QUALITY ASSURANCE MANUAL FOR
    WASTE  MANAGEMENT BRANCH  INVESTIGATIONS
Prepared by the Regional Quality Assurance Management Office
         USEPA Region 10, in cooperation with the
               Waste Management Branch
                   February, 1986

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To Users of the Quality Assurance Manual For Waste Management Branch Investigations:

     The following is an initial list of errata found in the initial copies of this manual.  If,
in use or review of this document, additional ones are found, please notify Roy R. Jones in
the Regional Quality Assurance Management Office so they may he corrected with the
first revision tentatively scheduled for May or June, 1986.  If major changes or new
references  should be noted, please give the RQAMO as much lead time as possible for
inclusion and/or further errata notice.  Thank you for your patience, cooperation and
assistance in developing this manual.


                                 Errata as of 2/12/86

Sect. V, pg 1, last sentence; change "  Sample Management Office (SMO)" to Regional
Sample Control Center (RSCC)

Sect VIII, pg 2,  1 st. paragraph; should read "...found in Section XVI."

Sect.X, pgs.4 & 5, part E.; should read "RSCC NOTIFICATION AND REPORTING", with
RSCC replacing "laboratory" in subsequent 2 paragraphs.  ALSO, delete SS from SSQAP in
last sentence of 2 nd. paragraph.

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SECTION
I.
n.
ni.
IV.
V.
VI.
VII.
vm.
IX.
X.
XI.
XII.
XIII.
XIV.
XV.
XVI.
XVII.
XVIII.
XIX
Appendix A:
Appendix B:
Appendix C:
Section No.
Revision No.
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TABLE OF CONTENTS
TITLE
Title
Table of Contents
List of Tables
List of Figures
Introduction
Project Description
Project Organization and Responsibilities
Objectives for Measurement Data
Sampling Procedures
Sample Custody and Documentation
Calibration Procedures and Frequency;
Preventative Maintenance
Analytical Procedures
Data Reduction, Validation, and Reporting
Internal Quality Control Checks
Performance and System Audits
Specific Routine Procedures Used to Assess Data
Precision, Accuracy, and Completeness
Corrective Action
Quality Assurance Reports to Management
Safety
Glossary of Terms
40 CFR Part 261
Model Quality Assurance Project Plan (QAPP)
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1 LIST OF TABLES
TABLE # TITLE
1 Persons Responsible for QA Activities
2 Example of Data Quality Objectives
for RCRA Measurement Data
3 Example of Sample Container and
Preservation Methods
4 Example of Methods for RCRA Analysis
5 Level of Effort for QA Samples
Section No. Ill
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SECTION PAGE
VII 3
VIII 3
IX 4
XII 2
XIV 1

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Section No. IV
IV. LIST OF FIGURES
FIGURE # TITLE
1 Project Organization
2 Chain of Custody Record
3 Examples of Custody Seals
4 Analysis Required Sheet-Water
5 Analysis Required Sheet-Sediment
6 Field Sample Data Sheet,
with Chain of Custody
7 Metals Analysis Required-Water
8 Pesticide Analysis Required-Water
9 Organics Traffic Report
10 Inorganics Traffic Report
11 High Hazard Traffic Report
Revision
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                                                             Section No.       V
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                                 V.  INTRODUCTION
      The Environmental Protection Agency (EPA) Region 10, Waste Management Branch
(WMB) administers implementation of the Resource Conservation and Recovery Act
(RCRA, see Appendix B, "40 CFR Part 261) and oversees compliance monitoring of
hazardous waste handling facilities. This includes on-site technical and field investigation
aimed at assessing compliance with permit requirements.  An effective multidisciplinary
technical and field investigation program requires a definitive quality assurance (QA)
program coupled with efficient scheduling of all resources.  The nature of the field
investigation as well as the combination of sampling and laboratory activities make QA of
all collected data critical. To obtain quality  data that are scientifically and legally
defensible, and to  have the requisite levels of precision and  accuracy with minimum
expenditures of resources, requires the development of a comprehensive and
well-documented Quality Assurance Project Plan (QAPP).

      The guidelines and procedures for quality assurance of data gathering, analysis, and
reporting under the RCRA Program are covered in this Quality Assurance Manual. This
manual describes those procedures which ensures the collection of data of adequate
quality to meet project objectives.

      Specific guidelines and activities that are addressed include:  sampling procedures;
sample custody; calibration  procedures; analytical procedures; and data
analysis/reduction, validation, and reporting.  The plan also addresses internal quality
control checks; performance and system audits; quality assurance reports to management;
preventive maintenance; corrective actions; and assessment of data precision, accuracy,
and completeness.

      It will be  necessary to prepare a WMB/RCRA specific  QA project sampling plan for
each project that includes monitoring and measuring activities that generate and process
environmental data.  Appendix C provides an  example of format for preparing all types of
QAPPs.  It can  be  utilized by simply "filling in the blanks" for routine and screening
efforts or expanded for developing a comprehensive plan for major data acquisition
efforts.  This model addresses all essential elements called for in national agency
guidance and regulations

      Each QAPP will be reviewed by appropriate Environmental Services  Division (ESD)
peer revicwer(s), and when concurred with by the Regional Quality Assurance
Management Office (RQAMO), will serve as an authorization to assign Laboratory sample
numbers and other ESD resources.   It cannot, be too strongly emphasized, that, except for
unique emergency  response situations, the QAPP must  be completed prior to the
initiation of sample collection.  Finally, the QAPP will serve as the basic tracking
document for the project managers, the RQAMO, and the Sample Management Office
(SMO).

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                                                            Section No.
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                            VI.  PROJECT  DESCRIPTION
      Data generated from the samples that are analyzed using the QA procedures
described in this manual will primarily he used for RCRA and solid waste permits,
compliance and enforcement cases. Data generated will he used for monitoring activities
related to:
       Generation
       Treatment
       Storage
       Disposal
       Closure (e.g. specific sites)
       Unregulated Discharges (e.g. spills)
       PA/SI's
                     Permit Development
                     Case development
                     Corrective Action Development
                     SWMU's
   Data will also he generated from hoth compliance, enforcement, and routine
surveillance activities covering hazardous waste facilities.  These data will he used for
facility plan evaluation, and information, education and technical assistance in
professional development programs.

   Under 40 CFR Part 261 (Appendix B) of the  RCRA regulations, a listing of hazardous
materials is provided. This part also requires analyses to he performed by methods
provided in SW-846 "Test Methods for Evaluating Solid Waste; Physical/Chemical
Methods"  . However, SW-846 does not provide methods of analysis for every material
listed as hazardous in 40 CFR Part 261. As new procedures are added to SW-846, the
laboratory will develop procedures the same as in SW-846 to perform these analyses.  All
groundwater sampling and analysis procedures also currently follow either SW-846, the
EPA 600 series, or SW-611.  This will be continued until such time as EPA promulgates
groundwater monitoring in SW-846.

   The specific parameters addressed by this plan are as  follows:
Ignitability
Corrosivity
Reactivity
EP Toxicity
Volatile Organics-
Semi-volat ile Organics
Polynuclear Aromatic
  Hydrocarbons

Total and Amenable Cyanide
TOX
Su I fides
pH
Antimony     Halogenated Volatile Organics
Arsenic       Nonhalogenated Volatile Organics
Barium        Aromatic Volatile Organics
Cadmium     Acrolein, Acrylonitrile, Acetonitrile
Chromium     Phenols
Lead          Phthalate Esters
Mercury      Organochorine Pesticides and PCBs
Nickel        Nitroaromatics and Cyclic Ketones
Selenium      Polynuclear Aromatic Hydrocarbons
Silver         Chlorinated Hydrocarbons
              Organophosphorous Pesticides
     Other parameters may be measured as part of the overall RCRA program.  These
parameters include, but are not necessarily limited to: TOC, polar organics, viscosity,
chlorides, specific gravity, BTU, proximate and ultimate analysis.

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                                                           Section No.      VII
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                   PROJECT ORGANIZATION  AND RESPONSIBILITIES
     The WMB is organized under the Branch Chief into three Sections. Out of these
three Sections, the compliance section and the permit section are responsible for
conducting monitoring activities.  The functions of this Section are described as follows:

     Provides technical assistance to Federal, State, and local agencies and industry.
Conducts compliance inspections and takes enforcement actions as appropriate.
Overviews state program monitoring activities.

     Project organization and individuals responsible for quality assurance are shown in
Figure I. Responsibilities of these personnel are summarized in Table I
                                      FIGURE I

                              PROJECT ORGANIZATION
                                  Hazardous Waste
                                  Division  Director
                                        WMB
                                    Branch Chief
                           Chief, RCRA Compliance Section
                                   Project Officer
                                Environmental Services
                               RQAMO and Peer Review
                               State Operations Offices

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                                                             Section No.       VII
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           Table 1,  Personnel  Responsible For  Quality Assurance  Activities
Personnel
Responsibilities
WMB Chief
RCRA Compliance Section
Chief
Project Officer
ESD Peer Reviewer(s)
RQAMO
Provides oversight of all program
activities; consult with section chief on
policy decisions and  major QA problems.

Reviews final-project QA needs,
problems, and requests; approves
appropriate QA corrective actions as
needed.  Sign-off responsibility for
Section on QAPPs.

Coordinates both internal and external
technical operations with appropriate
State or local agencies.  Liaison with
RQAMO. Ensures that QAPP is
prepared and adhered to: by proper
handling of logs, sample receipts,
custody records and  all other required
documentation; through careful
instrument calibration and
maintenance; that internal quality
control measures are implemented; that
corrective action is taken and RQAMO
is notified when problems occur; that
data, QA information, and reports are
produced in a timely manner.

Provides technical QA assistance to
ensure compliance with approved or
recommended sample collection
policies and procedures.

Reviews and has sign-off authority for
Region on all QAPPs; provides
teclmieal QA assistance and audits in
relation to EPA QA policies and
procedures.

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                                                            Section No.      VIII
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                   Vffl.  OBJECTIVES  FOR MEASUREMENT DATA
     The overall QA objective is to develop and implement procedures for field sampling,
chain of custody, laboratory analysis and reporting that will provide sound scientific data
and legally defensible results in a court of law.  Specific procedures to be used for
sampling, chain of custody, calibration, laboratory analysis, reporting, internal quality
control, audits, preventative maintenance and corrective actions are described in other
sections of this QA Manual. The purpose of this section is to define QA goals for
detection limits, precision, accuracy and completeness where possible and presented in a
tabular format similar to table 2. Such a table should be prepared by the project officer-
in consultation with the QA coordinator,  laboratory director and reviewed by the RQAMO
prior to initiating sampling efforts.

     All measurements will be made so that results are consistent and representative of
the media and conditions measured.  All data will be calculated and reported in units
consistent with other RCRA investigations to guarantee comparable data bases.
Establishment of these goals allows the project  manager to judge the adequacy of the
results obtained and either use them or take corrective action if necessary.

     Data quality objectives recommended by WMH for RCRA analyses are described
below:


     Detection  Limits - The detection limits most commonly used for the pur-pose of
     RCRA analyses are presented in Table 4 in Section XII.

     Accuracy - The QA accuracy objectives for quantitative analysis are expressed in
     terms of recovery of surrogate compounds or recovery of spiked analytes.  Recovery
     of a surrogate compound added to a sample will be defined as  follows:

     Recovery, % =  Grams of Surrogate  round  in Sample  x  100%
                  Grams of Surrogate Added to Sain pie

The recovery of a spiked analyte is defined as follows:

     Recovery, % =  Total Analyte Found - Analyte Originally Present x  100%
                                     Analyte Added


QA objectives for these recoveries are given in  Table 2.

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                                                            Section No.      VIII
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    Precision - The objective for precision where duplicates or replicate analyses have
    been performed are as follows:

    •     Analysis of Surrogate or Analyte Spikes:  One of the QA objectives is that the
          standard analysis of surrogate compounds or analyte spikes in duplicate samples
          from a given sampling point be within the limits specified in Table 2.

    •     Analysis of Duplicate Samples or Replicate Analytes :  One of the QA
          objectives is that the results or quantitative analysis for duplicate or replicate
          samples be  within the limits specified in Table 2.

    A more thorough discussion of, and the equations used to calculate precision are to be
found in Section 15.0.


    Completeness - Completeness is defined as the degree to which the number of
    activities initiated are actually finished. The degree of completeness is the total
    number of samples for which acceptable analytical data  are generated divided by the
    total  number of samples collected times 100%. As shown in Table 2, the QA data
    objective for the completeness of WMB projects is 95%.

    Comparability - To ensure a coherent data base, all results should be reported in the
    same  units of quantification. Measurement units most commonly used for the
    purpose of RCRA analyses are presented in Table 4 in Section XII.

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                                                           Section No.      VIII
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                                      TABLE 2
    EXAMPLE OF DATA QUALITY OBJECTIVES FOR RCRA MEASUREMENT DATA
Technique or
Parameter              Matrix                Precision     Accuracy   Completeness
Characteristics
Ignitability          Solid, Liquid ,sludge          ±20%       97-103%        95%
Corrosivity          Liquids, sludges             ±10%       90-110%        95%
KPToxicity         Solids ±30%                70-130%    95%

Composition
GC or GC/MS        Aqueous                   ±20%       ±3 SD           95%
 Volatile            Solids
 Organics           and Biota                   ±50%       ±3 SD           95%
 Base neutrals
 Acids
 Pesticides

Atomic Absorption   Solid, liquid, sludge          ±30%       70-130%        95%
                                                           for
                                                           spikes
                                                           ±2SD
                                                           for QC          95%
                                                           samples

Cyanide             Solid, liquid, sludge          ±20%       80-120%        95%
Sulfides             Solid, liquid, sludge          ±20%       80-120%        95%
pH                 Aqueous phase of 20%
                     total volume
TOX                Drinking & Ooundwaters    ±20%       80-120%        957c
'o

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                                                            Section No.      VIII
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    Following is a list of documents that provide information concerning statistical
procedures for measurement data:
Cochran, W.G.  1977. Sampling Techniques. 3rd edition
John Wiley & Sons, Inc.  New York, NY. 428 pp.

Finney, D.J.  1964.  Statistical methods in biological assay.
Hafner Publishing Co. New  York, NY.

Green, R.H.  1979.  Sampling design and statistical methods for enviornmental biologists.
John Wiley & Sons, N.Y.  257 pp.

U.S. Environmental Protection Agency, 1984.
Calculation of Precision, Bias, and Method Detection Limit for Chemical and Physical
Measurements.

Keith, L, W. Crummett, J. Deegan, Jr., R. Libby, J. Talor and G.  Wenther.  1983.
Principles of environmental  analysis. Analytical Chemistry, Vol.  55.  pp. 2210-2218.

Sokal, R.R., and F.J. Rohlf.  1969. Biometry. W.H. Freeman and Co., San Francisco, CA.
776 pp.

Tetra Tech.  1985.  Bioaccumulation monitoring guidance: Selection of target species and
analytical detection limits prepared for U.S. Environmental  Protection Agency,
Washington D.C.

U.S. Environmental Protection Agency.  1979a.  Handbook for analytical quality control in
water and waslewater laboratories.  EPA-600/4-79-019. Environmental Monitoring and
Support Laboratory, Cincinnati, OH.

U.S. Environmental Protection Agency.  1982a.  Handbook for sampling and sample
preservation of water and wastewater.  EPA-600/4-82-029. Environmental Monitoring
and Support Laboratory, Cincinnati, Oil.  402  pp.

U.S. Environmental Protection Agency.  1983b.  Environmental measurement method
performance data for establishing achievable data quality goals.  Environmental
Monitoring Systems Laboratory Research, Triangle Park, NC.

    Additional references for methods and associated measurement objectives are given
in Section 7 - Sampling Procedures, and Section 10 - Analytical Procedures.

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                                                            Section No.       IX
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                            K.  SAMPLING PROCEDURES
     Ultimate accuracy of any data generation begins with a sampling procedure that is
well conceived and implemented.  Prior to sample collection, a detailed QAPP (see
Appendix C for example of format) specifying sampling procedures and equipment, sample
container type and preparation, sample preservation methods and holding times and
shipping requirements will be prepared.

     The sampling procedures to be used by the HWMB for RCRA investigation are based
on those described in the following references:

     •    "Test Methods for Evaluating Solid Waste Physical/Chemical  Methods",
          SW-846, 2nd Edition, U.S. Environmental Protection Agency,  1982.

     •    "Sampling at Hazardous Materials Incidents", U.S. Environmental Protection
          Agency, Office of Emergency and Remedial Response, April 1984.

     •    "Field Sampling Workbook", Prepared by Region 10, U.S. environmental
          Protection Agency, Nov. 1984.

     Before sampling of any site is performed, the Project Officer will meet or talk with
the Compliance Section Chief or the RCRA QA Coordinator.  The purpose of the meeting
will be to establish the sampling objectives, sampling methodology to be employed and the
analytical test which will be performed on the samples. Where possible, the QA
coordinator and the field sampling team will establish the sensitivity required for the
analytical tests. All field activities and sampling will be documented in a stitched, bound,
and numbered field logbook. Modifications to approved or recommended sample
collection procedures will be described on the sample alteration checklist (Appendix C, pg
4) of the QAPP.  Overall responsibility to see that field staff is properly trained in
sampling procedures rests with the WMB Chief.

     The type of sample container and preservation method used will vary according to
the sample type and the parameters being measured.  The field sampler is responsible to
assure proper preservation methods are employed.

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                                                             Section No.       IX
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                                        Table3
                Example Of Sample Container And Preservation Methods
Parameter
Size and Tvoe of Container
Preservative*
Ignit ability

Corrosivity

Reactivity

EP Toxicity

Metals, except
Mercury and
Hexavalent Cr

Mercury


Hexavalent Cr

Volatile
Organ ics

Semi-volatile
Organics

Pesticides

Cyanide

TOX

Sul fides


pH
500 ml glass

1 liter plastic

1 liter plastic

1 quart glass



1 liter plastic

1 liter plastic


1 liter plastic

Purgeable vials (2 or more)



1 gallon glass

1 gallon glass

I liter plastic

Purgeable vials

I liter plastic


1 liter plastic
Iced or refrigerated

Iced or refrigerated

Iced or refrigerated

Iced or refrigerated



5 ml HN03/liter

20 ml (2.5% K2Cr207
in 25% HNO3)/liter and iced

Iced or refrigerated

Iced or refrigerated



Iced or refrigerated

Iced or refrigerated

1  ml 50% NaOH/litcr and iced

Iced or refrigerated

2 ml (2N) Zn(C2H302
per liter

Iced or refrigerated
*   Preservation used only if sample is aqueous. Non-aqueous samples are placed in a
    glass bottle and iced. If the sample is strongly alkaline or acidic, a preservative
    should not be used.  Volume of sample includes Quality Control effort.

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                                                           Section No.:  X—ALL QAPs
                                                           Revision No.:     2	
                                                           Date:      March 1986
                                                           Page:      I    of	15_


                  X.  SAMPLE CUSTODY AND DOCUMENTATION
     The possession of samples must he traceable (i.e. their whereabouts must be
determinable at all times evidenced by paper to prove it) from the time the samples are
collected until they are introduced as civil or criminal evidence in enforcement
proceedings, because of the potential evidentiary nature of sample collecting
investigations. In addition, all information pertinent to field activities must be recorded
in various forms, including logbooks, sample  tags, and photographs.  Such information,
since it is required and used to refresh the investigators memory years later at trial will
support the introduction into evidence of a particular sample, and potentially provide
important or corroborative evidence relevant to the matters at issue. Therefore, each
field worker must keep detailed records of inspections, investigations, photographs taken,
etc., and thoroughly review all notes before  leaving the site.  Document control is
implemented to ensure that all documents for a specific project are accounted for when
the project  is completed.  Accountable documents include items such as logbooks, field
data records, and photos.  Each document should bear a serial number and should be listed,
with the number, in a project document  inventory assembled at the project's completion.
Waterproof ink should be used in recording all data in documents bearing serial numbers.

     Under Rule 803(6) of the Federal Rules of Evidence written records of regularly
conducted business activities may be introduced into evidence as an exception to the
"hearsay rule" without the substantive oral testimony of the person(s) who made the
record, (IF the author can establish the proper foundation for admissibility  (date, time,
place, who was there, identify that a document was authored by him  (by signature,
initials, or handwriting) and be able to state  that that type of document is kept  in the
ordinary course of business).  Although it is preferable, it is not always possible for the
individuals who collected, kept  and analyzed samples to testify in court. In addition, if
the opposing party does not intend to contest the integrity of the sample or testing
evidence, admission under Rule 803(6) can save a great deal of trial time.   For these
reasons, it is important to standardize the procedures followed in collection and analysis
of evidentiary samples to qualify for the requirement of "regularly conducted activity".
Whether or not the team  members anticipate that various documents will be introduced as
evidence, they should make certain that all documents are as accurate and  objective as
possible.  THE SUCCESS OR FAILURE OF A COURT PROCEEDING COULD DEPEND ON
IT.


A.   FIELD LOGBOOK

     All information pertinent  of field act i\i1 ies should be entered in ;i bound book with
consecutively numbered pages.  At a minimum, logbook entries must  include:

           WHEN (date, time)
     •     WHERE (county, state, site address, sample location)
     •     WHO (those present  directly involved)
     •     WHAT (sample numbers, descriptions of observations and actions)
     •     HOW (equipment used,or procedures followed)

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                                                           Section No.: X—ALL QAPs
                                                           Revision No.:     2	
                                                           Date:      Maroh 1986
                                                           Page:      2   of    15

     Additional entries, of a WHY nature may he included, particularly if the sampler
feels they could act as collateral aids in refreshing his memory at a later date.
HOWEVER, caution should he exercised that these are essentially ohjective in nature as
they too would be considered as evidence. Such entries could include:

     •    Name and address of field contacts (federal, state, or local representatives
          present hut not directly involved in activity)
     •    Type of process producing the material
     •    Type of media sampled (drinking water, wastewater, sediment, etc.)
     •    References such as  maps or photographs taken or acquired of the sampling site
     •    Any field measurements made such as pH, total organic vapors, or
          explosiveness

Because sampling situations vary widely, notes should he as descriptive and  inclusive as
possible.  Those reading the  entries should he able to reconstruct the sampling situation
from the recorded information.  Language must be objective, factual, and free of personal
feelings or opinions or any other inappropriate terminology. If anyone other than the
person to whom the logbook was assigned makes an entry, they  must date and sign it.
Errors should he corrected with a single line drawn through the error; the correct data
filled in, and the correction  entry initialed and dated.


B.   PHOTOGRAPHS

      Photographs can be the most accurate demonstration of the field worker's
observation.  They can be significant to the field team during future inspections, informal
meetings, and hearings. A photograph should be documented withe the entries  listed as
MUST listed in  part A, above, if it is to be valid representation of an existing situation.  It
is a good idea to sign and date the final print or1 transparency, (o aid in positive
identification at a future date.  Comments should be limited  to an objective description.
Photographs should be taken with a camera-lens system with a  perspective similar to that
afforded by the naked eye.


C.   SAMPLE LABELS

      Each sample should be labeled using waterproof ink and sealed immediately after it
is collected.  Labels should be filled out before collection to minimize handling of the
sample container.  Records should be kept of the assignment  of serial sample tags to field
personnel  if such  forms arc used. Sample tags must never be discarded.  Lost, voided, or-
dain aged tags should be immediately noted in the logbook of the person  to whom they
were assigned.

      Labels must be firmly affixed to the sample containers .  'fags attached  l>.\ string
arc acceptable  when gummed labels are not  available or- applicable,  'flu: container- must
he dry enough for a gummed label  to be securely attached. The label must include at  the
minimium the assigned sample  number-. If supporting information, i.e. Name of collector-,
date and time of collection, place; of collection are not included on this label,  such
information  MUST be recorded in the bound  field  logbook at the time of actually taking
the sample and directly keyed to the assigned sample number and cross  referenced to the
appropriate  Field Data Sheet and Chain of Custody Form, and Analysis  Requested form.

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                                                           Section No.: X—ALL QAPs
                                                           Revision No.:     2	
                                                           Date:      March 1986
                                                           Page:      3   of    15
D.   CHAIN-OF-CUSTODY PROCEDURES
     As in any other activity that may be used to support litigation, the sample collector
must he able to provide documentation of the chain of possession and evidence of the
continued custody of any samples which are offered for evidence.  Written procedures
must be available and followed whenever evidentiary samples are collected, transferred,
stored, analyzed, or destroyed. The primary objective of these procedures is to create an
accurate written record which can be used to trace the possession and handling of the
sample from the moment of its collection through its  analysis and  to its introduction as
evidence.

     A sample is considered to be in someone's "custody" if:

     •     It is in one's actual possession, or
     •     It is in one's view,  after being in one's physical possession, or
     •     It is in one  physical possession and then locked up so that no one can tamper
           with  it, or
     •     It is kept in a secured area, restricted to authorized and accountable personnel
           only.

During sampling collection and shipment, specific procedures should be followed to
maintain proper  chain-of-custody and accurate field inventory sheets, logbooks, and other
supporting documentation. DO NOT LOSE THEM!

1.   Sample Collection, Handling, and Identification

     The number of persons involved in collecting and handling samples should be kept to
a safe minimum.  Field records should be completed at the time the sample is collected
and should be signed or initialed, including the data and time, by the sample collector(s).
Field records (in addition to those listed in Part A. of this section) should contain the
following  information:

     •     Unique sampling or log number
     •     Custody form numbers, if supplied
     •     Preservative used
     •     Name of collector(s)
     •     Copies of Field Data Sheets, Chain of Custody documentation,  Analysis
           Requested, Airbill  or Waybill documents if shipped by common carrier

     It should he confirmed by the sampler writing in his or her field log that each sample
is identified by the approved pressure-sensitive gummed label  or standardized tag on  (lie
container, and if the individual container is scaled.

     The sample con! ainer should t hen be  place*I in a I runsport at ion case,  along \\ it h t he
shipping copies of chain-of-custody record form, pertinent  field  records, and analysis
request  forms as needed.  The transportation case should be sealed or locked. A locked or
scaled  ice chest  eliminates the need  for close oversight of the individual samples.
However, on those occasions when the use of an ice chest  is inconvenient, tin; collector
should seal the cap of the individual sample container in such a way that any tampering
would be easy to detect.

-------
                                                           Section No.: X—ALL QAPs
                                                           Revision No.:     2	
                                                           Date:      March 1986
                                                           Page:      4   of    15

     When samples are composited over a period of time, unsealed samples can he
transferred from one crew to the next.  The transferring crew should list the samples and
condition and a memher of the receiving crew should verify the condition abd sign the
list.  The receiving crew either transfers the unfinished composite samples to another
crew or treats the finished composite sample as described above for samples.

     It is desirable  to photograph the sample location or any visible pollution to facilitate
identification later.  At the time the photo is taken, the photographer should record time,
date, site location, and a brief description of the subject in the Field Log book.  If
Polaroid is used, the photographer should sign and date on the back of the photo.  Film,
developed negatives, transparencies, photographs and written records that  may be used  as
evidence should be handled in such a way that  chain-of-custody c;ui be established.

2.   Transfer of Custody and Shipment

     When transferring the samples, the transferee must sign and record the date and
time in the chain-of-custody record (Either Fig. 2 or Fig. 6).  Custody transfers in the
field should be documented and account for each sample, although samples may be
transferred as a group (as long as each individual sample in the group is identified).  Kvery
person who takes custody  must  note if the individual samples or the sealed shipping
container is correctly sealed and in the same condition as noted by the previous custodian;
and must fill in the  appropriate section of the  chain-of-custody record.  To minimixe
custody records, the number of custodians in the chain-of-possession should bo minimized
(if possible).

     All packages sent to the laboratory should be accompanied by the chain-of-custody
record and other pertinent forms.  A copy of these forms should be retained by the
originating person.  Have the designated agent of the common carrier sign and date the
field copy of the chain of  custody form. Mailed packages can be registered with reI urn
receipt requested.  For packages sent by common carrier, receipts, bills of lading, airbills
or waybills or copies of these documents must  be  retained as  part of the permanent
chain-of-custody documentation.  If the originals of such documents must be forwarded to
finance for payment, be sure to keep a true copy (a true copy is one made or photocopied
by an individual who signs and dates the copy to identify it as an accurate reproduction  of
the original: "True copy of original. Made by John  Doe,  February 30, 1980.") for the chain
of custody documentation. Samples to be shipped must  be packed  so as not to break and
the package should  be sealed or  locked so that any tampering can be readily detected.
The FPA shipper and receiving personnel should both note the condition of the container
seals (brok(M) or unbroken) each time possession is exchanged. The preferred procedure
includes use of a custody seal (Figure 3) wrapped across filament tape that is wrapped
around the package at least twice.  The custody seal is then folded over and stuck  to itself
so that  the only access to the package is by cutting the  filament  tape or- breaking the seal
to unwrap the  tape. The seal is t hen signed.  As an altcrnat ive, tamper proof t ape max,  be
used to seal across the filimeiit  tape.

     Upon receiving the sample container the laboratory will verify the integrity of the
custody seals by noting in  the "miscellaneous"  section of the  Field Data Shoot/Chain of
Custody sheet  "seals intact" or  "seal broken", initialed and dated.  If containers arrive
with broken seals, the Laboratory will  immediately notify the Project Officer and the
KQAMO.

-------
                                                           Section No.:  X—ALL QAPs
                                                           Revision No.:      2	
                                                           Date:     March 1986
                                                           Page:     5    of    15
E.   LABORATORY NOTIFICATION AND REPORTING
     It is important to notify the Regional Sample Management Control Center (RSMCC)
by phone and verify the shipping schedule before sampling, whenever possible. The caller1
should  indicate that it is a high priority situation (if appropriate) and verify that the lab
will be able to receive the samples. Queries about the sample arrival, position in the job
stream etc., should be directed to the RSMCC.

     In an emergency situation, when the EPA RSMCC or laboratory cannot be notified
prior to sampling, the sampler must keep accurate records of sampling procedures and
locations. The sampler may use a physical description of the sample location, provided
that it is descriptive enough to differentiate between  locations.  As soon as possible
following the emergency response, a completed QAP will be submitted to facilitate
tracking and response.

     All prospective sampler's or Project Officers should contact the Sample Control
Center prior to any sampling to obtain copies of their  required forms.  A list of the forms
often required by laboratories  include:

     •    Chain of Custody Record (Figure 2)
     •    Examples of Custody Seals (Figure 3)
     •    Analysis Required: X-91,Priority Pollutants - Organies (Figure 4)
     •    Analysis Required Sheet: X-92, Metals (Figure 5)
     •    Field Sample Data  Sheet, with Chain of Custody  (Figure (>)
     •    Analysis Required: X-93, Physical and General Inorganics and Ion
          Chromatograph (Figiu-e 7)
     •    Analysis Required: X-94, Oxygen Demand, Solids & Nutrients (Figure 8)
     •    Contract  Lab Organic Traffic Report (Figure 9)
     •    Contract  Lab Inorganics Traffic Report (Figure  10)
     •    Contract  Lab High Hazard Traffic Report  (Figure II)

     Samplers should find out in advance which of these forms the laboratory requires.


F.   CORRECTIONS TO DOCUMENTATION

     If an error is made; on any accountable document assignee! to one individual, that
individual may make corrections simply by drawing a line through the error and enter-ing
t he correct information. The erroneous informal ion should not be obliterated.  Any
subsequent error discovered on an accountable document  should be corrected by 1 he
person who made the entry.  All corrections must be initialed and dated.

-------
                                                                Section No.: X—ALL QAPs
                                                                Revision No.:      2	
                                                                Date:       March 1986
                                                                Page:       6   of    15
oEPA
    United States
    Environmental Protection
    Agency
Region 10
1200 Sixth Avenue
Seattle WA 96101
    CHAIN OF CUSTODY RECORD
PROJECT
LAB #











STATION











DATE











TIME











RELINQUISHED BY: ts

DATE
SAMPLERS: /Signature!
SAMPLE TYPE
WATER











SEDIMENT











TISSUE











X











o
r-











O
— *
I
m
3











NUMBER
OF
CONTAINERS











REMARKS











RECEIVED BY: ts,gn.wr,, DATE/TIME
RECEIVED BY: «*»«». DATE/TIME
RECEIVED BY: isynawm DATE/TIME
REC'V'D BY MOBILE LAB FOR FIELD DATE/TIME
ANAL.: ISipnelurei
'TIME
RECEIVED FOR LAB BY: isv-ww DATE/TIME
METHOD OF SHIPMENT:
    Distribution. Original —Accompany Shipment
            One Copy-Survey Coordinator Field Files
                                        FIC.URE 2
                                Chain Of Custody Record

-------
                             Section No.:  X—ALL CMPs
                             Revision No.:      2	
                             Date:      March 1986
                             Page:      7    of	15
^">"-v UNITED STATES
v *± V ENVIRONMENTAL PROTECTION AGENCY
* ,^^, 5 OFFICIAL SAMPLE SEAL
\ss;
*'-l ..<*'<•

SAMPLE NO.
DATE
SIGNATURE
PRINT NAME AND TITLE (Inspector. Analyst cr T)xhnician)
ISEAL BROKEN BY I
in
0
IA
P*
IS
2
-------
                                                                   Section No.:  X—ALL QAPs
                                                                   Revision No.:      2	
                                                                   Hate:      March 1986
                                                                   Page:      8    of     15
  EPA Region 10 Laboratory
                                 Analyses Required
                                    PRIORITY POLLUTANTS - ORGANICS
  Project Name:
Project Code:.
Account Code:.
  Matrix Codas larOe oni onlyl
  10 Wner-Tolll
  11 Water-Dissolved
  40 Sediment/ Soil
  45 Semi-Solid/Sludge
  46 Sediment for EP Toxicity
  70 Tissue
  80 Oil/Solvent
  00 Other
                Sample Numbers
                                           /Analy/Comp
                                            Init/Daie
GC/MS Orgenic Scant
68 Base/Neutrals/Acids BIN/A
62 Base/Neutrals Only B/N
51 Volatile Organics VOA
65 Acids Only Acid
Specific IGC/MS) Organics List flrtow




GC Organic Scans
71 Pesticide/PCB's Pest/PCB
74 PCB's Only PCB
64 Purgeable Halocarbons Purg
S3 Trihalomethanes Tribal
73 HerbioOes Herb
70 Chlorinated Hydrocarbons
70 OrganophosDhate Pesticides
Specific (GO Organics LSI Booty




Specific Organics at
Other Miscellaneous
67 PolyAromHydro (HPLC) PAH
40 OH Identification Oil-Id
40 Pnenolics IAAP) Phenol
40 Oil 6 Grease Oil & Greas
40 Flashpoint Flashpt


















































































































































































































































































































































































































































































































































































































   Save samples after analysis? NONE, SOME or ALL. m sot/-, a
   Soecial detection limits and comments
EPA X-t1  Ub Copy
                                       FIGURE 4
             Analysis  Required: X-91,  Priority Pollutants - Organics

-------
                                                     Section No.:  X--ALL QAPs
                                                     Revision No.:      2	
                                                     Date:      March 1986
                                                     Page:      9    of	15
M<
We
W
EPA Region 10 Laboratory Analyses Required
Pmjort Name: P
Matrix Codes IcmM one onlyl
10 Water-Total
11 Water-Dissolved
40 Sediment/Soil
45 Semi-Solid/Sludoe
46 Sediment tor EP Touchy
70 Tissue
00 Oil/Solvent
00 Other
Uls IcirOf WC II
>rkgroup 30 - Standard Method
>rkgroup 34 - EP Toxicrty Method
Aluminum Al
Antimony Sb
Arsenic Ac
Barium Ba
Beryllium Be
Cadmium Cd
Calcium Ca
Chromium Cr
Chromium Hexavaient Cr •*• 6
Cooalt Co
Copper Cu
Iron Fe
Lead Pb
Magnesium Mg
Manganese Mn
Mercury Hg
Molybdenum Mo
Nickel Mi
Potassium K
Selenium Se
Silver Ag
Silicon Si
Sodium Na
Thallium T1
Vanadium V
Zinc Zn






//.












































reject Co
de- Ar

:count Code:
METALS

/ Sample Numbers /
'',

































I

/
/





























^
























































'//



















































'/,













































7////////




















i


















i






















































i









i





































1
1
i i





\




; 1 i



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i
























: i i
; i : i ; i : •
1 \ . , 1 i
I I'll i i '
1 ' ' i ' : • . ,
Save samples after analysis? NONE,
Soecial limns, methods and comments
Analy/Comp
Init/Date


































SOME Or ACL. (If SOM£. circit same* numoers .








Protect O'licfr Sifrwiurr U*fe

EPA X-S2  Ub Copy
                      Analysis KoquirtKi: X-92, Motals

-------
                                          FIELD SAMPLE DATA AND CHAIN OF CUSTODY SHEET

p
s
c.
•J-.


s.
EPA B^oo 10
1200 Stnh AWHM
SMUta WA 96101
Prnjact Code: Account:
Name/ Location:
Prniart Officer:
D Enforcement/Custody
D Possible Taxin/Hmardnus Nntas:
n On'" Tnnf jHflntifll
n Data for Slnrn*
Samplers'


HecorHnr-
UJ
O
CC UJ
3Q
OO
C/1U




















MATRIX











|
I










1










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1










6





















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!
3










0
.£
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2
I










4!
se

-







vlt
RV










rtS
.









LAB
NUMBER
Yr





-











Wk




















Seq








































STATION
NUMBER
















































































DATE
Yr




















Mo




















Dy




















Time

































-


COMPOSITE ONLY
ENDING DATE
Mo




:











Dy




-













Tims






















-








-
1










Fraq








-




-




STATION
DESCRIPTION










LAB
NUMBER
Yr




















Wk




















Seq








































DEPTH





























c
D



-
s


-

-
COL
MTD
CD



-









QA
CODE

































-


TEMP
DEC
C


-







-







-




-
pH






























CNDCTVTY
umho/cm






































-










MISCELLANEOUS










CHAIN OF CUSTODY RECORD
RELINQUISHED BY:>s««u~<
RELINQUISHED >Y:Uv>i«il
RELINQUISHED BY:isit*wi
RELINQUISHED BY:tt*~i»'.;

RECEIVED BY:u«/i.ur./ DATE
RECEIVED BYu&twml DATE
RECEIVED BY:>5vo.nn/ DATE
REC VO BY MOBILE LAB DATE
FOR FIELD ANAL.: is*~n.l


RECEIVED FOR LAB BY:»*n.».>DATE
TIME
rnTST
TIME
TIME
/TIME

L»bo.lliVY Copy Pro)*cl Otlicv COPY f "•« w Ott*-» Copy
                                                                                                                               £°*
                                                                                                                               H* CS ft)
                                                                                                                               00 S- <

                                                                                                                               a a £
                                                                                                                                    Si. O

                                                                                                                                    O 3
                                                                                                                                 P  "


                                                                                                                                 O
                                                                                                                                 CC

                                                                                                                                 CO
                                                                                                                                    to
X
I
I


t-
r

-------
                                                        Section No.: X—ALL QAPs
                                                        Revision No.:     2	
                                                        Date:      March lf)86
                                                        Page:      11   of    15
EPA Region 10 Laboratory Analyses Required
f
n
i
i
«
4
4
7
a
0
PHYSIO
rnjort Name: Pi
Matrix Codes IcirOe one omyl
3 Water-Total
1 Water-Dissolved i
3 Sediment/Soil /
5 Semi-Solid/Sludge /
> Sediment tor EP Toxicity /
0 Tissue / /
0 Oil/Solvent / /
0 Other / /
Physical ft General
Inorganics WG 1101
Turbidity TURB
pH (Lab) pH
Conductivity COND
Total Alkalinity T ALK
Total Hardness T HARD
Bicarbonate HC03
Calcium Ca
Carbonate C03
Chloride CI
Fluoride F
Sulfate SO4-TOT
Surfide S
Cyanide CN
Acidity Acidity
Hardness CaC03
Color Color



Ion Chromaiograph we lea
Calcium Ca
Chloride O
Cyanide CN
Fluoride F
Magnesium Mg
Potassium K
Sodium Na
Surtate S04
Nitrate N03
Nrtme N02
Ortho Phosphorous O-Phos.






















































!

\L£r
oject Coi
GENERAL
IONC
ie:

INORG
HROM
Account Co
ANICS AND
ATOGRAPH
de:

/ Sample Numbers /
w/////////////




















































































































































1 1
' 1
: '• 1
i ; 1
j











































































































i !


















































































i


















































1



























i i r
1 1 • i
i
i ' '
i i ' ' i : i
; • |

1 i i
1 i '
I' ! ' • , i
: ! ' ' i
Save samples after analysis? NONE. S
Special detection limits and comments
Analy/Comp
/ Inn/Date


DME or ALL. 
-------
                                                       Section No.:  X—ALL QAPs
                                                       Revision No.:      2	
                                                       Date:      March 1986
                                                       Page:      12    of   15
1
t
4
A
1
(
EPA Region 10 Laboratory Analyses Required
OXYGEN L
'rojeet Name:
Matrix Codes ic,roe one oniyi
0 Waler-Totel
1 Water-Dissolved
10 Sediment/ Soil
5 Semi-Solid/Sludge
IE Sediment tor EP Touchy
ro Tissue
B Oil /Solvent
XJOther
Oxygen Demand ft Carbon WG tJBl
Bio. Oxygen Demand BOD/5 day
Bio. Oxygen Demand BOD/20 day
Bio. Oxygen Demand BOD/60 day
Bio. Oxygen Demand
(5-d»y) Carbonaceous BOD/5 day-C
Chem. Oxygen Demand COD
Total Organic Carbon TOC




Solids we 1151
Total Dissolved TDS
Total Sus. Solids SS
Total Solids TS
Volatile TVS
Volatile Suspended TVSS
Senieable Solids SetSlds
% Total Solids % Tot
% Volatile Solids % V Slds
Grain Size Gm S\z
Nutrients we 12OI
Ammonia NH3
•Nitrate N03
•Nrmte N02
Nitrate + Nitrite N03 + N02
Kieldahl Kjel-N
Total Phosphorous T-Phos
Dissolved Phosphorous D*Phos
•Ortho Phosphorous O-Phos
Dissolved Ortn. Phos. D-0 Phos



/












































i



)EMAr
Project Code

JD, SOLIDS AND NUTRIENTS
• Account Code:



/ Sample Numbers /
//////////////// /*nal»r/ComP
/////////// ////// 'nit/Date
























; i
1


i




















































!





i











i

I



















































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1



























1 1
1 1
i , I i
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1 1 i






















i













i




































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1
1 i;i

i i i 1 1 1
,
!
1 ' i '
: i


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Save samples after analysis? NONE, SOME or ALL. >/r snu[ nrc/r- wnw nu/w.-.- >
Soecial derernnn limiis and comments •









ProtKI Ollmt Signature Ofie

=PA X-M Lab Couy
                                 KKUJRKS
         Analysis Required: X-94, Oxygen Demand, Solids and Nutrients

-------
                                                           Section No.:  X—ALL QAPs
                                                           Revision  No.:      2	
                                                           Date:      March 1986
                                                           Page:      13    of    15
         U5.ENVIRONMENTRLPROTECnON AGENCY HWI Sample Management Office
         P-O.Box818.Aiexandna.Vut5iiia22313-703 557.2490-FTS 557-2490 •--..-•
         ORGANICS  TRAFFIC  REPORT
                                                        Sample Number
                                                       JB  102
T) Case Number
 Sample Site Name/Code:
           SAMPLE CONCENTRATION
                   (Check One)
                                 Low Concentration
                                 Medium Concentration
                            SAMPLE MATRIX
                                (Check One)
                            	Water
                            	 Soil/Sediment
                                 0 Ship To:
                                          Attn:


                                          Transfer
                                          Ship To:
© Regional Office: _
Sampling Personnel:


        (Name)

        (Phone)
Sampling Date:
       © For each sample collected specify numbei
          of containers used and mark volume level
          on each bottle.
                         Number of
                         Containers
       Water
       (Extractable)
 (Begrn)
(End)
Water
(VOA)
® Shipping Information
    Name of Carrier
      Date Shipped:
        Soil/Sediment
        (Extractable)
                        Soil/Sediment
                        (VOA)
                        Other
     Airbill Number:
® Sample Description

  	 Surface Water

  	 Ground Water

  	 Leachate
         Mixed Media

         Solids

         Other (specify).
                           Approximal
                           Total Volum
                                             JB
1 JB


 JB


 JB


 JB
                                                             JB
                                             JB
                                                             JB
                           ©SampleI JB

                                     JB
102

 102

102

 102

102

102

102

102

 Ib2

Iu2
- Water
 (Em-actable)


-Water
 (Extractable)


- Water
 (Extractable)


- Water
 (Extractable)

• Water
 (VOA)


- Water
 (VOA)


- Soil/Sediment
 (Extractable)


-Soil/Sediment
 (Extractable)


• Soil/Sediment
 (VOA)


- Soil 'Sediment
 I VOA I
(To) Special Handling Instructions:
   (e.g., safety precautions, hazardous nature)
                                     SMOCOPY
                                  FICURI: y
                Contract Laboratory Organic Traffic  Report

-------
                                                               Section No.:  X—ALL QAPs
                                                               Revision No.:      2	
                                                               Date:      March 1986
                                                               Page:      14    ofIs
 .sa
U.S.ENVmONMENTALPROTECnON AGENCY  HWI Sample Management Officef
P.O.Box818,Alexandria,VA22313-703/557-2490• FTS/557-2490^:'§vfx"; ;r£T^;l^^t~4hfr'
INORGANICS TRAFFIC REPORTER
                                            Sample Number
                                             MJA700
 (7) Case Number:.
    Sample Site Name/Code:
   Sampling Office: _

   Sampling Personnel:
   (Name)	

   (Phone) 	
   Sampling Date:

   (Begin)	
       (End)
®     Sample Description:
       (Check One)
	 Surface Water
	 Ground Water
	 Leachnte
	 Mixed Media
__ Solids
	 Other 	
               (specify)
MATC1IES ORGANIC SAMPLE NO.
© SAMPLE CONCENTRATION
           (Check One)
	Low Concentration
	Medium Concentration
                       © SAMPLE MATRIX
                                  (Check One)
                       	Water
                       	Soil/Sediment
                      (?) Shipping Information:

                      Name Of Carrier:
                      Date Shipped:
                      Airbill Number:
                         Mark Volume Level
                         On Sample Bottle
                         Check Analysis required
                         Task 1 & 2
                        - Task 3 Ammonia
                             Sulfide
                             Cyanide
                                         SMOCOPY
                                                         Ship To:
                                                                   Attn:

                                                                   Transfer
                                                                   Ship To:
                               |MJ  A 700  -Ta*kl&2


                                 J  A 700  -Ta*kl&2


                               |MJ  A 700   Ta.«k3


                                MJ  A 700  -TaA3


                                MJ  A 7 0 0   Task 3


                                MJ  A 700   Task3


                                MJ  A 700  -TaskS
                                       l-KJURI-  10
                      Contract Laboratory Inorganics Traffic Report

-------
                                                         Section No.:  X—ALL QAPs
                                                         Revision No.:      2	
                                                         Date:      March 1986
                                                         Page:      15    of    15
     US. ENVIRONMENTaLH^aiBCTION AGENCY CLP Sample Management Ofine
     PO. Box aiB-Afaomdna, Vigaa 22313 Phone 7D3/5572-»90-FT5/557-a«0 •.  -  .      -  •  r
                           FIELD SAMPLE RECOPUD
-' Case Number:
Sample Site Name/Code:




i) Sampling Office:

Sampling Personnel:


(name)

(phone)

Sampling Date:
(begin) tend)

8} Shipping Information:
(name of earner)
(date shipped;
(airoiL TTjrrjDer)
(D Field Sample Description:
_ Drum
__ Aq-aeous Liquid
._. Siuage
Sohd
Q!
Othpr

(L1 Known or Suspected Hazards:








'Jj Preparations Requested:
(check beiow)
Sample Volume:

__ Volatile Qrganics
. Base/Neuiral, Add,
TCDD
_ Pestades, PCS
Inorganics
_ Total Metals
Total Mercury
._ Strong Acid Anions

^ Ship To:


AttTv


v§) Sample Location:









1 5152

' 5152
T 5152
J 5152 .;
1 C 4 r O
J 0 1 D £
Special Handling Instructions:
                                  SMOCopy
                                 I'KilJRl'  II
                         High Iliixard TntlTic Report

-------
                                                           Section No.       XI
                                                           Revision No.      0
                                                           Date
                                                           Page      1    of
 XL  CALIBRATION PROCEDURES,  FREQUENCY; PREVENTAM  MAITENANCE
     The calibration procedures and frequencies for laboratory analytical methods will be
those specified in SW-846. If field measurements are to be taken, all equipment and the
appropriate check and calibration  procedures should be described by reference in the
QAPP.

     Maintenance of equipment is an important part of every laboratory and field
operation. In the Regional Laboratory, contract laboratory, or field operations, the
responsibility of routine operating care lies with the analysts using the instruments.
Every manufacturer furnishes instrument maintenance manuals for their equipment.
These are kept on file in each laboratory for frequent reference; adjustments or repairs
which cannot be performed to satisfy these manuals are contracted to the manufacturer's
service department or representative.

     Preventative maintenance procedures are discussed in detail in the Regional
Laboratory QA Manual.

     Preventive maintenance and check procedures for field instrumentation will be
described separately for each instrument identified for use  in the QAPP

-------
                                                          Section No.      XII
                                                          Revision  No.     0
                                                          Date
                                                          Page     1   of
                              ANALYTICAL PROCEDURES
Methods and references for most analyses are summarized in table 4.

Analysis of chemical and biological samples collected during field investigations will be
performed by the Regional laboratory or contract laboratory program with established
protocols and QA procedures described in SW-846 or contract requirements.  When
approved or recommended EPA procedures are not available, a written description of the
procedure will be included as a reference to an EPA recommended method and what
modification have been made.  Modifications to approved or recommended methods for
analytical methods will be described on the sample alteration checklist (in Appendix C,
page 4) of the QAPP.

-------
                                                            Section No.      XII
                                                            Revision No.     0
                                                            Date 	
                                                            Page    2    of	3
                                       Table 4
             Methods  and Minimum Detection Limits for RCRA  Analysis
Parameter
                                               SW-846 Method
Detection Limit
    ug/L
Igiiitability                                     1010
Corrosivity                                     9040
Reactivity                                     Sect.6
EPToxicity                                    1310

Antimony                                      7040,7041
Arsenic                                        7060
Barium                                        7080,7081
Cadmium                                      7130,7131
Chromium                                     7190,7191
Chromium, Hexavalent                          7196,7197

Lead                                          7420,7421
Mercury                                       7470
Nickel                                         7520,7521
Selenium                                       7740
Silver                                          7760

Halogenated Volatile Organics                   8010
Nonhalogenated Volatile Organics                8015
Aromatic Volatile Organics                      8020
Acrolein,  Acrylonitrile, Acetonitrile              8030
Phenols                                        8040
Pthalate Esters                                 8060
Organochlorine Pesticides and PCBs              8080
Nitroarornatics and Cyclic Ketones               8090
Polynuclear Aromatic Hydrocarbons              8100
Chlorinated Hydrocarbons                       8120
Organophosphorus Pesticides                     8140
Chlorinated Herbicides                          8150

Volatile Organics (GC/MS)                       8240
Semi-volatile Organics (GC/MS)                  8270

Polynuclear Aroinatic Hydrocarbons (HPLC)       8310

Total and  Amenable Cyanide                     9010
Total Organic Halides (TOX)                     9020
Su If ides                                        9030
pH                                             9040
   N/A
   N/A
   N/A
   N/A

200., 3.0
1.0
100., 2.0
5.0, 1.0
50., 1.0
verification

100., 1.0
0.2
40., 1.0
2.0
10.0

0.03-0.5*
1.0 ug/G sample
1.0 ug/G sample
1.0 ug/G sample
0.1-16.0*
0.29-3.0*
0.004-0.176*
0.06-5.0*
1.0 ug/G sample
0.03-1.19*
0.1-5.0*
0.1-200.0*

1.6-7.2
0.9-45.0*

0.4-2.3*

Not Defined
*     Dependent on individual compound within group.
ug/L  microgram per Liter
ug/G  microgram per gram

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                                                            Section No.      XII
                                                            Revision No.     0
                                                            Date 	
                                                            Page    3    of	3
                                   Table 4 (Cont'd)
Parameter


Sample Preparation - Metals

 Acid Digestion Procedure for Flame Atomic
 Absorption Spectroscopy

 Acid Digestion Procedure for Furnace Atomic
 Absorption Spectroscopy

 Acid Digestion of Oils, Greases, or Waxes

 Dissolution Procedure for Oils, Greases or Waxes

 Acid Digestions of Sludges

 Alkaline Digestion


Sample Preparation - Organics

 Separatory Funnel Liquid - Liquid Extraction

 Continuous Liquid - Liquid Extraction

 Acid-Base Cleanup Extraction

 Soxhlet Extraction

 Sonieation Extraction


Sample Introduction - Organics

 Purge and Trap
SW-846 Method Number
        3010


        3020

        3030

        3040

        3050

        3060




        3510

        3520

        3530

        3540

        3550




        5030

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                                                            Section No.      XIII
                                                            Revision No. 	0_
                                                            Date
                                                            Page    1    of
                    DATA  REDUCTION, VALIDATION  AND  REPORTING
     Each QAPP will identify individuals responsible for handling data, and describe the
type of information to be transmitted with the data at each step. In general, laboratories
will provide verified data sets to the Project Officer and/or designated QA Coordinator
with adequate documentation to allow independent data validation.  The Project Officer
and/or QA Coordinator is responsible for conducting checks for internal consistency,
transmittal errors, laboratory protocols, and finally, a check for complete adherence to
the quality control elements specified in  Sections 6, 9, 10, and 12 of this manual.

     Data storage needs unique to the WMB operations will be specified after
consultation with ESD data management  staff.  Such needs might include the way in which
data are referenced to original documents, particular data qualifiers to be used, the level
of detail with which sampling and analysis methods are to be described, and the inclusion
of certain types of descriptive information or additional data.  Procedures and criteria for
evaluating both historical data and new data for completeness and comparability for
database inclusion should be developed by the WMB  QA Coordinator in conjunction with
the ESD data management staff.  Any other procedures or criteria used by the HWMB or
their contractors for assessing data validity must be described in the QAPP.   All data
submitted by contractors must be in a form consistent with other WMB investigations and
compatible with the Regional Data Management System.

     The  data analysis scheme planned for collected data, including units, and statistical
tests to be used will be specified in  the QAPP.  While such specification may be by
citation from this guidance, the Project Officer should encourage a well thought out
project plan and should clearly identify additional data needs to ensure comparability with
study site reference data or historical comparisons


     Each project officer is responsible for the accuracy of the reduction of data to
reports or final file inclusion.  If precision or accuracy are outside of established
acceptance limits, data analyzed with that group of QA data must either be re-analyzed
or considered for corrective action. Where appropriate and defensible adjustments cannot
be made, the data should not be used.  The Project Officer is also responsible for  further
use or release of the data or derived project reports.

     Standardized forms are to be used for data collection, analysis requests, reduction
and reporting. While data are entered into the computer system, the forms package will
be submitted to the WMB following QA acceptance.


     On at least a yearly basis, WMB  will cooperate with the SMO/RSCC, ESD in a
review and audit of the computer system  records of analysis, etc. maintained on the
sample tracking and laboratory reporting systems.

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                                                           Section No.
                                                           Revision No.
                                                           Date  	
                                                           Page
                                             XIV
                                             0
                                      1
              of
                  XIV.  INTERNAL QUALITY CONTROL  CHECKS
     Each measurement system shall have predetermined limits to identify when
corrective action is required, hefore data becomes unacceptable. The QAPP will specify
(from Table 4, Section XII) the analytical procedures to be used to identify that point.

     The QAPP will address controls for accurate location of sampling stations, the
rationale used in selecting the number and location of those stations, for sample
collection, and for sample handling, and the type and frequency of QA/QC samples as set
forth in Table 5:
                       Table 5: Level Of Effort In QA Samplinj
Data Characteristic
Frequency*
 Evaluated  	
Sample Type
Recommended
Field/Transport
 Contamination

Field/Transfer
 Contamination

Sampling Equipment

Laboratory
Contamination

Accuracy (Field
variability

Accuracy
Precision (Field
Variability)

Precision (Lab
Variability)

Container
Contamination
Field Blank
Field Blank
Field Blank

Lab (reagent)
  Blank

Field Spiked
Standard
Addition (Spike)
and performance
evaluation samples
or standard reference
materials: One per
20 samples

Field
replicates

Laboratory
One  per batch run

Empty
Container
One per 20 samples


One per 20 samples


As appropriate Final Rinse

One per batch nui


One per 20 samples


One per 10 Samples
One per 20 samples or
One per sample event

One per 10 samples or
One per sample event

One per container lot
    Where two alternatives are cited, the recommended alternative is that resulting in
    more frequent analysis.  Where less than 20 samples are taken at a site, Transport
    and/or Transfer blanks shall be taken to provide QA even to the minimum sampling
    efforts.

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                                                           Section No.
                                                           Revision No.
                                                           Date  	
                                                           Page
                                             XIV
                                              0
                                      I
              of
                  XIV.  INTERNAL QUALITY CONTROL  CHECKS
     Each measurement system shall have predetermined limits to identify when
corrective action is required, before data becomes unacceptable. The QAPP will specify
(from Table 4, Section XII) the analytical procedures to be used to identify that point.

     The  QAPP will address controls for accurate location of sampling stations, the
rationale used in selecting the number and location of those stations, for sample
collection, and for sample handling, and the type and frequency of QA/QC samples as set
forth in Table 5:
                       Table 5: Level Of Effort In QA Sampling
Data Characteristic
Frequency
  Evaluated	
Sample Type
Recommended
Field/Transport
 Contamination

Field/Transfer
 Contamination

Sampling Equipment

Laboratory
Contamination

Accuracy (Field
variability

Accuracy
Precision (Field
Variability)

Precision (Lab
Variability)

Container
Contamination
Field Blank
Field Blank
Field Blank

Lab (reagent)
  Blank

Field Spiked
Standard
Addition (Spike)
and performance
evaluation samples
or standard reference
materials: One per
20 samples

Field
replicates

Laboratory
One  per batch run

Empty
Container
One per 20 samples


One per 20 samples


As appropriate Final Rinse

One per batch run


One per 20 samples


One per 10 Samples
One per 20 samples or
One per sample event

One per 10 samples or
One per sample event

One per container lot
    Where two alternatives are cited, the recommended alternative is that resulting in
    more frequent analysis.  Where less than 20 samples are taken at  a site. Transport
    and/or Transfer blanks shall be taken to provide QA even to the minim m sampling
    efforts.

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                                                            Section No.      XV
                                                            Revision No.     0
                                                            Date
                                                            Page     1    of
                    XV.  PERFORMANCE AND SYSTEM AUDITS
     Each QAPP will describe the internal and external performance and system audits
that will he required to monitor the capability and performance of the measurement
system(s).

     Performance and system audits for WMB sampling and analysis operations will
consist of on-site reviews of field and laboratory quality assurance systems and equipment
for sampling, calibration, and measurement.  This includes review of items such as
documentation of quality control data, completeness of field forms, field data storage and
filing procedures, and sample custody sheets. Environmental monitoring equipment will
be routinely maintained and calibrated during field use (see Preventive Maintenance).

     Region  10 Laboratory and contract laboratories are required to take part in
performance evaluation studies conducted by the Environmental Monitoring and Support
Laboratory (EMSL) in Cincinnati, OH.  and Las Vegas NV..  Results of these audits are
available from the  RQAMO.  For internal quality control applications, analytical
standards  used in preparing performance evaluation samples and guidance for their use
can be obtained from:

               Environmental Monitoring Systems Laboratory.  U.S. Environmental
               Protection Agency.  Las Vegas, NV  89114

               Environmental Monitoring Systems Laboratory.  U.S. Environmental
               Protection Agency.  Cincinnati, OH  45268


    The RQAMO in conjunction with the WMR QAC  will develop and conduct system
audits based on this manual and also conduct optional site technical audits of operations
detailed in the QAPPs.

    The WMB QAC ensures that each  aspect of a project detailed in a QAPP will have
performed adequate internal audits of performance and systems before submitting quality
assurance reports to the management.

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                                                         Section No.      XVI
                                                         Revision No.  	0_
                                                         Date
                                                         Page     1   of
         XVI.  SPECIFIC  ROUTIE  PROCEDURES USED TO ASSESS DATA
                  PRECISION, ACCURACY, AND COMPLETENESS
     The assessment of data precision, accuracy, completeness, and blanks will he made
by the HWMB project officer or QAC.


Assessment of Precision;

     The mean, C, of a series of replicate measurements if concentration, C[, is
     calculated as:
                                       i = 1

     where n = number of replicate measurements; C, Cj are both on mg/L or mg/Kg

     The estimate of precision of duplicate measurements is expressed as the relative
     percent difference (RPD):

                                RPD = Cg-Cj x 100
                                         C
     The RPD calculated will be compared with the respective goals identified in the
     QAPP.

     The estimate of precision of a series of replicate measurements (primarily used in
     GC/MS analysis) is expressed as the relative standard deviation (RSD) where:
                                        'n     _
                               RSD = ±/I](C1-O)2
                                      i = 1
                                       n-l
Assessment of Accuracy:
     Accuracy is monitored by analyzing standards, samples that have been spiked with
     standard solutions, and control sain pies. Approximately 10% of all samples are
     analyzed as spiked samples.  The accuracy of new analytical methods is verified by
     analyzing replicate spiked samples intermixed with routine samples.

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                                                            Section No.      XVII
                                                            Revision No.  	0_
                                                            Date
                                                            Page     1   of
                            XVI  CORRECTIVE ACTION
    Corrective actions can fall into two categories:

          1.    Handling of sampling analysis, data processing, or equipment failures.

          2.    Handling of non-confonnance or non-compliance with the QA
               requirements that have been set forth (objectives for measurement data).

    Each  QAPP will address the corrective measures to be taken for the method or
equipment failure type of problem.  It will include predetermined limits of sample and
data acceptability, identification of the corrective action, and the organizational level
responsible for approval of action.  Routine procedures for correcting and limiting data
processing errors will cover data coding, data entry, and data reporting.  A formal
corrective actions program is difficult to define in advance for the non-conformance or
non-compliance type of problem. Each QAPP will list who is responsible for taking
actions, when actions are to be taken, and who ensures that actions taken produce desired
results. A special form  is included with the example QAPP to facilitate such
documentation.

    Corrective actions will be taken by the project officer when data are found to be
outside the predetermined limits of acceptability. The acceptable data range will be
listed on the corrective  action form,  which also provides a checklist  for procedures to be
followed.

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                                                          Section No.      XVIII
                                                          Revision No.     0
                                                          Date
                                                          Page     1    of
            XVE  QUALITY ASSURANCE REPORTS TO MANAGEMENT
     Reports to the WMB Branch Chief and the Project Officer will be made periodically
by the QA Coordinator. QAPPs will identify the mechanism of and the points to which
the reports will be made.  QA reporting should be tied to the completion of various
elements of the QAPP rather than to general time periods.  The reports will contain
information regarding data accuracy, precision, completeness, result of system mid
performance audits along with any reports of corrective action, sample alteration, or
other significant QA problems.  Through this mechanism, effective solutions to project
problems may be developed and applied.

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                                                             Section No.      XIX
                                                             Revision No. 	0_
                                                             Date
                                                             Page     1    of
                                    XH.  SAFETY
    RCRA inspectors must occasionally deal with the risk of incurring illness or injury
while conducting investigations.  They cannot anticipate every hazard, so they must take
precautions to prevent illness or injury to themselves, other workers, and the public.

    Since RCRA inspectors cannot eliminate risk, they must reduce it to the lowest
feasible level.  No set of rules can be uniformly applied to every situation.  The Project
Officer must judiciously apply the guidelines of the EPA Standard Operating Safety
Guides (SOSG) at each site visited.  The  Project Officer must access those variables
peculiar to each investigation in order to establish appropriate safeguards.  The EPA
Region 10 Safety and Health Officer (RSHO) is available at 442-0370 for consultation on
appropriate levels of protection, equipment, etc. to use for each investigation.

    Generally, all RCRA  site inspections requiring the collection  of samples or potential
exposure to toxic materials will require a site safety  plan. The Project Officer is
responsible for preparing the site safety  plan.  If the  investigation is quite complex, the
RSHO will prepare or assist with  the preparation of the plan.  The site safety plan in
non-emergency situations must be written,  posted, distributed and signed by all project
team  members, and discussed with  them prior to visiting the site.  Emergency situations
may require verbal safety instruction and use of standard operating procedures until
specific protocols can be written. The SOSG will be used as standard operating procedure
in emergency situations.

    Annex 9  and 10  of the SOSG  are two examples of site safety plans.  Examples of job
functions requiring to use of levels C  and B  are described on pages A9-2 and A9-3 of the
SOSG.

    All RCRA inspectors must complete training as described in the Regional  Policy on
Health, Safety  and Proficiency Training before being  allowed to participate in a RCRA
inspection or investigation.

    Special safety considerations may be addressed as part of the QAPP. I3ecause a
formal safety plan is already required as separate documentation on any field activity,
such considerations would only address the possible effect of plan  limits on achieving data
quality objectives.

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                                     APPENDIX A
                                GLOSSARY OF TERMS
AUDIT

A systematic check to determine the quality of operation of some function or activity.
Audits may be of two basic types: 1) performance audits on which quantitative data are
independently obtained for comparison with routinely obtained data in a measurement
system,  or 2) system audits of a qualitative nature that consist of an on-site review of a
laboratory's quality assurance system  and physical facilities for sampling, calibrations,
and measurement.


CHAIN-OF-CUSTODY

Documentation that describes the physical control of a sample, measurement or document.


DATA QUALITY

The totality of  features and characteristics of data that bears on its ability to satisfy a
given purpose.  The characteristics of major importance are accuracy, precision,
completeness, representativeness, and comparability. These characteristics  are defined
as follows:

      -     Accuracy - the degree of agreement of a measurement (or an average of
           measurements of the same thing), X, with accepted reference or  true value, T,
           usually expressed as the difference between the two values, X-T, or the
           difference as a percentage of the reference or true value, 100 (X-T)/T, and
           sometimes expressed as a ratio, X/T. Accuracy is a measures of  the bias in
           the  system.

           Precision - a measure of mutual agreement among individual measurements of
           the  same property, usually under prescribed similar conditions. Precision is
           best expressed in terms of the standard deviation. Various measures of
           precision exist depending upon the "prescribed similar conditions."

           Defensibility - ability to document the  origin, chain of custody, matrix of
           scientifically acceptable operations performed, reduction, and transcription of
           data, so that their limitations, representativeness, and applicability are known.

      -     Completeness - a  measure of the amount of valid data obtained from  a
           measurement system compared to the amount that was expected  to be
           obtained under correct normal conditions.

           Representativeness - expresses the degree to which data accurately and
           precisely represent a characteristic of a population, parameter variations at a
           sampling point, a process condition, or an environmental  condition.

           Comparability - expresses the confidence with which one data set can be
           compared to another.

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DATA VALIDATION

A systematic process for reviewing a body of data against a set of criteria to provide
assurance that the data are adequate for their intended use. Data validation consists of
data editing, screening, checking, auditing, verification, certification, and review.


ENVIRONMENTALLY RELATED MEASUREMENTS

Terms used to describe essentially all field and laboratory investigations that generate
data involving I) the measurement of chemical, physical, or biological variables in the
environment, 1) the determination of the presence or absence of contaminants in waste
streams, 3) assessment of health and ecological effect studies, 4) conduct of clinical and
epidemiological investigations, 5) performance of engineering and process evaluations, 6)
study of laboratory simulation of environmental events, and 7) study or measurement of
pollutant transport and fate, including dispersion models.


PERFORMANCE AUDITS

Procedures used to determine quantitatively the accuracy of the total measurement
system or component parts thereof.


QUALITY ASSURANCE

The total integrated program for assuring the reliability of monitoring and measurement
data. A system for integrating the quality planning, quality assessment, and quality
improvement efforts to meet user requirements.


QUALITY ASSURANCE PROGRAM PLAN

An orderly assemblage of management policies, objectives, principles, and general
procedures by which an agency or laboratory outlines how it intends to produce data of
known and accepted quality.


QUALITY ASSURANCE PROJECT PLAN

An orderly assembly of detailed and specific procedures which delineates how data  of
known and acceptable quality are produced for a specific project. (A given agency or
laboratory would have only one quality assurance plan, but would have a specific Quality
Assurance Project Plan(QAPP) for each of its projects.)


QUALITY CONTROL

The routine application of procedures for obtaining prescribed standards of performance
in the monitoring and measurement process.


STANDARD OPERATING PROCEDURE (SOP)

A written document that details an operation, analysis, or action whose mechanisms are
thoroughly prescribed and that is commonly accepted as the method for performing
certain  tasks.

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                  APPENDIX B
        CODE OF FEDERAL REGULATIONS






  TITLE 40: PROTECTION OF THE ENVIRONMENT






Part 261: Identification and Listing of Hazardous Waste



          as amended through July 1, 1984

-------
Environmental Protection Agoncy

  PART 261— IDENTIFICATION AND
  LISTING OF HAZARDOUS WASTE
Sec.
261.1  Purpose mnd icope.
261.3  Definition of solid wute.
261.3  Definition of hazardous waste.
261.4  Exclusions.
261.5  Special requirements for hazardous
   waste generated  by small quantity gen-
   erators.
261.6  Requirement* for recyclable materi-
   als.
261.7  Residues  of  hazardous  waste  In
   empty containers.


  Urlifict *f HawsWi Wmto «nd fw U»H«fl
           Wmtot
261.10  Criteria for Identifying the charac-
   teristics of hazardous waste.
261.11  Criteria for listing hazardous waste.
   SofcfM


261.20
261.21
261.22
261.23
261.24
       General.
       Characteristic of Instability.
       Characteristic of corroslvity.
       Characteristic of reactivity.
       Characteristic of EP toxlclty.
   Sufcp
             Ucta *f H«ur4*v* W««M
261.30  General.
261.31  Hazardous wastes from non-specific
   sources.
261.32  Hazardous  wastes  from  specific
   sources.
261.33  Discarded  commercial   chemical
   products, off-specification species,  con-
   tainer residues, and spill residues there-
   of.
              APPENDICES
APPENDIX   I—REPRESENTATIVE   SAMPLING
   MTTHODS
APPENDIX II—KP  Toxicrrv  TEST PROCE-
   DURES
APPENDIX  III—CHEMICAL ANALYSIS  TEST
   METHODS
APPENDIX IV—(RESERVED FOR  RADIOACTIVE
   WASTE TEST METHODS]
APPENDIX  V—(RESERVED FOB  INFECTIOUS
   WASTE TREATMENT SPECIFICATIONS]
APPENDIX  VI—[RESERVED  FOR  ETIOLOOIC
   AGENTS]
APPENDIX VII—BASIS FOR LISTING HAZARD-
   OUS WASTE
APPENDIX VIII—HAZARDOUS CONSTITUENTS
APPENDIX  IX—WASTES  EXCLUDED  UNDER
   1(260.20 AND 260.22
                                                                     §261.1

                                       Sec.
                                       APPENDIX  X—METHOD  OF ANALYSIS  FOR
                                          CLORINATED DIBENZO-P-DIOXINS AND Di-
                                          BENZOFUIIANS

                                         AUTHORITY: Sees. 1006, 2002(a), 3001 and
                                       3002 of  the Solid  Waste Disposal  Act. as
                                       amended by the Resource Conservation and
                                       Recovery Act of 1076. as amended (42 U£.C.
                                       6005. 6«12(a). 6921.  and 6022).

                                         SOURCE 45 PR 33110, May 10. 1080. unless
                                       otherwise noted.
         Subport A—General

B 261.1  Purpose and scope.
  (a) This part Identifies those solid
wastes which are subject to regulation
as hazardous  wastes under Parts 262
through 26S and Parts 270. 271. and
124 of  this chapter and which are sub-
ject to the notification  requirements
of section 3010 of RCRA. In this part:
  (1)  Subpart A defines the  terms
"solid  waste"  and "hazardous waste,"
Identifies those wastes which are ex-
cluded  from  regulation  under Parts
262 through 265. 270, 271 and 124 and
establishes  special  management  re-
quirements for  hazardous waste pro-
duced  by  small quantity generators
and hazardous waste which is used, re-
used, recycled or reclaimed.
  (2) Subpart  B sets forth the criteria
used by EPA to identify  characteris-
tics of hazardous waste and to list par-
ticular hazardous wastes.
  (3) Subpart C identifies characteris-
tics of  hazardous waste.
  (4) Subpart D lists particular haz-
ardous wastes.
  (b)(l) The definition of solid waste
contained in this part applies only  to
wastes that also are hazardous for pur-
poses of the regulations implementing
Subtitle C of RCRA. For example, it
does not apply  to materials (such  as
non-hazardous scrap,  paper, textiles,
or rubber) that  are not otherwise haz-
ardous wastes and that are recycled.
  (2) This part identifies only some  of
the materials which are  solid wastes
and hazardous wastes under Sections
3007, 3013, and 7003  of RCRA. A mate-
rial which  is not defined as  a solid
waste in this  part, or is not  a hazard-
ous waste identified or  listed  in this
part. Is still a solid waste and a hazard-
§261.2

ous waste  for purposes of these sec-
tions If:
  (I) In the case of Section* 3007 and
3013.  EPA has reason to believe that
the material  may be  a solid waste
within   the  meaning   of   Section
1004(27) of RCRA  and a  hazardous
waste within the  meaning  of  Section
1004(5) of RCRA: or
  (ii)  In the case of Section 7003, the
statutory elements are established.
  (c) For the purposes of (| 261.2 and
261.6:
  (DA "spent material" Is any materi-
al that has been used and  as a result
of contamination  can no longer serve
the purpose for which it was produced
without processing;
  (2)  "Sludge" has the same meaning
used in f 260.10 of this chapter:
  (3) A "by-product" Is a material that
Is not one of the primary products of a
production process and Is not solely or
separately produced by the  production
process. Examples are process residues
such  as slags  or distillation  column
bottoms. The term does not Include a
co-product  that  is produced  for the
general public's use and Is ordinarily
used in the form It is produced by the
process.
  (4)  A material is "reclaimed" If it Is
processed to recover a usable product,
or if it is regenerated.  Examples  are
recovery of lead values from spent bat-
teries and regeneration of spent sol-
vents.
  (5)  A material is "used or reused" if
It Is either
  (1)  Employed  as an  ingredient (In-
cluding use as an Intermediate) in an
industrial process to make a  product
(for  example,   distillation  bottoms
from one process used as feedstock In
another process).  However, a material
will not satisfy this condition if dis-
tinct components of the material  are
recovered as separate end products (as
when  metals  are  recovered  from
metal-containing secondary materials);
or
  (11) Employed in a particular func-
tion or application as an effective sub-
stitute for a commercial product (for
example, spent pickle  liquor  used  as
phosphorous  precipitant  and sludge
conditioner in wastewater treatment).
  (6) "Scrap metal" is bits and pieces
of  metal parts (e.g..)  bars, turnings.
         40 CFR Ch. I (7-1-M Edition)

rods, sheets, wire) or metal pieces that
may be combined together with bolts
or soldering (.e.g.. radiators, scrap auto-
mobiles,  railroad  box  cars),  which
when worn or superfluous can be recy-
cled.
  (7) A material Is  "recycled"  If It is
used, reused, or reclaimed.
  (8) A material IB "accumulated spec-
ulatively"  If it Is accumulated  before
being recycled. A material Is not accu-
mulated speculatlvely, however, if the
person accumulating it can show that
the material  Is potentially recyclable
and has a feasible means of being recy-
cled;  and  that—during the  calendar
year (commencing on January  1)—the
amount of material that Is recycled, or
transferred to a different site for recy-
cling,  equals at least  75 percent  by
weight or volume of the amount of
that material accumulated at the be-
ginning  of the period. In calculating
the percentage of turnover, the 75 per-
cent requirement Is to be applied to
each material of  the same type  
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Environmental Protection Agency

  (U) Recycled, as explained in  para-
graph (c) of this section; or
  (ill)  Considered  inherently  itxute-
lUce, as explained In paragraph (d) of
this section.
  (b) Materials are solid waste If they
are abandoned by being:
  (1) Disposed of; or
  (2) Burned or incinerated: or
  (3) Accumulated, stored, or  treated
(but not recycled) before or in lieu of
being abandoned by being disposed of,
burned, or Incinerated.
  (c) Materials are solid wastes if they
are  recycled—or accumulated, stored.
or treated before  recycling—as speci-
fied  in  paragraphs   (cKl)  through
  Materials  listed  In  paragraph
(d)(l) of this section.
  (f)  Documentation  of claim*  that
materials are not tolid wattes  or an
conditionally exempt from regulation.
Respondents in actions to enforce reg-
ulations implementing Subtitle C of
RCRA who raise a claim that a certain
material Is not a solid waste, or Is con-
ditionally  exempt  from  regulation.
must   demonstrate  that there is  a
known market or disposition for  the
material,  and  that they  meet  the
terms of  the exclusion or exemption.
In doing so, they  must provide  appro-
priate  documentation  (such as  con-
tracts showing that a second  person
uses the material  as an ingredient in a
production  process) to  demonstrate
that the material is not a waste, or is
exempt from  regulation. In addition,
owners or operators of  faculties claim-
ing that  they  actually are recycling
materials must  show  that  they have
the necessary equipment to do so.
[60 FR 604, Jan. 4. 1985)
  Emcrmt DATI Nore At 50 PR «64,  Jan.
4, 1885. | 261.2 was revised, effective July 5.
196S (except for paragraph (e) which was ef-
fective December 20. 1984). For the conven-
ience of the user, the superseded text Is set
out below:
         40 CFR Ch. I (7-l-a5 E«Uti«i)

IMU  Definition of *olU wuU.
  (a) A Mild WMU Is city garbage, refuse.
sludge or any other waste material which U
not excluded under I 361.4(a).
  (b) An "other waste materlaT U any solid,
liquid. semi-solid or contained gaseous mate-
rial, resulting from Industrial, commercial.
mining or agricultural operation*, or from
community activities which:
  (1) b discarded or Is being  accumulated.
stored or physically, chemically or biologi-
cally treated prior to being discarded: or
  (2) Has served Its original  Intended  use
and sometimes Is discarded; or
  (3) Is a manufacturing or mining by-prod-
uct and sometimes Is discarded.
  (c) A material Is "discarded" U It U aban-
doned (and not used, re-used,  reclaimed or
recycled) by being:
  (1) Disposed of: or
  O) Burned or Incinerated, except where
the material Is being burned as a fuel  for
the purpose of recovering usable energy; or
  (» Physically, chemically, or biologically
treated (other than burned or Incinerated)
In Ueu of or prior to being disposed of.
  (d) A material ls "disposed or U It ls  dis-
charged,   deposited.   Injected,  dumped,
spilled, leaked or placed into or on any land
or water so that such material or any con-
stituent thereof may enter the environment
or be emitted Into the air or discharged Into
ground or surface waters.
  (e) A "manufacturing or mining by-prod-
uct" Is a material that Is not one of the  pri-
mary  products of a particular manufactur-
ing or mining operation. Is a secondary  and
Incidental  product of the particular oper-
ation and would not be solely and separate-
ly manufactured or mined by the particular
manufacturing  or mining operation. The
term does not Include an Intermediate man-
ufacturing or mining- product which results
from one of the steps In a manufacturing or
mining process and Is typically  processed
through the next step of the process within
a short time.

1260 Definition of hazardous waste.
  (a) A solid waste,  as  defined   in
1201.2. la a hazardous waste U:
  (1) It is not excluded from regula-
tion  as  a  hazardous  waste  under
I 2«1.4(b); and
  (2) It meets any of the following  cri-
teria:
  (1) It exhibits any of  the characteris-
tics of  hazardous waste identified in
Subpart C.
  (11) It is listed In Subpart D and  has
not been excluded from the  lists In
Subpart D  under f{ 200.20 and 200.22
of this chapter.
                                     353
                                                                                                                           354

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  vlronmtintal Protection Agoncy

  111) It is a mixture of a solid waste
  d a hazardous waste that is listed in
  ibpart D solely because  It exhibits
  e or more of the  characteristics of
  .zardous waste identified in Subpart
   unless the resultant  mixture  no
  ager  exhibits any characteristic of
  .zardous waste identified in Subpart

  ;iv) It is a mixture  of solid waste and
  .e or more hazardous wastes listed In
  ibpart D and has not been excluded
  3m this paragraph under || 260.20
  id 260.22 of this  chapter; however,
  e following mixtures of solid wastes
  id hazardous wastes  listed In Sub-
  j-t D  are   not hazardous  wastes
  xcept by application of paragraph
  )(2) (1) or (U) of this  section) if the
  nerator can demonstrate  that the
  ixture consists of wastewater the dls-
  iarge of which is subject  to  regula-
  3n under either Section 402  or See-
  in 307(b) of the Clean Water Act (in-
  jding wastewater at facilities which
  we  eliminated  the  discharge  of
  istewater) and:
  (A) One  or  more  of the  following
  >ent   solvents  listed  in  8261.31—
  j-bon tetrachloride, tetrachloroethy-
  ne, trichoroethylene—provided that
  ie maximum total  weekly  usage of
  lese   solvents   (other   than   the
 nounts that can be  demonstrated not
 * be discharged to wastewater) divld-
 1 by  the average   weekly flow of
 astewater into the  headwords of the
 ^clltty's wastewater  treatment  or pre-
 •eatment system does not  exceed 1
 art per million; or
  (B) One or  more  of the  following
 >ent solvents listed in i 261.31— meth-
 ,ene  chloride.  1.1.1-trlchloroethane,
 ilorobenzene. o-dichlorobenzene, cre-
 ils, cresyllc acid, nitrobenzene, tolu-
 ne. methyl ethyl ketone, carbon dl-
 ilfide.  isobutanol,   pyridlne.   spent
 olorofluorocarbon solvents—provided
 lat the maximum total weekly usage
 [ these  solvents  (other  than  the
 mounts that can be  demonstrated not
 3 be discharged to wastewater) dlvid-
 d by  the average   weekly flow of
 •a&tewater into the  headworks of the
 icillty's wastewater  treatment  or pre-
 reatment system does  not  exceed 25
 arts per million; or
 (C) One  of  the   following  wastes
ated   in   i 261.32—heat  exchanger
                              § 261.3

bundle cleaning sludge from the petro-
leum refining Industry (EPA Hazard-
ous Waste No. KOSO); or
  (D) A  discarded commercial chemi-
cal product, or  chemical  Intermediate
listed In  ( 261.33, arising from at mini-
mis  losses  of  these  materials  from
manufacturing  operations  in  which
these materials are used as raw mate-
rials or are produced In the manufac-
turing process.  For purposes of  this
subparagraph. "de minimi*" losses In-
clude those from normal material han-
dling operations (e.g. spills  from the
unloading  or  transfer of  materials
from bins  or other containers, leaks
from pipes,  valves  or other devices
used  to  transfer  materials);  minor
leaks of process equipment,  storage
tanks or containers;  leaks from well-
maintained pump packings and seals;
sample   purgings;  relief  device  dis-
charges; discharges from safety show-
ers and rinsing and cleaning of person-
al safety equipment;  and rinsate from
empty containers or from  containers
that are rendered empty  by  that rins-
ing; or
  (E) Wastewater resulting from labo-
ratory operations containing toxic (T)
wastes listed  In Subpart D,  provided
that  the annuallzed average  flow  of
laboratory wastewater does not exceed
one  percent of  total wastewater  flow
into the headworks  of the  facility's
wastewater  treatment  or  pre-treat-
ment system, or provided the wastes,
combined annualized average concen-
tration  does not exceed one  part per
million in the headworks of the facili-
ty's wastewater treatment or pre-treat-
ment facility. Toxic (T) wastes used in
laboratories  that  are  demonstrated
not to be discharged to wastewater are
not to be Included In this calculation.
  (b) A  solid waste which is not ex-
cluded  from  regulation  under para-
graph (aXI) of  this section becomes a
hazardous waste when  any of the fol-
lowing events occur:
  (1)  In  the case of  a  waste listed  in
Subpart D. when the waste first meets
the  listing description set   forth  in
Subpart D.
  (2)  In the case of a mixture of solid
waste and one or more listed hazard-
ous  wastes, when a  hazardous waste
listed in Subpart D  is first added  to
the solid waste.
§ 261.4

  (3) In the  case of any  other waste
(Including a waste mixture), when the
waste exhibits any of the characteris-
tics Identified in Subpart C.
  (c) Unless and until It meets the cri-
teria of paragraph (d):
  (1)A hazardous waste will remain a
hazardous waste.
  (2X0 Except as otherwise provided
in paragraph (c)(2)(ll> of  this section,
any  solid waste generated from the
treatment, storage,  or disposal  of a
hazardous waste. Including any sludge,
spill  residue, ash,  emission control
dust,  or leachate (but not  including
precipitation run-off)  is a  hazardous
waste. (However, materials that are re-
claimed from solid wastes and that are
used beneficially are not  solid wastes
and  hence are  not  hazardous wastes
under this  provision  unless the  re-
claimed material is burned for energy
recovery or used in a manner consti-
tuting disposal.)
  (U)  The  following solid wastes are
not hazardous even though they are
generated  from  the treatment,  stor-
age, or disposal of a hazardous waste,
unless they exhibit one or more of the
characteristics of hazardous waste: (A)
Waste pickle liquor sludge generated
by lime  stabilization of spent  pickle
liquor from the iron and steel industry
(SIC Codes 331 and 332).
  (d)  Any solid waste  described  in
paragraph (c) of this section is not a
hazardous waste if It meets the follow-
ing criteria:
  (1) In the case of any solid waste. It
does not exhibit any of the character-
Istlcs of hazardous waste  identified in
Subpart C.
  (2) In the case of a waste which is a
listed waste under Subpart D, contains
a waste listed under Subpart D or is
derived from a waste listed in Subpart
D. it  also  has been  excluded  from
paragraph  (c)  under  |( 260.20  and
260.22 of this chapter.

[46 FR 33118, May 19. 1080. u amended at
46 FR 56588,  Nov. 11, 1981; 60 FR  14218.
Apr. 11, 1985}
  Erncnvi DATI  Norr At 60 FR 664, Jan.
4. 1986. and corrected at 60 FR 14219. Apr.
11. 1985, |261.3(cK2) was revised, effective
July 5, 1985.  For the convenience of  the
user, the superseded text Is »et out below:
         40 CFR Ch. I (7-1-15 Edition)

I Ml 4 DeflnHlM of haaardaw waste.
  (C)' * *
  (2X1) Except as otherwise  provided In
paragraph 
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Environmental Protection Agency

recovery furnace and then reused In
the pulping proceu, unleu It Is accu-
mulated ipeculatlvely as  defined  In
I 261.KO of this chapter.
  (7)  Spent sulfurtc  acid  used  to
produce virgin  sulfurtc acid, unless It
is accumulated speculatlvely as  de-
fined In | 261.Kc) of this chapter.
  (b)  Solid wutet which art not hat-
ardout   vxutei.  The following  solid
wastes are not hazardous wastes:
  (1)   Household  waste,   including
household waste that has been collect-
ed, transported, stored,  treated,  dis-
posed,  recovered (e.p.. refuse-derived
fuel), or reused. "Household waste"
means  any  waste material  (Including
garbage, trash  and  sanitary wastes In
septic tanks) derived from  households
(Including  single and multiple  resi-
dences,  hotels   and motels,  bunk-
houses, ranger stations, crew quarters,
campgrounds, picnic grounds, and day-
use recreation areas).
  (2) Solid wastes generated by any of
the following and which are returned
to the soils as fertilizers:
  (1) The growing  and  harvesting of
agricultural crops.
  (11) The raising of anim^iy, Including
animal manures.
  (3)  Mining overburden returned to
the mine site.
  (4) Fly ash waste, bottom ash waste,
slag waste, and flue gas emission con-
trol waste  generated primarily  from
the combustion  of coal or other fossil
fuels.
  (5) Drilling fluids, produced waters.
and other wastes associated with the
exploration,  development,  or produc-
tion of  crude oil, natural gas or geo-
thermal energy.
  (6X1) Wastes  which fail the test for
the characteristic of EP toxiclty be-
cause chromium is  present or  are
listed In Subpart D due to the pres-
ence of chromium,  which  do not fall
the test for  the characteristic of EP
toxicity for any other constituent or
are not listed due to the presence of
any other constituent, and which  do
not fall the text for any other charac-
teristic, if it is shown by a waste gener-
ator or by waste generators that:
  (A)  The chromium in  the waste is
exclusively (or  nearly exclusively) trt-
valent chromium; and
                             § 261.4

  (B) The waste Is generated from an
Industrial process which uses trivalent
chromium exlcuslvely (or nearly exclu-
sively) and the process does not gener-
ate hexavalent chromium; and
  (C) The  waste Is typically and fre-
quently managed In non-oxidizing en-
vironments.
  (II) Specific wastes which meet the
standard  in  paragraphs  (b)(6)UMA),
(B) and (C) (so long as they do not fall
the  test for  the charactrtstlc of EP
toxiclty. and do not fall the  test for
any other characteristic) are:
  (A) Chrome (blue) trimmings gener-
ated by the following subcategories of
the leather tanning and finishing In-
dustry; hair  pulp/chrome tan/retan/
wet finish;  hair  save/chrome tan/
retan/wet finish; re tan/wet  finish; no
beamhouse;   through-the-blue;   and
shearling.
  (B) Chrome (blue) shavings generat-
ed  by  the following subcategories of
the  leather tanning and finishing In-
dustry: hair  pulp/chrome tan/retan/
wet finish;  hair  save/chrome tan/
retan/wet finish; retan/wet  finish; no
beamhouse;   through-the-blue;   and
shearling.
  (C) Buffing dust generated by the
following subcategories of the leather
tanning  and  finishing Industry;  hair
pulp/chrome  tan/retan/wet  finish;
hair    save/chrome   tan/retan/wet
finish;  retan/wet  finish;  no beam-
house; through-the-blue.
  (D) Sewer  screenings generated by
the  following subcategories  of  the
leather tanning and finishing indus-
try: hair  pulp/crome tan/retan/wet
finish;  hair  save/chrome tan/retan/
wet finish; retan/wet finish; no beam-
house;  through-the-blue; and shear-
ling.
  (E)  Wastewater  treatment sludges
generated by the following subcategor-
ies of  the leather tanning and finish-
Ing  industry:  hair  pulp/chrome  tan/
retan/wet  finish;  hair  save/chrome
tan/retan/wet   finish;     retan/wet
finish;  no beamhouse;  through-the-
blue; and shearling.
  (F)  Wastewater  treatment  sludes
generated by the following subcategor-
ies of  the leather tanning and finish-
Ing  Industry:  hair  pulp/chrome  tan/
retan/wet  finish;  hair  save/chrome-
§ 261.4

tan/retan/wet  finish;  and  through-
the-blue.
  (O) Waste  scrap  leather from the
leather  tanning  Industry,  the  shoe
manufacturing  Industry,  and  other
leather product manufacturing Indus-
tries.
  (H) Wastewater treatment sludges
from the production of TiO, pigment
using chromium-bearing  ores by the
chloride process.
  (7) Solid waste from  the extraction.
beneficlatlon  and processing of ores
and  minerals (including coal),  includ-
ing  phosphate  rock and overburden
from the mining of uranium ore.
  (8) Cement kiln dust waste.
  (9) Solid waste which consists of dis-
carded wood or wood products which
falls the test for the characteristic of
EP toxiclty and which is not a hazard-
ous waste  for any other reason If the
waste is generated by persons who uti-
lize  the  arsenical-treated wood  and
wood products for these materials' In-
tended end use.
  (c) Hazardous wastes which are ex-
empted from  certain  regulations. A
hazardous waste which  is generated in
a  product  or raw  material storage
tank, a product or raw  material trans-
port vehicle or vessel, a product or raw
material pipeline,  or In a manufactur-
ing process unit or an associated non-
waste-treatment-manufacturing   unit,
is not subject to  regulation under
Parts 262  through  265. 270. 271 and
124 of this chapter  or to the notifica-
tion requirements of Section 3010 of
RCRA until it exits the unit In which
It was generated,  unless the unit Is a
surface  Impoundment,  or unless the
hazardous waste remains In the unit
more than  90 days after the  unit
ceases to be operated for manufactur-
ing, or for storage or transportation of
product or raw materials.
  (d) Samples. (1) Except as provided
In paragraph (d)(2) of  this section, a
sample of solid waste or a  sample of
water,  soil, or air, which Is collected
for the sole purpose of testing to de-
termine its characteristics or composi-
tion, is not subject to any require-
ments  of  this  part  or  Parts  262
through 267 or Part 270 or Part 124 of
this  chapter or to the notification re-
quirements of Section 3010 of RCRA,
when:
         40 CM Ch. I (7-1-C5 Edition)

  (1) The sample Is being transported
to a laboratory for the purpoae of tast-
ing; or
  (II) The sample Is being transported
back to the sample collector after test-
ing; or
  (111) The aample Is being stored by
the sample collector before transport
to a laboratory for testing; or
  (Iv) The aample is being stored In a
laboratory before testing; or
  (v) The sample Is  being stored In a
laboratory after testing but before It Is
returned to the aample collector or
  (vl) The aample Is being stored tem-
porarily In the laboratory after testing
for a specific  purpose (for example,
until conclusion of a court case or en-
forcement  action where further test-
Ing of the aample may be necessary).
  (2) In order to qualify  for the ex-
emption In  paragraphs (dXl) (1) and
(11) of this section,  a sample collector
shipping samples to a laboratory and a
laboratory  returning  samples  to  a
aample collector must:
  (1) Comply with U.S. Department of
Transportation  (DOT).  U.S.  Postal
Service  (USPS), or any other applica-
ble snipping requirements: or
  (11)  Comply with the following re-
quirements if the sample collector de-
termines that DOT, USPS. or  other
shipping requirements  do not apply to
the shipment of the sample:
  (A) Assure that the  following Infor-
mation accompanies the sample:
  (1)  The aample  collector's  name.
mailing-   address,   and    telephone
number
  (2) The laboratory's name, mailing
address, and telephone number
  (J) The quantity of the sample;
  (4) The date of shipment; and
  (5) A description of the sample.
  (B) Package the  sample so that It
does not leak, spill, or vaporize from
Its packaging.
  (3) This exemption does not apply If
the laboratory  determines that the
waste Is hazardous but the laboratory
is no longer meeting any of the condi-
tions stated in paragraph (dXl) of this
section.

(45 PR 33119. May 19, 1880. as amended at
46 PR 72037, Oct. 30.  1980; 45 PR  70620
Nov. 19. 1980; 45 PR 78931. Nov. 25. 1980: 45
PR 80287. Dec. 4, 1980: 46 PR 27476. Hay
20. 1981; 46 PR 47429, Sept. 25. 1981; 48 PR
                                   357
                                                                                                                     358

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Environmental Protection Agency

14293. Apr.  1. 1883; 48 PR 10116. June 30.
1983; 49 FR 44980, Nov. 13. 1984: 80 PR 645.
Jut. 4. 1986: 60 FR 14219. Apr. 11. 1986]
  Emcrivc DAT* NOTE At BO FR 686. Jan.
4. 1986. as corrected at 60 FR 14219. Apr. 11.
1986. |281.4(3).
or 266.36 is not Included in the quanti-
ty determinations of  this section and
is not subject to any requirements of
this section.  Hazardous waste that is
subject to the requirements of  {261.6
(b) and  (c) and  Subparts C, D.  and F
of Part 266 is included in the quantity
determination of  this  section  and is
subject  to the  requirements of this
section.
  (d) In determining the quantity of
hazardous waste he generates, a gener-
ator need not include:
  (1) His  hazardous waste when it is
removed from on-site storage; or
  (2) Hazardous waste produced by on-
slte treatment of his hazardous waste.
  (e) If a small  quantity generator
generates acutely hazardous waste in a
calendar month  in quantities greater
than set forth below, all quantities of
that acutely hazardous waste are sub-
ject to  regulation under  Parts  262
through 265 and Parts 270 and  124 of
this chapter, and  the notification re-
quirements of Section 3010 of RCRA:
  (DA total of one kilogram of acute
hazardous wastes  listed in  {{ 261.31.
261.32. or 261.33(e).
  (2) A total  of  100 kilograms of any
residue or contaminated soil, waste or
                              5 261.5

other debris resulting from the clean-
up of a spill, into or on any  land or
water, of  any acute hazardous wastes
listed in if 261.31, 261.32. or 261.33(e).
  (f) A small quantity generator may
accumulate hazardous waste on-site. If
he accumulates at any time more than
a total of 1000 kilograms of his haz-
ardous waste, or his acutely hazardous
wastes In quantities greater than set
forth in paragraph (eXl) or (e)(2) of
this  section, all of those accumulated
wastes  for  which  the accumulation
limit was  exceeded are subject to regu-
lation under Parts 262  through  265
and  Parts 270 and  124 of this chapter,
and  the  notification  requirements of
Section  3010  of  RCRA.  The  time
period of | 262.34 for accumulation of
wastes on-slte begins for a small quan-
tity  generator when the accumulated
wastes exceed the applicable exclusion
level.
  (g) In order for hazardous waste gen-
erated by a small quantity generator
to be excluded  from  full regulation
under this section, the generator must:
  (1) Comply with {262.11  of this
chapter,
  (2) If he  stores his  hazardous waste
on-site. store It in compliance with the
requirements of paragraph (f) of this
section: and
  (3) Either treat or dispose of his haz-
ardous waste in an on-site facility, or
ensure delivery to an off-site  storage,
treatment or disposal facility, either of
which is:
  (1) Permitted under Part 270 of this
chapter;
  (il) In interim status under Parts 270
and 265 of this chapter;
  (ill) Authorized  to  manage  hazard-
ous  waste by a State with a hazardous
waste management program approved
under Part 271 of this chapter;
  (Iv) Permitted, licensed or registered
by a State to manage municipal or in-
dustrial solid waste; or
  (v) A facility which:
  (A) Beneficially uses or re-uses, or le-
gitimately  recycles or  reclaims  his
waste; or
  (B) Treats his waste prior to benefi-
cial  use or re-use, or legitimate recy-
cling or reclamation.
  (h) Hazardous waste subject to the
reduced  requirements of  this section
may be  mixed  with non-hazardous
§ 261.6

waste and remain subject to these re-
duced  requirements even though the
resultant mixture exceeds the quanti-
ty limitations Identified in this section.
unless the mixture meets any of the
characteristics  of  hazardous wastes
Identified In Subpart C.
  (1) If a small  quantity generator
mixes  a solid waste with a hazardous
waste  that exceeds  a quantity exclu-
sion level of this section, the mixture
is subject to full regulation.

(45 FR 70823, Nov. 19. 1980. as amended at
48 FR 34687. July 2. 1981: 48 FR 14294. Apr.
1, 1983; 80 FR 886. Jan. 4. 1985: 80 FR 1999.
Jan. 14. 1988: 50 FR 14219. Apr. 11. 19881
  Emcrm D*« Wore: At 50 FR 885. Jan.
4. 1985. aa corrected at 60 FR 14219. Apr. 11.
1986. I 261.6(c) wa* revised, effective July 6.
1986. Al 60 FR 1999. Jan. 14. 1985. | 201.5
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Environmental Protection Agoncy

3010 of RCRA. except as provided in
paragraph (a) of this section.
  (cKl) Owners or operators of facili-
ties that store recyclable materials are
regulated  under all applicable provi-
sions of Subparts A through L of Parts
264 and 265 and Parts 270 and 124 of
this chapter and the  notification re-
quirement   under  Section  3010   of
RCRA,  except as  provided In para-
graph (a) of this section.
  (2) Owners or operators of facilities
that recycle recyclable materials with-
out storing them before they are recy-
cled  are subject to the following re-
quirements,  except as provided  in
paragraph (a) of this section:
  (I)  Notification requirements under
Section 3010 of RCRA:
  (11) Sections 265.71 and 265.72 (deal-
ing with the use of the manifest and
manifest discrepancies) of this chap-
ter.

[50 FR 885. Jan. 4. 1985]
  Emcerrvc DAW None At 60 FR 666. Jan.
4, 1886. I 261.6 waa revised, effective July 6.
1086. For the convenience of the uier. the
superseded text Is set out below:

IM1.C  Special  requirement! for  haxardoui
   waste which li med, re-iued, recycled or re-
   claimed.
  (a) Except u otherwise provided in para-
graph (b) of this section, a hazardous waste
which meets any of the following criteria Is
not subject to regulation  under Parts 262
through 266 or  Parts 270, 271. and 124 of
this Chapter and Is not subject to the notifi-
cation  requirements  of  Section  3010 of
RCRA until such time as the Administrator
promulgates regulations to the contrary:
  (1) It Is being beneficially used or re-used
or legitimately recycled or reclaimed.
  (2)  It Is  being  accumulated, stored or
physically, chemically or  biologically treat-
ed prior to beneficial use or re-use or legiti-
mate recycling or reclamation.
  (3) It is one of the following materials
being used,  reused, recycled or reclaimed In
the specified manner
  (I) Spent pickle liquor which is reused In
wastewater treatment at a facility holding a
National  Pollutant Discharge  Elimination
System (NPDES) permit, or which is being
accumulated,  stored, or physically, chemi-
cally  or  biologically  treated  before  such
reuse.
  (b) Except for those wastes listed in para-
graph  (a)(3)  of this  section,  a hazardous
waste that is a  sludge, or that Is  listed In
I 261.31 or | 261.32, or that contains one or
more hazardous wastes listed In | 261.31 or
I 261.32: and  that Is transported or stored
                              § 261.7

prior to being used, re-used, recycled, or re-
claimed Is subject to the following require-
ments with respect to such transporatlon or
storage:
  (1) Notification requirements under Sec-
tion 3010 RCRA.
  (2) Part 262 of this chapter.
  (3) Part 263 of this chapter.
  (4) Applicable provisions of Subparts A
through L of Part 264 of this chapter;
  (6) Applicable provisions of Subparts A
through L of Part 26S of this chapter
  (6) Parts 270 and 124 of this chapter, with
respect to storage facilities.
[45 FR 33110. May 10,  I960, as amended at
46 FR 44973. Sept. 8, 1981; 48 FR 2532. Jan.
20, 1983; 48 FR 14294, Apr. 1. 1983]

B 261.7 Residues of hazardous  waste  In
    empty containers.
  (a)(l) Any hazardous waste remain-
ing in either (1) an empty container or
(11) an Inner liner removed from an
empty container, as defined  in  para-
graph (b) of this section. Is not subject
to regulation under Parts 261  through
265, or Part  270 or 124 of this chapter
or to the notification requirements of
Section 3010 of RCRA.
  (2) Any hazardous  waste in either (1)
a container that is not empty or (il) an
Inner  liner removed  from a container
that is not empty, as defined In  para-
graph (b) of this section. Is subject to
regulation under  Parts 261  through
265,  and Parts  270  and 124 of this
chapter  and to the notification re-
quirements of Section 3010 of RCRA.
  (b)(l) A container or an inner liner
removed  from  a container that has
held  any  hazardous waste,  except a
waste that is a compressed gas or that
Is Identified  as an  acute  hazardous
waste listed  in {{261.31.  261.32, or
261.33(e) of this chapter is empty if:
  (1)  All  wastes have  been  removed
that  can  be removed using the  prac-
tices  commonly employed to remove
materials from that  type of container,
e.g., pouring, pumping, and aspirating,
and
  (11)  No more  than 2.5 centimeters
(one  inch)  of residue  remain on the
bottom of the container or Inner liner,
or
  (1I1XA) No  more than 3  percent by
weight of the  total capacity of the
container remains In the container or
inner liner If the container is less than
or equal to 110 gallons In size,  or
§261.10

  (B) No more than 0.3 percent  by
weight  of the total capacity  of  the
container remains In the container or
inner liner if the container Is greater
than 110 gallons In size.
  (2) A  container that has held a haz-
ardous waste that is a compressed gas
is empty when the pressure in the con-
tainer approaches atmospheric.
  (3) A  container or an Inner liner re-
moved from  a container that has held
an  acute hazardous waste  listed In
|| 261.31, 261.32, or 261.33(e> is empty
If:
  (I) The container  or Inner liner has
been triple rinsed using a solvent capa-
ble of removing the  commercial chemi-
cal product  or manufacturing  chemi-
cal Intermediate;
  (II) The container or Inner liner has
been cleaned by another method that
has been shown in the scientific litera-
ture, or by tests conducted by the gen-
erator,  to achieve equivalent removal;
or
  (111) In the case of a container, the
Inner liner  that  prevented contact of
the commercial  chemical product or
manufacturing chemical Intermediate
with the container,  has been removed.

(45 FR 78529. Nov. 25. 1080. as  amended at
47 FR 36097, Aug. 18, 1082: 48 FR 14204,
Apr. 1.1083: 50 FR 1099. Jan. 14. 1985]

  EFFTCTTVX DATE NOTE At 50 FR 1999, Jan.
14.  1985, |261.7(b)U>  and (3) Introductory
texts were revised, effective July 15. 1985.
For the  convenience of the user, the super-
seded text Is set out below:

IZ61.7 Residues of haiardoiu waste In  empty
    container*.
  (bKl) A container or an inner liner re-
moved from a container that has held any
hazardous waste, except a waste that Is  a
compressed  gas  or  that  Is Identified  in
I 261.33(0 of this chapter, is empty if:
  (3) A container or an Inner liner removed
 from a container that has held a hazardous
 waste identified In I 261.33(c) of this chap-
 ter Is empty if:
         40 OR Ch. I (7-145 Edition)

Subpart  R—Criteria  for  Identifying
  Hi*  Characteristics  of  Hazardous
  Watt*  and  for  Lifting  Hazardous
  Wast*

1261.10  Criteria for  identifying the char-
    acteristic* of hazardous waste.
  (a) The Administrator shall identify
and define a characteristic of hazard-
ous waste in Subpart C only upon de-
termining that:
  (DA solid waste that exhibits the
characteristic may:
  (1) Cause, or significantly contribute
to,  an Increase in mortality  or  an in-
crease in serious irreversible, or inca-
pacitating reversible. Illness: or
  (11) Pose a substantial present or po-
tential hazard to human health or the
environment when  It  Is  improperly
treated,  stored,  transported,  disposed
of or otherwise managed; and
  (2) The characteristic can be:
  (1) Measured by an available  stand-
ardized test method which Is reason-
ably within the capability of genera-
tors of solid waste or private  sector
laboratories that are available to serve
generators of wild waste; or
  (11) Reasonably detected by genera-
tors  of solid  waste  through  their
knowledge of their waste.

• 261.11  Criteria  for  listing  hazardous
    waste.
  (a) The Administrator  shall list  a
solid waste as a hazardous waste only
upon determining that the solid waste
meets one of the following criteria:
  (1) It exhibits any of the character-
istics of hazardous  waste identified in
Subpart C.
  (2) It has been found  to be fatal to
humans in low doses or, in the absence
of data on human toxicity, it has been
shown in studies to have an oral LD 50
toxicity (rat)  of less than  50 milli-
grams per kilogram, an  inhalation LC
50  toxicity (rat) of less than 2 milli-
grams per liter, or a dermal LD  50 tox-
icity (rabbit)  of less than  200 milli-
grams per kilogram or is otherwise ca-
pable of causing or significantly con-
tributing to an Increase In serious Irre-
versible,  or incapacitating reversible,
illness.  (Waste  listed  In accordance
with these criteria will  be designated
Acute Hazardous Waste.)
                                     361
                                                                                  362

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Environmental Protection Agency

  (3) It contaiiu any of the toxic con-
stituents  listed  in  Appendix  VIII
unless,  after considering any  of the
following factors,  the  Administrator
concludes that the waste is not  capa-
ble of posing a substantial present or
potential hazard to human health or
the  environment  when  improperly
treated, stored,  transported  or dis-
posed of. or otherwise managed:
  (I)  The nature of the toxiclty pre-
sented by the constituent.
  (11) The concentration  of the  constit-
uent in the waste.
  
-------
Environmental Protection Agoncy

or a Class B explosive as defined in 49
CFR 173.88.
  (b) A solid wute that exhibits  the
characteristic of reactivity, but Is  not
listed as a hazardous waste In Subpart
D.  has  the EPA  Hazardous  Waste
Number of D003.

I 261.24  ChBracteriitic of EP toxtclty.
   (a) A solid waste exhibits the charac-
teristic of EP toxiclty U. using the  test
methods described  In  Appendix II or
equivalent  methods approved by  the
Administrator  under  the  procedures
set forth in 1(260.20  and  260.21.  the
extract from a representative sample
of the waste contains  any of the con-
taminants  listed In Table I  at a con-
centration equal to or greater than the
respective  value given  In that Table.
Where the  waste contains less than 0.5
percent  filterable  solids,  the  waste
Itself,  after filtering. Is considered to
be the extract for the purposes of  this
section.
   (b) A solid waste that exhibits  the
characteristic of EP toxlcity,  but is not
listed as a hazardous waste In Subpart
D,  has  the EPA  Hazardous  Waste
Number specified In Table I which  cor-
responds  to the  toxic  contaminant
causing It to be hazardous.

TABLE I—MAXIMUM CONCENTRATION OF CON-
   TAMINANTS  FOR  CHARACTERISTIC OF EP
   Toxtcrrv
                                § 261.30
EPA
hatardou*
•nut*
numbar
PO04 . 	 , 	
O005 	
DOOfi
0007 	
DOOO
DOTJ8 	 '. 	
D010
D011
0012 	 	



0013 	 	

0014 	


001 S 	


Contammam

Bcnun, 	
f^aWtatMMIt
Chromum 	 	 _...
\.mfrt
Marcury 	

SDvar _.
Endnn (1.2,3.4, 10,104i*nach'
1 .4.4a.$.e,7.64*«cuhydn>
1,4 *ndo. aodo-S.»-Om»ttv
•nc-naphthalan*.
Und*n* (1^.3.4. 5,Ww«». chlor-
ocydoh*v*n*. gamm* aiomar.
Matnonychlor (1,1.1-Thchkxo-
Z3-U* (p4n*tho«y-
ptwnyl ] •ttiovw) .
Touphana (C-H^X. Tachnical
cnkxiniiad camphana, 87-6*
Barcant ehkirinal.
Manrwn
ton
(makgnm*
5.0
100.0
1.0
S.O
6.0
0.2
1.0
S.O
0.02



0.4

10.0


0.6

TABLE I—MAXIMUM CONCENTRATION OF CON-
  TAMINANTS FOR CHARACTERISTIC  OF  EP
  TOXICITY—Continued
EPA
hanrdou*
number
0016 	

DOI7


Conunwwrt

2.4-D. (2.4.Dcnlarophanoiyaca-
KICK)).
2 4.5-TP SitMl (2 4 S-Tncnto-
fOphanoKypropionic Kid).
Maiknum
lion
(iMhgnimi
par Mar)
10.0

1 0

    Subpart D—LUli of Hazardous
                 Wattot

G 261 JO  General.
  (a)  A  solid  waste  is  a  hazardous
waste If  it Is  listed  In this  subpart.
unless it has been excluded from this
list under }| 260.20 and 260.22.
  (b)  The Administrator will Indicate
his basis for listing the classes or types
of wastes listed in this Subpart by em-
ploying one or more of the following
Hazard Codes:
IgnnablaWaM*..
CorroaM* Wist*	
R««ctr«« WUM_
EPtcndc Wn»*_
Acutt Huantoui Wttta..
TodC Wa*ta..
(E)
IH)
m
                                             Appendix VII Identifies the  constitu-
                                             ent which caused the Administrator to
                                             list the waste as an EP Toxic Waste
                                             (E) or Toxic Waste (T) in  f{ 261.31
                                             and 261.32.
                                               (c)  Each  hazardous  waste  listed  in
                                             this subpart Is  assigned an EPA Haz-
                                             ardous Waste Number  which precedes
                                             the name of  the waste. This number
                                             must be  used in complying  with the
                                             notification  requirements  of Section
                                             3010  of  the Act and  certain  record-
                                             keeping  and  reporting  requirements
                                             under Parts 262 through 265  and Part
                                             270 of this chapter.
                                               (d)  The following hazardous wastes
                                             listed in i 261.31 or { 261.32 are subject
                                             to the exclusion limits for acutely haz-
                                             ardous wastes  established  in  {261.5:
                                             EPA  Hazardous Wastes Nos. FO20.
                                             FO21. PO22, PO23. PO26. and FO27.
           §2*1.31

           [45 FK 33110. May 19. 1980. u amended »t
           48 FR 14894. Apr. 1.  19§3; 60 PR 2000. Jan.
           14, 198S1
             EmcTtvc DATE NOTE At M FR 2000. Jan.
           14. 198S. I 261.30(d)  wu revised,  effective
           July  16, 1988. For the convenience  of the
           u§er. the iupewded text Is §et out below:
                                                                                                                                                    410 CHI Ch. I (7-1-M WHi.n)
                                                                                              IMIJt
                                                                                                (d) The following hatardous wwtes listed
                                                                                              In I 261.31 or 1361.32 are lubject to the ex-
                                                                                              clusion HmlU for acutely haurdoiu  wutes
                                                                                              established In I 261.8: (Reserved)
                                                  B 261.31  Huardoui waitei from non-ipeelfle (ouree*.
                                                    The  following  solid wastes  are listed  hazardous  wastes from  non-specific
                                                  sources unless they are excluded under II 260.20 and 260.22 and listed In Appen-
                                                  dix IX.
           Induny and EPA hasardou*
                 •MM No.
           Ganarie:
            F001...
            F002...



            F003_.


            F004...

            FOOS...


            Fooe..
                                                    F018..
                                                    F007._
                                                    FOM_

                                                    FON_

                                                    F010._

                                                    F011-.

                                                    F012_

                                                    F024._
                                                    FO20	
                                                    FO21..
                                          ; and •>• tM boaom*
Th* toaoamg apart haloganaiad autnanai u*ad In
 trioMoroathytana, nwhylan* Ontario*. 1.1.1-McNoroaliana. carbon MncHond*.
 and chKxmalad nuorocarbona, and akidaa* Irom t» racowvy ol n*M KUnnt* in
 dagraaang opanbon*.
Th* tottMtog apart hdoganatad njHamt l*t»eMoroa«i»l«na, mathytan* cNnrid*.
 >lLl. »an*«aMr, Haatamlar u»auiKm Hudg**, apant cualytt
                                 •ran** kltad in | 2C1.3Z).
                                WattM  (awapl msWMIar and •pant carbon  Irom hydraptn cMorlda pachtoroph*n* (rom highly purlnad 2.4.5-
                                 BichlQrophanol.1.
                                Wuta*  lanapt »a«n»*»i and apart carbon  Dam hydrogon chtono* puWcatlon)
                                 from VM production or manuaKturing u*a (a* I raaclant chamical Marmadial*. or
                                 component  In • lormuH»ng proeaai) ol DamaoMorophanol. or ol Mamtadialai
                                 u**d to product to dartnuba*.
                                                                                                                                       366
                                                                                          m
                                                           (D

                                                           II. TJ
                                                           m
                                                           (H.T»
                                                           (R.T)

                                                           (B.H
                                                           
-------
 environment*! Protection Agoncy
                                                                                        §261.32
                                                                                                            9201.32
                                                                                                                                                                          40 CHI Ok. I (7-145 ftUtloti)
 nduaty and EP*.
           i No
  FO2t	
  TOM-
   TOM.
  F027..
  FO2S..
                          tromVM iMnutaculnp, uee (a* a reectanl Chun
                          • tormuteeng piucnei>  ol Mr*-, penta-, or IM
                                                                           hlorti>» putticaepn)
                                                                           *, Of oomponant in
                        Wuw (now* imrtiiatef md «Mrt carbon Irom hydrogen entente purthcakon)
                          Irom *M production ol nMHrnH on •qupmwil pmvtomr/ uMd to to production
                          or mmuuicluring UM (M • nueunt chemical Marmaduita. or componanl In •
                          tormuMng prooaaa) of ki- and tatracMorophanoli. fThn kakng doaf not mduda
                          wtMm Irom aoupmanl uaad only tor the producbon or uee of Haucnloropnana
                          kom r«gnry purthad 2,4.6-kioMorophanol.).
                        INaMai (aioapl waalawatar and apant carbon kom hydrogen chtonda purMicakon)
                          kom aia producton of inamali on eo^pmani prevnuHy uaed lor »a manulactur-
                          ing uaa (a* a raadant. chamcal ntarmeoiaia.  or componenl in • lonnulatng
                          nronn) of Mm-, penu-, or hauchlorobaniana under akabne oondram.
                        tacafoed unuaed tormulaboni comairang t>. Ian-, or pantaoMorophanol or de-
                          canted unuaed (onnulatona oontanng compoundi den»ad kom meae chlorophan-
                          oH (Trw eMng doei not tnduda ttxmuujbora containing Haiachlorophena lytha-
                          aHed kom prapurHied 2.4.S-ktchk>rDphano! a> tna aola componanl).
                        fleaduaa reaumng rrom me Ironeiaton or thermal keatment of aoH oonumnaujd
                          ««n EPA Hasardoua w«ua No*. FO20, FO21. FO22. FO23, FO». and FO27.
                                                                                            Haiard
                                                                                           (M)
                                                                                           (H)
                                                                                           (H)
                                                                                           (H)
                                                                                           (T)
 (4« FR 4617. Jan. 16. 1B81. u amended at 46 PR 27477. May 30. 1981; 49 FR 5312. Feb. 10.
 1984; 49 FR 37070. Sept. 21. 1984: BO FR 666. Jan. 4. 1985; 50 FR 2000. Jan. 14. 1985]
   Erracnvc DAT* NOTE At 50 FR 665. Jan. 4. 1985, the hazardous waste listings for F007
 P008. P009. F010. P011. and P012 were revised, effective July 5. 1985. At 50 FR 2000. Jan. 14
 1985. the hazardous waste listings for F020. F021. P022. F023. FQ26. F027.  and  F028 were
 added, effective July 15, 1986. For the convenience of the user, the superseded  text is set
 out below:

 0 261.31   Hazardous wastes from non-specific sources.
Induety and EPA hazardous
       waataNo
                                                  Haiardout Mate
Hazard
 coda
  FOO?	Spent  cyanide  plating bath  aokitom  kom el»iuuuls»ig  operation*  (except  tor (R. T>
                          preotou* metal* aleeiiuulaiing (pent cyanide plating bath eolubon*).
                        Plaeng bath Nudges kom th* bonom ol plating bath* from eUr.nupl.um operation* (R, T)
                          where cyanide* are ueed In the procee* (except tor precious metal* aoctiuununtf
                          Plaeng ban aludgae).
  FOOS	Spent  »ii»x«ng and cmmng bath solutions kom eiectiuuHliiig operations where (A. T)
                          cyarade* are ueed In the procee* (except for precious metal* electroplating *P*nt
                          *UMJ«IU and deanng bath sotutioos)
  FOIO		 Ouencnmg bath  tludge from o* battw from metal  heat keeong operation* where (R. T)
                          cyanide*  are  uaed  n  tha  prcceea (except tor precnu*  metal* heat-treaMig
                          ojuancnng bath aludgea)
  F011	 Spent  cyarad*  aokjton*  from sen bath pot  cleaning  kom metal heal keatmg
                          operabun* (except lor preoou* metal* heat keatmg spent cyanide eokikon* from
                          «alt bath pot cleaning)
  F012	Quenching wealewater treetment aludgea from metal heal treating operations where (T)
                          cyanide*  are  uaed ki  th* process  (except  tor  preooua metal* heat keatmg
                          quenctwig waatewaler teaknent  dudge*)
0 261.32   Hazardous wastes from specific sources.
  The following solid  wastes are  listed  hazardous wastes from specific sources
unless they are excluded under {( 260.20  and 260.22 and listed in  Appendix IX.
Induatry and EPA hazardous
       watt* No.
Wood pra*arvaiion: K001	
                                                  Hazardous wait*
                        Bottom aeoVnent sludge kom the treatment ol waitewalen from wood preserving
                         prooe**e* that ua* creoaote and/or pentachloroprienol.

                                               367
Hazard
 code
                                                                                           ro
Induety end EPA nezarOoua
WaWaaV Nfi



KON 	
KOM... -
KOOS 	 	
Organic Chen ems*.
K010
K011 ,,.,„... :: „„ 	
K013
KOM
KOI 6

K017

K01B
KOI a
KQ20 	 	 , I.....,,,...,,...,,,.
Koa 	
KO94
fctnoa
xntu
KOX
KQZ7 	 , ,
iron
toot
KMS ..._
KOM 	
Knao
KM3
K109

KDM
Kins

icriTi ,,. 	
icon
K10B
K031 	
K032 	 	 	 	
K033 	
K034
K0g7 	
K035
KOM 	
K037 	 	 	
KOM 	 _
K040 .._ 	 „ 	
K041 ..
KOM 	 	

Hazardous waeu


eajmanta.
Waaneaur treatment abdne Irom tie produeeon el xlnc yi«»» pigment* 	 	
Waatawaiar iraatmant tfudpa from Via producton of chroma O.** groan plgmanti
(tvinydroua «* tiydratad).
WMtawatar boatman! •ludaa from Vw fntduoton oflronb.ua ptgman.*
Ovan raaMua from Via producton of chroma o*da groan aajmami.. 	
DMMaHon aMa outi from tha producton of •oataJdahyda from atnytana
Bottom *.ra.vn from lha »a.na.va*ar abtpnar m Via producton of aorytonartla.
fiotnvn atmaun Inpn *>• .M^terttriU eok|fiHi kn MM pnMfud.fn of may****** „ , .
Bottom* from VM acalonHytfca purMcaton column in Via producton of auy.tii.lbia
Btfl bottom* from tha Tftffton of banxyl chtorfda





producton.
Haavy andt from Via aiBMMon of vinyl chtortda in vfnyt cMoftda rfoonai
producton.
Aquaoua ipaot anilmonv calatVH waat* from ftonmaViana.. emdueilnn
D.*tHtatlon bottom tan from Via producton of phanol/aMtona from oumana



Diatttaton bottom* from tha producton of nUiobamaiia by Via ntttton of banMna
S^pf.i*ig rw tart* from Vit producton of mathy athyt pyrtrf.naa
Cantrtruoja and dwittatoon rvtMuaa from tohiana olaoryvnala p^nrvrttm

oattiana.

Haavy anoa from tha haavy andi ookimn from Via producton of 1,1,1«chtoroa«v
ana.
and parcriiorcpairiytana.




of chiorobantanat.
Brin*. .HV • iH. (.-
aaparatary prapurMad brina it not uaad.
proca« uaing grvphrt* anodat In cNorina producton.
Byproduct aalt* generated In tie production of MSMA and cacooVfe add
Wanawater treatment aludoe from th. production of chtordana 	 	
WaMawatar and ecrub water Irom the chtomaeon of cyOopentadMn* hi ma
production of chtordana.
™er "olid* from Uu nn.tlki.i ol heiecntaucyclupenuuleii* kt tie producton of
cnioroana.
V^ilordan.W" '*"*"*' hl>nl ™ enlon»n» enwtntlor ki IM producton of
Watlewater keatment »ludge* generated ki the producton ol creoaou
S« bonom* from toluene redamation OKWujbon ki the producton of diauiiolon_
Waateweter gaatmenl ^udoea kom the production ol dtouNolon
waaiawater from me waahng and (tripping of phonMo production 	 . _
rVIW CaWa (IWTI DM flrUalKM) Of dMthytCatipani^*vortflr|ifja»; mr^t tgt H^ mnA— IL-. «»J
phorata. '••— t- —• ~" « •• proounon 01

".«-.--...-, ^aaim.Kii jMuoga rioin tha pfoductw. of lomaptiaiia 	 	

Hazard
coda

(T)

(D
ID
(T)
(T)
(T)
(H, T)
(R,T)
(T)






m
rn
ro

(T)
O)
(T)



fO
CD



ro

ro

ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
ro
                                                                                                                                                          368

-------
Environmental Protection Agency
                              6261.33
todunry and EPA huwtiou
MSMlll Ite


KOM -. 	
EnHoaNaa:

K046

Patroiaurn fanrvngi

K050 	 — 	 ~_.™~—

fron and staat
K061 	 _ 	 	
K062 — -.— —
Secondary toad
KOM
K100
VataftftaiY pTOTtaoautca.*:
K1Q1 	

KIM 	

Ink tofmutaaon: KOM
Coking:
KWW
"ft*7

Hazardous waata

production of 2,4.5-T.
2 A-DchlarQptwfKri wat** from ttw producton of 2.44)
UntMtad wastawatar from ths producaon of 2.4-0 	 . 	 . 	 	


Waatawatw traatmant akjdgaa from tha manufacturing, tormulaaon and toadmg of
laad-toaaad «Mtmg compounds.
pjoaorrtd air Aotabon (OAF) float from f» pitrolaum rafnng industry 	 	
Stop o»J amulsion tottta from lh» patroiaum rahning industry 	 „.„„....„_„ 	 ,
Haat axchangar bundt* daanng atudga from tha palrotaum raftfwig Industry 	 	
API Mpantof atudoa from lha patroiaum rafwwig induatry 	 _ 	 „ 	
Tank bottom* (taadad) from lha patroiaum raArang •ndustry „„ 	 	 	
EfiMaton control duat/akudga from tha primary production of sta* in alicaic
lumaoaa.
Spant ptoUa •guor from ataai fmNnQ oparattona 	 	 . 	 _ 	
Emataton control duat/akidga from aaoondary taad amarang... 	
Waata •aach.ng aotoaon from aod (aactang of amaann oonlrol duat/aludga from
aaoondary toad antarang.
oaufecat* from arwrac or organo-araanc compounds,
DistMabon la/ raaiduaa from Vts drsOUtoon of anthna-baaad compounds in ttta

pounds
Raariut frtrn fftt utt of acfevatad cartwn to* daootonzaVon in tot produeaon of

Soivant waahas and aludgaa. caua&c waahaa and aludoas, or waiar waahaa and
aiudgaa from tiaaning uba and aqupmani usad In ma formulation of r* from

0*r>n1Mr Iv4f tar t^nlQt twn w¥ "'^ opvnlmnt

Huart
ood*

(1)
0)
(A)
(R)
(T)
("1
(T)
rn
0)
(T)
(T)
m
(C. T)
rn
(T)

fn

(T)

m
(T)
(T)

[46 FR 4618. Jan. 16. 1B81. u amended at 46 FR 27476-27477. May 20. 1B81; 49 PR 37070.
Sept. 21. 19843
6 261.33  Discarded  commercial  chemical
    producti, off-ipeclfleation ipeciet, con-
    tainer  residue*,  and  iplll  reilduei
    thereof.
  The following materials or Items are
hazardous wastes when they  are dis-
carded or Intended to be  discarded as
described  In { 261.2(a)(2)(i), when they
are burned for purposes of energy re-
covery In  lieu of their original Intend-
ed use, when they are used to produce
fuels In lieu of their original Intended
use, when they are applied to  the land
In lieu of their original intended use,
or when they  are contained  In prod-
ucts  that are applied  to  the land In
lieu of their original Intended use.
  (a) Any commercial  chemical prod-
uct, or manufacturing  chemical inter-
mediate   having  the  generic  name
listed in  paragraph  (e) or (f) of this
section.
  (b) Any off-specification commercial
chemical  product or manufacturing
chemical  intermediate which. If It met
specifications, would  have the generic
name listed  In paragraph (e) or (f) of
this section.
  (c) Any container  or Inner liner re-
moved from  a container that has been
used to hold any commercial chemical
product or manufacturing chemical in-
termediate having the generic names
listed In paragraph (e) of this section.
or  any container or inner liner re-
moved from  a container that has been
used to  hold  any   off-specification
chemical  product  and manufacturing
chemical  Intermediate which, If It met
specifications, would  have the generic
name listed  In paragraph (e) of this
$261.33

section, unless the container Is empty
as defined in | 261.7(b)(3) of this chap-
ter.
(Comment- Unleu the residue Is being bene-
ficially used or reused, or legitimately recy-
cled  or reclaimed:  or  being accumulated,
stored, transported or treated prior to such
use. re-use, recycling or reclamation, EPA
considers the residue to be Intended for dis-
card, and thus a hazardous waste. An exam-
ple of a legitimate re-use of the residue
would be where the residue remains In the
container and the container Is used to hold
the same commerlcal chemical product or
manufacturing chemical product or manu-
facturing chemical Intermediate It previous-
ly held. An example of the discard of the
residue would be where the drum Is sent to
a drum recondlttoner who reconditions the
drum but discards the residue.]

  (d) Any residue or contaminated soil,
water or  other debris resulting from
the cleanup of a  spill  Into or  on any
land  or  water  of  any  commercial
chemical   product or  manufacturing
chemical  Intermediate  having  the ge-
neric name listed In paragraph (e) or
(f) of this section,  or  any residue or
contaminated  soil,  water  or other
debris resulting from the cleanup of  a
spill, into  or on any land or  water, of
any  off-specification chemical product
and  manufacturing chemical Interme-
diate which,  If It met specifications,
would have the generic name listed In
paragraph (e) or (f) of this section.

[Comment- The phrase "commercial chemi-
cal product or manufacturing chemical In-
termediate having the  generic name listed
In ..."  refers to a  chemical substance
which  Is manufactured or formulated for
commercial or  manufacturing  use which
consists of the commercially pure  grade of
the chemical, any technical grades of the
chemical that  are produced or  marketed,
and all formulations In which the chemical
Is  the  sole active ingredient.  It does not
refer to a material, such as a manufacturing
process waste, that contains any of  the sub-
stances  listed  In paragraphs (e)  or  (f).
Where a manufacturing  process  waste  Is
deemed to  be a hazardous waste because  It
contains a substance listed In paragraphs (e)
or (f).  such waste will be listed In either
II 261.31 or 261.32 or will  be Identified as  a
hazardous  waste by the characteristics set
forth In Subpart C of this part.)

  (e)  The  commercial  chemical prod-
ucts, manufacturing chemical interme-
diates or  off-specification commercial
chemical  products or  manufacturing
         40 CM Ch. I (7-145 Edition)

chemical Intermediate* referred to In
paragraphs (a) through (d) of this sec-
tion, are Identified a* acute hazardous
wastes  (H) and are  subject to  be the
small  quantity  exclusion  defined in
I 261.6(e).
(Comment- For the convenience of the regu-
lated  community  the   primary  hazardous
properties of these materials have been Indi-
cated by the letters T (Toxlclty). and R (Re-
activity). Absence of a letter Indicates that
the compound only Is listed for acute toxlcl-
ty.)
  These wastes and  their correspond-
ing EPA Hazardous Waste Numbers
are:
                                                                                                                                  I No.
                                                                                                                             P023	
                                                                                                                             foot	
                                                                                                                             POST	
                                                                                                                             POSS	
                                                                                                                             coot.
                                                                                                               •*»»•
                                                                                                     2-feofO-
                                                                                              Aodte MM. SUXO-. ndun Hit
                                                                                                         acid.     N-{(nM4-2-4Nour»«
                                                                                                                                       Aldhn
                                                                                                                                       Alyliloohal
                                                                                              Ammonun pKnu (R)
                                                                                              Animonium vanadMa
          Anmc (HI) <**••
          Ancric (V) end*
          Aiwnfc

          avwn cysnM*


                  , 4-flMfD*
                        4-I1-hydn>iy-2-
-------
Environmental Protection Agency
                         § 261.33       § 2*1.33
                                                                                                                                                                40 CHt Ch. I (7-1-«5 SdhHon)
HUWOOM
MM* NO
POX 	 _...
P031 	 	
POM 	
PO36 	
P037 	
POM
PO39

P040 	
PM3..._ 	 _
P044 	
PO4S 	
P071 	
POBZ... 	 —
PO47 	 	 _
P034. 	 	 _..
P048 	
P020 	 „ 	
PO85 	 	
PQ39 	
P04B 	 	
P1M 	
POM 	
POU 	
POS1 	 _
PO12
PO46

P10I 	
POM 	
POB7 	
pose 	 	
P057 	
pose 	
PO65 	
pose 	
POS1 	
PO37 	
P060...._ 	
POM 	
poeo_ 	 _. 	
POM 	
P1 16 	
POM 	
P083 	
P096 	
P064
P007 	
PO92 	
P085 	
P016 	
P112 	
P1 18 ....
post 	
POS6
P087 	
SutMUno*
CyiradM IK*** cyvnd* uta). not i
wMn«MC«Md
Cywngm

Ik^dm
CMhylaran*
O.O-Owttiyl S-t2-(«OV»X)»«h»() ptmpd
d«M»U

OMOpropyl fkioaxitvMpW*
OmthocU
3.3-Dim«hy*-Hm«fiynNo(-2-«>uUnon«.
O.O-Orrwthyl CVfMvtraplMnyt pho^h
IhKMlt

t.^Omm-ocnttf md MM
2.4-Orttrophral
DmoMb
DwMMon
2.44MNotmm
EndcMUlin
EfldOttMl
Endm
EprapMni

Elhy.«xo-




^ydfUra, fiMVi)4.
HyOrocyinic Kid

*••
oro-
O-
om-
•n-
Itocyinc Kid. nwffiyl nur
3(2H|-liouiolan<. S-4imnoiTMV)y<>-
Mwcixy. I«c«««o-O)p4wi»1-
Mcrcwy lulnwMI* (R,T)
Mrturx. or»tt»-3«.4.7.7*-Mlratiydn>-
M*0xxnyl
2-McffMuiridifW
Methyl ryoraw
UMnyl aHcyenala
2-MWiytoctor.We
•Ipht-Naphttiymiioura*
NBkal caitonrl
Nickel cyanide
Nickel|ll) cyanide
Nickel utrK*ft>ony<
Nicotine and aata
                                                            Nnropen dxmde
Nltrooenomafia.2J-d«nalhanol. 1,«.5.6.7.7-he«-
  achtoro. cyckceulMa
Ooameftytpyiutjiiuephoramida
Oamun onda
Oamum latroad*
7-Oub«rcto[2^.1 )lMpUna-2.:
Phenol, 2-cydonaxyM.6-drt*o-
Phenol, 2.44kratiD-
Phenol. 2,4-dmliie-a^ietfiyt-
                                                            Pnenol. 2.4.8-*n»o-. ammonun un (R)
                                                            Phenyl dicnloioereni
                                                            N-PnwiyntwwM
                                                            Pnorau
                                                            Phoepnoric acid, dMtiyf p-rt»optieny( euer
                                                            PnoaphoreoWiioc acid. O.O-dmemyl S-C2-
                                                              (m«iyl«mno|-2-OK>ettiyl)eB«
                                                            Pnoepnorolluoric  aod.   tw(1-melhyta«ixl)-
Phoepftorottwic    acid,   O.O-dMhyl   S-
  (eViy»M»metriyl eater
Phoaphorotticci  acid. O.Cntvn^ CMp-rt«o-
                                                            Phoephorolhloic abd. O.Oxtethyl O- pyraHnyl

                                                            Phoaphoraffiioe aod. O.O-dvnelhyl O-1HI*-
                                                            Plumturx.
                                                            PoUMwm cyvwto
                                                            PaUMum «*v»t cyinidt
                                                            PraMral.    2-m«ttiyt-2-)ci>t>ony<)aiin*
                                                            Prap«n«n«rii*
                                                                          mnnrale- (R)
                                                            2'Propanona, Hnoflio-
                                                            Propargyl alcohol
                                                            2-Prapenal
                                                            2-Propan-l4l
                                                            1.2-Propylenimne
                                                            2-Piopyiv1 0.1% or taM
                                                                                                     2-AMiyivnnolluaran*
                                                                                                     AcMyt cMaridi (C.R.T)
                                                                                                                                                                             •(2-eWo
                                                                                                                                                                        •• L-
                                                                                                                                                                      «no > CH«mnuc«r>»ooy1)   oiy)m*B)yl]-
                                                                                                                                                                 BentlclKridne
                                                                                                                                                                 3.4-aenacrtdne
                                                                                                                                                                 Benzal cNartde
                                                                                                                                                                 U-Bcnonvnocn*
                                                                                                                                                                 1 j-BmnMrrann*. 7.12-dlm«>iyt-
                                                                                                                                                                            N.N -JtrmlX)! -«-ph»n
                                                                                                                                                                        O.T)
                                                                                                                                                                 1.8 0«iu»n«dic»itim»lc Kid inhydnd.
                                                                                                                                                                                     Kid.  (lM(2-«ttiyl-

                                                                                                                                                                 1^-a«iu«n»diMrbo«ytle add. dtanyl MUr
                                                                                                                                                                 1^-8*rmn*dKaitoiiylie Kid. dMKyt nMr
B«i»iw. 1.4-dkrtoro-
BMOOT*. (dkM
BvnMiw. 1.3-dMocywiiKXMIhyl- (R.T)
                                                                                                                                                                            ^ cfDortd* (C.R)
                                                                                                                                                                 0«n»»o«, 1.2.4,5-tofrMtto'O-
                                                                                                                                                                 B*nno*. (MenianKMttiy1)-
-------
Environmental Protection Agoncy
                                                                                 § 261.33
                                                                                                                  §261.33
                                                                                                                                                                      40 CFR Ch. I  (7-1-M EdHion)
 WuwNo.
 0234...
 0021...
 0202..
 O120..
 O022.
 0022
 O187..

 0050 .
 O065 .
 O021..
 1X173..
 0081..
 0085..
 O024..
 0027..
 0244..
 0028..
 0246..
 022S..
 O030-
 O128...
 0172-.
 0035-

 OO31...
 0158 _
 0063.
 0074 _
 O031.
 0136..

 O238-

 017*..
 0177..
 O218-
 U087..
 021S-
 0156 _
 0033.
 O211-.
 O033-
 O034..
 O03S-.
 O036...
 O026..
 O037...
 O038...
 O041...
 O042...
 O044...
 0046...
 0047-.
 O048...
 OO48...
 O032...
 O050...
 OOS1...
 OOS2...
 0052...
 0053...
 0055...
O246...
0187...
O056...
O057...
0130...
UOM.
O240...
O058...
                           Sutwunc*
                                           Himdom
                                           WuWNo
             B««nn*. IJ,Wrin*o- (R,T)

                                  . I.t
 3.4-Bantopyrana
 p-8ansoqunona
 BvuotncMondt (C.R.T)
 1.2-BauphanarHrnna
                      i. 3.3 -d«**orO-
                      i. S.S'-dmatttoxy-
                        3.3-o«iw(fly(.
 Btt(2-Ca>ilorM|thovy) nwttiww
 BaX2-ehloro»opro0yl) tHm
 Biacarbainoyl)d»ullida
             Bronx* cyanida
             4-Bromophanyl pltanyl <
             1.3-Bula<*«na. 1
             1-Buunamna. N-outyt-N-rtwao-
               bcnmw-
             t-auunol(q
             2-BuMnoni (I.T)
             2-Buunant
             2-Butaiwl
          add.  4-CBia(2-cNoioMiyqa>rino]
             n-6utyi afchcnol (t)
             Cacodyic add
                  IH.T)

                    O.T)
Cvbamic add. a«iyl aatar
             nwtti)4nim&-. Mnyf 4
        i. N attiyl N r
          N-niatfiyl NH*'
wtrtMtioyf craorkto, i
Cotonic lad. iMnJUnQ) uH
Cxtioiiochtondtc «cM. rnMiyt«
Cwton aiyfluond* (H.T)
Caiton minjiiuitu*
drDanyl «uortd» (B.T)
CNoral
                                         r(lT)
            4-Chkxo-nxrMol
                        >po«>i
                        viny1i0Mr

            CNoromMriyl rnMhyl •«•
            o-ChloraprMnol
            QvyMO*
            CrcoaoU
            Cnwll
            Cyinogwi bound*
            1.4-Cycfc»M>adi«n«tio
CycJohuwM (I)
Cydorwunon* (I)
1.3-Cydopwrodry1) dnopfOpytltnoc«(t)«m«l»
                                                                   O-OcMorobcn *n«
                                                                   m-DictilorotwnnrM
                                                                   p-DJCtilorobwmn*
                                                                   3 J -OcMoiotKi
                                                                   DcrHorodifluoromtthtnt
                                                                   DcNoro rtprnnyl tfBNoroMhww
                                                                   DicNoro d^rwnyl tncrHoroMWM
                                                      1.2-Oichtoro«ltiyH»«
                                                      UMM^'OAttiyl VtfMf
                                                      2.4-Oietiloroprnnul
                                                      2(V-OcMuruptwnol
                                                      2.4-Oicrik>ropr»»nu.y»
                                                                   1 i3.4-O*OCTmlt)inlhnom
                                                      •Ipntjlplu-OniMhytwnzylriydropOTOiiid* (R)
                                                      Dnwthytoftwnoyl cNomto
                                                      1.1-Onwihylnydruin*
                                                      1 ^-OntMhylriydnzirw
                                                      2.4-Dmwlhylprwnol
                                                      Dmttiyl phth4KU
                                                      OnMlhyl iurliu
                                                      2.4-OntrotokMn«
                                                      2.6-OnilrotoltMn*
                                                      Dnvoctyl ptithaKU
                                                      1.4-OioniM
                                                      Opropyumni (I)
                                                      [VN-propylflilnwamin*
                                                      Ettwfwl (I)
                                                      Emwurnn*.
                                                      Etron*. 1,2--
                                                      1^-EmarwdiyttncaitwmodnhMc «od
                                                      EitutM. l.1,l.2.2.2-h.x«c«oTO-
                                                      Elrun*.  1.1'-[nwltiyl«n«bn(oiy)lbltl2-ctikin>-
                                                      Ettnn.nrtrt« (I. T)
                                                      Etlunt.l.V^nylm- (I)
                                                      EttwM. 1.1 -OJtytmU-otHoro-
                                                      Elhvw, p*nl»ctuoro-
0208.,
0208.,
0216.,
0247...

O227.,
O043.,
O042...
O076.,
O078.,
O210...
0173.,
UOM...
uoo*.
U112,
0113.,
0236.,
0038,.
0114...
O087,.
0077.,
0116.,
0116...
O117...
O076.,
0116,
0118,
0138,
0120..
0122,
0123,
0124,
0125.
0147..
0213,
0125..
0124-
0206..

012«.
0183.
0127-
0128.
0128.
0130-
U131,
O132.
0243.
0133-
0086.
0088.
0088.
0108,
0134..
0134.
0135.
OO86.
O138.
0116.
O137.
0138.
O140.
0141.
0142.
0143.
0144.
0146.
0146.
0128.
O147.
0148.
O148..
                                                                                                                                            Subwnc*
                                                                                                                       . 1,1.1.2-latractHoro-
                                                                                                                 Emana. 1,1.2.2-tatiactiloro-
                                                                                                                 Elhanamoainda
                                                                                                                 Ethana.     l.1.1.-*icrrloro-2.2-tM(P-ma1rK»y
ErXana. 1.1.2-rnchioro-
Elhana. crUoro-
Elhana. 2-eMoroa«Kny-
Elrwna. 1.1-dKMoiD-
Ethana, lrana-1 J-dcMoro-
Ethana. 1.1.2.2-MtaeNoro-
Etrnnoi. 2.2'HrmreauiiiniuHiia-
Enanona. 1-prianyl-
Elhanoyt cMonda (C.H.T)
EBiyl aoaiata (I)
EBV acrylala (I)
Eltiyl cafbamau (urathan)
                                                                                                                  Ethytonabtaldrihiocaroanc aod)
                                                                                                                  Etytana dibromida
                                                                                                                  Ettiytana dctilonda
                                                                                                                  EMana onto (I.T)
                                                                                                                  Elhytana VMuraa
                                                                                                                  Ethylaiharll)
                                                                                                                  Etriytidana deNortda
                                                                                                                  EdyUnathacrylala
                                                                                                                                                 (0
0160,
0151,
0162,
U092
O028.
O045..
O046,
0068..
0080..
O075-

0119..

0121..

0226-
O044,
0121..
0123..
O036..
                                                                                                                                                          O164...-
                                                                                                                               Fwric dmrwi
                                                                                                                               FluorantriKM
                                                                                                                  Forme aod (C,T)
                                                                                                                  Finn (I)
                                                                                                                  2-furanciftould*hydt
                                                                                                                  2.5^irand»xw
                                                                                                                  Fur«n. Mrahydro- (I)
                                                                                                                  Furhnl (I)
                                                                                                                  Furturan(l)
                                                                                                                  D-GtucopyranOM, 2-o»oiy-2(3-m«tn>t-3-r»-
                                                                                                                    •ouraUo)-
                                                                                                                              Guin«Jn«. N-nltro«o-N^n«l»ni6»(2-cMoio«n*i«)
                                                      M«nyl^» c«orid«

                                                                                                                                                                                                    (I.T)
                                                                                                                                                                                                           .(H.T)
                                                                                                                                                                       KftMfayiigabiityl hMoiv (I)
                                                                                                                                                                       Mdhyl rmlwcryM* (I.T)
                                                                                                                                                                       U Milhyl If 1*11 N iiilnanuiaiHrtm
                                                                                                                                                                                          uli»u»i«i»
                                                                                                                                                                                    2-tMpt10-N4
                                                 373
                                                                                                                                                      374

-------
Environmental Pr*tacti*n Agency
                                                                               9261.31
 WMMNo.
U17l_
U1W.
U1S1-
uiss.
uocs.
U041	
U1S2	
U1S3	
U1S4	
HIM
SeeF027.
U1SS	
 U1M.
U101	
O1TO	
SeeROT.
   Do	
U1S7.
U14S.
UOS7_

U1M_
U180-
U1I1-
U1*2-
U1B4_
U110-
uoee.
U14t_
U171.
U027.
U193.
U002-
UOOT.
UOS4.
U243..
UOOB.
U1S2-
U113	
U11S	
0162	
See ROT.
U1»4	
UOB3	
•U1M	
U1S5	

U17S	
U191	
U1S4	
U1M-
U200-
U201-
U202.
U203-
U204_
U204.
                 pbendn
                                              U018_

                   «Mn

             e«i>llam>iollaliah>*o-,
           OdranelLT)
           PaniacnlanMhani
                   rtlrobi
           Pemaonlotaphenol
                                              U213 —
           Phenol 2«-iiia
           Phenol 2.4-dichlon>
           Phenol 44*R>.
                                              U220-
           Pnenol 2.4.W1enlon>
           1,10-(1J-i)henylene)oyrana
           Phoephonc add. LMd aaR
           PhoapnoraoWWe add,  0,0-**h»t., s-me4ny
           Phoepnt
                          (")
                                              U22«
           2-Ptooin*
                                              U22S«
           1^-iepanamlne (IT)
           1-PfOoanamlna, N iBUpfl (I)
                 IJ-Otromo-O-dHon
           Propane. 2-n*t>- (Q
           Prepane. 2J-o«y««2-ertoro-
           1>Propane autene
           1-Pnpanol 2.3-dtjnmo-. ehoaphala (3:1)
           t-fTopaool. 2>rapena. 1.1J
           2-PnpenenlMe
           2-PrapmnlMa. Z-metiji- (IT)
           2'f^opMnoBC acid (I)
           2^roptnoBC acsd, atttyt aalaf (1)
                                               U24B
           2-PrapenoJc add. 2^ne1hyl-. nMhyl eater fl.T)
           Propionlc add. 2-(2.4.6-»ichloropheno>f>-
           n*ropylen*» O.T)
           Propvtene acntoide
                                                         4.4-4Mbene«ol alpha^lphi'^ieSiyt.
                                                        SuNunc add, dtme»V eater
                                                        fitrffur phoephkle (A)
                                                        SuHw wMraoe (R,T)
                                                        2.4.6-T


                                                        1.1.1 J-TekacNonethane
                                                        I.IAJ-TeeaUamoelliane
                                                        TeliaUiluueUiyterie
                                                         TYuNiunm) cMorttto
                                                                   (I.T)
                                                         Thkam
                                                         Toluene
                                                         Tok>
                                                                        >iyl-.
                                                           koro o( 10% or I
           Pyrtdne
           »TrTioBna,
            mino)
     2-(U-n>-.
                                                                                                            Pmptortc aad. 2-<2,4,5-trtc**>ropt>.no«yK
                                                                                                 U2M	 2,4.«-TikMoraphennl.
                                                                                                 U231	2,4^-TrtcHorephenol.
                                                                                                 U230	2,4>TikMaroptMna>yw>e«c Mid.
                                                                                                Ammax. I—RXPRZSKIITATIVX SAMFUKO
                                                                                                                MITHOM

                                                                                                 The  methods  and  equipment used  for
                                                                                                ..tripling watte materials will vary with the
                                                                                                form and consistency of the waste materials
                                                                                                to  be sampled. Samples collected using the
                                                                                                sampling  protocols  listed below, for sam-
                                                                                                pling waste with properties similar to the In-
                                                                                                dicated materials, will be considered by the
                                                                                                Agency to be representative of the waste.

                                                                                                Extremely viscous liquid—ASTM Standard
                                                                                                 D140-70 Crushed or powdered material—
                                                                                                 ASTM Standard D346-76 Soil or rock-like
                                                                                                 material—ASTM Standard  D420-69 SoU-
                                                                                                 llke material—ASTM Standard D1453-66
                                                                                                Fly  Ash-like   material—ASTM  Standard
                                                                                                 D2234-76 [ASTM Standards are available
                                                                                                 from ASTM. 1916 Race St.. Philadelphia,
                                                                                                 PA 19103]
                                                                                                Containerized liquid waste*-"COLIWASA"
                                                                                                 described In 'Test Methods for the Eval-
                                                                                                 uation of Solid Waste. Physical/Chemical
                                                                                                                                                         40 CFK Ch. I (7-145 Edition)

                                                                                                                                                Methods." • U.S.  Environmental  Protec-
                                                                                                                                                tion Agency. Office of Solid Waste. Wash-
                                                                                                                                                ington, D.C.  20460. (Copies  may be ob-
                                                                                                                                                tained from Solid Waste Information. V£.
                                                                                                                                                Environmental  Protection Agency. 26  W.
                                                                                                                                                Bt. Clalr St.. Cincinnati. Ohio  452681
                                                                                                                                              Liquid  waste in  pits, ponds, lagoons, and
                                                                                                                                                similar reservoirs.—"Pond  Sampler" de-
                                                                                                                                                scribed in  "Test Methods for the Evalua-
                                                                                                                                                tion of  Solid Waste.  Physical/Chemical
                                                                                                                                                Methods." •

                                                                                                                                                This manual  also  contains additional in-
                                                                                                                                              formation on application of these protocols.
                                                                                                                                                  ATTENDEE II—EP Toxicnr TEST
                                                                                                                                                             PEOCKDUUS

                                                                                                                                                     JL Extraction Procedure (£/>>

                                                                                                                                                1. A representative sample of the waste to
                                                                                                                                              be tested (minimum site 100 grams) shall be
                                                                                                                                              obtained using the methods specified In Ap-
                                                                                                                                              pendix I or any other method capable  of
                                                                                                                                              yielding a representative sample within the
                                                                                                                                              meaning of Part 260. [For detailed guidance
                                                                                                                                              on conducting the various aspects of the EP
                                                                                                                                              see "Test  Methods for the Evaluation  of
                                                                                                                                              Solid Waste.  Physical/Chemical Methods"
                                                                                                                                              (Incorporated by reference, see I 260.11).]
                                                                                                                                                2. The sample shall be separated Into its
                                                                                                                                              component liquid and solid phases using the
                                                                                                                                              method described  In  "Separation  Proce-
                                                                                                                                              dure" below. If  the solid residue » obtained
                                                                                                                                              using this method  totals less than 0.5%  of
                                                                                                                                              the original weight of the waste, the residue
                                                                                                                                              can  be  discarded  and the operator shall
                                                                                                                                              treat the  liquid phase as  the  extract and
                                                                                                                                              proceed Immediately to Step 8.
                                                                                                                                                I. The solid material obtained from the
                                                                                                                                              Separation Procedure shall be evaluated for
                                                                                                                                              Its particle sixe. If  the solid material has a
                                                                                                                                              surface area per gram of material equal to.
                                                                                                                                              or greater than. S.I cm* or passes through a
                                                                                                                                              9A mm (0.375 inch) standard sieve, the oper-
                                                                                                                                              ator shall  proceed to Step 4. If the surface
                                                                                                                                              area  Is smaller  or  the particle size  larger
                                                                                                                                              than specified  above,  the solid  material
                                                                                                                                              shall be prepared for extraction by crush-
                                                                                                                                              Ing, cutting or grinding the material so that
                                                                                                                                               k These methods  are  also  described In
                                                                                                                                             "Samplers  and Sampling  Procedures for
                                                                                                                                             Hazardous Waste Streams," EPA 600/2-80-
                                                                                                                                             018. January 1980.
                                                                                                                                               •The  percent solids Is  determined  by
                                                                                                                                             drying the filter pad at 80*C until It reaches
                                                                                                                                             constant weight and  then calculating the
                                                                                                                                             percent solids  using the following equation:
                                                                                                                                               Percent solids -
                                                                                                                                                                - Q»» •*•(*) o«p»d)
                                           375
                                                                                                                                         376

-------
Environmental Pratstctlon Afancy

It psssm through a 9.6 mm (0.975 Inch) sieve
or. If the material Is In a single  piece, by
subjecting the material to the  "Structural
Integrity Procedure" described below.
  4. The tolld material obuined in Step I
•hall be welched and placed In an extractor
with 16 time* Its weight of delonised water.
Do not allow the material to dry prior to
weighing. For purposes of this  test, an ac-
ceptable extractor li one  which will Impart
sufficient agitation  to the mixture to not
 only prevent itratlfication of  the (ample
 and extraction fluid but also insure that all
•ample  surfaces are continuously brought
 Into contact with  well  mixed extraction
 fluM.
  6. After the Mild  material and  delontaed
water are placed In the extractor, the opera-
tor shall begin agitation  and measure the
pH of the solution in the extractor. If the
pH Is greater than 6.0. the pH of the solu-
tion shall be  decreased  to  5.0 ± 0.2 by
adding  0.5 N acetic add. If the pH U equal
to or less than 6.0, no acetic add should be
added. The pH of the solution shall be mon-
itored, as described below, during the course
of the extraction and if the pH rises above
6.2. 0.5N acetic add shall  be added to bring
the pH down to 6.0 ± 0.2. However, In no
event shall  the aggngrate amount of  add
added to the solution exceed 4 ml of  add
per gram of solid. The mixture shall be agi-
tated for 24 hours and maintained at 20'-
40'C (68--104T) during this time. It ls rec-
ommended that the  operator monitor and
adjust the pH during the course of the ex-
traction with a device such as the Type 46-A
pH Controller manufactured  by Chemtrix.
Inc.. Hlllsboro. Oregon 97123  or its equiva-
lent, in conjunction  with  a metering pump
and reservoir of 0.6N acetic add.  If such a
system   Is  not available,  the  following
manual  procedure shall be employed:
  (a) A  pH meter shall be calibrated In ac-
cordance with the  manufacturer's specifica-
tions.
  (b) The pH  of the  solution  shall be
checked and. If necessary, 0.6N acetic  add
shall be manually added to the  extractor
until the pH  reaches 5.0 ± 0.2.  The pH of
the solution shall be adjusted at 16. 30 and
80'  minute intervals, moving to  the next
longer Interval If the pB does not have to be
adjusted more than 0.6N pH units.
  (c)  The adjustment procedure shall be
continued for at least 6 noun.
  (d) If  at the end  of the 24-hour extraction
period,  the pH of  the solution Is not below
5.2  and  the maximum amount of acid (4 ml
per gram of solids) has not been added, the
pH  shall be adjusted to 5.0 ± 0.2 and the ex-
traction continued for  an  additional  four
hours, during which  the pH shall be adjust-
ed at one hour Intervals.
  8.  At  the  end of the 24 hour extraction
period,  delonlzed water shall be  added to
                       Part 261, App. II

the extractor In an amount  determined by
the following equation:
V-(20XW)-16-A
V-ml detonised water to be added
W-weight in grams of Mild  charged to ex-
    tractor
A-ml of 0.6N acetic  add added during ex-
    traction
  7. The material in the extractor shall be
separated into its  component  liquid and
Mild phases as described under "Separation
Procedure."
  8. The liquids resulting from Steps 2 and 7
shall be combined. This combined liquid (or
the waste Itself If it has leas than M percent
solid*, as noted In step 2) Is the extract and
shall be analyzed for the presence of any of
the contaminants  specified  in Table  I  of
1281.24  using the Analytical  Procedures
designated below.

          Separation Procedure

  Equipment: A filter holder, designed for
filtration media having a nominal pore sice
of 0.45 micrometers and capable of applying
a 6.3 kg/cm* (75 pel) hydrostatic pressure to
the solution being filtered,  shall be used.
For  mixtures  containing   nonabsorptlve
solid*, where separation can  be  effected
without <"T*"-<"g a 5.3 kg/cm' pressure dif-
ferential,  vacuum  filters employing a 0.46
micrometers filter  media can be used. (For
further guidance on filtration equipment or
procedures see "Test  Methods  for Evaluat-
ing Solid Waste. Physical/Chemical Meth-
ods"   incorporated  by   reference,   see
I 260.11). Procedure:*
  (I)  Following manufacturer's directions,
the filter unit shall  be assembled with a
filter bed consisting  of a 0.45 micrometer
filter membrane. For difficult  or slow  to
filter mixtures a prefilter bed consisting of
the following prefllters in increasing  pore
size (0.65 micrometer membrane, fine  glass
  'This procedure Is Intended to result In
separation of the "free" liquid portion of
the waste from any solid matter having a
particle size  >0.45 pm.  If the sample  will
not filter, various other separation tech-
niques can be used to aid In the filtration.
As  described  above,  pressure  filtration Is
employed to speed up the filtration process.
This does not alter the nature of the separa-
tion. If liquid does not separate during fil-
tration, the waste can be centrlfuged. If sep-
aration occurs  during  centiifugatlon,  the
liquid  portion  (centrlfugate)  Is  filtered
through the 0.45 pm filter prior to becoming
mixed  with the liquid portion of the waste
obtained from the Initial filtration. Any  ma-
terial that will not pass through the filter
after  centrifugatlon  Is considered a solid
and Is extracted.
Part 261, App. II

fiber prefilter.  and coarse glass fiber pre-
filter) can be used.
  (U) The waste shall be poured Into the ni-
tration unit.
  (ill) The reservoir shall be slowly pressur-
ized until liquid begins to flow from the fil-
trate outlet at which point the pressure In
the filter shall be Immediately lowered to
10-16 pslg.  Filtration shall  be continued
until liquid now ceases.
  (Iv) The pressure shall be Increased step-
wise In 10 psl Increments to 76 pslg and fil-
tration continued  until now ceases or  the
pressurizing gas begins to exit from the fil-
trate outlet.
  (v) The filter unit shall be depressurtced.
the Mild material removed and weighed and
then transferred  to the extraction  appara-
tus, or. in the case of final filtration prior to
analysis, discarded. Do not allow the materi-
al retained on the filter pad to dry prior to
weighing.
  (vl) The liquid phase shall be stored at 4'C
for subsequent use In Step 8.

     B. Structural Integrity Procedure

  Equipment: A Structural Integrity Tester
having a 3.18 cm (1.26 In.) diameter hammer
weighing 0.33 kg  (0.73 IDS.)  and having a
free fall of 16.24 cm (6 In.)  shall be used.
This  device is available  from  Associated
Design and Manufacturing Company, Alex-
andria, VA 22314, as Part No. 125. or It may
be fabricated  to  meet  the specifications
shown In Figure L
          40 C« Ch. I (T-1-S3

                Procedure
  1. The sample holder shall be filled with
the material to be tested. If the sample of
waste Is a large monolithic block, a portion
shall be  cut from the block  having the di-
mensions of a 34 cm (1.3 In.) diameter x 7.1
cm (2.8 In.) cylinder. For a  fixated waste.
samples may be cast In the form of a 3.3 cm
(14 In.) diameter x 7.1 cm (2.8 In.) cylinder
for purposes of conducting this test. In such
casts, the waste may be allowed to cure for
30 days prior to further testing.
  2. The sample holder shall  be placed into
the Structural Integrity Tester, then the
hammer shall be raised to  Its  maximum
height and dropped. This shall be repeated
fifteen tunes.
  3. The material shall be removed from the
•ample holder, weighed,  and  transferred to
the extraction apparatus for extraction.

Analytical Procedure* for Analysing Extract
              Contaminant!

  The  test methods for analyzing  the ex-
tract are as follows:
  I. For  arsenic, barium, cadmium,  chromi-
um, lead, mercury, selenium, silver, endrin.
llndane.   methoxychlor,  toxaphene,   2,4-
D(2,4-dlchlorophenoxyacetic  addl or 2.4.5-
TP [2.4.5-trtehlorophenoxyproplonlc  add):
"Test Methods for the Evaluation of Solid
Waste, Physical/Chemical Methods" (Incor-
porated by reference, see 1260.11).
  2. [Reserved]
  For all analyses, the methods of standard
addition *h«n bg used for qinntlflratlftn of
spedes concentration.
                                         377
                                                                                         378

-------
Environmental Protection Agency
Part 261, App. II
                                                O-i
                                               1525cm
                                                                 COMBINED
                                                                •  WEIGHT
                                                                  33Kg
                                                                 I 73101
                                                            (3 IScml
                                                            11.25"!
                                                                                J
                                                             •SAMPLE
                                                                   ELASTOMERIC*
                                                                   SAMPLE HOLDER
     *ELASTOMERIC SAMPLE HOLDER FABRICATED OF
       MATERIAL  FIRM ENOUGH TO SUPPORT THE SAMPLE

                                 Figure   1

                 COMPACTION  TESTER
  [45 PR 33119. May 19. 1980. « amended at 46 FR 35247. July 7. 19B11
                                          379
                            Port 261, App. Ill

                              APPENDIX III—CHEMICAL ANALYSIS
                                         TEST METHODS
                              Tables 1. 2. and 3 apeclfy the appropriate
                            analytical  procedure*,  described  In  "Teat
                            Methods (or Evaluating Solid Waite. Phyal-
                            cal/Chemlca) Method*."  (Incorporated  by
                            reference, aee I 260.11) which shall be lued
                            to determine whether  a sample contains a
                            given Appendix VII or VIII toxic constitu-
                            ent.
                              Table 1 Identifies each Appendix VII or
                            VIII organic constituent along with the ap-
                            proved measurement method. Table 2 Iden-
                            tities the  corresponding methods (or inor-
                            ganic apeclea. Table 3 summarizes  the con-
                            tents of 8W-S4B  and supplies specific sec-
                            tion and method numbers for sampling and
                            analysis methods.
                              Prior  to  final  sampling and  analysis
                            method selection the analyst should consult
                            the specific aectlon or  method described In
                            SW-846 for additional guidance on which of
                            the approved methods should be employed
                            for a specific sample analysis altuatlon.

                              TABLE  1—ANALYSIS METHODS FOR ORGANIC
                                  CHEMICALS CONTAINED IN SW-846
Compound

Ac'fl'i'"


BaVtMM


IUft»<^x-*O«yirj+





Cutann ib.Mrt. 	
CNordane 	 _ 	 	 	 _. 	
CNonattd Uphwiyta 	
Chtorimtid d*>*ruo-
                                                                        look)	
                                                                       TricNoiani
                                                                       VkMM»
                                                                       X»tw,_
•.01. (412.
a 12. us

•4)1. 174
•.01. U4
(.40. ITS
•.12, *TS
•4M. 875
8.09. 875
8.04, 875
8 09. 875
(.OS. US
•4)1. 802.
    874
•4)1. (74
a.oa. ITS
8.06. STS
8 12. 876
• 12, 875
•.12. ITS
8.12. US
•.0*. US
•.08. ITS
•4)1. 874
    •32
•4)1. 84)2.
    874
•4)1. 802.
    874
HO. 87S
8 06, 8.M.
    875
8.08. 875
•.04, ITS

8.01. 874
8.04, 875
84M. STS

•4W, 8.08.

•.OS. 8.08.
    875
8 08, 8.09.

•.OS, 8.08.
    875
8.12. 8TS
8.01. 874
8.01, 874
8.04. U4
8.02. 874

8.08. 875
8.08. 87S
8.01, 874
8.01. 874
8.01, 174
8.04. 875

•.40, STS
•.01. I
•.01, 874
•.01. 874
•.02. 874
M10. 8120.
    8290
M10. 8240
M10. 8240
8150. 8290
8120. 8250
8040. 8250
•090. 8250
8040. 8290
MM, B2SO
aoao! 82M

MIS. 8240
MIS. 8240
    8290
SOM. 8290
8120. 82M
8120, 8290
M10. 8240
8120.8250
MM. 8260
    •290
M10. 8240
    8250

MIS, 1240

MIS, (240
•100. 8260

MM. 8260
MM. 82SO
•040, 1240

M1S. 8240
8040. 8290
•040. 8290
     •140

     •140

MM. KM

MM, 8250

8090, 8290
8120. 8250
MtO. 8240
M10. 8240
8040. 8260
•020. M24
     8250
     8290
80M. 8250
M10. 8240
M10, 8240
M10. 8240
•040. 8290

•190. 8250
M10. 8240
M10. 8240
MtO. 8240
 8020. 8240
                                                                   380

-------
Environmental Protection Agency

  >Anafcna tor |Hiaiia»e»ana and oarbanto: I «waa •
praurK k> a raao banman 1.4:1 and 5:1 enoaota ahouU I
                                                                Port 261, App. Ill

                                          TABLE 2—ANALYSIS METHODS FOR INORGANIC
                                            CHEMICALS CONTAINED IN SW-646—Conttn-
                   •ort Ml, App. Ill                                  40 C« Ch. I (7-1-.S ioltion)

                          TABLE 3—SAM-UNO AND ANALYSIS METHODS CONTAINED m SW-*46—Continued
TABLE 2—ANALYSIS METHODS FOR INORGANIC
     CHEMICALS CONTAINED m SW-M6
                                                 CompoiKd
       Compound
 Anarac.
CrnmUKl
                       matrnoXa)
                           9.M
                           9.51
                           1.52
                           9.93
                           9*1
                     9A45. 9.54C.
                                 Saeond
7040,7041
TOM. 7061
TOM, 7091
TOM. 7091
71M. 7191
7196, 7196.
                                          Uarouy-
                                           Total Organic Hatogan	
                                                                 mavwdO)
1.647
 9.56
 9.57
 »M
 9.M
 9.M
 9.55
 9.M
 9.97
    7197
7420, 7421
T4TO. 7471
7620. 7521
7740. 7741
77M. 7791
    M10
    •020
    9030
            TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846

TW.
tencting of Sold WM*M 	
j>M»tapm«iH of App«opf»te famptng Ram ,.,, 	
FuTVaWittntAl BtttMtiCtV Conotpti
Diwr ptitrtral Rmv^M
S«TVrn« RiWwtom S*vnptk>o
Smitftod Rwmm Swrc>1'V)
&y*namtr nwrt?fn fivv^^X)

Conipo«to 6tMt^nO
fit*Mmp*«ig , ,
Cott md Lou Fww*^^



WMQM^ Bo***. 	
Pn^
ThM
Trt» 	
AJ^M

ffatortk^i «J Sangria rVwtfMnov*.

DocuiTBBtititaon o( CVMin ol CuMody 	 	 ™ 	 	 _-_ 	 . 	
Sanytoj LAtMto. 	 	 	 	 — ~ 	 	 - 	 — 	 	 	 	
Sarrtpto G*Mli
Fialfj tog Boo*
ChtMrxHOmodv ^tf^ftl
Svnpta AnvJyw FtequMt ShMt 	

R«c**pi and LoognQ of C >mpi< 	 	 	 	 ~ 	









SeUfltih CtOiWtf-Ciap Method 	




FMa
Saekon
No.
1.0
1.0
1J>-2

1 0-7



1.0-7



10-7

3.2 1
377
37J
37.4
375
37.6
37,7
3.3
33
2.0
2.0-1
20-3
2.0-5
2.0-e
2.0-A
20-10
20-10
20-12
2.0-13
30
38-2
3.2-2
3.2-2
37-2


4.0
4 1
4.1
SO
5.3
9.0
7.0
dMon
Maowd
No.











"










	


	















	
Saoond
Saekon
No.
1.0
1.1
111







1.1.47
1 1 4 .3
17


1717
17 U
171 4
171 6
17.1.6
1717
177
17.3
1.3
1.3.1
1.3.2
1.3.3
1.3.4
13.S
1.3.6
1.3.7
1.3.6
1.3.9
1 4
1.4.1
1.47
1.4.3
14.4
2.0
2.1
2.1.1
2.1.1
21.1
2.17
2.12
2.1.3
2.1.4
adMon
Uamod
No.

























— 	 	

	








1010
1020

1110



Ta*
E»ae*n Proo-ur. Teft* T«t 	

lriotv.wteT.Khn.quat..-.. 	 .--- 	 	 	 — • 	 	
"***• i,™ _ ..-

Ouok/ton Prooadura tor OH. Qraaaa or Wan 	

Saparaury Fumal UqwMJquU Extraction 	
Conttnuoua Uquld-UquhJ Extraction ,, 	 _ 	 - 	 ...,.,.-



Haaflanana


Antimony. Ftama AAS 	 	 	
Araanic, Flama AAS 	 -,..,.„,,,,-., ,,,„.„,-- , -
ytraanlf Fumac* AAS ... . • .•<
Barium Ramt AAS r ,


Cadrrium. Fumaet AA*

Chromum Furnana AAS . 	 .



Laad Flamt AAS
LaarJ Furtrr AAS ,.., ,
Marcury CoM Vapor liquid 	
Mwruy CoM V«m S&M , ,, ,
taokal Ftamp A, A$
NMial Fumaot AA8



Saiw, Fum»e» AAS 	 	 	
Organte Analytical Mtthnoa ,,
Kmm CrMonatuuiaplaL MaBmH
Hatonanatad Votatta Organlra


AcroWn AcrytonlMa Aoatonittaa

Pim-ut. ft-* 	 	 	
Oroanochlonna Paattddaa and PCS. 	


Organaphoaphonja raatictdai

OC/MS Volattlaa 	
QC/MS Saml-Volat»aa, Packad Column 	 	
QC/MS Saml-VolatlMa. CapWary 	
Analym of CrUomatad Duma and Obantolurana . 	
Potrnudaar Aromatic Hydnxartxma 	 	
MlacalUnanm An^ytcml Mattioda 	 	 	
Cyanida: Total and AmanaMa to CNortnaaori.., 	
Total Omanic Hatooan fTOX).
SuHUM 	 ' 	 "
pM Maamamanl 	

•acwn
No.
7.1. 7 A 74
74

•.49
.1
1
•.49-9
9.49-«
•.0
9.0
»JO
»JO
9.0
•.0
' 9.0
1.0
(.0
IJ)
•.0
•.0
•.0
•.0
IJ)
9.0
90
9J)
9.0
ta

CO

9.0
IX)

1.0

• 0
• 0
9.0
1.0
9.0
•J)





90
• 0
•A
9.0


1.0
9.0
1.0
90

9.0
• 0
1.0
90


10
idWon
UatHod
No.
	

	


	 ~tM»

9.1
9.01
• 94.
•JM
9.96
•.92


•.M
(.60
(.51
. 62
9.52
1.53

1-54
1.54

1,540
• 547
1.46
1.56
U7
157


-__
159
9.M
9.M






1.04
1.06
1.01
•.09


9.40
974

• 10




K>
•acend
SacHm
No.
21.4
4.0
4.1
4.1
4.1
4.1
4.1
47
47
4_2
47
47
5.0
5.0
5.0
7.0
7.0
74
7.0
7.0
70
7.0
7.0
7.0
7.0
7.0

7.0
70
7.0
70
7.0
7.0

70
70
70
7.0
7.0
90





|1
0 i
1.1
1.1


1.1



10



on

No
1310

3010
3020
3030
30M

3510
3520
3530
3540
3550
5020
5030

7470
7471
TOM
T061
TOM
7091
7130
7131
TOM
7191
7195
7196
7197
7420
7421
7470
7471
7520
7521
7740
7741
77M
mi






9040
90M
MM
MM


91M
6240
•250
62M






                                       381
                                                          382

-------
                  Prot*cH*n Agency                                 Fart 261. App. VII

        TABLE 3—SAMPLING, AND ANALYSIS METHODS CONTAINED m SW-846—Continued
                                                                        Part 261, App. VII
                                                                                                                                  40 CF« Ch. I (7-l-*5 EaHton)
    Mmdu
                                                          No.
                               10.0
                               104)
                               10.0
                               104
                               10.0
                               10.0
                                                                    No.
                                                                                                       EPA
                                                                                                     heunl-
                                                                             No.
                               10.1
                               10.1
                               10.1
                               10J

                               lOJ
                                                                                       No.
                                                                                                     •024.
   •See apedflc met*L

 148 PR 18281. Apr. 8.1983, M amended at M PR 2000. Jan. 14.1986)
             DAW NOTE At 50 PR 3000, JUL
 14. 1986, Put Ml. App. TJI wu amended M
 followi: In Table 1. the entry (or "Chlorin-
 ated dlbensodloxlni" wai  removed, and the
 entrie* for "Chlorinated  dlbenzo-p-dloxlna.
 and "Chlorinated dlbenzof urani" were added.
 In Table 3. the entry for "AnalyBii of Chlor-
 inated  Diozini   and  Dlbensofurani"  wai
 added under "Organic Analytical Method*—
 Oat  ChromatoKTaphic/Maai Spectroicopy
 Method! (DC/MS)" after the entry  "OCX
 MS   Seml-VolatUet,   Capillary".   Thete
 amendments are effective  July 16.19S6. For
 the convenience of the uaer,  the luperaeded
 entry from Table 1 U *et out below:

 TABLE 1—ANALYTICAL METHODS FOR ORGANIC
       CHEMICALS CONTAINED m SYV-846
                       Arrofonc VII—BASIS FOB LISTING
                                HAZARDOUS WASTE
          Compound
  Fnt
 edNon
mettodla)  methodta)
CNooneleddtieiiiDdiuiana..
                            . M*. US MM. 1250
      APPENDIX IV—[RESERVED FOR
  RADIOACTIVE WASTE TEST METHODS]

APPENDIX  V— [RESERVED   FOR   INFEC-
  TIOUS WASTE  TREATMENT SPECIFICA-
  TIONS]

      APPENDIX VI—[RESERVED FOR
            ETIOLOOIC AGENTS]
                    POOL


                    FOW-
FOM_
F004_
F006-

FOO»_

F007_
F008-
F00»..
F010-
F011_
F012..
F019..
F020..
                    FOZ1..


                    F022

                    F023..
                                Hazardoua eoneMuenia tor oNoh
                  V1.1->tchlc»o«l)iena,
                  itonnBvBd ftuofOCMtooflB.
                  fi)Mnt, nMttiytanc ct«onbs.
                                                                        FOM.


                                                                        FOZ7.
                                                                        FOM —
                                                                        K001-
                            NA
                                             kMora. carton
                                                          toobuttnol, pynArw.
                                                                          duonturu floni,
                                                         Cywiidi (Mtt«).
                            Cymnid* (ula).
                            CyinfcM (»tt»).
                            Cymnb. (MM).
                            Cyvnkto (camptoitd)
                            Heuvctani chromun, cyi
                             Xurane;   M-   and
          leiiachloiutihenoia and ttwr chtorophenoiy de-
          pt»nol wd to dwiviM*.
                                   p«iUcNo>o-
                            Ten-,  and  penuohlonxtt»nio-^d0m. tm-
                             •nd pexleciilonxtti*n>oturan»; >v and Mra-
                             ttitm uphenoli and mav cnlofophenoxy danva-
                             feva aoda, avtan. ethera, amna and olhat aalti.
                                                                                                      K010-
K011.
K01S.
K014.
K01t_

K016.
                                                                                                      K01T.
                                                                                                      KOH_

                                                                                                      K01t-
                                                                                                                         coneMuanla for when haled
       Chtoromethane.  OcMoromeihana,
         ana. cartoon MacNortda. dHoroethytena. 1.1-
         oKMoroefhana, U-djentoroethane.  nna-l-t-
         UVIiluiuelhylene,  1,1-dKhtoroetnytaoa,   1,1,1-
         MoNoroelhana, t.U-Mchloroamna, Mentor-
         otnAiM, l.1,U-ana. oeniena. cNatieraena. drcn-
         nna. Wuena. iietinaialana.

        Ten-, penu-, and nenacntororjbenio p dk)«jni. le-
         n-. penta-, and haiaehlonxtbeniohvana.

        Ten-, penta-. and henchkxodioenio^diorina: la-
         n- Dent*-, end heuehloroditaeniorinna: kV.
         len-. and penlacMorophenoU end their cMoro-
         phenoiy derivakve acxta. edert, ethera, emne
         and other aalla.

        Ten-, pema-, and heKechlcndrbenio^-dioilna: le-
         ka-, penta-, end heiachlorodlbenio
-------
Environmental Protection Agency
        1.1 J vqtamttmm,   t.1.1 J tt»mMut^»m\»,
 MM - 1 1,l-aaNaiw*im.  1.1.1
 (46 FR 4419. Jan. 16.1981. u amended at 46
 TO 17477. May 30.  1981; 49 FR 5313. Feb.
 10.1984; 60 FR 3000. Jan. 14, 1985]
  Emcrrvc DATS NOTE At 50 FR 3000, Jan.
 14. 1985. Put 361, App. Vn was amended by
 adding the entrle* tor F030 through P023.
 and F036  through F038. effective July  16.
 1985.
       Aimnnx VIH— HAZARDOUS
 Acetonltrfle (Ethanerutrfle)
 Acetopnenone (Ethanone. 1-phenyl)
 3Xalpha-Acetonylbenzyl>-4-
  hydroxycoumaiin and salts (Warfarin)
 3-Aeetylaminofluorene  (Acetamlde.  N-(BH-
  fluoren-3-yl)-)
 Acetyl chloride (Ethanoyl chloride)
 l-Acetyl-3-thiourea  (Aoetamlde.  N-
 6-Amino-l.la.2.8,8a,8b-hexahydro-8-
  ( hydro Jtymethyl >-8»-methoxy-5-methyl-
  carbamate     azlrinot2'.3':3.4]pyrrolo(1.2-
  allndole-4.7-dlone,  (ester) (Mltomycln  C)
  (AElrlno[2'3<:3,4)pyrrolo(l,2-a)lndole-4.7-
  dlone.                6-amino-B-[((amtno-
  carbonyl)oxy>methylM.la,2.8.8a,8b-
  hexahydro-8amethoxy-S-methy-)
6-(Amlnoinethyl>-3-lBOxazolol  (3(3H)-Isoxa-
  rolone,  Mamlnomethyl)-)  4-Aminopyrt-
  dlne (4-Pyrldinamine)
Amltrole (lH-1.2.4-Trlazol-3-amlne)
                     Port 261, App. VIM

Aniline (Benaenamine)
Antimony and compoundi. V.OJB.'
Aramlte (Bulfuroui acid. 3-chloroethyl-. 1-
  C4-( l.l-dlmethylethyl)phenoxy)-l-
  methylethyl ecter)
Anenlc and compoundi, V.OM.'
Arsenic acid (Orthoarsenic add)
Arsenic pentoxlde (Arsenic (V) oxide)
Anenlc trioxlde (Arsenic (III) oxide)
Auramine       (Benzenanune.       4.4'-
  carbonlmldoylbls[N,N-Dlmethyl-.   mono-
  hydrochloride)
Azaserine (L-6erlne, dlaaoacetate (ester))
Barium and compounds. N.OJB.*
Barium cyanide
Benzlclacrldlne (3.4-Benzacrldlne)
Benclalanthracene (1.3-Benuinthracene)
Benzene (Cyclohexatrlene)
Benzenearsonlc add (Arsonlc acid, phenyl-)
Benzene, dlchloromethyl- (Benzal chloride)
Bencenethiol (Thlophenol)
Benzidlne (tl,r-Biphenyn-4.4'dUmlne)
Bencolblfluoranthene (3,3-Benzof)uoranth-
  ene)
BensotJIOuoranthene  (7,8-Benzonuoranth-
  ene)
Beazotalpyrene (3,4-Benzopyrene)
p-Benzoqulnone (1.4-Cydohexadlenedtone)
Benzotrichloride (Benzene, trichloromethyl-
  )
Benzyl chloride (Benzene, (chloromethyl)-)
Beryllium and compounds, Jt.OS.*
Bl*(3-chloroetboxy>methane  (Ethane. 1.1'-
  [methylenebis(oxy»bls[2-chloro-])
Bls(3-chloroethyl)   ether   (Ethane.  1.1'-
  oxyblsI3-chloro-))
NJf-Bls(3-ch]oroethyl>-2-naphthylamlne
  (Chlomaphazlne)
Bls(3-chlorolsopropyl) ether  (Propane. 2.3'-
  oxy bist S-chloro- ])
Bls(chloromethyl)     ether     (Methane.
  oxyblitchloro-})
Bls(2-ethylhexyl) phthalaU (1.2-Benzenedl-
  carboxyllc acid. blB(3-ethylhexyl> ester)
Bromoacetone (2-Propuione,  1-bromo-)
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether (Benzene,  1-
  bromo-4-phenoxy-)
Bruclne (8trychnldln-10-one.  2.3-dlmethoxy-
  )
3-Butanone peroxide (Methyl ethyl ketone.
  peroxide)
Butyl benzyl phthalate  (1,2-Benzenedlcar-
  boxyllc  acid, butyl phenylmethyl ester)
2-sec-Butyl-4.6-dinltrophenol       (DNBP)
  (Phenol, 2.4-dlnltro-6-(l-methylpropyl)-)
Cadmium and compounds, N.O.S.*
Calcium chromate (Chromic acid, calcium
  salt)
Calcium cyanide
  'The abbreviation N.O.S. (not otherwise
specified) signifies those members of  the
general class not specifically listed by name
In this appendix.
Port 261, App. VIII

Carbon dlsulflde (Carbon bisulfide)
Carbon oxyfluorlde (Carbonyl fluoride)
Chloral (Acetaldehyde. trichloro-)
ChlorambucU   (Butanolc   acid,  4-Cbls<2-
  chloroethyDamlnolbenzene-)
Chlordane (alpha and gamma Isomers) (4,7-
  Methanolndan.   1.3.4,5.6.7,8.8-ocUchloro-
  3.4.7.7a-tetrahydro-> (alpha and  gamma
  Isomers)
Chlorinated benzenes. N.OJB.*
Chlorinated ethane. N.O A'
Chlorinated nuorocarbons. N.OJB.'
Chlorinated naphthalene, N.O.8.*
Chlorinated phenol, N.O J.'
Chloroacetaldehyde (Acetaldehyde. chloro-)
Chloroalkyl ethers. N.OJB.*
p-ChloroanlUne (Benzenamlne. 4-chloro-)
Chlorobeniene (Benzene, chloro-)
CnlorobenzUate  (Benzeneacetlc add,  4-
  chloro-alpha-(4-chlorophenyl>-alpha-
  hydroxy-, ethyl ester)
3-Chloro-l, 3-butadlene (chloroprene)
p-Chloro-m-cresol   (Phenol,   4-chloro-3-
  methyl)
l-Chloro-3.3-epoxypropane   (Oxlrane.   3-
  (chloromethyl)-)
3-Chloroethyl vinyl ether (Ethane, (2-chlor-
  oethoxy)-)
Chloroform (Methane, trichloro-)
Chloromethane (Methyl chloride)
Chloromethyl   methyl  ether  (Methane.
  chloromethoxy-)
3-Chloronaphthalene (Naphthalene,  beta-
  chloro-)
3-Chlorophenol (Phenol, o-chloro-)
l-(o-Chlorophenyl)thiourea (Thlourea, (3-
  chlorophenyl)-)
3-Chloropropene (allyl chloride)
3-Chloroproplonltrne   (PropanenltrUe,  »-
  chloro-)
Chromium and compounds. N.O^.*
Chrysene (1,3-Bensphenanthrene)
Citrus  red No.  3  (3-Naphthol,  l-t(X»-
  dlmethoxyphenyl)azo)-)
Coal tars
Copper cyanide
Creosote (Creosote, wood)
Cresols (Cresyllc add) (Phenol, methyl-)
Crotonaldehyde (3-Butenal)
Cyanides  (soluble salts  and   complexes).
  N.0.8.'
Cyanogen (EthanedlnltrQe)
Cyanogen bromide (Bromine cyanide)
Cyanogen chloride (Chlorine cyanide)
Cycasin (beta-D-Olucopyranoalde. (methyl-
  ONN-azoxyhnethyl-)
3-Cydohexyl-4.6-dlnltrophenol   (Phenol, 3-
  cyclohexyl-4,6-dlnltro-)
Cyclophosphamide   (2H-l,3.3,-Oxazaphos-
  phorine,  [bli(2-chloroeUiyl)amlno)-tetra-
  hydro-. 2-oxide)
Daunomydn  (5.13-Naphthacenedlone. (88-
  cts)-8-acetyMO-[(3-amlno-3.3.6-trideoxy)-
  alpha-L-lyxo-hexopyranosyl)oxy)-7,8.B.10-
  tetrahydro-6,8,ll-trihydroxy-l-methoxy-)
          40 Cnt Ch. I (7.145 MHton)

DDO    (Dtehlorodiphenyldlchloroethane)
  (Ethane.     l,l-dlchk>ro-2.2-bl»
Dlbens[a.hlanthracene (U.t.6-DIbenzanth-
  racene)
7H-Dibenao[fM)carbaiole (3.44.6-Dlbenscar.
  bazole)
Dlbenao(a,«)pyrene (1.3.4>Dlbenapyrene)
Dlbenio(a.hlpyrene (l.U.t-Dlbenzpyrene)
Dlbenzo[aJ)pyrene (1,3.7.8-Dtbenzpyrene)
1.3-Dibromo-3-chloropropane (Propane. 1.3-
  dlbromo-*-chloro-)
1,3-Dtbromoethane (Ethylene dlbromlde)
Dibromomethane (Methylene bromide)
Dl-n-butyl phthalate (U-Benzenedlcarbox-
  yllc add, dlbutyl ester)
o-Dlchlorobencene (Benzene. 1.2-dlchloro-)
m-Dlchlorobenzene (Benzene. l.J-dlchloro-)
p-Dichlorobenzene (Benzene. 1,4-dlchloro-)
Didilorobenzene. N.OJS.* (Benzene.
  dlchloro-. N.OA*)
l,3'-Dlchlorobenzldlne  ((l.r-Blphenyll-4.4'-
  dlamlne. 34'-dlchloro->
1.4-Dlchloro-3-butene  (3-Butene,  1.4-dlch-
  loro->
Dlchlorodinuoromethane  (Methane,  dlch-
  lorodlfluoro-)
1.1-Dlchloroethane (Ethylldene dlchloride)
1,2-Dichloroethane (Ethylene dlchloride)
trans-l^-Dichloroethene (U-Dichloroethy-
  lene)
Dlchloroethylene. N.OB.*  (Ethene,  dich-
  loro-. N.O.8.*)
1.1-Dichloroethylene (Ethene,  1.1-dichloro-)
Dichloromethane (Methylene chloride)
3.4-Dlchlorophenol (Phenol. 3,4-dlchloro-)
3.6-Dlchlorophenol (Phenol. 3.6-dlchtoro-)
2,4-Dlchlorophenoxyaoetlc add (3,4-D), salts
  and eaten (Acetic add,  2.4-dlchlorophen-
  oxy-, salts and eaters)
Dlchlorophe&yUntne  (Phenyl  dlchloroar-
  slne)
Dichloropropane,  N.OB.*  (Propane,  dlch-
  loro-. N.OB.*)
1.2-Dlchloropropane (Propylene dlchloride)
Dlchloropropanol, N.OB*  (Propanol, dlch-
  loro-. N.OB.*)
Dlchloropropene.  N.OB.*  (Propene.  dlch-
  loro-. N.OB.*)
1.3-Dlchloropropene  (1-Propene.  1.3-dlch-
  loro-)
Dleldrin (1.3.3.4,10.10.hexachloro4.7-epoxy-
  1.4.4a.6,6,7.8.8a-octa-hydro-endo,exo-
  1,4:6.8-Dimethanonaphthalene)
l.*c3.4'Dlepoxybutane (2.2'-Bioxirane)
Dlethylanlne (Andne, dlethyl-)
                                        385
                                                                                       386

-------
Environmental Protection Agency

NJI-Dtethylhydradne   (Hydnudne,   1.2-
  dlethyl)
O.O-Diethyl 8-methyl ester of phosphoro-
  dlthlole  Mid  (Phosphorodlthiolc  acid.
  O.O-dlethyl 8-methyl eater
O.O-Dlethylphosphoric   add.   O-p-nltro-
  pbenyl ectcr (Phosphoric add. diethyl p-
  nltropbenyl ester)
Diethyl phthalate  (1.3-Benzenedlcarboxyllc
  add. diethyl eiter)
O.O-Dlethyl  O-2-pyradnyl   phoaphoroth-
  loate  (Phosphorothlolc add, O.O-dlethyl
  O-pyrazlnyl eater
 Diethylstllbesterol        u^'-Stilbenedlol.
  alphajOpha-dlethyl. bla(dlhydrogen phos-
  phate. ->
 Dthydroaairole  (Bencene.  1,2-methylene-
  dlozy-4-propyl-)
 J.4-Dihydroxy-alpha--2-oxoethyn
  erter
 LS'-Dlmethoxybenzidlne   (Cl.l'-BlphenyU-
  4.4'dlamlne. 3-3'-dlmethoxy-)
 p-Dimethylamlnoazobenzene (Benzenamlne,
  N.N-dlmethyl-4-(phenylazo>-)
 7.12-Dlmethylbenz[a)anthracene  (1.2-Ben-
  zanthracene. 7.12-dlmethyl-)
 3.3'-Dimethylbenzldine ([1.1-Blphenyl]-4.4-
  dlamlne. 3.3'-dimethyl-)
Dlmethylcarbamoyl  chloride  (Carbamoyl
  chloride, dimethyl-)
 1.1-Dimethylhydnztne (Hydracine.  Li-di-
  methyl-)
 1.2-Dlmethylhydratlne (Hydracine.  1.2-dl-
  metbyl-)
S.3-Dlmethyl-l-(methylthlo)-2-butanone. O-
  [(methylamlno)  carbonyDoxlme   (Thlo-
  fanox)
alpha^lpha-Dlmethylphenethylamlne (Eth-
  anamlne. l.l-dlmethyl-2-phenyl-)
2.4-Dimethylphenol (Phenol. 2.4-dimethyl-)
Dimethyl phthalate (1.2-Benzenedicarboxy-
  llc add. dimethyl eater)
Dimethyl  aulfate  (SuUuric acid, dimethyl
  eiter)
Dlnitrobenzene.  N.O.S.* (Benzene, dlnltro-.
  N.O.8.')
4,6-Dlnltro-o-cresol and talU (Phenol. 2,4-
  dlnltro-6-methyl-, and aalta)
2.4-Dlnltrophenol (Phenol. 2,4-dlnltro-)
2.4-Dlnltrotoluene  (Benzene,   l-methyl-2,4-
  dlnltro-)
2.6-Dlnltrotoluene  (Benzene,   l-methyl-2.6-
  dlnltro-)
Dl-n-octyl phthalate (1.2-Benzenedlcarboxy-
  Uc acid. dJoctyl eater)
1.4-Dloxane (1.4-Diethylene oxide)
Diphenylamlne (Benzenamlne. N-pheny)-)
1.2-Diphenylhydracine (Hydracine.  1,2-dl-
  phenyl-)
                     Port 261, App. VIII

DI-n-propylnitroMmlne (N-Nltro*o-dl-n-pro-
  pylamlne)
Dliulfoton       (O.O-dlethyl        8-t>-
  (ethylthlo)ethyn pho«phorodlthioat«)
2,4-Dlthlobluret (Thlolmldodlcarbonlc dla- •
  mlde)
Kndoiulfan (6-Norbomene. 2.1-dlmethanol.
  1.4.B.6.7.7-hexachloro-. cyclic lulflte)
Bndrin and  metabolite*  (1.2,1,4.10.10-hex-
  achloro-6,7-epoxy-l,4,4a.6.a.7,8.8a-
  octahydro^ndo.endo-1.4:6.8-
  dimethanonaphthalene, and metabolite*)
Ethyl carbamate (Drethan) (Carbamlc add.
  ethyl eater)
Ethyl cyanide (propanenitrlle)
EthylenebUdlthlocarbamic add.  aalta and
  eaten  (1.2-EthanedlylblacarDamodlthlolc
  add. aalta and eaten
Ethylenelmlne (Azlridlne)
Ethylene oxide (Oxlrane)
Ethylenethlourea (2-ImidazoUdinethlone)
Ethyl  methacrylate  (2-Propenolc  acid.  2-
  methyl-. ethyl eater)
Ethyl  methaneaulfonate (Uethaneaulfonlc
  acid, ethyl eater)
 Fluoranthene (BcnzoCJjLlfluorene)
 Fluorine
 2-Fluoroacetamlde (Acetamlde,  2-fluoro-)
 Fluoroacetic add. aodlum aalt  (Acetic add,
  fluoro-, aodlum aalt)
 Formaldehyde (Methylene oxide)
 Formic acid (Methanoic acid)
 Olycldylaldehyde (l-Propanol-2,3-epoxy)
 Halomethane. N.O^.'
 Heptachlor        (4.7-Methano-lH-indene,
   1.4.6,6.7.B,8-heptacnloro-3a,4.7,7a-
  tetrahydro-)
 Heptachlor   epoxlde (alpha,   beta, and
  camma  laomen) (4.7-Methano-lH-lndene.
   1.4.E.8.7.S.e-heptachloro-2.3-epoxy-3a,4,7.7-
  tetrahydro-. alpha, beta, and camma Uo-
  men)
 Hexachlorobenzene (Benzene, hexachloro-)
 Hexachlorobutadlene       (1.3-Butadlene,
   1.1,2.3.4,4-hexachloro-)
 Hexachlorocyclohexane  (all Isomen) (Un-
  done and Uomen)
 Hexachlorocyclopentadlene  (1.3-Cydopen-
  tadlene, 1.2,3.4.S,6-hexachloro->
 Hexachlorodlbenzo-p-dloxlna
 Hexachlorodlbenzofurani
 Hexachloroethane (Ethane. 1.1.1,2.2,2-hex-
  achloro-)
 1.2.3.4.10.10-Hexachloro-1.4.4a.S.8.B«-
  hexahydro-1.4:&.B-endo.endo-
  dlmethanonaphthalene (Hexachlorohexa-
  hydro-endo.endo-dimethanonaphthalene)
 Hexachlorophene  (2.2'-Methylenebls(3.4.6-
  trichlorophenol))
 Hexachloropropene  (1-Propene. 1.1.2.3.3.}-
  hexachloro-)
 Hexaethyl   tetraphoaphate   (Tttrapboa-
  phorlc acid, hexaethyl eater)
 Hydrazlne (Dlamlne)
 Hydrocyanic add (Hydrofm cyanide)
 Hydrofluoric add (Hydroten nuorldt)
Part 261, App. VIII

Hydrogen auldde (Sulfur hydride)
Hydroxydlmethylanlne   oxide   (Caeodylle
  acid)
Indeno(l,2.3-cd)pyrene
  phenylene)pyrene)
lodomethane (Methyl Iodide)
Iron dextran (Ferric dextran)
kocytnlc acid, methyl  eater (Methyl lao-
  cyanate)
Uobutyl alcohol (1-Propanol. 2-methyl-)
Uoaalrole (Benzene.  1.2-methylenedloxy-4-
  allyl-)
Kepone  (Decachlorooctahydro-1.3.4-Meth-
  ano-2H-cyclobuta[cd]pentalen-2-one)
Lulocarplne (2-BuUnolc acid. 2-methyl-. 7-
  [(2,3-dUiydroxy-2-(l-methoxyethyl>->-
  methyl-l-oxobutoxy)methyl)-2.3.8.7a-
  tetrahydro-lH-pyrrollzln-1-yl eater)
Lead and compounds. N.O.8.*
Lead acetate (Acetic acid, lead aalt)
Lead phoaphate (Phosphoric acid, lead aalt)
Lead   subacetate    (Lead,    bla(acetato-
  O)tetrahydroxytri->
Malelc anhydride (2.5-Furandlone)
Malelc hydrazide (1.2-Dlhydro-3.e-pyridaxtn-
  edlone)
Malononitrile (Propanedlnltrile)
Melphalan      (Alanlne.       3-[p-bla(2-
  chloroethyl)aminolphenyl-, L-)
Mercury fulminate (Fulmlnlc add. mercury
  aalt)
Mercury and compound!. N.O.8.*
Methacrylonltrlle   (2-Propenenltrlle,    2-
  methyl-)
Methanethlol (Thiomethanol)
Methapyrilene       (Pyrldlne,       2-1(2-
  dlmethy lamlno )ethyll-2-thenylamlno-)
Metholmyl     (Acetlmidlc     add.     N-
  C(methylcarbamoyl)oxy3thio-,     methyl
  eater
Methoxychlor (Ethane,  l.l.l-trtchloro-2.2'-
  bla(p-methoxyphenyl)-)
2-Methylaziridlne (1,2-Propylenlmlne)
3-Methylcholanthrene
  (Benz[J]aceanthrylene,    1.2-dlhydro-l-
  methyl-)
Methyl chlorocarbonate (Carbonochloridic
  acid, methyl ester)
4,4'-MethyleneMs(3-chloroanUine) (Benzen-
  amlne. 4.4'-methyleneb!s-(2-ch)oro-)
Methyl ethyl ketone (MEK) (2-Butanone)
Methyl hydrazlne (Hydrazlne, methyl-)
2-Methyllactonltrile (Propanenltrile,  a-hy-
  droxy-2-methyl-)
Methyl  methacrylate  (3-Propenolc add,  2-
  methyl-. methyl ester)
Methyl methanesulfonate (Methanesulfonlc
  add. methyl ester)
2-Methyl-2-(methylthlo)proplonaldehyde-o-
  (methylcarbonyl)  oxime   (PropanaL   2-
  methyl-2-(methylthlo>-,               Q-
  I( methy lamlno Xajbonylloxlme)
N-Methyl-N'-nltro-N-nltroaoKuanldlne (Qua-
  nldlne. N-nltroso-N-methyl-N'-nltro-)
Methyl parathlon (O.O-dlmethyl O-(4-nitro-
  phenyl) phoaphorothloate)
          40 CFR Ch. I (7-1-«5 Edition)

Methylthlouraell (4-lH-Pyrtmldinone.  2.3-
  dlhyoro-tt-methyl-3-thloxo-)
Mustard gas (Sulflde. bia(2-chloroethyl)-)
Naphthalene
1.4-Naphthoqulnone     (1.4-Naphthalene-
  dlone)
1-Naphthylamlne (alpha-Naphthylamlne)
2-Naphthyiamlne (beta-Naphthylamine)
l-Naphthyl-2-thlourea  (Thiourea, 1-naphth-
  alenyl-)
Nickel and compounds. N.O.8.*
Nickel carbonyl (Nickel tetracarbonyl)
Nickel cyanide (Nickel (U) cyanide)
Nicotine  and   aalU  (Pyrldlne,  (8>-3-U-
  methyl-a-pyrrolidlnylK and aalts)
Nitric oxide (Nitrogen (D) oxide)
p-Nltroanlllne (Benzenamlne, 4-nltro-)
Nltrobencine (Benzene, nltro-)
Nitrogen dioxide (Nitrogen (TV) oxide)
Nitrogen  mustard and hydrochloride aalt
  (Ethanamlne. 3-ehloro-, N-(2-chloroethyl)-
  N-methyl-. and hydrochloride aalt)
Nitrogen  mustard N-Oxlde and  hydrochlo-
  ride aalt  (Ethanamlne.  2-chloro-.  N-(2-
  chloroethyl>-N-methyl-, and  hydrochlo-
  ride aalt)
Nitroglycerine   (1.2.1-Propanetriol.   trinl-
  trate)
4-Nltrophenol (Phenol, 4-nltro-)
4-NltroqulnoUne-l-oxide (Qulnollne. 4-nltro-
  1-oxide-)
Nltroaamine.  N.O.S.*
N-Nltroaodi-n-butylamlne   (1-Butanamine,
  N-butyl-N-nltroao-)
N-Nttrosodlethanolamme   (Ethanol,   2.21-
  (nltroaolmlno)bls-)
N-Nltroaodlethylamlne   (Ethanamlne.  N-
  ethyl-N-nltroao-)
N-Nltrosodlmethylamlne  (Dlmethylnltroaa-
  mlne)
N-Nltroao-N-ethylurea  (Carbamide, N-ethyl-
  N-nitroao-)
N-Nltroaomethylethylamine  (Ethanamlne.
  N-methyl-N-nltroso-)
N-Nltroso-N-methylurea  (Carbamide.  N-
  methyl-N-nltroao-)
N-Nltroao-N-methylurethane    (Carbamlc
  add. methylnltroso-. ethyl ester)
N-Nltroaomethylvlnylamine   (Ethenamlne,
  N-methyl-N-nltroao-)
N-Nltroaomorphollne (Morphollne, N-nltro-
  ao->
N-Nltrosonomicotine (Nomteotlne. N-
  nitroao-)
N-Nltroaoplperidlne (Pyrldlne, hexahydrc-.
  N-nitroao-)
Nltroaopyrrolldlne (Pyrrole, tetrahydro-, N-
  nltroao-)
N-Nltroaoaarcoalne (Sarcoaine. N-nltroao-)
5-Nltro-o-toluldlne (Benzenamlne. 2-methyl-
  5-nltro-)
Octamethylpyrophosphoramlde    (Dlphos-
  phoramide, octamethyl-)
Osmium tetroxlde (Oamlum (Vm> oxide)
7-OxablcycloC2J.l]heptane-2.3-dlcarboxyllc
  add (Endothal)
                                         387
                                                                                                                                  388

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Environmental Protection Agoncy

Paraldehyde    (1,3,5-Trioxane,    2,4.6-trl-
  methyl-)
Parathlon (Phosphorothlolc   Mid.  O,O-
  diethyl CMp-nitrophenyl) eater
Pentachlorobenzene (Bensene. penUchloro-
  )
Pentachlorodlbenzo-p-dloxlna
Pentachlorodlbenzofuran*
PenUchloroethuie (Ethane, penUchloro-)
Pentmchloronltrobenzene (PCNB) (Benzene.
  pentachloronltro-)
 PenUchloraphenol (Phenol, penUchloro-)
 Pheiucetin    (AceUmlde.    N-(4-ethoxy-
  phenyl)-)
 Phenol (Benzene, hydroxy-)
 Phenylenediamine (Benzenediamine)
 Phenylmercury acetate (Mercury. aceUto-
   phenyl-)
 N-Phenylthloure* (Thiourea, phenyl-)
 Phosgene (Carbonyl chloride)
 PhMphlne (Hydrogen phoiphlde)
 Phoephorodlthioic  acid.   O.O-diethyl   8-
   [(ethylthiotanethyl) eater (Phorate)
 Phoephorothlolc  acid.  O.O-dimethyl  O-lp-
  ((dlmethylaminotoulfonyDphenyl]   ester
  (Famphur)
 Phthalic acid  eaten. N.O.S.*  (Benzene,  1.2-
  dlcarboxylic acid, eaten. N.O.S.*)
 Phthalic anhydride (1.2-Benzenedlcarboxy-
  llc acid anhydride)
 2-Plcoline (Pyridine, a-methyl-)
 Polychlorlnated blphenyl. N.O.S.*
 Potassium cyanide
 Potassium silver cyanide (ArgentateUO. dl-
  cyano-. potassium)
 Pronamide  (3.5-Dichlorc-N-U.l-dlmethyl-2-
  propynyDbenzamlde)
 1.3-Propane sultone (1.2-Oxathiolane, 2,2-dl-
  oxide)
n-Propylamlne (1-Propanamlne)
Propylthlouracil     (Dndecamethylenedla-
  mine.   N.N'-bia(3-chlorobenzyl>-.   dlhy-
  drochlorlde)
2-Propyn-l-ol (Propargyl alcohol)
Pyridine
Reserpine  (Tohlmban-16-carboxyllc  acid.
  1 1.17-dlmethoxy-18-[(3.4.5-
  trimethoxybenzoyl)oxy)-. methyl eater)
Resorctnol (1,3-Benzenedlol)
Saccharin and salts (l,2-Benzoiaothlazolin-3-
  one. 1,1-dioxlde, and salts)
Saf role (Benzene, 1.2-methylenedloxy-4-
  allyl-)
Selenlous acid (Selenium dioxide)
Selenium and compounds. N.O.8.*
Selenium sulflde (Sulfur selenide)
Selenourea (Carbamlmldoselenolc acid)
Silver and compounds, N.O.S.*
Silver cyanide
Sodium cyanide
Streptozotocln (D-Glucopynnose. 2-deoxy-
  2-( 3-methyl-3-nltroaoureldo >-)
Strontium aulflde
Strychnine and salts  (Strychnldln-10-one.
  and salts)
1,2,4,6-Tetrachiorobenzene        (Benzene.
  1.2.4.5-tetrachloro-)
                     fort 961, App. VIII

XS.7.B-Tetnchlorodlbenso-p-dloxln (TCDD)
  (Dlbenco-p-dloxln, 2.3.7.B-tetrachloro-)
Tetrachlorodibenzo-p-dloxins
Tetrachlorodlbenzofurans
Tetrachloroethane, N.O.S.0 (Ethane,  tetra-
  chloro-. N.O.8.*>
l.l.l.a-Tetrachlorethane  (Ethane.  1.1.1.2-
  tetrachloro-)
1.1.2.2-Tetrachlorethane  (Ethane,  1.1,2.2-
  tetrachloro-)
Tetrachloroethane  (Ethene.   1.1.2.2-tetra-
  chloro-)
Tetrachloromethane (Carbon tetrachlorlde)
2.3.4.6,-Tetrachlorophenol (Phenol, 2,3,4.6-
  tetrachloro-)
Tetraethyldlthlopyrophosphate (Dlthlopyr-
  ophosphorlc acid, tetraethyl-eater)
Tetraethyl lead (Plumbane, tetraethyl-)
Tetraethylpyrophospbate (Pyrophoaphorlc
  acide. tetraethyl ester)
Tetranltromethane (Methane, tctrmnitro-)
 Thallium and compounds. N.O.8.*
 Thalllc oxide (Thallium (HI) oxide)
 Thallium  (I) acetate (Acetic acid, thallium
   (I)salt)
 Thallium (I) carbonate (Carbonic add, dlth-
   alllum(I)salt)
 Thallium (I) chloride
 Thallium  (I) nitrate (Nitric add, thallium
   (I) salt)
 Thallium selenite
 Thallium  (I) sullate (Sulfurlc add. thallium
   (I) salt)
 Thloacetamlde (Ethanethioamide)
 Thiosemlcarbszide   (Hydrazlnecarbothioa-
   mlde)
 Thiourea (Carbamide thlo-)
 Thiuram  (Bls(dimethylthlocarbamoyl)  dl-
   aulflde)
 Toluene (Benzene, methyl-)
 Toluenedlamlne (Dlaminotoluene)
 o-Toluldlne hydrochloride (Benzenamine. 2-
   methyl-. hydrochloride)
 Tolylene  dllsocyanate (Benzene. 1.3-dllso-
   cyanatomethyl-)
 Toxaphene (Camphene, octachloro-)
 Trlbromomethane (Bromofonn)
 1.2.4-Trichlorobenzene (Benzene. 1.2.4-trlch-
   loro-)
 1.1.1-Trlchloroethane (Methyl chloroform)
 1.1,2-Trichloroethane  (Ethane. 1,1,2-trich-
   loro-)
 Trlchloroethene (Trlchloroethylene)
 Trlchloromethanethlol      (Methanethlol.
   trlchloro-)
 Trichloromonofluoromethane    (Methane.
   trlchlorofluoro-)
 2,4.5-Trlchlorophenol  (Phenol, 2.4.6-trich-
   loro-)
 2.4.6-Trich)orophenol  (Phenol. 2,4.8-trich-
   loro-)
 2.4.5-Trlchlorophenoxyacetlc  acid (2.4.5-T)
   (Acetic acid, 2.4,5-trichlorophenoxy-)
 2,4,B-Trlchlorophenoxyproplonic acid (2,4.5-
   TP)  (Sllvex)  (Propionolc  acid. 2-(2,4,S-
   trlchl orophenoxy >-)
Part 261, App. IX

Trlchloropropane.  N.OJ.' (Propane, trich-
  loro-. N.OA*)
1.2.3-Trlchloropropane (Propane, l,J,3-trich-
  loro-)
O.O.O-Trlethyl  phoaphorothloate  (Phoa-
  phorothlolc acid. O.O.O-triethyl eater)
sym-Trlnltrobenzene (Benzene,  1,3.6-trlnl-
  tro-)
Trls(l-azridlnyl) phosphlne  sulflde (Phoa-
  phlne aulflde. triad •azlridinylO
Trls(2.3-dlbromopropyl) phosphate (1-Pro-
  psnol, 2.3-dlbromo-, phosphate)
Ttypsn  blue   (2,7-Naphthalenedlsulfonlc
  acid.    3,3'-[(3.3>-dlmethyl(l.r-blphenyl>-
  4.4'-dlyl)bls(azo)lbls(5-amino-4-hydroxy-.
  tetrasodlum salt)
Uracll    mustard    (Dracll     B-[bl»(2-
  chloroethyDamlno)-)
Vanadlc acid, ammonium salt (ammonium
  vansdate)
Vanadium pentoxide (Vanadium (V) oxide)
Vinyl chloride (Ethene. chloro-)
Zinc cyanide
Zinc phosphide
[46 PR 27477. May 20, 1081: 46 FR 29708,
June 3.1881. as amended at 49 FR 5312. Feb.
10. 1984; 60 FR 2000. Jan. 14. 1885]
  EmcTTVi DATE NOTE At 60 FR 2000. Jan.
14. 1985, Part 261, App. VIII was amended
by adding the  entries for  Hexachlorodl-
tMttH>-p-dioxlna,  Hexachlorodlbenzofurans.
Pentachlorodlbenzo-p-dloxins,  Pentachloro-
dlbenzofurana,  Tetrachlorodlbenzo-p-dlox-
1ns. and Tetrachlorodlbenzofurans. effective
July 15.1986.

    APPENDIX IX—WASTES EXCLUDED
       UNDER i{ 260-20 AND 260.22
   TABLE 1—WASTES EXCLUDED FROM NON-
             SPECIFIC SOURCES
 Mmopotttvi
  DiMnttol
  Grtctw
  Crannall
            StofwyPaM.
             NY.
            Qnckmtl. OH..
                              fl»n«rat«d  in*
                        Scpuntxr  21,  18*4.
                        wtiic^i oootain EPA Hex*
                        •ntow Wut* Not. FOO3
                        and F005 M wall u «•!
 Icgoan u ol
 21. 19S4.
SUiwd bottom nh
 («Pt»o«Jr»«>«ty  29.000
 attc ywdt).  oanWnid
 In th» North LtQOon, on
 S«p»mb»r 21,  19M.
               EPA
               Not
 FOOL F002. F003. FOO4,
 •ndFOOS.
                              40 CM Ch. I (7-105 Edition)

                     TABLE 2—WASTES EXCLUDED FROM SPECIFIC
                                    SOURCES
FcoWy
(Rwciv**)
AddraH

WMttt OMOnptOO

                    TABLE 3—WASTES EXCLUDED FROM COMMER-
                      CIAL. CHEMICAL PRODUCTS, OFF-SPECIFICA-
                      TION SPECIES, CONTAINER RESIDUES.  AND
                      SOIL RESIDUES THEREOF
                       FHMy
                    Union Cotkte
                      Coip.
                                T«n.LA..
                      ConUnwMMd tai (weraa-
                        miMy  11.000  eubk
                                            torn ol tow Km 9 ppm.
                     [49 FR 17070. Sept 21. 10S4)


                     APPENDIX X—METHOD or ANALYSIS FOR
                      CHLORINATED DiBEnio-r-DioxncB AND
                       -DIBENZOimtANS L l * 4

                                   ttethod 1210
                      1. Scope and Application
  i This method Is appropriate for the anal-
ysis of  tetra-, penta-, and hexachlorinated
dlbenio-p-dioxlna and -dibensof urana.
  •Analytical protocol for determination of
TCDDs In phenolic chemical wastes and soil
samples obtained from the  proximity of
«-h»mii*«i  dumps. T.O. Tlernan  and  M.
Taylor. Brehm laboratory.  Wright  State
University, Dayton. OH 46436.
  •Analytical protocol for determination of
chlorinated dlbenco-p-dloxlns and chlorinat-
ed dlbenzofurans In  river water. T.O. Tier-
nan  and M.  Taylor.   Brehm Laboratory.
Wright State University, Dayton. OH 46436.
  4 In general, the technique* that should be
used to handle these  materials  are  those
which  are followed for  radioactive or infec-
tious  laboratory materials.  Assistance In
evaluating laboratory practices may be ob-
tained from  Industrial  hyglenlsts and  per-
sons specialising In safe  laboratory prac-
tices.  Typical infectious waste Incinerators
are probably not satisfactory devices for dis-
posal of materials highly contaminated with
CDDs or CDFs. Safety  instructions are out-
lined In EPA Teat Method 613(4.0)
  See also: 1) "Program for monitoring po-
tential contamination In the laboratory fol-
lowing the handling and analyses of chlorin-
ated dlbenzo-p-dloxlns  and dlbenzofurans"
by F. D. Hlleman et aL. In: Human and En-
                                 ConUnued
                                         389
                                                                                                                                    300

-------
Environmental Protection Agoncy

  1.1 This method measure* the coneentra-
.Ion of  chlorinated dlbenao-p-dioxlns and
chlorinated  dlbeniofunni  In   chemical
vastes including still  bottom*,  (liter aids.
Judges, ipent carbon,  and reactor residues.
Ad In soils.
  1.2  The sensitivity of thli method 1* de-
jendent upon the level of Interference*.
  1.3  This method to recommended for use
inly by analysts experienced with residue
inalyili and skilled In mat* spectral analytl-
:al techniques.
  1.4  Because of the extreme  toxlclty of
.hese compounds,  the analyst  must take
lecessary  precautions to prevent exposure
•o himself, or to others, of materials known
>r believed to contain CDDs or CDPs.
  2. Summary of Ote Method
  2.1  This method is  an analytical  extrac-
ion  cleanup   procedure,  and  capillary
xilumn IBS chromatograph-low  resolution
nass spectrometry method, using capillary
x>lumn QC/MS  conditions  and  Internal
itandard techniques, which allow for the
aeasurement of PCDDs and PCDPs In the
ixtract.
  2.2  If Interferences are encountered, the
nethod provides  selected general purpose
•Jeanup procedures to aid the  analyst In
,helr elimination.
  3. Interference*
  3.1  Solvents,  reagents,  glassware,  and
ither sample processing hardware may yield
Uscrete artifacts and/or elevated baselines
Busing misinterpretation  of gas chromato-
{rams. All of these materials must be dem-
onstrated  to  be free from Interference*
jnder the conditions of the analysis by run-
ling method  blanks.  Specific selection of
reagents and purification of solvents by dls-
miatlon  In  all-glass  systems may  be  re-
quired.
  3.2 Interferences co-extracted from the
lamples will vary considerably from source
jo  source, depending upon the  diversity of
,he industry being sampled. PCDD  is often
usociated with other Interfering chlorinat-
ed  compounds such as PCB's which may be
it  concentrations several orders of  magnl-
:ude higher than that of PCDD. While gen-
eral cleanup techniques are provided as part
Df this method, unique samples may require
additional  cleanup  approaches  to  achieve
.he sensitivity stated In Table 1.
  3.3 The other Isomen of tetrachlorodi-
aenzo-p-dloxln may interfere with the meas-
urement of  2.3.7,8-TCDD. Capillary column
tas chromatography IB  required to  resolve
 /ironmental  Risks  of  Chlorinated  Dtoxlns
 uid Related Compounds. RJC. Tucker, et al,
 ads.. Plenum  Publishing  Corp..  1083.  2)
 Safety procedures outlined In EPA. Method
 313. Federal Register  volume 44. No. 233,
 December 3.1979.
                       Part 261, App. X

those Isomen that yield virtually Identical
mass fragmentation patterns.
  4. Apparatus and Uaterialt
  4.1.  Sampling equipment for discrete or
composite sampling.
  4.1.1 Orab sample bottle—amber glass, 1-
liter or 1-quart volume.  French or Boston
Round design Is recommended. The contain-
er must be washed and solvent rinsed before
use to minimize Interferences.
  4.1.2.  Bottle caps—threaded to screw on
to the sample bottles. Caps must be lined
with Teflon. Solvent washed foil,  used with
the shiny side towards the sample, may be
substituted  for the Teflon if sample is not
corrosive.
  4.1.3.  Compositing equipment—automatic
or m""i»i composing system. No tygon or
rubber tubing may be used, and the system
must Incorporate glass  sample  containers
for the collection of a minimum  of 250 ml.
Sample containers must be kept  refrigerat-
ed after sampling.
  4.2  Water bath—heated,  with  concentric
ring cover,  capable of temperature control
(±2 'C>. The bath should be used  In a hood.
  4.3  Oas chromatograph/mass spectrome-
ter data system.
  4.3.1  Oas chromatograph: An  analytical
system  with a temperature-programmable
gas chromatograph and all required accesso-
ries including syringes, analytical columns,
and gases.
  4.3.2  Column:  SP-2250 coated  on a 30 m
long  x 0.25 mrn  ij). glass column (Supelco
No.  2-3714  or equivalent).  Olass capillary
column conditions: Helium carrier gas at 30
cm/sec linear velocity run splitless. Column
temperature Is 210 'C.
  4.3.3  Mass spectrometer: Capable of scan-
ning  from 35 to 450 amu every 1 sec or leu,
utilizing 70 volts (nominal) electron energy
In the electron Impact ionlzstlon mode and
producing a mass spectrum which meets all
the criteria in Table 2 when 50 ng of deca-
fluorotriphenyl-phosphlne (DFTPP)  Is In-
jected through  the OC Inlet. The system
must also be capable of selected Ion moni-
toring (SIM) for at least  4  Ions simulta-
neously, with a cycle time of 1 sec or less.
Minimum integration  time for SIM  Is  100
ms. Selected ion monitoring Is verified by in-
jecting .015 ng of TCDD Cl" to give a mini-
mum signal to noise ratio of 5 to 1 at mass
328.
  4.3.4  OC/MS  Interface:  Any  OC-to-MS
Interface that gives acceptable calibration
points at 60 ng per Injection  for  each com-
pound of Interest  and achieves  acceptable
tuning  performance criteria  (see Sections
8.1-8.3) may be  used.  OC-to-MS Interfaces
constructed of all glass or glass-lined materi-
als are recommended. Olass can be deacti-
vated by  sllanlzlng with dlchlorodlmethylsl-
lane. The  Interface must be capable  of
Part 261, App. X

transporting at least  10 ng of  the  compo-
nents of Interest from  the OC to the  MS.
  4.3.5  Data system:  A  computer  system
must be interfaced to the mass spectrome-
ter. The system must  allow the continuous
acquisition and storage on machine-readable
media of all mass spectra obtained through-
out the duration of  the chromatographlc
program. The computer must have software
that can search any OC/MS data  file for
Ions of a specific mass  and that can plot
such Ion abundances  versus time  or scan
number. This type of  plot  Is defined as an
Extracted Ion Current Profile (EICP). Soft-
ware must also be able to Integrate  the
abundance. In  any EICP. between specified
time or scan number limits.
  4.4  Pipettes-Disposable. Pasteur, 150 mm
long x 5 mm ID (Fisher Scientific Co.. No.
13-678-6A or equivalent).
  4.6  Flint glass bottle (Tenon-lined screw
cap).
  4.8  Reactl-vlal (sUanlzed) (Pierce  Chemi-
cal Co.).
  6. Reapenti
  6.1  Potassium  hydroxlde-
-------
Environmental Protection Agency

traction. Chemical preservative* should not
be  used In the field unless more than 24
houn will elapse before delivery to the labo-
ratory. If an aqueous lunple Is Uken  and
the aample will not be extracted within 48
houn of collection, the sample ahould be
adjuited to  a pH ranee  of  9.0-8.0  with
aodlum hydroxide or iulf uric acid.
  8.3  All aamplei must be extracted within
 7 dayi and completely analyzed within 30
 days of collection.
  .9. Extraction and Cleanup Procedure*
  9.1  tlae an aUquot of 1-10 I aample of the
 chemical waste or aoU  to be analysed. Soil*
 ihould be  dried using  a ctream of prepurl-
 fled nitrogen and pulverized in a ball-mill or
 •Imllar device. Perform this operation  In a
 clear area  with proper  hood apace. Transfer
 the aample to a tared 136 ml flint clan
 bottle (Teflon-lined acrew  cap) and deter-
 mine the weight of the aample. Add an ap-
 propriate  quantity of  "Cl-labelled  3.3,7.8-
 TCDD (adjuit the quantity according to the
 required minimum  detectable concentra-
tion), which  U  employed at an  internal
standard.
  B.I  Extraction
  9.2.1   Extract chemical wa*te aample* by
 adding  10 ml methanol, 40 ml petroleum
 ether. 60 ml doubly distilled water, and then
 shaking the  mixture  for  2 minute*.  Tan
 should be completely dlaaolved in any of the
 recommended  neat   aolvenU.   Activated
 carbon aamplef muct be extracted with ben-
 zene using method 3640  In 8W-846 (Test
 Method* for Evaluating Solid Waite—Phyai-
 cal/Chemlcal  Method*,   available   from
 Qf.O.  Stock #056-022-81001-2).  Quantita-
 tively transfer the organic extract or dis-
 solved aample to a clean 260  mi nint  glass
 bottle  (Teflon lined screw cap), add 60 ml
 doubly distilled water  and  shake for 2 min-
 ute*. Discard  the aqueous layer and proceed
 with Step 9.3.
   9.2.2  Extract soil sample*  by adding 40
 ml of petroleum ether to  the aample, and
 then shaking for 20 minute*. Quantitatively
 transfer the  organic extract to a clean 260
 ml flint  glass bottle (Teflon-lined screw
 cap), add  60  ml doubly distilled water and
 shake  for 2  minutes.  Discard the  aqueous
 layer and  proceed with Step 9.3.
   9.3 Wash the organic layer with 60 ml of
 20% aqueous potassium hydroxide by shak-
 ing for 10 minutes and then remove and dis-
 card the aqueous layer.
   9.4 Wash the organic layer with 50 ml of
 doubly distilled water  by shaking for 2 min-
 utes, and discard the aqueous layer.
   9.6 Cautiously add 60  ml concentrated
 •ulfurtc add and shake  for 10 minute*.
 Allow the mixture to stand until layers sep-
 arate  (approximately 10 minutes),  and
 remove and discard the add  layer. Repeat
 acid washing until no color Is visible in the
 acid layer.
                       Part 261, App. X

  9.6  Add 60 ml of doubly distilled water to
the organic extract and shake for 2 minute*.
Remove and discard the aqueous  layer and
dry the organic layer by adding lOg of anhy-
drous sodium sulf ate.
  9.7  Concentrate the extract to Incipient
dryneas by heating in a 66'  C water bath
and simultaneously flowing a stream of pre-
purlfled nitrogen over the  extract. Quanti-
tatively transfer the residue  to an alumina
mlcrocolumn fabricated as follows:
  9.7.1  Cut off the top section of a 10 ml
disposable Pyrex pipette at the 4.0 ml mark
and Insert a plug of sllanlzed glass wool Into
the Up of the lower portion of the pipette.
  9.7.2  Add  2.8g of Woelm  basic alumina
(previously  activated at 000° C  overnight
and then cooled to room temperature  In a
desiccator lust prior to use).
  9.7.3  Transfer  sample   extract with a
small volume of methylene  chloride.
  9.8   Elule the mlcrocolumn with 10 ml of
1% methylene cholrlde-in-hexane followed
by  16  ml  of  20%  methylene  chlorlde-ln-
hexane and  discard these effluent*. Elute
the column with  16 ml of 60%  methylene
chlorlde-in-hexane and concentrate this ef-
fluent (66' C water bath, stream of prepurl-
fled nitrogen) to about 0.3-0.5 ml.
  9.9   Quantitatively transfer the residue
(using methylene  chloride  to rinse the con-
tainer) to a sllanized Reactl-Vial (Pierce
Chemical Co.). Evaporate, using a stream of
prepurtfted  nitrogen, almost to dryness.
rinse the walls of the vessel with approxi-
mately 0.6 ml methylene chloride, evaporate
just  to  dryness, and  tightly cap the  vial.
Store the vial at 6*  C until  analyst*, at
which time the aample Is  reconstituted by
the addition of trldecane.
  9.10  Approximately  1 hour  before  GC-
MS (HRQC-LRMS) analysis, dilute the resi-
due in the micro-reaction vessel with an ap-
propriate  quantity  of  trldecane. Gently
swirl the trldecane on the lower  portion of
 the vessel to ensure dissolution of the CDDs
 and CDF's. Analyze a sample by  OC/EC to
 provide Insight into the complexity of the
 problem, and  to determine the  manner In
 which the  mass spectrometer   should  be
 used. Inject an appropriate  aliquot  of the
 sample Into the OC-MS instrument, using a
 syringe.
   9.11  If, upon preliminary  OC-MS analy-
 sis, the sample appears to contain Interfer-
 ing substances which obscure the analyses
 for  CDDs and  CDFs,  high performance
 liquid chromalographtc (HPLC)  cleanup of
 the extract Is accomplished, prior to further
 OC-MB analysis.
   10. HPLC Cleanup Procedure'
   ' For cleanup see also method #8320 or
 #8330, SW-846. Test Methods for Evaluat-
 ing Solid  Waste, Physical/Chemical Meth-
 ods (1982).
Part 261, App. X

  10.1  Place approximately 2 ml of hexane
in a-60 ml flint glass sample bottle fitted
with a Tenon-lined cap.
  10.2  At the appropriate retention time,
position sample bottle  to collect the re-
quired fraction.
  10.3  Add 2 ml of 6% (w/v) sodium car-
bonate to the sample fraction collected and
shake for one minute.
  10.4  Quantitatively  remove the hexane
layer (top layer) and transfer to a micro-re-
action vessel.
  10.6  Concentrate the  fraction to dryness
and retain for further analysis.
  11. OC/ltS Analyti*
  11.1  The following column condition* are
recommended: Olas* capillary column condi-
tion*: BP-2260 coated on a SO  m long x 0.26
mm LD. glass column (Bupelco No. 2-3714.
or equivalent) with helium carrier gas at 30
cm/sec linear velocity, run splltless. Column
temperature I*  210'C. Dnder these condi-
tions the retention time for TCDDs I* about
9.5 minutes.  Calibrate  the  system daily
with, a minimum, three Injection* of stand-
ard mixture*.
  11.2  Calculate response factors for stand-
ards relative to  •Kn-TCDD/P (see Section
12).
  114  Analyse sample* with selected  Ion
monitoring of at least two Ion* from Table
1 Proof of the  presence of COD or CDF
exists If the following conditions are met:
  11.3.1 The retention time of the peak In
the sample must match  that  In the stand-
ard, within the  performance  specification*
of the analytical system.
  11.3.2 The ratio  of  ions  must  agree
within  10% with that of the standard.
          40 CPU Oi. I (7-103 fdttlan)

  11.3.3  The retention time of the  peak
 maximum for the tons of interest must ex-
 actly match that of the peak.
  11.4 Quantltate the CDD and CDF peaks
 from the response relative  to the   "Cl-
 TCDD/F internal standards. Recovery  of
 the Internal  standard should  be  greater
 than (0 percent.
  11.5 If a response I* obtained for the ap-
 propriate set of ion*, but I* outside the ex-
 pected ratio, a  oc-eluting impurity  may be
 suspected. In this case, another set of ion*
 characteristic of the CDD/CDF molecules
 should  be  analysed.  For TCDD  a  good
 choice of Ions I* m/e 367 and m/e 269. For
 TCDF a good choice of Ion* Is m/e 241 and
 343. These Ion* axe useful In characterizing
 the molecular structure to TCDD or TCDF.
 For analysis of  TCDD good analytical tech-
 nique would require using all four Ion*, m/e
 287. 330. 133. and 138. to verify detection
 and signal to noise ratio of 5 to 1. Suspected
 impurities such as DDE*. DDD. or PCB resi-
 due* can  be confirmed by checking for their
 major fragments. These materials can be re-
 moved by the cleanup columns. Failure  to
 meet criteria should  be  explained In the
 report, or the sample reanalyzed.
  11.6 If broad background Interference re-
.strict* the sensitivity of the OC/MS analy-
 sis, the analyst  should employ cleanup pro-
 cedures and reanalyze by OC/MS. See sec-
 tion 10.0.
  11.7 In those circumstance* where these
 procedures do not yield a definitive conclu-
 sion,  the use of high resolution mas* spec-
 trometry I* suggested.
  12. Calculation*
  12.1 Determine the concentration of Indi-
 vidual compound* according to the formula:
                      Concentration, fig/am-
                                                     AxA.
where:
A-(ig of Internal standard added to  the
   sample'
O-gm of sample extracted
A,-area of characteristic Ion of the com-
   pound being quantified.
A*-area of characteristic Ion of the  Inter-
   nal standard
R,-response factor •
  Response factors are calculated using data
obtained from the analyst* of standards ac-
cording to the formula:
  'The proper amount of standard  to  be
used  is determined  from the  calibration
curve (See Section 6.0).
,,'JL rt*"1**"1*  'or   PCDDs/Fs   and
HxCDDs/Fs are not available, response fac-
ton for Ions derived from these congeners
are calculated relative to 'Xn-TCDD/F The
analyst may use response factors for 1.2.3.4-
or   2.1.7.8-TCDD,   1,2.1,4,7-PeCDD.   or
1.2,3,4.7.8-HxCDD   for   quantltatlon   of
TCDDs/F*. PeCDDs/Ps and HxCDDs/Fs.
respectively. ImpUdt In this requirement Is
the assumption that the same response Is
obtained from PCDDs/Fs ccontalnlng  the
same numbers of chlorine atoms.
                                         393
                                                                                                                                  394

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Environmental Protection Aaoncy


                    A.XC.
              Rf
                    A..XC.
                        Port 261, App. X
•aual lo (~» MKM *<• QC background DOM attumng « 1
ml xwcto* Iml «ouiw o< »• 1 m> MTVM « 442.
                                               1 J  W EeMtMrp*. LE. Hvra. and W.L BmkM. 1876
                                             n«l»r»no« compound to cahbrvw ion abundino* m«uur»-
                                             fmnl  In ou ehronuiography^niu •pcdromny. Anilvtccl
 TABLE 3—LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING, Low
   RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
   AND HEXACHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS





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 [SO PR 2001. Jan. 14.1B851
   Emcnvr DATT NOTE At 60 FR 2001. Jan.
 14. 1886, Part 261. App. X was added, effec-
 tive July IS. 1085.
 395

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                                    APPENDIX C
                       QUALITY ASSURANCE PROJECT PLAN

                     (Must Be Completed For All Field Operations)
Project Name:
Project Manager:

Field Operations:
QA Office Concurrence:

ESD Peer Review:  	

Project No.: 	
           Date:

           Date:
    Account No.:
Laboratory Designated:
EPA
CLP
Private
Sample Numbers assigned: from _

Sample Schedule and Milestones:

     Activity/Date;	/	I
                  to
     Reports Required;
Regional Sample Control Center Review
Date:	

Project Description and Site Location:
Project Measurement Objectives (Intended use of data):
Sample rationale and network derivation:
                                        - 1 -

-------
 Analyses Rationale:


  # of      Parameter     QA       Matrix    Container    Holding    Preservation
                        Samples    	    	       Time      	
Data Quality Objectives:


  Parameter    Method     Detection     Precision      Accuracy    Completeness
                                lit
Sample procedures to he used:
Sample Custody and Documentation:
Calibration Procedures and Frequency:
Prevent ative Maintenance:
If, for any reason, the schedules or procedures above cannot be followed, the appropriate
person must complete a "Sample Alteration Checklist" for each element changed and have
it (them) verified and reviewed by the Project Manager and the QA Officer/Peer Review.
(See page 5)


                                       -  2 -

-------
Laboratory Data Reduction / QA Review:
Field Data Reduction/QA Review:
Reports (as deliverable or required):
System and Performance Audits:
Scheduled:                                Conducted:
Corrective Action: (IF YES, COMPLETE CORRECTIVE ACTION CHECKLIST AND/OR
SAMPLE ALTERATION FORMS, Appendix B.)


QA Report to Management:
                                       - 3 -

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Safety:
                                          -4-

-------
                          SAMPLE ALTERATION CHECKLIST
Project Name and Number:
Material to be sampled:
Measurement Parameter:
Standard Procedure for Field collection & Laboratory Analysis (cite references):
Reason for change in Field Procedure or Analytical Variation:
Variation from Field or Analytical Procedure:
Special Equipment, Materials, or Personnel  Required:








Initiators Name: _ _ Date:




Project Approval: _ _ _ Date:



Laboratory Approval:    • _ _ _ Date:



    Officer/Reviewer:                             Date:
SainPle Control Center: _  Date:
                                        - 5 -

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                          CORRECTIVE ACTION CHECKLIST
 Project Name and Number:
Sample Dates Involved:
Measurement Parameters):
Acceptable Data Range:
Problem Areas Requiring Corrective Action:
Measures Required to Correct Problems:
Means of Detecting Problems and Verifying Correction:
Initiators Name:	Date:




Project Approval: 	_ Date:




Laboratory Approval:	 Date:



QA Officer/Reviewer:  	Date:



Sample Control Center:	Date:
                                        -6-

-------