vv EPA
            United States
            Environmental Protection
            Agency
          Office of
          Solid Waste and
          Emergency Response
DIRECTIVE NUMBER:  99Q3.1

TITLE:
      Policy for Managing Leachate at PCB Landfills


APPROVAL DATE:

EFFECTIVE DATE:

ORIGINATING OFFICE:

0 FINAL

D DRAFT

 STATUS:



REFERENCE (other documents):
 OSWER     OSWER      OSWER
fE   DIRECTIVE   DIRECTIVE  Di

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          United States Environmental Protection Agency
                 Washington. DC 20460

OSWER Directive Initiation Request
                                                                   1. Directive Number

                                                                    9903.1
                                  2. Originator Information
       Name of Contact Person
           John A.  Moore
                                                Telephone Code
       3. Title
              Policy for Managing Leachate at PCB Landfills
       4. Summary of Directive (include brief statement of purpose)

               This policy guidance sets  forth requirements which apply to owners and

               operators  of TSCA approved landfills with regard to the management of PCB-

               containing leachates.
       5. Keywords
            PCB, leachate, TSCA §761.75 (b)(7)
       5a. Does This Directive Supersede Previous Directive(s)?
       b. Does It Supplement Previous Directive(s)?
                                          X No
                                            No
                                  Yes    What directive (number, title)
                                  Yes    What directive (number, title)
        Draft Level

           A - Signed by AA/DAA
          X  B •- Signed by Office Director
C - For Review & Comment
D - In Oevelopmen
8. Document to be distributed to States by Headquarters?
X

Yes


No
This Request Meets OSWER Directives System Format Standards.
9. Signature of Lead Office Directives Coordinator
10. Name and Title of Approving Official
Date
Date
      EPA Form 1315-17 (Rev. 5-87) Previous editions are obsolete.
   OSWER           OSWER                OSWER               0
VE    DIRECTIVE         DIRECTIVE         DIRECTIVE

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            UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

                       WASHINGTON. D.C. 20460
  JAN  I 6I98T                .
                                                  PCSTICIOCS ANO TOXIC SUMTA
 MEMORANDUM

 SUBJECT:  Policy for Managing Leachate at PCS Landfills

 FROM:      John A.  Moore              C)
           Assistant Administrator
             for Pesticides
             and Toxic Substances  (TS-788)

 TO:        Regional Administrators


      This policy guidance sets forth requirements which  apply to
 owners  and operators of TSCA approved landfills  with  regard  to
 the  management of  PCB-containing leachates.   There has been
 considerable discussion of  this  issue among  offices in
 Headquarters and the Regions and legitimate  points of view have
 been put forward on all sides of the issue.   However, it is
 necessary for the  Agency to have a  consistent policy  on  this
 matter  and therefore,  as National Program Manager for the TSCA
 PCB  regulatory program, I am issuing this policy guidance
 applicable to all  EPA PCB permits.                       ;

                            I.  SUMMARY

     Leachate from  TSCA approved landfills is properly regulated
under §761.75(b)(7)  of  the  PCB regulations.   The Regions have the
discretion  to  establish requirements for  leachate management
which are tailored  to the characteristics  of the leachates
present  at  specific  sites.   This approach  should ensure  that
leachates will receive  both  prompt  and environmentally sound
attention.

     This guidance  explains  the  basic  framework  for implementing
leachate management  under TSCA as an aspect  of the approval  of
chemical waste landfills  t-y  the  Regional  Administrators.
A.'ter a brief  discussion  about  leachate generation and its
characteristics, the memorandum  discusses  the guiding regulations
and policies  which  underlie  the  Agency's  approach to  managing
leachate.

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      Under  $761.75(b)(7),  leachates generated at TSCA approved
 landfills are  to be  treated to acceptable limits for discharge
 in  accordance  with State or Federal permits (typically NPDES or
 SPDES),  or  disposed  of by  other State or federally approved
 methods.  This provision is a signal to apply an "integrative"
 approach to leachate management which accounts not only for the
 TSCA  regulation of the PCS content of leachates, but also for
 other potentially applicable State and Federal requirements
 under the Clean Water Act  (CWA) and the Resource Conservation
 and Recovery Act (RCRA).  Also, the potential complexity and
 variability of leachate composition demands a flexible,
 site-specific  approach to the regulation of leachate
 management.  Effective integration of the applicable regulatory
 programs, as well as site-specific management requirements, can
be best  implemented through the inclusion of leachate management
 provisions  in  the conditions of approval for TSCA landfills.
 These conditions provide the enforceable standards governing
 leachate management at a permitted landfill site.  The Regions
 should include appropriate leachate management provisions in the
 conditions  of  approval for TSCA landfills that are now in the
 permitting  process or will be permitted in the future.   In
 addition, existing landfill approvals should be modified to
 incorporate such conditions.  These modifications ought to be
 accomplished without having to "re-permit" facilities;  i.e.,
 these modifications are not significant enough to warrant
 commencement of new permitting procedures.  Regions should plan
 to carry out the necessary modifications of existing landfill
 approvals within one year from the date of issuance of this
 guidance.

      The Agency's policy on leachate management requires:
 (1) That leachate be "characterized," i.e., subjected to
 sufficient  physical and chemical analysis in order to develop all
 the information that is necessary to treat or dispose of the
 leachater (2^  that based on the leachate's characterization and
on reference to available technical information, appropriate
 treatment processes or disposal methods be selected to accomplish
 environmentally sound management; (3) that treatment processes
 accomplish  necessary separation of PCBs from aqueous phases in
accordance  with any applicable effluent guidelines or pre-
 treatment standards in the facility's Clean Water Act permits;
 (4) that the management of the PCS-containing phases of leachate
be designed in all cases to maximize the separation of PCBs from
 aqueous phases into organic phases; (5) that treatment residuals
 and organic phases (especially those containing  >50 ppm PCBs) be
 disposed of by high-temperature incineration to the extent
possible, except when the material's characterization  suggests
 that  incineration is inappropriate; and  (6) that any PCB-
 containing  treatment residuals  (sludges or slurries) or  PCS-
containing  phases which ara not incinerated be  stabilized in
 accordance  with OSWER guidance on the  "Liquids  in  Landfills  Ban"
 .•>rior to being placed in chemical waste  Landfills.  Maximum
 integration and consistency with  RCRA management  standards  for
 azardous 'j>/astes is on ~s-  er.t al  element of this  colicv.

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      OPTS recognizes that some technical aspects  of this  subject
 may require further development.   The composition of leachate can
 be variable and complex,  and the  available  treatment technologies
 are numerous and evolving.   Upon  request, OPTS  will provide  the
 Regions with assistance concerning .these technical  aspects,  as
 well as assistance in drafting leachate management  provisions  in
 particular circumstances.

              II.  FRAMEWORK FOR LEACHATE MANAGEMENT

 A.   Leachate Characteristics

      Leachate is generated at a landfill when water and other
 liquids percolate through a  disposal  site.  Leachate  may have its
 source  in the liquid  fraction of materials  placed in the
 landfill,  but intrusions by  precipitation,  surface  waters, or
 groundwater may also  contribute to the  volume of  leachate
 generated.   As  these  liquids  percolate  through the  site, they
 transport with  them various  soluble and leach able components  from
 materials  buried at the site.  The design of the  landfill  (its
 susceptibility  to precipitation, run-on, or run-off), the  nature
 and  location of the substances placed in the landfill, and the '
 design  of  the leachate collection system all play a role in.
 determining  the  quality and  quantity  of  leachate  generated.   It
 is known  that the composition of leachate can be highly variable
 from one  site to another.  Even at a particular site, there are
biological,  physical, and chemical transformations  which can
cause the  leachate composition to vary  greatly over time.
 Because of  the  diversity of  constituents which can  appear  in  the
 leachate drawn  from chemical  waste landfills, a leachate
 treatment  system at a particular site must  be designed to  deal
effectively  with  the  various  constituents in the matrix in which
 they appear.  The management  of leachate, therefore,  is a  site-
specific  undertaking necessitating a  flexible regulatory
approach.

B-  Applicable  Regulatory Authority—40 CFR §761.75(b)(7)

     An examination of the PCS regulations  and the  rulemaking
records leads to  the conclusion that  40 CFR §761.75(b)(7)
provides the authority for regulating the management (treatment
and disposal) of  PCB  leachates.  With regard to leachate
collected at TSCA approved chemical waste landfills,  this
provision  specifies that:

     "The  leawhate should be  treated  to acceptable  limits  for
     discharge in accordance  with a State or Federal permit  or
     disposed of  by another  State or  federally  approved method."

    •This  language confers upon the Agency  the  discretion  to
approve, through  landfill approval conditions,  appropriate
treatment  processes and disposal rnethods for leachates  (and  any
treatr.ent  residuals).  It is  assured  that this  discretion  will be
exercised  in a  manner 'which  affords sound environmental

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 protection by integrating other applicable State and Federal
 regulatory programs.  Generally, this connotes integration of
 TSCA PCS management with any applicable Clean Water Act (CWA)
 facility standards (e.g./ effluent guidelines or pretreatment
 standards) for discharges to waterways or publicly owned
 treatment works, as well as hazardous waste management standards
 under the Resource Conservation and Recovery Act (RCRA) where
 hazardous wastes are also involved.

      Further regulatory support for addressing leachate
 management through approval conditions is found within 40 CFR
 761.75(c)(3)(ii),  which confers upon the Regional Administrators
 the authority to include in a landfill approval "...  any other
 requirements  or provisions that the Regional Administrator finds
 are necessary to ensure that operation of the chemical waste
 landfill does not  present an unreasonable risk to health and the
 environment from PCBs."  The control of leachate management
 .through  approval conditions is  necessary to  ensure that landfill
 operations  will not present such risks.

     At  the heart  of  this policy on leachate management is the'
 premise  that  §761.75(b)(7) of the PCS disposal regulations
 confers  upon  the Regional Administrators the discretion to
 approve  appropriate treatment processes and  disposal  methods for
 leachates and treatment residuals.   Appropriate processes  and
 methods  are those  that  will enable the facility owner or operator
 to  comply with any  applicable requirements  under other State and
 Federal  regulatory  programs (e.g.,  CWA and  RCRA)  as well as the
 goals  under TSCA for  the sound  environmental management of
 PCBs.  Significantly, PCB-containing leachates from TSCA-approved
 landfills are not regulated directly as PCS  wastes under
 §761.60(a); nor are they necessarily subject to §761.60(a)
 requirements  when removed from  the landfill  cell by required
 leachate collection systems.   Rather,  these  materials are subject
 co  the treatment and  disposal requirements  set out in the
 landfill approval conditions.  The rationale for this approach to
 leachate management is  as follows:

/         1.   Leachate  matrices may be quite complex  and
     variable,  so  subjecting such materials  to disposal
     requirements  which are based only on PCB concentration
 ..->' could  produce  results that are neither  feasible  nor
     ervironmentally  sound.  Were §761.60(a) the sole
     authority governing leachate nanagement,  any leachate
    . c^-  residual with >50 ppm PCBs would be subject to
 •"'   incineration  requirements, regardless  of its
     suitability for  incineration.  These materials may
     require  considerable treatment before they will  be in a
     form suited for  incineration, and for some .materials,
     effective treatment may be that which stabilizes it in
     preparation  for  landfiiling.  In any case, utilizing
     5761.75(b)(7)  as the authority for approving treatment
     processes avoids the administrative burdens which would
     occur  under a  5761.60 ascrcacr.  L'nder 5761.60,  the

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 Agency would have to issue separate  "alternative
 disposal" permits under §761.60(e) in o.rder to  approve
 the routine physical separation  processes  required  in
 the handling of leachates.   Moreover,  the  philosophy
 applicable to typical PCB disposal is  not  always
 appropriate to the management of leachate.   The
 presence of PCBs  as a leachate constituent  is but one
 factor which should be considered in determining the
 proper disposition of leachate;  other  factors (e.g.,
 high  ash content,  presence  of  heavy  metals)  may lead
 one to conclude that incineration is not appropriate.
 Also,  in the course of  treating  complex leachate
 matrices,  it may be appropriate  to mix compatible
 materials  and perform treatment  processes  that  might be
 construed  as prohibited dilution under the
 concentration-based PCB disposal requirements.
 Integration  of regulatory requirements and the
 necessities  of sound leachate  management argue  in favor
 of  an  approach recognizing.greater discretion than  is
 possible under the direct application  of §761.60(a)
 incineration requirements.

      2.   The record-for the PCB  Marking and  Disposal
 Rule supports  the  conclusion that leachates  were
 intended to  be a category of material  distinct  from the
 "PCB wastes"  regulated under the concentration-based disposal
 requirements of §761.60(a).  As  explained  in the proposed
 Disposal Rule  (42  Federal Register 26564 et  seq..),  the
 working  definition for the  purpose of  applicability of PCB
 disposal requirements was the  definition of  "PCB mixture,"
 as  that  term was defined and explained in  the regulations'
 and proposed  rule  preamble.  The later deletion (during the
 issuance of  the final  1979  PCB Ban Rule) of  the "PCB
 mixture" definition  in favor of  the  more general definition
 of  "PCBs" was  not  done with the  purpose of broadening th.-s
coverage of  the disposal requirements beyond the types of
 materials  (the "PCB mixtures") described in  the 1978
 Disposal Rule.  The  fullest  exposition on  the scope of the
 "PCB mixture"  language appears in the  proposed  Disposal Rule
 preamble  (42 Federal  Register  26565,  26566), and it is clear
 that, leachates  do  not  fit within any of the  classes of
 "commercial  applications"  (coolants,  dielectrics, etc.) or
other  "wastes"  described as within the intended scope of1
these requirements.   The Disposal Rule contemplated a
universe of  "wastes"  consisting  of PCB mixtures contaminated
 with PCBs on account  of:   (1)  Purposeful -c'ommercial uses  of
 PCBs  (e.g.,  as a hydraulic  fluid, dielectric, or wax
 extender),  (2)  incidental  exposure to  PCBs during commercial
 activities  (e.g.,  inadvertent  contamination of  mineral  oil
 during servicing of transformers), or  (3)  environmental
 exposure to  PCBs  from accidents  and  spills.   (See  42  FR
 26565).  It  is  for  these relatively  simple "PCB waste"
matrices that  §761.60 impose-s  rational and effective
disposal requirements.

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           3.   An interpretation holding that-, PCS-containing
      leachates are regulated under §761.60(a)  disposal
      requirements would render meaningless the clear command of
      §761.75 to allow either the treatment of  leachates or
      .disposal in accordance with other State or federally
      approved methods.   If these treatment and disposal luethods
      were intended to be limited only to high-temperature
      incineration (based on PCB concentration),  the leachate
      regulation would have specified this result.

           4.   In addition, it is critical to note  that the PCB
      regulations routinely and expressly reference §761.60
      disposal requirements when such disposal  is the intended
      result.   The reference in the leachate management provision
      to "another State  or federally approved method" is a
      significant deviation from this routine practice.   Such
      deviations appear  in the Disposal Rule record for only a few
      types of materials—leachate,  and materials drawn from
      groundwater monitoring wells (required to be  "treated to  •
      meet applicable State or Federal discharge standards or
      recycled to the landfill") [40 CFR §761.75(b)(6)(ii)].   By
      referencing other  State and Federal methods for leachates,
      the Disposal Rule  followed an approach which  was recommended
      for the  regulation of other, lower concentration PCB
      materials such as  PCB-containing dredge spoils and sewage
      sludges.   For such materials,  the Disposal Rule racord
      explains that environmental management through the effective
      integration of a variety of State and Federal regulatory
      programs was considered to be the most desirable approach.
      (See 42  FR 26565r  see also, 43 FR 7151).   In  light of the
      leachate provision's express reference to State and
      federally approved methods, and these other contexts in
      which the Disposal Rule record refers to  other regulatory
      programs,  the leachate provision's express language is
      properly construed as a signal to regulate PCB leachates
      with deference to  the requirements of other applicable
      regulatory programs,  including CWA and RCRA.

C.  Maximum Integration With RCRA Management Standards

      A major  emphasis of this guidance is integration with RCRA
management  standards  for the treatment and disposal of hazardous
wastes.   This  emphasis  is essential to the effective
implementation  of  leachate management at TSCA  permitted
landfills.

      Leachate  matrices  can be expected to contain  constituents
which are regulated  under RCRA as hazardous wastes.  Under RCRA
regulations,  leachates  generated from the Landfilling of "listed"
hazardous waste or  leachates which  exhibit one or  more of. the
hazardous waste characteristics  (i.e.,  ignitability.  corrosivity,
reactivity, and Extraction Procedure tcxicity) are hazardous
'wastes.   Also,  ?C?A  defines  ^ mixture of hazardous, ^aste and

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  other waste to be itself a hazardous  vaster  so, a leachate
  mixture containing PCBs  and  hazardous waste  is defined as RCRA
  hazardous waste.   These  leachates are subject to RCRA standards
  for hazardous waste management, including those for treatment in
  surface impoundments and tanks.

       The RCRA regulations dealing with treatment facilities
  (surface impoundments, tanks) are well suited for the control of
  leachate treatment.  For leachates that are  RCRA hazardous
  wastes,  the requirement  to characterize leachate prior to
  treatment is supported by 40 CFR §264.13, which requires the
  owner or operator of the facility to  obtain  a detailed physical
  and  chemical analysis of a hazardous  waste prior to any
  treatment.   At a  minimum, the analysis must  contain all the
  information which must be known to treat the waste in accordance
  with regulatory requirements.  Records of the analyses obtained
  and  the  treatment processes  performed must be kept at the
  facility.   Other  RCRA requirements (see Appendix I of 40 CFR,
  Part 265)  impose  additional  recordkeeping requirements in
  connection  with waste treatment.  While not  all leachates will .
  contain  hazardous  wastes, TSCA permit writers are advised by this
  policy to use  their approval authority to incorporate analysis
  and  records  requirements such as those under RCRA in their TSCA
  conditions  of  approval for leachate management.

      Also,  since  the currently operating TSCA approved landfills
  are  generally  units of larger landfill facilities regulated under
.  RCRA, the  treatment systems  in which  leachates may be treated are
  likely to consist  of the  landfill facility's associated tanks or
  surface  impoundments.  In addition to treatment units associated
 with landfills, RCRA regulations recognize that hazardous wastes
 may also be  treated:  (1) At surface  facilities associated with
 injection wells that dispose of hazardous waste,  (2) at
  "wastewater  treatment units" (as defined at  40 CFR §260.10), and
  (3) at other facilities  regulated pursuant to discharge
 conditions  in NPDES permits  [see 40 CFR §270.l(c)].

      PCB-containing leachates often will consist of hazardous
 waste mixtures, and in such  instances, it is entirely proper for
 treatment to take place  in facilities recognized as appropriate
 under RCRA.  Indeed, in  the absence of TSCA  design and operation
 standards for surface impoundments and tanks, this policy
 recommends that TSCA permit writers generally use their .-.pproval
 authority to approve treatment in the RCRA approved facilities.
 However, under this policy,  the primary goal of leachatf
 management is to ensure separation of PCBs from aqueous materials
 into an organic phase which may be segregated and, where
 appropriate, incinerated.  Therefore,  while  off-site treatment
 may be suitable for many aqueous materials,  this policy
 encourages TSCA permit  writers  to  require on-site treatment at
 least to the extent of  the separation and/or filtration processes
 necessary to ensure the  initial,  ad-equate seoaration of PC3s from
 aqueous  materials.  In  other  words,  approval  to transfer
 Laachatss- to off-site  facilities ( e . c . , wastewater treatment

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                                 3
 units or injection well facilities)  for additional  treatment
 should be limited only to the treatment of aqueous  phases from
 which PCBs have been initially separated to t"he satisfaction of
 the TSCA permit writers.   The extent of separation  that may  be
 required prior to allowing off-site  treatment  is  a  matter which
 must be determined on the basis of available treatment
 technologies and the complexity of the  leachate matrix.

 D.   Role of Incineration  In Leachate Management

      The discussion above in Part  II B  regarding  "appropriate"
 treatment and disposal  methods  emphasizes  that  leachates  are not
 subject  directly to the §761.60(a)(1) incineration  requirement.
 That  discussion  should  not be construed  to  suggest  that the  role
 of  high-temperature incineration in  destroying  PCBs is  diminished
•in  the  leachate  management  context.   This  policy  underscores the
 point that whenever PCBs  can practically be isolated by treatment
 in  an organic phase amenable to incineration, the TSCA permit
 writers  should use their  approval  authority to  require this
 disposal method.   Since the  outset of the  TSCA  PCS  disposal
 program,  the Agency has designated high-temperature incineration
 as  the  primary disposal method  for PCBs.   The  disposal
 requirements of  §761.60(a)  reflect this  policy  by directing
 most  PCB wastes  to incineration.   While  leachates are  not
 "PCS  wastes," the goals of  leachate  management  at landfills
'should also  reflect the policy  favoring  destruction of PCBs
 rather than  long-term containment.   The  PCB disposal requirements
 of  §761.60(a)  provide a useful  guide for approval conditions
 requiring  the incineration  of PCB-containing materials  (>50  ppm),
 unless the characterization  of  the material indicates  that the
materials  are not amenable  to incineration.
                      i
      Of  course,  the TSCA  permit writer's discretion to  approve
appropriate  treatment and disposal methods  for  leachates  extends
to  approving treatment  which does not result in PCB destruction,
 including  treatment which results  in stabilization  and
landfilling.   Where leachates are also hazardous  wastes,  such
treatment  is conditioned  upon .compliance with  the "Liquids  in
Landfills  Ban"•and the  OSWER guidance implementing  the
prohibition  of landfill disposal of  bulk liquids  and  free liquids
in  containerized  waste.   This guidance  generally relies upon the
 "Paint Filter Liquids Test"  to  determine when  prohibited liquids
are present,  and  it uses  an  "unconfined  compressive strength
test" to  determine whether  liquids (hazardous  wastes)  have been
adequately stabilized to  allow  their placement  in landfills.
 (See  OSWER Policy Directive  #9487.00-2A, June  11, 1986).

      TSCA  permit  writers  should follow  the OSWER guidance
implementing the  "Liquids in Landfills  Ban" in prescribing
conditions on the placement  of  any PCB-cor.taining materials
 (derived  from leachate) in  chemical  waste  landfills.   The Paint
 Filter  Liquids Test and uncon.fined corr.press i ve strength test
 should provide objective  criteria  for approving  landfill disposal
 of  residuals (i.e.,  sludses  and slurries)  -which cannot reasonably

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 be subjected to incineration.  Materials which have been
 sufficiently stabilized under these tests may be landfilled
 regardless of PCB concentration.

 E.  Leachate Management In the Landfill Approval Process

      While the incorporation of leachate management into the
 approval process for TSCA approved chemical  waste landfills will
 increase the complexity of the permit writer's task,  the
 discretion accorded to the Regional Administrators  is
 sufficiently broad to allow a variety of possible solutions to
 the management  challenges  posed by a given leachate.   This
 guidance emphasizes that the goal  of the permitting process with
 regard to leachate management is not to seek out any one,  "ideal"
 treatment system;  nor is leachate  management intended to be a
 "technology-forcing" device that would justify great expenditures
 for research and development by owners and operators of
 landfills.  Rather,  the goal of this guidance is to assure  that
 leachate management is accorded adequate consideration by being
 addressed in the permitting process.   The objective of the
 approval process is to assure that leachate  management is both
 prompt and environmentally sound.   The discussion which follows
 is intended only to  suggest how the process  might be implemented;
 it is  not intended  to constrain rigidly the  permit  writer's
 discretion.

      1.   The first  requirement 'in  any  leachate management
 scenario should be the requirement  that the  leachate  be
J*characterized," i.e.,  a requirement that the leachate be
 subjected  to sufficient physical and chemical  analysis  in order
 to develop  all the information that is necessary to treat or
 dispose  of the leachate.   For hazardous  wastes,  characterization
 requirements can be  readily imposed on the basis of RCRA waste
 analysis  requirements.   (40 CFR §264.13,  §265.13).   Approval
 conditions  should include  characterization requirements in  every
 case,  modeled after  the RCRA analysis  requirements  discussed
 above.   At  new facilities  (for which there is not yet leachate to
 characterize), one might attempt to project  the leachate
 composition  (on the  basis  of the wastes which will  be managed" at
 the facility) and impose interim treatment and disposal
 requirements.  Or, where collection and storage capacity is
 adequate,  characterization may be  deferred until there is actual
 leachate on-hand to  manage.

     2.   Based upon  the results  of  the leachite
 "characterization,"  one  should refer to the  available technical
 guidance  and other  literature  to determine the types of treatment
 processes  which are  likely to  be effective in treating the  given
 Leachate  constituents.   Ideally, several unit processes could be
 combined  into a  treatment  train or system providing the most
 effective  level of treatinent.   There are a variety  of physical
 and chemical treatment proces- es which nay be of benefit in
 treating  the various organic   •"? :. "organic constituents which may
 be found  in  leachate.   Siclt   ":  •-.::eat.-?.ent:, activated carbon

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 adsorption,  ion exchange,  chemical precipitation and
 flocculation, reverse osmosis,  oxidation and reduction processes,
 etc.,  are a  few examples of treatment processes  discussed in the
 literature.   For a more detailed description of  these processes
 and their limitations,  see the  Office of Solid Waste Document
 SW-871,  "Management of Hazardous Waste Leachate."

      3.   An  effective early step in managing PCB-containing
 leachates will consist of  density separation processes.   Since
 leachates are essentially  aqueous streams containing suspended or
 dissolved contaminants,  density separation  will  facilitate the
 segregation  of PCBs in  an  oil phase,  in a vater/dissolved solids
 phase, in an emulsion phase, and in a phase consisting of
 settleable solids.   The greater affinity of PCBs for the  "oil" or
 organic  phases suggests a  management scheme which  directs the
 PCBs in  the  organic phases to high-temperature incinerators
 (where characterization indicates that incineration  is
 appropriate),  while subjecting  the aqueous  phases  to additional
 treatment.   Effective management must also  provide for the
 characterization  and appropriate disposal of treatment residuals,
 such as  slurries  and sludges.   When these residuals  cannot
 reasonably be incinerated,  OSWER guidance on the "Liquids in
 Landfills Ban"  should be consulted as a reference  for
 stabilization criteria.

     4.   In  addition to the discretion which exists  to approve a
 variety  of treatment processes,  the Regional Administrators
 possess  considerable discretion insofar as  the level of
 penrdtting oversight over  the details of leachate  management.
 Where characterization  indicates that leachate composition is not
 complex,  it  may be  reasonable to impose simple management
 requirements based  largely on the PCS disposal requirements of
 §761.60.   A  simple  leachate matrix may consist essentially of
 materials  resembling a  "PCS mixture," or, treatment  may
 accomplish the  segregation of such materials.  In  such cases, the
 concentration-baafed disposal requirements of §761.60 ar:-•'
                                            \           fs'
     5.   Approved treatment of  leachates must occur  in facilities
 (e.g.,  RCRA  surface impoundments and iianks) approved by Regio:;al
 Administrators  under operating  conditions deemed neceasarry to
ensure protection against  unreasonable risks.  For existing
 facilities,  the "selection"  of  appropriate  leachate  treatment
processes may consist of upgrading an existing treatment  system
used for  treating hazardous wastes to assure the early and
effective  separation of  the PCBs from aqueous phases.  In
corr.-r-r. ir • -v-L^"-  .he separation  processes, approval may also
 ir.v '       •••cz..-   performance standards to assure that an  existing
 £'/•= •   '    -  •    'to maximize  its effectiveness in  treating
 0 "                 .-v^c,  TSCA ancrovai authoricv  enables the

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 Regional Administrators to require an owner or operator of a
 facility to demonstrate the efficacy of its treatment system.
 The results of any demonstration could justify the imposition of
 performance standards governing such factors as feed rates,
 removal efficiency of separators, required PCS concentration
 levels after filtration, and the like.

      6.  Both RCRA and TSCA regulations provide authority for
 including approval conditions restricting the commingling of
 incompatible materials.  TSCA landfilling provisions state that
 throughout the waste handling and disposal process for PCBs, the
 owner or operator must segregate other wastes (including
 solvents) that are "chemically incompatible" with PCBs.  [40 CFR
 §761.75(b)(8)].   Likewise,  RCRA treatment standards prohibit the
 simultaneous treatment of  "chemically incompatible" wastes,  which
 RCRA regulations  define as  wastes which,  when mixed,  will
 produce:   (1) Heat or pressure,  (2)  fire or explosion,  (3)
 violent reaction,  (4) toxic dusts, mists,  fumes,  or gases,  or
 (5)  flammable fumes or gases.   (See  40 CFR Part 265,  Appendix V).
 In addition  to conditions dealing with these examples of
 incompatible mixes,  the "incompatible waste"  language provides-a
 basis  for conditions  prohibiting the  commingling  of PCB leachates
 with other materials  which  would undermine the goals  of this
 policy.  For example,  once  treatment  has  accomplished segregation
 of PCBs  into the  organic phase,  one might prohibit further
 treatment that involves any commingling with  organic  solvents
 which would  enhance the subsequent leaching of PCBs from that
 leachate matrix.   Also,  during initial  treatment  processes,       <-
 conditions may be  included  prohibiting the commingling  with other
 waste streams  (e.g.,  heavy  metals) or materials which would
 affect  adversely  one's ability to efficiently segregate the PCBs
 from aqueous phases,  or which would  unnecessarily render the PCBs
 into a  form  unsuited  for incineration.   However,  neither these
 regulations,  nor  the  "anti-dilution"  language of  40 CFR §761.l(b)
 provide  the  basis  for prohibiting all types of mixing in the
 course  of treatment.   Commingling with other waste streams and
 the  materials necessary for approved  treatment is permissible as
 long as such commingling is  consistent  with effective treatment
 and  does not serve  to defeat the goals  of this policy.

 F.   Dealing  With Leachate From Pre-TSCA Landfills

     When EPA issued  its PCB disposal regulations, it did not
require that PCBs and  PCB Item?  placed  in landfills and dumps
prior to February  17,  1978,  be removed  for disposal.   (See Note
preceding §761.60).   PCBs disposed of in  pre-1978 ("pr--TSCA")
disposal sites are  considered to be  "in service," and there is no
T.SCA authority at this  time  to impose PCE disposal requirements
on these materials  until the wastes  are "removed" from  the
disposal site.

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                                 12
      Although the leachate management provision [40 CFR
  §761.75(b)(7)] provides ample authority and discretion to deal
  with the PCB leachates generated at TSCA approved landfills, this
  provision is not applicable to the leachates collected front pre-
  TSCA disposal sites.  Nevertheless, there are compelling policy
  reasons for handling leachates collected from some pre-TSCA
  disposal sites in a manner consistent with that for TSCA
  landfills.   First,  such leachates may also be found in complex
  forms which do not  resemble the simple "PCB waste" matrices
 intended to be covered by §761.60 disposal requirements.   Indeed,
 these materials are likely to be more complex than the leachates
  from TSCA approved  landfills.  So, these material^, may require
 considerable treatment before the PCBs will be irf^a form amenable
 to incineration.

      Second, such disposal sites are commonly encountered at
 landfill facilities which contain, in addition to active  cells
 currently receiving or managing chemical wastes,  inactive or
 closed  landfill units  which received their wastes prior to the
 effective date of TSCA or RCRA disposal  requirements.   These
 units were  neither  designed nor operated to comply with current
 regulations aimed at minimizing run-on and run-off,  protecting
 surface waters and  groundwater,  segregating incompatible
 materials,  and restricting free liquids  and leachable
 components.   These  pre-TSCA units present unique  post-closure
 care challenges,  including the management of their leachates,
 some  of which  may present  very complex matrices,  and may  contain
 PCBs  at relatively  high concentrations.

      In these  instances,  the practical necessities of  sound
 leachate management  argue  even more urgently for  the discretion
and prompt attention which  may be realized  through the  approval
process  reflected in this  guidance.   Also,  these  facilities
 (operating facilities which  include inactive or closed  pre-TSCA
units)  are the  ones  that  are likely to possess the means  and the
incentive to collect and manage  leachates emanating  from  their
pre-TSCA disposal sites.   Collection of  such leachates  may be
compelled by State permitting  authorities under the  terms of a
general  facility  permit, and  under new RCRA authority  [§3004(u)],
facilities could be required  to collect  Leachates  from  any
inactive waste management  units which generate releases requiring
"corrective action."  Although TSCA does  not provide express
authority for compelling the  collection  of  leachates from pre-
TSCA disposal sites, a pjlicy  regarding  their maiagement  which
enables them to be promptly  and  efficiently deaJ i with  may
promote their responsible  management  prior  to the generation of
"releases" requiring remedial  action.  While these materials are
not subject directly to §761.75,  it is clear that a  similar
approach to their management (i.e.,  approval of  appropriate
treatment and  disposal) would  best accommodate them.

     Therefore,  leachates  removed from pri- -TSCA landfill cells
may be  managed, upon approval,  at these  f-  ilities using the
treatment processes  approved under the fa  lity's TSCA landfiiL
oernits.  As a  colicv matter,  th:'.3 aocroc.   should create

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 sufficient  incentive  to bring  these  materials  within  the  approval
 process where they can be dealt  wi ih most appropriately.

      Of course,  these leachates  must be  characterized in  the same
 manner as §761.75 leachates, and where characterization suggests
 that these  leachates  may  be  chemically incompatible with  other
 leachates or wastes,  approval  conditions may prohibit commingling
 or  impose additional  treatment requirements.

                         III.  CONCLUSION .

      The leachate management policy  announced  in this guidance
 should  enable  leachate problems  to be  addressed with  the
 flexibility  necessary to  produce workable  solutions which are
 fully protective  of health and the environment.  Of course, the
 implementation of  this policy  will present  several administrative
 and  technical  challenges, including  the  obvious need  to develop a
 familiarity  with  the potentially effective  treatment  technologies
and their limitations.  Also, since the  policy announced here is
an "integrative" one, it will require  analyzing leachate issues
more comprehensively than is usually dene for the more
traditional  PCS waste issues.  Likewise,  it may require some
actual experience with the policy to develop and improve the
means and procedures by which a  site-specific approval process
can be worked  into the TSCA permitting of PCS  landfills.  OPTS
will work with the Regions to help surmount these difficulties.

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