EPA-AA-EOD/ES-83/1
                         Technical  Report
              Humidity Measurement Comparison Tests

                       Dew  Point  Hygrometer
                               vs.
                      Wet Bulb Psychrometer
                         Sherman D. Funk

                           January  1983
                              Notice

    This  Report  does   not   necessarily  represent  final  EPA
decisions or  positions.   It  is  intended  to  present  technical
analysis  of   the   issue   using  data   which   are   currently
available.  The  purpose in the release of  such reports  is to
facilitate the  exchange of technical  information and  to inform
the public  of technical developments  which  may  form  the basis
for a final EPA decision, position or regulatory action.

    This  document  has been approved  under the  EPA peer review
process and is available for internal and external distribution.
                        Engineering Staff
                 Engineering Operations Division
                     Office  of  Mobile  Sources
               Office of Air, Noise, and Radiation
               U.S.  Environmental  Protection Agency
                        2565 Plymouth  Road
                    Ann  Arbor,  Michigan  48105

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Abstract

    A series  of  comparison tests were  made  to characterize and
quantify causes of differences  in results  between  the dew point
hygrometer  anC  the wet  bulb  psychrometer methods  of measuring
humidity.   The  EPA  Laboratory  is  implementing  the dew  point
hygrometer  method  in  the Light  Duty  test  cells.   Tests  were
necessary  in  order  to  identify  any  potential  impact  on  test
results.   This  study provides  supportive data  to  address  the
test procedure comparability aspects of EPCA.

    The  results  of these  tests indicate  that  the pyschrometer
specific humidity indication will average  approximately 5 gR/lb
higher  than the dew point  hygrometer.   The major causes of this
error  are  the  wick  water  temperature  and  ventilating  air
velocity.

Introduction  (Background)

    The  Energy and  Policy Conservation Act  of 1975 and letters
dated February 1980  from the  EPA Administrator  to  Ford and GM
establishes  policy  that  mandates  the  EPA  laboratory  to  use
procedures  for testing  vehicles for  fuel  economy  that are the
same  as those  utilized  for  the 1975  model  year.  Provisions
were  made   by Congress  to allow  test  procedure  changes  that
would  improve  the  test  accuracy  and reduce  variability  of
emission and  fuel  economy measurements as  long  as  there  is no
significant  impact  on  Corporate Average  Fuel  Economy  (CAFE).
However, the  sensitive nature  of any  such  change necessitates a
quantification of the results of the action.

    The  EPA laboratory has  been in  the  process  of developing
and  installing new  ambient monitoring  instruments  in the Light
Duty  test   cells  that  will  be  interfaced   to   the  real  time
Laboratory  Computer  System  (LCS) .   One  of  these instruments,
the dew  point hygrometer will  replace  the  wet bulb psychrometer
for  measuring  humidity.   Studies  performed and  reported  in
December 1980, data  samples  taken  from official  tests  in 1982,
and  recent  direct  comparison  tests indicate  differences in the
results  of  these   two  measurement  methods.   The  comparisons
showed   the   wet   bulb   psychrometer   humidity  results  to  be
approximately 5 grains  higher  than  the dew  point results.   The
study of 1980 indicated that  the major differences were caused
by  the   wick  water  temperature and  low  air velocity  of  the
psychrometer.   In  order  to provide additional confirmatory and
supplemental  data that relate  to  these measurement differences,
another  series of  comparison  tests was designed  and performed.
This paper  reports the results of that study.

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Theory of Operation
    The wet^a-fld  dry bulb psychrometer and the condensation type
dew  point indicators  are two  distinctly different  methods  of
measuring humidity.
    The basic~form of a wet and dry  bulb psychrometer uses two
thermometers.  The bulb  of  one thermometer  is  covered  with  a
moistened  wick  and  is called  the  wet  bulb.   The bulb  of the
other  is  left bare  and  is  referred  to  as  the dry  bulb.   The
accuracy  of  humidity  measurements  requires  these thermometers
to  be  closely  matched.   The  evaporation  of   water  from  the
moistened wick of  the wet bulb  thermometer  produces  a lowering
in  temperature.   The  thermometer may be ventilated  by  a sling
or  forced air circulation.   Ventilation should be  provided  to
the  wick  at  a minimum velocity of 900  feet per  minute.  (See
Reference 4-NBS Circular 512) .

    Using  the   reading  of   the   two   thermometers   and   the
barometric pressure,  the  humidity,  specific  and/or  relative,
can   be  determined.    Specific   humidity   is   calculated  by
determining  the  saturation  pressure  of  water vapor  at  the wet
bulb  temperature   by  a least  squares fit  of Keenan  and Keyes
steam  table  and  the partial  pressure of  water  vapor  at  the dry
bulb   temperature.   These   are  determined   by  equations  as
recommended  by  Wexler  and  Greenspan  in  the  NES paper  "Vapor
Pressure  Equation  for  Water  in the Range of  0  to  100°C" and by
Eric   Zellin  in   "Procedures  for  Calculating  Humidity"  (See
Reference) .

    The condensation  dew point method of measuring  humidity is
a  fundamental  technique by  which  a  surface  is cooled  until  a
dew  layer is formed  on that  surface.   The  temperature  of the
surface at that point  is  called  dew point temperature.  The dew
point  temperature  is  defined  as that  temperature to which water
vapor  must be  reduced to obtain saturation vapor  pressure  or  a
relative  humidity  of  100 percent. The  unit discussed  in  this
paper  is  an  optical  condensation  type  dew  point meter.  With
this unit a  sample of  air is  drawn  across a mirror surface at a
flow rate of 2.0  SCFH.  The  mirror is  cooled by  thermoelectric
heat   pump   action  until  a   dew   layer  is   formed  by  the
condensation of moisture  from  the  sample air.   A  beam of light
from an LED  is  directed at the mirror  which  reflects the light
to a photo cell.   The  photo  cell detects the light and produces
a  corresponding  current.  When the  dew  layer  is  formed,  the
reflectance  of  light will sharply  decrease  causing  a decrease
in  photo  current.    The  system is  designed  to  control  the dew
layer  in  a   feedback  contol  loop by  heating  or cooling  of the
mirror surface.  This heating or cooling  is referenced to a 40

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percent  (40%)  decrease  in photo current  level  from a clean dry
mirror  condition.   The  temperature of  the  mirror  surface  is
measured  by-~a  platinium  RTD  thermometer  with  a  specified
accuracy  of_i 0.4°F,  is displayed  on  a  digital  meter  and  is
read  by the-- Laboratory  Computer System.   This reading  is the
dew  point temperature and  is  used to  calculate  the  specific
humidity  from  the partial  pressure  of  water  vapor  at  that
temperature and the barometric pressure.

    For the  data analysis of  this  experiment, the dew point has
been used to  represent the correct  humidity.   The dew point was
verified  by  an  ice  bath  closed  loop  coil  technique  that
produces a dew point of 32°F.

Test Plan

    A  series of  32  test  sequences was  developed  for  various
combinations  of  conditions  to  characterize  the  differences
between  the   wet  bulb and  the  dew point  humidity measurement
methods.   Psychrometer  air   velocity,   wick  exposure,   water
temperature  and  level,  and humidity levels were  varied  in the
test  plan.    The   test  set  up  consisted  of  a   Sargent  Welch
psychrometer  frame,  a flexible  hose,  and  adapter chamber, the
laboratory  ventilation  system  with an  adjustable  damper,  a
mercury  thermometer  (certified  accurate  and  readable  to  _+
0.2°F),  a  cotton   wick,  a  mercury thermometer   (readable  to
0.5°F)  matched  to  the certified version,  a type J thermocouple
and   recorder,   a   Thermo  Systems  Model   1650   heater  wire
anemometer,  and  a  General  Eastern Model  1200  APS dew point
meter.  The  equipment was  set up in the  Gas  Blending room (See
Figure  1).

    Simultaneous humidity measurements  were  made  using  the two
methods under  the  combinations  of   conditions as  shown  on Table
C.   Sock  up  means the  wet  bulb   was  entirely covered  in the
tube.   Sock  down  means  the   sock was  moved  down   on  the
thermometer  3/4"  from  the  top  of  the  tube.   Test conditions
included  the  reservoir  full,  and  1/2  full,   the wick  water
temperature  at  ambient  and within  _+2.0  degrees F from  the wet
bulb  temperature,  and  with  low  (450 FPM) ,  medium  (700  and 900
FPM)  and  high  (1300 and   1500  FPM)  air  velocities   of  the
psychrometer.  The  points where  the wick  water  was below the
wet bulb temperature were later deleted from  the data.

    The  readings  were  taken by  two  operators.   The  readings
made  by  SF   were   taken   with  a  magnified  jewelers  glass.
Measurements  were  also  taken  of   four  room humidity  settings
using  ambient  water  temperature,   air   velocity  at  900  FPM,
reservoir   full,   and   the   sock  completely   covering   the
thermometer  inside the  tube.    These  specific  humidity  levels
were approximately 80, 70,  50 and   35 grains  of water per pound
of  dry  air.  The first set  of  tests were made  on 11/30/82 and
12/1/82  and  consisted  of   six   readings   each.    A   set  of
confirmatory  tests   were   run  on  12/1/82   and   12/2/82  and
consisted  of  three   readings   for   each  condition.   The  room
humidity  level comparisons  were  run  on  12/3/82  and  12/9/82.
All  readings  taken were  approximately  2  minutes  apart  in each
sequence.

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Discussion (Summary of Test Results)

    The attached tables show the results of  the  tests.   Table A
shows the  te|t  plan overview and  includes  the  average  humidity
at each setTdf  indicated conditions.  Table  B shows  the average
effect of  each  parameter.   The average was  determined  from all
the pairwise differences involving the  parameter.   The  original
and confirmatory tests indicate the following:

    Increasing  the  air  velocity  from  450  to  1500  feet  per
    minute  in  steps  of  300  feet   per  minute  decrease  the
    measurement difference  at  both the  cold and  ambient  water
    temperature an average of 1.29  gr/lb.

    Decreasing  the water  temperature  from  ambient  to   the  wet
    bulb temp  or   up  to  2°  above  decreases the differences  at
    the air velocities tested an average of 3.55 gr/lb.

    With  all  other  conditions  at optimum  (sock  up,  standard
    humidity  level,  and  full  reservior),   increasing   the  air
    velocity to  the recommended level  or decreasing the  water
    temperature to the  wet bulb  temperature)   separately  will
    cause  a  decrease  in  the error  but will  not eliminate  it
    completely until all three conditions are optimized.

    As shown  in Table  B,   total  bias  caused  by  low  velocity,
    ambient  water,  low   reservoir  and   sock   not   completely
    covering the  bulb in  the  tube  can cause  the wet  bulb  to
    read about  1  grains/lb.  higher   than  the  dew point.   The
    typical bias  would  be at  the lower air velocity,  ambient
    temperature water,  and  a   half  full  reservior.   At  these
    conditions  the  psychrometer  reading   would   average  5.2
    grain/lb.  higher.

    Although  the  test  did  not   address   this  point,  type  J
    thermocouple accuracy  tolerance can introduce  an additional
    + 2.0  grain  error.   Since the wet  bulb  sensitivity  is +2.5
    gr./lb. per  +1°F,  an   accuracy  spec of  +.75°F on  Type  J
    could  cause  a  2.0   gr./lb.   error.   Likewise,  a  j+0.4°F
    technician integration error would  introduce a +1.0 gr./lb.
    error.

    As Table  C shows  the  majority of  these tests were  run  on
    three  consecutive days with  room  humidity  level  checks
    being made  on  12/9/82.  The majority of the original tests
    were  read   by  Steve  Pfeiffer  while the  majority  of  the
    confirmatories  were  read by  Sherm  Funk.   It appears  that
    after a plot analysis  and a later confirmation test  the wet
    bulb data  on   lines  1,  8,   and  9  were  mis-read  low by  1°.
    These  points  were  adjusted  on   Table  A  and   shown  in
    parenthesis, but were  deleted  from  the  calculated  values  of
    Table B and the plots on Figure 2.

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    One  of  the  difficult  parts  of   this  experiment  was  to
maintain the_temperature  in  the  reservior  to recommended levels
(+2.0°F from ""the  wet bulb temperature).   Crushed  ice was mixed
with  the  watEr  and  as  the  ice melted  the water  temperature
would rise. ~ -It  was necessary to take  six readings  two minutes
apart during  the  time  the  water temperature  was  in  the  four
degree  window.   It  was   found  that if more ice  was  used  the
temperature rise  was considerably slower.   NBS  recommends  that
the  water  temperature be maintained at  or slightly  above  the
wet bulb temperature, (See Reference, NBS circ.  512).

    Some points were read where  the wick  water temperature  was
below the  wet  bulb  temperature.   After the data  were plotted,
the  results  showed  that  at  these  conditions  the  psychrometer
read lower than the  dew point meter.   If  the dew point meter is
considered the  accurate  instrument, the results agree with  the
NBS  statements.    This  phenomena  was  taken into  account  and
these points were deleted from our reported data.

Conclusions/Recommendations

    This  experiment  demonstrates   and   quantifies   that   the
typical  conditions  of  our  psychrometer   (low  air  velocity,
ambient temperature  water  and less  than full reservior) cause a
positive  bias  of  about  5 grains.   If the  sock  is  down or  a
contaminated wick  condition is  added, the  bias increases  to
about 7  grains.    Furthermore,  the  thermometer  calibration  and
reading error could increase the bias  to  10 grain/lb. or more.
These tests  explain  the  causes  for  the  levels of  error  that
have  been  seen   in  previous  comparisons  and  reaffirms  the
humidity report of December  1980.

    The  dew  point  method  is   a  very accurate  and  reliable
    technique for  measuring  humidity.   The  dewpoint  hygrometer
    units  installed  in   this  laboratory  use   the  fundamental
    method of condensation,   and incorporates  such  measures  as
    an alarm  for  excessive  contamination,  automatic  correction
    circuitry,  a  highly  accurate platinium  RTD  thermometer  for
    surface  temperature  measurement,  and   a   mirror  surface
    self-cleaning  capability.   These  features  eliminate  the
    inherent characteristics of the wet  bulb psychrometer  that
    can result  in  a biased  humidity measurement.   In addition,
    the use  of  a  dew point  temperature is  a more  direct means
    of calculating humidity  as opposed  to wet bulb and dry bulb.

Recommendations

    It is  recommended that  the  dew point meter  be  implemented
    as the method  to measure humidity and  that  they  replace  the
    wet  bulb/dry  bulb psychrometer  and  the  Esterline  Angus
    recorders in the Light Duty test cells.

    It is recommended that  the  Laboratory Computer System (LCS)
    be used to  collect  and  process  the output   data  from these
    units and that  the data  be  used to  set room humidity levels
    and  to  calculate   NOx   correction   factor   for  official
    emission tests.

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References
    EPA  Admiu_istrator's  Letters  to  General  Motors  and  Ford,
    Subject:  bImpact of  Test  Procedure Changes  on  Corporate
    Average Tuel Economy  (CAFE), February 19, 1980.

    EPA  Technical  Report,  Test  Cell  Humidity  Investigation
    Report, Sherman D. Funk, April 17, 1980

    EPA  Technical  Report,   Assessment   of  Test  Cell  Humidity
    Measurement and  Control,  EPA-AA-EOD-80-13,  Sherman  D.  Funk,
    December 1980.

    NBS Circular  512, Methods of  Measuring  Humidity and Testing
    Hygrometers, A. Wexler, W.G. Brombacher, Sept.  28, 1951.

    Vapor  Pressure  Equation  for  Water  in  The Range  of   0  to
    100°C.  A Wexler and L. Greenspan, NBS,  Feb. 19, 1971.

    EPA   Memo,    Comparison   of   Humidity   Correction   Factor
    Procedures, Eric Zellin, May 31, 1973.

    EPA  Internal  Paper,  A  Procedure for Calculating Humidity,
    Eric Zellin, July 1975.

    Instruction  Manual   Dew   Point   Meter   1200  APS,   General
    Eastern Corp., June 1979.

    EPA  Internal  Document,  Technical References and  Procedures
    for Calculating Humidity, Eric Zellin, January 1983.

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                           Attachments
Table A -  -- ^Humidity   Differences    Relative    to   Variable
             ^Parameters (Wet Bulb - Dew Point)

Table B -     Analysis of Paired  Humidity  Differences (Wet Bulb
              - Dew Point)

Table C -     Wet Bulb vs.  Dew  Point Humidity Tests, Tables and
              Data

Figure 1 -    Humidity  Measurement   Comparison  Test   Set  Up
              (Room 305)

Figure 2 -    Factors Affective Psychrometer Accuracy

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i  i
!  i
TABLE A:
     HUMIDITY DIFFERENCES
RELATIVE TO VARIABLE PARAMETERS
(WET BULB - DEW POINT) (GR/LB)


AIR VEL
FPM ,
SOCK UP 2
RES lj FULL
ORIGINAL •
N = 6-1 5
CONFIRM e
N = f 7
SOCK UP 6
RES. FULtf
ORIGINAL; ,
N = 6 11
CONFIRM ::
N = 3
!•'•
SOCK i;
\ DOWN l<3
RES. FULL;
ORIGINAL, .
N = 6
HUMIDITY.
ORIGINAL . .
N = 6
§78.6,.
69.8
52.4
30.2
f
?9
JC,
- •__
TWP
i
450 i 700
1

+ 1.6 !
	 T"
-0, +2°F.
3
4
900 : 1300


+ 0.4

! + 0.2
j


+ 0.9


+ 0.2

+ 1.4 ;











5
1500


+ 0.04





J
- 0.3 ! + 0.3



. . ! ; i
1 ;
1

!







;

:
i r


- —.._----. — .. . — -.
* NOTE: DATA IN PARENTHESES ARE COR
- ONE DEGREE READING ERROR OF





75 + 2°F'
6789
450 700 900 1300

!
! i
+5.0 . + 4.0
t
+5.4 +4.6 i+3.6 +3.0



+ 1.4 + 0.6

1500


+ 2.6 .





- 0.1
(+ 6.0)* |(+ 5.2)* ;(+ 1.5)'
+ 4.6 +4.5 ; + 4.3 '. + 3.0






+8.0 ! + 6.4 i




+ 4.8

1 '
i
I
1
1 !
,
: + 2.2 ;
	
: +2.6
; + 1.9 i
+ 1.8
ECTED FOR A POSSIBLE i
WET BULB i
i A. 	 	
1 i
"."". '."."~1.'_. .TT... " .
.....

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                    TABLE B  -  ANALYSIS OF PAIRED DIFFERENCES
PARAMETER
CHANGED
                 RELATED PAIRED  DIFFERENCES
AVERAGE
 SHIFT
 GR/LB
DECREASE H2O
TEMP  (75 - WB)

INCREASE AIR
VELOCITY BY
500 fpm

RESERVOIR
FILLED
(1/2F - FULL)

SOCK POSITION
DOWN - UP
       (-3.4*, -3.6*, -4.4,  -3.2,  -4.0,  -2.7)
       (-1.2, -1.0, -1.4,  -1.7,  -0.3,  -1.5,  -1.6,  -1.6)
       (-0.5, -0.2, -0.4,  -0.7,  0.0)
        (-3.4, -2.2, -1.8)
 -3.55 '' f
                                                                   I >«r
 -1.29



 -0.36


 -2.50
EXAMPLE:
    * -3.4
    * -3.6
= 1.6 - 5.0  (See Table A)  @  450  fpm
   .4 - 4.0                @  900  fpm,  etc,
TOTAL BIAS         LOW VEL,  AMB H2O,  1/2 FULL, SOCK DOWN
TYPICAL BIAS       LOW VEL,  AMB H2O,  1/2 FULL, SOCK UP
TYPE J T/C ERROR
MANUAL INTEGRATION
  ERROR

MAXIMUM BIAS
                                                              -7.7
                                                              -5.2
                                                              + 2.0

                                                              +1.0

                                                              10.7

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                                                                                              13
1 I*.282 »
                          ^.FIGURE. 2 .-..FACTORS AFFECTING PSYCHROMETER ACCURACY
                           200   400  ;  600    800  1000   1200  1400   1600



                          •:: I :.•:•';.'•::! PSYCHROMETER AIR'VELOCITY fFPNO ' :-'l •
1800  2000
20 Squarii to I ho I:u'h

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