material
decreased to approximately 10% of nominal.  Concurrently, however,
we observed a pattern of increasing concentrations of hydrolyzed
carbofuran derivitives (TABLE 4).  The rapid decline of measured
concentrations of parent material in the 4-day acute test and the
stability of parent carbofuran in a stock solution over a 12-day
period (confirmed by chemical analyses) is further evidence that
carbofuran was degraded in seawater.
                                15

-------
  TABLE 3.   NOMINAL AND MEASURED CONCENTRATIONS OF CARBOFURAN DUR-
            ING ACUTE AND CHRONIC EXPOSURES OF SHEEPSHEAD MINNOWS
            (CYPRINODON VARIEGATUS)  IN FLOWING SEAWATER.
Concentration (yg/&)
Test Nominal
0
Acute Control
420
560
750
1,000
1,300

Chronic Control
Sol. Control
31
62
125
250
500
Measured
hour
cO.l
230
380
480
640
860
Mean
<0.1
_a
6
15
23
49
100
96 hour
<0.1
120
270
220
280
760
S.D.

-
±4
±11
±21
±44
±93
Mean '
_
175
325
350
460
810
Range '
2-12
-
2-12
1-29
1-65
2-150
20-270
£ of nom.
__
44
58
47
46
62
\ of nom.
_
-
19
24
18
20
20







# samples
7
-
7
10
12
12
10
 aNot analyzed.

 TABLE 4.  ANALYSIS OF PARENT AND  HYDROLYZED CARBOFURAN IN SEA-
           WATER SAMPLES COLLECTED FROM THE NOMINAL CONCENTRATION
           OF 500 yg/£ DURING A  131-DAY EXPOSURE OF SHEEPSHEAD
           MINNOWS  (CYPRINODON VARIEGATUS).

Test
Day
12
27
34
41
55
62
70
76
84
105
Parent
Carbofuran
(yg/£;ppb)
200
120
210
79
29
37
28
38
85
20

Hydrolyzed
Carbofurana
<1.0
<1.0
6.1
<1.0
<1.0
2.1
9.5
10.0
17.0
18.1
aThe percentage recovery of the hydrolyzed carbofuran from water
 is unknown. Therefore, these values  are  relative to each other.

                                16

-------
     Our  justification  for  and  methodology  of  determining the
hydrolyzed products  of  carbofuran  are  as  follow:

     Carbofuran  and  3-hydroxycarbofuran were completly  hydro-
lyzed within  24  hours when  saturated solutions were  made  pH  9.2
and  stored at 25°C  (FMC,  1969).  Similar  to the base-catalyzed
degradation of Sevin® to  1-hydroxynaphthol, carbofuran  was ex-
pected  to eliminate  the methylcarbamate group  to  form an  hydroxy-
sub-stituent  at  the  benzyl-oxygen.  Therefore, an analytical pro-
cedure  featuring derivatization of 1-naphthol  was utilized to
verify  any degradation  products of carbofuran  which  possess ac-
tive hydroxy-substituents.  Parent carbofuran  is  not detected by
this analyses since  it  does not contain the reactive hydroxy sub-
stituent.

     Approximately 2 g  of carbofuran were added to 300  m£ of nor-
mal  sodium hydroxide and  heated to 60°C for six hours.  The solu-
tion was  cooled,  hydrochloric acid was added to adjust  the solu-
tion to pH 4.0,  and  the hydrolyzed carbofuran  was extracted into
methylene chloride.  The  solvent was evaporated and  a portion of
the hydrolyzed carbofuran was weighed  and dissolved  in  benzene
to produce the hydrolyzed carbofuran working standard solution.

     An analytical procedure  (U. S. Environmental Protection
Agency, 1974)  designed  for the  gas  chromatographic determination
of 1-naphthol in urine, following  derivatization  with chloroace-
tic anhydride, was utilized to  verify  the hydrolysis of carbo-
furan.  Working  standards of hydrolyzed carbofuran were deriva-
tized and chromatographed under operating conditions previously
described (except by using electron capture detection) with the
following results:


 Weight of hydrolyzed     	Peak height response (mm)	
Carbofuran/7  m£  benzene  Retention~~\Retention
          (yg)	   time     " 3'° min'   time    = 4'2 min<
0 4
1 5
2 6
5 15
10 31
3
9.5
18
41
116
     An aliquot of the seawater sample extracts  (see TABLE 4) was
derivatized and the gas chromatograms were examined for the pre-
sence of quantity of hydrolyzed carbofuran.  A graph of peak
height versus weight of hydrolyzed carbofuran was constructed,

                               17

-------
by using the peak eluting in 4.2 minutes, and any hydrolyzed
carbofuran found was determined with the graph.  The data are
presented as relative concentrations found in the seawater  since
the extraction efficiency of the hydrolyzed carbofuran moiety
from the seawater was unknown.

     The concentrations of hydrolyzed carbofuran in seawater
continued to increase during the test period.  It is important
to note that sample extracts were not treated with an aqueous
base, but were derivatized directly.  Therefore, any hydrolysis
product of carbofuran detected was extracted from the seawater
sample.  Additionally, parent carbofuran working standards  sur-
vived the derivatization procedure virtually unchanged and  the
peaks at 3.0 and 4.2 minutes due to hydrolyzed carbofuran were
not observed.

ACUTE TOXICITY

     The acute toxicity of methoxychlor and malathion to sheeps-
head minnows was similar; carbofuran was one order of magnitude
less toxic (TABLE 5).
TABLE 5.  ACUTE TOXICITY OF THEEE PESTICIDES TO SHEEPSHEAD MIN-
          NOWS (CYPRINODON VARIEGATUS) EXPOSED IN FLOWING SEA-
          WATER.   SEAWATER FOR THE METHOXYCHLOR AND MALATHION
          TESTS WAS NATURAL; THAT FOR THE CARBOFURAN TEST WAS
          SYNTHETIC.  CALCULATIONS WERE BASED ON MEASURED CON-
          CENTRATIONS OF EACH PESTICIDE.
Compound
Methoxychlor
Malathion
Carbofuran
96-hour
LC50, \iq/H
49
51
386
95% confidence
limits, pg/£
37-65
41-63
311-480
Salinity
(°/oo)
23
20
21
Temperature
(°C)
30
29
22
     The acute toxicity of methoxychlor to sheepshead minnows
tested under dynamic conditions was within the range reported
for other estuarine fishes under static conditions, where esti-
mated 96-hour LCSO's ranged from 12-150 yg/&.  In static tests
with two cyprinodontid fishes, Eisler  (1970) estimated 96-hour
LC50 values of 30 and 36 yg/£ for the  striped killifish
(Fundulus majalis) and mummichog (F. heteroclitus), respectively.

     In flowing water tests, malathion was more acutely toxic to
sheepshead minnows than to the freshwater fathead minnow  (96-
hour LC50 9,000 yg/£) (Mount and Stephan, 1967) or bluegill


                               18

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 (96-hour LC50  108  yg/A)  (Eaton,  1970).   Similarly,  sheepshead
minnows were more  sensitive  than were  all but one of the seven
estuarine  fishes tested  under static conditions by Eisler (1970),
including  the  striped  killifish  and mummichog,  for which the 96-
hour LCSO's were 250 and 240 vg/l,  respectively.

     Carbofuran was of the same  order  of toxicity to sheepshead
minnows as to  three freshwater fishes  tested  under static condi-
tions.  Reported 96-hour TLM's (median tolerance  limits;  same
as LC50) for rainbow trout  (Salmo gardneri) ,  channel catfish
 (Ictalurus punctatus), and bluegill were 280,  210,  and 240 yg/£,
respectively  (Anonymous,  1971).

CHRONIC TOXICITY

Methoxychlor

     Methoxychlor  affected parental fish in the 140-day study.
Exposure to 48 yg/£ was  lethal to 100%  of the fish  in one dupli-
cate after 10  days and after 15  days in the other.   Mortality of
fish exposed to 23 yg/£  was  significantly greater than mortality
of control fish  (TABLE 6).
TABLE 6.  PERCENTAGE MORTALITY OF  PARENTAL  SHEEPSHEAD MINNOWS
           (CYPRINODON VARIEGATUS)  EXPOSED TO METHOXYCHLOR IN
          FLOWING  SEAWATER.  MORTALITY  IS THE AVERAGE FROM DU-
          PLICATE  AQUARIA AND DOES NOT  INCLUDE  DEATHS WHICH OC-
          CURRED IN THE  SPAWNING CHAMBERS.
                          Concentration  (yg/&)

Day
1-30
31-60
61-90
91-120
121-140

Control
0
0
0
0
0
Solvent
Control
0
0
0
0
0

3
0
0
0
0
0

5
2
0
0
0
0

12
0
0
0
0
0

23.
10
8
2
0
0

48
100
-
-
-
—
      Total       0         0020    20a    100a


   aSignificantly different from the control.

     Growth of parental fish exposed to methoxychlor was not
significantly different from growth of control  fish.   Although
growth was monitored biweekly, only measurements  at the begin-
ning, middle, and end of the exposure are presented  (TABLE  7).
                               19

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TABLE 7.  GROWTH OF SHEEPSHEAD MINNOWS (CYPRINODON VARIEGATUS)
          EXPOSED FOR 140 DAYS TO METHOXYCHLOR IN FLOWING, NAT-
          URAL SEAWATER.  MEAN STANDARD LENGTH AND STANDARD DE-
          VIATION ARE GIVEN IN CENTIMETERS AND WERE DETERMINED
          PHOTOGRAPHICALLY.  AVERAGE WEIGHT IS GIVEN IN GRAMS
          AND WAS DETERMINED IN WATER.

Concentration
(ygA)
Control
Sol. control
3
5
12
23
48
Day
Length
(cm)
1.4±0.2
1.4±0.2
1.4±0.2
1.4±0.2
1.5±0.2
1.5±0.3
1.5±0.2
0
Wt.
(Sl
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Day 58
Length
(cm)
2.9±0.2
2.8±0.3
2.8±0.3
2.7±0.3
2.8±0.3
2.8±0.4
^a

Wt.
(g)
0.6
0.6
0.3
0.5
0.6
0.7
—
Day
Length
(cm)
3.7±0.5
3.6±0.4
3.5±0.5
3.5±0.4
3.510.4
3.7±0.4
—
140
Wt.
. IaL
1.3
1.2
1.2
1.0
1.2
1.5
—
aAll fish had died.

     Fecundity (total eggs spawned)  of exposed fish was not sig-
nificantly different from that of control fish (TABLE 8).  Be-
cause female fish were killed by male fish in spawning chambers
in all treatments except 23 yg/£, we calculated eggs per female
spawning day-  These values were obtained by dividing the num-
ber of eggs obtained from a spawning chamber during a 24-hour
period by the number of live female fish in the spawning chamber
during the same period.  There was no significant difference be-
tween eggs per female spawning day in any treatment because of
variability within the treatments, but fewer eggs were spawned
per female spawning day by fish exposed to 5, 12, and 23 yg/£
than were spawned by control fish (TABLE 9).

     No female fish were killed by male fish in spawning chambers
in 23 yg/£, although 1 to 6 females were killed in spawning cham-
bers in lower concentrations and controls.  Based on observations
of fish in the spawning chambers, a probable reason is that ex-
posure to 23 yg/fc of methoxychlor decreased aggressive spawning
activity of male fish.

     Hatching success of fry from eggs spawned by fish exposed
to 23 yg/£ of methoxychlor was significantly less than hatching
success of control fry (TABLE 10).

     Neither fry mortality to 28 days posthatch nor growth of
the fry was significantly affected by exposure to methoxychlor
(TABLE 11).
                               20

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     TABLE 8.  NUMBER OF EGGS SPAWNED BY SHEEPSHEAD MINNOWS  (CYPRINODON VARIEGATUS)

EXPOSED TO METHOXYCHLOR IN
10-DAY SPAWNING PERIODS.
WERE PLACED IN A SPAWNING
FLOWING, NATURAL SEAWATER DURING THREE
FIVE UNSPAWNED FISH (2 MALES AND 3 FEMALES)
CHAMBER IN EACH DUPLICATE AQUARIUM, A AND B.
Concentration
Day
Day
54
to
63
101
to
110
116
to
125
™?!L
TOTAL
Control
A B
443 253a
778 514
342a 413a
1,563 1,180
2,743
Solvent
Control
ABA
244a 809 746
86a 1,183 322
367a 934 528
697 2,926 1,596
3,623
3
B
921
a 991
793
2,705
4,301
(vgA)
5 12
A BAB
49 575 162 399
476 277a 94 384
563a 829 517 163a
1,088 1,681 773 946
2,769 1,719

23
A B
91 5
189 570
38 1,085
318 1,660
1,978
aDeaths occurred in spawning chamber.

-------
         TABLE  9.   NUMBER OF EGGS SPAWNED PER  DAY  PER FEMALE SHEEPSHEAD MINNOW
                    (CYPRINODQN VARIEGATUS) EXPOSED TO METHOXYCHLOR IN FLOWING,
to
NATURAL SEAWATER DURING THREE 10-DAY SPAWNING PERIODS.
UNSPAWNED FISH (2 MALES AND 3 FEMALES) WERE PLACED IN A
ING CHAMBER IN EACH DUPLICATE AQUARIUM, A AND B.
FIVE
SPAW
Concentration (yg/£)
Day
54-63
101-110
116-125
Mean of
duplicate
Mean of
treatment
Control
A
15
26
16
19
B
11
17
15
14
17±5
Solvent
Control
A
12
5
12
10
B
27
39
31
32
21±13
3
A
25
11
18
18
25±
5
B
31
38
26
32
9
A
2
16
20
13
B
19
11
28
19
16±9
12
A B
5 13
3 13
17 8
8 11
10±5
23
A
3
6
1
3
B
0
19
26
18
11±14

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TABLE 10.  HATCHING SUCCESS OF FRY  FROM EGGS  SPAWNED BY SHEEPS-
           HEAD MINNOWS  (CYPRINODON VARIEGATUS)  EXPOSED TO
           METHOXYCHLOR  IN FLOWING, NATURAL SEAWATER.   MEAN PER-
           CENTAGE HATCH AND STANDARD  DEVIATION  REPRESENTS POOLED
           DATA FROM DUPLICATE AQUARIA DURING THREE  10-DAY SPAWN-
           ING PERIODS.
      Concentration
          (ygA)
Mean percentage
hatch and S.D.
Numbers of eggs
   examined

Sol




Control
. control
3
5
12
23
98±3
98±4
98±3
95±6
97±2
73±18a
1,200
2,040
2,400
1,450
700
1,055
      aSignificantly different  from  the  control.
TABLE 11.  PERCENTAGE MORTALITY, AVERAGE  STANDARD  LENGTH,  AND
           WEIGHT  (DETERMINED  IN WATER) OF  28-DAY  OLD SHEEPSHEAD
           MINNOW  (CYPRINODON  VARIEGATUS) FRY  HATCHED FROM EGGS
           SPAWNED BY FISH EXPOSED  TO  METHOXYCHLOR FOR 54-63
           DAYS.
Concentration


Sol




(yg/£)
Control
. control
3
5
12
23
Number
of fry
160
160
160
80
120
59
Mortality
Length
(%) (cm)
0
0
1
0
4
4
1.
1.
1.
1.
1.
1.
4±0.
4±0.
4±0.
3±0.
4±0.
5±0.
1
1
1
1
1
2
Weight
(g)
0.
0.
0.
0.
0.
0.
07
05
07
06
06
06
     Methoxychlor was accumulated by  adult  fish  exposed  continu-
ously for 140 days.  The pesticide was  also accumulated  in eggs
spawned by these fish.  Accumulation  was  dependent  upon  water
concentration during exposure  (TABLE  12).   Concentration factors
(based on measured water concentrations)  ranged  from 113-264.
These values are much lower than concentration factors for other
chlorinated hydrocarbon pesticides and  marine fishes (TABLE 13).
A maximum concentration of 1.1  yg/g was detected in eggs spawned
by fish exposed to 12
                                23

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TABLE  12.  CONCENTRATIONS  OF METHOXYCHLOR IN SURVIVING ADULT
           SHEEPSHEAD MINNOWS  (CYPRINODON VARIEGATUS)  EXPOSED
           FOR  140 DAYS.   MEAN TISSUE  RESIDUES  ARE WHOLE-BODY,
           WET-WEIGHT.  DUPLICATE  ANALYSES OF EACH POOLED SAMPLE
            (AT  LEAST 2  FISH PER  SAMPLE)  WERE PERFORMED.
Concentration
Water
(pg/£)
Control
Sol. control
3
5
12
23
Tissue
(yg/g)
<0.1
<0.1
0.3410.24
1.32±0.24
1.38+0.25
3.18+0.53
Concentration
factor
—
-
113
264
115
138
Number
of samples
4
4
6
6
6
6
TABLE 13.  ACCUMULATION OF ORGANOCHLORINE PESTICIDES  BY MARINE
           FISHES.  CONCENTRATION FACTORS WERE  DERIVED BY DI-
           VIDING CONCENTRATIONS IN FISH  (WHOLE-BODY,  WET-WEIGHT)
           BY CONCENTRATIONS IN TEST WATER.
                       Concentration
Pesticide     Fish        factor      Exposure        Source
                          (maximum)      (days)
DDT
Dieldrin
Atlantic
croaker
Pinfish
Spot
16,300a
40,000a
6,700b
21-35
14
35
Hansen and Wilson,
1970
Parrish et al. ,
                                                       1973
 Endrin
Sheepshead
  minnows
4,800b
33
Schimmel et al. ,
     •1975
^Based on nominal water concentration.
"Based on measured water concentration.

Malathion

     Malathion affected survival of parental fish but  did  not
affect their growth or fecundity  (TABLES 14-17).  Exposure to
86 yg/& was lethal to 100% of the fish in one duplicate  and 95%

                               24

-------
in the other  after  5  days;  exposure to 37 v-g/t* was lethal to 100%
in one duplicate  and  80%  in the other after 30 days.  Exposure
to 18 yg/£ was  lethal to  50% of the fish in both duplicates af-
ter 86 days.  No  deaths occurred in any concentration or control
after day 90  of the 140-day study.
TABLE 14.  PERCENTAGE  MORTALITY OF SHEEPSHEAD MINNOWS
            (CYPRINODON VARIEGATUS)  EXPOSED TO MALATHION IN
           FLOWING,  NATURAL SEAWATER FOR 140 DAYS.  MORTALITY
           IS THE AVERAGE FROM DUPLICATE AQUARIA AND DOES NOT
           INCLUDE  DEATHS WHICH OCCURRED IN THE SPAWNING CHAM-
           BERS.
Concentration (pg/£)

Day
1-30
31-60
61-90
91-120
121-140

Control
0
0
2
0
0
Solvent
Control
0
0
0
0
0

4
0
0
5
0
0

9
0
0
0
0
0

18
5
23
22
0
0

37
90
8
2
—
-

86
100
_
—
—
-
     Total
   0   50C
    100C
                                                        100'
    aSignificantly  different  from the control.

TABLE 15.  GROWTH OF  SHEEPSHEAD MINNOWS (CYPRINODON VARIEGATUS)
           EXPOSED  FOR  140  DAYS TO MALATHION IN FLOWING,  NAT-
           URAL SEAWATER.   MEAN STANDARD LENGTH AND STANDARD
           DEVIATION  ARE  GIVEN  IN CENTIMETERS AND WERE DETER-
           MINED PHOTOGRAPHICALLY.   AVERAGE WEIGHT IS GIVEN IN
           GRAMS AND  WAS  DETERMINED IN WATER.
Concentration
                       Day  0
                  Length    Wt.
   Day 61
           Day 140
Length
Wt.
                                                     Length   Wt.
Control
Sol. control
4
9
18
37
86
1.4±0.2
1. 3±0.2
1.4±0.2
1.3±0.2
1.3+0.2
1.4±0.2
1.4±0.2
0.1
0.1
0.2
0.1
0.1
0.1
0.1
2.8±0.4
2.7±0.6
2.7±0.3
2.8±0.3
2.6±0.4
2.4±0.2
_b
0.7
0.8
0.7
0.7
0.6
0.5
-
4.1±0.4
4.1+0.5
3.9±0.4
3.9±0.4
3.7±0.3
_b
-
1.4
1.4
1.2
1.3
_a
_
-
aAll fish were used  for  acetylcholinesterase inhibition
 analyses.
bAll fish had died.
                               25

-------
TABLE 16.  NUMBER OF EGGS  SPAWNED BY SHEEPSHEAD MINNOWS
            (CYPRINODON VARIEGATUS)  EXPOSED TO MALATHION IN
           FLOWING, NATURAL  SEAWATER DURING TWO 10-DAY SPAWN-
           ING PERIODS.  FIVE  UNSPAWNED FISH (2 MALES AND 3
           FEMALES) WERE PLACED  IN A SPAWNING CHAMBER IN EACH
           DUPLICATE AQUARIUM, A AND B.
Concentration (yg/Ji)
Day
87-96
119-128
SUBTOTAL
TOTAL
Control
A
154a
538
692
1,
B
747a
258
1,005
697
Solvent
Control
A
111
364
1,141
2,
B
626
325
951
092
A
422
535
957
2,
4
B
445
729
1,174
131

A
341
738
1,079
1,
9
B
a 481a
390
871
950
18
A
299
_b
299
1,
B
353
374a
727
026
aDeath(s) occurred in spawning  chamber.
    spawning chamber; 50% mortality  had  occurred.
TABLE 17.  NUMBER OF EGGS SPAWNED  PER DAY PER FEMALE SHEEPSHEAD
           MINNOW (CYPRINODON VARIEGATUS)  EXPOSED TO MALATHION
           IN FLOWING, NATURAL SEAWATER DURING TWO 10-DAY SPAWN-
           ING PERIODS.  FIVE UNSPAWNED FISH (2 MALES AND 3 FE-
           MALES) WERE PLACED IN A SPAWNING CHAMBER IN EACH
           DUPLICATE AQUARIUM, A AND  B.
Concentration (yg/£)
Day
87-96
119-128
Average of
duplicate
Mean of
treatment
Control
A B
11 30
18 9
14 20
17±9
Solvent
Control
A
26
12
19
18±
B
21
11
16
7
4
A B
14 15
18 24
16 20
18±4
9
A B
16 21
25 13
20 17
19±5
18
A
10
_a
10
14±

B
21
19
16
5
aNo
spawning chamber; 50% mortality  had occurred.
     Malathion did not affect hatching success of fry from eggs
                                26

-------
spawned  (TABLE 18) but did  affect  the  fry.   Mortality of fry
hatched  from eggs spawned by  fish  exposed to 9  and 18 yg/£ of
malathion was significantly greater  than  mortality of control
fry.  Growth of surviving fry was  not  affected  (TABLE 19).
TABLE 18.  HATCHING SUCCESS OF  FRY  FROM  EGGS  SPAWNED BY SHEEPS-
           HEAD MINNOWS  (CYPRINGDON VARIEGATU5)  EXPOSED TO MALA-
           THION IN FLOWING, NATURAL  SEAWATER.   MEAN PERCENTAGE
           HATCH AND STANDARD DEVIATION  REPRESENTS  POOLED DATA
           FROM DUPLICATE AQUARIA DURING TWO  10-DAY SPAWNING
           PERIODS.
         Concentration
             (yg/£)
Percentage
  hatch
Number of eggs
   examined
Control
Sol. control
4
9
18
97±5
99±2
97±3
97±2
96±6
850
700
1,000
900
350
TABLE 19.  PERCENTAGE MORTALITY, AVERAGE  STANDARD  LENGTH,  AND
           WEIGHT  (DETERMINED  IN WATER) OF  28-DAY  OLD SHEEPSHEAD
           MINNOW  (CYPRINODON  VARIEGATUS) FRY  HATCHED FROM EGGS
           PRODUCED BY FISH EXPOSED  TO  MALATHION FOR 87-96 DAYS.
Concentration
(yg/£)
Control
Sol. control
4
9
18
Number
of fry
160
160
160
160
120
Mortality
(%)
7
10
9
14b
15b
Length
(cm)
1.0±0.2
_a
1.1±0.2
1.2±0.2
1.2±0.1
Weight
(g)
0.04
0.03
0.04
0.04
0.03
   ^No data.
   ^Significantly different  from  the  control.

     Malathion was not detectable (<0.1  yg/g)  in  fish sampled at
the end of the 140-day study-  This is not  surprising because
fish readily convert malathion to the mono- and dicarboxylic
acids of malathion  (Cook and Moore, 1976).

Carbofuran

     Carbofuran affected survival of  parental  fish exposed to
the pesticide for 131 days.  Exposure to 100 yg/£ was lethal to
                               27

-------
100% of the fish in one duplicate  and  95%  in the other after 14
days.  Mortality of fish exposed to  49 ppb was significantly
greater than mortality of control  fish after 30 days of exposure
(TABLE 20).


TABLE 20.  PERCENTAGE MORTALITY OF SHEEPSHEAD MINNOWS (CYPRINODON
           VARIEGATUS) EXPOSED TO  CARBOFURAN IN FLOWING, SYNTHE-
           TIC SEAWATER.  MORTALITY  IS THE AVERAGE FROM DUPLICATE
           AQUARIA AND DOES NOT INCLUDE DEATHS FROM SPAWNING
           ACTIVITY.
Concentration (yg/S,)
Day
1-30
31-60
61-90
91-131
Control
0
5
2
0
6
5
5
0
0
15
2
8
5
0
23
5
10
0
0
49
40
10
0
0
100
100
-
-
—
         Total       7      10    15    15    50a   100a


         aSignificantly different  from the  control.

     Carbofuran did not significantly  affect  growth of parental
fish or number of eggs spawned in  any  concentration (TABLES 21-
22) .
TABLE 21.  GROWTH OF SHEEPSHEAD MINNOWS  (CYPRINODQN VARIEGATUS)
           EXPOSED FOR 131 DAYS TO CARBOFURAN IN FLOWING, SYN-
           THETIC SEAWATER.  MEAN STANDARD  LENGTH AND STANDARD
           DEVIATION ARE GIVEN IN CENTIMETERS AND WERE DETER-
           MINED PHOTOGRAPHICALLY.  .AVERAGE WEIGHT IS GIVEN IN
           GRAMS AND WAS DETERMINED  IN WATER.
Concentration
(vgA)
Control
6
15
23
49
100
Day 2
Length
2.9±0.4
3.8±0.5
3.1±0.4
2.810.4
2.8±0.5
3.010.5
Day 60
Length
3.8+0.3
3.610.4
3.6+0.3
3.210.4
3.310.3
_a
Day
Length
4.H0.3
4.010.2
3.9+0.3
3.810.3
3.7+0.5
—
131
Weight
*
1.15
1.10
1.16
0.92
1.05
—
     aAll fish had died.
                               28

-------
TABLE 22.  NUMBER OF EGGS SPAWNED  BY  SHEEPSHEAD MINNOWS
            (CYPRINODON VARIEGATUS)  EXPOSED  TO CARBOFURAN IN
           FLOWING, SYNTHETIC  SEAWATER.   ALL POSSIBLE PAIRS
           OF FISH IN EACH  DUPLICATE  AQUARIUM WERE SPAWNED.
      Concentration    	Number  of  eggs	
          (yg/&)	    Replicate A     Replicate  B    Total
Control
6
15
23
49
650
854
848
475
248
449
852
1,295
820
154
1,099
1,706
2,143
1,295
402a
       aFifty percent mortality  had occurred.

     Hatching success of  fry  from eggs  spawned by fish exposed
to 49 yg/£ was significantly  less than  hatching success of con-
trol fry  (TABLE 23).
TABLE 23.  HATCHING SUCCESS OF  FRY  FROM EGGS  SPAWNED BY SHEEPS-
           HEAD MINNOWS  (CYPRINODON VARIEGATUS)  EXPOSED TO CAR-
           BOFURAN IN FLOWING,  SYNTHETIC SEAWATER.   MEAN PER-
           CENTAGE HATCH AND  STANDARD  DEVIATION  REPRESENTS
           POOLED DATA FROM SPAWNING PAIRS  IN DUPLICATE AQUARIA.
         Concentration     Percentage     Number of eggs
             (yg/&)	       hatch           examined
Control
6
15
23
49
98±3
99±3
96±10
98±2
86±10a
450
700
937
609
233
          aSignificantly  different  from the  control.

     Mortality of  fry hatched  from  eggs spawned by fish exposed
to 23 and 49 yg/2.  was significantly greater  than mortality of
control fry.  Growth of surviving fry  in all concentrations was
not affected, however  (TABLE 24).
                               29

-------
TABLE 24.  PERCENTAGE MORTALITY AND AVERAGE STANDARD  LENGTH OF
           30-DAY OLD SHEEPSHEAD MINNOW  (CYRPINODON VARIEGATUS)
           FRY WHICH WERE HATCHED FROM EGGS SPAWNED BY  FISH EX-
           POSED TO CARBOFURAN FOR 42-95 DAYS IN FLOWING,  SYN-
           THETIC SEAWATER.  MORTALITY AND LENGTH ARE AVERAGES
           OF FOUR GROUPS OF 40 FRY EXCEPT AS NOTED.
Concentration
(pgA)
Control
6
15
23
49
Number
of fry
160
160
160
120
80
Mortality
(%)
5
2
8
12a
41a
Length
(cm)
1.4
r. 3
1.3
1.4
1.4
         aSignificantly different from the control.

APPLICATION FACTORS

     Application factors were calculated from the  results  of the
acute and chronic toxicity tests  (TABLE 25).


TABLE 25.  CONCENTRATIONS  (yg/£) OF THREE PESTICIDES  TOXIC TO
           SHEEPSHEAD MINNOWS (CYPRINODON VARIEGATUS)  IN ACUTE
           AND CHRONIC TESTS, AND THE RELATIONSHIP OF ACUTE TOX-
           ICITY TO CHRONIC TOXICITY.
                 96-hour LC50
                (95% confidence                     Application
  Pesticide         limits)        MATC limits     factor  limitsa
Methoxychlor
Malathion
Carbof uran
49
(37-65)
51
(41-63)
386
(311-480)
>12<23
>4<9
>15<23
0.
0.
0.
24-0.
08-0.
04-0.
47
18
06
aDerived by dividing the Maximum Acceptable Toxicant  Concentra-
 tion limits by the 96-hour LC50.

     We find no application factors in the literature on which
to base a comparison of the sensitivity of sheepshead minnows
and any freshwater fish to methoxychlor or carbofuran.   For


                               30

-------
malathion, however, studies by Mount and Stephan  (1967) with
fathead minnows and Eaton  (1970) with bluegill show that the
application factors derived for all three fishes were  similar
(TABLE 26).
TABLE 26.  COMPARISON OF ACUTE AND CHRONIC MALATHION TOXICITY
           TO TWO FRESHWATER FISHES AND A SALTWATER FISH.
96-hour LC50
(ygA)
MATC limits
(ygA)
Application
factors limits
Fathead
minnows a
9,000
200-580
0.02-0.06
Bluegillsb
108
4-7
0.04-0.06
Sheepshead
minnows
51
4-9
0.08-0.18
    aFrom Mount and Stephan, 1967.
    bFrom Eaton, 1970.

SUMMARY

1.  Carbofuran was less toxic to  sheepshead minnows than were
    methoxychlor and malathion in acute tests.  Estimated 96-
    hour LCSO's, based on average measured concentrations in
    water, were 386, 49, and 51 yg/£, respectively.

2.  All three pesticides killed parental fish in concentrations
    <50 yg/£ during chronic tests, and the lowest concentrations
    of the pesticides in which toxic effects were observed were
    similar  (TABLE 27).

3.  The life stages of progeny from exposed parental fish that
    were sensitive to each pesticide were:  methoxychlor—embryo;
    malathion—fry; and carbofuran—embryo and fry.

4.  The relationship of acute toxicity and chronic toxicity for
    sheepshead minnows exposed to malathion  (as expressed by ap-
    plication factors) was similar to that for two freshwater
    fishes exposed to malathion.

5.  Sheepshead minnows are a suitable estuarine fish for toxi-
    city tests which include the  reproductive portion of the
    life cycle and the first generation.
                               31

-------
TABLE 27.  SUMMARY OF SIGNIFICANT EFFECTS  OF METHOXYCHLOR,
           MALATHION, AND CARBOFURAN  ON SHEEPSHEAD MINNOWS
           (CYPRINODON VARIEGATUS)  DURING  CHRONIC EXPOSURES
IN
Methoxychlor

Malathion

Carbofuran


FLOWING SEAWATER.
Generation Life stage
Parental Adult
FI Embryo
Parental Adult
FI Fry
Parental Adult
FI Embryo
Fry

Effect
Death
Decreased
hatch
Death
Increased
mortality
Death
Decreased
hatch
Increased
mortality

Measured-
concentration
>23
23
>18
9 and 18
>49
49
23
                               32

-------
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Anonymous.  1971.  Furadan® Insecticide—Namaticide.  FMC Cor-
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APHA, AWWA, and WPCF.  1976.  Standard methods for the examina-
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Cook, G.H., and J.C. Moore.  1976.  Determination of malathion,
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Coppage, D.L.  1972.  Organophosphate pesticides:  specific level
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Coppage, D.L., and E. Matthews. 1974.  Short-term effects of
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Eaton,  J.G.  1970.  Chronic malathion toxicity to the bluegill
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Eaton,  J.G.  1973.  Recent developments in the use of laboratory
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Eisler, R.  1970.  Factors affecting pesticide-induced toxicity
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Finney, D.J.  1971.  Probit Analysis.  Cambridge University
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                               33

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FMC.  1969.  Personal communication.  FMC Corporation, Agricul-
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FMC.  1976.  Personal communication.  FMC Corporation, Agricul-
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                                34

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                                35

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                               36

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                            TECHNICAL RCPORT DATA
                      (l'ii die rmJ ImLj-iii lioini u.'i tin' /ci c r\( In I"T i umi'li luii;!
 REPORT NO.
 ERL-GB-0010
                                                 3 RLCIPI ENT'S ACCtSSIO^* NO.
 TITLE AND SUBTITLE
 Chronic Toxicity of Methoxychlor,  Malathion,
 and Carbofuran to Sheepshead Minnows
 (Cyprinodon variegatus)	
          6. Pi.RFORMING ORGANIZATION CODE
 AUTHOHI5)
 Patrick R.  Parrish, Elizabeth E.  Dyar,  Mark
 A.  Lindberg, Chiara M. Shanika,  and Joanna M.
 Enos
                                                 0. PERFORMING ORGANIZATION RCPORT NO.
 PERFORMING ORGANIZATION NAME AND ADDRESS
 EG&G,  Bionomics
 Marine Research Laboratory
 Route  6'-,  Box 1002
 Pensacola, Florida   32507
12..SPONSORING AGENCY NAME AND ADDRESS
 Environmental Research Laboratory
 Office of Research and Development
 U,S.  Environmental Protection Agency
 Gulf  Breeze, Florida  32561
                                                 . REPORT DAT E
                                                  April 1977  (Issuing Date)
          10. PROGRAM LLEM1NT NO.

            1EA615
          11. CONTRACT/GRANT NO.


            68-03-0264
          13. TYPE OF REPORT AND PERIOD COVf RED
            Final
          14. SPONSORING AGENCY CODE


            EPA-ORD
15. SUPPLEMENTARY NOTES
16. ABSTRACT
     Sheepshead minnows  (Cyprinodon variegatus) were exposed  to each of
three pesticides—methoxychlor,  malathion, and carbofuran--in flowing sea
water to determine  the acute and chronic  (partial life-cycle)  effects.
     Mortality of adult  fish exposed to concentrations of  methoxychlor
>23 yg/£ and hatching success of fry from eggs spawned by  fish exposed to
23 yg/£ were significantly different from the control.  The maximum ac-
ceptable toxicant concentration (MATC)  was estimated to be >12<23 yg/£;
application factor  (AF)  limits were 0.24-0.47.
     Mortality of adult  fish exposed to concentrations of  malathion ~>18
ygA and mortality  of fry hatched from eggs spawned by fish exposed to 9
and 18 yg/£ were significantly different from the control.  The MATC was
estimated to >4<9 yg/£;  AF limits were 0.08-0.18.
     Mortality of adult  fish exposed to concentrations of  carbofuran >49
yg/&, hatching success of fry from eggs spawned by fish exposed to 49
vg/^f and mortality of fry hatched from eggs spawned by fish  exposed to
23 and 49 ygA were significantly different from the control.   The MATJC
was estimated to >15<23  ygA; AF limits were 0.04-0.06.
17.
                          KEY WORDS AND DOCUMENT ANALYSIS
               DESCRIPTORS
 Toxicity
 Fish
 Saltwater
 Pesticides
 Methoxychlor
 Malathion
 Carbofuran
                                      b. IDENTIFIERS/OPEN ENDED TERMS
 Chronic toxicity
 Flowing seawatfer
 Application factor
                                                            i1.  COSATI 1 i
13. DISTRIBUTION STATEMENT

 Release unlimited
10. SECURITY CLAbS / //llt'A'r/
    Unclassified
NO. Of F'AGt S
   36
                                      20 SECURITY CLASS t.Y'.'i/t / dy
                                          Unclassified
                                                             ''.>. TRICE

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